Mathematic modeling of a new inlay buoyancy artefact ACTA IMEKO | www.imeko.org December 2020 | Volume 9 | Number 5 | 42 ACTA IMEKO ISSN: 2221-870X December 2020, Volume 9, Number 5, 42 - 46 MATHEMATIC MODELING OF A NEW INLAY BUOYANCY ARTEFACT K. Lehrmann1, F. Hรคrtig1, R. Tutsch2 1 Physikalisch-Technische Bundesanstalt, Braunschweig, Germany, katharina.lehrmann@ptb.de 2 Technical University Braunschweig, Institute of Production Metrology, Braunschweig, Germany, r.tutsch@tu-bs.de Abstract: The novel buoyancy artefact concept for the use in mass metrology enables the determination and correction of systematic air buoyancy effects caused by measurements outside a vacuum. In contrast to other buoyancy artefacts with a nominal mass of 1 kg, the new artefact, called inlay artefact, has a smaller volume resulting from an enclosed tungsten core. The theoretical design of the new artefact consists of dismountable discs with spherical distance pieces and a cylinder. This work focuses on the design and mathematical model considering limiting factors caused by the handling and the geometry of the comparators used. Keywords: buoyancy artefact; kilogram; silicon; inlay artefact; revised SI 1. INTRODUCTION Highly accurate mass calibrations require high sophisticated mass comparators which are operated in vacuum. Outside a vacuum the measurements are being strongly influenced by environmental conditions, such as buoyancy effects. This is particularly evident, if mass standards of the same nominal value made of different materials such as steel, platinum-iridium, or silicon are calibrated on the basis of a substitution method or compared against each other. In this case buoyancy effects significantly influence the findings because of the resulting different volumes [1]. One way to correct the buoyancy effects is to determine the air densities by using what is known as buoyancy artefacts calibrated by volume [2]. Most accurate results for the determination of air densities are achievable with a relative uncertainty in the order of magnitude of 5 ร— 10-5 [3]. Typically, aside the same nominal weight such artefacts have nearly the same surface areas and surface properties but different volumes. The greater the volume difference of buoyancy artefacts used, the more reliably the air density can be determined. A design is presented in order to achieve a large volume difference between buoyancy artefacts used. 2. DESIGN OF A NEW KIND OF BUOYANCY ARTEFACT Figure 1 shows a sketch of the proposed new buoyancy artefact. It consists of several discs made of monocrystalline silicon and one cylinder made of silicon with a tungsten core enclosed. The entire standard is referred to as an โ€œinlay artefactโ€. According to the principal approach of buoyancy artefacts, the nominal mass of the artefact ๐‘€ref is 1 kg and its nominal surface area must be identical to the surface area of the other buoyancy artefacts ๐ดref used. Due to the tungsten core the effective density of the artefact is much higher than the density of the buoyancy artefacts made of pure silicon. This leads to a smaller volume and thus, to less buoyancy. Distance pieces, which are part of a statically determined coupling, allow the stackable and demountable individual parts of the artefact to be dismantled for cleaning purposes. Figure 1: Exemplary figure of an inlay buoyancy artefact with two discs (top and center disc) and a cylinder with enclosed tungsten core For modeling the new buoyancy artefact, the following variable input parameters apply: โˆ’ the surface area ratio between discs and the cylinder โˆ’ the number of discs โˆ’ the diameter of the discs โˆ’ the diameter of the cylinder http://www.imeko.org/ mailto:katharina.lehrmann@ptb.de mailto:r.tutsch@tu-bs.de