id	sid	tid	token	lemma	pos
eurjchem-1140	1	1	untitled	untitle	VERB
eurjchem-1140	1	2	european	european	PROPN
eurjchem-1140	1	3	journal	journal	PROPN
eurjchem-1140	1	4	of	of	ADP
eurjchem-1140	1	5	chemistry	chemistry	NOUN
eurjchem-1140	1	6	6	6	NUM
eurjchem-1140	1	7	(	(	PUNCT
eurjchem-1140	1	8	1	1	NUM
eurjchem-1140	1	9	)	)	PUNCT
eurjchem-1140	1	10	(	(	PUNCT
eurjchem-1140	1	11	2015	2015	NUM
eurjchem-1140	1	12	)	)	PUNCT
eurjchem-1140	1	13	44‐47	44‐47	NUM
eurjchem-1140	1	14	european	european	PROPN
eurjchem-1140	1	15	journal	journal	PROPN
eurjchem-1140	1	16	of	of	ADP
eurjchem-1140	1	17	chemistry	chemistry	NOUN
eurjchem-1140	1	18	issn	issn	PROPN
eurjchem-1140	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-1140	1	20	(	(	PUNCT
eurjchem-1140	1	21	print	print	NOUN
eurjchem-1140	1	22	)	)	PUNCT
eurjchem-1140	1	23	/	/	SYM
eurjchem-1140	1	24	issn	issn	PROPN
eurjchem-1140	1	25	2153‐2257	2153‐2257	NUM
eurjchem-1140	1	26	(	(	PUNCT
eurjchem-1140	1	27	online	online	ADJ
eurjchem-1140	1	28	)	)	PUNCT
eurjchem-1140	1	29			NOUN
eurjchem-1140	1	30	2015	2015	NUM
eurjchem-1140	1	31	atlanta	atlanta	PROPN
eurjchem-1140	1	32	publishing	publishing	PROPN
eurjchem-1140	1	33	house	house	PROPN
eurjchem-1140	1	34	llc	llc	PROPN
eurjchem-1140	1	35	‐	‐	PUNCT
eurjchem-1140	1	36	all	all	DET
eurjchem-1140	1	37	rights	right	NOUN
eurjchem-1140	1	38	reserved	reserve	VERB
eurjchem-1140	1	39	‐	‐	NOUN
eurjchem-1140	1	40	printed	print	VERB
eurjchem-1140	1	41	in	in	ADP
eurjchem-1140	1	42	the	the	DET
eurjchem-1140	1	43	usa	usa	PROPN
eurjchem-1140	1	44	http://dx.doi.org/10.5155/eurjchem.6.1.44‐47.1140	http://dx.doi.org/10.5155/eurjchem.6.1.44‐47.1140	PROPN
eurjchem-1140	1	45	european	european	PROPN
eurjchem-1140	1	46	journal	journal	PROPN
eurjchem-1140	1	47	of	of	ADP
eurjchem-1140	1	48	chemistry	chemistry	PROPN
eurjchem-1140	1	49	journal	journal	PROPN
eurjchem-1140	1	50	webpage	webpage	NOUN
eurjchem-1140	1	51	:	:	PUNCT
eurjchem-1140	1	52	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1140	1	53	synthesis	synthesis	NOUN
eurjchem-1140	1	54	and	and	CCONJ
eurjchem-1140	1	55	characterization	characterization	NOUN
eurjchem-1140	1	56	of	of	ADP
eurjchem-1140	1	57	manganese(ii	manganese(ii	NOUN
eurjchem-1140	1	58	)	)	PUNCT
eurjchem-1140	1	59	,	,	PUNCT
eurjchem-1140	1	60	cobalt(ii	cobalt(ii	PROPN
eurjchem-1140	1	61	)	)	PUNCT
eurjchem-1140	1	62	,	,	PUNCT
eurjchem-1140	1	63	nickel(ii	nickel(ii	ADJ
eurjchem-1140	1	64	)	)	PUNCT
eurjchem-1140	1	65	,	,	PUNCT
eurjchem-1140	1	66	copper(ii	copper(ii	PROPN
eurjchem-1140	1	67	)	)	PUNCT
eurjchem-1140	1	68	and	and	CCONJ
eurjchem-1140	1	69	zinc(ii	zinc(ii	NUM
eurjchem-1140	1	70	)	)	PUNCT
eurjchem-1140	1	71	complexes	complex	NOUN
eurjchem-1140	1	72	with	with	ADP
eurjchem-1140	1	73	new	new	ADJ
eurjchem-1140	1	74	schiff	schiff	NOUN
eurjchem-1140	1	75	base	base	NOUN
eurjchem-1140	1	76	derived	derive	VERB
eurjchem-1140	1	77	from	from	ADP
eurjchem-1140	1	78	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐dione	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐dione	NUM
eurjchem-1140	1	79	and	and	CCONJ
eurjchem-1140	1	80	thiosemicarbazide	thiosemicarbazide	VERB
eurjchem-1140	1	81	mahmoud	mahmoud	PROPN
eurjchem-1140	1	82	najim	najim	PROPN
eurjchem-1140	1	83	al‐jibouri	al‐jibouri	PROPN
eurjchem-1140	1	84	*	*	PUNCT
eurjchem-1140	1	85	and	and	CCONJ
eurjchem-1140	1	86	saad	saad	PROPN
eurjchem-1140	1	87	mohammad	mohammad	PROPN
eurjchem-1140	1	88	hasun	hasun	PROPN
eurjchem-1140	1	89	department	department	PROPN
eurjchem-1140	1	90	of	of	ADP
eurjchem-1140	1	91	chemistry	chemistry	NOUN
eurjchem-1140	1	92	,	,	PUNCT
eurjchem-1140	1	93	college	college	NOUN
eurjchem-1140	1	94	of	of	ADP
eurjchem-1140	1	95	science	science	NOUN
eurjchem-1140	1	96	,	,	PUNCT
eurjchem-1140	1	97	al‐mustansiriya	al‐mustansiriya	PROPN
eurjchem-1140	1	98	university	university	PROPN
eurjchem-1140	1	99	,	,	PUNCT
eurjchem-1140	1	100	baghdad	baghdad	PROPN
eurjchem-1140	1	101	,	,	PUNCT
eurjchem-1140	1	102	964	964	NUM
eurjchem-1140	1	103	,	,	PUNCT
eurjchem-1140	1	104	iraq	iraq	PROPN
eurjchem-1140	1	105	*	*	PUNCT
eurjchem-1140	1	106	corresponding	correspond	VERB
eurjchem-1140	1	107	author	author	NOUN
eurjchem-1140	1	108	at	at	ADP
eurjchem-1140	1	109	:	:	PUNCT
eurjchem-1140	1	110	department	department	NOUN
eurjchem-1140	1	111	of	of	ADP
eurjchem-1140	1	112	chemistry	chemistry	NOUN
eurjchem-1140	1	113	,	,	PUNCT
eurjchem-1140	1	114	college	college	NOUN
eurjchem-1140	1	115	of	of	ADP
eurjchem-1140	1	116	science	science	NOUN
eurjchem-1140	1	117	,	,	PUNCT
eurjchem-1140	1	118	al‐mustansiriya	al‐mustansiriya	PROPN
eurjchem-1140	1	119	university	university	PROPN
eurjchem-1140	1	120	,	,	PUNCT
eurjchem-1140	1	121	baghdad	baghdad	PROPN
eurjchem-1140	1	122	,	,	PUNCT
eurjchem-1140	1	123	964	964	NUM
eurjchem-1140	1	124	,	,	PUNCT
eurjchem-1140	1	125	iraq	iraq	PROPN
eurjchem-1140	1	126	.	.	PUNCT
eurjchem-1140	2	1	tel	tel	PROPN
eurjchem-1140	2	2	.	.	PUNCT
eurjchem-1140	2	3	:	:	PUNCT
eurjchem-1140	3	1	+964.077.13460946	+964.077.13460946	X
eurjchem-1140	3	2	.	.	PUNCT
eurjchem-1140	4	1	fax	fax	NOUN
eurjchem-1140	4	2	:	:	PUNCT
eurjchem-1140	4	3	+964.077.13460946	+964.077.13460946	NUM
eurjchem-1140	4	4	.	.	PUNCT
eurjchem-1140	4	5	e‐mail	e‐mail	PUNCT
eurjchem-1140	5	1	address	address	NOUN
eurjchem-1140	5	2	:	:	PUNCT
eurjchem-1140	5	3	mahmoudnajim71@yahoo.com	mahmoudnajim71@yahoo.com	PROPN
eurjchem-1140	5	4	(	(	PUNCT
eurjchem-1140	5	5	m.n	m.n	PROPN
eurjchem-1140	5	6	.	.	PROPN
eurjchem-1140	5	7	al‐jibouri	al‐jibouri	PROPN
eurjchem-1140	5	8	)	)	PUNCT
eurjchem-1140	5	9	.	.	PUNCT
eurjchem-1140	6	1	article	article	NOUN
eurjchem-1140	6	2	information	information	PROPN
eurjchem-1140	6	3	abstract	abstract	ADJ
eurjchem-1140	6	4	doi	doi	NOUN
eurjchem-1140	6	5	:	:	PUNCT
eurjchem-1140	6	6	10.5155	10.5155	NUM
eurjchem-1140	6	7	/	/	SYM
eurjchem-1140	6	8	eurjchem.6.1.44‐47.1140	eurjchem.6.1.44‐47.1140	NOUN
eurjchem-1140	6	9	received	receive	VERB
eurjchem-1140	6	10	:	:	PUNCT
eurjchem-1140	6	11	01september	01september	PROPN
eurjchem-1140	6	12	2014	2014	NUM
eurjchem-1140	6	13	received	receive	VERB
eurjchem-1140	6	14	in	in	ADP
eurjchem-1140	6	15	revised	revise	VERB
eurjchem-1140	6	16	form	form	NOUN
eurjchem-1140	6	17	:	:	PUNCT
eurjchem-1140	6	18	22	22	NUM
eurjchem-1140	6	19	september	september	PROPN
eurjchem-1140	6	20	2014	2014	NUM
eurjchem-1140	6	21	accepted	accept	VERB
eurjchem-1140	6	22	:	:	PUNCT
eurjchem-1140	6	23	26	26	NUM
eurjchem-1140	6	24	september	september	PROPN
eurjchem-1140	6	25	2014	2014	NUM
eurjchem-1140	6	26	published	publish	VERB
eurjchem-1140	6	27	online	online	ADV
eurjchem-1140	6	28	:	:	PUNCT
eurjchem-1140	6	29	31	31	NUM
eurjchem-1140	6	30	march	march	PROPN
eurjchem-1140	6	31	2015	2015	NUM
eurjchem-1140	6	32	printed	print	VERB
eurjchem-1140	6	33	:	:	PUNCT
eurjchem-1140	6	34	31	31	NUM
eurjchem-1140	6	35	march	march	PROPN
eurjchem-1140	6	36	2015	2015	NUM
eurjchem-1140	6	37	new	new	ADJ
eurjchem-1140	6	38	transition	transition	NOUN
eurjchem-1140	6	39	metal	metal	NOUN
eurjchem-1140	6	40	complexes	complex	NOUN
eurjchem-1140	6	41	of	of	ADP
eurjchem-1140	6	42	quinoxaline‐2,3‐dione‐thiosemicarbazone	quinoxaline‐2,3‐dione‐thiosemicarbazone	PROPN
eurjchem-1140	6	43	ligand	ligand	NOUN
eurjchem-1140	6	44	were	be	AUX
eurjchem-1140	6	45	prepared	prepare	VERB
eurjchem-1140	6	46	and	and	CCONJ
eurjchem-1140	6	47	characterized	characterize	VERB
eurjchem-1140	6	48	by	by	ADP
eurjchem-1140	6	49	elemental	elemental	ADJ
eurjchem-1140	6	50	analysis	analysis	NOUN
eurjchem-1140	6	51	,	,	PUNCT
eurjchem-1140	6	52	1h	1h	NUM
eurjchem-1140	6	53	and	and	CCONJ
eurjchem-1140	6	54	13c	13c	NOUN
eurjchem-1140	6	55	nmr	nmr	NOUN
eurjchem-1140	6	56	spectroscopy	spectroscopy	NOUN
eurjchem-1140	6	57	.	.	PUNCT
eurjchem-1140	7	1	the	the	DET
eurjchem-1140	7	2	ligand	ligand	NOUN
eurjchem-1140	7	3	(	(	PUNCT
eurjchem-1140	7	4	lh	lh	PROPN
eurjchem-1140	7	5	)	)	PUNCT
eurjchem-1140	7	6	was	be	AUX
eurjchem-1140	7	7	obtained	obtain	VERB
eurjchem-1140	7	8	by	by	ADP
eurjchem-1140	7	9	the	the	DET
eurjchem-1140	7	10	reaction	reaction	NOUN
eurjchem-1140	7	11	of	of	ADP
eurjchem-1140	7	12	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐dione	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐dione	NUM
eurjchem-1140	7	13	with	with	ADP
eurjchem-1140	7	14	thiosemicarbazide	thiosemicarbazide	NOUN
eurjchem-1140	7	15	.	.	PUNCT
eurjchem-1140	8	1	all	all	DET
eurjchem-1140	8	2	the	the	DET
eurjchem-1140	8	3	complexes	complex	NOUN
eurjchem-1140	8	4	are	be	AUX
eurjchem-1140	8	5	found	find	VERB
eurjchem-1140	8	6	to	to	PART
eurjchem-1140	8	7	be	be	AUX
eurjchem-1140	8	8	monomer	monomer	NOUN
eurjchem-1140	8	9	in	in	ADP
eurjchem-1140	8	10	nature	nature	NOUN
eurjchem-1140	8	11	and	and	CCONJ
eurjchem-1140	8	12	have	have	VERB
eurjchem-1140	8	13	tetrahedral	tetrahedral	ADJ
eurjchem-1140	8	14	geometry	geometry	NOUN
eurjchem-1140	8	15	.	.	PUNCT
eurjchem-1140	9	1	the	the	DET
eurjchem-1140	9	2	ir	ir	PROPN
eurjchem-1140	9	3	spectra	spectra	PROPN
eurjchem-1140	9	4	data	datum	NOUN
eurjchem-1140	9	5	revealed	reveal	VERB
eurjchem-1140	9	6	that	that	SCONJ
eurjchem-1140	9	7	the	the	DET
eurjchem-1140	9	8	new	new	ADJ
eurjchem-1140	9	9	schiff	schiff	NOUN
eurjchem-1140	9	10	base	base	NOUN
eurjchem-1140	9	11	behaved	behave	VERB
eurjchem-1140	9	12	as	as	ADP
eurjchem-1140	9	13	monobasic	monobasic	PROPN
eurjchem-1140	9	14	tridentate	tridentate	PROPN
eurjchem-1140	9	15	ligand	ligand	NOUN
eurjchem-1140	9	16	through	through	ADP
eurjchem-1140	9	17	deprotonation	deprotonation	NOUN
eurjchem-1140	9	18	of	of	ADP
eurjchem-1140	9	19	thiol‐sh	thiol‐sh	PROPN
eurjchem-1140	9	20	group	group	NOUN
eurjchem-1140	9	21	,	,	PUNCT
eurjchem-1140	9	22	oxygen	oxygen	NOUN
eurjchem-1140	9	23	atom	atom	NOUN
eurjchem-1140	9	24	of	of	ADP
eurjchem-1140	9	25	c	c	PROPN
eurjchem-1140	9	26	=	=	NOUN
eurjchem-1140	9	27	o	o	NOUN
eurjchem-1140	9	28	of	of	ADP
eurjchem-1140	9	29	pyrazine	pyrazine	ADJ
eurjchem-1140	9	30	moiety	moiety	NOUN
eurjchem-1140	9	31	and	and	CCONJ
eurjchem-1140	9	32	nitrogen	nitrogen	NOUN
eurjchem-1140	9	33	atom	atom	NOUN
eurjchem-1140	9	34	of	of	ADP
eurjchem-1140	9	35	azomethine	azomethine	PROPN
eurjchem-1140	9	36	‐c	‐c	PROPN
eurjchem-1140	9	37	=	=	NOUN
eurjchem-1140	9	38	n‐	n‐	NOUN
eurjchem-1140	9	39	group	group	NOUN
eurjchem-1140	9	40	.	.	PUNCT
eurjchem-1140	10	1	however	however	ADV
eurjchem-1140	10	2	,	,	PUNCT
eurjchem-1140	10	3	the	the	DET
eurjchem-1140	10	4	molar	molar	ADJ
eurjchem-1140	10	5	conductivity	conductivity	NOUN
eurjchem-1140	10	6	measurements	measurement	NOUN
eurjchem-1140	10	7	proved	prove	VERB
eurjchem-1140	10	8	the	the	DET
eurjchem-1140	10	9	neutral	neutral	ADJ
eurjchem-1140	10	10	nature	nature	NOUN
eurjchem-1140	10	11	of	of	ADP
eurjchem-1140	10	12	all	all	DET
eurjchem-1140	10	13	metal	metal	NOUN
eurjchem-1140	10	14	complexes	complex	NOUN
eurjchem-1140	10	15	in	in	ADP
eurjchem-1140	10	16	dmso	dmso	ADJ
eurjchem-1140	10	17	solution	solution	NOUN
eurjchem-1140	10	18	,	,	PUNCT
eurjchem-1140	10	19	as	as	ADV
eurjchem-1140	10	20	well	well	ADV
eurjchem-1140	10	21	as	as	ADP
eurjchem-1140	10	22	the	the	DET
eurjchem-1140	10	23	magnetic	magnetic	ADJ
eurjchem-1140	10	24	moment	moment	NOUN
eurjchem-1140	10	25	measurements	measurement	NOUN
eurjchem-1140	10	26	investigated	investigate	VERB
eurjchem-1140	10	27	the	the	DET
eurjchem-1140	10	28	high	high	ADJ
eurjchem-1140	10	29	spin	spin	NOUN
eurjchem-1140	10	30	properties	property	NOUN
eurjchem-1140	10	31	of	of	ADP
eurjchem-1140	10	32	all	all	DET
eurjchem-1140	10	33	complexes	complex	NOUN
eurjchem-1140	10	34	.	.	PUNCT
eurjchem-1140	11	1	keywords	keyword	NOUN
eurjchem-1140	11	2	schiff	schiff	VERB
eurjchem-1140	11	3	base	base	PROPN
eurjchem-1140	11	4	quinoxaline	quinoxaline	PROPN
eurjchem-1140	11	5	benzopyrazine	benzopyrazine	VERB
eurjchem-1140	11	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-1140	11	7	quinoxalin‐2,3‐dione	quinoxalin‐2,3‐dione	NOUN
eurjchem-1140	11	8	transition	transition	NOUN
eurjchem-1140	11	9	metal	metal	NOUN
eurjchem-1140	11	10	complexes	complex	NOUN
eurjchem-1140	11	11	cite	cite	VERB
eurjchem-1140	11	12	this	this	PRON
eurjchem-1140	11	13	:	:	PUNCT
eurjchem-1140	11	14	eur	eur	PROPN
eurjchem-1140	11	15	.	.	PUNCT
eurjchem-1140	12	1	j.	j.	PROPN
eurjchem-1140	12	2	chem	chem	PROPN
eurjchem-1140	12	3	.	.	PUNCT
eurjchem-1140	13	1	2015	2015	NUM
eurjchem-1140	13	2	,	,	PUNCT
eurjchem-1140	13	3	6(1	6(1	NUM
eurjchem-1140	13	4	)	)	PUNCT
eurjchem-1140	14	1	,	,	PUNCT
eurjchem-1140	14	2	44‐47	44‐47	X
eurjchem-1140	14	3	1	1	NUM
eurjchem-1140	14	4	.	.	PUNCT
eurjchem-1140	14	5	introduction	introduction	NOUN
eurjchem-1140	14	6	schiff	schiff	NOUN
eurjchem-1140	14	7	bases	basis	NOUN
eurjchem-1140	14	8	of	of	ADP
eurjchem-1140	14	9	quinoxalines	quinoxaline	NOUN
eurjchem-1140	14	10	and	and	CCONJ
eurjchem-1140	14	11	benzopyrazines	benzopyrazine	NOUN
eurjchem-1140	14	12	have	have	AUX
eurjchem-1140	14	13	been	be	AUX
eurjchem-1140	14	14	extensively	extensively	ADV
eurjchem-1140	14	15	studied	study	VERB
eurjchem-1140	14	16	for	for	ADP
eurjchem-1140	14	17	biological	biological	ADJ
eurjchem-1140	14	18	applications	application	NOUN
eurjchem-1140	14	19	,	,	PUNCT
eurjchem-1140	14	20	such	such	ADJ
eurjchem-1140	14	21	as	as	ADP
eurjchem-1140	14	22	anti‐	anti‐	PROPN
eurjchem-1140	14	23	microbial	microbial	NOUN
eurjchem-1140	14	24	[	[	X
eurjchem-1140	14	25	1‐3	1‐3	NOUN
eurjchem-1140	14	26	]	]	PUNCT
eurjchem-1140	14	27	,	,	PUNCT
eurjchem-1140	14	28	insecticidal	insecticidal	NOUN
eurjchem-1140	14	29	[	[	X
eurjchem-1140	14	30	4	4	NUM
eurjchem-1140	14	31	]	]	PUNCT
eurjchem-1140	14	32	,	,	PUNCT
eurjchem-1140	14	33	anti‐hiv	anti‐hiv	PROPN
eurjchem-1140	15	1	[	[	X
eurjchem-1140	15	2	5	5	NUM
eurjchem-1140	15	3	]	]	PUNCT
eurjchem-1140	15	4	,	,	PUNCT
eurjchem-1140	15	5	antitumor	antitumor	PROPN
eurjchem-1140	16	1	[	[	X
eurjchem-1140	16	2	6	6	NUM
eurjchem-1140	16	3	]	]	PUNCT
eurjchem-1140	16	4	,	,	PUNCT
eurjchem-1140	16	5	and	and	CCONJ
eurjchem-1140	16	6	in	in	ADP
eurjchem-1140	16	7	vitro	vitro	X
eurjchem-1140	16	8	cytotoxic	cytotoxic	ADJ
eurjchem-1140	16	9	activities	activity	NOUN
eurjchem-1140	16	10	[	[	X
eurjchem-1140	16	11	7,8	7,8	NUM
eurjchem-1140	16	12	]	]	PUNCT
eurjchem-1140	16	13	.	.	PUNCT
eurjchem-1140	17	1	the	the	DET
eurjchem-1140	17	2	quinoxaline‐based	quinoxaline‐base	VERB
eurjchem-1140	17	3	schiff	schiff	NOUN
eurjchem-1140	17	4	bases	basis	NOUN
eurjchem-1140	17	5	were	be	AUX
eurjchem-1140	17	6	synthesized	synthesize	VERB
eurjchem-1140	17	7	and	and	CCONJ
eurjchem-1140	17	8	characterized	characterize	VERB
eurjchem-1140	17	9	by	by	ADP
eurjchem-1140	17	10	several	several	ADJ
eurjchem-1140	17	11	workers	worker	NOUN
eurjchem-1140	17	12	[	[	X
eurjchem-1140	17	13	9	9	NUM
eurjchem-1140	17	14	]	]	PUNCT
eurjchem-1140	17	15	.	.	PUNCT
eurjchem-1140	18	1	the	the	DET
eurjchem-1140	18	2	synthesis	synthesis	NOUN
eurjchem-1140	18	3	and	and	CCONJ
eurjchem-1140	18	4	catalytic	catalytic	ADJ
eurjchem-1140	18	5	activity	activity	NOUN
eurjchem-1140	18	6	of	of	ADP
eurjchem-1140	18	7	metal	metal	NOUN
eurjchem-1140	18	8	complexes	complex	NOUN
eurjchem-1140	18	9	derived	derive	VERB
eurjchem-1140	18	10	from	from	ADP
eurjchem-1140	18	11	quinoxalin‐2‐carboxaldehyde	quinoxalin‐2‐carboxaldehyde	NUM
eurjchem-1140	18	12	schiff	schiff	NOUN
eurjchem-1140	18	13	bases	basis	NOUN
eurjchem-1140	18	14	on	on	ADP
eurjchem-1140	18	15	the	the	DET
eurjchem-1140	18	16	oxidation	oxidation	NOUN
eurjchem-1140	18	17	of	of	ADP
eurjchem-1140	18	18	cyclohexane	cyclohexane	NOUN
eurjchem-1140	18	19	was	be	AUX
eurjchem-1140	18	20	reported	report	VERB
eurjchem-1140	18	21	by	by	ADP
eurjchem-1140	18	22	sebastian	sebastian	PROPN
eurjchem-1140	18	23	[	[	X
eurjchem-1140	18	24	10	10	NUM
eurjchem-1140	18	25	]	]	PUNCT
eurjchem-1140	18	26	.	.	PUNCT
eurjchem-1140	19	1	two	two	NUM
eurjchem-1140	19	2	bis‐azomethine	bis‐azomethine	NUM
eurjchem-1140	19	3	derived	derive	VERB
eurjchem-1140	19	4	from	from	ADP
eurjchem-1140	19	5	quinoxaline‐	quinoxaline‐	PROPN
eurjchem-1140	19	6	2‐carboxaldehyde	2‐carboxaldehyde	NUM
eurjchem-1140	19	7	were	be	AUX
eurjchem-1140	19	8	investigated	investigate	VERB
eurjchem-1140	19	9	on	on	ADP
eurjchem-1140	19	10	the	the	DET
eurjchem-1140	19	11	basis	basis	NOUN
eurjchem-1140	19	12	of	of	ADP
eurjchem-1140	19	13	x‐ray	x‐ray	ADJ
eurjchem-1140	19	14	crystallography	crystallography	NOUN
eurjchem-1140	19	15	by	by	ADP
eurjchem-1140	19	16	varghese	varghese	PROPN
eurjchem-1140	19	17	d.	d.	PROPN
eurjchem-1140	19	18	and	and	CCONJ
eurjchem-1140	19	19	coworkers	coworker	NOUN
eurjchem-1140	19	20	[	[	X
eurjchem-1140	19	21	11	11	NUM
eurjchem-1140	19	22	]	]	PUNCT
eurjchem-1140	19	23	.	.	PUNCT
eurjchem-1140	20	1	a	a	DET
eurjchem-1140	20	2	new	new	ADJ
eurjchem-1140	20	3	schiff	schiff	NOUN
eurjchem-1140	20	4	base	base	NOUN
eurjchem-1140	20	5	derived	derive	VERB
eurjchem-1140	20	6	from	from	ADP
eurjchem-1140	20	7	quinoxaline‐2‐carboxaldehyde	quinoxaline‐2‐carboxaldehyde	NUM
eurjchem-1140	20	8	and	and	CCONJ
eurjchem-1140	20	9	2‐	2‐	NUM
eurjchem-1140	20	10	aminocyclopent‐1‐ene‐1‐dithiocarboxylic	aminocyclopent‐1‐ene‐1‐dithiocarboxylic	NOUN
eurjchem-1140	20	11	acid	acid	NOUN
eurjchem-1140	20	12	and	and	CCONJ
eurjchem-1140	20	13	its	its	PRON
eurjchem-1140	20	14	fe(iii	fe(iii	NOUN
eurjchem-1140	20	15	)	)	PUNCT
eurjchem-1140	20	16	,	,	PUNCT
eurjchem-1140	20	17	co(ii	co(ii	PROPN
eurjchem-1140	20	18	)	)	PUNCT
eurjchem-1140	20	19	,	,	PUNCT
eurjchem-1140	20	20	ni(ii	ni(ii	PROPN
eurjchem-1140	20	21	)	)	PUNCT
eurjchem-1140	20	22	,	,	PUNCT
eurjchem-1140	20	23	and	and	CCONJ
eurjchem-1140	20	24	cu(ii	cu(ii	PROPN
eurjchem-1140	20	25	)	)	PUNCT
eurjchem-1140	20	26	complexes	complex	NOUN
eurjchem-1140	20	27	were	be	AUX
eurjchem-1140	20	28	synthesized	synthesize	VERB
eurjchem-1140	20	29	and	and	CCONJ
eurjchem-1140	20	30	characterized	characterize	VERB
eurjchem-1140	20	31	by	by	ADP
eurjchem-1140	20	32	various	various	ADJ
eurjchem-1140	20	33	spectral	spectral	ADJ
eurjchem-1140	20	34	and	and	CCONJ
eurjchem-1140	20	35	analytical	analytical	ADJ
eurjchem-1140	20	36	techniques	technique	NOUN
eurjchem-1140	20	37	[	[	X
eurjchem-1140	20	38	12	12	NUM
eurjchem-1140	20	39	]	]	PUNCT
eurjchem-1140	20	40	.	.	PUNCT
eurjchem-1140	21	1	recently	recently	ADV
eurjchem-1140	21	2	,	,	PUNCT
eurjchem-1140	21	3	new	new	ADJ
eurjchem-1140	21	4	co(iii	co(iii	NOUN
eurjchem-1140	21	5	)	)	PUNCT
eurjchem-1140	21	6	,	,	PUNCT
eurjchem-1140	21	7	ni(ii	ni(ii	PROPN
eurjchem-1140	21	8	)	)	PUNCT
eurjchem-1140	21	9	,	,	PUNCT
eurjchem-1140	21	10	and	and	CCONJ
eurjchem-1140	21	11	cu(ii	cu(ii	ADJ
eurjchem-1140	21	12	)	)	PUNCT
eurjchem-1140	21	13	complexes	complex	NOUN
eurjchem-1140	21	14	of	of	ADP
eurjchem-1140	21	15	schiff	schiff	NOUN
eurjchem-1140	21	16	bases	basis	NOUN
eurjchem-1140	21	17	derived	derive	VERB
eurjchem-1140	21	18	from	from	ADP
eurjchem-1140	21	19	4‐phenyl(‐methyl)‐thiosemicar‐	4‐phenyl(‐methyl)‐thiosemicar‐	NOUN
eurjchem-1140	21	20	bazone‐bases	bazone‐base	NOUN
eurjchem-1140	21	21	qunioxaline(1h,2h)‐2,3‐dione	qunioxaline(1h,2h)‐2,3‐dione	NOUN
eurjchem-1140	21	22	have	have	AUX
eurjchem-1140	21	23	been	be	AUX
