id	sid	tid	token	lemma	pos
ajst-6292	1	1	academic	academic	ADJ
ajst-6292	1	2	journal	journal	NOUN
ajst-6292	1	3	of	of	ADP
ajst-6292	1	4	science	science	NOUN
ajst-6292	1	5	and	and	CCONJ
ajst-6292	1	6	technology	technology	NOUN
ajst-6292	1	7	issn	issn	NOUN
ajst-6292	1	8	:	:	PUNCT
ajst-6292	1	9	2771	2771	NUM
ajst-6292	1	10	-	-	SYM
ajst-6292	1	11	3032	3032	NUM
ajst-6292	1	12	|	|	NOUN
ajst-6292	1	13	vol	vol	NOUN
ajst-6292	1	14	.	.	PROPN
ajst-6292	2	1	5	5	NUM
ajst-6292	2	2	,	,	PUNCT
ajst-6292	2	3	no	no	INTJ
ajst-6292	2	4	.	.	NOUN
ajst-6292	2	5	2	2	NUM
ajst-6292	2	6	,	,	PUNCT
ajst-6292	2	7	2023	2023	NUM
ajst-6292	2	8	105	105	NUM
ajst-6292	2	9	a	a	DET
ajst-6292	2	10	novel	novel	ADJ
ajst-6292	2	11	synthesis	synthesis	NOUN
ajst-6292	2	12	method	method	NOUN
ajst-6292	2	13	of	of	ADP
ajst-6292	2	14	meriolin1	meriolin1	PROPN
ajst-6292	2	15	jie	jie	PROPN
ajst-6292	2	16	rena	rena	PROPN
ajst-6292	2	17	,	,	PUNCT
ajst-6292	2	18	pengcheng	pengcheng	PROPN
ajst-6292	2	19	dingb	dingb	PROPN
ajst-6292	2	20	,	,	PUNCT
ajst-6292	2	21	jichao	jichao	PROPN
ajst-6292	2	22	zhouc	zhouc	NOUN
ajst-6292	2	23	,	,	PUNCT
ajst-6292	2	24	pengchao	pengchao	PROPN
ajst-6292	2	25	yud	yud	PROPN
ajst-6292	2	26	,	,	PUNCT
ajst-6292	2	27	xinyue	xinyue	PROPN
ajst-6292	2	28	wue	wue	PROPN
ajst-6292	2	29	and	and	CCONJ
ajst-6292	2	30	kun	kun	PROPN
ajst-6292	2	31	huf	huf	PROPN
ajst-6292	2	32	school	school	PROPN
ajst-6292	2	33	of	of	ADP
ajst-6292	2	34	pharmacy	pharmacy	NOUN
ajst-6292	2	35	,	,	PUNCT
ajst-6292	2	36	changzhou	changzhou	PROPN
ajst-6292	2	37	university	university	PROPN
ajst-6292	2	38	,	,	PUNCT
ajst-6292	2	39	213164	213164	NUM
ajst-6292	2	40	,	,	PUNCT
ajst-6292	2	41	changzhou	changzhou	PROPN
ajst-6292	2	42	,	,	PUNCT
ajst-6292	2	43	china	china	PROPN
ajst-6292	2	44	.	.	PUNCT
ajst-6292	3	1	arenjie2006@163.com	arenjie2006@163.com	PROPN
ajst-6292	3	2	,	,	PUNCT
ajst-6292	3	3	b2595131130	b2595131130	ADJ
ajst-6292	3	4	@qq.com	@qq.com	PROPN
ajst-6292	3	5	,	,	PUNCT
ajst-6292	3	6	c820250784@qq.com	c820250784@qq.com	X
ajst-6292	3	7	,	,	PUNCT
ajst-6292	3	8	d2754915088@qq.com	d2754915088@qq.com	PROPN
ajst-6292	3	9	,	,	PUNCT
ajst-6292	3	10	e954687726@qq.com	e954687726@qq.com	NUM
ajst-6292	3	11	,	,	PUNCT
ajst-6292	3	12	fhukun1979@163.com	fhukun1979@163.com	X
ajst-6292	3	13	abstract	abstract	ADJ
ajst-6292	3	14	:	:	PUNCT
ajst-6292	3	15	meriolins	meriolin	NOUN
ajst-6292	3	16	,	,	PUNCT
ajst-6292	3	17	a	a	DET
ajst-6292	3	18	compound	compound	NOUN
ajst-6292	3	19	designed	design	VERB
ajst-6292	3	20	and	and	CCONJ
ajst-6292	3	21	synthesized	synthesize	VERB
ajst-6292	3	22	by	by	ADP
ajst-6292	3	23	the	the	DET
ajst-6292	3	24	similar	similar	ADJ
ajst-6292	3	25	structure	structure	NOUN
ajst-6292	3	26	of	of	ADP
ajst-6292	3	27	natural	natural	ADJ
ajst-6292	3	28	marine	marine	ADJ
ajst-6292	3	29	products	product	NOUN
ajst-6292	3	30	meridianins	meridianin	NOUN
ajst-6292	3	31	and	and	CCONJ
ajst-6292	3	32	variolins	variolin	NOUN
ajst-6292	3	33	,	,	PUNCT
ajst-6292	3	34	has	have	AUX
ajst-6292	3	35	been	be	AUX
ajst-6292	3	36	proved	prove	VERB
ajst-6292	3	37	to	to	PART
ajst-6292	3	38	be	be	AUX
ajst-6292	3	39	a	a	DET
ajst-6292	3	40	new	new	ADJ
ajst-6292	3	41	kinase	kinase	NOUN
ajst-6292	3	42	inhibitor	inhibitor	NOUN
ajst-6292	3	43	that	that	PRON
ajst-6292	3	44	can	can	AUX
ajst-6292	3	45	enhance	enhance	VERB
ajst-6292	3	46	protein	protein	NOUN
ajst-6292	3	47	kinase	kinase	PROPN
ajst-6292	3	48	selectivity	selectivity	NOUN
ajst-6292	3	49	and	and	CCONJ
ajst-6292	3	50	cell	cell	NOUN
ajst-6292	3	51	death	death	NOUN
ajst-6292	3	52	.	.	PUNCT
ajst-6292	4	1	it	it	PRON
ajst-6292	4	2	has	have	VERB
ajst-6292	4	3	stronger	strong	ADJ
ajst-6292	4	4	inhibitory	inhibitory	ADJ
ajst-6292	4	5	activity	activity	NOUN
ajst-6292	4	6	,	,	PUNCT
ajst-6292	4	7	relative	relative	ADJ
ajst-6292	4	8	selectivity	selectivity	NOUN
ajst-6292	4	9	to	to	ADP
ajst-6292	4	10	kinases	kinase	NOUN
ajst-6292	4	11	and	and	CCONJ
ajst-6292	4	12	antitumor	antitumor	PROPN
ajst-6292	4	13	effect	effect	NOUN
ajst-6292	4	14	.	.	PUNCT
ajst-6292	5	1	as	as	ADP
ajst-6292	5	2	the	the	DET
ajst-6292	5	3	first	first	ADJ
ajst-6292	5	4	compound	compound	NOUN
ajst-6292	5	5	in	in	ADP
ajst-6292	5	6	the	the	DET
ajst-6292	5	7	meriolins	meriolin	NOUN
ajst-6292	5	8	series	series	NOUN
ajst-6292	5	9	,	,	PUNCT
ajst-6292	5	10	meriolin1	meriolin1	PROPN
ajst-6292	5	11	has	have	AUX
ajst-6292	5	12	been	be	AUX
ajst-6292	5	13	studied	study	VERB
ajst-6292	5	14	the	the	DET
ajst-6292	5	15	most	most	ADJ
ajst-6292	5	16	.	.	PUNCT
ajst-6292	6	1	in	in	ADP
ajst-6292	6	2	this	this	DET
ajst-6292	6	3	paper	paper	NOUN
ajst-6292	6	4	,	,	PUNCT
ajst-6292	6	5	the	the	DET
ajst-6292	6	6	synthesis	synthesis	NOUN
ajst-6292	6	7	methods	method	NOUN
ajst-6292	6	8	of	of	ADP
ajst-6292	6	9	meriolin1	meriolin1	NOUN
ajst-6292	6	10	at	at	ADP
ajst-6292	6	11	home	home	ADV
ajst-6292	6	12	and	and	CCONJ
ajst-6292	6	13	abroad	abroad	ADV
ajst-6292	6	14	were	be	AUX
ajst-6292	6	15	summarized	summarize	VERB
ajst-6292	6	16	and	and	CCONJ
ajst-6292	6	17	analyzed	analyze	VERB
ajst-6292	6	18	.	.	PUNCT
ajst-6292	7	1	on	on	ADP
ajst-6292	7	2	this	this	DET
ajst-6292	7	3	basis	basis	NOUN
ajst-6292	7	4	,	,	PUNCT
ajst-6292	7	5	a	a	DET
ajst-6292	7	6	more	more	ADV
ajst-6292	7	7	economical	economical	ADJ
ajst-6292	7	8	and	and	CCONJ
ajst-6292	7	9	effective	effective	ADJ
ajst-6292	7	10	synthesis	synthesis	NOUN
ajst-6292	7	11	route	route	NOUN
ajst-6292	7	12	was	be	AUX
ajst-6292	7	13	designed	design	VERB
ajst-6292	7	14	,	,	PUNCT
ajst-6292	7	15	that	that	ADV
ajst-6292	7	16	is	is	ADV
ajst-6292	7	17	,	,	PUNCT
ajst-6292	7	18	meriolin1	meriolin1	PROPN
ajst-6292	7	19	was	be	AUX
ajst-6292	7	20	finally	finally	ADV
ajst-6292	7	21	obtained	obtain	VERB
ajst-6292	7	22	from	from	ADP
ajst-6292	7	23	7	7	NUM
ajst-6292	7	24	-	-	PUNCT
ajst-6292	7	25	azaindole	azaindole	NOUN
ajst-6292	7	26	through	through	ADP
ajst-6292	7	27	friedel	friedel	PROPN
ajst-6292	7	28	-	-	PUNCT
ajst-6292	7	29	crafts	crafts	PROPN
ajst-6292	7	30	acylation	acylation	NOUN
ajst-6292	7	31	,	,	PUNCT
ajst-6292	7	32	protection	protection	NOUN
ajst-6292	7	33	,	,	PUNCT
ajst-6292	7	34	aldol	aldol	NOUN
ajst-6292	7	35	condensation	condensation	NOUN
ajst-6292	7	36	and	and	CCONJ
ajst-6292	7	37	cyclization	cyclization	NOUN
ajst-6292	7	38	reaction	reaction	NOUN
ajst-6292	7	39	.	.	PUNCT
ajst-6292	8	1	this	this	DET
ajst-6292	8	2	route	route	NOUN
ajst-6292	8	3	avoids	avoid	VERB
ajst-6292	8	4	the	the	DET
ajst-6292	8	5	disadvantages	disadvantage	NOUN
ajst-6292	8	6	of	of	ADP
ajst-6292	8	7	the	the	DET
ajst-6292	8	8	existing	exist	VERB
ajst-6292	8	9	routes	route	NOUN
ajst-6292	8	10	and	and	CCONJ
ajst-6292	8	11	has	have	VERB
ajst-6292	8	12	the	the	DET
ajst-6292	8	13	advantages	advantage	NOUN
ajst-6292	8	14	of	of	ADP
ajst-6292	8	15	mild	mild	ADJ
ajst-6292	8	16	reaction	reaction	NOUN
ajst-6292	8	17	conditions	condition	NOUN
ajst-6292	8	18	,	,	PUNCT
ajst-6292	8	19	simple	simple	ADJ
ajst-6292	8	20	operation	operation	NOUN
ajst-6292	8	21	and	and	CCONJ
ajst-6292	8	22	low	low	ADJ
ajst-6292	8	23	cost	cost	NOUN
ajst-6292	8	24	.	.	PUNCT
ajst-6292	9	1	the	the	DET
ajst-6292	9	2	structures	structure	NOUN
ajst-6292	9	3	of	of	ADP
ajst-6292	9	4	the	the	DET
ajst-6292	9	5	compounds	compound	NOUN
ajst-6292	9	6	were	be	AUX
ajst-6292	9	7	confirmed	confirm	VERB
ajst-6292	9	8	by	by	ADP
ajst-6292	9	9	1h	1h	NUM
ajst-6292	9	10	nmr	nmr	NOUN
ajst-6292	9	11	and	and	CCONJ
ajst-6292	9	12	13c	13c	NOUN
ajst-6292	9	13	nmr	nmr	NOUN
ajst-6292	9	14	.	.	PUNCT
ajst-6292	10	1	keywords	keyword	NOUN
ajst-6292	10	2	:	:	PUNCT
ajst-6292	10	3	meriolins	meriolin	NOUN
ajst-6292	10	4	,	,	PUNCT
ajst-6292	10	5	synthesis	synthesis	NOUN
ajst-6292	10	6	,	,	PUNCT
ajst-6292	10	7	anti	anti	ADJ
ajst-6292	10	8	-	-	ADJ
ajst-6292	10	9	cancer	cancer	ADJ
ajst-6292	10	10	,	,	PUNCT
ajst-6292	10	11	kinase	kinase	PROPN
ajst-6292	10	12	inhibitors	inhibitor	NOUN
ajst-6292	10	13	,	,	PUNCT
ajst-6292	10	14	marine	marine	ADJ
ajst-6292	10	15	organism	organism	NOUN
ajst-6292	10	16	.	.	PUNCT
ajst-6292	11	1	1	1	X
ajst-6292	11	2	.	.	X
ajst-6292	11	3	introduction	introduction	NOUN
ajst-6292	11	4	variolins	variolin	NOUN
ajst-6292	11	5	is	be	AUX
ajst-6292	11	6	a	a	DET
ajst-6292	11	7	kind	kind	NOUN
ajst-6292	11	8	of	of	ADP
ajst-6292	11	9	marine	marine	ADJ
ajst-6292	11	10	alkaloid	alkaloid	NOUN
ajst-6292	11	11	isolated	isolate	VERB
ajst-6292	11	12	from	from	ADP
ajst-6292	11	13	antarctic	antarctic	ADJ
ajst-6292	11	14	sponge	sponge	NOUN
ajst-6292	11	15	kirkpatrickia	kirkpatrickia	PROPN
ajst-6292	11	16	variolosa	variolosa	NOUN
ajst-6292	12	1	[	[	X
ajst-6292	12	2	1	1	NUM
ajst-6292	12	3	-	-	SYM
ajst-6292	12	4	2	2	NUM
ajst-6292	12	5	]	]	PUNCT
ajst-6292	12	6	,	,	PUNCT
ajst-6292	12	7	which	which	PRON
ajst-6292	12	8	has	have	VERB
ajst-6292	12	9	strong	strong	ADJ
ajst-6292	12	10	apoptosis	apoptosis	NOUN
ajst-6292	12	11	-	-	PUNCT
ajst-6292	12	12	promoting	promote	VERB
ajst-6292	12	13	activity	activity	NOUN
ajst-6292	12	14	[	[	X
ajst-6292	12	15	3	3	NUM
ajst-6292	12	16	]	]	PUNCT
ajst-6292	12	17	.	.	PUNCT
ajst-6292	13	1	meridianins	meridianin	NOUN
ajst-6292	13	2	is	be	AUX
ajst-6292	13	3	isolated	isolate	VERB
ajst-6292	13	4	from	from	ADP
ajst-6292	13	5	ascidian	ascidian	ADJ
ajst-6292	13	6	aplidium	aplidium	NOUN
ajst-6292	13	7	meridianum	meridianum	NOUN
ajst-6292	14	1	[	[	X
ajst-6292	14	2	4	4	NUM
ajst-6292	14	3	]	]	PUNCT
ajst-6292	14	4	,	,	PUNCT
ajst-6292	14	5	and	and	CCONJ
ajst-6292	14	6	also	also	ADV
ajst-6292	14	7	has	have	VERB
ajst-6292	14	8	antitumor	antitumor	PROPN
ajst-6292	14	9	activity	activity	NOUN
ajst-6292	14	10	.	.	PUNCT
ajst-6292	15	1	meridianins	meridianin	NOUN
ajst-6292	15	2	is	be	AUX
ajst-6292	15	3	considered	consider	VERB
ajst-6292	15	4	to	to	PART
ajst-6292	15	5	be	be	AUX
ajst-6292	15	6	a	a	DET
ajst-6292	15	7	mild	mild	ADJ
ajst-6292	15	8	non	non	ADJ
ajst-6292	15	9	selective	selective	ADJ
ajst-6292	15	10	kinase	kinase	PROPN
ajst-6292	15	11	inhibitor	inhibitor	PROPN
ajst-6292	15	12	,	,	PUNCT
ajst-6292	15	13	which	which	PRON
ajst-6292	15	14	has	have	AUX
ajst-6292	15	15	been	be	AUX
ajst-6292	15	16	widely	widely	ADV
ajst-6292	15	17	studied	study	VERB
ajst-6292	15	18	because	because	SCONJ
ajst-6292	15	19	of	of	ADP
ajst-6292	15	20	its	its	PRON
ajst-6292	15	21	strong	strong	ADJ
ajst-6292	15	22	antitumor	antitumor	PROPN
ajst-6292	15	23	effect	effect	NOUN
ajst-6292	15	24	and	and	CCONJ
ajst-6292	15	25	the	the	DET
ajst-6292	15	26	ability	ability	NOUN
ajst-6292	15	27	to	to	PART
ajst-6292	15	28	induce	induce	VERB
ajst-6292	15	29	cell	cell	NOUN
ajst-6292	15	30	death	death	NOUN
ajst-6292	15	31	.	.	PUNCT
ajst-6292	16	1	however	however	ADV
ajst-6292	16	2	,	,	PUNCT
ajst-6292	16	3	although	although	SCONJ
ajst-6292	16	4	marine	marine	ADJ
ajst-6292	16	5	natural	natural	ADJ
ajst-6292	16	6	products	product	NOUN
ajst-6292	16	7	are	be	AUX
ajst-6292	16	8	very	very	ADV
ajst-6292	16	9	useful	useful	ADJ
ajst-6292	16	10	from	from	ADP
ajst-6292	16	11	a	a	DET
ajst-6292	16	12	pharmacological	pharmacological	ADJ
ajst-6292	16	13	point	point	NOUN
ajst-6292	16	14	of	of	ADP
ajst-6292	16	15	view	view	NOUN
ajst-6292	16	16	,	,	PUNCT
ajst-6292	16	17	it	it	PRON
ajst-6292	16	18	is	be	AUX
ajst-6292	16	19	very	very	ADV
ajst-6292	16	20	difficult	difficult	ADJ
ajst-6292	16	21	to	to	PART
ajst-6292	16	22	obtain	obtain	VERB
ajst-6292	16	23	these	these	DET
ajst-6292	16	24	compounds	compound	NOUN
ajst-6292	16	25	from	from	ADP
ajst-6292	16	26	a	a	DET
ajst-6292	16	27	technical	technical	ADJ
ajst-6292	16	28	and	and	CCONJ
ajst-6292	16	29	biological	biological	ADJ
ajst-6292	16	30	point	point	NOUN
ajst-6292	16	31	of	of	ADP
ajst-6292	16	32	view	view	NOUN
ajst-6292	16	33	.	.	PUNCT
ajst-6292	17	1	at	at	ADP
ajst-6292	17	2	present	present	ADJ
ajst-6292	17	3	,	,	PUNCT
ajst-6292	17	4	the	the	DET
ajst-6292	17	5	chemical	chemical	ADJ
ajst-6292	17	6	synthesis	synthesis	NOUN
ajst-6292	17	7	of	of	ADP
ajst-6292	17	8	the	the	DET
ajst-6292	17	9	effective	effective	ADJ
ajst-6292	17	10	components	component	NOUN
ajst-6292	17	11	of	of	ADP
ajst-6292	17	12	marine	marine	ADJ
ajst-6292	17	13	products	product	NOUN
ajst-6292	17	14	has	have	AUX
ajst-6292	17	15	become	become	VERB
ajst-6292	17	16	the	the	DET
ajst-6292	17	17	current	current	ADJ
ajst-6292	17	18	research	research	NOUN
ajst-6292	17	19	hotspot	hotspot	NOUN
ajst-6292	17	20	[	[	X
ajst-6292	17	21	5	5	NUM
ajst-6292	17	22	]	]	PUNCT
ajst-6292	17	23	.	.	PUNCT
ajst-6292	18	1	after	after	ADP
ajst-6292	18	2	analyzing	analyze	VERB
ajst-6292	18	3	the	the	DET
ajst-6292	18	4	overlapping	overlap	VERB
ajst-6292	18	5	structure	structure	NOUN
ajst-6292	18	6	of	of	ADP
ajst-6292	18	7	natural	natural	ADJ
ajst-6292	18	8	marine	marine	ADJ
ajst-6292	18	9	products	product	NOUN
ajst-6292	18	10	meridianins	meridianin	NOUN
ajst-6292	18	11	and	and	CCONJ
ajst-6292	18	12	variolins	variolin	NOUN
ajst-6292	18	13	,	,	PUNCT
ajst-6292	18	14	marine	marine	ADJ
ajst-6292	18	15	biologists	biologist	NOUN
ajst-6292	18	16	designed	design	VERB
ajst-6292	18	17	and	and	CCONJ
ajst-6292	18	18	synthesized	synthesize	VERB
ajst-6292	18	19	meriolins	meriolin	NOUN
ajst-6292	18	20	,	,	PUNCT
ajst-6292	18	21	which	which	PRON
ajst-6292	18	22	has	have	AUX
ajst-6292	18	23	been	be	AUX
ajst-6292	18	24	proved	prove	VERB
ajst-6292	18	25	to	to	PART
ajst-6292	18	26	be	be	AUX
ajst-6292	18	27	a	a	DET
ajst-6292	18	28	new	new	ADJ
ajst-6292	18	29	kinase	kinase	NOUN
ajst-6292	18	30	inhibitor	inhibitor	NOUN
ajst-6292	18	31	that	that	PRON
ajst-6292	18	32	can	can	AUX
ajst-6292	18	33	enhance	enhance	VERB
ajst-6292	18	34	protein	protein	NOUN
ajst-6292	18	35	kinase	kinase	PROPN
