id sid tid token lemma pos eurjchem-101 1 1 microsoft microsoft PROPN eurjchem-101 1 2 word word NOUN eurjchem-101 1 3 european_journal_of_chemistry_1_4_2010_373_376_101 european_journal_of_chemistry_1_4_2010_373_376_101 PROPN eurjchem-101 1 4 european european ADJ eurjchem-101 1 5     SPACE eurjchem-101 1 6 journal journal NOUN eurjchem-101 1 7     SPACE eurjchem-101 1 8 of of ADP eurjchem-101 1 9     SPACE eurjchem-101 1 10 chemistry chemistry NOUN eurjchem-101 1 11     SPACE eurjchem-101 1 12 1 1 NUM eurjchem-101 1 13     SPACE eurjchem-101 1 14 ( ( PUNCT eurjchem-101 1 15 4 4 NUM eurjchem-101 1 16 ) ) PUNCT eurjchem-101 1 17     SPACE eurjchem-101 1 18 ( ( PUNCT eurjchem-101 1 19 2010 2010 NUM eurjchem-101 1 20 ) ) PUNCT eurjchem-101 1 21     SPACE eurjchem-101 1 22 373‐376 373‐376 PROPN eurjchem-101 1 23         SPACE eurjchem-101 1 24 european european ADJ eurjchem-101 1 25     SPACE eurjchem-101 1 26 journal journal NOUN eurjchem-101 1 27     SPACE eurjchem-101 1 28 of of ADP eurjchem-101 1 29     SPACE eurjchem-101 1 30 chemistry chemistry NOUN eurjchem-101 1 31     SPACE eurjchem-101 1 32 issn issn VERB eurjchem-101 1 33     SPACE eurjchem-101 1 34 2153‐2249 2153‐2249 NUM eurjchem-101 1 35     SPACE eurjchem-101 1 36 ( ( PUNCT eurjchem-101 1 37 print print NOUN eurjchem-101 1 38 ) ) PUNCT eurjchem-101 1 39     SPACE eurjchem-101 1 40 / / SYM eurjchem-101 1 41     SPACE eurjchem-101 1 42 issn issn VERB eurjchem-101 1 43     SPACE eurjchem-101 1 44 2153‐2257 2153‐2257 NUM eurjchem-101 1 45     SPACE eurjchem-101 1 46 ( ( PUNCT eurjchem-101 1 47 online online ADJ eurjchem-101 1 48 ) ) PUNCT eurjchem-101 1 49     SPACE eurjchem-101 1 50   NOUN eurjchem-101 1 51     SPACE eurjchem-101 1 52 2010 2010 NUM eurjchem-101 1 53     SPACE eurjchem-101 1 54 eurjchem eurjchem NOUN eurjchem-101 1 55     SPACE eurjchem-101 1 56 doi:10.5155 doi:10.5155 PROPN eurjchem-101 1 57 / / SYM eurjchem-101 1 58 eurjchem.1.4.373‐376.101 eurjchem.1.4.373‐376.101 PROPN eurjchem-101 1 59                 SPACE eurjchem-101 1 60 european european ADJ eurjchem-101 1 61     SPACE eurjchem-101 1 62 journal journal NOUN eurjchem-101 1 63     SPACE eurjchem-101 1 64 of of ADP eurjchem-101 1 65     SPACE eurjchem-101 1 66 chemistry chemistry NOUN eurjchem-101 1 67     SPACE eurjchem-101 1 68 journal journal NOUN eurjchem-101 1 69     SPACE eurjchem-101 1 70 homepage homepage NOUN eurjchem-101 1 71 : : PUNCT eurjchem-101 1 72     SPACE eurjchem-101 1 73 www.eurjchem.com www.eurjchem.com NOUN eurjchem-101 1 74                     SPACE eurjchem-101 1 75 stabilization stabilization NOUN eurjchem-101 1 76     SPACE eurjchem-101 1 77 of of ADP eurjchem-101 1 78     SPACE eurjchem-101 1 79 5‐aminolevulinic 5‐aminolevulinic NUM eurjchem-101 1 80     SPACE eurjchem-101 1 81 acid acid NOUN eurjchem-101 1 82     SPACE eurjchem-101 1 83 by by ADP eurjchem-101 1 84     SPACE eurjchem-101 1 85 the the DET eurjchem-101 1 86     SPACE eurjchem-101 1 87 zinc(ii zinc(ii NUM eurjchem-101 1 88 ) ) PUNCT eurjchem-101 1 89     SPACE eurjchem-101 1 90 ion ion NOUN eurjchem-101 1 91     SPACE eurjchem-101 1 92 in in ADP eurjchem-101 1 93     SPACE eurjchem-101 1 94 an an DET eurjchem-101 1 95     SPACE eurjchem-101 1 96 aqueous aqueous ADJ eurjchem-101 1 97     SPACE eurjchem-101 1 98 solution solution NOUN eurjchem-101 1 99     SPACE eurjchem-101 1 100 hiroshi hiroshi PROPN eurjchem-101 1 101     SPACE eurjchem-101 1 102 sakiyamaa sakiyamaa NOUN eurjchem-101 1 103 , , PUNCT eurjchem-101 1 104 * * NOUN eurjchem-101 1 105 , , PUNCT eurjchem-101 1 106     SPACE eurjchem-101 1 107 hidetatsu hidetatsu NOUN eurjchem-101 1 108     SPACE eurjchem-101 1 109 inouea inouea NOUN eurjchem-101 1 110 , , PUNCT eurjchem-101 1 111     SPACE eurjchem-101 1 112 md.kudrat‐e‐zahana md.kudrat‐e‐zahana PROPN eurjchem-101 1 113 , , PUNCT eurjchem-101 1 114     SPACE eurjchem-101 1 115 shoichi shoichi NOUN eurjchem-101 1 116     SPACE eurjchem-101 1 117 huekib huekib NOUN eurjchem-101 1 118 , , PUNCT eurjchem-101 1 119       SPACE eurjchem-101 1 120 naohisa naohisa NOUN eurjchem-101 1 121     SPACE eurjchem-101 1 122 tachiyab tachiyab ADJ eurjchem-101 1 123     SPACE eurjchem-101 1 124 and and CCONJ eurjchem-101 1 125     SPACE eurjchem-101 1 126 yuzo yuzo NOUN eurjchem-101 1 127     SPACE eurjchem-101 1 128 nishidaa nishidaa PROPN eurjchem-101 1 129     SPACE eurjchem-101 1 130 a a DET eurjchem-101 1 131     SPACE eurjchem-101 1 132 department department NOUN eurjchem-101 1 133     SPACE eurjchem-101 1 134 of of ADP eurjchem-101 1 135     SPACE eurjchem-101 1 136 material material NOUN eurjchem-101 1 137     SPACE eurjchem-101 1 138 and and CCONJ eurjchem-101 1 139     SPACE eurjchem-101 1 140 biological biological ADJ eurjchem-101 1 141     SPACE eurjchem-101 1 142 chemistry chemistry NOUN eurjchem-101 1 143 , , PUNCT eurjchem-101 1 144     SPACE eurjchem-101 1 145 faculty faculty NOUN eurjchem-101 1 146     SPACE eurjchem-101 1 147 of of ADP eurjchem-101 1 148     SPACE eurjchem-101 1 149 science science NOUN eurjchem-101 1 150 , , PUNCT eurjchem-101 1 151     SPACE eurjchem-101 1 152 yamagata yamagata PROPN eurjchem-101 1 153     SPACE eurjchem-101 1 154 university university NOUN eurjchem-101 1 155 , , PUNCT eurjchem-101 1 156     SPACE eurjchem-101 1 157 kojirakawa kojirakawa PROPN eurjchem-101 1 158 , , PUNCT eurjchem-101 1 159     SPACE eurjchem-101 1 160 yamagata yamagata PROPN eurjchem-101 1 161 , , PUNCT eurjchem-101 1 162     SPACE eurjchem-101 1 163 jp­990­8560 jp­990­8560 ADV eurjchem-101 1 164 , , PUNCT eurjchem-101 1 165     SPACE eurjchem-101 1 166 japan japan PROPN eurjchem-101 1 167     SPACE eurjchem-101 1 168 b b PROPN eurjchem-101 1 169     SPACE eurjchem-101 1 170 cosmo cosmo NOUN eurjchem-101 1 171     SPACE eurjchem-101 1 172 oil oil NOUN eurjchem-101 1 173     SPACE eurjchem-101 1 174 co. co. PROPN eurjchem-101 1 175 , , PUNCT eurjchem-101 1 176     SPACE eurjchem-101 1 177 ltd ltd PROPN eurjchem-101 1 178 . . PROPN eurjchem-101 1 179 , , PUNCT eurjchem-101 1 180     SPACE eurjchem-101 1 181 shibaura shibaura NOUN eurjchem-101 1 182 , , PUNCT eurjchem-101 1 183     SPACE eurjchem-101 1 184 minatoku minatoku NOUN eurjchem-101 1 185 , , PUNCT eurjchem-101 1 186     SPACE eurjchem-101 1 187 tokyo tokyo PROPN eurjchem-101 1 188 , , PUNCT eurjchem-101 1 189     SPACE eurjchem-101 1 190 jp­105­8528 jp­105­8528 PROPN eurjchem-101 1 191 , , PUNCT eurjchem-101 1 192     SPACE eurjchem-101 1 193 japan japan PROPN eurjchem-101 1 194     SPACE eurjchem-101 1 195 * * PROPN eurjchem-101 1 196 corresponding corresponding ADJ eurjchem-101 1 197     SPACE eurjchem-101 1 198 author author NOUN eurjchem-101 1 199     SPACE eurjchem-101 1 200 at at ADP eurjchem-101 1 201 : : PUNCT eurjchem-101 1 202     SPACE eurjchem-101 1 203 department department NOUN eurjchem-101 1 204     SPACE eurjchem-101 1 205 of of ADP eurjchem-101 1 206     SPACE eurjchem-101 1 207 material material NOUN eurjchem-101 1 208     SPACE eurjchem-101 1 209 and and CCONJ eurjchem-101 1 210     SPACE eurjchem-101 1 211 biological biological ADJ eurjchem-101 1 212     SPACE eurjchem-101 1 213 chemistry chemistry NOUN eurjchem-101 1 214 , , PUNCT eurjchem-101 1 215     SPACE eurjchem-101 1 216 faculty faculty NOUN eurjchem-101 1 217     SPACE eurjchem-101 1 218 of of ADP eurjchem-101 1 219     SPACE eurjchem-101 1 220 science science NOUN eurjchem-101 1 221 , , PUNCT eurjchem-101 1 222     SPACE eurjchem-101 1 223 yamagata yamagata PROPN eurjchem-101 1 224     SPACE eurjchem-101 1 225 university university NOUN eurjchem-101 1 226 , , PUNCT eurjchem-101 1 227     SPACE eurjchem-101 1 228 kojirakawa kojirakawa PROPN eurjchem-101 1 229 , , PUNCT eurjchem-101 1 230     SPACE eurjchem-101 1 231 yamagata yamagata PROPN eurjchem-101 1 232 , , PUNCT eurjchem-101 1 233     SPACE eurjchem-101 1 234 jp­990­8560 jp­990­8560 ADV eurjchem-101 1 235 , , PUNCT eurjchem-101 1 236     SPACE eurjchem-101 1 237 japan japan PROPN eurjchem-101 1 238 . . PUNCT eurjchem-101 1 239     SPACE eurjchem-101 2 1 tel tel PROPN eurjchem-101 2 2 . . PUNCT eurjchem-101 2 3 : : PUNCT eurjchem-101 2 4     SPACE eurjchem-101 2 5 +81.23.6284601 +81.23.6284601 NUM eurjchem-101 2 6 ; ; PUNCT eurjchem-101 2 7     SPACE eurjchem-101 2 8 fax fax NOUN eurjchem-101 2 9 : : PUNCT eurjchem-101 2 10     SPACE eurjchem-101 2 11 +81.23.6284591 +81.23.6284591 NUM eurjchem-101 2 12 . . PUNCT eurjchem-101 2 13     SPACE eurjchem-101 2 14 e­mail e­mail NOUN eurjchem-101 2 15     SPACE eurjchem-101 2 16 address address NOUN eurjchem-101 2 17 : : PUNCT eurjchem-101 2 18     SPACE eurjchem-101 2 19 saki@sci.kj.yamagata­u.ac.jp saki@sci.kj.yamagata­u.ac.jp NOUN eurjchem-101 2 20     SPACE eurjchem-101 2 21 ( ( PUNCT eurjchem-101 2 22 h. h. NOUN eurjchem-101 2 23     SPACE eurjchem-101 2 24 sakiyama sakiyama PROPN eurjchem-101 2 25 ) ) PUNCT eurjchem-101 2 26 . . PUNCT eurjchem-101 2 27                                 SPACE eurjchem-101 2 28 communication communication NOUN eurjchem-101 2 29     SPACE eurjchem-101 2 30 information information NOUN eurjchem-101 2 31         SPACE eurjchem-101 2 32 abstract abstract ADJ eurjchem-101 2 33 received receive VERB eurjchem-101 2 34 : : PUNCT eurjchem-101 2 35     SPACE eurjchem-101 2 36 06 06 NUM eurjchem-101 2 37     SPACE eurjchem-101 2 38 may may AUX eurjchem-101 2 39     SPACE eurjchem-101 2 40 2010 2010 NUM eurjchem-101 2 41     SPACE eurjchem-101 2 42 received receive VERB eurjchem-101 2 43     SPACE eurjchem-101 2 44 in in ADP eurjchem-101 2 45     SPACE eurjchem-101 2 46 revised revise VERB eurjchem-101 2 47     SPACE eurjchem-101 2 48 form form NOUN eurjchem-101 2 49 : : PUNCT eurjchem-101 2 50     SPACE eurjchem-101 2 51 09 09 NUM eurjchem-101 2 52     SPACE eurjchem-101 2 53 june june PROPN eurjchem-101 2 54     SPACE eurjchem-101 2 55 2010 2010 NUM eurjchem-101 2 56     SPACE eurjchem-101 2 57 accepted accept VERB eurjchem-101 2 58 : : PUNCT eurjchem-101 2 59     SPACE eurjchem-101 2 60 22 22 NUM eurjchem-101 2 61     SPACE eurjchem-101 2 62 june june PROPN eurjchem-101 2 63     SPACE eurjchem-101 2 64 2010 2010 NUM eurjchem-101 2 65     SPACE eurjchem-101 2 66 online online NOUN eurjchem-101 2 67 : : PUNCT eurjchem-101 2 68     SPACE eurjchem-101 2 69 31 31 NUM eurjchem-101 2 70     SPACE eurjchem-101 2 71 december december PROPN eurjchem-101 2 72     SPACE eurjchem-101 2 73 2010 2010 NUM eurjchem-101 2 74     SPACE eurjchem-101 2 75 keywords keyword NOUN eurjchem-101 2 76         SPACE eurjchem-101 2 77 it it PRON eurjchem-101 2 78     SPACE eurjchem-101 2 79 is be AUX eurjchem-101 2 80     SPACE eurjchem-101 2 81 known know VERB eurjchem-101 2 82     SPACE eurjchem-101 2 83 that that SCONJ eurjchem-101 2 84     SPACE eurjchem-101 2 85 5‐aminolevulinic 5‐aminolevulinic NUM eurjchem-101 2 86     SPACE eurjchem-101 2 87 acid acid NOUN eurjchem-101 2 88     SPACE eurjchem-101 2 89 ( ( PUNCT eurjchem-101 2 90 5‐ala 5‐ala NUM eurjchem-101 2 91 ) ) PUNCT eurjchem-101 2 92     SPACE eurjchem-101 2 93 is be AUX eurjchem-101 2 94     SPACE eurjchem-101 2 95 not not PART eurjchem-101 2 96     SPACE eurjchem-101 2 97 stable stable ADJ eurjchem-101 2 98     SPACE eurjchem-101 2 99 in in ADP eurjchem-101 2 100     SPACE eurjchem-101 2 101 an an DET eurjchem-101 2 102     SPACE eurjchem-101 2 103 aqueous aqueous ADJ eurjchem-101 2 104     SPACE eurjchem-101 2 105 solution solution NOUN eurjchem-101 2 106     SPACE eurjchem-101 2 107 because because SCONJ eurjchem-101 2 108     SPACE eurjchem-101 2 109 of of ADP eurjchem-101 2 110     SPACE eurjchem-101 2 111 the the DET eurjchem-101 2 112     SPACE eurjchem-101 2 113 auto‐condensation auto‐condensation NOUN eurjchem-101 2 114     SPACE eurjchem-101 2 115 reaction reaction NOUN eurjchem-101 2 116     SPACE eurjchem-101 2 117 between between ADP eurjchem-101 2 118     SPACE eurjchem-101 2 119 two two NUM eurjchem-101 2 120     SPACE eurjchem-101 2 121 5‐ala 5‐ala NUM eurjchem-101 2 122     SPACE eurjchem-101 2 123 molecules molecule NOUN eurjchem-101 2 124 ; ; PUNCT eurjchem-101 2 125     SPACE eurjchem-101 2 126 however however ADV eurjchem-101 2 127 , , PUNCT eurjchem-101 2 128     SPACE eurjchem-101 2 129 in in ADP eurjchem-101 2 130     SPACE eurjchem-101 2 131 this this DET eurjchem-101 2 132     SPACE eurjchem-101 2 133 study study NOUN eurjchem-101 2 134 , , PUNCT eurjchem-101 2 135     SPACE eurjchem-101 2 136 5‐ala 5‐ala NUM eurjchem-101 2 137     SPACE eurjchem-101 2 138 was be AUX eurjchem-101 2 139     SPACE eurjchem-101 2 140 stabilized stabilize VERB eurjchem-101 2 141     SPACE eurjchem-101 2 142 by by ADP eurjchem-101 2 143     SPACE eurjchem-101 2 144 the the DET eurjchem-101 2 145     SPACE eurjchem-101 2 146 zinc(ii zinc(ii NUM eurjchem-101 2 147 ) ) PUNCT eurjchem-101 2 148     SPACE eurjchem-101 2 149 ion ion NOUN eurjchem-101 2 150     SPACE eurjchem-101 2 151 in in ADP eurjchem-101 2 152     SPACE eurjchem-101 2 153 an an DET eurjchem-101 2 154     SPACE eurjchem-101 2 155 aqueous aqueous ADJ eurjchem-101 2 156     SPACE eurjchem-101 2 157 solution solution NOUN eurjchem-101 2 158     SPACE eurjchem-101 2 159 of of ADP eurjchem-101 2 160     SPACE eurjchem-101 2 161 neutral neutral ADJ eurjchem-101 2 162     SPACE eurjchem-101 2 163 ph ph PROPN eurjchem-101 2 164 . . PROPN eurjchem-101 2 165     SPACE eurjchem-101 2 166 this this DET eurjchem-101 2 167     SPACE eurjchem-101 2 168 stabilization stabilization NOUN eurjchem-101 2 169     SPACE eurjchem-101 2 170 effect effect NOUN eurjchem-101 2 171     SPACE eurjchem-101 2 172 was be AUX eurjchem-101 2 173     SPACE eurjchem-101 2 174 ascertained ascertain VERB eurjchem-101 2 175     SPACE eurjchem-101 2 176 by by ADP eurjchem-101 2 177     SPACE eurjchem-101 2 178 uv‐vis uv‐vi NOUN eurjchem-101 2 179     SPACE eurjchem-101 2 180 spectroscopy spectroscopy NOUN eurjchem-101 2 181     SPACE eurjchem-101 2 182 and and CCONJ eurjchem-101 2 183     SPACE eurjchem-101 2 184 1h 1h NUM eurjchem-101 2 185     SPACE eurjchem-101 2 186 and and CCONJ eurjchem-101 2 187     SPACE eurjchem-101 2 188 13c 13c NOUN eurjchem-101 2 189     SPACE eurjchem-101 2 190 nmr nmr NOUN eurjchem-101 2 191     SPACE eurjchem-101 2 192 spectroscopy spectroscopy NOUN eurjchem-101 2 193 . . PUNCT eurjchem-101 2 194     SPACE eurjchem-101 3 1 5‐aminolevulinic 5‐aminolevulinic NUM eurjchem-101 3 2     SPACE eurjchem-101 3 3 acid acid NOUN eurjchem-101 3 4     SPACE eurjchem-101 3 5 zinc(ii zinc(ii NUM eurjchem-101 3 6 ) ) PUNCT eurjchem-101 3 7     SPACE eurjchem-101 3 8 ion ion NOUN eurjchem-101 3 9     SPACE eurjchem-101 3 10 uv‐vis uv‐vis PROPN eurjchem-101 3 11     SPACE eurjchem-101 3 12 absorption absorption NOUN eurjchem-101 3 13     SPACE eurjchem-101 3 14 spectra spectra NOUN eurjchem-101 3 15     SPACE eurjchem-101 3 16 nmr nmr NOUN eurjchem-101 3 17     SPACE eurjchem-101 3 18 ph ph NOUN eurjchem-101 3 19         SPACE eurjchem-101 3 20 1 1 NUM eurjchem-101 3 21 . . PUNCT eurjchem-101 3 22     SPACE eurjchem-101 3 23 introduction introduction NOUN eurjchem-101 3 24         SPACE eurjchem-101 3 25 5‐aminolevulinic 5‐aminolevulinic NUM eurjchem-101 3 26     SPACE eurjchem-101 3 27 acid acid NOUN eurjchem-101 3 28     SPACE eurjchem-101 3 29 ( ( PUNCT eurjchem-101 3 30 5‐ala 5‐ala NUM eurjchem-101 3 31 ) ) PUNCT eurjchem-101 3 32     SPACE eurjchem-101 3 33 ( ( PUNCT eurjchem-101 3 34 scheme scheme NOUN eurjchem-101 3 35     SPACE eurjchem-101 3 36 1 1 NUM eurjchem-101 3 37 ) ) PUNCT eurjchem-101 3 38     SPACE eurjchem-101 3 39 is be AUX eurjchem-101 3 40     SPACE eurjchem-101 3 41 the the DET eurjchem-101 3 42     SPACE eurjchem-101 3 43 precursor precursor NOUN eurjchem-101 3 44     SPACE eurjchem-101 3 45 of of ADP eurjchem-101 3 46     SPACE eurjchem-101 3 47 all all PRON eurjchem-101 3 48     SPACE eurjchem-101 3 49 tetrapyrroles tetrapyrrole VERB eurjchem-101 3 50     SPACE