AG_56.05.13_HELMAN_finalonline:Layout 6 ANNALS OF GEOPHYSICS, 56, 5, 2013, G0564; doi:10.4401/ag-6184 G0564 Earth electricity: a review of mechanisms which cause telluric currents in the lithosphere Daniel S. Helman California State University Long Beach, Department of Geological Sciences, Long Beach, CA, United States ABSTRACT Telluric currents are natural electrical phenomena in the Earth or its bod- ies of water. The strongest electric currents are related to lightning phe- nomena or space weather. Earth electricity can cause damage to structures, and may be useful for earthquake forecasting and other appli- cations. Thirty-two distinct mechanisms that cause Earth electricity are described, and a broad selection of current research is highlighted. 1. Introduction Several phenomena that can generate telluric cur- rents have been described in scientific specializations whose members may not communicate with each other regularly. The study of this topic is both intrigu- ing and challenging: Electrical signals do not carry much of a marker to indicate how they are generated, beyond magnitude, frequency, and polarization. At- tenuation and new phenomena caused by transmission complicate signal characteristics. A wide range of pos- sible applications for telluric data exists in different fields (seismolog y, hydrolog y, mineral prospecting, geother mal prospecting, planetary science, etc.) For example, seismic electric signals may occur in a pe- riod leading to increased seismic risk, and understand- ing the causes of purported seismic electric signals is critical to characterizing any extant mechanism related to electricity and earthquake phenomena [Varotsos et al. 2011]. As another example, dissolved ions in groundwater increase rock conductivity, and the mo- tion of the groundwater itself creates an electrical sig- nal [Corwin and Hoover 1979]. This text is a brief selection of research in the subject, meant to be a re- source for further study. Along with artificial signals, Earth electrical phenomena are summarized in Table 1, and Table 2 lists telluric currents by frequency, mag- nitude and signal duration. Thirty-two causes of Earth electricity are described in the text that follows. Tel- luric currents were originally defined as natural elec- tric currents passing through the Earth’s soil or rock layers or bodies of water, as opposed to its atmosphere. Artificial currents were not included. For the purposes of this paper, any electric current in a planet or on it may be classed as a telluric current. 2. Space phenomena 2.1. Geomagnetically-induced currents, GIC The ionosphere is composed of charged particles and located 85 to 600 km above the Earth’s surface. Elec- trical phenomena are caused as the solar wind or space weather impact the ionosphere. The solar wind and space weather create ionospheric electromagnetic phe- nomena in the radio spectrum, and these disrupt com- munication. Eddies in the ionosphere also occur, and these create electric current in situ, from the motion of ions. This electric current affects the geomagnetic field, and the resulting geomagnetic anomalies induce telluric currents in the ground [Boteler et al. 1998]. This is GIC. Geomagnetically-induced currents cause corrosion in pipes and pipelines, and are a problem at high latitudes, where the Earth’s magnetic flux lines point towards (or away from) the surface of the Earth. Ore, or other rock bodies, or human-made struc- tures, such as pipes and cables, respond to electrical changes in the ionosphere, so that a telluric current is induced in the ground. Osella et al. [1998], Everett and Martinec [2003], Constable and Constable [2004], Pulkkinen et al. [2007], and others have studied this phenomenon. Cycles are related to space weather, and are dominated by the influence of the Sun’s eleven-year sunspot cycle, whose period predicts emissions of gas from the solar surface. Diurnal variations within this larger cycle have been recorded [Diodati et al. 2001]. Article history Received August 9, 2012; accepted June 27, 2013. Subject classification: Magnetosphere, Magnetic storms, Mineral physics and properties of rocks, Exploration geophysics, Magnetic and electrical methods, Geology, Space and planetary sciences, Solar-terrestrial interaction. The ongoing diurnal currents are responsible for the corrosion of pipelines and cables in some locations, es- pecially at high latitudes, and have been studied exten- sively in Scandinavia [Viljanen et al. 2006]. GIC typically are on the order of 200 amperes (A) in man-made con- ductors, with durations of approximately 10 seconds [Kappenman et al. 1981, Viljanen et al. 1999, Pulkkinen et al. 2008]. The oscillating frequency is typically 0.01 HELMAN 2 Name Cause Cycle Mechanism Space Phenomena GIC Cosmic Particle Flux Planetaty Magnetic Field Plasma Solar Cosmic Cosmic Events (Magnetotail) 11/24hr Not Known Not Known 28d Electromagnetic Induction Charge Transmission Charge Transmission Atmospheric Phenomena TID Lightning Strikes Lightning Strikes Induction Whistler Induction Whistler Plasma Volcanic Lightning Strikes Storm Charging Atmospheric Disturbavce Lightning Lightning Lightning Lightning Volcanic Lightning Weather Not Known Seasonal Seasonal Seasonal Seasonal Not Known Seasonal Electromagnetic Induction Charge Transmission Electromagnetic Induction Electromagnetic Induction Charge Transmission Charge Transmission Electrostatic Induction Oceanic Phenomena Electrochemical Effects Ocean Transport Induction Oceanic Charging Metabolic Electrochemistry Ocean Currents Ocean Currents Ocean Electric Currents Microbes and Algae Seasonal Seasonal Seasonal Not Known Charge Transmission Electromagnetic Induction Electromagnetic Induction Charge Transmission Surface Phenomena Artificial Signals Metabolic Electrochemistry Exo-Electron Emission Industry Microbes and Plants Primed Material Various 24hr Not Known Electromagnetic Induction Charge Transmission Charge Transmission Groundwater Phenomena Electrochemical Effects Electrokinetic Effects Seismic Dynamo Induction Radioactive Ionization Fluid Flow Fluid Flow in Porous Media Seismic waves Radioactive Decay Seasonal Various Not Known Not Known Charge Transmission Electrostatic Induction Charge Transmission Charge Transmission Other Terrestrial Phenomena Volcanic EM Signals Seismic EM Signals Seismic Electric Signals Fractoemission Defect Charging Piezoelectric Effects Thermoelectric Effects Pyroelectric Effects Magma Electrochemistry Radioactive Emission Volcanism Earthquakes Earthquakes Fracture Materiale Defects Crystal Lattice Geometry Temperature Gradient Temperature Gradient Magma Processes Radioactive Decay Not Known Not Known Not Known Not Known Not Known Not Known Not Known Not Known Not Known Not Known Not Known Not Known Not Known Charge Transmission Charge Transmission Domain Rearrangement Charge Transmission Domain Rearrangement Charge Transmission Charge Transmission Deep Terrestrial Phenomena Geomagnetic Jerk Geodynamo Not Known Electromagnetic Induction Table 1. Causes and periods of Earth electricity. GIC are geomagnetically induced currents, TID are traveling ionospheric disturbances, and EM is an abbreviation for the term electromagnetic. 