id	sid	tid	token	lemma	pos
ajst-3866	1	1	academic	academic	ADJ
ajst-3866	1	2	journal	journal	NOUN
ajst-3866	1	3	of	of	ADP
ajst-3866	1	4	science	science	NOUN
ajst-3866	1	5	and	and	CCONJ
ajst-3866	1	6	technology	technology	NOUN
ajst-3866	1	7	issn	issn	NOUN
ajst-3866	1	8	:	:	PUNCT
ajst-3866	1	9	2771	2771	NUM
ajst-3866	1	10	-	-	SYM
ajst-3866	1	11	3032	3032	NUM
ajst-3866	1	12	|	|	NOUN
ajst-3866	1	13	vol	vol	NOUN
ajst-3866	1	14	.	.	PROPN
ajst-3866	2	1	4	4	NUM
ajst-3866	2	2	,	,	PUNCT
ajst-3866	2	3	no	no	INTJ
ajst-3866	2	4	.	.	NOUN
ajst-3866	2	5	2	2	NUM
ajst-3866	2	6	,	,	PUNCT
ajst-3866	2	7	2022	2022	NUM
ajst-3866	2	8	5	5	NUM
ajst-3866	2	9	advances	advance	NOUN
ajst-3866	2	10	in	in	ADP
ajst-3866	2	11	the	the	DET
ajst-3866	2	12	synthesis	synthesis	NOUN
ajst-3866	2	13	of	of	ADP
ajst-3866	2	14	benzoazole	benzoazole	NOUN
ajst-3866	2	15	compounds	compound	VERB
ajst-3866	2	16	wenjuan	wenjuan	PROPN
ajst-3866	2	17	li	li	PROPN
ajst-3866	2	18	*	*	PROPN
ajst-3866	2	19	,	,	PUNCT
ajst-3866	2	20	fengying	fengye	VERB
ajst-3866	2	21	wang	wang	PROPN
ajst-3866	2	22	jining	jine	VERB
ajst-3866	2	23	normal	normal	ADJ
ajst-3866	2	24	college	college	NOUN
ajst-3866	2	25	,	,	PUNCT
ajst-3866	2	26	ulanqab	ulanqab	NOUN
ajst-3866	2	27	,	,	PUNCT
ajst-3866	2	28	inner	inner	PROPN
ajst-3866	2	29	mongolia	mongolia	PROPN
ajst-3866	2	30	012000	012000	NUM
ajst-3866	2	31	,	,	PUNCT
ajst-3866	2	32	china	china	PROPN
ajst-3866	2	33	abstract	abstract	NOUN
ajst-3866	2	34	:	:	PUNCT
ajst-3866	2	35	benzozole	benzozole	ADJ
ajst-3866	2	36	compounds	compound	NOUN
ajst-3866	2	37	are	be	AUX
ajst-3866	2	38	a	a	DET
ajst-3866	2	39	kind	kind	NOUN
ajst-3866	2	40	of	of	ADP
ajst-3866	2	41	nitrogen	nitrogen	NOUN
ajst-3866	2	42	-	-	PUNCT
ajst-3866	2	43	containing	contain	VERB
ajst-3866	2	44	heterocyclic	heterocyclic	ADJ
ajst-3866	2	45	compounds	compound	NOUN
ajst-3866	2	46	,	,	PUNCT
ajst-3866	2	47	which	which	PRON
ajst-3866	2	48	are	be	AUX
ajst-3866	2	49	widely	widely	ADV
ajst-3866	2	50	used	use	VERB
ajst-3866	2	51	in	in	ADP
ajst-3866	2	52	medicine	medicine	NOUN
ajst-3866	2	53	and	and	CCONJ
ajst-3866	2	54	materials	material	NOUN
ajst-3866	2	55	,	,	PUNCT
ajst-3866	2	56	and	and	CCONJ
ajst-3866	2	57	can	can	AUX
ajst-3866	2	58	also	also	ADV
ajst-3866	2	59	be	be	AUX
ajst-3866	2	60	used	use	VERB
ajst-3866	2	61	as	as	ADP
ajst-3866	2	62	an	an	DET
ajst-3866	2	63	important	important	ADJ
ajst-3866	2	64	intermediate	intermediate	NOUN
ajst-3866	2	65	to	to	PART
ajst-3866	2	66	prepare	prepare	VERB
ajst-3866	2	67	high	high	ADJ
ajst-3866	2	68	molecular	molecular	ADJ
ajst-3866	2	69	compounds	compound	NOUN
ajst-3866	2	70	.	.	PUNCT
ajst-3866	3	1	in	in	ADP
ajst-3866	3	2	this	this	DET
ajst-3866	3	3	paper	paper	NOUN
ajst-3866	3	4	,	,	PUNCT
ajst-3866	3	5	the	the	DET
ajst-3866	3	6	existing	exist	VERB
ajst-3866	3	7	synthesis	synthesis	NOUN
ajst-3866	3	8	methods	method	NOUN
ajst-3866	3	9	of	of	ADP
ajst-3866	3	10	benzozozole	benzozozole	NOUN
ajst-3866	3	11	compounds	compound	NOUN
ajst-3866	3	12	are	be	AUX
ajst-3866	3	13	summarized	summarize	VERB
ajst-3866	3	14	,	,	PUNCT
ajst-3866	3	15	according	accord	VERB
ajst-3866	3	16	to	to	ADP
ajst-3866	3	17	the	the	DET
ajst-3866	3	18	reaction	reaction	NOUN
ajst-3866	3	19	mechanism	mechanism	NOUN
ajst-3866	3	20	,	,	PUNCT
ajst-3866	3	21	which	which	PRON
ajst-3866	3	22	lays	lay	VERB
ajst-3866	3	23	a	a	DET
ajst-3866	3	24	foundation	foundation	NOUN
ajst-3866	3	25	for	for	ADP
ajst-3866	3	26	the	the	DET
ajst-3866	3	27	establishment	establishment	NOUN
ajst-3866	3	28	of	of	ADP
ajst-3866	3	29	a	a	DET
ajst-3866	3	30	greener	green	ADJ
ajst-3866	3	31	,	,	PUNCT
ajst-3866	3	32	more	more	ADV
ajst-3866	3	33	economical	economical	ADJ
ajst-3866	3	34	and	and	CCONJ
ajst-3866	3	35	more	more	ADV
ajst-3866	3	36	convenient	convenient	ADJ
ajst-3866	3	37	synthesis	synthesis	NOUN
ajst-3866	3	38	method	method	NOUN
ajst-3866	3	39	in	in	ADP
ajst-3866	3	40	the	the	DET
ajst-3866	3	41	future	future	NOUN
ajst-3866	3	42	.	.	PUNCT
ajst-3866	4	1	keywords	keyword	NOUN
ajst-3866	4	2	:	:	PUNCT
ajst-3866	4	3	benzimidazole	benzimidazole	NOUN
ajst-3866	4	4	,	,	PUNCT
ajst-3866	4	5	benzoxazole	benzoxazole	PROPN
ajst-3866	4	6	,	,	PUNCT
ajst-3866	4	7	benzimidazole	benzimidazole	NOUN
ajst-3866	4	8	,	,	PUNCT
ajst-3866	4	9	synthesis	synthesis	NOUN
ajst-3866	4	10	,	,	PUNCT
ajst-3866	4	11	reaction	reaction	NOUN
ajst-3866	4	12	mechanism	mechanism	NOUN
ajst-3866	4	13	.	.	PUNCT
ajst-3866	5	1	1	1	X
ajst-3866	5	2	.	.	X
ajst-3866	5	3	introduction	introduction	NOUN
ajst-3866	5	4	benzimidazole	benzimidazole	PROPN
ajst-3866	5	5	,	,	PUNCT
ajst-3866	5	6	benzothiazole	benzothiazole	NOUN
ajst-3866	5	7	,	,	PUNCT
ajst-3866	5	8	benzoxazole	benzoxazole	NOUN
ajst-3866	5	9	and	and	CCONJ
ajst-3866	5	10	other	other	ADJ
ajst-3866	5	11	benzoazole	benzoazole	NOUN
ajst-3866	5	12	derivatives	derivative	NOUN
ajst-3866	5	13	are	be	AUX
ajst-3866	5	14	common	common	ADJ
ajst-3866	5	15	nitrogenous	nitrogenous	ADJ
ajst-3866	5	16	heterocyclic	heterocyclic	ADJ
ajst-3866	5	17	compounds	compound	NOUN
ajst-3866	5	18	,	,	PUNCT
ajst-3866	5	19	which	which	PRON
ajst-3866	5	20	are	be	AUX
ajst-3866	5	21	characterized	characterize	VERB
ajst-3866	5	22	by	by	ADP
ajst-3866	5	23	good	good	ADJ
ajst-3866	5	24	biocompatibility	biocompatibility	NOUN
ajst-3866	5	25	and	and	CCONJ
ajst-3866	5	26	biodiversity	biodiversity	NOUN
ajst-3866	5	27	,	,	PUNCT
ajst-3866	5	28	complex	complex	ADJ
ajst-3866	5	29	and	and	CCONJ
ajst-3866	5	30	variable	variable	ADJ
ajst-3866	5	31	structure	structure	NOUN
ajst-3866	5	32	,	,	PUNCT
ajst-3866	5	33	low	low	ADJ
ajst-3866	5	34	toxicity	toxicity	NOUN
ajst-3866	5	35	,	,	PUNCT
ajst-3866	5	36	and	and	CCONJ
ajst-3866	5	37	are	be	AUX
ajst-3866	5	38	often	often	ADV
ajst-3866	5	39	used	use	VERB
ajst-3866	5	40	as	as	ADP
ajst-3866	5	41	important	important	ADJ
ajst-3866	5	42	"	"	PUNCT
ajst-3866	5	43	pharmacophore	pharmacophore	NOUN
ajst-3866	5	44	"	"	PUNCT
ajst-3866	5	45	in	in	ADP
ajst-3866	5	46	drugs	drug	NOUN
ajst-3866	5	47	.	.	PUNCT
ajst-3866	6	1	benzazole	benzazole	NOUN
ajst-3866	6	2	structures	structure	NOUN
ajst-3866	6	3	are	be	AUX
ajst-3866	6	4	widely	widely	ADV
ajst-3866	6	5	used	use	VERB
ajst-3866	6	6	in	in	ADP
ajst-3866	6	7	medicine	medicine	NOUN
ajst-3866	6	8	as	as	ADP
ajst-3866	6	9	antiviral	antiviral	ADJ
ajst-3866	6	10	,	,	PUNCT
ajst-3866	6	11	antibacterial	antibacterial	ADJ
ajst-3866	6	12	,	,	PUNCT
ajst-3866	6	13	anticancer	anticancer	NOUN
ajst-3866	6	14	,	,	PUNCT
ajst-3866	6	15	antihistamine	antihistamine	NOUN
ajst-3866	6	16	,	,	PUNCT
ajst-3866	6	17	anti	anti	ADJ
ajst-3866	6	18	-	-	ADJ
ajst-3866	6	19	tuberculosis	tuberculosis	ADJ
ajst-3866	6	20	,	,	PUNCT
ajst-3866	6	21	anti	anti	ADJ
ajst-3866	6	22	-	-	NOUN
ajst-3866	6	23	hypertension	hypertension	NOUN
ajst-3866	6	24	,	,	PUNCT
ajst-3866	6	25	anti	anti	X
ajst-3866	6	26	inflammatory	inflammatory	ADJ
ajst-3866	6	27	and	and	CCONJ
ajst-3866	6	28	plant	plant	NOUN
ajst-3866	6	29	growth	growth	NOUN
ajst-3866	6	30	regulators	regulator	NOUN
ajst-3866	6	31	.	.	PUNCT
ajst-3866	7	1	because	because	SCONJ
ajst-3866	7	2	of	of	ADP
ajst-3866	7	3	their	their	PRON
ajst-3866	7	4	wide	wide	ADJ
ajst-3866	7	5	application	application	NOUN
ajst-3866	7	6	prospect	prospect	NOUN
ajst-3866	7	7	,	,	PUNCT
ajst-3866	7	8	the	the	DET
ajst-3866	7	9	research	research	NOUN
ajst-3866	7	10	and	and	CCONJ
ajst-3866	7	11	development	development	NOUN
ajst-3866	7	12	of	of	ADP
ajst-3866	7	13	benzazole	benzazole	NOUN
ajst-3866	7	14	compounds	compound	NOUN
ajst-3866	7	15	has	have	AUX
ajst-3866	7	16	been	be	AUX
ajst-3866	7	17	widely	widely	ADV
ajst-3866	7	18	concerned.[1]the	concerned.[1]the	ADJ
ajst-3866	7	19	synthesis	synthesis	NOUN
ajst-3866	7	20	method	method	NOUN
ajst-3866	7	21	is	be	AUX
ajst-3866	7	22	particularly	particularly	ADV
ajst-3866	7	23	important	important	ADJ
ajst-3866	7	24	.	.	PUNCT
ajst-3866	8	1	n	n	NOUN
ajst-3866	8	2	x	x	SYM
ajst-3866	8	3	hr1	hr1	PROPN
ajst-3866	8	4	x	x	PROPN
ajst-3866	8	5	=	=	PROPN
ajst-3866	8	6	nh	nh	PROPN
ajst-3866	8	7	,	,	PUNCT
ajst-3866	8	8	s	s	PROPN
ajst-3866	8	9	,	,	PUNCT
ajst-3866	8	10	o	o	PROPN
ajst-3866	8	11	n	n	CCONJ
ajst-3866	8	12	n	n	PRON
ajst-3866	8	13	me	i	PRON
ajst-3866	8	14	n	n	CCONJ
ajst-3866	8	15	n	n	ADV
ajst-3866	8	16	me	i	PRON
ajst-3866	8	17	n	n	ADV
ajst-3866	8	18	-	-	PUNCT
ajst-3866	8	19	pr	pr	NOUN
ajst-3866	8	20	hooc	hooc	ADV
ajst-3866	8	21	hn	hn	PROPN
ajst-3866	8	22	n	n	ADV
ajst-3866	8	23	o	o	VERB
ajst-3866	8	24	me	i	PRON
ajst-3866	8	25	n	n	PRON
ajst-3866	8	26	h	h	NOUN
ajst-3866	9	1	n	n	ADP
ajst-3866	9	2	ome	ome	PROPN
ajst-3866	9	3	n	n	ADP
ajst-3866	9	4	me	i	PRON
ajst-3866	9	5	n	n	PRON
ajst-3866	9	6	cl	cl	NOUN
ajst-3866	9	7	cl	cl	NOUN
ajst-3866	10	1	oh	oh	INTJ
ajst-3866	10	2	o	o	X
ajst-3866	10	3	meo	meo	NOUN
ajst-3866	11	1	n	n	ADP
ajst-3866	11	2	h	h	NOUN
ajst-3866	11	3	n	n	NOUN
ajst-3866	11	4	s	s	PART
ajst-3866	11	5	o	o	PROPN
ajst-3866	11	6	n	n	PRON
ajst-3866	11	7	ome	ome	PROPN
ajst-3866	11	8	f3c	f3c	NOUN
ajst-3866	11	9	s	s	PART
ajst-3866	11	10	n	n	CCONJ
ajst-3866	11	11	n	n	CCONJ
ajst-3866	11	12	n	n	NOUN
ajst-3866	11	13	o	o	NOUN
ajst-3866	11	14	co2h	co2h	PROPN
ajst-3866	11	15	bendamustine	bendamustine	NOUN
ajst-3866	11	16	antileukemia	antileukemia	NOUN
ajst-3866	11	17	drug	drug	NOUN
ajst-3866	11	18	zopolrestat	zopolrestat	NOUN
ajst-3866	11	19	antidiabetes	antidiabete	VERB
ajst-3866	11	20	drug	drug	NOUN
ajst-3866	11	21	pimobendan	pimobendan	PROPN
ajst-3866	11	22	calcium	calcium	NOUN
ajst-3866	11	23	-	-	PUNCT
ajst-3866	11	24	sensitizer	sensitizer	NOUN
ajst-3866	11	25	drug	drug	NOUN
ajst-3866	11	26	micardis	micardis	PROPN
ajst-3866	11	27	antihypertention	antihypertention	PROPN
ajst-3866	11	28	drug	drug	PROPN
ajst-3866	11	29	omeprazole	omeprazole	ADJ
ajst-3866	11	30	antiulcer	antiulcer	NOUN
ajst-3866	11	31	drug	drug	NOUN
ajst-3866	11	32	figure	figure	NOUN
ajst-3866	11	33	1	1	NUM
ajst-3866	11	34	.	.	PUNCT
ajst-3866	11	35	representative	representative	ADJ
ajst-3866	11	36	drugs	drug	NOUN
ajst-3866	11	37	containing	contain	VERB
ajst-3866	11	38	benzoazole	benzoazole	NOUN
ajst-3866	11	39	skeletons	skeleton	NOUN
ajst-3866	11	40	2	2	NUM
ajst-3866	11	41	.	.	X
ajst-3866	11	42	review	review	NOUN
ajst-3866	11	43	of	of	ADP
ajst-3866	11	44	synthesis	synthesis	NOUN
ajst-3866	11	45	methods	method	NOUN
ajst-3866	11	46	of	of	ADP
ajst-3866	11	47	benzazole	benzazole	NOUN
ajst-3866	11	48	compounds	compound	VERB
ajst-3866	11	49	in1872	in1872	PROPN
ajst-3866	11	50	,	,	PUNCT
ajst-3866	11	51	hoebrecker	hoebrecker	PROPN
ajst-3866	11	52	first	first	ADV
ajst-3866	11	53	synthesized	synthesize	VERB
ajst-3866	11	54	the	the	DET
ajst-3866	11	55	2,5	2,5	NUM
ajst-3866	11	56	-	-	PUNCT
ajst-3866	11	57	dimethyl	dimethyl	NOUN
ajst-3866	11	58	benzimidazole.they	benzimidazole.they	PRON
ajst-3866	11	59	pioneered	pioneer	VERB
ajst-3866	11	60	the	the	DET
ajst-3866	11	61	synthesis	synthesis	NOUN
ajst-3866	11	62	method	method	NOUN
ajst-3866	11	63	of	of	ADP
ajst-3866	11	64	benzimidazole	benzimidazole	NOUN
ajst-3866	11	65	although	although	SCONJ
ajst-3866	11	66	the	the	DET
ajst-3866	11	67	yield	yield	NOUN
ajst-3866	11	68	of	of	ADP
ajst-3866	11	69	this	this	DET
ajst-3866	11	70	reaction	reaction	NOUN
ajst-3866	11	71	was	be	AUX
ajst-3866	11	72	not	not	PART
ajst-3866	11	73	high	high	ADJ
ajst-3866	11	74	.	.	PUNCT
ajst-3866	12	1	in	in	ADP
ajst-3866	12	2	1875	1875	NUM
ajst-3866	12	3	,	,	PUNCT
