id	sid	tid	token	lemma	pos
afs-72028	1	1	journal	journal	NOUN
afs-72028	1	2	of	of	ADP
afs-72028	1	3	the	the	DET
afs-72028	1	4	scientific	scientific	ADJ
afs-72028	1	5	agricultural	agricultural	ADJ
afs-72028	1	6	society	society	NOUN
afs-72028	1	7	of	of	ADP
afs-72028	1	8	finland	finland	PROPN
afs-72028	1	9	maataloustieteellinen	maataloustieteellinen	PROPN
afs-72028	1	10	aikakauskirja	aikakauskirja	PROPN
afs-72028	1	11	34	34	NUM
afs-72028	1	12	vol	vol	NOUN
afs-72028	1	13	.	.	PUNCT
afs-72028	2	1	52:3444	52:3444	NUM
afs-72028	2	2	,	,	PUNCT
afs-72028	2	3	1980	1980	NUM
afs-72028	2	4	oxygen	oxygen	NOUN
afs-72028	2	5	as	as	ADP
afs-72028	2	6	an	an	DET
afs-72028	2	7	exchangeable	exchangeable	ADJ
afs-72028	2	8	ligand	ligand	NOUN
afs-72028	2	9	in	in	ADP
afs-72028	2	10	soil	soil	NOUN
afs-72028	2	11	erkki	erkki	ADJ
afs-72028	2	12	aura	aura	NOUN
afs-72028	2	13	1	1	NUM
afs-72028	2	14	)	)	PUNCT
afs-72028	2	15	department	department	NOUN
afs-72028	2	16	of	of	ADP
afs-72028	2	17	agricultural	agricultural	ADJ
afs-72028	2	18	chemistry	chemistry	NOUN
afs-72028	2	19	,	,	PUNCT
afs-72028	2	20	university	university	NOUN
afs-72028	2	21	of	of	ADP
afs-72028	2	22	helsinki	helsinki	PROPN
afs-72028	2	23	00710	00710	PROPN
afs-72028	3	1	helsinki	helsinki	PROPN
afs-72028	3	2	71	71	NUM
afs-72028	3	3	abstract	abstract	NOUN
afs-72028	3	4	.	.	PUNCT
afs-72028	4	1	an	an	DET
afs-72028	4	2	attempt	attempt	NOUN
afs-72028	4	3	was	be	AUX
afs-72028	4	4	made	make	VERB
afs-72028	4	5	to	to	PART
afs-72028	4	6	clarify	clarify	VERB
afs-72028	4	7	the	the	DET
afs-72028	4	8	adsorption	adsorption	NOUN
afs-72028	4	9	of	of	ADP
afs-72028	4	10	oxygen	oxygen	NOUN
afs-72028	4	11	ligands	ligand	NOUN
afs-72028	4	12	onto	onto	ADP
afs-72028	4	13	the	the	DET
afs-72028	4	14	aland	aland	PROPN
afs-72028	4	15	fe	fe	PROPN
afs-72028	4	16	-	-	PUNCT
afs-72028	4	17	oxides	oxide	NOUN
afs-72028	4	18	in	in	ADP
afs-72028	4	19	the	the	DET
afs-72028	4	20	soil	soil	NOUN
afs-72028	4	21	.	.	PUNCT
afs-72028	5	1	in	in	ADP
afs-72028	5	2	the	the	DET
afs-72028	5	3	ligand	ligand	NOUN
afs-72028	5	4	exchange	exchange	NOUN
afs-72028	5	5	the	the	DET
afs-72028	5	6	central	central	ADJ
afs-72028	5	7	ions	ion	NOUN
afs-72028	5	8	al	al	PROPN
afs-72028	5	9	3	3	NUM
afs-72028	5	10	+	+	NUM
afs-72028	5	11	and	and	CCONJ
afs-72028	5	12	fe3	fe3	PROPN
afs-72028	5	13	+	+	NUM
afs-72028	5	14	of	of	ADP
afs-72028	5	15	the	the	DET
afs-72028	5	16	oxides	oxide	NOUN
afs-72028	5	17	are	be	AUX
afs-72028	5	18	lewis	lewis	PROPN
afs-72028	5	19	acids	acid	NOUN
afs-72028	5	20	or	or	CCONJ
afs-72028	5	21	electron	electron	NOUN
afs-72028	5	22	acceptors	acceptor	NOUN
afs-72028	5	23	and	and	CCONJ
afs-72028	5	24	the	the	DET
afs-72028	5	25	ligands	ligand	NOUN
afs-72028	5	26	are	be	AUX
afs-72028	5	27	lewis	lewis	NOUN
afs-72028	5	28	bases	basis	NOUN
afs-72028	5	29	or	or	CCONJ
afs-72028	5	30	electron	electron	NOUN
afs-72028	5	31	donors	donor	NOUN
afs-72028	5	32	.	.	PUNCT
afs-72028	6	1	the	the	DET
afs-72028	6	2	binding	binding	NOUN
afs-72028	6	3	of	of	ADP
afs-72028	6	4	ligand	ligand	ADJ
afs-72028	6	5	oxygen	oxygen	NOUN
afs-72028	6	6	by	by	ADP
afs-72028	6	7	the	the	DET
afs-72028	6	8	central	central	ADJ
afs-72028	6	9	ion	ion	NOUN
afs-72028	6	10	is	be	AUX
afs-72028	6	11	primarily	primarily	ADV
afs-72028	6	12	dependent	dependent	ADJ
afs-72028	6	13	on	on	ADP
afs-72028	6	14	the	the	DET
afs-72028	6	15	nucleophilic	nucleophilic	ADJ
afs-72028	6	16	strength	strength	NOUN
afs-72028	6	17	of	of	ADP
afs-72028	6	18	the	the	DET
afs-72028	6	19	ligand	ligand	ADJ
afs-72028	6	20	oxygen	oxygen	NOUN
afs-72028	6	21	.	.	PUNCT
afs-72028	7	1	the	the	DET
afs-72028	7	2	proton	proton	NOUN
afs-72028	7	3	is	be	AUX
afs-72028	7	4	a	a	DET
afs-72028	7	5	hard	hard	ADJ
afs-72028	7	6	lewis	lewis	NOUN
afs-72028	7	7	acid	acid	PROPN
afs-72028	7	8	as	as	SCONJ
afs-72028	7	9	are	be	AUX
afs-72028	7	10	al3	al3	NOUN
afs-72028	7	11	+	+	CCONJ
afs-72028	7	12	and	and	CCONJ
afs-72028	7	13	fe3	fe3	PROPN
afs-72028	7	14	+	+	PROPN
afs-72028	7	15	.	.	PUNCT
afs-72028	8	1	the	the	DET
afs-72028	8	2	pka	pka	NOUN
afs-72028	8	3	-	-	PUNCT
afs-72028	8	4	value	value	NOUN
afs-72028	8	5	of	of	ADP
afs-72028	8	6	the	the	DET
afs-72028	8	7	acid	acid	NOUN
afs-72028	8	8	corresponding	corresponding	NOUN
afs-72028	8	9	to	to	ADP
afs-72028	8	10	the	the	DET
afs-72028	8	11	anion	anion	NOUN
afs-72028	8	12	shows	show	VERB
afs-72028	8	13	the	the	DET
afs-72028	8	14	ability	ability	NOUN
afs-72028	8	15	of	of	ADP
afs-72028	8	16	ligand	ligand	ADJ
afs-72028	8	17	oxygen	oxygen	NOUN
afs-72028	8	18	to	to	PART
afs-72028	8	19	bind	bind	VERB
afs-72028	8	20	a	a	DET
afs-72028	8	21	proton	proton	NOUN
afs-72028	8	22	and	and	CCONJ
afs-72028	8	23	also	also	ADV
afs-72028	8	24	the	the	DET
afs-72028	8	25	ability	ability	NOUN
afs-72028	8	26	to	to	PART
afs-72028	8	27	bind	bind	VERB
afs-72028	8	28	al3	al3	NOUN
afs-72028	8	29	+	+	CCONJ
afs-72028	8	30	and	and	CCONJ
afs-72028	8	31	fe3	fe3	PROPN
afs-72028	8	32	+	+	NOUN
afs-72028	8	33	.	.	PUNCT
afs-72028	9	1	the	the	PRON
afs-72028	9	2	greater	great	ADJ
afs-72028	9	3	the	the	DET
afs-72028	9	4	nucleophilic	nucleophilic	ADJ
afs-72028	9	5	strength	strength	NOUN
afs-72028	9	6	of	of	ADP
afs-72028	9	7	the	the	DET
afs-72028	9	8	ligand	ligand	NOUN
afs-72028	9	9	,	,	PUNCT
afs-72028	9	10	the	the	DET
afs-72028	9	11	more	more	ADV
afs-72028	9	12	covalent	covalent	NOUN
afs-72028	9	13	the	the	DET
afs-72028	9	14	nature	nature	NOUN
afs-72028	9	15	of	of	ADP
afs-72028	9	16	the	the	DET
afs-72028	9	17	bond	bond	NOUN
afs-72028	9	18	between	between	ADP
afs-72028	9	19	ligand	ligand	ADJ
afs-72028	9	20	oxygen	oxygen	NOUN
afs-72028	9	21	and	and	CCONJ
afs-72028	9	22	the	the	DET
afs-72028	9	23	central	central	ADJ
afs-72028	9	24	ion	ion	NOUN
afs-72028	9	25	.	.	PUNCT
afs-72028	10	1	however	however	ADV
afs-72028	10	2	,	,	PUNCT
afs-72028	10	3	the	the	DET
afs-72028	10	4	covalent	covalent	ADJ
afs-72028	10	5	character	character	NOUN
afs-72028	10	6	of	of	ADP
afs-72028	10	7	this	this	DET
afs-72028	10	8	bond	bond	NOUN
afs-72028	10	9	does	do	AUX
afs-72028	10	10	not	not	PART
afs-72028	10	11	make	make	VERB
afs-72028	10	12	the	the	DET
afs-72028	10	13	adsorption	adsorption	NOUN
afs-72028	10	14	of	of	ADP
afs-72028	10	15	a	a	DET
afs-72028	10	16	ligand	ligand	NOUN
afs-72028	10	17	by	by	ADP
afs-72028	10	18	oxides	oxide	NOUN
afs-72028	10	19	an	an	DET
afs-72028	10	20	exothermic	exothermic	ADJ
afs-72028	10	21	reaction	reaction	NOUN
afs-72028	10	22	.	.	PUNCT
afs-72028	11	1	the	the	DET
afs-72028	11	2	entropy	entropy	NOUN
afs-72028	11	3	changes	change	VERB
afs-72028	11	4	in	in	ADP
afs-72028	11	5	adsorption	adsorption	NOUN
afs-72028	11	6	determine	determine	VERB
afs-72028	11	7	the	the	DET
afs-72028	11	8	exchange	exchange	NOUN
afs-72028	11	9	equilibrium	equilibrium	NOUN
afs-72028	11	10	of	of	ADP
afs-72028	11	11	the	the	DET
afs-72028	11	12	anions	anion	NOUN
afs-72028	11	13	.	.	PUNCT
afs-72028	12	1	the	the	DET
afs-72028	12	2	nucleophilic	nucleophilic	ADJ
afs-72028	12	3	strength	strength	NOUN
afs-72028	12	4	of	of	ADP
afs-72028	12	5	ligand	ligand	ADJ
afs-72028	12	6	oxygen	oxygen	NOUN
afs-72028	12	7	also	also	ADV
afs-72028	12	8	determines	determine	VERB
afs-72028	12	9	the	the	DET
afs-72028	12	10	rate	rate	NOUN
afs-72028	12	11	of	of	ADP
afs-72028	12	12	exchange	exchange	NOUN
afs-72028	12	13	.	.	PUNCT
afs-72028	13	1	if	if	SCONJ
afs-72028	13	2	an	an	DET
afs-72028	13	3	anion	anion	NOUN
afs-72028	13	4	has	have	VERB
afs-72028	13	5	a	a	DET
afs-72028	13	6	high	high	ADJ
afs-72028	13	7	nucleophilic	nucleophilic	ADJ
afs-72028	13	8	strength	strength	NOUN
afs-72028	13	9	,	,	PUNCT
afs-72028	13	10	it	it	PRON
afs-72028	13	11	is	be	AUX
afs-72028	13	12	rapidly	rapidly	ADV
afs-72028	13	13	adsorbed	adsorb	VERB
afs-72028	13	14	by	by	ADP
afs-72028	13	15	oxides	oxide	NOUN
afs-72028	13	16	but	but	CCONJ
afs-72028	13	17	the	the	DET
afs-72028	13	18	desorption	desorption	NOUN
afs-72028	13	19	is	be	AUX
afs-72028	13	20	slow	slow	ADJ
afs-72028	13	21	.	.	PUNCT
afs-72028	14	1	the	the	DET
afs-72028	14	2	theory	theory	NOUN
afs-72028	14	3	explains	explain	VERB
afs-72028	14	4	the	the	DET
afs-72028	14	5	relationship	relationship	NOUN
afs-72028	14	6	between	between	ADP
afs-72028	14	7	the	the	DET
afs-72028	14	8	adsorption	adsorption	NOUN
afs-72028	14	9	of	of	ADP
afs-72028	14	10	anions	anion	NOUN
afs-72028	14	11	to	to	ADP
afs-72028	14	12	oxides	oxide	NOUN
afs-72028	14	13	and	and	CCONJ
afs-72028	14	14	the	the	DET
afs-72028	14	15	ph	ph	NOUN
afs-72028	14	16	-	-	PUNCT
afs-72028	14	17	value	value	NOUN
afs-72028	14	18	in	in	ADP
afs-72028	14	19	the	the	DET
afs-72028	14	20	equilibrum	equilibrum	NOUN
afs-72028	14	21	solution	solution	NOUN
afs-72028	14	22	.	.	PUNCT
afs-72028	15	1	the	the	DET
afs-72028	15	2	theory	theory	NOUN
afs-72028	15	3	also	also	ADV
afs-72028	15	4	illuminates	illuminate	VERB
afs-72028	15	5	the	the	DET
afs-72028	15	6	factors	factor	NOUN
afs-72028	15	7	,	,	PUNCT
afs-72028	15	8	which	which	PRON
afs-72028	15	9	determine	determine	VERB
afs-72028	15	10	the	the	DET
afs-72028	15	11	leaching	leaching	NOUN
afs-72028	15	12	of	of	ADP
afs-72028	15	13	an	an	DET
afs-72028	15	14	anion	anion	NOUN
afs-72028	15	15	from	from	ADP
afs-72028	15	16	the	the	DET
afs-72028	15	17	soil	soil	NOUN
afs-72028	15	18	and	and	CCONJ
afs-72028	15	19	the	the	DET
afs-72028	15	20	uptake	uptake	ADJ
afs-72028	15	21	rate	rate	NOUN
afs-72028	15	22	of	of	ADP
afs-72028	15	23	an	an	DET
afs-72028	15	24	anion	anion	NOUN
afs-72028	15	25	from	from	ADP
afs-72028	15	26	the	the	DET
afs-72028	15	27	soil	soil	NOUN
afs-72028	15	28	by	by	ADP
afs-72028	15	29	plants	plant	NOUN
afs-72028	15	30	.	.	PUNCT
afs-72028	16	1	introduction	introduction	NOUN
afs-72028	16	2	the	the	DET
afs-72028	16	3	oxygen	oxygen	NOUN
afs-72028	16	4	is	be	AUX
afs-72028	16	5	the	the	DET
afs-72028	16	6	most	most	ADV
afs-72028	16	7	abundant	abundant	ADJ
afs-72028	16	8	chemical	chemical	NOUN
afs-72028	16	9	element	element	NOUN
afs-72028	16	10	in	in	ADP
afs-72028	16	11	the	the	DET
afs-72028	16	12	soil	soil	NOUN
afs-72028	16	13	.	.	PUNCT
afs-72028	17	1	this	this	PRON
afs-72028	17	2	is	be	AUX
afs-72028	17	3	due	due	ADJ
afs-72028	17	4	to	to	ADP
afs-72028	17	5	the	the	DET
afs-72028	17	6	fact	fact	NOUN
afs-72028	17	7	that	that	SCONJ
afs-72028	17	8	the	the	DET
afs-72028	17	9	earth	earth	NOUN
afs-72028	17	10	’s	’s	PART
afs-72028	17	11	crust	crust	NOUN
afs-72028	17	12	contains	contain	VERB
afs-72028	17	13	46.6	46.6	NUM
afs-72028	17	14	%	%	NOUN
afs-72028	17	15	oxygen	oxygen	NOUN
afs-72028	17	16	by	by	ADP
afs-72028	17	17	weight	weight	NOUN
afs-72028	17	18	(	(	PUNCT
afs-72028	17	19	weast	weast	NOUN
afs-72028	17	20	1969	1969	NUM
afs-72028	17	21	)	)	PUNCT
afs-72028	17	22	.	.	PUNCT
afs-72028	18	1	the	the	DET
afs-72028	18	2	oxygen	oxygen	NOUN
afs-72028	18	3	plays	play	VERB
afs-72028	18	4	an	an	DET
afs-72028	18	5	important	important	ADJ
afs-72028	18	6	role	role	NOUN
afs-72028	18	7	in	in	ADP
afs-72028	18	8	the	the	DET
afs-72028	18	9	most	most	ADV
afs-72028	18	10	reactive	reactive	ADJ
afs-72028	18	11	components	component	NOUN
afs-72028	18	12	of	of	ADP
afs-72028	18	13	soil	soil	NOUN
afs-72028	18	14	.	.	PUNCT
afs-72028	19	1	this	this	DET
afs-72028	19	2	chemically	chemically	ADV
afs-72028	19	3	active	active	ADJ
afs-72028	19	4	part	part	NOUN
afs-72028	19	5	of	of	ADP
afs-72028	19	6	the	the	DET
afs-72028	19	7	soil	soil	NOUN
afs-72028	19	8	consists	consist	VERB
afs-72028	19	9	of	of	ADP
afs-72028	19	10	soil	soil	NOUN
afs-72028	19	11	organic	organic	ADJ
afs-72028	19	12	matter	matter	NOUN
afs-72028	19	13	,	,	PUNCT
afs-72028	19	14	clay	clay	NOUN
afs-72028	19	15	minerals	mineral	NOUN
afs-72028	19	16	and	and	CCONJ
afs-72028	19	17	polymeric	polymeric	ADJ
afs-72028	19	18	aland	aland	PROPN
afs-72028	19	19	fe	fe	PROPN
afs-72028	19	20	-	-	NOUN
afs-72028	19	21	oxides	oxide	NOUN
afs-72028	19	22	.	.	PUNCT
afs-72028	20	1	the	the	DET
afs-72028	20	2	most	most	ADV
afs-72028	20	3	reactive	reactive	ADJ
afs-72028	20	4	groups	group	NOUN
afs-72028	20	5	of	of	ADP
afs-72028	20	6	the	the	DET
afs-72028	20	7	soil	soil	NOUN
afs-72028	20	8	organic	organic	ADJ
afs-72028	20	9	matter	matter	NOUN
afs-72028	20	10	are	be	AUX
afs-72028	20	11	the	the	DET
afs-72028	20	12	carboxyl	carboxyl	NOUN
afs-72028	20	13	and	and	CCONJ
afs-72028	20	14	phenolic	phenolic	ADJ
afs-72028	20	15	oh	oh	NUM
afs-72028	20	16	groups	group	NOUN
afs-72028	20	17	.	.	PUNCT
afs-72028	21	1	these	these	PRON
afs-72028	21	2	are	be	AUX
afs-72028	21	3	able	able	ADJ
afs-72028	21	4	to	to	PART
afs-72028	21	5	bind	bind	VERB
afs-72028	21	6	a	a	DET
afs-72028	21	7	proton	proton	NOUN
afs-72028	21	8	or	or	CCONJ
afs-72028	21	9	another	another	DET
afs-72028	21	10	cations	cation	NOUN
afs-72028	21	11	(	(	PUNCT
afs-72028	21	12	schnitzer	schnitzer	NOUN
afs-72028	21	13	1978	1978	NUM
afs-72028	21	14	)	)	PUNCT
afs-72028	21	15	.	.	PUNCT
afs-72028	22	1	in	in	ADP
afs-72028	22	2	the	the	DET
afs-72028	22	3	clay	clay	NOUN
afs-72028	22	4	minerals	mineral	NOUN
afs-72028	22	5	the	the	DET
afs-72028	22	6	central	central	ADJ
afs-72028	22	7	ions	ion	NOUN
afs-72028	22	8	(	(	PUNCT
afs-72028	22	9	e.	e.	PROPN
afs-72028	22	10	g.	g.	PROPN
afs-72028	22	11	si4	si4	PROPN
afs-72028	22	12	+	+	PROPN
afs-72028	22	13	,	,	PUNCT
afs-72028	22	14	al	al	PROPN
afs-72028	22	15	3	3	PROPN
afs-72028	22	16	+	+	PROPN
afs-72028	22	17	,	,	PUNCT
afs-72028	22	18	fe	fe	X
afs-72028	22	19	3	3	NUM
afs-72028	22	20	+	+	CCONJ
afs-72028	22	21	)	)	PUNCT
afs-72028	22	22	are	be	AUX
afs-72028	22	23	surrounded	surround	VERB
afs-72028	22	24	by	by	ADP
afs-72028	22	25	negatively	negatively	ADV
afs-72028	22	26	charged	charge	VERB
afs-72028	22	27	oxygen	oxygen	NOUN
afs-72028	22	28	ions	ion	NOUN
afs-72028	22	29	in	in	ADP
afs-72028	22	30	tetrahedral	tetrahedral	ADJ
afs-72028	22	31	or	or	CCONJ
afs-72028	22	32	octahedral	octahedral	ADJ
afs-72028	22	33	layers	layer	NOUN
afs-72028	22	34	.	.	PUNCT
afs-72028	23	1	in	in	ADP
afs-72028	23	2	the	the	DET
afs-72028	23	3	amorphous	amorphous	ADJ
afs-72028	23	4	or	or	CCONJ
afs-72028	23	5	crystallized	crystallized	ADJ
afs-72028	23	6	aland	aland	PROPN
afs-72028	23	7	fe	fe	PROPN
afs-72028	23	8	-	-	PUNCT
afs-72028	23	9	oxides	oxide	NOUN
afs-72028	23	10	the	the	DET
afs-72028	23	11	central	central	ADJ
afs-72028	23	12	ions	ion	NOUN
afs-72028	23	13	are	be	AUX
afs-72028	23	14	surrounded	surround	VERB
afs-72028	23	15	by	by	ADP
afs-72028	23	16	six	six	NUM
afs-72028	23	17	oxygen	oxygen	NOUN
afs-72028	23	18	atoms	atom	NOUN
afs-72028	23	19	.	.	PUNCT
afs-72028	24	1	x	x	X
afs-72028	24	2	)	)	PUNCT
afs-72028	24	3	present	present	ADJ
afs-72028	24	4	adress	adress	NOUN
afs-72028	24	5	:	:	PUNCT
afs-72028	24	6	institute	institute	NOUN
afs-72028	24	7	of	of	ADP
afs-72028	24	8	soil	soil	NOUN
afs-72028	24	9	chemistry	chemistry	NOUN
afs-72028	24	10	and	and	CCONJ
afs-72028	24	11	physics	physics	NOUN
afs-72028	24	12	,	,	PUNCT
afs-72028	24	13	agricultural	agricultural	ADJ
afs-72028	24	14	research	research	NOUN
afs-72028	24	15	centre	centre	PROPN
afs-72028	24	16	31600	31600	NUM
afs-72028	24	17	jokioinen	jokioinen	NOUN
afs-72028	24	18	.	.	PUNCT
afs-72028	24	19	https://www.c-info.fi/en/info/?token=y5xeky5_mqwet6ho.3qthxvgpsykg_tosyqgbhw.vms9mbmgosqhsars39pj-wise1qtbqkxhsofpyzezv6qb1gbnahnlvrunq8yp_arasrowwelxhh71mqdvgcz21ezwk6e4z5cylikbmzofvgwpzlgel_saquh43iv--1mxgxku2_gtftfinvkutmqe6yyry70kk7v	https://www.c-info.fi/en/info/?token=y5xeky5_mqwet6ho.3qthxvgpsykg_tosyqgbhw.vms9mbmgosqhsars39pj-wise1qtbqkxhsofpyzezv6qb1gbnahnlvrunq8yp_arasrowwelxhh71mqdvgcz21ezwk6e4z5cylikbmzofvgwpzlgel_saquh43iv--1mxgxku2_gtftfinvkutmqe6yyry70kk7v	VERB
afs-72028	24	20	35	35	NUM
afs-72028	24	21	the	the	DET
afs-72028	24	22	polymeric	polymeric	ADJ
afs-72028	24	23	aland	aland	PROPN
afs-72028	24	24	fe	fe	NOUN
afs-72028	24	25	-	-	NOUN
afs-72028	24	26	oxides	oxide	NOUN
afs-72028	24	27	of	of	ADP
afs-72028	24	28	the	the	DET
afs-72028	24	29	soil	soil	NOUN
afs-72028	24	30	are	be	AUX
afs-72028	24	31	very	very	ADV
afs-72028	24	32	porous	porous	ADJ
afs-72028	24	33	substances	substance	NOUN
afs-72028	24	34	.	.	PUNCT
afs-72028	25	1	in	in	ADP
afs-72028	25	2	the	the	DET
afs-72028	25	3	amorphous	amorphous	ADJ
afs-72028	25	4	form	form	NOUN
afs-72028	25	5	their	their	PRON
afs-72028	25	6	specific	specific	ADJ
afs-72028	25	7	surface	surface	NOUN
afs-72028	25	8	area	area	NOUN
afs-72028	25	9	is	be	AUX
afs-72028	25	10	over	over	ADP
afs-72028	25	11	100	100	NUM
afs-72028	25	12	m2	m2	PROPN
afs-72028	25	13	/	/	SYM
afs-72028	25	14	g	g	PROPN
afs-72028	25	15	(	(	PUNCT
afs-72028	25	16	e.	e.	PROPN
afs-72028	25	17	g.	g.	PROPN
afs-72028	25	18	rajan	rajan	PROPN
afs-72028	25	19	et	et	PROPN
afs-72028	25	20	al	al	PROPN
afs-72028	25	21	.	.	PROPN
afs-72028	25	22	1974	1974	NUM
afs-72028	25	23	,	,	PUNCT
afs-72028	25	24	parfitt	parfitt	PROPN
afs-72028	25	25	et	et	PROPN
afs-72028	25	26	al	al	PROPN
afs-72028	25	27	.	.	PROPN
afs-72028	25	28	1975	1975	NUM
afs-72028	25	29	)	)	PUNCT
afs-72028	25	30	.	.	PUNCT
afs-72028	26	1	the	the	DET
afs-72028	26	2	great	great	ADJ
afs-72028	26	3	specific	specific	ADJ
afs-72028	26	4	surface	surface	NOUN
afs-72028	26	5	shows	show	NOUN
afs-72028	26	6	,	,	PUNCT
afs-72028	26	7	that	that	SCONJ
afs-72028	26	8	the	the	DET
afs-72028	26	9	amorphous	amorphous	ADJ
afs-72028	26	10	oxides	oxide	NOUN
afs-72028	26	11	have	have	VERB
afs-72028	26	12	plenty	plenty	NOUN
afs-72028	26	13	of	of	ADP
afs-72028	26	14	pores	pore	NOUN
afs-72028	26	15	,	,	PUNCT
afs-72028	26	16	which	which	PRON
afs-72028	26	17	have	have	VERB
afs-72028	26	18	a	a	DET
afs-72028	26	19	diameter	diameter	NOUN
afs-72028	26	20	in	in	ADP
afs-72028	26	21	the	the	DET
afs-72028	26	22	order	order	NOUN
afs-72028	26	23	of	of	ADP
afs-72028	26	24	small	small	ADJ
afs-72028	26	25	molecules	molecule	NOUN
afs-72028	26	26	(	(	PUNCT
afs-72028	26	27	parfitt	parfitt	NOUN
afs-72028	26	28	1971	1971	NUM
afs-72028	26	29	)	)	PUNCT
afs-72028	26	30	.	.	PUNCT
afs-72028	27	1	the	the	DET
afs-72028	27	2	oxide	oxide	NOUN
afs-72028	27	3	polymers	polymer	NOUN
afs-72028	27	4	do	do	AUX
afs-72028	27	5	not	not	PART
afs-72028	27	6	always	always	ADV
afs-72028	27	7	exist	exist	VERB
afs-72028	27	8	as	as	ADP
afs-72028	27	9	separate	separate	ADJ
afs-72028	27	10	paricles	paricle	NOUN
afs-72028	27	11	in	in	ADP
afs-72028	27	12	soil	soil	NOUN
afs-72028	27	13	.	.	PUNCT
afs-72028	28	1	the	the	DET
afs-72028	28	2	aluminium	aluminium	NOUN
afs-72028	28	3	oxides	oxide	VERB
afs-72028	28	4	specially	specially	ADV
afs-72028	28	5	form	form	VERB
afs-72028	28	6	layers	layer	NOUN
afs-72028	28	7	on	on	ADP
afs-72028	28	8	the	the	DET
afs-72028	28	9	surface	surface	NOUN
afs-72028	28	10	of	of	ADP
afs-72028	28	11	clay	clay	NOUN
afs-72028	28	12	particles	particle	NOUN
afs-72028	28	13	(	(	PUNCT
afs-72028	28	14	clark	clark	NOUN
afs-72028	28	15	1964	1964	NUM
afs-72028	28	16	)	)	PUNCT
afs-72028	28	17	.	.	PUNCT
afs-72028	29	1	the	the	DET
afs-72028	29	2	aluminium	aluminium	NOUN
afs-72028	29	3	and	and	CCONJ
afs-72028	29	4	iron	iron	NOUN
afs-72028	29	5	oxides	oxide	NOUN
afs-72028	29	6	can	can	AUX
afs-72028	29	7	also	also	ADV
afs-72028	29	8	be	be	AUX
afs-72028	29	9	attached	attach	VERB
afs-72028	29	10	to	to	ADP
afs-72028	29	11	the	the	DET
afs-72028	29	12	soil	soil	NOUN
afs-72028	29	13	organic	organic	ADJ
afs-72028	29	14	matter	matter	NOUN
afs-72028	29	15	by	by	ADP
afs-72028	29	16	various	various	ADJ
afs-72028	29	17	chemical	chemical	ADJ
afs-72028	29	18	bonds	bond	NOUN
afs-72028	29	19	.	.	PUNCT
afs-72028	30	1	the	the	DET
afs-72028	30	2	surfaces	surface	NOUN
afs-72028	30	3	of	of	ADP
afs-72028	30	4	polymeric	polymeric	ADJ
afs-72028	30	5	aland	aland	PROPN
afs-72028	30	6	fe	fe	PROPN
afs-72028	30	7	-	-	PUNCT
afs-72028	30	8	oxides	oxide	NOUN
afs-72028	30	9	are	be	AUX
afs-72028	30	10	the	the	DET
afs-72028	30	11	anion	anion	NOUN
afs-72028	30	12	exchangers	exchanger	NOUN
afs-72028	30	13	in	in	ADP
afs-72028	30	14	the	the	DET
afs-72028	30	15	soil	soil	NOUN
afs-72028	30	16	.	.	PUNCT
afs-72028	31	1	if	if	SCONJ
afs-72028	31	2	the	the	DET
afs-72028	31	3	oxygen	oxygen	NOUN
afs-72028	31	4	atom	atom	NOUN
afs-72028	31	5	is	be	AUX
afs-72028	31	6	situated	situate	VERB
afs-72028	31	7	internaly	internaly	VERB
afs-72028	31	8	in	in	ADP
afs-72028	31	9	oxides	oxide	NOUN
afs-72028	31	10	,	,	PUNCT
afs-72028	31	11	it	it	PRON
afs-72028	31	12	is	be	AUX
afs-72028	31	13	bound	bind	VERB
afs-72028	31	14	by	by	ADP
afs-72028	31	15	more	more	ADJ
afs-72028	31	16	than	than	ADP
afs-72028	31	17	one	one	NUM
afs-72028	31	18	al	al	PROPN
afs-72028	31	19	3	3	PROPN
afs-72028	31	20	+	+	CCONJ
afs-72028	31	21	(	(	PUNCT
afs-72028	31	22	or	or	CCONJ
afs-72028	31	23	fe	fe	INTJ
afs-72028	31	24	3	3	NUM
afs-72028	31	25	+	+	CCONJ
afs-72028	31	26	)	)	PUNCT
afs-72028	31	27	-ion	-ion	NOUN
afs-72028	31	28	.	.	PUNCT
afs-72028	32	1	in	in	ADP
afs-72028	32	2	this	this	DET
afs-72028	32	3	case	case	NOUN
afs-72028	32	4	the	the	DET
afs-72028	32	5	oxygen	oxygen	NOUN
afs-72028	32	6	is	be	AUX
afs-72028	32	7	inactive	inactive	ADJ
afs-72028	32	8	in	in	ADP
afs-72028	32	9	the	the	DET
afs-72028	32	10	soil	soil	NOUN
afs-72028	32	11	.	.	PUNCT
afs-72028	33	1	whereas	whereas	SCONJ
afs-72028	33	2	on	on	ADP
afs-72028	33	3	the	the	DET
afs-72028	33	4	surface	surface	NOUN
afs-72028	33	5	of	of	ADP
afs-72028	33	6	the	the	DET
afs-72028	33	7	oxides	oxide	NOUN
afs-72028	33	8	,	,	PUNCT
afs-72028	33	9	oxygen	oxygen	NOUN
afs-72028	33	10	can	can	AUX
afs-72028	33	11	be	be	AUX
afs-72028	33	12	attached	attach	VERB
afs-72028	33	13	to	to	ADP
afs-72028	33	14	only	only	ADV
afs-72028	33	15	one	one	NUM
afs-72028	33	16	aluminium	aluminium	NOUN
afs-72028	33	17	or	or	CCONJ
afs-72028	33	18	iron	iron	NOUN
afs-72028	33	19	ion	ion	NOUN
afs-72028	33	20	and	and	CCONJ
afs-72028	33	21	can	can	AUX
afs-72028	33	22	also	also	ADV
afs-72028	33	23	be	be	AUX
afs-72028	33	24	a	a	DET
afs-72028	33	25	part	part	NOUN
afs-72028	33	26	of	of	ADP
afs-72028	33	27	the	the	DET
afs-72028	33	28	structure	structure	NOUN
afs-72028	33	29	of	of	ADP
afs-72028	33	30	the	the	DET
afs-72028	33	31	following	follow	VERB
afs-72028	33	32	anions	anion	NOUN
afs-72028	33	33	or	or	CCONJ
afs-72028	33	34	ligands	ligand	NOUN
afs-72028	33	35	:	:	PUNCT
afs-72028	33	36	water	water	NOUN
afs-72028	33	37	,	,	PUNCT
afs-72028	33	38	hydroxyl	hydroxyl	NOUN
afs-72028	33	39	,	,	PUNCT
afs-72028	33	40	sulphate	sulphate	NOUN
afs-72028	33	41	,	,	PUNCT
afs-72028	33	42	phosphate	phosphate	NOUN
afs-72028	33	43	,	,	PUNCT
afs-72028	33	44	carbonate	carbonate	NOUN
afs-72028	33	45	,	,	PUNCT
afs-72028	33	46	selenite	selenite	NOUN
afs-72028	33	47	,	,	PUNCT
afs-72028	33	48	molybdate	molybdate	ADJ
afs-72028	33	49	,	,	PUNCT
afs-72028	33	50	borate	borate	NOUN
afs-72028	33	51	,	,	PUNCT
afs-72028	33	52	silicate	silicate	NOUN
afs-72028	33	53	and	and	CCONJ
afs-72028	33	54	the	the	DET
afs-72028	33	55	carboxjd	carboxjd	NOUN
afs-72028	33	56	and	and	CCONJ
afs-72028	33	57	phenolic	phenolic	ADJ
afs-72028	33	58	oh	oh	INTJ
afs-72028	33	59	group	group	NOUN
afs-72028	33	60	of	of	ADP
afs-72028	33	61	organic	organic	ADJ
afs-72028	33	62	matter	matter	NOUN
afs-72028	33	63	.	.	PUNCT
afs-72028	34	1	these	these	DET
afs-72028	34	2	anions	anion	NOUN
afs-72028	34	3	are	be	AUX
afs-72028	34	4	not	not	PART
afs-72028	34	5	always	always	ADV
afs-72028	34	6	coordinated	coordinate	VERB
afs-72028	34	7	on	on	ADP
afs-72028	34	8	the	the	DET
afs-72028	34	9	surface	surface	NOUN
afs-72028	34	10	of	of	ADP
afs-72028	34	11	oxides	oxide	NOUN
afs-72028	34	12	.	.	PUNCT
afs-72028	35	1	for	for	ADP
afs-72028	35	2	example	example	NOUN
afs-72028	35	3	a	a	DET
afs-72028	35	4	part	part	NOUN
afs-72028	35	5	of	of	ADP
afs-72028	35	6	phosphate	phosphate	NOUN
afs-72028	35	7	is	be	AUX
afs-72028	35	8	blocked	block	VERB
afs-72028	35	9	in	in	ADP
afs-72028	35	10	oxides	oxide	NOUN
afs-72028	35	11	due	due	ADP
afs-72028	35	12	to	to	ADP
afs-72028	35	13	the	the	DET
afs-72028	35	14	precipitation	precipitation	NOUN
afs-72028	35	15	reactions	reaction	NOUN
afs-72028	35	16	of	of	ADP
afs-72028	35	17	phosphate	phosphate	NOUN
afs-72028	35	18	in	in	ADP
afs-72028	35	19	the	the	DET
afs-72028	35	20	soil	soil	NOUN
afs-72028	35	21	.	.	PUNCT
afs-72028	36	1	however	however	ADV
afs-72028	36	2	,	,	PUNCT
afs-72028	36	3	primarily	primarily	ADV
afs-72028	36	4	the	the	DET
afs-72028	36	5	anions	anion	NOUN
