id	sid	tid	token	lemma	pos
ecletica-511	1	1	a07v28n1.pdf	a07v28n1.pdf	PROPN
ecletica-511	1	2	55	55	NUM
ecletica-511	1	3	about	about	ADP
ecletica-511	1	4	the	the	DET
ecletica-511	1	5	kinetics	kinetic	NOUN
ecletica-511	1	6	and	and	CCONJ
ecletica-511	1	7	mechanism	mechanism	NOUN
ecletica-511	1	8	of	of	ADP
ecletica-511	1	9	the	the	DET
ecletica-511	1	10	reactions	reaction	NOUN
ecletica-511	1	11	of	of	ADP
ecletica-511	1	12	4-(2	4-(2	PROPN
ecletica-511	1	13	-	-	PUNCT
ecletica-511	1	14	pyridylazo)-resorcinol	pyridylazo)-resorcinol	NOUN
ecletica-511	1	15	,	,	PUNCT
ecletica-511	1	16	with	with	ADP
ecletica-511	1	17	zn2	zn2	PROPN
ecletica-511	1	18	+	+	PROPN
ecletica-511	1	19	,	,	PUNCT
ecletica-511	1	20	cu2	cu2	NOUN
ecletica-511	1	21	+	+	X
ecletica-511	1	22	and	and	CCONJ
ecletica-511	1	23	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	1	24	+	+	CCONJ
ecletica-511	1	25	equimolar	equimolar	ADJ
ecletica-511	1	26	mixtures	mixture	NOUN
ecletica-511	1	27	,	,	PUNCT
ecletica-511	1	28	in	in	ADP
ecletica-511	1	29	aqueous	aqueous	ADJ
ecletica-511	1	30	solutions	solution	NOUN
ecletica-511	1	31	a.	a.	NOUN
ecletica-511	1	32	v.	v.	PROPN
ecletica-511	1	33	rossi1	rossi1	PROPN
ecletica-511	1	34	;	;	PUNCT
ecletica-511	1	35	m.	m.	NOUN
ecletica-511	1	36	tubino1	tubino1	PROPN
ecletica-511	1	37	1	1	NUM
ecletica-511	1	38	instituto	instituto	PROPN
ecletica-511	1	39	de	de	PROPN
ecletica-511	1	40	química	química	PROPN
ecletica-511	1	41	universidade	universidade	PROPN
ecletica-511	1	42	estadual	estadual	PROPN
ecletica-511	1	43	de	de	PROPN
ecletica-511	1	44	campinas	campinas	PROPN
ecletica-511	1	45	–	–	PUNCT
ecletica-511	1	46	unicamp	unicamp	NOUN
ecletica-511	1	47	-13084	-13084	NOUN
ecletica-511	1	48	-	-	PUNCT
ecletica-511	1	49	971	971	NUM
ecletica-511	1	50	campinas	campina	NOUN
ecletica-511	1	51	–	–	PUNCT
ecletica-511	1	52	sp	sp	ADP
ecletica-511	1	53	–	–	PUNCT
ecletica-511	1	54	brasil	brasil	NOUN
ecletica-511	1	55	introduction	introduction	NOUN
ecletica-511	1	56	since	since	SCONJ
ecletica-511	1	57	1960	1960	NUM
ecletica-511	1	58	,	,	PUNCT
ecletica-511	1	59	derivatives	derivative	NOUN
ecletica-511	1	60	of	of	ADP
ecletica-511	1	61	2	2	NUM
ecletica-511	1	62	-	-	PUNCT
ecletica-511	1	63	pyridylazo	pyridylazo	NOUN
ecletica-511	1	64	have	have	AUX
ecletica-511	1	65	been	be	AUX
ecletica-511	1	66	extensively	extensively	ADV
ecletica-511	1	67	studied	study	VERB
ecletica-511	1	68	for	for	ADP
ecletica-511	1	69	analytical	analytical	ADJ
ecletica-511	1	70	purposes	purpose	NOUN
ecletica-511	1	71	.	.	PUNCT
ecletica-511	2	1	a	a	DET
ecletica-511	2	2	very	very	ADV
ecletica-511	2	3	important	important	ADJ
ecletica-511	2	4	example	example	NOUN
ecletica-511	2	5	is	be	AUX
ecletica-511	2	6	4-(2pyridylazo)-resorcinol	4-(2pyridylazo)-resorcinol	NOUN
ecletica-511	2	7	,	,	PUNCT
ecletica-511	2	8	par	par	NOUN
ecletica-511	2	9	.	.	PUNCT
ecletica-511	3	1	this	this	PRON
ecletica-511	3	2	is	be	AUX
ecletica-511	3	3	an	an	DET
ecletica-511	3	4	excellent	excellent	ADJ
ecletica-511	3	5	metallochromic	metallochromic	ADJ
ecletica-511	3	6	indicator	indicator	NOUN
ecletica-511	3	7	and	and	CCONJ
ecletica-511	3	8	also	also	ADV
ecletica-511	3	9	very	very	ADV
ecletica-511	3	10	useful	useful	ADJ
ecletica-511	3	11	as	as	ADP
ecletica-511	3	12	a	a	DET
ecletica-511	3	13	chromogenic	chromogenic	ADJ
ecletica-511	3	14	agent	agent	NOUN
ecletica-511	3	15	for	for	ADP
ecletica-511	3	16	the	the	DET
ecletica-511	3	17	quantitative	quantitative	ADJ
ecletica-511	3	18	determination	determination	NOUN
ecletica-511	3	19	of	of	ADP
ecletica-511	3	20	over	over	ADP
ecletica-511	3	21	50	50	NUM
ecletica-511	3	22	elements	element	NOUN
ecletica-511	3	23	,	,	PUNCT
ecletica-511	3	24	including	include	VERB
ecletica-511	3	25	at	at	ADP
ecletica-511	3	26	trace	trace	NOUN
ecletica-511	3	27	levels	level	NOUN
ecletica-511	3	28	[	[	X
ecletica-511	3	29	10	10	NUM
ecletica-511	3	30	]	]	PUNCT
ecletica-511	3	31	.	.	PUNCT
ecletica-511	4	1	par	par	PROPN
ecletica-511	4	2	,	,	PUNCT
ecletica-511	4	3	c11h9n3o2	c11h9n3o2	NOUN
ecletica-511	4	4	,	,	PUNCT
ecletica-511	4	5	is	be	AUX
ecletica-511	4	6	commercially	commercially	ADV
ecletica-511	4	7	available	available	ADJ
ecletica-511	4	8	as	as	ADP
ecletica-511	4	9	the	the	DET
ecletica-511	4	10	free	free	ADJ
ecletica-511	4	11	dye	dye	NOUN
ecletica-511	4	12	in	in	ADP
ecletica-511	4	13	the	the	DET
ecletica-511	4	14	protonated	protonate	VERB
ecletica-511	4	15	form	form	NOUN
ecletica-511	4	16	(	(	PUNCT
ecletica-511	4	17	represented	represent	VERB
ecletica-511	4	18	as	as	ADP
ecletica-511	4	19	h2l	h2l	NOUN
ecletica-511	4	20	)	)	PUNCT
ecletica-511	4	21	or	or	CCONJ
ecletica-511	4	22	as	as	ADP
ecletica-511	4	23	the	the	DET
ecletica-511	4	24	monosodium	monosodium	NOUN
ecletica-511	4	25	(	(	PUNCT
ecletica-511	4	26	nahl.h2o	nahl.h2o	NOUN
ecletica-511	4	27	)	)	PUNCT
ecletica-511	4	28	or	or	CCONJ
ecletica-511	4	29	disodium	disodium	NOUN
ecletica-511	4	30	salt	salt	NOUN
ecletica-511	4	31	(	(	PUNCT
ecletica-511	4	32	na2l.2h2o	na2l.2h2o	PROPN
ecletica-511	4	33	)	)	PUNCT
ecletica-511	4	34	.	.	PUNCT
ecletica-511	5	1	the	the	DET
ecletica-511	5	2	sequence	sequence	NOUN
ecletica-511	5	3	shows	show	VERB
ecletica-511	5	4	the	the	DET
ecletica-511	5	5	proton	proton	NOUN
ecletica-511	5	6	dissociation	dissociation	NOUN
ecletica-511	5	7	scheme	scheme	NOUN
ecletica-511	5	8	of	of	ADP
ecletica-511	5	9	par	par	NOUN
ecletica-511	5	10	in	in	ADP
ecletica-511	5	11	aqueous	aqueous	ADJ
ecletica-511	5	12	solution	solution	NOUN
ecletica-511	5	13	.	.	PUNCT
ecletica-511	6	1	the	the	DET
ecletica-511	6	2	dissociation	dissociation	NOUN
ecletica-511	6	3	constant	constant	ADJ
ecletica-511	6	4	are	be	AUX
ecletica-511	6	5	pk1	pk1	NOUN
ecletica-511	6	6	(	(	PUNCT
ecletica-511	6	7	n+h	n+h	NUM
ecletica-511	6	8	)	)	PUNCT
ecletica-511	6	9	=	=	SYM
ecletica-511	6	10	3.1	3.1	NUM
ecletica-511	6	11	,	,	PUNCT
ecletica-511	6	12	pk2	pk2	PROPN
ecletica-511	6	13	(	(	PUNCT
ecletica-511	6	14	p	p	NOUN
ecletica-511	6	15	-	-	PUNCT
ecletica-511	6	16	oh	oh	NOUN
ecletica-511	6	17	)	)	PUNCT
ecletica-511	6	18	=	=	SYM
ecletica-511	6	19	5.6	5.6	NUM
ecletica-511	6	20	and	and	CCONJ
ecletica-511	6	21	pk3	pk3	NOUN
ecletica-511	6	22	(	(	PUNCT
ecletica-511	6	23	o	o	NOUN
ecletica-511	6	24	-	-	NOUN
ecletica-511	6	25	oh	oh	INTJ
ecletica-511	6	26	)	)	PUNCT
ecletica-511	6	27	=	=	NOUN
ecletica-511	7	1	11.9	11.9	NUM
ecletica-511	7	2	.	.	PUNCT
ecletica-511	8	1	two	two	NUM
ecletica-511	8	2	protonated	protonate	VERB
ecletica-511	8	3	species	specie	NOUN
ecletica-511	8	4	,	,	PUNCT
ecletica-511	8	5	h4l2	h4l2	PROPN
ecletica-511	8	6	+	+	CCONJ
ecletica-511	8	7	and	and	CCONJ
ecletica-511	8	8	h5l3	h5l3	X
ecletica-511	8	9	+	+	PROPN
ecletica-511	8	10	,	,	PUNCT
ecletica-511	8	11	can	can	AUX
ecletica-511	8	12	exist	exist	VERB
ecletica-511	8	13	in	in	ADP
ecletica-511	8	14	50	50	NUM
ecletica-511	8	15	and	and	CCONJ
ecletica-511	8	16	90	90	NUM
ecletica-511	8	17	%	%	NOUN
ecletica-511	8	18	sulfuric	sulfuric	NOUN
ecletica-511	8	19	acid	acid	NOUN
ecletica-511	8	20	solution	solution	NOUN
ecletica-511	8	21	respectively	respectively	ADV
ecletica-511	8	22	[	[	X
ecletica-511	8	23	10,1	10,1	NUM
ecletica-511	8	24	]	]	PUNCT
ecletica-511	8	25	.	.	PUNCT
ecletica-511	9	1	par	par	PROPN
ecletica-511	9	2	behaves	behave	VERB
ecletica-511	9	3	as	as	ADP
ecletica-511	9	4	a	a	DET
ecletica-511	9	5	terdentate	terdentate	NOUN
ecletica-511	9	6	or	or	CCONJ
ecletica-511	9	7	a	a	DET
ecletica-511	9	8	bidentate	bidentate	ADJ
ecletica-511	9	9	ligand	ligand	NOUN
ecletica-511	9	10	to	to	PART
ecletica-511	9	11	form	form	VERB
ecletica-511	9	12	soluble	soluble	ADJ
ecletica-511	9	13	or	or	CCONJ
ecletica-511	9	14	insoluble	insoluble	ADJ
ecletica-511	9	15	colored	colored	ADJ
ecletica-511	9	16	complexes	complex	NOUN
ecletica-511	9	17	with	with	ADP
ecletica-511	9	18	cations	cation	NOUN
ecletica-511	9	19	of	of	ADP
ecletica-511	9	20	mg	mg	PROPN
ecletica-511	9	21	,	,	PUNCT
ecletica-511	9	22	al	al	PROPN
ecletica-511	9	23	,	,	PUNCT
ecletica-511	9	24	ca	ca	PROPN
ecletica-511	9	25	,	,	PUNCT
ecletica-511	9	26	sr	sr	PROPN
ecletica-511	9	27	,	,	PUNCT
ecletica-511	9	28	ba	ba	PROPN
ecletica-511	9	29	,	,	PUNCT
ecletica-511	9	30	sc	sc	PROPN
ecletica-511	9	31	,	,	PUNCT
ecletica-511	9	32	ti	ti	NOUN
ecletica-511	9	33	,	,	PUNCT
ecletica-511	9	34	v	v	NOUN
ecletica-511	9	35	,	,	PUNCT
ecletica-511	9	36	cr	cr	PROPN
ecletica-511	9	37	,	,	PUNCT
ecletica-511	9	38	mn	mn	PROPN
ecletica-511	9	39	,	,	PUNCT
ecletica-511	9	40	fe	fe	X
ecletica-511	9	41	,	,	PUNCT
ecletica-511	9	42	co	co	NOUN
ecletica-511	9	43	,	,	PUNCT
ecletica-511	9	44	ni	ni	PROPN
ecletica-511	9	45	,	,	PUNCT
ecletica-511	9	46	cu	cu	PROPN
ecletica-511	9	47	,	,	PUNCT
ecletica-511	9	48	zn	zn	PROPN
ecletica-511	9	49	,	,	PUNCT
ecletica-511	9	50	ga	ga	PROPN
ecletica-511	9	51	,	,	PUNCT
ecletica-511	9	52	y	y	PROPN
ecletica-511	9	53	,	,	PUNCT
ecletica-511	9	54	zr	zr	PROPN
ecletica-511	9	55	,	,	PUNCT
ecletica-511	9	56	nb	nb	PROPN
ecletica-511	9	57	,	,	PUNCT
ecletica-511	9	58	ru	ru	PROPN
ecletica-511	9	59	,	,	PUNCT
ecletica-511	9	60	rh	rh	PROPN
ecletica-511	9	61	,	,	PUNCT
ecletica-511	9	62	pd	pd	PROPN
ecletica-511	9	63	,	,	PUNCT
ecletica-511	9	64	ag	ag	PROPN
ecletica-511	9	65	,	,	PUNCT
ecletica-511	9	66	cd	cd	PROPN
ecletica-511	9	67	,	,	PUNCT
ecletica-511	9	68	in	in	ADP
ecletica-511	9	69	,	,	PUNCT
ecletica-511	9	70	sn	sn	INTJ
ecletica-511	9	71	,	,	PUNCT
ecletica-511	9	72	hf	hf	INTJ
ecletica-511	9	73	,	,	PUNCT
ecletica-511	9	74	ta	ta	PROPN
ecletica-511	9	75	,	,	PUNCT
ecletica-511	9	76	os	os	PROPN
ecletica-511	9	77	,	,	PUNCT
ecletica-511	9	78	ir	ir	PROPN
ecletica-511	9	79	,	,	PUNCT
ecletica-511	9	80	pt	pt	PROPN
ecletica-511	9	81	,	,	PUNCT
ecletica-511	9	82	au	au	ADP
ecletica-511	9	83	,	,	PUNCT
ecletica-511	9	84	hg	hg	NOUN
ecletica-511	9	85	,	,	PUNCT
ecletica-511	9	86	tl	tl	PROPN
ecletica-511	9	87	,	,	PUNCT
ecletica-511	9	88	pb	pb	PROPN
ecletica-511	9	89	,	,	PUNCT
ecletica-511	9	90	bi	bi	NOUN
ecletica-511	9	91	,	,	PUNCT
ecletica-511	9	92	th	th	X
ecletica-511	9	93	,	,	PUNCT
ecletica-511	9	94	u	u	NOUN
ecletica-511	9	95	,	,	PUNCT
ecletica-511	9	96	np	np	INTJ
ecletica-511	9	97	and	and	CCONJ
ecletica-511	9	98	the	the	DET
ecletica-511	9	99	lanthanides	lanthanide	NOUN
ecletica-511	9	100	at	at	ADP
ecletica-511	9	101	specific	specific	ADJ
ecletica-511	9	102	ph	ph	ADJ
ecletica-511	9	103	values	value	NOUN
ecletica-511	9	104	.	.	PUNCT
ecletica-511	10	1	the	the	DET
ecletica-511	10	2	cu2	cu2	NOUN
ecletica-511	10	3	+	+	X
ecletica-511	10	4	complex	complex	NOUN
ecletica-511	10	5	is	be	AUX
ecletica-511	10	6	formed	form	VERB
ecletica-511	10	7	at	at	ADP
ecletica-511	10	8	ph	ph	ADJ
ecletica-511	10	9	values	value	NOUN
ecletica-511	10	10	higher	high	ADJ
ecletica-511	10	11	than	than	ADP
ecletica-511	10	12	5	5	NUM
ecletica-511	10	13	and	and	CCONJ
ecletica-511	10	14	the	the	DET
ecletica-511	10	15	complex	complex	NOUN
ecletica-511	10	16	with	with	ADP
ecletica-511	10	17	zn2	zn2	PROPN
ecletica-511	10	18	+	+	X
ecletica-511	10	19	is	be	AUX
ecletica-511	10	20	formed	form	VERB
ecletica-511	10	21	at	at	ADP
ecletica-511	10	22	ph	ph	ADJ
ecletica-511	10	23	values	value	NOUN
ecletica-511	10	24	higher	high	ADJ
ecletica-511	10	25	than	than	ADP
ecletica-511	10	26	8	8	NUM
ecletica-511	10	27	.	.	PUNCT
ecletica-511	11	1	most	most	ADJ
ecletica-511	11	2	par	par	NOUN
ecletica-511	11	3	complexes	complex	NOUN
ecletica-511	11	4	are	be	AUX
ecletica-511	11	5	red	red	ADJ
ecletica-511	11	6	or	or	CCONJ
ecletica-511	11	7	red	red	ADJ
ecletica-511	11	8	-	-	PUNCT
ecletica-511	11	9	violet	violet	NOUN
ecletica-511	11	10	and	and	CCONJ
ecletica-511	11	11	,	,	PUNCT
ecletica-511	11	12	in	in	ADP
ecletica-511	11	13	some	some	DET
ecletica-511	11	14	cases	case	NOUN
ecletica-511	11	15	,	,	PUNCT
ecletica-511	11	16	the	the	DET
ecletica-511	11	17	color	color	NOUN
ecletica-511	11	18	changes	change	VERB
ecletica-511	11	19	with	with	ADP
ecletica-511	11	20	ph	ph	NOUN
ecletica-511	11	21	[	[	PUNCT
ecletica-511	11	22	10	10	NUM
ecletica-511	11	23	]	]	PUNCT
ecletica-511	11	24	.	.	PUNCT
ecletica-511	12	1	in	in	ADP
ecletica-511	12	2	the	the	DET
ecletica-511	12	3	case	case	NOUN
ecletica-511	12	4	of	of	ADP
ecletica-511	12	5	divalent	divalent	ADJ
ecletica-511	12	6	cations	cation	NOUN
ecletica-511	12	7	,	,	PUNCT
ecletica-511	12	8	the	the	DET
ecletica-511	12	9	complex	complex	NOUN
ecletica-511	12	10	formed	form	VERB
ecletica-511	12	11	is	be	AUX
ecletica-511	12	12	uncharged	uncharged	ADJ
ecletica-511	12	13	,	,	PUNCT
ecletica-511	12	14	coordination	coordination	NOUN
ecletica-511	12	15	-	-	PUNCT
ecletica-511	12	16	saturated	saturate	VERB
ecletica-511	12	17	[	[	X
ecletica-511	12	18	10	10	NUM
ecletica-511	12	19	]	]	PUNCT
ecletica-511	12	20	,	,	PUNCT
ecletica-511	12	21	with	with	ADP
ecletica-511	12	22	a	a	DET
ecletica-511	12	23	cation	cation	NOUN
ecletica-511	12	24	to	to	PART
ecletica-511	12	25	ligand	ligand	VERB
ecletica-511	12	26	ratio	ratio	NOUN
ecletica-511	12	27	equal	equal	ADJ
ecletica-511	12	28	to	to	ADP
ecletica-511	12	29	1:2	1:2	NUM
ecletica-511	12	30	,	,	PUNCT
ecletica-511	12	31	m(hl)2(2	m(hl)2(2	PROPN
ecletica-511	12	32	)	)	PUNCT
ecletica-511	12	33	.	.	PUNCT
ecletica-511	13	1	for	for	ADP
ecletica-511	13	2	complexes	complex	NOUN
ecletica-511	13	3	of	of	ADP
ecletica-511	13	4	par	par	NOUN
ecletica-511	13	5	with	with	ADP
ecletica-511	13	6	cu2	cu2	NOUN
ecletica-511	13	7	+	+	NUM
ecletica-511	13	8	and	and	CCONJ
ecletica-511	13	9	zn2	zn2	X
ecletica-511	13	10	+	+	PROPN
ecletica-511	13	11	,	,	PUNCT
ecletica-511	13	12	in	in	ADP
ecletica-511	13	13	aqueous	aqueous	ADJ
ecletica-511	13	14	solution	solution	NOUN
ecletica-511	13	15	at	at	ADP
ecletica-511	13	16	25	25	NUM
ecletica-511	13	17	°	°	NOUN
ecletica-511	13	18	c	c	NOUN
ecletica-511	13	19	,	,	PUNCT
ecletica-511	13	20	with	with	ADP
ecletica-511	13	21	ionic	ionic	ADJ
ecletica-511	13	22	abstract	abstract	NOUN
ecletica-511	13	23	the	the	DET
ecletica-511	13	24	kinetics	kinetic	NOUN
ecletica-511	13	25	and	and	CCONJ
ecletica-511	13	26	mechanism	mechanism	NOUN
ecletica-511	13	27	of	of	ADP
ecletica-511	13	28	the	the	DET
ecletica-511	13	29	reactions	reaction	NOUN
ecletica-511	13	30	between	between	ADP
ecletica-511	13	31	4-(2	4-(2	PROPN
ecletica-511	13	32	-	-	PUNCT
ecletica-511	13	33	pyridylazo)-resorcinol	pyridylazo)-resorcinol	PROPN
ecletica-511	13	34	and	and	CCONJ
ecletica-511	13	35	zn2	zn2	NOUN
ecletica-511	13	36	+	+	PROPN
ecletica-511	13	37	,	,	PUNCT
ecletica-511	13	38	cu2	cu2	NOUN
ecletica-511	13	39	+	+	X
ecletica-511	13	40	and	and	CCONJ
ecletica-511	13	41	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	13	42	+	+	CCONJ
ecletica-511	13	43	equimolar	equimolar	ADJ
ecletica-511	13	44	mixtures	mixture	NOUN
ecletica-511	13	45	were	be	AUX
ecletica-511	13	46	studied	study	VERB
ecletica-511	13	47	.	.	PUNCT
ecletica-511	14	1	the	the	DET
ecletica-511	14	2	reactions	reaction	NOUN
ecletica-511	14	3	were	be	AUX
ecletica-511	14	4	performed	perform	VERB
ecletica-511	14	5	in	in	ADP
ecletica-511	14	6	aqueous	aqueous	ADJ
ecletica-511	14	7	solution	solution	NOUN
ecletica-511	14	8	(	(	PUNCT
ecletica-511	14	9	ph	ph	NOUN
ecletica-511	14	10	=	=	SYM
ecletica-511	14	11	8.5	8.5	NUM
ecletica-511	14	12	,	,	PUNCT
ecletica-511	14	13	borate	borate	NOUN
ecletica-511	14	14	buffer	buffer	NOUN
ecletica-511	14	15	)	)	PUNCT
ecletica-511	14	16	and	and	CCONJ
ecletica-511	14	17	monitored	monitor	VERB
ecletica-511	14	18	spectrophotometrically	spectrophotometrically	ADV
ecletica-511	14	19	at	at	ADP
ecletica-511	14	20	500	500	NUM
ecletica-511	14	21	nm	nm	NOUN
ecletica-511	14	22	using	use	VERB
ecletica-511	14	23	stopped	stop	VERB
ecletica-511	14	24	-	-	PUNCT
ecletica-511	14	25	flow	flow	NOUN
ecletica-511	14	26	technique	technique	NOUN
ecletica-511	14	27	.	.	PUNCT
ecletica-511	15	1	spectral	spectral	ADJ
ecletica-511	15	2	and	and	CCONJ
ecletica-511	15	3	kinetic	kinetic	ADJ
ecletica-511	15	4	data	datum	NOUN
ecletica-511	15	5	indicate	indicate	VERB
ecletica-511	15	6	that	that	SCONJ
ecletica-511	15	7	the	the	DET
ecletica-511	15	8	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	15	9	+	+	NOUN
ecletica-511	15	10	equimolar	equimolar	ADJ
ecletica-511	15	11	mixture	mixture	NOUN
ecletica-511	15	12	behaves	behave	VERB
ecletica-511	15	13	as	as	ADP
ecletica-511	15	14	an	an	DET
ecletica-511	15	15	unique	unique	ADJ
ecletica-511	15	16	species	specie	NOUN
ecletica-511	15	17	and	and	CCONJ
ecletica-511	15	18	it	it	PRON
ecletica-511	15	19	can	can	AUX
ecletica-511	15	20	be	be	AUX
ecletica-511	15	21	attributed	attribute	VERB
ecletica-511	15	22	to	to	ADP
ecletica-511	15	23	the	the	DET
ecletica-511	15	24	interactions	interaction	NOUN
ecletica-511	15	25	of	of	ADP
ecletica-511	15	26	zn2	zn2	PROPN
ecletica-511	15	27	+	+	PROPN
ecletica-511	15	28	and	and	CCONJ
ecletica-511	15	29	of	of	ADP
ecletica-511	15	30	cu2	cu2	NOUN
ecletica-511	15	31	+	+	X
ecletica-511	15	32	with	with	ADP
ecletica-511	15	33	water	water	NOUN
ecletica-511	15	34	molecules	molecule	NOUN
ecletica-511	15	35	in	in	ADP
ecletica-511	15	36	the	the	DET
ecletica-511	15	37	aqueous	aqueous	ADJ
ecletica-511	15	38	solution	solution	NOUN
ecletica-511	15	39	.	.	PUNCT
ecletica-511	16	1	a	a	DET
ecletica-511	16	2	mechanism	mechanism	NOUN
ecletica-511	16	3	is	be	AUX
ecletica-511	16	4	proposed	propose	VERB
ecletica-511	16	5	and	and	CCONJ
ecletica-511	16	6	the	the	DET
ecletica-511	16	7	rate	rate	NOUN
ecletica-511	16	8	constants	constant	NOUN
ecletica-511	16	9	are	be	AUX
ecletica-511	16	10	calculated	calculate	VERB
ecletica-511	16	11	.	.	PUNCT
ecletica-511	17	1	keywords	keyword	NOUN
ecletica-511	17	2	:	:	PUNCT
ecletica-511	17	3	par	par	NOUN
ecletica-511	17	4	,	,	PUNCT
ecletica-511	17	5	zinc	zinc	NOUN
ecletica-511	17	6	,	,	PUNCT
ecletica-511	17	7	copper	copper	NOUN
ecletica-511	17	8	,	,	PUNCT
ecletica-511	17	9	kinetics	kinetic	NOUN
ecletica-511	17	10	,	,	PUNCT
ecletica-511	17	11	mechanism	mechanism	NOUN
ecletica-511	17	12	volume	volume	NOUN
ecletica-511	17	13	28	28	NUM
ecletica-511	17	14	(	(	PUNCT
ecletica-511	17	15	2003	2003	NUM
ecletica-511	17	16	)	)	PUNCT
ecletica-511	17	17	número	número	NOUN
ecletica-511	17	18	1	1	NUM
ecletica-511	17	19	www.scielo.br/eq	www.scielo.br/eq	PROPN
ecletica-511	17	20	ecl	ecl	PROPN
ecletica-511	17	21	.	.	PROPN
ecletica-511	17	22	quím	quím	PROPN
ecletica-511	17	23	.	.	PUNCT
ecletica-511	17	24	,	,	PUNCT
ecletica-511	17	25	são	são	PROPN
ecletica-511	17	26	paulo	paulo	PROPN
ecletica-511	17	27	,	,	PUNCT
ecletica-511	17	28	28(1	28(1	NOUN
ecletica-511	17	29	):	):	PUNCT
ecletica-511	17	30	55	55	NUM
ecletica-511	17	31	-	-	SYM
ecletica-511	17	32	62	62	NUM
ecletica-511	17	33	,	,	PUNCT
ecletica-511	17	34	2003	2003	NUM
ecletica-511	17	35	,	,	PUNCT
ecletica-511	17	36	56	56	NUM
ecletica-511	17	37	strength	strength	NOUN
ecletica-511	17	38	=	=	SYM
ecletica-511	17	39	0.1	0.1	NUM
ecletica-511	17	40	mol	mol	ADP
ecletica-511	17	41	l-1	l-1	PROPN
ecletica-511	17	42	,	,	PUNCT
ecletica-511	17	43	the	the	DET
ecletica-511	17	44	logarithm	logarithm	NOUN
ecletica-511	17	45	of	of	ADP
ecletica-511	17	46	the	the	DET
ecletica-511	17	47	first	first	ADJ
ecletica-511	17	48	stability	stability	NOUN
ecletica-511	17	49	constants	constant	NOUN
ecletica-511	17	50	(	(	PUNCT
ecletica-511	17	51	k	k	X
ecletica-511	17	52	mhl	mhl	PROPN
ecletica-511	17	53	)	)	PUNCT
ecletica-511	17	54	are	be	AUX
ecletica-511	17	55	14.8	14.8	NUM
ecletica-511	17	56	and	and	CCONJ
ecletica-511	17	57	10.5	10.5	NUM
ecletica-511	17	58	respectively	respectively	ADV
ecletica-511	17	59	.	.	PUNCT
ecletica-511	18	1	the	the	DET
ecletica-511	18	2	logarithm	logarithm	NOUN
ecletica-511	18	3	of	of	ADP
ecletica-511	18	4	the	the	DET
ecletica-511	18	5	second	second	ADJ
ecletica-511	18	6	stability	stability	NOUN
ecletica-511	18	7	constant	constant	ADJ
ecletica-511	18	8	(	(	PUNCT
ecletica-511	18	9	k	k	X
ecletica-511	18	10	mhl2	mhl2	PROPN
ecletica-511	18	11	)	)	PUNCT
ecletica-511	18	12	are	be	AUX
ecletica-511	18	13	9.1	9.1	NUM
ecletica-511	18	14	and	and	CCONJ
ecletica-511	18	15	6.6	6.6	NUM
ecletica-511	18	16	respectively	respectively	ADV
ecletica-511	18	17	[	[	X
ecletica-511	18	18	1	1	NUM
ecletica-511	18	19	]	]	PUNCT
ecletica-511	18	20	.	.	PUNCT
ecletica-511	19	1	aqueous	aqueous	ADJ
ecletica-511	19	2	solutions	solution	NOUN
ecletica-511	19	3	are	be	AUX
