id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
eurjchem-624	Kyong, Jin Burm; Lee, Yelin; D'Souza, Malcolm John; Mahon, Brian Patrick; Kevill, Dennis Neil	Correlation of the rates of solvolysis of tert-butyl chlorothioformate and observations concerning the reaction mechanism	2012	6	.pdf	application/pdf	5319	330	67	Discussions of the development of Y scales and values for a wide variety of YX scales have previously been presented [4,13]. (a) Unimolecular Solvolyses (b) Unimolecular Solvolysis‐Decomposition Scheme 2 268 D'Souza et al. / European Journal of Chemistry 3 (3) (2012) 267‐272 While there was some success in applying the original form of the equation to bimolecular solvolyses for a series of aqueous‐organic solvent compositions for a given organic component [3], it was realized that for an application involving a single LFER for solvolyses in a series of aqueous‐organic mixtures an extended approach would be required, and this led to the addition of a second term to give the original (extended) two‐term G‐W equation [Equation 2]. Values at three elevated temperatures in 100% and 80% ethanol and at three reduced temperatures in 97% and 90% 2,2,2‐trifluoroethanol (TFE) were also obtained.	cache/eurjchem-624.pdf	txt/eurjchem-624.txt