AP1_01.vp 1 Introduction Nitrogen is a nutrient essential to all forms of life as a basic building block of plant and animal protein. Nevertheless, too much of it can be toxic. The presence of nitrogen excess in the environment has caused serious distortions of the natural nutrient cycle between the living world and the soil, water, and atmosphere. Nitrogen in the form of nitrous oxide, nitric oxide, nitrate, nitrite or ammonia/ammonium is soluble in water and can end up in ground water and drinking water. One of the best-documented and best-understood conse- quences of human alterations of the nitrogen cycles is the eutrophication of estuaries and coastal seas (Oenema and Roest, 1998). According to the instruction of the European Community Council (CCE) of 15 July 1980, the maxi- mum permissible level of ammonium in drinking water is 0.5 mg l�1. The processes used for the removal of ammonium ions from drinking waters include air stripping, nitrification, breakpoint chlorination, and ion exchange. The properties of synthetic and natural zeolites as ion exchangers for re- moval of ammonium ions have been discussed in great de- tail (Jörgensen, 1976; Gaspard and Martin, 1983; Hlavay et al., 1983; Vokáčová, et al., 1986; Hódi et al., 1995; Booker et al., 1996; Beler Baykal and Akca Guven, 1997; Cooney et al., 1999). The behavior of the exchange and the quantities of ammonium removed are very much dependent on the origin of the material, the impurities contained, the counter ions, as well as the pretreatment performed on the zeolite. The objective of our work is to treat drinking water spiked with NH4 + (10 � 0.5, 5 � 0.5, and 2 � 0.5) mg l�1 with the use of clinoptilolite and under pretreatments of the mineral. 2 Zeolites in drinking water treatment Zeolites are natural minerals, which can be described chemically as aluminum silicates. They are used for various applications, e.g., ion exchange, molecular sieves, and air- -drying. The simplified chemical composition and structure of zeolites can be seen in Fig. 1. In the regular structure of silicates a few places are occu- pied by aluminum ions, and so an additional charge is caused. This charge is compensated by other ions like sodium, potas- sium or ammonia, which are reversibly fixed by interactions and can easily be exchanged by other ions. The composition of this structure leads to various forms of zeolites. Of all these zeolite types, clinoptilolite has the best selectivity for ammonia. Preparing clinoptilolite so that all exchange places are filled with sodium ions results in a form with the best selectivity for ammonia (Jörgensen et al. 1979; Oldenburg M. and Sekoulov I., 1995). 3 Materials and methods Physical description of the system Fig. 2 consists of a column set with the following characteristics: Internal diameter = 20 mm, total height of column = 60 cm, height of the bed of zeolite = 33 cm, 100 ml of material at a volumetric flow rate of 8.7 ml min�1, which is equivalent to 5.25 bed volumes (BV) per hour, particle-size of mate- rial = 3–5 mm, mass of zeolite in column = 100 g. A nylon screen supported the zeolite in the column. © Czech Technical University Publishing House http://ctn.cvut.cz/ap/ 41 Acta Polytechnica Vol. 41 No.1/2001 Clinoptilolite in Drinking Water Treatment for Ammonia Removal H. M. Abd El-Hady, A. Grünwald, K. Vlčková, J. Zeithammerová In most countries today the removal of ammonium ions from drinking water has become almost a necessity. The natural zeolite clinoptilolite is mined commercially in many parts of the world. It is a selective exchanger for the ammonium cation, and this has prompted its use in water treatment, wastewater treatment, swimming pools and fish farming. The work described in this paper provides dynamic data on cation exchange processes in clinoptilolite involving the NH4 +, Ca+2 and Mg+2 cations. We used material of natural origin – clinoptilolite from Nižný Hrabovec in Slovakia (particle-size 3–5 mm). The