id	sid	tid	token	lemma	pos
cet-15395	1	1	doi	doi	NOUN
cet-15395	1	2	:	:	PUNCT
cet-15395	1	3	10.3303	10.3303	NUM
cet-15395	1	4	/	/	SYM
cet-15395	1	5	cet25117145	cet25117145	NOUN
cet-15395	1	6	paper	paper	NOUN
cet-15395	1	7	received	receive	VERB
cet-15395	1	8	:	:	PUNCT
cet-15395	1	9	17	17	NUM
cet-15395	1	10	december	december	PROPN
cet-15395	1	11	2024	2024	NUM
cet-15395	1	12	;	;	PUNCT
cet-15395	1	13	revised	revise	VERB
cet-15395	1	14	:	:	PUNCT
cet-15395	1	15	15	15	NUM
cet-15395	1	16	march	march	NOUN
cet-15395	1	17	2025	2025	NUM
cet-15395	1	18	;	;	PUNCT
cet-15395	1	19	accepted	accept	VERB
cet-15395	1	20	:	:	PUNCT
cet-15395	1	21	17	17	NUM
cet-15395	1	22	may	may	AUX
cet-15395	1	23	2025	2025	NUM
cet-15395	1	24	please	please	INTJ
cet-15395	1	25	cite	cite	VERB
cet-15395	1	26	this	this	DET
cet-15395	1	27	article	article	NOUN
cet-15395	1	28	as	as	ADP
cet-15395	1	29	:	:	PUNCT
cet-15395	1	30	silva	silva	NOUN
cet-15395	1	31	c.c.g	c.c.g	PROPN
cet-15395	1	32	.	.	PROPN
cet-15395	1	33	,	,	PUNCT
cet-15395	1	34	silva	silva	PROPN
cet-15395	1	35	l.h.s	l.h.s	PROPN
cet-15395	1	36	.	.	PROPN
cet-15395	1	37	,	,	PUNCT
cet-15395	1	38	guirardello	guirardello	PROPN
cet-15395	1	39	r.	r.	PROPN
cet-15395	1	40	,	,	PUNCT
cet-15395	1	41	2025	2025	NUM
cet-15395	1	42	,	,	PUNCT
cet-15395	1	43	synthesis	synthesis	NOUN
cet-15395	1	44	of	of	ADP
cet-15395	1	45	global	global	ADJ
cet-15395	1	46	reaction	reaction	NOUN
cet-15395	1	47	routes	route	NOUN
cet-15395	1	48	using	use	VERB
cet-15395	1	49	thermodynamic	thermodynamic	ADJ
cet-15395	1	50	evaluation	evaluation	NOUN
cet-15395	1	51	,	,	PUNCT
cet-15395	1	52	chemical	chemical	NOUN
cet-15395	1	53	engineering	engineering	NOUN
cet-15395	1	54	transactions	transaction	NOUN
cet-15395	1	55	,	,	PUNCT
cet-15395	1	56	117	117	NUM
cet-15395	1	57	,	,	PUNCT
cet-15395	1	58	865	865	NUM
cet-15395	1	59	-	-	SYM
cet-15395	1	60	870	870	NUM
cet-15395	1	61	doi:10.3303	doi:10.3303	NOUN
cet-15395	1	62	/	/	SYM
cet-15395	1	63	cet25117145	cet25117145	NOUN
cet-15395	1	64	chemical	chemical	NOUN
cet-15395	1	65	engineering	engineering	NOUN
cet-15395	1	66	transactions	transaction	NOUN
cet-15395	1	67	vol	vol	NOUN
cet-15395	1	68	.	.	PROPN
cet-15395	1	69	117	117	NUM
cet-15395	1	70	,	,	PUNCT
cet-15395	1	71	2025	2025	NUM
cet-15395	1	72	a	a	DET
cet-15395	1	73	publication	publication	NOUN
cet-15395	1	74	of	of	ADP
cet-15395	1	75	the	the	DET
cet-15395	1	76	italian	italian	ADJ
cet-15395	1	77	association	association	NOUN
cet-15395	1	78	of	of	ADP
cet-15395	1	79	chemical	chemical	PROPN
cet-15395	1	80	engineering	engineering	NOUN
cet-15395	1	81	online	online	ADV
cet-15395	1	82	at	at	ADP
cet-15395	1	83	www.cetjournal.it	www.cetjournal.it	PROPN
cet-15395	1	84	guest	guest	NOUN
cet-15395	1	85	editors	editor	NOUN
cet-15395	1	86	:	:	PUNCT
cet-15395	1	87	fabrizio	fabrizio	PROPN
cet-15395	1	88	bezzo	bezzo	PROPN
cet-15395	1	89	,	,	PUNCT
cet-15395	1	90	flavio	flavio	PROPN
cet-15395	1	91	manenti	manenti	PROPN
cet-15395	1	92	,	,	PUNCT
cet-15395	1	93	gabriele	gabriele	PROPN
cet-15395	1	94	pannocchia	pannocchia	PROPN
cet-15395	1	95	,	,	PUNCT
cet-15395	1	96	almerinda	almerinda	PROPN
cet-15395	1	97	di	di	PROPN
cet-15395	1	98	benedetto	benedetto	PROPN
cet-15395	1	99	copyright	copyright	PROPN
cet-15395	1	100	©	©	PROPN
cet-15395	1	101	2025	2025	NUM
cet-15395	1	102	,	,	PUNCT
cet-15395	1	103	aidic	aidic	ADJ
cet-15395	1	104	servizi	servizi	PROPN
cet-15395	1	105	s.r.l	s.r.l	NOUN
cet-15395	1	106	.	.	PUNCT
cet-15395	2	1	isbn	isbn	PROPN
cet-15395	2	2	979	979	NUM
cet-15395	2	3	-	-	SYM
cet-15395	2	4	12	12	NUM
cet-15395	2	5	-	-	PUNCT
cet-15395	2	6	81206	81206	NUM
cet-15395	2	7	-	-	SYM
cet-15395	2	8	17	17	NUM
cet-15395	2	9	-	-	SYM
cet-15395	2	10	5	5	NUM
cet-15395	3	1	;	;	PUNCT
cet-15395	3	2	issn	issn	PROPN
cet-15395	3	3	2283	2283	NUM
cet-15395	3	4	-	-	SYM
cet-15395	3	5	9216	9216	NUM
cet-15395	3	6	synthesis	synthesis	NOUN
cet-15395	3	7	of	of	ADP
cet-15395	3	8	global	global	ADJ
cet-15395	3	9	reaction	reaction	NOUN
cet-15395	3	10	routes	route	NOUN
cet-15395	3	11	using	use	VERB
cet-15395	3	12	thermodynamic	thermodynamic	ADJ
cet-15395	3	13	evaluation	evaluation	NOUN
cet-15395	3	14	consuelo	consuelo	PROPN
cet-15395	3	15	c.g	c.g	PROPN
cet-15395	3	16	.	.	PROPN
cet-15395	3	17	silvaa	silvaa	PROPN
cet-15395	3	18	,	,	PUNCT
cet-15395	3	19	luiz	luiz	PROPN
cet-15395	3	20	henrique	henrique	PROPN
cet-15395	3	21	s.	s.	PROPN
cet-15395	3	22	silvab	silvab	PROPN
cet-15395	3	23	,	,	PUNCT
cet-15395	3	24	reginaldo	reginaldo	VERB
cet-15395	3	25	guirardelloc	guirardelloc	NOUN
cet-15395	3	26	a	a	DET
cet-15395	3	27	,	,	PUNCT
cet-15395	3	28	b	b	PROPN
cet-15395	3	29	federal	federal	ADJ
cet-15395	3	30	university	university	PROPN
cet-15395	3	31	of	of	ADP
cet-15395	3	32	recôncavo	recôncavo	ADJ
cet-15395	3	33	bahia	bahia	X
cet-15395	3	34	–	–	PUNCT
cet-15395	3	35	ufrb	ufrb	NOUN
cet-15395	3	36	–	–	PUNCT
cet-15395	3	37	brazil	brazil	PROPN
cet-15395	3	38	c	c	PROPN
cet-15395	3	39	school	school	NOUN
cet-15395	3	40	of	of	ADP
cet-15395	3	41	chemical	chemical	NOUN
cet-15395	3	42	engineering	engineering	NOUN
cet-15395	3	43	–	–	PUNCT
cet-15395	3	44	unicamp	unicamp	NOUN
cet-15395	3	45	,	,	PUNCT
cet-15395	3	46	av	av	PROPN
cet-15395	3	47	.	.	PUNCT
cet-15395	4	1	albert	albert	PROPN
cet-15395	4	2	einstein	einstein	PROPN
cet-15395	4	3	500	500	NUM
cet-15395	4	4	,	,	PUNCT
cet-15395	4	5	campinas	campina	NOUN
cet-15395	4	6	–	–	PUNCT
cet-15395	4	7	sp	sp	NOUN
cet-15395	4	8	,	,	PUNCT
cet-15395	4	9	13083	13083	NUM
cet-15395	4	10	-	-	SYM
cet-15395	4	11	852	852	NUM
cet-15395	4	12	,	,	PUNCT
cet-15395	4	13	brazil	brazil	PROPN
cet-15395	4	14	guira@feq.unicamp.br	guira@feq.unicamp.br	VERB
cet-15395	4	15	the	the	DET
cet-15395	4	16	global	global	ADJ
cet-15395	4	17	demand	demand	NOUN
cet-15395	4	18	for	for	ADP
cet-15395	4	19	sustainable	sustainable	ADJ
cet-15395	4	20	,	,	PUNCT
cet-15395	4	21	energy	energy	NOUN
cet-15395	4	22	-	-	PUNCT
cet-15395	4	23	efficient	efficient	ADJ
cet-15395	4	24	chemical	chemical	NOUN
cet-15395	4	25	processes	process	NOUN
cet-15395	4	26	has	have	AUX
cet-15395	4	27	accelerated	accelerate	VERB
cet-15395	4	28	innovations	innovation	NOUN
cet-15395	4	29	in	in	ADP
cet-15395	4	30	methane	methane	NOUN
cet-15395	4	31	(	(	PUNCT
cet-15395	4	32	ch4	ch4	NOUN
cet-15395	4	33	)	)	PUNCT
cet-15395	4	34	utilization	utilization	NOUN
cet-15395	4	35	.	.	PUNCT
cet-15395	5	1	methane	methane	NOUN
cet-15395	5	2	,	,	PUNCT
cet-15395	5	3	a	a	DET
cet-15395	5	4	versatile	versatile	ADJ
cet-15395	5	5	and	and	CCONJ
cet-15395	5	6	abundant	abundant	ADJ
cet-15395	5	7	resource	resource	NOUN
cet-15395	5	8	,	,	PUNCT
cet-15395	5	9	offers	offer	VERB
cet-15395	5	10	dual	dual	ADJ
cet-15395	5	11	benefits	benefit	NOUN
cet-15395	5	12	:	:	PUNCT
cet-15395	5	13	meeting	meet	VERB
cet-15395	5	14	energy	energy	NOUN
cet-15395	5	15	demands	demand	NOUN
cet-15395	5	16	while	while	SCONJ
cet-15395	5	17	reducing	reduce	VERB
cet-15395	5	18	environmental	environmental	ADJ
cet-15395	5	19	impacts	impact	NOUN
cet-15395	5	20	through	through	ADP
cet-15395	5	21	advanced	advanced	ADJ
cet-15395	5	22	conversion	conversion	NOUN
cet-15395	5	23	methods	method	NOUN
cet-15395	5	24	.	.	PUNCT
cet-15395	6	1	however	however	ADV
cet-15395	6	2	,	,	PUNCT
cet-15395	6	3	existing	exist	VERB
cet-15395	6	4	approaches	approach	NOUN
cet-15395	6	5	often	often	ADV
cet-15395	6	6	face	face	VERB
cet-15395	6	7	the	the	DET
cet-15395	6	8	challenge	challenge	NOUN
cet-15395	6	9	of	of	ADP
cet-15395	6	10	being	be	AUX
cet-15395	6	11	endothermic	endothermic	ADJ
cet-15395	6	12	,	,	PUNCT
cet-15395	6	13	consuming	consume	VERB
cet-15395	6	14	substantial	substantial	ADJ
cet-15395	6	15	energy	energy	NOUN
cet-15395	6	16	and	and	CCONJ
cet-15395	6	17	limiting	limit	VERB
cet-15395	6	18	industrial	industrial	ADJ
cet-15395	6	19	feasibility	feasibility	NOUN
cet-15395	6	20	.	.	PUNCT
cet-15395	7	1	this	this	DET
cet-15395	7	2	study	study	NOUN
cet-15395	7	3	introduces	introduce	NOUN
cet-15395	7	4	as	as	ADP
cet-15395	7	5	a	a	DET
cet-15395	7	6	goal	goal	NOUN
cet-15395	7	7	an	an	DET
cet-15395	7	8	exothermic	exothermic	ADJ
cet-15395	7	9	process	process	NOUN
cet-15395	7	10	design	design	NOUN
cet-15395	7	11	to	to	PART
cet-15395	7	12	optimize	optimize	VERB
cet-15395	7	13	energy	energy	NOUN
cet-15395	7	14	use	use	NOUN
cet-15395	7	15	,	,	PUNCT
cet-15395	7	16	while	while	SCONJ
cet-15395	7	17	achieving	achieve	VERB
cet-15395	7	18	sustainability	sustainability	NOUN
cet-15395	7	19	goals	goal	NOUN
cet-15395	7	20	such	such	ADJ
cet-15395	7	21	as	as	ADP
cet-15395	7	22	avoiding	avoid	VERB
cet-15395	7	23	the	the	DET
cet-15395	7	24	emission	emission	NOUN
cet-15395	7	25	of	of	ADP
cet-15395	7	26	carbon	carbon	NOUN
cet-15395	7	27	dioxide	dioxide	NOUN
cet-15395	7	28	.	.	PUNCT
cet-15395	8	1	through	through	ADP
cet-15395	8	2	thermodynamic	thermodynamic	ADJ
cet-15395	8	3	pathway	pathway	NOUN
cet-15395	8	4	evaluations	evaluation	NOUN
cet-15395	8	5	,	,	PUNCT
cet-15395	8	6	one	one	NUM
cet-15395	8	7	case	case	NOUN
cet-15395	8	8	study	study	NOUN
cet-15395	8	9	,	,	PUNCT
cet-15395	8	10	the	the	DET
cet-15395	8	11	production	production	NOUN
cet-15395	8	12	of	of	ADP
cet-15395	8	13	urea	urea	NOUN
cet-15395	8	14	,	,	PUNCT
cet-15395	8	15	was	be	AUX
cet-15395	8	16	identified	identify	VERB
cet-15395	8	17	as	as	ADP
cet-15395	8	18	a	a	DET
cet-15395	8	19	viable	viable	ADJ
cet-15395	8	20	product	product	NOUN
cet-15395	8	21	of	of	ADP
cet-15395	8	22	ch4	ch4	PROPN
cet-15395	8	23	conversion	conversion	PROPN
cet-15395	8	24	,	,	PUNCT
cet-15395	8	25	alongside	alongside	ADP
cet-15395	8	26	with	with	ADP
cet-15395	8	27	hydrogen	hydrogen	NOUN
cet-15395	8	28	generation	generation	NOUN
cet-15395	8	29	,	,	PUNCT
cet-15395	8	30	in	in	ADP
cet-15395	8	31	an	an	DET
cet-15395	8	32	overall	overall	ADJ
cet-15395	8	33	energetically	energetically	ADV
cet-15395	8	34	favourable	favourable	ADJ
cet-15395	8	35	process	process	NOUN
cet-15395	8	36	.	.	PUNCT
cet-15395	9	1	rigorous	rigorous	ADJ
cet-15395	9	2	simulations	simulation	NOUN
cet-15395	9	3	analyze	analyze	VERB
cet-15395	9	4	the	the	DET
cet-15395	9	5	process	process	NOUN
cet-15395	9	6	feasibility	feasibility	NOUN
cet-15395	9	7	,	,	PUNCT
cet-15395	9	8	emphasizing	emphasize	VERB
cet-15395	9	9	carbon	carbon	NOUN
cet-15395	9	10	emission	emission	NOUN
cet-15395	9	11	reductions	reduction	NOUN
cet-15395	9	12	and	and	CCONJ
cet-15395	9	13	resource	resource	NOUN
cet-15395	9	14	efficiency	efficiency	NOUN
cet-15395	9	15	.	.	PUNCT
cet-15395	10	1	by	by	ADP
cet-15395	10	2	integrating	integrate	VERB
cet-15395	10	3	advanced	advanced	ADJ
cet-15395	10	4	modelling	modelling	NOUN
cet-15395	10	5	tools	tool	NOUN
cet-15395	10	6	,	,	PUNCT
cet-15395	10	7	this	this	DET
cet-15395	10	8	work	work	NOUN
cet-15395	10	9	aligns	align	VERB
cet-15395	10	10	with	with	ADP
cet-15395	10	11	global	global	ADJ
cet-15395	10	12	efforts	effort	NOUN
cet-15395	10	13	to	to	PART
cet-15395	10	14	develop	develop	VERB
cet-15395	10	15	green	green	ADJ
cet-15395	10	16	chemical	chemical	NOUN
cet-15395	10	17	technologies	technology	NOUN
cet-15395	10	18	,	,	PUNCT
cet-15395	10	19	highlighting	highlight	VERB
cet-15395	10	20	its	its	PRON
cet-15395	10	21	role	role	NOUN
cet-15395	10	22	in	in	ADP
cet-15395	10	23	industrial	industrial	ADJ
cet-15395	10	24	innovation	innovation	NOUN
cet-15395	10	25	and	and	CCONJ
cet-15395	10	26	environmental	environmental	ADJ
cet-15395	10	27	responsibility	responsibility	NOUN
cet-15395	10	28	.	.	PUNCT
cet-15395	11	1	1	1	X
cet-15395	11	2	.	.	X
cet-15395	11	3	introduction	introduction	NOUN
cet-15395	11	4	many	many	ADJ
cet-15395	11	5	processes	process	NOUN
cet-15395	11	6	aiming	aim	VERB
cet-15395	11	7	to	to	PART
cet-15395	11	8	use	use	VERB
cet-15395	11	9	ch4	ch4	NOUN
cet-15395	11	10	without	without	ADP
cet-15395	11	11	emitting	emit	VERB
cet-15395	11	12	co2	co2	NOUN
cet-15395	11	13	have	have	VERB
cet-15395	11	14	the	the	DET
cet-15395	11	15	disadvantage	disadvantage	NOUN
cet-15395	11	16	of	of	ADP
cet-15395	11	17	being	be	AUX
cet-15395	11	18	endothermic	endothermic	ADJ
cet-15395	11	19	,	,	PUNCT
cet-15395	11	20	that	that	ADV
cet-15395	11	21	is	is	ADV
cet-15395	11	22	,	,	PUNCT
cet-15395	11	23	they	they	PRON
cet-15395	11	24	consume	consume	VERB
cet-15395	11	25	energy	energy	NOUN
cet-15395	11	26	,	,	PUNCT
cet-15395	11	27	so	so	SCONJ
cet-15395	11	28	the	the	DET
cet-15395	11	29	motivation	motivation	NOUN
cet-15395	11	30	for	for	ADP
cet-15395	11	31	this	this	DET
cet-15395	11	32	work	work	NOUN
cet-15395	11	33	is	be	AUX
cet-15395	11	34	from	from	ADP
cet-15395	11	35	the	the	DET
cet-15395	11	36	very	very	ADV
cet-15395	11	37	beginning	beginning	NOUN
cet-15395	11	38	the	the	DET
cet-15395	11	39	process	process	NOUN
cet-15395	11	40	to	to	PART
cet-15395	11	41	use	use	VERB
cet-15395	11	42	reagents	reagent	NOUN
cet-15395	11	43	and	and	CCONJ
cet-15395	11	44	products	product	NOUN
cet-15395	11	45	in	in	ADP
cet-15395	11	46	such	such	DET
cet-15395	11	47	a	a	DET
cet-15395	11	48	way	way	NOUN
cet-15395	11	49	that	that	PRON
cet-15395	11	50	the	the	DET
cet-15395	11	51	overall	overall	ADJ
cet-15395	11	52	process	process	NOUN
cet-15395	11	53	is	be	AUX
cet-15395	11	54	exothermal	exothermal	ADJ
cet-15395	11	55	or	or	CCONJ
cet-15395	11	56	autothermal	autothermal	ADJ
cet-15395	11	57	,	,	PUNCT
cet-15395	11	58	so	so	SCONJ
cet-15395	11	59	that	that	SCONJ
cet-15395	11	60	it	it	PRON
cet-15395	11	61	does	do	AUX
cet-15395	11	62	not	not	PART
cet-15395	11	63	consume	consume	VERB
cet-15395	11	64	energy	energy	NOUN
cet-15395	11	65	.	.	PUNCT
cet-15395	12	1	the	the	DET
cet-15395	12	2	thermodynamic	thermodynamic	ADJ
cet-15395	12	3	evaluation	evaluation	NOUN
cet-15395	12	4	of	of	ADP
cet-15395	12	5	a	a	DET
cet-15395	12	6	global	global	ADJ
cet-15395	12	7	reaction	reaction	NOUN
cet-15395	12	8	route	route	NOUN
cet-15395	12	9	is	be	AUX
cet-15395	12	10	performed	perform	VERB
cet-15395	12	11	in	in	ADP
cet-15395	12	12	order	order	NOUN
cet-15395	12	13	to	to	PART
cet-15395	12	14	determine	determine	VERB
cet-15395	12	15	whether	whether	SCONJ
cet-15395	12	16	the	the	DET
cet-15395	12	17	overall	overall	ADJ
cet-15395	12	18	reaction	reaction	NOUN
cet-15395	12	19	is	be	AUX
cet-15395	12	20	thermodynamically	thermodynamically	ADV
cet-15395	12	21	favourable	favourable	ADJ
cet-15395	12	22	or	or	CCONJ
cet-15395	12	23	not	not	PART
cet-15395	12	24	.	.	PUNCT
cet-15395	13	1	this	this	DET
cet-15395	13	2	step	step	NOUN
cet-15395	13	3	is	be	AUX
cet-15395	13	4	important	important	ADJ
cet-15395	13	5	,	,	PUNCT
cet-15395	13	6	because	because	SCONJ
cet-15395	13	7	it	it	PRON
cet-15395	13	8	predicts	predict	VERB
cet-15395	13	9	whether	whether	SCONJ
cet-15395	13	10	the	the	DET
cet-15395	13	11	process	process	NOUN
cet-15395	13	12	will	will	AUX
cet-15395	13	13	consume	consume	VERB
cet-15395	13	14	energy	energy	NOUN
cet-15395	13	15	or	or	CCONJ
cet-15395	13	16	not	not	PART
cet-15395	13	17	.	.	PUNCT
cet-15395	14	1	from	from	ADP
cet-15395	14	2	the	the	DET
cet-15395	14	3	formation	formation	NOUN
cet-15395	14	4	enthalpy	enthalpy	NOUN
cet-15395	14	5	,	,	PUNCT
cet-15395	14	6	the	the	DET
cet-15395	14	7	enthalpy	enthalpy	NOUN
cet-15395	14	8	variation	variation	NOUN
cet-15395	14	9	δh	δh	NOUN
cet-15395	14	10	of	of	ADP
cet-15395	14	11	the	the	DET
cet-15395	14	12	global	global	ADJ
cet-15395	14	13	reaction	reaction	NOUN
cet-15395	14	14	is	be	AUX
cet-15395	14	15	calculated	calculate	VERB
cet-15395	14	16	.	.	PUNCT
cet-15395	15	1	in	in	ADP
cet-15395	15	2	addition	addition	NOUN
cet-15395	15	3	,	,	PUNCT
cet-15395	15	4	δg	δg	VERB
cet-15395	15	5	provides	provide	VERB
cet-15395	15	6	important	important	ADJ
cet-15395	15	7	information	information	NOUN
cet-15395	15	8	regarding	regard	VERB
cet-15395	15	9	the	the	DET
cet-15395	15	10	spontaneity	spontaneity	NOUN
cet-15395	15	11	of	of	ADP
cet-15395	15	12	the	the	DET
cet-15395	15	13	process	process	NOUN
cet-15395	15	14	or	or	CCONJ
cet-15395	15	15	individual	individual	ADJ
cet-15395	15	16	steps	step	NOUN
cet-15395	15	17	.	.	PUNCT
cet-15395	16	1	if	if	SCONJ
cet-15395	16	2	δg	δg	NOUN
cet-15395	16	3	is	be	AUX