eurjchem-1140	21	24	prepared	prepare	VERB
eurjchem-1140	21	25	and	and	CCONJ
eurjchem-1140	21	26	antimicrobial	antimicrobial	ADJ
eurjchem-1140	21	27	studied	study	VERB
eurjchem-1140	21	28	.	.	PUNCT
eurjchem-1140	22	1	the	the	DET
eurjchem-1140	22	2	ligands	ligand	NOUN
eurjchem-1140	22	3	were	be	AUX
eurjchem-1140	22	4	a	a	DET
eurjchem-1140	22	5	monobasic	monobasic	ADJ
eurjchem-1140	22	6	tridentate	tridentate	NOUN
eurjchem-1140	22	7	nns	nns	NOUN
eurjchem-1140	22	8	donor	donor	NOUN
eurjchem-1140	22	9	in	in	ADP
eurjchem-1140	22	10	the	the	DET
eurjchem-1140	22	11	co(ii	co(ii	PROPN
eurjchem-1140	22	12	)	)	PUNCT
eurjchem-1140	22	13	and	and	CCONJ
eurjchem-1140	22	14	cu(ii	cu(ii	PROPN
eurjchem-1140	22	15	)	)	PUNCT
eurjchem-1140	22	16	complexes	complex	NOUN
eurjchem-1140	22	17	and	and	CCONJ
eurjchem-1140	22	18	neutral	neutral	ADJ
eurjchem-1140	22	19	bi	bi	ADJ
eurjchem-1140	22	20	dentate	dentate	NOUN
eurjchem-1140	22	21	nitrogen	nitrogen	NOUN
eurjchem-1140	22	22	and	and	CCONJ
eurjchem-1140	22	23	sulphur	sulphur	NOUN
eurjchem-1140	22	24	donor	donor	NOUN
eurjchem-1140	22	25	in	in	ADP
eurjchem-1140	22	26	the	the	DET
eurjchem-1140	22	27	ni(ii	ni(ii	PROPN
eurjchem-1140	22	28	)	)	PUNCT
eurjchem-1140	22	29	complex	complex	NOUN
eurjchem-1140	22	30	.	.	PUNCT
eurjchem-1140	23	1	the	the	DET
eurjchem-1140	23	2	cytotoxicity	cytotoxicity	NOUN
eurjchem-1140	23	3	of	of	ADP
eurjchem-1140	23	4	co(iii	co(iii	NOUN
eurjchem-1140	23	5	)	)	PUNCT
eurjchem-1140	23	6	complex	complex	NOUN
eurjchem-1140	23	7	was	be	AUX
eurjchem-1140	23	8	determined	determine	VERB
eurjchem-1140	23	9	in‐vitro	in‐vitro	VERB
eurjchem-1140	23	10	as	as	ADV
eurjchem-1140	23	11	well	well	ADV
eurjchem-1140	23	12	as	as	ADP
eurjchem-1140	23	13	in	in	ADP
eurjchem-1140	23	14	tissue	tissue	NOUN
eurjchem-1140	23	15	culture	culture	NOUN
eurjchem-1140	23	16	methods	method	NOUN
eurjchem-1140	23	17	[	[	X
eurjchem-1140	23	18	13	13	NUM
eurjchem-1140	23	19	]	]	PUNCT
eurjchem-1140	23	20	.	.	PUNCT
eurjchem-1140	24	1	al‐jibouri	al‐jibouri	PROPN
eurjchem-1140	24	2	,	,	PUNCT
eurjchem-1140	24	3	m.n	m.n	PROPN
eurjchem-1140	24	4	.	.	PROPN
eurjchem-1140	24	5	has	have	AUX
eurjchem-1140	24	6	reported	report	VERB
eurjchem-1140	24	7	the	the	DET
eurjchem-1140	24	8	synthesis	synthesis	NOUN
eurjchem-1140	24	9	,	,	PUNCT
eurjchem-1140	24	10	characterization	characterization	NOUN
eurjchem-1140	24	11	and	and	CCONJ
eurjchem-1140	24	12	antimicrobial	antimicrobial	ADJ
eurjchem-1140	24	13	activity	activity	NOUN
eurjchem-1140	24	14	of	of	ADP
eurjchem-1140	24	15	template	template	NOUN
eurjchem-1140	24	16	metal	metal	NOUN
eurjchem-1140	24	17	complexes	complex	NOUN
eurjchem-1140	24	18	derived	derive	VERB
eurjchem-1140	24	19	from	from	ADP
eurjchem-1140	24	20	quinoxaline‐2,3‐dione	quinoxaline‐2,3‐dione	PROPN
eurjchem-1140	24	21	[	[	X
eurjchem-1140	24	22	14	14	NUM
eurjchem-1140	24	23	]	]	PUNCT
eurjchem-1140	24	24	.	.	PUNCT
eurjchem-1140	25	1	satish	satish	PROPN
eurjchem-1140	25	2	m.a	m.a	PROPN
eurjchem-1140	25	3	.	.	PROPN
eurjchem-1140	25	4	and	and	CCONJ
eurjchem-1140	25	5	coworkers	coworker	NOUN
eurjchem-1140	25	6	have	have	AUX
eurjchem-1140	25	7	reported	report	VERB
eurjchem-1140	25	8	synthesis	synthesis	NOUN
eurjchem-1140	25	9	and	and	CCONJ
eurjchem-1140	25	10	spectroscopic	spectroscopic	NOUN
eurjchem-1140	25	11	of	of	ADP
eurjchem-1140	25	12	binuclear	binuclear	ADJ
eurjchem-1140	25	13	metal	metal	NOUN
eurjchem-1140	25	14	complexes	complex	NOUN
eurjchem-1140	25	15	with	with	ADP
eurjchem-1140	25	16	acyclic	acyclic	ADJ
eurjchem-1140	25	17	polydentate	polydentate	ADJ
eurjchem-1140	25	18	schiff	schiff	NOUN
eurjchem-1140	25	19	base	base	NOUN
eurjchem-1140	25	20	derived	derive	VERB
eurjchem-1140	25	21	from	from	ADP
eurjchem-1140	25	22	quinoxaline‐2,3‐dione	quinoxaline‐2,3‐dione	NOUN
eurjchem-1140	25	23	[	[	X
eurjchem-1140	25	24	15	15	NUM
eurjchem-1140	25	25	]	]	PUNCT
eurjchem-1140	25	26	.	.	PUNCT
eurjchem-1140	26	1	the	the	DET
eurjchem-1140	26	2	present	present	ADJ
eurjchem-1140	26	3	work	work	NOUN
eurjchem-1140	26	4	described	describe	VERB
eurjchem-1140	26	5	the	the	DET
eurjchem-1140	26	6	synthesis	synthesis	NOUN
eurjchem-1140	26	7	and	and	CCONJ
eurjchem-1140	26	8	characterization	characterization	NOUN
eurjchem-1140	26	9	of	of	ADP
eurjchem-1140	26	10	new	new	ADJ
eurjchem-1140	26	11	metal	metal	NOUN
eurjchem-1140	26	12	complexes	complex	NOUN
eurjchem-1140	26	13	of	of	ADP
eurjchem-1140	26	14	mn(ii	mn(ii	PROPN
eurjchem-1140	26	15	)	)	PUNCT
eurjchem-1140	26	16	,	,	PUNCT
eurjchem-1140	26	17	co(ii	co(ii	PROPN
eurjchem-1140	26	18	)	)	PUNCT
eurjchem-1140	26	19	,	,	PUNCT
eurjchem-1140	26	20	ni(ii	ni(ii	PROPN
eurjchem-1140	26	21	)	)	PUNCT
eurjchem-1140	26	22	,	,	PUNCT
eurjchem-1140	26	23	co(ii	co(ii	PROPN
eurjchem-1140	26	24	)	)	PUNCT
eurjchem-1140	26	25	and	and	CCONJ
eurjchem-1140	26	26	zn(ii	zn(ii	NOUN
eurjchem-1140	26	27	)	)	PUNCT
eurjchem-1140	26	28	with	with	ADP
eurjchem-1140	26	29	new	new	ADJ
eurjchem-1140	26	30	schiff	schiff	NOUN
eurjchem-1140	26	31	base	base	NOUN
eurjchem-1140	26	32	involving	involve	VERB
eurjchem-1140	26	33	quinoxlin‐2,3‐dion‐thiosemicarbazide	quinoxlin‐2,3‐dion‐thiosemicarbazide	NOUN
eurjchem-1140	26	34	.	.	PUNCT
eurjchem-1140	27	1	2	2	X
eurjchem-1140	27	2	.	.	X
eurjchem-1140	27	3	experimental	experimental	ADJ
eurjchem-1140	27	4	2.1	2.1	NUM
eurjchem-1140	27	5	.	.	PUNCT
eurjchem-1140	28	1	instrumentation	instrumentation	NOUN
eurjchem-1140	28	2	elemental	elemental	ADJ
eurjchem-1140	28	3	analyses	analysis	NOUN
eurjchem-1140	28	4	(	(	PUNCT
eurjchem-1140	28	5	chns	chns	NOUN
eurjchem-1140	28	6	)	)	PUNCT
eurjchem-1140	28	7	of	of	ADP
eurjchem-1140	28	8	the	the	DET
eurjchem-1140	28	9	new	new	ADJ
eurjchem-1140	28	10	schiff	schiff	NOUN
eurjchem-1140	28	11	base	base	NOUN
eurjchem-1140	28	12	hl	hl	NOUN
eurjchem-1140	28	13	and	and	CCONJ
eurjchem-1140	28	14	its	its	PRON
eurjchem-1140	28	15	metal(ii	metal(ii	NOUN
eurjchem-1140	28	16	)	)	PUNCT
eurjchem-1140	28	17	complexes	complex	NOUN
eurjchem-1140	28	18	were	be	AUX
eurjchem-1140	28	19	determined	determine	VERB
eurjchem-1140	28	20	using	use	VERB
eurjchem-1140	28	21	euro	euro	PROPN
eurjchem-1140	28	22	ea	ea	X
eurjchem-1140	28	23	elemental	elemental	ADJ
eurjchem-1140	28	24	analyzer	analyzer	NOUN
eurjchem-1140	28	25	(	(	PUNCT
eurjchem-1140	28	26	italy	italy	PROPN
eurjchem-1140	28	27	model	model	PROPN
eurjchem-1140	28	28	)	)	PUNCT
eurjchem-1140	28	29	.	.	PUNCT
eurjchem-1140	29	1	the	the	DET
eurjchem-1140	29	2	electronic	electronic	ADJ
eurjchem-1140	29	3	spectra	spectra	NOUN
eurjchem-1140	29	4	of	of	ADP
eurjchem-1140	29	5	the	the	DET
eurjchem-1140	29	6	prepared	prepare	VERB
eurjchem-1140	29	7	compounds	compound	NOUN
eurjchem-1140	29	8	were	be	AUX
eurjchem-1140	29	9	recorded	record	VERB
eurjchem-1140	29	10	using	use	VERB
eurjchem-1140	29	11	cary	cary	PROPN
eurjchem-1140	29	12	varian	varian	PROPN
eurjchem-1140	29	13	uv‐	uv‐	PROPN
eurjchem-1140	29	14	visible	visible	ADJ
eurjchem-1140	29	15	spectrometer	spectrometer	NOUN
eurjchem-1140	29	16	in	in	ADP
eurjchem-1140	29	17	the	the	DET
eurjchem-1140	29	18	range	range	NOUN
eurjchem-1140	29	19	200‐800	200‐800	NUM
eurjchem-1140	29	20	nm	nm	NOUN
eurjchem-1140	29	21	in	in	ADP
eurjchem-1140	29	22	ethanol	ethanol	NOUN
eurjchem-1140	29	23	and	and	CCONJ
eurjchem-1140	29	24	n	n	CCONJ
eurjchem-1140	29	25	,	,	PUNCT
eurjchem-1140	29	26	n‐dimethylformamide	n‐dimethylformamide	X
eurjchem-1140	29	27	(	(	PUNCT
eurjchem-1140	29	28	dmf	dmf	NOUN
eurjchem-1140	29	29	)	)	PUNCT
eurjchem-1140	29	30	solvents	solvent	NOUN
eurjchem-1140	29	31	.	.	PUNCT
eurjchem-1140	30	1	al‐jibouri	al‐jibouri	PROPN
eurjchem-1140	30	2	and	and	CCONJ
eurjchem-1140	30	3	hasun	hasun	PROPN
eurjchem-1140	30	4	/	/	SYM
eurjchem-1140	30	5	european	european	PROPN
eurjchem-1140	30	6	journal	journal	PROPN
eurjchem-1140	30	7	of	of	ADP
eurjchem-1140	30	8	chemistry	chemistry	NOUN
eurjchem-1140	30	9	6	6	NUM
eurjchem-1140	30	10	(	(	PUNCT
eurjchem-1140	30	11	1	1	NUM
eurjchem-1140	30	12	)	)	PUNCT
eurjchem-1140	30	13	(	(	PUNCT
eurjchem-1140	30	14	2015	2015	NUM
eurjchem-1140	30	15	)	)	PUNCT
eurjchem-1140	30	16	44‐47	44‐47	NOUN
eurjchem-1140	30	17	45	45	NUM
eurjchem-1140	30	18	scheme	scheme	NOUN
eurjchem-1140	30	19	1	1	NUM
eurjchem-1140	30	20	scheme	scheme	NOUN
eurjchem-1140	30	21	2	2	NUM
eurjchem-1140	30	22	the	the	DET
eurjchem-1140	30	23	1h	1h	NUM
eurjchem-1140	30	24	and	and	CCONJ
eurjchem-1140	30	25	13c	13c	NOUN
eurjchem-1140	30	26	nmr	nmr	NOUN
eurjchem-1140	30	27	spectra	spectra	NOUN
eurjchem-1140	30	28	were	be	AUX
eurjchem-1140	30	29	carried	carry	VERB
eurjchem-1140	30	30	at	at	ADP
eurjchem-1140	30	31	al‐yarmook	al‐yarmook	PROPN
eurjchem-1140	30	32	university	university	PROPN
eurjchem-1140	30	33	,	,	PUNCT
eurjchem-1140	30	34	amman	amman	NOUN
eurjchem-1140	30	35	on	on	ADP
eurjchem-1140	30	36	bruker	bruker	PROPN
eurjchem-1140	30	37	300	300	NUM
eurjchem-1140	30	38	mhz	mhz	NOUN
eurjchem-1140	30	39	spectrometer	spectrometer	NOUN
eurjchem-1140	30	40	in	in	ADP
eurjchem-1140	30	41	dmso‐d6	dmso‐d6	PROPN
eurjchem-1140	30	42	solvent	solvent	NOUN
eurjchem-1140	30	43	.	.	PUNCT
eurjchem-1140	31	1	the	the	DET
eurjchem-1140	31	2	fourier	fourier	NOUN
eurjchem-1140	31	3	transform	transform	NOUN
eurjchem-1140	31	4	infrared	infrared	ADJ
eurjchem-1140	31	5	spectra	spectra	NOUN
eurjchem-1140	31	6	of	of	ADP
eurjchem-1140	31	7	the	the	DET
eurjchem-1140	31	8	prepared	prepare	VERB
eurjchem-1140	31	9	complexes	complex	NOUN
eurjchem-1140	31	10	were	be	AUX
eurjchem-1140	31	11	recorded	record	VERB
eurjchem-1140	31	12	in	in	ADP
eurjchem-1140	31	13	kbr	kbr	PROPN
eurjchem-1140	31	14	and	and	CCONJ
eurjchem-1140	31	15	csi	csi	ADJ
eurjchem-1140	31	16	discs	disc	NOUN
eurjchem-1140	31	17	on	on	ADP
eurjchem-1140	31	18	shimadzu	shimadzu	ADJ
eurjchem-1140	31	19	model	model	NOUN
eurjchem-1140	31	20	ft‐ir‐8400	ft‐ir‐8400	NOUN
eurjchem-1140	31	21	spectrometer	spectrometer	NOUN
eurjchem-1140	31	22	at	at	ADP
eurjchem-1140	31	23	the	the	DET
eurjchem-1140	31	24	laboratories	laboratory	NOUN
eurjchem-1140	31	25	of	of	ADP
eurjchem-1140	31	26	chemistry	chemistry	NOUN
eurjchem-1140	31	27	department	department	NOUN
eurjchem-1140	31	28	,	,	PUNCT
eurjchem-1140	31	29	college	college	NOUN
eurjchem-1140	31	30	of	of	ADP
eurjchem-1140	31	31	science	science	NOUN
eurjchem-1140	31	32	,	,	PUNCT
eurjchem-1140	31	33	al‐mustansirya	al‐mustansirya	PROPN
eurjchem-1140	31	34	university	university	PROPN
eurjchem-1140	31	35	,	,	PUNCT
eurjchem-1140	31	36	iraq	iraq	PROPN
eurjchem-1140	31	37	.	.	PUNCT
eurjchem-1140	32	1	the	the	DET
eurjchem-1140	32	2	molar	molar	ADJ
eurjchem-1140	32	3	conductance	conductance	NOUN
eurjchem-1140	32	4	measurements	measurement	NOUN
eurjchem-1140	32	5	were	be	AUX
eurjchem-1140	32	6	made	make	VERB
eurjchem-1140	32	7	on	on	ADP
eurjchem-1140	32	8	philips	philip	NOUN
eurjchem-1140	32	9	conductivity	conductivity	NOUN
eurjchem-1140	32	10	bridge	bridge	NOUN
eurjchem-1140	32	11	type	type	NOUN
eurjchem-1140	32	12	cm‐82	cm‐82	PROPN
eurjchem-1140	32	13	with	with	ADP
eurjchem-1140	32	14	a	a	DET
eurjchem-1140	32	15	cell	cell	NOUN
eurjchem-1140	32	16	having	have	VERB
eurjchem-1140	32	17	a	a	DET
eurjchem-1140	32	18	cell	cell	NOUN
eurjchem-1140	32	19	constant	constant	ADJ
eurjchem-1140	32	20	of	of	ADP
eurjchem-1140	32	21	1.1	1.1	NUM
eurjchem-1140	32	22	cm‐1	cm‐1	NOUN
eurjchem-1140	32	23	in	in	ADP
eurjchem-1140	32	24	dmso	dmso	ADJ
eurjchem-1140	32	25	solutions	solution	NOUN
eurjchem-1140	32	26	.	.	PUNCT
eurjchem-1140	33	1	the	the	DET
eurjchem-1140	33	2	percent	percent	NOUN
eurjchem-1140	33	3	of	of	ADP
eurjchem-1140	33	4	metal	metal	NOUN
eurjchem-1140	33	5	contents	content	NOUN
eurjchem-1140	33	6	of	of	ADP
eurjchem-1140	33	7	the	the	DET
eurjchem-1140	33	8	complexes	complex	NOUN
eurjchem-1140	33	9	were	be	AUX
eurjchem-1140	33	10	determined	determine	VERB
eurjchem-1140	33	11	by	by	ADP
eurjchem-1140	33	12	flame	flame	NOUN
eurjchem-1140	33	13	atomic	atomic	ADJ
eurjchem-1140	33	14	absorption	absorption	NOUN
eurjchem-1140	33	15	on	on	ADP
eurjchem-1140	33	16	shimadzu	shimadzu	ADJ
eurjchem-1140	33	17	a.a‐670	a.a‐670	NOUN
eurjchem-1140	33	18	spectro‐	spectro‐	NOUN
eurjchem-1140	33	19	meter	meter	NOUN
eurjchem-1140	33	20	at	at	ADP
eurjchem-1140	33	21	instrumental	instrumental	ADJ
eurjchem-1140	33	22	analyses	analysis	NOUN
eurjchem-1140	33	23	laboratory	laboratory	NOUN
eurjchem-1140	33	24	,	,	PUNCT
eurjchem-1140	33	25	chemistry	chemistry	NOUN
eurjchem-1140	33	26	depart‐	depart‐	VERB
eurjchem-1140	33	27	ment	ment	PROPN
eurjchem-1140	33	28	,	,	PUNCT
eurjchem-1140	33	29	al‐mustansiriya	al‐mustansiriya	PROPN
eurjchem-1140	33	30	university	university	PROPN
eurjchem-1140	33	31	,	,	PUNCT
eurjchem-1140	33	32	baghdad	baghdad	PROPN
eurjchem-1140	33	33	,	,	PUNCT
eurjchem-1140	33	34	iraq	iraq	PROPN
eurjchem-1140	33	35	.	.	PUNCT
eurjchem-1140	34	1	the	the	DET
eurjchem-1140	34	2	magnetic	magnetic	ADJ
eurjchem-1140	34	3	susceptibility	susceptibility	NOUN
eurjchem-1140	34	4	of	of	ADP
eurjchem-1140	34	5	the	the	DET
eurjchem-1140	34	6	solid	solid	ADJ
eurjchem-1140	34	7	metal	metal	NOUN
eurjchem-1140	34	8	complexes	complex	NOUN
eurjchem-1140	34	9	was	be	AUX
eurjchem-1140	34	10	measured	measure	VERB
eurjchem-1140	34	11	on	on	ADP
eurjchem-1140	34	12	sherewood	sherewood	PROPN
eurjchem-1140	34	13	magnetic	magnetic	ADJ
eurjchem-1140	34	14	balance	balance	NOUN
eurjchem-1140	34	15	apparatus	apparatus	NOUN
eurjchem-1140	34	16	at	at	ADP
eurjchem-1140	34	17	inorganic	inorganic	ADJ
eurjchem-1140	34	18	chemistry	chemistry	NOUN
eurjchem-1140	34	19	laboratory	laboratory	NOUN
eurjchem-1140	34	20	for	for	ADP
eurjchem-1140	34	21	post	post	NOUN
eurjchem-1140	34	22	graduate	graduate	ADJ
eurjchem-1140	34	23	students	student	NOUN
eurjchem-1140	34	24	via	via	ADP
eurjchem-1140	34	25	farady	farady	PROPN
eurjchem-1140	34	26	's	's	PART
eurjchem-1140	34	27	method	method	NOUN
eurjchem-1140	34	28	at	at	ADP
eurjchem-1140	34	29	303	303	NUM
eurjchem-1140	34	30	k.	k.	NOUN
eurjchem-1140	34	31	2.2	2.2	NUM
eurjchem-1140	34	32	.	.	PUNCT
eurjchem-1140	35	1	materials	material	NOUN
eurjchem-1140	35	2	the	the	DET
eurjchem-1140	35	3	hydrated	hydrated	ADJ
eurjchem-1140	35	4	metal	metal	NOUN
eurjchem-1140	35	5	chlorides	chloride	VERB
eurjchem-1140	35	6	mncl2·4h2o	mncl2·4h2o	NOUN
eurjchem-1140	35	7	,	,	PUNCT
eurjchem-1140	35	8	cocl2·6h2o	cocl2·6h2o	NOUN
eurjchem-1140	35	9	,	,	PUNCT
eurjchem-1140	35	10	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-1140	35	11	,	,	PUNCT
eurjchem-1140	35	12	cucl2·2h2o	cucl2·2h2o	NOUN
eurjchem-1140	35	13	and	and	CCONJ
eurjchem-1140	35	14	zncl2	zncl2	NOUN
eurjchem-1140	35	15	were	be	AUX
eurjchem-1140	35	16	provided	provide	VERB
eurjchem-1140	35	17	from	from	ADP
eurjchem-1140	35	18	sigma‐	sigma‐	PROPN
eurjchem-1140	35	19	aldrich	aldrich	PROPN
eurjchem-1140	35	20	company	company	PROPN
eurjchem-1140	35	21	and	and	CCONJ
eurjchem-1140	35	22	used	use	VERB
eurjchem-1140	35	23	without	without	ADP
eurjchem-1140	35	24	purification	purification	NOUN
eurjchem-1140	35	25	.	.	PUNCT
eurjchem-1140	36	1	the	the	DET
eurjchem-1140	36	2	oxalic	oxalic	NOUN
eurjchem-1140	36	3	acid	acid	NOUN
eurjchem-1140	36	4	,	,	PUNCT
eurjchem-1140	36	5	4,5‐dimethyl,1,2‐phenylenediamine	4,5‐dimethyl,1,2‐phenylenediamine	NUM
eurjchem-1140	36	6	and	and	CCONJ
eurjchem-1140	36	7	solvents	solvent	NOUN
eurjchem-1140	36	8	were	be	AUX
eurjchem-1140	36	9	supplied	supply	VERB
eurjchem-1140	36	10	from	from	ADP
eurjchem-1140	36	11	fluka	fluka	PROPN
eurjchem-1140	36	12	company	company	NOUN
eurjchem-1140	36	13	in	in	ADP
eurjchem-1140	36	14	99	99	NUM
eurjchem-1140	36	15	%	%	NOUN
eurjchem-1140	36	16	purity	purity	NOUN
eurjchem-1140	36	17	.	.	PUNCT
eurjchem-1140	37	1	all	all	DET
eurjchem-1140	37	2	other	other	ADJ
eurjchem-1140	37	3	chemicals	chemical	NOUN
eurjchem-1140	37	4	used	use	VERB
eurjchem-1140	37	5	were	be	AUX
eurjchem-1140	37	6	of	of	ADP
eurjchem-1140	37	7	analar	analar	ADJ
eurjchem-1140	37	8	grade	grade	NOUN
eurjchem-1140	37	9	.	.	PUNCT
eurjchem-1140	38	1	2.3	2.3	NUM
eurjchem-1140	38	2	.	.	PUNCT
eurjchem-1140	39	1	methods	method	NOUN
eurjchem-1140	39	2	2.3.1	2.3.1	NUM
eurjchem-1140	39	3	.	.	PUNCT
eurjchem-1140	39	4	synthesis	synthesis	NOUN
eurjchem-1140	39	5	of	of	ADP
eurjchem-1140	39	6	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐	PROPN
eurjchem-1140	39	7	dione	dione	NOUN
eurjchem-1140	39	8	(	(	PUNCT
eurjchem-1140	39	9	dmq	dmq	PROPN
eurjchem-1140	39	10	)	)	PUNCT
eurjchem-1140	39	11	the	the	DET
eurjchem-1140	39	12	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐dione	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐dione	PROPN
eurjchem-1140	39	13	was	be	AUX
eurjchem-1140	39	14	pre‐	pre‐	NOUN
eurjchem-1140	39	15	pared	pare	VERB
eurjchem-1140	39	16	according	accord	VERB
eurjchem-1140	39	17	to	to	ADP
eurjchem-1140	39	18	the	the	DET
eurjchem-1140	39	19	published	publish	VERB
eurjchem-1140	39	20	method	method	NOUN
eurjchem-1140	39	21	in	in	ADP
eurjchem-1140	39	22	literature	literature	NOUN
eurjchem-1140	39	23	[	[	X
eurjchem-1140	39	24	14	14	NUM
eurjchem-1140	39	25	]	]	PUNCT
eurjchem-1140	39	26	,	,	PUNCT
eurjchem-1140	39	27	scheme	scheme	NOUN
eurjchem-1140	39	28	1	1	NUM
eurjchem-1140	39	29	.	.	PUNCT
eurjchem-1140	39	30	color	color	NOUN
eurjchem-1140	39	31	:	:	PUNCT
eurjchem-1140	39	32	white	white	VERB
eurjchem-1140	39	33	off	off	ADV
eurjchem-1140	39	34	.	.	PUNCT
eurjchem-1140	40	1	yield	yield	NOUN
eurjchem-1140	40	2	:	:	PUNCT
eurjchem-1140	40	3	95	95	NUM
eurjchem-1140	40	4	%	%	NOUN
eurjchem-1140	40	5	.	.	PUNCT
eurjchem-1140	41	1	m.p	m.p	PROPN
eurjchem-1140	41	2	.	.	PROPN
eurjchem-1140	41	3	:	:	PUNCT
eurjchem-1140	42	1	289‐291	289‐291	NUM
eurjchem-1140	42	2	°	°	ADP
eurjchem-1140	42	3	c	c	NOUN
eurjchem-1140	42	4	.	.	PUNCT
eurjchem-1140	43	1	ft‐ir	ft‐ir	NOUN
eurjchem-1140	43	2	(	(	PUNCT
eurjchem-1140	43	3	kbr	kbr	PROPN
eurjchem-1140	43	4	,	,	PUNCT
eurjchem-1140	43	5			PROPN
eurjchem-1140	43	6	,	,	PUNCT
eurjchem-1140	43	7	cm‐1	cm‐1	PROPN
eurjchem-1140	43	8	):	):	PUNCT
eurjchem-1140	43	9	3200‐3100	3200‐3100	NUM
eurjchem-1140	43	10	(	(	PUNCT
eurjchem-1140	43	11	nh	nh	NOUN
eurjchem-1140	43	12	)	)	PUNCT
eurjchem-1140	43	13	(	(	PUNCT
eurjchem-1140	43	14	quinoxalineamido	quinoxalineamido	PROPN
eurjchem-1140	43	15	)	)	PUNCT
eurjchem-1140	43	16	,	,	PUNCT
eurjchem-1140	43	17	1734	1734	NUM
eurjchem-1140	43	18	,	,	PUNCT
eurjchem-1140	43	19	(	(	PUNCT
eurjchem-1140	43	20	c	c	X
eurjchem-1140	43	21	=	=	NOUN
eurjchem-1140	43	22	o	o	NOUN
eurjchem-1140	43	23	)	)	PUNCT
eurjchem-1140	43	24	(	(	PUNCT
eurjchem-1140	43	25	lactam	lactam	NOUN
eurjchem-1140	43	26	)	)	PUNCT
eurjchem-1140	43	27	,	,	PUNCT
eurjchem-1140	43	28	1610	1610	NUM
eurjchem-1140	43	29	(	(	PUNCT
eurjchem-1140	43	30	‐c	‐c	NOUN
eurjchem-1140	43	31	=	=	NOUN
eurjchem-1140	43	32	n‐	n‐	NOUN
eurjchem-1140	43	33	)	)	PUNCT
eurjchem-1140	43	34	(	(	PUNCT
eurjchem-1140	43	35	amide	amide	NOUN
eurjchem-1140	43	36	pyrazine	pyrazine	NOUN
eurjchem-1140	43	37	)	)	PUNCT
eurjchem-1140	43	38	,	,	PUNCT
eurjchem-1140	43	39	1320(‐c‐n	1320(‐c‐n	NUM
eurjchem-1140	43	40	)	)	PUNCT
eurjchem-1140	43	41	(	(	PUNCT
eurjchem-1140	43	42	pyrazine	pyrazine	NOUN
eurjchem-1140	43	43	ring	ring	NOUN