ecletica-511	19	4	the	the	DET
ecletica-511	19	5	most	most	ADV
ecletica-511	19	6	common	common	ADJ
ecletica-511	19	7	medium	medium	NOUN
ecletica-511	19	8	for	for	ADP
ecletica-511	19	9	chemical	chemical	ADJ
ecletica-511	19	10	reactions	reaction	NOUN
ecletica-511	19	11	but	but	CCONJ
ecletica-511	19	12	,	,	PUNCT
ecletica-511	19	13	for	for	ADP
ecletica-511	19	14	simplification	simplification	NOUN
ecletica-511	19	15	purposes	purpose	NOUN
ecletica-511	19	16	,	,	PUNCT
ecletica-511	19	17	individual	individual	ADJ
ecletica-511	19	18	interactions	interaction	NOUN
ecletica-511	19	19	of	of	ADP
ecletica-511	19	20	the	the	DET
ecletica-511	19	21	reactive	reactive	ADJ
ecletica-511	19	22	species	specie	NOUN
ecletica-511	19	23	with	with	ADP
ecletica-511	19	24	water	water	NOUN
ecletica-511	19	25	are	be	AUX
ecletica-511	19	26	usually	usually	ADV
ecletica-511	19	27	neglected	neglect	VERB
ecletica-511	19	28	.	.	PUNCT
ecletica-511	20	1	usually	usually	ADV
ecletica-511	20	2	,	,	PUNCT
ecletica-511	20	3	kinetic	kinetic	NOUN
ecletica-511	20	4	-	-	PUNCT
ecletica-511	20	5	mechanistic	mechanistic	ADJ
ecletica-511	20	6	studies	study	NOUN
ecletica-511	20	7	of	of	ADP
ecletica-511	20	8	the	the	DET
ecletica-511	20	9	complexation	complexation	NOUN
ecletica-511	20	10	of	of	ADP
ecletica-511	20	11	metal	metal	NOUN
ecletica-511	20	12	transition	transition	NOUN
ecletica-511	20	13	cations	cation	NOUN
ecletica-511	20	14	have	have	AUX
ecletica-511	20	15	been	be	AUX
ecletica-511	20	16	performed	perform	VERB
ecletica-511	20	17	in	in	ADP
ecletica-511	20	18	the	the	DET
ecletica-511	20	19	presence	presence	NOUN
ecletica-511	20	20	of	of	ADP
ecletica-511	20	21	only	only	ADV
ecletica-511	20	22	one	one	NUM
ecletica-511	20	23	species	specie	NOUN
ecletica-511	20	24	of	of	ADP
ecletica-511	20	25	cation	cation	NOUN
ecletica-511	20	26	and	and	CCONJ
ecletica-511	20	27	not	not	PART
ecletica-511	20	28	in	in	ADP
ecletica-511	20	29	conditions	condition	NOUN
ecletica-511	20	30	where	where	SCONJ
ecletica-511	20	31	a	a	DET
ecletica-511	20	32	mixture	mixture	NOUN
ecletica-511	20	33	of	of	ADP
ecletica-511	20	34	cations	cation	NOUN
ecletica-511	20	35	reacts	react	NOUN
ecletica-511	20	36	with	with	ADP
ecletica-511	20	37	the	the	DET
ecletica-511	20	38	ligand	ligand	NOUN
ecletica-511	20	39	.	.	PUNCT
ecletica-511	21	1	nevertheless	nevertheless	ADV
ecletica-511	21	2	,	,	PUNCT
ecletica-511	21	3	in	in	ADP
ecletica-511	21	4	nature	nature	NOUN
ecletica-511	21	5	and	and	CCONJ
ecletica-511	21	6	in	in	ADP
ecletica-511	21	7	analytical	analytical	ADJ
ecletica-511	21	8	sample	sample	NOUN
ecletica-511	21	9	matrixes	matrix	NOUN
ecletica-511	21	10	,	,	PUNCT
ecletica-511	21	11	complexation	complexation	NOUN
ecletica-511	21	12	reactions	reaction	NOUN
ecletica-511	21	13	occur	occur	VERB
ecletica-511	21	14	with	with	ADP
ecletica-511	21	15	cations	cation	NOUN
ecletica-511	21	16	and	and	CCONJ
ecletica-511	21	17	ligands	ligand	NOUN
ecletica-511	21	18	that	that	PRON
ecletica-511	21	19	are	be	AUX
ecletica-511	21	20	in	in	ADP
ecletica-511	21	21	the	the	DET
ecletica-511	21	22	presence	presence	NOUN
ecletica-511	21	23	of	of	ADP
ecletica-511	21	24	water	water	NOUN
ecletica-511	21	25	and	and	CCONJ
ecletica-511	21	26	other	other	ADJ
ecletica-511	21	27	species	specie	NOUN
ecletica-511	21	28	,	,	PUNCT
ecletica-511	21	29	including	include	VERB
ecletica-511	21	30	other	other	ADJ
ecletica-511	21	31	cations	cation	NOUN
ecletica-511	21	32	than	than	SCONJ
ecletica-511	21	33	can	can	AUX
ecletica-511	21	34	be	be	AUX
ecletica-511	21	35	complexed	complexe	VERB
ecletica-511	21	36	[	[	PUNCT
ecletica-511	21	37	9	9	NUM
ecletica-511	21	38	]	]	PUNCT
ecletica-511	21	39	.	.	PUNCT
ecletica-511	22	1	the	the	DET
ecletica-511	22	2	effect	effect	NOUN
ecletica-511	22	3	of	of	ADP
ecletica-511	22	4	the	the	DET
ecletica-511	22	5	interactions	interaction	NOUN
ecletica-511	22	6	among	among	ADP
ecletica-511	22	7	water	water	NOUN
ecletica-511	22	8	molecules	molecule	NOUN
ecletica-511	22	9	,	,	PUNCT
ecletica-511	22	10	among	among	ADP
ecletica-511	22	11	water	water	NOUN
ecletica-511	22	12	and	and	CCONJ
ecletica-511	22	13	reacting	react	VERB
ecletica-511	22	14	species	specie	NOUN
ecletica-511	22	15	,	,	PUNCT
ecletica-511	22	16	among	among	ADP
ecletica-511	22	17	water	water	NOUN
ecletica-511	22	18	and	and	CCONJ
ecletica-511	22	19	other	other	ADJ
ecletica-511	22	20	species	specie	NOUN
ecletica-511	22	21	,	,	PUNCT
ecletica-511	22	22	etc	etc	X
ecletica-511	22	23	.	.	X
ecletica-511	22	24	,	,	PUNCT
ecletica-511	22	25	are	be	AUX
ecletica-511	22	26	usually	usually	ADV
ecletica-511	22	27	neglected	neglect	VERB
ecletica-511	22	28	due	due	ADP
ecletica-511	22	29	to	to	ADP
ecletica-511	22	30	simplification	simplification	NOUN
ecletica-511	22	31	purposes	purpose	NOUN
ecletica-511	22	32	.	.	PUNCT
ecletica-511	23	1	however	however	ADV
ecletica-511	23	2	,	,	PUNCT
ecletica-511	23	3	in	in	ADP
ecletica-511	23	4	some	some	DET
ecletica-511	23	5	cases	case	NOUN
ecletica-511	23	6	,	,	PUNCT
ecletica-511	23	7	this	this	DET
ecletica-511	23	8	simplification	simplification	NOUN
ecletica-511	23	9	can	can	AUX
ecletica-511	23	10	hide	hide	VERB
ecletica-511	23	11	the	the	DET
ecletica-511	23	12	actual	actual	ADJ
ecletica-511	23	13	mechanism	mechanism	NOUN
ecletica-511	23	14	of	of	ADP
ecletica-511	23	15	the	the	DET
ecletica-511	23	16	reaction	reaction	NOUN
ecletica-511	23	17	and	and	CCONJ
ecletica-511	23	18	the	the	DET
ecletica-511	23	19	actual	actual	ADJ
ecletica-511	23	20	nature	nature	NOUN
ecletica-511	23	21	of	of	ADP
ecletica-511	23	22	the	the	DET
ecletica-511	23	23	complex	complex	NOUN
ecletica-511	23	24	formed	form	VERB
ecletica-511	23	25	.	.	PUNCT
ecletica-511	24	1	despite	despite	SCONJ
ecletica-511	24	2	the	the	DET
ecletica-511	24	3	fact	fact	NOUN
ecletica-511	24	4	that	that	SCONJ
ecletica-511	24	5	these	these	DET
ecletica-511	24	6	interactions	interaction	NOUN
ecletica-511	24	7	in	in	ADP
ecletica-511	24	8	water	water	NOUN
ecletica-511	24	9	solutions	solution	NOUN
ecletica-511	24	10	can	can	AUX
ecletica-511	24	11	be	be	AUX
ecletica-511	24	12	considered	consider	VERB
ecletica-511	24	13	weak	weak	ADJ
ecletica-511	24	14	,	,	PUNCT
ecletica-511	24	15	in	in	ADP
ecletica-511	24	16	some	some	DET
ecletica-511	24	17	cases	case	NOUN
ecletica-511	24	18	they	they	PRON
ecletica-511	24	19	are	be	AUX
ecletica-511	24	20	detectable	detectable	ADJ
ecletica-511	24	21	and	and	CCONJ
ecletica-511	24	22	can	can	AUX
ecletica-511	24	23	be	be	AUX
ecletica-511	24	24	understood	understand	VERB
ecletica-511	24	25	according	accord	VERB
ecletica-511	24	26	to	to	ADP
ecletica-511	24	27	the	the	DET
ecletica-511	24	28	characteristics	characteristic	NOUN
ecletica-511	24	29	of	of	ADP
ecletica-511	24	30	the	the	DET
ecletica-511	24	31	species	specie	NOUN
ecletica-511	24	32	involved	involve	VERB
ecletica-511	24	33	[	[	PUNCT
ecletica-511	24	34	9	9	NUM
ecletica-511	24	35	,	,	PUNCT
ecletica-511	24	36	7	7	NUM
ecletica-511	24	37	]	]	PUNCT
ecletica-511	24	38	.	.	PUNCT
ecletica-511	25	1	in	in	ADP
ecletica-511	25	2	a	a	DET
ecletica-511	25	3	study	study	NOUN
ecletica-511	25	4	of	of	ADP
ecletica-511	25	5	the	the	DET
ecletica-511	25	6	mechanism	mechanism	NOUN
ecletica-511	25	7	of	of	ADP
ecletica-511	25	8	the	the	DET
ecletica-511	25	9	reaction	reaction	NOUN
ecletica-511	25	10	of	of	ADP
ecletica-511	25	11	cu2	cu2	NOUN
ecletica-511	25	12	+	+	PROPN
ecletica-511	25	13	,	,	PUNCT
ecletica-511	25	14	of	of	ADP
ecletica-511	25	15	zn2	zn2	PROPN
ecletica-511	25	16	+	+	PROPN
ecletica-511	25	17	and	and	CCONJ
ecletica-511	25	18	of	of	ADP
ecletica-511	25	19	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	25	20	+	+	CCONJ
ecletica-511	25	21	equimolar	equimolar	NOUN
ecletica-511	25	22	mixtures	mixture	NOUN
ecletica-511	25	23	with	with	ADP
ecletica-511	25	24	zincon	zincon	NOUN
ecletica-511	25	25	[	[	X
ecletica-511	25	26	9	9	NUM
ecletica-511	25	27	]	]	PUNCT
ecletica-511	25	28	,	,	PUNCT
ecletica-511	25	29	it	it	PRON
ecletica-511	25	30	was	be	AUX
ecletica-511	25	31	shown	show	VERB
ecletica-511	25	32	that	that	SCONJ
ecletica-511	25	33	the	the	DET
ecletica-511	25	34	water	water	NOUN
ecletica-511	25	35	molecules	molecule	NOUN
ecletica-511	25	36	in	in	ADP
ecletica-511	25	37	the	the	DET
ecletica-511	25	38	solvation	solvation	NOUN
ecletica-511	25	39	shells	shell	NOUN
ecletica-511	25	40	of	of	ADP
ecletica-511	25	41	the	the	DET
ecletica-511	25	42	ions	ion	NOUN
ecletica-511	25	43	probably	probably	ADV
ecletica-511	25	44	determinate	determinate	VERB
ecletica-511	25	45	the	the	DET
ecletica-511	25	46	mechanism	mechanism	NOUN
ecletica-511	25	47	and	and	CCONJ
ecletica-511	25	48	the	the	DET
ecletica-511	25	49	equilibrium	equilibrium	NOUN
ecletica-511	25	50	of	of	ADP
ecletica-511	25	51	the	the	DET
ecletica-511	25	52	reaction	reaction	NOUN
ecletica-511	25	53	.	.	PUNCT
ecletica-511	26	1	the	the	DET
ecletica-511	26	2	aim	aim	NOUN
ecletica-511	26	3	of	of	ADP
ecletica-511	26	4	the	the	DET
ecletica-511	26	5	present	present	ADJ
ecletica-511	26	6	work	work	NOUN
ecletica-511	26	7	was	be	AUX
ecletica-511	26	8	to	to	PART
ecletica-511	26	9	show	show	VERB
ecletica-511	26	10	that	that	SCONJ
ecletica-511	26	11	some	some	DET
ecletica-511	26	12	weak	weak	ADJ
ecletica-511	26	13	interactions	interaction	NOUN
ecletica-511	26	14	in	in	ADP
ecletica-511	26	15	aqueous	aqueous	ADJ
ecletica-511	26	16	solutions	solution	NOUN
ecletica-511	26	17	can	can	AUX
ecletica-511	26	18	actually	actually	ADV
ecletica-511	26	19	influence	influence	VERB
ecletica-511	26	20	the	the	DET
ecletica-511	26	21	kinetics	kinetic	NOUN
ecletica-511	26	22	and	and	CCONJ
ecletica-511	26	23	the	the	DET
ecletica-511	26	24	equilibrium	equilibrium	NOUN
ecletica-511	26	25	of	of	ADP
ecletica-511	26	26	chemical	chemical	ADJ
ecletica-511	26	27	reactions	reaction	NOUN
ecletica-511	26	28	.	.	PUNCT
ecletica-511	27	1	this	this	DET
ecletica-511	27	2	knowledge	knowledge	NOUN
ecletica-511	27	3	could	could	AUX
ecletica-511	27	4	help	help	VERB
ecletica-511	27	5	to	to	PART
ecletica-511	27	6	understand	understand	VERB
ecletica-511	27	7	and	and	CCONJ
ecletica-511	27	8	to	to	PART
ecletica-511	27	9	prevent	prevent	VERB
ecletica-511	27	10	interference	interference	NOUN
ecletica-511	27	11	,	,	PUNCT
ecletica-511	27	12	in	in	ADP
ecletica-511	27	13	kinetic	kinetic	NOUN
ecletica-511	27	14	and	and	CCONJ
ecletica-511	27	15	in	in	ADP
ecletica-511	27	16	equilibrium	equilibrium	NOUN
ecletica-511	27	17	analytical	analytical	ADJ
ecletica-511	27	18	procedures	procedure	NOUN
ecletica-511	27	19	,	,	PUNCT
ecletica-511	27	20	that	that	PRON
ecletica-511	27	21	can	can	AUX
ecletica-511	27	22	be	be	AUX
ecletica-511	27	23	caused	cause	VERB
ecletica-511	27	24	by	by	ADP
ecletica-511	27	25	these	these	DET
ecletica-511	27	26	weak	weak	ADJ
ecletica-511	27	27	interactions	interaction	NOUN
ecletica-511	27	28	.	.	PUNCT
ecletica-511	28	1	certainly	certainly	ADV
ecletica-511	28	2	,	,	PUNCT
ecletica-511	28	3	it	it	PRON
ecletica-511	28	4	could	could	AUX
ecletica-511	28	5	also	also	ADV
ecletica-511	28	6	be	be	AUX
ecletica-511	28	7	applied	apply	VERB
ecletica-511	28	8	to	to	ADP
ecletica-511	28	9	other	other	ADJ
ecletica-511	28	10	fields	field	NOUN
ecletica-511	28	11	of	of	ADP
ecletica-511	28	12	the	the	DET
ecletica-511	28	13	chemistry	chemistry	NOUN
ecletica-511	28	14	although	although	SCONJ
ecletica-511	28	15	this	this	PRON
ecletica-511	28	16	is	be	AUX
ecletica-511	28	17	out	out	ADP
ecletica-511	28	18	of	of	ADP
ecletica-511	28	19	the	the	DET
ecletica-511	28	20	scope	scope	NOUN
ecletica-511	28	21	of	of	ADP
ecletica-511	28	22	the	the	DET
ecletica-511	28	23	present	present	ADJ
ecletica-511	28	24	work	work	NOUN
ecletica-511	28	25	.	.	PUNCT
ecletica-511	29	1	experimental	experimental	ADJ
ecletica-511	29	2	materials	material	NOUN
ecletica-511	29	3	all	all	DET
ecletica-511	29	4	reagents	reagent	NOUN
ecletica-511	29	5	were	be	AUX
ecletica-511	29	6	of	of	ADP
ecletica-511	29	7	analytical	analytical	ADJ
ecletica-511	29	8	grade	grade	NOUN
ecletica-511	29	9	and	and	CCONJ
ecletica-511	29	10	solutions	solution	NOUN
ecletica-511	29	11	were	be	AUX
ecletica-511	29	12	prepared	prepare	VERB
ecletica-511	29	13	with	with	ADP
ecletica-511	29	14	water	water	NOUN
ecletica-511	29	15	obtained	obtain	VERB
ecletica-511	29	16	from	from	ADP
ecletica-511	29	17	an	an	DET
ecletica-511	29	18	all	all	DET
ecletica-511	29	19	-	-	PUNCT
ecletica-511	29	20	glass	glass	NOUN
ecletica-511	29	21	distillation	distillation	NOUN
ecletica-511	29	22	apparatus	apparatus	NOUN
ecletica-511	29	23	.	.	PUNCT
ecletica-511	30	1	kcl	kcl	PROPN
ecletica-511	30	2	was	be	AUX
ecletica-511	30	3	used	use	VERB
ecletica-511	30	4	to	to	PART
ecletica-511	30	5	maintain	maintain	VERB
ecletica-511	30	6	constant	constant	ADJ
ecletica-511	30	7	ionic	ionic	ADJ
ecletica-511	30	8	strength	strength	NOUN
ecletica-511	30	9	(	(	PUNCT
ecletica-511	30	10	1.00	1.00	NUM
ecletica-511	30	11	mol	mol	ADP
ecletica-511	30	12	l-1	l-1	NUM
ecletica-511	30	13	)	)	PUNCT
ecletica-511	30	14	in	in	ADP
ecletica-511	30	15	all	all	DET
ecletica-511	30	16	working	work	VERB
ecletica-511	30	17	solutions	solution	NOUN
ecletica-511	30	18	.	.	PUNCT
ecletica-511	31	1	a	a	DET
ecletica-511	31	2	(	(	PUNCT
ecletica-511	31	3	1.528±0.001)×10	1.528±0.001)×10	NUM
ecletica-511	31	4	-	-	SYM
ecletica-511	31	5	2	2	NUM
ecletica-511	31	6	mol	mol	ADP
ecletica-511	31	7	l1	l1	PROPN
ecletica-511	31	8	stock	stock	NOUN
ecletica-511	31	9	solution	solution	NOUN
ecletica-511	31	10	of	of	ADP
ecletica-511	31	11	zinc	zinc	NOUN
ecletica-511	31	12	chloride	chloride	NOUN
ecletica-511	31	13	was	be	AUX
ecletica-511	31	14	prepared	prepare	VERB
ecletica-511	31	15	by	by	ADP
ecletica-511	31	16	dissolving	dissolve	VERB
ecletica-511	31	17	metallic	metallic	ADJ
ecletica-511	31	18	zinc	zinc	NOUN
ecletica-511	31	19	in	in	ADP
ecletica-511	31	20	6.0	6.0	NUM
ecletica-511	31	21	mol	mol	ADP
ecletica-511	31	22	l-1	l-1	PROPN
ecletica-511	31	23	hcl	hcl	PROPN
ecletica-511	31	24	.	.	PUNCT
ecletica-511	32	1	working	work	VERB
ecletica-511	32	2	zn2	zn2	PROPN
ecletica-511	32	3	+	+	SYM
ecletica-511	32	4	solutions	solution	NOUN
ecletica-511	32	5	were	be	AUX
ecletica-511	32	6	prepared	prepare	VERB
ecletica-511	32	7	by	by	ADP
ecletica-511	32	8	dilution	dilution	NOUN
ecletica-511	32	9	.	.	PUNCT
ecletica-511	33	1	a	a	DET
ecletica-511	33	2	(	(	PUNCT
ecletica-511	33	3	1.550±0.005)×10	1.550±0.005)×10	NUM
ecletica-511	33	4	-	-	SYM
ecletica-511	33	5	2	2	NUM
ecletica-511	33	6	mol	mol	ADP
ecletica-511	33	7	l-1	l-1	NOUN
ecletica-511	33	8	stock	stock	NOUN
ecletica-511	33	9	solution	solution	NOUN
ecletica-511	33	10	of	of	ADP
ecletica-511	33	11	copper	copper	NOUN
ecletica-511	33	12	sulfate	sulfate	NOUN
ecletica-511	33	13	was	be	AUX
ecletica-511	33	14	prepared	prepare	VERB
ecletica-511	33	15	by	by	ADP
ecletica-511	33	16	dissolving	dissolve	VERB
ecletica-511	33	17	cuso4.5h2o	cuso4.5h2o	NOUN
ecletica-511	33	18	in	in	ADP
ecletica-511	33	19	distilled	distil	VERB
ecletica-511	33	20	water	water	NOUN
ecletica-511	33	21	followed	follow	VERB
ecletica-511	33	22	by	by	ADP
ecletica-511	33	23	standardization	standardization	NOUN
ecletica-511	33	24	by	by	ADP
ecletica-511	33	25	the	the	DET
ecletica-511	33	26	iodometric	iodometric	ADJ
ecletica-511	33	27	method	method	NOUN
ecletica-511	33	28	[	[	X
ecletica-511	33	29	13	13	NUM
ecletica-511	33	30	]	]	PUNCT
ecletica-511	33	31	.	.	PUNCT
ecletica-511	34	1	working	work	VERB
ecletica-511	34	2	cu2	cu2	NOUN
ecletica-511	34	3	+	+	CCONJ
ecletica-511	34	4	solutions	solution	NOUN
ecletica-511	34	5	were	be	AUX
ecletica-511	34	6	prepared	prepare	VERB
ecletica-511	34	7	by	by	ADP
ecletica-511	34	8	dilution	dilution	NOUN
ecletica-511	34	9	with	with	ADP
ecletica-511	34	10	distilled	distil	VERB
ecletica-511	34	11	water	water	NOUN
ecletica-511	34	12	.	.	PUNCT
ecletica-511	35	1	working	work	VERB
ecletica-511	35	2	solutions	solution	NOUN
ecletica-511	35	3	of	of	ADP
ecletica-511	35	4	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	35	5	+	+	CCONJ
ecletica-511	35	6	equimolar	equimolar	ADJ
ecletica-511	35	7	mixtures	mixture	NOUN
ecletica-511	35	8	were	be	AUX
ecletica-511	35	9	prepared	prepare	VERB
ecletica-511	35	10	by	by	ADP
ecletica-511	35	11	dilution	dilution	NOUN
ecletica-511	35	12	of	of	ADP
ecletica-511	35	13	mixtures	mixture	NOUN
ecletica-511	35	14	of	of	ADP
ecletica-511	35	15	appropriate	appropriate	ADJ
ecletica-511	35	16	volumes	volume	NOUN
ecletica-511	35	17	of	of	ADP
ecletica-511	35	18	the	the	DET
ecletica-511	35	19	above	above	ADJ
ecletica-511	35	20	stock	stock	NOUN
ecletica-511	35	21	solutions	solution	NOUN
ecletica-511	35	22	with	with	ADP
ecletica-511	35	23	distilled	distil	VERB
ecletica-511	35	24	water	water	NOUN
ecletica-511	35	25	.	.	PUNCT
ecletica-511	36	1	buffer	buffer	NOUN
ecletica-511	36	2	solutions	solution	NOUN
ecletica-511	36	3	(	(	PUNCT
ecletica-511	36	4	ph	ph	NOUN
ecletica-511	36	5	=	=	SYM
ecletica-511	36	6	8.5	8.5	NUM
ecletica-511	36	7	)	)	PUNCT
ecletica-511	36	8	were	be	AUX
ecletica-511	36	9	obtained	obtain	VERB
ecletica-511	36	10	by	by	ADP
ecletica-511	36	11	mixing	mix	VERB
ecletica-511	36	12	50.0	50.0	NUM
ecletica-511	36	13	ml	ml	NOUN
ecletica-511	36	14	of	of	ADP
ecletica-511	36	15	0.10	0.10	NUM
ecletica-511	36	16	mol	mol	NOUN
ecletica-511	36	17	l-1	l-1	PROPN
ecletica-511	36	18	h3bo3	h3bo3	PROPN
ecletica-511	36	19	prepared	prepare	VERB
ecletica-511	36	20	in	in	ADP
ecletica-511	36	21	1.00	1.00	NUM
ecletica-511	36	22	mol	mol	ADP
ecletica-511	36	23	l-1	l-1	NOUN
ecletica-511	36	24	kcl	kcl	PROPN
ecletica-511	36	25	solution	solution	NOUN
ecletica-511	36	26	with	with	ADP
ecletica-511	36	27	10.0	10.0	NUM
ecletica-511	36	28	ml	ml	NOUN
ecletica-511	36	29	of	of	ADP
ecletica-511	36	30	0.10	0.10	NUM
ecletica-511	36	31	mol	mol	ADP
ecletica-511	36	32	l-1	l-1	PROPN
ecletica-511	36	33	naoh	naoh	PROPN
ecletica-511	36	34	solution	solution	NOUN
ecletica-511	37	1	[	[	X
ecletica-511	37	2	14	14	NUM
ecletica-511	37	3	]	]	PUNCT
ecletica-511	37	4	.	.	PUNCT
ecletica-511	38	1	par	par	PROPN
ecletica-511	38	2	solutions	solution	NOUN
ecletica-511	38	3	were	be	AUX
ecletica-511	38	4	prepared	prepare	VERB
ecletica-511	38	5	daily	daily	ADV
ecletica-511	38	6	by	by	ADP
ecletica-511	38	7	direct	direct	ADJ
ecletica-511	38	8	weighing	weighing	NOUN
ecletica-511	38	9	of	of	ADP
ecletica-511	38	10	the	the	DET
ecletica-511	38	11	monosodium	monosodium	NOUN
ecletica-511	38	12	salt	salt	NOUN
ecletica-511	38	13	for	for	ADP
ecletica-511	38	14	dissolution	dissolution	NOUN
ecletica-511	38	15	in	in	ADP
ecletica-511	38	16	the	the	DET
ecletica-511	38	17	buffer	buffer	NOUN
ecletica-511	38	18	solution	solution	NOUN
ecletica-511	38	19	.	.	PUNCT
ecletica-511	39	1	spectra	spectra	VERB
ecletica-511	39	2	the	the	DET
ecletica-511	39	3	visible	visible	ADJ
ecletica-511	39	4	electronic	electronic	ADJ
ecletica-511	39	5	spectra	spectra	NOUN
ecletica-511	39	6	were	be	AUX
ecletica-511	39	7	determined	determine	VERB
ecletica-511	39	8	with	with	ADP
ecletica-511	39	9	a	a	DET
ecletica-511	39	10	hp-8452	hp-8452	NOUN
ecletica-511	39	11	diode	diode	NOUN
ecletica-511	39	12	array	array	NOUN
ecletica-511	39	13	spectrophotometer	spectrophotometer	NOUN
ecletica-511	39	14	and	and	CCONJ
ecletica-511	39	15	a	a	DET
ecletica-511	39	16	1.00	1.00	NUM
ecletica-511	39	17	cm	cm	NOUN
ecletica-511	39	18	path	path	NOUN
ecletica-511	39	19	quartz	quartz	NOUN
ecletica-511	39	20	cell	cell	NOUN
ecletica-511	39	21	.	.	PUNCT
ecletica-511	40	1	the	the	DET
ecletica-511	40	2	following	follow	VERB
ecletica-511	40	3	solutions	solution	NOUN
ecletica-511	40	4	were	be	AUX
ecletica-511	40	5	used	use	VERB
ecletica-511	40	6	:	:	PUNCT
ecletica-511	40	7	3.03×10	3.03×10	X
ecletica-511	40	8	-	-	SYM
ecletica-511	40	9	5	5	NUM
ecletica-511	40	10	mol	mol	ADP
ecletica-511	40	11	l-1	l-1	PROPN
ecletica-511	40	12	zn(hl)2	zn(hl)2	NOUN
ecletica-511	40	13	;	;	PUNCT
ecletica-511	40	14	2.96×10	2.96×10	X
ecletica-511	40	15	-	-	SYM
ecletica-511	40	16	5	5	NUM
ecletica-511	40	17	mol	mol	ADP
ecletica-511	40	18	l-1	l-1	PROPN
ecletica-511	40	19	cu(hl)2	cu(hl)2	PROPN
ecletica-511	40	20	and	and	CCONJ
ecletica-511	40	21	(	(	PUNCT
ecletica-511	40	22	1.50	1.50	NUM
ecletica-511	40	23	+	+	NOUN
ecletica-511	40	24	1.50)×10	1.50)×10	NOUN