ajst-6292	18	36	selectivity	selectivity	NOUN
ajst-6292	18	37	and	and	CCONJ
ajst-6292	18	38	cell	cell	NOUN
ajst-6292	18	39	death	death	NOUN
ajst-6292	19	1	[	[	X
ajst-6292	19	2	67	67	NUM
ajst-6292	19	3	]	]	PUNCT
ajst-6292	19	4	.	.	PUNCT
ajst-6292	20	1	meriolins	meriolin	NOUN
ajst-6292	20	2	showed	show	VERB
ajst-6292	20	3	stronger	strong	ADJ
ajst-6292	20	4	inhibitory	inhibitory	ADJ
ajst-6292	20	5	activity	activity	NOUN
ajst-6292	20	6	,	,	PUNCT
ajst-6292	20	7	relative	relative	ADJ
ajst-6292	20	8	selectivity	selectivity	NOUN
ajst-6292	20	9	to	to	ADP
ajst-6292	20	10	kinase	kinase	PROPN
ajst-6292	20	11	and	and	CCONJ
ajst-6292	20	12	antitumor	antitumor	PROPN
ajst-6292	20	13	effect	effect	NOUN
ajst-6292	20	14	than	than	ADP
ajst-6292	20	15	its	its	PRON
ajst-6292	20	16	lead	lead	NOUN
ajst-6292	20	17	compounds	compound	VERB
ajst-6292	20	18	[	[	X
ajst-6292	20	19	8	8	NUM
ajst-6292	20	20	]	]	PUNCT
ajst-6292	20	21	.	.	PUNCT
ajst-6292	21	1	the	the	DET
ajst-6292	21	2	structures	structure	NOUN
ajst-6292	21	3	are	be	AUX
ajst-6292	21	4	shown	show	VERB
ajst-6292	21	5	in	in	ADP
ajst-6292	21	6	fig	fig	NOUN
ajst-6292	21	7	.	.	PUNCT
ajst-6292	22	1	1	1	X
ajst-6292	22	2	.	.	X
ajst-6292	22	3	figure	figure	NOUN
ajst-6292	22	4	1	1	NUM
ajst-6292	22	5	.	.	PUNCT
ajst-6292	23	1	structure	structure	NOUN
ajst-6292	23	2	of	of	ADP
ajst-6292	23	3	three	three	NUM
ajst-6292	23	4	compounds	compound	NOUN
ajst-6292	23	5	meriolin1	meriolin1	NOUN
ajst-6292	23	6	,	,	PUNCT
ajst-6292	23	7	as	as	SCONJ
ajst-6292	23	8	the	the	DET
ajst-6292	23	9	first	first	ADJ
ajst-6292	23	10	compound	compound	NOUN
ajst-6292	23	11	in	in	ADP
ajst-6292	23	12	meriolins	meriolin	NOUN
ajst-6292	23	13	series	series	NOUN
ajst-6292	23	14	to	to	PART
ajst-6292	23	15	be	be	AUX
ajst-6292	23	16	synthesized	synthesize	VERB
ajst-6292	23	17	and	and	CCONJ
ajst-6292	23	18	named	name	VERB
ajst-6292	23	19	,	,	PUNCT
ajst-6292	23	20	has	have	AUX
ajst-6292	23	21	been	be	AUX
ajst-6292	23	22	studied	study	VERB
ajst-6292	23	23	most	most	ADV
ajst-6292	23	24	.	.	PUNCT
ajst-6292	24	1	the	the	DET
ajst-6292	24	2	synthetic	synthetic	ADJ
ajst-6292	24	3	methods	method	NOUN
ajst-6292	24	4	can	can	AUX
ajst-6292	24	5	be	be	AUX
ajst-6292	24	6	summarized	summarize	VERB
ajst-6292	24	7	as	as	SCONJ
ajst-6292	24	8	follows	follow	VERB
ajst-6292	24	9	.	.	PUNCT
ajst-6292	25	1	in	in	ADP
ajst-6292	25	2	2005	2005	NUM
ajst-6292	25	3	,	,	PUNCT
ajst-6292	25	4	a.s	a.s	PROPN
ajst-6292	25	5	.	.	PROPN
ajst-6292	25	6	karpov	karpov	PROPN
ajst-6292	25	7	et	et	PROPN
ajst-6292	25	8	al	al	PROPN
ajst-6292	25	9	[	[	X
ajst-6292	25	10	9	9	NUM
ajst-6292	25	11	]	]	PUNCT
ajst-6292	25	12	synthesized	synthesize	VERB
ajst-6292	25	13	meriolin1	meriolin1	NOUN
ajst-6292	25	14	in	in	ADP
ajst-6292	25	15	only	only	ADV
ajst-6292	25	16	four	four	NUM
ajst-6292	25	17	steps	step	NOUN
ajst-6292	25	18	by	by	ADP
ajst-6292	25	19	iodization	iodization	NOUN
ajst-6292	25	20	reaction	reaction	NOUN
ajst-6292	25	21	,	,	PUNCT
ajst-6292	25	22	protecting	protect	VERB
ajst-6292	25	23	nitrogen	nitrogen	NOUN
ajst-6292	25	24	on	on	ADP
ajst-6292	25	25	indole	indole	ADJ
ajst-6292	25	26	ring	ring	NOUN
ajst-6292	25	27	,	,	PUNCT
ajst-6292	25	28	introducing	introduce	VERB
ajst-6292	25	29	alkyne	alkyne	NOUN
ajst-6292	25	30	ketone	ketone	NOUN
ajst-6292	25	31	under	under	ADP
ajst-6292	25	32	catalyst	catalyst	NOUN
ajst-6292	25	33	conditions	condition	NOUN
ajst-6292	25	34	,	,	PUNCT
ajst-6292	25	35	and	and	CCONJ
ajst-6292	25	36	cyclization	cyclization	NOUN
ajst-6292	25	37	reaction	reaction	NOUN
ajst-6292	25	38	.	.	PUNCT
ajst-6292	26	1	in	in	ADP
ajst-6292	26	2	the	the	DET
ajst-6292	26	3	third	third	ADJ
ajst-6292	26	4	step	step	NOUN
ajst-6292	26	5	,	,	PUNCT
ajst-6292	26	6	when	when	SCONJ
ajst-6292	26	7	pd	pd	PROPN
ajst-6292	26	8	(	(	PUNCT
ajst-6292	26	9	dppf	dppf	PROPN
ajst-6292	26	10	)	)	PUNCT
ajst-6292	26	11	cl2	cl2	PROPN
ajst-6292	26	12	was	be	AUX
ajst-6292	26	13	used	use	VERB
ajst-6292	26	14	alone	alone	ADV
ajst-6292	26	15	,	,	PUNCT
ajst-6292	26	16	alkyne	alkyne	ADJ
ajst-6292	26	17	ketone	ketone	NOUN
ajst-6292	26	18	became	become	VERB
ajst-6292	26	19	the	the	DET
ajst-6292	26	20	secondary	secondary	ADJ
ajst-6292	26	21	product	product	NOUN
ajst-6292	26	22	and	and	CCONJ
ajst-6292	26	23	tms	tms	PROPN
ajst-6292	26	24	ethynyl	ethynyl	NOUN
ajst-6292	26	25	indole	indole	NOUN
ajst-6292	26	26	was	be	AUX
ajst-6292	26	27	the	the	DET
ajst-6292	26	28	main	main	ADJ
ajst-6292	26	29	product	product	NOUN
ajst-6292	26	30	.	.	PUNCT
ajst-6292	27	1	so	so	ADV
ajst-6292	27	2	far	far	ADV
ajst-6292	27	3	,	,	PUNCT
ajst-6292	27	4	the	the	DET
ajst-6292	27	5	mechanism	mechanism	NOUN
ajst-6292	27	6	of	of	ADP
ajst-6292	27	7	the	the	DET
ajst-6292	27	8	effect	effect	NOUN
ajst-6292	27	9	of	of	ADP
ajst-6292	27	10	this	this	DET
ajst-6292	27	11	special	special	ADJ
ajst-6292	27	12	catalyst	catalyst	NOUN
ajst-6292	27	13	mixture	mixture	NOUN
ajst-6292	27	14	on	on	ADP
ajst-6292	27	15	the	the	DET
ajst-6292	27	16	alkynylation	alkynylation	NOUN
ajst-6292	27	17	selectivity	selectivity	NOUN
ajst-6292	27	18	of	of	ADP
ajst-6292	27	19	carbonyl	carbonyl	NOUN
ajst-6292	27	20	compounds	compound	NOUN
ajst-6292	27	21	is	be	AUX
ajst-6292	27	22	not	not	PART
ajst-6292	27	23	clear	clear	ADJ
ajst-6292	27	24	.	.	PUNCT
ajst-6292	28	1	then	then	ADV
ajst-6292	28	2	,	,	PUNCT
ajst-6292	28	3	in	in	ADP
ajst-6292	28	4	the	the	DET
ajst-6292	28	5	last	last	ADJ
ajst-6292	28	6	step	step	NOUN
ajst-6292	28	7	of	of	ADP
ajst-6292	28	8	cyclization	cyclization	NOUN
ajst-6292	28	9	reaction	reaction	NOUN
ajst-6292	28	10	,	,	PUNCT
ajst-6292	28	11	the	the	DET
ajst-6292	28	12	reagent	reagent	NOUN
ajst-6292	28	13	is	be	AUX
ajst-6292	28	14	particularly	particularly	ADV
ajst-6292	28	15	important	important	ADJ
ajst-6292	28	16	.	.	PUNCT
ajst-6292	29	1	after	after	ADP
ajst-6292	29	2	many	many	ADJ
ajst-6292	29	3	failures	failure	NOUN
ajst-6292	29	4	,	,	PUNCT
ajst-6292	29	5	the	the	DET
ajst-6292	29	6	effect	effect	NOUN
ajst-6292	29	7	of	of	ADP
ajst-6292	29	8	using	use	VERB
ajst-6292	29	9	tert	tert	NOUN
ajst-6292	29	10	-	-	PUNCT
ajst-6292	29	11	butyl	butyl	NOUN
ajst-6292	29	12	alcohol	alcohol	NOUN
ajst-6292	29	13	and	and	CCONJ
ajst-6292	29	14	acetonitrile	acetonitrile	NOUN
ajst-6292	29	15	as	as	ADP
ajst-6292	29	16	mixed	mixed	ADJ
ajst-6292	29	17	solvent	solvent	NOUN
ajst-6292	29	18	was	be	AUX
ajst-6292	29	19	the	the	DET
ajst-6292	29	20	most	most	ADV
ajst-6292	29	21	unexpected	unexpected	ADJ
ajst-6292	29	22	.	.	PUNCT
ajst-6292	30	1	this	this	PRON
ajst-6292	30	2	not	not	PART
ajst-6292	30	3	only	only	ADV
ajst-6292	30	4	contributed	contribute	VERB
ajst-6292	30	5	to	to	ADP
ajst-6292	30	6	the	the	DET
ajst-6292	30	7	michael	michael	PROPN
ajst-6292	30	8	addition	addition	NOUN
ajst-6292	30	9	of	of	ADP
ajst-6292	30	10	methanol	methanol	NOUN
ajst-6292	30	11	and	and	CCONJ
ajst-6292	30	12	successfully	successfully	ADV
ajst-6292	30	13	synthesized	synthesize	VERB
ajst-6292	30	14	the	the	DET
ajst-6292	30	15	pyrimidine	pyrimidine	NOUN
ajst-6292	30	16	ring	ring	NOUN
ajst-6292	30	17	,	,	PUNCT
ajst-6292	30	18	but	but	CCONJ
ajst-6292	30	19	also	also	ADV
ajst-6292	30	20	cleaved	cleaved	ADJ
ajst-6292	30	21	and	and	CCONJ
ajst-6292	30	22	removed	remove	VERB
ajst-6292	30	23	the	the	DET
ajst-6292	30	24	tms	tms	PROPN
ajst-6292	30	25	and	and	CCONJ
ajst-6292	30	26	boc	boc	NOUN
ajst-6292	30	27	groups	group	NOUN
ajst-6292	30	28	at	at	ADP
ajst-6292	30	29	the	the	DET
ajst-6292	30	30	same	same	ADJ
ajst-6292	30	31	time	time	NOUN
ajst-6292	30	32	,	,	PUNCT
ajst-6292	30	33	eliminating	eliminate	VERB
ajst-6292	30	34	the	the	DET
ajst-6292	30	35	deprotection	deprotection	NOUN
ajst-6292	30	36	step	step	NOUN
ajst-6292	30	37	.	.	PUNCT
ajst-6292	31	1	however	however	ADV
ajst-6292	31	2	,	,	PUNCT
ajst-6292	31	3	in	in	ADP
ajst-6292	31	4	the	the	DET
ajst-6292	31	5	third	third	ADJ
ajst-6292	31	6	step	step	NOUN
ajst-6292	31	7	,	,	PUNCT
ajst-6292	31	8	palladium	palladium	NOUN
ajst-6292	31	9	catalyst	catalyst	NOUN
ajst-6292	31	10	,	,	PUNCT
ajst-6292	31	11	co	co	X
ajst-6292	31	12	gas	gas	NOUN
ajst-6292	31	13	and	and	CCONJ
ajst-6292	31	14	highly	highly	ADV
ajst-6292	31	15	flammable	flammable	ADJ
ajst-6292	31	16	trimethylsilylene	trimethylsilylene	NOUN
ajst-6292	31	17	are	be	AUX
ajst-6292	31	18	used	use	VERB
ajst-6292	31	19	,	,	PUNCT
ajst-6292	31	20	which	which	PRON
ajst-6292	31	21	makes	make	VERB
ajst-6292	31	22	the	the	DET
ajst-6292	31	23	condition	condition	NOUN
ajst-6292	31	24	control	control	VERB
ajst-6292	31	25	more	more	ADV
ajst-6292	31	26	stringent	stringent	ADJ
ajst-6292	31	27	.	.	PUNCT
ajst-6292	32	1	the	the	DET
ajst-6292	32	2	specific	specific	ADJ
ajst-6292	32	3	conditions	condition	NOUN
ajst-6292	32	4	are	be	AUX
ajst-6292	32	5	shown	show	VERB
ajst-6292	32	6	in	in	ADP
ajst-6292	32	7	fig	fig	NOUN
ajst-6292	32	8	.	.	PUNCT
ajst-6292	33	1	2	2	NUM
ajst-6292	33	2	.	.	NUM
ajst-6292	33	3	106	106	NUM
ajst-6292	33	4	figure	figure	NOUN
ajst-6292	33	5	2	2	NUM
ajst-6292	33	6	.	.	PUNCT
ajst-6292	34	1	synthetic	synthetic	ADJ
ajst-6292	34	2	route	route	NOUN
ajst-6292	34	3	of	of	ADP
ajst-6292	34	4	meriolin1	meriolin1	PROPN
ajst-6292	34	5	(	(	PUNCT
ajst-6292	34	6	a.s	a.s	PROPN
ajst-6292	34	7	.	.	PROPN
ajst-6292	34	8	karpov	karpov	PROPN
ajst-6292	34	9	et	et	PROPN
ajst-6292	34	10	al	al	PROPN
ajst-6292	34	11	)	)	PUNCT
ajst-6292	34	12	in	in	ADP
ajst-6292	34	13	2011	2011	NUM
ajst-6292	34	14	,	,	PUNCT
ajst-6292	34	15	e.	e.	PROPN
ajst-6292	34	16	merkul	merkul	PROPN
ajst-6292	34	17	et	et	PROPN
ajst-6292	34	18	al	al	PROPN
ajst-6292	34	19	.	.	PUNCT
ajst-6292	35	1	[	[	X
ajst-6292	35	2	10	10	NUM
ajst-6292	35	3	]	]	PUNCT
ajst-6292	35	4	synthesized	synthesize	VERB
ajst-6292	35	5	meriolin1	meriolin1	NOUN
ajst-6292	35	6	in	in	ADP
ajst-6292	35	7	only	only	ADV
ajst-6292	35	8	three	three	NUM
ajst-6292	35	9	steps	step	NOUN
ajst-6292	35	10	.	.	PUNCT
ajst-6292	36	1	on	on	ADP
ajst-6292	36	2	the	the	DET
ajst-6292	36	3	one	one	NUM
ajst-6292	36	4	hand	hand	NOUN
ajst-6292	36	5	,	,	PUNCT
ajst-6292	36	6	cs2co3	cs2co3	VERB
ajst-6292	36	7	was	be	AUX
ajst-6292	36	8	used	use	VERB
ajst-6292	36	9	to	to	PART
ajst-6292	36	10	promote	promote	VERB
ajst-6292	36	11	the	the	DET
ajst-6292	36	12	suzuki	suzuki	NOUN
ajst-6292	36	13	-	-	PUNCT
ajst-6292	36	14	miyaura	miyaura	NOUN
ajst-6292	36	15	reaction	reaction	NOUN
ajst-6292	36	16	,	,	PUNCT
ajst-6292	36	17	and	and	CCONJ
ajst-6292	36	18	in	in	ADP
ajst-6292	36	19	this	this	DET
ajst-6292	36	20	reaction	reaction	NOUN
ajst-6292	36	21	solution	solution	NOUN
ajst-6292	36	22	,	,	PUNCT
ajst-6292	36	23	the	the	DET
ajst-6292	36	24	protective	protective	ADJ
ajst-6292	36	25	group	group	NOUN
ajst-6292	36	26	of	of	ADP
ajst-6292	36	27	tert	tert	NOUN
ajst-6292	36	28	butoxycarbonyl	butoxycarbonyl	NOUN
ajst-6292	36	29	can	can	AUX
ajst-6292	36	30	be	be	AUX
ajst-6292	36	31	cracked	crack	VERB
ajst-6292	36	32	to	to	PART
ajst-6292	36	33	obtain	obtain	VERB
ajst-6292	36	34	the	the	DET
ajst-6292	36	35	product	product	NOUN
ajst-6292	36	36	directly	directly	ADV
ajst-6292	36	37	without	without	ADP
ajst-6292	36	38	additional	additional	ADJ
ajst-6292	36	39	deprotection	deprotection	NOUN
ajst-6292	36	40	steps	step	NOUN
ajst-6292	36	41	.	.	PUNCT
ajst-6292	37	1	as	as	SCONJ
ajst-6292	37	2	shown	show	VERB
ajst-6292	37	3	in	in	ADP
ajst-6292	37	4	fig	fig	NOUN
ajst-6292	37	5	.	.	PUNCT
ajst-6292	38	1	3	3	NUM
ajst-6292	38	2	,	,	PUNCT
ajst-6292	38	3	azaindolyl	azaindolyl	ADJ
ajst-6292	38	4	iodide	iodide	NOUN
ajst-6292	38	5	[	[	X
ajst-6292	38	6	11	11	NUM
ajst-6292	38	7	]	]	PUNCT
ajst-6292	38	8	protected	protect	VERB
ajst-6292	38	9	by	by	ADP
ajst-6292	38	10	tert	tert	NOUN
ajst-6292	38	11	butoxycarbonyl	butoxycarbonyl	NOUN
ajst-6292	38	12	was	be	AUX
ajst-6292	38	13	easy	easy	ADJ
ajst-6292	38	14	to	to	PART
ajst-6292	38	15	obtain	obtain	VERB
ajst-6292	38	16	and	and	CCONJ
ajst-6292	38	17	store	store	VERB
ajst-6292	38	18	,	,	PUNCT
ajst-6292	38	19	and	and	CCONJ
ajst-6292	38	20	can	can	AUX
ajst-6292	38	21	be	be	AUX
ajst-6292	38	22	used	use	VERB
ajst-6292	38	23	as	as	ADP
ajst-6292	38	24	an	an	DET
ajst-6292	38	25	important	important	ADJ
ajst-6292	38	26	part	part	NOUN
ajst-6292	38	27	of	of	ADP
ajst-6292	38	28	cross	cross	NOUN
ajst-6292	38	29	coupling	coupling	NOUN
ajst-6292	38	30	reaction	reaction	NOUN
ajst-6292	38	31	.	.	PUNCT
ajst-6292	39	1	since	since	SCONJ
ajst-6292	39	2	its	its	PRON
ajst-6292	39	3	direct	direct	ADJ
ajst-6292	39	4	coupling	coupling	NOUN
ajst-6292	39	5	with	with	ADP
ajst-6292	39	6	heteroarylboric	heteroarylboric	ADJ
ajst-6292	39	7	acid	acid	NOUN
ajst-6292	39	8	or	or	CCONJ
ajst-6292	39	9	ester	ester	NOUN
ajst-6292	39	10	would	would	AUX
ajst-6292	39	11	be	be	AUX
ajst-6292	39	12	limited	limit	VERB
ajst-6292	39	13	by	by	ADP
ajst-6292	39	14	the	the	DET
ajst-6292	39	15	latter	latter	ADJ
ajst-6292	39	16	,	,	PUNCT
ajst-6292	39	17	they	they	PRON
ajst-6292	39	18	first	first	ADV
ajst-6292	39	19	converted	convert	VERB
ajst-6292	39	20	the	the	DET
ajst-6292	39	21	iodide	iodide	NOUN
ajst-6292	39	22	into	into	ADP
ajst-6292	39	23	the	the	DET
ajst-6292	39	24	corresponding	corresponding	ADJ
ajst-6292	39	25	pinacol	pinacol	NOUN
ajst-6292	39	26	ester	ester	NOUN
ajst-6292	39	27	[	[	X
ajst-6292	39	28	12	12	NUM
ajst-6292	39	29	]	]	PUNCT
ajst-6292	39	30	,	,	PUNCT
ajst-6292	39	31	and	and	CCONJ
ajst-6292	39	32	then	then	ADV
ajst-6292	39	33	reacted	react	VERB
ajst-6292	39	34	with	with	ADP
ajst-6292	39	35	heterocyclic	heterocyclic	ADJ
ajst-6292	39	36	halide	halide	NOUN
ajst-6292	39	37	on	on	ADP
ajst-6292	39	38	the	the	DET
ajst-6292	39	39	way	way	NOUN
ajst-6292	39	40	,	,	PUNCT
ajst-6292	39	41	which	which	PRON
ajst-6292	39	42	makes	make	VERB
