001.docx CHEMICAL ENGINEERING TRANSACTIONS VOL. 83, 2021 A publication of The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Jeng Shiun Lim, Nor Alafiza Yunus, Jiří Jaromír Klemeš Copyright © 2021, AIDIC Servizi S.r.l. ISBN 978-88-95608-81-5; ISSN 2283-9216 Synthesis of a Sustainable Wastewater Treatment Plant for Sago Industry using Fuzzy Optimisation Jo Yee Hoa, Kelvin Teo Kai Wena, Yoke Kin Wana,*, Viknesh Andiappanb aSchool of Engineering, Faculty of Innovation and Technology, Taylor’s University, Lakeside Campus, No. 1 Jalan Taylor’s, 47500 Subang Jaya, Selangor, Malaysia. bSchool of Engineering and Physical Sciences, Heriot-Watt University Malaysia, 62200, Putrajaya, Wilayah Persekutuan Putrajaya, Malaysia yokekin.wan@taylors.edu.my Wastewater treatment plant (WWTP) is an essential process in the manufacturing industry. However, wastewater treatment process is not a profitable process as it requires a significant amount of investment. It is important to design a WWTP that meets wastewater discharge legalisation with low investment costs. To do this, area footprint (land area) occupied by technologies in a WWTP must be factored into the design decision. Unfortunately, the area footprint is yet to be studied. As wastewater treatment processes involve multiple treatment units, the different combinations of these treatment units will give a range of capital costs and costs associated with the area occupied. In addition, the carbon footprint of technology resulting from power consumption must be considered. Each technology possesses unique power consumption requirements and these requirements may influence the total carbon footprint for a given WWTP design. Investment costs, area footprint and carbon footprint must be considered simultaneously but are conflicting in nature. This work aims to present a multi-objective decision-making tool to screen wastewater treatment technologies and to synthesise a WWTP design with low investment cost, low area footprint, and low carbon footprint. Specifically, fuzzy multi- objective optimisation (FMOO) is used to determine a desirable trade-off between investment costs, area footprint, and carbon footprint. To demonstrate the developed approach, a sago-based WWTP case study is solved. Based on the results, a trade-off between these optimisation objectives had reduced 5.35 m2 of area footprint, 986 USD/d of total investment cost, and 108 kg CO2/d of carbon footprint of the synthesised WWTP. 1. Introduction Sago industry is one of the major industries in Sarawak, Malaysia that generates a significant amount of organic wastewater (Yunus et al., 2014). According to Adeni et al. (2010), every 1 t of sago starch produced, approximately 10 t to 22 t of organic wastewater will be generated. This significant amount of wastewater produced requires proper wastewater treatment. A proper wastewater treatment process can be synthesised before actual installation and operation to avoid extra investment costs needed to rectify the process in the future. In this respect, there are several published research works had incorporated cost optimisation (Ho et al., 2019) and carbon footprint optimisation (Padrón-páez et al., 2020) of a WWTP. However, limited research works had considered area footprint (land area) as an important design criterion in synthesising a WWTP. Shortage of land area is an issue in some countries as the rapid development of cities and heavy industries had led to global deforestation issues. Malaysia for instance, had the world’s highest rate of deforestation between year 2000 and 2012 (Butler, 2013). Consequently, authorised organisations and departments had implemented more stringent regulations to control the rate of deforestation, resulting in land prices in Malaysia to rise significantly for the past 10 y (WWF, 2020). The area footprint required to synthesise a WWTP is essential to be optimised as the land area cost of a WWTP contributes to a high capital cost. To optimise the area footprint of a WWTP, the size of equipment must be minimised. Nevertheless, smaller wastewater treatment technologies are usually more advanced technologies and require higher cost compared to conventional wastewater treatment technologies (Ang et al., 2019). In addition, smaller advanced technologies may consume higher power consumption, resulting in a higher carbon footprint (Fernandez-Dacosta et al., 2016). Due to the extensive DOI: 10.3303/CET2183063 Paper Received: 21/06/2020; Revised: 04/08/2020; Accepted: 10/08/2020 Please cite this article as: Ho J.Y., Wen K.T.K., Wan Y.K., Andiappan V., 