cet-15395	16	4	negative	negative	ADJ
cet-15395	16	5	the	the	DET
cet-15395	16	6	reaction	reaction	NOUN
cet-15395	16	7	route	route	NOUN
cet-15395	16	8	is	be	AUX
cet-15395	16	9	thermodynamically	thermodynamically	ADV
cet-15395	16	10	favourable	favourable	ADJ
cet-15395	16	11	.	.	PUNCT
cet-15395	17	1	therefore	therefore	ADV
cet-15395	17	2	,	,	PUNCT
cet-15395	17	3	the	the	DET
cet-15395	17	4	thermodynamic	thermodynamic	ADJ
cet-15395	17	5	evaluation	evaluation	NOUN
cet-15395	17	6	of	of	ADP
cet-15395	17	7	a	a	DET
cet-15395	17	8	global	global	ADJ
cet-15395	17	9	reaction	reaction	NOUN
cet-15395	17	10	route	route	NOUN
cet-15395	17	11	involves	involve	VERB
cet-15395	17	12	the	the	DET
cet-15395	17	13	evaluation	evaluation	NOUN
cet-15395	17	14	of	of	ADP
cet-15395	17	15	the	the	DET
cet-15395	17	16	formation	formation	NOUN
cet-15395	17	17	enthalpy	enthalpy	NOUN
cet-15395	17	18	of	of	ADP
cet-15395	17	19	reagents	reagent	NOUN
cet-15395	17	20	and	and	CCONJ
cet-15395	17	21	products	product	NOUN
cet-15395	17	22	,	,	PUNCT
cet-15395	17	23	the	the	DET
cet-15395	17	24	determination	determination	NOUN
cet-15395	17	25	of	of	ADP
cet-15395	17	26	variations	variation	NOUN
cet-15395	17	27	of	of	ADP
cet-15395	17	28	enthalpy	enthalpy	NOUN
cet-15395	17	29	and	and	CCONJ
cet-15395	17	30	gibbs	gibbs	PROPN
cet-15395	17	31	energy	energy	NOUN
cet-15395	17	32	,	,	PUNCT
cet-15395	17	33	and	and	CCONJ
cet-15395	17	34	the	the	DET
cet-15395	17	35	interpretation	interpretation	NOUN
cet-15395	17	36	of	of	ADP
cet-15395	17	37	the	the	DET
cet-15395	17	38	results	result	NOUN
cet-15395	17	39	to	to	PART
cet-15395	17	40	determine	determine	VERB
cet-15395	17	41	whether	whether	SCONJ
cet-15395	17	42	the	the	DET
cet-15395	17	43	reaction	reaction	NOUN
cet-15395	17	44	route	route	NOUN
cet-15395	17	45	is	be	AUX
cet-15395	17	46	thermodynamically	thermodynamically	ADV
cet-15395	17	47	favourable	favourable	ADJ
cet-15395	17	48	or	or	CCONJ
cet-15395	17	49	not	not	PART
cet-15395	17	50	.	.	PUNCT
cet-15395	18	1	the	the	DET
cet-15395	18	2	thermodynamics	thermodynamic	NOUN
cet-15395	18	3	of	of	ADP
cet-15395	18	4	a	a	DET
cet-15395	18	5	global	global	ADJ
cet-15395	18	6	reaction	reaction	NOUN
cet-15395	18	7	route	route	NOUN
cet-15395	18	8	can	can	AUX
cet-15395	18	9	also	also	ADV
cet-15395	18	10	be	be	AUX
cet-15395	18	11	evaluated	evaluate	VERB
cet-15395	18	12	by	by	ADP
cet-15395	18	13	considering	consider	VERB
cet-15395	18	14	the	the	DET
cet-15395	18	15	variation	variation	NOUN
cet-15395	18	16	of	of	ADP
cet-15395	18	17	gibbs	gibbs	PROPN
cet-15395	18	18	energy	energy	PROPN
cet-15395	18	19	δg	δg	PROPN
cet-15395	18	20	.	.	PUNCT
cet-15395	19	1	the	the	DET
cet-15395	19	2	gibbs	gibbs	PROPN
cet-15395	19	3	energy	energy	NOUN
cet-15395	19	4	is	be	AUX
cet-15395	19	5	the	the	DET
cet-15395	19	6	available	available	ADJ
cet-15395	19	7	energy	energy	NOUN
cet-15395	19	8	to	to	PART
cet-15395	19	9	perform	perform	VERB
cet-15395	19	10	work	work	NOUN
cet-15395	19	11	in	in	ADP
cet-15395	19	12	a	a	DET
cet-15395	19	13	system	system	NOUN
cet-15395	19	14	and	and	CCONJ
cet-15395	19	15	is	be	AUX
cet-15395	19	16	related	relate	VERB
cet-15395	19	17	to	to	ADP
cet-15395	19	18	variations	variation	NOUN
cet-15395	19	19	of	of	ADP
cet-15395	19	20	enthalpy	enthalpy	NOUN
cet-15395	19	21	and	and	CCONJ
cet-15395	19	22	entropy	entropy	NOUN
cet-15395	19	23	.	.	PUNCT
cet-15395	20	1	if	if	SCONJ
cet-15395	20	2	δg	δg	NOUN
cet-15395	20	3	is	be	AUX
cet-15395	20	4	negative	negative	ADJ
cet-15395	20	5	,	,	PUNCT
cet-15395	20	6	it	it	PRON
cet-15395	20	7	means	mean	VERB
cet-15395	20	8	that	that	SCONJ
cet-15395	20	9	the	the	DET
cet-15395	20	10	reaction	reaction	NOUN
cet-15395	20	11	is	be	AUX
cet-15395	20	12	spontaneous	spontaneous	ADJ
cet-15395	20	13	and	and	CCONJ
cet-15395	20	14	the	the	DET
cet-15395	20	15	reaction	reaction	NOUN
cet-15395	20	16	route	route	NOUN
cet-15395	20	17	is	be	AUX
cet-15395	20	18	thermodynamically	thermodynamically	ADV
cet-15395	20	19	favourable	favourable	ADJ
cet-15395	20	20	.	.	PUNCT
cet-15395	21	1	if	if	SCONJ
cet-15395	21	2	δg	δg	NOUN
cet-15395	21	3	is	be	AUX
cet-15395	21	4	positive	positive	ADJ
cet-15395	21	5	,	,	PUNCT
cet-15395	21	6	it	it	PRON
cet-15395	21	7	means	mean	VERB
cet-15395	21	8	that	that	SCONJ
cet-15395	21	9	the	the	DET
cet-15395	21	10	reaction	reaction	NOUN
cet-15395	21	11	is	be	AUX
cet-15395	21	12	not	not	PART
cet-15395	21	13	spontaneous	spontaneous	ADJ
cet-15395	21	14	and	and	CCONJ
cet-15395	21	15	the	the	DET
cet-15395	21	16	reaction	reaction	NOUN
cet-15395	21	17	route	route	NOUN
cet-15395	21	18	is	be	AUX
cet-15395	21	19	thermodynamically	thermodynamically	ADV
cet-15395	21	20	unfavourable	unfavourable	ADJ
cet-15395	21	21	.	.	PUNCT
cet-15395	22	1	as	as	ADP
cet-15395	22	2	a	a	DET
cet-15395	22	3	case	case	NOUN
cet-15395	22	4	study	study	NOUN
cet-15395	22	5	,	,	PUNCT
cet-15395	22	6	the	the	DET
cet-15395	22	7	proposed	propose	VERB
cet-15395	22	8	approach	approach	NOUN
cet-15395	22	9	was	be	AUX
cet-15395	22	10	applied	apply	VERB
cet-15395	22	11	in	in	ADP
cet-15395	22	12	a	a	DET
cet-15395	22	13	thermodynamic	thermodynamic	ADJ
cet-15395	22	14	analysis	analysis	NOUN
cet-15395	22	15	for	for	ADP
cet-15395	22	16	the	the	DET
cet-15395	22	17	production	production	NOUN
cet-15395	22	18	of	of	ADP
cet-15395	22	19	urea	urea	NOUN
cet-15395	22	20	,	,	PUNCT
cet-15395	22	21	which	which	PRON
cet-15395	22	22	is	be	AUX
cet-15395	22	23	exothermic	exothermic	ADJ
cet-15395	22	24	,	,	PUNCT
cet-15395	22	25	while	while	SCONJ
cet-15395	22	26	avoiding	avoid	VERB
cet-15395	22	27	the	the	DET
cet-15395	22	28	production	production	NOUN
cet-15395	22	29	of	of	ADP
cet-15395	22	30	co2	co2	NOUN
cet-15395	22	31	.	.	PUNCT
cet-15395	23	1	for	for	ADP
cet-15395	23	2	thermodynamic	thermodynamic	ADJ
cet-15395	23	3	analysis	analysis	NOUN
cet-15395	23	4	,	,	PUNCT
cet-15395	23	5	it	it	PRON
cet-15395	23	6	is	be	AUX
cet-15395	23	7	considered	consider	VERB
cet-15395	23	8	how	how	SCONJ
cet-15395	23	9	many	many	ADJ
cet-15395	23	10	reaction	reaction	NOUN
cet-15395	23	11	routes	route	NOUN
cet-15395	23	12	are	be	AUX
cet-15395	23	13	possible	possible	ADJ
cet-15395	23	14	for	for	ADP
cet-15395	23	15	the	the	DET
cet-15395	23	16	same	same	ADJ
cet-15395	23	17	reagent	reagent	NOUN
cet-15395	23	18	and	and	CCONJ
cet-15395	23	19	the	the	DET
cet-15395	23	20	same	same	ADJ
cet-15395	23	21	product	product	NOUN
cet-15395	23	22	.	.	PUNCT
cet-15395	24	1	the	the	DET
cet-15395	24	2	data	datum	NOUN
cet-15395	24	3	obtained	obtain	VERB
cet-15395	24	4	was	be	AUX
cet-15395	24	5	handled	handle	VERB
cet-15395	24	6	in	in	ADP
cet-15395	24	7	graphical	graphical	ADJ
cet-15395	24	8	and	and	CCONJ
cet-15395	24	9	numerical	numerical	ADJ
cet-15395	24	10	computational	computational	ADJ
cet-15395	24	11	simulations	simulation	NOUN
cet-15395	24	12	with	with	ADP
cet-15395	24	13	the	the	DET
cet-15395	24	14	help	help	NOUN
cet-15395	24	15	of	of	ADP
cet-15395	24	16	the	the	DET
cet-15395	24	17	software	software	NOUN
cet-15395	24	18	aspen	aspen	NOUN
cet-15395	24	19	,	,	PUNCT
cet-15395	24	20	which	which	PRON
cet-15395	24	21	is	be	AUX
cet-15395	24	22	a	a	DET
cet-15395	24	23	process	process	NOUN
cet-15395	24	24	modelling	model	VERB
cet-15395	24	25	tool	tool	NOUN
cet-15395	24	26	used	use	VERB
cet-15395	24	27	for	for	ADP
cet-15395	24	28	process	process	NOUN
cet-15395	24	29	monitoring	monitoring	NOUN
cet-15395	24	30	,	,	PUNCT
cet-15395	24	31	optimization	optimization	NOUN
cet-15395	24	32	and	and	CCONJ
cet-15395	24	33	simulation	simulation	NOUN
cet-15395	24	34	.	.	PUNCT
cet-15395	25	1	also	also	ADV
cet-15395	25	2	,	,	PUNCT
cet-15395	25	3	this	this	DET
cet-15395	25	4	particular	particular	ADJ
cet-15395	25	5	case	case	NOUN
cet-15395	25	6	study	study	NOUN
cet-15395	25	7	(	(	PUNCT
cet-15395	25	8	urea	urea	NOUN
cet-15395	25	9	production	production	NOUN
cet-15395	25	10	)	)	PUNCT
cet-15395	25	11	uses	use	VERB
cet-15395	25	12	the	the	DET
cet-15395	25	13	co2	co2	NOUN
cet-15395	25	14	generated	generate	VERB
cet-15395	25	15	in	in	ADP
cet-15395	25	16	one	one	NUM
cet-15395	25	17	reaction	reaction	NOUN
cet-15395	25	18	step	step	NOUN
cet-15395	25	19	to	to	PART
cet-15395	25	20	produce	produce	VERB
cet-15395	25	21	the	the	DET
cet-15395	25	22	final	final	ADJ
cet-15395	25	23	product	product	NOUN
cet-15395	25	24	,	,	PUNCT
cet-15395	25	25	thus	thus	ADV
cet-15395	25	26	preventing	prevent	VERB
cet-15395	25	27	carbon	carbon	NOUN
cet-15395	25	28	dioxide	dioxide	NOUN
cet-15395	25	29	from	from	ADP
cet-15395	25	30	being	be	AUX
cet-15395	25	31	released	release	VERB
cet-15395	25	32	into	into	ADP
cet-15395	25	33	the	the	DET
cet-15395	25	34	atmosphere	atmosphere	NOUN
cet-15395	25	35	.	.	PUNCT
cet-15395	26	1	finally	finally	ADV
cet-15395	26	2	,	,	PUNCT
cet-15395	26	3	hydrogen	hydrogen	NOUN
cet-15395	26	4	is	be	AUX
cet-15395	26	5	also	also	ADV
cet-15395	26	6	produced	produce	VERB
cet-15395	26	7	as	as	ADP
cet-15395	26	8	a	a	DET
cet-15395	26	9	by	by	ADP
cet-15395	26	10	-	-	PUNCT
cet-15395	26	11	product	product	NOUN
cet-15395	26	12	in	in	ADP
cet-15395	26	13	this	this	DET
cet-15395	26	14	particular	particular	ADJ
cet-15395	26	15	process	process	NOUN
cet-15395	26	16	.	.	PUNCT
cet-15395	27	1	865	865	NUM
cet-15395	27	2	2	2	NUM
cet-15395	27	3	.	.	PUNCT
cet-15395	27	4	methodology	methodology	NOUN
cet-15395	27	5	linear	linear	PROPN
cet-15395	27	6	programming	programming	NOUN
cet-15395	27	7	model	model	NOUN
cet-15395	27	8	this	this	PRON
cet-15395	27	9	is	be	AUX
cet-15395	27	10	a	a	DET
cet-15395	27	11	synthesis	synthesis	NOUN
cet-15395	27	12	strategy	strategy	NOUN
cet-15395	27	13	,	,	PUNCT
cet-15395	27	14	since	since	SCONJ
cet-15395	27	15	the	the	DET
cet-15395	27	16	process	process	NOUN
cet-15395	27	17	is	be	AUX
cet-15395	27	18	not	not	PART
cet-15395	27	19	known	know	VERB
cet-15395	27	20	in	in	ADP
cet-15395	27	21	advance	advance	NOUN
cet-15395	27	22	,	,	PUNCT
cet-15395	27	23	not	not	PART
cet-15395	27	24	even	even	ADV
cet-15395	27	25	the	the	DET
cet-15395	27	26	products	product	NOUN
cet-15395	27	27	and	and	CCONJ
cet-15395	27	28	reactants	reactant	NOUN
cet-15395	27	29	,	,	PUNCT
cet-15395	27	30	except	except	SCONJ
cet-15395	27	31	methane	methane	NOUN
cet-15395	27	32	as	as	ADP
cet-15395	27	33	raw	raw	ADJ
cet-15395	27	34	material	material	NOUN
cet-15395	27	35	,	,	PUNCT
cet-15395	27	36	hydrogen	hydrogen	NOUN
cet-15395	27	37	as	as	ADP
cet-15395	27	38	a	a	DET
cet-15395	27	39	by	by	ADP
cet-15395	27	40	-	-	PUNCT
cet-15395	27	41	product	product	NOUN
cet-15395	27	42	and	and	CCONJ
cet-15395	27	43	carbon	carbon	NOUN
cet-15395	27	44	dioxide	dioxide	NOUN
cet-15395	27	45	is	be	AUX
cet-15395	27	46	not	not	PART
cet-15395	27	47	desired	desire	VERB
cet-15395	27	48	as	as	ADP
cet-15395	27	49	a	a	DET
cet-15395	27	50	product	product	NOUN
cet-15395	27	51	(	(	PUNCT
cet-15395	27	52	maybe	maybe	ADV
cet-15395	27	53	only	only	ADV
cet-15395	27	54	as	as	ADP
cet-15395	27	55	an	an	DET
cet-15395	27	56	intermediate	intermediate	ADJ
cet-15395	27	57	)	)	PUNCT
cet-15395	27	58	.	.	PUNCT
cet-15395	28	1	also	also	ADV
cet-15395	28	2	,	,	PUNCT
cet-15395	28	3	it	it	PRON
cet-15395	28	4	is	be	AUX
cet-15395	28	5	desirable	desirable	ADJ
cet-15395	28	6	that	that	SCONJ
cet-15395	28	7	the	the	DET
cet-15395	28	8	global	global	ADJ
cet-15395	28	9	process	process	NOUN
cet-15395	28	10	be	be	AUX
cet-15395	28	11	exothermic	exothermic	ADJ
cet-15395	28	12	.	.	PUNCT
cet-15395	29	1	the	the	DET
cet-15395	29	2	first	first	ADJ
cet-15395	29	3	step	step	NOUN
cet-15395	29	4	is	be	AUX
cet-15395	29	5	the	the	DET
cet-15395	29	6	definition	definition	NOUN
cet-15395	29	7	of	of	ADP
cet-15395	29	8	the	the	DET
cet-15395	29	9	products	product	NOUN
cet-15395	29	10	and	and	CCONJ
cet-15395	29	11	the	the	DET
cet-15395	29	12	reactants	reactant	NOUN
cet-15395	29	13	.	.	PUNCT
cet-15395	30	1	they	they	PRON
cet-15395	30	2	are	be	AUX
cet-15395	30	3	not	not	PART
cet-15395	30	4	specified	specify	VERB
cet-15395	30	5	in	in	ADP
cet-15395	30	6	advance	advance	NOUN
cet-15395	30	7	,	,	PUNCT
cet-15395	30	8	they	they	PRON
cet-15395	30	9	will	will	AUX
cet-15395	30	10	be	be	AUX
cet-15395	30	11	determined	determine	VERB
cet-15395	30	12	from	from	ADP
cet-15395	30	13	a	a	DET
cet-15395	30	14	list	list	NOUN
cet-15395	30	15	of	of	ADP
cet-15395	30	16	possible	possible	ADJ
cet-15395	30	17	substances	substance	NOUN
cet-15395	30	18	that	that	PRON
cet-15395	30	19	may	may	AUX
cet-15395	30	20	exist	exist	VERB
cet-15395	30	21	or	or	CCONJ
cet-15395	30	22	not	not	PART
cet-15395	30	23	.	.	PUNCT
cet-15395	31	1	these	these	DET
cet-15395	31	2	substances	substance	NOUN
cet-15395	31	3	have	have	VERB
cet-15395	31	4	their	their	PRON
cet-15395	31	5	enthalpies	enthalpy	NOUN
cet-15395	31	6	evaluated	evaluate	VERB
cet-15395	31	7	at	at	ADP
cet-15395	31	8	the	the	DET
cet-15395	31	9	conditions	condition	NOUN
cet-15395	31	10	of	of	ADP
cet-15395	31	11	the	the	DET
cet-15395	31	12	feed	feed	NOUN
cet-15395	31	13	and	and	CCONJ
cet-15395	31	14	exit	exit	NOUN
cet-15395	31	15	of	of	ADP
cet-15395	31	16	the	the	DET
cet-15395	31	17	process	process	NOUN
cet-15395	31	18	(	(	PUNCT
cet-15395	31	19	reference	reference	NOUN
cet-15395	31	20	state	state	NOUN
cet-15395	31	21	)	)	PUNCT
cet-15395	31	22	,	,	PUNCT
cet-15395	31	23	to	to	PART
cet-15395	31	24	calculate	calculate	VERB
cet-15395	31	25	the	the	DET
cet-15395	31	26	total	total	ADJ
cet-15395	31	27	enthalpy	enthalpy	NOUN
cet-15395	31	28	variation	variation	NOUN
cet-15395	31	29	,	,	PUNCT
cet-15395	31	30	so	so	SCONJ
cet-15395	31	31	that	that	SCONJ
cet-15395	31	32	the	the	DET
cet-15395	31	33	whole	whole	ADJ
cet-15395	31	34	process	process	NOUN
cet-15395	31	35	is	be	AUX
cet-15395	31	36	exothermic	exothermic	ADJ
cet-15395	31	37	,	,	PUNCT
cet-15395	31	38	to	to	PART
cet-15395	31	39	avoid	avoid	VERB
cet-15395	31	40	energy	energy	NOUN
cet-15395	31	41	consumption	consumption	NOUN
cet-15395	31	42	.	.	PUNCT
cet-15395	32	1	this	this	DET
cet-15395	32	2	problem	problem	NOUN
cet-15395	32	3	can	can	AUX
cet-15395	32	4	then	then	ADV
cet-15395	32	5	be	be	AUX
cet-15395	32	6	formulated	formulate	VERB
cet-15395	32	7	as	as	ADP
cet-15395	32	8	a	a	DET
cet-15395	32	9	linear	linear	ADJ
cet-15395	32	10	programming	programming	NOUN
cet-15395	32	11	model	model	NOUN
cet-15395	32	12	,	,	PUNCT
cet-15395	32	13	whose	whose	DET
cet-15395	32	14	resolution	resolution	NOUN
cet-15395	32	15	will	will	AUX
cet-15395	32	16	define	define	VERB
cet-15395	32	17	the	the	DET
cet-15395	32	18	overall	overall	ADJ
cet-15395	32	19	process	process	NOUN
cet-15395	32	20	,	,	PUNCT
cet-15395	32	21	and	and	CCONJ
cet-15395	32	22	is	be	AUX
cet-15395	32	23	given	give	VERB
cet-15395	32	24	by	by	ADP
cet-15395	32	25	:	:	PUNCT
cet-15395	32	26	max	max	PROPN
cet-15395	32	27	𝑛𝑖	𝑛𝑖	PROPN
cet-15395	32	28	𝑛desired	𝑛desire	VERB
cet-15395	32	29	product	product	NOUN
cet-15395	32	30	(	(	PUNCT
cet-15395	32	31	1	1	X
cet-15395	32	32	)	)	PUNCT
cet-15395	32	33	𝑎𝑚𝑖	𝑎𝑚𝑖	NOUN
cet-15395	32	34	∙	∙	PROPN
cet-15395	32	35	𝑛𝑖	𝑛𝑖	PRON
cet-15395	32	36	products	product	NOUN
cet-15395	32	37	=	=	PUNCT
cet-15395	32	38	𝑁𝑝	𝑁𝑝	NOUN
cet-15395	32	39	𝑖=1	𝑖=1	PROPN
cet-15395	32	40	𝑎𝑚𝑖	𝑎𝑚𝑖	AUX
cet-15395	32	41	∙	∙	PROPN
cet-15395	32	42	𝑛𝑖	𝑛𝑖	PRON
cet-15395	32	43	reactants	reactant	VERB
cet-15395	32	44	𝑁𝑟	𝑁𝑟	PROPN
cet-15395	32	45	𝑖=1	𝑖=1	PROPN
cet-15395	32	46	(	(	PUNCT
cet-15395	32	47	atomic	atomic	ADJ
cet-15395	32	48	balance	balance	NOUN
cet-15395	32	49	)	)	PUNCT
cet-15395	32	50	(	(	PUNCT
cet-15395	32	51	2	2	NUM
cet-15395	32	52	)	)	PUNCT
cet-15395	32	53	−∆𝐻𝑅	−∆𝐻𝑅	ADV
cet-15395	32	54	global	global	ADJ
cet-15395	32	55	≥	≥	NOUN
cet-15395	32	56	given	give	VERB
cet-15395	32	57	value	value	NOUN
cet-15395	32	58	≥	≥	NOUN
cet-15395	32	59	0	0	NUM
cet-15395	32	60	(	(	PUNCT
cet-15395	32	61	3	3	NUM
cet-15395	32	62	)	)	PUNCT
cet-15395	32	63	𝑛𝑖	𝑛𝑖	PROPN
cet-15395	32	64	≥	≥	PROPN
cet-15395	32	65	0	0	NUM
cet-15395	32	66	(	(	PUNCT
cet-15395	32	67	4	4	NUM
cet-15395	32	68	)	)	PUNCT
cet-15395	33	1	where	where	SCONJ
cet-15395	33	2	:	:	PUNCT
cet-15395	33	3	∆𝐻𝑅	∆𝐻𝑅	SYM
cet-15395	33	4	global	global	ADJ
cet-15395	33	5	𝑇0,𝑃0	𝑇0,𝑃0	NOUN