3 to 0.001 Hz [Price 2002]. Peak current can be on the order of 2000 A, and these occur about 10 to 100 times in 100 years [Pulkkinen et al. 2008]. Diurnal flux rates at the sub-auroral latitudes are on the order of a few millivolts per kilometer (mV km-1) [Mather et al. 1964]. The strongest oscillation frequency of these diurnal signals is 0.4 Hz, and is widespread at different latitudes [Mather et al. 1964]. At high latitudes, the motion of charged particles also creates a distinct radio signal, termed the polar chorus, with a charac- teristic frequency of 300 Hz to 2 kHz [Barr et al. 2000]. Polar chorus is associated with the solar wind, and the peak intensity is around 50 μV m-1 as recorded from stations on the ground in Antarctica. It typically exhibits a diurnal variation [Salvati et al. 2000]. Telluric currents (and specifically GIC) were first documented in the 1840s with the invention of the telegraph. Buried tele- graph lines are electrical conductors, and susceptible to electrical induction. Geomagnetically-induced currents caused interference during telegraph transmission, so that the telegraph needles hung frozen by the signals of the GIC. At first this phenomenon was attributed to weather causes, but it was soon recognized that the hung needles coincided with the occurrence of aurora borealis and magnetic storms [Walker 1861]. 2.2. Cosmic-particle flux Direct bombardment by high-energy charged par- ticles and radiation coming from solar, stellar, and cos- mic sources, act generally to form GIC. For example, a gamma-ray flare from a neutron star 23,000 light years away was reported in 1999 as causing VLF amplitude changes of more than 20 decibels from interaction with the ionosphere. The Lyrid, delta-Aquarid and Perseid metoer showers have caused phase variations in a 16 kHz signal due to GIC [Barr et al. 2000]. For planetary bodies with no atmosphere, this flux of cosmic particles creates telluric currents directly [Madey et al. 2002]. Cosmic ray ions have an energy flux of about 6 × 109 eV cm-2 s-1 for bodies in the Solar System. For Mars, protons and neutrons strike the sur- face with energy fluxes of around 6000 and 1400 MeV cm-2, respectively [Molina-Cuberos et al. 2001]. This process is not occurring on the Earth’s surface at pres- ent; the atmosphere intervenes. 2.3. Planetary magnetic-field plasma If ultraviolet and X-Ray emissions from a star en- counter a magnetic field, the interactions will create a plasma of energetic electrons. Such a plasma is created in the Earth’s magnetosphere from solar radiation, and strikes the moon’s surface as it passes through the Earth’s magnetotail. as described in Stubbs et al. [2007]. The magnitude of the charging can be several thousand volts [Halekas and Fox 2012]. A magnetotail is the dis- tal part of an oblong magnetic field, caused in this case by the solar wind. 3. Atmospheric phenomena 3.1. Traveling ionospheric disturbances, TID Atmospheric compression (i.e. acoustic waves) from a sudden event, such as an earthquake, tsunami, volcanic eruption, severe weather or rocket launches can create traveling ionospheric disturbances (TID) [Georges 1968, Johnston 1997, Afraimovich et al. 2001], and these TID can induce telluric currents in the ground via the geo- magnetic field. TID are themselves a category of GIC. The ionosphere also has resonant electrical phe- nomena, called Schumann resonances, at a fundamen- tal frequency of 10.6 Hz, with overtones at 18.4, 26.0, 33.5 and 41.1 Hz [Barr et al. 2000]. The background am- plitude of measured Shumann resonances is about 1.0 picoteslas [Schlegel and Füllekrug 1999]. In addition to the above examples, TID can form as the result of grav- ity waves at the troposphere-ionosphere interface [Georges 1968]. A gravity wave is one where buoyancy or gravity (or both) act to oppose the displacement. A common example of a gravity wave is the wind-gener- ated wave forms one sees at the ocean at the ocean-air interface. Some TID are akin to these, occurring at the troposphere-ionosphere interface. No quantitative re- ports of the magnitudes of telluric currents resulting from TID are extant, to the best of the author's knowl- edge, though qualitative magnitudes are known. Space weather events are the strongest TID, and then, in de- scending order, daytime signals, atmospheric compres- sion events, and gravity waves [Georges 1968]. The effect of TID within the ionosphere is for the disturbance to develop a potential on the order of 1 mil- livolt per meter [Shiokawa et al. 2003]. Frequency for the ionospheric dynamo region is modeled to be on the order of 10-6 to 10-7 Hz [Kaladze et al. 2003]. Higher fre- quencies are also present [Munro 1958]. Short-term changes (on the order of hours) to the Earth’s magnetic field may be caused by ionospheric activity. Kaladze et al. [2003] have modeled ionospheric activity that matches the magnitude and timing of ground observa- tions of changes to the geomagnetic field. The ionosphere is studied with dedicated ground- based facilities, such as the High Frequency Active Au- roral Research Program (HAARP) and with satellites. A network of satellites measuring ionospheric distur- bances are in place. A 1996 space experiment with a nearly 2 km long conducting line gathered electrical data in the ionosphere, and then compared these with EARTH ELECTRICITY: A REVIEW OF MECHANISMS satellite data. The accuracy of modeled ionospheric ac- tivity between satellites is low. Modeled electrical data are off by as much 140% [Szuszczewicz et al. 1998]. On the ground, HAARP has been in operation in Alaska since 1993 [Bailey and Worthington 1997]. That facility is designed to transmit radio-frequency electro- magnetic radiation into the ionosphere for communi- cation with submarines, with the electrolytes in the ocean acting as an antenna. HAARP is also suited for ionospheric studies. HAARP experiments are designed to study the structure of the ionosphere, and for determining practi- cal applications of wave propagation, such as radio sig- naling. Results have included techniques to produce very low frequency and extremely low frequency (VLF/ELF - 30 Hz to 30 kHz) radio waves [Cohen et al. 2008]. Light- ning channels broadcast electromagnetic radiation in the VLF range, and HAARP can duplicate this VLF. HAARP has also been used for magnetotelluric surveying. In a magnetotelluric survey, both electrical and magnetic fields are used for remote sensing, to deter- mine the electrical resistivity of an area, and variations within it, according to an empirical equation (1) where t is the resistivity in ohm meters (Ω m), f is fre- quency in Hertz (Hz), E is the electric field tensor in volts per meter (V m-1), and B is the magnetic field ten- sor in nanoteslas (nT) [Wescott and Sentman 2002]. HAARP can generate magnetotelluric signals, and was used as the transmitter for a proof-of-concept con- trolled-source audio-magnetotelluric survey (CSAMT) in Alaska in 1999 and 2000, prospecting for petroleum [Wescott and Sentman 2002]. This is a new trend. Most magnetotelluric surveys have historically used natural fields [Simpson and Bahr 2005]. Simultaneous meas- urements of the geomagnetic field and of telluric cur- rents are used to calculate a value for the electrical impedence at depth, to explore subsurface features. 