ecletica-511	40	25	-	-	SYM
ecletica-511	40	26	5	5	NUM
ecletica-511	40	27	mol	mol	NOUN
ecletica-511	40	28	l-1	l-1	NUM
ecletica-511	41	1	[	[	X
ecletica-511	41	2	(	(	PUNCT
ecletica-511	41	3	zn+cu)(hl)2	zn+cu)(hl)2	PROPN
ecletica-511	41	4	]	]	PUNCT
ecletica-511	41	5	.	.	PUNCT
ecletica-511	42	1	kinetics	kinetic	VERB
ecletica-511	42	2	the	the	DET
ecletica-511	42	3	reactions	reaction	NOUN
ecletica-511	42	4	were	be	AUX
ecletica-511	42	5	monitored	monitor	VERB
ecletica-511	42	6	spectrophotometrically	spectrophotometrically	ADV
ecletica-511	42	7	at	at	ADP
ecletica-511	42	8	500	500	NUM
ecletica-511	42	9	nm	nm	NOUN
ecletica-511	42	10	,	,	PUNCT
ecletica-511	42	11	at	at	ADP
ecletica-511	42	12	(	(	PUNCT
ecletica-511	42	13	25.0	25.0	NUM
ecletica-511	42	14	±	±	NUM
ecletica-511	42	15	0.1	0.1	NUM
ecletica-511	42	16	)	)	PUNCT
ecletica-511	43	1	°	°	ADP
ecletica-511	43	2	c	c	PROPN
ecletica-511	43	3	,	,	PUNCT
ecletica-511	43	4	using	use	VERB
ecletica-511	43	5	a	a	DET
ecletica-511	43	6	stopped	stop	VERB
ecletica-511	43	7	-	-	PUNCT
ecletica-511	43	8	flow	flow	NOUN
ecletica-511	43	9	apparatus	apparatus	NOUN
ecletica-511	43	10	built	build	VERB
ecletica-511	43	11	in	in	ADP
ecletica-511	43	12	our	our	PRON
ecletica-511	43	13	laboratory	laboratory	NOUN
ecletica-511	43	14	[	[	X
ecletica-511	43	15	8	8	NUM
ecletica-511	43	16	,	,	PUNCT
ecletica-511	43	17	11,12	11,12	NOUN
ecletica-511	43	18	]	]	PUNCT
ecletica-511	43	19	.	.	PUNCT
ecletica-511	44	1	in	in	ADP
ecletica-511	44	2	order	order	NOUN
ecletica-511	44	3	to	to	PART
ecletica-511	44	4	study	study	VERB
ecletica-511	44	5	the	the	DET
ecletica-511	44	6	influence	influence	NOUN
ecletica-511	44	7	of	of	ADP
ecletica-511	44	8	the	the	DET
ecletica-511	44	9	concentration	concentration	NOUN
ecletica-511	44	10	of	of	ADP
ecletica-511	44	11	the	the	DET
ecletica-511	44	12	metal	metal	NOUN
ecletica-511	44	13	and	and	CCONJ
ecletica-511	44	14	of	of	ADP
ecletica-511	44	15	the	the	DET
ecletica-511	44	16	ligand	ligand	NOUN
ecletica-511	44	17	on	on	ADP
ecletica-511	44	18	the	the	DET
ecletica-511	44	19	reaction	reaction	NOUN
ecletica-511	44	20	,	,	PUNCT
ecletica-511	44	21	two	two	NUM
ecletica-511	44	22	series	series	NOUN
ecletica-511	44	23	of	of	ADP
ecletica-511	44	24	experiments	experiment	NOUN
ecletica-511	44	25	were	be	AUX
ecletica-511	44	26	performed	perform	VERB
ecletica-511	44	27	for	for	ADP
ecletica-511	44	28	each	each	DET
ecletica-511	44	29	metal	metal	NOUN
ecletica-511	44	30	and	and	CCONJ
ecletica-511	44	31	for	for	ADP
ecletica-511	44	32	the	the	DET
ecletica-511	44	33	equimolar	equimolar	NOUN
ecletica-511	44	34	mixture	mixture	NOUN
ecletica-511	44	35	of	of	ADP
ecletica-511	44	36	zinc	zinc	NOUN
ecletica-511	44	37	and	and	CCONJ
ecletica-511	44	38	copper	copper	NOUN
ecletica-511	44	39	.	.	PUNCT
ecletica-511	45	1	series	series	PROPN
ecletica-511	45	2	i	i	PRON
ecletica-511	45	3	:	:	PUNCT
ecletica-511	45	4	to	to	PART
ecletica-511	45	5	study	study	VERB
ecletica-511	45	6	the	the	DET
ecletica-511	45	7	influence	influence	NOUN
ecletica-511	45	8	of	of	ADP
ecletica-511	45	9	the	the	DET
ecletica-511	45	10	metal	metal	NOUN
ecletica-511	45	11	concentration	concentration	NOUN
ecletica-511	45	12	on	on	ADP
ecletica-511	45	13	the	the	DET
ecletica-511	45	14	reaction	reaction	NOUN
ecletica-511	45	15	rate	rate	NOUN
ecletica-511	45	16	,	,	PUNCT
ecletica-511	45	17	where	where	SCONJ
ecletica-511	45	18	the	the	DET
ecletica-511	45	19	concentration	concentration	NOUN
ecletica-511	45	20	of	of	ADP
ecletica-511	45	21	the	the	DET
ecletica-511	45	22	metal	metal	NOUN
ecletica-511	45	23	varied	varied	ADJ
ecletica-511	45	24	from	from	ADP
ecletica-511	45	25	5×10	5×10	NUM
ecletica-511	45	26	-	-	SYM
ecletica-511	45	27	6	6	NUM
ecletica-511	45	28	to	to	ADP
ecletica-511	45	29	8×10	8×10	NUM
ecletica-511	45	30	-	-	SYM
ecletica-511	45	31	5	5	NUM
ecletica-511	45	32	mol	mol	NOUN
ecletica-511	45	33	l-1	l-1	NOUN
ecletica-511	45	34	and	and	CCONJ
ecletica-511	45	35	the	the	DET
ecletica-511	45	36	par	par	NOUN
ecletica-511	45	37	concentration	concentration	NOUN
ecletica-511	45	38	was	be	AUX
ecletica-511	45	39	fixed	fix	VERB
ecletica-511	45	40	near	near	ADP
ecletica-511	45	41	8×10	8×10	NUM
ecletica-511	45	42	-	-	SYM
ecletica-511	45	43	4	4	NUM
ecletica-511	45	44	mol	mol	NOUN
ecletica-511	45	45	l-1	l-1	PROPN
ecletica-511	45	46	.	.	PUNCT
ecletica-511	46	1	series	series	PROPN
ecletica-511	46	2	ii	ii	PROPN
ecletica-511	46	3	:	:	PUNCT
ecletica-511	46	4	to	to	PART
ecletica-511	46	5	study	study	VERB
ecletica-511	46	6	the	the	DET
ecletica-511	46	7	influence	influence	NOUN
ecletica-511	46	8	of	of	ADP
ecletica-511	46	9	par	par	NOUN
ecletica-511	46	10	concentration	concentration	NOUN
ecletica-511	46	11	on	on	ADP
ecletica-511	46	12	the	the	DET
ecletica-511	46	13	reaction	reaction	NOUN
ecletica-511	46	14	rate	rate	NOUN
ecletica-511	46	15	,	,	PUNCT
ecletica-511	46	16	where	where	SCONJ
ecletica-511	46	17	the	the	DET
ecletica-511	46	18	concentration	concentration	NOUN
ecletica-511	46	19	of	of	ADP
ecletica-511	46	20	par	par	NOUN
ecletica-511	46	21	varied	varied	ADJ
ecletica-511	46	22	from	from	ADP
ecletica-511	46	23	4×10	4×10	NUM
ecletica-511	46	24	-	-	SYM
ecletica-511	46	25	5	5	NUM
ecletica-511	46	26	to	to	ADP
ecletica-511	46	27	1×10	1×10	NUM
ecletica-511	46	28	-	-	SYM
ecletica-511	46	29	4	4	NUM
ecletica-511	46	30	mol	mol	NOUN
ecletica-511	46	31	l-1	l-1	NOUN
ecletica-511	46	32	and	and	CCONJ
ecletica-511	46	33	the	the	DET
ecletica-511	46	34	metal	metal	PROPN
ecletica-511	46	35	concentraecl	concentraecl	PROPN
ecletica-511	46	36	.	.	PUNCT
ecletica-511	47	1	quím	quím	PROPN
ecletica-511	47	2	.	.	PUNCT
ecletica-511	47	3	,	,	PUNCT
ecletica-511	47	4	são	são	PROPN
ecletica-511	47	5	paulo	paulo	PROPN
ecletica-511	47	6	,	,	PUNCT
ecletica-511	47	7	28(1	28(1	NOUN
ecletica-511	47	8	):	):	PUNCT
ecletica-511	47	9	55	55	NUM
ecletica-511	47	10	-	-	SYM
ecletica-511	47	11	62	62	NUM
ecletica-511	47	12	,	,	PUNCT
ecletica-511	47	13	2003	2003	NUM
ecletica-511	47	14	57	57	NUM
ecletica-511	47	15	tion	tion	NOUN
ecletica-511	47	16	was	be	AUX
ecletica-511	47	17	fixed	fix	VERB
ecletica-511	47	18	near	near	ADP
ecletica-511	47	19	5×10	5×10	NUM
ecletica-511	47	20	-	-	SYM
ecletica-511	47	21	4	4	NUM
ecletica-511	47	22	mol	mol	ADP
ecletica-511	47	23	l-1	l-1	NOUN
ecletica-511	47	24	.	.	PUNCT
ecletica-511	48	1	in	in	ADP
ecletica-511	48	2	both	both	DET
ecletica-511	48	3	series	series	NOUN
ecletica-511	48	4	,	,	PUNCT
ecletica-511	48	5	both	both	CCONJ
ecletica-511	48	6	sulfate	sulfate	NOUN
ecletica-511	48	7	and	and	CCONJ
ecletica-511	48	8	chloride	chloride	NOUN
ecletica-511	48	9	solutions	solution	NOUN
ecletica-511	48	10	were	be	AUX
ecletica-511	48	11	tested	test	VERB
ecletica-511	48	12	to	to	PART
ecletica-511	48	13	verify	verify	VERB
ecletica-511	48	14	a	a	DET
ecletica-511	48	15	possible	possible	ADJ
ecletica-511	48	16	effect	effect	NOUN
ecletica-511	48	17	of	of	ADP
ecletica-511	48	18	the	the	DET
ecletica-511	48	19	anion	anion	NOUN
ecletica-511	48	20	on	on	ADP
ecletica-511	48	21	the	the	DET
ecletica-511	48	22	kinetics	kinetic	NOUN
ecletica-511	48	23	.	.	PUNCT
ecletica-511	49	1	the	the	DET
ecletica-511	49	2	results	result	NOUN
ecletica-511	49	3	are	be	AUX
ecletica-511	49	4	the	the	DET
ecletica-511	49	5	average	average	NOUN
ecletica-511	49	6	of	of	ADP
ecletica-511	49	7	at	at	ADV
ecletica-511	49	8	least	least	ADV
ecletica-511	49	9	five	five	NUM
ecletica-511	49	10	individual	individual	ADJ
ecletica-511	49	11	determinations	determination	NOUN
ecletica-511	49	12	obtained	obtain	VERB
ecletica-511	49	13	in	in	ADP
ecletica-511	49	14	immediate	immediate	ADJ
ecletica-511	49	15	succession	succession	NOUN
ecletica-511	49	16	.	.	PUNCT
ecletica-511	50	1	the	the	DET
ecletica-511	50	2	reaction	reaction	NOUN
ecletica-511	50	3	rate	rate	NOUN
ecletica-511	50	4	constants	constant	NOUN
ecletica-511	50	5	were	be	AUX
ecletica-511	50	6	determined	determine	VERB
ecletica-511	50	7	considering	consider	VERB
ecletica-511	50	8	the	the	DET
ecletica-511	50	9	initial	initial	ADJ
ecletica-511	50	10	<	<	X
ecletica-511	50	11	20	20	NUM
ecletica-511	50	12	%	%	NOUN
ecletica-511	50	13	of	of	ADP
ecletica-511	50	14	the	the	DET
ecletica-511	50	15	total	total	ADJ
ecletica-511	50	16	variation	variation	NOUN
ecletica-511	50	17	of	of	ADP
ecletica-511	50	18	absorbance	absorbance	NOUN
ecletica-511	50	19	.	.	PUNCT
ecletica-511	51	1	experimental	experimental	ADJ
ecletica-511	51	2	readings	reading	NOUN
ecletica-511	51	3	were	be	AUX
ecletica-511	51	4	taken	take	VERB
ecletica-511	51	5	on	on	ADP
ecletica-511	51	6	an	an	DET
ecletica-511	51	7	interfaced	interfaced	ADJ
ecletica-511	51	8	pc	pc	NOUN
ecletica-511	51	9	and	and	CCONJ
ecletica-511	51	10	rates	rate	NOUN
ecletica-511	51	11	were	be	AUX
ecletica-511	51	12	calculated	calculate	VERB
ecletica-511	51	13	using	use	VERB
ecletica-511	51	14	a	a	DET
ecletica-511	51	15	program	program	NOUN
ecletica-511	51	16	in	in	ADP
ecletica-511	51	17	quickbasic	quickbasic	PROPN
ecletica-511	51	18	3.0	3.0	NUM
ecletica-511	51	19	especially	especially	ADV
ecletica-511	51	20	developed	develop	VERB
ecletica-511	51	21	for	for	ADP
ecletica-511	51	22	this	this	DET
ecletica-511	51	23	work	work	NOUN
ecletica-511	51	24	,	,	PUNCT
ecletica-511	51	25	including	include	VERB
ecletica-511	51	26	unweighted	unweighte	VERB
ecletica-511	51	27	-	-	PUNCT
ecletica-511	51	28	average	average	ADJ
ecletica-511	51	29	smoothing	smoothing	NOUN
ecletica-511	51	30	.	.	PUNCT
ecletica-511	52	1	the	the	DET
ecletica-511	52	2	stopped	stop	VERB
ecletica-511	52	3	-	-	PUNCT
ecletica-511	52	4	flow	flow	NOUN
ecletica-511	52	5	experiments	experiment	NOUN
ecletica-511	52	6	were	be	AUX
ecletica-511	52	7	done	do	VERB
ecletica-511	52	8	with	with	ADP
ecletica-511	52	9	the	the	DET
ecletica-511	52	10	par	par	NOUN
ecletica-511	52	11	solutions	solution	NOUN
ecletica-511	52	12	buffered	buffer	VERB
ecletica-511	52	13	at	at	ADP
ecletica-511	52	14	ph	ph	NOUN
ecletica-511	52	15	=	=	SYM
ecletica-511	52	16	8.5	8.5	NUM
ecletica-511	52	17	and	and	CCONJ
ecletica-511	52	18	an	an	DET
ecletica-511	52	19	ionic	ionic	ADJ
ecletica-511	52	20	strength	strength	NOUN
ecletica-511	52	21	of	of	ADP
ecletica-511	52	22	1.00	1.00	NUM
ecletica-511	52	23	mol	mol	ADP
ecletica-511	52	24	l-1	l-1	PROPN
ecletica-511	52	25	(	(	PUNCT
ecletica-511	52	26	kcl	kcl	PROPN
ecletica-511	52	27	)	)	PUNCT
ecletica-511	52	28	.	.	PUNCT
ecletica-511	53	1	the	the	DET
ecletica-511	53	2	zn2	zn2	PROPN
ecletica-511	53	3	+	+	PROPN
ecletica-511	53	4	and	and	CCONJ
ecletica-511	53	5	cu2	cu2	NOUN
ecletica-511	53	6	+	+	NOUN
ecletica-511	53	7	solutions	solution	NOUN
ecletica-511	53	8	were	be	AUX
ecletica-511	53	9	prepared	prepare	VERB
ecletica-511	53	10	only	only	ADV
ecletica-511	53	11	with	with	ADP
ecletica-511	53	12	distilled	distil	VERB
ecletica-511	53	13	water	water	NOUN
ecletica-511	53	14	and	and	CCONJ
ecletica-511	53	15	enough	enough	ADJ
ecletica-511	53	16	kcl	kcl	NOUN
ecletica-511	53	17	to	to	PART
ecletica-511	53	18	obtain	obtain	VERB
ecletica-511	53	19	the	the	DET
ecletica-511	53	20	desired	desire	VERB
ecletica-511	53	21	ionic	ionic	ADJ
ecletica-511	53	22	strength	strength	NOUN
ecletica-511	53	23	.	.	PUNCT
ecletica-511	54	1	no	no	DET
ecletica-511	54	2	precipitation	precipitation	NOUN
ecletica-511	54	3	was	be	AUX
ecletica-511	54	4	observed	observe	VERB
ecletica-511	54	5	during	during	ADP
ecletica-511	54	6	the	the	DET
ecletica-511	54	7	course	course	NOUN
ecletica-511	54	8	of	of	ADP
ecletica-511	54	9	these	these	DET
ecletica-511	54	10	experiments	experiment	NOUN
ecletica-511	54	11	.	.	PUNCT
ecletica-511	55	1	results	result	NOUN
ecletica-511	55	2	and	and	CCONJ
ecletica-511	55	3	discussion	discussion	VERB
ecletica-511	55	4	the	the	DET
ecletica-511	55	5	electronic	electronic	ADJ
ecletica-511	55	6	spectra	spectra	NOUN
ecletica-511	55	7	of	of	ADP
ecletica-511	55	8	the	the	DET
ecletica-511	55	9	aqueous	aqueous	ADJ
ecletica-511	55	10	solutions	solution	NOUN
ecletica-511	55	11	of	of	ADP
ecletica-511	55	12	par	par	NOUN
ecletica-511	55	13	complexes	complex	NOUN
ecletica-511	55	14	,	,	PUNCT
ecletica-511	55	15	m(hl)2	m(hl)2	PROPN
ecletica-511	55	16	,	,	PUNCT
ecletica-511	55	17	where	where	SCONJ
ecletica-511	55	18	m	m	PROPN
ecletica-511	55	19	is	be	AUX
ecletica-511	55	20	zn	zn	PROPN
ecletica-511	55	21	2	2	NUM
ecletica-511	55	22	+	+	PROPN
ecletica-511	55	23	,	,	PUNCT
ecletica-511	55	24	cu2	cu2	NOUN
ecletica-511	55	25	+	+	CCONJ
ecletica-511	55	26	and	and	CCONJ
ecletica-511	55	27	zn2++	zn2++	NOUN
ecletica-511	55	28	cu2	cu2	VERB
ecletica-511	55	29	+	+	CCONJ
ecletica-511	55	30	equimolar	equimolar	ADJ
ecletica-511	55	31	mixture	mixture	NOUN
ecletica-511	55	32	are	be	AUX
ecletica-511	55	33	shown	show	VERB
ecletica-511	55	34	in	in	ADP
ecletica-511	55	35	figure	figure	NOUN
ecletica-511	55	36	1	1	NUM
ecletica-511	55	37	electronic	electronic	ADJ
ecletica-511	55	38	spectra	spectra	NOUN
ecletica-511	55	39	of	of	ADP
ecletica-511	55	40	aqueous	aqueous	ADJ
ecletica-511	55	41	solutions	solution	NOUN
ecletica-511	55	42	of	of	ADP
ecletica-511	55	43	(	(	PUNCT
ecletica-511	55	44	a	a	NOUN
ecletica-511	55	45	)	)	PUNCT
ecletica-511	56	1	[	[	X
ecletica-511	56	2	cu(hl)2	cu(hl)2	X
ecletica-511	56	3	]	]	X
ecletica-511	56	4	2.96	2.96	NUM
ecletica-511	56	5	x	x	SYM
ecletica-511	56	6	10	10	NUM
ecletica-511	56	7	-	-	SYM
ecletica-511	56	8	5	5	NUM
ecletica-511	56	9	mol	mol	ADP
ecletica-511	56	10	l-1	l-1	NUM
ecletica-511	56	11	;	;	PUNCT
ecletica-511	56	12	(	(	PUNCT
ecletica-511	56	13	b	b	X
ecletica-511	56	14	)	)	PUNCT
ecletica-511	56	15	mixture	mixture	NOUN
ecletica-511	56	16	[	[	X
ecletica-511	56	17	(	(	PUNCT
ecletica-511	56	18	zn+cu)(hl)2	zn+cu)(hl)2	NOUN
ecletica-511	56	19	]	]	X
ecletica-511	56	20	(	(	PUNCT
ecletica-511	56	21	1.50	1.50	NUM
ecletica-511	56	22	+	+	NOUN
ecletica-511	56	23	1.50)×10	1.50)×10	NOUN
ecletica-511	56	24	-	-	SYM
ecletica-511	56	25	5	5	NUM
ecletica-511	56	26	mol	mol	ADP
ecletica-511	56	27	l-1	l-1	NUM
ecletica-511	56	28	;	;	PUNCT
ecletica-511	56	29	(	(	PUNCT
ecletica-511	56	30	c	c	X
ecletica-511	56	31	)	)	PUNCT
ecletica-511	57	1	[	[	X
ecletica-511	57	2	zn(hl)2	zn(hl)2	X
ecletica-511	57	3	]	]	X
ecletica-511	57	4	3.03×10	3.03×10	X
ecletica-511	57	5	-	-	SYM
ecletica-511	57	6	5	5	NUM
ecletica-511	57	7	mol	mol	ADP
ecletica-511	57	8	l-1	l-1	PROPN
ecletica-511	57	9	.	.	PUNCT
ecletica-511	58	1	distilled	distil	VERB
ecletica-511	58	2	water	water	NOUN
ecletica-511	58	3	was	be	AUX
ecletica-511	58	4	used	use	VERB
ecletica-511	58	5	as	as	ADP
ecletica-511	58	6	reference	reference	NOUN
ecletica-511	58	7	.	.	PUNCT
ecletica-511	59	1	the	the	DET
ecletica-511	59	2	values	value	NOUN
ecletica-511	59	3	of	of	ADP
ecletica-511	59	4	the	the	DET
ecletica-511	59	5	molar	molar	ADJ
ecletica-511	59	6	absorptivity	absorptivity	NOUN
ecletica-511	59	7	,	,	PUNCT
ecletica-511	59	8	ε	ε	PROPN
ecletica-511	59	9	,	,	PUNCT
ecletica-511	59	10	were	be	AUX
ecletica-511	59	11	calculated	calculate	VERB
ecletica-511	59	12	at	at	ADP
ecletica-511	59	13	500	500	NUM
ecletica-511	59	14	nm	nm	NOUN
ecletica-511	59	15	,	,	PUNCT
ecletica-511	59	16	for	for	ADP
ecletica-511	59	17	the	the	DET
ecletica-511	59	18	m(hl)2	m(hl)2	PROPN
ecletica-511	59	19	complexes	complex	NOUN
ecletica-511	59	20	and	and	CCONJ
ecletica-511	59	21	they	they	PRON
ecletica-511	59	22	are	be	AUX
ecletica-511	59	23	presented	present	VERB
ecletica-511	59	24	in	in	ADP
ecletica-511	59	25	table	table	NOUN
ecletica-511	59	26	1	1	NUM
ecletica-511	59	27	.	.	PUNCT
ecletica-511	60	1	it	it	PRON
ecletica-511	60	2	is	be	AUX
ecletica-511	60	3	noted	note	VERB
ecletica-511	60	4	that	that	SCONJ
ecletica-511	60	5	the	the	DET
ecletica-511	60	6	molar	molar	ADJ
ecletica-511	60	7	absorptivity	absorptivity	NOUN
ecletica-511	60	8	of	of	ADP
ecletica-511	60	9	the	the	DET
ecletica-511	60	10	zn2	zn2	PROPN
ecletica-511	60	11	+	+	PROPN
ecletica-511	60	12	+	+	NUM
ecletica-511	60	13	cu2	cu2	ADJ
ecletica-511	60	14	+	+	CCONJ
ecletica-511	60	15	equimolar	equimolar	ADJ
ecletica-511	60	16	mixture	mixture	NOUN
ecletica-511	60	17	complex	complex	NOUN
ecletica-511	60	18	is	be	AUX
ecletica-511	60	19	not	not	PART
ecletica-511	60	20	the	the	DET
ecletica-511	60	21	mean	mean	NOUN
ecletica-511	60	22	of	of	ADP
ecletica-511	60	23	the	the	DET
ecletica-511	60	24	two	two	NUM
ecletica-511	60	25	independent	independent	ADJ
ecletica-511	60	26	complexes	complex	NOUN
ecletica-511	60	27	of	of	ADP
ecletica-511	60	28	copper	copper	NOUN
ecletica-511	60	29	and	and	CCONJ
ecletica-511	60	30	of	of	ADP
ecletica-511	60	31	zinc	zinc	NOUN
ecletica-511	60	32	but	but	CCONJ
ecletica-511	60	33	is	be	AUX
ecletica-511	60	34	closer	close	ADJ
ecletica-511	60	35	to	to	ADP
ecletica-511	60	36	that	that	PRON
ecletica-511	60	37	of	of	ADP
ecletica-511	60	38	the	the	DET
ecletica-511	60	39	copper	copper	NOUN
ecletica-511	60	40	complex	complex	NOUN
ecletica-511	60	41	.	.	PUNCT
ecletica-511	61	1	this	this	PRON
ecletica-511	61	2	is	be	AUX
ecletica-511	61	3	confirmed	confirm	VERB
ecletica-511	61	4	by	by	ADP
ecletica-511	61	5	inspection	inspection	NOUN
ecletica-511	61	6	of	of	ADP
ecletica-511	61	7	the	the	DET
ecletica-511	61	8	spectrum	spectrum	NOUN
ecletica-511	61	9	of	of	ADP
ecletica-511	61	10	the	the	DET
ecletica-511	61	11	equimolar	equimolar	NOUN
ecletica-511	61	12	zn2++	zn2++	NOUN
ecletica-511	61	13	cu2	cu2	NOUN
ecletica-511	62	1	+	+	CCONJ
ecletica-511	62	2	mixture	mixture	NOUN
ecletica-511	62	3	par	par	NOUN
ecletica-511	62	4	complex	complex	NOUN
ecletica-511	62	5	(	(	PUNCT
ecletica-511	62	6	figure	figure	NOUN
ecletica-511	62	7	1	1	NUM
ecletica-511	62	8	)	)	PUNCT
ecletica-511	62	9	which	which	PRON
ecletica-511	62	10	resembles	resemble	VERB
ecletica-511	62	11	to	to	ADP
ecletica-511	62	12	that	that	PRON
ecletica-511	62	13	of	of	ADP
ecletica-511	62	14	cu2	cu2	NOUN
ecletica-511	62	15	+	+	X
ecletica-511	62	16	complex	complex	ADJ
ecletica-511	62	17	.	.	PUNCT
ecletica-511	63	1	this	this	PRON
ecletica-511	63	2	suggests	suggest	VERB
ecletica-511	63	3	that	that	SCONJ
ecletica-511	63	4	cu2	cu2	NOUN
ecletica-511	63	5	+	+	CCONJ
ecletica-511	63	6	presents	present	VERB
ecletica-511	63	7	a	a	DET
ecletica-511	63	8	higher	high	ADJ
ecletica-511	63	9	influence	influence	NOUN
ecletica-511	63	10	on	on	ADP
ecletica-511	63	11	the	the	DET
ecletica-511	63	12	structure	structure	NOUN
ecletica-511	63	13	of	of	ADP
ecletica-511	63	14	the	the	DET
ecletica-511	63	15	complex	complex	NOUN
ecletica-511	63	16	than	than	ADP
ecletica-511	63	17	zn2	zn2	PROPN
ecletica-511	63	18	+	+	PROPN
ecletica-511	63	19	and	and	CCONJ
ecletica-511	63	20	,	,	PUNCT
ecletica-511	63	21	as	as	ADP
ecletica-511	63	22	a	a	DET
ecletica-511	63	23	consequence	consequence	NOUN
ecletica-511	63	24	,	,	PUNCT
ecletica-511	63	25	this	this	DET
ecletica-511	63	26	cation	cation	NOUN
ecletica-511	63	27	should	should	AUX
ecletica-511	63	28	influence	influence	VERB
ecletica-511	63	29	the	the	DET
ecletica-511	63	30	kinetic	kinetic	ADJ
ecletica-511	63	31	behavior	behavior	NOUN
ecletica-511	63	32	of	of	ADP
ecletica-511	63	33	the	the	DET
ecletica-511	63	34	mixture	mixture	NOUN
ecletica-511	63	35	more	more	ADJ
ecletica-511	63	36	than	than	ADP
ecletica-511	63	37	zn2	zn2	PROPN
ecletica-511	63	38	+	+	PROPN
ecletica-511	63	39	.	.	NOUN
ecletica-511	63	40	table	table	NOUN
ecletica-511	63	41	1	1	NUM
ecletica-511	63	42	.	.	PUNCT
ecletica-511	63	43	molar	molar	ADJ
ecletica-511	63	44	absorptivity	absorptivity	NOUN
ecletica-511	63	45	of	of	ADP
ecletica-511	63	46	cu2	cu2	PROPN
ecletica-511	63	47	+	+	PROPN
ecletica-511	63	48	,	,	PUNCT
ecletica-511	63	49	zn2	zn2	PROPN
ecletica-511	63	50	+	+	PROPN
ecletica-511	63	51	and	and	CCONJ
ecletica-511	63	52	zn2++	zn2++	NOUN
ecletica-511	63	53	cu2	cu2	PROPN
ecletica-511	63	54	+	+	CCONJ
ecletica-511	63	55	complexes	complex	NOUN
ecletica-511	63	56	with	with	ADP
ecletica-511	63	57	monoprotonated	monoprotonate	VERB
ecletica-511	63	58	par	par	NOUN
ecletica-511	63	59	,	,	PUNCT
ecletica-511	63	60	hl-	hl-	INTJ
ecletica-511	63	61	,	,	PUNCT
ecletica-511	63	62	in	in	ADP
ecletica-511	63	63	aqueous	aqueous	ADJ
ecletica-511	63	64	solution	solution	NOUN
ecletica-511	63	65	;	;	PUNCT
ecletica-511	63	66	ph	ph	PROPN
ecletica-511	63	67	=	=	SYM
ecletica-511	63	68	8.5	8.5	NUM
ecletica-511	63	69	(	(	PUNCT
