id sid tid token lemma pos eurjchem-124 1 1 microsoft microsoft PROPN eurjchem-124 1 2 word word NOUN eurjchem-124 1 3 european_journal_of_chemistry_1_3_2010_221_227_124 european_journal_of_chemistry_1_3_2010_221_227_124 PROPN eurjchem-124 1 4 european european ADJ eurjchem-124 1 5     SPACE eurjchem-124 1 6 journal journal NOUN eurjchem-124 1 7     SPACE eurjchem-124 1 8 of of ADP eurjchem-124 1 9     SPACE eurjchem-124 1 10 chemistry chemistry NOUN eurjchem-124 1 11     SPACE eurjchem-124 1 12 1 1 NUM eurjchem-124 1 13     SPACE eurjchem-124 1 14 ( ( PUNCT eurjchem-124 1 15 3 3 NUM eurjchem-124 1 16 ) ) PUNCT eurjchem-124 1 17     SPACE eurjchem-124 1 18 ( ( PUNCT eurjchem-124 1 19 2010 2010 NUM eurjchem-124 1 20 ) ) PUNCT eurjchem-124 1 21     SPACE eurjchem-124 1 22 221‐227 221‐227 PROPN eurjchem-124 1 23         SPACE eurjchem-124 1 24 european european ADJ eurjchem-124 1 25     SPACE eurjchem-124 1 26 journal journal NOUN eurjchem-124 1 27     SPACE eurjchem-124 1 28 of of ADP eurjchem-124 1 29     SPACE eurjchem-124 1 30 chemistry chemistry NOUN eurjchem-124 1 31     SPACE eurjchem-124 1 32 issn issn VERB eurjchem-124 1 33     SPACE eurjchem-124 1 34 2153‐2249 2153‐2249 NUM eurjchem-124 1 35     SPACE eurjchem-124 1 36 ( ( PUNCT eurjchem-124 1 37 print print NOUN eurjchem-124 1 38 ) ) PUNCT eurjchem-124 1 39     SPACE eurjchem-124 1 40 / / SYM eurjchem-124 1 41     SPACE eurjchem-124 1 42 issn issn VERB eurjchem-124 1 43     SPACE eurjchem-124 1 44 2153‐2257 2153‐2257 NUM eurjchem-124 1 45     SPACE eurjchem-124 1 46 ( ( PUNCT eurjchem-124 1 47 online online ADJ eurjchem-124 1 48 ) ) PUNCT eurjchem-124 1 49     SPACE eurjchem-124 1 50   NOUN eurjchem-124 1 51     SPACE eurjchem-124 1 52 2010 2010 NUM eurjchem-124 1 53     SPACE eurjchem-124 1 54 eurjchem eurjchem NOUN eurjchem-124 1 55     SPACE eurjchem-124 1 56 doi:10.5155 doi:10.5155 PROPN eurjchem-124 1 57 / / SYM eurjchem-124 1 58 eurjchem.1.3.221‐227.124 eurjchem.1.3.221‐227.124 NOUN eurjchem-124 1 59                 SPACE eurjchem-124 1 60 european european ADJ eurjchem-124 1 61     SPACE eurjchem-124 1 62 journal journal NOUN eurjchem-124 1 63     SPACE eurjchem-124 1 64 of of ADP eurjchem-124 1 65     SPACE eurjchem-124 1 66 chemistry chemistry NOUN eurjchem-124 1 67     SPACE eurjchem-124 1 68 journal journal NOUN eurjchem-124 1 69     SPACE eurjchem-124 1 70 homepage homepage NOUN eurjchem-124 1 71 : : PUNCT eurjchem-124 1 72     SPACE eurjchem-124 1 73 www.eurjchem.com www.eurjchem.com NOUN eurjchem-124 1 74                     SPACE eurjchem-124 1 75 synthesis synthesis NOUN eurjchem-124 1 76 , , PUNCT eurjchem-124 1 77     SPACE eurjchem-124 1 78 spectroscopic spectroscopic NOUN eurjchem-124 1 79     SPACE eurjchem-124 1 80 characterization characterization NOUN eurjchem-124 1 81 , , PUNCT eurjchem-124 1 82     SPACE eurjchem-124 1 83 crystal crystal NOUN eurjchem-124 1 84     SPACE eurjchem-124 1 85 structure structure NOUN eurjchem-124 1 86     SPACE eurjchem-124 1 87 and and CCONJ eurjchem-124 1 88     SPACE eurjchem-124 1 89 pharmacological pharmacological NOUN eurjchem-124 1 90     SPACE eurjchem-124 1 91 properties property NOUN eurjchem-124 1 92     SPACE eurjchem-124 1 93 of of ADP eurjchem-124 1 94     SPACE eurjchem-124 1 95 some some DET eurjchem-124 1 96     SPACE eurjchem-124 1 97 novel novel NOUN eurjchem-124 1 98     SPACE eurjchem-124 1 99 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 1 100     SPACE eurjchem-124 1 101 core core NOUN eurjchem-124 1 102     SPACE eurjchem-124 1 103 derivatives derivative NOUN eurjchem-124 1 104     SPACE eurjchem-124 1 105 sohail sohail NOUN eurjchem-124 1 106     SPACE eurjchem-124 1 107 saeeda saeeda NOUN eurjchem-124 1 108 , , PUNCT eurjchem-124 1 109 * * PUNCT eurjchem-124 1 110 , , PUNCT eurjchem-124 1 111     SPACE eurjchem-124 1 112 naghmana naghmana PROPN eurjchem-124 1 113     SPACE eurjchem-124 1 114 rashida rashida PROPN eurjchem-124 1 115 , , PUNCT eurjchem-124 1 116     SPACE eurjchem-124 1 117 muhammad muhammad PROPN eurjchem-124 1 118     SPACE eurjchem-124 1 119 alib alib NOUN eurjchem-124 1 120 , , PUNCT eurjchem-124 1 121     SPACE eurjchem-124 1 122 rizwan rizwan PROPN eurjchem-124 1 123     SPACE eurjchem-124 1 124 hussainc hussainc PROPN eurjchem-124 1 125     SPACE eurjchem-124 1 126 and and CCONJ eurjchem-124 1 127     SPACE eurjchem-124 1 128 peter peter PROPN eurjchem-124 1 129     SPACE eurjchem-124 1 130 jonesd jonesd VERB eurjchem-124 1 131     SPACE eurjchem-124 1 132 a a DET eurjchem-124 1 133     SPACE eurjchem-124 1 134 department department NOUN eurjchem-124 1 135     SPACE eurjchem-124 1 136 of of ADP eurjchem-124 1 137     SPACE eurjchem-124 1 138 chemistry chemistry NOUN eurjchem-124 1 139 , , PUNCT eurjchem-124 1 140     SPACE eurjchem-124 1 141 research research NOUN eurjchem-124 1 142     SPACE eurjchem-124 1 143 complex complex NOUN eurjchem-124 1 144 , , PUNCT eurjchem-124 1 145     SPACE eurjchem-124 1 146 allama allama PROPN eurjchem-124 1 147     SPACE eurjchem-124 1 148 iqbal iqbal PROPN eurjchem-124 1 149     SPACE eurjchem-124 1 150 open open ADJ eurjchem-124 1 151     SPACE eurjchem-124 1 152 university university NOUN eurjchem-124 1 153 , , PUNCT eurjchem-124 1 154     SPACE eurjchem-124 1 155 islamabad islamabad PROPN eurjchem-124 1 156 , , PUNCT eurjchem-124 1 157     SPACE eurjchem-124 1 158 44000 44000 NUM eurjchem-124 1 159 , , PUNCT eurjchem-124 1 160     SPACE eurjchem-124 1 161 pakistan pakistan PROPN eurjchem-124 1 162       SPACE eurjchem-124 1 163 b b PROPN eurjchem-124 1 164     SPACE eurjchem-124 1 165 department department NOUN eurjchem-124 1 166     SPACE eurjchem-124 1 167 of of ADP eurjchem-124 1 168     SPACE eurjchem-124 1 169 pharmacy pharmacy NOUN eurjchem-124 1 170 , , PUNCT eurjchem-124 1 171     SPACE eurjchem-124 1 172 university university NOUN eurjchem-124 1 173     SPACE eurjchem-124 1 174 of of ADP eurjchem-124 1 175     SPACE eurjchem-124 1 176 the the DET eurjchem-124 1 177     SPACE eurjchem-124 1 178 punjab punjab ADJ eurjchem-124 1 179 , , PUNCT eurjchem-124 1 180     SPACE eurjchem-124 1 181 lahore lahore NOUN eurjchem-124 1 182 , , PUNCT eurjchem-124 1 183     SPACE eurjchem-124 1 184 54590 54590 NUM eurjchem-124 1 185 , , PUNCT eurjchem-124 1 186     SPACE eurjchem-124 1 187 pakistan pakistan PROPN eurjchem-124 1 188       SPACE eurjchem-124 1 189 c c PROPN eurjchem-124 1 190     SPACE eurjchem-124 1 191 national national ADJ eurjchem-124 1 192     SPACE eurjchem-124 1 193 engineering engineering NOUN eurjchem-124 1 194     SPACE eurjchem-124 1 195 & & CCONJ eurjchem-124 1 196     SPACE eurjchem-124 1 197 scientific scientific ADJ eurjchem-124 1 198     SPACE eurjchem-124 1 199 commission commission NOUN eurjchem-124 1 200 , , PUNCT eurjchem-124 1 201     SPACE eurjchem-124 1 202 p.o p.o PROPN eurjchem-124 1 203 . . PROPN eurjchem-124 1 204     SPACE eurjchem-124 1 205 box box NOUN eurjchem-124 1 206     SPACE eurjchem-124 1 207 2801 2801 NUM eurjchem-124 1 208 , , PUNCT eurjchem-124 1 209     SPACE eurjchem-124 1 210 islamabad islamabad PROPN eurjchem-124 1 211 , , PUNCT eurjchem-124 1 212     SPACE eurjchem-124 1 213 pakistan pakistan PROPN eurjchem-124 1 214     SPACE eurjchem-124 1 215 d d PROPN eurjchem-124 1 216     SPACE eurjchem-124 1 217 institut institut PROPN eurjchem-124 1 218     SPACE eurjchem-124 1 219 für für PROPN eurjchem-124 1 220     SPACE eurjchem-124 1 221 anorganische anorganische PROPN eurjchem-124 1 222     SPACE eurjchem-124 1 223 und und PROPN eurjchem-124 1 224     SPACE eurjchem-124 1 225 analytische analytische NOUN eurjchem-124 1 226     SPACE eurjchem-124 1 227 chemie chemie PROPN eurjchem-124 1 228 , , PUNCT eurjchem-124 1 229     SPACE eurjchem-124 1 230 technische technische PROPN eurjchem-124 1 231     SPACE eurjchem-124 1 232 universität universität NOUN eurjchem-124 1 233     SPACE eurjchem-124 1 234 braunschweig braunschweig NOUN eurjchem-124 1 235 , , PUNCT eurjchem-124 1 236     SPACE eurjchem-124 1 237 braunschweig braunschweig NOUN eurjchem-124 1 238 , , PUNCT eurjchem-124 1 239     SPACE eurjchem-124 1 240 d­38023 d­38023 PROPN eurjchem-124 1 241 , , PUNCT eurjchem-124 1 242     SPACE eurjchem-124 1 243 germany germany PROPN eurjchem-124 1 244     SPACE eurjchem-124 1 245 * * PROPN eurjchem-124 1 246 corresponding corresponding ADJ eurjchem-124 1 247     SPACE eurjchem-124 1 248 author author NOUN eurjchem-124 1 249     SPACE eurjchem-124 1 250 at at ADP eurjchem-124 1 251 : : PUNCT eurjchem-124 1 252     SPACE eurjchem-124 1 253 department department NOUN eurjchem-124 1 254     SPACE eurjchem-124 1 255 of of ADP eurjchem-124 1 256     SPACE eurjchem-124 1 257 chemistry chemistry NOUN eurjchem-124 1 258 , , PUNCT eurjchem-124 1 259     SPACE eurjchem-124 1 260 research research NOUN eurjchem-124 1 261     SPACE eurjchem-124 1 262 complex complex NOUN eurjchem-124 1 263 , , PUNCT eurjchem-124 1 264     SPACE eurjchem-124 1 265 allama allama PROPN eurjchem-124 1 266     SPACE eurjchem-124 1 267 iqbal iqbal PROPN eurjchem-124 1 268     SPACE eurjchem-124 1 269 open open ADJ eurjchem-124 1 270     SPACE eurjchem-124 1 271 university university NOUN eurjchem-124 1 272 , , PUNCT eurjchem-124 1 273     SPACE eurjchem-124 1 274 islamabad islamabad PROPN eurjchem-124 1 275 , , PUNCT eurjchem-124 1 276     SPACE eurjchem-124 1 277 44000 44000 NUM eurjchem-124 1 278 , , PUNCT eurjchem-124 1 279     SPACE eurjchem-124 1 280 pakistan pakistan PROPN eurjchem-124 1 281 . . PUNCT eurjchem-124 1 282     SPACE eurjchem-124 2 1 tel tel PROPN eurjchem-124 2 2 . . PUNCT eurjchem-124 2 3 : : PUNCT eurjchem-124 2 4     SPACE eurjchem-124 2 5 +92.51.9250081 +92.51.9250081 NUM eurjchem-124 2 6 ; ; PUNCT eurjchem-124 2 7     SPACE eurjchem-124 2 8 fax fax NOUN eurjchem-124 2 9 : : PUNCT eurjchem-124 2 10     SPACE eurjchem-124 2 11 +92.51.9250081 +92.51.9250081 PROPN eurjchem-124 2 12 . . PUNCT eurjchem-124 2 13     SPACE eurjchem-124 2 14 e­mail e­mail NOUN eurjchem-124 2 15     SPACE eurjchem-124 2 16 address address NOUN eurjchem-124 2 17 : : PUNCT eurjchem-124 2 18     SPACE eurjchem-124 2 19 sohail262001@yahoo.com sohail262001@yahoo.com PROPN eurjchem-124 2 20       SPACE eurjchem-124 2 21 ( ( PUNCT eurjchem-124 2 22 s. s. PROPN eurjchem-124 2 23     SPACE eurjchem-124 2 24 saeed saeed PROPN eurjchem-124 2 25 ) ) PUNCT eurjchem-124 2 26 . . PUNCT eurjchem-124 2 27                                 SPACE eurjchem-124 2 28 article article NOUN eurjchem-124 2 29     SPACE eurjchem-124 2 30 information information NOUN eurjchem-124 2 31         SPACE eurjchem-124 2 32 abstract abstract ADJ eurjchem-124 2 33 received receive VERB eurjchem-124 2 34 : : PUNCT eurjchem-124 2 35     SPACE eurjchem-124 2 36 23 23 NUM eurjchem-124 2 37     SPACE eurjchem-124 2 38 may may AUX eurjchem-124 2 39     SPACE eurjchem-124 2 40 2010 2010 NUM eurjchem-124 2 41     SPACE eurjchem-124 2 42 received receive VERB eurjchem-124 2 43     SPACE eurjchem-124 2 44 in in ADP eurjchem-124 2 45     SPACE eurjchem-124 2 46 revised revise VERB eurjchem-124 2 47     SPACE eurjchem-124 2 48 form form NOUN eurjchem-124 2 49 : : PUNCT eurjchem-124 2 50     SPACE eurjchem-124 2 51 19 19 NUM eurjchem-124 2 52     SPACE eurjchem-124 2 53 july july PROPN eurjchem-124 2 54     SPACE eurjchem-124 2 55 2010 2010 NUM eurjchem-124 2 56     SPACE eurjchem-124 2 57 accepted accept VERB eurjchem-124 2 58 : : PUNCT eurjchem-124 2 59     SPACE eurjchem-124 2 60 19 19 NUM eurjchem-124 2 61     SPACE eurjchem-124 2 62 july july PROPN eurjchem-124 2 63     SPACE eurjchem-124 2 64 2010 2010 NUM eurjchem-124 2 65     SPACE eurjchem-124 2 66 online online NOUN eurjchem-124 2 67 : : PUNCT eurjchem-124 2 68     SPACE eurjchem-124 2 69 30 30 NUM eurjchem-124 2 70     SPACE eurjchem-124 2 71 september september PROPN eurjchem-124 2 72       SPACE eurjchem-124 2 73 2010 2010 NUM eurjchem-124 2 74     SPACE eurjchem-124 2 75 keywords keyword VERB eurjchem-124 2 76         SPACE eurjchem-124 2 77 this this DET eurjchem-124 2 78     SPACE eurjchem-124 2 79 article article NOUN eurjchem-124 2 80     SPACE eurjchem-124 2 81 presents present VERB eurjchem-124 2 82     SPACE eurjchem-124 2 83 our our PRON eurjchem-124 2 84     SPACE eurjchem-124 2 85 research research NOUN eurjchem-124 2 86     SPACE eurjchem-124 2 87 concerning concern VERB eurjchem-124 2 88     SPACE eurjchem-124 2 89 the the DET eurjchem-124 2 90     SPACE eurjchem-124 2 91 synthesis synthesis NOUN eurjchem-124 2 92     SPACE eurjchem-124 2 93 of of ADP eurjchem-124 2 94     SPACE eurjchem-124 2 95 new new ADJ eurjchem-124 2 96     SPACE eurjchem-124 2 97 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 2 98     SPACE eurjchem-124 2 99 derivatives derivative NOUN eurjchem-124 2 100     SPACE eurjchem-124 2 101 ( ( PUNCT eurjchem-124 2 102 1‐12 1‐12 NUM eurjchem-124 2 103 ) ) PUNCT eurjchem-124 2 104     SPACE eurjchem-124 2 105 and and CCONJ eurjchem-124 2 106     SPACE eurjchem-124 2 107 their their PRON eurjchem-124 2 108     SPACE eurjchem-124 2 109 pharmacological pharmacological NOUN eurjchem-124 2 110     SPACE eurjchem-124 2 111 properties property NOUN eurjchem-124 2 112 . . PUNCT eurjchem-124 2 113     SPACE eurjchem-124 3 1 these these DET eurjchem-124 3 2     SPACE eurjchem-124 3 3 novel novel NOUN eurjchem-124 3 4     SPACE eurjchem-124 3 5 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 3 6     SPACE eurjchem-124 3 7 derivatives derivative NOUN eurjchem-124 3 8     SPACE eurjchem-124 3 9 were be AUX eurjchem-124 3 10     SPACE eurjchem-124 3 11 synthesized synthesize VERB eurjchem-124 3 12     SPACE eurjchem-124 3 13 and and CCONJ eurjchem-124 3 14     SPACE eurjchem-124 3 15 characterized characterize VERB eurjchem-124 3 16     SPACE eurjchem-124 3 17 by by ADP eurjchem-124 3 18     SPACE eurjchem-124 3 19 ir ir PROPN eurjchem-124 3 20 , , PUNCT eurjchem-124 3 21     SPACE eurjchem-124 3 22 1h 1h NUM eurjchem-124 3 23     SPACE eurjchem-124 3 24 and and CCONJ eurjchem-124 3 25     SPACE eurjchem-124 3 26 13c 13c NOUN eurjchem-124 3 27     SPACE eurjchem-124 3 28 nmr nmr NOUN eurjchem-124 3 29     SPACE eurjchem-124 3 30 spectroscopy spectroscopy NOUN eurjchem-124 3 31 , , PUNCT eurjchem-124 3 32     SPACE eurjchem-124 3 33 mass mass ADJ eurjchem-124 3 34     SPACE eurjchem-124 3 35 spectrometry spectrometry NOUN eurjchem-124 3 36     SPACE eurjchem-124 3 37 and and CCONJ eurjchem-124 3 38     SPACE eurjchem-124 3 39 elemental elemental NOUN eurjchem-124 3 40     SPACE eurjchem-124 3 41 analysis analysis NOUN eurjchem-124 3 42 . . PUNCT eurjchem-124 3 43     SPACE eurjchem-124 4 1 the the DET eurjchem-124 4 2     SPACE eurjchem-124 4 3 crystal crystal NOUN eurjchem-124 4 4     SPACE eurjchem-124 4 5 structure structure NOUN eurjchem-124 4 6     SPACE eurjchem-124 4 7 of of ADP eurjchem-124 4 8     SPACE eurjchem-124 4 9 n n CCONJ eurjchem-124 4 10 , , PUNCT eurjchem-124 4 11 n‐diphenyl‐n’‐(thiophene‐2‐ n‐diphenyl‐n’‐(thiophene‐2‐ PRON eurjchem-124 4 12 carbonyl)‐thiourea carbonyl)‐thiourea NOUN eurjchem-124 4 13     SPACE eurjchem-124 4 14 was be AUX eurjchem-124 4 15     SPACE eurjchem-124 4 16 determined determine VERB eurjchem-124 4 17     SPACE eurjchem-124 4 18 from from ADP eurjchem-124 4 19     SPACE eurjchem-124 4 20 single single ADJ eurjchem-124 4 21     SPACE eurjchem-124 4 22 crystal crystal NOUN eurjchem-124 4 23     SPACE eurjchem-124 4 24 x‐ray x‐ray PROPN eurjchem-124 4 25     SPACE eurjchem-124 4 26 diffraction diffraction NOUN eurjchem-124 4 27     SPACE eurjchem-124 4 28 data datum NOUN eurjchem-124 4 29 . . PUNCT eurjchem-124 4 30     SPACE eurjchem-124 5 1 it it PRON eurjchem-124 5 2     SPACE eurjchem-124 5 3 crystallizes crystallize VERB eurjchem-124 5 4     SPACE eurjchem-124 5 5 in in ADP eurjchem-124 5 6     SPACE eurjchem-124 5 7 the the DET eurjchem-124 5 8     SPACE eurjchem-124 5 9 monoclinic monoclinic ADJ eurjchem-124 5 10     SPACE eurjchem-124 5 11 space space NOUN eurjchem-124 5 12     SPACE eurjchem-124 5 13 group group NOUN eurjchem-124 5 14     SPACE eurjchem-124 5 15 p21 p21 NOUN eurjchem-124 5 16     SPACE eurjchem-124 5 17 with with ADP eurjchem-124 5 18     SPACE eurjchem-124 5 19 unit unit NOUN eurjchem-124 5 20     SPACE eurjchem-124 5 21 cell cell NOUN eurjchem-124 5 22     SPACE eurjchem-124 5 23 dimensions dimension NOUN eurjchem-124 5 24     SPACE eurjchem-124 5 25 of of ADP eurjchem-124 5 26     SPACE eurjchem-124 5 27 a=11.7469(5 a=11.7469(5 PROPN eurjchem-124 5 28 ) ) PUNCT eurjchem-124 5 29     SPACE eurjchem-124 5 30 å å PROPN eurjchem-124 5 31 , , PUNCT eurjchem-124 5 32     SPACE eurjchem-124 5 33 b=6.0849(2 b=6.0849(2 NOUN eurjchem-124 5 34 ) ) PUNCT eurjchem-124 5 35     SPACE eurjchem-124 5 36 å å PROPN eurjchem-124 5 37 , , PUNCT eurjchem-124 5 38     SPACE eurjchem-124 5 39 c=12.5792(6 c=12.5792(6 ADJ eurjchem-124 5 40 ) ) PUNCT eurjchem-124 5 41     SPACE eurjchem-124 6 1 å å PROPN eurjchem-124 6 2 , , PUNCT eurjchem-124 6 3     SPACE eurjchem-124 6 4 β= β= NOUN eurjchem-124 6 5     SPACE eurjchem-124 6 6 117.736(7 117.736(7 NUM eurjchem-124 6 7 ) ) PUNCT eurjchem-124 6 8     SPACE eurjchem-124 6 9 ° ° NOUN eurjchem-124 6 10     SPACE eurjchem-124 6 11 and and CCONJ eurjchem-124 6 12     SPACE eurjchem-124 6 13 v v NOUN eurjchem-124 6 14     SPACE eurjchem-124 6 15 = = NOUN eurjchem-124 6 16     SPACE eurjchem-124 6 17 795.8(6 795.8(6 NOUN eurjchem-124 6 18 ) ) PUNCT eurjchem-124 6 19     SPACE eurjchem-124 6 20 å3 å3 PROPN eurjchem-124 6 21 . . PUNCT eurjchem-124 6 22     SPACE eurjchem-124 7 1 the the DET eurjchem-124 7 2     SPACE eurjchem-124 7 3 mass mass ADJ eurjchem-124 7 4     SPACE eurjchem-124 7 5 fragmentation fragmentation NOUN eurjchem-124 7 6     SPACE eurjchem-124 7 7 pattern pattern NOUN eurjchem-124 7 8     SPACE eurjchem-124 7 9 has have AUX eurjchem-124 7 10     SPACE eurjchem-124 7 11 also also ADV eurjchem-124 7 12     SPACE eurjchem-124 7 13 been be AUX eurjchem-124 7 14     SPACE eurjchem-124 7 15 discussed discuss VERB eurjchem-124 7 16 . . PUNCT eurjchem-124 7 17     SPACE eurjchem-124 8 1 the the DET eurjchem-124 8 2     SPACE eurjchem-124 8 3 synthesized synthesize VERB eurjchem-124 8 4     SPACE eurjchem-124 8 5 compounds compound NOUN eurjchem-124 8 6     SPACE eurjchem-124 8 7 were be AUX eurjchem-124 8 8     SPACE eurjchem-124 8 9 screened screen VERB eurjchem-124 8 10     SPACE eurjchem-124 8 11 for for ADP eurjchem-124 8 12     SPACE eurjchem-124 8 13 their their PRON eurjchem-124 8 14     SPACE eurjchem-124 8 15 in in ADP eurjchem-124 8 16     SPACE eurjchem-124 8 17 vitro vitro VERB eurjchem-124 8 18     SPACE eurjchem-124 8 19 antifungal antifungal ADJ eurjchem-124 8 20     SPACE eurjchem-124 8 21 activities activity NOUN eurjchem-124 8 22     SPACE eurjchem-124 8 23 against against ADP eurjchem-124 8 24     SPACE eurjchem-124 8 25 the the DET eurjchem-124 8 26     SPACE eurjchem-124 8 27 standard standard NOUN eurjchem-124 8 28     SPACE eurjchem-124 8 29 strains strain NOUN eurjchem-124 8 30 : : PUNCT eurjchem-124 8 31     SPACE eurjchem-124 8 32 c. c. NOUN eurjchem-124 8 33     SPACE eurjchem-124 8 34 albicans albican NOUN eurjchem-124 8 35 , , PUNCT eurjchem-124 8 36     SPACE eurjchem-124 8 37 c. c. PROPN eurjchem-124 8 38     SPACE eurjchem-124 8 39 glabrata glabrata NOUN eurjchem-124 8 40 , , PUNCT eurjchem-124 8 41     SPACE eurjchem-124 8 42 and and CCONJ eurjchem-124 8 43     SPACE eurjchem-124 8 44 c. c. NOUN eurjchem-124 8 45     SPACE eurjchem-124 8 46 tropicalis tropicalis PROPN eurjchem-124 8 47 . . PUNCT eurjchem-124 8 48     SPACE eurjchem-124 9 1 the the DET eurjchem-124 9 2     SPACE eurjchem-124 9 3 compounds compound NOUN eurjchem-124 9 4     SPACE eurjchem-124 9 5 n‐thiophene‐n’,n’‐bis(dimethyl‐phosphinoylmethyl)thiourea n‐thiophene‐n’,n’‐bis(dimethyl‐phosphinoylmethyl)thiourea PROPN eurjchem-124 9 6 , , PUNCT eurjchem-124 9 7     SPACE eurjchem-124 9 8 n‐[(4‐nitro‐1h‐ n‐[(4‐nitro‐1h‐ ADV eurjchem-124 9 9 imidazol‐2‐yl)carbamothioyl]thiophene‐2‐carboxamide imidazol‐2‐yl)carbamothioyl]thiophene‐2‐carboxamide NOUN eurjchem-124 9 10     SPACE eurjchem-124 9 11 and and CCONJ eurjchem-124 9 12     SPACE eurjchem-124 9 13 n n CCONJ eurjchem-124 9 14 , , PUNCT eurjchem-124 9 15 n‐diethyl‐n’‐(thiophene‐2‐ n‐diethyl‐n’‐(thiophene‐2‐ ADP eurjchem-124 9 16 carbonyl)‐thiourea carbonyl)‐thiourea VERB eurjchem-124 9 17     SPACE eurjchem-124 9 18 showed show VERB eurjchem-124 9 19     SPACE eurjchem-124 9 20 significant significant ADJ eurjchem-124 9 21     SPACE eurjchem-124 9 22 antifungal antifungal ADJ eurjchem-124 9 23     SPACE eurjchem-124 9 24 activities activity NOUN eurjchem-124 9 25     SPACE eurjchem-124 9 26 against against ADP eurjchem-124 9 27     SPACE eurjchem-124 9 28 microbial microbial ADJ eurjchem-124 9 29     SPACE eurjchem-124 9 30 species specie NOUN eurjchem-124 9 31 . . PUNCT eurjchem-124 9 32     SPACE eurjchem-124 9 33 thiourea thiourea NOUN eurjchem-124 9 34     SPACE eurjchem-124 9 35 derivatives derivative NOUN eurjchem-124 9 36     SPACE eurjchem-124 9 37 thiophene thiophene NOUN eurjchem-124 9 38     SPACE eurjchem-124 9 39 single single ADJ eurjchem-124 9 40     SPACE eurjchem-124 9 41 crystal crystal NOUN eurjchem-124 9 42     SPACE eurjchem-124 9 43 structure structure NOUN eurjchem-124 9 44     SPACE eurjchem-124 9 45 determination determination NOUN eurjchem-124 9 46     SPACE eurjchem-124 9 47 mass mass ADJ eurjchem-124 9 48     SPACE eurjchem-124 9 49 fragmentation fragmentation NOUN eurjchem-124 9 50       SPACE eurjchem-124 9 51 antifungal antifungal ADJ eurjchem-124 9 52     SPACE eurjchem-124 9 53 activity activity NOUN eurjchem-124 9 54         SPACE eurjchem-124 9 55 1 1 NUM eurjchem-124 9 56 . . PUNCT eurjchem-124 9 57     SPACE eurjchem-124 9 58 introduction introduction NOUN eurjchem-124 9 59         SPACE eurjchem-124 9 60 sulphur sulphur NOUN eurjchem-124 9 61     SPACE eurjchem-124 9 62 has have AUX eurjchem-124 9 63     SPACE eurjchem-124 9 64 been be AUX eurjchem-124 9 65     SPACE eurjchem-124 9 66 an an DET eurjchem-124 9 67     SPACE eurjchem-124 9 68 interesting interesting ADJ eurjchem-124 9 69     SPACE eurjchem-124 9 70 element element NOUN eurjchem-124 9 71     SPACE eurjchem-124 9 72 particularly particularly ADV eurjchem-124 9 73     SPACE eurjchem-124 9 74 for for ADP eurjchem-124 9 75     SPACE eurjchem-124 9 76 the the DET eurjchem-124 9 77     SPACE eurjchem-124 9 78 varieties variety NOUN eurjchem-124 9 79     SPACE eurjchem-124 9 80 of of ADP eurjchem-124 9 81     SPACE eurjchem-124 9 82 its its PRON eurjchem-124 9 83     SPACE eurjchem-124 9 84 compounds compound NOUN eurjchem-124 9 85     SPACE eurjchem-124 9 86 and and CCONJ eurjchem-124 9 87     SPACE eurjchem-124 9 88 varieties variety NOUN eurjchem-124 9 89     SPACE eurjchem-124 9 90 of of ADP eurjchem-124 9 91     SPACE eurjchem-124 9 92 bondings bonding NOUN eurjchem-124 9 93     SPACE eurjchem-124 9 94 it it PRON eurjchem-124 9 95     SPACE eurjchem-124 9 96 is be AUX eurjchem-124 9 97     SPACE eurjchem-124 9 98 involved involve VERB eurjchem-124 9 99     SPACE eurjchem-124 9 100 in in ADP eurjchem-124 9 101     SPACE eurjchem-124 9 102 [ [ X eurjchem-124 9 103 1 1 NUM eurjchem-124 9 104 ] ] PUNCT eurjchem-124 9 105 . . PUNCT eurjchem-124 9 106     SPACE eurjchem-124 10 1 it it PRON eurjchem-124 10 2     SPACE eurjchem-124 10 3 has have VERB eurjchem-124 10 4     SPACE eurjchem-124 10 5 a a DET eurjchem-124 10 6     SPACE eurjchem-124 10 7 prominent prominent ADJ eurjchem-124 10 8     SPACE eurjchem-124 10 9 bioorganic bioorganic ADJ eurjchem-124 10 10     SPACE eurjchem-124 10 11 chemistry chemistry NOUN eurjchem-124 10 12     SPACE eurjchem-124 10 13 and and CCONJ eurjchem-124 10 14     SPACE eurjchem-124 10 15 a a DET eurjchem-124 10 16     SPACE eurjchem-124 10 17 large large ADJ eurjchem-124 10 18     SPACE eurjchem-124 10 19 number number NOUN eurjchem-124 10 20     SPACE eurjchem-124 10 21 of of ADP eurjchem-124 10 22     SPACE eurjchem-124 10 23 enzymes enzyme NOUN eurjchem-124 10 24     SPACE eurjchem-124 10 25 and and CCONJ eurjchem-124 10 26     SPACE eurjchem-124 10 27 other other ADJ eurjchem-124 10 28     SPACE eurjchem-124 10 29 proteins protein NOUN eurjchem-124 10 30     SPACE eurjchem-124 10 31 such such ADJ eurjchem-124 10 32     SPACE eurjchem-124 10 33 as as ADP eurjchem-124 10 34     SPACE eurjchem-124 10 35 the the DET eurjchem-124 10 36     SPACE eurjchem-124 10 37 iron iron NOUN eurjchem-124 10 38     SPACE eurjchem-124 10 39 sulphur sulphur NOUN eurjchem-124 10 40     SPACE eurjchem-124 10 41 proteins protein NOUN eurjchem-124 10 42     SPACE eurjchem-124 10 43 exhibit exhibit NOUN eurjchem-124 10 44     SPACE eurjchem-124 10 45 fantastic fantastic ADJ eurjchem-124 10 46     SPACE eurjchem-124 10 47 properties property NOUN eurjchem-124 10 48     SPACE eurjchem-124 10 49 involving involve VERB eurjchem-124 10 50     SPACE eurjchem-124 10 51 the the DET eurjchem-124 10 52     SPACE eurjchem-124 10 53 sulphur sulphur NOUN eurjchem-124 10 54     SPACE eurjchem-124 10 55 atoms atom NOUN eurjchem-124 10 56     SPACE eurjchem-124 10 57 in in ADP eurjchem-124 10 58     SPACE eurjchem-124 10 59 them they PRON eurjchem-124 10 60     SPACE eurjchem-124 11 1 [ [ X eurjchem-124 11 2 2,3 2,3 NUM eurjchem-124 11 3 ] ] PUNCT eurjchem-124 11 4 . . PUNCT eurjchem-124 11 5     SPACE eurjchem-124 11 6 it it PRON eurjchem-124 11 7     SPACE eurjchem-124 11 8 is be AUX eurjchem-124 11 9     SPACE eurjchem-124 11 10 an an DET eurjchem-124 11 11     SPACE eurjchem-124 11 12 important important ADJ eurjchem-124 11 13     SPACE eurjchem-124 11 14 element element NOUN eurjchem-124 11 15     SPACE eurjchem-124 11 16 forming form VERB eurjchem-124 11 17     SPACE eurjchem-124 11 18 chains chain NOUN eurjchem-124 11 19     SPACE eurjchem-124 11 20 [ [ X eurjchem-124 11 21 4 4 NUM eurjchem-124 11 22 ] ] SYM eurjchem-124 11 23     SPACE eurjchem-124 11 24 and and CCONJ eurjchem-124 11 25     SPACE eurjchem-124 11 26 more more ADJ eurjchem-124 11 27     SPACE eurjchem-124 11 28 interestingly interestingly ADV eurjchem-124 11 29 , , PUNCT eurjchem-124 11 30     SPACE eurjchem-124 11 31 bridges bridge NOUN eurjchem-124 11 32     SPACE eurjchem-124 11 33 in in ADP eurjchem-124 11 34     SPACE eurjchem-124 11 35 polymers polymer NOUN eurjchem-124 11 36     SPACE eurjchem-124 11 37 and and CCONJ eurjchem-124 11 38     SPACE eurjchem-124 11 39 in in ADP eurjchem-124 11 40     SPACE eurjchem-124 11 41 varieties variety NOUN eurjchem-124 11 42     SPACE eurjchem-124 11 43 of of ADP eurjchem-124 11 44     SPACE eurjchem-124 11 45 composite composite ADJ eurjchem-124 11 46     SPACE eurjchem-124 11 47 materials material NOUN eurjchem-124 11 48 , , PUNCT eurjchem-124 11 49     SPACE eurjchem-124 11 50 giving give VERB eurjchem-124 11 51     SPACE eurjchem-124 11 52 rise rise NOUN eurjchem-124 11 53     SPACE eurjchem-124 11 54 to to PART eurjchem-124 11 55     SPACE eurjchem-124 11 56 strength strength NOUN eurjchem-124 11 57     SPACE eurjchem-124 11 58 and and CCONJ eurjchem-124 11 59     SPACE eurjchem-124 11 60 resistance resistance NOUN eurjchem-124 11 61     SPACE eurjchem-124 11 62 to to ADP eurjchem-124 11 63     SPACE eurjchem-124 11 64 aging age VERB eurjchem-124 11 65 . . PUNCT eurjchem-124 11 66     SPACE eurjchem-124 12 1 thioureas thiourea NOUN eurjchem-124 12 2     SPACE eurjchem-124 12 3 are be AUX eurjchem-124 12 4     SPACE eurjchem-124 12 5 potentially potentially ADV eurjchem-124 12 6     SPACE eurjchem-124 12 7 very very ADV eurjchem-124 12 8     SPACE eurjchem-124 12 9 versatile versatile ADJ eurjchem-124 12 10     SPACE eurjchem-124 12 11 ligands ligand NOUN eurjchem-124 12 12 , , PUNCT eurjchem-124 12 13     SPACE eurjchem-124 12 14 able able ADJ eurjchem-124 12 15     SPACE eurjchem-124 12 16 to to PART eurjchem-124 12 17     SPACE eurjchem-124 12 18 coordinate coordinate VERB eurjchem-124 12 19     SPACE eurjchem-124 12 20 to to ADP eurjchem-124 12 21     SPACE eurjchem-124 12 22 a a DET eurjchem-124 12 23     SPACE eurjchem-124 12 24 range range NOUN eurjchem-124 12 25     SPACE eurjchem-124 12 26 of of ADP eurjchem-124 12 27     SPACE eurjchem-124 12 28 metal metal NOUN eurjchem-124 12 29     SPACE eurjchem-124 12 30 centres centre NOUN eurjchem-124 12 31     SPACE eurjchem-124 12 32 as as ADP eurjchem-124 12 33     SPACE eurjchem-124 12 34 neutral neutral ADJ eurjchem-124 12 35     SPACE eurjchem-124 12 36 ligands ligand NOUN eurjchem-124 12 37 , , PUNCT eurjchem-124 12 38     SPACE eurjchem-124 12 39 monoanions monoanion NOUN eurjchem-124 12 40     SPACE eurjchem-124 12 41 or or CCONJ eurjchem-124 12 42     SPACE eurjchem-124 12 43 dianions dianion NOUN eurjchem-124 12 44     SPACE eurjchem-124 12 45 [ [ X eurjchem-124 12 46 5‐13 5‐13 NUM eurjchem-124 12 47 ] ] PUNCT eurjchem-124 12 48 . . PUNCT eurjchem-124 12 49     SPACE eurjchem-124 12 50 in in ADP eurjchem-124 12 51     SPACE eurjchem-124 12 52 addition addition NOUN eurjchem-124 12 53 , , PUNCT eurjchem-124 12 54     SPACE eurjchem-124 12 55 the the DET eurjchem-124 12 56     SPACE eurjchem-124 12 57 oxygen oxygen NOUN eurjchem-124 12 58 , , PUNCT eurjchem-124 12 59     SPACE eurjchem-124 12 60 nitrogen nitrogen NOUN eurjchem-124 12 61     SPACE eurjchem-124 12 62 and and CCONJ eurjchem-124 12 63     SPACE eurjchem-124 12 64 sulphur sulphur NOUN eurjchem-124 12 65     SPACE eurjchem-124 12 66 donor donor NOUN eurjchem-124 12 67     SPACE eurjchem-124 12 68 atoms atom NOUN eurjchem-124 12 69     SPACE eurjchem-124 12 70 provide provide VERB eurjchem-124 12 71     SPACE eurjchem-124 12 72 a a DET eurjchem-124 12 73     SPACE eurjchem-124 12 74 multitude multitude NOUN eurjchem-124 12 75     SPACE eurjchem-124 12 76 of of ADP eurjchem-124 12 77     SPACE eurjchem-124 12 78 bonding bonding NOUN eurjchem-124 12 79     SPACE eurjchem-124 12 80 possibilities possibility NOUN eurjchem-124 12 81 . . PUNCT eurjchem-124 12 82     SPACE eurjchem-124 13 1 the the DET eurjchem-124 13 2     SPACE eurjchem-124 13 3 coordination coordination NOUN eurjchem-124 13 4     SPACE eurjchem-124 13 5 chemistry chemistry NOUN eurjchem-124 13 6     SPACE eurjchem-124 13 7 of of ADP eurjchem-124 13 8     SPACE eurjchem-124 13 9 substituted substitute VERB eurjchem-124 13 10     SPACE eurjchem-124 13 11 thioureas thiourea NOUN eurjchem-124 13 12     SPACE eurjchem-124 13 13 has have AUX eurjchem-124 13 14     SPACE eurjchem-124 13 15 led lead VERB eurjchem-124 13 16     SPACE eurjchem-124 13 17 to to ADP eurjchem-124 13 18     SPACE eurjchem-124 13 19 some some DET eurjchem-124 13 20     SPACE eurjchem-124 13 21 interesting interesting ADJ eurjchem-124 13 22     SPACE eurjchem-124 13 23 practical practical ADJ eurjchem-124 13 24     SPACE eurjchem-124 13 25 applications application NOUN eurjchem-124 13 26 , , PUNCT eurjchem-124 13 27     SPACE eurjchem-124 13 28 including include VERB eurjchem-124 13 29     SPACE eurjchem-124 13 30 liquid‐liquid liquid‐liquid PROPN eurjchem-124 13 31     SPACE eurjchem-124 13 32 extraction extraction NOUN eurjchem-124 13 33 , , PUNCT eurjchem-124 13 34     SPACE eurjchem-124 13 35 pre‐ pre‐ NOUN eurjchem-124 13 36 concentration concentration NOUN eurjchem-124 13 37     SPACE eurjchem-124 13 38 and and CCONJ eurjchem-124 13 39     SPACE eurjchem-124 13 40 highly highly ADV eurjchem-124 13 41     SPACE eurjchem-124 13 42 efficient efficient ADJ eurjchem-124 13 43     SPACE eurjchem-124 13 44 chromatographic chromatographic ADJ eurjchem-124 13 45     SPACE eurjchem-124 13 46 separation separation NOUN eurjchem-124 13 47 , , PUNCT eurjchem-124 13 48     SPACE eurjchem-124 13 49 fluorimetric fluorimetric ADJ eurjchem-124 13 50     SPACE eurjchem-124 13 51 detection detection NOUN eurjchem-124 13 52     SPACE eurjchem-124 13 53 of of ADP eurjchem-124 13 54     SPACE eurjchem-124 13 55 the the DET eurjchem-124 13 56     SPACE eurjchem-124 13 57 platinum platinum NOUN eurjchem-124 13 58     SPACE eurjchem-124 13 59 group group NOUN eurjchem-124 13 60     SPACE eurjchem-124 13 61 metals metal NOUN eurjchem-124 13 62 , , PUNCT eurjchem-124 13 63     SPACE eurjchem-124 13 64 and and CCONJ eurjchem-124 13 65     SPACE eurjchem-124 13 66 the the DET eurjchem-124 13 67     SPACE eurjchem-124 13 68 selective selective ADJ eurjchem-124 13 69     SPACE eurjchem-124 13 70 on‐line on‐line NOUN eurjchem-124 13 71     SPACE eurjchem-124 13 72 pre‐concentration pre‐concentration NOUN eurjchem-124 13 73     SPACE eurjchem-124 13 74 of of ADP eurjchem-124 13 75     SPACE eurjchem-124 13 76 ultra‐traces ultra‐trace NOUN eurjchem-124 13 77     SPACE eurjchem-124 13 78 of of ADP eurjchem-124 13 79     SPACE eurjchem-124 13 80 palladium palladium NOUN eurjchem-124 13 81 , , PUNCT eurjchem-124 13 82     SPACE eurjchem-124 13 83 followed follow VERB eurjchem-124 13 84     SPACE eurjchem-124 13 85 by by ADP eurjchem-124 13 86     SPACE eurjchem-124 13 87 its its PRON eurjchem-124 13 88     SPACE eurjchem-124 13 89 determination determination NOUN eurjchem-124 13 90     SPACE eurjchem-124 13 91 using use VERB eurjchem-124 13 92     SPACE eurjchem-124 13 93 graphite graphite NOUN eurjchem-124 13 94     SPACE eurjchem-124 13 95 furnace furnace NOUN eurjchem-124 13 96     SPACE eurjchem-124 13 97 atom atom NOUN eurjchem-124 13 98     SPACE eurjchem-124 13 99 absorption absorption NOUN eurjchem-124 13 100     SPACE eurjchem-124 13 101 spectrometry spectrometry NOUN eurjchem-124 13 102     SPACE eurjchem-124 14 1 [ [ X eurjchem-124 14 2 14,15 14,15 NUM eurjchem-124 14 3 ] ] X eurjchem-124 14 4 . . PUNCT eurjchem-124 14 5     SPACE eurjchem-124 14 6 thiourea thiourea NOUN eurjchem-124 14 7     SPACE eurjchem-124 14 8 and and CCONJ eurjchem-124 14 9     SPACE eurjchem-124 14 10 its its PRON eurjchem-124 14 11     SPACE eurjchem-124 14 12 derivatives derivative NOUN eurjchem-124 14 13     SPACE eurjchem-124 14 14 have have AUX eurjchem-124 14 15     SPACE eurjchem-124 14 16 found find VERB eurjchem-124 14 17     SPACE eurjchem-124 14 18 extensive extensive ADJ eurjchem-124 14 19     SPACE eurjchem-124 14 20 applications application NOUN eurjchem-124 14 21     SPACE eurjchem-124 14 22 in in ADP eurjchem-124 14 23     SPACE eurjchem-124 14 24 the the DET eurjchem-124 14 25     SPACE eurjchem-124 14 26 fields field NOUN eurjchem-124 14 27     SPACE eurjchem-124 14 28 of of ADP eurjchem-124 14 29     SPACE eurjchem-124 14 30 medicine medicine NOUN eurjchem-124 14 31 , , PUNCT eurjchem-124 14 32     SPACE eurjchem-124 14 33 agriculture agriculture NOUN eurjchem-124 