cet-15395	33	6	=	=	SYM
cet-15395	33	7	𝑛𝑖	𝑛𝑖	PROPN
cet-15395	33	8	products	product	VERB
cet-15395	33	9	∙	∙	PROPN
cet-15395	33	10	ℎ	ℎ	X
cet-15395	33	11	𝑖(𝑇0,𝑃0	𝑖(𝑇0,𝑃0	ADJ
cet-15395	33	12	)	)	PUNCT
cet-15395	33	13	𝑁𝑝	𝑁𝑝	VERB
cet-15395	33	14	𝑖=1	𝑖=1	PROPN
cet-15395	33	15	−	−	PROPN
cet-15395	33	16	𝑛𝑖	𝑛𝑖	PROPN
cet-15395	33	17	reactants	reactant	VERB
cet-15395	33	18	∙	∙	PROPN
cet-15395	33	19	ℎ	ℎ	X
cet-15395	33	20	𝑖(𝑇0,𝑃0	𝑖(𝑇0,𝑃0	ADJ
cet-15395	33	21	)	)	PUNCT
cet-15395	33	22	𝑁𝑟	𝑁𝑟	PROPN
cet-15395	33	23	𝑖=1	𝑖=1	PROPN
cet-15395	33	24	(	(	PUNCT
cet-15395	33	25	5	5	NUM
cet-15395	33	26	)	)	PUNCT
cet-15395	33	27	and	and	CCONJ
cet-15395	33	28	where	where	SCONJ
cet-15395	33	29	the	the	DET
cet-15395	33	30	decision	decision	NOUN
cet-15395	33	31	variables	variable	NOUN
cet-15395	33	32	are	be	AUX
cet-15395	33	33	𝑛𝑖	𝑛𝑖	VERB
cet-15395	33	34	:	:	PUNCT
cet-15395	33	35	if	if	SCONJ
cet-15395	33	36	𝑛𝑖	𝑛𝑖	PROPN
cet-15395	33	37	>	>	X
cet-15395	33	38	0	0	PUNCT
cet-15395	34	1	the	the	DET
cet-15395	34	2	substance	substance	NOUN
cet-15395	34	3	exists	exist	VERB
cet-15395	34	4	in	in	ADP
cet-15395	34	5	the	the	DET
cet-15395	34	6	global	global	ADJ
cet-15395	34	7	mass	mass	PROPN
cet-15395	34	8	balance	balance	NOUN
cet-15395	34	9	,	,	PUNCT
cet-15395	34	10	while	while	SCONJ
cet-15395	34	11	if	if	SCONJ
cet-15395	34	12	𝑛𝑖	𝑛𝑖	PROPN
cet-15395	34	13	=	=	X
cet-15395	34	14	0	0	PROPN
cet-15395	35	1	the	the	DET
cet-15395	35	2	substance	substance	NOUN
cet-15395	35	3	is	be	AUX
cet-15395	35	4	not	not	PART
cet-15395	35	5	present	present	ADJ
cet-15395	35	6	in	in	ADP
cet-15395	35	7	the	the	DET
cet-15395	35	8	global	global	ADJ
cet-15395	35	9	balance	balance	NOUN
cet-15395	35	10	(	(	PUNCT
cet-15395	35	11	it	it	PRON
cet-15395	35	12	may	may	AUX
cet-15395	35	13	only	only	ADV
cet-15395	35	14	exist	exist	VERB
cet-15395	35	15	as	as	ADP
cet-15395	35	16	an	an	DET
cet-15395	35	17	intermediate	intermediate	ADJ
cet-15395	35	18	)	)	PUNCT
cet-15395	35	19	.	.	PUNCT
cet-15395	36	1	one	one	NUM
cet-15395	36	2	critical	critical	ADJ
cet-15395	36	3	step	step	NOUN
cet-15395	36	4	is	be	AUX
cet-15395	36	5	the	the	DET
cet-15395	36	6	definition	definition	NOUN
cet-15395	36	7	of	of	ADP
cet-15395	36	8	the	the	DET
cet-15395	36	9	set	set	NOUN
cet-15395	36	10	𝑖	𝑖	SYM
cet-15395	36	11	∈	∈	PROPN
cet-15395	36	12	{	{	PUNCT
cet-15395	36	13	list	list	NOUN
cet-15395	36	14	of	of	ADP
cet-15395	36	15	possible	possible	ADJ
cet-15395	36	16	substances	substance	NOUN
cet-15395	36	17	}	}	PUNCT
cet-15395	36	18	.	.	PUNCT
cet-15395	37	1	once	once	ADV
cet-15395	37	2	the	the	DET
cet-15395	37	3	raw	raw	ADJ
cet-15395	37	4	materials	material	NOUN
cet-15395	37	5	and	and	CCONJ
cet-15395	37	6	products	product	NOUN
cet-15395	37	7	have	have	AUX
cet-15395	37	8	been	be	AUX
cet-15395	37	9	determined	determine	VERB
cet-15395	37	10	,	,	PUNCT
cet-15395	37	11	a	a	DET
cet-15395	37	12	viable	viable	ADJ
cet-15395	37	13	reaction	reaction	NOUN
cet-15395	37	14	route	route	NOUN
cet-15395	37	15	must	must	AUX
cet-15395	37	16	be	be	AUX
cet-15395	37	17	found	find	VERB
cet-15395	37	18	to	to	PART
cet-15395	37	19	obtain	obtain	VERB
cet-15395	37	20	the	the	DET
cet-15395	37	21	desired	desire	VERB
cet-15395	37	22	products	product	NOUN
cet-15395	37	23	from	from	ADP
cet-15395	37	24	the	the	DET
cet-15395	37	25	raw	raw	ADJ
cet-15395	37	26	materials	material	NOUN
cet-15395	37	27	.	.	PUNCT
cet-15395	38	1	this	this	DET
cet-15395	38	2	step	step	NOUN
cet-15395	38	3	involves	involve	VERB
cet-15395	38	4	an	an	DET
cet-15395	38	5	analysis	analysis	NOUN
cet-15395	38	6	of	of	ADP
cet-15395	38	7	the	the	DET
cet-15395	38	8	gibbs	gibbs	PROPN
cet-15395	38	9	energy	energy	NOUN
cet-15395	38	10	of	of	ADP
cet-15395	38	11	each	each	DET
cet-15395	38	12	intermediate	intermediate	ADJ
cet-15395	38	13	reaction	reaction	NOUN
cet-15395	38	14	involved	involve	VERB
cet-15395	38	15	,	,	PUNCT
cet-15395	38	16	so	so	SCONJ
cet-15395	38	17	that	that	SCONJ
cet-15395	38	18	each	each	DET
cet-15395	38	19	reaction	reaction	NOUN
cet-15395	38	20	has	have	VERB
cet-15395	38	21	a	a	DET
cet-15395	38	22	favourable	favourable	ADJ
cet-15395	38	23	equilibrium	equilibrium	NOUN
cet-15395	38	24	at	at	ADP
cet-15395	38	25	the	the	DET
cet-15395	38	26	temperature	temperature	NOUN
cet-15395	38	27	,	,	PUNCT
cet-15395	38	28	pressure	pressure	NOUN
cet-15395	38	29	and	and	CCONJ
cet-15395	38	30	composition	composition	NOUN
cet-15395	38	31	of	of	ADP
cet-15395	38	32	each	each	DET
cet-15395	38	33	reaction	reaction	NOUN
cet-15395	38	34	step	step	NOUN
cet-15395	38	35	in	in	ADP
cet-15395	38	36	real	real	ADJ
cet-15395	38	37	operating	operating	NOUN
cet-15395	38	38	conditions	condition	NOUN
cet-15395	38	39	(	(	PUNCT
cet-15395	38	40	since	since	SCONJ
cet-15395	38	41	intermediate	intermediate	ADJ
cet-15395	38	42	steps	step	NOUN
cet-15395	38	43	may	may	AUX
cet-15395	38	44	use	use	VERB
cet-15395	38	45	different	different	ADJ
cet-15395	38	46	temperatures	temperature	NOUN
cet-15395	38	47	and	and	CCONJ
cet-15395	38	48	pressures	pressure	NOUN
cet-15395	38	49	than	than	ADP
cet-15395	38	50	the	the	DET
cet-15395	38	51	reference	reference	NOUN
cet-15395	38	52	conditions	condition	NOUN
cet-15395	38	53	)	)	PUNCT
cet-15395	38	54	.	.	PUNCT
cet-15395	39	1	this	this	DET
cet-15395	39	2	stage	stage	NOUN
cet-15395	39	3	of	of	ADP
cet-15395	39	4	the	the	DET
cet-15395	39	5	project	project	NOUN
cet-15395	39	6	can	can	AUX
cet-15395	39	7	then	then	ADV
cet-15395	39	8	be	be	AUX
cet-15395	39	9	carried	carry	VERB
cet-15395	39	10	out	out	ADP
cet-15395	39	11	using	use	VERB
cet-15395	39	12	a	a	DET
cet-15395	39	13	commercial	commercial	ADJ
cet-15395	39	14	software	software	NOUN
cet-15395	39	15	,	,	PUNCT
cet-15395	39	16	such	such	ADJ
cet-15395	39	17	as	as	ADP
cet-15395	39	18	aspen	aspen	NOUN
cet-15395	39	19	,	,	PUNCT
cet-15395	39	20	to	to	PART
cet-15395	39	21	simulate	simulate	VERB
cet-15395	39	22	the	the	DET
cet-15395	39	23	entire	entire	ADJ
cet-15395	39	24	process	process	NOUN
cet-15395	39	25	with	with	ADP
cet-15395	39	26	the	the	DET
cet-15395	39	27	routes	route	NOUN
cet-15395	39	28	considered	consider	VERB
cet-15395	39	29	.	.	PUNCT
cet-15395	40	1	3	3	X
cet-15395	40	2	.	.	X
cet-15395	40	3	case	case	NOUN
cet-15395	40	4	study	study	NOUN
cet-15395	40	5	global	global	ADJ
cet-15395	40	6	route	route	NOUN
cet-15395	40	7	this	this	PRON
cet-15395	40	8	is	be	AUX
cet-15395	40	9	just	just	ADV
cet-15395	40	10	an	an	DET
cet-15395	40	11	illustrative	illustrative	ADJ
cet-15395	40	12	example	example	NOUN
cet-15395	40	13	,	,	PUNCT
cet-15395	40	14	since	since	SCONJ
cet-15395	40	15	the	the	DET
cet-15395	40	16	proposed	propose	VERB
cet-15395	40	17	methodology	methodology	NOUN
cet-15395	40	18	is	be	AUX
cet-15395	40	19	general	general	ADJ
cet-15395	40	20	.	.	PUNCT
cet-15395	41	1	the	the	DET
cet-15395	41	2	following	follow	VERB
cet-15395	41	3	conditions	condition	NOUN
cet-15395	41	4	were	be	AUX
cet-15395	41	5	considered	consider	VERB
cet-15395	41	6	:	:	PUNCT
cet-15395	41	7	potential	potential	ADJ
cet-15395	41	8	raw	raw	ADJ
cet-15395	41	9	materials	material	NOUN
cet-15395	41	10	:	:	PUNCT
cet-15395	41	11	ch4	ch4	NOUN
cet-15395	41	12	,	,	PUNCT
cet-15395	41	13	o2	o2	PROPN
cet-15395	41	14	,	,	PUNCT
cet-15395	41	15	n2	n2	NOUN
cet-15395	41	16	,	,	PUNCT
cet-15395	41	17	h2o	h2o	ADJ
cet-15395	41	18	potential	potential	ADJ
cet-15395	41	19	products	product	NOUN
cet-15395	41	20	:	:	PUNCT
cet-15395	41	21	(	(	PUNCT
cet-15395	41	22	nh2)2co	nh2)2co	INTJ
cet-15395	41	23	(	(	PUNCT
cet-15395	41	24	urea	urea	NOUN
cet-15395	41	25	)	)	PUNCT
cet-15395	41	26	,	,	PUNCT
cet-15395	41	27	c2h4	c2h4	X
cet-15395	41	28	(	(	PUNCT
cet-15395	41	29	ethylene	ethylene	NOUN
cet-15395	41	30	)	)	PUNCT
cet-15395	41	31	,	,	PUNCT
cet-15395	41	32	c6h6	c6h6	NOUN
cet-15395	41	33	(	(	PUNCT
cet-15395	41	34	benzene	benzene	NOUN
cet-15395	41	35	)	)	PUNCT
cet-15395	41	36	,	,	PUNCT
cet-15395	41	37	h2o	h2o	PROPN
cet-15395	41	38	,	,	PUNCT
cet-15395	41	39	h2	h2	NOUN
cet-15395	41	40	note	note	VERB
cet-15395	41	41	that	that	SCONJ
cet-15395	41	42	in	in	ADP
cet-15395	41	43	this	this	DET
cet-15395	41	44	step	step	NOUN
cet-15395	41	45	water	water	NOUN
cet-15395	41	46	can	can	AUX
cet-15395	41	47	be	be	AUX
cet-15395	41	48	either	either	CCONJ
cet-15395	41	49	a	a	DET
cet-15395	41	50	raw	raw	ADJ
cet-15395	41	51	material	material	NOUN
cet-15395	41	52	or	or	CCONJ
cet-15395	41	53	a	a	DET
cet-15395	41	54	product	product	NOUN
cet-15395	41	55	,	,	PUNCT
cet-15395	41	56	it	it	PRON
cet-15395	41	57	is	be	AUX
cet-15395	41	58	not	not	PART
cet-15395	41	59	yet	yet	ADV
cet-15395	41	60	known	know	VERB
cet-15395	41	61	.	.	PUNCT
cet-15395	42	1	calculation	calculation	NOUN
cet-15395	42	2	basis	basis	NOUN
cet-15395	42	3	:	:	PUNCT
cet-15395	42	4	100	100	NUM
cet-15395	42	5	mol	mol	ADP
cet-15395	42	6	ch4	ch4	NOUN
cet-15395	42	7	reference	reference	NOUN
cet-15395	42	8	conditions	condition	NOUN
cet-15395	42	9	for	for	ADP
cet-15395	42	10	the	the	DET
cet-15395	42	11	beginning	beginning	NOUN
cet-15395	42	12	and	and	CCONJ
cet-15395	42	13	end	end	NOUN
cet-15395	42	14	of	of	ADP
cet-15395	42	15	the	the	DET
cet-15395	42	16	overall	overall	ADJ
cet-15395	42	17	process	process	NOUN
cet-15395	42	18	:	:	PUNCT
cet-15395	42	19	25	25	NUM
cet-15395	42	20	ºc	ºc	NOUN
cet-15395	42	21	and	and	CCONJ
cet-15395	42	22	1	1	NUM
cet-15395	42	23	atm	atm	NOUN
cet-15395	42	24	.	.	PUNCT
cet-15395	43	1	the	the	DET
cet-15395	43	2	enthalpy	enthalpy	NOUN
cet-15395	43	3	of	of	ADP
cet-15395	43	4	formation	formation	NOUN
cet-15395	43	5	data	datum	NOUN
cet-15395	43	6	were	be	AUX
cet-15395	43	7	obtained	obtain	VERB
cet-15395	43	8	from	from	ADP
cet-15395	43	9	the	the	DET
cet-15395	43	10	thermodynamics	thermodynamic	NOUN
cet-15395	43	11	literature	literature	NOUN
cet-15395	43	12	(	(	PUNCT
cet-15395	43	13	reid	reid	PROPN
cet-15395	43	14	et	et	PROPN
cet-15395	43	15	al	al	PROPN
cet-15395	43	16	,	,	PUNCT
cet-15395	43	17	1987	1987	NUM
cet-15395	43	18	)	)	PUNCT
cet-15395	43	19	.	.	PUNCT
cet-15395	44	1	the	the	DET
cet-15395	44	2	calculations	calculation	NOUN
cet-15395	44	3	were	be	AUX
cet-15395	44	4	performed	perform	VERB
cet-15395	44	5	with	with	ADP
cet-15395	44	6	an	an	DET
cet-15395	44	7	excel	excel	NOUN
cet-15395	44	8	spreadsheet	spreadsheet	NOUN
cet-15395	44	9	,	,	PUNCT
cet-15395	44	10	using	use	VERB
cet-15395	44	11	solver	solver	ADV
cet-15395	44	12	to	to	PART
cet-15395	44	13	find	find	VERB
cet-15395	44	14	the	the	DET
cet-15395	44	15	solution	solution	NOUN
cet-15395	44	16	of	of	ADP
cet-15395	44	17	the	the	DET
cet-15395	44	18	lp	lp	PROPN
cet-15395	44	19	model	model	NOUN
cet-15395	44	20	.	.	PUNCT
cet-15395	45	1	using	use	VERB
cet-15395	45	2	this	this	DET
cet-15395	45	3	small	small	ADJ
cet-15395	45	4	list	list	NOUN
cet-15395	45	5	of	of	ADP
cet-15395	45	6	substances	substance	NOUN
cet-15395	45	7	,	,	PUNCT
cet-15395	45	8	the	the	DET
cet-15395	45	9	substance	substance	NOUN
cet-15395	45	10	that	that	PRON
cet-15395	45	11	leads	lead	VERB
cet-15395	45	12	to	to	ADP
cet-15395	45	13	more	more	ADJ
cet-15395	45	14	hydrogen	hydrogen	NOUN
cet-15395	45	15	is	be	AUX
cet-15395	45	16	benzene	benzene	NOUN
cet-15395	45	17	(	(	PUNCT
cet-15395	45	18	burning	burn	VERB
cet-15395	45	19	part	part	NOUN
cet-15395	45	20	of	of	ADP
cet-15395	45	21	the	the	DET
cet-15395	45	22	hydrogen	hydrogen	NOUN
cet-15395	45	23	for	for	ADP
cet-15395	45	24	∆𝐻global	∆𝐻global	PROPN
cet-15395	45	25	>	>	X
cet-15395	45	26	0	0	NUM
cet-15395	45	27	)	)	PUNCT
cet-15395	45	28	,	,	PUNCT
cet-15395	45	29	but	but	CCONJ
cet-15395	45	30	the	the	DET
cet-15395	45	31	difference	difference	NOUN
cet-15395	45	32	with	with	ADP
cet-15395	45	33	urea	urea	NOUN
cet-15395	45	34	is	be	AUX
cet-15395	45	35	small	small	ADJ
cet-15395	45	36	.	.	PUNCT
cet-15395	46	1	also	also	ADV
cet-15395	46	2	,	,	PUNCT
cet-15395	46	3	urea	urea	PROPN
cet-15395	46	4	is	be	AUX
cet-15395	46	5	useful	useful	ADJ
cet-15395	46	6	as	as	ADP
cet-15395	46	7	a	a	DET
cet-15395	46	8	fertilizer	fertilizer	NOUN
cet-15395	46	9	.	.	PUNCT
cet-15395	47	1	therefore	therefore	ADV
cet-15395	47	2	,	,	PUNCT
cet-15395	47	3	this	this	DET
cet-15395	47	4	case	case	NOUN
cet-15395	47	5	study	study	NOUN
cet-15395	47	6	was	be	AUX
cet-15395	47	7	set	set	VERB
cet-15395	47	8	to	to	ADP
cet-15395	47	9	the	the	DET
cet-15395	47	10	production	production	NOUN
cet-15395	47	11	of	of	ADP
cet-15395	47	12	urea	urea	NOUN
cet-15395	47	13	.	.	PUNCT
cet-15395	48	1	the	the	DET
cet-15395	48	2	raw	raw	ADJ
cet-15395	48	3	materials	material	NOUN
cet-15395	48	4	were	be	AUX
cet-15395	48	5	ch4	ch4	NOUN
cet-15395	48	6	,	,	PUNCT
cet-15395	48	7	n2	n2	NOUN
cet-15395	48	8	and	and	CCONJ
cet-15395	48	9	h2o	h2o	NOUN
cet-15395	48	10	,	,	PUNCT
cet-15395	48	11	while	while	SCONJ
cet-15395	48	12	the	the	DET
cet-15395	48	13	products	product	NOUN
cet-15395	48	14	866	866	NUM
cet-15395	48	15	were	be	AUX
cet-15395	48	16	(	(	PUNCT
cet-15395	48	17	nh2)2co	nh2)2co	NOUN
cet-15395	48	18	and	and	CCONJ
cet-15395	48	19	h2	h2	NOUN
cet-15395	48	20	.	.	PUNCT
cet-15395	49	1	however	however	ADV
cet-15395	49	2	,	,	PUNCT
cet-15395	49	3	this	this	DET
cet-15395	49	4	step	step	NOUN
cet-15395	49	5	does	do	AUX
cet-15395	49	6	not	not	PART
cet-15395	49	7	provide	provide	VERB
cet-15395	49	8	the	the	DET
cet-15395	49	9	reaction	reaction	NOUN
cet-15395	49	10	routes	route	NOUN
cet-15395	49	11	from	from	ADP
cet-15395	49	12	the	the	DET
cet-15395	49	13	reactants	reactant	NOUN
cet-15395	49	14	to	to	ADP
cet-15395	49	15	the	the	DET
cet-15395	49	16	final	final	ADJ
cet-15395	49	17	products	product	NOUN
cet-15395	49	18	.	.	PUNCT
cet-15395	50	1	therefore	therefore	ADV
cet-15395	50	2	,	,	PUNCT
cet-15395	50	3	the	the	DET
cet-15395	50	4	next	next	ADJ
cet-15395	50	5	step	step	NOUN
cet-15395	50	6	is	be	AUX
cet-15395	50	7	finding	find	VERB
cet-15395	50	8	an	an	DET
cet-15395	50	9	adequate	adequate	ADJ
cet-15395	50	10	route	route	NOUN
cet-15395	50	11	,	,	PUNCT
cet-15395	50	12	which	which	PRON
cet-15395	50	13	in	in	ADP
cet-15395	50	14	this	this	DET
cet-15395	50	15	case	case	NOUN
cet-15395	50	16	is	be	AUX
cet-15395	50	17	well	well	ADV
cet-15395	50	18	known	know	VERB
cet-15395	50	19	(	(	PUNCT
cet-15395	50	20	figure	figure	NOUN
cet-15395	50	21	1	1	NUM
cet-15395	50	22	):	):	PUNCT
cet-15395	50	23	step1	step1	PROPN
cet-15395	50	24	:	:	PUNCT
cet-15395	51	1	ch4	ch4	PROPN
cet-15395	51	2	+	+	CCONJ
cet-15395	51	3	2	2	NUM
cet-15395	51	4	h2o	h2o	NOUN
cet-15395	51	5			NUM
cet-15395	51	6	co2	co2	VERB
cet-15395	51	7	+	+	CCONJ
cet-15395	51	8	4	4	NUM
cet-15395	51	9	h2	h2	NOUN
cet-15395	51	10	(	(	PUNCT
cet-15395	51	11	6	6	NUM
cet-15395	51	12	)	)	PUNCT
cet-15395	51	13	step2	step2	NOUN
cet-15395	51	14	:	:	PUNCT
cet-15395	51	15	n2	n2	NOUN
cet-15395	51	16	+	+	CCONJ
cet-15395	51	17	3	3	NUM
cet-15395	51	18	h2	h2	NOUN
cet-15395	51	19	2	2	NOUN
cet-15395	51	20	nh3	nh3	PROPN
cet-15395	51	21	(	(	PUNCT
cet-15395	51	22	7	7	X
cet-15395	51	23	)	)	PUNCT
cet-15395	51	24	step3	step3	NOUN
cet-15395	51	25	:	:	PUNCT
cet-15395	51	26	co2	co2	NOUN
cet-15395	51	27	+	+	CCONJ
cet-15395	51	28	2	2	NUM
cet-15395	51	29	nh3	nh3	NOUN
cet-15395	51	30			PROPN
cet-15395	51	31	co(nh2)2	co(nh2)2	VERB
cet-15395	51	32	+	+	CCONJ
cet-15395	52	1	h2o	h2o	PROPN
cet-15395	53	1	(	(	PUNCT
cet-15395	53	2	8)	8)	NUM
cet-15395	53	3	global	global	NOUN
cet-15395	53	4	:	:	PUNCT
cet-15395	53	5	ch4	ch4	PROPN
cet-15395	53	6	+	+	CCONJ
cet-15395	53	7	h2o	h2o	PROPN
cet-15395	53	8	+	+	CCONJ
cet-15395	53	9	n2	n2	ADJ
cet-15395	53	10			NUM
cet-15395	53	11	co(nh2)2	co(nh2)2	NOUN
cet-15395	53	12	+	+	X
cet-15395	53	13	h2	h2	NOUN
cet-15395	53	14	(	(	PUNCT
cet-15395	53	15	9	9	NUM
cet-15395	53	16	)	)	PUNCT
cet-15395	53	17	font	font	NOUN
cet-15395	53	18	:	:	PUNCT
cet-15395	53	19	developed	develop	VERB
cet-15395	53	20	by	by	ADP
cet-15395	53	21	the	the	DET
cet-15395	53	22	author	author	NOUN
cet-15395	53	23	figure	figure	NOUN
cet-15395	53	24	1	1	NUM
cet-15395	53	25	:	:	PUNCT
cet-15395	53	26	process	process	NOUN
cet-15395	53	27	flow	flow	NOUN
cet-15395	53	28	diagram	diagram	NOUN
cet-15395	53	29	then	then	ADV
cet-15395	53	30	,	,	PUNCT
cet-15395	53	31	after	after	ADP