ajst-6292	39	43	it	it	PRON
ajst-6292	39	44	easier	easy	ADJ
ajst-6292	39	45	to	to	PART
ajst-6292	39	46	obtain	obtain	VERB
ajst-6292	39	47	the	the	DET
ajst-6292	39	48	final	final	ADJ
ajst-6292	39	49	product	product	NOUN
ajst-6292	39	50	.	.	PUNCT
ajst-6292	40	1	the	the	DET
ajst-6292	40	2	difference	difference	NOUN
ajst-6292	40	3	from	from	ADP
ajst-6292	40	4	the	the	DET
ajst-6292	40	5	previous	previous	ADJ
ajst-6292	40	6	route	route	NOUN
ajst-6292	40	7	is	be	AUX
ajst-6292	40	8	that	that	SCONJ
ajst-6292	40	9	one	one	NUM
ajst-6292	40	10	pot	pot	NOUN
ajst-6292	40	11	borylation/	borylation/	NUM
ajst-6292	40	12	suzuki	suzuki	NOUN
ajst-6292	40	13	-	-	PUNCT
ajst-6292	40	14	miyaura	miyaura	NOUN
ajst-6292	40	15	reaction	reaction	NOUN
ajst-6292	40	16	was	be	AUX
ajst-6292	40	17	used	use	VERB
ajst-6292	40	18	as	as	ADP
ajst-6292	40	19	the	the	DET
ajst-6292	40	20	key	key	ADJ
ajst-6292	40	21	step	step	NOUN
ajst-6292	40	22	,	,	PUNCT
ajst-6292	40	23	and	and	CCONJ
ajst-6292	40	24	meriolin1	meriolin1	NOUN
ajst-6292	40	25	was	be	AUX
ajst-6292	40	26	synthesized	synthesize	VERB
ajst-6292	40	27	in	in	ADP
ajst-6292	40	28	the	the	DET
ajst-6292	40	29	same	same	ADJ
ajst-6292	40	30	fourstep	fourstep	ADJ
ajst-6292	40	31	reaction	reaction	NOUN
ajst-6292	40	32	.	.	PUNCT
ajst-6292	41	1	the	the	DET
ajst-6292	41	2	price	price	NOUN
ajst-6292	41	3	of	of	ADP
ajst-6292	41	4	2	2	NUM
ajst-6292	41	5	-	-	PUNCT
ajst-6292	41	6	amino-4	amino-4	NOUN
ajst-6292	41	7	-	-	PUNCT
ajst-6292	41	8	chloropyrimidine	chloropyrimidine	NOUN
ajst-6292	41	9	and	and	CCONJ
ajst-6292	41	10	catalyst	catalyst	NOUN
ajst-6292	41	11	in	in	ADP
ajst-6292	41	12	the	the	DET
ajst-6292	41	13	last	last	ADJ
ajst-6292	41	14	step	step	NOUN
ajst-6292	41	15	of	of	ADP
ajst-6292	41	16	this	this	DET
ajst-6292	41	17	route	route	NOUN
ajst-6292	41	18	is	be	AUX
ajst-6292	41	19	relatively	relatively	ADV
ajst-6292	41	20	high	high	ADJ
ajst-6292	41	21	.	.	PUNCT
ajst-6292	42	1	figure	figure	NOUN
ajst-6292	42	2	3	3	NUM
ajst-6292	42	3	.	.	PUNCT
ajst-6292	43	1	synthetic	synthetic	ADJ
ajst-6292	43	2	route	route	NOUN
ajst-6292	43	3	of	of	ADP
ajst-6292	43	4	meriolin1(e	meriolin1(e	PROPN
ajst-6292	43	5	.	.	PROPN
ajst-6292	43	6	merkul	merkul	PROPN
ajst-6292	43	7	et	et	PROPN
ajst-6292	43	8	al	al	PROPN
ajst-6292	43	9	)	)	PUNCT
ajst-6292	43	10	in	in	ADP
ajst-6292	43	11	2014	2014	NUM
ajst-6292	43	12	,	,	PUNCT
ajst-6292	43	13	based	base	VERB
ajst-6292	43	14	on	on	ADP
ajst-6292	43	15	the	the	DET
ajst-6292	43	16	synthesis	synthesis	NOUN
ajst-6292	43	17	of	of	ADP
ajst-6292	43	18	meridianin	meridianin	ADJ
ajst-6292	43	19	,	,	PUNCT
ajst-6292	43	20	s.r	s.r	PROPN
ajst-6292	43	21	.	.	PROPN
ajst-6292	43	22	walker	walker	PROPN
ajst-6292	43	23	et	et	PROPN
ajst-6292	43	24	al	al	PROPN
ajst-6292	44	1	[	[	X
ajst-6292	44	2	13	13	NUM
ajst-6292	44	3	]	]	PUNCT
ajst-6292	44	4	took	take	VERB
ajst-6292	44	5	2	2	NUM
ajst-6292	44	6	-	-	PUNCT
ajst-6292	44	7	amino-3	amino-3	NOUN
ajst-6292	44	8	-	-	PUNCT
ajst-6292	44	9	iodopyridine	iodopyridine	NOUN
ajst-6292	44	10	as	as	ADP
ajst-6292	44	11	raw	raw	ADJ
ajst-6292	44	12	material	material	NOUN
ajst-6292	44	13	,	,	PUNCT
ajst-6292	44	14	underwent	underwent	NOUN
ajst-6292	44	15	acylation	acylation	NOUN
ajst-6292	44	16	reaction	reaction	NOUN
ajst-6292	44	17	,	,	PUNCT
ajst-6292	44	18	and	and	CCONJ
ajst-6292	44	19	then	then	ADV
ajst-6292	44	20	reacted	react	VERB
ajst-6292	44	21	with	with	ADP
ajst-6292	44	22	iodide	iodide	NOUN
ajst-6292	44	23	under	under	ADP
ajst-6292	44	24	the	the	DET
ajst-6292	44	25	action	action	NOUN
ajst-6292	44	26	of	of	ADP
ajst-6292	44	27	metal	metal	NOUN
ajst-6292	44	28	catalyst	catalyst	NOUN
ajst-6292	44	29	to	to	PART
ajst-6292	44	30	obtain	obtain	VERB
ajst-6292	44	31	the	the	DET
ajst-6292	44	32	parent	parent	NOUN
ajst-6292	44	33	nuclear	nuclear	ADJ
ajst-6292	44	34	skeleton	skeleton	NOUN
ajst-6292	44	35	.	.	PUNCT
ajst-6292	45	1	finally	finally	ADV
ajst-6292	45	2	,	,	PUNCT
ajst-6292	45	3	the	the	DET
ajst-6292	45	4	protective	protective	ADJ
ajst-6292	45	5	group	group	NOUN
ajst-6292	45	6	was	be	AUX
ajst-6292	45	7	removed	remove	VERB
ajst-6292	45	8	as	as	ADP
ajst-6292	45	9	a	a	DET
ajst-6292	45	10	whole	whole	NOUN
ajst-6292	45	11	by	by	ADP
ajst-6292	45	12	one	one	NUM
ajst-6292	45	13	pot	pot	NOUN
ajst-6292	45	14	method	method	NOUN
ajst-6292	45	15	to	to	PART
ajst-6292	45	16	obtain	obtain	VERB
ajst-6292	45	17	compound	compound	NOUN
ajst-6292	45	18	meriolin1	meriolin1	NOUN
ajst-6292	45	19	.	.	PUNCT
ajst-6292	46	1	this	this	DET
ajst-6292	46	2	method	method	NOUN
ajst-6292	46	3	is	be	AUX
ajst-6292	46	4	not	not	PART
ajst-6292	46	5	only	only	ADV
ajst-6292	46	6	complex	complex	ADJ
ajst-6292	46	7	and	and	CCONJ
ajst-6292	46	8	cumbersome	cumbersome	ADJ
ajst-6292	46	9	,	,	PUNCT
ajst-6292	46	10	but	but	CCONJ
ajst-6292	46	11	also	also	ADV
ajst-6292	46	12	the	the	DET
ajst-6292	46	13	raw	raw	ADJ
ajst-6292	46	14	material	material	NOUN
ajst-6292	46	15	price	price	NOUN
ajst-6292	46	16	is	be	AUX
ajst-6292	46	17	six	six	NUM
ajst-6292	46	18	times	time	NOUN
ajst-6292	46	19	that	that	PRON
ajst-6292	46	20	of	of	ADP
ajst-6292	46	21	the	the	DET
ajst-6292	46	22	previous	previous	ADJ
ajst-6292	46	23	two	two	NUM
ajst-6292	46	24	routes	route	NOUN
ajst-6292	46	25	.	.	PUNCT
ajst-6292	47	1	in	in	ADP
ajst-6292	47	2	addition	addition	NOUN
ajst-6292	47	3	,	,	PUNCT
ajst-6292	47	4	the	the	DET
ajst-6292	47	5	metal	metal	NOUN
ajst-6292	47	6	catalyst	catalyst	NOUN
ajst-6292	47	7	is	be	AUX
ajst-6292	47	8	used	use	VERB
ajst-6292	47	9	,	,	PUNCT
ajst-6292	47	10	so	so	CCONJ
ajst-6292	47	11	the	the	DET
ajst-6292	47	12	reaction	reaction	NOUN
ajst-6292	47	13	conditions	condition	NOUN
ajst-6292	47	14	are	be	AUX
ajst-6292	47	15	relatively	relatively	ADV
ajst-6292	47	16	strict	strict	ADJ
ajst-6292	47	17	,	,	PUNCT
ajst-6292	47	18	which	which	PRON
ajst-6292	47	19	has	have	VERB
ajst-6292	47	20	no	no	DET
ajst-6292	47	21	advantage	advantage	NOUN
ajst-6292	47	22	over	over	ADP
ajst-6292	47	23	the	the	DET
ajst-6292	47	24	previous	previous	ADJ
ajst-6292	47	25	two	two	NUM
ajst-6292	47	26	routes	route	NOUN
ajst-6292	47	27	.	.	PUNCT
ajst-6292	48	1	the	the	DET
ajst-6292	48	2	specific	specific	ADJ
ajst-6292	48	3	conditions	condition	NOUN
ajst-6292	48	4	are	be	AUX
ajst-6292	48	5	shown	show	VERB
ajst-6292	48	6	in	in	ADP
ajst-6292	48	7	fig.4	fig.4	PROPN
ajst-6292	48	8	.	.	PROPN
ajst-6292	48	9	figure	figure	NOUN
ajst-6292	48	10	4	4	NUM
ajst-6292	48	11	.	.	PUNCT
ajst-6292	49	1	synthetic	synthetic	ADJ
ajst-6292	49	2	route	route	NOUN
ajst-6292	49	3	of	of	ADP
ajst-6292	49	4	meriolin1(s.r	meriolin1(s.r	PROPN
ajst-6292	49	5	.	.	PROPN
ajst-6292	49	6	walker	walker	PROPN
ajst-6292	49	7	et	et	PROPN
ajst-6292	49	8	al	al	PROPN
ajst-6292	49	9	)	)	PUNCT
ajst-6292	49	10	on	on	ADP
ajst-6292	49	11	this	this	DET
ajst-6292	49	12	basis	basis	NOUN
ajst-6292	49	13	,	,	PUNCT
ajst-6292	49	14	adhering	adhere	VERB
ajst-6292	49	15	to	to	ADP
ajst-6292	49	16	the	the	DET
ajst-6292	49	17	concept	concept	NOUN
ajst-6292	49	18	of	of	ADP
ajst-6292	49	19	innovation	innovation	NOUN
ajst-6292	49	20	,	,	PUNCT
ajst-6292	49	21	we	we	PRON
ajst-6292	49	22	designed	design	VERB
ajst-6292	49	23	an	an	DET
ajst-6292	49	24	economic	economic	ADJ
ajst-6292	49	25	and	and	CCONJ
ajst-6292	49	26	effective	effective	ADJ
ajst-6292	49	27	synthetic	synthetic	ADJ
ajst-6292	49	28	route	route	NOUN
ajst-6292	49	29	.	.	PUNCT
ajst-6292	50	1	2	2	X
ajst-6292	50	2	.	.	NOUN
ajst-6292	50	3	results	result	NOUN
ajst-6292	50	4	and	and	CCONJ
ajst-6292	50	5	discussion	discussion	NOUN
ajst-6292	50	6	using	use	VERB
ajst-6292	50	7	7	7	NUM
ajst-6292	50	8	-	-	PUNCT
ajst-6292	50	9	azaindole	azaindole	NOUN
ajst-6292	50	10	as	as	ADP
ajst-6292	50	11	raw	raw	ADJ
ajst-6292	50	12	material	material	NOUN
ajst-6292	50	13	,	,	PUNCT
ajst-6292	50	14	the	the	DET
ajst-6292	50	15	compound	compound	NOUN
ajst-6292	50	16	(	(	PUNCT
ajst-6292	50	17	2	2	NUM
ajst-6292	50	18	)	)	PUNCT
ajst-6292	50	19	was	be	AUX
ajst-6292	50	20	obtained	obtain	VERB
ajst-6292	50	21	by	by	ADP
ajst-6292	50	22	friedel	friedel	PROPN
ajst-6292	50	23	-	-	PUNCT
ajst-6292	50	24	crafts	crafts	PROPN
ajst-6292	50	25	acylation	acylation	NOUN
ajst-6292	50	26	reaction	reaction	NOUN
ajst-6292	50	27	in	in	ADP
ajst-6292	50	28	the	the	DET
ajst-6292	50	29	first	first	ADJ
ajst-6292	50	30	step	step	NOUN
ajst-6292	50	31	.	.	PUNCT
ajst-6292	51	1	in	in	ADP
ajst-6292	51	2	the	the	DET
ajst-6292	51	3	second	second	ADJ
ajst-6292	51	4	step	step	NOUN
ajst-6292	51	5	,	,	PUNCT
ajst-6292	51	6	potassium	potassium	NOUN
ajst-6292	51	7	tert	tert	NOUN
ajst-6292	51	8	-	-	PUNCT
ajst-6292	51	9	butanol	butanol	NOUN
ajst-6292	51	10	was	be	AUX
ajst-6292	51	11	used	use	VERB
ajst-6292	51	12	to	to	PART
ajst-6292	51	13	extract	extract	VERB
ajst-6292	51	14	hydrogen	hydrogen	NOUN
ajst-6292	51	15	.	.	PUNCT
ajst-6292	52	1	in	in	ADP
ajst-6292	52	2	order	order	NOUN
ajst-6292	52	3	to	to	PART
ajst-6292	52	4	avoid	avoid	VERB
ajst-6292	52	5	secondary	secondary	ADJ
ajst-6292	52	6	amine	amine	NOUN
ajst-6292	52	7	being	be	AUX
ajst-6292	52	8	affected	affect	VERB
ajst-6292	52	9	in	in	ADP
ajst-6292	52	10	the	the	DET
ajst-6292	52	11	follow	follow	VERB
ajst-6292	52	12	-	-	PUNCT
ajst-6292	52	13	up	up	ADP
ajst-6292	52	14	reaction	reaction	NOUN
ajst-6292	52	15	,	,	PUNCT
ajst-6292	52	16	potassium	potassium	NOUN
ajst-6292	52	17	t	t	PROPN
ajst-6292	52	18	-	-	PUNCT
ajst-6292	52	19	butoxide	butoxide	NOUN
ajst-6292	52	20	was	be	AUX
ajst-6292	52	21	used	use	VERB
ajst-6292	52	22	to	to	PART
ajst-6292	52	23	protect	protect	VERB
ajst-6292	52	24	the	the	DET
ajst-6292	52	25	amino	amino	NOUN
ajst-6292	52	26	group	group	NOUN
ajst-6292	52	27	,	,	PUNCT
ajst-6292	52	28	and	and	CCONJ
ajst-6292	52	29	then	then	ADV
ajst-6292	52	30	the	the	DET
ajst-6292	52	31	compound	compound	NOUN
ajst-6292	52	32	(	(	PUNCT
ajst-6292	52	33	3	3	NUM
ajst-6292	52	34	)	)	PUNCT
ajst-6292	52	35	was	be	AUX
ajst-6292	52	36	obtained	obtain	VERB
ajst-6292	52	37	.	.	PUNCT
ajst-6292	53	1	then	then	ADV
ajst-6292	53	2	the	the	DET
ajst-6292	53	3	compound	compound	NOUN
ajst-6292	53	4	(	(	PUNCT
ajst-6292	53	5	4	4	NUM
ajst-6292	53	6	)	)	PUNCT
ajst-6292	53	7	was	be	AUX
ajst-6292	53	8	obtained	obtain	VERB
ajst-6292	53	9	by	by	ADP
ajst-6292	53	10	condensation	condensation	NOUN
ajst-6292	53	11	with	with	ADP
ajst-6292	53	12	dmf	dmf	PROPN
ajst-6292	53	13	-	-	PROPN
ajst-6292	53	14	dma	dma	PROPN
ajst-6292	53	15	[	[	X
ajst-6292	53	16	14	14	NUM
ajst-6292	53	17	-	-	SYM
ajst-6292	53	18	15	15	NUM
ajst-6292	53	19	]	]	PUNCT
ajst-6292	53	20	,	,	PUNCT
ajst-6292	53	21	and	and	CCONJ
ajst-6292	53	22	meriolin1	meriolin1	NOUN
ajst-6292	53	23	was	be	AUX
ajst-6292	53	24	obtained	obtain	VERB
ajst-6292	53	25	by	by	ADP
ajst-6292	53	26	cyclization	cyclization	NOUN
ajst-6292	53	27	of	of	ADP
ajst-6292	53	28	the	the	DET
ajst-6292	53	29	compound	compound	NOUN
ajst-6292	53	30	(	(	PUNCT
ajst-6292	53	31	4	4	NUM
ajst-6292	53	32	)	)	PUNCT
ajst-6292	53	33	with	with	ADP
ajst-6292	53	34	guanidine	guanidine	ADJ
ajst-6292	53	35	hydrochloride	hydrochloride	NOUN
ajst-6292	53	36	in	in	ADP
ajst-6292	53	37	an	an	DET
ajst-6292	53	38	overall	overall	ADJ
ajst-6292	53	39	yield	yield	NOUN
ajst-6292	53	40	of	of	ADP
ajst-6292	53	41	27.58	27.58	NUM
ajst-6292	53	42	%	%	NOUN
ajst-6292	53	43	.	.	PUNCT
ajst-6292	54	1	the	the	DET
ajst-6292	54	2	specific	specific	ADJ
ajst-6292	54	3	conditions	condition	NOUN
ajst-6292	54	4	are	be	AUX
ajst-6292	54	5	shown	show	VERB
ajst-6292	54	6	in	in	ADP
ajst-6292	54	7	fig.5	fig.5	PROPN
ajst-6292	54	8	.	.	PUNCT
ajst-6292	55	1	in	in	ADP
ajst-6292	55	2	the	the	DET
ajst-6292	55	3	process	process	NOUN
ajst-6292	55	4	of	of	ADP
ajst-6292	55	5	synthesizing	synthesize	VERB
ajst-6292	55	6	meriolin1	meriolin1	NOUN
ajst-6292	55	7	,	,	PUNCT
ajst-6292	55	8	in	in	ADP
ajst-6292	55	9	order	order	NOUN
ajst-6292	55	10	to	to	PART
ajst-6292	55	11	ensure	ensure	VERB
ajst-6292	55	12	innovation	innovation	NOUN
ajst-6292	55	13	,	,	PUNCT
ajst-6292	55	14	we	we	PRON
ajst-6292	55	15	compared	compare	VERB
ajst-6292	55	16	with	with	ADP
ajst-6292	55	17	the	the	DET
ajst-6292	55	18	above	above	ADJ
ajst-6292	55	19	synthetic	synthetic	ADJ
ajst-6292	55	20	route	route	NOUN
ajst-6292	55	21	to	to	ADP
ajst-6292	55	22	107	107	NUM
ajst-6292	55	23	avoid	avoid	VERB
ajst-6292	55	24	some	some	DET
ajst-6292	55	25	disadvantages	disadvantage	NOUN
ajst-6292	55	26	in	in	ADP
ajst-6292	55	27	other	other	ADJ
ajst-6292	55	28	’	'	PUNCT
ajst-6292	55	29	routes	route	NOUN
ajst-6292	55	30	,	,	PUNCT
ajst-6292	55	31	such	such	ADJ
ajst-6292	55	32	as	as	ADP
ajst-6292	55	33	the	the	DET
ajst-6292	55	34	use	use	NOUN
ajst-6292	55	35	of	of	ADP
ajst-6292	55	36	expensive	expensive	ADJ
ajst-6292	55	37	raw	raw	ADJ
ajst-6292	55	38	materials	material	NOUN
ajst-6292	55	39	and	and	CCONJ
ajst-6292	55	40	metal	metal	NOUN
ajst-6292	55	41	catalysts	catalyst	NOUN
ajst-6292	55	42	,	,	PUNCT
ajst-6292	55	43	complex	complex	ADJ
ajst-6292	55	44	conditions	condition	NOUN
ajst-6292	55	45	and	and	CCONJ
ajst-6292	55	46	post	post	NOUN
ajst-6292	55	47	-	-	NOUN
ajst-6292	55	48	treatment	treatment	NOUN
ajst-6292	55	49	,	,	PUNCT
ajst-6292	55	50	and	and	CCONJ
ajst-6292	55	51	reagents	reagent	NOUN
ajst-6292	55	52	with	with	ADP
ajst-6292	55	53	strong	strong	ADJ
ajst-6292	55	54	irritation	irritation	NOUN
ajst-6292	55	55	or	or	CCONJ
ajst-6292	55	56	toxicity	toxicity	NOUN
ajst-6292	55	57	,	,	PUNCT
ajst-6292	55	58	etc	etc	X
ajst-6292	55	59	.	.	X
ajst-6292	55	60	in	in	ADP
ajst-6292	55	61	the	the	DET
ajst-6292	55	62	preparation	preparation	NOUN
ajst-6292	55	63	of	of	ADP
ajst-6292	55	64	compound	compound	NOUN
ajst-6292	55	65	(	(	PUNCT
