49 © 2023 Adama Science & Technology University. All rights reserved Ethiopian Journal of Science and Sustainable Development e-ISSN 2663-3205 Volume 10 (1), 2023 Journal Home Page: www.ejssd.astu.edu.et ASTU Research Paper Assessment of Soil Acidity and Determination of Lime Requirement under Different Land Uses in Gumer District, Southern Ethiopia Aliyu Nesru1, Achalu Chimdi2, Wondwosen Tena3 1Department of Natural Resources Management, Wolkite University, Wolkite, Ethiopia 2Department of Natural Resource Management, Ambo University, Ambo, Ethiopia 3Department of Plant Biology and Biodiversity Management, Addis Ababa University, Addis Ababa, Ethiopia Article Info Abstract Article History: Received 02 June 2022 Received in revised form 18 November 2022 Accepted 28 December 2022 The study was initiated to assess the level of soil acidity and lime requirement of four types of land uses (forest lands, grazing lands, cultivated lands, and Eucalyptus tree plantation) and in replications from 0-20 cm soil depth. Lime requirement was evaluated by exchangeable acidity and buffer solution methods. The data were analyzed by SAS software, version 9.1. The study revealed that soils of cultivated and Eucalyptus lands were very strongly acidic with mean of pH 4.8 and 5.0, whereas soils of grazing lands were strongly acidic with pH 5.5 and forest lands were moderately acidic with pH 5.7and 5.6 in both kebeles, respectively. Meaningfully higher pH, OM, TN, CEC, exchangeable Ca2+, and Mg2+ were noted under forest lands as compared to the remaining land uses. However, meaningfully lower exchangeable acidity (EA) (1.06) and percentage acid saturation (PAS) (5.18) were obtained in the forest lands than in the other land uses. Significantly higher available P (2.54) was noted in the grazing land, followed by natural forest (1.77) land for Berchernamocheya kebele, and higher available P was recorded under forest (2.50), followed by grazing land (2.37) for Badnayegor kebele. Significantly higher exchangeable K+ (1.29) and Na+ (0.63) were observed in grazing land for Badnayegor and Berchernamocheya Kebeles, respectively. The results of the lime requirement revealed that using the SMP buffer solution method recorded 4.1-11.3 t/ha while using the exchangeable acidity method recorded 1.3-6.7 t/ha across the land uses for both kebeles. Based on lime requirement determination methods, the amount of lime required highly varies among the land uses. The investigation showed that soil acidification is a serious problem in the study areas. Thus, integrated land management needs to be practiced to overcome the problem of soil acidification and achieve sustainable agricultural production. Keywords: Land Uses, Lime Requirement, Soil Acidity, Soil Properties, 1. Introduction Different land uses have various influences on soil deprivation on physicochemical properties (Alelgn et al., 2021). Assessment of soil quality indicators related to updated soil nutrient management practices is a suitable and primary indicator for sustainable agricultural land management (Agbede, 2010; Wang et al., 2010). Such an assessment is used to understand Corresponding author, e-mail: achaluchimdi@yahoo.com https://doi.org/10.20372/ejssdastu:v10.i1.2023.512 nutrient availability in soils. This knowledge can determine whether definite land uses are suitable for a given crop production system or not (Wang et al., 2010). Soil acidification is one of the fundamental chemical soil degradation problems limiting crop production and productivity in various parts of Ethiopian highlands receiving high rainfall. The problem is also intensifying http://www.ejssd.astu.edu/ Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 50 in scope in most other Ethiopian highlands, severely limiting crop production. For instance, in most barley, wheat, and faba bean growing areas of central and southern Ethiopian highlands, agriculturalists have shifted to the production of acid-tolerant crops such as oats rather than acid-sensitive crops (Wassie & Boke, 2009; Chimdi et al., 2012). Challenges of soil acidification are mainly related to acid soil forming exchangeable aluminum (Al3+) and exchangeable Hydrogen (H+) and low availability of exchangeable basic cations. In acidic soil areas, exchangeable bases are easily removed through leaching and crop harvest (Lenka et al., 2007; Ermias et al., 2016). Most of the Ethiopian agricultural lands are affected by soil acidity and need appropriate amendment options including the application of liming material (Birhanu et al., 2014; Behera & Shukla, 2015; Bikila, 2019; Mesfin et al., 2020). Therefore, soil acidity is a serious concern calling for urgent consideration in most Ethiopian highlands because of its impact on crop yields and soil fertility (Chimdi et al., 2012; Chimdi, 2014; Kidanu & Chimdi, 2018). Even though soil acidity is recognized as an issue requiring urgent thoughtfulness in most Ethiopian highlands, there is very limited information about the impact of land uses on the level of acidity and the magnitude of lime required to neutralize soil acidity and other acidity-associated soil physicochemical properties in Gumer district. Hence, the current research was initiated with the specific objective of assessing the degree of soil acidification and the level of lime needed to reclaim acidification under three land uses. 2. Materials and Methods 2.1.Description of the study area The current investigation was undertaken in the Gumer District of Gurage Zone, Southern Nations- Nationalities, and People's Regional State. The district is located 220 kilometers south of Addis Ababa on the main road to Jimma, and 65 kilometers from Wolkite, the capital of Gurage Zone (Figure 1). It is found at 7º8′4″- 8o00′6″ latitude North and 37º8′9″- 38º2′00″ longitudes East. 2.1.1. Topography and climate. Topographically, the study district is composed of a flat plain (7%), and average slope (35%), and the extremely sloppy area covers 58% of the district. The altitude of the study site ranges from 2,600 to 3,170 masl and falls in the highland agro-climatic zone. According to Ethiopian Meteorological Agency, the average annual rainfall of the area is 1001- 1400 mm, with a bimodal rainfall pattern. The main rainy season ranges from June to September and the short rain period covers the months from February to April. The genuine rainy season ranges from June to the end of September. The mean maximum and minimum annual temperature of the study area varies between 17.5oC and 10.1oC, respectively (National meteorological agency, 2017). 2.1.2. Farming system and soil types Agriculture is the main source of revenue in the Gumer District. The district comprises a largely diversified farming system that includes field crop production (which includes Enset, Eucalyptus tree, barley, bean, pea, and wheat as the main economic activities and livestock rearing (cattle, goat and sheep) as the second most important economic activity in the district. The major vegetables grown in the area are potato, cabbage, garlic, onion, endive, beetroot, carrot, and many more. The data obtained from FAO (1991) shows the soil type in the district is mainly Cambisols and Plinthosols. 2.1.3. Site selection and soil sampling technique Purposive field surveillance and reconnaissance survey and selection techniques were undertaken before selecting the study site. Among the sixteen districts of Gurage Zone, Gumer District was purposively selected; this was because of susceptibility to land degradation and soil acidity in most of the highland areas of the district. The presence of representative land uses and topographical situation were the criteria used to identify the study site. Accordingly, cultivated land, eucalyptus plantation land, natural forest land, and grazing land were selected from Brchernamocheya and Badnayegor kebeles and considered for the study. A soil sample was collected from each land use with a random and uniform collection of representative soils. Replication of nearly 1 kg representative soil from the top surface (0-20 cm) of every land use was collected, dried, sieved, prepared, labeled, and transported for laboratory analysis. By doing so, 24 composite soil samples were collected from the selected land uses of the two Kebeles. Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 51 Figure 1: Location map of the study area Additionally, for the determination of soil bulk density, undisturbed 24 soil samples were taken from each land use in replication using a core sampler. Conversely, soil samples were grounded to pass a 0.5- mm size sieve for analysis of total N and OC. A randomized complete block design was conducted with three replications. 2.2. Soil Laboratory Analysis The analysis of soil samples was carried out at Wolkite Soil Laboratory Center using regular laboratory procedures and methods for the determination of lime requirement. 2.2.1. Evaluation of selected soil parameters Soil texture was measured through the Bouyoucos hydrometer method, which can be written (Day (1965). Soil bulk density was determined using the core sampler method. An average value of soil particle density of 2.65g cm-3 was considered for the calculation of total soil porosity. Total porosity was estimated from bulk and particle densities as described by Brady and Weil (2016). Soil pH was measured using a digital pH meter as a suspension of a 1:2.5 soil-water ratio (Van Reeuwijk, 2002). Cation exchange capacity (CEC) and exchangeable bases were extracted by 1M of NH4COCH3 at (pH 7) as described by Chapman (1965). The extracts of exchangeable Ca2+ and Mg2+ as well as Na+ and K+ were measured using atomic absorption spectrophotometer flame photometer, respectively (Chapman, 1965). The CEC was determined from the displaced NH4 + through distillation followed by titration. Exchangeable acid was determined by saturating the soil with 1N KCl solution and titrating it with NaOH as described by McLean (1965). A neutral 1N KCl solution was used to leach exchangeable H+ and Al3+ ions from the soil. After the determination of Organic carbon, using wet digestion, soil organic matter was calculated from organic carbon (OM=1.724 * %OC)as described by Walkley & Black (1934). Soil Total N was measured using the Kjeldahl digestion procedure as designated by Jackson (1958). The available P was determined by using the Olsen method (Olsen et al., 1954). Soil percent base saturation (PBS) was calculated by taking the ratio of the sum of basic exchangeable cations (Ca2+, Mg2+, Na+, and K+) ions to CEC as a percentage. Effective CEC, PBS, and PAS were calculated as follows: (1) 100* )(. CEC ionsNaKMgCabaseEx PBS Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 52 𝐸𝐶𝐸𝐶 = (𝐸𝑥. 𝑏𝑎𝑠𝑒𝑠(𝐶𝑎2+ + 𝑀𝑔2+ + 𝐾+ + 𝑁𝑎+) + 𝐸𝑥. 𝐴 (2) 100* . ECEC acidityEx PAS (3) 𝐸𝑥. 𝐴 = (EX. H+ + Ex. Al3+) (4) 2.2.2. Methods used for lime requirement (LR) determination The methods that were used for the lime requirement determination for this research were exchangeable acidity with the unbuffered neutral salt solution method and the SMP buffer solutions method. Shoemaker, McLean, and Pratt buffer for the lime requirement was employed using the buffer solutions method as developed by Shoemaker, McLean, and Pratt (SMP) buffer solution (Shoemaker et al., 1961). The SMP buffer method measures the change in pH of a buffer triggered by soil acidity and alteration in buffer pH is a quantity of lime requirement of soil. After determination of the prepared buffer pH, soil samples were determined by using SMP buffer solutions, at Wolkite Soil Testing Center, and the lime requirement was assessed by referring to a published table, linking buffer pH to aimed pH. 2.2.3. Extraction of exchange acidity method Exchange acid is the total exchangeable H+ and Al3+ adsorbed on a soil exchange complex. The exchangeable acidity above pH 5.5 is very low or even absent since exchangeable acidity is present appreciably only at pH < 5.5. The soil exchangeable acidity was determined as designated by Shoemaker et al. (1961). The mathematical model developed by Kamprath (1984) was used to calculate LR determination. 𝐿𝑅, 𝐶𝑎𝐶𝑂3 ( 𝑘𝑔 ℎ𝑎 ) = 𝑐𝑚𝑜𝑙𝐸𝐴 𝐾𝑔𝑠𝑜𝑖𝑙 ∗ 0.2𝑚 ∗ 1000𝑚2 ∗ 𝐵𝐷 ( 𝑚𝑔 𝑚3 ) ∗ 100 200 (5) Where: EA = Exchangeable acidity and BD = Bulk density 2.2.4. Data Analysis: Data generated from laboratory analysis were subjected to analysis of variance (ANOVA) using Statistical Analysis System (1999) version 9.1. 3. Results and Discussion 3.1.Soil Physical Properties The analytical result showed that all soil textures changed highly significantly (p < 0.01) in Badnayegor and Berchernamocheya kebeles except the silt portion in Badnayegor kebele, which significantly (p < 0.05) varied between land uses (Table 1). In all land uses of Berchernamocheya kebele, a sand portion was high (52.33- 32.33%) tailed by a silt portion (39.33 - 24.67%) and a clay portion (28.83- 16.67%). However, in Badnayegor kebele, sand, silt, and clay fractions ranged from 55.67 - 41.0%, 36.33 to 26.0%, and 30.0% - 15.33% respectively, in all land uses (Table 1). Relatively, the sand fraction was the largest proportion in all land uses of the two kebeles. The current finding is corroborated by the findings of Abbasi et al., (2007) and Tessema (2008). The authors state that the disparity of soil texture between land uses implies the effects of land uses on soil properties triggered by different utilization and management system of land uses (Abbasi et al., 2007; Tessema, 2008). In Berchernamocheya kebele, soil textural class of cultivation land (CL), EL, GL, and NF were loam, clay loam, sandy clay loam, and sandy loam, whereas in Badnayegor kebele, textural class of cultivation land (CL), EL, GL) and NF was sandy clay loam, clay loam, sandy loam and loam (Table 1). Changes in textural class among land uses resulted from amendment in management practices and pedogenic practices at the study area. 3.2.Soil bulk density and total porosity The analysis of variance depicted that land uses significantly (P < 0.01) affected bulk density (BD) in both kebeles. Numerically, the highest BD was found under the grazing lands (1.41 g/cm3 and 1.44 g/cm3) followed by cultivated lands (1.38 g/cm3 and 1.34 g/cm3). However, the lowest value of BD (1.21g/ cm3 and 1.17 g/cm3) was detected under NF followed by the soil under EL (1.28 g/cm3 and 1.18g/cm3) for Berchernamocheya and Badnayegor kebeles, respectively. Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 53 Table1. Mean values of selected soil physical properties Land uses Berchernamocheya kebele Badnayegor kebele Percentage (%) Percentage(%) Sand Clay Silt Tx. C Sand Clay Silt Tx. C CL 44.33a 21.0b 34.67ab L 46.33b 28.33a 25.33b SL EL 32.33b 28.33a 39.33a CL 41.0c 30.0a 29.0ab CL GL 47.0a 28.33a 24.67c SCL 55.67a 18.33b 26.0b SL NF 52.33a 16.67c 31.0cb SL 48.33b 15.33b 36.33a L LSD (0.05) 9.6 4.3 7.11 4.61 4.61 7.69 CV% 11.59 9.72 11.64 5.12 10.65 13.99 Land uses BD/gcm3 TP (%) BD/gcm3 TP (%) CL 1.38a 48.05b 1.34a 49.56b EL 1.28ab 51.69a 1.18b 55.59a GL 1.41a 46.78b 1.44a 45.53b NF 1.21b 54.47a 1.17b 55.97a LSD (0.05) 0.14 5.31 0.13 19.03 CV% 4.08 4.04 5.51 5.15 cmol(+) kg-1 cmol(+) kg-1 Land uses pH (H2O) EA Ex. Al Ex. H PAS pH (H2O) EA Ex. Al Ex. H PAS CL 4.80b 3.80ab 2.82a 0.98b 45.96a 5.0b 3.4ab 2.54b 0.86a 26.53a EL 4.87b 5.25a 3.29a 1.96a 34.19a 4.93b 4.91a 3.91a 0.99 a 37.45a GL 5.53a 2.04cb 1.06b 0.88b 9.69b 5.53a 2.27cb 1.29bc 0.97a 11.09b NF 5.67a 1.06c 0.30b 0.76b 5.18b 5.63a 1.29c 0.27c 1.03a 6.24b LSD (0.05) 0.27 1.96 1.58 0.73 12.73 0.27 1.52 1.35 0.77ns 12.41 CV% 2.71 24.2 24.78 26.0 18.46 2.68 27.23 25.79 22.51 13.79 Meq/100g soil Meq/100g soil Ca Mg Na K Ca Mg Na K CL 3.33b 0.69b 0.25b 0.23b 7.67cb 2.09b 0.09b 0.26c EL 6.0b 3.33b 0.19b 0.44b 4.33c 3.0b 0.10b 0.73b GL 10.0a 7.33a 0.63a 1.07a 9.0ab 7.67a 0.43a 1.29a NF 11.0 a 7.33a 0.36b 0.99a 12.33a 6.0a 0.32a 0.74a LSD (0.05) 3.92 3.01 0.26 0.52 3.77 2.54 0.17 0.32 CV% 27.45 14.27 19.45 20.71 24.00 17.75 18.29 17.71 N.B. The mean values in the table that are followed by the same letter are not significantly different from each other at P < 0.05, GL= grazing land, CL= cultivation land, EL= Eucalyptus land, NF= Natural forest, CV= Coefficient of variation, LSD= least significant difference, EA= exchangeable acidity, Ex. Al= exchangeable Al, Ex. H= exchangeable H, PAS=Percentage acid saturation. The possible reason why the BD was higher in GL and CL as compared to NF and EL could be attributed to the compaction effect of livestock during free grazing, deforestation, and consequent tillage practices that might have resulted in worsening soil structure, which in turn leads to soil compaction (Muche et al., 2015). The lowest soil OM available in the cultivation land can also subsidize the highest BD. In addition to this, the current finding is in line with Wakene and Heluf (2003), who stated that the highest BD detected in unrestricted land was caused by soil compaction and deprivation of OM. According to ratings by Hazelton and Murphy (2007), soil BD is rated as very low (<1 g/cm3), low (1-1.3 g/cm3), medium (1.3-1.6 g/cm3), high (1.6 -1.9 g/cm3) and very high (>1.9 g/cm3). Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 54 Table 2. Mean values of selected soil chemical properties. Land uses Berchernamocheya kebele Badnayegor kebele Meq/100g soil Meq/100g soil TEB ECEC CEC PBS TEB ECEC CEC PBS CL 4.51c 8.31c 24.28c 18.57c 10.12b 13.52b 28.07b 36.22a EL 9.96b 15.22b 30.03b 33.17b 8.17b 13.08b 32.67b 26.33a GL 19.03a 21.08a 30.13b 63.16a 18.39a 20.66a 42.07a 43.71a NF 19.65a 20.71a 35.0a 56.49a 19.39a 20.68a 43.27a 44.81a LSD (0.05) 2.87 2.67 3.67 10.39 4.09 4.17 7.90 23.08ns CV% 11.48 8.69 6.49 12.94 15.51 13.03 11.49 23.33 (mg kg-1) cmol(+) kg-1 (mgKg-1) cmol(+) kg-1 Land uses Av.P OC OM TN C: N Av. P OC OM TN C: N CL 1.09c 1.35c 2.33c 0.14b 9.59ab 1.36b 1.40d 2.42d 0.20b 7.19b EL 0.32d 2.17b 3.77b 0.24b 9.02ab 0.63b 2.47c 4.27c 0.21b 11.56a GL 2.54a 1.55c 2.69c 0.21b 6.29b 2.37a 3.37b 5.78b 0.46a 7.37b NF 1.77b 5.93a 10.2a 0.51a 11.71a 2.50a 5.47a 9.40 a 0.50a 10.9a LSD (0.05) 0.59 0.57 0.99 0.11 4.07 0.80 0.45 0.78 0.05 1.93 CV% 18.05 10.94 11.12 20.79 17.02 17.81 7.55 7.59 8.24 11.08 Land uses BpH LRSMP t/ha LREA t/ha BpH LRSMP t/ha LREA t/ha CL 5.63a 11.3a 5.1ab 5.73c 10.2a 4.55ab EL 5.80a 9.7a 6.7a 5.80cb 9.5ab 5.72a GL 6.17a 6.0a 2.8cb 6.10ab 6.6cb 3.29cb NF 6.33a 4.7a 1.3c 6.40a 4.1c 1.5c LSD (0.05) 0.74 7.1 2.58 0.33 3.02 1.9 CV% 4.73 24.15 17.41 2.92 21.1 N.B. Means within a column followed by the same letter are not significantly different from each other at P < 0.05, BpH = Buffer pH, LRSMP= Lime requirement determination method as Shoemaker, McLean, and Pratt, LREA= Lime requirement determination method by extraction of exchange acidity, Av. P= Available P, OC= Organic carbon, OM= Organic Matter, TN= total N, PBS= percentage base saturation, CEC= Cation exchange capacity, TEB= total exchangeable bases, ECEC= effective cation exchange capacity, ns = non-significant. Soil total porosity (TP) is a signal of the degree of compaction in the soil. Analysis of variance reveals significant (P < 0.01) differences in TP among land uses for Badnayegor and Berchernamocheya kebeles. The highest TP (54.47% and 55.97%) was detected in natural forest land followed by