D e t e r m i n a t i o n o f S u r f a c e H e a t F l o w i n Mazesta ( U S S R ) (*> H . A . L U B I M O V A , L . M . L U S O V A , F . Y . F I R S O V , G . N . S T A R I K O V A , A . P . S H U S H P A N O V ( * * ) Ricevuto il 7 dicembre 1960 A great number of temperature measurements in deep bore-holes are made on the territory of the Soviet Union. The results of these mea- surements are partly systematized in the work " Problems of Geother- mie " t1). However they can be hardly used for the calculations of heat flow because of the absence of the corresponding determinations of the thermal conductivity of rock cores taken directly from these bore- holes. In the present paper the temperature gradient and the thermal conductivity of samples of rocks for the same place are determined and by means of these data the value of the thermal flow is estimated. For temperature measurements the electric resistance thermometer was used t h a t is designed by Dergunov I. D. and improved for the con- ditions of work in deep bore-holes (up to 4-5 km) at rather high pressures and temperatures. The electrical resistance was measured by means of the compensation methods by a special potentiometer and a high sensi- tive mirror galvanometer. Four bringing wires are used for doing away with the erratic currents and the influence of the wires. As a result of it the accuracy of the temperature measurements is about 0.01°C. Fig. 1 represents the exterior of the apparatus and the thermometer. The thermometer is a hollow cylinder on the surface of which a copper wire is winded bifllarily, whose resistance is measured. When the cylinder is buried into a bore-hole it is washed by a solution from outside and inside. Together with the application of ftorplast isolation this decreases the ther- mal inertia of the thermometer down to 1.5 sec. For the sake of strength annular justs are made on the cylinder. The thermometer stands the pressure up to 600 a t m and the temperature up to 200°C. (*) P a p e r r e a d a t t h e Helsinky Assembly of t h e I.U.G.G., 1960. (**) I n s t i t u t e of E a r t h ' s Physics A c a d e m y of Science U S S R ) . 1 5 8 L U B I M O V A , L U S O V A , F I R S O V , S T A R I K O V A , S I I U S H P A N O V l a t h e process of the determinations of t h e t e m p e r a t u r e t h e requi- rements of t h e bore-holes measurements' methodics were strictly obser- ved; the measurements were made by a point method in bore-holes t h a t were in rest for 8 to 10 months. As a total about 20 bore-holes with the depths f r o m 100 to 2600 m were investigated. Here the d a t a for the 3 bore-holes Mazesta-Hosta (Caucasus) are given. Temperatures were measured twice in it in 1955 a n d 1957 and yielded t h e same results. As to its geology the region Mazesta refers to a great tectonic depression submerged below t h e level of t h e Black sea in its South-Western p a r t a n d extended in t h e direction of t h e general striking of t h e Caucasus for t h e length of 60 to 65 k m and amounting its m a x i m u m width of 20 to 25 k m . The complete formation of t h e depression and t h e submergence of its p a r t below t h e sea level are d a t e d to t h e end of the Tertiary and the beginning of t h e Q u a t e r n a r y (2). Pig. 4, represents t h e lithological and stratigraphical cross-section of t h e bore-hole 3T. The t h e r m a l constants of rock cores were determined b y t h e im- pulse sound method. I