afs-72028	36	6	that	that	PRON
afs-72028	36	7	are	be	AUX
afs-72028	36	8	adsorbed	adsorb	VERB
afs-72028	36	9	on	on	ADP
afs-72028	36	10	the	the	DET
afs-72028	36	11	pore	pore	ADJ
afs-72028	36	12	surface	surface	NOUN
afs-72028	36	13	of	of	ADP
afs-72028	36	14	the	the	DET
afs-72028	36	15	oxides	oxide	NOUN
afs-72028	36	16	participate	participate	VERB
afs-72028	36	17	in	in	ADP
afs-72028	36	18	exchange	exchange	NOUN
afs-72028	36	19	reactions	reaction	NOUN
afs-72028	36	20	.	.	PUNCT
afs-72028	37	1	the	the	DET
afs-72028	37	2	anion	anion	NOUN
afs-72028	37	3	exchange	exchange	NOUN
afs-72028	37	4	in	in	ADP
afs-72028	37	5	the	the	DET
afs-72028	37	6	soil	soil	NOUN
afs-72028	37	7	is	be	AUX
afs-72028	37	8	of	of	ADP
afs-72028	37	9	great	great	ADJ
afs-72028	37	10	importance	importance	NOUN
afs-72028	37	11	e.	e.	PROPN
afs-72028	37	12	g.	g.	PROPN
afs-72028	37	13	in	in	ADP
afs-72028	37	14	the	the	DET
afs-72028	37	15	plant	plant	NOUN
afs-72028	37	16	nutrition	nutrition	NOUN
afs-72028	37	17	.	.	PUNCT
afs-72028	38	1	the	the	DET
afs-72028	38	2	purpose	purpose	NOUN
afs-72028	38	3	of	of	ADP
afs-72028	38	4	this	this	DET
afs-72028	38	5	study	study	NOUN
afs-72028	38	6	was	be	AUX
afs-72028	38	7	to	to	PART
afs-72028	38	8	examine	examine	VERB
afs-72028	38	9	the	the	DET
afs-72028	38	10	factors	factor	NOUN
afs-72028	38	11	,	,	PUNCT
afs-72028	38	12	which	which	PRON
afs-72028	38	13	effect	effect	VERB
afs-72028	38	14	the	the	DET
afs-72028	38	15	coordination	coordination	NOUN
afs-72028	38	16	of	of	ADP
afs-72028	38	17	the	the	DET
afs-72028	38	18	ligand	ligand	ADJ
afs-72028	38	19	oxygen	oxygen	NOUN
afs-72028	38	20	with	with	ADP
afs-72028	38	21	the	the	DET
afs-72028	38	22	central	central	ADJ
afs-72028	38	23	ions	ion	NOUN
afs-72028	38	24	of	of	ADP
afs-72028	38	25	alor	alor	PROPN
afs-72028	38	26	fe	fe	NOUN
afs-72028	38	27	-	-	NOUN
afs-72028	38	28	oxides	oxide	NOUN
afs-72028	38	29	.	.	PUNCT
afs-72028	39	1	the	the	DET
afs-72028	39	2	factors	factor	NOUN
afs-72028	39	3	influencing	influence	VERB
afs-72028	39	4	the	the	DET
afs-72028	39	5	rate	rate	NOUN
afs-72028	39	6	of	of	ADP
afs-72028	39	7	exchange	exchange	NOUN
afs-72028	39	8	were	be	AUX
afs-72028	39	9	also	also	ADV
afs-72028	39	10	considered	consider	VERB
afs-72028	39	11	.	.	PUNCT
afs-72028	40	1	the	the	DET
afs-72028	40	2	emphasis	emphasis	NOUN
afs-72028	40	3	was	be	AUX
afs-72028	40	4	laid	lay	VERB
afs-72028	40	5	on	on	ADP
afs-72028	40	6	the	the	DET
afs-72028	40	7	bonding	bonding	NOUN
afs-72028	40	8	of	of	ADP
afs-72028	40	9	oxygen	oxygen	NOUN
afs-72028	40	10	to	to	ADP
afs-72028	40	11	the	the	DET
afs-72028	40	12	central	central	ADJ
afs-72028	40	13	ion	ion	NOUN
afs-72028	40	14	.	.	PUNCT
afs-72028	41	1	the	the	DET
afs-72028	41	2	effect	effect	NOUN
afs-72028	41	3	of	of	ADP
afs-72028	41	4	the	the	DET
afs-72028	41	5	detailed	detailed	ADJ
afs-72028	41	6	structure	structure	NOUN
afs-72028	41	7	of	of	ADP
afs-72028	41	8	oxides	oxide	NOUN
afs-72028	41	9	on	on	ADP
afs-72028	41	10	the	the	DET
afs-72028	41	11	coordination	coordination	NOUN
afs-72028	41	12	was	be	AUX
afs-72028	41	13	not	not	PART
afs-72028	41	14	examined	examine	VERB
afs-72028	41	15	.	.	PUNCT
afs-72028	42	1	central	central	ADJ
afs-72028	42	2	ions	ion	NOUN
afs-72028	42	3	of	of	ADP
afs-72028	42	4	oxides	oxide	NOUN
afs-72028	42	5	and	and	CCONJ
afs-72028	42	6	ligand	ligand	PROPN
afs-72028	42	7	exchange	exchange	VERB
afs-72028	42	8	the	the	DET
afs-72028	42	9	theory	theory	NOUN
afs-72028	42	10	of	of	ADP
afs-72028	42	11	acids	acid	NOUN
afs-72028	42	12	and	and	CCONJ
afs-72028	42	13	bases	basis	NOUN
afs-72028	42	14	presented	present	VERB
afs-72028	42	15	by	by	ADP
afs-72028	42	16	pearson	pearson	PROPN
afs-72028	42	17	(	(	PUNCT
afs-72028	42	18	1966	1966	NUM
afs-72028	42	19	)	)	PUNCT
afs-72028	42	20	seems	seem	VERB
afs-72028	42	21	to	to	PART
afs-72028	42	22	be	be	AUX
afs-72028	42	23	very	very	ADV
afs-72028	42	24	useful	useful	ADJ
afs-72028	42	25	in	in	ADP
afs-72028	42	26	the	the	DET
afs-72028	42	27	study	study	NOUN
afs-72028	42	28	of	of	ADP
afs-72028	42	29	ligand	ligand	ADJ
afs-72028	42	30	exchange	exchange	NOUN
afs-72028	42	31	in	in	ADP
afs-72028	42	32	soil	soil	NOUN
afs-72028	42	33	:	:	PUNCT
afs-72028	42	34	in	in	ADP
afs-72028	42	35	the	the	DET
afs-72028	42	36	ligand	ligand	NOUN
afs-72028	42	37	exchange	exchange	NOUN
afs-72028	42	38	the	the	DET
afs-72028	42	39	central	central	ADJ
afs-72028	42	40	ions	ion	NOUN
afs-72028	42	41	al	al	PROPN
afs-72028	42	42	3	3	NUM
afs-72028	42	43	+	+	NUM
afs-72028	42	44	and	and	CCONJ
afs-72028	42	45	fe	fe	X
afs-72028	42	46	3	3	NUM
afs-72028	42	47	+	+	NUM
afs-72028	42	48	are	be	AUX
afs-72028	42	49	lewis	lewis	PROPN
afs-72028	42	50	acids	acid	NOUN
afs-72028	42	51	or	or	CCONJ
afs-72028	42	52	electron	electron	NOUN
afs-72028	42	53	acceptors	acceptor	NOUN
afs-72028	42	54	and	and	CCONJ
afs-72028	42	55	ligands	ligand	NOUN
afs-72028	42	56	are	be	AUX
afs-72028	42	57	lewis	lewis	PROPN
afs-72028	42	58	bases	basis	NOUN
afs-72028	42	59	or	or	CCONJ
afs-72028	42	60	electron	electron	NOUN
afs-72028	42	61	donors	donor	NOUN
afs-72028	42	62	.	.	PUNCT
afs-72028	43	1	the	the	DET
afs-72028	43	2	ions	ion	NOUN
afs-72028	43	3	al	al	PROPN
afs-72028	43	4	3	3	NUM
afs-72028	43	5	+	+	NUM
afs-72028	43	6	and	and	CCONJ
afs-72028	43	7	fe	fe	X
afs-72028	43	8	3	3	NUM
afs-72028	43	9	+	+	NUM
afs-72028	43	10	belong	belong	VERB
afs-72028	43	11	to	to	ADP
afs-72028	43	12	the	the	DET
afs-72028	43	13	group	group	NOUN
afs-72028	43	14	of	of	ADP
afs-72028	43	15	hard	hard	PROPN
afs-72028	43	16	lewis	lewis	PROPN
afs-72028	43	17	acids	acid	NOUN
afs-72028	43	18	.	.	PUNCT
afs-72028	44	1	these	these	DET
afs-72028	44	2	ions	ion	NOUN
afs-72028	44	3	have	have	VERB
afs-72028	44	4	the	the	DET
afs-72028	44	5	distinguishing	distinguish	VERB
afs-72028	44	6	property	property	NOUN
afs-72028	44	7	of	of	ADP
afs-72028	44	8	small	small	ADJ
afs-72028	44	9	size	size	NOUN
afs-72028	44	10	and	and	CCONJ
afs-72028	44	11	high	high	ADJ
afs-72028	44	12	positive	positive	ADJ
afs-72028	44	13	oxidation	oxidation	NOUN
afs-72028	44	14	state	state	NOUN
afs-72028	44	15	.	.	PUNCT
afs-72028	45	1	hard	hard	ADJ
afs-72028	45	2	acids	acid	NOUN
afs-72028	45	3	prefer	prefer	VERB
afs-72028	45	4	to	to	PART
afs-72028	45	5	associate	associate	VERB
afs-72028	45	6	with	with	ADP
afs-72028	45	7	hard	hard	ADJ
afs-72028	45	8	bases	basis	NOUN
afs-72028	45	9	.	.	PUNCT
afs-72028	46	1	the	the	DET
afs-72028	46	2	latter	latter	ADJ
afs-72028	46	3	have	have	VERB
afs-72028	46	4	low	low	ADJ
afs-72028	46	5	polarizability	polarizability	NOUN
afs-72028	46	6	and	and	CCONJ
afs-72028	46	7	high	high	ADJ
afs-72028	46	8	electronegativity	electronegativity	NOUN
afs-72028	46	9	.	.	PUNCT
afs-72028	47	1	the	the	DET
afs-72028	47	2	donor	donor	NOUN
afs-72028	47	3	atom	atom	NOUN
afs-72028	47	4	is	be	AUX
afs-72028	47	5	often	often	ADV
afs-72028	47	6	o	o	NOUN
afs-72028	47	7	,	,	PUNCT
afs-72028	47	8	but	but	CCONJ
afs-72028	47	9	can	can	AUX
afs-72028	47	10	also	also	ADV
afs-72028	47	11	be	be	AUX
afs-72028	47	12	f	f	PROPN
afs-72028	47	13	or	or	CCONJ
afs-72028	47	14	n.	n.	VERB
afs-72028	47	15	the	the	DET
afs-72028	47	16	acidic	acidic	ADJ
afs-72028	47	17	property	property	NOUN
afs-72028	47	18	of	of	ADP
afs-72028	47	19	al	al	PROPN
afs-72028	47	20	3	3	PROPN
afs-72028	47	21	+	+	NUM
afs-72028	47	22	and	and	CCONJ
afs-72028	47	23	fe	fe	X
afs-72028	48	1	3	3	NUM
afs-72028	48	2	+	+	NOUN
afs-72028	48	3	in	in	ADP
afs-72028	48	4	water	water	NOUN
afs-72028	48	5	solution	solution	NOUN
afs-72028	48	6	is	be	AUX
afs-72028	48	7	due	due	ADJ
afs-72028	48	8	to	to	ADP
afs-72028	48	9	the	the	DET
afs-72028	48	10	fact	fact	NOUN
afs-72028	48	11	that	that	SCONJ
afs-72028	48	12	the	the	DET
afs-72028	48	13	oxygen	oxygen	NOUN
afs-72028	48	14	from	from	ADP
afs-72028	48	15	six	six	NUM
afs-72028	48	16	water	water	NOUN
afs-72028	48	17	molecules	molecule	NOUN
afs-72028	48	18	around	around	ADP
afs-72028	48	19	the	the	DET
afs-72028	48	20	al	al	PROPN
afs-72028	48	21	3	3	PROPN
afs-72028	48	22	+	+	NUM
afs-72028	48	23	or	or	CCONJ
afs-72028	48	24	fe	fe	X
afs-72028	48	25	3	3	NUM
afs-72028	48	26	+	+	NOUN
afs-72028	48	27	ions	ion	NOUN
afs-72028	48	28	are	be	AUX
afs-72028	48	29	electron	electron	NOUN
afs-72028	48	30	donors	donor	NOUN
afs-72028	48	31	,	,	PUNCT
afs-72028	48	32	which	which	PRON
afs-72028	48	33	aids	aid	VERB
afs-72028	48	34	the	the	DET
afs-72028	48	35	detachment	detachment	NOUN
afs-72028	48	36	of	of	ADP
afs-72028	48	37	a	a	DET
afs-72028	48	38	proton	proton	NOUN
afs-72028	48	39	from	from	ADP
afs-72028	48	40	the	the	DET
afs-72028	48	41	coordinated	coordinate	VERB
afs-72028	48	42	water	water	NOUN
afs-72028	48	43	molecule	molecule	NOUN
afs-72028	48	44	.	.	PUNCT
afs-72028	49	1	the	the	DET
afs-72028	49	2	electrons	electron	NOUN
afs-72028	49	3	of	of	ADP
afs-72028	49	4	oxygen	oxygen	NOUN
afs-72028	49	5	are	be	AUX
afs-72028	49	6	shared	share	VERB
afs-72028	49	7	more	more	ADV
afs-72028	49	8	strongly	strongly	ADV
afs-72028	49	9	with	with	ADP
afs-72028	49	10	fe	fe	X
afs-72028	49	11	3	3	NUM
afs-72028	49	12	+	+	NUM
afs-72028	49	13	than	than	ADP
afs-72028	49	14	with	with	ADP
afs-72028	49	15	al	al	PROPN
afs-72028	49	16	3	3	PROPN
afs-72028	49	17	+	+	NUM
afs-72028	49	18	the	the	DET
afs-72028	49	19	acid	acid	NOUN
afs-72028	49	20	hydrolysis	hydrolysis	NOUN
afs-72028	49	21	constant	constant	ADJ
afs-72028	49	22	is	be	AUX
afs-72028	49	23	5.0	5.0	NUM
afs-72028	49	24	at	at	ADP
afs-72028	49	25	25	25	NUM
afs-72028	50	1	°	°	NOUN
afs-72028	50	2	c	c	NOUN
afs-72028	50	3	for	for	ADP
afs-72028	50	4	al	al	PROPN
afs-72028	50	5	3	3	PROPN
afs-72028	50	6	+	+	NUM
afs-72028	50	7	and	and	CCONJ
afs-72028	50	8	2.2	2.2	NUM
afs-72028	50	9	for	for	ADP
afs-72028	50	10	fe	fe	X
afs-72028	50	11	3	3	NUM
afs-72028	50	12	+	+	CCONJ
afs-72028	50	13	(	(	PUNCT
afs-72028	50	14	hunt	hunt	NOUN
afs-72028	50	15	1963	1963	NUM
afs-72028	50	16	,	,	PUNCT
afs-72028	50	17	p.	p.	NOUN
afs-72028	50	18	50	50	NUM
afs-72028	50	19	)	)	PUNCT
afs-72028	50	20	.	.	PUNCT
afs-72028	51	1	due	due	ADP
afs-72028	51	2	to	to	ADP
afs-72028	51	3	the	the	DET
afs-72028	51	4	decrease	decrease	NOUN
afs-72028	51	5	of	of	ADP
afs-72028	51	6	charge	charge	NOUN
afs-72028	51	7	in	in	ADP
afs-72028	51	8	hydrolysis	hydrolysis	NOUN
afs-72028	51	9	,	,	PUNCT
afs-72028	51	10	the	the	DET
afs-72028	51	11	monomeric	monomeric	ADJ
afs-72028	51	12	ai(h	ai(h	ADP
afs-72028	51	13	2	2	NUM
afs-72028	51	14	o	o	NOUN
afs-72028	51	15	)	)	PUNCT
afs-72028	51	16	soh	soh	NOUN
afs-72028	51	17	or	or	CCONJ
afs-72028	51	18	fe(h	fe(h	NOUN
afs-72028	51	19	2o	2o	NOUN
afs-72028	51	20	)	)	PUNCT
afs-72028	51	21	6oh	6oh	NOUN
afs-72028	51	22	tend	tend	VERB
afs-72028	51	23	to	to	PART
afs-72028	51	24	polymerize	polymerize	VERB
afs-72028	51	25	.	.	PUNCT
afs-72028	52	1	in	in	ADP
afs-72028	52	2	water	water	NOUN
afs-72028	52	3	solutions	solution	NOUN
afs-72028	52	4	ferric	ferric	ADJ
afs-72028	52	5	ions	ion	NOUN
afs-72028	52	6	polymerize	polymerize	VERB
afs-72028	52	7	readily	readily	ADV
afs-72028	52	8	above	above	ADP
afs-72028	52	9	ph	ph	X
afs-72028	52	10	2	2	NUM
afs-72028	52	11	and	and	CCONJ
afs-72028	52	12	aluminium	aluminium	NOUN
afs-72028	52	13	ions	ion	NOUN
afs-72028	52	14	above	above	ADP
afs-72028	52	15	ph	ph	X
afs-72028	52	16	5	5	NUM
afs-72028	52	17	(	(	PUNCT
afs-72028	52	18	e.	e.	PROPN
afs-72028	52	19	g.	g.	PROPN
afs-72028	52	20	jackson	jackson	PROPN
afs-72028	52	21	1960	1960	PROPN
afs-72028	52	22	,	,	PUNCT
afs-72028	52	23	murphy	murphy	PROPN
afs-72028	52	24	et	et	PROPN
afs-72028	52	25	al	al	PROPN
afs-72028	52	26	.	.	PROPN
afs-72028	52	27	1975	1975	NUM
afs-72028	52	28	)	)	PUNCT
afs-72028	52	29	.	.	PUNCT
afs-72028	53	1	polymerization	polymerization	NOUN
afs-72028	53	2	can	can	AUX
afs-72028	53	3	be	be	AUX
afs-72028	53	4	seen	see	VERB
afs-72028	53	5	as	as	ADP
afs-72028	53	6	a	a	DET
afs-72028	53	7	ligand	ligand	ADJ
afs-72028	53	8	exchange	exchange	NOUN
afs-72028	53	9	.	.	PUNCT
afs-72028	54	1	the	the	DET
afs-72028	54	2	oh	oh	NUM
afs-72028	54	3	-	-	PUNCT
afs-72028	54	4	group	group	NOUN
afs-72028	54	5	attached	attach	VERB
afs-72028	54	6	to	to	ADP
afs-72028	54	7	the	the	DET
afs-72028	54	8	central	central	ADJ
afs-72028	54	9	ion	ion	NOUN
afs-72028	54	10	is	be	AUX
afs-72028	54	11	exchanged	exchange	VERB
afs-72028	54	12	by	by	ADP
afs-72028	54	13	the	the	DET
afs-72028	54	14	oxygen	oxygen	NOUN
afs-72028	54	15	which	which	PRON
afs-72028	54	16	is	be	AUX
afs-72028	54	17	bound	bind	VERB
afs-72028	54	18	by	by	ADP
afs-72028	54	19	the	the	DET
afs-72028	54	20	other	other	ADJ
afs-72028	54	21	central	central	ADJ
afs-72028	54	22	ion	ion	NOUN
afs-72028	54	23	for	for	ADP
afs-72028	54	24	example	example	NOUN
afs-72028	54	25	:	:	PUNCT
afs-72028	54	26	36	36	NUM
afs-72028	54	27	\	\	NOUN
afs-72028	54	28	/	/	SYM
afs-72028	54	29	\	\	PROPN
afs-72028	54	30	/	/	SYM
afs-72028	54	31	al	al	PROPN
afs-72028	54	32	/	/	SYM
afs-72028	54	33	\	\	NOUN
afs-72028	54	34	\	\	NOUN
afs-72028	54	35	/	/	PUNCT
afs-72028	54	36	ai	ai	PROPN
afs-72028	54	37	/	/	SYM
afs-72028	54	38	\	\	NOUN
afs-72028	54	39	\	\	NOUN
afs-72028	54	40	,	,	PUNCT
afs-72028	54	41	alal	alal	PROPN
afs-72028	55	1	oh	oh	INTJ
afs-72028	55	2	+	+	NUM
afs-72028	55	3	ho	ho	PROPN
afs-72028	55	4	.	.	PUNCT
afs-72028	55	5	o	o	PROPN
afs-72028	56	1	+	+	CCONJ
afs-72028	56	2	h	h	NOUN
afs-72028	56	3	2	2	NUM
afs-72028	56	4	o	o	NOUN
afs-72028	56	5	/	/	SYM
afs-72028	56	6	/	/	SYM
afs-72028	56	7	\	\	NOUN
afs-72028	56	8	the	the	DET
afs-72028	56	9	reduction	reduction	NOUN
afs-72028	56	10	of	of	ADP
afs-72028	56	11	fe	fe	X
afs-72028	56	12	3	3	NUM
afs-72028	56	13	+	+	NUM
afs-72028	56	14	to	to	ADP
afs-72028	56	15	fe	fe	NOUN
afs-72028	56	16	2	2	NUM
afs-72028	56	17	+	+	NUM
afs-72028	56	18	decreases	decrease	VERB
afs-72028	56	19	greatly	greatly	ADV
afs-72028	56	20	the	the	DET
afs-72028	56	21	ability	ability	NOUN
afs-72028	56	22	of	of	ADP
afs-72028	56	23	iron	iron	NOUN
afs-72028	56	24	to	to	PART
afs-72028	56	25	bind	bind	VERB
afs-72028	56	26	the	the	DET
afs-72028	56	27	electrons	electron	NOUN
afs-72028	56	28	of	of	ADP
afs-72028	56	29	the	the	DET
afs-72028	56	30	oxygen	oxygen	NOUN
afs-72028	56	31	ligand	ligand	NOUN
afs-72028	56	32	.	.	PUNCT
afs-72028	57	1	consequently	consequently	ADV
afs-72028	57	2	the	the	DET
afs-72028	57	3	acid	acid	NOUN
afs-72028	57	4	hydrolysis	hydrolysis	NOUN
afs-72028	57	5	constant	constant	ADJ
afs-72028	57	6	of	of	ADP
afs-72028	57	7	fe	fe	X
afs-72028	57	8	2	2	NUM
afs-72028	57	9	+	+	NOUN
afs-72028	57	10	at	at	ADP
afs-72028	57	11	25	25	NUM
afs-72028	57	12	°	°	NOUN
afs-72028	57	13	cis	cis	NOUN
afs-72028	57	14	as	as	ADV
afs-72028	57	15	high	high	ADJ
afs-72028	57	16	as	as	ADP
afs-72028	57	17	9.5	9.5	NUM
afs-72028	57	18	(	(	PUNCT
afs-72028	57	19	basolo	basolo	NOUN
afs-72028	57	20	and	and	CCONJ
afs-72028	57	21	pearson	pearson	PROPN
afs-72028	57	22	1967	1967	NUM
afs-72028	57	23	,	,	PUNCT
afs-72028	57	24	p.	p.	NOUN
afs-72028	57	25	32	32	NUM
afs-72028	57	26	)	)	PUNCT
afs-72028	57	27	.	.	PUNCT
afs-72028	58	1	in	in	ADP
afs-72028	58	2	reductive	reductive	ADJ
afs-72028	58	3	conditions	condition	NOUN
afs-72028	58	4	the	the	DET
afs-72028	58	5	iron	iron	NOUN
afs-72028	58	6	oxides	oxide	NOUN
afs-72028	58	7	tend	tend	VERB
afs-72028	58	8	to	to	PART
afs-72028	58	9	break	break	VERB
afs-72028	58	10	up	up	ADP
afs-72028	58	11	and	and	CCONJ
afs-72028	58	12	fe	fe	X
afs-72028	59	1	2	2	NUM
afs-72028	59	2	+	+	NUM
afs-72028	59	3	is	be	AUX
afs-72028	59	4	easily	easily	ADV
afs-72028	59	5	released	release	VERB
afs-72028	59	6	from	from	ADP
afs-72028	59	7	oxides	oxide	NOUN
afs-72028	59	8	as	as	ADP
afs-72028	59	9	a	a	DET
afs-72028	59	10	monomeric	monomeric	ADJ
afs-72028	59	11	cation	cation	NOUN
afs-72028	59	12	.	.	PUNCT
afs-72028	60	1	the	the	DET
afs-72028	60	2	chemical	chemical	NOUN
afs-72028	60	3	bond	bond	NOUN
afs-72028	60	4	between	between	ADP
afs-72028	60	5	the	the	DET
afs-72028	60	6	oxygen	oxygen	NOUN
afs-72028	60	7	ligand	ligand	NOUN
afs-72028	60	8	and	and	CCONJ
afs-72028	60	9	central	central	ADJ
afs-72028	60	10	ion	ion	NOUN
afs-72028	60	11	of	of	ADP
afs-72028	60	12	oxides	oxide	NOUN
afs-72028	60	13	the	the	DET
afs-72028	60	14	binding	binding	NOUN
afs-72028	60	15	of	of	ADP
afs-72028	60	16	oxygen	oxygen	NOUN
afs-72028	60	17	by	by	ADP
afs-72028	60	18	the	the	DET
afs-72028	60	19	central	central	ADJ
afs-72028	60	20	ion	ion	NOUN
afs-72028	60	21	is	be	AUX
afs-72028	60	22	primarily	primarily	ADV
afs-72028	60	23	dependent	dependent	ADJ
afs-72028	60	24	on	on	ADP
afs-72028	60	25	the	the	DET
afs-72028	60	26	nucleophilic	nucleophilic	ADJ
afs-72028	60	27	strength	strength	NOUN
afs-72028	60	28	of	of	ADP
afs-72028	60	29	the	the	DET
afs-72028	60	30	oxyanion	oxyanion	NOUN
afs-72028	60	31	or	or	CCONJ
afs-72028	60	32	ligand	ligand	NOUN
afs-72028	60	33	.	.	PUNCT
afs-72028	61	1	the	the	DET
afs-72028	61	2	cation	cation	NOUN
afs-72028	61	3	h+	h+	PUNCT
afs-72028	61	4	is	be	AUX
afs-72028	61	5	the	the	DET
afs-72028	61	6	prototype	prototype	NOUN
afs-72028	61	7	hard	hard	PROPN
afs-72028	61	8	lewis	lewis	PROPN
afs-72028	61	9	acid	acid	PROPN
afs-72028	61	10	and	and	CCONJ
afs-72028	61	11	any	any	DET
afs-72028	61	12	base	base	NOUN
afs-72028	61	13	which	which	PRON
afs-72028	61	14	binds	bind	VERB
afs-72028	61	15	strongly	strongly	ADV
afs-72028	61	16	to	to	ADP
afs-72028	61	17	the	the	DET
afs-72028	61	18	proton	proton	NOUN
afs-72028	61	19	will	will	AUX
afs-72028	61	20	also	also	ADV
afs-72028	61	21	bind	bind	VERB
afs-72028	61	22	to	to	ADP
afs-72028	61	23	other	other	ADJ
afs-72028	61	24	hard	hard	ADJ
afs-72028	61	25	acids	acid	NOUN
afs-72028	61	26	as	as	ADV
afs-72028	61	27	well	well	ADV
afs-72028	61	28	(	(	PUNCT
afs-72028	61	29	pearson	pearson	NOUN
afs-72028	61	30	1966	1966	NUM
afs-72028	61	31	)	)	PUNCT
afs-72028	61	32	the	the	DET
afs-72028	61	33	pka	pka	NOUN
afs-72028	61	34	-	-	PUNCT
afs-72028	61	35	value	value	NOUN
afs-72028	61	36	of	of	ADP
afs-72028	61	37	the	the	DET
afs-72028	61	38	acids	acid	NOUN
afs-72028	61	39	corresponding	correspond	VERB
afs-72028	61	40	the	the	DET
afs-72028	61	41	oxyanions	oxyanion	NOUN
afs-72028	61	42	shows	show	VERB
afs-72028	61	43	the	the	DET
afs-72028	61	44	ability	ability	NOUN
afs-72028	61	45	of	of	ADP
afs-72028	61	46	anion	anion	NOUN
afs-72028	61	47	oxygen	oxygen	NOUN
afs-72028	61	48	to	to	PART
afs-72028	61	49	bind	bind	VERB
afs-72028	61	50	a	a	DET
afs-72028	61	51	proton	proton	NOUN
afs-72028	61	52	and	and	CCONJ
afs-72028	61	53	also	also	ADV
afs-72028	61	54	the	the	DET
afs-72028	61	55	nucleophilic	nucleophilic	ADJ
afs-72028	61	56	strength	strength	NOUN
afs-72028	61	57	.	.	PUNCT
afs-72028	62	1	the	the	PRON
afs-72028	62	2	higher	high	ADJ
afs-72028	62	3	the	the	DET
afs-72028	62	4	pka	pka	NOUN
afs-72028	62	5	-	-	PUNCT
afs-72028	62	6	value	value	NOUN
afs-72028	62	7	the	the	DET
afs-72028	62	8	more	more	ADV
afs-72028	62	9	stable	stable	ADJ
afs-72028	62	10	is	be	AUX
afs-72028	62	11	the	the	DET
afs-72028	62	12	bond	bond	NOUN
afs-72028	62	13	between	between	ADP
afs-72028	62	14	oxygen	oxygen	NOUN
afs-72028	62	15	and	and	CCONJ
afs-72028	62	16	the	the	DET
afs-72028	62	17	central	central	ADJ
afs-72028	62	18	ions	ion	NOUN
afs-72028	62	19	al	al	PROPN
afs-72028	62	20	3	3	NUM
afs-72028	62	21	+	+	NUM
afs-72028	62	22	and	and	CCONJ
afs-72028	62	23	fe	fe	X
afs-72028	62	24	3	3	NUM
afs-72028	62	25	(	(	PUNCT
afs-72028	62	26	edwards	edwards	PROPN
afs-72028	62	27	1956	1956	NUM
afs-72028	62	28	,	,	PUNCT
afs-72028	62	29	pearson	pearson	NOUN
afs-72028	62	30	1966	1966	NUM
afs-72028	62	31	)	)	PUNCT
afs-72028	62	32	.	.	PUNCT
afs-72028	63	1	edwards	edwards	PROPN
afs-72028	63	2	(	(	PUNCT
afs-72028	63	3	1956	1956	NUM
afs-72028	63	4	)	)	PUNCT
afs-72028	63	5	has	have	AUX
afs-72028	63	6	shown	show	VERB
afs-72028	63	7	that	that	SCONJ
afs-72028	63	8	the	the	DET
afs-72028	63	9	nucleophilic	nucleophilic	ADJ
afs-72028	63	10	character	character	NOUN
afs-72028	63	11	of	of	ADP
afs-72028	63	12	the	the	DET
afs-72028	63	13	donor	donor	NOUN
afs-72028	63	14	depends	depend	VERB
afs-72028	63	15	on	on	ADP
afs-72028	63	16	both	both	CCONJ
afs-72028	63	17	the	the	DET
afs-72028	63	18	basicity	basicity	NOUN
afs-72028	63	19	of	of	ADP
afs-72028	63	20	the	the	DET
afs-72028	63	21	ligand	ligand	NOUN
afs-72028	63	22	and	and	CCONJ
afs-72028	63	23	also	also	ADV
afs-72028	63	24	on	on	ADP
afs-72028	63	25	the	the	DET
afs-72028	63	26	ease	ease	NOUN
afs-72028	63	27	with	with	ADP
afs-72028	63	28	which	which	PRON
afs-72028	63	29	the	the	DET
afs-72028	63	30	donors	donor	NOUN
afs-72028	63	31	polarize	polarize	VERB
afs-72028	63	32	.	.	PUNCT
afs-72028	64	1	the	the	DET
afs-72028	64	2	ability	ability	NOUN
afs-72028	64	3	of	of	ADP
afs-72028	64	4	the	the	DET
afs-72028	64	5	ligand	ligand	NOUN
afs-72028	64	6	to	to	PART
afs-72028	64	7	coordinate	coordinate	VERB
afs-72028	64	8	to	to	ADP
afs-72028	64	9	the	the	DET
afs-72028	64	10	central	central	ADJ
afs-72028	64	11	atom	atom	NOUN
afs-72028	64	12	,	,	PUNCT
afs-72028	64	13	when	when	SCONJ
afs-72028	64	14	it	it	PRON
afs-72028	64	15	is	be	AUX
afs-72028	64	16	a	a	DET
afs-72028	64	17	hard	hard	ADJ
afs-72028	64	18	lewis	lewis	PROPN
afs-72028	64	19	acid	acid	NOUN
afs-72028	64	20	,	,	PUNCT
afs-72028	64	21	is	be	AUX
afs-72028	64	22	primarily	primarily	ADV
afs-72028	64	23	related	relate	VERB
afs-72028	64	24	to	to	ADP
afs-72028	64	25	the	the	DET
afs-72028	64	26	basicity	basicity	NOUN
afs-72028	64	27	of	of	ADP
afs-72028	64	28	the	the	DET
afs-72028	64	29	ligand	ligand	NOUN
afs-72028	64	30	(	(	PUNCT
afs-72028	64	31	edwards	edwards	PROPN
afs-72028	64	32	and	and	CCONJ
afs-72028	64	33	pearson	pearson	PROPN
afs-72028	64	34	1962	1962	NUM
afs-72028	64	35	,	,	PUNCT
afs-72028	64	36	pearson	pearson	NOUN
afs-72028	64	37	1966	1966	NUM
afs-72028	64	38	)	)	PUNCT
afs-72028	64	39	.	.	PUNCT
afs-72028	65	1	table	table	NOUN
afs-72028	65	2	1	1	NUM
afs-72028	65	3	.	.	PUNCT
afs-72028	66	1	the	the	DET
afs-72028	66	2	pka	pka	NOUN
afs-72028	66	3	-	-	PUNCT
afs-72028	66	4	values	value	NOUN
afs-72028	66	5	of	of	ADP
afs-72028	66	6	acids	acid	NOUN
afs-72028	66	7	corresponding	correspond	VERB
afs-72028	66	8	to	to	ADP
afs-72028	66	9	the	the	DET
afs-72028	66	10	ligands	ligand	NOUN
afs-72028	66	11	(	(	PUNCT
afs-72028	66	12	sasaki	sasaki	PROPN
afs-72028	66	13	et	et	PROPN
afs-72028	66	14	al	al	PROPN
afs-72028	66	15	.	.	PROPN
afs-72028	66	16	1959	1959	NUM
afs-72028	66	17	,	,	PUNCT
afs-72028	66	18	weast	weast	NOUN
afs-72028	66	19	1969	1969	NUM
afs-72028	66	20	)	)	PUNCT
afs-72028	66	21	.	.	PUNCT
afs-72028	67	1	ligand	ligand	PROPN
afs-72028	67	2	acid	acid	PROPN
afs-72028	67	3	pka	pka	PROPN
afs-72028	67	4	(	(	PUNCT
afs-72028	67	5	25	25	NUM
afs-72028	67	6	°	°	NOUN
afs-72028	67	7	c	c	NOUN
afs-72028	67	8	)	)	PUNCT
afs-72028	67	9	h	h	NOUN
afs-72028	68	1	2	2	NUM
afs-72028	68	2	o	o	NOUN
afs-72028	68	3	no	no	INTJ
afs-72028	68	4	;	;	PUNCT
afs-72028	68	5	hso4	hso4	PROPN
afs-72028	68	6	so	so	ADV
afs-72028	68	7	;	;	PUNCT
afs-72028	68	8	h	h	PROPN
afs-72028	68	9	2	2	NUM
afs-72028	68	10	po	po	NOUN
afs-72028	68	11	4	4	NUM
afs-72028	68	12	hse03	hse03	NOUN
afs-72028	68	13	mooj	mooj	NOUN
afs-72028	68	14	hco3	hco3	PROPN
afs-72028	68	15	hpoj	hpoj	PROPN
afs-72028	68	16	seoj	seoj	VERB
afs-72028	68	17	h2bo	h2bo	PUNCT
afs-72028	68	18	3	3	NUM
afs-72028	68	19	h3si04	h3si04	PROPN
afs-72028	68	20	co|	co|	PROPN
afs-72028	68	21	pof--4	pof--4	NOUN
afs-72028	68	22	oh	oh	NUM
afs-72028	68	23	hao+	hao+	NOUN
afs-72028	68	24	-1.74	-1.74	PROPN
afs-72028	69	1	hno3	hno3	PROPN
afs-72028	69	2	h2	h2	PROPN
afs-72028	69	3	so4	so4	PROPN
afs-72028	69	4	hs04	hs04	PROPN
afs-72028	69	5	1.92	1.92	NUM
afs-72028	69	6	h3p04	h3p04	PROPN
afs-72028	69	7	2.12	2.12	NUM
afs-72028	69	8	h2	h2	NOUN
afs-72028	69	9	se03	se03	PROPN
afs-72028	69	10	2.46	2.46	NUM
afs-72028	69	11	hmoq4	hmoq4	NOUN
afs-72028	69	12	4.1	4.1	NUM
afs-72028	69	13	h2	h2	NOUN
afs-72028	69	14	c03	c03	NOUN
afs-72028	69	15	6.37	6.37	NUM
afs-72028	69	16	h2p0	h2p0	VERB
afs-72028	69	17	4	4	NUM
afs-72028	69	18	7.21	7.21	NUM
afs-72028	69	19	hseoj	hseoj	NOUN
afs-72028	69	20	7.31	7.31	NUM
afs-72028	69	21	h3b0	h3b0	X
afs-72028	69	22	3	3	NUM
afs-72028	69	23	9.14	9.14	NUM
afs-72028	69	24	(	(	PUNCT
afs-72028	69	25	20	20	NUM
afs-72028	69	26	°	°	NUM
afs-72028	69	27	c	c	NOUN
afs-72028	69	28	)	)	PUNCT
afs-72028	69	29	h	h	NOUN
afs-72028	69	30	4si04	4si04	NUM