eurjchem-101 3 51 in in ADP eurjchem-101 3 52     SPACE eurjchem-101 3 53 biological biological ADJ eurjchem-101 3 54     SPACE eurjchem-101 3 55 systems system NOUN eurjchem-101 3 56     SPACE eurjchem-101 4 1 [ [ X eurjchem-101 4 2 1 1 NUM eurjchem-101 4 3 ] ] PUNCT eurjchem-101 4 4 ; ; PUNCT eurjchem-101 4 5     SPACE eurjchem-101 4 6 in in ADP eurjchem-101 4 7     SPACE eurjchem-101 4 8 the the DET eurjchem-101 4 9     SPACE eurjchem-101 4 10 case case NOUN eurjchem-101 4 11     SPACE eurjchem-101 4 12 of of ADP eurjchem-101 4 13     SPACE eurjchem-101 4 14 mammals mammal NOUN eurjchem-101 4 15 , , PUNCT eurjchem-101 4 16     SPACE eurjchem-101 4 17 heme heme NOUN eurjchem-101 4 18     SPACE eurjchem-101 4 19 is be AUX eurjchem-101 4 20     SPACE eurjchem-101 4 21 synthesized synthesize VERB eurjchem-101 4 22     SPACE eurjchem-101 4 23 from from ADP eurjchem-101 4 24     SPACE eurjchem-101 4 25 5‐ala 5‐ala NUM eurjchem-101 4 26 , , PUNCT eurjchem-101 4 27     SPACE eurjchem-101 4 28 and and CCONJ eurjchem-101 4 29 , , PUNCT eurjchem-101 4 30     SPACE eurjchem-101 4 31 in in ADP eurjchem-101 4 32     SPACE eurjchem-101 4 33 the the DET eurjchem-101 4 34     SPACE eurjchem-101 4 35 case case NOUN eurjchem-101 4 36     SPACE eurjchem-101 4 37 of of ADP eurjchem-101 4 38     SPACE eurjchem-101 4 39 green green ADJ eurjchem-101 4 40     SPACE eurjchem-101 4 41 plants plant NOUN eurjchem-101 4 42 , , PUNCT eurjchem-101 4 43     SPACE eurjchem-101 4 44 chlorophyll chlorophyll NOUN eurjchem-101 4 45     SPACE eurjchem-101 4 46 is be AUX eurjchem-101 4 47     SPACE eurjchem-101 4 48 synthesized synthesize VERB eurjchem-101 4 49     SPACE eurjchem-101 4 50 from from ADP eurjchem-101 4 51     SPACE eurjchem-101 4 52 5‐ala 5‐ala NUM eurjchem-101 4 53 . . PUNCT eurjchem-101 4 54     SPACE eurjchem-101 4 55 in in ADP eurjchem-101 4 56     SPACE eurjchem-101 4 57 both both DET eurjchem-101 4 58     SPACE eurjchem-101 4 59 biosynthetic biosynthetic ADJ eurjchem-101 4 60     SPACE eurjchem-101 4 61 processes process NOUN eurjchem-101 4 62 , , PUNCT eurjchem-101 4 63     SPACE eurjchem-101 4 64 two two NUM eurjchem-101 4 65     SPACE eurjchem-101 4 66 5‐ala 5‐ala NUM eurjchem-101 4 67     SPACE eurjchem-101 4 68 molecules molecule NOUN eurjchem-101 4 69     SPACE eurjchem-101 4 70 are be AUX eurjchem-101 4 71     SPACE eurjchem-101 4 72 condensed condense VERB eurjchem-101 4 73     SPACE eurjchem-101 4 74 to to PART eurjchem-101 4 75     SPACE eurjchem-101 4 76 give give VERB eurjchem-101 4 77     SPACE eurjchem-101 4 78 porphobilinogen porphobilinogen NOUN eurjchem-101 4 79     SPACE eurjchem-101 4 80 by by ADP eurjchem-101 4 81     SPACE eurjchem-101 4 82 an an DET eurjchem-101 4 83     SPACE eurjchem-101 4 84 enzyme enzyme NOUN eurjchem-101 4 85 , , PUNCT eurjchem-101 4 86     SPACE eurjchem-101 4 87 5‐aminolevulinic 5‐aminolevulinic NUM eurjchem-101 4 88     SPACE eurjchem-101 4 89 acid acid NOUN eurjchem-101 4 90     SPACE eurjchem-101 4 91 dehydratase dehydratase NOUN eurjchem-101 4 92     SPACE eurjchem-101 4 93 ( ( PUNCT eurjchem-101 4 94 ec ec PROPN eurjchem-101 4 95     SPACE eurjchem-101 4 96 4.2.1.24 4.2.1.24 PROPN eurjchem-101 4 97 ) ) PUNCT eurjchem-101 4 98 ; ; PUNCT eurjchem-101 4 99     SPACE eurjchem-101 4 100 however however ADV eurjchem-101 4 101 , , PUNCT eurjchem-101 4 102     SPACE eurjchem-101 4 103 without without ADP eurjchem-101 4 104     SPACE eurjchem-101 4 105 the the DET eurjchem-101 4 106     SPACE eurjchem-101 4 107 enzyme enzyme NOUN eurjchem-101 4 108 , , PUNCT eurjchem-101 4 109     SPACE eurjchem-101 4 110 two two NUM eurjchem-101 4 111     SPACE eurjchem-101 4 112 5‐ala 5‐ala NUM eurjchem-101 4 113     SPACE eurjchem-101 4 114 molecules molecule NOUN eurjchem-101 4 115     SPACE eurjchem-101 4 116 are be AUX eurjchem-101 4 117     SPACE eurjchem-101 4 118 condensed condense VERB eurjchem-101 4 119     SPACE eurjchem-101 4 120 in in ADP eurjchem-101 4 121     SPACE eurjchem-101 4 122 a a DET eurjchem-101 4 123     SPACE eurjchem-101 4 124 different different ADJ eurjchem-101 4 125     SPACE eurjchem-101 4 126 manner manner NOUN eurjchem-101 4 127     SPACE eurjchem-101 4 128 to to PART eurjchem-101 4 129     SPACE eurjchem-101 4 130 give give VERB eurjchem-101 4 131     SPACE eurjchem-101 4 132 different different ADJ eurjchem-101 4 133     SPACE eurjchem-101 4 134 products product NOUN eurjchem-101 4 135     SPACE eurjchem-101 4 136 [ [ X eurjchem-101 4 137 2–6 2–6 NOUN eurjchem-101 4 138 ] ] X eurjchem-101 4 139 . . PUNCT eurjchem-101 4 140     SPACE eurjchem-101 5 1 the the DET eurjchem-101 5 2     SPACE eurjchem-101 5 3 mechanism mechanism NOUN eurjchem-101 5 4     SPACE eurjchem-101 5 5 of of ADP eurjchem-101 5 6     SPACE eurjchem-101 5 7 this this DET eurjchem-101 5 8     SPACE eurjchem-101 5 9 auto‐ auto‐ NOUN eurjchem-101 5 10 condensation condensation NOUN eurjchem-101 5 11     SPACE eurjchem-101 5 12 of of ADP eurjchem-101 5 13     SPACE eurjchem-101 5 14 5‐ala 5‐ala NUM eurjchem-101 5 15     SPACE eurjchem-101 5 16 was be AUX eurjchem-101 5 17     SPACE eurjchem-101 5 18 studied study VERB eurjchem-101 5 19     SPACE eurjchem-101 5 20 by by ADP eurjchem-101 5 21     SPACE eurjchem-101 5 22 jaffe jaffe PROPN eurjchem-101 5 23     SPACE eurjchem-101 5 24 and and CCONJ eurjchem-101 5 25     SPACE eurjchem-101 5 26 coworkers coworker NOUN eurjchem-101 5 27     SPACE eurjchem-101 6 1 [ [ X eurjchem-101 6 2 2 2 NUM eurjchem-101 6 3 ] ] PUNCT eurjchem-101 6 4     SPACE eurjchem-101 6 5 and and CCONJ eurjchem-101 6 6     SPACE eurjchem-101 6 7 novo novo NOUN eurjchem-101 6 8     SPACE eurjchem-101 6 9 and and CCONJ eurjchem-101 6 10     SPACE eurjchem-101 6 11 coworkers coworker NOUN eurjchem-101 6 12     SPACE eurjchem-101 7 1 [ [ X eurjchem-101 7 2 3 3 NUM eurjchem-101 7 3 ] ] PUNCT eurjchem-101 7 4 . . PUNCT eurjchem-101 7 5     SPACE eurjchem-101 7 6 they they PRON eurjchem-101 7 7     SPACE eurjchem-101 7 8 reported report VERB eurjchem-101 7 9     SPACE eurjchem-101 7 10 that that SCONJ eurjchem-101 7 11     SPACE eurjchem-101 7 12 two two NUM eurjchem-101 7 13     SPACE eurjchem-101 7 14 5‐ala 5‐ala NUM eurjchem-101 7 15     SPACE eurjchem-101 7 16 molecules molecule NOUN eurjchem-101 7 17     SPACE eurjchem-101 7 18 were be AUX eurjchem-101 7 19     SPACE eurjchem-101 7 20 condensed condense VERB eurjchem-101 7 21     SPACE eurjchem-101 7 22 to to PART eurjchem-101 7 23     SPACE eurjchem-101 7 24 form form VERB eurjchem-101 7 25     SPACE eurjchem-101 7 26 2,5‐bis(2‐carboxyethyl 2,5‐bis(2‐carboxyethyl NUM eurjchem-101 7 27 ) ) PUNCT eurjchem-101 7 28     SPACE eurjchem-101 7 29 dihydropyrazine(2,5‐dihydropyrazinedipropionic dihydropyrazine(2,5‐dihydropyrazinedipropionic ADJ eurjchem-101 7 30     SPACE eurjchem-101 7 31 acid acid NOUN eurjchem-101 7 32 , , PUNCT eurjchem-101 7 33     SPACE eurjchem-101 7 34 hpdpa hpdpa PROPN eurjchem-101 7 35 ) ) PUNCT eurjchem-101 7 36     SPACE eurjchem-101 7 37 and and CCONJ eurjchem-101 7 38     SPACE eurjchem-101 7 39 then then ADV eurjchem-101 7 40     SPACE eurjchem-101 7 41 hpdpa hpdpa NOUN eurjchem-101 7 42     SPACE eurjchem-101 7 43 was be AUX eurjchem-101 7 44     SPACE eurjchem-101 7 45 oxidized oxidize VERB eurjchem-101 7 46     SPACE eurjchem-101 7 47 by by ADP eurjchem-101 7 48     SPACE eurjchem-101 7 49 molecular molecular ADJ eurjchem-101 7 50     SPACE eurjchem-101 7 51 oxygen oxygen NOUN eurjchem-101 7 52     SPACE eurjchem-101 7 53 to to PART eurjchem-101 7 54     SPACE eurjchem-101 7 55 form form VERB eurjchem-101 7 56       SPACE eurjchem-101 7 57 2,5‐bis(2‐carboxyethyl)pyrazine(2,5‐pyrazinedipropionic 2,5‐bis(2‐carboxyethyl)pyrazine(2,5‐pyrazinedipropionic NUM eurjchem-101 7 58     SPACE eurjchem-101 7 59 acid acid ADJ eurjchem-101 7 60 , , PUNCT eurjchem-101 7 61     SPACE eurjchem-101 7 62 pdpa pdpa NOUN eurjchem-101 7 63 ) ) PUNCT eurjchem-101 7 64 . . PUNCT eurjchem-101 7 65         SPACE eurjchem-101 8 1 o o X eurjchem-101 8 2 o o X eurjchem-101 8 3 ohh2n ohh2n NOUN eurjchem-101 8 4     SPACE eurjchem-101 8 5 5‐ala 5‐ala NUM eurjchem-101 8 6         SPACE eurjchem-101 8 7 scheme scheme NOUN eurjchem-101 8 8     SPACE eurjchem-101 8 9 1 1 NUM eurjchem-101 8 10         SPACE eurjchem-101 8 11 recently recently ADV eurjchem-101 8 12     SPACE eurjchem-101 8 13 5‐ala 5‐ala NUM eurjchem-101 8 14     SPACE eurjchem-101 8 15 has have AUX eurjchem-101 8 16     SPACE eurjchem-101 8 17 been be AUX eurjchem-101 8 18     SPACE eurjchem-101 8 19 used use VERB eurjchem-101 8 20     SPACE eurjchem-101 8 21 as as ADP eurjchem-101 8 22     SPACE eurjchem-101 8 23 a a DET eurjchem-101 8 24     SPACE eurjchem-101 8 25 fertilizer fertilizer NOUN eurjchem-101 8 26     SPACE eurjchem-101 8 27 for for ADP eurjchem-101 8 28     SPACE eurjchem-101 8 29 tomatoes tomato NOUN eurjchem-101 8 30 , , PUNCT eurjchem-101 8 31     SPACE eurjchem-101 8 32 wine wine NOUN eurjchem-101 8 33     SPACE eurjchem-101 8 34 grapes grape NOUN eurjchem-101 8 35 , , PUNCT eurjchem-101 8 36     SPACE eurjchem-101 8 37 strawberries strawberry NOUN eurjchem-101 8 38 , , PUNCT eurjchem-101 8 39     SPACE eurjchem-101 8 40 and and CCONJ eurjchem-101 8 41     SPACE eurjchem-101 8 42 other other ADJ eurjchem-101 8 43     SPACE eurjchem-101 8 44 crops crop NOUN eurjchem-101 8 45 ; ; PUNCT eurjchem-101 8 46     SPACE eurjchem-101 8 47 however however ADV eurjchem-101 8 48 , , PUNCT eurjchem-101 8 49     SPACE eurjchem-101 8 50 the the DET eurjchem-101 8 51     SPACE eurjchem-101 8 52 auto‐ auto‐ NOUN eurjchem-101 8 53 condensation condensation NOUN eurjchem-101 8 54     SPACE eurjchem-101 8 55 of of ADP eurjchem-101 8 56     SPACE eurjchem-101 8 57 5‐ala 5‐ala NUM eurjchem-101 8 58     SPACE eurjchem-101 8 59 reduces reduce VERB eurjchem-101 8 60     SPACE eurjchem-101 8 61 the the DET eurjchem-101 8 62     SPACE eurjchem-101 8 63 concentration concentration NOUN eurjchem-101 8 64     SPACE eurjchem-101 8 65 of of ADP eurjchem-101 8 66     SPACE eurjchem-101 8 67 5‐ala 5‐ala NUM eurjchem-101 8 68     SPACE eurjchem-101 8 69 in in ADP eurjchem-101 8 70     SPACE eurjchem-101 8 71 the the DET eurjchem-101 8 72     SPACE eurjchem-101 8 73 fertilizer fertilizer NOUN eurjchem-101 8 74     SPACE eurjchem-101 8 75 solution solution NOUN eurjchem-101 8 76 , , PUNCT eurjchem-101 8 77     SPACE eurjchem-101 8 78 which which PRON eurjchem-101 8 79     SPACE eurjchem-101 8 80 is be AUX eurjchem-101 8 81     SPACE eurjchem-101 8 82 a a DET eurjchem-101 8 83     SPACE eurjchem-101 8 84 problem problem NOUN eurjchem-101 8 85 . . PUNCT eurjchem-101 8 86     SPACE eurjchem-101 8 87 therefore therefore ADV eurjchem-101 8 88 , , PUNCT eurjchem-101 8 89     SPACE eurjchem-101 8 90 we we PRON eurjchem-101 8 91     SPACE eurjchem-101 8 92 are be AUX eurjchem-101 8 93     SPACE eurjchem-101 8 94 looking look VERB eurjchem-101 8 95     SPACE eurjchem-101 8 96 for for ADP eurjchem-101 8 97     SPACE eurjchem-101 8 98 a a DET eurjchem-101 8 99     SPACE eurjchem-101 8 100 method method NOUN eurjchem-101 8 101     SPACE eurjchem-101 8 102 to to PART eurjchem-101 8 103     SPACE eurjchem-101 8 104 stabilize stabilize VERB eurjchem-101 8 105     SPACE eurjchem-101 8 106 5‐ala 5‐ala NUM eurjchem-101 8 107     SPACE eurjchem-101 8 108 in in ADP eurjchem-101 8 109     SPACE eurjchem-101 8 110 an an DET eurjchem-101 8 111     SPACE eurjchem-101 8 112 aqueous aqueous ADJ eurjchem-101 8 113     SPACE eurjchem-101 8 114 solution solution NOUN eurjchem-101 8 115     SPACE eurjchem-101 8 116 of of ADP eurjchem-101 8 117     SPACE eurjchem-101 8 118 neutral neutral ADJ eurjchem-101 8 119     SPACE eurjchem-101 8 120 ph ph PROPN eurjchem-101 8 121 . . PROPN eurjchem-101 8 122     SPACE eurjchem-101 8 123 in in ADP eurjchem-101 8 124     SPACE eurjchem-101 8 125 the the DET eurjchem-101 8 126     SPACE eurjchem-101 8 127 auto‐condensation auto‐condensation NOUN eurjchem-101 8 128 , , PUNCT eurjchem-101 8 129     SPACE eurjchem-101 8 130 the the DET eurjchem-101 8 131     SPACE eurjchem-101 8 132 first first ADJ eurjchem-101 8 133     SPACE eurjchem-101 8 134 condensation condensation NOUN eurjchem-101 8 135     SPACE eurjchem-101 8 136 process process NOUN eurjchem-101 8 137     SPACE eurjchem-101 8 138 is be AUX eurjchem-101 8 139     SPACE eurjchem-101 8 140 thought think VERB eurjchem-101 8 141     SPACE eurjchem-101 8 142 to to PART eurjchem-101 8 143     SPACE eurjchem-101 8 144 start start VERB eurjchem-101 8 145     SPACE eurjchem-101 8 146 with with ADP eurjchem-101 8 147     SPACE eurjchem-101 8 148 a a DET eurjchem-101 8 149     SPACE eurjchem-101 8 150 nucleophilic nucleophilic ADJ eurjchem-101 8 151     SPACE eurjchem-101 8 152 attack attack NOUN eurjchem-101 8 153     SPACE eurjchem-101 8 154 by by ADP eurjchem-101 8 155     SPACE eurjchem-101 8 156 a a DET eurjchem-101 8 157     SPACE eurjchem-101 8 158 lone lone ADJ eurjchem-101 8 159     SPACE eurjchem-101 8 160 pair pair NOUN eurjchem-101 8 161     SPACE eurjchem-101 8 162 of of ADP eurjchem-101 8 163     SPACE eurjchem-101 8 164 the the DET eurjchem-101 8 165     SPACE eurjchem-101 8 166 amino amino NOUN eurjchem-101 8 167     SPACE eurjchem-101 8 168 group group NOUN eurjchem-101 8 169     SPACE eurjchem-101 8 170 of of ADP eurjchem-101 8 171     SPACE eurjchem-101 8 172 5‐ala 5‐ala NUM eurjchem-101 8 173     SPACE eurjchem-101 8 174 to to ADP eurjchem-101 8 175     SPACE eurjchem-101 8 176 a a DET eurjchem-101 8 177     SPACE eurjchem-101 8 178 γ‐carbonyl γ‐carbonyl NUM eurjchem-101 8 179     SPACE eurjchem-101 8 180 carbon carbon NOUN eurjchem-101 8 181     SPACE eurjchem-101 8 182 of of ADP eurjchem-101 8 183     SPACE eurjchem-101 8 184 another another DET eurjchem-101 8 185     SPACE eurjchem-101 8 186 5‐ala 5‐ala NUM eurjchem-101 8 187     SPACE eurjchem-101 8 188 molecule molecule NOUN eurjchem-101 8 189 . . PUNCT eurjchem-101 8 190     SPACE eurjchem-101 9 1 therefore therefore ADV eurjchem-101 9 2 , , PUNCT eurjchem-101 9 3     SPACE eurjchem-101 9 4 if if SCONJ eurjchem-101 9 5     SPACE eurjchem-101 9 6 metal metal NOUN eurjchem-101 9 7     SPACE eurjchem-101 9 8 ions ion NOUN eurjchem-101 9 9     SPACE eurjchem-101 9 10 are be AUX eurjchem-101 9 11     SPACE eurjchem-101 9 12 added add VERB eurjchem-101 9 13     SPACE eurjchem-101 9 14 to to ADP eurjchem-101 9 15     SPACE eurjchem-101 9 16 a a DET eurjchem-101 9 17     SPACE eurjchem-101 9 18 5‐ala 5‐ala NUM eurjchem-101 9 19     SPACE eurjchem-101 9 20 solution solution NOUN eurjchem-101 9 21     SPACE eurjchem-101 9 22 and and CCONJ eurjchem-101 9 23     SPACE eurjchem-101 9 24 bind bind VERB eurjchem-101 9 25     SPACE eurjchem-101 9 26 to to ADP eurjchem-101 9 27     SPACE eurjchem-101 9 28 the the DET eurjchem-101 9 29     SPACE eurjchem-101 9 30 amino amino NOUN eurjchem-101 9 31     SPACE eurjchem-101 9 32 groups group NOUN eurjchem-101 9 33     SPACE eurjchem-101 9 34 of of ADP eurjchem-101 9 35     SPACE eurjchem-101 9 36 5‐ala 5‐ala NUM eurjchem-101 9 37     SPACE eurjchem-101 9 38 molecules molecule NOUN eurjchem-101 9 39 , , PUNCT eurjchem-101 9 40     SPACE eurjchem-101 9 41 the the DET eurjchem-101 9 42     SPACE eurjchem-101 9 43 initial initial ADJ eurjchem-101 9 44     SPACE eurjchem-101 9 45 nucleophilic nucleophilic ADJ eurjchem-101 9 46     SPACE eurjchem-101 9 47 attack attack NOUN eurjchem-101 9 48     SPACE eurjchem-101 9 49 will will AUX eurjchem-101 9 50     SPACE eurjchem-101 9 51 be be AUX eurjchem-101 9 52     SPACE eurjchem-101 9 53 stopped stop VERB eurjchem-101 9 54 , , PUNCT eurjchem-101 9 55     SPACE eurjchem-101 9 56 and and CCONJ eurjchem-101 9 57       SPACE eurjchem-101 9 58 5‐ala 5‐ala NUM eurjchem-101 9 59     SPACE eurjchem-101 9 60 molecules molecule NOUN eurjchem-101 9 61     SPACE eurjchem-101 9 62 should should AUX eurjchem-101 9 63     SPACE eurjchem-101 9 64 be be AUX