breakthrough capacity was determined by dynamic laboratory investigations, and we investigated the influence of thermal pretreatment of clinoptilolite and the concentration of regenerant solution (2, 5, and 10% NaCl). The concentrations of ammonium ion inputs in the tap water that we used were 10, 5, and 2 mg NH4 + l �1 and down to levels below 0.5 mg NH4 + l�1. The experimental results show that repeated pretreatment sufficiently improves the zeolite’s properties, and the structure of clinoptilolite remains unchanged during the loading and regeneration cycles. Ammonium removal capacities were increased by approximately 40 % and 20 % for heat-treated zeolite samples. There was no difference between the regenerates for 10% and 5% NaCl. We conclude that the use of zeolite is an attractive and promising method for ammonium removal. Keywords: clinoptilolite, zeolite, ion exchange, ammonia removal, drinking water. Me +n Al SiSi Me n+ xAlnx Siy O2(nx+y) Y/X > 1 Me n+ ^ K + , Ca 2+ , Na + , Mg 2+ , Fe 3+ , NH4 + Fig. 1: Simplified chemical composition and structure of zeolites Acta Polytechnica Vol. 41 No.1/2001 Analysis All analyses were made according to standard methods (APHA, see Greenberg et al., 1992). Ammonia was de- termined by Nessler methods using a spectrophotometer (Model Hach DR/2000). Calcium and magnesium were deter- mined by the EDTA titrimetric method. Specification of the material Two materials were used for the investigation: a) Natural clinoptilolite (clino. 1). Origin: Nižný Hrabovec, Slovakia. The chemical composition is given as: SiO2 Al2O3 Fe2O3 FeO TiO2 CaO MgO 69.77 % 12.24 % 2.2 % 0.14 % 0.45 % 1.68 % 1 % Na2O K2O MnO P2O5 H2O Total 2.7 % 2.11 % 0.034 % 0.08 % 7.3 % 99.704 % b) Activated clinoptilolite. The activation process was per- formed by heating for two samples: the samples were exposed to an elevated temperature of 400 °C for 6 h. Before being heated, the first sample (clino. 2) (previously used as natural clinoptilolite) was washed with distilled water, while the second sample (clino. 3) was heated in its natural form. System operation parameters The first experiment was carried out to see the exhaustion performance of (clino. 1) using distilled water spiked at 10 mg NH4 � l �1 concentration. Then we applied tap water contain- ing Ca�2 = 60 mg l �1 and Mg�2 = 12 mg l �1. The concentra- tions of ammonium input were 10, 5 and 2 mg NH4 + l �1 as (NH4Cl) and down to levels below 0.5 mg l �1. Clino. 2 and clino. 3 were applied only with tap water containing Ca�2, Mg�2 and NH4 +. In the regeneration phase, 2.0% NaCl at pH range (11.5–12.5), at a volumetric flow rate of 8.7 ml min�1, which is equivalent to 5.25 bed volumes (BV) per hour was investi- gated for clino. 1 in the first experiment and then at 5%, 10% NaCl for clino. 1. For clino. 2 and clino. 3, NaCl only was spiked at 5 %. After regeneration, the excess Cl � was removed from the clinoptilolite, with the use of distilled water. This washing was repeated until visual tests with AgNO3 revealed zero chloride. 4 Results and discussion Breakthrough capacity and effects of activated clinoptilolite Within the scope of this work, the results from the first ex- periment using distilled water for clino. 1 indicated that the breakthrough capacity defined as 0.5 mg l �1 in NH4 � was 0.47 mol l �1 for NH4 � = 10 mg l �1 as shown in Table 1. Figs. 3, 4 and 5 and Table 2 show that, for tap water containing calcium and magnesium ions, the breakthrough capacity were 0.038, 0.052, 0.058 mol l �1 for NH4 � = 10, 5, and 2 mg l �1. For clino. 2 the values were 0.048, 0.063, 0.068 mol l �1 for NH4 � = 10, 5, and 2 mg l �1, and for clino. 3 the values were 0.06, 0.063, 0.076 mol l �1, respectively. These values indicate that tap water provides a lower breakthrough capacity than distilled water, due to the presence of other ions, especially ions with a polyvalent charge in water, such as Ca�2 and Mg�2. 