ecletica-511	63	70	borate	borate	NOUN
ecletica-511	63	71	buffer	buffer	NOUN
ecletica-511	63	72	)	)	PUNCT
ecletica-511	63	73	tables	table	NOUN
ecletica-511	63	74	2	2	NUM
ecletica-511	63	75	to	to	PART
ecletica-511	63	76	7	7	NUM
ecletica-511	63	77	show	show	VERB
ecletica-511	63	78	the	the	DET
ecletica-511	63	79	experimental	experimental	ADJ
ecletica-511	63	80	rates	rate	NOUN
ecletica-511	63	81	obtained	obtain	VERB
ecletica-511	63	82	from	from	ADP
ecletica-511	63	83	the	the	DET
ecletica-511	63	84	kinetic	kinetic	ADJ
ecletica-511	63	85	experiments	experiment	NOUN
ecletica-511	63	86	at	at	ADP
ecletica-511	63	87	the	the	DET
ecletica-511	63	88	indicated	indicate	VERB
ecletica-511	63	89	concentrations	concentration	NOUN
ecletica-511	63	90	of	of	ADP
ecletica-511	63	91	reagents	reagent	NOUN
ecletica-511	63	92	.	.	PUNCT
ecletica-511	64	1	it	it	PRON
ecletica-511	64	2	can	can	AUX
ecletica-511	64	3	be	be	AUX
ecletica-511	64	4	observed	observe	VERB
ecletica-511	64	5	that	that	SCONJ
ecletica-511	64	6	the	the	DET
ecletica-511	64	7	reaction	reaction	NOUN
ecletica-511	64	8	rate	rate	NOUN
ecletica-511	64	9	increases	increase	VERB
ecletica-511	64	10	with	with	ADP
ecletica-511	64	11	the	the	DET
ecletica-511	64	12	increasing	increasing	NOUN
ecletica-511	64	13	of	of	ADP
ecletica-511	64	14	the	the	DET
ecletica-511	64	15	concentration	concentration	NOUN
ecletica-511	64	16	of	of	ADP
ecletica-511	64	17	the	the	DET
ecletica-511	64	18	reagents	reagent	NOUN
ecletica-511	64	19	.	.	PUNCT
ecletica-511	65	1	the	the	DET
ecletica-511	65	2	reaction	reaction	NOUN
ecletica-511	65	3	rate	rate	NOUN
ecletica-511	65	4	constants	constant	NOUN
ecletica-511	65	5	and	and	CCONJ
ecletica-511	65	6	the	the	DET
ecletica-511	65	7	order	order	NOUN
ecletica-511	65	8	of	of	ADP
ecletica-511	65	9	reaction	reaction	NOUN
ecletica-511	65	10	were	be	AUX
ecletica-511	65	11	determined	determine	VERB
ecletica-511	65	12	from	from	ADP
ecletica-511	65	13	these	these	DET
ecletica-511	65	14	data	datum	NOUN
ecletica-511	65	15	.	.	PUNCT
ecletica-511	66	1	the	the	DET
ecletica-511	66	2	data	datum	NOUN
ecletica-511	66	3	fit	fit	VERB
ecletica-511	66	4	a	a	DET
ecletica-511	66	5	first	first	ADJ
ecletica-511	66	6	order	order	NOUN
ecletica-511	66	7	rate	rate	NOUN
ecletica-511	66	8	treatment	treatment	NOUN
ecletica-511	66	9	with	with	ADP
ecletica-511	66	10	respect	respect	NOUN
ecletica-511	66	11	to	to	ADP
ecletica-511	66	12	each	each	DET
ecletica-511	66	13	reagent	reagent	NOUN
ecletica-511	66	14	in	in	ADP
ecletica-511	66	15	the	the	DET
ecletica-511	66	16	concentration	concentration	NOUN
ecletica-511	66	17	range	range	NOUN
ecletica-511	66	18	studied	study	VERB
ecletica-511	66	19	.	.	PUNCT
ecletica-511	67	1	table	table	NOUN
ecletica-511	67	2	2	2	NUM
ecletica-511	67	3	:	:	PUNCT
ecletica-511	67	4	initial	initial	ADJ
ecletica-511	67	5	reaction	reaction	NOUN
ecletica-511	67	6	rates	rate	NOUN
ecletica-511	67	7	for	for	ADP
ecletica-511	67	8	aqueous	aqueous	ADJ
ecletica-511	67	9	cucl2	cucl2	NOUN
ecletica-511	67	10	and	and	CCONJ
ecletica-511	67	11	cuso4	cuso4	NOUN
ecletica-511	67	12	solutions	solution	NOUN
ecletica-511	67	13	with	with	ADP
ecletica-511	67	14	aqueous	aqueous	ADJ
ecletica-511	67	15	monoprotonated	monoprotonate	VERB
ecletica-511	67	16	par	par	NOUN
ecletica-511	67	17	,	,	PUNCT
ecletica-511	67	18	hl-	hl-	INTJ
ecletica-511	67	19	,	,	PUNCT
ecletica-511	67	20	solutions	solution	NOUN
ecletica-511	67	21	,	,	PUNCT
ecletica-511	67	22	at	at	ADP
ecletica-511	67	23	25.0±0.1	25.0±0.1	NUM
ecletica-511	67	24	°	°	ADP
ecletica-511	67	25	c	c	NOUN
ecletica-511	67	26	,	,	PUNCT
ecletica-511	67	27	in	in	ADP
ecletica-511	67	28	borate	borate	NOUN
ecletica-511	67	29	buffer	buffer	NOUN
ecletica-511	67	30	,	,	PUNCT
ecletica-511	67	31	ph	ph	NOUN
ecletica-511	67	32	=	=	SYM
ecletica-511	67	33	8.5	8.5	NUM
ecletica-511	67	34	.	.	PUNCT
ecletica-511	68	1	ecl	ecl	PROPN
ecletica-511	68	2	.	.	PROPN
ecletica-511	68	3	quím	quím	PROPN
ecletica-511	68	4	.	.	PUNCT
ecletica-511	69	1	,	,	PUNCT
ecletica-511	69	2	são	são	PROPN
ecletica-511	69	3	paulo	paulo	PROPN
ecletica-511	69	4	,	,	PUNCT
ecletica-511	69	5	28(1	28(1	NOUN
ecletica-511	69	6	):	):	PUNCT
ecletica-511	69	7	55	55	NUM
ecletica-511	69	8	-	-	SYM
ecletica-511	69	9	62	62	NUM
ecletica-511	69	10	,	,	PUNCT
ecletica-511	69	11	2003	2003	NUM
ecletica-511	69	12	58	58	NUM
ecletica-511	69	13	table	table	NOUN
ecletica-511	69	14	3	3	NUM
ecletica-511	69	15	:	:	PUNCT
ecletica-511	69	16	initial	initial	ADJ
ecletica-511	69	17	reaction	reaction	NOUN
ecletica-511	69	18	rates	rate	NOUN
ecletica-511	69	19	for	for	ADP
ecletica-511	69	20	aqueous	aqueous	ADJ
ecletica-511	69	21	zncl2	zncl2	NOUN
ecletica-511	69	22	and	and	CCONJ
ecletica-511	69	23	znso4	znso4	NOUN
ecletica-511	69	24	solutions	solution	NOUN
ecletica-511	69	25	with	with	ADP
ecletica-511	69	26	aqueous	aqueous	ADJ
ecletica-511	69	27	monoprotonated	monoprotonate	VERB
ecletica-511	69	28	par	par	NOUN
ecletica-511	69	29	,	,	PUNCT
ecletica-511	69	30	hl-	hl-	INTJ
ecletica-511	69	31	,	,	PUNCT
ecletica-511	69	32	solutions	solution	NOUN
ecletica-511	69	33	,	,	PUNCT
ecletica-511	69	34	at	at	ADP
ecletica-511	69	35	25.0±0.1	25.0±0.1	NUM
ecletica-511	69	36	°	°	ADP
ecletica-511	69	37	c	c	NOUN
ecletica-511	69	38	,	,	PUNCT
ecletica-511	69	39	in	in	ADP
ecletica-511	69	40	borate	borate	NOUN
ecletica-511	69	41	buffer	buffer	NOUN
ecletica-511	69	42	,	,	PUNCT
ecletica-511	69	43	ph	ph	NOUN
ecletica-511	69	44	=	=	SYM
ecletica-511	69	45	8.5	8.5	NUM
ecletica-511	69	46	.	.	PUNCT
ecletica-511	69	47	table	table	NOUN
ecletica-511	69	48	4	4	NUM
ecletica-511	69	49	:	:	PUNCT
ecletica-511	69	50	initial	initial	ADJ
ecletica-511	69	51	rate	rate	NOUN
ecletica-511	69	52	reaction	reaction	NOUN
ecletica-511	69	53	for	for	ADP
ecletica-511	69	54	aqueous	aqueous	ADJ
ecletica-511	69	55	cucl2	cucl2	NOUN
ecletica-511	69	56	+	+	CCONJ
ecletica-511	69	57	zncl2	zncl2	NOUN
ecletica-511	69	58	solutions	solution	NOUN
ecletica-511	69	59	with	with	ADP
ecletica-511	69	60	aqueous	aqueous	ADJ
ecletica-511	69	61	monoprotonated	monoprotonate	VERB
ecletica-511	69	62	par	par	NOUN
ecletica-511	69	63	,	,	PUNCT
ecletica-511	69	64	hl-	hl-	INTJ
ecletica-511	69	65	,	,	PUNCT
ecletica-511	69	66	solutions	solution	NOUN
ecletica-511	69	67	,	,	PUNCT
ecletica-511	69	68	at	at	ADP
ecletica-511	69	69	25.0±0.1	25.0±0.1	NUM
ecletica-511	69	70	°	°	ADP
ecletica-511	69	71	c	c	NOUN
ecletica-511	69	72	,	,	PUNCT
ecletica-511	69	73	in	in	ADP
ecletica-511	69	74	borate	borate	NOUN
ecletica-511	69	75	buffer	buffer	NOUN
ecletica-511	69	76	,	,	PUNCT
ecletica-511	69	77	ph	ph	NOUN
ecletica-511	69	78	=	=	SYM
ecletica-511	69	79	8.5	8.5	NUM
ecletica-511	69	80	.	.	PUNCT
ecletica-511	69	81	table	table	NOUN
ecletica-511	69	82	5	5	NUM
ecletica-511	69	83	:	:	PUNCT
ecletica-511	69	84	initial	initial	ADJ
ecletica-511	69	85	rate	rate	NOUN
ecletica-511	69	86	reaction	reaction	NOUN
ecletica-511	69	87	for	for	ADP
ecletica-511	69	88	aqueous	aqueous	ADJ
ecletica-511	69	89	cuso4	cuso4	NOUN
ecletica-511	69	90	+	+	CCONJ
ecletica-511	69	91	zncl2	zncl2	NOUN
ecletica-511	69	92	solutions	solution	NOUN
ecletica-511	69	93	with	with	ADP
ecletica-511	69	94	aqueous	aqueous	ADJ
ecletica-511	69	95	monoprotonated	monoprotonate	VERB
ecletica-511	69	96	par	par	NOUN
ecletica-511	69	97	,	,	PUNCT
ecletica-511	69	98	hl-	hl-	INTJ
ecletica-511	69	99	,	,	PUNCT
ecletica-511	69	100	solutions	solution	NOUN
ecletica-511	69	101	,	,	PUNCT
ecletica-511	69	102	at	at	ADP
ecletica-511	69	103	25.0±0.1	25.0±0.1	NUM
ecletica-511	69	104	°	°	ADP
ecletica-511	69	105	c	c	NOUN
ecletica-511	69	106	,	,	PUNCT
ecletica-511	69	107	in	in	ADP
ecletica-511	69	108	borate	borate	NOUN
ecletica-511	69	109	buffer	buffer	NOUN
ecletica-511	69	110	,	,	PUNCT
ecletica-511	69	111	ph	ph	NOUN
ecletica-511	69	112	=	=	SYM
ecletica-511	69	113	8.5	8.5	NUM
ecletica-511	69	114	.	.	PUNCT
ecletica-511	69	115	table	table	NOUN
ecletica-511	69	116	6	6	NUM
ecletica-511	69	117	:	:	PUNCT
ecletica-511	69	118	initial	initial	ADJ
ecletica-511	69	119	rate	rate	NOUN
ecletica-511	69	120	reaction	reaction	NOUN
ecletica-511	69	121	for	for	ADP
ecletica-511	69	122	aqueous	aqueous	ADJ
ecletica-511	69	123	cucl2	cucl2	NOUN
ecletica-511	69	124	+	+	CCONJ
ecletica-511	69	125	znso4	znso4	NOUN
ecletica-511	69	126	solutions	solution	NOUN
ecletica-511	69	127	with	with	ADP
ecletica-511	69	128	aqueous	aqueous	ADJ
ecletica-511	69	129	monoprotonated	monoprotonate	VERB
ecletica-511	69	130	par	par	NOUN
ecletica-511	69	131	,	,	PUNCT
ecletica-511	69	132	hl-	hl-	INTJ
ecletica-511	69	133	,	,	PUNCT
ecletica-511	69	134	solutions	solution	NOUN
ecletica-511	69	135	,	,	PUNCT
ecletica-511	69	136	at	at	ADP
ecletica-511	69	137	25.0±0.1	25.0±0.1	NUM
ecletica-511	69	138	°	°	ADP
ecletica-511	69	139	c	c	NOUN
ecletica-511	69	140	,	,	PUNCT
ecletica-511	69	141	in	in	ADP
ecletica-511	69	142	borate	borate	NOUN
ecletica-511	69	143	buffer	buffer	NOUN
ecletica-511	69	144	,	,	PUNCT
ecletica-511	69	145	ph	ph	NOUN
ecletica-511	69	146	=	=	SYM
ecletica-511	69	147	8.5	8.5	NUM
ecletica-511	69	148	.	.	PUNCT
ecletica-511	69	149	table	table	NOUN
ecletica-511	69	150	7	7	NUM
ecletica-511	69	151	:	:	PUNCT
ecletica-511	69	152	initial	initial	ADJ
ecletica-511	69	153	rate	rate	NOUN
ecletica-511	69	154	reaction	reaction	NOUN
ecletica-511	69	155	for	for	ADP
ecletica-511	69	156	aqueous	aqueous	ADJ
ecletica-511	69	157	cuso4	cuso4	NOUN
ecletica-511	70	1	+	+	CCONJ
ecletica-511	70	2	znso4	znso4	NOUN
ecletica-511	70	3	solutions	solution	NOUN
ecletica-511	70	4	with	with	ADP
ecletica-511	70	5	aqueous	aqueous	ADJ
ecletica-511	70	6	monoprotonated	monoprotonate	VERB
ecletica-511	70	7	par	par	NOUN
ecletica-511	70	8	,	,	PUNCT
ecletica-511	70	9	hl-	hl-	INTJ
ecletica-511	70	10	,	,	PUNCT
ecletica-511	70	11	solutions	solution	NOUN
ecletica-511	70	12	,	,	PUNCT
ecletica-511	70	13	at	at	ADP
ecletica-511	70	14	25.0±0.1	25.0±0.1	NUM
ecletica-511	70	15	°	°	ADP
ecletica-511	70	16	c	c	NOUN
ecletica-511	70	17	,	,	PUNCT
ecletica-511	70	18	in	in	ADP
ecletica-511	70	19	borate	borate	NOUN
ecletica-511	70	20	buffer	buffer	NOUN
ecletica-511	70	21	,	,	PUNCT
ecletica-511	70	22	ph	ph	NOUN
ecletica-511	70	23	=	=	SYM
ecletica-511	70	24	8.5	8.5	NUM
ecletica-511	70	25	.	.	PUNCT
ecletica-511	71	1	ecl	ecl	PROPN
ecletica-511	71	2	.	.	PROPN
ecletica-511	71	3	quím	quím	PROPN
ecletica-511	71	4	.	.	PUNCT
ecletica-511	72	1	,	,	PUNCT
ecletica-511	72	2	são	são	PROPN
ecletica-511	72	3	paulo	paulo	PROPN
ecletica-511	72	4	,	,	PUNCT
ecletica-511	72	5	28(1	28(1	NOUN
ecletica-511	72	6	):	):	PUNCT
ecletica-511	72	7	55	55	NUM
ecletica-511	72	8	-	-	SYM
ecletica-511	72	9	62	62	NUM
ecletica-511	72	10	,	,	PUNCT
ecletica-511	72	11	2003	2003	NUM
ecletica-511	72	12	59	59	NUM
ecletica-511	72	13	the	the	DET
ecletica-511	72	14	monitored	monitor	VERB
ecletica-511	72	15	species	specie	NOUN
ecletica-511	72	16	,	,	PUNCT
ecletica-511	72	17	m(hl)2	m(hl)2	PROPN
ecletica-511	72	18	,	,	PUNCT
ecletica-511	72	19	is	be	AUX
ecletica-511	72	20	the	the	DET
ecletica-511	72	21	product	product	NOUN
ecletica-511	72	22	of	of	ADP
ecletica-511	72	23	the	the	DET
ecletica-511	72	24	reaction	reaction	NOUN
ecletica-511	72	25	whose	whose	DET
ecletica-511	72	26	concentrations	concentration	NOUN
ecletica-511	72	27	can	can	AUX
ecletica-511	72	28	be	be	AUX
ecletica-511	72	29	directly	directly	ADV
ecletica-511	72	30	associated	associate	VERB
ecletica-511	72	31	to	to	ADP
ecletica-511	72	32	the	the	DET
ecletica-511	72	33	consumption	consumption	NOUN
ecletica-511	72	34	of	of	ADP
ecletica-511	72	35	the	the	DET
ecletica-511	72	36	less	less	ADV
ecletica-511	72	37	concentrated	concentrated	ADJ
ecletica-511	72	38	reagent	reagent	NOUN
ecletica-511	72	39	,	,	PUNCT
ecletica-511	72	40	a	a	DET
ecletica-511	72	41	=	=	X
ecletica-511	72	42	ligand	ligand	ADJ
ecletica-511	72	43	or	or	CCONJ
ecletica-511	72	44	metal	metal	NOUN
ecletica-511	72	45	cation	cation	NOUN
ecletica-511	72	46	.	.	PUNCT
ecletica-511	73	1	the	the	DET
ecletica-511	73	2	excess	excess	ADJ
ecletica-511	73	3	reagent	reagent	ADJ
ecletica-511	73	4	concentration	concentration	NOUN
ecletica-511	73	5	,	,	PUNCT
ecletica-511	73	6	b	b	NOUN
ecletica-511	73	7	,	,	PUNCT
ecletica-511	73	8	can	can	AUX
ecletica-511	73	9	be	be	AUX
ecletica-511	73	10	assumed	assume	VERB
ecletica-511	73	11	as	as	ADP
ecletica-511	73	12	constant	constant	ADJ
ecletica-511	73	13	during	during	ADP
ecletica-511	73	14	the	the	DET
ecletica-511	73	15	reaction	reaction	NOUN
ecletica-511	73	16	,	,	PUNCT
ecletica-511	73	17	so	so	CCONJ
ecletica-511	73	18	its	its	PRON
ecletica-511	73	19	value	value	NOUN
ecletica-511	73	20	can	can	AUX
ecletica-511	73	21	be	be	AUX
ecletica-511	73	22	included	include	VERB
ecletica-511	73	23	in	in	ADP
ecletica-511	73	24	the	the	DET
ecletica-511	73	25	observed	observe	VERB
ecletica-511	73	26	constant	constant	ADJ
ecletica-511	73	27	.	.	PUNCT
ecletica-511	74	1	considering	consider	VERB
ecletica-511	74	2	that	that	SCONJ
ecletica-511	74	3	the	the	DET
ecletica-511	74	4	reaction	reaction	NOUN
ecletica-511	74	5	is	be	AUX
ecletica-511	74	6	overall	overall	ADJ
ecletica-511	74	7	second	second	ADJ
ecletica-511	74	8	order	order	NOUN
ecletica-511	74	9	and	and	CCONJ
ecletica-511	74	10	that	that	SCONJ
ecletica-511	74	11	the	the	DET
ecletica-511	74	12	rate	rate	NOUN
ecletica-511	74	13	equation	equation	NOUN
ecletica-511	74	14	obeys	obey	VERB
ecletica-511	74	15	a	a	DET
ecletica-511	74	16	first	first	ADJ
ecletica-511	74	17	order	order	NOUN
ecletica-511	74	18	law	law	NOUN
ecletica-511	74	19	with	with	ADP
ecletica-511	74	20	respect	respect	NOUN
ecletica-511	74	21	to	to	ADP
ecletica-511	74	22	each	each	DET
ecletica-511	74	23	reagent	reagent	NOUN
ecletica-511	74	24	,	,	PUNCT
ecletica-511	74	25	cation	cation	NOUN
ecletica-511	74	26	or	or	CCONJ
ecletica-511	74	27	ligand	ligand	NOUN
ecletica-511	74	28	,	,	PUNCT
ecletica-511	74	29	it	it	PRON
ecletica-511	74	30	can	can	AUX
ecletica-511	74	31	be	be	AUX
ecletica-511	74	32	assumed	assume	VERB
ecletica-511	74	33	that	that	SCONJ
ecletica-511	74	34	the	the	DET
ecletica-511	74	35	formation	formation	NOUN
ecletica-511	74	36	of	of	ADP
ecletica-511	74	37	the	the	DET
ecletica-511	74	38	species	specie	NOUN
ecletica-511	74	39	m(hl)+	m(hl)+	PROPN
ecletica-511	74	40	is	be	AUX
ecletica-511	74	41	the	the	DET
ecletica-511	74	42	rate	rate	NOUN
ecletica-511	74	43	determining	determine	VERB
ecletica-511	74	44	step	step	NOUN
ecletica-511	74	45	.	.	PUNCT
ecletica-511	75	1	therefore	therefore	ADV
ecletica-511	75	2	the	the	DET
ecletica-511	75	3	following	follow	VERB
ecletica-511	75	4	sequence	sequence	NOUN
ecletica-511	75	5	of	of	ADP
ecletica-511	75	6	reactions	reaction	NOUN
ecletica-511	75	7	can	can	AUX
ecletica-511	75	8	be	be	AUX
ecletica-511	75	9	proposed	propose	VERB
ecletica-511	75	10	,	,	PUNCT
ecletica-511	75	11	being	be	AUX
ecletica-511	75	12	r2	r2	PROPN
ecletica-511	75	13	>	>	X
ecletica-511	75	14	>	>	X
ecletica-511	75	15	r1	r1	PROPN
ecletica-511	75	16	:	:	PUNCT
ecletica-511	75	17	consequently	consequently	ADV
ecletica-511	75	18	,	,	PUNCT
ecletica-511	75	19	the	the	DET
ecletica-511	75	20	equation	equation	NOUN
ecletica-511	75	21	rate	rate	NOUN
ecletica-511	75	22	can	can	AUX
ecletica-511	75	23	be	be	AUX
ecletica-511	75	24	written	write	VERB
ecletica-511	75	25	as	as	ADP
ecletica-511	75	26	r	r	NOUN
ecletica-511	75	27	=	=	SYM
ecletica-511	75	28	kb	kb	X
ecletica-511	75	29	x	x	PUNCT
ecletica-511	76	1	[	[	X
ecletica-511	76	2	a	a	X
ecletica-511	76	3	]	]	X
ecletica-511	76	4	(	(	PUNCT
ecletica-511	76	5	1	1	X
ecletica-511	76	6	)	)	PUNCT
ecletica-511	76	7	where	where	SCONJ
ecletica-511	76	8	a	a	PRON
ecletica-511	76	9	is	be	AUX
ecletica-511	76	10	the	the	DET
ecletica-511	76	11	species	specie	NOUN
ecletica-511	76	12	with	with	ADP
ecletica-511	76	13	variable	variable	ADJ
ecletica-511	76	14	concentration	concentration	NOUN
ecletica-511	76	15	and	and	CCONJ
ecletica-511	76	16	b	b	NOUN
ecletica-511	76	17	is	be	AUX
ecletica-511	76	18	the	the	DET
ecletica-511	76	19	species	specie	NOUN
ecletica-511	76	20	with	with	ADP
ecletica-511	76	21	constant	constant	ADJ
ecletica-511	76	22	concentration	concentration	NOUN
ecletica-511	76	23	,	,	PUNCT
ecletica-511	76	24	and	and	CCONJ
ecletica-511	76	25	where	where	SCONJ
ecletica-511	76	26	kb	kb	PROPN
ecletica-511	76	27	=	=	SYM
ecletica-511	76	28	k1	k1	PROPN
ecletica-511	76	29	x	x	PUNCT
ecletica-511	77	1	[	[	X
ecletica-511	77	2	b	b	X
ecletica-511	77	3	]	]	X
ecletica-511	77	4	(	(	PUNCT
ecletica-511	77	5	2	2	NUM
ecletica-511	77	6	)	)	PUNCT
ecletica-511	77	7	for	for	ADP
ecletica-511	77	8	the	the	DET
ecletica-511	77	9	experiments	experiment	NOUN
ecletica-511	77	10	with	with	ADP
ecletica-511	77	11	the	the	DET
ecletica-511	77	12	par	par	PROPN
ecletica-511	77	13	concentration	concentration	NOUN
ecletica-511	77	14	constant	constant	ADJ
ecletica-511	77	15	,	,	PUNCT
ecletica-511	77	16	the	the	DET
ecletica-511	77	17	plot	plot	NOUN
ecletica-511	77	18	(	(	PUNCT
ecletica-511	77	19	r	r	NOUN
ecletica-511	77	20	versus	versus	X
ecletica-511	77	21	[	[	X
ecletica-511	77	22	m2	m2	PROPN
ecletica-511	77	23	+	+	PROPN
ecletica-511	77	24	]	]	X
ecletica-511	77	25	)	)	PUNCT
ecletica-511	77	26	is	be	AUX
ecletica-511	77	27	a	a	DET
ecletica-511	77	28	straight	straight	ADJ
ecletica-511	77	29	line	line	NOUN
ecletica-511	77	30	whose	whose	DET
ecletica-511	77	31	angular	angular	ADJ
ecletica-511	77	32	coefficient	coefficient	NOUN
ecletica-511	77	33	corresponds	correspond	VERB
ecletica-511	77	34	to	to	ADP
ecletica-511	77	35	kpar	kpar	NOUN
ecletica-511	77	36	=	=	PUNCT
ecletica-511	78	1	k’1	k’1	NOUN
ecletica-511	79	1	x	x	PUNCT
ecletica-511	80	1	[	[	X
ecletica-511	80	2	hl-	hl-	X
ecletica-511	80	3	]	]	X
ecletica-511	80	4	(	(	PUNCT
ecletica-511	80	5	3	3	X
ecletica-511	80	6	)	)	PUNCT
ecletica-511	80	7	for	for	SCONJ
ecletica-511	80	8	the	the	DET
ecletica-511	80	9	experiments	experiment	NOUN
ecletica-511	80	10	with	with	ADP
ecletica-511	80	11	metal	metal	NOUN
ecletica-511	80	12	cation	cation	NOUN
ecletica-511	80	13	concentration	concentration	NOUN
ecletica-511	80	14	constant	constant	ADJ
ecletica-511	80	15	,	,	PUNCT
ecletica-511	80	16	the	the	DET
ecletica-511	80	17	plot	plot	NOUN
ecletica-511	80	18	(	(	PUNCT
ecletica-511	80	19	r	r	NOUN
ecletica-511	80	20	versus	versus	ADP
ecletica-511	80	21	[	[	X
ecletica-511	80	22	hl-	hl-	X
ecletica-511	80	23	]	]	PUNCT
ecletica-511	80	24	)	)	PUNCT
ecletica-511	80	25	is	be	AUX
ecletica-511	80	26	a	a	DET
ecletica-511	80	27	straight	straight	ADJ
ecletica-511	80	28	line	line	NOUN
ecletica-511	80	29	whose	whose	DET
ecletica-511	80	30	angular	angular	ADJ
ecletica-511	80	31	coefficient	coefficient	NOUN
ecletica-511	80	32	corresponds	correspond	VERB
ecletica-511	80	33	to	to	ADP
ecletica-511	81	1	kmetal	kmetal	ADJ
ecletica-511	81	2	=	=	SYM
ecletica-511	81	3	k’’1	k’’1	PROPN
ecletica-511	81	4	x	x	PUNCT
ecletica-511	82	1	[	[	X
ecletica-511	82	2	m2	m2	PROPN
ecletica-511	82	3	+	+	PROPN
ecletica-511	82	4	]	]	X
ecletica-511	82	5	(	(	PUNCT
ecletica-511	82	6	4	4	NUM
ecletica-511	82	7	)	)	PUNCT
ecletica-511	82	8	from	from	ADP
ecletica-511	82	9	the	the	DET
ecletica-511	82	10	above	above	ADJ
ecletica-511	82	11	discussion	discussion	NOUN
ecletica-511	82	12	,	,	PUNCT
ecletica-511	82	13	the	the	DET
ecletica-511	82	14	reaction	reaction	NOUN
ecletica-511	82	15	rate	rate	NOUN
ecletica-511	82	16	law	law	NOUN
ecletica-511	82	17	is	be	AUX
ecletica-511	82	18	shown	show	VERB
ecletica-511	82	19	in	in	ADP
ecletica-511	82	20	equation	equation	NOUN
ecletica-511	82	21	5	5	NUM
ecletica-511	82	22	,	,	PUNCT
ecletica-511	82	23	where	where	SCONJ
ecletica-511	82	24	k1	k1	NOUN
ecletica-511	82	25	=	=	SYM
ecletica-511	82	26	k’1	k’1	NOUN
ecletica-511	83	1	=	=	PUNCT
ecletica-511	83	2	k’’1	k’’1	PROPN
ecletica-511	83	3	.	.	PUNCT
ecletica-511	84	1	r	r	NOUN
ecletica-511	84	2	=	=	SYM
ecletica-511	84	3	k1	k1	NOUN
ecletica-511	84	4	x	x	PUNCT
ecletica-511	85	1	[	[	X
ecletica-511	85	2	hl-	hl-	X
ecletica-511	85	3	]	]	X
ecletica-511	85	4	x	x	PUNCT
ecletica-511	86	1	[	[	X
ecletica-511	86	2	m2	m2	PROPN
ecletica-511	86	3	+	+	PROPN
ecletica-511	86	4	]	]	X
ecletica-511	86	5	(	(	PUNCT
ecletica-511	86	6	5	5	X
ecletica-511	86	7	)	)	PUNCT
ecletica-511	86	8	calculations	calculation	NOUN