EL (51.69 and 55.59 %). In contrast, the lowest mean values (46.78% and 45.53%) of TP were registered under grazing lands followed by CL (48.05% and 49.56%) for Berchernamocheya and Badnayegor kebeles, respectively (Table 1). Alterations in TP among land uses might be due to high soil OM and lowest BD of natural forest lands and low OM content and high compaction due to the flattening effect of livestock during unrestricted foraging in grazing land. Factors that affect BD have also a direct effect on TP. The results of the current study are in agreement with Gebrelibanos and Mohammed (2013), who asserted that the high TP in the soil of natural forests is accredited to higher OM, as TP is affected by the level of soil OM and BD (Habtamu et al. 2014). According to the ranking of FAO (2006), soil TP (< 2%) was classified as very low,(5-10%) low, (10-15%) medium, (15-40%) high, and ( > 40%) very high. Based on this rating, the TP of Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 55 all land uses was found to be very high (> 40%). Higher TP implies better aggregation and provides good aeration for microorganisms and an opportunity for crop production. 3.3.Soil chemical parameters Soil pH was highly significantly (P < 0.01) affected by land uses. Comparison of the mean pH value of cultivation and eucalyptus lands with grazing and natural forest lands indicates statistically significant differences in Berchernamocheya and Badnayegor kebeles. However, there were no significant differences between EL and CL as well as between GL and NF lands of the two kebeles (Table 1). Relatively the highest (5.67) and the lowest (4.8) pH were documented in the natural forest and CL of Berchernamocheya kebele respectively. On the other hand, relatively the highest (5.63) and the lowest (4.93) pH were verified under the natural forest and EL of Badnayegor kebele respectively (Table 1). Low pH in CL and EL could be due to high tillage frequency and high rates of annual rainfall that resulted in different forms of soil erosion, removal of plant residues after harvesting of plants, and leaching of basic cations. The current findings are consistent with previous findings that indicate soil pH was significantly lower in the soil of CL when compared to uncultivated soils (Malo et al., 2005). Consistent with the current study, Gebeyaw (2015) also observed a significant alteration in pH value among land uses and showed lower pH in the soil of cultivation land. According to Jones (2003), soil pH rated for Berchernamocheya kebele, mean pH for CL, EL, GL, and NF were respectively, 4.80, 4.87, 5.53, and 5.67 and the rating ranged from very strong acid for CL to moderate acid for NF. Similarly, for soil pH rating for Badnayegor kebele, the mean pH value for CL, EL, GL, and NF was respectively 5.0, 4.93, 5.53, and 5.63, and rating ranges from very strongly acidic for CL to moderate acidic soil for NF (Table 1). 3.4.Exchangeable acidity (EA) and Percent Acid saturation (PAS) The analysis of variance revealed EA and PAS varied highly significantly (P < 0.01) through land uses in both kebeles. The mean EA values for CL, EL GL, and NF lands were (3.8, 5.25, 2.04, and 1.06 cmol(+) kg- 1), and (3.4, 4.91, 2.27, and 1.29 cmol (+) kg-1) for Berchernamocheya and Badnayegor kebeles, respectively (Table 1). The highest EA value was attained from EL (5.25 cmol (+) kg-1) and (4.91 cmol (+) kg-1) and the lowest EA value was acquired from NF lands (1.06 cmol (+) kg-1) and (1.29 cmol (+) kg-1) for Berchernamocheya & Badnayegor kebeles, respectively (Table 1). The mean PAS values for cultivated land, EL, GL, and NF land were (45.96, 34.19, 9.69, and 5.18 cmol (+) kg-1) and (26.53, 37.45, 11.09, and 6.24 cmol (+) kg-1) for Berchernamocheya and Badnayegor kebeles respectively (Table 1). The highest PAS value was achieved from cultivation land the PAS (45.96 cmol (+) kg-1) and the lowest (5.18 cmol (+) kg-1) value was achieved from NF land of Berchernamocheya kebele. Likewise, the highest PAS attained from EL (37.45 cmol (+) kg-1) and the lowest (6.24 cmol (+) kg-1) PAS value was achieved from NF land of Badnayegor kebele. 