afs-72028	69	31	9.66	9.66	NUM
afs-72028	69	32	(	(	PUNCT
afs-72028	69	33	30	30	NUM
afs-72028	69	34	°	°	NUM
afs-72028	69	35	c	c	NOUN
afs-72028	69	36	)	)	PUNCT
afs-72028	70	1	hc03	hc03	PROPN
afs-72028	70	2	10.25	10.25	NUM
afs-72028	70	3	hpo=	hpo=	NOUN
afs-72028	70	4	12.67	12.67	NUM
afs-72028	70	5	(	(	PUNCT
afs-72028	70	6	18	18	NUM
afs-72028	70	7	°	°	NUM
afs-72028	70	8	c	c	NOUN
afs-72028	70	9	)	)	PUNCT
afs-72028	70	10	h	h	NOUN
afs-72028	70	11	2	2	NUM
afs-72028	70	12	o	o	NOUN
afs-72028	70	13	15.74	15.74	NUM
afs-72028	70	14	the	the	DET
afs-72028	70	15	pka	pka	NOUN
afs-72028	70	16	-	-	PUNCT
afs-72028	70	17	values	value	NOUN
afs-72028	70	18	of	of	ADP
afs-72028	70	19	the	the	DET
afs-72028	70	20	most	most	ADV
afs-72028	70	21	usual	usual	ADJ
afs-72028	70	22	inorganic	inorganic	ADJ
afs-72028	70	23	ligands	ligand	NOUN
afs-72028	70	24	are	be	AUX
afs-72028	70	25	shown	show	VERB
afs-72028	70	26	in	in	ADP
afs-72028	70	27	table	table	NOUN
afs-72028	70	28	1	1	NUM
afs-72028	70	29	.	.	PUNCT
afs-72028	71	1	if	if	SCONJ
afs-72028	71	2	the	the	DET
afs-72028	71	3	pka	pka	NOUN
afs-72028	71	4	-	-	PUNCT
afs-72028	71	5	value	value	NOUN
afs-72028	71	6	is	be	AUX
afs-72028	71	7	high	high	ADJ
afs-72028	71	8	,	,	PUNCT
afs-72028	71	9	the	the	DET
afs-72028	71	10	anion	anion	NOUN
afs-72028	71	11	concentration	concentration	NOUN
afs-72028	71	12	in	in	ADP
afs-72028	71	13	the	the	DET
afs-72028	71	14	equilibrium	equilibrium	NOUN
afs-72028	71	15	solution	solution	NOUN
afs-72028	71	16	in	in	ADP
afs-72028	71	17	contact	contact	NOUN
afs-72028	71	18	with	with	ADP
afs-72028	71	19	acid	acid	NOUN
afs-72028	71	20	soil	soil	NOUN
afs-72028	71	21	is	be	AUX
afs-72028	71	22	low	low	ADJ
afs-72028	71	23	,	,	PUNCT
afs-72028	71	24	because	because	SCONJ
afs-72028	71	25	the	the	DET
afs-72028	71	26	anion	anion	NOUN
afs-72028	71	27	ligand	ligand	NOUN
afs-72028	71	28	tends	tend	VERB
afs-72028	71	29	to	to	PART
afs-72028	71	30	be	be	AUX
afs-72028	71	31	strongly	strongly	ADV
afs-72028	71	32	bound	bind	VERB
afs-72028	71	33	to	to	ADP
afs-72028	71	34	both	both	PRON
afs-72028	72	1	al	al	PROPN
afs-72028	72	2	3	3	PROPN
afs-72028	72	3	+	+	CCONJ
afs-72028	72	4	(	(	PUNCT
afs-72028	72	5	fe3	fe3	NOUN
afs-72028	72	6	+	+	NUM
afs-72028	72	7	)	)	PUNCT
afs-72028	72	8	and	and	CCONJ
afs-72028	72	9	h+	h+	X
afs-72028	72	10	.	.	PUNCT
afs-72028	73	1	the	the	DET
afs-72028	73	2	anions	anion	NOUN
afs-72028	73	3	of	of	ADP
afs-72028	73	4	polyprotic	polyprotic	ADJ
afs-72028	73	5	acids	acid	NOUN
afs-72028	73	6	can	can	AUX
afs-72028	73	7	be	be	AUX
afs-72028	73	8	37	37	NUM
afs-72028	73	9	bound	bind	VERB
afs-72028	73	10	to	to	ADP
afs-72028	73	11	two	two	NUM
afs-72028	73	12	adjacent	adjacent	ADJ
afs-72028	73	13	central	central	ADJ
afs-72028	73	14	ions	ion	NOUN
afs-72028	73	15	on	on	ADP
afs-72028	73	16	the	the	DET
afs-72028	73	17	surface	surface	NOUN
afs-72028	73	18	of	of	ADP
afs-72028	73	19	the	the	DET
afs-72028	73	20	oxide	oxide	NOUN
afs-72028	73	21	pores	pore	NOUN
afs-72028	73	22	forming	form	VERB
afs-72028	73	23	a	a	DET
afs-72028	73	24	ring	ring	NOUN
afs-72028	73	25	structure	structure	NOUN
afs-72028	73	26	(	(	PUNCT
afs-72028	73	27	parfiti	parfiti	PROPN
afs-72028	73	28	et	et	PROPN
afs-72028	73	29	al	al	PROPN
afs-72028	73	30	.	.	PROPN
afs-72028	73	31	1975	1975	NUM
afs-72028	73	32	,	,	PUNCT
afs-72028	73	33	pareitt	pareitt	NOUN
afs-72028	73	34	and	and	CCONJ
afs-72028	73	35	smart	smart	ADJ
afs-72028	73	36	1978	1978	NUM
afs-72028	73	37	,	,	PUNCT
afs-72028	73	38	rajan	rajan	NOUN
afs-72028	73	39	1978	1978	NUM
afs-72028	73	40	)	)	PUNCT
afs-72028	73	41	.	.	PUNCT
afs-72028	74	1	this	this	DET
afs-72028	74	2	binuclear	binuclear	NOUN
afs-72028	74	3	bridging	bridging	NOUN
afs-72028	74	4	probably	probably	ADV
afs-72028	74	5	increases	increase	VERB
afs-72028	74	6	the	the	DET
afs-72028	74	7	stability	stability	NOUN
afs-72028	74	8	of	of	ADP
afs-72028	74	9	the	the	DET
afs-72028	74	10	coordination	coordination	NOUN
afs-72028	74	11	(	(	PUNCT
afs-72028	74	12	kingston	kingston	PROPN
afs-72028	74	13	et	et	PROPN
afs-72028	74	14	al	al	PROPN
afs-72028	74	15	.	.	PROPN
afs-72028	74	16	1974	1974	NUM
afs-72028	74	17	)	)	PUNCT
afs-72028	74	18	.	.	PUNCT
afs-72028	75	1	since	since	SCONJ
afs-72028	75	2	the	the	DET
afs-72028	75	3	polymeric	polymeric	ADJ
afs-72028	75	4	aland	aland	PROPN
afs-72028	75	5	fe	fe	PROPN
afs-72028	75	6	-	-	PUNCT
afs-72028	75	7	hydroxides	hydroxide	NOUN
afs-72028	75	8	probably	probably	ADV
afs-72028	75	9	contain	contain	VERB
afs-72028	75	10	plenty	plenty	NOUN
afs-72028	75	11	of	of	ADP
afs-72028	75	12	micropores	micropore	NOUN
afs-72028	75	13	then	then	ADV
afs-72028	75	14	the	the	DET
afs-72028	75	15	size	size	NOUN
afs-72028	75	16	of	of	ADP
afs-72028	75	17	the	the	DET
afs-72028	75	18	ligand	ligand	NOUN
afs-72028	75	19	will	will	AUX
afs-72028	75	20	effect	effect	VERB
afs-72028	75	21	the	the	DET
afs-72028	75	22	adsorption	adsorption	NOUN
afs-72028	75	23	of	of	ADP
afs-72028	75	24	the	the	DET
afs-72028	75	25	ligand	ligand	NOUN
afs-72028	75	26	to	to	ADP
afs-72028	75	27	the	the	DET
afs-72028	75	28	surfaces	surface	NOUN
afs-72028	75	29	of	of	ADP
afs-72028	75	30	the	the	DET
afs-72028	75	31	pores	pore	NOUN
afs-72028	75	32	.	.	PUNCT
afs-72028	76	1	the	the	DET
afs-72028	76	2	pka	pka	NOUN
afs-72028	76	3	-	-	PUNCT
afs-72028	76	4	value	value	NOUN
afs-72028	76	5	of	of	ADP
afs-72028	76	6	an	an	DET
afs-72028	76	7	acid	acid	NOUN
afs-72028	76	8	corresponding	corresponding	NOUN
afs-72028	76	9	to	to	ADP
afs-72028	76	10	the	the	DET
afs-72028	76	11	ligand	ligand	NOUN
afs-72028	76	12	reveals	reveal	VERB
afs-72028	76	13	something	something	PRON
afs-72028	76	14	about	about	ADP
afs-72028	76	15	the	the	DET
afs-72028	76	16	character	character	NOUN
afs-72028	76	17	of	of	ADP
afs-72028	76	18	the	the	DET
afs-72028	76	19	bond	bond	NOUN
afs-72028	76	20	between	between	ADP
afs-72028	76	21	the	the	DET
afs-72028	76	22	oxygen	oxygen	NOUN
afs-72028	76	23	and	and	CCONJ
afs-72028	76	24	the	the	DET
afs-72028	76	25	central	central	ADJ
afs-72028	76	26	ion	ion	NOUN
afs-72028	76	27	al	al	PROPN
afs-72028	76	28	3	3	NUM
afs-72028	76	29	+	+	NUM
afs-72028	76	30	or	or	CCONJ
afs-72028	76	31	fe	fe	X
afs-72028	76	32	3	3	NUM
afs-72028	76	33	+	+	NOUN
afs-72028	76	34	.	.	PUNCT
afs-72028	77	1	the	the	PRON
afs-72028	77	2	greater	great	ADJ
afs-72028	77	3	the	the	DET
afs-72028	77	4	nucleophilic	nucleophilic	ADJ
afs-72028	77	5	strength	strength	NOUN
afs-72028	77	6	of	of	ADP
afs-72028	77	7	the	the	DET
afs-72028	77	8	donor	donor	NOUN
afs-72028	77	9	,	,	PUNCT
afs-72028	77	10	the	the	DET
afs-72028	77	11	more	more	ADJ
afs-72028	77	12	covalent	covalent	ADJ
afs-72028	77	13	character	character	NOUN
afs-72028	77	14	of	of	ADP
afs-72028	77	15	the	the	DET
afs-72028	77	16	bond	bond	NOUN
afs-72028	77	17	.	.	PUNCT
afs-72028	78	1	the	the	DET
afs-72028	78	2	hydroxyl	hydroxyl	PROPN
afs-72028	78	3	oxygen	oxygen	NOUN
afs-72028	78	4	,	,	PUNCT
afs-72028	78	5	which	which	PRON
afs-72028	78	6	has	have	VERB
afs-72028	78	7	three	three	NUM
afs-72028	78	8	unshared	unshared	ADJ
afs-72028	78	9	electron	electron	NOUN
afs-72028	78	10	pairs	pair	NOUN
afs-72028	78	11	,	,	PUNCT
afs-72028	78	12	probably	probably	ADV
afs-72028	78	13	forms	form	VERB
afs-72028	78	14	both	both	CCONJ
afs-72028	78	15	aand	aand	PRON
afs-72028	78	16	7r	7r	NUM
afs-72028	78	17	-	-	PUNCT
afs-72028	78	18	bond	bond	NOUN
afs-72028	78	19	with	with	ADP
afs-72028	78	20	fe	fe	X
afs-72028	78	21	3	3	NUM
afs-72028	78	22	+	+	NUM
afs-72028	78	23	and	and	CCONJ
afs-72028	78	24	al	al	PROPN
afs-72028	78	25	3	3	NUM
afs-72028	78	26	+	+	PROPN
afs-72028	78	27	-ions	-ion	NOUN
afs-72028	78	28	(	(	PUNCT
afs-72028	78	29	baran	baran	NOUN
afs-72028	78	30	1971	1971	NUM
afs-72028	78	31	)	)	PUNCT
afs-72028	78	32	.	.	PUNCT
afs-72028	79	1	the	the	DET
afs-72028	79	2	changes	change	NOUN
afs-72028	79	3	of	of	ADP
afs-72028	79	4	standard	standard	ADJ
afs-72028	79	5	enthalpy	enthalpy	NOUN
afs-72028	79	6	and	and	CCONJ
afs-72028	79	7	entropy	entropy	NOUN
afs-72028	79	8	in	in	ADP
afs-72028	79	9	ligand	ligand	NOUN
afs-72028	79	10	exchange	exchange	VERB
afs-72028	79	11	the	the	DET
afs-72028	79	12	covalent	covalent	ADJ
afs-72028	79	13	character	character	NOUN
afs-72028	79	14	of	of	ADP
afs-72028	79	15	the	the	DET
afs-72028	79	16	strong	strong	ADJ
afs-72028	79	17	bond	bond	NOUN
afs-72028	79	18	between	between	ADP
afs-72028	79	19	the	the	DET
afs-72028	79	20	oxygen	oxygen	NOUN
afs-72028	79	21	ligand	ligand	NOUN
afs-72028	79	22	and	and	CCONJ
afs-72028	79	23	the	the	DET
afs-72028	79	24	central	central	ADJ
afs-72028	79	25	ion	ion	NOUN
afs-72028	79	26	does	do	AUX
afs-72028	79	27	not	not	PART
afs-72028	79	28	make	make	VERB
afs-72028	79	29	the	the	DET
afs-72028	79	30	adsorption	adsorption	NOUN
afs-72028	79	31	of	of	ADP
afs-72028	79	32	the	the	DET
afs-72028	79	33	ligand	ligand	NOUN
afs-72028	79	34	by	by	ADP
afs-72028	79	35	oxides	oxide	NOUN
afs-72028	79	36	an	an	DET
afs-72028	79	37	exothermic	exothermic	ADJ
afs-72028	79	38	reaction	reaction	NOUN
afs-72028	79	39	.	.	PUNCT
afs-72028	80	1	when	when	SCONJ
afs-72028	80	2	an	an	DET
afs-72028	80	3	anion	anion	NOUN
afs-72028	80	4	exchanges	exchange	NOUN
afs-72028	80	5	from	from	ADP
afs-72028	80	6	the	the	DET
afs-72028	80	7	surface	surface	NOUN
afs-72028	80	8	of	of	ADP
afs-72028	80	9	oxides	oxide	NOUN
afs-72028	80	10	e.	e.	PROPN
afs-72028	80	11	g.	g.	PROPN
afs-72028	80	12	a	a	DET
afs-72028	80	13	water	water	NOUN
afs-72028	80	14	molecule	molecule	NOUN
afs-72028	80	15	,	,	PUNCT
afs-72028	80	16	energy	energy	NOUN
afs-72028	80	17	is	be	AUX
afs-72028	80	18	consumed	consume	VERB
afs-72028	80	19	for	for	ADP
afs-72028	80	20	the	the	DET
afs-72028	80	21	detachment	detachment	NOUN
afs-72028	80	22	of	of	ADP
afs-72028	80	23	h	h	NOUN
afs-72028	80	24	2o	2o	NOUN
afs-72028	80	25	from	from	ADP
afs-72028	80	26	the	the	DET
afs-72028	80	27	central	central	ADJ
afs-72028	80	28	ion	ion	NOUN
afs-72028	80	29	and	and	CCONJ
afs-72028	80	30	also	also	ADV
afs-72028	80	31	for	for	ADP
afs-72028	80	32	the	the	DET
afs-72028	80	33	decresae	decresae	NOUN
afs-72028	80	34	of	of	ADP
afs-72028	80	35	the	the	DET
afs-72028	80	36	hydration	hydration	NOUN
afs-72028	80	37	number	number	NOUN
afs-72028	80	38	of	of	ADP
afs-72028	80	39	the	the	DET
afs-72028	80	40	anion	anion	NOUN
afs-72028	80	41	.	.	PUNCT
afs-72028	81	1	often	often	ADV
afs-72028	81	2	the	the	DET
afs-72028	81	3	change	change	NOUN
afs-72028	81	4	of	of	ADP
afs-72028	81	5	the	the	DET
afs-72028	81	6	standard	standard	ADJ
afs-72028	81	7	entropy	entropy	NOUN
afs-72028	81	8	primarily	primarily	ADV
afs-72028	81	9	determines	determine	VERB
afs-72028	81	10	the	the	DET
afs-72028	81	11	equilibrium	equilibrium	NOUN
afs-72028	81	12	of	of	ADP
afs-72028	81	13	the	the	DET
afs-72028	81	14	ligand	ligand	ADJ
afs-72028	81	15	exchange	exchange	NOUN
afs-72028	81	16	in	in	ADP
afs-72028	81	17	the	the	DET
afs-72028	81	18	soil	soil	NOUN
afs-72028	81	19	.	.	PUNCT
afs-72028	82	1	according	accord	VERB
afs-72028	82	2	to	to	ADP
afs-72028	82	3	the	the	DET
afs-72028	82	4	van’t	van’t	NUM
afs-72028	82	5	hoff	hoff	NOUN
afs-72028	82	6	equation	equation	NOUN
afs-72028	82	7	the	the	DET
afs-72028	82	8	equilibrium	equilibrium	NOUN
afs-72028	82	9	constant	constant	ADJ
afs-72028	82	10	k	k	PROPN
afs-72028	82	11	of	of	ADP
afs-72028	82	12	the	the	DET
afs-72028	82	13	chemical	chemical	NOUN
afs-72028	82	14	reaction	reaction	NOUN
afs-72028	82	15	is	be	AUX
afs-72028	82	16	dependent	dependent	ADJ
afs-72028	82	17	on	on	ADP
afs-72028	82	18	the	the	DET
afs-72028	82	19	temperature	temperature	NOUN
afs-72028	82	20	as	as	SCONJ
afs-72028	82	21	follows	follow	VERB
afs-72028	82	22	;	;	PUNCT
afs-72028	82	23	ah	ah	INTJ
afs-72028	82	24	0	0	NUM
afs-72028	82	25	1	1	NUM
afs-72028	82	26	in	in	ADP
afs-72028	82	27	k	k	PROPN
afs-72028	82	28	h	h	PROPN
afs-72028	82	29	oconstant	oconstant	ADJ
afs-72028	82	30	(	(	PUNCT
afs-72028	82	31	1	1	X
afs-72028	82	32	)	)	PUNCT
afs-72028	82	33	r	r	NOUN
afs-72028	82	34	t	t	NOUN
afs-72028	82	35	where	where	SCONJ
afs-72028	82	36	ah	ah	INTJ
afs-72028	82	37	°	°	NOUN
afs-72028	82	38	=	=	SYM
afs-72028	82	39	the	the	DET
afs-72028	82	40	change	change	NOUN
afs-72028	82	41	of	of	ADP
afs-72028	82	42	the	the	DET
afs-72028	82	43	standard	standard	ADJ
afs-72028	82	44	enthalpy	enthalpy	PROPN
afs-72028	82	45	j	j	PROPN
afs-72028	82	46	/	/	SYM
afs-72028	82	47	mol	mol	ADP
afs-72028	82	48	r	r	NOUN
afs-72028	82	49	=	=	PUNCT
afs-72028	82	50	the	the	DET
afs-72028	82	51	gas	gas	NOUN
afs-72028	82	52	constant	constant	VERB
afs-72028	82	53	8.314	8.314	NUM
afs-72028	82	54	j	j	PROPN
afs-72028	82	55	/	/	SYM
afs-72028	82	56	k	k	PROPN
afs-72028	82	57	mol	mol	ADP
afs-72028	82	58	t	t	PROPN
afs-72028	82	59	=	=	PUNCT
afs-72028	82	60	the	the	DET
afs-72028	82	61	absolute	absolute	ADJ
afs-72028	82	62	temperature	temperature	NOUN
afs-72028	82	63	k	k	PROPN
afs-72028	82	64	when	when	SCONJ
afs-72028	82	65	an	an	DET
afs-72028	82	66	anion	anion	NOUN
afs-72028	82	67	a~	a~	PROPN
afs-72028	82	68	exchanges	exchange	NOUN
afs-72028	82	69	with	with	ADP
afs-72028	82	70	the	the	DET
afs-72028	82	71	ligand	ligand	ADJ
afs-72028	82	72	water	water	NOUN
afs-72028	82	73	,	,	PUNCT
afs-72028	82	74	the	the	DET
afs-72028	82	75	equilibrium	equilibrium	NOUN
afs-72028	82	76	constant	constant	ADJ
afs-72028	82	77	k	k	PROPN
afs-72028	82	78	can	can	AUX
afs-72028	82	79	be	be	AUX
afs-72028	82	80	defined	define	VERB
afs-72028	82	81	as	as	SCONJ
afs-72028	82	82	follows	follow	VERB
afs-72028	82	83	:	:	PUNCT
afs-72028	82	84	ai	ai	VERB
afs-72028	82	85	+	+	NOUN
afs-72028	82	86	h	h	PROPN
afs-72028	82	87	2o	2o	PROPN
afs-72028	82	88	s	s	PART
afs-72028	82	89	>	>	X
afs-72028	82	90	a	a	X
afs-72028	82	91	;	;	PUNCT
afs-72028	82	92	+	+	CCONJ
afs-72028	82	93	(	(	PUNCT
afs-72028	82	94	2	2	X
afs-72028	82	95	)	)	PUNCT
afs-72028	82	96	y	y	NOUN
afs-72028	82	97	x	x	PUNCT
afs-72028	82	98	a	a	PRON
afs-72028	82	99	(	(	PUNCT
afs-72028	82	100	h	h	NOUN
afs-72028	82	101	2	2	NUM
afs-72028	82	102	0	0	NUM
afs-72028	82	103	1	1	NUM
afs-72028	82	104	)	)	PUNCT
afs-72028	82	105	x	x	X
afs-72028	82	106	a	a	DET
afs-72028	82	107	(	(	PUNCT
afs-72028	82	108	a	a	PRON
afs-72028	82	109	)	)	PUNCT
afs-72028	82	110	l	l	NOUN
afs-72028	82	111	xh	xh	PROPN
afs-72028	82	112	a0	a0	PROPN
afs-72028	82	113	(	(	PUNCT
afs-72028	82	114	a	a	DET
afs-72028	82	115	)	)	PUNCT
afs-72028	82	116	l	l	NOUN
afs-72028	82	117	xh	xh	PROPN
afs-72028	83	1	a	a	DET
afs-72028	83	2	0	0	NUM
afs-72028	83	3	(	(	PUNCT
afs-72028	83	4	3	3	NUM
afs-72028	83	5	)	)	PUNCT
afs-72028	83	6	where	where	SCONJ
afs-72028	83	7	(	(	PUNCT
afs-72028	83	8	a	a	X
afs-72028	83	9	)	)	PUNCT
afs-72028	83	10	j	j	NOUN
afs-72028	83	11	=	=	PUNCT
afs-72028	83	12	the	the	DET
afs-72028	83	13	activity	activity	NOUN
afs-72028	83	14	of	of	ADP
afs-72028	83	15	anion	anion	NOUN
afs-72028	83	16	a	a	PRON
afs-72028	83	17	*	*	PUNCT
afs-72028	83	18	in	in	ADP
afs-72028	83	19	the	the	DET
afs-72028	83	20	equilibrium	equilibrium	NOUN
afs-72028	83	21	solution	solution	NOUN
afs-72028	83	22	(	(	PUNCT
afs-72028	83	23	h	h	NOUN
afs-72028	83	24	20	20	NUM
afs-72028	83	25	)	)	PUNCT
afs-72028	83	26	!	!	PUNCT
afs-72028	84	1	=	=	PRON
afs-72028	85	1	the	the	DET
afs-72028	85	2	activity	activity	NOUN
afs-72028	85	3	of	of	ADP
afs-72028	85	4	water	water	NOUN
afs-72028	85	5	in	in	ADP
afs-72028	85	6	solution	solution	NOUN
afs-72028	85	7	«	«	PUNCT
afs-72028	85	8	s	s	PROPN
afs-72028	85	9	1	1	NUM
afs-72028	85	10	xa	xa	NOUN
afs-72028	85	11	=	=	NOUN
afs-72028	85	12	the	the	DET
afs-72028	85	13	mole	mole	NOUN
afs-72028	85	14	fraction	fraction	NOUN
afs-72028	85	15	of	of	ADP
afs-72028	85	16	a	a	PRON
afs-72028	85	17	”	"	PUNCT
afs-72028	85	18	on	on	ADP
afs-72028	85	19	the	the	DET
afs-72028	85	20	surface	surface	NOUN
afs-72028	85	21	of	of	ADP
afs-72028	85	22	oxides	oxide	NOUN
afs-72028	85	23	.	.	PUNCT
afs-72028	86	1	the	the	DET
afs-72028	86	2	activity	activity	NOUN
afs-72028	86	3	coefficient	coefficient	NOUN
afs-72028	86	4	of	of	ADP
afs-72028	86	5	a’has	a’ha	VERB
afs-72028	86	6	the	the	DET
afs-72028	86	7	value	value	NOUN
afs-72028	86	8	of	of	ADP
afs-72028	86	9	1	1	NUM
afs-72028	86	10	.	.	PUNCT
afs-72028	87	1	xh	xh	PROPN
afs-72028	87	2	2	2	NUM
afs-72028	87	3	o	o	NOUN
afs-72028	87	4	=	=	PUNCT
afs-72028	88	1	the	the	DET
afs-72028	88	2	mole	mole	NOUN
afs-72028	88	3	fraction	fraction	NOUN
afs-72028	88	4	of	of	ADP
afs-72028	88	5	h	h	PROPN
afs-72028	88	6	a	a	DET
afs-72028	88	7	o	o	NOUN
afs-72028	88	8	on	on	ADP
afs-72028	88	9	the	the	DET
afs-72028	88	10	surface	surface	NOUN
afs-72028	88	11	of	of	ADP
afs-72028	88	12	oxides	oxide	NOUN
afs-72028	88	13	.	.	PUNCT
afs-72028	89	1	the	the	DET
afs-72028	89	2	activity	activity	NOUN
afs-72028	89	3	coefficient	coefficient	NOUN
afs-72028	89	4	of	of	ADP
afs-72028	89	5	h2o	h2o	PROPN
afs-72028	89	6	has	have	VERB
afs-72028	89	7	the	the	DET
afs-72028	89	8	value	value	NOUN
afs-72028	89	9	of	of	ADP
afs-72028	89	10	1	1	NUM
afs-72028	89	11	.	.	PUNCT
afs-72028	90	1	if	if	SCONJ
afs-72028	90	2	there	there	PRON
afs-72028	90	3	are	be	VERB
afs-72028	90	4	no	no	DET
afs-72028	90	5	other	other	ADJ
afs-72028	90	6	ligands	ligand	NOUN
afs-72028	90	7	than	than	ADP
afs-72028	90	8	a	a	PRON
afs-72028	90	9	and	and	CCONJ
afs-72028	90	10	hao	hao	PROPN
afs-72028	90	11	,	,	PUNCT
afs-72028	90	12	it	it	PRON
afs-72028	90	13	follows	follow	VERB
afs-72028	90	14	that	that	SCONJ
afs-72028	90	15	xhao	xhao	PROPN
afs-72028	91	1	=	=	SYM
afs-72028	91	2	1	1	NUM
afs-72028	91	3	xa	xa	X
afs-72028	91	4	.	.	PUNCT
afs-72028	92	1	combining	combine	VERB
afs-72028	92	2	this	this	PRON
afs-72028	92	3	with	with	ADP
afs-72028	92	4	the	the	DET
afs-72028	92	5	equation	equation	NOUN
afs-72028	92	6	(	(	PUNCT
afs-72028	92	7	3	3	X
afs-72028	92	8	)	)	PUNCT
afs-72028	92	9	we	we	PRON
afs-72028	92	10	get	get	VERB
afs-72028	92	11	the	the	DET
afs-72028	92	12	langmuir	langmuir	PROPN
afs-72028	92	13	adsorption	adsorption	NOUN
afs-72028	92	14	equation	equation	NOUN
afs-72028	92	15	for	for	ADP
afs-72028	92	16	the	the	DET
afs-72028	92	17	sorption	sorption	NOUN
afs-72028	92	18	of	of	ADP
afs-72028	92	19	a	a	DET
afs-72028	92	20	"	"	PUNCT
afs-72028	92	21	:	:	PUNCT
afs-72028	92	22	v	v	NUM
afs-72028	92	23	k	k	PROPN
afs-72028	92	24	(	(	PUNCT
afs-72028	92	25	a')lx	a')lx	NOUN
afs-72028	92	26	a	a	DET
afs-72028	92	27	(	(	PUNCT
afs-72028	92	28	4	4	NUM
afs-72028	92	29	)	)	SYM
afs-72028	92	30	1	1	NUM
afs-72028	93	1	+	+	CCONJ
afs-72028	93	2	k	k	X
afs-72028	93	3	(	(	PUNCT
afs-72028	93	4	a	a	X
afs-72028	93	5	)	)	PUNCT
afs-72028	93	6	4	4	NUM
afs-72028	93	7	the	the	DET
afs-72028	93	8	coefficient	coefficient	NOUN
afs-72028	93	9	k	k	PROPN
afs-72028	93	10	is	be	AUX
afs-72028	93	11	constant	constant	ADJ
afs-72028	93	12	only	only	ADV
afs-72028	93	13	if	if	SCONJ
afs-72028	93	14	all	all	DET
afs-72028	93	15	the	the	DET
afs-72028	93	16	adsorption	adsorption	NOUN
afs-72028	93	17	sites	site	NOUN
afs-72028	93	18	have	have	VERB
afs-72028	93	19	the	the	DET
afs-72028	93	20	same	same	ADJ
afs-72028	93	21	standard	standard	ADJ
afs-72028	93	22	free	free	ADJ
afs-72028	93	23	energy	energy	NOUN
afs-72028	93	24	of	of	ADP
afs-72028	93	25	adsorption	adsorption	NOUN
afs-72028	93	26	.	.	PUNCT
afs-72028	94	1	in	in	ADP
afs-72028	94	2	reality	reality	NOUN
afs-72028	94	3	k	k	NOUN
afs-72028	94	4	is	be	AUX
afs-72028	94	5	not	not	PART
afs-72028	94	6	constant	constant	ADJ
afs-72028	94	7	.	.	PUNCT
afs-72028	95	1	the	the	DET
afs-72028	95	2	applicability	applicability	NOUN
afs-72028	95	3	of	of	ADP
afs-72028	95	4	the	the	DET
afs-72028	95	5	langmuir	langmuir	PROPN
afs-72028	95	6	equation	equation	NOUN
afs-72028	95	7	can	can	AUX
afs-72028	95	8	be	be	AUX
afs-72028	95	9	improved	improve	VERB
afs-72028	95	10	using	use	VERB
afs-72028	95	11	the	the	DET
afs-72028	95	12	equation	equation	NOUN
afs-72028	95	13	of	of	ADP
afs-72028	95	14	the	the	DET
afs-72028	95	15	two	two	NUM
afs-72028	95	16	adsorption	adsorption	NOUN
afs-72028	95	17	surfaces	surface	NOUN
afs-72028	95	18	(	(	PUNCT
afs-72028	95	19	syers	syer	NOUN
afs-72028	95	20	et	et	PROPN
afs-72028	95	21	al	al	PROPN
afs-72028	95	22	.	.	PROPN
afs-72028	95	23	1973	1973	NUM
afs-72028	95	24	)	)	PUNCT
afs-72028	95	25	.	.	PUNCT
afs-72028	96	1	for	for	ADP
afs-72028	96	2	simplicity	simplicity	NOUN
afs-72028	96	3	the	the	DET
afs-72028	96	4	conventional	conventional	ADJ
afs-72028	96	5	langmuir	langmuir	X
afs-72028	96	6	equation	equation	NOUN
afs-72028	96	7	is	be	AUX
afs-72028	96	8	used	use	VERB
afs-72028	96	9	in	in	ADP
afs-72028	96	10	this	this	DET
afs-72028	96	11	study	study	NOUN
afs-72028	96	12	.	.	PUNCT
afs-72028	97	1	hartikainen	hartikainen	PROPN
afs-72028	97	2	(	(	PUNCT
afs-72028	97	3	1979	1979	NUM
afs-72028	97	4	)	)	PUNCT
afs-72028	97	5	has	have	AUX
afs-72028	97	6	studied	study	VERB
afs-72028	97	7	with	with	ADP
afs-72028	97	8	several	several	ADJ
afs-72028	97	9	acid	acid	NOUN
afs-72028	97	10	soil	soil	NOUN
afs-72028	97	11	samples	sample	NOUN
afs-72028	97	12	,	,	PUNCT
afs-72028	97	13	how	how	SCONJ
afs-72028	97	14	the	the	DET
afs-72028	97	15	phosphate	phosphate	ADJ
afs-72028	97	16	concentration	concentration	NOUN
afs-72028	97	17	in	in	ADP
afs-72028	97	18	the	the	DET
afs-72028	97	19	equilibrium	equilibrium	NOUN
afs-72028	97	20	solution	solution	NOUN
afs-72028	97	21	in	in	ADP
afs-72028	97	22	contact	contact	NOUN
afs-72028	97	23	with	with	ADP
afs-72028	97	24	soil	soil	NOUN
afs-72028	97	25	depends	depend	VERB
afs-72028	97	26	on	on	ADP
afs-72028	97	27	the	the	DET
afs-72028	97	28	temperature	temperature	NOUN
afs-72028	97	29	.	.	PUNCT
afs-72028	98	1	this	this	PRON
afs-72028	98	2	had	have	VERB
afs-72028	98	3	no	no	DET
afs-72028	98	4	effect	effect	NOUN
afs-72028	98	5	on	on	ADP
afs-72028	98	6	the	the	DET
afs-72028	98	7	concentration	concentration	NOUN
afs-72028	98	8	or	or	CCONJ
afs-72028	98	9	the	the	DET
afs-72028	98	10	influence	influence	NOUN
afs-72028	98	11	was	be	AUX
afs-72028	98	12	slightly	slightly	ADV
afs-72028	98	13	positive	positive	ADJ
afs-72028	98	14	or	or	CCONJ
afs-72028	98	15	negative	negative	ADJ
afs-72028	98	16	.	.	PUNCT
afs-72028	99	1	the	the	DET
afs-72028	99	2	equation	equation	NOUN
afs-72028	99	3	(	(	PUNCT
afs-72028	99	4	1	1	X
afs-72028	99	5	)	)	PUNCT
afs-72028	99	6	shows	show	VERB
afs-72028	99	7	that	that	SCONJ
afs-72028	99	8	the	the	DET
afs-72028	99	9	change	change	NOUN
afs-72028	99	10	of	of	ADP
afs-72028	99	11	the	the	DET
afs-72028	99	12	standard	standard	ADJ
afs-72028	99	13	enthalpy	enthalpy	NOUN
afs-72028	99	14	in	in	ADP
afs-72028	99	15	the	the	DET
afs-72028	99	16	adsorption	adsorption	NOUN
afs-72028	99	17	of	of	ADP
afs-72028	99	18	phosphate	phosphate	NOUN
afs-72028	99	19	is	be	AUX
afs-72028	99	20	small	small	ADJ
afs-72028	99	21	.	.	PUNCT
afs-72028	100	1	since	since	SCONJ
afs-72028	100	2	ag	ag	PROPN
afs-72028	100	3	°	°	PROPN
afs-72028	100	4	=	=	PUNCT
afs-72028	100	5	-rt	-rt	NOUN
afs-72028	100	6	ink	ink	NOUN
afs-72028	100	7	(	(	PUNCT
afs-72028	100	8	5	5	NUM
afs-72028	100	9	)	)	PUNCT
afs-72028	100	10	(	(	PUNCT
afs-72028	100	11	6)ag0	6)ag0	NUM
afs-72028	100	12	=	=	PUNCT
afs-72028	100	13	ah0	ah0	NOUN
afs-72028	100	14	tas	ta	NOUN
afs-72028	100	15	°	°	PROPN
afs-72028	100	16	where	where	SCONJ
afs-72028	100	17	ag	ag	PROPN
afs-72028	100	18	°	°	PROPN
afs-72028	100	19	=	=	PRON
afs-72028	100	20	the	the	DET
afs-72028	100	21	change	change	NOUN
afs-72028	100	22	of	of	ADP
afs-72028	100	23	free	free	ADJ
afs-72028	100	24	energy	energy	PROPN
afs-72028	100	25	j	j	PROPN
afs-72028	100	26	/	/	SYM
afs-72028	100	27	mol	mol	PROPN
afs-72028	100	28	as	as	ADP
afs-72028	100	29	°	°	NOUN
afs-72028	100	30	=	=	SYM
afs-72028	100	31	the	the	DET
afs-72028	100	32	change	change	NOUN
afs-72028	100	33	of	of	ADP
afs-72028	100	34	entropy	entropy	PROPN
afs-72028	100	35	j	j	PROPN
afs-72028	100	36	/	/	SYM
afs-72028	100	37	mol	mol	ADP
afs-72028	100	38	k	k	PROPN
afs-72028	100	39	the	the	DET
afs-72028	100	40	entropy	entropy	NOUN
afs-72028	100	41	changes	change	NOUN
afs-72028	100	42	determine	determine	VERB
afs-72028	100	43	the	the	DET
afs-72028	100	44	equilibrium	equilibrium	NOUN
afs-72028	100	45	of	of	ADP
afs-72028	100	46	phosphate	phosphate	ADJ
afs-72028	100	47	adsorption	adsorption	NOUN
afs-72028	100	48	in	in	ADP
afs-72028	100	49	acid	acid	ADJ
afs-72028	100	50	soils	soil	NOUN
afs-72028	100	51	.	.	PUNCT
afs-72028	101	1	the	the	DET
