id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
eurjchem-1566	Kevill, Dennis Neil; Ryu, Zoon Ha; D’Souza, Malcolm John	Correlation analysis of the rates of solvolysis of 4-bromopiperidine: A reaction following a Grob fragmentation pathway	2017	6	.pdf	application/pdf	4624	243	61	In the consideration of the influence of solvent on a methoxy group, it has been convincingly shown [35] that the electron‐withdrawing capacity of a non‐partici‐ pating methoxy in the solvolysis of a 2‐methoxy substituted 2‐ cyclohexenyl p‐nitrobenzoate is strongly influenced by the hydrogen‐bond donation from the solvent to the oxygen of the substituent, and the effect is much greater in solvents rich in TFE than in aqueous acetone or aqueous ethanol. These are exactly the effects to be expected from the presence of an appreciable degree of multicollinearity in the absence of fluoroalcohol‐containing solvents.	cache/eurjchem-1566.pdf	txt/eurjchem-1566.txt