ajst-6292	55	66	2	2	NUM
ajst-6292	55	67	)	)	PUNCT
ajst-6292	55	68	,	,	PUNCT
ajst-6292	55	69	when	when	SCONJ
ajst-6292	55	70	acetyl	acetyl	NOUN
ajst-6292	55	71	chloride	chloride	NOUN
ajst-6292	55	72	was	be	AUX
ajst-6292	55	73	used	use	VERB
ajst-6292	55	74	as	as	ADP
ajst-6292	55	75	acylating	acylate	VERB
ajst-6292	55	76	agent	agent	NOUN
ajst-6292	55	77	,	,	PUNCT
ajst-6292	55	78	the	the	DET
ajst-6292	55	79	reaction	reaction	NOUN
ajst-6292	55	80	conversion	conversion	NOUN
ajst-6292	55	81	was	be	AUX
ajst-6292	55	82	complete	complete	ADJ
ajst-6292	55	83	and	and	CCONJ
ajst-6292	55	84	the	the	DET
ajst-6292	55	85	yield	yield	NOUN
ajst-6292	55	86	was	be	AUX
ajst-6292	55	87	80.44	80.44	NUM
ajst-6292	55	88	%	%	NOUN
ajst-6292	55	89	.	.	PUNCT
ajst-6292	56	1	in	in	ADP
ajst-6292	56	2	the	the	DET
ajst-6292	56	3	preparation	preparation	NOUN
ajst-6292	56	4	of	of	ADP
ajst-6292	56	5	compound	compound	NOUN
ajst-6292	56	6	(	(	PUNCT
ajst-6292	56	7	3	3	NUM
ajst-6292	56	8	)	)	PUNCT
ajst-6292	56	9	,	,	PUNCT
ajst-6292	56	10	the	the	DET
ajst-6292	56	11	protection	protection	NOUN
ajst-6292	56	12	of	of	ADP
ajst-6292	56	13	boc	boc	NOUN
ajst-6292	56	14	was	be	AUX
ajst-6292	56	15	not	not	PART
ajst-6292	56	16	conducive	conducive	ADJ
ajst-6292	56	17	to	to	ADP
ajst-6292	56	18	the	the	DET
ajst-6292	56	19	next	next	ADJ
ajst-6292	56	20	reaction	reaction	NOUN
ajst-6292	56	21	.	.	PUNCT
ajst-6292	57	1	in	in	ADP
ajst-6292	57	2	this	this	DET
ajst-6292	57	3	step	step	NOUN
ajst-6292	57	4	,	,	PUNCT
ajst-6292	57	5	tosyl	tosyl	PROPN
ajst-6292	57	6	was	be	AUX
ajst-6292	57	7	selected	select	VERB
ajst-6292	57	8	as	as	ADP
ajst-6292	57	9	the	the	DET
ajst-6292	57	10	protective	protective	ADJ
ajst-6292	57	11	group	group	NOUN
ajst-6292	57	12	,	,	PUNCT
ajst-6292	57	13	and	and	CCONJ
ajst-6292	57	14	the	the	DET
ajst-6292	57	15	yield	yield	NOUN
ajst-6292	57	16	was	be	AUX
ajst-6292	57	17	99.00	99.00	NUM
ajst-6292	57	18	%	%	NOUN
ajst-6292	57	19	.	.	PUNCT
ajst-6292	58	1	in	in	ADP
ajst-6292	58	2	the	the	DET
ajst-6292	58	3	preparation	preparation	NOUN
ajst-6292	58	4	of	of	ADP
ajst-6292	58	5	compound	compound	NOUN
ajst-6292	58	6	(	(	PUNCT
ajst-6292	58	7	4	4	NUM
ajst-6292	58	8	)	)	PUNCT
ajst-6292	58	9	,	,	PUNCT
ajst-6292	58	10	dmf	dmf	PROPN
ajst-6292	58	11	-	-	PUNCT
ajst-6292	58	12	dma	dma	PROPN
ajst-6292	58	13	was	be	AUX
ajst-6292	58	14	directly	directly	ADV
ajst-6292	58	15	used	use	VERB
ajst-6292	58	16	as	as	ADP
ajst-6292	58	17	solvent	solvent	ADJ
ajst-6292	58	18	and	and	CCONJ
ajst-6292	58	19	reacted	react	VERB
ajst-6292	58	20	at	at	ADP
ajst-6292	58	21	room	room	NOUN
ajst-6292	58	22	temperature	temperature	NOUN
ajst-6292	58	23	and	and	CCONJ
ajst-6292	58	24	then	then	ADV
ajst-6292	58	25	at	at	ADP
ajst-6292	58	26	high	high	ADJ
ajst-6292	58	27	temperature	temperature	NOUN
ajst-6292	58	28	.	.	PUNCT
ajst-6292	59	1	the	the	DET
ajst-6292	59	2	yield	yield	NOUN
ajst-6292	59	3	was	be	AUX
ajst-6292	59	4	61.70	61.70	NUM
ajst-6292	59	5	%	%	NOUN
ajst-6292	59	6	.	.	PUNCT
ajst-6292	60	1	in	in	ADP
ajst-6292	60	2	the	the	DET
ajst-6292	60	3	preparation	preparation	NOUN
ajst-6292	60	4	of	of	ADP
ajst-6292	60	5	meriolin1	meriolin1	PROPN
ajst-6292	60	6	,	,	PUNCT
ajst-6292	60	7	the	the	DET
ajst-6292	60	8	dosage	dosage	NOUN
ajst-6292	60	9	of	of	ADP
ajst-6292	60	10	guanidine	guanidine	ADJ
ajst-6292	60	11	hydrochloride	hydrochloride	NOUN
ajst-6292	60	12	was	be	AUX
ajst-6292	60	13	selected	select	VERB
ajst-6292	60	14	.	.	PUNCT
ajst-6292	61	1	when	when	SCONJ
ajst-6292	61	2	the	the	DET
ajst-6292	61	3	equivalent	equivalent	NOUN
ajst-6292	61	4	of	of	ADP
ajst-6292	61	5	guanidine	guanidine	ADJ
ajst-6292	61	6	hydrochloride	hydrochloride	NOUN
ajst-6292	61	7	was	be	AUX
ajst-6292	61	8	5.0	5.0	NUM
ajst-6292	61	9	,	,	PUNCT
ajst-6292	61	10	the	the	DET
ajst-6292	61	11	yield	yield	NOUN
ajst-6292	61	12	was	be	AUX
ajst-6292	61	13	56.14	56.14	NUM
ajst-6292	61	14	%	%	NOUN
ajst-6292	61	15	.	.	PUNCT
ajst-6292	62	1	figure	figure	NOUN
ajst-6292	62	2	5	5	NUM
ajst-6292	62	3	.	.	PUNCT
ajst-6292	63	1	synthetic	synthetic	ADJ
ajst-6292	63	2	route	route	NOUN
ajst-6292	63	3	of	of	ADP
ajst-6292	63	4	meriolin1	meriolin1	PROPN
ajst-6292	63	5	3	3	NUM
ajst-6292	63	6	.	.	PUNCT
ajst-6292	63	7	experimental	experimental	ADJ
ajst-6292	63	8	section	section	NOUN
ajst-6292	63	9	3.1	3.1	NUM
ajst-6292	63	10	.	.	PUNCT
ajst-6292	64	1	materials	material	NOUN
ajst-6292	64	2	all	all	DET
ajst-6292	64	3	chemicals	chemical	NOUN
ajst-6292	64	4	provided	provide	VERB
ajst-6292	64	5	by	by	ADP
ajst-6292	64	6	commercial	commercial	ADJ
ajst-6292	64	7	sellers	seller	NOUN
ajst-6292	64	8	were	be	AUX
ajst-6292	64	9	analytical	analytical	ADJ
ajst-6292	64	10	grade	grade	NOUN
ajst-6292	64	11	,	,	PUNCT
ajst-6292	64	12	which	which	PRON
ajst-6292	64	13	can	can	AUX
ajst-6292	64	14	be	be	AUX
ajst-6292	64	15	used	use	VERB
ajst-6292	64	16	directly	directly	ADV
ajst-6292	64	17	without	without	ADP
ajst-6292	64	18	purification	purification	NOUN
ajst-6292	64	19	.	.	PUNCT
ajst-6292	65	1	1h	1h	NUM
ajst-6292	65	2	nmr	nmr	NOUN
ajst-6292	65	3	and	and	CCONJ
ajst-6292	65	4	13c	13c	NOUN
ajst-6292	65	5	nmr	nmr	NOUN
ajst-6292	65	6	spectra	spectra	NOUN
ajst-6292	65	7	were	be	AUX
ajst-6292	65	8	recorded	record	VERB
ajst-6292	65	9	in	in	ADP
ajst-6292	65	10	cdcl3	cdcl3	NOUN
ajst-6292	65	11	or	or	CCONJ
ajst-6292	65	12	dmso	dmso	NOUN
ajst-6292	65	13	with	with	ADP
ajst-6292	65	14	tms	tms	PROPN
ajst-6292	65	15	as	as	ADP
ajst-6292	65	16	internal	internal	ADJ
ajst-6292	65	17	standard	standard	NOUN
ajst-6292	65	18	using	use	VERB
ajst-6292	65	19	a	a	DET
ajst-6292	65	20	bruker	bruker	NOUN
ajst-6292	65	21	400	400	NUM
ajst-6292	65	22	mhz	mhz	NOUN
ajst-6292	65	23	spectrometer	spectrometer	NOUN
ajst-6292	65	24	.	.	PUNCT
ajst-6292	66	1	3.2	3.2	NUM
ajst-6292	66	2	.	.	PUNCT
ajst-6292	67	1	general	general	ADJ
ajst-6292	67	2	procedures	procedure	NOUN
ajst-6292	67	3	3.2.1	3.2.1	NUM
ajst-6292	67	4	.	.	PUNCT
ajst-6292	68	1	preparation	preparation	NOUN
ajst-6292	68	2	of	of	ADP
ajst-6292	68	3	compound	compound	NOUN
ajst-6292	68	4	3	3	NUM
ajst-6292	68	5	-	-	PUNCT
ajst-6292	68	6	acetyl-7	acetyl-7	NOUN
ajst-6292	68	7	-	-	PUNCT
ajst-6292	68	8	azaindole	azaindole	NOUN
ajst-6292	68	9	(	(	PUNCT
ajst-6292	68	10	2	2	X
ajst-6292	68	11	)	)	PUNCT
ajst-6292	68	12	added	add	VERB
ajst-6292	68	13	anhydrous	anhydrous	ADJ
ajst-6292	68	14	alcl3	alcl3	NOUN
ajst-6292	69	1	(	(	PUNCT
ajst-6292	69	2	22.4	22.4	NUM
ajst-6292	69	3	g	g	NOUN
ajst-6292	69	4	,	,	PUNCT
ajst-6292	69	5	167.98	167.98	NUM
ajst-6292	69	6	mmol	mmol	NOUN
ajst-6292	69	7	)	)	PUNCT
ajst-6292	69	8	and	and	CCONJ
ajst-6292	69	9	anhydrous	anhydrous	ADJ
ajst-6292	69	10	ch2cl2	ch2cl2	X
ajst-6292	69	11	(	(	PUNCT
ajst-6292	69	12	40	40	NUM
ajst-6292	69	13	ml	ml	NOUN
ajst-6292	69	14	)	)	PUNCT
ajst-6292	69	15	into	into	ADP
ajst-6292	69	16	a	a	DET
ajst-6292	69	17	100	100	NUM
ajst-6292	69	18	ml	ml	NOUN
ajst-6292	69	19	round	round	ADJ
ajst-6292	69	20	bottomed	bottom	VERB
ajst-6292	69	21	flask	flask	NOUN
ajst-6292	69	22	.	.	PUNCT
ajst-6292	70	1	after	after	ADP
ajst-6292	70	2	stirring	stir	VERB
ajst-6292	70	3	for	for	ADP
ajst-6292	70	4	5	5	NUM
ajst-6292	70	5	min	min	NOUN
ajst-6292	70	6	,	,	PUNCT
ajst-6292	70	7	added	add	VERB
ajst-6292	70	8	7	7	NUM
ajst-6292	70	9	-	-	PUNCT
ajst-6292	70	10	azaindole	azaindole	NOUN
ajst-6292	70	11	(	(	PUNCT
ajst-6292	70	12	10	10	NUM
ajst-6292	70	13	g	g	NOUN
ajst-6292	70	14	,	,	PUNCT
ajst-6292	70	15	84.64	84.64	NUM
ajst-6292	70	16	mmol	mmol	NOUN
ajst-6292	70	17	)	)	PUNCT
ajst-6292	70	18	for	for	ADP
ajst-6292	70	19	n2	n2	ADJ
ajst-6292	70	20	protection	protection	NOUN
ajst-6292	70	21	.	.	PUNCT
ajst-6292	71	1	slowly	slowly	ADV
ajst-6292	71	2	added	add	VERB
ajst-6292	71	3	acetyl	acetyl	NOUN
ajst-6292	71	4	chloride	chloride	NOUN
ajst-6292	71	5	(	(	PUNCT
ajst-6292	71	6	19.92	19.92	NUM
ajst-6292	71	7	g	g	NOUN
ajst-6292	71	8	,	,	PUNCT
ajst-6292	71	9	253.98	253.98	NUM
ajst-6292	71	10	mmol	mmol	NOUN
ajst-6292	71	11	)	)	PUNCT
ajst-6292	71	12	in	in	ADP
ajst-6292	71	13	an	an	DET
ajst-6292	71	14	ice	ice	NOUN
ajst-6292	71	15	bath	bath	NOUN
ajst-6292	71	16	and	and	CCONJ
ajst-6292	71	17	moved	move	VERB
ajst-6292	71	18	it	it	PRON
ajst-6292	71	19	to	to	PART
ajst-6292	71	20	room	room	VERB
ajst-6292	71	21	temperature	temperature	NOUN
ajst-6292	71	22	for	for	ADP
ajst-6292	71	23	stirring	stirring	NOUN
ajst-6292	71	24	.	.	PUNCT
ajst-6292	72	1	after	after	ADP
ajst-6292	72	2	12	12	NUM
ajst-6292	72	3	hours	hour	NOUN
ajst-6292	72	4	of	of	ADP
ajst-6292	72	5	reaction	reaction	NOUN
ajst-6292	72	6	,	,	PUNCT
ajst-6292	72	7	the	the	DET
ajst-6292	72	8	reaction	reaction	NOUN
ajst-6292	72	9	was	be	AUX
ajst-6292	72	10	completed	complete	VERB
ajst-6292	72	11	by	by	ADP
ajst-6292	72	12	tlc	tlc	PROPN
ajst-6292	72	13	.	.	PUNCT
ajst-6292	73	1	the	the	DET
ajst-6292	73	2	reaction	reaction	NOUN
ajst-6292	73	3	solution	solution	NOUN
ajst-6292	73	4	was	be	AUX
ajst-6292	73	5	slowly	slowly	ADV
ajst-6292	73	6	dripped	drip	VERB
ajst-6292	73	7	into	into	ADP
ajst-6292	73	8	100	100	NUM
ajst-6292	73	9	ml	ml	NOUN
ajst-6292	73	10	ice	ice	NOUN
ajst-6292	73	11	water	water	NOUN
ajst-6292	73	12	to	to	PART
ajst-6292	73	13	quench	quench	VERB
ajst-6292	73	14	,	,	PUNCT
ajst-6292	73	15	a	a	DET
ajst-6292	73	16	large	large	ADJ
ajst-6292	73	17	number	number	NOUN
ajst-6292	73	18	of	of	ADP
ajst-6292	73	19	solids	solid	NOUN
ajst-6292	73	20	were	be	AUX
ajst-6292	73	21	precipitated	precipitate	VERB
ajst-6292	73	22	in	in	ADP
ajst-6292	73	23	the	the	DET
ajst-6292	73	24	process	process	NOUN
ajst-6292	73	25	.	.	PUNCT
ajst-6292	74	1	after	after	SCONJ
ajst-6292	74	2	the	the	DET
ajst-6292	74	3	solid	solid	ADJ
ajst-6292	74	4	was	be	AUX
ajst-6292	74	5	precipitated	precipitate	VERB
ajst-6292	74	6	,	,	PUNCT
ajst-6292	74	7	the	the	DET
ajst-6292	74	8	filter	filter	NOUN
ajst-6292	74	9	cake	cake	NOUN
ajst-6292	74	10	was	be	AUX
ajst-6292	74	11	collected	collect	VERB
ajst-6292	74	12	and	and	CCONJ
ajst-6292	74	13	dried	dry	VERB
ajst-6292	74	14	,	,	PUNCT
ajst-6292	74	15	and	and	CCONJ
ajst-6292	74	16	then	then	ADV
ajst-6292	74	17	10.91	10.91	NUM
ajst-6292	74	18	g	g	NOUN
ajst-6292	74	19	of	of	ADP
ajst-6292	74	20	light	light	ADJ
ajst-6292	74	21	yellow	yellow	ADJ
ajst-6292	74	22	solid	solid	ADJ
ajst-6292	74	23	was	be	AUX
ajst-6292	74	24	obtained	obtain	VERB
ajst-6292	74	25	with	with	ADP
ajst-6292	74	26	a	a	DET
ajst-6292	74	27	yield	yield	NOUN
ajst-6292	74	28	of	of	ADP
ajst-6292	74	29	80.44%.1h	80.44%.1h	NUM
ajst-6292	74	30	nmr	nmr	NOUN
ajst-6292	74	31	(	(	PUNCT
ajst-6292	74	32	400	400	NUM
ajst-6292	74	33	mhz	mhz	NOUN
ajst-6292	74	34	,	,	PUNCT
ajst-6292	74	35	dmso	dmso	NOUN
ajst-6292	74	36	):	):	PUNCT
ajst-6292	74	37	δ	δ	PROPN
ajst-6292	74	38	12.52(bs	12.52(bs	PROPN
ajst-6292	74	39	,	,	PUNCT
ajst-6292	74	40	1	1	NUM
ajst-6292	74	41	h	h	NOUN
ajst-6292	74	42	)	)	PUNCT
ajst-6292	74	43	,	,	PUNCT
ajst-6292	74	44	8.47	8.47	NUM
ajst-6292	74	45	(	(	PUNCT
ajst-6292	74	46	dd	dd	NOUN
ajst-6292	74	47	,	,	PUNCT
ajst-6292	74	48	2	2	NUM
ajst-6292	74	49	h	h	NOUN
ajst-6292	74	50	,	,	PUNCT
ajst-6292	74	51	j	j	PROPN
ajst-6292	75	1	=	=	SYM
ajst-6292	75	2	9.6	9.6	NUM
ajst-6292	75	3	hz	hz	NOUN
ajst-6292	75	4	)	)	PUNCT
ajst-6292	75	5	,	,	PUNCT
ajst-6292	75	6	8.32	8.32	NUM
ajst-6292	75	7	(	(	PUNCT
ajst-6292	75	8	dd	dd	NOUN
ajst-6292	75	9	,	,	PUNCT
ajst-6292	75	10	1	1	NUM
ajst-6292	75	11	h	h	NOUN
ajst-6292	75	12	,	,	PUNCT
ajst-6292	75	13	j	j	PROPN
ajst-6292	75	14	=	=	NOUN
ajst-6292	75	15	6.4	6.4	NUM
ajst-6292	75	16	hz	hz	NOUN
ajst-6292	75	17	)	)	PUNCT
ajst-6292	75	18	,	,	PUNCT
ajst-6292	75	19	7.25	7.25	NUM
ajst-6292	75	20	(	(	PUNCT
ajst-6292	75	21	dd	dd	NOUN
ajst-6292	75	22	,	,	PUNCT
ajst-6292	75	23	1	1	NUM
ajst-6292	75	24	h	h	NOUN
ajst-6292	75	25	,	,	PUNCT
ajst-6292	75	26	j	j	PROPN
ajst-6292	75	27	=	=	NOUN
ajst-6292	75	28	12.8	12.8	NUM
ajst-6292	75	29	hz	hz	NOUN
ajst-6292	75	30	)	)	PUNCT
ajst-6292	75	31	,	,	PUNCT
ajst-6292	75	32	2.47	2.47	NUM
ajst-6292	75	33	(	(	PUNCT
ajst-6292	75	34	s	s	PROPN
ajst-6292	75	35	,	,	PUNCT
ajst-6292	75	36	3	3	NUM
ajst-6292	75	37	h	h	NOUN
ajst-6292	75	38	)	)	PUNCT
ajst-6292	75	39	;	;	PUNCT
ajst-6292	75	40	13c	13c	X
ajst-6292	75	41	nmr	nmr	NOUN
ajst-6292	75	42	(	(	PUNCT
ajst-6292	75	43	400	400	NUM
ajst-6292	75	44	mhz	mhz	NOUN
ajst-6292	75	45	,	,	PUNCT
ajst-6292	75	46	dmso	dmso	NOUN
ajst-6292	75	47	):	):	PUNCT
ajst-6292	75	48	δ	δ	PROPN
ajst-6292	75	49	193.34	193.34	NUM
ajst-6292	75	50	,	,	PUNCT
ajst-6292	75	51	149.50	149.50	NUM
ajst-6292	75	52	,	,	PUNCT
ajst-6292	75	53	144.59	144.59	NUM
ajst-6292	75	54	,	,	PUNCT
ajst-6292	75	55	135.21	135.21	NUM
ajst-6292	75	56	,	,	PUNCT
ajst-6292	75	57	130.02	130.02	NUM
ajst-6292	75	58	,	,	PUNCT
ajst-6292	75	59	118.47	118.47	NUM
ajst-6292	75	60	,	,	PUNCT
ajst-6292	75	61	118.07	118.07	NUM
ajst-6292	75	62	,	,	PUNCT
ajst-6292	75	63	115.92	115.92	NUM
ajst-6292	75	64	,	,	PUNCT
ajst-6292	75	65	27.40	27.40	NUM
ajst-6292	75	66	.	.	PUNCT
ajst-6292	75	67	3.2.2	3.2.2	NUM
ajst-6292	75	68	.	.	PUNCT
ajst-6292	75	69	preparation	preparation	NOUN
ajst-6292	75	70	of	of	ADP
ajst-6292	75	71	compound	compound	NOUN
ajst-6292	75	72	1	1	NUM
ajst-6292	75	73	-	-	PUNCT
ajst-6292	75	74	p	p	NUM
ajst-6292	75	75	-	-	PUNCT
ajst-6292	75	76	toluenesulfonyl-3acetyl-7	toluenesulfonyl-3acetyl-7	NOUN
ajst-6292	75	77	-	-	PUNCT
ajst-6292	75	78	azaindole	azaindole	NOUN
ajst-6292	75	79	(	(	PUNCT
ajst-6292	75	80	3	3	NUM
ajst-6292	75	81	)	)	PUNCT
ajst-6292	75	82	in	in	ADP
ajst-6292	75	83	a	a	DET
ajst-6292	75	84	100	100	NUM
ajst-6292	75	85	ml	ml	NOUN
ajst-6292	75	86	round	round	ADJ
ajst-6292	75	87	bottom	bottom	ADJ
ajst-6292	75	88	flask	flask	NOUN
ajst-6292	75	89	,	,	PUNCT
