001.docx


 CHEMICAL ENGINEERING TRANSACTIONS  
 

VOL. 83, 2021 

A publication of 

 
The Italian Association 

of Chemical Engineering 
Online at www.cetjournal.it 

Guest Editors: Jeng Shiun Lim, Nor Alafiza Yunus, Jiří Jaromír Klemeš 
Copyright © 2021, AIDIC Servizi S.r.l. 
ISBN 978-88-95608-81-5; ISSN 2283-9216 

Integration of LiBr/H2O Absorption Heat Pump and Absorption 
Heat Transformer in Total Site Heat Integration 

Kai Jun Hoonga, Peng Yen Liewa,*, Timothy Gordon Walmsleyb, Nor Ruwaida 
Jamiana, Jeng Shiun Limc 
aDepartment of Chemical and Environmental Engineering, Malaysia – Japan International Institute of Technology (MJIIT),  
 Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, 54100 Kuala Lumpur, Malaysia.  
bSustainable Energy, Water and Resilient Systems Group, School of Engineering, The University of Waikato, Hamilton  
 3216, New Zealand 
cSchool of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 83100 UTM Johor  
 Bahru, Johor, Malaysia. 
 pyliew@utm.my 

Energy efficiency is one of the main solutions to reduce CO2 emissions in the energy sector and improve 
primary energy intensity. Energy savings are at the centre of the numerous advantages of energy efficiency 
and connect to many other economic, social and environmental advantages. Total Site Heat Integration 
(TSHI) was introduced to maximise the heat recovery from various processes through a centralized utility 
system. Heat pump using absorption cycle has been identified as one of the waste heat recovery techniques. 
The challenges of heat pumps applications include limited temperature applications and long payback periods. 
However, these problems can be tackled by proper design and suitable types of heat pumps considerations. 
This paper integrates two different kinds of absorption cycle heat pump which are absorption heat pump 
(AHP) and absorption heat transformer (AHT) into the context of TSHI. This integration is able to reduce the 
industrial waste heat and generate quality steam. The heat generation of AHP and AHT are estimated based 
on the enthalpy of working fluid pair of water-lithium bromide. A case study is done to compare and verify the 
proposed methodology. Economic analysis is performed to compare the different integration approaches of 
AHP and AHT. Results showed that the integration of hybrid AHP and AHT contribute to the highest annual 
saving (21,351 USD/y) of utility cost compared to 12,356 USD/y for AHP system and 9,119 USD/y for AHT 
system. 

1. Introduction 
The increasing world energy consumption and energy-related CO2 emissions have contributed to the serious 
global challenge of climate change. Energy efficiency is one of the main solutions for decreasing CO2 
emissions in the energy sector and decreasing primary energy intensity. Improving energy efficiency and 
increasing the use of renewable energy are two useful approaches to reduce greenhouse gas emissions in the 
perspective of the global energy transition. It is estimated that energy efficiency enhancements since 2000 
prohibited 12 % more energy use in 2017 globally (IEA, 2018). Energy savings connect to many other 
economic, social and environmental advantages. 
To conserve energy, one of the effective approaches is by maximising heat recovery via heat integration 
(Klemeš et al., 2018). By developing heat integration concept, Total Site Heat Integration (TSHI) has received 
increasing attention since its beginning in the 90s (Dhole and Linnhoff, 1993). TSHI integrates individual 
processes for inter-process heat recovery through a centralized utlitiy system (Liew et al., 2017). TSHI has 
been practised not only in various chemical industrial sites (Matsuda et al., 2009) but also in heterogeneous 
Total Sites, e.g., consisting of industrial, municipal and commercial energy consumers (Lee et al., 2020). 
Heat pumps have been identified as one of the energy recovery techniques. Xu and Wang (2017) reviewed 
different types of absorption heat pumps and absorption heat transformers available and its respective 
applications for waste heat recovery. Some of the application problems that heat pumps face include limited 

