item: #1 of 303 id: chimtech-1047 author: Zhuk, S. I.; Minchenko, L. M.; Chemezov, O. V.; Malkov, V. B.; Isakov, A. V.; Zaikov, Yu. P. title: Silicon phase origin on glassy carbon in KF-KCl-K2SiF6 fusion date: 2014-09-30 words: 1780 flesch: 101 summary: Из SEM-микрофотографий за- родышей кремния, выращенных на стеклоуглеродной подложке в по- тенциостатическом режиме в интер- вале потенциалов от –0.005 до –0.03 В в расплаве KF-KCl-K2SiF6 при Т = 675 °С, видно, что в условиях од- ного эксперимента они имеют разме- ры, различающиеся в несколько раз, что подтверждает прогрессирующий характер возникновения зародышей кремния. С. И. Жук, Л. М. Минченко, О. В. Чемезов, В. Б. Малков, А. В. Исаков, Ю. П. Зайков. 69 2014 | № 2 | CTAФазозарождение кремния на стеклоуглероде в расплаве KF-KCl-K2SiF6 Результаты и обсуждение На начальных участках хроноам- перометрических кривых был зареги- стрирован пик, относящийся к зарядке двойного электрического слоя (рис. 1). keywords: k2sif6; kcl; зародышей; кремния; при; расплаве; что cache: chimtech-1047.pdf plain text: chimtech-1047.txt item: #2 of 303 id: chimtech-1094 author: Farlenkov, A. S.; Anan’ev, M. V. title: Modeling of a microstructure and calculation of a tortuosity factor for cathodic materials of LSM–YSZ date: 2015-03-29 words: 3968 flesch: 81 summary: По-видимому, процесс межфазного обмена кислорода на ТФГ протекает достаточно быстро по сравнению с об- меном кислорода на индивидуальных компонентах LSM и YSZ. По проведенной 3D-реконструкции микроструктуры электродов симметричных ячеек (рис. 4), получена зависимость ТФГ (кон- такт между LSM | YSZ | O2) от времени. keywords: factor; fig; lsm; material; microstructure; oxygen; tortuosity; ysz; для; извилистости; материала; микроструктуры; рис cache: chimtech-1094.pdf plain text: chimtech-1094.txt item: #3 of 303 id: chimtech-1095 author: Lyagaeva, Ju. G.; Medvedev, D. A. title: Structure and transport properties of composite materials on a basis of Ce0.8Nd0.2O2-δ and BaCe0.8Nd0.2O3-δ date: 2015-03-29 words: 4379 flesch: 78 summary: Concentration dependence of the ion (a), electron (b) and hole (c) conductivity and activation energy for (1–x) Ce0.8Nd0.2O2–δ– xBaCe0.8Nd0.2O3–δ ceramics in the wet air a b c Structure and transport properties of composite materials on a basis of Ce 0.8 Nd 0.2 O 2-δ and BaCe 0.8 Nd 0.2 O 3-δ 36 № 1 | 2015 Chimica Techno Acta the system «perovskite-fluorite» tend to be higher than for basic oxides as Ce0.8Nd0.2O2–δ and BaCe0.8Nd0.2O3–δ, which confirms the phenomenon of blocking both the electron and hole conductivity in composites(1–3). The temperature dependence of the conductivity of (1–x) Ce0.8Nd0.2O2–δ– xBaCe0.8Nd0.2O3–δ materials is shown in Fig. keywords: ce0.8nd0.2o2; conductivity; fig; materials; xbace0.8nd0.2o3; для; материалов; проводимость; рис cache: chimtech-1095.pdf plain text: chimtech-1095.txt item: #4 of 303 id: chimtech-1096 author: Zhuk, S. I.; Minchenko, L. M.; Chemezov, O. V.; Malkov, V. B.; Isakov, A. V.; Zaikov, Yu. P. title: RETRACTED: Silicon phase origin on glassy carbon in KF-KCl-K2SiF6 fusion date: 2015-03-29 words: 3475 flesch: 79 summary: Фазозарождение кремния на стеклоуглероде в расплаве KF–KCl–K 2 SiF 6 RE TR AC TE D 47 № 1 | 2015 Chimica Techno Acta Результаты и обсуждение На начальных участках хроноам- перометрических кривых был зарегис- трирован пик, относящийся к зарядке двойного электрического слоя (рис. 1). Полученные хроноамперометриче- ские зависимости в расплаве KF–KCl– K2SiF6 при Т = 675 ºС в зависимости от приложенных потенциалов интервале от –0,05 до –0,15 В относительно крем- ниевого электрода сравнения пред- ставлены на рис. keywords: carbon; electrode; glassy; k2sif6; kcl; silicon; кремния; при; расплаве cache: chimtech-1096.pdf plain text: chimtech-1096.txt item: #5 of 303 id: chimtech-1097 author: Khazhieva, I. S.; Glukhareva, T. V.; Morzherin, Yu. Yu. title: Reaction of 4-acetyl-1,2,3-triazol-5-olate with hydrazine derivatives date: 2015-03-29 words: 2773 flesch: 91 summary: H Found, %: C 55,15 H 5,80 N 26,80. keywords: -nh cache: chimtech-1097.pdf plain text: chimtech-1097.txt item: #6 of 303 id: chimtech-1098 author: Kaymieva, O. S.; Morozova, M. V.; Buyanova, E. S. title: Synthesis and investigation of La1-xBixMn1-yFeyO3-δ structure date: 2015-03-29 words: 2154 flesch: 78 summary: Точное содержание Mn и Fe определить не удалось из-за наложения линий приэнергии 6,4 кэВ. Для определения содержания Mn и Fe в образцах с помощью АЭС-ИСП были выбраны характеристические ли- нии этих элементов Mn (257,6; 259,3; 279,4 нм) и Fe (218,7; 239,5; 259,8; 274,9; 371,9 нм). Найденный элементный состав соответствует значени- ям, заявленным в формуле. keywords: method cache: chimtech-1098.pdf plain text: chimtech-1098.txt item: #7 of 303 id: chimtech-1099 author: Terenteva, Yu. V.; Fomina, L. V.; Beznosyuk, S. A. title: Physicochemical conditions for the stability of manganese-doped nanolayers of gallium arsenide and its iso-electronic analogues date: 2015-03-29 words: 4535 flesch: 77 summary: При размере кластера в 4 элементар- ные ячейки To calculate the parameters {εij (r)} of pair binding energy of atoms in structures AIIIBV MnAs, the method of non-local functional density was used6. keywords: aiiibv; alas; atoms; cluster; manganese; mnas; model; nanolayers; size; stability; structure; атомов; для; кластера; марганца; структуры cache: chimtech-1099.pdf plain text: chimtech-1099.txt item: #8 of 303 id: chimtech-1100 author: Komarovskih, N. V.; Fomina, L. V.; Beznosyuk, S. A. title: Physicochemical conditions of GaAs/GaAsxNy/GaN nanochips stability date: 2015-03-29 words: 3688 flesch: 79 summary: Свободную поверхностную энер- гию гетероструктур GaAs/GaAsxNy/ GaN можно определить по формуле: U E E E / /x y x y = − − − GaAs GaAs N GaN GaN GaAs GaAs N/ . Another advantage of GaAs substrates is the possibility to use different crystallographic surfaces for GaN film growth, which allows setting epitaxial growth orientation of the surface layer of GaN crystal structure of GaN at the initial stage. keywords: atoms; energy; gaas; gaasxny; gan; layer; nanochips; nitrogen; structure; surface; азота; атомов; для; наночипов cache: chimtech-1100.pdf plain text: chimtech-1100.txt item: #9 of 303 id: chimtech-1102 author: Pershin, P. S.; Burich, A. A.; Khalimullina, Yu. R.; Arkhipov, P. A.; Zaikov, Yu. P. title: Electrode processes during the electrorefiniment of lead in the KCl-PbCl2-PbO melt date: 2015-05-27 words: 2780 flesch: 84 summary: от концентрации PbO в расплаве и плотности тока представле- ны в табл. В зависимости от концентрации PbO в хлоридном рас- плаве, осажденный оксид может снова раствориться в расплаве с низкой кон- центрацией PbO, а в насыщенном по оксиду свинца расплаве останется на поверхности катода или будет присут- ствовать в приэлектродном катодном пространстве. keywords: cathode; current; kcl; lead; melt; pbcl2; pbo; расплаве; свинца; току cache: chimtech-1102.pdf plain text: chimtech-1102.txt item: #10 of 303 id: chimtech-1120 author: Poluikova, A. A.; Platonova, A. Yu.; Glukhareva, T. V.; Morzherin, Yu. Yu. title: Synthesis of 5-thiocarbomoyl- and 5-(thiazol-2-yl)-2,3,4,4a,5,6-hexahydro-1Н-pyrido[1,2-a]quinoline-5-carbonitriles date: 2015-05-27 words: 3683 flesch: 88 summary: These include the cyclization of conjugate N, N-disubstituted amines, a key stage in which is the transfer of hy- drogen from the formally non-activated α-carbon atom of the dialkylamino group to one of the atoms of an unsaturated substituent such as, for ex-ample, C = C, C = N, N = O , C = O, etc. Методика получения соединения 2 К раствору 2,0 ммоль цианацет- тиоамида в 8,0 мл этанола добавляют 2,0 ммоль α-бромацетофенона. keywords: arh; reaction cache: chimtech-1120.pdf plain text: chimtech-1120.txt item: #11 of 303 id: chimtech-1121 author: Reznikova, O. G.; Darintseva, A. B.; Murashova, I. B. title: About the stabilization of the dendritic structure of GG brand copper powder date: 2015-05-27 words: 3530 flesch: 81 summary: Изменение диаметра электрода с осадком (О) и катодного перенапряжения (линия) в ходе трехимпульсного электролиза 124 № 2 | 2015 Chimica Techno Acta Резникова О. Г., Даринцева А. Б., Мурашова И. Б. до 2500 с, диаметр электрода с осад- ком к моменту остановки процесса составляет 6 мм. Current pulse increases the cathode overvoltage; dendritic precipitate at the time of switching current begins to de- velop more actively. keywords: current; diameter; electrode; electrolysis; fig; pulse; sediment; осадка; осадком; при; рис; тока; электрода cache: chimtech-1121.pdf plain text: chimtech-1121.txt item: #12 of 303 id: chimtech-1123 author: Karpov, V. V.; Bazhenov, A. V.; Abramov, A. V.; Polovov, I. B.; Rebrin, O. I. title: Corrosion resistance of alloys of Hastelloy in chloroaluminate melts date: 2015-05-27 words: 2300 flesch: 73 summary: The experimental part This work is aimed at a comprehen- sive study of the interaction of high-tem- perature alloys Hastelloy S, Hastelloy X, Haynes 230, and corrosion-resistant al- loys Hastelloy N, Hastelloy G35 and Has- telloy C2000 with chloroaluminate melts. Факс: (343) 374-54-91, тел.: (343) 375-41-51; E-mail: polovov@dpt.ustu.ru Коррозионная стойкость сплавов семейства «Hastelloy хастеллой» в хлоралюминатных расплавах Изучена коррозия сплавов Hastelloy S, Hastelloy X, Haynes 230, Hastelloy N, Hastelloy G35 и Hastelloy C2000 в расплавах KCl–AlCl 3 при 550 °С. Опреде- лены скорости и механизмы коррозии исследуемых материалов в данных условиях. keywords: alcl3; alloys; corrosion; g35; hastelloy; kcl; сплавов cache: chimtech-1123.pdf plain text: chimtech-1123.txt item: #13 of 303 id: chimtech-1124 author: Urusova, A. S.; Bryuzgina, A. V.; Aksenova, T. V.; Cherepanov, V. A. title: Crystal structure and oxygen nonstoichiometry of oxides in the Ba-Me-Me’-Y-O (Me, Me’=Co, Fe) system date: 2015-05-27 words: 3151 flesch: 75 summary: Параметры элементарных яче- ек однофазных оксидов были рассчита- ны в программе “Сelref-3” и уточнены методом полнопрофильного анализа Ритвелда в программе “Fullprof-2008”. BaCo1–xYxO3–δ и BaFe0,9–yY0,1CoyO3–δ от температуры (в диапазоне 273–1373 K) изучали ме- тодом термогравиметрического анали- за (ТГА) на воздухе. keywords: baco1; oxygen; xyxo3 cache: chimtech-1124.pdf plain text: chimtech-1124.txt item: #14 of 303 id: chimtech-1126 author: Khalymbadzha, I. A.; Deev, S. L.; Shestakova, T. S.; Rusinov, V. L.; Chupakhin, O. N. title: Synthesis of acyclic nucleoside analogues based on 1,2,4-triazolo[1,5-a]pyrimidine-7-ones by one-step Vorbrüggen glycosylation date: 2015-05-27 words: 1919 flesch: 80 summary: Boechat N., Pinheiro L. C. S., Silva T. S., Carvalho A. S., Bastos M. M., Costa C. C., Mendonca J. S., Dutra K. D., Santos-Filho O. A., Pinto A. C., Aguiar A. C., Ceravolo I. P., Krettli A. U., Pinheiro S., Valverde A. L. New trifluoromethyl triazolopyrimidines as Anti-Plasmodium falciparum agents. Boechat N., Pinheiro L. C. S., Silva T. S., Carvalho A. S., Bastos M. M., Costa C. C., Mendonca J. S., Dutra K. D., Santos-Filho O. A., Pinto A. C., Aguiar A. C., Ceravolo I. P., Krettli A. U., Pinheiro S., Valverde A. L. New trifluoromethyl triazolopyrimidines as Anti-Plasmodium falciparum agents // Molecules. 2012. keywords: 1,2,4 cache: chimtech-1126.pdf plain text: chimtech-1126.txt item: #15 of 303 id: chimtech-1127 author: Bakanov, V. M.; Maskaeva, L. N.; Markov, V. F. title: Thermosensitization of nanostructured PbSe films date: 2015-05-27 words: 2377 flesch: 78 summary: 2 shows the dependence of the photo-response of PbSe films from the time they were annealed at temperatures of 648, 673 and 698 K. Dependencies have pronounced maximum of response, which with increasing temperature shifts toward shorter annealing. It is found that the decrease in crystallite sizes, which form PbSe films, contributes to a signifi- cant increase in the level of its photore- sponse. keywords: films; layers; lead; pbse; selenide; для; пленок; при; свинца; слоев cache: chimtech-1127.pdf plain text: chimtech-1127.txt item: #16 of 303 id: chimtech-1161 author: Savateeva, E. A.; Emelyanov, V. V.; Musalnikova, A. V.; Sidorova, L. P.; Maksimova, N. E.; Machulskaya, N. N.; Chereshnev, V. A. title: Sulfur-containing heterocyclic compounds with potential antidiabetic activity date: 2014-12-31 words: 1171 flesch: 91 summary: и производными 1,3,4-тиадиазина, в процентах к уровню контрольного опыта Е. А. Саватеева, В. В. Емельянов, А. В. Мусальникова, Л. П. Сидорова, Н. Е. Максимова, Н. Н. Мочульская, В. А. Черешнев 85 2014 | № 3 | CTA Серосодержащие гетероциклические соединения с потенциальной противодиабетической активностью зой и промежуточными карбонильны- ми продуктами НГБ В этих условиях преобладает образование ФА по ами- ногруппе G-SH, в связи с чем уровень ФА в модельной системе на поздних сроках инкубации повышался. keywords: 1,3,4; накопление; нгб cache: chimtech-1161.pdf plain text: chimtech-1161.txt item: #17 of 303 id: chimtech-1183 author: Patrushev, A. V.; Ostanina, T. N.; Rudoy, V. M.; Vereshchagina, A. V.; Zalesova, O. L.; Soloviev, A. S.; Shtirba, N. I. title: The choice of the conditions to receive the electrolytic zinc powders for metal-rich compositions date: 2015-03-29 words: 3737 flesch: 77 summary: Measurements have shown that the electrical conductivity of zinc-rich coatings containing electrolytic zinc powder, not inferior to the conductivity of the film with powder PZHD-0 obtained by the method of evaporation-condensation, despite the sig- nificant difference in the amount of zinc pigment. On the basis of the received data we can conclude that the use of electrolytic zinc powder as a pigment will significantly save zinc. keywords: current; dendrites; metal; pigment; powder; precipitation; zinc; дендритов; для; цинка cache: chimtech-1183.pdf plain text: chimtech-1183.txt item: #18 of 303 id: chimtech-1233 author: Suzdaltsev, A. V.; Khramov, A. P.; Zaikov, Yu. P.; Limanovskaya, O. V.; Nekrasov, V. N. title: Chronopotentiometry at platinum electrode in KF-NaF-AlF3-Al2O3 melt date: 2015-10-06 words: 3268 flesch: 78 summary: Мира, 19. E-mail: limanovskaya@yandex.ru Хронопотенциометрия на платине в расплаве KF-NaF-AlF 3 -Al 2 O 3 * Методом хронопотенциометрии были исследованы некоторые особенно- сти механизма анодного процесса на платине в расплаве KF–NaF–AlF 3 –Al 2 O 3 при 750–780 °C в зависимости от анодной плотности тока (от 0,5 мА/см2 до 2,0 А/см2) и длительности анодного импульса. Its expression is observed for the system under study with an increase in the magnitude of anode current density from 0.5 A/cm2 (Fig. 1b), at that the transition times are from 2 ms to 10–15 s. Chronopotentiometry at platinum electrode in KF-NaF-AlF 3 -Al 2 O 3 melt 192 № 3 | 2015 Chimica Techno Acta Analysis of curves of change in the platinum potential under current inter- ruption points indicates a long period of term relaxation of the platinum potential as after the anode current density pulse of value of 30 mA/cm2 (30–35 s), so after pulses of value of 0.5–2.0 A/cm2 (10–15 s). keywords: al2o3; anode; cm2; current; naf; platinum; при; см2; тока cache: chimtech-1233.pdf plain text: chimtech-1233.txt item: #19 of 303 id: chimtech-1276 author: Dolmatova, E. A.; Dayanov, A. D.; Ostanina, T. N. title: Simulation of an electrolytic bath for electrodeposition of multilayer shielding coatings date: 2015-10-06 words: 3032 flesch: 72 summary: С помощью метода математиче- ского моделирования материальных балансов гальванической ванны и сборной емкости определены состав входящего циркуляционного потока в ванну, а также скорость и состав кор- ректирующего потока в сборную ем- кость. Однов- ременно в сборную емкость подается корректировочный поток (ϑкорр), в ко- тором концентрация ацетатов меди и никеля выше, чем в ванне. keywords: bath; copper; electrolyte; mol; nickel; vessel; для; меди cache: chimtech-1276.pdf plain text: chimtech-1276.txt item: #20 of 303 id: chimtech-1277 author: Nikitin, V. S.; Ostanina, T. N.; Rudoi, V. M.; Farlenkov, A. S. title: Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes date: 2015-10-06 words: 2926 flesch: 69 summary: 208 V. S. Nikitin, Т. N. Ostanina, V. М. Rudoy, А. S. Farlenkov Ural Federal University, 19, Mira str., Ekaterinburg, Russia, E-mail: nikitin-viachieslav@mail.ru Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes In the work the dynamics of growth of zinc dendritic deposits in the galva- nostatic and potentiostatic modes from an electrolyte containing 0.3 mol/L of ZnO, and 4 mol/L of NaOH has been studied. keywords: change; dendrites; dendritic; density; deposits; fig; galvanostatic; zinc; осадков; рис cache: chimtech-1277.pdf plain text: chimtech-1277.txt item: #21 of 303 id: chimtech-1278 author: Kylosova, O. V.; Ilbuldina, A. B.; Yaroslavtseva, O. V. title: Study of instantaneous rate of corrosion of aluminum in media with different acidity date: 2015-10-06 words: 2581 flesch: 73 summary: на мгновенная скорость коррозии алюминия в средах с различной кислотно- стью. A resulting time series of instantaneous corrosion rate have been analyzed us- ing the standardized range. keywords: aluminum; corrosion; polarization; rate; resistance; solution; time; коррозии; скорости; сопротивления cache: chimtech-1278.pdf plain text: chimtech-1278.txt item: #22 of 303 id: chimtech-1279 author: Titov, A. G.; Gil'vanova, Z. R.; Shevchenko, E. A.; Masnaviev, M. K.; Bir, A. A. title: Quantitative assessment of reentrainment in the electrocyclone date: 2015-10-06 words: 2532 flesch: 78 summary: 3 видно, что в  мокром режиме при U = 17 кВ (электроциклон- ный режим) унос составляет менее 1 %, при снижении напряжения до Мира, 28. E-mail: paht@yandex.ru Количественная оценка вторичного уноса в электроциклоне* Статья посвящена исследованию вторичного уноса – паразитного явле- ния, возникающего в газоочистных устройствах, – электроциклонах. keywords: ash; electrocyclone; fig; gas; mode; reentrainment; вторичного; при; уноса cache: chimtech-1279.pdf plain text: chimtech-1279.txt item: #23 of 303 id: chimtech-1281 author: Medvedeva, N. R.; Sapozhnikova, I. S.; Rusinov, V. L.; Ulomsky, E. N. title: The redox transformations and nucleophilic replacements as possible metabolic reactions of the drug “Triazaverin”. The chemical modeling of the metabolic processes date: 2015-10-06 words: 5709 flesch: 79 summary: 9,84 (1H, уш.с., NH), 3,05 (3Н, с, CH3); 13C NMR (DMSO-d6, 100 MHz): 169,09 (C2), 157,32 (C3a), 144,05 (C7), 143,57 (C6), 25,58 (СН3SO); IR (ν/sm –1): 1750 (С=O); 1036 (–SO-); 1553,1340 (NO2); Элемент. анализ С5H4N6O4S, вычислено %: С  – 24,59, H  – 1,65, N  – 34,42, найдено, %: C – 24,62, H – 1,43, N – 34,28. (1H, уш.с., NH), 3,41 (3Н, с, CH3); 13C NMR (DMSO-d6, 100 MHz): 163,86 (C2), 158.41 (C3a), 144,69 (C7), 143,64 (C6), 41,84 (СН3SO2); IR (ν/sm–1): 1759 (С = O); 1347, 1138 (–SO2 –); 1570, 1323 (NO2); Элементный анализ С5H4N6O5S, вычислено %: С  – 23,08, H  – 1,55, N  – 32,30, найдено, %: C – 23,21, H – 1,31, N – 32,33. keywords: dmso; mhz; nmr; no2 cache: chimtech-1281.pdf plain text: chimtech-1281.txt item: #24 of 303 id: chimtech-1538 author: Bezmaternykh, M. A.; Selezneva, I. S title: Milestones of chemical technology institute: our past and present date: 2015-10-06 words: 7046 flesch: 60 summary: The main scientific research fields of the department relate to: Ȥ development of heat and mass trans- fer apparatus based on the Venturi tube; Ȥ implementation of high-speed spray type apparatus for the treatment of pro- cess gases in a variety of productions; Ȥ removal of harmful impurities, cool- ing, absorption; Ȥ development of systems of gas puri- fication from dust, mist, vapor, based on ejection type scrubbers; Ȥ modernization of evaporation and heat exchange equipment, boiler deaerators; Ȥ study of wear of parts of hydraulic machines at cavitation and hydroabrasive impact; Ȥ development of apparatus in the field of resource and energy saving tech- nologies; Ȥ use of hydrodynamic cavitation sys- tems for dissipative heating; homogeniz- ing and pasteurizing liquids for food and industrial use; Ȥ applying the principle of evapora- tion-condensation heat exchange to cre- ate technological and power equipment, utilization of secondary energy resources; Ȥ development and implementation of energy technological complexes, provid- ing the ultimate closure of material and energy flows within the unit, department, factory; Ȥ investigation of processes and devel- opment of equipment for the food industry. Основными научными направлени- ями работы кафедры являются: Ȥ оптимизация процессов перера- ботки углей и  получаемых из них при различных пирогенетических процес- сах продуктов; Ȥ экологическая экспертиза проек- тов и  разработка экологической про- ектной документации. keywords: acta; chemical; chemical technology; chemistry; chimica; department; development; institute; organic; present; professor; research; sciences; students; synthesis; technology; university; ural; года; году; для; кафедра; настоящее; профессор; разработка; технология cache: chimtech-1538.pdf plain text: chimtech-1538.txt item: #25 of 303 id: chimtech-1544 author: Panteleeva, V. V.; Shein, A. B.; Kamenschikov, O. Yu. title: The impedance of anodic pro-cesses on passive NiSi-electrode in sulfuric fluoride containing electrolyte date: 2016-03-15 words: 3590 flesch: 78 summary: M NaF в области пассивного состояния. Микроскопическое исследование NiSi до и после электрохимических испытаний показывает, что анодное травление силицида при E области пассивного состояния в 0,5 М H2SO4 + +  0,05М keywords: anodic; electrode; film; fluoride; h2so4; impedance; layer; naf; nisi; solution; при cache: chimtech-1544.pdf plain text: chimtech-1544.txt item: #26 of 303 id: chimtech-1545 author: Melnikova, A. V.; Figilyantov, F. P.; Shein, A. B. title: Investigation of industrial compositions SONKOR as corrosion inhibitors of mild steel in neutral media containing hydrogen sulfide date: 2015-10-06 words: 3429 flesch: 72 summary: Гравиметри- ческим методом было изучено защит- ное действие ингибиторов в  концен- трациях: 0,025; 0,050; 0,100; 0,200 г/л. Одновременное присутствие в  кор- розионной среде Н2S и  О2 приводит к  еще большему разрушению металла, поскольку возможно протекание реак- ции, в  которой промежуточный про- дукт Н2S2 является деполяризатором, равным по силе кислороду keywords: corrosion; h2s; hydrogen; inhibitors; nacl; sonkor; steel; sulfide; ингибиторов; коррозии; сонкор cache: chimtech-1545.pdf plain text: chimtech-1545.txt item: #27 of 303 id: chimtech-1649 author: Tkach, V. V.; de Oliveira, C. S.; Maia, J.; Soares, B. G.; Ojani, R.; Yagodynets, P. I. title: The mathematical description of the electrosynthesis of composites of oxy-hydroxycompounds cobalt with polypyrrole overooxidazed date: 2016-03-15 words: 6916 flesch: 80 summary: Его окси-гидрокси- соединения в форме пленок могут применяться в качестве противокор- розионных покрытий, а также в каче- стве поверхностей-носителей для фо- тоэлектрокатализа, −       2 0d d , (1) где h0 – это концентрация протонов в  объеме раствора, ro – скорость про- цесса переокисления, ra – скорость протонной атаки переокисленного по- лимера. keywords: cobalt; nechyporuk; polypyrrole; tkach; tkach v.; yagodynets; − ;  ;  cache: chimtech-1649.pdf plain text: chimtech-1649.txt item: #28 of 303 id: chimtech-1677 author: Ivanov, M. G.; Nechaev, A. V.; Mokrushin, V. S.; Ostroukhova, O. I. title: The effect of fluorine-containing inhibitors of corrosion of copper in atmospheric conditions date: 2016-03-15 words: 1937 flesch: 69 summary: Однако только характер поляриза- ционных кривых не позволяет одно- значно судить о влиянии ингибитора на коррозионную стойкость меди в ат- мосферных условиях. Влияние фторсодержащих ингибиторов на коррозию меди в атмосферных условиях keywords: compositions; copper; corrosion; curves; pfa; polarization; меди; при; пфа cache: chimtech-1677.pdf plain text: chimtech-1677.txt item: #29 of 303 id: chimtech-1679 author: Zvereva, I.; Pavlova, T.; Pantchuk, V.; Semenov, V.; Breard, Y.; Choisnet, J. title: The solid solution Sr3Ti2-xFexO7-δ (x ≤ 0.5): characterization of Fe (III) – Fe (IV) mixed valences date: 2016-03-15 words: 5402 flesch: 65 summary: Keywords: layered oxides; solid solutions; iron; mixed valence; magnetic susceptibility; Mössbauer spec- trometry. As it was previously performed in the chro- mium containing solid solution Sr3Ti2-x CrxO7-δ keywords: air; compositions; fe4; iron; oxygen; solid; solution cache: chimtech-1679.pdf plain text: chimtech-1679.txt item: #30 of 303 id: chimtech-1687 author: Khaikina, G. E.; Solodovnikov, S. F.; Basovich, O. M.; Solodovnikova, Z. A.; Kadyrova, Yu. M.; Savina, A. A.; Zolotova, E. S.; Yudin, V. N.; Spiridonova, T. S. title: Triple molybdates one-, one - and three(two)valence metals date: 2015-12-25 words: 13233 flesch: 84 summary: Triple molybdates of the type 1-1-3 The first systematic searching re- searches of triple molybdates of one-, one-, and trivalent metals were conducted for lithium-containing systems Li2MoO4– M2MoO4–R2(MoO4)3 (M = K–Cs, Tl, Ag, R = Bi, Ln, Y, In, Sc, Fe, Ga, Cr, Al). Solodovnikova3, Y. M. Kadyrova1, A. A. Savina1,2, E. S. Zolotova3, V. N. Yudin3,4, T. S. Spiridonova1,2 1 FSBUN Baikal Institute of nature management SB RAS, 670047, Ulan-Ude, Sakhyanovoy str., 6 2 FSBGU HPE “Buryat state University”, 670000, Ulan-Ude, Smolina str., 24a 3 Institute of inorganic chemistry Sibiryan Branch RAS, 630090, Novosibirsk, prospect Akademika Lavrentyeva, 3 4 Federal state Autonomous educational institution “Novosibirsk national research state University”, 630090, Novosibirsk, Pirogov str., 2 egkha@mail.ru, solod@niic.nsc.ru Triple molybdates one-, one - and three(two)valence metals the review summarizes experimental data on the phase formation, structure and properties of new complex oxide compounds group – triple molybdates containing tetrahedral molybdate ion, two different singly charged cation, to- gether with tri- or divalent cation. keywords: a. a.; acta; basovich; chimica; compounds; cs2moo4; cs6zn5(moo4)8; fig; formation; khaikina; li2moo4; molybdates; phase; solid; solodovnikov; structure; systems; techno; triple; z. a.; молибдатов; тройных; хайкина cache: chimtech-1687.pdf plain text: chimtech-1687.txt item: #31 of 303 id: chimtech-1688 author: Editors, Chimica Techno Acta title: Vladimir Mikhailovich Zhukovsky date: 2015-12-25 words: 1432 flesch: 71 summary: В 1964 г. были защищены первые дипломные работы по физической химии твердого тела, а в 1965 г. – созданы первые экспе- риментальные установки термическо- го и термогравиметрического анализа. Инженерно-техниче- скую деятельность начинал в атомной промышленности на старейшем в keywords: chemical; chemistry; mikhailovich; vladimir; твердого; тела; химии cache: chimtech-1688.pdf plain text: chimtech-1688.txt item: #32 of 303 id: chimtech-1689 author: Zuev, A. Yu.; Tsvetkov, D. S. title: Oxygen non-stoichiometry and defect structure of LaMn1-zCuzO3+δ date: 2015-12-25 words: 4834 flesch: 81 summary: +/// ///  (2) with the equilibrium constant K O V V Mn Mn O La Mn Mn Mn 2 3 6 =     ⋅ ′′′  ⋅ ′′′    ⋅         × ×   ⋅ 6 3 2 2 pO , where MnMn ´ и MnMn  – Mn+3 и Mn+4, respectively, as well as the disproportion- ation of manganese 2Mn Mn MnMn Mn Mn × ⇔ + / (3) with the equilibrium constant K Mn Mn Mn Mn Mn Mn 3 2=    ⋅         ×  / , where 2Mn Mn MnMn Mn Mn × ⇔ + / , together with the relevant conditions of mass bal- ance and electroneutrality, we obtain the system of equations that defines the model of the defect structure of LaMn1-zCuzO3+δ (4) 2Mn Mn MnMn Mn Mn × ⇔ + / (3) с константой равновесия K Mn Mn Mn Mn Mn Mn 3 2=    ⋅         ×  / , , где Mn MnMn / − +2 , keywords: k mn; mn cu; mn mn; mn o; mn ×; oxygen; structure;   cache: chimtech-1689.pdf plain text: chimtech-1689.txt item: #33 of 303 id: chimtech-1691 author: Buyanova, E. S.; Emelyanova, Yu. V.; Morozova, M. V.; Mikhailovskaya, Z. A.; Kaymieva, O. S.; Zhukovskiy, V. M.; Petrova, S. A. title: Crystal structure and conductivity of bismuth-containing complex oxides date: 2015-12-25 words: 7565 flesch: 71 summary: Зависимость объема элементарной ячейки от состава: 1 – Bi13Mo5–yFeyO34±δ; 2 – Bi13–xCaxMo5O34±δ; 3 – Bi4V2–xFex/2Nbx/2O11–δ; 4 – Bi4V2–xFexO11-δ Буянова Е. С., Емельянова Ю. В., Морозова М. В., Михайловская З. А., Каймиева О. С., Жуковский В. М., Петрова С. А. 321 № 4 | 2015 Chimica Techno Acta Оценка элементного состава иссле- дуемых фаз, взятых в виде порошка, либо вблизи поверхности и в объеме спеченных брикетов методами атом- ной спектроскопии и электронной микроскопии выявила, что не всегда реализуется равномерное распределе- ние атомов в структурах твердых рас- творов. Коэффициенты термического расширения обеих фаз близки, единственным отличием меж- ду ними является область 973–1073 K, в которой для фазы δ/ наблюдается аномалия параметров элементарной ячейки, связанная с началом распада. keywords: bi13; bimevox; bismuth; buyanova; conductivity; doi; e. s.; journal; morozova; oxides; petrova; petrova s.; phase; s. a.; solutions; structure; synthesis; temperature; v. m.; zhukovskiy v.; висмута; для; при cache: chimtech-1691.pdf plain text: chimtech-1691.txt item: #34 of 303 id: chimtech-1692 author: Guseva, A. F.; Trifonova, M. V. title: Surface reactions with participation of oxides of molybdenum and tungsten date: 2015-12-25 words: 9120 flesch: 78 summary: Surface reactions with participation of oxides of molybdenum and tungsten The kinetics of surface reactions in one-dimensional and radial (two-dimensional) distribution of diffusant MoO 3 (WO 3 ) on the surface of the substrate MeO (Me is Cd, Ni, Pb, Mn, Cu) were investigated. Keywords: diffusant; molybdates; complex oxides; surface reaction diffusion; scanning electron microscopy (SEM) keywords: diffusant; diffusion; distribution; fig; length; moo3; nio; product; radial; reaction; substrate; surface; surface layer; surface reactions; time; диффузанта; диффузии; для; поверхностного; подложки; при; продукта; реакции; рис; слоя; что cache: chimtech-1692.pdf plain text: chimtech-1692.txt item: #35 of 303 id: chimtech-1693 author: Kosova, N. V.; Podgornova, O. A. title: Supervalent doping of LiFePO4 for enhanced electrochemical performance date: 2015-12-25 words: 6330 flesch: 83 summary: Очевидно, что LVP образует более мелкие частицы, предпочтительно на поверхности более крупных частиц LFP, таким образом, вероятно, увели- чивая поверхность для диффузии ио- нов Li в композите. Это плато соответствует рабочей паре Ti4+/Ti3+ в LTP. keywords: acta; chem; chimica; doi; doping; ions; lfp; lftp; lfvp; lifepo4; lithium; ltp; lvp; structure; для; при; что cache: chimtech-1693.pdf plain text: chimtech-1693.txt item: #36 of 303 id: chimtech-1694 author: Animitsa, I. E.; Kochetova, N. A. title: Crystal structure and imperfection of the perovskite-like proton conductor Ba4Ca2Nb2O11 date: 2016-03-15 words: 7533 flesch: 82 summary: Зависимость концентрации протонных дефектов в структуре Ba4Ca2Nb2O11 × Представленные расчеты для моде- ли структурных вакансий кислорода демонстрируют отличие от случая вне- дрения воды в сложные оксиды с при- месным разупорядочением. keywords: 1/3; acta; atoms; ba4ca2nb2o11; chimica; concentration; defects; o o; oxygen; proton; structure; techno; vacancies; water; воды; дефектов; как; кислорода; протонных; рн2о cache: chimtech-1694.pdf plain text: chimtech-1694.txt item: #37 of 303 id: chimtech-1719 author: Guseva, A. F.; Trifonova, M. V.; Pestereva, N. N. title: Surface reactions with participation of oxides of molybdenum and tungsten: the influence of external factors date: 2016-03-15 words: 6575 flesch: 81 summary: Длина поверхностного слоя в за- висимости от величины напряжения и направления пропускания электри- ческого тока варьируется от 1200 до 2000 мкм, а толщина слоя в месте кон- такта от 3 до 24 мкм Таким образом, воздействие элек- трического поля в диапазоне значений U = –300 …+300В позволяет изменить ℓs в 1,7 раз, а ℓ – в 8 раз. Это свидетельствует о различии механизма массопереноса на повер- хности и в месте контакта. keywords: briquettes; contact; diffusion; field; fig; layer; mass; mn2o3; moo3; oxygen; po2; product; rate; reaction; surface; synthesis; для; реакции; рис; скорость cache: chimtech-1719.pdf plain text: chimtech-1719.txt item: #38 of 303 id: chimtech-1745 author: Tkach, V. V.; de Oliveira, S. C.; de Oliveira, S. K. B.; Ojani, R.; Elenich, O. V.; Yagodynets, P. I. title: The mechanism for the electrooxidation of procarbazine pharmaceutical preparation in alkaline media and its mathematical description date: 2016-03-15 words: 4407 flesch: 79 summary:   −    g G k F RT lk F 12 1 0 1 1 2 3 1 2 1 2 = −          + + − − − exp ( ) exp ϕ θ θ θ ϕ00 RT          g G k F RT mk F 13 1 0 1 1 2 3 1 2 1 2 = −          + + − − − exp ( ) exp ϕ θ θ θ ϕ00 RT     keywords: exp; procarbazine; − ;  ; ; ;  − cache: chimtech-1745.pdf plain text: chimtech-1745.txt item: #39 of 303 id: chimtech-1885 author: Dolmatova, E. A.; Patrushev, A. V.; Ostanina, T. N. title: Measurement of the specific surface area of loose copper deposit by electrochemical methods date: 2016-07-23 words: 3365 flesch: 77 summary: Tel.: (343) 375- 44-63; E-mail: arcfan@yandex.ru Measurement of the specific surface area of loose copper deposit by electrochemical methods In the work the surface area of the electrode with dispersed copper deposit obtained within 30 seconds was evaluated by techniques of chronopotentiometry (CPM) and impedance spectroscopy. It is found that within 30 seconds of electrolysis the surface area of loose copper deposit in so- lution 1 with sulfuric acid is higher than in solution 2 with sodium sulfate. keywords: area; copper; current; deposit; electrode; impedance; solution; surface; меди; осадка; осадком; площади; поверхности; при; электрода cache: chimtech-1885.pdf plain text: chimtech-1885.txt item: #40 of 303 id: chimtech-1886 author: Uritskaya, A. A.; Kozhevnikova, N. S.; Yakubova, T. V. title: Kinetics of chemical bath deposition of zinc sulfide ZnS date: 2016-07-23 words: 5273 flesch: 79 summary: (6) Заключение Таким образом, в выбранных в дан- ной работе условиях скорость процес- са (1) слабо зависит от величины рН, что объясняется буферным действием этилендиамина, зависит от концен- трации осадителя (тиомочевины) и уменьшается с увеличением концен- трации лиганда (этилендиамина) из-за снижения концентрации свободных ионов цинка в растворе. The data got on equalization (5) show that at the changing concentra- tions of components of reaction rate of reaction mixture k' remain permanent within the limits of error of experiment. keywords: concentration; formation; kinetic; n2h4cs; order; process; rate; reaction; surface; temperature; zinc; zns; для; концентрации; при; реакции; скорости cache: chimtech-1886.pdf plain text: chimtech-1886.txt item: #41 of 303 id: chimtech-1938 author: Kurysheva, V. V.; Ivanova, E. A.; Prokhorova, P. E. title: Extractants for rare earth metals date: 2016-07-23 words: 7576 flesch: 79 summary: [3], пришедших в негодность жестких дисков компьютеров Кислые фосфорил-содержа- щие поданды 16, 18, 19 были описаны в 1989 году как комплексообразовате- ли для щелочных металлов keywords: acid; actinides; calixarenes; cations; compounds; crown; doi; earth; earth metals; efficiency; ethers; extractants; extraction; lanthanides; metals; nitric; podands; rare; separation; solvent; для; катионов; кислоты; краун; лантаноидов; рзм; что; экстракции cache: chimtech-1938.pdf plain text: chimtech-1938.txt item: #42 of 303 id: chimtech-1940 author: Shevyrin, V. A. title: Differentiation of 2- and 6-isomers of (2-dimethylaminopropyl)benzofuran by tandem mass spectrometry date: 2016-07-23 words: 1729 flesch: 76 summary: При проведении анализа методом хроматомасс-спектрометрии с исполь- зованием типичных для определения наркотиков газохроматографических колонок с неполярной диметилполи- силоксановой неподвижной фазой (типа НР-5) дифференциация соеди- нений 5-АРВ и 6-АРВ, или 5-MAPB и 6-MAPB возможна за счет различия Fig. When conducting analysis by gas chromatogra- phy–mass spectrometry using typical gas chromatography columns for drug iden- tification with dimethylpolysiloxane non- polar stationary phase (such as HP–5) the differentiation of compounds 5-APB and 6-APB or 5-MAPB and 6-MAPB is pos- sible due to the differences in the values of parameters of the chromatographic reten- tion of these compounds (Fig. 2) or their acyl derivatives keywords: compounds; mapb; mass; мapb; соединений cache: chimtech-1940.pdf plain text: chimtech-1940.txt item: #43 of 303 id: chimtech-2035 author: Mitin, V. V.; Ivanova, E. A.; Prokhorova, P. E.; Morzherin, Yu. Yu. title: Chlorophenols in organic synthesis date: 2016-12-01 words: 8732 flesch: 84 summary: Кроме того, в реакции с 4-хлорфенолом 1b вместо атмосферы азота использовался обычный воздух. Ими был использо- ван в  качестве катализатора комплекс палладия и дикетоиминофосфина. keywords: catalyst; chlorophenol; compounds; conditions; coupling; derivatives; doi; formation; kotbu; ligand; mmol; naotbu; palladium; pd(oac)2; product; reactions; synthesis; table; yield; для; катализатора; ммоль; при; реакции; также cache: chimtech-2035.pdf plain text: chimtech-2035.txt item: #44 of 303 id: chimtech-2036 author: Poluikova, A. A.; Platonova, A. Yu. title: Technology of the pilot production of the tetrahydroquinoline derivative (3aS*,4R*)-4-cyano-1,2,3,3а,4,5-hexahydro-1Н- pyrrolo[1,2-а]quinoline-4-carbothioamide date: 2016-12-01 words: 8859 flesch: 86 summary: γ 100 % ТКА 0,988 воды в осадке 0,01 примеси в осадке 0,002 Состав маточного раствора Б Раствор, в т. γ 100 % ТКА 0,995 воды в осадке 0,003 примеси в осадке 0,002 Состав маточного раствора Б Раствор, в т. keywords: apparatus; precipitate; water; примеси; том; числе cache: chimtech-2036.pdf plain text: chimtech-2036.txt item: #45 of 303 id: chimtech-2070 author: Korshunova, N. A.; Tukhvatullina, R. F.; El'tsov, O. S. title: The study of the curing of the polyurethane coating by method of IR spectroscopy date: 2016-12-30 words: 5151 flesch: 69 summary: ИК-спектры записывались с пе- риодичностью раз в сутки в течение 25 дней. 0,50 %, 0,75  %, 1,00 % от массы смеси. keywords: catalyst; coating; content; curing; groups; isocyanate; mass; n o; n r; o o; o ocn; polyurethane; process; reaction cache: chimtech-2070.pdf plain text: chimtech-2070.txt item: #46 of 303 id: chimtech-2071 author: Tkach, V. V.; de Oliveira, S. C.; Ojani, R.; Elenich, O. V.; Yagodynets, P. I. title: Mathematical description of «polythiophene paradox» for potentiostatic electropolymerization of electrochemically modified thiophenes date: 2016-12-30 words: 4593 flesch: 74 summary: Данное явление, открытое в 1989 году, полу- чило название «политиофенового па- радокса» и проявляется в появлении в полимере кислородсодержащих функ- циональных групп и снижении прово- димости, ввиду изменения конфигу- рации сопряженной системы щего в растворе в избытке, мы вводим две переменные: – Θ1 – степень покрытия электрода модифицированным мономером; – Θ2 – степень покрытия электрода непереокисленным политиофеном. keywords: = −; electrochemical; monomer; paradox; polythiophene; r r; system; для; − −; − ;  ;  cache: chimtech-2071.pdf plain text: chimtech-2071.txt item: #47 of 303 id: chimtech-2132 author: Nechaev, A. V.; Nechaev, A. A.; Timina, A. A. title: Anodic behaviour of aluminium and its alloys in sodium chlorate solutions date: 2017-05-30 words: 3244 flesch: 67 summary: Изучение анодного поведения ис- следуемых алюминиевых сплавов в за- висимости от температуры раствора скорости вращения дискового электрода показало, что максимальная плотность тока на анодных поляризационных кривых с понижением концентрации 51 раствора хлората натрия от 5М до хлората натрия: 1 – прямой ход поляризационной кривой; 2 – обратный ход поляризационной кривой 53 поверхности после электрохимической обработки алюминиевых сплавов в рас- творах хлората натрия могут быть свя- заны с образованием на поверхности электрода специфической оксидной пленки и подавлением вследствие это- го электрохимической гетерогенности структурных составляющих алюмини- евых сплавов за счет дополнительного потенциального барьера на границе ме- талл – пленка, что и приводит к умень- шению масштабов травления. keywords: alloys; aluminium; chlorate; current; dissolution; electrode; sodium; solutions; surface; алюминиевых; натрия; при; растворах; сплавов; хлората; электрода cache: chimtech-2132.pdf plain text: chimtech-2132.txt item: #48 of 303 id: chimtech-2246 author: Fan, Zhijin title: Memorize organic chemist Professor Yuri Yurievich Morzherin date: 2017-05-30 words: 1163 flesch: 78 summary: В «Анализах Конфуция» говорится: «Пусть покойник будет в мире, а живые должны жить дальше». In Russian 11 января 2017 года стал необычным днем в моей жизни. keywords: chemistry; laboratory; его cache: chimtech-2246.pdf plain text: chimtech-2246.txt item: #49 of 303 id: chimtech-2247 author: Gushchin, A. V.; Kalistratova, O. S.; Maleeva, A. I.; Kuropatov, V. A.; Yemelyanov, D. N. title: Tert-butyl-diphenylmethylnitroxyl radical formation with the reaction of triphenylbismuth dicrotonate and C-phenyl-N-tert-butylnitrone in benzene date: 2017-09-08 words: 2210 flesch: 75 summary: Так- же ранее была изучена фотоиндуци- рованная катионная полимеризация оксиранов и  виниловых мономеров, в  которой инициаторами выступали соли триарил(1-пиренил)висмута In Russian Ранее методом радикальной поли- меризации в  присутствии инициато- ров был получен полиметилметакри- лат (ПММА) с  добавками различных металлоорганических соединений Bi(V) keywords: benzene; chch3)2; dicrotonate; light; polymerization; radical; reaction; tert; triphenylbismuth; трифенилвисмута cache: chimtech-2247.pdf plain text: chimtech-2247.txt item: #50 of 303 id: chimtech-2248 author: Sosnovskikh, V. Ya.; Roshentaler, G.-V. title: Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent date: 2017-05-30 words: 3211 flesch: 80 summary: Отметим, что в последнем случае региоселектив- ность падает и соотношение продуктов Схема 3 Схема 4 39 1,4- и 1,2-присоединения составляет ~3: 2, в результате чего 8-азахроманоны 9 были выделены лишь с умеренным вы- ходом (27–35 %). [18] в ходе работы по изучению противо- опухолевой активности трифторме- тилированных флавоноидов провели трифторметилирование флавона 18 и изофлавона 19 в наших условиях и установили, что в первом случае имеет место 1,2-, а во втором – 1,4-присоедине- ние с образованием продуктов 20 и 21, соответственно (схема 10). keywords: 1,4; addition; cf3; nucleophilic; presence; reaction; scheme; trifl; uoromethylation; схема; что cache: chimtech-2248.pdf plain text: chimtech-2248.txt item: #51 of 303 id: chimtech-2256 author: Ulomsky, E. N.; Lyapustin, D. N.; Fedotov, V. V.; El'tsov, O. S.; Sapozhnikova, I. M.; Kozhevnikov, D. N.; Mukhin, E. M. title: The features of nucleophilic substitution of the nitro group in 4-alkyl-6-nitro-1,2,4-triazolo[5,1-c][1,2,4]triazines date: 2017-05-30 words: 4822 flesch: 85 summary: Th e reaction mass is evaporated to dry- ness in vacuum. Th e nucleophile was used N-morpho- line as the least reactive reagent, allowing us to identify key intermediates. keywords: ch2; nmr; spectrum; спектр; ямр cache: chimtech-2256.pdf plain text: chimtech-2256.txt item: #52 of 303 id: chimtech-2341 author: Editors, Chimica Techno Acta title: In memory of Yu. Yu. Morzherin date: 2017-05-30 words: 822 flesch: 98 summary: , - , , 11 2017 , , , . (09.08.1964–11.01.2017) Юрий Юрьевич Моржерин родился 9  августа 1964 году в  поселке Азамар Читинской области, но свое детство провел в  Активная и плодотворная деятель- ность Юрия Юрьевича распространя- лась не только на кафедре, но и в инсти- туте, и университете. keywords: году; его; юрий; юрьевич cache: chimtech-2341.pdf plain text: chimtech-2341.txt item: #53 of 303 id: chimtech-2342 author: Kozhevnikov, D. N.; Kozhevnikov, V. N. title: Combinatorial approach to the synthesis of substituted 1,2,4-triazines date: 2017-05-30 words: 1055 flesch: 82 summary: Kopchuk D. S., Chepchugov N. V., Kovalev I. S., Santra S., Rahman M., Giri K., Zyry- anov G. V., Majee A., Charushin V. N., Chupakhin O. N. RSC Adv. 2017;7:9610–9619. Kozhevnikov V.  N., Kozhevnikov D. N., Shabunina O. V., Kataeva N. N., Yushchuk S. A., Rusinov V. L., Chupakhin O. N. Russ. keywords: 1,2,4; triazines cache: chimtech-2342.pdf plain text: chimtech-2342.txt item: #54 of 303 id: chimtech-2378 author: Scharf, F.; Mikhnevich, E.; Safronov, A. title: Interaction of iron oxide nanoparticles synthesized by laser target evaporation with polyacrylamide in composites and ferrogels date: 2017-09-09 words: 5063 flesch: 61 summary: Inset: histogram – calculation of particle number fraction from the image analysis, line – fitting of PSD by equation (1) Fig. 2. XRD diffractogram of FeOx MNPs synthesized by laser target evaporation Fig. 3. Adsorption of LPAAm on FeOx MNPs from water solution at 25 °C. 1 – intact FeOx surface; 2 – Citrate covered FeOx surface ferent (Fig. 3, Curve 2). keywords: adsorption; concentration; enthalpy; feox; feox mnps; ferrogels; fig; lpaam; mnps; network; polyacrylamide; surface; water cache: chimtech-2378.pdf plain text: chimtech-2378.txt item: #55 of 303 id: chimtech-2380 author: Mikhaylovskaya, Z. A.; Morozova, M. V.; Buyanova, E. S.; Petrova, S. A.; Nikolaenko, I. V.; Kellerman, D. G. title: Preparation and characterization of Bi26-2xMn2xMo10O69-d and Bi26.4Mn0.6Mo10-2yMe2yO69-d (Me = V, Fe) Solid Solutions date: 2017-09-08 words: 3003 flesch: 62 summary: It was shown previ- ously that the best conductivity proper- ties of Bi26-2xMn2xMo10O69-d series was re- lated to the x = 0.3 compound general for- mula Bi26-2xMn2xMo10O69-d and Bi26-2xMn2x- Mo10-2yMe2y O69-d were prepared using Bi2O3 (99.9 %), MoO3 (99.5 %), MnO (99.7 %), V2O5 (99.5 %) Fe2O3 (99.5 %) as precursors. keywords: 2xmn2xmo10; bi26; conductivity; fig; solid; structure cache: chimtech-2380.pdf plain text: chimtech-2380.txt item: #56 of 303 id: chimtech-2398 author: Krinochkin, A. P.; Kopchuk, D. S.; Starnovskaya, E. S.; Shtaiz, Ya. K.; Khasanov, A. F.; Kovalev, I. S.; Taniya, O. S.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N. title: The synthesis of 1,2,4-triazines bearing the residues of higher alcohols in the 5-position via the ipso-substitution of cyano group under the solvent-free conditions date: 2017-09-08 words: 2797 flesch: 86 summary: The ipso-substitution of a cyanogroup deserves a special attention because 5-cyano-1,2,4-triazines are highly affordable compounds due to previously developed convenient method of obtain- ing them by using the direct nucleophilic substitution of hydrogen in the series of 1,2,4-triazine-4-oxides Chlorination of 5,6-Dimethyl-3-phenyl-as-triazine. keywords: 1,2,4; ipso; substitution; synthesis; tol; triazines cache: chimtech-2398.pdf plain text: chimtech-2398.txt item: #57 of 303 id: chimtech-2403 author: Shankar, A.; Safronov, A. P.; Beketov, I. title: Encapsulation of metallic iron magnetic nanoparticles by polyacrylamide in water suspensions date: 2017-10-10 words: 4015 flesch: 60 summary: The resulted solution was then used as a stock for the encapsulation of iron MNPs. The aggregation features of iron MNPs in water suspension can be qualitatively modeled by the extended DLVO approach. keywords: iron; iron mnps; layer; mnps; nanoparticles; paam; steric; surface; water cache: chimtech-2403.pdf plain text: chimtech-2403.txt item: #58 of 303 id: chimtech-2555 author: Mukherjee, Anindita; Chatterjee, Rana; De, Aramita; Samanta, Satyajit; Mahato, Sachinta; Ghosal, Nirnita Chakraborty; Zyryanov, G. V.; Majee, Adinath title: Conjugated Addition of Amines to Electron Deficient Alkenes: A Green Approach date: 2017-07-14 words: 2822 flesch: 66 summary: LiClO4 accelerated Michael addition of amines to α, β-unsaturated olefins under solvent-free conditions. β-Cyclodextrin promoted aza- Michael addition of amines to conjugated alkenes in water. keywords: addition; amines; chem; doi:10.1016; michael; reaction; synthesis; tea; tetrahedron cache: chimtech-2555.pdf plain text: chimtech-2555.txt item: #59 of 303 id: chimtech-2556 author: Ramana, P. V.; Krishna, B. S.; Reddy, N. B.; Sravaya, G.; Zyryanov, G. V.; Reddy, C. S. title: Potassium carbonate supported efficient synthesis of new diethyl arylphosphoramidates date: 2017-07-14 words: 3371 flesch: 76 summary: Diethyl 1H-benzo[d]imida- zol-1-ylphosphonate (3n): Yield: 84 %; Brown solid; IR (ZnSe): 3356 (NH  Aro- matic), 1198 (P=O), 959 (P-O-Caliphatic) cm-1; 1H NMR (500 MHz, DMSO-d6): δ 1.26–1.34 (6H, m, 2CH3), 4.50–4.53 (4H, m, 2CH2), 7.26–7.62 (4H, m, ArH), 8.18 (1H, s, N=CH-N) ppm; 13C NMR (125 MHz, DMSO-d6): δ 16.22, 60.12, 115.26, 124.08, 137.84, 139.05, 142.25 ppm; 31P NMR (200 MHz, DMSO-d6): δ –6.724 ppm; LC–MS m/z (%): 254 (100) Found: C, 45.35; H, 7.32; N, 9.85. Diethyl thiazol-2-ylphosphoram- idate (3g): Yield: 87 %; Brown solid; IR (ZnSe): 3356 (NH  Aromatic), 1206 (P=O), 938 (P-O-Caliphatic) cm -1; 1H NMR (500 MHz, DMSO-d6): keywords: diethyl; dmso; mhz; nmr; ppm; yield cache: chimtech-2556.pdf plain text: chimtech-2556.txt item: #60 of 303 id: chimtech-2585 author: Sednev, A. L.; Tsvetkov, D. S. title: Study and optimization of the synthesis routine of the single phase YBaCo2O6-δ double perovskite date: 2017-10-05 words: 3251 flesch: 70 summary: [14] as well as that a synthesis routine for these intermediate phases has been already described in lite- rature [15, 16] we selected YCoO3–δ and BaCoO3–δ as starting reagents for prepara- tion of the YBaCo2O6–δ double perovskite. We only would like to emphasize once again the key role, which thermo- dynamic stability of YCoO3 plays in the optimization of synthesis routine for the YBaCo2O6–δ double perovskite. keywords: air; bacoo3; oxygen; perovskite; synthesis; ybaco2o6; ycoo3 cache: chimtech-2585.pdf plain text: chimtech-2585.txt item: #61 of 303 id: chimtech-2604 author: Krylov, A. A.; Emelyanova, Yu. V.; Buyanova, E. S.; Morozova, M. V.; Vylkov, A. I.; Chuykin, A. Yu. title: Materials based on BIFEVOX and bismuth or iron simple oxides nanopowders date: 2017-11-03 words: 2837 flesch: 62 summary: Materials based on BIFEVOX and bismuth or iron simple oxides nanopowders. Materials based on BIFEVOX and bismuth or iron simple oxides nanopowders 202 Krylov A.A., Emelyanova Yu. keywords: air; bifevox; composite; conductivity; materials; oxide; structure; temperature cache: chimtech-2604.pdf plain text: chimtech-2604.txt item: #62 of 303 id: chimtech-2607 author: Efremov, V. N.; Golosman, E. Z.; Kashinskaya, A. V.; Mugenov, T. I.; Zolotareva, V. E.; Polivanov, B. I.; Polushin, A. P. title: Resistance of industrial nickel-containing methanation catalysts to the poisoning by organic carbon dioxide absorbents date: 2017-09-06 words: 6211 flesch: 74 summary: Процесс разложения МДЭА в  среде воздуха сопровождает- ся убылью массы. В  процессе воздействия на активированные катализаторы при температуре 320 °С водного раствора МДЭА в  потоке АВС происходит их пассивация. keywords: activity; al2o3; c13; carbon; catalysts; component; gas; mdea; methanation; niap-07; nickel; nio; nkm-7; russian; solution; strength; водного; для; катализаторов; мдэа; метанирования; ниап-07; нкм-7; при; раствора; что cache: chimtech-2607.pdf plain text: chimtech-2607.txt item: #63 of 303 id: chimtech-2640 author: Klyndyuk, A. I.; Chizhova, E. A.; Poznyak, A. I. title: Preparation and characterization of Bi4–xPrxTi3O12 solid solutions date: 2017-12-15 words: 3356 flesch: 65 summary: Pardo L. Dielectric and mechanoelastic relaxations due to point defects in layered bismuth titanate ceramics. Effect of Ce and La substitution on dielectric properties of bismuth titanate ceramics. keywords: bi4; bi4ti3o12; ceramics; conductivity; dielectric; electrical; fig; temperature; xprxti3o12 cache: chimtech-2640.pdf plain text: chimtech-2640.txt item: #64 of 303 id: chimtech-2649 author: Grossman, V. G.; Bazarov, B. G.; Bazarova, Zh. G. title: Phase equilibria in the Tl2MoO4–R2(MoO4)3–Zr(MoO4)2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl5RZr(MoO4)6 and TlRZr0.5(MoO4)3 date: 2017-12-12 words: 1982 flesch: 63 summary: The analysis of X-ray diffraction pat- terns of the compounds obtained shows that the reflection positions and their intensity ratio for TlRZr0.5(MoO4)3 and Tl5RZr(MoO4)6 (R = Al, Cr) are similar to TlFeHf0.5(MoO4)3 G. Bazarova2 1Baikal Institute of Nature Management, Siberian Branch of Russian Academy of Sciences, 8 Sakh’yanovoi St., Ulan-Ude, 670047, Russian Federation e-mail: grossmanv@mail.ru 2Buryat State University, 24a SmolinaSt., Ulan-Ude, 670000, Russian Federation Phase equilibria in the Tl 2 MoO 4 –R 2 (MoO 4 ) 3 –Zr(MoO 4 ) 2 (R = Al, Cr) systems: synthesis, structure and properties of new triple molybdates Tl 5 RZr(MoO 4 ) 6 and TlRZr 0.5 (MoO 4 ) 3 The Tl 2 MoO 4 –R 2 (MoO 4 ) 3 –Zr(MoO 4 ) 2 (R = Al, Cr) systems were studied in the subsolidus region using X-ray powder diffraction and differential scanning calo- rimetric (DSC) analysis. keywords: phase; systems; tl2moo4 cache: chimtech-2649.pdf plain text: chimtech-2649.txt item: #65 of 303 id: chimtech-2704 author: Koroleva, M. S.; Piir, I. V.; Istomina, E. I. title: Synthesis, structure and electrical properties of Mg-, Ni-codoped bismuth niobates date: 2017-12-15 words: 4674 flesch: 75 summary: The disordered structures and low temperature dielectric relaxation properties of two misplaced- displacive cubic pyrochlores found in the Bi2O3–M IIO–Nb2O5 (M = Mg, Ni) systems. 7. Gao L, Jiang Sh, Li R, Li B, Li Y. Structure and dielectric properties of sput- tered bismuth magnesium niobate thin films. keywords: ceramics; dielectric; properties; pyrochlore; sites; temperature cache: chimtech-2704.pdf plain text: chimtech-2704.txt item: #66 of 303 id: chimtech-2705 author: Grivel, J.-C. title: Subsolidus phase equilibria of the CuO – SrO – ZnO pseudoternary system in air at 900 °C date: 2017-12-15 words: 4412 flesch: 76 summary: Subsolidus phase relations of the CaO – REOx – CuO systems (RE = Eu, Tb, Dy, Ho, Er, Lu and Sc) at 900 °C in air. Subsolidus phase relations of the SrO – REOx – CuO systems (RE  = Ce, Pr and Tb). keywords: air; cuo; doi; equilibria; lattice; phase; relations; samples; sro; subsolidus; system; xrd; zno cache: chimtech-2705.pdf plain text: chimtech-2705.txt item: #67 of 303 id: chimtech-2715 author: Vedmid', L. B.; Dimitrov, V. M.; Fedorova, O. M. title: Low-temperature synthesis under low oxygen pressure and thermodynamic properties of YbFe2O4-δ date: 2018-05-08 words: 2464 flesch: 63 summary: Keywords: oxygen partial pressure, mixed-valence compound, thermodynamic properties, complex oxides, oxygen nonstoichiometry Received: 27.11.2017. Reducing con- ditions were provided by maintaining the required value of oxygen partial pressure using the electrochemical method [5]. keywords: oxygen; pressure; temperature; ybfe2o4 cache: chimtech-2715.pdf plain text: chimtech-2715.txt item: #68 of 303 id: chimtech-2717 author: Bazarova, Zh. G.; Grossman, V. G.; Bazarov, B. G.; Tushinova, Yu. L.; Chimitova, O. D.; Bazarova, Ts. T. title: Phase diagrams for the M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 systems, where M = Li–Cs, Tl and Ln = La–Lu date: 2017-12-12 words: 2285 flesch: 68 summary: Subsolidus phase diagrams of ternary systems were constructed and new triple molybdates were obtained. The first group includes systems with Ln = La–Tb in which two intermediate phases LiLn5(MoO4)8 and LiLn(MoO4)2 possess a significant homo- geneity range. keywords: hf(moo4)2; ln2(moo4)3; phase; systems cache: chimtech-2717.pdf plain text: chimtech-2717.txt item: #69 of 303 id: chimtech-2860 author: Decterov, S. A. title: Thermodynamic database for multicomponent oxide systems date: 2018-05-08 words: 15458 flesch: 62 summary: Thermodynamic model of a heterovalent solid solution at local elec- troneutrality. Statistical thermodynamic models for ideal oxide and silicate solid solutions, with application to plagioclase. keywords: al2o3; binary; cao; components; database; decterov; decterov sa; doi; energy; experimental; gibbs; jak; melts; mixing; model; modeling; multicomponent; oxide; pelton; phase; properties; sio2; solutions; system; ternary; thermodynamic; viscosity cache: chimtech-2860.pdf plain text: chimtech-2860.txt item: #70 of 303 id: chimtech-3065 author: Volkova, N. E.; Khvostova, L. V.; Galaida, A. P.; Gavrilova, L. Ya.; Cherepanov, V. A. title: Phase equilibria, crystal structure and oxygen nonstoichiometry of the complex oxides in the Sm – (Sr, Ba) – (Co, Fe) – O systems date: 2018-05-08 words: 9814 flesch: 77 summary: Thermodynamic stability of the Sm1–хSrхCoO3–δ solid solutions has not been studied yet. [59] Table 6 The unit cell parameters for the Sr1–xSmxFeO3–δ solid solution x Structure a, Å b, Å c, Å Ref. 0.5 Orthorhombic sp. gr. keywords: air; cell; chem; doi; fig; mater; oxygen; parameters; perovskite; phase; properties; route; solid; state; structure; system; unit cache: chimtech-3065.pdf plain text: chimtech-3065.txt item: #71 of 303 id: chimtech-3102 author: Zvereva, I. A.; Tugova, E. A.; Popova, V. F.; Silyukov, O. I.; Minich, I. A. title: The impact of Nd3+/La3+ substitution on the cation distribution and phase diagram in the La2SrAl2O7-Nd2SrAl2O7 system date: 2018-05-08 words: 2500 flesch: 61 summary: Certainly, the stu- died solid solutions cannot be described in terms of regular solution model, since the entropy contribution to the Gibbs energy of solid solutions formation, accompanied by the cation redistribution between the non-equivalent 12-coordinated (cuboc- tahedron AO12) and 9-coordinated (anti- prism AO9) sites, should not be neglected. Keywords: perovskites, transition metal oxides, solid solutions, layered compounds, phase diagram Received: 28.04.2018. keywords: cation; distribution; nd2sral2o7; solutions; xndx)2sral2o7 cache: chimtech-3102.pdf plain text: chimtech-3102.txt item: #72 of 303 id: chimtech-3120 author: Rotermel, M. V.; Krasnenko, T. I.; Petrova, S. A.; Titova, S. G. title: Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides date: 2018-05-08 words: 2669 flesch: 64 summary: Keywords: non-autonomous phase, volume thermal expansion, M 2 V 2 O 7 Received: 02.03.2018. The participation of non-autonomous phases in the solid-phase synthesis and sintering of ceramic sam- ples at Tammann temperature due to the melting of the non-autonomous phase on the matrix surface were assumed and ther- modynamically justified, as well as par- ticipation of the non-autonomous phase in the charge and mass transfer processes was shown [10–16]. keywords: monoclinic; phase; russian; temperature cache: chimtech-3120.pdf plain text: chimtech-3120.txt item: #73 of 303 id: chimtech-3170 author: Singh, Boota; Waliya, Rohan Ranjan; Santra, Sougata; Giri, Kousik; Zyryanov, Grigory V. title: Effect of Alkylation on the Kinetic Stability of Arsenodiester and Organoarsenicals against Hydrolysis: A Theoretical Study date: 2018-07-31 words: 2581 flesch: 59 summary: The process of converting As– O-bond-based compounds to  As–C was also proposed in  mammals, where liver cell first reducts Asi diester by using glu- tathione and then, after methyl transferases for methylation, finally produced various species of arsenic acid from Asi diester (see Fig. 1). [10] 98 Methods Hydrolysis pathways for Asi diester are well documented in the literature [4, 12]. keywords: arsenate; arsenic; asi; bond; compounds; diester; hydrolysis; rate cache: chimtech-3170.pdf plain text: chimtech-3170.txt item: #74 of 303 id: chimtech-3261 author: Soliev, L.; Jumaev, M. T.; Turaev, R. O.; Makhmadov, H. R.; Dzabborov, B. B. title: Structure of the solubility diagram in the Na2SO4-Na2CO3-NaHCO3-H2O system at 0, 25 and 50 °С date: 2018-07-31 words: 1334 flesch: 68 summary: °C using solubility method. Structure of the solubility diagram in the Na2SO4-Na2CO3-NaHCO3-H2O system at 0, 25 and 50 ?? 104 L. Soliev, M. T. Jumaev, R. O. Turaev, H. R. Makhmadov, B. B. Dzabborov Tajik State Pedagogical University named after S. Ayni 121 Prospect Rudaki, Dushanbe, 734003, Tajikistan E-mail: Soliev.Lutfullo@yandex.com; jumaev_m@bk.ru Structure of the solubility diagram in the Na 2 SO 4 ‑Na 2 CO 3 ‑NaHCO 3 ‑H 2 O system AT 0, 25 and 50 °С The solubilities in invariant points of Na 2 SO 4 -Na 2 CO 3 -NaHCO 3 -H 2 O system were investigated at 0, 25 and 50 °С. The phase equilibria in the said system were discussed, and phase diagrams at given temperatures were constructed. keywords: h2o; phase; system cache: chimtech-3261.pdf plain text: chimtech-3261.txt item: #75 of 303 id: chimtech-3299 author: Malyshkin, D. A.; Novikov, A. Yu.; Tsvetkov, D. S. title: Oxygen content and defect structure of the perovskite La0.5Ba0.5CoO3–δ date: 2018-07-31 words: 3256 flesch: 72 summary:   11 0 2 2 2 0 2 0 R K H RT S R � � � � � � � ��� ���� �� �� �� � � � � � � Co Co Co exp Co Co Co  �� � � � � � ��� �� � ��� �� � �� �� � �� �� �� �� � � � Co Ba Co V Co C Co La Co O Co  2 oo Co O V Co Co O O �� �� � �� �� � �� �� � � �� �� � � � � �   1 3 � � (3) Co O � � � � � � � � �� ���� �� 2 212 2 1 0 5 2 2 i ii ii � , . keywords: defect; la0.5ba0.5coo3; oxygen; perovskite; structure; temperature cache: chimtech-3299.pdf plain text: chimtech-3299.txt item: #76 of 303 id: chimtech-3444 author: Bazarova, J. G.; Tushinova, Yu. L.; Grossman, V. G.; Bazarova, Ts. T.; Bazarov, B. G.; Kurbatov, R. V. title: Phase relations in the Me2MoO4–In2(MoO4)3–Hf(MoO4)2 systems, where Me = Li, K, Tl, Rb, Cs date: 2018-10-15 words: 1899 flesch: 64 summary: Since the phase relations in the K2MoO4–In2(MoO4)3 and Cs2MoO4–In2(MoO4)3 systems enriched by either potassium molybdate or by ce- sium molybdate were found to  be non- quasibinary, the studies of the Me2MoO4– In2(MoO4)3–Hf(MoO4)2 (Me  = K, Cs) systems were limited to the Hf(MoO4)2– Me8Hf(MoO4)6–MeIn(MoO4)2–In2(MoO4)3 (Me = K, Cs) regions. The formation of ternary mo- lybdates Me5InHf (MoO4)6 for Me = K, Tl, Rb, Cs and Мe2InHf2(MoO4)6.5 for Me = Rb, Cs was established. keywords: phase; systems cache: chimtech-3444.pdf plain text: chimtech-3444.txt item: #77 of 303 id: chimtech-3455 author: Kotova, Irina Yu.; Savina, Aleksandra A.; Vandysheva, Alena I.; Belov, Dmitry A.; Stefanovich, Sergey Yu. title: Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals date: 2018-10-22 words: 4642 flesch: 72 summary: Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals 132 D O I: 1 0. 