14 34     SPACE eurjchem-124 14 35 and and CCONJ eurjchem-124 14 36     SPACE eurjchem-124 14 37 analytical analytical ADJ eurjchem-124 14 38     SPACE eurjchem-124 14 39 chemistry chemistry NOUN eurjchem-124 14 40 . . PUNCT eurjchem-124 14 41     SPACE eurjchem-124 15 1 they they PRON eurjchem-124 15 2     SPACE eurjchem-124 15 3 are be AUX eurjchem-124 15 4     SPACE eurjchem-124 15 5 known know VERB eurjchem-124 15 6     SPACE eurjchem-124 15 7 to to PART eurjchem-124 15 8     SPACE eurjchem-124 15 9 exhibit exhibit VERB eurjchem-124 15 10     SPACE eurjchem-124 15 11 a a DET eurjchem-124 15 12     SPACE eurjchem-124 15 13 wide wide ADJ eurjchem-124 15 14     SPACE eurjchem-124 15 15 variety variety NOUN eurjchem-124 15 16     SPACE eurjchem-124 15 17 of of ADP eurjchem-124 15 18     SPACE eurjchem-124 15 19 biological biological ADJ eurjchem-124 15 20     SPACE eurjchem-124 15 21 activities activity NOUN eurjchem-124 15 22     SPACE eurjchem-124 15 23 such such ADJ eurjchem-124 15 24     SPACE eurjchem-124 15 25 as as ADP eurjchem-124 15 26     SPACE eurjchem-124 15 27 antiviral antiviral ADJ eurjchem-124 15 28 , , PUNCT eurjchem-124 15 29     SPACE eurjchem-124 15 30 antibacterial antibacterial ADJ eurjchem-124 15 31 , , PUNCT eurjchem-124 15 32     SPACE eurjchem-124 15 33 antifungal antifungal PROPN eurjchem-124 15 34     SPACE eurjchem-124 16 1 [ [ X eurjchem-124 16 2 16 16 NUM eurjchem-124 16 3 ] ] PUNCT eurjchem-124 16 4 , , PUNCT eurjchem-124 16 5     SPACE eurjchem-124 16 6 antitubercular antitubercular ADJ eurjchem-124 16 7 , , PUNCT eurjchem-124 16 8     SPACE eurjchem-124 16 9 herbicidal herbicidal NOUN eurjchem-124 16 10 , , PUNCT eurjchem-124 16 11     SPACE eurjchem-124 16 12 insecticidal insecticidal NOUN eurjchem-124 16 13     SPACE eurjchem-124 16 14 [ [ X eurjchem-124 16 15 17 17 NUM eurjchem-124 16 16 ] ] PUNCT eurjchem-124 16 17 , , PUNCT eurjchem-124 16 18     SPACE eurjchem-124 16 19 and and CCONJ eurjchem-124 16 20     SPACE eurjchem-124 16 21 to to PART eurjchem-124 16 22     SPACE eurjchem-124 16 23 act act VERB eurjchem-124 16 24     SPACE eurjchem-124 16 25 as as ADP eurjchem-124 16 26     SPACE eurjchem-124 16 27 chelating chelating NOUN eurjchem-124 16 28     SPACE eurjchem-124 16 29 agents agent NOUN eurjchem-124 16 30     SPACE eurjchem-124 16 31 [ [ X eurjchem-124 16 32 18 18 NUM eurjchem-124 16 33 ] ] PUNCT eurjchem-124 16 34 , , PUNCT eurjchem-124 16 35     SPACE eurjchem-124 16 36 in in ADP eurjchem-124 16 37     SPACE eurjchem-124 16 38 catalysis catalysis NOUN eurjchem-124 16 39     SPACE eurjchem-124 16 40 [ [ X eurjchem-124 16 41 19 19 NUM eurjchem-124 16 42 ] ] PUNCT eurjchem-124 16 43 , , PUNCT eurjchem-124 16 44     SPACE eurjchem-124 16 45 in in ADP eurjchem-124 16 46     SPACE eurjchem-124 16 47 anion anion NOUN eurjchem-124 16 48     SPACE eurjchem-124 16 49 recognition recognition NOUN eurjchem-124 16 50     SPACE eurjchem-124 17 1 [ [ X eurjchem-124 17 2 20 20 NUM eurjchem-124 17 3 ] ] SYM eurjchem-124 17 4     SPACE eurjchem-124 17 5 and and CCONJ eurjchem-124 17 6     SPACE eurjchem-124 17 7 to to PART eurjchem-124 17 8     SPACE eurjchem-124 17 9 play play VERB eurjchem-124 17 10     SPACE eurjchem-124 17 11 a a DET eurjchem-124 17 12     SPACE eurjchem-124 17 13 role role NOUN eurjchem-124 17 14     SPACE eurjchem-124 17 15 in in ADP eurjchem-124 17 16     SPACE eurjchem-124 17 17 some some DET eurjchem-124 17 18     SPACE eurjchem-124 17 19 epoxy epoxy NOUN eurjchem-124 17 20     SPACE eurjchem-124 17 21 resin resin NOUN eurjchem-124 17 22     SPACE eurjchem-124 17 23 curing cure VERB eurjchem-124 17 24     SPACE eurjchem-124 17 25 agents agent NOUN eurjchem-124 17 26     SPACE eurjchem-124 17 27 containing contain VERB eurjchem-124 17 28     SPACE eurjchem-124 17 29 amino amino NOUN eurjchem-124 17 30     SPACE eurjchem-124 17 31 functional functional ADJ eurjchem-124 17 32     SPACE eurjchem-124 17 33 groups group NOUN eurjchem-124 17 34     SPACE eurjchem-124 18 1 [ [ X eurjchem-124 18 2 16 16 NUM eurjchem-124 18 3 ] ] PUNCT eurjchem-124 18 4 . . PUNCT eurjchem-124 18 5     SPACE eurjchem-124 18 6 substituted substitute VERB eurjchem-124 18 7     SPACE eurjchem-124 18 8 thioureas thiourea NOUN eurjchem-124 18 9     SPACE eurjchem-124 18 10 are be AUX eurjchem-124 18 11     SPACE eurjchem-124 18 12 an an DET eurjchem-124 18 13     SPACE eurjchem-124 18 14 important important ADJ eurjchem-124 18 15     SPACE eurjchem-124 18 16 class class NOUN eurjchem-124 18 17     SPACE eurjchem-124 18 18 of of ADP eurjchem-124 18 19     SPACE eurjchem-124 18 20 compounds compound NOUN eurjchem-124 18 21 , , PUNCT eurjchem-124 18 22     SPACE eurjchem-124 18 23 precursors precursor NOUN eurjchem-124 18 24     SPACE eurjchem-124 18 25 or or CCONJ eurjchem-124 18 26     SPACE eurjchem-124 18 27 intermediates intermediate NOUN eurjchem-124 18 28     SPACE eurjchem-124 18 29 for for ADP eurjchem-124 18 30     SPACE eurjchem-124 18 31 the the DET eurjchem-124 18 32     SPACE eurjchem-124 18 33 synthesis synthesis NOUN eurjchem-124 18 34     SPACE eurjchem-124 18 35 of of ADP eurjchem-124 18 36     SPACE eurjchem-124 18 37 a a DET eurjchem-124 18 38     SPACE eurjchem-124 18 39 variety variety NOUN eurjchem-124 18 40     SPACE eurjchem-124 18 41 of of ADP eurjchem-124 18 42     SPACE eurjchem-124 18 43 heterocyclic heterocyclic ADJ eurjchem-124 18 44     SPACE eurjchem-124 18 45 systems system NOUN eurjchem-124 18 46     SPACE eurjchem-124 18 47 such such ADJ eurjchem-124 18 48     SPACE eurjchem-124 18 49 as as ADP eurjchem-124 18 50     SPACE eurjchem-124 18 51 imidazole‐2‐thiones imidazole‐2‐thione NOUN eurjchem-124 18 52     SPACE eurjchem-124 18 53 [ [ X eurjchem-124 18 54 21 21 NUM eurjchem-124 18 55 ] ] PUNCT eurjchem-124 18 56 , , PUNCT eurjchem-124 18 57     SPACE eurjchem-124 18 58 2‐imino‐ 2‐imino‐ NUM eurjchem-124 18 59 1,3‐thiazolines 1,3‐thiazolines NUM eurjchem-124 18 60     SPACE eurjchem-124 19 1 [ [ PUNCT eurjchem-124 19 2 22 22 NUM eurjchem-124 19 3 ] ] PUNCT eurjchem-124 19 4 , , PUNCT eurjchem-124 19 5     SPACE eurjchem-124 19 6 pyrimidine‐2‐thiones pyrimidine‐2‐thione NOUN eurjchem-124 19 7     SPACE eurjchem-124 19 8 and and CCONJ eurjchem-124 19 9     SPACE eurjchem-124 19 10 benzothiazolyl‐ benzothiazolyl‐ PUNCT eurjchem-124 20 1 4‐quinazolinones 4‐quinazolinone NOUN eurjchem-124 20 2     SPACE eurjchem-124 21 1 [ [ X eurjchem-124 21 2 23 23 NUM eurjchem-124 21 3 ] ] PUNCT eurjchem-124 21 4 , , PUNCT eurjchem-124 21 5     SPACE eurjchem-124 21 6 n‐(substituted n‐(substitute VERB eurjchem-124 21 7     SPACE eurjchem-124 21 8 phenyl)‐n‐phenylthio phenyl)‐n‐phenylthio NOUN eurjchem-124 21 9     SPACE eurjchem-124 21 10 ureas urea NOUN eurjchem-124 21 11     SPACE eurjchem-124 21 12 have have AUX eurjchem-124 21 13     SPACE eurjchem-124 21 14 been be AUX eurjchem-124 21 15     SPACE eurjchem-124 21 16 developed develop VERB eurjchem-124 21 17     SPACE eurjchem-124 21 18 as as ADP eurjchem-124 21 19     SPACE eurjchem-124 21 20 anion‐binding anion‐binding NOUN eurjchem-124 21 21     SPACE eurjchem-124 21 22 sites site NOUN eurjchem-124 21 23     SPACE eurjchem-124 21 24 in in ADP eurjchem-124 21 25     SPACE eurjchem-124 21 26 a a DET eurjchem-124 21 27     SPACE eurjchem-124 21 28 hydrogen‐bonding hydrogen‐bonde VERB eurjchem-124 21 29     SPACE eurjchem-124 21 30 receptor receptor NOUN eurjchem-124 21 31     SPACE eurjchem-124 21 32 [ [ X eurjchem-124 21 33 24 24 NUM eurjchem-124 21 34 ] ] PUNCT eurjchem-124 21 35 , , PUNCT eurjchem-124 21 36     SPACE eurjchem-124 21 37 calixarenes calixarene NOUN eurjchem-124 21 38     SPACE eurjchem-124 21 39 containing contain VERB eurjchem-124 21 40     SPACE eurjchem-124 21 41 thioureas thiourea NOUN eurjchem-124 21 42     SPACE eurjchem-124 21 43 as as ADP eurjchem-124 21 44     SPACE eurjchem-124 21 45 neutral neutral ADJ eurjchem-124 21 46     SPACE eurjchem-124 21 47 receptors receptor NOUN eurjchem-124 21 48     SPACE eurjchem-124 21 49 towards towards ADP eurjchem-124 21 50     SPACE eurjchem-124 21 51 α α NOUN eurjchem-124 21 52 , , PUNCT eurjchem-124 21 53 α‐dicarboxylate α‐dicarboxylate ADP eurjchem-124 21 54     SPACE eurjchem-124 21 55 anions anion NOUN eurjchem-124 21 56     SPACE eurjchem-124 22 1 [ [ X eurjchem-124 22 2 25 25 NUM eurjchem-124 22 3 ] ] PUNCT eurjchem-124 22 4 , , PUNCT eurjchem-124 22 5     SPACE eurjchem-124 22 6 and and CCONJ eurjchem-124 22 7     SPACE eurjchem-124 22 8 n‐4‐substituted‐benzyl‐n‐tert‐butylbenzyl n‐4‐substituted‐benzyl‐n‐tert‐butylbenzyl NOUN eurjchem-124 22 9     SPACE eurjchem-124 22 10 thioureas thiourea NOUN eurjchem-124 22 11     SPACE eurjchem-124 22 12 as as ADP eurjchem-124 22 13     SPACE eurjchem-124 22 14 vanilloid vanilloid NOUN eurjchem-124 22 15     SPACE eurjchem-124 22 16 receptor receptor NOUN eurjchem-124 22 17     SPACE eurjchem-124 22 18 ligands ligand NOUN eurjchem-124 22 19     SPACE eurjchem-124 22 20 and and CCONJ eurjchem-124 22 21     SPACE eurjchem-124 22 22 antagonists antagonist NOUN eurjchem-124 22 23     SPACE eurjchem-124 22 24 in in ADP eurjchem-124 22 25     SPACE eurjchem-124 22 26 rate rate NOUN eurjchem-124 22 27     SPACE eurjchem-124 22 28 drg drg NOUN eurjchem-124 22 29     SPACE eurjchem-124 22 30 neurons neuron NOUN eurjchem-124 22 31     SPACE eurjchem-124 23 1 [ [ X eurjchem-124 23 2 26 26 NUM eurjchem-124 23 3 ] ] PUNCT eurjchem-124 23 4 . . PUNCT eurjchem-124 23 5     SPACE eurjchem-124 24 1 as as ADP eurjchem-124 24 2     SPACE eurjchem-124 24 3 part part NOUN eurjchem-124 24 4     SPACE eurjchem-124 24 5 of of ADP eurjchem-124 24 6     SPACE eurjchem-124 24 7 our our PRON eurjchem-124 24 8     SPACE eurjchem-124 24 9 research research NOUN eurjchem-124 24 10     SPACE eurjchem-124 24 11 on on ADP eurjchem-124 24 12     SPACE eurjchem-124 24 13 coordination coordination NOUN eurjchem-124 24 14     SPACE eurjchem-124 24 15 chemistry chemistry NOUN eurjchem-124 24 16     SPACE eurjchem-124 24 17 of of ADP eurjchem-124 24 18     SPACE eurjchem-124 24 19 thioureas thiourea NOUN eurjchem-124 24 20 , , PUNCT eurjchem-124 24 21     SPACE eurjchem-124 24 22 we we PRON eurjchem-124 24 23     SPACE eurjchem-124 24 24 are be AUX eurjchem-124 24 25     SPACE eurjchem-124 24 26 interested interested ADJ eurjchem-124 24 27     SPACE eurjchem-124 24 28 in in ADP eurjchem-124 24 29     SPACE eurjchem-124 24 30 the the DET eurjchem-124 24 31     SPACE eurjchem-124 24 32 study study NOUN eurjchem-124 24 33     SPACE eurjchem-124 24 34 of of ADP eurjchem-124 24 35     SPACE eurjchem-124 24 36 the the DET eurjchem-124 24 37     SPACE eurjchem-124 24 38 influence influence NOUN eurjchem-124 24 39     SPACE eurjchem-124 24 40 of of ADP eurjchem-124 24 41     SPACE eurjchem-124 24 42 non‐covalent non‐covalent NUM eurjchem-124 24 43     SPACE eurjchem-124 24 44 interactions interaction NOUN eurjchem-124 24 45 , , PUNCT eurjchem-124 24 46     SPACE eurjchem-124 24 47 especially especially ADV eurjchem-124 24 48     SPACE eurjchem-124 24 49 hydrogen hydrogen NOUN eurjchem-124 24 50     SPACE eurjchem-124 24 51 bonds bond NOUN eurjchem-124 24 52     SPACE eurjchem-124 24 53 and and CCONJ eurjchem-124 24 54     SPACE eurjchem-124 24 55 π‐π π‐π PROPN eurjchem-124 24 56     SPACE eurjchem-124 24 57 stacking stack VERB eurjchem-124 24 58     SPACE eurjchem-124 24 59 interactions interaction NOUN eurjchem-124 24 60 , , PUNCT eurjchem-124 24 61     SPACE eurjchem-124 24 62 on on ADP eurjchem-124 24 63     SPACE eurjchem-124 24 64 the the DET eurjchem-124 24 65     SPACE eurjchem-124 24 66 coordination coordination NOUN eurjchem-124 24 67     SPACE eurjchem-124 24 68 modes mode NOUN eurjchem-124 24 69     SPACE eurjchem-124 24 70 of of ADP eurjchem-124 24 71     SPACE eurjchem-124 24 72 thiocarbonyl thiocarbonyl NOUN eurjchem-124 24 73     SPACE eurjchem-124 24 74 donor donor NOUN eurjchem-124 24 75     SPACE eurjchem-124 24 76 groups group NOUN eurjchem-124 24 77     SPACE eurjchem-124 24 78 with with ADP eurjchem-124 24 79     SPACE eurjchem-124 24 80 transition transition NOUN eurjchem-124 24 81     SPACE eurjchem-124 24 82 metal metal NOUN eurjchem-124 24 83     SPACE eurjchem-124 24 84 ions ion NOUN eurjchem-124 24 85 . . PUNCT eurjchem-124 24 86     SPACE eurjchem-124 24 87 such such ADJ eurjchem-124 24 88     SPACE eurjchem-124 24 89 coordination coordination NOUN eurjchem-124 24 90     SPACE eurjchem-124 24 91 compounds compound NOUN eurjchem-124 24 92     SPACE eurjchem-124 24 93 of of ADP eurjchem-124 24 94     SPACE eurjchem-124 24 95 thiourea thiourea NOUN eurjchem-124 24 96     SPACE eurjchem-124 24 97 have have AUX eurjchem-124 24 98     SPACE eurjchem-124 24 99 been be AUX eurjchem-124 24 100     SPACE eurjchem-124 24 101 studied study VERB eurjchem-124 24 102     SPACE eurjchem-124 24 103 for for ADP eurjchem-124 24 104     SPACE eurjchem-124 24 105 various various ADJ eurjchem-124 24 106     SPACE eurjchem-124 24 107 biological biological ADJ eurjchem-124 24 108     SPACE eurjchem-124 24 109 systems system NOUN eurjchem-124 24 110     SPACE eurjchem-124 24 111 with with ADP eurjchem-124 24 112     SPACE eurjchem-124 24 113 respect respect NOUN eurjchem-124 24 114     SPACE eurjchem-124 24 115 to to ADP eurjchem-124 24 116     SPACE eurjchem-124 24 117 antibacterial antibacterial ADJ eurjchem-124 24 118 , , PUNCT eurjchem-124 24 119     SPACE eurjchem-124 24 120 antifungal antifungal ADJ eurjchem-124 24 121     SPACE eurjchem-124 24 122 and and CCONJ eurjchem-124 24 123     SPACE eurjchem-124 24 124 anticancer anticancer NOUN eurjchem-124 24 125     SPACE eurjchem-124 24 126 activities activity NOUN eurjchem-124 24 127     SPACE eurjchem-124 24 128 [ [ X eurjchem-124 24 129 27 27 NUM eurjchem-124 24 130 ] ] PUNCT eurjchem-124 24 131 . . PUNCT eurjchem-124 24 132     SPACE eurjchem-124 25 1 the the DET eurjchem-124 25 2     SPACE eurjchem-124 25 3 remarkable remarkable ADJ eurjchem-124 25 4     SPACE eurjchem-124 25 5 pharmacological pharmacological NOUN eurjchem-124 25 6     SPACE eurjchem-124 25 7 efficiency efficiency NOUN eurjchem-124 25 8     SPACE eurjchem-124 25 9 of of ADP eurjchem-124 25 10     SPACE eurjchem-124 25 11 the the DET eurjchem-124 25 12     SPACE eurjchem-124 25 13 compounds compound NOUN eurjchem-124 25 14     SPACE eurjchem-124 25 15 with with ADP eurjchem-124 25 16     SPACE eurjchem-124 25 17 thiophene thiophene NOUN eurjchem-124 25 18     SPACE eurjchem-124 25 19 nucleus nucleus NOUN eurjchem-124 25 20     SPACE eurjchem-124 25 21 in in ADP eurjchem-124 25 22     SPACE eurjchem-124 25 23 their their PRON eurjchem-124 25 24     SPACE eurjchem-124 25 25 structure structure NOUN eurjchem-124 25 26     SPACE eurjchem-124 25 27 such such ADJ eurjchem-124 25 28     SPACE eurjchem-124 25 29 as as ADP eurjchem-124 25 30 : : PUNCT eurjchem-124 25 31     SPACE eurjchem-124 25 32 duloxetine duloxetine NOUN eurjchem-124 25 33 , , PUNCT eurjchem-124 25 34     SPACE eurjchem-124 25 35 phethenylate phethenylate NOUN eurjchem-124 25 36     SPACE eurjchem-124 25 37 sodium sodium NOUN eurjchem-124 25 38 , , PUNCT eurjchem-124 25 39     SPACE eurjchem-124 25 40 pyrantel pyrantel NOUN eurjchem-124 25 41 , , PUNCT eurjchem-124 25 42     SPACE eurjchem-124 25 43 tiemonium tiemonium NOUN eurjchem-124 25 44     SPACE eurjchem-124 25 45 iodide iodide NOUN eurjchem-124 25 46 , , PUNCT eurjchem-124 25 47     SPACE eurjchem-124 25 48 chlorothen chlorothen ADV eurjchem-124 25 49 , , PUNCT eurjchem-124 25 50     SPACE eurjchem-124 25 51 carticaine carticaine VERB eurjchem-124 25 52 , , PUNCT eurjchem-124 25 53     SPACE eurjchem-124 25 54 thennaldine thennaldine VERB eurjchem-124 25 55 , , PUNCT eurjchem-124 25 56     SPACE eurjchem-124 25 57 tipepidine tipepidine NOUN eurjchem-124 25 58 , , PUNCT eurjchem-124 25 59     SPACE eurjchem-124 25 60 tenosal tenosal NOUN eurjchem-124 25 61     SPACE eurjchem-124 25 62 known know VERB eurjchem-124 25 63     SPACE eurjchem-124 25 64 for for ADP eurjchem-124 25 65     SPACE eurjchem-124 25 66 their their PRON eurjchem-124 25 67     SPACE eurjchem-124 25 68 antidepresant antidepresant ADJ eurjchem-124 25 69 , , PUNCT eurjchem-124 25 70     SPACE eurjchem-124 25 71 anticonvulsant anticonvulsant ADJ eurjchem-124 25 72 , , PUNCT eurjchem-124 25 73     SPACE eurjchem-124 25 74 anthelmintic anthelmintic NOUN eurjchem-124 25 75     SPACE eurjchem-124 25 76 ( ( PUNCT eurjchem-124 25 77 nematodes nematode NOUN eurjchem-124 25 78 ) ) PUNCT eurjchem-124 25 79 , , PUNCT eurjchem-124 25 80     SPACE eurjchem-124 25 81 antispasmoidic antispasmoidic ADJ eurjchem-124 25 82 , , PUNCT eurjchem-124 25 83     SPACE eurjchem-124 25 84 antihistaminic antihistaminic NOUN eurjchem-124 25 85 , , PUNCT eurjchem-124 25 86     SPACE eurjchem-124 25 87 anesthetic anesthetic NOUN eurjchem-124 25 88 , , PUNCT eurjchem-124 25 89     SPACE eurjchem-124 25 90 antipruritic antipruritic ADJ eurjchem-124 25 91 , , PUNCT eurjchem-124 25 92     SPACE eurjchem-124 25 93 antitussive antitussive NOUN eurjchem-124 25 94 , , PUNCT eurjchem-124 25 95     SPACE eurjchem-124 25 96 analgesic analgesic ADJ eurjchem-124 25 97     SPACE eurjchem-124 25 98 action action NOUN eurjchem-124 25 99     SPACE eurjchem-124 26 1 [ [ X eurjchem-124 26 2 28 28 NUM eurjchem-124 26 3 ] ] SYM eurjchem-124 26 4     SPACE eurjchem-124 26 5 and and CCONJ eurjchem-124 26 6     SPACE eurjchem-124 26 7 low low ADJ eurjchem-124 26 8     SPACE eurjchem-124 26 9 side side NOUN eurjchem-124 26 10     SPACE eurjchem-124 26 11 effects effect NOUN eurjchem-124 26 12 , , PUNCT eurjchem-124 26 13     SPACE eurjchem-124 26 14 and and CCONJ eurjchem-124 26 15     SPACE eurjchem-124 26 16 the the DET eurjchem-124 26 17     SPACE eurjchem-124 26 18 positive positive ADJ eurjchem-124 26 19     SPACE eurjchem-124 26 20 results result NOUN eurjchem-124 26 21     SPACE eurjchem-124 26 22 of of ADP eurjchem-124 26 23     SPACE eurjchem-124 26 24 the the DET eurjchem-124 26 25     SPACE eurjchem-124 26 26 previous previous ADJ eurjchem-124 26 27     SPACE eurjchem-124 26 28 synthesized synthesize VERB eurjchem-124 26 29     SPACE eurjchem-124 26 30 thioureides thioureide NOUN eurjchem-124 26 31 , , PUNCT eurjchem-124 26 32     SPACE eurjchem-124 26 33 led lead VERB eurjchem-124 26 34     SPACE eurjchem-124 26 35 us we PRON eurjchem-124 26 36     SPACE eurjchem-124 26 37 to to PART eurjchem-124 26 38     SPACE eurjchem-124 26 39 obtain obtain VERB eurjchem-124 26 40     SPACE eurjchem-124 26 41 new new ADJ eurjchem-124 26 42     SPACE eurjchem-124 26 43 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 26 44     SPACE eurjchem-124 26 45 derivatives derivative NOUN eurjchem-124 26 46 . . PUNCT eurjchem-124 26 47     SPACE eurjchem-124 27 1 the the DET eurjchem-124 27 2     SPACE eurjchem-124 27 3 importance importance NOUN eurjchem-124 27 4     SPACE eurjchem-124 27 5 of of ADP eurjchem-124 27 6     SPACE eurjchem-124 27 7 such such ADJ eurjchem-124 27 8     SPACE eurjchem-124 27 9 work work NOUN eurjchem-124 27 10     SPACE eurjchem-124 27 11 lies lie VERB eurjchem-124 27 12     SPACE eurjchem-124 27 13 in in ADP eurjchem-124 27 14     SPACE eurjchem-124 27 15 the the DET eurjchem-124 27 16     SPACE eurjchem-124 27 17 possibility possibility NOUN eurjchem-124 27 18     SPACE eurjchem-124 27 19 that that SCONJ eurjchem-124 27 20     SPACE eurjchem-124 27 21 the the DET eurjchem-124 27 22     SPACE eurjchem-124 27 23 next next ADJ eurjchem-124 27 24     SPACE eurjchem-124 27 25 generation generation NOUN eurjchem-124 27 26     SPACE eurjchem-124 27 27 of of ADP eurjchem-124 27 28     SPACE eurjchem-124 27 29 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 27 30     SPACE eurjchem-124 27 31 derivatives derivative NOUN eurjchem-124 27 32     SPACE eurjchem-124 27 33 might might AUX eurjchem-124 27 34     SPACE eurjchem-124 27 35 be be AUX eurjchem-124 27 36     SPACE eurjchem-124 27 37 more more ADV eurjchem-124 27 38     SPACE eurjchem-124 27 39 efficacious efficacious ADJ eurjchem-124 27 40     SPACE eurjchem-124 27 41 as as ADP eurjchem-124 27 42     SPACE eurjchem-124 27 43 antifungal antifungal NOUN eurjchem-124 27 44     SPACE eurjchem-124 27 45 and and CCONJ eurjchem-124 27 46     SPACE eurjchem-124 27 47 anticancer anticancer NOUN eurjchem-124 27 48     SPACE eurjchem-124 27 49 agents agent NOUN eurjchem-124 27 50 . . PUNCT eurjchem-124 27 51     SPACE eurjchem-124 28 1 however however ADV eurjchem-124 28 2 , , PUNCT eurjchem-124 28 3     SPACE eurjchem-124 28 4 a a DET eurjchem-124 28 5     SPACE eurjchem-124 28 6 thorough thorough ADJ eurjchem-124 28 7     SPACE eurjchem-124 28 8 investigation investigation NOUN eurjchem-124 28 9     SPACE eurjchem-124 28 10 relating relate VERB eurjchem-124 28 11     SPACE eurjchem-124 28 12 structure structure NOUN eurjchem-124 28 13     SPACE eurjchem-124 28 14 and and CCONJ eurjchem-124 28 15     SPACE eurjchem-124 28 16 activity activity NOUN eurjchem-124 28 17     SPACE eurjchem-124 28 18 of of ADP eurjchem-124 28 19     SPACE eurjchem-124 28 20 222 222 NUM eurjchem-124 28 21     SPACE eurjchem-124 28 22 saeed saeed PROPN eurjchem-124 28 23     SPACE eurjchem-124 28 24 et et PROPN eurjchem-124 28 25     SPACE eurjchem-124 28 26 al al PROPN eurjchem-124 28 27 . . PROPN eurjchem-124 28 28     SPACE eurjchem-124 28 29 / / SYM eurjchem-124 28 30     SPACE eurjchem-124 28 31 european european ADJ eurjchem-124 28 32     SPACE eurjchem-124 28 33 journal journal NOUN eurjchem-124 28 34     SPACE eurjchem-124 28 35 of of ADP eurjchem-124 28 36     SPACE eurjchem-124 28 37 chemistry chemistry NOUN eurjchem-124 28 38     SPACE eurjchem-124 28 39 1 1 NUM eurjchem-124 28 40     SPACE eurjchem-124 28 41 ( ( PUNCT eurjchem-124 28 42 3 3 NUM eurjchem-124 28 43 ) ) PUNCT eurjchem-124 28 44     SPACE eurjchem-124 28 45 ( ( PUNCT eurjchem-124 28 46 2010 2010 NUM eurjchem-124 28 47 ) ) PUNCT eurjchem-124 28 48     SPACE eurjchem-124 28 49 221­227 221­227 NUM eurjchem-124 28 50         SPACE eurjchem-124 28 51 thiourea thiourea NOUN eurjchem-124 28 52     SPACE eurjchem-124 28 53 derivatives derivative NOUN eurjchem-124 28 54     SPACE eurjchem-124 28 55 and and CCONJ eurjchem-124 28 56     SPACE eurjchem-124 28 57 their their PRON eurjchem-124 28 58     SPACE eurjchem-124 28 59 stability stability NOUN eurjchem-124 28 60     SPACE eurjchem-124 28 61 under under ADP eurjchem-124 28 62     SPACE eurjchem-124 28 63 biological biological ADJ eurjchem-124 28 64     SPACE eurjchem-124 28 65 conditions condition NOUN eurjchem-124 28 66     SPACE eurjchem-124 28 67 is be AUX eurjchem-124 28 68     SPACE eurjchem-124 28 69 required require VERB eurjchem-124 28 70 . . PUNCT eurjchem-124 28 71     SPACE eurjchem-124 28 72 in in ADP eurjchem-124 28 73     SPACE eurjchem-124 28 74 this this DET eurjchem-124 28 75     SPACE eurjchem-124 28 76 communication communication NOUN eurjchem-124 28 77 , , PUNCT eurjchem-124 28 78     SPACE eurjchem-124 28 79 we we PRON eurjchem-124 28 80     SPACE eurjchem-124 28 81 describe describe VERB eurjchem-124 28 82     SPACE eurjchem-124 28 83 the the DET eurjchem-124 28 84     SPACE eurjchem-124 28 85 synthesis synthesis NOUN eurjchem-124 28 86 , , PUNCT eurjchem-124 28 87     SPACE eurjchem-124 28 88 characterization characterization NOUN eurjchem-124 28 89 , , PUNCT eurjchem-124 28 90     SPACE eurjchem-124 28 91 crystal crystal NOUN eurjchem-124 28 92     SPACE eurjchem-124 28 93 structure structure NOUN eurjchem-124 28 94     SPACE eurjchem-124 28 95 and and CCONJ eurjchem-124 28 96     SPACE eurjchem-124 28 97 antifungal antifungal ADJ eurjchem-124 28 98     SPACE eurjchem-124 28 99 activity activity NOUN eurjchem-124 28 100     SPACE eurjchem-124 28 101 of of ADP eurjchem-124 28 102     SPACE eurjchem-124 28 103 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 28 104     SPACE eurjchem-124 28 105 derivatives derivative NOUN eurjchem-124 28 106 . . PUNCT eurjchem-124 28 107           SPACE eurjchem-124 29 1 2 2 NUM eurjchem-124 29 2 . . PUNCT eurjchem-124 29 3     SPACE eurjchem-124 29 4 experimental experimental ADJ eurjchem-124 29 5         SPACE eurjchem-124 29 6 2.1 2.1 NUM eurjchem-124 29 7 . . PUNCT eurjchem-124 29 8     SPACE eurjchem-124 29 9 chemicals chemical NOUN eurjchem-124 29 10     SPACE eurjchem-124 29 11 and and CCONJ eurjchem-124 29 12     SPACE eurjchem-124 29 13 instrumentation instrumentation NOUN eurjchem-124 29 14         SPACE eurjchem-124 29 15 thiophene‐2‐carbonyl thiophene‐2‐carbonyl NOUN eurjchem-124 29 16     SPACE eurjchem-124 29 17 chloride chloride NOUN eurjchem-124 29 18 , , PUNCT eurjchem-124 29 19     SPACE eurjchem-124 29 20 ammonium ammonium NOUN eurjchem-124 29 21     SPACE eurjchem-124 29 22 thiocyanate thiocyanate NOUN eurjchem-124 29 23 , , PUNCT eurjchem-124 29 24     SPACE eurjchem-124 29 25 diphenylamine diphenylamine NOUN eurjchem-124 29 26 , , PUNCT eurjchem-124 29 27     SPACE eurjchem-124 29 28 p‐chloroaniline p‐chloroaniline PUNCT eurjchem-124 29 29 , , PUNCT eurjchem-124 29 30     SPACE eurjchem-124 29 31 p‐nitroaniline p‐nitroaniline SYM eurjchem-124 29 32 , , PUNCT eurjchem-124 29 33     SPACE eurjchem-124 29 34 4‐methylaniline 4‐methylaniline NUM eurjchem-124 29 35 , , PUNCT eurjchem-124 29 36     SPACE eurjchem-124 29 37 1‐naphthylamine 1‐naphthylamine NUM eurjchem-124 29 38 , , PUNCT eurjchem-124 29 39     SPACE eurjchem-124 29 40 diethylamine diethylamine ADJ eurjchem-124 29 41 , , PUNCT eurjchem-124 29 42     SPACE eurjchem-124 29 43 5‐methoxy‐1,3‐benzothiazol‐2‐ 5‐methoxy‐1,3‐benzothiazol‐2‐ NUM eurjchem-124 29 44 amine amine NOUN eurjchem-124 29 45 , , PUNCT eurjchem-124 29 46     SPACE eurjchem-124 29 47 2‐amino‐5‐nitrothiazole 2‐amino‐5‐nitrothiazole NUM eurjchem-124 29 48 , , PUNCT eurjchem-124 29 49     SPACE eurjchem-124 29 50 dipropylamine dipropylamine NOUN eurjchem-124 29 51     SPACE eurjchem-124 29 52 of of ADP eurjchem-124 29 53     SPACE eurjchem-124 29 54 analytical analytical ADJ eurjchem-124 29 55     SPACE eurjchem-124 29 56 grade grade NOUN eurjchem-124 29 57     SPACE eurjchem-124 29 58 from from ADP eurjchem-124 29 59     SPACE eurjchem-124 29 60 merck merck NOUN eurjchem-124 29 61     SPACE eurjchem-124 29 62 and and CCONJ eurjchem-124 29 63     SPACE eurjchem-124 29 64 were be AUX eurjchem-124 29 65     SPACE eurjchem-124 29 66 used use VERB eurjchem-124 29 67     SPACE eurjchem-124 29 68 as as SCONJ eurjchem-124 29 69     SPACE eurjchem-124 29 70 received receive VERB eurjchem-124 29 71 . . PUNCT eurjchem-124 29 72     SPACE eurjchem-124 30 1 bis(dimethyl‐ bis(dimethyl‐ PROPN eurjchem-124 30 2 phosphinoylmethyl)‐amine phosphinoylmethyl)‐amine PROPN eurjchem-124 30 3     SPACE eurjchem-124 30 4 was be AUX eurjchem-124 30 5     SPACE eurjchem-124 30 6 prepared prepare VERB eurjchem-124 30 7     SPACE eurjchem-124 30 8 according accord VERB eurjchem-124 30 9     SPACE eurjchem-124 30 10 to to PART eurjchem-124 30 11     SPACE eurjchem-124 30 12 reference reference VERB eurjchem-124 30 13     SPACE eurjchem-124 30 14 [ [ X eurjchem-124 30 15 29 29 NUM eurjchem-124 30 16 ] ] PUNCT eurjchem-124 30 17 . . PUNCT eurjchem-124 30 18     SPACE eurjchem-124 30 19 solvents solvent NOUN eurjchem-124 30 20 ; ; PUNCT eurjchem-124 30 21     SPACE eurjchem-124 30 22 acetone acetone NOUN eurjchem-124 30 23 , , PUNCT eurjchem-124 30 24     SPACE eurjchem-124 30 25 ethyl ethyl PROPN eurjchem-124 30 26     SPACE eurjchem-124 30 27 acetate acetate NOUN eurjchem-124 30 28 , , PUNCT eurjchem-124 30 29     SPACE eurjchem-124 30 30 ethanol ethanol NOUN eurjchem-124 30 31 , , PUNCT eurjchem-124 30 32     SPACE eurjchem-124 30 33 methanol methanol NOUN eurjchem-124 30 34 , , PUNCT eurjchem-124 30 35     SPACE eurjchem-124 30 36 dichloromethane dichloromethane NOUN eurjchem-124 30 37     SPACE eurjchem-124 30 38 were be AUX eurjchem-124 30 39     SPACE eurjchem-124 30 40 obtained obtain VERB eurjchem-124 30 41     SPACE eurjchem-124 30 42 from from ADP eurjchem-124 30 43     SPACE eurjchem-124 30 44 riedel riedel NOUN eurjchem-124 30 45     SPACE eurjchem-124 30 46 and and CCONJ eurjchem-124 30 47     SPACE eurjchem-124 30 48 used use VERB eurjchem-124 30 49     SPACE eurjchem-124 30 50 without without ADP eurjchem-124 30 51     SPACE eurjchem-124 30 52 further further ADJ eurjchem-124 30 53     SPACE eurjchem-124 30 54 purification purification NOUN eurjchem-124 30 55 . . PUNCT eurjchem-124 30 56     SPACE eurjchem-124 31 1 the the DET eurjchem-124 31 2     SPACE eurjchem-124 31 3 1h 1h NUM eurjchem-124 31 4     SPACE eurjchem-124 31 5 and and CCONJ eurjchem-124 31 6     SPACE eurjchem-124 31 7 13c 13c NOUN eurjchem-124 31 8     SPACE eurjchem-124 31 9 nmr nmr NOUN eurjchem-124 31 10     SPACE eurjchem-124 31 11 spectra spectra NOUN eurjchem-124 31 12     SPACE eurjchem-124 31 13 were be AUX eurjchem-124 31 14     SPACE eurjchem-124 31 15 recorded record VERB eurjchem-124 31 16     SPACE eurjchem-124 31 17 in in ADP eurjchem-124 31 18     SPACE eurjchem-124 31 19 dmso‐d6 dmso‐d6 NOUN eurjchem-124 31 20     SPACE eurjchem-124 31 21 solvent solvent NOUN eurjchem-124 31 22     SPACE eurjchem-124 31 23 on on ADP eurjchem-124 31 24     SPACE eurjchem-124 31 25 a a DET eurjchem-124 31 26     SPACE eurjchem-124 31 27 bruker bruker NOUN eurjchem-124 31 28     SPACE eurjchem-124 31 29 300 300 NUM eurjchem-124 31 30     SPACE eurjchem-124 31 31 mhz mhz NOUN eurjchem-124 31 32     SPACE eurjchem-124 31 33 spectrophotometer spectrophotometer NOUN eurjchem-124 31 34     SPACE eurjchem-124 31 35 using use VERB eurjchem-124 31 36     SPACE eurjchem-124 31 37 tetramethylsilane tetramethylsilane NOUN eurjchem-124 31 38     SPACE eurjchem-124 31 39 as as ADP eurjchem-124 31 40     SPACE eurjchem-124 31 41 an an DET eurjchem-124 31 42     SPACE eurjchem-124 31 43 internal internal ADJ eurjchem-124 31 44     SPACE eurjchem-124 31 45 reference reference NOUN eurjchem-124 31 46 . . PUNCT eurjchem-124 31 47     SPACE eurjchem-124 32 1 the the DET eurjchem-124 32 2     SPACE eurjchem-124 32 3 apparent apparent ADJ eurjchem-124 32 4     SPACE eurjchem-124 32 5 resonance resonance NOUN eurjchem-124 32 6     SPACE eurjchem-124 32 7 multiplicity multiplicity NOUN eurjchem-124 32 8     SPACE eurjchem-124 32 9 is be AUX eurjchem-124 32 10     SPACE eurjchem-124 32 11 described describe VERB eurjchem-124 32 12     SPACE eurjchem-124 32 13 as as ADP eurjchem-124 32 14 : : PUNCT eurjchem-124 32 15     SPACE eurjchem-124 32 16 s s VERB eurjchem-124 32 17     SPACE eurjchem-124 32 18 ( ( PUNCT eurjchem-124 32 19 singlet singlet NOUN eurjchem-124 32 20 ) ) PUNCT eurjchem-124 32 21 , , PUNCT eurjchem-124 32 22     SPACE eurjchem-124 32 23 br br PROPN eurjchem-124 32 24     SPACE eurjchem-124 32 25 s s VERB eurjchem-124 32 26     SPACE eurjchem-124 32 27 ( ( PUNCT eurjchem-124 32 28 broad broad ADJ eurjchem-124 32 29     SPACE eurjchem-124 32 30 singlet singlet NOUN eurjchem-124 32 31 ) ) PUNCT eurjchem-124 32 32 , , PUNCT eurjchem-124 32 33     SPACE eurjchem-124 32 34 d d X eurjchem-124 32 35     SPACE eurjchem-124 32 36 ( ( PUNCT eurjchem-124 32 37 doublet doublet PROPN eurjchem-124 32 38 ) ) PUNCT eurjchem-124 32 39 , , PUNCT eurjchem-124 32 40     SPACE eurjchem-124 32 41 dd dd VERB eurjchem-124 32 42     SPACE eurjchem-124 32 43 ( ( PUNCT eurjchem-124 32 44 doublet doublet PROPN eurjchem-124 32 45     SPACE eurjchem-124 32 46 of of ADP eurjchem-124 32 47     SPACE eurjchem-124 32 48 doublets doublet NOUN eurjchem-124 32 49 ) ) PUNCT eurjchem-124 32 50 , , PUNCT eurjchem-124 32 51     SPACE eurjchem-124 32 52 t t PROPN eurjchem-124 32 53     SPACE eurjchem-124 32 54 ( ( PUNCT eurjchem-124 32 55 triplet triplet NOUN eurjchem-124 32 56 ) ) PUNCT eurjchem-124 32 57 , , PUNCT eurjchem-124 32 58     SPACE eurjchem-124 32 59 q q NOUN eurjchem-124 32 60     SPACE eurjchem-124 32 61 ( ( PUNCT eurjchem-124 32 62 quartet quartet NOUN eurjchem-124 32 63 ) ) PUNCT eurjchem-124 32 64     SPACE eurjchem-124 32 65 and and CCONJ eurjchem-124 32 66     SPACE eurjchem-124 32 67 m m VERB eurjchem-124 32 68     SPACE eurjchem-124 32 69 ( ( PUNCT eurjchem-124 32 70 multiplet multiplet NOUN eurjchem-124 32 71 ) ) PUNCT eurjchem-124 32 72 . . PUNCT eurjchem-124 32 73     SPACE eurjchem-124 32 74 melting melt VERB eurjchem-124 32 75     SPACE eurjchem-124 32 76 points point NOUN eurjchem-124 32 77     SPACE eurjchem-124 32 78 were be AUX eurjchem-124 32 79     SPACE eurjchem-124 32 80 recorded record VERB eurjchem-124 32 81     SPACE eurjchem-124 32 82 on on ADP eurjchem-124 32 83     SPACE eurjchem-124 32 84 electrothermal electrothermal ADJ eurjchem-124 32 85     SPACE eurjchem-124 32 86 ia9000 ia9000 ADJ eurjchem-124 32 87     SPACE eurjchem-124 32 88 series series NOUN eurjchem-124 32 89     SPACE eurjchem-124 32 90 digital digital PROPN eurjchem-124 32 91     SPACE eurjchem-124 32 92 melting melting NOUN eurjchem-124 32 93     SPACE eurjchem-124 32 94 point point NOUN eurjchem-124 32 95     SPACE eurjchem-124 32 96 apparatus apparatus NOUN eurjchem-124 32 97 . . PUNCT eurjchem-124 32 98         SPACE eurjchem-124 33 1 infrared infrare VERB eurjchem-124 33 2     SPACE eurjchem-124 33 3 measurements measurement NOUN eurjchem-124 33 4     SPACE eurjchem-124 33 5 were be AUX eurjchem-124 33 6     SPACE eurjchem-124 33 7 recorded record VERB eurjchem-124 33 8     SPACE eurjchem-124 33 9 in in ADP eurjchem-124 33 10     SPACE eurjchem-124 33 11 the the DET eurjchem-124 33 12     SPACE eurjchem-124 33 13 range range NOUN eurjchem-124 33 14     SPACE eurjchem-124 33 15 400‐ 400‐ NUM eurjchem-124 33 16     SPACE eurjchem-124 33 17 4000 4000 NUM eurjchem-124 33 18     SPACE eurjchem-124 33 19 cm‐1 cm‐1 NOUN eurjchem-124 33 20     SPACE eurjchem-124 33 21 on on ADP eurjchem-124 33 22     SPACE eurjchem-124 33 23 spectrum spectrum NOUN eurjchem-124 33 24     SPACE eurjchem-124 33 25 2000 2000 NUM eurjchem-124 33 26     SPACE eurjchem-124 33 27 by by ADP eurjchem-124 33 28     SPACE eurjchem-124 33 29 perkin perkin PROPN eurjchem-124 33 30     SPACE eurjchem-124 33 31 elmer elmer PROPN eurjchem-124 33 32 . . PUNCT eurjchem-124 33 33     SPACE eurjchem-124 34 1 elemental elemental ADJ eurjchem-124 34 2     SPACE eurjchem-124 34 3 analysis analysis NOUN eurjchem-124 34 4     SPACE eurjchem-124 34 5 was be AUX eurjchem-124 34 6     SPACE eurjchem-124 34 7 carried carry VERB eurjchem-124 34 8     SPACE eurjchem-124 34 9 out out ADP eurjchem-124 34 10     SPACE eurjchem-124 34 11 using use VERB eurjchem-124 34 12     SPACE eurjchem-124 34 13 perkin perkin PROPN eurjchem-124 34 14     SPACE eurjchem-124 