3.5.Exchangeable bases The analysis of variance depicted that mean values of exchangeable cations (Ca2+, Mg2+, Na+, and K+) were highly significantly (P < 0.01) different across land uses for Badnayegor kebele while Ca2+ and Mg2+ and Na+ and K+ were highly significantly (P < 0.01 and P < 0.05 respectively) diverse for Berchernamocheya kebele. The highest mean values of exchangeable bases Ca2+ and Mg2+ (11.0 and 7.33) were recorded in the soil of NF land and Na+ and K+ (0.63 and 1.07) were recorded in the soil of GL. The lowest mean values of exchangeable bases Ca2+, Mg2+, and K+ (3.33, 0.69, and 0.23) were recorded in the soil of CL, and Na+ (0.19) was recorded under eucalyptus land for Berchernamocheya kebele, respectively. Similarly, the highest mean values of exchangeable cations Ca2+ (12.33) in NF land and Mg2+, Na+, and K+ (7.67, 0.43, and 1.29) were registered under GL, whereas the lowest mean values of exchangeable cation Ca2+ (4.33) were registered under Eucalyptus land, and Mg2+, Na, and K+ (2.09, 0.09 and 0.26) were recorded under CL for Badnayegor kebele respectively (Table 1). The relatively high exchangeable (Ca2+ and Mg2+) observed in soils of NF land might be due to the presence of relatively higher soil OM and low exposure to soil erosion under NF lands. However, lower exchangeable Ca2+ and Mg2+ were observed in soils of CL and EL soils, which resulted from lower pH and soil OM as well as due to continuous removal of Ca2+ and Mg2+ with crop harvest from topsoil. The present Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 56 finding was in covenant with Aboytu (2019) who showed that soil acidification limits the availability of essential nutrients from the top soils. The impact of high soil acidification results in a deficiency of available Ca, P, and Mo and domination of soluble Al, Mn, and other acid-forming metallic ions (Getachew & Sommer, 2000). 3.6.Cation exchange capacity and percent base saturation The analysis of variance revealed that soil CEC was highly significantly (P < 0.01) affected by land uses at the two kebeles. Accordingly, the highest (35.0 cmol (+) kg-1) CEC value was observed in NF soil, followed by GL (30.13), while the lowest (24.28) in CL soil, followed by EL (30.03) for Berchernamocheya kebele. The highest (43.27) CEC value was observed in NF land soil, followed by GL (42.07), whereas the lowest (28.07) was recorded in CL, followed by EL (32.67) for Badnayegor kebele (Table 2). A possible reason for the highest and lowest CEC in NF land and CL respectively might be due to high soil OM in FL land but low level of OM and high leaching of basic cations from cultivation land. This finding was in agreement with the findings of Bore & Bedadi (2015), who stated that the decline in soil properties is mainly due to the transformation of native forest and range land into cultivated land. According to Hazelton and Murphy (2007), the CEC of soils in CL was medium (24.28) & high (28.07) for Berchernamocheya and Badnayegor kebeles respectively; CEC in EL soil was high for both kebeles. High CEC was revealed in grazing land (30.03) and NF land (35.0) for Berchernamocheya, and very high CEC was confirmed in grazing land (42.07) & NF land (43.27) for Badnayegor kebeles (Table 2). The value of PBS showed a highly significant (p<0.01) difference amongst land uses in Berchernamocheya kebele. However, it showed an insignificant (p > 0.05) difference among land uses in Badnayegor kebele. Likewise, numerical variations were observed among the four land uses. Relatively, the highest PBS (63.24%) was observed in grazing land, followed by NF land (56.49%), while the lowest PBS (18.57%) was recorded in CL, followed by EL (33.17%) in Berchernamocheya kebele. The reason for the high PBS content in grazing land in this kebele is probably due to the high total exchangeable bases (TEB) content noted in GL, while the low PBS documented in CL is probably due to the presence of a lower level of total exchangeable bases (TEB) observed in CL, low pH values and soil OM and removal of basic nutrients from topsoil by erosion and crop harvest for the Berchernamocheya kebele (Table 2). The findings of the current study agree with the findings of Jobira (2018) and Kedir (2015), who reported that the highest PBS (57.87%) was measured in GL soil, whereas the lowest (31.23%) was recorded in CL soil. 3.7.Soil organic matter, total N, C: N ratio and available P The analysis of variance showed that soil OM was very highly significantly (P < 0.001) affected by land uses in both kebeles. The highest (10.2 %) and (9.40%) SOM were documented in the soil of NF land, while relatively lowest (2.33 %) and (2.42%) SOM were recorded in the soil of CL for Berchernamocheya and Badnayegor kebeles, respectively. The mean value of SOM increased from CL to GL, EL, and NF lands and from CL to EL, GL, and NF land at Berchernamocheya and Badnayegor kebeles, respectively (Table 2). The highest soil OM recorded in the NF land is due to the fall of plant biomass like leaves, barks, limbs, and other remaining plants and low exposure to soil. Conversely, the lower SOM of CL is probably due to the removal of SOM through oxidation, which is resulted from the mismanagement of cultivated land triggered by intensive cultivation and soil erosion, which then leads to the washout of soil OM. According to Tekalign et al., (1991), (< 0.86) OM is rated as very low, (0.86-2.59 %) low, (2.59-5.17%) medium/moderate, and > (5.17%) high. Based on this rating, the