 
 
 
 
 
 
 
 
 
 
                                                                                                                                                                 DOI: 10.3303/CET2183024 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
Paper Received: 11/05/2020; Revised: 08/08/2020; Accepted: 08/08/2020 
Please cite this article as: Hoong K.J., Liew P.Y., Walmsley T.G., Jamian N.R., Lim J.S., 2021, Integration of LiBr/H2O Absorption Heat Pump 
and Absorption Heat Transformer in Total Site Heat Integration, Chemical Engineering Transactions, 83, 139-144  DOI:10.3303/CET2183024 
  

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temperature applications and long payback periods (IEA, 2014). However, these challenges can be solved by 
proper design and suitable types of heat pumps considerations. 
Horuz and Kurt (2010) presented an industrial application of absorption heat transformers to increase the 
temperature of waste heat. Liew and Walmsley (2016) proposed a novel methodology for integrating two 
forms of open cycle heat pumps to recover waste heat in Total Sites. A hybrid heat pump concept is 
introduced for energy recovery in a spray dryer system by Walmsley et al. (2017). Li et al. (2019) proposed the 
integration of an absorption heat pump in solar thermal power plants for cogeneration. Schlosser et al. (2019) 
reviewed and evaluated the concept of heat pump integration for industrial uses based on Pinch Analysis. Gai 
et al. (2020) explored the possibility for integrating conventional heat pump and Joule Cycle in Process 
Integration methodologies for waste heat utilisation in process plants. 
Latest study has developed methods for the applications of AHP-alone-system, AHT-alone-system and other 
various types of heat pumps. In this study, the use of two different kinds of absorption heat pump systems for 
direct incorporation with the utility system in TSHI is presented. This study explores the effective utilisation of 
Absorption Heat Pumps (AHP) and Absorption Heat Transformers (AHT) in TSHI methodology based on the 
enthalpy of working fluid pair of water-lithium bromide. The combined impact of both AHP and AHT systems 
are also studied in this work. The study compares the options based on the reduction of utility consumption 
and simple payback period based on the existing system without AHP and AHT. 

2. Heat recovery via absorption cycle 
The absorption heat pump has diverse configurations for different objectives. Commonly, the term Absorption 
Heat Pump (AHP) not only denotes to the common idea of absorption heat pump but also refers exactly to the 
absorption heat pump for heat amplification while the term Absorption Heat Transformer (AHT) refers to the 
absorption heat pump for temperature upgrading. AHP is also being labelled as type-I AHP while AHT is 
referred to as type-II AHP. AHP is used for heat amplification while AHT is used for temperature upgrading. 
The AHT operates in a reverse cycle to that of AHP. Four heat exchangers: an evaporator, condenser, 
generator, and absorber are found in both AHP and AHT systems as shown in Figure 1. The heat pump cycle 
consists of a refrigerant cycle and an absorbent cycle. Lithium bromide solution and water is the typical 
working medium pair being used. This study will focus on the application of water-LiBr solution in both AHP 
and AHT systems with water as the refrigerant. 
The flow ratio, 𝑅𝑅, is a vital design parameter in the absorption cycle. It is defined as the ratio of the mass flow 
rate of the strong solution, 𝑚𝑚𝑠𝑠̇ , to the mass flow rate of refrigerant, 𝑚𝑚𝑟𝑟̇  in Eq(1). 

𝑅𝑅 = �̇�𝑚𝑠𝑠 �̇�𝑚𝑟𝑟⁄   (1) 

The water vapour produced in the generator and evaporator of both AHP and AHT systems is in superheated 
conditions. The enthalpy of superheated water vapour, ℎ𝑤𝑤,𝑠𝑠𝑠𝑠𝑠𝑠 at different temperatures can be estimated by 
Eq(2), where the reference temperature is at 0 °C. 