ajst-6292	75	90	added	add	VERB
ajst-6292	75	91	compound	compound	NOUN
ajst-6292	75	92	(	(	PUNCT
ajst-6292	75	93	2	2	NUM
ajst-6292	75	94	)	)	PUNCT
ajst-6292	75	95	(	(	PUNCT
ajst-6292	75	96	10	10	NUM
ajst-6292	75	97	g	g	NOUN
ajst-6292	75	98	,	,	PUNCT
ajst-6292	75	99	62.42	62.42	NUM
ajst-6292	75	100	mmol	mmol	NOUN
ajst-6292	75	101	)	)	PUNCT
ajst-6292	75	102	and	and	CCONJ
ajst-6292	75	103	thf	thf	NOUN
ajst-6292	75	104	(	(	PUNCT
ajst-6292	75	105	35	35	NUM
ajst-6292	75	106	ml	ml	NOUN
ajst-6292	75	107	)	)	PUNCT
ajst-6292	75	108	to	to	PART
ajst-6292	75	109	make	make	VERB
ajst-6292	75	110	it	it	PRON
ajst-6292	75	111	fully	fully	ADV
ajst-6292	75	112	dissolve	dissolve	VERB
ajst-6292	75	113	.	.	PUNCT
ajst-6292	76	1	slowly	slowly	ADV
ajst-6292	76	2	added	add	VERB
ajst-6292	76	3	t	t	PROPN
ajst-6292	76	4	-	-	PUNCT
ajst-6292	76	5	buok	buok	NOUN
ajst-6292	76	6	(	(	PUNCT
ajst-6292	76	7	14	14	NUM
ajst-6292	76	8	g	g	NOUN
ajst-6292	76	9	,	,	PUNCT
ajst-6292	76	10	124.76	124.76	NUM
ajst-6292	76	11	mmol	mmol	NOUN
ajst-6292	76	12	)	)	PUNCT
ajst-6292	76	13	in	in	ADP
ajst-6292	76	14	an	an	DET
ajst-6292	76	15	ice	ice	NOUN
ajst-6292	76	16	bath	bath	NOUN
ajst-6292	76	17	.	.	PUNCT
ajst-6292	77	1	after	after	ADP
ajst-6292	77	2	half	half	DET
ajst-6292	77	3	an	an	DET
ajst-6292	77	4	hour	hour	NOUN
ajst-6292	77	5	,	,	PUNCT
ajst-6292	77	6	added	add	VERB
ajst-6292	77	7	tosyl	tosyl	PROPN
ajst-6292	77	8	chloride	chloride	NOUN
ajst-6292	77	9	(	(	PUNCT
ajst-6292	77	10	13.09	13.09	NUM
ajst-6292	77	11	g	g	NOUN
ajst-6292	77	12	,	,	PUNCT
ajst-6292	77	13	68.66	68.66	NUM
ajst-6292	77	14	mmol	mmol	NOUN
ajst-6292	77	15	)	)	PUNCT
ajst-6292	77	16	to	to	ADP
ajst-6292	77	17	the	the	DET
ajst-6292	77	18	flask	flask	NOUN
ajst-6292	77	19	and	and	CCONJ
ajst-6292	77	20	heated	heat	VERB
ajst-6292	77	21	it	it	PRON
ajst-6292	77	22	for	for	ADP
ajst-6292	77	23	reflux	reflux	NOUN
ajst-6292	77	24	.	.	PUNCT
ajst-6292	78	1	two	two	NUM
ajst-6292	78	2	hours	hour	NOUN
ajst-6292	78	3	later	later	ADV
ajst-6292	78	4	,	,	PUNCT
ajst-6292	78	5	the	the	DET
ajst-6292	78	6	reaction	reaction	NOUN
ajst-6292	78	7	was	be	AUX
ajst-6292	78	8	found	find	VERB
ajst-6292	78	9	to	to	PART
ajst-6292	78	10	be	be	AUX
ajst-6292	78	11	complete	complete	ADJ
ajst-6292	78	12	by	by	ADP
ajst-6292	78	13	tlc	tlc	PROPN
ajst-6292	78	14	.	.	PUNCT
ajst-6292	79	1	added	add	VERB
ajst-6292	79	2	ice	ice	NOUN
ajst-6292	79	3	water	water	NOUN
ajst-6292	79	4	to	to	ADP
ajst-6292	79	5	the	the	DET
ajst-6292	79	6	reaction	reaction	NOUN
ajst-6292	79	7	solution	solution	NOUN
ajst-6292	79	8	and	and	CCONJ
ajst-6292	79	9	stirred	stir	VERB
ajst-6292	79	10	it	it	PRON
ajst-6292	79	11	.	.	PUNCT
ajst-6292	80	1	a	a	DET
ajst-6292	80	2	large	large	ADJ
ajst-6292	80	3	amount	amount	NOUN
ajst-6292	80	4	of	of	ADP
ajst-6292	80	5	flocculent	flocculent	NOUN
ajst-6292	80	6	substances	substance	NOUN
ajst-6292	80	7	were	be	AUX
ajst-6292	80	8	precipitated	precipitate	VERB
ajst-6292	80	9	.	.	PUNCT
ajst-6292	81	1	after	after	ADP
ajst-6292	81	2	standing	stand	VERB
ajst-6292	81	3	for	for	ADP
ajst-6292	81	4	10	10	NUM
ajst-6292	81	5	minutes	minute	NOUN
ajst-6292	81	6	,	,	PUNCT
ajst-6292	81	7	filtered	filter	VERB
ajst-6292	81	8	under	under	ADP
ajst-6292	81	9	reduced	reduce	VERB
ajst-6292	81	10	pressure	pressure	NOUN
ajst-6292	81	11	and	and	CCONJ
ajst-6292	81	12	collected	collect	VERB
ajst-6292	81	13	the	the	DET
ajst-6292	81	14	filter	filter	NOUN
ajst-6292	81	15	cake	cake	NOUN
ajst-6292	81	16	.	.	PUNCT
ajst-6292	82	1	if	if	SCONJ
ajst-6292	82	2	the	the	DET
ajst-6292	82	3	product	product	NOUN
ajst-6292	82	4	was	be	AUX
ajst-6292	82	5	impure	impure	NOUN
ajst-6292	82	6	,	,	PUNCT
ajst-6292	82	7	added	add	VERB
ajst-6292	82	8	petroleum	petroleum	NOUN
ajst-6292	82	9	ether	ether	NOUN
ajst-6292	82	10	to	to	PART
ajst-6292	82	11	dissolve	dissolve	VERB
ajst-6292	82	12	the	the	DET
ajst-6292	82	13	excess	excess	ADJ
ajst-6292	82	14	tosyl	tosyl	ADJ
ajst-6292	82	15	chloride	chloride	NOUN
ajst-6292	82	16	,	,	PUNCT
ajst-6292	82	17	and	and	CCONJ
ajst-6292	82	18	filtered	filter	VERB
ajst-6292	82	19	again	again	ADV
ajst-6292	82	20	.	.	PUNCT
ajst-6292	83	1	after	after	SCONJ
ajst-6292	83	2	the	the	DET
ajst-6292	83	3	filter	filter	NOUN
ajst-6292	83	4	cake	cake	NOUN
ajst-6292	83	5	was	be	AUX
ajst-6292	83	6	dried	dry	VERB
ajst-6292	83	7	,	,	PUNCT
ajst-6292	83	8	19.42	19.42	NUM
ajst-6292	83	9	g	g	NOUN
ajst-6292	83	10	of	of	ADP
ajst-6292	83	11	light	light	ADJ
ajst-6292	83	12	yellow	yellow	ADJ
ajst-6292	83	13	solid	solid	ADJ
ajst-6292	83	14	was	be	AUX
ajst-6292	83	15	obtained	obtain	VERB
ajst-6292	83	16	with	with	ADP
ajst-6292	83	17	a	a	DET
ajst-6292	83	18	yield	yield	NOUN
ajst-6292	83	19	of	of	ADP
ajst-6292	83	20	99.00	99.00	NUM
ajst-6292	83	21	%	%	NOUN
ajst-6292	83	22	.	.	PUNCT
ajst-6292	84	1	1h	1h	NUM
ajst-6292	84	2	nmr	nmr	NOUN
ajst-6292	84	3	(	(	PUNCT
ajst-6292	84	4	400	400	NUM
ajst-6292	84	5	mhz	mhz	NOUN
ajst-6292	84	6	,	,	PUNCT
ajst-6292	84	7	cdcl3	cdcl3	NOUN
ajst-6292	84	8	):	):	PUNCT
ajst-6292	84	9	δ	δ	PROPN
ajst-6292	84	10	8.60	8.60	NUM
ajst-6292	84	11	(	(	PUNCT
ajst-6292	84	12	dd	dd	NOUN
ajst-6292	84	13	,	,	PUNCT
ajst-6292	84	14	1	1	NUM
ajst-6292	84	15	h	h	NOUN
ajst-6292	84	16	,	,	PUNCT
ajst-6292	84	17	j	j	PROPN
ajst-6292	84	18	=	=	NOUN
ajst-6292	84	19	1.4	1.4	NUM
ajst-6292	84	20	hz	hz	NOUN
ajst-6292	84	21	)	)	PUNCT
ajst-6292	84	22	,	,	PUNCT
ajst-6292	84	23	8.48	8.48	NUM
ajst-6292	84	24	(	(	PUNCT
ajst-6292	84	25	dd	dd	NOUN
ajst-6292	84	26	,	,	PUNCT
ajst-6292	84	27	1	1	NUM
ajst-6292	84	28	h	h	NOUN
ajst-6292	84	29	,	,	PUNCT
ajst-6292	84	30	j	j	PROPN
ajst-6292	84	31	=	=	SYM
ajst-6292	84	32	1.2	1.2	NUM
ajst-6292	84	33	hz	hz	NOUN
ajst-6292	84	34	)	)	PUNCT
ajst-6292	84	35	,	,	PUNCT
ajst-6292	84	36	8.36	8.36	NUM
ajst-6292	84	37	(	(	PUNCT
ajst-6292	84	38	s	s	PROPN
ajst-6292	84	39	,	,	PUNCT
ajst-6292	84	40	1	1	NUM
ajst-6292	84	41	h	h	NOUN
ajst-6292	84	42	)	)	PUNCT
ajst-6292	84	43	,	,	PUNCT
ajst-6292	84	44	8.17	8.17	NUM
ajst-6292	84	45	(	(	PUNCT
ajst-6292	84	46	d	d	NOUN
ajst-6292	84	47	,	,	PUNCT
ajst-6292	84	48	2	2	NUM
ajst-6292	84	49	h	h	NOUN
ajst-6292	84	50	,	,	PUNCT
ajst-6292	84	51	j	j	PROPN
ajst-6292	85	1	=	=	SYM
ajst-6292	85	2	8.0	8.0	NUM
ajst-6292	85	3	hz	hz	NOUN
ajst-6292	85	4	)	)	PUNCT
ajst-6292	85	5	,	,	PUNCT
ajst-6292	85	6	7.33	7.33	NUM
ajst-6292	85	7	(	(	PUNCT
ajst-6292	85	8	d	d	NOUN
ajst-6292	85	9	,	,	PUNCT
ajst-6292	85	10	2	2	NUM
ajst-6292	85	11	h	h	NOUN
ajst-6292	85	12	,	,	PUNCT
ajst-6292	85	13	j	j	PROPN
ajst-6292	85	14	=	=	NOUN
ajst-6292	85	15	8.4	8.4	NUM
ajst-6292	85	16	hz	hz	NOUN
ajst-6292	85	17	)	)	PUNCT
ajst-6292	85	18	,	,	PUNCT
ajst-6292	85	19	7.29	7.29	NUM
ajst-6292	85	20	(	(	PUNCT
ajst-6292	85	21	t	t	PROPN
ajst-6292	85	22	,	,	PUNCT
ajst-6292	85	23	1	1	NUM
ajst-6292	85	24	h	h	NOUN
ajst-6292	85	25	,	,	PUNCT
ajst-6292	85	26	j	j	PROPN
ajst-6292	86	1	=	=	NOUN
ajst-6292	86	2	5.2	5.2	NUM
ajst-6292	86	3	hz	hz	NOUN
ajst-6292	86	4	)	)	PUNCT
ajst-6292	86	5	,	,	PUNCT
ajst-6292	86	6	2.58	2.58	NUM
ajst-6292	86	7	(	(	PUNCT
ajst-6292	86	8	s	s	PROPN
ajst-6292	86	9	,	,	PUNCT
ajst-6292	86	10	3	3	NUM
ajst-6292	86	11	h	h	NOUN
ajst-6292	86	12	)	)	PUNCT
ajst-6292	86	13	,	,	PUNCT
ajst-6292	86	14	2.39	2.39	NUM
ajst-6292	86	15	(	(	PUNCT
ajst-6292	86	16	s	s	PROPN
ajst-6292	86	17	,	,	PUNCT
ajst-6292	86	18	3	3	NUM
ajst-6292	86	19	h	h	NOUN
ajst-6292	86	20	)	)	PUNCT
ajst-6292	86	21	;	;	PUNCT
ajst-6292	86	22	13c	13c	X
ajst-6292	86	23	nmr	nmr	NOUN
ajst-6292	86	24	(	(	PUNCT
ajst-6292	86	25	400	400	NUM
ajst-6292	86	26	mhz	mhz	NOUN
ajst-6292	86	27	,	,	PUNCT
ajst-6292	86	28	cdcl3	cdcl3	NOUN
ajst-6292	86	29	):	):	PUNCT
ajst-6292	86	30	δ	δ	PROPN
ajst-6292	86	31	193.24	193.24	NUM
ajst-6292	86	32	,	,	PUNCT
ajst-6292	86	33	147.09	147.09	NUM
ajst-6292	86	34	,	,	PUNCT
ajst-6292	86	35	146.13	146.13	NUM
ajst-6292	86	36	,	,	PUNCT
ajst-6292	86	37	134.41	134.41	NUM
ajst-6292	86	38	,	,	PUNCT
ajst-6292	86	39	131.81	131.81	NUM
ajst-6292	86	40	,	,	PUNCT
ajst-6292	86	41	131.78	131.78	NUM
ajst-6292	86	42	,	,	PUNCT
ajst-6292	86	43	129.89	129.89	NUM
ajst-6292	86	44	,	,	PUNCT
ajst-6292	86	45	128.57	128.57	NUM
ajst-6292	86	46	,	,	PUNCT
ajst-6292	86	47	120.47	120.47	NUM
ajst-6292	86	48	,	,	PUNCT
ajst-6292	86	49	120.21	120.21	NUM
ajst-6292	86	50	,	,	PUNCT
ajst-6292	86	51	118.66	118.66	NUM
ajst-6292	86	52	,	,	PUNCT
ajst-6292	86	53	99.98	99.98	NUM
ajst-6292	86	54	,	,	PUNCT
ajst-6292	86	55	27.27	27.27	NUM
ajst-6292	86	56	,	,	PUNCT
ajst-6292	86	57	21.74	21.74	NUM
ajst-6292	86	58	.	.	PUNCT
ajst-6292	87	1	3.2.3	3.2.3	NUM
ajst-6292	87	2	.	.	PUNCT
ajst-6292	87	3	preparation	preparation	NOUN
ajst-6292	87	4	of	of	ADP
ajst-6292	87	5	compound	compound	NOUN
ajst-6292	87	6	(	(	PUNCT
ajst-6292	87	7	e)-1-[1	e)-1-[1	NOUN
ajst-6292	87	8	-	-	PUNCT
ajst-6292	87	9	ptoluenesulfonyl-7	ptoluenesulfonyl-7	NOUN
ajst-6292	87	10	-	-	PUNCT
ajst-6292	87	11	azaindole]-3(dimethylamino)-2propene-1	azaindole]-3(dimethylamino)-2propene-1	NOUN
ajst-6292	87	12	-	-	PUNCT
ajst-6292	87	13	one	one	NUM
ajst-6292	87	14	(	(	PUNCT
ajst-6292	87	15	4	4	NUM
ajst-6292	87	16	)	)	PUNCT
ajst-6292	87	17	added	add	VERB
ajst-6292	87	18	compound	compound	NOUN
ajst-6292	87	19	(	(	PUNCT
ajst-6292	87	20	3	3	NUM
ajst-6292	87	21	)	)	PUNCT
ajst-6292	87	22	(	(	PUNCT
ajst-6292	87	23	10	10	NUM
ajst-6292	87	24	g	g	NOUN
ajst-6292	87	25	,	,	PUNCT
ajst-6292	87	26	79.50	79.50	NUM
ajst-6292	87	27	mmol	mmol	NOUN
ajst-6292	87	28	)	)	PUNCT
ajst-6292	87	29	and	and	CCONJ
ajst-6292	87	30	n	n	CCONJ
ajst-6292	87	31	,	,	PUNCT
ajst-6292	87	32	ndimethylformamide	ndimethylformamide	ADJ
ajst-6292	87	33	dimethyl	dimethyl	PROPN
ajst-6292	87	34	acetal	acetal	NOUN
ajst-6292	87	35	(	(	PUNCT
ajst-6292	87	36	120	120	NUM
ajst-6292	87	37	ml	ml	NOUN
ajst-6292	87	38	)	)	PUNCT
ajst-6292	87	39	into	into	ADP
ajst-6292	87	40	a	a	DET
ajst-6292	87	41	100	100	NUM
ajst-6292	87	42	ml	ml	NOUN
ajst-6292	87	43	round	round	ADJ
ajst-6292	87	44	bottom	bottom	ADJ
ajst-6292	87	45	flask	flask	NOUN
ajst-6292	87	46	.	.	PUNCT
ajst-6292	88	1	the	the	DET
ajst-6292	88	2	compounds	compound	NOUN
ajst-6292	88	3	were	be	AUX
ajst-6292	88	4	dissolved	dissolve	VERB
ajst-6292	88	5	as	as	ADV
ajst-6292	88	6	fully	fully	ADV
ajst-6292	88	7	as	as	ADP
ajst-6292	88	8	possible	possible	ADJ
ajst-6292	88	9	by	by	ADP
ajst-6292	88	10	ultrasound	ultrasound	NOUN
ajst-6292	88	11	and	and	CCONJ
ajst-6292	88	12	refluxed	refluxe	VERB
ajst-6292	88	13	after	after	ADP
ajst-6292	88	14	reacting	react	VERB
ajst-6292	88	15	at	at	ADP
ajst-6292	88	16	room	room	NOUN
ajst-6292	88	17	temperature	temperature	NOUN
ajst-6292	88	18	for	for	ADP
ajst-6292	88	19	6	6	NUM
ajst-6292	88	20	hours	hour	NOUN
ajst-6292	88	21	.	.	PUNCT
ajst-6292	89	1	the	the	DET
ajst-6292	89	2	reaction	reaction	NOUN
ajst-6292	89	3	was	be	AUX
ajst-6292	89	4	completed	complete	VERB
ajst-6292	89	5	after	after	ADP
ajst-6292	89	6	20	20	NUM
ajst-6292	89	7	hours	hour	NOUN
ajst-6292	89	8	of	of	ADP
ajst-6292	89	9	tlc	tlc	NOUN
ajst-6292	89	10	monitoring	monitoring	NOUN
ajst-6292	89	11	.	.	PUNCT
ajst-6292	90	1	after	after	ADP
ajst-6292	90	2	cooling	cool	VERB
ajst-6292	90	3	to	to	ADP
ajst-6292	90	4	room	room	NOUN
ajst-6292	90	5	temperature	temperature	NOUN
ajst-6292	90	6	,	,	PUNCT
ajst-6292	90	7	ice	ice	NOUN
ajst-6292	90	8	water	water	NOUN
ajst-6292	90	9	was	be	AUX
ajst-6292	90	10	slowly	slowly	ADV
ajst-6292	90	11	added	add	VERB
ajst-6292	90	12	to	to	ADP
ajst-6292	90	13	the	the	DET
ajst-6292	90	14	flask	flask	NOUN
ajst-6292	90	15	.	.	PUNCT
ajst-6292	91	1	then	then	ADV
ajst-6292	91	2	the	the	DET
ajst-6292	91	3	mixture	mixture	NOUN
ajst-6292	91	4	was	be	AUX
ajst-6292	91	5	extracted	extract	VERB
ajst-6292	91	6	with	with	ADP
ajst-6292	91	7	ea	ea	PROPN
ajst-6292	91	8	(	(	PUNCT
ajst-6292	91	9	100ml	100ml	PROPN
ajst-6292	91	10	×	×	NOUN
ajst-6292	91	11	4	4	NUM
ajst-6292	91	12	)	)	PUNCT
ajst-6292	91	13	.	.	PUNCT
ajst-6292	92	1	the	the	DET
ajst-6292	92	2	combined	combine	VERB
ajst-6292	92	3	organic	organic	ADJ
ajst-6292	92	4	phases	phase	NOUN
ajst-6292	92	5	were	be	AUX
ajst-6292	92	6	washed	wash	VERB
ajst-6292	92	7	with	with	ADP
ajst-6292	92	8	saturated	saturate	VERB
ajst-6292	92	9	nacl	nacl	ADJ
ajst-6292	92	10	solution	solution	NOUN
ajst-6292	92	11	(	(	PUNCT
ajst-6292	92	12	100ml	100ml	NOUN
ajst-6292	92	13	×	×	NOUN
ajst-6292	92	14	4	4	NUM
ajst-6292	92	15	)	)	PUNCT
ajst-6292	92	16	and	and	CCONJ
ajst-6292	92	17	dried	dry	VERB
ajst-6292	92	18	with	with	ADP
ajst-6292	92	19	anhydrous	anhydrous	ADJ
ajst-6292	92	20	sodium	sodium	NOUN
ajst-6292	92	21	sulfate	sulfate	NOUN
ajst-6292	92	22	.	.	PUNCT
ajst-6292	93	1	the	the	DET
ajst-6292	93	2	solvent	solvent	NOUN
ajst-6292	93	3	was	be	AUX
ajst-6292	93	4	evaporated	evaporate	VERB
ajst-6292	93	5	by	by	ADP
ajst-6292	93	6	vacuum	vacuum	NOUN
ajst-6292	93	7	rotary	rotary	ADJ
ajst-6292	93	8	evaporator	evaporator	NOUN
ajst-6292	93	9	to	to	PART
ajst-6292	93	10	obtain	obtain	VERB
ajst-6292	93	11	7.25	7.25	NUM
ajst-6292	93	12	g	g	NOUN
ajst-6292	93	13	of	of	ADP
ajst-6292	93	14	light	light	ADJ
ajst-6292	93	15	yellow	yellow	ADJ
ajst-6292	93	16	solid	solid	ADJ
ajst-6292	93	17	with	with	ADP
ajst-6292	93	18	a	a	DET
ajst-6292	93	19	yield	yield	NOUN
ajst-6292	93	20	of	of	ADP
ajst-6292	93	21	61.70	61.70	NUM
ajst-6292	93	22	%	%	NOUN
ajst-6292	93	23	.	.	PUNCT
ajst-6292	94	1	1h	1h	NUM
ajst-6292	94	2	nmr	nmr	NOUN
ajst-6292	94	3	(	(	PUNCT
ajst-6292	94	4	400	400	NUM
ajst-6292	94	5	mhz	mhz	NOUN
ajst-6292	94	6	,	,	PUNCT
ajst-6292	94	7	cdcl3	cdcl3	NOUN
ajst-6292	94	8	):	):	PUNCT
ajst-6292	94	9	δ	δ	PROPN
ajst-6292	94	10	8.64	8.64	NUM
ajst-6292	94	11	(	(	PUNCT
ajst-6292	94	12	d	d	PROPN
ajst-6292	94	13	,	,	PUNCT
ajst-6292	94	14	1	1	NUM
