Microsoft Word - 1murphy.docx CHEMICAL ENGINEERING TRANSACTIONS VOL. 58, 2017 A publication of The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Remigio Berruto, Pietro Catania, Mariangela Vallone Copyright © 2017, AIDIC Servizi S.r.l. ISBN 978-88-95608-52-5; ISSN 2283-9216 Energy Demand and Greenhouse Gases Emissions in the Life Cycle of Coffee Harvesters Edemilson J. Mantoama, Thiago L. Romanelli*b, Leandro M. Gimenezc, Marcos Milanc a CNH Latin America, Brazil b Laboratory of Systemic Management and Sustainability, Department of Biosystems Engineering, “Luiz de Queiroz” College of Agriculture, University of Sao Paulo, Brazil c Department of Biosystems Engineering, “Luiz de Queiroz” College of Agriculture, University of Sao Paulo, Brazil romanelli@usp.br Besides global climate changes and the exhaustion of natural resources, the concern about energy resources is one of the main challenges of 21st century. The growing population and, consequently, the increasing demand for food, fibre and bioenergy leads to an intensive use of machinery and equipment, resulting in more energy required and more greenhouse gases emitted. Materials and energy sources are consumed during a product’s life cycle, so it is important to optimize them through reuse, recycling, reducing their demand and replacing them for more environmentally-friendly materials. In current agricultural production system, machinery is considered fundamental for biomass production. Energy analysis in agricultural machinery has been evaluated, but the indicators are mostly from the late 1960s and mostly were based on car industry. Studies on the embodied energy and emissions in agricultural mechanization should be carried out, due to the importance of food and bioenergy production systems in world economy. This study aimed to determine the inventory for materials, embodied energy and greenhouse gases emissions during the life cycle of a coffee harvester. Data were collected in a multinational manufacturer, in its unit located at Piracicaba municipality, State of São Paulo. For the coffee harvester, the consumption of the direct input used in the assembly phase and the input used in the maintenance phase were accounted. Input data were presented as materials flows, which were translated by their embodied energy indices and emissions factor, resulting in the embodied energy and greenhouse gases emissions required by the production system. Results presented the following embodied energy (67.05 MJ kg-1) and greenhouse gases emissions (4.75 kg CO2e kg-1). Keywords: Life cycle assessment; sustainability; machinery. 1. Introduction Energy is vital for the development of economies and societies and its demand is increasing globally (Abubakar and Umar, 2006), being mandatory to produce goods from natural resources and to provide services (Hinrichs and Kleinbach, 2009). Energy analysis regards the physical amounts involved in a process, measuring its energy content (Fluck and Baird, 1980). To evaluate a production process, the material flows converging into a product and wastes need to be determined (Dyer and Desjardins, 2006). Differently from some industrial sectors (Nassim and Hassan, 2017; Wang and Ho, 2017), for agricultural machinery assembling, life cycle assessments determining embodied energy and greenhouse gas emissions are rare (Mantoam et al., 2014; Mantoam et al., 2016). Berry and Fels (1972) determined the embodied energy index (81.2 MJ kg-1), based on the car industry from the late 