OM for CL, GL Eucalyptus plantation land, and NF land in Berchernamocheya kebele were 2.33%, 2.69%, 3.77%, and 10.2% respectively. The mean values of SOM for Badnayegor kebele were 2.42%, 4.27%, 5.78%, and 9.40% in CL, EP, GL, and NF land respectively. The result indicated that SOM was low under CL of both kebeles, medium under Eucalyptus and GL, and high under NF lands of both kebeles (Table 2). The total N was very highly significantly (P < 0.001) affected by different land uses in both kebeles. The highest mean values (0.51% and 0.50%) of the TN were Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 57 documented in NF lands, while the lowest (0.14% and 0.20%) were noted in CL of Berchernamocheya and Badnayegor kebeles respectively (Table 2). This might be due to comparatively high SOM content noted in natural FL and low SOM content in CL as well as due to land use change from natural FL to CL, which may trigger the decline of TN content. This result is congruent with the findings of (Dawit et al., 2002). Based on the rating suggested by Barber (1984), the TN content recorded in CL was low for both kebeles, medium in grazing and EL lands in Berchernamocheya kebele and eucalyptus land in Badnayegor kebele, and very high in NF lands at both kebeles (Table 2). The result of the C: N ratio showed significant (P<0.05) and highly significant (P<0.01) variations amongst land uses in Berchernamocheya and Badnayegor kebeles, respectively (Table 2). The highest (11.71) C: N was noted in NF land, followed by CL (9.59), while the relatively lowest (6.29) C: N was documented in GL, followed by EL (9.02) in Berchernamochya kebele. Similarly, the highest (11.56) C: N was documented in EL, followed by NF land (10.9), while the lowest (7.19) C: N was observed in CL, followed by GL (7.37) in Badnayegor kebele (Table 2). Low input of SOC, removal of crop residues from CL, and overgrazing are probably the reasons for a low level of C: N in CL and GL, whereas higher C: N is probably due to higher contents of soil OC and high plant biomass in natural FL. Similarly, previous findings also stated that narrow C: N at the surface soils of CL is probably due to higher microbial activity in the surface 0-20 cm soil layer (Chimdi, 2014). Based on the ratings by Hazelton and Murphy (2007), we have found out that except for natural FL, which was low C: N, for all the remaining land, uses, the C: N was rated as very low at grazing and CL in Berchernamocheya kebele, low at the EP land and natural FL in Badnayegor kebele (Table 2). Available P was highly significantly (P<0.01) affected by land uses in both kebeles. Relatively, the soil under grazing land was documented with the highest available P (2.54 mg/kg), followed by NF land and CL (1.77 and 1.09mg/kg) respectively; the lowest (0.32mg/kg) was noted in EL in Berchernamocheya kebele. On the other hand, the highest available P was noted (2.50 mg/ kg) in NF land, followed by grazing and CL (2.37 and 1.36 mg/kg) respectively, and the lowest (0.63 mg/kg) was registered in EL in Badnayegor kebele. This result agrees with the finding of Tessema (2008), who reported that low available P in acid soils is due to the inherently high P fixing capacity of the soil. As rated by Barber (1984), the available P was qualifying very low in all land uses in both kebeles; however, it is numerically better in soils of NF land and GL of both kebeles (Table 2). 3.8.Lime requirement(LR) determination with the SMP buffer solution method The amount of lime required by using the buffer solution method of lime requirement determination (LR_SMP) of the experimental soil was highly significantly (P < 0.01) affected by land uses at Badnayegor kebele; however, it is insignificantly affected by land uses at Berchernamocheya kebele (Table 2). Accordingly, the highest (10.2 t/ha) value of LR was noted in CL soil, followed by EP land (9.5 t/ha), while the lowest (4.1 t/ha) was documented in NF land soil, followed by GL (6.6 t/ha) at Badnayegor kebele. A possible reason for the highest quantity of LR verified in CL and EL is probably due to lower OM content, low pH values, relative existence of substantial quantity of Al and H ions, and low level of basic nutrients. However, a lower quantity of LR was documented in NF and GL soil is probably due to relatively higher OM content, high pH (above 5.5), and high quantity of basic nutrients. The quantity of lime requirement determined by using buffer solution method of lime requirement determination SMP methods to change the current pH value of soils to targeted pH 6.5 was in line with the finding, CL and GL required 14.0 - 15.90 ton/ha of lime to change the soil from 5.13-6.5 by SMP buffer solution method (Birhanu, 2008). 