ajst-3866	12	4	the	the	DET
ajst-3866	12	5	ladenburg	ladenburg	PROPN
ajst-3866	12	6	research	research	NOUN
ajst-3866	12	7	group[2]studied	group[2]studie	VERB
ajst-3866	12	8	the	the	DET
ajst-3866	12	9	synthesis	synthesis	NOUN
ajst-3866	12	10	reaction	reaction	NOUN
ajst-3866	12	11	of	of	ADP
ajst-3866	12	12	4	4	NUM
ajst-3866	12	13	-	-	PUNCT
ajst-3866	12	14	methyl	methyl	NOUN
ajst-3866	12	15	-	-	PUNCT
ajst-3866	12	16	o	o	NOUN
ajst-3866	12	17	-	-	NOUN
ajst-3866	12	18	phenylenediamine	phenylenediamine	NOUN
ajst-3866	12	19	and	and	CCONJ
ajst-3866	12	20	acetic	acetic	ADJ
ajst-3866	12	21	acid	acid	NOUN
ajst-3866	12	22	under	under	ADP
ajst-3866	12	23	reflux	reflux	NOUN
ajst-3866	12	24	heating	heating	NOUN
ajst-3866	12	25	,	,	PUNCT
ajst-3866	12	26	and	and	CCONJ
ajst-3866	12	27	the	the	DET
ajst-3866	12	28	product	product	NOUN
ajst-3866	12	29	was	be	AUX
ajst-3866	12	30	benzimidazole	benzimidazole	ADJ
ajst-3866	12	31	.	.	PUNCT
ajst-3866	13	1	so	so	ADV
ajst-3866	13	2	far	far	ADV
ajst-3866	13	3	,	,	PUNCT
ajst-3866	13	4	the	the	DET
ajst-3866	13	5	reaction	reaction	NOUN
ajst-3866	13	6	of	of	ADP
ajst-3866	13	7	o	o	NOUN
ajst-3866	13	8	-	-	NOUN
ajst-3866	13	9	phenylenediamine	phenylenediamine	NOUN
ajst-3866	13	10	and	and	CCONJ
ajst-3866	13	11	its	its	PRON
ajst-3866	13	12	derivatives	derivative	NOUN
ajst-3866	13	13	with	with	ADP
ajst-3866	13	14	strong	strong	ADJ
ajst-3866	13	15	acids	acid	NOUN
ajst-3866	13	16	(	(	PUNCT
ajst-3866	13	17	such	such	ADJ
ajst-3866	13	18	as	as	ADP
ajst-3866	13	19	hcl	hcl	PROPN
ajst-3866	13	20	,	,	PUNCT
ajst-3866	13	21	polyphosphoric	polyphosphoric	ADJ
ajst-3866	13	22	acid	acid	PROPN
ajst-3866	13	23	ppa	ppa	PROPN
ajst-3866	13	24	,	,	PUNCT
ajst-3866	13	25	p	p	ADJ
ajst-3866	13	26	-	-	PUNCT
ajst-3866	13	27	toluenesulfonic	toluenesulfonic	ADJ
ajst-3866	13	28	acid	acid	NOUN
ajst-3866	13	29	,	,	PUNCT
ajst-3866	13	30	mixed	mixed	ADJ
ajst-3866	13	31	acid	acid	NOUN
ajst-3866	13	32	,	,	PUNCT
ajst-3866	13	33	etc	etc	X
ajst-3866	13	34	.	.	X
ajst-3866	13	35	)	)	PUNCT
ajst-3866	14	1	at	at	ADP
ajst-3866	14	2	high	high	ADJ
ajst-3866	14	3	temperature	temperature	NOUN
ajst-3866	14	4	has	have	AUX
ajst-3866	14	5	become	become	VERB
ajst-3866	14	6	a	a	DET
ajst-3866	14	7	classic	classic	ADJ
ajst-3866	14	8	preparation	preparation	NOUN
ajst-3866	14	9	method	method	NOUN
ajst-3866	14	10	of	of	ADP
ajst-3866	14	11	benzimidazole	benzimidazole	PROPN
ajst-3866	14	12	compounds	compound	NOUN
ajst-3866	14	13	,	,	PUNCT
ajst-3866	14	14	but	but	CCONJ
ajst-3866	14	15	the	the	DET
ajst-3866	14	16	reaction	reaction	NOUN
ajst-3866	14	17	conditions	condition	NOUN
ajst-3866	14	18	are	be	AUX
ajst-3866	14	19	harsh	harsh	ADJ
ajst-3866	14	20	and	and	CCONJ
ajst-3866	14	21	the	the	DET
ajst-3866	14	22	reaction	reaction	NOUN
ajst-3866	14	23	time	time	NOUN
ajst-3866	14	24	is	be	AUX
ajst-3866	14	25	long	long	ADJ
ajst-3866	14	26	.	.	PUNCT
ajst-3866	15	1	h3c	h3c	VERB
ajst-3866	15	2	no2	no2	PROPN
ajst-3866	15	3	nhcoch3	nhcoch3	PROPN
ajst-3866	15	4	sn	sn	PROPN
ajst-3866	15	5	hcl	hcl	PROPN
ajst-3866	15	6	h3c	h3c	VERB
ajst-3866	15	7	nh2	nh2	PROPN
ajst-3866	15	8	nhcoch3	nhcoch3	PROPN
ajst-3866	15	9	h2o	h2o	PROPN
ajst-3866	15	10	h3c	h3c	VERB
ajst-3866	15	11	n	n	CCONJ
ajst-3866	15	12	h	h	NOUN
ajst-3866	15	13	n	n	PROPN
ajst-3866	15	14	ch3	ch3	PROPN
ajst-3866	15	15	figure	figure	NOUN
ajst-3866	15	16	2	2	NUM
ajst-3866	15	17	.	.	PUNCT
ajst-3866	16	1	the	the	DET
ajst-3866	16	2	synthesis	synthesis	NOUN
ajst-3866	16	3	method	method	NOUN
ajst-3866	16	4	of	of	ADP
ajst-3866	16	5	2,5	2,5	NUM
ajst-3866	16	6	-	-	PUNCT
ajst-3866	16	7	dimethyl	dimethyl	NOUN
ajst-3866	16	8	benzimidazole	benzimidazole	NOUN
ajst-3866	16	9	in	in	ADP
ajst-3866	16	10	1886	1886	NUM
ajst-3866	16	11	,	,	PUNCT
ajst-3866	16	12	jacobson	jacobson	PROPN
ajst-3866	16	13	et	et	PROPN
ajst-3866	16	14	al	al	PROPN
ajst-3866	16	15	.	.	PUNCT
ajst-3866	17	1	[	[	X
ajst-3866	17	2	3	3	NUM
ajst-3866	17	3	]	]	PUNCT
ajst-3866	17	4	first	first	ADV
ajst-3866	17	5	synthesized	synthesize	VERB
ajst-3866	17	6	benzothiazole	benzothiazole	NOUN
ajst-3866	17	7	with	with	ADP
ajst-3866	17	8	n	n	NOUN
ajst-3866	17	9	-	-	PUNCT
ajst-3866	17	10	phenylthiobenzamide	phenylthiobenzamide	NOUN
ajst-3866	17	11	as	as	ADP
ajst-3866	17	12	raw	raw	ADJ
ajst-3866	17	13	material	material	NOUN
ajst-3866	17	14	under	under	ADP
ajst-3866	17	15	the	the	DET
ajst-3866	17	16	action	action	NOUN
ajst-3866	17	17	of	of	ADP
ajst-3866	17	18	potassium	potassium	NOUN
ajst-3866	17	19	hexacyanoferrate	hexacyanoferrate	ADJ
ajst-3866	17	20	(	(	PUNCT
ajst-3866	17	21	iii	iii	NOUN
ajst-3866	17	22	)	)	PUNCT
ajst-3866	17	23	and	and	CCONJ
ajst-3866	17	24	sodium	sodium	NOUN
ajst-3866	17	25	hydroxide	hydroxide	NOUN
ajst-3866	17	26	,	,	PUNCT
ajst-3866	17	27	and	and	CCONJ
ajst-3866	17	28	established	establish	VERB
ajst-3866	17	29	jacobson	jacobson	PROPN
ajst-3866	17	30	's	's	PART
ajst-3866	17	31	ring	ring	NOUN
ajst-3866	17	32	method	method	NOUN
ajst-3866	17	33	(	(	PUNCT
ajst-3866	17	34	fig	fig	NOUN
ajst-3866	17	35	.	.	PUNCT
ajst-3866	18	1	3	3	NUM
ajst-3866	18	2	)	)	PUNCT
ajst-3866	18	3	.	.	PUNCT
ajst-3866	19	1	jacobson	jacobson	PROPN
ajst-3866	19	2	uses	use	VERB
ajst-3866	19	3	liquid	liquid	ADJ
ajst-3866	19	4	bromine	bromine	NOUN
ajst-3866	19	5	as	as	ADP
ajst-3866	19	6	oxidant	oxidant	NOUN
ajst-3866	19	7	to	to	PART
ajst-3866	19	8	oxidize	oxidize	VERB
ajst-3866	19	9	thioamide	thioamide	ADV
ajst-3866	19	10	to	to	PART
ajst-3866	19	11	prepare	prepare	VERB
ajst-3866	19	12	benzothiazole	benzothiazole	NOUN
ajst-3866	19	13	.	.	PUNCT
ajst-3866	20	1	because	because	SCONJ
ajst-3866	20	2	it	it	PRON
ajst-3866	20	3	is	be	AUX
ajst-3866	20	4	difficult	difficult	ADJ
ajst-3866	20	5	to	to	PART
ajst-3866	20	6	determine	determine	VERB
ajst-3866	20	7	the	the	DET
ajst-3866	20	8	amount	amount	NOUN
ajst-3866	20	9	of	of	ADP
ajst-3866	20	10	substances	substance	NOUN
ajst-3866	20	11	involved	involve	VERB
ajst-3866	20	12	in	in	ADP
ajst-3866	20	13	the	the	DET
ajst-3866	20	14	reaction	reaction	NOUN
ajst-3866	20	15	with	with	ADP
ajst-3866	20	16	liquid	liquid	ADJ
ajst-3866	20	17	bromine	bromine	NOUN
ajst-3866	20	18	,	,	PUNCT
ajst-3866	20	19	by	by	ADP
ajst-3866	20	20	-	-	PUNCT
ajst-3866	20	21	products	product	NOUN
ajst-3866	20	22	are	be	AUX
ajst-3866	20	23	often	often	ADV
ajst-3866	20	24	generated	generate	VERB
ajst-3866	20	25	,	,	PUNCT
ajst-3866	20	26	and	and	CCONJ
ajst-3866	20	27	liquid	liquid	ADJ
ajst-3866	20	28	bromine	bromine	NOUN
ajst-3866	20	29	is	be	AUX
ajst-3866	20	30	highly	highly	ADV
ajst-3866	20	31	corrosive	corrosive	ADJ
ajst-3866	20	32	and	and	CCONJ
ajst-3866	20	33	toxic	toxic	ADJ
ajst-3866	20	34	,	,	PUNCT
ajst-3866	20	35	it	it	PRON
ajst-3866	20	36	does	do	AUX
ajst-3866	20	37	not	not	PART
ajst-3866	20	38	meet	meet	VERB
ajst-3866	20	39	the	the	DET
ajst-3866	20	40	economic	economic	ADJ
ajst-3866	20	41	and	and	CCONJ
ajst-3866	20	42	environmental	environmental	ADJ
ajst-3866	20	43	requirements	requirement	NOUN
ajst-3866	20	44	of	of	ADP
ajst-3866	20	45	green	green	ADJ
ajst-3866	20	46	chemistry	chemistry	NOUN
ajst-3866	20	47	.	.	PUNCT
ajst-3866	21	1	nh	nh	PROPN
ajst-3866	21	2	s	s	PART
ajst-3866	21	3	r	r	PROPN
ajst-3866	21	4	k3fe(cn)6	k3fe(cn)6	PROPN
ajst-3866	21	5	naoh	naoh	NOUN
ajst-3866	21	6	n	n	PROPN
ajst-3866	21	7	s	s	PART
ajst-3866	21	8	figure	figure	NOUN
ajst-3866	21	9	3	3	X
ajst-3866	21	10	.	.	PUNCT
ajst-3866	22	1	the	the	DET
ajst-3866	22	2	synthesis	synthesis	NOUN
ajst-3866	22	3	of	of	ADP
ajst-3866	22	4	benzothiazole	benzothiazole	NOUN
ajst-3866	22	5	by	by	ADP
ajst-3866	22	6	n	n	CCONJ
ajst-3866	22	7	-	-	PUNCT
ajst-3866	22	8	pheny	pheny	NOUN
ajst-3866	22	9	lthiophenylformamide	lthiophenylformamide	NOUN
ajst-3866	22	10	since	since	SCONJ
ajst-3866	22	11	there	there	PRON
ajst-3866	22	12	is	be	VERB
ajst-3866	22	13	a	a	DET
ajst-3866	22	14	method	method	NOUN
ajst-3866	22	15	to	to	PART
ajst-3866	22	16	synthesize	synthesize	VERB
ajst-3866	22	17	benzimidazole	benzimidazole	NOUN
ajst-3866	22	18	and	and	CCONJ
ajst-3866	22	19	benzothiazole	benzothiazole	NOUN
ajst-3866	22	20	,	,	PUNCT
ajst-3866	22	21	the	the	DET
ajst-3866	22	22	synthesis	synthesis	NOUN
ajst-3866	22	23	of	of	ADP
ajst-3866	22	24	these	these	DET
ajst-3866	22	25	compounds	compound	NOUN
ajst-3866	22	26	has	have	AUX
ajst-3866	22	27	become	become	VERB
ajst-3866	22	28	a	a	DET
ajst-3866	22	29	hot	hot	ADJ
ajst-3866	22	30	spot	spot	NOUN
ajst-3866	22	31	in	in	ADP
ajst-3866	22	32	organic	organic	ADJ
ajst-3866	22	33	synthesis	synthesis	NOUN
ajst-3866	22	34	.	.	PUNCT
ajst-3866	23	1	chemists	chemist	NOUN
ajst-3866	23	2	have	have	AUX
ajst-3866	23	3	been	be	AUX
ajst-3866	23	4	trying	try	VERB
ajst-3866	23	5	to	to	PART
ajst-3866	23	6	find	find	VERB
ajst-3866	23	7	a	a	DET
ajst-3866	23	8	more	more	ADV
ajst-3866	23	9	economical	economical	ADJ
ajst-3866	23	10	,	,	PUNCT
ajst-3866	23	11	efficient	efficient	ADJ
ajst-3866	23	12	and	and	CCONJ
ajst-3866	23	13	green	green	ADJ
ajst-3866	23	14	synthesis	synthesis	NOUN
ajst-3866	23	15	method	method	NOUN
ajst-3866	23	16	.	.	PUNCT
ajst-3866	24	1	according	accord	VERB
ajst-3866	24	2	to	to	ADP
ajst-3866	24	3	literature	literature	PROPN
ajst-3866	24	4	review	review	PROPN
ajst-3866	24	5	,	,	PUNCT
ajst-3866	24	6	the	the	DET
ajst-3866	24	7	synthesis	synthesis	NOUN
ajst-3866	24	8	methods	method	NOUN
ajst-3866	24	9	of	of	ADP
ajst-3866	24	10	benzozole	benzozole	ADJ
ajst-3866	24	11	compounds	compound	NOUN
ajst-3866	24	12	are	be	AUX
ajst-3866	24	13	mainly	mainly	ADV
ajst-3866	24	14	as	as	SCONJ
ajst-3866	24	15	follows	follow	VERB
ajst-3866	24	16	:	:	PUNCT
ajst-3866	24	17	first	first	ADV
ajst-3866	24	18	,	,	PUNCT
ajst-3866	24	19	aniline	aniline	NOUN
ajst-3866	24	20	substituted	substitute	VERB
ajst-3866	24	21	by	by	ADP
ajst-3866	24	22	o	o	NOUN
ajst-3866	24	23	-	-	NOUN
ajst-3866	24	24	amino	amino	ADJ
ajst-3866	24	25	,	,	PUNCT
ajst-3866	24	26	o	o	NOUN
ajst-3866	24	27	-	-	PUNCT
ajst-3866	24	28	mercapto	mercapto	NOUN
ajst-3866	24	29	and	and	CCONJ
ajst-3866	24	30	o	o	NOUN
ajst-3866	24	31	-	-	ADJ
ajst-3866	24	32	hydroxy	hydroxy	ADJ
ajst-3866	24	33	is	be	AUX
ajst-3866	24	34	prepared	prepare	VERB
ajst-3866	24	35	by	by	ADP
ajst-3866	24	36	condensation	condensation	NOUN
ajst-3866	24	37	reaction	reaction	NOUN
ajst-3866	24	38	with	with	ADP
ajst-3866	24	39	carboxylic	carboxylic	ADJ
ajst-3866	24	40	acid	acid	NOUN
ajst-3866	24	41	,	,	PUNCT
ajst-3866	24	42	nitrile	nitrile	NOUN
ajst-3866	24	43	and	and	CCONJ
ajst-3866	24	44	ester	ester	NOUN
ajst-3866	24	45	,	,	PUNCT
ajst-3866	24	46	which	which	PRON
ajst-3866	24	47	generally	generally	ADV
ajst-3866	24	48	needs	need	VERB
ajst-3866	24	49	to	to	PART
ajst-3866	24	50	be	be	AUX
ajst-3866	24	51	carried	carry	VERB
ajst-3866	24	52	out	out	ADP
ajst-3866	24	53	under	under	ADP
ajst-3866	24	54	strong	strong	ADJ
ajst-3866	24	55	acid	acid	NOUN
ajst-3866	24	56	and	and	CCONJ
ajst-3866	24	57	high	high	ADJ
ajst-3866	24	58	temperature	temperature	NOUN
ajst-3866	24	59	conditions	condition	NOUN
ajst-3866	24	60	;	;	PUNCT
ajst-3866	24	61	second	second	X
ajst-3866	24	62	,	,	PUNCT
ajst-3866	24	63	aniline	aniline	NOUN
ajst-3866	24	64	substituted	substitute	VERB
ajst-3866	24	65	by	by	ADP
ajst-3866	24	66	o	o	NOUN
ajst-3866	24	67	-	-	ADJ
ajst-3866	24	68	amino	amino	ADJ
ajst-3866	24	69	group	group	NOUN
ajst-3866	24	70	,	,	PUNCT
ajst-3866	24	71	o	o	ADJ
ajst-3866	24	72	-	-	PUNCT
ajst-3866	24	73	mercapto	mercapto	VERB
