Format And Type Fonts CCHHEEMMIICCAALL EENNGGIINNEEEERRIINNGG TTRRAANNSSAACCTTIIOONNSS VOL. 45, 2015 A publication of The Italian Association of Chemical Engineering www.aidic.it/cet Guest Editors: Petar Sabev Varbanov, Jiří Jaromír Klemeš, Sharifah Rafidah Wan Alwi, Jun Yow Yong, Xia Liu Copyright © 2015, AIDIC Servizi S.r.l., ISBN 978-88-95608-36-5; ISSN 2283-9216 DOI: 10.3303/CET1545108 Please cite this article as: Fu C. , Gundersen T., 2015, Appropriate placement of compressors and expanders in above ambient processes, Chemical Engineering Transactions, 45, 643-648 DOI:10.3303/CET1545108 643 Appropriate Placement of Compressors and Expanders in Above Ambient Processes Chao Fu*, Truls Gundersen Norwegian University of Science and Technology, Department of Energy and Process Engineering, Kolbjoern Hejes vei 1.A, NO-7491, Trondheim, Norway chao.fu@ntnu.no The appropriate placement of compressors and expanders is studied in this paper. Since both heat and work are involved, the topic is extended from heat integration to the integration of both heat and work. The objective is to minimize exergy consumption for the integrated processes. A set of theorems have been proposed for assisting the design. A graphical design methodology using the Grand Composite Curve is developed that achieves the target of minimum exergy consumption. 1. Introduction The concept of Appropriate Placement, also referred to as Correct Integration, is fundamental in Pinch Analysis, and a special case of the plus/minus principle (Linnhoff and Vredeveld, 1984). A quantitative approach is based on the Grand Composite Curve (GCC) that gives the amount of heat that can be correctly integrated. While this type of analysis is simple for reactors (Glavič et al., 1988), distillation columns (Linnhoff et al., 1983), evaporators (Smith and Linnhoff, 1988), heat pumps and heat engines (Townsend and Linnhoff, 1983), it is considerably more complicated for compressors and expanders since both heat and work are involved. The problem is extended to the integration of both heat and work. In addition, the shape of the GCC will change since the streams to be compressed or expanded are included when drawing the GCC. The placement of compressors was shortly discussed in the work by Glavič et al. (1988) with focus on reactor systems. Aspelund et al. (2007) formulated two heuristic rules for the placement of compressors and expanders in heat exchanger networks (HENs): (i) compression adds heat to the system and should preferably be done above Pinch, and (ii) expansion provides cooling to the system and should preferably be done below Pinch. The rules were stated more specifically by Gundersen et al. (2009) in the sense that both compression and expansion should start at the pinch temperature. An application example is the recuperative vapour recompression cryogenic air distillation process developed by Fu and Gundersen (2013). Another application is the N2 Brayton cycle in oxy-combustion processes (Fu and Gundersen, 2014). On the basis of the heuristic rules proposed by Gundersen et al. (2009), Wechsung et al. (2011) presented an MINLP optimization formulation for the synthesis of sub-ambient HENs including compression and expansion. The work is further extended by Onishi et al. (2014) using a superstructure with the objective of minimizing total annualized cost. The integration of compressors and expanders into HENs is not a straightforward task following the heuristic rules proposed by Gundersen et al. (2009). This paper presents a systematic methodology for such integration in above ambient processes. The objective is to minimize exergy consumption. A straightforward graphical design procedure is proposed on the basis of a set of theorems. 