ARID ZONE JOURNAL OF ENGINEERING, TECHNOLOGY & ENVIRONMENT AZOJETE, September 2019. Vol. 15(3) 678-691 Published by the Faculty of Engineering, University of Maiduguri, Maiduguri, Nigeria. Print ISSN: 1596-2490, Electronic ISSN: 2545-5818 www.azojete.com.ng 678 ORIGINAL RESEARCH ARTICLE SEASONAL VARIATION IN RATES OF DUST FALL AT MOTOR PARKS OF UNIVERSITY OF ILORIN, ILORIN, NIGERIA F. O. Nwosu1*, O. D. Olayinka1 and C. O. Akoshile2 (1Department of Industrial Chemistry, University of Ilorin, P.M.B 1515 Ilorin, Nigeria 2Department of Physics, University of Ilorin, P.M.B. 1515 Ilorin, Nigeria) * Corresponding author’s email address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng ARTICLE INFORMATION Submitted 22 November, 2018 Revised 7 March, 2019 Accepted 10 March, 2019 Keywords: Insoluble Dust Soluble Dust Ash Volatile Matter Wet Season Dry Season ABSTRACT The enormous vehicular activities on the commercial motor parks of University of Ilorin, Nigeria called for concern as a result of noticeable level of particulate matter in the atmosphere of the area. This study was carried out to indicate the seasonal variation in the rate of dust fall at three motor parks in the permanent site of the University campus by using the single bucket sampling method. The study was carried out for five months each of wet and dry season periods. The sampling sites were First Motor Park (PK1), New Motor Park (PK2) and Clinic Area (Cl). Gravimetric method was used to quantify the soluble, insoluble, volatile matter and ash content of the dust. Volatile matter and ash were the component of insoluble dust and the highest rate of insoluble dust deposition was observed in January (2043.12 ± 41.4 and 284.1 ± 35.5 mg/m2/day) for PK2 and Cl and in November (1282.7 ± 64.9 mg/m2/day) for PK1 when their respective traffic density (1509.5 ±72.1, 29.8 ± 1.2 and 1000.8 ± 48.3 vehicles per hour) was highest. The highest (32713.0 ± 1290.1 mg/m2/day) and lowest (70.6 ± 6.9 mg/m2/day) rate of soluble dust deposition in the study were observed at PK1 for September and February respectively which was suspected to be due to increase and decrease in the amount of rain fall. The Pearson Correlation showed that increases in traffic density were correlated with increases in the rate of insoluble dust fall at various sites and the relationship was in the stronger order of PK2 > PK1 > Cl. The motor parks ambient air was highly contaminated with soluble dust in the wet season and insoluble dust in the dry season their being values are more than the recommended 133 mg/m2/day. © 2019 Faculty of Engineering, University of Maiduguri, Nigeria. All rights reserved. 1.0 Introduction Air pollutants can either be particles, liquids or gaseous in nature. Pollutants may come from natural sources or caused by human activities (anthropogenic) such as use of motor vehicles, domestic activities, industry and other economic activities (Jimoda, 2012). Particulate matter is used to describe contaminant particles like dust found in the air (Yahi et al., 2014; Nwosu et al., 2016). There could be environmental degradation and hazard on the health status of human and animal due to presence of particulate matter in the air (Kamble, 2015). Particulate matter in the form of dust is usually in the size range from about 1 to 10μm in diameter, and they settle slowly mailto:f.o.nwosu@gmail.com http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 679 under the influence of gravity (Espinosa et al., 2001). The ones greater than 10μm that settle to surfaces from the air are the main component of dust fall (Sami et al., 2006; Alahmr et al., 2012) and are too heavy to remain suspended in the air for any period of time. The potential environmental impacts of dust fall were described by Piechota et al. (2002) to include surface and groundwater quality deterioration, soil contamination, toxicity to soil and water Its toxicity to humans, air pollution and changes in hydrologic characteristics of the soils cannot be over emphasized. A number of medical conditions can be traced to the impact of dust, and the effects of fine wind-borne particles on human health (Garrison et al., 2003, Polizzi et al., 2007, Alahmr et al., 2012). The most health-damaging dust particles are those lesser in size with a diameter less than 10 microns (10µ ≤ PM). Humans mostly at risk are elderly and children with symptoms of asthma, heart or cardiovascular disease as stated by Kamble (2015). The presence of dust in the ambient air is very noticeable in the areas where there are more vehicular activities and the composition varies in complex mixture of soluble and insoluble forms of organic and inorganic substances suspended in the air (Polizzi et al., 2007). The enormous vehicular activities on the commercial motor parks of University of Ilorin, Nigeria called for concern as a result of noticeable level of particulate matter in the atmosphere of the area due to continuous increase of students and other users of the parks. Therefore, the objective of this study is to assess the seasonal variations and traffic effect on the rate of soluble, insoluble, volatile matter, ash and total dust fall at three different parks in the permanent site of the University of Ilorn. 