ajst-3866	24	74	group	group	NOUN
ajst-3866	24	75	and	and	CCONJ
ajst-3866	24	76	ohydroxyl	ohydroxyl	PROPN
ajst-3866	24	77	group	group	NOUN
ajst-3866	24	78	is	be	AUX
ajst-3866	24	79	prepared	prepare	VERB
ajst-3866	24	80	by	by	ADP
ajst-3866	24	81	oxidative	oxidative	ADJ
ajst-3866	24	82	cyclization	cyclization	NOUN
ajst-3866	24	83	reaction	reaction	NOUN
ajst-3866	24	84	with	with	ADP
ajst-3866	24	85	aldehyde	aldehyde	NOUN
ajst-3866	24	86	or	or	CCONJ
ajst-3866	24	87	alcohol	alcohol	NOUN
ajst-3866	24	88	,	,	PUNCT
ajst-3866	24	89	which	which	PRON
ajst-3866	24	90	requires	require	VERB
ajst-3866	24	91	stoichiometric	stoichiometric	ADJ
ajst-3866	24	92	oxidant	oxidant	NOUN
ajst-3866	24	93	;	;	PUNCT
ajst-3866	24	94	the	the	DET
ajst-3866	24	95	third	third	NOUN
ajst-3866	24	96	is	be	AUX
ajst-3866	24	97	the	the	DET
ajst-3866	24	98	method	method	NOUN
ajst-3866	24	99	of	of	ADP
ajst-3866	24	100	synthesizing	synthesize	VERB
ajst-3866	24	101	benzimidazole	benzimidazole	NOUN
ajst-3866	24	102	by	by	ADP
ajst-3866	24	103	reaction	reaction	NOUN
ajst-3866	24	104	of	of	ADP
ajst-3866	24	105	n	n	CCONJ
ajst-3866	24	106	,	,	PUNCT
ajst-3866	24	107	n	n	CCONJ
ajst-3866	24	108	-	-	PUNCT
ajst-3866	24	109	dimethylformamide	dimethylformamide	NOUN
ajst-3866	24	110	(	(	PUNCT
ajst-3866	24	111	dmf	dmf	PROPN
ajst-3866	24	112	)	)	PUNCT
ajst-3866	24	113	with	with	ADP
ajst-3866	24	114	o	o	NOUN
ajst-3866	24	115	-	-	NOUN
ajst-3866	24	116	mercapto	mercapto	ADJ
ajst-3866	24	117	,	,	PUNCT
ajst-3866	24	118	o	o	NOUN
ajst-3866	24	119	-	-	NOUN
ajst-3866	24	120	hydroxy	hydroxy	ADJ
ajst-3866	24	121	and	and	CCONJ
ajst-3866	24	122	o	o	ADJ
ajst-3866	24	123	-	-	ADJ
ajst-3866	24	124	amino	amino	ADJ
ajst-3866	24	125	substituted	substitute	VERB
ajst-3866	24	126	aniline	aniline	NOUN
ajst-3866	24	127	reported	report	VERB
ajst-3866	24	128	in	in	ADP
ajst-3866	24	129	recent	recent	ADJ
ajst-3866	24	130	years	year	NOUN
ajst-3866	24	131	.	.	PUNCT
ajst-3866	25	1	this	this	DET
ajst-3866	25	2	kind	kind	NOUN
ajst-3866	25	3	of	of	ADP
ajst-3866	25	4	synthesis	synthesis	NOUN
ajst-3866	25	5	method	method	NOUN
ajst-3866	25	6	requires	require	VERB
ajst-3866	25	7	expensive	expensive	ADJ
ajst-3866	25	8	reagents	reagent	NOUN
ajst-3866	25	9	such	such	ADJ
ajst-3866	25	10	as	as	ADP
ajst-3866	25	11	phosphorus	phosphorus	NOUN
ajst-3866	25	12	and	and	CCONJ
ajst-3866	25	13	boron	boron	NOUN
ajst-3866	25	14	,	,	PUNCT
ajst-3866	25	15	or	or	CCONJ
ajst-3866	25	16	needs	need	VERB
ajst-3866	25	17	to	to	PART
ajst-3866	25	18	be	be	AUX
ajst-3866	25	19	carried	carry	VERB
ajst-3866	25	20	out	out	ADP
ajst-3866	25	21	under	under	ADP
ajst-3866	25	22	strong	strong	ADJ
ajst-3866	25	23	acid	acid	NOUN
ajst-3866	25	24	,	,	PUNCT
ajst-3866	25	25	strong	strong	ADJ
ajst-3866	25	26	oxidation	oxidation	NOUN
ajst-3866	25	27	and	and	CCONJ
ajst-3866	25	28	strong	strong	ADJ
ajst-3866	25	29	corrosion	corrosion	NOUN
ajst-3866	25	30	conditions	condition	NOUN
ajst-3866	25	31	,	,	PUNCT
ajst-3866	25	32	which	which	PRON
ajst-3866	25	33	has	have	VERB
ajst-3866	25	34	the	the	DET
ajst-3866	25	35	disadvantages	disadvantage	NOUN
ajst-3866	25	36	of	of	ADP
ajst-3866	25	37	high	high	ADJ
ajst-3866	25	38	requirements	requirement	NOUN
ajst-3866	25	39	for	for	ADP
ajst-3866	25	40	synthesis	synthesis	NOUN
ajst-3866	25	41	conditions	condition	NOUN
ajst-3866	25	42	,	,	PUNCT
ajst-3866	25	43	trivial	trivial	ADJ
ajst-3866	25	44	reaction	reaction	NOUN
ajst-3866	25	45	steps	step	NOUN
ajst-3866	25	46	and	and	CCONJ
ajst-3866	25	47	low	low	ADJ
ajst-3866	25	48	yield	yield	NOUN
ajst-3866	25	49	;	;	PUNCT
ajst-3866	25	50	as	as	ADV
ajst-3866	25	51	well	well	ADV
ajst-3866	25	52	as	as	ADP
ajst-3866	25	53	the	the	DET
ajst-3866	25	54	recent	recent	ADJ
ajst-3866	25	55	rise	rise	NOUN
ajst-3866	25	56	in	in	ADP
ajst-3866	25	57	the	the	DET
ajst-3866	25	58	use	use	NOUN
ajst-3866	25	59	of	of	ADP
ajst-3866	25	60	co2	co2	NOUN
ajst-3866	25	61	to	to	PART
ajst-3866	25	62	prepare	prepare	VERB
ajst-3866	25	63	benzozole	benzozole	ADJ
ajst-3866	25	64	compounds	compound	NOUN
ajst-3866	25	65	,	,	PUNCT
ajst-3866	25	66	microwave	microwave	NOUN
ajst-3866	25	67	radiation	radiation	NOUN
ajst-3866	25	68	method	method	NOUN
ajst-3866	25	69	to	to	PART
ajst-3866	25	70	prepare	prepare	VERB
ajst-3866	25	71	benzozole	benzozole	ADJ
ajst-3866	25	72	compounds	compound	NOUN
ajst-3866	25	73	and	and	CCONJ
ajst-3866	25	74	other	other	ADJ
ajst-3866	25	75	new	new	ADJ
ajst-3866	25	76	6	6	NUM
ajst-3866	25	77	methods	method	NOUN
ajst-3866	25	78	.	.	PUNCT
ajst-3866	26	1	these	these	DET
ajst-3866	26	2	reactions	reaction	NOUN
ajst-3866	26	3	have	have	VERB
ajst-3866	26	4	their	their	PRON
ajst-3866	26	5	own	own	ADJ
ajst-3866	26	6	characteristics	characteristic	NOUN
ajst-3866	26	7	.	.	PUNCT
ajst-3866	27	1	the	the	DET
ajst-3866	27	2	following	follow	VERB
ajst-3866	27	3	is	be	AUX
ajst-3866	27	4	a	a	DET
ajst-3866	27	5	systematic	systematic	ADJ
ajst-3866	27	6	review	review	NOUN
ajst-3866	27	7	of	of	ADP
ajst-3866	27	8	these	these	DET
ajst-3866	27	9	synthesis	synthesis	NOUN
ajst-3866	27	10	methods	method	NOUN
ajst-3866	27	11	.	.	PUNCT
ajst-3866	28	1	(	(	PUNCT
ajst-3866	28	2	1	1	X
ajst-3866	28	3	)	)	PUNCT
ajst-3866	28	4	condensation	condensation	NOUN
ajst-3866	28	5	reaction	reaction	NOUN
ajst-3866	28	6	of	of	ADP
ajst-3866	28	7	o	o	NOUN
ajst-3866	28	8	-	-	NOUN
ajst-3866	28	9	phenylenediamine	phenylenediamine	NOUN
ajst-3866	28	10	with	with	ADP
ajst-3866	28	11	carboxylic	carboxylic	ADJ
ajst-3866	28	12	acid	acid	NOUN
ajst-3866	28	13	,	,	PUNCT
ajst-3866	28	14	nitrile	nitrile	NOUN
ajst-3866	28	15	and	and	CCONJ
ajst-3866	28	16	ester	ester	NOUN
ajst-3866	28	17	.	.	PUNCT
ajst-3866	29	1	in	in	ADP
ajst-3866	29	2	2003	2003	NUM
ajst-3866	29	3	,	,	PUNCT
ajst-3866	29	4	chen	chen	PROPN
ajst-3866	29	5	xingquan	xingquan	PROPN
ajst-3866	29	6	et	et	PROPN
ajst-3866	29	7	al.[4]reacted	al.[4]reacte	VERB
ajst-3866	29	8	with	with	ADP
ajst-3866	29	9	cyanamide	cyanamide	NOUN
ajst-3866	29	10	and	and	CCONJ
ajst-3866	29	11	o	o	NOUN
ajst-3866	29	12	-	-	NOUN
ajst-3866	29	13	phenylenediamine	phenylenediamine	NOUN
ajst-3866	29	14	as	as	ADP
ajst-3866	29	15	raw	raw	ADJ
ajst-3866	29	16	materials	material	NOUN
ajst-3866	29	17	under	under	ADP
ajst-3866	29	18	the	the	DET
ajst-3866	29	19	catalysis	catalysis	NOUN
ajst-3866	29	20	of	of	ADP
ajst-3866	29	21	naoh	naoh	NOUN
ajst-3866	29	22	to	to	PART
ajst-3866	29	23	obtain	obtain	VERB
ajst-3866	29	24	2	2	NUM
ajst-3866	29	25	-	-	NOUN
ajst-3866	29	26	aminobenzimidazole	aminobenzimidazole	NOUN
ajst-3866	29	27	with	with	ADP
ajst-3866	29	28	a	a	DET
ajst-3866	29	29	yield	yield	NOUN
ajst-3866	29	30	of	of	ADP
ajst-3866	29	31	78	78	NUM
ajst-3866	29	32	%	%	NOUN
ajst-3866	29	33	81	81	NUM
ajst-3866	29	34	%	%	NOUN
ajst-3866	29	35	(	(	PUNCT
ajst-3866	29	36	fig	fig	NOUN
ajst-3866	29	37	.	.	PUNCT
ajst-3866	29	38	4	4	NUM
ajst-3866	29	39	)	)	PUNCT
ajst-3866	29	40	.	.	PUNCT
ajst-3866	30	1	nh2	nh2	PROPN
ajst-3866	30	2	nh2	nh2	PROPN
ajst-3866	30	3	nh2cn	nh2cn	PROPN
ajst-3866	30	4	hcl	hcl	PROPN
ajst-3866	30	5	naoh	naoh	PROPN
ajst-3866	30	6	n	n	PROPN
ajst-3866	30	7	h	h	NOUN
ajst-3866	30	8	n	n	PRON
ajst-3866	30	9	nh2	nh2	NOUN
ajst-3866	30	10	figure	figure	NOUN
ajst-3866	30	11	4	4	NUM
ajst-3866	30	12	.	.	PUNCT
ajst-3866	31	1	the	the	DET
ajst-3866	31	2	synthesis	synthesis	NOUN
ajst-3866	31	3	of	of	ADP
ajst-3866	31	4	2	2	NUM
ajst-3866	31	5	-	-	PUNCT
ajst-3866	31	6	aminobenzimidazole	aminobenzimidazole	NOUN
ajst-3866	31	7	by	by	ADP
ajst-3866	31	8	ophenylenediamine	ophenylenediamine	NOUN
ajst-3866	31	9	and	and	CCONJ
ajst-3866	31	10	cyanamide	cyanamide	VERB
ajst-3866	31	11	in	in	ADP
ajst-3866	31	12	2007	2007	NUM
ajst-3866	31	13	,	,	PUNCT
ajst-3866	31	14	zhang	zhang	PROPN
ajst-3866	31	15	et	et	PROPN
ajst-3866	31	16	al.[5]reacted	al.[5]reacte	VERB
ajst-3866	31	17	with	with	ADP
ajst-3866	31	18	ortho	ortho	PROPN
ajst-3866	31	19	pheny	pheny	PROPN
ajst-3866	31	20	lenediamine	lenediamine	PROPN
ajst-3866	31	21	and	and	CCONJ
ajst-3866	31	22	ortho	ortho	PROPN
ajst-3866	31	23	ester	ester	NOUN
ajst-3866	31	24	to	to	PART
ajst-3866	31	25	obtain	obtain	VERB
ajst-3866	31	26	benzimidazole	benzimidazole	NOUN
ajst-3866	31	27	with	with	ADP
ajst-3866	31	28	95	95	NUM
ajst-3866	31	29	%	%	NOUN
ajst-3866	31	30	yield	yield	NOUN
ajst-3866	31	31	under	under	ADP
ajst-3866	31	32	the	the	DET
ajst-3866	31	33	action	action	NOUN
ajst-3866	31	34	of	of	ADP
ajst-3866	31	35	lewis	lewis	PROPN
ajst-3866	31	36	acid	acid	NOUN
ajst-3866	31	37	catalysts	catalyst	NOUN
ajst-3866	31	38	such	such	ADJ
ajst-3866	31	39	as	as	ADP
ajst-3866	31	40	zrcl4	zrcl4	PROPN
ajst-3866	31	41	,	,	PUNCT
ajst-3866	31	42	sncl4	sncl4	PROPN
ajst-3866	31	43	·	·	PUNCT
ajst-3866	32	1	5h2o	5h2o	NUM
ajst-3866	32	2	,	,	PUNCT
ajst-3866	32	3	ticl4	ticl4	PROPN
ajst-3866	32	4	,	,	PUNCT
ajst-3866	32	5	bf3	bf3	X
ajst-3866	32	6	·	·	PUNCT
ajst-3866	32	7	et2o	et2o	ADJ
ajst-3866	32	8	,	,	PUNCT
ajst-3866	32	9	zrocl2	zrocl2	NOUN
ajst-3866	32	10	·	·	PUNCT
ajst-3866	32	11	8h2o	8h2o	NOUN
ajst-3866	32	12	,	,	PUNCT
ajst-3866	32	13	hfcl4	hfcl4	PROPN
ajst-3866	32	14	,	,	PUNCT
ajst-3866	32	15	etc	etc	X
ajst-3866	32	16	.	.	X
ajst-3866	33	1	nh2	nh2	PROPN
ajst-3866	33	2	nh2	nh2	PROPN
ajst-3866	33	3	r'c(or")3	r'c(or")3	NOUN
ajst-3866	33	4	n	n	PRON
ajst-3866	33	5	h	h	NOUN
ajst-3866	33	6	nlewis	nlewis	VERB
ajst-3866	33	7	acids	acid	NOUN
ajst-3866	33	8	etoh	etoh	NOUN
ajst-3866	33	9	,	,	PUNCT
ajst-3866	33	10	rt	rt	PROPN
ajst-3866	33	11	figure	figure	NOUN
ajst-3866	33	12	5	5	NUM
ajst-3866	33	13	.	.	PUNCT
ajst-3866	34	1	the	the	DET
ajst-3866	34	2	synthesis	synthesis	NOUN
ajst-3866	34	3	of	of	ADP
ajst-3866	34	4	benzimidazole	benzimidazole	NOUN
ajst-3866	34	5	by	by	ADP
ajst-3866	34	6	o	o	NOUN
ajst-3866	34	7	-	-	NOUN
ajst-3866	34	8	phenylenediamine	phenylenediamine	NOUN
ajst-3866	34	9	and	and	CCONJ
ajst-3866	34	10	ortho	ortho	NOUN
ajst-3866	34	11	-	-	PUNCT
ajst-3866	34	12	ester	ester	NOUN
ajst-3866	34	13	with	with	ADP
ajst-3866	34	14	the	the	DET
ajst-3866	34	15	condensation	condensation	NOUN
ajst-3866	34	16	reaction	reaction	NOUN
ajst-3866	34	17	of	of	ADP
ajst-3866	34	18	o	o	NOUN
ajst-3866	34	19	-	-	NOUN
ajst-3866	34	20	phenylenediamine	phenylenediamine	NOUN
ajst-3866	34	21	with	with	ADP
ajst-3866	34	22	carboxylic	carboxylic	ADJ
ajst-3866	34	23	acid	acid	NOUN
ajst-3866	34	24	,	,	PUNCT
ajst-3866	34	25	nitrile	nitrile	NOUN
ajst-3866	34	26	and	and	CCONJ
ajst-3866	34	27	ester	ester	NOUN
ajst-3866	34	28	,	,	PUNCT
ajst-3866	34	29	the	the	DET
ajst-3866	34	30	reaction	reaction	NOUN
ajst-3866	34	31	mechanism	mechanism	NOUN
ajst-3866	34	32	can	can	AUX
ajst-3866	34	33	be	be	AUX
ajst-3866	34	34	summarized	summarize	VERB
ajst-3866	34	35	as	as	SCONJ
ajst-3866	34	36	follows	follow	VERB
ajst-3866	34	37	:	:	PUNCT
ajst-3866	34	38	o	o	ADJ
ajst-3866	34	39	-	-	ADJ
ajst-3866	34	40	phenyl	phenyl	ADJ
ajst-3866	34	41	-enediamine	-enediamine	NOUN
ajst-3866	34	42	first	first	ADJ
ajst-3866	34	43	forms	form	NOUN
ajst-3866	34	44	n	n	CCONJ
ajst-3866	34	45	-	-	PUNCT
ajst-3866	34	46	acyl	acyl	NOUN
ajst-3866	34	47	o	o	NOUN
ajst-3866	34	48	-	-	NOUN
ajst-3866	34	49	phenyl	phenyl	NOUN
ajst-3866	34	50	-	-	PUNCT
ajst-3866	34	51	enediamine	enediamine	NOUN
ajst-3866	34	52	intermediate	intermediate	ADJ
ajst-3866	34	53	with	with	ADP
ajst-3866	34	54	carboxylic	carboxylic	ADJ
ajst-3866	34	55	acid	acid	NOUN
ajst-3866	34	56	,	,	PUNCT