2. Problem statement The following problem is to be solved: “Given a set of process streams with supply and target states (temperature and pressure), as well as utilities for power, heating and cooling, design a network of heat exchangers, compressors and expanders in such a way that the exergy consumption is minimized or the exergy production is maximized”. 644 Table 1: Stream data Stream s T , o C tT , o C pmc , kW/ o C H , kW sp , bar tp , bar H1 400 35 2 730 2 1 H2 320 160 4 640 - - H3 110 35 3 225 - - C1 15 380 3 1095 1 2 C2 190 250 10 600 - - Hot utility 400 400 - - - - Cold utility 15 15 - - - - As an illustrative example, the stream data is shown in Table 1, where sT and tT are the supply and target temperatures, sp and tp are the supply and target pressures, pmc is the heat capacity flowrate, and ΔH is the enthalpy change due to temperature change. The following assumptions are made: (1) polytropic efficiency for compressors and expanders = 1, (2) minimum temperature difference for heat transfer minT = 20 °C, (3) ambient temperature 0T = 15 °C, (4) cold utility at CUT =1 5 °C and hot utility at HU T = 400 °C are available, and (5) the fluid to be compressed/expanded is ideal gas with constant specific heat ratio  = 1.4. The question to be addressed is at what temperatures C1 and H1 should be compressed/expanded so that the exergy consumption is minimised. 3. Theorems The following four theorems are proposed for the integration of compressors in above-ambient HENs (the proof is not included due to space limitation): (1) A HEN design with Pinch Compression (compression starts at pinch temperature PI T ) consumes the smallest amount of exergy if the following conditions are satisfied: (i) the outlet temperature of Ambient Compression (compression starts at 0 T ), comp,0 T , is lower than HU T , and (ii) Pinch Compression does not produce more heating than required. (2) If the heating demand has been satisfied by Pinch Compression, Ambient Compression is used for the remaining portion if comp,0 PI T T . (3) If the heating demand has been satisfied by Pinch Compression and comp,0 PI T T , Ambient Compression is used for the remaining portion and the corresponding heat (above pinch) should be utilized to reduce the portion using Pinch Compression. (4) The compression is done at 0 T if comp,0 HU T T . T’ ( o C) H (kW) T’0 T’PI Qcomp,max T’comp,PI QHU,0 a b cd Qexp,max T’exp,PI a' b' c' d' e' f' QCU,0 T’HU Figure 1: GCC without pressure manipulation 645 Calculate comp,0T exp,HU 0 [T T ?] Compression at Yes No Draw the GCC without pressure manipulation, determine YesNo 0 T p exp,PI,max [(mc ) ] p p exp,PI,max [(mc ) (mc ) ?] Pinch Compression [Pinch Expansion] is implemented The stream is split. The portion for Pinch Compression [Expansion] is p exp,PI,max [(mc ) ] Draw new GCC without pressure manipulation for the remaining portion, find new p exp,PI,max [(mc ) 0 ?] [Expansion at or ] 0 T YesNo exp,HU PI [T T ?] No Yes New GCCs are produced and pressure is manipulated only for the portion with compression [expansion] at , find The is reduced by the portion compressed [expanded] at p mc exp,HU [T ] HU comp,0 T T ? [Expansion at ]HUT p comp,PI,max (mc ) p p comp,PI,max (mc ) (mc ) ? p comp,PI,max (mc ) p exp,PI,max [(mc ) ]p comp,PI,max(mc ) p comp,PI,max (mc ) 0 ? PI comp,0T T ? Compression at 0 T The remaining portion is compressed [expanded] at and added to the total portion for compression [expansion] at 0 T HU [T ] p exp,PI,max [(mc ) ] p comp,PI,max (mc ) HU T 0 T HU [T ] 0 T HU [T ] 0 T HU [T ] Figure 2: The design procedure Similarly, the following four theorems are proposed for the integration of expanders in above ambient HENs: (5) A HEN design with Pinch Expansion (expansion starts at PI T ) consumes the smallest amount of exergy if the following conditions are satisfied: (i) the outlet temperature of expansion at HU T , exp,HU T , is higher than 0 T , and (ii) Pinch Expansion does not produce more cooling than required. (6) If the cooling demand has been satisfied