2021, Synthesis of a Sustainable Wastewater Treatment Plant for Sago Industry using Fuzzy Optimisation, Chemical Engineering Transactions, 83, 373-378 DOI:10.3303/CET2183063 373 selection of technologies, this becomes a challenge for industrial decision-makers to select the optimum wastewater treatment pathway which fits all the desired objectives while ensuring the discharge effluent complies with local discharge legislation. The combination of different technologies with various specifications will affect the performance, investment cost, and area footprint (land area) of the entire WWTP. In this respect, this work had employed fuzzy multi-objective optimisation (FMOO) in the developed mathematical model from this study. FMOO provides a trade-off between multiple optimisation objectives by integrating these objectives into a single parameter or degree of satisfaction, λ (Zimmermann, 1978). This method is useful to address the vagueness and ambiguity present in quantifying the target range of each optimisation objective while having more than one selection between the WWTP pathway alternatives. In this situation, FMOO is a better tool to solve multi-objective optimisation problems with uncertainty in identifying the importance or contribution of each optimisation objective (Pan et al., 2014). To illustrate the developed approach, this work aims to present a FMOO tool to synthesise an optimum sago biorefinery WWTP with minimum cost, minimum area footprint and minimum carbon footprint which meets the effluent quality discharge regulation (COD, BOD and TSS). 2. Problem statement The problem definition in this work is as follows: Wastewater feed f 𝜖𝜖 F is treated by a series of treatment stages beginning from preliminary treatment p 𝜖𝜖 P, chemical treatment r 𝜖𝜖 R, biological treatment s 𝜖𝜖 S, and tertiary treatment t 𝜖𝜖 T to produce treated wastewater as shown in Figure 1. In chemical treatment and biological treatment, a certain amount of sludge will be generated. These generated sludges will flow into the sludge treatment process u 𝜖𝜖 U. Based on the problem shown in Figure 1, a mathematical model is formulated. Figure 1: Generic superstructure of WWTP 3. Fuzzy multi-objective optimisation (FMOO) model The mathematical model developed in this work consists of flowrate balance, component balance, area footprint, cost computation, carbon footprint, and fuzzy equations as shown in each subsection. Based on Figure 1, these equations will be repetitive at each treatment stage. A more generic formulation is presented in this paper where index a represents the previous treatment stage, index b represents the present treatment stage and index c would represent the subsequent treatment stage. For instance, to formulate equations for biological treatment s, the present index b represents chemical treatment s (b = s). Index a will represent the preceding chemical treatment r (a = r) and index c will represent the succeeding tertiary treatment t or sludge treatment u (c = t,u). 3.1 Flowrate and component balance This work aims to synthesise an organic WWTP considering COD balance, BOD balance, and TSS balance. In this respect, the formulation for volumetric flowrate balance and component balance for an organic WWTP can be found in Ho et al. (2019). The concentration of components (COD, BOD and TSS) present in the treated wastewater from the synthesised WWTP will always comply with the local discharge regulation as shown in the constraint in Eq(1). 𝐶𝐶𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐,𝑐𝑐𝑡𝑡𝑐𝑐𝑡𝑡𝑐𝑐𝑐𝑐𝑡𝑡 𝑊𝑊𝑊𝑊𝑊𝑊 ≤ Ccomponent,std (1) 374 3.2 Area footprint The formulation of area footprint is based on the area factor, P (m2) obtained from literature review or industrial vendors as shown in Eq(2). 𝐴𝐴𝐴𝐴𝐴𝐴𝑎𝑎𝑏𝑏 represents the area footprint for present treatment stage b while 𝑃𝑃𝑏𝑏 Area represents the area factor for each technology in the present treatment stage b. 𝐴𝐴𝐴𝐴𝐴𝐴𝑎𝑎𝑏𝑏 = 𝑃𝑃𝑏𝑏 Area ∀𝑏𝑏 (2) 3.3 Cost computation The total investment cost for technology b, 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Total (USD/m3) includes the capital expenditure (CAPEX), operating cost, and the land area cost formulated as shown in Eq(3) to Eq(6). The CAPEX for present technology b, 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 CAPEX (USD) is formulated based on the CAPEX factor, 𝑃𝑃𝑏𝑏 CAPEX (USD) retrieved from literature reviews or industrial vendors. The operating cost for present technology b, 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Opt (USD/m3) is contributed from the material cost for technology b, 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Mat (USD/m3) and power cost for technology b, 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Power (USD/m3). In addition, 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Area (USD) represents the total land area cost for present technology b and 𝑃𝑃𝑏𝑏 LandCost (USD/m2) represents the area cost factor for technology b. To annualised the CAPEX and land area cost, an annualised factor, 𝑃𝑃Annual is obtained based on the expected operating years and inflation rate. 