34 15 elmer elmer NOUN eurjchem-124 34 16     SPACE eurjchem-124 34 17 chns chns PROPN eurjchem-124 34 18 / / SYM eurjchem-124 34 19 o o NOUN eurjchem-124 34 20     SPACE eurjchem-124 34 21 2400 2400 NUM eurjchem-124 34 22 . . PUNCT eurjchem-124 34 23     SPACE eurjchem-124 35 1 obtained obtain VERB eurjchem-124 35 2     SPACE eurjchem-124 35 3 results result NOUN eurjchem-124 35 4     SPACE eurjchem-124 35 5 were be AUX eurjchem-124 35 6     SPACE eurjchem-124 35 7 within within ADP eurjchem-124 35 8     SPACE eurjchem-124 35 9 0.4 0.4 NUM eurjchem-124 35 10     SPACE eurjchem-124 35 11 % % NOUN eurjchem-124 35 12     SPACE eurjchem-124 35 13 of of ADP eurjchem-124 35 14     SPACE eurjchem-124 35 15 the the DET eurjchem-124 35 16     SPACE eurjchem-124 35 17 theoretical theoretical ADJ eurjchem-124 35 18     SPACE eurjchem-124 35 19 values value NOUN eurjchem-124 35 20 . . PUNCT eurjchem-124 35 21     SPACE eurjchem-124 36 1 the the DET eurjchem-124 36 2     SPACE eurjchem-124 36 3 mass mass PROPN eurjchem-124 36 4     SPACE eurjchem-124 36 5 spectra spectra NOUN eurjchem-124 36 6     SPACE eurjchem-124 36 7 were be AUX eurjchem-124 36 8     SPACE eurjchem-124 36 9 run run VERB eurjchem-124 36 10     SPACE eurjchem-124 36 11 on on ADP eurjchem-124 36 12     SPACE eurjchem-124 36 13 a a DET eurjchem-124 36 14     SPACE eurjchem-124 36 15 finnigan finnigan NOUN eurjchem-124 36 16     SPACE eurjchem-124 36 17 tsq‐70 tsq‐70 NOUN eurjchem-124 36 18     SPACE eurjchem-124 36 19 spectrometer spectrometer NOUN eurjchem-124 36 20     SPACE eurjchem-124 36 21 ( ( PUNCT eurjchem-124 36 22 finnigan finnigan PROPN eurjchem-124 36 23 , , PUNCT eurjchem-124 36 24     SPACE eurjchem-124 36 25 usa usa PROPN eurjchem-124 36 26 ) ) PUNCT eurjchem-124 36 27     SPACE eurjchem-124 36 28 at at SCONJ eurjchem-124 36 29     SPACE eurjchem-124 36 30 70 70 NUM eurjchem-124 36 31     SPACE eurjchem-124 36 32 ev ev PROPN eurjchem-124 36 33 . . PROPN eurjchem-124 36 34     SPACE eurjchem-124 36 35 single single ADJ eurjchem-124 36 36     SPACE eurjchem-124 36 37 crystal crystal NOUN eurjchem-124 36 38     SPACE eurjchem-124 36 39 x‐ x‐ PROPN eurjchem-124 36 40 ray ray PROPN eurjchem-124 36 41     SPACE eurjchem-124 36 42 data datum NOUN eurjchem-124 36 43     SPACE eurjchem-124 36 44 were be AUX eurjchem-124 36 45     SPACE eurjchem-124 36 46 collected collect VERB eurjchem-124 36 47     SPACE eurjchem-124 36 48 on on ADP eurjchem-124 36 49     SPACE eurjchem-124 36 50 an an DET eurjchem-124 36 51     SPACE eurjchem-124 36 52 oxford oxford ADJ eurjchem-124 36 53     SPACE eurjchem-124 36 54 diffraction diffraction PROPN eurjchem-124 36 55     SPACE eurjchem-124 36 56 xcalibur xcalibur PROPN eurjchem-124 36 57     SPACE eurjchem-124 36 58 diffractometer diffractometer NOUN eurjchem-124 36 59     SPACE eurjchem-124 36 60 using use VERB eurjchem-124 36 61     SPACE eurjchem-124 36 62 monochromated monochromate VERB eurjchem-124 36 63     SPACE eurjchem-124 36 64 mo‐kα mo‐kα NUM eurjchem-124 36 65     SPACE eurjchem-124 36 66 radiation radiation NOUN eurjchem-124 36 67 . . PUNCT eurjchem-124 36 68     SPACE eurjchem-124 37 1 thin thin ADJ eurjchem-124 37 2     SPACE eurjchem-124 37 3 layer layer NOUN eurjchem-124 37 4     SPACE eurjchem-124 37 5 chromatography chromatography NOUN eurjchem-124 37 6     SPACE eurjchem-124 37 7 ( ( PUNCT eurjchem-124 37 8 tlc tlc NOUN eurjchem-124 37 9 ) ) PUNCT eurjchem-124 37 10     SPACE eurjchem-124 37 11 analysis analysis NOUN eurjchem-124 37 12     SPACE eurjchem-124 37 13 were be AUX eurjchem-124 37 14     SPACE eurjchem-124 37 15 carried carry VERB eurjchem-124 37 16     SPACE eurjchem-124 37 17 out out ADP eurjchem-124 37 18     SPACE eurjchem-124 37 19 on on ADP eurjchem-124 37 20     SPACE eurjchem-124 37 21 5 5 NUM eurjchem-124 37 22     SPACE eurjchem-124 37 23 × × NOUN eurjchem-124 37 24     SPACE eurjchem-124 37 25 20 20 NUM eurjchem-124 37 26     SPACE eurjchem-124 37 27 cm cm NOUN eurjchem-124 37 28     SPACE eurjchem-124 37 29 plates plate NOUN eurjchem-124 37 30     SPACE eurjchem-124 37 31 coated coat VERB eurjchem-124 37 32     SPACE eurjchem-124 37 33 with with ADP eurjchem-124 37 34     SPACE eurjchem-124 37 35 silica silica NOUN eurjchem-124 37 36     SPACE eurjchem-124 37 37 gel gel NOUN eurjchem-124 37 38     SPACE eurjchem-124 37 39 gf254 gf254 PROPN eurjchem-124 37 40     SPACE eurjchem-124 37 41 type type NOUN eurjchem-124 37 42     SPACE eurjchem-124 37 43 60 60 NUM eurjchem-124 37 44     SPACE eurjchem-124 37 45 ( ( PUNCT eurjchem-124 37 46 25‐250 25‐250 NOUN eurjchem-124 37 47     SPACE eurjchem-124 37 48 mesh mesh NOUN eurjchem-124 37 49 ) ) PUNCT eurjchem-124 37 50     SPACE eurjchem-124 37 51 using use VERB eurjchem-124 37 52     SPACE eurjchem-124 37 53 an an DET eurjchem-124 37 54     SPACE eurjchem-124 37 55 ethyl ethyl NOUN eurjchem-124 37 56     SPACE eurjchem-124 37 57 acetate‐petroleum acetate‐petroleum NOUN eurjchem-124 37 58     SPACE eurjchem-124 37 59 ether ether NOUN eurjchem-124 37 60     SPACE eurjchem-124 37 61 mixture mixture NOUN eurjchem-124 37 62     SPACE eurjchem-124 37 63 ( ( PUNCT eurjchem-124 37 64 1:2 1:2 NUM eurjchem-124 37 65 ) ) PUNCT eurjchem-124 37 66     SPACE eurjchem-124 37 67 as as ADP eurjchem-124 37 68     SPACE eurjchem-124 37 69 solvent solvent NOUN eurjchem-124 37 70 . . PUNCT eurjchem-124 37 71           SPACE eurjchem-124 38 1 2.2 2.2 NUM eurjchem-124 38 2 . . PUNCT eurjchem-124 38 3     SPACE eurjchem-124 39 1 synthesis synthesis NOUN eurjchem-124 39 2         SPACE eurjchem-124 39 3 2.2.1 2.2.1 NUM eurjchem-124 39 4     SPACE eurjchem-124 39 5 preparation preparation NOUN eurjchem-124 39 6     SPACE eurjchem-124 39 7 of of ADP eurjchem-124 39 8     SPACE eurjchem-124 39 9 compounds compound VERB eurjchem-124 39 10     SPACE eurjchem-124 39 11 1­12 1­12 NOUN eurjchem-124 39 12         SPACE eurjchem-124 39 13 all all DET eurjchem-124 39 14     SPACE eurjchem-124 39 15 the the DET eurjchem-124 39 16     SPACE eurjchem-124 39 17 chemicals chemical NOUN eurjchem-124 39 18     SPACE eurjchem-124 39 19 used use VERB eurjchem-124 39 20     SPACE eurjchem-124 39 21 for for ADP eurjchem-124 39 22     SPACE eurjchem-124 39 23 the the DET eurjchem-124 39 24     SPACE eurjchem-124 39 25 preparation preparation NOUN eurjchem-124 39 26     SPACE eurjchem-124 39 27 were be AUX eurjchem-124 39 28     SPACE eurjchem-124 39 29 of of ADP eurjchem-124 39 30     SPACE eurjchem-124 39 31 reagent reagent ADJ eurjchem-124 39 32     SPACE eurjchem-124 39 33 grade grade NOUN eurjchem-124 39 34     SPACE eurjchem-124 39 35 quality quality NOUN eurjchem-124 39 36 . . PUNCT eurjchem-124 39 37     SPACE eurjchem-124 40 1 the the DET eurjchem-124 40 2     SPACE eurjchem-124 40 3 ammonium ammonium NOUN eurjchem-124 40 4     SPACE eurjchem-124 40 5 thiocyanate thiocyanate NOUN eurjchem-124 40 6     SPACE eurjchem-124 40 7 was be AUX eurjchem-124 40 8     SPACE eurjchem-124 40 9 dried dry VERB eurjchem-124 40 10     SPACE eurjchem-124 40 11 by by ADP eurjchem-124 40 12     SPACE eurjchem-124 40 13 heating heating NOUN eurjchem-124 40 14     SPACE eurjchem-124 40 15 at at ADP eurjchem-124 40 16     SPACE eurjchem-124 40 17 100 100 NUM eurjchem-124 40 18     SPACE eurjchem-124 40 19 oc oc NOUN eurjchem-124 40 20     SPACE eurjchem-124 40 21 and and CCONJ eurjchem-124 40 22     SPACE eurjchem-124 40 23 the the DET eurjchem-124 40 24     SPACE eurjchem-124 40 25 acetone acetone NOUN eurjchem-124 40 26     SPACE eurjchem-124 40 27 using use VERB eurjchem-124 40 28     SPACE eurjchem-124 40 29 potassium potassium NOUN eurjchem-124 40 30     SPACE eurjchem-124 40 31 carbonate carbonate NOUN eurjchem-124 40 32 . . PUNCT eurjchem-124 40 33     SPACE eurjchem-124 40 34 a a DET eurjchem-124 40 35     SPACE eurjchem-124 40 36 solution solution NOUN eurjchem-124 40 37     SPACE eurjchem-124 40 38 of of ADP eurjchem-124 40 39     SPACE eurjchem-124 40 40 thiophene‐2‐carbonyl thiophene‐2‐carbonyl NOUN eurjchem-124 40 41     SPACE eurjchem-124 40 42 chloride chloride NOUN eurjchem-124 40 43     SPACE eurjchem-124 40 44 ( ( PUNCT eurjchem-124 40 45 0.01 0.01 NUM eurjchem-124 40 46     SPACE eurjchem-124 40 47 mol mol NOUN eurjchem-124 40 48 ) ) PUNCT eurjchem-124 40 49     SPACE eurjchem-124 40 50 in in ADP eurjchem-124 40 51     SPACE eurjchem-124 40 52 anhydrous anhydrous ADJ eurjchem-124 40 53     SPACE eurjchem-124 40 54 acetone acetone NOUN eurjchem-124 40 55     SPACE eurjchem-124 40 56 ( ( PUNCT eurjchem-124 40 57 80 80 NUM eurjchem-124 40 58     SPACE eurjchem-124 40 59 ml ml NOUN eurjchem-124 40 60 ) ) PUNCT eurjchem-124 40 61     SPACE eurjchem-124 40 62 and and CCONJ eurjchem-124 40 63     SPACE eurjchem-124 40 64 3 3 NUM eurjchem-124 40 65 % % NOUN eurjchem-124 40 66     SPACE eurjchem-124 40 67 tetrabutylammonium tetrabutylammonium NOUN eurjchem-124 40 68     SPACE eurjchem-124 40 69 bromide bromide NOUN eurjchem-124 40 70     SPACE eurjchem-124 40 71 ( ( PUNCT eurjchem-124 40 72 tbab tbab PROPN eurjchem-124 40 73 ) ) PUNCT eurjchem-124 40 74     SPACE eurjchem-124 40 75 in in ADP eurjchem-124 40 76     SPACE eurjchem-124 40 77 anhydrous anhydrous ADJ eurjchem-124 40 78     SPACE eurjchem-124 40 79 acetone acetone NOUN eurjchem-124 40 80     SPACE eurjchem-124 40 81 was be AUX eurjchem-124 40 82     SPACE eurjchem-124 40 83 added add VERB eurjchem-124 40 84     SPACE eurjchem-124 40 85 dropwise dropwise NOUN eurjchem-124 40 86     SPACE eurjchem-124 40 87 to to ADP eurjchem-124 40 88     SPACE eurjchem-124 40 89 a a DET eurjchem-124 40 90     SPACE eurjchem-124 40 91 suspension suspension NOUN eurjchem-124 40 92     SPACE eurjchem-124 40 93 of of ADP eurjchem-124 40 94     SPACE eurjchem-124 40 95 dry dry ADJ eurjchem-124 40 96     SPACE eurjchem-124 40 97 ammonium ammonium NOUN eurjchem-124 40 98     SPACE eurjchem-124 40 99 thiocyanate thiocyanate NOUN eurjchem-124 40 100     SPACE eurjchem-124 40 101 ( ( PUNCT eurjchem-124 40 102 0.01 0.01 NUM eurjchem-124 40 103     SPACE eurjchem-124 40 104 mol mol NOUN eurjchem-124 40 105 ) ) PUNCT eurjchem-124 40 106     SPACE eurjchem-124 40 107 in in ADP eurjchem-124 40 108     SPACE eurjchem-124 40 109 acetone acetone NOUN eurjchem-124 40 110     SPACE eurjchem-124 40 111 ( ( PUNCT eurjchem-124 40 112 50 50 NUM eurjchem-124 40 113     SPACE eurjchem-124 40 114 ml ml NOUN eurjchem-124 40 115 ) ) PUNCT eurjchem-124 40 116     SPACE eurjchem-124 40 117 and and CCONJ eurjchem-124 40 118     SPACE eurjchem-124 40 119 the the DET eurjchem-124 40 120     SPACE eurjchem-124 40 121 reaction reaction NOUN eurjchem-124 40 122     SPACE eurjchem-124 40 123 mixture mixture NOUN eurjchem-124 40 124     SPACE eurjchem-124 40 125 was be AUX eurjchem-124 40 126     SPACE eurjchem-124 40 127 refluxed refluxe VERB eurjchem-124 40 128     SPACE eurjchem-124 40 129 for for ADP eurjchem-124 40 130     SPACE eurjchem-124 40 131 45 45 NUM eurjchem-124 40 132     SPACE eurjchem-124 40 133 min min NOUN eurjchem-124 40 134     SPACE eurjchem-124 40 135 ( ( PUNCT eurjchem-124 40 136 scheme scheme NOUN eurjchem-124 40 137     SPACE eurjchem-124 40 138 1 1 NUM eurjchem-124 40 139 ) ) PUNCT eurjchem-124 40 140 . . PUNCT eurjchem-124 40 141     SPACE eurjchem-124 41 1 after after ADP eurjchem-124 41 2     SPACE eurjchem-124 41 3 cooling cool VERB eurjchem-124 41 4     SPACE eurjchem-124 41 5 to to PART eurjchem-124 41 6     SPACE eurjchem-124 41 7 room room NOUN eurjchem-124 41 8     SPACE eurjchem-124 41 9 temperature temperature NOUN eurjchem-124 41 10 , , PUNCT eurjchem-124 41 11     SPACE eurjchem-124 41 12 a a DET eurjchem-124 41 13     SPACE eurjchem-124 41 14 solution solution NOUN eurjchem-124 41 15     SPACE eurjchem-124 41 16 of of ADP eurjchem-124 41 17     SPACE eurjchem-124 41 18 primary primary ADJ eurjchem-124 41 19 / / SYM eurjchem-124 41 20 secondary secondary ADJ eurjchem-124 41 21     SPACE eurjchem-124 41 22 amine amine NOUN eurjchem-124 41 23     SPACE eurjchem-124 41 24 ( ( PUNCT eurjchem-124 41 25 0.01 0.01 NUM eurjchem-124 41 26     SPACE eurjchem-124 41 27 mol mol NOUN eurjchem-124 41 28 ) ) PUNCT eurjchem-124 41 29     SPACE eurjchem-124 41 30 in in ADP eurjchem-124 41 31     SPACE eurjchem-124 41 32 anhydrous anhydrous ADJ eurjchem-124 41 33     SPACE eurjchem-124 41 34 acetone acetone NOUN eurjchem-124 41 35     SPACE eurjchem-124 41 36 ( ( PUNCT eurjchem-124 41 37 25 25 NUM eurjchem-124 41 38     SPACE eurjchem-124 41 39 ml ml NOUN eurjchem-124 41 40 ) ) PUNCT eurjchem-124 41 41     SPACE eurjchem-124 41 42 was be AUX eurjchem-124 41 43     SPACE eurjchem-124 41 44 added add VERB eurjchem-124 41 45     SPACE eurjchem-124 41 46 and and CCONJ eurjchem-124 41 47     SPACE eurjchem-124 41 48 the the DET eurjchem-124 41 49     SPACE eurjchem-124 41 50 resulting result VERB eurjchem-124 41 51     SPACE eurjchem-124 41 52 mixture mixture NOUN eurjchem-124 41 53     SPACE eurjchem-124 41 54 refluxed refluxe VERB eurjchem-124 41 55     SPACE eurjchem-124 41 56 for for ADP eurjchem-124 41 57     SPACE eurjchem-124 41 58 2 2 NUM eurjchem-124 41 59     SPACE eurjchem-124 41 60 h. h. NOUN eurjchem-124 41 61     SPACE eurjchem-124 41 62 hydrochloric hydrochloric ADJ eurjchem-124 41 63     SPACE eurjchem-124 41 64 acid acid NOUN eurjchem-124 41 65     SPACE eurjchem-124 41 66 ( ( PUNCT eurjchem-124 41 67 0.1n 0.1n PROPN eurjchem-124 41 68 , , PUNCT eurjchem-124 41 69     SPACE eurjchem-124 41 70 400 400 NUM eurjchem-124 41 71     SPACE eurjchem-124 41 72 ml ml NOUN eurjchem-124 41 73 ) ) PUNCT eurjchem-124 41 74     SPACE eurjchem-124 41 75 was be AUX eurjchem-124 41 76     SPACE eurjchem-124 41 77 added add VERB eurjchem-124 41 78 , , PUNCT eurjchem-124 41 79     SPACE eurjchem-124 41 80 and and CCONJ eurjchem-124 41 81     SPACE eurjchem-124 41 82 the the DET eurjchem-124 41 83     SPACE eurjchem-124 41 84 solution solution NOUN eurjchem-124 41 85     SPACE eurjchem-124 41 86 was be AUX eurjchem-124 41 87     SPACE eurjchem-124 41 88 filtered filter VERB eurjchem-124 41 89 . . PUNCT eurjchem-124 41 90     SPACE eurjchem-124 42 1 the the DET eurjchem-124 42 2     SPACE eurjchem-124 42 3 solid solid ADJ eurjchem-124 42 4     SPACE eurjchem-124 42 5 product product NOUN eurjchem-124 42 6     SPACE eurjchem-124 42 7 was be AUX eurjchem-124 42 8     SPACE eurjchem-124 42 9 washed wash VERB eurjchem-124 42 10     SPACE eurjchem-124 42 11 with with ADP eurjchem-124 42 12     SPACE eurjchem-124 42 13 water water NOUN eurjchem-124 42 14     SPACE eurjchem-124 42 15 and and CCONJ eurjchem-124 42 16     SPACE eurjchem-124 42 17 purified purify VERB eurjchem-124 42 18     SPACE eurjchem-124 42 19 by by ADP eurjchem-124 42 20     SPACE eurjchem-124 42 21 re‐crystallization re‐crystallization NOUN eurjchem-124 42 22     SPACE eurjchem-124 42 23 from from ADP eurjchem-124 42 24     SPACE eurjchem-124 42 25 an an DET eurjchem-124 42 26     SPACE eurjchem-124 42 27 ethanol‐dichloromethane ethanol‐dichloromethane NOUN eurjchem-124 42 28     SPACE eurjchem-124 42 29 mixture mixture NOUN eurjchem-124 42 30     SPACE eurjchem-124 42 31 ( ( PUNCT eurjchem-124 42 32 1:2 1:2 NUM eurjchem-124 42 33 ) ) PUNCT eurjchem-124 42 34 . . PUNCT eurjchem-124 42 35         SPACE eurjchem-124 43 1 n­thiophene­n’,n’­bis(dimethyl­phosphinoylmethyl)thio­ n­thiophene­n’,n’­bis(dimethyl­phosphinoylmethyl)thio­ NOUN eurjchem-124 43 2     SPACE eurjchem-124 43 3 urea urea NOUN eurjchem-124 43 4     SPACE eurjchem-124 43 5 ( ( PUNCT eurjchem-124 43 6 1 1 NUM eurjchem-124 43 7 ): ): SYM eurjchem-124 43 8     SPACE eurjchem-124 43 9 white white ADJ eurjchem-124 43 10 . . PUNCT eurjchem-124 43 11     SPACE eurjchem-124 43 12 yield yield NOUN eurjchem-124 43 13 : : PUNCT eurjchem-124 43 14     SPACE eurjchem-124 43 15 95 95 NUM eurjchem-124 43 16 % % NOUN eurjchem-124 43 17 . . PUNCT eurjchem-124 43 18     SPACE eurjchem-124 44 1 m.p.:131‐132 m.p.:131‐132 VERB eurjchem-124 44 2     SPACE eurjchem-124 44 3 oc oc NOUN eurjchem-124 44 4 . . PUNCT eurjchem-124 44 5     SPACE eurjchem-124 44 6 ft‐ir ft‐ir NOUN eurjchem-124 44 7     SPACE eurjchem-124 44 8 ( ( PUNCT eurjchem-124 44 9 kbr kbr NOUN eurjchem-124 44 10     SPACE eurjchem-124 44 11 pellet pellet NOUN eurjchem-124 44 12 ) ) PUNCT eurjchem-124 44 13     SPACE eurjchem-124 44 14 in in ADP eurjchem-124 44 15     SPACE eurjchem-124 44 16 cm‐1 cm‐1 NOUN eurjchem-124 44 17 : : PUNCT eurjchem-124 44 18     SPACE eurjchem-124 44 19 3365 3365 NUM eurjchem-124 44 20 , , PUNCT eurjchem-124 44 21     SPACE eurjchem-124 44 22 3208 3208 NUM eurjchem-124 44 23     SPACE eurjchem-124 44 24 ( ( PUNCT eurjchem-124 44 25 n‐h n‐h NUM eurjchem-124 44 26 ) ) PUNCT eurjchem-124 44 27 , , PUNCT eurjchem-124 44 28     SPACE eurjchem-124 44 29 3065‐3046 3065‐3046 NUM eurjchem-124 44 30     SPACE eurjchem-124 44 31 ( ( PUNCT eurjchem-124 44 32 c‐h c‐h X eurjchem-124 44 33 ) ) PUNCT eurjchem-124 44 34 , , PUNCT eurjchem-124 44 35     SPACE eurjchem-124 44 36 1678 1678 NUM eurjchem-124 44 37     SPACE eurjchem-124 44 38 ( ( PUNCT eurjchem-124 44 39 c c NOUN eurjchem-124 44 40 = = NOUN eurjchem-124 44 41 o o NOUN eurjchem-124 44 42 ) ) PUNCT eurjchem-124 44 43 , , PUNCT eurjchem-124 44 44     SPACE eurjchem-124 44 45 1593 1593 NUM eurjchem-124 44 46     SPACE eurjchem-124 44 47 ( ( PUNCT eurjchem-124 44 48 aromatic aromatic ADJ eurjchem-124 44 49     SPACE eurjchem-124 44 50 c c NOUN eurjchem-124 44 51 = = SYM eurjchem-124 44 52 c c NOUN eurjchem-124 44 53 ) ) PUNCT eurjchem-124 44 54 , , PUNCT eurjchem-124 44 55     SPACE eurjchem-124 44 56 1308 1308 NUM eurjchem-124 44 57     SPACE eurjchem-124 44 58 ( ( PUNCT eurjchem-124 44 59 ch3p ch3p PROPN eurjchem-124 44 60 ) ) PUNCT eurjchem-124 44 61 , , PUNCT eurjchem-124 44 62     SPACE eurjchem-124 44 63 1292 1292 NUM eurjchem-124 44 64     SPACE eurjchem-124 44 65 ( ( PUNCT eurjchem-124 44 66 c c X eurjchem-124 44 67 = = SYM eurjchem-124 44 68 s s NOUN eurjchem-124 44 69 ) ) PUNCT eurjchem-124 44 70 , , PUNCT eurjchem-124 44 71     SPACE eurjchem-124 44 72 1162 1162 NUM eurjchem-124 44 73     SPACE eurjchem-124 44 74 ( ( PUNCT eurjchem-124 44 75 p p NOUN eurjchem-124 44 76 = = NOUN eurjchem-124 44 77 o o NOUN eurjchem-124 44 78 ) ) PUNCT eurjchem-124 44 79 . . PUNCT eurjchem-124 44 80     SPACE eurjchem-124 45 1 1h 1h NUM eurjchem-124 45 2     SPACE eurjchem-124 45 3 nmr nmr NOUN eurjchem-124 45 4     SPACE eurjchem-124 45 5 ( ( PUNCT eurjchem-124 45 6 300 300 NUM eurjchem-124 45 7     SPACE eurjchem-124 45 8 mhz mhz NOUN eurjchem-124 45 9 , , PUNCT eurjchem-124 45 10     SPACE eurjchem-124 45 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 45 12 ) ) PUNCT eurjchem-124 45 13     SPACE eurjchem-124 45 14 in in ADP eurjchem-124 45 15     SPACE eurjchem-124 45 16 δ δ PROPN eurjchem-124 45 17     SPACE eurjchem-124 45 18 ( ( PUNCT eurjchem-124 45 19 ppm ppm NOUN eurjchem-124 45 20 ) ) PUNCT eurjchem-124 45 21     SPACE eurjchem-124 45 22 and and CCONJ eurjchem-124 45 23     SPACE eurjchem-124 45 24 j j NOUN eurjchem-124 45 25     SPACE eurjchem-124 45 26 ( ( PUNCT eurjchem-124 45 27 hz hz PROPN eurjchem-124 45 28 ): ): PROPN eurjchem-124 45 29     SPACE eurjchem-124 45 30 11.92 11.92 NUM eurjchem-124 45 31     SPACE eurjchem-124 45 32 ( ( PUNCT eurjchem-124 45 33 1h 1h NUM eurjchem-124 45 34 , , PUNCT eurjchem-124 45 35     SPACE eurjchem-124 45 36 s s PROPN eurjchem-124 45 37 , , PUNCT eurjchem-124 45 38     SPACE eurjchem-124 45 39 conh conh NOUN eurjchem-124 45 40 ) ) PUNCT eurjchem-124 45 41 , , PUNCT eurjchem-124 45 42     SPACE eurjchem-124 45 43 8.21 8.21 NUM eurjchem-124 45 44     SPACE eurjchem-124 45 45 ( ( PUNCT eurjchem-124 45 46 2h 2h NUM eurjchem-124 45 47 , , PUNCT eurjchem-124 45 48     SPACE eurjchem-124 45 49 d d PROPN eurjchem-124 45 50 , , PUNCT eurjchem-124 45 51     SPACE eurjchem-124 45 52 j j PROPN eurjchem-124 45 53     SPACE eurjchem-124 45 54 = = NOUN eurjchem-124 45 55     SPACE eurjchem-124 45 56 9.1 9.1 NUM eurjchem-124 45 57     SPACE eurjchem-124 45 58 hz hz VERB eurjchem-124 45 59 , , PUNCT eurjchem-124 45 60     SPACE eurjchem-124 45 61 ar ar NOUN eurjchem-124 45 62     SPACE eurjchem-124 45 63 h h NOUN eurjchem-124 45 64 ) ) PUNCT eurjchem-124 45 65 , , PUNCT eurjchem-124 45 66     SPACE eurjchem-124 45 67 7.62 7.62 NUM eurjchem-124 45 68     SPACE eurjchem-124 45 69 ( ( PUNCT eurjchem-124 45 70 2h 2h NUM eurjchem-124 45 71 , , PUNCT eurjchem-124 45 72     SPACE eurjchem-124 45 73 d d PROPN eurjchem-124 45 74 , , PUNCT eurjchem-124 45 75           SPACE eurjchem-124 45 76 j j PROPN eurjchem-124 45 77     SPACE eurjchem-124 45 78 = = NOUN eurjchem-124 45 79     SPACE eurjchem-124 45 80 6.5 6.5 NUM eurjchem-124 45 81     SPACE eurjchem-124 45 82 hz hz VERB eurjchem-124 45 83 , , PUNCT eurjchem-124 45 84     SPACE eurjchem-124 45 85 ar ar NOUN eurjchem-124 45 86     SPACE eurjchem-124 45 87 h h NOUN eurjchem-124 45 88 ) ) PUNCT eurjchem-124 45 89 , , PUNCT eurjchem-124 45 90     SPACE eurjchem-124 45 91 8.28 8.28 NUM eurjchem-124 45 92     SPACE eurjchem-124 45 93 ( ( PUNCT eurjchem-124 45 94 1h 1h NUM eurjchem-124 45 95 , , PUNCT eurjchem-124 45 96     SPACE eurjchem-124 45 97 dd dd NOUN eurjchem-124 45 98 , , PUNCT eurjchem-124 45 99     SPACE eurjchem-124 45 100 j1 j1 PROPN eurjchem-124 45 101     SPACE eurjchem-124 45 102 = = NOUN eurjchem-124 45 103     SPACE eurjchem-124 45 104 7.8 7.8 NUM eurjchem-124 45 105     SPACE eurjchem-124 45 106 hz hz VERB eurjchem-124 45 107 , , PUNCT eurjchem-124 45 108     SPACE eurjchem-124 45 109 j2 j2 PROPN eurjchem-124 45 110     SPACE eurjchem-124 45 111 = = NOUN eurjchem-124 45 112     SPACE eurjchem-124 45 113 8.4 8.4 NUM eurjchem-124 45 114     SPACE eurjchem-124 45 115 hz hz VERB eurjchem-124 45 116 , , PUNCT eurjchem-124 45 117     SPACE eurjchem-124 45 118 thiophene thiophene NOUN eurjchem-124 45 119     SPACE eurjchem-124 45 120 ch ch NOUN eurjchem-124 45 121 ) ) PUNCT eurjchem-124 45 122 , , PUNCT eurjchem-124 45 123     SPACE eurjchem-124 45 124 8.02 8.02 NUM eurjchem-124 45 125     SPACE eurjchem-124 45 126 ( ( PUNCT eurjchem-124 45 127 1h 1h NUM eurjchem-124 45 128 , , PUNCT eurjchem-124 45 129     SPACE eurjchem-124 45 130 dd dd VERB eurjchem-124 45 131 , , PUNCT eurjchem-124 45 132     SPACE eurjchem-124 45 133 j1 j1 PROPN eurjchem-124 45 134     SPACE eurjchem-124 46 1 = = NOUN eurjchem-124 46 2     SPACE eurjchem-124 46 3 7.5 7.5 NUM eurjchem-124 46 4     SPACE eurjchem-124 46 5 hz hz VERB eurjchem-124 46 6 , , PUNCT eurjchem-124 46 7     SPACE eurjchem-124 46 8 j2 j2 PROPN eurjchem-124 46 9     SPACE eurjchem-124 46 10 = = NOUN eurjchem-124 46 11     SPACE eurjchem-124 46 12 8.2 8.2 NUM eurjchem-124 46 13     SPACE eurjchem-124 46 14 hz hz VERB eurjchem-124 46 15 , , PUNCT eurjchem-124 46 16     SPACE eurjchem-124 46 17 thiophene thiophene NOUN eurjchem-124 46 18     SPACE eurjchem-124 46 19 ch),7.21 ch),7.21 NOUN eurjchem-124 46 20     SPACE eurjchem-124 46 21 ( ( PUNCT eurjchem-124 46 22 1h 1h NUM eurjchem-124 46 23 , , PUNCT eurjchem-124 46 24     SPACE eurjchem-124 46 25 dd dd VERB eurjchem-124 46 26 , , PUNCT eurjchem-124 46 27     SPACE eurjchem-124 46 28 j1 j1 PROPN eurjchem-124 46 29     SPACE eurjchem-124 46 30 = = NOUN eurjchem-124 46 31     SPACE eurjchem-124 46 32 6.7 6.7 NUM eurjchem-124 46 33     SPACE eurjchem-124 46 34 hz hz VERB eurjchem-124 46 35 , , PUNCT eurjchem-124 46 36     SPACE eurjchem-124 46 37 j2 j2 PROPN eurjchem-124 46 38     SPACE eurjchem-124 46 39 = = NOUN eurjchem-124 46 40     SPACE eurjchem-124 46 41 9.0 9.0 NUM eurjchem-124 46 42     SPACE eurjchem-124 46 43 hz hz VERB eurjchem-124 46 44 , , PUNCT eurjchem-124 46 45     SPACE eurjchem-124 46 46 thiophene thiophene NOUN eurjchem-124 46 47     SPACE eurjchem-124 46 48 ch ch NOUN eurjchem-124 46 49 ) ) PUNCT eurjchem-124 46 50 , , PUNCT eurjchem-124 46 51     SPACE eurjchem-124 46 52 2.43 2.43 NUM eurjchem-124 46 53     SPACE eurjchem-124 46 54 ( ( PUNCT eurjchem-124 46 55 4h 4h NUM eurjchem-124 46 56 , , PUNCT eurjchem-124 46 57 s s X eurjchem-124 46 58 , , PUNCT eurjchem-124 46 59                         SPACE eurjchem-124 46 60 ‐nch2 ‐nch2 NOUN eurjchem-124 46 61 ) ) PUNCT eurjchem-124 46 62 , , PUNCT eurjchem-124 46 63     SPACE eurjchem-124 46 64 0.98 0.98 NUM eurjchem-124 46 65     SPACE eurjchem-124 46 66 ( ( PUNCT eurjchem-124 46 67 12h 12h NUM eurjchem-124 46 68 , , PUNCT eurjchem-124 46 69     SPACE eurjchem-124 46 70 s s PROPN eurjchem-124 46 71 , , PUNCT eurjchem-124 46 72     SPACE eurjchem-124 46 73 ‐ch3 ‐ch3 ADJ eurjchem-124 46 74 ) ) PUNCT eurjchem-124 46 75 . . PUNCT eurjchem-124 46 76     SPACE eurjchem-124 47 1 13c 13c NOUN eurjchem-124 47 2     SPACE eurjchem-124 47 3 nmr nmr NOUN eurjchem-124 47 4     SPACE eurjchem-124 47 5 ( ( PUNCT eurjchem-124 47 6 300 300 NUM eurjchem-124 47 7     SPACE eurjchem-124 47 8 mhz mhz NOUN eurjchem-124 47 9 , , PUNCT eurjchem-124 47 10     SPACE eurjchem-124 47 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 47 12 ) ) PUNCT eurjchem-124 47 13     SPACE eurjchem-124 47 14 in in ADP eurjchem-124 47 15     SPACE eurjchem-124 47 16 δ δ PROPN eurjchem-124 47 17     SPACE eurjchem-124 47 18 ( ( PUNCT eurjchem-124 47 19 ppm ppm PROPN eurjchem-124 47 20 ): ): PUNCT eurjchem-124 47 21     SPACE eurjchem-124 47 22 178.0 178.0 NUM eurjchem-124 47 23     SPACE eurjchem-124 47 24 ( ( PUNCT eurjchem-124 47 25 c c PROPN eurjchem-124 47 26 = = SYM eurjchem-124 47 27 s s NOUN eurjchem-124 47 28 ) ) PUNCT eurjchem-124 47 29 , , PUNCT eurjchem-124 47 30     SPACE eurjchem-124 47 31 162.2 162.2 NUM eurjchem-124 47 32     SPACE eurjchem-124 47 33 ( ( PUNCT eurjchem-124 47 34 c c NOUN eurjchem-124 47 35 = = NOUN eurjchem-124 47 36 o o NOUN eurjchem-124 47 37 ) ) PUNCT eurjchem-124 47 38 , , PUNCT eurjchem-124 47 39     SPACE eurjchem-124 47 40 141.4 141.4 NUM eurjchem-124 47 41     SPACE eurjchem-124 47 42 ( ( PUNCT eurjchem-124 47 43 c c NOUN eurjchem-124 47 44 ) ) PUNCT eurjchem-124 47 45 , , PUNCT eurjchem-124 47 46     SPACE eurjchem-124 47 47 136.2 136.2 NUM eurjchem-124 47 48     SPACE eurjchem-124 47 49 ( ( PUNCT eurjchem-124 47 50 c c NOUN eurjchem-124 47 51 ) ) PUNCT eurjchem-124 47 52 , , PUNCT eurjchem-124 47 53     SPACE eurjchem-124 47 54 135.7 135.7 NUM eurjchem-124 47 55     SPACE eurjchem-124 47 56 ( ( PUNCT eurjchem-124 47 57 c c NOUN eurjchem-124 47 58 ) ) PUNCT eurjchem-124 47 59 , , PUNCT eurjchem-124 47 60     SPACE eurjchem-124 47 61 132.0 132.0 NUM eurjchem-124 47 62     SPACE eurjchem-124 47 63 ( ( PUNCT eurjchem-124 47 64 c c NOUN eurjchem-124 47 65 ) ) PUNCT eurjchem-124 47 66 , , PUNCT eurjchem-124 47 67     SPACE eurjchem-124 47 68 61.1 61.1 NUM eurjchem-124 47 69     SPACE eurjchem-124 47 70 ( ( PUNCT eurjchem-124 47 71 2c 2c NOUN eurjchem-124 47 72 ) ) PUNCT eurjchem-124 47 73 , , PUNCT eurjchem-124 47 74     SPACE eurjchem-124 47 75 21.2 21.2 NUM eurjchem-124 47 76     SPACE eurjchem-124 47 77 ( ( PUNCT eurjchem-124 47 78 4c 4c NOUN eurjchem-124 47 79 ) ) PUNCT eurjchem-124 47 80 . . PUNCT eurjchem-124 47 81     SPACE eurjchem-124 48 1 ei ei PROPN eurjchem-124 48 2     SPACE eurjchem-124 48 3 ms ms PROPN eurjchem-124 48 4 , , PUNCT eurjchem-124 48 5     SPACE eurjchem-124 48 6 m m PROPN eurjchem-124 48 7 / / PROPN eurjchem-124 49 1 z z NOUN eurjchem-124 49 2     SPACE eurjchem-124 49 3 ( ( PUNCT eurjchem-124 49 4 % % INTJ eurjchem-124 49 5 ): ): PUNCT eurjchem-124 49 6     SPACE eurjchem-124 49 7 366 366 NUM eurjchem-124 49 8 . . PUNCT eurjchem-124 49 9     SPACE eurjchem-124 50 1 anal anal ADJ eurjchem-124 50 2 . . PUNCT eurjchem-124 50 3     SPACE eurjchem-124 50 4 calcd calcd NOUN eurjchem-124 50 5 . . PUNCT eurjchem-124 50 6     SPACE eurjchem-124 50 7 for for ADP eurjchem-124 50 8     SPACE eurjchem-124 50 9 c12h20n3o3p2s2 c12h20n3o3p2s2 NOUN eurjchem-124 50 10 : : PUNCT eurjchem-124 50 11     SPACE eurjchem-124 50 12 c c X eurjchem-124 50 13 , , PUNCT eurjchem-124 50 14     SPACE eurjchem-124 50 15 39.34 39.34 NUM eurjchem-124 50 16 ; ; PUNCT eurjchem-124 50 17     SPACE eurjchem-124 50 18 h h NOUN eurjchem-124 50 19 , , PUNCT eurjchem-124 50 20     SPACE eurjchem-124 50 21 5.50 5.50 NUM eurjchem-124 50 22 ; ; PUNCT eurjchem-124 50 23     SPACE eurjchem-124 50 24 n n CCONJ eurjchem-124 50 25 , , PUNCT eurjchem-124 50 26     SPACE eurjchem-124 50 27 7.65 7.65 NUM eurjchem-124 50 28 ; ; PUNCT eurjchem-124 50 29     SPACE eurjchem-124 50 30 s,17.50 s,17.50 PROPN eurjchem-124 50 31 . . PUNCT eurjchem-124 50 32     SPACE eurjchem-124 50 33 found find VERB eurjchem-124 50 34 : : PUNCT eurjchem-124 50 35     SPACE eurjchem-124 50 36 c c X eurjchem-124 50 37 , , PUNCT eurjchem-124 50 38     SPACE eurjchem-124 50 39 39.38 39.38 NUM eurjchem-124 50 40 ; ; PUNCT eurjchem-124 50 41     SPACE eurjchem-124 50 42 h h NOUN eurjchem-124 50 43 , , PUNCT eurjchem-124 50 44     SPACE eurjchem-124 50 45 5.55 5.55 NUM eurjchem-124 50 46 ; ; PUNCT eurjchem-124 50 47     SPACE eurjchem-124 50 48 n n CCONJ eurjchem-124 50 49 , , PUNCT eurjchem-124 50 50     SPACE eurjchem-124 50 51 7.63 7.63 NUM eurjchem-124 50 52 ; ; PUNCT eurjchem-124 50 53     SPACE eurjchem-124 50 54 s s PROPN eurjchem-124 50 55 , , PUNCT eurjchem-124 50 56     SPACE eurjchem-124 50 57 17.48 17.48 NUM eurjchem-124 50 58 . . PUNCT eurjchem-124 50 59           SPACE eurjchem-124 51 1 n­[(4­nitro­1h­imidazol­2­yl)carbamothioyl n­[(4­nitro­1h­imidazol­2­yl)carbamothioyl ADJ eurjchem-124 51 2 ] ] X eurjchem-124 51 3     SPACE eurjchem-124 51 4 thiophene­2­ thiophene­2­ NUM eurjchem-124 51 5 carboxamide carboxamide NOUN eurjchem-124 51 6     SPACE eurjchem-124 51 7 ( ( PUNCT eurjchem-124 51 8 2 2 NUM eurjchem-124 51 9 ): ): SYM eurjchem-124 51 10     SPACE eurjchem-124 51 11 light light ADJ eurjchem-124 51 12     SPACE eurjchem-124 51 13 yellow yellow ADJ eurjchem-124 51 14     SPACE eurjchem-124 51 15 solid solid ADJ eurjchem-124 51 16 . . PUNCT eurjchem-124 51 17     SPACE eurjchem-124 51 18 yield yield NOUN eurjchem-124 51 19 : : PUNCT eurjchem-124 51 20     SPACE eurjchem-124 51 21 88 88 NUM eurjchem-124 51 22 % % NOUN eurjchem-124 51 23 . . PUNCT eurjchem-124 51 24     SPACE eurjchem-124 52 1 m.p m.p PROPN eurjchem-124 52 2 . . PROPN eurjchem-124 52 3 : : PUNCT eurjchem-124 52 4     SPACE eurjchem-124 52 5 174‐175 174‐175 NUM eurjchem-124 52 6     SPACE eurjchem-124 52 7 oc oc PROPN eurjchem-124 52 8 . . PUNCT eurjchem-124 52 9     SPACE eurjchem-124 52 10 ft‐ir ft‐ir NOUN eurjchem-124 52 11     SPACE eurjchem-124 52 12 ( ( PUNCT eurjchem-124 52 13 kbr kbr NOUN eurjchem-124 52 14     SPACE eurjchem-124 52 15 pellet pellet NOUN eurjchem-124 52 16 ) ) PUNCT eurjchem-124 52 17     SPACE eurjchem-124 52 18 in in ADP eurjchem-124 52 19     SPACE eurjchem-124 52 20 cm‐1 cm‐1 NOUN eurjchem-124 52 21 : : PUNCT eurjchem-124 52 22     SPACE eurjchem-124 52 23 3263 3263 NUM eurjchem-124 52 24 , , PUNCT eurjchem-124 52 25     SPACE eurjchem-124 52 26 3209 3209 NUM eurjchem-124 52 27     SPACE eurjchem-124 52 28 ( ( PUNCT eurjchem-124 52 29 n‐h n‐h NOUN eurjchem-124 52 30 ) ) PUNCT eurjchem-124 52 31 , , PUNCT eurjchem-124 52 32     SPACE eurjchem-124 52 33 3063‐3031 3063‐3031 NUM eurjchem-124 52 34     SPACE eurjchem-124 52 35 ( ( PUNCT eurjchem-124 52 36 c‐ c‐ NOUN eurjchem-124 52 37 h h NOUN eurjchem-124 52 38 ) ) PUNCT eurjchem-124 52 39 , , PUNCT eurjchem-124 52 40     SPACE eurjchem-124 52 41 1675 1675 NUM eurjchem-124 52 42     SPACE eurjchem-124 52 43 ( ( PUNCT eurjchem-124 52 44 c c NOUN eurjchem-124 52 45 = = NOUN eurjchem-124 52 46 o o NOUN eurjchem-124 52 47 ) ) PUNCT eurjchem-124 52 48 , , PUNCT eurjchem-124 52 49     SPACE eurjchem-124 52 50 1593 1593 NUM eurjchem-124 52 51     SPACE eurjchem-124 52 52 ( ( PUNCT eurjchem-124 52 53 aromatic aromatic ADJ eurjchem-124 52 54     SPACE eurjchem-124 52 55 c c NOUN eurjchem-124 52 56 = = SYM eurjchem-124 52 57 c c NOUN eurjchem-124 52 58 ) ) PUNCT eurjchem-124 52 59 , , PUNCT eurjchem-124 52 60     SPACE eurjchem-124 52 61 1234 1234 NUM eurjchem-124 52 62     SPACE eurjchem-124 52 63 ( ( PUNCT eurjchem-124 52 64 c c PROPN eurjchem-124 52 65 = = SYM eurjchem-124 52 66 s s NOUN eurjchem-124 52 67 ) ) PUNCT eurjchem-124 52 68 . . PUNCT eurjchem-124 52 69     SPACE eurjchem-124 53 1 1h 1h NUM eurjchem-124 53 2     SPACE eurjchem-124 53 3 nmr nmr NOUN eurjchem-124 53 4     SPACE eurjchem-124 53 5 ( ( PUNCT eurjchem-124 53 6 300 300 NUM eurjchem-124 53 7     SPACE eurjchem-124 53 8 mhz mhz NOUN eurjchem-124 53 9 , , PUNCT eurjchem-124 53 10     SPACE eurjchem-124 53 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 53 12 ) ) PUNCT eurjchem-124 53 13     SPACE eurjchem-124 53 14 in in ADP eurjchem-124 53 15     SPACE eurjchem-124 53 16 δ δ PROPN eurjchem-124 53 17     SPACE eurjchem-124 53 18 ( ( PUNCT eurjchem-124 53 19 ppm ppm NOUN eurjchem-124 53 20 ) ) PUNCT eurjchem-124 53 21     SPACE eurjchem-124 53 22 and and CCONJ eurjchem-124 53 23     SPACE eurjchem-124 53 24 j j NOUN eurjchem-124 53 25     SPACE eurjchem-124 53 26 ( ( PUNCT eurjchem-124 53 27 hz hz PROPN eurjchem-124 53 28 ): ): PROPN eurjchem-124 53 29     SPACE eurjchem-124 53 30 12.65 12.65 NUM eurjchem-124 53 31     SPACE eurjchem-124 53 32 ( ( PUNCT eurjchem-124 53 33 1h 1h NUM eurjchem-124 53 34 , , PUNCT eurjchem-124 53 35     SPACE eurjchem-124 53 36 s s PROPN eurjchem-124 53 37 , , PUNCT eurjchem-124 53 38     SPACE eurjchem-124 53 39 csnh csnh PROPN eurjchem-124 53 40 ) ) PUNCT eurjchem-124 53 41 , , PUNCT eurjchem-124 53 42     SPACE eurjchem-124 53 43 11.33 11.33 NUM eurjchem-124 53 44     SPACE eurjchem-124 53 45 ( ( PUNCT eurjchem-124 53 46 1h 1h NUM eurjchem-124 53 47 , , PUNCT eurjchem-124 53 48     SPACE eurjchem-124 53 49 s s PROPN eurjchem-124 53 50 , , PUNCT eurjchem-124 53 51     SPACE eurjchem-124 53 52 conh conh NOUN eurjchem-124 53 53 ) ) PUNCT eurjchem-124 53 54 , , PUNCT eurjchem-124 53 55     SPACE eurjchem-124 53 56 8.2 8.2 NUM eurjchem-124 53 57     SPACE eurjchem-124 53 58 ( ( PUNCT eurjchem-124 53 59 1h 1h NUM eurjchem-124 53 60 , , PUNCT eurjchem-124 53 61     SPACE eurjchem-124 53 62 dd dd VERB eurjchem-124 53 63 , , PUNCT eurjchem-124 53 64     SPACE eurjchem-124 53 65 j1 j1 PROPN eurjchem-124 53 66     SPACE eurjchem-124 53 67 = = NOUN eurjchem-124 53 68     SPACE eurjchem-124 53 69 7.2 7.2 NUM eurjchem-124 53 70     SPACE eurjchem-124 53 71 hz hz VERB eurjchem-124 53 72 , , PUNCT eurjchem-124 53 73     SPACE eurjchem-124 53 74 j2 j2 PROPN eurjchem-124 53 75     SPACE eurjchem-124 53 76 = = NOUN eurjchem-124 53 77     SPACE eurjchem-124 53 78 8.1 8.1 NUM eurjchem-124 53 79     SPACE eurjchem-124 53 80 hz hz VERB eurjchem-124 53 81 , , PUNCT eurjchem-124 53 82     SPACE eurjchem-124 53 83 thiophene thiophene NOUN eurjchem-124 53 84     SPACE eurjchem-124 53 85 ch ch NOUN eurjchem-124 53 86 ) ) PUNCT eurjchem-124 53 87 , , PUNCT eurjchem-124 53 88     SPACE eurjchem-124 53 89 8.05 8.05 NUM eurjchem-124 53 90     SPACE eurjchem-124 53 91 ( ( PUNCT eurjchem-124 53 92 1h 1h NUM eurjchem-124 53 93 , , PUNCT eurjchem-124 53 94     SPACE eurjchem-124 53 95 dd dd NOUN eurjchem-124 53 96 , , PUNCT eurjchem-124 53 97     SPACE eurjchem-124 53 98 j1 j1 PROPN eurjchem-124 53 99     SPACE eurjchem-124 53 100 = = NOUN eurjchem-124 53 101     SPACE eurjchem-124 53 102 7.5 7.5 NUM eurjchem-124 53 103     SPACE eurjchem-124 53 104 hz hz VERB eurjchem-124 53 105 , , PUNCT eurjchem-124 53 106     SPACE eurjchem-124 53 107 j2 j2 PROPN eurjchem-124 53 108     SPACE eurjchem-124 53 109 = = NOUN eurjchem-124 53 110     SPACE eurjchem-124 53 111 8.2 8.2 NUM eurjchem-124 53 112     SPACE eurjchem-124 53 113 hz hz VERB eurjchem-124 53 114 , , PUNCT eurjchem-124 53 115     SPACE eurjchem-124 53 116 thiophene thiophene NOUN eurjchem-124 53 117     SPACE eurjchem-124 53 118 ch ch NOUN eurjchem-124 53 119 ) ) PUNCT eurjchem-124 53 120 , , PUNCT eurjchem-124 53 121     SPACE eurjchem-124 53 122 8.01 8.01 NUM eurjchem-124 53 123     SPACE eurjchem-124 53 124 ( ( PUNCT eurjchem-124 53 125 2h 2h NUM eurjchem-124 53 126 , , PUNCT eurjchem-124 53 127     SPACE eurjchem-124 53 128 d d PROPN eurjchem-124 53 129 , , PUNCT eurjchem-124 53 130     SPACE eurjchem-124 53 131 j j PROPN eurjchem-124 53 132     SPACE eurjchem-124 53 133 = = NOUN eurjchem-124 53 134     SPACE eurjchem-124 53 135 8.2 8.2 NUM eurjchem-124 53 136     SPACE eurjchem-124 53 137 hz hz NOUN eurjchem-124 53 138 ) ) PUNCT eurjchem-124 53 139 , , PUNCT eurjchem-124 53 140     SPACE eurjchem-124 53 141 7.65 7.65 NUM eurjchem-124 53 142     SPACE eurjchem-124 53 143 ( ( PUNCT eurjchem-124 53 144 2h 2h NUM eurjchem-124 53 145 , , PUNCT eurjchem-124 53 146     SPACE eurjchem-124 53 147 d d PROPN eurjchem-124 53 148 , , PUNCT eurjchem-124 53 149     SPACE eurjchem-124 53 150 j j PROPN eurjchem-124 53 151     SPACE eurjchem-124 54 1 = = NOUN eurjchem-124 54 2     SPACE eurjchem-124 54 3 6.9 6.9 NUM eurjchem-124 54 4     SPACE eurjchem-124 54 5 hz hz NOUN eurjchem-124 54 6 ) ) PUNCT eurjchem-124 54 7 , , PUNCT eurjchem-124 54 8     SPACE eurjchem-124 54 9 7.03 7.03 NUM eurjchem-124 54 10     SPACE eurjchem-124 54 11 ( ( PUNCT eurjchem-124 54 12 1h 1h NUM eurjchem-124 54 13 , , PUNCT eurjchem-124 54 14     SPACE eurjchem-124 54 15 dd dd NOUN eurjchem-124 54 16 , , PUNCT eurjchem-124 54 17     SPACE eurjchem-124 54 18 j1 j1 PROPN eurjchem-124 54 19     SPACE eurjchem-124 55 1 = = NOUN eurjchem-124 55 2     SPACE eurjchem-124 55 3 6.7 6.7 NUM eurjchem-124 55 4     SPACE eurjchem-124 55 5 hz hz VERB eurjchem-124 55 6 , , PUNCT eurjchem-124 55 7     SPACE eurjchem-124 55 8 j2 j2 PROPN eurjchem-124 55 9     SPACE eurjchem-124 55 10 = = NOUN eurjchem-124 55 11     SPACE eurjchem-124 55 12 8.6 8.6 NUM eurjchem-124 55 13     SPACE eurjchem-124 55 14 hz hz VERB eurjchem-124 55 15 , , PUNCT eurjchem-124 55 16       SPACE eurjchem-124 55 17 thiophene thiophene NOUN eurjchem-124 55 18     SPACE eurjchem-124 55 19 ch ch NOUN eurjchem-124 55 20 ) ) PUNCT eurjchem-124 55 21 . . PUNCT eurjchem-124 55 22     SPACE eurjchem-124 56 1 13c 13c NOUN eurjchem-124 56 2     SPACE eurjchem-124 56 3 nmr nmr NOUN eurjchem-124 56 4     SPACE eurjchem-124 56 5 ( ( PUNCT eurjchem-124 56 6 300 300 NUM eurjchem-124 56 7     SPACE eurjchem-124 56 8 mhz mhz NOUN eurjchem-124 56 9 , , PUNCT eurjchem-124 56 10     SPACE eurjchem-124 56 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 56 12 ) ) PUNCT eurjchem-124 56 13     SPACE eurjchem-124 56 14 in in ADP eurjchem-124 56 15     SPACE eurjchem-124 56 16 δ δ PROPN eurjchem-124 56 17     SPACE eurjchem-124 56 18 ( ( PUNCT eurjchem-124 56 19 ppm ppm PROPN eurjchem-124 56 20 ): ): PUNCT eurjchem-124 56 21     SPACE eurjchem-124 56 22 179.8 179.8 NUM eurjchem-124 56 23     SPACE eurjchem-124 56 24 ( ( PUNCT eurjchem-124 56 25 c c PROPN eurjchem-124 56 26 = = SYM eurjchem-124 56 27 s s NOUN eurjchem-124 56 28 ) ) PUNCT eurjchem-124 56 29 , , PUNCT eurjchem-124 56 30     SPACE eurjchem-124 56 31 170.1 170.1 NUM eurjchem-124 56 32     SPACE eurjchem-124 56 33 ( ( PUNCT eurjchem-124 56 34 c c NOUN eurjchem-124 56 35 = = NOUN eurjchem-124 56 36 o o NOUN eurjchem-124 56 37 ) ) PUNCT eurjchem-124 56 38 , , PUNCT eurjchem-124 56 39     SPACE eurjchem-124 56 40 165.0 165.0 NUM eurjchem-124 56 41     SPACE eurjchem-124 56 42 ( ( PUNCT eurjchem-124 56 43 c c NOUN eurjchem-124 56 44 = = SYM eurjchem-124 56 45 n n NUM eurjchem-124 56 46 ) ) PUNCT eurjchem-124 56 47 , , PUNCT eurjchem-124 56 48     SPACE eurjchem-124 56 49 149.1 149.1 NUM eurjchem-124 56 50     SPACE eurjchem-124 56 51 ( ( PUNCT eurjchem-124 56 52 c c NOUN eurjchem-124 56 53 ) ) PUNCT eurjchem-124 56 54 , , PUNCT eurjchem-124 56 55     SPACE eurjchem-124 56 56 145.5 145.5 NUM eurjchem-124 56 57     SPACE eurjchem-124 56 58 ( ( PUNCT eurjchem-124 56 59 c c NOUN eurjchem-124 56 60 ) ) PUNCT eurjchem-124 56 61 , , PUNCT eurjchem-124 56 62     SPACE eurjchem-124 56 63 141.3 141.3 NUM eurjchem-124 56 64     SPACE eurjchem-124 56 65 ( ( PUNCT eurjchem-124 56 66 c c NOUN eurjchem-124 56 67 ) ) PUNCT eurjchem-124 56 68 , , PUNCT eurjchem-124 56 69     SPACE eurjchem-124 56 70 133.7(c 133.7(c PROPN eurjchem-124 56 71 ) ) PUNCT eurjchem-124 56 72 , , PUNCT eurjchem-124 56 73     SPACE eurjchem-124 56 74 132.5 132.5 NUM eurjchem-124 56 75     SPACE eurjchem-124 56 76 ( ( PUNCT eurjchem-124 56 77 c c NOUN eurjchem-124 56 78 ) ) PUNCT eurjchem-124 56 79 , , PUNCT eurjchem-124 56 80     SPACE eurjchem-124 56 81 121.0 121.0 NUM eurjchem-124 56 82     SPACE eurjchem-124 56 83 ( ( PUNCT eurjchem-124 56 84 c c NOUN eurjchem-124 56 85 ) ) PUNCT eurjchem-124 56 86 . . PUNCT eurjchem-124 56 87     SPACE eurjchem-124 57 1 ei ei PROPN eurjchem-124 57 2     SPACE eurjchem-124 57 3 ms ms NOUN eurjchem-124 57 4 , , PUNCT eurjchem-124 57 5     SPACE eurjchem-124 57 6 m m PROPN eurjchem-124 57 7 / / PROPN eurjchem-124 57 8 z z NOUN eurjchem-124 57 9     SPACE eurjchem-124 57 10 ( ( PUNCT eurjchem-124 57 11 % % INTJ eurjchem-124 57 12 ): ): PUNCT eurjchem-124 57 13 297 297 NUM eurjchem-124 57 14 . . PUNCT eurjchem-124 57 15     SPACE eurjchem-124 57 16 anal anal ADJ eurjchem-124 57 17 . . PUNCT eurjchem-124 57 18     SPACE eurjchem-124 57 19 calcd calcd NOUN eurjchem-124 57 20 . . PUNCT eurjchem-124 57 21     SPACE eurjchem-124 57 22 for for ADP eurjchem-124 57 23     SPACE eurjchem-124 57 24 c9h7n5o3s2 c9h7n5o3s2 NOUN eurjchem-124 57 25 : : PUNCT eurjchem-124 57 26 : : PUNCT eurjchem-124 57 27     SPACE eurjchem-124 57 28 c c X eurjchem-124 57 29 , , PUNCT eurjchem-124 57 30     SPACE eurjchem-124 57 31 36.36 36.36 NUM eurjchem-124 57 32 ; ; PUNCT eurjchem-124 57 33     SPACE eurjchem-124 57 34 h h NOUN eurjchem-124 57 35 , , PUNCT eurjchem-124 57 36     SPACE eurjchem-124 57 37 2.37 2.37 NUM eurjchem-124 57 38 ; ; PUNCT eurjchem-124 57 39     SPACE eurjchem-124 57 40 n n CCONJ eurjchem-124 57 41 , , PUNCT eurjchem-124 57 42     SPACE eurjchem-124 57 43 23.56 23.56 NUM eurjchem-124 57 44 ; ; PUNCT eurjchem-124 57 45     SPACE eurjchem-124 57 46 s s PROPN eurjchem-124 57 47 , , PUNCT eurjchem-124 57 48     SPACE eurjchem-124 57 49 21.57 21.57 NUM eurjchem-124 57 50 . . PUNCT eurjchem-124 57 51     SPACE eurjchem-124 57 52 found find VERB eurjchem-124 57 53 : : PUNCT eurjchem-124 57 54     SPACE eurjchem-124 57 55 c c X eurjchem-124 57 56 , , PUNCT eurjchem-124 57 57     SPACE eurjchem-124 57 58 36.39 36.39 NUM eurjchem-124 57 59 ; ; PUNCT eurjchem-124 57 60     SPACE eurjchem-124 57 61 h h NOUN eurjchem-124 57 62 , , PUNCT eurjchem-124 57 63     SPACE eurjchem-124 57 64 2.40 2.40 NUM eurjchem-124 57 65 ; ; PUNCT eurjchem-124 57 66     SPACE eurjchem-124 57 67 n n CCONJ eurjchem-124 57 68 , , PUNCT eurjchem-124 57 69     SPACE eurjchem-124 57 70 23.54 23.54 NUM eurjchem-124 57 71 ; ; PUNCT eurjchem-124 57 72     SPACE eurjchem-124 57 73 s s PROPN eurjchem-124 57 74 , , PUNCT eurjchem-124 57 75     SPACE eurjchem-124 57 76 21.55 21.55 NUM eurjchem-124 57 77 . . PUNCT eurjchem-124 57 78         SPACE eurjchem-124 57 79 ethyl ethyl PROPN eurjchem-124 57 80     SPACE eurjchem-124 57 81 4­{[(thiophen­2­ylcarbonyl 4­{[(thiophen­2­ylcarbonyl NOUN eurjchem-124 57 82 ) ) PUNCT eurjchem-124 57 83     SPACE eurjchem-124 57 84 carbamothioyl carbamothioyl NOUN eurjchem-124 57 85 ] ] X eurjchem-124 57 86     SPACE eurjchem-124 57 87 amino amino NOUN eurjchem-124 57 88 } } PUNCT eurjchem-124 57 89     SPACE eurjchem-124 57 90 benzoate benzoate NOUN eurjchem-124 57 91     SPACE eurjchem-124 57 92 ( ( PUNCT eurjchem-124 57 93 3 3 NUM eurjchem-124 57 94 ): ): SYM eurjchem-124 57 95     SPACE eurjchem-124 57 96 light light ADJ eurjchem-124 57 97     SPACE eurjchem-124 57 98 yellow yellow ADJ eurjchem-124 57 99     SPACE eurjchem-124 57 100 crystals crystal NOUN eurjchem-124 57 101 . . PUNCT eurjchem-124 57 102     SPACE eurjchem-124 57 103 yield yield NOUN eurjchem-124 57 104 : : PUNCT eurjchem-124 57 105     SPACE eurjchem-124 57 106 91 91 NUM eurjchem-124 57 107 % % NOUN eurjchem-124 57 108 . . PUNCT eurjchem-124 57 109     SPACE eurjchem-124 58 1 m.p m.p PROPN eurjchem-124 58 2 . . PROPN eurjchem-124 58 3 : : PUNCT eurjchem-124 58 4     SPACE eurjchem-124 58 5 160‐161 160‐161 NUM eurjchem-124 58 6     SPACE eurjchem-124 58 7 oc oc PROPN eurjchem-124 58 8 . . PUNCT eurjchem-124 58 9     SPACE eurjchem-124 58 10 ft‐ir ft‐ir NOUN eurjchem-124 58 11     SPACE eurjchem-124 58 12 ( ( PUNCT eurjchem-124 58 13 kbr kbr NOUN eurjchem-124 58 14     SPACE eurjchem-124 58 15 pellet pellet NOUN eurjchem-124 58 16 ) ) PUNCT eurjchem-124 58 17     SPACE eurjchem-124 58 18 in in ADP eurjchem-124 58 19     SPACE eurjchem-124 58 20 cm‐1 cm‐1 NOUN eurjchem-124 58 21 : : PUNCT eurjchem-124 58 22     SPACE eurjchem-124 58 23 3363 3363 NUM eurjchem-124 58 24     SPACE eurjchem-124 58 25 ( ( PUNCT eurjchem-124 58 26 free free ADJ eurjchem-124 58 27     SPACE eurjchem-124 58 28 nh nh PROPN eurjchem-124 58 29 ) ) PUNCT eurjchem-124 58 30 , , PUNCT eurjchem-124 58 31     SPACE eurjchem-124 58 32 3210 3210 NUM eurjchem-124 58 33     SPACE eurjchem-124 58 34 ( ( PUNCT eurjchem-124 58 35 assoc assoc NOUN eurjchem-124 58 36     SPACE eurjchem-124 58 37 nh nh PROPN eurjchem-124 58 38 ) ) PUNCT eurjchem-124 58 39 , , PUNCT eurjchem-124 58 40     SPACE eurjchem-124 58 41 1725 1725 NUM eurjchem-124 58 42     SPACE eurjchem-124 58 43 ( ( PUNCT eurjchem-124 58 44 c c NOUN eurjchem-124 58 45 = = SYM eurjchem-124 58 46 o o NOUN eurjchem-124 58 47     SPACE eurjchem-124 58 48 ester ester NOUN eurjchem-124 58 49 ) ) PUNCT eurjchem-124 58 50 , , PUNCT eurjchem-124 58 51     SPACE eurjchem-124 58 52 1676 1676 NUM eurjchem-124 58 53     SPACE eurjchem-124 58 54 ( ( PUNCT eurjchem-124 58 55 c c NOUN eurjchem-124 58 56 = = SYM eurjchem-124 58 57 o o NOUN eurjchem-124 58 58     SPACE eurjchem-124 58 59 amide amide NOUN eurjchem-124 58 60 ) ) PUNCT eurjchem-124 58 61 , , PUNCT eurjchem-124 58 62     SPACE eurjchem-124 58 63 1593 1593 NUM eurjchem-124 58 64     SPACE eurjchem-124 58 65 ( ( PUNCT eurjchem-124 58 66 aromatic aromatic ADJ eurjchem-124 58 67     SPACE eurjchem-124 58 68 c c NOUN eurjchem-124 58 69 = = SYM eurjchem-124 58 70 c c NOUN eurjchem-124 58 71 ) ) PUNCT eurjchem-124 58 72 , , PUNCT eurjchem-124 58 73     SPACE eurjchem-124 58 74 1276 1276 NUM eurjchem-124 58 75     SPACE eurjchem-124 58 76 ( ( PUNCT eurjchem-124 58 77 c c X eurjchem-124 58 78 = = SYM eurjchem-124 58 79 s s NOUN eurjchem-124 58 80 ) ) PUNCT eurjchem-124 58 81 . . PUNCT eurjchem-124 58 82     SPACE eurjchem-124 59 1 1h 1h NUM eurjchem-124 59 2     SPACE eurjchem-124 59 3 nmr nmr NOUN eurjchem-124 59 4     SPACE eurjchem-124 59 5 ( ( PUNCT eurjchem-124 59 6 300 300 NUM eurjchem-124 59 7     SPACE eurjchem-124 59 8 mhz mhz NOUN eurjchem-124 59 9 , , PUNCT eurjchem-124 59 10     SPACE eurjchem-124 59 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 59 12 ) ) PUNCT eurjchem-124 59 13     SPACE eurjchem-124 59 14 in in ADP eurjchem-124 59 15     SPACE eurjchem-124 59 16 δ δ PROPN eurjchem-124 59 17     SPACE eurjchem-124 59 18 ( ( PUNCT eurjchem-124 59 19 ppm ppm NOUN eurjchem-124 59 20 ) ) PUNCT eurjchem-124 59 21     SPACE eurjchem-124 59 22 and and CCONJ eurjchem-124 59 23     SPACE eurjchem-124 59 24 j j PROPN eurjchem-124 59 25     SPACE eurjchem-124 59 26 ( ( PUNCT eurjchem-124 59 27 hz hz PROPN eurjchem-124 59 28 ): ): PROPN eurjchem-124 59 29     SPACE eurjchem-124 59 30 12.78 12.78 NUM eurjchem-124 59 31     SPACE eurjchem-124 59 32 ( ( PUNCT eurjchem-124 59 33 1h 1h NUM eurjchem-124 59 34 , , PUNCT eurjchem-124 59 35     SPACE eurjchem-124 59 36 br br PROPN eurjchem-124 59 37     SPACE eurjchem-124 59 38 s s PROPN eurjchem-124 59 39 , , PUNCT eurjchem-124 59 40     SPACE eurjchem-124 59 41 csnh csnh NOUN eurjchem-124 59 42 ) ) PUNCT eurjchem-124 59 43 , , PUNCT eurjchem-124 59 44     SPACE eurjchem-124 59 45 11.63 11.63 NUM eurjchem-124 59 46     SPACE eurjchem-124 59 47 ( ( PUNCT eurjchem-124 59 48 1h 1h NUM eurjchem-124 59 49 , , PUNCT eurjchem-124 59 50     SPACE eurjchem-124 59 51 br br PROPN eurjchem-124 59 52     SPACE eurjchem-124 59 53 s s PROPN eurjchem-124 59 54 , , PUNCT eurjchem-124 59 55     SPACE eurjchem-124 59 56 conh conh NOUN eurjchem-124 59 57 ) ) PUNCT eurjchem-124 59 58 , , PUNCT eurjchem-124 59 59     SPACE eurjchem-124 59 60 8.30 8.30 NUM eurjchem-124 59 61     SPACE eurjchem-124 59 62 ( ( PUNCT eurjchem-124 59 63 1h 1h NUM eurjchem-124 59 64 , , PUNCT eurjchem-124 59 65     SPACE eurjchem-124 59 66 dd dd NOUN eurjchem-124 59 67 , , PUNCT eurjchem-124 59 68     SPACE eurjchem-124 59 69 j1 j1 PROPN eurjchem-124 59 70     SPACE eurjchem-124 59 71 = = NOUN eurjchem-124 59 72     SPACE eurjchem-124 59 73 7.2 7.2 NUM eurjchem-124 59 74     SPACE eurjchem-124 59 75 hz hz VERB eurjchem-124 59 76 , , PUNCT eurjchem-124 59 77     SPACE eurjchem-124 59 78 j2 j2 PROPN eurjchem-124 59 79     SPACE eurjchem-124 59 80 = = NOUN eurjchem-124 59 81     SPACE eurjchem-124 59 82 8.1 8.1 NUM eurjchem-124 59 83     SPACE eurjchem-124 59 84 hz hz VERB eurjchem-124 59 85 , , PUNCT eurjchem-124 59 86       SPACE eurjchem-124 59 87 thiophene thiophene NOUN eurjchem-124 59 88     SPACE eurjchem-124 59 89 ch ch NOUN eurjchem-124 59 90 ) ) PUNCT eurjchem-124 59 91 , , PUNCT eurjchem-124 59 92     SPACE eurjchem-124 59 93 8.01 8.01 NUM eurjchem-124 59 94     SPACE eurjchem-124 59 95 ( ( PUNCT eurjchem-124 59 96 1h 1h NUM eurjchem-124 59 97 , , PUNCT eurjchem-124 59 98     SPACE eurjchem-124 59 99 dd dd NOUN eurjchem-124 59 100 , , PUNCT eurjchem-124 59 101     SPACE eurjchem-124 59 102 j1 j1 PROPN eurjchem-124 59 103     SPACE eurjchem-124 59 104 = = NOUN eurjchem-124 59 105     SPACE eurjchem-124 59 106 7.5 7.5 NUM eurjchem-124 59 107     SPACE eurjchem-124 59 108 hz hz VERB eurjchem-124 59 109 , , PUNCT eurjchem-124 59 110     SPACE eurjchem-124 59 111 j2 j2 PROPN eurjchem-124 59 112     SPACE eurjchem-124 59 113 = = NOUN eurjchem-124 59 114     SPACE eurjchem-124 59 115 8.2 8.2 NUM eurjchem-124 59 116     SPACE eurjchem-124 59 117 hz hz VERB eurjchem-124 59 118 , , PUNCT eurjchem-124 59 119     SPACE eurjchem-124 59 120 thiophene thiophene NOUN eurjchem-124 59 121     SPACE eurjchem-124 59 122 ch ch NOUN eurjchem-124 59 123 ) ) PUNCT eurjchem-124 59 124 , , PUNCT eurjchem-124 59 125     SPACE eurjchem-124 59 126 7.75 7.75 NUM eurjchem-124 59 127     SPACE eurjchem-124 59 128 ( ( PUNCT eurjchem-124 59 129 2h 2h NUM eurjchem-124 59 130 , , PUNCT eurjchem-124 59 131     SPACE eurjchem-124 59 132 d d PROPN eurjchem-124 59 133 , , PUNCT eurjchem-124 59 134     SPACE eurjchem-124 59 135 j j PROPN eurjchem-124 59 136     SPACE eurjchem-124 59 137 = = NOUN eurjchem-124 59 138     SPACE eurjchem-124 59 139 8.2 8.2 NUM eurjchem-124 59 140     SPACE eurjchem-124 59 141 hz hz NOUN eurjchem-124 59 142 ) ) PUNCT eurjchem-124 59 143 , , PUNCT eurjchem-124 59 144     SPACE eurjchem-124 59 145 7.65 7.65 NUM eurjchem-124 59 146     SPACE eurjchem-124 59 147 ( ( PUNCT eurjchem-124 59 148 2h 2h NUM eurjchem-124 59 149 , , PUNCT eurjchem-124 59 150     SPACE eurjchem-124 59 151 d d PROPN eurjchem-124 59 152 , , PUNCT eurjchem-124 59 153     SPACE eurjchem-124 59 154 j j PROPN eurjchem-124 59 155     SPACE eurjchem-124 59 156 = = NOUN eurjchem-124 59 157     SPACE eurjchem-124 59 158 6.9 6.9 NUM eurjchem-124 59 159     SPACE eurjchem-124 59 160 hz hz NOUN eurjchem-124 59 161 ) ) PUNCT eurjchem-124 59 162 , , PUNCT eurjchem-124 59 163     SPACE eurjchem-124 59 164 7.03 7.03 NUM eurjchem-124 59 165     SPACE eurjchem-124 59 166 ( ( PUNCT eurjchem-124 59 167 1h 1h NUM eurjchem-124 59 168 , , PUNCT eurjchem-124 59 169     SPACE eurjchem-124 59 170 dd dd VERB eurjchem-124 59 171 , , PUNCT eurjchem-124 59 172     SPACE eurjchem-124 59 173 j1 j1 PROPN eurjchem-124 59 174     SPACE eurjchem-124 60 1 = = NOUN eurjchem-124 60 2     SPACE eurjchem-124 60 3 6.7 6.7 NUM eurjchem-124 60 4     SPACE eurjchem-124 60 5 hz hz VERB eurjchem-124 60 6 , , PUNCT eurjchem-124 60 7     SPACE eurjchem-124 60 8 j2 j2 PROPN eurjchem-124 60 9     SPACE eurjchem-124 60 10 = = NOUN eurjchem-124 60 11     SPACE eurjchem-124 60 12 8.6 8.6 NUM eurjchem-124 60 13     SPACE eurjchem-124 60 14 hz hz VERB eurjchem-124 60 15 , , PUNCT eurjchem-124 60 16     SPACE eurjchem-124 60 17 thiophene thiophene NOUN eurjchem-124 60 18     SPACE eurjchem-124 60 19 ch ch NOUN eurjchem-124 60 20 ) ) PUNCT eurjchem-124 60 21 , , PUNCT eurjchem-124 60 22     SPACE eurjchem-124 60 23 4.32 4.32 NUM eurjchem-124 60 24     SPACE eurjchem-124 60 25 ( ( PUNCT eurjchem-124 60 26 2h 2h NUM eurjchem-124 60 27 , , PUNCT eurjchem-124 60 28     SPACE eurjchem-124 60 29 q q NOUN eurjchem-124 60 30 , , PUNCT eurjchem-124 60 31     SPACE eurjchem-124 60 32 ‐och2 ‐och2 NOUN eurjchem-124 60 33 ) ) PUNCT eurjchem-124 60 34 , , PUNCT eurjchem-124 60 35     SPACE eurjchem-124 60 36 1.31 1.31 NUM eurjchem-124 60 37     SPACE eurjchem-124 60 38 ( ( PUNCT eurjchem-124 60 39 3h 3h NUM eurjchem-124 60 40 , , PUNCT eurjchem-124 60 41     SPACE eurjchem-124 60 42 t t PROPN eurjchem-124 60 43 , , PUNCT eurjchem-124 60 44     SPACE eurjchem-124 60 45 ‐ch3 ‐ch3 ADJ eurjchem-124 60 46     SPACE eurjchem-124 60 47 ) ) PUNCT eurjchem-124 60 48 . . PUNCT eurjchem-124 60 49     SPACE eurjchem-124 61 1 13c 13c NOUN eurjchem-124 61 2     SPACE eurjchem-124 61 3 nmr nmr NOUN eurjchem-124 61 4     SPACE eurjchem-124 61 5 ( ( PUNCT eurjchem-124 61 6 300 300 NUM eurjchem-124 61 7     SPACE eurjchem-124 61 8 mhz mhz NOUN eurjchem-124 61 9 , , PUNCT eurjchem-124 61 10     SPACE eurjchem-124 61 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 61 12 ) ) PUNCT eurjchem-124 61 13     SPACE eurjchem-124 61 14 in in ADP eurjchem-124 61 15     SPACE eurjchem-124 61 16 δ δ PROPN eurjchem-124 61 17     SPACE eurjchem-124 61 18 ( ( PUNCT eurjchem-124 61 19 ppm ppm PROPN eurjchem-124 61 20 ): ): PUNCT eurjchem-124 61 21     SPACE eurjchem-124 61 22 179.8 179.8 NUM eurjchem-124 61 23     SPACE eurjchem-124 61 24 ( ( PUNCT eurjchem-124 61 25 c c X eurjchem-124 61 26 = = SYM eurjchem-124 61 27 s s NOUN eurjchem-124 61 28     SPACE eurjchem-124 61 29 thioamide thioamide NOUN eurjchem-124 61 30 ) ) PUNCT eurjchem-124 61 31 , , PUNCT eurjchem-124 61 32     SPACE eurjchem-124 61 33 168.2 168.2 NUM eurjchem-124 61 34     SPACE eurjchem-124 61 35 ( ( PUNCT eurjchem-124 61 36 c c NOUN eurjchem-124 61 37 = = SYM eurjchem-124 61 38 o o NOUN eurjchem-124 61 39     SPACE eurjchem-124 61 40 ester ester NOUN eurjchem-124 61 41 ) ) PUNCT eurjchem-124 61 42 , , PUNCT eurjchem-124 61 43     SPACE eurjchem-124 61 44 165.0 165.0 NUM eurjchem-124 61 45     SPACE eurjchem-124 61 46 ( ( PUNCT eurjchem-124 61 47 c c X eurjchem-124 61 48 = = NOUN eurjchem-124 61 49 o o NOUN eurjchem-124 61 50     SPACE eurjchem-124 61 51 amide amide NOUN eurjchem-124 61 52 ) ) PUNCT eurjchem-124 61 53 , , PUNCT eurjchem-124 61 54     SPACE eurjchem-124 61 55 145.4 145.4 NUM eurjchem-124 61 56     SPACE eurjchem-124 61 57 ( ( PUNCT eurjchem-124 61 58 c c NOUN eurjchem-124 61 59 ) ) PUNCT eurjchem-124 61 60 , , PUNCT eurjchem-124 61 61     SPACE eurjchem-124 61 62 142.5 142.5 NUM eurjchem-124 61 63     SPACE eurjchem-124 61 64 ( ( PUNCT eurjchem-124 61 65 c c NOUN eurjchem-124 61 66 ) ) PUNCT eurjchem-124 61 67 , , PUNCT eurjchem-124 61 68     SPACE eurjchem-124 61 69 134.4 134.4 NUM eurjchem-124 61 70     SPACE eurjchem-124 61 71 ( ( PUNCT eurjchem-124 61 72 c c NOUN eurjchem-124 61 73 ) ) PUNCT eurjchem-124 61 74 , , PUNCT eurjchem-124 61 75     SPACE eurjchem-124 61 76 132.2 132.2 NUM eurjchem-124 61 77     SPACE eurjchem-124 61 78 ( ( PUNCT eurjchem-124 61 79 c c NOUN eurjchem-124 61 80 ) ) PUNCT eurjchem-124 61 81 , , PUNCT eurjchem-124 61 82     SPACE eurjchem-124 61 83 128.8 128.8 NUM eurjchem-124 61 84     SPACE eurjchem-124 61 85 ( ( PUNCT eurjchem-124 61 86 c c NOUN eurjchem-124 61 87 ) ) PUNCT eurjchem-124 61 88 , , PUNCT eurjchem-124 61 89     SPACE eurjchem-124 61 90 128.1 128.1 NUM eurjchem-124 61 91     SPACE eurjchem-124 61 92 ( ( PUNCT eurjchem-124 61 93 c c NOUN eurjchem-124 61 94 ) ) PUNCT eurjchem-124 61 95 , , PUNCT eurjchem-124 61 96     SPACE eurjchem-124 61 97 127.5 127.5 NUM eurjchem-124 61 98     SPACE eurjchem-124 61 99 ( ( PUNCT eurjchem-124 61 100 c c NOUN eurjchem-124 61 101 ) ) PUNCT eurjchem-124 61 102 , , PUNCT eurjchem-124 61 103     SPACE eurjchem-124 61 104 123.4 123.4 NUM eurjchem-124 61 105     SPACE eurjchem-124 61 106 ( ( PUNCT eurjchem-124 61 107 c c NOUN eurjchem-124 61 108 ) ) PUNCT eurjchem-124 61 109 , , PUNCT eurjchem-124 61 110     SPACE eurjchem-124 61 111 60.7 60.7 NUM eurjchem-124 61 112     SPACE eurjchem-124 61 113 ( ( PUNCT eurjchem-124 61 114 c c NOUN eurjchem-124 61 115 ) ) PUNCT eurjchem-124 61 116 , , PUNCT eurjchem-124 61 117     SPACE eurjchem-124 61 118 14.1 14.1 NUM eurjchem-124 61 119     SPACE eurjchem-124 61 120 ( ( PUNCT eurjchem-124 61 121 c c NOUN eurjchem-124 61 122 ) ) PUNCT eurjchem-124 61 123 . . PUNCT eurjchem-124 61 124     SPACE eurjchem-124 62 1 ei ei PROPN eurjchem-124 62 2     SPACE eurjchem-124 62 3 ms ms PROPN eurjchem-124 62 4 , , PUNCT eurjchem-124 62 5     SPACE eurjchem-124 62 6 m m PROPN eurjchem-124 62 7 / / PROPN eurjchem-124 63 1 z z NOUN eurjchem-124 63 2     SPACE eurjchem-124 63 3 ( ( PUNCT eurjchem-124 63 4 % % INTJ eurjchem-124 63 5 ): ): PUNCT eurjchem-124 63 6     SPACE eurjchem-124 63 7 334 334 NUM eurjchem-124 63 8     SPACE eurjchem-124 63 9 ( ( PUNCT eurjchem-124 63 10 m+ m+ NUM eurjchem-124 63 11 , , PUNCT eurjchem-124 63 12     SPACE eurjchem-124 63 13 15 15 NUM eurjchem-124 63 14 ) ) PUNCT eurjchem-124 63 15 , , PUNCT eurjchem-124 63 16     SPACE eurjchem-124 63 17 169 169 NUM eurjchem-124 63 18     SPACE eurjchem-124 63 19 ( ( PUNCT eurjchem-124 63 20 30.5 30.5 NUM eurjchem-124 63 21 ) ) PUNCT eurjchem-124 63 22 , , PUNCT eurjchem-124 63 23     SPACE eurjchem-124 63 24 161 161 NUM eurjchem-124 63 25     SPACE eurjchem-124 63 26 ( ( PUNCT eurjchem-124 63 27 52 52 NUM eurjchem-124 63 28 ) ) PUNCT eurjchem-124 63 29 , , PUNCT eurjchem-124 63 30     SPACE eurjchem-124 63 31 141 141 NUM eurjchem-124 63 32     SPACE eurjchem-124 63 33 ( ( PUNCT eurjchem-124 63 34 4.7 4.7 NUM eurjchem-124 63 35 ) ) PUNCT eurjchem-124 63 36 , , PUNCT eurjchem-124 63 37     SPACE eurjchem-124 63 38 135 135 NUM eurjchem-124 63 39     SPACE eurjchem-124 63 40 ( ( PUNCT eurjchem-124 63 41 6.5 6.5 NUM eurjchem-124 63 42 ) ) PUNCT eurjchem-124 63 43 , , PUNCT eurjchem-124 63 44     SPACE eurjchem-124 63 45 111 111 NUM eurjchem-124 63 46     SPACE eurjchem-124 63 47 ( ( PUNCT eurjchem-124 63 48 100 100 NUM eurjchem-124 63 49 ) ) PUNCT eurjchem-124 63 50 , , PUNCT eurjchem-124 63 51     SPACE eurjchem-124 63 52 95 95 NUM eurjchem-124 63 53     SPACE eurjchem-124 63 54 ( ( PUNCT eurjchem-124 63 55 25.2 25.2 NUM eurjchem-124 63 56 ) ) PUNCT eurjchem-124 63 57 , , PUNCT eurjchem-124 63 58     SPACE eurjchem-124 63 59 73 73 NUM eurjchem-124 63 60     SPACE eurjchem-124 63 61 ( ( PUNCT eurjchem-124 63 62 20 20 NUM eurjchem-124 63 63 ) ) PUNCT eurjchem-124 63 64 , , PUNCT eurjchem-124 63 65     SPACE eurjchem-124 63 66 31 31 NUM eurjchem-124 63 67     SPACE eurjchem-124 63 68 ( ( PUNCT eurjchem-124 63 69 10 10 NUM eurjchem-124 63 70 ) ) PUNCT eurjchem-124 63 71 , , PUNCT eurjchem-124 63 72     SPACE eurjchem-124 63 73 15 15 NUM eurjchem-124 63 74     SPACE eurjchem-124 63 75 ( ( PUNCT eurjchem-124 63 76 3.4 3.4 NUM eurjchem-124 63 77 ) ) PUNCT eurjchem-124 63 78 . . PUNCT eurjchem-124 63 79     SPACE eurjchem-124 64 1 anal anal ADJ eurjchem-124 64 2 . . PUNCT eurjchem-124 64 3     SPACE eurjchem-124 64 4 calcd calcd NOUN eurjchem-124 64 5 . . PUNCT eurjchem-124 64 6     SPACE eurjchem-124 64 7 for for ADP eurjchem-124 64 8     SPACE eurjchem-124 64 9 c15h14n2o3s2 c15h14n2o3s2 NOUN eurjchem-124 64 10     SPACE eurjchem-124 64 11 : : PUNCT eurjchem-124 64 12     SPACE eurjchem-124 64 13 c c X eurjchem-124 64 14 , , PUNCT eurjchem-124 64 15     SPACE eurjchem-124 64 16 53.87 53.87 NUM eurjchem-124 64 17 ; ; PUNCT eurjchem-124 64 18     SPACE eurjchem-124 64 19 h h NOUN eurjchem-124 64 20 , , PUNCT eurjchem-124 64 21     SPACE eurjchem-124 64 22 4.22 4.22 NUM eurjchem-124 64 23 ; ; PUNCT eurjchem-124 64 24     SPACE eurjchem-124 64 25 n n CCONJ eurjchem-124 64 26 , , PUNCT eurjchem-124 64 27     SPACE eurjchem-124 64 28 8.38 8.38 NUM eurjchem-124 64 29 ; ; PUNCT eurjchem-124 64 30     SPACE eurjchem-124 64 31 s,19.18 s,19.18 PROPN eurjchem-124 64 32 . . PROPN eurjchem-124 64 33     SPACE eurjchem-124 64 34 found find VERB eurjchem-124 64 35 : : PUNCT eurjchem-124 64 36     SPACE eurjchem-124 64 37 c c X eurjchem-124 64 38 , , PUNCT eurjchem-124 64 39     SPACE eurjchem-124 64 40 53.89 53.89 NUM eurjchem-124 64 41 ; ; PUNCT eurjchem-124 64 42     SPACE eurjchem-124 64 43 h h NOUN eurjchem-124 64 44 , , PUNCT eurjchem-124 64 45     SPACE eurjchem-124 64 46 4.28 4.28 NUM eurjchem-124 64 47 ; ; PUNCT eurjchem-124 64 48     SPACE eurjchem-124 64 49 n n CCONJ eurjchem-124 64 50 , , PUNCT eurjchem-124 64 51     SPACE eurjchem-124 64 52 8.38 8.38 NUM eurjchem-124 64 53 ; ; PUNCT eurjchem-124 64 54     SPACE eurjchem-124 64 55 s s PROPN eurjchem-124 64 56 , , PUNCT eurjchem-124 64 57     SPACE eurjchem-124 64 58 19.20 19.20 NUM eurjchem-124 64 59 . . PUNCT eurjchem-124 64 60         SPACE eurjchem-124 65 1 n­(4­nitrophenyl)­n’­(thiophene­2­carbonyl)­thiourea n­(4­nitrophenyl)­n’­(thiophene­2­carbonyl)­thiourea ADV eurjchem-124 65 2     SPACE eurjchem-124 65 3 ( ( PUNCT eurjchem-124 65 4 4 4 NUM eurjchem-124 65 5 ): ): SYM eurjchem-124 65 6     SPACE eurjchem-124 65 7 dark dark ADJ eurjchem-124 65 8     SPACE eurjchem-124 65 9 yellow yellow ADJ eurjchem-124 65 10     SPACE eurjchem-124 65 11 solid solid ADJ eurjchem-124 65 12 . . PUNCT eurjchem-124 65 13     SPACE eurjchem-124 65 14 yield yield NOUN eurjchem-124 65 15 : : PUNCT eurjchem-124 65 16     SPACE eurjchem-124 65 17 94 94 NUM eurjchem-124 65 18 % % NOUN eurjchem-124 65 19 . . PUNCT eurjchem-124 65 20     SPACE eurjchem-124 66 1 m.p m.p PROPN eurjchem-124 66 2 . . PROPN eurjchem-124 66 3 : : PUNCT eurjchem-124 66 4     SPACE eurjchem-124 66 5 163‐164 163‐164 NOUN eurjchem-124 66 6     SPACE eurjchem-124 66 7 oc oc PROPN eurjchem-124 66 8 . . PUNCT eurjchem-124 66 9     SPACE eurjchem-124 66 10 ft‐ir ft‐ir NOUN eurjchem-124 66 11     SPACE eurjchem-124 66 12 ( ( PUNCT eurjchem-124 66 13 kbr kbr NOUN eurjchem-124 66 14     SPACE eurjchem-124 66 15 pellet pellet NOUN eurjchem-124 66 16 ) ) PUNCT eurjchem-124 66 17     SPACE eurjchem-124 66 18 in in ADP eurjchem-124 66 19     SPACE eurjchem-124 66 20 cm‐1 cm‐1 NOUN eurjchem-124 66 21 : : PUNCT eurjchem-124 66 22     SPACE eurjchem-124 66 23 3265 3265 NUM eurjchem-124 66 24 , , PUNCT eurjchem-124 66 25     SPACE eurjchem-124 66 26 3189 3189 NUM eurjchem-124 66 27     SPACE eurjchem-124 66 28 ( ( PUNCT eurjchem-124 66 29 n‐h n‐h NOUN eurjchem-124 66 30 ) ) PUNCT eurjchem-124 66 31 , , PUNCT eurjchem-124 66 32     SPACE eurjchem-124 66 33 3065‐3046 3065‐3046 NUM eurjchem-124 66 34     SPACE eurjchem-124 66 35 ( ( PUNCT eurjchem-124 66 36 c‐h c‐h X eurjchem-124 66 37 ) ) PUNCT eurjchem-124 66 38 , , PUNCT eurjchem-124 66 39     SPACE eurjchem-124 66 40 1678 1678 NUM eurjchem-124 66 41     SPACE eurjchem-124 66 42 ( ( PUNCT eurjchem-124 66 43 c c NOUN eurjchem-124 66 44 = = NOUN eurjchem-124 66 45 o o NOUN eurjchem-124 66 46 ) ) PUNCT eurjchem-124 66 47 , , PUNCT eurjchem-124 66 48     SPACE eurjchem-124 66 49 1593 1593 NUM eurjchem-124 66 50     SPACE eurjchem-124 66 51 ( ( PUNCT eurjchem-124 66 52 aromatic aromatic ADJ eurjchem-124 66 53     SPACE eurjchem-124 66 54 c c NOUN eurjchem-124 66 55 = = SYM eurjchem-124 66 56 c c NOUN eurjchem-124 66 57 ) ) PUNCT eurjchem-124 66 58 , , PUNCT eurjchem-124 66 59     SPACE eurjchem-124 66 60 1512 1512 NUM eurjchem-124 66 61     SPACE eurjchem-124 66 62 ( ( PUNCT eurjchem-124 66 63 no2 no2 PROPN eurjchem-124 66 64 ) ) PUNCT eurjchem-124 66 65 , , PUNCT eurjchem-124 66 66     SPACE eurjchem-124 66 67 1236 1236 NUM eurjchem-124 66 68     SPACE eurjchem-124 66 69 ( ( PUNCT eurjchem-124 66 70 c c NOUN eurjchem-124 66 71 = = SYM eurjchem-124 66 72 s s NOUN eurjchem-124 66 73 ) ) PUNCT eurjchem-124 66 74 . . PUNCT eurjchem-124 66 75     SPACE eurjchem-124 67 1 1h 1h NUM eurjchem-124 67 2     SPACE eurjchem-124 67 3 nmr nmr NOUN eurjchem-124 67 4     SPACE eurjchem-124 67 5 ( ( PUNCT eurjchem-124 67 6 300 300 NUM eurjchem-124 67 7     SPACE eurjchem-124 67 8 mhz mhz NOUN eurjchem-124 67 9 , , PUNCT eurjchem-124 67 10     SPACE eurjchem-124 67 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 67 12 ) ) PUNCT eurjchem-124 67 13     SPACE eurjchem-124 67 14 in in ADP eurjchem-124 67 15     SPACE eurjchem-124 67 16 δ δ PROPN eurjchem-124 67 17     SPACE eurjchem-124 67 18 ( ( PUNCT eurjchem-124 67 19 ppm ppm NOUN eurjchem-124 67 20 ) ) PUNCT eurjchem-124 67 21     SPACE eurjchem-124 67 22 and and CCONJ eurjchem-124 67 23     SPACE eurjchem-124 67 24 j j PROPN eurjchem-124 67 25     SPACE eurjchem-124 67 26 ( ( PUNCT eurjchem-124 67 27 hz hz PROPN eurjchem-124 67 28 ): ): PROPN eurjchem-124 67 29     SPACE eurjchem-124 67 30 12.41 12.41 NUM eurjchem-124 67 31     SPACE eurjchem-124 67 32 ( ( PUNCT eurjchem-124 67 33 1h 1h NUM eurjchem-124 67 34 , , PUNCT eurjchem-124 67 35     SPACE eurjchem-124 67 36 s s PROPN eurjchem-124 67 37 , , PUNCT eurjchem-124 67 38     SPACE eurjchem-124 67 39 csnh csnh NOUN eurjchem-124 67 40 ) ) PUNCT eurjchem-124 67 41 , , PUNCT eurjchem-124 67 42     SPACE eurjchem-124 67 43 11.92 11.92 NUM eurjchem-124 67 44     SPACE eurjchem-124 67 45 ( ( PUNCT eurjchem-124 67 46 1h 1h NUM eurjchem-124 67 47 , , PUNCT eurjchem-124 67 48     SPACE eurjchem-124 67 49 s s PROPN eurjchem-124 67 50 , , PUNCT eurjchem-124 67 51     SPACE eurjchem-124 67 52 conh conh NOUN eurjchem-124 67 53 ) ) PUNCT eurjchem-124 67 54 , , PUNCT eurjchem-124 67 55     SPACE eurjchem-124 67 56 8.21 8.21 NUM eurjchem-124 67 57     SPACE eurjchem-124 67 58 ( ( PUNCT eurjchem-124 67 59 2h 2h NUM eurjchem-124 67 60 , , PUNCT eurjchem-124 67 61     SPACE eurjchem-124 67 62 d d PROPN eurjchem-124 67 63 , , PUNCT eurjchem-124 67 64     SPACE eurjchem-124 67 65 j j PROPN eurjchem-124 67 66     SPACE eurjchem-124 67 67 = = NOUN eurjchem-124 67 68     SPACE eurjchem-124 67 69 9.1 9.1 NUM eurjchem-124 67 70     SPACE eurjchem-124 67 71 hz hz VERB eurjchem-124 67 72 , , PUNCT eurjchem-124 67 73     SPACE eurjchem-124 67 74 ar ar NOUN eurjchem-124 67 75     SPACE eurjchem-124 67 76 h h NOUN eurjchem-124 67 77 ) ) PUNCT eurjchem-124 67 78 , , PUNCT eurjchem-124 67 79     SPACE eurjchem-124 67 80 7.62 7.62 NUM eurjchem-124 67 81     SPACE eurjchem-124 67 82 ( ( PUNCT eurjchem-124 67 83 2h 2h NUM eurjchem-124 67 84 , , PUNCT eurjchem-124 67 85     SPACE eurjchem-124 67 86 d d PROPN eurjchem-124 67 87 , , PUNCT eurjchem-124 67 88             SPACE eurjchem-124 67 89 j j PROPN eurjchem-124 67 90     SPACE eurjchem-124 67 91 = = NOUN eurjchem-124 67 92     SPACE eurjchem-124 67 93 6.5 6.5 NUM eurjchem-124 67 94     SPACE eurjchem-124 67 95 hz hz VERB eurjchem-124 67 96 , , PUNCT eurjchem-124 67 97     SPACE eurjchem-124 67 98 ar ar NOUN eurjchem-124 67 99     SPACE eurjchem-124 67 100 h h NOUN eurjchem-124 67 101 ) ) PUNCT eurjchem-124 67 102 , , PUNCT eurjchem-124 67 103     SPACE eurjchem-124 67 104 8.30 8.30 NUM eurjchem-124 67 105     SPACE eurjchem-124 67 106 ( ( PUNCT eurjchem-124 67 107 1h 1h NUM eurjchem-124 67 108 , , PUNCT eurjchem-124 67 109     SPACE eurjchem-124 67 110 dd dd NOUN eurjchem-124 67 111 , , PUNCT eurjchem-124 67 112     SPACE eurjchem-124 67 113 j1 j1 PROPN eurjchem-124 67 114     SPACE eurjchem-124 67 115 = = NOUN eurjchem-124 67 116     SPACE eurjchem-124 67 117 7.9 7.9 NUM eurjchem-124 67 118     SPACE eurjchem-124 67 119 hz hz VERB eurjchem-124 67 120 , , PUNCT eurjchem-124 67 121     SPACE eurjchem-124 67 122 j2 j2 PROPN eurjchem-124 67 123     SPACE eurjchem-124 67 124 = = NOUN eurjchem-124 67 125     SPACE eurjchem-124 67 126 8.4 8.4 NUM eurjchem-124 67 127     SPACE eurjchem-124 67 128 hz hz VERB eurjchem-124 67 129 , , PUNCT eurjchem-124 67 130     SPACE eurjchem-124 67 131 thiophene thiophene NOUN eurjchem-124 67 132     SPACE eurjchem-124 67 133 ch ch NOUN eurjchem-124 67 134 ) ) PUNCT eurjchem-124 67 135 , , PUNCT eurjchem-124 67 136     SPACE eurjchem-124 67 137 8.01 8.01 NUM eurjchem-124 67 138     SPACE eurjchem-124 67 139 ( ( PUNCT eurjchem-124 67 140 1h 1h NUM eurjchem-124 67 141 , , PUNCT eurjchem-124 67 142     SPACE eurjchem-124 67 143 dd dd NOUN eurjchem-124 67 144 , , PUNCT eurjchem-124 67 145     SPACE eurjchem-124 67 146 j1 j1 PROPN eurjchem-124 67 147     SPACE eurjchem-124 67 148 = = NOUN eurjchem-124 67 149     SPACE eurjchem-124 67 150 7.5 7.5 NUM eurjchem-124 67 151     SPACE eurjchem-124 67 152 hz hz VERB eurjchem-124 67 153 , , PUNCT eurjchem-124 67 154     SPACE eurjchem-124 67 155 j2 j2 PROPN eurjchem-124 67 156     SPACE eurjchem-124 67 157 = = NOUN eurjchem-124 67 158     SPACE eurjchem-124 67 159 8.2 8.2 NUM eurjchem-124 67 160     SPACE eurjchem-124 67 161 hz hz VERB eurjchem-124 67 162 , , PUNCT eurjchem-124 67 163     SPACE eurjchem-124 67 164 thiophene thiophene NOUN eurjchem-124 67 165     SPACE eurjchem-124 67 166 ch ch NOUN eurjchem-124 67 167 ) ) PUNCT eurjchem-124 67 168 , , PUNCT