ecletica-511	86	9	for	for	ADP
ecletica-511	86	10	all	all	DET
ecletica-511	86	11	sets	set	NOUN
ecletica-511	86	12	of	of	ADP
ecletica-511	86	13	experimental	experimental	ADJ
ecletica-511	86	14	data	datum	NOUN
ecletica-511	86	15	to	to	PART
ecletica-511	86	16	give	give	VERB
ecletica-511	86	17	rate	rate	NOUN
ecletica-511	86	18	constant	constant	ADJ
ecletica-511	86	19	k1	k1	NOUN
ecletica-511	86	20	are	be	AUX
ecletica-511	86	21	described	describe	VERB
ecletica-511	86	22	in	in	ADP
ecletica-511	86	23	table	table	NOUN
ecletica-511	86	24	8	8	NUM
ecletica-511	86	25	.	.	PUNCT
ecletica-511	87	1	it	it	PRON
ecletica-511	87	2	can	can	AUX
ecletica-511	87	3	be	be	AUX
ecletica-511	87	4	observed	observe	VERB
ecletica-511	87	5	that	that	SCONJ
ecletica-511	87	6	the	the	DET
ecletica-511	87	7	anions	anion	NOUN
ecletica-511	87	8	do	do	AUX
ecletica-511	87	9	not	not	PART
ecletica-511	87	10	affect	affect	VERB
ecletica-511	87	11	the	the	DET
ecletica-511	87	12	values	value	NOUN
ecletica-511	87	13	of	of	ADP
ecletica-511	87	14	the	the	DET
ecletica-511	87	15	rate	rate	NOUN
ecletica-511	87	16	constant	constant	ADJ
ecletica-511	87	17	.	.	PUNCT
ecletica-511	88	1	also	also	ADV
ecletica-511	88	2	,	,	PUNCT
ecletica-511	88	3	it	it	PRON
ecletica-511	88	4	is	be	AUX
ecletica-511	88	5	clear	clear	ADJ
ecletica-511	88	6	that	that	SCONJ
ecletica-511	88	7	the	the	DET
ecletica-511	88	8	rate	rate	NOUN
ecletica-511	88	9	constants	constant	NOUN
ecletica-511	88	10	for	for	ADP
ecletica-511	88	11	the	the	DET
ecletica-511	88	12	cu2	cu2	NOUN
ecletica-511	88	13	+	+	X
ecletica-511	88	14	solutions	solution	NOUN
ecletica-511	88	15	(	(	PUNCT
ecletica-511	88	16	cuso4	cuso4	NOUN
ecletica-511	88	17	or	or	CCONJ
ecletica-511	88	18	cucl2	cucl2	NOUN
ecletica-511	88	19	)	)	PUNCT
ecletica-511	88	20	are	be	AUX
ecletica-511	88	21	higher	high	ADJ
ecletica-511	88	22	(	(	PUNCT
ecletica-511	88	23	k1cu	k1cu	X
ecletica-511	88	24	=	=	SYM
ecletica-511	88	25	1.66×104	1.66×104	PROPN
ecletica-511	88	26	l	l	PROPN
ecletica-511	88	27	mol-1	mol-1	X
ecletica-511	88	28	s-1	s-1	NOUN
ecletica-511	88	29	)	)	PUNCT
ecletica-511	88	30	than	than	ADP
ecletica-511	88	31	for	for	ADP
ecletica-511	88	32	zn2	zn2	PROPN
ecletica-511	88	33	+	+	PROPN
ecletica-511	88	34	solutions	solution	NOUN
ecletica-511	88	35	(	(	PUNCT
ecletica-511	88	36	znso4	znso4	NOUN
ecletica-511	88	37	or	or	CCONJ
ecletica-511	88	38	zncl2	zncl2	NUM
ecletica-511	88	39	)	)	PUNCT
ecletica-511	89	1	(	(	PUNCT
ecletica-511	89	2	k1zn	k1zn	NOUN
ecletica-511	89	3	=	=	SYM
ecletica-511	89	4	0.94×104	0.94×104	PROPN
ecletica-511	89	5	l	l	PROPN
ecletica-511	89	6	mol-1	mol-1	X
ecletica-511	89	7	s-1	s-1	NOUN
ecletica-511	89	8	)	)	PUNCT
ecletica-511	89	9	.	.	PUNCT
ecletica-511	90	1	for	for	ADP
ecletica-511	90	2	the	the	DET
ecletica-511	90	3	solutions	solution	NOUN
ecletica-511	90	4	containing	contain	VERB
ecletica-511	90	5	zn2++	zn2++	PROPN
ecletica-511	90	6	cu2	cu2	PROPN
ecletica-511	90	7	+	+	ADP
ecletica-511	90	8	equimolar	equimolar	ADJ
ecletica-511	90	9	mixtures	mixture	NOUN
ecletica-511	90	10	k1mixture	k1mixture	NOUN
ecletica-511	90	11	=	=	SYM
ecletica-511	90	12	1.54×104	1.54×104	NUM
ecletica-511	90	13	l	l	NOUN
ecletica-511	90	14	mol-1	mol-1	X
ecletica-511	90	15	s-1	s-1	NOUN
ecletica-511	90	16	.	.	PUNCT
ecletica-511	91	1	if	if	SCONJ
ecletica-511	91	2	the	the	DET
ecletica-511	91	3	rate	rate	NOUN
ecletica-511	91	4	constant	constant	ADJ
ecletica-511	91	5	observed	observe	VERB
ecletica-511	91	6	for	for	ADP
ecletica-511	91	7	the	the	DET
ecletica-511	91	8	mixture	mixture	NOUN
ecletica-511	91	9	of	of	ADP
ecletica-511	91	10	the	the	DET
ecletica-511	91	11	cations	cation	NOUN
ecletica-511	91	12	was	be	AUX
ecletica-511	91	13	only	only	ADV
ecletica-511	91	14	an	an	DET
ecletica-511	91	15	average	average	NOUN
ecletica-511	91	16	of	of	ADP
ecletica-511	91	17	the	the	DET
ecletica-511	91	18	independent	independent	ADJ
ecletica-511	91	19	reaction	reaction	NOUN
ecletica-511	91	20	processes	process	NOUN
ecletica-511	91	21	of	of	ADP
ecletica-511	91	22	each	each	DET
ecletica-511	91	23	cation	cation	NOUN
ecletica-511	91	24	,	,	PUNCT
ecletica-511	91	25	a	a	DET
ecletica-511	91	26	value	value	NOUN
ecletica-511	91	27	close	close	ADV
ecletica-511	91	28	to	to	ADP
ecletica-511	91	29	1.30×104	1.30×104	PROPN
ecletica-511	91	30	l	l	PROPN
ecletica-511	91	31	mol-1	mol-1	X
ecletica-511	91	32	s-1	s-1	NOUN
ecletica-511	91	33	(	(	PUNCT
ecletica-511	91	34	the	the	DET
ecletica-511	91	35	mathematical	mathematical	ADJ
ecletica-511	91	36	mean	mean	NOUN
ecletica-511	91	37	value	value	NOUN
ecletica-511	91	38	of	of	ADP
ecletica-511	91	39	the	the	DET
ecletica-511	91	40	rate	rate	NOUN
ecletica-511	91	41	constants	constant	NOUN
ecletica-511	91	42	)	)	PUNCT
ecletica-511	91	43	should	should	AUX
ecletica-511	91	44	be	be	AUX
ecletica-511	91	45	observed	observe	VERB
ecletica-511	91	46	.	.	PUNCT
ecletica-511	92	1	however	however	ADV
ecletica-511	92	2	,	,	PUNCT
ecletica-511	92	3	the	the	DET
ecletica-511	92	4	higher	high	ADJ
ecletica-511	92	5	value	value	NOUN
ecletica-511	92	6	observed	observe	VERB
ecletica-511	92	7	is	be	AUX
ecletica-511	92	8	closer	close	ADJ
ecletica-511	92	9	to	to	ADP
ecletica-511	92	10	the	the	DET
ecletica-511	92	11	rate	rate	NOUN
ecletica-511	92	12	constant	constant	ADJ
ecletica-511	92	13	of	of	ADP
ecletica-511	92	14	the	the	DET
ecletica-511	92	15	copper	copper	NOUN
ecletica-511	92	16	solutions	solution	NOUN
ecletica-511	92	17	.	.	PUNCT
ecletica-511	93	1	this	this	DET
ecletica-511	93	2	fact	fact	NOUN
ecletica-511	93	3	suggests	suggest	VERB
ecletica-511	93	4	that	that	SCONJ
ecletica-511	93	5	the	the	DET
ecletica-511	93	6	reaction	reaction	NOUN
ecletica-511	93	7	of	of	ADP
ecletica-511	93	8	the	the	DET
ecletica-511	93	9	mixture	mixture	NOUN
ecletica-511	93	10	is	be	AUX
ecletica-511	93	11	more	more	ADV
ecletica-511	93	12	influenced	influence	VERB
ecletica-511	93	13	by	by	ADP
ecletica-511	93	14	cu2	cu2	NOUN
ecletica-511	93	15	+	+	NUM
ecletica-511	93	16	than	than	ADP
ecletica-511	93	17	by	by	ADP
ecletica-511	93	18	zn2	zn2	PROPN
ecletica-511	93	19	+	+	PROPN
ecletica-511	93	20	.	.	PUNCT
ecletica-511	94	1	the	the	DET
ecletica-511	94	2	electronic	electronic	ADJ
ecletica-511	94	3	spectrum	spectrum	NOUN
ecletica-511	94	4	of	of	ADP
ecletica-511	94	5	the	the	DET
ecletica-511	94	6	complex	complex	NOUN
ecletica-511	94	7	of	of	ADP
ecletica-511	94	8	the	the	DET
ecletica-511	94	9	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	94	10	+	+	NOUN
ecletica-511	94	11	equimolar	equimolar	ADJ
ecletica-511	94	12	mixtures	mixture	NOUN
ecletica-511	94	13	in	in	ADP
ecletica-511	94	14	solution	solution	NOUN
ecletica-511	94	15	also	also	ADV
ecletica-511	94	16	resembles	resemble	VERB
ecletica-511	94	17	that	that	PRON
ecletica-511	94	18	of	of	ADP
ecletica-511	94	19	cu2	cu2	NOUN
ecletica-511	94	20	+	+	PROPN
ecletica-511	94	21	,	,	PUNCT
ecletica-511	94	22	as	as	SCONJ
ecletica-511	94	23	can	can	AUX
ecletica-511	94	24	be	be	AUX
ecletica-511	94	25	seen	see	VERB
ecletica-511	94	26	in	in	ADP
ecletica-511	94	27	figure	figure	NOUN
ecletica-511	94	28	1	1	NUM
ecletica-511	94	29	.	.	PUNCT
ecletica-511	95	1	these	these	DET
ecletica-511	95	2	two	two	NUM
ecletica-511	95	3	observations	observation	NOUN
ecletica-511	95	4	indicate	indicate	VERB
ecletica-511	95	5	that	that	SCONJ
ecletica-511	95	6	zn2	zn2	PROPN
ecletica-511	95	7	+	+	X
ecletica-511	95	8	and	and	CCONJ
ecletica-511	95	9	cu2	cu2	VERB
ecletica-511	95	10	+	+	PROPN
ecletica-511	95	11	,	,	PUNCT
ecletica-511	95	12	when	when	SCONJ
ecletica-511	95	13	mixed	mix	VERB
ecletica-511	95	14	in	in	ADP
ecletica-511	95	15	solution	solution	NOUN
ecletica-511	95	16	,	,	PUNCT
ecletica-511	95	17	assume	assume	VERB
ecletica-511	95	18	properties	property	NOUN
ecletica-511	95	19	as	as	SCONJ
ecletica-511	95	20	if	if	SCONJ
ecletica-511	95	21	they	they	PRON
ecletica-511	95	22	were	be	AUX
ecletica-511	95	23	an	an	DET
ecletica-511	95	24	unique	unique	ADJ
ecletica-511	95	25	species	specie	NOUN
ecletica-511	95	26	.	.	PUNCT
ecletica-511	96	1	this	this	DET
ecletica-511	96	2	behavior	behavior	NOUN
ecletica-511	96	3	had	have	AUX
ecletica-511	96	4	already	already	ADV
ecletica-511	96	5	been	be	AUX
ecletica-511	96	6	observed	observe	VERB
ecletica-511	96	7	in	in	ADP
ecletica-511	96	8	the	the	DET
ecletica-511	96	9	study	study	NOUN
ecletica-511	96	10	of	of	ADP
ecletica-511	96	11	the	the	DET
ecletica-511	96	12	reaction	reaction	NOUN
ecletica-511	96	13	of	of	ADP
ecletica-511	96	14	cu2	cu2	NOUN
ecletica-511	96	15	+	+	CCONJ
ecletica-511	96	16	and	and	CCONJ
ecletica-511	96	17	zn2	zn2	PRON
ecletica-511	96	18	+	+	X
ecletica-511	96	19	with	with	ADP
ecletica-511	96	20	zincon	zincon	NOUN
ecletica-511	97	1	[	[	X
ecletica-511	97	2	9	9	NUM
ecletica-511	97	3	]	]	PUNCT
ecletica-511	97	4	.	.	PUNCT
ecletica-511	98	1	m+	m+	NUM
ecletica-511	98	2	hl	hl	PROPN
ecletica-511	98	3	m(hl	m(hl	NOUN
ecletica-511	98	4	)	)	PUNCT
ecletica-511	98	5	slow	slow	ADJ
ecletica-511	98	6	rate	rate	NOUN
ecletica-511	98	7	=	=	SYM
ecletica-511	98	8	r	r	NOUN
ecletica-511	98	9	m(hl	m(hl	NOUN
ecletica-511	98	10	)	)	PUNCT
ecletica-511	99	1	+	+	NUM
ecletica-511	99	2	hl	hl	NOUN
ecletica-511	99	3	m(hl	m(hl	NOUN
ecletica-511	99	4	)	)	PUNCT
ecletica-511	99	5	fast	fast	ADJ
ecletica-511	99	6	rate	rate	NOUN
ecletica-511	99	7	=	=	NOUN
ecletica-511	100	1	r	r	NOUN
ecletica-511	100	2	2	2	NUM
ecletica-511	100	3	+	+	CCONJ
ecletica-511	100	4	+	+	CCONJ
ecletica-511	100	5	+	+	SYM
ecletica-511	100	6	1	1	NUM
ecletica-511	100	7	2	2	NUM
ecletica-511	100	8	2	2	NUM
ecletica-511	100	9	table	table	NOUN
ecletica-511	100	10	8	8	NUM
ecletica-511	100	11	:	:	PUNCT
ecletica-511	100	12	reaction	reaction	NOUN
ecletica-511	100	13	rate	rate	NOUN
ecletica-511	100	14	constants	constant	NOUN
ecletica-511	100	15	for	for	ADP
ecletica-511	100	16	aqueous	aqueous	ADJ
ecletica-511	100	17	zn2	zn2	NOUN
ecletica-511	100	18	+	+	PROPN
ecletica-511	100	19	and	and	CCONJ
ecletica-511	100	20	cu2	cu2	NOUN
ecletica-511	100	21	+	+	CCONJ
ecletica-511	100	22	(	(	PUNCT
ecletica-511	100	23	chlorides	chloride	NOUN
ecletica-511	100	24	,	,	PUNCT
ecletica-511	100	25	sulfates	sulfate	NOUN
ecletica-511	100	26	and	and	CCONJ
ecletica-511	100	27	mixtures	mixture	NOUN
ecletica-511	100	28	)	)	PUNCT
ecletica-511	100	29	solutions	solution	NOUN
ecletica-511	100	30	with	with	ADP
ecletica-511	100	31	aqueous	aqueous	ADJ
ecletica-511	100	32	monoprotonated	monoprotonate	VERB
ecletica-511	100	33	par	par	NOUN
ecletica-511	100	34	,	,	PUNCT
ecletica-511	100	35	hl-,solutions	hl-,solution	NOUN
ecletica-511	100	36	,	,	PUNCT
ecletica-511	100	37	at	at	ADP
ecletica-511	100	38	25.0	25.0	NUM
ecletica-511	100	39	±	±	NUM
ecletica-511	100	40	0.1	0.1	NUM
ecletica-511	100	41	°	°	ADP
ecletica-511	100	42	c	c	NOUN
ecletica-511	100	43	,	,	PUNCT
ecletica-511	100	44	in	in	ADP
ecletica-511	100	45	borate	borate	NOUN
ecletica-511	100	46	buffer	buffer	NOUN
ecletica-511	100	47	,	,	PUNCT
ecletica-511	101	1	ph	ph	NOUN
ecletica-511	101	2	=	=	SYM
ecletica-511	101	3	8.5	8.5	NUM
ecletica-511	101	4	.	.	PUNCT
ecletica-511	102	1	figure	figure	NOUN
ecletica-511	102	2	1	1	NUM
ecletica-511	102	3	.	.	PUNCT
ecletica-511	102	4	electronic	electronic	ADJ
ecletica-511	102	5	spectra	spectra	NOUN
ecletica-511	102	6	of	of	ADP
ecletica-511	102	7	aqueous	aqueous	ADJ
ecletica-511	102	8	solutions	solution	NOUN
ecletica-511	102	9	of	of	ADP
ecletica-511	102	10	(	(	PUNCT
ecletica-511	102	11	a	a	NOUN
ecletica-511	102	12	)	)	PUNCT
ecletica-511	103	1	[	[	X
ecletica-511	103	2	cu(hl)2	cu(hl)2	X
ecletica-511	103	3	]	]	X
ecletica-511	103	4	2.96	2.96	NUM
ecletica-511	103	5	10	10	NUM
ecletica-511	103	6	-	-	SYM
ecletica-511	103	7	5	5	NUM
ecletica-511	103	8	mol	mol	ADP
ecletica-511	103	9	l-1	l-1	NUM
ecletica-511	103	10	;	;	PUNCT
ecletica-511	103	11	(	(	PUNCT
ecletica-511	103	12	b	b	X
ecletica-511	103	13	)	)	PUNCT
ecletica-511	103	14	mixture	mixture	NOUN
ecletica-511	103	15	[	[	X
ecletica-511	103	16	(	(	PUNCT
ecletica-511	103	17	zn+cu)(hl)2	zn+cu)(hl)2	NOUN
ecletica-511	103	18	]	]	X
ecletica-511	103	19	(	(	PUNCT
ecletica-511	103	20	1.50	1.50	NUM
ecletica-511	103	21	+	+	NOUN
ecletica-511	103	22	1.50)×10	1.50)×10	NOUN
ecletica-511	103	23	-	-	SYM
ecletica-511	103	24	5	5	NUM
ecletica-511	103	25	mol	mol	ADP
ecletica-511	103	26	l-1	l-1	NUM
ecletica-511	103	27	;	;	PUNCT
ecletica-511	103	28	(	(	PUNCT
ecletica-511	103	29	c	c	X
ecletica-511	103	30	)	)	PUNCT
ecletica-511	104	1	[	[	X
ecletica-511	104	2	zn(hl)2	zn(hl)2	X
ecletica-511	104	3	]	]	X
ecletica-511	104	4	3.03×10	3.03×10	X
ecletica-511	104	5	-	-	SYM
ecletica-511	104	6	5	5	NUM
ecletica-511	104	7	mol	mol	ADP
ecletica-511	104	8	l-1	l-1	PROPN
ecletica-511	104	9	.	.	PUNCT
ecletica-511	105	1	distilled	distil	VERB
ecletica-511	105	2	water	water	NOUN
ecletica-511	105	3	was	be	AUX
ecletica-511	105	4	used	use	VERB
ecletica-511	105	5	as	as	ADP
ecletica-511	105	6	reference	reference	NOUN
ecletica-511	105	7	.	.	PUNCT
ecletica-511	106	1	ecl	ecl	PROPN
ecletica-511	106	2	.	.	PROPN
ecletica-511	106	3	quím	quím	PROPN
ecletica-511	106	4	.	.	PUNCT
ecletica-511	106	5	,	,	PUNCT
ecletica-511	106	6	são	são	PROPN
ecletica-511	106	7	paulo	paulo	PROPN
ecletica-511	106	8	,	,	PUNCT
ecletica-511	106	9	28(1	28(1	NOUN
ecletica-511	106	10	):	):	PUNCT
ecletica-511	106	11	55	55	NUM
ecletica-511	106	12	-	-	SYM
ecletica-511	106	13	62	62	NUM
ecletica-511	106	14	,	,	PUNCT
ecletica-511	106	15	2003	2003	NUM
ecletica-511	106	16	60	60	NUM
ecletica-511	106	17	according	accord	VERB
ecletica-511	106	18	to	to	ADP
ecletica-511	106	19	eigen	eigen	PROPN
ecletica-511	107	1	[	[	X
ecletica-511	107	2	3	3	NUM
ecletica-511	107	3	]	]	PUNCT
ecletica-511	107	4	,	,	PUNCT
ecletica-511	107	5	the	the	DET
ecletica-511	107	6	release	release	NOUN
ecletica-511	107	7	of	of	ADP
ecletica-511	107	8	water	water	NOUN
ecletica-511	107	9	molecules	molecule	NOUN
ecletica-511	107	10	from	from	ADP
ecletica-511	107	11	the	the	DET
ecletica-511	107	12	central	central	ADJ
ecletica-511	107	13	metal	metal	NOUN
ecletica-511	107	14	species	specie	NOUN
ecletica-511	107	15	is	be	AUX
ecletica-511	107	16	rate	rate	NOUN
ecletica-511	107	17	-	-	PUNCT
ecletica-511	107	18	determining	determine	VERB
ecletica-511	107	19	and	and	CCONJ
ecletica-511	107	20	controls	control	VERB
ecletica-511	107	21	the	the	DET
ecletica-511	107	22	formation	formation	NOUN
ecletica-511	107	23	of	of	ADP
ecletica-511	107	24	the	the	DET
ecletica-511	107	25	first	first	ADJ
ecletica-511	107	26	metalligand	metalligand	NOUN
ecletica-511	107	27	bond	bond	NOUN
ecletica-511	107	28	.	.	PUNCT
ecletica-511	108	1	usually	usually	ADV
ecletica-511	108	2	the	the	DET
ecletica-511	108	3	chelate	chelate	NOUN
ecletica-511	108	4	ring	ring	NOUN
ecletica-511	108	5	closure	closure	NOUN
ecletica-511	108	6	is	be	AUX
ecletica-511	108	7	very	very	ADV
ecletica-511	108	8	rapid	rapid	ADJ
ecletica-511	108	9	,	,	PUNCT
ecletica-511	108	10	compared	compare	VERB
ecletica-511	108	11	with	with	ADP
ecletica-511	108	12	the	the	DET
ecletica-511	108	13	rate	rate	NOUN
ecletica-511	108	14	of	of	ADP
ecletica-511	108	15	this	this	DET
ecletica-511	108	16	first	first	ADJ
ecletica-511	108	17	coordination	coordination	NOUN
ecletica-511	108	18	[	[	X
ecletica-511	108	19	5	5	NUM
ecletica-511	108	20	]	]	PUNCT
ecletica-511	108	21	.	.	PUNCT
ecletica-511	109	1	the	the	DET
ecletica-511	109	2	experimental	experimental	ADJ
ecletica-511	109	3	observations	observation	NOUN
ecletica-511	109	4	done	do	VERB
ecletica-511	109	5	in	in	ADP
ecletica-511	109	6	this	this	DET
ecletica-511	109	7	work	work	NOUN
ecletica-511	109	8	and	and	CCONJ
ecletica-511	109	9	eigen	eigen	PROPN
ecletica-511	109	10	’s	’s	PART
ecletica-511	109	11	proposition	proposition	NOUN
ecletica-511	109	12	,	,	PUNCT
ecletica-511	109	13	summarized	summarize	VERB
ecletica-511	109	14	above	above	ADV
ecletica-511	109	15	,	,	PUNCT
ecletica-511	109	16	can	can	AUX
ecletica-511	109	17	be	be	AUX
ecletica-511	109	18	understood	understand	VERB
ecletica-511	109	19	in	in	ADP
ecletica-511	109	20	terms	term	NOUN
ecletica-511	109	21	of	of	ADP
ecletica-511	109	22	the	the	DET
ecletica-511	109	23	water	water	NOUN
ecletica-511	109	24	solvation	solvation	NOUN
ecletica-511	109	25	shells	shell	NOUN
ecletica-511	109	26	of	of	ADP
ecletica-511	109	27	the	the	DET
ecletica-511	109	28	cations	cation	NOUN
ecletica-511	109	29	.	.	PUNCT
ecletica-511	110	1	initially	initially	ADV
ecletica-511	110	2	it	it	PRON
ecletica-511	110	3	must	must	AUX
ecletica-511	110	4	be	be	AUX
ecletica-511	110	5	supposed	suppose	VERB
ecletica-511	110	6	that	that	SCONJ
ecletica-511	110	7	the	the	DET
ecletica-511	110	8	ions	ion	NOUN
ecletica-511	110	9	are	be	AUX
ecletica-511	110	10	homogeneously	homogeneously	ADV
ecletica-511	110	11	distributed	distribute	VERB
ecletica-511	110	12	through	through	ADP
ecletica-511	110	13	the	the	DET
ecletica-511	110	14	solvent	solvent	NOUN
ecletica-511	110	15	.	.	PUNCT
ecletica-511	111	1	the	the	DET
ecletica-511	111	2	solvated	solvate	VERB
ecletica-511	111	3	cations	cation	NOUN
ecletica-511	111	4	can	can	AUX
ecletica-511	111	5	be	be	AUX
ecletica-511	111	6	assumed	assume	VERB
ecletica-511	111	7	to	to	PART
ecletica-511	111	8	form	form	VERB
ecletica-511	111	9	clusters	cluster	NOUN
ecletica-511	111	10	that	that	PRON
ecletica-511	111	11	could	could	AUX
ecletica-511	111	12	contain	contain	VERB
ecletica-511	111	13	more	more	ADJ
ecletica-511	111	14	than	than	ADP
ecletica-511	111	15	one	one	NUM
ecletica-511	111	16	cation	cation	NOUN
ecletica-511	111	17	.	.	PUNCT
ecletica-511	112	1	the	the	DET
ecletica-511	112	2	solution	solution	NOUN
ecletica-511	112	3	could	could	AUX
ecletica-511	112	4	be	be	AUX
ecletica-511	112	5	understood	understand	VERB
ecletica-511	112	6	as	as	ADP
ecletica-511	112	7	an	an	DET
ecletica-511	112	8	assembly	assembly	NOUN
ecletica-511	112	9	of	of	ADP
ecletica-511	112	10	these	these	DET
ecletica-511	112	11	clusters	cluster	NOUN
ecletica-511	112	12	that	that	PRON
ecletica-511	112	13	interact	interact	VERB
ecletica-511	112	14	among	among	ADP
ecletica-511	112	15	themselves	themselves	PRON
ecletica-511	112	16	through	through	ADP
ecletica-511	112	17	hydrogen	hydrogen	NOUN
ecletica-511	112	18	bonding	bonding	NOUN
ecletica-511	112	19	.	.	PUNCT
ecletica-511	113	1	despite	despite	SCONJ
ecletica-511	113	2	the	the	DET
ecletica-511	113	3	fact	fact	NOUN
ecletica-511	113	4	that	that	SCONJ
ecletica-511	113	5	the	the	DET
ecletica-511	113	6	interactions	interaction	NOUN
ecletica-511	113	7	that	that	PRON
ecletica-511	113	8	form	form	VERB
ecletica-511	113	9	the	the	DET
ecletica-511	113	10	clusters	cluster	NOUN
ecletica-511	113	11	are	be	AUX
ecletica-511	113	12	weak	weak	ADJ
ecletica-511	113	13	,	,	PUNCT
ecletica-511	113	14	it	it	PRON
ecletica-511	113	15	seems	seem	VERB
ecletica-511	113	16	that	that	SCONJ
ecletica-511	113	17	they	they	PRON
ecletica-511	113	18	determine	determine	VERB
ecletica-511	113	19	the	the	DET
ecletica-511	113	20	complexation	complexation	NOUN
ecletica-511	113	21	reaction	reaction	NOUN
ecletica-511	113	22	.	.	PUNCT
ecletica-511	114	1	mixed	mixed	ADJ
ecletica-511	114	2	clusters	cluster	NOUN
ecletica-511	114	3	can	can	AUX
ecletica-511	114	4	be	be	AUX
ecletica-511	114	5	imagined	imagine	VERB
ecletica-511	114	6	in	in	ADP
ecletica-511	114	7	solutions	solution	NOUN
ecletica-511	114	8	such	such	ADJ
ecletica-511	114	9	as	as	ADP
ecletica-511	114	10	a	a	DET
ecletica-511	114	11	mixture	mixture	NOUN
ecletica-511	114	12	of	of	ADP
ecletica-511	114	13	zn2++	zn2++	PROPN
ecletica-511	114	14	cu2	cu2	VERB
ecletica-511	115	1	+	+	PROPN
ecletica-511	115	2	.	.	PUNCT
ecletica-511	116	1	therefore	therefore	ADV
ecletica-511	116	2	,	,	PUNCT
ecletica-511	116	3	the	the	DET
ecletica-511	116	4	final	final	ADJ
ecletica-511	116	5	product	product	NOUN
ecletica-511	116	6	,	,	PUNCT
ecletica-511	116	7	in	in	ADP
ecletica-511	116	8	solution	solution	NOUN
ecletica-511	116	9	,	,	PUNCT
ecletica-511	116	10	after	after	SCONJ
ecletica-511	116	11	the	the	DET
ecletica-511	116	12	reaction	reaction	NOUN
ecletica-511	116	13	of	of	ADP
ecletica-511	116	14	complexation	complexation	NOUN
ecletica-511	116	15	can	can	AUX
ecletica-511	116	16	be	be	AUX
ecletica-511	116	17	a	a	DET
ecletica-511	116	18	polynuclear	polynuclear	NOUN
ecletica-511	116	19	hydrated	hydrated	ADJ