afs-72028	101	2	phosphate	phosphate	ADJ
afs-72028	101	3	anion	anion	NOUN
afs-72028	101	4	in	in	ADP
afs-72028	101	5	solution	solution	NOUN
afs-72028	101	6	and	and	CCONJ
afs-72028	101	7	the	the	DET
afs-72028	101	8	central	central	ADJ
afs-72028	101	9	ion	ion	NOUN
afs-72028	101	10	on	on	ADP
afs-72028	101	11	the	the	DET
afs-72028	101	12	surface	surface	NOUN
afs-72028	101	13	of	of	ADP
afs-72028	101	14	al	al	PROPN
afs-72028	101	15	-	-	PUNCT
afs-72028	101	16	and	and	CCONJ
afs-72028	101	17	fe	fe	NOUN
afs-72028	101	18	-	-	PUNCT
afs-72028	101	19	oxides	oxide	NOUN
afs-72028	101	20	increase	increase	VERB
afs-72028	101	21	the	the	DET
afs-72028	101	22	order	order	NOUN
afs-72028	101	23	of	of	ADP
afs-72028	101	24	water	water	NOUN
afs-72028	101	25	molecules	molecule	NOUN
afs-72028	101	26	in	in	ADP
afs-72028	101	27	the	the	DET
afs-72028	101	28	solution	solution	NOUN
afs-72028	101	29	.	.	PUNCT
afs-72028	102	1	the	the	DET
afs-72028	102	2	attachment	attachment	NOUN
afs-72028	102	3	of	of	ADP
afs-72028	102	4	phosphate	phosphate	ADJ
afs-72028	102	5	oxygen	oxygen	NOUN
afs-72028	102	6	to	to	ADP
afs-72028	102	7	the	the	DET
afs-72028	102	8	al	al	PROPN
afs-72028	102	9	3	3	PROPN
afs-72028	102	10	+	+	NUM
afs-72028	102	11	or	or	CCONJ
afs-72028	102	12	fe	fe	X
afs-72028	102	13	3	3	NUM
afs-72028	102	14	+	+	NUM
afs-72028	102	15	neutralize	neutralize	VERB
afs-72028	102	16	the	the	DET
afs-72028	102	17	charges	charge	NOUN
afs-72028	102	18	of	of	ADP
afs-72028	102	19	these	these	DET
afs-72028	102	20	ions	ion	NOUN
afs-72028	102	21	,	,	PUNCT
afs-72028	102	22	which	which	PRON
afs-72028	102	23	increases	increase	VERB
afs-72028	102	24	the	the	DET
afs-72028	102	25	disorder	disorder	NOUN
afs-72028	102	26	of	of	ADP
afs-72028	102	27	water	water	NOUN
afs-72028	102	28	molecules	molecule	NOUN
afs-72028	102	29	in	in	ADP
afs-72028	102	30	the	the	DET
afs-72028	102	31	solution	solution	NOUN
afs-72028	102	32	.	.	PUNCT
afs-72028	103	1	biggar	biggar	PROPN
afs-72028	103	2	and	and	CCONJ
afs-72028	103	3	fireman	fireman	NOUN
afs-72028	103	4	(	(	PUNCT
afs-72028	103	5	1960	1960	NUM
afs-72028	103	6	)	)	PUNCT
afs-72028	103	7	have	have	AUX
afs-72028	103	8	stated	state	VERB
afs-72028	103	9	that	that	SCONJ
afs-72028	103	10	the	the	DET
afs-72028	103	11	adsorption	adsorption	NOUN
afs-72028	103	12	of	of	ADP
afs-72028	103	13	borate	borate	NOUN
afs-72028	103	14	to	to	ADP
afs-72028	103	15	soil	soil	NOUN
afs-72028	103	16	becomes	become	VERB
afs-72028	103	17	slightly	slightly	ADV
afs-72028	103	18	weaker	weak	ADJ
afs-72028	103	19	,	,	PUNCT
afs-72028	103	20	when	when	SCONJ
afs-72028	103	21	the	the	DET
afs-72028	103	22	temperature	temperature	NOUN
afs-72028	103	23	rises	rise	VERB
afs-72028	103	24	.	.	PUNCT
afs-72028	104	1	in	in	ADP
afs-72028	104	2	the	the	DET
afs-72028	104	3	studies	study	NOUN
afs-72028	104	4	of	of	ADP
afs-72028	104	5	bingham	bingham	PROPN
afs-72028	104	6	et	et	PROPN
afs-72028	104	7	al	al	PROPN
afs-72028	104	8	.	.	PROPN
afs-72028	105	1	(	(	PUNCT
afs-72028	105	2	1971	1971	NUM
afs-72028	105	3	)	)	PUNCT
afs-72028	105	4	the	the	DET
afs-72028	105	5	effect	effect	NOUN
afs-72028	105	6	of	of	ADP
afs-72028	105	7	the	the	DET
afs-72028	105	8	temperature	temperature	NOUN
afs-72028	105	9	was	be	AUX
afs-72028	105	10	to	to	PART
afs-72028	105	11	bind	bind	VERB
afs-72028	105	12	borate	borate	NOUN
afs-72028	105	13	anions	anion	NOUN
afs-72028	105	14	more	more	ADV
afs-72028	105	15	strongly	strongly	ADV
afs-72028	105	16	,	,	PUNCT
afs-72028	105	17	which	which	PRON
afs-72028	105	18	shows	show	VERB
afs-72028	105	19	that	that	SCONJ
afs-72028	105	20	the	the	DET
afs-72028	105	21	reaction	reaction	NOUN
afs-72028	105	22	was	be	AUX
afs-72028	105	23	endothermic	endothermic	ADJ
afs-72028	105	24	.	.	PUNCT
afs-72028	106	1	kingston	kingston	PROPN
afs-72028	106	2	and	and	CCONJ
afs-72028	106	3	raupach	raupach	NOUN
afs-72028	106	4	(	(	PUNCT
afs-72028	106	5	1967	1967	NUM
afs-72028	106	6	)	)	PUNCT
afs-72028	106	7	have	have	AUX
afs-72028	106	8	studied	study	VERB
afs-72028	106	9	the	the	DET
afs-72028	106	10	sorption	sorption	NOUN
afs-72028	106	11	of	of	ADP
afs-72028	106	12	silicate	silicate	NOUN
afs-72028	106	13	to	to	ADP
afs-72028	106	14	the	the	DET
afs-72028	106	15	al	al	PROPN
afs-72028	106	16	-	-	PUNCT
afs-72028	106	17	hydroxy	hydroxy	PROPN
afs-72028	106	18	polymers	polymer	NOUN
afs-72028	106	19	and	and	CCONJ
afs-72028	106	20	found	find	VERB
afs-72028	106	21	that	that	DET
afs-72028	106	22	adsorption	adsorption	NOUN
afs-72028	106	23	of	of	ADP
afs-72028	106	24	first	first	ADJ
afs-72028	106	25	silicate	silicate	ADJ
afs-72028	106	26	layer	layer	NOUN
afs-72028	106	27	on	on	ADP
afs-72028	106	28	the	the	DET
afs-72028	106	29	surface	surface	NOUN
afs-72028	106	30	of	of	ADP
afs-72028	106	31	the	the	DET
afs-72028	106	32	oxides	oxide	NOUN
afs-72028	106	33	was	be	AUX
afs-72028	106	34	almost	almost	ADV
afs-72028	106	35	independent	independent	ADJ
afs-72028	106	36	of	of	ADP
afs-72028	106	37	the	the	DET
afs-72028	106	38	temperature	temperature	NOUN
afs-72028	106	39	.	.	PUNCT
afs-72028	107	1	the	the	DET
afs-72028	107	2	measurements	measurement	NOUN
afs-72028	107	3	of	of	ADP
afs-72028	107	4	reyes	reyes	PROPN
afs-72028	107	5	and	and	CCONJ
afs-72028	107	6	jurinak	jurinak	PROPN
afs-72028	107	7	(	(	PUNCT
afs-72028	107	8	1967	1967	NUM
afs-72028	107	9	)	)	PUNCT
afs-72028	107	10	showed	show	VERB
afs-72028	107	11	no	no	DET
afs-72028	107	12	relationship	relationship	NOUN
afs-72028	107	13	between	between	ADP
afs-72028	107	14	the	the	DET
afs-72028	107	15	temperature	temperature	NOUN
afs-72028	107	16	and	and	CCONJ
afs-72028	107	17	adsorption	adsorption	NOUN
afs-72028	107	18	of	of	ADP
afs-72028	107	19	molybdate	molybdate	NOUN
afs-72028	107	20	by	by	ADP
afs-72028	107	21	hematite	hematite	NOUN
afs-72028	107	22	,	,	PUNCT
afs-72028	107	23	when	when	SCONJ
afs-72028	107	24	the	the	DET
afs-72028	107	25	concentration	concentration	NOUN
afs-72028	107	26	of	of	ADP
afs-72028	107	27	molybdate	molybdate	NOUN
afs-72028	107	28	was	be	AUX
afs-72028	107	29	not	not	PART
afs-72028	107	30	high	high	ADJ
afs-72028	107	31	in	in	ADP
afs-72028	107	32	the	the	DET
afs-72028	107	33	equilibrium	equilibrium	NOUN
afs-72028	107	34	solution	solution	NOUN
afs-72028	107	35	.	.	PUNCT
afs-72028	108	1	the	the	DET
afs-72028	108	2	nucleophilic	nucleophilic	ADJ
afs-72028	108	3	strength	strength	NOUN
afs-72028	108	4	of	of	ADP
afs-72028	108	5	ligand	ligand	ADJ
afs-72028	108	6	oxygen	oxygen	NOUN
afs-72028	108	7	is	be	AUX
afs-72028	108	8	closely	closely	ADV
afs-72028	108	9	related	relate	VERB
afs-72028	108	10	to	to	ADP
afs-72028	108	11	the	the	DET
afs-72028	108	12	amount	amount	NOUN
afs-72028	108	13	of	of	ADP
afs-72028	108	14	negative	negative	ADJ
afs-72028	108	15	charge	charge	NOUN
afs-72028	108	16	associated	associate	VERB
afs-72028	108	17	with	with	ADP
afs-72028	108	18	ligand	ligand	ADJ
afs-72028	108	19	oxygen	oxygen	NOUN
afs-72028	108	20	.	.	PUNCT
afs-72028	109	1	the	the	PRON
afs-72028	109	2	higher	high	ADJ
afs-72028	109	3	the	the	DET
afs-72028	109	4	pka	pka	NOUN
afs-72028	109	5	-	-	PUNCT
afs-72028	109	6	value	value	NOUN
afs-72028	109	7	of	of	ADP
afs-72028	109	8	the	the	DET
afs-72028	109	9	acid	acid	NOUN
afs-72028	109	10	corresponding	corresponding	NOUN
afs-72028	109	11	to	to	ADP
afs-72028	109	12	the	the	DET
afs-72028	109	13	anion	anion	NOUN
afs-72028	109	14	ligand	ligand	NOUN
afs-72028	109	15	is	be	AUX
afs-72028	109	16	,	,	PUNCT
afs-72028	109	17	the	the	PRON
afs-72028	109	18	more	more	ADV
afs-72028	109	19	the	the	DET
afs-72028	109	20	charge	charge	NOUN
afs-72028	109	21	is	be	AUX
afs-72028	109	22	concentrated	concentrate	VERB
afs-72028	109	23	on	on	ADP
afs-72028	109	24	the	the	DET
afs-72028	109	25	ligand	ligand	ADJ
afs-72028	109	26	oxygen	oxygen	NOUN
afs-72028	109	27	and	and	CCONJ
afs-72028	109	28	the	the	PRON
afs-72028	109	29	more	more	ADV
afs-72028	109	30	effectively	effectively	ADV
afs-72028	109	31	the	the	DET
afs-72028	109	32	ligand	ligand	ADJ
afs-72028	109	33	oxygen	oxygen	NOUN
afs-72028	109	34	increases	increase	VERB
afs-72028	109	35	the	the	DET
afs-72028	109	36	order	order	NOUN
afs-72028	109	37	of	of	ADP
afs-72028	109	38	water	water	NOUN
afs-72028	109	39	molecules	molecule	NOUN
afs-72028	109	40	in	in	ADP
afs-72028	109	41	the	the	DET
afs-72028	109	42	solution	solution	NOUN
afs-72028	109	43	(	(	PUNCT
afs-72028	109	44	e.	e.	PROPN
afs-72028	109	45	g.	g.	PROPN
afs-72028	109	46	fitz	fitz	PROPN
afs-72028	109	47	1975	1975	NUM
afs-72028	109	48	)	)	PUNCT
afs-72028	109	49	.	.	PUNCT
afs-72028	110	1	the	the	DET
afs-72028	110	2	entropies	entropy	NOUN
afs-72028	110	3	of	of	ADP
afs-72028	110	4	ligands	ligand	NOUN
afs-72028	110	5	in	in	ADP
afs-72028	110	6	water	water	NOUN
afs-72028	110	7	solution	solution	NOUN
afs-72028	110	8	are	be	AUX
afs-72028	110	9	given	give	VERB
afs-72028	110	10	in	in	ADP
afs-72028	110	11	table	table	NOUN
afs-72028	110	12	2	2	NUM
afs-72028	110	13	.	.	PUNCT
afs-72028	110	14	as	as	ADP
afs-72028	110	15	table	table	NOUN
afs-72028	110	16	2	2	NUM
afs-72028	110	17	shows	show	NOUN
afs-72028	110	18	,	,	PUNCT
afs-72028	110	19	the	the	DET
afs-72028	110	20	entropies	entropy	NOUN
afs-72028	110	21	of	of	ADP
afs-72028	110	22	the	the	DET
afs-72028	110	23	ligands	ligand	NOUN
afs-72028	110	24	are	be	AUX
afs-72028	110	25	in	in	ADP
afs-72028	110	26	a	a	DET
afs-72028	110	27	negative	negative	ADJ
afs-72028	110	28	correlation	correlation	NOUN
afs-72028	110	29	to	to	ADP
afs-72028	110	30	the	the	DET
afs-72028	110	31	pka	pka	NOUN
afs-72028	110	32	-	-	PUNCT
afs-72028	110	33	values	value	NOUN
afs-72028	110	34	of	of	ADP
afs-72028	110	35	the	the	DET
afs-72028	110	36	acids	acid	NOUN
afs-72028	110	37	.	.	PUNCT
afs-72028	111	1	the	the	DET
afs-72028	111	2	strong	strong	ADJ
afs-72028	111	3	adsorption	adsorption	NOUN
afs-72028	111	4	of	of	ADP
afs-72028	111	5	the	the	DET
afs-72028	111	6	anions	anion	NOUN
afs-72028	111	7	of	of	ADP
afs-72028	111	8	weak	weak	ADJ
afs-72028	111	9	acids	acid	NOUN
afs-72028	111	10	is	be	AUX
afs-72028	111	11	due	due	ADJ
afs-72028	111	12	to	to	ADP
afs-72028	111	13	the	the	DET
afs-72028	111	14	low	low	ADJ
afs-72028	111	15	entropy	entropy	NOUN
afs-72028	111	16	of	of	ADP
afs-72028	111	17	these	these	DET
afs-72028	111	18	anions	anion	NOUN
afs-72028	111	19	in	in	ADP
afs-72028	111	20	the	the	DET
afs-72028	111	21	water	water	NOUN
afs-72028	111	22	solution	solution	NOUN
afs-72028	111	23	.	.	PUNCT
afs-72028	112	1	table	table	NOUN
afs-72028	112	2	2	2	NUM
afs-72028	112	3	.	.	PUNCT
afs-72028	113	1	the	the	DET
afs-72028	113	2	entropies	entropy	NOUN
afs-72028	113	3	of	of	ADP
afs-72028	113	4	ligands	ligand	NOUN
afs-72028	113	5	in	in	ADP
afs-72028	113	6	water	water	NOUN
afs-72028	113	7	solution	solution	NOUN
afs-72028	113	8	j	j	PROPN
afs-72028	113	9	/	/	SYM
afs-72028	113	10	mol	mol	PROPN
afs-72028	113	11	k.	k.	PROPN
afs-72028	113	12	the	the	DET
afs-72028	113	13	entropy	entropy	PROPN
afs-72028	113	14	of	of	ADP
afs-72028	113	15	standard	standard	ADJ
afs-72028	113	16	ion	ion	NOUN
afs-72028	113	17	h+	h+	X
afs-72028	113	18	is	be	AUX
afs-72028	113	19	o	o	PROPN
afs-72028	113	20	(	(	PUNCT
afs-72028	113	21	rossini	rossini	X
afs-72028	113	22	et	et	PROPN
afs-72028	113	23	ai	ai	VERB
afs-72028	113	24	.	.	PROPN
afs-72028	113	25	1952	1952	NUM
afs-72028	113	26	)	)	PUNCT
afs-72028	113	27	.	.	PUNCT
afs-72028	114	1	h	h	NOUN
afs-72028	115	1	2	2	NUM
afs-72028	115	2	o	o	NOUN
afs-72028	115	3	70	70	NUM
afs-72028	115	4	noj	noj	NOUN
afs-72028	115	5	146	146	NUM
afs-72028	115	6	soi	soi	ADJ
afs-72028	115	7	17	17	NUM
afs-72028	115	8	hso~	hso~	NOUN
afs-72028	115	9	127	127	NUM
afs-72028	115	10	hpoi	hpoi	NOUN
afs-72028	115	11	-36	-36	PUNCT
afs-72028	115	12	oh	oh	INTJ
afs-72028	115	13	"	"	PUNCT
afs-72028	115	14	-10	-10	NUM
afs-72028	115	15	38	38	NUM
afs-72028	115	16	39	39	NUM
afs-72028	115	17	the	the	DET
afs-72028	115	18	adsorption	adsorption	NOUN
afs-72028	115	19	of	of	ADP
afs-72028	115	20	anion	anion	NOUN
afs-72028	115	21	and	and	CCONJ
afs-72028	115	22	ph	ph	PROPN
afs-72028	115	23	kingston	kingston	PROPN
afs-72028	115	24	et	et	PROPN
afs-72028	115	25	al	al	PROPN
afs-72028	115	26	.	.	PROPN
afs-72028	115	27	(	(	PUNCT
afs-72028	115	28	1968	1968	NUM
afs-72028	115	29	)	)	PUNCT
afs-72028	115	30	have	have	AUX
afs-72028	115	31	stated	state	VERB
afs-72028	115	32	that	that	SCONJ
afs-72028	115	33	the	the	DET
afs-72028	115	34	adsorption	adsorption	NOUN
afs-72028	115	35	of	of	ADP
afs-72028	115	36	many	many	ADJ
afs-72028	115	37	anions	anion	NOUN
afs-72028	115	38	to	to	ADP
afs-72028	115	39	aland	aland	PROPN
afs-72028	115	40	fe	fe	PROPN
afs-72028	115	41	-	-	PUNCT
afs-72028	115	42	oxides	oxide	NOUN
afs-72028	115	43	reaches	reach	VERB
afs-72028	115	44	a	a	DET
afs-72028	115	45	maximum	maximum	NOUN
afs-72028	115	46	where	where	SCONJ
afs-72028	115	47	the	the	DET
afs-72028	115	48	ph	ph	VERB
afs-72028	115	49	-	-	PUNCT
afs-72028	115	50	value	value	NOUN
afs-72028	115	51	is	be	AUX
afs-72028	115	52	of	of	ADP
afs-72028	115	53	the	the	DET
afs-72028	115	54	same	same	ADJ
afs-72028	115	55	order	order	NOUN
afs-72028	115	56	as	as	ADP
afs-72028	115	57	the	the	DET
afs-72028	115	58	pka	pka	NOUN
afs-72028	115	59	of	of	ADP
afs-72028	115	60	the	the	DET
afs-72028	115	61	corresponding	corresponding	ADJ
afs-72028	115	62	acid	acid	NOUN
afs-72028	115	63	.	.	PUNCT
afs-72028	116	1	this	this	DET
afs-72028	116	2	result	result	NOUN
afs-72028	116	3	is	be	AUX
afs-72028	116	4	easily	easily	ADV
afs-72028	116	5	explained	explain	VERB
afs-72028	116	6	by	by	ADP
afs-72028	116	7	the	the	DET
afs-72028	116	8	theory	theory	NOUN
afs-72028	116	9	presented	present	VERB
afs-72028	116	10	above	above	ADV
afs-72028	116	11	.	.	PUNCT
afs-72028	117	1	when	when	SCONJ
afs-72028	117	2	the	the	DET
afs-72028	117	3	ph	ph	NOUN
afs-72028	117	4	of	of	ADP
afs-72028	117	5	the	the	DET
afs-72028	117	6	equilibrium	equilibrium	NOUN
afs-72028	117	7	solution	solution	NOUN
afs-72028	117	8	is	be	AUX
afs-72028	117	9	much	much	ADV
afs-72028	117	10	below	below	ADP
afs-72028	117	11	the	the	DET
afs-72028	117	12	pka	pka	NOUN
afs-72028	117	13	-	-	PUNCT
afs-72028	117	14	value	value	NOUN
afs-72028	117	15	,	,	PUNCT
afs-72028	117	16	the	the	DET
afs-72028	117	17	concentration	concentration	NOUN
afs-72028	117	18	of	of	ADP
afs-72028	117	19	the	the	DET
afs-72028	117	20	anion	anion	NOUN
afs-72028	117	21	in	in	ADP
afs-72028	117	22	solution	solution	NOUN
afs-72028	117	23	is	be	AUX
afs-72028	117	24	low	low	ADJ
afs-72028	117	25	,	,	PUNCT
afs-72028	117	26	because	because	SCONJ
afs-72028	117	27	h	h	PROPN
afs-72028	117	28	+	+	CCONJ
afs-72028	117	29	competes	compete	VERB
afs-72028	117	30	with	with	ADP
afs-72028	117	31	al3	al3	PROPN
afs-72028	117	32	+	+	CCONJ
afs-72028	117	33	and	and	CCONJ
afs-72028	117	34	fe	fe	X
afs-72028	117	35	3	3	NUM
afs-72028	117	36	+	+	NUM
afs-72028	117	37	of	of	ADP
afs-72028	117	38	oxides	oxide	NOUN
afs-72028	117	39	for	for	ADP
afs-72028	117	40	anions	anion	NOUN
afs-72028	117	41	.	.	PUNCT
afs-72028	118	1	if	if	SCONJ
afs-72028	118	2	the	the	DET
afs-72028	118	3	ph	ph	NOUN
afs-72028	118	4	of	of	ADP
afs-72028	118	5	a	a	DET
afs-72028	118	6	solution	solution	NOUN
afs-72028	118	7	is	be	AUX
afs-72028	118	8	near	near	ADP
afs-72028	118	9	the	the	DET
afs-72028	118	10	pka	pka	NOUN
afs-72028	118	11	,	,	PUNCT
afs-72028	118	12	the	the	DET
afs-72028	118	13	rise	rise	NOUN
afs-72028	118	14	in	in	ADP
afs-72028	118	15	the	the	DET
afs-72028	118	16	ph	ph	NOUN
afs-72028	118	17	greatly	greatly	ADV
afs-72028	118	18	increases	increase	VERB
afs-72028	118	19	the	the	DET
afs-72028	118	20	degree	degree	NOUN
afs-72028	118	21	of	of	ADP
afs-72028	118	22	dissociation	dissociation	NOUN
afs-72028	118	23	of	of	ADP
afs-72028	118	24	the	the	DET
afs-72028	118	25	acid	acid	NOUN
afs-72028	118	26	.	.	PUNCT
afs-72028	119	1	when	when	SCONJ
afs-72028	119	2	the	the	DET
afs-72028	119	3	ph	ph	NOUN
afs-72028	119	4	becomes	become	VERB
afs-72028	119	5	higher	high	ADJ
afs-72028	119	6	than	than	ADP
afs-72028	119	7	the	the	DET
afs-72028	119	8	pka	pka	NOUN
afs-72028	119	9	-	-	PUNCT
afs-72028	119	10	value	value	NOUN
afs-72028	119	11	,	,	PUNCT
afs-72028	119	12	the	the	DET
afs-72028	119	13	degree	degree	NOUN
afs-72028	119	14	of	of	ADP
afs-72028	119	15	dissociation	dissociation	NOUN
afs-72028	119	16	becomes	become	VERB
afs-72028	119	17	near	near	ADP
afs-72028	119	18	1	1	NUM
afs-72028	119	19	and	and	CCONJ
afs-72028	119	20	can	can	AUX
afs-72028	119	21	change	change	VERB
afs-72028	119	22	only	only	ADV
afs-72028	119	23	slightly	slightly	ADV
afs-72028	119	24	.	.	PUNCT
afs-72028	120	1	on	on	ADP
afs-72028	120	2	the	the	DET
afs-72028	120	3	other	other	ADJ
afs-72028	120	4	hand	hand	NOUN
afs-72028	120	5	when	when	SCONJ
afs-72028	120	6	the	the	DET
afs-72028	120	7	concentration	concentration	NOUN
afs-72028	120	8	of	of	ADP
afs-72028	120	9	oh	oh	NUM
afs-72028	120	10	-	-	PUNCT
afs-72028	120	11	ions	ion	NOUN
afs-72028	120	12	in	in	ADP
afs-72028	120	13	a	a	DET
afs-72028	120	14	solution	solution	NOUN
afs-72028	120	15	rises	rise	NOUN
afs-72028	120	16	,	,	PUNCT
afs-72028	120	17	the	the	DET
afs-72028	120	18	adsorption	adsorption	NOUN
afs-72028	120	19	of	of	ADP
afs-72028	120	20	oh	oh	NOUN
afs-72028	120	21	-	-	PUNCT
afs-72028	120	22	groups	group	NOUN
afs-72028	120	23	is	be	AUX
afs-72028	120	24	increased	increase	VERB
afs-72028	120	25	,	,	PUNCT
afs-72028	120	26	but	but	CCONJ
afs-72028	120	27	the	the	DET
afs-72028	120	28	adsorption	adsorption	NOUN
afs-72028	120	29	of	of	ADP
afs-72028	120	30	other	other	ADJ
afs-72028	120	31	anions	anion	NOUN
afs-72028	120	32	is	be	AUX
afs-72028	120	33	decreased	decrease	VERB
afs-72028	120	34	.	.	PUNCT
afs-72028	121	1	the	the	DET
afs-72028	121	2	relationship	relationship	NOUN
afs-72028	121	3	between	between	ADP
afs-72028	121	4	the	the	DET
afs-72028	121	5	ph	ph	NOUN
afs-72028	121	6	and	and	CCONJ
afs-72028	121	7	the	the	DET
afs-72028	121	8	adsorption	adsorption	NOUN
afs-72028	121	9	of	of	ADP
afs-72028	121	10	anions	anion	NOUN
afs-72028	121	11	can	can	AUX
afs-72028	121	12	be	be	AUX
afs-72028	121	13	studied	study	VERB
afs-72028	121	14	as	as	SCONJ
afs-72028	121	15	follows	follow	VERB
afs-72028	121	16	:	:	PUNCT
afs-72028	121	17	x	x	PUNCT
afs-72028	121	18	a	a	X
afs-72028	121	19	=	=	X
afs-72028	121	20	the	the	DET
afs-72028	121	21	amount	amount	NOUN
afs-72028	121	22	of	of	ADP
afs-72028	121	23	adsorbed	adsorb	VERB
afs-72028	121	24	anions	anion	NOUN
afs-72028	121	25	mmol	mmol	NOUN
afs-72028	121	26	/	/	SYM
afs-72028	121	27	kg	kg	NOUN
afs-72028	121	28	of	of	ADP
afs-72028	121	29	soil	soil	NOUN
afs-72028	121	30	(	(	PUNCT
afs-72028	121	31	or	or	CCONJ
afs-72028	121	32	oxides	oxide	NOUN
afs-72028	121	33	)	)	PUNCT
afs-72028	121	34	x	x	X
afs-72028	122	1	=	=	PUNCT
afs-72028	122	2	the	the	DET
afs-72028	122	3	amount	amount	NOUN
afs-72028	122	4	of	of	ADP
afs-72028	122	5	water	water	NOUN
afs-72028	122	6	adsorbed	adsorb	VERB
afs-72028	122	7	mmol	mmol	NOUN
afs-72028	122	8	/	/	SYM
afs-72028	122	9	kgh	kgh	VERB
afs-72028	122	10	a	a	DET
afs-72028	122	11	o	o	X
afs-72028	122	12	c	c	NOUN
afs-72028	122	13	a	a	NOUN
afs-72028	122	14	=	=	X
afs-72028	122	15	the	the	DET
afs-72028	122	16	concentration	concentration	NOUN
afs-72028	122	17	of	of	ADP
afs-72028	122	18	anion	anion	NOUN
afs-72028	122	19	in	in	ADP
afs-72028	122	20	the	the	DET
afs-72028	122	21	solution	solution	NOUN
afs-72028	122	22	mmol/1	mmol/1	PROPN
afs-72028	122	23	x	x	NOUN
afs-72028	122	24	,	,	PUNCT
afs-72028	122	25	.	.	PUNCT
afs-72028	122	26	„	„	PUNCT
afs-72028	123	1	=	=	PUNCT
afs-72028	123	2	the	the	DET
afs-72028	123	3	amount	amount	NOUN
afs-72028	123	4	of	of	ADP
afs-72028	123	5	adsorbed	adsorbed	ADJ
afs-72028	123	6	oh	oh	NUM
afs-72028	123	7	mmol	mmol	NOUN
afs-72028	123	8	/	/	SYM
afs-72028	123	9	kg	kg	NOUN
afs-72028	123	10	oh	oh	INTJ
afs-72028	123	11	c	c	NOUN
afs-72028	123	12	=	=	PUNCT
afs-72028	123	13	the	the	DET
afs-72028	123	14	concentration	concentration	NOUN
afs-72028	123	15	of	of	ADP
afs-72028	123	16	oh	oh	INTJ
afs-72028	123	17	in	in	ADP
afs-72028	123	18	solution	solution	NOUN
afs-72028	123	19	mmol/1oh	mmol/1oh	X
afs-72028	123	20	c	c	NOUN
afs-72028	123	21	h	h	NOUN
afs-72028	123	22	=	=	PUNCT
afs-72028	123	23	the	the	DET
afs-72028	123	24	concentration	concentration	NOUN
afs-72028	123	25	of	of	ADP
afs-72028	123	26	hydrogen	hydrogen	NOUN
afs-72028	123	27	ion	ion	NOUN
afs-72028	123	28	in	in	ADP
afs-72028	123	29	solution	solution	NOUN
afs-72028	123	30	mmol/1	mmol/1	PROPN
afs-72028	123	31	cha	cha	NOUN
afs-72028	123	32	=	=	PUNCT
afs-72028	123	33	the	the	DET
afs-72028	123	34	concentration	concentration	NOUN
afs-72028	123	35	of	of	ADP
afs-72028	123	36	acid	acid	NOUN
afs-72028	123	37	corresponding	corresponding	NOUN
afs-72028	123	38	to	to	ADP
afs-72028	123	39	the	the	DET
afs-72028	123	40	ligand	ligand	NOUN
afs-72028	123	41	in	in	ADP
afs-72028	123	42	solution	solution	NOUN
afs-72028	123	43	mmol/1	mmol/1	PROPN
afs-72028	123	44	=	=	PUNCT
afs-72028	123	45	the	the	DET
afs-72028	123	46	fractional	fractional	ADJ
afs-72028	123	47	surface	surface	NOUN
afs-72028	123	48	coverage	coverage	NOUN
afs-72028	123	49	by	by	ADP
afs-72028	123	50	anion	anion	NOUN
afs-72028	123	51	ki	ki	PROPN
afs-72028	123	52	x	x	X
afs-72028	123	53	'	'	PART
afs-72028	123	54	•	•	NUM
afs-72028	123	55	x	x	NOUN
afs-72028	123	56	'	'	PUNCT
afs-72028	123	57	=	=	ADJ
afs-72028	123	58	k	k	NOUN
afs-72028	123	59	,	,	PUNCT
afs-72028	123	60	c	c	NOUN
afs-72028	123	61	x	x	NOUN
afs-72028	123	62	'	'	PUNCT
afs-72028	123	63	c	c	NOUN
afs-72028	123	64	x	x	NOUN
afs-72028	123	65	'	'	X
afs-72028	123	66	a	a	DET
afs-72028	123	67	1	1	NUM
afs-72028	123	68	a	a	DET
afs-72028	123	69	h2o	h2o	PROPN
afs-72028	123	70	a	a	DET
afs-72028	123	71	hjo	hjo	X
afs-72028	123	72	(	(	PUNCT
afs-72028	123	73	7	7	NUM
afs-72028	123	74	)	)	PUNCT
afs-72028	123	75	k	k	NOUN
afs-72028	123	76	2	2	NUM
afs-72028	123	77	—	—	PUNCT
afs-72028	123	78	—	—	PUNCT
afs-72028	123	79	-x	-x	NOUN
afs-72028	123	80	’	'	PUNCT
afs-72028	123	81	=	=	SYM
afs-72028	123	82	k	k	PROPN
afs-72028	123	83	c	c	NOUN
afs-72028	123	84	x	x	X
afs-72028	123	85	'	'	PUNCT
afs-72028	123	86	c	c	NOUN
afs-72028	123	87	x	x	SYM
afs-72028	124	1	oh	oh	INTJ
afs-72028	124	2	2	2	NUM
afs-72028	125	1	oh	oh	NUM
afs-72028	125	2	h	h	NOUN
afs-72028	125	3	,	,	PUNCT
afs-72028	125	4	o	o	NOUN
afs-72028	126	1	oh	oh	INTJ
afs-72028	126	2	h	h	NOUN
afs-72028	127	1	a	a	DET
afs-72028	127	2	o	o	X
afs-72028	127	3	(	(	PUNCT
afs-72028	127	4	8)	8)	NUM
afs-72028	127	5	the	the	DET
afs-72028	127	6	constants	constant	NOUN
afs-72028	127	7	k	k	PROPN
afs-72028	127	8	!	!	PUNCT
afs-72028	128	1	and	and	CCONJ
afs-72028	128	2	k	k	PROPN
afs-72028	128	3	2	2	NUM
afs-72028	128	4	show	show	VERB
afs-72028	128	5	the	the	DET
afs-72028	128	6	equilibrium	equilibrium	NOUN
afs-72028	128	7	of	of	ADP
afs-72028	128	8	exchange	exchange	NOUN
afs-72028	128	9	of	of	ADP
afs-72028	128	10	anion	anion	NOUN
afs-72028	128	11	and	and	CCONJ
afs-72028	128	12	oh	oh	INTJ
afs-72028	128	13	with	with	ADP
afs-72028	128	14	the	the	DET
afs-72028	128	15	coordination	coordination	NOUN
afs-72028	128	16	water	water	NOUN
afs-72028	128	17	.	.	PUNCT
afs-72028	129	1	theoretically	theoretically	ADV
afs-72028	129	2	the	the	DET
afs-72028	129	3	values	value	NOUN
afs-72028	129	4	of	of	ADP
afs-72028	129	5	k	k	PROPN
afs-72028	129	6	x	x	X
afs-72028	129	7	and	and	CCONJ
afs-72028	129	8	k	k	PROPN
afs-72028	129	9	2	2	NUM
afs-72028	129	10	can	can	AUX
afs-72028	129	11	be	be	AUX
afs-72028	129	12	determined	determine	VERB
afs-72028	129	13	using	use	VERB
afs-72028	129	14	the	the	DET
afs-72028	129	15	langmuir	langmuir	PROPN
afs-72028	129	16	equation	equation	NOUN
afs-72028	129	17	.	.	PUNCT
afs-72028	130	1	however	however	ADV
afs-72028	130	2	,	,	PUNCT
afs-72028	130	3	it	it	PRON
afs-72028	130	4	is	be	AUX
afs-72028	130	5	very	very	ADV
afs-72028	130	6	difficult	difficult	ADJ
afs-72028	130	7	to	to	PART
afs-72028	130	8	determine	determine	VERB
afs-72028	130	9	the	the	DET
afs-72028	130	10	amount	amount	NOUN
afs-72028	130	11	of	of	ADP
afs-72028	130	12	h	h	NOUN
afs-72028	130	13	2o	2o	NOUN
afs-72028	130	14	and	and	CCONJ
afs-72028	130	15	oh	oh	INTJ
afs-72028	130	16	adsorbed	adsorb	VERB
afs-72028	130	17	on	on	ADP
afs-72028	130	18	the	the	DET
afs-72028	130	19	surface	surface	NOUN
afs-72028	130	20	of	of	ADP