eurjchem-124 67 169     SPACE eurjchem-124 67 170 7.21 7.21 NUM eurjchem-124 67 171     SPACE eurjchem-124 67 172 ( ( PUNCT eurjchem-124 67 173 1h 1h NUM eurjchem-124 67 174 , , PUNCT eurjchem-124 67 175     SPACE eurjchem-124 67 176 dd dd VERB eurjchem-124 67 177 , , PUNCT eurjchem-124 67 178     SPACE eurjchem-124 67 179 j1 j1 PROPN eurjchem-124 67 180     SPACE eurjchem-124 67 181 = = NOUN eurjchem-124 67 182     SPACE eurjchem-124 67 183 6.7 6.7 NUM eurjchem-124 67 184     SPACE eurjchem-124 67 185 hz hz VERB eurjchem-124 67 186 , , PUNCT eurjchem-124 67 187     SPACE eurjchem-124 67 188 j2 j2 PROPN eurjchem-124 67 189     SPACE eurjchem-124 67 190 = = NOUN eurjchem-124 67 191     SPACE eurjchem-124 67 192 9.0 9.0 NUM eurjchem-124 67 193     SPACE eurjchem-124 67 194 hz hz VERB eurjchem-124 67 195 , , PUNCT eurjchem-124 67 196     SPACE eurjchem-124 67 197 thiophene thiophene NOUN eurjchem-124 67 198     SPACE eurjchem-124 67 199 ch ch NOUN eurjchem-124 67 200 ) ) PUNCT eurjchem-124 67 201 . . PUNCT eurjchem-124 67 202     SPACE eurjchem-124 67 203 13c 13c NOUN eurjchem-124 67 204     SPACE eurjchem-124 67 205 nmr nmr NOUN eurjchem-124 67 206     SPACE eurjchem-124 67 207 ( ( PUNCT eurjchem-124 67 208 300 300 NUM eurjchem-124 67 209     SPACE eurjchem-124 67 210 mhz mhz NOUN eurjchem-124 67 211 , , PUNCT eurjchem-124 67 212 dmso‐d6 dmso‐d6 NOUN eurjchem-124 67 213 ) ) PUNCT eurjchem-124 67 214     SPACE eurjchem-124 67 215 in in ADP eurjchem-124 67 216     SPACE eurjchem-124 67 217 δ δ PROPN eurjchem-124 67 218     SPACE eurjchem-124 67 219 ( ( PUNCT eurjchem-124 67 220 ppm ppm PROPN eurjchem-124 67 221 ): ): PUNCT eurjchem-124 67 222     SPACE eurjchem-124 67 223 178.1 178.1 NUM eurjchem-124 67 224     SPACE eurjchem-124 67 225 ( ( PUNCT eurjchem-124 67 226 c c NOUN eurjchem-124 67 227 = = SYM eurjchem-124 67 228 s s NOUN eurjchem-124 67 229 ) ) PUNCT eurjchem-124 67 230 , , PUNCT eurjchem-124 67 231     SPACE eurjchem-124 67 232 168.0 168.0 NUM eurjchem-124 67 233     SPACE eurjchem-124 67 234 ( ( PUNCT eurjchem-124 67 235 c c NOUN eurjchem-124 67 236 = = NOUN eurjchem-124 67 237 o o NOUN eurjchem-124 67 238 ) ) PUNCT eurjchem-124 67 239 , , PUNCT eurjchem-124 67 240     SPACE eurjchem-124 67 241 145.4 145.4 NUM eurjchem-124 67 242     SPACE eurjchem-124 67 243 ( ( PUNCT eurjchem-124 67 244 c c NOUN eurjchem-124 67 245 ) ) PUNCT eurjchem-124 67 246 , , PUNCT eurjchem-124 67 247     SPACE eurjchem-124 67 248 136.2 136.2 NUM eurjchem-124 67 249     SPACE eurjchem-124 67 250 ( ( PUNCT eurjchem-124 67 251 c c NOUN eurjchem-124 67 252 ) ) PUNCT eurjchem-124 67 253 , , PUNCT eurjchem-124 67 254     SPACE eurjchem-124 67 255 135.7 135.7 NUM eurjchem-124 67 256     SPACE eurjchem-124 67 257 ( ( PUNCT eurjchem-124 67 258 c c NOUN eurjchem-124 67 259 ) ) PUNCT eurjchem-124 67 260 , , PUNCT eurjchem-124 67 261     SPACE eurjchem-124 67 262 135.0 135.0 NUM eurjchem-124 67 263     SPACE eurjchem-124 67 264 ( ( PUNCT eurjchem-124 67 265 c c NOUN eurjchem-124 67 266 ) ) PUNCT eurjchem-124 67 267 , , PUNCT eurjchem-124 67 268     SPACE eurjchem-124 67 269 132.2 132.2 NUM eurjchem-124 67 270     SPACE eurjchem-124 67 271 ( ( PUNCT eurjchem-124 67 272 c c NOUN eurjchem-124 67 273 ) ) PUNCT eurjchem-124 67 274 , , PUNCT eurjchem-124 67 275     SPACE eurjchem-124 67 276 129.8 129.8 NUM eurjchem-124 67 277     SPACE eurjchem-124 67 278 ( ( PUNCT eurjchem-124 67 279 c c NOUN eurjchem-124 67 280 ) ) PUNCT eurjchem-124 67 281 , , PUNCT eurjchem-124 67 282     SPACE eurjchem-124 67 283 128.7 128.7 NUM eurjchem-124 67 284     SPACE eurjchem-124 67 285 ( ( PUNCT eurjchem-124 67 286 2c 2c NOUN eurjchem-124 67 287 ) ) PUNCT eurjchem-124 67 288 , , PUNCT eurjchem-124 67 289     SPACE eurjchem-124 67 290 127.4 127.4 NUM eurjchem-124 67 291     SPACE eurjchem-124 67 292 ( ( PUNCT eurjchem-124 67 293 2c 2c NOUN eurjchem-124 67 294 ) ) PUNCT eurjchem-124 67 295 . . PUNCT eurjchem-124 67 296     SPACE eurjchem-124 68 1 ei ei PROPN eurjchem-124 68 2     SPACE eurjchem-124 68 3 ms ms PROPN eurjchem-124 68 4 , , PUNCT eurjchem-124 68 5     SPACE eurjchem-124 68 6 m m PROPN eurjchem-124 68 7 / / PROPN eurjchem-124 69 1 z z NOUN eurjchem-124 69 2     SPACE eurjchem-124 69 3 ( ( PUNCT eurjchem-124 69 4 % % INTJ eurjchem-124 69 5 ): ): PUNCT eurjchem-124 69 6     SPACE eurjchem-124 69 7 307 307 NUM eurjchem-124 69 8     SPACE eurjchem-124 69 9 ( ( PUNCT eurjchem-124 69 10 m+ m+ NUM eurjchem-124 69 11 , , PUNCT eurjchem-124 69 12     SPACE eurjchem-124 69 13 18 18 NUM eurjchem-124 69 14 ) ) PUNCT eurjchem-124 69 15 , , PUNCT eurjchem-124 69 16     SPACE eurjchem-124 69 17 273 273 NUM eurjchem-124 69 18     SPACE eurjchem-124 69 19 ( ( PUNCT eurjchem-124 69 20 5.1 5.1 NUM eurjchem-124 69 21 ) ) PUNCT eurjchem-124 69 22 , , PUNCT eurjchem-124 69 23     SPACE eurjchem-124 69 24 180 180 NUM eurjchem-124 69 25     SPACE eurjchem-124 69 26 ( ( PUNCT eurjchem-124 69 27 10 10 NUM eurjchem-124 69 28 ) ) PUNCT eurjchem-124 69 29 , , PUNCT eurjchem-124 69 30     SPACE eurjchem-124 69 31 137 137 NUM eurjchem-124 69 32     SPACE eurjchem-124 69 33 ( ( PUNCT eurjchem-124 69 34 7.5 7.5 NUM eurjchem-124 69 35 ) ) PUNCT eurjchem-124 69 36 , , PUNCT eurjchem-124 69 37     SPACE eurjchem-124 69 38 127 127 NUM eurjchem-124 69 39     SPACE eurjchem-124 69 40 ( ( PUNCT eurjchem-124 69 41 8.7 8.7 NUM eurjchem-124 69 42 ) ) PUNCT eurjchem-124 69 43 , , PUNCT eurjchem-124 69 44     SPACE eurjchem-124 69 45 111 111 NUM eurjchem-124 69 46     SPACE eurjchem-124 69 47 ( ( PUNCT eurjchem-124 69 48 100 100 NUM eurjchem-124 69 49 ) ) PUNCT eurjchem-124 69 50 , , PUNCT eurjchem-124 69 51     SPACE eurjchem-124 69 52 92 92 NUM eurjchem-124 69 53     SPACE eurjchem-124 69 54 ( ( PUNCT eurjchem-124 69 55 17.1 17.1 NUM eurjchem-124 69 56 ) ) PUNCT eurjchem-124 69 57 , , PUNCT eurjchem-124 69 58     SPACE eurjchem-124 69 59 84 84 NUM eurjchem-124 69 60     SPACE eurjchem-124 69 61 ( ( PUNCT eurjchem-124 69 62 55 55 NUM eurjchem-124 69 63 ) ) PUNCT eurjchem-124 69 64 . . PUNCT eurjchem-124 69 65     SPACE eurjchem-124 70 1 anal anal ADJ eurjchem-124 70 2 . . PUNCT eurjchem-124 70 3     SPACE eurjchem-124 70 4 calcd calcd NOUN eurjchem-124 70 5 . . PUNCT eurjchem-124 70 6     SPACE eurjchem-124 70 7 for for ADP eurjchem-124 70 8     SPACE eurjchem-124 70 9 c12h9n3o3s2 c12h9n3o3s2 NOUN eurjchem-124 70 10     SPACE eurjchem-124 70 11 : : PUNCT eurjchem-124 70 12     SPACE eurjchem-124 70 13 c c X eurjchem-124 70 14 , , PUNCT eurjchem-124 70 15     SPACE eurjchem-124 70 16 46.89 46.89 NUM eurjchem-124 70 17 ; ; PUNCT eurjchem-124 70 18     SPACE eurjchem-124 70 19 h h NOUN eurjchem-124 70 20 , , PUNCT eurjchem-124 70 21     SPACE eurjchem-124 70 22 2.95 2.95 NUM eurjchem-124 70 23 ; ; PUNCT eurjchem-124 70 24     SPACE eurjchem-124 70 25 n n CCONJ eurjchem-124 70 26 , , PUNCT eurjchem-124 70 27     SPACE eurjchem-124 70 28 13.67 13.67 NUM eurjchem-124 70 29 ; ; PUNCT eurjchem-124 70 30     SPACE eurjchem-124 70 31 s s PROPN eurjchem-124 70 32 , , PUNCT eurjchem-124 70 33     SPACE eurjchem-124 70 34 20.87 20.87 NUM eurjchem-124 70 35 . . PUNCT eurjchem-124 70 36     SPACE eurjchem-124 70 37 found find VERB eurjchem-124 70 38 : : PUNCT eurjchem-124 70 39     SPACE eurjchem-124 70 40 c c X eurjchem-124 70 41 , , PUNCT eurjchem-124 70 42     SPACE eurjchem-124 70 43 46.90 46.90 NUM eurjchem-124 70 44 ; ; PUNCT eurjchem-124 70 45     SPACE eurjchem-124 70 46 h h NOUN eurjchem-124 70 47 , , PUNCT eurjchem-124 70 48     SPACE eurjchem-124 70 49 2.98 2.98 NUM eurjchem-124 70 50 ; ; PUNCT eurjchem-124 70 51     SPACE eurjchem-124 70 52 n n CCONJ eurjchem-124 70 53 , , PUNCT eurjchem-124 70 54     SPACE eurjchem-124 70 55 13.65 13.65 NUM eurjchem-124 70 56 ; ; PUNCT eurjchem-124 70 57     SPACE eurjchem-124 70 58 s s PROPN eurjchem-124 70 59 , , PUNCT eurjchem-124 70 60     SPACE eurjchem-124 70 61 20.86 20.86 NUM eurjchem-124 70 62 . . PUNCT eurjchem-124 70 63         SPACE eurjchem-124 71 1 n­(4­chlorophenyl)­n’­(thiophene­2­carbonyl)­thiourea n­(4­chlorophenyl)­n’­(thiophene­2­carbonyl)­thiourea ADV eurjchem-124 71 2     SPACE eurjchem-124 71 3 ( ( PUNCT eurjchem-124 71 4 5 5 NUM eurjchem-124 71 5 ): ): SYM eurjchem-124 71 6     SPACE eurjchem-124 71 7 white white ADJ eurjchem-124 71 8     SPACE eurjchem-124 71 9 crystals crystal NOUN eurjchem-124 71 10 . . PUNCT eurjchem-124 71 11     SPACE eurjchem-124 71 12 yield yield NOUN eurjchem-124 71 13 : : PUNCT eurjchem-124 71 14     SPACE eurjchem-124 71 15 92 92 NUM eurjchem-124 71 16 % % NOUN eurjchem-124 71 17 . . PUNCT eurjchem-124 71 18     SPACE eurjchem-124 72 1 m.p m.p PROPN eurjchem-124 72 2 . . PROPN eurjchem-124 72 3 : : PUNCT eurjchem-124 72 4     SPACE eurjchem-124 72 5 151‐152 151‐152 NUM eurjchem-124 72 6     SPACE eurjchem-124 72 7 oc oc PROPN eurjchem-124 72 8 . . PUNCT eurjchem-124 72 9     SPACE eurjchem-124 72 10 ft‐ir ft‐ir NOUN eurjchem-124 72 11     SPACE eurjchem-124 72 12 ( ( PUNCT eurjchem-124 72 13 kbr kbr NOUN eurjchem-124 72 14     SPACE eurjchem-124 72 15 pellet pellet NOUN eurjchem-124 72 16 ) ) PUNCT eurjchem-124 72 17     SPACE eurjchem-124 72 18 in in ADP eurjchem-124 72 19     SPACE eurjchem-124 72 20 cm‐1 cm‐1 NOUN eurjchem-124 72 21 : : PUNCT eurjchem-124 72 22     SPACE eurjchem-124 72 23 3263 3263 NUM eurjchem-124 72 24 , , PUNCT eurjchem-124 72 25     SPACE eurjchem-124 72 26 3209 3209 NUM eurjchem-124 72 27     SPACE eurjchem-124 72 28 ( ( PUNCT eurjchem-124 72 29 n‐h n‐h NOUN eurjchem-124 72 30 ) ) PUNCT eurjchem-124 72 31 , , PUNCT eurjchem-124 72 32     SPACE eurjchem-124 72 33 3063‐3031 3063‐3031 NUM eurjchem-124 72 34     SPACE eurjchem-124 72 35 ( ( PUNCT eurjchem-124 72 36 c‐h c‐h NUM eurjchem-124 72 37 ) ) PUNCT eurjchem-124 72 38 , , PUNCT eurjchem-124 72 39     SPACE eurjchem-124 72 40 1675 1675 NUM eurjchem-124 72 41     SPACE eurjchem-124 72 42 ( ( PUNCT eurjchem-124 72 43 c c NOUN eurjchem-124 72 44 = = NOUN eurjchem-124 72 45 o o NOUN eurjchem-124 72 46 ) ) PUNCT eurjchem-124 72 47 , , PUNCT eurjchem-124 72 48     SPACE eurjchem-124 72 49 1593 1593 NUM eurjchem-124 72 50     SPACE eurjchem-124 72 51 ( ( PUNCT eurjchem-124 72 52 aromatic aromatic ADJ eurjchem-124 72 53     SPACE eurjchem-124 72 54 c c NOUN eurjchem-124 72 55 = = SYM eurjchem-124 72 56 c c NOUN eurjchem-124 72 57 ) ) PUNCT eurjchem-124 72 58 , , PUNCT eurjchem-124 72 59     SPACE eurjchem-124 72 60 1234 1234 NUM eurjchem-124 72 61     SPACE eurjchem-124 72 62 ( ( PUNCT eurjchem-124 72 63 c c PROPN eurjchem-124 72 64 = = SYM eurjchem-124 72 65 s s NOUN eurjchem-124 72 66 ) ) PUNCT eurjchem-124 72 67 . . PUNCT eurjchem-124 72 68     SPACE eurjchem-124 72 69 1h 1h NUM eurjchem-124 72 70     SPACE eurjchem-124 72 71 nmr nmr NOUN eurjchem-124 72 72     SPACE eurjchem-124 72 73 ( ( PUNCT eurjchem-124 72 74 300 300 NUM eurjchem-124 72 75     SPACE eurjchem-124 72 76 mhz mhz NOUN eurjchem-124 72 77 , , PUNCT eurjchem-124 72 78     SPACE eurjchem-124 72 79 dmso‐d6 dmso‐d6 NOUN eurjchem-124 72 80 ) ) PUNCT eurjchem-124 72 81     SPACE eurjchem-124 72 82 in in ADP eurjchem-124 72 83     SPACE eurjchem-124 72 84 δ δ PROPN eurjchem-124 72 85     SPACE eurjchem-124 72 86 ( ( PUNCT eurjchem-124 72 87 ppm ppm NOUN eurjchem-124 72 88 ) ) PUNCT eurjchem-124 72 89     SPACE eurjchem-124 72 90 and and CCONJ eurjchem-124 72 91     SPACE eurjchem-124 72 92 j j NOUN eurjchem-124 72 93     SPACE eurjchem-124 72 94 ( ( PUNCT eurjchem-124 72 95 hz hz PROPN eurjchem-124 72 96 ): ): PROPN eurjchem-124 72 97     SPACE eurjchem-124 72 98 12.20 12.20 NUM eurjchem-124 72 99     SPACE eurjchem-124 72 100 ( ( PUNCT eurjchem-124 72 101     SPACE eurjchem-124 72 102 1h 1h NUM eurjchem-124 72 103 , , PUNCT eurjchem-124 72 104     SPACE eurjchem-124 72 105 s s PROPN eurjchem-124 72 106 , , PUNCT eurjchem-124 72 107     SPACE eurjchem-124 72 108 csnh csnh PROPN eurjchem-124 72 109 ) ) PUNCT eurjchem-124 72 110 , , PUNCT eurjchem-124 72 111     SPACE eurjchem-124 72 112 11.55 11.55 NUM eurjchem-124 72 113     SPACE eurjchem-124 72 114 ( ( PUNCT eurjchem-124 72 115 1h 1h NUM eurjchem-124 72 116 , , PUNCT eurjchem-124 72 117     SPACE eurjchem-124 72 118 s s PROPN eurjchem-124 72 119 , , PUNCT eurjchem-124 72 120     SPACE eurjchem-124 72 121 conh conh NOUN eurjchem-124 72 122 ) ) PUNCT eurjchem-124 72 123 , , PUNCT eurjchem-124 72 124     SPACE eurjchem-124 72 125 8.31 8.31 NUM eurjchem-124 72 126     SPACE eurjchem-124 72 127 ( ( PUNCT eurjchem-124 72 128 1h 1h NUM eurjchem-124 72 129 , , PUNCT eurjchem-124 72 130     SPACE eurjchem-124 72 131 dd dd NOUN eurjchem-124 72 132 , , PUNCT eurjchem-124 72 133     SPACE eurjchem-124 72 134 j1 j1 PROPN eurjchem-124 72 135     SPACE eurjchem-124 73 1 = = NOUN eurjchem-124 73 2     SPACE eurjchem-124 73 3 7.2 7.2 NUM eurjchem-124 73 4     SPACE eurjchem-124 73 5 hz hz VERB eurjchem-124 73 6 , , PUNCT eurjchem-124 73 7     SPACE eurjchem-124 73 8 j2 j2 PROPN eurjchem-124 73 9     SPACE eurjchem-124 73 10 = = NOUN eurjchem-124 73 11     SPACE eurjchem-124 73 12 8.6 8.6 NUM eurjchem-124 73 13     SPACE eurjchem-124 73 14 hz hz VERB eurjchem-124 73 15 , , PUNCT eurjchem-124 73 16     SPACE eurjchem-124 73 17 thiophene thiophene NOUN eurjchem-124 73 18     SPACE eurjchem-124 73 19 ch ch NOUN eurjchem-124 73 20 ) ) PUNCT eurjchem-124 73 21 , , PUNCT eurjchem-124 73 22     SPACE eurjchem-124 74 1 8.01 8.01 NUM eurjchem-124 74 2     SPACE eurjchem-124 74 3 ( ( PUNCT eurjchem-124 74 4 1h 1h NUM eurjchem-124 74 5 , , PUNCT eurjchem-124 74 6     SPACE eurjchem-124 74 7 dd dd NOUN eurjchem-124 74 8 , , PUNCT eurjchem-124 74 9     SPACE eurjchem-124 74 10 j1 j1 PROPN eurjchem-124 74 11     SPACE eurjchem-124 74 12 = = NOUN eurjchem-124 74 13     SPACE eurjchem-124 74 14 7.5 7.5 NUM eurjchem-124 74 15     SPACE eurjchem-124 74 16 hz hz VERB eurjchem-124 74 17 , , PUNCT eurjchem-124 74 18     SPACE eurjchem-124 74 19 j2 j2 PROPN eurjchem-124 74 20     SPACE eurjchem-124 74 21 = = NOUN eurjchem-124 74 22     SPACE eurjchem-124 74 23 8.2 8.2 NUM eurjchem-124 74 24     SPACE eurjchem-124 74 25 hz hz VERB eurjchem-124 74 26 , , PUNCT eurjchem-124 74 27     SPACE eurjchem-124 74 28 thiophene thiophene NOUN eurjchem-124 74 29     SPACE eurjchem-124 74 30 ch ch NOUN eurjchem-124 74 31 ) ) PUNCT eurjchem-124 74 32 , , PUNCT eurjchem-124 74 33     SPACE eurjchem-124 74 34 7.03 7.03 NUM eurjchem-124 74 35     SPACE eurjchem-124 74 36 ( ( PUNCT eurjchem-124 74 37 1h 1h NUM eurjchem-124 74 38 , , PUNCT eurjchem-124 74 39     SPACE eurjchem-124 74 40 dd dd NOUN eurjchem-124 74 41 , , PUNCT eurjchem-124 74 42     SPACE eurjchem-124 74 43 j1 j1 PROPN eurjchem-124 74 44     SPACE eurjchem-124 75 1 = = NOUN eurjchem-124 75 2     SPACE eurjchem-124 75 3 6.7 6.7 NUM eurjchem-124 75 4     SPACE eurjchem-124 75 5 hz hz VERB eurjchem-124 75 6 , , PUNCT eurjchem-124 75 7     SPACE eurjchem-124 75 8 j2 j2 PROPN eurjchem-124 75 9     SPACE eurjchem-124 75 10 = = NOUN eurjchem-124 75 11     SPACE eurjchem-124 75 12 8.5 8.5 NUM eurjchem-124 75 13     SPACE eurjchem-124 75 14 hz hz VERB eurjchem-124 75 15 , , PUNCT eurjchem-124 75 16       SPACE eurjchem-124 75 17 thiophene thiophene NOUN eurjchem-124 75 18     SPACE eurjchem-124 75 19 ch ch NOUN eurjchem-124 75 20 ) ) PUNCT eurjchem-124 75 21 , , PUNCT eurjchem-124 75 22     SPACE eurjchem-124 75 23 7.76 7.76 NUM eurjchem-124 75 24     SPACE eurjchem-124 75 25 ( ( PUNCT eurjchem-124 75 26 2h 2h NUM eurjchem-124 75 27 , , PUNCT eurjchem-124 75 28     SPACE eurjchem-124 75 29 d d PROPN eurjchem-124 75 30 , , PUNCT eurjchem-124 75 31     SPACE eurjchem-124 75 32 j j PROPN eurjchem-124 75 33     SPACE eurjchem-124 75 34 = = NOUN eurjchem-124 75 35     SPACE eurjchem-124 75 36 8.2 8.2 NUM eurjchem-124 75 37     SPACE eurjchem-124 75 38 hz hz VERB eurjchem-124 75 39 , , PUNCT eurjchem-124 75 40     SPACE eurjchem-124 75 41 ar ar NOUN eurjchem-124 75 42     SPACE eurjchem-124 75 43 h h NOUN eurjchem-124 75 44 ) ) PUNCT eurjchem-124 75 45 , , PUNCT eurjchem-124 75 46     SPACE eurjchem-124 75 47 7.61 7.61 NUM eurjchem-124 75 48     SPACE eurjchem-124 75 49 ( ( PUNCT eurjchem-124 75 50 2h 2h NUM eurjchem-124 75 51 , , PUNCT eurjchem-124 75 52     SPACE eurjchem-124 75 53 d d PROPN eurjchem-124 75 54 , , PUNCT eurjchem-124 75 55     SPACE eurjchem-124 75 56 j j PROPN eurjchem-124 75 57     SPACE eurjchem-124 76 1 = = NOUN eurjchem-124 76 2     SPACE eurjchem-124 76 3 6.5 6.5 NUM eurjchem-124 76 4     SPACE eurjchem-124 76 5 hz hz VERB eurjchem-124 76 6 , , PUNCT eurjchem-124 76 7     SPACE eurjchem-124 76 8 ar ar NOUN eurjchem-124 76 9     SPACE eurjchem-124 76 10 h h NOUN eurjchem-124 76 11 ) ) PUNCT eurjchem-124 76 12 . . PUNCT eurjchem-124 76 13     SPACE eurjchem-124 77 1 13c 13c NOUN eurjchem-124 77 2     SPACE eurjchem-124 77 3 nmr nmr NOUN eurjchem-124 77 4     SPACE eurjchem-124 77 5 ( ( PUNCT eurjchem-124 77 6 300 300 NUM eurjchem-124 77 7     SPACE eurjchem-124 77 8 mhz mhz NOUN eurjchem-124 77 9 , , PUNCT eurjchem-124 77 10     SPACE eurjchem-124 77 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 77 12 ) ) PUNCT eurjchem-124 77 13     SPACE eurjchem-124 77 14 in in ADP eurjchem-124 77 15     SPACE eurjchem-124 77 16 δ δ PROPN eurjchem-124 77 17     SPACE eurjchem-124 77 18 ( ( PUNCT eurjchem-124 77 19 ppm ppm PROPN eurjchem-124 77 20 ): ): PUNCT eurjchem-124 77 21     SPACE eurjchem-124 77 22 179.1 179.1 NUM eurjchem-124 77 23     SPACE eurjchem-124 77 24 ( ( PUNCT eurjchem-124 77 25 c c NOUN eurjchem-124 77 26 = = SYM eurjchem-124 77 27 s s NOUN eurjchem-124 77 28 ) ) PUNCT eurjchem-124 77 29 , , PUNCT eurjchem-124 77 30     SPACE eurjchem-124 77 31 162.3 162.3 NUM eurjchem-124 77 32     SPACE eurjchem-124 77 33 ( ( PUNCT eurjchem-124 77 34 c c NOUN eurjchem-124 77 35 = = NOUN eurjchem-124 77 36 o o NOUN eurjchem-124 77 37 ) ) PUNCT eurjchem-124 77 38 , , PUNCT eurjchem-124 77 39     SPACE eurjchem-124 77 40 141.0 141.0 NUM eurjchem-124 77 41     SPACE eurjchem-124 77 42 ( ( PUNCT eurjchem-124 77 43 c c NOUN eurjchem-124 77 44 ) ) PUNCT eurjchem-124 77 45 , , PUNCT eurjchem-124 77 46     SPACE eurjchem-124 77 47 135.5 135.5 NUM eurjchem-124 77 48     SPACE eurjchem-124 77 49 ( ( PUNCT eurjchem-124 77 50 c c NOUN eurjchem-124 77 51 ) ) PUNCT eurjchem-124 77 52 , , PUNCT eurjchem-124 77 53     SPACE eurjchem-124 77 54 133.0 133.0 NUM eurjchem-124 77 55     SPACE eurjchem-124 77 56 ( ( PUNCT eurjchem-124 77 57 c c NOUN eurjchem-124 77 58 ) ) PUNCT eurjchem-124 77 59 , , PUNCT eurjchem-124 77 60     SPACE eurjchem-124 77 61 132.2 132.2 NUM eurjchem-124 77 62     SPACE eurjchem-124 77 63 ( ( PUNCT eurjchem-124 77 64 c c NOUN eurjchem-124 77 65 ) ) PUNCT eurjchem-124 77 66 , , PUNCT eurjchem-124 77 67     SPACE eurjchem-124 77 68 132.0 132.0 NUM eurjchem-124 77 69     SPACE eurjchem-124 77 70 ( ( PUNCT eurjchem-124 77 71 c c NOUN eurjchem-124 77 72 ) ) PUNCT eurjchem-124 77 73 , , PUNCT eurjchem-124 77 74     SPACE eurjchem-124 77 75 130.5 130.5 NUM eurjchem-124 77 76     SPACE eurjchem-124 77 77 ( ( PUNCT eurjchem-124 77 78 c c NOUN eurjchem-124 77 79 ) ) PUNCT eurjchem-124 77 80 , , PUNCT eurjchem-124 77 81     SPACE eurjchem-124 77 82 128.0 128.0 NUM eurjchem-124 77 83     SPACE eurjchem-124 77 84 ( ( PUNCT eurjchem-124 77 85 2c 2c NOUN eurjchem-124 77 86 ) ) PUNCT eurjchem-124 77 87 , , PUNCT eurjchem-124 77 88     SPACE eurjchem-124 77 89 127.2 127.2 NUM eurjchem-124 77 90     SPACE eurjchem-124 77 91 ( ( PUNCT eurjchem-124 77 92 2c 2c NOUN eurjchem-124 77 93 ) ) PUNCT eurjchem-124 77 94 . . PUNCT eurjchem-124 77 95     SPACE eurjchem-124 78 1 ei ei PROPN eurjchem-124 78 2     SPACE eurjchem-124 78 3 ms ms PROPN eurjchem-124 78 4 , , PUNCT eurjchem-124 78 5     SPACE eurjchem-124 78 6 m m PROPN eurjchem-124 78 7 / / SYM eurjchem-124 78 8 z(% z(% NOUN eurjchem-124 78 9 ): ): PUNCT eurjchem-124 78 10     SPACE eurjchem-124 78 11 298 298 NUM eurjchem-124 78 12     SPACE eurjchem-124 78 13 ( ( PUNCT eurjchem-124 78 14 m+ m+ NUM eurjchem-124 78 15 , , PUNCT eurjchem-124 78 16     SPACE eurjchem-124 78 17 5.5 5.5 NUM eurjchem-124 78 18 ) ) PUNCT eurjchem-124 78 19 , , PUNCT eurjchem-124 78 20     SPACE eurjchem-124 78 21 296 296 NUM eurjchem-124 78 22     SPACE eurjchem-124 78 23 ( ( PUNCT eurjchem-124 78 24 m+ m+ NUM eurjchem-124 78 25 , , PUNCT eurjchem-124 78 26     SPACE eurjchem-124 78 27 20 20 NUM eurjchem-124 78 28 ) ) PUNCT eurjchem-124 78 29 , , PUNCT eurjchem-124 78 30     SPACE eurjchem-124 78 31 262 262 NUM eurjchem-124 78 32     SPACE eurjchem-124 78 33 ( ( PUNCT eurjchem-124 78 34 6.4 6.4 NUM eurjchem-124 78 35 ) ) PUNCT eurjchem-124 78 36 , , PUNCT eurjchem-124 78 37     SPACE eurjchem-124 78 38 169 169 NUM eurjchem-124 78 39     SPACE eurjchem-124 78 40 ( ( PUNCT eurjchem-124 78 41 52 52 NUM eurjchem-124 78 42 ) ) PUNCT eurjchem-124 78 43 , , PUNCT eurjchem-124 78 44     SPACE eurjchem-124 78 45 170 170 NUM eurjchem-124 78 46     SPACE eurjchem-124 78 47 ( ( PUNCT eurjchem-124 78 48 3 3 NUM eurjchem-124 78 49 ) ) PUNCT eurjchem-124 78 50 , , PUNCT eurjchem-124 78 51     SPACE eurjchem-124 78 52 126 126 NUM eurjchem-124 78 53     SPACE eurjchem-124 78 54 ( ( PUNCT eurjchem-124 78 55 5.5 5.5 NUM eurjchem-124 78 56 ) ) PUNCT eurjchem-124 78 57 , , PUNCT eurjchem-124 78 58     SPACE eurjchem-124 78 59 111 111 NUM eurjchem-124 78 60     SPACE eurjchem-124 78 61 ( ( PUNCT eurjchem-124 78 62 100 100 NUM eurjchem-124 78 63 ) ) PUNCT eurjchem-124 78 64 , , PUNCT eurjchem-124 78 65     SPACE eurjchem-124 78 66 84 84 NUM eurjchem-124 78 67     SPACE eurjchem-124 78 68 ( ( PUNCT eurjchem-124 78 69 57 57 NUM eurjchem-124 78 70 ) ) PUNCT eurjchem-124 78 71 . . PUNCT eurjchem-124 78 72     SPACE eurjchem-124 79 1 anal anal ADJ eurjchem-124 79 2 . . PUNCT eurjchem-124 79 3     SPACE eurjchem-124 79 4 calcd calcd NOUN eurjchem-124 79 5 . . PUNCT eurjchem-124 79 6     SPACE eurjchem-124 79 7 for for ADP eurjchem-124 79 8     SPACE eurjchem-124 79 9 c12h9cln2os2 c12h9cln2os2 NOUN eurjchem-124 79 10     SPACE eurjchem-124 79 11 : : PUNCT eurjchem-124 79 12     SPACE eurjchem-124 79 13 c c X eurjchem-124 79 14 , , PUNCT eurjchem-124 79 15     SPACE eurjchem-124 79 16 48.56 48.56 NUM eurjchem-124 79 17 ; ; PUNCT eurjchem-124 79 18     SPACE eurjchem-124 79 19 h h NOUN eurjchem-124 79 20 , , PUNCT eurjchem-124 79 21     SPACE eurjchem-124 79 22 3.06 3.06 NUM eurjchem-124 79 23 ; ; PUNCT eurjchem-124 79 24     SPACE eurjchem-124 79 25 n n CCONJ eurjchem-124 79 26 , , PUNCT eurjchem-124 79 27     SPACE eurjchem-124 79 28 9.44 9.44 NUM eurjchem-124 79 29 ; ; PUNCT eurjchem-124 79 30     SPACE eurjchem-124 79 31 s s PROPN eurjchem-124 79 32 , , PUNCT eurjchem-124 79 33     SPACE eurjchem-124 79 34 21.61 21.61 NUM eurjchem-124 79 35 . . PUNCT eurjchem-124 79 36     SPACE eurjchem-124 79 37 found find VERB eurjchem-124 79 38 : : PUNCT eurjchem-124 79 39     SPACE eurjchem-124 79 40 c c X eurjchem-124 79 41 , , PUNCT eurjchem-124 79 42     SPACE eurjchem-124 79 43 48.57 48.57 NUM eurjchem-124 79 44 ; ; PUNCT eurjchem-124 79 45     SPACE eurjchem-124 79 46 h h NOUN eurjchem-124 79 47 , , PUNCT eurjchem-124 79 48     SPACE eurjchem-124 79 49 3.09 3.09 NUM eurjchem-124 79 50 ; ; PUNCT eurjchem-124 79 51     SPACE eurjchem-124 79 52 n n CCONJ eurjchem-124 79 53 , , PUNCT eurjchem-124 79 54     SPACE eurjchem-124 79 55 9.46 9.46 NUM eurjchem-124 79 56 ; ; PUNCT eurjchem-124 79 57     SPACE eurjchem-124 79 58 s s PROPN eurjchem-124 79 59 , , PUNCT eurjchem-124 79 60     SPACE eurjchem-124 79 61 21.61 21.61 NUM eurjchem-124 79 62 . . PUNCT eurjchem-124 79 63         SPACE eurjchem-124 79 64 n n CCONJ eurjchem-124 79 65 , , PUNCT eurjchem-124 79 66 n­diphenyl­n’­(thiophene­2­carbonyl)­thiourea n­diphenyl­n’­(thiophene­2­carbonyl)­thiourea NUM eurjchem-124 79 67     SPACE eurjchem-124 79 68 ( ( PUNCT eurjchem-124 79 69 6 6 NUM eurjchem-124 79 70 ): ): SYM eurjchem-124 79 71     SPACE eurjchem-124 79 72 dark dark ADJ eurjchem-124 79 73     SPACE eurjchem-124 79 74 yellow yellow ADJ eurjchem-124 79 75     SPACE eurjchem-124 79 76 crystals crystal NOUN eurjchem-124 79 77 . . PUNCT eurjchem-124 79 78     SPACE eurjchem-124 79 79 yield yield NOUN eurjchem-124 79 80 : : PUNCT eurjchem-124 79 81     SPACE eurjchem-124 79 82 91 91 NUM eurjchem-124 79 83 % % NOUN eurjchem-124 79 84 . . PUNCT eurjchem-124 79 85     SPACE eurjchem-124 80 1 m.p m.p PROPN eurjchem-124 80 2 . . PROPN eurjchem-124 80 3 : : PUNCT eurjchem-124 80 4     SPACE eurjchem-124 80 5 153‐154 153‐154 NUM eurjchem-124 80 6     SPACE eurjchem-124 80 7 oc oc PROPN eurjchem-124 80 8 . . PUNCT eurjchem-124 80 9     SPACE eurjchem-124 80 10 ft‐ir ft‐ir NOUN eurjchem-124 80 11     SPACE eurjchem-124 80 12 ( ( PUNCT eurjchem-124 80 13 kbr kbr NOUN eurjchem-124 80 14     SPACE eurjchem-124 80 15 pellet pellet NOUN eurjchem-124 80 16 ) ) PUNCT eurjchem-124 80 17     SPACE eurjchem-124 80 18 in in ADP eurjchem-124 80 19         SPACE eurjchem-124 80 20 cm‐1 cm‐1 NOUN eurjchem-124 80 21 : : PUNCT eurjchem-124 80 22         SPACE eurjchem-124 80 23 3245 3245 NUM eurjchem-124 80 24       SPACE eurjchem-124 80 25 ( ( PUNCT eurjchem-124 80 26 nh nh NOUN eurjchem-124 80 27 ) ) PUNCT eurjchem-124 80 28 , , PUNCT eurjchem-124 80 29         SPACE eurjchem-124 80 30 3063‐3031 3063‐3031 NUM eurjchem-124 80 31       SPACE eurjchem-124 80 32 ( ( PUNCT eurjchem-124 80 33 c‐h c‐h PROPN eurjchem-124 80 34 ) ) PUNCT eurjchem-124 80 35 , , PUNCT eurjchem-124 80 36         SPACE eurjchem-124 80 37 1680 1680 NUM eurjchem-124 80 38       SPACE eurjchem-124 80 39 ( ( PUNCT eurjchem-124 80 40 c c NOUN eurjchem-124 80 41 = = NOUN eurjchem-124 80 42 o o NOUN eurjchem-124 80 43 ) ) PUNCT eurjchem-124 80 44 , , PUNCT eurjchem-124 80 45         SPACE eurjchem-124 80 46 1593 1593 NUM eurjchem-124 80 47       SPACE eurjchem-124 80 48 saeed saeed PROPN eurjchem-124 80 49     SPACE eurjchem-124 80 50 et et PROPN eurjchem-124 80 51     SPACE eurjchem-124 80 52 al al PROPN eurjchem-124 80 53 . . PROPN eurjchem-124 80 54     SPACE eurjchem-124 80 55 / / SYM eurjchem-124 80 56     SPACE eurjchem-124 80 57 european european ADJ eurjchem-124 80 58     SPACE eurjchem-124 80 59 journal journal NOUN eurjchem-124 80 60     SPACE eurjchem-124 80 61 of of ADP eurjchem-124 80 62     SPACE eurjchem-124 80 63 chemistry chemistry NOUN eurjchem-124 80 64     SPACE eurjchem-124 80 65 1 1 NUM eurjchem-124 80 66     SPACE eurjchem-124 80 67 ( ( PUNCT eurjchem-124 80 68 3 3 NUM eurjchem-124 80 69 ) ) PUNCT eurjchem-124 80 70     SPACE eurjchem-124 80 71 ( ( PUNCT eurjchem-124 80 72 2010 2010 NUM eurjchem-124 80 73 ) ) PUNCT eurjchem-124 80 74     SPACE eurjchem-124 80 75 221­227 221­227 NUM eurjchem-124 80 76     SPACE eurjchem-124 80 77 223 223 NUM eurjchem-124 80 78     SPACE eurjchem-124 80 79 s s PART eurjchem-124 80 80 o o NOUN eurjchem-124 80 81 n n SYM eurjchem-124 80 82 s s NOUN eurjchem-124 80 83 n n PRON eurjchem-124 81 1 p p NOUN eurjchem-124 81 2 o o X eurjchem-124 81 3 h3c h3c X eurjchem-124 81 4 ch3 ch3 PROPN eurjchem-124 81 5 po po PROPN eurjchem-124 81 6 ch3 ch3 PROPN eurjchem-124 81 7 ch3 ch3 PROPN eurjchem-124 81 8 h h PROPN eurjchem-124 81 9 s s PART eurjchem-124 81 10 o o PROPN eurjchem-124 81 11 n n SYM eurjchem-124 81 12 s s NOUN eurjchem-124 81 13 n n PRON eurjchem-124 81 14 h h NOUN eurjchem-124 82 1 o o X eurjchem-124 82 2 o o X eurjchem-124 82 3 ch3 ch3 PROPN eurjchem-124 82 4 h h PROPN eurjchem-124 82 5 s s PART eurjchem-124 82 6 o o PROPN eurjchem-124 82 7 n n ADP eurjchem-124 82 8 s s PROPN eurjchem-124 82 9 n n PRON eurjchem-124 82 10 no2 no2 NOUN eurjchem-124 82 11 h h NOUN eurjchem-124 82 12 h h NOUN eurjchem-124 82 13 s s PART eurjchem-124 82 14 o o PROPN eurjchem-124 82 15 n n SYM eurjchem-124 82 16 s s PROPN eurjchem-124 82 17 n n PRON eurjchem-124 82 18 h h NOUN eurjchem-124 82 19 h h NOUN eurjchem-124 82 20 cl cl NOUN eurjchem-124 82 21 s s PART eurjchem-124 82 22 o o X eurjchem-124 82 23 n n SYM eurjchem-124 82 24 s s NOUN eurjchem-124 83 1 n n NUM eurjchem-124 84 1 h h NOUN eurjchem-124 85 1 h h NOUN eurjchem-124 85 2 s s PART eurjchem-124 85 3 o o PROPN eurjchem-124 85 4 n n SYM eurjchem-124 85 5 s s NOUN eurjchem-124 85 6 n n NOUN eurjchem-124 85 7 h h NOUN eurjchem-124 85 8 s s NOUN eurjchem-124 85 9 o o PROPN eurjchem-124 85 10 n n SYM eurjchem-124 85 11 s s PROPN eurjchem-124 85 12 n n PRON eurjchem-124 86 1 h h NOUN eurjchem-124 86 2 h h PROPN eurjchem-124 86 3 ch3 ch3 PROPN eurjchem-124 86 4 s s PART eurjchem-124 86 5 o o PROPN eurjchem-124 86 6 n n ADP eurjchem-124 86 7 s s NOUN eurjchem-124 86 8 n n PRON eurjchem-124 86 9 h h NOUN eurjchem-124 87 1 n n ADV eurjchem-124 87 2 h h NOUN eurjchem-124 88 1 hn hn PROPN eurjchem-124 88 2 no2 no2 PROPN eurjchem-124 88 3 s s PART eurjchem-124 88 4 o o PROPN eurjchem-124 88 5 n n ADP eurjchem-124 88 6 s s PROPN eurjchem-124 88 7 n n PRON eurjchem-124 88 8 h h PROPN eurjchem-124 88 9 ch3 ch3 PROPN eurjchem-124 88 10 ch3 ch3 PROPN eurjchem-124 88 11 s s PART eurjchem-124 88 12 o o PROPN eurjchem-124 88 13 n n ADP eurjchem-124 88 14 s s PROPN eurjchem-124 88 15 n n PRON eurjchem-124 89 1 h h NOUN eurjchem-124 89 2 h h PROPN eurjchem-124 89 3 ch3 ch3 PROPN eurjchem-124 89 4 s s PART eurjchem-124 89 5 o o PROPN eurjchem-124 89 6 n n ADP eurjchem-124 89 7 s s PROPN eurjchem-124 89 8 n n PRON eurjchem-124 89 9 h h NOUN eurjchem-124 89 10 ch3 ch3 PROPN eurjchem-124 89 11 h3c h3c VERB eurjchem-124 89 12 s s PROPN eurjchem-124 89 13 o o PROPN eurjchem-124 89 14 n n SYM eurjchem-124 89 15 s s NOUN eurjchem-124 89 16 n n NUM eurjchem-124 89 17 h h NOUN eurjchem-124 89 18 n n CCONJ eurjchem-124 89 19 s s PROPN eurjchem-124 89 20 och3 och3 PROPN eurjchem-124 89 21 h h NOUN eurjchem-124 89 22 s s PART eurjchem-124 89 23 o o NOUN eurjchem-124 89 24 cl cl NOUN eurjchem-124 90 1 nh4scn nh4scn PROPN eurjchem-124 90 2 s s X eurjchem-124 90 3 o o NOUN eurjchem-124 90 4 n n ADP eurjchem-124 90 5 c c NOUN eurjchem-124 90 6 s s PART eurjchem-124 90 7 tbab tbab PROPN eurjchem-124 90 8 p p X eurjchem-124 90 9 o o PROPN eurjchem-124 90 10 ch3 ch3 PROPN eurjchem-124 90 11 h3c h3c VERB eurjchem-124 91 1 n n PRON eurjchem-124 91 2 h h NOUN eurjchem-124 91 3 p p NOUN eurjchem-124 91 4 o o X eurjchem-124 91 5 h3c h3c VERB eurjchem-124 91 6 ch3 ch3 PROPN eurjchem-124 92 1 hn hn PROPN eurjchem-124 92 2 n n PROPN eurjchem-124 92 3 h2n h2n PROPN eurjchem-124 92 4 no2 no2 NOUN eurjchem-124 92 5 o o NOUN eurjchem-124 92 6 o o X eurjchem-124 92 7 ch3 ch3 PROPN eurjchem-124 92 8 h2n h2n PROPN eurjchem-124 92 9 h2n h2n PROPN eurjchem-124 92 10 no2 no2 PROPN eurjchem-124 92 11 h2n h2n PROPN eurjchem-124 92 12 cl cl NOUN eurjchem-124 92 13 h h PROPN eurjchem-124 92 14 n n PROPN eurjchem-124 92 15 h2n h2n PROPN eurjchem-124 92 16 ch3 ch3 PROPN eurjchem-124 92 17 nh2 nh2 PROPN eurjchem-124 92 18 h3c h3c VERB eurjchem-124 92 19 n n PROPN eurjchem-124 92 20 h h PROPN eurjchem-124 92 21 ch3 ch3 PROPN eurjchem-124 93 1 nh2h3c nh2h3c ADP eurjchem-124 93 2 h3c h3c PROPN eurjchem-124 93 3 h h NOUN eurjchem-124 93 4 n n PROPN eurjchem-124 93 5 ch3 ch3 PROPN eurjchem-124 93 6 n n PROPN eurjchem-124 93 7 s s PROPN eurjchem-124 93 8 och3 och3 PROPN eurjchem-124 93 9 h2n h2n PROPN eurjchem-124 93 10 ( ( PUNCT eurjchem-124 93 11 1 1 NUM eurjchem-124 93 12 ) ) PUNCT eurjchem-124 93 13 ( ( PUNCT eurjchem-124 93 14 2 2 X eurjchem-124 93 15 ) ) PUNCT eurjchem-124 93 16 ( ( PUNCT eurjchem-124 93 17 3 3 X eurjchem-124 93 18 ) ) PUNCT eurjchem-124 93 19 ( ( PUNCT eurjchem-124 93 20 4 4 X eurjchem-124 93 21 ) ) PUNCT eurjchem-124 93 22 ( ( PUNCT eurjchem-124 93 23 5 5 NUM eurjchem-124 93 24 ) ) PUNCT eurjchem-124 93 25 ( ( PUNCT eurjchem-124 93 26 6 6 NUM eurjchem-124 93 27 ) ) PUNCT eurjchem-124 93 28 ( ( PUNCT eurjchem-124 93 29 7 7 NUM eurjchem-124 93 30 ) ) PUNCT eurjchem-124 93 31 ( ( PUNCT eurjchem-124 93 32 8 8 NUM eurjchem-124 93 33 ) ) PUNCT eurjchem-124 93 34 ( ( PUNCT eurjchem-124 93 35 9 9 NUM eurjchem-124 93 36 ) ) PUNCT eurjchem-124 93 37 ( ( PUNCT eurjchem-124 93 38 10 10 NUM eurjchem-124 93 39 ) ) PUNCT eurjchem-124 93 40 ( ( PUNCT eurjchem-124 93 41 11 11 NUM eurjchem-124 93 42 ) ) PUNCT eurjchem-124 93 43 ( ( PUNCT eurjchem-124 93 44 12 12 NUM eurjchem-124 93 45 ) ) PUNCT eurjchem-124 93 46     SPACE eurjchem-124 93 47 scheme scheme NOUN eurjchem-124 93 48     SPACE eurjchem-124 93 49 1 1 NUM eurjchem-124 93 50         SPACE eurjchem-124 93 51 ( ( PUNCT eurjchem-124 93 52 aromatic aromatic ADJ eurjchem-124 93 53     SPACE eurjchem-124 93 54 c c NOUN eurjchem-124 93 55 = = SYM eurjchem-124 93 56 c c NOUN eurjchem-124 93 57 ) ) PUNCT eurjchem-124 93 58 , , PUNCT eurjchem-124 93 59     SPACE eurjchem-124 93 60 1230 1230 NUM eurjchem-124 93 61     SPACE eurjchem-124 93 62 ( ( PUNCT eurjchem-124 93 63 c c NOUN eurjchem-124 93 64 = = SYM eurjchem-124 93 65 s s NOUN eurjchem-124 93 66 ) ) PUNCT eurjchem-124 93 67 . . PUNCT eurjchem-124 93 68     SPACE eurjchem-124 94 1 1h 1h NUM eurjchem-124 94 2     SPACE eurjchem-124 94 3 nmr nmr NOUN eurjchem-124 94 4     SPACE eurjchem-124 94 5 ( ( PUNCT eurjchem-124 94 6 300 300 NUM eurjchem-124 94 7     SPACE eurjchem-124 94 8 mhz mhz NOUN eurjchem-124 94 9 , , PUNCT eurjchem-124 94 10     SPACE eurjchem-124 94 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 94 12 ) ) PUNCT eurjchem-124 94 13     SPACE eurjchem-124 94 14 in in ADP eurjchem-124 94 15     SPACE eurjchem-124 94 16 δ δ PROPN eurjchem-124 94 17     SPACE eurjchem-124 94 18 ( ( PUNCT eurjchem-124 94 19 ppm ppm NOUN eurjchem-124 94 20 ) ) PUNCT eurjchem-124 94 21     SPACE eurjchem-124 94 22 and and CCONJ eurjchem-124 94 23     SPACE eurjchem-124 94 24 j j PROPN eurjchem-124 94 25     SPACE eurjchem-124 94 26 ( ( PUNCT eurjchem-124 94 27 hz hz PROPN eurjchem-124 94 28 ): ): PROPN eurjchem-124 94 29     SPACE eurjchem-124 94 30 11.41 11.41 NUM eurjchem-124 94 31     SPACE eurjchem-124 94 32 ( ( PUNCT eurjchem-124 94 33 1h 1h NUM eurjchem-124 94 34 , , PUNCT eurjchem-124 94 35     SPACE eurjchem-124 94 36 s s PROPN eurjchem-124 94 37 , , PUNCT eurjchem-124 94 38     SPACE eurjchem-124 94 39 broad broad ADJ eurjchem-124 94 40 , , PUNCT eurjchem-124 94 41     SPACE eurjchem-124 94 42 conh conh NOUN eurjchem-124 94 43 ) ) PUNCT eurjchem-124 94 44 , , PUNCT eurjchem-124 94 45     SPACE eurjchem-124 94 46 8.32 8.32 NUM eurjchem-124 94 47     SPACE eurjchem-124 94 48 ( ( PUNCT eurjchem-124 94 49 1h 1h NUM eurjchem-124 94 50 , , PUNCT eurjchem-124 94 51     SPACE eurjchem-124 94 52 dd dd NOUN eurjchem-124 94 53 , , PUNCT eurjchem-124 94 54     SPACE eurjchem-124 94 55 j1 j1 PROPN eurjchem-124 94 56     SPACE eurjchem-124 94 57 = = NOUN eurjchem-124 94 58     SPACE eurjchem-124 94 59 7.2 7.2 