ecletica-511	116	20	species	specie	NOUN
ecletica-511	116	21	containing	contain	VERB
ecletica-511	116	22	zn2	zn2	PROPN
ecletica-511	116	23	+	+	PROPN
ecletica-511	116	24	and	and	CCONJ
ecletica-511	116	25	cu2	cu2	NOUN
ecletica-511	116	26	+	+	PROPN
ecletica-511	116	27	,	,	PUNCT
ecletica-511	116	28	for	for	ADP
ecletica-511	116	29	instance	instance	NOUN
ecletica-511	116	30	,	,	PUNCT
ecletica-511	116	31	[	[	X
ecletica-511	116	32	(	(	PUNCT
ecletica-511	116	33	zn+cu)(h2o)n	zn+cu)(h2o)n	X
ecletica-511	116	34	(	(	PUNCT
ecletica-511	116	35	hl)2]x	hl)2]x	NOUN
ecletica-511	116	36	.	.	PROPN
ecletica-511	117	1	this	this	DET
ecletica-511	117	2	supposition	supposition	NOUN
ecletica-511	117	3	is	be	AUX
ecletica-511	117	4	reinforced	reinforce	VERB
ecletica-511	117	5	by	by	ADP
ecletica-511	117	6	the	the	DET
ecletica-511	117	7	spectral	spectral	ADJ
ecletica-511	117	8	and	and	CCONJ
ecletica-511	117	9	kinetical	kinetical	ADJ
ecletica-511	117	10	observations	observation	NOUN
ecletica-511	117	11	obtained	obtain	VERB
ecletica-511	117	12	in	in	ADP
ecletica-511	117	13	this	this	DET
ecletica-511	117	14	work	work	NOUN
ecletica-511	117	15	.	.	PUNCT
ecletica-511	118	1	despite	despite	SCONJ
ecletica-511	118	2	the	the	DET
ecletica-511	118	3	fact	fact	NOUN
ecletica-511	118	4	that	that	SCONJ
ecletica-511	118	5	,	,	PUNCT
ecletica-511	118	6	from	from	ADP
ecletica-511	118	7	the	the	DET
ecletica-511	118	8	experimental	experimental	ADJ
ecletica-511	118	9	data	datum	NOUN
ecletica-511	118	10	obtained	obtain	VERB
ecletica-511	118	11	in	in	ADP
ecletica-511	118	12	this	this	DET
ecletica-511	118	13	work	work	NOUN
ecletica-511	118	14	,	,	PUNCT
ecletica-511	118	15	the	the	DET
ecletica-511	118	16	polynuclear	polynuclear	NOUN
ecletica-511	118	17	species	specie	NOUN
ecletica-511	118	18	are	be	AUX
ecletica-511	118	19	only	only	ADV
ecletica-511	118	20	evident	evident	ADJ
ecletica-511	118	21	in	in	ADP
ecletica-511	118	22	the	the	DET
ecletica-511	118	23	mixed	mixed	ADJ
ecletica-511	118	24	solution	solution	NOUN
ecletica-511	118	25	,	,	PUNCT
ecletica-511	118	26	certainly	certainly	ADV
ecletica-511	118	27	,	,	PUNCT
ecletica-511	118	28	this	this	DET
ecletica-511	118	29	character	character	NOUN
ecletica-511	118	30	must	must	AUX
ecletica-511	118	31	be	be	AUX
ecletica-511	118	32	considered	consider	VERB
ecletica-511	118	33	for	for	ADP
ecletica-511	118	34	the	the	DET
ecletica-511	118	35	solutions	solution	NOUN
ecletica-511	118	36	containing	contain	VERB
ecletica-511	118	37	only	only	ADV
ecletica-511	118	38	one	one	NUM
ecletica-511	118	39	kind	kind	NOUN
ecletica-511	118	40	of	of	ADP
ecletica-511	118	41	cation	cation	NOUN
ecletica-511	118	42	,	,	PUNCT
ecletica-511	118	43	such	such	ADJ
ecletica-511	118	44	as	as	ADP
ecletica-511	118	45	zn2	zn2	PROPN
ecletica-511	118	46	+	+	NOUN
ecletica-511	118	47	or	or	CCONJ
ecletica-511	118	48	cu2	cu2	NOUN
ecletica-511	118	49	+	+	NOUN
ecletica-511	118	50	.	.	PUNCT
ecletica-511	119	1	according	accord	VERB
ecletica-511	119	2	to	to	ADP
ecletica-511	119	3	eigen	eigen	PROPN
ecletica-511	119	4	[	[	X
ecletica-511	119	5	3	3	NUM
ecletica-511	119	6	]	]	PUNCT
ecletica-511	119	7	,	,	PUNCT
ecletica-511	119	8	the	the	DET
ecletica-511	119	9	characteristic	characteristic	ADJ
ecletica-511	119	10	rate	rate	NOUN
ecletica-511	119	11	constants	constant	NOUN
ecletica-511	119	12	for	for	ADP
ecletica-511	119	13	h2o	h2o	NOUN
ecletica-511	119	14	substitution	substitution	NOUN
ecletica-511	119	15	in	in	ADP
ecletica-511	119	16	the	the	DET
ecletica-511	119	17	inner	inner	ADJ
ecletica-511	119	18	coordination	coordination	NOUN
ecletica-511	119	19	sphere	sphere	NOUN
ecletica-511	119	20	of	of	ADP
ecletica-511	119	21	cu2	cu2	NOUN
ecletica-511	119	22	+	+	CCONJ
ecletica-511	119	23	is	be	AUX
ecletica-511	119	24	about	about	ADV
ecletica-511	119	25	3×108	3×108	NUM
ecletica-511	119	26	s-1	s-1	NOUN
ecletica-511	119	27	and	and	CCONJ
ecletica-511	119	28	of	of	ADP
ecletica-511	119	29	zn2	zn2	PROPN
ecletica-511	119	30	+	+	PROPN
ecletica-511	119	31	is	be	AUX
ecletica-511	119	32	about	about	ADP
ecletica-511	119	33	3×107	3×107	NUM
ecletica-511	119	34	s-1	s-1	NOUN
ecletica-511	119	35	.	.	PUNCT
ecletica-511	120	1	the	the	DET
ecletica-511	120	2	observed	observe	VERB
ecletica-511	120	3	rate	rate	NOUN
ecletica-511	120	4	constant	constant	ADJ
ecletica-511	120	5	for	for	ADP
ecletica-511	120	6	the	the	DET
ecletica-511	120	7	reaction	reaction	NOUN
ecletica-511	120	8	of	of	ADP
ecletica-511	120	9	cu2	cu2	NOUN
ecletica-511	120	10	+	+	X
ecletica-511	120	11	with	with	ADP
ecletica-511	120	12	hlis	hlis	NOUN
ecletica-511	120	13	higher	high	ADJ
ecletica-511	120	14	than	than	ADP
ecletica-511	120	15	that	that	PRON
ecletica-511	120	16	for	for	ADP
ecletica-511	120	17	zn2	zn2	PROPN
ecletica-511	120	18	+	+	PROPN
ecletica-511	120	19	,	,	PUNCT
ecletica-511	120	20	as	as	SCONJ
ecletica-511	120	21	can	can	AUX
ecletica-511	120	22	be	be	AUX
ecletica-511	120	23	seen	see	VERB
ecletica-511	120	24	in	in	ADP
ecletica-511	120	25	table	table	NOUN
ecletica-511	120	26	8	8	NUM
ecletica-511	120	27	,	,	PUNCT
ecletica-511	120	28	following	follow	VERB
ecletica-511	120	29	the	the	DET
ecletica-511	120	30	order	order	NOUN
ecletica-511	120	31	found	find	VERB
ecletica-511	120	32	by	by	ADP
ecletica-511	120	33	eigen	eigen	PROPN
ecletica-511	120	34	.	.	PUNCT
ecletica-511	121	1	it	it	PRON
ecletica-511	121	2	suggests	suggest	VERB
ecletica-511	121	3	that	that	SCONJ
ecletica-511	121	4	the	the	DET
ecletica-511	121	5	entrance	entrance	NOUN
ecletica-511	121	6	of	of	ADP
ecletica-511	121	7	the	the	DET
ecletica-511	121	8	ligand	ligand	NOUN
ecletica-511	121	9	is	be	AUX
ecletica-511	121	10	strongly	strongly	ADV
ecletica-511	121	11	dependent	dependent	ADJ
ecletica-511	121	12	on	on	ADP
ecletica-511	121	13	the	the	DET
ecletica-511	121	14	leaving	leaving	NOUN
ecletica-511	121	15	of	of	ADP
ecletica-511	121	16	water	water	NOUN
ecletica-511	121	17	molecules	molecule	NOUN
ecletica-511	121	18	from	from	ADP
ecletica-511	121	19	the	the	DET
ecletica-511	121	20	cation	cation	NOUN
ecletica-511	121	21	.	.	PUNCT
ecletica-511	122	1	conclusion	conclusion	NOUN
ecletica-511	122	2	on	on	ADP
ecletica-511	122	3	the	the	DET
ecletica-511	122	4	basis	basis	NOUN
ecletica-511	122	5	of	of	ADP
ecletica-511	122	6	the	the	DET
ecletica-511	122	7	kinetic	kinetic	ADJ
ecletica-511	122	8	results	result	NOUN
ecletica-511	122	9	obtained	obtain	VERB
ecletica-511	122	10	in	in	ADP
ecletica-511	122	11	this	this	DET
ecletica-511	122	12	work	work	NOUN
ecletica-511	122	13	,	,	PUNCT
ecletica-511	122	14	a	a	DET
ecletica-511	122	15	plausible	plausible	ADJ
ecletica-511	122	16	mechanism	mechanism	NOUN
ecletica-511	122	17	of	of	ADP
ecletica-511	122	18	this	this	DET
ecletica-511	122	19	reaction	reaction	NOUN
ecletica-511	122	20	can	can	AUX
ecletica-511	122	21	be	be	AUX
ecletica-511	122	22	proposed	propose	VERB
ecletica-511	122	23	.	.	PUNCT
ecletica-511	123	1	the	the	DET
ecletica-511	123	2	following	follow	VERB
ecletica-511	123	3	representations	representation	NOUN
ecletica-511	123	4	are	be	AUX
ecletica-511	123	5	used	use	VERB
ecletica-511	123	6	:	:	PUNCT
ecletica-511	123	7	ki	ki	PROPN
ecletica-511	123	8	=	=	PUNCT
ecletica-511	123	9	rate	rate	NOUN
ecletica-511	123	10	constants	constant	NOUN
ecletica-511	123	11	;	;	PUNCT
ecletica-511	124	1	[	[	X
ecletica-511	124	2	m(h2o)n]2	m(h2o)n]2	X
ecletica-511	124	3	+	+	VERB
ecletica-511	124	4	represents	represent	VERB
ecletica-511	124	5	the	the	DET
ecletica-511	124	6	metal	metal	NOUN
ecletica-511	124	7	cation	cation	NOUN
ecletica-511	124	8	and	and	CCONJ
ecletica-511	124	9	its	its	PRON
ecletica-511	124	10	solvation	solvation	NOUN
ecletica-511	124	11	sphere	sphere	NOUN
ecletica-511	124	12	;	;	PUNCT
ecletica-511	124	13	hl	hl	X
ecletica-511	124	14	-	-	PUNCT
ecletica-511	124	15	is	be	AUX
ecletica-511	124	16	the	the	DET
ecletica-511	124	17	ligand	ligand	NOUN
ecletica-511	124	18	in	in	ADP
ecletica-511	124	19	the	the	DET
ecletica-511	124	20	monoprotonoated	monoprotonoated	ADJ
ecletica-511	124	21	form	form	NOUN
ecletica-511	124	22	(	(	PUNCT
ecletica-511	124	23	reacting	react	VERB
ecletica-511	124	24	species	specie	NOUN
ecletica-511	124	25	at	at	ADP
ecletica-511	124	26	the	the	DET
ecletica-511	124	27	working	work	VERB
ecletica-511	124	28	ph	ph	NOUN
ecletica-511	124	29	=	=	SYM
ecletica-511	124	30	8.5	8.5	NUM
ecletica-511	124	31	,	,	PUNCT
ecletica-511	124	32	according	accord	VERB
ecletica-511	124	33	to	to	ADP
ecletica-511	124	34	par	par	PROPN
ecletica-511	124	35	pka	pka	PROPN
ecletica-511	124	36	values(1,2	values(1,2	PROPN
ecletica-511	124	37	)	)	PUNCT
ecletica-511	124	38	)	)	PUNCT
ecletica-511	124	39	;	;	PUNCT
ecletica-511	125	1	[	[	X
ecletica-511	125	2	m(h2o)n-4(hl)2	m(h2o)n-4(hl)2	X
ecletica-511	125	3	]	]	X
ecletica-511	125	4	is	be	AUX
ecletica-511	125	5	the	the	DET
ecletica-511	125	6	formed	form	VERB
ecletica-511	125	7	complex	complex	ADJ
ecletica-511	125	8	,	,	PUNCT
ecletica-511	125	9	i.e.	i.e.	X
ecletica-511	125	10	,	,	PUNCT
ecletica-511	125	11	the	the	DET
ecletica-511	125	12	spectroscopically	spectroscopically	ADV
ecletica-511	125	13	monitored	monitor	VERB
ecletica-511	125	14	species	specie	NOUN
ecletica-511	125	15	.	.	PUNCT
ecletica-511	126	1	[	[	X
ecletica-511	126	2	m(h2o)n]2	m(h2o)n]2	X
ecletica-511	126	3	+	+	NOUN
ecletica-511	126	4	and	and	CCONJ
ecletica-511	126	5	[	[	X
ecletica-511	126	6	m(h2o)n-4(hl)2	m(h2o)n-4(hl)2	X
ecletica-511	126	7	]	]	PUNCT
ecletica-511	126	8	can	can	AUX
ecletica-511	126	9	be	be	AUX
ecletica-511	126	10	polynuclear	polynuclear	ADJ
ecletica-511	126	11	species	specie	NOUN
ecletica-511	126	12	and	and	CCONJ
ecletica-511	126	13	therefore	therefore	ADV
ecletica-511	126	14	the	the	DET
ecletica-511	126	15	representations	representation	NOUN
ecletica-511	126	16	used	use	VERB
ecletica-511	126	17	are	be	AUX
ecletica-511	126	18	simplifications	simplification	NOUN
ecletica-511	126	19	.	.	PUNCT
ecletica-511	127	1	in	in	ADP
ecletica-511	127	2	the	the	DET
ecletica-511	127	3	proposed	propose	VERB
ecletica-511	127	4	mechanism	mechanism	NOUN
ecletica-511	127	5	,	,	PUNCT
ecletica-511	127	6	the	the	DET
ecletica-511	127	7	first	first	ADJ
ecletica-511	127	8	ligand	ligand	NOUN
ecletica-511	127	9	site	site	NOUN
ecletica-511	127	10	coordination	coordination	NOUN
ecletica-511	127	11	is	be	AUX
ecletica-511	127	12	supposed	suppose	VERB
ecletica-511	127	13	to	to	PART
ecletica-511	127	14	be	be	AUX
ecletica-511	127	15	the	the	DET
ecletica-511	127	16	slow	slow	ADJ
ecletica-511	127	17	step	step	NOUN
ecletica-511	127	18	.	.	PUNCT
ecletica-511	128	1	the	the	DET
ecletica-511	128	2	second	second	ADJ
ecletica-511	128	3	ligand	ligand	NOUN
ecletica-511	128	4	site	site	NOUN
ecletica-511	128	5	coordination	coordination	NOUN
ecletica-511	128	6	is	be	AUX
ecletica-511	128	7	faster	fast	ADJ
ecletica-511	128	8	.	.	PUNCT
ecletica-511	129	1	both	both	DET
ecletica-511	129	2	steps	step	NOUN
ecletica-511	129	3	involve	involve	VERB
ecletica-511	129	4	the	the	DET
ecletica-511	129	5	exchange	exchange	NOUN
ecletica-511	129	6	of	of	ADP
ecletica-511	129	7	water	water	NOUN
ecletica-511	129	8	solvation	solvation	NOUN
ecletica-511	129	9	molecules	molecule	NOUN
ecletica-511	129	10	and	and	CCONJ
ecletica-511	129	11	the	the	DET
ecletica-511	129	12	solution	solution	NOUN
ecletica-511	129	13	is	be	AUX
ecletica-511	129	14	assumed	assume	VERB
ecletica-511	129	15	as	as	ADP
ecletica-511	129	16	homogeneous	homogeneous	ADJ
ecletica-511	129	17	distribution	distribution	NOUN
ecletica-511	129	18	of	of	ADP
ecletica-511	129	19	groups	group	NOUN
ecletica-511	129	20	of	of	ADP
ecletica-511	129	21	cations	cation	NOUN
ecletica-511	129	22	and	and	CCONJ
ecletica-511	129	23	water	water	NOUN
ecletica-511	129	24	solvation	solvation	NOUN
ecletica-511	129	25	molecules	molecule	NOUN
ecletica-511	129	26	.	.	PUNCT
ecletica-511	130	1	the	the	DET
ecletica-511	130	2	following	follow	VERB
ecletica-511	130	3	scheme	scheme	NOUN
ecletica-511	130	4	illustrates	illustrate	VERB
ecletica-511	130	5	a	a	DET
ecletica-511	130	6	simplified	simplified	ADJ
ecletica-511	130	7	model	model	NOUN
ecletica-511	130	8	for	for	ADP
ecletica-511	130	9	this	this	DET
ecletica-511	130	10	proposal	proposal	NOUN
ecletica-511	130	11	.	.	PUNCT
ecletica-511	131	1	the	the	DET
ecletica-511	131	2	experimental	experimental	ADJ
ecletica-511	131	3	deviations	deviation	NOUN
ecletica-511	131	4	of	of	ADP
ecletica-511	131	5	the	the	DET
ecletica-511	131	6	kinetic	kinetic	ADJ
ecletica-511	131	7	measurements	measurement	NOUN
ecletica-511	131	8	are	be	AUX
ecletica-511	131	9	quite	quite	ADV
ecletica-511	131	10	satisfactory	satisfactory	ADJ
ecletica-511	131	11	for	for	ADP
ecletica-511	131	12	stoppedflow	stoppedflow	ADJ
ecletica-511	131	13	experiments	experiment	NOUN
ecletica-511	131	14	.	.	PUNCT
ecletica-511	132	1	all	all	DET
ecletica-511	132	2	the	the	DET
ecletica-511	132	3	individual	individual	ADJ
ecletica-511	132	4	solution	solution	NOUN
ecletica-511	132	5	behaviors	behavior	NOUN
ecletica-511	132	6	are	be	AUX
ecletica-511	132	7	coherent	coherent	ADJ
ecletica-511	132	8	with	with	ADP
ecletica-511	132	9	this	this	DET
ecletica-511	132	10	model	model	NOUN
ecletica-511	132	11	and	and	CCONJ
ecletica-511	132	12	the	the	DET
ecletica-511	132	13	rate	rate	NOUN
ecletica-511	132	14	constant	constant	ADJ
ecletica-511	132	15	depends	depend	VERB
ecletica-511	132	16	only	only	ADV
ecletica-511	132	17	on	on	ADP
ecletica-511	132	18	the	the	DET
ecletica-511	132	19	cation	cation	NOUN
ecletica-511	132	20	.	.	PUNCT
ecletica-511	133	1	the	the	DET
ecletica-511	133	2	effect	effect	NOUN
ecletica-511	133	3	of	of	ADP
ecletica-511	133	4	the	the	DET
ecletica-511	133	5	anion	anion	NOUN
ecletica-511	133	6	does	do	AUX
ecletica-511	133	7	not	not	PART
ecletica-511	133	8	significantly	significantly	ADV
ecletica-511	133	9	affect	affect	VERB
ecletica-511	133	10	the	the	DET
ecletica-511	133	11	reaction	reaction	NOUN
ecletica-511	133	12	.	.	PUNCT
ecletica-511	134	1	as	as	SCONJ
ecletica-511	134	2	was	be	AUX
ecletica-511	134	3	already	already	ADV
ecletica-511	134	4	pointed	point	VERB
ecletica-511	134	5	out	out	ADP
ecletica-511	134	6	,	,	PUNCT
ecletica-511	134	7	it	it	PRON
ecletica-511	134	8	seems	seem	VERB
ecletica-511	134	9	that	that	SCONJ
ecletica-511	134	10	the	the	DET
ecletica-511	134	11	equimolar	equimolar	NOUN
ecletica-511	134	12	mixtures	mixture	NOUN
ecletica-511	134	13	react	react	VERB
ecletica-511	134	14	like	like	ADP
ecletica-511	134	15	an	an	DET
ecletica-511	134	16	unique	unique	ADJ
ecletica-511	134	17	species	specie	NOUN
ecletica-511	134	18	with	with	ADP
ecletica-511	134	19	a	a	DET
ecletica-511	134	20	rate	rate	NOUN
ecletica-511	134	21	constant	constant	ADJ
ecletica-511	134	22	closer	close	ADV
ecletica-511	134	23	to	to	ADP
ecletica-511	134	24	that	that	PRON
ecletica-511	134	25	of	of	ADP
ecletica-511	134	26	copper	copper	NOUN
ecletica-511	134	27	.	.	PUNCT
ecletica-511	135	1	the	the	DET
ecletica-511	135	2	complex	complex	NOUN
ecletica-511	135	3	formed	form	VERB
ecletica-511	135	4	in	in	ADP
ecletica-511	135	5	the	the	DET
ecletica-511	135	6	solution	solution	NOUN
ecletica-511	135	7	containing	contain	VERB
ecletica-511	135	8	both	both	DET
ecletica-511	135	9	cations	cation	NOUN
ecletica-511	135	10	closely	closely	ADV
ecletica-511	135	11	resembles	resemble	VERB
ecletica-511	135	12	that	that	PRON
ecletica-511	135	13	of	of	ADP
ecletica-511	135	14	copper	copper	NOUN
ecletica-511	135	15	alone	alone	ADJ
ecletica-511	135	16	than	than	ADP
ecletica-511	135	17	that	that	PRON
ecletica-511	135	18	of	of	ADP
ecletica-511	135	19	zinc	zinc	NOUN
ecletica-511	135	20	.	.	PUNCT
ecletica-511	136	1	this	this	DET
ecletica-511	136	2	kind	kind	NOUN
ecletica-511	136	3	of	of	ADP
ecletica-511	136	4	behavior	behavior	NOUN
ecletica-511	136	5	may	may	AUX
ecletica-511	136	6	be	be	AUX
ecletica-511	136	7	surprising	surprising	ADJ
ecletica-511	136	8	but	but	CCONJ
ecletica-511	136	9	it	it	PRON
ecletica-511	136	10	becomes	become	VERB
ecletica-511	136	11	easier	easy	ADJ
ecletica-511	136	12	to	to	PART
ecletica-511	136	13	understand	understand	VERB
ecletica-511	136	14	if	if	SCONJ
ecletica-511	136	15	interactions	interaction	NOUN
ecletica-511	136	16	of	of	ADP
ecletica-511	136	17	water	water	NOUN
ecletica-511	136	18	molecules	molecule	NOUN
ecletica-511	136	19	of	of	ADP
ecletica-511	136	20	the	the	DET
ecletica-511	136	21	solution	solution	NOUN
ecletica-511	136	22	and	and	CCONJ
ecletica-511	136	23	the	the	DET
ecletica-511	136	24	metallic	metallic	ADJ
ecletica-511	136	25	cations	cation	NOUN
ecletica-511	136	26	are	be	AUX
ecletica-511	136	27	considered	consider	VERB
ecletica-511	136	28	to	to	PART
ecletica-511	136	29	form	form	VERB
ecletica-511	136	30	an	an	DET
ecletica-511	136	31	assembly	assembly	NOUN
ecletica-511	136	32	.	.	PUNCT
ecletica-511	137	1	this	this	DET
ecletica-511	137	2	kind	kind	NOUN
ecletica-511	137	3	of	of	ADP
ecletica-511	137	4	interaction	interaction	NOUN
ecletica-511	137	5	,	,	PUNCT
ecletica-511	137	6	briefly	briefly	ADV
ecletica-511	137	7	commented	comment	VERB
ecletica-511	137	8	above	above	ADV
ecletica-511	137	9	is	be	AUX
ecletica-511	137	10	hard	hard	ADJ
ecletica-511	137	11	to	to	PART
ecletica-511	137	12	visualize	visualize	VERB
ecletica-511	137	13	due	due	ADP
ecletica-511	137	14	to	to	ADP
ecletica-511	137	15	the	the	DET
ecletica-511	137	16	difficulty	difficulty	NOUN
ecletica-511	137	17	in	in	ADP
ecletica-511	137	18	providing	provide	VERB
ecletica-511	137	19	a	a	DET
ecletica-511	137	20	structural	structural	ADJ
ecletica-511	137	21	description	description	NOUN
ecletica-511	137	22	which	which	PRON
ecletica-511	137	23	accounts	account	VERB
ecletica-511	137	24	for	for	ADP
ecletica-511	137	25	the	the	DET
ecletica-511	137	26	ability	ability	NOUN
ecletica-511	137	27	of	of	ADP
ecletica-511	137	28	water	water	NOUN
ecletica-511	137	29	molecules	molecule	NOUN
ecletica-511	137	30	to	to	PART
ecletica-511	137	31	form	form	VERB
ecletica-511	137	32	structures	structure	NOUN
ecletica-511	137	33	of	of	ADP
ecletica-511	137	34	a	a	DET
ecletica-511	137	35	collective	collective	ADJ
ecletica-511	137	36	character	character	NOUN
ecletica-511	137	37	.	.	PUNCT
ecletica-511	138	1	so	so	ADV
ecletica-511	138	2	,	,	PUNCT
ecletica-511	138	3	in	in	ADP
ecletica-511	138	4	most	most	ADJ
ecletica-511	138	5	cases	case	NOUN
ecletica-511	138	6	the	the	DET
ecletica-511	138	7	effects	effect	NOUN
ecletica-511	138	8	of	of	ADP
ecletica-511	138	9	these	these	DET
ecletica-511	138	10	interactions	interaction	NOUN
ecletica-511	138	11	are	be	AUX
ecletica-511	138	12	neglected	neglect	VERB
ecletica-511	138	13	.	.	PUNCT
ecletica-511	139	1	earlier	early	ADV
ecletica-511	139	2	infrared	infrared	ADJ
ecletica-511	139	3	studies	study	NOUN
ecletica-511	139	4	of	of	ADP
ecletica-511	139	5	aqueous	aqueous	ADJ
ecletica-511	139	6	ionic	ionic	ADJ
ecletica-511	139	7	solutions	solution	NOUN
ecletica-511	139	8	[	[	X
ecletica-511	139	9	7	7	NUM
ecletica-511	139	10	]	]	PUNCT
ecletica-511	139	11	and	and	CCONJ
ecletica-511	139	12	kinetic	kinetic	ADJ
ecletica-511	139	13	studies	study	NOUN
ecletica-511	139	14	of	of	ADP
ecletica-511	139	15	zincon	zincon	NOUN
ecletica-511	139	16	complexes	complex	NOUN
ecletica-511	140	1	[	[	X
ecletica-511	140	2	9	9	NUM
ecletica-511	140	3	]	]	PUNCT
ecletica-511	140	4	indicate	indicate	VERB
ecletica-511	140	5	that	that	SCONJ
ecletica-511	140	6	the	the	DET
ecletica-511	140	7	solvation	solvation	NOUN
ecletica-511	140	8	water	water	NOUN
ecletica-511	140	9	molecules	molecule	NOUN
ecletica-511	140	10	,	,	PUNCT
ecletica-511	140	11	and	and	CCONJ
ecletica-511	140	12	the	the	DET
ecletica-511	140	13	“	"	PUNCT
ecletica-511	140	14	structure	structure	NOUN
ecletica-511	140	15	”	"	PUNCT
ecletica-511	140	16	of	of	ADP
ecletica-511	140	17	the	the	DET
ecletica-511	140	18	aqueous	aqueous	ADJ
ecletica-511	140	19	solution	solution	NOUN
ecletica-511	140	20	,	,	PUNCT
ecletica-511	140	21	must	must	AUX
ecletica-511	140	22	be	be	AUX
ecletica-511	140	23	considered	consider	VERB
ecletica-511	140	24	in	in	ADP
ecletica-511	140	25	reaction	reaction	NOUN
ecletica-511	140	26	mechanism	mechanism	NOUN
ecletica-511	140	27	studies	study	NOUN
ecletica-511	140	28	.	.	PUNCT
ecletica-511	141	1	although	although	SCONJ