ajst-3866	34	57	nitrile	nitrile	NOUN
ajst-3866	34	58	and	and	CCONJ
ajst-3866	34	59	ester	ester	NOUN
ajst-3866	34	60	,	,	PUNCT
ajst-3866	34	61	and	and	CCONJ
ajst-3866	34	62	then	then	ADV
ajst-3866	34	63	dehydrates	dehydrate	VERB
ajst-3866	34	64	and	and	CCONJ
ajst-3866	34	65	cyclizes	cyclize	VERB
ajst-3866	34	66	to	to	PART
ajst-3866	34	67	form	form	VERB
ajst-3866	34	68	benzozole	benzozole	ADJ
ajst-3866	34	69	compounds	compound	NOUN
ajst-3866	34	70	.	.	PUNCT
ajst-3866	35	1	(	(	PUNCT
ajst-3866	35	2	2	2	X
ajst-3866	35	3	)	)	PUNCT
ajst-3866	35	4	oxidative	oxidative	ADJ
ajst-3866	35	5	cyclization	cyclization	NOUN
ajst-3866	35	6	of	of	ADP
ajst-3866	35	7	o	o	ADJ
ajst-3866	35	8	-	-	PUNCT
ajst-3866	35	9	substituted	substitute	VERB
ajst-3866	35	10	anilines	aniline	NOUN
ajst-3866	35	11	with	with	ADP
ajst-3866	35	12	aldehydes	aldehyde	NOUN
ajst-3866	35	13	and	and	CCONJ
ajst-3866	35	14	alcohols	alcohol	NOUN
ajst-3866	35	15	.	.	PUNCT
ajst-3866	36	1	in	in	ADP
ajst-3866	36	2	2012	2012	NUM
ajst-3866	36	3	,	,	PUNCT
ajst-3866	36	4	chen	chen	PROPN
ajst-3866	36	5	et	et	PROPN
ajst-3866	36	6	al.[6]studied	al.[6]studie	VERB
ajst-3866	36	7	the	the	DET
ajst-3866	36	8	method	method	NOUN
ajst-3866	36	9	of	of	ADP
ajst-3866	36	10	synthe	synthe	ADJ
ajst-3866	36	11	-sizing	-sizing	PROPN
ajst-3866	36	12	benzimidazole	benzimidazole	NOUN
ajst-3866	36	13	with	with	ADP
ajst-3866	36	14	aromatic	aromatic	ADJ
ajst-3866	36	15	aldehydes	aldehyde	NOUN
ajst-3866	36	16	and	and	CCONJ
ajst-3866	36	17	o	o	NOUN
ajst-3866	36	18	-	-	NOUN
ajst-3866	36	19	phenyl	phenyl	NOUN
ajst-3866	36	20	enediamine	enediamine	NOUN
ajst-3866	36	21	as	as	ADP
ajst-3866	36	22	raw	raw	ADJ
ajst-3866	36	23	materials	material	NOUN
ajst-3866	36	24	under	under	ADP
ajst-3866	36	25	fecl3	fecl3	PROPN
ajst-3866	36	26	/	/	SYM
ajst-3866	36	27	al2o3	al2o3	PROPN
ajst-3866	36	28	catalysis	catalysis	NOUN
ajst-3866	36	29	.	.	PUNCT
ajst-3866	37	1	although	although	SCONJ
ajst-3866	37	2	the	the	DET
ajst-3866	37	3	conditions	condition	NOUN
ajst-3866	37	4	of	of	ADP
ajst-3866	37	5	these	these	DET
ajst-3866	37	6	two	two	NUM
ajst-3866	37	7	methods	method	NOUN
ajst-3866	37	8	are	be	AUX
ajst-3866	37	9	relatively	relatively	ADV
ajst-3866	37	10	mild	mild	ADJ
ajst-3866	37	11	,	,	PUNCT
ajst-3866	37	12	they	they	PRON
ajst-3866	37	13	both	both	PRON
ajst-3866	37	14	have	have	VERB
ajst-3866	37	15	the	the	DET
ajst-3866	37	16	disadvantage	disadvantage	NOUN
ajst-3866	37	17	of	of	ADP
ajst-3866	37	18	poor	poor	ADJ
ajst-3866	37	19	selectivity	selectivity	NOUN
ajst-3866	37	20	(	(	PUNCT
ajst-3866	37	21	figure	figure	NOUN
ajst-3866	37	22	6	6	NUM
ajst-3866	37	23	)	)	PUNCT
ajst-3866	37	24	.	.	PUNCT
ajst-3866	38	1	s	s	PART
ajst-3866	38	2	s	s	VERB
ajst-3866	38	3	nh2	nh2	PROPN
ajst-3866	38	4	nh2nh2h2n	nh2nh2h2n	PROPN
ajst-3866	38	5	o	o	NOUN
ajst-3866	38	6	h	h	NOUN
ajst-3866	38	7	o	o	NOUN
ajst-3866	38	8	r	r	NOUN
ajst-3866	38	9	fecl3·6h2o	fecl3·6h2o	NOUN
ajst-3866	38	10	ch3oh	ch3oh	NOUN
ajst-3866	38	11	r	r	NOUN
ajst-3866	38	12	,	,	PUNCT
ajst-3866	38	13	t	t	PROPN
ajst-3866	38	14	h2n	h2n	PROPN
ajst-3866	38	15	o	o	PROPN
ajst-3866	38	16	n	n	CCONJ
ajst-3866	38	17	s	s	NOUN
ajst-3866	38	18	r	r	NOUN
ajst-3866	38	19	r	r	NOUN
ajst-3866	38	20	=	=	NOUN
ajst-3866	38	21	h	h	NOUN
ajst-3866	38	22	,	,	PUNCT
ajst-3866	38	23	br	br	PROPN
ajst-3866	38	24	,	,	PUNCT
ajst-3866	38	25	och3	och3	ADJ
ajst-3866	38	26	o	o	NOUN
ajst-3866	38	27	figure	figure	NOUN
ajst-3866	38	28	6	6	NUM
ajst-3866	38	29	.	.	PUNCT
ajst-3866	39	1	the	the	DET
ajst-3866	39	2	synthesis	synthesis	NOUN
ajst-3866	39	3	of	of	ADP
ajst-3866	39	4	benzimidazole	benzimidazole	NOUN
ajst-3866	39	5	by	by	ADP
ajst-3866	39	6	o	o	NOUN
ajst-3866	39	7	-	-	NOUN
ajst-3866	39	8	phenylenediamine	phenylenediamine	NOUN
ajst-3866	39	9	and	and	CCONJ
ajst-3866	39	10	aldehyde	aldehyde	NOUN
ajst-3866	39	11	with	with	ADP
ajst-3866	39	12	metal	metal	NOUN
ajst-3866	39	13	in	in	ADP
ajst-3866	39	14	2013	2013	NUM
ajst-3866	39	15	,	,	PUNCT
ajst-3866	39	16	zhang	zhang	PROPN
ajst-3866	39	17	zhiwei	zhiwei	PROPN
ajst-3866	39	18	and	and	CCONJ
ajst-3866	39	19	others[7]studied	others[7]studie	VERB
ajst-3866	39	20	a	a	DET
ajst-3866	39	21	new	new	ADJ
ajst-3866	39	22	method	method	NOUN
ajst-3866	39	23	of	of	ADP
ajst-3866	39	24	iron	iron	NOUN
ajst-3866	39	25	catalyzed	catalyze	VERB
ajst-3866	39	26	synthesis	synthesis	NOUN
ajst-3866	39	27	of	of	ADP
ajst-3866	39	28	benzimidazole	benzimidazole	ADJ
ajst-3866	39	29	derivatives	derivative	NOUN
ajst-3866	39	30	from	from	ADP
ajst-3866	39	31	disulfides	disulfide	NOUN
ajst-3866	39	32	:	:	PUNCT
ajst-3866	39	33	under	under	ADP
ajst-3866	39	34	room	room	NOUN
ajst-3866	39	35	temperature	temperature	NOUN
ajst-3866	39	36	,	,	PUNCT
ajst-3866	39	37	2	2	NUM
ajst-3866	39	38	-	-	PUNCT
ajst-3866	39	39	substituted	substitute	VERB
ajst-3866	39	40	benzimidazole	benzimidazole	NOUN
ajst-3866	39	41	derivatives	derivative	NOUN
ajst-3866	39	42	were	be	AUX
ajst-3866	39	43	synthesized	synthesize	VERB
ajst-3866	39	44	in	in	ADP
ajst-3866	39	45	one	one	NUM
ajst-3866	39	46	pot	pot	NOUN
ajst-3866	39	47	with	with	ADP
ajst-3866	39	48	aromatic	aromatic	ADJ
ajst-3866	39	49	o	o	ADJ
ajst-3866	39	50	-	-	ADJ
ajst-3866	39	51	amino	amino	ADJ
ajst-3866	39	52	disulfides	disulfide	NOUN
ajst-3866	39	53	and	and	CCONJ
ajst-3866	39	54	aromatic	aromatic	ADJ
ajst-3866	39	55	aldehydes	aldehyde	NOUN
ajst-3866	39	56	as	as	ADP
ajst-3866	39	57	raw	raw	ADJ
ajst-3866	39	58	materials	material	NOUN
ajst-3866	39	59	under	under	ADP
ajst-3866	39	60	the	the	DET
ajst-3866	39	61	catalysis	catalysis	NOUN
ajst-3866	39	62	of	of	ADP
ajst-3866	39	63	fecl3	fecl3	PROPN
ajst-3866	39	64	·	·	PUNCT
ajst-3866	39	65	6h2o	6h2o	NOUN
ajst-3866	39	66	(	(	PUNCT
ajst-3866	39	67	fig	fig	NOUN
ajst-3866	39	68	.	.	PUNCT
ajst-3866	40	1	1	1	NUM
ajst-3866	40	2	-	-	SYM
ajst-3866	40	3	7	7	NUM
ajst-3866	40	4	)	)	PUNCT
ajst-3866	40	5	.	.	PUNCT
ajst-3866	41	1	rcho	rcho	NOUN
ajst-3866	41	2	75	75	NUM
ajst-3866	41	3	%	%	NOUN
ajst-3866	41	4	fe	fe	ADJ
ajst-3866	41	5	/	/	SYM
ajst-3866	41	6	ceo2	ceo2	ADJ
ajst-3866	41	7	-	-	PUNCT
ajst-3866	41	8	zro2	zro2	NOUN
ajst-3866	41	9	nano	nano	NOUN
ajst-3866	41	10	fine	fine	ADJ
ajst-3866	41	11	particle	particle	NOUN
ajst-3866	41	12	etoh	etoh	NOUN
ajst-3866	41	13	,	,	PUNCT
ajst-3866	41	14	r.t	r.t	PROPN
ajst-3866	41	15	.	.	PROPN
ajst-3866	41	16	80%-90	80%-90	NUM
ajst-3866	41	17	%	%	NOUN
ajst-3866	41	18	trace	trace	NOUN
ajst-3866	41	19	r1	r1	NOUN
ajst-3866	41	20	=	=	NOUN
ajst-3866	41	21	h	h	NOUN
ajst-3866	41	22	,	,	PUNCT
ajst-3866	41	23	me	i	PRON
ajst-3866	41	24	,	,	PUNCT
ajst-3866	41	25	no2;r=2	no2;r=2	NOUN
ajst-3866	41	26	-	-	PUNCT
ajst-3866	41	27	meoc6h4,3	meoc6h4,3	NOUN
ajst-3866	41	28	-	-	PUNCT
ajst-3866	41	29	mec6h4,3,4-(meo)2c6h4	mec6h4,3,4-(meo)2c6h4	ADJ
ajst-3866	41	30	,	,	PUNCT
ajst-3866	41	31	2,4	2,4	NUM
ajst-3866	41	32	-	-	PUNCT
ajst-3866	41	33	cl2c6h4,4	cl2c6h4,4	ADJ
ajst-3866	41	34	-	-	PUNCT
ajst-3866	41	35	no2c6h4,4	no2c6h4,4	ADJ
ajst-3866	41	36	-	-	PUNCT
ajst-3866	41	37	me2nc6h4,etc	me2nc6h4,etc	NOUN
ajst-3866	41	38	rcho	rcho	NOUN
ajst-3866	41	39	fecl3	fecl3	PROPN
ajst-3866	41	40	/	/	SYM
ajst-3866	41	41	al2o3	al2o3	PROPN
ajst-3866	41	42	dmf,25	dmf,25	PROPN
ajst-3866	41	43	℃	℃	PROPN
ajst-3866	41	44	n	n	ADP
ajst-3866	41	45	h	h	NOUN
ajst-3866	41	46	n	n	NOUN
ajst-3866	41	47	r	r	NOUN
ajst-3866	41	48	74%-98	74%-98	NUM
ajst-3866	41	49	%	%	NOUN
ajst-3866	41	50	r	r	NOUN
ajst-3866	41	51	=	=	NOUN
ajst-3866	41	52	c6h5,2	c6h5,2	NOUN
ajst-3866	41	53	-	-	PUNCT
ajst-3866	41	54	clc6h4,3	clc6h4,3	PRON
ajst-3866	41	55	-	-	PUNCT
ajst-3866	41	56	clc6h4,4	clc6h4,4	NOUN
ajst-3866	41	57	-	-	PUNCT
ajst-3866	41	58	meoc6h4,2	meoc6h4,2	NOUN
ajst-3866	41	59	-	-	PUNCT
ajst-3866	41	60	no2c6h4,3	no2c6h4,3	NOUN
ajst-3866	41	61	-	-	PUNCT
ajst-3866	41	62	no2c6h4	no2c6h4	NOUN
ajst-3866	41	63	,	,	PUNCT
ajst-3866	41	64	4	4	NUM
ajst-3866	41	65	-	-	PUNCT
ajst-3866	41	66	no2c6h4,4	no2c6h4,4	ADJ
ajst-3866	41	67	-	-	PUNCT
ajst-3866	41	68	mec6h4,4	mec6h4,4	NOUN
ajst-3866	41	69	-	-	PUNCT
ajst-3866	41	70	me2nc6h4,2	me2nc6h4,2	NOUN
ajst-3866	41	71	-	-	PUNCT
ajst-3866	41	72	furanyl,3,4	furanyl,3,4	NOUN
ajst-3866	41	73	-	-	PUNCT
ajst-3866	41	74	och2oc6h3	och2oc6h3	ADV
ajst-3866	41	75	nh2	nh2	PROPN
ajst-3866	41	76	nh2	nh2	PROPN
ajst-3866	41	77	r1	r1	PROPN
ajst-3866	41	78	n	n	CCONJ
ajst-3866	41	79	h	h	NOUN
ajst-3866	41	80	n	n	CCONJ
ajst-3866	41	81	r	r	NOUN
ajst-3866	41	82	r1	r1	PROPN
ajst-3866	41	83	n	n	CCONJ
ajst-3866	41	84	n	n	NOUN
ajst-3866	41	85	r	r	NOUN
ajst-3866	41	86	r1	r1	NOUN
ajst-3866	41	87	r	r	NOUN
ajst-3866	41	88	nh2	nh2	PROPN
ajst-3866	41	89	nh2	nh2	PROPN
ajst-3866	41	90	trace	trace	NOUN
ajst-3866	41	91	n	n	CCONJ
ajst-3866	41	92	n	n	NOUN
ajst-3866	41	93	r	r	NOUN
ajst-3866	41	94	r	r	NOUN
ajst-3866	41	95	figure	figure	NOUN
ajst-3866	41	96	7	7	NUM
ajst-3866	41	97	.	.	PUNCT
ajst-3866	42	1	the	the	DET
ajst-3866	42	2	synthesis	synthesis	NOUN
ajst-3866	42	3	of	of	ADP
ajst-3866	42	4	benzimidazole	benzimidazole	NOUN
ajst-3866	42	5	by	by	ADP
ajst-3866	42	6	aromatic	aromatic	ADJ
ajst-3866	42	7	aminodisulfide	aminodisulfide	NOUN
ajst-3866	42	8	and	and	CCONJ
ajst-3866	42	9	aldehyde	aldehyde	NOUN
ajst-3866	42	10	with	with	ADP
ajst-3866	42	11	metal	metal	NOUN
ajst-3866	42	12	synthesizing	synthesize	VERB
ajst-3866	42	13	the	the	DET
ajst-3866	42	14	oxidative	oxidative	ADJ
ajst-3866	42	15	cyclization	cyclization	NOUN
ajst-3866	42	16	reaction	reaction	NOUN
ajst-3866	42	17	of	of	ADP
ajst-3866	42	18	o	o	NOUN
ajst-3866	42	19	-	-	NOUN
ajst-3866	42	20	amino	amino	ADJ
ajst-3866	42	21	and	and	CCONJ
ajst-3866	42	22	o	o	NOUN
ajst-3866	42	23	-	-	PUNCT
ajst-3866	42	24	mercapto	mercapto	ADJ
ajst-3866	42	25	substituted	substitute	VERB
ajst-3866	42	26	aniline	aniline	NOUN
ajst-3866	42	27	with	with	ADP
ajst-3866	42	28	aldehyde	aldehyde	NOUN
ajst-3866	42	29	and	and	CCONJ
ajst-3866	42	30	alcohol	alcohol	NOUN
ajst-3866	42	31	,	,	PUNCT
ajst-3866	42	32	it	it	PRON
ajst-3866	42	33	can	can	AUX
ajst-3866	42	34	be	be	AUX
ajst-3866	42	35	concluded	conclude	VERB
ajst-3866	42	36	that	that	SCONJ
ajst-3866	42	37	the	the	DET
ajst-3866	42	38	reaction	reaction	NOUN
ajst-3866	42	39	mechanism	mechanism	NOUN
ajst-3866	42	40	is	be	AUX
ajst-3866	42	41	:	:	PUNCT
ajst-3866	42	42	o	o	NOUN
ajst-3866	42	43	-	-	NOUN
ajst-3866	42	44	amino	amino	ADJ
ajst-3866	42	45	and	and	CCONJ
ajst-3866	42	46	o	o	NOUN
ajst-3866	42	47	-	-	PUNCT
ajst-3866	42	48	mercapto	mercapto	VERB
ajst-3866	42	49	substituted	substitute	VERB
ajst-3866	42	50	aniline	aniline	NOUN
ajst-3866	42	51	first	first	ADJ
ajst-3866	42	52	forms	form	NOUN
ajst-3866	42	53	schiff	schiff	NOUN
ajst-3866	42	54	base	base	NOUN
ajst-3866	42	55	with	with	ADP
ajst-3866	42	56	aldehyde	aldehyde	NOUN
ajst-3866	42	57	,	,	PUNCT
ajst-3866	42	58	schiff	schiff	NOUN
ajst-3866	42	59	base	base	NOUN
ajst-3866	42	60	cyclizes	cyclize	NOUN
ajst-3866	42	61	with	with	ADP
ajst-3866	42	62	ortho	ortho	PROPN
ajst-3866	42	63	-	-	PUNCT
ajst-3866	42	64	nh2	nh2	NOUN
ajst-3866	42	65	to	to	PART
ajst-3866	42	66	form	form	VERB
ajst-3866	42	67	hydrogenation	hydrogenation	NOUN
ajst-3866	42	68	intermediate	intermediate	ADJ
ajst-3866	42	69	,	,	PUNCT
ajst-3866	42	70	and	and	CCONJ
ajst-3866	42	71	dehydrates	dehydrate	VERB
ajst-3866	42	72	to	to	PART
ajst-3866	42	73	form	form	VERB
ajst-3866	42	74	target	target	NOUN
ajst-3866	42	75	product	product	NOUN
ajst-3866	42	76	under	under	ADP