cet-15395	53	32	choosing	choose	VERB
cet-15395	53	33	a	a	DET
cet-15395	53	34	route	route	NOUN
cet-15395	53	35	,	,	PUNCT
cet-15395	53	36	this	this	DET
cet-15395	53	37	study	study	NOUN
cet-15395	53	38	evaluates	evaluate	VERB
cet-15395	53	39	the	the	DET
cet-15395	53	40	reaction	reaction	NOUN
cet-15395	53	41	routes	route	NOUN
cet-15395	53	42	'	'	PART
cet-15395	53	43	thermodynamic	thermodynamic	ADJ
cet-15395	53	44	and	and	CCONJ
cet-15395	53	45	energetic	energetic	ADJ
cet-15395	53	46	feasibility	feasibility	NOUN
cet-15395	53	47	using	use	VERB
cet-15395	53	48	aspen	aspen	NOUN
cet-15395	53	49	plus	plus	CCONJ
cet-15395	53	50	simulations	simulation	NOUN
cet-15395	53	51	and	and	CCONJ
cet-15395	53	52	thermodynamic	thermodynamic	ADJ
cet-15395	53	53	analyses	analysis	NOUN
cet-15395	53	54	to	to	PART
cet-15395	53	55	optimize	optimize	VERB
cet-15395	53	56	operating	operating	NOUN
cet-15395	53	57	conditions	condition	NOUN
cet-15395	53	58	and	and	CCONJ
cet-15395	53	59	maximize	maximize	VERB
cet-15395	53	60	efficiency	efficiency	NOUN
cet-15395	53	61	.	.	PUNCT
cet-15395	54	1	simulations	simulation	NOUN
cet-15395	54	2	modelled	model	VERB
cet-15395	54	3	reaction	reaction	NOUN
cet-15395	54	4	conditions	condition	NOUN
cet-15395	54	5	and	and	CCONJ
cet-15395	54	6	calculated	calculate	VERB
cet-15395	54	7	mass	mass	ADJ
cet-15395	54	8	-	-	PUNCT
cet-15395	54	9	energy	energy	NOUN
cet-15395	54	10	balances	balance	NOUN
cet-15395	54	11	.	.	PUNCT
cet-15395	55	1	thermodynamic	thermodynamic	ADJ
cet-15395	55	2	analyses	analysis	NOUN
cet-15395	55	3	determined	determine	VERB
cet-15395	55	4	key	key	ADJ
cet-15395	55	5	quantities	quantity	NOUN
cet-15395	55	6	(	(	PUNCT
cet-15395	55	7	δh	δh	NOUN
cet-15395	55	8	,	,	PUNCT
cet-15395	55	9	δs	δs	NOUN
cet-15395	55	10	,	,	PUNCT
cet-15395	55	11	δg	δg	VERB
cet-15395	55	12	)	)	PUNCT
cet-15395	55	13	to	to	PART
cet-15395	55	14	assess	assess	VERB
cet-15395	55	15	reaction	reaction	NOUN
cet-15395	55	16	spontaneity	spontaneity	NOUN
cet-15395	55	17	and	and	CCONJ
cet-15395	55	18	favourable	favourable	ADJ
cet-15395	55	19	conditions	condition	NOUN
cet-15395	55	20	.	.	PUNCT
cet-15395	56	1	integrating	integrate	VERB
cet-15395	56	2	these	these	DET
cet-15395	56	3	results	result	NOUN
cet-15395	56	4	provides	provide	VERB
cet-15395	56	5	an	an	DET
cet-15395	56	6	approach	approach	NOUN
cet-15395	56	7	for	for	ADP
cet-15395	56	8	developing	develop	VERB
cet-15395	56	9	efficient	efficient	ADJ
cet-15395	56	10	,	,	PUNCT
cet-15395	56	11	sustainable	sustainable	ADJ
cet-15395	56	12	processes	process	NOUN
cet-15395	56	13	.	.	PUNCT
cet-15395	57	1	4	4	X
cet-15395	57	2	.	.	X
cet-15395	57	3	case	case	NOUN
cet-15395	57	4	studies	study	NOUN
cet-15395	57	5	routes	route	NOUN
cet-15395	57	6	of	of	ADP
cet-15395	57	7	reactions	reaction	NOUN
cet-15395	57	8	4.1	4.1	NUM
cet-15395	57	9	.	.	PUNCT
cet-15395	58	1	methane	methane	NOUN
cet-15395	58	2	and	and	CCONJ
cet-15395	58	3	oxygen	oxygen	NOUN
cet-15395	58	4	reaction	reaction	NOUN
cet-15395	58	5	this	this	DET
cet-15395	58	6	case	case	NOUN
cet-15395	58	7	study	study	NOUN
cet-15395	58	8	analyzes	analyze	VERB
cet-15395	58	9	the	the	DET
cet-15395	58	10	chemical	chemical	NOUN
cet-15395	58	11	reaction	reaction	NOUN
cet-15395	58	12	between	between	ADP
cet-15395	58	13	methane	methane	NOUN
cet-15395	58	14	(	(	PUNCT
cet-15395	58	15	ch4	ch4	NOUN
cet-15395	58	16	)	)	PUNCT
cet-15395	58	17	and	and	CCONJ
cet-15395	58	18	oxygen	oxygen	NOUN
cet-15395	58	19	(	(	PUNCT
cet-15395	58	20	o2	o2	PROPN
cet-15395	58	21	)	)	PUNCT
cet-15395	58	22	,	,	PUNCT
cet-15395	58	23	with	with	ADP
cet-15395	58	24	the	the	DET
cet-15395	58	25	aim	aim	NOUN
cet-15395	58	26	of	of	ADP
cet-15395	58	27	evaluating	evaluate	VERB
cet-15395	58	28	the	the	DET
cet-15395	58	29	products	product	NOUN
cet-15395	58	30	formed	form	VERB
cet-15395	58	31	,	,	PUNCT
cet-15395	58	32	the	the	DET
cet-15395	58	33	energy	energy	NOUN
cet-15395	58	34	involved	involve	VERB
cet-15395	58	35	and	and	CCONJ
cet-15395	58	36	the	the	DET
cet-15395	58	37	associated	associated	ADJ
cet-15395	58	38	flows	flow	NOUN
cet-15395	58	39	.	.	PUNCT
cet-15395	59	1	the	the	DET
cet-15395	59	2	analysis	analysis	NOUN
cet-15395	59	3	was	be	AUX
cet-15395	59	4	carried	carry	VERB
cet-15395	59	5	out	out	ADP
cet-15395	59	6	using	use	VERB
cet-15395	59	7	aspen	aspen	PROPN
cet-15395	59	8	plus	plus	CCONJ
cet-15395	59	9	software	software	NOUN
cet-15395	59	10	.	.	PUNCT
cet-15395	60	1	the	the	DET
cet-15395	60	2	reaction	reaction	NOUN
cet-15395	60	3	between	between	ADP
cet-15395	60	4	methane	methane	NOUN
cet-15395	60	5	and	and	CCONJ
cet-15395	60	6	oxygen	oxygen	NOUN
cet-15395	60	7	can	can	AUX
cet-15395	60	8	take	take	VERB
cet-15395	60	9	place	place	NOUN
cet-15395	60	10	via	via	ADP
cet-15395	60	11	different	different	ADJ
cet-15395	60	12	chemical	chemical	NOUN
cet-15395	60	13	routes	route	NOUN
cet-15395	60	14	,	,	PUNCT
cet-15395	60	15	depending	depend	VERB
cet-15395	60	16	on	on	ADP
cet-15395	60	17	the	the	DET
cet-15395	60	18	conditions	condition	NOUN
cet-15395	60	19	of	of	ADP
cet-15395	60	20	temperature	temperature	NOUN
cet-15395	60	21	,	,	PUNCT
cet-15395	60	22	pressure	pressure	NOUN
cet-15395	60	23	and	and	CCONJ
cet-15395	60	24	the	the	DET
cet-15395	60	25	ratio	ratio	NOUN
cet-15395	60	26	between	between	ADP
cet-15395	60	27	the	the	DET
cet-15395	60	28	reactants	reactant	NOUN
cet-15395	60	29	.	.	PUNCT
cet-15395	61	1	these	these	DET
cet-15395	61	2	conditions	condition	NOUN
cet-15395	61	3	were	be	AUX
cet-15395	61	4	chosen	choose	VERB
cet-15395	61	5	to	to	PART
cet-15395	61	6	evaluate	evaluate	VERB
cet-15395	61	7	the	the	DET
cet-15395	61	8	behaviour	behaviour	NOUN
cet-15395	61	9	of	of	ADP
cet-15395	61	10	the	the	DET
cet-15395	61	11	different	different	ADJ
cet-15395	61	12	chemical	chemical	NOUN
cet-15395	61	13	routes	route	NOUN
cet-15395	61	14	,	,	PUNCT
cet-15395	61	15	providing	provide	VERB
cet-15395	61	16	a	a	DET
cet-15395	61	17	basis	basis	NOUN
cet-15395	61	18	for	for	ADP
cet-15395	61	19	future	future	ADJ
cet-15395	61	20	adjustments	adjustment	NOUN
cet-15395	61	21	.	.	PUNCT
cet-15395	62	1	the	the	DET
cet-15395	62	2	main	main	ADJ
cet-15395	62	3	reactions	reaction	NOUN
cet-15395	62	4	include	include	VERB
cet-15395	62	5	:	:	PUNCT
cet-15395	62	6	1	1	X
cet-15395	62	7	.	.	X
cet-15395	62	8	complete	complete	ADJ
cet-15395	62	9	combustion	combustion	NOUN
cet-15395	62	10	(	(	PUNCT
cet-15395	62	11	highly	highly	ADV
cet-15395	62	12	exothermic	exothermic	ADJ
cet-15395	62	13	):	):	PUNCT
cet-15395	62	14	ch4	ch4	NOUN
cet-15395	62	15	+	+	CCONJ
cet-15395	62	16	2	2	NUM
cet-15395	62	17	o2	o2	NOUN
cet-15395	62	18	→	→	SYM
cet-15395	62	19	co2	co2	NOUN
cet-15395	62	20	+	+	CCONJ
cet-15395	62	21	2	2	NUM
cet-15395	62	22	h2o	h2o	NOUN
cet-15395	62	23	(	(	PUNCT
cet-15395	62	24	10	10	NUM
cet-15395	62	25	)	)	PUNCT
cet-15395	62	26	2	2	NUM
cet-15395	62	27	.	.	PUNCT
cet-15395	62	28	incomplete	incomplete	ADJ
cet-15395	62	29	combustion	combustion	NOUN
cet-15395	62	30	(	(	PUNCT
cet-15395	62	31	exothermic	exothermic	NOUN
cet-15395	62	32	):	):	PUNCT
cet-15395	62	33	ch4	ch4	NOUN
cet-15395	62	34	+	+	CCONJ
cet-15395	62	35	3/2	3/2	NUM
cet-15395	62	36	o2	o2	PROPN
cet-15395	62	37	→	→	SYM
cet-15395	62	38	co	co	NOUN
cet-15395	62	39	+	+	PROPN
cet-15395	62	40	2	2	NUM
cet-15395	62	41	h2o	h2o	NOUN
cet-15395	62	42	(	(	PUNCT
cet-15395	62	43	11	11	NUM
cet-15395	62	44	)	)	SYM
cet-15395	62	45	3	3	NUM
cet-15395	62	46	.	.	PUNCT
cet-15395	62	47	partial	partial	ADJ
cet-15395	62	48	oxidation	oxidation	NOUN
cet-15395	62	49	reaction	reaction	NOUN
cet-15395	62	50	(	(	PUNCT
cet-15395	62	51	slightly	slightly	ADV
cet-15395	62	52	exothermic	exothermic	ADJ
cet-15395	62	53	):	):	PUNCT
cet-15395	62	54	ch4	ch4	NOUN
cet-15395	62	55	+	+	CCONJ
cet-15395	62	56	1/2	1/2	NUM
cet-15395	62	57	o2	o2	PROPN
cet-15395	62	58	→	→	SYM
cet-15395	62	59	co	co	NOUN
cet-15395	62	60	+	+	ADJ
cet-15395	62	61	2	2	NUM
cet-15395	62	62	h2	h2	NOUN
cet-15395	62	63	(	(	PUNCT
cet-15395	62	64	12	12	NUM
cet-15395	62	65	)	)	PUNCT
cet-15395	62	66	4	4	NUM
cet-15395	62	67	.	.	PUNCT
cet-15395	62	68	solid	solid	ADJ
cet-15395	62	69	carbon	carbon	NOUN
cet-15395	62	70	formation	formation	NOUN
cet-15395	62	71	(	(	PUNCT
cet-15395	62	72	if	if	SCONJ
cet-15395	62	73	oxygen	oxygen	NOUN
cet-15395	62	74	is	be	AUX
cet-15395	62	75	extremely	extremely	ADV
cet-15395	62	76	limited	limited	ADJ
cet-15395	62	77	,	,	PUNCT
cet-15395	62	78	endothermic	endothermic	NOUN
cet-15395	62	79	):	):	PUNCT
cet-15395	62	80	ch4	ch4	PROPN
cet-15395	62	81	→	→	SYM
cet-15395	62	82	c	c	PROPN
cet-15395	62	83	+	+	CCONJ
cet-15395	62	84	2	2	NUM
cet-15395	62	85	h2	h2	NOUN
cet-15395	62	86	(	(	PUNCT
cet-15395	62	87	13	13	NUM
cet-15395	62	88	)	)	PUNCT
cet-15395	62	89	867	867	NUM
cet-15395	62	90	the	the	DET
cet-15395	62	91	products	product	NOUN
cet-15395	62	92	depend	depend	VERB
cet-15395	62	93	on	on	ADP
cet-15395	62	94	the	the	DET
cet-15395	62	95	prevailing	prevailing	ADJ
cet-15395	62	96	thermodynamic	thermodynamic	ADJ
cet-15395	62	97	conditions	condition	NOUN
cet-15395	62	98	and	and	CCONJ
cet-15395	62	99	chemical	chemical	NOUN
cet-15395	62	100	routes	route	NOUN
cet-15395	62	101	,	,	PUNCT
cet-15395	62	102	which	which	PRON
cet-15395	62	103	are	be	AUX
cet-15395	62	104	:	:	PUNCT
cet-15395	62	105	carbon	carbon	NOUN
cet-15395	62	106	dioxide	dioxide	NOUN
cet-15395	62	107	(	(	PUNCT
cet-15395	62	108	co2	co2	NOUN
cet-15395	62	109	)	)	PUNCT
cet-15395	62	110	,	,	PUNCT
cet-15395	62	111	water	water	NOUN
cet-15395	62	112	(	(	PUNCT
cet-15395	62	113	h2o	h2o	PROPN
cet-15395	62	114	)	)	PUNCT
cet-15395	62	115	,	,	PUNCT
cet-15395	62	116	carbon	carbon	NOUN
cet-15395	62	117	monoxide	monoxide	NOUN
cet-15395	62	118	(	(	PUNCT
cet-15395	62	119	co	co	NOUN
cet-15395	62	120	)	)	PUNCT
cet-15395	62	121	,	,	PUNCT
cet-15395	62	122	hydrogen	hydrogen	NOUN
cet-15395	62	123	(	(	PUNCT
cet-15395	62	124	h2	h2	PROPN
cet-15395	62	125	)	)	PUNCT
cet-15395	62	126	,	,	PUNCT
cet-15395	62	127	solid	solid	ADJ
cet-15395	62	128	carbon	carbon	NOUN
cet-15395	62	129	(	(	PUNCT
cet-15395	62	130	c	c	NOUN
cet-15395	62	131	)	)	PUNCT
cet-15395	62	132	.	.	PUNCT
cet-15395	63	1	for	for	ADP
cet-15395	63	2	preliminary	preliminary	ADJ
cet-15395	63	3	analysis	analysis	NOUN
cet-15395	63	4	,	,	PUNCT
cet-15395	63	5	it	it	PRON
cet-15395	63	6	was	be	AUX
cet-15395	63	7	considered	consider	VERB
cet-15395	63	8	at	at	ADP
cet-15395	63	9	the	the	DET
cet-15395	63	10	feed	feed	NOUN
cet-15395	63	11	:	:	PUNCT
cet-15395	63	12	molar	molar	ADJ
cet-15395	63	13	ratio	ratio	NOUN
cet-15395	63	14	1	1	NUM
cet-15395	63	15	ch4	ch4	NOUN
cet-15395	63	16	:	:	PUNCT
cet-15395	63	17	2	2	NUM
cet-15395	63	18	o2	o2	PROPN
cet-15395	63	19	,	,	PUNCT
cet-15395	63	20	t	t	NOUN
cet-15395	63	21	=	=	SYM
cet-15395	63	22	25oc	25oc	NOUN
cet-15395	63	23	,	,	PUNCT
cet-15395	63	24	p	p	NOUN
cet-15395	63	25	=	=	SYM
cet-15395	63	26	1	1	NUM
cet-15395	63	27	atm	atm	NOUN
cet-15395	63	28	.	.	PROPN
cet-15395	64	1	4.2	4.2	NUM
cet-15395	64	2	.	.	PUNCT
cet-15395	65	1	methane	methane	NOUN
cet-15395	65	2	and	and	CCONJ
cet-15395	65	3	water	water	NOUN
cet-15395	65	4	reaction	reaction	NOUN
cet-15395	65	5	this	this	DET
cet-15395	65	6	case	case	NOUN
cet-15395	65	7	study	study	NOUN
cet-15395	65	8	analyzes	analyze	VERB
cet-15395	65	9	the	the	DET
cet-15395	65	10	interaction	interaction	NOUN
cet-15395	65	11	between	between	ADP
cet-15395	65	12	methane	methane	NOUN
cet-15395	65	13	(	(	PUNCT
cet-15395	65	14	ch4	ch4	NOUN
cet-15395	65	15	)	)	PUNCT
cet-15395	65	16	and	and	CCONJ
cet-15395	65	17	water	water	NOUN
cet-15395	65	18	(	(	PUNCT
cet-15395	65	19	h2o	h2o	PROPN
cet-15395	65	20	)	)	PUNCT
cet-15395	65	21	,	,	PUNCT
cet-15395	65	22	focusing	focus	VERB
cet-15395	65	23	on	on	ADP
cet-15395	65	24	the	the	DET
cet-15395	65	25	thermodynamic	thermodynamic	ADJ
cet-15395	65	26	analysis	analysis	NOUN
cet-15395	65	27	and	and	CCONJ
cet-15395	65	28	feasibility	feasibility	NOUN
cet-15395	65	29	of	of	ADP
cet-15395	65	30	the	the	DET
cet-15395	65	31	process	process	NOUN
cet-15395	65	32	.	.	PUNCT
cet-15395	66	1	the	the	DET
cet-15395	66	2	simulation	simulation	NOUN
cet-15395	66	3	,	,	PUNCT
cet-15395	66	4	carried	carry	VERB
cet-15395	66	5	out	out	ADP
cet-15395	66	6	in	in	ADP
cet-15395	66	7	the	the	DET
cet-15395	66	8	aspen	aspen	NOUN
cet-15395	66	9	plus	plus	CCONJ
cet-15395	66	10	software	software	NOUN
cet-15395	66	11	,	,	PUNCT
cet-15395	66	12	investigates	investigate	VERB
cet-15395	66	13	the	the	DET
cet-15395	66	14	energy	energy	NOUN
cet-15395	66	15	flows	flow	VERB
cet-15395	66	16	,	,	PUNCT
cet-15395	66	17	the	the	DET
cet-15395	66	18	molar	molar	ADJ
cet-15395	66	19	and	and	CCONJ
cet-15395	66	20	volumetric	volumetric	ADJ
cet-15395	66	21	fractions	fraction	NOUN
cet-15395	66	22	of	of	ADP
cet-15395	66	23	the	the	DET
cet-15395	66	24	products	product	NOUN
cet-15395	66	25	,	,	PUNCT
cet-15395	66	26	as	as	ADV
cet-15395	66	27	well	well	ADV
cet-15395	66	28	as	as	ADP
cet-15395	66	29	the	the	DET
cet-15395	66	30	overall	overall	ADJ
cet-15395	66	31	efficiency	efficiency	NOUN
cet-15395	66	32	of	of	ADP
cet-15395	66	33	the	the	DET
cet-15395	66	34	reactions	reaction	NOUN
cet-15395	66	35	,	,	PUNCT
cet-15395	66	36	allowing	allow	VERB
cet-15395	66	37	a	a	DET
cet-15395	66	38	detailed	detailed	ADJ
cet-15395	66	39	assessment	assessment	NOUN
cet-15395	66	40	of	of	ADP
cet-15395	66	41	the	the	DET
cet-15395	66	42	ideal	ideal	ADJ
cet-15395	66	43	conditions	condition	NOUN
cet-15395	66	44	for	for	ADP
cet-15395	66	45	industrial	industrial	ADJ
cet-15395	66	46	applications	application	NOUN
cet-15395	66	47	.	.	PUNCT
cet-15395	67	1	the	the	DET
cet-15395	67	2	reaction	reaction	NOUN
cet-15395	67	3	between	between	ADP
cet-15395	67	4	ch4	ch4	PROPN
cet-15395	67	5	and	and	CCONJ
cet-15395	67	6	h2o	h2o	PROPN
cet-15395	67	7	follows	follow	VERB
cet-15395	67	8	various	various	ADJ
cet-15395	67	9	chemical	chemical	NOUN
cet-15395	67	10	routes	route	NOUN
cet-15395	67	11	,	,	PUNCT
cet-15395	67	12	which	which	PRON
cet-15395	67	13	are	be	AUX
cet-15395	67	14	widely	widely	ADV
cet-15395	67	15	used	use	VERB
cet-15395	67	16	in	in	ADP
cet-15395	67	17	industrial	industrial	ADJ
cet-15395	67	18	processes	process	NOUN
cet-15395	67	19	,	,	PUNCT
cet-15395	67	20	such	such	ADJ
cet-15395	67	21	as	as	ADP
cet-15395	67	22	the	the	DET
cet-15395	67	23	production	production	NOUN
cet-15395	67	24	of	of	ADP
cet-15395	67	25	synthesis	synthesis	NOUN
cet-15395	67	26	gas	gas	NOUN
cet-15395	67	27	(	(	PUNCT
cet-15395	67	28	syngas	syngas	NOUN
cet-15395	67	29	)	)	PUNCT
cet-15395	67	30	and	and	CCONJ
cet-15395	67	31	hydrogen	hydrogen	NOUN
cet-15395	67	32	.	.	PUNCT
cet-15395	68	1	the	the	DET
cet-15395	68	2	products	product	NOUN
cet-15395	68	3	vary	vary	VERB
cet-15395	68	4	according	accord	VERB
cet-15395	68	5	to	to	ADP
cet-15395	68	6	the	the	DET
cet-15395	68	7	predominant	predominant	ADJ
cet-15395	68	8	chemical	chemical	NOUN
cet-15395	68	9	route	route	NOUN
cet-15395	68	10	and	and	CCONJ
cet-15395	68	11	thermodynamic	thermodynamic	ADJ
cet-15395	68	12	conditions	condition	NOUN
cet-15395	68	13	.	.	PUNCT
cet-15395	69	1	the	the	DET
cet-15395	69	2	main	main	ADJ
cet-15395	69	3	reactions	reaction	NOUN
cet-15395	69	4	include	include	VERB
cet-15395	69	5	:	:	PUNCT
cet-15395	69	6	1	1	X
cet-15395	69	7	.	.	X
cet-15395	69	8	methane	methane	NOUN
cet-15395	69	9	steam	steam	NOUN
cet-15395	69	10	reform	reform	NOUN
cet-15395	69	11	(	(	PUNCT
cet-15395	69	12	endothermic	endothermic	NOUN
cet-15395	69	13	):	):	PUNCT
cet-15395	69	14	ch4	ch4	NOUN
cet-15395	69	15	+	+	CCONJ
cet-15395	69	16	h2o	h2o	PROPN
cet-15395	69	17	→	→	SYM
cet-15395	69	18	co	co	NOUN
cet-15395	69	19	+	+	NOUN
cet-15395	69	20	3	3	NUM
cet-15395	69	21	h2	h2	NOUN
cet-15395	69	22	(	(	PUNCT
cet-15395	69	23	14	14	NUM
cet-15395	69	24	)	)	PUNCT
cet-15395	69	25	this	this	PRON
cet-15395	69	26	is	be	AUX
cet-15395	69	27	the	the	DET
cet-15395	69	28	main	main	ADJ
cet-15395	69	29	reaction	reaction	NOUN
cet-15395	69	30	in	in	ADP
cet-15395	69	31	industrial	industrial	ADJ
cet-15395	69	32	processes	process	NOUN
cet-15395	69	33	for	for	ADP