ajst-6292	94	15	h	h	NOUN
ajst-6292	94	16	,	,	PUNCT
ajst-6292	94	17	j	j	PROPN
ajst-6292	94	18	=	=	NOUN
ajst-6292	94	19	7.6	7.6	NUM
ajst-6292	94	20	hz	hz	NOUN
ajst-6292	94	21	)	)	PUNCT
ajst-6292	94	22	,	,	PUNCT
ajst-6292	94	23	8.42	8.42	NUM
ajst-6292	94	24	(	(	PUNCT
ajst-6292	94	25	d	d	NOUN
ajst-6292	94	26	,	,	PUNCT
ajst-6292	94	27	2	2	NUM
ajst-6292	94	28	h	h	NOUN
ajst-6292	94	29	,	,	PUNCT
ajst-6292	94	30	j	j	PROPN
ajst-6292	95	1	=	=	SYM
ajst-6292	95	2	4.0	4.0	NUM
ajst-6292	95	3	hz	hz	NOUN
ajst-6292	95	4	)	)	PUNCT
ajst-6292	95	5	,	,	PUNCT
ajst-6292	95	6	8.22	8.22	NUM
ajst-6292	95	7	(	(	PUNCT
ajst-6292	95	8	s	s	PROPN
ajst-6292	95	9	,	,	PUNCT
ajst-6292	95	10	1	1	NUM
ajst-6292	95	11	h	h	NOUN
ajst-6292	95	12	)	)	PUNCT
ajst-6292	95	13	,	,	PUNCT
ajst-6292	95	14	8.10	8.10	NUM
ajst-6292	95	15	(	(	PUNCT
ajst-6292	95	16	d	d	NOUN
ajst-6292	95	17	,	,	PUNCT
ajst-6292	95	18	2	2	NUM
ajst-6292	95	19	h	h	NOUN
ajst-6292	95	20	,	,	PUNCT
ajst-6292	95	21	j	j	PROPN
ajst-6292	95	22	=	=	NOUN
ajst-6292	95	23	8.0	8.0	NUM
ajst-6292	95	24	hz),7.78	hz),7.78	NOUN
ajst-6292	95	25	(	(	PUNCT
ajst-6292	95	26	d	d	NOUN
ajst-6292	95	27	,	,	PUNCT
ajst-6292	95	28	2	2	NUM
ajst-6292	95	29	h	h	NOUN
ajst-6292	95	30	,	,	PUNCT
ajst-6292	95	31	j	j	PROPN
ajst-6292	95	32	=	=	SYM
ajst-6292	95	33	12.4	12.4	NUM
ajst-6292	95	34	hz	hz	NOUN
ajst-6292	95	35	)	)	PUNCT
ajst-6292	95	36	,	,	PUNCT
ajst-6292	95	37	7.27	7.27	NUM
ajst-6292	95	38	(	(	PUNCT
ajst-6292	95	39	d	d	NOUN
ajst-6292	95	40	,	,	PUNCT
ajst-6292	95	41	2	2	NUM
ajst-6292	95	42	h	h	NOUN
ajst-6292	95	43	,	,	PUNCT
ajst-6292	95	44	j	j	PROPN
ajst-6292	95	45	=	=	NOUN
ajst-6292	95	46	8.4	8.4	NUM
ajst-6292	95	47	hz	hz	NOUN
ajst-6292	95	48	)	)	PUNCT
ajst-6292	95	49	,	,	PUNCT
ajst-6292	95	50	5.60	5.60	NUM
ajst-6292	95	51	(	(	PUNCT
ajst-6292	95	52	d	d	NOUN
ajst-6292	95	53	,	,	PUNCT
ajst-6292	95	54	1	1	NUM
ajst-6292	95	55	h	h	NOUN
ajst-6292	95	56	,	,	PUNCT
ajst-6292	95	57	j	j	PROPN
ajst-6292	95	58	=	=	SYM
ajst-6292	95	59	12.4	12.4	NUM
ajst-6292	95	60	hz	hz	NOUN
ajst-6292	95	61	)	)	PUNCT
ajst-6292	95	62	,	,	PUNCT
ajst-6292	95	63	3.13	3.13	NUM
ajst-6292	95	64	(	(	PUNCT
ajst-6292	95	65	d	d	NOUN
ajst-6292	95	66	,	,	PUNCT
ajst-6292	95	67	6	6	NUM
ajst-6292	95	68	h	h	NOUN
ajst-6292	95	69	)	)	PUNCT
ajst-6292	95	70	,	,	PUNCT
ajst-6292	95	71	2.34	2.34	NUM
ajst-6292	95	72	(	(	PUNCT
ajst-6292	95	73	s	s	PROPN
ajst-6292	95	74	,	,	PUNCT
ajst-6292	95	75	3	3	NUM
ajst-6292	95	76	h	h	NOUN
ajst-6292	95	77	)	)	PUNCT
ajst-6292	96	1	;	;	PUNCT
ajst-6292	96	2	13c	13c	X
ajst-6292	96	3	nmr	nmr	NOUN
ajst-6292	96	4	(	(	PUNCT
ajst-6292	96	5	400	400	NUM
ajst-6292	96	6	mhz	mhz	NOUN
ajst-6292	96	7	,	,	PUNCT
ajst-6292	96	8	cdcl3	cdcl3	PROPN
ajst-6292	96	9	):	):	PUNCT
ajst-6292	96	10	δ	δ	PROPN
ajst-6292	96	11	183.39	183.39	NUM
ajst-6292	96	12	,	,	PUNCT
ajst-6292	96	13	153.12	153.12	NUM
ajst-6292	96	14	,	,	PUNCT
ajst-6292	96	15	147.27	147.27	NUM
ajst-6292	96	16	,	,	PUNCT
ajst-6292	96	17	145.63	145.63	NUM
ajst-6292	96	18	,	,	PUNCT
ajst-6292	96	19	145.43	145.43	NUM
ajst-6292	96	20	,	,	PUNCT
ajst-6292	96	21	134.85	134.85	NUM
ajst-6292	96	22	,	,	PUNCT
ajst-6292	96	23	132.00	132.00	NUM
ajst-6292	96	24	,	,	PUNCT
ajst-6292	96	25	129.74	129.74	NUM
ajst-6292	96	26	,	,	PUNCT
ajst-6292	96	27	128.26	128.26	NUM
ajst-6292	96	28	,	,	PUNCT
ajst-6292	96	29	127.95	127.95	NUM
ajst-6292	96	30	,	,	PUNCT
ajst-6292	96	31	121.54	121.54	NUM
ajst-6292	96	32	,	,	PUNCT
ajst-6292	96	33	120.52	120.52	NUM
ajst-6292	96	34	,	,	PUNCT
ajst-6292	96	35	119.87	119.87	NUM
ajst-6292	96	36	,	,	PUNCT
ajst-6292	96	37	92.44	92.44	NUM
ajst-6292	96	38	,	,	PUNCT
ajst-6292	96	39	45.06	45.06	NUM
ajst-6292	96	40	,	,	PUNCT
ajst-6292	96	41	37.43	37.43	NUM
ajst-6292	96	42	,	,	PUNCT
ajst-6292	96	43	21.67	21.67	NUM
ajst-6292	96	44	.	.	PUNCT
ajst-6292	96	45	3.2.4	3.2.4	NUM
ajst-6292	96	46	.	.	PUNCT
ajst-6292	96	47	preparation	preparation	NOUN
ajst-6292	96	48	of	of	ADP
ajst-6292	96	49	compound	compound	NOUN
ajst-6292	96	50	3-(2	3-(2	PROPN
ajst-6292	96	51	-	-	PUNCT
ajst-6292	96	52	aminopyrimidine)7	aminopyrimidine)7	NOUN
ajst-6292	96	53	-	-	NOUN
ajst-6292	96	54	azaindole	azaindole	PROPN
ajst-6292	96	55	(	(	PUNCT
ajst-6292	96	56	meriolin1	meriolin1	NOUN
ajst-6292	96	57	)	)	PUNCT
ajst-6292	96	58	compound	compound	NOUN
ajst-6292	96	59	(	(	PUNCT
ajst-6292	96	60	4	4	NUM
ajst-6292	96	61	)	)	PUNCT
ajst-6292	96	62	(	(	PUNCT
ajst-6292	96	63	2	2	NUM
ajst-6292	96	64	g	g	NOUN
ajst-6292	96	65	,	,	PUNCT
ajst-6292	96	66	5.4	5.4	NUM
ajst-6292	96	67	mmol	mmol	NOUN
ajst-6292	96	68	)	)	PUNCT
ajst-6292	96	69	,	,	PUNCT
ajst-6292	96	70	anhydrous	anhydrous	ADJ
ajst-6292	96	71	k2co3	k2co3	NOUN
ajst-6292	96	72	(	(	PUNCT
ajst-6292	96	73	2.24	2.24	NUM
ajst-6292	96	74	g	g	NOUN
ajst-6292	96	75	,	,	PUNCT
ajst-6292	96	76	16.20	16.20	NUM
ajst-6292	96	77	mmol	mmol	NOUN
ajst-6292	96	78	)	)	PUNCT
ajst-6292	96	79	and	and	CCONJ
ajst-6292	96	80	guanidine	guanidine	ADJ
ajst-6292	96	81	hydrochloride	hydrochloride	NOUN
ajst-6292	96	82	(	(	PUNCT
ajst-6292	96	83	2.56	2.56	NUM
ajst-6292	96	84	g	g	NOUN
ajst-6292	96	85	,	,	PUNCT
ajst-6292	96	86	26.78	26.78	NUM
ajst-6292	96	87	mmol	mmol	NOUN
ajst-6292	96	88	)	)	PUNCT
ajst-6292	96	89	were	be	AUX
ajst-6292	96	90	added	add	VERB
ajst-6292	96	91	into	into	ADP
ajst-6292	96	92	a	a	DET
ajst-6292	96	93	50	50	NUM
ajst-6292	96	94	ml	ml	NOUN
ajst-6292	96	95	round	round	ADJ
ajst-6292	96	96	bottom	bottom	ADJ
ajst-6292	96	97	flask	flask	NOUN
ajst-6292	96	98	,	,	PUNCT
ajst-6292	96	99	and	and	CCONJ
ajst-6292	96	100	then	then	ADV
ajst-6292	96	101	dmf	dmf	PROPN
ajst-6292	96	102	was	be	AUX
ajst-6292	96	103	added	add	VERB
ajst-6292	96	104	to	to	PART
ajst-6292	96	105	dissolve	dissolve	VERB
ajst-6292	96	106	it	it	PRON
ajst-6292	96	107	and	and	CCONJ
ajst-6292	96	108	heat	heat	VERB
ajst-6292	96	109	it	it	PRON
ajst-6292	96	110	at	at	ADP
ajst-6292	96	111	130	130	NUM
ajst-6292	96	112	°	°	NOUN
ajst-6292	96	113	c	c	NOUN
ajst-6292	96	114	.	.	PUNCT
ajst-6292	97	1	after	after	ADP
ajst-6292	97	2	4	4	NUM
ajst-6292	97	3	h	h	NOUN
ajst-6292	97	4	,	,	PUNCT
ajst-6292	97	5	the	the	DET
ajst-6292	97	6	reaction	reaction	NOUN
ajst-6292	97	7	was	be	AUX
ajst-6292	97	8	found	find	VERB
ajst-6292	97	9	to	to	PART
ajst-6292	97	10	be	be	AUX
ajst-6292	97	11	complete	complete	ADJ
ajst-6292	97	12	by	by	ADP
ajst-6292	97	13	tlc	tlc	PROPN
ajst-6292	97	14	.	.	PUNCT
ajst-6292	98	1	the	the	DET
ajst-6292	98	2	reaction	reaction	NOUN
ajst-6292	98	3	solution	solution	NOUN
ajst-6292	98	4	was	be	AUX
ajst-6292	98	5	extracted	extract	VERB
ajst-6292	98	6	with	with	ADP
ajst-6292	98	7	ch2cl2	ch2cl2	PUNCT
ajst-6292	98	8	(	(	PUNCT
ajst-6292	98	9	100ml	100ml	NOUN
ajst-6292	98	10	×	×	NOUN
ajst-6292	98	11	4	4	NUM
ajst-6292	98	12	)	)	PUNCT
ajst-6292	98	13	,	,	PUNCT
ajst-6292	98	14	washed	wash	VERB
ajst-6292	98	15	with	with	ADP
ajst-6292	98	16	108	108	NUM
ajst-6292	98	17	saturated	saturated	ADJ
ajst-6292	98	18	nacl	nacl	NOUN
ajst-6292	98	19	solution	solution	NOUN
ajst-6292	98	20	(	(	PUNCT
ajst-6292	98	21	100ml	100ml	NOUN
ajst-6292	98	22	×	×	NOUN
ajst-6292	98	23	4	4	NUM
ajst-6292	98	24	)	)	PUNCT
ajst-6292	98	25	and	and	CCONJ
ajst-6292	98	26	dried	dry	VERB
ajst-6292	98	27	with	with	ADP
ajst-6292	98	28	anhydrous	anhydrous	ADJ
ajst-6292	98	29	sodium	sodium	NOUN
ajst-6292	98	30	sulfate	sulfate	NOUN
ajst-6292	98	31	.	.	PUNCT
ajst-6292	99	1	after	after	SCONJ
ajst-6292	99	2	the	the	DET
ajst-6292	99	3	organic	organic	ADJ
ajst-6292	99	4	phase	phase	NOUN
ajst-6292	99	5	was	be	AUX
ajst-6292	99	6	combined	combine	VERB
ajst-6292	99	7	,	,	PUNCT
ajst-6292	99	8	it	it	PRON
ajst-6292	99	9	was	be	AUX
ajst-6292	99	10	rotated	rotate	VERB
ajst-6292	99	11	and	and	CCONJ
ajst-6292	99	12	evaporated	evaporate	VERB
ajst-6292	99	13	under	under	ADP
ajst-6292	99	14	reduced	reduce	VERB
ajst-6292	99	15	pressure	pressure	NOUN
ajst-6292	99	16	to	to	PART
ajst-6292	99	17	obtain	obtain	VERB
ajst-6292	99	18	light	light	ADJ
ajst-6292	99	19	yellow	yellow	ADJ
ajst-6292	99	20	solid	solid	ADJ
ajst-6292	99	21	powder	powder	NOUN
ajst-6292	99	22	.	.	PUNCT
ajst-6292	100	1	a	a	DET
ajst-6292	100	2	small	small	ADJ
ajst-6292	100	3	amount	amount	NOUN
ajst-6292	100	4	of	of	ADP
ajst-6292	100	5	ethyl	ethyl	PROPN
ajst-6292	100	6	acetate	acetate	PROPN
ajst-6292	100	7	was	be	AUX
ajst-6292	100	8	added	add	VERB
ajst-6292	100	9	to	to	ADP
ajst-6292	100	10	the	the	DET
ajst-6292	100	11	solid	solid	ADJ
ajst-6292	100	12	,	,	PUNCT
ajst-6292	100	13	heated	heat	VERB
ajst-6292	100	14	by	by	ADP
ajst-6292	100	15	ultrasound	ultrasound	NOUN
ajst-6292	100	16	,	,	PUNCT
ajst-6292	100	17	filtered	filter	VERB
ajst-6292	100	18	under	under	ADP
ajst-6292	100	19	reduced	reduced	ADJ
ajst-6292	100	20	pressure	pressure	NOUN
ajst-6292	100	21	,	,	PUNCT
ajst-6292	100	22	the	the	DET
ajst-6292	100	23	filter	filter	NOUN
ajst-6292	100	24	cake	cake	NOUN
ajst-6292	100	25	was	be	AUX
ajst-6292	100	26	taken	take	VERB
ajst-6292	100	27	and	and	CCONJ
ajst-6292	100	28	dried	dry	VERB
ajst-6292	100	29	to	to	PART
ajst-6292	100	30	obtain	obtain	VERB
ajst-6292	100	31	1.28	1.28	NUM
ajst-6292	100	32	g	g	NOUN
ajst-6292	100	33	of	of	ADP
ajst-6292	100	34	light	light	ADJ
ajst-6292	100	35	yellow	yellow	ADJ
ajst-6292	100	36	solid	solid	ADJ
ajst-6292	100	37	with	with	ADP
ajst-6292	100	38	a	a	DET
ajst-6292	100	39	yield	yield	NOUN
ajst-6292	100	40	of	of	ADP
ajst-6292	100	41	56.14	56.14	NUM
ajst-6292	100	42	%	%	NOUN
ajst-6292	100	43	.	.	PUNCT
ajst-6292	101	1	1h	1h	NUM
ajst-6292	101	2	nmr	nmr	NOUN
ajst-6292	101	3	(	(	PUNCT
ajst-6292	101	4	400	400	NUM
ajst-6292	101	5	mhz	mhz	NOUN
ajst-6292	101	6	,	,	PUNCT
ajst-6292	101	7	dmso	dmso	NOUN
ajst-6292	101	8	):	):	PUNCT
ajst-6292	101	9	δ	δ	PROPN
ajst-6292	101	10	12.16	12.16	NUM
ajst-6292	101	11	(	(	PUNCT
ajst-6292	101	12	bs	bs	NOUN
ajst-6292	101	13	,	,	PUNCT
ajst-6292	101	14	1	1	NUM
ajst-6292	101	15	h	h	NOUN
ajst-6292	101	16	)	)	PUNCT
ajst-6292	101	17	,	,	PUNCT
ajst-6292	101	18	8.89	8.89	NUM
ajst-6292	101	19	(	(	PUNCT
ajst-6292	101	20	dd	dd	NOUN
ajst-6292	101	21	,	,	PUNCT
ajst-6292	101	22	1	1	NUM
ajst-6292	101	23	h	h	NOUN
ajst-6292	101	24	,	,	PUNCT
ajst-6292	101	25	j	j	PROPN
ajst-6292	101	26	=	=	NOUN
ajst-6292	101	27	1.6	1.6	NUM
ajst-6292	101	28	hz	hz	NOUN
ajst-6292	101	29	)	)	PUNCT
ajst-6292	101	30	,	,	PUNCT
ajst-6292	101	31	8.30(s	8.30(s	PROPN
ajst-6292	101	32	,	,	PUNCT
ajst-6292	101	33	1	1	NUM
ajst-6292	101	34	h	h	NOUN
ajst-6292	101	35	)	)	PUNCT
ajst-6292	101	36	,	,	PUNCT
ajst-6292	101	37	8.25	8.25	NUM
ajst-6292	101	38	(	(	PUNCT
ajst-6292	101	39	dd	dd	NOUN
ajst-6292	101	40	,	,	PUNCT
ajst-6292	101	41	1	1	NUM
ajst-6292	101	42	h	h	NOUN
ajst-6292	101	43	,	,	PUNCT
ajst-6292	101	44	j	j	PROPN
ajst-6292	102	1	=	=	NOUN
ajst-6292	102	2	1.4	1.4	NUM
ajst-6292	102	3	hz	hz	NOUN
ajst-6292	102	4	)	)	PUNCT
ajst-6292	102	5	,	,	PUNCT
ajst-6292	102	6	8.10	8.10	NUM
ajst-6292	102	7	(	(	PUNCT
ajst-6292	102	8	d	d	NOUN
ajst-6292	102	9	,	,	PUNCT
ajst-6292	102	10	1	1	NUM
ajst-6292	102	11	h	h	NOUN
ajst-6292	102	12	,	,	PUNCT
ajst-6292	102	13	j	j	PROPN
ajst-6292	103	1	=	=	NOUN
ajst-6292	103	2	5.2	5.2	NUM
ajst-6292	103	3	hz	hz	NOUN
ajst-6292	103	4	)	)	PUNCT
ajst-6292	103	5	,	,	PUNCT
ajst-6292	103	6	7.17	7.17	NUM
ajst-6292	103	7	(	(	PUNCT
ajst-6292	103	8	dd	dd	NOUN
ajst-6292	103	9	,	,	PUNCT
ajst-6292	103	10	1	1	NUM
ajst-6292	103	11	h	h	NOUN
ajst-6292	103	12	,	,	PUNCT
ajst-6292	103	13	j	j	PROPN
ajst-6292	103	14	=	=	SYM
ajst-6292	103	15	4.6	4.6	NUM
ajst-6292	103	16	hz),7.02	hz),7.02	PUNCT
ajst-6292	103	17	(	(	PUNCT
ajst-6292	103	18	d	d	NOUN
ajst-6292	103	19	,	,	PUNCT
ajst-6292	103	20	1	1	NUM
ajst-6292	103	21	h	h	NOUN
ajst-6292	103	22	,	,	PUNCT
ajst-6292	103	23	j	j	PROPN
ajst-6292	103	24	=	=	SYM
ajst-6292	103	25	5.6	5.6	NUM
ajst-6292	103	26	hz	hz	NOUN
ajst-6292	103	27	)	)	PUNCT
ajst-6292	103	28	,	,	PUNCT
ajst-6292	103	29	6.44(s	6.44(s	PROPN
ajst-6292	103	30	,	,	PUNCT
ajst-6292	103	31	2	2	NUM
ajst-6292	103	32	h	h	NOUN
ajst-6292	103	33	)	)	PUNCT
ajst-6292	103	34	;	;	PUNCT
ajst-6292	103	35	13c	13c	X
ajst-6292	103	36	nmr	nmr	NOUN
ajst-6292	103	37	(	(	PUNCT
ajst-6292	103	38	400	400	NUM
ajst-6292	103	39	mhz	mhz	NOUN
ajst-6292	103	40	,	,	PUNCT
ajst-6292	103	41	dmso	dmso	NOUN
ajst-6292	103	42	):	):	PUNCT
ajst-6292	103	43	δ	δ	PROPN
ajst-6292	103	44	163.95	163.95	NUM
ajst-6292	103	45	,	,	PUNCT
ajst-6292	103	46	162.55	162.55	NUM
ajst-6292	103	47	,	,	PUNCT
ajst-6292	103	48	157.75	157.75	NUM
ajst-6292	103	49	,	,	PUNCT
ajst-6292	103	50	149.63	149.63	NUM
ajst-6292	103	51	,	,	PUNCT
ajst-6292	103	52	143.90	143.90	NUM
ajst-6292	103	53	,	,	PUNCT
ajst-6292	103	54	131.23	131.23	NUM
ajst-6292	103	55	,	,	PUNCT
ajst-6292	103	56	128.93	128.93	NUM
ajst-6292	103	57	,	,	PUNCT
ajst-6292	103	58	118.27	118.27	NUM
ajst-6292	103	59	,	,	PUNCT
ajst-6292	103	60	117.20	117.20	NUM
ajst-6292	103	61	,	,	PUNCT
ajst-6292	103	62	112.86	112.86	NUM
ajst-6292	103	63	,	,	PUNCT
ajst-6292	103	64	105.46	105.46	NUM
ajst-6292	103	65	.	.	PUNCT
ajst-6292	103	66	4	4	NUM
ajst-6292	103	67	.	.	X
ajst-6292	103	68	conclusion	conclusion	NOUN
ajst-6292	103	69	in	in	ADP
ajst-6292	103	70	this	this	DET
ajst-6292	103	71	paper	paper	NOUN
ajst-6292	103	72	,	,	PUNCT
ajst-6292	103	73	a	a	DET
ajst-6292	103	74	simple	simple	ADJ
ajst-6292	103	75	and	and	CCONJ
ajst-6292	103	76	novel	novel	ADJ
ajst-6292	103	77	route	route	NOUN
ajst-6292	103	78	was	be	AUX
ajst-6292	103	79	used	use	VERB
ajst-6292	103	80	to	to	PART
ajst-6292	103	81	synthesize	synthesize	VERB
ajst-6292	103	82	meriolin1	meriolin1	NOUN
ajst-6292	103	83	in	in	ADP
ajst-6292	103	84	an	an	DET
ajst-6292	103	85	overall	overall	ADJ
ajst-6292	103	86	yield	yield	NOUN
ajst-6292	103	87	of	of	ADP
ajst-6292	103	88	27.58	27.58	NUM