1960s. Deleage et al. (1979) determined the index (75.0 MJ kg-1) for tractors, due to different material quantities and proportions from car industry. Although recently, Mantoam et al. (2014) determined indices for sugarcane harvesters, finding values around 2.6 times greater than those determined by Berry and Fels (1972). But, sugarcane harvesters are machines with specific applications, being used around 3100 hours per year. The rate of use and the field conditions in which they operate result in a high requirement of maintenance and repair that their data on energy demand should not be applied to other kinds of machines. This study aimed at determining the energy demanded and DOI: 10.3303/CET1758030 Please cite this article as: Mantoam E., Romanelli T., Gimenez L., Milan M., 2017, Energy demand and greenhouse gases emissions in the life cycle of coffee harvesters, Chemical Engineering Transactions, 58, 175-180 DOI: 10.3303/CET1758030 175 GHG emissions in the life cycle of coffee harvesters, due their importance on this crop in some tropical countries. 2. Material and methods The coffee harvester evaluated presented a 3-cylinder Diesel engine (40 kW) and weighted 5600 kg. Its life cycle considered was 6000 h according to the manufacturer (Figure 1). To evaluate the coffee harvester, this study applied a methodology to determine energy and emissions flows based on material demand of the assembly and maintenance phases of the machine life cycle (Mantoam et. al., 2014). Figure 1: Coffee harvesting performed by the evaluated machine (CASE, 2014). Fuel consumption on machinery operation was not considered, because it varies due to management decisions, field conditions and operator skills. The indices of embodied energy and GHG emission factors consider fossil energy and electricity required to obtain the materials that constitute the coffee harvester´s parts. For assembly phase, the directly used inputs refer to the parts supplied. These parts were grouped into material groups, for the importance of these materials in the machinery composition to be verified. Indirectly used inputs in assembly phase, such as electricity, liquefied petroleum gas, labor and water, were not assessed in this study due to lower embodied energy (Mantoam et. al., 2014). The maintenance phase considered the inputs directly and indirectly used, which are necessary according to the recommendations of the manufacturer. This assumption was done to avoid discrepancies among farmers and other users, because they may adopt distinct maintenance strategies to their equipment. Material flows were calculated and indices of energy embodiment for each input that were obtained in references (Table 1). So, they were used for the input energy flows to be determined. After the determination of the embodied energy in direct inputs and embodied energy in maintenance, their sum provides the embodied energy of the life cycle of a coffee harvester (Eq. (1)). EE = ∑ ∑ ( ∗ ) (1) where: EE is total embodied energy in the inputs on tractor life cycle (MJ); MF is the material flow directly used in the parts assembled and maintenance into a tractor (kg, L, h); EI is the energy index of the material used (MJ kg-1; MJ L-1; MJ h-1, Table 1); i = i-th material; j = j-th phases (maintenance, parts). GHG emissions were determined also based on material flows and multiplyed them by the respective emissions factor (Table 1). After the determination of the emissions in direct inputs and emissions in maintenance, their sum provides the emissions of the life cycle of a tractor (Eq. (2)). 