eurjchem-1140	43	44	)	)	PUNCT
eurjchem-1140	43	45	.	.	PUNCT
eurjchem-1140	44	1	uv	uv	NOUN
eurjchem-1140	44	2	/	/	SYM
eurjchem-1140	44	3	vis	vis	X
eurjchem-1140	44	4	(	(	PUNCT
eurjchem-1140	44	5	methanol	methanol	NOUN
eurjchem-1140	44	6	,	,	PUNCT
eurjchem-1140	44	7	λmax	λmax	NOUN
eurjchem-1140	44	8	,	,	PUNCT
eurjchem-1140	44	9	nm	nm	NOUN
eurjchem-1140	44	10	,	,	PUNCT
eurjchem-1140	44	11	(	(	PUNCT
eurjchem-1140	44	12			PROPN
eurjchem-1140	44	13	)	)	PUNCT
eurjchem-1140	44	14	):	):	PUNCT
eurjchem-1140	44	15	330	330	NUM
eurjchem-1140	44	16	(	(	PUNCT
eurjchem-1140	44	17	4.77	4.77	NUM
eurjchem-1140	44	18	)	)	PUNCT
eurjchem-1140	44	19	,	,	PUNCT
eurjchem-1140	44	20	290	290	NUM
eurjchem-1140	44	21	(	(	PUNCT
eurjchem-1140	44	22	4.42	4.42	NUM
eurjchem-1140	44	23	)	)	PUNCT
eurjchem-1140	44	24	.	.	PUNCT
eurjchem-1140	45	1	1h	1h	NUM
eurjchem-1140	45	2	nmr	nmr	NOUN
eurjchem-1140	45	3	(	(	PUNCT
eurjchem-1140	45	4	300	300	NUM
eurjchem-1140	45	5	mhz	mhz	NOUN
eurjchem-1140	45	6	,	,	PUNCT
eurjchem-1140	45	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1140	45	8	,	,	PUNCT
eurjchem-1140	45	9	δ	δ	PROPN
eurjchem-1140	45	10	,	,	PUNCT
eurjchem-1140	45	11	ppm	ppm	NUM
eurjchem-1140	45	12	):	):	PUNCT
eurjchem-1140	45	13	3.09	3.09	NUM
eurjchem-1140	45	14	(	(	PUNCT
eurjchem-1140	45	15	s	s	PROPN
eurjchem-1140	45	16	,	,	PUNCT
eurjchem-1140	45	17	6h	6h	NUM
eurjchem-1140	45	18	,	,	PUNCT
eurjchem-1140	45	19	2ch3	2ch3	NUM
eurjchem-1140	45	20	)	)	PUNCT
eurjchem-1140	45	21	,	,	PUNCT
eurjchem-1140	45	22	7.66‐8.05	7.66‐8.05	NUM
eurjchem-1140	45	23	(	(	PUNCT
eurjchem-1140	45	24	m	m	PROPN
eurjchem-1140	45	25	,	,	PUNCT
eurjchem-1140	45	26	4h	4h	NUM
eurjchem-1140	45	27	,	,	PUNCT
eurjchem-1140	45	28	ar‐h+	ar‐h+	NOUN
eurjchem-1140	45	29	nh‐co	nh‐co	ADJ
eurjchem-1140	45	30	)	)	PUNCT
eurjchem-1140	45	31	.	.	PUNCT
eurjchem-1140	46	1	13c	13c	NOUN
eurjchem-1140	46	2	nmr	nmr	NOUN
eurjchem-1140	46	3	(	(	PUNCT
eurjchem-1140	46	4	300	300	NUM
eurjchem-1140	46	5	mhz	mhz	NOUN
eurjchem-1140	46	6	,	,	PUNCT
eurjchem-1140	46	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1140	46	8	,	,	PUNCT
eurjchem-1140	46	9	δ	δ	PROPN
eurjchem-1140	46	10	,	,	PUNCT
eurjchem-1140	46	11	ppm	ppm	NUM
eurjchem-1140	46	12	):	):	PUNCT
eurjchem-1140	46	13	160.32	160.32	NUM
eurjchem-1140	46	14	(	(	PUNCT
eurjchem-1140	46	15	2c	2c	NOUN
eurjchem-1140	46	16	,	,	PUNCT
eurjchem-1140	46	17	c	c	PROPN
eurjchem-1140	46	18	=	=	SYM
eurjchem-1140	46	19	o	o	NOUN
eurjchem-1140	46	20	)	)	PUNCT
eurjchem-1140	46	21	,	,	PUNCT
eurjchem-1140	46	22	130.50	130.50	NUM
eurjchem-1140	46	23	(	(	PUNCT
eurjchem-1140	46	24	2c	2c	NUM
eurjchem-1140	46	25	,	,	PUNCT
eurjchem-1140	46	26	c‐n‐	c‐n‐	ADP
eurjchem-1140	46	27	pyrazine	pyrazine	NOUN
eurjchem-1140	46	28	)	)	PUNCT
eurjchem-1140	46	29	,	,	PUNCT
eurjchem-1140	46	30	125.60	125.60	NUM
eurjchem-1140	46	31	(	(	PUNCT
eurjchem-1140	46	32	2c	2c	NOUN
eurjchem-1140	46	33	,	,	PUNCT
eurjchem-1140	46	34	‐c	‐c	NOUN
eurjchem-1140	46	35	=	=	NOUN
eurjchem-1140	46	36	c‐	c‐	NOUN
eurjchem-1140	46	37	)	)	PUNCT
eurjchem-1140	46	38	,	,	PUNCT
eurjchem-1140	46	39	118.55	118.55	NUM
eurjchem-1140	46	40	(	(	PUNCT
eurjchem-1140	46	41	2c	2c	NUM
eurjchem-1140	46	42	,	,	PUNCT
eurjchem-1140	46	43	c	c	X
eurjchem-1140	46	44	=	=	SYM
eurjchem-1140	46	45	c‐ch3	c‐ch3	ADJ
eurjchem-1140	46	46	)	)	PUNCT
eurjchem-1140	46	47	,	,	PUNCT
eurjchem-1140	46	48	19.22	19.22	NUM
eurjchem-1140	46	49	(	(	PUNCT
eurjchem-1140	46	50	2c	2c	NOUN
eurjchem-1140	46	51	,	,	PUNCT
eurjchem-1140	46	52	ar‐ch3	ar‐ch3	PROPN
eurjchem-1140	46	53	)	)	PUNCT
eurjchem-1140	46	54	.	.	PUNCT
eurjchem-1140	47	1	anal	anal	PROPN
eurjchem-1140	47	2	.	.	PUNCT
eurjchem-1140	47	3	calcd	calcd	NOUN
eurjchem-1140	47	4	.	.	PUNCT
eurjchem-1140	48	1	for	for	SCONJ
eurjchem-1140	48	2	c10h10n2o2	c10h10n2o2	NOUN
eurjchem-1140	48	3	:	:	PUNCT
eurjchem-1140	48	4	c	c	X
eurjchem-1140	48	5	,	,	PUNCT
eurjchem-1140	48	6	63.15	63.15	NUM
eurjchem-1140	48	7	;	;	PUNCT
eurjchem-1140	48	8	h	h	NOUN
eurjchem-1140	48	9	,	,	PUNCT
eurjchem-1140	48	10	5.30	5.30	NUM
eurjchem-1140	48	11	;	;	PUNCT
eurjchem-1140	48	12	n	n	CCONJ
eurjchem-1140	48	13	,	,	PUNCT
eurjchem-1140	48	14	14.73	14.73	NUM
eurjchem-1140	48	15	.	.	PUNCT
eurjchem-1140	48	16	found	find	VERB
eurjchem-1140	48	17	:	:	PUNCT
eurjchem-1140	49	1	c	c	X
eurjchem-1140	49	2	,	,	PUNCT
eurjchem-1140	49	3	62.67	62.67	NUM
eurjchem-1140	49	4	;	;	PUNCT
eurjchem-1140	49	5	h	h	NOUN
eurjchem-1140	49	6	,	,	PUNCT
eurjchem-1140	49	7	4.99	4.99	NUM
eurjchem-1140	49	8	;	;	PUNCT
eurjchem-1140	49	9	n	n	CCONJ
eurjchem-1140	49	10	,	,	PUNCT
eurjchem-1140	49	11	13.67	13.67	NUM
eurjchem-1140	49	12	%	%	NOUN
eurjchem-1140	49	13	.	.	PUNCT
eurjchem-1140	50	1	2.3.2	2.3.2	X
eurjchem-1140	50	2	.	.	X
eurjchem-1140	50	3	synthesis	synthesis	NOUN
eurjchem-1140	50	4	of	of	ADP
eurjchem-1140	50	5	2‐(6,7‐dimethyl‐3‐oxo‐3,4‐dihydro	2‐(6,7‐dimethyl‐3‐oxo‐3,4‐dihydro	NUM
eurjchem-1140	50	6	quinoxalin‐2(1h)‐ylidene	quinoxalin‐2(1h)‐ylidene	NOUN
eurjchem-1140	50	7	)	)	PUNCT
eurjchem-1140	50	8	hydrazinecarbothioamide	hydrazinecarbothioamide	NOUN
eurjchem-1140	51	1	[	[	X
eurjchem-1140	51	2	hl	hl	X
eurjchem-1140	51	3	]	]	X
eurjchem-1140	51	4	0.01	0.01	NUM
eurjchem-1140	51	5	mole	mole	NOUN
eurjchem-1140	51	6	of	of	ADP
eurjchem-1140	51	7	thiosemicarbazide	thiosemicarbazide	NOUN
eurjchem-1140	51	8	(	(	PUNCT
eurjchem-1140	51	9	0.91	0.91	NUM
eurjchem-1140	51	10	g	g	NOUN
eurjchem-1140	51	11	)	)	PUNCT
eurjchem-1140	51	12	in	in	ADP
eurjchem-1140	51	13	100	100	NUM
eurjchem-1140	51	14	ml	ml	NOUN
eurjchem-1140	51	15	ethanol	ethanol	NOUN
eurjchem-1140	51	16	was	be	AUX
eurjchem-1140	51	17	added	add	VERB
eurjchem-1140	51	18	gradually	gradually	ADV
eurjchem-1140	51	19	to	to	ADP
eurjchem-1140	51	20	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐	6,7‐dimethyl‐quinoxaline‐2,3(1h,4h)‐	PROPN
eurjchem-1140	51	21	dione	dione	NOUN
eurjchem-1140	51	22	(	(	PUNCT
eurjchem-1140	51	23	dmq	dmq	PROPN
eurjchem-1140	51	24	)	)	PUNCT
eurjchem-1140	51	25	(	(	PUNCT
eurjchem-1140	51	26	1.90	1.90	NUM
eurjchem-1140	51	27	g	g	NOUN
eurjchem-1140	51	28	)	)	PUNCT
eurjchem-1140	51	29	.	.	PUNCT
eurjchem-1140	52	1	the	the	DET
eurjchem-1140	52	2	reaction	reaction	NOUN
eurjchem-1140	52	3	mixture	mixture	NOUN
eurjchem-1140	52	4	was	be	AUX
eurjchem-1140	52	5	refluxed	refluxe	VERB
eurjchem-1140	52	6	for	for	ADP
eurjchem-1140	52	7	6	6	NUM
eurjchem-1140	52	8	hrs	hrs	NOUN
eurjchem-1140	52	9	on	on	ADP
eurjchem-1140	52	10	water	water	NOUN
eurjchem-1140	52	11	bath	bath	NOUN
eurjchem-1140	52	12	and	and	CCONJ
eurjchem-1140	52	13	the	the	DET
eurjchem-1140	52	14	pale	pale	ADJ
eurjchem-1140	52	15	yellow	yellow	ADJ
eurjchem-1140	52	16	solid	solid	ADJ
eurjchem-1140	52	17	separated	separate	VERB
eurjchem-1140	52	18	was	be	AUX
eurjchem-1140	52	19	filtered	filter	VERB
eurjchem-1140	52	20	,	,	PUNCT
eurjchem-1140	52	21	washed	wash	VERB
eurjchem-1140	52	22	several	several	ADJ
eurjchem-1140	52	23	times	time	NOUN
eurjchem-1140	52	24	with	with	ADP
eurjchem-1140	52	25	ethanol	ethanol	NOUN
eurjchem-1140	52	26	and	and	CCONJ
eurjchem-1140	52	27	dried	dry	VERB
eurjchem-1140	52	28	in	in	ADP
eurjchem-1140	52	29	oven	oven	NOUN
eurjchem-1140	52	30	,	,	PUNCT
eurjchem-1140	52	31	scheme	scheme	NOUN
eurjchem-1140	52	32	2	2	NUM
eurjchem-1140	52	33	.	.	PUNCT
eurjchem-1140	52	34	color	color	NOUN
eurjchem-1140	52	35	:	:	PUNCT
eurjchem-1140	52	36	pale	pale	ADJ
eurjchem-1140	52	37	yellow	yellow	ADJ
eurjchem-1140	52	38	.	.	PUNCT
eurjchem-1140	53	1	yield	yield	NOUN
eurjchem-1140	53	2	:	:	PUNCT
eurjchem-1140	53	3	80	80	NUM
eurjchem-1140	53	4	%	%	NOUN
eurjchem-1140	53	5	.	.	PUNCT
eurjchem-1140	54	1	m.p	m.p	PROPN
eurjchem-1140	54	2	.	.	PROPN
eurjchem-1140	54	3	:	:	PUNCT
eurjchem-1140	55	1	233‐235	233‐235	NUM
eurjchem-1140	55	2	°	°	SYM
eurjchem-1140	55	3	c	c	NOUN
eurjchem-1140	55	4	.	.	PUNCT
eurjchem-1140	56	1	ft‐	ft‐	PROPN
eurjchem-1140	56	2	ir	ir	PROPN
eurjchem-1140	56	3	(	(	PUNCT
eurjchem-1140	56	4	kbr	kbr	PROPN
eurjchem-1140	56	5	,	,	PUNCT
eurjchem-1140	56	6			PROPN
eurjchem-1140	56	7	,	,	PUNCT
eurjchem-1140	56	8	cm‐1	cm‐1	PROPN
eurjchem-1140	56	9	):	):	PUNCT
eurjchem-1140	56	10	3250	3250	NUM
eurjchem-1140	56	11	(	(	PUNCT
eurjchem-1140	56	12	nh	nh	NOUN
eurjchem-1140	56	13	)	)	PUNCT
eurjchem-1140	56	14	(	(	PUNCT
eurjchem-1140	56	15	amide	amide	NOUN
eurjchem-1140	56	16	and	and	CCONJ
eurjchem-1140	56	17	lactam	lactam	NOUN
eurjchem-1140	56	18	)	)	PUNCT
eurjchem-1140	56	19	,	,	PUNCT
eurjchem-1140	56	20	1680	1680	NUM
eurjchem-1140	56	21	(	(	PUNCT
eurjchem-1140	56	22	c	c	NOUN
eurjchem-1140	56	23	=	=	NOUN
eurjchem-1140	56	24	o	o	NOUN
eurjchem-1140	56	25	)	)	PUNCT
eurjchem-1140	56	26	(	(	PUNCT
eurjchem-1140	56	27	amide	amide	NOUN
eurjchem-1140	56	28	)	)	PUNCT
eurjchem-1140	56	29	,	,	PUNCT
eurjchem-1140	56	30	1610	1610	NUM
eurjchem-1140	56	31	(	(	PUNCT
eurjchem-1140	56	32	c	c	NOUN
eurjchem-1140	56	33	=	=	SYM
eurjchem-1140	56	34	n	n	NUM
eurjchem-1140	56	35	)	)	PUNCT
eurjchem-1140	56	36	(	(	PUNCT
eurjchem-1140	56	37	imine	imine	NOUN
eurjchem-1140	56	38	of	of	ADP
eurjchem-1140	56	39	pyrazine	pyrazine	NOUN
eurjchem-1140	56	40	ring	ring	NOUN
eurjchem-1140	56	41	)	)	PUNCT
eurjchem-1140	56	42	,	,	PUNCT
eurjchem-1140	56	43	2972	2972	NUM
eurjchem-1140	56	44	(	(	PUNCT
eurjchem-1140	56	45	c‐h	c‐h	NUM
eurjchem-1140	56	46	)	)	PUNCT
eurjchem-1140	56	47	(	(	PUNCT
eurjchem-1140	56	48	aliphatic‐ch3	aliphatic‐ch3	PROPN
eurjchem-1140	56	49	)	)	PUNCT
eurjchem-1140	56	50	.	.	PUNCT
eurjchem-1140	57	1	1h	1h	NUM
eurjchem-1140	57	2	nmr	nmr	NOUN
eurjchem-1140	57	3	(	(	PUNCT
eurjchem-1140	57	4	300	300	NUM
eurjchem-1140	57	5	mhz	mhz	NOUN
eurjchem-1140	57	6	,	,	PUNCT
eurjchem-1140	57	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1140	57	8	,	,	PUNCT
eurjchem-1140	57	9	δ	δ	PROPN
eurjchem-1140	57	10	,	,	PUNCT
eurjchem-1140	57	11	ppm	ppm	NUM
eurjchem-1140	57	12	):	):	PUNCT
eurjchem-1140	57	13	3.40	3.40	NUM
eurjchem-1140	57	14	(	(	PUNCT
eurjchem-1140	57	15	s	s	PROPN
eurjchem-1140	57	16	,	,	PUNCT
eurjchem-1140	57	17	6h	6h	NUM
eurjchem-1140	57	18	,	,	PUNCT
eurjchem-1140	57	19	ch3	ch3	PROPN
eurjchem-1140	57	20	)	)	PUNCT
eurjchem-1140	57	21	,	,	PUNCT
eurjchem-1140	57	22	5.62	5.62	NUM
eurjchem-1140	57	23	(	(	PUNCT
eurjchem-1140	57	24	s	s	PROPN
eurjchem-1140	57	25	,	,	PUNCT
eurjchem-1140	57	26	1h	1h	NUM
eurjchem-1140	57	27	,	,	PUNCT
eurjchem-1140	57	28	nh	nh	PROPN
eurjchem-1140	57	29	)	)	PUNCT
eurjchem-1140	57	30	,	,	PUNCT
eurjchem-1140	57	31	6.21	6.21	NUM
eurjchem-1140	57	32	(	(	PUNCT
eurjchem-1140	57	33	s	s	PROPN
eurjchem-1140	57	34	,	,	PUNCT
eurjchem-1140	57	35	1h	1h	NUM
eurjchem-1140	57	36	,	,	PUNCT
eurjchem-1140	57	37	ar‐h	ar‐h	NOUN
eurjchem-1140	57	38	)	)	PUNCT
eurjchem-1140	57	39	,	,	PUNCT
eurjchem-1140	57	40	6.78	6.78	NUM
eurjchem-1140	57	41	(	(	PUNCT
eurjchem-1140	57	42	s	s	PROPN
eurjchem-1140	57	43	,	,	PUNCT
eurjchem-1140	57	44	1h	1h	NUM
eurjchem-1140	57	45	,	,	PUNCT
eurjchem-1140	57	46	ar‐h	ar‐h	NOUN
eurjchem-1140	57	47	)	)	PUNCT
eurjchem-1140	57	48	7.89	7.89	NUM
eurjchem-1140	57	49	(	(	PUNCT
eurjchem-1140	57	50	s	s	PROPN
eurjchem-1140	57	51	,	,	PUNCT
eurjchem-1140	57	52	1h	1h	NUM
eurjchem-1140	57	53	,	,	PUNCT
eurjchem-1140	57	54	hn	hn	PROPN
eurjchem-1140	57	55	)	)	PUNCT
eurjchem-1140	57	56	,	,	PUNCT
eurjchem-1140	57	57	8.01	8.01	NUM
eurjchem-1140	57	58	(	(	PUNCT
eurjchem-1140	57	59	s	s	PROPN
eurjchem-1140	57	60	,	,	PUNCT
eurjchem-1140	57	61	1h	1h	NUM
eurjchem-1140	57	62	,	,	PUNCT
eurjchem-1140	57	63	hn	hn	PROPN
eurjchem-1140	57	64	)	)	PUNCT
eurjchem-1140	57	65	,	,	PUNCT
eurjchem-1140	57	66	8.61	8.61	NUM
eurjchem-1140	57	67	(	(	PUNCT
eurjchem-1140	57	68	s	s	PROPN
eurjchem-1140	57	69	,	,	PUNCT
eurjchem-1140	57	70	2h	2h	NUM
eurjchem-1140	57	71	,	,	PUNCT
eurjchem-1140	57	72	h2n	h2n	NOUN
eurjchem-1140	57	73	)	)	PUNCT
eurjchem-1140	57	74	.	.	PUNCT
eurjchem-1140	58	1	13c	13c	NOUN
eurjchem-1140	58	2	nmr	nmr	NOUN
eurjchem-1140	58	3	(	(	PUNCT
eurjchem-1140	58	4	300	300	NUM
eurjchem-1140	58	5	mhz	mhz	NOUN
eurjchem-1140	58	6	,	,	PUNCT
eurjchem-1140	58	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1140	58	8	,	,	PUNCT
eurjchem-1140	58	9	δ	δ	PROPN
eurjchem-1140	58	10	,	,	PUNCT
eurjchem-1140	58	11	ppm	ppm	NUM
eurjchem-1140	58	12	):	):	PUNCT
eurjchem-1140	58	13	155.2	155.2	NUM
eurjchem-1140	58	14	(	(	PUNCT
eurjchem-1140	58	15	c	c	NOUN
eurjchem-1140	58	16	,	,	PUNCT
eurjchem-1140	58	17	c	c	X
eurjchem-1140	58	18	=	=	SYM
eurjchem-1140	58	19	s	s	NOUN
eurjchem-1140	58	20	thioamide	thioamide	NOUN
eurjchem-1140	58	21	)	)	PUNCT
eurjchem-1140	58	22	,	,	PUNCT
eurjchem-1140	58	23	131.91	131.91	NUM
eurjchem-1140	58	24	(	(	PUNCT
eurjchem-1140	58	25	c	c	X
eurjchem-1140	58	26	,	,	PUNCT
eurjchem-1140	58	27	amide‐c	amide‐c	PROPN
eurjchem-1140	58	28	=	=	PROPN
eurjchem-1140	58	29	o	o	NOUN
eurjchem-1140	58	30	)	)	PUNCT
eurjchem-1140	58	31	,	,	PUNCT
eurjchem-1140	58	32	128.9	128.9	NUM
eurjchem-1140	58	33	(	(	PUNCT
eurjchem-1140	58	34	c	c	NOUN
eurjchem-1140	58	35	,	,	PUNCT
eurjchem-1140	58	36	c	c	NOUN
eurjchem-1140	58	37	=	=	X
eurjchem-1140	58	38	n‐imine	n‐imine	X
eurjchem-1140	58	39	)	)	PUNCT
eurjchem-1140	58	40	,	,	PUNCT
eurjchem-1140	58	41	127.7	127.7	NUM
eurjchem-1140	58	42	(	(	PUNCT
eurjchem-1140	58	43	c	c	NOUN
eurjchem-1140	58	44	,	,	PUNCT
eurjchem-1140	58	45	c‐n‐	c‐n‐	ADP
eurjchem-1140	58	46	pyrazine	pyrazine	NOUN
eurjchem-1140	58	47	)	)	PUNCT
eurjchem-1140	58	48	,	,	PUNCT
eurjchem-1140	58	49	126.7	126.7	NUM
eurjchem-1140	58	50	(	(	PUNCT
eurjchem-1140	58	51	c	c	NOUN
eurjchem-1140	58	52	,	,	PUNCT
eurjchem-1140	58	53	‐c‐n‐pyrazine	‐c‐n‐pyrazine	NUM
eurjchem-1140	58	54	)	)	PUNCT
eurjchem-1140	58	55	,	,	PUNCT
eurjchem-1140	58	56	123.90	123.90	NUM
eurjchem-1140	58	57	(	(	PUNCT
eurjchem-1140	58	58	c	c	NOUN
eurjchem-1140	58	59	,	,	PUNCT
eurjchem-1140	58	60	c	c	NOUN
eurjchem-1140	58	61	=	=	NOUN
eurjchem-1140	58	62	c‐ar	c‐ar	ADJ
eurjchem-1140	58	63	)	)	PUNCT
eurjchem-1140	58	64	,	,	PUNCT
eurjchem-1140	58	65	122.04	122.04	NUM
eurjchem-1140	58	66	(	(	PUNCT
eurjchem-1140	58	67	c	c	NOUN
eurjchem-1140	58	68	,	,	PUNCT
eurjchem-1140	58	69	c	c	NOUN
eurjchem-1140	58	70	=	=	NOUN
eurjchem-1140	58	71	c‐	c‐	PROPN
eurjchem-1140	58	72	ar	ar	NOUN
eurjchem-1140	58	73	)	)	PUNCT
eurjchem-1140	58	74	,	,	PUNCT
eurjchem-1140	58	75	115.61	115.61	NUM
eurjchem-1140	58	76	(	(	PUNCT
eurjchem-1140	58	77	9c	9c	NUM
eurjchem-1140	58	78	,	,	PUNCT
eurjchem-1140	58	79	c‐ar	c‐ar	NUM
eurjchem-1140	58	80	)	)	PUNCT
eurjchem-1140	58	81	,	,	PUNCT
eurjchem-1140	58	82	110.79	110.79	NUM
eurjchem-1140	58	83	(	(	PUNCT
eurjchem-1140	58	84	c	c	NOUN
eurjchem-1140	58	85	=	=	NOUN
eurjchem-1140	58	86	c‐ar	c‐ar	NUM
eurjchem-1140	58	87	)	)	PUNCT
eurjchem-1140	58	88	,	,	PUNCT
eurjchem-1140	58	89	51.4	51.4	NUM
eurjchem-1140	58	90	(	(	PUNCT
eurjchem-1140	58	91	c	c	PROPN
eurjchem-1140	58	92	,	,	PUNCT
eurjchem-1140	58	93	ch3	ch3	PROPN
eurjchem-1140	58	94	)	)	PUNCT
eurjchem-1140	58	95	,	,	PUNCT
eurjchem-1140	58	96	25.2	25.2	NUM
eurjchem-1140	58	97	(	(	PUNCT
eurjchem-1140	58	98	c	c	X
eurjchem-1140	58	99	,	,	PUNCT
eurjchem-1140	58	100	ch3	ch3	PROPN
eurjchem-1140	58	101	)	)	PUNCT
eurjchem-1140	58	102	.	.	PUNCT
eurjchem-1140	59	1	uv	uv	NOUN
eurjchem-1140	59	2	/	/	SYM
eurjchem-1140	59	3	vis	vis	X
eurjchem-1140	59	4	(	(	PUNCT
eurjchem-1140	59	5	ethanol	ethanol	NOUN
eurjchem-1140	59	6	,	,	PUNCT
eurjchem-1140	59	7	λmax	λmax	NOUN
eurjchem-1140	59	8	,	,	PUNCT
eurjchem-1140	59	9	nm	nm	NOUN
eurjchem-1140	59	10	,	,	PUNCT
eurjchem-1140	59	11	(	(	PUNCT
eurjchem-1140	59	12			PROPN
eurjchem-1140	59	13	)	)	PUNCT
eurjchem-1140	59	14	):	):	PUNCT
eurjchem-1140	59	15	350	350	NUM
eurjchem-1140	59	16	(	(	PUNCT
eurjchem-1140	59	17	3.82	3.82	NUM
eurjchem-1140	59	18	)	)	PUNCT
eurjchem-1140	59	19	,	,	PUNCT
eurjchem-1140	59	20	222	222	NUM
eurjchem-1140	59	21	(	(	PUNCT
eurjchem-1140	59	22	5.401	5.401	NUM
eurjchem-1140	59	23	)	)	PUNCT
eurjchem-1140	59	24	.	.	PUNCT
eurjchem-1140	60	1	ms	ms	NOUN
eurjchem-1140	60	2	(	(	PUNCT
eurjchem-1140	60	3	ei	ei	PROPN
eurjchem-1140	60	4	,	,	PUNCT
eurjchem-1140	60	5	m	m	PROPN
eurjchem-1140	60	6	/	/	SYM
eurjchem-1140	60	7	z	z	PROPN
eurjchem-1140	60	8	(	(	PUNCT
eurjchem-1140	60	9	%	%	NOUN
eurjchem-1140	60	10	)	)	PUNCT
eurjchem-1140	60	11	):	):	PUNCT
eurjchem-1140	60	12	264	264	NUM
eurjchem-1140	60	13	(	(	PUNCT
eurjchem-1140	60	14	m+	m+	NUM
eurjchem-1140	60	15	,	,	PUNCT
eurjchem-1140	60	16	100	100	NUM
eurjchem-1140	60	17	)	)	PUNCT
eurjchem-1140	60	18	.	.	PUNCT
eurjchem-1140	61	1	anal	anal	PROPN
eurjchem-1140	61	2	.	.	PUNCT
eurjchem-1140	61	3	calcd	calcd	NOUN
eurjchem-1140	61	4	.	.	PUNCT
eurjchem-1140	62	1	for	for	ADP
eurjchem-1140	62	2	c11h13n5os	c11h13n5o	NOUN
eurjchem-1140	62	3	:	:	PUNCT
eurjchem-1140	62	4	c	c	X
eurjchem-1140	62	5	,	,	PUNCT
eurjchem-1140	62	6	50.17	50.17	NUM
eurjchem-1140	62	7	;	;	PUNCT
eurjchem-1140	62	8	h	h	NOUN
eurjchem-1140	62	9	,	,	PUNCT
eurjchem-1140	62	10	4.98	4.98	NUM
eurjchem-1140	62	11	;	;	PUNCT
eurjchem-1140	62	12	n	n	CCONJ
eurjchem-1140	62	13	,	,	PUNCT
eurjchem-1140	62	14	26.60	26.60	NUM
eurjchem-1140	62	15	.	.	PUNCT
eurjchem-1140	62	16	found	find	VERB
eurjchem-1140	62	17	:	:	PUNCT
eurjchem-1140	63	1	c	c	X
eurjchem-1140	63	2	,	,	PUNCT
eurjchem-1140	63	3	49.07	49.07	NUM
eurjchem-1140	63	4	;	;	PUNCT
eurjchem-1140	63	5	h	h	NOUN
eurjchem-1140	63	6	,	,	PUNCT
eurjchem-1140	63	7	3.99	3.99	NUM
eurjchem-1140	63	8	;	;	PUNCT
eurjchem-1140	63	9	n	n	CCONJ
eurjchem-1140	63	10	,	,	PUNCT
eurjchem-1140	63	11	25.22	25.22	NUM
eurjchem-1140	63	12	%	%	NOUN
eurjchem-1140	63	13	.	.	PUNCT
eurjchem-1140	64	1	2.4	2.4	NUM
eurjchem-1140	64	2	.	.	PUNCT
eurjchem-1140	65	1	synthesis	synthesis	NOUN
eurjchem-1140	65	2	of	of	ADP
eurjchem-1140	65	3	the	the	DET
eurjchem-1140	65	4	metal	metal	NOUN
eurjchem-1140	65	5	complexes	complexe	VERB
eurjchem-1140	65	6	a	a	DET
eurjchem-1140	65	7	methanolic	methanolic	NOUN
eurjchem-1140	65	8	solution	solution	NOUN
eurjchem-1140	65	9	(	(	PUNCT
eurjchem-1140	65	10	100	100	NUM
eurjchem-1140	65	11	ml	ml	NOUN
eurjchem-1140	65	12	)	)	PUNCT
eurjchem-1140	65	13	of	of	ADP
eurjchem-1140	65	14	metal(ii	metal(ii	PROPN
eurjchem-1140	65	15	)	)	PUNCT
eurjchem-1140	65	16	chloride	chloride	NOUN
eurjchem-1140	65	17	(	(	PUNCT
eurjchem-1140	65	18	mncl2·4h2o	mncl2·4h2o	NOUN
eurjchem-1140	65	19	(	(	PUNCT
eurjchem-1140	65	20	0.221	0.221	NUM
eurjchem-1140	65	21	g	g	NOUN
eurjchem-1140	65	22	)	)	PUNCT
eurjchem-1140	65	23	,	,	PUNCT
eurjchem-1140	65	24	cocl2·6h2o	cocl2·6h2o	NOUN
eurjchem-1140	65	25	(	(	PUNCT
eurjchem-1140	65	26	0.237	0.237	NUM
eurjchem-1140	65	27	g	g	NOUN
eurjchem-1140	65	28	)	)	PUNCT
eurjchem-1140	65	29	,	,	PUNCT
eurjchem-1140	65	30	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-1140	65	31	(	(	PUNCT
eurjchem-1140	65	32	0.237	0.237	NUM
eurjchem-1140	65	33	g	g	NOUN
eurjchem-1140	65	34	)	)	PUNCT
eurjchem-1140	65	35	,	,	PUNCT
eurjchem-1140	65	36	cucl2·2h2o	cucl2·2h2o	NOUN
eurjchem-1140	65	37	(	(	PUNCT
eurjchem-1140	65	38	0.170	0.170	NUM
eurjchem-1140	65	39	g	g	NOUN
eurjchem-1140	65	40	)	)	PUNCT
eurjchem-1140	65	41	and	and	CCONJ
eurjchem-1140	65	42	zncl2	zncl2	NOUN
eurjchem-1140	65	43	(	(	PUNCT
eurjchem-1140	65	44	0.135	0.135	NUM
eurjchem-1140	65	45	g	g	NOUN
eurjchem-1140	65	46	)	)	PUNCT