NUM eurjchem-124 94 60     SPACE eurjchem-124 94 61 hz hz VERB eurjchem-124 94 62 , , PUNCT eurjchem-124 94 63     SPACE eurjchem-124 94 64 j2 j2 PROPN eurjchem-124 94 65     SPACE eurjchem-124 94 66 = = NOUN eurjchem-124 94 67     SPACE eurjchem-124 94 68 8.1 8.1 NUM eurjchem-124 94 69     SPACE eurjchem-124 94 70 hz hz VERB eurjchem-124 94 71 , , PUNCT eurjchem-124 94 72       SPACE eurjchem-124 94 73 thiophene thiophene NOUN eurjchem-124 94 74     SPACE eurjchem-124 94 75 ch ch NOUN eurjchem-124 94 76 ) ) PUNCT eurjchem-124 94 77 , , PUNCT eurjchem-124 94 78     SPACE eurjchem-124 94 79 8.10 8.10 NUM eurjchem-124 94 80     SPACE eurjchem-124 94 81 ( ( PUNCT eurjchem-124 94 82 1h 1h NUM eurjchem-124 94 83 , , PUNCT eurjchem-124 94 84     SPACE eurjchem-124 94 85 dd dd NOUN eurjchem-124 94 86 , , PUNCT eurjchem-124 94 87     SPACE eurjchem-124 94 88 j1 j1 PROPN eurjchem-124 94 89     SPACE eurjchem-124 94 90 = = NOUN eurjchem-124 94 91     SPACE eurjchem-124 94 92 7.5 7.5 NUM eurjchem-124 94 93     SPACE eurjchem-124 94 94 hz hz VERB eurjchem-124 94 95 , , PUNCT eurjchem-124 94 96     SPACE eurjchem-124 94 97 j2 j2 PROPN eurjchem-124 94 98     SPACE eurjchem-124 94 99 = = NOUN eurjchem-124 94 100     SPACE eurjchem-124 94 101 8.2 8.2 NUM eurjchem-124 94 102     SPACE eurjchem-124 94 103 hz hz VERB eurjchem-124 94 104 , , PUNCT eurjchem-124 94 105     SPACE eurjchem-124 94 106 thiophene thiophene NOUN eurjchem-124 94 107     SPACE eurjchem-124 94 108 ch ch NOUN eurjchem-124 94 109 ) ) PUNCT eurjchem-124 94 110 , , PUNCT eurjchem-124 94 111     SPACE eurjchem-124 94 112 7.23 7.23 NUM eurjchem-124 94 113     SPACE eurjchem-124 94 114 ( ( PUNCT eurjchem-124 94 115 1h 1h NUM eurjchem-124 94 116 , , PUNCT eurjchem-124 94 117     SPACE eurjchem-124 94 118 dd dd VERB eurjchem-124 94 119 , , PUNCT eurjchem-124 94 120     SPACE eurjchem-124 94 121 j1 j1 PROPN eurjchem-124 94 122     SPACE eurjchem-124 94 123 = = NOUN eurjchem-124 94 124     SPACE eurjchem-124 94 125 6.7 6.7 NUM eurjchem-124 94 126     SPACE eurjchem-124 94 127 hz hz VERB eurjchem-124 94 128 , , PUNCT eurjchem-124 94 129     SPACE eurjchem-124 94 130 j2 j2 PROPN eurjchem-124 94 131     SPACE eurjchem-124 94 132 = = NOUN eurjchem-124 94 133     SPACE eurjchem-124 94 134 8.3 8.3 NUM eurjchem-124 94 135     SPACE eurjchem-124 94 136 hz hz VERB eurjchem-124 94 137 , , PUNCT eurjchem-124 94 138     SPACE eurjchem-124 94 139 thiophene thiophene NOUN eurjchem-124 94 140     SPACE eurjchem-124 94 141 ch ch NOUN eurjchem-124 94 142 ) ) PUNCT eurjchem-124 94 143 , , PUNCT eurjchem-124 94 144     SPACE eurjchem-124 94 145 7.63‐7.27 7.63‐7.27 NOUN eurjchem-124 94 146     SPACE eurjchem-124 94 147 ( ( PUNCT eurjchem-124 94 148 m m PROPN eurjchem-124 94 149 , , PUNCT eurjchem-124 94 150     SPACE eurjchem-124 94 151 10h 10h NUM eurjchem-124 94 152 , , PUNCT eurjchem-124 94 153     SPACE eurjchem-124 94 154 arom‐h arom‐h NOUN eurjchem-124 94 155 ) ) PUNCT eurjchem-124 94 156 . . PUNCT eurjchem-124 94 157     SPACE eurjchem-124 94 158 13c 13c NOUN eurjchem-124 94 159     SPACE eurjchem-124 94 160 nmr nmr NOUN eurjchem-124 94 161     SPACE eurjchem-124 94 162 ( ( PUNCT eurjchem-124 94 163 300 300 NUM eurjchem-124 94 164     SPACE eurjchem-124 94 165 mhz mhz NOUN eurjchem-124 94 166 , , PUNCT eurjchem-124 94 167     SPACE eurjchem-124 94 168 dmso‐d6 dmso‐d6 NOUN eurjchem-124 94 169 ) ) PUNCT eurjchem-124 94 170     SPACE eurjchem-124 94 171 in in ADP eurjchem-124 94 172     SPACE eurjchem-124 94 173 δ δ PROPN eurjchem-124 94 174     SPACE eurjchem-124 94 175 ( ( PUNCT eurjchem-124 94 176 ppm ppm PROPN eurjchem-124 94 177 ): ): PUNCT eurjchem-124 94 178     SPACE eurjchem-124 94 179 178.4 178.4 NUM eurjchem-124 94 180     SPACE eurjchem-124 94 181 ( ( PUNCT eurjchem-124 94 182 c c NOUN eurjchem-124 94 183 = = SYM eurjchem-124 94 184 s s NOUN eurjchem-124 94 185 ) ) PUNCT eurjchem-124 94 186 , , PUNCT eurjchem-124 94 187     SPACE eurjchem-124 94 188 162.5 162.5 NUM eurjchem-124 94 189     SPACE eurjchem-124 94 190 ( ( PUNCT eurjchem-124 94 191 c c NOUN eurjchem-124 94 192 = = NOUN eurjchem-124 94 193 o o NOUN eurjchem-124 94 194 ) ) PUNCT eurjchem-124 94 195 , , PUNCT eurjchem-124 94 196     SPACE eurjchem-124 94 197 136.3 136.3 NUM eurjchem-124 94 198     SPACE eurjchem-124 94 199 ( ( PUNCT eurjchem-124 94 200 c c NOUN eurjchem-124 94 201 ) ) PUNCT eurjchem-124 94 202 , , PUNCT eurjchem-124 94 203     SPACE eurjchem-124 94 204 133.1 133.1 NUM eurjchem-124 94 205     SPACE eurjchem-124 94 206 ( ( PUNCT eurjchem-124 94 207 c c NOUN eurjchem-124 94 208 ) ) PUNCT eurjchem-124 94 209 , , PUNCT eurjchem-124 94 210     SPACE eurjchem-124 94 211 131.4 131.4 NUM eurjchem-124 94 212     SPACE eurjchem-124 94 213 ( ( PUNCT eurjchem-124 94 214 c c NOUN eurjchem-124 94 215 ) ) PUNCT eurjchem-124 94 216 , , PUNCT eurjchem-124 94 217     SPACE eurjchem-124 94 218 129.1 129.1 NUM eurjchem-124 94 219     SPACE eurjchem-124 94 220 ( ( PUNCT eurjchem-124 94 221 c c NOUN eurjchem-124 94 222 ) ) PUNCT eurjchem-124 94 223 , , PUNCT eurjchem-124 94 224     SPACE eurjchem-124 94 225 128‐125.1 128‐125.1 NUM eurjchem-124 94 226     SPACE eurjchem-124 94 227 ( ( PUNCT eurjchem-124 94 228 phenyl phenyl NOUN eurjchem-124 94 229     SPACE eurjchem-124 94 230 carbons carbon NOUN eurjchem-124 94 231 ) ) PUNCT eurjchem-124 94 232 . . PUNCT eurjchem-124 94 233     SPACE eurjchem-124 95 1 ei ei PROPN eurjchem-124 95 2     SPACE eurjchem-124 95 3 ms ms NOUN eurjchem-124 95 4 , , PUNCT eurjchem-124 95 5     SPACE eurjchem-124 95 6 m m PROPN eurjchem-124 95 7 / / PROPN eurjchem-124 95 8 z z NOUN eurjchem-124 95 9     SPACE eurjchem-124 95 10 ( ( PUNCT eurjchem-124 95 11 % % INTJ eurjchem-124 95 12 ): ): PUNCT eurjchem-124 95 13     SPACE eurjchem-124 95 14 338 338 NUM eurjchem-124 95 15     SPACE eurjchem-124 95 16 ( ( PUNCT eurjchem-124 95 17 m+ m+ NUM eurjchem-124 95 18 , , PUNCT eurjchem-124 95 19     SPACE eurjchem-124 95 20 23 23 NUM eurjchem-124 95 21 ) ) PUNCT eurjchem-124 95 22 , , PUNCT eurjchem-124 95 23     SPACE eurjchem-124 95 24 228 228 NUM eurjchem-124 95 25     SPACE eurjchem-124 95 26 ( ( PUNCT eurjchem-124 95 27 4.3 4.3 NUM eurjchem-124 95 28 ) ) PUNCT eurjchem-124 95 29 , , PUNCT eurjchem-124 95 30     SPACE eurjchem-124 95 31 169 169 NUM eurjchem-124 95 32     SPACE eurjchem-124 95 33 ( ( PUNCT eurjchem-124 95 34 52 52 NUM eurjchem-124 95 35 ) ) PUNCT eurjchem-124 95 36 , , PUNCT eurjchem-124 95 37     SPACE eurjchem-124 95 38 141 141 NUM eurjchem-124 95 39     SPACE eurjchem-124 95 40 ( ( PUNCT eurjchem-124 95 41 3 3 NUM eurjchem-124 95 42 ) ) PUNCT eurjchem-124 95 43 , , PUNCT eurjchem-124 95 44     SPACE eurjchem-124 95 45 127 127 NUM eurjchem-124 95 46     SPACE eurjchem-124 95 47 ( ( PUNCT eurjchem-124 95 48 7.5 7.5 NUM eurjchem-124 95 49 ) ) PUNCT eurjchem-124 95 50 , , PUNCT eurjchem-124 95 51     SPACE eurjchem-124 95 52 111 111 NUM eurjchem-124 95 53     SPACE eurjchem-124 95 54 ( ( PUNCT eurjchem-124 95 55 100 100 NUM eurjchem-124 95 56 ) ) PUNCT eurjchem-124 95 57 , , PUNCT eurjchem-124 95 58     SPACE eurjchem-124 95 59 93 93 NUM eurjchem-124 95 60     SPACE eurjchem-124 95 61 ( ( PUNCT eurjchem-124 95 62 29.1 29.1 NUM eurjchem-124 95 63 ) ) PUNCT eurjchem-124 95 64 , , PUNCT eurjchem-124 95 65     SPACE eurjchem-124 95 66 84 84 NUM eurjchem-124 95 67     SPACE eurjchem-124 95 68 ( ( PUNCT eurjchem-124 95 69 62 62 NUM eurjchem-124 95 70 ) ) PUNCT eurjchem-124 95 71 . . PUNCT eurjchem-124 95 72     SPACE eurjchem-124 96 1 anal anal ADJ eurjchem-124 96 2 . . PUNCT eurjchem-124 96 3     SPACE eurjchem-124 96 4 calcd calcd NOUN eurjchem-124 96 5 . . PUNCT eurjchem-124 96 6     SPACE eurjchem-124 96 7 for for ADP eurjchem-124 96 8     SPACE eurjchem-124 96 9 c18h14n2os2 c18h14n2os2 NOUN eurjchem-124 96 10     SPACE eurjchem-124 96 11 : : PUNCT eurjchem-124 96 12     SPACE eurjchem-124 96 13 c c X eurjchem-124 96 14 , , PUNCT eurjchem-124 96 15     SPACE eurjchem-124 96 16 63.88 63.88 NUM eurjchem-124 96 17     SPACE eurjchem-124 96 18 ; ; PUNCT eurjchem-124 96 19 h h NOUN eurjchem-124 96 20 , , PUNCT eurjchem-124 96 21     SPACE eurjchem-124 96 22 4.17 4.17 NUM eurjchem-124 96 23 ; ; PUNCT eurjchem-124 96 24     SPACE eurjchem-124 96 25 n n CCONJ eurjchem-124 96 26 , , PUNCT eurjchem-124 96 27     SPACE eurjchem-124 96 28 8.28 8.28 NUM eurjchem-124 96 29 ; ; PUNCT eurjchem-124 96 30     SPACE eurjchem-124 96 31 s s PROPN eurjchem-124 96 32 , , PUNCT eurjchem-124 96 33     SPACE eurjchem-124 96 34 18.95 18.95 NUM eurjchem-124 96 35 . . PUNCT eurjchem-124 96 36     SPACE eurjchem-124 96 37 found find VERB eurjchem-124 96 38 : : PUNCT eurjchem-124 96 39     SPACE eurjchem-124 96 40 c c X eurjchem-124 96 41 , , PUNCT eurjchem-124 96 42     SPACE eurjchem-124 96 43 63.89 63.89 NUM eurjchem-124 96 44 ; ; PUNCT eurjchem-124 96 45     SPACE eurjchem-124 96 46 h h NOUN eurjchem-124 96 47 , , PUNCT eurjchem-124 96 48     SPACE eurjchem-124 96 49 4.18 4.18 NUM eurjchem-124 96 50 ; ; PUNCT eurjchem-124 96 51     SPACE eurjchem-124 96 52 n n CCONJ eurjchem-124 96 53 , , PUNCT eurjchem-124 96 54     SPACE eurjchem-124 96 55 8.28 8.28 NUM eurjchem-124 96 56 ; ; PUNCT eurjchem-124 96 57     SPACE eurjchem-124 96 58 s s PROPN eurjchem-124 96 59 , , PUNCT eurjchem-124 96 60     SPACE eurjchem-124 96 61 18.94 18.94 NUM eurjchem-124 96 62 . . PUNCT eurjchem-124 96 63           SPACE eurjchem-124 96 64 n­(4­methylphenyl)­n’­(thiophene­2­carbonyl)­thiourea n­(4­methylphenyl)­n’­(thiophene­2­carbonyl)­thiourea ADV eurjchem-124 96 65     SPACE eurjchem-124 96 66 ( ( PUNCT eurjchem-124 96 67 7 7 NUM eurjchem-124 96 68 ): ): SYM eurjchem-124 96 69     SPACE eurjchem-124 96 70 white white ADJ eurjchem-124 96 71     SPACE eurjchem-124 96 72 solid solid ADJ eurjchem-124 96 73 . . PUNCT eurjchem-124 96 74     SPACE eurjchem-124 96 75 yield yield NOUN eurjchem-124 96 76 : : PUNCT eurjchem-124 96 77     SPACE eurjchem-124 96 78 94 94 NUM eurjchem-124 96 79 % % NOUN eurjchem-124 96 80 . . PUNCT eurjchem-124 96 81     SPACE eurjchem-124 97 1 m.p m.p PROPN eurjchem-124 97 2 . . PROPN eurjchem-124 97 3 : : PUNCT eurjchem-124 97 4     SPACE eurjchem-124 97 5 158‐159 158‐159 NUM eurjchem-124 97 6     SPACE eurjchem-124 97 7 oc oc PROPN eurjchem-124 97 8 . . PUNCT eurjchem-124 97 9     SPACE eurjchem-124 97 10 ft‐ir ft‐ir NOUN eurjchem-124 97 11     SPACE eurjchem-124 97 12 ( ( PUNCT eurjchem-124 97 13 kbr kbr NOUN eurjchem-124 97 14     SPACE eurjchem-124 97 15 pellet pellet NOUN eurjchem-124 97 16 ) ) PUNCT eurjchem-124 97 17     SPACE eurjchem-124 97 18 in in ADP eurjchem-124 97 19     SPACE eurjchem-124 97 20 cm‐1 cm‐1 NOUN eurjchem-124 97 21 : : PUNCT eurjchem-124 97 22     SPACE eurjchem-124 97 23 3265 3265 NUM eurjchem-124 97 24 , , PUNCT eurjchem-124 97 25     SPACE eurjchem-124 97 26 3189 3189 NUM eurjchem-124 97 27     SPACE eurjchem-124 97 28 ( ( PUNCT eurjchem-124 97 29 n‐h n‐h NOUN eurjchem-124 97 30 ) ) PUNCT eurjchem-124 97 31 , , PUNCT eurjchem-124 97 32     SPACE eurjchem-124 97 33 3065‐3046 3065‐3046 NUM eurjchem-124 97 34     SPACE eurjchem-124 97 35 ( ( PUNCT eurjchem-124 97 36 c‐h c‐h X eurjchem-124 97 37 ) ) PUNCT eurjchem-124 97 38 , , PUNCT eurjchem-124 97 39     SPACE eurjchem-124 97 40 1678 1678 NUM eurjchem-124 97 41     SPACE eurjchem-124 97 42 ( ( PUNCT eurjchem-124 97 43 c c NOUN eurjchem-124 97 44 = = NOUN eurjchem-124 97 45 o o NOUN eurjchem-124 97 46 ) ) PUNCT eurjchem-124 97 47 , , PUNCT eurjchem-124 97 48     SPACE eurjchem-124 97 49 1591 1591 NUM eurjchem-124 97 50     SPACE eurjchem-124 97 51 ( ( PUNCT eurjchem-124 97 52 aromatic aromatic ADJ eurjchem-124 97 53     SPACE eurjchem-124 97 54 c c NOUN eurjchem-124 97 55 = = SYM eurjchem-124 97 56 c c NOUN eurjchem-124 97 57 ) ) PUNCT eurjchem-124 97 58 , , PUNCT eurjchem-124 97 59     SPACE eurjchem-124 97 60 1236 1236 NUM eurjchem-124 97 61     SPACE eurjchem-124 97 62 ( ( PUNCT eurjchem-124 97 63 c c NOUN eurjchem-124 97 64 = = SYM eurjchem-124 97 65 s s NOUN eurjchem-124 97 66 ) ) PUNCT eurjchem-124 97 67 . . PUNCT eurjchem-124 97 68     SPACE eurjchem-124 97 69 1h 1h NUM eurjchem-124 97 70     SPACE eurjchem-124 97 71 nmr nmr NOUN eurjchem-124 97 72     SPACE eurjchem-124 97 73 ( ( PUNCT eurjchem-124 97 74 300 300 NUM eurjchem-124 97 75     SPACE eurjchem-124 97 76 mhz mhz NOUN eurjchem-124 97 77 , , PUNCT eurjchem-124 97 78     SPACE eurjchem-124 97 79 dmso‐d6 dmso‐d6 NOUN eurjchem-124 97 80 ) ) PUNCT eurjchem-124 97 81     SPACE eurjchem-124 97 82 in in ADP eurjchem-124 97 83     SPACE eurjchem-124 97 84 δ δ PROPN eurjchem-124 97 85     SPACE eurjchem-124 97 86 ( ( PUNCT eurjchem-124 97 87 ppm ppm NOUN eurjchem-124 97 88 ) ) PUNCT eurjchem-124 97 89     SPACE eurjchem-124 97 90 and and CCONJ eurjchem-124 97 91     SPACE eurjchem-124 97 92 j j PROPN eurjchem-124 97 93     SPACE eurjchem-124 97 94 ( ( PUNCT eurjchem-124 97 95 hz hz PROPN eurjchem-124 97 96 ): ): PROPN eurjchem-124 97 97     SPACE eurjchem-124 97 98 12.36 12.36 NUM eurjchem-124 97 99     SPACE eurjchem-124 97 100 ( ( PUNCT eurjchem-124 97 101 1h 1h NUM eurjchem-124 97 102 , , PUNCT eurjchem-124 97 103     SPACE eurjchem-124 97 104 s s PROPN eurjchem-124 97 105 , , PUNCT eurjchem-124 97 106     SPACE eurjchem-124 97 107 csnh csnh NOUN eurjchem-124 97 108 ) ) PUNCT eurjchem-124 97 109 , , PUNCT eurjchem-124 97 110     SPACE eurjchem-124 97 111 11.53 11.53 NUM eurjchem-124 97 112     SPACE eurjchem-124 97 113 ( ( PUNCT eurjchem-124 97 114 1h 1h NUM eurjchem-124 97 115 , , PUNCT eurjchem-124 97 116     SPACE eurjchem-124 97 117 s s PROPN eurjchem-124 97 118 , , PUNCT eurjchem-124 97 119     SPACE eurjchem-124 97 120 conh conh NOUN eurjchem-124 97 121 ) ) PUNCT eurjchem-124 97 122 , , PUNCT eurjchem-124 97 123     SPACE eurjchem-124 97 124 8.36 8.36 NUM eurjchem-124 97 125     SPACE eurjchem-124 97 126 ( ( PUNCT eurjchem-124 97 127 1h 1h NUM eurjchem-124 97 128 , , PUNCT eurjchem-124 97 129     SPACE eurjchem-124 97 130 dd dd NOUN eurjchem-124 97 131 , , PUNCT eurjchem-124 97 132     SPACE eurjchem-124 97 133 j1 j1 PROPN eurjchem-124 97 134     SPACE eurjchem-124 98 1 = = NOUN eurjchem-124 98 2     SPACE eurjchem-124 98 3 7.2 7.2 NUM eurjchem-124 98 4     SPACE eurjchem-124 98 5 hz hz VERB eurjchem-124 98 6 , , PUNCT eurjchem-124 98 7     SPACE eurjchem-124 98 8 j2 j2 PROPN eurjchem-124 98 9     SPACE eurjchem-124 98 10 = = NOUN eurjchem-124 98 11     SPACE eurjchem-124 98 12 8.0 8.0 NUM eurjchem-124 98 13     SPACE eurjchem-124 98 14 hz hz VERB eurjchem-124 98 15 , , PUNCT eurjchem-124 98 16     SPACE eurjchem-124 98 17 thiophene thiophene NOUN eurjchem-124 98 18     SPACE eurjchem-124 98 19 ch ch NOUN eurjchem-124 98 20 ) ) PUNCT eurjchem-124 98 21 , , PUNCT eurjchem-124 98 22     SPACE eurjchem-124 99 1 8.01 8.01 NUM eurjchem-124 99 2     SPACE eurjchem-124 99 3 ( ( PUNCT eurjchem-124 99 4 1h 1h NUM eurjchem-124 99 5 , , PUNCT eurjchem-124 99 6     SPACE eurjchem-124 99 7 dd dd NOUN eurjchem-124 99 8 , , PUNCT eurjchem-124 99 9     SPACE eurjchem-124 99 10 j1 j1 PROPN eurjchem-124 99 11     SPACE eurjchem-124 99 12 = = NOUN eurjchem-124 99 13     SPACE eurjchem-124 99 14 7.5 7.5 NUM eurjchem-124 99 15     SPACE eurjchem-124 99 16 hz hz VERB eurjchem-124 99 17 , , PUNCT eurjchem-124 99 18     SPACE eurjchem-124 99 19 j2 j2 PROPN eurjchem-124 99 20     SPACE eurjchem-124 99 21 = = NOUN eurjchem-124 99 22     SPACE eurjchem-124 99 23 8.2 8.2 NUM eurjchem-124 99 24     SPACE eurjchem-124 99 25 hz hz VERB eurjchem-124 99 26 , , PUNCT eurjchem-124 99 27     SPACE eurjchem-124 99 28 thiophene thiophene NOUN eurjchem-124 99 29     SPACE eurjchem-124 99 30 ch ch NOUN eurjchem-124 99 31 ) ) PUNCT eurjchem-124 99 32 , , PUNCT eurjchem-124 99 33     SPACE eurjchem-124 99 34 7.20 7.20 NUM eurjchem-124 99 35     SPACE eurjchem-124 99 36 ( ( PUNCT eurjchem-124 99 37 1h 1h NUM eurjchem-124 99 38 , , PUNCT eurjchem-124 99 39     SPACE eurjchem-124 99 40 dd dd NOUN eurjchem-124 99 41 , , PUNCT eurjchem-124 99 42     SPACE eurjchem-124 99 43 j1 j1 PROPN eurjchem-124 99 44     SPACE eurjchem-124 100 1 = = NOUN eurjchem-124 100 2     SPACE eurjchem-124 100 3 6.7 6.7 NUM eurjchem-124 100 4     SPACE eurjchem-124 100 5 hz hz VERB eurjchem-124 100 6 , , PUNCT eurjchem-124 100 7     SPACE eurjchem-124 100 8 j2 j2 PROPN eurjchem-124 100 9     SPACE eurjchem-124 100 10 = = NOUN eurjchem-124 100 11     SPACE eurjchem-124 100 12 8.8 8.8 NUM eurjchem-124 100 13     SPACE eurjchem-124 100 14 hz hz VERB eurjchem-124 100 15 , , PUNCT eurjchem-124 100 16     SPACE eurjchem-124 100 17 thiophene thiophene NOUN eurjchem-124 100 18     SPACE eurjchem-124 100 19 ch ch NOUN eurjchem-124 100 20 ) ) PUNCT eurjchem-124 100 21 , , PUNCT eurjchem-124 100 22     SPACE eurjchem-124 100 23 7.74 7.74 NUM eurjchem-124 100 24     SPACE eurjchem-124 100 25 ( ( PUNCT eurjchem-124 100 26 2h 2h NUM eurjchem-124 100 27 , , PUNCT eurjchem-124 100 28     SPACE eurjchem-124 100 29 d d PROPN eurjchem-124 100 30 , , PUNCT eurjchem-124 100 31     SPACE eurjchem-124 100 32 j j PROPN eurjchem-124 100 33     SPACE eurjchem-124 100 34 = = NOUN eurjchem-124 100 35     SPACE eurjchem-124 100 36 8.1 8.1 NUM eurjchem-124 100 37     SPACE eurjchem-124 100 38 hz hz VERB eurjchem-124 100 39 , , PUNCT eurjchem-124 100 40     SPACE eurjchem-124 100 41 ar ar NOUN eurjchem-124 100 42     SPACE eurjchem-124 100 43 h h NOUN eurjchem-124 100 44 ) ) PUNCT eurjchem-124 100 45 , , PUNCT eurjchem-124 100 46     SPACE eurjchem-124 100 47 7.62 7.62 NUM eurjchem-124 100 48     SPACE eurjchem-124 100 49 ( ( PUNCT eurjchem-124 100 50 2h 2h NUM eurjchem-124 100 51 , , PUNCT eurjchem-124 100 52     SPACE eurjchem-124 100 53 d d PROPN eurjchem-124 100 54 , , PUNCT eurjchem-124 100 55     SPACE eurjchem-124 100 56 j j PROPN eurjchem-124 100 57     SPACE eurjchem-124 100 58 = = NOUN eurjchem-124 100 59     SPACE eurjchem-124 100 60 6.5 6.5 NUM eurjchem-124 100 61     SPACE eurjchem-124 100 62 hz hz VERB eurjchem-124 100 63 , , PUNCT eurjchem-124 100 64     SPACE eurjchem-124 100 65 ar ar NOUN eurjchem-124 100 66     SPACE eurjchem-124 100 67 h h NOUN eurjchem-124 100 68 ) ) PUNCT eurjchem-124 100 69 , , PUNCT eurjchem-124 100 70     SPACE eurjchem-124 100 71 2.31 2.31 NUM eurjchem-124 100 72     SPACE eurjchem-124 100 73 ( ( PUNCT eurjchem-124 100 74 3h 3h NUM eurjchem-124 100 75 , , PUNCT eurjchem-124 100 76     SPACE eurjchem-124 100 77 s s PROPN eurjchem-124 100 78 , , PUNCT eurjchem-124 100 79 ch3,ph ch3,ph PROPN eurjchem-124 100 80     SPACE eurjchem-124 100 81 ch3 ch3 PROPN eurjchem-124 100 82 ) ) PUNCT eurjchem-124 100 83 . . PUNCT eurjchem-124 100 84     SPACE eurjchem-124 101 1 13c 13c NOUN eurjchem-124 101 2     SPACE eurjchem-124 101 3 nmr nmr NOUN eurjchem-124 101 4     SPACE eurjchem-124 101 5 ( ( PUNCT eurjchem-124 101 6 300 300 NUM eurjchem-124 101 7     SPACE eurjchem-124 101 8 mhz mhz NOUN eurjchem-124 101 9 , , PUNCT eurjchem-124 101 10     SPACE eurjchem-124 101 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 101 12 ) ) PUNCT eurjchem-124 101 13     SPACE eurjchem-124 101 14 in in ADP eurjchem-124 101 15     SPACE eurjchem-124 101 16 δ δ PROPN eurjchem-124 101 17     SPACE eurjchem-124 101 18 ( ( PUNCT eurjchem-124 101 19 ppm ppm PROPN eurjchem-124 101 20 ): ): PUNCT eurjchem-124 101 21     SPACE eurjchem-124 101 22 178.9 178.9 NUM eurjchem-124 101 23     SPACE eurjchem-124 101 24 ( ( PUNCT eurjchem-124 101 25 c c PROPN eurjchem-124 101 26 = = SYM eurjchem-124 101 27 s s NOUN eurjchem-124 101 28 ) ) PUNCT eurjchem-124 101 29 , , PUNCT eurjchem-124 101 30     SPACE eurjchem-124 101 31 162.3 162.3 NUM eurjchem-124 101 32     SPACE eurjchem-124 101 33 ( ( PUNCT eurjchem-124 101 34 c c NOUN eurjchem-124 101 35 = = NOUN eurjchem-124 101 36 o o NOUN eurjchem-124 101 37 ) ) PUNCT eurjchem-124 101 38 , , PUNCT eurjchem-124 101 39     SPACE eurjchem-124 101 40 136.0 136.0 NUM eurjchem-124 101 41     SPACE eurjchem-124 101 42 ( ( PUNCT eurjchem-124 101 43 c c NOUN eurjchem-124 101 44 ) ) PUNCT eurjchem-124 101 45 , , PUNCT eurjchem-124 101 46     SPACE eurjchem-124 101 47 135.7 135.7 NUM eurjchem-124 101 48     SPACE eurjchem-124 101 49 ( ( PUNCT eurjchem-124 101 50 c c NOUN eurjchem-124 101 51 ) ) PUNCT eurjchem-124 101 52 , , PUNCT eurjchem-124 101 53     SPACE eurjchem-124 101 54 135.3 135.3 NUM eurjchem-124 101 55     SPACE eurjchem-124 101 56 ( ( PUNCT eurjchem-124 101 57 c c NOUN eurjchem-124 101 58 ) ) PUNCT eurjchem-124 101 59 , , PUNCT eurjchem-124 101 60     SPACE eurjchem-124 101 61 132.2 132.2 NUM eurjchem-124 101 62     SPACE eurjchem-124 101 63 ( ( PUNCT eurjchem-124 101 64 c c NOUN eurjchem-124 101 65 ) ) PUNCT eurjchem-124 101 66 , , PUNCT eurjchem-124 101 67     SPACE eurjchem-124 101 68 128.5 128.5 NUM eurjchem-124 101 69     SPACE eurjchem-124 101 70 ( ( PUNCT eurjchem-124 101 71 c c NOUN eurjchem-124 101 72 ) ) PUNCT eurjchem-124 101 73 , , PUNCT eurjchem-124 101 74     SPACE eurjchem-124 101 75 129.2 129.2 NUM eurjchem-124 101 76     SPACE eurjchem-124 101 77 ( ( PUNCT eurjchem-124 101 78 2c 2c NOUN eurjchem-124 101 79 ) ) PUNCT eurjchem-124 101 80 , , PUNCT eurjchem-124 101 81     SPACE eurjchem-124 101 82 128.6 128.6 NUM eurjchem-124 101 83     SPACE eurjchem-124 101 84 ( ( PUNCT eurjchem-124 101 85 c c NOUN eurjchem-124 101 86 ) ) PUNCT eurjchem-124 101 87 , , PUNCT eurjchem-124 101 88     SPACE eurjchem-124 101 89 124.1 124.1 NUM eurjchem-124 101 90     SPACE eurjchem-124 101 91 ( ( PUNCT eurjchem-124 101 92 c c NOUN eurjchem-124 101 93 ) ) PUNCT eurjchem-124 101 94 , , PUNCT eurjchem-124 101 95     SPACE eurjchem-124 101 96 20.5 20.5 NUM eurjchem-124 101 97     SPACE eurjchem-124 101 98 ( ( PUNCT eurjchem-124 101 99 ch3 ch3 PROPN eurjchem-124 101 100 ) ) PUNCT eurjchem-124 101 101 . . PUNCT eurjchem-124 101 102         SPACE eurjchem-124 102 1 ei ei PROPN eurjchem-124 102 2     SPACE eurjchem-124 102 3 ms ms PROPN eurjchem-124 102 4 , , PUNCT eurjchem-124 102 5     SPACE eurjchem-124 102 6 m m PROPN eurjchem-124 102 7 / / PROPN eurjchem-124 103 1 z z NOUN eurjchem-124 103 2     SPACE eurjchem-124 103 3 ( ( PUNCT eurjchem-124 103 4 % % INTJ eurjchem-124 103 5 ): ): PUNCT eurjchem-124 103 6     SPACE eurjchem-124 103 7 276 276 NUM eurjchem-124 103 8     SPACE eurjchem-124 103 9 ( ( PUNCT eurjchem-124 103 10 m+ m+ NUM eurjchem-124 103 11 , , PUNCT eurjchem-124 103 12     SPACE eurjchem-124 103 13 16 16 NUM eurjchem-124 103 14 ) ) PUNCT eurjchem-124 103 15 , , PUNCT eurjchem-124 103 16     SPACE eurjchem-124 103 17 242 242 NUM eurjchem-124 103 18     SPACE eurjchem-124 103 19 ( ( PUNCT eurjchem-124 103 20 6.3 6.3 NUM eurjchem-124 103 21 ) ) PUNCT eurjchem-124 103 22 , , PUNCT eurjchem-124 103 23     SPACE eurjchem-124 103 24 149 149 NUM eurjchem-124 103 25     SPACE eurjchem-124 103 26 ( ( PUNCT eurjchem-124 103 27 20 20 NUM eurjchem-124 103 28 ) ) PUNCT eurjchem-124 103 29 , , PUNCT eurjchem-124 103 30     SPACE eurjchem-124 103 31 127 127 NUM eurjchem-124 103 32     SPACE eurjchem-124 103 33 ( ( PUNCT eurjchem-124 103 34 7.5 7.5 NUM eurjchem-124 103 35 ) ) PUNCT eurjchem-124 103 36 , , PUNCT eurjchem-124 103 37     SPACE eurjchem-124 103 38 111 111 NUM eurjchem-124 103 39     SPACE eurjchem-124 103 40 ( ( PUNCT eurjchem-124 103 41 100 100 NUM eurjchem-124 103 42 ) ) PUNCT eurjchem-124 103 43 , , PUNCT eurjchem-124 103 44     SPACE eurjchem-124 103 45 106 106 NUM eurjchem-124 103 46     SPACE eurjchem-124 103 47 ( ( PUNCT eurjchem-124 103 48 3.8 3.8 NUM eurjchem-124 103 49 ) ) PUNCT eurjchem-124 103 50 , , PUNCT eurjchem-124 103 51     SPACE eurjchem-124 103 52 84 84 NUM eurjchem-124 103 53     SPACE eurjchem-124 103 54 ( ( PUNCT eurjchem-124 103 55 58 58 NUM eurjchem-124 103 56 ) ) PUNCT eurjchem-124 103 57 , , PUNCT eurjchem-124 103 58     SPACE eurjchem-124 103 59 15 15 NUM eurjchem-124 103 60     SPACE eurjchem-124 103 61 ( ( PUNCT eurjchem-124 103 62 6.1 6.1 NUM eurjchem-124 103 63 ) ) PUNCT eurjchem-124 103 64 . . PUNCT eurjchem-124 103 65     SPACE eurjchem-124 104 1 anal anal ADJ eurjchem-124 104 2 . . PUNCT eurjchem-124 104 3     SPACE eurjchem-124 104 4 calcd calcd NOUN eurjchem-124 104 5 . . PUNCT eurjchem-124 104 6     SPACE eurjchem-124 104 7 for for ADP eurjchem-124 104 8     SPACE eurjchem-124 104 9 c13h12n2os2 c13h12n2os2 NOUN eurjchem-124 104 10     SPACE eurjchem-124 104 11 : : PUNCT eurjchem-124 104 12     SPACE eurjchem-124 104 13 c c X eurjchem-124 104 14 , , PUNCT eurjchem-124 104 15     SPACE eurjchem-124 104 16 56.49 56.49 NUM eurjchem-124 104 17 ; ; PUNCT eurjchem-124 104 18     SPACE eurjchem-124 104 19 h h NOUN eurjchem-124 104 20 , , PUNCT eurjchem-124 104 21     SPACE eurjchem-124 104 22 4.38 4.38 NUM eurjchem-124 104 23 ; ; PUNCT eurjchem-124 104 24     SPACE eurjchem-124 104 25 n n CCONJ eurjchem-124 104 26 , , PUNCT eurjchem-124 104 27     SPACE eurjchem-124 104 28 10.14 10.14 NUM eurjchem-124 104 29 ; ; PUNCT eurjchem-124 104 30     SPACE eurjchem-124 104 31 s s PROPN eurjchem-124 104 32 , , PUNCT eurjchem-124 104 33     SPACE eurjchem-124 104 34 23.20 23.20 NUM eurjchem-124 104 35 . . PUNCT eurjchem-124 104 36     SPACE eurjchem-124 104 37 found find VERB eurjchem-124 104 38 : : PUNCT eurjchem-124 104 39     SPACE eurjchem-124 104 40 c c X eurjchem-124 104 41 , , PUNCT eurjchem-124 104 42     SPACE eurjchem-124 104 43 56.51 56.51 NUM eurjchem-124 104 44 ; ; PUNCT eurjchem-124 104 45     SPACE eurjchem-124 104 46 h h NOUN eurjchem-124 104 47 , , PUNCT eurjchem-124 104 48     SPACE eurjchem-124 104 49 4.40 4.40 NUM eurjchem-124 104 50 ; ; PUNCT eurjchem-124 104 51     SPACE eurjchem-124 104 52 n n CCONJ eurjchem-124 104 53 , , PUNCT eurjchem-124 104 54     SPACE eurjchem-124 104 55 10.14 10.14 NUM eurjchem-124 104 56 ; ; PUNCT eurjchem-124 104 57     SPACE eurjchem-124 104 58 s s PROPN eurjchem-124 104 59 , , PUNCT eurjchem-124 104 60     SPACE eurjchem-124 104 61 23.25 23.25 NUM eurjchem-124 104 62 . . PUNCT eurjchem-124 104 63         SPACE eurjchem-124 105 1 n­(naphthalene­2­yl)­n’­(thiophene­2­carbonyl)­thiourea n­(naphthalene­2­yl)­n’­(thiophene­2­carbonyl)­thiourea ADV eurjchem-124 105 2     SPACE eurjchem-124 105 3 ( ( PUNCT eurjchem-124 105 4 8) 8) NUM eurjchem-124 105 5 : : PUNCT eurjchem-124 105 6     SPACE eurjchem-124 105 7 white white ADJ eurjchem-124 105 8     SPACE eurjchem-124 105 9 solid solid ADJ eurjchem-124 105 10 . . PUNCT eurjchem-124 105 11     SPACE eurjchem-124 105 12 yield yield NOUN eurjchem-124 105 13 : : PUNCT eurjchem-124 105 14     SPACE eurjchem-124 105 15 93 93 NUM eurjchem-124 105 16 % % NOUN eurjchem-124 105 17 . . PUNCT eurjchem-124 105 18     SPACE eurjchem-124 106 1 m.p m.p PROPN eurjchem-124 106 2 . . PROPN eurjchem-124 106 3 : : PUNCT eurjchem-124 106 4     SPACE eurjchem-124 106 5 175‐176 175‐176 PROPN eurjchem-124 106 6     SPACE eurjchem-124 106 7 oc oc PROPN eurjchem-124 106 8 . . PUNCT eurjchem-124 106 9     SPACE eurjchem-124 106 10 ft‐ir ft‐ir NOUN eurjchem-124 106 11     SPACE eurjchem-124 106 12 ( ( PUNCT eurjchem-124 106 13 kbr kbr NOUN eurjchem-124 106 14     SPACE eurjchem-124 106 15 pellet pellet NOUN eurjchem-124 106 16 ) ) PUNCT eurjchem-124 106 17     SPACE eurjchem-124 106 18 in in ADP eurjchem-124 106 19     SPACE eurjchem-124 106 20 cm‐1 cm‐1 NOUN eurjchem-124 106 21 : : PUNCT eurjchem-124 106 22     SPACE eurjchem-124 106 23 3256 3256 NUM eurjchem-124 106 24 , , PUNCT eurjchem-124 106 25     SPACE eurjchem-124 106 26 3175 3175 NUM eurjchem-124 106 27     SPACE eurjchem-124 106 28 ( ( PUNCT eurjchem-124 106 29 nh nh NOUN eurjchem-124 106 30 ) ) PUNCT eurjchem-124 106 31 , , PUNCT eurjchem-124 106 32     SPACE eurjchem-124 106 33 3063‐3031 3063‐3031 NUM eurjchem-124 106 34     SPACE eurjchem-124 106 35 ( ( PUNCT eurjchem-124 106 36 c‐h c‐h PROPN eurjchem-124 106 37 ) ) PUNCT eurjchem-124 106 38 , , PUNCT eurjchem-124 106 39     SPACE eurjchem-124 106 40 1680 1680 NUM eurjchem-124 106 41     SPACE eurjchem-124 106 42 ( ( PUNCT eurjchem-124 106 43 c c NOUN eurjchem-124 106 44 = = NOUN eurjchem-124 106 45 o o NOUN eurjchem-124 106 46 ) ) PUNCT eurjchem-124 106 47 , , PUNCT eurjchem-124 106 48     SPACE eurjchem-124 106 49 1593 1593 NUM eurjchem-124 106 50     SPACE eurjchem-124 106 51 ( ( PUNCT eurjchem-124 106 52 aromatic aromatic ADJ eurjchem-124 106 53     SPACE eurjchem-124 106 54 c c NOUN eurjchem-124 106 55 = = SYM eurjchem-124 106 56 c c NOUN eurjchem-124 106 57 ) ) PUNCT eurjchem-124 106 58 , , PUNCT eurjchem-124 106 59     SPACE eurjchem-124 106 60 1234 1234 NUM eurjchem-124 106 61     SPACE eurjchem-124 106 62 ( ( PUNCT eurjchem-124 106 63 c c PROPN eurjchem-124 106 64 = = SYM eurjchem-124 106 65 s s NOUN eurjchem-124 106 66 ) ) PUNCT eurjchem-124 106 67 . . PUNCT eurjchem-124 106 68     SPACE eurjchem-124 107 1 1h 1h NUM eurjchem-124 107 2     SPACE eurjchem-124 107 3 nmr nmr NOUN eurjchem-124 107 4     SPACE eurjchem-124 107 5 ( ( PUNCT eurjchem-124 107 6 300 300 NUM eurjchem-124 107 7     SPACE eurjchem-124 107 8 mhz mhz NOUN eurjchem-124 107 9 , , PUNCT eurjchem-124 107 10     SPACE eurjchem-124 107 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 107 12 ) ) PUNCT eurjchem-124 107 13     SPACE eurjchem-124 107 14 in in ADP eurjchem-124 107 15     SPACE eurjchem-124 107 16 δ δ PROPN eurjchem-124 107 17     SPACE eurjchem-124 107 18 ( ( PUNCT eurjchem-124 107 19 ppm ppm NOUN eurjchem-124 107 20 ) ) PUNCT eurjchem-124 107 21     SPACE eurjchem-124 107 22 and and CCONJ eurjchem-124 107 23     SPACE eurjchem-124 107 24 j j PROPN eurjchem-124 107 25     SPACE eurjchem-124 107 26 ( ( PUNCT eurjchem-124 107 27 hz hz PROPN eurjchem-124 107 28 ): ): PROPN eurjchem-124 107 29     SPACE eurjchem-124 107 30 12.26 12.26 NUM eurjchem-124 107 31     SPACE eurjchem-124 107 32 ( ( PUNCT eurjchem-124 107 33 1h 1h NUM eurjchem-124 107 34 , , PUNCT eurjchem-124 107 35     SPACE eurjchem-124 107 36 s s PROPN eurjchem-124 107 37 , , PUNCT eurjchem-124 107 38     SPACE eurjchem-124 107 39 csnh csnh NOUN eurjchem-124 107 40 ) ) PUNCT eurjchem-124 107 41 , , PUNCT eurjchem-124 107 42     SPACE eurjchem-124 107 43 11.75 11.75 NUM eurjchem-124 107 44     SPACE eurjchem-124 107 45 ( ( PUNCT eurjchem-124 107 46 1h 1h NUM eurjchem-124 107 47 , , PUNCT eurjchem-124 107 48     SPACE eurjchem-124 107 49 s s PROPN eurjchem-124 107 50 , , PUNCT eurjchem-124 107 51 conh conh NOUN eurjchem-124 107 52 ) ) PUNCT eurjchem-124 107 53 , , PUNCT eurjchem-124 107 54     SPACE eurjchem-124 107 55 224 224 NUM eurjchem-124 107 56     SPACE eurjchem-124 107 57 saeed saeed PROPN eurjchem-124 107 58     SPACE eurjchem-124 107 59 et et PROPN eurjchem-124 107 60     SPACE eurjchem-124 107 61 al al PROPN eurjchem-124 107 62 . . PROPN eurjchem-124 107 63     SPACE eurjchem-124 107 64 / / SYM eurjchem-124 107 65     SPACE eurjchem-124 107 66 european european ADJ eurjchem-124 107 67     SPACE eurjchem-124 107 68 journal journal NOUN eurjchem-124 107 69     SPACE eurjchem-124 107 70 of of ADP eurjchem-124 107 71     SPACE eurjchem-124 107 72 chemistry chemistry NOUN eurjchem-124 107 73     SPACE eurjchem-124 107 74 1 1 NUM eurjchem-124 107 75     SPACE eurjchem-124 107 76 ( ( PUNCT eurjchem-124 107 77 3 3 NUM eurjchem-124 107 78 ) ) PUNCT eurjchem-124 107 79     SPACE eurjchem-124 107 80 ( ( PUNCT eurjchem-124 107 81 2010 2010 NUM eurjchem-124 107 82 ) ) PUNCT eurjchem-124 107 83     SPACE eurjchem-124 107 84 221­227 221­227 NUM eurjchem-124 107 85         SPACE eurjchem-124 107 86 8.32 8.32 NUM eurjchem-124 107 87     SPACE eurjchem-124 107 88 ( ( PUNCT eurjchem-124 107 89 1h 1h NUM eurjchem-124 107 90 , , PUNCT eurjchem-124 107 91     SPACE eurjchem-124 107 92 dd dd NOUN eurjchem-124 107 93 , , PUNCT eurjchem-124 107 94     SPACE eurjchem-124 107 95 j1 j1 PROPN eurjchem-124 107 96     SPACE eurjchem-124 107 97 = = NOUN eurjchem-124 107 98     SPACE eurjchem-124 107 99 7.2 7.2 NUM eurjchem-124 107 100     SPACE eurjchem-124 107 101 hz hz VERB eurjchem-124 107 102 , , PUNCT eurjchem-124 107 103     SPACE eurjchem-124 107 104 j2 j2 PROPN eurjchem-124 107 105     SPACE eurjchem-124 107 106 = = NOUN eurjchem-124 107 107     SPACE eurjchem-124 107 108 8.5 8.5 NUM eurjchem-124 107 109     SPACE eurjchem-124 107 110 hz hz VERB eurjchem-124 107 111 , , PUNCT eurjchem-124 107 112     SPACE eurjchem-124 107 113 thiophene thiophene NOUN eurjchem-124 107 114     SPACE eurjchem-124 107 115 ch ch NOUN eurjchem-124 107 116 ) ) PUNCT eurjchem-124 107 117 , , PUNCT eurjchem-124 107 118     SPACE eurjchem-124 107 119 8.04 8.04 NUM eurjchem-124 107 120     SPACE eurjchem-124 107 121 ( ( PUNCT eurjchem-124 107 122 1h 1h NUM eurjchem-124 107 123 , , PUNCT eurjchem-124 107 124     SPACE eurjchem-124 107 125 dd dd NOUN eurjchem-124 107 126 , , PUNCT eurjchem-124 107 127     SPACE eurjchem-124 107 128 j1 j1 PROPN eurjchem-124 107 129     SPACE eurjchem-124 107 130 = = NOUN eurjchem-124 107 131     SPACE eurjchem-124 107 132 7.5 7.5 NUM eurjchem-124 107 133     SPACE eurjchem-124 107 134 hz hz VERB eurjchem-124 107 135 , , PUNCT eurjchem-124 107 136     SPACE eurjchem-124 107 137 j2 j2 PROPN eurjchem-124 107 138     SPACE eurjchem-124 107 139 = = NOUN eurjchem-124 107 140     SPACE eurjchem-124 107 141 8.2 8.2 NUM eurjchem-124 107 142     SPACE eurjchem-124 107 143 hz hz VERB eurjchem-124 107 144 , , PUNCT eurjchem-124 107 145     SPACE eurjchem-124 107 146 thiophene thiophene NOUN eurjchem-124 107 147     SPACE eurjchem-124 107 148 ch ch NOUN eurjchem-124 107 149 ) ) PUNCT eurjchem-124 107 150 , , PUNCT eurjchem-124 107 151     SPACE eurjchem-124 107 152 7.24 7.24 NUM eurjchem-124 107 153     SPACE eurjchem-124 107 154 ( ( PUNCT eurjchem-124 107 155 1h 1h NUM eurjchem-124 107 156 , , PUNCT eurjchem-124 107 157     SPACE eurjchem-124 107 158 dd dd NOUN eurjchem-124 107 159 , , PUNCT eurjchem-124 107 160     SPACE eurjchem-124 107 161 j1 j1 PROPN eurjchem-124 107 162     SPACE eurjchem-124 108 1 = = NOUN eurjchem-124 108 2     SPACE eurjchem-124 108 3 6.7 6.7 NUM eurjchem-124 108 4     SPACE eurjchem-124 108 5 hz hz VERB eurjchem-124 108 6 , , PUNCT eurjchem-124 108 7     SPACE eurjchem-124 108 8 j2 j2 PROPN eurjchem-124 108 9     SPACE eurjchem-124 108 10 = = NOUN eurjchem-124 108 11     SPACE eurjchem-124 108 12 8.7 8.7 NUM eurjchem-124 108 13     SPACE eurjchem-124 108 14 hz hz VERB eurjchem-124 108 15 , , PUNCT eurjchem-124 108 16     SPACE eurjchem-124 108 17 thiophene thiophene NOUN eurjchem-124 108 18     SPACE eurjchem-124 108 19 ch ch NOUN eurjchem-124 108 20 ) ) PUNCT eurjchem-124 108 21 , , PUNCT eurjchem-124 108 22     SPACE eurjchem-124 108 23 7.95‐7.84 7.95‐7.84 NOUN eurjchem-124 108 24     SPACE eurjchem-124 108 25 ( ( PUNCT eurjchem-124 108 26 m m PROPN