n a core sample two holes are drilled a t a distance r from each other. One is for an electric heater and t h e other for ther- Pig. 1 - T h e e x t e r i o r of t h e A p p a r a t u s a n d t h e r m o m e t e r for t h e m e a s u r e - m e n t of t e m p e r a t u r e . D E T E R M I N A T I O N O F S U R F A C E I I E A T F L O W I N O L D M A Z E S T A 1 5 9 mopair. The exterior of the a p p a r a t u s is represented in fig. 2. A current impulse is transmitted through the heater during 3 to 4 sec which creates a practically instantaneous source of heat since the time of the thermal impulse propagation from t h e source to the observations point is of the order of a hundred seconds. The movement of the light spot of a mirror Fig. 2 - P h o t o g r a p h of t h e a p p a r a t u s for t h e m e a s u r e m e n t of t h e t h e r m a l c o n s t a n t s of rocks galvanometer indicates t h e moment when the maximum temperature is reached a t a given point. The time interval tmax and t h e value of the m a x i m u m temperature 0m a x a t a given point of observation are deter- mined and used for t h e determination of the thermal diffusivity lc and the thermal capacity eg simultaneously. These d a t a are applied for the calculation of the thermal conductivity A = Iccg. This method lias essential advantages over the stationary method, the so-called " divided b a r " method. I t does not require a through polishing of a core sample before the experiment, which greatly disturbs its n a t u r a l state. The preparation of the sample for the experiments consists only in boring of holes for t h e heater and t h e thermopair. The experiment takes some 1 6 0 L U B I M O V A , L U S O V A , F I R S O V , S T A R I K O V A , S I I U S H P A N O V minutes. A pressing spring being a heater's spiral a t t h e same t u n e prov- ides a close contact with the rock. This method permits to determine t h e heat conductivity both along and across the rocks striking and can be used for the determination of the thermal conductivity " in situ " . d i s t a n c e s r f r o m t h e source. The heater is a kind of a rod with the radius of 0,3 cm and t h e length 2 1 = 5 cm. F o r calculation such a source can be considered neither point nor spherical. The formula for the t e m p e r a t u r e distribution a b o u t an infinitely long and thin source in an infinite medium was used where r is t h e distance between t h e source and t h e thermopair, Q is t h e generated heat for the unit length of t h e source. D E T E R M I N A T I O N OF S U R F A C E I I E A T F L O W I N O L D M A Z E S T A 1 6 1 The values k and eg are determined from t h e conditions of t h e id extremum = 0 by t h e formulas o t r2 Q.e~ 1 1 = it 5 « = 6 71V2 > [2] ^ 1 m a x " m a x • ' ' where i m a x is t h e time moment when 0 — 6max a t a given point. However t h e comparison of t h e experimental and theoretical curves 0 calculated by means of formula [1] of the t e m p e r a t u r e variation with time (fig. 3) shows t h a t these curves are similar as to their p a t t e r n b u t tliey are somewhat shifted relative to the time axis a n d have different values of t h e t e m p e r a t u r e maximum. This difference does not disappear if to allow for the ultimate duration of the impulse At and the ultimate size of t h e sample. These effects account for the error not greater t h a n 1 per cent if the conditions A t < 10 sec are observed and t h e