2. Materials and Method 2.1 Study Area The dust samples were collected at three different motor parks within the permanent site of University of Ilorin, Kwara State, Nigeria. There were two parking locations for commercial vehicles within the campus of the permanent site of University of Ilorin between 2016 and 2017 during the period of this study. The first motor park is located behind Lagos Boys’ Hostels of the school, another park; the New Park is by the Sky Chicken restaurant in the permanent site of the University campus. The Clinic Area of the University is about 150 m away from the location of the New Park and is a parking lot for the clinic staff and their visitors. Figure 1 shows the sampling point locations. It should be noted that none of the parks was paved during the period of the study. Figure 1: Google Map of University of Ilorin (permanent site) showing the Park locations The nomenclature of sampling points and description of geographical coordinates are given in Table 1. file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng Nwosu and Olayinka: Seasonal Variation in Rates of Dust Fall at Motor Parks of University of Ilorin, Ilorin, Nigeria. AZOJETE, 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com, fonwosu@unilorin.edu.ng 680 Table 1: Description of sampling points and their geographical location. Sampling Points Location Point Coordinates PK1 First Motor Park 8°47’94.2’’N 4°67’06.9’’E PK2 New Motor Park 8°48’13.8’’N 4°66’84.0’’E Cl Clinic Area 8°48’27.5’’N 4°66’90.3’’E 2.2 Material Preparation All the sampling buckets were usually washed thoroughly with soap and water, followed by dilute nitric acid and then deionised water before drying properly. Also, all the sampling apparatus were cleansed by subjecting them to acid wash and then rinse with distilled water before use. Analytical grade stock solutions were used for the preparation of samples and standards. 2.3 Sampling Method The dust fall (bulk type) was sampled using the method of open bucket system according to IS 5182 (2006) and ASTM (2010) standard procedures. This involved the use of a cylindrical sampling bucket with height (h), radius (r) and surface area (A) of 0.342 m, 0.138 m and 0.05983 m2 respectively as employed by. Annegarn and Scorgie, (2002); Moja and Mnisi, (2013); Kamble, (2015) and Nwosu et al., (2016) in their various studies. The 20 L bucket was filled with a known 5 L of distilled water, opened and exposed on a rigid stand to trap the dust fall sample. The rigid stand of 2 m long comprised of a ring supported by four stabilizing bars above the base plate to prevent the sample from contamination by perching birds. The openings of the buckets were covered with insect net so as to only collect dust of smaller size which is most hazardous to health. Although there was rapid evaporation due to exposure of sampling bucket, the 5 L distilled water in the bucket was sufficient to remain and trap dust sample during each sampling period. Also, it usually do not overflow due to rainfall during sampling period. Figure 2 shows one of the rigid stands with bucket used for the sampling. The stands were buried into the earth to a depth of about 0.5 m according to some criteria laid by ASTM D 5111 Standards (ASTM, 1996) such as locating the sampler towards the predominant wind direction and considering the distance from obstacles that could interfere in sampling. The sampling buckets were exposed at the various sites for a month and the sampling buckets were replaced with new ones of the same dimensions following the same process. The study was carried out for a total of ten months to include five months of rainy season period (September and October, 2016; April to June, 2017) and five months of dry season period (November and December 2016, January to March, 2017). Figure 2: One of the Sampling Stands at the First Park http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 681 2.4 Traffic Density The estimation of the traffic density was conducted by counting the number of vehicles that went in and out of the park during the periods of heavy traffic, usually about 3h in the morning and 3h in the afternoon. The average of morning and afternoon counts was the traffic count for a day. Two different daily counts were obtained during the sampling period of each month throughout the study. The average of the daily counts was used to determine the traffic density for each month (number of vehicles per hour) according to Adekola and Oloruntoba (2000). 