eurjchem-124 108 27 , , PUNCT eurjchem-124 108 28     SPACE eurjchem-124 108 29 7h 7h NUM eurjchem-124 108 30 , , PUNCT eurjchem-124 108 31     SPACE eurjchem-124 108 32 arom‐h arom‐h NOUN eurjchem-124 108 33 ) ) PUNCT eurjchem-124 108 34 . . PUNCT eurjchem-124 108 35     SPACE eurjchem-124 109 1 13c 13c NOUN eurjchem-124 109 2     SPACE eurjchem-124 109 3 nmr nmr NOUN eurjchem-124 109 4     SPACE eurjchem-124 109 5 ( ( PUNCT eurjchem-124 109 6 300 300 NUM eurjchem-124 109 7     SPACE eurjchem-124 109 8 mhz mhz NOUN eurjchem-124 109 9 , , PUNCT eurjchem-124 109 10     SPACE eurjchem-124 109 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 109 12 ) ) PUNCT eurjchem-124 109 13     SPACE eurjchem-124 109 14 in in ADP eurjchem-124 109 15     SPACE eurjchem-124 109 16 δ δ PROPN eurjchem-124 109 17     SPACE eurjchem-124 109 18 ( ( PUNCT eurjchem-124 109 19 ppm ppm PROPN eurjchem-124 109 20 ): ): PUNCT eurjchem-124 109 21     SPACE eurjchem-124 109 22 179.7 179.7 NUM eurjchem-124 109 23     SPACE eurjchem-124 109 24 ( ( PUNCT eurjchem-124 109 25 c c NOUN eurjchem-124 109 26 = = SYM eurjchem-124 109 27 s s NOUN eurjchem-124 109 28 ) ) PUNCT eurjchem-124 109 29 , , PUNCT eurjchem-124 109 30     SPACE eurjchem-124 109 31 164.3 164.3 NUM eurjchem-124 109 32     SPACE eurjchem-124 109 33 ( ( PUNCT eurjchem-124 109 34 c c NOUN eurjchem-124 109 35 = = NOUN eurjchem-124 109 36 o o NOUN eurjchem-124 109 37 ) ) PUNCT eurjchem-124 109 38 , , PUNCT eurjchem-124 109 39     SPACE eurjchem-124 109 40 136.5 136.5 NUM eurjchem-124 109 41     SPACE eurjchem-124 109 42 ( ( PUNCT eurjchem-124 109 43 c c NOUN eurjchem-124 109 44 ) ) PUNCT eurjchem-124 109 45 , , PUNCT eurjchem-124 109 46     SPACE eurjchem-124 109 47 134.3 134.3 NUM eurjchem-124 109 48     SPACE eurjchem-124 109 49 ( ( PUNCT eurjchem-124 109 50 c c NOUN eurjchem-124 109 51 ) ) PUNCT eurjchem-124 109 52 , , PUNCT eurjchem-124 109 53     SPACE eurjchem-124 109 54 133.4 133.4 NUM eurjchem-124 109 55     SPACE eurjchem-124 109 56 ( ( PUNCT eurjchem-124 109 57 c c NOUN eurjchem-124 109 58 ) ) PUNCT eurjchem-124 109 59 , , PUNCT eurjchem-124 109 60     SPACE eurjchem-124 109 61 132.5 132.5 NUM eurjchem-124 109 62     SPACE eurjchem-124 109 63 ( ( PUNCT eurjchem-124 109 64 c c NOUN eurjchem-124 109 65 ) ) PUNCT eurjchem-124 109 66 , , PUNCT eurjchem-124 109 67     SPACE eurjchem-124 109 68 129.2‐123.4 129.2‐123.4 NOUN eurjchem-124 109 69     SPACE eurjchem-124 109 70 ( ( PUNCT eurjchem-124 109 71 naphthalene naphthalene NOUN eurjchem-124 109 72     SPACE eurjchem-124 109 73 carbons carbon NOUN eurjchem-124 109 74 ) ) PUNCT eurjchem-124 109 75 . . PUNCT eurjchem-124 109 76     SPACE eurjchem-124 110 1 ei ei PROPN eurjchem-124 110 2     SPACE eurjchem-124 110 3 ms ms PROPN eurjchem-124 110 4 , , PUNCT eurjchem-124 110 5     SPACE eurjchem-124 110 6 m m PROPN eurjchem-124 110 7 / / PROPN eurjchem-124 111 1 z z NOUN eurjchem-124 111 2     SPACE eurjchem-124 111 3 ( ( PUNCT eurjchem-124 111 4 % % INTJ eurjchem-124 111 5 ): ): PUNCT eurjchem-124 111 6     SPACE eurjchem-124 111 7 312 312 NUM eurjchem-124 111 8     SPACE eurjchem-124 111 9 ( ( PUNCT eurjchem-124 111 10 m+ m+ NUM eurjchem-124 111 11 , , PUNCT eurjchem-124 111 12     SPACE eurjchem-124 111 13 18 18 NUM eurjchem-124 111 14 ) ) PUNCT eurjchem-124 111 15 , , PUNCT eurjchem-124 111 16     SPACE eurjchem-124 111 17 228 228 NUM eurjchem-124 111 18     SPACE eurjchem-124 111 19 ( ( PUNCT eurjchem-124 111 20 4.3 4.3 NUM eurjchem-124 111 21 ) ) PUNCT eurjchem-124 111 22 , , PUNCT eurjchem-124 111 23     SPACE eurjchem-124 111 24 169 169 NUM eurjchem-124 111 25     SPACE eurjchem-124 111 26 ( ( PUNCT eurjchem-124 111 27 52 52 NUM eurjchem-124 111 28 ) ) PUNCT eurjchem-124 111 29 , , PUNCT eurjchem-124 111 30     SPACE eurjchem-124 111 31 141 141 NUM eurjchem-124 111 32     SPACE eurjchem-124 111 33 ( ( PUNCT eurjchem-124 111 34 3 3 NUM eurjchem-124 111 35 ) ) PUNCT eurjchem-124 111 36 , , PUNCT eurjchem-124 111 37     SPACE eurjchem-124 111 38 127 127 NUM eurjchem-124 111 39     SPACE eurjchem-124 111 40 ( ( PUNCT eurjchem-124 111 41 7.5 7.5 NUM eurjchem-124 111 42 ) ) PUNCT eurjchem-124 111 43 , , PUNCT eurjchem-124 111 44     SPACE eurjchem-124 111 45 111 111 NUM eurjchem-124 111 46     SPACE eurjchem-124 111 47 ( ( PUNCT eurjchem-124 111 48 100 100 NUM eurjchem-124 111 49 ) ) PUNCT eurjchem-124 111 50 , , PUNCT eurjchem-124 111 51     SPACE eurjchem-124 111 52 93 93 NUM eurjchem-124 111 53     SPACE eurjchem-124 111 54 ( ( PUNCT eurjchem-124 111 55 29.1 29.1 NUM eurjchem-124 111 56 ) ) PUNCT eurjchem-124 111 57 , , PUNCT eurjchem-124 111 58     SPACE eurjchem-124 111 59 84 84 NUM eurjchem-124 111 60     SPACE eurjchem-124 111 61 ( ( PUNCT eurjchem-124 111 62 38 38 NUM eurjchem-124 111 63 ) ) PUNCT eurjchem-124 111 64 . . PUNCT eurjchem-124 111 65     SPACE eurjchem-124 112 1 anal anal ADJ eurjchem-124 112 2 . . PUNCT eurjchem-124 112 3     SPACE eurjchem-124 112 4 calcd calcd NOUN eurjchem-124 112 5 . . PUNCT eurjchem-124 112 6     SPACE eurjchem-124 112 7 for for ADP eurjchem-124 112 8     SPACE eurjchem-124 112 9 c16h12n2os2 c16h12n2os2 NOUN eurjchem-124 112 10     SPACE eurjchem-124 112 11 : : PUNCT eurjchem-124 112 12     SPACE eurjchem-124 112 13 c c X eurjchem-124 112 14 , , PUNCT eurjchem-124 112 15     SPACE eurjchem-124 112 16 61.51 61.51 NUM eurjchem-124 112 17 ; ; PUNCT eurjchem-124 112 18     SPACE eurjchem-124 112 19 h h NOUN eurjchem-124 112 20 , , PUNCT eurjchem-124 112 21     SPACE eurjchem-124 112 22 3.87 3.87 NUM eurjchem-124 112 23 ; ; PUNCT eurjchem-124 112 24     SPACE eurjchem-124 112 25 n n CCONJ eurjchem-124 112 26 , , PUNCT eurjchem-124 112 27     SPACE eurjchem-124 112 28 8.97 8.97 NUM eurjchem-124 112 29 ; ; PUNCT eurjchem-124 112 30     SPACE eurjchem-124 112 31 s s PROPN eurjchem-124 112 32 , , PUNCT eurjchem-124 112 33     SPACE eurjchem-124 112 34 20.53 20.53 NUM eurjchem-124 112 35 . . PUNCT eurjchem-124 112 36     SPACE eurjchem-124 112 37 found find VERB eurjchem-124 112 38 : : PUNCT eurjchem-124 112 39     SPACE eurjchem-124 112 40 c c X eurjchem-124 112 41 , , PUNCT eurjchem-124 112 42     SPACE eurjchem-124 112 43 61.53 61.53 NUM eurjchem-124 112 44 ; ; PUNCT eurjchem-124 112 45     SPACE eurjchem-124 112 46 h h NOUN eurjchem-124 112 47 , , PUNCT eurjchem-124 112 48     SPACE eurjchem-124 112 49 3.89 3.89 NUM eurjchem-124 112 50 ; ; PUNCT eurjchem-124 112 51     SPACE eurjchem-124 112 52 n n CCONJ eurjchem-124 112 53 , , PUNCT eurjchem-124 112 54     SPACE eurjchem-124 112 55 8.99 8.99 NUM eurjchem-124 112 56 ; ; PUNCT eurjchem-124 112 57     SPACE eurjchem-124 112 58 s s PROPN eurjchem-124 112 59 , , PUNCT eurjchem-124 112 60     SPACE eurjchem-124 112 61 20.52 20.52 NUM eurjchem-124 112 62 . . PUNCT eurjchem-124 112 63         SPACE eurjchem-124 112 64 n n CCONJ eurjchem-124 112 65 , , PUNCT eurjchem-124 112 66 n­diethyl­n’­(thiophene­2­carbonyl)­thiourea n­diethyl­n’­(thiophene­2­carbonyl)­thiourea PROPN eurjchem-124 112 67     SPACE eurjchem-124 112 68 ( ( PUNCT eurjchem-124 112 69 9 9 NUM eurjchem-124 112 70 ): ): SYM eurjchem-124 112 71     SPACE eurjchem-124 112 72 white white ADJ eurjchem-124 112 73     SPACE eurjchem-124 112 74 solid solid ADJ eurjchem-124 112 75 . . PUNCT eurjchem-124 112 76     SPACE eurjchem-124 112 77 yield yield NOUN eurjchem-124 112 78 : : PUNCT eurjchem-124 112 79     SPACE eurjchem-124 112 80 90 90 NUM eurjchem-124 112 81 % % NOUN eurjchem-124 112 82 . . PUNCT eurjchem-124 112 83     SPACE eurjchem-124 113 1 m.p m.p PROPN eurjchem-124 113 2 . . PROPN eurjchem-124 113 3 : : PUNCT eurjchem-124 113 4     SPACE eurjchem-124 113 5 136‐137 136‐137 NUM eurjchem-124 113 6     SPACE eurjchem-124 113 7 oc oc PROPN eurjchem-124 113 8 . . PUNCT eurjchem-124 113 9     SPACE eurjchem-124 113 10 ft‐ir ft‐ir NOUN eurjchem-124 113 11     SPACE eurjchem-124 113 12 ( ( PUNCT eurjchem-124 113 13 kbr kbr NOUN eurjchem-124 113 14     SPACE eurjchem-124 113 15 pellet pellet NOUN eurjchem-124 113 16 ) ) PUNCT eurjchem-124 113 17     SPACE eurjchem-124 113 18 in in ADP eurjchem-124 113 19     SPACE eurjchem-124 113 20 cm‐1 cm‐1 NOUN eurjchem-124 113 21 : : PUNCT eurjchem-124 113 22     SPACE eurjchem-124 113 23 3263 3263 NUM eurjchem-124 113 24 , , PUNCT eurjchem-124 113 25     SPACE eurjchem-124 113 26 3209 3209 NUM eurjchem-124 113 27     SPACE eurjchem-124 113 28 ( ( PUNCT eurjchem-124 113 29 n‐h n‐h NOUN eurjchem-124 113 30 ) ) PUNCT eurjchem-124 113 31 , , PUNCT eurjchem-124 113 32     SPACE eurjchem-124 113 33 3063‐3031 3063‐3031 NUM eurjchem-124 113 34     SPACE eurjchem-124 113 35 ( ( PUNCT eurjchem-124 113 36 c‐h c‐h NUM eurjchem-124 113 37 ) ) PUNCT eurjchem-124 113 38 , , PUNCT eurjchem-124 113 39     SPACE eurjchem-124 113 40 1675 1675 NUM eurjchem-124 113 41     SPACE eurjchem-124 113 42 ( ( PUNCT eurjchem-124 113 43 c c NOUN eurjchem-124 113 44 = = NOUN eurjchem-124 113 45 o o NOUN eurjchem-124 113 46 ) ) PUNCT eurjchem-124 113 47 , , PUNCT eurjchem-124 113 48     SPACE eurjchem-124 113 49 1593 1593 NUM eurjchem-124 113 50     SPACE eurjchem-124 113 51 ( ( PUNCT eurjchem-124 113 52 aromatic aromatic ADJ eurjchem-124 113 53     SPACE eurjchem-124 113 54 c c NOUN eurjchem-124 113 55 = = SYM eurjchem-124 113 56 c c NOUN eurjchem-124 113 57 ) ) PUNCT eurjchem-124 113 58 , , PUNCT eurjchem-124 113 59     SPACE eurjchem-124 113 60 1238 1238 NUM eurjchem-124 113 61     SPACE eurjchem-124 113 62 ( ( PUNCT eurjchem-124 113 63 c c NOUN eurjchem-124 113 64 = = SYM eurjchem-124 113 65 s s NOUN eurjchem-124 113 66 ) ) PUNCT eurjchem-124 113 67 . . PUNCT eurjchem-124 113 68     SPACE eurjchem-124 114 1 1h 1h NUM eurjchem-124 114 2     SPACE eurjchem-124 114 3 nmr nmr NOUN eurjchem-124 114 4     SPACE eurjchem-124 114 5 ( ( PUNCT eurjchem-124 114 6 300 300 NUM eurjchem-124 114 7     SPACE eurjchem-124 114 8 mhz mhz NOUN eurjchem-124 114 9 , , PUNCT eurjchem-124 114 10     SPACE eurjchem-124 114 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 114 12 ) ) PUNCT eurjchem-124 114 13     SPACE eurjchem-124 114 14 in in ADP eurjchem-124 114 15     SPACE eurjchem-124 114 16 δ δ PROPN eurjchem-124 114 17     SPACE eurjchem-124 114 18 ( ( PUNCT eurjchem-124 114 19 ppm ppm NOUN eurjchem-124 114 20 ) ) PUNCT eurjchem-124 114 21     SPACE eurjchem-124 114 22 and and CCONJ eurjchem-124 114 23     SPACE eurjchem-124 114 24 j j PROPN eurjchem-124 114 25     SPACE eurjchem-124 114 26 ( ( PUNCT eurjchem-124 114 27 hz hz PROPN eurjchem-124 114 28 ): ): PROPN eurjchem-124 114 29     SPACE eurjchem-124 114 30 11.43 11.43 NUM eurjchem-124 114 31     SPACE eurjchem-124 114 32 ( ( PUNCT eurjchem-124 114 33 1h 1h NUM eurjchem-124 114 34 , , PUNCT eurjchem-124 114 35     SPACE eurjchem-124 114 36 s s PROPN eurjchem-124 114 37 , , PUNCT eurjchem-124 114 38     SPACE eurjchem-124 114 39 conh conh NOUN eurjchem-124 114 40 ) ) PUNCT eurjchem-124 114 41 , , PUNCT eurjchem-124 114 42     SPACE eurjchem-124 114 43 8.2 8.2 NUM eurjchem-124 114 44     SPACE eurjchem-124 114 45 ( ( PUNCT eurjchem-124 114 46 1h 1h NUM eurjchem-124 114 47 , , PUNCT eurjchem-124 114 48     SPACE eurjchem-124 114 49 dd dd NOUN eurjchem-124 114 50 , , PUNCT eurjchem-124 114 51     SPACE eurjchem-124 114 52 j1 j1 PROPN eurjchem-124 114 53     SPACE eurjchem-124 114 54 = = NOUN eurjchem-124 114 55     SPACE eurjchem-124 114 56 7.2 7.2 NUM eurjchem-124 114 57     SPACE eurjchem-124 114 58 hz hz VERB eurjchem-124 114 59 , , PUNCT eurjchem-124 114 60         SPACE eurjchem-124 114 61 j2 j2 PROPN eurjchem-124 114 62     SPACE eurjchem-124 114 63 = = NOUN eurjchem-124 114 64     SPACE eurjchem-124 114 65 8.1 8.1 NUM eurjchem-124 114 66     SPACE eurjchem-124 114 67 hz hz VERB eurjchem-124 114 68 , , PUNCT eurjchem-124 114 69       SPACE eurjchem-124 114 70 thiophene thiophene NOUN eurjchem-124 114 71     SPACE eurjchem-124 114 72 ch ch NOUN eurjchem-124 114 73 ) ) PUNCT eurjchem-124 114 74 , , PUNCT eurjchem-124 114 75     SPACE eurjchem-124 114 76 8.02 8.02 NUM eurjchem-124 114 77     SPACE eurjchem-124 114 78 ( ( PUNCT eurjchem-124 114 79 1h 1h NUM eurjchem-124 114 80 , , PUNCT eurjchem-124 114 81     SPACE eurjchem-124 114 82 dd dd NOUN eurjchem-124 114 83 , , PUNCT eurjchem-124 114 84     SPACE eurjchem-124 114 85 j1 j1 PROPN eurjchem-124 114 86     SPACE eurjchem-124 114 87 = = NOUN eurjchem-124 114 88     SPACE eurjchem-124 114 89 7.5 7.5 NUM eurjchem-124 114 90     SPACE eurjchem-124 114 91 hz hz VERB eurjchem-124 114 92 , , PUNCT eurjchem-124 114 93     SPACE eurjchem-124 114 94 j2 j2 PROPN eurjchem-124 114 95     SPACE eurjchem-124 114 96 = = NOUN eurjchem-124 114 97     SPACE eurjchem-124 114 98 8.2 8.2 NUM eurjchem-124 114 99     SPACE eurjchem-124 114 100 hz hz VERB eurjchem-124 114 101 , , PUNCT eurjchem-124 114 102     SPACE eurjchem-124 114 103 thiophene thiophene NOUN eurjchem-124 114 104     SPACE eurjchem-124 114 105 ch ch NOUN eurjchem-124 114 106 ) ) PUNCT eurjchem-124 114 107 , , PUNCT eurjchem-124 114 108     SPACE eurjchem-124 114 109 7.03 7.03 NUM eurjchem-124 114 110     SPACE eurjchem-124 114 111 ( ( PUNCT eurjchem-124 114 112 1h 1h NUM eurjchem-124 114 113 , , PUNCT eurjchem-124 114 114     SPACE eurjchem-124 114 115 dd dd NOUN eurjchem-124 114 116 , , PUNCT eurjchem-124 114 117     SPACE eurjchem-124 114 118 j1 j1 PROPN eurjchem-124 114 119     SPACE eurjchem-124 114 120 = = NOUN eurjchem-124 114 121     SPACE eurjchem-124 114 122 6.7 6.7 NUM eurjchem-124 114 123     SPACE eurjchem-124 114 124 hz hz VERB eurjchem-124 114 125 , , PUNCT eurjchem-124 114 126     SPACE eurjchem-124 114 127 j2 j2 PROPN eurjchem-124 114 128     SPACE eurjchem-124 114 129 = = NOUN eurjchem-124 114 130     SPACE eurjchem-124 114 131 8.6 8.6 NUM eurjchem-124 114 132     SPACE eurjchem-124 114 133 hz hz VERB eurjchem-124 114 134 , , PUNCT eurjchem-124 114 135       SPACE eurjchem-124 114 136 thiophene thiophene NOUN eurjchem-124 114 137     SPACE eurjchem-124 114 138 ch ch NOUN eurjchem-124 114 139 ) ) PUNCT eurjchem-124 114 140 , , PUNCT eurjchem-124 114 141     SPACE eurjchem-124 114 142 2.16 2.16 NUM eurjchem-124 114 143     SPACE eurjchem-124 114 144 ( ( PUNCT eurjchem-124 114 145 4h 4h NOUN eurjchem-124 114 146 , , PUNCT eurjchem-124 114 147 q q NOUN eurjchem-124 114 148 , , PUNCT eurjchem-124 114 149     SPACE eurjchem-124 114 150 ‐ch2 ‐ch2 NOUN eurjchem-124 114 151 ) ) PUNCT eurjchem-124 114 152 , , PUNCT eurjchem-124 114 153     SPACE eurjchem-124 114 154 0.96 0.96 NUM eurjchem-124 114 155     SPACE eurjchem-124 114 156 ( ( PUNCT eurjchem-124 114 157 6h 6h NUM eurjchem-124 114 158 , , PUNCT eurjchem-124 114 159     SPACE eurjchem-124 114 160 t t PROPN eurjchem-124 114 161 , , PUNCT eurjchem-124 114 162     SPACE eurjchem-124 114 163 ‐ch3 ‐ch3 ADJ eurjchem-124 114 164     SPACE eurjchem-124 114 165 , , PUNCT eurjchem-124 114 166     SPACE eurjchem-124 114 167 j j PROPN eurjchem-124 114 168     SPACE eurjchem-124 114 169 = = NOUN eurjchem-124 114 170     SPACE eurjchem-124 114 171 7.1 7.1 NUM eurjchem-124 114 172     SPACE eurjchem-124 114 173 hz hz NOUN eurjchem-124 114 174 ) ) PUNCT eurjchem-124 114 175 . . PUNCT eurjchem-124 114 176     SPACE eurjchem-124 114 177 13c 13c NOUN eurjchem-124 114 178     SPACE eurjchem-124 114 179 nmr nmr NOUN eurjchem-124 114 180     SPACE eurjchem-124 114 181 ( ( PUNCT eurjchem-124 114 182 300 300 NUM eurjchem-124 114 183     SPACE eurjchem-124 114 184 mhz mhz NOUN eurjchem-124 114 185 , , PUNCT eurjchem-124 114 186     SPACE eurjchem-124 114 187 dmso‐d6 dmso‐d6 NOUN eurjchem-124 114 188 ) ) PUNCT eurjchem-124 114 189     SPACE eurjchem-124 114 190 in in ADP eurjchem-124 114 191     SPACE eurjchem-124 114 192 δ δ PROPN eurjchem-124 114 193     SPACE eurjchem-124 114 194 ( ( PUNCT eurjchem-124 114 195 ppm ppm PROPN eurjchem-124 114 196 ): ): PUNCT eurjchem-124 114 197     SPACE eurjchem-124 114 198 179.8 179.8 NUM eurjchem-124 114 199     SPACE eurjchem-124 114 200 ( ( PUNCT eurjchem-124 114 201 c c PROPN eurjchem-124 114 202 = = SYM eurjchem-124 114 203 s s NOUN eurjchem-124 114 204 ) ) PUNCT eurjchem-124 114 205 , , PUNCT eurjchem-124 114 206     SPACE eurjchem-124 114 207 170.1 170.1 NUM eurjchem-124 114 208     SPACE eurjchem-124 114 209 ( ( PUNCT eurjchem-124 114 210 c c NOUN eurjchem-124 114 211 = = NOUN eurjchem-124 114 212 o o NOUN eurjchem-124 114 213 ) ) PUNCT eurjchem-124 114 214 , , PUNCT eurjchem-124 114 215     SPACE eurjchem-124 114 216 135.3 135.3 NUM eurjchem-124 114 217     SPACE eurjchem-124 114 218 ( ( PUNCT eurjchem-124 114 219 c c NOUN eurjchem-124 114 220 ) ) PUNCT eurjchem-124 114 221 , , PUNCT eurjchem-124 114 222     SPACE eurjchem-124 114 223 133.7 133.7 NUM eurjchem-124 114 224     SPACE eurjchem-124 114 225 ( ( PUNCT eurjchem-124 114 226 c c NOUN eurjchem-124 114 227 ) ) PUNCT eurjchem-124 114 228 , , PUNCT eurjchem-124 114 229     SPACE eurjchem-124 114 230 132.5 132.5 NUM eurjchem-124 114 231     SPACE eurjchem-124 114 232 ( ( PUNCT eurjchem-124 114 233 c c NOUN eurjchem-124 114 234 ) ) PUNCT eurjchem-124 114 235 , , PUNCT eurjchem-124 114 236     SPACE eurjchem-124 114 237 132.0 132.0 NUM eurjchem-124 114 238     SPACE eurjchem-124 114 239 ( ( PUNCT eurjchem-124 114 240 c c NOUN eurjchem-124 114 241 ) ) PUNCT eurjchem-124 114 242 , , PUNCT eurjchem-124 114 243     SPACE eurjchem-124 114 244 34.2 34.2 NUM eurjchem-124 114 245     SPACE eurjchem-124 114 246 ( ( PUNCT eurjchem-124 114 247 2c 2c NOUN eurjchem-124 114 248 ) ) PUNCT eurjchem-124 114 249 , , PUNCT eurjchem-124 114 250     SPACE eurjchem-124 114 251 21.8 21.8 NUM eurjchem-124 114 252     SPACE eurjchem-124 114 253 ( ( PUNCT eurjchem-124 114 254 2c 2c NOUN eurjchem-124 114 255 ) ) PUNCT eurjchem-124 114 256 . . PUNCT eurjchem-124 114 257     SPACE eurjchem-124 115 1 ei ei PROPN eurjchem-124 115 2     SPACE eurjchem-124 115 3 ms ms PROPN eurjchem-124 115 4 , , PUNCT eurjchem-124 115 5     SPACE eurjchem-124 115 6 m m PROPN eurjchem-124 115 7 / / PROPN eurjchem-124 116 1 z z NOUN eurjchem-124 116 2     SPACE eurjchem-124 116 3 ( ( PUNCT eurjchem-124 116 4 % % INTJ eurjchem-124 116 5 ): ): PUNCT eurjchem-124 116 6     SPACE eurjchem-124 116 7 242 242 NUM eurjchem-124 116 8     SPACE eurjchem-124 116 9 ( ( PUNCT eurjchem-124 116 10 m+ m+ NUM eurjchem-124 116 11 , , PUNCT eurjchem-124 116 12     SPACE eurjchem-124 116 13 15 15 NUM eurjchem-124 116 14 ) ) PUNCT eurjchem-124 116 15 , , PUNCT eurjchem-124 116 16     SPACE eurjchem-124 116 17 217 217 NUM eurjchem-124 116 18     SPACE eurjchem-124 116 19 ( ( PUNCT eurjchem-124 116 20 3.4 3.4 NUM eurjchem-124 116 21 ) ) PUNCT eurjchem-124 116 22 , , PUNCT eurjchem-124 116 23     SPACE eurjchem-124 116 24 169 169 NUM eurjchem-124 116 25     SPACE eurjchem-124 116 26 ( ( PUNCT eurjchem-124 116 27 52 52 NUM eurjchem-124 116 28 ) ) PUNCT eurjchem-124 116 29 , , PUNCT eurjchem-124 116 30     SPACE eurjchem-124 116 31 141 141 NUM eurjchem-124 116 32     SPACE eurjchem-124 116 33 ( ( PUNCT eurjchem-124 116 34 4.7 4.7 NUM eurjchem-124 116 35 ) ) PUNCT eurjchem-124 116 36 , , PUNCT eurjchem-124 116 37     SPACE eurjchem-124 116 38 127(7.5 127(7.5 NUM eurjchem-124 116 39 ) ) PUNCT eurjchem-124 116 40 , , PUNCT eurjchem-124 116 41     SPACE eurjchem-124 116 42 111 111 NUM eurjchem-124 116 43     SPACE eurjchem-124 116 44 ( ( PUNCT eurjchem-124 116 45 100 100 NUM eurjchem-124 116 46 ) ) PUNCT eurjchem-124 116 47 , , PUNCT eurjchem-124 116 48     SPACE eurjchem-124 116 49 93 93 NUM eurjchem-124 116 50     SPACE eurjchem-124 116 51 ( ( PUNCT eurjchem-124 116 52 21.1 21.1 NUM eurjchem-124 116 53 ) ) PUNCT eurjchem-124 116 54 , , PUNCT eurjchem-124 116 55     SPACE eurjchem-124 116 56 84 84 NUM eurjchem-124 116 57     SPACE eurjchem-124 116 58 ( ( PUNCT eurjchem-124 116 59 45 45 NUM eurjchem-124 116 60 ) ) PUNCT eurjchem-124 116 61 , , PUNCT eurjchem-124 116 62     SPACE eurjchem-124 116 63 28 28 NUM eurjchem-124 116 64     SPACE eurjchem-124 116 65 ( ( PUNCT eurjchem-124 116 66 15 15 NUM eurjchem-124 116 67 ) ) PUNCT eurjchem-124 116 68 , , PUNCT eurjchem-124 116 69     SPACE eurjchem-124 116 70 15 15 NUM eurjchem-124 116 71     SPACE eurjchem-124 116 72 ( ( PUNCT eurjchem-124 116 73 3.4 3.4 NUM eurjchem-124 116 74 ) ) PUNCT eurjchem-124 116 75 . . PUNCT eurjchem-124 116 76     SPACE eurjchem-124 117 1 anal anal ADJ eurjchem-124 117 2 . . PUNCT eurjchem-124 117 3     SPACE eurjchem-124 117 4 calcd calcd NOUN eurjchem-124 117 5 . . PUNCT eurjchem-124 117 6     SPACE eurjchem-124 117 7 for for ADP eurjchem-124 117 8     SPACE eurjchem-124 117 9 c10h14n2os2 c10h14n2os2 NOUN eurjchem-124 117 10     SPACE eurjchem-124 117 11 : : PUNCT eurjchem-124 117 12     SPACE eurjchem-124 117 13 c c X eurjchem-124 117 14 , , PUNCT eurjchem-124 117 15     SPACE eurjchem-124 117 16 49.56 49.56 NUM eurjchem-124 117 17 ; ; PUNCT eurjchem-124 117 18     SPACE eurjchem-124 117 19 h h NOUN eurjchem-124 117 20 , , PUNCT eurjchem-124 117 21     SPACE eurjchem-124 117 22 5.82 5.82 NUM eurjchem-124 117 23 ; ; PUNCT eurjchem-124 117 24     SPACE eurjchem-124 117 25 n n CCONJ eurjchem-124 117 26 , , PUNCT eurjchem-124 117 27     SPACE eurjchem-124 117 28 11.56 11.56 NUM eurjchem-124 117 29 ; ; PUNCT eurjchem-124 117 30     SPACE eurjchem-124 117 31 s s PROPN eurjchem-124 117 32 , , PUNCT eurjchem-124 117 33     SPACE eurjchem-124 117 34 26.46 26.46 NUM eurjchem-124 117 35 . . PUNCT eurjchem-124 117 36     SPACE eurjchem-124 117 37 found find VERB eurjchem-124 117 38 : : PUNCT eurjchem-124 117 39     SPACE eurjchem-124 117 40 c c X eurjchem-124 117 41 , , PUNCT eurjchem-124 117 42     SPACE eurjchem-124 117 43 49.54 49.54 NUM eurjchem-124 117 44 ; ; PUNCT eurjchem-124 117 45     SPACE eurjchem-124 117 46 h h NOUN eurjchem-124 117 47 , , PUNCT eurjchem-124 117 48     SPACE eurjchem-124 117 49 5.86 5.86 NUM eurjchem-124 117 50 ; ; PUNCT eurjchem-124 117 51     SPACE eurjchem-124 117 52 n n CCONJ eurjchem-124 117 53 , , PUNCT eurjchem-124 117 54     SPACE eurjchem-124 117 55 11.53 11.53 NUM eurjchem-124 117 56 ; ; PUNCT eurjchem-124 117 57     SPACE eurjchem-124 117 58 s s PROPN eurjchem-124 117 59 , , PUNCT eurjchem-124 117 60     SPACE eurjchem-124 117 61 26.47 26.47 NUM eurjchem-124 117 62 . . PUNCT eurjchem-124 117 63         SPACE eurjchem-124 117 64 n­decyl­n’­(thiophene­2­carbonyl)­thiourea n­decyl­n’­(thiophene­2­carbonyl)­thiourea PROPN eurjchem-124 117 65     SPACE eurjchem-124 117 66 ( ( PUNCT eurjchem-124 117 67 10 10 NUM eurjchem-124 117 68 ): ): SYM eurjchem-124 117 69     SPACE eurjchem-124 117 70 light light ADJ eurjchem-124 117 71     SPACE eurjchem-124 117 72 yellow yellow ADJ eurjchem-124 117 73     SPACE eurjchem-124 117 74 solid solid ADJ eurjchem-124 117 75 . . PUNCT eurjchem-124 117 76     SPACE eurjchem-124 117 77 yield yield NOUN eurjchem-124 117 78 : : PUNCT eurjchem-124 117 79     SPACE eurjchem-124 117 80 88 88 NUM eurjchem-124 117 81 % % NOUN eurjchem-124 117 82 . . PUNCT eurjchem-124 117 83     SPACE eurjchem-124 118 1 m.p m.p PROPN eurjchem-124 118 2 . . PROPN eurjchem-124 118 3 : : PUNCT eurjchem-124 118 4     SPACE eurjchem-124 118 5 145‐146 145‐146 NUM eurjchem-124 118 6     SPACE eurjchem-124 118 7 oc oc PROPN eurjchem-124 118 8 . . PUNCT eurjchem-124 118 9     SPACE eurjchem-124 118 10 ft‐ir ft‐ir NOUN eurjchem-124 118 11     SPACE eurjchem-124 118 12 ( ( PUNCT eurjchem-124 118 13 kbr kbr NOUN eurjchem-124 118 14     SPACE eurjchem-124 118 15 pellet pellet NOUN eurjchem-124 118 16 ) ) PUNCT eurjchem-124 118 17     SPACE eurjchem-124 118 18 in in ADP eurjchem-124 118 19     SPACE eurjchem-124 118 20 cm‐1 cm‐1 NOUN eurjchem-124 118 21 : : PUNCT eurjchem-124 118 22     SPACE eurjchem-124 118 23 3263 3263 NUM eurjchem-124 118 24 , , PUNCT eurjchem-124 118 25     SPACE eurjchem-124 118 26 3209 3209 NUM eurjchem-124 118 27     SPACE eurjchem-124 118 28 ( ( PUNCT eurjchem-124 118 29 n‐h n‐h NOUN eurjchem-124 118 30 ) ) PUNCT eurjchem-124 118 31 , , PUNCT eurjchem-124 118 32     SPACE eurjchem-124 118 33 3063‐3031 3063‐3031 NUM eurjchem-124 118 34     SPACE eurjchem-124 118 35 ( ( PUNCT eurjchem-124 118 36 c‐h c‐h NUM eurjchem-124 118 37 ) ) PUNCT eurjchem-124 118 38 , , PUNCT eurjchem-124 118 39     SPACE eurjchem-124 118 40 1670 1670 NUM eurjchem-124 118 41     SPACE eurjchem-124 118 42 ( ( PUNCT eurjchem-124 118 43 c c NOUN eurjchem-124 118 44 = = NOUN eurjchem-124 118 45 o o NOUN eurjchem-124 118 46 ) ) PUNCT eurjchem-124 118 47 , , PUNCT eurjchem-124 118 48     SPACE eurjchem-124 118 49 1593 1593 NUM eurjchem-124 118 50     SPACE eurjchem-124 118 51 ( ( PUNCT eurjchem-124 118 52 aromatic aromatic ADJ eurjchem-124 118 53     SPACE eurjchem-124 118 54 c c NOUN eurjchem-124 118 55 = = SYM eurjchem-124 118 56 c c NOUN eurjchem-124 118 57 ) ) PUNCT eurjchem-124 118 58 , , PUNCT eurjchem-124 118 59     SPACE eurjchem-124 118 60 1237 1237 NUM eurjchem-124 118 61     SPACE eurjchem-124 118 62 ( ( PUNCT eurjchem-124 118 63 c c X eurjchem-124 118 64 = = SYM eurjchem-124 118 65 s s NOUN eurjchem-124 118 66 ) ) PUNCT eurjchem-124 118 67 . . PUNCT eurjchem-124 118 68     SPACE eurjchem-124 119 1 1h 1h NUM eurjchem-124 119 2     SPACE eurjchem-124 119 3 nmr nmr NOUN eurjchem-124 119 4     SPACE eurjchem-124 119 5 ( ( PUNCT eurjchem-124 119 6 300 300 NUM eurjchem-124 119 7     SPACE eurjchem-124 119 8 mhz mhz NOUN eurjchem-124 119 9 , , PUNCT eurjchem-124 119 10     SPACE eurjchem-124 119 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 119 12 ) ) PUNCT eurjchem-124 119 13     SPACE eurjchem-124 119 14 in in ADP eurjchem-124 119 15     SPACE eurjchem-124 119 16 δ δ PROPN eurjchem-124 119 17     SPACE eurjchem-124 119 18 ( ( PUNCT eurjchem-124 119 19 ppm ppm NOUN eurjchem-124 119 20 ) ) PUNCT eurjchem-124 119 21     SPACE eurjchem-124 119 22 and and CCONJ eurjchem-124 119 23     SPACE eurjchem-124 119 24 j j PROPN eurjchem-124 119 25     SPACE eurjchem-124 119 26 ( ( PUNCT eurjchem-124 119 27 hz hz PROPN eurjchem-124 119 28 ): ): PROPN eurjchem-124 119 29     SPACE eurjchem-124 119 30 12.43 12.43 NUM eurjchem-124 119 31     SPACE eurjchem-124 119 32 ( ( PUNCT eurjchem-124 119 33 1h 1h NUM eurjchem-124 119 34 , , PUNCT eurjchem-124 119 35     SPACE eurjchem-124 119 36 s s PROPN eurjchem-124 119 37 , , PUNCT eurjchem-124 119 38     SPACE eurjchem-124 119 39 csnh csnh NOUN eurjchem-124 119 40 ) ) PUNCT eurjchem-124 119 41 , , PUNCT eurjchem-124 119 42     SPACE eurjchem-124 119 43 11.53 11.53 NUM eurjchem-124 119 44     SPACE eurjchem-124 119 45 ( ( PUNCT eurjchem-124 119 46 1h 1h NUM eurjchem-124 119 47 , , PUNCT eurjchem-124 119 48     SPACE eurjchem-124 119 49 s s PROPN eurjchem-124 119 50 , , PUNCT eurjchem-124 119 51     SPACE eurjchem-124 119 52 conh conh NOUN eurjchem-124 119 53 ) ) PUNCT eurjchem-124 119 54 , , PUNCT eurjchem-124 119 55     SPACE eurjchem-124 119 56 8.2 8.2 NUM eurjchem-124 119 57     SPACE eurjchem-124 119 58 ( ( PUNCT eurjchem-124 119 59 1h 1h NUM eurjchem-124 119 60 , , PUNCT eurjchem-124 119 61     SPACE eurjchem-124 119 62 dd dd VERB eurjchem-124 119 63 , , PUNCT eurjchem-124 119 64     SPACE eurjchem-124 119 65 j1 j1 PROPN eurjchem-124 119 66     SPACE eurjchem-124 119 67 = = NOUN eurjchem-124 119 68     SPACE eurjchem-124 119 69 7.2 7.2 NUM eurjchem-124 119 70     SPACE eurjchem-124 119 71 hz hz VERB eurjchem-124 119 72 , , PUNCT eurjchem-124 119 73     SPACE eurjchem-124 119 74 j2 j2 PROPN eurjchem-124 119 75     SPACE eurjchem-124 119 76 = = NOUN eurjchem-124 119 77     SPACE eurjchem-124 119 78 8.1 8.1 NUM eurjchem-124 119 79     SPACE eurjchem-124 119 80 hz hz VERB eurjchem-124 119 81 , , PUNCT eurjchem-124 119 82         SPACE eurjchem-124 119 83 thiophene thiophene NOUN eurjchem-124 119 84     SPACE eurjchem-124 119 85 ch ch NOUN eurjchem-124 119 86 ) ) PUNCT eurjchem-124 119 87 , , PUNCT eurjchem-124 119 88     SPACE eurjchem-124 119 89 8.02 8.02 NUM eurjchem-124 119 90     SPACE eurjchem-124 119 91 ( ( PUNCT eurjchem-124 119 92 1h 1h NUM eurjchem-124 119 93 , , PUNCT eurjchem-124 119 94     SPACE eurjchem-124 119 95 dd dd NOUN eurjchem-124 119 96 , , PUNCT eurjchem-124 119 97               SPACE eurjchem-124 119 98 j1 j1 PROPN eurjchem-124 119 99     SPACE eurjchem-124 120 1 = = NOUN eurjchem-124 120 2     SPACE eurjchem-124 120 3 7.5 7.5 NUM eurjchem-124 120 4     SPACE eurjchem-124 120 5 hz hz VERB eurjchem-124 120 6 , , PUNCT eurjchem-124 120 7     SPACE eurjchem-124 120 8 j2 j2 PROPN eurjchem-124 120 9     SPACE eurjchem-124 120 10 = = NOUN eurjchem-124 120 11     SPACE eurjchem-124 120 12 8.2 8.2 NUM eurjchem-124 120 13     SPACE eurjchem-124 120 14 hz hz VERB eurjchem-124 120 15 , , PUNCT eurjchem-124 120 16     SPACE eurjchem-124 120 17 thiophene thiophene NOUN eurjchem-124 120 18     SPACE eurjchem-124 120 19 ch ch NOUN eurjchem-124 120 20 ) ) PUNCT eurjchem-124 120 21 , , PUNCT eurjchem-124 120 22     SPACE eurjchem-124 120 23 7.03 7.03 NUM eurjchem-124 120 24     SPACE eurjchem-124 120 25 ( ( PUNCT eurjchem-124 120 26 1h 1h NUM eurjchem-124 120 27 , , PUNCT eurjchem-124 120 28     SPACE eurjchem-124 120 29 dd dd NOUN eurjchem-124 120 30 , , PUNCT eurjchem-124 120 31     SPACE eurjchem-124 120 32 j1 j1 PROPN eurjchem-124 120 33     SPACE eurjchem-124 120 34 = = NOUN eurjchem-124 120 35     SPACE eurjchem-124 120 36 6.7 6.7 NUM eurjchem-124 120 37     SPACE eurjchem-124 120 38 hz hz VERB eurjchem-124 120 39 , , PUNCT eurjchem-124 120 40     SPACE eurjchem-124 120 41 j2 j2 PROPN eurjchem-124 120 42     SPACE eurjchem-124 120 43 = = NOUN eurjchem-124 120 44     SPACE eurjchem-124 120 45 8.6 8.6 NUM eurjchem-124 120 46     SPACE eurjchem-124 120 47 hz hz VERB eurjchem-124 120 48 , , PUNCT eurjchem-124 120 49     SPACE eurjchem-124 120 50 thiophene thiophene NOUN eurjchem-124 120 51     SPACE eurjchem-124 120 52 ch ch NOUN eurjchem-124 120 53 ) ) PUNCT eurjchem-124 120 54 , , PUNCT eurjchem-124 120 55     SPACE eurjchem-124 120 56 2.17 2.17 NUM eurjchem-124 120 57     SPACE eurjchem-124 120 58 ( ( PUNCT eurjchem-124 120 59 2h 2h NUM eurjchem-124 120 60 , , PUNCT eurjchem-124 120 61     SPACE eurjchem-124 120 62 t t PROPN eurjchem-124 120 63 , , PUNCT eurjchem-124 120 64     SPACE eurjchem-124 120 65 ‐nch2 ‐nch2 NOUN eurjchem-124 120 66 ) ) PUNCT eurjchem-124 120 67 , , PUNCT eurjchem-124 120 68     SPACE eurjchem-124 120 69 1.45‐1.14 1.45‐1.14 NUM eurjchem-124 120 70     SPACE eurjchem-124 120 71 ( ( PUNCT eurjchem-124 120 72 2h 2h NUM eurjchem-124 120 73 , , PUNCT eurjchem-124 120 74 m m NOUN eurjchem-124 120 75 , , PUNCT eurjchem-124 120 76     SPACE eurjchem-124 120 77 ch2 ch2 PROPN eurjchem-124 120 78 ) ) PUNCT eurjchem-124 120 79 , , PUNCT eurjchem-124 120 80     SPACE eurjchem-124 120 81 0.93 0.93 NUM eurjchem-124 120 82     SPACE eurjchem-124 120 83 ( ( PUNCT eurjchem-124 120 84 3h 3h NUM eurjchem-124 120 85 , , PUNCT eurjchem-124 120 86     SPACE eurjchem-124 120 87 t t PROPN eurjchem-124 120 88 , , PUNCT eurjchem-124 120 89     SPACE eurjchem-124 120 90 ‐ch3 ‐ch3 ADJ eurjchem-124 120 91 , , PUNCT eurjchem-124 120 92     SPACE eurjchem-124 120 93 j j PROPN eurjchem-124 120 94     SPACE eurjchem-124 120 95 = = NOUN eurjchem-124 120 96     SPACE eurjchem-124 120 97 7.1 7.1 NUM eurjchem-124 120 98     SPACE eurjchem-124 120 99 hz hz NOUN eurjchem-124 120 100 ) ) PUNCT eurjchem-124 120 101 . . PUNCT eurjchem-124 120 102     SPACE eurjchem-124 120 103 13c 13c NOUN eurjchem-124 120 104     SPACE eurjchem-124 120 105 nmr nmr NOUN eurjchem-124 120 106     SPACE eurjchem-124 120 107 ( ( PUNCT eurjchem-124 120 108 300 300 NUM eurjchem-124 120 109     SPACE eurjchem-124 120 110 mhz mhz NOUN eurjchem-124 120 111 , , PUNCT eurjchem-124 120 112     SPACE eurjchem-124 120 113 dmso‐d6 dmso‐d6 NOUN eurjchem-124 120 114 ) ) PUNCT eurjchem-124 120 115     SPACE eurjchem-124 120 116 in in ADP eurjchem-124 120 117     SPACE eurjchem-124 120 118 δ δ PROPN eurjchem-124 120 119     SPACE eurjchem-124 120 120 ( ( PUNCT eurjchem-124 120 121 ppm ppm PROPN eurjchem-124 120 122 ): ): PUNCT eurjchem-124 120 123     SPACE eurjchem-124 120 124 179.6 179.6 NUM eurjchem-124 120 125     SPACE eurjchem-124 120 126 ( ( PUNCT eurjchem-124 120 127 c c PROPN eurjchem-124 120 128 = = SYM eurjchem-124 120 129 s s NOUN eurjchem-124 120 130 ) ) PUNCT eurjchem-124 120 131 , , PUNCT eurjchem-124 120 132     SPACE eurjchem-124 120 133 169.8 169.8 NUM eurjchem-124 120 134     SPACE eurjchem-124 120 135 ( ( PUNCT eurjchem-124 120 136 c c NOUN eurjchem-124 120 137 = = NOUN eurjchem-124 120 138 o o NOUN eurjchem-124 120 139 ) ) PUNCT eurjchem-124 120 140 , , PUNCT eurjchem-124 120 141     SPACE eurjchem-124 120 142 135.3 135.3 NUM eurjchem-124 120 143     SPACE eurjchem-124 120 144 ( ( PUNCT eurjchem-124 120 145 c c NOUN eurjchem-124 120 146 ) ) PUNCT eurjchem-124 120 147 , , PUNCT eurjchem-124 120 148     SPACE eurjchem-124 120 149 133.7 133.7 NUM eurjchem-124 120 150     SPACE eurjchem-124 120 151 ( ( PUNCT eurjchem-124 120 152 c c NOUN eurjchem-124 120 153 ) ) PUNCT eurjchem-124 120 154 , , PUNCT eurjchem-124 120 155     SPACE eurjchem-124 120 156 132.5 132.5 NUM eurjchem-124 120 157     SPACE eurjchem-124 120 158 ( ( PUNCT eurjchem-124 120 159 c c NOUN eurjchem-124 120 160 ) ) PUNCT eurjchem-124 120 161 , , PUNCT eurjchem-124 120 162     SPACE eurjchem-124 120 163 132.0 132.0 NUM eurjchem-124 120 164     SPACE eurjchem-124 120 165 ( ( PUNCT eurjchem-124 120 166 c c NOUN eurjchem-124 120 167 ) ) PUNCT eurjchem-124 120 168 , , PUNCT eurjchem-124 120 169     SPACE eurjchem-124 120 170 34.2 34.2 NUM eurjchem-124 120 171     SPACE eurjchem-124 120 172 ( ( PUNCT eurjchem-124 120 173 2c 2c NOUN eurjchem-124 120 174 ) ) PUNCT eurjchem-124 120 175 , , PUNCT eurjchem-124 120 176     SPACE eurjchem-124 120 177 21.8 21.8 NUM eurjchem-124 120 178     SPACE eurjchem-124 120 179 ( ( PUNCT eurjchem-124 120 180 2c 2c NOUN eurjchem-124 120 181 ) ) PUNCT eurjchem-124 120 182 . . PUNCT eurjchem-124 120 183     SPACE eurjchem-124 121 1 ei ei PROPN eurjchem-124 121 2     SPACE eurjchem-124 121 3 ms ms PROPN eurjchem-124 121 4 , , PUNCT eurjchem-124 121 5     SPACE eurjchem-124 121 6 m m PROPN eurjchem-124 121 7 / / PROPN eurjchem-124 122 1 z z NOUN eurjchem-124 122 2     SPACE eurjchem-124 122 3 ( ( PUNCT eurjchem-124 122 4 % % INTJ eurjchem-124 122 5 ): ): PUNCT eurjchem-124 122 6     SPACE eurjchem-124 122 7 326 326 NUM eurjchem-124 122 8     SPACE eurjchem-124 122 9 ( ( PUNCT eurjchem-124 122 10 m+ m+ NUM eurjchem-124 122 11 , , PUNCT eurjchem-124 122 12     SPACE eurjchem-124 122 13 15 15 NUM eurjchem-124 122 14 ) ) PUNCT eurjchem-124 122 15 , , PUNCT eurjchem-124 122 16     SPACE eurjchem-124 122 17 217 217 NUM eurjchem-124 122 18     SPACE eurjchem-124 122 19 ( ( PUNCT