3.2. Lightning strikes Electrical charge is transferred between the ground and the atmosphere during lightning strikes, and the tops of stormclouds close an electrical circuit with the ionosphere. Lightning discharge is energetic and creates plasma that we see. The first pulse of light- ning occurs as charges within the cloud consolidate to form a strike leader, and plasma from the ground rises up to meet the leader in that cloud. The next pulse comes from the cloud to the ground. The process re- peats, with alternating pulse initiations between ground and cloud. A lightning strike is a combination of about 30 pulse events, each lasting nanoseconds, and its overall duration is on the order of milliseconds [Uman 1994]. The bulk result is a negative charge given to the ground. Peak electric current is 99 ± 7 kA, meas- ured by quantifying remanent magnetization of the ground and calculating the peak magnetic field [Ver- rier and Rochette 2002]. Oscillation signal frequencies are on the order of 10-3 MHz to 103 MHz, or higher [Uman and Krider 1982]. The previous data have been normalized to a 10 km distance, and higher frequency signals are known to attenuate. With some dry light- ning and strikes which ignite fires, a positive charge is given from the cloud to the ground. The magnitude of charge carried by positive cloud to ground strikes is increased by the presence of aerosols and smoke [Nichitiu et al. 2009]. 3.3. Lightning-strike induction Lightning strikes can also cause transient changes to the geomagnetic field [Verrier and Rochette 2002]. Lightning can occur in various weather conditions, in- cluding thunderstorms, dust storms and tornadoes [Barr et al. 2000]. Telluric currents arising from this phe- nomenon ought to have frequencies of 10-3 MHz to 103 MHz, based on the ns to ms variations recorded in lightning phenomena. These are the same frequencies that a direct flash of lightning will display. Induction is localized, and portions of large buildings and towers are frequently subject to induction when they are struck. Hussein et al. [2003] compare data from several structures, and the average magnitudes are between 7 and 12 kA, with peak magnitudes from 20 to 100 kA. 3.4. Whistler induction Lightning discharge heats the air and creates plasma. The entire lightning channel radiates electro- magnetic energy. If in the radio frequency, it is called a radio atmospheric signal, or sferic. If the plasma from lightning dishcarge travels along geomagnetic lines, the resulting radio-frequency disturbances are termed “whistlers” and are named for the sound which this in- terference makes in telephone lines, as first described in 1919 [Schlatter 2008]. The sound was attributed to light- ning phenomena in 1953. Whistlers typically occur in the ELF/VLF range of 3 Hz to 30 kHz [Barr et al. 2000]. For example, observations made from Antarctica at 22.3 kHz show common changes in amplitude of 3 decibels to an artificially transmitted signal, with duration of around 30 seconds. These changes were associated with whistler activity [Helliwell et al. 1973]. The propogation of whistlers along geomagnetic flux lines can induce changes to local magnetic fields, and these can cause in- duction of human-made conductors and ore bodies. HELMAN 4 1/5 f E/B ,t = 26 @ 5 3.5. Whistler plasma Whistlers are caused when plasma from lightning travels along the geomagnetic flux lines. The magni- tude of the electron density striking the Earth is on the order of 104 electrons per cm3 during whistler events at the equator. Poleward densities should be higher, as the flux lines there are more inclined to the Earth’s sur- face [Schlatter 2008]. 3.6. Volcanic lightning strikes An electrical response in the ground as lightning strikes during volcanic eruptions has been described in [Aizawa et al. 2010]. They describe magnetotelluric data from Sakurajima volcano in Kyushu, Japan, from May 2008 to July 2009. Magnetotelluric pulses were recorded coincident with several strikes. Generally, volcanic plume heights where volcanic lightning has been observed are distributed bimodally: plume heights 1 to 4 km, and plume heights 7 to 12 km. In the former, volcanic lightning is due to vent processes, and in the latter volcanic lightning is due to stratospheric processes [McNutt and Williams 2010]. Occurrence of volcanic lightning increases with height in the stratospheric plumes, and peak currents greater than three thousand amperes have been observed [Ben- nett et al. 2010]. Ash erupted from a volcano is electri- cally charged. Whether a circuit is made between charged ash and the ionosphere has not yet been re- ported. Low frequency (30 kHz to 300 kHz) sferics are reported, as with meteoroligical lightning events, but the emission spectra of the flash itself has not been. Likewise, the author has not found reports of the mag- nitude of electrical discharge during volcanic lightning. James et al. [2000] have described a mechanism for ash charging. In a series of experiments, ash-sized par- ticles were ground from several crustal rock samples in a non-conducting sample holder. The materials devel- oped charges of both polarities, generally based on the chemical composition of the particles, with the net charge of ≈10-5 to 10-6 coulombs per kilogram (C kg-1). Their data are consistent with measurements taken previously within ash fall plumes [James et al. 2000]. They attribute the charge in the ash to fracture-charg- ing, also called fractoemission, where electrical charge is caused in a fracture as electrons are distributed un- evenly during fracture processes. Lightning in volcanic plumes is controlled by to- pography and wind direction, with negative strikes (negative charge carried to the ground) and positive strikes (positive charge carried to the ground) evolving over the course of an eruption [Hoblitt 1994] or occur- ring simultaneously. The role of water in the magma and its influence in volcanic lightning is still an open question, though the occurrence of volcanic light- ning is not related to latitude, and, hence, is likely not related to the ability of the air to hold water [McNutt and Williams 2010]. 