ℎ𝑤𝑤,𝑠𝑠𝑠𝑠𝑠𝑠 = 2501 + 1.88(𝑇𝑇 − 𝑇𝑇𝑟𝑟𝑟𝑟𝑟𝑟)  (2) 

Stream 2 that leaves the condenser is in a liquid state. The enthalpy of pure liquid water, ℎ𝑤𝑤,𝑙𝑙𝑙𝑙𝑙𝑙𝑠𝑠𝑙𝑙𝑙𝑙, at any 
temperature, T, can be estimated from Eq(3), where the reference temperature, Tref, is at 0 °C. 
 

 

Figure 1: System configurations of a) absorption heat pump b) absorption heat transformer (Xu and Wang, 
2017) 

4

Throttling
 valve

Condenser Generator

Evaporator Absorber

Sol ution 
pump3

2

5

6

1

10

8

9

7

Sol ution heat 
exchanger

Flow:
Refrigerant flow

Weak solution flow

St rong sol ution flow

Qeva

Qgen

Qabs

Qcond

Throttling 
valve

4

Refrigerant
pump Throttling

valve

Evaporator Absorber

Condenser Generator

Sol ution 
pump

2

3

7

8

1

6

5

5'

8'

Sol ution heat 
exchanger

Qeva

Qgen

Qabs

Qcond

(a) (b) 

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ℎ𝑤𝑤,𝑙𝑙𝑙𝑙𝑙𝑙𝑠𝑠𝑙𝑙𝑙𝑙 = 4.19(𝑇𝑇 − 𝑇𝑇𝑟𝑟𝑟𝑟𝑟𝑟)  (3) 

The strong and weak water-lithium bromide solution deviates from ideal solution behaviour. The specific 
enthalpy of the solution can be obtained from the thermophysical properties table of water-lithium bromide 
solution pair by ASHRAE (2009). 

2.1 Absorption heat pump (Type-I AHP) 

The heat flows, Q, in the major components in the AHP can be calculated using Eq(4-7) below:  

𝑄𝑄𝑔𝑔𝑟𝑟𝑔𝑔 = �̇�𝑚𝑟𝑟(ℎ1 − ℎ7) + �̇�𝑚𝑟𝑟𝑅𝑅(ℎ8 − ℎ7)  (4) 

𝑄𝑄𝑎𝑎𝑎𝑎𝑠𝑠 = �̇�𝑚𝑟𝑟[(ℎ4 − ℎ5) + 𝑅𝑅(ℎ10 − ℎ5)]  (5) 

𝑄𝑄𝑟𝑟𝑒𝑒𝑎𝑎 = �̇�𝑚𝑟𝑟(ℎ4 − ℎ3)  (6) 

𝑄𝑄𝑐𝑐𝑐𝑐𝑔𝑔𝑙𝑙 = �̇�𝑚𝑟𝑟(ℎ1 − ℎ2)   (7) 

The first term in Eq(4) signifies the heat required to produce water vapour at state 1 (refer to Figure 2) from 
weak solution at state 7 and the second term in Eq(4) denotes the sensible heat required to increase the 
temperature of the solution from state 7 to state 8. The first term in Eq(5) signifies the enthalpy change of 
water as it condenses from vapour at state 4 to liquid at state 5. The second term in Eq(5) denotes the 
sensible heat transferred as the solution at state 10 is cooled to state 5. 