eurjchem-1140	65	47	)	)	PUNCT
eurjchem-1140	65	48	was	be	AUX
eurjchem-1140	65	49	added	add	VERB
eurjchem-1140	65	50	with	with	ADP
eurjchem-1140	65	51	stirring	stir	VERB
eurjchem-1140	65	52	to	to	ADP
eurjchem-1140	65	53	an	an	DET
eurjchem-1140	65	54	ethanol	ethanol	NOUN
eurjchem-1140	65	55	solution	solution	NOUN
eurjchem-1140	65	56	of	of	ADP
eurjchem-1140	65	57	the	the	DET
eurjchem-1140	65	58	ligand	ligand	NOUN
eurjchem-1140	65	59	(	(	PUNCT
eurjchem-1140	65	60	lh	lh	PROPN
eurjchem-1140	65	61	(	(	PUNCT
eurjchem-1140	65	62	0.264	0.264	NOUN
eurjchem-1140	65	63	g	g	NOUN
eurjchem-1140	65	64	)	)	PUNCT
eurjchem-1140	65	65	and	and	CCONJ
eurjchem-1140	65	66	refluxed	refluxe	VERB
eurjchem-1140	65	67	on	on	ADP
eurjchem-1140	65	68	water	water	NOUN
eurjchem-1140	65	69	bath	bath	NOUN
eurjchem-1140	65	70	for	for	ADP
eurjchem-1140	65	71	6‐8	6‐8	ADJ
eurjchem-1140	65	72	hours	hour	NOUN
eurjchem-1140	65	73	.	.	PUNCT
eurjchem-1140	66	1	so	so	ADV
eurjchem-1140	66	2	,	,	PUNCT
eurjchem-1140	66	3	the	the	DET
eurjchem-1140	66	4	obtained	obtain	VERB
eurjchem-1140	66	5	solid	solid	ADJ
eurjchem-1140	66	6	complex	complex	NOUN
eurjchem-1140	66	7	was	be	AUX
eurjchem-1140	66	8	separated	separate	VERB
eurjchem-1140	66	9	by	by	ADP
eurjchem-1140	66	10	filtration	filtration	NOUN
eurjchem-1140	66	11	under	under	ADP
eurjchem-1140	66	12	suction	suction	NOUN
eurjchem-1140	66	13	,	,	PUNCT
eurjchem-1140	66	14	washed	wash	VERB
eurjchem-1140	66	15	with	with	ADP
eurjchem-1140	66	16	hot	hot	ADJ
eurjchem-1140	66	17	ethanol	ethanol	NOUN
eurjchem-1140	66	18	and	and	CCONJ
eurjchem-1140	66	19	dried	dry	VERB
eurjchem-1140	66	20	in	in	ADP
eurjchem-1140	66	21	vacuum	vacuum	NOUN
eurjchem-1140	66	22	.	.	PUNCT
eurjchem-1140	67	1	the	the	DET
eurjchem-1140	67	2	characterization	characterization	NOUN
eurjchem-1140	67	3	data	datum	NOUN
eurjchem-1140	67	4	of	of	ADP
eurjchem-1140	67	5	all	all	DET
eurjchem-1140	67	6	metal	metal	NOUN
eurjchem-1140	67	7	complexes	complex	NOUN
eurjchem-1140	67	8	were	be	AUX
eurjchem-1140	67	9	shown	show	VERB
eurjchem-1140	67	10	in	in	ADP
eurjchem-1140	67	11	tables	table	NOUN
eurjchem-1140	67	12	1‐3	1‐3	PROPN
eurjchem-1140	67	13	.	.	PUNCT
eurjchem-1140	68	1	3	3	X
eurjchem-1140	68	2	.	.	NOUN
eurjchem-1140	68	3	results	result	NOUN
eurjchem-1140	68	4	and	and	CCONJ
eurjchem-1140	68	5	discussion	discussion	NOUN
eurjchem-1140	68	6	the	the	DET
eurjchem-1140	68	7	new	new	ADJ
eurjchem-1140	68	8	metal	metal	NOUN
eurjchem-1140	68	9	complexes	complex	NOUN
eurjchem-1140	68	10	prepared	prepare	VERB
eurjchem-1140	68	11	in	in	ADP
eurjchem-1140	68	12	this	this	DET
eurjchem-1140	68	13	course	course	NOUN
eurjchem-1140	68	14	were	be	AUX
eurjchem-1140	68	15	non‐hygroscopic	non‐hygroscopic	ADJ
eurjchem-1140	68	16	(	(	PUNCT
eurjchem-1140	68	17	stable	stable	ADJ
eurjchem-1140	68	18	at	at	ADP
eurjchem-1140	68	19	the	the	DET
eurjchem-1140	68	20	room	room	NOUN
eurjchem-1140	68	21	temperature	temperature	NOUN
eurjchem-1140	68	22	)	)	PUNCT
eurjchem-1140	68	23	and	and	CCONJ
eurjchem-1140	68	24	in	in	ADP
eurjchem-1140	68	25	the	the	DET
eurjchem-1140	68	26	form	form	NOUN
eurjchem-1140	68	27	of	of	ADP
eurjchem-1140	68	28	amorphous	amorphous	ADJ
eurjchem-1140	68	29	solids	solid	NOUN
eurjchem-1140	68	30	.	.	PUNCT
eurjchem-1140	69	1	these	these	PRON
eurjchem-1140	69	2	are	be	AUX
eurjchem-1140	69	3	soluble	soluble	ADJ
eurjchem-1140	69	4	easily	easily	ADV
eurjchem-1140	69	5	in	in	ADP
eurjchem-1140	69	6	dmso	dmso	NOUN
eurjchem-1140	69	7	,	,	PUNCT
eurjchem-1140	69	8	dmf	dmf	PROPN
eurjchem-1140	69	9	and	and	CCONJ
eurjchem-1140	69	10	sparingly	sparingly	ADV
eurjchem-1140	69	11	in	in	ADP
eurjchem-1140	69	12	ethanol	ethanol	NOUN
eurjchem-1140	69	13	and	and	CCONJ
eurjchem-1140	69	14	methanol	methanol	NOUN
eurjchem-1140	69	15	whereas	whereas	SCONJ
eurjchem-1140	69	16	they	they	PRON
eurjchem-1140	69	17	are	be	AUX
eurjchem-1140	69	18	insoluble	insoluble	ADJ
eurjchem-1140	69	19	in	in	ADP
eurjchem-1140	69	20	chlorinated	chlorinated	ADJ
eurjchem-1140	69	21	hydrocarbons	hydrocarbon	NOUN
eurjchem-1140	69	22	.	.	PUNCT
eurjchem-1140	70	1	the	the	DET
eurjchem-1140	70	2	elemental	elemental	ADJ
eurjchem-1140	70	3	analysis	analysis	NOUN
eurjchem-1140	70	4	data	datum	NOUN
eurjchem-1140	70	5	of	of	ADP
eurjchem-1140	70	6	the	the	DET
eurjchem-1140	70	7	ligand	ligand	NOUN
eurjchem-1140	70	8	and	and	CCONJ
eurjchem-1140	70	9	its	its	PRON
eurjchem-1140	70	10	metal	metal	NOUN
eurjchem-1140	70	11	complexes	complex	NOUN
eurjchem-1140	70	12	along	along	ADP
eurjchem-1140	70	13	with	with	ADP
eurjchem-1140	70	14	their	their	PRON
eurjchem-1140	70	15	physical	physical	ADJ
eurjchem-1140	70	16	properties	property	NOUN
eurjchem-1140	70	17	are	be	AUX
eurjchem-1140	70	18	shown	show	VERB
eurjchem-1140	70	19	in	in	ADP
eurjchem-1140	70	20	table	table	NOUN
eurjchem-1140	70	21	1	1	NUM
eurjchem-1140	70	22	.	.	PUNCT
eurjchem-1140	71	1	however	however	ADV
eurjchem-1140	71	2	,	,	PUNCT
eurjchem-1140	71	3	the	the	DET
eurjchem-1140	71	4	continuous	continuous	ADJ
eurjchem-1140	71	5	variation	variation	NOUN
eurjchem-1140	71	6	method	method	NOUN
eurjchem-1140	71	7	was	be	AUX
eurjchem-1140	71	8	adopted	adopt	VERB
eurjchem-1140	71	9	to	to	PART
eurjchem-1140	71	10	deduce	deduce	VERB
eurjchem-1140	71	11	the	the	DET
eurjchem-1140	71	12	mole	mole	NOUN
eurjchem-1140	71	13	ratio	ratio	NOUN
eurjchem-1140	71	14	of	of	ADP
eurjchem-1140	71	15	ligand	ligand	NOUN
eurjchem-1140	71	16	to	to	PART
eurjchem-1140	71	17	metal	metal	NOUN
eurjchem-1140	71	18	ion	ion	NOUN
eurjchem-1140	71	19	at	at	ADP
eurjchem-1140	71	20	maximum	maximum	ADJ
eurjchem-1140	71	21	wavelength	wavelength	NOUN
eurjchem-1140	71	22	of	of	ADP
eurjchem-1140	71	23	absorption	absorption	NOUN
eurjchem-1140	71	24	[	[	X
eurjchem-1140	71	25	16	16	NUM
eurjchem-1140	71	26	]	]	PUNCT
eurjchem-1140	71	27	.	.	PUNCT
eurjchem-1140	72	1	3.1	3.1	NUM
eurjchem-1140	72	2	.	.	PUNCT
eurjchem-1140	72	3	molar	molar	ADJ
eurjchem-1140	72	4	conductivity	conductivity	NOUN
eurjchem-1140	72	5	measurements	measurement	NOUN
eurjchem-1140	72	6	the	the	DET
eurjchem-1140	72	7	molar	molar	ADJ
eurjchem-1140	72	8	conductance	conductance	NOUN
eurjchem-1140	72	9	values	value	NOUN
eurjchem-1140	72	10	of	of	ADP
eurjchem-1140	72	11	the	the	DET
eurjchem-1140	72	12	complexes	complex	NOUN
eurjchem-1140	72	13	measured	measure	VERB
eurjchem-1140	72	14	at	at	ADP
eurjchem-1140	72	15	room	room	NOUN
eurjchem-1140	72	16	temperature	temperature	NOUN
eurjchem-1140	72	17	in	in	ADP
eurjchem-1140	72	18	dmso	dmso	ADJ
eurjchem-1140	72	19	solution	solution	NOUN
eurjchem-1140	72	20	with	with	ADP
eurjchem-1140	72	21	0.001	0.001	NUM
eurjchem-1140	72	22	mol	mol	NOUN
eurjchem-1140	72	23	/	/	SYM
eurjchem-1140	72	24	dm3	dm3	NOUN
eurjchem-1140	72	25	concentration	concentration	NOUN
eurjchem-1140	72	26	fall	fall	NOUN
eurjchem-1140	72	27	in	in	ADP
eurjchem-1140	72	28	the	the	DET
eurjchem-1140	72	29	range	range	NOUN
eurjchem-1140	72	30	10‐22	10‐22	NUM
eurjchem-1140	72	31	ohm.cm2	ohm.cm2	PROPN
eurjchem-1140	72	32	/	/	SYM
eurjchem-1140	72	33	mol	mol	NOUN
eurjchem-1140	72	34	indicating	indicate	VERB
eurjchem-1140	72	35	the	the	DET
eurjchem-1140	72	36	non‐electrolytic	non‐electrolytic	ADJ
eurjchem-1140	72	37	nature	nature	NOUN
eurjchem-1140	72	38	of	of	ADP
eurjchem-1140	72	39	the	the	DET
eurjchem-1140	72	40	complexes	complex	NOUN
eurjchem-1140	72	41	[	[	X
eurjchem-1140	72	42	17	17	NUM
eurjchem-1140	72	43	]	]	PUNCT
eurjchem-1140	72	44	.	.	PUNCT
eurjchem-1140	73	1	compara‐	compara‐	PROPN
eurjchem-1140	73	2	tively	tively	ADV
eurjchem-1140	73	3	high	high	ADJ
eurjchem-1140	73	4	values	value	NOUN
eurjchem-1140	73	5	are	be	AUX
eurjchem-1140	73	6	due	due	ADJ
eurjchem-1140	73	7	to	to	ADP
eurjchem-1140	73	8	the	the	DET
eurjchem-1140	73	9	interaction	interaction	NOUN
eurjchem-1140	73	10	of	of	ADP
eurjchem-1140	73	11	solvent	solvent	ADJ
eurjchem-1140	73	12	molecules	molecule	NOUN
eurjchem-1140	73	13	of	of	ADP
eurjchem-1140	73	14	dmso	dmso	NOUN
eurjchem-1140	73	15	on	on	ADP
eurjchem-1140	73	16	the	the	DET
eurjchem-1140	73	17	vacant	vacant	ADJ
eurjchem-1140	73	18	orbital	orbital	NOUN
eurjchem-1140	73	19	's	's	PART
eurjchem-1140	73	20	of	of	ADP
eurjchem-1140	73	21	metal	metal	NOUN
eurjchem-1140	73	22	ions	ion	NOUN
eurjchem-1140	73	23	.	.	PUNCT
eurjchem-1140	74	1	3.2	3.2	NUM
eurjchem-1140	74	2	.	.	PUNCT
eurjchem-1140	75	1	ir	ir	PROPN
eurjchem-1140	75	2	spectral	spectral	PROPN
eurjchem-1140	75	3	study	study	VERB
eurjchem-1140	75	4	the	the	DET
eurjchem-1140	75	5	important	important	ADJ
eurjchem-1140	75	6	ir	ir	PROPN
eurjchem-1140	75	7	spectral	spectral	ADJ
eurjchem-1140	75	8	bands	band	NOUN
eurjchem-1140	75	9	of	of	ADP
eurjchem-1140	75	10	ligand	ligand	ADJ
eurjchem-1140	75	11	and	and	CCONJ
eurjchem-1140	75	12	corresponding	corresponding	ADJ
eurjchem-1140	75	13	complexes	complex	NOUN
eurjchem-1140	75	14	along	along	ADP
eurjchem-1140	75	15	with	with	ADP
eurjchem-1140	75	16	assignments	assignment	NOUN
eurjchem-1140	75	17	are	be	AUX
eurjchem-1140	75	18	presented	present	VERB
eurjchem-1140	75	19	in	in	ADP
eurjchem-1140	75	20	table	table	NOUN
eurjchem-1140	75	21	2	2	NUM
eurjchem-1140	75	22	.	.	NOUN
eurjchem-1140	75	23	46	46	NUM
eurjchem-1140	75	24	al‐jibouri	al‐jibouri	PROPN
eurjchem-1140	75	25	and	and	CCONJ
eurjchem-1140	75	26	hasun	hasun	PROPN
eurjchem-1140	75	27	/	/	SYM
eurjchem-1140	75	28	european	european	PROPN
eurjchem-1140	75	29	journal	journal	PROPN
eurjchem-1140	75	30	of	of	ADP
eurjchem-1140	75	31	chemistry	chemistry	NOUN
eurjchem-1140	75	32	6	6	NUM
eurjchem-1140	75	33	(	(	PUNCT
eurjchem-1140	75	34	1	1	NUM
eurjchem-1140	75	35	)	)	PUNCT
eurjchem-1140	75	36	(	(	PUNCT
eurjchem-1140	75	37	2015	2015	NUM
eurjchem-1140	75	38	)	)	PUNCT
eurjchem-1140	75	39	44‐47	44‐47	NOUN
eurjchem-1140	75	40	table	table	NOUN
eurjchem-1140	75	41	1	1	NUM
eurjchem-1140	75	42	.	.	PUNCT
eurjchem-1140	76	1	the	the	DET
eurjchem-1140	76	2	physical	physical	ADJ
eurjchem-1140	76	3	properties	property	NOUN
eurjchem-1140	76	4	and	and	CCONJ
eurjchem-1140	76	5	elemental	elemental	ADJ
eurjchem-1140	76	6	analysis	analysis	NOUN
eurjchem-1140	76	7	of	of	ADP
eurjchem-1140	76	8	the	the	DET
eurjchem-1140	76	9	prepared	prepared	ADJ
eurjchem-1140	76	10	metal	metal	NOUN
eurjchem-1140	76	11	complexes	complex	NOUN
eurjchem-1140	76	12	.	.	PUNCT
eurjchem-1140	77	1	compound	compound	NOUN
eurjchem-1140	77	2	color	color	NOUN
eurjchem-1140	77	3	m.p	m.p	PROPN
eurjchem-1140	77	4	.	.	PROPN
eurjchem-1140	78	1	(	(	PUNCT
eurjchem-1140	78	2	)	)	PUNCT
eurjchem-1140	78	3	a	a	DET
eurjchem-1140	78	4	c%	c%	ADJ
eurjchem-1140	78	5	calculated	calculate	VERB
eurjchem-1140	78	6	(	(	PUNCT
eurjchem-1140	78	7	found	find	VERB
eurjchem-1140	78	8	)	)	PUNCT
eurjchem-1140	78	9	h%	h%	CCONJ
eurjchem-1140	79	1	calculated	calculated	ADJ
eurjchem-1140	79	2	(	(	PUNCT
eurjchem-1140	79	3	found	find	VERB
eurjchem-1140	79	4	)	)	PUNCT
eurjchem-1140	79	5	n%	n%	PROPN
eurjchem-1140	79	6	calculated	calculate	VERB
eurjchem-1140	79	7	(	(	PUNCT
eurjchem-1140	79	8	found	find	VERB
eurjchem-1140	79	9	)	)	PUNCT
eurjchem-1140	79	10	s%	s%	NOUN
eurjchem-1140	79	11	calculated	calculate	VERB
eurjchem-1140	79	12	(	(	PUNCT
eurjchem-1140	79	13	found	find	VERB
eurjchem-1140	79	14	)	)	PUNCT
eurjchem-1140	79	15	m%	m%	PROPN
eurjchem-1140	79	16	b	b	PROPN
eurjchem-1140	79	17	hl	hl	PROPN
eurjchem-1140	79	18	pale	pale	ADJ
eurjchem-1140	79	19	yellow	yellow	ADJ
eurjchem-1140	79	20	233‐235	233‐235	NUM
eurjchem-1140	79	21	50.17	50.17	NUM
eurjchem-1140	79	22	(	(	PUNCT
eurjchem-1140	79	23	49.07	49.07	NUM
eurjchem-1140	79	24	)	)	PUNCT
eurjchem-1140	79	25	4.98	4.98	NUM
eurjchem-1140	79	26	(	(	PUNCT
eurjchem-1140	79	27	3.99	3.99	NUM
eurjchem-1140	79	28	)	)	PUNCT
eurjchem-1140	79	29	26.60	26.60	NUM
eurjchem-1140	79	30	(	(	PUNCT
eurjchem-1140	79	31	25.22	25.22	NUM
eurjchem-1140	79	32	)	)	PUNCT
eurjchem-1140	79	33	12.18	12.18	NUM
eurjchem-1140	79	34	(	(	PUNCT
eurjchem-1140	79	35	11.88	11.88	NUM
eurjchem-1140	79	36	)	)	PUNCT
eurjchem-1140	80	1	[	[	X
eurjchem-1140	80	2	mnlcl	mnlcl	X
eurjchem-1140	80	3	]	]	X
eurjchem-1140	80	4	yellow	yellow	ADJ
eurjchem-1140	80	5	298	298	NUM
eurjchem-1140	80	6	(	(	PUNCT
eurjchem-1140	80	7	dec	dec	PROPN
eurjchem-1140	80	8	.	.	PROPN
eurjchem-1140	80	9	)	)	PUNCT
eurjchem-1140	81	1	37.46	37.46	NUM
eurjchem-1140	81	2	(	(	PUNCT
eurjchem-1140	81	3	36.55	36.55	NUM
eurjchem-1140	81	4	)	)	PUNCT
eurjchem-1140	81	5	3.43	3.43	NUM
eurjchem-1140	81	6	(	(	PUNCT
eurjchem-1140	81	7	3.22	3.22	NUM
eurjchem-1140	81	8	)	)	PUNCT
eurjchem-1140	81	9	19.87	19.87	NUM
eurjchem-1140	81	10	(	(	PUNCT
eurjchem-1140	81	11	20.09	20.09	NUM
eurjchem-1140	81	12	)	)	PUNCT
eurjchem-1140	81	13	9.10	9.10	NUM
eurjchem-1140	81	14	(	(	PUNCT
eurjchem-1140	81	15	8.48	8.48	NUM
eurjchem-1140	81	16	)	)	PUNCT
eurjchem-1140	81	17	15.58	15.58	NUM
eurjchem-1140	81	18	(	(	PUNCT
eurjchem-1140	81	19	14.72	14.72	NUM
eurjchem-1140	81	20	)	)	PUNCT
eurjchem-1140	82	1	[	[	X
eurjchem-1140	82	2	colcl	colcl	NOUN
eurjchem-1140	82	3	]	]	X
eurjchem-1140	82	4	brown	brown	ADJ
eurjchem-1140	82	5	312	312	NUM
eurjchem-1140	82	6	(	(	PUNCT
eurjchem-1140	82	7	dec	dec	PROPN
eurjchem-1140	82	8	.	.	PROPN
eurjchem-1140	82	9	)	)	PUNCT
eurjchem-1140	83	1	37.04	37.04	NUM
eurjchem-1140	83	2	(	(	PUNCT
eurjchem-1140	83	3	36.44	36.44	NUM
eurjchem-1140	83	4	)	)	PUNCT
eurjchem-1140	83	5	3.39	3.39	NUM
eurjchem-1140	83	6	(	(	PUNCT
eurjchem-1140	83	7	2.88	2.88	NUM
eurjchem-1140	83	8	)	)	PUNCT
eurjchem-1140	83	9	19.63	19.63	NUM
eurjchem-1140	83	10	(	(	PUNCT
eurjchem-1140	83	11	19.77	19.77	NUM
eurjchem-1140	83	12	)	)	PUNCT
eurjchem-1140	83	13	8.99	8.99	NUM
eurjchem-1140	83	14	(	(	PUNCT
eurjchem-1140	83	15	8.76	8.76	NUM
eurjchem-1140	83	16	)	)	PUNCT
eurjchem-1140	83	17	16.55	16.55	NUM
eurjchem-1140	83	18	(	(	PUNCT
eurjchem-1140	83	19	15.77	15.77	NUM
eurjchem-1140	83	20	)	)	PUNCT
eurjchem-1140	84	1	[	[	X
eurjchem-1140	84	2	nilcl	nilcl	X
eurjchem-1140	84	3	]	]	X
eurjchem-1140	84	4	red	red	ADJ
eurjchem-1140	84	5	319	319	NUM
eurjchem-1140	84	6	(	(	PUNCT
eurjchem-1140	84	7	dec	dec	PROPN
eurjchem-1140	84	8	.	.	PROPN
eurjchem-1140	84	9	)	)	PUNCT
eurjchem-1140	85	1	36.59	36.59	NUM
eurjchem-1140	85	2	(	(	PUNCT
eurjchem-1140	85	3	35.39	35.39	NUM
eurjchem-1140	85	4	)	)	PUNCT
eurjchem-1140	85	5	3.15	3.15	NUM
eurjchem-1140	85	6	(	(	PUNCT
eurjchem-1140	85	7	2.00	2.00	NUM
eurjchem-1140	85	8	)	)	PUNCT
eurjchem-1140	85	9	19.39	19.39	NUM
eurjchem-1140	85	10	(	(	PUNCT
eurjchem-1140	85	11	20.11	20.11	NUM
eurjchem-1140	85	12	)	)	PUNCT
eurjchem-1140	85	13	8.82	8.82	NUM
eurjchem-1140	85	14	(	(	PUNCT
eurjchem-1140	85	15	8.11	8.11	NUM
eurjchem-1140	85	16	)	)	PUNCT
eurjchem-1140	85	17	17.11	17.11	NUM
eurjchem-1140	85	18	(	(	PUNCT
eurjchem-1140	85	19	16.17	16.17	NUM
eurjchem-1140	85	20	)	)	PUNCT
eurjchem-1140	86	1	[	[	X
eurjchem-1140	86	2	culcl	culcl	NOUN
eurjchem-1140	86	3	]	]	X
eurjchem-1140	86	4	dark	dark	ADJ
eurjchem-1140	86	5	brown	brown	PROPN
eurjchem-1140	86	6	315	315	NUM
eurjchem-1140	86	7	(	(	PUNCT
eurjchem-1140	86	8	dec	dec	PROPN
eurjchem-1140	86	9	.	.	PROPN
eurjchem-1140	86	10	)	)	PUNCT
eurjchem-1140	87	1	36.60	36.60	NUM
eurjchem-1140	87	2	(	(	PUNCT
eurjchem-1140	87	3	35.63	35.63	NUM
eurjchem-1140	87	4	)	)	PUNCT
eurjchem-1140	87	5	3.35	3.35	NUM
eurjchem-1140	87	6	(	(	PUNCT
eurjchem-1140	87	7	3.12	3.12	NUM
eurjchem-1140	87	8	)	)	PUNCT
eurjchem-1140	87	9	19.39	19.39	NUM
eurjchem-1140	87	10	(	(	PUNCT
eurjchem-1140	87	11	20.11	20.11	NUM
eurjchem-1140	87	12	)	)	PUNCT
eurjchem-1140	87	13	8	8	NUM
eurjchem-1140	87	14	.	.	X
eurjchem-1140	87	15	82	82	NUM
eurjchem-1140	87	16	(	(	PUNCT
eurjchem-1140	87	17	9.90	9.90	NUM
eurjchem-1140	87	18	)	)	PUNCT
eurjchem-1140	87	19	17.59	17.59	NUM
eurjchem-1140	87	20	(	(	PUNCT
eurjchem-1140	87	21	16.66	16.66	NUM
eurjchem-1140	87	22	)	)	PUNCT
eurjchem-1140	88	1	[	[	X
eurjchem-1140	88	2	znlcl	znlcl	X
eurjchem-1140	88	3	]	]	X
eurjchem-1140	88	4	white	white	ADJ
eurjchem-1140	88	5	off	off	ADP
eurjchem-1140	88	6	322	322	NUM
eurjchem-1140	88	7	(	(	PUNCT
eurjchem-1140	88	8	dec	dec	PROPN
eurjchem-1140	88	9	.	.	PROPN
eurjchem-1140	88	10	)	)	PUNCT
eurjchem-1140	89	1	36.38	36.38	NUM
eurjchem-1140	89	2	(	(	PUNCT
eurjchem-1140	89	3	35.00	35.00	NUM
eurjchem-1140	89	4	)	)	PUNCT
eurjchem-1140	89	5	3.34	3.34	NUM
eurjchem-1140	89	6	(	(	PUNCT
eurjchem-1140	89	7	2.80	2.80	NUM
eurjchem-1140	89	8	)	)	PUNCT
eurjchem-1140	89	9	19.29	19.29	NUM
eurjchem-1140	89	10	(	(	PUNCT
eurjchem-1140	89	11	19.79	19.79	NUM
eurjchem-1140	89	12	)	)	PUNCT
eurjchem-1140	89	13	8.92	8.92	NUM
eurjchem-1140	89	14	(	(	PUNCT
eurjchem-1140	89	15	7.97	7.97	NUM
eurjchem-1140	89	16	)	)	PUNCT
eurjchem-1140	89	17	18.22	18.22	NUM
eurjchem-1140	89	18	(	(	PUNCT
eurjchem-1140	89	19	17.55	17.55	NUM
eurjchem-1140	89	20	)	)	PUNCT
eurjchem-1140	89	21	a	a	DET
eurjchem-1140	89	22	dec	dec	PROPN
eurjchem-1140	89	23	:	:	PUNCT
eurjchem-1140	89	24	decomposed	decomposed	ADJ
eurjchem-1140	89	25	.	.	PUNCT
eurjchem-1140	90	1	b	b	X
eurjchem-1140	90	2	content	content	NOUN
eurjchem-1140	90	3	of	of	ADP
eurjchem-1140	90	4	metal	metal	NOUN
eurjchem-1140	90	5	was	be	AUX
eurjchem-1140	90	6	done	do	VERB
eurjchem-1140	90	7	by	by	ADP
eurjchem-1140	90	8	flame	flame	NOUN
eurjchem-1140	90	9	atomic	atomic	ADJ
eurjchem-1140	90	10	absorption	absorption	NOUN
eurjchem-1140	90	11	spectroscopy	spectroscopy	NOUN
eurjchem-1140	90	12	.	.	PUNCT
eurjchem-1140	91	1	table	table	NOUN
eurjchem-1140	91	2	2	2	NUM
eurjchem-1140	91	3	.	.	PUNCT
eurjchem-1140	91	4	ft‐ir	ft‐ir	ADJ
eurjchem-1140	91	5	absorptions	absorption	NOUN
eurjchem-1140	91	6	of	of	ADP
eurjchem-1140	91	7	the	the	DET
eurjchem-1140	91	8	schiff	schiff	NOUN
eurjchem-1140	91	9	base	base	NOUN
eurjchem-1140	91	10	hl	hl	NOUN
eurjchem-1140	91	11	and	and	CCONJ
eurjchem-1140	91	12	its	its	PRON
eurjchem-1140	91	13	template	template	NOUN
eurjchem-1140	91	14	metal	metal	NOUN
eurjchem-1140	91	15	complexes	complex	NOUN
eurjchem-1140	91	16	in	in	ADP
eurjchem-1140	91	17	cm‐1	cm‐1	PROPN
eurjchem-1140	91	18	*	*	PUNCT
eurjchem-1140	91	19	.	.	PUNCT
eurjchem-1140	92	1	compound	compound	VERB
eurjchem-1140	92	2	νnh	νnh	ADJ
eurjchem-1140	92	3	νc	νc	PROPN
eurjchem-1140	92	4	=	=	NOUN
eurjchem-1140	92	5	o	o	X
eurjchem-1140	92	6	νc	νc	NOUN
eurjchem-1140	92	7	=	=	NOUN
eurjchem-1140	92	8	n	n	PRON
eurjchem-1140	92	9	νc	νc	NOUN
eurjchem-1140	92	10	=	=	NOUN
eurjchem-1140	92	11	s	s	NOUN
eurjchem-1140	92	12	νc‐n	νc‐n	PROPN
eurjchem-1140	92	13	νm	νm	PROPN
eurjchem-1140	92	14	–	–	PUNCT
eurjchem-1140	92	15	n	n	PRON
eurjchem-1140	92	16	νm	νm	PROPN
eurjchem-1140	92	17	–	–	PUNCT
eurjchem-1140	92	18	o	o	X
eurjchem-1140	92	19	νm‐s	νm‐s	X
eurjchem-1140	92	20	νm‐cl	νm‐cl	ADJ
eurjchem-1140	92	21	other	other	ADJ
eurjchem-1140	92	22	bands	band	NOUN
eurjchem-1140	92	23	dmq	dmq	PROPN
eurjchem-1140	92	24	3250(m	3250(m	NOUN
eurjchem-1140	92	25	)	)	PUNCT
eurjchem-1140	92	26	1689(s	1689(s	NUM
eurjchem-1140	92	27	)	)	PUNCT
eurjchem-1140	92	28	1622(s	1622(s	NOUN
eurjchem-1140	92	29	)	)	PUNCT
eurjchem-1140	92	30	‐	‐	ADP
eurjchem-1140	92	31	1189(m	1189(m	NUM
eurjchem-1140	92	32	)	)	PUNCT
eurjchem-1140	92	33	‐	‐	NOUN
eurjchem-1140	92	34	‐	‐	ADV
eurjchem-1140	92	35	‐	‐	ADV
eurjchem-1140	92	36	‐	‐	ADV