176 EM = ∑ ∑ ( ∗ ) (2) where: EM is total emissions in the inputs on tractor life cycle (kg CO2eq.); MF is the material flow directly used in the parts assembled and maintenance into a tractor (kg, L); EF is the emissions factor of the material used (kg CO2eq. kg -1; kg CO2eq. L -1, Table 1); i = i-th material; j = j-th phases (maintenance, parts). After determination of the embodied energy and emissions, provides the embodied energy and emissions indicators, per life time, mass and engine power. Table 1: Energy embodiment and emissions factor indices for inputs Input Embodied energy GHG emission factor Value Unit Value Unit Aluminum 231.00 MJ kg-1 15.00 kg CO2e kg-1 Anticorrosive fluid 2.29 MJ kg-1 2.26 kg CO2e kg-1 Brass 140.00 MJ kg-1 2.82 kg CO2e kg-1 Carbon steel 51.52 MJ kg-1 3.19 kg CO2e kg-1 Cellulose film 192.53 MJ kg-1 1.60 kg CO2e kg-1 Chemical powder ABC 2.48 MJ kg-1 0.12 kg CO2e kg-1 Copper 140.00 MJ kg-1 6.00 kg CO2e kg-1 Cotton synthetic fiber 45.29 MJ kg-1 1.28 kg CO2e kg-1 Diesel oil 47.78 MJ L-1 2.60 kg CO2e L-1 Ductile iron 32.66 MJ kg-1 0.75 kg CO2e kg-1 Engine oil 37.28 MJ L-1 2.54 kg CO2e L-1 Fiberglass & aluminum 0.79 MJ kg-1 1.53 kg CO2e kg-1 Fiberglass & polyester 0.79 MJ kg-1 8.10 kg CO2e kg-1 Grease 43.38 MJ kg-1 5.30 kg CO2e kg-1 Hydraulic oil 37.28 MJ L-1 2.54 kg CO2e L-1 Inorganic fiberglass 0.79 MJ kg-1 1.53 kg CO2e kg-1 Labour 2.20 MJ h-1 - - Lead 17.31 MJ kg-1 1.13 kg CO2e kg-1 Lubricating oil 37.28 MJ L-1 2.54 kg CO2e L-1 Nylon 6.6 31.80 MJ kg-1 6.50 kg CO2e kg-1 Paint 2.48 MJ kg-1 3.56 kg CO2e kg-1 Paper 34.38 MJ kg-1 1.50 kg CO2e kg-1 Plate glass 30.22 MJ kg-1 0.85 kg CO2e kg-1 Polyethylene high density 52.45 MJ kg-1 1.60 kg CO2e kg-1 Polypropylene 110.16 MJ kg-1 1.65 kg CO2e kg-1 Polyurethane 110.16 MJ kg-1 3.00 kg CO2e kg-1 Polyurethane foam 110.16 MJ kg-1 14.50 kg CO2e kg-1 PVC 10.64 MJ kg-1 3.00 kg CO2e kg-1 ABS 1.24 MJ kg-1 3.10 kg CO2e kg-1 Rubber 88.00 MJ kg-1 3.18 kg CO2e kg-1 Solvent 2.48 MJ kg-1 3.56 kg CO2e kg-1 Stainless steel 81.77 MJ kg-1 2.20 kg CO2e kg-1 Steel wire 19.10 MJ kg-1 2.83 kg CO2e kg-1 Sulphuric acid 2.48 MJ kg-1 2.26 kg CO2e kg-1 Data collected by Mantoam et al. (2016). 3. Results and Discussion Evaluations of material flows and GHG emissions were carried out for the assembling (Table 2) and maintenance (Table 3) phases. 3.1 Energy demand Out of the total energy required by the coffee harvester to exist in its life cycle, 70.2 % is due to its assembling and constitution. The remaining 29.8 % is due to repair and maintenance. This is completely different for the situation described for sugarcane harvester by Mantoam et al. (2014), when 72.8 % of energy was required in by repair and maintenance. For the total life cycle of a coffee harvester 402.3 GJ were required. 177 For the assembling phase carbon steel represents 67.4 % of total energy and nylon 10.8 %, together both are responsible for 55 % of total energy demand in its life cycle. Table 2: Material and energy demand and GHG emissions in the assembling phase of a coffee harvester Components Material flow Energy demand GHG emission Qty Unity MJ % kg CO2e % 1.1 Metallic Ferrous Metals Carbon steel 3582.7 kg 184580.7 67.4 11428.8 57.1 Ductile iron 511.4 kg 16703.3 6.1 383.6 1.9 Steel wire 12.5 kg 237.9 0.1 35.2 0.2 1.2 Metallic Non-Ferrous Metals Aluminum 35.0 kg 8080.4 2.9 524.7 2.6 Lead 10.1 kg 2461.9 0.9 105.5 0.5 Copper 17.6 kg 175.2 0.1 11.4 0.1 Brass 0.2 kg 31.9 0.0 