ACTA IMEKO | www.imeko.org December 2020 | Volume 9 | Number 5 | 43 For practical handling the radius of the discs and the cylinder should be equivalent. To achieve the specific surface areas, the surface area ratio of discs to cylinder should be at least two. First investigations have shown that the required surface area can be manufactured by three identical discs made of pure silicon. In order to provide enough volume to include a tungsten core the size of the ground disc have to be enlarged. From now on the ground disc was named cylinder (silicon disc with tungsten core). An additional estimation shows that the resulting surface area could be realized by a minimum of two further discs. Further requirements for the new buoyancy artefact are shown in Table 1 and depend on the geometric specifications of the comparators used, practical handling and the considerations of tilting stability. Table 1: Settings for numerical iteration Parameter Range max. total height โ„Žmax โ‰ค 105 mm tilt stability 20 mm โ‰ค ๐‘Ÿdsc, ๐‘Ÿcyl โ‰ค 45 mm number of discs 2 โ€“ 5 The silicon cylinder and the plug enclosing the inlay core are detachably bonded to each other according to the specifications of conical tapered ground joints [4] as used for gas-tight silicon oxide compounds. For all calculations, the density of silicon is assumed to be 2 328.8 kg/mยณ [5] and for tungsten is assumed to be 19 250.0 kg/mยณ [6]. 3. MATHEMATIC MODELING OF A NEW KIND OF BUOYANCY ARTEFACT For the sophisticated calculation of the inlay artefact, a number of limiting conditions have to be considered. For example, the surface area must correspond to a specified reference surface area and at the same time the mass must correspond to a specified nominal mass. In addition to the basic cylindrical geometry, the geometries of the spherical distance pieces and chamfers have to be taken into account for constructive reasons. Based on all these complex and correlated specifications, the radii and heights of the discs and the cylinder must be precisely dimensioned. In this section, first the calculations for the surface areas and then the masses are outlined. The corrections caused by chamfers are addressed comprehensively in section 4, while corrections relating to distance pieces are explained in section 5. In the following, this refers to all subsequent calculations that correlate with chamfers and distance pieces. 3.1. Calculation of the Surface Areas for Cylinder and Discs The pure surface area ๐ดdsc of all discs, without any corrections for chamfers and distance pieces, depends on the given surface area of the reference ๐ดref, and the surface area ratio of discs to cylinder, denoted ๐‘Ÿ๐‘Ž๐‘ก๐‘–๐‘œ. This results in: ๐ดdsc = ๐ดref ๐‘Ÿ๐‘Ž๐‘ก๐‘–๐‘œ ๐‘Ÿ๐‘Ž๐‘ก๐‘–๐‘œ + 1 โˆ’ ๐ดcorr,dsc,cal + ๐ดcorr,dsc,cha (1) and includes the correction for chamfers ๐ดcorr,dsc,cha, and the correction for distance pieces ๐ดcorr,dsc,cal. The surface of the cylindrical part is obtained as: ๐ดcyl = ๐ดref 1 ๐‘Ÿ๐‘Ž๐‘ก๐‘–๐‘œ + 1 โˆ’ ๐ดcorr,cyl,cal + ๐ดcorr,cyl,cha (2) including the reference surface ๐ดref , surface area ratio of discs to cylinder ๐‘Ÿ๐‘Ž๐‘ก๐‘–๐‘œ and the correction for distance pieces ๐ดcorr,cyl,cal as well as the correction for chamfers ๐ดcorr,cyl,cha. The height of a disc โ„Ždsc is calculated from: โ„Ždsc = ๐ดdsc ๐‘›dsc โˆ’ 2 ฯ€ โˆ™ ๐‘Ÿdsc 2 2 ฯ€ โˆ™ ๐‘Ÿdsc (3) with number of discs ๐‘›dsc and radius of the disc(s) ๐‘Ÿdsc. The height โ„Žcyl of a cylinder with radius ๐‘Ÿcyl can be calculated as: โ„Žcyl = ๐ดcyl โˆ’ 2 ฯ€ โˆ™ ๐‘Ÿcyl 2 2 ฯ€ โˆ™ ๐‘Ÿcyl (4) with the surface area of the cylinder ๐ดcyl calculated in equation (2). 