ajst-3866	42	77	the	the	DET
ajst-3866	42	78	action	action	NOUN
ajst-3866	42	79	of	of	ADP
ajst-3866	42	80	oxidant	oxidant	NOUN
ajst-3866	42	81	.	.	PUNCT
ajst-3866	43	1	(	(	PUNCT
ajst-3866	43	2	3	3	X
ajst-3866	43	3	)	)	PUNCT
ajst-3866	43	4	preparation	preparation	NOUN
ajst-3866	43	5	of	of	ADP
ajst-3866	43	6	benzozoles	benzozole	NOUN
ajst-3866	43	7	from	from	ADP
ajst-3866	43	8	n	n	CCONJ
ajst-3866	43	9	,	,	PUNCT
ajst-3866	43	10	n	n	CCONJ
ajst-3866	43	11	-	-	PUNCT
ajst-3866	43	12	dimethyl	dimethyl	NOUN
ajst-3866	43	13	formamide	formamide	ADV
ajst-3866	43	14	(	(	PUNCT
ajst-3866	43	15	dmf	dmf	PROPN
ajst-3866	43	16	)	)	PUNCT
ajst-3866	43	17	.	.	PUNCT
ajst-3866	44	1	in	in	ADP
ajst-3866	44	2	2016	2016	NUM
ajst-3866	44	3	,	,	PUNCT
ajst-3866	44	4	liu	liu	PROPN
ajst-3866	44	5	zhimin	zhimin	PROPN
ajst-3866	44	6	et	et	PROPN
ajst-3866	44	7	al.[8]proposed	al.[8]propose	VERB
ajst-3866	44	8	a	a	DET
ajst-3866	44	9	method	method	NOUN
ajst-3866	44	10	to	to	PART
ajst-3866	44	11	synthesize	synthesize	VERB
ajst-3866	44	12	nitrogen	nitrogen	NOUN
ajst-3866	44	13	containing	contain	VERB
ajst-3866	44	14	heterocyclic	heterocyclic	ADJ
ajst-3866	44	15	compounds	compound	NOUN
ajst-3866	44	16	,	,	PUNCT
ajst-3866	44	17	which	which	PRON
ajst-3866	44	18	has	have	VERB
ajst-3866	44	19	a	a	DET
ajst-3866	44	20	high	high	ADJ
ajst-3866	44	21	yield	yield	NOUN
ajst-3866	44	22	:	:	PUNCT
ajst-3866	44	23	with	with	ADP
ajst-3866	44	24	o	o	NOUN
ajst-3866	44	25	-	-	NOUN
ajst-3866	44	26	aminothiophenol	aminothiophenol	NOUN
ajst-3866	44	27	and	and	CCONJ
ajst-3866	44	28	dmf	dmf	PROPN
ajst-3866	44	29	as	as	ADP
ajst-3866	44	30	the	the	DET
ajst-3866	44	31	reaction	reaction	NOUN
ajst-3866	44	32	model	model	NOUN
ajst-3866	44	33	,	,	PUNCT
ajst-3866	44	34	under	under	ADP
ajst-3866	44	35	the	the	DET
ajst-3866	44	36	catalysis	catalysis	NOUN
ajst-3866	44	37	of	of	ADP
ajst-3866	44	38	b	b	PROPN
ajst-3866	44	39	(	(	PUNCT
ajst-3866	44	40	c6f5	c6f5	X
ajst-3866	44	41	)	)	PUNCT
ajst-3866	44	42	3	3	NUM
ajst-3866	44	43	,	,	PUNCT
ajst-3866	44	44	co2	co2	NOUN
ajst-3866	44	45	and	and	CCONJ
ajst-3866	44	46	et2sih2	et2sih2	PROPN
ajst-3866	44	47	are	be	AUX
ajst-3866	44	48	used	use	VERB
ajst-3866	44	49	to	to	PART
ajst-3866	44	50	promote	promote	VERB
ajst-3866	44	51	the	the	DET
ajst-3866	44	52	effect	effect	NOUN
ajst-3866	44	53	of	of	ADP
ajst-3866	44	54	allyl	allyl	ADJ
ajst-3866	44	55	alcohol	alcohol	NOUN
ajst-3866	44	56	on	on	ADP
ajst-3866	44	57	α	α	PROPN
ajst-3866	44	58	for	for	ADP
ajst-3866	44	59	the	the	DET
ajst-3866	44	60	effective	effective	ADJ
ajst-3866	44	61	hydration	hydration	NOUN
ajst-3866	44	62	of	of	ADP
ajst-3866	44	63	hydroxy	hydroxy	PROPN
ajst-3866	44	64	ketones	ketone	NOUN
ajst-3866	44	65	,	,	PUNCT
ajst-3866	44	66	the	the	DET
ajst-3866	44	67	yield	yield	NOUN
ajst-3866	44	68	of	of	ADP
ajst-3866	44	69	the	the	DET
ajst-3866	44	70	target	target	NOUN
ajst-3866	44	71	product	product	NOUN
ajst-3866	44	72	benzothiazole	benzothiazole	NOUN
ajst-3866	44	73	can	can	AUX
ajst-3866	44	74	reach	reach	VERB
ajst-3866	44	75	99	99	NUM
ajst-3866	44	76	%	%	NOUN
ajst-3866	44	77	at	at	ADP
ajst-3866	44	78	120	120	NUM
ajst-3866	44	79	�	�	NOUN
ajst-3866	44	80	for	for	ADP
ajst-3866	44	81	24	24	NUM
ajst-3866	44	82	hours	hour	NOUN
ajst-3866	44	83	(	(	PUNCT
ajst-3866	44	84	fig	fig	NOUN
ajst-3866	44	85	.	.	PUNCT
ajst-3866	45	1	1	1	NUM
ajst-3866	45	2	-	-	SYM
ajst-3866	45	3	8)	8)	NUM
ajst-3866	45	4	.	.	PUNCT
ajst-3866	46	1	this	this	DET
ajst-3866	46	2	method	method	NOUN
ajst-3866	46	3	combines	combine	VERB
ajst-3866	46	4	b(c6f5)3	b(c6f5)3	NOUN
ajst-3866	46	5	with	with	ADP
ajst-3866	46	6	co2	co2	NOUN
ajst-3866	46	7	in	in	ADP
ajst-3866	46	8	the	the	DET
ajst-3866	46	9	atmosphere	atmosphere	NOUN
ajst-3866	46	10	,	,	PUNCT
ajst-3866	46	11	which	which	PRON
ajst-3866	46	12	can	can	AUX
ajst-3866	46	13	effectively	effectively	ADV
ajst-3866	46	14	promote	promote	VERB
ajst-3866	46	15	various	various	ADJ
ajst-3866	46	16	types	type	NOUN
ajst-3866	46	17	of	of	ADP
ajst-3866	46	18	cyclization	cyclization	NOUN
ajst-3866	46	19	reactions	reaction	NOUN
ajst-3866	46	20	.	.	PUNCT
ajst-3866	47	1	it	it	PRON
ajst-3866	47	2	is	be	AUX
ajst-3866	47	3	also	also	ADV
ajst-3866	47	4	suitable	suitable	ADJ
ajst-3866	47	5	for	for	ADP
ajst-3866	47	6	the	the	DET
ajst-3866	47	7	synthesis	synthesis	NOUN
ajst-3866	47	8	of	of	ADP
ajst-3866	47	9	o	o	NOUN
ajst-3866	47	10	-	-	NOUN
ajst-3866	47	11	phenylenediamine	phenylenediamine	NOUN
ajst-3866	47	12	and	and	CCONJ
ajst-3866	47	13	its	its	PRON
ajst-3866	47	14	derivatives	derivative	NOUN
ajst-3866	47	15	with	with	ADP
ajst-3866	47	16	dmf	dmf	PROPN
ajst-3866	47	17	.	.	PUNCT
ajst-3866	48	1	a	a	DET
ajst-3866	48	2	series	series	NOUN
ajst-3866	48	3	of	of	ADP
ajst-3866	48	4	nitrogen	nitrogen	NOUN
ajst-3866	48	5	containing	contain	VERB
ajst-3866	48	6	heterocyclic	heterocyclic	ADJ
ajst-3866	48	7	compounds	compound	NOUN
ajst-3866	48	8	(	(	PUNCT
ajst-3866	48	9	including	include	VERB
ajst-3866	48	10	benzothiazole	benzothiazole	NOUN
ajst-3866	48	11	,	,	PUNCT
ajst-3866	48	12	benzoimidazole	benzoimidazole	NOUN
ajst-3866	48	13	,	,	PUNCT
ajst-3866	48	14	p	p	NOUN
ajst-3866	48	15	-	-	PUNCT
ajst-3866	48	16	quinazolone	quinazolone	NOUN
ajst-3866	48	17	,	,	PUNCT
ajst-3866	48	18	benzoxazole	benzoxazole	NOUN
ajst-3866	48	19	)	)	PUNCT
ajst-3866	48	20	can	can	AUX
ajst-3866	48	21	be	be	AUX
ajst-3866	48	22	obtained	obtain	VERB
ajst-3866	48	23	in	in	ADP
ajst-3866	48	24	68	68	NUM
ajst-3866	48	25	%	%	NOUN
ajst-3866	48	26	99	99	NUM
ajst-3866	48	27	%	%	NOUN
ajst-3866	48	28	yields	yield	NOUN
ajst-3866	48	29	.	.	PUNCT
ajst-3866	49	1	this	this	DET
ajst-3866	49	2	work	work	NOUN
ajst-3866	49	3	proposes	propose	VERB
ajst-3866	49	4	a	a	DET
ajst-3866	49	5	new	new	ADJ
ajst-3866	49	6	method	method	NOUN
ajst-3866	49	7	of	of	ADP
ajst-3866	49	8	preparing	prepare	VERB
ajst-3866	49	9	nitrogen	nitrogen	NOUN
ajst-3866	49	10	heterocyclic	heterocyclic	NOUN
ajst-3866	49	11	compounds	compound	NOUN
ajst-3866	49	12	with	with	ADP
ajst-3866	49	13	metal	metal	NOUN
ajst-3866	49	14	free	free	ADJ
ajst-3866	49	15	catalyst	catalyst	NOUN
ajst-3866	49	16	,	,	PUNCT
ajst-3866	49	17	and	and	CCONJ
ajst-3866	49	18	also	also	ADV
ajst-3866	49	19	uses	use	VERB
ajst-3866	49	20	carbon	carbon	NOUN
ajst-3866	49	21	dioxide	dioxide	NOUN
ajst-3866	49	22	gas	gas	NOUN
ajst-3866	49	23	that	that	PRON
ajst-3866	49	24	causes	cause	VERB
ajst-3866	49	25	greenhouse	greenhouse	NOUN
ajst-3866	49	26	effect	effect	NOUN
ajst-3866	49	27	.	.	PUNCT
ajst-3866	50	1	however	however	ADV
ajst-3866	50	2	,	,	PUNCT
ajst-3866	50	3	this	this	DET
ajst-3866	50	4	reaction	reaction	NOUN
ajst-3866	50	5	has	have	VERB
ajst-3866	50	6	the	the	DET
ajst-3866	50	7	disadvantages	disadvantage	NOUN
ajst-3866	50	8	of	of	ADP
ajst-3866	50	9	expensive	expensive	ADJ
ajst-3866	50	10	reagents	reagent	NOUN
ajst-3866	50	11	and	and	CCONJ
ajst-3866	50	12	long	long	ADJ
ajst-3866	50	13	reaction	reaction	NOUN
ajst-3866	50	14	time	time	NOUN
ajst-3866	50	15	.	.	PUNCT
ajst-3866	51	1	xh	xh	PROPN
ajst-3866	51	2	nh2	nh2	PROPN
ajst-3866	51	3	co2,et2sih2	co2,et2sih2	NUM
ajst-3866	51	4	x	x	SYM
ajst-3866	51	5	n	n	NUM
ajst-3866	51	6	h	h	NOUN
ajst-3866	51	7	n	n	NOUN
ajst-3866	51	8	o	o	X
ajst-3866	51	9	b(c6f5)3	b(c6f5)3	X
ajst-3866	51	10	x	x	NOUN
ajst-3866	51	11	=	=	PROPN
ajst-3866	51	12	nh	nh	PROPN
ajst-3866	51	13	,	,	PUNCT
ajst-3866	51	14	s	s	PART
ajst-3866	51	15	,	,	PUNCT
ajst-3866	51	16	o	o	NOUN
ajst-3866	51	17	figure	figure	NOUN
ajst-3866	51	18	8	8	NUM
ajst-3866	51	19	.	.	PUNCT
ajst-3866	52	1	the	the	DET
ajst-3866	52	2	synthesis	synthesis	NOUN
ajst-3866	52	3	of	of	ADP
ajst-3866	52	4	nitrogenous	nitrogenous	ADJ
ajst-3866	52	5	heterocyclic	heterocyclic	ADJ
ajst-3866	52	6	compounds	compound	NOUN
ajst-3866	52	7	by	by	ADP
ajst-3866	52	8	co2	co2	NOUN
ajst-3866	52	9	and	and	CCONJ
ajst-3866	52	10	b(c6f5)3	b(c6f5)3	NOUN
ajst-3866	52	11	it	it	PRON
ajst-3866	52	12	is	be	AUX
ajst-3866	52	13	supposed	suppose	VERB
ajst-3866	52	14	that	that	SCONJ
ajst-3866	52	15	the	the	DET
ajst-3866	52	16	possible	possible	ADJ
ajst-3866	52	17	reaction	reaction	NOUN
ajst-3866	52	18	mechanism	mechanism	NOUN
ajst-3866	52	19	is	be	AUX
ajst-3866	52	20	that	that	PRON
ajst-3866	52	21	b	b	X
ajst-3866	52	22	(	(	PUNCT
ajst-3866	52	23	c6f5	c6f5	X
ajst-3866	52	24	)	)	PUNCT
ajst-3866	52	25	3	3	NUM
ajst-3866	52	26	activates	activate	VERB
ajst-3866	52	27	dmf	dmf	PROPN
ajst-3866	52	28	through	through	ADP
ajst-3866	52	29	electrostatic	electrostatic	ADJ
ajst-3866	52	30	action	action	NOUN
ajst-3866	52	31	,	,	PUNCT
ajst-3866	52	32	which	which	PRON
ajst-3866	52	33	makes	make	VERB
ajst-3866	52	34	it	it	PRON
ajst-3866	52	35	easier	easy	ADJ
ajst-3866	52	36	for	for	SCONJ
ajst-3866	52	37	the	the	DET
ajst-3866	52	38	nucleophilic	nucleophilic	ADJ
ajst-3866	52	39	reaction	reaction	NOUN
ajst-3866	52	40	to	to	PART
ajst-3866	52	41	form	form	VERB
ajst-3866	52	42	formylated	formylate	VERB
ajst-3866	52	43	intermediate	intermediate	ADJ
ajst-3866	52	44	a	a	PRON
ajst-3866	52	45	,	,	PUNCT
ajst-3866	52	46	while	while	SCONJ
ajst-3866	52	47	dimethylamine	dimethylamine	NOUN
ajst-3866	52	48	is	be	AUX
ajst-3866	52	49	released	release	VERB
ajst-3866	52	50	by	by	ADP
ajst-3866	52	51	dmf	dmf	PROPN
ajst-3866	52	52	,	,	PUNCT
ajst-3866	52	53	which	which	PRON
ajst-3866	52	54	further	far	ADV
ajst-3866	52	55	reacts	react	VERB
ajst-3866	52	56	with	with	ADP
ajst-3866	52	57	co2	co2	NOUN
ajst-3866	52	58	and	and	CCONJ
ajst-3866	52	59	silane	silane	NOUN
ajst-3866	52	60	,	,	PUNCT
ajst-3866	52	61	pushing	push	VERB
ajst-3866	52	62	the	the	DET
ajst-3866	52	63	reaction	reaction	NOUN
ajst-3866	52	64	to	to	ADP
ajst-3866	52	65	the	the	DET
ajst-3866	52	66	right	right	NOUN
ajst-3866	52	67	to	to	PART
ajst-3866	52	68	dehydrate	dehydrate	VERB
ajst-3866	52	69	molecule	molecule	NOUN
ajst-3866	52	70	b	b	NOUN
ajst-3866	52	71	to	to	PART
ajst-3866	52	72	form	form	VERB
ajst-3866	52	73	c	c	PROPN
ajst-3866	52	74	(	(	PUNCT
ajst-3866	52	75	fig	fig	NOUN
ajst-3866	52	76	.	.	PUNCT
ajst-3866	53	1	9	9	NUM
ajst-3866	53	2	)	)	PUNCT
ajst-3866	53	3	.	.	PUNCT
ajst-3866	54	1	7	7	NUM
ajst-3866	54	2	r	r	NOUN
ajst-3866	54	3	nh2	nh2	NOUN
ajst-3866	54	4	xh	xh	PROPN
ajst-3866	54	5	o	o	INTJ
ajst-3866	54	6	h	h	NOUN
ajst-3866	54	7	n	n	CCONJ
ajst-3866	54	8	r	r	NOUN
ajst-3866	54	9	h	h	NOUN
ajst-3866	54	10	n	n	VERB
ajst-3866	54	11	xh	xh	PROPN
ajst-3866	54	12	n	n	CCONJ
ajst-3866	54	13	o	o	NOUN
ajst-3866	54	14	h	h	NOUN
ajst-3866	54	15	h	h	PROPN
ajst-3866	54	16	nh(ch3)2	nh(ch3)2	NOUN
ajst-3866	54	17	co2	co2	NOUN
ajst-3866	54	18	detected	detect	VERB
ajst-3866	54	19	silane	silane	NOUN
ajst-3866	54	20	n	n	PROPN
ajst-3866	54	21	detectedr	detectedr	PROPN
ajst-3866	54	22	h	h	PROPN
ajst-3866	54	23	n	n	CCONJ
ajst-3866	54	24	xh	xh	PROPN
ajst-3866	55	1	c	c	NOUN
ajst-3866	55	2	o	o	NOUN
ajst-3866	55	3	h	h	NOUN
ajst-3866	55	4	a	a	DET
ajst-3866	55	5	r	r	NOUN
ajst-3866	55	6	h	h	NOUN
ajst-3866	56	1	n	n	NOUN
ajst-3866	56	2	x	x	PROPN
ajst-3866	56	3	b	b	PROPN
ajst-3866	56	4	ohr	ohr	PROPN
ajst-3866	56	5	n	n	PROPN
ajst-3866	56	6	x	x	SYM
ajst-3866	56	7	c	c	NOUN
ajst-3866	56	8	cl	cl	NOUN
ajst-3866	56	9	x	x	NOUN
ajst-3866	56	10	=	=	NOUN
ajst-3866	56	11	nh	nh	X
ajst-3866	56	12	,	,	PUNCT
ajst-3866	56	13	s	s	PART
ajst-3866	56	14	,	,	PUNCT
ajst-3866	56	15	o	o	PROPN
ajst-3866	56	16	h2o	h2o	PROPN
ajst-3866	56	17	figure	figure	NOUN
ajst-3866	56	18	9	9	NUM