eurjchem-1140	92	37	2964(m	2964(m	NOUN
eurjchem-1140	92	38	)	)	PUNCT
eurjchem-1140	92	39	,	,	PUNCT
eurjchem-1140	92	40	3020(w	3020(w	NUM
eurjchem-1140	92	41	)	)	PUNCT
eurjchem-1140	92	42	hl	hl	NOUN
eurjchem-1140	92	43	3320(m	3320(m	NOUN
eurjchem-1140	92	44	)	)	PUNCT
eurjchem-1140	92	45	1680(s	1680(s	NUM
eurjchem-1140	92	46	)	)	PUNCT
eurjchem-1140	92	47	1610	1610	NUM
eurjchem-1140	92	48	(	(	PUNCT
eurjchem-1140	92	49	s	s	NOUN
eurjchem-1140	92	50	)	)	PUNCT
eurjchem-1140	92	51	890(s	890(s	NUM
eurjchem-1140	92	52	)	)	PUNCT
eurjchem-1140	92	53	1150(m	1150(m	NUM
eurjchem-1140	92	54	)	)	PUNCT
eurjchem-1140	92	55	‐	‐	NOUN
eurjchem-1140	92	56	‐	‐	ADV
eurjchem-1140	92	57	‐	‐	ADV
eurjchem-1140	92	58	‐	‐	ADJ
eurjchem-1140	92	59	2976(m	2976(m	NOUN
eurjchem-1140	92	60	)	)	PUNCT
eurjchem-1140	92	61	,	,	PUNCT
eurjchem-1140	92	62	3050(w	3050(w	NUM
eurjchem-1140	92	63	)	)	PUNCT
eurjchem-1140	93	1	[	[	X
eurjchem-1140	93	2	mnlcl	mnlcl	X
eurjchem-1140	93	3	]	]	X
eurjchem-1140	93	4	3180(m	3180(m	NUM
eurjchem-1140	93	5	)	)	PUNCT
eurjchem-1140	93	6	1666(sh	1666(sh	NUM
eurjchem-1140	93	7	)	)	PUNCT
eurjchem-1140	93	8	1589(s	1589(s	NOUN
eurjchem-1140	93	9	)	)	PUNCT
eurjchem-1140	93	10	833(m	833(m	PROPN
eurjchem-1140	93	11	)	)	PUNCT
eurjchem-1140	93	12	1160(m	1160(m	NOUN
eurjchem-1140	93	13	)	)	PUNCT
eurjchem-1140	93	14	500(m	500(m	NUM
eurjchem-1140	93	15	)	)	PUNCT
eurjchem-1140	93	16	400(m	400(m	PROPN
eurjchem-1140	93	17	)	)	PUNCT
eurjchem-1140	94	1	522(m	522(m	NUM
eurjchem-1140	94	2	)	)	PUNCT
eurjchem-1140	94	3	288(w	288(w	NOUN
eurjchem-1140	94	4	)	)	PUNCT
eurjchem-1140	94	5	2984(m	2984(m	NUM
eurjchem-1140	94	6	)	)	PUNCT
eurjchem-1140	94	7	,	,	PUNCT
eurjchem-1140	94	8	3020(w	3020(w	PUNCT
eurjchem-1140	94	9	)	)	PUNCT
eurjchem-1140	95	1	[	[	X
eurjchem-1140	95	2	colcl	colcl	NOUN
eurjchem-1140	95	3	]	]	X
eurjchem-1140	95	4	3180(br	3180(br	NUM
eurjchem-1140	95	5	)	)	PUNCT
eurjchem-1140	95	6	1677(s	1677(s	NUM
eurjchem-1140	95	7	)	)	PUNCT
eurjchem-1140	95	8	1569(s	1569(s	X
eurjchem-1140	95	9	)	)	PUNCT
eurjchem-1140	95	10	780(m	780(m	NOUN
eurjchem-1140	95	11	)	)	PUNCT
eurjchem-1140	95	12	1144(m	1144(m	NUM
eurjchem-1140	95	13	)	)	PUNCT
eurjchem-1140	96	1	490(m	490(m	NOUN
eurjchem-1140	96	2	)	)	PUNCT
eurjchem-1140	96	3	430(m	430(m	PROPN
eurjchem-1140	96	4	)	)	PUNCT
eurjchem-1140	96	5	540(m	540(m	PROPN
eurjchem-1140	96	6	)	)	PUNCT
eurjchem-1140	96	7	280(w	280(w	NUM
eurjchem-1140	96	8	)	)	PUNCT
eurjchem-1140	96	9	2976(s	2976(s	NUM
eurjchem-1140	96	10	)	)	PUNCT
eurjchem-1140	96	11	,	,	PUNCT
eurjchem-1140	96	12	3050(w	3050(w	NUM
eurjchem-1140	96	13	)	)	PUNCT
eurjchem-1140	97	1	[	[	X
eurjchem-1140	97	2	nilcl	nilcl	X
eurjchem-1140	97	3	]	]	X
eurjchem-1140	97	4	3235(br	3235(br	NUM
eurjchem-1140	97	5	)	)	PUNCT
eurjchem-1140	97	6	1666(sh	1666(sh	NUM
eurjchem-1140	97	7	)	)	PUNCT
eurjchem-1140	97	8	1577(s	1577(s	NUM
eurjchem-1140	97	9	)	)	PUNCT
eurjchem-1140	98	1	835(m	835(m	PROPN
eurjchem-1140	98	2	)	)	PUNCT
eurjchem-1140	98	3	1140(m	1140(m	NOUN
eurjchem-1140	98	4	)	)	PUNCT
eurjchem-1140	99	1	480(m	480(m	NOUN
eurjchem-1140	99	2	)	)	PUNCT
eurjchem-1140	99	3	430(w	430(w	PROPN
eurjchem-1140	99	4	)	)	PUNCT
eurjchem-1140	99	5	533(m	533(m	PROPN
eurjchem-1140	99	6	)	)	PUNCT
eurjchem-1140	99	7	370(w	370(w	PROPN
eurjchem-1140	99	8	)	)	PUNCT
eurjchem-1140	99	9	2933(m	2933(m	NOUN
eurjchem-1140	99	10	)	)	PUNCT
eurjchem-1140	99	11	,	,	PUNCT
eurjchem-1140	99	12	3080(w	3080(w	NUM
eurjchem-1140	99	13	)	)	PUNCT
eurjchem-1140	100	1	[	[	X
eurjchem-1140	100	2	culcl	culcl	NOUN
eurjchem-1140	100	3	]	]	X
eurjchem-1140	100	4	3169(m	3169(m	NUM
eurjchem-1140	100	5	)	)	PUNCT
eurjchem-1140	100	6	1640(s	1640(s	X
eurjchem-1140	100	7	)	)	PUNCT
eurjchem-1140	100	8	1580(s	1580(s	X
eurjchem-1140	100	9	)	)	PUNCT
eurjchem-1140	101	1	740(m	740(m	NOUN
eurjchem-1140	101	2	)	)	PUNCT
eurjchem-1140	101	3	1180(m	1180(m	NUM
eurjchem-1140	101	4	)	)	PUNCT
eurjchem-1140	101	5	485(m	485(m	PROPN
eurjchem-1140	101	6	)	)	PUNCT
eurjchem-1140	101	7	433(w	433(w	PROPN
eurjchem-1140	101	8	)	)	PUNCT
eurjchem-1140	101	9	525(m	525(m	PROPN
eurjchem-1140	101	10	)	)	PUNCT
eurjchem-1140	101	11	280(w	280(w	PROPN
eurjchem-1140	101	12	)	)	PUNCT
eurjchem-1140	101	13	,	,	PUNCT
eurjchem-1140	101	14	344(w	344(w	NUM
eurjchem-1140	101	15	)	)	PUNCT
eurjchem-1140	101	16	2890(m	2890(m	NUM
eurjchem-1140	101	17	)	)	PUNCT
eurjchem-1140	101	18	,	,	PUNCT
eurjchem-1140	101	19	3060(w	3060(w	NOUN
eurjchem-1140	101	20	)	)	PUNCT
eurjchem-1140	102	1	[	[	X
eurjchem-1140	102	2	znlcl	znlcl	X
eurjchem-1140	102	3	]	]	X
eurjchem-1140	102	4	3300(m	3300(m	NUM
eurjchem-1140	102	5	)	)	PUNCT
eurjchem-1140	102	6	1655(sh	1655(sh	NUM
eurjchem-1140	102	7	)	)	PUNCT
eurjchem-1140	103	1	1575(s	1575(s	NUM
eurjchem-1140	103	2	)	)	PUNCT
eurjchem-1140	103	3	826	826	NUM
eurjchem-1140	103	4	(	(	PUNCT
eurjchem-1140	103	5	m	m	NOUN
eurjchem-1140	103	6	)	)	PUNCT
eurjchem-1140	103	7	1060(m	1060(m	NUM
eurjchem-1140	103	8	)	)	PUNCT
eurjchem-1140	103	9	500(w	500(w	NOUN
eurjchem-1140	103	10	)	)	PUNCT
eurjchem-1140	103	11	444(w	444(w	NOUN
eurjchem-1140	103	12	)	)	PUNCT
eurjchem-1140	103	13	518(m	518(m	PROPN
eurjchem-1140	103	14	)	)	PUNCT
eurjchem-1140	103	15	375(w	375(w	NUM
eurjchem-1140	103	16	)	)	PUNCT
eurjchem-1140	103	17	2980(s	2980(s	NUM
eurjchem-1140	103	18	)	)	PUNCT
eurjchem-1140	103	19	,	,	PUNCT
eurjchem-1140	104	1	3013(w	3013(w	ADV
eurjchem-1140	104	2	)	)	PUNCT
eurjchem-1140	105	1	*	*	PUNCT
eurjchem-1140	105	2	s	s	X
eurjchem-1140	105	3	:	:	PUNCT
eurjchem-1140	105	4	strong	strong	ADJ
eurjchem-1140	105	5	,	,	PUNCT
eurjchem-1140	105	6	m	m	NOUN
eurjchem-1140	105	7	:	:	PUNCT
eurjchem-1140	105	8	medium	medium	ADJ
eurjchem-1140	105	9	,	,	PUNCT
eurjchem-1140	105	10	br	br	NOUN
eurjchem-1140	105	11	:	:	PUNCT
eurjchem-1140	105	12	broad	broad	ADJ
eurjchem-1140	105	13	,	,	PUNCT
eurjchem-1140	105	14	w	w	ADJ
eurjchem-1140	105	15	:	:	PUNCT
eurjchem-1140	105	16	weak	weak	ADJ
eurjchem-1140	105	17	,	,	PUNCT
eurjchem-1140	105	18	sh	sh	PROPN
eurjchem-1140	105	19	:	:	PUNCT
eurjchem-1140	105	20	shoulder	shoulder	NOUN
eurjchem-1140	105	21	.	.	PUNCT
eurjchem-1140	105	22	table	table	NOUN
eurjchem-1140	105	23	3	3	NUM
eurjchem-1140	105	24	.	.	PUNCT
eurjchem-1140	106	1	the	the	DET
eurjchem-1140	106	2	electronic	electronic	ADJ
eurjchem-1140	106	3	spectra	spectra	NOUN
eurjchem-1140	106	4	and	and	CCONJ
eurjchem-1140	106	5	molar	molar	ADJ
eurjchem-1140	106	6	conductance	conductance	NOUN
eurjchem-1140	106	7	of	of	ADP
eurjchem-1140	106	8	the	the	DET
eurjchem-1140	106	9	prepared	prepared	ADJ
eurjchem-1140	106	10	complexes	complex	NOUN
eurjchem-1140	106	11	*	*	PUNCT
eurjchem-1140	106	12	.	.	PUNCT
eurjchem-1140	107	1	complex	complex	ADJ
eurjchem-1140	107	2	uv‐visible	uv‐visible	ADJ
eurjchem-1140	107	3	,	,	PUNCT
eurjchem-1140	107	4	λ	λ	PROPN
eurjchem-1140	107	5	(	(	PUNCT
eurjchem-1140	107	6	nm	nm	PROPN
eurjchem-1140	107	7	)	)	PUNCT
eurjchem-1140	107	8	μ	μ	PROPN
eurjchem-1140	107	9	(	(	PUNCT
eurjchem-1140	107	10	b.m	b.m	PROPN
eurjchem-1140	107	11	.	.	PROPN
eurjchem-1140	107	12	)	)	PUNCT
eurjchem-1140	108	1	λm	λm	X
eurjchem-1140	108	2	(	(	PUNCT
eurjchem-1140	108	3	s.mol‐1.cm2	s.mol‐1.cm2	ADJ
eurjchem-1140	108	4	)	)	PUNCT
eurjchem-1140	108	5	geometry	geometry	NOUN
eurjchem-1140	108	6	dmq	dmq	NOUN
eurjchem-1140	108	7	290,330	290,330	NUM
eurjchem-1140	108	8	‐	‐	NOUN
eurjchem-1140	108	9	‐	‐	ADV
eurjchem-1140	108	10	‐	‐	PUNCT
eurjchem-1140	108	11	hl	hl	NOUN
eurjchem-1140	108	12	222,350	222,350	NUM
eurjchem-1140	108	13	‐	‐	NOUN
eurjchem-1140	108	14	‐	‐	ADV
eurjchem-1140	108	15	‐	‐	NOUN
eurjchem-1140	108	16	[	[	X
eurjchem-1140	108	17	mnlcl	mnlcl	NOUN
eurjchem-1140	108	18	]	]	X
eurjchem-1140	108	19	340,470	340,470	NUM
eurjchem-1140	108	20	5.45	5.45	NUM
eurjchem-1140	108	21	12	12	NUM
eurjchem-1140	108	22	tetrahedral	tetrahedral	ADJ
eurjchem-1140	108	23	[	[	X
eurjchem-1140	108	24	colcl	colcl	NOUN
eurjchem-1140	108	25	]	]	X
eurjchem-1140	108	26	390,550,670	390,550,670	NUM
eurjchem-1140	108	27	4.22	4.22	NUM
eurjchem-1140	108	28	67	67	NUM
eurjchem-1140	108	29	tetrahedral	tetrahedral	ADJ
eurjchem-1140	108	30	[	[	X
eurjchem-1140	108	31	nilcl	nilcl	NOUN
eurjchem-1140	108	32	]	]	X
eurjchem-1140	108	33	388,650,700	388,650,700	NUM
eurjchem-1140	108	34	2.84	2.84	NUM
eurjchem-1140	108	35	22	22	NUM
eurjchem-1140	108	36	tetrahedral	tetrahedral	ADJ
eurjchem-1140	109	1	[	[	X
eurjchem-1140	109	2	culcl	culcl	NOUN
eurjchem-1140	109	3	]	]	X
eurjchem-1140	109	4	370,690	370,690	NUM
eurjchem-1140	109	5	1.56	1.56	NUM
eurjchem-1140	109	6	10	10	NUM
eurjchem-1140	109	7	tetrahedral	tetrahedral	ADJ
eurjchem-1140	109	8	[	[	X
eurjchem-1140	109	9	znlcl	znlcl	X
eurjchem-1140	109	10	]	]	X
eurjchem-1140	109	11	344,365(ct	344,365(ct	NUM
eurjchem-1140	109	12	)	)	PUNCT
eurjchem-1140	109	13	0	0	NUM
eurjchem-1140	109	14	13	13	NUM
eurjchem-1140	109	15	tetrahedral	tetrahedral	NOUN
eurjchem-1140	109	16	*	*	PUNCT
eurjchem-1140	109	17	λm	λm	NOUN
eurjchem-1140	109	18	=	=	PUNCT
eurjchem-1140	109	19	molar	molar	ADJ
eurjchem-1140	109	20	conductance	conductance	NOUN
eurjchem-1140	109	21	's	's	PART
eurjchem-1140	109	22	were	be	AUX
eurjchem-1140	109	23	measured	measure	VERB
eurjchem-1140	109	24	in	in	ADP
eurjchem-1140	109	25	dmf	dmf	PROPN
eurjchem-1140	109	26	solutions	solution	NOUN
eurjchem-1140	109	27	and	and	CCONJ
eurjchem-1140	109	28	ct	ct	NOUN
eurjchem-1140	109	29	:	:	PUNCT
eurjchem-1140	109	30	charge	charge	NOUN
eurjchem-1140	109	31	transfer	transfer	NOUN
eurjchem-1140	109	32	.	.	PUNCT
eurjchem-1140	110	1	the	the	DET
eurjchem-1140	110	2	absence	absence	NOUN
eurjchem-1140	110	3	of	of	ADP
eurjchem-1140	110	4	a	a	DET
eurjchem-1140	110	5	band	band	NOUN
eurjchem-1140	110	6	in	in	ADP
eurjchem-1140	110	7	the	the	DET
eurjchem-1140	110	8	region	region	NOUN
eurjchem-1140	110	9	2500‐2600	2500‐2600	NUM
eurjchem-1140	110	10	cm‐1	cm‐1	NOUN
eurjchem-1140	110	11	,	,	PUNCT
eurjchem-1140	110	12	which	which	PRON
eurjchem-1140	110	13	is	be	AUX
eurjchem-1140	110	14	characteristic	characteristic	ADJ
eurjchem-1140	110	15	of	of	ADP
eurjchem-1140	110	16	thiol	thiol	PROPN
eurjchem-1140	110	17	group	group	PROPN
eurjchem-1140	110	18	ν(sh	ν(sh	PROPN
eurjchem-1140	110	19	)	)	PUNCT
eurjchem-1140	110	20	,	,	PUNCT
eurjchem-1140	110	21	suggests	suggest	VERB
eurjchem-1140	110	22	the	the	DET
eurjchem-1140	110	23	stable	stable	NOUN
eurjchem-1140	110	24	of	of	ADP
eurjchem-1140	110	25	the	the	DET
eurjchem-1140	110	26	thione	thione	NOUN
eurjchem-1140	110	27	amide	amide	NOUN
eurjchem-1140	110	28	form	form	NOUN
eurjchem-1140	110	29	in	in	ADP
eurjchem-1140	110	30	the	the	DET
eurjchem-1140	110	31	solid	solid	ADJ
eurjchem-1140	110	32	state	state	NOUN
eurjchem-1140	110	33	,	,	PUNCT
eurjchem-1140	110	34	hence	hence	ADV
eurjchem-1140	110	35	decline	decline	VERB
eurjchem-1140	110	36	the	the	DET
eurjchem-1140	110	37	thione‐	thione‐	PROPN
eurjchem-1140	110	38	thiol	thiol	ADJ
eurjchem-1140	110	39	tautomerism	tautomerism	NOUN
eurjchem-1140	110	40	(	(	PUNCT
eurjchem-1140	110	41	h	h	NOUN
eurjchem-1140	110	42	–	–	PUNCT
eurjchem-1140	110	43	n	n	CCONJ
eurjchem-1140	110	44	–	–	PUNCT
eurjchem-1140	110	45	c	c	NOUN
eurjchem-1140	110	46	=	=	SYM
eurjchem-1140	110	47	s	s	NOUN
eurjchem-1140	110	48	,	,	PUNCT
eurjchem-1140	110	49	c	c	NOUN
eurjchem-1140	110	50	=	=	SYM
eurjchem-1140	110	51	n	n	CCONJ
eurjchem-1140	110	52	–	–	PUNCT
eurjchem-1140	110	53	sh	sh	PROPN
eurjchem-1140	110	54	)	)	PUNCT
eurjchem-1140	110	55	in	in	ADP
eurjchem-1140	110	56	the	the	DET
eurjchem-1140	110	57	present	present	ADJ
eurjchem-1140	110	58	set	set	NOUN
eurjchem-1140	110	59	of	of	ADP
eurjchem-1140	110	60	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-1140	110	61	ligand	ligand	NOUN
eurjchem-1140	111	1	[	[	X
eurjchem-1140	111	2	18,19	18,19	NUM
eurjchem-1140	111	3	]	]	PUNCT
eurjchem-1140	111	4	.	.	PUNCT
eurjchem-1140	112	1	the	the	DET
eurjchem-1140	112	2	thioamidic	thioamidic	ADJ
eurjchem-1140	112	3	coupled	couple	VERB
eurjchem-1140	112	4	vibrations	vibration	NOUN
eurjchem-1140	112	5	,	,	PUNCT
eurjchem-1140	112	6	i	i	PRON
eurjchem-1140	112	7	[	[	X
eurjchem-1140	112	8	ν(cn	ν(cn	NUM
eurjchem-1140	112	9	)	)	PUNCT
eurjchem-1140	112	10	and	and	CCONJ
eurjchem-1140	112	11	ν(nh	ν(nh	NOUN
eurjchem-1140	112	12	)	)	PUNCT
eurjchem-1140	113	1	+	+	CCONJ
eurjchem-1140	113	2	δ(ch	δ(ch	NOUN
eurjchem-1140	113	3	)	)	PUNCT
eurjchem-1140	113	4	]	]	PUNCT
eurjchem-1140	113	5	,	,	PUNCT
eurjchem-1140	113	6	ii	ii	PROPN
eurjchem-1140	114	1	[	[	X
eurjchem-1140	114	2	ν(cn	ν(cn	NUM
eurjchem-1140	114	3	)	)	PUNCT
eurjchem-1140	114	4	and	and	CCONJ
eurjchem-1140	114	5	ν(cs	ν(c	NOUN
eurjchem-1140	114	6	)	)	PUNCT
eurjchem-1140	114	7	]	]	PUNCT
eurjchem-1140	114	8	,	,	PUNCT
eurjchem-1140	114	9	iii	iii	X
eurjchem-1140	115	1	[	[	X
eurjchem-1140	115	2	ν(cs	ν(c	NOUN
eurjchem-1140	115	3	)	)	PUNCT
eurjchem-1140	115	4	and	and	CCONJ
eurjchem-1140	115	5	ν(cs	ν(c	NOUN
eurjchem-1140	115	6	)	)	PUNCT
eurjchem-1140	116	1	+	+	CCONJ
eurjchem-1140	116	2	ν(cn	ν(cn	NUM
eurjchem-1140	116	3	)	)	PUNCT
eurjchem-1140	116	4	]	]	PUNCT
eurjchem-1140	116	5	and	and	CCONJ
eurjchem-1140	116	6	iv	iv	NUM
eurjchem-1140	116	7	ν(cs	ν(c	NOUN
eurjchem-1140	116	8	)	)	PUNCT
eurjchem-1140	116	9	were	be	AUX
eurjchem-1140	116	10	observed	observe	VERB
eurjchem-1140	116	11	around	around	ADP
eurjchem-1140	116	12	1600	1600	NUM
eurjchem-1140	116	13	,	,	PUNCT
eurjchem-1140	116	14	1545	1545	NUM
eurjchem-1140	116	15	,	,	PUNCT
eurjchem-1140	116	16	1460	1460	NUM
eurjchem-1140	116	17	and	and	CCONJ
eurjchem-1140	116	18	940	940	NUM
eurjchem-1140	116	19	cm‐1	cm‐1	NOUN
eurjchem-1140	116	20	confirm	confirm	VERB
eurjchem-1140	116	21	the	the	DET
eurjchem-1140	116	22	thio‐keto	thio‐keto	NOUN
eurjchem-1140	116	23	form	form	NOUN
eurjchem-1140	116	24	of	of	ADP
eurjchem-1140	116	25	ligand	ligand	NOUN
eurjchem-1140	117	1	[	[	X
eurjchem-1140	117	2	15,16	15,16	NUM
eurjchem-1140	117	3	]	]	PUNCT
eurjchem-1140	117	4	.	.	PUNCT
eurjchem-1140	118	1	the	the	DET
eurjchem-1140	118	2	ν(c	ν(c	PROPN
eurjchem-1140	118	3	=	=	SYM
eurjchem-1140	118	4	o	o	NOUN
eurjchem-1140	118	5	)	)	PUNCT
eurjchem-1140	118	6	of	of	ADP
eurjchem-1140	118	7	pyrazine	pyrazine	NOUN
eurjchem-1140	118	8	ring	ring	NOUN
eurjchem-1140	118	9	was	be	AUX
eurjchem-1140	118	10	observed	observe	VERB
eurjchem-1140	118	11	as	as	ADP
eurjchem-1140	118	12	a	a	DET
eurjchem-1140	118	13	sharp	sharp	ADJ
eurjchem-1140	118	14	,	,	PUNCT
eurjchem-1140	118	15	intense	intense	ADJ
eurjchem-1140	118	16	band	band	NOUN
eurjchem-1140	118	17	at	at	ADP
eurjchem-1140	118	18	1683	1683	NUM
eurjchem-1140	118	19	cm‐1	cm‐1	NOUN
eurjchem-1140	118	20	and	and	CCONJ
eurjchem-1140	118	21	the	the	DET
eurjchem-1140	118	22	stretching	stretch	VERB
eurjchem-1140	118	23	vibrations	vibration	NOUN
eurjchem-1140	118	24	of	of	ADP
eurjchem-1140	118	25	azomethine	azomethine	NOUN
eurjchem-1140	118	26	functionality	functionality	NOUN
eurjchem-1140	118	27	ν(c	ν(c	PROPN
eurjchem-1140	118	28	=	=	SYM
eurjchem-1140	118	29	n	n	CCONJ
eurjchem-1140	118	30	)	)	PUNCT
eurjchem-1140	118	31	were	be	AUX
eurjchem-1140	118	32	observed	observe	VERB
eurjchem-1140	118	33	near	near	ADP
eurjchem-1140	118	34	1620	1620	NUM
eurjchem-1140	118	35	cm‐1	cm‐1	NOUN
eurjchem-1140	118	36	.	.	PUNCT
eurjchem-1140	119	1	the	the	DET
eurjchem-1140	119	2	absorption	absorption	NOUN
eurjchem-1140	119	3	of	of	ADP
eurjchem-1140	119	4	ν(nh	ν(nh	NOUN
eurjchem-1140	119	5	)	)	PUNCT
eurjchem-1140	119	6	related	relate	VERB
eurjchem-1140	119	7	to	to	ADP
eurjchem-1140	119	8	quinoxaline	quinoxaline	PROPN
eurjchem-1140	119	9	ring	ring	NOUN
eurjchem-1140	119	10	and	and	CCONJ
eurjchem-1140	119	11	hydrazine	hydrazine	NOUN
eurjchem-1140	119	12	ν(nh2	ν(nh2	PROPN
eurjchem-1140	119	13	)	)	PUNCT
eurjchem-1140	119	14	were	be	AUX
eurjchem-1140	119	15	observed	observe	VERB
eurjchem-1140	119	16	around	around	ADP
eurjchem-1140	119	17	3400	3400	NUM
eurjchem-1140	119	18	cm‐1	cm‐1	NOUN
eurjchem-1140	119	19	as	as	ADV
eurjchem-1140	119	20	double	double	ADJ
eurjchem-1140	119	21	intense	intense	ADJ
eurjchem-1140	119	22	band	band	NOUN
eurjchem-1140	119	23	[	[	X
eurjchem-1140	119	24	20	20	NUM
eurjchem-1140	119	25	]	]	PUNCT
eurjchem-1140	119	26	.	.	PUNCT
eurjchem-1140	120	1	for	for	ADP
eurjchem-1140	120	2	the	the	DET
eurjchem-1140	120	3	free	free	ADJ
eurjchem-1140	120	4	schiff	schiff	PROPN
eurjchem-1140	120	5	base	base	PROPN
eurjchem-1140	120	6	hl	hl	PROPN
eurjchem-1140	120	7	,	,	PUNCT
eurjchem-1140	120	8	a	a	DET
eurjchem-1140	120	9	sharp	sharp	ADJ
eurjchem-1140	120	10	band	band	NOUN
eurjchem-1140	120	11	at	at	ADP
eurjchem-1140	120	12	1689	1689	NUM
eurjchem-1140	120	13	cm‐1	cm‐1	NOUN
eurjchem-1140	120	14	is	be	AUX
eurjchem-1140	120	15	assigned	assign	VERB
eurjchem-1140	120	16	to	to	ADP
eurjchem-1140	120	17	ν(c	ν(c	NOUN
eurjchem-1140	120	18	=	=	SYM
eurjchem-1140	120	19	o	o	NOUN
eurjchem-1140	120	20	)	)	PUNCT
eurjchem-1140	121	1	[	[	X
eurjchem-1140	121	2	19	19	NUM
eurjchem-1140	121	3	]	]	PUNCT
eurjchem-1140	121	4	.	.	PUNCT
eurjchem-1140	122	1	in	in	ADP
eurjchem-1140	122	2	the	the	DET
eurjchem-1140	122	3	complexes	complex	NOUN
eurjchem-1140	122	4	,	,	PUNCT
eurjchem-1140	122	5	it	it	PRON
eurjchem-1140	122	6	shifts	shift	VERB
eurjchem-1140	122	7	to	to	ADP
eurjchem-1140	122	8	lower	low	ADJ
eurjchem-1140	122	9	frequency	frequency	NOUN
eurjchem-1140	122	10	region	region	NOUN
eurjchem-1140	122	11	(	(	PUNCT
eurjchem-1140	122	12	1680‐1644	1680‐1644	NUM
eurjchem-1140	122	13	cm‐1	cm‐1	NOUN
eurjchem-1140	122	14	)	)	PUNCT
eurjchem-1140	122	15	due	due	ADP
eurjchem-1140	122	16	to	to	ADP
eurjchem-1140	122	17	the	the	DET
eurjchem-1140	122	18	carbonyl	carbonyl	NOUN
eurjchem-1140	122	19	oxygen	oxygen	NOUN
eurjchem-1140	122	20	coordination	coordination	NOUN
eurjchem-1140	122	21	[	[	X
eurjchem-1140	122	22	19	19	NUM
eurjchem-1140	122	23	]	]	PUNCT
eurjchem-1140	122	24	.	.	PUNCT
eurjchem-1140	123	1	in	in	ADP
eurjchem-1140	123	2	the	the	DET
eurjchem-1140	123	3	spectra	spectra	NOUN
eurjchem-1140	123	4	of	of	ADP
eurjchem-1140	123	5	all	all	DET
eurjchem-1140	123	6	metal	metal	NOUN
eurjchem-1140	123	7	complexes	complex	NOUN
eurjchem-1140	123	8	,	,	PUNCT
eurjchem-1140	123	9	weak	weak	ADJ
eurjchem-1140	123	10	bands	band	NOUN
eurjchem-1140	123	11	appeared	appear	VERB
eurjchem-1140	123	12	in	in	ADP
eurjchem-1140	123	13	the	the	DET
eurjchem-1140	123	14	far‐infrared	far‐infrare	VERB
eurjchem-1140	123	15	regions	region	NOUN
eurjchem-1140	123	16	270‐375	270‐375	PROPN
eurjchem-1140	123	17	cm‐1	cm‐1	PROPN
eurjchem-1140	123	18	,	,	PUNCT
eurjchem-1140	123	19	this	this	PRON
eurjchem-1140	123	20	may	may	AUX
eurjchem-1140	123	21	be	be	AUX
eurjchem-1140	123	22	attributed	attribute	VERB
eurjchem-1140	123	23	to	to	ADP
eurjchem-1140	123	24	m‐	m‐	NOUN
eurjchem-1140	123	25	cl	cl	NOUN
eurjchem-1140	123	26	bonds	bond	NOUN
eurjchem-1140	123	27	and	and	CCONJ
eurjchem-1140	123	28	support	support	VERB
eurjchem-1140	123	29	the	the	DET
eurjchem-1140	123	30	participation	participation	NOUN
eurjchem-1140	123	31	of	of	ADP
eurjchem-1140	123	32	chloride	chloride	NOUN
eurjchem-1140	123	33	ions	ion	NOUN
eurjchem-1140	123	34	in	in	ADP
eurjchem-1140	123	35	inner	inner	ADJ
eurjchem-1140	123	36	sphere	sphere	NOUN
eurjchem-1140	123	37	of	of	ADP