3.7. Storm charging Terrestrial electrical f ields occur during storm activity. A vertical f ield on the order of 100 V m-1 and a current density at the surface of roughly 2 × 10-2 A m-2 has been measured during thunderstorm activity, with water droplet interactions in clouds perhaps serving as the source of the initial (nega- tive) charge buildup. These may induce a positive charge in the ground. In thunderstorm clouds, the negative charge at the bottom of the cloud is offset by a positive charge in the top portion, that together form a con- ductive circuit flowing upward through the strato- sphere, also called a thundercloud cell. In reality, negative charge is flowing downward. The current has been experimentally determined to be around 0.7 A per thundercloud cell [Troshichev et al. 2004]. Current flow in a thundercloud cell accounts for about 96% of the electrical activity of a storm, while lightning discharges account for a minority (≈ 4%). Electrical charg ing of storm clouds is offset by charging of the ocean surface, where daily electrical ocean surface variations are consistent with the daily change of the total area occupied by thunder- storms [Troshichev et al. 2004]. Electrical frequency spectra in the g round from electrostatic storm charg ing are not reported, to the author's knowl- edge. 4. Oceanic phenomena 4.1. Electrochemical effects in the ocean In the oceans, different layers of water will be stratif ied by temperature and salinity, and each in- fluences density. Both of these gradients influence electrical conductivity, and create variations in elec- tric currents in the oceans [Chave and Luther 1990]. The signals are low-frequency (30 kHz to 300 kHz) or lower, typically. Voltages from temperature and salinity variations in the ocean are less than a few mV (silver/silver-chloride electrodes were used) and the differences in salinity and temperature were less than a few parts per thousand and a few degrees Celsius, respectively, between electrodes [Larsen 1992]. The electrode material affects the observed voltage. Internal waves (within the stratified ocean) are measurable electrically in their vertical compo- nent as gradients are crossed [Chave 1984]. EARTH ELECTRICITY: A REVIEW OF MECHANISMS 4.2. Ocean transport induction Electrical induction in the oceans occurs by three processes: transport of seawater across the geomagnetic field (treated in this subsection); the influence of GIC on saltwater, a conductor (treated in the subsections above dealing with GIC and TID); and variations in sea water due to variations in salinity and temperature (treated above.) Bulk water transport was first measured electrically by Faraday in 1832, at the Waterloo Bridge with electrodes placed in the Thames River, but sunspot activity (unfortunately) masked the periodic influence of the Gulf Stream [Larsen 1992]. Induced voltage due to transport of saline water has been observed success- fully, with a magnitude on the order of 25 mV per kilo- meter, measured on a cable fitted with electrodes in the Straits of Florida [Larsen 1992]. The GIC (with peaks up to about 50 mV km-1 but with typical values of 10 to 20 mV km-1) had been subtracted out of the data by hand. The voltages occur at frequencies from 10-3.8 to 10-7.0 Hz and are incomplete, and tidal variation and other outliers create peaks around 10-5 Hz. 4.3. Oceanic charging Two sources of electric currents in the ocean al- ready described in this text are: storm clouds charging the ocean surface (above); and processes to charge water strata in the ocean itself. Electricity from both of these may be transmitted to the rock with which it is in contact via electrostatic induction [Cox 1981]. The oceanic lithosphere receives a quasi-static charge from the ocean. Due to the high metal content of the rock, both electrostatic and electromagnetic induction will occur if major changes to electric current in the oceans or to the geomagnetic field also occur. 4.4. Metabolic electrochemistry in the ocean The metabolic action of micro- and macrobiota in the oceans may contribute to an electrical signal that is measurable. Bohlin et al. [1989] describes how fish are attracted to electric signals; this phenomenon might be related either to physiology or to food sens- ing. Brahic [2010] describes how an extensive network of microbial electric currents may exist in oceanic mud. Atekwana and Slater [2009] introduce the study of microbial geophysical signatures in a comprehen- sive manner; biogeophysics is an emerging field, and more research is warranted. 5. Surface phenomena 5.1. Artificial signals Earth electric currents may come from the trans- mission of electricity or electromagnetic radiation em- anating from human-made sources [Keller 1968, Pham et al. 1998] and also from on-ground activity, such as from electric trains. Telluric currents may come from electrical fields set up intentionally as, for example, from a direct-current (DC) electrical field designed to remove contaminants from soils [Probstein and Hicks 1993]. Electroremediation can be accomplished with a field strength of about 150 V m-1. A complexing agent is added to the groundwater, and contaminants are at- tracted to wells for removal [Wong et al. 1997]. The magnitude of artificial telluric currents de- pends directly upon the generation process. Extremely low frequency radio waves are generated by heating the ionosphere, and are used by the US military to commu- nicate with submarines, for example. Nuclear explosions above ground also create ionospheric VLF radiation, with frequencies of 10 kHz to 15 kHz [Barr et al. 2000]. 5.2. Metabolic electrochemistry in soil The daily action of plants, fungi, bacteria, lichen or algae that inhabit soil and rock fissures may produce electrical signals from electrochemical processes related to metabolism. Some evidence exists that soil microbes respond to changes in the geomagnetic field [Jie Li et al. 2009], though the converse has not been shown. Abdel Aal et al. [2010] report that the imaginary component of measured conductivity in sand is increased linearly as Pseudomonas aeruginosa are introduced to the grains. The imaginary component of conductivity is a measure of its dissipation, part of the field equations that model oscillating or alternating current. Abdel Aal et al. [2010] used low frequency (0.1 to 1000 Hz) signals for their study. No change to the real component of the conduc- tivity was observed. Regarding plants: despite the existence of diurnal electrical variations measured in sapwood [Gilbert et al. 2006], and in leaves and leaf stems [Gil et al. 2008], and also despite the invention of functional electrical circuitry powered by plants and trees [Himes et al. 2010, Yamaguchi and Hashimoto 2012], no diurnal soil-root signal from plants has been detected [Love et al. 2008]. A new sensor for these signals has recently been devel- oped [Gurovich 2009], but no evidence of diurnal sig- nals has been published yet. 5.3. Exo-electron emission The process of stress relaxation may release elec- trons after an initial priming, as can the addition of heat or photons to a previously stressed sample [Oster et al. 1999]. These and related processes are termed exo-elec- tron emission if the energy of the electrons is low (less than or equal to one electron volt), to distinguish it from high-energy electron emission phenomena, such as frac- HELMAN 6 7 toemission. Exo-electron emission functions by means of traps and defects and requires a solid-gas or solid-vac- uum interface for its action: it acts at a surface. Exo-elec- tron emission may occur in the vadose zone or on the surface of the crust [Oster et al. 1999, Freund 2011]. Exo- electron flux is observed as less than or equal to 108 elec- trons (e-) per square centimeter [Oster et al. 1999]. 