ajst-3866	56	19	.	.	PUNCT
ajst-3866	57	1	the	the	DET
ajst-3866	57	2	reaction	reaction	NOUN
ajst-3866	57	3	mechanism	mechanism	NOUN
ajst-3866	57	4	of	of	ADP
ajst-3866	57	5	nitrogenous	nitrogenous	ADJ
ajst-3866	57	6	heterocyclic	heterocyclic	ADJ
ajst-3866	57	7	compounds	compound	NOUN
ajst-3866	57	8	by	by	ADP
ajst-3866	57	9	co2	co2	NOUN
ajst-3866	57	10	and	and	CCONJ
ajst-3866	57	11	b(c6f5)3	b(c6f5)3	NOUN
ajst-3866	57	12	(	(	PUNCT
ajst-3866	57	13	4	4	NUM
ajst-3866	57	14	)	)	PUNCT
ajst-3866	57	15	preparation	preparation	NOUN
ajst-3866	57	16	of	of	ADP
ajst-3866	57	17	benzothiazole	benzothiazole	NOUN
ajst-3866	57	18	from	from	ADP
ajst-3866	57	19	carbon	carbon	NOUN
ajst-3866	57	20	dioxide	dioxide	NOUN
ajst-3866	57	21	.	.	PUNCT
ajst-3866	58	1	in	in	ADP
ajst-3866	58	2	2014	2014	NUM
ajst-3866	58	3	,	,	PUNCT
ajst-3866	58	4	liu	liu	PROPN
ajst-3866	58	5	zhimin	zhimin	PROPN
ajst-3866	58	6	,	,	PUNCT
ajst-3866	58	7	gao	gao	PROPN
ajst-3866	58	8	xiang	xiang	PROPN
ajst-3866	58	9	and	and	CCONJ
ajst-3866	58	10	others	other	NOUN
ajst-3866	58	11	in	in	ADP
ajst-3866	58	12	liu	liu	PROPN
ajst-3866	58	13	zhimin	zhimin	PROPN
ajst-3866	58	14	's	's	PART
ajst-3866	58	15	research	research	NOUN
ajst-3866	58	16	group[9]prepared	group[9]prepare	VERB
ajst-3866	58	17	benzothiazole	benzothiazole	NOUN
ajst-3866	58	18	with	with	ADP
ajst-3866	58	19	oaminothiophenol	oaminothiophenol	NOUN
ajst-3866	58	20	and	and	CCONJ
ajst-3866	58	21	carbon	carbon	NOUN
ajst-3866	58	22	dioxide	dioxide	NOUN
ajst-3866	58	23	as	as	ADP
ajst-3866	58	24	raw	raw	ADJ
ajst-3866	58	25	materials	material	NOUN
ajst-3866	58	26	under	under	ADP
ajst-3866	58	27	the	the	DET
ajst-3866	58	28	joint	joint	ADJ
ajst-3866	58	29	action	action	NOUN
ajst-3866	58	30	of	of	ADP
ajst-3866	58	31	solvent	solvent	ADJ
ajst-3866	58	32	n	n	X
ajst-3866	58	33	-	-	PUNCT
ajst-3866	58	34	methylpyrrolidone	methylpyrrolidone	NOUN
ajst-3866	58	35	(	(	PUNCT
ajst-3866	58	36	nmp	nmp	PROPN
ajst-3866	58	37	)	)	PUNCT
ajst-3866	58	38	and	and	CCONJ
ajst-3866	58	39	catalyst	catalyst	NOUN
ajst-3866	58	40	organic	organic	ADJ
ajst-3866	58	41	base	base	NOUN
ajst-3866	58	42	dbn	dbn	NOUN
ajst-3866	58	43	,	,	PUNCT
ajst-3866	58	44	diethylsilane	diethylsilane	NOUN
ajst-3866	58	45	(	(	PUNCT
ajst-3866	58	46	et2sih2	et2sih2	PROPN
ajst-3866	58	47	)	)	PUNCT
ajst-3866	58	48	(	(	PUNCT
ajst-3866	58	49	fig	fig	NOUN
ajst-3866	58	50	.	.	PUNCT
ajst-3866	59	1	1	1	NUM
ajst-3866	59	2	-	-	SYM
ajst-3866	59	3	10	10	NUM
ajst-3866	59	4	)	)	PUNCT
ajst-3866	59	5	.	.	PUNCT
ajst-3866	60	1	the	the	DET
ajst-3866	60	2	yield	yield	NOUN
ajst-3866	60	3	of	of	ADP
ajst-3866	60	4	the	the	DET
ajst-3866	60	5	reaction	reaction	NOUN
ajst-3866	60	6	is	be	AUX
ajst-3866	60	7	82	82	NUM
ajst-3866	60	8	%	%	NOUN
ajst-3866	60	9	,	,	PUNCT
ajst-3866	60	10	but	but	CCONJ
ajst-3866	60	11	the	the	DET
ajst-3866	60	12	reaction	reaction	NOUN
ajst-3866	60	13	conditions	condition	NOUN
ajst-3866	60	14	are	be	AUX
ajst-3866	60	15	harsh	harsh	ADJ
ajst-3866	60	16	and	and	CCONJ
ajst-3866	60	17	need	need	VERB
ajst-3866	60	18	to	to	PART
ajst-3866	60	19	be	be	AUX
ajst-3866	60	20	carried	carry	VERB
ajst-3866	60	21	out	out	ADP
ajst-3866	60	22	at	at	ADP
ajst-3866	60	23	high	high	ADJ
ajst-3866	60	24	temperature	temperature	NOUN
ajst-3866	60	25	.	.	PUNCT
ajst-3866	61	1	the	the	DET
ajst-3866	61	2	possible	possible	ADJ
ajst-3866	61	3	reaction	reaction	NOUN
ajst-3866	61	4	mechanism	mechanism	NOUN
ajst-3866	61	5	:	:	PUNCT
ajst-3866	61	6	carbon	carbon	NOUN
ajst-3866	61	7	dioxide	dioxide	NOUN
ajst-3866	61	8	and	and	CCONJ
ajst-3866	61	9	hydrosilane	hydrosilane	NOUN
ajst-3866	61	10	are	be	AUX
ajst-3866	61	11	activated	activate	VERB
ajst-3866	61	12	by	by	ADP
ajst-3866	61	13	catalyst	catalyst	NOUN
ajst-3866	61	14	dbn	dbn	PROPN
ajst-3866	61	15	(	(	PUNCT
ajst-3866	61	16	1,5	1,5	NUM
ajst-3866	61	17	-	-	PUNCT
ajst-3866	61	18	diazabicyclo	diazabicyclo	NOUN
ajst-3866	62	1	[	[	X
ajst-3866	62	2	4.3.0	4.3.0	X
ajst-3866	62	3	]	]	PUNCT
ajst-3866	62	4	non-5	non-5	NOUN
ajst-3866	62	5	-	-	NUM
ajst-3866	62	6	ene	ene	NOUN
ajst-3866	62	7	)	)	PUNCT
ajst-3866	62	8	to	to	PART
ajst-3866	62	9	form	form	VERB
ajst-3866	62	10	an	an	DET
ajst-3866	62	11	intermediate	intermediate	ADJ
ajst-3866	62	12	.	.	PUNCT
ajst-3866	63	1	o	o	ADJ
ajst-3866	63	2	-	-	PUNCT
ajst-3866	63	3	aminothio	aminothio	ADJ
ajst-3866	63	4	phenol	phenol	NOUN
ajst-3866	63	5	further	further	ADJ
ajst-3866	63	6	constructs	construct	VERB
ajst-3866	63	7	carbon	carbon	NOUN
ajst-3866	63	8	nitrogen	nitrogen	NOUN
ajst-3866	63	9	double	double	ADJ
ajst-3866	63	10	bond	bond	NOUN
ajst-3866	63	11	and	and	CCONJ
ajst-3866	63	12	carbon	carbon	NOUN
ajst-3866	63	13	sulfur	sulfur	NOUN
ajst-3866	63	14	bond	bond	NOUN
ajst-3866	63	15	with	with	ADP
ajst-3866	63	16	the	the	DET
ajst-3866	63	17	intermediate	intermediate	ADJ
ajst-3866	63	18	to	to	PART
ajst-3866	63	19	form	form	VERB
ajst-3866	63	20	the	the	DET
ajst-3866	63	21	product	product	NOUN
ajst-3866	63	22	benzothiazole	benzothiazole	NOUN
ajst-3866	63	23	.	.	PUNCT
ajst-3866	64	1	sh	sh	PROPN
ajst-3866	64	2	nh2	nh2	PROPN
ajst-3866	64	3	co2	co2	PROPN
ajst-3866	64	4	et2sih2	et2sih2	PROPN
ajst-3866	64	5	dbn	dbn	PROPN
ajst-3866	64	6	,	,	PUNCT
ajst-3866	64	7	nmp	nmp	PROPN
ajst-3866	64	8	s	s	PART
ajst-3866	64	9	n	n	PRON
ajst-3866	64	10	5mpa,150	5mpa,150	PROPN
ajst-3866	64	11	℃	℃	PROPN
ajst-3866	64	12	figure	figure	NOUN
ajst-3866	64	13	10	10	NUM
ajst-3866	64	14	.	.	PUNCT
ajst-3866	65	1	the	the	DET
ajst-3866	65	2	synthesis	synthesis	NOUN
ajst-3866	65	3	of	of	ADP
ajst-3866	65	4	benzothiazole	benzothiazole	NOUN
ajst-3866	65	5	by	by	ADP
ajst-3866	65	6	o	o	NOUN
ajst-3866	65	7	-	-	NOUN
ajst-3866	65	8	aminobenzene	aminobenzene	VERB
ajst-3866	65	9	and	and	CCONJ
ajst-3866	65	10	co2	co2	NOUN
ajst-3866	65	11	3	3	NUM
ajst-3866	65	12	.	.	PUNCT
ajst-3866	65	13	preparation	preparation	NOUN
ajst-3866	65	14	of	of	ADP
ajst-3866	65	15	benzozoles	benzozole	NOUN
ajst-3866	65	16	by	by	ADP
ajst-3866	65	17	microwave	microwave	NOUN
ajst-3866	65	18	irradiation	irradiation	NOUN
ajst-3866	65	19	in	in	ADP
ajst-3866	65	20	recent	recent	ADJ
ajst-3866	65	21	years	year	NOUN
ajst-3866	65	22	,	,	PUNCT
ajst-3866	65	23	microwave	microwave	NOUN
ajst-3866	65	24	radiation	radiation	NOUN
ajst-3866	65	25	has	have	AUX
ajst-3866	65	26	become	become	VERB
ajst-3866	65	27	a	a	DET
ajst-3866	65	28	widely	widely	ADV
ajst-3866	65	29	accepted	accept	VERB
ajst-3866	65	30	unconventional	unconventional	ADJ
ajst-3866	65	31	energy	energy	NOUN
ajst-3866	65	32	source	source	NOUN
ajst-3866	65	33	in	in	ADP
ajst-3866	65	34	organic	organic	ADJ
ajst-3866	65	35	synthesis	synthesis	NOUN
ajst-3866	65	36	,	,	PUNCT
ajst-3866	65	37	and	and	CCONJ
ajst-3866	65	38	has	have	AUX
ajst-3866	65	39	been	be	AUX
ajst-3866	65	40	widely	widely	ADV
ajst-3866	65	41	used	use	VERB
ajst-3866	65	42	in	in	ADP
ajst-3866	65	43	cycloaddition	cycloaddition	NOUN
ajst-3866	65	44	reaction	reaction	NOUN
ajst-3866	65	45	,	,	PUNCT
ajst-3866	65	46	radioisotope	radioisotope	NOUN
ajst-3866	65	47	synthesis	synthesis	NOUN
ajst-3866	65	48	,	,	PUNCT
ajst-3866	65	49	fullerene	fullerene	ADJ
ajst-3866	65	50	chemistry	chemistry	NOUN
ajst-3866	65	51	,	,	PUNCT
ajst-3866	65	52	polymer	polymer	NOUN
ajst-3866	65	53	generation	generation	NOUN
ajst-3866	65	54	,	,	PUNCT
ajst-3866	65	55	pharmaceutical	pharmaceutical	ADJ
ajst-3866	65	56	chemistry	chemistry	NOUN
ajst-3866	65	57	,	,	PUNCT
ajst-3866	65	58	green	green	ADJ
ajst-3866	65	59	chemistry	chemistry	NOUN
ajst-3866	65	60	,	,	PUNCT
ajst-3866	65	61	etc	etc	X
ajst-3866	65	62	.	.	X
ajst-3866	66	1	microwave	microwave	NOUN
ajst-3866	66	2	assisted	assist	VERB
ajst-3866	66	3	organic	organic	ADJ
ajst-3866	66	4	synthesis	synthesis	NOUN
ajst-3866	66	5	,	,	PUNCT
ajst-3866	66	6	with	with	ADP
ajst-3866	66	7	heating	heating	NOUN
ajst-3866	66	8	speed	speed	NOUN
ajst-3866	66	9	and	and	CCONJ
ajst-3866	66	10	heating	heating	NOUN
ajst-3866	66	11	efficiency	efficiency	NOUN
ajst-3866	66	12	unmatched	unmatched	ADJ
ajst-3866	66	13	by	by	ADP
ajst-3866	66	14	traditional	traditional	ADJ
ajst-3866	66	15	heating	heating	NOUN
ajst-3866	66	16	methods	method	NOUN
ajst-3866	66	17	,	,	PUNCT
ajst-3866	66	18	has	have	VERB
ajst-3866	66	19	the	the	DET
ajst-3866	66	20	advantages	advantage	NOUN
ajst-3866	66	21	of	of	ADP
ajst-3866	66	22	mild	mild	ADJ
ajst-3866	66	23	reaction	reaction	NOUN
ajst-3866	66	24	conditions	condition	NOUN
ajst-3866	66	25	,	,	PUNCT
ajst-3866	66	26	short	short	ADJ
ajst-3866	66	27	reaction	reaction	NOUN
ajst-3866	66	28	time	time	NOUN
ajst-3866	66	29	,	,	PUNCT
ajst-3866	66	30	good	good	ADJ
ajst-3866	66	31	reaction	reaction	NOUN
ajst-3866	66	32	selectivity	selectivity	NOUN
ajst-3866	66	33	and	and	CCONJ
ajst-3866	66	34	high	high	ADJ
ajst-3866	66	35	product	product	NOUN
ajst-3866	66	36	yield	yield	NOUN
ajst-3866	66	37	.	.	PUNCT
ajst-3866	67	1	microwave	microwave	NOUN
ajst-3866	67	2	heating	heating	NOUN
ajst-3866	67	3	converts	convert	NOUN
ajst-3866	67	4	electromagnetic	electromagnetic	ADJ
ajst-3866	67	5	energy	energy	NOUN
ajst-3866	67	6	into	into	ADP
ajst-3866	67	7	heat	heat	NOUN
ajst-3866	67	8	energy	energy	NOUN
ajst-3866	67	9	.	.	PUNCT
ajst-3866	68	1	energy	energy	NOUN
ajst-3866	68	2	transmission	transmission	NOUN
ajst-3866	68	3	is	be	AUX
ajst-3866	68	4	caused	cause	VERB
ajst-3866	68	5	by	by	ADP
ajst-3866	68	6	dielectric	dielectric	ADJ
ajst-3866	68	7	loss	loss	NOUN
ajst-3866	68	8	,	,	PUNCT
ajst-3866	68	9	which	which	PRON
ajst-3866	68	10	is	be	AUX
ajst-3866	68	11	contrary	contrary	ADJ
ajst-3866	68	12	to	to	ADP
ajst-3866	68	13	the	the	DET
ajst-3866	68	14	conduction	conduction	NOUN
ajst-3866	68	15	and	and	CCONJ
ajst-3866	68	16	convection	convection	NOUN
ajst-3866	68	17	process	process	NOUN
ajst-3866	68	18	observed	observe	VERB
ajst-3866	68	19	in	in	ADP
ajst-3866	68	20	traditional	traditional	ADJ
ajst-3866	68	21	heating	heating	NOUN
ajst-3866	68	22	.	.	PUNCT
ajst-3866	69	1	the	the	DET
ajst-3866	69	2	amount	amount	NOUN
ajst-3866	69	3	of	of	ADP
ajst-3866	69	4	heat	heat	NOUN
ajst-3866	69	5	heated	heat	VERB
ajst-3866	69	6	depends	depend	VERB
ajst-3866	69	7	on	on	ADP
ajst-3866	69	8	the	the	DET
ajst-3866	69	9	dielectric	dielectric	ADJ
ajst-3866	69	10	properties	property	NOUN
ajst-3866	69	11	of	of	ADP
ajst-3866	69	12	molecules	molecule	NOUN
ajst-3866	69	13	,	,	PUNCT
ajst-3866	69	14	which	which	PRON
ajst-3866	69	15	means	mean	VERB
ajst-3866	69	16	that	that	SCONJ
ajst-3866	69	17	radiation	radiation	NOUN
ajst-3866	69	18	and	and	CCONJ
ajst-3866	69	19	heating	heating	NOUN
ajst-3866	69	20	can	can	AUX
ajst-3866	69	21	be	be	AUX
ajst-3866	69	22	selectively	selectively	ADV
ajst-3866	69	23	absorbed	absorb	VERB
ajst-3866	69	24	.	.	PUNCT
ajst-3866	70	1	microwave	microwave	NOUN
ajst-3866	70	2	radiation	radiation	NOUN
ajst-3866	70	3	makes	make	VERB
ajst-3866	70	4	the	the	DET
ajst-3866	70	5	whole	whole	ADJ
ajst-3866	70	6	volume	volume	NOUN
ajst-3866	70	7	of	of	ADP
ajst-3866	70	8	materials	material	NOUN
ajst-3866	70	9	rapidly	rapidly	ADV
ajst-3866	70	10	heated	heat	VERB
ajst-3866	70	11	at	at	ADP
ajst-3866	70	12	the	the	DET
ajst-3866	70	13	same	same	ADJ
ajst-3866	70	14	time	time	NOUN
ajst-3866	70	15	,	,	PUNCT
ajst-3866	70	16	while	while	SCONJ
ajst-3866	70	17	traditional	traditional	ADJ
ajst-3866	70	18	heating	heating	NOUN
ajst-3866	70	19	is	be	AUX
ajst-3866	70	20	to	to	PART
ajst-3866	70	21	slowly	slowly	ADV