cet-15395	69	34	synthesis	synthesis	NOUN
cet-15395	69	35	gas	gas	NOUN
cet-15395	69	36	production	production	NOUN
cet-15395	69	37	(	(	PUNCT
cet-15395	69	38	mixture	mixture	NOUN
cet-15395	69	39	of	of	ADP
cet-15395	69	40	co	co	NOUN
cet-15395	69	41	and	and	CCONJ
cet-15395	69	42	h2	h2	PROPN
cet-15395	69	43	)	)	PUNCT
cet-15395	69	44	.	.	PUNCT
cet-15395	70	1	2	2	X
cet-15395	70	2	.	.	X
cet-15395	70	3	gas	gas	NOUN
cet-15395	70	4	-	-	PUNCT
cet-15395	70	5	water	water	NOUN
cet-15395	70	6	shift	shift	NOUN
cet-15395	70	7	reaction	reaction	NOUN
cet-15395	70	8	(	(	PUNCT
cet-15395	70	9	slightly	slightly	ADV
cet-15395	70	10	exothermic	exothermic	ADJ
cet-15395	70	11	):	):	PUNCT
cet-15395	70	12	co	co	X
cet-15395	70	13	+	+	ADJ
cet-15395	70	14	h2o	h2o	NOUN
cet-15395	70	15	→	→	PUNCT
cet-15395	70	16	co2	co2	NOUN
cet-15395	70	17	+	+	X
cet-15395	70	18	h2	h2	NOUN
cet-15395	70	19	(	(	PUNCT
cet-15395	70	20	15	15	NUM
cet-15395	70	21	)	)	PUNCT
cet-15395	70	22	3	3	NUM
cet-15395	70	23	.	.	PUNCT
cet-15395	70	24	solid	solid	ADJ
cet-15395	70	25	carbon	carbon	NOUN
cet-15395	70	26	formation	formation	NOUN
cet-15395	70	27	(	(	PUNCT
cet-15395	70	28	exothermic	exothermic	NOUN
cet-15395	70	29	):	):	PUNCT
cet-15395	70	30	2	2	NUM
cet-15395	70	31	co	co	NOUN
cet-15395	70	32	→	→	PROPN
cet-15395	70	33	c	c	PROPN
cet-15395	70	34	+	+	X
cet-15395	70	35	co2	co2	NOUN
cet-15395	70	36	(	(	PUNCT
cet-15395	70	37	16	16	NUM
cet-15395	70	38	)	)	PUNCT
cet-15395	70	39	the	the	DET
cet-15395	70	40	products	product	NOUN
cet-15395	70	41	depend	depend	VERB
cet-15395	70	42	on	on	ADP
cet-15395	70	43	the	the	DET
cet-15395	70	44	prevailing	prevailing	ADJ
cet-15395	70	45	thermodynamic	thermodynamic	ADJ
cet-15395	70	46	conditions	condition	NOUN
cet-15395	70	47	and	and	CCONJ
cet-15395	70	48	chemical	chemical	NOUN
cet-15395	70	49	routes	route	NOUN
cet-15395	70	50	,	,	PUNCT
cet-15395	70	51	which	which	PRON
cet-15395	70	52	are	be	AUX
cet-15395	70	53	:	:	PUNCT
cet-15395	70	54	hydrogen	hydrogen	NOUN
cet-15395	70	55	(	(	PUNCT
cet-15395	70	56	h2	h2	PROPN
cet-15395	70	57	)	)	PUNCT
cet-15395	70	58	,	,	PUNCT
cet-15395	70	59	carbon	carbon	NOUN
cet-15395	70	60	monoxide	monoxide	NOUN
cet-15395	70	61	(	(	PUNCT
cet-15395	70	62	co	co	NOUN
cet-15395	70	63	)	)	PUNCT
cet-15395	70	64	,	,	PUNCT
cet-15395	70	65	carbon	carbon	NOUN
cet-15395	70	66	dioxide	dioxide	NOUN
cet-15395	70	67	(	(	PUNCT
cet-15395	70	68	co2	co2	NOUN
cet-15395	70	69	)	)	PUNCT
cet-15395	70	70	,	,	PUNCT
cet-15395	70	71	water	water	NOUN
cet-15395	70	72	(	(	PUNCT
cet-15395	70	73	h2o	h2o	PROPN
cet-15395	70	74	)	)	PUNCT
cet-15395	70	75	and	and	CCONJ
cet-15395	70	76	solid	solid	ADJ
cet-15395	70	77	carbon	carbon	NOUN
cet-15395	70	78	(	(	PUNCT
cet-15395	70	79	c	c	NOUN
cet-15395	70	80	)	)	PUNCT
cet-15395	70	81	.	.	PUNCT
cet-15395	71	1	for	for	ADP
cet-15395	71	2	preliminary	preliminary	ADJ
cet-15395	71	3	analysis	analysis	NOUN
cet-15395	71	4	,	,	PUNCT
cet-15395	71	5	it	it	PRON
cet-15395	71	6	was	be	AUX
cet-15395	71	7	considered	consider	VERB
cet-15395	71	8	at	at	ADP
cet-15395	71	9	the	the	DET
cet-15395	71	10	feed	feed	NOUN
cet-15395	71	11	:	:	PUNCT
cet-15395	71	12	molar	molar	ADJ
cet-15395	71	13	fractions	fraction	NOUN
cet-15395	71	14	ych4	ych4	NOUN
cet-15395	71	15	=	=	SYM
cet-15395	71	16	0.5289	0.5289	NUM
cet-15395	71	17	and	and	CCONJ
cet-15395	71	18	yh2o	yh2o	PROPN
cet-15395	71	19	=	=	SYM
cet-15395	71	20	0.4710	0.4710	NUM
cet-15395	71	21	,	,	PUNCT
cet-15395	71	22	t	t	NOUN
cet-15395	71	23	=	=	SYM
cet-15395	71	24	25oc	25oc	NOUN
cet-15395	71	25	,	,	PUNCT
cet-15395	71	26	p	p	NOUN
cet-15395	71	27	=	=	SYM
cet-15395	71	28	1	1	NUM
cet-15395	71	29	atm	atm	NOUN
cet-15395	71	30	.	.	PUNCT
cet-15395	72	1	4.3	4.3	NUM
cet-15395	72	2	.	.	PUNCT
cet-15395	72	3	converting	convert	VERB
cet-15395	72	4	intermediate	intermediate	ADJ
cet-15395	72	5	products	product	NOUN
cet-15395	72	6	into	into	ADP
cet-15395	72	7	value	value	NOUN
cet-15395	72	8	added	add	VERB
cet-15395	72	9	products	product	NOUN
cet-15395	72	10	using	use	VERB
cet-15395	72	11	the	the	DET
cet-15395	72	12	results	result	NOUN
cet-15395	72	13	of	of	ADP
cet-15395	72	14	the	the	DET
cet-15395	72	15	previous	previous	ADJ
cet-15395	72	16	case	case	NOUN
cet-15395	72	17	studies	study	NOUN
cet-15395	72	18	,	,	PUNCT
cet-15395	72	19	which	which	PRON
cet-15395	72	20	demonstrate	demonstrate	VERB
cet-15395	72	21	the	the	DET
cet-15395	72	22	thermodynamic	thermodynamic	ADJ
cet-15395	72	23	feasibility	feasibility	NOUN
cet-15395	72	24	of	of	ADP
cet-15395	72	25	the	the	DET
cet-15395	72	26	reactions	reaction	NOUN
cet-15395	72	27	between	between	ADP
cet-15395	72	28	methane	methane	NOUN
cet-15395	72	29	and	and	CCONJ
cet-15395	72	30	oxygen	oxygen	NOUN
cet-15395	72	31	and	and	CCONJ
cet-15395	72	32	methane	methane	NOUN
cet-15395	72	33	and	and	CCONJ
cet-15395	72	34	water	water	NOUN
cet-15395	72	35	,	,	PUNCT
cet-15395	72	36	it	it	PRON
cet-15395	72	37	is	be	AUX
cet-15395	72	38	proposed	propose	VERB
cet-15395	72	39	a	a	DET
cet-15395	72	40	process	process	NOUN
cet-15395	72	41	to	to	PART
cet-15395	72	42	use	use	VERB
cet-15395	72	43	these	these	DET
cet-15395	72	44	reactions	reaction	NOUN
cet-15395	72	45	in	in	ADP
cet-15395	72	46	the	the	DET
cet-15395	72	47	production	production	NOUN
cet-15395	72	48	of	of	ADP
cet-15395	72	49	more	more	ADV
cet-15395	72	50	valued	value	VERB
cet-15395	72	51	products	product	NOUN
cet-15395	72	52	,	,	PUNCT
cet-15395	72	53	such	such	ADJ
cet-15395	72	54	as	as	ADP
cet-15395	72	55	urea	urea	NOUN
cet-15395	72	56	.	.	PUNCT
cet-15395	73	1	this	this	PRON
cet-15395	73	2	is	be	AUX
cet-15395	73	3	based	base	VERB
cet-15395	73	4	on	on	ADP
cet-15395	73	5	the	the	DET
cet-15395	73	6	proposed	propose	VERB
cet-15395	73	7	approach	approach	NOUN
cet-15395	73	8	of	of	ADP
cet-15395	73	9	focusing	focus	VERB
cet-15395	73	10	on	on	ADP
cet-15395	73	11	the	the	DET
cet-15395	73	12	synthesis	synthesis	NOUN
cet-15395	73	13	of	of	ADP
cet-15395	73	14	high	high	ADJ
cet-15395	73	15	value	value	NOUN
cet-15395	73	16	-	-	PUNCT
cet-15395	73	17	added	add	VERB
cet-15395	73	18	chemical	chemical	NOUN
cet-15395	73	19	compounds	compound	NOUN
cet-15395	73	20	,	,	PUNCT
cet-15395	73	21	integrating	integrate	VERB
cet-15395	73	22	sustainable	sustainable	ADJ
cet-15395	73	23	technologies	technology	NOUN
cet-15395	73	24	and	and	CCONJ
cet-15395	73	25	optimized	optimize	VERB
cet-15395	73	26	processes	process	NOUN
cet-15395	73	27	.	.	PUNCT
cet-15395	74	1	in	in	ADP
cet-15395	74	2	the	the	DET
cet-15395	74	3	case	case	NOUN
cet-15395	74	4	of	of	ADP
cet-15395	74	5	urea	urea	NOUN
cet-15395	74	6	,	,	PUNCT
cet-15395	74	7	it	it	PRON
cet-15395	74	8	can	can	AUX
cet-15395	74	9	be	be	AUX
cet-15395	74	10	obtained	obtain	VERB
cet-15395	74	11	from	from	ADP
cet-15395	74	12	the	the	DET
cet-15395	74	13	reaction	reaction	NOUN
cet-15395	74	14	between	between	ADP
cet-15395	74	15	ammonia	ammonia	NOUN
cet-15395	74	16	(	(	PUNCT
cet-15395	74	17	nh3	nh3	NOUN
cet-15395	74	18	)	)	PUNCT
cet-15395	74	19	and	and	CCONJ
cet-15395	74	20	carbon	carbon	NOUN
cet-15395	74	21	dioxide	dioxide	NOUN
cet-15395	74	22	(	(	PUNCT
cet-15395	74	23	co2	co2	NOUN
cet-15395	74	24	)	)	PUNCT
cet-15395	74	25	,	,	PUNCT
cet-15395	74	26	by	by	ADP
cet-15395	74	27	developing	develop	VERB
cet-15395	74	28	and	and	CCONJ
cet-15395	74	29	evaluating	evaluate	VERB
cet-15395	74	30	thermodynamically	thermodynamically	ADV
cet-15395	74	31	viable	viable	ADJ
cet-15395	74	32	and	and	CCONJ
cet-15395	74	33	economically	economically	ADV
cet-15395	74	34	attractive	attractive	ADJ
cet-15395	74	35	routes	route	NOUN
cet-15395	74	36	.	.	PUNCT
cet-15395	75	1	for	for	ADP
cet-15395	75	2	example	example	NOUN
cet-15395	75	3	,	,	PUNCT
cet-15395	75	4	integrating	integrate	VERB
cet-15395	75	5	with	with	ADP
cet-15395	75	6	methane	methane	NOUN
cet-15395	75	7	reforming	reforming	NOUN
cet-15395	75	8	,	,	PUNCT
cet-15395	75	9	using	use	VERB
cet-15395	75	10	the	the	DET
cet-15395	75	11	hydrogen	hydrogen	NOUN
cet-15395	75	12	(	(	PUNCT
cet-15395	75	13	h2	h2	NOUN
cet-15395	75	14	)	)	PUNCT
cet-15395	75	15	produced	produce	VERB
cet-15395	75	16	in	in	ADP
cet-15395	75	17	steam	steam	NOUN
cet-15395	75	18	reforming	reform	VERB
cet-15395	75	19	as	as	ADP
cet-15395	75	20	raw	raw	ADJ
cet-15395	75	21	material	material	NOUN
cet-15395	75	22	for	for	ADP
cet-15395	75	23	the	the	DET
cet-15395	75	24	synthesis	synthesis	NOUN
cet-15395	75	25	of	of	ADP
cet-15395	75	26	ammonia	ammonia	NOUN
cet-15395	75	27	(	(	PUNCT
cet-15395	75	28	nh3	nh3	NOUN
cet-15395	75	29	)	)	PUNCT
cet-15395	75	30	and	and	CCONJ
cet-15395	75	31	evaluating	evaluate	VERB
cet-15395	75	32	the	the	DET
cet-15395	75	33	energy	energy	NOUN
cet-15395	75	34	efficiency	efficiency	NOUN
cet-15395	75	35	of	of	ADP
cet-15395	75	36	the	the	DET
cet-15395	75	37	ammonia	ammonia	ADJ
cet-15395	75	38	synthesis	synthesis	NOUN
cet-15395	75	39	process	process	NOUN
cet-15395	75	40	considering	consider	VERB
cet-15395	75	41	the	the	DET
cet-15395	75	42	use	use	NOUN
cet-15395	75	43	of	of	ADP
cet-15395	75	44	nitrogen	nitrogen	NOUN
cet-15395	75	45	from	from	ADP
cet-15395	75	46	the	the	DET
cet-15395	75	47	air	air	NOUN
cet-15395	75	48	.	.	PUNCT
cet-15395	76	1	for	for	ADP
cet-15395	76	2	the	the	DET
cet-15395	76	3	conversion	conversion	NOUN
cet-15395	76	4	of	of	ADP
cet-15395	76	5	co2	co2	NOUN
cet-15395	76	6	and	and	CCONJ
cet-15395	76	7	nh3	nh3	NOUN
cet-15395	76	8	into	into	ADP
cet-15395	76	9	urea	urea	NOUN
cet-15395	76	10	,	,	PUNCT
cet-15395	76	11	the	the	DET
cet-15395	76	12	co2	co2	NOUN
cet-15395	76	13	captured	capture	VERB
cet-15395	76	14	in	in	ADP
cet-15395	76	15	the	the	DET
cet-15395	76	16	combustion	combustion	NOUN
cet-15395	76	17	and	and	CCONJ
cet-15395	76	18	the	the	DET
cet-15395	76	19	reforming	reforming	NOUN
cet-15395	76	20	can	can	AUX
cet-15395	76	21	be	be	AUX
cet-15395	76	22	used	use	VERB
cet-15395	76	23	to	to	PART
cet-15395	76	24	produce	produce	VERB
cet-15395	76	25	urea	urea	NOUN
cet-15395	76	26	(	(	PUNCT
cet-15395	76	27	nh2conh2	nh2conh2	NOUN
cet-15395	76	28	)	)	PUNCT
cet-15395	76	29	,	,	PUNCT
cet-15395	76	30	a	a	DET
cet-15395	76	31	product	product	NOUN
cet-15395	76	32	used	use	VERB
cet-15395	76	33	as	as	ADP
cet-15395	76	34	a	a	DET
cet-15395	76	35	fertilizer	fertilizer	NOUN
cet-15395	76	36	and	and	CCONJ
cet-15395	76	37	industrial	industrial	ADJ
cet-15395	76	38	additive	additive	NOUN
cet-15395	76	39	.	.	PUNCT
cet-15395	77	1	the	the	DET
cet-15395	77	2	final	final	ADJ
cet-15395	77	3	process	process	NOUN
cet-15395	77	4	will	will	AUX
cet-15395	77	5	be	be	AUX
cet-15395	77	6	found	find	VERB
cet-15395	77	7	by	by	ADP
cet-15395	77	8	carrying	carry	VERB
cet-15395	77	9	out	out	ADP
cet-15395	77	10	simulations	simulation	NOUN
cet-15395	77	11	to	to	PART
cet-15395	77	12	determine	determine	VERB
cet-15395	77	13	the	the	DET
cet-15395	77	14	optimal	optimal	ADJ
cet-15395	77	15	conditions	condition	NOUN
cet-15395	77	16	(	(	PUNCT
cet-15395	77	17	temperature	temperature	NOUN
cet-15395	77	18	,	,	PUNCT
cet-15395	77	19	pressure	pressure	NOUN
cet-15395	77	20	and	and	CCONJ
cet-15395	77	21	molar	molar	ADJ
cet-15395	77	22	ratios	ratio	NOUN
cet-15395	77	23	)	)	PUNCT
cet-15395	77	24	to	to	PART
cet-15395	77	25	maximize	maximize	VERB
cet-15395	77	26	the	the	DET
cet-15395	77	27	urea	urea	NOUN
cet-15395	77	28	yield	yield	NOUN
cet-15395	77	29	.	.	PUNCT
cet-15395	78	1	5	5	X
cet-15395	78	2	.	.	X
cet-15395	78	3	numerical	numerical	PROPN
cet-15395	78	4	results	result	NOUN
cet-15395	78	5	the	the	DET
cet-15395	78	6	thermodynamic	thermodynamic	ADJ
cet-15395	78	7	analysis	analysis	NOUN
cet-15395	78	8	of	of	ADP
cet-15395	78	9	global	global	ADJ
cet-15395	78	10	reaction	reaction	NOUN
cet-15395	78	11	routes	route	NOUN
cet-15395	78	12	plays	play	VERB
cet-15395	78	13	a	a	DET
cet-15395	78	14	fundamental	fundamental	ADJ
cet-15395	78	15	role	role	NOUN
cet-15395	78	16	in	in	ADP
cet-15395	78	17	the	the	DET
cet-15395	78	18	development	development	NOUN
cet-15395	78	19	of	of	ADP
cet-15395	78	20	sustainable	sustainable	ADJ
cet-15395	78	21	processes	process	NOUN
cet-15395	78	22	for	for	ADP
cet-15395	78	23	utilizing	utilize	VERB
cet-15395	78	24	methane	methane	NOUN
cet-15395	78	25	(	(	PUNCT
cet-15395	78	26	ch4	ch4	NOUN
cet-15395	78	27	)	)	PUNCT
cet-15395	78	28	without	without	ADP
cet-15395	78	29	emitting	emit	VERB
cet-15395	78	30	carbon	carbon	NOUN
cet-15395	78	31	dioxide	dioxide	NOUN
cet-15395	78	32	(	(	PUNCT
cet-15395	78	33	co2	co2	NOUN
cet-15395	78	34	)	)	PUNCT
cet-15395	78	35	.	.	PUNCT
cet-15395	79	1	this	this	DET
cet-15395	79	2	study	study	NOUN
cet-15395	79	3	is	be	AUX
cet-15395	79	4	especially	especially	ADV
cet-15395	79	5	relevant	relevant	ADJ
cet-15395	79	6	to	to	PART
cet-15395	79	7	overcome	overcome	VERB
cet-15395	79	8	the	the	DET
cet-15395	79	9	limitation	limitation	NOUN
cet-15395	79	10	of	of	ADP
cet-15395	79	11	many	many	ADJ
cet-15395	79	12	endothermic	endothermic	NOUN
cet-15395	79	13	processes	process	NOUN
cet-15395	79	14	,	,	PUNCT
cet-15395	79	15	which	which	PRON
cet-15395	79	16	consume	consume	VERB
cet-15395	79	17	energy	energy	NOUN
cet-15395	79	18	and	and	CCONJ
cet-15395	79	19	reduce	reduce	VERB
cet-15395	79	20	economic	economic	ADJ
cet-15395	79	21	and	and	CCONJ
cet-15395	79	22	environmental	environmental	ADJ
cet-15395	79	23	viability	viability	NOUN
cet-15395	79	24	.	.	PUNCT
cet-15395	80	1	this	this	DET
cet-15395	80	2	work	work	NOUN
cet-15395	80	3	focused	focus	VERB
cet-15395	80	4	on	on	ADP
cet-15395	80	5	evaluating	evaluate	VERB
cet-15395	80	6	different	different	ADJ
cet-15395	80	7	reaction	reaction	NOUN
cet-15395	80	8	routes	route	NOUN
cet-15395	80	9	for	for	ADP
cet-15395	80	10	the	the	DET
cet-15395	80	11	production	production	NOUN
cet-15395	80	12	of	of	ADP
cet-15395	80	13	urea	urea	NOUN
cet-15395	80	14	,	,	PUNCT
cet-15395	80	15	as	as	ADP
cet-15395	80	16	a	a	DET
cet-15395	80	17	case	case	NOUN
cet-15395	80	18	study	study	NOUN
cet-15395	80	19	,	,	PUNCT
cet-15395	80	20	avoiding	avoid	VERB
cet-15395	80	21	the	the	DET
cet-15395	80	22	emission	emission	NOUN
cet-15395	80	23	of	of	ADP
cet-15395	80	24	co2	co2	NOUN
cet-15395	80	25	,	,	PUNCT
cet-15395	80	26	with	with	ADP
cet-15395	80	27	a	a	DET
cet-15395	80	28	focus	focus	NOUN
cet-15395	80	29	on	on	ADP
cet-15395	80	30	identifying	identify	VERB
cet-15395	80	31	a	a	DET
cet-15395	80	32	global	global	ADJ
cet-15395	80	33	exothermic	exothermic	ADJ
cet-15395	80	34	process	process	NOUN
cet-15395	80	35	.	.	PUNCT
cet-15395	81	1	thermodynamics	thermodynamic	NOUN
cet-15395	81	2	was	be	AUX
cet-15395	81	3	considered	consider	VERB
cet-15395	81	4	by	by	ADP
cet-15395	81	5	calculating	calculate	VERB
cet-15395	81	6	the	the	DET
cet-15395	81	7	enthalpy	enthalpy	NOUN
cet-15395	81	8	variations	variation	NOUN
cet-15395	81	9	(	(	PUNCT
cet-15395	81	10	δh	δh	NOUN
cet-15395	81	11	)	)	PUNCT
cet-15395	81	12	and	and	CCONJ
cet-15395	81	13	gibbs	gibbs	PROPN
cet-15395	81	14	energy	energy	NOUN
cet-15395	81	15	(	(	PUNCT
cet-15395	81	16	δg	δg	PROPN
cet-15395	81	17	)	)	PUNCT
cet-15395	81	18	of	of	ADP
cet-15395	81	19	the	the	DET
cet-15395	81	20	reactions	reaction	NOUN
cet-15395	81	21	.	.	PUNCT
cet-15395	82	1	these	these	DET
cet-15395	82	2	analyses	analysis	NOUN
cet-15395	82	3	made	make	VERB
cet-15395	82	4	it	it	PRON
cet-15395	82	5	possible	possible	ADJ
cet-15395	82	6	to	to	PART
cet-15395	82	7	predict	predict	VERB
cet-15395	82	8	the	the	DET
cet-15395	82	9	spontaneity	spontaneity	NOUN
cet-15395	82	10	and	and	CCONJ
cet-15395	82	11	thermodynamic	thermodynamic	ADJ
cet-15395	82	12	feasibility	feasibility	NOUN
cet-15395	82	13	of	of	ADP
cet-15395	82	14	the	the	DET
cet-15395	82	15	processes	process	NOUN
cet-15395	82	16	studied	study	VERB
cet-15395	82	17	.	.	PUNCT
cet-15395	83	1	the	the	DET
cet-15395	83	2	initial	initial	ADJ
cet-15395	83	3	conditions	condition	NOUN
cet-15395	83	4	for	for	ADP
cet-15395	83	5	the	the	DET
cet-15395	83	6	reactants	reactant	NOUN
cet-15395	83	7	and	and	CCONJ
cet-15395	83	8	the	the	DET
cet-15395	83	9	final	final	ADJ
cet-15395	83	10	conditions	condition	NOUN
cet-15395	83	11	for	for	ADP
cet-15395	83	12	the	the	DET
