id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
eurjchem-1307	Silverberg, Lee Jonathan; Kistler, Kurt Andrew; Brobst, Kyle; Yennawar, Hemant Prabhakar; Lagalante, Anthony; He, Gang; Ali, Khalid; Blatt, Ashbyilyin; Foster, Shalay; Grossman, Dennis; Hegel, Stefan; Minehan, Michael; Valinsky, Dana; Yeasted, James Gabriel	Reactions of the halonium ions of carenes and pinenes: An experimental and theoretical study	2015	14	.pdf	application/pdf	10360	482	63	The overall greater hardness in ions 7‐Br+ and 11‐Br+ compared to ion 1‐Br+ is probably explained by the lower ring strain of the cyclobutyl moiety compared to the cyclopropyl, and this also can explain the relatively less planar carbocation character of C8 in the pinene bromonium ions, compared to ion 1‐Br+. To the best of our knowledge, this method has not been used for analyzing such reactive intermediates, but the results showed that ion 1‐Br+ displays similar hardness, or the lack thereof, as those of bromonium ions of the conjugated cyclohexenes included in this theoretical study, which was expected, and ions 7‐Br+ and 11‐ Br+, while somewhat harder than ion 1‐Br+, also displayed hardness values much lower than bromonium ions of non‐ conjugated mono‐alkenes included in this report.	cache/eurjchem-1307.pdf	txt/eurjchem-1307.txt