15 82 6/ ch im te ch .2 01 8. 5. 3. 02 Kotova I. Yu., Savina A. A., Vandysheva A. I., Belov D. A., Stefanovich S. Yu. Moscow State University, Leninskie Gory, 1, Moscow 119991, Russian Federation *E-mail: alex551112@mail.ru Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals A possibility of the triple molybdates formation with both NASICON-like and NaMg3In(MoO4)5 structures in the Ag2MoO4–AMoO4–Ga2(MoO4)3 (A = Mn, Co, Zn, Ni) systems was studied by powder X-ray diffraction analysis. keywords: 0.015(1; compounds; conductivity; molybdates; structure; temperature; triple cache: chimtech-3455.pdf plain text: chimtech-3455.txt item: #78 of 303 id: chimtech-3462 author: Nikonov, I. L.; Kopchuk, D. S.; Khasanov, A. F.; Krinochkin, A. P.; Starnovskaya, E. S.; Shtaiz, Ya. K.; Savchuk, M. I.; Tanya, O. S.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N. title: Two mutually complementary synthetic approaches towards 3-substituted 3,4-disubstituted and 1-(2-pyridyl)-substituted isoquinolines date: 2018-10-28 words: 1345 flesch: 65 summary: © Nikonov I. L., Kopchuk D. S., Khasanov A. F., Krinochkin A. P., Starnovskaya E. S., Shtaiz Ya. K., Savchuk M. I, Tanya O. S., Zyryanov G. V., Rusinov V. L., Chupakhin O. N., 2018 D O I: 1 0. 15 82 6/ ch im te ch .2 01 8. 5. 3. 04 Results and Discussion Aryne intermediates, generated in situ, are currently attracting more and more attention from the point of  view of  their use in  organic synthesis, since practically useful products of various pur- poses can be obtained [1–3]. This article analyzes the two synthetic approaches we have developed for the syn- thesis of 1- (2-pyridyl) isoquinolines with different substituents in the C3 and C4 po- sitions, which are of interest, in particular, as ligands for transition metal cations [5], as well as from the point of view of creat- ing OLED [6]. Nikonov I. L., Kopchuk D. S., Khasanov A. F., Krinochkin A. P., Starnovskaya E. S., Shtaiz Ya. K., Savchuk M. I, Tanya O. S., Zyryanov G. V., Rusinov V. L., Chupakhin O. N. Chimica Techno Acta. 2018. keywords: isoquinolines; synthesis cache: chimtech-3462.pdf plain text: chimtech-3462.txt item: #79 of 303 id: chimtech-3463 author: George, Cijin J.; Santra, Sougata; Zyryanov, G. V.; Giri, Kousik title: Arsenate and Arsenite Reaction Kinetics with Ferric Hydroxides Using Quantum Chemical Calculations date: 2018-10-29 words: 2198 flesch: 55 summary: The results of the study indicate that Gibbs free energy for the reaction has a significant role in controlling the kinetics of the adsorption and sorption process of arsenate on ferric hydroxide clusters. Despite the studies done on arsenate- ferric hydroxide complex formation, a little is known about the mechanism of this re- action. keywords: adsorption; arsenate; bidentate; complex; doi; kcal; mol; reaction cache: chimtech-3463.pdf plain text: chimtech-3463.txt item: #80 of 303 id: chimtech-3464 author: Raskovalov, Anton A. title: Hopping conductivity in a system with ZnS crystal lattice by non-constant force field molecular dynamics date: 2018-10-28 words: 2220 flesch: 65 summary: This means that if length of  electron hopping is lesser than 2.7  Å, the system will not have electronic con- ductivity. ISSN 2409–5613 Introduction Concentration dependences of  conductivity in  different systems has already for a long time obtained the atten- tion of researchers [1–3]. keywords: conductivity; distance; electron; field; hopping; system cache: chimtech-3464.pdf plain text: chimtech-3464.txt item: #81 of 303 id: chimtech-3474 author: Mikhaylovskaya, Zoya Alekseevna; Buyanova, Elena Stanislavovna; Petrova, Sofia Aleksandrovna; Nikitina, Alena Andreevna title: Sheelite-related strontium molybdates: synthesis and characterization date: 2018-12-20 words: 2853 flesch: 67 summary: The tgδ vs temperature curves of Sr1–1.5xBixMoO4 compositions at 1 kHZ Fig. 6. Choi GK., Kim JR., Yoon SH., Hong KS. keywords: cell; compositions; dielectric; doi; fig; properties; sr1–1.5xbixmoo4; unit cache: chimtech-3474.pdf plain text: chimtech-3474.txt item: #82 of 303 id: chimtech-3492 author: Galayda, Anastasia P.; Volkova, Nadezhda E.; Dyagileva, Anastasia I.; Gavrilova, Ludmila Ya.; Cherepanov, Vladimir A.; Battle, Peter D. title: Crystal structure and properties of novel oxide Sm0.9Ca1.1Fe0.7Co0.3O4-d date: 2018-12-15 words: 2605 flesch: 69 summary: ISSN 2409–5613 A. P. Galaydaa*, N. E. Volkovaa, A. I. Dyagilevaa, L. Ya. Gavrilovaa, V. A. Cherepanova, P. D. Battleb a Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federation b Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, UK *E-mail: anastasia.galaida@urfu.ru Crystal structure and properties of novel oxide Sm0.9Ca1.1Fe0.7Co0.3O4–δ Sm0.9Ca1.1Fe0.7Co0.3O4–δ oxide with the K2NiF4-type structure was prepared us- ing a glycerin-nitrate technique. The present study has focused on the structure and properties of the novel Sm0.9Ca1.1Fe0.7Co0.3O4–δ oxide with the K2NiF4-type structure. keywords: air; doi; oxide; sm0.9ca1.1fe0.7co0.3o4; solid; structure; temperature; type cache: chimtech-3492.pdf plain text: chimtech-3492.txt item: #83 of 303 id: chimtech-3494 author: Porotnikova, Natalia M.; Antonova, Ekaterina P.; Khodimchuk, Anna V.; Tropin, Eugene S.; Farlenkov, Andrey S.; Ananyev, Maxim V. title: Oxygen diffusion and surface exchange kinetics for the mixed-conducting oxide La0.6Sr0.4Co0.8Fe0.2O3-δ date: 2018-12-24 words: 3310 flesch: 64 summary: The effective activation energies for oxygen exchange and diffusion processes as well as the exponents in the dependence of these values versus oxygen pressure in the double logarithmic coordinates were calculated. Effect of oxygen nonstoichiometry on kinetics of oxygen exchange and diffusion in lanthanum-strontium cobaltites. keywords: diffusion; doi; exchange; fig; kinetics; la0.6sr0.4co0.8fe0.2o3; oxide; oxygen; rate; solid cache: chimtech-3494.pdf plain text: chimtech-3494.txt item: #84 of 303 id: chimtech-3549 author: Jantzen, T.; Hack, K.; Yazhenskikh, E.; Müller, M. title: Thermodynamic assessment of oxide system In2O3-SnO2-ZnO date: 2018-12-15 words: 10307 flesch: 71 summary: j i j v ij v i j v � � � � � � �� �� � � � � �� � ln 0 (1) where xi is the mole fraction of phase con- stituent i (including the associate species), °Gi is the molar Gibbs energy of the pure phase constituent i and is an interaction coefficient between components i and j, according to the Redlich — Kister polyno- mial. O Liq Ti O SGPS 2 3 2 3 � � � �G GSn Liq Sn SGPS � � � �G GSn keywords: bixbyite; compounds; data; doi; in2o3; liquid; oxide; phase; sno2; solid; spinel; system; thermodynamic; zno; � g cache: chimtech-3549.pdf plain text: chimtech-3549.txt item: #85 of 303 id: chimtech-3578 author: Samigullina, R. F.; Rotermel, M. V.; Ivanova, I. V.; Krasnenko, T. I. title: Sol-gel synthesis and crystal chemical properties of the pigment Zn1.9Cu0.1SiO4 date: 2018-12-24 words: 1822 flesch: 62 summary: Thermogravimet- ric (TG) analysis together with differential thermal analysis (DTA) were performed using a Setsys Evolution thermal analyz- er (Setaram) in air at a temperature scan rate of 10 ° / min in the temperature range 20–1100 °C, with alumina as a reference substance. The precursor for the final stage of synthesis was obtained by evaporation of  the mixture for  2 hours at  65  °C.  keywords: blue; synthesis; temperature; zn1.9cu0.1sio4 cache: chimtech-3578.pdf plain text: chimtech-3578.txt item: #86 of 303 id: chimtech-3596 author: Raskovalov, Anton A. title: Simulation of borosilicate glasses with non-constant force field molecular dynamics date: 2018-12-28 words: 2976 flesch: 70 summary: The bonds breaking and formation realized by methodology of non-constant force field allow glass structure to be “dynamical,” i.e. to destroy ones atomic groups and to cre- ate others. Alkali ion migration mechanisms in silicate glasses probed by molecular dynamics simulations. keywords: dynamics; fig; glasses; simulation cache: chimtech-3596.pdf plain text: chimtech-3596.txt item: #87 of 303 id: chimtech-3638 author: Editorial Board, CTA title: Preface date: 2018-12-31 words: 445 flesch: 49 summary: 158 This issue is dedicated to  Professor Alexander Petrov, whose 75th birthday we have celebrated this year. During all his life Alexander Petrov was deeply involved into teaching and research in the Chemical Faculty of  the Ural State University. keywords: petrov; professor cache: chimtech-3638.pdf plain text: chimtech-3638.txt item: #88 of 303 id: chimtech-3695 author: Deriouche, W.; Anger, E.; Amdouni, N.; Pralong, V. title: Sodium intercalation into α- and β-VOSO4 date: 2019-03-25 words: 2390 flesch: 69 summary: Powder X-ray diffraction pattern of as prepared a-VOSO4 phase (lower curve); powder X-ray diffraction pattern of a-VOSO4 phase after ball milling (middle curve); powder X-ray diffraction pattern of a-VOSO4 phase after Na intercalation (upper curve) 36 4. Iron(III) sulfate: a stable, cost effec- tive electrode material for sodium ion batteries. keywords: intercalation; sodium; voso4 cache: chimtech-3695.pdf plain text: chimtech-3695.txt item: #89 of 303 id: chimtech-3709 author: Soliev, L.; Jumaev, M. T. title: Phase equilibria in the Na,Ca//SO4,CO3,HCO3-H2O system at 0 °C date: 2019-03-25 words: 1946 flesch: 64 summary: The phase composition of the sediments, corresponding to the multi-variant curves that connect four-phase invariant points, can be represented as follows: E1 4 E2 4 = Mb+Nk; E1 4 E5 4 = Mb+C·10; E1 4 E8 4 = C·10+Nk; E2 4 E3 4 = Nk+Gp; E2 4 E7 4 = Gp+Mb; E3 4 E4 4 = CaG+Gp; E3 4 E10 4 = Nk+CaG; E4 4 E6 4 = Gp+Cc; E4 4 E9 4 = Cc+CaG; E5 4 E7 4 = Mb+Gl; E5 4 E8 4 = Gl+C·10; E6 4 E7 4 = Gp+Gl; E6 4 E9 4 = Gl+Cc; E8 4 E10 4 = Nk+Gl; E9 4 E10 4 = Gl+CaG. Table 1 Phase composition of precipitates for the invariant points in the 4-component systems, which are compile the complex 5-component Na,Ca,//SO4,CO3,HCO3-H2O system at 0 °C Invariant points Solid phases in equilibrium Invariant points Solid phases in equilibrium Na2SO4–Na2CO3–NaHCO3–H2O system Na,Ca||SO4,CO3–H2O system E1 4 Mb+Nk+C·10 E5 4 Gl+Mb+C·10 Na,Ca||SO4,HCO3-H2O system E6 4 Gp+Gl+Cc E2 4 Gp+Mb+Nk More detailed de- scription of  the translation method that can be used for predicting and construct- ing of equilibrium phase diagrams for the multicomponent water — salt systems are considered in the works [3–5]. keywords: h2o; phase; system cache: chimtech-3709.pdf plain text: chimtech-3709.txt item: #90 of 303 id: chimtech-3900 author: Vdovin, Gennady; Rudenko, Anna; Antonov, Boris; Malkov, Vacheslav; Demin, Anatoly; Medvedev, Dmitry title: Manipulating the grain boundary properties of BaCeO3-based ceramic materials through sintering additives introduction date: 2019-06-28 words: 3097 flesch: 63 summary: To reveal grain (σg.) and grain boundary (σg.b.) The  obtained spectra (Fig.  3) were ana- lyzed using an equivalent circuit scheme of  Ro–(R1Q1)–(R2Q2)–(R3Q3), where R is the resistance, Q is the constant phase element,  indexes of  1, 2, 3 correspond to  grain, grain boundary and electrode processes, respectively. keywords: bcg; boundary; ceramic; doi; grain; materials; oxide; proton cache: chimtech-3900.pdf plain text: chimtech-3900.txt item: #91 of 303 id: chimtech-3966 author: Kaimieva, Olga S.; Sabirova, Irina E.; Buyanova, Elena S.; Petrova, Sophia A. title: Synthesis and Properties of Vanadium Substituted Bismuth Tungstates with Fluorite-like Structure date: 2019-07-24 words: 2001 flesch: 66 summary: The results showed that the substitution of tungsten with vanadium ions increased electrical conductivity values by one order of magnitude. The results show that the substitution of tungsten with vanadium ions increases electrical conductivity values by one order of magnitude. keywords: bismuth; conductivity; structure; tungstates cache: chimtech-3966.pdf plain text: chimtech-3966.txt item: #92 of 303 id: chimtech-3968 author: Beketov, I. V.; Safronov, A. P.; Medvedev, A. I.; Murzakaev, A. M.; Zhidkov, I. S.; Cholah, S. O.; Maximov, A. D. title: Encapsulation of Ni nanoparticles with oxide shell in vapor condensation date: 2019-09-18 words: 4762 flesch: 60 summary: Resulting oxide shells encapsulating Ni particles weaken their agglomeration processes as well as protect the surface of the Ni nanoparticles from further oxidation. Consequently, with the increase in the overheating ratio, the diameter of  Ni particles diminishes from 100 down to 60 nm in average. keywords: eew; fig; nanoparticles; nio; overheating; oxidation; oxide; oxygen; particles; surface cache: chimtech-3968.pdf plain text: chimtech-3968.txt item: #93 of 303 id: chimtech-3974 author: Kiselev, Evgeny Alexandrovich; Gaczynski, Piotr; Eckold, Götz; Feldhoff, Armin; Becker, Klaus-Dieter; Cherepanov, Vladimir Alexandrovich title: Investigations into the structure of La3Ni2−xFexO7±δ date: 2019-08-01 words: 9243 flesch: 69 summary: Table 4 summarizes R-factors and chi-square values (χ2) for all refined patterns in the framework of the proposed structural models with two inequivalent sites for Ni/Fe  — space group Fmmm which provides only a single site for Ni/Fe is included for comparison. The crystal structures of La3Ni2–xFexO7±δ (x  = 0, 0.05, 0.10) solid solutions con- fined to space groups Cmmm, Cmma, and Bmmb with two inequivalent sites (Ni1 and Ni2) for Ni/Fe are shown in  Fig.  keywords: cations; cmmm; doi; fmmm; groups; iron; la3ni2; mössbauer; nickel; sites; solid; space; structure; table; xfexo7±δ cache: chimtech-3974.pdf plain text: chimtech-3974.txt item: #94 of 303 id: chimtech-3986 author: Redkin, Alexander A.; Pershina, Svetlana V.; Il'ina, Evgenia A.; Kataev, Alexander A.; Zaikov, Yurii P. title: Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3 date: 2019-10-16 words: 2761 flesch: 71 summary: Keywords: heat of fusion; melting point; cryolite; heat balance; differential scanning calo- rimetry. Melting points of  mixtures under in- vestigation are in  the interval of  1200– 1220  keywords: cryolite; fluoride; fusion; heat; melting; na3alf6; temperature cache: chimtech-3986.pdf plain text: chimtech-3986.txt item: #95 of 303 id: chimtech-3995 author: Dutta, Uma; Haque, Ariful; Seikh, Md. Motin title: Synthesis, structure and magnetic properties of Ti doped La2MnNiO6 double perovskite date: 2019-09-18 words: 6129 flesch: 71 summary: The double perovskites in which both metal ions are magnetic exhibit ferromagnetic ordering. Ti doping, indicating the robustness of magnetic ordering in La2MnNiO6. keywords: doi; ferromagnetic; mn4; ordering; temperature cache: chimtech-3995.pdf plain text: chimtech-3995.txt item: #96 of 303 id: chimtech-4119 author: Soliev, L.; Jumaev, M. T.; Varkaeva, A. M.; Makhmadov, Kh. R.; Sinoi, G. title: Solubility in the Na,Ca||SO4,HCO3-H2O system at 25 °C date: 2019-12-18 words: 2266 flesch: 59 summary: Na , Ca||SO4, HCO3–H2O system is a constitu- ent of the more complex six-component Na,Ca||SO4,CO3,HCO3,F–H2O system; the phase equilibria in the latter determines the conditions for recycling of aluminum liquid waste. 2. (a) General and (b) salt-area solubility diagrams for the Na,Ca||SO4,HCO4–H2O system at 25 °C b a 135 Table 2 Description of the content for the geometric images in Fig. keywords: crystallization; h2o; phase; russian; solubility; system cache: chimtech-4119.pdf plain text: chimtech-4119.txt item: #97 of 303 id: chimtech-4162 author: Vayenas, Michael; Vaitsis, Christos; Sourkouni, Georgia; Pandis, Pavlos K.; Argirusis, Christos title: Investigation of alternative materials as bifunctional catalysts for electrochemical applications date: 2019-11-19 words: 3029 flesch: 63 summary: Utilization of HKUST-1 as air catalyst shows increased battery performance, as the battery is able to remarkably perform for over 350 consecutive cycles on pulse charging of 20 min without any apparent deterioration (see Fig. 5). Electrochemical performance of Zinc-air batteries using MnO2 (blue) and MnO2-CNTs (black) as air catalysts: a — OCV plots; b — Polarization curves and c — the corresponding power density; d — Energy efficiency curve for MOCN-10 cell (red) regarding its power density curve (black) vs current density 125 of ZnO structures that increase the polari- zation and lead to degradation can easily be observed [12, 13]. keywords: air; battery; catalyst; cell; cycling; fig; mno2; zinc cache: chimtech-4162.pdf plain text: chimtech-4162.txt item: #98 of 303 id: chimtech-4280 author: Kiseleva, D. V. title: Matrix-matched calibration in LA-ICP-MS of silicate, phosphate and carbonate minerals: application of G-Probe samples date: 2020-02-27 words: 3896 flesch: 51 summary: [Interlaboratory quality con- trol of direct atomic emission analysis using the series of rock samples of GeoPT proficiency testing programme for geoanalytical laboratories]. [The studies of evaporation of silicates, phosphates, and sulphides as a basis for LA methodologies of trace element analysis with high spatial resolution]. keywords: analysis; calibration; composition; icp; probe; results; samples; standard cache: chimtech-4280.pdf plain text: chimtech-4280.txt item: #99 of 303 id: chimtech-4281 author: Chebykin, Nikolai S.; Sandalov, Ivan P.; Zamyatin, Dmitry A.; Votyakov, Sergey L. title: Determination of platinum group elements in catalysts recycling products by SEM with energy dispersive spectrometer date: 2020-03-13 words: 1513 flesch: 64 summary: Keywords: PGE; platinum powder concentrate; SEM-EDS; microanalysis; X-ray lines Received: 24.12.2019. The lines for the two last of the listed PGEs do not overlapped with X-ray lines for Al, Cr, Ti, V, Ca, Cl, the  presence of  which is typical for studied samples (Fig. 3); their content was measured by the corresponding X-ray lines Al Kα1, Cr Kα1, Ti Kα1, V Kα1, Ca Kα1, Cl Kα1. keywords: k176; sample cache: chimtech-4281.pdf plain text: chimtech-4281.txt item: #100 of 303 id: chimtech-4284 author: Levina, A. A.; Tadevosyan, N. O.; Petrova, S. A.; Buyanova, E. S.; Morozova, M. V. title: Phase formation processes and synthesis of solid solutions in Ca-R-Nb-M-O systems date: 2020-03-13 words: 2996 flesch: 59 summary: In bismuth-con- taining samples conductivity increases within the  monoclinic phase existence Fig. 2. The  following phases were additionally detected in  Ca1–uRuWO4+δ and CaW1–zNbzO4–δ samples with sub- sequent substitution to  a  small extent: La22W9O60, R2WO6, La0.14WO3, La2(WO4)3. keywords: binbo4; conductivity; phase; samples; solid; temperature cache: chimtech-4284.pdf plain text: chimtech-4284.txt item: #101 of 303 id: chimtech-4370 author: Klyndyuk, A. I.; Chizhova, E. A.; Shevchenko, S. V. title: Spin–state transition in the layered barium cobaltite derivatives and their thermoelectric properties date: 2020-03-25 words: 3179 flesch: 61 summary: Delorme F, Chen C, Pignon B, Schoenstein F, Perriere L, Giovannelli F. Promising high temperature thermoelectric properties of dense Ba2Co9O14 ceramics. It was found that BCO are p-type semiconductors, in which the spin-state transition oc- curs within 460–700 K temperature interval due to change in spin state of cobalt ions, which accompanied the sharp increase in electrical conductivity, activation energy of electrical conductivity, and linear thermal expansion coefficient, while thermo-EMF coefficient decreased. keywords: ba2co9o14; conductivity; spin; state; temperature; values cache: chimtech-4370.pdf plain text: chimtech-4370.txt item: #102 of 303 id: chimtech-4420 author: Selyanin, I. O.; Steparuk, A. S.; Irgashev, R. A.; Mekhaev, A. V.; Rusinov, G. L.; Vorokh, A. S. title: TiO2 paste for DSSC photoanode: preparation and optimization of application method date: 2020-10-21 words: 3990 flesch: 61 summary: A  balance between oxide layer continu- ity and thickness should be found to op- timize the  DSSC operation. To improve the continuity of the layer, preliminary (before applying the paste to the glass) and final (after ap- plying and annealing the paste) treatments with TiCl4 hydrochloric acid solution were performed. 146 Strong adhesion of oxide layers plays an  important role when they have been immersed in a dye solution for a long time. keywords: a.t; cell; commercial; glass; layer; mesh; paste; thickness; tio2 cache: chimtech-4420.pdf plain text: chimtech-4420.txt item: #103 of 303 id: chimtech-4448 author: Antipov, Aleksey S.; Nizov, Vasily A.; Antipova, Anna Yu. title: Technology for the industrial production of K3 series vitamins based on menadione date: 2020-06-29 words: 2282 flesch: 55 summary: The best results were obtained under the process temperature between 20–40 °C, solution pH after dilution of MNB in a range of 5.5–5.7, and MNB content in initial solution of 25–30%. The  return of  substandard MNB to the scope of implementation is expected to be achieved through the sequential pro- cesses presented in schemes 1–3. keywords: content; menadione; mnb; solution cache: chimtech-4448.pdf plain text: chimtech-4448.txt item: #104 of 303 id: chimtech-4449 author: Soliev, L.; Jumaev, M. T. title: Phase complex of the system Na,Ca||SO4,CO3,HCO3-H2O at 100 ºC date: 2020-06-22 words: 3135 flesch: 65 summary: Pr — gayluscite, Na2CO3·CaCO3·2H2O; Cc — calcite CaCO3; Na·1 — Na2CO3; Ber — berkeite, 2Na2SO4·Na2CO3; Table 1 Phase composition of precipitates for the non-variant points in the Na,Ca||SO4,CO3,HCO3-H2O system at 100 °C at the four-component composition level Invariant points Solid phase equilibrium Invariant points Solid phase equilibrium Na2SO4-Na2CO3-NaHCO3-H2O system Na,Ca||SO4,CO3-H2O system E1 4 Te+Nk+3Na·C E10 4 Te+Br+Gb E2 4 Br+Na·1+Tr E11 4 5Ca·Na·3+Gp+Cc E3 4 Te+Br+Tr E12 4 Br+Na·1+Pr E4 4 Te+Tr+3Na·C E13 4 Gb+5Ca·Na·3+Br System CaSO4-CaCO3-Ca(HCO3)2-H2O E14 4 Pr+Cc+5Ca·Na·3 E5 4 Gp+Cc+CaG E15 4 Br+Pr+5Ca·Na·3 Na,Ca||SO4,HCO3-H2O system Na,Ca||CO3,HCO3–H2O system E6 4 Nk+Te+Gb E16 4 Na·1+Tr+Pr E7 4 Gp+5Ca·Na·3+CaG E17 4 Pr+Cc+CaG E8 4 Nk+CaG+Gb E18 4 Nk+3Na·C+CaG E9 4 Gb+CaG+5Ca·Na·3 E19 4 Tr+3Na·C+Pr E20 4 Pr+3Na·C+CaG 73 Tr — trona, Na2CO3·NaHCO3·2H2O; 3Na·C — 3NaHCO3·Na2CO3; Gb — glauberit, Na2SO4·CaSO4; 5Ca·Na·3 – 5CaSO4·Na2SO4·3H2O. Results and discussion Based on the  data listed in  Table  1 the  phase diagram (phase complex) for the  Na,Ca||SO4,CO3,HCO3-H2O system was constructed at  100  °C at  the  level of four component composition of the salt part, which is shown in the figure as pro- jection of tetrahedral faces. 80 7. Tursunbadalov Sh, Soliev L. Phase Equilibria in the quinery Na,K||SO4,CO3,HCO3– H2O system at 75 °C. keywords: component; h2o; phase; system cache: chimtech-4449.pdf plain text: chimtech-4449.txt item: #105 of 303 id: chimtech-4468 author: Tsvetkov, Dmitry S.; Sereda, Vladimir V.; Malyshkin, Dmitry A.; Sednev-Lugovets, Anton L.; Zuev, Andrey Yu.; Ivanov, Ivan L. title: Thermodynamics of formation of solid solutions between BaZrO3 and BaPrO3 date: 2020-05-11 words: 4446 flesch: 66 summary: [ ] 1 3 3 3 BaZr Pr O (BaZrO ) (BaPrO ) ln( ) (1 ) ln(1 ) (1 ) , x x S R x x x x x S x S − = = − ⋅ + − ⋅ − + + − ⋅ + ⋅    (4) where R is  the  universal gas constant, the  first term in  the  right hand side is the entropy of ideal mixing and 3(BaZrO ) S and 3(BaPrO ) S   — the  standard entropies of  BaPrO3 and BaPrO3, respectively. Formation Enthalpies of Tetravalent Lanthanide Perovskites by High Temperature Oxide Melt Solution Calorimetry. keywords: bapro3; bazr1; entropy; formation; oxides; standard; xprxo3 cache: chimtech-4468.pdf plain text: chimtech-4468.txt item: #106 of 303 id: chimtech-4478 author: Tsvetkov, Dmitry S.; Mazurin, Maxim O. title: Crystal structure of mono-β-alanine hydrochloride date: 2020-05-31 words: 2676 flesch: 73 summary: Crystal structure of 3-ammonium propionic acid mono- hydrogen-phosphite, (H3NC2H4COOH)(HPO3H). Each layer consists of two halves linked by hydrogen bonds between carbonyl and NH3 + groups and, also, between NH3 + groups and Cl– anions. keywords: ala·hcl; crystal; hydrogen; structure cache: chimtech-4478.pdf plain text: chimtech-4478.txt item: #107 of 303 id: chimtech-4537 author: Nosova, Emiliya V.; Batanova, Olga A.; Mochulskaya, Nataliya N.; Lipunova, Galina N. title: Synthetic approaches to 2-aryl/hetaryl- and 2-(hetaryl)ylidene derivatives of fluorinated 1,3-benzothiazin-4-ones date: 2020-09-01 words: 3364 flesch: 74 summary: Signals of NH groups are absent in  1H NMR spectra of compounds 12a‑h, spectra of 6,7,8-tri- fluorobenzothiazinones 12a‑d exhibited ddd signal of fluoroarene residue Н5 pro- ton at 8.13–8.24 ppm. Yield 0.646 g (76%), mp 160–162 0С. 1Н NMR, δ (ppm), J (Hz): 7.62 m (2Н, Ph), 7.73 m (1Н, Ph), 8.15 ddd (1Н, H5, 3J 10.3, 4J 7.4, 5J 2.2), 8.19 m (2Н, Ph). keywords: nmr; ppm cache: chimtech-4537.pdf plain text: chimtech-4537.txt item: #108 of 303 id: chimtech-4593 author: Savchuk, M. I.; Starnovskaya, E. S.; Shtaitz, Y. K.; Krinochkin, A. P.; Kopchuk, D. S.; Santra, S.; Rahman, M.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N. title: Direct synthesis of 5-arylethynyl-1,2,4-triazines via direct CH-functionalization date: 2020-09-01 words: 2102 flesch: 69 summary: Kozhevnikov DN, Kozhevnikov VN, Prokhorov AM, Ustinova MM, Rusinov VL, Chupakhin ON, Aleksandrov GG, König B. Consecutive nucleophilic substitution and aza Diels — Alder reaction — an efficient strategy to functionalized 2,2'-bipy- ridines. Studies on the interactions of 5-R-3-(2-pyridyl) — 1,2,4-triazines with arynes: inverse demand aza-Diels — Alder reaction versus aryne-mediated domino process. keywords: 1,2,4; chupakhin; doi; reaction; synthesis; triazines cache: chimtech-4593.pdf plain text: chimtech-4593.txt item: #109 of 303 id: chimtech-4615 author: Azev, Yu. A.; Koptyaeva, O. S.; Eltsov, O. S.; Yakovleva, Yu. A.; Pospelova, T. A. title: New pathways for the synthesis of indolyl-containing quinazoline trifluoroacetohydrazides date: 2020-09-30 words: 3138 flesch: 77 summary: The  structure of  acylation products 7a,b was confirmed by  1H, 13C, 15N, and N N H N N NHR NHN H 4 3d,e A 6a,b 3: d R=H, e R=CH3 1 2 3 4 5 6 7 3a 7a 1'2' 3' 4' 5'6' 7' 8' 8 TFA 51-55% NH N N H R NHN H 1' 3'2' 5' 6' 7' 8' 4a' 8a' CF3COO - H N N N F3C O H R 6: a R=H, b R=CH3 Scheme 3 N N NN H N NH O O F3C H H H TFA N N N OH O CF3 H H N N N O F3C H 3d,e 7a,b -H2O R R R R d R=H; e R=CH3 A B a R=H; b R=CH3 Scheme 4 Fig. 1. The 1H NMR N H N HN 1 2 33a 4 5 6 7 7a 1' 2' 3' R1NH H2N HN R2R1 O 3a-e + R2 1a,b 3: a: R1 = Me; R2 = NO2 b: R1 = Me; R2 = Me c: R1 = Me; R2 = F d: R1 = H; R2 = H e: R1 = Me; R2 = H ∆, EtOH, HCl 2a-d 4' 5' 6' 7' 1: a: R1 = H b: R1 = Me 2: a: R2 = NO2 b: R2 = Me c: R2 = F d: R2 = H Scheme 1 N N H N N NHH3CR NHN H N H CH3 N HN R N H N N O CF3 RCH3 NHN H 4 3a-c A 5a-c 3,5: a R=NO2, b R=CH3, c R=F 1' 4' 3'2' 5' 6' 7' 8' 4a' 8a' 1 2 3 45 6 7 3a 7a 1' 2' 3' 4' 5' 6' 7' 8' 8 CF3COO - TFA H 65–71% Scheme 2 113 spectrum contain characteristic signals: the  H4’’ proton singlet at  6.24 ppm (6a) and a pair of two-proton doublets of aro- matic protons H6’, H5’ (7.61 and 7.92 ppm, respectively (6a)). keywords: nmr; quinazoline cache: chimtech-4615.pdf plain text: chimtech-4615.txt item: #110 of 303 id: chimtech-4618 author: Mikhnevich, E. A.; Safronov, A. P.; Beketov, I. V.; Medvedev, A. I. title: Carbon coated Nickel Nanoparticles in Polyacrylamide Ferrogels: Interaction with Polymeric Network and Impact on Swelling date: 2020-10-07 words: 5174 flesch: 57 summary: In the present study the interfacial interaction of carbon coated Ni MNPs (Ni@C) with polyacryla- mide (PAAm) has been studied in com- parison with Ni MNPs focusing on appli- cation in PAAm ferrogels. XRD pattern of Ni MNPs 121 the unit cell parameter а = 0.3533(3) nm. keywords: carbon; composites; enthalpy; ferrogels; mnps; nanoparticles; ni mnps; ni@c; paam; surface; swelling; water cache: chimtech-4618.pdf plain text: chimtech-4618.txt item: #111 of 303 id: chimtech-4635 author: Krinochkin, A. P.; Guda, M. R.; Rammohan, A.; Kopchuk, D. S.