by Pinch Expansion, the remaining expansion should be done at HU T or 0 T if exp,HU PI T T . (7) If the cooling demand has been satisfied by Pinch Expansion and exp,HU PI T T , Pinch Compression/Expansion should be used (Theorems 1 and 5). The work resulting from Pinch Compression/Expansion is determined to be comp,maxQ = 270 kW and ,maxexpQ = 100 kW based on Figure 3(a). The maximum portions are determined to be p comp,PI,max(mc ) = 2.66 kW/°C and p exp,PI,max(mc ) = 1.15 kW/°C. Streams C1 and H1 should thus be split: the first portions (indexed α) are compressed/expanded at PI T while the remaining portions are temporarily not compressed/expanded. A new GCC is then drawn and two new pinch points are created at 100 and 310 °C. The maximum portions compressed/expanded at the new pinch temperatures can thus be determined with a similar procedure using the concept of Potential Pinch Points: p comp,PI,max,new(mc ) = 0.64 kW/°C and p exp,PI,max,new(mc ) = 2.18 kW/°C. The remaining portions (indexed β) of streams H1 and C1 can thus be completely compressed/expanded at the new PIT . Table 2: New stream data for H1 and C1 Streams s T , °C tT , °C pmc , kW/°C H , kW sp , bar tp , bar Case I H1 279.1 35 2 488.2 1 1 C1 78.1 380 3 905.7 2 2 Case II H1_1 400 210 2 380 2 2 H1_2 123.2 35 2 176.4 1 1 C1_1 15 190 3 525 1 1 C1_2 291.4 380 3 265.8 2 2 Case III H1_α1 400 210 1.15 218.5 2 2 H1_α2 123.2 35 1.15 101.4 1 1 H1_β1 400 110 0.85 246.5 2 2 H1_β2 41.2 35 0.85 5.3 1 1 C1_α1 15 190 2.66 465.5 1 1 C1_α2 291.4 380 2.66 235.7 2 2 C1_β1 15 300 0.34 96.9 1 1 C1_β2 425.5 380 0.34 15.5 2 2 648 Table 3: Performance comparison Cases O I II III Hot utility demand, kW 350 591.8 119.4 37.6 Cold utility demand, kW 250 439.3 150 91.7 Pinch temperature, o C 200 200 100 100; 200; 310 Compression work, kW - 189.3 304.2 312.4 Expansion work, kW - 241.8 173.6 158.3 Exergy consumption, kW - 286.0 198.9 175.6 Due to pressure manipulation, the new data for streams H1 and C1 are shown in Table 2 and the corresponding GCCs are shown in Figure 3. The performance comparison is presented in Table 3. Compared to Case I (compression at 0T and expansion at HUT ), the exergy consumption is reduced by 30.5 % when both compression and expansion start at PIT (Case II) following the heuristic rules proposed by Gundersen et al. (2009). However, the original pinch has been removed according to Figure 3(c), indicating that too large portions have been compressed/expanded at PIT . Minimum exergy consumption is achieved when the proposed procedure is applied (Case III). The exergy consumption is reduced by 38.6 % compared to Case I. The reason for exergy savings is that the heat resulting from both compression and expansion has been completely utilised. This fact can be observed by comparing Cases III and O. The heating/cooling demand in Case III is reduced by an amount equal to the compression/expansion work. 6. Conclusions A systematic methodology for the integration of compressors and expanders into heat exchanger networks above ambient temperature has been developed. The objective has been to minimize exergy consumption since both heat and work are involved. The Grand Composite Curve has been used as a tool in the graphical design procedure. Considerable exergy savings (38.6 %) have been achieved in the illustrative example by maximum utilization of Pinch Compression/Expansion. References Aspelund A., Berstad D.O., Gundersen T., 2007, An Extended Pinch Analysis and Design procedure utilizing pressure based exergy for subambient cooling, Appl. Therm. Eng., 27(16), 2633-2649. Fu C., Gundersen T., 2013, Recuperative vapor recompression heat pumps in cryogenic air separation processes, Energy, 59, 708-718. Fu C., Gundersen T., 2014, N2 Brayton cycle in oxy-combustion power plants, Chemical Engineering Transactions, 39, 223-228. 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