0.6 0.0 2 Non-Metallic Materials Nylon 6.6 932.2 kg 29642.9 10.8 6059.1 30.3 Rubber 226.3 kg 19914.4 7.3 719.6 3.6 Polyethylene high density 42.5 kg 2231.4 0.8 68.1 0.3 Polypropylene 9.1 kg 1002.5 0.4 15.0 0.1 Polyurethane foam 4.5 kg 495.7 0.2 65.3 0.3 Cellulose film 1.6 kg 300.3 0.1 2.5 0.0 Plate glass 6.8 kg 205.5 0.1 5.8 0.0 Polyurethane 1.0 kg 110.2 0.0 3.0 0.0 PVC (Poly Vinyl Chloride) 11.9 kg 126.4 0.0 35.6 0.2 Paper (printed news) 1.3 kg 43.0 0.0 1.9 0.0 Recycled ABS 1.0 kg 1.2 0.0 3.1 0.0 Sulphuric acid (H2SO4) 1.7 kg 4.2 0.0 3.8 0.0 Chemical powder ABC 3.2 kg 7.9 0.0 0.4 0.0 3 Lubricants and Fluids Hydraulic oil 158.0 L 5890.2 2.2 401.3 2.0 Diesel oil 14.0 L 668.9 0.2 36.4 0.2 Engine oil 15.3 L 568.5 0.2 38.7 0.2 Lubricating oil 7.5 L 279.6 0.1 19.1 0.1 Grease 3.7 kg 160.5 0.1 19.6 0.1 Anticorrosive fluid 1.0 kg 2.3 0.0 2.3 0.0 4 Paint and Solvent Paint 8.0 kg 19.8 0.0 28.5 0.1 Solvent 2.0 kg 5.0 0.0 7.1 0.0 Total 273951.8 100.0 20026.0 100.0 For maintenance, rubber is the most demanding material for 28 % of energy demand, followed by hydraulic oil (15 %), carbon steel (12 %), lubricant oil (11 %) and nylon (9 %). Five components respond to 75% of emissions in maintenance (~22 % of total). 3.2 GHG emissions Unfortunately, for GHG emissions, there are not data from references for comparisons to be made, such as performed for energy demand. Assembling phase was responsible for 70.3 % of GHG emissions and maintenance for 29.7 %. The total emissions were 28500 kg CO2e in its life cycle. For the assembling phase carbon steel represents 57.1 % of total energy and nylon 30.3 %, together both are responsible for 62 % of total GHG emitted in its life cycle. In maintenance, nylon is the most demanding material for 29 % of GHG emissions, followed by hydraulic oil (16 %), rubber (15 %), carbon steel (12 %) and lubricant oil (11 %). Five components respond to 83 % of emissions in maintenance (~24 % of total). 178 Table 3: Material and energy demand and GHG emissions in the maintenance phase of a coffee harvester Component Material flow Energy demand GHG emission Qty. Unity % % 1 Labor Labor 1393.8 h 2.4 - 2.1 Metallic Ferrous Metals Carbon steel 307.3 kg 12.3 11.6 Ductile iron 102.0 kg 2.6 0.9 2.2 Metallic Non-Ferrous Metals Aluminum 41.4 kg 7.4 7.3 3 Non-Metallic Materials Rubber 405.4 kg 27.8 15.2 Nylon 6.6 375.0 kg 9.3 28.8 Cellulose film 30.2 kg 4.5 0.6 Inorganic fiberglass 3.6 kg 0.0 0.1 Polypropylene 0.6 kg 0.1 0.0 4 Lubricants and Fluids Hydraulic oil 526.7 L 15.3 15.8 Lubricating oil 367.5 L 10.7 11.0 Engine oil 225.0 L 6.5 6.7 Grease 32.5 kg 1.1 2.0 Total (%) 100.0 100.0 Total (unit) 128.4 GJ 8474.1 kg CO2e For energy, the indices found were 67.05 MJ h-1; 71.84 MJ kg-1 and 10.06 GJ kW-1 (Table 4), respectively relating energy by life cycle, mass and gross power. Its index by mass can be compared with those presented by Berry and Fels (1972) - 81.2 MJ kg-1, and Deleage et al. (1979) - 75.0 MJ kg-1, showing that the coffee harvester is energetically less intense per mass than tractors. Besides also being a harvester, its index is even further from the sugarcane one 202.6 – 204.3 MJ kg-1, (Mantoam et al., 2014). Its level is comparable with a 246-kW tractor that presented 62.7 MJ kg-1 (Mantoam et al., 2016). More powerful tractors were more efficient than less power ones 98.7 MJ kg-1 (55 kW) to 72.1 MJ kg-1 (172 kW). Table 4: Energy indicators for coffee harvester Phase Total value Energy indices GJ MJ h-1 GJ kW-1 MJ kg-1 Assembly 273.9 45.65 6.85 