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N. title: A convenient synthetic approach to 5-(het)arylhydrazine substituted 1,2,4-triazines date: 2020-12-20 words: 1950 flesch: 73 summary: The  starting 5-cyano-1,2,4-triazines 1 were obtained according to the described method [8]. ISSN 2409–5613 Introduction 1,2,4-Triazines with moieties of (hetero)arylhydrazines at С5 position are of  interest as  substrates for further heterocyclizations for the  synthesis of different condensed triazines, e.g., 2H- pyrazolo[3,4-e][1,2,4]triazin-7(6H)  — ones, 2,6-dihydro-[1,2,4]triazino[5,6-d] keywords: 1,2,4; chem; chupakhin; synthesis; triazines cache: chimtech-4635.pdf plain text: chimtech-4635.txt item: #112 of 303 id: chimtech-4636 author: Krinochkin, A. P.; Savchuk, M. I.; Starnovskaya, E. S.; Shtaitz, Y. K.; Kopchuk, D. S.; Nikonov, I. L.; Kovalev, I. S.; Zyryanov, G. V.; Rusinov, V. L.; Chupakhin, O. N. title: New monomers for (bi)pyridine-containing polymers date: 2020-12-20 words: 2382 flesch: 75 summary: Sato Y, Kagotani M, Yamamoto T, Souma Y. Novel Effective Poly(2,2′-Bipyridine- 5,5′-Diyl)-CuCl2 Catalyst for Synthesis of Dimethyl Carbonate (DMC) by Oxidative Carbonylation of Methanol. Synthesis and characterization of pyridine-based polybenzimidazoles for high temperature polymer electrolyte membrane fuel cell applicationsx. keywords: mmol; synthesis cache: chimtech-4636.pdf plain text: chimtech-4636.txt item: #113 of 303 id: chimtech-4655 author: Moseev, T. D.; Khasanov, A. F.; Varaksin, M. V.; Kopchuk, D. S.; Kovalev, I. S.; Taniya, O. S.; Rahman, M.; Santra, S.; Zyryanov, G. V.; Chupakhin, O. N.; Charushin, V. N. title: Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations date: 2020-12-20 words: 2892 flesch: 72 summary: 217 Studies of  the  interactions of  calix- arenes 3–4 with cations The studies of the interactions of com- pounds 3–4 with Zn2+ and Cd2+ cations were carried out at  the  concentrations of  3–4 of  (1-9)·10–6 M (depending on the  value of  the  absorption coefficient (A  ≤ 0.1)) in  anhydrous freshly distilled THF. The response of calixarene 3 to Zn2+ and Cd2+ cations is shown below. keywords: calixarene; cations; chem; reaction; synthesis cache: chimtech-4655.pdf plain text: chimtech-4655.txt item: #114 of 303 id: chimtech-4715 author: Frolov, Evgeniy I.; Notina, Polina V.; Zvonarev, Sergey V.; Il'ina, Evgeniya A.; Churkin, Vyacheslav Yu. title: Synthesis and Research of Alumina Ceramics Properties date: 2020-12-21 words: 3128 flesch: 56 summary: Precipitation method The alumina oxide was obtained by the method of alumi- num nitrate precipitation by the alkali (potassium hydrox- ide) up to pH = 9–10. Thus, the purpose of the study is to obtain aluminum oxide by various synthesis methods, to produce ceramics on its basis and to research the optical properties of the ceramics obtained. keywords: alumina; ceramics; gel; method; precipitation; sol cache: chimtech-4715.pdf plain text: chimtech-4715.txt item: #115 of 303 id: chimtech-4719 author: Zhuravlev, Victor D.; Nefedova, Ksenia V.; Evschik, Elizaveta Yu.; Sherstobitova, Elena A.; Kolmakov, Valery G.; Dobrovolsky, Yury A.; Porotnikova, Natalia M.; Korchun, Andrey V.; Shikhovtseva, Anna V. title: Effect of lithium borate coating on the electrochemical properties of LiCoO2 electrode for lithium-ion batteries date: 2020-12-21 words: 4408 flesch: 57 summary: Most coating strategies are based on the sol-gel method or impregnation of cathode materials powders with salt solutions with subsequent drying and annealing [1-3, 5-7]. Fig. 5 shows the charge-discharge curves of the first cycle for LCO, LCO+5% LBO and LCO +7% LBO. keywords: cathode; coating; combustion; discharge; doi:10.1016; electrochemical; lbo; lco; licoo2; lithium; material; powders; solid; solution; state; synthesis cache: chimtech-4719.pdf plain text: chimtech-4719.txt item: #116 of 303 id: chimtech-4739 author: Filisteev, O. V.; Sharov, A. V. title: To the question of the influence of a silanol cover on the protolytic properties of aminopropyl silica gels date: 2020-12-21 words: 3141 flesch: 60 summary: [ ]SiOHs s sSiOH SiO–C≡  = ≡ + ≡  (6) where NH s2 C‑ and SiOHsC≡ are the total con- centration of  surface amino groups and silanol groups, respectively. The paper proposes a model that describes the acid-base properties of amino groups grafted onto the surface, taking into account their interaction with silanol groups. keywords: amino; aminopropyl; concentration; groups; hydrogen; ions; silanol; silica; surface cache: chimtech-4739.pdf plain text: chimtech-4739.txt item: #117 of 303 id: chimtech-4768 author: Azev, Yuri A.; Koptyaeva, Olga S.; Eltsov, Oleg S.; Tsmokalyuk, Anton N.; Pospelova, Tatyana A. title: 8-Hydroxy-5-nitroquinoline as a C-nucleophilic reagent in the reaction of C, C-coupling with quinazoline date: 2020-12-27 words: 1608 flesch: 67 summary: As a result of the reaction of C, C-coupling, a stable σ-adduct containing the drug nitroxalin on a heterocyclic carrier was obtained. Keywords: 5-nitro-8-hydroxyquinoline; quinazoline; C, C-coupling Received: 20.11.2020. keywords: hydroxyquinoline; quinazoline cache: chimtech-4768.pdf plain text: chimtech-4768.txt item: #118 of 303 id: chimtech-4769 author: Shaydullin, S. M.; Belanova, E. A.; Kozlov, P. V.; Remizov, M. B.; Dvoryanchikova, E. M. title: Investigation of Borosilicate Glasses with Simulated HLW Components and Determination of Their Chemical Durability date: 2021-03-04 words: 4026 flesch: 54 summary: Compositions of borosilicate glasses with HLW components are described, temperatures of their melting and easy pouring are determined. Compositions of the investigated glasses, melting temperatures and easy pouring temperatures G la s s N o Mass fraction of oxides in borosilicate glasses, % Тm., °С Тe.p., °С SiO2 B2O3 Li2O Na2O Al2O3 Fe2O3 Cr2O3 NiO MnO CaO K2O MgO SO3 Glass frit 72.00 8.00 8.00 12.00 - - - - - - - - - - 1200 1 61.43 6.80 6.80 18.69 3.19 0.56 0.26 0.67 0.18 0.09 0.67 0.13 0.54 1050 1150 2 50.85 5.60 5.60 25.37 6.37 1.13 0.52 1.33 0.36 0.19 1.34 0.26 1.07 1000 1100 3 40.28 4.40 4.40 32.06 9.56 1.69 0.77 2.00 0.55 0.28 2.01 0.39 1.61 950 1000 4 29.71 3.20 3.20 38.75 12.74 2.26 1.03 2.66 0.73 0.37 2.69 0.52 2.14 900 950 a Тm. - melting temperature b Тe.p. - easy pouring temperature Chimica Techno Acta 2021, vol. keywords: borosilicate; chemical; composition; glasses; hlw; leaching; sludge; temperature; waste cache: chimtech-4769.pdf plain text: chimtech-4769.txt item: #119 of 303 id: chimtech-4800 author: Yakovishin, L. A.; Grishkovets, V. I.; Korzh, E. N.; Golovchenko, I. V.; Nagirnyak, A. A. title: Molecular Complexation of Hederasaponin C with Cholesterol in Aqueous Isopropyl Alcohol date: 2020-12-13 words: 1695 flesch: 73 summary: UV spectra of Chol solutions (0.50 · A character- istic feature of triterpene glycosides is their ability to form molecular complexes with sterols keywords: chol; complex; hedc cache: chimtech-4800.pdf plain text: chimtech-4800.txt item: #120 of 303 id: chimtech-4801 author: Maraeva, E. V.; Permiakov, N. V.; Kedruk, Y. Y.; Gritsenko, L. V.; Abdullin, Kh. A. title: Creating a virtual device for processing the results of sorption measurements in the study of zinc oxide nanorods date: 2020-12-14 words: 1606 flesch: 57 summary: Plots of adsorption isotherms for samples 1–5 Table 1 ZnO specific surface area vs. heat treatment temperature and duration № Heat treatment parameters SBET, m 2/g T, °C t, hours 1 400 2 13 2 400 4 9 3 400 10 10 4 700 2 5 5 700 4 5 156 Fig. 1 shows the nitrogen adsorption isotherm for a series of zinc oxide samples 1–5. A program has been developed that automates the process of calculating the size of nanorods based on sorption analysis data. keywords: analysis; samples; sorption; surface; zinc cache: chimtech-4801.pdf plain text: chimtech-4801.txt item: #121 of 303 id: chimtech-4802 author: Dzyurkevich, M. S.; Shtyrlin, N. V.; Shtyrlin, Y. G. title: Synthetic route optimization of Sumepirin antiepileptic drug candidate date: 2020-12-14 words: 4523 flesch: 66 summary: After reaction is finished, reaction mixture is cooled down to the room temperature and neutralized by the 1M solution of hy- drochloric acid to  the  pH = 6.5. After whole amount is added reaction mixture is stirred for additional 0.5  h and then extracted with 3×200 ml of distilled water and washed with brine. keywords: compound; mixture; ppm; reaction; sodium; synthesis; water cache: chimtech-4802.pdf plain text: chimtech-4802.txt item: #122 of 303 id: chimtech-4803 author: Titov, Anatolii; Shrimpton, John; Shao, Cheng; Li, Zhuohan title: Reducing of industrial atmospheric emissions using electrocyclone date: 2020-12-14 words: 1361 flesch: 62 summary: Keywords: gas purification; electrocyclone; cyclone; electrostatic precipitator Received: 16.10.2020. It is shown, that without an electric field, the degree of gas purification from parti- cles with a size less than 50 microns de- Table 1 Characteristics of the materials under research № Material True density, k/gm3 Specific electric resistance, Ohm·m Particle diameter, μm d10 d50 d90 1 Sodium percarbonate 2144 <104 10 35 67 2 Iron-vanadium concentrate 5100 103 16 73 90 3 Sublimates of furnaces 4600 107 2.5 6 15 4 Fly ash 2200 >108 15 32 64 Fig. keywords: u=0; u=17 cache: chimtech-4803.pdf plain text: chimtech-4803.txt item: #123 of 303 id: chimtech-4804 author: Trinkunas, Anton; Pomortseva, Lidia; Titov, Anatolii; Rusinova, Zalina title: Using the profiled elements to increase electrocyclone effectiveness date: 2020-12-14 words: 1415 flesch: 62 summary: Profiled elements 175 The  second part of  the  study was the visual and partly quantitative evaluation of the installation of profiled elements on the external collecting electrodes of the an- nular channel. 2015;156(2):795–802. doi:10.1016/j.seppur.2015.11.004 Table 1 Comparative effectiveness of the profiled elements № Element type Collected ash mass, g Quantity of elements, piece Collected ash mass corresponding on 1 element, g 1 No elements 16.2 2 8.1 2 C-shaped 26.0 2 13.0 4 C-shaped double 27.6 2 13.8 5 C-shaped rounded 22.4 4 5.6 6 Z-shaped 34.0 3 11.3 keywords: collecting; electrocyclone; elements; entrainment cache: chimtech-4804.pdf plain text: chimtech-4804.txt item: #124 of 303 id: chimtech-4805 author: Tsvetkova, I. V.; Golovanov, A. A.; Reznikova, N. S.; Chirkunova, N. V. title: Obtaining cyclopentanone from acidic wastewater of caprolactam production date: 2020-12-14 words: 685 flesch: 54 summary: Keywords: wastes from caprolactam production; adipic acid; cyclopentanone; derivatography; calcium adipate; gas chromatography Received: 22.10.2020. Obtaining cyclopentanone from acidic wastewater of caprolactam production 177 D O I: 1 0. 15 82 6/ ch im te ch .2 02 0. 7. 4. 07 Tsvetkova I. V., Golovanov A. A., Reznikova N. S., Chirkunova N. V. Chimica Techno Acta. 2020. keywords: cyclopentanone; fig; production cache: chimtech-4805.pdf plain text: chimtech-4805.txt item: #125 of 303 id: chimtech-4806 author: Yakovishin, L. A.; Grishkovets, V. I. title: Intermolecular Interaction of Glycyrrhizin with Cholesterol date: 2020-12-14 words: 2431 flesch: 73 summary: Similar shifts of  the  absorp- tion bands of  C=O bonds in  IR spectra were previously observed during the in- teraction of ivy triterpene glycosides with Chol [12], as well as during the formation of GA and GC complexes [11]. These facts may indi- cate the presence of hydrophobic contacts between Chol and GC molecules. keywords: chol; cm–1 cache: chimtech-4806.pdf plain text: chimtech-4806.txt item: #126 of 303 id: chimtech-4807 author: Patianova, A. O.; Ivanova, K. Yu.; Rogozhina, L. G.; Kuzmin, M. V.; Semenov, V. L. title: Improving the environmental production of electrodes for solar panels date: 2020-12-14 words: 2052 flesch: 52 summary: The synthesized compounds were used to de- velop flux compositions for tinning copper wire and producing electrodes for solar panels. The possibility of using a flux for hot tinning of copper wire is shown, which makes it possible to increase the environmental friendliness of the production of electrodes for solar panels. keywords: ch2; copper; flux; h2c; production; tinning; wire cache: chimtech-4807.pdf plain text: chimtech-4807.txt item: #127 of 303 id: chimtech-4808 author: Khizrieva, S. S.; Vetrova, E. V.; Borisenko, S. N.; Maksimenko, E. V.; Borisenko, N. I. title: Synthesis and study of complexes of the novel Russian antiviral drug Camphecene with pentacyclic triterpenes of licorice date: 2020-12-14 words: 2469 flesch: 65 summary: Obtained from the binding constant, the change in Gibbs energy ∆G = –38.4 kJ. Based on the obtained negative value, it can be concluded that the reaction proceeds spontaneously during the forma- tion of GA and Camph complexes. [Mass spectrometry of glycyrrethenic acid complexes with striptomycines]. keywords: acid; camph; camphecene; complexes; fig; gla cache: chimtech-4808.pdf plain text: chimtech-4808.txt item: #128 of 303 id: chimtech-4809 author: Ivanova, K. Yu.; Kuzmin, M. V.; Kol’tsov, N. I. title: Synthesis and research of polyfunctional silicon-containing amines – new promoters of adhesion date: 2020-12-14 words: 1694 flesch: 55 summary: Keywords: 3-aminopropyltriethoxysilane; aminoalkoxysiloxanes; adhesion promoters Received: 30.10.2020. Amine compounds are the main hardeners for epoxy compositions. keywords: adhesion; compounds; epoxy; nh2; reaction cache: chimtech-4809.pdf plain text: chimtech-4809.txt item: #129 of 303 id: chimtech-4814 author: Karsakova, O. A.; Kuzmin, M. V. title: Synthesis and research of photocurable protective coatings on the basis of olygoesteracrylates date: 2020-12-21 words: 1181 flesch: 44 summary: It was found that the composition based on polyethylene glycol dimethacrylate modified with triethylene glycol dimethacrylate at a ratio of 70:30 has the highest strength. The photocurable compositions were obtained by mixing at different ratios the following methacrylic acid esters: polyethylene glycol dimethacrylate 400 and triethylene glycol dimethacrylate ether, polyethylene glycol dimethacrylate 400 and oligourethane dimethacrylate, polyethylene glycol dimethacrylate 400 and pentae- rythritol tetraacrylate. keywords: compositions; dimethacrylate; glycol; polyethylene cache: chimtech-4814.pdf plain text: chimtech-4814.txt item: #130 of 303 id: chimtech-4815 author: Sharapov, A. D.; Fatykhov, R. F.; Khalymbadzha, I. A.; Chupakhin, O. N. title: Direct CH/CH functionalization of 1,3-dihydroxy-9H-xanthen-9-one and 1,3-dimethoxy-9H-xanthen-9-one with 1,2,4-triazines and quinazoline date: 2020-12-21 words: 1711 flesch: 68 summary: 1H NMR (DMSO-d6): 1H NMR (DMSO-d6): keywords: 1,3 cache: chimtech-4815.pdf plain text: chimtech-4815.txt item: #131 of 303 id: chimtech-4827 author: Kutuzova, T. M.; Kuznetzova, O. M.; Akhmedyanova, R. A. title: Cation-exchange resins as heterogeneous catalysts for the synthesis of 1,3-butadiene from propylene and formaldehyde date: 2021-04-28 words: 2895 flesch: 55 summary: The relevance of the development of a new energy- efficient, sophisticated process based on the use of modern achievements of chemical science and technology, led us to study the regularities of BD synthesis from isopropyl alco- hol (IPA) (propylene) and FA in the presence of CER – het- erogeneous acid catalysts that allow reactions to proceed under mild conditions and are not corrosive. Table 2 Main products yield obtained at BD synthesis from IPA and FA at different temperatures: keywords: formaldehyde; reaction; synthesis; yield cache: chimtech-4827.pdf plain text: chimtech-4827.txt item: #132 of 303 id: chimtech-4866 author: Zhuravleva, D. A.; Kazakov, A. V.; Selezneva, I. S.; Baranova, A. A. title: Relevance of application of irradiated starter cultures to production of fermented milk products date: 2020-12-28 words: 3014 flesch: 53 summary: Relevance of application of irradiated starter cultures to production of fermented milk products Nowadays yogurt, fermented milk products, enriched with biologically active substances, acquire increasingly important significance in people’s diets. keywords: cultures; euflorine; liquid; microorganisms; milk; products; russian; starter cache: chimtech-4866.pdf plain text: chimtech-4866.txt item: #133 of 303 id: chimtech-4867 author: Maskaeva, L. N.; Kutyavina, A. D.; Pozdin, A. V.; Miroshnikov, B. N.; Miroshnikova, I. N.; Markov, V. F. title: Annealing effect on temperature stability and mechanical stress at the “CdxPb1−xS film – substrate” interface date: 2020-12-28 words: 3895 flesch: 55 summary: As  for the  film of  individual lead sulfide and solid solutions films based on PbS, elastic compressive stresses are cre- ated in them, that evidenced by the nega- tive temperature dependences σ = f (T) in Fig. 4. The  absolute value of  mechani- cal stresses of  these films increases with an increasing the annealing temperature from 350 to  893  K.  Compressive stress- es rise in absolute terms from about 200 to 1200 kN/m2 for PbS and from 150–250 to 2000–2750 kN/m2 for CdxPb1−xS under these conditions. Gardi SB, Singh A, Yousuf M. Structural stability of PbS films as function of tem- perature. keywords: annealing; cds; cdxpb1; expansion; films; pbs; solutions; stresses; substrate; temperature cache: chimtech-4867.pdf plain text: chimtech-4867.txt item: #134 of 303 id: chimtech-4869 author: Grigoreva, T. F.; Pavlov, E. A.; Vitiaz, P. A.; Lyakhov, N. Z. title: Mechanochemical synthesis of intermetallic compounds in the system gallium – ruthenium date: 2021-02-08 words: 2629 flesch: 61 summary: Abstract The interaction of a solid inert metal Ru with liquid active metal Ga during mechanical activation in a high-energy planetary ball mill was studied using the X-ray diffraction and the high resolution scan- ning electron microscopy with energy dispersive X-ray microa- nalyses. Pene- tration of liquid metal along the grain boundaries sharply reduces the strength characteristics of the latter [6–9]. keywords: activation; compounds; fig; gallium; intermetallic; liquid; min; ruthenium cache: chimtech-4869.pdf plain text: chimtech-4869.txt item: #135 of 303 id: chimtech-4914 author: Loza, S. A.; Smyshlyaev, N. A.; Korzhov, A. N.; Romanyuk, N. A. title: Electrodialysis concentration of sulfuric acid date: 2021-03-31 words: 3761 flesch: 49 summary: Thus, the use of polyaniline for the modification of cation- exchange membranes reduces the current efficiency and reduces energy consumption in the process of electrodial- ysis processing of sulfuric acid solutions [24]. Ion Transport in sulfuric acid solution through anisotropic com- posites based on heterogeneous membranes and polyaniline. keywords: acid; concentration; diffusion; doi:10.1016; electrodialysis; exchange; membranes; process; separation; solutions; sulfuric cache: chimtech-4914.pdf plain text: chimtech-4914.txt item: #136 of 303 id: chimtech-4934 author: Korchun, A. V.; Evshchik, E. Yu.; Baskakov, S. A.; Bushkova, O. V.; Dobrovolsky, Y. A. title: Influence of a binder on the electrochemical behaviour of Si/RGO composite as negative electrode material for Li-ion batteries date: 2021-01-12 words: 3759 flesch: 59 summary: The theoretical capacity (Qth) of the composite is calculated using formula (1): ,th Si Si RGO RGOQ Q Q= ⋅ω + ⋅ω (1) where QSi and QRGO are theoretical capaci- ties of Si and RGO, respectively; ωSi and ωRGO are mass fractions of  Si and RGO in the composite, respectively. Lestriez B, Bahri S, Sandu I, Roue L, Guyomard D. On the binding mechanism of  CMC in  Si negative electrodes for Li-ion batteries. keywords: batteries; binder; capacity; cmc; composite; cycle; electrode; ion; material; rgo; silicon cache: chimtech-4934.pdf plain text: chimtech-4934.txt item: #137 of 303 id: chimtech-4960 author: Nekrasov, K. A.; Galashev, A. E.; Seitov, D. D.; Gupta, S. K. title: Diffusion of oxygen in hypostoichiometric uranium dioxide nanocrystals. A molecular dynamics simulation date: 2021-03-31 words: 4396 flesch: 57 summary: To clarify the features of oxygen diffusion at signifi- cant deviations of UO2x from stoichiometry, computation- al simulation of this process is of interest. Molecular dynamic modeling of oxygen diffusion in UO2 was previously carried out at temperatures signifi- cantly higher than 923 K keywords: coefficient; crystal; diffusion; nucl; oxygen; potentials; uo2; uranium cache: chimtech-4960.pdf plain text: chimtech-4960.txt item: #138 of 303 id: chimtech-4962 author: Tolkacheva, Anna S.; Shkerin, Sergey N.; Petrova, Sofya A.; Fedorova, Olga M.; Titova, Svetlana G.; Leonidov, Ivan I. title: In situ synthesis, structural chemistry and vibrational spectroscopy of Zn-doped Ca5Mg4(VO4)6 date: 2022-03-23 words: 5780 flesch: 70 summary: For example, the synthesis of Ca5M4(VO4)6 (M = Mg and Zn) can be done tak- ing MgCO3, ZnO, CaCO3 and either NH4VO3, or V2O5 as initial reagents with further annealing of the reaction mixture at 800–850 °C. °C and the rate <5 °C/min with the dwell time of 1 h at every step. keywords: 0≤x≤4; acta; fig; garnet; group; modes; phase; raman; solid; structure; synthesis; temperature; xrpd cache: chimtech-4962.pdf plain text: chimtech-4962.txt item: #139 of 303 id: chimtech-4978 author: Khizrieva, S. S.; Vetrova, E. V.; Borisenko, S. N.; Maksimenko, E. V.; Borisenko, N. I. title: Synthesis and study of complexes of the novel Russian antiviral drug Camphecene with Plant’s Flavonoids date: 2021-04-28 words: 2982 flesch: 58 summary: The UV-VIS spec- trophotometric analysis of the mixture of Camph and Qu has shown that the increase in Qu concentration is accom- panied by the change in the shape of the Camph spectrum due to complex formation (its maximum of absorbance becomes lower). The obtained results demonstrate the high potential of flavonoids Qu and Rut to the development of novel phar- maceutical forms using the Camphecene in the form of molecular complexes, as the novel forms of delivery. keywords: camph; camphecene; complexes; concentration; fig; quercetin; rut cache: chimtech-4978.pdf plain text: chimtech-4978.txt item: #140 of 303 id: chimtech-5021 author: Kutyavina, A. D.; Maskaeva, L. N.; Voronin, V. I.; Anokhina, I. A.; Markov, V. F. title: Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath date: 2021-06-10 words: 6029 flesch: 57 summary: The crystal structure of solid solution films deposited from solutions with 0.005, 0.01, 0.1, 0.12, and 0.14 mol/l concentrations of cadmium chloride was studied by X-ray diffraction. Experimental The reaction mixture for the chemical bath deposition of CdxPb1−xS solid solutions films included the following components. keywords: bath; cadmium; cds; cdxpb1−xs; concentration; content; deposition; ethylenediamine; films; formation; lead; mol; pbs; reaction; solid; solutions; sulfide cache: chimtech-5021.pdf plain text: chimtech-5021.txt item: #141 of 303 id: chimtech-5031 author: Bryuzgina, A. V.; Urusova, A. S.; Ivanov, I. L.; Cherepanov, V. A. title: Phase equilibria in the YFeO3 – YСoO3 system in air date: 2021-04-13 words: 3955 flesch: 71 summary: Yttrium ferrite quenched from high temperature within the entire range (1173 – 1473 K) or slowly cooled to RT possesses ortho- rhombically distorted perovskite structure, which is in good agreement with the results reported earlier [1-4]. Fig. 1 illustrates XRD patterns of YFeO3 prepared at vari- ous conditions and evaluated values of unit cell parame- ters, as an example. Since YСоO3 is only stable below 1266 K, it is likely that a continuous series of YFe1-xCoxO3 solid solutions cannot be obtained at higher temperatures. keywords: fig; phase; solid; structure; system; temperature; yfe1; yfeo3 cache: chimtech-5031.pdf plain text: chimtech-5031.txt item: #142 of 303 id: chimtech-5055 author: Jawad, Akram Jassim; Braihi, Auda J. title: Physical and Chemical Characterization of Drag Reducing Polymer Based on Polyvinylpyrrolidone (PVP) in Human Blood Flow date: 2021-05-11 words: 3529 flesch: 62 summary: Atomic force microscopy (AFM) parameters provide other indicators about the role of PVP as a drag reduction agent for blood flow, where all of the amplitude, hy- brid and special parameters decreased significantly. [15] In our present research, we tried to use Polyvinylpyr- rolidone (PVP) as a bio drag reducing agent and water- soluble polymer in blood flow at very tiny additive ratios. keywords: blood; drag; fig; flow; polymer; pvp; rate; reduction; shear; viscosity cache: chimtech-5055.pdf plain text: chimtech-5055.txt item: #143 of 303 id: chimtech-5061 author: Davidov, D. V.; Nosova, E. N.; Loza, S. A.; Achoh, A. R.; Korzhov, A. N.; Melnikov, S. S. title: Using a microheterogeneous model to assess the applicability of ion-exchange membranes in the process of reverse electrodialysis date: 2021-04-30 words: 5956 flesch: 59 summary: Długołecki P, Nymeijer K, Metz S, Wessling M. Current status of ion exchange membranes for power generation from salin- ity gradients. Spe- cific ion effects on membrane potential and the permselectiv- ity of ion exchange membranes. keywords: batch; concentration; conductivity; diffusion; exchange; exchange membranes; ion; membranes; mk-40; permeability; ralex; solution cache: chimtech-5061.pdf plain text: chimtech-5061.txt item: #144 of 303 id: chimtech-5072 author: Kalinina, E. G.; Rusakova, D. S.; Pikalova, E. Yu. title: Electrophoretic deposition of coatings and bulk compacts using magnesium-doped aluminum oxide nanopowders date: 2021-05-07 words: 4518 flesch: 59 summary: 4. Conclusions The study of electrophoretic deposition of coatings and bulk compacts from stable suspensions of the nanopowder of aluminum oxide doped with magnesium in an isopropyl alcohol media with subsequent sintering of samples into dense ceramics was carried out. Kishida S, Ju D, He H, Li Y. Coating of γ-Al2O3 on the stainless steel substrate by electrophoretic deposition method. keywords: al2o3; bulk; ceramics; coatings; compacts; deposition; electrophoretic; epd; method; nanopowder; suspension; thickness cache: chimtech-5072.pdf plain text: chimtech-5072.txt item: #145 of 303 id: chimtech-5075 author: Mikhaylovskaya, Z. A.; Buyanova, E. S.; Petrova, S. A.; Klimova, A. V. title: ABO4 type scheelite phases in (Ca/Sr)MoO4 - BiVO4 - Bi2Mo3O12 systems: synthesis, structure and optical properties date: 2021-04-29 words: 3778 flesch: 62 summary: The areas of solid solutions (ordinary scheelite and superstructured scheelite) and inveatigated fields of triple phase diagram are shown at Fig. The areas of scheelite-type solid solutions (red), superstructured scheelite solid solutions (blue) and tree-phases areas (gray) in CaMoO4 - BiVO4 - Bi2Mo3O12 (a) and SrMoO4 - BiVO4 - Bi2Mo3O12 (b) ternary diagram. keywords: bismuth; compositions; doi:10.1016; fig; properties; scheelite; solid; sr1−1.5x; srmoo4; ybix+yфxmo1; yvyo4 cache: chimtech-5075.pdf plain text: chimtech-5075.txt item: #146 of 303 id: chimtech-5076 author: Azev, Yu. A.; Koptyaeva, O. S.; Pospelova, T. A. title: New possibilities of the functionalization of 6-hydrazino-1,3-dimethyluracils: one-pot synthesis of 5,7-dimethylpyrazolopyrimidine-4,6-dione and 1,3-dimethyl-5-arylidenebarbituric acid derivatives date: 2021-04-28 words: 2486 flesch: 71 summary: It is known that pyrazolopyrimidine derivatives have a wide spectrum of biological activity, including antimicrobial[1, 2, 3], antivi- ral[4, 5], anti-inflammatory and etc. We found that heating hydrazones 2а-c in TFA gave 5,7-dimethylpyrazolopyrimidine-4,6-diones 3а-c and 5- benzylidene-1,3-dimethylpyrimidine-2,4,6-trione deriva- tives 4а-c. Considering the literature data, it can be as- sumed that the formation of pyrazolopyrimidines 3a-c occurs through the 5-trifluoroacyl intermediate A. The formation of intermediate A occurs as a result of acylation of the starting hydrazones 2a-c of TFA. keywords: ch3 cache: chimtech-5076.pdf plain text: chimtech-5076.txt item: #147 of 303 id: chimtech-5080 author: Mukhortova, L. I.; Nasakin, O. E.; Eremkin, A. V.; Glushkov, I. V. title: Continuous copper leaching technology date: 2021-04-13 words: 1722 flesch: 57 summary: 3. Results and Discussion The main criteria for the effectiveness of the process of leaching copper with nitric acid are the concentration of copper ions in the solution at the reactor outlet and the formation of nitrogen dioxide. High values of redox potentials of nitric acid solutions allow dissolving copper. keywords: acid; copper; nitric; solution; working cache: chimtech-5080.pdf plain text: chimtech-5080.txt item: #148 of 303 id: chimtech-5081 author: Yaschenko, N. N.; Zhitar, S. V.; Zinovjeva, E. G. title: Determination of phenolic compounds in medicinal preparations by galvanostatic coulometry date: 2021-04-13 words: 1636 flesch: 42 summary: It was found that for the quantitative de- termination of phenolic acids, the optimal reagent is electrogenerat- ed bromine, for rutin - electrogenerated bromine and iodine, and for ascorbic acid - any of the studied electrogenerated titrants (Cl2, Br2, I2 and [Fe(CN)6] 3- ). Results and Discussion The objects of the study were: rutin - as a representative of the class of flavonoids and polyphenols; salicylic acid as a representative of phenolic acids and drugs containing phenolic compounds such as «Ascorutin», «Salicylic Paste» and «Salicylic Ointmen». keywords: acid; ascorbic; ascorutin; determination cache: chimtech-5081.pdf plain text: chimtech-5081.txt item: #149 of 303 id: chimtech-5083 author: Kovalev, I. S.; Sadieva, L. K.; Taniya, O. S.; Yurk, V. M.; Minin, A. S.; Kopchuk, D. S.; Zyryanov, G. V.; Charushin, V. N.; Chupakhin, O. N. title: Bispyrenylalkane Chemosensor for the Naked-eye Detection of Nitro-explosives date: 2021-05-20 words: 2304 flesch: 62 summary: Can J Chem. J Chem Phys. keywords: chem; detection; doi:10.1021; emission; excimer; explosives; fluorescence; pyrene; quenching; tnt cache: chimtech-5083.pdf plain text: chimtech-5083.txt item: #150 of 303 id: chimtech-5085 author: Snegirev, V. A.; Yurk, V. M. title: The development of technology for production of zeolites from fly-ash from Troitskaya power plant date: 2021-04-16 words: 3048 flesch: 62 summary: Synthesized from fly ash zeolites are used in the purifi- cation of water from metal ions. The main components of fly ash are silicon oxides, alumi- num, iron, calcium, potassium, sodium and titanium, the main content of which in all ash is 50-60% SiO2, 20-30% Al2O3, 5-10% Fe2O3 [2,3]. keywords: activation; ash; composition; fly; phase; plant; power; temperature; troitskaya; zeolite cache: chimtech-5085.pdf plain text: chimtech-5085.txt item: #151 of 303 id: chimtech-5086 author: Yurk, V. M.; Zaytsev, O. B.; Zaytseva, A. V.; Malahova, N. A. title: Using the mineral component of building refuse in heavy metals sorption from their mixture date: 2021-04-16 words: 3480 flesch: 54 summary: The mechanisms of accumula- tion of heavy metal ions on the surface of the mixture particles are described. , № 20218112 LETTER 2 of 5 for the production of a geochemical barrier to the migra- tion of heavy metal ions is promising. keywords: barrier; building; ions; metals; mixture; model; sand; soils; sorption; surface cache: chimtech-5086.pdf plain text: chimtech-5086.txt item: #152 of 303 id: chimtech-5091 author: Kovalev, I. S.; Sadieva, L. K.; Taniya, O. S.; Kopchuk, D. S.; Zyryanov, G. V.; Ulomsky, E. N.; Rusinov, V. L.; Chupakhin, O. N. title: Detection of Anti-viral Drug Riamilovir and Herbicides in Aqueous Media by Using Pyrene-based Fluorescent Chemosensors date: 2021-05-20 words: 1451 flesch: 52 summary: Analysis of fluorescence quenching was performed on the basis of a Stern-Volmer equation of static quenching (1): 𝐼0 𝐼 = 1 + 𝐾SV Despite the fact that the antiviral drug Riami- lovir (Triazavirin ®) is not a specific drug against SARS- CoV-2, it has successfully shown itself among other drugs in reducing the incidence of respiratory, cardiac, hepatic, renal and other complications, associated with corona- virus infection (COVID-19) keywords: chemosensors; fluorescence; quenching; riamilovir cache: chimtech-5091.pdf plain text: chimtech-5091.txt item: #153 of 303 id: chimtech-5102 author: Tokmeilova, S.; Maraeva, E. V. title: Overview of sorption analysis capabilities for meso- and microporous zeolites nanomaterials date: 2021-07-07 words: 3086 flesch: 51 summary: Fiziko-himicheskie osnovy adsorbcionnogo ana- liza dispersnyh i poristyh materialov [Physicochemical bases of adsorption analysis of dispersed and porous