cet-15395	83	13	products	product	NOUN
cet-15395	83	14	in	in	ADP
cet-15395	83	15	the	the	DET
cet-15395	83	16	global	global	ADJ
cet-15395	83	17	process	process	NOUN
cet-15395	83	18	were	be	AUX
cet-15395	83	19	considered	consider	VERB
cet-15395	83	20	at	at	ADP
cet-15395	83	21	the	the	DET
cet-15395	83	22	reference	reference	NOUN
cet-15395	83	23	state	state	NOUN
cet-15395	83	24	of	of	ADP
cet-15395	83	25	25	25	NUM
cet-15395	83	26	°	°	NOUN
cet-15395	83	27	c	c	NOUN
cet-15395	83	28	and	and	CCONJ
cet-15395	83	29	1	1	NUM
cet-15395	83	30	atm	atm	NOUN
cet-15395	83	31	.	.	PUNCT
cet-15395	84	1	in	in	ADP
cet-15395	84	2	order	order	NOUN
cet-15395	84	3	to	to	PART
cet-15395	84	4	achieve	achieve	VERB
cet-15395	84	5	the	the	DET
cet-15395	84	6	proposed	propose	VERB
cet-15395	84	7	objectives	objective	NOUN
cet-15395	84	8	,	,	PUNCT
cet-15395	84	9	the	the	DET
cet-15395	84	10	aspen	aspen	PROPN
cet-15395	84	11	software	software	NOUN
cet-15395	84	12	was	be	AUX
cet-15395	84	13	used	use	VERB
cet-15395	84	14	to	to	PART
cet-15395	84	15	carry	carry	VERB
cet-15395	84	16	out	out	ADP
cet-15395	84	17	graphical	graphical	ADJ
cet-15395	84	18	and	and	CCONJ
cet-15395	84	19	numerical	numerical	ADJ
cet-15395	84	20	simulations	simulation	NOUN
cet-15395	84	21	,	,	PUNCT
cet-15395	84	22	using	use	VERB
cet-15395	84	23	a	a	DET
cet-15395	84	24	conversion	conversion	NOUN
cet-15395	84	25	reactor	reactor	NOUN
cet-15395	84	26	.	.	PUNCT
cet-15395	85	1	the	the	DET
cet-15395	85	2	input	input	NOUN
cet-15395	85	3	data	datum	NOUN
cet-15395	85	4	,	,	PUNCT
cet-15395	85	5	which	which	PRON
cet-15395	85	6	included	include	VERB
cet-15395	85	7	ch4	ch4	NOUN
cet-15395	85	8	,	,	PUNCT
cet-15395	85	9	o2	o2	PROPN
cet-15395	85	10	,	,	PUNCT
cet-15395	85	11	and	and	CCONJ
cet-15395	85	12	specific	specific	ADJ
cet-15395	85	13	temperature	temperature	NOUN
cet-15395	85	14	and	and	CCONJ
cet-15395	85	15	pressure	pressure	NOUN
cet-15395	85	16	conditions	condition	NOUN
cet-15395	85	17	,	,	PUNCT
cet-15395	85	18	was	be	AUX
cet-15395	85	19	parameterized	parameterized	ADJ
cet-15395	85	20	to	to	PART
cet-15395	85	21	evaluate	evaluate	VERB
cet-15395	85	22	the	the	DET
cet-15395	85	23	thermodynamic	thermodynamic	ADJ
cet-15395	85	24	behaviour	behaviour	NOUN
cet-15395	85	25	of	of	ADP
cet-15395	85	26	different	different	ADJ
cet-15395	85	27	combinations	combination	NOUN
cet-15395	85	28	of	of	ADP
cet-15395	85	29	868	868	NUM
cet-15395	85	30	reactants	reactant	NOUN
cet-15395	85	31	and	and	CCONJ
cet-15395	85	32	products	product	NOUN
cet-15395	85	33	.	.	PUNCT
cet-15395	86	1	the	the	DET
cet-15395	86	2	simulations	simulation	NOUN
cet-15395	86	3	carried	carry	VERB
cet-15395	86	4	out	out	ADP
cet-15395	86	5	were	be	AUX
cet-15395	86	6	fundamental	fundamental	ADJ
cet-15395	86	7	in	in	ADP
cet-15395	86	8	determining	determine	VERB
cet-15395	86	9	global	global	ADJ
cet-15395	86	10	enthalpy	enthalpy	NOUN
cet-15395	86	11	variations	variation	NOUN
cet-15395	86	12	and	and	CCONJ
cet-15395	86	13	identifying	identify	VERB
cet-15395	86	14	potentially	potentially	ADV
cet-15395	86	15	favourable	favourable	ADJ
cet-15395	86	16	reaction	reaction	NOUN
cet-15395	86	17	routes	route	NOUN
cet-15395	86	18	.	.	PUNCT
cet-15395	87	1	the	the	DET
cet-15395	87	2	work	work	NOUN
cet-15395	87	3	also	also	ADV
cet-15395	87	4	considered	consider	VERB
cet-15395	87	5	the	the	DET
cet-15395	87	6	need	need	NOUN
cet-15395	87	7	for	for	SCONJ
cet-15395	87	8	the	the	DET
cet-15395	87	9	reactions	reaction	NOUN
cet-15395	87	10	to	to	PART
cet-15395	87	11	be	be	AUX
cet-15395	87	12	sufficiently	sufficiently	ADV
cet-15395	87	13	exothermic	exothermic	ADJ
cet-15395	87	14	to	to	PART
cet-15395	87	15	compensate	compensate	VERB
cet-15395	87	16	for	for	ADP
cet-15395	87	17	losses	loss	NOUN
cet-15395	87	18	in	in	ADP
cet-15395	87	19	the	the	DET
cet-15395	87	20	process	process	NOUN
cet-15395	87	21	,	,	PUNCT
cet-15395	87	22	ensuring	ensure	VERB
cet-15395	87	23	greater	great	ADJ
cet-15395	87	24	efficiency	efficiency	NOUN
cet-15395	87	25	and	and	CCONJ
cet-15395	87	26	sustainability	sustainability	NOUN
cet-15395	87	27	.	.	PUNCT
cet-15395	88	1	the	the	DET
cet-15395	88	2	results	result	NOUN
cet-15395	88	3	presented	present	VERB
cet-15395	88	4	below	below	ADP
cet-15395	88	5	provide	provide	VERB
cet-15395	88	6	an	an	DET
cet-15395	88	7	analysis	analysis	NOUN
cet-15395	88	8	of	of	ADP
cet-15395	88	9	the	the	DET
cet-15395	88	10	routes	route	NOUN
cet-15395	88	11	evaluated	evaluate	VERB
cet-15395	88	12	,	,	PUNCT
cet-15395	88	13	taking	take	VERB
cet-15395	88	14	into	into	ADP
cet-15395	88	15	account	account	NOUN
cet-15395	88	16	the	the	DET
cet-15395	88	17	thermodynamic	thermodynamic	ADJ
cet-15395	88	18	criteria	criterion	NOUN
cet-15395	88	19	established	establish	VERB
cet-15395	88	20	and	and	CCONJ
cet-15395	88	21	the	the	DET
cet-15395	88	22	practical	practical	ADJ
cet-15395	88	23	feasibility	feasibility	NOUN
cet-15395	88	24	of	of	ADP
cet-15395	88	25	implementation	implementation	NOUN
cet-15395	88	26	of	of	ADP
cet-15395	88	27	the	the	DET
cet-15395	88	28	proposed	propose	VERB
cet-15395	88	29	strategy	strategy	NOUN
cet-15395	88	30	.	.	PUNCT
cet-15395	89	1	table	table	NOUN
cet-15395	89	2	1	1	NUM
cet-15395	89	3	:	:	PUNCT
cet-15395	89	4	case	case	NOUN
cet-15395	89	5	study	study	NOUN
cet-15395	89	6	1	1	NUM
cet-15395	89	7	–	–	PUNCT
cet-15395	89	8	ch4	ch4	NOUN
cet-15395	89	9	+	+	CCONJ
cet-15395	89	10	o2	o2	PROPN
cet-15395	89	11	compound	compound	NOUN
cet-15395	89	12	molar	molar	PROPN
cet-15395	89	13	ratio	ratio	NOUN
cet-15395	89	14	ch4	ch4	PROPN
cet-15395	89	15	1	1	NUM
cet-15395	89	16	o2	o2	ADJ
cet-15395	89	17	2	2	NUM
cet-15395	89	18	table	table	NOUN
cet-15395	89	19	2	2	NUM
cet-15395	89	20	:	:	PUNCT
cet-15395	89	21	case	case	NOUN
cet-15395	89	22	study	study	NOUN
cet-15395	89	23	1	1	NUM
cet-15395	89	24	–	–	PUNCT
cet-15395	89	25	flows	flow	VERB
cet-15395	89	26	energy	energy	NOUN
cet-15395	89	27	molar	molar	ADJ
cet-15395	89	28	flow	flow	NOUN
cet-15395	89	29	mass	mass	NOUN
cet-15395	89	30	flow	flow	NOUN
cet-15395	89	31	enthalpy	enthalpy	PROPN
cet-15395	89	32	-4646.14kw	-4646.14kw	PROPN
cet-15395	89	33	62.35	62.35	NUM
cet-15395	89	34	mol	mol	NOUN
cet-15395	89	35	/	/	SYM
cet-15395	89	36	s	s	PART
cet-15395	89	37	1kg	1kg	ADJ
cet-15395	89	38	/	/	SYM
cet-15395	89	39	s	s	PART
cet-15395	89	40	-15.50	-15.50	PUNCT
cet-15395	89	41	kj	kj	PROPN
cet-15395	89	42	/	/	SYM
cet-15395	89	43	kmol	kmol	PROPN
cet-15395	89	44	as	as	SCONJ
cet-15395	89	45	shown	show	VERB
cet-15395	89	46	in	in	ADP
cet-15395	89	47	tables	table	NOUN
cet-15395	89	48	1	1	NUM
cet-15395	89	49	and	and	CCONJ
cet-15395	89	50	2	2	NUM
cet-15395	89	51	,	,	PUNCT
cet-15395	89	52	the	the	DET
cet-15395	89	53	negative	negative	ADJ
cet-15395	89	54	variation	variation	NOUN
cet-15395	89	55	in	in	ADP
cet-15395	89	56	enthalpy	enthalpy	NOUN
cet-15395	89	57	indicates	indicate	VERB
cet-15395	89	58	that	that	SCONJ
cet-15395	89	59	the	the	DET
cet-15395	89	60	process	process	NOUN
cet-15395	89	61	is	be	AUX
cet-15395	89	62	exothermic	exothermic	ADJ
cet-15395	89	63	,	,	PUNCT
cet-15395	89	64	which	which	PRON
cet-15395	89	65	is	be	AUX
cet-15395	89	66	in	in	ADP
cet-15395	89	67	agreement	agreement	NOUN
cet-15395	89	68	that	that	PRON
cet-15395	89	69	the	the	DET
cet-15395	89	70	simulated	simulate	VERB
cet-15395	89	71	reaction	reaction	NOUN
cet-15395	89	72	route	route	NOUN
cet-15395	89	73	meets	meet	VERB
cet-15395	89	74	the	the	DET
cet-15395	89	75	objective	objective	NOUN
cet-15395	89	76	of	of	ADP
cet-15395	89	77	compensating	compensate	VERB
cet-15395	89	78	for	for	ADP
cet-15395	89	79	energy	energy	NOUN
cet-15395	89	80	losses	loss	NOUN
cet-15395	89	81	,	,	PUNCT
cet-15395	89	82	making	make	VERB
cet-15395	89	83	the	the	DET
cet-15395	89	84	process	process	NOUN
cet-15395	89	85	thermodynamically	thermodynamically	ADV
cet-15395	89	86	favourable	favourable	ADJ
cet-15395	89	87	in	in	ADP
cet-15395	89	88	terms	term	NOUN
cet-15395	89	89	of	of	ADP
cet-15395	89	90	energy	energy	NOUN
cet-15395	89	91	released	release	VERB
cet-15395	89	92	.	.	PUNCT
cet-15395	90	1	also	also	ADV
cet-15395	90	2	,	,	PUNCT
cet-15395	90	3	all	all	DET
cet-15395	90	4	the	the	DET
cet-15395	90	5	reaction	reaction	NOUN
cet-15395	90	6	products	product	NOUN
cet-15395	90	7	are	be	AUX
cet-15395	90	8	in	in	ADP
cet-15395	90	9	the	the	DET
cet-15395	90	10	gas	gas	NOUN
cet-15395	90	11	phase	phase	NOUN
cet-15395	90	12	at	at	ADP
cet-15395	90	13	the	the	DET
cet-15395	90	14	end	end	NOUN
cet-15395	90	15	of	of	ADP
cet-15395	90	16	the	the	DET
cet-15395	90	17	process	process	NOUN
cet-15395	90	18	.	.	PUNCT
cet-15395	91	1	the	the	DET
cet-15395	91	2	increase	increase	NOUN
cet-15395	91	3	in	in	ADP
cet-15395	91	4	molar	molar	ADJ
cet-15395	91	5	flux	flux	NOUN
cet-15395	91	6	suggests	suggest	VERB
cet-15395	91	7	a	a	DET
cet-15395	91	8	reaction	reaction	NOUN
cet-15395	91	9	with	with	ADP
cet-15395	91	10	efficient	efficient	ADJ
cet-15395	91	11	conversion	conversion	NOUN
cet-15395	91	12	of	of	ADP
cet-15395	91	13	reactants	reactant	NOUN
cet-15395	91	14	into	into	ADP
cet-15395	91	15	products	product	NOUN
cet-15395	91	16	,	,	PUNCT
cet-15395	91	17	since	since	SCONJ
cet-15395	91	18	for	for	ADP
cet-15395	91	19	an	an	DET
cet-15395	91	20	initial	initial	ADJ
cet-15395	91	21	mole	mole	NOUN
cet-15395	91	22	of	of	ADP
cet-15395	91	23	ch4	ch4	NOUN
cet-15395	91	24	and	and	CCONJ
cet-15395	91	25	2	2	NUM
cet-15395	91	26	moles	mole	NOUN
cet-15395	91	27	of	of	ADP
cet-15395	91	28	o2	o2	PROPN
cet-15395	91	29	,	,	PUNCT
cet-15395	91	30	an	an	DET
cet-15395	91	31	increase	increase	NOUN
cet-15395	91	32	in	in	ADP
cet-15395	91	33	molar	molar	ADJ
cet-15395	91	34	flow	flow	NOUN
cet-15395	91	35	indicates	indicate	VERB
cet-15395	91	36	the	the	DET
cet-15395	91	37	formation	formation	NOUN
cet-15395	91	38	of	of	ADP
cet-15395	91	39	several	several	ADJ
cet-15395	91	40	products	product	NOUN
cet-15395	91	41	per	per	ADP
cet-15395	91	42	mole	mole	NOUN
cet-15395	91	43	of	of	ADP
cet-15395	91	44	reactant	reactant	NOUN
cet-15395	91	45	,	,	PUNCT
cet-15395	91	46	such	such	ADJ
cet-15395	91	47	as	as	ADP
cet-15395	91	48	co2	co2	NOUN
cet-15395	91	49	and	and	CCONJ
cet-15395	91	50	h2o	h2o	NOUN
cet-15395	91	51	.	.	PUNCT
cet-15395	92	1	on	on	ADP
cet-15395	92	2	the	the	DET
cet-15395	92	3	other	other	ADJ
cet-15395	92	4	hand	hand	NOUN
cet-15395	92	5	,	,	PUNCT
cet-15395	92	6	a	a	DET
cet-15395	92	7	constant	constant	ADJ
cet-15395	92	8	mass	mass	NOUN
cet-15395	92	9	flow	flow	NOUN
cet-15395	92	10	(	(	PUNCT
cet-15395	92	11	not	not	PART
cet-15395	92	12	molar	molar	ADJ
cet-15395	92	13	flow	flow	NOUN
cet-15395	92	14	)	)	PUNCT
cet-15395	92	15	just	just	ADV
cet-15395	92	16	reflects	reflect	VERB
cet-15395	92	17	the	the	DET
cet-15395	92	18	conservation	conservation	NOUN
cet-15395	92	19	of	of	ADP
cet-15395	92	20	mass	mass	NOUN
cet-15395	92	21	in	in	ADP
cet-15395	92	22	the	the	DET
cet-15395	92	23	process	process	NOUN
cet-15395	92	24	.	.	PUNCT
cet-15395	93	1	the	the	DET
cet-15395	93	2	conversion	conversion	NOUN
cet-15395	93	3	of	of	ADP
cet-15395	93	4	ch4	ch4	PROPN
cet-15395	93	5	and	and	CCONJ
cet-15395	93	6	o2	o2	PROPN
cet-15395	93	7	into	into	ADP
cet-15395	93	8	products	product	NOUN
cet-15395	93	9	maintains	maintain	VERB
cet-15395	93	10	the	the	DET
cet-15395	93	11	same	same	ADJ
cet-15395	93	12	initial	initial	ADJ
cet-15395	93	13	mass	mass	NOUN
cet-15395	93	14	flow	flow	NOUN
cet-15395	93	15	,	,	PUNCT
cet-15395	93	16	with	with	ADP
cet-15395	93	17	the	the	DET
cet-15395	93	18	difference	difference	NOUN
cet-15395	93	19	concentrated	concentrate	VERB
cet-15395	93	20	in	in	ADP
cet-15395	93	21	the	the	DET
cet-15395	93	22	composition	composition	NOUN
cet-15395	93	23	of	of	ADP
cet-15395	93	24	the	the	DET
cet-15395	93	25	products	product	NOUN
cet-15395	93	26	.	.	PUNCT
cet-15395	94	1	the	the	DET
cet-15395	94	2	negative	negative	ADJ
cet-15395	94	3	enthalpy	enthalpy	NOUN
cet-15395	94	4	reinforces	reinforce	VERB
cet-15395	94	5	the	the	DET
cet-15395	94	6	exothermic	exothermic	ADJ
cet-15395	94	7	nature	nature	NOUN
cet-15395	94	8	of	of	ADP
cet-15395	94	9	the	the	DET
cet-15395	94	10	reaction	reaction	NOUN
cet-15395	94	11	.	.	PUNCT
cet-15395	95	1	this	this	DET
cet-15395	95	2	value	value	NOUN
cet-15395	95	3	reflects	reflect	VERB
cet-15395	95	4	the	the	DET
cet-15395	95	5	release	release	NOUN
cet-15395	95	6	of	of	ADP
cet-15395	95	7	heat	heat	NOUN
cet-15395	95	8	in	in	ADP
cet-15395	95	9	the	the	DET
cet-15395	95	10	process	process	NOUN
cet-15395	95	11	,	,	PUNCT
cet-15395	95	12	contributing	contribute	VERB
cet-15395	95	13	to	to	ADP
cet-15395	95	14	the	the	DET
cet-15395	95	15	goal	goal	NOUN
cet-15395	95	16	of	of	ADP
cet-15395	95	17	minimizing	minimize	VERB
cet-15395	95	18	the	the	DET
cet-15395	95	19	need	need	NOUN
cet-15395	95	20	for	for	ADP
cet-15395	95	21	external	external	ADJ
cet-15395	95	22	energy	energy	NOUN
cet-15395	95	23	.	.	PUNCT
cet-15395	96	1	table	table	NOUN
cet-15395	96	2	3	3	NUM
cet-15395	96	3	:	:	PUNCT
cet-15395	96	4	case	case	NOUN
cet-15395	96	5	study	study	NOUN
cet-15395	96	6	2	2	NUM
cet-15395	96	7	–	–	PUNCT
cet-15395	96	8	ch4	ch4	NOUN
cet-15395	96	9	+	+	CCONJ
cet-15395	96	10	h2o	h2o	PROPN
cet-15395	96	11	compound	compound	NOUN
cet-15395	96	12	molar	molar	ADJ
cet-15395	96	13	faction	faction	NOUN
cet-15395	96	14	input	input	NOUN
cet-15395	96	15	ch4	ch4	PROPN
cet-15395	96	16	0.5289	0.5289	NUM
cet-15395	96	17	h2o	h2o	VERB
cet-15395	96	18	0.4710	0.4710	NUM
cet-15395	96	19	table	table	NOUN
cet-15395	96	20	4	4	NUM
cet-15395	96	21	:	:	PUNCT
cet-15395	96	22	case	case	NOUN
cet-15395	96	23	study	study	NOUN
cet-15395	96	24	2	2	NUM
cet-15395	96	25	–	–	PUNCT
cet-15395	96	26	flows	flow	VERB
cet-15395	96	27	energy	energy	NOUN
cet-15395	96	28	molar	molar	ADJ
cet-15395	96	29	flow	flow	NOUN
cet-15395	96	30	mass	mass	NOUN
cet-15395	96	31	flow	flow	NOUN
cet-15395	96	32	enthalpy	enthalpy	PROPN
cet-15395	96	33	-20699kw	-20699kw	NOUN
cet-15395	96	34	117.84	117.84	NUM
cet-15395	96	35	mol	mol	ADP
cet-15395	96	36	/	/	SYM
cet-15395	96	37	s	s	PART
cet-15395	96	38	2kg	2kg	NOUN
cet-15395	96	39	/	/	SYM
cet-15395	96	40	s	s	PROPN
cet-15395	96	41	22332.9	22332.9	NUM
cet-15395	96	42	kj	kj	PROPN
cet-15395	96	43	/	/	SYM
cet-15395	96	44	kmol	kmol	PROPN
cet-15395	96	45	as	as	SCONJ
cet-15395	96	46	shown	show	VERB
cet-15395	96	47	in	in	ADP
cet-15395	96	48	tables	table	NOUN
cet-15395	96	49	3	3	NUM
cet-15395	96	50	and	and	CCONJ
cet-15395	96	51	4	4	NUM
cet-15395	96	52	,	,	PUNCT
cet-15395	96	53	this	this	DET
cet-15395	96	54	process	process	NOUN
cet-15395	96	55	is	be	AUX
cet-15395	96	56	endothermic	endothermic	ADJ
cet-15395	96	57	,	,	PUNCT
cet-15395	96	58	which	which	PRON
cet-15395	96	59	suggests	suggest	VERB
cet-15395	96	60	that	that	SCONJ
cet-15395	96	61	the	the	DET
cet-15395	96	62	chemical	chemical	ADJ
cet-15395	96	63	reactions	reaction	NOUN
cet-15395	96	64	between	between	ADP
cet-15395	96	65	ch4	ch4	PROPN
cet-15395	96	66	and	and	CCONJ
cet-15395	96	67	h2o	h2o	PROPN
cet-15395	96	68	involve	involve	VERB
cet-15395	96	69	the	the	DET
cet-15395	96	70	formation	formation	NOUN
cet-15395	96	71	of	of	ADP
cet-15395	96	72	energetic	energetic	ADJ
cet-15395	96	73	by	by	ADP
cet-15395	96	74	-	-	PUNCT
cet-15395	96	75	products	product	NOUN
cet-15395	96	76	.	.	PUNCT
cet-15395	97	1	possible	possible	ADJ
cet-15395	97	2	answers	answer	NOUN
cet-15395	97	3	include	include	VERB
cet-15395	97	4	:	:	PUNCT
cet-15395	97	5	steam	steam	NOUN
cet-15395	97	6	reforming	reforming	NOUN
cet-15395	97	7	(	(	PUNCT
cet-15395	97	8	endothermic	endothermic	NOUN
cet-15395	97	9	):	):	PUNCT
cet-15395	97	10	ch4	ch4	NOUN
cet-15395	97	11	+	+	CCONJ
cet-15395	97	12	h2o	h2o	PROPN
cet-15395	97	13	→	→	SYM
cet-15395	97	14	co	co	NOUN
cet-15395	97	15	+	+	NOUN
cet-15395	97	16	3	3	NUM
cet-15395	97	17	h2	h2	NOUN
cet-15395	97	18	(	(	PUNCT
cet-15395	97	19	17	17	NUM
cet-15395	97	20	)	)	PUNCT
cet-15395	97	21	the	the	DET
cet-15395	97	22	reforming	reform	VERB
cet-15395	97	23	event	event	NOUN
cet-15395	97	24	is	be	AUX
cet-15395	97	25	endothermic	endothermic	ADJ
cet-15395	97	26	,	,	PUNCT
cet-15395	97	27	but	but	CCONJ