eurjchem-1140	123	38	metal	metal	NOUN
eurjchem-1140	123	39	complexes	complex	NOUN
eurjchem-1140	123	40	structures	structure	NOUN
eurjchem-1140	124	1	[	[	X
eurjchem-1140	124	2	14,16	14,16	NUM
eurjchem-1140	124	3	]	]	X
eurjchem-1140	124	4	.	.	PUNCT
eurjchem-1140	125	1	a	a	DET
eurjchem-1140	125	2	new	new	ADJ
eurjchem-1140	125	3	band	band	NOUN
eurjchem-1140	125	4	was	be	AUX
eurjchem-1140	125	5	appeared	appear	VERB
eurjchem-1140	125	6	around	around	ADP
eurjchem-1140	125	7	1230‐1200	1230‐1200	NUM
eurjchem-1140	125	8	cm‐1	cm‐1	NOUN
eurjchem-1140	125	9	attributable	attributable	ADJ
eurjchem-1140	125	10	to	to	ADP
eurjchem-1140	125	11	ν(c	ν(c	PROPN
eurjchem-1140	125	12	–	–	PUNCT
eurjchem-1140	125	13	o	o	NOUN
eurjchem-1140	125	14	)	)	PUNCT
eurjchem-1140	125	15	confirms	confirm	VERB
eurjchem-1140	125	16	the	the	DET
eurjchem-1140	125	17	same	same	ADJ
eurjchem-1140	125	18	oxygen	oxygen	NOUN
eurjchem-1140	125	19	after	after	ADP
eurjchem-1140	125	20	deprotonation	deprotonation	NOUN
eurjchem-1140	125	21	.	.	PUNCT
eurjchem-1140	126	1	the	the	DET
eurjchem-1140	126	2	band	band	NOUN
eurjchem-1140	126	3	due	due	ADP
eurjchem-1140	126	4	to	to	ADP
eurjchem-1140	126	5	ν(c	ν(c	NOUN
eurjchem-1140	126	6	=	=	SYM
eurjchem-1140	126	7	n	n	CCONJ
eurjchem-1140	126	8	)	)	PUNCT
eurjchem-1140	126	9	has	have	AUX
eurjchem-1140	126	10	been	be	AUX
eurjchem-1140	126	11	shifted	shift	VERB
eurjchem-1140	126	12	to	to	ADP
eurjchem-1140	126	13	the	the	DET
eurjchem-1140	126	14	lower	low	ADJ
eurjchem-1140	126	15	frequency	frequency	NOUN
eurjchem-1140	126	16	side	side	NOUN
eurjchem-1140	126	17	in	in	ADP
eurjchem-1140	126	18	all	all	DET
eurjchem-1140	126	19	the	the	DET
eurjchem-1140	126	20	complexes	complex	NOUN
eurjchem-1140	126	21	,	,	PUNCT
eurjchem-1140	126	22	owing	owe	VERB
eurjchem-1140	126	23	to	to	ADP
eurjchem-1140	126	24	the	the	DET
eurjchem-1140	126	25	coordination	coordination	NOUN
eurjchem-1140	126	26	of	of	ADP
eurjchem-1140	126	27	nitrogen	nitrogen	NOUN
eurjchem-1140	126	28	atom	atom	NOUN
eurjchem-1140	126	29	of	of	ADP
eurjchem-1140	126	30	azomethine	azomethine	NOUN
eurjchem-1140	126	31	c	c	X
eurjchem-1140	126	32	=	=	NOUN
eurjchem-1140	126	33	n‐	n‐	NOUN
eurjchem-1140	126	34	moiety	moiety	NOUN
eurjchem-1140	127	1	[	[	X
eurjchem-1140	127	2	20‐22	20‐22	NUM
eurjchem-1140	127	3	]	]	PUNCT
eurjchem-1140	127	4	.	.	PUNCT
eurjchem-1140	128	1	the	the	DET
eurjchem-1140	128	2	thioamide	thioamide	ADJ
eurjchem-1140	128	3	bands	band	NOUN
eurjchem-1140	128	4	having	have	VERB
eurjchem-1140	128	5	major	major	ADJ
eurjchem-1140	128	6	contribution	contribution	NOUN
eurjchem-1140	128	7	from	from	ADP
eurjchem-1140	128	8	the	the	DET
eurjchem-1140	128	9	ν(c	ν(c	PROPN
eurjchem-1140	128	10	=	=	SYM
eurjchem-1140	128	11	s	s	NOUN
eurjchem-1140	128	12	)	)	PUNCT
eurjchem-1140	128	13	group	group	NOUN
eurjchem-1140	128	14	in	in	ADP
eurjchem-1140	128	15	the	the	DET
eurjchem-1140	128	16	regions	region	NOUN
eurjchem-1140	128	17	890cm‐1	890cm‐1	NUM
eurjchem-1140	128	18	which	which	PRON
eurjchem-1140	128	19	were	be	AUX
eurjchem-1140	128	20	disappeared	disappear	VERB
eurjchem-1140	128	21	in	in	ADP
eurjchem-1140	128	22	the	the	DET
eurjchem-1140	128	23	ir	ir	PROPN
eurjchem-1140	128	24	spectra	spectra	NOUN
eurjchem-1140	128	25	of	of	ADP
eurjchem-1140	128	26	all	all	DET
eurjchem-1140	128	27	complexes	complex	NOUN
eurjchem-1140	128	28	,	,	PUNCT
eurjchem-1140	128	29	thus	thus	ADV
eurjchem-1140	128	30	indicates	indicate	VERB
eurjchem-1140	128	31	the	the	DET
eurjchem-1140	128	32	transformation	transformation	NOUN
eurjchem-1140	128	33	to	to	PART
eurjchem-1140	128	34	thiol	thiol	NOUN
eurjchem-1140	128	35	form	form	VERB
eurjchem-1140	128	36	up	up	ADP
eurjchem-1140	128	37	on	on	ADP
eurjchem-1140	128	38	coordination	coordination	NOUN
eurjchem-1140	128	39	with	with	ADP
eurjchem-1140	128	40	central	central	ADJ
eurjchem-1140	128	41	metal	metal	NOUN
eurjchem-1140	128	42	ions	ion	NOUN
eurjchem-1140	128	43	.	.	PUNCT
eurjchem-1140	129	1	it	it	PRON
eurjchem-1140	129	2	is	be	AUX
eurjchem-1140	129	3	further	far	ADV
eurjchem-1140	129	4	supported	support	VERB
eurjchem-1140	129	5	by	by	ADP
eurjchem-1140	129	6	the	the	DET
eurjchem-1140	129	7	weak	weak	ADJ
eurjchem-1140	129	8	absorption	absorption	NOUN
eurjchem-1140	129	9	at	at	ADP
eurjchem-1140	129	10	770‐835	770‐835	PROPN
eurjchem-1140	129	11	cm‐1	cm‐1	PROPN
eurjchem-1140	129	12	attributable	attributable	ADJ
eurjchem-1140	129	13	to	to	ADP
eurjchem-1140	129	14	ν(c	ν(c	PROPN
eurjchem-1140	129	15	–	–	PUNCT
eurjchem-1140	129	16	s	s	NOUN
eurjchem-1140	129	17	)	)	PUNCT
eurjchem-1140	129	18	.	.	PUNCT
eurjchem-1140	130	1	the	the	DET
eurjchem-1140	130	2	absence	absence	NOUN
eurjchem-1140	130	3	of	of	ADP
eurjchem-1140	130	4	ν(s	ν(s	NOUN
eurjchem-1140	130	5	–	–	PUNCT
eurjchem-1140	130	6	h	h	NOUN
eurjchem-1140	130	7	)	)	PUNCT
eurjchem-1140	130	8	in	in	ADP
eurjchem-1140	130	9	the	the	DET
eurjchem-1140	130	10	complexes	complex	NOUN
eurjchem-1140	130	11	suggests	suggest	VERB
eurjchem-1140	130	12	the	the	DET
eurjchem-1140	130	13	coordination	coordination	NOUN
eurjchem-1140	130	14	of	of	ADP
eurjchem-1140	130	15	sulfur	sulfur	NOUN
eurjchem-1140	130	16	through	through	ADP
eurjchem-1140	130	17	deprotonation	deprotonation	NOUN
eurjchem-1140	130	18	.	.	PUNCT
eurjchem-1140	131	1	the	the	DET
eurjchem-1140	131	2	bands	band	NOUN
eurjchem-1140	131	3	due	due	ADP
eurjchem-1140	131	4	to	to	ADP
eurjchem-1140	131	5	ν(nh	ν(nh	NOUN
eurjchem-1140	131	6	)	)	PUNCT
eurjchem-1140	131	7	are	be	AUX
eurjchem-1140	131	8	broadened	broaden	VERB
eurjchem-1140	131	9	in	in	ADP
eurjchem-1140	131	10	all	all	DET
eurjchem-1140	131	11	the	the	DET
eurjchem-1140	131	12	complexes	complex	NOUN
eurjchem-1140	131	13	due	due	ADP
eurjchem-1140	131	14	to	to	ADP
eurjchem-1140	131	15	the	the	DET
eurjchem-1140	131	16	overlapping	overlapping	NOUN
eurjchem-1140	131	17	of	of	ADP
eurjchem-1140	131	18	ν(oh	ν(oh	NOUN
eurjchem-1140	131	19	)	)	PUNCT
eurjchem-1140	131	20	bands	band	NOUN
eurjchem-1140	131	21	of	of	ADP
eurjchem-1140	131	22	coordinated	coordinated	ADJ
eurjchem-1140	131	23	water	water	NOUN
eurjchem-1140	131	24	molecule	molecule	NOUN
eurjchem-1140	131	25	.	.	PUNCT
eurjchem-1140	132	1	the	the	DET
eurjchem-1140	132	2	new	new	ADJ
eurjchem-1140	132	3	bands	band	NOUN
eurjchem-1140	132	4	in	in	ADP
eurjchem-1140	132	5	the	the	DET
eurjchem-1140	132	6	far‐ir	far‐ir	PROPN
eurjchem-1140	132	7	spectra	spectra	NOUN
eurjchem-1140	132	8	for	for	ADP
eurjchem-1140	132	9	all	all	DET
eurjchem-1140	132	10	metal	metal	NOUN
eurjchem-1140	132	11	complexes	complex	NOUN
eurjchem-1140	132	12	in	in	ADP
eurjchem-1140	132	13	the	the	DET
eurjchem-1140	132	14	500‐480	500‐480	PROPN
eurjchem-1140	132	15	cm‐1	cm‐1	NOUN
eurjchem-1140	132	16	,	,	PUNCT
eurjchem-1140	132	17	400‐440	400‐440	PROPN
eurjchem-1140	132	18	and	and	CCONJ
eurjchem-1140	132	19	518‐544	518‐544	PROPN
eurjchem-1140	132	20	cm‐1	cm‐1	NOUN
eurjchem-1140	132	21	regions	region	NOUN
eurjchem-1140	132	22	are	be	AUX
eurjchem-1140	132	23	assigned	assign	VERB
eurjchem-1140	132	24	to	to	ADP
eurjchem-1140	132	25	ν(m	ν(m	NOUN
eurjchem-1140	132	26	–	–	PUNCT
eurjchem-1140	132	27	n	n	CCONJ
eurjchem-1140	132	28	)	)	PUNCT
eurjchem-1140	132	29	,	,	PUNCT
eurjchem-1140	132	30	ν(m	ν(m	PROPN
eurjchem-1140	132	31	–	–	PUNCT
eurjchem-1140	132	32	o	o	NOUN
eurjchem-1140	132	33	)	)	PUNCT
eurjchem-1140	132	34	and	and	CCONJ
eurjchem-1140	132	35	ν(m‐s	ν(m‐s	NUM
eurjchem-1140	132	36	)	)	PUNCT
eurjchem-1140	132	37	bonds	bond	NOUN
eurjchem-1140	132	38	,	,	PUNCT
eurjchem-1140	132	39	respectively	respectively	ADV
eurjchem-1140	132	40	[	[	X
eurjchem-1140	132	41	20,22	20,22	NUM
eurjchem-1140	132	42	]	]	X
eurjchem-1140	132	43	.	.	PUNCT
eurjchem-1140	133	1	3.3	3.3	NUM
eurjchem-1140	133	2	.	.	PUNCT
eurjchem-1140	134	1	electronic	electronic	ADJ
eurjchem-1140	134	2	spectra	spectra	NOUN
eurjchem-1140	134	3	and	and	CCONJ
eurjchem-1140	134	4	magnetic	magnetic	ADJ
eurjchem-1140	134	5	moments	moment	NOUN
eurjchem-1140	134	6	the	the	DET
eurjchem-1140	134	7	magnetic	magnetic	ADJ
eurjchem-1140	134	8	and	and	CCONJ
eurjchem-1140	134	9	electronic	electronic	ADJ
eurjchem-1140	134	10	spectral	spectral	ADJ
eurjchem-1140	134	11	data	datum	NOUN
eurjchem-1140	134	12	is	be	AUX
eurjchem-1140	134	13	in	in	ADP
eurjchem-1140	134	14	relevance	relevance	NOUN
eurjchem-1140	134	15	with	with	ADP
eurjchem-1140	134	16	proposed	propose	VERB
eurjchem-1140	134	17	geometry	geometry	NOUN
eurjchem-1140	134	18	of	of	ADP
eurjchem-1140	134	19	complexes	complex	NOUN
eurjchem-1140	134	20	.	.	PUNCT
eurjchem-1140	135	1	the	the	DET
eurjchem-1140	135	2	free	free	ADJ
eurjchem-1140	135	3	ligand	ligand	NOUN
eurjchem-1140	135	4	solution	solution	NOUN
eurjchem-1140	135	5	displays	display	VERB
eurjchem-1140	135	6	high	high	ADJ
eurjchem-1140	135	7	intensity	intensity	NOUN
eurjchem-1140	135	8	peaks	peak	NOUN
eurjchem-1140	135	9	in	in	ADP
eurjchem-1140	135	10	the	the	DET
eurjchem-1140	135	11	uv	uv	NOUN
eurjchem-1140	135	12	regions	region	NOUN
eurjchem-1140	135	13	at	at	ADP
eurjchem-1140	135	14	290‐	290‐	NUM
eurjchem-1140	135	15	330	330	NUM
eurjchem-1140	135	16	nm	nm	NOUN
eurjchem-1140	135	17	which	which	PRON
eurjchem-1140	135	18	are	be	AUX
eurjchem-1140	135	19	assigned	assign	VERB
eurjchem-1140	135	20	to	to	PART
eurjchem-1140	135	21	ligand	ligand	VERB
eurjchem-1140	135	22	field	field	NOUN
eurjchem-1140	135	23	of	of	ADP
eurjchem-1140	135	24	c	c	NOUN
eurjchem-1140	135	25	=	=	NOUN
eurjchem-1140	135	26	n	n	NOUN
eurjchem-1140	135	27	and	and	CCONJ
eurjchem-1140	135	28	c	c	X
eurjchem-1140	135	29	=	=	NOUN
eurjchem-1140	135	30	c	c	NOUN
eurjchem-1140	135	31	chromophores	chromophore	NOUN
eurjchem-1140	135	32	[	[	X
eurjchem-1140	135	33	23	23	NUM
eurjchem-1140	135	34	]	]	PUNCT
eurjchem-1140	135	35	.	.	PUNCT
eurjchem-1140	136	1	the	the	DET
eurjchem-1140	136	2	electronic	electronic	ADJ
eurjchem-1140	136	3	transitions	transition	NOUN
eurjchem-1140	136	4	from	from	ADP
eurjchem-1140	136	5	the	the	DET
eurjchem-1140	136	6	6a1	6a1	NUM
eurjchem-1140	136	7	ground	ground	NOUN
eurjchem-1140	136	8	term	term	NOUN
eurjchem-1140	136	9	of	of	ADP
eurjchem-1140	136	10	mn(ii	mn(ii	NOUN
eurjchem-1140	136	11	)	)	PUNCT
eurjchem-1140	136	12	to	to	ADP
eurjchem-1140	136	13	higher	high	ADJ
eurjchem-1140	136	14	energy	energy	NOUN
eurjchem-1140	136	15	terms	term	NOUN
eurjchem-1140	136	16	are	be	AUX
eurjchem-1140	136	17	spin‐	spin‐	NOUN
eurjchem-1140	136	18	forbidden	forbid	VERB
eurjchem-1140	136	19	.	.	PUNCT
eurjchem-1140	137	1	however	however	ADV
eurjchem-1140	137	2	,	,	PUNCT
eurjchem-1140	137	3	the	the	DET
eurjchem-1140	137	4	band	band	NOUN
eurjchem-1140	137	5	appearing	appear	VERB
eurjchem-1140	137	6	in	in	ADP
eurjchem-1140	137	7	the	the	DET
eurjchem-1140	137	8	region	region	NOUN
eurjchem-1140	137	9	570‐340	570‐340	NUM
eurjchem-1140	137	10	nm	nm	NOUN
eurjchem-1140	137	11	in	in	ADP
eurjchem-1140	137	12	the	the	DET
eurjchem-1140	137	13	electronic	electronic	ADJ
eurjchem-1140	137	14	spectrum	spectrum	NOUN
eurjchem-1140	137	15	of	of	ADP
eurjchem-1140	137	16	mn(ii	mn(ii	PROPN
eurjchem-1140	137	17	)	)	PUNCT
eurjchem-1140	137	18	complex	complex	NOUN
eurjchem-1140	137	19	is	be	AUX
eurjchem-1140	137	20	assigned	assign	VERB
eurjchem-1140	137	21	to	to	ADP
eurjchem-1140	137	22	6a1	6a1	NUM
eurjchem-1140	137	23	→	→	SYM
eurjchem-1140	137	24	4t1(g	4t1(g	NUM
eurjchem-1140	137	25	)	)	PUNCT
eurjchem-1140	137	26	and	and	CCONJ
eurjchem-1140	137	27	is	be	AUX
eurjchem-1140	137	28	consistent	consistent	ADJ
eurjchem-1140	137	29	with	with	ADP
eurjchem-1140	137	30	tetrahedral	tetrahedral	ADJ
eurjchem-1140	137	31	geometry	geometry	NOUN
eurjchem-1140	137	32	.	.	PUNCT
eurjchem-1140	138	1	for	for	ADP
eurjchem-1140	138	2	the	the	DET
eurjchem-1140	138	3	cobalt(ii	cobalt(ii	ADJ
eurjchem-1140	138	4	)	)	PUNCT
eurjchem-1140	138	5	complex	complex	NOUN
eurjchem-1140	138	6	,	,	PUNCT
eurjchem-1140	138	7	the	the	DET
eurjchem-1140	138	8	band	band	NOUN
eurjchem-1140	138	9	at	at	ADP
eurjchem-1140	138	10	670	670	NUM
eurjchem-1140	138	11	and	and	CCONJ
eurjchem-1140	138	12	550	550	NUM
eurjchem-1140	138	13	nm	nm	NOUN
eurjchem-1140	138	14	are	be	AUX
eurjchem-1140	138	15	assigned	assign	VERB
eurjchem-1140	138	16	to	to	ADP
eurjchem-1140	138	17	the	the	DET
eurjchem-1140	138	18	4a2	4a2	NUM
eurjchem-1140	138	19	→	→	SYM
eurjchem-1140	138	20	4t1(p	4t1(p	NUM
eurjchem-1140	138	21	)	)	PUNCT
eurjchem-1140	138	22	and	and	CCONJ
eurjchem-1140	138	23	4a2	4a2	NUM
eurjchem-1140	138	24	→	→	SYM
eurjchem-1140	138	25	4t1(f	4t1(f	NUM
eurjchem-1140	138	26	)	)	PUNCT
eurjchem-1140	138	27	,	,	PUNCT
eurjchem-1140	138	28	respectively	respectively	ADV
eurjchem-1140	138	29	,	,	PUNCT
eurjchem-1140	138	30	which	which	PRON
eurjchem-1140	138	31	is	be	AUX
eurjchem-1140	138	32	typical	typical	ADJ
eurjchem-1140	138	33	for	for	ADP
eurjchem-1140	138	34	tetrahedral	tetrahedral	ADJ
eurjchem-1140	138	35	co(ii	co(ii	ADJ
eurjchem-1140	138	36	)	)	PUNCT
eurjchem-1140	138	37	complexes	complex	NOUN
eurjchem-1140	138	38	.	.	PUNCT
eurjchem-1140	139	1	the	the	DET
eurjchem-1140	139	2	bands	band	NOUN
eurjchem-1140	139	3	at	at	ADP
eurjchem-1140	139	4	735‐650	735‐650	PROPN
eurjchem-1140	139	5	nm	nm	NOUN
eurjchem-1140	139	6	in	in	ADP
eurjchem-1140	139	7	the	the	DET
eurjchem-1140	139	8	ni(ii	ni(ii	PROPN
eurjchem-1140	139	9	)	)	PUNCT
eurjchem-1140	139	10	complex	complex	NOUN
eurjchem-1140	139	11	are	be	AUX
eurjchem-1140	139	12	assigned	assign	VERB
eurjchem-1140	139	13	to	to	ADP
eurjchem-1140	139	14	the	the	DET
eurjchem-1140	139	15	forbidden	forbidden	ADJ
eurjchem-1140	139	16	transition	transition	NOUN
eurjchem-1140	139	17	3t1(f	3t1(f	NUM
eurjchem-1140	139	18	)	)	PUNCT
eurjchem-1140	139	19	→	→	SYM
eurjchem-1140	139	20	3t1(p	3t1(p	NUM
eurjchem-1140	139	21	)	)	PUNCT
eurjchem-1140	139	22	,	,	PUNCT
eurjchem-1140	139	23	due	due	ADP
eurjchem-1140	139	24	to	to	ADP
eurjchem-1140	139	25	the	the	DET
eurjchem-1140	139	26	tetrahedral	tetrahedral	ADJ
eurjchem-1140	139	27	structure	structure	NOUN
eurjchem-1140	139	28	around	around	ADP
eurjchem-1140	139	29	ni(ii	ni(ii	NOUN
eurjchem-1140	139	30	)	)	PUNCT
eurjchem-1140	139	31	.	.	PUNCT
eurjchem-1140	140	1	due	due	ADP
eurjchem-1140	140	2	to	to	ADP
eurjchem-1140	140	3	the	the	DET
eurjchem-1140	140	4	distorted	distorted	ADJ
eurjchem-1140	140	5	tetrahedral	tetrahedral	ADJ
eurjchem-1140	140	6	configuration	configuration	NOUN
eurjchem-1140	140	7	,	,	PUNCT
eurjchem-1140	140	8	the	the	DET
eurjchem-1140	140	9	copper(ii	copper(ii	NOUN
eurjchem-1140	140	10	)	)	PUNCT
eurjchem-1140	140	11	complex	complex	NOUN
eurjchem-1140	140	12	shows	show	VERB
eurjchem-1140	140	13	a	a	DET
eurjchem-1140	140	14	broad	broad	ADJ
eurjchem-1140	140	15	band	band	NOUN
eurjchem-1140	140	16	at	at	ADP
eurjchem-1140	140	17	690	690	NUM
eurjchem-1140	140	18	nm	nm	NOUN
eurjchem-1140	140	19	for	for	ADP
eurjchem-1140	140	20	2t2	2t2	NUM
eurjchem-1140	140	21	→	→	SYM
eurjchem-1140	140	22	2e	2e	NUM
eurjchem-1140	140	23	transition	transition	NOUN
eurjchem-1140	140	24	[	[	X
eurjchem-1140	140	25	24	24	NUM
eurjchem-1140	140	26	]	]	PUNCT
eurjchem-1140	140	27	.	.	PUNCT
eurjchem-1140	141	1	the	the	DET
eurjchem-1140	141	2	low	low	ADJ
eurjchem-1140	141	3	energy	energy	NOUN
eurjchem-1140	141	4	bands	band	NOUN
eurjchem-1140	141	5	in	in	ADP
eurjchem-1140	141	6	the	the	DET
eurjchem-1140	141	7	visible	visible	ADJ
eurjchem-1140	141	8	region	region	NOUN
eurjchem-1140	141	9	for	for	ADP
eurjchem-1140	141	10	all	all	DET
eurjchem-1140	141	11	complexes	complex	NOUN
eurjchem-1140	141	12	solutions	solution	NOUN
eurjchem-1140	141	13	confirms	confirm	VERB
eurjchem-1140	141	14	the	the	DET
eurjchem-1140	141	15	tetrahedral	tetrahedral	ADJ
eurjchem-1140	141	16	geometry	geometry	NOUN
eurjchem-1140	141	17	of	of	ADP
eurjchem-1140	141	18	metal(ii	metal(ii	PROPN
eurjchem-1140	141	19	)	)	PUNCT
eurjchem-1140	141	20	complexes	complex	NOUN
eurjchem-1140	141	21	[	[	X
eurjchem-1140	141	22	18,24	18,24	NUM
eurjchem-1140	141	23	]	]	X
eurjchem-1140	141	24	,	,	PUNCT
eurjchem-1140	141	25	respectively	respectively	ADV
eurjchem-1140	141	26	.	.	PUNCT
eurjchem-1140	142	1	the	the	DET
eurjchem-1140	142	2	room	room	NOUN
eurjchem-1140	142	3	temperature	temperature	NOUN
eurjchem-1140	142	4	magnetic	magnetic	ADJ
eurjchem-1140	142	5	moment	moment	NOUN
eurjchem-1140	142	6	values	value	NOUN
eurjchem-1140	142	7	of	of	ADP
eurjchem-1140	142	8	nickel	nickel	NOUN
eurjchem-1140	142	9	and	and	CCONJ
eurjchem-1140	142	10	cobalt	cobalt	NOUN
eurjchem-1140	142	11	complexes	complex	NOUN
eurjchem-1140	142	12	were	be	AUX
eurjchem-1140	142	13	found	find	VERB
eurjchem-1140	142	14	to	to	PART
eurjchem-1140	142	15	be	be	AUX
eurjchem-1140	142	16	2.84	2.84	NUM
eurjchem-1140	142	17	and	and	CCONJ
eurjchem-1140	142	18	4.22	4.22	NUM
eurjchem-1140	142	19	bm	bm	PROPN
eurjchem-1140	142	20	for	for	ADP
eurjchem-1140	142	21	[	[	NOUN
eurjchem-1140	142	22	nilcl	nilcl	NOUN
eurjchem-1140	142	23	]	]	X
eurjchem-1140	142	24	and	and	CCONJ
eurjchem-1140	142	25	[	[	X
eurjchem-1140	142	26	colcl	colcl	NOUN
eurjchem-1140	142	27	]	]	X
eurjchem-1140	142	28	,	,	PUNCT
eurjchem-1140	142	29	respectively	respectively	ADV
eurjchem-1140	142	30	,	,	PUNCT
eurjchem-1140	142	31	suggesting	suggest	VERB
eurjchem-1140	142	32	the	the	DET
eurjchem-1140	142	33	four	four	NUM
eurjchem-1140	142	34	coordinated	coordinated	ADJ
eurjchem-1140	142	35	,	,	PUNCT
eurjchem-1140	142	36	tetrahedral	tetrahedral	ADJ
eurjchem-1140	142	37	geometry	geometry	NOUN
eurjchem-1140	142	38	[	[	X
eurjchem-1140	142	39	25	25	NUM
eurjchem-1140	142	40	]	]	PUNCT
eurjchem-1140	142	41	.	.	PUNCT
eurjchem-1140	143	1	whereas	whereas	SCONJ
eurjchem-1140	143	2	copper	copper	NOUN
eurjchem-1140	143	3	complex	complex	NOUN
eurjchem-1140	143	4	[	[	X
eurjchem-1140	143	5	culcl	culcl	NOUN
eurjchem-1140	143	6	]	]	PUNCT
eurjchem-1140	143	7	exhibit	exhibit	VERB
eurjchem-1140	143	8	the	the	DET
eurjchem-1140	143	9	magnetic	magnetic	ADJ
eurjchem-1140	143	10	moment	moment	NOUN
eurjchem-1140	143	11	value	value	NOUN
eurjchem-1140	143	12	1.56	1.56	NUM
eurjchem-1140	143	13	bm	bm	PROPN
eurjchem-1140	143	14	.	.	PUNCT
eurjchem-1140	144	1	fairly	fairly	ADV
eurjchem-1140	144	2	lower	low	ADJ
eurjchem-1140	144	3	magnetic	magnetic	ADJ
eurjchem-1140	144	4	moment	moment	NOUN
eurjchem-1140	144	5	value	value	NOUN
eurjchem-1140	144	6	of	of	ADP
eurjchem-1140	144	7	copper	copper	NOUN
eurjchem-1140	144	8	complex	complex	NOUN
eurjchem-1140	144	9	is	be	AUX
eurjchem-1140	144	10	attributed	attribute	VERB
eurjchem-1140	144	11	to	to	ADP
eurjchem-1140	144	12	the	the	DET
eurjchem-1140	144	13	higher	high	ADJ
eurjchem-1140	144	14	covalence	covalence	NOUN
eurjchem-1140	144	15	of	of	ADP
eurjchem-1140	144	16	s	s	NOUN
eurjchem-1140	144	17	–	–	PUNCT
eurjchem-1140	144	18	cu	cu	NOUN
eurjchem-1140	144	19	bond	bond	NOUN
eurjchem-1140	144	20	and	and	CCONJ
eurjchem-1140	144	21	lower	low	ADJ
eurjchem-1140	144	22	orbital	orbital	ADJ
eurjchem-1140	144	23	contribution	contribution	NOUN
eurjchem-1140	144	24	of	of	ADP
eurjchem-1140	144	25	sulphur	sulphur	NOUN
eurjchem-1140	144	26	[	[	X
eurjchem-1140	144	27	25,26	25,26	NUM
eurjchem-1140	144	28	]	]	X
eurjchem-1140	144	29	.	.	PUNCT
eurjchem-1140	145	1	3.4	3.4	NUM