afs-72028	130	21	oxides	oxide	NOUN
afs-72028	130	22	.	.	PUNCT
afs-72028	131	1	the	the	DET
afs-72028	131	2	strong	strong	ADJ
afs-72028	131	3	nucleophilic	nucleophilic	ADJ
afs-72028	131	4	character	character	NOUN
afs-72028	131	5	of	of	ADP
afs-72028	131	6	oh	oh	INTJ
afs-72028	131	7	is	be	AUX
afs-72028	131	8	seen	see	VERB
afs-72028	131	9	e.	e.	PROPN
afs-72028	131	10	g.	g.	PROPN
afs-72028	131	11	from	from	ADP
afs-72028	131	12	the	the	DET
afs-72028	131	13	fact	fact	NOUN
afs-72028	131	14	that	that	SCONJ
afs-72028	131	15	the	the	DET
afs-72028	131	16	aland	aland	PROPN
afs-72028	131	17	fe	fe	PROPN
afs-72028	131	18	-	-	PUNCT
afs-72028	131	19	oxides	oxide	NOUN
afs-72028	131	20	do	do	AUX
afs-72028	131	21	not	not	PART
afs-72028	131	22	adsorb	adsorb	VERB
afs-72028	131	23	sulphate	sulphate	NOUN
afs-72028	131	24	,	,	PUNCT
afs-72028	131	25	when	when	SCONJ
afs-72028	131	26	the	the	DET
afs-72028	131	27	ph	ph	NOUN
afs-72028	131	28	is	be	AUX
afs-72028	131	29	above	above	ADP
afs-72028	131	30	the	the	DET
afs-72028	131	31	zero	zero	NUM
afs-72028	131	32	point	point	NOUN
afs-72028	131	33	of	of	ADP
afs-72028	131	34	charge	charge	NOUN
afs-72028	131	35	(	(	PUNCT
afs-72028	131	36	zpc	zpc	NOUN
afs-72028	131	37	)	)	PUNCT
afs-72028	131	38	,	,	PUNCT
afs-72028	131	39	which	which	PRON
afs-72028	131	40	for	for	ADP
afs-72028	131	41	oxides	oxide	NOUN
afs-72028	131	42	can	can	AUX
afs-72028	131	43	be	be	AUX
afs-72028	131	44	about	about	ADV
afs-72028	131	45	8	8	NUM
afs-72028	131	46	(	(	PUNCT
afs-72028	131	47	kingston	kingston	PROPN
afs-72028	131	48	et	et	PROPN
afs-72028	131	49	al	al	PROPN
afs-72028	131	50	.	.	PROPN
afs-72028	131	51	1972	1972	NUM
afs-72028	131	52	)	)	PUNCT
afs-72028	131	53	.	.	PUNCT
afs-72028	132	1	an	an	DET
afs-72028	132	2	approximate	approximate	ADJ
afs-72028	132	3	idea	idea	NOUN
afs-72028	132	4	of	of	ADP
afs-72028	132	5	the	the	DET
afs-72028	132	6	value	value	NOUN
afs-72028	132	7	of	of	ADP
afs-72028	132	8	k	k	NOUN
afs-72028	132	9	,	,	PUNCT
afs-72028	132	10	can	can	AUX
afs-72028	132	11	be	be	AUX
afs-72028	132	12	had	have	VERB
afs-72028	132	13	by	by	ADP
afs-72028	132	14	supposing	suppose	VERB
afs-72028	132	15	that	that	SCONJ
afs-72028	132	16	half	half	NOUN
afs-72028	132	17	of	of	ADP
afs-72028	132	18	the	the	DET
afs-72028	132	19	adsorption	adsorption	NOUN
afs-72028	132	20	sites	site	NOUN
afs-72028	132	21	of	of	ADP
afs-72028	132	22	h	h	PROPN
afs-72028	132	23	2o	2o	NOUN
afs-72028	132	24	are	be	AUX
afs-72028	132	25	occupied	occupy	VERB
afs-72028	132	26	by	by	ADP
afs-72028	132	27	oh	oh	INTJ
afs-72028	132	28	,	,	PUNCT
afs-72028	132	29	when	when	SCONJ
afs-72028	132	30	the	the	DET
afs-72028	132	31	ph	ph	NOUN
afs-72028	132	32	of	of	ADP
afs-72028	132	33	the	the	DET
afs-72028	132	34	solution	solution	NOUN
afs-72028	132	35	is	be	AUX
afs-72028	132	36	7	7	NUM
afs-72028	132	37	.	.	PUNCT
afs-72028	133	1	the	the	DET
afs-72028	133	2	concentration	concentration	NOUN
afs-72028	133	3	coh	coh	NOUN
afs-72028	133	4	is	be	AUX
afs-72028	133	5	in	in	ADP
afs-72028	133	6	this	this	DET
afs-72028	133	7	case	case	NOUN
afs-72028	134	1	10'4	10'4	NOUN
afs-72028	134	2	mmol/1	mmol/1	PROPN
afs-72028	134	3	and	and	CCONJ
afs-72028	134	4	ooh0	ooh0	PROPN
afs-72028	135	1	oh	oh	INTJ
afs-72028	135	2	has	have	VERB
afs-72028	135	3	a	a	DET
afs-72028	135	4	value	value	NOUN
afs-72028	135	5	of	of	ADP
afs-72028	135	6	0.5	0.5	NUM
afs-72028	135	7	.	.	PUNCT
afs-72028	136	1	k	k	PROPN
afs-72028	136	2	2	2	NUM
afs-72028	136	3	cohooh	cohooh	NOUN
afs-72028	136	4	=	=	NOUN
afs-72028	136	5	1	1	X
afs-72028	136	6	.	.	PUNCT
afs-72028	137	1	k	k	PROPN
afs-72028	137	2	r1	r1	PROPN
afs-72028	137	3	+	+	CCONJ
afs-72028	137	4	k	k	PROPN
afs-72028	137	5	2	2	NUM
afs-72028	137	6	'	'	NUM
afs-72028	137	7	-'oh	-'oh	PRON
afs-72028	137	8	■	■	NOUN
afs-72028	137	9	>	>	PROPN
afs-72028	137	10	■	■	PUNCT
afs-72028	137	11	k	k	ADJ
afs-72028	137	12	2	2	X
afs-72028	137	13	=	=	SYM
afs-72028	137	14	101	101	NUM
afs-72028	137	15	1	1	NUM
afs-72028	137	16	/	/	SYM
afs-72028	137	17	mmol	mmol	NOUN
afs-72028	137	18	if	if	SCONJ
afs-72028	137	19	h2o	h2o	NOUN
afs-72028	137	20	,	,	PUNCT
afs-72028	137	21	a	a	PRON
afs-72028	137	22	’	'	PUNCT
afs-72028	137	23	an	an	DET
afs-72028	137	24	oh	oh	NOUN
afs-72028	137	25	are	be	AUX
afs-72028	137	26	the	the	DET
afs-72028	137	27	only	only	ADJ
afs-72028	137	28	adsorbing	adsorb	VERB
afs-72028	137	29	ligands	ligand	NOUN
afs-72028	137	30	,	,	PUNCT
afs-72028	137	31	the	the	DET
afs-72028	137	32	number	number	NOUN
afs-72028	137	33	of	of	ADP
afs-72028	137	34	adsorption	adsorption	NOUN
afs-72028	137	35	sites	site	NOUN
afs-72028	137	36	in	in	ADP
afs-72028	137	37	the	the	DET
afs-72028	137	38	soil	soil	NOUN
afs-72028	137	39	(	(	PUNCT
afs-72028	137	40	oxides	oxide	NOUN
afs-72028	137	41	)	)	PUNCT
afs-72028	137	42	according	accord	VERB
afs-72028	137	43	to	to	ADP
afs-72028	137	44	equations	equation	NOUN
afs-72028	137	45	(	(	PUNCT
afs-72028	137	46	7	7	NUM
afs-72028	137	47	)	)	PUNCT
afs-72028	137	48	and	and	CCONJ
afs-72028	137	49	(	(	PUNCT
afs-72028	137	50	8)	8)	NUM
afs-72028	137	51	can	can	AUX
afs-72028	137	52	be	be	AUX
afs-72028	137	53	formulated	formulate	VERB
afs-72028	137	54	as	as	ADP
afs-72028	137	55	follows	follow	VERB
afs-72028	137	56	:	:	PUNCT
afs-72028	137	57	be	be	AUX
afs-72028	137	58	formulated	formulate	VERB
afs-72028	137	59	as	as	SCONJ
afs-72028	137	60	follows	follow	VERB
afs-72028	137	61	:	:	PUNCT
afs-72028	137	62	x	x	X
afs-72028	137	63	'	'	PUNCT
afs-72028	137	64	j.	j.	PROPN
afs-72028	137	65	k	k	PROPN
afs-72028	137	66	,	,	PUNCT
afs-72028	137	67	c	c	PROPN
afs-72028	137	68	x	x	X
afs-72028	137	69	'	'	PUNCT
afs-72028	137	70	+	+	ADJ
afs-72028	137	71	k	k	PROPN
afs-72028	137	72	,	,	PUNCT
afs-72028	137	73	cn	cn	PROPN
afs-72028	137	74	„	„	PROPN
afs-72028	137	75	x'hgo	x'hgo	PROPN
afs-72028	137	76	1	1	NUM
afs-72028	137	77	a	a	DET
afs-72028	137	78	h2o	h2o	PROPN
afs-72028	137	79	2	2	NUM
afs-72028	137	80	0h	0h	NUM
afs-72028	137	81	h	h	NOUN
afs-72028	137	82	2	2	NUM
afs-72028	137	83	o	o	NOUN
afs-72028	137	84	(	(	PUNCT
afs-72028	137	85	9	9	NUM
afs-72028	137	86	)	)	PUNCT
afs-72028	137	87	the	the	PRON
afs-72028	137	88	combining	combine	VERB
afs-72028	137	89	the	the	DET
afs-72028	137	90	equations	equation	NOUN
afs-72028	137	91	(	(	PUNCT
afs-72028	137	92	7	7	NUM
afs-72028	137	93	)	)	PUNCT
afs-72028	137	94	and	and	CCONJ
afs-72028	137	95	(	(	PUNCT
afs-72028	137	96	9	9	X
afs-72028	137	97	)	)	PUNCT
afs-72028	137	98	c	c	NOUN
afs-72028	137	99	an	an	DET
afs-72028	137	100	_	_	NOUN
afs-72028	137	101	1	1	NUM
afs-72028	137	102	a"a	a"a	NOUN
afs-72028	137	103	=	=	SYM
afs-72028	137	104	1	1	NUM
afs-72028	138	1	+	+	CCONJ
afs-72028	138	2	kj	kj	PROPN
afs-72028	138	3	c	c	PROPN
afs-72028	138	4	a	a	PROPN
afs-72028	138	5	+	+	X
afs-72028	138	6	k	k	SYM
afs-72028	138	7	2	2	NUM
afs-72028	138	8	c0h	c0h	X
afs-72028	138	9	(	(	PUNCT
afs-72028	138	10	10	10	NUM
afs-72028	138	11	)	)	PUNCT
afs-72028	138	12	let	let	VERB
afs-72028	138	13	ka	ka	PROPN
afs-72028	138	14	be	be	AUX
afs-72028	138	15	the	the	DET
afs-72028	138	16	acid	acid	NOUN
afs-72028	138	17	constant	constant	ADJ
afs-72028	138	18	corresponding	corresponding	NOUN
afs-72028	138	19	to	to	ADP
afs-72028	138	20	the	the	DET
afs-72028	138	21	anion	anion	NOUN
afs-72028	138	22	:	:	PUNCT
afs-72028	138	23	ha	ha	INTJ
afs-72028	138	24	>	>	X
afs-72028	138	25	h+	h+	PROPN
afs-72028	139	1	+	+	CCONJ
afs-72028	139	2	a	a	DET
afs-72028	139	3	ch/1000	ch/1000	NOUN
afs-72028	139	4	c	c	NOUN
afs-72028	139	5	a/1000ka	a/1000ka	NOUN
afs-72028	139	6	=	=	SYM
afs-72028	139	7	cha/1000	cha/1000	NOUN
afs-72028	139	8	(	(	PUNCT
afs-72028	139	9	11	11	NUM
afs-72028	139	10	)	)	PUNCT
afs-72028	139	11	g	g	NOUN
afs-72028	139	12	=	=	SYM
afs-72028	139	13	cra	cra	PROPN
afs-72028	139	14	“	"	PUNCT
afs-72028	139	15	h	h	NOUN
afs-72028	139	16	rnrnol/1	rnrnol/1	ADV
afs-72028	139	17	1000	1000	NUM
afs-72028	139	18	ka	ka	X
afs-72028	140	1	c	c	PROPN
afs-72028	140	2	c	c	PROPN
afs-72028	140	3	a	a	PRON
afs-72028	140	4	1000	1000	NUM
afs-72028	140	5	ka	ka	NOUN
afs-72028	140	6	+	+	CCONJ
afs-72028	140	7	ch	ch	PROPN
afs-72028	140	8	(	(	PUNCT
afs-72028	140	9	12	12	NUM
afs-72028	140	10	)	)	PUNCT
afs-72028	140	11	the	the	DET
afs-72028	140	12	last	last	ADJ
afs-72028	140	13	equation	equation	NOUN
afs-72028	140	14	was	be	AUX
afs-72028	140	15	combined	combine	VERB
afs-72028	140	16	with	with	ADP
afs-72028	140	17	the	the	DET
afs-72028	140	18	equation	equation	NOUN
afs-72028	140	19	(	(	PUNCT
afs-72028	140	20	10	10	NUM
afs-72028	140	21	)	)	PUNCT
afs-72028	140	22	and	and	CCONJ
afs-72028	140	23	the	the	DET
afs-72028	140	24	curves	curve	NOUN
afs-72028	140	25	in	in	ADP
afs-72028	140	26	figure	figure	NOUN
afs-72028	140	27	1	1	NUM
afs-72028	140	28	were	be	AUX
afs-72028	140	29	calculated	calculate	VERB
afs-72028	140	30	using	use	VERB
afs-72028	140	31	the	the	DET
afs-72028	140	32	value	value	NOUN
afs-72028	140	33	104	104	NUM
afs-72028	140	34	for	for	ADP
afs-72028	140	35	the	the	DET
afs-72028	140	36	constant	constant	ADJ
afs-72028	140	37	k	k	PROPN
afs-72028	140	38	2	2	NUM
afs-72028	140	39	.	.	PUNCT
afs-72028	141	1	the	the	DET
afs-72028	141	2	curves	curve	NOUN
afs-72028	141	3	show	show	VERB
afs-72028	141	4	that	that	SCONJ
afs-72028	141	5	the	the	DET
afs-72028	141	6	maximum	maximum	ADJ
afs-72028	141	7	adsorption	adsorption	NOUN
afs-72028	141	8	of	of	ADP
afs-72028	141	9	the	the	DET
afs-72028	141	10	anions	anion	NOUN
afs-72028	141	11	is	be	AUX
afs-72028	141	12	near	near	ADP
afs-72028	141	13	the	the	DET
afs-72028	141	14	pka	pka	NOUN
afs-72028	141	15	-	-	PUNCT
afs-72028	141	16	value	value	NOUN
afs-72028	141	17	.	.	PUNCT
afs-72028	142	1	the	the	DET
afs-72028	142	2	rise	rise	NOUN
afs-72028	142	3	in	in	ADP
afs-72028	142	4	the	the	DET
afs-72028	142	5	ph	ph	NOUN
afs-72028	142	6	has	have	VERB
afs-72028	142	7	only	only	ADV
afs-72028	142	8	a	a	DET
afs-72028	142	9	negative	negative	ADJ
afs-72028	142	10	effect	effect	NOUN
afs-72028	142	11	on	on	ADP
afs-72028	142	12	the	the	DET
afs-72028	142	13	adsorption	adsorption	NOUN
afs-72028	142	14	of	of	ADP
afs-72028	142	15	the	the	DET
afs-72028	142	16	anion	anion	NOUN
afs-72028	142	17	,	,	PUNCT
afs-72028	142	18	whose	whose	DET
afs-72028	142	19	pka	pka	PROPN
afs-72028	142	20	is	be	AUX
afs-72028	142	21	small	small	ADJ
afs-72028	142	22	.	.	PUNCT
afs-72028	143	1	if	if	SCONJ
afs-72028	143	2	the	the	DET
afs-72028	143	3	pka	pka	PROPN
afs-72028	143	4	is	be	AUX
afs-72028	143	5	high	high	ADJ
afs-72028	143	6	,	,	PUNCT
afs-72028	143	7	then	then	ADV
afs-72028	143	8	adsorption	adsorption	NOUN
afs-72028	143	9	below	below	ADP
afs-72028	143	10	ph	ph	ADJ
afs-72028	143	11	7is	7is	PROPN
afs-72028	143	12	weak	weak	ADJ
afs-72028	143	13	.	.	PUNCT
afs-72028	144	1	silicate	silicate	PROPN
afs-72028	144	2	is	be	AUX
afs-72028	144	3	an	an	DET
afs-72028	144	4	anion	anion	NOUN
afs-72028	144	5	of	of	ADP
afs-72028	144	6	this	this	DET
afs-72028	144	7	kind	kind	NOUN
afs-72028	144	8	.	.	PUNCT
afs-72028	145	1	the	the	DET
afs-72028	145	2	maximum	maximum	ADJ
afs-72028	145	3	degree	degree	NOUN
afs-72028	145	4	of	of	ADP
afs-72028	145	5	adsorption	adsorption	NOUN
afs-72028	145	6	is	be	AUX
afs-72028	145	7	near	near	ADP
afs-72028	145	8	the	the	DET
afs-72028	145	9	pkavalue	pkavalue	NOUN
afs-72028	145	10	9.7	9.7	NUM
afs-72028	145	11	(	(	PUNCT
afs-72028	145	12	kingston	kingston	PROPN
afs-72028	145	13	et	et	PROPN
afs-72028	145	14	al	al	PROPN
afs-72028	145	15	.	.	PROPN
afs-72028	145	16	1968	1968	NUM
afs-72028	145	17	)	)	PUNCT
afs-72028	145	18	.	.	PUNCT
afs-72028	146	1	if	if	SCONJ
afs-72028	146	2	an	an	DET
afs-72028	146	3	anion	anion	NOUN
afs-72028	146	4	is	be	AUX
afs-72028	146	5	polyprotic	polyprotic	ADJ
afs-72028	146	6	like	like	ADP
afs-72028	146	7	for	for	ADP
afs-72028	146	8	example	example	NOUN
afs-72028	146	9	fig	fig	NOUN
afs-72028	146	10	.	.	PUNCT
afs-72028	147	1	1	1	X
afs-72028	147	2	.	.	X
afs-72028	147	3	adsorption	adsorption	NOUN
afs-72028	147	4	of	of	ADP
afs-72028	147	5	anions	anion	NOUN
afs-72028	147	6	onto	onto	ADP
afs-72028	147	7	oxides	oxide	NOUN
afs-72028	147	8	and	and	CCONJ
afs-72028	147	9	ph	ph	NOUN
afs-72028	147	10	of	of	ADP
afs-72028	147	11	equilibrium	equilibrium	NOUN
afs-72028	147	12	solution	solution	NOUN
afs-72028	147	13	.	.	PUNCT
afs-72028	148	1	the	the	DET
afs-72028	148	2	curves	curve	NOUN
afs-72028	148	3	are	be	AUX
afs-72028	148	4	calculated	calculate	VERB
afs-72028	148	5	using	use	VERB
afs-72028	148	6	the	the	DET
afs-72028	148	7	equation	equation	NOUN
afs-72028	148	8	(	(	PUNCT
afs-72028	148	9	10	10	NUM
afs-72028	148	10	)	)	PUNCT
afs-72028	148	11	.	.	PUNCT
afs-72028	149	1	40	40	NUM
afs-72028	149	2	41	41	NUM
afs-72028	149	3	phosphate	phosphate	NOUN
afs-72028	149	4	,	,	PUNCT
afs-72028	149	5	the	the	DET
afs-72028	149	6	decrease	decrease	NOUN
afs-72028	149	7	of	of	ADP
afs-72028	149	8	adsorption	adsorption	NOUN
afs-72028	149	9	with	with	ADP
afs-72028	149	10	the	the	DET
afs-72028	149	11	rise	rise	NOUN
afs-72028	149	12	in	in	ADP
afs-72028	149	13	the	the	DET
afs-72028	149	14	ph	ph	NOUN
afs-72028	149	15	is	be	AUX
afs-72028	149	16	less	less	ADJ
afs-72028	149	17	than	than	ADP
afs-72028	149	18	for	for	ADP
afs-72028	149	19	an	an	DET
afs-72028	149	20	anion	anion	NOUN
afs-72028	149	21	,	,	PUNCT
afs-72028	149	22	which	which	PRON
afs-72028	149	23	dissociates	dissociate	VERB
afs-72028	149	24	with	with	ADP
afs-72028	149	25	only	only	ADV
afs-72028	149	26	one	one	NUM
afs-72028	149	27	h+	h+	NOUN
afs-72028	149	28	.	.	PUNCT
afs-72028	150	1	the	the	DET
afs-72028	150	2	dissociation	dissociation	NOUN
afs-72028	150	3	of	of	ADP
afs-72028	150	4	more	more	ADJ
afs-72028	150	5	than	than	ADP
afs-72028	150	6	one	one	NUM
afs-72028	150	7	hydrogen	hydrogen	NOUN
afs-72028	150	8	ion	ion	NOUN
afs-72028	150	9	increases	increase	VERB
afs-72028	150	10	the	the	DET
afs-72028	150	11	nucleophilic	nucleophilic	ADJ
afs-72028	150	12	strength	strength	NOUN
afs-72028	150	13	of	of	ADP
afs-72028	150	14	the	the	DET
afs-72028	150	15	anion	anion	NOUN
afs-72028	150	16	.	.	PUNCT
afs-72028	151	1	when	when	SCONJ
afs-72028	151	2	the	the	DET
afs-72028	151	3	ph	ph	NOUN
afs-72028	151	4	rises	rise	NOUN
afs-72028	151	5	above	above	ADP
afs-72028	151	6	the	the	DET
afs-72028	151	7	last	last	ADJ
afs-72028	151	8	pka	pka	NOUN
afs-72028	151	9	-	-	PUNCT
afs-72028	151	10	value	value	NOUN
afs-72028	151	11	of	of	ADP
afs-72028	151	12	the	the	DET
afs-72028	151	13	polyprotic	polyprotic	ADJ
afs-72028	151	14	anion	anion	NOUN
afs-72028	151	15	,	,	PUNCT
afs-72028	151	16	the	the	DET
afs-72028	151	17	competing	compete	VERB
afs-72028	151	18	effect	effect	NOUN
afs-72028	151	19	of	of	ADP
afs-72028	151	20	oh	oh	INTJ
afs-72028	151	21	becomes	become	VERB
afs-72028	151	22	clearer	clear	ADJ
afs-72028	151	23	.	.	PUNCT
afs-72028	152	1	the	the	DET
afs-72028	152	2	adsorption	adsorption	NOUN
afs-72028	152	3	decreases	decrease	VERB
afs-72028	152	4	more	more	ADV
afs-72028	152	5	sharply	sharply	ADV
afs-72028	152	6	than	than	ADP
afs-72028	152	7	when	when	SCONJ
afs-72028	152	8	the	the	DET
afs-72028	152	9	ph	ph	NOUN
afs-72028	152	10	is	be	AUX
afs-72028	152	11	near	near	ADP
afs-72028	152	12	the	the	DET
afs-72028	152	13	other	other	ADJ
afs-72028	152	14	pka	pka	PROPN
afs-72028	152	15	-	-	PUNCT
afs-72028	152	16	values	value	NOUN
afs-72028	152	17	of	of	ADP
afs-72028	152	18	the	the	DET
afs-72028	152	19	polyprotic	polyprotic	ADJ
afs-72028	152	20	anion	anion	NOUN
afs-72028	152	21	as	as	SCONJ
afs-72028	152	22	shown	show	VERB
afs-72028	152	23	experimentally	experimentally	ADV
afs-72028	152	24	by	by	ADP
afs-72028	152	25	kingston	kingston	PROPN
afs-72028	152	26	et	et	PROPN
afs-72028	152	27	al	al	PROPN
afs-72028	152	28	.	.	PROPN
afs-72028	153	1	(	(	PUNCT
afs-72028	153	2	1968	1968	NUM
afs-72028	153	3	)	)	PUNCT
afs-72028	153	4	.	.	PUNCT
afs-72028	154	1	kinetics	kinetic	NOUN
afs-72028	154	2	of	of	ADP
afs-72028	154	3	ligand	ligand	PROPN
afs-72028	154	4	exchange	exchange	VERB
afs-72028	154	5	the	the	DET
afs-72028	154	6	rate	rate	NOUN
afs-72028	154	7	of	of	ADP
afs-72028	154	8	the	the	DET
afs-72028	154	9	ligand	ligand	NOUN
afs-72028	154	10	exchange	exchange	NOUN
afs-72028	154	11	also	also	ADV
afs-72028	154	12	depends	depend	VERB
afs-72028	154	13	on	on	ADP
afs-72028	154	14	the	the	DET
afs-72028	154	15	nucleophilic	nucleophilic	ADJ
afs-72028	154	16	strength	strength	NOUN
afs-72028	154	17	of	of	ADP
afs-72028	154	18	the	the	DET
afs-72028	154	19	ligand	ligand	ADJ
afs-72028	154	20	oxygen	oxygen	NOUN
afs-72028	154	21	.	.	PUNCT
afs-72028	155	1	the	the	DET
afs-72028	155	2	rate	rate	NOUN
afs-72028	155	3	of	of	ADP
afs-72028	155	4	the	the	DET
afs-72028	155	5	exchange	exchange	NOUN
afs-72028	155	6	of	of	ADP
afs-72028	155	7	ligand	ligand	NOUN
afs-72028	155	8	is	be	AUX
afs-72028	155	9	especially	especially	ADV
afs-72028	155	10	related	relate	VERB
afs-72028	155	11	to	to	ADP
afs-72028	155	12	the	the	DET
afs-72028	155	13	basicity	basicity	NOUN
afs-72028	155	14	of	of	ADP
afs-72028	155	15	the	the	DET
afs-72028	155	16	ligand	ligand	NOUN
afs-72028	155	17	,	,	PUNCT
afs-72028	155	18	if	if	SCONJ
afs-72028	155	19	the	the	DET
afs-72028	155	20	central	central	ADJ
afs-72028	155	21	ion	ion	NOUN
afs-72028	155	22	is	be	AUX
afs-72028	155	23	a	a	DET
afs-72028	155	24	hard	hard	ADJ
afs-72028	155	25	lewis	lewis	NOUN
afs-72028	155	26	acid	acid	PROPN
afs-72028	155	27	such	such	ADJ
afs-72028	155	28	as	as	ADP
afs-72028	155	29	al	al	PROPN
afs-72028	155	30	3	3	NUM
afs-72028	155	31	+	+	NUM
afs-72028	155	32	or	or	CCONJ
afs-72028	155	33	fe	fe	X
afs-72028	155	34	3	3	NUM
afs-72028	155	35	+	+	NUM
afs-72028	155	36	.	.	PUNCT
afs-72028	156	1	the	the	DET
afs-72028	156	2	high	high	PROPN
afs-72028	156	3	pka	pka	PROPN
afs-72028	156	4	shows	show	VERB
afs-72028	156	5	a	a	DET
afs-72028	156	6	high	high	ADJ
afs-72028	156	7	nucleophilic	nucleophilic	ADJ
afs-72028	156	8	reactivity	reactivity	NOUN
afs-72028	156	9	of	of	ADP
afs-72028	156	10	oxygen	oxygen	NOUN
afs-72028	156	11	(	(	PUNCT
afs-72028	156	12	edwards	edwards	PROPN
afs-72028	156	13	1956	1956	NUM
afs-72028	156	14	,	,	PUNCT
afs-72028	156	15	edwards	edwards	PROPN
afs-72028	156	16	and	and	CCONJ
afs-72028	156	17	pearson	pearson	PROPN
afs-72028	156	18	1962	1962	NUM
afs-72028	156	19	)	)	PUNCT
afs-72028	156	20	.	.	PUNCT
afs-72028	157	1	correspondingly	correspondingly	ADV
afs-72028	157	2	the	the	DET
afs-72028	157	3	detachment	detachment	NOUN
afs-72028	157	4	of	of	ADP
afs-72028	157	5	ligand	ligand	ADJ
afs-72028	157	6	oxygen	oxygen	NOUN
afs-72028	157	7	becomes	become	VERB
afs-72028	157	8	slower	slow	ADJ
afs-72028	157	9	,	,	PUNCT
afs-72028	157	10	when	when	SCONJ
afs-72028	157	11	the	the	DET
afs-72028	157	12	pka	pka	NOUN
afs-72028	157	13	-	-	PUNCT
afs-72028	157	14	value	value	NOUN
afs-72028	157	15	rises	rise	NOUN
afs-72028	157	16	.	.	PUNCT
afs-72028	158	1	the	the	DET
afs-72028	158	2	coordination	coordination	NOUN
afs-72028	158	3	water	water	NOUN
afs-72028	158	4	is	be	AUX
afs-72028	158	5	not	not	PART
afs-72028	158	6	tightly	tightly	ADV
afs-72028	158	7	bound	bind	VERB
afs-72028	158	8	by	by	ADP
afs-72028	158	9	the	the	DET
afs-72028	158	10	central	central	ADJ
afs-72028	158	11	ions	ion	NOUN
afs-72028	158	12	,	,	PUNCT
afs-72028	158	13	and	and	CCONJ
afs-72028	158	14	the	the	DET
afs-72028	158	15	exchange	exchange	NOUN
afs-72028	158	16	of	of	ADP
afs-72028	158	17	coordinated	coordinate	VERB
afs-72028	158	18	water	water	NOUN
afs-72028	158	19	occurs	occur	VERB
afs-72028	158	20	rapidly	rapidly	ADV
afs-72028	158	21	.	.	PUNCT
afs-72028	159	1	the	the	DET
afs-72028	159	2	first	first	ADJ
afs-72028	159	3	order	order	NOUN
afs-72028	159	4	rate	rate	NOUN
afs-72028	159	5	constant	constant	ADJ
afs-72028	159	6	for	for	ADP
afs-72028	159	7	the	the	DET
afs-72028	159	8	removal	removal	NOUN
afs-72028	159	9	of	of	ADP
afs-72028	159	10	water	water	NOUN
afs-72028	159	11	molecule	molecule	NOUN
afs-72028	159	12	from	from	ADP
afs-72028	159	13	the	the	DET
afs-72028	159	14	first	first	ADJ
afs-72028	159	15	coordination	coordination	NOUN
afs-72028	159	16	sphere	sphere	NOUN
afs-72028	159	17	of	of	ADP
afs-72028	159	18	fe	fe	X
afs-72028	159	19	3	3	NUM
afs-72028	159	20	+	+	NUM
afs-72028	159	21	is	be	AUX
afs-72028	159	22	about	about	ADV
afs-72028	159	23	104	104	NUM
afs-72028	159	24	s	s	NUM
afs-72028	159	25	°	°	NOUN
afs-72028	159	26	(	(	PUNCT
afs-72028	159	27	connick	connick	NOUN
afs-72028	159	28	and	and	CCONJ
afs-72028	159	29	stover	stover	NOUN
afs-72028	159	30	1961	1961	NUM
afs-72028	159	31	)	)	PUNCT
afs-72028	159	32	.	.	PUNCT
afs-72028	160	1	the	the	DET
afs-72028	160	2	difference	difference	NOUN
afs-72028	160	3	between	between	ADP
afs-72028	160	4	the	the	DET
afs-72028	160	5	rates	rate	NOUN
afs-72028	160	6	of	of	ADP
afs-72028	160	7	adsorption	adsorption	NOUN
afs-72028	160	8	and	and	CCONJ
afs-72028	160	9	desorption	desorption	NOUN
afs-72028	160	10	is	be	AUX
afs-72028	160	11	distinct	distinct	ADJ
afs-72028	160	12	in	in	ADP
afs-72028	160	13	the	the	DET
afs-72028	160	14	sorption	sorption	NOUN
afs-72028	160	15	of	of	ADP
afs-72028	160	16	an	an	DET
afs-72028	160	17	anion	anion	NOUN
afs-72028	160	18	,	,	PUNCT
afs-72028	160	19	which	which	PRON
afs-72028	160	20	is	be	AUX
afs-72028	160	21	tightly	tightly	ADV
afs-72028	160	22	'	'	PUNCT
afs-72028	160	23	bound	bind	VERB
afs-72028	160	24	by	by	ADP
afs-72028	160	25	oxides	oxide	NOUN
afs-72028	160	26	.	.	PUNCT
afs-72028	161	1	for	for	ADP
afs-72028	161	2	example	example	NOUN
afs-72028	161	3	phosphate	phosphate	NOUN
afs-72028	161	4	is	be	AUX
afs-72028	161	5	rapidly	rapidly	ADV
afs-72028	161	6	bound	bind	VERB
afs-72028	161	7	by	by	ADP
afs-72028	161	8	alor	alor	PROPN
afs-72028	161	9	fe	fe	PROPN
afs-72028	161	10	-	-	NOUN
afs-72028	161	11	oxides	oxide	NOUN
afs-72028	161	12	,	,	PUNCT
afs-72028	161	13	but	but	CCONJ
afs-72028	161	14	100	100	NUM
afs-72028	161	15	%	%	NOUN
afs-72028	161	16	desorption	desorption	NOUN
afs-72028	161	17	is	be	AUX
afs-72028	161	18	almost	almost	ADV
afs-72028	161	19	impossible	impossible	ADJ
afs-72028	161	20	,	,	PUNCT
afs-72028	161	21	when	when	SCONJ
afs-72028	161	22	ligands	ligand	NOUN
afs-72028	161	23	,	,	PUNCT
afs-72028	161	24	which	which	PRON
afs-72028	161	25	are	be	AUX
afs-72028	161	26	not	not	PART
afs-72028	161	27	strongly	strongly	ADV
afs-72028	161	28	adsorbed	adsorb	VERB
afs-72028	161	29	by	by	ADP
afs-72028	161	30	oxides	oxide	NOUN
afs-72028	161	31	,	,	PUNCT
afs-72028	161	32	are	be	AUX
afs-72028	161	33	used	use	VERB
afs-72028	161	34	as	as	ADP
afs-72028	161	35	exchangers	exchanger	NOUN
afs-72028	161	36	(	(	PUNCT
afs-72028	161	37	kingston	kingston	PROPN
afs-72028	161	38	et	et	PROPN
afs-72028	161	39	al	al	PROPN
afs-72028	161	40	.	.	PROPN
afs-72028	161	41	1974	1974	NUM
afs-72028	161	42	)	)	PUNCT
afs-72028	161	43	.	.	PUNCT
afs-72028	162	1	the	the	DET
afs-72028	162	2	micropore	micropore	NOUN
afs-72028	162	3	structure	structure	NOUN
afs-72028	162	4	of	of	ADP
afs-72028	162	5	hydrous	hydrous	ADJ
afs-72028	162	6	oxides	oxide	NOUN
afs-72028	162	7	also	also	ADV
afs-72028	162	8	apparently	apparently	ADV
afs-72028	162	9	slows	slow	VERB
afs-72028	162	10	down	down	ADP
afs-72028	162	11	the	the	DET
afs-72028	162	12	desorption	desorption	NOUN
afs-72028	162	13	of	of	ADP
afs-72028	162	14	strongly	strongly	ADV
afs-72028	162	15	bound	bind	VERB
afs-72028	162	16	phosphate	phosphate	NOUN
afs-72028	162	17	from	from	ADP
afs-72028	162	18	acid	acid	NOUN
afs-72028	162	19	soil	soil	NOUN
afs-72028	162	20	(	(	PUNCT
afs-72028	162	21	aura	aura	NOUN
afs-72028	162	22	1978	1978	NUM
afs-72028	162	23	)	)	PUNCT
afs-72028	162	24	.	.	PUNCT
afs-72028	163	1	the	the	DET
afs-72028	163	2	rate	rate	NOUN
afs-72028	163	3	of	of	ADP
afs-72028	163	4	the	the	DET
afs-72028	163	5	exchange	exchange	NOUN
afs-72028	163	6	of	of	ADP
afs-72028	163	7	hydroxyl	hydroxyl	NOUN
afs-72028	163	8	with	with	ADP
afs-72028	163	9	water	water	NOUN
afs-72028	163	10	is	be	AUX
afs-72028	163	11	an	an	DET
afs-72028	163	12	exception	exception	NOUN
afs-72028	163	13	.	.	PUNCT
afs-72028	164	1	the	the	DET
afs-72028	164	2	hydroxyl	hydroxyl	NOUN
afs-72028	164	3	oxygen	oxygen	NOUN
afs-72028	164	4	is	be	AUX
afs-72028	164	5	very	very	ADV
afs-72028	164	6	nucleophilic	nucleophilic	ADJ
afs-72028	164	7	,	,	PUNCT
afs-72028	164	8	and	and	CCONJ
afs-72028	164	9	easily	easily	ADV
afs-72028	164	10	takes	take	VERB