materials]. As can be seen from Table 3, in the case of long-term storage of zeolite samples in high humidity conditions, the measured specific surface area of the samples decreases by 2–3 times. keywords: adsorption; analysis; materials; method; micropores; nitrogen; sample; surface; volume cache: chimtech-5102.pdf plain text: chimtech-5102.txt item: #154 of 303 id: chimtech-5103 author: Raskovalov, A. A.; Saetova, N. S.; Popov, I. S. title: Structural changes in V2O5-P2O5 glasses: non-constant force field molecular dynamics and IR spectroscopy date: 2021-06-10 words: 7809 flesch: 72 summary: Vanadium glasses have a complex structure because vanadium ions can exist in four-, five- and six-coordinated states (tetrahedron, square pyramid, trigonal bipyramid, and octahedron Nmr quadrupole interactions in vanadium phosphate glass. keywords: content; cycles; fig; glasses; mol; number; p2o5; spectra; v2o5; vanadium; vibrations cache: chimtech-5103.pdf plain text: chimtech-5103.txt item: #155 of 303 id: chimtech-5120 author: Chuprynina, D. A.; Lupanova, I. A.; Konshin, V. V.; Konshina, D. N. title: Silica gel functionalized with imidazolium group via click chemistry – new stationary phase for ion chromatography date: 2021-12-11 words: 3939 flesch: 57 summary: Chromatographic properties of the column packed with modified silica gel were studied using a modular high- performance liquid chromatograph from Shimadzu (Kyoto, Japan) including a CTO-20A column thermostat, an LC-20AD sp mobile phase feed module, and CDD-10A vp. conductometric detector. The thermal stabilities of modified silica gel samples were studied on an STA 409 PC Luxx synchronous thermal analyzer (Netzsch, Gemrany) in a temperature range from 30 to 1000 °C at a heating rate of 10 оC/min in the air at- mosphere in Al2O3 ceramic crucibles. keywords: anion; chromatography; exchange; gel; ion; liquid; phase; range; separation; silica; surface cache: chimtech-5120.pdf plain text: chimtech-5120.txt item: #156 of 303 id: chimtech-5124 author: Khizrieva, S. S.; Borisenko, S. N.; Maksimenko, E. V.; Borisenko, N. I. title: Evaluation of different extraction techniques for the assay of anti - acetylcholinesterase activity of olive leaves (Olea europaea) date: 2021-11-09 words: 3178 flesch: 59 summary: Therefore, the purpose of the present work is the eval- uation of different extraction techniques for the assay of anti-AChE activity, and the determination of total amount of phenolic components of OL extracts obtained using both subcritical water extraction (SbWE) and traditional sol- vent extraction (TSE). The collected data on the anti - acetylcholinesterase activity of olive leaves clearly demon- strate the prospects for use of OL extracts in the development of novel pharmaceutical substances and nutraceuticals for the preven- tion and/or the treatment of Alzheimer's disease as well as some other neurodegenerative diseases. keywords: ache; activity; extracts; ic50; olive; water cache: chimtech-5124.pdf plain text: chimtech-5124.txt item: #157 of 303 id: chimtech-5133 author: Klyndyuk, A. I.; Zhuravleva, Ya. Yu.; Gundilovich, N. N. title: Crystal structure, thermal and electrotransport properties of NdBa1–xSrxFeCo0.5Cu0.5O5+δ (0.02 ≤ x ≤ 0.20) solid solutions date: 2021-07-08 words: 3162 flesch: 58 summary: Xue J, Shen Y, He T. Performance of double-perovskite YBa0.5Sr0.5Co2O5+ as cathode material for intermediate- temperature solid oxide fuel cells. Zhang S-L, Chen K, Zhang A-P, Li C-X, Li C-Y. Effect of Fe doping on the performance of suspension plasma-sprayed PrBa0.5Sr0.5Co2–xFexO5+ cathodes for intermediate- temperature solid oxide fuel cells. keywords: materials; ndba1; oxide; samples; solutions; structure; temperature; xsrxfeco0.5cu0.5o5+δ cache: chimtech-5133.pdf plain text: chimtech-5133.txt item: #158 of 303 id: chimtech-5186 author: Ivanova, K. Yu.; Kuzmin, M. V.; Rogozhina, L. G.; Patianova, A. O.; Semenov, V. L.; Alexandrov, R. I. title: Synthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy date: 2021-09-13 words: 2893 flesch: 55 summary: Copper wire coated with various alloys, which is currently one of the main materials in electrical engineering, is widely used as conductive electrodes [2]. As a rule, wire coating is performed by electroplating or hot dipping [5]. keywords: alloy; coating; copper; electrodeposition; indium; jhh; silylureas; tin; wire cache: chimtech-5186.pdf plain text: chimtech-5186.txt item: #159 of 303 id: chimtech-5216 author: Lyutina, A. S.; Kataev, A. A.; Rudenko, A. V.; Tkacheva, O. Yu. title: Effect of Al2O3 and CaF2 additives on the viscosity of conventional cryolite melts date: 2021-09-21 words: 4044 flesch: 61 summary: Thus, despite the importance of viscosity for the tech- nological process, the viscosity of cryolite melts of conven- tional electrolytes has not been properly studied yet. The regression equation for estimating viscosity of cryolite melts on several independent parameters, ob- tained by approximating the experimental data, satisfacto- rily describes (within 1.5%) the viscosity of conventional electrolytes for aluminum production. keywords: al2o3; caf2; cryolite; melts; temperature; viscosity; wt% cache: chimtech-5216.pdf plain text: chimtech-5216.txt item: #160 of 303 id: chimtech-5225 author: Kutyavina, A. D.; Maskaeva, L. N.; Voronin, V. I.; Anokhina, I. A.; Markov, V. F. title: Corrigendum to Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath date: 2021-07-04 words: 344 flesch: 34 summary: 8(2), № 20218212 eISSN 2411-1414; chimicatechnoacta.ru DOI: 10.15826/chimtech.2021.8.2.12 1 of 1 Corrigendum to Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath A.D. Kutyavina a,* , L.N. Maskaeva a,b , V.I. Voronin c , I.А. Anokhina d , V.F. Markov a,b a: Ural Federal University named after the first President of Russia B.N. Yeltsin, 620002, 19 Mira st., Yekaterinburg, Russia b: Ural Institute of the State Fire Service of the EMERCOM of Russia, 620062, 22 Mira st., Yekaterinburg, Russia c: M.N. Miheev Institute of Metal Physics, Ural Branch of Russian Academy of Sciences, 620108, 18 S. Kovalevskaya st., Yekaterinburg, Russia d: Institute of High Temperature Electrochemistry, Ural Branch of the Russian Academy of Sciences, 620990, 20 Akademicheskaya st., Yekaterinburg, Russia * Corrigendum to Morphological and structural features of the CdxPb1−xS films obtained by CBD from ethylenediamine-citrate bath Chimica Techno Acta CORRIGENDUM published by Ural Federal University 2021, vol. keywords: russia; ural cache: chimtech-5225.pdf plain text: chimtech-5225.txt item: #161 of 303 id: chimtech-5226 author: Subanakov, Alexey K.; Kovtunets, Evgeniy V.; Bazarov, Bair G.; Bazarova, Jibzema G. title: Synthesis, crystal structure, and thermal stability of double borate Na3ErB2O6 date: 2021-10-20 words: 2942 flesch: 68 summary: 4.163 Rp, % 2.571 Rwp, % 3.534 Rexp, % 1.572 Bragg R-factor, % 1.864 χ2 2.249 Table 2 Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters of Na3ErB2O6 structure x y z Biso*/Beq Er 0.0970(3) 0.1261(1) 0.3287(1) 0.9(2) Na1 0.380(2) 0.8039(8) 0.3841(7) 1.1(3) Na2 0.058(2) 0.2963(8) 0.0802(8) 0.9(3) Na3 0.331(2) 0.9488(8) 0.1134(7) 3.1(3) B1 0.139(3) 0.4379(7) 0.3695(8) 1.0(6) B2 0.351(1) 0.5864(8) 0.1209(5) 1.0(6) O1 0.255(2) 0.334(1) 0.4714(9) 0.5(2) O2 0.049(2) 0.373(2) 0.2513(7) 0.5(2) O3 0.137(2) 0.600(1) 0.3911(9) 0.5(2) O4 0.226(1) 0.674(1) 0.1611(5) 0.5(2) O5 0.251(2) 0.505(1) 0.0086(7) 0.5(2) O6 0.413(1) 0.080(1) 0.3075(5) 0.5(2) Chimica Techno Acta 2021, vol. Synthesis, crystal structure, and thermal stability of double borate Na3ErB2O6 Chimica Techno Acta ARTICLE published by Ural Federal University 2021, vol. keywords: borate; crystal; doi:10.1016; fig; na3erb2o6; structure cache: chimtech-5226.pdf plain text: chimtech-5226.txt item: #162 of 303 id: chimtech-5232 author: Naveen Kumar, B. V.; Samuel, T.; Bevara, Samatha; Ramachandra Rao, K.; Chirauri, Satya Kamal title: Bright blue emissions on UV-excitation of LaBO3 (B=In, Ga, Al) perovskite structured phosphors for commercial solid-state lighting applications date: 2022-03-11 words: 3991 flesch: 67 summary: A few research groups have also reported that Bi3+ doped LaInO3 and LaGaO3 are efficient blue-emitting luminescent materials. XRD studies XRD patterns of undoped and selected Bi3+ doped LaInO3, LaGaO3 and LaAlO3 samples calcined at 1000 °C are shown in Fig. 1 (a–c). keywords: at.%; bi3; blue; emission; fig; laalo3; lagao3; laino3; samples cache: chimtech-5232.pdf plain text: chimtech-5232.txt item: #163 of 303 id: chimtech-5278 author: Bachinin, Semyon; Gilemkhanova, Venera; Timofeeva, Maria; Kenzhebayeva, Yuliya; Yankin, Andrei; Milichko, Valentin A. title: Metal-Organic Frameworks for Metal-Ion Batteries: Towards Scalability date: 2021-08-27 words: 6112 flesch: 55 summary: Metal–organic frameworks in modern physics: Du J, Li F, Sun L. Metal–organic frameworks and their deriva- tives as electrocatalysts for the oxygen evolution reaction. keywords: anode; batteries; cathode; chemical; chemistry; cvd; deposition; doi:10.1016; energy; fig; films; frameworks; ion; journal; lithium; materials; metal; mofs; synthesis; wang; zhang cache: chimtech-5278.pdf plain text: chimtech-5278.txt item: #164 of 303 id: chimtech-5289 author: Eltyshev, Alexander K.; Belskaya, Nataliya P. title: Sensitivity of the phenoxy derivatives of 2,4-dihydro-5H-[1,2,3]triazolo[4,5-d]pyrimidin-5-ones to acidic and basic stimuli date: 2021-08-17 words: 2655 flesch: 61 summary: 3 Absorption (a) and emission (b) of DTP 2c solution in DMSO with addition of different eq. of NaOH. In this case new maximum was located at 395 nm when 25 eq. of NaOH solution were added, and further NaOH addition led to increasing of this Fig. keywords: absorption; acids; bases; dtps; emission; fluorescence; properties; solution cache: chimtech-5289.pdf plain text: chimtech-5289.txt item: #165 of 303 id: chimtech-5317 author: Sukanya, S. H.; Venkatesh, Talavara; Rao, S.J. Aditya; Shivakumara, N.; Joy, Muthipeedika Nibin title: Facile synthesis of some 5-(3-substituted-thiophene)-pyrimidine derivatives and their pharmacological and computational studies date: 2021-10-15 words: 8687 flesch: 63 summary: IR spec- trum of compound 3a showed that the absorption band in the region 3373 cm–1 is attributed to the amide stretching vibration, and the absorption band at 1654 cm–1 corre- sponds to stretching vibration of the carbonyl group (C=O). 9054 corresponds to the molecular weight of compound 3a (Supporting information: keywords: activity; anticancer; binding; cell; chem; compounds; derivatives; dna; doi:10.1016; drug; n h; n n; n o; reaction; studies; study; synthesis; table cache: chimtech-5317.pdf plain text: chimtech-5317.txt item: #166 of 303 id: chimtech-5353 author: Tikhanova, Sofia M.; Lebedev, Lev A.; Kirillova, Svetlana A.; Tomkovich, Maria V.; Popkov, Vadim I. title: Synthesis, structure, and visible-light-driven activity of o-YbFeO3/h-YbFeO3/CeO2 photocatalysts date: 2021-12-02 words: 6416 flesch: 53 summary: It is worth noting that the size of o-YbFeO3 nanoparticles regularly decreases with the addition of cerium, which is also confirmed by the XRD results (Fig. 4c). Thus, in the case of pure YbFeO3 without added cerium (Fig. 6a), the distinguishable nanoparticles are weakly agglomerated, have a spherical morphology, and are aggregated into foam-like structures of micron sizes. keywords: ceo2; cerium; fenton; fig; light; nanocomposites; orthoferrite; photocatalytic; process; samples; solution; surface; ybfeo3; ytterbium cache: chimtech-5353.pdf plain text: chimtech-5353.txt item: #167 of 303 id: chimtech-5394 author: Lugovitskaya, T. N.; Shipovskaya, A. B.; Shipenok, X. M. title: Kinetic instability of a chitosan – aspartic acid – water system as a method for obtaining nano- and microparticles date: 2021-11-26 words: 5829 flesch: 58 summary: CTS solutions in HCl have a weak film-forming abil- ity and give a loose structure with a pore diameter of more than 10 mm when dried on an inert surface. CTS solutions are also char- acterized by instability of viscosity properties over time, which is usually explained by the destruction of macro- molecules as a result of acid hydrolysis of glycosidic bonds [5–7]. keywords: acid; aspa; chitosan; concentration; conductivity; cts; dielectric; increase; nanoparticles; phase; polymer; properties; solutions; system; æsp; н2о; сcts cache: chimtech-5394.pdf plain text: chimtech-5394.txt item: #168 of 303 id: chimtech-5430 author: Mamand, Dyari Mustafa; Awla, Awat Hamad; Kak Anwer, Twana Mohammed; Qadr, Hiwa Mohammad title: Quantum chemical study of heterocyclic organic compounds on the corrosion inhibition date: 2022-04-17 words: 7093 flesch: 62 summary: The ratios of corrosion inhibition of materials are different, but organic compounds have high efficiency in aqueous corrosion inhibition for various alloys and metals. Using corrosion inhibitors is one of the best and most effective ways to protect the surface of ma- terials from corrosion in acid environments keywords: basis; calculations; chemical; compounds; corrosion; derivatives; energy; inhibition; molecular; molecule; phase; quantum; thiadiazole cache: chimtech-5430.pdf plain text: chimtech-5430.txt item: #169 of 303 id: chimtech-5433 author: Gorbunova, I. A.; Shipilovskikh, D. A.; Shipilovskikh, S. A. title: Deoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide date: 2021-12-03 words: 2373 flesch: 64 summary: Reaction progress was monitored by GC/MS analysis and thin layer chromatography (TLC) on aluminum backed plates with Merck Kiesel 60 F254 silica gel. Nickel(II)-carbene intermedi- ates in reactions of geminal dihaloalkanes with nickel(0) re- agents and the corresponding carbene capture as the phos- phonium ylide. keywords: chem; equiv; mmol; nmr; ppm cache: chimtech-5433.pdf plain text: chimtech-5433.txt item: #170 of 303 id: chimtech-5434 author: Siutkina, Alena I.; Makhmudov, Ramiz R.; Shipilovskikh, Daria A. title: Synthesis and analgesic activity evaluation of derivatives of 2-[(1,4-dioxo-1-amino-4-arylbutyl-2-en-2-yl)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylic acid date: 2021-11-22 words: 3328 flesch: 61 summary: In this paper, synthesis and analgesic activity of new 2-[(1,4-dioxo-1-amino-4-arylbutyl-2-en-2-yl)amino]- 4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylic acid derivatives is discussed. Evaluation of analgesic activity was carried out in the Perm State National Research University, the Research Laboratory of Biologically Active Substances. keywords: acids; activity; analgesic; chem; derivatives; harom; reaction; russ; synthesis cache: chimtech-5434.pdf plain text: chimtech-5434.txt item: #171 of 303 id: chimtech-5436 author: Suprunchuk, Victoria E. title: Efficiency of ultrasonic treatment of polysaccharide from brown algae date: 2021-12-23 words: 2490 flesch: 55 summary: The work revealed that cavitation activity changes un- evenly. However, its effectiveness depends on several fac- tors, including cavitation activity in the treatment medium. keywords: activity; cavitation; fucoidan; intensity; medium; treatment; ultrasonic; ultrasound cache: chimtech-5436.pdf plain text: chimtech-5436.txt item: #172 of 303 id: chimtech-5437 author: Beya, C. L.; Kanwugu, O. N.; Ivantsova, M. N. title: Modern biotechnological methods in wastewater treatment: a review date: 2022-04-16 words: 3707 flesch: 43 summary: This method of wastewater treatment uses flocculation – coagulation technique, which consists of mixing coagulant matters with water to collect, in solid clusters, the materials in suspension by gravity. This paper describes and assesses some modern biotechnology methods used in wastewater treatment. keywords: bed; bioadsorption; biofilm; biological; biotechnology; m.n.i; processes; reactor; review; systems; treatment; wastewater; wastewater treatment cache: chimtech-5437.pdf plain text: chimtech-5437.txt item: #173 of 303 id: chimtech-5438 author: Ramirez, L. I.; Kanwugu, O. N.; Ivantsova, M. N. title: Impact of herbal supplements nowadays: an overview date: 2022-04-22 words: 5402 flesch: 50 summary: Although herbal products are recognized by the WHO as an essential component of the healthcare system, there have been increasing concerns regarding their quality and safety. Generally, herbal products are not strictly regulated as they are largely categorized under dietary supplements, thus escaping the rigorous scrutiny meted out to pharmaceuticals. keywords: countries; doi:10.1016; drug; effects; health; herbal; interactions; l.i.r; m.n.i; market; medicine; o.n.k; products; review; safety; supplements; use cache: chimtech-5438.pdf plain text: chimtech-5438.txt item: #174 of 303 id: chimtech-5441 author: Kozlova, M. M.; Markov, V. F.; Maskaeva, L. N. title: Oxidative destruction of anionite AV-17×8 using the Fenton reaction date: 2021-11-26 words: 3328 flesch: 54 summary: [5–14] are aimed at choosing the optimal conditions for the oxidative destruction of ion exchange resins of some foreign brands. Bio- technological destruction of ion exchange resins. keywords: anionite; av-17×8; exchange; fenton; mol; oxidation; process; temperature cache: chimtech-5441.pdf plain text: chimtech-5441.txt item: #175 of 303 id: chimtech-5445 author: Sharapov, A. D.; Fatykhov, R. F.; Khalymbadzha, I. A.; Chupakhin, O. N. title: Synthesis of 4-hydroxy and 6-hydroxyindoles: a renaissance of the Bischler reaction date: 2022-04-15 words: 2058 flesch: 61 summary: Hydroxyindoles are particularly convenient to prepare by the Bischler reaction, since in some cases it is not necessary to use protecting groups in order to block the phenolic hydroxyl. In addition, some aspects of the regiochemistry of the formation of hydroxyindoles from meta-aminophenol and benzoin have remained unclear until now. keywords: hydroxyindoles; reaction cache: chimtech-5445.pdf plain text: chimtech-5445.txt item: #176 of 303 id: chimtech-5446 author: Yakovishin, L. A.; Ratnikov, V. D.; Bazhan, P. I.; Zaitsev, G. P. title: New molecular complex of ammonium glycyrrhizate with rutin date: 2022-01-11 words: 2031 flesch: 64 summary: ACW = 161.2 nM and ACL = 157.3 nM (in terms of trolox for 49.5 mg/L solutions of Rut–GC complex in 70% aque- ous ethanol (v/v)). However, molecular complexes of Rut with GC have not been described. keywords: complex; rut cache: chimtech-5446.pdf plain text: chimtech-5446.txt item: #177 of 303 id: chimtech-5447 author: Yakovishin, L. A.; Tkachenko, E. V. title: Composite materials based on dental acrylic plastic and chitosan date: 2021-12-17 words: 2210 flesch: 67 summary: , № 20218413 LETTER 3 of 3 The IR spectra of chitosan and PMMA composites show low-frequency shifts of the absorption band of stretching vibrations of О–Н and N–H bonds in chitosan from 3310 cm–1 to 3297 cm–1 (for composite 1), to 3247 cm–1 (for composite 2) and to 3239 cm–1 (for composite 3; Fig. 1). For example, composite materials are widely used in modern dentistry keywords: composite cache: chimtech-5447.pdf plain text: chimtech-5447.txt item: #178 of 303 id: chimtech-5449 author: Aleksandrova, V. V.; Kuzmin, M. V.; Patianova, A. O.; Semenov, V. L.; Alexandrov, R. I. title: Determination of optimal parameters technological process of polling of copper wire with alloy POS-61 date: 2022-06-21 words: 1715 flesch: 56 summary: Nominal diameter of copper wire, mm Melt temperature, °С Linear speed, m/min Diamond die diameter, mm 0.12−0.003 +0.005 0.15−0.003 +0.005 0.20−0.003 +0.005 0.30−0.005 +0.007 185 215 245 110 125 140 0.187 0.238 0.385 Table 3 shows an example, which is one of the varia- tions in the manufacturing modes of round copper wire with a POS-61 coating, used as a braid in cable products for various purposes. Keywords technological process alloy tin lead tinning round copper wire Received: 03.11.21 Revised: 14.06.22 Accepted: 16.06.22 Available online: 21.06.22 Key findings ● The round copper wire coated with POS 61 alloy is used as shielding elements in cable and wire products. keywords: alloy; copper; k.m.v; pos-61; round; wire cache: chimtech-5449.pdf plain text: chimtech-5449.txt item: #179 of 303 id: chimtech-5453 author: Titov, Anatolii G.; Rusinova, Zalina R.; Kalimullina, Ekaterina A.; Vorobev, Anatoliy M. title: Drop motion during mass transfer accompanied by interphase convection date: 2022-06-22 words: 1984 flesch: 57 summary: Drop motion during mass transfer accompanied by interphase Chimica Techno Acta LETTER published by Ural Federal University 2022, vol. No. 202292S9 eISSN 2411-1414; chimicatechnoacta.ru DOI: 10.15826/chimtech.2022.9.2.S9 1 of 5 Drop motion during mass transfer accompanied by interphase convection Anatolii G. Titov a* , Zalina R. Rusinova a, Ekaterina A. Kalimullina a, Anatoliy M. Vorobev b a: Institute of Chemical Engineering, Ural Federal University, Ekaterinburg 620009, Russia b: Engineering Department, University of Southampton, University Road, Southampton SO17 1BJ, Unit- ed Kingdom * Corresponding author: a.g.titov@urfu.ru This paper belongs to the MOSM2021 Special Issue. keywords: acid; concentration; droplets; mass; mol; transfer cache: chimtech-5453.pdf plain text: chimtech-5453.txt item: #180 of 303 id: chimtech-5462 author: Bazarov, B. G.; Dorzhieva, S. G.; Shendrik, R. Y.; Tushinova, Y. L.; Bazarova, Ts. T.; Sofich, D. O.; Chimitova, O. D.; Bazarova, J. G. title: Synthesis and luminescent properties of new tungstates Ln2Zr(WO4)5 (Ln = Tb, Dy) date: 2022-05-03 words: 3029 flesch: 60 summary: This work was devoted to synthesis and luminescent characteristics of double tung- states Ln2Zr(WO4)5 (Ln = Tb, Dy) obtained by a solid- phase synthesis and sol-gel methods. Also, double tungstates Ln2Zr(WO4)5 (Ln = Tb, Dy) were synthesized by the Pechini method, where ethylene glycol is completely replaced by water, there by reducing the amount of organic compounds. keywords: bazarova; double; gel; ln2zr(wo4)5; luminescence; molybdate; synthesis; tungstates cache: chimtech-5462.pdf plain text: chimtech-5462.txt item: #181 of 303 id: chimtech-5463 author: Illarionova, M. S.; Ivanova, K. Y.; Kuzmin, M. V.; Patianova, A. O.; Semenov, V. L. title: Development of technology for obtaining electrodes based on copper wire using in the manufacture of solar modules date: 2022-03-31 words: 2401 flesch: 56 summary: 2. Table 1 Technological mode of electrochemical degreasing Brand and nominal diame- ter of copper wire, mm Degreasing solution Тemperature, °С Electric current, А Speed, m/min Wire diameter after degreasing, mm ММ 0.25±0.001 TG-19 38 20 50 0.25±0.001 Table 2 Technological mode of wire coating with POIN-52 solder Mode Copper wire diameter according to tech- nical specifications Copper wire brand and ac- Development of technology for obtaining electrodes based on copper wire using in the manufacture of solar modules Chimica Techno Acta LETTER published by Ural Federal University 2022, vol. keywords: copper; modules; parameters; russian; table; tests; wire cache: chimtech-5463.pdf plain text: chimtech-5463.txt item: #182 of 303 id: chimtech-5477 author: Azev, Y. A.; Koptyaeva, O. S.; Mkrtchan, A. A.; Pospelova, T. A. title: Features of -C-C- coupling of quinoxaline-2-one with ethyl acetoacetate under acid catalysis date: 2022-01-14 words: 1900 flesch: 63 summary: The precipi- tate of the mixture of reaction products was filtered off. 9(1), No. 20229103 eISSN 2411-1414; chimicatechnoacta.ru DOI: 10.15826/chimtech.2022.9.1.03 1 of 3 Features of –C–C– coupling of quinoxaline-2-one with ethyl acetoacetate under acid catalysis Yu.A. Azev *, O.S. Koptyaeva, A.A. Mkrtchyan, T.A. Pospelova Ural Federal University, 620002 Mira st., 19, Ekaterinburg, Russia * Corresponding author: azural@yandex.ru This short communication (letter) belongs to the Regular Issue. keywords: compound; ethyl; formation; quinoxaline-2; reaction cache: chimtech-5477.pdf plain text: chimtech-5477.txt item: #183 of 303 id: chimtech-5478 author: Sharapov, A. D.; Fatykhov, R. F.; Khalymbadzha, I. A.; Potapova, A. P.; Slepukhin, P. A.; Chupakhin, O. N. title: Unusual nicotinoylation of 4-phenyl-5,7-dihydroxycoumarin date: 2022-01-26 words: 1978 flesch: 65 summary: The structure of the nicotinoyl derivative was proved by X-ray diffraction analysis. One may assume that the selectivity of this re- action is associated with non-covalent interactions in the tran- sition state, such as π-π stacking between the pyridyl ring of nicotinoyl derivatives and the phenyl ring of coumarin. Fig. keywords: 5,7; nicotinoylation; synthesis cache: chimtech-5478.pdf plain text: chimtech-5478.txt item: #184 of 303 id: chimtech-5479 author: Tusseyev, Turgara T.; Danlybaeva, Aktolkyn K.; Raimkul, Saltanat S.; Kiykabaeva, Aizhan A.; Doszhanov, Ospan M. title: Radiation-stimulated adsorption processes on the surface of beryllium oxide date: 2022-01-28 words: 3571 flesch: 54 summary: 2 Dose dependence of radiation adsorption of gases on beryllium oxide: 1 – hydrogen adsorption, 2 – oxygen adsorption (P = 113 Pa) Fig. 3 presents a graphical representation of the kinet- ics of radiation adsorption of O2 on the BeO surface. 3 Kinetics of radiation adsorption of O2 by BeO: 1 – Ро=110 –1, 2 – 1.210–1, 3 – 0.510–1, 4 – 8.510–1 mmHg Chimica Techno Acta 2022, vol. keywords: adsorption; beo; beryllium; centers; fig; oxide; oxygen; radiation; samples; surface; temperature cache: chimtech-5479.pdf plain text: chimtech-5479.txt item: #185 of 303 id: chimtech-5484 author: Tretiakov, Andrey V.; Yaroshuk, Sergey B.; Markov, Vyacheslav F.; Budnik, Lyudmila G. title: Influence of preparative form on the target efficiency and toxicity of the solid insecticide based on pyrethroid and neonicatinoid date: 2022-01-13 words: 5095 flesch: 54 summary: Р 4.2.2643-10, the criteria for evaluating insecticidal agents are: 1. Acute effect on flightless insects: death in 24 hours – not less than 100%; 2. Maksoud HA, Mahfouz MK, Soliman MI, et al. Harmful effects of pyrethroid ester insecticide on the male reproductive sys- tem mainly through affecting testicular function and inflam- matory markers. keywords: action; acute; agent; animals; days; effect; hours; impact; insects; pyrethroid; skin; test; toxicity cache: chimtech-5484.pdf plain text: chimtech-5484.txt item: #186 of 303 id: chimtech-5495 author: Anjan Kumar, G. C.; Bodke, Yadav D.; Manjunatha, B.; Satyanarayan, N. D.; Nippu, B. N.; Joy, Muthipeedika Nibin title: Novel synthesis of 3-(Phenyl) (ethylamino) methyl)-4-hydroxy-2H-chromen-2-one derivatives using biogenic ZnO nanoparticles and their applications date: 2022-01-21 words: 9520 flesch: 66 summary: Chemistry The structure of synthesized compounds was characterized by using different spectroscopic techniques such as UV-Vis, FT-IR, 1H NMR, 13C NMR and HRMS. 6 Electronic spectra of synthesized compounds in different solvents Chimica Techno Acta 2022, vol. keywords: = o; activity; catalyst; chem; compounds; corrosion; coumarin; derivatives; dmso; fig; mol; nano; nmr; ppm; synthesis; table; zno cache: chimtech-5495.pdf plain text: chimtech-5495.txt item: #187 of 303 id: chimtech-5531 author: Tsvetkova, I. V.; Golovanov, A. A.; Kondrateva, A. A.; Chirkunova, N. V. title: Obtaining cyclopentanone in the presence of metal oxides date: 2021-12-15 words: 1415 flesch: 58 summary: Calcium adipate pyrolysis can proceed in two direc- tions – with the formation of cyclopentanone and cyclo- pentene (Fig. 1). The thermal stabil- ity study of calcium adipate using a Shimadzu DTG- 60/60H derivatograph was carried out. keywords: acid; calcium; cyclopentanone; fig; presence cache: chimtech-5531.pdf plain text: chimtech-5531.txt item: #188 of 303 id: chimtech-5540 author: Spiridonova, Tatyana S.; Savina, Aleksandra A.; Kovtunets, Evgeniy V.; Khaikina, Elena G. title: New triple molybdate and tungstate Na5Rb7Sc2(XO4)9 (X = Mo, W) date: 2021-12-16 words: 4746 flesch: 65 summary: Sc2(ХO4)3 (Х = Mo, W) was obtained from Sc2O3 and ХO3 (Х = Mo, 773–1023 K, 80 h; Х = W, 773–1123 K, 80 h). Polycrystalline Na5Rb7Sc2(ХO4)9 (Х = Mo, W) were synthe- sized by annealing the stoichiometric mixtures of Na2ХO4, Rb2ХO4 and Sc2(ХO4)3 at 773–823 K for 80 h (Х = Mo), 100 h (Х = W). keywords: crystal; expansion; na5rb7sc2(wo4)9; structure; temperature; triple cache: chimtech-5540.pdf plain text: chimtech-5540.txt item: #189 of 303 id: chimtech-5558 author: Zhestkij, N. A.; Gunina, E. V.; Fisenko, S. P.; Rubtsov, A. E.; Shipilovskikh, D. A.; Milichko, V. A.; Shipilovskikh, S. A. title: Synthesis of highly stable luminescent molecular crystals based on (E)-2-((3-(ethoxycarbonyl)-5-methyl-4-phenylthiophen-2-yl)amino)-4-oxo-4-(p-tolyl)but-2-enoic acid date: 2021-12-15 words: 2975 flesch: 64 summary: Generally, organic crystals (OCs) are based on organic molecules packed in a specific order, where weak intermolecular interactions maintain the integrity of the crystal structure. This organic compound was then utilized to create new organic molecular crystals in the form of single microcrystals and large scale thin films demonstrating highly efficient and stable photolumi- nescence at ambient conditions. keywords: acid; crystals; mcs; organic; synthesis; wang cache: chimtech-5558.pdf plain text: chimtech-5558.txt item: #190 of 303 id: chimtech-5568 author: Nikonov, Igor L.; Khalymbadzha, Igor A.; Sadieva, Leila К.; Savchuk, Maria I.; Starnovskaya, Ekaterina S.; Kopchuk, Dmitry S.; Коvalev, Igor S.; Kim, Grigory А.; Chupakhin, Oleg N. title: Benzo[de]naphtho[1,8-gh]quinolines: synthesis, photophysical studies and nitro explosives detection date: 2021-12-23 words: 3262 flesch: 67 summary: J Chem Soc, Perkin Trans. J Chem Phys. 1980;72:650–4. keywords: compounds; fluorescence cache: chimtech-5568.pdf plain text: chimtech-5568.txt item: #191 of 303 id: chimtech-5569 author: Nikonov, Igor L.; Sadieva, Leila K.; Savchuk, Мaria I.; Starnovskaya, Еkaterina S.; Kopchuk, Dmitry S.; Kovalev, Igor S.; Кim, Grigory А.; Chupakhin, Oleg N. title: New naphtho[1,8-ef]perimidines: synthesis, fluorescence studies and application for detection of nitroanalytes date: 2021-12-24 words: 3091 flesch: 62 summary: J Chem Phys. J Chem Phys. keywords: chem; chemosensors; fluorescence; nitroanalytes; values cache: chimtech-5569.pdf plain text: chimtech-5569.txt item: #192 of 303 id: chimtech-5571 author: Krinochkin, Alexey P.; Savchuk, Мaria I.; Starnovskaya, Еkaterina S.; Nikonov, Igor L.; Baklykov, Artem V.; Kudryashova, Ekaterina A.; Rybakova, Svetlana S.; Ladin, Evgeny D.; Kopchuk, Dmitry S.; Wang, Zhuo; Chupakhin, Oleg N. title: New 2,5-bis(2-ethylhexyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-2,2’-bipyridine-based co-polymer, synthesis, photophysical properties and response to metal cations date: 2021-12-24 words: 2094 flesch: 60 summary: Wang T, Zhang N, Baic W, Bao Y. Fluorescent chemosensors based on conjugated polymers with N-heterocyclic moieties: two decades of progress. 