ajst-3866	70	22	transfer	transfer	VERB
ajst-3866	70	23	heat	heat	NOUN
ajst-3866	70	24	to	to	ADP
ajst-3866	70	25	the	the	DET
ajst-3866	70	26	surface	surface	NOUN
ajst-3866	70	27	of	of	ADP
ajst-3866	70	28	the	the	DET
ajst-3866	70	29	sample	sample	NOUN
ajst-3866	70	30	through	through	ADP
ajst-3866	70	31	heat	heat	NOUN
ajst-3866	70	32	conduction	conduction	NOUN
ajst-3866	70	33	,	,	PUNCT
ajst-3866	70	34	and	and	CCONJ
ajst-3866	70	35	then	then	ADV
ajst-3866	70	36	gradually	gradually	ADV
ajst-3866	70	37	transfer	transfer	VERB
ajst-3866	70	38	it	it	PRON
ajst-3866	70	39	to	to	ADP
ajst-3866	70	40	the	the	DET
ajst-3866	70	41	interior	interior	NOUN
ajst-3866	70	42	of	of	ADP
ajst-3866	70	43	the	the	DET
ajst-3866	70	44	sample	sample	NOUN
ajst-3866	70	45	.	.	PUNCT
ajst-3866	71	1	the	the	DET
ajst-3866	71	2	thermal	thermal	ADJ
ajst-3866	71	3	effect	effect	NOUN
ajst-3866	71	4	observed	observe	VERB
ajst-3866	71	5	under	under	ADP
ajst-3866	71	6	microwave	microwave	NOUN
ajst-3866	71	7	radiation	radiation	NOUN
ajst-3866	71	8	is	be	AUX
ajst-3866	71	9	the	the	DET
ajst-3866	71	10	result	result	NOUN
ajst-3866	71	11	of	of	ADP
ajst-3866	71	12	reverse	reverse	ADJ
ajst-3866	71	13	heat	heat	NOUN
ajst-3866	71	14	transfer	transfer	NOUN
ajst-3866	71	15	.	.	PUNCT
ajst-3866	72	1	the	the	DET
ajst-3866	72	2	selective	selective	ADJ
ajst-3866	72	3	absorption	absorption	NOUN
ajst-3866	72	4	of	of	ADP
ajst-3866	72	5	microwave	microwave	NOUN
ajst-3866	72	6	radiation	radiation	NOUN
ajst-3866	72	7	by	by	ADP
ajst-3866	72	8	polar	polar	ADJ
ajst-3866	72	9	compounds	compound	NOUN
ajst-3866	72	10	or	or	CCONJ
ajst-3866	72	11	solvents	solvent	NOUN
ajst-3866	72	12	can	can	AUX
ajst-3866	72	13	rapidly	rapidly	ADV
ajst-3866	72	14	heat	heat	VERB
ajst-3866	72	15	the	the	DET
ajst-3866	72	16	sample	sample	NOUN
ajst-3866	72	17	inside	inside	ADV
ajst-3866	72	18	.	.	PUNCT
ajst-3866	73	1	after	after	ADP
ajst-3866	73	2	absorbing	absorb	VERB
ajst-3866	73	3	microwave	microwave	NOUN
ajst-3866	73	4	energy	energy	NOUN
ajst-3866	73	5	,	,	PUNCT
ajst-3866	73	6	reactants	reactant	NOUN
ajst-3866	73	7	can	can	AUX
ajst-3866	73	8	improve	improve	VERB
ajst-3866	73	9	the	the	DET
ajst-3866	73	10	reaction	reaction	NOUN
ajst-3866	73	11	process	process	NOUN
ajst-3866	73	12	and	and	CCONJ
ajst-3866	73	13	change	change	VERB
ajst-3866	73	14	the	the	DET
ajst-3866	73	15	selectivity	selectivity	NOUN
ajst-3866	73	16	of	of	ADP
ajst-3866	73	17	the	the	DET
ajst-3866	73	18	reaction	reaction	NOUN
ajst-3866	73	19	.	.	PUNCT
ajst-3866	74	1	in	in	ADP
ajst-3866	74	2	2015	2015	NUM
ajst-3866	74	3	,	,	PUNCT
ajst-3866	74	4	kattimani	kattimani	PROPN
ajst-3866	74	5	et	et	PROPN
ajst-3866	74	6	al.[10]proposed	al.[10]propose	VERB
ajst-3866	74	7	the	the	DET
ajst-3866	74	8	method	method	NOUN
ajst-3866	74	9	of	of	ADP
ajst-3866	74	10	synthesizing	synthesize	VERB
ajst-3866	74	11	benzimidazole	benzimidazole	NOUN
ajst-3866	74	12	in	in	ADP
ajst-3866	74	13	70	70	NUM
ajst-3866	74	14	%	%	NOUN
ajst-3866	74	15	hcl	hcl	PROPN
ajst-3866	74	16	medium	medium	NOUN
ajst-3866	74	17	using	use	VERB
ajst-3866	74	18	microwave	microwave	NOUN
ajst-3866	74	19	heating	heating	NOUN
ajst-3866	74	20	and	and	CCONJ
ajst-3866	74	21	o	o	NOUN
ajst-3866	74	22	-	-	NOUN
ajst-3866	74	23	phenylenediamine	phenylenediamine	NOUN
ajst-3866	74	24	and	and	CCONJ
ajst-3866	74	25	n	n	CCONJ
ajst-3866	74	26	,	,	PUNCT
ajst-3866	74	27	ndimethylformamide	ndimethylformamide	PROPN
ajst-3866	74	28	(	(	PUNCT
ajst-3866	74	29	dmf	dmf	PROPN
ajst-3866	74	30	)	)	PUNCT
ajst-3866	74	31	as	as	ADP
ajst-3866	74	32	raw	raw	ADJ
ajst-3866	74	33	materials	material	NOUN
ajst-3866	74	34	.	.	PUNCT
ajst-3866	75	1	moreover	moreover	ADV
ajst-3866	75	2	,	,	PUNCT
ajst-3866	75	3	it	it	PRON
ajst-3866	75	4	proved	prove	VERB
ajst-3866	75	5	that	that	SCONJ
ajst-3866	75	6	this	this	DET
ajst-3866	75	7	method	method	NOUN
ajst-3866	75	8	has	have	VERB
ajst-3866	75	9	good	good	ADJ
ajst-3866	75	10	universality	universality	NOUN
ajst-3866	75	11	.	.	PUNCT
ajst-3866	76	1	different	different	ADJ
ajst-3866	76	2	csubstituted	csubstituted	ADJ
ajst-3866	76	3	amides	amide	NOUN
ajst-3866	76	4	were	be	AUX
ajst-3866	76	5	used	use	VERB
ajst-3866	76	6	to	to	PART
ajst-3866	76	7	replace	replace	VERB
ajst-3866	76	8	dmf	dmf	PROPN
ajst-3866	76	9	to	to	PART
ajst-3866	76	10	obtain	obtain	VERB
ajst-3866	76	11	2substituted	2substituted	NUM
ajst-3866	76	12	benzimidazoles	benzimidazole	NOUN
ajst-3866	76	13	with	with	ADP
ajst-3866	76	14	yields	yield	NOUN
ajst-3866	76	15	of	of	ADP
ajst-3866	76	16	80	80	NUM
ajst-3866	76	17	%	%	NOUN
ajst-3866	76	18	92	92	NUM
ajst-3866	76	19	%	%	NOUN
ajst-3866	76	20	.	.	PUNCT
ajst-3866	77	1	the	the	DET
ajst-3866	77	2	similarities	similarity	NOUN
ajst-3866	77	3	and	and	CCONJ
ajst-3866	77	4	differences	difference	NOUN
ajst-3866	77	5	between	between	ADP
ajst-3866	77	6	conventional	conventional	ADJ
ajst-3866	77	7	heating	heating	NOUN
ajst-3866	77	8	method	method	NOUN
ajst-3866	77	9	and	and	CCONJ
ajst-3866	77	10	microwave	microwave	NOUN
ajst-3866	77	11	assisted	assist	VERB
ajst-3866	77	12	method	method	NOUN
ajst-3866	77	13	were	be	AUX
ajst-3866	77	14	compared	compare	VERB
ajst-3866	77	15	.	.	PUNCT
ajst-3866	78	1	this	this	DET
ajst-3866	78	2	method	method	NOUN
ajst-3866	78	3	has	have	VERB
ajst-3866	78	4	short	short	ADJ
ajst-3866	78	5	reaction	reaction	NOUN
ajst-3866	78	6	time	time	NOUN
ajst-3866	78	7	,	,	PUNCT
ajst-3866	78	8	simple	simple	ADJ
ajst-3866	78	9	operation	operation	NOUN
ajst-3866	78	10	and	and	CCONJ
ajst-3866	78	11	no	no	DET
ajst-3866	78	12	catalyst	catalyst	NOUN
ajst-3866	78	13	,	,	PUNCT
ajst-3866	78	14	but	but	CCONJ
ajst-3866	78	15	it	it	PRON
ajst-3866	78	16	still	still	ADV
ajst-3866	78	17	requires	require	VERB
ajst-3866	78	18	the	the	DET
ajst-3866	78	19	presence	presence	NOUN
ajst-3866	78	20	of	of	ADP
ajst-3866	78	21	strong	strong	ADJ
ajst-3866	78	22	acid	acid	NOUN
ajst-3866	78	23	(	(	PUNCT
ajst-3866	78	24	70	70	NUM
ajst-3866	78	25	%	%	NOUN
ajst-3866	78	26	hcl	hcl	PROPN
ajst-3866	78	27	)	)	PUNCT
ajst-3866	78	28	and	and	CCONJ
ajst-3866	78	29	harsh	harsh	ADJ
ajst-3866	78	30	reaction	reaction	NOUN
ajst-3866	78	31	conditions	condition	NOUN
ajst-3866	78	32	(	(	PUNCT
ajst-3866	78	33	fig	fig	NOUN
ajst-3866	78	34	.	.	PUNCT
ajst-3866	78	35	11	11	NUM
ajst-3866	78	36	)	)	PUNCT
ajst-3866	78	37	.	.	PUNCT
ajst-3866	79	1	nh2	nh2	PROPN
ajst-3866	79	2	nh2	nh2	PROPN
ajst-3866	79	3	n	n	CCONJ
ajst-3866	79	4	h3c	h3c	VERB
ajst-3866	79	5	h3c	h3c	PUNCT
ajst-3866	79	6	o	o	X
ajst-3866	79	7	h	h	NOUN
ajst-3866	79	8	(	(	PUNCT
ajst-3866	79	9	1)100	1)100	NUM
ajst-3866	79	10	℃	℃	PROPN
ajst-3866	79	11	,∆	,∆	PUNCT
ajst-3866	79	12	(	(	PUNCT
ajst-3866	79	13	2)mw,150w,150	2)mw,150w,150	NOUN
ajst-3866	79	14	℃	℃	PROPN
ajst-3866	79	15	n	n	PRON
ajst-3866	79	16	h	h	NOUN
ajst-3866	80	1	n	n	NOUN
ajst-3866	81	1	70%hcl	70%hcl	NUM
ajst-3866	81	2	figure	figure	VERB
ajst-3866	81	3	11	11	NUM
ajst-3866	81	4	.	.	PUNCT
ajst-3866	82	1	the	the	DET
ajst-3866	82	2	synthesis	synthesis	NOUN
ajst-3866	82	3	of	of	ADP
ajst-3866	82	4	benzimidazole	benzimidazole	NOUN
ajst-3866	82	5	by	by	ADP
ajst-3866	82	6	o	o	NOUN
ajst-3866	82	7	-	-	NOUN
ajst-3866	82	8	phenylenediamine	phenylenediamine	NOUN
ajst-3866	82	9	and	and	CCONJ
ajst-3866	82	10	dmf	dmf	PROPN
ajst-3866	82	11	in	in	ADP
ajst-3866	82	12	70	70	NUM
ajst-3866	82	13	%	%	NOUN
ajst-3866	82	14	hcl	hcl	PROPN
ajst-3866	82	15	4	4	NUM
ajst-3866	82	16	.	.	PUNCT
ajst-3866	82	17	conclusion	conclusion	NOUN
ajst-3866	82	18	the	the	DET
ajst-3866	82	19	above	above	ADP
ajst-3866	82	20	classification	classification	NOUN
ajst-3866	82	21	and	and	CCONJ
ajst-3866	82	22	summary	summary	NOUN
ajst-3866	82	23	of	of	ADP
ajst-3866	82	24	the	the	DET
ajst-3866	82	25	synthesis	synthesis	NOUN
ajst-3866	82	26	of	of	ADP
ajst-3866	82	27	benzoxazole	benzoxazole	NOUN
ajst-3866	82	28	compounds	compound	NOUN
ajst-3866	82	29	(	(	PUNCT
ajst-3866	82	30	benzimidazole	benzimidazole	NOUN
ajst-3866	82	31	,	,	PUNCT
ajst-3866	82	32	benzothiazole	benzothiazole	NOUN
ajst-3866	82	33	,	,	PUNCT
ajst-3866	82	34	benzoxazole	benzoxazole	NOUN
ajst-3866	82	35	and	and	CCONJ
ajst-3866	82	36	its	its	PRON
ajst-3866	82	37	derivatives	derivative	NOUN
ajst-3866	82	38	)	)	PUNCT
ajst-3866	82	39	are	be	AUX
ajst-3866	82	40	based	base	VERB
ajst-3866	82	41	on	on	ADP
ajst-3866	82	42	the	the	DET
ajst-3866	82	43	reaction	reaction	NOUN
ajst-3866	82	44	mechanism	mechanism	NOUN
ajst-3866	82	45	.	.	PUNCT
ajst-3866	83	1	although	although	SCONJ
ajst-3866	83	2	these	these	DET
ajst-3866	83	3	methods	method	NOUN
ajst-3866	83	4	have	have	AUX
ajst-3866	83	5	made	make	VERB
ajst-3866	83	6	outstanding	outstanding	ADJ
ajst-3866	83	7	contributions	contribution	NOUN
ajst-3866	83	8	to	to	ADP
ajst-3866	83	9	the	the	DET
ajst-3866	83	10	synthesis	synthesis	NOUN
ajst-3866	83	11	of	of	ADP
ajst-3866	83	12	benzoxazole	benzoxazole	NOUN
ajst-3866	83	13	compounds	compound	NOUN
ajst-3866	83	14	,	,	PUNCT
ajst-3866	83	15	the	the	DET
ajst-3866	83	16	current	current	ADJ
ajst-3866	83	17	methods	method	NOUN
ajst-3866	83	18	still	still	ADV
ajst-3866	83	19	have	have	VERB
ajst-3866	83	20	some	some	DET
ajst-3866	83	21	shortcomings	shortcoming	NOUN
ajst-3866	83	22	,	,	PUNCT
ajst-3866	83	23	such	such	ADJ
ajst-3866	83	24	as	as	ADP
ajst-3866	83	25	very	very	ADV
ajst-3866	83	26	high	high	ADJ
ajst-3866	83	27	requirements	requirement	NOUN
ajst-3866	83	28	for	for	ADP
ajst-3866	83	29	reaction	reaction	NOUN
ajst-3866	83	30	conditions	condition	NOUN
ajst-3866	83	31	,	,	PUNCT
ajst-3866	83	32	difficult	difficult	ADJ
ajst-3866	83	33	access	access	NOUN
ajst-3866	83	34	to	to	ADP
ajst-3866	83	35	raw	raw	ADJ
ajst-3866	83	36	materials	material	NOUN
ajst-3866	83	37	,	,	PUNCT
ajst-3866	83	38	trivial	trivial	ADJ
ajst-3866	83	39	reaction	reaction	NOUN
ajst-3866	83	40	steps	step	NOUN
ajst-3866	83	41	,	,	PUNCT
ajst-3866	83	42	low	low	ADJ
ajst-3866	83	43	yield	yield	NOUN
ajst-3866	83	44	,	,	PUNCT
ajst-3866	83	45	etc	etc	X
ajst-3866	83	46	.	.	X
ajst-3866	83	47	through	through	ADP
ajst-3866	83	48	the	the	DET
ajst-3866	83	49	summary	summary	NOUN
ajst-3866	83	50	of	of	ADP
ajst-3866	83	51	this	this	DET
ajst-3866	83	52	paper	paper	NOUN
ajst-3866	83	53	,	,	PUNCT
ajst-3866	83	54	the	the	DET
ajst-3866	83	55	basis	basis	NOUN
ajst-3866	83	56	for	for	ADP
ajst-3866	83	57	the	the	DET
ajst-3866	83	58	next	next	ADJ
ajst-3866	83	59	step	step	NOUN
ajst-3866	83	60	to	to	PART
ajst-3866	83	61	establish	establish	VERB
ajst-3866	83	62	a	a	DET
ajst-3866	83	63	more	more	ADV
ajst-3866	83	64	green	green	ADJ
ajst-3866	83	65	,	,	PUNCT
ajst-3866	83	66	more	more	ADV
ajst-3866	83	67	economical	economical	ADJ
ajst-3866	83	68	and	and	CCONJ
ajst-3866	83	69	easier	easy	ADJ
ajst-3866	83	70	to	to	PART
ajst-3866	83	71	operate	operate	VERB
ajst-3866	83	72	synthesis	synthesis	NOUN
ajst-3866	83	73	method	method	NOUN
ajst-3866	83	74	is	be	AUX
ajst-3866	83	75	laid	lay	VERB
ajst-3866	83	76	.	.	PUNCT
ajst-3866	84	1	references	reference	NOUN
ajst-3866	84	2	[	[	X
ajst-3866	84	3	1	1	NUM
ajst-3866	84	4	]	]	PUNCT
ajst-3866	84	5	sheng	sheng	PROPN
ajst-3866	84	6	c	c	PROPN
ajst-3866	84	7	,	,	PUNCT
ajst-3866	84	8	che	che	PROPN
ajst-3866	84	9	x	x	PROPN
ajst-3866	84	10	,	,	PUNCT
ajst-3866	84	11	wang	wang	PROPN
ajst-3866	84	12	w	w	PROPN
ajst-3866	84	13	,	,	PUNCT
ajst-3866	84	14	et	et	PROPN
ajst-3866	84	15	al	al	PROPN
ajst-3866	84	16	.	.	PROPN
ajst-3866	84	17	design	design	NOUN