diameter of t h e sample a t r < 3 sm. A more essential error is due to the assumption t h a t the heater is an infinite straight line. The integration of the function describing t h e temperature influence of t h e instantaneous point heat source along with the cylinder surfaces with t h e radius a and length 21 yields a formula 131 which gives the temperature distribution about a cylindrical instanta- neous source of finite dimensions, where I„ (x) is t h e Bessel function of t h e zero order from an imaginary argument, erf is t h e integral of t h e errors. Hence t h e t h e r m a l diffusivitv k is determined graphically from t h e equa- tion for = 0 : 0 t ar _ ^ U f c w ) _ 1 . 6XP (~ ±kt) 4 f c < m a x 2 A ^ a x y ( OT \ 2 J-' Tlkt erf / }_ ^ 2fc, grad T = 12,24°C/km . [8] The deviation of AT2 observed t e m p e r a t u r e f r o m t h e calculated using formulas [8] is given in t a b l e 4, column 1. The s t a n d a r d error is 0.11°C. Below t h e values of t h e h e a t c o n d u c t i v i t y of rock cores across t h e striking are represented. 250-290 0,00725 0,00653 0,00689 Limestone of t h e T u r o n 290-315 0,00517 0,00594 c p e f l H e e 0,00556 Marls of t h e senoman tufaceous s a n d s t o n e of t h e senoman 315-328 0,00417 328-375 0,00664 0,00627 c p e , a ; H e e 0,00646 Marls of t h e Alb a n d t h e A p t 375-950 0,00677 0,00666 0,00737 0,00658 cpeflHee 0,00685 Limestone of t h e V a l a n g i n i a n - B a r r e m i a n T h e average v a l u e of t h e t h e r m a l c o n d u c t i v i t y in t h e r a n g e of 250 to 950 m consisting of a great n u m b e r of layers was calculated b y m e a n s of t h e f o r m u l a ^ DI — DK 70000 Di A + l Dk_ 1000 57500 Xi Xi - f 1 " h 6,89 • 1 0 - s 6,85 • 10~3 = 6,64 • 10~3 ± o , 6 o • 10-3 . cm20C sec cm20C sec D E T E R M I N A T I O N OF S U R F A C E I I E A T FLOW IN OLD MAZESTA 1 6 5 The average values of A for t h e I I and I I I intervals are equal to 5,84 • 1 0 3 and 6,85 • 10"3 — ~ — . We obtain for the h e a t flow cm200 sec B = I grad T = 6,64 • 1(T3 • 1,22 • 1(T4 = 0,81 • 10"' — — ± cm2 sec cal ± 0,07 • lO"6 cm2 sec T a b l e No. 1 ^ D D e p t h T ATX AT, Z — • 1 0 5 K at3 m. °C °C °C cm 2 sec °C <>C cal 1 7 5 2 3 , 8 2 — 0 , 1 1 2 0 0 2 4 , 7 2 + 0 , 0 9 2 2 5 2 5 , 4 5 + 0 , 1 1 2 5 0 2 5 , 9 2 — 0 , 1 2 + 0 , 0 5 + 0 , 4 6 4 2 , 8 0 8 + 0 , 6 2 2 7 5 2 6 , 0 0 — 0 , 0 4 + 0 , 2 3 4 7 , 0 8 9 + 0 , 3 5 3 0 0 2 6 , 1 6 — 0 , 0 4 + 0 , 0 9 5 1 , 3 7 0 + 0 , 1 6 3 2 5 2 6 , 4 1 + 0 , 0 4 + 0 , 0 3 5 5 , 6 5 1 + 0 , 0 5 3 5 0 2 6 , 3 7 + 0 , 0 4 — 0 , 1 1 5 9 , 9 3 1 — 0 , 1 4 3 7 5 2 6 , 3 8 — 0 , 0 2 — 0 , 1 6 — 0 , 3 1 6 4 , 2 1 2 — 0 . 3 8 4 0 0 2 7 , 2 4 + 0 , 0 8 — 0 , 0 6 6 7 , 8 6 3 — 0 , 1 2 4 2 5 2 7 , 6 1 + 0 , 1 4 + 0 , 0 1 7 1 , 5 1 2 — 0 , 0 5 4 5 0 2 7 , 8 7 + 0 , 0 8 — 0 , 0 4 7 5 , 1 6 2 — 0 , 0 5 4 7 5 2 8 , 2 0 + 0 , 1 0 - 0 , 0 1 7 8 , 8 1 2 — 0 , 0 6 5 0 0 2 8 , 4 8 + 0 , 0 6 — 0 , 0 3 8 2 , 4 6 1 — 0 , 0 8 5 2 5 2 8 , 8 2 + 0 , 0 9 0 8 6 , 1 1 1 — 0 , 0 4 5 5 0 2 9 , 1 2 + 0 , 0 7 - 0 , 0 1 8 9 , 7 6 0 — 0 , 0 5 5 7 5 2 9 , 3 5 - 0 , 0 2 — 0 , 0 9 9 3 , 4 1 0 — 0 , 1 2 6 0 0 2 9 , 6 5 — 0 , 0 3 — 0 , 0 9 9 7 , 0 6 0 — 0 , 1 2 6 2 5 2 9 , 8 0 — 0 , 2 0 — 0 , 2 5 1 0 0 , 7 0 9 — 0 , 2 7 6 5 0 3 0 , 1 9 — 0 , 1 3 — 0 , 1 7 1 0 4 , 3 5 9 — 0 , 1 8 6 7 5 3 0 , 4 9 — 0 , 1 4 — 0 , 1 7 1 0 8 , 0 0 8 — 0 , 1 8 7 0 0 3 0 , 8 4 — 0 , 1 1 — 0 , 1 3 1 1 1 , 6 5 8 — 0 , 1 3 7 2 5 3 1 , 2 0 — 0 , 0 6 — 0 , 0 7 1 1 5 , 3 0 8 — 0 , 0 7 7 5 0 3 1 , 5 7 — 0 , 0 1 — 0 , 0 1 1 1 8 , 9 5 7 0 7 7 5 3 1 , 9 0 0 + 0 , 0 1 1 2 2 , 6 0 7 + 0 , 0 3 8 0 0 3 2 , 2 8 + 0 , 0 7 + 0 , 0 9 1 2 6 , 2 5 6 + 0 , 1 1 8 2 5 3 2 , 6 1 + 0 , 0 8 + 0 , 1 1 1 2 9 , 9 0 5 + 0 , 1 4 8 5 0 3 2 , 8 7 + 0 , 0 3 + 0 , 0 7 1 3 3 , 5 5 6 + 0 , 1 0 8 7 5 3 3 , 2 3 + 0 , 0 7 + 0 , 1 2 1 3 7 , 2 0 5 + 0 , 1 5 9 0 0 3 3 , 5 5 + 0 , 0 7 + 0 , 1 3 1 4 0 , 8 5 5 + 0 , 1 7 9 2 5 3 3 , 8 5 + 0 , 0 6 + 0 , 1 3 1 4 4 , 5 0 4 + 0 , 1 7 9 5 0 3 4 , 1 0 — 0 , 0 1 + 0 , 0 7 1 4 8 , 1 5 4 + 0 , 1 2 ± 0 , 1 1 ± 0 , 1 8 1 6 6 L U B I M O V A , L U S O V A , F I R S O V , S T A R I K O V A , S I I U S H P A N O V In accordance with a more precise method of the determination of the average heat flow through a multi-layered medium [4] we h a v e T T E = ,, ; [9] 2 DijXi 2 Di Values — — for each range of depths are given in table 1, Xi column 5. The corresponding deviations AT3 of the observed value T from the calculated one using formula [9] are given in the last column. The equation for T is T = 21,77 + 0,82 • 10-* £ D - »=1 M cal cal H = 0,82 • 10"6 ± 0,05 • 10-6 ~ cm2 sec cm2 sec which is very close to t h e value obtained above. We obtained t h e values of t h e t e m p e r a t u r e s for t h e near located bore-holes 2 T New Mazesta and 2 T Hosta also and determined t h e heat flow on the base of t h e known lithological cross-sections and d a t a on X: 1) for t h e bore hole 2 T New Mazesta T = 28,58 + 0,987 • 10~4D , grad T = 0,987 • 10"1 ; H = 0.68 • lO"6 2) for t h e bore hole 2 T H o s t a T = 16,95 + 1,810 • 10~4D , grad T = 1,81 • 10"4 , H = 1,14 • 10"6 . Then t h e average value of heat flow for Mazesta-Hosta region C£Jjl is equal (0,88 ± 0,16) • 1 0 - 6 . I t is possible there is t h e coo- cm2 sec ling effect of t h e near located Black Sea and of the Mazesta's springs. SUMMARY The results of the measurements of the temperature and the thermal conductivity of rocks for the three boreholes Mazesta's region are described. The special thermometer of the resistance ivas used. The method of the mea- surements of the thermal conductivity and capacity based upon the principle of the instant linear heat source. Then calculated magnitude of heat floiv is equal 0.88 • 10~e cal/cm2/sec. It is likely that there is the cooling effect of the near located Blaclc Sea and of the Mazesta's springs. D E T E R M I N A T I O N OF S U R F A C E I I E A T F L O W I N O L D M A Z E S T A 1 6 7 RIASSUNTO Sono descritti i risultati delle misure della temperatura e della condut- tivita termica delle roece per i 3 fori praticati nella regione della Mazesta. E stato usato lo speciale termometro a resistenza. II metodo delle misure della eonduttivita e della capacita termica si basa sul principio della sorgente improvvisa lineare di colore. L'ampiezza calcolata delVemissione di colore e uguale a 0.88 • 10~6 cal/cm2/sec. R E F E R E N C E S (x) Problems of Geothermie. T r a n s a c t i o n s of tlie All-Union Congress of geo- t h e r i n i c i n v e s t i g a t i o n s , Acad. Sci. U S S R . (1959). (2) MAKARENKO F . A., On the Genesis of the Sulpheretted Hydrogen Waters of Mazesta. T r a n s a c t i o n s of t h e L a b o r a t o r y of Hydrogeological P r o b l e m s Acad. Sci. U S S R , v. 2, (1949). (3) BENFIELD A. E., Terrestrial Heat Flow in Great Britain, P r o c . Roy. Soc. 173, 428-450, ( 1 9 3 9 ) . . (4) BULLARD E . C., Heat Flow in South Africa. P r o c . Roy. Soc. A., 173, 474-502, (1939).