8(4), № 20218417 eISSN 2411-1414; chimicatechnoacta.ru DOI: 10.15826/chimtech.2021.8.4.17 1 of 4 New 2,5-bis(2-ethylhexyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)- dione-2,2’-bipyridine-based co-polymer, synthesis, photophysical properties and response to metal cations Alexey P. Krinochkin ab*, Мaria I. Savchuk ab, Еkaterina S. Starnovskaya аb, Igor L. Nikonov ab , Artem V. Baklykov ab, Ekaterina A. Kudryashova a, Svetlana S. Rybakova a, Evgeny D. Ladin a, Dmitry S. Kopchuk ab , Zhuo Wang c,Оleg N. Chupakhin ab a: Ural Federal University, 620002 Mira st., 19, Yekaterinburg, Russia b: I.Ya. keywords: absorption; cations; chem; doi:10.1016; monomer; polymer; properties; synthesis cache: chimtech-5571.pdf plain text: chimtech-5571.txt item: #193 of 303 id: chimtech-5672 author: Zuev, Mikhail G.; Il'ves, Vladislav G.; Sokovnin, Sergei Yu. title: Nanoluminofors based on siliсates and germanates of rare earth elements for visualization of biotissues date: 2022-07-19 words: 2707 flesch: 56 summary: Firstly, they should have a UCPL and, secondly, they should have a sufficiently high X-ray attenuation covering the entire range of X-ray energies (10-100 keV) used in medical X-ray diagnostics. X-ray attenuation mass coefficients Let us consider the dependencies of mass attenuation coef- ficients (μ) on X-ray energy for the samples Sr2Y6.8YbEr0.2Si6O26 and Sr2La7.75Er0.075Yb0.075Ge6O26 (Fig- ures 3, 4). keywords: energy; figure; imaging; nanoparticles; nir; radiation; ray cache: chimtech-5672.pdf plain text: chimtech-5672.txt item: #194 of 303 id: chimtech-5677 author: Bazunova, Marina V.; Lazdin, Roman Yu.; Elinson, Mariya R.; Sharafutdinova, Lucia A.; Mustakimov, Robert A.; Kulish, Elena I. title: On the possibility of obtaining the elastic and biocompatible film materials based on chitosan and N-succinyl chitosan date: 2022-03-16 words: 4923 flesch: 57 summary: At the same time, it is known that the structure and, consequently, both physico-chemical and physico-mechanical properties (the plasticity being among them) of ChT films are defined by the way of their forming and modification 1 Phase contrast AFS images of the surface of ChT films obtained from initial solutions in the absence of glycerol (a) and in the presence of glycerol with a concentration of 2 mol/l (b) Table 2 keywords: alcohols; chitosan; cht; concentration; films; glycerol; glycol; materials; mol; presence; properties; scht; solutions cache: chimtech-5677.pdf plain text: chimtech-5677.txt item: #195 of 303 id: chimtech-5713 author: Shipilovskikh, D. A.; Konkova, M. F.; Nikonov, I. P.; Gladysheva, M. M.; Shipilovskikh, S. A. title: A method of mild deoxydichlorination of aldehydes catalyzed by Triphenylphosphine oxide date: 2022-03-25 words: 4379 flesch: 58 summary: J Org Chem. J Org Chem. keywords: aldehydes; catalytic; chem; dichloride; equiv; method; mmol; mol.%; oxide; phthaloyl; ppm; reaction; synthesis; triphenylphosphine cache: chimtech-5713.pdf plain text: chimtech-5713.txt item: #196 of 303 id: chimtech-5717 author: Shapkin, Nikolai Р.; Khalchenko, Irina G.; Kim, Kvan H.; Papynov, Evgeniy K.; Fedorets, Alexander N.; Maslova, Natalia V.; Balanov, Michael I. title: Synthesis of polycalciumphenylsiloxane and composites based on the skeleton of a sea urchin with the resulting polymer date: 2022-06-14 words: 3701 flesch: 57 summary: 202292S6 ARTICLE 3 of 7 Gel chromatography of soluble fractions 1.1 and 2.1 was carried out; the results were identical. In the IR spectra of soluble fractions of syntheses 1 and 2, absorption bands of medium intensity are observed at 3627 cm–1, corresponding to stretching vibrations of the O – H bond at the silicon atom; a weak band at 3402 cm–1 corresponds to the vibrations of the O – H bond in coordi- nated molecules water. keywords: acetylacetonate; calcium; cm–1; composite; figure; fraction; sea; skeleton; synthesis; vibrations cache: chimtech-5717.pdf plain text: chimtech-5717.txt item: #197 of 303 id: chimtech-5734 author: Chiriapkin, Alexey S.; Kodonidi, Ivan P.; Pozdnyakov, Dmitry I.; Glushko, Alexander A. title: Synthesis, in vitro and docking studies of 2-substituted 5,6,7,8-tetrahydrobenzo[4,5]thieno[2,3-d]pyrimidine-4(3H)-one derivatives as agents for the treatment of Alzheimer's disease date: 2022-04-26 words: 6652 flesch: 60 summary: Thus, the search for new compounds with the above properties is a cutting-edge area of medicinal chemistry and neuropharmacology 1H NMR spectrum (400 MHz, DMSO-d6), δ, ppm: 1.85–1.71 (m, 4H, CH2), 2.75 (q, J = 3.9, 2.3 Hz, 2H, CH2), 2.91 (t, J = 5.6 Hz, 2H, CH2), 7.53 (d, J = 3.7 Hz, 1H. ArH), 7.60 (d, J = 3.8 Hz, 1H, ArH), 8.35–8.25 (m, 4H, ArH), 12.84 (s, 1H, NH). keywords: acetylcholinesterase; ache; activity; alzheimer; amyloid; arh; ch2; chem; compounds; derivatives; disease; docking; donepezil; phe; spectrum; synthesis cache: chimtech-5734.pdf plain text: chimtech-5734.txt item: #198 of 303 id: chimtech-5812 author: Kopchuk, Dmitry S.; Krinochkin, Alexey P.; Valieva, Мaria I.; Starnovskaya, Еkaterina S.; Shtaitz, Yaroslav K.; Rybakova, Svetlana S.; Ladin, Evgeny D.; Kudryashova, Ekaterina A.; Sharafieva, Elvira R.; Chupakhin, Оleg N. title: Improved method for the obtaining DTTA-appended 2,2’-bipyridine ligands for lanthanide cations date: 2022-05-30 words: 2575 flesch: 59 summary: Keywords DTTA tert-butyl ester 2,2'-bipyridines Finkelstein reaction ligands for lanthanide cations alkylation Received: 25.03.22 Revised: 24.05.22 Accepted: 24.05.22 Available online: 30.05.22 Key findings ● The composition of the reaction mixture after DTTA ester alkylation with 6-bromomethyl-2,2'- bipyridine was studied. ● An improved procedure for DTTA ether alkylation with 6-halomethyl-2,2'-bipyridines was proposed. keywords: dtta; ester; lanthanide; method; mmol; reaction; yield cache: chimtech-5812.pdf plain text: chimtech-5812.txt item: #199 of 303 id: chimtech-5824 author: Rudenko, A. V.; Kataev, A. A.; Neupokoeva, M. M.; Tkacheva, O. Yu. title: Borated graphite cathodes for low-temperature aluminum electrolysis date: 2022-05-26 words: 5974 flesch: 60 summary: Principles of aluminum electrolysis. Cathode process in the KF-AlF3-Al2O3 melts. keywords: alf3; aluminum; boron; cathode; cell; current; electrolysis; electrolyte; graphite; layer; melt; temperature cache: chimtech-5824.pdf plain text: chimtech-5824.txt item: #200 of 303 id: chimtech-5831 author: Magombe, Ngonidzaishe; Kostenko, Viktoria V.; Antosyuk, Olga N.; Bolotnik, Elizaveta V. title: Testing the antigenotoxicity and anticytotoxicity properties of Prunella Grandiflora L. extract using the example of Drosophila Melanogaster date: 2022-08-08 words: 3237 flesch: 56 summary: The cytotoxic properties of etoposide of both concentrations are mani- fested in a change in the shape of the wing plate, both with respect to linear parameters and the size and shape of individual wing cells. The data obtained by us showed the absence of geno- toxic manifestations in P. grandiflora extract in 10% concentration relative to the nutrient substrate (F = 58.3; p<0.05) (Figure 4). keywords: analysis; cells; dna; etoposide; extract; grandiflora; melanogaster; wing cache: chimtech-5831.pdf plain text: chimtech-5831.txt item: #201 of 303 id: chimtech-5832 author: Gorbunova, Marina; Lemkina, Larisa; Beloglazova, Yulia title: Phosphorous-containing copolymers loaded with silver nanoparticles for biomedical purposes date: 2022-08-08 words: 4055 flesch: 52 summary: Synthesis of silver nanocomposites New silver nanocomposites based on new copolymers were obtained by the reduction of AgNO3 with NaBH4 in the copolymer solution. The article is devoted to the incorporation of silver nanoparticles into the matrices of VP copolymers with DAAP-BF4 and DAAP-Cl. keywords: activity; bf4; copolymers; daap; formation; m.n.g; nanocomposites; nanoparticles; salts; silver cache: chimtech-5832.pdf plain text: chimtech-5832.txt item: #202 of 303 id: chimtech-5834 author: Polkovnikova, Yulia A.; Glizhova, Tamara N.; Arutyunova, Naira V.; Sokulskaya, Natalya N. title: PEG- 4000 increases solubility and dissolution rate of vinpocetin in solid dispersion system date: 2022-06-30 words: 2447 flesch: 51 summary: An increased proportion of vinpocetine molecules unbound with PEG-4000 is due to the formation of clusters of substance molecules (Figures 4, 5). This is due to the smaller number of vinpocetine molecules in the system. keywords: der; figure; molecules; peg-4000; ratio; vinpocetine; water cache: chimtech-5834.pdf plain text: chimtech-5834.txt item: #203 of 303 id: chimtech-5853 author: Shurshina, Anzhela; Lazdin, Roman; Zakharova, Elena; Titlova, Anastasiya; Kulish, Elena title: Prolonging effect of polyvinyl alcohol on the drug release date: 2022-05-11 words: 5695 flesch: 61 summary: It is claimed that when moving from solutions to polymer films, the rate of drug release is also determined by the structure of the polymer matrix. Thus, in the course of evaluating the ability to prolong the action of polyvinyl al- cohol, it was shown that using some prolongation techniques, it is possible to achieve targeted regulation of the rate of drug release from polymer dosage forms. keywords: alcohol; cfz; concentration; diffusion; doi:10.1016; drug; drug release; film; increase; interaction; polymer; polyvinyl; pva; release; solution; viscosity cache: chimtech-5853.pdf plain text: chimtech-5853.txt item: #204 of 303 id: chimtech-5874 author: Kundu, Shrishnu Kumar; Patra, Susanta; Sardar, Chayan; Bhanja, Sunil Kumar; Patra, Prasanta title: Synthesis of 5H-Chromeno[4,3-b]pyridin-5-one derivatives as a backbone of natural product polyneomarline C scaffolds in presence of Et3N and NH4OAc in EtOH date: 2022-06-14 words: 2881 flesch: 56 summary: Santiagonamine is a natu- rally occurring pyridine fused coumarin derivatives found in the stems and branches of Berberisdarwinii Hook, which is a shrub that abounds in South America having wound-healing properties [13, 14]. Scheme 3 Probable mechanism for the formation of pyridocoumarin derivatives. keywords: chem; chromeno[4,3; coumarin; derivatives; et3n; etoh; nh4oac; synthesis cache: chimtech-5874.pdf plain text: chimtech-5874.txt item: #205 of 303 id: chimtech-5881 author: Kalinina, Elena G.; Rusakova, Darya S.; Pikalova, Elena Yu. title: Peculiarities of electrophoretic deposition and morphology of deposited films in non-aqueous suspensions of Al2O3–Al nanopowder date: 2022-05-12 words: 5688 flesch: 54 summary: The dependence of zeta potential on the concentration of the Al2O3–Al suspension is re- vealed. Appearance of bubbles in the deposited coatings due to the interaction of metallic aluminum particles with the liquid suspension medium during electrochemical reactions on the electrodes is defined as the main feature of the electrophoretic deposition process in the Al2O3–Al suspensions. keywords: al2o3; bubbles; coatings; concentration; deposition; electrophoretic; epd; formation; min; nanopowder; potential; suspension; time cache: chimtech-5881.pdf plain text: chimtech-5881.txt item: #206 of 303 id: chimtech-5882 author: Skugoreva, Svetlana; Gushchina, Polina; Sharipova, Yana; Darovskikh, Larisa title: Influence of the micromycete Fusarium culmorum and its antagonists on the state of the antioxidant system of Melissa officinalis L. date: 2022-05-30 words: 3596 flesch: 52 summary: It was found that the presence of the pathogenic mi- cromycete F. culmorum in the soils for growing lemon balm for two months has a stressful effect on lemon balm plants: the intensity of lipid peroxidation, the content of phenolic compounds and the amount of antioxidants in the in plant leaves were significantly high- er than in the control. Keywords lemon balm oxidative stress antioxidant system phytopathogens micromycetes antagonists Received: 29.04.22 Revised: 06.05.22 Accepted: 24.05.22 Available online: 30.05.22 Key findings ● The presence of the pathogenic micromycete Fusarium culmorum in the soil has a strong effect on lemon balm plants: it enhances lipid peroxidation, leads to the accumulation of phenolic compounds and antioxidants. keywords: antagonists; balm; content; control; culmorum; lemon; plants; russian; soil; viride cache: chimtech-5882.pdf plain text: chimtech-5882.txt item: #207 of 303 id: chimtech-5903 author: Boyandin, Anatoly N.; Sukhanova, Anna A.; Ertiletskaya, Natalya L. title: Slow-release agricultural pesticide formulations: state of the art date: 2022-06-27 words: 7218 flesch: 53 summary: Kumar J, Nisar K, Shakil NA, Sharma R. Residue and bio- efficacy evaluation of controlled release formulations of metribuzin against weeds in wheat. Fernández-Pérez M, Villafranca-Sánchez M, Flores-Céspedes F, Daza-Fernández I. Ethylcellulose and lignin as bearer poly- mers in controlled release formulations of chloridazon. keywords: bentonite; carriers; clay; components; composite; days; forms; formulations; herbicide; hours; metribuzin; pesticide; polymer; preparation; release; soil; water cache: chimtech-5903.pdf plain text: chimtech-5903.txt item: #208 of 303 id: chimtech-5912 author: Tarasova, Nataliia; Galisheva, Anzhelika; Belova, Ksenia; Mushnikova, Anastasia; Volokitina, Elena title: Ceramic materials based on lanthanum zirconate for the bone augmentation purposes: materials science approach date: 2022-05-30 words: 2556 flesch: 57 summary: Bone healing materials in the treat- ment of recalcitrant nonunions and bone defects. 9(2), No. 20229209 LETTER 4 of 4 and future opportunities for bone tissue engineering: The un- solved challenge. keywords: bone; ceramic; compositions; lanthanum; materials; method; phase; samples; tissue; zirconate cache: chimtech-5912.pdf plain text: chimtech-5912.txt item: #209 of 303 id: chimtech-5924 author: Chiriapkin, Alexey S.; Kodonidi, Ivan P.; Pozdnyakov, Dmitry I. title: Synthesis and evaluation of cerebroprotective activity of novel 6,7-dimethoxyquinazolin-4(3H)-one derivatives containing residues of amino acids and dipeptides date: 2022-06-16 words: 9125 flesch: 65 summary: General procedure for synthesis of 6,7-dimetho- xyquinazolin-4(3H)-one derivatives containing resi- dues of amino acids and dipeptides (3a–3m) A mixture of 0.01 mole of the corresponding 2-alkyl-6,7-di- methoxy-3,1-benzoxazine-4-one (2a–2e) and 0.01 mole of amino acid or dipeptide was dissolved at boiling in 10-15 ml of glacial acetic acid. Correction of mito- chondrial dysfunction by succinic acid derivatives under ex- perimental cerebral ischemia conditions. keywords: = o; acid; activity; arh; benzoxazine-4; brain; c =; ch2; ch3; compounds; derivatives; dmso; mhz; nmr; novel; ppm; spectrum; synthesis cache: chimtech-5924.pdf plain text: chimtech-5924.txt item: #210 of 303 id: chimtech-5927 author: Kokorina, Lyubov; Chernyavskaya, Yana V.; Denisova, Tatiana P.; Simonova, Elena V.; Safronov, Alexander P.; Kurlyandskaya, Galina V. title: Variability of pathogenicity factors representative of the human microbiome under the influence of γ-Fe2O3 nanoparticles date: 2022-07-04 words: 3843 flesch: 38 summary: Previously, the toxic and mutagenic properties of iron oxide nanoparticles as well as their effect on the growth and morphology of the microflora were ex- tensively investigated. Keywords laser target evaporation iron oxide nanoparticles magnetic nanoparticles biomedical applications eukaryotic and prokaryotic microorganisms normal human microflora pathogenicity factors Received: 17.05.22 Revised: 16.06.22 Accepted: 21.06.22 Available online: 04.07.22 1. keywords: + +; activity; aureus; coli; factors; human; iron; mnps; nanoparticles; oxide; pathogenicity; presence; suspension cache: chimtech-5927.pdf plain text: chimtech-5927.txt item: #211 of 303 id: chimtech-5928 author: Eshmemet’eva, Diana A.; Vshivkov, Danil K.; Vasev, Yury A.; Myasnikov, Danil A. title: Synthetic strategy toward furyl- and benzofuryl-containing building blocks for organic materials date: 2022-07-12 words: 3799 flesch: 62 summary: Kaur T, Wadhwa P, Sharma A. Arylsulfonylmethyl isocyanides: a novel paradigm in organic synthesis. Synthetic strategy toward furyl- and benzofuryl-containing building blocks for organic materials published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru ARTICLE 2022, vol. keywords: cdcl3; chem; mhz; nmr; ppm; reaction; synthesis cache: chimtech-5928.pdf plain text: chimtech-5928.txt item: #212 of 303 id: chimtech-5937 author: Sharonova, Olga M.; Solovyov, Leonid A.; Anshits, Alexander G. title: Factors for increasing strength of composite materials based on fine high-calcium fly ash date: 2022-07-19 words: 4791 flesch: 55 summary: Fly ashes with high calcium content (20–40%) contain calcium-bearing phases that inde- pendently exhibit binding properties: lime CaO, anhydrite CaSO4, calcium aluminate Ca3Al2O6, calcium aluminoferrite Ca4Al2Fe2O10, and dicalcium silicate β-Ca2SiO4 A review of the multi-component utilisation of coal fly ash. keywords: ash; calcium; cement; composition; content; fly; hcfa; materials; specimens; strength; superplasticizer cache: chimtech-5937.pdf plain text: chimtech-5937.txt item: #213 of 303 id: chimtech-5938 author: Igolnikov, Alexander A.; Yampol'skiy, Aleksandr D. title: To the possibility of experimental estimation of the diffusion spinodal position of binary mixture with LCST via pulsed heating method date: 2022-08-10 words: 3485 flesch: 59 summary: Experimental estimation of the diffusion spinodal position of binary mixture with LCST based on the method of isobaric pulse heating published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru ARTICLE 2022, vol. 9(4), No. 20229408 DOI: 10.15826/chimtech.2022.9.4.08 1 of 6 To the possibility of experimental estimation of the diffusion spinodal position of binary mixture with LCST via pulsed heating method Alexander A. Igolnikov ab , Aleksandr D. Yampol'skiy a a: Institute of Thermal Physics UB RAS, Ekaterinburg 620016 Russia b: Ural Federal University, Ekaterinburg 620000, Russia keywords: heating; mixture; phase; pressure; probe; spinodal; temperature cache: chimtech-5938.pdf plain text: chimtech-5938.txt item: #214 of 303 id: chimtech-5974 author: Shakiyeva, Tatyana V.; Sassykova, Larissa R.; Khamlenko, Anastassiya A.; Dzhatkambayeva, Ulzhan N.; Sassykova, Albina R.; Batyrbayeva, Aigul A.; Zhaxibayeva, Zhanar M.; Ismailova, Akmaral G.; Sendilvelan, Subramanian title: Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products date: 2022-07-04 words: 5662 flesch: 57 summary: Composition of gaseous products (%) of M-100 fuel oil cracking (wsuspension = 1.0 h –1, T = 470 °C) Composition of gases Cracking conditions without catalyst and air without cata- lyst, wair=0.15 h –1 0.2 wt.% zeolite- containing catalyst, without air 0.2 wt.% zeo- lite- containing catalyst, wair=0.15 h –1 Hydrogen 2.8 3.4 10.7 4.3 Methane/ Ethane 16.2/15.5 20.1/18.4 68.0/4.9 21.8/20.1 Ethylene/ Butylene 25.4/9.2 25.7/6.1 11.7/0.2 29.3/2.8 Propane/ Propylene 5.6/17.6 5.6/14.0 0.1/0.1 5.6/12.2 Carbon Monoxide/ Carbon Dioxide 6.3/1.4 6.7/0 4.9/0 3.8/0.1 Figure 5 Composition of gaseous products of M-100 fuel oil cracking. Senter C, Mastry MC, Mannion AM, McGuire Jr R. Quantita- tive visual characterization of contaminant metals and their mobility in fluid catalytic cracking catalysts. keywords: air; catalyst; catalytic; chem; composition; cracking; doi:10.1016; fractions; fuel; fuel oil; gas; heavy; hydrocarbon; m-100; oil; presence; process; products; sassykova; yield; zeolite cache: chimtech-5974.pdf plain text: chimtech-5974.txt item: #215 of 303 id: chimtech-5975 author: Tashmukhambetova, Zheneta Kh.; Kalamgali, Tanakoz O.; Aubakirov, Yermek A.; Sassykova, Larissa R.; Akhmetova, Firuza Zh.; Alpysbay, Albina S. title: Activity features of catalysts for thermocatalytic hydrogenation processing of polymer waste date: 2022-07-05 words: 3769 flesch: 54 summary: Activity features of catalysts for thermocatalytic hydrogenation processing of polymer waste published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru ARTICLE 2022, vol. 9(3), No. 20229302 DOI: 10.15826/chimtech.2022.9.3.02 1 of 6 Activity features of catalysts for thermocatalytic hydrogenation processing of polymer waste Zheneta Kh. keywords: catalysts; composition; diatomite; doi:10.1016; fraction; fuel; hydrogenation; mo(vi; oil; polymer; processing; w(vi)/diatomite; waste cache: chimtech-5975.pdf plain text: chimtech-5975.txt item: #216 of 303 id: chimtech-5979 author: Tarasova, Nataliia; Galisheva, Anzhelika title: Phosphorus-doped protonic conductors based on BaLanInnO3n+1 (n = 1, 2): applying oxyanion doping strategy to the layered perovskite structure date: 2022-07-12 words: 4100 flesch: 58 summary: The scheme of oxyanion doping strategy of layered per- ovskites. 4. Conclusions In this paper, the oxyanion doping strategy was purpose- fully applied to the proton-conducting layered perovskites for the first time. keywords: cells; ceramic; conducting; conductivity; doi:10.1016; doping; energy; int; materials; oxide; oxyanion; perovskite; proton; protonic; solid cache: chimtech-5979.pdf plain text: chimtech-5979.txt item: #217 of 303 id: chimtech-5980 author: Komolikov, Yury I.; Ermakova, Larisa V.; Khrustov, Vladimir R.; Zhuravlev, Victor D. title: Dilatometric characteristics of weakly sintered ceramics date: 2022-09-13 words: 3890 flesch: 58 summary: Introduction Thermal stability of ceramic materials based on zirconium and/or aluminum oxides makes it possible to use them as functional ceramics and thermal barrier coatings at high temperatures [1–5]. For thermal barrier coatings (TBC) it is particularly important to determine the linear thermal-expansion coeffi- cient (LTEC), since for providing good contact between lay- ers of gradient coating it is necessary to select compositions with close, gradually varying LTEC values. keywords: cazro3; ceramics; density; doi:10.1016; la2zr2o7; materials; mgal2o4; powders; samples; sintering; temperature cache: chimtech-5980.pdf plain text: chimtech-5980.txt item: #218 of 303 id: chimtech-5988 author: Eremina, Natalya V.; Makarova, Svetlana V.; Isaev, Denis D.; Bulina, Natalya V. title: Soft mechanochemical synthesis and thermal stability of hydroxyapatites with different types of substitution date: 2022-07-26 words: 4391 flesch: 57 summary: Cu-substituted HA Figure 1a shows that PXRD patterns of HA samples contain- ing copper are identical and match the pattern of unsubsti- tuted HA. Therefore, in the sample 0.5Cu(О)–OH, copper ions do not replace hydroxyl groups. keywords: calcium; cations; copper; figure; iron; phase; samples; stability; synthesis; temperature cache: chimtech-5988.pdf plain text: chimtech-5988.txt item: #219 of 303 id: chimtech-5990 author: Nepochatov, Yuri K.; Pletnev, Pyotr M.; Kosarev, Vladimir F.; Gudyma, Tatiana S. title: Development of technology for deposition of thick copper layers onto ceramic substrates applied in power electronics date: 2022-07-26 words: 2593 flesch: 55 summary: Development of technology for deposition of thick copper layers onto ceramic substrates applied in power electronics published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru LETTER 2022, vol. 9(3), No. 20229307 DOI: 10.15826/chimtech.2022.9.3.07 1 of 4 Development of technology for deposition of thick copper layers onto ceramic substrates applied in power electronics Yuri K. Nepochatov a, Pyotr M. Pletnev b , Vladimir F. Kosarev c, Тatiana S. Gudyma d* keywords: aluminum; ceramics; coating; cold; copper; gdcs; spray; substrates cache: chimtech-5990.pdf plain text: chimtech-5990.txt item: #220 of 303 id: chimtech-5994 author: Kodintcev, Anton N. title: Characterization and potential applications of silver nanoparticles: an insight on different mechanisms date: 2022-07-11 words: 17470 flesch: 51 summary: Additionally, biochemical and pathophysiological mechanisms of silver nanoparticles activity against various microorganisms and tumor cells are considered. Silver nanoparticles (AgNPs) have unique binding proper- ties, including internal antimicrobial activity and poten- tially low toxicity. keywords: acta; activity; addition; agents; aggregation; agnps; antibacterial; antifungal; applications; cancer; cell; charge; chen; chimica; coli; concentration; data; dna; doi:10.1016; doi:10.2147; doi:10.3390; effect; environ; figure; formation; growth; increase; inhibition; int; interaction; ions; mechanisms; membrane; nanoparticles; potential; processes; properties; protein; res; review; role; sci; silver; silver nanoparticles; size; stability; surface; synthesis; techno; toxicity; virus; vitro; vol cache: chimtech-5994.pdf plain text: chimtech-5994.txt item: #221 of 303 id: chimtech-6010 author: Titkov, Alexander A.; Borisenko, Tatiana A.; Logutenko, Olga A. title: Glucose-assisted polyol synthesis of silver nanoplates and nanoprisms in the presence of oxyethylated carboxylic acid date: 2022-08-03 words: 3168 flesch: 61 summary: As shown in this study, the addition of glucose (Glu) in the synthesis of silver nanoparticles in a mixture of eth- ylene glycol and sodium salt of MEEAA (NaR) affects the yield of silver nanoplates. Glucose-assisted polyol synthesis of silver nanoplates and nanoprisms in the presence of oxyethylated carboxylic acid published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru LETTER 2022, vol. keywords: glucose; nanoparticles; nanoplates; nanoprisms; presence; silver; synthesis; temperature; yield cache: chimtech-6010.pdf plain text: chimtech-6010.txt item: #222 of 303 id: chimtech-6012 author: Golovakhin, Valeriy V.; Kim, Ekaterina Yu.; Novgorodtseva, Oksana N.; Bannov, Alexander G. title: Effect of chemical treatment of multi-walled carbon nanotubes on the specific capacitance of supercapacitors date: 2022-08-08 words: 3779 flesch: 54 summary: Similarly, carbon nanotubes with different morphologies (single-walled and multi-walled carbon nanotubes (MWNTs)) can be produced by varying differ- ent catalysts and process parameters. A decrease in specific surface area, similarly associ- ated with the oxidation of carbon nanotubes, was also ob- served. keywords: acid; capacitance; carbon; chemical; effect; electrode; functionalization; groups; materials; nanotubes; oxidation; oxygen; surface; treatment cache: chimtech-6012.pdf plain text: chimtech-6012.txt item: #223 of 303 id: chimtech-6013 author: Mishchenko, Kseniya V.; Kirsanova, Maria A.; Slobodyuk, Arseny B.; Krinitsyna, Anna A.; Kosova, Nina V. title: Effect of cooling rate on the structure and electrochemical properties of Mn-based oxyfluorides with cation-disordered rock-salt structure date: 2022-08-04 words: 6522 flesch: 58 summary: On the other hand, using geometrical- topological method (bond-valence site energy modeling, BVSE), and density functional theory (DFT) calculations, we demonstrated that Mn ions form MnO6 clusters, which are preferably linked in dense layers in Li1.3Nb0.3Mn0.4O2, and negatively affects lithium diffusion The decrease in the state of charge can be explained by a partial reduction of Mn ions during synthesis. keywords: capacity; cathode; content; disordered; f0.05; f0.15q; figure; fluorine; ions; lithium; materials; redox; samples; spectra; state; structure cache: chimtech-6013.pdf plain text: chimtech-6013.txt item: #224 of 303 id: chimtech-6014 author: Jeldybayeva, Indira M.; Kairbekov, Zhaksyntay K.; Kishibayev, Kazhmukan O.; Yermoldina, Elmira T.; Suimbayeva, Saltanat M. title: Catalytic activity and selectivity of Palladium and Nickel catalysts in hydrogenation reactions of nitro- and acetylene compounds date: 2022-07-26 words: 3952 flesch: 55 summary: It was shown that the activity and selectivity of nickel catalysts in the hydrogenation of phenylacety- lene depend on the nature of modifying additives (Cu, Zn, Ti, Cr, Bi, Ti–Cu, Mn, Fe), and the activity and selectivity of palladium catalysts based on a polymer of metal complexes depends on the method of their preparation. A Study of catalytic activity of palladium catalysts with potassium humate in hydrogenation reactions. keywords: activity; catalysts; hydrogenation; nickel; palladium; phenylacetylene; polymer; pth; selectivity cache: chimtech-6014.pdf plain text: chimtech-6014.txt item: #225 of 303 id: chimtech-6015 author: Maksotova, Kuralay S.; Kalikh, Dariya T.; Omirzakova, Arnur T.; Bakirova, Botagoz S.; Akbayeva, Dina N. title: Polymer-metal complex based on copper(II) acetate and polyvinyl alcohol: thermodynamic and catalytic properties date: 2022-07-26 words: 4317 flesch: 54 summary: Given the steric, electronic and conformational properties, suitable ligands must be designed for metal complexes that function as effective catalysts. Furthermore, the consideration of steric, electronic and conformational properties is necessary for the design of suitable ligands for metal complexes that will serve as ef- fective catalysts. keywords: acetate; alcohol; complex; copper(ii; formation; metal; oxidation; phosphorus; polymer; polyvinyl; process; pva; reaction; solution cache: chimtech-6015.pdf plain text: chimtech-6015.txt item: #226 of 303 id: chimtech-6016 author: Lapekin, Nikita I.; Anufrieva, Tatyana V.; Ukhina, Arina V.; Shestakov, Artem A.; Bannov, Alexander G. title: Solvent effect on the NO2 sensing properties of multi-walled carbon nanotubes date: 2022-08-08 words: 3799 flesch: 59 summary: Keywords carbon nanomaterials MWNTs films gas sensors NO2 detection ultrasonic dispersion polar solvent Received:25.06.22 Revised: 22.07.22 Accepted: 22.07.22 Available online: Typically, gas sensors are implemented http://chimicatechnoacta.ru/ https://doi.org/10.15826/chimtech.2022.9.3.11 mailto:Bannov.alexander@gmail.com https://www.kaznu.kz/en/25415/page http://creativecommons.org/licenses/by/4.0/ https://orcid.org/0000-0001-6101-9707 https://orcid.org/0000-0001-5868-9013 https://crossmark.crossref.org/dialog/?doi=https://doi.org/10.15826/chimtech.2022.9.3.11&domain=pdf&date_stamp=2022-8-8 Chimica Techno Acta 2022, vol. keywords: carbon; figure; films; gas; mwnts; no2; ppm; properties; recovery; response; sensing; sensors; solvent; temperature cache: chimtech-6016.pdf plain text: chimtech-6016.txt item: #227 of 303 id: chimtech-6017 author: Tryakhov, Denis E.; Polytov, Anatoly A. title: Chemical-mechanical treatment of potato starch for isolation of nanocrystal particles date: 2022-08-12 words: 2604 flesch: 56 summary: With longer hydrolysis and ultrasonic processing, sub- micron plates of starch particles are destroyed and more isometric nanoparticles with a characteristic size of 20–200 nm are formed. 