eurjchem-1140	145	2	.	.	PUNCT
eurjchem-1140	145	3	1h	1h	NUM
eurjchem-1140	145	4	and	and	CCONJ
eurjchem-1140	145	5	13	13	NUM
eurjchem-1140	145	6	c	c	PROPN
eurjchem-1140	145	7	nmr	nmr	NOUN
eurjchem-1140	145	8	study	study	VERB
eurjchem-1140	145	9	the	the	DET
eurjchem-1140	145	10	1	1	NUM
eurjchem-1140	145	11	h	h	NOUN
eurjchem-1140	145	12	nmr	nmr	NOUN
eurjchem-1140	145	13	spectra	spectra	ADJ
eurjchem-1140	145	14	study	study	NOUN
eurjchem-1140	145	15	of	of	ADP
eurjchem-1140	145	16	the	the	DET
eurjchem-1140	145	17	free	free	ADJ
eurjchem-1140	145	18	schiff	schiff	PROPN
eurjchem-1140	145	19	base	base	NOUN
eurjchem-1140	145	20	hl	hl	NOUN
eurjchem-1140	145	21	is	be	AUX
eurjchem-1140	145	22	recorded	record	VERB
eurjchem-1140	145	23	in	in	ADP
eurjchem-1140	145	24	dmso‐d6	dmso‐d6	NOUN
eurjchem-1140	145	25	solution	solution	NOUN
eurjchem-1140	145	26	using	use	VERB
eurjchem-1140	145	27	tetramethylsilane	tetramethylsilane	NOUN
eurjchem-1140	145	28	as	as	ADP
eurjchem-1140	145	29	internal	internal	ADJ
eurjchem-1140	145	30	standard	standard	NOUN
eurjchem-1140	145	31	.	.	PUNCT
eurjchem-1140	146	1	the	the	DET
eurjchem-1140	146	2	chemical	chemical	ADJ
eurjchem-1140	146	3	shifts	shift	NOUN
eurjchem-1140	146	4	of	of	ADP
eurjchem-1140	146	5	the	the	DET
eurjchem-1140	146	6	different	different	ADJ
eurjchem-1140	146	7	types	type	NOUN
eurjchem-1140	146	8	of	of	ADP
eurjchem-1140	146	9	protons	proton	NOUN
eurjchem-1140	146	10	found	find	VERB
eurjchem-1140	146	11	in	in	ADP
eurjchem-1140	146	12	the	the	DET
eurjchem-1140	146	13	1h	1h	NUM
eurjchem-1140	146	14	and	and	CCONJ
eurjchem-1140	146	15	13	13	NUM
eurjchem-1140	146	16	c	c	PROPN
eurjchem-1140	146	17	nmr	nmr	NOUN
eurjchem-1140	146	18	spectra	spectra	NOUN
eurjchem-1140	146	19	of	of	ADP
eurjchem-1140	146	20	dmq	dmq	PROPN
eurjchem-1140	146	21	and	and	CCONJ
eurjchem-1140	146	22	lh	lh	PROPN
eurjchem-1140	146	23	compounds	compound	NOUN
eurjchem-1140	146	24	are	be	AUX
eurjchem-1140	146	25	listed	list	VERB
eurjchem-1140	146	26	in	in	ADP
eurjchem-1140	146	27	the	the	DET
eurjchem-1140	146	28	experimental	experimental	ADJ
eurjchem-1140	146	29	section	section	NOUN
eurjchem-1140	146	30	.	.	PUNCT
eurjchem-1140	147	1	the	the	DET
eurjchem-1140	147	2	1h	1h	NUM
eurjchem-1140	147	3	nmr	nmr	NOUN
eurjchem-1140	147	4	spectrum	spectrum	NOUN
eurjchem-1140	147	5	of	of	ADP
eurjchem-1140	147	6	dmq	dmq	PROPN
eurjchem-1140	147	7	compound	compound	NOUN
eurjchem-1140	147	8	exhibits	exhibit	VERB
eurjchem-1140	147	9	absorption	absorption	NOUN
eurjchem-1140	147	10	at	at	ADP
eurjchem-1140	147	11	3.09	3.09	NUM
eurjchem-1140	147	12	ppm	ppm	NOUN
eurjchem-1140	147	13	that	that	PRON
eurjchem-1140	147	14	belongs	belong	VERB
eurjchem-1140	147	15	to	to	ADP
eurjchem-1140	147	16	resonance	resonance	NOUN
eurjchem-1140	147	17	of	of	ADP
eurjchem-1140	147	18	6h	6h	NUM
eurjchem-1140	147	19	of	of	ADP
eurjchem-1140	147	20	–	–	PUNCT
eurjchem-1140	147	21	ch3	ch3	NOUN
eurjchem-1140	147	22	groups	group	NOUN
eurjchem-1140	147	23	linked	link	VERB
eurjchem-1140	147	24	to	to	ADP
eurjchem-1140	147	25	phenyl	phenyl	NOUN
eurjchem-1140	147	26	moiety	moiety	NOUN
eurjchem-1140	147	27	at	at	ADP
eurjchem-1140	147	28	6	6	NUM
eurjchem-1140	147	29	and	and	CCONJ
eurjchem-1140	147	30	7	7	NUM
eurjchem-1140	147	31	positions	position	NOUN
eurjchem-1140	147	32	[	[	X
eurjchem-1140	147	33	15,27	15,27	NUM
eurjchem-1140	147	34	]	]	PUNCT
eurjchem-1140	147	35	.	.	PUNCT
eurjchem-1140	148	1	as	as	ADV
eurjchem-1140	148	2	well	well	ADV
eurjchem-1140	148	3	as	as	ADP
eurjchem-1140	148	4	the	the	DET
eurjchem-1140	148	5	al‐jibouri	al‐jibouri	NOUN
eurjchem-1140	148	6	and	and	CCONJ
eurjchem-1140	148	7	hasun	hasun	PROPN
eurjchem-1140	148	8	/	/	SYM
eurjchem-1140	148	9	european	european	PROPN
eurjchem-1140	148	10	journal	journal	PROPN
eurjchem-1140	148	11	of	of	ADP
eurjchem-1140	148	12	chemistry	chemistry	NOUN
eurjchem-1140	148	13	6	6	NUM
eurjchem-1140	148	14	(	(	PUNCT
eurjchem-1140	148	15	1	1	NUM
eurjchem-1140	148	16	)	)	PUNCT
eurjchem-1140	148	17	(	(	PUNCT
eurjchem-1140	148	18	2015	2015	NUM
eurjchem-1140	148	19	)	)	PUNCT
eurjchem-1140	148	20	44‐47	44‐47	NOUN
eurjchem-1140	148	21	47	47	NUM
eurjchem-1140	148	22	peaks	peak	NOUN
eurjchem-1140	148	23	at	at	ADP
eurjchem-1140	148	24	7.66‐8.05	7.66‐8.05	NUM
eurjchem-1140	148	25	ppm	ppm	NOUN
eurjchem-1140	148	26	may	may	AUX
eurjchem-1140	148	27	be	be	AUX
eurjchem-1140	148	28	assigned	assign	VERB
eurjchem-1140	148	29	to	to	ADP
eurjchem-1140	148	30	aromatic	aromatic	ADJ
eurjchem-1140	148	31	ar‐h	ar‐h	NOUN
eurjchem-1140	148	32	and	and	CCONJ
eurjchem-1140	148	33	amide	amide	VERB
eurjchem-1140	148	34	nh‐co	nh‐co	PRON
eurjchem-1140	148	35	,	,	PUNCT
eurjchem-1140	148	36	respectively	respectively	ADV
eurjchem-1140	148	37	[	[	X
eurjchem-1140	148	38	27	27	NUM
eurjchem-1140	148	39	]	]	PUNCT
eurjchem-1140	148	40	.	.	PUNCT
eurjchem-1140	149	1	the	the	DET
eurjchem-1140	149	2	1h	1h	NUM
eurjchem-1140	149	3	nmr	nmr	NOUN
eurjchem-1140	149	4	spectrum	spectrum	NOUN
eurjchem-1140	149	5	of	of	ADP
eurjchem-1140	149	6	lh	lh	PROPN
eurjchem-1140	149	7	schiff	schiff	PROPN
eurjchem-1140	149	8	base	base	PROPN
eurjchem-1140	149	9	shows	show	NOUN
eurjchem-1140	149	10	signal	signal	VERB
eurjchem-1140	149	11	observed	observe	VERB
eurjchem-1140	149	12	at	at	ADP
eurjchem-1140	149	13	8.61	8.61	NUM
eurjchem-1140	149	14	ppm	ppm	NOUN
eurjchem-1140	149	15	that	that	PRON
eurjchem-1140	149	16	is	be	AUX
eurjchem-1140	149	17	assigned	assign	VERB
eurjchem-1140	149	18	to	to	ADP
eurjchem-1140	149	19	2h	2h	NUM
eurjchem-1140	149	20	of	of	ADP
eurjchem-1140	149	21	h2n‐c	h2n‐c	NOUN
eurjchem-1140	149	22	=	=	SYM
eurjchem-1140	149	23	s	s	NOUN
eurjchem-1140	149	24	moiety	moiety	NOUN
eurjchem-1140	150	1	[	[	X
eurjchem-1140	150	2	14,15,27	14,15,27	NUM
eurjchem-1140	150	3	]	]	PUNCT
eurjchem-1140	150	4	.	.	PUNCT
eurjchem-1140	151	1	the	the	DET
eurjchem-1140	151	2	resonance	resonance	NOUN
eurjchem-1140	151	3	of	of	ADP
eurjchem-1140	151	4	–	–	PUNCT
eurjchem-1140	151	5	nh	nh	NOUN
eurjchem-1140	151	6	protons	proton	NOUN
eurjchem-1140	151	7	of	of	ADP
eurjchem-1140	151	8	pyrazine	pyrazine	NOUN
eurjchem-1140	151	9	ring	ring	NOUN
eurjchem-1140	151	10	are	be	AUX
eurjchem-1140	151	11	showed	show	VERB
eurjchem-1140	151	12	at	at	ADP
eurjchem-1140	151	13	7.89	7.89	NUM
eurjchem-1140	151	14	and	and	CCONJ
eurjchem-1140	151	15	8.01	8.01	NUM
eurjchem-1140	151	16	ppm	ppm	NOUN
eurjchem-1140	151	17	,	,	PUNCT
eurjchem-1140	151	18	respectively	respectively	ADV
eurjchem-1140	151	19	[	[	X
eurjchem-1140	151	20	13,14	13,14	NUM
eurjchem-1140	151	21	]	]	PUNCT
eurjchem-1140	151	22	.	.	PUNCT
eurjchem-1140	152	1	the	the	DET
eurjchem-1140	152	2	peaks	peak	NOUN
eurjchem-1140	152	3	that	that	PRON
eurjchem-1140	152	4	are	be	AUX
eurjchem-1140	152	5	showed	show	VERB
eurjchem-1140	152	6	in	in	ADP
eurjchem-1140	152	7	6.21	6.21	NUM
eurjchem-1140	152	8	,	,	PUNCT
eurjchem-1140	152	9	6.78	6.78	NUM
eurjchem-1140	152	10	and	and	CCONJ
eurjchem-1140	152	11	7.89	7.89	NUM
eurjchem-1140	152	12	ppm	ppm	NOUN
eurjchem-1140	152	13	could	could	AUX
eurjchem-1140	152	14	be	be	AUX
eurjchem-1140	152	15	attributed	attribute	VERB
eurjchem-1140	152	16	to	to	ADP
eurjchem-1140	152	17	aromatic	aromatic	ADJ
eurjchem-1140	152	18	ar‐h	ar‐h	PROPN
eurjchem-1140	152	19	and	and	CCONJ
eurjchem-1140	152	20	–	–	PUNCT
eurjchem-1140	152	21	c	c	X
eurjchem-1140	152	22	=	=	SYM
eurjchem-1140	152	23	n‐	n‐	NOUN
eurjchem-1140	152	24	nh‐	nh‐	NUM
eurjchem-1140	152	25	protons	proton	NOUN
eurjchem-1140	152	26	,	,	PUNCT
eurjchem-1140	152	27	respectively	respectively	ADV
eurjchem-1140	152	28	[	[	X
eurjchem-1140	152	29	15	15	NUM
eurjchem-1140	152	30	]	]	PUNCT
eurjchem-1140	152	31	.	.	PUNCT
eurjchem-1140	153	1	however	however	ADV
eurjchem-1140	153	2	,	,	PUNCT
eurjchem-1140	153	3	the	the	DET
eurjchem-1140	153	4	shielded	shielded	ADJ
eurjchem-1140	153	5	protons	proton	NOUN
eurjchem-1140	153	6	of	of	ADP
eurjchem-1140	153	7	–	–	PUNCT
eurjchem-1140	153	8	ch3	ch3	NOUN
eurjchem-1140	153	9	groups	group	NOUN
eurjchem-1140	153	10	are	be	AUX
eurjchem-1140	153	11	recorded	record	VERB
eurjchem-1140	153	12	at	at	ADP
eurjchem-1140	153	13	3.40	3.40	NUM
eurjchem-1140	153	14	ppm	ppm	NOUN
eurjchem-1140	153	15	as	as	ADP
eurjchem-1140	153	16	singlet	singlet	ADJ
eurjchem-1140	153	17	peak	peak	NOUN
eurjchem-1140	153	18	.	.	PUNCT
eurjchem-1140	154	1	in	in	ADP
eurjchem-1140	154	2	addition	addition	NOUN
eurjchem-1140	154	3	,	,	PUNCT
eurjchem-1140	154	4	13	13	NUM
eurjchem-1140	154	5	c	c	PROPN
eurjchem-1140	154	6	nmr	nmr	NOUN
eurjchem-1140	154	7	spectra	spectra	ADJ
eurjchem-1140	154	8	data	datum	NOUN
eurjchem-1140	154	9	of	of	ADP
eurjchem-1140	154	10	lh	lh	PROPN
eurjchem-1140	154	11	also	also	ADV
eurjchem-1140	154	12	entirely	entirely	ADV
eurjchem-1140	154	13	agree	agree	VERB
eurjchem-1140	154	14	with	with	ADP
eurjchem-1140	154	15	the	the	DET
eurjchem-1140	154	16	data	datum	NOUN
eurjchem-1140	154	17	of	of	ADP
eurjchem-1140	154	18	1h	1h	NUM
eurjchem-1140	154	19	nmr	nmr	NOUN
eurjchem-1140	154	20	spectra	spectra	NOUN
eurjchem-1140	155	1	[	[	X
eurjchem-1140	155	2	27‐29	27‐29	NUM
eurjchem-1140	155	3	]	]	PUNCT
eurjchem-1140	155	4	.	.	PUNCT
eurjchem-1140	156	1	4	4	X
eurjchem-1140	156	2	.	.	X
eurjchem-1140	156	3	conclusions	conclusion	NOUN
eurjchem-1140	156	4	the	the	DET
eurjchem-1140	156	5	mn(ii	mn(ii	PROPN
eurjchem-1140	156	6	)	)	PUNCT
eurjchem-1140	156	7	,	,	PUNCT
eurjchem-1140	156	8	co(ii	co(ii	PROPN
eurjchem-1140	156	9	)	)	PUNCT
eurjchem-1140	156	10	,	,	PUNCT
eurjchem-1140	156	11	ni(ii	ni(ii	PROPN
eurjchem-1140	156	12	)	)	PUNCT
eurjchem-1140	156	13	,	,	PUNCT
eurjchem-1140	156	14	co(ii	co(ii	PROPN
eurjchem-1140	156	15	)	)	PUNCT
eurjchem-1140	156	16	and	and	CCONJ
eurjchem-1140	156	17	zn(ii	zn(ii	NOUN
eurjchem-1140	156	18	)	)	PUNCT
eurjchem-1140	156	19	complexes	complex	NOUN
eurjchem-1140	156	20	with	with	ADP
eurjchem-1140	156	21	tridentate	tridentate	ADJ
eurjchem-1140	156	22	monobasic	monobasic	PROPN
eurjchem-1140	156	23	lh	lh	PROPN
eurjchem-1140	156	24	ligand	ligand	PROPN
eurjchem-1140	156	25	synthesized	synthesize	VERB
eurjchem-1140	156	26	in	in	ADP
eurjchem-1140	156	27	this	this	DET
eurjchem-1140	156	28	study	study	NOUN
eurjchem-1140	156	29	have	have	VERB
eurjchem-1140	156	30	a	a	DET
eurjchem-1140	156	31	monomer	monomer	NOUN
eurjchem-1140	156	32	structure	structure	NOUN
eurjchem-1140	156	33	as	as	SCONJ
eurjchem-1140	156	34	suggested	suggest	VERB
eurjchem-1140	156	35	by	by	ADP
eurjchem-1140	156	36	elemental	elemental	ADJ
eurjchem-1140	156	37	analysis	analysis	NOUN
eurjchem-1140	156	38	,	,	PUNCT
eurjchem-1140	156	39	nmr	nmr	NOUN
eurjchem-1140	156	40	,	,	PUNCT
eurjchem-1140	156	41	ft‐ir	ft‐ir	NOUN
eurjchem-1140	156	42	,	,	PUNCT
eurjchem-1140	156	43	uv‐visible	uv‐visible	ADJ
eurjchem-1140	156	44	spectra	spectra	NOUN
eurjchem-1140	156	45	and	and	CCONJ
eurjchem-1140	156	46	magnetic	magnetic	ADJ
eurjchem-1140	156	47	moments	moment	NOUN
eurjchem-1140	156	48	data	datum	NOUN
eurjchem-1140	156	49	.	.	PUNCT
eurjchem-1140	157	1	the	the	DET
eurjchem-1140	157	2	values	value	NOUN
eurjchem-1140	157	3	of	of	ADP
eurjchem-1140	157	4	infrared	infrared	ADJ
eurjchem-1140	157	5	stretching	stretching	NOUN
eurjchem-1140	157	6	frequencies	frequency	NOUN
eurjchem-1140	157	7	corresponding	correspond	VERB
eurjchem-1140	157	8	to	to	ADP
eurjchem-1140	157	9	the	the	DET
eurjchem-1140	157	10	c	c	NOUN
eurjchem-1140	157	11	=	=	NOUN
eurjchem-1140	157	12	s	s	NOUN
eurjchem-1140	157	13	and	and	CCONJ
eurjchem-1140	157	14	m‐cl	m‐cl	NOUN
eurjchem-1140	157	15	bands	band	NOUN
eurjchem-1140	157	16	are	be	AUX
eurjchem-1140	157	17	in	in	ADP
eurjchem-1140	157	18	good	good	ADJ
eurjchem-1140	157	19	agreement	agreement	NOUN
eurjchem-1140	157	20	with	with	ADP
eurjchem-1140	157	21	four‐	four‐	NOUN
eurjchem-1140	157	22	coordinated	coordinate	VERB
eurjchem-1140	157	23	metal(ii	metal(ii	PROPN
eurjchem-1140	157	24	)	)	PUNCT
eurjchem-1140	157	25	complexes	complex	NOUN
eurjchem-1140	157	26	and	and	CCONJ
eurjchem-1140	157	27	the	the	DET
eurjchem-1140	157	28	electronic	electronic	ADJ
eurjchem-1140	157	29	spectra	spectra	NOUN
eurjchem-1140	157	30	of	of	ADP
eurjchem-1140	157	31	these	these	DET
eurjchem-1140	157	32	complexes	complex	NOUN
eurjchem-1140	157	33	also	also	ADV
eurjchem-1140	157	34	exhibit	exhibit	VERB
eurjchem-1140	157	35	spectral	spectral	ADJ
eurjchem-1140	157	36	bands	band	NOUN
eurjchem-1140	157	37	corresponding	correspond	VERB
eurjchem-1140	157	38	to	to	ADP
eurjchem-1140	157	39	the	the	DET
eurjchem-1140	157	40	electronic	electronic	ADJ
eurjchem-1140	157	41	transitions	transition	NOUN
eurjchem-1140	157	42	characteristic	characteristic	ADJ
eurjchem-1140	157	43	of	of	ADP
eurjchem-1140	157	44	tetrahedral	tetrahedral	ADJ
eurjchem-1140	157	45	complex	complex	NOUN
eurjchem-1140	157	46	.	.	PUNCT
eurjchem-1140	158	1	the	the	DET
eurjchem-1140	158	2	four	four	NUM
eurjchem-1140	158	3	coordinated	coordinate	VERB
eurjchem-1140	158	4	metal	metal	NOUN
eurjchem-1140	158	5	complexes	complex	NOUN
eurjchem-1140	158	6	with	with	ADP
eurjchem-1140	158	7	the	the	DET
eurjchem-1140	158	8	novel	novel	ADJ
eurjchem-1140	158	9	schiff	schiff	NOUN
eurjchem-1140	158	10	base	base	NOUN
eurjchem-1140	158	11	lh	lh	PROPN
eurjchem-1140	158	12	is	be	AUX
eurjchem-1140	158	13	again	again	ADV
eurjchem-1140	158	14	confirmed	confirm	VERB
eurjchem-1140	158	15	by	by	ADP
eurjchem-1140	158	16	the	the	DET
eurjchem-1140	158	17	molar	molar	ADJ
eurjchem-1140	158	18	conductance	conductance	NOUN
eurjchem-1140	158	19	measurements	measurement	NOUN
eurjchem-1140	158	20	that	that	PRON
eurjchem-1140	158	21	assigned	assign	VERB
eurjchem-1140	158	22	the	the	DET
eurjchem-1140	158	23	non‐electrolytes	non‐electrolyte	NOUN
eurjchem-1140	158	24	species	specie	NOUN
eurjchem-1140	158	25	with	with	ADP
eurjchem-1140	158	26	[	[	X
eurjchem-1140	158	27	mlcl	mlcl	NOUN
eurjchem-1140	158	28	]	]	X
eurjchem-1140	158	29	formula	formula	NOUN
eurjchem-1140	158	30	.	.	PUNCT
eurjchem-1140	159	1	according	accord	VERB
eurjchem-1140	159	2	to	to	ADP
eurjchem-1140	159	3	the	the	DET
eurjchem-1140	159	4	obtained	obtain	VERB
eurjchem-1140	159	5	results	result	NOUN
eurjchem-1140	159	6	from	from	ADP
eurjchem-1140	159	7	molar	molar	ADJ
eurjchem-1140	159	8	conductance	conductance	NOUN
eurjchem-1140	159	9	,	,	PUNCT
eurjchem-1140	159	10	magnetic	magnetic	ADJ
eurjchem-1140	159	11	susceptibility	susceptibility	NOUN
eurjchem-1140	159	12	and	and	CCONJ
eurjchem-1140	159	13	spectra	spectra	ADJ
eurjchem-1140	159	14	data	datum	NOUN
eurjchem-1140	159	15	,	,	PUNCT
eurjchem-1140	159	16	the	the	DET
eurjchem-1140	159	17	tetrahedral	tetrahedral	ADJ
eurjchem-1140	159	18	geometry	geometry	NOUN
eurjchem-1140	159	19	of	of	ADP
eurjchem-1140	159	20	the	the	DET
eurjchem-1140	159	21	prepared	prepared	ADJ
eurjchem-1140	159	22	complexes	complex	NOUN
eurjchem-1140	159	23	was	be	AUX
eurjchem-1140	159	24	shown	show	VERB
eurjchem-1140	159	25	in	in	ADP
eurjchem-1140	159	26	scheme	scheme	NOUN
eurjchem-1140	159	27	3	3	NUM
eurjchem-1140	159	28	.	.	PUNCT
eurjchem-1140	159	29	scheme	scheme	NOUN
eurjchem-1140	159	30	3	3	NUM
eurjchem-1140	159	31	acknowledgements	acknowledgement	NOUN
eurjchem-1140	159	32	the	the	DET
eurjchem-1140	159	33	authors	author	NOUN
eurjchem-1140	159	34	thank	thank	VERB
eurjchem-1140	159	35	department	department	PROPN
eurjchem-1140	159	36	of	of	ADP
eurjchem-1140	159	37	chemistry	chemistry	NOUN
eurjchem-1140	159	38	,	,	PUNCT
eurjchem-1140	159	39	college	college	NOUN
eurjchem-1140	159	40	of	of	ADP
eurjchem-1140	159	41	science	science	NOUN
eurjchem-1140	159	42	,	,	PUNCT
eurjchem-1140	159	43	al‐mustansiriya	al‐mustansiriya	PROPN
eurjchem-1140	159	44	university	university	PROPN
eurjchem-1140	159	45	for	for	ADP
eurjchem-1140	159	46	providing	provide	VERB
eurjchem-1140	159	47	spectra	spectra	ADJ
eurjchem-1140	159	48	and	and	CCONJ
eurjchem-1140	159	49	analytical	analytical	ADJ
eurjchem-1140	159	50	facility	facility	NOUN
eurjchem-1140	159	51	.	.	PUNCT
eurjchem-1140	160	1	recording	recording	NOUN
eurjchem-1140	160	2	of	of	ADP
eurjchem-1140	160	3	magnetic	magnetic	ADJ
eurjchem-1140	160	4	susceptibility	susceptibility	NOUN
eurjchem-1140	160	5	and	and	CCONJ
eurjchem-1140	160	6	elemental	elemental	ADJ
eurjchem-1140	160	7	analyses	analysis	NOUN
eurjchem-1140	160	8	are	be	AUX
eurjchem-1140	160	9	gratefully	gratefully	ADV
eurjchem-1140	160	10	acknowledged	acknowledge	VERB
eurjchem-1140	160	11	.	.	PUNCT
eurjchem-1140	161	1	furthermore	furthermore	ADV
eurjchem-1140	161	2	,	,	PUNCT
eurjchem-1140	161	3	the	the	DET
eurjchem-1140	161	4	authors	author	NOUN
eurjchem-1140	161	5	also	also	ADV
eurjchem-1140	161	6	thanked	thank	VERB
eurjchem-1140	161	7	al‐yarmook	al‐yarmook	PROPN
eurjchem-1140	161	8	university	university	PROPN
eurjchem-1140	161	9	(	(	PUNCT
eurjchem-1140	161	10	jordan	jordan	PROPN
eurjchem-1140	161	11	)	)	PUNCT
eurjchem-1140	161	12	for	for	ADP
eurjchem-1140	161	13	facilitating	facilitate	VERB
eurjchem-1140	161	14	the	the	DET
eurjchem-1140	161	15	nmr	nmr	NOUN
eurjchem-1140	161	16	analyses	analysis	NOUN
eurjchem-1140	161	17	.	.	PUNCT
eurjchem-1140	162	1	references	reference	NOUN
eurjchem-1140	162	2	[	[	X
eurjchem-1140	162	3	1	1	NUM
eurjchem-1140	162	4	]	]	PUNCT
eurjchem-1140	162	5	.	.	PUNCT
eurjchem-1140	163	1	andrien	andrien	PROPN
eurjchem-1140	163	2	,	,	PUNCT
eurjchem-1140	163	3	m.	m.	PROPN
eurjchem-1140	163	4	b.	b.	PROPN
eurjchem-1140	163	5	m.	m.	PROPN
eurjchem-1140	163	6	;	;	PUNCT
eurjchem-1140	163	7	merour	merour	NOUN
eurjchem-1140	163	8	,	,	PUNCT
eurjchem-1140	163	9	j.	j.	PROPN
eurjchem-1140	163	10	y.	y.	PROPN
eurjchem-1140	163	11	tetrahedron	tetrahedron	PROPN
eurjchem-1140	163	12	1998	1998	NUM
eurjchem-1140	163	13	,	,	PUNCT
eurjchem-1140	163	14	54	54	NUM
eurjchem-1140	163	15	,	,	PUNCT
eurjchem-1140	163	16	11095‐11110	11095‐11110	NUM
eurjchem-1140	163	17	.	.	PUNCT
eurjchem-1140	164	1	[	[	X
eurjchem-1140	164	2	2	2	NUM
eurjchem-1140	164	3	]	]	PUNCT
eurjchem-1140	164	4	.	.	PUNCT
eurjchem-1140	165	1	carta	carta	PROPN
eurjchem-1140	165	2	,	,	PUNCT
eurjchem-1140	165	3	a.	a.	NOUN
eurjchem-1140	165	4	;	;	PUNCT
eurjchem-1140	165	5	pagliett	pagliett	PROPN
eurjchem-1140	165	6	,	,	PUNCT
eurjchem-1140	165	7	g.	g.	PROPN
eurjchem-1140	165	8	;	;	PUNCT
eurjchem-1140	165	9	nikoot	nikoot	NOUN
eurjchem-1140	165	10	,	,	PUNCT
eurjchem-1140	165	11	m.	m.	NOUN
eurjchem-1140	165	12	;	;	PUNCT
eurjchem-1140	165	13	sanna	sanna	NOUN
eurjchem-1140	165	14	,	,	PUNCT
eurjchem-1140	165	15	p.	p.	NOUN
eurjchem-1140	165	16	;	;	PUNCT
eurjchem-1140	165	17	sechi	sechi	PROPN
eurjchem-1140	165	18	,	,	PUNCT
eurjchem-1140	165	19	l.	l.	PROPN
eurjchem-1140	165	20	;	;	PUNCT
eurjchem-1140	165	21	zanetti	zanetti	PROPN
eurjchem-1140	165	22	,	,	PUNCT
eurjchem-1140	165	23	s.	s.	PROPN
eurjchem-1140	165	24	eur	eur	PROPN
eurjchem-1140	165	25	.	.	PUNCT
eurjchem-1140	166	1	j.	j.	PROPN
eurjchem-1140	166	2	med	med	PROPN
eurjchem-1140	166	3	.	.	PROPN
eurjchem-1140	166	4	chem	chem	PROPN
eurjchem-1140	166	5	.	.	PUNCT
eurjchem-1140	167	1	2002	2002	NUM
eurjchem-1140	167	2	,	,	PUNCT
eurjchem-1140	167	3	37	37	NUM
eurjchem-1140	167	4	,	,	PUNCT
eurjchem-1140	167	5	355‐366	355‐366	NUM
eurjchem-1140	167	6	.	.	PUNCT