2.2 Absorption Heat Transformer (Type-II AHP) 

The heat of the input of evaporator and heat output of condenser can be calculated using Eq(6) and Eq(7). 
The heat flows in the other two major components in the AHT can be calculated via Eqs(8) to (9) as shown:  

𝑄𝑄𝑔𝑔𝑟𝑟𝑔𝑔 = �̇�𝑚𝑟𝑟[(ℎ1 − ℎ6) + 𝑅𝑅(ℎ7 − ℎ6)]   (8) 

𝑄𝑄𝑎𝑎𝑎𝑎𝑠𝑠 = �̇�𝑚𝑟𝑟[(ℎ4 − ℎ5) + 𝑅𝑅(ℎ8′ − ℎ5)]  (9) 

The first term in Eq(8) signifies energy required to produce water vapour from solution at state 6 to state 1 and 
the second term in Eq(8) denotes the sensible heat necessary to heat the solution from state 6 to state 7. The 
first term in Eq(9) signifies the enthalpy change of water changes from vapour at state 4 to liquid at state 5. 
The second term in Eq(9) denotes the sensible heat transferred as the solution at state 8’ is cooled to state 5. 

3. Methodology 
This study suggests a new TSHI targeting methodology integrating AHP and AHT, which is used to determine 
the feasibility of the absorption cycle techniques in TS. 

3.1 Data extraction 

Processes stream data has to be analysed to determine the heating and cooling requirements. The data 
extraction involves temperature, enthalpy and heat capacity of the stream flowing in each process. 

3.2 Individual process Pinch Analysis 

From the process stream data obtained previously, the minimum energy required for hot and cold utilities is 
targeted based on the process using Pinch Analysis. The numerical approach of the Problem Table Algorithm 
(PTA) will be used to identify the Pinch temperature in each process. The amount of heat source and heat sink 
will be identified. With the use of Multiple Utility Problem Table Algorithm (MU-PTA), the exact amount of 
utilities required within the given temperature ranges of utilities can be targeted (Liew et al., 2012).  

3.3 Total Site Heat Integration (TSHI) 

The utility production and consumption possibilities are determined via the Total Site Problem Table Algorithm 
(TS-PTA) (Liew et al., 2012). The quantity of heat targeted at above the TS Pinch denotes the heat demand 
while the quantity of heat available below TS Pinch denotes the waste heat obtainable in the TS level. 

3.4 Heat generation estimation 

By setting the temperatures of the major equipment in the absorption cycle, the enthalpies at all of the state 
points are obtained using Eq(2-3) and through ASHRAE (2009). The heat generation estimation can be 

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calculated using Eqs(1) to (9). The following assumptions have been made to estimate the heat generation in 
both AHP and AHT systems: 

a. The refrigerant, weak and strong solution are in steady-state and thermodynamic equilibrium conditions. 
b. The solution exiting the generator and absorber, the refrigerant exiting the condenser and the evaporator 

are all saturated. 
c. The mechanical work required by the pump is considered negligible, the temperature and enthalpy of the 

fluid entering and exiting the pump remained constant. 
d. Throttling valve does not change the enthalpy of the working fluid. 
e. The gross temperature lift of AHT is taken as 50 °C (Horuz and Kurt, 2009). 
f. The temperatures of evaporator and generator in AHT are the same, while the temperature of condenser 

and absorber in AHP are also the same. 
g. The flow ratio of the absorption cycle is 12.0 (Horuz and Kurt, 2009). 
h. The concentrations of strong and weak solutions are 0.65 and 0.60 (Horuz and Kurt, 2009). 

3.5 Economic analysis 

The economic analysis is done by comparing the total utility cost saving in the possible system configurations. 
The natural gas consumption of the boiler and heater as well as electricity consumption of the cooling tower 
are used to estimate the operating cost reduction (Liew and Walmsley, 2016). The reduction of utility loads is 
estimated to compare the effectiveness of each configuration. The equipment cost is estimated and the 
payback period is analysed. 