ajst-6292	103	89	%	%	NOUN
ajst-6292	103	90	.	.	PUNCT
ajst-6292	104	1	the	the	DET
ajst-6292	104	2	synthesis	synthesis	NOUN
ajst-6292	104	3	of	of	ADP
ajst-6292	104	4	meriolin1	meriolin1	NOUN
ajst-6292	104	5	from	from	ADP
ajst-6292	104	6	7	7	NUM
ajst-6292	104	7	-	-	PUNCT
ajst-6292	104	8	azaindole	azaindole	NOUN
ajst-6292	104	9	has	have	AUX
ajst-6292	104	10	not	not	PART
ajst-6292	104	11	been	be	AUX
ajst-6292	104	12	reported	report	VERB
ajst-6292	104	13	before	before	ADV
ajst-6292	104	14	.	.	PUNCT
ajst-6292	105	1	this	this	DET
ajst-6292	105	2	route	route	NOUN
ajst-6292	105	3	avoids	avoid	VERB
ajst-6292	105	4	the	the	DET
ajst-6292	105	5	disadvantages	disadvantage	NOUN
ajst-6292	105	6	of	of	ADP
ajst-6292	105	7	the	the	DET
ajst-6292	105	8	existing	exist	VERB
ajst-6292	105	9	route	route	NOUN
ajst-6292	105	10	,	,	PUNCT
ajst-6292	105	11	and	and	CCONJ
ajst-6292	105	12	meriolin	meriolin	NOUN
ajst-6292	105	13	1	1	NUM
ajst-6292	105	14	can	can	AUX
ajst-6292	105	15	be	be	AUX
ajst-6292	105	16	synthesized	synthesize	VERB
ajst-6292	105	17	in	in	ADP
ajst-6292	105	18	only	only	ADV
ajst-6292	105	19	four	four	NUM
ajst-6292	105	20	steps	step	NOUN
ajst-6292	105	21	with	with	ADP
ajst-6292	105	22	cheap	cheap	ADJ
ajst-6292	105	23	raw	raw	ADJ
ajst-6292	105	24	materials	material	NOUN
ajst-6292	105	25	and	and	CCONJ
ajst-6292	105	26	simple	simple	ADJ
ajst-6292	105	27	post	post	ADJ
ajst-6292	105	28	-	-	NOUN
ajst-6292	105	29	treatment	treatment	NOUN
ajst-6292	105	30	,	,	PUNCT
ajst-6292	105	31	which	which	PRON
ajst-6292	105	32	lays	lay	VERB
ajst-6292	105	33	a	a	DET
ajst-6292	105	34	foundation	foundation	NOUN
ajst-6292	105	35	for	for	ADP
ajst-6292	105	36	the	the	DET
ajst-6292	105	37	research	research	NOUN
ajst-6292	105	38	of	of	ADP
ajst-6292	105	39	meriolin	meriolin	PROPN
ajst-6292	105	40	series	series	NOUN
ajst-6292	105	41	compounds	compound	VERB
ajst-6292	105	42	in	in	ADP
ajst-6292	105	43	the	the	DET
ajst-6292	105	44	future	future	NOUN
ajst-6292	105	45	.	.	PUNCT
ajst-6292	106	1	5	5	X
ajst-6292	106	2	.	.	X
ajst-6292	106	3	conflicts	conflict	NOUN
ajst-6292	106	4	of	of	ADP
ajst-6292	106	5	interest	interest	NOUN
ajst-6292	106	6	the	the	DET
ajst-6292	106	7	authors	author	NOUN
ajst-6292	106	8	declare	declare	VERB
ajst-6292	106	9	no	no	DET
ajst-6292	106	10	conflicts	conflict	NOUN
ajst-6292	106	11	of	of	ADP
ajst-6292	106	12	interest	interest	NOUN
ajst-6292	106	13	.	.	PUNCT
ajst-6292	107	1	acknowledgment	acknowledgment	NOUN
ajst-6292	107	2	we	we	PRON
ajst-6292	107	3	sincerely	sincerely	ADV
ajst-6292	107	4	thank	thank	VERB
ajst-6292	107	5	the	the	DET
ajst-6292	107	6	financial	financial	ADJ
ajst-6292	107	7	support	support	NOUN
ajst-6292	107	8	from	from	ADP
ajst-6292	107	9	the	the	DET
ajst-6292	107	10	postgraduate	postgraduate	NOUN
ajst-6292	107	11	research	research	NOUN
ajst-6292	107	12	&	&	CCONJ
ajst-6292	107	13	practice	practice	PROPN
ajst-6292	107	14	innovation	innovation	NOUN
ajst-6292	107	15	program	program	NOUN
ajst-6292	107	16	of	of	ADP
ajst-6292	107	17	jiangsu	jiangsu	PROPN
ajst-6292	107	18	province	province	PROPN
ajst-6292	107	19	(	(	PUNCT
ajst-6292	107	20	grant	grant	VERB
ajst-6292	107	21	no	no	INTJ
ajst-6292	107	22	.	.	PUNCT
ajst-6292	108	1	sjcx22_1445	sjcx22_1445	NOUN
ajst-6292	109	1	and	and	CCONJ
ajst-6292	109	2	grant	grant	VERB
ajst-6292	109	3	no	no	INTJ
ajst-6292	109	4	.	.	PUNCT
ajst-6292	109	5	sjcx21_1239	sjcx21_1239	PROPN
ajst-6292	109	6	)	)	PUNCT
ajst-6292	109	7	.	.	PUNCT
ajst-6292	110	1	references	reference	NOUN
ajst-6292	110	2	[	[	X
ajst-6292	110	3	1	1	NUM
ajst-6292	110	4	]	]	X
ajst-6292	110	5	s.r	s.r	PROPN
ajst-6292	110	6	.	.	PROPN
ajst-6292	110	7	walker	walker	PROPN
ajst-6292	110	8	,	,	PUNCT
ajst-6292	110	9	e.j	e.j	PROPN
ajst-6292	110	10	.	.	PROPN
ajst-6292	110	11	carter	carter	PROPN
ajst-6292	110	12	,	,	PUNCT
ajst-6292	110	13	b.c	b.c	PROPN
ajst-6292	110	14	.	.	PROPN
ajst-6292	110	15	huff	huff	PROPN
ajst-6292	110	16	,	,	PUNCT
ajst-6292	110	17	and	and	CCONJ
ajst-6292	110	18	j.c	j.c	PROPN
ajst-6292	110	19	.	.	PROPN
ajst-6292	110	20	morris	morris	PROPN
ajst-6292	110	21	,	,	PUNCT
ajst-6292	110	22	“	"	PUNCT
ajst-6292	110	23	variolins	variolin	NOUN
ajst-6292	110	24	and	and	CCONJ
ajst-6292	110	25	related	relate	VERB
ajst-6292	110	26	alkaloids	alkaloid	NOUN
ajst-6292	110	27	”	"	PUNCT
ajst-6292	110	28	,	,	PUNCT
ajst-6292	110	29	chemical	chemical	NOUN
ajst-6292	110	30	reviews	review	NOUN
ajst-6292	110	31	,	,	PUNCT
ajst-6292	110	32	2009	2009	NUM
ajst-6292	110	33	,	,	PUNCT
ajst-6292	110	34	vol	vol	NOUN
ajst-6292	110	35	.	.	PUNCT
ajst-6292	110	36	109(7	109(7	NUM
ajst-6292	110	37	)	)	PUNCT
ajst-6292	110	38	,	,	PUNCT
ajst-6292	110	39	p3080	p3080	PROPN
ajst-6292	110	40	.	.	PUNCT
ajst-6292	111	1	[	[	X
ajst-6292	111	2	2	2	NUM
ajst-6292	111	3	]	]	X
ajst-6292	111	4	m.f	m.f	PROPN
ajst-6292	111	5	.	.	PROPN
ajst-6292	111	6	pilar	pilar	PROPN
ajst-6292	111	7	,	,	PUNCT
ajst-6292	111	8	m.	m.	NOUN
ajst-6292	111	9	pedro	pedro	PROPN
ajst-6292	111	10	,	,	PUNCT
ajst-6292	111	11	d.	d.	PROPN
ajst-6292	111	12	santiago	santiago	PROPN
ajst-6292	111	13	,	,	PUNCT
ajst-6292	111	14	“	"	PUNCT
ajst-6292	111	15	synthetic	synthetic	ADJ
ajst-6292	111	16	studies	study	NOUN
ajst-6292	111	17	towards	towards	ADP
ajst-6292	111	18	the	the	DET
ajst-6292	111	19	2	2	NUM
ajst-6292	111	20	-	-	PUNCT
ajst-6292	111	21	aminopyrimidine	aminopyrimidine	NOUN
ajst-6292	111	22	alkaloids	alkaloid	NOUN
ajst-6292	111	23	variolins	variolin	NOUN
ajst-6292	111	24	and	and	CCONJ
ajst-6292	111	25	meridianins	meridianin	NOUN
ajst-6292	111	26	from	from	ADP
ajst-6292	111	27	marine	marine	ADJ
ajst-6292	111	28	origin	origin	NOUN
ajst-6292	111	29	”	"	PUNCT
ajst-6292	111	30	,	,	PUNCT
ajst-6292	111	31	tetrahedron	tetrahedron	NOUN
ajst-6292	111	32	letters	letter	NOUN
ajst-6292	111	33	,	,	PUNCT
ajst-6292	111	34	2000	2000	NUM
ajst-6292	111	35	,	,	PUNCT
ajst-6292	111	36	vol	vol	NOUN
ajst-6292	111	37	.	.	NOUN
ajst-6292	111	38	41(24	41(24	NUM
ajst-6292	111	39	)	)	PUNCT
ajst-6292	111	40	,	,	PUNCT
ajst-6292	111	41	p4777	p4777	PROPN
ajst-6292	111	42	-	-	PUNCT
ajst-6292	111	43	4780．	4780．	PROPN
ajst-6292	111	44	[	[	X
ajst-6292	111	45	3	3	NUM
ajst-6292	111	46	]	]	PUNCT
ajst-6292	111	47	m.	m.	NOUN
ajst-6292	111	48	simone	simone	PROPN
ajst-6292	111	49	,	,	PUNCT
ajst-6292	111	50	e.	e.	PROPN
ajst-6292	111	51	erba	erba	PROPN
ajst-6292	111	52	,	,	PUNCT
ajst-6292	111	53	g.	g.	PROPN
ajst-6292	111	54	damia	damia	PROPN
ajst-6292	111	55	,	,	PUNCT
ajst-6292	111	56	f.	f.	PROPN
ajst-6292	111	57	vikhanskaya	vikhanskaya	PROPN
ajst-6292	111	58	and	and	CCONJ
ajst-6292	111	59	r.	r.	PROPN
ajst-6292	111	60	riccardi	riccardi	PROPN
ajst-6292	111	61	,	,	PUNCT
ajst-6292	111	62	“	"	PUNCT
ajst-6292	111	63	variolin	variolin	NOUN
ajst-6292	111	64	b	b	NOUN
ajst-6292	111	65	and	and	CCONJ
ajst-6292	111	66	its	its	PRON
ajst-6292	111	67	derivate	derivate	NOUN
ajst-6292	111	68	deoxy	deoxy	NOUN
ajst-6292	111	69	-	-	NOUN
ajst-6292	111	70	variolin	variolin	NOUN
ajst-6292	111	71	b	b	NOUN
ajst-6292	111	72	:	:	PUNCT
ajst-6292	111	73	new	new	ADJ
ajst-6292	111	74	marine	marine	ADJ
ajst-6292	111	75	natural	natural	ADJ
ajst-6292	111	76	compounds	compound	NOUN
ajst-6292	111	77	with	with	ADP
ajst-6292	111	78	cyclin	cyclin	NOUN
ajst-6292	111	79	-	-	PUNCT
ajst-6292	111	80	dependent	dependent	ADJ
ajst-6292	111	81	kinase	kinase	NOUN
ajst-6292	111	82	inhibitor	inhibitor	NOUN
ajst-6292	111	83	activity	activity	NOUN
ajst-6292	111	84	”	"	PUNCT
ajst-6292	111	85	,	,	PUNCT
ajst-6292	111	86	european	european	PROPN
ajst-6292	111	87	journal	journal	PROPN
ajst-6292	111	88	of	of	ADP
ajst-6292	111	89	cancer	cancer	NOUN
ajst-6292	111	90	,	,	PUNCT
ajst-6292	111	91	2005	2005	NUM
ajst-6292	111	92	,	,	PUNCT
ajst-6292	111	93	vol	vol	NOUN
ajst-6292	111	94	.	.	PUNCT
ajst-6292	112	1	41(15	41(15	NUM
ajst-6292	112	2	)	)	PUNCT
ajst-6292	112	3	,	,	PUNCT
ajst-6292	112	4	p2366	p2366	PROPN
ajst-6292	112	5	-	-	SYM
ajst-6292	112	6	2377	2377	NUM
ajst-6292	112	7	.	.	PUNCT
ajst-6292	113	1	[	[	X
ajst-6292	113	2	4	4	NUM
ajst-6292	113	3	]	]	PUNCT
ajst-6292	113	4	m.	m.	NOUN
ajst-6292	113	5	gompel	gompel	PROPN
ajst-6292	113	6	,	,	PUNCT
ajst-6292	113	7	m.	m.	NOUN
ajst-6292	113	8	leost	leost	PROPN
ajst-6292	113	9	,	,	PUNCT
ajst-6292	113	10	e.	e.	PROPN
ajst-6292	113	11	joffe	joffe	PROPN
ajst-6292	113	12	,	,	PUNCT
ajst-6292	113	13	l.	l.	PROPN
ajst-6292	113	14	puricelli	puricelli	PROPN
ajst-6292	113	15	,	,	PUNCT
ajst-6292	113	16	l.h	l.h	PROPN
ajst-6292	113	17	.	.	PROPN
ajst-6292	113	18	franco	franco	PROPN
ajst-6292	113	19	and	and	CCONJ
ajst-6292	113	20	j.	j.	PROPN
ajst-6292	113	21	palermo	palermo	PROPN
ajst-6292	113	22	,	,	PUNCT
ajst-6292	113	23	“	"	PUNCT
ajst-6292	113	24	meridianins	meridianin	NOUN
ajst-6292	113	25	,	,	PUNCT
ajst-6292	113	26	a	a	DET
ajst-6292	113	27	new	new	ADJ
ajst-6292	113	28	family	family	NOUN
ajst-6292	113	29	of	of	ADP
ajst-6292	113	30	protein	protein	NOUN
ajst-6292	113	31	kinase	kinase	PROPN
ajst-6292	113	32	inhibitors	inhibitor	NOUN
ajst-6292	113	33	isolated	isolate	VERB
ajst-6292	113	34	from	from	ADP
ajst-6292	113	35	the	the	DET
ajst-6292	113	36	ascidian	ascidian	ADJ
ajst-6292	113	37	aplidium	aplidium	NOUN
ajst-6292	113	38	meridianum	meridianum	PROPN
ajst-6292	113	39	”	"	PUNCT
ajst-6292	113	40	,	,	PUNCT
ajst-6292	113	41	cheminform	cheminform	NOUN
ajst-6292	113	42	,	,	PUNCT
ajst-6292	113	43	2004	2004	NUM
ajst-6292	113	44	,	,	PUNCT
ajst-6292	113	45	vol	vol	NOUN
ajst-6292	113	46	.	.	PUNCT
ajst-6292	113	47	35(7	35(7	NUM
ajst-6292	113	48	)	)	PUNCT
ajst-6292	113	49	,	,	PUNCT
ajst-6292	113	50	p1703	p1703	PROPN
ajst-6292	113	51	-	-	PUNCT
ajst-6292	113	52	1707	1707	NUM
ajst-6292	113	53	.	.	PUNCT
ajst-6292	114	1	[	[	X
ajst-6292	114	2	5	5	X
ajst-6292	114	3	]	]	PUNCT
ajst-6292	114	4	s.	s.	PROPN
ajst-6292	114	5	dan	dan	PROPN
ajst-6292	114	6	,	,	PUNCT
ajst-6292	114	7	w.	w.	PROPN
ajst-6292	114	8	wenbin	wenbin	PROPN
ajst-6292	114	9	,	,	PUNCT
ajst-6292	114	10	w.	w.	PROPN
ajst-6292	114	11	xinyue	xinyue	PROPN
ajst-6292	114	12	,	,	PUNCT
ajst-6292	114	13	l.	l.	PROPN
ajst-6292	114	14	minyue	minyue	PROPN
ajst-6292	114	15	,	,	PUNCT
ajst-6292	114	16	y.	y.	PROPN
ajst-6292	114	17	xue	xue	PROPN
ajst-6292	114	18	and	and	CCONJ
ajst-6292	114	19	h.	h.	PROPN
ajst-6292	114	20	zhonghong	zhonghong	PROPN
ajst-6292	114	21	,	,	PUNCT
ajst-6292	114	22	“	"	PUNCT
ajst-6292	114	23	meriolin1	meriolin1	NOUN
ajst-6292	114	24	induces	induce	VERB
ajst-6292	114	25	cell	cell	NOUN
ajst-6292	114	26	cycle	cycle	NOUN
ajst-6292	114	27	arrest	arrest	NOUN
ajst-6292	114	28	,	,	PUNCT
ajst-6292	114	29	apoptosis	apoptosis	NOUN
ajst-6292	114	30	,	,	PUNCT
ajst-6292	114	31	autophagy	autophagy	NOUN
ajst-6292	114	32	and	and	CCONJ
ajst-6292	114	33	targeting	target	VERB
ajst-6292	114	34	the	the	DET
ajst-6292	114	35	akt	akt	PROPN
ajst-6292	114	36	/	/	SYM
ajst-6292	114	37	mapks	mapks	NOUN
ajst-6292	114	38	pathways	pathway	NOUN
ajst-6292	114	39	in	in	ADP
ajst-6292	114	40	human	human	ADJ
ajst-6292	114	41	neuroblastoma	neuroblastoma	NOUN
ajst-6292	114	42	sh	sh	PROPN
ajst-6292	114	43	-	-	PUNCT
ajst-6292	114	44	sy5y	sy5y	PROPN
ajst-6292	114	45	cells	cell	NOUN
ajst-6292	114	46	”	"	PUNCT
ajst-6292	114	47	,	,	PUNCT
ajst-6292	114	48	the	the	DET
ajst-6292	114	49	journal	journal	NOUN
ajst-6292	114	50	of	of	ADP
ajst-6292	114	51	pharmacy	pharmacy	NOUN
ajst-6292	114	52	and	and	CCONJ
ajst-6292	114	53	pharmacology	pharmacology	NOUN
ajst-6292	114	54	,	,	PUNCT
ajst-6292	114	55	2019	2019	NUM
ajst-6292	114	56	,	,	PUNCT
ajst-6292	114	57	vol	vol	NOUN
ajst-6292	114	58	.	.	PUNCT
ajst-6292	115	1	72(4	72(4	NUM
ajst-6292	115	2	)	)	PUNCT
ajst-6292	115	3	,	,	PUNCT
ajst-6292	115	4	p561	p561	PROPN
ajst-6292	115	5	-	-	PUNCT
ajst-6292	115	6	574	574	NUM
ajst-6292	115	7	.	.	PUNCT
ajst-6292	116	1	[	[	X
ajst-6292	116	2	6	6	NUM
ajst-6292	116	3	]	]	PUNCT
ajst-6292	116	4	j.	j.	PROPN
ajst-6292	116	5	dumas	dumas	PROPN
ajst-6292	116	6	,	,	PUNCT
ajst-6292	116	7	“	"	PUNCT
ajst-6292	116	8	protein	protein	NOUN
ajst-6292	116	9	kinase	kinase	NOUN
ajst-6292	116	10	inhibitors	inhibitor	NOUN
ajst-6292	116	11	：	：	PUNCT
ajst-6292	116	12	emerging	emerge	VERB
ajst-6292	116	13	pharmacophores	pharmacophore	NOUN
ajst-6292	116	14	1997	1997	NUM
ajst-6292	116	15	-	-	SYM
ajst-6292	116	16	2000	2000	NUM
ajst-6292	116	17	”	"	PUNCT
ajst-6292	116	18	,	,	PUNCT
ajst-6292	116	19	expert	expert	ADJ
ajst-6292	116	20	opinion	opinion	NOUN
ajst-6292	116	21	on	on	ADP
ajst-6292	116	22	therapeutic	therapeutic	ADJ
ajst-6292	116	23	patents	patent	NOUN
ajst-6292	116	24	,	,	PUNCT
ajst-6292	116	25	2001	2001	NUM
ajst-6292	116	26	,	,	PUNCT
ajst-6292	116	27	vol	vol	NOUN
ajst-6292	116	28	.	.	PUNCT
ajst-6292	116	29	11(3	11(3	NUM
ajst-6292	116	30	)	)	PUNCT
ajst-6292	116	31	,	,	PUNCT
ajst-6292	116	32	p405	p405	PROPN
ajst-6292	116	33	-	-	SYM
ajst-6292	116	34	429	429	NUM
ajst-6292	116	35	.	.	PUNCT
ajst-6292	117	1	[	[	X
ajst-6292	117	2	7	7	X
ajst-6292	117	3	]	]	X
ajst-6292	117	4	p.	p.	NOUN
ajst-6292	117	5	traxler	traxler	NOUN
ajst-6292	117	6	,	,	PUNCT
ajst-6292	117	7	p.	p.	PROPN
ajst-6292	117	8	furet	furet	PROPN
ajst-6292	117	9	,	,	PUNCT
ajst-6292	117	10	“	"	PUNCT
ajst-6292	117	11	strategies	strategy	NOUN
ajst-6292	117	12	toward	toward	ADP
ajst-6292	117	13	the	the	DET
ajst-6292	117	14	design	design	NOUN
ajst-6292	117	15	of	of	ADP
ajst-6292	117	16	novel	novel	NOUN
ajst-6292	117	17	and	and	CCONJ
ajst-6292	117	18	selective	selective	ADJ
ajst-6292	117	19	protein	protein	NOUN
ajst-6292	117	20	tyrosine	tyrosine	NOUN
ajst-6292	117	21	kinase	kinase	PROPN
ajst-6292	117	22	inhibitors	inhibitor	NOUN
ajst-6292	117	23	”	"	PUNCT
ajst-6292	117	24	,	,	PUNCT
ajst-6292	117	25	pharmacology	pharmacology	NOUN