eurjchem-1140	168	1	[	[	X
eurjchem-1140	168	2	3	3	NUM
eurjchem-1140	168	3	]	]	PUNCT
eurjchem-1140	168	4	.	.	PUNCT
eurjchem-1140	168	5	moreno	moreno	PROPN
eurjchem-1140	168	6	,	,	PUNCT
eurjchem-1140	168	7	e.	e.	PROPN
eurjchem-1140	168	8	;	;	PUNCT
eurjchem-1140	168	9	ancizu	ancizu	PROPN
eurjchem-1140	168	10	,	,	PUNCT
eurjchem-1140	168	11	s.	s.	PROPN
eurjchem-1140	168	12	;	;	PUNCT
eurjchem-1140	168	13	perez‐silanes	perez‐silanes	PROPN
eurjchem-1140	168	14	,	,	PUNCT
eurjchem-1140	168	15	s.	s.	PROPN
eurjchem-1140	168	16	;	;	PUNCT
eurjchem-1140	168	17	torres	torre	NOUN
eurjchem-1140	168	18	,	,	PUNCT
eurjchem-1140	168	19	e.	e.	PROPN
eurjchem-1140	168	20	;	;	PUNCT
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eurjchem-1140	168	22	,	,	PUNCT
eurjchem-1140	168	23	l.	l.	PROPN
eurjchem-1140	168	24	;	;	PUNCT
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eurjchem-1140	168	26	,	,	PUNCT
eurjchem-1140	168	27	a.	a.	PROPN
eurjchem-1140	168	28	eur	eur	PROPN
eurjchem-1140	168	29	.	.	PUNCT
eurjchem-1140	169	1	med	med	PROPN
eurjchem-1140	169	2	.	.	PUNCT
eurjchem-1140	170	1	j.	j.	PROPN
eurjchem-1140	170	2	chem	chem	PROPN
eurjchem-1140	170	3	.	.	PUNCT
eurjchem-1140	171	1	2010	2010	NUM
eurjchem-1140	171	2	,	,	PUNCT
eurjchem-1140	171	3	45(10	45(10	NUM
eurjchem-1140	171	4	)	)	PUNCT
eurjchem-1140	171	5	,	,	PUNCT
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eurjchem-1140	171	7	.	.	PUNCT
eurjchem-1140	172	1	[	[	X
eurjchem-1140	172	2	4	4	NUM
eurjchem-1140	172	3	]	]	PUNCT
eurjchem-1140	172	4	.	.	PUNCT
eurjchem-1140	173	1	justin	justin	PROPN
eurjchem-1140	173	2	,	,	PUNCT
eurjchem-1140	173	3	d.	d.	PROPN
eurjchem-1140	173	4	c.	c.	PROPN
eurjchem-1140	173	5	;	;	PUNCT
eurjchem-1140	173	6	johnson	johnson	PROPN
eurjchem-1140	173	7	,	,	PUNCT
eurjchem-1140	173	8	j.	j.	PROPN
eurjchem-1140	173	9	spectrochim	spectrochim	PROPN
eurjchem-1140	173	10	.	.	PUNCT
eurjchem-1140	174	1	acta	acta	PROPN
eurjchem-1140	174	2	a	a	DET
eurjchem-1140	174	3	2014	2014	NUM
eurjchem-1140	174	4	,	,	PUNCT
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eurjchem-1140	174	6	,	,	PUNCT
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eurjchem-1140	174	8	.	.	PUNCT
eurjchem-1140	175	1	[	[	X
eurjchem-1140	175	2	5	5	NUM
eurjchem-1140	175	3	]	]	PUNCT
eurjchem-1140	175	4	.	.	PUNCT
eurjchem-1140	176	1	anantha	anantha	PROPN
eurjchem-1140	176	2	,	,	PUNCT
eurjchem-1140	176	3	p.	p.	NOUN
eurjchem-1140	176	4	v.	v.	PROPN
eurjchem-1140	176	5	;	;	PUNCT
eurjchem-1140	176	6	satyanarayana	satyanarayana	PROPN
eurjchem-1140	176	7	,	,	PUNCT
eurjchem-1140	176	8	t.	t.	PROPN
eurjchem-1140	176	9	;	;	PUNCT
eurjchem-1140	176	10	reddy	reddy	PROPN
eurjchem-1140	176	11	,	,	PUNCT
eurjchem-1140	176	12	p.	p.	PROPN
eurjchem-1140	176	13	s.	s.	PROPN
eurjchem-1140	176	14	chin	chin	PROPN
eurjchem-1140	176	15	.	.	PUNCT
eurjchem-1140	177	1	j.	j.	PROPN
eurjchem-1140	177	2	chem	chem	PROPN
eurjchem-1140	177	3	.	.	PUNCT
eurjchem-1140	178	1	2012	2012	NUM
eurjchem-1140	178	2	,	,	PUNCT
eurjchem-1140	178	3	30(4	30(4	NUM
eurjchem-1140	178	4	)	)	PUNCT
eurjchem-1140	178	5	,	,	PUNCT
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eurjchem-1140	178	7	.	.	PUNCT
eurjchem-1140	179	1	[	[	X
eurjchem-1140	179	2	6	6	NUM
eurjchem-1140	179	3	]	]	PUNCT
eurjchem-1140	179	4	.	.	PUNCT
eurjchem-1140	180	1	gauri	gauri	PROPN
eurjchem-1140	180	2	,	,	PUNCT
eurjchem-1140	180	3	g.	g.	PROPN
eurjchem-1140	180	4	;	;	PUNCT
eurjchem-1140	180	5	pretti	pretti	PROPN
eurjchem-1140	180	6	,	,	PUNCT
eurjchem-1140	180	7	v.	v.	ADP
eurjchem-1140	180	8	chem	chem	NOUN
eurjchem-1140	180	9	.	.	PUNCT
eurjchem-1140	181	1	sci	sci	PROPN
eurjchem-1140	181	2	.	.	PUNCT
eurjchem-1140	181	3	transac	transac	NOUN
eurjchem-1140	181	4	.	.	PUNCT
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eurjchem-1140	181	6	,	,	PUNCT
eurjchem-1140	181	7	3(3	3(3	NUM
eurjchem-1140	181	8	)	)	PUNCT
eurjchem-1140	181	9	,	,	PUNCT
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eurjchem-1140	181	11	.	.	PUNCT
eurjchem-1140	182	1	[	[	X
eurjchem-1140	182	2	7	7	NUM
eurjchem-1140	182	3	]	]	PUNCT
eurjchem-1140	182	4	.	.	PUNCT
eurjchem-1140	183	1	khan	khan	PROPN
eurjchem-1140	183	2	,	,	PUNCT
eurjchem-1140	183	3	s.	s.	PROPN
eurjchem-1140	183	4	a.	a.	PROPN
eurjchem-1140	183	5	;	;	PUNCT
eurjchem-1140	183	6	saleem	saleem	PROPN
eurjchem-1140	183	7	,	,	PUNCT
eurjchem-1140	183	8	k.	k.	PROPN
eurjchem-1140	183	9	;	;	PUNCT
eurjchem-1140	183	10	khan	khan	PROPN
eurjchem-1140	183	11	,	,	PUNCT
eurjchem-1140	183	12	z.	z.	PROPN
eurjchem-1140	183	13	eur	eur	PROPN
eurjchem-1140	183	14	.	.	PUNCT
eurjchem-1140	184	1	j.	j.	PROPN
eurjchem-1140	184	2	med	med	PROPN
eurjchem-1140	184	3	.	.	PROPN
eurjchem-1140	185	1	2007	2007	NUM
eurjchem-1140	185	2	,	,	PUNCT
eurjchem-1140	185	3	42	42	NUM
eurjchem-1140	185	4	,	,	PUNCT
eurjchem-1140	185	5	103‐108	103‐108	NUM
eurjchem-1140	185	6	.	.	PUNCT
eurjchem-1140	186	1	[	[	X
eurjchem-1140	186	2	8	8	NUM
eurjchem-1140	186	3	]	]	SYM
eurjchem-1140	186	4	.	.	PUNCT
eurjchem-1140	186	5	montoya	montoya	PROPN
eurjchem-1140	186	6	,	,	PUNCT
eurjchem-1140	186	7	m.	m.	PROPN
eurjchem-1140	186	8	e.	e.	PROPN
eurjchem-1140	186	9	;	;	PUNCT
eurjchem-1140	186	10	sainz	sainz	PROPN
eurjchem-1140	186	11	,	,	PUNCT
eurjchem-1140	186	12	y.	y.	PROPN
eurjchem-1140	186	13	;	;	PUNCT
eurjchem-1140	186	14	ortega	ortega	PROPN
eurjchem-1140	186	15	,	,	PUNCT
eurjchem-1140	186	16	m.	m.	NOUN
eurjchem-1140	186	17	a.	a.	PROPN
eurjchem-1140	186	18	;	;	PUNCT
eurjchem-1140	186	19	cerain	cerain	NOUN
eurjchem-1140	186	20	,	,	PUNCT
eurjchem-1140	186	21	a.	a.	PROPN
eurjchem-1140	186	22	l.	l.	PROPN
eurjchem-1140	186	23	;	;	PUNCT
eurjchem-1140	186	24	monge	monge	PROPN
eurjchem-1140	186	25	,	,	PUNCT
eurjchem-1140	186	26	a.	a.	PROPN
eurjchem-1140	186	27	il	il	PROPN
eurjchem-1140	186	28	farmaco	farmaco	PROPN
eurjchem-1140	186	29	1998	1998	NUM
eurjchem-1140	186	30	,	,	PUNCT
eurjchem-1140	186	31	53	53	NUM
eurjchem-1140	186	32	,	,	PUNCT
eurjchem-1140	186	33	570‐573	570‐573	NUM
eurjchem-1140	186	34	.	.	PUNCT
eurjchem-1140	187	1	[	[	X
eurjchem-1140	187	2	9	9	NUM
eurjchem-1140	187	3	]	]	PUNCT
eurjchem-1140	187	4	.	.	PUNCT
eurjchem-1140	187	5	dharanaj	dharanaj	PROPN
eurjchem-1140	187	6	,	,	PUNCT
eurjchem-1140	187	7	j.	j.	PROPN
eurjchem-1140	187	8	;	;	PUNCT
eurjchem-1140	187	9	johnson	johnson	PROPN
eurjchem-1140	187	10	,	,	PUNCT
eurjchem-1140	187	11	j.	j.	PROPN
eurjchem-1140	187	12	spectrochim	spectrochim	PROPN
eurjchem-1140	187	13	.	.	PUNCT
eurjchem-1140	188	1	acta	acta	PROPN
eurjchem-1140	188	2	a	a	DET
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eurjchem-1140	188	4	,	,	PUNCT
eurjchem-1140	188	5	118(24	118(24	NUM
eurjchem-1140	188	6	)	)	PUNCT
eurjchem-1140	188	7	,	,	PUNCT
eurjchem-1140	188	8	624‐631	624‐631	NOUN
eurjchem-1140	188	9	.	.	PUNCT
eurjchem-1140	189	1	[	[	X
eurjchem-1140	189	2	10	10	NUM
eurjchem-1140	189	3	]	]	PUNCT
eurjchem-1140	189	4	.	.	PUNCT
eurjchem-1140	190	1	sebastian	sebastian	PROPN
eurjchem-1140	190	2	,	,	PUNCT
eurjchem-1140	190	3	m.	m.	NOUN
eurjchem-1140	190	4	ph	ph	PROPN
eurjchem-1140	190	5	.	.	PROPN
eurjchem-1140	190	6	d.	d.	PROPN
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eurjchem-1140	190	8	,	,	PUNCT
eurjchem-1140	190	9	cohin	cohin	PROPN
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eurjchem-1140	190	11	,	,	PUNCT
eurjchem-1140	190	12	kochi	kochi	PROPN
eurjchem-1140	190	13	,	,	PUNCT
eurjchem-1140	190	14	2010	2010	NUM
eurjchem-1140	190	15	.	.	PUNCT
eurjchem-1140	191	1	[	[	X
eurjchem-1140	191	2	11	11	NUM
eurjchem-1140	191	3	]	]	PUNCT
eurjchem-1140	191	4	.	.	PUNCT
eurjchem-1140	192	1	varghese	varghese	PROPN
eurjchem-1140	192	2	,	,	PUNCT
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eurjchem-1140	192	4	;	;	PUNCT
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eurjchem-1140	192	6	,	,	PUNCT
eurjchem-1140	192	7	v.	v.	PROPN
eurjchem-1140	192	8	;	;	PUNCT
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eurjchem-1140	192	10	,	,	PUNCT
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eurjchem-1140	192	21	;	;	PUNCT
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eurjchem-1140	192	27	,	,	PUNCT
eurjchem-1140	192	28	k.	k.	PROPN
eurjchem-1140	192	29	k.	k.	PROPN
eurjchem-1140	192	30	m.	m.	PROPN
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eurjchem-1140	192	32	.	.	PUNCT
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eurjchem-1140	193	2	.	.	PUNCT
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eurjchem-1140	194	3	,	,	PUNCT
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eurjchem-1140	194	5	,	,	PUNCT
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eurjchem-1140	194	7	.	.	PUNCT
eurjchem-1140	195	1	[	[	X
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eurjchem-1140	195	3	]	]	PUNCT
eurjchem-1140	195	4	.	.	PUNCT
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eurjchem-1140	196	2	,	,	PUNCT
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eurjchem-1140	196	4	;	;	PUNCT
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eurjchem-1140	196	6	,	,	PUNCT
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eurjchem-1140	196	8	j.	j.	PROPN
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eurjchem-1140	196	10	.	.	PUNCT
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eurjchem-1140	197	2	.	.	PUNCT
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eurjchem-1140	198	2	.	.	PROPN
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eurjchem-1140	198	4	,	,	PUNCT
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eurjchem-1140	198	6	,	,	PUNCT
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eurjchem-1140	198	8	.	.	PUNCT
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eurjchem-1140	199	3	]	]	PUNCT
eurjchem-1140	199	4	.	.	PUNCT
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eurjchem-1140	199	6	,	,	PUNCT
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eurjchem-1140	199	8	k.	k.	PROPN
eurjchem-1140	199	9	;	;	PUNCT
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eurjchem-1140	199	11	,	,	PUNCT
eurjchem-1140	199	12	k.	k.	PROPN
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eurjchem-1140	199	14	;	;	PUNCT
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eurjchem-1140	199	16	,	,	PUNCT
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eurjchem-1140	199	21	,	,	PUNCT
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eurjchem-1140	199	23	h.	h.	PROPN
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eurjchem-1140	199	25	.	.	PROPN
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eurjchem-1140	200	4	,	,	PUNCT
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eurjchem-1140	200	6	,	,	PUNCT
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eurjchem-1140	200	8	.	.	PUNCT
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eurjchem-1140	201	3	]	]	PUNCT
eurjchem-1140	201	4	.	.	PUNCT
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eurjchem-1140	202	2	,	,	PUNCT
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eurjchem-1140	202	8	.	.	PUNCT
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eurjchem-1140	203	2	.	.	PUNCT
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eurjchem-1140	204	2	,	,	PUNCT
eurjchem-1140	204	3	3(4	3(4	NUM
eurjchem-1140	204	4	)	)	PUNCT
eurjchem-1140	204	5	,	,	PUNCT
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eurjchem-1140	204	7	.	.	PUNCT
eurjchem-1140	205	1	[	[	X
eurjchem-1140	205	2	15	15	NUM
eurjchem-1140	205	3	]	]	SYM
eurjchem-1140	205	4	.	.	PUNCT
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eurjchem-1140	205	6	,	,	PUNCT
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eurjchem-1140	205	8	a.	a.	NOUN
eurjchem-1140	205	9	;	;	PUNCT
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eurjchem-1140	205	11	,	,	PUNCT
eurjchem-1140	205	12	m.	m.	NOUN
eurjchem-1140	205	13	p.	p.	NOUN
eurjchem-1140	205	14	;	;	PUNCT
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eurjchem-1140	205	16	,	,	PUNCT
eurjchem-1140	205	17	v.	v.	PROPN
eurjchem-1140	205	18	k.	k.	PROPN
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eurjchem-1140	205	20	.	.	PROPN
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eurjchem-1140	205	22	.	.	PUNCT
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eurjchem-1140	206	2	.	.	PUNCT
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eurjchem-1140	207	2	,	,	PUNCT
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eurjchem-1140	207	4	,	,	PUNCT
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eurjchem-1140	207	6	.	.	PUNCT
eurjchem-1140	208	1	[	[	X
eurjchem-1140	208	2	16	16	NUM
eurjchem-1140	208	3	]	]	PUNCT
eurjchem-1140	208	4	.	.	PUNCT
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eurjchem-1140	209	2	,	,	PUNCT
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eurjchem-1140	209	7	chemistry	chemistry	NOUN
eurjchem-1140	209	8	,	,	PUNCT
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eurjchem-1140	209	11	,	,	PUNCT
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eurjchem-1140	209	13	,	,	PUNCT
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eurjchem-1140	210	2	17	17	NUM
eurjchem-1140	210	3	]	]	PUNCT
eurjchem-1140	210	4	.	.	PUNCT
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eurjchem-1140	211	2	,	,	PUNCT
eurjchem-1140	211	3	w.	w.	PROPN
eurjchem-1140	211	4	j.	j.	PROPN
eurjchem-1140	211	5	coord	coord	PROPN
eurjchem-1140	211	6	.	.	PUNCT
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eurjchem-1140	212	3	.	.	PROPN
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eurjchem-1140	212	5	,	,	PUNCT
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eurjchem-1140	212	7	)	)	PUNCT
eurjchem-1140	212	8	,	,	PUNCT
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eurjchem-1140	212	10	.	.	PUNCT
eurjchem-1140	213	1	[	[	X
eurjchem-1140	213	2	18	18	NUM
eurjchem-1140	213	3	]	]	PUNCT
eurjchem-1140	213	4	.	.	PUNCT
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eurjchem-1140	213	6	,	,	PUNCT
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eurjchem-1140	214	13	ltd	ltd	PROPN
eurjchem-1140	214	14	.	.	PROPN
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eurjchem-1140	214	17	.	.	PUNCT
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eurjchem-1140	215	3	]	]	PUNCT
eurjchem-1140	215	4	.	.	PUNCT
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eurjchem-1140	216	2	,	,	PUNCT
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eurjchem-1140	216	5	;	;	PUNCT
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eurjchem-1140	216	7	,	,	PUNCT
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eurjchem-1140	216	9	k.	k.	PROPN
eurjchem-1140	216	10	;	;	PUNCT
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eurjchem-1140	216	12	,	,	PUNCT
eurjchem-1140	216	13	j.	j.	PROPN
eurjchem-1140	216	14	y.	y.	PROPN
eurjchem-1140	216	15	;	;	PUNCT
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eurjchem-1140	216	17	,	,	PUNCT
eurjchem-1140	216	18	s.	s.	PROPN
eurjchem-1140	216	19	k.	k.	PROPN
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eurjchem-1140	216	21	.	.	PUNCT
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eurjchem-1140	217	2	.	.	PROPN
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eurjchem-1140	217	4	.	.	PUNCT
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eurjchem-1140	218	2	.	.	PUNCT
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eurjchem-1140	219	2	,	,	PUNCT
eurjchem-1140	219	3	14(2	14(2	NUM
eurjchem-1140	219	4	)	)	PUNCT
eurjchem-1140	219	5	,	,	PUNCT
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eurjchem-1140	219	7	.	.	PUNCT
eurjchem-1140	220	1	[	[	X
eurjchem-1140	220	2	20	20	NUM
eurjchem-1140	220	3	]	]	PUNCT
eurjchem-1140	220	4	.	.	PUNCT
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eurjchem-1140	221	2	,	,	PUNCT
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eurjchem-1140	221	12	compounds	compound	NOUN
eurjchem-1140	221	13	,	,	PUNCT
eurjchem-1140	221	14	5thedn	5thedn	NUM
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eurjchem-1140	221	16	,	,	PUNCT
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eurjchem-1140	221	19	sons	sons	PROPN
eurjchem-1140	221	20	,	,	PUNCT
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eurjchem-1140	221	23	,	,	PUNCT
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eurjchem-1140	221	25	,	,	PUNCT
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eurjchem-1140	221	27	.	.	PUNCT
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eurjchem-1140	222	2	.	.	PUNCT
eurjchem-1140	223	1	[	[	X
eurjchem-1140	223	2	21	21	NUM
eurjchem-1140	223	3	]	]	PUNCT
eurjchem-1140	223	4	.	.	PUNCT
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eurjchem-1140	224	2	,	,	PUNCT
eurjchem-1140	224	3	s.	s.	PROPN
eurjchem-1140	224	4	r.	r.	PROPN
eurjchem-1140	224	5	;	;	PUNCT
eurjchem-1140	224	6	parupalli	parupalli	PROPN
eurjchem-1140	224	7	,	,	PUNCT
eurjchem-1140	224	8	v.	v.	PROPN
eurjchem-1140	224	9	a.	a.	PROPN
eurjchem-1140	224	10	;	;	PUNCT
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eurjchem-1140	224	12	,	,	PUNCT
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eurjchem-1140	225	2	.	.	PUNCT
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eurjchem-1140	226	2	,	,	PUNCT
eurjchem-1140	226	3	19(1	19(1	NUM
eurjchem-1140	226	4	)	)	PUNCT
eurjchem-1140	226	5	,	,	PUNCT
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eurjchem-1140	226	7	.	.	PUNCT
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eurjchem-1140	227	3	]	]	PUNCT
eurjchem-1140	227	4	.	.	PUNCT
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eurjchem-1140	228	3	s.	s.	PROPN
eurjchem-1140	228	4	;	;	PUNCT
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eurjchem-1140	228	6	,	,	PUNCT
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eurjchem-1140	228	11	.	.	PUNCT
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eurjchem-1140	229	2	.	.	PUNCT
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eurjchem-1140	230	2	.	.	PUNCT
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eurjchem-1140	231	4	.	.	PUNCT
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eurjchem-1140	232	2	,	,	PUNCT
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eurjchem-1140	232	4	)	)	PUNCT
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eurjchem-1140	232	7	.	.	PUNCT
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eurjchem-1140	233	2	23	23	NUM
eurjchem-1140	233	3	]	]	PUNCT
eurjchem-1140	233	4	.	.	PUNCT
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eurjchem-1140	234	2	,	,	PUNCT
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eurjchem-1140	235	2	24	24	NUM
eurjchem-1140	235	3	]	]	PUNCT
eurjchem-1140	235	4	.	.	PUNCT
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eurjchem-1140	236	4	;	;	PUNCT
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eurjchem-1140	237	2	.	.	PUNCT
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eurjchem-1140	238	2	,	,	PUNCT
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eurjchem-1140	238	4	)	)	PUNCT
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