eurjchem-101 9 65     SPACE eurjchem-101 9 66 stabilized stabilize VERB eurjchem-101 9 67 . . PUNCT eurjchem-101 9 68     SPACE eurjchem-101 10 1 in in ADP eurjchem-101 10 2     SPACE eurjchem-101 10 3 this this DET eurjchem-101 10 4     SPACE eurjchem-101 10 5 study study NOUN eurjchem-101 10 6 , , PUNCT eurjchem-101 10 7     SPACE eurjchem-101 10 8 we we PRON eurjchem-101 10 9     SPACE eurjchem-101 10 10 examined examine VERB eurjchem-101 10 11     SPACE eurjchem-101 10 12 the the DET eurjchem-101 10 13     SPACE eurjchem-101 10 14 effect effect NOUN eurjchem-101 10 15     SPACE eurjchem-101 10 16 of of ADP eurjchem-101 10 17     SPACE eurjchem-101 10 18 a a DET eurjchem-101 10 19     SPACE eurjchem-101 10 20 zinc(ii zinc(ii NUM eurjchem-101 10 21 ) ) PUNCT eurjchem-101 10 22     SPACE eurjchem-101 10 23 ion ion NOUN eurjchem-101 10 24     SPACE eurjchem-101 10 25 because because SCONJ eurjchem-101 10 26     SPACE eurjchem-101 10 27 the the DET eurjchem-101 10 28     SPACE eurjchem-101 10 29 zinc(ii zinc(ii NUM eurjchem-101 10 30 ) ) PUNCT eurjchem-101 10 31     SPACE eurjchem-101 10 32 ion ion NOUN eurjchem-101 10 33     SPACE eurjchem-101 10 34 is be AUX eurjchem-101 10 35     SPACE eurjchem-101 10 36 colorless colorless ADJ eurjchem-101 10 37     SPACE eurjchem-101 10 38 and and CCONJ eurjchem-101 10 39     SPACE eurjchem-101 10 40 diamagnetic diamagnetic NOUN eurjchem-101 10 41     SPACE eurjchem-101 10 42 due due ADJ eurjchem-101 10 43     SPACE eurjchem-101 10 44 to to ADP eurjchem-101 10 45     SPACE eurjchem-101 10 46 its its PRON eurjchem-101 10 47     SPACE eurjchem-101 10 48 d10 d10 PROPN eurjchem-101 10 49     SPACE eurjchem-101 10 50 electronic electronic ADJ eurjchem-101 10 51     SPACE eurjchem-101 10 52 configuration configuration NOUN eurjchem-101 10 53     SPACE eurjchem-101 10 54 and and CCONJ eurjchem-101 10 55     SPACE eurjchem-101 10 56 is be AUX eurjchem-101 10 57     SPACE eurjchem-101 10 58 suitable suitable ADJ eurjchem-101 10 59     SPACE eurjchem-101 10 60 for for ADP eurjchem-101 10 61     SPACE eurjchem-101 10 62 uv‐vis uv‐vi NOUN eurjchem-101 10 63     SPACE eurjchem-101 10 64 spectroscopy spectroscopy NOUN eurjchem-101 10 65     SPACE eurjchem-101 10 66 and and CCONJ eurjchem-101 10 67     SPACE eurjchem-101 10 68 nmr nmr NOUN eurjchem-101 10 69     SPACE eurjchem-101 10 70 spectroscopy spectroscopy NOUN eurjchem-101 10 71 . . PUNCT eurjchem-101 10 72         SPACE eurjchem-101 11 1 2 2 NUM eurjchem-101 11 2 . . PUNCT eurjchem-101 11 3     SPACE eurjchem-101 11 4 experimental experimental ADJ eurjchem-101 11 5         SPACE eurjchem-101 11 6 2.1 2.1 NUM eurjchem-101 11 7 . . PUNCT eurjchem-101 11 8     SPACE eurjchem-101 11 9 measurements measurement NOUN eurjchem-101 11 10         SPACE eurjchem-101 11 11 electronic electronic ADJ eurjchem-101 11 12     SPACE eurjchem-101 11 13 spectra spectra NOUN eurjchem-101 11 14     SPACE eurjchem-101 11 15 were be AUX eurjchem-101 11 16     SPACE eurjchem-101 11 17 recorded record VERB eurjchem-101 11 18     SPACE eurjchem-101 11 19 on on ADP eurjchem-101 11 20     SPACE eurjchem-101 11 21 a a DET eurjchem-101 11 22     SPACE eurjchem-101 11 23 jasco jasco NOUN eurjchem-101 11 24     SPACE eurjchem-101 11 25 v‐560 v‐560 PROPN eurjchem-101 11 26     SPACE eurjchem-101 11 27 spectrometer spectrometer NOUN eurjchem-101 11 28 . . PUNCT eurjchem-101 11 29     SPACE eurjchem-101 12 1 1h 1h NUM eurjchem-101 12 2     SPACE eurjchem-101 12 3 and and CCONJ eurjchem-101 12 4     SPACE eurjchem-101 12 5 13c 13c NOUN eurjchem-101 12 6     SPACE eurjchem-101 12 7 nmr nmr NOUN eurjchem-101 12 8     SPACE eurjchem-101 12 9 spectra spectra NOUN eurjchem-101 12 10     SPACE eurjchem-101 12 11 ( ( PUNCT eurjchem-101 12 12 400 400 NUM eurjchem-101 12 13     SPACE eurjchem-101 12 14 mhz mhz NOUN eurjchem-101 12 15 ) ) PUNCT eurjchem-101 12 16     SPACE eurjchem-101 12 17 were be AUX eurjchem-101 12 18     SPACE eurjchem-101 12 19 recorded record VERB eurjchem-101 12 20     SPACE eurjchem-101 12 21 on on ADP eurjchem-101 12 22     SPACE eurjchem-101 12 23 a a DET eurjchem-101 12 24     SPACE eurjchem-101 12 25 jeol jeol NOUN eurjchem-101 12 26     SPACE eurjchem-101 12 27 jnm‐α400 jnm‐α400 NOUN eurjchem-101 12 28     SPACE eurjchem-101 12 29 spectrometer spectrometer NOUN eurjchem-101 12 30     SPACE eurjchem-101 12 31 in in ADP eurjchem-101 12 32     SPACE eurjchem-101 12 33 d2o d2o NOUN eurjchem-101 12 34     SPACE eurjchem-101 12 35 using use VERB eurjchem-101 12 36     SPACE eurjchem-101 12 37 sodium sodium NOUN eurjchem-101 12 38     SPACE eurjchem-101 12 39 3‐trimethylsilyl‐2,2,3,3‐tetradeuteropropionate 3‐trimethylsilyl‐2,2,3,3‐tetradeuteropropionate NOUN eurjchem-101 12 40     SPACE eurjchem-101 12 41 ( ( PUNCT eurjchem-101 12 42 tsp tsp NOUN eurjchem-101 12 43 ) ) PUNCT eurjchem-101 12 44     SPACE eurjchem-101 12 45 as as ADP eurjchem-101 12 46     SPACE eurjchem-101 12 47 the the DET eurjchem-101 12 48     SPACE eurjchem-101 12 49 internal internal ADJ eurjchem-101 12 50     SPACE eurjchem-101 12 51 standard standard NOUN eurjchem-101 12 52 . . PUNCT eurjchem-101 12 53         SPACE eurjchem-101 13 1 2.2 2.2 NUM eurjchem-101 13 2 . . PUNCT eurjchem-101 13 3     SPACE eurjchem-101 13 4 materials material NOUN eurjchem-101 13 5         SPACE eurjchem-101 13 6 hydrochloric hydrochloric ADJ eurjchem-101 13 7     SPACE eurjchem-101 13 8 salt salt NOUN eurjchem-101 13 9     SPACE eurjchem-101 13 10 of of ADP eurjchem-101 13 11     SPACE eurjchem-101 13 12 5‐ala 5‐ala NUM eurjchem-101 13 13     SPACE eurjchem-101 13 14 ( ( PUNCT eurjchem-101 13 15 5‐ala·hcl 5‐ala·hcl ADJ eurjchem-101 13 16 ) ) PUNCT eurjchem-101 13 17     SPACE eurjchem-101 13 18 was be AUX eurjchem-101 13 19     SPACE eurjchem-101 13 20 prepared prepare VERB eurjchem-101 13 21     SPACE eurjchem-101 13 22 by by ADP eurjchem-101 13 23     SPACE eurjchem-101 13 24 cosmo cosmo PROPN eurjchem-101 13 25     SPACE eurjchem-101 13 26 oil oil NOUN eurjchem-101 13 27     SPACE eurjchem-101 13 28 co. co. PROPN eurjchem-101 13 29 , , PUNCT eurjchem-101 13 30     SPACE eurjchem-101 13 31 ltd ltd PROPN eurjchem-101 13 32 . . PROPN eurjchem-101 13 33     SPACE eurjchem-101 13 34 using use VERB eurjchem-101 13 35     SPACE eurjchem-101 13 36 a a DET eurjchem-101 13 37     SPACE eurjchem-101 13 38 fermentation fermentation NOUN eurjchem-101 13 39     SPACE eurjchem-101 13 40 method method NOUN eurjchem-101 13 41     SPACE eurjchem-101 14 1 [ [ X eurjchem-101 14 2 7 7 NUM eurjchem-101 14 3 ] ] PUNCT eurjchem-101 14 4 . . PUNCT eurjchem-101 14 5     SPACE eurjchem-101 15 1 all all DET eurjchem-101 15 2     SPACE eurjchem-101 15 3 other other ADJ eurjchem-101 15 4     SPACE eurjchem-101 15 5 chemicals chemical NOUN eurjchem-101 15 6     SPACE eurjchem-101 15 7 were be AUX eurjchem-101 15 8     SPACE eurjchem-101 15 9 commercial commercial ADJ eurjchem-101 15 10     SPACE eurjchem-101 15 11 products product NOUN eurjchem-101 15 12     SPACE eurjchem-101 15 13 and and CCONJ eurjchem-101 15 14     SPACE eurjchem-101 15 15 were be AUX eurjchem-101 15 16     SPACE eurjchem-101 15 17 used use VERB eurjchem-101 15 18     SPACE eurjchem-101 15 19 as as SCONJ eurjchem-101 15 20     SPACE eurjchem-101 15 21 supplied supply VERB eurjchem-101 15 22 . . PUNCT eurjchem-101 15 23         SPACE eurjchem-101 16 1 3 3 NUM eurjchem-101 16 2 . . PUNCT eurjchem-101 16 3     SPACE eurjchem-101 16 4 results result VERB eurjchem-101 16 5     SPACE eurjchem-101 16 6 and and CCONJ eurjchem-101 16 7     SPACE eurjchem-101 16 8 discussion discussion NOUN eurjchem-101 16 9         SPACE eurjchem-101 16 10 3.1 3.1 NUM eurjchem-101 16 11 . . PUNCT eurjchem-101 16 12     SPACE eurjchem-101 16 13 auto­condensation auto­condensation NOUN eurjchem-101 16 14     SPACE eurjchem-101 16 15 reaction reaction NOUN eurjchem-101 16 16     SPACE eurjchem-101 16 17 of of ADP eurjchem-101 16 18     SPACE eurjchem-101 16 19 5­ala 5­ala PRON eurjchem-101 16 20     SPACE eurjchem-101 16 21 monitored monitor VERB eurjchem-101 16 22     SPACE eurjchem-101 16 23 by by ADP eurjchem-101 16 24     SPACE eurjchem-101 16 25 electronic electronic ADJ eurjchem-101 16 26     SPACE eurjchem-101 16 27 spectra spectra NOUN eurjchem-101 16 28         SPACE eurjchem-101 16 29 before before ADP eurjchem-101 16 30     SPACE eurjchem-101 16 31 examining examine VERB eurjchem-101 16 32     SPACE eurjchem-101 16 33 the the DET eurjchem-101 16 34     SPACE eurjchem-101 16 35 stabilization stabilization NOUN eurjchem-101 16 36     SPACE eurjchem-101 16 37 effect effect NOUN eurjchem-101 16 38     SPACE eurjchem-101 16 39 of of ADP eurjchem-101 16 40     SPACE eurjchem-101 16 41 zinc(ii zinc(ii NUM eurjchem-101 16 42 ) ) PUNCT eurjchem-101 16 43     SPACE eurjchem-101 16 44 ion ion NOUN eurjchem-101 16 45 , , PUNCT eurjchem-101 16 46     SPACE eurjchem-101 16 47 the the DET eurjchem-101 16 48     SPACE eurjchem-101 16 49 auto‐condensation auto‐condensation NOUN eurjchem-101 16 50     SPACE eurjchem-101 16 51 reaction reaction NOUN eurjchem-101 16 52     SPACE eurjchem-101 16 53 of of ADP eurjchem-101 16 54     SPACE eurjchem-101 16 55 5‐ala 5‐ala NUM eurjchem-101 16 56     SPACE eurjchem-101 16 57 was be AUX eurjchem-101 16 58     SPACE eurjchem-101 16 59 monitored monitor VERB eurjchem-101 16 60     SPACE eurjchem-101 16 61 by by ADP eurjchem-101 16 62     SPACE eurjchem-101 16 63 the the DET eurjchem-101 16 64       SPACE eurjchem-101 16 65 374 374 NUM eurjchem-101 16 66     SPACE eurjchem-101 16 67 sakiyama sakiyama NOUN eurjchem-101 16 68     SPACE eurjchem-101 16 69 et et NOUN eurjchem-101 16 70     SPACE eurjchem-101 16 71 al al PROPN eurjchem-101 16 72 . . PROPN eurjchem-101 16 73     SPACE eurjchem-101 16 74 / / SYM eurjchem-101 16 75     SPACE eurjchem-101 16 76 european european ADJ eurjchem-101 16 77     SPACE eurjchem-101 16 78 journal journal NOUN eurjchem-101 16 79     SPACE eurjchem-101 16 80 of of ADP eurjchem-101 16 81     SPACE eurjchem-101 16 82 chemistry chemistry NOUN eurjchem-101 16 83     SPACE eurjchem-101 16 84 1 1 NUM eurjchem-101 16 85     SPACE eurjchem-101 16 86 ( ( PUNCT eurjchem-101 16 87 4 4 NUM eurjchem-101 16 88 ) ) PUNCT eurjchem-101 16 89     SPACE eurjchem-101 16 90 ( ( PUNCT eurjchem-101 16 91 2010 2010 NUM eurjchem-101 16 92 ) ) PUNCT eurjchem-101 16 93     SPACE eurjchem-101 16 94 373­376 373­376 NUM eurjchem-101 16 95                 SPACE eurjchem-101 16 96 figure figure NOUN eurjchem-101 16 97     SPACE eurjchem-101 16 98 1 1 NUM eurjchem-101 16 99 . . PUNCT eurjchem-101 16 100     SPACE eurjchem-101 16 101 electronic electronic ADJ eurjchem-101 16 102     SPACE eurjchem-101 16 103 spectral spectral ADJ eurjchem-101 16 104     SPACE eurjchem-101 16 105 change change NOUN eurjchem-101 16 106     SPACE eurjchem-101 16 107 for for ADP eurjchem-101 16 108     SPACE eurjchem-101 16 109 an an DET eurjchem-101 16 110     SPACE eurjchem-101 16 111 aqueous aqueous ADJ eurjchem-101 16 112     SPACE eurjchem-101 16 113 5‐ala 5‐ala NUM eurjchem-101 16 114     SPACE eurjchem-101 16 115 solution solution NOUN eurjchem-101 16 116     SPACE eurjchem-101 16 117 ( ( PUNCT eurjchem-101 16 118 left leave VERB eurjchem-101 16 119 ) ) PUNCT eurjchem-101 16 120     SPACE eurjchem-101 16 121 and and CCONJ eurjchem-101 16 122     SPACE eurjchem-101 16 123 time time NOUN eurjchem-101 16 124     SPACE eurjchem-101 16 125 dependencies dependency NOUN eurjchem-101 16 126     SPACE eurjchem-101 16 127 of of ADP eurjchem-101 16 128     SPACE eurjchem-101 16 129 the the DET eurjchem-101 16 130     SPACE eurjchem-101 16 131 absorbance absorbance NOUN eurjchem-101 16 132     SPACE eurjchem-101 16 133 for for ADP eurjchem-101 16 134     SPACE eurjchem-101 16 135 the the DET eurjchem-101 16 136     SPACE eurjchem-101 16 137 solution solution NOUN eurjchem-101 16 138     SPACE eurjchem-101 16 139 at at ADP eurjchem-101 16 140     SPACE eurjchem-101 16 141 245 245 NUM eurjchem-101 16 142     SPACE eurjchem-101 16 143 nm nm PROPN eurjchem-101 16 144     SPACE eurjchem-101 16 145 ( ( PUNCT eurjchem-101 16 146 ○ ○ PROPN eurjchem-101 16 147 ) ) PUNCT eurjchem-101 16 148     SPACE eurjchem-101 16 149 and and CCONJ eurjchem-101 16 150     SPACE eurjchem-101 16 151 275 275 NUM eurjchem-101 16 152     SPACE eurjchem-101 16 153 nm nm NOUN eurjchem-101 16 154     SPACE eurjchem-101 16 155 ( ( PUNCT eurjchem-101 16 156 δ δ PROPN eurjchem-101 16 157 ) ) PUNCT eurjchem-101 16 158     SPACE eurjchem-101 16 159 ( ( PUNCT eurjchem-101 16 160 right right NOUN eurjchem-101 16 161 ) ) PUNCT eurjchem-101 16 162 . . PUNCT eurjchem-101 16 163     SPACE eurjchem-101 17 1 conditions condition NOUN eurjchem-101 17 2 : : PUNCT eurjchem-101 17 3     SPACE eurjchem-101 17 4 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 17 5     SPACE eurjchem-101 17 6 ( ( PUNCT eurjchem-101 17 7 20 20 NUM eurjchem-101 17 8     SPACE eurjchem-101 17 9 μmol μmol NOUN eurjchem-101 17 10 ) ) PUNCT eurjchem-101 17 11     SPACE eurjchem-101 17 12 and and CCONJ eurjchem-101 17 13     SPACE eurjchem-101 17 14 lioh lioh ADV eurjchem-101 17 15     SPACE eurjchem-101 17 16 ( ( PUNCT eurjchem-101 17 17 40 40 NUM eurjchem-101 17 18     SPACE eurjchem-101 17 19 μmol μmol NOUN eurjchem-101 17 20 ) ) PUNCT eurjchem-101 17 21     SPACE eurjchem-101 17 22 in in ADP eurjchem-101 17 23     SPACE eurjchem-101 17 24 5 5 NUM eurjchem-101 17 25     SPACE eurjchem-101 17 26 ml ml NOUN eurjchem-101 17 27     SPACE eurjchem-101 17 28 of of ADP eurjchem-101 17 29     SPACE eurjchem-101 17 30 water water NOUN eurjchem-101 17 31     SPACE eurjchem-101 17 32 under under ADP eurjchem-101 17 33     SPACE eurjchem-101 17 34 aerobic aerobic ADJ eurjchem-101 17 35     SPACE eurjchem-101 17 36 conditions condition NOUN eurjchem-101 17 37     SPACE eurjchem-101 17 38 at at ADP eurjchem-101 17 39     SPACE eurjchem-101 17 40 room room NOUN eurjchem-101 17 41     SPACE eurjchem-101 17 42 temperature temperature NOUN eurjchem-101 17 43     SPACE eurjchem-101 17 44 ( ( PUNCT eurjchem-101 17 45 ph=8.0 ph=8.0 PROPN eurjchem-101 17 46 ) ) PUNCT eurjchem-101 17 47 . . PUNCT eurjchem-101 17 48     SPACE eurjchem-101 18 1 measurements measurement NOUN eurjchem-101 18 2     SPACE eurjchem-101 18 3 were be AUX eurjchem-101 18 4     SPACE eurjchem-101 18 5 conducted conduct VERB eurjchem-101 18 6     SPACE eurjchem-101 18 7 for for ADP eurjchem-101 18 8     SPACE eurjchem-101 18 9 20 20 NUM eurjchem-101 18 10     SPACE eurjchem-101 18 11 hours hour NOUN eurjchem-101 18 12     SPACE eurjchem-101 18 13 at at ADP eurjchem-101 18 14     SPACE eurjchem-101 18 15 one‐hour one‐hour NUM eurjchem-101 18 16     SPACE eurjchem-101 18 17 intervals interval NOUN eurjchem-101 18 18 . . PUNCT eurjchem-101 18 19             SPACE eurjchem-101 18 20 figure figure NOUN eurjchem-101 18 21     SPACE eurjchem-101 18 22 2 2 NUM eurjchem-101 18 23 . . PUNCT eurjchem-101 18 24     SPACE eurjchem-101 18 25 electronic electronic ADJ eurjchem-101 18 26     SPACE eurjchem-101 18 27 spectral spectral ADJ eurjchem-101 18 28     SPACE eurjchem-101 18 29 change change NOUN eurjchem-101 18 30     SPACE eurjchem-101 18 31 for for ADP eurjchem-101 18 32     SPACE eurjchem-101 18 33 an an DET eurjchem-101 18 34     SPACE eurjchem-101 18 35 n2‐exchangerd n2‐exchangerd ADJ eurjchem-101 18 36     SPACE eurjchem-101 18 37 aqueous aqueous ADJ eurjchem-101 18 38     SPACE eurjchem-101 18 39 5‐ala 5‐ala NUM eurjchem-101 18 40     SPACE eurjchem-101 18 41 solution solution NOUN eurjchem-101 18 42     SPACE eurjchem-101 18 43 ( ( PUNCT eurjchem-101 18 44 left leave VERB eurjchem-101 18 45 ) ) PUNCT eurjchem-101 18 46     SPACE eurjchem-101 18 47 and and CCONJ eurjchem-101 18 48     SPACE eurjchem-101 18 49 time time NOUN eurjchem-101 18 50     SPACE eurjchem-101 18 51 dependencies dependency NOUN eurjchem-101 18 52     SPACE eurjchem-101 18 53 of of