ajst-6292	117	26	therapeutics	therapeutic	NOUN
ajst-6292	117	27	,	,	PUNCT
ajst-6292	117	28	1999	1999	NUM
ajst-6292	117	29	,	,	PUNCT
ajst-6292	117	30	vol	vol	NOUN
ajst-6292	117	31	.	.	PROPN
ajst-6292	117	32	82(2	82(2	NUM
ajst-6292	117	33	)	)	PUNCT
ajst-6292	117	34	,	,	PUNCT
ajst-6292	117	35	p195	p195	PROPN
ajst-6292	117	36	-	-	NOUN
ajst-6292	117	37	206	206	NUM
ajst-6292	117	38	.	.	PUNCT
ajst-6292	118	1	[	[	X
ajst-6292	118	2	8	8	NUM
ajst-6292	118	3	]	]	SYM
ajst-6292	118	4	e.k	e.k	PROPN
ajst-6292	118	5	.	.	PROPN
ajst-6292	118	6	bettay	bettay	PROPN
ajst-6292	118	7	,	,	PUNCT
ajst-6292	118	8	o.m	o.m	PROPN
ajst-6292	118	9	.	.	PROPN
ajst-6292	118	10	tirado	tirado	PROPN
ajst-6292	118	11	,	,	PUNCT
ajst-6292	118	12	l.s	l.s	PROPN
ajst-6292	118	13	.	.	PROPN
ajst-6292	118	14	marionneau	marionneau	PROPN
ajst-6292	118	15	,	,	PUNCT
ajst-6292	118	16	y.	y.	PROPN
ajst-6292	118	17	ferandin	ferandin	PROPN
ajst-6292	118	18	,	,	PUNCT
ajst-6292	118	19	o.	o.	PROPN
ajst-6292	118	20	lozach	lozach	PROPN
ajst-6292	118	21	and	and	CCONJ
ajst-6292	118	22	j.c	j.c	PROPN
ajst-6292	118	23	.	.	PROPN
ajst-6292	118	24	morris	morris	PROPN
ajst-6292	118	25	,	,	PUNCT
ajst-6292	118	26	“	"	PUNCT
ajst-6292	118	27	meriolins	meriolin	NOUN
ajst-6292	118	28	,	,	PUNCT
ajst-6292	118	29	a	a	DET
ajst-6292	118	30	new	new	ADJ
ajst-6292	118	31	class	class	NOUN
ajst-6292	118	32	of	of	ADP
ajst-6292	118	33	cell	cell	NOUN
ajst-6292	118	34	death	death	NOUN
ajst-6292	118	35	inducing	induce	VERB
ajst-6292	118	36	kinase	kinase	ADJ
ajst-6292	118	37	inhibitors	inhibitor	NOUN
ajst-6292	118	38	with	with	ADP
ajst-6292	118	39	enhanced	enhanced	ADJ
ajst-6292	118	40	selectivity	selectivity	NOUN
ajst-6292	118	41	for	for	ADP
ajst-6292	118	42	cyclindependent	cyclindependent	NOUN
ajst-6292	118	43	kinases	kinase	NOUN
ajst-6292	118	44	”	"	PUNCT
ajst-6292	118	45	,	,	PUNCT
ajst-6292	118	46	cancer	cancer	NOUN
ajst-6292	118	47	research	research	NOUN
ajst-6292	118	48	,	,	PUNCT
ajst-6292	118	49	2007	2007	NUM
ajst-6292	118	50	,	,	PUNCT
ajst-6292	118	51	vol	vol	NOUN
ajst-6292	118	52	,	,	PUNCT
ajst-6292	118	53	67(17	67(17	NUM
ajst-6292	118	54	)	)	PUNCT
ajst-6292	118	55	,	,	PUNCT
ajst-6292	118	56	p8325	p8325	PROPN
ajst-6292	118	57	-	-	PROPN
ajst-6292	118	58	8334	8334	NUM
ajst-6292	118	59	.	.	PUNCT
ajst-6292	119	1	[	[	X
ajst-6292	119	2	9	9	NUM
ajst-6292	119	3	]	]	X
ajst-6292	119	4	a.s	a.s	PROPN
ajst-6292	119	5	.	.	PROPN
ajst-6292	119	6	karpov	karpov	PROPN
ajst-6292	119	7	,	,	PUNCT
ajst-6292	119	8	e.	e.	PROPN
ajst-6292	119	9	merkul	merkul	PROPN
ajst-6292	119	10	,	,	PUNCT
ajst-6292	119	11	f.	f.	PROPN
ajst-6292	119	12	rominger	rominger	PROPN
ajst-6292	119	13	and	and	CCONJ
ajst-6292	119	14	t.	t.	PROPN
ajst-6292	119	15	mueller	mueller	PROPN
ajst-6292	119	16	,	,	PUNCT
ajst-6292	119	17	“	"	PUNCT
ajst-6292	119	18	concise	concise	ADJ
ajst-6292	119	19	syntheses	synthesis	NOUN
ajst-6292	119	20	of	of	ADP
ajst-6292	119	21	meridianins	meridianin	NOUN
ajst-6292	119	22	by	by	ADP
ajst-6292	119	23	carbonylative	carbonylative	ADJ
ajst-6292	119	24	alkynylation	alkynylation	NOUN
ajst-6292	119	25	and	and	CCONJ
ajst-6292	119	26	a	a	DET
ajst-6292	119	27	four	four	NUM
ajst-6292	119	28	-	-	PUNCT
ajst-6292	119	29	component	component	NOUN
ajst-6292	119	30	pyrimidine	pyrimidine	NOUN
ajst-6292	119	31	synthesis	synthesis	NOUN
ajst-6292	119	32	”	"	PUNCT
ajst-6292	119	33	,	,	PUNCT
ajst-6292	119	34	cheminform	cheminform	NOUN
ajst-6292	119	35	,	,	PUNCT
ajst-6292	119	36	2006	2006	NUM
ajst-6292	119	37	,	,	PUNCT
ajst-6292	119	38	vol	vol	NOUN
ajst-6292	119	39	.	.	PUNCT
ajst-6292	119	40	44(42	44(42	NUM
ajst-6292	119	41	)	)	PUNCT
ajst-6292	119	42	,	,	PUNCT
ajst-6292	119	43	p6951	p6951	NOUN
ajst-6292	119	44	-	-	SYM
ajst-6292	119	45	6956	6956	NUM
ajst-6292	119	46	.	.	PUNCT
ajst-6292	120	1	[	[	X
ajst-6292	120	2	10	10	NUM
ajst-6292	120	3	]	]	X
ajst-6292	120	4	e.	e.	PROPN
ajst-6292	120	5	merkul	merkul	PROPN
ajst-6292	120	6	,	,	PUNCT
ajst-6292	120	7	e.	e.	PROPN
ajst-6292	120	8	schaefe	schaefe	PROPN
ajst-6292	120	9	,	,	PUNCT
ajst-6292	120	10	and	and	CCONJ
ajst-6292	120	11	t.j.j	t.j.j	NOUN
ajst-6292	120	12	.	.	PUNCT
ajst-6292	121	1	mueller	mueller	PROPN
ajst-6292	121	2	,	,	PUNCT
ajst-6292	121	3	“	"	PUNCT
ajst-6292	121	4	rapid	rapid	ADJ
ajst-6292	121	5	synthesis	synthesis	NOUN
ajst-6292	121	6	of	of	ADP
ajst-6292	121	7	bis(hetero)aryls	bis(hetero)aryls	NUM
ajst-6292	121	8	by	by	ADP
ajst-6292	121	9	one	one	NUM
ajst-6292	121	10	-	-	PUNCT
ajst-6292	121	11	pot	pot	NOUN
ajst-6292	121	12	masuda	masuda	PROPN
ajst-6292	121	13	borylation	borylation	PROPN
ajst-6292	121	14	-	-	PUNCT
ajst-6292	121	15	suzuki	suzuki	PROPN
ajst-6292	121	16	coupling	coupling	NOUN
ajst-6292	121	17	sequence	sequence	NOUN
ajst-6292	121	18	and	and	CCONJ
ajst-6292	121	19	its	its	PRON
ajst-6292	121	20	application	application	NOUN
ajst-6292	121	21	to	to	PART
ajst-6292	121	22	concise	concise	ADJ
ajst-6292	121	23	total	total	ADJ
ajst-6292	121	24	syntheses	synthesis	NOUN
ajst-6292	121	25	of	of	ADP
ajst-6292	121	26	meridianins	meridianin	NOUN
ajst-6292	121	27	a	a	PRON
ajst-6292	121	28	and	and	CCONJ
ajst-6292	121	29	g	g	NOUN
ajst-6292	121	30	”	"	PUNCT
ajst-6292	121	31	,	,	PUNCT
ajst-6292	121	32	organic	organic	ADJ
ajst-6292	121	33	&	&	CCONJ
ajst-6292	121	34	biomolecular	biomolecular	ADJ
ajst-6292	121	35	chemistry	chemistry	NOUN
ajst-6292	121	36	,	,	PUNCT
ajst-6292	121	37	2011	2011	NUM
ajst-6292	121	38	,	,	PUNCT
ajst-6292	121	39	vol	vol	NOUN
ajst-6292	121	40	.	.	PUNCT
ajst-6292	122	1	9(9	9(9	NUM
ajst-6292	122	2	)	)	PUNCT
ajst-6292	122	3	,	,	PUNCT
ajst-6292	122	4	p3139	p3139	PROPN
ajst-6292	122	5	-	-	PUNCT
ajst-6292	122	6	3141	3141	NUM
ajst-6292	122	7	.	.	PUNCT
ajst-6292	123	1	[	[	X
ajst-6292	123	2	11	11	NUM
ajst-6292	123	3	]	]	PUNCT
ajst-6292	123	4	w.	w.	PROPN
ajst-6292	123	5	bernhard	bernhard	PROPN
ajst-6292	123	6	,	,	PUNCT
ajst-6292	123	7	b.	b.	PROPN
ajst-6292	123	8	nicole	nicole	PROPN
ajst-6292	123	9	,	,	PUNCT
ajst-6292	123	10	and	and	CCONJ
ajst-6292	123	11	b.	b.	PROPN
ajst-6292	123	12	uwe	uwe	PROPN
ajst-6292	123	13	,	,	PUNCT
ajst-6292	123	14	“	"	PUNCT
ajst-6292	123	15	hydroboration	hydroboration	NOUN
ajst-6292	123	16	and	and	CCONJ
ajst-6292	123	17	suzuki	suzuki	NOUN
ajst-6292	123	18	-	-	PUNCT
ajst-6292	123	19	miyaura	miyaura	NOUN
ajst-6292	123	20	coupling	coupling	NOUN
ajst-6292	123	21	reactions	reaction	NOUN
ajst-6292	123	22	with	with	ADP
ajst-6292	123	23	the	the	DET
ajst-6292	123	24	electronically	electronically	ADV
ajst-6292	123	25	modulated	modulate	VERB
ajst-6292	123	26	variant	variant	NOUN
ajst-6292	123	27	of	of	ADP
ajst-6292	123	28	an	an	DET
ajst-6292	123	29	ynamine	ynamine	NOUN
ajst-6292	123	30	:	:	PUNCT
ajst-6292	123	31	the	the	DET
ajst-6292	123	32	synthesis	synthesis	NOUN
ajst-6292	123	33	of	of	ADP
ajst-6292	123	34	(	(	PUNCT
ajst-6292	123	35	e)-βarylenamides	e)-βarylenamide	NOUN
ajst-6292	123	36	”	"	PUNCT
ajst-6292	123	37	,	,	PUNCT
ajst-6292	123	38	tetrahedron	tetrahedron	NOUN
ajst-6292	123	39	,	,	PUNCT
ajst-6292	123	40	2000	2000	NUM
ajst-6292	123	41	,	,	PUNCT
ajst-6292	123	42	vol	vol	NOUN
ajst-6292	123	43	.	.	PUNCT
ajst-6292	123	44	56(43	56(43	NUM
ajst-6292	123	45	)	)	PUNCT
ajst-6292	123	46	,	,	PUNCT
ajst-6292	123	47	p8473	p8473	VERB
ajst-6292	123	48	.	.	PUNCT
ajst-6292	124	1	[	[	X
ajst-6292	124	2	12	12	NUM
ajst-6292	124	3	]	]	X
ajst-6292	124	4	a.k	a.k	PROPN
ajst-6292	124	5	.	.	PROPN
ajst-6292	124	6	venkata	venkata	PROPN
ajst-6292	124	7	,	,	PUNCT
ajst-6292	124	8	s.	s.	PROPN
ajst-6292	124	9	feng	feng	PROPN
ajst-6292	124	10	,	,	PUNCT
ajst-6292	124	11	and	and	CCONJ
ajst-6292	124	12	f.	f.	PROPN
ajst-6292	124	13	sulagna	sulagna	PROPN
ajst-6292	124	14	,	,	PUNCT
ajst-6292	124	15	“	"	PUNCT
ajst-6292	124	16	cheminform	cheminform	NOUN
ajst-6292	124	17	abstract	abstract	NOUN
ajst-6292	124	18	:	:	PUNCT
ajst-6292	124	19	boc	boc	NOUN
ajst-6292	124	20	groups	group	NOUN
ajst-6292	124	21	as	as	ADP
ajst-6292	124	22	protectors	protector	NOUN
ajst-6292	124	23	and	and	CCONJ
ajst-6292	124	24	directors	director	NOUN
ajst-6292	124	25	for	for	ADP
ajst-6292	124	26	ir	ir	NOUN
ajst-6292	124	27	-	-	PUNCT
ajst-6292	124	28	catalyzed	catalyze	VERB
ajst-6292	124	29	c	c	NOUN
ajst-6292	124	30	-	-	PUNCT
ajst-6292	124	31	h	h	NOUN
ajst-6292	124	32	borylation	borylation	NOUN
ajst-6292	124	33	of	of	ADP
ajst-6292	124	34	heterocycles	heterocycle	NOUN
ajst-6292	124	35	”	"	PUNCT
ajst-6292	124	36	,	,	PUNCT
ajst-6292	124	37	cheminform	cheminform	NOUN
ajst-6292	124	38	,	,	PUNCT
ajst-6292	124	39	2010	2010	NUM
ajst-6292	124	40	,	,	PUNCT
ajst-6292	124	41	vol	vol	NOUN
ajst-6292	124	42	.	.	PUNCT
ajst-6292	125	1	41(18	41(18	NUM
ajst-6292	125	2	)	)	PUNCT
ajst-6292	125	3	,	,	PUNCT
ajst-6292	125	4	p9199	p9199	NOUN
ajst-6292	125	5	-	-	PUNCT
ajst-6292	125	6	9201	9201	NUM
ajst-6292	125	7	.	.	PUNCT
ajst-6292	126	1	[	[	X
ajst-6292	126	2	13	13	NUM
ajst-6292	126	3	]	]	X
ajst-6292	126	4	s.r	s.r	PROPN
ajst-6292	126	5	.	.	PROPN
ajst-6292	126	6	walker	walker	PROPN
ajst-6292	126	7	,	,	PUNCT
ajst-6292	126	8	m.l	m.l	PROPN
ajst-6292	126	9	.	.	PROPN
ajst-6292	126	10	czyz	czyz	PROPN
ajst-6292	126	11	and	and	CCONJ
ajst-6292	126	12	j.c	j.c	PROPN
ajst-6292	126	13	.	.	PROPN
ajst-6292	126	14	morris	morris	PROPN
ajst-6292	126	15	,	,	PUNCT
ajst-6292	126	16	“	"	PUNCT
ajst-6292	126	17	concise	concise	ADJ
ajst-6292	126	18	syntheses	synthesis	NOUN
ajst-6292	126	19	of	of	ADP
ajst-6292	126	20	meridianins	meridianin	NOUN
ajst-6292	126	21	and	and	CCONJ
ajst-6292	126	22	meriolins	meriolin	NOUN
ajst-6292	126	23	using	use	VERB
ajst-6292	126	24	a	a	DET
ajst-6292	126	25	catalytic	catalytic	ADJ
ajst-6292	126	26	domino	domino	NOUN
ajst-6292	126	27	aminopalladation	aminopalladation	NOUN
ajst-6292	126	28	reaction	reaction	NOUN
ajst-6292	126	29	”	"	PUNCT
ajst-6292	126	30	,	,	PUNCT
ajst-6292	126	31	organic	organic	ADJ
ajst-6292	126	32	letters	letter	NOUN
ajst-6292	126	33	,	,	PUNCT
ajst-6292	126	34	2014	2014	NUM
ajst-6292	126	35	,	,	PUNCT
ajst-6292	126	36	vol	vol	NOUN
ajst-6292	126	37	.	.	PUNCT
ajst-6292	126	38	16(3	16(3	NUM
ajst-6292	126	39	)	)	PUNCT
ajst-6292	126	40	,	,	PUNCT
ajst-6292	126	41	p708	p708	NUM
ajst-6292	126	42	.	.	PUNCT
ajst-6292	127	1	[	[	X
ajst-6292	127	2	14	14	NUM
ajst-6292	127	3	]	]	PUNCT
ajst-6292	127	4	a.	a.	NOUN
ajst-6292	127	5	fathi	fathi	PROPN
ajst-6292	127	6	,	,	PUNCT
ajst-6292	127	7	a.	a.	PROPN
ajst-6292	127	8	ahmed，and	ahmed，and	PROPN
ajst-6292	127	9	m.	m.	PROPN
ajst-6292	127	10	sayed	say	VERB
ajst-6292	127	11	,	,	PUNCT
ajst-6292	127	12	“	"	PUNCT
ajst-6292	127	13	synthesis	synthesis	NOUN
ajst-6292	127	14	of	of	ADP
ajst-6292	127	15	1,4	1,4	NUM
ajst-6292	127	16	-	-	PUNCT
ajst-6292	127	17	diarylpiperazine-2,5	diarylpiperazine-2,5	ADP
ajst-6292	127	18	-	-	PUNCT
ajst-6292	127	19	diones	dione	NOUN
ajst-6292	127	20	：	：	PUNCT
ajst-6292	127	21	new	new	ADJ
ajst-6292	127	22	behavior	behavior	NOUN
ajst-6292	127	23	of	of	ADP
ajst-6292	127	24	n	n	CCONJ
ajst-6292	127	25	,	,	PUNCT
ajst-6292	127	26	ndimethylformamide	ndimethylformamide	ADJ
ajst-6292	127	27	dimethyl	dimethyl	PROPN
ajst-6292	127	28	acetal	acetal	PROPN
ajst-6292	127	29	(	(	PUNCT
ajst-6292	127	30	dmfdma	dmfdma	NOUN
ajst-6292	127	31	)	)	PUNCT
ajst-6292	127	32	”	"	PUNCT
ajst-6292	127	33	,	,	PUNCT
ajst-6292	127	34	synthetic	synthetic	ADJ
ajst-6292	127	35	communications	communication	NOUN
ajst-6292	127	36	,	,	PUNCT
ajst-6292	127	37	2008	2008	NUM
ajst-6292	127	38	,	,	PUNCT
ajst-6292	127	39	vol	vol	NOUN
ajst-6292	127	40	.	.	PUNCT
ajst-6292	128	1	38(3	38(3	NUM
ajst-6292	128	2	)	)	PUNCT
ajst-6292	128	3	,	,	PUNCT
ajst-6292	129	1	p376	p376	PROPN
ajst-6292	129	2	-	-	PUNCT
ajst-6292	129	3	382	382	NUM
ajst-6292	129	4	.	.	PUNCT
ajst-6292	130	1	[	[	X
ajst-6292	130	2	15	15	NUM
ajst-6292	130	3	]	]	X
ajst-6292	130	4	t.m	t.m	PROPN
ajst-6292	130	5	.	.	PROPN
ajst-6292	130	6	tarasiuk	tarasiuk	PROPN
ajst-6292	130	7	,	,	PUNCT
ajst-6292	130	8	a.v	a.v	PROPN
ajst-6292	130	9	.	.	PROPN
ajst-6292	130	10	tatyana	tatyana	PROPN
ajst-6292	130	11	,	,	PUNCT
ajst-6292	130	12	and	and	CCONJ
ajst-6292	130	13	s.p	s.p	PROPN
ajst-6292	130	14	.	.	PROPN
ajst-6292	130	15	kirill	kirill	PROPN
ajst-6292	130	16	,	,	PUNCT
ajst-6292	130	17	“	"	PUNCT
ajst-6292	130	18	reactions	reaction	NOUN
ajst-6292	130	19	of	of	ADP
ajst-6292	130	20	4,5	4,5	NUM
ajst-6292	130	21	-	-	PUNCT
ajst-6292	130	22	dihydro-1,4	dihydro-1,4	NUM
ajst-6292	130	23	-	-	PUNCT
ajst-6292	130	24	benzothiazepin-3(2h)-one1,1	benzothiazepin-3(2h)-one1,1	NOUN
ajst-6292	130	25	-	-	PUNCT
ajst-6292	130	26	dioxide	dioxide	NOUN
ajst-6292	130	27	and	and	CCONJ
ajst-6292	130	28	1,5	1,5	NUM
ajst-6292	130	29	-	-	PUNCT
ajst-6292	130	30	dihydro-4,1	dihydro-4,1	NOUN
ajst-6292	130	31	-	-	PUNCT
ajst-6292	130	32	benzothiazepin-2(3h)-one	benzothiazepin-2(3h)-one	NOUN
ajst-6292	130	33	4,4	4,4	ADJ
ajst-6292	130	34	-	-	PUNCT
ajst-6292	130	35	dioxide	dioxide	NOUN
ajst-6292	130	36	derivatives	derivative	NOUN
ajst-6292	130	37	with	with	ADP
ajst-6292	130	38	vilsmeier	vilsmeier	ADJ
ajst-6292	130	39	reagent	reagent	NOUN
ajst-6292	130	40	and	and	CCONJ
ajst-6292	130	41	dmfdma	dmfdma	NOUN
ajst-6292	130	42	”	"	PUNCT
ajst-6292	130	43	,	,	PUNCT
ajst-6292	130	44	journal	journal	NOUN
ajst-6292	130	45	of	of	ADP
ajst-6292	130	46	heterocyclic	heterocyclic	ADJ
ajst-6292	130	47	chemistry	chemistry	NOUN
ajst-6292	130	48	,	,	PUNCT
ajst-6292	130	49	2014	2014	NUM
ajst-6292	130	50	,	,	PUNCT
ajst-6292	130	51	vol	vol	NOUN
ajst-6292	130	52	.	.	PUNCT
ajst-6292	130	53	51(3	51(3	NUM
ajst-6292	130	54	)	)	PUNCT
ajst-6292	130	55	,	,	PUNCT
ajst-6292	130	56	p755	p755	PROPN
ajst-6292	130	57	-	-	SYM
ajst-6292	130	58	759	759	NUM
ajst-6292	130	59	.	.	PUNCT