id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
cet-15417		cet-15417		6	.pdf	application/pdf	3359	119	46	References Barbarossa S., Casu M., Orrù R., Locci A.M., Cao G., Garroni S., Bellucci D., Cannillo V., 2024, Synthesis, Sintering, Mechanical Properties and Oxidation Behavior of (Zr0.5Me0.5)B2 (Me = Ta, Hf) Solid Solutions, Ceramics International, 50, 7, 12158-12166 Barin I., 1995, Thermochemical Data of Pure Substances, 3rd ed., VCH, Germany Fahrenholtz W.G., Binner J., Zou J., 2016, Synthesis of ultra-refractory transition metal diboride compounds, Journal of Materials Research, 31, 2757–2772 Green D.W., Perry H.R., 2007, Perry’s Chemical Engineers’ Handbook, 8th ed., McGraw-Hill, USA Guo W.-M., Zhang G.-J., You Y., Wu S.-H., Lin H.-T., 2014, TiB2 Powders Synthesis by Borothermal Reduction in TiO2 Under Vacuum, Journal of the American Ceramic Society, 97, 5, 1359–1362 Kolios G., Frauhammer J., Eigenberger G., 2002, Efficient reactor concepts for coupling of endothermic and exothermic reactions, Chemical Engineering Science, 57, 9, 1505-1510 Licheri R., Musa C., Orrù R., Cao G., Sciti D., Silvestroni L., 2016, Bulk Monolithic Zirconium and Tantalum Diborides by Reactive and Non-reactive Spark Plasma Sintering, Journal of Alloys and Compounds, 663 351-359 Munir Z.A., Anselmi-Tamburini U., 1989, Self-propagating exothermic reactions: The synthesis of high- temperature materials by combustion, Materials Science Reports, 3, 7–8, 277-365 Sani E., Meucci M., Mercatelli L., Balbo A., Musa C., Licheri R., Orrù R., Cao G., 2017, Titanium diboride ceramics for solar thermal absorbers, Solar Energy Materials and Solar Cells, 169, 313 – 319 Wu K.-H., Wang Y., Yu-Yang, Zhang G.-H., Jiao S.-Q., Chou K.-C., 2019, Low temperature synthesis of titanium diboride nanosheets by molten salt–assisted borothermal reduction of TiO2, Journal of Nanoparticle Research, 21, 103 1002 CET-vol117-b.pdf 191casu.pdf Process Integration Approach for the Efficient Synthesis of Metal Boride Ceramics Thermodynamic analysis Defining Z as the molar fraction of the desired product obtained according to Eq(1) and (1 − Z) as the molar fraction obtained by Eq(2), the enthalpy balance for the adiabatic SHS process is: 0 = ∆hr + υMeB2qMeB2 + (1 − Z)υB2O3qB2O3 (3) where the heat generated by the combined reactions can be described as: ∆hr = υMeB2∆hf,MeB2 + (1 − Z)υB2O3∆hf,B2O3 − (1 − Z)υMeO2∆hf,MeO2 (4)	cache/cet-15417.pdf	txt/cet-15417.txt