4. Case study 
A modified case study is shown to demonstrate the methodology suggested. The case study involves four 
different processes which consist of industrial plants, hotel and residential area (Liew et al., 2014). The 
minimum temperature difference between the process streams and the utility, ΔTmin,up, and the minimum 
temperature difference between the process streams, ΔTmin,pp, are both assumed to be 12 °C. The utilities 
obtainable in Total Site are Intermediate Pressure Steam (IPS) at 180 °C, Low Pressure Steam (LPS) at 130 
°C, a hot water system (HW) at 50 °C and the cooling utility of cooling water (CW) at 30 °C.  
After performing Total Site energy targeting, the TS Pinch is located between IPS and LPS. This means that 
the excess LPS below the Pinch can be used in AHP or AHT to fulfil the IPS demand above Pinch. From TS-
PTA, the HW is in deficit although it is located below the TS Pinch. This potential heat demand could be 
satisfied by the integration of AHP. In all the 3 cases, the net heat requirements before heat cascade will be 
used for the integration of AHP and AHT. The case study is done under 3 cases: Absorption heat transformer 
(AHT) (Case 1), Absorption heat pump (AHP) (Case 2), and Hybrid AHP and AHT (Case 3). 
In Case 1, all of the excess LPS is fed into the AHT system. By using Eq(6-9), the heat generated from the 
AHT system can be calculated. The integration of AHT has successfully achieved temperature upgrading from 
LPS to IPS. From Eq(6-9), the required refrigerant mass flow rate, �̇�𝑚𝑟𝑟, is obtained as 0.0248 kg/s. The net 
heat requirement after AHT integration is summarized in Table 1. The integration of AHT has successfully 
achieved the IPS heat demand, however, the HW demand is not satisfied. Unlike AHP, the function of AHT 
serves to provide heat demand above TS Pinch by increasing the temperature of the excess available heat.  
In Case 2, the HW output requirement is set and the heat input requirements to the AHP system are 
calculated using Eq(4) and Eq(6). The integration of AHP system has successfully achieved heat amplification 
from 24.80 kW of LPS to 44.48 kW of HW generation. From Eq(4-7), the required refrigerant mass flow rate, 
�̇�𝑚𝑟𝑟, is obtained as 0.0084 kg/s. The net heat requirement after AHP integration is summarized in Table 1. The 
integration of AHP has successfully achieved the HW demand, however, the IPS demand is not satisfied. 
Case 3 is the extension of Case 2 by considering both AHP and AHT system. Once the IPS heat output is set, 
the heat input requirements can be calculated  using Eq(6) and Eq(8). The CW generation is calculated using 
Eq(7). From Eq(4-9), the required refrigerant mass flow rate, �̇�𝑚𝑟𝑟, is obtained as 0.0084 kg/s in AHP system 
and 0.0117 kg/s in AHT system. The net heat requirement after hybrid AHP and AHT integration is 
summarized in Table 1. The integration of two absorption systems has successfully achieved both IPS and 
HW demand. The integration of AHT satisfied the heat demand of IPS above TS Pinch; integration of AHP 
satisfied the heat demand of HW below TS Pinch; whereas the integration of both systems satisfied both IPS 
and HW demands above and below TS Pinch. 
The utility cost consumption estimation is 302.21 USD/kW∙y for natural gas of steam boilers and 28.45 
USD/kW∙y for power of cooling towers (Liew and Walmsley, 2016). Assuming the gas fired heater has 
efficiency of 88.0 %, the assumed utility price is 249.32 USD/kW∙y for natural gas consumption of heaters 
(Raluy and Dias, 2020). The cost changes for boiler, heater and cooling tower, as well as total utility cost-
saving from different absorption systems, are analysed and summarised in Table 2. It can be said that the 

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integration of a hybrid AHP and AHT system provides the biggest saving of utility cost compared to AHP and 
AHT alone system. The heat amplification AHP system is not very effective because it does not upgrade the 
heat across the Pinch. The use of temperature upgrading AHT system is more effective due to the heat 
transfer across the Pinch. However, the integration of both AHP and AHT systems is found to be the most 
effective solution when there is both IPS and HW demand by using excess LPS in Total Site. The equipment 
cost of AHP and AHT is estimated as 275 USD/kW of heat output and 270 USD/kW of heat output (Zhang et 
al., 2016). Considering the equipment cost and total utility cost-savings, the payback periods for AHT is 3.6 y; 
1.0 y for AHP; and 1.3 y for hybrid AHP and AHT systems. Based on the overall results of economic analysis, 
a relatively short payback period (1.3 y) for hybrid AHP and AHT systems which offers the highest annual 
saving of utility cost signify that hybrid system is the best integration choice. 