ADP eurjchem-101 18 54     SPACE eurjchem-101 18 55 the the DET eurjchem-101 18 56     SPACE eurjchem-101 18 57 absorbance absorbance NOUN eurjchem-101 18 58     SPACE eurjchem-101 18 59 for for ADP eurjchem-101 18 60     SPACE eurjchem-101 18 61 the the DET eurjchem-101 18 62     SPACE eurjchem-101 18 63 solution solution NOUN eurjchem-101 18 64     SPACE eurjchem-101 18 65 at at ADP eurjchem-101 18 66     SPACE eurjchem-101 18 67 245 245 NUM eurjchem-101 18 68     SPACE eurjchem-101 18 69 nm nm VERB eurjchem-101 18 70     SPACE eurjchem-101 18 71 ( ( PUNCT eurjchem-101 18 72 ○ ○ PROPN eurjchem-101 18 73 ) ) PUNCT eurjchem-101 18 74     SPACE eurjchem-101 18 75 and and CCONJ eurjchem-101 18 76     SPACE eurjchem-101 18 77 275 275 NUM eurjchem-101 18 78     SPACE eurjchem-101 18 79 nm nm NOUN eurjchem-101 18 80     SPACE eurjchem-101 18 81 ( ( PUNCT eurjchem-101 18 82 δ δ PROPN eurjchem-101 18 83 ) ) PUNCT eurjchem-101 18 84     SPACE eurjchem-101 18 85 ( ( PUNCT eurjchem-101 18 86 right right ADJ eurjchem-101 18 87 ) ) PUNCT eurjchem-101 18 88 . . PUNCT eurjchem-101 18 89     SPACE eurjchem-101 19 1 conditions condition NOUN eurjchem-101 19 2 : : PUNCT eurjchem-101 19 3           SPACE eurjchem-101 19 4 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 19 5     SPACE eurjchem-101 19 6 ( ( PUNCT eurjchem-101 19 7 20 20 NUM eurjchem-101 19 8     SPACE eurjchem-101 19 9 μmol μmol NOUN eurjchem-101 19 10 ) ) PUNCT eurjchem-101 19 11 , , PUNCT eurjchem-101 19 12     SPACE eurjchem-101 19 13 lioh lioh ADV eurjchem-101 19 14     SPACE eurjchem-101 19 15 ( ( PUNCT eurjchem-101 19 16 40 40 NUM eurjchem-101 19 17     SPACE eurjchem-101 19 18 μmol μmol NOUN eurjchem-101 19 19 ) ) PUNCT eurjchem-101 19 20     SPACE eurjchem-101 19 21 in in ADP eurjchem-101 19 22     SPACE eurjchem-101 19 23 5 5 NUM eurjchem-101 19 24     SPACE eurjchem-101 19 25 ml ml NOUN eurjchem-101 19 26     SPACE eurjchem-101 19 27 of of ADP eurjchem-101 19 28     SPACE eurjchem-101 19 29 water water NOUN eurjchem-101 19 30     SPACE eurjchem-101 19 31 under under ADP eurjchem-101 19 32     SPACE eurjchem-101 19 33 n2 n2 ADJ eurjchem-101 19 34     SPACE eurjchem-101 19 35 condition condition NOUN eurjchem-101 19 36     SPACE eurjchem-101 19 37 at at ADP eurjchem-101 19 38     SPACE eurjchem-101 19 39 room room NOUN eurjchem-101 19 40     SPACE eurjchem-101 19 41 temperature temperature NOUN eurjchem-101 19 42 . . PUNCT eurjchem-101 19 43     SPACE eurjchem-101 20 1 measured measure VERB eurjchem-101 20 2     SPACE eurjchem-101 20 3 for for ADP eurjchem-101 20 4     SPACE eurjchem-101 20 5 20 20 NUM eurjchem-101 20 6     SPACE eurjchem-101 20 7 hours hour NOUN eurjchem-101 20 8     SPACE eurjchem-101 20 9 at at ADP eurjchem-101 20 10     SPACE eurjchem-101 20 11 one one NUM eurjchem-101 20 12     SPACE eurjchem-101 20 13 hour hour NOUN eurjchem-101 20 14     SPACE eurjchem-101 20 15 intervals interval NOUN eurjchem-101 20 16 . . PUNCT eurjchem-101 20 17         SPACE eurjchem-101 20 18 electronic electronic ADJ eurjchem-101 20 19     SPACE eurjchem-101 20 20 spectra spectra NOUN eurjchem-101 20 21     SPACE eurjchem-101 20 22 as as SCONJ eurjchem-101 20 23     SPACE eurjchem-101 20 24 follows follow VERB eurjchem-101 20 25 . . PUNCT eurjchem-101 20 26     SPACE eurjchem-101 20 27 an an DET eurjchem-101 20 28     SPACE eurjchem-101 20 29 aqueous aqueous ADJ eurjchem-101 20 30     SPACE eurjchem-101 20 31 solution solution NOUN eurjchem-101 20 32     SPACE eurjchem-101 20 33 of of ADP eurjchem-101 20 34     SPACE eurjchem-101 20 35 5‐ala 5‐ala NUM eurjchem-101 20 36     SPACE eurjchem-101 20 37 ( ( PUNCT eurjchem-101 20 38 ph=~8 ph=~8 NOUN eurjchem-101 20 39 ) ) PUNCT eurjchem-101 20 40     SPACE eurjchem-101 20 41 was be AUX eurjchem-101 20 42     SPACE eurjchem-101 20 43 prepared prepare VERB eurjchem-101 20 44     SPACE eurjchem-101 20 45 by by ADP eurjchem-101 20 46     SPACE eurjchem-101 20 47 mixing mix VERB eurjchem-101 20 48     SPACE eurjchem-101 20 49 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 20 50     SPACE eurjchem-101 20 51 and and CCONJ eurjchem-101 20 52     SPACE eurjchem-101 20 53 lithium lithium NOUN eurjchem-101 20 54     SPACE eurjchem-101 20 55 hydroxide hydroxide NOUN eurjchem-101 20 56     SPACE eurjchem-101 20 57 ( ( PUNCT eurjchem-101 20 58 lioh lioh PROPN eurjchem-101 20 59 ) ) PUNCT eurjchem-101 20 60     SPACE eurjchem-101 20 61 in in ADP eurjchem-101 20 62     SPACE eurjchem-101 20 63 a a DET eurjchem-101 20 64     SPACE eurjchem-101 20 65 1:2 1:2 NUM eurjchem-101 20 66     SPACE eurjchem-101 20 67 molar molar ADJ eurjchem-101 20 68     SPACE eurjchem-101 20 69 ratio ratio NOUN eurjchem-101 20 70 , , PUNCT eurjchem-101 20 71     SPACE eurjchem-101 20 72 and and CCONJ eurjchem-101 20 73     SPACE eurjchem-101 20 74 the the DET eurjchem-101 20 75     SPACE eurjchem-101 20 76 absorption absorption NOUN eurjchem-101 20 77     SPACE eurjchem-101 20 78 spectra spectra NOUN eurjchem-101 20 79     SPACE eurjchem-101 20 80 of of ADP eurjchem-101 20 81     SPACE eurjchem-101 20 82 the the DET eurjchem-101 20 83     SPACE eurjchem-101 20 84 resulting result VERB eurjchem-101 20 85     SPACE eurjchem-101 20 86 solution solution NOUN eurjchem-101 20 87     SPACE eurjchem-101 20 88 were be AUX eurjchem-101 20 89     SPACE eurjchem-101 20 90 measured measure VERB eurjchem-101 20 91     SPACE eurjchem-101 20 92 for for ADP eurjchem-101 20 93     SPACE eurjchem-101 20 94 20 20 NUM eurjchem-101 20 95     SPACE eurjchem-101 20 96 hours hour NOUN eurjchem-101 20 97     SPACE eurjchem-101 20 98 at at ADP eurjchem-101 20 99     SPACE eurjchem-101 20 100 one‐hour one‐hour NUM eurjchem-101 20 101     SPACE eurjchem-101 20 102 intervals interval NOUN eurjchem-101 20 103     SPACE eurjchem-101 20 104 ( ( PUNCT eurjchem-101 20 105 figure figure NOUN eurjchem-101 20 106     SPACE eurjchem-101 20 107 1 1 NUM eurjchem-101 20 108 ) ) PUNCT eurjchem-101 20 109 . . PUNCT eurjchem-101 20 110     SPACE eurjchem-101 21 1 at at ADP eurjchem-101 21 2     SPACE eurjchem-101 21 3 first first ADV eurjchem-101 21 4 , , PUNCT eurjchem-101 21 5     SPACE eurjchem-101 21 6 a a DET eurjchem-101 21 7     SPACE eurjchem-101 21 8 new new ADJ eurjchem-101 21 9     SPACE eurjchem-101 21 10 absorption absorption NOUN eurjchem-101 21 11     SPACE eurjchem-101 21 12 band band NOUN eurjchem-101 21 13     SPACE eurjchem-101 21 14 appeared appear VERB eurjchem-101 21 15     SPACE eurjchem-101 21 16 at at ADP eurjchem-101 21 17     SPACE eurjchem-101 21 18 around around ADP eurjchem-101 21 19     SPACE eurjchem-101 21 20 245 245 NUM eurjchem-101 21 21     SPACE eurjchem-101 21 22 nm nm NOUN eurjchem-101 21 23 , , PUNCT eurjchem-101 21 24     SPACE eurjchem-101 21 25 and and CCONJ eurjchem-101 21 26     SPACE eurjchem-101 21 27 then then ADV eurjchem-101 21 28     SPACE eurjchem-101 21 29 another another DET eurjchem-101 21 30     SPACE eurjchem-101 21 31 band band NOUN eurjchem-101 21 32     SPACE eurjchem-101 21 33 appeared appear VERB eurjchem-101 21 34     SPACE eurjchem-101 21 35 at at ADP eurjchem-101 21 36     SPACE eurjchem-101 21 37 around around ADP eurjchem-101 21 38     SPACE eurjchem-101 21 39 275 275 NUM eurjchem-101 21 40     SPACE eurjchem-101 21 41 nm nm NOUN eurjchem-101 21 42     SPACE eurjchem-101 21 43 together together ADV eurjchem-101 21 44     SPACE eurjchem-101 21 45 with with ADP eurjchem-101 21 46     SPACE eurjchem-101 21 47 two two NUM eurjchem-101 21 48     SPACE eurjchem-101 21 49 shoulder shoulder NOUN eurjchem-101 21 50     SPACE eurjchem-101 21 51 bands band NOUN eurjchem-101 21 52     SPACE eurjchem-101 21 53 at at ADP eurjchem-101 21 54     SPACE eurjchem-101 21 55 around around ADP eurjchem-101 21 56     SPACE eurjchem-101 21 57 300 300 NUM eurjchem-101 21 58     SPACE eurjchem-101 21 59 nm nm NOUN eurjchem-101 21 60     SPACE eurjchem-101 21 61 and and CCONJ eurjchem-101 21 62     SPACE eurjchem-101 21 63 330 330 NUM eurjchem-101 21 64     SPACE eurjchem-101 21 65 nm nm NOUN eurjchem-101 21 66 . . PUNCT eurjchem-101 21 67     SPACE eurjchem-101 21 68 the the DET eurjchem-101 21 69     SPACE eurjchem-101 21 70 result result NOUN eurjchem-101 21 71     SPACE eurjchem-101 21 72 is be AUX eurjchem-101 21 73     SPACE eurjchem-101 21 74 consistent consistent ADJ eurjchem-101 21 75     SPACE eurjchem-101 21 76 with with ADP eurjchem-101 21 77     SPACE eurjchem-101 21 78 the the DET eurjchem-101 21 79     SPACE eurjchem-101 21 80 results result NOUN eurjchem-101 21 81     SPACE eurjchem-101 21 82 of of ADP eurjchem-101 21 83     SPACE eurjchem-101 21 84 novo novo NOUN eurjchem-101 21 85     SPACE eurjchem-101 21 86 and and CCONJ eurjchem-101 21 87     SPACE eurjchem-101 21 88 coworkers coworker NOUN eurjchem-101 21 89     SPACE eurjchem-101 22 1 [ [ X eurjchem-101 22 2 3 3 NUM eurjchem-101 22 3 ] ] PUNCT eurjchem-101 22 4 ; ; PUNCT eurjchem-101 22 5     SPACE eurjchem-101 22 6 the the DET eurjchem-101 22 7     SPACE eurjchem-101 22 8 appearance appearance NOUN eurjchem-101 22 9     SPACE eurjchem-101 22 10 of of ADP eurjchem-101 22 11     SPACE eurjchem-101 22 12 the the DET eurjchem-101 22 13     SPACE eurjchem-101 22 14 first first ADJ eurjchem-101 22 15     SPACE eurjchem-101 22 16 band band NOUN eurjchem-101 22 17     SPACE eurjchem-101 22 18 at at ADP eurjchem-101 22 19     SPACE eurjchem-101 22 20 around around ADV eurjchem-101 22 21     SPACE eurjchem-101 22 22 245 245 NUM eurjchem-101 22 23     SPACE eurjchem-101 22 24 nm nm NOUN eurjchem-101 22 25     SPACE eurjchem-101 22 26 corresponds correspond NOUN eurjchem-101 22 27     SPACE eurjchem-101 22 28 to to ADP eurjchem-101 22 29     SPACE eurjchem-101 22 30 the the DET eurjchem-101 22 31     SPACE eurjchem-101 22 32 formation formation NOUN eurjchem-101 22 33     SPACE eurjchem-101 22 34 of of ADP eurjchem-101 22 35     SPACE eurjchem-101 22 36 hpdpa hpdpa NOUN eurjchem-101 22 37 , , PUNCT eurjchem-101 22 38     SPACE eurjchem-101 22 39 and and CCONJ eurjchem-101 22 40     SPACE eurjchem-101 22 41 the the DET eurjchem-101 22 42     SPACE eurjchem-101 22 43 second second ADJ eurjchem-101 22 44     SPACE eurjchem-101 22 45 band band NOUN eurjchem-101 22 46     SPACE eurjchem-101 22 47 at at ADP eurjchem-101 22 48     SPACE eurjchem-101 22 49 around around ADP eurjchem-101 22 50     SPACE eurjchem-101 22 51 275 275 NUM eurjchem-101 22 52     SPACE eurjchem-101 22 53 nm nm NOUN eurjchem-101 22 54     SPACE eurjchem-101 22 55 corresponds correspond NOUN eurjchem-101 22 56     SPACE eurjchem-101 22 57 to to ADP eurjchem-101 22 58     SPACE eurjchem-101 22 59 the the DET eurjchem-101 22 60     SPACE eurjchem-101 22 61 formation formation NOUN eurjchem-101 22 62     SPACE eurjchem-101 22 63 of of ADP eurjchem-101 22 64     SPACE eurjchem-101 22 65 pdpa pdpa NOUN eurjchem-101 22 66 . . PUNCT eurjchem-101 22 67     SPACE eurjchem-101 23 1 an an DET eurjchem-101 23 2     SPACE eurjchem-101 23 3 experiment experiment NOUN eurjchem-101 23 4     SPACE eurjchem-101 23 5 was be AUX eurjchem-101 23 6     SPACE eurjchem-101 23 7 also also ADV eurjchem-101 23 8     SPACE eurjchem-101 23 9 carried carry VERB eurjchem-101 23 10     SPACE eurjchem-101 23 11 out out ADP eurjchem-101 23 12     SPACE eurjchem-101 23 13 under under ADP eurjchem-101 23 14     SPACE eurjchem-101 23 15 nitrogen nitrogen NOUN eurjchem-101 23 16     SPACE eurjchem-101 23 17 ( ( PUNCT eurjchem-101 23 18 figure figure NOUN eurjchem-101 23 19     SPACE eurjchem-101 23 20 2 2 NUM eurjchem-101 23 21 ) ) PUNCT eurjchem-101 23 22 , , PUNCT eurjchem-101 23 23     SPACE eurjchem-101 23 24 and and CCONJ eurjchem-101 23 25     SPACE eurjchem-101 23 26 as as ADV eurjchem-101 23 27     SPACE eurjchem-101 23 28 anticipated anticipate VERB eurjchem-101 23 29 , , PUNCT eurjchem-101 23 30     SPACE eurjchem-101 23 31 the the DET eurjchem-101 23 32     SPACE eurjchem-101 23 33 first first ADJ eurjchem-101 23 34     SPACE eurjchem-101 23 35 band band NOUN eurjchem-101 23 36     SPACE eurjchem-101 23 37 appeared appear VERB eurjchem-101 23 38     SPACE eurjchem-101 23 39 at at ADP eurjchem-101 23 40     SPACE eurjchem-101 23 41 around around ADV eurjchem-101 23 42     SPACE eurjchem-101 23 43 245 245 NUM eurjchem-101 23 44     SPACE eurjchem-101 23 45 nm nm NOUN eurjchem-101 23 46     SPACE eurjchem-101 23 47 as as ADV eurjchem-101 23 48     SPACE eurjchem-101 23 49 well well ADV eurjchem-101 23 50     SPACE eurjchem-101 23 51 as as ADP eurjchem-101 23 52     SPACE eurjchem-101 23 53 in in ADP eurjchem-101 23 54     SPACE eurjchem-101 23 55 the the DET eurjchem-101 23 56     SPACE eurjchem-101 23 57 aerobic aerobic ADJ eurjchem-101 23 58     SPACE eurjchem-101 23 59 experiment experiment NOUN eurjchem-101 23 60 ; ; PUNCT eurjchem-101 23 61     SPACE eurjchem-101 23 62 however however ADV eurjchem-101 23 63 , , PUNCT eurjchem-101 23 64     SPACE eurjchem-101 23 65 the the DET eurjchem-101 23 66     SPACE eurjchem-101 23 67 intensity intensity NOUN eurjchem-101 23 68     SPACE eurjchem-101 23 69 of of ADP eurjchem-101 23 70     SPACE eurjchem-101 23 71 the the DET eurjchem-101 23 72     SPACE eurjchem-101 23 73 second second ADJ eurjchem-101 23 74     SPACE eurjchem-101 23 75 band band NOUN eurjchem-101 23 76     SPACE eurjchem-101 23 77 at at ADP eurjchem-101 23 78     SPACE eurjchem-101 23 79 around around ADP eurjchem-101 23 80     SPACE eurjchem-101 23 81 275 275 NUM eurjchem-101 23 82     SPACE eurjchem-101 23 83 nm nm VERB eurjchem-101 23 84     SPACE eurjchem-101 23 85 was be AUX eurjchem-101 23 86     SPACE eurjchem-101 23 87 significantly significantly ADV eurjchem-101 23 88     SPACE eurjchem-101 23 89 smaller small ADJ eurjchem-101 23 90     SPACE eurjchem-101 23 91 than than ADP eurjchem-101 23 92     SPACE eurjchem-101 23 93 that that PRON eurjchem-101 23 94     SPACE eurjchem-101 23 95 in in ADP eurjchem-101 23 96     SPACE eurjchem-101 23 97 the the DET eurjchem-101 23 98     SPACE eurjchem-101 23 99 aerobic aerobic ADJ eurjchem-101 23 100     SPACE eurjchem-101 23 101 experiment experiment NOUN eurjchem-101 23 102 . . PUNCT eurjchem-101 23 103         SPACE eurjchem-101 24 1 3.2 3.2 NUM eurjchem-101 24 2 . . PUNCT eurjchem-101 24 3     SPACE eurjchem-101 24 4 stabilization stabilization NOUN eurjchem-101 24 5     SPACE eurjchem-101 24 6 of of ADP eurjchem-101 24 7     SPACE eurjchem-101 24 8 5­ala 5­ala NUM eurjchem-101 24 9     SPACE eurjchem-101 24 10 by by ADP eurjchem-101 24 11     SPACE eurjchem-101 24 12 zinc(ii zinc(ii NUM eurjchem-101 24 13 ) ) PUNCT eurjchem-101 24 14     SPACE eurjchem-101 24 15 ion ion NOUN eurjchem-101 24 16           SPACE eurjchem-101 24 17 the the DET eurjchem-101 24 18     SPACE eurjchem-101 24 19 effect effect NOUN eurjchem-101 24 20     SPACE eurjchem-101 24 21 of of ADP eurjchem-101 24 22     SPACE eurjchem-101 24 23 zinc(ii zinc(ii NUM eurjchem-101 24 24 ) ) PUNCT eurjchem-101 24 25     SPACE eurjchem-101 24 26 ion ion NOUN eurjchem-101 24 27     SPACE eurjchem-101 24 28 on on ADP eurjchem-101 24 29     SPACE eurjchem-101 24 30 the the DET eurjchem-101 24 31     SPACE eurjchem-101 24 32 auto‐condensation auto‐condensation NOUN eurjchem-101 24 33     SPACE eurjchem-101 24 34 of of ADP eurjchem-101 24 35     SPACE eurjchem-101 24 36 5‐ala 5‐ala NUM eurjchem-101 24 37     SPACE eurjchem-101 24 38 was be AUX eurjchem-101 24 39     SPACE eurjchem-101 24 40 examined examine VERB eurjchem-101 24 41     SPACE eurjchem-101 24 42 by by ADP eurjchem-101 24 43     SPACE eurjchem-101 24 44 the the DET eurjchem-101 24 45     SPACE eurjchem-101 24 46 method method NOUN eurjchem-101 24 47     SPACE eurjchem-101 24 48 described describe VERB eurjchem-101 24 49     SPACE eurjchem-101 24 50 in in ADP eurjchem-101 24 51     SPACE eurjchem-101 24 52 section section NOUN eurjchem-101 24 53     SPACE eurjchem-101 24 54 3.1 3.1 NUM eurjchem-101 24 55 . . PUNCT