cet-15395	97	28	the	the	DET
cet-15395	97	29	overall	overall	ADJ
cet-15395	97	30	process	process	NOUN
cet-15395	97	31	can	can	AUX
cet-15395	97	32	be	be	AUX
cet-15395	97	33	exothermic	exothermic	ADJ
cet-15395	97	34	due	due	ADP
cet-15395	97	35	to	to	ADP
cet-15395	97	36	other	other	ADJ
cet-15395	97	37	interactions	interaction	NOUN
cet-15395	97	38	.	.	PUNCT
cet-15395	98	1	gas	gas	NOUN
cet-15395	98	2	-	-	PUNCT
cet-15395	98	3	water	water	NOUN
cet-15395	98	4	displacement	displacement	NOUN
cet-15395	98	5	reaction	reaction	NOUN
cet-15395	98	6	(	(	PUNCT
cet-15395	98	7	exothermic	exothermic	NOUN
cet-15395	98	8	):	):	PUNCT
cet-15395	98	9	co	co	ADJ
cet-15395	98	10	+	+	ADJ
cet-15395	98	11	h2o	h2o	NOUN
cet-15395	98	12	→	→	PUNCT
cet-15395	98	13	co2	co2	NOUN
cet-15395	98	14	+	+	X
cet-15395	98	15	h2	h2	NOUN
cet-15395	98	16	(	(	PUNCT
cet-15395	98	17	18	18	NUM
cet-15395	98	18	)	)	PUNCT
cet-15395	98	19	the	the	DET
cet-15395	98	20	following	follow	VERB
cet-15395	98	21	observations	observation	NOUN
cet-15395	98	22	can	can	AUX
cet-15395	98	23	also	also	ADV
cet-15395	98	24	be	be	AUX
cet-15395	98	25	made	make	VERB
cet-15395	98	26	,	,	PUNCT
cet-15395	98	27	at	at	ADP
cet-15395	98	28	the	the	DET
cet-15395	98	29	end	end	NOUN
cet-15395	98	30	of	of	ADP
cet-15395	98	31	the	the	DET
cet-15395	98	32	overall	overall	ADJ
cet-15395	98	33	process	process	NOUN
cet-15395	98	34	:	:	PUNCT
cet-15395	98	35	product	product	NOUN
cet-15395	98	36	phase	phase	NOUN
cet-15395	98	37	●	●	PUNCT
cet-15395	98	38	approximately	approximately	ADV
cet-15395	98	39	half	half	NOUN
cet-15395	98	40	of	of	ADP
cet-15395	98	41	the	the	DET
cet-15395	98	42	products	product	NOUN
cet-15395	98	43	are	be	AUX
cet-15395	98	44	in	in	ADP
cet-15395	98	45	the	the	DET
cet-15395	98	46	vapour	vapour	NOUN
cet-15395	98	47	phase	phase	NOUN
cet-15395	98	48	,	,	PUNCT
cet-15395	98	49	while	while	SCONJ
cet-15395	98	50	the	the	DET
cet-15395	98	51	rest	rest	NOUN
cet-15395	98	52	remain	remain	VERB
cet-15395	98	53	in	in	ADP
cet-15395	98	54	the	the	DET
cet-15395	98	55	liquid	liquid	ADJ
cet-15395	98	56	phase	phase	NOUN
cet-15395	98	57	.	.	PUNCT
cet-15395	99	1	●	●	PUNCT
cet-15395	99	2	the	the	DET
cet-15395	99	3	presence	presence	NOUN
cet-15395	99	4	of	of	ADP
cet-15395	99	5	the	the	DET
cet-15395	99	6	liquid	liquid	ADJ
cet-15395	99	7	phase	phase	NOUN
cet-15395	99	8	can	can	AUX
cet-15395	99	9	be	be	AUX
cet-15395	99	10	attributed	attribute	VERB
cet-15395	99	11	to	to	ADP
cet-15395	99	12	excess	excess	ADJ
cet-15395	99	13	(	(	PUNCT
cet-15395	99	14	unconverted	unconverted	ADJ
cet-15395	99	15	)	)	PUNCT
cet-15395	99	16	water	water	NOUN
cet-15395	99	17	or	or	CCONJ
cet-15395	99	18	to	to	ADP
cet-15395	99	19	the	the	DET
cet-15395	99	20	partial	partial	ADJ
cet-15395	99	21	condensation	condensation	NOUN
cet-15395	99	22	of	of	ADP
cet-15395	99	23	water	water	NOUN
cet-15395	99	24	vapour	vapour	NOUN
cet-15395	99	25	under	under	ADP
cet-15395	99	26	reference	reference	NOUN
cet-15395	99	27	conditions	condition	NOUN
cet-15395	99	28	(	(	PUNCT
cet-15395	99	29	25	25	NUM
cet-15395	99	30	°	°	NOUN
cet-15395	99	31	c	c	NOUN
cet-15395	99	32	,	,	PUNCT
cet-15395	99	33	1atm	1atm	NUM
cet-15395	99	34	)	)	PUNCT
cet-15395	99	35	at	at	ADP
cet-15395	99	36	the	the	DET
cet-15395	99	37	end	end	NOUN
cet-15395	99	38	of	of	ADP
cet-15395	99	39	the	the	DET
cet-15395	99	40	process	process	NOUN
cet-15395	99	41	.	.	PUNCT
cet-15395	100	1	●	●	NUM
cet-15395	100	2	components	component	NOUN
cet-15395	100	3	in	in	ADP
cet-15395	100	4	the	the	DET
cet-15395	100	5	vapour	vapour	NOUN
cet-15395	100	6	phase	phase	NOUN
cet-15395	100	7	predominantly	predominantly	ADV
cet-15395	100	8	include	include	VERB
cet-15395	100	9	h2	h2	NOUN
cet-15395	100	10	,	,	PUNCT
cet-15395	100	11	co	co	NOUN
cet-15395	100	12	,	,	PUNCT
cet-15395	100	13	and	and	CCONJ
cet-15395	100	14	possibly	possibly	ADV
cet-15395	100	15	residual	residual	ADJ
cet-15395	100	16	ch4	ch4	NOUN
cet-15395	100	17	.	.	PUNCT
cet-15395	101	1	in	in	ADP
cet-15395	101	2	the	the	DET
cet-15395	101	3	liquid	liquid	ADJ
cet-15395	101	4	phase	phase	NOUN
cet-15395	101	5	,	,	PUNCT
cet-15395	101	6	water	water	NOUN
cet-15395	101	7	dominates	dominate	VERB
cet-15395	101	8	.	.	PUNCT
cet-15395	102	1	869	869	NUM
cet-15395	102	2	physical	physical	ADJ
cet-15395	102	3	flows	flow	VERB
cet-15395	102	4	●	●	PUNCT
cet-15395	102	5	the	the	DET
cet-15395	102	6	molar	molar	ADJ
cet-15395	102	7	amount	amount	NOUN
cet-15395	102	8	of	of	ADP
cet-15395	102	9	products	product	NOUN
cet-15395	102	10	is	be	AUX
cet-15395	102	11	significantly	significantly	ADV
cet-15395	102	12	greater	great	ADJ
cet-15395	102	13	than	than	ADP
cet-15395	102	14	the	the	DET
cet-15395	102	15	input	input	NOUN
cet-15395	102	16	of	of	ADP
cet-15395	102	17	reactants	reactant	NOUN
cet-15395	102	18	,	,	PUNCT
cet-15395	102	19	suggesting	suggest	VERB
cet-15395	102	20	the	the	DET
cet-15395	102	21	formation	formation	NOUN
cet-15395	102	22	of	of	ADP
cet-15395	102	23	multiple	multiple	ADJ
cet-15395	102	24	molecules	molecule	NOUN
cet-15395	102	25	of	of	ADP
cet-15395	102	26	gaseous	gaseous	ADJ
cet-15395	102	27	products	product	NOUN
cet-15395	102	28	,	,	PUNCT
cet-15395	102	29	such	such	ADJ
cet-15395	102	30	as	as	ADP
cet-15395	102	31	h2	h2	NOUN
cet-15395	102	32	.	.	PUNCT
cet-15395	103	1	●	●	PUNCT
cet-15395	103	2	volumetric	volumetric	ADJ
cet-15395	103	3	expansion	expansion	NOUN
cet-15395	103	4	is	be	AUX
cet-15395	103	5	associated	associate	VERB
cet-15395	103	6	with	with	ADP
cet-15395	103	7	the	the	DET
cet-15395	103	8	production	production	NOUN
cet-15395	103	9	of	of	ADP
cet-15395	103	10	gases	gas	NOUN
cet-15395	103	11	,	,	PUNCT
cet-15395	103	12	such	such	ADJ
cet-15395	103	13	as	as	ADP
cet-15395	103	14	h2	h2	NOUN
cet-15395	103	15	,	,	PUNCT
cet-15395	103	16	which	which	PRON
cet-15395	103	17	occupy	occupy	VERB
cet-15395	103	18	a	a	DET
cet-15395	103	19	larger	large	ADJ
cet-15395	103	20	volume	volume	NOUN
cet-15395	103	21	than	than	ADP
cet-15395	103	22	liquids	liquid	NOUN
cet-15395	103	23	.	.	PUNCT
cet-15395	104	1	enthalpy	enthalpy	NOUN
cet-15395	104	2	variation	variation	NOUN
cet-15395	104	3	●	●	PUNCT
cet-15395	104	4	a	a	DET
cet-15395	104	5	negative	negative	ADJ
cet-15395	104	6	value	value	NOUN
cet-15395	104	7	indicates	indicate	VERB
cet-15395	104	8	an	an	DET
cet-15395	104	9	exothermic	exothermic	ADJ
cet-15395	104	10	system	system	NOUN
cet-15395	104	11	.	.	PUNCT
cet-15395	105	1	this	this	PRON
cet-15395	105	2	is	be	AUX
cet-15395	105	3	in	in	ADP
cet-15395	105	4	line	line	NOUN
cet-15395	105	5	with	with	ADP
cet-15395	105	6	the	the	DET
cet-15395	105	7	energy	energy	NOUN
cet-15395	105	8	released	release	VERB
cet-15395	105	9	in	in	ADP
cet-15395	105	10	secondary	secondary	ADJ
cet-15395	105	11	reactions	reaction	NOUN
cet-15395	105	12	,	,	PUNCT
cet-15395	105	13	such	such	ADJ
cet-15395	105	14	as	as	ADP
cet-15395	105	15	the	the	DET
cet-15395	105	16	gas	gas	NOUN
cet-15395	105	17	-	-	PUNCT
cet-15395	105	18	water	water	NOUN
cet-15395	105	19	displacement	displacement	ADJ
cet-15395	105	20	reaction	reaction	NOUN
cet-15395	105	21	.	.	PUNCT
cet-15395	106	1	the	the	DET
cet-15395	106	2	results	result	NOUN
cet-15395	106	3	are	be	AUX
cet-15395	106	4	in	in	ADP
cet-15395	106	5	line	line	NOUN
cet-15395	106	6	with	with	ADP
cet-15395	106	7	advanced	advanced	ADJ
cet-15395	106	8	studies	study	NOUN
cet-15395	106	9	on	on	ADP
cet-15395	106	10	methane	methane	NOUN
cet-15395	106	11	reforming	reform	VERB
cet-15395	106	12	and	and	CCONJ
cet-15395	106	13	co2	co2	NOUN
cet-15395	106	14	capture	capture	NOUN
cet-15395	106	15	.	.	PUNCT
cet-15395	107	1	aasberg	aasberg	PROPN
cet-15395	107	2	-	-	PUNCT
cet-15395	107	3	petersen	petersen	PROPN
cet-15395	107	4	et	et	PROPN
cet-15395	107	5	al	al	PROPN
cet-15395	107	6	.	.	PROPN
cet-15395	108	1	(	(	PUNCT
cet-15395	108	2	2003	2003	NUM
cet-15395	108	3	)	)	PUNCT
cet-15395	108	4	highlighted	highlight	VERB
cet-15395	108	5	that	that	SCONJ
cet-15395	108	6	autothermal	autothermal	ADJ
cet-15395	108	7	reforming	reform	VERB
cet-15395	108	8	improves	improve	VERB
cet-15395	108	9	energy	energy	NOUN
cet-15395	108	10	efficiency	efficiency	NOUN
cet-15395	108	11	.	.	PUNCT
cet-15395	109	1	adhikari	adhikari	PROPN
cet-15395	109	2	et	et	PROPN
cet-15395	109	3	al	al	PROPN
cet-15395	109	4	.	.	PROPN
cet-15395	110	1	(	(	PUNCT
cet-15395	110	2	2007	2007	NUM
cet-15395	110	3	)	)	PUNCT
cet-15395	110	4	demonstrated	demonstrate	VERB
cet-15395	110	5	that	that	SCONJ
cet-15395	110	6	the	the	DET
cet-15395	110	7	combination	combination	NOUN
cet-15395	110	8	of	of	ADP
cet-15395	110	9	reformers	reformer	NOUN
cet-15395	110	10	and	and	CCONJ
cet-15395	110	11	displacement	displacement	ADJ
cet-15395	110	12	reactions	reaction	NOUN
cet-15395	110	13	improves	improve	VERB
cet-15395	110	14	the	the	DET
cet-15395	110	15	conversion	conversion	NOUN
cet-15395	110	16	of	of	ADP
cet-15395	110	17	co	co	NOUN
cet-15395	110	18	to	to	ADP
cet-15395	110	19	h2	h2	PROPN
cet-15395	110	20	.	.	PUNCT
cet-15395	111	1	6	6	NUM
cet-15395	111	2	.	.	PUNCT
cet-15395	111	3	conclusions	conclusion	NOUN
cet-15395	111	4	this	this	DET
cet-15395	111	5	study	study	NOUN
cet-15395	111	6	contributes	contribute	VERB
cet-15395	111	7	with	with	ADP
cet-15395	111	8	optimized	optimize	VERB
cet-15395	111	9	strategies	strategy	NOUN
cet-15395	111	10	for	for	ADP
cet-15395	111	11	urea	urea	NOUN
cet-15395	111	12	and	and	CCONJ
cet-15395	111	13	h2	h2	NOUN
cet-15395	111	14	production	production	NOUN
cet-15395	111	15	from	from	ADP
cet-15395	111	16	methane	methane	NOUN
cet-15395	111	17	,	,	PUNCT
cet-15395	111	18	as	as	ADP
cet-15395	111	19	a	a	DET
cet-15395	111	20	case	case	NOUN
cet-15395	111	21	study	study	NOUN
cet-15395	111	22	,	,	PUNCT
cet-15395	111	23	while	while	SCONJ
cet-15395	111	24	avoiding	avoid	VERB
cet-15395	111	25	co2	co2	NOUN
cet-15395	111	26	release	release	NOUN
cet-15395	111	27	.	.	PUNCT
cet-15395	112	1	based	base	VERB
cet-15395	112	2	on	on	ADP
cet-15395	112	3	a	a	DET
cet-15395	112	4	list	list	NOUN
cet-15395	112	5	of	of	ADP
cet-15395	112	6	possible	possible	ADJ
cet-15395	112	7	products	product	NOUN
cet-15395	112	8	and	and	CCONJ
cet-15395	112	9	raw	raw	ADJ
cet-15395	112	10	materials	material	NOUN
cet-15395	112	11	,	,	PUNCT
cet-15395	112	12	with	with	ADP
cet-15395	112	13	the	the	DET
cet-15395	112	14	goal	goal	NOUN
cet-15395	112	15	of	of	ADP
cet-15395	112	16	a	a	DET
cet-15395	112	17	global	global	ADJ
cet-15395	112	18	process	process	NOUN
cet-15395	112	19	that	that	PRON
cet-15395	112	20	is	be	AUX
cet-15395	112	21	exothermic	exothermic	ADJ
cet-15395	112	22	and	and	CCONJ
cet-15395	112	23	produces	produce	VERB
cet-15395	112	24	a	a	DET
cet-15395	112	25	valuable	valuable	ADJ
cet-15395	112	26	product	product	NOUN
cet-15395	112	27	and	and	CCONJ
cet-15395	112	28	hydrogen	hydrogen	NOUN
cet-15395	112	29	,	,	PUNCT
cet-15395	112	30	without	without	ADP
cet-15395	112	31	releasing	release	VERB
cet-15395	112	32	carbon	carbon	NOUN
cet-15395	112	33	dioxide	dioxide	NOUN
cet-15395	112	34	,	,	PUNCT
cet-15395	112	35	the	the	DET
cet-15395	112	36	product	product	NOUN
cet-15395	112	37	chosen	choose	VERB
cet-15395	112	38	was	be	AUX
cet-15395	112	39	urea	urea	NOUN
cet-15395	112	40	and	and	CCONJ
cet-15395	112	41	hydrogen	hydrogen	NOUN
cet-15395	112	42	,	,	PUNCT
cet-15395	112	43	using	use	VERB
cet-15395	112	44	methane	methane	NOUN
cet-15395	112	45	,	,	PUNCT
cet-15395	112	46	water	water	NOUN
cet-15395	112	47	and	and	CCONJ
cet-15395	112	48	air	air	NOUN
cet-15395	112	49	(	(	PUNCT
cet-15395	112	50	n2	n2	ADJ
cet-15395	112	51	and	and	CCONJ
cet-15395	112	52	o2	o2	ADJ
cet-15395	112	53	)	)	PUNCT
cet-15395	112	54	as	as	ADP
cet-15395	112	55	reactants	reactant	NOUN
cet-15395	112	56	.	.	PUNCT
cet-15395	113	1	the	the	DET
cet-15395	113	2	preliminary	preliminary	ADJ
cet-15395	113	3	results	result	NOUN
cet-15395	113	4	indicated	indicate	VERB
cet-15395	113	5	the	the	DET
cet-15395	113	6	viability	viability	NOUN
cet-15395	113	7	of	of	ADP
cet-15395	113	8	the	the	DET
cet-15395	113	9	proposal	proposal	NOUN
cet-15395	113	10	.	.	PUNCT
cet-15395	114	1	however	however	ADV
cet-15395	114	2	,	,	PUNCT
cet-15395	114	3	this	this	DET
cet-15395	114	4	global	global	ADJ
cet-15395	114	5	route	route	NOUN
cet-15395	114	6	requires	require	VERB
cet-15395	114	7	some	some	DET
cet-15395	114	8	reactions	reaction	NOUN
cet-15395	114	9	to	to	PART
cet-15395	114	10	achieve	achieve	VERB
cet-15395	114	11	the	the	DET
cet-15395	114	12	main	main	ADJ
cet-15395	114	13	goal	goal	NOUN
cet-15395	114	14	,	,	PUNCT
cet-15395	114	15	so	so	SCONJ
cet-15395	114	16	some	some	PRON
cet-15395	114	17	of	of	ADP
cet-15395	114	18	these	these	DET
cet-15395	114	19	individual	individual	ADJ
cet-15395	114	20	reactions	reaction	NOUN
cet-15395	114	21	of	of	ADP
cet-15395	114	22	the	the	DET
cet-15395	114	23	global	global	ADJ
cet-15395	114	24	route	route	NOUN
cet-15395	114	25	were	be	AUX
cet-15395	114	26	studied	study	VERB
cet-15395	114	27	in	in	ADP
cet-15395	114	28	this	this	DET
cet-15395	114	29	work	work	NOUN
cet-15395	114	30	.	.	PUNCT
cet-15395	115	1	analysis	analysis	NOUN
cet-15395	115	2	of	of	ADP
cet-15395	115	3	the	the	DET
cet-15395	115	4	ch4	ch4	NOUN
cet-15395	115	5	+	+	CCONJ
cet-15395	115	6	o2	o2	PROPN
cet-15395	115	7	route	route	NOUN
cet-15395	115	8	indicated	indicate	VERB
cet-15395	115	9	that	that	SCONJ
cet-15395	115	10	it	it	PRON
cet-15395	115	11	is	be	AUX
cet-15395	115	12	exothermic	exothermic	ADJ
cet-15395	115	13	and	and	CCONJ
cet-15395	115	14	produces	produce	VERB
cet-15395	115	15	carbon	carbon	NOUN
cet-15395	115	16	dioxide	dioxide	NOUN
cet-15395	115	17	,	,	PUNCT
cet-15395	115	18	which	which	PRON
cet-15395	115	19	can	can	AUX
cet-15395	115	20	be	be	AUX
cet-15395	115	21	used	use	VERB
cet-15395	115	22	later	later	ADV
cet-15395	115	23	in	in	ADP
cet-15395	115	24	the	the	DET
cet-15395	115	25	production	production	NOUN
cet-15395	115	26	of	of	ADP
cet-15395	115	27	urea	urea	NOUN
cet-15395	115	28	.	.	PUNCT
cet-15395	116	1	analysis	analysis	NOUN
cet-15395	116	2	of	of	ADP
cet-15395	116	3	the	the	DET
cet-15395	116	4	ch4	ch4	NOUN
cet-15395	116	5	+	+	CCONJ
cet-15395	116	6	h2o	h2o	PROPN
cet-15395	116	7	route	route	NOUN
cet-15395	116	8	highlights	highlight	VERB
cet-15395	116	9	a	a	DET
cet-15395	116	10	thermodynamically	thermodynamically	ADV
cet-15395	116	11	promising	promising	ADJ
cet-15395	116	12	process	process	NOUN
cet-15395	116	13	for	for	ADP
cet-15395	116	14	generating	generate	VERB
cet-15395	116	15	useful	useful	ADJ
cet-15395	116	16	gases	gas	NOUN
cet-15395	116	17	such	such	ADJ
cet-15395	116	18	as	as	ADP
cet-15395	116	19	h2	h2	NOUN
cet-15395	116	20	and	and	CCONJ
cet-15395	116	21	co	co	NOUN
cet-15395	116	22	,	,	PUNCT
cet-15395	116	23	with	with	ADP
cet-15395	116	24	strategic	strategic	ADJ
cet-15395	116	25	potential	potential	NOUN
cet-15395	116	26	for	for	ADP
cet-15395	116	27	meeting	meet	VERB
cet-15395	116	28	the	the	DET
cet-15395	116	29	demand	demand	NOUN
cet-15395	116	30	for	for	ADP
cet-15395	116	31	chemical	chemical	NOUN
cet-15395	116	32	and	and	CCONJ
cet-15395	116	33	energy	energy	NOUN
cet-15395	116	34	inputs	input	NOUN
cet-15395	116	35	in	in	ADP
cet-15395	116	36	the	the	DET
cet-15395	116	37	transition	transition	NOUN
cet-15395	116	38	to	to	ADP
cet-15395	116	39	more	more	ADV
cet-15395	116	40	sustainable	sustainable	ADJ
cet-15395	116	41	technologies	technology	NOUN
cet-15395	116	42	.	.	PUNCT
cet-15395	117	1	the	the	DET
cet-15395	117	2	coexistence	coexistence	NOUN
cet-15395	117	3	of	of	ADP
cet-15395	117	4	liquid	liquid	ADJ
cet-15395	117	5	and	and	CCONJ
cet-15395	117	6	steam	steam	NOUN
cet-15395	117	7	phases	phase	NOUN
cet-15395	117	8	at	at	ADP
cet-15395	117	9	the	the	DET
cet-15395	117	10	end	end	NOUN
cet-15395	117	11	of	of	ADP
cet-15395	117	12	the	the	DET
cet-15395	117	13	process	process	NOUN
cet-15395	117	14	reflects	reflect	VERB
cet-15395	117	15	the	the	DET
cet-15395	117	16	presence	presence	NOUN
cet-15395	117	17	of	of	ADP
cet-15395	117	18	unconverted	unconverte	VERB
cet-15395	117	19	residual	residual	ADJ
cet-15395	117	20	water	water	NOUN
cet-15395	117	21	,	,	PUNCT