42 © Czech Technical University Publishing House http://ctn.cvut.cz/ap/ Reservoir Regeneration Peristaltic pump Valve Service Ion exchange Resin column Fig. 2: Laboratory column Zeolite column - NH 4 Cl Feed Breakthrough Curve 0 0.1 0.2 0.3 0.4 0.5 0.6 0 20 40 60 80 100 120 Bed Volume Passed N H 4 + m g l- 1 Clino. 1 Clino. 2 Clino. 3 breakthrough level Fig. 3: Breakthrough curves of ion exchange resin for a tap water con- taining (NH4 + = 10 mg/ l, Ca2+ = 60 mg/l, Mg2+ = 12 mg/ l) Zeolite column - NH 4 Cl Feed Breakthrough Curve 0 0.1 0.2 0.3 0.4 0.5 0.6 100 120 140 160 180 200 220 240 260 280 300 Bed Volume Passed N H 4 + m g l- 1 Clino. 1 Clino. 2 Clino. 3 breakthrough level Fig. 4: Breakthrough curves of ion exchange resin for a tap water con- taining (NH4 + = 5 mg/ l, Ca2+ = 60 mg/l, Mg2+ = 12 mg/ l) These results reveal that thermal activation increases clinoptilolite selectivity for ammonium ions. The results shown in Fig. 6 indicate that the breakthrough capacities of a thermally activated sample are on average roughly 20 %, 40 % for clino. 2 and clino. 3, respectively, higher than the value for untreated clinoptilolite. In addition, these results in- dicate that ammonium ions can be removed efficiency by the zeolite, and the exchange capacity of zeolites depends on the initial ammonia concentration at the column inlet. Table 1: Important parameters measured during the experiment using distilled water spiked with NH4 � inf. = 10 mg l�1 for clino. 1 Solution volume – L 50 61 72 82 88.5 NH4 � eff. – mg l�1 0.06 0.088 0.094 0.29 0.503 BV 500 610 720 820 885 Table 2: Important parameters measured during the experiment using tap water spiked with ammonia Materials Clino. 1 Clino. 2 Clino. 3 NH4 � inf [mg l �1 ] 10 5 2 10 5 2 10 5 2 Volume L 7.25 21 70 9 25 81 11.25 28 91 BV 72.5 210 700 90 250 810 112.5 280 910 Capacity [mol l �1 ] 0.038 0.052 0.058 0.048 0.063 0.068 0.06 0.063 0.076 Comparing the results summarized in Figs. 7, 8, it can be seen that the removal of calcium and magnesium at break- through level of ammonia for clino. 2 and clino. 3 was lower than for clino. 1 at all concentrations of ammonia, which agrees with the selectivity rules for ionic exchange in un- treated clinoptilolite zeolite. These results reveal that the removal efficiency of calcium and magnesium for clino. 1 was higher than for clino. 2 and clino. 3. Regeneration effects The result from the first regeneration using 2% NaCl indicate that 140 BV of a NaCl solution is sufficient for ammo- nium elution from clino. 1. The elution curves (Figs. 9, 10 and Table 3) indicate that no difference between regeneration by 10% and 5% NaCl solution for clino. 1. 65 BV of a NaCl solu- tion is sufficient for ammonium elution. On the other hand, complete elution of ammonia from clino. 2 and clino. 3 © Czech Technical University Publishing House http://ctn.cvut.cz/ap/ 43 Acta Polytechnica Vol. 41 No.1/2001 Zeolite column - NH 4 Cl Feed Breakthrough Curve 0 0.1 0.2 0.3 0.4 0.5 0.6 500 540 580 620 660 700 740 780 820 860 900 940 Bed Volume Passed N H 4 + m g l- 1 Clino. 1 Clino. 2 Clino. 3 breakthrough level Fig. 5: Breakthrough curves of ion exchange resin for a tap water containing (NH4 � = 2 mg/ l, Ca2� = 60 mg/ l, Mg2� = 12 mg/ l) Useful capacity of exchange 0 0.02 0.04 0.06 0.08 0.1 0 1 2 3 4 5 6 7 8 9 10 11 12 NH 4 + = mg/l m o l l- 1 clino .1 clino .2 clino .3 Fig. 6: Exchange capacity 0 15 30 45 60 10 5 2 NH4 + - mg l -1 m g l-1 Clino. 1 Clino. 2 Clino. 3 Fig. 7: Comparison of calcium breakthrough of ion exchange resin for a tap water containing (NH4 +, Ca2+= 60 mg/ l, Mg2+= 12 mg/ l) 0 3 6 9 12 15 10 5 2 NH4 + - mg l-1 m g l- 1 Clino. 1 Clino. 2 Clino. 3 Fig. 8: Comparison of magnesium breakthrough of ion exchange resin for a tap water containing (NH4 +, Ca2+= 60 mg/l, Mg2+= 12 mg/l) 44 © Czech Technical University Publishing House http://ctn.cvut.cz/ap/ Acta Polytechnica Vol. 41 No.1/2001 require 110 BV of using 5% NaCl solution. These results reveal that clino. 1 is slightly more economical than clino. 