eurjchem-101 24 56     SPACE eurjchem-101 24 57 in in ADP eurjchem-101 24 58     SPACE eurjchem-101 24 59 the the DET eurjchem-101 24 60     SPACE eurjchem-101 24 61 presence presence NOUN eurjchem-101 24 62     SPACE eurjchem-101 24 63 of of ADP eurjchem-101 24 64     SPACE eurjchem-101 24 65 zncl2 zncl2 NOUN eurjchem-101 24 66     SPACE eurjchem-101 24 67 in in ADP eurjchem-101 24 68     SPACE eurjchem-101 24 69 the the DET eurjchem-101 24 70     SPACE eurjchem-101 24 71 molar molar ADJ eurjchem-101 24 72     SPACE eurjchem-101 24 73 ratio ratio NOUN eurjchem-101 24 74     SPACE eurjchem-101 24 75 of of ADP eurjchem-101 24 76     SPACE eurjchem-101 24 77 5‐ala 5‐ala NUM eurjchem-101 24 78 : : PUNCT eurjchem-101 24 79 zncl2 zncl2 NOUN eurjchem-101 24 80     SPACE eurjchem-101 24 81 ( ( PUNCT eurjchem-101 24 82 2:1 2:1 NUM eurjchem-101 24 83 ) ) PUNCT eurjchem-101 24 84 , , PUNCT eurjchem-101 24 85     SPACE eurjchem-101 24 86 the the DET eurjchem-101 24 87     SPACE eurjchem-101 24 88 rate rate NOUN eurjchem-101 24 89     SPACE eurjchem-101 24 90 of of ADP eurjchem-101 24 91     SPACE eurjchem-101 24 92 pdpa pdpa NOUN eurjchem-101 24 93     SPACE eurjchem-101 24 94 formation formation NOUN eurjchem-101 24 95     SPACE eurjchem-101 24 96 decrease decrease NOUN eurjchem-101 24 97     SPACE eurjchem-101 24 98 to to ADP eurjchem-101 24 99     SPACE eurjchem-101 24 100 about about ADV eurjchem-101 24 101     SPACE eurjchem-101 24 102 15 15 NUM eurjchem-101 24 103 % % NOUN eurjchem-101 24 104     SPACE eurjchem-101 24 105 ( ( PUNCT eurjchem-101 24 106 figure figure NOUN eurjchem-101 24 107     SPACE eurjchem-101 24 108 3 3 NUM eurjchem-101 24 109 ) ) PUNCT eurjchem-101 24 110     SPACE eurjchem-101 25 1 [ [ X eurjchem-101 25 2 slope slope NOUN eurjchem-101 25 3     SPACE eurjchem-101 25 4 of of ADP eurjchem-101 25 5     SPACE eurjchem-101 25 6 absorbance absorbance NOUN eurjchem-101 25 7     SPACE eurjchem-101 25 8 at at ADP eurjchem-101 25 9     SPACE eurjchem-101 25 10 275 275 NUM eurjchem-101 25 11     SPACE eurjchem-101 25 12 nm nm NOUN eurjchem-101 25 13 : : PUNCT eurjchem-101 25 14     SPACE eurjchem-101 25 15 2.5 2.5 NUM eurjchem-101 25 16     SPACE eurjchem-101 25 17 × × NOUN eurjchem-101 25 18     SPACE eurjchem-101 25 19 10‐2 10‐2 NUM eurjchem-101 25 20     SPACE eurjchem-101 25 21 min‐1 min‐1 NOUN eurjchem-101 25 22     SPACE eurjchem-101 25 23 in in ADP eurjchem-101 25 24     SPACE eurjchem-101 25 25 figure figure NOUN eurjchem-101 25 26     SPACE eurjchem-101 25 27 3 3 NUM eurjchem-101 25 28     SPACE eurjchem-101 25 29 and and CCONJ eurjchem-101 25 30     SPACE eurjchem-101 25 31 1.7 1.7 NUM eurjchem-101 25 32     SPACE eurjchem-101 25 33 × × NOUN eurjchem-101 25 34     SPACE eurjchem-101 25 35 10‐1 10‐1 NUM eurjchem-101 25 36     SPACE eurjchem-101 25 37 min‐1 min‐1 NOUN eurjchem-101 25 38     SPACE eurjchem-101 25 39 in in ADP eurjchem-101 25 40     SPACE eurjchem-101 25 41 figure figure NOUN eurjchem-101 25 42     SPACE eurjchem-101 25 43 1 1 NUM eurjchem-101 25 44 ] ] PUNCT eurjchem-101 25 45 . . PUNCT eurjchem-101 25 46         SPACE eurjchem-101 26 1 it it PRON eurjchem-101 26 2     SPACE eurjchem-101 26 3 is be AUX eurjchem-101 26 4     SPACE eurjchem-101 26 5 noteworthy noteworthy ADJ eurjchem-101 26 6     SPACE eurjchem-101 26 7 that that SCONJ eurjchem-101 26 8     SPACE eurjchem-101 26 9 the the DET eurjchem-101 26 10     SPACE eurjchem-101 26 11 subtle subtle ADJ eurjchem-101 26 12     SPACE eurjchem-101 26 13 precipitation precipitation NOUN eurjchem-101 26 14     SPACE eurjchem-101 26 15 of of ADP eurjchem-101 26 16     SPACE eurjchem-101 26 17 zinc zinc NOUN eurjchem-101 26 18     SPACE eurjchem-101 26 19 hydroxide hydroxide NOUN eurjchem-101 26 20     SPACE eurjchem-101 26 21 caused cause VERB eurjchem-101 26 22     SPACE eurjchem-101 26 23 an an DET eurjchem-101 26 24     SPACE eurjchem-101 26 25 increase increase NOUN eurjchem-101 26 26     SPACE eurjchem-101 26 27 in in ADP eurjchem-101 26 28     SPACE eurjchem-101 26 29 the the DET eurjchem-101 26 30     SPACE eurjchem-101 26 31 absorbance absorbance NOUN eurjchem-101 26 32     SPACE eurjchem-101 26 33 in in ADP eurjchem-101 26 34     SPACE eurjchem-101 26 35 a a DET eurjchem-101 26 36     SPACE eurjchem-101 26 37 wide wide ADJ eurjchem-101 26 38     SPACE eurjchem-101 26 39 wave‐length wave‐length NOUN eurjchem-101 26 40     SPACE eurjchem-101 26 41 range range NOUN eurjchem-101 26 42     SPACE eurjchem-101 26 43 just just ADV eurjchem-101 26 44     SPACE eurjchem-101 26 45 after after ADP eurjchem-101 26 46     SPACE eurjchem-101 26 47 preparing prepare VERB eurjchem-101 26 48     SPACE eurjchem-101 26 49 the the DET eurjchem-101 26 50     SPACE eurjchem-101 26 51 solution solution NOUN eurjchem-101 26 52 , , PUNCT eurjchem-101 26 53     SPACE eurjchem-101 26 54 but but CCONJ eurjchem-101 26 55     SPACE eurjchem-101 26 56 this this PRON eurjchem-101 26 57     SPACE eurjchem-101 26 58 disappeared disappear VERB eurjchem-101 26 59     SPACE eurjchem-101 26 60 within within ADP eurjchem-101 26 61     SPACE eurjchem-101 26 62 several several ADJ eurjchem-101 26 63     SPACE eurjchem-101 26 64 hours hour NOUN eurjchem-101 26 65 . . PUNCT eurjchem-101 26 66     SPACE eurjchem-101 26 67 when when SCONJ eurjchem-101 26 68     SPACE eurjchem-101 26 69 zncl2 zncl2 PRON eurjchem-101 26 70     SPACE eurjchem-101 26 71 was be AUX eurjchem-101 26 72     SPACE eurjchem-101 26 73 added add VERB eurjchem-101 26 74     SPACE eurjchem-101 26 75 to to ADP eurjchem-101 26 76     SPACE eurjchem-101 26 77 a a DET eurjchem-101 26 78     SPACE eurjchem-101 26 79 5‐ala 5‐ala NUM eurjchem-101 26 80     SPACE eurjchem-101 26 81 solution solution NOUN eurjchem-101 26 82     SPACE eurjchem-101 26 83 in in ADP eurjchem-101 26 84     SPACE eurjchem-101 26 85 a a DET eurjchem-101 26 86     SPACE eurjchem-101 26 87 1 1 NUM eurjchem-101 26 88 : : PUNCT eurjchem-101 26 89     SPACE eurjchem-101 26 90 1 1 NUM eurjchem-101 26 91     SPACE eurjchem-101 26 92 molar molar ADJ eurjchem-101 26 93     SPACE eurjchem-101 26 94 ratio ratio NOUN eurjchem-101 26 95 , , PUNCT eurjchem-101 26 96     SPACE eurjchem-101 26 97 the the DET eurjchem-101 26 98     SPACE eurjchem-101 26 99 rate rate NOUN eurjchem-101 26 100     SPACE eurjchem-101 26 101 of of ADP eurjchem-101 26 102     SPACE eurjchem-101 26 103 pdpa pdpa NOUN eurjchem-101 26 104     SPACE eurjchem-101 26 105 formation formation NOUN eurjchem-101 26 106     SPACE eurjchem-101 26 107 became become VERB eurjchem-101 26 108     SPACE eurjchem-101 26 109 less less ADJ eurjchem-101 26 110     SPACE eurjchem-101 26 111 than than ADP eurjchem-101 26 112     SPACE eurjchem-101 26 113 5 5 NUM eurjchem-101 26 114 % % NOUN eurjchem-101 26 115     SPACE eurjchem-101 26 116 ( ( PUNCT eurjchem-101 26 117 figure figure NOUN eurjchem-101 26 118     SPACE eurjchem-101 26 119 4 4 NUM eurjchem-101 26 120 ) ) PUNCT eurjchem-101 26 121     SPACE eurjchem-101 27 1 [ [ X eurjchem-101 27 2 slope slope NOUN eurjchem-101 27 3     SPACE eurjchem-101 27 4 of of ADP eurjchem-101 27 5     SPACE eurjchem-101 27 6 absorbance absorbance NOUN eurjchem-101 27 7     SPACE eurjchem-101 27 8 at at ADP eurjchem-101 27 9     SPACE eurjchem-101 27 10 275 275 NUM eurjchem-101 27 11     SPACE eurjchem-101 27 12 nm nm NOUN eurjchem-101 27 13 : : PUNCT eurjchem-101 27 14     SPACE eurjchem-101 27 15 7.1 7.1 NUM eurjchem-101 27 16     SPACE eurjchem-101 27 17 × × NOUN eurjchem-101 27 18     SPACE eurjchem-101 27 19 10‐3 10‐3 NUM eurjchem-101 27 20     SPACE eurjchem-101 27 21 min‐1 min‐1 NOUN eurjchem-101 27 22     SPACE eurjchem-101 27 23 in in ADP eurjchem-101 27 24     SPACE eurjchem-101 27 25 figure figure NOUN eurjchem-101 27 26     SPACE eurjchem-101 27 27 4 4 NUM eurjchem-101 27 28 ] ] PUNCT eurjchem-101 27 29 . . PUNCT eurjchem-101 27 30     SPACE eurjchem-101 28 1 the the DET eurjchem-101 28 2     SPACE eurjchem-101 28 3 formation formation NOUN eurjchem-101 28 4     SPACE eurjchem-101 28 5 of of ADP eurjchem-101 28 6     SPACE eurjchem-101 28 7 hpdpa hpdpa NOUN eurjchem-101 28 8     SPACE eurjchem-101 28 9 and and CCONJ eurjchem-101 28 10     SPACE eurjchem-101 28 11 pdpa pdpa NOUN eurjchem-101 28 12     SPACE eurjchem-101 28 13 was be AUX eurjchem-101 28 14     SPACE eurjchem-101 28 15 significantly significantly ADV eurjchem-101 28 16     SPACE eurjchem-101 28 17 inhibited inhibit VERB eurjchem-101 28 18     SPACE eurjchem-101 28 19 by by ADP eurjchem-101 28 20     SPACE eurjchem-101 28 21 the the DET eurjchem-101 28 22     SPACE eurjchem-101 28 23 zinc(ii zinc(ii NUM eurjchem-101 28 24 ) ) PUNCT eurjchem-101 28 25     SPACE eurjchem-101 28 26 ion ion NOUN eurjchem-101 28 27 , , PUNCT eurjchem-101 28 28     SPACE eurjchem-101 28 29 and and CCONJ eurjchem-101 28 30     SPACE eurjchem-101 28 31 we we PRON eurjchem-101 28 32     SPACE eurjchem-101 28 33 can can AUX eurjchem-101 28 34     SPACE eurjchem-101 28 35 conclude conclude VERB eurjchem-101 28 36     SPACE eurjchem-101 28 37 that that SCONJ eurjchem-101 28 38     SPACE eurjchem-101 28 39 the the DET eurjchem-101 28 40     SPACE eurjchem-101 28 41 zinc(ii zinc(ii NUM eurjchem-101 28 42 ) ) PUNCT eurjchem-101 28 43     SPACE eurjchem-101 28 44 ion ion NOUN eurjchem-101 28 45     SPACE eurjchem-101 28 46 stabilizes stabilize VERB eurjchem-101 28 47     SPACE eurjchem-101 28 48 5‐ala 5‐ala NUM eurjchem-101 28 49     SPACE eurjchem-101 28 50 in in ADP eurjchem-101 28 51     SPACE eurjchem-101 28 52 solution solution NOUN eurjchem-101 28 53 . . PUNCT eurjchem-101 28 54     SPACE eurjchem-101 29 1 the the DET eurjchem-101 29 2     SPACE eurjchem-101 29 3 stabilization stabilization NOUN eurjchem-101 29 4     SPACE eurjchem-101 29 5 effect effect NOUN eurjchem-101 29 6     SPACE eurjchem-101 29 7 of of ADP eurjchem-101 29 8     SPACE eurjchem-101 29 9 the the DET eurjchem-101 29 10     SPACE eurjchem-101 29 11 zinc(ii zinc(ii NUM eurjchem-101 29 12 ) ) PUNCT eurjchem-101 29 13     SPACE eurjchem-101 29 14 ion ion NOUN eurjchem-101 29 15     SPACE eurjchem-101 29 16 was be AUX eurjchem-101 29 17     SPACE eurjchem-101 29 18 also also ADV eurjchem-101 29 19     SPACE eurjchem-101 29 20 ascertained ascertain VERB eurjchem-101 29 21     SPACE eurjchem-101 29 22 by by ADP eurjchem-101 29 23     SPACE eurjchem-101 29 24 1h 1h NUM eurjchem-101 29 25     SPACE eurjchem-101 29 26 and and CCONJ eurjchem-101 29 27     SPACE eurjchem-101 29 28 13c 13c NOUN eurjchem-101 29 29     SPACE eurjchem-101 29 30 nmr nmr NOUN eurjchem-101 29 31     SPACE eurjchem-101 29 32 ( ( PUNCT eurjchem-101 29 33 figure figure NOUN eurjchem-101 29 34     SPACE eurjchem-101 29 35 5 5 NUM eurjchem-101 29 36     SPACE eurjchem-101 29 37 and and CCONJ eurjchem-101 29 38     SPACE eurjchem-101 29 39 6 6 NUM eurjchem-101 29 40 ) ) PUNCT eurjchem-101 29 41 . . PUNCT eurjchem-101 29 42     SPACE eurjchem-101 30 1 without without ADP eurjchem-101 30 2     SPACE eurjchem-101 30 3 the the DET eurjchem-101 30 4     SPACE eurjchem-101 30 5 zinc(ii zinc(ii NUM eurjchem-101 30 6 ) ) PUNCT eurjchem-101 30 7     SPACE eurjchem-101 30 8 ions ion NOUN eurjchem-101 30 9 , , PUNCT eurjchem-101 30 10     SPACE eurjchem-101 30 11 the the DET eurjchem-101 30 12     SPACE eurjchem-101 30 13 signals signal NOUN eurjchem-101 30 14     SPACE eurjchem-101 30 15 of of ADP eurjchem-101 30 16     SPACE eurjchem-101 30 17 5‐ala 5‐ala NUM eurjchem-101 30 18     SPACE eurjchem-101 30 19 [ [ X eurjchem-101 30 20 1h 1h NUM eurjchem-101 30 21     SPACE eurjchem-101 30 22 nmr nmr NOUN eurjchem-101 30 23 : : PUNCT eurjchem-101 30 24     SPACE eurjchem-101 30 25 δ δ PROPN eurjchem-101 30 26     SPACE eurjchem-101 30 27 = = NOUN eurjchem-101 30 28     SPACE eurjchem-101 30 29 2.71 2.71 NUM eurjchem-101 30 30     SPACE eurjchem-101 30 31 ( ( PUNCT eurjchem-101 30 32 t t PROPN eurjchem-101 30 33 , , PUNCT eurjchem-101 30 34     SPACE eurjchem-101 30 35 2h 2h NUM eurjchem-101 30 36 ) ) PUNCT eurjchem-101 30 37 ; ; PUNCT eurjchem-101 30 38     SPACE eurjchem-101 30 39 2.90 2.90 NUM eurjchem-101 30 40     SPACE eurjchem-101 30 41 ( ( PUNCT eurjchem-101 30 42 t t PROPN eurjchem-101 30 43 , , PUNCT eurjchem-101 30 44     SPACE eurjchem-101 30 45 2h 2h NUM eurjchem-101 30 46 ) ) PUNCT eurjchem-101 30 47 ; ; PUNCT eurjchem-101 30 48     SPACE eurjchem-101 30 49 4.13 4.13 NUM eurjchem-101 30 50     SPACE eurjchem-101 30 51 ( ( PUNCT eurjchem-101 30 52 s s PROPN eurjchem-101 30 53 , , PUNCT eurjchem-101 30 54     SPACE eurjchem-101 30 55 2h 2h NUM eurjchem-101 30 56 ) ) PUNCT eurjchem-101 30 57     SPACE eurjchem-101 30 58 ppm ppm NOUN eurjchem-101 30 59 ; ; PUNCT eurjchem-101 30 60     SPACE eurjchem-101 30 61 13c 13c NOUN eurjchem-101 30 62     SPACE eurjchem-101 30 63 nmr nmr NOUN eurjchem-101 30 64 : : PUNCT eurjchem-101 30 65     SPACE eurjchem-101 30 66 δ δ PROPN eurjchem-101 30 67     SPACE eurjchem-101 30 68 = = NOUN eurjchem-101 30 69     SPACE eurjchem-101 30 70 30.4 30.4 NUM eurjchem-101 30 71 ; ; PUNCT eurjchem-101 30 72     SPACE eurjchem-101 30 73 37.3 37.3 NUM eurjchem-101 30 74 ; ; PUNCT eurjchem-101 30 75     SPACE eurjchem-101 30 76 50.0 50.0 NUM eurjchem-101 30 77 ; ; PUNCT eurjchem-101 30 78     SPACE eurjchem-101 30 79 179.8 179.8 NUM eurjchem-101 30 80 ; ; PUNCT eurjchem-101 30 81     SPACE eurjchem-101 30 82 207.0 207.0 NUM eurjchem-101 30 83     SPACE eurjchem-101 30 84 ppm ppm NOUN eurjchem-101 30 85 ] ] PUNCT eurjchem-101 30 86     SPACE eurjchem-101 30 87 disappeared disappear VERB eurjchem-101 30 88 , , PUNCT eurjchem-101 30 89     SPACE eurjchem-101 30 90 and and CCONJ eurjchem-101 30 91     SPACE eurjchem-101 30 92 the the DET eurjchem-101 30 93     SPACE eurjchem-101 30 94 signals signal NOUN eurjchem-101 30 95     SPACE eurjchem-101 30 96 of of ADP eurjchem-101 30 97     SPACE eurjchem-101 30 98 hpdpa hpdpa PROPN eurjchem-101 30 99     SPACE eurjchem-101 31 1 [ [ X eurjchem-101 31 2 1h 1h NUM eurjchem-101 31 3     SPACE eurjchem-101 31 4 nmr nmr NOUN eurjchem-101 31 5 : : PUNCT eurjchem-101 31 6     SPACE eurjchem-101 31 7 δ δ PROPN eurjchem-101 31 8     SPACE eurjchem-101 31 9 = = NOUN eurjchem-101 31 10     SPACE eurjchem-101 31 11 2.40 2.40 NUM eurjchem-101 31 12     SPACE eurjchem-101 31 13 ( ( PUNCT eurjchem-101 31 14 s s PROPN eurjchem-101 31 15 , , PUNCT eurjchem-101 31 16     SPACE eurjchem-101 31 17 2h 2h NUM eurjchem-101 31 18 ) ) PUNCT eurjchem-101 31 19 ; ; PUNCT eurjchem-101 31 20     SPACE eurjchem-101 31 21 2.42 2.42 NUM eurjchem-101 31 22     SPACE eurjchem-101 31 23 ( ( PUNCT eurjchem-101 31 24 t t PROPN eurjchem-101 31 25 , , PUNCT eurjchem-101 31 26     SPACE eurjchem-101 31 27 2h 2h NUM eurjchem-101 31 28 ) ) PUNCT eurjchem-101 31 29 ; ; PUNCT eurjchem-101 31 30     SPACE eurjchem-101 31 31 2.57 2.57 NUM eurjchem-101 31 32     SPACE eurjchem-101 31 33 ( ( PUNCT eurjchem-101 31 34 t t PROPN eurjchem-101 31 35 , , PUNCT eurjchem-101 31 36     SPACE eurjchem-101 31 37 2h 2h NUM eurjchem-101 31 38 ) ) PUNCT eurjchem-101 31 39     SPACE eurjchem-101 31 40 ppm ppm NOUN eurjchem-101 31 41 ; ; PUNCT eurjchem-101 31 42     SPACE eurjchem-101 31 43 13c 13c NOUN eurjchem-101 31 44     SPACE eurjchem-101 31 45 nmr nmr NOUN eurjchem-101 31 46 : : PUNCT eurjchem-101 31 47     SPACE eurjchem-101 31 48 δ δ PROPN eurjchem-101 31 49     SPACE eurjchem-101 31 50 = = NOUN eurjchem-101 31 51     SPACE eurjchem-101 31 52 36.2 36.2 NUM eurjchem-101 31 53 ; ; PUNCT eurjchem-101 31 54     SPACE eurjchem-101 31 55 36.2 36.2 NUM eurjchem-101 31 56 ; ; PUNCT eurjchem-101 31 57     SPACE eurjchem-101 31 58 36.3 36.3 NUM eurjchem-101 31 59 ; ; PUNCT eurjchem-101 31 60     SPACE eurjchem-101 31 61 175.8 175.8 NUM eurjchem-101 31 62 ; ; PUNCT eurjchem-101 31 63     SPACE eurjchem-101 31 64 184.5 184.5 NUM eurjchem-101 31 65     SPACE eurjchem-101 31 66 ppm ppm NOUN eurjchem-101 31 67 ] ] PUNCT eurjchem-101 31 68     