afs-72028	164	11	up	up	ADP
afs-72028	164	12	a	a	DET
afs-72028	164	13	proton	proton	NOUN
afs-72028	164	14	to	to	PART
afs-72028	164	15	form	form	VERB
afs-72028	164	16	water	water	NOUN
afs-72028	164	17	.	.	PUNCT
afs-72028	165	1	the	the	DET
afs-72028	165	2	hydroxyl	hydroxyl	NOUN
afs-72028	165	3	oxygen	oxygen	NOUN
afs-72028	165	4	does	do	AUX
afs-72028	165	5	not	not	PART
afs-72028	165	6	need	need	VERB
afs-72028	165	7	to	to	PART
afs-72028	165	8	be	be	AUX
afs-72028	165	9	released	release	VERB
afs-72028	165	10	from	from	ADP
afs-72028	165	11	the	the	DET
afs-72028	165	12	central	central	ADJ
afs-72028	165	13	ion	ion	NOUN
afs-72028	165	14	.	.	PUNCT
afs-72028	166	1	the	the	DET
afs-72028	166	2	easily	easily	ADV
afs-72028	166	3	moving	move	VERB
afs-72028	166	4	proton	proton	NOUN
afs-72028	166	5	can	can	AUX
afs-72028	166	6	be	be	AUX
afs-72028	166	7	detached	detach	VERB
afs-72028	166	8	from	from	ADP
afs-72028	166	9	the	the	DET
afs-72028	166	10	water	water	NOUN
afs-72028	166	11	in	in	ADP
afs-72028	166	12	solution	solution	NOUN
afs-72028	166	13	and	and	CCONJ
afs-72028	166	14	associated	associate	VERB
afs-72028	166	15	with	with	ADP
afs-72028	166	16	the	the	DET
afs-72028	166	17	oh	oh	NUM
afs-72028	166	18	-	-	PUNCT
afs-72028	166	19	group	group	NOUN
afs-72028	166	20	on	on	ADP
afs-72028	166	21	the	the	DET
afs-72028	166	22	surface	surface	NOUN
afs-72028	166	23	of	of	ADP
afs-72028	166	24	the	the	DET
afs-72028	166	25	oxides	oxide	NOUN
afs-72028	166	26	(	(	PUNCT
afs-72028	166	27	fitz	fitz	PROPN
afs-72028	166	28	1975	1975	NUM
afs-72028	166	29	p.	p.	NOUN
afs-72028	166	30	385	385	NUM
afs-72028	166	31	)	)	PUNCT
afs-72028	166	32	.	.	PUNCT
afs-72028	167	1	discussion	discussion	NOUN
afs-72028	167	2	the	the	DET
afs-72028	167	3	slow	slow	ADJ
afs-72028	167	4	desorption	desorption	NOUN
afs-72028	167	5	of	of	ADP
afs-72028	167	6	phosphate	phosphate	NOUN
afs-72028	167	7	from	from	ADP
afs-72028	167	8	aluminium	aluminium	NOUN
afs-72028	167	9	and	and	CCONJ
afs-72028	167	10	iron	iron	NOUN
afs-72028	167	11	oxides	oxide	NOUN
afs-72028	167	12	can	can	AUX
afs-72028	167	13	be	be	AUX
afs-72028	167	14	explained	explain	VERB
afs-72028	167	15	by	by	ADP
afs-72028	167	16	the	the	DET
afs-72028	167	17	fact	fact	NOUN
afs-72028	167	18	that	that	SCONJ
afs-72028	167	19	phosphate	phosphate	NOUN
afs-72028	167	20	can	can	AUX
afs-72028	167	21	be	be	AUX
afs-72028	167	22	bound	bind	VERB
afs-72028	167	23	to	to	ADP
afs-72028	167	24	two	two	NUM
afs-72028	167	25	adjacent	adjacent	ADJ
afs-72028	167	26	central	central	ADJ
afs-72028	167	27	ions	ion	NOUN
afs-72028	167	28	in	in	ADP
afs-72028	167	29	the	the	DET
afs-72028	167	30	oxides	oxide	NOUN
afs-72028	167	31	forming	form	VERB
afs-72028	167	32	a	a	DET
afs-72028	167	33	ring	ring	NOUN
afs-72028	167	34	structure	structure	NOUN
afs-72028	167	35	.	.	PUNCT
afs-72028	168	1	this	this	DET
afs-72028	168	2	structure	structure	NOUN
afs-72028	168	3	probably	probably	ADV
afs-72028	168	4	stabilizes	stabilize	VERB
afs-72028	168	5	the	the	DET
afs-72028	168	6	bond	bond	NOUN
afs-72028	168	7	between	between	ADP
afs-72028	168	8	phosphate	phosphate	NOUN
afs-72028	168	9	and	and	CCONJ
afs-72028	168	10	oxide	oxide	NOUN
afs-72028	168	11	,	,	PUNCT
afs-72028	168	12	but	but	CCONJ
afs-72028	168	13	the	the	DET
afs-72028	168	14	ring	ring	NOUN
afs-72028	168	15	structure	structure	NOUN
afs-72028	168	16	does	do	AUX
afs-72028	168	17	not	not	PART
afs-72028	168	18	alone	alone	ADV
afs-72028	168	19	explain	explain	VERB
afs-72028	168	20	the	the	DET
afs-72028	168	21	strong	strong	ADJ
afs-72028	168	22	adsorption	adsorption	NOUN
afs-72028	168	23	of	of	ADP
afs-72028	168	24	phosphate	phosphate	NOUN
afs-72028	168	25	to	to	ADP
afs-72028	168	26	oxides	oxide	NOUN
afs-72028	168	27	.	.	PUNCT
afs-72028	169	1	for	for	ADP
afs-72028	169	2	example	example	NOUN
afs-72028	169	3	sulphate	sulphate	NOUN
afs-72028	169	4	forms	form	VERB
afs-72028	169	5	the	the	DET
afs-72028	169	6	ring	ring	NOUN
afs-72028	169	7	structure	structure	NOUN
afs-72028	169	8	,	,	PUNCT
afs-72028	169	9	when	when	SCONJ
afs-72028	169	10	it	it	PRON
afs-72028	169	11	is	be	AUX
afs-72028	169	12	bound	bind	VERB
afs-72028	169	13	by	by	ADP
afs-72028	169	14	aland	aland	PROPN
afs-72028	169	15	fe	fe	PROPN
afs-72028	169	16	-	-	PUNCT
afs-72028	169	17	oxides	oxide	NOUN
afs-72028	169	18	(	(	PUNCT
afs-72028	169	19	parfitt	parfitt	NOUN
afs-72028	169	20	and	and	CCONJ
afs-72028	169	21	smart	smart	ADJ
afs-72028	169	22	1978	1978	NUM
afs-72028	169	23	,	,	PUNCT
afs-72028	169	24	rajan	rajan	NOUN
afs-72028	169	25	1978	1978	NUM
afs-72028	169	26	)	)	PUNCT
afs-72028	169	27	,	,	PUNCT
afs-72028	169	28	but	but	CCONJ
afs-72028	169	29	is	be	AUX
afs-72028	169	30	desorbed	desorb	VERB
afs-72028	169	31	from	from	ADP
afs-72028	169	32	oxides	oxide	NOUN
afs-72028	169	33	much	much	ADV
afs-72028	169	34	more	more	ADV
afs-72028	169	35	easily	easily	ADV
afs-72028	169	36	than	than	ADP
afs-72028	169	37	phosphate	phosphate	ADJ
afs-72028	169	38	.	.	PUNCT
afs-72028	170	1	primarily	primarily	ADV
afs-72028	170	2	the	the	DET
afs-72028	170	3	nucleophilic	nucleophilic	ADJ
afs-72028	170	4	strength	strength	NOUN
afs-72028	170	5	of	of	ADP
afs-72028	170	6	the	the	DET
afs-72028	170	7	ligand	ligand	ADJ
afs-72028	170	8	oxygen	oxygen	NOUN
afs-72028	170	9	determines	determine	VERB
afs-72028	170	10	the	the	DET
afs-72028	170	11	bond	bond	NOUN
afs-72028	170	12	between	between	ADP
afs-72028	170	13	anion	anion	NOUN
afs-72028	170	14	and	and	CCONJ
afs-72028	170	15	al	al	PROPN
afs-72028	170	16	3	3	PROPN
afs-72028	170	17	+	+	NUM
afs-72028	170	18	or	or	CCONJ
afs-72028	170	19	fe	fe	X
afs-72028	170	20	3	3	NUM
afs-72028	170	21	+	+	NUM
afs-72028	170	22	of	of	ADP
afs-72028	170	23	oxides	oxide	NOUN
afs-72028	170	24	.	.	PUNCT
afs-72028	171	1	both	both	PRON
afs-72028	171	2	carboxyl	carboxyl	NOUN
afs-72028	171	3	and	and	CCONJ
afs-72028	171	4	phenolic	phenolic	ADJ
afs-72028	171	5	oh	oh	INTJ
afs-72028	171	6	group	group	NOUN
afs-72028	171	7	of	of	ADP
afs-72028	171	8	soil	soil	NOUN
afs-72028	171	9	organic	organic	ADJ
afs-72028	171	10	matter	matter	NOUN
afs-72028	171	11	bind	bind	VERB
afs-72028	171	12	al	al	PROPN
afs-72028	171	13	3	3	PROPN
afs-72028	171	14	+	+	NUM
afs-72028	171	15	and	and	CCONJ
afs-72028	171	16	fe	fe	X
afs-72028	171	17	3	3	NUM
afs-72028	171	18	+	+	CCONJ
afs-72028	171	19	(	(	PUNCT
afs-72028	171	20	schnitzer	schnitzer	NOUN
afs-72028	171	21	and	and	CCONJ
afs-72028	171	22	skinner	skinner	NOUN
afs-72028	171	23	1965	1965	NUM
afs-72028	171	24	)	)	PUNCT
afs-72028	171	25	.	.	PUNCT
afs-72028	172	1	since	since	SCONJ
afs-72028	172	2	the	the	DET
afs-72028	172	3	pka	pka	NOUN
afs-72028	172	4	-	-	PUNCT
afs-72028	172	5	value	value	NOUN
afs-72028	172	6	of	of	ADP
afs-72028	172	7	carboxyl	carboxyl	NOUN
afs-72028	172	8	and	and	CCONJ
afs-72028	172	9	phenolic	phenolic	ADJ
afs-72028	172	10	oh	oh	INTJ
afs-72028	172	11	groups	group	NOUN
afs-72028	172	12	varies	vary	VERB
afs-72028	172	13	greatly	greatly	ADV
afs-72028	172	14	,	,	PUNCT
afs-72028	172	15	there	there	PRON
afs-72028	172	16	are	be	VERB
afs-72028	172	17	great	great	ADJ
afs-72028	172	18	differences	difference	NOUN
afs-72028	172	19	between	between	ADP
afs-72028	172	20	carboxyl	carboxyl	NOUN
afs-72028	172	21	groups	group	NOUN
afs-72028	172	22	and	and	CCONJ
afs-72028	172	23	between	between	ADP
afs-72028	172	24	phenolic	phenolic	ADJ
afs-72028	172	25	oh	oh	NUM
afs-72028	172	26	groups	group	NOUN
afs-72028	172	27	in	in	ADP
afs-72028	172	28	the	the	DET
afs-72028	172	29	bonding	bonding	NOUN
afs-72028	172	30	to	to	ADP
afs-72028	172	31	al	al	PROPN
afs-72028	172	32	3	3	PROPN
afs-72028	172	33	+	+	NUM
afs-72028	172	34	or	or	CCONJ
afs-72028	172	35	42	42	NUM
afs-72028	172	36	fe	fe	NOUN
afs-72028	172	37	3	3	NUM
afs-72028	172	38	+	+	CCONJ
afs-72028	172	39	.	.	PUNCT
afs-72028	173	1	large	large	ADJ
afs-72028	173	2	organic	organic	ADJ
afs-72028	173	3	molecules	molecule	NOUN
afs-72028	173	4	are	be	AUX
afs-72028	173	5	easily	easily	ADV
afs-72028	173	6	bound	bind	VERB
afs-72028	173	7	to	to	ADP
afs-72028	173	8	oxides	oxide	NOUN
afs-72028	173	9	by	by	ADP
afs-72028	173	10	several	several	ADJ
afs-72028	173	11	carboxyl	carboxyl	NOUN
afs-72028	173	12	and	and	CCONJ
afs-72028	173	13	phenolic	phenolic	ADJ
afs-72028	173	14	oh	oh	NUM
afs-72028	173	15	groups	group	NOUN
afs-72028	173	16	,	,	PUNCT
afs-72028	173	17	which	which	PRON
afs-72028	173	18	stabilize	stabilize	VERB
afs-72028	173	19	the	the	DET
afs-72028	173	20	association	association	NOUN
afs-72028	173	21	between	between	ADP
afs-72028	173	22	organic	organic	ADJ
afs-72028	173	23	molecules	molecule	NOUN
afs-72028	173	24	and	and	CCONJ
afs-72028	173	25	oxides	oxide	NOUN
afs-72028	173	26	.	.	PUNCT
afs-72028	174	1	the	the	DET
afs-72028	174	2	ligands	ligand	NOUN
afs-72028	174	3	can	can	AUX
afs-72028	174	4	be	be	AUX
afs-72028	174	5	grouped	group	VERB
afs-72028	174	6	as	as	SCONJ
afs-72028	174	7	follows	follow	VERB
afs-72028	174	8	.	.	PUNCT
afs-72028	175	1	the	the	DET
afs-72028	175	2	anions	anion	NOUN
afs-72028	175	3	,	,	PUNCT
afs-72028	175	4	which	which	PRON
afs-72028	175	5	are	be	AUX
afs-72028	175	6	more	more	ADV
afs-72028	175	7	weakly	weakly	ADV
afs-72028	175	8	adsorbed	adsorb	VERB
afs-72028	175	9	than	than	ADP
afs-72028	175	10	water	water	NOUN
afs-72028	175	11	,	,	PUNCT
afs-72028	175	12	form	form	VERB
afs-72028	175	13	the	the	DET
afs-72028	175	14	first	first	ADJ
afs-72028	175	15	group	group	NOUN
afs-72028	175	16	.	.	PUNCT
afs-72028	176	1	these	these	DET
afs-72028	176	2	anions	anion	NOUN
afs-72028	176	3	are	be	AUX
afs-72028	176	4	outside	outside	ADP
afs-72028	176	5	the	the	DET
afs-72028	176	6	coordination	coordination	NOUN
afs-72028	176	7	sphere	sphere	NOUN
afs-72028	176	8	of	of	ADP
afs-72028	176	9	the	the	DET
afs-72028	176	10	aluminium	aluminium	NOUN
afs-72028	176	11	and	and	CCONJ
afs-72028	176	12	iron	iron	NOUN
afs-72028	176	13	and	and	CCONJ
afs-72028	176	14	can	can	AUX
afs-72028	176	15	be	be	AUX
afs-72028	176	16	bound	bind	VERB
afs-72028	176	17	only	only	ADV
afs-72028	176	18	by	by	ADP
afs-72028	176	19	oxides	oxide	NOUN
afs-72028	176	20	,	,	PUNCT
afs-72028	176	21	if	if	SCONJ
afs-72028	176	22	the	the	DET
afs-72028	176	23	surface	surface	NOUN
afs-72028	176	24	of	of	ADP
afs-72028	176	25	oxides	oxide	NOUN
afs-72028	176	26	is	be	AUX
afs-72028	176	27	positively	positively	ADV
afs-72028	176	28	charged	charge	VERB
afs-72028	176	29	.	.	PUNCT
afs-72028	177	1	nitrate	nitrate	NOUN
afs-72028	177	2	belongs	belong	VERB
afs-72028	177	3	to	to	ADP
afs-72028	177	4	this	this	DET
afs-72028	177	5	group	group	NOUN
afs-72028	177	6	(	(	PUNCT
afs-72028	177	7	serna	serna	PROPN
afs-72028	177	8	et	et	PROPN
afs-72028	177	9	al	al	PROPN
afs-72028	177	10	.	.	PROPN
afs-72028	177	11	1977	1977	NUM
afs-72028	177	12	)	)	PUNCT
afs-72028	177	13	.	.	PUNCT
afs-72028	178	1	the	the	DET
afs-72028	178	2	second	second	ADJ
afs-72028	178	3	group	group	NOUN
afs-72028	178	4	are	be	AUX
afs-72028	178	5	anions	anion	NOUN
afs-72028	178	6	,	,	PUNCT
afs-72028	178	7	which	which	PRON
afs-72028	178	8	are	be	AUX
afs-72028	178	9	more	more	ADV
afs-72028	178	10	strongly	strongly	ADV
afs-72028	178	11	bound	bind	VERB
afs-72028	178	12	than	than	ADP
afs-72028	178	13	water	water	NOUN
afs-72028	178	14	to	to	ADP
afs-72028	178	15	the	the	DET
afs-72028	178	16	oxides	oxide	NOUN
afs-72028	178	17	,	,	PUNCT
afs-72028	178	18	but	but	CCONJ
afs-72028	178	19	can	can	AUX
afs-72028	178	20	not	not	PART
afs-72028	178	21	change	change	VERB
afs-72028	178	22	the	the	DET
afs-72028	178	23	structure	structure	NOUN
afs-72028	178	24	of	of	ADP
afs-72028	178	25	oxides	oxide	NOUN
afs-72028	178	26	.	.	PUNCT
afs-72028	179	1	sulphate	sulphate	NOUN
afs-72028	179	2	belongs	belong	VERB
afs-72028	179	3	to	to	ADP
afs-72028	179	4	this	this	DET
afs-72028	179	5	group	group	NOUN
afs-72028	179	6	(	(	PUNCT
afs-72028	179	7	kingston	kingston	PROPN
afs-72028	179	8	et	et	PROPN
afs-72028	179	9	al	al	PROPN
afs-72028	179	10	.	.	PROPN
afs-72028	179	11	1972	1972	NUM
afs-72028	179	12	,	,	PUNCT
afs-72028	179	13	rajan	rajan	NOUN
afs-72028	179	14	1979	1979	NUM
afs-72028	179	15	)	)	PUNCT
afs-72028	179	16	.	.	PUNCT
afs-72028	180	1	in	in	ADP
afs-72028	180	2	the	the	DET
afs-72028	180	3	third	third	ADJ
afs-72028	180	4	group	group	NOUN
afs-72028	180	5	are	be	AUX
afs-72028	180	6	the	the	DET
afs-72028	180	7	anions	anion	NOUN
afs-72028	180	8	,	,	PUNCT
afs-72028	180	9	which	which	PRON
afs-72028	180	10	are	be	AUX
afs-72028	180	11	firmly	firmly	ADV
afs-72028	180	12	bound	bind	VERB
afs-72028	180	13	by	by	ADP
afs-72028	180	14	oxides	oxide	NOUN
afs-72028	180	15	above	above	ADP
afs-72028	180	16	zpc	zpc	NOUN
afs-72028	180	17	making	make	VERB
afs-72028	180	18	the	the	DET
afs-72028	180	19	surface	surface	NOUN
afs-72028	180	20	of	of	ADP
afs-72028	180	21	oxide	oxide	NOUN
afs-72028	180	22	more	more	ADV
afs-72028	180	23	negative	negative	ADJ
afs-72028	180	24	.	.	PUNCT
afs-72028	181	1	anions	anion	NOUN
afs-72028	181	2	of	of	ADP
afs-72028	181	3	this	this	DET
afs-72028	181	4	type	type	NOUN
afs-72028	181	5	can	can	AUX
afs-72028	181	6	radically	radically	ADV
afs-72028	181	7	change	change	VERB
afs-72028	181	8	the	the	DET
afs-72028	181	9	structure	structure	NOUN
afs-72028	181	10	of	of	ADP
afs-72028	181	11	oxides	oxide	NOUN
afs-72028	181	12	,	,	PUNCT
afs-72028	181	13	if	if	SCONJ
afs-72028	181	14	the	the	DET
afs-72028	181	15	anion	anion	NOUN
afs-72028	181	16	concentration	concentration	NOUN
afs-72028	181	17	in	in	ADP
afs-72028	181	18	equilibrium	equilibrium	NOUN
afs-72028	181	19	solution	solution	NOUN
afs-72028	181	20	is	be	AUX
afs-72028	181	21	high	high	ADJ
afs-72028	181	22	enough	enough	ADV
afs-72028	181	23	.	.	PUNCT
afs-72028	182	1	phosphate	phosphate	NOUN
afs-72028	182	2	(	(	PUNCT
afs-72028	182	3	rajan	rajan	PROPN
afs-72028	182	4	et	et	PROPN
afs-72028	182	5	al	al	PROPN
afs-72028	182	6	.	.	PROPN
afs-72028	182	7	1974	1974	NUM
afs-72028	182	8	)	)	PUNCT
afs-72028	182	9	and	and	CCONJ
afs-72028	182	10	hydroxyl	hydroxyl	NOUN
afs-72028	182	11	are	be	AUX
afs-72028	182	12	in	in	ADP
afs-72028	182	13	this	this	DET
afs-72028	182	14	group	group	NOUN
afs-72028	182	15	.	.	PUNCT
afs-72028	183	1	humus	humus	NOUN
afs-72028	183	2	molecules	molecule	NOUN
afs-72028	183	3	belong	belong	VERB
afs-72028	183	4	to	to	ADP
afs-72028	183	5	the	the	DET
afs-72028	183	6	third	third	ADJ
afs-72028	183	7	group	group	NOUN
afs-72028	183	8	(	(	PUNCT
afs-72028	183	9	schnitzer	schnitzer	NOUN
afs-72028	183	10	and	and	CCONJ
afs-72028	183	11	skinner	skinner	NOUN
afs-72028	183	12	1963	1963	NUM
afs-72028	183	13	)	)	PUNCT
afs-72028	183	14	as	as	SCONJ
afs-72028	183	15	does	do	AUX
afs-72028	183	16	silicate	silicate	VERB
afs-72028	183	17	when	when	SCONJ
afs-72028	183	18	the	the	DET
afs-72028	183	19	ph	ph	NOUN
afs-72028	183	20	is	be	AUX
afs-72028	183	21	above	above	ADP
afs-72028	183	22	7	7	NUM
afs-72028	183	23	(	(	PUNCT
afs-72028	183	24	kingston	kingston	NOUN
afs-72028	183	25	and	and	CCONJ
afs-72028	183	26	raupach	raupach	NOUN
afs-72028	183	27	1967	1967	NUM
afs-72028	183	28	)	)	PUNCT
afs-72028	183	29	.	.	PUNCT
afs-72028	184	1	molybdate	molybdate	VERB
afs-72028	184	2	and	and	CCONJ
afs-72028	184	3	selenite	selenite	NOUN
afs-72028	184	4	are	be	AUX
afs-72028	184	5	apparently	apparently	ADV
afs-72028	184	6	in	in	ADP
afs-72028	184	7	the	the	DET
afs-72028	184	8	second	second	ADJ
afs-72028	184	9	group	group	NOUN
afs-72028	184	10	.	.	PUNCT
afs-72028	185	1	if	if	SCONJ
afs-72028	185	2	an	an	DET
afs-72028	185	3	anion	anion	NOUN
afs-72028	185	4	is	be	AUX
afs-72028	185	5	not	not	PART
afs-72028	185	6	able	able	ADJ
afs-72028	185	7	to	to	PART
afs-72028	185	8	exchange	exchange	VERB
afs-72028	185	9	the	the	DET
afs-72028	185	10	coordination	coordination	NOUN
afs-72028	185	11	water	water	NOUN
afs-72028	185	12	from	from	ADP
afs-72028	185	13	the	the	DET
afs-72028	185	14	surface	surface	NOUN
afs-72028	185	15	of	of	ADP
afs-72028	185	16	oxides	oxide	NOUN
afs-72028	185	17	,	,	PUNCT
afs-72028	185	18	the	the	DET
afs-72028	185	19	diffusion	diffusion	NOUN
afs-72028	185	20	of	of	ADP
afs-72028	185	21	the	the	DET
afs-72028	185	22	anion	anion	NOUN
afs-72028	185	23	in	in	ADP
afs-72028	185	24	soil	soil	NOUN
afs-72028	185	25	is	be	AUX
afs-72028	185	26	rapid	rapid	ADJ
afs-72028	185	27	.	.	PUNCT
afs-72028	186	1	the	the	DET
afs-72028	186	2	anion	anion	NOUN
afs-72028	186	3	is	be	AUX
afs-72028	186	4	easily	easily	ADV
afs-72028	186	5	carried	carry	VERB
afs-72028	186	6	in	in	ADP
afs-72028	186	7	soil	soil	NOUN
afs-72028	186	8	by	by	ADP
afs-72028	186	9	mass	mass	ADJ
afs-72028	186	10	flow	flow	NOUN
afs-72028	186	11	.	.	PUNCT
afs-72028	187	1	the	the	DET
afs-72028	187	2	activation	activation	NOUN
afs-72028	187	3	energy	energy	NOUN
afs-72028	187	4	of	of	ADP
afs-72028	187	5	diffusion	diffusion	NOUN
afs-72028	187	6	in	in	ADP
afs-72028	187	7	soil	soil	NOUN
afs-72028	187	8	is	be	AUX
afs-72028	187	9	about	about	ADV
afs-72028	187	10	the	the	DET
afs-72028	187	11	same	same	ADJ
afs-72028	187	12	as	as	ADP
afs-72028	187	13	in	in	ADP
afs-72028	187	14	water	water	NOUN
afs-72028	187	15	solution	solution	NOUN
afs-72028	187	16	or	or	CCONJ
afs-72028	187	17	about	about	ADV
afs-72028	187	18	20	20	NUM
afs-72028	187	19	kj	kj	PROPN
afs-72028	187	20	/	/	SYM
afs-72028	187	21	mol	mol	PROPN
afs-72028	187	22	(	(	PUNCT
afs-72028	187	23	glastone	glastone	PROPN
afs-72028	187	24	et	et	PROPN
afs-72028	187	25	al	al	PROPN
afs-72028	187	26	.	.	PROPN
afs-72028	187	27	1941	1941	NUM
afs-72028	187	28	,	,	PUNCT
afs-72028	187	29	p.	p.	NOUN
afs-72028	187	30	401	401	NUM
afs-72028	187	31	)	)	PUNCT
afs-72028	187	32	.	.	PUNCT
afs-72028	188	1	when	when	SCONJ
afs-72028	188	2	an	an	DET
afs-72028	188	3	anion	anion	NOUN
afs-72028	188	4	coordinates	coordinate	VERB
afs-72028	188	5	with	with	ADP
afs-72028	188	6	the	the	DET
afs-72028	188	7	central	central	ADJ
afs-72028	188	8	ions	ion	NOUN
afs-72028	188	9	of	of	ADP
afs-72028	188	10	oxides	oxide	NOUN
afs-72028	188	11	,	,	PUNCT
afs-72028	188	12	the	the	DET
afs-72028	188	13	diffusing	diffuse	VERB
afs-72028	188	14	anion	anion	NOUN
afs-72028	188	15	is	be	AUX
afs-72028	188	16	repeteadly	repeteadly	ADV
afs-72028	188	17	bound	bind	VERB
afs-72028	188	18	by	by	ADP
afs-72028	188	19	the	the	DET
afs-72028	188	20	oxides	oxide	NOUN
afs-72028	188	21	.	.	PUNCT
afs-72028	189	1	the	the	DET
afs-72028	189	2	high	high	ADJ
afs-72028	189	3	nucleophilic	nucleophilic	ADJ
afs-72028	189	4	strength	strength	NOUN
afs-72028	189	5	of	of	ADP
afs-72028	189	6	the	the	DET
afs-72028	189	7	anion	anion	NOUN
afs-72028	189	8	slows	slow	VERB
afs-72028	189	9	down	down	ADP
afs-72028	189	10	its	its	PRON
afs-72028	189	11	detachment	detachment	NOUN
afs-72028	189	12	from	from	ADP
afs-72028	189	13	the	the	DET
afs-72028	189	14	central	central	ADJ
afs-72028	189	15	ions	ion	NOUN
afs-72028	189	16	of	of	ADP
afs-72028	189	17	oxide	oxide	NOUN
afs-72028	189	18	and	and	CCONJ
afs-72028	189	19	decreases	decrease	VERB
afs-72028	189	20	the	the	DET
afs-72028	189	21	diffusion	diffusion	NOUN
afs-72028	189	22	coefficient	coefficient	NOUN
afs-72028	189	23	of	of	ADP
afs-72028	189	24	the	the	DET
afs-72028	189	25	anion	anion	NOUN
afs-72028	189	26	in	in	ADP
afs-72028	189	27	soil	soil	NOUN
afs-72028	189	28	.	.	PUNCT
afs-72028	190	1	for	for	ADP
afs-72028	190	2	example	example	NOUN
afs-72028	190	3	the	the	DET
afs-72028	190	4	diffusion	diffusion	NOUN
afs-72028	190	5	coefficient	coefficient	NOUN
afs-72028	190	6	of	of	ADP
afs-72028	190	7	nitrate	nitrate	NOUN
afs-72028	190	8	in	in	ADP
afs-72028	190	9	soil	soil	NOUN
afs-72028	190	10	is	be	AUX
afs-72028	190	11	about	about	ADV
afs-72028	190	12	10'5	10'5	NUM
afs-72028	190	13	cm	cm	NOUN
afs-72028	190	14	2	2	NUM
afs-72028	190	15	/s	/s	NOUN
afs-72028	190	16	and	and	CCONJ
afs-72028	190	17	that	that	PRON
afs-72028	190	18	of	of	ADP
afs-72028	190	19	phosphate	phosphate	NOUN
afs-72028	190	20	10’9	10’9	NUM
afs-72028	190	21	cm	cm	NOUN
afs-72028	190	22	2	2	NUM
afs-72028	190	23	/	/	SYM
afs-72028	190	24	s	s	X
afs-72028	190	25	(	(	PUNCT
afs-72028	190	26	nye	nye	NOUN
afs-72028	190	27	and	and	CCONJ
afs-72028	190	28	tinker	tinker	VERB
afs-72028	190	29	1977	1977	NUM
afs-72028	190	30	p.	p.	NOUN
afs-72028	190	31	82	82	NUM
afs-72028	190	32	)	)	PUNCT
afs-72028	190	33	.	.	PUNCT
afs-72028	191	1	the	the	DET
afs-72028	191	2	dependence	dependence	NOUN
afs-72028	191	3	of	of	ADP
afs-72028	191	4	the	the	DET
afs-72028	191	5	diffusion	diffusion	NOUN
afs-72028	191	6	coefficient	coefficient	NOUN
afs-72028	191	7	on	on	ADP
afs-72028	191	8	the	the	DET
afs-72028	191	9	temperature	temperature	NOUN
afs-72028	191	10	is	be	AUX
afs-72028	191	11	higher	high	ADJ
afs-72028	191	12	for	for	ADP
afs-72028	191	13	those	those	DET
afs-72028	191	14	anions	anion	NOUN
afs-72028	191	15	that	that	PRON
afs-72028	191	16	coordinate	coordinate	VERB
afs-72028	191	17	with	with	ADP
afs-72028	191	18	the	the	DET
afs-72028	191	19	central	central	ADJ
afs-72028	191	20	ions	ion	NOUN
afs-72028	191	21	of	of	ADP
afs-72028	191	22	oxides	oxide	NOUN
afs-72028	191	23	than	than	ADP
afs-72028	191	24	for	for	ADP
afs-72028	191	25	those	those	DET
afs-72028	191	26	anions	anion	NOUN
afs-72028	191	27	that	that	PRON
afs-72028	191	28	are	be	AUX
afs-72028	191	29	outside	outside	ADP
afs-72028	191	30	the	the	DET
afs-72028	191	31	coordination	coordination	NOUN
afs-72028	191	32	sphere	sphere	NOUN
afs-72028	191	33	(	(	PUNCT
afs-72028	191	34	see	see	VERB
afs-72028	191	35	aura	aura	NOUN
afs-72028	191	36	1978	1978	NUM
afs-72028	191	37	)	)	PUNCT
afs-72028	191	38	.	.	PUNCT
afs-72028	192	1	since	since	SCONJ
afs-72028	192	2	the	the	DET
afs-72028	192	3	bond	bond	NOUN
afs-72028	192	4	between	between	ADP
afs-72028	192	5	phosphate	phosphate	NOUN
afs-72028	192	6	and	and	CCONJ
afs-72028	192	7	al	al	PROPN
afs-72028	192	8	3	3	PROPN
afs-72028	192	9	+	+	NUM
afs-72028	192	10	or	or	CCONJ
afs-72028	192	11	fe	fe	X
afs-72028	192	12	3	3	NUM
afs-72028	192	13	+	+	NUM
afs-72028	192	14	is	be	AUX
afs-72028	192	15	strong	strong	ADJ
afs-72028	192	16	,	,	PUNCT
afs-72028	192	17	the	the	DET
afs-72028	192	18	movement	movement	NOUN
afs-72028	192	19	of	of	ADP
afs-72028	192	20	phosphate	phosphate	NOUN
afs-72028	192	21	in	in	ADP
afs-72028	192	22	soil	soil	NOUN
afs-72028	192	23	by	by	ADP
afs-72028	192	24	mass	mass	ADJ
afs-72028	192	25	flow	flow	NOUN
afs-72028	192	26	is	be	AUX
afs-72028	192	27	slight	slight	ADJ
afs-72028	192	28	.	.	PUNCT
afs-72028	193	1	the	the	DET
afs-72028	193	2	strong	strong	ADJ
afs-72028	193	3	adsorption	adsorption	NOUN
afs-72028	193	4	of	of	ADP
afs-72028	193	5	anions	anion	NOUN
afs-72028	193	6	to	to	ADP
afs-72028	193	7	oxides	oxide	NOUN
afs-72028	193	8	reduces	reduce	VERB
afs-72028	193	9	the	the	DET
afs-72028	193	10	leaching	leaching	NOUN
afs-72028	193	11	from	from	ADP
afs-72028	193	12	the	the	DET
afs-72028	193	13	cultivated	cultivate	VERB
afs-72028	193	14	layer	layer	NOUN
afs-72028	193	15	.	.	PUNCT
afs-72028	194	1	when	when	SCONJ
afs-72028	194	2	a	a	DET
afs-72028	194	3	plant	plant	NOUN
afs-72028	194	4	takes	take	VERB
afs-72028	194	5	phosphorus	phosphorus	NOUN
afs-72028	194	6	from	from	ADP
afs-72028	194	7	the	the	DET
afs-72028	194	8	soil	soil	NOUN
afs-72028	194	9	,	,	PUNCT
afs-72028	194	10	a	a	DET
afs-72028	194	11	determining	determine	VERB
afs-72028	194	12	factor	factor	NOUN
afs-72028	194	13	in	in	ADP
afs-72028	194	14	the	the	DET
afs-72028	194	15	process	process	NOUN
afs-72028	194	16	is	be	AUX
afs-72028	194	17	the	the	DET
afs-72028	194	18	slow	slow	ADJ
afs-72028	194	19	diffusion	diffusion	NOUN
afs-72028	194	20	of	of	ADP
afs-72028	194	21	phosphate	phosphate	NOUN
afs-72028	194	22	in	in	ADP
afs-72028	194	23	the	the	DET
afs-72028	194	24	soil	soil	NOUN
afs-72028	194	25	surrounding	surround	VERB
afs-72028	194	26	the	the	DET
afs-72028	194	27	root	root	NOUN
afs-72028	194	28	surface	surface	NOUN
afs-72028	194	29	and	and	CCONJ
afs-72028	194	30	root	root	NOUN
afs-72028	194	31	hairs	hair	NOUN
afs-72028	194	32	(	(	PUNCT
afs-72028	194	33	nye	nye	NOUN
afs-72028	194	34	and	and	CCONJ
afs-72028	194	35	tinker	tinker	VERB
afs-72028	194	36	1977	1977	NUM
afs-72028	194	37	)	)	PUNCT
afs-72028	194	38	.	.	PUNCT
afs-72028	195	1	the	the	DET
afs-72028	195	2	uptake	uptake	NOUN
afs-72028	195	3	of	of	ADP
afs-72028	195	4	phosphate	phosphate	NOUN
afs-72028	195	5	by	by	ADP