2, and clino. 3 and 5% NaCl should be used. 5 Conclusions The experimental results indicate that ammonium ions can be removed efficiency by zeolites. Pretreatment of the zeolite considerably improves its ion exchange capacity, and clino. 3 can be used for ammonia removal as a more economi- cal exchanger than clino. 1 and clino. 2. Ammonium removal capacities were increased by approximately 40 % and 20 % for heat-treated zeolite samples. There was no difference be- tween the regenerates for 10% and 5% NaCl. The removal efficiency of calcium and magnesium for clino. 1 was higher than for clino. 2 and clino. 3. We conclude that the use of zeolite is an attractive and promising method for ammonium removal. References [1] APHA: Standard methods for examination of water and waste water. 18th Edition, 1992, Published by American Public Health Association, Washington, USA [2] Beler Baykal, B. and Akca Guven, D.: Performance of clin- optilolite alone and in combination with sand filters for the removal of ammonia peaks from domestic wastewater. Wat. Sci. Technol., 1997, Vol. 35, No. 7, pp. 47–54 [3] Booker, N., Cooney, E. and Priestly, A.: Ammonia Removal from Sewage Using Natural Australian Zeolite. Wat. Sci. Technol., 1996, Vol. 34, No. 9, pp. 17–24 Clino. 1 NaCl 2% NaCl 5% NaCl 10% Volume (ml) NH4 + (mg l �1) BV Volume (ml) NH4 + (mg l �1) BV Volume (ml) NH4 + (mg l �1) BV 1000 24.1 10 1000 27.6 10 1000 659 10 5000 2.65 50 5000 1.08 50 6000 25 60 6000 0.098 60 6000 0.098 60 1000 0.98 100 6500 0.036 65 6500 0.04 65 14000 0.028 140 NaCl 5% Clino. 2 Clino. 3 Volume (ml) NH4 + (mg l �1) BV Volume (ml) NH4 + (mg l �1) BV 1000 40.39 10 1000 23.77 10 6000 3.01 60 6000 2.66 60 10000 0.255 100 10000 0.266 100 11000 0.05 110 11000 0.04 110 Table 3: Elution of ammonia from the resins using NaCl NaCl = 5% 0 10 20 30 40 50 60 70 80 90 100 0 20 40 60 80 Bed Volume Paseed N H 4 + m g l-1 Clino.1 Clino. 2 Clino. 3 Fig. 9: Typical regeneration curves for elution of ammonia from reins using NaCl = 5% NaCl = 10% 0 25 50 75 100 125 0 20 40 60 80 Bed Volume Passed N H 4 + m g l-1 Clino.1 Fig. 10: Typical regeneration curves for elution of ammonia from reins using NaCl = 10% © Czech Technical University Publishing House http://ctn.cvut.cz/ap/ 45 Acta Polytechnica Vol. 41 No.1/2001 [4] Cooney, E., Booker, N., Shallcross, D. and Stevens, G.: Am- monia Removal from Wastewater Using Natural Australian Zeolite. I. Characterization of the Zeolite. Sep. Sci. Technol., 1999, Vol. 34, No. 12, pp. 2307–2327 [5] Gaspard, M. and Martin, A.: Clinoptilolite in Drinking Water treatment for NH4 + Removal. Wat. Res., 1983, Vol. 17, No. 3, pp. 279–288 [6] Hlavay, J., Vigh, Gy., Olaszi, V. and Inczédy, J.: Ammonia and iron removal from drinking water with clinoptilolite tuff. Zeolite 3, 1983, pp. 188–190 [7] Hódi, M., Polyák, K. and Hlavay, J.: Removal of pollutants from drinking water by combined ion exchange and adsorption methods. Envir. International, 1995, Vol. 21, No. 3, pp. 325–331 [8] Jörgensen, S. E., Libor, O., Barkacs, K. and Kuna, L.: Equilibrium and capacity data of clinoptilolite. Wat. Res., 1979, Vol. 13, pp. 159–165 [9] Jörgensen, S. E.: Ammonia removal by use of clinoptilolite. Wat. Res., 1976, Vol. 10, pp. 213–224 [10] Oenema, O. and Roest, C. W. J.: Nitrogen and phosphorus losses from agriculture into surface waters: the effects of policies and measures in the Netherlands. Wat. Sci. Technol., 1998, Vol. 37, No. 2, pp. 19–26 [11] Vokáčová, M., Matejka, Z. and Ellášek, J.: Sorption of Ammonium-Ion by Clinoptilolite and by Strongly Acidic Cation Exchangers. Acta Hydrochim, 1986, Vol. 14, No. 6, pp. 605–611 Hossam Monier Abd El-Hady phone: +420 2 2435 4605 e-mail: hoss@fsv.cvut.cz Prof. Ing. Alexander Grünwald, CSc. phone: +420 2 2435 4638 e-mail: grunwald@fsv.cvut.cz Ing. Karla Vlčková Ing. Jitka Zeithammerová Department of Sanitary Engineering Czech Technical University in Prague Faculty of Civil Engineering Thákurova 7, 166 29 Praha 6, Czech Republic