6. Groundwater phenomena 6.1. Electrochemical effects in groundwater As ionically-charged fluids travel in porous rock, an electric current is created by the motion of the sus- pended ions [Corwin and Hoover 1979]. This is the prin- ciple behind household chemical batteries, and is common in nature. The electrochemical effect found in ore bodies, for example, is akin to commercial electro- chemical batteries in magnitude (a few volts) [Lile 1996]. While the chemistry of the fluid determines the volt- age, the signal frequencies are controlled by the motion. 6.2. The electrokinetic effect Just as the motion of ionically-charged fluids in porous rock creates an electrochemical current, so too the interaction of the charged fluid with the bounding rock creates a complementary charging in the rock it- self. At the fluid-rock interface, a single layer of ad- sorbed ions attracts a second layer of the opposite sign, and these are sufficient to create an electrical potential over a distance. This so-called streaming potential, caused by an electrokinetic effect, involves electrostatic induction by moving ions. Self potential is a combina- tion of streaming potential (based on the electrokinetic effect) and of the diffusion of the ions themselves. Typically, self potential is present in groundwa- ter flows [ Aubert and Atangana 1996, Birch 1998, Revil et al. 2003, Jardani et al. 2006], but can also be found in many geologic settings, such as sulphide ore bodies [Lile 1996] and other mineral deposits, includ- ing graphitic deposits [Stoll et al. 1995], and on volca- noes, where the phenomenon is due to hydrothermal activity, changes in groundwater flow, and magma dis- placement [Zlotnicki and Nishida 2003]. In hy- drothermal settings, streaming potential from electrokinetic effects is much stronger than associated thermoelectric effects [Corwin and Hoover 1979]. A streaming potential of up to 30 mV can be generated from a groundwater change of 50 cm, if the fluid re- sistivity is 102 Ω m and the rock permeability is 10-12 m2 [Jouniaux and Pozzi 1995]. Streaming potential variations occur, with pulses in amplitude of 15 to 40 mV, and a frequency of 0.1 to 0.5 Hz [Jouniaux and Pozzi 1997]. 6.3. Seismic-dynamo induction Rock is displaced as seismic waves pass through. Groundwater in the pore space is displaced as well, as are ions in the groundwater. The motion of ions rela- tive to the geomagnetic field creates circularly or ellipti- cally polarized electric fields, with opposite orientations for positive and negative ions. This effect was reported in 2009, and was observed both for artificial seismic waves from blasting and for natural seismic waves [Honkura et al. 2009]. The magnitude of the seismic-dy- namo effect is on the order of μ V to mV, and frequency depends upon the ions in the groundwater, with ob- served values between approximately 10 and 50 Hz. Cyclotron frequency is the name given for charged particles moving in circular motion perpendicular to a magnetic field. Each charged particle has a cyclotron frequency based on its charge, mass and velocity rela- tive to the magnetic field. The observed seismic-dy- namo effect reported in Honkura et al. [2009] shows electric frequencies that may be interpreted as reso- nances of the cyclotron frequency of particles and the geomagnetic field, with bicarbonate, chloride, sodium and calcium taken as constituents. These vary in abun- dance by location, and account for differences of ori- entation in the observed electric fields. 6.4. Radioactive ionization Radionuclides release energy as they decay, and that energy can ionize surrounding material. Radon gas is one example. The most common isotope of radon (222Ra) has a half-life of 3.8 days [Jordan et al. 2011]. Sev- eral thousand scientific publications have described the presence of radon as co-seismic with major events. Radon at the Earth's surface ionizes particles in the air, and the motion of these ions creates atmospheric elec- trical phenomena linking the surface to the ionosphere [Pulinets 2007]. Co-seismic ionospheric anomalies might be attributed to the action of ions created as radon is released. Studies of radon occurrence as an earthquake precursor often look for radon concentra- tions in groundwater [Jordan et al. 2011]. It is plausible to assume that radon ionizes other atoms in ground- water, and that the motion of these ions can create an electric signal. Other radionuclides could do the same. 7. Other terrestrial phenomena 7.1. Volcanic electromagnetic signals Hata et al. [2001] report detection of consistent electromagnetic signals during the Izu-Miyake volcanic eruption of 2000 in Japan. The signals preceded the eruption by a week, and were associated with changes to the surface of the Earth from magma dike growth. EARTH ELECTRICITY: A REVIEW OF MECHANISMS The exact mechanism of the signal generation is un- known. The observational apparatus was set to detect extremely low frequency radio waves (between 10 Hz and 300 Hz). Below 10 Hz, ionospheric and other geo- magnetic signals predominate, and above 300 Hz, light- ning noise predominates. The full spectrum of the occuring radiation is not known. 7.2. Seismic electromagnetic signals Matsumoto et al. [1998] report television signal in- terference associated with the 1995 Kobe earthquake in Japan. The electromagnetic radiation preceded the earthquake by 6.5 hours, and was characterized as hav- ing a magnitude of a few tens of mV m-1, a frequency in the 217 MHz range with microsecond duration. Other reports of electromagnetic phenomena during earth- quakes are common, typically involving ionospheric dis- turbances [Davies and Baker 1965, Pulinets and Boyarchuk 2004, Popov et al. 2004, Singh and Singh 2007, Pulinets 2007, Perrone et al. 2010, Heki 2011, Zolotov et al. 2012]. 