afs-72028	195	6	mass	mass	ADJ
afs-72028	195	7	flow	flow	NOUN
afs-72028	195	8	is	be	AUX
afs-72028	195	9	slight	slight	ADJ
afs-72028	195	10	.	.	PUNCT
afs-72028	196	1	since	since	SCONJ
afs-72028	196	2	the	the	DET
afs-72028	196	3	diffusion	diffusion	NOUN
afs-72028	196	4	coefficient	coefficient	NOUN
afs-72028	196	5	of	of	ADP
afs-72028	196	6	phosphate	phosphate	NOUN
afs-72028	196	7	depends	depend	VERB
afs-72028	196	8	strongly	strongly	ADV
afs-72028	196	9	on	on	ADP
afs-72028	196	10	the	the	DET
afs-72028	196	11	temperature	temperature	NOUN
afs-72028	196	12	,	,	PUNCT
afs-72028	196	13	the	the	DET
afs-72028	196	14	rise	rise	NOUN
afs-72028	196	15	of	of	ADP
afs-72028	196	16	soil	soil	NOUN
afs-72028	196	17	temperature	temperature	NOUN
afs-72028	196	18	has	have	VERB
afs-72028	196	19	a	a	DET
afs-72028	196	20	considerable	considerable	ADJ
afs-72028	196	21	positive	positive	ADJ
afs-72028	196	22	effect	effect	NOUN
afs-72028	196	23	on	on	ADP
afs-72028	196	24	the	the	DET
afs-72028	196	25	uptake	uptake	NOUN
afs-72028	196	26	of	of	ADP
afs-72028	196	27	phosphate	phosphate	NOUN
afs-72028	196	28	from	from	ADP
afs-72028	196	29	soil	soil	NOUN
afs-72028	196	30	.	.	PUNCT
afs-72028	197	1	43	43	NUM
afs-72028	197	2	references	reference	NOUN
afs-72028	197	3	aura	aura	NOUN
afs-72028	197	4	,	,	PUNCT
afs-72028	197	5	e.	e.	PROPN
afs-72028	197	6	1978	1978	NUM
afs-72028	197	7	.	.	PUNCT
afs-72028	198	1	phosphate	phosphate	ADJ
afs-72028	198	2	desorption	desorption	NOUN
afs-72028	198	3	from	from	ADP
afs-72028	198	4	soil	soil	NOUN
afs-72028	198	5	in	in	ADP
afs-72028	198	6	anion	anion	NOUN
afs-72028	198	7	-	-	PUNCT
afs-72028	198	8	exchange	exchange	NOUN
afs-72028	198	9	resin	resin	NOUN
afs-72028	198	10	extraction	extraction	NOUN
afs-72028	198	11	.	.	PUNCT
afs-72028	199	1	j.	j.	PROPN
afs-72028	199	2	scient	scient	PROPN
afs-72028	199	3	.	.	PUNCT
afs-72028	200	1	agric	agric	PROPN
afs-72028	200	2	.	.	PUNCT
afs-72028	200	3	soc	soc	PROPN
afs-72028	200	4	.	.	PUNCT
afs-72028	201	1	finl	finl	NOUN
afs-72028	201	2	.	.	PUNCT
afs-72028	202	1	50	50	NUM
afs-72028	202	2	:	:	SYM
afs-72028	202	3	335	335	NUM
afs-72028	202	4	345	345	NUM
afs-72028	202	5	.	.	PUNCT
afs-72028	203	1	baran	baran	NOUN
afs-72028	203	2	,	,	PUNCT
afs-72028	203	3	v.	v.	PROPN
afs-72028	203	4	1971	1971	NUM
afs-72028	203	5	.	.	PUNCT
afs-72028	204	1	hydroxyl	hydroxyl	NOUN
afs-72028	204	2	ion	ion	NOUN
afs-72028	204	3	as	as	ADP
afs-72028	204	4	a	a	DET
afs-72028	204	5	ligand	ligand	NOUN
afs-72028	204	6	.	.	PUNCT
afs-72028	205	1	coord	coord	NOUN
afs-72028	205	2	.	.	PUNCT
afs-72028	206	1	chem	chem	PROPN
afs-72028	206	2	.	.	PUNCT
afs-72028	207	1	rev	rev	PROPN
afs-72028	207	2	.	.	PROPN
afs-72028	208	1	6	6	NUM
afs-72028	208	2	:	:	SYM
afs-72028	208	3	65	65	NUM
afs-72028	208	4	93	93	NUM
afs-72028	208	5	.	.	PUNCT
afs-72028	209	1	basolo	basolo	PROPN
afs-72028	209	2	,	,	PUNCT
afs-72028	209	3	f.	f.	PROPN
afs-72028	209	4	&	&	CCONJ
afs-72028	209	5	pearson	pearson	PROPN
afs-72028	209	6	,	,	PUNCT
afs-72028	209	7	r.	r.	PROPN
afs-72028	209	8	g.	g.	PROPN
afs-72028	209	9	1967	1967	NUM
afs-72028	209	10	.	.	PUNCT
afs-72028	210	1	mechanisms	mechanism	NOUN
afs-72028	210	2	of	of	ADP
afs-72028	210	3	inorganic	inorganic	ADJ
afs-72028	210	4	reactions	reaction	NOUN
afs-72028	210	5	.	.	PUNCT
afs-72028	211	1	670	670	NUM
afs-72028	211	2	p.	p.	PROPN
afs-72028	211	3	new	new	PROPN
afs-72028	211	4	york	york	PROPN
afs-72028	211	5	.	.	PUNCT
afs-72028	212	1	biggar	biggar	PROPN
afs-72028	212	2	,	,	PUNCT
afs-72028	212	3	j	j	PROPN
afs-72028	212	4	,	,	PUNCT
afs-72028	212	5	w.	w.	PROPN
afs-72028	212	6	&	&	CCONJ
afs-72028	212	7	fireman	fireman	PROPN
afs-72028	212	8	,	,	PUNCT
afs-72028	212	9	m.	m.	NOUN
afs-72028	212	10	1960	1960	NUM
afs-72028	212	11	.	.	PUNCT
afs-72028	213	1	boron	boron	NOUN
afs-72028	213	2	adsorption	adsorption	NOUN
afs-72028	213	3	and	and	CCONJ
afs-72028	213	4	release	release	NOUN
afs-72028	213	5	by	by	ADP
afs-72028	213	6	soils	soil	NOUN
afs-72028	213	7	.	.	PUNCT
afs-72028	214	1	soil	soil	PROPN
afs-72028	214	2	sci	sci	PROPN
afs-72028	214	3	.	.	PUNCT
afs-72028	214	4	soc	soc	PROPN
afs-72028	214	5	.	.	PUNCT
afs-72028	215	1	amer	amer	PROPN
afs-72028	215	2	.	.	PUNCT
afs-72028	216	1	proc	proc	PROPN
afs-72028	216	2	.	.	PUNCT
afs-72028	217	1	24	24	NUM
afs-72028	217	2	;	;	PUNCT
afs-72028	217	3	115	115	NUM
afs-72028	217	4	120	120	NUM
afs-72028	217	5	.	.	PUNCT
afs-72028	218	1	bingham	bingham	PROPN
afs-72028	218	2	,	,	PUNCT
afs-72028	218	3	f.	f.	PROPN
afs-72028	218	4	t.	t.	PROPN
afs-72028	218	5	,	,	PUNCT
afs-72028	218	6	page	page	NOUN
afs-72028	218	7	,	,	PUNCT
afs-72028	218	8	a.	a.	PROPN
afs-72028	218	9	l.	l.	PROPN
afs-72028	218	10	,	,	PUNCT
afs-72028	218	11	coleman	coleman	PROPN
afs-72028	218	12	,	,	PUNCT
afs-72028	218	13	n.	n.	PROPN
afs-72028	218	14	t.	t.	PROPN
afs-72028	218	15	&	&	CCONJ
afs-72028	218	16	flach	flach	PROPN
afs-72028	218	17	,	,	PUNCT
afs-72028	218	18	k.	k.	PROPN
afs-72028	218	19	1971	1971	NUM
afs-72028	218	20	.	.	PUNCT
afs-72028	219	1	boron	boron	NOUN
afs-72028	219	2	adsorption	adsorption	NOUN
afs-72028	219	3	characteristics	characteristic	NOUN
afs-72028	219	4	of	of	ADP
afs-72028	219	5	selected	select	VERB
afs-72028	219	6	amorphous	amorphous	ADJ
afs-72028	219	7	soils	soil	NOUN
afs-72028	219	8	from	from	ADP
afs-72028	219	9	mexico	mexico	PROPN
afs-72028	219	10	and	and	CCONJ
afs-72028	219	11	hawaii	hawaii	PROPN
afs-72028	219	12	.	.	PUNCT
afs-72028	220	1	soil	soil	PROPN
afs-72028	220	2	sei	sei	PROPN
afs-72028	220	3	.	.	PUNCT
afs-72028	220	4	soc	soc	PROPN
afs-72028	220	5	.	.	PUNCT
afs-72028	221	1	amer	amer	PROPN
afs-72028	221	2	.	.	PUNCT
afs-72028	221	3	proc	proc	PROPN
afs-72028	221	4	.	.	PUNCT
afs-72028	222	1	35:546	35:546	NUM
afs-72028	222	2	-	-	SYM
afs-72028	222	3	550	550	NUM
afs-72028	222	4	.	.	PUNCT
afs-72028	223	1	clark	clark	PROPN
afs-72028	223	2	,	,	PUNCT
afs-72028	223	3	j.	j.	PROPN
afs-72028	223	4	s.	s.	PROPN
afs-72028	223	5	1964	1964	NUM
afs-72028	223	6	.	.	PUNCT
afs-72028	224	1	aluminium	aluminium	NOUN
afs-72028	224	2	and	and	CCONJ
afs-72028	224	3	iron	iron	NOUN
afs-72028	224	4	fixation	fixation	NOUN
afs-72028	224	5	in	in	ADP
afs-72028	224	6	relation	relation	NOUN
afs-72028	224	7	to	to	ADP
afs-72028	224	8	exchangeable	exchangeable	ADJ
afs-72028	224	9	hydrogen	hydrogen	NOUN
afs-72028	224	10	in	in	ADP
afs-72028	224	11	soils	soil	NOUN
afs-72028	224	12	.	.	PUNCT
afs-72028	225	1	soil	soil	PROPN
afs-72028	225	2	sci	sci	PROPN
afs-72028	225	3	.	.	PROPN
afs-72028	226	1	98	98	NUM
afs-72028	226	2	:	:	SYM
afs-72028	226	3	302	302	NUM
afs-72028	226	4	-	-	SYM
afs-72028	226	5	306	306	NUM
afs-72028	226	6	.	.	PUNCT
afs-72028	227	1	connick	connick	PROPN
afs-72028	227	2	,	,	PUNCT
afs-72028	227	3	r.	r.	PROPN
afs-72028	227	4	e.	e.	PROPN
afs-72028	227	5	&	&	CCONJ
afs-72028	227	6	stover	stover	PROPN
afs-72028	227	7	,	,	PUNCT
afs-72028	227	8	e.	e.	PROPN
afs-72028	227	9	d.	d.	PROPN
afs-72028	227	10	1961	1961	NUM
afs-72028	227	11	.	.	PUNCT
afs-72028	228	1	rate	rate	NOUN
afs-72028	228	2	of	of	ADP
afs-72028	228	3	elimination	elimination	NOUN
afs-72028	228	4	of	of	ADP
afs-72028	228	5	water	water	NOUN
afs-72028	228	6	molecules	molecule	NOUN
afs-72028	228	7	irom	irom	ADP
afs-72028	228	8	the	the	DET
afs-72028	228	9	first	first	ADJ
afs-72028	228	10	coordination	coordination	NOUN
afs-72028	228	11	sphere	sphere	NOUN
afs-72028	228	12	of	of	ADP
afs-72028	228	13	paramagnetic	paramagnetic	ADJ
afs-72028	228	14	cations	cation	NOUN
afs-72028	228	15	as	as	SCONJ
afs-72028	228	16	detected	detect	VERB
afs-72028	228	17	by	by	ADP
afs-72028	228	18	nuclear	nuclear	ADJ
afs-72028	228	19	magnetic	magnetic	ADJ
afs-72028	228	20	resonance	resonance	NOUN
afs-72028	228	21	measurements	measurement	NOUN
afs-72028	228	22	of	of	ADP
afs-72028	228	23	017.o	017.o	PROPN
afs-72028	228	24	17	17	NUM
afs-72028	228	25	.	.	PUNCT
afs-72028	229	1	j.	j.	PROPN
afs-72028	229	2	phys	phys	PROPN
afs-72028	229	3	.	.	PUNCT
afs-72028	230	1	chem	chem	PROPN
afs-72028	230	2	.	.	PUNCT
afs-72028	231	1	65	65	NUM
afs-72028	231	2	:	:	SYM
afs-72028	231	3	2075	2075	NUM
afs-72028	231	4	2077	2077	NUM
afs-72028	231	5	.	.	PUNCT
afs-72028	232	1	edwards	edwards	PROPN
afs-72028	232	2	,	,	PUNCT
afs-72028	232	3	j.	j.	PROPN
afs-72028	232	4	o.	o.	PROPN
afs-72028	232	5	1956	1956	NUM
afs-72028	232	6	.	.	PUNCT
afs-72028	233	1	polarizability	polarizability	NOUN
afs-72028	233	2	,	,	PUNCT
afs-72028	233	3	basicity	basicity	NOUN
afs-72028	233	4	and	and	CCONJ
afs-72028	233	5	nucleophilic	nucleophilic	ADJ
afs-72028	233	6	character	character	NOUN
afs-72028	233	7	.	.	PUNCT
afs-72028	234	1	j.	j.	PROPN
afs-72028	234	2	amer	amer	PROPN
afs-72028	234	3	.	.	PROPN
afs-72028	234	4	chem	chem	PROPN
afs-72028	234	5	.	.	PUNCT
afs-72028	235	1	soc	soc	PROPN
afs-72028	235	2	.	.	PUNCT
afs-72028	236	1	76	76	NUM
afs-72028	236	2	:	:	PUNCT
afs-72028	236	3	1819	1819	NUM
afs-72028	236	4	-	-	SYM
afs-72028	236	5	1820	1820	NUM
afs-72028	236	6	.	.	PUNCT
afs-72028	237	1	&	&	CCONJ
afs-72028	237	2	pearson	pearson	PROPN
afs-72028	237	3	,	,	PUNCT
afs-72028	237	4	r.	r.	PROPN
afs-72028	237	5	g.	g.	PROPN
afs-72028	237	6	1962	1962	NUM
afs-72028	237	7	.	.	PUNCT
afs-72028	238	1	the	the	DET
afs-72028	238	2	factors	factor	NOUN
afs-72028	238	3	determining	determine	VERB
afs-72028	238	4	nucleophilic	nucleophilic	ADJ
afs-72028	238	5	reactivities	reactivity	NOUN
afs-72028	238	6	.	.	PUNCT
afs-72028	239	1	j.	j.	PROPN
afs-72028	239	2	amer	amer	PROPN
afs-72028	239	3	.	.	PROPN
afs-72028	239	4	chem	chem	PROPN
afs-72028	239	5	.	.	PUNCT
afs-72028	240	1	soc	soc	PROPN
afs-72028	240	2	.	.	PUNCT
afs-72028	241	1	84	84	NUM
afs-72028	241	2	:	:	PUNCT
afs-72028	241	3	16	16	NUM
afs-72028	241	4	24	24	NUM
afs-72028	241	5	.	.	PUNCT
afs-72028	241	6	fitz	fitz	PROPN
afs-72028	241	7	,	,	PUNCT
afs-72028	241	8	i.	i.	PROPN
afs-72028	241	9	1975	1975	NUM
afs-72028	241	10	.	.	PUNCT
afs-72028	242	1	reaktionstypen	reaktionstypen	ADJ
afs-72028	242	2	in	in	ADP
afs-72028	242	3	der	der	NOUN
afs-72028	242	4	anorganischen	anorganischen	ADJ
afs-72028	242	5	chemie	chemie	PROPN
afs-72028	242	6	.	.	PUNCT
afs-72028	243	1	465	465	NUM
afs-72028	243	2	p.	p.	NUM
afs-72028	243	3	berlin	berlin	PROPN
afs-72028	243	4	.	.	PUNCT
afs-72028	244	1	glastone	glastone	PROPN
afs-72028	244	2	,	,	PUNCT
afs-72028	244	3	s.	s.	PROPN
afs-72028	244	4	,	,	PUNCT
afs-72028	244	5	laidler	laidler	PROPN
afs-72028	244	6	,	,	PUNCT
afs-72028	244	7	k	k	PROPN
afs-72028	244	8	,	,	PUNCT
afs-72028	244	9	j.	j.	PROPN
afs-72028	244	10	&	&	CCONJ
afs-72028	244	11	eyring	eyring	PROPN
afs-72028	244	12	,	,	PUNCT
afs-72028	244	13	h.	h.	PROPN
afs-72028	244	14	1941	1941	NUM
afs-72028	244	15	.	.	PUNCT
afs-72028	245	1	the	the	DET
afs-72028	245	2	theory	theory	NOUN
afs-72028	245	3	of	of	ADP
afs-72028	245	4	rate	rate	NOUN
afs-72028	245	5	processes	process	NOUN
afs-72028	245	6	.	.	PUNCT
afs-72028	246	1	611	611	NUM
afs-72028	246	2	p.	p.	PROPN
afs-72028	246	3	new	new	PROPN
afs-72028	246	4	york	york	PROPN
afs-72028	246	5	.	.	PUNCT
afs-72028	247	1	hartikainen	hartikainen	PROPN
afs-72028	247	2	,	,	PUNCT
afs-72028	247	3	h.	h.	PROPN
afs-72028	247	4	1979	1979	NUM
afs-72028	247	5	.	.	PUNCT
afs-72028	248	1	phosphorus	phosphorus	NOUN
afs-72028	248	2	and	and	CCONJ
afs-72028	248	3	its	its	PRON
afs-72028	248	4	reactions	reaction	NOUN
afs-72028	248	5	in	in	ADP
afs-72028	248	6	terrestrial	terrestrial	ADJ
afs-72028	248	7	soils	soil	NOUN
afs-72028	248	8	and	and	CCONJ
afs-72028	248	9	lake	lake	NOUN
afs-72028	248	10	sediments	sediment	NOUN
afs-72028	248	11	.	.	PUNCT
afs-72028	249	1	j.	j.	PROPN
afs-72028	249	2	scient	scient	PROPN
afs-72028	249	3	.	.	PUNCT
afs-72028	250	1	agric	agric	PROPN
afs-72028	250	2	.	.	PUNCT
afs-72028	250	3	soc	soc	PROPN
afs-72028	250	4	.	.	PUNCT
afs-72028	251	1	finl	finl	NOUN
afs-72028	251	2	.	.	PUNCT
afs-72028	252	1	51:537	51:537	NUM
afs-72028	252	2	624	624	NUM
afs-72028	252	3	.	.	PUNCT
afs-72028	253	1	kingston	kingston	PROPN
afs-72028	253	2	,	,	PUNCT
afs-72028	253	3	f.	f.	PROPN
afs-72028	253	4	j.	j.	PROPN
afs-72028	253	5	,	,	PUNCT
afs-72028	253	6	atkinson	atkinson	PROPN
afs-72028	253	7	,	,	PUNCT
afs-72028	253	8	r.	r.	PROPN
afs-72028	253	9	j.	j.	PROPN
afs-72028	253	10	,	,	PUNCT
afs-72028	253	11	posner	posner	NOUN
afs-72028	253	12	,	,	PUNCT
afs-72028	253	13	a.	a.	NOUN
afs-72028	253	14	m.	m.	PROPN
afs-72028	253	15	&	&	CCONJ
afs-72028	253	16	quirk	quirk	PROPN
afs-72028	253	17	,	,	PUNCT
afs-72028	253	18	j.	j.	PROPN
afs-72028	253	19	p.	p.	PROPN
afs-72028	253	20	1968	1968	NUM
afs-72028	253	21	.	.	PUNCT
afs-72028	254	1	specific	specific	ADJ
afs-72028	254	2	adsorption	adsorption	NOUN
afs-72028	254	3	of	of	ADP
afs-72028	254	4	anions	anion	NOUN
afs-72028	254	5	on	on	ADP
afs-72028	254	6	goethite	goethite	NOUN
afs-72028	254	7	.	.	PUNCT
afs-72028	255	1	trans	trans	PROPN
afs-72028	255	2	.	.	PUNCT
afs-72028	256	1	9th	9th	ADJ
afs-72028	256	2	intern	intern	NOUN
afs-72028	256	3	.	.	PUNCT
afs-72028	257	1	gongr	gongr	NOUN
afs-72028	257	2	.	.	PUNCT
afs-72028	258	1	soil	soil	PROPN
afs-72028	258	2	sci	sci	PROPN
afs-72028	258	3	.	.	PUNCT
afs-72028	259	1	i	i	PRON
afs-72028	259	2	:	:	PUNCT
afs-72028	259	3	669—678	669—678	X
afs-72028	259	4	.	.	PUNCT
afs-72028	259	5	,	,	PUNCT
afs-72028	259	6	posner	posner	NOUN
afs-72028	259	7	,	,	PUNCT
afs-72028	259	8	a.	a.	NOUN
afs-72028	259	9	m.	m.	PROPN
afs-72028	259	10	&	&	CCONJ
afs-72028	259	11	quirk	quirk	PROPN
afs-72028	259	12	,	,	PUNCT
afs-72028	259	13	j.	j.	PROPN
afs-72028	259	14	p.	p.	PROPN
afs-72028	259	15	1972	1972	NUM
afs-72028	259	16	.	.	PUNCT
afs-72028	260	1	anion	anion	NOUN
afs-72028	260	2	adsorption	adsorption	NOUN
afs-72028	260	3	by	by	ADP
afs-72028	260	4	goethite	goethite	NOUN
afs-72028	260	5	and	and	CCONJ
afs-72028	260	6	gibbsite	gibbsite	ADJ
afs-72028	260	7	.	.	PUNCT
afs-72028	261	1	i.	i.	NOUN
afs-72028	261	2	the	the	DET
afs-72028	261	3	role	role	NOUN
afs-72028	261	4	of	of	ADP
afs-72028	261	5	the	the	DET
afs-72028	261	6	proton	proton	NOUN
afs-72028	261	7	in	in	ADP
afs-72028	261	8	determining	determine	VERB
afs-72028	261	9	adsorption	adsorption	NOUN
afs-72028	261	10	envelopes	envelope	NOUN
afs-72028	261	11	.	.	PUNCT
afs-72028	262	1	j.	j.	PROPN
afs-72028	262	2	soil	soil	PROPN
afs-72028	262	3	sci	sci	PROPN
afs-72028	262	4	.	.	PROPN
afs-72028	263	1	23	23	NUM
afs-72028	263	2	:	:	SYM
afs-72028	263	3	177	177	NUM
afs-72028	263	4	192	192	NUM
afs-72028	263	5	.	.	PUNCT
afs-72028	263	6	,	,	PUNCT
afs-72028	263	7	posner	posner	NOUN
afs-72028	263	8	,	,	PUNCT
afs-72028	263	9	a.	a.	NOUN
afs-72028	263	10	m.	m.	PROPN
afs-72028	263	11	&	&	CCONJ
afs-72028	263	12	quirk	quirk	PROPN
afs-72028	263	13	,	,	PUNCT
afs-72028	263	14	j.	j.	PROPN
afs-72028	263	15	p.	p.	PROPN
afs-72028	263	16	1974	1974	NUM
afs-72028	263	17	.	.	PUNCT
afs-72028	264	1	anion	anion	NOUN
afs-72028	264	2	adsorption	adsorption	NOUN
afs-72028	264	3	by	by	ADP
afs-72028	264	4	goethite	goethite	NOUN
afs-72028	264	5	and	and	CCONJ
afs-72028	264	6	gibbsite	gibbsite	ADJ
afs-72028	264	7	.	.	PUNCT
afs-72028	265	1	11	11	NUM
afs-72028	265	2	.	.	PUNCT
afs-72028	266	1	desorption	desorption	NOUN
afs-72028	266	2	of	of	ADP
afs-72028	266	3	anions	anion	NOUN
afs-72028	266	4	from	from	ADP
afs-72028	266	5	hydrous	hydrous	ADJ
afs-72028	266	6	oxide	oxide	NOUN
afs-72028	266	7	surfaces	surface	NOUN
afs-72028	266	8	.	.	PUNCT
afs-72028	267	1	j.	j.	PROPN
afs-72028	267	2	soil	soil	PROPN
afs-72028	267	3	sci	sci	PROPN
afs-72028	267	4	.	.	PUNCT
afs-72028	268	1	25	25	NUM
afs-72028	268	2	:	:	PUNCT
afs-72028	268	3	16	16	NUM
afs-72028	268	4	26	26	NUM
afs-72028	268	5	.	.	PUNCT
afs-72028	268	6	&	&	CCONJ
afs-72028	268	7	raupach	raupach	PROPN
afs-72028	268	8	,	,	PUNCT
afs-72028	268	9	f.	f.	PROPN
afs-72028	268	10	j.	j.	PROPN
afs-72028	268	11	1967	1967	NUM
afs-72028	268	12	.	.	PUNCT
afs-72028	269	1	the	the	DET
afs-72028	269	2	reaction	reaction	NOUN
afs-72028	269	3	between	between	ADP
afs-72028	269	4	monosilicic	monosilicic	NOUN
afs-72028	269	5	acid	acid	NOUN
afs-72028	269	6	and	and	CCONJ
afs-72028	269	7	aluminium	aluminium	NOUN
afs-72028	269	8	hydroxide	hydroxide	NOUN
afs-72028	269	9	.	.	PUNCT
afs-72028	270	1	1	1	X
afs-72028	270	2	.	.	PUNCT
afs-72028	270	3	kinetics	kinetic	NOUN
afs-72028	270	4	of	of	ADP
afs-72028	270	5	adsorption	adsorption	NOUN
afs-72028	270	6	of	of	ADP
afs-72028	270	7	silicic	silicic	NOUN
afs-72028	270	8	acid	acid	NOUN
afs-72028	270	9	by	by	ADP
afs-72028	270	10	aluminium	aluminium	NOUN
afs-72028	270	11	hydroxide	hydroxide	NOUN
afs-72028	270	12	.	.	PUNCT
afs-72028	271	1	aust	aust	PROPN
afs-72028	271	2	.	.	PUNCT
afs-72028	272	1	j.	j.	PROPN
afs-72028	272	2	soil	soil	PROPN
afs-72028	272	3	res	re	NOUN
afs-72028	272	4	.	.	PUNCT
afs-72028	273	1	5:295	5:295	NUM
afs-72028	273	2	-	-	SYM
afs-72028	273	3	309	309	NUM
afs-72028	273	4	.	.	PUNCT
afs-72028	274	1	hunt	hunt	NOUN
afs-72028	274	2	,	,	PUNCT
afs-72028	274	3	j.	j.	PROPN
afs-72028	274	4	p.	p.	PROPN
afs-72028	274	5	1963	1963	NUM
afs-72028	274	6	.	.	PUNCT
afs-72028	275	1	metal	metal	NOUN
afs-72028	275	2	ions	ion	NOUN
afs-72028	275	3	in	in	ADP
afs-72028	275	4	aqueous	aqueous	ADJ
afs-72028	275	5	solution	solution	NOUN
afs-72028	275	6	.	.	PUNCT
afs-72028	276	1	121	121	NUM
afs-72028	276	2	p.	p.	PROPN
afs-72028	276	3	new	new	PROPN
afs-72028	276	4	york	york	PROPN
afs-72028	276	5	.	.	PUNCT
afs-72028	277	1	jackson	jackson	PROPN
afs-72028	277	2	,	,	PUNCT
afs-72028	277	3	m.	m.	PROPN
afs-72028	277	4	l.	l.	PROPN
afs-72028	277	5	1960	1960	NUM
afs-72028	277	6	.	.	PUNCT
afs-72028	278	1	structural	structural	ADJ
afs-72028	278	2	role	role	NOUN
afs-72028	278	3	of	of	ADP
afs-72028	278	4	hydronium	hydronium	NOUN
afs-72028	278	5	in	in	ADP
afs-72028	278	6	layer	layer	NOUN
afs-72028	278	7	silicates	silicate	NOUN
afs-72028	278	8	during	during	ADP
afs-72028	278	9	soil	soil	NOUN
afs-72028	278	10	genesis	genesis	NOUN
afs-72028	278	11	.	.	PUNCT
afs-72028	279	1	trans	trans	PROPN
afs-72028	279	2	,	,	PUNCT
afs-72028	279	3	7th	7th	ADJ
afs-72028	279	4	intern	intern	NOUN
afs-72028	279	5	.	.	PUNCT
afs-72028	279	6	congr	congr	NOUN
afs-72028	279	7	.	.	PUNCT
afs-72028	280	1	soil	soil	PROPN
afs-72028	280	2	sci	sci	PROPN
afs-72028	280	3	.	.	PROPN
afs-72028	280	4	11:445—455	11:445—455	NUM
afs-72028	280	5	.	.	PUNCT
afs-72028	281	1	murphy	murphy	PROPN
afs-72028	281	2	,	,	PUNCT
afs-72028	281	3	p.	p.	PROPN
afs-72028	281	4	j.	j.	PROPN
afs-72028	281	5	,	,	PUNCT
afs-72028	281	6	posner	posner	NOUN
afs-72028	281	7	,	,	PUNCT
afs-72028	281	8	a.	a.	NOUN
afs-72028	281	9	m.	m.	PROPN
afs-72028	281	10	&	&	CCONJ
afs-72028	281	11	quirk	quirk	PROPN
afs-72028	281	12	,	,	PUNCT
afs-72028	281	13	j.	j.	PROPN
afs-72028	281	14	p.	p.	PROPN
afs-72028	281	15	1975	1975	NUM
afs-72028	281	16	.	.	PUNCT
afs-72028	282	1	chemistry	chemistry	NOUN
afs-72028	282	2	of	of	ADP
afs-72028	282	3	iron	iron	NOUN
afs-72028	282	4	in	in	ADP
afs-72028	282	5	soils	soil	NOUN
afs-72028	282	6	.	.	PUNCT
afs-72028	283	1	ferric	ferric	ADJ
afs-72028	283	2	hydrolysis	hydrolysis	NOUN
afs-72028	283	3	products	product	NOUN
afs-72028	283	4	.	.	PUNCT
afs-72028	284	1	aust	aust	PROPN
afs-72028	284	2	.	.	PUNCT
afs-72028	285	1	j.	j.	PROPN
afs-72028	285	2	soil	soil	PROPN
afs-72028	285	3	res	re	NOUN
afs-72028	285	4	.	.	PUNCT
afs-72028	286	1	13	13	NUM
afs-72028	286	2	:	:	SYM
afs-72028	286	3	189	189	NUM
afs-72028	286	4	201	201	NUM
afs-72028	286	5	.	.	PUNCT
afs-72028	287	1	nye	nye	NOUN
afs-72028	287	2	,	,	PUNCT
afs-72028	287	3	p.	p.	PROPN
afs-72028	287	4	h.	h.	PROPN
afs-72028	287	5	&	&	CCONJ
afs-72028	287	6	tinker	tinker	PROPN
afs-72028	287	7	,	,	PUNCT
afs-72028	287	8	p.	p.	PROPN
afs-72028	287	9	b	b	PROPN
afs-72028	287	10	,	,	PUNCT
afs-72028	287	11	1977	1977	NUM
afs-72028	287	12	.	.	PUNCT
afs-72028	288	1	solute	solute	PROPN
afs-72028	288	2	movement	movement	NOUN
afs-72028	288	3	in	in	ADP
afs-72028	288	4	the	the	DET
afs-72028	288	5	soil	soil	NOUN
afs-72028	288	6	root	root	NOUN
afs-72028	288	7	system	system	NOUN
afs-72028	288	8	.	.	PUNCT
afs-72028	289	1	342	342	NUM
afs-72028	289	2	p.	p.	NOUN
afs-72028	289	3	oxford	oxford	NOUN
afs-72028	289	4	,	,	PUNCT
afs-72028	289	5	parfitt	parfitt	NOUN
afs-72028	289	6	,	,	PUNCT
afs-72028	289	7	g.	g.	PROPN
afs-72028	289	8	d.	d.	PROPN
afs-72028	289	9	1971	1971	NUM
afs-72028	289	10	.	.	PUNCT
afs-72028	290	1	introductory	introductory	ADJ
afs-72028	290	2	lecture	lecture	NOUN
afs-72028	290	3	.	.	PUNCT
afs-72028	291	1	discussions	discussion	NOUN
afs-72028	291	2	of	of	ADP
afs-72028	291	3	faraday	faraday	PROPN
afs-72028	291	4	soc	soc	PROPN
afs-72028	291	5	.	.	PUNCT
afs-72028	292	1	52	52	NUM
afs-72028	292	2	:	:	SYM
afs-72028	292	3	9	9	NUM
afs-72028	292	4	13	13	NUM
afs-72028	292	5	.	.	PUNCT
afs-72028	293	1	parfitt	parfitt	NOUN
afs-72028	293	2	,	,	PUNCT
afs-72028	293	3	r	r	PROPN
afs-72028	293	4	,	,	PUNCT
afs-72028	293	5	l.	l.	PROPN
afs-72028	293	6	,	,	PUNCT
afs-72028	293	7	atkinson	atkinson	PROPN
afs-72028	293	8	,	,	PUNCT
afs-72028	293	9	r.	r.	PROPN
afs-72028	293	10	j.	j.	PROPN
afs-72028	293	11	&	&	CCONJ
afs-72028	293	12	smart	smart	PROPN
afs-72028	293	13	,	,	PUNCT
afs-72028	293	14	r.	r.	PROPN
afs-72028	293	15	c.	c.	PROPN
afs-72028	293	16	1975	1975	NUM
afs-72028	293	17	.	.	PUNCT
afs-72028	294	1	the	the	DET
afs-72028	294	2	mechanisms	mechanism	NOUN
afs-72028	294	3	of	of	ADP
afs-72028	294	4	phosphate	phosphate	ADJ
afs-72028	294	5	fixation	fixation	NOUN
afs-72028	294	6	by	by	ADP
afs-72028	294	7	iron	iron	NOUN
afs-72028	294	8	oxides	oxide	NOUN
afs-72028	294	9	.	.	PUNCT
afs-72028	295	1	soil	soil	NOUN
afs-72028	295	2	sei	sei	PROPN
afs-72028	295	3	.	.	PUNCT
afs-72028	295	4	soc	soc	PROPN
afs-72028	295	5	.	.	PUNCT
afs-72028	296	1	amer	amer	PROPN
afs-72028	296	2	.	.	PUNCT
afs-72028	297	1	proc	proc	PROPN
afs-72028	297	2	.	.	PUNCT
afs-72028	298	1	39	39	NUM
afs-72028	298	2	:	:	PUNCT
afs-72028	298	3	837	837	NUM
afs-72028	298	4	841	841	NUM
afs-72028	298	5	.	.	PUNCT
afs-72028	298	6	&	&	CCONJ
afs-72028	298	7	smart	smart	PROPN
afs-72028	298	8	,	,	PUNCT
afs-72028	298	9	r.	r.	PROPN
afs-72028	298	10	c.	c.	PROPN
afs-72028	298	11	1978	1978	NUM
afs-72028	298	12	.	.	PUNCT
afs-72028	299	1	the	the	DET
afs-72028	299	2	mechanism	mechanism	NOUN
afs-72028	299	3	of	of	ADP
afs-72028	299	4	sulfate	sulfate	NOUN
afs-72028	299	5	adsorption	adsorption	NOUN
afs-72028	299	6	on	on	ADP
afs-72028	299	7	iron	iron	NOUN
afs-72028	299	8	oxides	oxide	NOUN
afs-72028	299	9	.	.	PUNCT
afs-72028	300	1	soil	soil	PROPN
afs-72028	300	2	sci	sci	PROPN
afs-72028	300	3	.	.	PUNCT
afs-72028	300	4	soc	soc	PROPN
afs-72028	300	5	.	.	PUNCT
afs-72028	301	1	amer	amer	PROPN
afs-72028	301	2	.	.	PUNCT
afs-72028	302	1	j.	j.	PROPN
afs-72028	302	2	42	42	NUM
afs-72028	302	3	:	:	PUNCT
afs-72028	302	4	48	48	NUM
afs-72028	302	5	50	50	NUM
afs-72028	302	6	.	.	PUNCT
afs-72028	303	1	pearson	pearson	PROPN
afs-72028	303	2	,	,	PUNCT
afs-72028	303	3	r.	r.	PROPN
afs-72028	303	4	g.	g.	PROPN
afs-72028	303	5	1966	1966	NUM
afs-72028	303	6	.	.	PUNCT
afs-72028	304	1	acids	acid	NOUN
afs-72028	304	2	and	and	CCONJ
afs-72028	304	3	bases	basis	NOUN
afs-72028	304	4	.	.	PUNCT
afs-72028	305	1	science	science	NOUN
afs-72028	305	2	151	151	NUM
afs-72028	305	3	:	:	PUNCT
afs-72028	305	4	172—177	172—177	NUM
afs-72028	305	5	.	.	PUNCT
afs-72028	306	1	rajan	rajan	PROPN
afs-72028	306	2	,	,	PUNCT
afs-72028	306	3	s.	s.	PROPN
afs-72028	306	4	s.	s.	PROPN
afs-72028	306	5	s.	s.	PROPN
afs-72028	306	6	1978	1978	NUM
afs-72028	306	7	.	.	PUNCT
afs-72028	307	1	sulfate	sulfate	NOUN
afs-72028	307	2	adsorbed	adsorb	VERB
afs-72028	307	3	on	on	ADP
afs-72028	307	4	hydrous	hydrous	ADJ
afs-72028	307	5	alumina	alumina	NOUN
afs-72028	307	6	,	,	PUNCT
afs-72028	307	7	ligands	ligand	NOUN
afs-72028	307	8	displaced	displace	VERB
afs-72028	307	9	,	,	PUNCT
afs-72028	307	10	and	and	CCONJ
afs-72028	307	11	changes	change	NOUN
afs-72028	307	12	in	in	ADP
afs-72028	307	13	surface	surface	NOUN
afs-72028	307	14	charge	charge	NOUN
afs-72028	307	15	.	.	PUNCT
afs-72028	308	1	soil	soil	NOUN
afs-72028	308	2	sei	sei	PROPN
afs-72028	308	3	.	.	PUNCT
afs-72028	308	4	soc	soc	PROPN
afs-72028	308	5	.	.	PUNCT
afs-72028	309	1	amer	amer	PROPN
afs-72028	309	2	.	.	PUNCT
afs-72028	310	1	j.	j.	PROPN
afs-72028	310	2	42	42	NUM
afs-72028	310	3	;	;	PUNCT
afs-72028	310	4	39—44	39—44	NUM
afs-72028	310	5	.	.	NOUN
afs-72028	310	6	1979	1979	NUM