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 CAPEX = 𝑃𝑃𝑏𝑏 CAPEX ∀𝑏𝑏 (3) 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Opt = Cost𝑏𝑏 Mat + Cost𝑏𝑏 Power ∀𝑏𝑏 (4) 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Area = 𝐴𝐴𝐴𝐴𝐴𝐴𝑎𝑎𝑏𝑏𝑃𝑃𝑏𝑏 LandCost ∀𝑏𝑏 (5) 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Total = (𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 CAPEX + 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Area)𝑃𝑃Annual + 𝐶𝐶𝐶𝐶𝐶𝐶𝑡𝑡𝑏𝑏 Opt ∀𝑏𝑏 (6) 3.4 Carbon footprint Carbon footprint formulation is presented in Eq(7) where, 𝐶𝐶𝑎𝑎𝐴𝐴𝑏𝑏𝐶𝐶𝑛𝑛𝑏𝑏 (kg CO2/d) is the carbon footprint for present technology b, 𝐸𝐸𝑏𝑏 power (kWh/m3) is the power consumption for technology b and 𝑃𝑃𝑏𝑏 carbon (kg CO2/kWh) is the carbon footprint factor representing how much carbon dioxide will be released for every power consumption. 𝐶𝐶𝑎𝑎𝐴𝐴𝑏𝑏𝐶𝐶𝑛𝑛𝑏𝑏 = 𝐹𝐹𝑏𝑏 in𝐸𝐸𝑏𝑏 power𝑃𝑃𝑏𝑏 carbon ∀𝑏𝑏 (7) 3.5 Fuzzy optimisation To incorporate multiple objectives that are contradictory in nature, fuzzy optimisation is used as shown in Eq(8) to Eq(10). Fuzzy optimisation integrates multiple objectives into a single parameter called the degree of satisfaction, λ. λ ranges from 0 to 1, whereby 0 indicates the total area footprint, cost, and carbon footprint are approaching their upper limits (undesirable) while 1 indicates these optimisation objectives are approaching their lower limits (desirable). Higher λ represents higher satisfaction for each objective. The total area footprint, cost, and carbon footprint are represented by TotArea (m2), TotCost (USD/m3) and TotCarbon (kg CO2). Superscript UL represents the predetermined upper limit each objective while superscript LL represents the predetermined lower limit for each objective. These predetermined limits can be obtained based on decision- makers’ interests or determined by optimising the model one objective at a time (Zadeh, 1965). TotAreaUL−𝑊𝑊𝑐𝑐𝑐𝑐𝑇𝑇𝑡𝑡𝑐𝑐𝑡𝑡 TotAreaUL−TotAreaLL ≥ 𝜆𝜆 (8) TotCostUL−𝑊𝑊𝑐𝑐𝑐𝑐𝑇𝑇𝑐𝑐𝑇𝑇𝑐𝑐 TotCostUL−TotCostLL ≥ 𝜆𝜆 (9) TotCarbonUL−𝑊𝑊𝑐𝑐𝑐𝑐𝑇𝑇𝑡𝑡𝑡𝑡𝑏𝑏𝑐𝑐𝑐𝑐 TotCarbonUL−TotCarbonLL ≥ 𝜆𝜆 (10) To solve the fuzzy model, the fuzzy degree of satisfaction, λ will be maximised as shown in Eq(11). Maximise 𝜆𝜆 (11) 375 4. Case study In this case study, a WWTP is synthesised to treat sago wastewater obtained from a sago-based biorefinery in Sarawak, Malaysia (Wan and Ng, 2015). Sago wastewater enters at a flowrate of 276 m3/d with a COD level of 7,763 ppm, BOD level of 3,362 ppm, and TSS level of 4,942 ppm. Based on the local discharge legalisation (Standard B), the synthesised WWTP in this work will reduce the level of COD, BOD and TSS present in the sago wastewater to 200 ppm, 50 ppm, and 100 ppm (Department of Environment Malaysia, 2010). A series of wastewater treatment technologies suitable for this case study were included as shown in Figure 2. Figure 2: Case study superstructure of sago biorefinery WWTP in Sarawak, Malaysia. Table 1 and Table 2 summarised the wastewater treatment technologies specifications such as removal efficiency, dryness, CAPEX, material cost (MAT), power cost (POW), area footprint (AF), and power consumption (E) obtained from industrial partners. To calculate the power cost, local electricity rates were obtained. According to Sarawak Energy Berhad (2020), the electrical rate is USD 4.58/kWh for heavy industry class I1. In addition, the carbon emission factor for Malaysia is 0.693 kg CO2/kWh (International Energy Agency (IEA), 2016). The land area cost of the WWTP is calculated based on local industrial land rates in Sarawak which is USD 212.25/m2 (Malaysian Investment Development Authority (MIDA), 2020). Table 1: Specifications of case study wastewater treatment technologies (Lakghomi et al., 2015) Table 2: Specifications of case study sludge treatment technologies (Wang et al., 2019) Technologies Removal efficiency (%) CAPEX (USD) MAT (USD/m3) POW (USD/m3) AF (m2) E (kWh/m3) TSS COD BOD Bar Screen 65 0 0 4,128 0 0 15.00 0 Grit Removal 40 0 0 7,523 0 0 20.00 0 DAF 91 70 65 3,440 0.34 1.02 15.95 0.222 CAAS 85 85 88 22,936 0.60 12.17 - 2.652 MBR 99 