ecletica-511	141	2	these	these	DET
ecletica-511	141	3	kinds	kind	NOUN
ecletica-511	141	4	of	of	ADP
ecletica-511	141	5	interactions	interaction	NOUN
ecletica-511	141	6	are	be	AUX
ecletica-511	141	7	weak	weak	ADJ
ecletica-511	141	8	,	,	PUNCT
ecletica-511	141	9	they	they	PRON
ecletica-511	141	10	probably	probably	ADV
ecletica-511	141	11	affect	affect	VERB
ecletica-511	141	12	the	the	DET
ecletica-511	141	13	complexation	complexation	NOUN
ecletica-511	141	14	.	.	PUNCT
ecletica-511	142	1	it	it	PRON
ecletica-511	142	2	can	can	AUX
ecletica-511	142	3	be	be	AUX
ecletica-511	142	4	supposed	suppose	VERB
ecletica-511	142	5	that	that	SCONJ
ecletica-511	142	6	in	in	ADP
ecletica-511	142	7	aqueous	aqueous	ADJ
ecletica-511	142	8	solution	solution	NOUN
ecletica-511	142	9	there	there	PRON
ecletica-511	142	10	are	be	VERB
ecletica-511	142	11	solvated	solvate	VERB
ecletica-511	142	12	cations	cation	NOUN
ecletica-511	142	13	ecl	ecl	PROPN
ecletica-511	142	14	.	.	PROPN
ecletica-511	142	15	quím	quím	PROPN
ecletica-511	142	16	.	.	PUNCT
ecletica-511	142	17	,	,	PUNCT
ecletica-511	142	18	são	são	PROPN
ecletica-511	142	19	paulo	paulo	PROPN
ecletica-511	142	20	,	,	PUNCT
ecletica-511	142	21	28(1	28(1	NOUN
ecletica-511	142	22	):	):	PUNCT
ecletica-511	142	23	55	55	NUM
ecletica-511	142	24	-	-	SYM
ecletica-511	142	25	62	62	NUM
ecletica-511	142	26	,	,	PUNCT
ecletica-511	142	27	2003	2003	NUM
ecletica-511	142	28	61	61	NUM
ecletica-511	142	29	clusters	cluster	NOUN
ecletica-511	142	30	linked	link	VERB
ecletica-511	142	31	by	by	ADP
ecletica-511	142	32	h	h	NOUN
ecletica-511	142	33	-	-	PUNCT
ecletica-511	142	34	bondings	bonding	NOUN
ecletica-511	142	35	.	.	PUNCT
ecletica-511	143	1	in	in	ADP
ecletica-511	143	2	solutions	solution	NOUN
ecletica-511	143	3	of	of	ADP
ecletica-511	143	4	zn2++	zn2++	PROPN
ecletica-511	143	5	cu2	cu2	PROPN
ecletica-511	143	6	+	+	CCONJ
ecletica-511	143	7	mixtures	mixture	NOUN
ecletica-511	143	8	,	,	PUNCT
ecletica-511	143	9	these	these	DET
ecletica-511	143	10	assemblies	assembly	NOUN
ecletica-511	143	11	probably	probably	ADV
ecletica-511	143	12	contain	contain	VERB
ecletica-511	143	13	both	both	DET
ecletica-511	143	14	cations	cation	NOUN
ecletica-511	143	15	.	.	PUNCT
ecletica-511	144	1	the	the	DET
ecletica-511	144	2	reaction	reaction	NOUN
ecletica-511	144	3	of	of	ADP
ecletica-511	144	4	complex	complex	ADJ
ecletica-511	144	5	formation	formation	NOUN
ecletica-511	144	6	would	would	AUX
ecletica-511	144	7	occur	occur	VERB
ecletica-511	144	8	through	through	ADP
ecletica-511	144	9	these	these	DET
ecletica-511	144	10	solvated	solvate	VERB
ecletica-511	144	11	cations	cation	NOUN
ecletica-511	144	12	clusters	cluster	NOUN
ecletica-511	144	13	,	,	PUNCT
ecletica-511	144	14	whose	whose	DET
ecletica-511	144	15	properties	property	NOUN
ecletica-511	144	16	are	be	AUX
ecletica-511	144	17	not	not	PART
ecletica-511	144	18	necessarily	necessarily	ADV
ecletica-511	144	19	the	the	DET
ecletica-511	144	20	average	average	NOUN
ecletica-511	144	21	of	of	ADP
ecletica-511	144	22	zn2	zn2	PROPN
ecletica-511	144	23	+	+	PROPN
ecletica-511	144	24	and	and	CCONJ
ecletica-511	144	25	cu2	cu2	NOUN
ecletica-511	144	26	+	+	CCONJ
ecletica-511	144	27	individual	individual	ADJ
ecletica-511	144	28	clusters	cluster	NOUN
ecletica-511	144	29	.	.	PUNCT
ecletica-511	145	1	in	in	ADP
ecletica-511	145	2	this	this	DET
ecletica-511	145	3	way	way	NOUN
ecletica-511	145	4	,	,	PUNCT
ecletica-511	145	5	the	the	DET
ecletica-511	145	6	proposed	propose	VERB
ecletica-511	145	7	mechanism	mechanism	NOUN
ecletica-511	145	8	could	could	AUX
ecletica-511	145	9	be	be	AUX
ecletica-511	145	10	described	describe	VERB
ecletica-511	145	11	in	in	ADP
ecletica-511	145	12	more	more	ADJ
ecletica-511	145	13	detail	detail	NOUN
ecletica-511	145	14	by	by	ADP
ecletica-511	145	15	considering	consider	VERB
ecletica-511	145	16	the	the	DET
ecletica-511	145	17	solvated	solvate	VERB
ecletica-511	145	18	cations	cation	NOUN
ecletica-511	145	19	clusters	cluster	NOUN
ecletica-511	145	20	.	.	PUNCT
ecletica-511	146	1	under	under	ADP
ecletica-511	146	2	such	such	ADJ
ecletica-511	146	3	conditions	condition	NOUN
ecletica-511	146	4	the	the	DET
ecletica-511	146	5	kinetics	kinetic	NOUN
ecletica-511	146	6	of	of	ADP
ecletica-511	146	7	the	the	DET
ecletica-511	146	8	mixtures	mixture	NOUN
ecletica-511	146	9	could	could	AUX
ecletica-511	146	10	be	be	AUX
ecletica-511	146	11	understood	understand	VERB
ecletica-511	146	12	.	.	PUNCT
ecletica-511	147	1	polynuclear	polynuclear	PROPN
ecletica-511	147	2	aquo	aquo	PROPN
ecletica-511	147	3	-	-	PUNCT
ecletica-511	147	4	hydroxo	hydroxo	PROPN
ecletica-511	147	5	copper	copper	NOUN
ecletica-511	147	6	and	and	CCONJ
ecletica-511	147	7	zinc	zinc	NOUN
ecletica-511	147	8	complexes	complex	NOUN
ecletica-511	147	9	have	have	AUX
ecletica-511	147	10	been	be	AUX
ecletica-511	147	11	reported	report	VERB
ecletica-511	147	12	in	in	ADP
ecletica-511	147	13	the	the	DET
ecletica-511	147	14	literature	literature	NOUN
ecletica-511	147	15	[	[	X
ecletica-511	147	16	2	2	NUM
ecletica-511	147	17	,	,	PUNCT
ecletica-511	147	18	6	6	NUM
ecletica-511	147	19	,	,	PUNCT
ecletica-511	147	20	4	4	NUM
ecletica-511	147	21	]	]	PUNCT
ecletica-511	147	22	.	.	PUNCT
ecletica-511	148	1	in	in	ADP
ecletica-511	148	2	complexation	complexation	NOUN
ecletica-511	148	3	reactions	reaction	NOUN
ecletica-511	148	4	of	of	ADP
ecletica-511	148	5	zincon	zincon	NOUN
ecletica-511	148	6	with	with	ADP
ecletica-511	148	7	zn2	zn2	PROPN
ecletica-511	148	8	+	+	PROPN
ecletica-511	148	9	and	and	CCONJ
ecletica-511	148	10	cu2	cu2	NOUN
ecletica-511	148	11	+	+	PROPN
ecletica-511	148	12	,	,	PUNCT
ecletica-511	148	13	such	such	ADJ
ecletica-511	148	14	aquo	aquo	ADJ
ecletica-511	148	15	-	-	PUNCT
ecletica-511	148	16	hydroxo	hydroxo	ADJ
ecletica-511	148	17	complexes	complex	NOUN
ecletica-511	148	18	are	be	AUX
ecletica-511	148	19	assumed	assume	VERB
ecletica-511	148	20	to	to	PART
ecletica-511	148	21	play	play	VERB
ecletica-511	148	22	an	an	DET
ecletica-511	148	23	important	important	ADJ
ecletica-511	148	24	role	role	NOUN
ecletica-511	148	25	[	[	X
ecletica-511	148	26	9	9	NUM
ecletica-511	148	27	]	]	PUNCT
ecletica-511	148	28	.	.	PUNCT
ecletica-511	149	1	the	the	DET
ecletica-511	149	2	formation	formation	NOUN
ecletica-511	149	3	of	of	ADP
ecletica-511	149	4	hydroxo	hydroxo	NOUN
ecletica-511	149	5	and/or	and/or	CCONJ
ecletica-511	149	6	borate	borate	VERB
ecletica-511	149	7	aquo	aquo	NOUN
ecletica-511	149	8	complexes	complex	NOUN
ecletica-511	149	9	of	of	ADP
ecletica-511	149	10	zn2	zn2	PROPN
ecletica-511	149	11	+	+	PROPN
ecletica-511	149	12	and	and	CCONJ
ecletica-511	149	13	of	of	ADP
ecletica-511	149	14	cu2	cu2	NOUN
ecletica-511	149	15	+	+	CCONJ
ecletica-511	149	16	can	can	AUX
ecletica-511	149	17	not	not	PART
ecletica-511	149	18	be	be	AUX
ecletica-511	149	19	actually	actually	ADV
ecletica-511	149	20	ignored	ignore	VERB
ecletica-511	149	21	as	as	SCONJ
ecletica-511	149	22	borate	borate	NOUN
ecletica-511	149	23	buffer	buffer	NOUN
ecletica-511	149	24	was	be	AUX
ecletica-511	149	25	used	use	VERB
ecletica-511	149	26	.	.	PUNCT
ecletica-511	150	1	for	for	ADP
ecletica-511	150	2	instance	instance	NOUN
ecletica-511	150	3	,	,	PUNCT
ecletica-511	150	4	borate	borate	NOUN
ecletica-511	150	5	could	could	AUX
ecletica-511	150	6	be	be	AUX
ecletica-511	150	7	supposed	suppose	VERB
ecletica-511	150	8	to	to	PART
ecletica-511	150	9	be	be	AUX
ecletica-511	150	10	bonded	bond	VERB
ecletica-511	150	11	to	to	ADP
ecletica-511	150	12	cations	cation	NOUN
ecletica-511	150	13	complexed	complexe	VERB
ecletica-511	150	14	with	with	ADP
ecletica-511	150	15	par	par	NOUN
ecletica-511	150	16	,	,	PUNCT
ecletica-511	150	17	substituting	substitute	VERB
ecletica-511	150	18	water	water	NOUN
ecletica-511	150	19	molecules	molecule	NOUN
ecletica-511	150	20	or	or	CCONJ
ecletica-511	150	21	oh-	oh-	NOUN
ecletica-511	150	22	,	,	PUNCT
ecletica-511	150	23	acting	acting	NOUN
ecletica-511	150	24	,	,	PUNCT
ecletica-511	150	25	or	or	CCONJ
ecletica-511	150	26	not	not	PART
ecletica-511	150	27	,	,	PUNCT
ecletica-511	150	28	as	as	ADP
ecletica-511	150	29	bridges	bridge	NOUN
ecletica-511	150	30	.	.	PUNCT
ecletica-511	151	1	however	however	ADV
ecletica-511	151	2	the	the	DET
ecletica-511	151	3	borate	borate	NOUN
ecletica-511	151	4	buffer	buffer	NOUN
ecletica-511	151	5	was	be	AUX
ecletica-511	151	6	chosen	choose	VERB
ecletica-511	151	7	among	among	ADP
ecletica-511	151	8	others	other	NOUN
ecletica-511	151	9	as	as	ADP
ecletica-511	151	10	less	less	ADV
ecletica-511	151	11	troubling	troubling	ADJ
ecletica-511	151	12	and	and	CCONJ
ecletica-511	151	13	the	the	DET
ecletica-511	151	14	eventual	eventual	ADJ
ecletica-511	151	15	participation	participation	NOUN
ecletica-511	151	16	of	of	ADP
ecletica-511	151	17	borate	borate	NOUN
ecletica-511	151	18	may	may	AUX
ecletica-511	151	19	be	be	AUX
ecletica-511	151	20	neglected	neglect	VERB
ecletica-511	151	21	in	in	ADP
ecletica-511	151	22	the	the	DET
ecletica-511	151	23	general	general	ADJ
ecletica-511	151	24	mechanism	mechanism	NOUN
ecletica-511	151	25	proposed	propose	VERB
ecletica-511	151	26	above	above	ADV
ecletica-511	151	27	.	.	PUNCT
ecletica-511	152	1	the	the	DET
ecletica-511	152	2	results	result	NOUN
ecletica-511	152	3	obtained	obtain	VERB
ecletica-511	152	4	in	in	ADP
ecletica-511	152	5	this	this	DET
ecletica-511	152	6	study	study	NOUN
ecletica-511	152	7	indicate	indicate	VERB
ecletica-511	152	8	that	that	SCONJ
ecletica-511	152	9	in	in	ADP
ecletica-511	152	10	kinetic	kinetic	ADJ
ecletica-511	152	11	studies	study	NOUN
ecletica-511	152	12	,	,	PUNCT
ecletica-511	152	13	and	and	CCONJ
ecletica-511	152	14	therefore	therefore	ADV
ecletica-511	152	15	in	in	ADP
ecletica-511	152	16	the	the	DET
ecletica-511	152	17	development	development	NOUN
ecletica-511	152	18	of	of	ADP
ecletica-511	152	19	quantitative	quantitative	ADJ
ecletica-511	152	20	kinetic	kinetic	ADJ
ecletica-511	152	21	methods	method	NOUN
ecletica-511	152	22	of	of	ADP
ecletica-511	152	23	analysis	analysis	NOUN
ecletica-511	152	24	,	,	PUNCT
ecletica-511	152	25	the	the	DET
ecletica-511	152	26	results	result	NOUN
ecletica-511	152	27	obtained	obtain	VERB
ecletica-511	152	28	in	in	ADP
ecletica-511	152	29	mixtures	mixture	NOUN
ecletica-511	152	30	are	be	AUX
ecletica-511	152	31	not	not	PART
ecletica-511	152	32	necessarily	necessarily	ADV
ecletica-511	152	33	the	the	DET
ecletica-511	152	34	mathematical	mathematical	ADJ
ecletica-511	152	35	mean	mean	NOUN
ecletica-511	152	36	of	of	ADP
ecletica-511	152	37	those	those	PRON
ecletica-511	152	38	of	of	ADP
ecletica-511	152	39	the	the	DET
ecletica-511	152	40	individual	individual	ADJ
ecletica-511	152	41	species	specie	NOUN
ecletica-511	152	42	.	.	PUNCT
ecletica-511	153	1	also	also	ADV
ecletica-511	153	2	,	,	PUNCT
ecletica-511	153	3	for	for	ADP
ecletica-511	153	4	analytical	analytical	ADJ
ecletica-511	153	5	determinations	determination	NOUN
ecletica-511	153	6	in	in	ADP
ecletica-511	153	7	equilibrium	equilibrium	NOUN
ecletica-511	153	8	systems	system	NOUN
ecletica-511	153	9	,	,	PUNCT
ecletica-511	153	10	it	it	PRON
ecletica-511	153	11	must	must	AUX
ecletica-511	153	12	be	be	AUX
ecletica-511	153	13	taken	take	VERB
ecletica-511	153	14	into	into	ADP
ecletica-511	153	15	account	account	NOUN
ecletica-511	153	16	that	that	SCONJ
ecletica-511	153	17	the	the	DET
ecletica-511	153	18	spectra	spectra	NOUN
ecletica-511	153	19	of	of	ADP
ecletica-511	153	20	the	the	DET
ecletica-511	153	21	complexes	complex	NOUN
ecletica-511	153	22	formed	form	VERB
ecletica-511	153	23	in	in	ADP
ecletica-511	153	24	solutions	solution	NOUN
ecletica-511	153	25	containing	contain	VERB
ecletica-511	153	26	more	more	ADJ
ecletica-511	153	27	than	than	ADP
ecletica-511	153	28	one	one	NUM
ecletica-511	153	29	kind	kind	NOUN
ecletica-511	153	30	of	of	ADP
ecletica-511	153	31	cation	cation	NOUN
ecletica-511	153	32	that	that	PRON
ecletica-511	153	33	is	be	AUX
ecletica-511	153	34	being	be	AUX
ecletica-511	153	35	complexed	complexe	VERB
ecletica-511	153	36	,	,	PUNCT
ecletica-511	153	37	are	be	AUX
ecletica-511	153	38	not	not	PART
ecletica-511	153	39	necessarily	necessarily	ADV
ecletica-511	153	40	the	the	DET
ecletica-511	153	41	sum	sum	NOUN
ecletica-511	153	42	of	of	ADP
ecletica-511	153	43	the	the	DET
ecletica-511	153	44	individual	individual	ADJ
ecletica-511	153	45	spectra	spectra	PROPN
ecletica-511	153	46	.	.	PUNCT
ecletica-511	154	1	acknowledgement	acknowledgement	NOUN
ecletica-511	154	2	the	the	DET
ecletica-511	154	3	authors	author	NOUN
ecletica-511	154	4	gratefully	gratefully	ADV
ecletica-511	154	5	acknowledge	acknowledge	VERB
ecletica-511	154	6	the	the	DET
ecletica-511	154	7	fundação	fundação	PROPN
ecletica-511	154	8	de	de	PROPN
ecletica-511	154	9	amparo	amparo	PROPN
ecletica-511	154	10	a	a	DET
ecletica-511	154	11	pesquisa	pesquisa	NOUN
ecletica-511	154	12	do	do	AUX
ecletica-511	154	13	estado	estado	PROPN
ecletica-511	154	14	de	de	PROPN
ecletica-511	154	15	são	são	PROPN
ecletica-511	154	16	paulo	paulo	PROPN
ecletica-511	154	17	(	(	PUNCT
ecletica-511	154	18	fapesp	fapesp	NOUN
ecletica-511	154	19	)	)	PUNCT
ecletica-511	154	20	and	and	CCONJ
ecletica-511	154	21	the	the	DET
ecletica-511	154	22	conselho	conselho	ADJ
ecletica-511	154	23	nacional	nacional	PROPN
ecletica-511	154	24	de	de	X
ecletica-511	154	25	desenvolvimento	desenvolvimento	PROPN
ecletica-511	154	26	científico	científico	PROPN
ecletica-511	154	27	e	e	NOUN
ecletica-511	154	28	tecnológico	tecnológico	PROPN
ecletica-511	154	29	(	(	PUNCT
ecletica-511	154	30	cnpq	cnpq	NOUN
ecletica-511	154	31	)	)	PUNCT
ecletica-511	154	32	for	for	ADP
ecletica-511	154	33	financial	financial	ADJ
ecletica-511	154	34	support	support	NOUN
ecletica-511	154	35	and	and	CCONJ
ecletica-511	154	36	scholarships	scholarship	NOUN
ecletica-511	154	37	.	.	PUNCT
ecletica-511	155	1	rossi	rossi	PROPN
ecletica-511	155	2	,	,	PUNCT
ecletica-511	155	3	a.	a.	PROPN
ecletica-511	155	4	v.	v.	PROPN
ecletica-511	155	5	;	;	PUNCT
ecletica-511	155	6	tubino	tubino	NOUN
ecletica-511	155	7	,	,	PUNCT
ecletica-511	155	8	m.	m.	NOUN
ecletica-511	155	9	sobre	sobre	PROPN
ecletica-511	155	10	a	a	DET
ecletica-511	155	11	cinética	cinética	PROPN
ecletica-511	155	12	e	e	X
ecletica-511	155	13	o	o	PROPN
ecletica-511	155	14	mecanismo	mecanismo	VERB
ecletica-511	155	15	das	das	PROPN
ecletica-511	155	16	reações	reações	PROPN
ecletica-511	155	17	de	de	PROPN
ecletica-511	155	18	4	4	NUM
ecletica-511	155	19	-	-	SYM
ecletica-511	155	20	2(piridilazo)-resorcinol	2(piridilazo)-resorcinol	NUM
ecletica-511	155	21	como	como	ADJ
ecletica-511	155	22	zn2	zn2	PROPN
ecletica-511	156	1	+	+	PROPN
ecletica-511	156	2	,	,	PUNCT
ecletica-511	156	3	cu2	cu2	NOUN
ecletica-511	156	4	+	+	CCONJ
ecletica-511	156	5	e	e	NOUN
ecletica-511	156	6	com	com	NOUN
ecletica-511	156	7	misturas	misturas	PROPN
ecletica-511	156	8	equimolares	equimolares	PROPN
ecletica-511	156	9	de	de	X
ecletica-511	156	10	zn2	zn2	PROPN
ecletica-511	156	11	+	+	PROPN
ecletica-511	156	12	+	+	CCONJ
ecletica-511	156	13	cu2	cu2	NOUN
ecletica-511	156	14	+	+	PROPN
ecletica-511	156	15	,	,	PUNCT
ecletica-511	156	16	em	em	PRON
ecletica-511	156	17	solução	solução	NOUN
ecletica-511	156	18	aquosa	aquosa	PROPN
ecletica-511	156	19	.	.	PUNCT
ecletica-511	157	1	resumo	resumo	VERB
ecletica-511	157	2	a	a	DET
ecletica-511	157	3	cinética	cinética	NOUN
ecletica-511	157	4	e	e	X
ecletica-511	157	5	o	o	PROPN
ecletica-511	157	6	mecanismo	mecanismo	VERB
ecletica-511	157	7	das	das	PROPN
ecletica-511	157	8	reações	reações	PROPN
ecletica-511	157	9	entre	entre	PROPN
ecletica-511	157	10	4-(2	4-(2	PROPN
ecletica-511	157	11	-	-	PUNCT
ecletica-511	157	12	piridilazo)-resorcinol	piridilazo)-resorcinol	PROPN
ecletica-511	157	13	e	e	NOUN
ecletica-511	157	14	zn2	zn2	NOUN
ecletica-511	157	15	+	+	PROPN
ecletica-511	157	16	,	,	PUNCT
ecletica-511	157	17	cu2	cu2	NOUN
ecletica-511	158	1	+	+	CCONJ
ecletica-511	158	2	e	e	NOUN
ecletica-511	158	3	misturas	misturas	X
ecletica-511	158	4	equimolares	equimolare	NOUN
ecletica-511	158	5	de	de	X
ecletica-511	158	6	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	158	7	+	+	CCONJ
ecletica-511	158	8	foram	foram	NOUN
ecletica-511	158	9	estudados	estudado	NOUN
ecletica-511	158	10	.	.	PUNCT
ecletica-511	159	1	as	as	SCONJ
ecletica-511	159	2	reações	reações	PROPN
ecletica-511	159	3	foram	foram	PROPN
ecletica-511	159	4	realizadas	realizada	VERB
ecletica-511	159	5	em	em	PRON
ecletica-511	159	6	solução	solução	NOUN
ecletica-511	159	7	aquosa	aquosa	NOUN
ecletica-511	159	8	(	(	PUNCT
ecletica-511	159	9	ph	ph	NOUN
ecletica-511	159	10	=	=	SYM
ecletica-511	159	11	8.5	8.5	NUM
ecletica-511	159	12	,	,	PUNCT
ecletica-511	159	13	tampão	tampão	ADJ
ecletica-511	159	14	borato	borato	NOUN
ecletica-511	159	15	)	)	PUNCT
ecletica-511	160	1	e	e	NOUN
ecletica-511	160	2	monitoradas	monitorada	VERB
ecletica-511	160	3	espectrofotometricamente	espectrofotometricamente	ADV
ecletica-511	160	4	em	em	PRON
ecletica-511	160	5	500	500	NUM
ecletica-511	160	6	nm	nm	NOUN
ecletica-511	160	7	com	com	NOUN
ecletica-511	160	8	a	a	DET
ecletica-511	160	9	técnica	técnica	PROPN
ecletica-511	160	10	de	de	PROPN
ecletica-511	160	11	fluxo	fluxo	PROPN
ecletica-511	160	12	interrompido	interrompido	NOUN
ecletica-511	160	13	.	.	PUNCT
ecletica-511	161	1	os	os	PROPN
ecletica-511	161	2	dados	dado	NOUN
ecletica-511	161	3	espectrais	espectrais	PROPN
ecletica-511	161	4	e	e	X
ecletica-511	161	5	cinéticos	cinéticos	PROPN
ecletica-511	161	6	indicam	indicam	VERB
ecletica-511	161	7	que	que	PROPN
ecletica-511	161	8	a	a	DET
ecletica-511	161	9	mistura	mistura	PROPN
ecletica-511	161	10	equimolar	equimolar	NOUN
ecletica-511	161	11	zn2++cu2	zn2++cu2	PUNCT
ecletica-511	161	12	+	+	CCONJ
ecletica-511	161	13	comporta	comporta	PROPN
ecletica-511	161	14	-	-	PUNCT
ecletica-511	161	15	se	se	PROPN
ecletica-511	161	16	como	como	PROPN
ecletica-511	161	17	uma	uma	PROPN
ecletica-511	161	18	única	única	PROPN
ecletica-511	161	19	espécie	espécie	PROPN
ecletica-511	161	20	,	,	PUNCT
ecletica-511	161	21	sendo	sendo	PROPN
ecletica-511	161	22	que	que	PROPN
ecletica-511	161	23	isto	isto	PROPN
ecletica-511	161	24	pode	pode	PROPN
ecletica-511	161	25	ser	ser	PROPN
ecletica-511	161	26	atribuído	atribuído	PROPN
ecletica-511	161	27	a	a	DET
ecletica-511	161	28	interações	interações	NOUN
ecletica-511	161	29	dos	dos	NOUN
ecletica-511	161	30	íons	íon	NOUN
ecletica-511	161	31	zn2	zn2	VERB
ecletica-511	161	32	+	+	ADP
ecletica-511	161	33	e	e	X
ecletica-511	161	34	cu2	cu2	X
ecletica-511	161	35	+	+	NOUN
ecletica-511	161	36	com	com	NOUN
ecletica-511	161	37	moléculas	molécula	NOUN
ecletica-511	161	38	de	de	PROPN
ecletica-511	161	39	água	água	PROPN
ecletica-511	161	40	na	na	X
ecletica-511	161	41	solução	solução	PROPN
ecletica-511	161	42	aquosa	aquosa	PROPN
ecletica-511	161	43	.	.	PUNCT
ecletica-511	162	1	apresenta	apresenta	PROPN
ecletica-511	162	2	-	-	PUNCT
ecletica-511	162	3	se	se	PROPN
ecletica-511	162	4	uma	uma	PROPN
ecletica-511	162	5	proposta	proposta	PROPN
ecletica-511	162	6	de	de	X
ecletica-511	162	7	mecanismo	mecanismo	PROPN
ecletica-511	162	8	e	e	PROPN
ecletica-511	162	9	as	as	SCONJ
ecletica-511	162	10	constantes	constante	NOUN
ecletica-511	162	11	de	de	PROPN
ecletica-511	162	12	velocidade	velocidade	PROPN
ecletica-511	162	13	são	são	PROPN
ecletica-511	162	14	calculadas	calculada	VERB
ecletica-511	162	15	.	.	PUNCT
ecletica-511	163	1	palavras	palavra	NOUN
ecletica-511	163	2	-	-	PUNCT
ecletica-511	163	3	chave	chave	NOUN
ecletica-511	163	4	:	:	PUNCT
ecletica-511	163	5	par	par	NOUN
ecletica-511	163	6	,	,	PUNCT
ecletica-511	163	7	zinco	zinco	PROPN
ecletica-511	163	8	,	,	PUNCT
ecletica-511	163	9	cobre	cobre	PROPN
ecletica-511	163	10	,	,	PUNCT
ecletica-511	163	11	cinética	cinética	PROPN
ecletica-511	163	12	,	,	PUNCT
ecletica-511	163	13	mecanismo	mecanismo	VERB
ecletica-511	163	14	.	.	PUNCT
ecletica-511	164	1	references	reference	NOUN
ecletica-511	164	2	[	[	X
ecletica-511	164	3	1	1	NUM
ecletica-511	164	4	]	]	X
ecletica-511	164	5	cheng	cheng	PROPN
ecletica-511	164	6	,	,	PUNCT
ecletica-511	164	7	k.	k.	PROPN
ecletica-511	164	8	l.	l.	PROPN
ecletica-511	164	9	;	;	PUNCT
ecletica-511	164	10	ueno	ueno	PROPN
ecletica-511	164	11	,	,	PUNCT