Table 1: Summary of the net heat requirements after integration of AHP and AHT 

Utility Utility 
temperature (oC) 

Net heat requirement - 
before (kW) 

System utility 
input (kW) 

System utility 
generation (kW) 

Net heat requirement -
after (kW) 

Integration of AHT (Case 1) 
IPS 180 26.9 - 56.8 -29.9 
LPS 130 -130.0 130.0 - 0.0 
HW 50 44.5 - - 44.5 
CW 15 -76.4 - 65.0 -141.4 
Integration of AHP (Case 2) 
IPS 180 26.9 - - 26.9 
LPS 130 -130.0 24.8 - -105.2 
HW 50 44.5 - 44.5 0.0 
CW 15 -76.4 19.7 - -56.7 
Integration of hybrid AHP and AHT (Case 3) 
IPS 180 26.9 - 26.9 0.00 
LPS 130 -105.2 61.5 - -43.7 
HW 50 0.0 - - 0.0 
CW 15 -56.7 - 30.8 -87.5 

Table 2: Energy and cost saving from AHP and AHT integration 

Utility Unit Existing AHT (Case 1) AHP (Case 2) AHP+AHT (Case 3) 
IPS kW 26.9 -29.9 26.9 0.0 
LPS kW -130.0 0.0 -105.2 -43.7 
HW kW 44.5 44.5 0.0 0.0 
CW kW -76.4 -141.4 -56.7 -87.5 
Boiler Load kW 26.9 0.0 26.9 0.0 
Boiler Load Changes kW - -26.9 0.0 -26.9 
Boiler Cost Changes  USD/y - -8,121 0.0 -8,121 
Heater Load kW 44.5 44.5 0.0 0.0 
Heater Load Changes kW - 0.0 -44.5 -44.5 
Heater Cost Changes USD/y - 0.0 -11,090 -11,090 
Cooling Tower Load kW 206.4 171.3 161.9 131.2 
Cooling Tower Load Changes kW - -35.1 -44.5 -75.2 
Cooling Tower Cost Changes  USD/y - -998 -1,265 -2,140 
Total Utility Cost Saving USD/y - 9,119 12,356 21,351 
Capital Cost USD - 32,885 12,232 27,791 
Payback Period y - 3.6 1.0 1.3 

5. Conclusions 
A new methodology for integrating water-lithium bromide absorption heat pump and absorption heat 
transformer is presented in this work. The case study demonstrates that the use of absorption cycle can help 
reduce utility demand and achieve cost saving in Total Site. The integration of hybrid AHP and AHT  (Case 3) 
provides the highest annual saving of utility cost of USD 21,351 compared to USD 9,119 for AHT-alone-
system (Case 2) and USD 12,356 for AHP-alone-system (Case 1). The combination of both AHP and AHT 
systems has a relatively short payback period of only 1.3 y. This study provides a different approach by taking 

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two different absorption cycles into the consideration of increasing energy efficiency. A detailed capital cost 
and operating cost for the absorption cycles should be considered in future study. The consideration of 
different time slices in Total Site will be the opportunitiy for enhancing heat recovery in a Locally Integrated 
Energy System.  

Acknowledgements 

The authors would like to thank for the financial support from Universiti Teknologi Malaysia and Ministry of 
Higher Education Malaysia through Fundamental Research Grant Scheme (FRGS/1/2018/TK02/UTM/02/26; 
R.K130000.7843.5F075) and MRUN Translational Research Grant Scheme (R.K130000.7843. 4L883).  

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