2.5 Determination of Insoluble Particle Fall Out Rate A dried pre-weighed ashless filter paper number 42 was placed in the filter unit according to IS 5182 (Part 1) (2006). The bucket content was then carefully poured through the filtration set up to obtain a filtrate and residue. The residue, an insoluble component of the dust fall, was weighed after drying in an oven at 105°C for 2 hrs. The rate of insoluble dust fall was estimated in duplicate following the method stated by IS 5182 (Part 1) (2006) and Norela et al. (2009) based on number of days and the surface area of the bucket, calculated as in equation (1): where: Cidf = Concentration of Insoluble dust fall (mg/m2/day), Mf = Weight of loaded filter (mg), Mb = Weight of blank filter (mg), A = Surface area of the bucket (m2), T = Sample duration (days). 2.6 Determination of Total Soluble Particle Fall Out Rate A known volume of filtrate (soluble matter) obtained from 2.3 was concentrated in a pre- weighed evaporating dish and dried in an oven at 105°C for 2h as stated by Latif and Rozali (1999). It was cooled in a desiccator before being weighed. The rate of soluble dust fall was calculated as given in the equation (2): Css (mg/m2 )/day = �� −�� �� �2 AT ………….(2) where: Css = Concentration of soluble solids, M3 = Weight of evaporating dish without the soluble matter (mg), M4 = Weight of soluble matter with the weight of the evaporating dish (mg), V1 = volume of filtrate (all the water in the sampling bucket) (mL), V2 = Volume of filtrate used for analysis (30 mL), A = Bucket surface area (m2), T = Sampling period (days). file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng Nwosu and Olayinka: Seasonal Variation in Rates of Dust Fall at Motor Parks of University of Ilorin, Ilorin, Nigeria. AZOJETE, 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com, fonwosu@unilorin.edu.ng 682 2.7 Determination of Total Dust Particle Fall Out Rate Total dust particle was computed in duplicate by the addition of concentration of the insoluble and soluble dust fall together according to the AQMM (2016) and IS 5182 (Part 1) (2006) as shown in equation (3): TDF (mg/m2/day) = Cidf +Css ………… (3) where: TDF = Total dust fall rate (mg/m2/day), Cidf = Concentration of Insoluble dust fall (mg/m2/day), Css = Concentration of soluble solids (mg/m2/day). 2.8 Determination of Ash Particle Fall Out Rate A known mass of the homogenised dried insoluble matter from 2.3 above was collected into an ashless filter paper. This was then put in a pre-weighed porcelain crucible. The porcelain crucible was placed in a muffle furnace and fired at 550 ºC for 4 h. The sample was cooled to constant weight. The amount of ash was determined in duplicate using the equation (4) due to Norela et al. (2009): AshRate mg/m2/day = (Mfa − Mco) AT ………….(�) where: Mfa = Weight of porcelain crucible with ash after incineration (mg), Mco = Weight of porcelain crucible only (mg), A= Surface area of the sampling bucket (m2), T= Sampling period (days). 2.9 Determination of Volatile Particle Fall Out Rate This was estimated in duplicate using equation (5) due to Al-Harbi (2015) and Kamble (2015). VM (mg/m2/day) = Cidf – Ash rate …………….(5) where: VM =Volatile matter, Cidf = Rate of Insoluble PM in mg/m2/day 2.10 Meteorological data Meteorology data of rain fall, wind speed, humidity and temperature were obtained from the Atmospheric Research Laboratory, Physics Department, University of Ilorin, Ilorin, Nigeria. This department have the appropriate instruments that measured the various meterological factors. 3.0 Results and Discussion 3.1 Traffic Density Table 2 shows the average rate of various dust depositions with traffic density at the three sites. The highest traffic density at PK1 was 1000.8 ± 48.3 vehicles per hour in November while the least traffic density at PK1 was 3.0 ± 0.5 vehicles per hour in April. The highest traffic density at PK2 was in January (1509.5 ± 72.1 vehicles per hour) while the least (43 ± 3.3 vehicles per hour) was in September. The traffic density at Cl was highest (29.8 ± 1.2 vehicles per hour) in January while lowest (16.5 ± 0.7) in September. The least value of traffic density in this study was observed in April (3 ± 0.5 vehicles per hour) at PK1 during the period of inter-semester break http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 683 and when it was not really active as Motor Park. Though, the school resumed in October, it seemed most students and staff resumed fully to school or more visitors entered into the school campus in January. This accounted for the highest traffic density in this study to be in January (1509.5 ± 72.1 vehicles per hour) at PK2. Also PK2 was the most active park during this January period. Nwosu et al. (2016) reported a similar observation on a motor park in the same University. Table 2: Average and Standard Deviation of Soluble, Insoluble, Ash, Volatile and Total Dust Fall in mg/m2/day with Traffic Density (Number of vehicles per hour) (n = 2). Month Sample Insoluble Soluble Ash Volatile Matter Total Dust Fall Traffic Density Sep PK1 340.8 ± 3 32713.03 ± 1290 94.4 ± 1.4 246.1 ± 4.3 33053.5 ± 1287 305 ± 22.6 PK2 208.9 ± 0 27579.6 ± 732 82.7 ± 1.2 126.2 ± 1.2 27788.5 ± 732 43 ± 3.3 Cl 154.6 ± 5.9 19706.2 ± 442 116.3 ± 3.9 38.3 ± 2.0 19860.8 ± 448 16.5 ± 0.7 Oct PK1 355.1 ± 5.9 18094.8± 928 124.4 ± 14.6 230 ± 8.7 18094.8 ± 928 387.8± 22.4 PK2 305.4 ± 6.5 17012.1 ± 666 136.1 ± 17.03 169 ± 23.5 17317.5 ± 672 51.2 ±2.1 Cl 213.1 ± 5.9 13780.4 ± 826 170.1 ± 15.5 43 ± 9.6 13993.5 ± 8 18.3 ±0.9 Nov PK1 1282.7 ± 64.9 4671.5 ± 454 690.1± 16.8 592.6 ± 48.1 5954.2 ± 389 1000.8 ± 48.3 PK2 630.9 ± 17.7 1848.5 ± 102 503.7 ± 66.4 127.2 ± 48.7 2479.4 ± 120 58.5 ±3.1 Cl 238.6 ± 29.5 1314.4 ± 199 179.4 ± 29.4 58.8 ± 0.3 1552.5 ± 228 25.7 ± 1.9 Dec PK1 129.5 ± 5.9 2372.3 ± 466 40.9 ± 4.6 88.7 ± 1.3 2501.8 ± 460 3.5 ± 0.7 PK2 2013.9 ± 118.2 891.1 ± 31.2 431.02 ± 27.2 1582.8 ± 91 2905 ± 87 1428.7 ± 388 Cl 309.2 ± 11.8 727.7 ± 26.6 227.7 ± 16.3 81.5 ± 4.5 1036.84 ± 14.8 25.8 ± 2.6 Jan PK1 259.0 ± 11.8 825.9 ± 33.2 213.5 ± 11.7 45.5 ± 0.1 1085 ± 21.4 5.3 ± 0.9 PK2 2043.1 ± 41.1 1247.3 ± 39.5 1865.8 ± 30.4 177.3 ± 11 3290.4 ±1.9 1509.5 ±72.1 Cl 284.1 ± 35.5 983.5 ± 12.1 266.2 ± 34.5 17.9 ± 0.9 1267.6 ± 47.6 29.8 ± 1.2 Feb PK1 254.9 ±29.5 70.6 ± 6.9 179.8 ±21.1 75.0 ± 8.5 325.5 ± 22.7 4.3 ± 0.9 PK2 1654.6 ±23.6 134.9 ±15.6 363.3 ±10.3 1291.2 ± 13.4 1789.1 ± 8 1506 ±144.2 Cl 267.4 ±11.8 281.5 ± 25.7 192.3 ± 9.9 75.1 ± 1.9 548.9 ± 13.8 29.7 ± 2.8 file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng Nwosu and Olayinka: Seasonal Variation in Rates of Dust Fall at Motor Parks of University of Ilorin, Ilorin, Nigeria. AZOJETE, 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com, fonwosu@unilorin.edu.ng 684 Mar PK1 208.9 ± 11.8 297.5 ± 41.4 88.6 ± 2.4 120.3 ± 14.2 506.4 ± 29.5 3.8 ± 0.2 PK2 1261.8 ± 11.8 500.6 ± 15.3 554.6 ± 1 707.2 ± 10.8 1762.4 ± 3.5 930 ± 59.4 Cl 263.2 ± 5.9 446.4 ± 10.8 115.8 ± 0.12 147.4 ± 5.79 709.6 ± 4.92 21.8 ± 1.2 Apr PK1 254.9 ± 5.9 502.6 ± 1.4 76.4 ± 4.8 178.5 ± 10.7 757.5 ± 4.6 3 ± 0.5 PK2 292.5 ± 11.8 886.0 ± 64.6 104.7 ± 1.5 187.8 ± 13.3 1178.5 ± 52.8 528 ± 169.7 Cl 288.3 ± 5.9 690.4 ± 9.7 170.1 ± 0.6 118.2 ± 6.5 978.7 ± 3.8 17 ± 1.9 May PK1 167.1 ± 11.8 4129.4 ±382 60.5 ± 8.2 106.6 ± 3.6 4296.5 ± 370.2 3.7 ± 0.9 PK2 259.0 ± 11.7 2541.6 ±10.0 239.7 ± 16.4 19.3 ± 4.6 2800.6 ± 21.9 1164 ± 67.9 Cl 228.1 ± 3.6 2219.2 ±208 189.3 ± 0.3 38.8 ± 3.8 2447.3± 211.9 26.3 ± 0.9 Jun PK1 271.6 ± 17.7 3416.3 ± 364 68.0 ± 8.9 203.5 ± 8.9 3687.8 ± 381 992 ± 18.4 PK2 196.4 ± 17.7 3326.1 ± 174 37.4 ± 0.9 158.9 ± 16.9 3522.5 ± 156.7 1057.5 ± 31.8 Cl 346.8 ± 17.7 3813.5 ± 299 154.8 ± 21.3 191.9 ± 3.6 4160.3 ± 281 24.5 ± 0.7 (±) standard deviation 3.2 Insoluble, Soluble Dust and Traffic Density The lowest insoluble dust was observed at PK1 in the month of December (129.5 ± 5.9 mg/m2/day) which could be due to low traffic density (3.5 ± 0.7 vehicles per hour) observed at this park during the month as shown in Table 2. The highest (2043.12 ± 41.4 mg/m2/day) insoluble dust was observed at PK2 for the month of January which may be attributed to the highest traffic density (1509.5 ±72.1 vehicles per hour) observed at the park in that month. The highest insoluble dust was observed in January (2043.12 ± 41.4 and 284.1 ± 35.5 mg/m2/day) for PK2 and Cl respectively; PK1 in November (1282.7 ± 64.9 mg/m2/day) when their respective traffic density (1509.5 ±72.1, 29.8 ± 1.2 and 1000.8 ± 48.3 vehicles per hour) was highest. The same observation was reported by Khan et al., (2002), Khan et al. (2013), Norela et al. (2009), Malokootia et al. (2013), Tyagi et al., (2014) and Nwosu et al., (2016) in their separate studies. That is, the rate of insoluble dust deposition increased as the traffic density increased. This means that movement of vehicles and passengers are key factors in the generation of insoluble dust. The soluble dust had no regular pattern of relationship with the traffic density. Thus, some other factors may be responsible for its deposition. 3.3 Ash Matter, Volatile Matter and Traffic Density Generally, the highest (1865.8 ± 30.4 mg/m2/day) ash matter was observed at PK2 for January and the lowest (40.9 ± 4.6 mg/m2/day) was obtained at PK1 for December as given in Table 2. http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 685 The traffic density was highest (1509.5 ±72.1 vehicles per hour) at PK2 in the month of January. Also, PK1 which had the lowest ash in December had a very low traffic density (3.5 ± 0.7 1 vehicles per hour). Thus, it seemed that the major cause of the ash component is dependent on the traffic activities. During the period of this study, the highest (1582.8 ± 91 mg/m2/day) volatile matter was observed at PK2 for December which was not the month of its highest traffic density. Volatile matter was lowest (17.9 ± 0.9 mg/m2/day) for January at Cl when it had its highest traffic density as 29.8 ± 1.2 vehicles per hour. This seemed that volatile matter did not necessarily depend on the traffic density. That is, vehicular activities were likely not the major cause of volatile matter but probably the combustion of oil, refuse and tiny decaying leaves shed from the trees around the areas of study (Kamble, 2015). 