90 90 68,807 0.46 16.35 - 3.565 MBBR 85 90 92 57,339 0.37 9.27 - 2.022 Chlorination 16 56 55 18,349 0.73 0.12 7.84 0.026 Ozone disinfection 60 83 70 22,936 0.46 4.82 3.92 1.051 Activated carbon system 58 65 60 11,009 1.15 0.50 6.09 1.110 Technologies Dryness (kg SS/m3) CAPEX (USD) Operating cost (USD/m3) Area (m2) E (kWh/m3) MAT POW Filter press 25.0 18,349 0.11 8.26 2.80 1.800 Grit Removal 29.9 22,936 0.11 6.78 4.30 1.478 Activated carbon system 28.5 27,523 0.13 11.47 3.00 2.500 376 The FMOO model developed for this case study is a mixed integer non-linear programming (MINLP) model. Using a commercial optimisation software, LINGO (version 18.0) the case study is solved with computer specification of Intel ® Core ™ i7-6500U @ 8 GB RAM, x64-based processor. An optimum wastewater treatment pathway with minimal area footprint, total investment cost, and carbon footprint will be synthesised. This will be done by optimising each objective individually to determine the upper and lower limits for each optimisation objective as summarised in Table 3. Table 3: Summarised results for each optimised objective WWTP pathways. The area footprint, total investment cost, and carbon footprint for each optimised pathway were tabulated in Table 4. By optimising each objective individually, the best (lower limit) values and worst (upper limit) values can be identified to set a range for trade-offs. A global optimised wastewater treatment pathway at a degree of satisfaction, λ of 0.5813 is synthesised as shown in Figure 3. The optimum wastewater treatment process consists of bar screen, dissolved air flotation (DAF) tank, moving bed biofilm reactor (MBBR), activated carbon system, and filter press. Comparing to the worst scenarios, by applying a maximum trade-off percentage of 58.13 %, the area footprint is decreased from 60.10 m2 (Pathway C) to 54.75 m2. At the same time, the cost needed for the WWTP is decreased from 20,273.43 USD/d (Pathway B) to 19,286.77 USD/d where lesser advanced technology in preliminary treatment and sludge treatment is chosen. In addition, a significant amount of carbon footprint is reduced from 657 kg CO2/d (Pathway A) to 549 kg CO2/d. Table 4: Comparison of wastewater treatment pathways at different optimisation objectives. *UL – Upper limit LL – Lower limit Figure 3: Optimal configuration of case study WWTP with traded off cost, area footprint, and carbon footprint. 5. Conclusion In conclusion, this work had developed a decision-making tool to synthesise WWTP based on different optimisation objectives such as minimum cost, minimum area footprint, and minimum carbon footprint. The contradicting problem between these optimisation objectives is solved via FMOO. The case study in this work Pathways Preliminary treatment Chemical treatment Biological treatment Tertiary treatment Sludge treatment Min. area footprint (Pathway A) Bar screen DAF MBBR Ozone disinfection Centrifugal Min. total investment cost (Pathway B) Bar screen DAF MBBR Ozone disinfection Filter press Min. carbon footprint (Pathway C) Grit removal DAF MBBR Activated carbon system Belt filter press Objective function Area footprint (m2) Total investment cost (USD/d) Carbon footprint (kg/d) Min. area footprint (Pathway A) 52.33LL 19,915.93 657.38UL Min. total investment cost (Pathway B) 53.13 18,576.11LL 631.75 Min. carbon footprint (Pathway C) 60.10UL 20,273.43UL 472.04LL Final optimised results (λ=0.5813) 54.75 19,286.77 549.64 377 had demonstrated that area footprint is an important criterion to be considered during the synthesis of WWTP as the cost associated with the land area is significant. Results from the case study indicate that a maximum trade-off at approximately 58 % would reduce 5.35 m2 of area footprint, 986 USD/d of total investment cost, and 108 kg CO2/d of carbon footprint. For future work, the weightage of each optimisation objective can be included in the model to allow a more extensive decision making during a WWTP synthesis. Acknowledgement The authors would like to gratefully acknowledge the financial support provided by the Taylor's Internal Research Grant Scheme - Emerging Research Funding Scheme (TIRGS-ERFS) (TIRGS-ERFS/1/2019/SOE/002) and LINDO Systems for providing academic licenses to complete this research work. References Ang M.S., Duyag J., Tee K.C., Sy C.L., 2019, A multi-period and multi-criterion optimization model integrating multiple input configurations, reuse, and disposal options for a wastewater treatment facility, Journal of Cleaner Production, 231, 1437–1449. 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