afs-72028	310	7	.	.	PUNCT
afs-72028	311	1	adsorption	adsorption	NOUN
afs-72028	311	2	and	and	CCONJ
afs-72028	311	3	desorption	desorption	NOUN
afs-72028	311	4	of	of	ADP
afs-72028	311	5	sulfate	sulfate	NOUN
afs-72028	311	6	and	and	CCONJ
afs-72028	311	7	charge	charge	NOUN
afs-72028	311	8	relationships	relationship	NOUN
afs-72028	311	9	in	in	ADP
afs-72028	311	10	allophanic	allophanic	ADJ
afs-72028	311	11	clays	clay	NOUN
afs-72028	311	12	.	.	PUNCT
afs-72028	312	1	soil	soil	NOUN
afs-72028	312	2	sei	sei	PROPN
afs-72028	312	3	.	.	PUNCT
afs-72028	312	4	soc	soc	PROPN
afs-72028	312	5	.	.	PUNCT
afs-72028	313	1	amer	amer	PROPN
afs-72028	313	2	.	.	PUNCT
afs-72028	314	1	j.	j.	PROPN
afs-72028	314	2	43	43	NUM
afs-72028	314	3	:	:	PUNCT
afs-72028	314	4	65	65	NUM
afs-72028	314	5	69	69	NUM
afs-72028	314	6	.	.	PUNCT
afs-72028	314	7	,	,	PUNCT
afs-72028	314	8	perrot	perrot	PROPN
afs-72028	314	9	,	,	PUNCT
afs-72028	314	10	k.	k.	PROPN
afs-72028	314	11	w.	w.	PROPN
afs-72028	314	12	&	&	CCONJ
afs-72028	314	13	saunders	saunders	PROPN
afs-72028	314	14	,	,	PUNCT
afs-72028	314	15	w.	w.	PROPN
afs-72028	314	16	m	m	PROPN
afs-72028	314	17	,	,	PUNCT
afs-72028	314	18	h.	h.	PROPN
afs-72028	314	19	1974	1974	NUM
afs-72028	314	20	.	.	PUNCT
afs-72028	315	1	identification	identification	NOUN
afs-72028	315	2	of	of	ADP
afs-72028	315	3	phosphate	phosphate	ADJ
afs-72028	315	4	-	-	PUNCT
afs-72028	315	5	reactive	reactive	ADJ
afs-72028	315	6	sites	site	NOUN
afs-72028	315	7	of	of	ADP
afs-72028	315	8	hydrous	hydrous	ADJ
afs-72028	315	9	alumina	alumina	NOUN
afs-72028	315	10	from	from	ADP
afs-72028	315	11	proton	proton	NOUN
afs-72028	315	12	consumption	consumption	NOUN
afs-72028	315	13	during	during	ADP
afs-72028	315	14	phosphate	phosphate	ADJ
afs-72028	315	15	adsorption	adsorption	NOUN
afs-72028	315	16	at	at	ADP
afs-72028	315	17	constant	constant	ADJ
afs-72028	315	18	ph	ph	ADJ
afs-72028	315	19	values	value	NOUN
afs-72028	315	20	.	.	PUNCT
afs-72028	316	1	j.	j.	PROPN
afs-72028	316	2	soil	soil	PROPN
afs-72028	316	3	sci	sci	PROPN
afs-72028	316	4	.	.	PUNCT
afs-72028	316	5	25:438—447	25:438—447	NUM
afs-72028	316	6	.	.	PUNCT
afs-72028	316	7	reyes	reyes	PROPN
afs-72028	316	8	,	,	PUNCT
afs-72028	316	9	e.	e.	PROPN
afs-72028	316	10	d.	d.	PROPN
afs-72028	316	11	&	&	CCONJ
afs-72028	316	12	jurinak	jurinak	PROPN
afs-72028	316	13	,	,	PUNCT
afs-72028	316	14	j.	j.	PROPN
afs-72028	316	15	j.	j.	PROPN
afs-72028	316	16	1967	1967	NUM
afs-72028	316	17	.	.	PUNCT
afs-72028	317	1	a	a	DET
afs-72028	317	2	mechanism	mechanism	NOUN
afs-72028	317	3	of	of	ADP
afs-72028	317	4	molybdate	molybdate	ADJ
afs-72028	317	5	adsorption	adsorption	NOUN
afs-72028	317	6	on	on	ADP
afs-72028	317	7	a	a	DET
afs-72028	317	8	-	-	PUNCT
afs-72028	317	9	fc203	fc203	NOUN
afs-72028	317	10	.	.	PUNCT
afs-72028	318	1	soil	soil	NOUN
afs-72028	318	2	sei	sei	PROPN
afs-72028	318	3	.	.	PUNCT
afs-72028	318	4	soc	soc	PROPN
afs-72028	318	5	.	.	PUNCT
afs-72028	319	1	amer	amer	PROPN
afs-72028	319	2	.	.	PUNCT
afs-72028	320	1	proc	proc	PROPN
afs-72028	320	2	.	.	PUNCT
afs-72028	321	1	31:637	31:637	NUM
afs-72028	321	2	640	640	NUM
afs-72028	321	3	.	.	PUNCT
afs-72028	322	1	rossini	rossini	PROPN
afs-72028	322	2	,	,	PUNCT
afs-72028	322	3	f.	f.	PROPN
afs-72028	322	4	r.	r.	PROPN
afs-72028	322	5	,	,	PUNCT
afs-72028	322	6	wagman	wagman	PROPN
afs-72028	322	7	,	,	PUNCT
afs-72028	322	8	d.	d.	PROPN
afs-72028	322	9	d.	d.	PROPN
afs-72028	322	10	,	,	PUNCT
afs-72028	322	11	evans	evans	PROPN
afs-72028	322	12	,	,	PUNCT
afs-72028	322	13	w.	w.	PROPN
afs-72028	322	14	h.	h.	PROPN
afs-72028	322	15	,	,	PUNCT
afs-72028	322	16	levine	levine	PROPN
afs-72028	322	17	,	,	PUNCT
afs-72028	322	18	s.	s.	PROPN
afs-72028	322	19	&	&	CCONJ
afs-72028	322	20	jakke	jakke	PROPN
afs-72028	322	21	,	,	PUNCT
afs-72028	322	22	i.	i.	PROPN
afs-72028	322	23	1952	1952	NUM
afs-72028	322	24	.	.	PUNCT
afs-72028	323	1	selected	select	VERB
afs-72028	323	2	values	value	NOUN
afs-72028	323	3	of	of	ADP
afs-72028	323	4	chemical	chemical	ADJ
afs-72028	323	5	thermodynamic	thermodynamic	ADJ
afs-72028	323	6	properties	property	NOUN
afs-72028	323	7	.	.	PUNCT
afs-72028	324	1	1267	1267	NUM
afs-72028	324	2	p.	p.	PROPN
afs-72028	324	3	washington	washington	PROPN
afs-72028	324	4	.	.	PUNCT
afs-72028	325	1	44	44	NUM
afs-72028	325	2	sasaki	sasaki	PROPN
afs-72028	325	3	,	,	PUNCT
afs-72028	325	4	y.	y.	PROPN
afs-72028	325	5	,	,	PUNCT
afs-72028	325	6	lindqvist	lindqvist	NOUN
afs-72028	325	7	,	,	PUNCT
afs-72028	325	8	i.	i.	PROPN
afs-72028	325	9	&	&	CCONJ
afs-72028	325	10	sillen	sillen	PROPN
afs-72028	325	11	,	,	PUNCT
afs-72028	325	12	l.	l.	PROPN
afs-72028	325	13	g.	g.	PROPN
afs-72028	325	14	1959	1959	NUM
afs-72028	325	15	.	.	PUNCT
afs-72028	326	1	on	on	ADP
afs-72028	326	2	the	the	DET
afs-72028	326	3	first	first	ADJ
afs-72028	326	4	equilibrium	equilibrium	NOUN
afs-72028	326	5	steps	step	NOUN
afs-72028	326	6	in	in	ADP
afs-72028	326	7	the	the	DET
afs-72028	326	8	acidification	acidification	NOUN
afs-72028	326	9	of	of	ADP
afs-72028	326	10	the	the	DET
afs-72028	326	11	molybdate	molybdate	ADJ
afs-72028	326	12	ion	ion	NOUN
afs-72028	326	13	.	.	PUNCT
afs-72028	327	1	j.	j.	PROPN
afs-72028	327	2	inorg	inorg	PROPN
afs-72028	327	3	,	,	PUNCT
afs-72028	327	4	nuc	nuc	PROPN
afs-72028	327	5	.	.	PROPN
afs-72028	327	6	chem	chem	PROPN
afs-72028	327	7	.	.	PUNCT
afs-72028	328	1	9	9	NUM
afs-72028	328	2	;	;	PUNCT
afs-72028	328	3	93	93	NUM
afs-72028	328	4	94	94	NUM
afs-72028	328	5	.	.	PUNCT
afs-72028	329	1	schnitzer	schnitzer	PROPN
afs-72028	329	2	,	,	PUNCT
afs-72028	329	3	m.	m.	NOUN
afs-72028	329	4	1978	1978	NUM
afs-72028	329	5	.	.	PUNCT
afs-72028	330	1	humic	humic	ADJ
afs-72028	330	2	substances	substance	NOUN
afs-72028	330	3	:	:	PUNCT
afs-72028	330	4	chemistry	chemistry	NOUN
afs-72028	330	5	and	and	CCONJ
afs-72028	330	6	reactions	reaction	NOUN
afs-72028	330	7	.	.	PUNCT
afs-72028	331	1	in	in	ADP
afs-72028	331	2	schenitzer	schenitzer	NOUN
afs-72028	331	3	,	,	PUNCT
afs-72028	331	4	m.	m.	NOUN
afs-72028	331	5	&	&	CCONJ
afs-72028	331	6	khan	khan	PROPN
afs-72028	331	7	,	,	PUNCT
afs-72028	331	8	s.	s.	PROPN
afs-72028	331	9	u.	u.	PROPN
afs-72028	331	10	(	(	PUNCT
afs-72028	331	11	ed	ed	NOUN
afs-72028	331	12	.	.	PUNCT
afs-72028	331	13	)	)	PUNCT
afs-72028	332	1	soil	soil	NOUN
afs-72028	332	2	organic	organic	ADJ
afs-72028	332	3	matter	matter	NOUN
afs-72028	332	4	.	.	PUNCT
afs-72028	333	1	development	development	NOUN
afs-72028	333	2	in	in	ADP
afs-72028	333	3	soil	soil	NOUN
afs-72028	333	4	science	science	NOUN
afs-72028	333	5	8	8	NUM
afs-72028	333	6	;	;	PUNCT
afs-72028	333	7	1	1	NUM
afs-72028	333	8	58	58	NUM
afs-72028	333	9	.	.	PUNCT
afs-72028	334	1	319	319	NUM
afs-72028	334	2	p.	p.	NOUN
afs-72028	334	3	oxford	oxford	PROPN
afs-72028	334	4	.	.	PUNCT
afs-72028	334	5	&	&	CCONJ
afs-72028	334	6	skinner	skinner	PROPN
afs-72028	334	7	,	,	PUNCT
afs-72028	334	8	s.	s.	PROPN
afs-72028	334	9	i.	i.	PROPN
afs-72028	334	10	m.	m.	PROPN
afs-72028	334	11	1963	1963	NUM
afs-72028	334	12	.	.	PUNCT
afs-72028	335	1	organo	organo	ADJ
afs-72028	335	2	-	-	ADJ
afs-72028	335	3	metallic	metallic	ADJ
afs-72028	335	4	interactions	interaction	NOUN
afs-72028	335	5	in	in	ADP
afs-72028	335	6	soils	soil	NOUN
afs-72028	335	7	:	:	PUNCT
afs-72028	335	8	2	2	X
afs-72028	335	9	.	.	X
afs-72028	335	10	reactions	reaction	NOUN
afs-72028	335	11	between	between	ADP
afs-72028	335	12	different	different	ADJ
afs-72028	335	13	forms	form	NOUN
afs-72028	335	14	of	of	ADP
afs-72028	335	15	iron	iron	NOUN
afs-72028	335	16	and	and	CCONJ
afs-72028	335	17	aluminium	aluminium	NOUN
afs-72028	335	18	and	and	CCONJ
afs-72028	335	19	the	the	DET
afs-72028	335	20	organic	organic	ADJ
afs-72028	335	21	matter	matter	NOUN
afs-72028	335	22	of	of	ADP
afs-72028	335	23	a	a	DET
afs-72028	335	24	podzol	podzol	ADJ
afs-72028	335	25	bh	bh	NOUN
afs-72028	335	26	horizon	horizon	NOUN
afs-72028	335	27	.	.	PUNCT
afs-72028	336	1	soil	soil	PROPN
afs-72028	336	2	sci	sci	PROPN
afs-72028	336	3	.	.	PROPN
afs-72028	337	1	96	96	NUM
afs-72028	337	2	;	;	PUNCT
afs-72028	337	3	181	181	NUM
afs-72028	337	4	-	-	SYM
afs-72028	337	5	186	186	NUM
afs-72028	337	6	.	.	PUNCT
afs-72028	337	7	&	&	CCONJ
afs-72028	337	8	skinner	skinner	PROPN
afs-72028	337	9	,	,	PUNCT
afs-72028	337	10	s.	s.	PROPN
afs-72028	337	11	i.	i.	PROPN
afs-72028	337	12	m.	m.	PROPN
afs-72028	337	13	1965	1965	NUM
afs-72028	337	14	.	.	PUNCT
afs-72028	338	1	organo	organo	ADJ
afs-72028	338	2	-	-	ADJ
afs-72028	338	3	metallic	metallic	ADJ
afs-72028	338	4	interactions	interaction	NOUN
afs-72028	338	5	in	in	ADP
afs-72028	338	6	soils	soil	NOUN
afs-72028	338	7	:	:	PUNCT
afs-72028	338	8	4	4	NUM
afs-72028	338	9	.	.	NOUN
afs-72028	338	10	carboxyl	carboxyl	NOUN
afs-72028	338	11	and	and	CCONJ
afs-72028	338	12	hydroxyl	hydroxyl	NOUN
afs-72028	338	13	groups	group	NOUN
afs-72028	338	14	in	in	ADP
afs-72028	338	15	organic	organic	ADJ
afs-72028	338	16	matter	matter	NOUN
afs-72028	338	17	and	and	CCONJ
afs-72028	338	18	metal	metal	NOUN
afs-72028	338	19	retention	retention	NOUN
afs-72028	338	20	.	.	PUNCT
afs-72028	339	1	soil	soil	PROPN
afs-72028	339	2	sci	sci	PROPN
afs-72028	339	3	.	.	PROPN
afs-72028	340	1	99	99	NUM
afs-72028	340	2	:	:	PUNCT
afs-72028	340	3	278	278	NUM
afs-72028	340	4	284	284	NUM
afs-72028	340	5	.	.	PUNCT
afs-72028	341	1	serna	serna	PROPN
afs-72028	341	2	,	,	PUNCT
afs-72028	341	3	c.	c.	PROPN
afs-72028	341	4	j.	j.	PROPN
afs-72028	341	5	,	,	PUNCT
afs-72028	341	6	white	white	PROPN
afs-72028	341	7	,	,	PUNCT
afs-72028	341	8	j.	j.	PROPN
afs-72028	341	9	l.	l.	PROPN
afs-72028	341	10	&	&	CCONJ
afs-72028	341	11	hem	hem	PROPN
afs-72028	341	12	,	,	PUNCT
afs-72028	341	13	s.	s.	PROPN
afs-72028	341	14	l.	l.	PROPN
afs-72028	341	15	1977	1977	NUM
afs-72028	341	16	.	.	PUNCT
afs-72028	342	1	anion	anion	NOUN
afs-72028	342	2	-	-	PUNCT
afs-72028	342	3	aluminium	aluminium	NOUN
afs-72028	342	4	hydroxide	hydroxide	NOUN
afs-72028	342	5	gel	gel	NOUN
afs-72028	342	6	interactions	interaction	NOUN
afs-72028	342	7	.	.	PUNCT
afs-72028	343	1	soil	soil	NOUN
afs-72028	343	2	sei	sei	PROPN
afs-72028	343	3	.	.	PUNCT
afs-72028	343	4	soc	soc	PROPN
afs-72028	343	5	.	.	PUNCT
afs-72028	344	1	amer	amer	PROPN
afs-72028	344	2	.	.	PUNCT
afs-72028	345	1	j.	j.	PROPN
afs-72028	345	2	41	41	NUM
afs-72028	345	3	:	:	SYM
afs-72028	345	4	1009	1009	NUM
afs-72028	345	5	1013	1013	NUM
afs-72028	345	6	.	.	PUNCT
afs-72028	346	1	syers	syer	NOUN
afs-72028	346	2	,	,	PUNCT
afs-72028	346	3	j.	j.	PROPN
afs-72028	346	4	k.	k.	PROPN
afs-72028	346	5	,	,	PUNCT
afs-72028	346	6	browman	browman	NOUN
afs-72028	346	7	,	,	PUNCT
afs-72028	346	8	m.	m.	NOUN
afs-72028	346	9	g.	g.	PROPN
afs-72028	346	10	,	,	PUNCT
afs-72028	346	11	smillie	smillie	PROPN
afs-72028	346	12	,	,	PUNCT
afs-72028	346	13	g.	g.	PROPN
afs-72028	346	14	w.	w.	PROPN
afs-72028	346	15	&	&	CCONJ
afs-72028	346	16	corey	corey	PROPN
afs-72028	346	17	,	,	PUNCT
afs-72028	346	18	r.	r.	PROPN
afs-72028	346	19	b.	b.	PROPN
afs-72028	346	20	1973	1973	NUM
afs-72028	346	21	.	.	PUNCT
afs-72028	347	1	phosphate	phosphate	ADJ
afs-72028	347	2	sorption	sorption	NOUN
afs-72028	347	3	by	by	ADP
afs-72028	347	4	soils	soil	NOUN
afs-72028	347	5	evaluated	evaluate	VERB
afs-72028	347	6	by	by	ADP
afs-72028	347	7	the	the	DET
afs-72028	347	8	langmuir	langmuir	PROPN
afs-72028	347	9	adsorption	adsorption	NOUN
afs-72028	347	10	equation	equation	NOUN
afs-72028	347	11	.	.	PUNCT
afs-72028	348	1	soil	soil	NOUN
afs-72028	348	2	sei	sei	PROPN
afs-72028	348	3	.	.	PUNCT
afs-72028	348	4	soc	soc	PROPN
afs-72028	348	5	.	.	PUNCT
afs-72028	349	1	amer	amer	PROPN
afs-72028	349	2	.	.	PUNCT
afs-72028	350	1	proc	proc	PROPN
afs-72028	350	2	.	.	PUNCT
afs-72028	351	1	37	37	NUM
afs-72028	351	2	;	;	PUNCT
afs-72028	351	3	358	358	NUM
afs-72028	351	4	-	-	SYM
afs-72028	351	5	363	363	NUM
afs-72028	351	6	.	.	PUNCT
afs-72028	352	1	weast	weast	PROPN
afs-72028	352	2	,	,	PUNCT
afs-72028	352	3	r.	r.	PROPN
afs-72028	352	4	c.	c.	PROPN
afs-72028	352	5	1969	1969	NUM
afs-72028	352	6	.	.	PUNCT
afs-72028	353	1	handbook	handbook	NOUN
afs-72028	353	2	of	of	ADP
afs-72028	353	3	chemistry	chemistry	NOUN
afs-72028	353	4	and	and	CCONJ
afs-72028	353	5	physics	physics	NOUN
afs-72028	353	6	.	.	PUNCT
afs-72028	354	1	2356	2356	NUM
afs-72028	354	2	p	p	NOUN
afs-72028	354	3	,	,	PUNCT
afs-72028	354	4	cleveland	cleveland	PROPN
afs-72028	354	5	.	.	PUNCT
afs-72028	355	1	ms	ms	PROPN
afs-72028	355	2	received	receive	VERB
afs-72028	355	3	september	september	PROPN
afs-72028	355	4	24	24	NUM
afs-72028	355	5	,	,	PUNCT
afs-72028	355	6	1979	1979	NUM
afs-72028	355	7	.	.	PUNCT
afs-72028	356	1	selostus	selostus	PROPN
afs-72028	356	2	happi	happi	PROPN
afs-72028	356	3	vaihtuvana	vaihtuvana	PROPN
afs-72028	356	4	ligandina	ligandina	PROPN
afs-72028	356	5	maassa	maassa	PROPN
afs-72028	356	6	erkki	erkki	PROPN
afs-72028	356	7	aura	aura	NOUN
afs-72028	356	8	1	1	NUM
afs-72028	356	9	)	)	PUNCT
afs-72028	356	10	helsingin	helsingin	NOUN
afs-72028	356	11	yliopiston	yliopiston	NOUN
afs-72028	356	12	maanviljelyskemian	maanviljelyskemian	ADJ
afs-72028	356	13	laitos	laito	NOUN
afs-72028	356	14	,	,	PUNCT
afs-72028	356	15	00710	00710	NUM
afs-72028	356	16	helsinki	helsinki	PROPN
afs-72028	356	17	71	71	NUM
afs-72028	356	18	anioninvaihto	anioninvaihto	NOUN
afs-72028	356	19	kuuluu	kuuluu	PROPN
afs-72028	356	20	kuten	kuten	PROPN
afs-72028	356	21	kationinvaihtokin	kationinvaihtokin	PROPN
afs-72028	356	22	maaperäkemian	maaperäkemian	PROPN
afs-72028	356	23	keskeisimpiin	keskeisimpiin	PROPN
afs-72028	356	24	ilmiöihin	ilmiöihin	PROPN
afs-72028	356	25	.	.	PUNCT
afs-72028	357	1	teoreettisen	teoreettisen	PROPN
afs-72028	357	2	tarkastelun	tarkastelun	PROPN
afs-72028	357	3	avulla	avulla	NOUN
afs-72028	357	4	pyrittiin	pyrittiin	NOUN
afs-72028	357	5	selvittämään	selvittämään	PROPN
afs-72028	357	6	eri	eri	PROPN
afs-72028	357	7	happiligandien	happiligandien	PROPN
afs-72028	357	8	pidättymistä	pidättymistä	PROPN
afs-72028	357	9	polymeeristen	polymeeristen	PROPN
afs-72028	357	10	alumiini	alumiini	PROPN
afs-72028	357	11	-	-	PUNCT
afs-72028	357	12	ja	ja	PROPN
afs-72028	357	13	rautaoksidien	rautaoksidien	NOUN
afs-72028	357	14	pinnoille	pinnoille	NOUN
afs-72028	357	15	.	.	PUNCT
afs-72028	358	1	anionin	anionin	PROPN
afs-72028	358	2	sitoutuminen	sitoutuminen	PROPN
afs-72028	358	3	oksidien	oksidien	PROPN
afs-72028	358	4	al3	al3	PROPN
afs-72028	358	5	+	+	CCONJ
afs-72028	358	6	tai	tai	X
afs-72028	358	7	fe	fe	X
afs-72028	358	8	3	3	NUM
afs-72028	358	9	+	+	NUM
afs-72028	358	10	ioneihin	ioneihin	NOUN
afs-72028	358	11	riippuu	riippuu	NOUN
afs-72028	358	12	erityisesti	erityisesti	VERB
afs-72028	358	13	ligandihapen	ligandihapen	PROPN
afs-72028	358	14	kyvystä	kyvystä	PROPN
afs-72028	358	15	luovuttaa	luovuttaa	PROPN
afs-72028	358	16	elektroneja	elektroneja	PROPN
afs-72028	358	17	ligandin	ligandin	VERB
afs-72028	358	18	ja	ja	PROPN
afs-72028	358	19	keskusionin	keskusionin	PROPN
afs-72028	358	20	väliseen	väliseen	PROPN
afs-72028	358	21	sidokseen	sidokseen	NOUN
afs-72028	358	22	.	.	PUNCT
afs-72028	359	1	koska	koska	PROPN
afs-72028	359	2	protoni	protoni	PROPN
afs-72028	359	3	on	on	ADP
afs-72028	359	4	kuten	kuten	PROPN
afs-72028	359	5	al	al	PROPN
afs-72028	359	6	3	3	PROPN
afs-72028	359	7	+	+	SYM
afs-72028	359	8	tai	tai	X
afs-72028	359	9	fe	fe	X
afs-72028	359	10	3	3	NUM
afs-72028	359	11	+	+	NUM
afs-72028	359	12	tyypillinen	tyypillinen	PROPN
afs-72028	359	13	elektronien	elektronien	PROPN
afs-72028	359	14	vastaanottaja	vastaanottaja	PROPN
afs-72028	359	15	eli	eli	PROPN
afs-72028	359	16	lewisin	lewisin	PROPN
afs-72028	359	17	happo	happo	PROPN
afs-72028	359	18	,	,	PUNCT
afs-72028	359	19	anionia	anionia	PROPN
afs-72028	359	20	vastaava	vastaava	PROPN
afs-72028	359	21	happovakio	happovakio	PROPN
afs-72028	359	22	pka	pka	PROPN
afs-72028	359	23	ilmaisee	ilmaisee	PROPN
afs-72028	359	24	anionin	anionin	ADJ
afs-72028	359	25	taipumusta	taipumusta	NOUN
afs-72028	359	26	sitoutua	sitoutua	NOUN
afs-72028	359	27	oksideihin	oksideihin	ADJ
afs-72028	359	28	.	.	PUNCT
afs-72028	360	1	mitä	mitä	PROPN
afs-72028	360	2	helpommin	helpommin	PROPN
afs-72028	360	3	ligandihappi	ligandihappi	PROPN
afs-72028	360	4	luovuttaa	luovuttaa	PROPN
afs-72028	360	5	elektroneja	elektroneja	ADJ
afs-72028	360	6	keskusionille	keskusionille	NOUN
afs-72028	360	7	,	,	PUNCT
afs-72028	360	8	sitä	sitä	ADV
afs-72028	360	9	vahvempi	vahvempi	ADJ
afs-72028	360	10	sidos	sido	NOUN
afs-72028	360	11	muodostuu	muodostuu	VERB
afs-72028	360	12	hapen	hapen	PROPN
afs-72028	360	13	ja	ja	PROPN
afs-72028	360	14	keskusionin	keskusionin	PROPN
afs-72028	360	15	välille	välille	PROPN
afs-72028	360	16	.	.	PUNCT
afs-72028	361	1	vahva	vahva	PROPN
afs-72028	361	2	kovalenttinen	kovalenttinen	PROPN
afs-72028	361	3	sidos	sidos	PROPN
afs-72028	361	4	ei	ei	X
afs-72028	361	5	kuitenkaan	kuitenkaan	PROPN
afs-72028	361	6	merkitse	merkitse	PROPN
afs-72028	361	7	,	,	PUNCT
afs-72028	361	8	että	että	PROPN
afs-72028	361	9	anionin	anionin	PROPN
afs-72028	361	10	adsorptio	adsorptio	PROPN
afs-72028	361	11	oksidien	oksidien	ADJ
afs-72028	361	12	pinnoille	pinnoille	PROPN
afs-72028	361	13	olisi	olisi	ADP
afs-72028	361	14	aina	aina	PROPN
afs-72028	361	15	eksoterminen	eksoterminen	PROPN
afs-72028	361	16	reaktio	reaktio	PROPN
afs-72028	361	17	.	.	PUNCT
afs-72028	362	1	lähinnä	lähinnä	ADJ
afs-72028	362	2	entropiasuhteet	entropiasuhteet	NOUN
afs-72028	362	3	määräävät	määräävät	VERB
afs-72028	362	4	vaihdon	vaihdon	PROPN
afs-72028	362	5	tasapainon	tasapainon	NOUN
afs-72028	362	6	.	.	PUNCT
afs-72028	363	1	esitetty	esitetty	PROPN
afs-72028	363	2	teoria	teoria	PROPN
afs-72028	363	3	selittää	selittää	PROPN
afs-72028	363	4	anionien	anionien	PROPN
afs-72028	363	5	pidättymisen	pidättymisen	PROPN
afs-72028	363	6	ja	ja	PROPN
afs-72028	363	7	ph	ph	PROPN
afs-72028	363	8	:	:	PUNCT
afs-72028	363	9	n	n	PRON
afs-72028	363	10	välisen	välisen	NOUN
afs-72028	363	11	yhteyden	yhteyden	PROPN
afs-72028	363	12	.	.	PUNCT
afs-72028	364	1	pidättyminen	pidättyminen	NOUN
afs-72028	364	2	oksideihin	oksideihin	ADV
afs-72028	364	3	on	on	ADP
afs-72028	364	4	voimakkainta	voimakkainta	ADJ
afs-72028	364	5	,	,	PUNCT
afs-72028	364	6	kun	kun	PROPN
afs-72028	364	7	ph	ph	PROPN
afs-72028	364	8	on	on	ADP
afs-72028	364	9	suunnilleen	suunnilleen	PROPN
afs-72028	364	10	sama	sama	PROPN
afs-72028	364	11	kuin	kuin	PROPN
afs-72028	364	12	anionia	anionia	PROPN
afs-72028	364	13	vastaavan	vastaavan	PROPN
afs-72028	364	14	hapon	hapon	PROPN
afs-72028	364	15	pkaarvo	pkaarvo	NOUN
afs-72028	364	16	.	.	PUNCT
afs-72028	365	1	kun	kun	PROPN
afs-72028	365	2	maan	maan	PROPN
afs-72028	365	3	kanssa	kanssa	PROPN
afs-72028	365	4	tasapainossa	tasapainossa	PROPN
afs-72028	365	5	olevan	olevan	NOUN
afs-72028	365	6	liuoksen	liuoksen	NOUN
afs-72028	365	7	ph	ph	PROPN
afs-72028	365	8	on	on	ADP
afs-72028	365	9	paljon	paljon	NOUN
afs-72028	365	10	alle	alle	NOUN
afs-72028	365	11	pka	pka	PROPN
afs-72028	365	12	-	-	PUNCT
afs-72028	365	13	arvon	arvon	PROPN
afs-72028	365	14	,	,	PUNCT
afs-72028	365	15	anionin	anionin	PROPN
afs-72028	365	16	konsentraatio	konsentraatio	NOUN
afs-72028	366	1	liuoksessa	liuoksessa	NOUN
afs-72028	366	2	on	on	ADP
afs-72028	366	3	hyvin	hyvin	PROPN
afs-72028	366	4	pieni	pieni	PROPN
afs-72028	366	5	,	,	PUNCT
afs-72028	367	1	koska	koska	PROPN
afs-72028	367	2	h+-ioni	h+-ioni	PROPN
afs-72028	367	3	kilpailee	kilpailee	PROPN
afs-72028	367	4	oksidien	oksidien	PROPN
afs-72028	368	1	al	al	PROPN
afs-72028	368	2	3+;n	3+;n	PROPN
afs-72028	368	3	ja	ja	PROPN
afs-72028	368	4	fe	fe	PROPN
afs-72028	368	5	3+:n	3+:n	NUM
afs-72028	368	6	kanssa	kanssa	PROPN
afs-72028	368	7	sitoutumisesta	sitoutumisesta	PROPN
afs-72028	368	8	anioniin	anioniin	NOUN
afs-72028	368	9	.	.	PUNCT
afs-72028	369	1	kun	kun	PROPN
afs-72028	369	2	liuoksen	liuoksen	PROPN
afs-72028	369	3	ph	ph	PROPN
afs-72028	369	4	on	on	ADP
afs-72028	369	5	suunnilleen	suunnilleen	PROPN
afs-72028	369	6	pka	pka	PROPN
afs-72028	369	7	,	,	PUNCT
afs-72028	369	8	happamuuden	happamuuden	ADJ
afs-72028	369	9	väheneminen	väheneminen	NOUN
afs-72028	369	10	lisää	lisää	PROPN
afs-72028	369	11	nopeasti	nopeasti	PROPN
afs-72028	369	12	anionia	anionia	PROPN
afs-72028	369	13	vastaavan	vastaavan	PROPN
afs-72028	369	14	hapon	hapon	NOUN
afs-72028	369	15	dissosioituraisastetta	dissosioituraisastetta	NOUN
afs-72028	369	16	.	.	PUNCT
afs-72028	370	1	kun	kun	PROPN
afs-72028	370	2	ph	ph	PROPN
afs-72028	370	3	on	on	ADP
afs-72028	370	4	paljon	paljon	NOUN
afs-72028	370	5	yli	yli	PROPN
afs-72028	370	6	pkaarvon	pkaarvon	PROPN
afs-72028	370	7	,	,	PUNCT
afs-72028	370	8	anionia	anionia	PROPN
afs-72028	370	9	vastaava	vastaava	PROPN
afs-72028	370	10	happo	happo	PROPN
afs-72028	370	11	on	on	ADP
afs-72028	370	12	lähes	lähe	NOUN
afs-72028	370	13	täysin	täysin	PROPN
afs-72028	370	14	dissoisoitunut	dissoisoitunut	PROPN
afs-72028	370	15	.	.	PUNCT
afs-72028	371	1	kuitenkin	kuitenkin	PROPN
afs-72028	371	2	liuoksen	liuoksen	PROPN
afs-72028	372	1	oh	oh	INTJ
afs-72028	372	2	-	-	PUNCT
afs-72028	372	3	konsentraatio	konsentraatio	NOUN
afs-72028	372	4	kasvaa	kasvaa	PROPN
afs-72028	372	5	edelleen	edelleen	VERB
afs-72028	372	6	ph	ph	VERB
afs-72028	372	7	:	:	PUNCT
afs-72028	372	8	n	n	PRON
afs-72028	372	9	suuretessa	suuretessa	NOUN
afs-72028	372	10	,	,	PUNCT
afs-72028	372	11	mikä	mikä	PROPN
afs-72028	372	12	lisää	lisää	PROPN
afs-72028	373	1	oh	oh	INTJ
afs-72028	373	2	:	:	PUNCT
afs-72028	373	3	n	n	PRON
afs-72028	373	4	pidättymistä	pidättymistä	PROPN
afs-72028	373	5	oksidien	oksidien	PROPN
afs-72028	373	6	pinnalle	pinnalle	NOUN
afs-72028	373	7	,	,	PUNCT
afs-72028	373	8	mutta	mutta	X
afs-72028	373	9	vähentää	vähentää	ADV
afs-72028	373	10	muiden	muiden	PROPN
afs-72028	373	11	anionien	anionien	PROPN
afs-72028	373	12	adsorptiota	adsorptiota	PROPN
afs-72028	373	13	.	.	PUNCT
afs-72028	374	1	ligandihapen	ligandihapen	ADJ
afs-72028	374	2	taipumus	taipumus	PROPN
afs-72028	374	3	luovuttaa	luovuttaa	PROPN
afs-72028	374	4	elektroneja	elektroneja	ADJ
afs-72028	374	5	keskusionille	keskusionille	NOUN
afs-72028	374	6	vaikuttaa	vaikuttaa	ADV
afs-72028	374	7	myös	myös	PROPN
afs-72028	374	8	vaihdon	vaihdon	PROPN
afs-72028	374	9	kinetiikkaan	kinetiikkaan	PROPN
afs-72028	374	10	.	.	PUNCT
afs-72028	375	1	voimakkaasti	voimakkaasti	PROPN
afs-72028	375	2	sitoutuva	sitoutuva	PROPN
afs-72028	375	3	anioni	anioni	PROPN
afs-72028	375	4	reagoi	reagoi	PROPN
afs-72028	375	5	nopeasti	nopeasti	PROPN
afs-72028	375	6	oksidien	oksidien	ADJ
afs-72028	375	7	pinnan	pinnan	NOUN
afs-72028	375	8	al3+;n	al3+;n	PROPN
afs-72028	375	9	ja	ja	PROPN
afs-72028	375	10	fe	fe	PROPN
afs-72028	376	1	3+:n	3+:n	NUM
afs-72028	376	2	kanssa	kanssa	NOUN
afs-72028	376	3	,	,	PUNCT
afs-72028	376	4	mutta	mutta	PROPN
afs-72028	376	5	tällaisten	tällaisten	VERB
afs-72028	376	6	anionien	anionien	PROPN
afs-72028	376	7	irroittaminen	irroittaminen	PROPN
afs-72028	376	8	oksideista	oksideista	PROPN
afs-72028	376	9	käyttäen	käyttäen	PROPN
afs-72028	376	10	heikosti	heikosti	PROPN
afs-72028	376	11	sitoutuvia	sitoutuvia	ADP
afs-72028	376	12	ligandeja	ligandeja	PROPN
afs-72028	376	13	on	on	ADP
afs-72028	376	14	vaikeaa	vaikeaa	NOUN
afs-72028	376	15	.	.	PUNCT
afs-72028	377	1	esitetyn	esitetyn	NOUN
afs-72028	377	2	teorian	teorian	ADJ
afs-72028	377	3	avulla	avulla	PROPN
afs-72028	377	4	voidaan	voidaan	PROPN
afs-72028	377	5	selittää	selittää	PROPN
afs-72028	377	6	useita	useita	PROPN
afs-72028	377	7	anionien	anionien	PROPN
afs-72028	377	8	huuhtoutumiseen	huuhtoutumiseen	PRON
afs-72028	377	9	tai	tai	PROPN
afs-72028	377	10	kasvin	kasvin	PROPN
afs-72028	377	11	ravinteiden	ravinteiden	PROPN
afs-72028	377	12	saantiin	saantiin	PROPN
afs-72028	377	13	vaikuttavia	vaikuttavia	ADP
afs-72028	377	14	tekijöitä	tekijöitä	ADV
afs-72028	377	15	.	.	PUNCT
afs-72028	378	1	*	*	PUNCT
afs-72028	378	2	)	)	PUNCT
afs-72028	378	3	nykyinen	nykyinen	NOUN
afs-72028	378	4	osoite	osoite	NOUN
afs-72028	378	5	:	:	PUNCT
afs-72028	378	6	maatalouden	maatalouden	ADJ
afs-72028	378	7	tutkimuskeskus	tutkimuskesku	NOUN
afs-72028	378	8	,	,	PUNCT
afs-72028	378	9	maanviljelyskemian	maanviljelyskemian	ADJ
afs-72028	378	10	ja	ja	PROPN
afs-72028	378	11	-fysiikan	-fysiikan	PROPN
afs-72028	378	12	laitos	laito	NOUN
afs-72028	378	13	31600	31600	NUM
afs-72028	378	14	jokioinen	jokioinen	NOUN
afs-72028	378	15	.	.	PUNCT