3.4 Dust fall at various sampling points As can be seen from Table 2, the soluble dust generally decreased monthly from September to February and increased from March to May at all the sampling points such that the highest (32713.0 ± 1290.1 mg/m2/day) and lowest (70.6 ± 6.9mg/m2/day) soluble dust in the study were observed at PK1 for September and February respectively. The decrease in the soluble dust must be due to decrease in the amount of rain fall from September to February while the increase must be due to increase in rain fall and precipitation from March to May. This was in line with the findings of Norela et al. (2009) and Kamble (2015) who said that the soluble dust was always more than the insoluble dust in the wet season. Therefore, the major cause of the soluble dust may be components of aerosols which are usually washed down from the atmosphere in larger quantity by rain during wet seasons. On the other hand, the insoluble dust increased from September to January and decreased from February to May for PK2 and Cl. At PK1, the insoluble dust increased from September to November before the park became inactive in December. The increase in the insoluble dust was likely due to decrease in the amount of rain fall from September to January. AL-Harb (2015) reported that insoluble dust increases as the rain fall decreases. This is because when there is no heavy rain fall to wet the ground and wash away the top soil, the traffic activities would be able to lift more dust into the atmosphere. 3.5 Seasonal Comparison of the three sampling points and other studies The average rate of parameters of each season was obtained by taking the average of monthly concentrations for each season. Table 3 presents seasonal comparison of average insoluble, soluble, volatile, ash and total dust fall. 3.5.1 Wet Season The results in Table 3 for wet season shows that rate of soluble dust was highest (11771.2mg/m2/day) at PK1 followed by PK2 (10269.1mg/m2/day) and then Cl (8041.9mg/m2/day). There was probably high amount of soluble particles in the suspended particulate that was washed down by rain fall at PK1 than PK2 and Cl. The observed amount for the rate of soluble dust in the present study at all the sampling sites during the wet season period was higher than observed by Norela et al. (2009) (216.11 mg/m2/day) and Alahmr et al. (2012) (78.41 mg/m2/day). This may be because the study of Norela was at a residential area and that of Alahmr et al. (2012) was at a Semi-Urban Area both of which have less amount of soluble aerosol or suspended particulate matter washed down by the rain fall or the rain falls were not heavy enough to wash down the suspended matter. The insoluble dust at all sampling points were very close in the wet season with PK1 having the highest (277.9mg/m2/day), followed by file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng Nwosu and Olayinka: Seasonal Variation in Rates of Dust Fall at Motor Parks of University of Ilorin, Ilorin, Nigeria. AZOJETE, 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com, fonwosu@unilorin.edu.ng 686 PK2 (252.4 mg/m2/day) and then Cl (246.2 mg/m2/day). The insoluble dust at all the sampling points in this present study during the period of wet season were more than that of Norela et al. (2009) (37.83 mg/m2/day) and Alahmr et al. (2012) (53.08 mg/m2/day). This may be attributed to the two studies conducted in areas of less traffic densities and low generation of dust. Table 3: Seasonal Comparison of Average Insoluble, Soluble, Ash, Volatile and Total Dust fall (mg/m2/day) in this study and previous studies (*) Not available The total dust fall at PK1 was highest (12049.1 mg/m2/day) followed by PK2 (10521.5 mg/m2/day) and then Cl (8288.1 mg/m2/day) according to Table 3. That means the rate of dust deposition at PK1 was higher than PK2 and Cl in the wet season period. The observed amounts of total dust Study Research Site Area Season Traffic Density Soluble Insoluble Volatile Matter Ash Total Dust Fall DOE, 2005 This study,PK1 Motor Park Wet Season 338.3 hr-1 11771.2 277.9 193.1 84.7 12049.1 133 Dry Season 203.5 hr-1 1647.6 427 184.4 242.6 2074.6 This study,PK2 Motor Park Wet Season 568.7 hr-1 10269.1 252.4 132.3 144.4 10521.5 Hot Season 1086.5 hr-1 924.5 1520.8 543.2 974 2445.3 This study,Cl Motor Park Wet Season 20.5 hr-1 8041.9 246.2 85.3 167.6 8288.1 Dry Season 26.6 hr-1 750.7 272.4 76.1 196.3 1023.1 Nwosu et al., (2016) Unilorin Motor Park Dry Season 300 day-1 * 1122.2 * * * Kwasu Motor Park Dry Season 103.2 day-1 * 627.7 * * * Unibadan Motor Park Dry Season 273.4 day-1 * 316.3 * * * Alahmret al., (2012) Semi- Urban Area (Kajang and Bangi, Malaysia) Wet Season * 78.41 53.08 * * 131.50 Norela et al., (2009) Residential Area (Negeri Malaysia) Wet Season * 216.11 37.83 * 106.96 253.95 Al-Harbi, 2015 Urban area, (Shuwaikh, Kuwait) Dry Season * * * * 944.23 * http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 687 fall in this study at all the sampling stations were higher than observed by Norela et al. (2009) (253.95 mg/m2/day) and Alahmr et al. (2012) (131.50 mg/m2/day). This may be because the study of Norela was at a residential area and that of Alahmr was at a Semi-Urban Area, both of which may have lesser amount of settling dust. The volatile matter component was highest (193.1mg/m2/day) at PK1 followed by PK2 (132.3 mg/m2/day) and then Cl (85.2mg/m2/day) in the wet season. Volatile was higher than ash in the months of the wet season while low in the months of the dry season for PK1. It was probably because PK1 had been a motor park quite a time before this study. Rainfalls could have washed down suspended matter generated as a result of combustion of oil, refuse and tiny decaying leaves shed from the trees around the area. The volatile matter was higher than ash in the months of the wet season for PK1. The ash matter in the wet season as presented in Table 6 shows highest value (167.5mg/m2/day) at Cl followed by PK2 (144.4 mg/m2/day) and PK1 (84.7mg/m2/day). This high value at Cl could mean that the top sandy soil at Cl was rich in soil mineral than in PK1 and PK2 areas in the wet season period. The top soil could be blown up by rainy season wind to become settling dust. All the values obtained for ash in this study during wet season period were higher than (106.96mg/m2/day) obtained by Norela et al, (2009). 3.5.2 Dry Season Table 3 also presents the results obtained in the dry season period. Soluble component was highest (1647.6 mg/m2/day) at PK1 followed by PK2 (924.4mg/m2/day) and then Cl (750.7mg/m2/day). The highest value at PK1 could be as a result of deposition of soluble particles lifted from the ground. The insoluble component was highest (1520.8mg/m2/day) at PK2 followed by PK1 (427mg/m2/day) and then Cl (272.4mg/m2/day) in the dry season as presented on Table 3. This must have resulted from their respective obtained traffic density (1086.5, 203.5, 26.6 vehicles per hour) in the season. The insoluble dust obtained for PK2 in the dry season of this present study was more (1743.3mg/m2/day) than that obtained by Nwosu et al. (2016) (1122.2 mg/m2/day) at a motor park in the same university environment. The higher average traffic density (1086.5 vehicles per hour) observed for dry season at PK2 during this present study compared to that of Nwosu et al. (2016) (300, 103.2 and 273.4 vehicles per day) in the same dry season must have contributed to the increase in the insoluble dust. Total dust fall at PK2 was the highest (2445.3mg/m2/day) followed by PK1 (2074.5mg/m2/day) and then Cl (1023.1 mg/m2/day) in the dry season. The high traffic density (1086.5 hr-1) and hauling movement of people on the dry unpaved area of land at PK2 must have greatly contributed to this high value. Volatile matter component was highest at PK2 (543.2 mg/m2/day) followed by PK1 (184.4 mg/m2/day) and then Cl (76.1mg/m2/day) in the dry season as shown in Table 3. The soil around PK2 could contain more of volatile dust than other sites in this study. It might be because it was formerly a grass land before it was recently adopted as a motor park. Therefore, it was easier for traffic activities and hauling movement of people to have contributed to lifting of soil reach in organic matter in the area. The ash matter component presented on Table 6 was highest (974 mg/m2/day) at PK2 followed by PK1 (242.5mg/m2/day) and Cl (196.3mg/m2/day) in the dry season. That is the insoluble dust collected at PK2 during the dry season contains more of ash than Cl which has the highest in the rainy season. Also, ash component at PK2 in the dry season was more than that obtained (944.23 mg/m2/day) by Al-Harbi 2015 in an urban area of his study. file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng Nwosu and Olayinka: Seasonal Variation in Rates of Dust Fall at Motor Parks of University of Ilorin, Ilorin, Nigeria. AZOJETE, 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com, fonwosu@unilorin.edu.ng 688 3.5.3 Comparison between Dry and Wet Seasons Figures 4-6 show the seasonal comparison of dust fall and components at all sampling sites. It was observed that at all the sampling points in this study; the total dust in the wet season period was more than that in the dry season period which could be attributed to the washing down of more suspended particulate matter in the rainy season than dry season. According to Alahmr et al. (2012), wet deposition is the main process which brings down particles from the air. Soluble component obtained during the wet season period was found to be more than that of the dry season period. That is, rain fall do contribute to the washing of the atmosphere thereby depositing aerosol and other particulate matter most of which are probably dissolved in water. Chate and Pranesha (2004) reported that heavy rain could capture aerosol