7.3. Seismic electric signals Three types of signals have been reported from a network of monitoring stations in Greece [Varotsos et al. 1993]. First, a gradual variation in the electric field of the Earth (GVEF) has been recorded, on the order of weeks or more before an earthquake, and with voltage an order of magnitude higher than other purported pre- cursory SES. These occur rarely. Second, presumed seis- mic electric signals, on the order of hours to 11 days before an earthquake, with an order of magnitude in the millivolt range, occur commonly. Third, a short du- ration pulse, 1 to 4 minutes precedent to seismic waves, with an order of magnitude in the volt range, occur rarely [Ralshovsky and Komarov 1993, Varotsos et al. 1993]. All three are low-frequency signals, less than or equal to 1 Hz [Varotsos et al. 2011]. Similar seismic sig- nal data have been reported in Japan using the same method [Uyeda et al. 2009]. 7.4. Fractoemission Fractoemission, in which electrons escape from a freshly cleaved surface, has been described in James et al. [2000]. Their observations show electrical charging of about 10-5 coulombs per kilogram for volcanic ash. Fracture experiments have recorded up to 10 parts per million (ppm) ozone production from the crushing of typical terrestrial crustal rock, with the ozone being generated by electricity from physical charge separa- tion during fracture [Baragiola et al. 2011] The energy of the emitted electrons can be very high, up to tens of thousands of electron volts (10 keV) or higher. The elec- trons are produced as the surface attains and maintains a charge, often pulling electrons from deep inside, termed the Malter effect [Oster et al. 1999]. Electro- magnetic emission resulting from a single crack in ice under various stress regimes has a frequency of 103 to 105 Hz, with a change in potential of about 2 mV [Shibkov et al. 2005]. 7.5. Defect charging Pressure can cause defects in materials. Defects can both liberate charge carriers, such as ions or electrons, and create charge acceptors, such as holes or lattice va- cancies. Pressure changes can also result in the reorien- tation and charging of lattice defects, called defect charging. These processes have characteristic electro- magnetic emissions, with frequencies in the range 102 to 106 Hz for crystals with predominantly ionic bonds [Shibkov et al. 2005]. Defect charging has been studied as a candidate for the cause of electrical signals associated with earth- quake phenomena [Varotsos et al. 1998, Freund 2011]. Takeuchi and Nagao [2013] demonstrate an electro- motive force of 80 mV in gabbro with 50 MPa of load. Freund [2011] proposes that peroxy defects present in silicate rocks, where the tetrahedral silicate bonds are O3Si - OO - SiO3 instead of O3Si - O - SiO3, can be a source of mobile charge carriers. Peroxy bonds commonly break under pressure. The new structure can accept an electron from a neighboring silica-oxygen tetrahedron. That transfer, in turn, creates a positive hole in the elec- tron donor. Positive holes can also interact with nega- tive ions liberated from the lattice by changes in pressure, e.g. from seismic waves. This condition may form paths for electric current to flow. Such defect phenomena are fundamental to how semiconducting materials work, and are probably wide- spread in nature. General terms for the process de- scribed above are "charge-vacancy coupling" or "defect and charge transport" [Raymond and Smyth 1996]. Per- oxy bonds exist in silicate rocks in enough numbers to create measurable electricity. The process of charge-va- cancy coupling is nontrivial in all rocks, given the right conditions. Typical electric currents from defect charg- ing in rock are on the order of 1 nanoampere at 20 megapascals of pressure [Freund 2011]. 7.6. The piezoelectric effect The piezoelectric effect (electric field or charge caused by applied pressure) has been modeled as a crys- tal lattice effect, as deformation from stress or strain dis- places the positions of shared electrical bonds [Cady 1946, Mason 1950]. This is the mechanism first de- scribed by Voigt [Voigt 1910, Katzir 2006]. Stress is an HELMAN 8 9 internal pressure of particles acting on each other, caused by external load. Strain is a change to the shape of a material, caused by stress. Piezoelectricity is based on the symmetry of a crystal. A more in-depth treatment of the ideas in the fol- lowing paragraph can be found in Sands [1994]. Crys- tals can have three types of symmetry. If the coordinates of a crystal lattice are hypothetically reflected through a point, a new inverse lattice with new inverse coordi- nates is created. If the inverse lattice is identical to the original crystal lattice, the crystal is centrosymmetric. If the inverse lattice is not identical to the original crys- tal lattice, but the inverse lattice can be rotated to match the original lattice, then the crystal is non-centrosym- metric. If the inverse lattice is not identical to the origi- nal crystal lattice, and the inverse lattice cannot be rotated to match the original lattice, then the crystal is chiral, also called enantiomorphic. The terms “chiral” and “enantiomorphic” are synonyms and refer to hand- edness. These crystals occur in both left-handed and right-handed forms. For a more in depth treatment of the following de- scriptions of piezoelectricity, see Cady [1946]. A cen- trosymmetric crystal lattice ought not allow for any electrical charge to build up under pressure. Every bond displaced will be countered by another bond whose dis- placement can cancel the charge of the first. However, some minerals with centrosymmetric crystal lattices, such as zeolites and topaz, express electricity under stress and strain. No explanation has yet been proposed for this anomaly. Many chiral and non-centrosymmetric minerals display the piezoelectric effect. The most well-known is quartz, and the most intuitive application at one time was in record needles or microphones, to change varia- tions in pressure into an electrical signal. The electrical signals in these devices are very small, on the order of 10-12 coulombs per newton (C N-1) for a single crystal. Piezoelectric data for some minerals can be found in SpringerMaterials, an online version of the Landolt- Börnstein Database [SPRINGER 2012]. 