3.9.Lime requirement determination with exchangeable acidity method The mean values of LR evaluated using the extraction of exchange acidity method were highly significantly (P < 0.01) affected by different land uses in both kebeles. The study revealed the highest (6.7 and 5.72) t/ha mean value of LR in EL soil, followed by CL (5.1 and 4.55) t/ha, and the lowest (1.3 and 1.5) t/ha in NF land, followed by GL (2.8 and 3.29) t/ha in Berchernamocheya and Badnayegor kebeles, respectively (Table 2). A possible reason for the difference in LR among land uses is probably due to high Aliyu Nesru et al Ethiop.J.Sci.Sustain.Dev., Vol. 10 (1), 2023 58 OM, high pH values, and lower amount of exchangeable acidic cation (Al+ and H+). Low acid saturation was recorded in NF land and GL in the study area requires a relatively low quantity of lime. However, soils under CL and EL require a high quantity of lime probably due to low OM content, lower pH values, a relatively higher quantity of acidic cation (Al+ and H+), and high acid saturation. This means that when the soils contain a substantial value of acidic cations, a higher quantity of lime is required to reclaim soil acidity (Desalegn et al., 2017). 3.10. Comparison of lime requirement determination methods Of the two lime requirement determination methods stated above, lime requirement determination by using the buffer solution method (LR_SMP) was exaggerated (4.1 t/ha to 11.3 t/ha) across the land uses. However, in lime requirement by using the extraction of exchangeable acidity method, the quantity of lime required ranged from 1.3 t/ha to 6.7 t/ha across land uses for the study area. The quantity of lime required by using the extraction of exchangeable acidity method was very low for NF lands (1.3 t, 1.5 t) and GL (2.8 t, 3.29 t) as compared to the amount of lime required by using the buffer solution method, where the quantity of lime required for NF lands (4.7 t, 4.1 t) and grazing lands (6.0 t, 6.6 t) was very high for Berchernamocheya and Badnayegor kebeles respectively. Similarly, the quantity of lime required by using the extraction of exchangeable acidity method was very low for CL (5.1 t, 4.55 t) and EL (6.7 t, 5.72 t) as compared to the quantity of lime required by using the buffer solution method for CL (11.3 t, 10.2 t) and EL (9.7 t, 9.5 t), which was very high for Berchernamocheya and Badnayegor kebeles respectively (Table 2). Although lime requirement can be determined both through SMP buffer and exchangeable acidity methods, a more suitable method should be identified by validating it under field conditions. 4. Conclusion The assessment of soil acidity in four land uses showed that very low soil pH (4.8 and 4.87), (5.0 and 4.93); and higher acid saturation (45.96% and 34.2%), (26.53 and 37.45) were recorded in CL and EL for Berchernamocheya and Badnayegor kebeles, respectively. The findings of the study also indicated overall variation and loss of soil fertility in CL and EL as compared to NF land and GL. Accordingly, CL and EL soils were also poor in macronutrient contents and fell below TEB (from 4.51 to 13.52), CEC (from 24.28 to 32.67), and PBS (from18.57% to 33.17%). However, relatively higher soil pH (>5.5) and lower acid saturation (from 5.1% to 11.09%) in NF land and GL soils indicated its suitability for better available nutrients. The TEB ranged from (19.03 to 19.65); CEC from (30.13 to 43.27) and PBS from (43.71% to 63.16%) were recorded in the soil of NF land and GL. Based on the evaluation of lime requirement under the four land uses, we have observed that the quantity of lime required varies greatly among land uses. This variation is probably due to low pH values in CL and EL soils, which require a higher quantity of lime than adjacent NF land and GL. Finally, this soil acidity and reduction of basic cations lead to the intensification of risks to agricultural productivity. Immediate and integrated land management interventions are required to overcome soil acidity, improve soil productivity, and achieve viable agricultural crop production. . Application of agricultural lime and organic fertilizers is considered a dominant measure for such acidified cultivated land. Finally, we recommended that further studies are needed on lime recommendation rates in the study area based on locational field experiments. Acknowledgments The authors would like to acknowledge Wolkite Town Administration for financial support and Wolkite Soil Testing Center for providing us with materials and supporting us in soil analysis. Reference Abbasi, M., Zafar, M., & Khan, S. (2007). Influence of different land-cover types on the changes of selected soil properties in the mountain region of Rawalakot Azad Jammu and Kashmir. Nutrient Cycling in Agroecosystems., 78:97-110. Aboytu, S. (2019). Soil acidity and its management options in Ethiopia. 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