cet-15395	117	22	opening	open	VERB
cet-15395	117	23	up	up	ADP
cet-15395	117	24	the	the	DET
cet-15395	117	25	opportunity	opportunity	NOUN
cet-15395	117	26	to	to	PART
cet-15395	117	27	optimize	optimize	VERB
cet-15395	117	28	the	the	DET
cet-15395	117	29	process	process	NOUN
cet-15395	117	30	through	through	ADP
cet-15395	117	31	precise	precise	ADJ
cet-15395	117	32	control	control	NOUN
cet-15395	117	33	of	of	ADP
cet-15395	117	34	operating	operate	VERB
cet-15395	117	35	variables	variable	NOUN
cet-15395	117	36	such	such	ADJ
cet-15395	117	37	as	as	ADP
cet-15395	117	38	temperature	temperature	NOUN
cet-15395	117	39	and	and	CCONJ
cet-15395	117	40	pressure	pressure	NOUN
cet-15395	117	41	,	,	PUNCT
cet-15395	117	42	as	as	ADV
cet-15395	117	43	well	well	ADV
cet-15395	117	44	as	as	ADP
cet-15395	117	45	the	the	DET
cet-15395	117	46	introduction	introduction	NOUN
cet-15395	117	47	of	of	ADP
cet-15395	117	48	more	more	ADJ
cet-15395	117	49	selective	selective	ADJ
cet-15395	117	50	catalysts	catalyst	NOUN
cet-15395	117	51	.	.	PUNCT
cet-15395	118	1	in	in	ADP
cet-15395	118	2	addition	addition	NOUN
cet-15395	118	3	,	,	PUNCT
cet-15395	118	4	partial	partial	ADJ
cet-15395	118	5	conversion	conversion	NOUN
cet-15395	118	6	observed	observe	VERB
cet-15395	118	7	suggest	suggest	VERB
cet-15395	118	8	that	that	SCONJ
cet-15395	118	9	fine	fine	ADJ
cet-15395	118	10	adjustments	adjustment	NOUN
cet-15395	118	11	to	to	ADP
cet-15395	118	12	the	the	DET
cet-15395	118	13	reaction	reaction	NOUN
cet-15395	118	14	design	design	NOUN
cet-15395	118	15	can	can	AUX
cet-15395	118	16	significantly	significantly	ADV
cet-15395	118	17	increase	increase	VERB
cet-15395	118	18	the	the	DET
cet-15395	118	19	efficiency	efficiency	NOUN
cet-15395	118	20	of	of	ADP
cet-15395	118	21	the	the	DET
cet-15395	118	22	process	process	NOUN
cet-15395	118	23	.	.	PUNCT
cet-15395	119	1	the	the	DET
cet-15395	119	2	integration	integration	NOUN
cet-15395	119	3	of	of	ADP
cet-15395	119	4	optimized	optimize	VERB
cet-15395	119	5	reforming	reforming	NOUN
cet-15395	119	6	and	and	CCONJ
cet-15395	119	7	water	water	NOUN
cet-15395	119	8	-	-	PUNCT
cet-15395	119	9	gas	gas	NOUN
cet-15395	119	10	shift	shift	NOUN
cet-15395	119	11	steps	step	NOUN
cet-15395	119	12	can	can	AUX
cet-15395	119	13	increase	increase	VERB
cet-15395	119	14	h2	h2	NOUN
cet-15395	119	15	production	production	NOUN
cet-15395	119	16	,	,	PUNCT
cet-15395	119	17	consolidating	consolidate	VERB
cet-15395	119	18	the	the	DET
cet-15395	119	19	system	system	NOUN
cet-15395	119	20	as	as	ADP
cet-15395	119	21	an	an	DET
cet-15395	119	22	attractive	attractive	ADJ
cet-15395	119	23	solution	solution	NOUN
cet-15395	119	24	for	for	ADP
cet-15395	119	25	generating	generate	VERB
cet-15395	119	26	clean	clean	ADJ
cet-15395	119	27	energy	energy	NOUN
cet-15395	119	28	and	and	CCONJ
cet-15395	119	29	high	high	ADJ
cet-15395	119	30	value	value	NOUN
cet-15395	119	31	-	-	PUNCT
cet-15395	119	32	added	add	VERB
cet-15395	119	33	chemical	chemical	NOUN
cet-15395	119	34	inputs	input	NOUN
cet-15395	119	35	.	.	PUNCT
cet-15395	120	1	in	in	ADP
cet-15395	120	2	this	this	DET
cet-15395	120	3	way	way	NOUN
cet-15395	120	4	,	,	PUNCT
cet-15395	120	5	this	this	DET
cet-15395	120	6	study	study	NOUN
cet-15395	120	7	provides	provide	VERB
cet-15395	120	8	a	a	DET
cet-15395	120	9	solid	solid	ADJ
cet-15395	120	10	basis	basis	NOUN
cet-15395	120	11	for	for	ADP
cet-15395	120	12	the	the	DET
cet-15395	120	13	development	development	NOUN
cet-15395	120	14	of	of	ADP
cet-15395	120	15	promising	promising	ADJ
cet-15395	120	16	technologies	technology	NOUN
cet-15395	120	17	in	in	ADP
cet-15395	120	18	the	the	DET
cet-15395	120	19	use	use	NOUN
cet-15395	120	20	of	of	ADP
cet-15395	120	21	ch4	ch4	NOUN
cet-15395	120	22	,	,	PUNCT
cet-15395	120	23	with	with	ADP
cet-15395	120	24	direct	direct	ADJ
cet-15395	120	25	implications	implication	NOUN
cet-15395	120	26	for	for	ADP
cet-15395	120	27	environmental	environmental	ADJ
cet-15395	120	28	sustainability	sustainability	NOUN
cet-15395	120	29	and	and	CCONJ
cet-15395	120	30	the	the	DET
cet-15395	120	31	advancement	advancement	NOUN
cet-15395	120	32	of	of	ADP
cet-15395	120	33	a	a	DET
cet-15395	120	34	low	low	ADJ
cet-15395	120	35	-	-	PUNCT
cet-15395	120	36	carbon	carbon	NOUN
cet-15395	120	37	economy	economy	NOUN
cet-15395	120	38	.	.	PUNCT
cet-15395	121	1	other	other	ADJ
cet-15395	121	2	steps	step	NOUN
cet-15395	121	3	of	of	ADP
cet-15395	121	4	reactions	reaction	NOUN
cet-15395	121	5	to	to	PART
cet-15395	121	6	produce	produce	VERB
cet-15395	121	7	urea	urea	NOUN
cet-15395	121	8	have	have	VERB
cet-15395	121	9	to	to	PART
cet-15395	121	10	be	be	AUX
cet-15395	121	11	evaluated	evaluate	VERB
cet-15395	121	12	,	,	PUNCT
cet-15395	121	13	such	such	ADJ
cet-15395	121	14	as	as	ADP
cet-15395	121	15	the	the	DET
cet-15395	121	16	production	production	NOUN
cet-15395	121	17	of	of	ADP
cet-15395	121	18	nh3	nh3	NOUN
cet-15395	121	19	and	and	CCONJ
cet-15395	121	20	the	the	DET
cet-15395	121	21	reaction	reaction	NOUN
cet-15395	121	22	of	of	ADP
cet-15395	121	23	co2	co2	NOUN
cet-15395	121	24	and	and	CCONJ
cet-15395	121	25	nh3	nh3	NOUN
cet-15395	121	26	,	,	PUNCT
cet-15395	121	27	using	use	VERB
cet-15395	121	28	real	real	ADJ
cet-15395	121	29	process	process	NOUN
cet-15395	121	30	conditions	condition	NOUN
cet-15395	121	31	(	(	PUNCT
cet-15395	121	32	temperature	temperature	NOUN
cet-15395	121	33	and	and	CCONJ
cet-15395	121	34	pressure	pressure	NOUN
cet-15395	121	35	at	at	ADP
cet-15395	121	36	operating	operating	NOUN
cet-15395	121	37	conditions	condition	NOUN
cet-15395	121	38	)	)	PUNCT
cet-15395	121	39	,	,	PUNCT
cet-15395	121	40	simulated	simulate	VERB
cet-15395	121	41	with	with	ADP
cet-15395	121	42	a	a	DET
cet-15395	121	43	software	software	NOUN
cet-15395	121	44	such	such	ADJ
cet-15395	121	45	as	as	ADP
cet-15395	121	46	aspen	aspen	NOUN
cet-15395	121	47	.	.	PUNCT
cet-15395	122	1	it	it	PRON
cet-15395	122	2	will	will	AUX
cet-15395	122	3	be	be	AUX
cet-15395	122	4	a	a	DET
cet-15395	122	5	part	part	NOUN
cet-15395	122	6	of	of	ADP
cet-15395	122	7	this	this	DET
cet-15395	122	8	work	work	NOUN
cet-15395	122	9	as	as	ADP
cet-15395	122	10	future	future	ADJ
cet-15395	122	11	research	research	NOUN
cet-15395	122	12	,	,	PUNCT
cet-15395	122	13	as	as	ADV
cet-15395	122	14	well	well	ADV
cet-15395	122	15	as	as	ADP
cet-15395	122	16	the	the	DET
cet-15395	122	17	scale	scale	NOUN
cet-15395	122	18	-	-	PUNCT
cet-15395	122	19	up	up	NOUN
cet-15395	122	20	and	and	CCONJ
cet-15395	122	21	technical	technical	ADJ
cet-15395	122	22	economic	economic	ADJ
cet-15395	122	23	analysis	analysis	NOUN
cet-15395	122	24	of	of	ADP
cet-15395	122	25	the	the	DET
cet-15395	122	26	process	process	NOUN
cet-15395	122	27	.	.	PUNCT
cet-15395	123	1	references	reference	NOUN
cet-15395	123	2	aasberg	aasberg	PROPN
cet-15395	123	3	-	-	PROPN
cet-15395	123	4	petersen	petersen	PROPN
cet-15395	123	5	k.	k.	PROPN
cet-15395	123	6	,	,	PUNCT
cet-15395	123	7	christensen	christensen	PROPN
cet-15395	123	8	t.s	t.s	PROPN
cet-15395	123	9	.	.	PROPN
cet-15395	123	10	,	,	PUNCT
cet-15395	123	11	nielsen	nielsen	PROPN
cet-15395	123	12	c.s	c.s	AUX
cet-15395	123	13	.	.	PROPN
cet-15395	123	14	,	,	PUNCT
cet-15395	123	15	dybkjaer	dybkjaer	PROPN
cet-15395	123	16	i.	i.	PROPN
cet-15395	123	17	,	,	PUNCT
cet-15395	123	18	2003	2003	NUM
cet-15395	123	19	,	,	PUNCT
cet-15395	123	20	recent	recent	ADJ
cet-15395	123	21	developments	development	NOUN
cet-15395	123	22	in	in	ADP
cet-15395	123	23	autothermal	autothermal	ADJ
cet-15395	123	24	reforming	reform	VERB
cet-15395	123	25	and	and	CCONJ
cet-15395	123	26	pre	pre	ADJ
cet-15395	123	27	-	-	ADJ
cet-15395	123	28	reforming	reform	VERB
cet-15395	123	29	for	for	ADP
cet-15395	123	30	synthesis	synthesis	NOUN
cet-15395	123	31	gas	gas	NOUN
cet-15395	123	32	production	production	NOUN
cet-15395	123	33	in	in	ADP
cet-15395	123	34	gtl	gtl	PROPN
cet-15395	123	35	applications	application	NOUN
cet-15395	123	36	.	.	PUNCT
cet-15395	124	1	fuel	fuel	NOUN
cet-15395	124	2	processing	processing	NOUN
cet-15395	124	3	technology	technology	NOUN
cet-15395	124	4	,	,	PUNCT
cet-15395	124	5	amsterdam	amsterdam	PROPN
cet-15395	124	6	,	,	PUNCT
cet-15395	124	7	v.	v.	PROPN
cet-15395	124	8	83	83	NUM
cet-15395	124	9	,	,	PUNCT
cet-15395	124	10	n.	n.	NOUN
cet-15395	124	11	13	13	NUM
cet-15395	124	12	,	,	PUNCT
cet-15395	124	13	p.	p.	NOUN
cet-15395	124	14	253261	253261	NUM
cet-15395	124	15	.	.	PUNCT
cet-15395	125	1	adhikiri	adhikiri	PROPN
cet-15395	125	2	s.	s.	PROPN
cet-15395	125	3	,	,	PUNCT
cet-15395	125	4	fernado	fernado	PROPN
cet-15395	125	5	s.	s.	PROPN
cet-15395	125	6	,	,	PUNCT
cet-15395	125	7	gwaltney	gwaltney	PROPN
cet-15395	125	8	s.	s.	PROPN
cet-15395	125	9	,	,	PUNCT
cet-15395	125	10	2007	2007	NUM
cet-15395	125	11	,	,	PUNCT
cet-15395	125	12	a	a	DET
cet-15395	125	13	thermodynamic	thermodynamic	ADJ
cet-15395	125	14	analysis	analysis	NOUN
cet-15395	125	15	of	of	ADP
cet-15395	125	16	hydrogen	hydrogen	NOUN
cet-15395	125	17	production	production	NOUN
cet-15395	125	18	by	by	ADP
cet-15395	125	19	steam	steam	NOUN
cet-15395	125	20	reforming	reforming	NOUN
cet-15395	125	21	of	of	ADP
cet-15395	125	22	glycerol	glycerol	NOUN
cet-15395	125	23	.	.	PUNCT
cet-15395	126	1	international	international	ADJ
cet-15395	126	2	journal	journal	PROPN
cet-15395	126	3	of	of	ADP
cet-15395	126	4	hydrogen	hydrogen	NOUN
cet-15395	126	5	energy	energy	NOUN
cet-15395	126	6	,	,	PUNCT
cet-15395	126	7	p.	p.	NOUN
cet-15395	126	8	2875	2875	NUM
cet-15395	126	9	–	–	PUNCT
cet-15395	126	10	2880	2880	NUM
cet-15395	126	11	.	.	PUNCT
cet-15395	127	1	boros	boros	PROPN
cet-15395	127	2	l.a.d	l.a.d	PROPN
cet-15395	127	3	.	.	PROPN
cet-15395	127	4	,	,	PUNCT
cet-15395	127	5	mathematical	mathematical	ADJ
cet-15395	127	6	and	and	CCONJ
cet-15395	127	7	thermodynamic	thermodynamic	ADJ
cet-15395	127	8	modeling	modeling	NOUN
cet-15395	127	9	of	of	ADP
cet-15395	127	10	solid	solid	ADJ
cet-15395	127	11	-	-	PUNCT
cet-15395	127	12	liquid	liquid	ADJ
cet-15395	127	13	equilibrium	equilibrium	NOUN
cet-15395	127	14	of	of	ADP
cet-15395	127	15	fatty	fatty	NOUN
cet-15395	127	16	systems	system	NOUN
cet-15395	127	17	,	,	PUNCT
cet-15395	127	18	2005	2005	NUM
cet-15395	127	19	,	,	PUNCT
cet-15395	127	20	master	master	NOUN
cet-15395	127	21	's	's	PART
cet-15395	127	22	thesis	thesis	NOUN
cet-15395	127	23	in	in	ADP
cet-15395	127	24	chemical	chemical	NOUN
cet-15395	127	25	engineering	engineering	NOUN
cet-15395	127	26	–	–	PUNCT
cet-15395	127	27	unicamp	unicamp	NOUN
cet-15395	127	28	–	–	PUNCT
cet-15395	127	29	brazil	brazil	PROPN
cet-15395	127	30	.	.	PUNCT
cet-15395	128	1	chaubey	chaubey	PROPN
cet-15395	128	2	r.	r.	PROPN
cet-15395	128	3	,	,	PUNCT
cet-15395	128	4	sahu	sahu	PROPN
cet-15395	128	5	s.	s.	PROPN
cet-15395	128	6	,	,	PUNCT
cet-15395	128	7	james	james	PROPN
cet-15395	128	8	o.o	o.o	PROPN
cet-15395	128	9	.	.	PROPN
cet-15395	128	10	,	,	PUNCT
cet-15395	128	11	maity	maity	PROPN
cet-15395	128	12	s.	s.	PROPN
cet-15395	128	13	,	,	PUNCT
cet-15395	128	14	2013	2013	NUM
cet-15395	128	15	,	,	PUNCT
cet-15395	128	16	a	a	DET
cet-15395	128	17	review	review	NOUN
cet-15395	128	18	on	on	ADP
cet-15395	128	19	development	development	NOUN
cet-15395	128	20	of	of	ADP
cet-15395	128	21	industrial	industrial	ADJ
cet-15395	128	22	processes	process	NOUN
cet-15395	128	23	and	and	CCONJ
cet-15395	128	24	emerging	emerge	VERB
cet-15395	128	25	techniques	technique	NOUN
cet-15395	128	26	for	for	ADP
cet-15395	128	27	production	production	NOUN
cet-15395	128	28	of	of	ADP
cet-15395	128	29	hydrogen	hydrogen	NOUN
cet-15395	128	30	from	from	ADP
cet-15395	128	31	renew	renew	VERB
cet-15395	128	32	able	able	ADJ
cet-15395	128	33	and	and	CCONJ
cet-15395	128	34	sustainable	sustainable	ADJ
cet-15395	128	35	sources	source	NOUN
cet-15395	128	36	.	.	PUNCT
cet-15395	129	1	renewable	renewable	ADJ
cet-15395	129	2	and	and	CCONJ
cet-15395	129	3	sustainable	sustainable	ADJ
cet-15395	129	4	energy	energy	NOUN
cet-15395	129	5	review	review	NOUN
cet-15395	129	6	s	s	NOUN
cet-15395	129	7	,	,	PUNCT
cet-15395	129	8	oxford	oxford	PROPN
cet-15395	129	9	,	,	PUNCT
cet-15395	129	10	v.	v.	ADP
cet-15395	129	11	23	23	NUM
cet-15395	129	12	,	,	PUNCT
cet-15395	129	13	p.	p.	NOUN
cet-15395	129	14	443	443	NUM
cet-15395	129	15	-	-	SYM
cet-15395	129	16	462	462	NUM
cet-15395	129	17	.	.	PUNCT
cet-15395	130	1	edgar	edgar	PROPN
cet-15395	130	2	t.f	t.f	PROPN
cet-15395	130	3	.	.	PROPN
cet-15395	130	4	,	,	PUNCT
cet-15395	130	5	himmelblau	himmelblau	VERB
cet-15395	130	6	d.m	d.m	PROPN
cet-15395	130	7	.	.	PROPN
cet-15395	130	8	,	,	PUNCT
cet-15395	130	9	lasdon	lasdon	PROPN
cet-15395	131	1	l.s	l.s	PROPN
cet-15395	131	2	.	.	PROPN
cet-15395	131	3	,	,	PUNCT
cet-15395	131	4	2001	2001	NUM
cet-15395	131	5	,	,	PUNCT
cet-15395	131	6	optimization	optimization	NOUN
cet-15395	131	7	of	of	ADP
cet-15395	131	8	chemical	chemical	NOUN
cet-15395	131	9	processes	process	NOUN
cet-15395	131	10	,	,	PUNCT
cet-15395	131	11	mcgraw	mcgraw	PROPN
cet-15395	131	12	-	-	PUNCT
cet-15395	131	13	hill	hill	NOUN
cet-15395	131	14	,	,	PUNCT
cet-15395	131	15	2nd	2nd	PROPN
cet-15395	131	16	ed	ed	NOUN
cet-15395	131	17	.	.	PROPN
cet-15395	131	18	,	,	PUNCT
cet-15395	131	19	new	new	PROPN
cet-15395	131	20	york	york	PROPN
cet-15395	131	21	.	.	PUNCT
cet-15395	132	1	freitas	freitas	PROPN
cet-15395	132	2	a.c.d	a.c.d	PROPN
cet-15395	132	3	,	,	PUNCT
cet-15395	132	4	guirardello	guirardello	PROPN
cet-15395	132	5	r.	r.	PROPN
cet-15395	132	6	,	,	PUNCT
cet-15395	132	7	2014	2014	NUM
cet-15395	132	8	,	,	PUNCT
cet-15395	132	9	thermodynamic	thermodynamic	ADJ
cet-15395	132	10	analysis	analysis	NOUN
cet-15395	132	11	of	of	ADP
cet-15395	132	12	methane	methane	NOUN
cet-15395	132	13	reforming	reform	VERB
cet-15395	132	14	with	with	ADP
cet-15395	132	15	co2	co2	NOUN
cet-15395	132	16	,	,	PUNCT
cet-15395	132	17	co2	co2	NOUN
cet-15395	132	18	+	+	CCONJ
cet-15395	132	19	h2o	h2o	NOUN
cet-15395	132	20	,	,	PUNCT
cet-15395	132	21	co2	co2	NOUN
cet-15395	132	22	+	+	CCONJ
cet-15395	132	23	o2	o2	ADJ
cet-15395	132	24	and	and	CCONJ
cet-15395	132	25	co2	co2	NOUN
cet-15395	132	26	+	+	CCONJ
cet-15395	132	27	air	air	NOUN
cet-15395	132	28	for	for	ADP
cet-15395	132	29	hydrogen	hydrogen	NOUN
cet-15395	132	30	and	and	CCONJ
cet-15395	132	31	synthesis	synthesis	NOUN
cet-15395	132	32	gas	gas	NOUN
cet-15395	132	33	production	production	NOUN
cet-15395	132	34	.	.	PUNCT
cet-15395	133	1	journal	journal	NOUN
cet-15395	133	2	of	of	ADP
cet-15395	133	3	co2	co2	NOUN
cet-15395	133	4	utilization	utilization	NOUN
cet-15395	133	5	,	,	PUNCT
cet-15395	133	6	p	p	NOUN
cet-15395	133	7	30	30	NUM
cet-15395	133	8	-	-	SYM
cet-15395	133	9	38	38	NUM
cet-15395	133	10	.	.	PUNCT
cet-15395	134	1	reid	reid	PROPN
cet-15395	134	2	r.c	r.c	PROPN
cet-15395	134	3	.	.	PROPN
cet-15395	134	4	,	,	PUNCT
cet-15395	134	5	prausnitz	prausnitz	PROPN
cet-15395	134	6	j.m	j.m	PROPN
cet-15395	134	7	.	.	PROPN
cet-15395	134	8	,	,	PUNCT
cet-15395	134	9	poling	pole	VERB
cet-15395	134	10	b.e	b.e	PROPN
cet-15395	134	11	.	.	PROPN
cet-15395	134	12	,	,	PUNCT
cet-15395	134	13	1987	1987	NUM
cet-15395	134	14	,	,	PUNCT
cet-15395	134	15	the	the	DET
cet-15395	134	16	properties	property	NOUN
cet-15395	134	17	of	of	ADP
cet-15395	134	18	gases	gas	NOUN
cet-15395	134	19	&	&	CCONJ
cet-15395	134	20	liquids	liquid	NOUN
cet-15395	134	21	,	,	PUNCT
cet-15395	134	22	4th	4th	ADJ
cet-15395	134	23	edition	edition	NOUN
cet-15395	134	24	,	,	PUNCT
cet-15395	134	25	mcgraw	mcgraw	PROPN
cet-15395	134	26	-	-	PUNCT
cet-15395	134	27	hill	hill	PROPN
cet-15395	134	28	,	,	PUNCT
cet-15395	134	29	new	new	PROPN
cet-15395	134	30	york	york	PROPN
cet-15395	134	31	.	.	PUNCT
cet-15395	135	1	870	870	NUM
cet-15395	135	2	cet-vol117-b.pdf	cet-vol117-b.pdf	NUM
cet-15395	135	3	56gomessilva.pdf	56gomessilva.pdf	NUM
cet-15395	135	4	synthesis	synthesis	NOUN
cet-15395	135	5	of	of	ADP
cet-15395	135	6	global	global	ADJ
cet-15395	135	7	reaction	reaction	NOUN
cet-15395	135	8	routes	route	NOUN
cet-15395	135	9	using	use	VERB
cet-15395	135	10	thermodynamic	thermodynamic	ADJ
cet-15395	135	11	evaluation	evaluation	NOUN