particles and wash it down from the atmosphere. The insoluble matter was lower in the wet season period than in the dry at all the sampling points. Glavas et al. (2008) and Al-Harbi (2015) reported that heavy rain fall causes wetting of the ground and wearing away of the top soil which cause reduction in insoluble matter during wet season. That is, insoluble dust increases from wet season period to the dry season period. Figure 4: Seasonal Comparison of Total Dust Fall and Components at PK1 (Tdf = total dust fall, Sol = soluble dust, Ins = insoluble dust, Vol = volatile matter and Ash) Figure 5: Seasonal Comparison of Total Dust Fall and Components at PK2 (Tdf = total dust fall, Sol = soluble dust, Ins = insoluble dust, Vol = volatile matter and Ash) This is according to the findings of Kamble (2015) and Ifeanyi et al. (2016) that reported dust fall increases during the dry season because of low humidity conditions which enables easy lifting of dry soil by hauling movement and traffic activities. Volatile matter was lower in wet season http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 689 period than in the dry season period at PK2, while the opposite was the case at PK1 and Cl. Rainfalls could have washed down suspended matter generated as a result of combustion of oil, refuse and tiny decaying leaves shed from the trees around the PK1 and Cl. Kamble (2015) also observed that increase in volatile matter may be from combustion of oil, coal or refuse. Ash matter was also lower in wet season period than in dry season period at all the sampling points. The observation suggested that the surface dust found around all the sampling points may be rich in minerals which have been blown into the container by traffic and wind activities. Figure 6: Seasonal Comparison of Total Dust Fall and Components at Cl (Tdf = total dust fall, Sol = soluble dust, Ins = insoluble dust, Vol = volatile matter and Ash) 3.6 Influence of Meteorological parameters on Dust Fall Level Table 4: Meteorological Data Parameter Wet Period Dry Period Temperature (ºC) 28.02 ± 2.18 31.51 ± 1.67 Relative humidity (%) 59.57 ± 11.07 44.02 ± 8.49 Rainfall (mm) 0.73 ± 1.02 0 Wind speed (km/h) 2.04 ± 0.69 1.76 ± 0.7 Table 5: Pearson Correlation Sig (2-tailed) for Comparison of Dust fall, Traffic Density and Rainfall Pearson Correlation Coefficient (r) Sites Insoluble/Traffic Density Insoluble/Rainfall Soluble/Traffic Density Soluble/Rainfall PK1 0.687 -0.018 0.178 0.988 PK2 0.707 -0.432 -0.641 0.991 Cl 0.557 -0.757 -0.633 0.978 Correlation is significant at the 0.05 level The meteorological data supported the discussion so far. There was a lower average temperature (28.02 ºC), higher relative humidity (59.57 %) average higher rainfall (0.73 mm) and an average higher wind speed (2.04 km/h) in wet season than their dry season corresponding value as shown in the Table 4. The lower temperature and higher humidity favour the binding of aerosol particles in the atmosphere while the higher rainfall contribute in increasing the washing down of these aerosol particles which are majorly soluble in water in rainy season. Although the wind speed was lower in the dry season, the increase in the level of insoluble dust must have been caused by the hauling movement and traffic activities in the studied sites. Also, increase in file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng Nwosu and Olayinka: Seasonal Variation in Rates of Dust Fall at Motor Parks of University of Ilorin, Ilorin, Nigeria. AZOJETE, 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com, fonwosu@unilorin.edu.ng 690 temperature, decrease in relative humidity, and decrease in rainfall activities favour the lifting of soil particles into the collecting containers (Mkoma et al. (2010), Kamble (2015) and Ifeanyi et al. (2016). 3.7 Pearson Correlation A Pearson product-moment correlation coefficient was computed to assess the relationship between the levels of insoluble and soluble dust generated with traffic density and rainfalls at various sites. The closer the coefficient (r) to 1, the stronger the relationship while the closer it is to 0, the weaker the relationship. The results are shown in the Table 5. There was a positive correlation for monthly data of insoluble/traffic density at various sites such that increases in traffic density were correlated with increases in the level of insoluble dust at various sites. The relationship was strongest at PK2 (r = 0.707), followed by PK1 (r = 0.687) and the Cl (r = 0.557). However, there was a negative correlation for monthly data of insoluble/rainfall at various sites. That is, as either of them increases, the other decreases. The monthly level of soluble dust showed a weak positive correlation (0.178) with traffic density at PK1 while it was negative at PK2 (r = -0.641) and Cl (r = -0.633). Also, level of soluble dust showed a very strong correlation with amount of rainfall at all sites, PK1 (r = 0.988), PK2 (r = 0.991) and Cl (r = 0.978). This also suggests that increases in the amount of rainfall correlated with increases in the level of soluble dust fall. 4.0 Conclusion This study had observed that the highest total dust fall and soluble dust fall were obtained in the month of September while that of insoluble dust was in the month of January for PK2 and Cl while in November for PK1. Also, the rate of soluble dust and total dust deposition decreases from wet season to dry season while that of insoluble dust and ash deposition increases from the wet season to dry season. These variations were observed to be majorly as a result of traffic density and were supported with meteorological data. The observed total dust fall in dry and wet seasons at various sites is more than the recommended 133 mg/m2/day of Malaysian Department of Environment. It was also above the South African permissible limit (600 – 1200 mg/m2/day) for dust in heavy commercial and industrial area (SANS 1929, 2005). Therefore, the motor parks ambient air was highly contaminated with soluble dust in the wet season and insoluble dust in the dry season. It is therefore advisable for the University Community and other appropriate authority that have unpaved motor parks all over the nation to take necessary control measurements such as proper paving or regular wetting of the park. References Adekola, FA. and Oloruntoba, K.2000. Seasonal Variation in Heavy Metals Distribution in the Roadside Soils and Vegetation in Ilorin City and Its Environs, Nigeria. Bioscience Research Communications, 1(2): 1-8. Ahmad, N. 1975. Air Pollution Survey of the Peshawar University Area. Pakistan Journal Science, 27:149–152. AQMM, 2016. National Environmental Engineering Research Institute, 1978. Air Quality Monitoring Manual. Nagpur, India, pp. 3-21. Accessed online (16/07/2017). Alahmr, FO., Murnira, O., Nurul, BA., Azhar, A. and Mohd, TL. 2012. Composition of Dust Fall around Semi-Urban Areas in Malaysia. Aerosol and Air Quality Research, 12:629-642. http://www.azojete.com.ng Arid Zone Journal of Engineering, Technology and Environment, September, 2019; Vol. 15(3):678-691. ISSN 1596-2490; e-ISSN 2545-5818; www.azojete.com.ng Corresponding author’s e-mail address: f.o.nwosu@gmail.com , fonwosu@unilorin.edu.ng 691 Al-Harbi, M. 2015. Characteristics and composition of the falling dust in urban environment. International Journal of Environmental Science and Technology. 12:641-652 Annegarn, HJ. and Scorgie, Y.2002. Air quality – chemistry and physics of the atmosphere. MSc Course Work Notes, University of the Witwatersrand. ASTM, 1996. Standard Guide for Choosing Locations and Sampling Methods to Monitor Atmospheric Deposition at Non – Urban Locations. ASTM International, West Conshohocken. Pp.48-64. ASTM, 2010. Standard Test Method for Collection and Measurement of Dust Fall (Settleable particulate matter). pp. 1739-98, ASTM International, West Conshohocken. Beg, MAA., Yousufzai, AHK. and Mehmood, SN. 1987. Air pollution in Karachi. Pakistan Journal of Science and Resources. 30: 60-66. Cattle, SR., McTainsh, GH. and Wagner, S. 2002. Aeolian dust contribution to soil of the Namoi Valley, Northern NSW, Australia. Catena, 47: 245-264. Chate, DM. and Pranesha, TS. 2004. Field studies of scavenging of aerosols by rain events. Journal of Aerosol Science, 35:695–706. Espinosa, AJF., Rodriguez, MT., DelaRoza, FJB. and Sanchez, JCJ. 2001. Size Distribution of Metals in Urban Aerosols in Seville (Spain). Atmospheric Environment 35:2595-2601. Garrison, VH., Shinn, EA., Foreman, WT., Griffin, DW., Holmes, CW., Kellogg, CA., Majewski, MS.,Richardson, LL., Ritchie, KB. and Smith, GW. 2003. African and Asian dust: from desert soils to coral reefs. BioScience, 53: 469-480. Glavas, SD., Nikolakis, P., Ambatzoglou, D. and Mihalopoulos, N. 2008. Factors Affecting the Seasonal Variation of Mass and Ionic Composition of PM2.5 at a Central Mediterranean Coastal Site. Atmospheric Environment, 42: 5365–5373. Ifeanyi, FO., Gilbert, UA. and Godson, RA. 2016. Review of Particulate Matter and Elemental Composition of Aerosols at Selected Locations in Nigeria from 1985-2015. Journal of Health and Pollution, 6(10):1-18. IS 5182. 2006. Indian Standard, Methods for Measurement of Air Pollution. Part 1Dust Fall (First Revision), ICS 13.040.30. Bureau of Indian Standards, Manak Bhavan, 9 Bahadur Shah Zafar Marg, New Delhi. Pp. 1-8. IUPAC, 1990. Glossary of atmospheric chemistry terms. International Union of Pure and Applied Chemistry, Applied Chemistry Division, Commission on Atmospheric Chemistry. Pure and Applied Chemistry 62(11):2167-2219. Jimoda, LA. 2012. Effects of Particulate Matter on Human Health, Ecosystem, Climate and Materials: A Review. Working and Living Environmental Protection, 9(1): 27–44. Kamble, RK. 2015. Dust Fall Rate and Its Composition in Chandrapur Industrial Cluster, Central India. International Journal of Environment, 4(3); 96-110 file:///C:/Users/user/Downloads/azojete143/www.azojete.com.ng