7.7. The thermoelectric effect A homogeneous conductor expresses a voltage when there is a temperature gradient, with electrons (the more negative) at the cold end. This is called the Seebeck effect (or the thermoelectric effect), and is di- rectly observable as electric current when two dissimi- lar conductors are connected to each other under a thermal gradient [Goupil et al. 2011]. Thermocouples are based on this effect. For more information on the following discussion, see von Baeckmann et al. [1997]. Corrosion of bridges and other metal structures where dissimilar metals are found is caused by this phenome- non. In the crustal materials of the Earth, the thermo- electric effect is important in ore bodies, and in regions with high heat flux. The magnitude is on the order of 10-5 volts per degree Kelvin [SPRINGER 2012]. Geologic case studies are abundant. Shankland [1975] describes measurements of thermoelectricity from rock samples in a laboratory setting. Leinov et al. [2010] describe thermoelectric effects in brine-saturated sandstone in situ. The thermoelectric effect from ore minerals, for example from pyrite during computer- aided resistivity surveys for gold (called pyrite-thermo- electric surveying), has also been described [Cao Ye et al. 2008, Zhang Yun-qiang et al. 2010], as has thermo- electricity from magnetite grains in the Earth’s crust, and especially in the middle-lower crust [Junfeng Shen et al. 2010]. This widespread effect is similar to defect charging (described in the Defect charging subsection, above) in that both processes mobilize charge carriers and holes (acceptors), the one with a temperature gra- dient, the other with pressure. Note that both of the temperature effects listed in this section (i.e. the thermo-and pyroelectric effects) have sometimes been lumped together as the thermo- electric effect. They have been described as such by Cor- win and Hoover [1979], who treat temperature effects as unwanted signal noise in self potential surveying. They are unwanted if one is looking for electrical indi- cations of water flow (from the motion of ion-rich water, and from the electrokinetic effect) for geother- mal use. 7.8. The pyroelectric effect Water is a polar molecule. Any material whose structure has an axis with dissimilar ends, and whose ends are of uneven electrical charge, is a polar mate- rial. The dissimilar ends are called a permanent elec- tric dipole. In polar minerals, electric charges located at the ends of the permanent electric dipole are rapidly neutralized by the environment under normal condi- tions. During heating or cooling, however, the charges do not have time to dissipate, and are detectable. This phenomenon is called pyroelectricity, or the pyroelec- tric effect [Bhalla et al. 1993]. It is sensitive to both the change in temperature and the rate of change in tem- perature of a polar material. Tourmalines are common minerals that exhibit this effect [Hawkins et al. 1995]. Typical magnitudes are on the order of 10-6 coulombs per square meter per Kelvin for single crystal samples. 7.9. Magma electrochemistry The motion of magma during volcanic processes and also of volatiles can hypothetically create an elec- EARTH ELECTRICITY: A REVIEW OF MECHANISMS tric signal. Volatiles can in some instances ionize sur- rounding materials, and magma itself can be rich with ions. No study of these natural electrical phenomena is found in the literature, to the author's knowledge. Tora- maru and Yamauchi [2012], in trying to create an analog to layered dikes and sills, used an externally applied elec- tric field to create cyclically-layered structure in an arti- ficial material, PbI2. 7.10. Radioactive emission Electric current can hypothetically be caused di- rectly by the motion of charged particles released by the breakdown of radionuclides. For example, α -parti- cle emission is a steady source of charged particles, and therefore creates an electric signal. Significant radioac- tive decay has been reported in natural fission reactors as having occurred in the past [Gauthier-Lafaye 1997, Jensen and Ewing 2001, Stille et al. 2003]. Electrical ob- servations of this phenomenon are not in the published literature, to the author’s knowledge. 8. Deep terrestrial phenomena 8.1. Geomagnetic jerk Short-term changes to the second derivative of the geomagnetic field are termed geomagnetic jerks, and arise from electrical signals traveling through the man- tle during deep (core) events [Nagao et al. 2003]. Trans- mission of electricity from the upper mantle to the lower crust is likely, but has not been observed. Separate geomagnetic jerks of limited extent have been modeled as having been caused by single events originating in and traveling through Earth’s core, as described in Chulliat et al. [2009]. The physical models suggest that quantify- ing mantle conductivity is still an open question [Malin and Hodder 1982]. The electrical conductivity of the deep mantle is two orders of magnitude higher than that of the shal- low mantle, with a transition depth of 670 km. An- other region of higher conductivity transition occurs at 2700 km, the D’’ layer, so named as part of Keith Bullen’s Earth taxonomy from the 1940s [Chao 2000, Constable and Constable 2004, Duffy 2008, Ohta et al. 2008]. The increased conductivity has been modeled using a combination of proton conduction if hydrogen is present and polaron conduction, which is electron hole hopping between Fe2+ and Fe3+ ions in minerals that contain iron [Yoshino 2010]. Both of these are semiconductor phenomena. A wet mantle is not gen- erally required to fit the observations [Yoshino et al. 2008]. The increase at the D’’ layer is also related to the transition from perovskite, an orthorhombic mineral, to post-perovskite, a sheet mineral, that occurs at this depth [Duffy 2008]. Bulk rock responses to local changes in the geo- magnetic field caused by changes in the Earth’s core ought to affect ore bodies or other rock with high con- ductivity. No articles are apparently available that report long-term telluric currents caused by fluctuations in the geomagnetic field originating in the Earth’s core. 9. Producing electricity Several models depict electricity-generation processes. Four of these are useful in conjunction with the study of telluric currents. These are listed in Table 3, with a brief explanation for each. Charged particles, if they change location, transfer charge. Charged particles, such as electrons or ions, are termed charge carriers. The motions of ions or electrons are examples of the direct transfer of electric charge. A deeper treatment of the ideas in the following de- scription may be found in Jonassen [2002]. Electrostatic induction is a special case of charged particle transfer. An external charge elicits an electrical response from a second material containing mobile charge carriers. The charge carriers move to neutralize the applied field. If the external charge is positive, for example, then nega- tive charge carriers will migrate within the second ma- terial to the site of the external charge. This model is termed electrostatic induction because the charge trans- fer is induced within one of the materials, but no charge is transferred between them. A more thorough treatment of the ideas in the fol- lowing description may be found in Schieber [1986]. Electromagnetic induction occurs in any electrical con- ductor where a change in a magnetic field occurs, so that the magnetic flux lines pass through the conduc- tor. The combination of mobile charge carriers and magnetic flux creates an electromotive force. This is the principle behind electrical power generation, for exam- ple. A coil of wire moves through a magnetic field, and the motion creates electric current in the wire. Elec- tricity is generated. If the charge carriers in a material are not mobile, electricity can be generated by deformation of the ma- terial, or some other process that changes the config- uration of the domains carrying electric charge. The rearrangement of electrical domains can generate electricity. 