4. Conclusions This work proposes a chemical-mechanical method for producing potato starch nanoparticles with controlled par- ticle size. keywords: granules; hydrolysis; nanoparticles; native; particles; potato; size; starch cache: chimtech-6017.pdf plain text: chimtech-6017.txt item: #228 of 303 id: chimtech-6018 author: Zhumabekova, Arai K.; Tastanova, Lyazzat K.; Orynbassar, Raigul O.; Aubakirov, Yermek A.; Zhunusova, Elvira B. title: Conversion of model C6–C9 alkanes and straight-run gasoline over Pt(0.1%)-Fe(5%)/Al2O3 catalysts promoted with various additives date: 2022-07-26 words: 3503 flesch: 58 summary: Molecular sieve effect was shown when comparing the properties of catalysts containing L and E zeolites. Abstract Growing demand for hydrogen promotes the research devoted to the development of new catalysts for hydrocarbons processing in ab- sence of H2 or at its low concentration. keywords: catalyst; conversion; gasoline; hydrocarbons; isoalkanes; yield; zeolite cache: chimtech-6018.pdf plain text: chimtech-6018.txt item: #229 of 303 id: chimtech-6025 author: Bushueva, Evdokiya; Turlo, Evgeniy; Kladieva, Evgeniya; Sulyaeva, Veronica; Pukhova, Elizaveta title: Influence of alloying (Cr, Fe, Ni) on the corrosion resistance of layers formed by electron-beam processing date: 2022-08-12 words: 2183 flesch: 49 summary: One of the reasons for corrosion resistance of chromium- modified layers is related to the morphology of the chromi- um borides Cr2B formed during the surfacing. 8. Bushueva E, Turlo Y, Khamgushkeeva G. Influence of chromium concentration on corrosion resistance of surface layers of stain- less steel. keywords: beam; borides; boron; chromium; corrosion; electron; materials; resistance; steel; surfacing cache: chimtech-6025.pdf plain text: chimtech-6025.txt item: #230 of 303 id: chimtech-6026 author: Bagryantseva, Irina N.; Kungurtsev, Yuri E.; Ponomareva, Valentina G. title: Proton-conducting membranes based on CsH2PO4 and copolymer of tetrafluoroethylene with vinylidene fluoride date: 2022-07-19 words: 2921 flesch: 55 summary: Mechanical properties of the mem- branes were measured by Vickers microhardness tests for a low pol- ymer content (x˂0.15), also the tensile strength for membranes with high polymer content x=0.2–0.3 were evaluated. For higher polymer content (x>0.15) it was possi- ble to produce thin flexible films with a thickness ~150 µm by tape casting method. keywords: conductivity; csh2po4; electrolytes; i.n.b; membranes; polymer; proton; salt; solid; temperature cache: chimtech-6026.pdf plain text: chimtech-6026.txt item: #231 of 303 id: chimtech-6027 author: Afonina, Liubov I.; Timakova, Tatiana E.; Timakova, Evgeniya V.; Gerasimov, Konstantin B.; Yukhin, Yuri M. title: Thermal transformations of bismuth (III) tartrates date: 2022-08-25 words: 4691 flesch: 58 summary: However, the use of bismuth tartrate as a precursor for the synthesis of oxide materials has not yet been suffi- ciently reported in the literature. The composition of bismuth tartrate was not indicated, nor was the polymorphic modification of the resulting oxide. keywords: acid; bi2o3; bismuth; cm–1; figure; ions; nitrate; oxide; samples; synthesis; tartrate; thermal; thermolysis cache: chimtech-6027.pdf plain text: chimtech-6027.txt item: #232 of 303 id: chimtech-6038 author: Priyanto, Slamet; Sudrajat, Ronny W.; Suherman, Suherman; Pramudono, Bambang; Riyanto, Teguh; Setianingrum, Desty D.; Pratama, Alfin A. title: Synthesis and performance evaluation of polymeric surfactant from rice husk and polyethylene glycol for the enhanced oil recovery process date: 2022-07-12 words: 6634 flesch: 63 summary: The research that has been done is to produce SLS surfactant from rice husk Synthesis and performance evaluation of polymeric surfactant from rice husk and polyethylene glycol for the enhanced oil recovery process published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru ARTICLE 2022, vol. keywords: brine; eor; ift; increase; oil; peg; process; recovery; rice; sls; sls surfactant; solution; surfactant; test; value; viscosity; water cache: chimtech-6038.pdf plain text: chimtech-6038.txt item: #233 of 303 id: chimtech-6074 author: Svalova, Tatiana S.; Zaidullina, Regina A.; Medvedeva, Margarita V.; Vedernikova, Elizaveta D.; Kozitsina, Alisa N. title: Electrochemical behavior of chloramphenicol on carbon electrodes in a microelectrochemical cell date: 2022-08-16 words: 2787 flesch: 51 summary: 9(4), No. 20229409 ARTICLE 4 of 5 Scheme 1 Proposed mechanism of CAP electrochemical reduction in microcell. Transition from standard electrochemical cells to portable microdevices requires additional studies of the http://chimicatechnoacta.ru/ https://doi.org/10.15826/chimtech.2022.9.4.09 mailto:zaidullina.regina@urfu.ru http://creativecommons.org/licenses/by/4.0/ https://orcid.org/0000-0002-0263-2111 https://crossmark.crossref.org/dialog/?doi=https://doi.org/10.15826/chimtech.2022.9.4.09&domain=pdf&date_stamp=2022-8-16 Chimica Techno Acta 2022, vol. keywords: cap; cell; chloramphenicol; current; detection; determination; electrode; figure; peak cache: chimtech-6074.pdf plain text: chimtech-6074.txt item: #234 of 303 id: chimtech-6086 author: Deeva, Yulia A.; Mirzorakhimov, Abdullo A.; Suntsov, Alexey Yu.; Kadyrova, Nadezhda I.; Melnikova, Nina V.; Chupakhina, Tatyana I. title: The effect of processing conditions on the dielectric properties of doped calcium lanthanum nickelate date: 2022-08-23 words: 5880 flesch: 59 summary: Abstract The influence of thermal and thermobaric (TBT) effects on the struc- ture, microstructure, and dielectric properties of ceramics based on solid solutions of the La1.8Ca0.2Ni0.8M0.2O4+δ (M = Co, Cu) composition was studied. Dielectric properties of La1.8Ca0.2Ni0.8M0.2O4+δ (M = Co, Cu) ceramics The relative complex permittivity, admittance and loss tan- gent were estimated by measuring the impedance Z = Re Z + i ImZ with the equation: ∗(𝜔) = 𝑙 𝑆 1 𝑖𝜔 0𝑍 ∗(𝜔) , (2) 𝑌∗(𝜔) = 1 𝑍∗(𝜔) , (3) tan 𝛿(𝜔) = Im Re , (4) where  is the circular frequency (ω = 2π𝑓, and 𝑓 is the lin- ear frequency of electric field), 0 is the dielectric constant of vacuum, and 𝑙 and S are the sample thickness and the surface area contacting with one electrode, respectively. keywords: ceramics; constant; dielectric; figure; frequency; la1.8ca0.2ni0.8m0.2o4+δ; properties; samples; structure; tbt; temperature; treatment cache: chimtech-6086.pdf plain text: chimtech-6086.txt item: #235 of 303 id: chimtech-6103 author: Shcherban, Pavel; Masyutin, Yakov; Vatagina, Anna; Belova, Margarita; Stolyarenko, Alexander title: Investigation of physical and chemical parameters of the raw hydrocarbon material base of Kaliningrad region for the concept development of an oil refinery date: 2022-09-13 words: 4813 flesch: 54 summary: ● The necessities of the Kaliningrad region in gasoline, diesel, fuel oil, and other petroleum products could be fulfilled by local crude oil fields. The balance is based on the distillation (primary) processes and not takes into account the additional separation of fuel oil (secondary processes). keywords: chemical; crude; diesel; fuel; gasoline; kaliningrad; oil; oils; production; products; refinery; region; samples; volume cache: chimtech-6103.pdf plain text: chimtech-6103.txt item: #236 of 303 id: chimtech-6133 author: Uvarov, Nikolai F.; Aubakirov, Ermek A. title: The CTFM2022 special issue: Chemical Technologies of Functional Materials date: 2022-08-25 words: 322 flesch: 26 summary: Physical and chemical studies of catalytic processes and catalysts of petrochemicals and oil refining. The Special Issue of the journal Chimica Techno Acta includes papers presented at 8-th International Russian- Kazakhstan Conference “Chemical Technologies of Func- tional Materials” held at Al-Farabi Kazakh National Uni- versity, Almaty, Kazakhstan, 28–29 April 2022. keywords: conference; university cache: chimtech-6133.pdf plain text: chimtech-6133.txt item: #237 of 303 id: chimtech-6159 author: Anh, L. H. Q.; Tran, Uyen P. N.; Nghi, P. V. G.; Le, H. T.; Khuyen, N. T. B.; Hai, T. D. title: Titanium dioxide - activated carbon composite for photoelectrochemical degradation of phenol date: 2022-10-25 words: 7339 flesch: 62 summary: The TiO2–AC pho- toanode exhibited a better charge transfer in comparison to TiO2 one because Nyquist plots of the TiO2–AC photoanode show smaller semicircles in both UV and non-UV excitation. Moreover, the TiO2–AC photoanode presents a higher efficiency of PEC degradation of phenol than the TiO2 photoanode owing to the contribution of electric con- ductivity of AC. keywords: carbon; contact; degradation; figure; pec; ph0; phenol; photoanode; photocatalytic; photoelectrochemical; time; tio2 cache: chimtech-6159.pdf plain text: chimtech-6159.txt item: #238 of 303 id: chimtech-6219 author: Biryukov, Alexander I.; Zakharyevich, Dmitry A.; Batmanova, Tatyana V.; Galin, Rashit G.; Ulyanov, Maksim N.; Zhivulin, Vladimir E. title: Corrosion of diffusion zinc coatings in sodium chloride solutions date: 2022-11-18 words: 4174 flesch: 58 summary: Diffusion coatings have a number of advantages over other types of zinc coatings. Corrosion of diffusion zinc coatings in sodium chloride solutions published by Ural Federal University eISSN 2411-1414; chimicatechnoacta.ru ARTICLE 2022, vol. keywords: chloride; coatings; corrosion; diffusion; phase; products; rate; steel; surface; thickness; zinc; zinc coatings cache: chimtech-6219.pdf plain text: chimtech-6219.txt item: #239 of 303 id: chimtech-6227 author: Shchemelev, Ivan S.; Khasanov, Danil S.; Smirnova, Maria A.; Ivanov, Alexander V.; Ferapontov, Nikolay B.; Tokmachev, Mikhail G. title: Determination of reducing carbohydrates in natural honey samples by optical micrometry method date: 2022-11-07 words: 3945 flesch: 55 summary: Materials and methods All necessary reagents and solution preparation methods are described in [29]. Besides, OM method can be simply miniaturized and used out of laboratories, whereas the most important limitation of photonic crystal sensors is a strictly fixed angle angle between the sensitive element and the measurement device. keywords: analysis; determination; fructose; glucose; honey; method; moscow; polymer; pva; samples; solution; swelling cache: chimtech-6227.pdf plain text: chimtech-6227.txt item: #240 of 303 id: chimtech-6270 author: Vereshchagina, Tatiana A.; Kutikhina, Ekaterina A.; Buyko, Olga V.; Anshits, Alexander G. title: Hydrothermal synthesis and sorption performance to Cs(I) and Sr(II) of zirconia-analcime composites derived from coal fly ash cenospheres date: 2022-11-10 words: 6618 flesch: 60 summary: The zirconia inclusions in the bulk of analcime crystals with an average Zr content of 4.8 wt.% was supported in [32] by the SEM-EDS measurements over analcime crystal cross-sections and X-ray photoelectron spectroscopy. The enhanced SSA of the Zr-free SS-ANA-50 is likely to be due to the porosity of residual leached glass and mi- cro/meso-sized voids between analcime crystals fixed on glass. keywords: analcime; ana–30; bearing; composite; cs+; figure; hzd; materials; phase; solid; sorption; sr2; synthesis; waste; zirconia; zirconium cache: chimtech-6270.pdf plain text: chimtech-6270.txt item: #241 of 303 id: chimtech-6273 author: Rabadanova, Alina; Abdurakhmanov, Magomed; Gulakhmedov, Rashid; Shuaibov, Abdulatip; Selimov, Daud; Sobola, Dinara; Částková, Klára; Ramazanov, Shikhgasan; Orudzhev, Farid title: Piezo-, photo- and piezophotocatalytic activity of electrospun fibrous PVDF/CTAB membrane date: 2022-11-17 words: 5447 flesch: 53 summary: In situ growth of ZnO/Ag2O heterostructures on PVDF nanofibers as efficient visible-light-driven photocatalysts. PVDF nanofibers were produced by coaxial electrospinning on a Contipro 4SPIN LAB facility (Contipro as, Dolni Dobrouc, Czech Republic). keywords: activity; ctab; decomposition; doi:10.1016; figure; light; membrane; nanofibers; phase; photocatalytic; polymer; pvdf cache: chimtech-6273.pdf plain text: chimtech-6273.txt item: #242 of 303 id: chimtech-6274 author: G.V., Megha; Bodke, Yadav D.; H., Shanavaz; Joy, Muthipeedika Nibin title: Substituted benzocoumarin derivatives: synthesis, characterization, biological activities and molecular docking with ADME studies date: 2022-11-16 words: 7152 flesch: 65 summary: The molecular weight of synthesized compounds was confirmed by a LC-MS 2010, SHIMADZU, mass analyzer. Table 1 Analysis and specification of synthesized compounds (4a–j). keywords: = o; activity; cancer; chem; compounds; coumarin; derivatives; dmso; docking; drug; mol; nmr; results; studies; table cache: chimtech-6274.pdf plain text: chimtech-6274.txt item: #243 of 303 id: chimtech-6290 author: Maraeva, Evgeniya; Radaykin, Dmitriy; Bobkov, Anton; Permiakov, Nikita; Matveev, Vasily; Maximov, Alexander; Moshnikov, Vyacheslav title: Sorption analysis of composites based on zinc oxide for catalysis and medical materials science date: 2022-11-22 words: 4795 flesch: 53 summary: NTD belongs to the group of non-destructive techniques that provide express analysis of such parameters of nano- materials as specific surface area, average particle size, mesopore size distribution, and presence or absence of micropores in the system [26]. The aim of this work was to obtain composite struc- tures based on zinc oxide and hydroxyapatite, as well as zinc oxide with silver additives, to study their phase com- position, specific surface area and nanoparticle size. keywords: area; composites; hydroxyapatite; nanoparticles; oxide; properties; sample; silver; size; solution; surface; surface area; zinc; zinc oxide; zno cache: chimtech-6290.pdf plain text: chimtech-6290.txt item: #244 of 303 id: chimtech-6294 author: Abdurakhimova, Rayana K.; Laptev, Michail V.; Leonova, Natalia M.; Leonova, Anastasia M.; Schmygalev, Alexander S.; Suzdaltsev, Andrey V. title: Electroreduction of silicon from the NaI–KI–K2SiF6 melt for lithium-ion power sources date: 2022-12-06 words: 4512 flesch: 52 summary: 01.12.22 Available online: 06.12.22 Key findings ● The possibility of electrodeposition of silicon deposits with a developed surface from the NaI–KI–K2SiF6 melt at a temperature from 650 to 750 °С was shown for the first time. To decrease the electrolysis temperature, stabilize the composition of the silicon-containing electroactive parti- cles and to control the morphology of silicon deposits, the melts containing iodides may be used. keywords: anode; cathode; deposits; electrolysis; electroreduction; ion; k2sif6; lithium; melt; molten; nai; power; silicon; temperature cache: chimtech-6294.pdf plain text: chimtech-6294.txt item: #245 of 303 id: chimtech-6296 author: Mozharovskaia, Polina N.; Ivoilova, Alexandra V.; Drokin, Roman A.; Ivanova, Alla V.; Kozitsina, Alisa N.; Rusinov, Vladimir L. title: The electrochemical behavior’s character of a potential antiviral drug 3-nitro-4-hydroxy-7-methylthio-4H-[1,2,4]triazolo[5,1-c][1,2,4]triazinide monohydrate date: 2022-12-13 words: 4179 flesch: 55 summary: Figure 3 Values of current (A) and potential (B) of the peak of compound 1 (5 mM) with a change in the pH of the buffer solution at ν = 100 mV/s. Figure 4 Logarithmic dependence of the peak current on the rate of potential application (a) and dependence of the peak current on the square root of the rate of application of potential compound 1 in the BRB pH = 2 on the GCE (b). 9(4), No. 20229426 ARTICLE 4 of 6 Note that compound 1 is a salt formed by the Na+ cation and heterocyclic anions; therefore, its reduction should have proceeded at more negative potential values compared to compounds 2–3. keywords: antiviral; compound; current; drug; ecr; electrode; figure; medium; nitro; potential; reduction; solution cache: chimtech-6296.pdf plain text: chimtech-6296.txt item: #246 of 303 id: chimtech-6317 author: Troitskaia, Irina B.; Syrokvashin, Mikhail M.; Korotaev, Evgeny V.; Saprykin, Anatoly I. title: Effect of gas-chromatography column regeneration during the CHN/S analysis of copper-chromium disulfide date: 2022-11-22 words: 2423 flesch: 56 summary: The baseline shape influence on the measured C, H, N, S contents was estimated by analyzing the SAM and ATRS standards after GCC regeneration using the above proce- dure. Such baseline shape provides good separation of chromatographic peaks and a highly accurate determination of C, H, N, S contents in the subsequent measurements. keywords: analysis; baseline; chn; copper; cucrs2; effect; figure; gcc; regeneration; samples cache: chimtech-6317.pdf plain text: chimtech-6317.txt item: #247 of 303 id: chimtech-6321 author: Solovev, Artem V.; Starostin, Georgy N.; Zvonareva, Inna A.; Tulenin, Stanislav S.; Markov, Vyacheslav F. title: Electrophoretic deposition of YSZ layers on pyrolytic graphite and a porous anode substrate based on NiO-YSZ date: 2022-12-09 words: 3670 flesch: 51 summary: Electrophoretic deposition of YSZ layers on pyrolytic graphite and a porous anode substrate based on NiO-YSZ published by Ural Federal University eISSN2411-1414; chimicatechnoacta.ru LETTER 2022, vol. 9(4), No. 20229425 DOI: 10.15826/chimtech.2022.9.4.25 1 of 6 Electrophoretic deposition of YSZ layers on pyrolytic graphite and a porous anode substrate based on NiO–YSZ Artem V. Solovev a* , George N. Starostin ab , Inna A. Zvonareva ab , Stanislav S. Tulenin a , Vyacheslav F. Markov ac a: Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg 620002, Russia b: Institute of High Temperature Electrochemistry, Ekaterinburg 620660, Russia c: Ural Institute of the State Fire Service of the Ministry of Emergency Situations of Russia, Ekaterinburg 620062, Russia * keywords: anode; deposition; electrophoretic; fuel; graphite; layers; nio; oxide; solid; substrate; suspension; ysz cache: chimtech-6321.pdf plain text: chimtech-6321.txt item: #248 of 303 id: chimtech-6325 author: Igidov, Sergei N.; Lipin, Dmitriy V.; Turyshev, Aleksey Yu.; Chashchina, Svetlana V.; Shipilovskikh, Daria A.; Zvereva, Ol’ga V.; Mitusova, Ksenia A.; Silaichev, Pavel S.; Igidov, Nazim M. title: Synthesis, intramolecular cyclization and anti-inflammatory activity of substituted 2-(2-(Furan-2-carbonyl)hydrazono)-4-oxobutanoic Acids date: 2022-12-16 words: 5520 flesch: 70 summary: Synthesis, intramolecular cyclization and anti-inflammatory activity of substituted 2-(2-(Furan-2-carbonyl)hydrazono)-4-oxobutanoic Acids published by Ural Federal University eISSN 2411-1414 chimicatechnoacta.ru ARTICLE 2023, vol. Intramolecular cyclization of acids 3a–h occurs upon slow heating to 150 °С in propionic anhydride and led to the formation of substituted N'-(2-oxofuran-3(2H)-ylidene)fu- ran-2-carbohydrazides 4a–h (Scheme 3). keywords: form; harom; jhh; spectrum; synthesis cache: chimtech-6325.pdf plain text: chimtech-6325.txt item: #249 of 303 id: chimtech-6331 author: Timofeeva, Maria V.; Yankin, Andrey N. title: Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt date: 2022-12-22 words: 5113 flesch: 57 summary: Jia R, Zhang R, Yu L, Kong X, Bao S, Tu M, Xu B. Engineering a hierarchical carbon supported magnetite nanoparticles composite from metal organic framework and graphene oxide for lithium-ion storage. De novo synthesis and particle size control of iron metal organic framework for diclofenac drug delivery. keywords: acid; chem; diffraction; dmf; doi:10.1016; framework; h2o; m.v.t; materials; metal; mof; mofs; salt; samples; solvent; structure; synthesis; zhang; znbtc cache: chimtech-6331.pdf plain text: chimtech-6331.txt item: #250 of 303 id: chimtech-6347 author: Igidov, Sergei N.; Gorbunova, Irina A.; Turyshev, Aleksey Yu.; Shipilovskikh, Daria A.; Kozlov, Danil A.; Rogova, Anna S.; Makhmudov, Ramiz R.; Silaichev, Pavel S.; Igidov, Nazim M. title: Synthesis, recyclization under the action of methanol and analgetic activity of N'-(5-aryl-2-oxofuran-3(2H)-ylidene)furan-2-carbohydrazides date: 2022-12-01 words: 6170 flesch: 66 summary: Russ J Org Chem. Russ J Org Chem. keywords: acids; activity; chem; compounds; dmso; form; harom; jhh; nmr; ppm; russ; shipilovskikh; synthesis cache: chimtech-6347.pdf plain text: chimtech-6347.txt item: #251 of 303 id: chimtech-6369 author: Berlina, Anna N.; Ragozina, Maria Y.; Komova, Nadezhda S.; Serebrennikova, Kseniya V.; Zherdev, Anatoly V.; Dzantiev, Boris B. title: Сomparison of Au, Au-Pt, and Au-Ag nanoparticles as markers for immunochromatographic determination of nonylphenol date: 2022-12-19 words: 3605 flesch: 51 summary: Composition of lateral flow test strip and the main com- ponents for analysis. Then, pre- pared Au nanoparticles were pre-adjusted to pH of 8.0 by 0.2 M K2CO3. keywords: analysis; dzantiev; flow; gold; nanoparticles; nonylphenol; protein; synthesis; test; zherdev cache: chimtech-6369.pdf plain text: chimtech-6369.txt item: #252 of 303 id: chimtech-6370 author: Salimgareeva, Elena; Igdisanova, Dinara; Gordeeva, Daria; Yarkova, Elena; Matern, Anatoly; Gerasimova, Elena; Ivanova, Alla title: Portable potentiometric device for determining the antioxidant capacity date: 2022-12-21 words: 5550 flesch: 51 summary: Arikana B, Alpa FN, Ozfidan-Konakcib C, Balcia M, Elbasana F, Yildiztugaya E, Cavusoglu H. Fe2O3-modified graphene ox- ide mitigates nanoplastic toxicity via regulating gas ex- change, photosynthesis, and antioxidant system in Triticum aestivum. Many methods for assessing antioxidant properties use strong oxidizing agents, or the analysis is carried out in an acidic solution, which, again, makes it difficult to use them for the analysis of objects containing proteins and amino acids. keywords: analysis; antioxidant; aoc; capacity; chem; content; device; grade; method; microcell; objects; portable; potentiometric; scheme; silver; wire cache: chimtech-6370.pdf plain text: chimtech-6370.txt item: #253 of 303 id: chimtech-6378 author: Okhokhonin, Andrei V.; Ibatullina, Alsu A.; Izmozherova, Yulia V.; Stepanova, Marina I.; Matern, Anatoliy I.; Kozitsina, Alisa N. title: Electrochemical creatinine determination with metal-organic framework catalyst based on copper and acetylenedicarboxylic acid date: 2023-03-29 words: 3588 flesch: 50 summary: The most popular electrochemical catalysts used in electrochemical sensors are metal (platinum, gold, palla- dium, etc.) and carbon nanomaterials, metal–organic com- plexes. In the past, a lot of MOFs with different linkers and metal ions were synthesized and applied as sensing recep- tors in electrochemical sensors. keywords: creatinine; cuadca; cuadca@gce; determination; electrode; glucose; https://doi.org/10.15826/chimtech.2023.10.2.01; metal; sensors; synthesis; urea cache: chimtech-6378.pdf plain text: chimtech-6378.txt item: #254 of 303 id: chimtech-6396 author: Awad, Eman S.; Abdulla, Siraj M.; Sabirova, T. M.; Alsalhy, Qusay F. title: Membrane techniques for removal detergents and petroleum products from carwash effluents: a review date: 2023-01-11 words: 7888 flesch: 54 summary: The utilization of UF membranes are the main focus of membrane research in the carwash sector [45, 46]. Also, Tan and Tang clarified that it is preferable to utilize pre- treatment before UF membrane to prevent more con- taminants from adsorbing in pores. keywords: anionic; carwash; carwash wastewater; coagulation; cod; concentration; filtration; grease; membrane; ntu; oil; review; study; surfactant; treatment; turbidity; wastewater cache: chimtech-6396.pdf plain text: chimtech-6396.txt item: #255 of 303 id: chimtech-6411 author: Obydennov, Konstantin L.; Kalinina, Tatiana A.; Ryabova, Daria V.; Kosterina, Maria F.; Glukhareva, Tatiana V. title: 2-(4-Oxo-1,3-thiazolidin-2-ylidene)acetamid as promising scaffold for designing new antifungal compounds date: 2022-12-29 words: 4085 flesch: 67 summary: Introduction Derivatives of 1,3-thiazolidin-4-one with a double C=O, C=N, C=S, C=C exocyclic bond in position 2 of the hetero ring have a wide range of biological activity: antituberculo- sis 13С NMR spec- trum (100 MHz, DMSO-d6, δ, ppm: 31.45 (CH2); 42.49 (CH2N); 46.38 (CH2N); 94.32 (С-2’); 127.26 (C Ar); 127.90 (C Ar); 127.97 (C Ar); 128.75 (C Ar); 129.11 (C Ar); 135.56 (C Ar); 140.15 (C Ar); 152.47 (C-2), 166.53 (C=O), 173.21 (C=O). keywords: activity; c ar; chem; compounds; oxo-1,3; spectrum; synthesis; thiazolidin-2 cache: chimtech-6411.pdf plain text: chimtech-6411.txt item: #256 of 303 id: chimtech-6461 author: Putri, Yulia Eka; Wendari, Tio Putra; Arham, Restu Aulia; Muharmi, Melvi; Satria, Dedi; Rahmayeni, Rahmayeni; Wellia, Diana Vanda title: Optical response of SrTiO3 thin films grown via a sol-gel-hydrothermal method date: 2023-01-23 words: 4088 flesch: 61 summary: Keywords SrTiO3 thin film perovskite hydrothermal optical properties Received: 18.12.22 Revised: Thin films are currently employed in various fields to develop their capabilities keywords: films; gel; glass; glass substrate; layer; method; properties; samples; solution; srtio3; stof-75; substrate; tio2 cache: chimtech-6461.pdf plain text: chimtech-6461.txt item: #257 of 303 id: chimtech-6480 author: Yushkov, Anton A.; Kolosov, Vladimir Yu. title: The crystallization of thin Sb2Te films with vacuum annealing and an electron beam date: 2023-03-03 words: 3911 flesch: 54 summary: The crystallization of thin Sb2Te films with vacuum annealing and an electron beam published by Ural Federal University eISSN 2411-1414 chimicatechnoacta.ru ARTICLE 2023, vol. No. 202310111 DOI: 10.15826/chimtech.2023.10.1.11 1 of 7 The crystallization of thin Sb2Te films with vacuum annealing and an electron beam Anton A. Yushkov *, Vladimir Yu. keywords: annealing; beam; crystallization; doi:10.1016; electron; film; phase; sample; sb2te; temperature; thickness cache: chimtech-6480.pdf plain text: chimtech-6480.txt item: #258 of 303 id: chimtech-6537 author: Yadav, C. Kiran; Nandeshwarappa, B.P.; Mussuvir Pasha, K.M. title: Synthesis, computational study, solvatochromism and biological studies of thiazole-owing hydrazone derivatives date: 2023-02-20 words: 7174 flesch: 67 summary: 10(1), No. 202310110 ARTICLE 8 of 13 DOI: 10.15826/chimtech.2023.10.1.10 Table 3 Quantum chemical parameters calculated for synthesized compounds 5(a–h). 