ajst-3866	84	18	and	and	CCONJ
ajst-3866	84	19	synthesis	synthesis	NOUN
ajst-3866	84	20	of	of	ADP
ajst-3866	84	21	antifungal	antifungal	ADJ
ajst-3866	84	22	benzoheterocyclic	benzoheterocyclic	NOUN
ajst-3866	84	23	derivatives	derivative	NOUN
ajst-3866	84	24	by	by	ADP
ajst-3866	84	25	scaffold	scaffold	NOUN
ajst-3866	84	26	hopping[j	hopping[j	PROPN
ajst-3866	84	27	]	]	PUNCT
ajst-3866	84	28	.	.	PUNCT
ajst-3866	85	1	european	european	PROPN
ajst-3866	85	2	journal	journal	PROPN
ajst-3866	85	3	of	of	ADP
ajst-3866	85	4	medicinal	medicinal	ADJ
ajst-3866	85	5	chemistry	chemistry	NOUN
ajst-3866	85	6	,	,	PUNCT
ajst-3866	85	7	2011	2011	NUM
ajst-3866	85	8	,	,	PUNCT
ajst-3866	85	9	46(5	46(5	NUM
ajst-3866	85	10	):	):	PUNCT
ajst-3866	85	11	1706	1706	NUM
ajst-3866	85	12	-	-	SYM
ajst-3866	85	13	1712	1712	NUM
ajst-3866	85	14	.	.	PUNCT
ajst-3866	86	1	[	[	X
ajst-3866	86	2	2	2	X
ajst-3866	86	3	]	]	X
ajst-3866	86	4	katritzky	katritzky	NOUN
ajst-3866	86	5	a	a	DET
ajst-3866	86	6	r	r	NOUN
ajst-3866	86	7	,	,	PUNCT
ajst-3866	86	8	lan	lan	PROPN
ajst-3866	86	9	x	x	SYM
ajst-3866	86	10	,	,	PUNCT
ajst-3866	86	11	yang	yang	PROPN
ajst-3866	86	12	j	j	PROPN
ajst-3866	87	1	z	z	PROPN
ajst-3866	87	2	,	,	PUNCT
ajst-3866	87	3	et	et	PROPN
ajst-3866	87	4	al	al	PROPN
ajst-3866	87	5	.	.	PUNCT
ajst-3866	87	6	properties	property	NOUN
ajst-3866	87	7	and	and	CCONJ
ajst-3866	87	8	synthetic	synthetic	ADJ
ajst-3866	87	9	utility	utility	NOUN
ajst-3866	87	10	of	of	ADP
ajst-3866	87	11	n	n	ADV
ajst-3866	87	12	-	-	PUNCT
ajst-3866	87	13	substituted	substitute	VERB
ajst-3866	87	14	benzotriazoles[j	benzotriazoles[j	NOUN
ajst-3866	87	15	]	]	PUNCT
ajst-3866	87	16	.	.	PUNCT
ajst-3866	88	1	chemical	chemical	NOUN
ajst-3866	88	2	reviews	review	NOUN
ajst-3866	88	3	,	,	PUNCT
ajst-3866	88	4	1998	1998	NUM
ajst-3866	88	5	,	,	PUNCT
ajst-3866	88	6	98(2	98(2	NUM
ajst-3866	88	7	):	):	PUNCT
ajst-3866	88	8	409	409	NUM
ajst-3866	88	9	-	-	SYM
ajst-3866	88	10	548	548	NUM
ajst-3866	88	11	.	.	PUNCT
ajst-3866	89	1	[	[	X
ajst-3866	89	2	3	3	X
ajst-3866	89	3	]	]	X
ajst-3866	89	4	jacobson	jacobson	PROPN
ajst-3866	89	5	p.	p.	PROPN
ajst-3866	89	6	ueber	ueber	PROPN
ajst-3866	89	7	bildung	bildung	PROPN
ajst-3866	89	8	von	von	PROPN
ajst-3866	89	9	anhydrover	anhydrover	PROPN
ajst-3866	89	10	-bindungen	-bindungen	PROPN
ajst-3866	89	11	des	des	X
ajst-3866	89	12	orthoamidophenylmercaptans	orthoamidophenylmercaptans	PROPN
ajst-3866	89	13	aus	aus	PROPN
ajst-3866	89	14	thioaniliden[j	thioaniliden[j	PROPN
ajst-3866	89	15	]	]	PUNCT
ajst-3866	89	16	.	.	PUNCT
ajst-3866	90	1	european	european	PROPN
ajst-3866	90	2	journal	journal	PROPN
ajst-3866	90	3	of	of	ADP
ajst-3866	90	4	inorganic	inorganic	ADJ
ajst-3866	90	5	chemistry	chemistry	NOUN
ajst-3866	90	6	,	,	PUNCT
ajst-3866	90	7	1886	1886	NUM
ajst-3866	90	8	,	,	PUNCT
ajst-3866	90	9	19(1	19(1	NUM
ajst-3866	90	10	):	):	PUNCT
ajst-3866	90	11	1067	1067	NUM
ajst-3866	90	12	-	-	SYM
ajst-3866	90	13	1077	1077	NUM
ajst-3866	90	14	.	.	PUNCT
ajst-3866	91	1	[	[	X
ajst-3866	91	2	4	4	X
ajst-3866	91	3	]	]	X
ajst-3866	91	4	chen	chen	PROPN
ajst-3866	91	5	xingquan	xingquan	PROPN
ajst-3866	91	6	,	,	PUNCT
ajst-3866	91	7	zhao	zhao	PROPN
ajst-3866	91	8	tiansheng	tiansheng	PROPN
ajst-3866	91	9	synthesis	synthesis	NOUN
ajst-3866	91	10	of	of	ADP
ajst-3866	91	11	2aminobenzimidazole	2aminobenzimidazole	PROPN
ajst-3866	91	12	[	[	X
ajst-3866	91	13	j	j	X
ajst-3866	91	14	]	]	X
ajst-3866	91	15	fine	fine	ADJ
ajst-3866	91	16	petrochemical	petrochemical	NOUN
ajst-3866	91	17	industry	industry	NOUN
ajst-3866	91	18	,	,	PUNCT
ajst-3866	91	19	2004	2004	NUM
ajst-3866	91	20	(	(	PUNCT
ajst-3866	91	21	1	1	NUM
ajst-3866	91	22	):	):	PUNCT
ajst-3866	91	23	45	45	NUM
ajst-3866	91	24	-	-	SYM
ajst-3866	91	25	46	46	NUM
ajst-3866	91	26	.	.	PUNCT
ajst-3866	92	1	[	[	X
ajst-3866	92	2	5	5	X
ajst-3866	92	3	]	]	X
ajst-3866	92	4	zhang	zhang	PROPN
ajst-3866	92	5	z	z	PROPN
ajst-3866	92	6	h	h	PROPN
ajst-3866	92	7	,	,	PUNCT
ajst-3866	92	8	yin	yin	PROPN
ajst-3866	92	9	l	l	PROPN
ajst-3866	92	10	,	,	PUNCT
ajst-3866	92	11	wang	wang	PROPN
ajst-3866	92	12	y	y	PROPN
ajst-3866	92	13	m.	m.	VERB
ajst-3866	92	14	an	an	DET
ajst-3866	92	15	expeditious	expeditious	ADJ
ajst-3866	92	16	synthesis	synthesis	NOUN
ajst-3866	92	17	of	of	ADP
ajst-3866	92	18	benzimidazole	benzimidazole	ADJ
ajst-3866	92	19	derivatives	derivative	NOUN
ajst-3866	92	20	catalyzed	catalyze	VERB
ajst-3866	92	21	by	by	ADP
ajst-3866	92	22	lewis	lewis	PROPN
ajst-3866	92	23	acids[j	acids[j	PROPN
ajst-3866	92	24	]	]	PUNCT
ajst-3866	92	25	.	.	PUNCT
ajst-3866	93	1	catalysis	catalysis	NOUN
ajst-3866	93	2	communications	communication	NOUN
ajst-3866	93	3	,	,	PUNCT
ajst-3866	93	4	2007	2007	NUM
ajst-3866	93	5	,	,	PUNCT
ajst-3866	93	6	8(7	8(7	NUM
ajst-3866	93	7	):	):	PUNCT
ajst-3866	93	8	1126	1126	NUM
ajst-3866	93	9	-	-	SYM
ajst-3866	93	10	1131	1131	NUM
ajst-3866	93	11	.	.	PUNCT
ajst-3866	94	1	[	[	X
ajst-3866	94	2	6	6	NUM
ajst-3866	94	3	]	]	X
ajst-3866	94	4	chen	chen	PROPN
ajst-3866	94	5	y	y	PROPN
ajst-3866	94	6	x	x	PROPN
ajst-3866	94	7	,	,	PUNCT
ajst-3866	94	8	qian	qian	PROPN
ajst-3866	94	9	l	l	PROPN
ajst-3866	95	1	f	f	X
ajst-3866	95	2	,	,	PUNCT
ajst-3866	95	3	zhang	zhang	PROPN
ajst-3866	95	4	w	w	PROPN
ajst-3866	95	5	,	,	PUNCT
ajst-3866	95	6	et	et	PROPN
ajst-3866	95	7	al	al	PROPN
ajst-3866	95	8	.	.	PROPN
ajst-3866	95	9	efficient	efficient	ADJ
ajst-3866	95	10	aerobic	aerobic	ADJ
ajst-3866	95	11	oxidative	oxidative	ADJ
ajst-3866	95	12	synthesis	synthesis	NOUN
ajst-3866	95	13	of	of	ADP
ajst-3866	95	14	2	2	NUM
ajst-3866	95	15	‐	‐	ADJ
ajst-3866	95	16	substituted	substitute	VERB
ajst-3866	95	17	benzoxazoles	benzoxazole	NOUN
ajst-3866	95	18	,	,	PUNCT
ajst-3866	95	19	benzothiazoles	benzothiazole	NOUN
ajst-3866	95	20	,	,	PUNCT
ajst-3866	95	21	and	and	CCONJ
ajst-3866	95	22	benzimidazoles	benzimidazole	NOUN
ajst-3866	95	23	catalyzed	catalyze	VERB
ajst-3866	95	24	by	by	ADP
ajst-3866	95	25	4	4	NUM
ajst-3866	95	26	‐	‐	NOUN
ajst-3866	95	27	methoxy	methoxy	NOUN
ajst-3866	95	28	‐	‐	ADP
ajst-3866	95	29	tempo[j	tempo[j	PROPN
ajst-3866	95	30	]	]	PUNCT
ajst-3866	95	31	.	.	PUNCT
ajst-3866	96	1	angewandte	angewandte	PROPN
ajst-3866	96	2	chemie	chemie	PROPN
ajst-3866	96	3	international	international	PROPN
ajst-3866	96	4	edition	edition	PROPN
ajst-3866	96	5	,	,	PUNCT
ajst-3866	96	6	2008	2008	NUM
ajst-3866	96	7	,	,	PUNCT
ajst-3866	96	8	47(48	47(48	PROPN
ajst-3866	96	9	):	):	PUNCT
ajst-3866	96	10	9330	9330	NUM
ajst-3866	96	11	-	-	SYM
ajst-3866	96	12	9333	9333	NUM
ajst-3866	96	13	.	.	PUNCT
ajst-3866	97	1	[	[	X
ajst-3866	97	2	7	7	X
ajst-3866	97	3	]	]	X
ajst-3866	97	4	zhang	zhang	PROPN
ajst-3866	97	5	zhiwei	zhiwei	PROPN
ajst-3866	97	6	,	,	PUNCT
ajst-3866	97	7	a	a	DET
ajst-3866	97	8	new	new	ADJ
ajst-3866	97	9	method	method	NOUN
ajst-3866	97	10	for	for	ADP
ajst-3866	97	11	the	the	DET
ajst-3866	97	12	synthesis	synthesis	NOUN
ajst-3866	97	13	of	of	ADP
ajst-3866	97	14	benzothiazole	benzothiazole	NOUN
ajst-3866	97	15	derivatives	derivative	NOUN
ajst-3866	97	16	from	from	ADP
ajst-3866	97	17	disulfide	disulfide	NOUN
ajst-3866	97	18	catalyzed	catalyze	VERB
ajst-3866	97	19	by	by	ADP
ajst-3866	97	20	iron	iron	NOUN
ajst-3866	97	21	[	[	X
ajst-3866	97	22	d	d	X
ajst-3866	97	23	]	]	X
ajst-3866	97	24	inner	inner	PROPN
ajst-3866	97	25	mongolia	mongolia	PROPN
ajst-3866	97	26	university	university	PROPN
ajst-3866	97	27	of	of	ADP
ajst-3866	97	28	technology	technology	NOUN
ajst-3866	97	29	,	,	PUNCT
ajst-3866	97	30	2013:14	2013:14	NUM
ajst-3866	97	31	-	-	SYM
ajst-3866	97	32	16	16	NUM
ajst-3866	97	33	.	.	PUNCT
ajst-3866	98	1	[	[	X
ajst-3866	98	2	8	8	NUM
ajst-3866	98	3	]	]	X
ajst-3866	98	4	nale	nale	PROPN
ajst-3866	98	5	d	d	PROPN
ajst-3866	98	6	b	b	PROPN
ajst-3866	98	7	,	,	PUNCT
ajst-3866	98	8	bhanage	bhanage	NOUN
ajst-3866	98	9	b	b	PROPN
ajst-3866	98	10	m.	m.	NOUN
ajst-3866	98	11	n	n	CCONJ
ajst-3866	98	12	-	-	PUNCT
ajst-3866	98	13	substituted	substitute	VERB
ajst-3866	98	14	forma	forma	NOUN
ajst-3866	98	15	-mides	-mide	NOUN
ajst-3866	98	16	as	as	ADP
ajst-3866	98	17	c1sources	c1source	NOUN
ajst-3866	98	18	for	for	ADP
ajst-3866	98	19	the	the	DET
ajst-3866	98	20	synthesis	synthesis	NOUN
ajst-3866	98	21	of	of	ADP
ajst-3866	98	22	benzimidazole	benzimidazole	NOUN
ajst-3866	98	23	and	and	CCONJ
ajst-3866	98	24	benzothiazole	benzothiazole	NOUN
ajst-3866	98	25	derivatives	derivative	NOUN
ajst-3866	98	26	by	by	ADP
ajst-3866	98	27	using	use	VERB
ajst-3866	98	28	zinc	zinc	NOUN
ajst-3866	98	29	catalyzers[j	catalyzers[j	PROPN
ajst-3866	98	30	]	]	PUNCT
ajst-3866	98	31	.	.	PUNCT
ajst-3866	99	1	synlett	synlett	PROPN
ajst-3866	99	2	,	,	PUNCT
ajst-3866	99	3	2015	2015	NUM
ajst-3866	99	4	,	,	PUNCT
ajst-3866	99	5	26(20	26(20	NUM
ajst-3866	99	6	):	):	PUNCT
ajst-3866	99	7	2835	2835	NUM
ajst-3866	99	8	-	-	SYM
ajst-3866	99	9	2842	2842	NUM
ajst-3866	99	10	.	.	PUNCT
ajst-3866	99	11	8	8	NUM
ajst-3866	100	1	[	[	SYM
ajst-3866	100	2	9	9	NUM
ajst-3866	100	3	]	]	X
ajst-3866	100	4	gao	gao	PROPN
ajst-3866	100	5	x	x	X
ajst-3866	100	6	,	,	PUNCT
ajst-3866	100	7	yu	yu	PROPN
ajst-3866	100	8	b	b	PROPN
ajst-3866	100	9	,	,	PUNCT
ajst-3866	100	10	zhao	zhao	PROPN
ajst-3866	100	11	y	y	PROPN
ajst-3866	100	12	,	,	PUNCT
ajst-3866	100	13	et	et	PROPN
ajst-3866	100	14	al	al	PROPN
ajst-3866	100	15	.	.	PUNCT
ajst-3866	100	16	hydrosilane	hydrosilane	ADV
ajst-3866	100	17	-	-	PUNCT
ajst-3866	100	18	promoted	promote	VERB
ajst-3866	100	19	cyclization	cyclization	NOUN
ajst-3866	100	20	of	of	ADP
ajst-3866	100	21	2	2	NUM
ajst-3866	100	22	-	-	PUNCT
ajst-3866	100	23	aminothiophenols	aminothiophenol	NOUN
ajst-3866	100	24	by	by	ADP
ajst-3866	100	25	co2	co2	VERB
ajst-3866	100	26	to	to	ADP
ajst-3866	100	27	benzothia	benzothia	NOUN
ajst-3866	100	28	-zoles[j	-zoles[j	PROPN
ajst-3866	100	29	]	]	PUNCT
ajst-3866	100	30	.	.	PUNCT
ajst-3866	101	1	rsc	rsc	PROPN
ajst-3866	101	2	advances	advance	NOUN
ajst-3866	101	3	,	,	PUNCT
ajst-3866	101	4	2014	2014	NUM
ajst-3866	101	5	,	,	PUNCT
ajst-3866	101	6	4(100	4(100	NUM
ajst-3866	101	7	):	):	PUNCT
ajst-3866	101	8	56957	56957	NUM
ajst-3866	101	9	-	-	SYM
ajst-3866	101	10	56960	56960	NUM
ajst-3866	101	11	.	.	PUNCT
ajst-3866	102	1	[	[	X
ajst-3866	102	2	10	10	NUM
ajst-3866	102	3	]	]	X
ajst-3866	102	4	kumbar	kumbar	PROPN
ajst-3866	102	5	m	m	PROPN
ajst-3866	102	6	n	n	CCONJ
ajst-3866	102	7	,	,	PUNCT
ajst-3866	102	8	kamble	kamble	ADJ
ajst-3866	102	9	r	r	NOUN
ajst-3866	102	10	r	r	NOUN
ajst-3866	102	11	,	,	PUNCT
ajst-3866	102	12	kamble	kamble	ADJ
ajst-3866	102	13	a	a	DET
ajst-3866	102	14	a	a	NOUN
ajst-3866	102	15	,	,	PUNCT
ajst-3866	102	16	et	et	PROPN
ajst-3866	102	17	al	al	PROPN
ajst-3866	102	18	.	.	PROPN
ajst-3866	102	19	design	design	NOUN
ajst-3866	102	20	and	and	CCONJ
ajst-3866	102	21	microwave	microwave	NOUN
ajst-3866	102	22	assisted	assist	VERB
ajst-3866	102	23	synthesis	synthesis	NOUN
ajst-3866	102	24	of	of	ADP
ajst-3866	102	25	coumarin	coumarin	NOUN
ajst-3866	102	26	derivatives	derivative	NOUN
ajst-3866	102	27	as	as	ADP
ajst-3866	102	28	pde	pde	NOUN
ajst-3866	102	29	inhibitors[j	inhibitors[j	PROPN
ajst-3866	102	30	]	]	PUNCT
ajst-3866	102	31	.	.	PUNCT
ajst-3866	103	1	international	international	ADJ
ajst-3866	103	2	journal	journal	PROPN
ajst-3866	103	3	of	of	ADP
ajst-3866	103	4	medicinal	medicinal	ADJ
ajst-3866	103	5	chemistry	chemistry	NOUN
ajst-3866	103	6	,	,	PUNCT
ajst-3866	103	7	2016	2016	NUM
ajst-3866	103	8	.	.	PUNCT