3.2. Calculation of Masses of Cylinder and Discs The calculation of the total mass shall be composed of the calculation of the mass of the individual discs ๐‘€dsc and the mass of the cylinder ๐‘€cyl . The discs are designed on the basis of the previously determined heights and radii. The total mass of the cylinder ๐‘€cyl consisting of the silicon shell and the inlay core of tungsten is calculated, knowing the reference mass ๐‘€ref and the mass of all discs ๐‘€dsc, by means of: ๐‘€cyl = ๐‘€ref โˆ’ ๐‘€dsc (5) The further steps are simplified if only cylindrical geometries are used for calculations. In order to obtain these principles, the masses of the distance pieces and chamfers are extracted from the surrounding silicon cylinder. The pure cylinder mass ๐‘€cyl,pure is given by: ๐‘€cyl,pure = ๐‘€cyl โˆ’ ๐‘€corr,cal + ๐‘€corr,cha (6) http://www.imeko.org/ ACTA IMEKO | www.imeko.org December 2020 | Volume 9 | Number 5 | 44 As previously stated, the corrections for the distance pieces ๐‘€corr,cal and chamfers ๐‘€corr,cha will be shown in sections 4 and 5. Having the volume of the cylinder ๐‘‰cyl,Si,pure , the mass of the tungsten core ๐‘€cyl,W , can be described by: ๐‘€cyl,W = ๐‘€cyl,pureโˆ’ ๐œŒSiโˆ™๐‘‰cyl,Si,pure ๐œŒWโˆ’๐œŒSi โˆ™ ๐œŒW (7) including the corresponding densities of silicon ๐œŒSi and tungsten ๐œŒW. According to: ๐‘‰cyl,Si,pure = ๐‘‰cyl,Si โˆ’ ๐‘‰corr,cyl,cal + ๐‘‰corr,cyl,cha (8) the value of the reduced volume ๐‘‰cyl,Si,pure of the silicon cylinder considers the volumetric corrections influenced by both, the spherical distance pieces ๐‘‰corr,cyl,cal and the chamfer ๐‘‰corr,cyl,cha. For reasons of symmetry and to simplify the calculation elegantly, the geometric proportions of the enclosing silicon cylinder ๐‘Ÿcyl , โ„Žcyl and the internal tungsten core are assumed to be identical, so that: ๐‘Ÿcyl โ„Žcyl = ๐‘Ÿcyl,W โ„Žcyl,W (9) Both the radius ๐‘Ÿcyl,W of the inlay cylinder, given by: ๐‘Ÿcyl,W = โˆš ๐‘‰cyl,W ฯ€ ๐‘Ÿcyl โ„Žcyl 3 (10) and the height of the inlay cylinder โ„Žcyl,W, given by: โ„Žcyl,W = ๐‘Ÿcyl,W โˆ™ ๐‘Ÿcyl โ„Žcyl (11) are calculated from the fixed ratio of the geometry of the silicon cylinder for reasons of symmetry. The effective density of the inlay artefact ๐œŒily is calculated as: ๐œŒily = ๐‘€dsc + ๐‘€cyl,Si + ๐‘€cyl,W ๐‘‰dsc + ๐‘‰cyl (12) derived from the mass of the discs and the mass of the cylinder with the inlay tungsten artefact. 4. CORRECTION OF CHAMFER To correct the chamfers, volume, mass and surface area differences must be determined in comparison with the uncorrected discs and cylinder. The adjustment is classified by cylinder and chamfer. Figure 2 shows a section through a cylinder or disc with a circumferential chamfer. According to the mathematical description in section 2, the radii ๐‘Ÿdsc or ๐‘Ÿcyl must be substituted for the variable ๐‘Ÿ. The ring surface ๐ดrng, the lateral surface ๐ดshl of the uncorrected cylinder and the resulting chamfer surface ๐ดcha are shown under the chamfer angle ฮฑ. Figure 2: Schematic cross section through a cylindrical object with straight chamfers 4.1. Calculation of the Surface Areas for Chamfer The correction ๐ดcorr,cha depends on the surface of the cylinder shell surface area ๐ดshl , the ring surface area of the disc ๐ดrng and the surface area of the chamfer ๐ดcha. As a result: ๐ดcorr,cha = (๐ดrng + ๐ดshl โˆ’ ๐ดcha). (13) The surface area of an annular ring of the top face of a disc can be expressed as: ๐ดrng = ฯ€ (๐‘Ÿ 2 โˆ’ (๐‘Ÿ โˆ’ ๐‘Ž tan ๐›ผ ) 2 ) (14) The surface area of a disc of solid material without chamfer can be calculated from: ๐ดshl = 2 ฯ€ โˆ™ ๐‘Ÿ โˆ™ ๐‘Ž (15) For the surface correction of a chamfer the general approach for calculating rotational symmetric bodies [7]: ๐ดcha = 2 ฯ€ โˆซ ๐‘“(๐‘ง) โˆš1 + (๐‘“ โ€ฒ(๐‘ง)) 2 ๐‘‘๐‘ง ๐‘Ž 0 (16) is chosen. Herein the function ๐‘“(๐‘ง) describes the mathematical cross section of the rotatory body. ๐‘“(๐‘ง) = ๐‘Ÿ โˆ’ ๐‘ง โˆ™ tan ๐›ผ (17) Hence, the correction of the chamfer surface area results in: ๐ดcha = 2 ฯ€ โˆซ (๐‘Ÿ โˆ’ ๐‘ง โˆ™ tan ๐›ผ) โˆ™ โˆš1 + (tan ๐›ผ) 2 ๐‘‘๐‘ง ๐‘Ž 0 (18) After resolving the integral, the final correction for all chamfers is: ๐ดcorr,cha = ๐‘›dsc โˆ™ ๐‘›cha โˆ™ ( โˆ’2 ฯ€ โˆš1 + (tan ๐›ผ)2 โˆ™ (๐‘Ž โˆ™ ๐‘Ÿ โˆ’ ๐‘Ž2 2 ) + 2 ฯ€ โˆ™ ๐‘Ÿ โˆ™ ๐‘Ž + ฯ€ (๐‘Ÿ2 โˆ’ (๐‘Ÿ โˆ’ ๐‘Ž tan ๐›ผ ) 2 ) ) (19) http://www.imeko.org/ ACTA IMEKO | www.imeko.org December 2020 | Volume 9 | Number 5 | 45 4.2. Calculation of Volume and Mass of Chamfers The mathematical theory results from the approach to calculate a quarter torus. The general formula for the volume of a rotational symmetric object is [7]: ๐‘‰ = ฯ€ โˆซ (๐‘“(๐‘ง)) 2 ๐‘‘๐‘ง ๐‘Ž 0 (20) The resulting correction for volume of chamfers is described by the uncorrected cylinder volume ๐‘‰cyl subtracted by the chamfer volume correction ๐‘‰corr,cha which results in: ๐‘‰cha = ๐‘‰cyl โˆ’ ๐‘‰corr,cha (21) The detailed relation of this correction reads: ๐‘‰corr,cha = ฯ€ โˆซ ๐‘Ÿ2 ๐‘‘๐‘ง ๐‘Ž 0 โˆ’ ฯ€ โˆซ (๐‘Ÿ โˆ’ ๐‘ง โˆ™ tan ๐›ผ)2๐‘‘๐‘ง ๐‘Ž 0 (22) After solving the integrals, the final volume correction ๐‘‰corr,cha becomes: ๐‘‰corr,cha = ๐‘›cha โˆ™ (ฯ€ ๐‘Ÿ 2๐‘Ž โˆ’ ฯ€ (๐‘Ÿ 2 โˆ™ ๐‘Ž + ๐‘Ž3 3 โˆ™ (tan ๐›ผ)2 โˆ’ ๐‘Ÿ โˆ™ ๐‘Ž2 โˆ™ tan ๐›ผ)) (23) Assuming the known density ๐œŒSi and the determined correction ๐‘‰corr,cha, the adjustment for the mass of the chamfers is: ๐‘€corr,cha = ๐œŒSi โˆ™ ๐‘‰corr,cha (24) 5. CORRECTION OF DISTANCE PIECES The distance pieces enlarge the mass and surface area of the entire inlay artefact. Hence, corrective calculations are necessary. Distance pieces are placed on the top and bottom of the discs and the cylinder in relation to each other as shown in Figure 3. Distance pieces can be attached firmly to a disc in various methods, for example with a bond connection or high-vacuum compatible adhesive. Figure 3: Illustration of gap with spherical distance pieces (silicon spheres, ๐‘Ÿ = 2 mm, ๐›ฝ = 45ยฐ) In this context, only the upper half of the distance pieces must be considered for the correction of mass and surface area. Table 2 lists the relation between the number of distance pieces and the disc type or cylinder. Good mechanic design points out that a six-point mounting is the most stable stacking method for statically determined bearings. This avoids wiggling or instability of couplings. The selected stacking method requires exactly nine distance pieces per gap. This results in six distance pieces which are fixed on the top side of the cylinder. In addition, for any center disc, there are six distance pieces on the bottom side, and three further distance pieces on the top side. Finally, there are three distance pieces left for the top disc. Table 2: The total number of distance pieces per top disc, centre disc or cylinder and numbers for variable ๐‘›, where ๐‘› depends on the number of total discs Type of discs/cylinder Number of distance pieces (๐’Œ) Numbers for variable (๐’) top disc 3 2 center disc(s) 9 ๐‘›dsc cylinder 6 2 5.1. Calculation of the Surface Areas for Spherical Distance Pieces The surface area correction ๐ดcorr,cpl derives from the spherical surface area ๐ดcpl. However, the surface area of the cylinder ๐ดcir which is covered by the base of the hemisphere must be subtracted as: ๐ดcorr,cpl = ๐ดcpl โˆ’ ๐ดcir (25) Using the relevant parameters regarding the number of distance pieces ๐‘˜ the correction becomes: ๐ดcorr,cpl = ๐‘˜ 2 โˆ™ 4 ฯ€ โˆ™ ๐‘Ÿcpl 2 โˆ’ k โˆ™ ฯ€ โˆ™ ๐‘Ÿcpl 2 (26) 5.2. Calculation of Volume and Mass of Spherical Distance Pieces The volume correction through all distance pieces is made considering the number of discs ๐‘›. Polished silicon spheres with a radius of 2 mm serve as distance pieces. Depending on