SPACE eurjchem-101 31 69 appeared appear VERB eurjchem-101 31 70 ; ; PUNCT eurjchem-101 31 71     SPACE eurjchem-101 31 72 however however ADV eurjchem-101 31 73 , , PUNCT eurjchem-101 31 74     SPACE eurjchem-101 31 75 with with ADP eurjchem-101 31 76     SPACE eurjchem-101 31 77 zinc(ii zinc(ii NUM eurjchem-101 31 78 ) ) PUNCT eurjchem-101 31 79     SPACE eurjchem-101 31 80 ions ion NOUN eurjchem-101 31 81     SPACE eurjchem-101 31 82 ( ( PUNCT eurjchem-101 31 83 5‐ala 5‐ala NUM eurjchem-101 31 84 : : PUNCT eurjchem-101 31 85 zncl zncl NOUN eurjchem-101 31 86 , , PUNCT eurjchem-101 31 87     SPACE eurjchem-101 31 88 1:1 1:1 NUM eurjchem-101 31 89 ) ) PUNCT eurjchem-101 31 90 , , PUNCT eurjchem-101 31 91     SPACE eurjchem-101 31 92 the the DET eurjchem-101 31 93     SPACE eurjchem-101 31 94 signals signal NOUN eurjchem-101 31 95     SPACE eurjchem-101 31 96 of of ADP eurjchem-101 31 97     SPACE eurjchem-101 31 98 5‐ala 5‐ala NUM eurjchem-101 31 99     SPACE eurjchem-101 31 100 remained remain VERB eurjchem-101 31 101 , , PUNCT eurjchem-101 31 102     SPACE eurjchem-101 31 103 and and CCONJ eurjchem-101 31 104     SPACE eurjchem-101 31 105 a a DET eurjchem-101 31 106     SPACE eurjchem-101 31 107 small small ADJ eurjchem-101 31 108     SPACE eurjchem-101 31 109 amount amount NOUN eurjchem-101 31 110     SPACE eurjchem-101 31 111 of of ADP eurjchem-101 31 112     SPACE eurjchem-101 31 113 hpdpa hpdpa NOUN eurjchem-101 31 114     SPACE eurjchem-101 31 115 was be AUX eurjchem-101 31 116     SPACE eurjchem-101 31 117 observed observe VERB eurjchem-101 31 118     SPACE eurjchem-101 32 1 [ [ X eurjchem-101 32 2 1h 1h NUM eurjchem-101 32 3     SPACE eurjchem-101 32 4 nmr nmr NOUN eurjchem-101 32 5 : : PUNCT eurjchem-101 32 6     SPACE eurjchem-101 32 7 δ δ PROPN eurjchem-101 32 8     SPACE eurjchem-101 32 9 = = NOUN eurjchem-101 32 10     SPACE eurjchem-101 32 11 2.51 2.51 NUM eurjchem-101 32 12     SPACE eurjchem-101 32 13 ( ( PUNCT eurjchem-101 32 14 t t PROPN eurjchem-101 32 15 , , PUNCT eurjchem-101 32 16     SPACE eurjchem-101 32 17 2h 2h NUM eurjchem-101 32 18 ) ) PUNCT eurjchem-101 32 19 ; ; PUNCT eurjchem-101 32 20     SPACE eurjchem-101 32 21 2.81 2.81 NUM eurjchem-101 32 22     SPACE eurjchem-101 32 23 ( ( PUNCT eurjchem-101 32 24 t t PROPN eurjchem-101 32 25 , , PUNCT eurjchem-101 32 26     SPACE eurjchem-101 32 27 2h 2h NUM eurjchem-101 32 28 ) ) PUNCT eurjchem-101 32 29 ; ; PUNCT eurjchem-101 32 30     SPACE eurjchem-101 32 31 4.09 4.09 NUM eurjchem-101 32 32     SPACE eurjchem-101 32 33 ( ( PUNCT eurjchem-101 32 34 s s PROPN eurjchem-101 32 35 , , PUNCT eurjchem-101 32 36     SPACE eurjchem-101 32 37 ~1.1h ~1.1h NUM eurjchem-101 32 38 ) ) PUNCT eurjchem-101 32 39     SPACE eurjchem-101 32 40 ppm ppm NOUN eurjchem-101 32 41 ; ; PUNCT eurjchem-101 32 42     SPACE eurjchem-101 32 43 13c 13c NOUN eurjchem-101 32 44     SPACE eurjchem-101 32 45 nmr nmr NOUN eurjchem-101 32 46 : : PUNCT eurjchem-101 32 47     SPACE eurjchem-101 32 48 δ δ PROPN eurjchem-101 32 49     SPACE eurjchem-101 32 50 = = NOUN eurjchem-101 32 51     SPACE eurjchem-101 32 52 33.5 33.5 NUM eurjchem-101 32 53 ; ; PUNCT eurjchem-101 32 54     SPACE eurjchem-101 32 55 36.08 36.08 NUM eurjchem-101 32 56     SPACE eurjchem-101 32 57 ( ( PUNCT eurjchem-101 32 58 hpdpa hpdpa PROPN eurjchem-101 32 59 ) ) PUNCT eurjchem-101 32 60 ; ; PUNCT eurjchem-101 32 61     SPACE eurjchem-101 32 62 38.8 38.8 NUM eurjchem-101 32 63 ; ; PUNCT eurjchem-101 32 64     SPACE eurjchem-101 32 65 50.2 50.2 NUM eurjchem-101 32 66 ; ; PUNCT eurjchem-101 32 67     SPACE eurjchem-101 32 68 183.9 183.9 NUM eurjchem-101 32 69 ; ; PUNCT eurjchem-101 32 70     SPACE eurjchem-101 32 71 208.9 208.9 NUM eurjchem-101 32 72     SPACE eurjchem-101 32 73 ppm ppm NOUN eurjchem-101 32 74 ] ] PUNCT eurjchem-101 32 75 . . PUNCT eurjchem-101 32 76     SPACE eurjchem-101 33 1 in in ADP eurjchem-101 33 2     SPACE eurjchem-101 33 3 the the DET eurjchem-101 33 4     SPACE eurjchem-101 33 5 1h 1h NUM eurjchem-101 33 6     SPACE eurjchem-101 33 7 nmr nmr NOUN eurjchem-101 33 8     SPACE eurjchem-101 33 9 in in ADP eurjchem-101 33 10     SPACE eurjchem-101 33 11 the the DET eurjchem-101 33 12     SPACE eurjchem-101 33 13 presence presence NOUN eurjchem-101 33 14     SPACE eurjchem-101 33 15 of of ADP eurjchem-101 33 16     SPACE eurjchem-101 33 17 zinc(ii zinc(ii NUM eurjchem-101 33 18 ) ) PUNCT eurjchem-101 33 19     SPACE eurjchem-101 33 20 ions ion NOUN eurjchem-101 33 21     SPACE eurjchem-101 33 22 ( ( PUNCT eurjchem-101 33 23 figure figure NOUN eurjchem-101 33 24     SPACE eurjchem-101 33 25 5c 5c NUM eurjchem-101 33 26 ) ) PUNCT eurjchem-101 33 27 , , PUNCT eurjchem-101 33 28     SPACE eurjchem-101 33 29 the the DET eurjchem-101 33 30     SPACE eurjchem-101 33 31 integrated integrated ADJ eurjchem-101 33 32     SPACE eurjchem-101 33 33 intensity intensity NOUN eurjchem-101 33 34     SPACE eurjchem-101 33 35 of of ADP eurjchem-101 33 36     SPACE eurjchem-101 33 37 the the DET eurjchem-101 33 38     SPACE eurjchem-101 33 39 δ‐methylene δ‐methylene NOUN eurjchem-101 33 40     SPACE eurjchem-101 33 41 protons proton NOUN eurjchem-101 33 42     SPACE eurjchem-101 33 43 was be AUX eurjchem-101 33 44     SPACE eurjchem-101 33 45 smaller small ADJ eurjchem-101 33 46     SPACE eurjchem-101 33 47 than than SCONJ eurjchem-101 33 48     SPACE eurjchem-101 33 49 expected expect VERB eurjchem-101 33 50 ; ; PUNCT eurjchem-101 33 51     SPACE eurjchem-101 33 52 this this PRON eurjchem-101 33 53     SPACE eurjchem-101 33 54 may may AUX eurjchem-101 33 55     SPACE eurjchem-101 33 56 be be AUX eurjchem-101 33 57     SPACE eurjchem-101 33 58 explained explain VERB eurjchem-101 33 59     SPACE eurjchem-101 33 60 by by ADP eurjchem-101 33 61     SPACE eurjchem-101 33 62 the the DET eurjchem-101 33 63     SPACE eurjchem-101 33 64 d‐h d‐h PROPN eurjchem-101 33 65     SPACE eurjchem-101 33 66 exchange exchange NOUN eurjchem-101 33 67     SPACE eurjchem-101 33 68 through through ADP eurjchem-101 33 69     SPACE eurjchem-101 33 70 enolization enolization NOUN eurjchem-101 33 71     SPACE eurjchem-101 33 72 of of ADP eurjchem-101 33 73     SPACE eurjchem-101 33 74 5‐ala 5‐ala NUM eurjchem-101 33 75     SPACE eurjchem-101 33 76 in in ADP eurjchem-101 33 77     SPACE eurjchem-101 33 78 d2o d2o NOUN eurjchem-101 33 79     SPACE eurjchem-101 34 1 [ [ X eurjchem-101 34 2 2 2 NUM eurjchem-101 34 3 ] ] PUNCT eurjchem-101 34 4 . . PUNCT eurjchem-101 34 5     SPACE eurjchem-101 34 6 in in ADP eurjchem-101 34 7     SPACE eurjchem-101 34 8 the the DET eurjchem-101 34 9     SPACE eurjchem-101 34 10 presence presence NOUN eurjchem-101 34 11     SPACE eurjchem-101 34 12 of of ADP eurjchem-101 34 13     SPACE eurjchem-101 34 14 zinc(ii zinc(ii NUM eurjchem-101 34 15 ) ) PUNCT eurjchem-101 34 16     SPACE eurjchem-101 34 17 ions ion NOUN eurjchem-101 34 18 , , PUNCT eurjchem-101 34 19     SPACE eurjchem-101 34 20 the the DET eurjchem-101 34 21     SPACE eurjchem-101 34 22 1h 1h NUM eurjchem-101 34 23     SPACE eurjchem-101 34 24 nmr nmr NOUN eurjchem-101 34 25     SPACE eurjchem-101 34 26 signals signal NOUN eurjchem-101 34 27     SPACE eurjchem-101 34 28 shifted shift VERB eurjchem-101 34 29     SPACE eurjchem-101 34 30 downfield downfield NOUN eurjchem-101 34 31     SPACE eurjchem-101 34 32 as as ADP eurjchem-101 34 33     SPACE eurjchem-101 34 34 compared compare VERB eurjchem-101 34 35     SPACE eurjchem-101 34 36 with with ADP eurjchem-101 34 37     SPACE eurjchem-101 34 38 the the DET eurjchem-101 34 39     SPACE eurjchem-101 34 40 solution solution NOUN eurjchem-101 34 41     SPACE eurjchem-101 34 42 without without ADP eurjchem-101 34 43     SPACE eurjchem-101 34 44 zinc(ii zinc(ii NUM eurjchem-101 34 45 ) ) PUNCT eurjchem-101 34 46     SPACE eurjchem-101 34 47 ions ion NOUN eurjchem-101 34 48     SPACE eurjchem-101 34 49 at at ADP eurjchem-101 34 50     SPACE eurjchem-101 34 51 ph ph NOUN eurjchem-101 34 52     SPACE eurjchem-101 34 53 7 7 NUM eurjchem-101 34 54     SPACE eurjchem-101 34 55 ( ( PUNCT eurjchem-101 34 56 δ δ NOUN eurjchem-101 34 57     SPACE eurjchem-101 34 58 = = NOUN eurjchem-101 34 59     SPACE eurjchem-101 34 60 2.45 2.45 NUM eurjchem-101 34 61 ; ; PUNCT eurjchem-101 34 62     SPACE eurjchem-101 34 63 2.75 2.75 NUM eurjchem-101 34 64 ; ; PUNCT eurjchem-101 34 65     SPACE eurjchem-101 34 66 4.05 4.05 NUM eurjchem-101 34 67     SPACE eurjchem-101 34 68 ppm ppm NOUN eurjchem-101 34 69 ) ) PUNCT eurjchem-101 34 70     SPACE eurjchem-101 35 1 [ [ X eurjchem-101 35 2 2 2 NUM eurjchem-101 35 3 ] ] PUNCT eurjchem-101 35 4 ; ; PUNCT eurjchem-101 35 5     SPACE eurjchem-101 35 6 this this PRON eurjchem-101 35 7     SPACE eurjchem-101 35 8 may may AUX eurjchem-101 35 9     SPACE eurjchem-101 35 10 suggest suggest VERB eurjchem-101 35 11     SPACE eurjchem-101 35 12 the the DET eurjchem-101 35 13     SPACE eurjchem-101 35 14 coordination coordination NOUN eurjchem-101 35 15     SPACE eurjchem-101 35 16 of of ADP eurjchem-101 35 17     SPACE eurjchem-101 35 18 5‐ala 5‐ala NUM eurjchem-101 35 19     SPACE eurjchem-101 35 20 to to ADP eurjchem-101 35 21     SPACE eurjchem-101 35 22 the the DET eurjchem-101 35 23     SPACE eurjchem-101 35 24 zinc(ii zinc(ii NUM eurjchem-101 35 25 ) ) PUNCT eurjchem-101 35 26     SPACE eurjchem-101 35 27 ion ion NOUN eurjchem-101 35 28     SPACE eurjchem-101 35 29 to to PART eurjchem-101 35 30     SPACE eurjchem-101 35 31 form form VERB eurjchem-101 35 32     SPACE eurjchem-101 35 33 a a DET eurjchem-101 35 34     SPACE eurjchem-101 35 35 zinc(ii zinc(ii NUM eurjchem-101 35 36 ) ) PUNCT eurjchem-101 35 37     SPACE eurjchem-101 35 38 complex complex NOUN eurjchem-101 35 39 . . PUNCT eurjchem-101 35 40     SPACE eurjchem-101 35 41 sakiyama sakiyama PROPN eurjchem-101 35 42     SPACE eurjchem-101 35 43 et et NOUN eurjchem-101 35 44     SPACE eurjchem-101 35 45 al al PROPN eurjchem-101 35 46 . . PROPN eurjchem-101 35 47     SPACE eurjchem-101 35 48 / / SYM eurjchem-101 35 49     SPACE eurjchem-101 35 50 european european ADJ eurjchem-101 35 51     SPACE eurjchem-101 35 52 journal journal NOUN eurjchem-101 35 53     SPACE eurjchem-101 35 54 of of ADP eurjchem-101 35 55     SPACE eurjchem-101 35 56 chemistry chemistry NOUN eurjchem-101 35 57     SPACE eurjchem-101 35 58 1 1 NUM eurjchem-101 35 59     SPACE eurjchem-101 35 60 ( ( PUNCT eurjchem-101 35 61 4 4 NUM eurjchem-101 35 62 ) ) PUNCT eurjchem-101 35 63     SPACE eurjchem-101 35 64 ( ( PUNCT eurjchem-101 35 65 2010 2010 NUM eurjchem-101 35 66 ) ) PUNCT eurjchem-101 35 67     SPACE eurjchem-101 35 68 373­376 373­376 NUM eurjchem-101 35 69     SPACE eurjchem-101 35 70 375 375 NUM eurjchem-101 35 71             SPACE eurjchem-101 35 72 figure figure NOUN eurjchem-101 35 73     SPACE eurjchem-101 35 74 3 3 NUM eurjchem-101 35 75 . . PUNCT eurjchem-101 35 76     SPACE eurjchem-101 35 77 electronic electronic ADJ eurjchem-101 35 78     SPACE eurjchem-101 35 79 spectral spectral ADJ eurjchem-101 35 80     SPACE eurjchem-101 35 81 change change NOUN eurjchem-101 35 82     SPACE eurjchem-101 35 83 for for ADP eurjchem-101 35 84     SPACE eurjchem-101 35 85 an an DET eurjchem-101 35 86     SPACE eurjchem-101 35 87 aqueous aqueous ADJ eurjchem-101 35 88     SPACE eurjchem-101 35 89 5‐ala 5‐ala NUM eurjchem-101 35 90     SPACE eurjchem-101 35 91 solution solution NOUN eurjchem-101 35 92     SPACE eurjchem-101 35 93 in in ADP eurjchem-101 35 94     SPACE eurjchem-101 35 95 the the DET eurjchem-101 35 96     SPACE eurjchem-101 35 97 presence presence NOUN eurjchem-101 35 98     SPACE eurjchem-101 35 99 of of ADP eurjchem-101 35 100     SPACE eurjchem-101 35 101 zinc(ii zinc(ii NUM eurjchem-101 35 102 ) ) PUNCT eurjchem-101 35 103     SPACE eurjchem-101 35 104 ion ion NOUN eurjchem-101 35 105     SPACE eurjchem-101 35 106 ( ( PUNCT eurjchem-101 35 107 left leave VERB eurjchem-101 35 108 ) ) PUNCT eurjchem-101 35 109     SPACE eurjchem-101 35 110 and and CCONJ eurjchem-101 35 111     SPACE eurjchem-101 35 112 time time NOUN eurjchem-101 35 113     SPACE eurjchem-101 35 114 dependencies dependency NOUN eurjchem-101 35 115     SPACE eurjchem-101 35 116 of of ADP eurjchem-101 35 117     SPACE eurjchem-101 35 118 the the DET eurjchem-101 35 119     SPACE eurjchem-101 35 120 absorbance absorbance NOUN eurjchem-101 35 121     SPACE eurjchem-101 35 122 for for ADP eurjchem-101 35 123     SPACE eurjchem-101 35 124 the the DET eurjchem-101 35 125     SPACE eurjchem-101 35 126 solution solution NOUN eurjchem-101 35 127     SPACE eurjchem-101 35 128 at at ADP eurjchem-101 35 129     SPACE eurjchem-101 35 130 245 245 NUM eurjchem-101 35 131     SPACE eurjchem-101 35 132 nm nm VERB eurjchem-101 35 133     SPACE eurjchem-101 35 134 ( ( PUNCT eurjchem-101 35 135 ○ ○ PROPN eurjchem-101 35 136 ) ) PUNCT eurjchem-101 35 137     SPACE eurjchem-101 35 138 and and CCONJ eurjchem-101 35 139     SPACE eurjchem-101 35 140 275 275 NUM eurjchem-101 35 141     SPACE eurjchem-101 35 142 nm nm NOUN eurjchem-101 35 143     SPACE eurjchem-101 35 144 ( ( PUNCT eurjchem-101 35 145 δ δ PROPN eurjchem-101 35 146 ) ) PUNCT eurjchem-101 35 147     SPACE eurjchem-101 35 148 ( ( PUNCT eurjchem-101 35 149 right right ADJ eurjchem-101 35 150 ) ) PUNCT eurjchem-101 35 151 . . PUNCT eurjchem-101 35 152     SPACE eurjchem-101 36 1 conditions condition NOUN eurjchem-101 36 2 : : PUNCT eurjchem-101 36 3     SPACE eurjchem-101 36 4 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 36 5     SPACE eurjchem-101 36 6 ( ( PUNCT eurjchem-101 36 7 20 20 NUM eurjchem-101 36 8     SPACE eurjchem-101 36 9 μmol μmol NOUN eurjchem-101 36 10 ) ) PUNCT eurjchem-101 36 11 , , PUNCT eurjchem-101 36 12     SPACE eurjchem-101 36 13 zncl2 zncl2 NOUN eurjchem-101 36 14     SPACE eurjchem-101 36 15 ( ( PUNCT eurjchem-101 36 16 10 10 NUM eurjchem-101 36 17     SPACE eurjchem-101 36 18 μmol μmol NOUN eurjchem-101 36 19 ) ) PUNCT eurjchem-101 36 20 , , PUNCT eurjchem-101 36 21     SPACE eurjchem-101 36 22 and and CCONJ eurjchem-101 36 23     SPACE eurjchem-101 36 24 lioh lioh ADV eurjchem-101 36 25     SPACE eurjchem-101 36 26 ( ( PUNCT eurjchem-101 36 27 40 40 NUM eurjchem-101 36 28     SPACE eurjchem-101 36 29 μmol μmol NOUN eurjchem-101 36 30 ) ) PUNCT eurjchem-101 36 31     SPACE eurjchem-101 36 32 in in ADP eurjchem-101 36 33     SPACE eurjchem-101 36 34 5 5 NUM eurjchem-101 36 35     SPACE eurjchem-101 36 36 ml ml NOUN eurjchem-101 36 37     SPACE eurjchem-101 36 38 of of ADP eurjchem-101 36 39     SPACE eurjchem-101 36 40 water water NOUN eurjchem-101 36 41     SPACE eurjchem-101 36 42 under under ADP eurjchem-101 36 43     SPACE eurjchem-101 36 44 aerobic aerobic ADJ eurjchem-101 36 45     SPACE eurjchem-101 36 46 conditions condition NOUN eurjchem-101 36 47     SPACE eurjchem-101 36 48 at at ADP eurjchem-101 36 49     SPACE eurjchem-101 36 50 room room NOUN eurjchem-101 36 51     SPACE eurjchem-101 36 52 temperature temperature NOUN eurjchem-101 36 53     SPACE eurjchem-101 36 54 ( ( PUNCT eurjchem-101 36 55 ph ph VERB eurjchem-101 36 56     SPACE eurjchem-101 36 57 = = NOUN eurjchem-101 36 58     SPACE eurjchem-101 36 59 7.2 7.2 NUM eurjchem-101 36 60 ) ) PUNCT eurjchem-101 36 61 . . PUNCT eurjchem-101 36 62     SPACE eurjchem-101 37 1 measurements measurement NOUN eurjchem-101 37 2     SPACE eurjchem-101 37 3 were be AUX eurjchem-101 37 4     SPACE eurjchem-101 37 5 conducted conduct VERB eurjchem-101 37 6     SPACE eurjchem-101 37 7 for for ADP eurjchem-101 37 8     SPACE eurjchem-101 37 9 20 20 NUM eurjchem-101 37 10     SPACE eurjchem-101 37 11 hours hour NOUN eurjchem-101 37 12     SPACE eurjchem-101 37 13 at at ADP eurjchem-101 37 14     SPACE eurjchem-101 37 15 one‐hour one‐hour NUM eurjchem-101 37 16     SPACE eurjchem-101 37 17 intervals interval NOUN eurjchem-101 37 18 . . PUNCT eurjchem-101 37 19             SPACE eurjchem-101 37 20 figure