10(1), No. 202310110 ARTICLE 9 of 13 DOI: 10.15826/chimtech.2023.10.1.10 Table 4 Antimicrobial activity results of synthesized compounds 5(a–h). keywords: activity; arh; c =; chem; compounds; derivatives; dmso; doi:10.1016; figure; leu; n n; nmr; synthesis; thiazole; val cache: chimtech-6537.pdf plain text: chimtech-6537.txt item: #259 of 303 id: chimtech-6569 author: Abdulrahman, Sarah A.; Ibraheem, Salah S.; Shnain, Zainab Y. title: An overview of wastewater treatment using combined heterogeneous photocatalysis and membrane distillation date: 2023-03-22 words: 9417 flesch: 48 summary: New forms of photocatalytic membrane re- actors that combine photocatalysis with dialysis, pervapo- ration, and direct contact membrane distillation were re- ported [22]. Photocatalytic membrane for in situ enhanced removal of semi-volatile organic compounds in membrane distillation under visible light. keywords: band; chem; chemical; concentration; degradation; distillation; doi:10.1016; electron; eng; environ; light; membrane; membrane distillation; oxidation; photocatalyst; photocatalytic; pollutants; process; processes; reaction; reactors; removal; review; surface; tio2; treatment; wastewater cache: chimtech-6569.pdf plain text: chimtech-6569.txt item: #260 of 303 id: chimtech-6573 author: Kalyakin, Anatoly S.; Volkov, Alexander N. title: Electrochemical detection of simple alkanes by utilizing a solid-state zirconia-based gas sensor date: 2023-02-14 words: 3273 flesch: 56 summary: Shan K, Yi Z-Z, Yin X-T, Cui L, Dastan D, Garmestani H. Diffu- sion kinetics mechanism of oxygen ion in dense diffusion barrier limiting current oxygen sensors. Finally, Table 3 lists the experimental results for the propane – nitrogen gas mixtures. keywords: cm2; current; diffusion; gas; mixtures; sensor; s–1 cache: chimtech-6573.pdf plain text: chimtech-6573.txt item: #261 of 303 id: chimtech-6579 author: Markovskaya, Dina V.; Kozlova, Ekaterina A. title: Application of the similarity theory to analysis of photocatalytic hydrogen production and photocurrent generation date: 2023-04-04 words: 14892 flesch: 56 summary: 10(2), No. 202310203 DOI: 10.15826/chimtech.2023.10.2.03 1 of 21 Application of the similarity theory to analysis of photocatalytic hydrogen production and photocurrent generation Dina V. Markovskaya * , Ekaterina A. Kozlova Department of heterogeneous catalysis, Boreskov Institute of Catalysis, Novosibirsk 630090, Russia * However, these compounds are ac- tive co-catalysts for photocatalytic hydrogen production [8]. keywords: case; cds; cell; criterion; doi:10.1016; electrons; energy; evolution; generation; hydrogen; hydrogen evolution; hydrogen production; lamp; m na2s; na2so3; number; photocatalytic; photocatalytic hydrogen; photocurrent; photoelectrochemical; samples; similarity; ∙ 𝑁𝐴 cache: chimtech-6579.pdf plain text: chimtech-6579.txt item: #262 of 303 id: chimtech-6588 author: Khaliullina, Adelya S.; Meshcherskikh, Anastasia N.; Dunyushkina, Liliya A. title: Effect of Sn doping on sinterability and electrical conductivity of strontium hafnate date: 2023-03-17 words: 5224 flesch: 59 summary: Figure 6 Arrhenius plots of SrHfxSn1–xO3–δ conductivity in dry air. A schematic diagram of the fabrication of SrHfxSn1–xO3–δ samples is presented in Figure 1. keywords: conductivity; density; doi:10.1016; figure; hafnate; samples; solid; srhfxsn1; strontium; temperature; tin; xo3 cache: chimtech-6588.pdf plain text: chimtech-6588.txt item: #263 of 303 id: chimtech-6611 author: Kabouche, Zoubir; Belhocine, Youghourta; Benlecheb, Tahar; Assaba, Ibtissem Meriem; Litim, Abdelkarim; Lalalou, Rabab; Mechhoud, Asma title: A DFT-D4 investigation of the complexation phenomenon between pentachlorophenol and β-cyclodextrin date: 2023-04-28 words: 4616 flesch: 47 summary: A dispersion corrected DFT investigation of the inclu- sion complexation of dexamethasone with β-Cyclodextrin and molecular docking study of its potential activity against COVID-19. Inclusion complex formation of β-Cyclodextrin with the nonsteroidal anti-inflammatory drug flufenamic acid: computational study. keywords: chem; complexation; cyclodextrin; energy; figure; guest; host; inclusion; interactions; mol; pcp; pcp@β; pentachlorophenol; process cache: chimtech-6611.pdf plain text: chimtech-6611.txt item: #264 of 303 id: chimtech-6627 author: Fatykhov, Ramil F.; Khalymbadzha, Igor A.; Sharapov, Ainur D.; Potapova, Anastasia P.; Starnovskaya, Ekaterina S.; Kopchuk, Dmitry S.; Chupakhin, Oleg N. title: Expedient synthesis of 1,2,4-triazinyl substituted benzo[c]coumarins via double oxidation strategy date: 2023-04-11 words: 4941 flesch: 65 summary: This double aromatization strategy allowed us to extend the opportunities of SNH reactions in triazines providing stringboard access to 1,2,4-triazinyl substituted benzo[c]coumarins. J Med Chem. keywords: cdcl3; chem; coumarin; ddq; mhz; nmr; oxidation; synthesis; yield cache: chimtech-6627.pdf plain text: chimtech-6627.txt item: #265 of 303 id: chimtech-6664 author: Bykov, V. A.; Kovalenko, D. A.; Sterkhov, E. V.; Kulikova, T. V. title: Crystallization kinetics of GdYScAlCo high-entropy bulk metallic glass date: 2023-04-18 words: 5635 flesch: 52 summary: It should be noted that the Jeziorny’s method is often used to calculate the Avrami in- dex of non-isothermal crystallization kinetics of amorphous metallic glasses due to the developed algorithm for the in- terpretation of the polymer crystallization mechanism. Figure 2 Experimental DSC curves of GdYScAlCo amorphous alloy at different heating rates (inset: temperatures Tm, Tl for heating rate of 10 K/min). keywords: alloy; amorphous; crystallization; energy; figure; gdyscalco; glass; growth; heating; kinetics; method; nucleation; process; rate; temperature cache: chimtech-6664.pdf plain text: chimtech-6664.txt item: #266 of 303 id: chimtech-6670 author: Mukhacheva, Polina P.; Vatutina, Yuliya V.; Mik, Ivan A.; Nadeina, Ksenia A.; Kazakov, Maxim O.; Klenov, Oleg P.; Klimov, Oleg V.; Noskov, Aleksandr S. title: Testing conditions for CoMo HDS catalyst in the kinetic region: integrated approach using the math calculations and catalytic experiments date: 2023-04-24 words: 7411 flesch: 60 summary: Table 3 DBT conversion for catalyst fractions 0.1–0.25 Table 5 Effectiveness factor for catalyst fractions keywords: catalyst; catalytic; conditions; dbt; diffusion; doi:10.1016; effectiveness; factor; fraction; hydrotreating; influence; liquid; mass; reaction; reactor; temperature cache: chimtech-6670.pdf plain text: chimtech-6670.txt item: #267 of 303 id: chimtech-6675 author: Klyushnikov, Alexander M.; Pikalov, Sergey M.; Gulyaeva, Roza I. title: Kinetics of solid-state oxidation of iron, copper and zinc sulfide mixture date: 2023-03-30 words: 9683 flesch: 61 summary: Application of sulfide copper ores oxidizing roasting products as sulfidizing agent during melting nickel raw materials to matte. Klyushnikov A, Gulyaeva R, Pikalov S. Cold crystallization ki- netics of slag from the joint smelting of oxidized nickel and sulfide copper ores. keywords: acta; cobalt; copper; data; doi:10.1007; dsc; elementary; https://doi.org/10.15826/chimtech.2023.10.2.02; iron; kinetics; ore; oxidation; peaks; pyrite; reactions; roasting; sulfide; temperature; thermal; zinc cache: chimtech-6675.pdf plain text: chimtech-6675.txt item: #268 of 303 id: chimtech-6701 author: Bedarkova, Anzhelika; Tarasova, Nataliia; Animitsa, Irina; Abakumova, Ekaterina; Fedorova, Irina; Cheremisina, Polina; Verinkina, Evgenia title: Novel co-doped protonic conductors BaLa1.9Sr0.1In1.95M0.05O6.925 with layered perovskite structure date: 2023-04-11 words: 4212 flesch: 58 summary: 11.04.23 Key findings ● Cationic co-doping leads to an increase in proton conductivity of BaLa2In2O7 values of up to ~0.8 orders of magnitude. The possi- bility of proton conductivity in bilayer AA′2B2O7 perovskites such as on BaLa2In2O7 keywords: bala1.9sr0.1in1.95ca0.05o6.925; bala2in2o7; compositions; conductivity; doping; energy; figure; increase; layered; oxygen; perovskite; proton; values cache: chimtech-6701.pdf plain text: chimtech-6701.txt item: #269 of 303 id: chimtech-6705 author: Urakaev, Farit Kh.; Khan, Natalya V.; Niyazbayeva, Almagul I.; Zharlykasimova, Dinar N.; Burkitbayev, Mukhambetkali M. title: Mechanochemical recrystallization: Forgotten basics and new possibilities date: 2023-06-02 words: 5760 flesch: 52 summary: Method for producing sulfur nanoparticles from solutions in dimethyl sulphoxide, using solution of sulfur in dimethyl sul- foxide saturated at room temperature with specific sulfur concentration when diluted with water or acetone. The essence of this method is shown using the example of mechanical activation of the S–AgNO3–NH4X system, where X = Cl, Br, I, with the addition of dimethyl sulfoxide (DMSO), and the resulting mechano- chemical synthesis of sulfur-containing nanocomposites S/AgX with the controlled content of sulfur nanoparticles (nanosulfur). keywords: agi; content; dmso; figure; https://doi.org/10.15826/chimtech.2023.10.2.13; liquid; mechanochemical; method; nanocomposites; nanosulfur; phase; pulverisette; recrystallization; sulfur; synthesis; water cache: chimtech-6705.pdf plain text: chimtech-6705.txt item: #270 of 303 id: chimtech-6708 author: Nosova, Emiliya V.; Butorin, Ilya I.; Likhacheva, Margarita D.; Kotovskaya, Svetlana K. title: Synthesis and cytotoxic activity of (2-arylquinazolin-4-yl)hydrazones of 2-hydroxybenzaldehydes date: 2023-05-04 words: 6208 flesch: 65 summary: Protein kinase CK2 is a ubiquitous, highly conserved, and constitutively active serine/threonine pro- tein kinase; overexpression and hyperactivation of CK2 was observed in a wide variety of cancers, including breast, lung, prostate, colorectal, and renal Faust RA, Niehans G, Gapany M, Hoistad D, Knapp D, Cher- witz D, Davis A, Adams GL, Ahmed K. Subcellular immuno- localization of protein kinase CK2 in normal and carcinoma cells. keywords: activity; cells; ck2; compounds; docking; kinase; nmr; ppm; protein; synthesis cache: chimtech-6708.pdf plain text: chimtech-6708.txt item: #271 of 303 id: chimtech-6748 author: Yarkaeva, Yulia A.; Dymova, Daria A.; Nazyrov, Marat I.; Zagitova, Liana R.; Maistrenko, Valery N. title: Voltammetric sensor based on molecular imprinted polymer for lincomycin determination date: 2023-04-28 words: 5673 flesch: 56 summary: Figure 6 DPVs of Lin solutions of various concentrations (1 – 0.0025, 2 – 0.01, 3 – 0.03, 4 – 0.05, 5 – 0.1, 6 – 0.2, 7 – 0.3, 8 – 0.4, 9 – 0.5 mM) on GCE/rGO/miPAP (a); calibration curves of GCE (1), GCE/rGO (2), GCE/rGO/PAP (3) and GCE/rGO/miPAP (4) sensors (PBS, 20 mV s–1, n = 5, P = 0.95) (b). Lin detection Lin electrooxidation is a one-electron one-proton process with the formation of a dimerized product [6]. keywords: cm–1; detection; determination; doi:10.1016; electrochemical; electrode; figure; gce; https://doi.org/10.15826/chimtech.2023.10.2.10; lin; lincomycin; mipap; polymer; rgo; sensitivity; sensor; solution cache: chimtech-6748.pdf plain text: chimtech-6748.txt item: #272 of 303 id: chimtech-676 author: Kalinina, T. A.; Bystrykh, O. A.; Shakhmina, J. S.; Glukhareva, T. V.; Fan, Zhi-Jin; Morzherin, Yu. Yu. title: Synthesis and research of cis-trans isomerism for 5-(4-methoxybenzoyl)-6-(4-metoxyphenyl)-6,7-dihydro-5H-[1,2,3]triazolo[5,1-b][1,3,4]thiadiazine date: 2014-09-30 words: 1729 flesch: 95 summary: J. Fan, Ю. Ю. Моржерин 47 2014 | № 2 | CTA Синтез и исследование цис-транс-изомерии 5-(4-метоксибензоил)-6- (4-метоксифенил)-6,7-дигидро-5H-[1,2,3]триазоло[5,1-b][1,3,4]тиадиазина Таблица 1 Соотношение изомеров в спектрах ЯМР 1Н, снятых в разных растворителях при разных температурах Растворитель Температура, °С Отн. полярность растворителя, ЕT Отн. (J, Гц): Транс-изомер: 7.87 (2H, д, J = 8.9, ArH); 7.24 (2H, д, J = 8.7, ArH); 7.03 (1H, д, J = 3.5, NH); 6.91 (2H, д, J = = 8.9, ArH); 6.75 (2H, д, J = 8.7, ArH); 5.21 (1H, дд, J = 3.4, J = 3.5, C-(6) Т. А. Калинина, О. А. Быстрых, Ю. С. Шахмина, Т. В. Глухарева, Zh. keywords: arh; j =; och3 cache: chimtech-676.pdf plain text: chimtech-676.txt item: #273 of 303 id: chimtech-6763 author: Cheretaeva, Alisa O.; Glukhov, Pavel A.; Shafeev, Marat R.; Denisova, Alyona G.; Borgardt, Eugeny D.; Polunin, Anton V.; Katsman, Alexander V.; Krishtal, Mikhail M. title: Improvement of protective oxide layers formed by high-frequency plasma electrolytic oxidation on Mg-RE alloy with LPSO-phase date: 2023-05-29 words: 11034 flesch: 53 summary: Jangde A, Kumar S, Blawert C. Role of glycerine on formation & corrosion characteristic of PEO layer formed over Mg alloy in a high-concentrated mixed silicate-phosphate-based elec- trolyte. The use of electrolyte with addition of sodium silicate reduced the adhesive strength by 1.5 times and brought down the long-term corrosion resistance of oxide layers by an order of magnitude, as compared with the electrolyte with sodium aluminate. keywords: alloy; aluminate; coatings; composition; corrosion; current; doi:10.1016; effect; electrolyte; figure; formation; frequency; increase; layer; magnesium; oxidation; oxide; oxide layers; peo; phase; pulse; resistance; silicate; sodium; specimen cache: chimtech-6763.pdf plain text: chimtech-6763.txt item: #274 of 303 id: chimtech-679 author: Mikhailovskaya, Z. A.; Buyanova, E. S.; Petrova, S. A.; Zakharov, R. G. title: Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties date: 2014-06-30 words: 2013 flesch: 95 summary: Электропроводность образцов исследовали методом импедансной спектроскопии (импедансметр Elins Z-3000) в интервале температур 1123– 523 К. Замещенные молибдаты висмута на основе Bi 13 Mo 5 O 34±δ : Так, эффективное замеще- ние в подрешетке молибдена возможно в случае устойчивого тетраэдрического окружения, а замещение изолированно- го иона висмута – в случае стабильной координации с координационным чи- слом к. ч. keywords: iia; висмута; для; металлы; основе; при; температур; что cache: chimtech-679.pdf plain text: chimtech-679.txt item: #275 of 303 id: chimtech-680 author: Titov, A. G.; Gilvanova, Z. R.; Inyushkin, N. V.; Aitova, A. I.; Shhelchkov, I. P.; Tokareva, N. A.; Mankov, M. G.; Perfilov, S. A. title: Elektrocyclone hydrodynamic flow computation date: 2014-06-30 words: 1399 flesch: 99 summary: E-mail: paht@yandex.ru Расчет гидродинамики потока в электроциклоне* Для анализа гидродинамики потока в электроциклоне применен компью- терный расчет с использованием метода конечных элементов (МКЭ). Линии тока А. Г. Титов, З. Р. Гильванова, Н. В. Инюшкин, А. И. Аитова, И. П. Щелчков, Н. А. Токарева, М. Г. Маньков, С. А. Перфилов 25 2014 | № 1 | CTAРасчет гидродинамики потока в электроциклоне 1. keywords: потока; рис; электроциклона cache: chimtech-680.pdf plain text: chimtech-680.txt item: #276 of 303 id: chimtech-6802 author: Medvedev, Dmitry A. title: Editorial date: 2023-05-15 words: 1274 flesch: 52 summary: Another point consists in the support of the published items by visual facilities that have online journals. In high school, I actively participated in the city Olympiads in various subjects. keywords: chemistry; editorial; journal cache: chimtech-6802.pdf plain text: chimtech-6802.txt item: #277 of 303 id: chimtech-681 author: Vasin, A. A.; Zuev, M. G. title: Luminescent properties of complexly substituted oxides Ме2Ln8 (XO4)6O2 (Me=Sr, Ca; Ln=La, Gd, Eu; X= Si, P) date: 2014-06-30 words: 2213 flesch: 100 summary: Зависимости интегральной интенсивности люминесценции образцов от концентрации ионов заместителей (х): а – Ca2La8(1–x)Eu8xSi6O26; б – Ca2Eu8Si6(1–x)P6xO26; в – Sr2Gd7.2Eu0.8Si6(1–x)P6xO26 а б в 30 CTA | № 1 | 2014 трами возбуждения, поэтому механизм тушения, предложенный Декстером, также не реализуется. [1–3], посвященных соединениям типа AE2RE8(SiO4)6O2:Eu, где RE − ионы РЗЭ, такие как Y, Lu, La, Gd; AE − ионы щелочноземельных эле- ментов, например Ca, Sr, Ba, в которых приводится описание спектрально-лю- минесцентных свойств этих соедине- ний. keywords: x)p6xo26; были; для; образцов; при; рис cache: chimtech-681.pdf plain text: chimtech-681.txt item: #278 of 303 id: chimtech-6889 author: Akbayeva, Dina N.; Smagulova, Indira A.; Timurkyzy, Azhar; Bakirova, Botagoz S. title: Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity date: 2023-07-24 words: 3779 flesch: 54 summary: 10(3), No. 202310301 ARTICLE 2 of 6 DOI: 10.15826/chimtech.2023.10.3.01 Sodium bromate has been used for selective oxidation of vicinal diols to -hydroxy ketones, oxidation of alco- hols and alkyl arenes to the corresponding carbonyl compounds, and selective oxidation of sulfides to sulfox- ides Shaabani A, Farhangi E, Rahmati A. Ionic liquid promoted selective oxidation of organic compounds with NaBrO3. keywords: complex; complexes; figure; mmol; octene-1; oxidation; peg; polymer; pvp; reaction; solution; temperature cache: chimtech-6889.pdf plain text: chimtech-6889.txt item: #279 of 303 id: chimtech-6904 author: Meteleva, Elizaveta S.; Roenko, Elizaveta A.; Polyakov, Nikolay E. title: Increase of solubility and transmembrane permeability of niclosamide from its mechanochemically synthesized solid dispersions date: 2023-08-14 words: 6569 flesch: 58 summary: Content test The drug contents of NS SDs with CaCO3, (1/1 mass ratio) MG (1/1 mass ratio), MG (5/1 mass ratio) and HP-β-CD (1/1 molar ratio) were determined to be 100.0%, 100.0%, 96.7% and 100.0%, respectively. It suggests the prepara- tion of NS SDs by mechanochemichal processing was with high content uniformity. keywords: complex; compositions; drug; figure; formation; mass; molar; niclosamide; nmr; ratio; sds; solubility; solution cache: chimtech-6904.pdf plain text: chimtech-6904.txt item: #280 of 303 id: chimtech-6907 author: Timakova, Evgeniya V.; Timakova, Tatiana E.; Afonina, Liubov I. title: High purity β-Bi2O3 preparation by thermal decomposition of tartrates date: 2023-08-03 words: 5248 flesch: 58 summary: The hydrolytic precipita- tion of bismuth from nitric acid solution, as well as investiga- tion of solid precursor – carboxylic acid solution processes were carried out in fluoroplastic or glass vessels equipped with stirrers and thermostatically controlled in water baths. Therefore, it is of interest to consider the process of obtaining BiC4H3O6·H2O by treating solid bismuth precursors with tartaric acid solution. keywords: acid; bands; bic4h3o6; bismuth; bismuth(iii; cm–1; curve; figure; raman; samples; spectra; tartrate cache: chimtech-6907.pdf plain text: chimtech-6907.txt item: #281 of 303 id: chimtech-6915 author: Kenessova, Aruzhan K.; Rakhym, Akmaral B.; Zhaksybay, Bagashar B.; Seilkhanova, Gulziya A. title: The effect of ammonia activation on the desalination potential of natural zeolite date: 2023-08-04 words: 3284 flesch: 57 summary: ● NH4Cl modification alters zeolite's cation-exchange capacity, favoring enhanced Na+ and K+ ion adsorption for desalination. Various investiga- tions regarding saline water desalination by zeolites have been carried out. keywords: adsorption; desalination; doi:10.1016; ions; modification; na+; nh4cl; saline; water; zeolite cache: chimtech-6915.pdf plain text: chimtech-6915.txt item: #282 of 303 id: chimtech-6919 author: Sassykova, Larissa R.; Dossumova, Binara T.; Ilmuratova, Madina S.; Shakiyeva, Tatyana V.; Baizhomartov, Bedelzhan B.; Sassykova, Albina R.; Zhaxibayeva, Zhanar M.; Abildin, Tleutai S. title: Development of nanostructured catalysts for catalytic oxidative water purification from organic impurities, including phenolic compounds date: 2023-08-22 words: 4528 flesch: 53 summary: Catalytic activity of the magnetic nanocomposites with composition Fe3O4, CoFe2O4 and CoFe2O4/PEI was checked in the pro- cess of phenol oxidation (Cphenol = 0.003 mol/L). According to IR-spectroscopy, there was the presence of C=O bonds of the carbonyl group of benzoquinone and C–H and C–C bonds of the quinone ring in the products of phenol oxidation with oxygen. keywords: catalysts; cm–1; cobalt; cofe2o4; compounds; figure; iron; magnetic; nanoparticles; oxidation; oxygen; pei; phenol; properties; pvp; synthesis; water cache: chimtech-6919.pdf plain text: chimtech-6919.txt item: #283 of 303 id: chimtech-6921 author: Gainutdinov, Igor; Uvarov, Nikolay title: Molecular dynamic simulation of the [N(C4H9)4]BF4 / (110) α-Al2O3 interface date: 2023-08-16 words: 5324 flesch: 57 summary: As for composites with solid ionic salts, only LiI-Al2O3 The salt located in the [N4]BF4/(110)Al2O3 inter- face exhibits high values of anion self-diffusion coefficients which are higher by 1.2–2 orders of magnitude than in pure salt. keywords: al2o3; anions; atoms; chem; conductivity; cooling; interface; ionic; n4]bf4; phys; plastic; salt; state; structure; temperature cache: chimtech-6921.pdf plain text: chimtech-6921.txt item: #284 of 303 id: chimtech-6929 author: Petrova, Yuliya Yu.; Bulatova, Elena V.; Zelentsov, Dmitry O.; Mateyshina, Yuliya G. title: Hydrophilic molecularly imprinted phenol-amine-formaldehyde resins date: 2023-08-23 words: 4639 flesch: 55 summary: At the same time, the empirical coefficient β, which characterizes the adsorption of quercetin, is 1.5– 3.0 times higher for MIR samples than for NIR samples. Therefore, the following studies will be aimed at increasing the sorption capacity of MIR samples by optimizing the amount of poro- gen. keywords: doi:10.1016; formaldehyde; hydrophilic; imprinting; melamine; mir; molecularly; nir; pmf; pmfr; quercetin; resin; samples; sorption cache: chimtech-6929.pdf plain text: chimtech-6929.txt item: #285 of 303 id: chimtech-693 author: Kholkina, A. S.; Arkhipov, P. A.; Zaikov, Yu. P. title: Lead activity in Pb-Sb-Bi alloys date: 2014-06-30 words: 1454 flesch: 103 summary: Общий вид урав- нения можно представить следующим выражением: E = a+ b · T. Согласно полученным результатам, при одной и той же температуре с уменьшени- ем мольной доли свинца в тройном сплаве потенциал этого сплава от- носительно металлического свинца сдвигается в область положительных значений. % На основании экспериментальных данных рассчитали активность свинца в тройном сплаве (рис. 5–7). keywords: при; рис; свинца; сплаве cache: chimtech-693.pdf plain text: chimtech-693.txt item: #286 of 303 id: chimtech-6930 author: Popov, M. V.; Chudakova, M. V.; Kurmashov, P. B.; Bannov, A. G.; Kleimenov, A. V. title: Decomposition of light hydrocarbons on a Ni-containing glass fiber catalyst date: 2023-08-08 words: 3196 flesch: 52 summary: Figure 1 Appearance of glass fiber catalyst layer. The reaching of optimum activity of catalysts will be achieved by cre- ating new nanoparticle-based fiberglass systems with enhanced conversion of C1-C4 hydrocarbons. keywords: atm; carbon; catalyst; decomposition; fiber; gcat; glass; hydrogen; pressure; temperature cache: chimtech-6930.pdf plain text: chimtech-6930.txt item: #287 of 303 id: chimtech-695 author: Grishko, M. S.; Zhukovsky, M. S.; Beznosyuk, S. A. title: The study of self-assembly and self-organization of atomic metal nanoparticles of iron group by Monte Carlo method date: 2014-06-30 words: 2124 flesch: 98 summary: Из представленных графиков кине- тических кривых видно, что энергия нанокластера в модели квантово-запу- танного квазистационарного состояния составила около –320 кДж/моль, а в модели квантово-незапутанного ква- зистационарного состояния – около –220 кДж/моль. Направление и вероятность не- адиабатического квантового скачка ядер на фемтосекундных стадиях зада- на в модели стохастического Марков- ского процесса случайной генерацией направления скачка с последующей оценкой вероятности этого скачка по методу Монте-Карло. keywords: атомных; для; железа; карло; квантово; монте; наночастиц; при; самоорганизации; самосборки; что cache: chimtech-695.pdf plain text: chimtech-695.txt item: #288 of 303 id: chimtech-6956 author: Tran, Hai D.; Nguyen, Dinh Quan title: Study on methylene blue adsorption using cashew nut shell-based activated carbon date: 2023-08-07 words: 5337 flesch: 60 summary: ● The equilibrium of MB adsorption onto the CNS AC is in good agreement with the Freundlich and D-K isotherms. The analysis of isotherm and kinetic results revealed the na- ture of MB adsorption on the CNS AC. keywords: adsorbent; adsorption; blue; carbon; cns; cns ac; doi:10.1016; figure; isotherm; methylene; removal; solution; surface cache: chimtech-6956.pdf plain text: chimtech-6956.txt item: #289 of 303 id: chimtech-696 author: Mansurov, R. R.; Safronov, A. P.; Lakiza, N. V.; Leiman, D. V. title: Adsorption of TX-100 and SDBS on the surface of alumina and maghemite nanoparticles from aqueous solutions date: 2014-09-30 words: 1794 flesch: 97 summary: Мира, 19. Адсорбция TX-100 и SDBS на поверхности нанопорошков Al 2 O 3 и γ-Fe 2 O 3 из водных растворов* Методом УФ-спектрофотомерии были исследованы адсорбционные рав- новесия в водных наносуспензиях оксидов алюминия и железа, стабилизи- рованных SDBS и TX-100. и Al2O3 б – (РЭМ, Karl-ZeissLEO 982) Р. Р. Мансуров, А. П. Сафронов, Н. В. Лакиза, Д. В. Лейман 53 2014 | № 2 | CTA Адсорбция TX-100 и SDBS на поверхности нанопорошков Al 2 O 3 и γ-Fe 2 O 3 из водных растворов были получены калибровочные гра- фики, по которым, используя закон Бугера – Ламберта – Бера, определяли остаточную концентрацию ПАВ в на- носуспензиях оксидов металлов после адсорбции. keywords: sdbs; tx-100; водных; для; пав; поверхности cache: chimtech-696.pdf plain text: chimtech-696.txt item: #290 of 303 id: chimtech-6960 author: Zelentsov, Dmitry O.; Petrova, Yuliya Yu.; Korobkin, Alexander V.; Ivanova, Anastasia A.; Cheremisin, Alexey N.; Shanenkov, Ivan I.; Pak, Alexander Ya.; Mateyshina, Yuliya G. title: Influence of anionic surfactant on stability of nanoparticles in aqueous solutions date: 2023-07-27 words: 5288 flesch: 57 summary: Size distribution of nanoparticle aggregates by laser diffraction The particle size was evaluated with a SALD-2300 (Shi- madzu) analyzer for selection of oxide nanoparticles and study of surfactant influence on carbon nanoparticle aggre- gation. Here, a drop of liquid with lower density (n-hexane) was placed inside the denser fluid (surfactant or surfac- tant–nanoparticle solutions) in a horizontal tube. keywords: aggregates; aggregation; figure; mmol; nanoparticles; npts; oil; sds; size; solutions; surfactant; tio2; water cache: chimtech-6960.pdf plain text: chimtech-6960.txt item: #291 of 303 id: chimtech-6961 author: Fedorov, Nikita; Ulihin, Artem; Uvarov, Nikolai title: Synthesis and properties of polymer electrolytes based on polyurethane elastomer and lithium salts date: 2023-08-24 words: 3117 flesch: 53 summary: Ionic conductivity of polymer solid electrolytes occurs via flexible fragments that form an amorphous subsystem (so-called gel phase), whereas hard fragments form crys- talline regions of the polymer [3–7]. Polyurethane is a promising material as a matrix for creating solid polymer electrolytes. keywords: concentration; conductivity; dmso; electrolytes; libf4; lithium; polymer; salt; solutions; swelling cache: chimtech-6961.pdf plain text: chimtech-6961.txt item: #292 of 303 id: chimtech-699 author: Karpov, V. V.; Volkovich, V. A.; Polovov, I. B.; Rebrin, O. I. title: Determination of solubility of chlorides of d-elements in chloroaluminate melts date: 2014-09-30 words: 1669 flesch: 102 summary: Растворимость хлорида железа в хлоралюминатном расплаве опреде- ляется растворимостью двойных хло- ридов KFeCl3 и K2FeCl4, имеющих относительно высокие температуры плавления (399–406 и 374–380 °С со- ответственно). 2. Растворимость хлорида молибде- на в расплавах при соотношении K : keywords: kcl; никеля; при; расплавах; растворимость; состава; хлорида cache: chimtech-699.pdf plain text: chimtech-699.txt item: #293 of 303 id: chimtech-700 author: Gabov, A. L.; Belosludtsev, I. S.; Medvedeva, N. A.; Skryabina, N. E.; Fruchart, D. title: The influence of the magnesium alloys microstructure on the cathodic hydrogen evolution date: 2014-09-30 words: 1790 flesch: 99 summary: каче- стве добавок, например в сплав AZ31 (Al, Zn) и ZK60 (Zn) Микроструктура образцов магния и его сплавов в исходном состоянии: а – Mg; б – AZ31; в – ZK60 и после деформации РКУП при 200 °C, 1 проход: г – Mg; д – AZ31; е – ZK60 а б в г е д Исходный образец магния (рис. 2 а) keywords: az31; zk60; магния; при; рис; что cache: chimtech-700.pdf plain text: chimtech-700.txt item: #294 of 303 id: chimtech-7013 author: Ulitko, Maria; Antonets, Yulia; Antropova, Irina; Mullabaev, Albert; Volokitina, Elena; Kasyanova, Anna; Loginova, Ekaterina; Tarasova, Nataliia title: Ceramic materials based on lanthanum zirconate for the bone augmentation purposes: cytocompatibility in a cell culture model date: 2023-08-16 words: 3941 flesch: 48 summary: Doping ceramic materials can contribute to the process of osteogenesis and rapid bone healing [13, 14]. In this work, the cytocom- patibility of ceramic materials based on lanthanum zirconate (La2Zr2O7) was determined to assess the prospects for their use as implants and com- ponents of human joint endoprostheses. keywords: bone; cells; ceramic; control; cultivation; culture; fibroblasts; ions; lanthanum; materials; medium; samples; viability; zirconate cache: chimtech-7013.pdf plain text: chimtech-7013.txt item: #295 of 303 id: chimtech-715 author: Obydennov, K. L.; Golovko, N. A.; Morzherin, Yu. Yu. title: Synthesis of 2-(5-arylidene-4-oxo-3-arylthiazolydine-2)-N-phenylethanthiamides derivatives from malondithioamides date: 2014-09-30 words: 898 flesch: 90 summary: В спектрах ЯМР 1Н тиазолидино- нов 2a,b мы наблюдали уширенный сигнал NH группы в 10.66 и 10.90 м. два мак- симума поглощения: в области 300 и 330 нм (со слабой интенсивностью) keywords: chem cache: chimtech-715.pdf plain text: chimtech-715.txt item: #296 of 303 id: chimtech-716 author: Fedorova, E. A.; Bazanova, E. A.; Maskaeva, L. N.; Markov, V. F. title: Formation mechanism of SnS films by chemical bath deposition from aqueous solutions date: 2014-09-30 words: 1896 flesch: 100 summary: Исходя из физи- ко-химического содержания процес- са, можно предположить их активную роль и в дальнейшем формировании пленок. течение 5, 60 и 120 минут в герметичных стеклянных реакторах, в которые помещали подложки, закре- keywords: sns; водных; гидрохимическом; механизм; олова; осаждении; пленок; при; роста; фазы; формирования; что cache: chimtech-716.pdf plain text: chimtech-716.txt item: #297 of 303 id: chimtech-717 author: Tatarenko, K. V.; Suzdaltsev, A. V.; Khramov, A. P.; Zaikov, Yu. P. title: Anode process on platinum in CaCl2-CaO-based melt date: 2014-12-31 words: 1859 flesch: 97 summary: К. В. Татаренко, А. В. Суздальцев, А. П. Храмов, Ю. П. Зайков 89 2014 | № 3 | CTAАнодный процесс на платине в расплаве на основе CaCl 2 -CaO Результаты и обсуждение В ходе измерений была провере- на функция используемого электрода сравнения. + 4Ca 8 2,999 2,996 2,994 К. В. Татаренко, А. В. Суздальцев, А. П. Храмов, Ю. П. Зайков 91 2014 | № 3 | CTAАнодный процесс на платине в расплаве на основе CaCl 2 -CaO слорода или с образованием оксидной пленки на поверхности платины. keywords: cacl2; cao; кислорода; при; расплаве cache: chimtech-717.pdf plain text: chimtech-717.txt item: #298 of 303 id: chimtech-718 author: Bandin, A. E.; Zhukovsky, M. S.; Beznosyuk, S. A. title: Computer modeling of the mechanisms of melting metal nanoparticles of different shapes date: 2014-12-31 words: 1636 flesch: 98 summary: Для описания свойств наноча- стиц предложено уравнение: 1( ) exp ( 1)( 1) ( ) 3 m m r f d T T −  = − α − − ∞   , (3) где Tm(r) и Tm(∞) – температуры плав- ления (K) нанокристалла и компактно- го металла, соответственно; d – высота А. Е. Бандин, М. С. Жуковский, С. А. Безносюк 95 2014 | № 3 | CTA Компьютерное моделирование механизмов плавления наночастиц металлов различной формы монослоя атомов в кристаллической структуре; f – параметр, учитываю- щий форму наночастицы; α – отноше- ние среднеквадратичных смещений на поверхности и в объеме наночастицы (значение α в большинстве случаев ме- няется от 2 до 4). Доля повер- хностных атомов в сферических на- ночастицах размером 3 нм достигает приблизительно 50 %, и их колебания сильно влияют на критерий Линде- мана. keywords: атомов; для; железа; конуса; наночастиц; плавления; размера; сферы; температуры; формы; цилиндра; частицы; что cache: chimtech-718.pdf plain text: chimtech-718.txt item: #299 of 303 id: chimtech-719 author: Forostyanaya, N. A.; Polepishina, A. O.; Markov, V. F.; Maskaeva, L. N. title: Preparation of CdS-PbS solid solutions thin films by modifying of the cadmium sulfide film surface when it exposed to an aqueous solution of lead salt date: 2014-12-31 words: 1849 flesch: 96 summary: Продолжительность выдержки син- тезированных слоев CdS в водном рас- творе 2 показаны электронно-ми- кроскопические изображения повер- хности пленок CdS (а), PbS (б) и CdS, выдержанных в водном растворе аце- тата свинца Pb(CH3COO)2 при макси- мальной из используемых температур − 368 K. Продолжительность выдержки пленки сульфида кадмия в растворе ацетата свинца составила 60 минут (в) keywords: cds; pbs; для; кадмия; пленки; пленок; при; растворе; растворов; свинца; соли; сульфида cache: chimtech-719.pdf plain text: chimtech-719.txt item: #300 of 303 id: chimtech-720 author: Demina, E. G.; Darintseva, A. B.; Murashova, I. B. title: Electrochemical copper extraction from sulphate electrolyte date: 2014-12-31 words: 2064 flesch: 96 summary: В результате опытов удалось снизить концентрацию меди в растворе до 1 г/л через 2 часа элек- тролиза; на катоде уменьшением концентрации ее в объеме VΣ: keywords: copper; меди; обезмеживания; осадка; при; рис; электролита cache: chimtech-720.pdf plain text: chimtech-720.txt item: #301 of 303 id: chimtech-722 author: Jagovcev, A. V.; Obabkov, N. V. title: Interaction of ZG-refractory with mold flux and ambient air date: 2014-12-31 words: 1487 flesch: 98 summary: На лабораторном прессе прессо- вали образцы в виде цилиндров с ди- аметром 50 мм. +1 +1 +1 +1 – 1 –1 9 +1 –1 –1 – 1 +1 – 1 10 +1 +1 –1 – 1 +1 +1 11 +1 –1 +1 – 1 +1 +1 12 keywords: +1 +1; бора; карбида; образцы; состав cache: chimtech-722.pdf plain text: chimtech-722.txt item: #302 of 303 id: chimtech-729 author: Ivanova, E. A.; Glukhareva, T. V.; Morzherin, Yu. Yu. title: The synthesis and alkylation of p-tetrakischloro-calix[4]arene date: 2014-06-30 words: 2182 flesch: 102 summary: Например, в области ароматических протонов присутствует двухпротонные синглет при 7,53 м.д., синглет при 7,07 м.д. данные, в процентах 560 (М) 100 100 562 (М+2) keywords: ммоль; натрия; при; что; ямр cache: chimtech-729.pdf plain text: chimtech-729.txt item: #303 of 303 id: chimtech-790 author: Volodina, N. S.; Terziyan, T. V.; Safronov, A. P.; Petrov, A. V. title: Thermodynamics of disaggregated polymer composites based on nanosized powders of Ni and NiO date: 2015-03-29 words: 3484 flesch: 76 summary: на основе нанодисперсных порошков Ni и NiO 11 № 1 | 2015 Chimica Techno Acta поверхности металлических частиц Ni. основе нанодисперсных порошков Ni и NiO 15 № 1 | 2015 Chimica Techno Acta полимера и l0 – характерная толщина адгезионного стеклообразного слоя). keywords: composites; enthalpy; interaction; nickel; nio; polymer; surface; взаимодействия; для; композиций; никеля; энтальпии cache: chimtech-790.pdf plain text: chimtech-790.txt