10. Monitoring telluric currents The geomagnetic field is currently monitored by an extensive network of government-run observatories and includes a near-real-time international data reposi- tory [Kerridge 2001, INTERMAGNET 2012]. The same is not the case for Earth’s telluric phenomena, but some HELMAN 10 11 EARTH ELECTRICITY: A REVIEW OF MECHANISMS Model Explanation Direct Transfer of Charge Charge carriers such as ions or electrons change location, and their motion transfers electric charge Electrostatic Induction External electric charge creates an electromotive force within a material as particles move to neutralize the external charge Electromagnetic Induction Relative motion of a magnetic field creates an electromotive force on electric charge carriers within it Rearrangement of Electrical Domains Deformation creates electricity as it changes the position of immobile charge carriers in a material Table 3. Electricity-generation models. Name Magnitude Duration Frequency Lightning Strikes Lightning Strike Induction Volcanic Lightning Strikes Artificial Signals GIC (Space Weather) 105 A (peak) 105 A (peak)/104 A > 3kA (peak) Various 200 A (metal) 50 μV m-1 (chorus) Not reported (γ-rays) Not reported (meteors) 1 ms 1 ms Not reported Various ≈ 10s Various Various Various 10-3 to 103 MHz 10-3 to 103 MHz Not reported Various 10-3 to 10-2 Hz 300 Hz to 2 kHz VLF 16 kHz Planetary Magnetic Field Plasma Storm Charging Electrochemical Effetcs Electrokinetic Effects Ocean Transport Induction GIC (Diurnal) Cosmic Particle Flux Whistler Plasma Seismic EM Signals Fractoemission Seismic Electric Signals Seismic Dynamo Induction Thermoelectric Effects Pyroelectric Effects Defect Charging Exo-Electron Emission Volcanic EM Signals TID (Schumann Resonances) Geomagnetic Jerk Magma Electrochemistry Radiaoctive Emission Radioactive Ionization 5000 V (Lunar surface) 10-2 A m-2 5 V 100 mV km-1 25 mV km-1 (metal) 1 mV km-1 (ionosphere) 6000 MeV cm-2 (Mars) 104 e- cm-3 (surface) ≈ 20 to 50 mV m-1 10-5 C kg-1 (ash) 1 to 10 mV μV to mV 10-5 V K-1 10-6 C m-2 K-1 (single crystal) 10-9 A ≤ 108 e- cm-2 1 to 5 pT 1.0 pT Not reported Not reported Not reported Not reported ≈ 1 week hrs to days Various Ongoing Ongoing ≈ 1 d Various Not reported ≈ 1 μs Various Various Various Ongoing Ongoing Various Various Various Ongoing Ongoing Ongoing Not reported Not reported Not reported Not reported < 300 kHz (ocean) 0.1 to 0.5 Hz Some from 10-7.0 to 10-3.8 hz 0.4 Hz Not reported Not reported 217 MHz 103 to 105 Hz (ice) ≤ 1 Hz 10 to 50 Hz Not reported Not reported 102 to 106 Hz Not reported Radio frequencies 10.6, 18.4, 26.0, 33.5, and 41.1 Hz Not reported Not reported Not reported Not reported Oceanic Charging TID (Compressive Event) TID (Gravity Wave) Whistler Induction Metabolic Electrochemistry Not reported Not reported Not reported Not reported Not reported Ongoing Various Ongoing ≈ 30 s Not reported (Hypothetical) Not reported Not reported 10-7 to 10-6 Hz 10 Hz to 30 kHz Not reported Table 2. Magnitude, duration and transmission frequency of Earth electricity, arranged by magnitude. GIC are geomagnetically induced currents, TID are traveling ionospheric disturbances and e- is electrons. national institutions and systems are in place and usu- ally produce freely-available data. China, Russia, South Africa, Japan, Greece, the United States and Canada, for example, all have networks of magnetotelluric stations to monitor seismic events as they sometimes correlate with electrical and magnetic signals. References or web- sites exist for China [Xuhui Shen et al. 2011], Russia [ISTP SB RAS 2012], South Africa [Fourie 2011, FACE- BOOK 2012], Japan [Kawase et al. 1993, Uyeshima et al. 2001, Geospatial Information Authority of Japan 2010], Greece [Varotsos et al. 1993], and the U.S. and Canada [Zhdanov et al. 2011, Incorporated Research Institutions for Seismology 2012]. No global correlation network of electric signal data exists in real time, though the MTNet, maintained by a working group of the International Association of Geomagnetism and Aeronomy will perhaps assume this role [MTNET 2012]. This association houses research results and data, acts as an international forum, and hosts workshops and conferences. Likewise, a working group of the In- ternational Union of Geodesy and Geophysics (IUGG) hosts conferences and workshops on Electromagnetic Studies of Earthquakes and Volcanoes [EMSEV 2013], and they may have a strong interest in creating this type of network. 11. Discussion Thirty-two distinct causes of telluric currents have been listed above. Here are some highlights that might serve to promote further research. These have been se- lected as affecting either public health, the economy, or human progress. – Lightning phenomena, GIC, TID and the ther- moelectric effect are mechanisms that have been of the greatest interest to society, since these can disrupt com- munications or destroy structures and equipment. Ex- cept for lightning, these act via corrosion, and are slow. – The references to self-potential and the electro- kinetic effect may deserve more interest, especially the work out of China, looking at sulfide ores and gold. Rare earth elements also seem to be of strategic eco- nomic and political importance. – Seismic electric phenomena may have immense practical applications for public safety. Distinguishing between purported seismic electric signals and other electrical events might allow for successful earthquake forecasting. – The papers on using plant metabolism to power circuits and batteries may be of interest for alternative energy research. Harnessing plants directly for electric- ity would attack anthropogenic climate change on two levels: by providing carbon sequestration and energy production. It is hoped that there will be more progress in these areas, and that Tables 1 and 2 will be critically assessed and added to. Electrical energy is one of the hallmarks of life, and of space. It is critical for the transfer of in- formation, as well. As more of human culture takes ad- vantage of electronic media, it seems logical and benign to extend human knowledge of electricity in the Earth itself. For example, remote sensing is now available for our homes, and we can turn on lights in a room just by moving towards it. How much more important is it, now, to build a more complete system of remote sens- ing for our global home, the Earth, and its environs? 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