the type of disc or cylinder, different numbers of the spherical distance pieces ๐‘˜ must be inserted into the calculations. This results in the equation for the volume correction ๐‘‰corr,cpl according to: ๐‘‰corr,cpl = (๐‘› โˆ’ 1) โˆ™ ๐‘˜ 2 โˆ™ 4 3 ฯ€ โˆ™ ๐‘Ÿcpl 3 (27) Knowing the density ๐œŒSi and the calculated correction ๐‘‰corr,cpl leads to the adjustment for the mass of the distance pieces ๐‘€corr,cpl as: ๐‘€corr,cpl = ๐œŒSi โˆ™ ๐‘‰corr,cpl (28) http://www.imeko.org/ ACTA IMEKO | www.imeko.org December 2020 | Volume 9 | Number 5 | 46 6. RESULTS The parameters for height and radius of the discs and the cylinder are determined numerically by a minimizing fit algorithm (Newtonian method) provided by Mathematica [8]. The solution fulfilling all constraints can be achieved, if discs and the cylinder have an identical diameter and a minimum number of discs is used. This results in a volume difference of approximately 315 cmยณ between the new inlay artefact and a silicon buoyancy hollow cylinder with a volume of approximately 646 cmยณ [1]. To sum up, 1690 iteration runs were evaluated. Table 3 shows one solution for the fitted values for the designed inlay artefact, which fulfills all constraints. Table 3: Model parameters for an inlay artefact Input parameters Value Unit mass 1 kg ratio 2 - radius of disc(s) 0.034 m radius of cylinder 0.034 m chamfer angle 45 ยฐ chamfer length 0.000 5 m Fitted parameters Value Unit mass of tungsten inlay 0.261 42 kg mass of silicon 0.738 58 kg number of discs 2 - total height 0.096 689 8 m height of one disc 0.030 187 1 m height of cylinder 0.030 658 8 m height of tungsten core 0.015 204 4 m radius of tungsten core 0.016 861 4 m radial wall thickness Si cylinder 0.017 138 6 m axial wall thickness Si cylinder 0.007 727 2 m Results Value Unit volume 0.000 330 60 mยณ effective density of new inlay artefact 3024.78 kg/mยณ 7. SUMMARY The aim of this theoretical design study of a new inlay buoyancy artefact was to create a buoyancy artefact of nominal mass 1 kg with a small volume compared to other buoyancy artefacts. The small volume of the artefact, resulting in a particularly low air buoyancy was achieved by a combination of discs and a cylinder made of silicon, with a tungsten core inside. In contrast to conventional artefacts made of stainless steel, the newly designed artefact can be efficiently and gently cleaned the same way as the reference, like a silicon sphere. Special focus is given on the correction of chamfer and spherical distance pieces. A version of the inlay artefact is exemplarily calculated and illustrated. The theoretical design study for parameters, i.e. radius and height of the silicon parts and the tungsten core, were determined by numerous constraints using a variation method and could be a basis for future manufacturing. 8. REFERENCES [1] K. Lehrmann, R. Tutsch, F. Hรคrtig, โ€œDesign of sorption and buoyancy artefacts made of siliconโ€, IMEKO, Cavtat-Dubrovnik, 2020, not yet published. [2] D. Knopf, Th. Wiedenhรถfer, K. Lehrmann, F. Hรคrtig, โ€œA quantum of action on a scale? Dissemination of the quantum based kilogramโ€, Metrologia 56 024003, 2019. [3] M. Kochsiek, M. Glรคser (eds.), โ€œComprehensive Mass Metrologyโ€, ISBN 3-527-29614-X, p. 255, VCH, Berlin, 2000. [4] DIN 12242-1, Laboratory glassware; interchangeable conical ground joints, dimensions, tolerances, 1980. [5] PTB internal density determination by hydrostatic weighing at 20 ยฐC, May 2020. [6] N. Greenwood, A. Earnshaw, Chemie der Elemente, Edition 1, VCH, Weinheim, ISBN 3- 527-26169-9, S. 1291, 1988. [7] T. Ahrens et al., Mathematik, Ch. 11 Heidelberg, ISBN 978-3-8274-1758-9, 2008. [8] www.wolfram.com/mathematica/ (2020-05-08). http://www.imeko.org/ http://www.wolfram.com/mathematica/