figure NOUN eurjchem-101 37 21     SPACE eurjchem-101 37 22 4 4 NUM eurjchem-101 37 23 . . PUNCT eurjchem-101 37 24     SPACE eurjchem-101 37 25 electronic electronic ADJ eurjchem-101 37 26     SPACE eurjchem-101 37 27 spectral spectral ADJ eurjchem-101 37 28     SPACE eurjchem-101 37 29 change change NOUN eurjchem-101 37 30     SPACE eurjchem-101 37 31 for for ADP eurjchem-101 37 32     SPACE eurjchem-101 37 33 an an DET eurjchem-101 37 34     SPACE eurjchem-101 37 35 aqueous aqueous ADJ eurjchem-101 37 36     SPACE eurjchem-101 37 37 5‐ala 5‐ala NUM eurjchem-101 37 38     SPACE eurjchem-101 37 39 solution solution NOUN eurjchem-101 37 40     SPACE eurjchem-101 37 41 in in ADP eurjchem-101 37 42     SPACE eurjchem-101 37 43 the the DET eurjchem-101 37 44     SPACE eurjchem-101 37 45 presence presence NOUN eurjchem-101 37 46     SPACE eurjchem-101 37 47 of of ADP eurjchem-101 37 48     SPACE eurjchem-101 37 49 zinc(ii zinc(ii NUM eurjchem-101 37 50 ) ) PUNCT eurjchem-101 37 51     SPACE eurjchem-101 37 52 ion ion NOUN eurjchem-101 37 53     SPACE eurjchem-101 37 54 ( ( PUNCT eurjchem-101 37 55 left leave VERB eurjchem-101 37 56 ) ) PUNCT eurjchem-101 37 57     SPACE eurjchem-101 37 58 and and CCONJ eurjchem-101 37 59     SPACE eurjchem-101 37 60 time time NOUN eurjchem-101 37 61     SPACE eurjchem-101 37 62 dependencies dependency NOUN eurjchem-101 37 63     SPACE eurjchem-101 37 64 of of ADP eurjchem-101 37 65     SPACE eurjchem-101 37 66 the the DET eurjchem-101 37 67     SPACE eurjchem-101 37 68 absorbance absorbance NOUN eurjchem-101 37 69     SPACE eurjchem-101 37 70 for for ADP eurjchem-101 37 71     SPACE eurjchem-101 37 72 the the DET eurjchem-101 37 73     SPACE eurjchem-101 37 74 solution solution NOUN eurjchem-101 37 75     SPACE eurjchem-101 37 76 at at ADP eurjchem-101 37 77     SPACE eurjchem-101 37 78 245 245 NUM eurjchem-101 37 79     SPACE eurjchem-101 37 80 nm nm VERB eurjchem-101 37 81     SPACE eurjchem-101 37 82 ( ( PUNCT eurjchem-101 37 83 ○ ○ PROPN eurjchem-101 37 84 ) ) PUNCT eurjchem-101 37 85     SPACE eurjchem-101 37 86 and and CCONJ eurjchem-101 37 87     SPACE eurjchem-101 37 88 275 275 NUM eurjchem-101 37 89     SPACE eurjchem-101 37 90 nm nm NOUN eurjchem-101 37 91     SPACE eurjchem-101 37 92 ( ( PUNCT eurjchem-101 37 93 δ δ PROPN eurjchem-101 37 94 ) ) PUNCT eurjchem-101 37 95     SPACE eurjchem-101 37 96 ( ( PUNCT eurjchem-101 37 97 right right ADJ eurjchem-101 37 98 ) ) PUNCT eurjchem-101 37 99 . . PUNCT eurjchem-101 37 100     SPACE eurjchem-101 38 1 conditions condition NOUN eurjchem-101 38 2 : : PUNCT eurjchem-101 38 3     SPACE eurjchem-101 38 4 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 38 5     SPACE eurjchem-101 38 6 ( ( PUNCT eurjchem-101 38 7 20 20 NUM eurjchem-101 38 8     SPACE eurjchem-101 38 9 μmol μmol NOUN eurjchem-101 38 10 ) ) PUNCT eurjchem-101 38 11 , , PUNCT eurjchem-101 38 12     SPACE eurjchem-101 38 13 zncl2 zncl2 NOUN eurjchem-101 38 14     SPACE eurjchem-101 38 15 ( ( PUNCT eurjchem-101 38 16 20 20 NUM eurjchem-101 38 17     SPACE eurjchem-101 38 18 μmol μmol NOUN eurjchem-101 38 19 ) ) PUNCT eurjchem-101 38 20 , , PUNCT eurjchem-101 38 21     SPACE eurjchem-101 38 22 and and CCONJ eurjchem-101 38 23     SPACE eurjchem-101 38 24 lioh lioh ADV eurjchem-101 38 25     SPACE eurjchem-101 38 26 ( ( PUNCT eurjchem-101 38 27 40 40 NUM eurjchem-101 38 28     SPACE eurjchem-101 38 29 μmol μmol NOUN eurjchem-101 38 30 ) ) PUNCT eurjchem-101 38 31     SPACE eurjchem-101 38 32 in in ADP eurjchem-101 38 33     SPACE eurjchem-101 38 34 5 5 NUM eurjchem-101 38 35     SPACE eurjchem-101 38 36 ml ml NOUN eurjchem-101 38 37     SPACE eurjchem-101 38 38 of of ADP eurjchem-101 38 39     SPACE eurjchem-101 38 40 water water NOUN eurjchem-101 38 41     SPACE eurjchem-101 38 42 under under ADP eurjchem-101 38 43     SPACE eurjchem-101 38 44 aerobic aerobic ADJ eurjchem-101 38 45     SPACE eurjchem-101 38 46 conditions condition NOUN eurjchem-101 38 47     SPACE eurjchem-101 38 48 at at ADP eurjchem-101 38 49     SPACE eurjchem-101 38 50 room room NOUN eurjchem-101 38 51     SPACE eurjchem-101 38 52 temperature temperature NOUN eurjchem-101 38 53     SPACE eurjchem-101 38 54 ( ( PUNCT eurjchem-101 38 55 ph ph VERB eurjchem-101 38 56     SPACE eurjchem-101 38 57 = = NOUN eurjchem-101 38 58     SPACE eurjchem-101 38 59 6.7 6.7 NUM eurjchem-101 38 60 ) ) PUNCT eurjchem-101 38 61 . . PUNCT eurjchem-101 38 62     SPACE eurjchem-101 39 1 measurements measurement NOUN eurjchem-101 39 2     SPACE eurjchem-101 39 3 were be AUX eurjchem-101 39 4     SPACE eurjchem-101 39 5 conducted conduct VERB eurjchem-101 39 6     SPACE eurjchem-101 39 7 for for ADP eurjchem-101 39 8     SPACE eurjchem-101 39 9 20 20 NUM eurjchem-101 39 10     SPACE eurjchem-101 39 11 hours hour NOUN eurjchem-101 39 12     SPACE eurjchem-101 39 13 at at ADP eurjchem-101 39 14     SPACE eurjchem-101 39 15 one‐hour one‐hour NUM eurjchem-101 39 16     SPACE eurjchem-101 39 17 intervals interval NOUN eurjchem-101 39 18 . . PUNCT eurjchem-101 39 19             SPACE eurjchem-101 39 20 figure figure NOUN eurjchem-101 39 21     SPACE eurjchem-101 39 22 5 5 NUM eurjchem-101 39 23 . . PUNCT eurjchem-101 39 24     SPACE eurjchem-101 39 25 1h 1h NUM eurjchem-101 39 26     SPACE eurjchem-101 39 27 nmr nmr NOUN eurjchem-101 39 28     SPACE eurjchem-101 39 29 spectra spectra NOUN eurjchem-101 39 30     SPACE eurjchem-101 39 31 of of ADP eurjchem-101 39 32     SPACE eurjchem-101 39 33 5‐ala 5‐ala NUM eurjchem-101 39 34     SPACE eurjchem-101 39 35 in in ADP eurjchem-101 39 36     SPACE eurjchem-101 39 37 d2o d2o NOUN eurjchem-101 39 38 : : PUNCT eurjchem-101 39 39     SPACE eurjchem-101 39 40 ( ( PUNCT eurjchem-101 39 41 a a X eurjchem-101 39 42 ) ) PUNCT eurjchem-101 39 43     SPACE eurjchem-101 39 44 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 39 45 , , PUNCT eurjchem-101 39 46     SPACE eurjchem-101 39 47 ( ( PUNCT eurjchem-101 39 48 b b NOUN eurjchem-101 39 49 ) ) PUNCT eurjchem-101 39 50     SPACE eurjchem-101 39 51 neutralized neutralize VERB eurjchem-101 39 52     SPACE eurjchem-101 39 53 with with ADP eurjchem-101 39 54     SPACE eurjchem-101 39 55 lioh lioh ADV eurjchem-101 39 56 , , PUNCT eurjchem-101 39 57     SPACE eurjchem-101 39 58 and and CCONJ eurjchem-101 39 59     SPACE eurjchem-101 39 60 ( ( PUNCT eurjchem-101 39 61 c c NOUN eurjchem-101 39 62 ) ) PUNCT eurjchem-101 39 63     SPACE eurjchem-101 39 64 neutralized neutralize VERB eurjchem-101 39 65     SPACE eurjchem-101 39 66 with with ADP eurjchem-101 39 67     SPACE eurjchem-101 39 68 lioh lioh ADV eurjchem-101 39 69     SPACE eurjchem-101 39 70 in in ADP eurjchem-101 39 71     SPACE eurjchem-101 39 72 the the DET eurjchem-101 39 73     SPACE eurjchem-101 39 74 presence presence NOUN eurjchem-101 39 75     SPACE eurjchem-101 39 76 of of ADP eurjchem-101 39 77     SPACE eurjchem-101 39 78 zncl2 zncl2 NOUN eurjchem-101 39 79     SPACE eurjchem-101 39 80 ( ( PUNCT eurjchem-101 39 81 ph ph VERB eurjchem-101 39 82     SPACE eurjchem-101 39 83 = = NOUN eurjchem-101 39 84     SPACE eurjchem-101 39 85 7 7 NUM eurjchem-101 39 86 ) ) PUNCT eurjchem-101 39 87 . . PUNCT eurjchem-101 39 88             SPACE eurjchem-101 40 1 figure figure VERB eurjchem-101 40 2     SPACE eurjchem-101 40 3 6 6 NUM eurjchem-101 40 4 . . PUNCT eurjchem-101 40 5     SPACE eurjchem-101 40 6 13c 13c NOUN eurjchem-101 40 7     SPACE eurjchem-101 40 8 nmr nmr NOUN eurjchem-101 40 9     SPACE eurjchem-101 40 10 spectra spectra NOUN eurjchem-101 40 11     SPACE eurjchem-101 40 12 of of ADP eurjchem-101 40 13     SPACE eurjchem-101 40 14 5‐ala 5‐ala NUM eurjchem-101 40 15     SPACE eurjchem-101 40 16 in in ADP eurjchem-101 40 17     SPACE eurjchem-101 40 18 d2o d2o NOUN eurjchem-101 40 19 : : PUNCT eurjchem-101 40 20     SPACE eurjchem-101 40 21 ( ( PUNCT eurjchem-101 40 22 a a X eurjchem-101 40 23 ) ) PUNCT eurjchem-101 40 24     SPACE eurjchem-101 40 25 5‐ala·hcl 5‐ala·hcl ADV eurjchem-101 40 26 , , PUNCT eurjchem-101 40 27     SPACE eurjchem-101 40 28 ( ( PUNCT eurjchem-101 40 29 b b NOUN eurjchem-101 40 30 ) ) PUNCT eurjchem-101 40 31     SPACE eurjchem-101 40 32 neutralized neutralize VERB eurjchem-101 40 33     SPACE eurjchem-101 40 34 with with ADP eurjchem-101 40 35     SPACE eurjchem-101 40 36 lioh lioh ADV eurjchem-101 40 37 , , PUNCT eurjchem-101 40 38     SPACE eurjchem-101 40 39 and and CCONJ eurjchem-101 40 40     SPACE eurjchem-101 40 41 ( ( PUNCT eurjchem-101 40 42 c c NOUN eurjchem-101 40 43 ) ) PUNCT eurjchem-101 40 44     SPACE eurjchem-101 40 45 neutralized neutralize VERB eurjchem-101 40 46     SPACE eurjchem-101 40 47 with with ADP eurjchem-101 40 48     SPACE eurjchem-101 40 49 lioh lioh ADV eurjchem-101 40 50     SPACE eurjchem-101 40 51 in in ADP eurjchem-101 40 52     SPACE eurjchem-101 40 53 the the DET eurjchem-101 40 54     SPACE eurjchem-101 40 55 presence presence NOUN eurjchem-101 40 56     SPACE eurjchem-101 40 57 of of ADP eurjchem-101 40 58     SPACE eurjchem-101 40 59 zncl2 zncl2 NOUN eurjchem-101 40 60     SPACE eurjchem-101 40 61 ( ( PUNCT eurjchem-101 40 62 ph ph VERB eurjchem-101 40 63     SPACE eurjchem-101 40 64 = = NOUN eurjchem-101 40 65     SPACE eurjchem-101 40 66 7 7 NUM eurjchem-101 40 67 ) ) PUNCT eurjchem-101 40 68 . . PUNCT eurjchem-101 40 69     SPACE eurjchem-101 41 1 376 376 NUM eurjchem-101 41 2     SPACE eurjchem-101 41 3 sakiyama sakiyama NOUN eurjchem-101 41 4     SPACE eurjchem-101 41 5 et et NOUN eurjchem-101 41 6     SPACE eurjchem-101 41 7 al al PROPN eurjchem-101 41 8 . . PROPN eurjchem-101 41 9     SPACE eurjchem-101 41 10 / / SYM eurjchem-101 41 11     SPACE eurjchem-101 41 12 european european ADJ eurjchem-101 41 13     SPACE eurjchem-101 41 14 journal journal NOUN eurjchem-101 41 15     SPACE eurjchem-101 41 16 of of ADP eurjchem-101 41 17     SPACE eurjchem-101 41 18 chemistry chemistry NOUN eurjchem-101 41 19     SPACE eurjchem-101 41 20 1 1 NUM eurjchem-101 41 21     SPACE eurjchem-101 41 22 ( ( PUNCT eurjchem-101 41 23 4 4 NUM eurjchem-101 41 24 ) ) PUNCT eurjchem-101 41 25     SPACE eurjchem-101 41 26 ( ( PUNCT eurjchem-101 41 27 2010 2010 NUM eurjchem-101 41 28 ) ) PUNCT eurjchem-101 41 29     SPACE eurjchem-101 41 30 373­376 373­376 NUM eurjchem-101 41 31         SPACE eurjchem-101 41 32 3.3 3.3 NUM eurjchem-101 41 33 . . PUNCT eurjchem-101 41 34     SPACE eurjchem-101 41 35 stabilization stabilization NOUN eurjchem-101 41 36     SPACE eurjchem-101 41 37 mechanism mechanism NOUN eurjchem-101 41 38     SPACE eurjchem-101 41 39 of of ADP eurjchem-101 41 40     SPACE eurjchem-101 41 41 5­ala 5­ala NUM eurjchem-101 41 42     SPACE eurjchem-101 41 43 by by ADP eurjchem-101 41 44     SPACE eurjchem-101 41 45 zinc(ii zinc(ii NUM eurjchem-101 41 46 ) ) PUNCT eurjchem-101 41 47     SPACE eurjchem-101 41 48 ion ion NOUN eurjchem-101 41 49           SPACE eurjchem-101 41 50 as as SCONJ eurjchem-101 41 51     SPACE eurjchem-101 41 52 reported report VERB eurjchem-101 41 53     SPACE eurjchem-101 41 54 in in ADP eurjchem-101 41 55     SPACE eurjchem-101 41 56 the the DET eurjchem-101 41 57     SPACE eurjchem-101 41 58 introduction introduction NOUN eurjchem-101 41 59 , , PUNCT eurjchem-101 41 60     SPACE eurjchem-101 41 61 the the DET eurjchem-101 41 62     SPACE eurjchem-101 41 63 auto‐condensation auto‐condensation NOUN eurjchem-101 41 64     SPACE eurjchem-101 41 65 of of ADP eurjchem-101 41 66       SPACE eurjchem-101 41 67 5‐ala 5‐ala NUM eurjchem-101 41 68     SPACE eurjchem-101 41 69 starts start NOUN eurjchem-101 41 70     SPACE eurjchem-101 41 71 with with ADP eurjchem-101 41 72     SPACE eurjchem-101 41 73 a a DET eurjchem-101 41 74     SPACE eurjchem-101 41 75 nucleophilic nucleophilic ADJ eurjchem-101 41 76     SPACE eurjchem-101 41 77 attack attack NOUN eurjchem-101 41 78     SPACE eurjchem-101 41 79 by by ADP eurjchem-101 41 80     SPACE eurjchem-101 41 81 a a DET eurjchem-101 41 82     SPACE eurjchem-101 41 83 lone lone ADJ eurjchem-101 41 84     SPACE eurjchem-101 41 85 pair pair NOUN eurjchem-101 41 86     SPACE eurjchem-101 41 87 of of ADP eurjchem-101 41 88     SPACE eurjchem-101 41 89 the the DET eurjchem-101 41 90     SPACE eurjchem-101 41 91 amino amino NOUN eurjchem-101 41 92     SPACE eurjchem-101 41 93 group group NOUN eurjchem-101 41 94     SPACE eurjchem-101 41 95 of of ADP eurjchem-101 41 96     SPACE eurjchem-101 41 97 5‐ala 5‐ala NUM eurjchem-101 41 98     SPACE eurjchem-101 41 99 to to ADP eurjchem-101 41 100     SPACE eurjchem-101 41 101 a a DET eurjchem-101 41 102     SPACE eurjchem-101 41 103 γ‐carbonyl γ‐carbonyl NOUN eurjchem-101 41 104     SPACE eurjchem-101 41 105 carbon carbon NOUN eurjchem-101 41 106     SPACE eurjchem-101 41 107 of of ADP eurjchem-101 41 108     SPACE eurjchem-101 41 109 another another DET eurjchem-101 41 110     SPACE eurjchem-101 41 111 5‐ala 5‐ala NUM eurjchem-101 41 112     SPACE eurjchem-101 41 113 molecule molecule NOUN eurjchem-101 41 114 . . PUNCT eurjchem-101 41 115     SPACE eurjchem-101 42 1 judging judge VERB eurjchem-101 42 2     SPACE eurjchem-101 42 3 from from ADP eurjchem-101 42 4     SPACE eurjchem-101 42 5 the the DET eurjchem-101 42 6     SPACE eurjchem-101 42 7 downfield downfield NOUN eurjchem-101 42 8     SPACE eurjchem-101 42 9 shift shift NOUN eurjchem-101 42 10     SPACE eurjchem-101 42 11 in in ADP eurjchem-101 42 12     SPACE eurjchem-101 42 13 1h 1h NUM eurjchem-101 42 14     SPACE eurjchem-101 42 15 nmr nmr NOUN eurjchem-101 42 16 , , PUNCT eurjchem-101 42 17     SPACE eurjchem-101 42 18 5‐ala 5‐ala NUM eurjchem-101 42 19     SPACE eurjchem-101 42 20 seems seem VERB eurjchem-101 42 21     SPACE eurjchem-101 42 22 to to PART eurjchem-101 42 23     SPACE eurjchem-101 42 24 coordinate coordinate VERB eurjchem-101 42 25     SPACE eurjchem-101 42 26 to to ADP eurjchem-101 42 27     SPACE eurjchem-101 42 28 the the DET eurjchem-101 42 29     SPACE eurjchem-101 42 30 zinc(ii zinc(ii NUM eurjchem-101 42 31 ) ) PUNCT eurjchem-101 42 32     SPACE eurjchem-101 42 33 ion ion NOUN eurjchem-101 42 34     SPACE eurjchem-101 42 35 to to PART eurjchem-101 42 36     SPACE eurjchem-101 42 37 form form VERB eurjchem-101 42 38     SPACE eurjchem-101 42 39 a a DET eurjchem-101 42 40     SPACE eurjchem-101 42 41 zinc(ii zinc(ii NUM eurjchem-101 42 42 ) ) PUNCT eurjchem-101 42 43     SPACE eurjchem-101 42 44 complex complex NOUN eurjchem-101 42 45 . . PUNCT eurjchem-101 42 46     SPACE eurjchem-101 43 1 since since SCONJ eurjchem-101 43 2     SPACE eurjchem-101 43 3 the the DET eurjchem-101 43 4     SPACE eurjchem-101 43 5 lone lone ADJ eurjchem-101 43 6     SPACE eurjchem-101 43 7 pair pair NOUN eurjchem-101 43 8     SPACE eurjchem-101 43 9 is be AUX eurjchem-101 43 10     SPACE eurjchem-101 43 11 used use VERB eurjchem-101 43 12     SPACE eurjchem-101 43 13 for for ADP eurjchem-101 43 14     SPACE eurjchem-101 43 15 the the DET eurjchem-101 43 16     SPACE eurjchem-101 43 17 coordination coordination NOUN eurjchem-101 43 18     SPACE eurjchem-101 43 19 bond bond NOUN eurjchem-101 43 20     SPACE eurjchem-101 43 21 in in ADP eurjchem-101 43 22     SPACE eurjchem-101 43 23 the the DET eurjchem-101 43 24     SPACE eurjchem-101 43 25 complex complex NOUN eurjchem-101 43 26 , , PUNCT eurjchem-101 43 27     SPACE eurjchem-101 43 28 the the DET eurjchem-101 43 29     SPACE eurjchem-101 43 30 initial initial ADJ eurjchem-101 43 31     SPACE eurjchem-101 43 32 nucleophilic nucleophilic ADJ eurjchem-101 43 33     SPACE eurjchem-101 43 34 attack attack NOUN eurjchem-101 43 35     SPACE eurjchem-101 43 36 can can AUX eurjchem-101 43 37 not not PART eurjchem-101 43 38     SPACE eurjchem-101 43 39 occur occur VERB eurjchem-101 43 40 , , PUNCT eurjchem-101 43 41     SPACE eurjchem-101 43 42 and and CCONJ eurjchem-101 43 43     SPACE eurjchem-101 43 44 5‐ala 5‐ala NUM eurjchem-101 43 45     SPACE eurjchem-101 43 