ecletica-511	164	12	k.	k.	PROPN
ecletica-511	164	13	;	;	PUNCT
ecletica-511	164	14	imamura	imamura	PROPN
ecletica-511	164	15	,	,	PUNCT
ecletica-511	164	16	t.	t.	PROPN
ecletica-511	164	17	r.	r.	PROPN
ecletica-511	164	18	handbook	handbook	PROPN
ecletica-511	164	19	of	of	ADP
ecletica-511	164	20	organic	organic	ADJ
ecletica-511	164	21	analytical	analytical	ADJ
ecletica-511	164	22	reagents	reagent	NOUN
ecletica-511	164	23	.	.	PUNCT
ecletica-511	165	1	flórida	flórida	NOUN
ecletica-511	165	2	:	:	PUNCT
ecletica-511	165	3	crc	crc	PROPN
ecletica-511	165	4	press	press	PROPN
ecletica-511	165	5	,	,	PUNCT
ecletica-511	165	6	1982	1982	NUM
ecletica-511	165	7	.	.	PUNCT
ecletica-511	166	1	p.	p.	NOUN
ecletica-511	166	2	195	195	NUM
ecletica-511	166	3	.	.	PUNCT
ecletica-511	167	1	[	[	X
ecletica-511	167	2	2	2	NUM
ecletica-511	167	3	]	]	PUNCT
ecletica-511	167	4	colson	colson	PROPN
ecletica-511	167	5	,	,	PUNCT
ecletica-511	167	6	s.	s.	PROPN
ecletica-511	167	7	d.	d.	PROPN
ecletica-511	167	8	;	;	PUNCT
ecletica-511	167	9	dunning	dun	VERB
ecletica-511	167	10	jr	jr	PROPN
ecletica-511	167	11	.	.	PROPN
ecletica-511	167	12	,	,	PUNCT
ecletica-511	167	13	t.	t.	PROPN
ecletica-511	167	14	h.	h.	PROPN
ecletica-511	168	1	the	the	DET
ecletica-511	168	2	structure	structure	NOUN
ecletica-511	168	3	of	of	ADP
ecletica-511	168	4	natures	nature	NOUN
ecletica-511	168	5	solvent	solvent	ADJ
ecletica-511	168	6	:	:	PUNCT
ecletica-511	168	7	water	water	NOUN
ecletica-511	168	8	.	.	PUNCT
ecletica-511	169	1	science	science	NOUN
ecletica-511	169	2	,	,	PUNCT
ecletica-511	169	3	v.	v.	ADP
ecletica-511	169	4	265	265	NUM
ecletica-511	169	5	,	,	PUNCT
ecletica-511	169	6	n.	n.	NOUN
ecletica-511	169	7	5168	5168	NUM
ecletica-511	169	8	,	,	PUNCT
ecletica-511	169	9	p.	p.	NOUN
ecletica-511	169	10	43	43	NUM
ecletica-511	169	11	-	-	SYM
ecletica-511	169	12	44	44	NUM
ecletica-511	169	13	,	,	PUNCT
ecletica-511	169	14	1994	1994	NUM
ecletica-511	169	15	.	.	PUNCT
ecletica-511	170	1	[	[	X
ecletica-511	170	2	3	3	NUM
ecletica-511	170	3	]	]	X
ecletica-511	170	4	eigen	eigen	X
ecletica-511	170	5	,	,	PUNCT
ecletica-511	170	6	m.	m.	NOUN
ecletica-511	170	7	fast	fast	PROPN
ecletica-511	170	8	elementary	elementary	ADJ
ecletica-511	170	9	steps	step	NOUN
ecletica-511	170	10	in	in	ADP
ecletica-511	170	11	chemical	chemical	ADJ
ecletica-511	170	12	analysis	analysis	NOUN
ecletica-511	170	13	.	.	PUNCT
ecletica-511	171	1	pure	pure	ADJ
ecletica-511	171	2	appl	appl	PROPN
ecletica-511	171	3	.	.	PUNCT
ecletica-511	172	1	chem	chem	PROPN
ecletica-511	172	2	.	.	PUNCT
ecletica-511	172	3	,	,	PUNCT
ecletica-511	173	1	v.	v.	ADP
ecletica-511	173	2	6	6	NUM
ecletica-511	173	3	,	,	PUNCT
ecletica-511	173	4	n.	n.	NOUN
ecletica-511	173	5	2	2	NUM
ecletica-511	173	6	,	,	PUNCT
ecletica-511	173	7	p.	p.	NOUN
ecletica-511	173	8	97	97	NUM
ecletica-511	173	9	-	-	SYM
ecletica-511	173	10	115	115	NUM
ecletica-511	173	11	,	,	PUNCT
ecletica-511	173	12	1963	1963	NUM
ecletica-511	173	13	.	.	PUNCT
ecletica-511	174	1	[	[	X
ecletica-511	174	2	4	4	NUM
ecletica-511	174	3	]	]	X
ecletica-511	174	4	gourbatsis	gourbatsis	NOUN
ecletica-511	174	5	,	,	PUNCT
ecletica-511	174	6	s.	s.	PROPN
ecletica-511	174	7	;	;	PUNCT
ecletica-511	174	8	hadjiliadis	hadjiliadis	PROPN
ecletica-511	174	9	,	,	PUNCT
ecletica-511	174	10	n.	n.	NOUN
ecletica-511	174	11	;	;	PUNCT
ecletica-511	174	12	perlepes	perlepe	NOUN
ecletica-511	174	13	,	,	PUNCT
ecletica-511	174	14	s.	s.	PROPN
ecletica-511	174	15	p.	p.	PROPN
ecletica-511	174	16	;	;	PUNCT
ecletica-511	174	17	garoufs	garoufs	NOUN
ecletica-511	174	18	,	,	PUNCT
ecletica-511	174	19	a.	a.	NOUN
ecletica-511	174	20	;	;	PUNCT
ecletica-511	174	21	butler	butler	PROPN
ecletica-511	174	22	,	,	PUNCT
ecletica-511	174	23	i.	i.	PROPN
ecletica-511	174	24	s.	s.	PROPN
ecletica-511	174	25	structural	structural	ADJ
ecletica-511	174	26	and	and	CCONJ
ecletica-511	174	27	spectroscopic	spectroscopic	ADJ
ecletica-511	174	28	characterization	characterization	NOUN
ecletica-511	174	29	of	of	ADP
ecletica-511	174	30	a	a	DET
ecletica-511	174	31	cationic	cationic	ADJ
ecletica-511	174	32	aquanitrato	aquanitrato	NOUN
ecletica-511	174	33	copper(ii	copper(ii	NOUN
ecletica-511	174	34	)	)	PUNCT
ecletica-511	174	35	complex	complex	NOUN
ecletica-511	174	36	with	with	ADP
ecletica-511	174	37	the	the	DET
ecletica-511	174	38	tetradentate	tetradentate	NOUN
ecletica-511	174	39	schiff	schiff	NOUN
ecletica-511	174	40	-	-	PUNCT
ecletica-511	174	41	base	base	NOUN
ecletica-511	174	42	ligand	ligand	NOUN
ecletica-511	174	43	n	n	CCONJ
ecletica-511	174	44	,	,	PUNCT
ecletica-511	174	45	n’bis[1-(2	n’bis[1-(2	PROPN
ecletica-511	174	46	-	-	PUNCT
ecletica-511	174	47	pyridyl)ethylidene]ethane-1,2	pyridyl)ethylidene]ethane-1,2	NOUN
ecletica-511	174	48	-	-	PUNCT
ecletica-511	174	49	diamine	diamine	NOUN
ecletica-511	174	50	.	.	PUNCT
ecletica-511	175	1	transition	transition	NOUN
ecletica-511	175	2	met	meet	VERB
ecletica-511	175	3	.	.	PUNCT
ecletica-511	176	1	chem	chem	NOUN
ecletica-511	176	2	.	.	PUNCT
ecletica-511	176	3	,	,	PUNCT
ecletica-511	177	1	v.	v.	ADP
ecletica-511	177	2	23	23	NUM
ecletica-511	177	3	,	,	PUNCT
ecletica-511	177	4	n.	n.	NOUN
ecletica-511	177	5	5	5	NUM
ecletica-511	177	6	,	,	PUNCT
ecletica-511	177	7	p.	p.	NOUN
ecletica-511	177	8	599	599	NUM
ecletica-511	177	9	-	-	SYM
ecletica-511	177	10	604	604	NUM
ecletica-511	177	11	,	,	PUNCT
ecletica-511	177	12	1998	1998	NUM
ecletica-511	177	13	.	.	PUNCT
ecletica-511	178	1	[	[	X
ecletica-511	178	2	5	5	NUM
ecletica-511	178	3	]	]	X
ecletica-511	178	4	hubbard	hubbard	PROPN
ecletica-511	178	5	,	,	PUNCT
ecletica-511	178	6	c.	c.	PROPN
ecletica-511	178	7	d.	d.	PROPN
ecletica-511	178	8	;	;	PUNCT
ecletica-511	178	9	pacheco	pacheco	PROPN
ecletica-511	178	10	,	,	PUNCT
ecletica-511	178	11	d.	d.	PROPN
ecletica-511	178	12	the	the	DET
ecletica-511	178	13	kinetics	kinetic	NOUN
ecletica-511	178	14	of	of	ADP
ecletica-511	178	15	the	the	DET
ecletica-511	178	16	reactions	reaction	NOUN
ecletica-511	178	17	of	of	ADP
ecletica-511	178	18	1-(2	1-(2	PROPN
ecletica-511	178	19	-	-	PUNCT
ecletica-511	178	20	pyridylazo)-2	pyridylazo)-2	NOUN
ecletica-511	178	21	-	-	PUNCT
ecletica-511	178	22	naphtol	naphtol	NOUN
ecletica-511	178	23	with	with	ADP
ecletica-511	178	24	the	the	DET
ecletica-511	178	25	ions	ion	NOUN
ecletica-511	178	26	of	of	ADP
ecletica-511	178	27	nickel(ii	nickel(ii	NOUN
ecletica-511	178	28	)	)	PUNCT
ecletica-511	178	29	,	,	PUNCT
ecletica-511	178	30	copper(ii	copper(ii	PROPN
ecletica-511	178	31	)	)	PUNCT
ecletica-511	178	32	and	and	CCONJ
ecletica-511	178	33	zinc(ii	zinc(ii	PROPN
ecletica-511	178	34	)	)	PUNCT
ecletica-511	178	35	.	.	PUNCT
ecletica-511	179	1	j.	j.	PROPN
ecletica-511	179	2	inorg	inorg	PROPN
ecletica-511	179	3	.	.	PUNCT
ecletica-511	180	1	nucl	nucl	PROPN
ecletica-511	180	2	.	.	PUNCT
ecletica-511	181	1	chem	chem	PROPN
ecletica-511	181	2	.	.	PUNCT
ecletica-511	181	3	,	,	PUNCT
ecletica-511	182	1	v.	v.	ADP
ecletica-511	182	2	39	39	NUM
ecletica-511	182	3	,	,	PUNCT
ecletica-511	182	4	n.	n.	NOUN
ecletica-511	182	5	1373	1373	NUM
ecletica-511	182	6	-	-	SYM
ecletica-511	182	7	1375	1375	NUM
ecletica-511	182	8	,	,	PUNCT
ecletica-511	182	9	1977	1977	NUM
ecletica-511	182	10	.	.	PUNCT
ecletica-511	183	1	[	[	X
ecletica-511	183	2	6	6	NUM
ecletica-511	183	3	]	]	X
ecletica-511	183	4	james	james	PROPN
ecletica-511	183	5	,	,	PUNCT
ecletica-511	183	6	d.	d.	PROPN
ecletica-511	183	7	w.	w.	PROPN
ecletica-511	183	8	spectroscopic	spectroscopic	PROPN
ecletica-511	183	9	studies	study	NOUN
ecletica-511	183	10	of	of	ADP
ecletica-511	183	11	ion	ion	NOUN
ecletica-511	183	12	-	-	PUNCT
ecletica-511	183	13	ion	ion	NOUN
ecletica-511	183	14	-	-	PUNCT
ecletica-511	183	15	solvent	solvent	NOUN
ecletica-511	183	16	interaction	interaction	NOUN
ecletica-511	183	17	in	in	ADP
ecletica-511	183	18	solutions	solution	NOUN
ecletica-511	183	19	containing	contain	VERB
ecletica-511	183	20	oxyanions	oxyanion	NOUN
ecletica-511	183	21	.	.	PUNCT
ecletica-511	184	1	in	in	ADP
ecletica-511	184	2	:	:	PUNCT
ecletica-511	184	3	lippard	lippard	ADV
ecletica-511	184	4	,	,	PUNCT
ecletica-511	184	5	s.	s.	PROPN
ecletica-511	184	6	j.	j.	PROPN
ecletica-511	184	7	(	(	PUNCT
ecletica-511	184	8	ed	ed	NOUN
ecletica-511	184	9	.	.	PUNCT
ecletica-511	184	10	)	)	PUNCT
ecletica-511	184	11	.	.	PUNCT
ecletica-511	185	1	progress	progress	NOUN
ecletica-511	185	2	in	in	ADP
ecletica-511	185	3	inorganic	inorganic	ADJ
ecletica-511	185	4	chemistry	chemistry	NOUN
ecletica-511	185	5	.	.	PUNCT
ecletica-511	186	1	new	new	PROPN
ecletica-511	186	2	york	york	PROPN
ecletica-511	186	3	:	:	PUNCT
ecletica-511	187	1	john	john	PROPN
ecletica-511	187	2	wiley	wiley	PROPN
ecletica-511	187	3	,	,	PUNCT
ecletica-511	187	4	1985	1985	NUM
ecletica-511	187	5	.	.	PUNCT
ecletica-511	188	1	v.	v.	ADP
ecletica-511	188	2	33	33	NUM
ecletica-511	189	1	,	,	PUNCT
ecletica-511	189	2	p.	p.	NOUN
ecletica-511	189	3	353	353	NUM
ecletica-511	189	4	-	-	SYM
ecletica-511	189	5	391	391	NUM
ecletica-511	189	6	.	.	PUNCT
ecletica-511	190	1	[	[	X
ecletica-511	190	2	7	7	NUM
ecletica-511	190	3	]	]	X
ecletica-511	190	4	rossi	rossi	ADJ
ecletica-511	190	5	,	,	PUNCT
ecletica-511	190	6	a.	a.	PROPN
ecletica-511	190	7	v.	v.	PROPN
ecletica-511	190	8	;	;	PUNCT
ecletica-511	190	9	davanzo	davanzo	NOUN
ecletica-511	190	10	,	,	PUNCT
ecletica-511	190	11	c.	c.	PROPN
ecletica-511	190	12	u.	u.	PROPN
ecletica-511	190	13	;	;	PUNCT
ecletica-511	190	14	tubino	tubino	NOUN
ecletica-511	190	15	,	,	PUNCT
ecletica-511	190	16	m.	m.	NOUN
ecletica-511	190	17	the	the	DET
ecletica-511	190	18	structure	structure	NOUN
ecletica-511	190	19	of	of	ADP
ecletica-511	190	20	liquid	liquid	ADJ
ecletica-511	190	21	water	water	NOUN
ecletica-511	190	22	in	in	ADP
ecletica-511	190	23	aqueous	aqueous	ADJ
ecletica-511	190	24	solutions	solution	NOUN
ecletica-511	190	25	:	:	PUNCT
ecletica-511	190	26	a	a	DET
ecletica-511	190	27	proposed	propose	VERB
ecletica-511	190	28	model	model	NOUN
ecletica-511	190	29	from	from	ADP
ecletica-511	190	30	near	near	ADP
ecletica-511	190	31	and	and	CCONJ
ecletica-511	190	32	mid	mid	ADJ
ecletica-511	190	33	infrared	infrared	ADJ
ecletica-511	190	34	spectroscopy	spectroscopy	NOUN
ecletica-511	190	35	.	.	PUNCT
ecletica-511	191	1	j.	j.	PROPN
ecletica-511	191	2	braz	braz	PROPN
ecletica-511	191	3	.	.	PUNCT
ecletica-511	191	4	chem	chem	PROPN
ecletica-511	191	5	.	.	PUNCT
ecletica-511	192	1	soc	soc	PROPN
ecletica-511	192	2	.	.	PUNCT
ecletica-511	192	3	,	,	PUNCT
ecletica-511	192	4	v.	v.	ADV
ecletica-511	192	5	7	7	NUM
ecletica-511	192	6	,	,	PUNCT
ecletica-511	192	7	n.	n.	NOUN
ecletica-511	192	8	6	6	NUM
ecletica-511	192	9	,	,	PUNCT
ecletica-511	192	10	p.	p.	NOUN
ecletica-511	192	11	403	403	NUM
ecletica-511	192	12	-	-	SYM
ecletica-511	192	13	410	410	NUM
ecletica-511	192	14	,	,	PUNCT
ecletica-511	192	15	1996	1996	NUM
ecletica-511	192	16	.	.	PUNCT
ecletica-511	193	1	[	[	X
ecletica-511	193	2	8	8	NUM
ecletica-511	193	3	]	]	X
ecletica-511	193	4	rossi	rossi	ADJ
ecletica-511	193	5	,	,	PUNCT
ecletica-511	193	6	a.	a.	PROPN
ecletica-511	193	7	v.	v.	PROPN
ecletica-511	193	8	;	;	PUNCT
ecletica-511	193	9	rohwedder	rohwedder	NOUN
ecletica-511	193	10	,	,	PUNCT
ecletica-511	193	11	j.	j.	PROPN
ecletica-511	193	12	j	j	PROPN
ecletica-511	193	13	.r	.r	PROPN
ecletica-511	193	14	.	.	PUNCT
ecletica-511	194	1	;	;	PUNCT
ecletica-511	194	2	tubino	tubino	NOUN
ecletica-511	194	3	,	,	PUNCT
ecletica-511	194	4	m.	m.	NOUN
ecletica-511	194	5	a	a	DET
ecletica-511	194	6	low	low	ADJ
ecletica-511	194	7	cost	cost	NOUN
ecletica-511	194	8	stopped	stop	VERB
ecletica-511	194	9	flow	flow	NOUN
ecletica-511	194	10	system	system	NOUN
ecletica-511	194	11	.	.	PUNCT
ecletica-511	195	1	lab	lab	NOUN
ecletica-511	195	2	.	.	PUNCT
ecletica-511	195	3	microcomputer	microcomputer	NOUN
ecletica-511	195	4	,	,	PUNCT
ecletica-511	195	5	v.	v.	ADP
ecletica-511	195	6	13	13	NUM
ecletica-511	195	7	,	,	PUNCT
ecletica-511	195	8	n.	n.	NOUN
ecletica-511	195	9	2	2	NUM
ecletica-511	195	10	-	-	SYM
ecletica-511	195	11	4	4	NUM
ecletica-511	195	12	,	,	PUNCT
ecletica-511	195	13	p.	p.	NOUN
ecletica-511	195	14	67	67	NUM
ecletica-511	195	15	-	-	SYM
ecletica-511	195	16	69	69	NUM
ecletica-511	195	17	,	,	PUNCT
ecletica-511	195	18	1994	1994	NUM
ecletica-511	195	19	.	.	PUNCT
ecletica-511	196	1	ecl	ecl	PROPN
ecletica-511	196	2	.	.	PROPN
ecletica-511	196	3	quím	quím	PROPN
ecletica-511	196	4	.	.	PUNCT
ecletica-511	196	5	,	,	PUNCT
ecletica-511	196	6	são	são	PROPN
ecletica-511	196	7	paulo	paulo	PROPN
ecletica-511	196	8	,	,	PUNCT
ecletica-511	196	9	28(1	28(1	NOUN
ecletica-511	196	10	):	):	PUNCT
ecletica-511	196	11	55	55	NUM
ecletica-511	196	12	-	-	SYM
ecletica-511	196	13	62	62	NUM
ecletica-511	196	14	,	,	PUNCT
ecletica-511	196	15	2003	2003	NUM
ecletica-511	196	16	62	62	NUM
ecletica-511	197	1	[	[	X
ecletica-511	197	2	9	9	NUM
ecletica-511	197	3	]	]	SYM
ecletica-511	197	4	rossi	rossi	ADJ
ecletica-511	197	5	,	,	PUNCT
ecletica-511	197	6	a.	a.	NOUN
ecletica-511	197	7	v.	v.	PROPN
ecletica-511	197	8	;	;	PUNCT
ecletica-511	197	9	tubino	tubino	NOUN
ecletica-511	197	10	,	,	PUNCT
ecletica-511	197	11	m.	m.	NOUN
ecletica-511	197	12	kinetics	kinetic	NOUN
ecletica-511	197	13	and	and	CCONJ
ecletica-511	197	14	mechanism	mechanism	NOUN
ecletica-511	197	15	of	of	ADP
ecletica-511	197	16	the	the	DET
ecletica-511	197	17	reaction	reaction	NOUN
ecletica-511	197	18	of	of	ADP
ecletica-511	197	19	zincon	zincon	NOUN
ecletica-511	197	20	,	,	PUNCT
ecletica-511	197	21	o-[1-(2	o-[1-(2	X
ecletica-511	197	22	-	-	PUNCT
ecletica-511	197	23	hydroxy-5	hydroxy-5	NUM
ecletica-511	197	24	-	-	PUNCT
ecletica-511	197	25	sulfophenyl)3	sulfophenyl)3	NOUN
ecletica-511	197	26	-	-	PUNCT
ecletica-511	197	27	phenyl-5	phenyl-5	NOUN
ecletica-511	197	28	-	-	PUNCT
ecletica-511	197	29	formazane	formazane	NOUN
ecletica-511	197	30	]	]	PUNCT
ecletica-511	197	31	benzoic	benzoic	ADJ
ecletica-511	197	32	acid	acid	NOUN
ecletica-511	197	33	,	,	PUNCT
ecletica-511	197	34	with	with	ADP
ecletica-511	197	35	zn2	zn2	PROPN
ecletica-511	197	36	+	+	PROPN
ecletica-511	197	37	,	,	PUNCT
ecletica-511	197	38	cu2	cu2	NOUN
ecletica-511	197	39	+	+	NOUN
ecletica-511	197	40	and	and	CCONJ
ecletica-511	198	1	[	[	X
ecletica-511	198	2	zn2	zn2	X
ecletica-511	198	3	+	+	X
ecletica-511	198	4	+	+	NUM
ecletica-511	198	5	cu2	cu2	ADJ
ecletica-511	198	6	+	+	NOUN
ecletica-511	198	7	]	]	X
ecletica-511	198	8	equimolar	equimolar	ADJ
ecletica-511	198	9	mixtures	mixture	NOUN
ecletica-511	198	10	.	.	PUNCT
ecletica-511	199	1	j.	j.	PROPN
ecletica-511	199	2	braz	braz	PROPN
ecletica-511	199	3	.	.	PUNCT
ecletica-511	199	4	chem	chem	PROPN
ecletica-511	199	5	.	.	PUNCT
ecletica-511	200	1	soc	soc	PROPN
ecletica-511	200	2	.	.	PUNCT
ecletica-511	200	3	,	,	PUNCT
ecletica-511	200	4	v.	v.	ADV
ecletica-511	200	5	7	7	NUM
ecletica-511	200	6	,	,	PUNCT
ecletica-511	200	7	n.	n.	NOUN
ecletica-511	200	8	3	3	NUM
ecletica-511	200	9	,	,	PUNCT
ecletica-511	200	10	p.	p.	NOUN
ecletica-511	200	11	161	161	NUM
ecletica-511	200	12	-	-	SYM
ecletica-511	200	13	168	168	NUM
ecletica-511	200	14	,	,	PUNCT
ecletica-511	200	15	1996	1996	NUM
ecletica-511	200	16	.	.	PUNCT
ecletica-511	201	1	[	[	X
ecletica-511	201	2	10	10	NUM
ecletica-511	201	3	]	]	X
ecletica-511	201	4	shibata	shibata	PROPN
ecletica-511	201	5	,	,	PUNCT
ecletica-511	201	6	s.	s.	PROPN
ecletica-511	201	7	chelates	chelate	VERB
ecletica-511	201	8	in	in	ADP
ecletica-511	201	9	analytical	analytical	ADJ
ecletica-511	201	10	chemistry	chemistry	NOUN
ecletica-511	201	11	.	.	PUNCT
ecletica-511	202	1	new	new	PROPN
ecletica-511	202	2	york	york	PROPN
ecletica-511	202	3	:	:	PUNCT
ecletica-511	202	4	marcel	marcel	PROPN
ecletica-511	202	5	dekker	dekker	PROPN
ecletica-511	202	6	,	,	PUNCT
ecletica-511	202	7	1972	1972	NUM
ecletica-511	202	8	.	.	PUNCT
ecletica-511	203	1	v.	v.	ADP
ecletica-511	203	2	4	4	NUM
ecletica-511	203	3	,	,	PUNCT
ecletica-511	203	4	p.	p.	NOUN
ecletica-511	203	5	207	207	NUM
ecletica-511	203	6	.	.	PUNCT
ecletica-511	204	1	[	[	X
ecletica-511	204	2	11	11	NUM
ecletica-511	204	3	]	]	SYM
ecletica-511	204	4	tubino	tubino	NOUN
ecletica-511	204	5	,	,	PUNCT
ecletica-511	204	6	m.	m.	NOUN
ecletica-511	204	7	um	um	INTJ
ecletica-511	204	8	stopped	stop	VERB
ecletica-511	204	9	flow	flow	NOUN
ecletica-511	204	10	de	de	X
ecletica-511	204	11	fácil	fácil	X
ecletica-511	204	12	construção	construção	PROPN
ecletica-511	204	13	.	.	PUNCT
ecletica-511	205	1	quim	quim	PROPN
ecletica-511	205	2	.	.	PUNCT
ecletica-511	206	1	nova	nova	PROPN
ecletica-511	206	2	,	,	PUNCT
ecletica-511	206	3	v.	v.	ADP
ecletica-511	206	4	8	8	NUM
ecletica-511	206	5	,	,	PUNCT
ecletica-511	206	6	n.	n.	NOUN
ecletica-511	206	7	4	4	NUM
ecletica-511	206	8	,	,	PUNCT
ecletica-511	206	9	p.	p.	NOUN
ecletica-511	206	10	324	324	NUM
ecletica-511	206	11	-	-	SYM
ecletica-511	206	12	328	328	NUM
ecletica-511	206	13	,	,	PUNCT
ecletica-511	206	14	1985	1985	NUM
ecletica-511	206	15	.	.	PUNCT
ecletica-511	207	1	[	[	X
ecletica-511	207	2	12	12	NUM
ecletica-511	207	3	]	]	PUNCT
ecletica-511	207	4	tubino	tubino	NOUN
ecletica-511	207	5	,	,	PUNCT
ecletica-511	207	6	m.	m.	NOUN
ecletica-511	207	7	;	;	PUNCT
ecletica-511	207	8	rossi	rossi	ADJ
ecletica-511	207	9	,	,	PUNCT
ecletica-511	207	10	a.	a.	PROPN
ecletica-511	207	11	v.	v.	ADP
ecletica-511	207	12	construção	construção	PROPN
ecletica-511	207	13	de	de	PROPN
ecletica-511	207	14	um	um	INTJ
ecletica-511	207	15	aparelho	aparelho	PROPN
ecletica-511	207	16	de	de	PROPN
ecletica-511	207	17	fluxo	fluxo	X
ecletica-511	207	18	interrompido	interrompido	NOUN
ecletica-511	207	19	.	.	PUNCT
ecletica-511	208	1	quim	quim	PROPN
ecletica-511	208	2	.	.	PUNCT
ecletica-511	209	1	nova	nova	PROPN
ecletica-511	209	2	,	,	PUNCT
ecletica-511	209	3	v.	v.	ADV
ecletica-511	209	4	14	14	NUM
ecletica-511	209	5	,	,	PUNCT
ecletica-511	209	6	n.	n.	NOUN
ecletica-511	209	7	2	2	NUM
ecletica-511	209	8	,	,	PUNCT
ecletica-511	209	9	p.	p.	NOUN
ecletica-511	209	10	109111	109111	NUM
ecletica-511	209	11	,	,	PUNCT
ecletica-511	209	12	1991	1991	NUM
ecletica-511	209	13	.	.	PUNCT
ecletica-511	210	1	[	[	X
ecletica-511	210	2	13	13	NUM
ecletica-511	210	3	]	]	PUNCT
ecletica-511	210	4	vogel	vogel	NOUN
ecletica-511	210	5	,	,	PUNCT
ecletica-511	210	6	a.	a.	PROPN
ecletica-511	210	7	i.	i.	PROPN
ecletica-511	210	8	a	a	DET
ecletica-511	210	9	textbook	textbook	NOUN
ecletica-511	210	10	of	of	ADP
ecletica-511	210	11	quantitative	quantitative	ADJ
ecletica-511	210	12	inorganic	inorganic	ADJ
ecletica-511	210	13	analysis	analysis	NOUN
ecletica-511	210	14	including	include	VERB
ecletica-511	210	15	elementary	elementary	ADJ
ecletica-511	210	16	instrumental	instrumental	ADJ
ecletica-511	210	17	analysis	analysis	NOUN
ecletica-511	210	18	.	.	PUNCT
ecletica-511	211	1	london	london	PROPN
ecletica-511	211	2	:	:	PUNCT
ecletica-511	211	3	lowe	lowe	PROPN
ecletica-511	211	4	&	&	CCONJ
ecletica-511	211	5	brydone	brydone	PROPN
ecletica-511	211	6	,	,	PUNCT
ecletica-511	211	7	1961	1961	NUM
ecletica-511	211	8	.	.	PUNCT
ecletica-511	212	1	p.	p.	NOUN
ecletica-511	212	2	358	358	NUM
ecletica-511	212	3	.	.	PUNCT
ecletica-511	213	1	[	[	X
ecletica-511	213	2	14	14	NUM
ecletica-511	213	3	]	]	SYM
ecletica-511	213	4	welcher	welcher	NOUN
ecletica-511	213	5	,	,	PUNCT
ecletica-511	213	6	f.	f.	PROPN
ecletica-511	213	7	j.	j.	PROPN
ecletica-511	213	8	chemical	chemical	PROPN
ecletica-511	213	9	solutions	solutions	PROPN
ecletica-511	213	10	.	.	PUNCT
ecletica-511	214	1	new	new	PROPN
ecletica-511	214	2	york	york	PROPN
ecletica-511	214	3	:	:	PUNCT
ecletica-511	214	4	d.	d.	PROPN
ecletica-511	214	5	van	van	PROPN
ecletica-511	214	6	.	.	PROPN
ecletica-511	214	7	nostrand	nostrand	PROPN
ecletica-511	214	8	,	,	PUNCT
ecletica-511	214	9	1964	1964	NUM
ecletica-511	214	10	.	.	PUNCT
ecletica-511	215	1	p.	p.	NOUN
ecletica-511	215	2	185	185	NUM
ecletica-511	215	3	.	.	PUNCT
ecletica-511	216	1	ecl	ecl	PROPN
ecletica-511	216	2	.	.	PROPN
ecletica-511	216	3	quím	quím	PROPN
ecletica-511	216	4	.	.	PUNCT
ecletica-511	216	5	,	,	PUNCT
ecletica-511	216	6	são	são	PROPN
ecletica-511	216	7	paulo	paulo	PROPN
ecletica-511	216	8	,	,	PUNCT
ecletica-511	216	9	28(1	28(1	NOUN
ecletica-511	216	10	):	):	PUNCT
ecletica-511	216	11	55	55	NUM
ecletica-511	216	12	-	-	SYM
ecletica-511	216	13	62	62	NUM
ecletica-511	216	14	,	,	PUNCT
ecletica-511	216	15	2003	2003	NUM