48.91 Maintenance 128.4 21.40 3.21 22.93 402.3 67.05 10.06 71.84 For GHG emissions, the indices found were 4.75/ kg CO2e h-1, 5.09 kg CO2e kg-1 and 712.50 kg CO2e kW-1 (Table 5), respectively relating GHG emissions by life cycle, mass and gross power. Comparing the emission by mass (4.7 kg CO2e kg-1) with those found by Mantoam et al. (2016) for tractors 1.0 (55 kW, 2650 kg) to 2.4 (246 kW, 10950 kg), it is possible to state that coffee harvesting requires materials with highest emission levels than tractors. Table 5: Indicators for GHG emissions for coffee harvester Phase Total value GHG emission indices kg CO2e kg CO2e h-1 kg CO2e kW-1 kg CO2e kg-1 Assembly 20026.0 3.34 500.65 3.58 Maintenance 8474.1 1.41 211.85 1.51 28500.1 4.75 712.50 5.09 4. Conclusions Comparisons among distinct agricultural machines show that they present distinct levels of energy demand and GHG emissions. So, using indices of other kinds of machinery may bring an incorrect evaluation of the production system evaluated. 179 In the assembling phase carbon steel and nylon are the most important causes of either energy demand or GHG emission. In maintenance, nylon, rubber, hydraulic oil, carbon steel and lubricant oil are the most important causes. Nylon affects more GHG emissions while rubber is the main one for energy demand. Adoption of other materials rather than nylon, carbon steel and rubber should be looked for, in order to increase the efficiency of the coffee harvester. Acknowledgments The authors acknowledge the group CNH Industrial Latin America Ltda for providing us data and FAPESP – São Paulo Research Foundation (Project 2015/01613-1) and CNPq – National Council of Scientific and Technological Development (301532/2015-0) for the grants provided. References Abubakar M., Umar B., 2006, Comparison of energy use patterns in Maiduguri and Yoke flour mills Nigeria. The CIGR Journal of Scientific Research and Development, Agricultural Engineering International. 16 p. Berry R.S., Fels M.F., 1972, The production and consumption of automobiles. An energy analysis of the manufacture, discard and reuse of the automobile and its component materials. A report of the Illinois Institute for Environmental Quality. Department of Chemistry, University of Chicago. 74 p. CASE, 2014, Coffee Express Manual Acessed 11.05.2017 Deleage J.P., Julien J.M., Sauget-Naudin N., Souchon C., 1979, Eco-energetics analysis of an agricultural system: The French case in 1970. Agroecosyst., 5, 345-365. Dyer J.A., Desjardins R.L., 2006, Carbon dioxide emissions associated with the manufacturing of tractors and farm machinery in Canada. Biosyst. Eng., 93, 107-118. Fluck R.C., Baird C.D., 1980. Agricultural energetics. Westport: AVI Publishers. 192 p. Hinrichs R.A., Kleinbach M. , 2009, Energia e meio ambiente. 3. ed. Tradução [tradução técnica VICHI, F.M.; MELLO L.F.]. São Paulo: Cengage Learning. 543 p. Mantoam E.J., Milan M., Gimenez L.M., Romanelli T.L., 2014, Embodied energy on sugarcane harvesters. Biosyst. Eng., 118,156-166. Mantoam E.J., Romanelli T.L., Gimenez L.M., 2016, Energy demand and greenhouse gases emissions in the life cycle of tractors. Biosyst. Eng.,151, 158-170. Nassim T., Hassan M.P., 2017, Development of a model for benchmarking of energy consumption and CO2 emission in cold-end of olefin plant Chem. Eng. Trans., 56, 1219-1224. Wang T.W.; Ho, C.S., 2017, Carbon and energy use reporting for buildings in Putrajaya: implementation status and drive factors. Chem. Eng. Trans., 56, 607-612. 180