46 molecules molecule NOUN eurjchem-101 43 47     SPACE eurjchem-101 43 48 are be AUX eurjchem-101 43 49     SPACE eurjchem-101 43 50 stabilized stabilize VERB eurjchem-101 43 51 . . PUNCT eurjchem-101 43 52     SPACE eurjchem-101 44 1 although although SCONJ eurjchem-101 44 2     SPACE eurjchem-101 44 3 the the DET eurjchem-101 44 4     SPACE eurjchem-101 44 5 zinc(ii zinc(ii NUM eurjchem-101 44 6 ) ) PUNCT eurjchem-101 44 7     SPACE eurjchem-101 44 8 complex complex NOUN eurjchem-101 44 9     SPACE eurjchem-101 44 10 has have AUX eurjchem-101 44 11     SPACE eurjchem-101 44 12 not not PART eurjchem-101 44 13     SPACE eurjchem-101 44 14 been be AUX eurjchem-101 44 15     SPACE eurjchem-101 44 16 isolated isolate VERB eurjchem-101 44 17 , , PUNCT eurjchem-101 44 18     SPACE eurjchem-101 44 19 attempts attempt VERB eurjchem-101 44 20     SPACE eurjchem-101 44 21 to to PART eurjchem-101 44 22     SPACE eurjchem-101 44 23 do do VERB eurjchem-101 44 24     SPACE eurjchem-101 44 25 so so ADV eurjchem-101 44 26     SPACE eurjchem-101 44 27 is be AUX eurjchem-101 44 28     SPACE eurjchem-101 44 29 underway underway ADJ eurjchem-101 44 30 . . PUNCT eurjchem-101 44 31         SPACE eurjchem-101 45 1 4 4 NUM eurjchem-101 45 2 . . PUNCT eurjchem-101 45 3     SPACE eurjchem-101 45 4 conclusion conclusion NOUN eurjchem-101 45 5         SPACE eurjchem-101 45 6 a a DET eurjchem-101 45 7     SPACE eurjchem-101 45 8 method method NOUN eurjchem-101 45 9     SPACE eurjchem-101 45 10 of of ADP eurjchem-101 45 11     SPACE eurjchem-101 45 12 stabilizing stabilize VERB eurjchem-101 45 13     SPACE eurjchem-101 45 14 5‐ala 5‐ala NUM eurjchem-101 45 15     SPACE eurjchem-101 45 16 at at ADP eurjchem-101 45 17     SPACE eurjchem-101 45 18 neutral neutral ADJ eurjchem-101 45 19     SPACE eurjchem-101 45 20 ph ph NOUN eurjchem-101 45 21     SPACE eurjchem-101 45 22 was be AUX eurjchem-101 45 23     SPACE eurjchem-101 45 24 being be AUX eurjchem-101 45 25     SPACE eurjchem-101 45 26 required require VERB eurjchem-101 45 27     SPACE eurjchem-101 45 28 in in ADP eurjchem-101 45 29     SPACE eurjchem-101 45 30 order order NOUN eurjchem-101 45 31     SPACE eurjchem-101 45 32 to to PART eurjchem-101 45 33     SPACE eurjchem-101 45 34 use use VERB eurjchem-101 45 35     SPACE eurjchem-101 45 36 5‐ala 5‐ala NUM eurjchem-101 45 37     SPACE eurjchem-101 45 38 for for ADP eurjchem-101 45 39     SPACE eurjchem-101 45 40 some some DET eurjchem-101 45 41     SPACE eurjchem-101 45 42 application application NOUN eurjchem-101 45 43     SPACE eurjchem-101 45 44 purposes purpose NOUN eurjchem-101 45 45 . . PUNCT eurjchem-101 45 46     SPACE eurjchem-101 46 1 it it PRON eurjchem-101 46 2     SPACE eurjchem-101 46 3 is be AUX eurjchem-101 46 4     SPACE eurjchem-101 46 5 known know VERB eurjchem-101 46 6     SPACE eurjchem-101 46 7 that that SCONJ eurjchem-101 46 8     SPACE eurjchem-101 46 9 5‐ala 5‐ala NUM eurjchem-101 46 10     SPACE eurjchem-101 46 11 is be AUX eurjchem-101 46 12     SPACE eurjchem-101 46 13 not not PART eurjchem-101 46 14     SPACE eurjchem-101 46 15 stable stable ADJ eurjchem-101 46 16     SPACE eurjchem-101 46 17 in in ADP eurjchem-101 46 18     SPACE eurjchem-101 46 19 an an DET eurjchem-101 46 20     SPACE eurjchem-101 46 21 aqueous aqueous ADJ eurjchem-101 46 22     SPACE eurjchem-101 46 23 solution solution NOUN eurjchem-101 46 24     SPACE eurjchem-101 46 25 at at ADP eurjchem-101 46 26     SPACE eurjchem-101 46 27 neutral neutral ADJ eurjchem-101 46 28     SPACE eurjchem-101 46 29 ph ph PROPN eurjchem-101 46 30 . . PROPN eurjchem-101 46 31     SPACE eurjchem-101 46 32 in in ADP eurjchem-101 46 33     SPACE eurjchem-101 46 34 this this DET eurjchem-101 46 35     SPACE eurjchem-101 46 36 study study NOUN eurjchem-101 46 37 , , PUNCT eurjchem-101 46 38     SPACE eurjchem-101 46 39 the the DET eurjchem-101 46 40     SPACE eurjchem-101 46 41 zinc(ii zinc(ii NUM eurjchem-101 46 42 ) ) PUNCT eurjchem-101 46 43     SPACE eurjchem-101 46 44 ion ion NOUN eurjchem-101 46 45     SPACE eurjchem-101 46 46 was be AUX eurjchem-101 46 47     SPACE eurjchem-101 46 48 found find VERB eurjchem-101 46 49     SPACE eurjchem-101 46 50 to to PART eurjchem-101 46 51     SPACE eurjchem-101 46 52 stabilize stabilize VERB eurjchem-101 46 53     SPACE eurjchem-101 46 54 5‐ala 5‐ala NUM eurjchem-101 46 55     SPACE eurjchem-101 46 56 in in ADP eurjchem-101 46 57     SPACE eurjchem-101 46 58 an an DET eurjchem-101 46 59     SPACE eurjchem-101 46 60 aqueous aqueous ADJ eurjchem-101 46 61     SPACE eurjchem-101 46 62 solution solution NOUN eurjchem-101 46 63     SPACE eurjchem-101 46 64 of of ADP eurjchem-101 46 65     SPACE eurjchem-101 46 66 neutral neutral ADJ eurjchem-101 46 67     SPACE eurjchem-101 46 68 ph ph NOUN eurjchem-101 46 69     SPACE eurjchem-101 46 70 by by ADP eurjchem-101 46 71     SPACE eurjchem-101 46 72 forming form VERB eurjchem-101 46 73     SPACE eurjchem-101 46 74 a a DET eurjchem-101 46 75     SPACE eurjchem-101 46 76 zinc(ii zinc(ii NUM eurjchem-101 46 77 ) ) PUNCT eurjchem-101 46 78     SPACE eurjchem-101 46 79 complex complex NOUN eurjchem-101 46 80 . . PUNCT eurjchem-101 46 81         SPACE eurjchem-101 47 1 references reference NOUN eurjchem-101 47 2         SPACE eurjchem-101 47 3 [ [ X eurjchem-101 47 4 1 1 NUM eurjchem-101 47 5 ] ] PUNCT eurjchem-101 47 6 . . PUNCT eurjchem-101 48 1 shemin shemin NOUN eurjchem-101 48 2 , , PUNCT eurjchem-101 48 3     SPACE eurjchem-101 48 4 d. d. PROPN eurjchem-101 48 5 ; ; PUNCT eurjchem-101 48 6     SPACE eurjchem-101 48 7 russell russell PROPN eurjchem-101 48 8 , , PUNCT eurjchem-101 48 9     SPACE eurjchem-101 48 10 c. c. PROPN eurjchem-101 48 11     SPACE eurjchem-101 48 12 s. s. PROPN eurjchem-101 48 13     SPACE eurjchem-101 48 14 j. j. PROPN eurjchem-101 48 15     SPACE eurjchem-101 48 16 am be AUX eurjchem-101 48 17 . . PUNCT eurjchem-101 48 18     SPACE eurjchem-101 48 19 chem chem NOUN eurjchem-101 48 20 . . PUNCT eurjchem-101 48 21     SPACE eurjchem-101 48 22 soc soc PROPN eurjchem-101 48 23 . . PUNCT eurjchem-101 48 24     SPACE eurjchem-101 48 25 1953 1953 NUM eurjchem-101 48 26 , , PUNCT eurjchem-101 48 27     SPACE eurjchem-101 48 28 75 75 NUM eurjchem-101 48 29 , , PUNCT eurjchem-101 48 30     SPACE eurjchem-101 48 31 4873–4874 4873–4874 NOUN eurjchem-101 48 32 . . PUNCT eurjchem-101 48 33     SPACE eurjchem-101 49 1 [ [ X eurjchem-101 49 2 2 2 NUM eurjchem-101 49 3 ] ] PUNCT eurjchem-101 49 4 . . PUNCT eurjchem-101 50 1 jaffe jaffe PROPN eurjchem-101 50 2 , , PUNCT eurjchem-101 50 3     SPACE eurjchem-101 50 4 e. e. PROPN eurjchem-101 50 5     SPACE eurjchem-101 50 6 k. k. PROPN eurjchem-101 50 7 ; ; PUNCT eurjchem-101 50 8     SPACE eurjchem-101 50 9 rajagopalan rajagopalan NOUN eurjchem-101 50 10 , , PUNCT eurjchem-101 50 11     SPACE eurjchem-101 50 12 j. j. PROPN eurjchem-101 50 13     SPACE eurjchem-101 50 14 s. s. PROPN eurjchem-101 50 15     SPACE eurjchem-101 50 16 bioinorg bioinorg PROPN eurjchem-101 50 17 . . PUNCT eurjchem-101 50 18     SPACE eurjchem-101 50 19 chem chem NOUN eurjchem-101 50 20 . . PUNCT eurjchem-101 50 21     SPACE eurjchem-101 50 22 1990 1990 NUM eurjchem-101 50 23 , , PUNCT eurjchem-101 50 24     SPACE eurjchem-101 50 25 18 18 NUM eurjchem-101 50 26 , , PUNCT eurjchem-101 50 27     SPACE eurjchem-101 50 28 381–394 381–394 NUM eurjchem-101 50 29 . . PUNCT eurjchem-101 50 30       SPACE eurjchem-101 51 1 [ [ X eurjchem-101 51 2 3 3 NUM eurjchem-101 51 3 ] ] PUNCT eurjchem-101 51 4 . . PUNCT eurjchem-101 52 1 novo novo PROPN eurjchem-101 52 2 , , PUNCT eurjchem-101 52 3     SPACE eurjchem-101 52 4 m. m. NOUN eurjchem-101 52 5 ; ; PUNCT eurjchem-101 52 6     SPACE eurjchem-101 52 7 hüttmann hüttmann VERB eurjchem-101 52 8 , , PUNCT eurjchem-101 52 9     SPACE eurjchem-101 52 10 g. g. NOUN eurjchem-101 52 11 ; ; PUNCT eurjchem-101 52 12     SPACE eurjchem-101 52 13 diddens didden NOUN eurjchem-101 52 14 , , PUNCT eurjchem-101 52 15     SPACE eurjchem-101 52 16 h. h. PROPN eurjchem-101 52 17     SPACE eurjchem-101 52 18 j. j. PROPN eurjchem-101 52 19     SPACE eurjchem-101 52 20 photochem photochem PROPN eurjchem-101 52 21 . . PUNCT eurjchem-101 52 22     SPACE eurjchem-101 52 23 photobiol photobiol PROPN eurjchem-101 52 24 . . PUNCT eurjchem-101 52 25     SPACE eurjchem-101 52 26 b. b. PROPN eurjchem-101 52 27     SPACE eurjchem-101 52 28 biol biol PROPN eurjchem-101 52 29 . . PUNCT eurjchem-101 52 30     SPACE eurjchem-101 52 31 1996 1996 NUM eurjchem-101 52 32 , , PUNCT eurjchem-101 52 33     SPACE eurjchem-101 52 34 34 34 NUM eurjchem-101 52 35 , , PUNCT eurjchem-101 52 36     SPACE eurjchem-101 52 37 143–148 143–148 NUM eurjchem-101 52 38 . . PUNCT eurjchem-101 52 39       SPACE eurjchem-101 53 1 [ [ X eurjchem-101 53 2 4 4 NUM eurjchem-101 53 3 ] ] PUNCT eurjchem-101 53 4 . . PUNCT eurjchem-101 54 1 elfsson elfsson NOUN eurjchem-101 54 2 , , PUNCT eurjchem-101 54 3     SPACE eurjchem-101 54 4 b. b. PROPN eurjchem-101 54 5 ; ; PUNCT eurjchem-101 54 6     SPACE eurjchem-101 54 7 wallin wallin NOUN eurjchem-101 54 8 , , PUNCT eurjchem-101 54 9     SPACE eurjchem-101 54 10 i. i. NOUN eurjchem-101 54 11 ; ; PUNCT eurjchem-101 54 12     SPACE eurjchem-101 54 13 eksborg eksborg ADJ eurjchem-101 54 14 , , PUNCT eurjchem-101 54 15     SPACE eurjchem-101 54 16 s. s. PROPN eurjchem-101 54 17 ; ; PUNCT eurjchem-101 54 18     SPACE eurjchem-101 54 19 rudaeus rudaeus NOUN eurjchem-101 54 20 , , PUNCT eurjchem-101 54 21     SPACE eurjchem-101 54 22 k. k. PROPN eurjchem-101 54 23 ; ; PUNCT eurjchem-101 54 24     SPACE eurjchem-101 54 25 ros ros PROPN eurjchem-101 54 26 , , PUNCT eurjchem-101 54 27     SPACE eurjchem-101 54 28 a. a. NOUN eurjchem-101 54 29     SPACE eurjchem-101 54 30 m. m. NOUN eurjchem-101 54 31 ; ; PUNCT eurjchem-101 54 32     SPACE eurjchem-101 54 33 ehrsson ehrsson NOUN eurjchem-101 54 34 , , PUNCT eurjchem-101 54 35     SPACE eurjchem-101 54 36 h. h. PROPN eurjchem-101 54 37     SPACE eurjchem-101 54 38 eur eur PROPN eurjchem-101 54 39 . . PUNCT eurjchem-101 54 40     SPACE eurjchem-101 54 41 j. j. PROPN eurjchem-101 54 42     SPACE eurjchem-101 54 43 pharm pharm PROPN eurjchem-101 54 44 . . PUNCT eurjchem-101 54 45     SPACE eurjchem-101 55 1 sci sci PROPN eurjchem-101 55 2 . . PUNCT eurjchem-101 55 3     SPACE eurjchem-101 55 4 1998 1998 NUM eurjchem-101 55 5 , , PUNCT eurjchem-101 55 6     SPACE eurjchem-101 55 7 7 7 NUM eurjchem-101 55 8 , , PUNCT eurjchem-101 55 9     SPACE eurjchem-101 55 10 87–91 87–91 NUM eurjchem-101 55 11 . . PUNCT eurjchem-101 55 12     SPACE eurjchem-101 56 1 [ [ X eurjchem-101 56 2 5 5 NUM eurjchem-101 56 3 ] ] PUNCT eurjchem-101 56 4 . . PUNCT eurjchem-101 57 1 bunke bunke NOUN eurjchem-101 57 2 , , PUNCT eurjchem-101 57 3     SPACE eurjchem-101 57 4 a. a. NOUN eurjchem-101 57 5 ; ; PUNCT eurjchem-101 57 6     SPACE eurjchem-101 57 7 zerbe zerbe NOUN eurjchem-101 57 8 , , PUNCT eurjchem-101 57 9     SPACE eurjchem-101 57 10 o. o. PROPN eurjchem-101 57 11 ; ; PUNCT eurjchem-101 57 12     SPACE eurjchem-101 57 13 schmid schmid PROPN eurjchem-101 57 14 , , PUNCT eurjchem-101 57 15     SPACE eurjchem-101 57 16 h. h. PROPN eurjchem-101 57 17 ; ; PUNCT eurjchem-101 57 18     SPACE eurjchem-101 57 19 burmeister burmeister NOUN eurjchem-101 57 20 , , PUNCT eurjchem-101 57 21     SPACE eurjchem-101 57 22 g. g. NOUN eurjchem-101 57 23 ; ; PUNCT eurjchem-101 57 24     SPACE eurjchem-101 57 25 merkle merkle NOUN eurjchem-101 57 26 , , PUNCT eurjchem-101 57 27     SPACE eurjchem-101 57 28 h. h. PROPN eurjchem-101 57 29     SPACE eurjchem-101 57 30 p. p. PROPN eurjchem-101 57 31 ; ; PUNCT eurjchem-101 57 32     SPACE eurjchem-101 57 33 gander gander NOUN eurjchem-101 57 34 , , PUNCT eurjchem-101 57 35     SPACE eurjchem-101 57 36 b. b. PROPN eurjchem-101 57 37     SPACE eurjchem-101 57 38 j. j. PROPN eurjchem-101 57 39     SPACE eurjchem-101 57 40 pharm pharm PROPN eurjchem-101 57 41 . . PUNCT eurjchem-101 57 42     SPACE eurjchem-101 58 1 sci sci PROPN eurjchem-101 58 2 . . PUNCT eurjchem-101 58 3     SPACE eurjchem-101 58 4 2000 2000 NUM eurjchem-101 58 5 , , PUNCT eurjchem-101 58 6     SPACE eurjchem-101 58 7 89 89 NUM eurjchem-101 58 8 , , PUNCT eurjchem-101 58 9     SPACE eurjchem-101 58 10 1335–1341 1335–1341 NUM eurjchem-101 58 11 . . PUNCT eurjchem-101 58 12     SPACE eurjchem-101 59 1 [ [ X eurjchem-101 59 2 6 6 NUM eurjchem-101 59 3 ] ] PUNCT eurjchem-101 59 4 . . PUNCT eurjchem-101 60 1 gadmar gadmar PROPN eurjchem-101 60 2 , , PUNCT eurjchem-101 60 3     SPACE eurjchem-101 60 4 ø ø PROPN eurjchem-101 60 5 . . PUNCT eurjchem-101 60 6     SPACE eurjchem-101 60 7 b. b. PROPN eurjchem-101 60 8 ; ; PUNCT eurjchem-101 60 9     SPACE eurjchem-101 60 10 moan moan VERB eurjchem-101 60 11 , , PUNCT eurjchem-101 60 12     SPACE eurjchem-101 60 13 j. j. PROPN eurjchem-101 60 14 ; ; PUNCT eurjchem-101 60 15     SPACE eurjchem-101 60 16 scheie scheie ADJ eurjchem-101 60 17 , , PUNCT eurjchem-101 60 18     SPACE eurjchem-101 60 19 e. e. PROPN eurjchem-101 60 20 ; ; PUNCT eurjchem-101 60 21     SPACE eurjchem-101 60 22 ma ma PROPN eurjchem-101 60 23 , , PUNCT eurjchem-101 60 24     SPACE eurjchem-101 60 25 l. l. PROPN eurjchem-101 60 26     SPACE eurjchem-101 60 27 w. w. PROPN eurjchem-101 60 28 ; ; PUNCT eurjchem-101 60 29     SPACE eurjchem-101 60 30 peng peng PROPN eurjchem-101 60 31 , , PUNCT eurjchem-101 60 32     SPACE eurjchem-101 60 33 q. q. PROPN eurjchem-101 60 34     SPACE eurjchem-101 60 35 j. j. PROPN eurjchem-101 60 36     SPACE eurjchem-101 60 37 photochem photochem PROPN eurjchem-101 60 38 . . PUNCT eurjchem-101 60 39     SPACE eurjchem-101 60 40 photobiol photobiol NOUN eurjchem-101 60 41 . . PUNCT eurjchem-101 60 42     SPACE eurjchem-101 61 1 b b X eurjchem-101 61 2 : : PUNCT eurjchem-101 61 3     SPACE eurjchem-101 61 4 biol biol PROPN eurjchem-101 61 5 . . PUNCT eurjchem-101 61 6     SPACE eurjchem-101 62 1 2002 2002 NUM eurjchem-101 62 2 , , PUNCT eurjchem-101 62 3     SPACE eurjchem-101 62 4 67 67 NUM eurjchem-101 62 5 , , PUNCT eurjchem-101 62 6     SPACE eurjchem-101 62 7 187–193 187–193 NUM eurjchem-101 62 8 . . PUNCT eurjchem-101 62 9     SPACE eurjchem-101 63 1 [ [ X eurjchem-101 63 2 7 7 NUM eurjchem-101 63 3 ] ] PUNCT eurjchem-101 63 4 . . PUNCT eurjchem-101 63 5 nishikawa nishikawa PROPN eurjchem-101 63 6 , , PUNCT eurjchem-101 63 7     SPACE eurjchem-101 63 8 s. s. PROPN eurjchem-101 63 9 ; ; PUNCT eurjchem-101 63 10     SPACE eurjchem-101 63 11 watanabe watanabe PROPN eurjchem-101 63 12 , , PUNCT eurjchem-101 63 13     SPACE eurjchem-101 63 14 k. k. PROPN eurjchem-101 63 15 ; ; PUNCT eurjchem-101 63 16     SPACE eurjchem-101 63 17 tanaka tanaka PROPN eurjchem-101 63 18 , , PUNCT eurjchem-101 63 19     SPACE eurjchem-101 63 20 t. t. PROPN eurjchem-101 63 21 ; ; PUNCT eurjchem-101 63 22     SPACE eurjchem-101 63 23 miyachi miyachi NOUN eurjchem-101 63 24 , , PUNCT eurjchem-101 63 25     SPACE eurjchem-101 63 26 n. n. NOUN eurjchem-101 63 27 ; ; PUNCT eurjchem-101 63 28     SPACE eurjchem-101 63 29 hotta hotta ADJ eurjchem-101 63 30 , , PUNCT eurjchem-101 63 31     SPACE eurjchem-101 63 32 y. y. NOUN eurjchem-101 63 33 ; ; PUNCT eurjchem-101 63 34     SPACE eurjchem-101 63 35 murooka murooka VERB eurjchem-101 63 36 , , PUNCT eurjchem-101 63 37     SPACE eurjchem-101 63 38 y. y. PROPN eurjchem-101 63 39     SPACE eurjchem-101 63 40 j. j. PROPN eurjchem-101 63 41     SPACE eurjchem-101 63 42 biosci biosci PROPN eurjchem-101 63 43 . . PUNCT eurjchem-101 63 44     SPACE eurjchem-101 63 45 bioeng bioeng PROPN eurjchem-101 63 46 . . PUNCT eurjchem-101 63 47     SPACE eurjchem-101 63 48 1999 1999 NUM eurjchem-101 63 49 , , PUNCT eurjchem-101 63 50     SPACE eurjchem-101 63 51 87 87 NUM eurjchem-101 63 52 , , PUNCT eurjchem-101 63 53     SPACE eurjchem-101 63 54 798–804 798–804 NUM eurjchem-101 63 55 . . PUNCT eurjchem-101 63 56         SPACE