eurjchem-124 122 20 3.4 3.4 NUM eurjchem-124 122 21 ) ) PUNCT eurjchem-124 122 22 , , PUNCT eurjchem-124 122 23     SPACE eurjchem-124 122 24 169 169 NUM eurjchem-124 122 25     SPACE eurjchem-124 122 26 ( ( PUNCT eurjchem-124 122 27 52 52 NUM eurjchem-124 122 28 ) ) PUNCT eurjchem-124 122 29 , , PUNCT eurjchem-124 122 30     SPACE eurjchem-124 122 31 141 141 NUM eurjchem-124 122 32     SPACE eurjchem-124 122 33 ( ( PUNCT eurjchem-124 122 34 4.7 4.7 NUM eurjchem-124 122 35 ) ) PUNCT eurjchem-124 122 36 , , PUNCT eurjchem-124 122 37     SPACE eurjchem-124 122 38 127 127 NUM eurjchem-124 122 39     SPACE eurjchem-124 122 40 ( ( PUNCT eurjchem-124 122 41 7.5 7.5 NUM eurjchem-124 122 42 ) ) PUNCT eurjchem-124 122 43 , , PUNCT eurjchem-124 122 44     SPACE eurjchem-124 122 45 111 111 NUM eurjchem-124 122 46     SPACE eurjchem-124 122 47 ( ( PUNCT eurjchem-124 122 48 100 100 NUM eurjchem-124 122 49 ) ) PUNCT eurjchem-124 122 50 , , PUNCT eurjchem-124 122 51     SPACE eurjchem-124 122 52 93 93 NUM eurjchem-124 122 53     SPACE eurjchem-124 122 54 ( ( PUNCT eurjchem-124 122 55 21.1 21.1 NUM eurjchem-124 122 56 ) ) PUNCT eurjchem-124 122 57 , , PUNCT eurjchem-124 122 58     SPACE eurjchem-124 122 59 84 84 NUM eurjchem-124 122 60     SPACE eurjchem-124 122 61 ( ( PUNCT eurjchem-124 122 62 45 45 NUM eurjchem-124 122 63 ) ) PUNCT eurjchem-124 122 64 , , PUNCT eurjchem-124 122 65     SPACE eurjchem-124 122 66 28 28 NUM eurjchem-124 122 67     SPACE eurjchem-124 122 68 ( ( PUNCT eurjchem-124 122 69 15 15 NUM eurjchem-124 122 70 ) ) PUNCT eurjchem-124 122 71 , , PUNCT eurjchem-124 122 72     SPACE eurjchem-124 122 73 15 15 NUM eurjchem-124 122 74     SPACE eurjchem-124 122 75 ( ( PUNCT eurjchem-124 122 76 3.4 3.4 NUM eurjchem-124 122 77 ) ) PUNCT eurjchem-124 122 78 . . PUNCT eurjchem-124 122 79     SPACE eurjchem-124 123 1 anal anal ADJ eurjchem-124 123 2 . . PUNCT eurjchem-124 123 3     SPACE eurjchem-124 123 4 calcd calcd NOUN eurjchem-124 123 5 . . PUNCT eurjchem-124 123 6     SPACE eurjchem-124 124 1 for for ADP eurjchem-124 124 2     SPACE eurjchem-124 124 3 c16h26n2os2 c16h26n2os2 NOUN eurjchem-124 124 4     SPACE eurjchem-124 124 5 : : PUNCT eurjchem-124 124 6     SPACE eurjchem-124 124 7 c c X eurjchem-124 124 8 , , PUNCT eurjchem-124 124 9     SPACE eurjchem-124 124 10 58.85 58.85 NUM eurjchem-124 124 11 ; ; PUNCT eurjchem-124 124 12     SPACE eurjchem-124 124 13 h h NOUN eurjchem-124 124 14 , , PUNCT eurjchem-124 124 15     SPACE eurjchem-124 124 16 8.03 8.03 NUM eurjchem-124 124 17 ; ; PUNCT eurjchem-124 124 18     SPACE eurjchem-124 124 19 n n CCONJ eurjchem-124 124 20 , , PUNCT eurjchem-124 124 21     SPACE eurjchem-124 124 22 8.58 8.58 NUM eurjchem-124 124 23 ; ; PUNCT eurjchem-124 124 24     SPACE eurjchem-124 124 25 s s PROPN eurjchem-124 124 26 , , PUNCT eurjchem-124 124 27     SPACE eurjchem-124 124 28 19.64 19.64 NUM eurjchem-124 124 29 . . PUNCT eurjchem-124 124 30     SPACE eurjchem-124 124 31 found find VERB eurjchem-124 124 32 : : PUNCT eurjchem-124 124 33     SPACE eurjchem-124 124 34 c c X eurjchem-124 124 35 , , PUNCT eurjchem-124 124 36     SPACE eurjchem-124 124 37 58.83 58.83 NUM eurjchem-124 124 38 ; ; PUNCT eurjchem-124 124 39     SPACE eurjchem-124 124 40 h h NOUN eurjchem-124 124 41 , , PUNCT eurjchem-124 124 42     SPACE eurjchem-124 124 43 8.15 8.15 NUM eurjchem-124 124 44 ; ; PUNCT eurjchem-124 124 45     SPACE eurjchem-124 124 46 n n CCONJ eurjchem-124 124 47 , , PUNCT eurjchem-124 124 48     SPACE eurjchem-124 124 49 8.59 8.59 NUM eurjchem-124 124 50 ; ; PUNCT eurjchem-124 124 51     SPACE eurjchem-124 124 52 s s PROPN eurjchem-124 124 53 , , PUNCT eurjchem-124 124 54     SPACE eurjchem-124 124 55 19.65 19.65 NUM eurjchem-124 124 56 . . PUNCT eurjchem-124 124 57         SPACE eurjchem-124 125 1 n­(dipropylcarbamothioyl)thiophene­2­carboxamide n­(dipropylcarbamothioyl)thiophene­2­carboxamide ADV eurjchem-124 125 2     SPACE eurjchem-124 125 3 ( ( PUNCT eurjchem-124 125 4 11 11 NUM eurjchem-124 125 5 ): ): SYM eurjchem-124 125 6     SPACE eurjchem-124 125 7 white white ADJ eurjchem-124 125 8     SPACE eurjchem-124 125 9 solid solid ADJ eurjchem-124 125 10 . . PUNCT eurjchem-124 125 11     SPACE eurjchem-124 125 12 yield yield NOUN eurjchem-124 125 13 : : PUNCT eurjchem-124 125 14     SPACE eurjchem-124 125 15 86 86 NUM eurjchem-124 125 16 % % NOUN eurjchem-124 125 17 . . PUNCT eurjchem-124 125 18     SPACE eurjchem-124 126 1 m.p m.p PROPN eurjchem-124 126 2 . . PROPN eurjchem-124 126 3 : : PUNCT eurjchem-124 126 4     SPACE eurjchem-124 126 5 135‐136 135‐136 ADJ eurjchem-124 126 6     SPACE eurjchem-124 126 7 oc oc PROPN eurjchem-124 126 8 . . PUNCT eurjchem-124 126 9     SPACE eurjchem-124 126 10 ft‐ir ft‐ir NOUN eurjchem-124 126 11     SPACE eurjchem-124 126 12 ( ( PUNCT eurjchem-124 126 13 kbr kbr NOUN eurjchem-124 126 14     SPACE eurjchem-124 126 15 pellet pellet NOUN eurjchem-124 126 16 ) ) PUNCT eurjchem-124 126 17     SPACE eurjchem-124 126 18 in in ADP eurjchem-124 126 19     SPACE eurjchem-124 126 20 cm‐1 cm‐1 NOUN eurjchem-124 126 21 : : PUNCT eurjchem-124 126 22     SPACE eurjchem-124 126 23 3261 3261 NUM eurjchem-124 126 24     SPACE eurjchem-124 126 25 ( ( PUNCT eurjchem-124 126 26 n‐h n‐h NOUN eurjchem-124 126 27 ) ) PUNCT eurjchem-124 126 28 , , PUNCT eurjchem-124 126 29     SPACE eurjchem-124 126 30 3064‐3031 3064‐3031 NUM eurjchem-124 126 31     SPACE eurjchem-124 126 32 ( ( PUNCT eurjchem-124 126 33 c‐h c‐h X eurjchem-124 126 34 ) ) PUNCT eurjchem-124 126 35 , , PUNCT eurjchem-124 126 36     SPACE eurjchem-124 126 37 1673 1673 NUM eurjchem-124 126 38     SPACE eurjchem-124 126 39 ( ( PUNCT eurjchem-124 126 40 c c NOUN eurjchem-124 126 41 = = NOUN eurjchem-124 126 42 o o NOUN eurjchem-124 126 43 ) ) PUNCT eurjchem-124 126 44 , , PUNCT eurjchem-124 126 45     SPACE eurjchem-124 126 46 1590 1590 NUM eurjchem-124 126 47     SPACE eurjchem-124 126 48 ( ( PUNCT eurjchem-124 126 49 aromatic aromatic ADJ eurjchem-124 126 50     SPACE eurjchem-124 126 51 c c NOUN eurjchem-124 126 52 = = SYM eurjchem-124 126 53 c c NOUN eurjchem-124 126 54 ) ) PUNCT eurjchem-124 126 55 , , PUNCT eurjchem-124 126 56     SPACE eurjchem-124 126 57 1236 1236 NUM eurjchem-124 126 58     SPACE eurjchem-124 126 59 ( ( PUNCT eurjchem-124 126 60 c c NOUN eurjchem-124 126 61 = = SYM eurjchem-124 126 62 s s NOUN eurjchem-124 126 63 ) ) PUNCT eurjchem-124 126 64 . . PUNCT eurjchem-124 126 65     SPACE eurjchem-124 127 1 1h 1h NUM eurjchem-124 127 2     SPACE eurjchem-124 127 3 nmr nmr NOUN eurjchem-124 127 4     SPACE eurjchem-124 127 5 ( ( PUNCT eurjchem-124 127 6 300 300 NUM eurjchem-124 127 7     SPACE eurjchem-124 127 8 mhz mhz NOUN eurjchem-124 127 9 , , PUNCT eurjchem-124 127 10     SPACE eurjchem-124 127 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 127 12 ) ) PUNCT eurjchem-124 127 13     SPACE eurjchem-124 127 14 in in ADP eurjchem-124 127 15     SPACE eurjchem-124 127 16 δ δ PROPN eurjchem-124 127 17     SPACE eurjchem-124 127 18 ( ( PUNCT eurjchem-124 127 19 ppm ppm NOUN eurjchem-124 127 20 ) ) PUNCT eurjchem-124 127 21     SPACE eurjchem-124 127 22 and and CCONJ eurjchem-124 127 23     SPACE eurjchem-124 127 24 j j PROPN eurjchem-124 127 25     SPACE eurjchem-124 127 26 ( ( PUNCT eurjchem-124 127 27 hz hz PROPN eurjchem-124 127 28 ): ): PROPN eurjchem-124 127 29     SPACE eurjchem-124 127 30 11.48 11.48 NUM eurjchem-124 127 31     SPACE eurjchem-124 127 32 ( ( PUNCT eurjchem-124 127 33 1h 1h NUM eurjchem-124 127 34 , , PUNCT eurjchem-124 127 35     SPACE eurjchem-124 127 36 s s PROPN eurjchem-124 127 37 , , PUNCT eurjchem-124 127 38     SPACE eurjchem-124 127 39 conh conh NOUN eurjchem-124 127 40 ) ) PUNCT eurjchem-124 127 41 , , PUNCT eurjchem-124 127 42     SPACE eurjchem-124 127 43 8.2 8.2 NUM eurjchem-124 127 44     SPACE eurjchem-124 127 45 ( ( PUNCT eurjchem-124 127 46 1h 1h NUM eurjchem-124 127 47 , , PUNCT eurjchem-124 127 48     SPACE eurjchem-124 127 49 dd dd NOUN eurjchem-124 127 50 , , PUNCT eurjchem-124 127 51     SPACE eurjchem-124 127 52 j1 j1 PROPN eurjchem-124 127 53     SPACE eurjchem-124 127 54 = = NOUN eurjchem-124 127 55     SPACE eurjchem-124 127 56 7.2 7.2 NUM eurjchem-124 127 57     SPACE eurjchem-124 127 58 hz hz VERB eurjchem-124 127 59 , , PUNCT eurjchem-124 127 60       SPACE eurjchem-124 127 61 j2 j2 PROPN eurjchem-124 127 62     SPACE eurjchem-124 127 63 = = NOUN eurjchem-124 127 64     SPACE eurjchem-124 127 65 8.1 8.1 NUM eurjchem-124 127 66     SPACE eurjchem-124 127 67 hz hz VERB eurjchem-124 127 68 , , PUNCT eurjchem-124 127 69       SPACE eurjchem-124 127 70 thiophene thiophene NOUN eurjchem-124 127 71     SPACE eurjchem-124 127 72 ch ch NOUN eurjchem-124 127 73 ) ) PUNCT eurjchem-124 127 74 , , PUNCT eurjchem-124 127 75     SPACE eurjchem-124 127 76 8.02 8.02 NUM eurjchem-124 127 77     SPACE eurjchem-124 127 78 ( ( PUNCT eurjchem-124 127 79 1h 1h NUM eurjchem-124 127 80 , , PUNCT eurjchem-124 127 81     SPACE eurjchem-124 127 82 dd dd NOUN eurjchem-124 127 83 , , PUNCT eurjchem-124 127 84     SPACE eurjchem-124 127 85 j1 j1 PROPN eurjchem-124 127 86     SPACE eurjchem-124 127 87 = = NOUN eurjchem-124 127 88     SPACE eurjchem-124 127 89 7.5 7.5 NUM eurjchem-124 127 90     SPACE eurjchem-124 127 91 hz hz VERB eurjchem-124 127 92 , , PUNCT eurjchem-124 127 93     SPACE eurjchem-124 127 94 j2 j2 PROPN eurjchem-124 127 95     SPACE eurjchem-124 127 96 = = NOUN eurjchem-124 127 97     SPACE eurjchem-124 127 98 8.2 8.2 NUM eurjchem-124 127 99     SPACE eurjchem-124 127 100 hz hz VERB eurjchem-124 127 101 , , PUNCT eurjchem-124 127 102     SPACE eurjchem-124 127 103 thiophene thiophene NOUN eurjchem-124 127 104     SPACE eurjchem-124 127 105 ch ch NOUN eurjchem-124 127 106 ) ) PUNCT eurjchem-124 127 107 , , PUNCT eurjchem-124 127 108     SPACE eurjchem-124 127 109 7.03 7.03 NUM eurjchem-124 127 110     SPACE eurjchem-124 127 111 ( ( PUNCT eurjchem-124 127 112 1h 1h NUM eurjchem-124 127 113 , , PUNCT eurjchem-124 127 114     SPACE eurjchem-124 127 115 dd dd NOUN eurjchem-124 127 116 , , PUNCT eurjchem-124 127 117     SPACE eurjchem-124 127 118 j1 j1 PROPN eurjchem-124 127 119     SPACE eurjchem-124 127 120 = = NOUN eurjchem-124 127 121     SPACE eurjchem-124 127 122 6.7 6.7 NUM eurjchem-124 127 123     SPACE eurjchem-124 127 124 hz hz VERB eurjchem-124 127 125 , , PUNCT eurjchem-124 127 126     SPACE eurjchem-124 127 127 j2 j2 PROPN eurjchem-124 127 128     SPACE eurjchem-124 127 129 = = NOUN eurjchem-124 127 130     SPACE eurjchem-124 127 131 8.6 8.6 NUM eurjchem-124 127 132     SPACE eurjchem-124 127 133 hz hz VERB eurjchem-124 127 134 , , PUNCT eurjchem-124 127 135       SPACE eurjchem-124 127 136 thiophene thiophene NOUN eurjchem-124 127 137     SPACE eurjchem-124 127 138 ch ch NOUN eurjchem-124 127 139 ) ) PUNCT eurjchem-124 127 140 , , PUNCT eurjchem-124 127 141     SPACE eurjchem-124 127 142 2.45 2.45 NUM eurjchem-124 127 143     SPACE eurjchem-124 127 144 ( ( PUNCT eurjchem-124 127 145 4h 4h NOUN eurjchem-124 127 146 , , PUNCT eurjchem-124 127 147     SPACE eurjchem-124 127 148 q q NOUN eurjchem-124 127 149 , , PUNCT eurjchem-124 127 150     SPACE eurjchem-124 127 151 ‐nch2 ‐nch2 NOUN eurjchem-124 127 152 ) ) PUNCT eurjchem-124 127 153 , , PUNCT eurjchem-124 127 154         SPACE eurjchem-124 127 155 1.15 1.15 NUM eurjchem-124 127 156     SPACE eurjchem-124 127 157 ( ( PUNCT eurjchem-124 127 158 4h 4h NOUN eurjchem-124 127 159 , , PUNCT eurjchem-124 127 160     SPACE eurjchem-124 127 161 m m PROPN eurjchem-124 127 162 , , PUNCT eurjchem-124 127 163     SPACE eurjchem-124 127 164 ‐ch2 ‐ch2 NUM eurjchem-124 127 165 ) ) PUNCT eurjchem-124 127 166 , , PUNCT eurjchem-124 127 167     SPACE eurjchem-124 127 168 0.95 0.95 NUM eurjchem-124 127 169     SPACE eurjchem-124 127 170 ( ( PUNCT eurjchem-124 127 171 6h 6h NUM eurjchem-124 127 172 , , PUNCT eurjchem-124 127 173     SPACE eurjchem-124 127 174 t t PROPN eurjchem-124 127 175 , , PUNCT eurjchem-124 127 176     SPACE eurjchem-124 127 177 ‐ch3 ‐ch3 ADJ eurjchem-124 127 178 , , PUNCT eurjchem-124 127 179             SPACE eurjchem-124 127 180 j j PROPN eurjchem-124 127 181     SPACE eurjchem-124 127 182 = = NOUN eurjchem-124 127 183     SPACE eurjchem-124 127 184 7.1 7.1 NUM eurjchem-124 127 185     SPACE eurjchem-124 127 186 hz hz NOUN eurjchem-124 127 187 ) ) PUNCT eurjchem-124 127 188 . . PUNCT eurjchem-124 127 189     SPACE eurjchem-124 127 190 13c 13c NOUN eurjchem-124 127 191     SPACE eurjchem-124 127 192 nmr nmr NOUN eurjchem-124 127 193     SPACE eurjchem-124 127 194 ( ( PUNCT eurjchem-124 127 195 300 300 NUM eurjchem-124 127 196     SPACE eurjchem-124 127 197 mhz mhz NOUN eurjchem-124 127 198 , , PUNCT eurjchem-124 127 199     SPACE eurjchem-124 127 200 dmso‐d6 dmso‐d6 NOUN eurjchem-124 127 201 ) ) PUNCT eurjchem-124 127 202     SPACE eurjchem-124 127 203 in in ADP eurjchem-124 127 204     SPACE eurjchem-124 127 205 δ δ PROPN eurjchem-124 127 206     SPACE eurjchem-124 127 207 ( ( PUNCT eurjchem-124 127 208 ppm ppm PROPN eurjchem-124 127 209 ): ): PUNCT eurjchem-124 127 210     SPACE eurjchem-124 127 211 179.8 179.8 NUM eurjchem-124 127 212     SPACE eurjchem-124 127 213 ( ( PUNCT eurjchem-124 127 214 c c PROPN eurjchem-124 127 215 = = SYM eurjchem-124 127 216 s s NOUN eurjchem-124 127 217 ) ) PUNCT eurjchem-124 127 218 , , PUNCT eurjchem-124 127 219     SPACE eurjchem-124 127 220 170.1 170.1 NUM eurjchem-124 127 221     SPACE eurjchem-124 127 222 ( ( PUNCT eurjchem-124 127 223 c c NOUN eurjchem-124 127 224 = = NOUN eurjchem-124 127 225 o o NOUN eurjchem-124 127 226 ) ) PUNCT eurjchem-124 127 227 , , PUNCT eurjchem-124 127 228     SPACE eurjchem-124 127 229 135.3 135.3 NUM eurjchem-124 127 230     SPACE eurjchem-124 127 231 ( ( PUNCT eurjchem-124 127 232 c c NOUN eurjchem-124 127 233 ) ) PUNCT eurjchem-124 127 234 , , PUNCT eurjchem-124 127 235     SPACE eurjchem-124 127 236 133.7 133.7 NUM eurjchem-124 127 237     SPACE eurjchem-124 127 238 ( ( PUNCT eurjchem-124 127 239 c c NOUN eurjchem-124 127 240 ) ) PUNCT eurjchem-124 127 241 , , PUNCT eurjchem-124 127 242     SPACE eurjchem-124 127 243 132.5 132.5 NUM eurjchem-124 127 244     SPACE eurjchem-124 127 245 ( ( PUNCT eurjchem-124 127 246 c c NOUN eurjchem-124 127 247 ) ) PUNCT eurjchem-124 127 248 , , PUNCT eurjchem-124 127 249     SPACE eurjchem-124 127 250 132.0 132.0 NUM eurjchem-124 127 251     SPACE eurjchem-124 127 252 ( ( PUNCT eurjchem-124 127 253 c c NOUN eurjchem-124 127 254 ) ) PUNCT eurjchem-124 127 255 , , PUNCT eurjchem-124 127 256     SPACE eurjchem-124 127 257 46 46 NUM eurjchem-124 127 258     SPACE eurjchem-124 127 259 ( ( PUNCT eurjchem-124 127 260 2c 2c NOUN eurjchem-124 127 261 ) ) PUNCT eurjchem-124 127 262 , , PUNCT eurjchem-124 127 263     SPACE eurjchem-124 127 264 34.2 34.2 NUM eurjchem-124 127 265     SPACE eurjchem-124 127 266 ( ( PUNCT eurjchem-124 127 267 2c 2c NOUN eurjchem-124 127 268 ) ) PUNCT eurjchem-124 127 269 , , PUNCT eurjchem-124 127 270     SPACE eurjchem-124 127 271 21.8 21.8 NUM eurjchem-124 127 272     SPACE eurjchem-124 127 273 ( ( PUNCT eurjchem-124 127 274 2c 2c NOUN eurjchem-124 127 275 ) ) PUNCT eurjchem-124 127 276 . . PUNCT eurjchem-124 127 277     SPACE eurjchem-124 128 1 ms ms PROPN eurjchem-124 128 2     SPACE eurjchem-124 128 3 ( ( PUNCT eurjchem-124 128 4 70 70 NUM eurjchem-124 128 5     SPACE eurjchem-124 128 6 ev ev NOUN eurjchem-124 128 7 ) ) PUNCT eurjchem-124 128 8     SPACE eurjchem-124 128 9 m m PROPN eurjchem-124 128 10 / / PROPN eurjchem-124 128 11 z z NOUN eurjchem-124 128 12     SPACE eurjchem-124 128 13 ( ( PUNCT eurjchem-124 128 14 % % INTJ eurjchem-124 128 15 ): ): PUNCT eurjchem-124 128 16     SPACE eurjchem-124 128 17 270 270 NUM eurjchem-124 128 18 . . PUNCT eurjchem-124 128 19     SPACE eurjchem-124 128 20 anal anal ADJ eurjchem-124 128 21 . . PUNCT eurjchem-124 128 22     SPACE eurjchem-124 128 23 calcd calcd NOUN eurjchem-124 128 24 . . PUNCT eurjchem-124 128 25     SPACE eurjchem-124 128 26 for for ADP eurjchem-124 128 27     SPACE eurjchem-124 128 28 c12h18n2os2 c12h18n2os2 NOUN eurjchem-124 128 29     SPACE eurjchem-124 128 30 : : PUNCT eurjchem-124 128 31 c c X eurjchem-124 128 32 , , PUNCT eurjchem-124 128 33     SPACE eurjchem-124 128 34 53.30 53.30 NUM eurjchem-124 128 35 ; ; PUNCT eurjchem-124 128 36     SPACE eurjchem-124 128 37 h h NOUN eurjchem-124 128 38 , , PUNCT eurjchem-124 128 39     SPACE eurjchem-124 128 40 6.71 6.71 NUM eurjchem-124 128 41 ; ; PUNCT eurjchem-124 128 42     SPACE eurjchem-124 128 43 n n CCONJ eurjchem-124 128 44 , , PUNCT eurjchem-124 128 45     SPACE eurjchem-124 128 46 10.36 10.36 NUM eurjchem-124 128 47 ; ; PUNCT eurjchem-124 128 48     SPACE eurjchem-124 128 49 s s PROPN eurjchem-124 128 50 , , PUNCT eurjchem-124 128 51     SPACE eurjchem-124 128 52 23.72 23.72 NUM eurjchem-124 128 53 . . PUNCT eurjchem-124 128 54     SPACE eurjchem-124 128 55 found find VERB eurjchem-124 128 56 : : PUNCT eurjchem-124 128 57     SPACE eurjchem-124 128 58 c c X eurjchem-124 128 59 , , PUNCT eurjchem-124 128 60     SPACE eurjchem-124 128 61 53.33 53.33 NUM eurjchem-124 128 62 ; ; PUNCT eurjchem-124 128 63     SPACE eurjchem-124 128 64 h h NOUN eurjchem-124 128 65 , , PUNCT eurjchem-124 128 66     SPACE eurjchem-124 128 67 6.75 6.75 NUM eurjchem-124 128 68 ; ; PUNCT eurjchem-124 128 69     SPACE eurjchem-124 128 70 n n CCONJ eurjchem-124 128 71 , , PUNCT eurjchem-124 128 72     SPACE eurjchem-124 128 73 10.35 10.35 NUM eurjchem-124 128 74 ; ; PUNCT eurjchem-124 128 75     SPACE eurjchem-124 128 76 s s PROPN eurjchem-124 128 77 , , PUNCT eurjchem-124 128 78     SPACE eurjchem-124 128 79 23.72 23.72 NUM eurjchem-124 128 80 . . PUNCT eurjchem-124 128 81         SPACE eurjchem-124 129 1 n­[(5­methoxy­1,3­benzothiazol­2­yl)carbamothioyl]thio n­[(5­methoxy­1,3­benzothiazol­2­yl)carbamothioyl]thio PROPN eurjchem-124 129 2     SPACE eurjchem-124 129 3 phene­2­carboxamide phene­2­carboxamide NOUN eurjchem-124 129 4     SPACE eurjchem-124 129 5 ( ( PUNCT eurjchem-124 129 6 12 12 NUM eurjchem-124 129 7 ): ): SYM eurjchem-124 129 8     SPACE eurjchem-124 129 9 dark dark ADJ eurjchem-124 129 10     SPACE eurjchem-124 129 11 yellow yellow ADJ eurjchem-124 129 12     SPACE eurjchem-124 129 13 solid solid ADJ eurjchem-124 129 14 . . PUNCT eurjchem-124 129 15     SPACE eurjchem-124 129 16 yield yield NOUN eurjchem-124 129 17 : : PUNCT eurjchem-124 129 18     SPACE eurjchem-124 129 19 89 89 NUM eurjchem-124 129 20 % % NOUN eurjchem-124 129 21 . . PUNCT eurjchem-124 129 22     SPACE eurjchem-124 130 1 m.p m.p PROPN eurjchem-124 130 2 . . PROPN eurjchem-124 130 3 : : PUNCT eurjchem-124 130 4     SPACE eurjchem-124 130 5 167‐168 167‐168 NOUN eurjchem-124 130 6     SPACE eurjchem-124 130 7 oc oc PROPN eurjchem-124 130 8 . . PUNCT eurjchem-124 130 9     SPACE eurjchem-124 130 10 ft‐ir ft‐ir NOUN eurjchem-124 130 11     SPACE eurjchem-124 130 12 ( ( PUNCT eurjchem-124 130 13 kbr kbr NOUN eurjchem-124 130 14     SPACE eurjchem-124 130 15 pellet pellet NOUN eurjchem-124 130 16 ) ) PUNCT eurjchem-124 130 17     SPACE eurjchem-124 130 18 in in ADP eurjchem-124 130 19     SPACE eurjchem-124 130 20 cm‐1 cm‐1 NOUN eurjchem-124 130 21 : : PUNCT eurjchem-124 130 22     SPACE eurjchem-124 130 23 3263 3263 NUM eurjchem-124 130 24 , , PUNCT eurjchem-124 130 25     SPACE eurjchem-124 130 26 3209 3209 NUM eurjchem-124 130 27     SPACE eurjchem-124 130 28 ( ( PUNCT eurjchem-124 130 29 n‐h n‐h NOUN eurjchem-124 130 30 ) ) PUNCT eurjchem-124 130 31 , , PUNCT eurjchem-124 130 32     SPACE eurjchem-124 130 33 3063‐3031(c‐h 3063‐3031(c‐h NUM eurjchem-124 130 34 ) ) PUNCT eurjchem-124 130 35 , , PUNCT eurjchem-124 130 36     SPACE eurjchem-124 130 37 1671 1671 NUM eurjchem-124 130 38     SPACE eurjchem-124 130 39 ( ( PUNCT eurjchem-124 130 40 c c NOUN eurjchem-124 130 41 = = NOUN eurjchem-124 130 42 o o NOUN eurjchem-124 130 43 ) ) PUNCT eurjchem-124 130 44 , , PUNCT eurjchem-124 130 45     SPACE eurjchem-124 130 46 1591 1591 NUM eurjchem-124 130 47     SPACE eurjchem-124 130 48 ( ( PUNCT eurjchem-124 130 49 aromatic aromatic ADJ eurjchem-124 130 50     SPACE eurjchem-124 130 51 c c NOUN eurjchem-124 130 52 = = SYM eurjchem-124 130 53 c c NOUN eurjchem-124 130 54 ) ) PUNCT eurjchem-124 130 55 , , PUNCT eurjchem-124 130 56     SPACE eurjchem-124 130 57 1233 1233 NUM eurjchem-124 130 58     SPACE eurjchem-124 130 59 ( ( PUNCT eurjchem-124 130 60 c c X eurjchem-124 130 61 = = SYM eurjchem-124 130 62 s s NOUN eurjchem-124 130 63 ) ) PUNCT eurjchem-124 130 64 . . PUNCT eurjchem-124 130 65     SPACE eurjchem-124 130 66 1h 1h NUM eurjchem-124 130 67     SPACE eurjchem-124 130 68 nmr nmr NOUN eurjchem-124 130 69     SPACE eurjchem-124 130 70 ( ( PUNCT eurjchem-124 130 71 300 300 NUM eurjchem-124 130 72     SPACE eurjchem-124 130 73 mhz mhz NOUN eurjchem-124 130 74 , , PUNCT eurjchem-124 130 75     SPACE eurjchem-124 130 76 dmso‐d6 dmso‐d6 NOUN eurjchem-124 130 77 ) ) PUNCT eurjchem-124 130 78     SPACE eurjchem-124 130 79 in in ADP eurjchem-124 130 80     SPACE eurjchem-124 130 81 δ δ PROPN eurjchem-124 130 82     SPACE eurjchem-124 130 83 ( ( PUNCT eurjchem-124 130 84 ppm ppm NOUN eurjchem-124 130 85 ) ) PUNCT eurjchem-124 130 86     SPACE eurjchem-124 130 87 and and CCONJ eurjchem-124 130 88     SPACE eurjchem-124 130 89 j j NOUN eurjchem-124 130 90     SPACE eurjchem-124 130 91 ( ( PUNCT eurjchem-124 130 92 hz hz PROPN eurjchem-124 130 93 ): ): PROPN eurjchem-124 130 94     SPACE eurjchem-124 130 95 12.25 12.25 NUM eurjchem-124 130 96     SPACE eurjchem-124 130 97 ( ( PUNCT eurjchem-124 130 98 1h 1h NUM eurjchem-124 130 99 , , PUNCT eurjchem-124 130 100     SPACE eurjchem-124 130 101 s s PROPN eurjchem-124 130 102 , , PUNCT eurjchem-124 130 103     SPACE eurjchem-124 130 104 csnh csnh NOUN eurjchem-124 130 105 ) ) PUNCT eurjchem-124 130 106 , , PUNCT eurjchem-124 130 107     SPACE eurjchem-124 130 108 11.37 11.37 NUM eurjchem-124 130 109     SPACE eurjchem-124 130 110 ( ( PUNCT eurjchem-124 130 111 1h 1h NUM eurjchem-124 130 112 , , PUNCT eurjchem-124 130 113     SPACE eurjchem-124 130 114 s s PROPN eurjchem-124 130 115 , , PUNCT eurjchem-124 130 116     SPACE eurjchem-124 130 117 conh conh NOUN eurjchem-124 130 118 ) ) PUNCT eurjchem-124 130 119 , , PUNCT eurjchem-124 130 120     SPACE eurjchem-124 130 121 8.10 8.10 NUM eurjchem-124 130 122     SPACE eurjchem-124 130 123 ( ( PUNCT eurjchem-124 130 124 1h 1h NUM eurjchem-124 130 125 , , PUNCT eurjchem-124 130 126     SPACE eurjchem-124 130 127 dd dd NOUN eurjchem-124 130 128 , , PUNCT eurjchem-124 130 129     SPACE eurjchem-124 130 130 j1 j1 PROPN eurjchem-124 130 131     SPACE eurjchem-124 130 132 = = NOUN eurjchem-124 130 133     SPACE eurjchem-124 130 134 7.2 7.2 NUM eurjchem-124 130 135     SPACE eurjchem-124 130 136 hz hz VERB eurjchem-124 130 137 , , PUNCT eurjchem-124 130 138     SPACE eurjchem-124 130 139 j2 j2 PROPN eurjchem-124 130 140     SPACE eurjchem-124 130 141 = = NOUN eurjchem-124 130 142     SPACE eurjchem-124 130 143 8.1 8.1 NUM eurjchem-124 130 144     SPACE eurjchem-124 130 145 hz hz VERB eurjchem-124 130 146 , , PUNCT eurjchem-124 130 147     SPACE eurjchem-124 130 148 thiophene thiophene NOUN eurjchem-124 130 149     SPACE eurjchem-124 130 150 ch ch NOUN eurjchem-124 130 151 ) ) PUNCT eurjchem-124 130 152 , , PUNCT eurjchem-124 130 153     SPACE eurjchem-124 130 154 8.02 8.02 NUM eurjchem-124 130 155     SPACE eurjchem-124 130 156 ( ( PUNCT eurjchem-124 130 157 1h 1h NUM eurjchem-124 130 158 , , PUNCT eurjchem-124 130 159     SPACE eurjchem-124 130 160 dd dd NOUN eurjchem-124 130 161 , , PUNCT eurjchem-124 130 162     SPACE eurjchem-124 130 163 j1 j1 PROPN eurjchem-124 130 164     SPACE eurjchem-124 131 1 = = NOUN eurjchem-124 131 2     SPACE eurjchem-124 131 3 7.5 7.5 NUM eurjchem-124 131 4     SPACE eurjchem-124 131 5 hz hz VERB eurjchem-124 131 6 , , PUNCT eurjchem-124 131 7     SPACE eurjchem-124 131 8 j2 j2 PROPN eurjchem-124 131 9     SPACE eurjchem-124 131 10 = = NOUN eurjchem-124 131 11     SPACE eurjchem-124 131 12 8.2 8.2 NUM eurjchem-124 131 13     SPACE eurjchem-124 131 14 hz hz VERB eurjchem-124 131 15 , , PUNCT eurjchem-124 131 16     SPACE eurjchem-124 131 17 thiophene thiophene NOUN eurjchem-124 131 18     SPACE eurjchem-124 131 19 ch ch NOUN eurjchem-124 131 20 ) ) PUNCT eurjchem-124 131 21 , , PUNCT eurjchem-124 131 22     SPACE eurjchem-124 131 23 7.35 7.35 NUM eurjchem-124 131 24     SPACE eurjchem-124 131 25 ( ( PUNCT eurjchem-124 131 26 2h 2h NUM eurjchem-124 131 27 , , PUNCT eurjchem-124 131 28     SPACE eurjchem-124 131 29 d d PROPN eurjchem-124 131 30 , , PUNCT eurjchem-124 131 31     SPACE eurjchem-124 131 32 j j PROPN eurjchem-124 131 33     SPACE eurjchem-124 131 34 = = NOUN eurjchem-124 131 35     SPACE eurjchem-124 131 36 8.5 8.5 NUM eurjchem-124 131 37     SPACE eurjchem-124 131 38 hz hz NOUN eurjchem-124 131 39 ) ) PUNCT eurjchem-124 131 40 , , PUNCT eurjchem-124 131 41     SPACE eurjchem-124 131 42 7.30 7.30 NUM eurjchem-124 131 43     SPACE eurjchem-124 131 44 ( ( PUNCT eurjchem-124 131 45 2h 2h NUM eurjchem-124 131 46 , , PUNCT eurjchem-124 131 47     SPACE eurjchem-124 131 48 d d PROPN eurjchem-124 131 49 , , PUNCT eurjchem-124 131 50     SPACE eurjchem-124 131 51 j j PROPN eurjchem-124 131 52     SPACE eurjchem-124 132 1 = = NOUN eurjchem-124 132 2     SPACE eurjchem-124 132 3 8.1 8.1 NUM eurjchem-124 132 4     SPACE eurjchem-124 132 5 hz hz NOUN eurjchem-124 132 6 ) ) PUNCT eurjchem-124 132 7 , , PUNCT eurjchem-124 132 8     SPACE eurjchem-124 132 9 7.50 7.50 NUM eurjchem-124 132 10     SPACE eurjchem-124 132 11 ( ( PUNCT eurjchem-124 132 12 1h 1h NUM eurjchem-124 132 13 , , PUNCT eurjchem-124 132 14     SPACE eurjchem-124 132 15 dd dd NOUN eurjchem-124 132 16 , , PUNCT eurjchem-124 132 17     SPACE eurjchem-124 132 18 j1 j1 PROPN eurjchem-124 132 19     SPACE eurjchem-124 133 1 = = NOUN eurjchem-124 133 2     SPACE eurjchem-124 133 3 6.7 6.7 NUM eurjchem-124 133 4     SPACE eurjchem-124 133 5 hz hz VERB eurjchem-124 133 6 , , PUNCT eurjchem-124 133 7     SPACE eurjchem-124 133 8 j2 j2 PROPN eurjchem-124 133 9     SPACE eurjchem-124 133 10 = = NOUN eurjchem-124 133 11     SPACE eurjchem-124 133 12 8.6 8.6 NUM eurjchem-124 133 13     SPACE eurjchem-124 133 14 hz hz VERB eurjchem-124 133 15 , , PUNCT eurjchem-124 133 16         SPACE eurjchem-124 133 17 thiophene thiophene NOUN eurjchem-124 133 18     SPACE eurjchem-124 133 19 ch ch NOUN eurjchem-124 133 20 ) ) PUNCT eurjchem-124 133 21 , , PUNCT eurjchem-124 133 22     SPACE eurjchem-124 133 23 7.01 7.01 NUM eurjchem-124 133 24     SPACE eurjchem-124 133 25 ( ( PUNCT eurjchem-124 133 26 1h 1h NUM eurjchem-124 133 27 , , PUNCT eurjchem-124 133 28     SPACE eurjchem-124 133 29 s s PROPN eurjchem-124 133 30 , , PUNCT eurjchem-124 133 31     SPACE eurjchem-124 133 32 ph ph NOUN eurjchem-124 133 33 ) ) PUNCT eurjchem-124 133 34 , , PUNCT eurjchem-124 133 35     SPACE eurjchem-124 133 36 4.35 4.35 NUM eurjchem-124 133 37     SPACE eurjchem-124 133 38 ( ( PUNCT eurjchem-124 133 39 3h 3h NUM eurjchem-124 133 40 , , PUNCT eurjchem-124 133 41     SPACE eurjchem-124 133 42 s s PROPN eurjchem-124 133 43 , , PUNCT eurjchem-124 133 44     SPACE eurjchem-124 133 45 och3 och3 ADJ eurjchem-124 133 46 ) ) PUNCT eurjchem-124 133 47 . . PUNCT eurjchem-124 133 48     SPACE eurjchem-124 134 1 13c 13c NOUN eurjchem-124 134 2     SPACE eurjchem-124 134 3 nmr nmr NOUN eurjchem-124 134 4     SPACE eurjchem-124 134 5 ( ( PUNCT eurjchem-124 134 6 300 300 NUM eurjchem-124 134 7     SPACE eurjchem-124 134 8 mhz mhz NOUN eurjchem-124 134 9 , , PUNCT eurjchem-124 134 10     SPACE eurjchem-124 134 11 dmso‐d6 dmso‐d6 NOUN eurjchem-124 134 12 ) ) PUNCT eurjchem-124 134 13     SPACE eurjchem-124 134 14 in in ADP eurjchem-124 134 15     SPACE eurjchem-124 134 16 δ δ PROPN eurjchem-124 134 17     SPACE eurjchem-124 134 18 ( ( PUNCT eurjchem-124 134 19 ppm ppm PROPN eurjchem-124 134 20 ): ): PUNCT eurjchem-124 134 21     SPACE eurjchem-124 134 22 180.0 180.0 NUM eurjchem-124 134 23     SPACE eurjchem-124 134 24 ( ( PUNCT eurjchem-124 134 25 c c NOUN eurjchem-124 134 26 = = SYM eurjchem-124 134 27 s s NOUN eurjchem-124 134 28 ) ) PUNCT eurjchem-124 134 29 , , PUNCT eurjchem-124 134 30     SPACE eurjchem-124 134 31 174.2 174.2 NUM eurjchem-124 134 32     SPACE eurjchem-124 134 33 ( ( PUNCT eurjchem-124 134 34 c c NOUN eurjchem-124 134 35 = = SYM eurjchem-124 134 36 n n NUM eurjchem-124 134 37 ) ) PUNCT eurjchem-124 134 38 , , PUNCT eurjchem-124 134 39     SPACE eurjchem-124 134 40 168.2 168.2 NUM eurjchem-124 134 41     SPACE eurjchem-124 134 42 ( ( PUNCT eurjchem-124 134 43 c c NOUN eurjchem-124 134 44 = = NOUN eurjchem-124 134 45 o o NOUN eurjchem-124 134 46 ) ) PUNCT eurjchem-124 134 47 , , PUNCT eurjchem-124 134 48     SPACE eurjchem-124 134 49 149.7 149.7 NUM eurjchem-124 134 50 , , PUNCT eurjchem-124 134 51     SPACE eurjchem-124 134 52 145.5 145.5 NUM eurjchem-124 134 53 , , PUNCT eurjchem-124 134 54     SPACE eurjchem-124 134 55 137.0 137.0 NUM eurjchem-124 134 56 , , PUNCT eurjchem-124 134 57     SPACE eurjchem-124 134 58 135.7 135.7 NUM eurjchem-124 134 59 , , PUNCT eurjchem-124 134 60     SPACE eurjchem-124 134 61 130.3 130.3 NUM eurjchem-124 134 62 , , PUNCT eurjchem-124 134 63     SPACE eurjchem-124 134 64 128.4 128.4 NUM eurjchem-124 134 65 , , PUNCT eurjchem-124 134 66     SPACE eurjchem-124 134 67 122.3 122.3 NUM eurjchem-124 134 68 , , PUNCT eurjchem-124 134 69     SPACE eurjchem-124 134 70 120.7 120.7 NUM eurjchem-124 134 71 , , PUNCT eurjchem-124 134 72     SPACE eurjchem-124 134 73 62.5 62.5 NUM eurjchem-124 134 74 . . PUNCT eurjchem-124 134 75     SPACE eurjchem-124 135 1 ei ei PROPN eurjchem-124 135 2     SPACE eurjchem-124 135 3 ms ms NOUN eurjchem-124 135 4     SPACE eurjchem-124 135 5 ( ( PUNCT eurjchem-124 135 6 70 70 NUM eurjchem-124 135 7     SPACE eurjchem-124 135 8 ev ev NOUN eurjchem-124 135 9 ) ) PUNCT eurjchem-124 135 10     SPACE eurjchem-124 135 11 m m PROPN eurjchem-124 135 12 / / PROPN eurjchem-124 135 13 z z NOUN eurjchem-124 135 14     SPACE eurjchem-124 135 15 ( ( PUNCT eurjchem-124 135 16 % % INTJ eurjchem-124 135 17 ): ): PUNCT eurjchem-124 135 18     SPACE eurjchem-124 135 19 349 349 NUM eurjchem-124 135 20 . . PUNCT eurjchem-124 135 21     SPACE eurjchem-124 135 22 anal anal ADJ eurjchem-124 135 23 . . PUNCT eurjchem-124 135 24     SPACE eurjchem-124 135 25 calcd calcd NOUN eurjchem-124 135 26 . . PUNCT eurjchem-124 135 27     SPACE eurjchem-124 135 28 for for ADP eurjchem-124 135 29     SPACE eurjchem-124 135 30 c14h11n3o2s3 c14h11n3o2s3 PROPN eurjchem-124 135 31     SPACE eurjchem-124 135 32 : : PUNCT eurjchem-124 135 33     SPACE eurjchem-124 135 34 c c X eurjchem-124 135 35 , , PUNCT eurjchem-124 135 36     SPACE eurjchem-124 135 37 48.12 48.12 NUM eurjchem-124 135 38 ; ; PUNCT eurjchem-124 135 39     SPACE eurjchem-124 135 40 h h NOUN eurjchem-124 135 41 , , PUNCT eurjchem-124 135 42     SPACE eurjchem-124 135 43 3.17 3.17 NUM eurjchem-124 135 44 ; ; PUNCT eurjchem-124 135 45     SPACE eurjchem-124 135 46 n n CCONJ eurjchem-124 135 47 , , PUNCT eurjchem-124 135 48     SPACE eurjchem-124 135 49 12.02 12.02 NUM eurjchem-124 135 50 ; ; PUNCT eurjchem-124 135 51     SPACE eurjchem-124 135 52 s s PROPN eurjchem-124 135 53 , , PUNCT eurjchem-124 135 54     SPACE eurjchem-124 135 55 27.53 27.53 NUM eurjchem-124 135 56 . . PUNCT eurjchem-124 135 57     SPACE eurjchem-124 135 58 found find VERB eurjchem-124 135 59 : : PUNCT eurjchem-124 135 60     SPACE eurjchem-124 135 61 c c X eurjchem-124 135 62 , , PUNCT eurjchem-124 135 63     SPACE eurjchem-124 135 64 48.15 48.15 NUM eurjchem-124 135 65 ; ; PUNCT eurjchem-124 135 66     SPACE eurjchem-124 135 67 h h NOUN eurjchem-124 135 68 , , PUNCT eurjchem-124 135 69     SPACE eurjchem-124 135 70 3.17 3.17 NUM eurjchem-124 135 71 ; ; PUNCT eurjchem-124 135 72     SPACE eurjchem-124 135 73 n n CCONJ eurjchem-124 135 74 , , PUNCT eurjchem-124 135 75     SPACE eurjchem-124 135 76 12.04 12.04 NUM eurjchem-124 135 77 ; ; PUNCT eurjchem-124 135 78     SPACE eurjchem-124 135 79 s s PROPN eurjchem-124 135 80 , , PUNCT eurjchem-124 135 81     SPACE eurjchem-124 135 82 27.51 27.51 NUM eurjchem-124 135 83 . . PUNCT eurjchem-124 135 84         SPACE eurjchem-124 136 1 2.2.2 2.2.2 NUM eurjchem-124 136 2     SPACE eurjchem-124 136 3 crystal crystal NOUN eurjchem-124 136 4     SPACE eurjchem-124 136 5 structure structure NOUN eurjchem-124 136 6     SPACE eurjchem-124 136 7 determination determination NOUN eurjchem-124 136 8     SPACE eurjchem-124 136 9 of of ADP eurjchem-124 136 10     SPACE eurjchem-124 136 11 n n CCONJ eurjchem-124 136 12 , , PUNCT eurjchem-124 136 13 n­diphenyl­n’­ n­diphenyl­n’­ PROPN eurjchem-124 136 14 ( ( PUNCT eurjchem-124 136 15 thiophene­2­carbonyl)­thiourea thiophene­2­carbonyl)­thiourea ADV eurjchem-124 136 16     SPACE eurjchem-124 136 17 ( ( PUNCT eurjchem-124 136 18 6 6 NUM eurjchem-124 136 19 ) ) PUNCT eurjchem-124 136 20         SPACE eurjchem-124 136 21 crystal crystal NOUN eurjchem-124 136 22     SPACE eurjchem-124 136 23 data datum NOUN eurjchem-124 136 24 : : PUNCT eurjchem-124 136 25     SPACE eurjchem-124 136 26 c18h14n2os2 c18h14n2os2 NOUN eurjchem-124 136 27 , , PUNCT eurjchem-124 136 28     SPACE eurjchem-124 136 29 monoclinic monoclinic ADJ eurjchem-124 136 30 , , PUNCT eurjchem-124 136 31     SPACE eurjchem-124 136 32 space space NOUN eurjchem-124 136 33     SPACE eurjchem-124 136 34 group group NOUN eurjchem-124 136 35     SPACE eurjchem-124 136 36 p21 p21 NOUN eurjchem-124 136 37 , , PUNCT eurjchem-124 136 38                   SPACE eurjchem-124 136 39 a=11.7469(5 a=11.7469(5 PROPN eurjchem-124 136 40 ) ) PUNCT eurjchem-124 136 41 , , PUNCT eurjchem-124 136 42     SPACE eurjchem-124 136 43 b=6.0849(2 b=6.0849(2 NOUN eurjchem-124 136 44 ) ) PUNCT eurjchem-124 136 45 , , PUNCT eurjchem-124 136 46     SPACE eurjchem-124 136 47 c=12.5792(6 c=12.5792(6 ADJ eurjchem-124 136 48 ) ) PUNCT eurjchem-124 136 49     SPACE eurjchem-124 136 50 å å PROPN eurjchem-124 136 51 , , PUNCT eurjchem-124 136 52     SPACE eurjchem-124 136 53 =117.736(7 =117.736(7 PROPN eurjchem-124 136 54 ) ) PUNCT eurjchem-124 136 55     SPACE eurjchem-124 136 56 ° ° PROPN eurjchem-124 136 57 , , PUNCT eurjchem-124 136 58     SPACE eurjchem-124 136 59 v=795.8(6 v=795.8(6 NOUN eurjchem-124 136 60 ) ) PUNCT eurjchem-124 136 61     SPACE eurjchem-124 136 62 å3 å3 PROPN eurjchem-124 136 63 , , PUNCT eurjchem-124 136 64     SPACE eurjchem-124 136 65 t=100(2 t=100(2 NUM eurjchem-124 136 66 ) ) PUNCT eurjchem-124 136 67     SPACE eurjchem-124 136 68 k k PROPN eurjchem-124 136 69 , , PUNCT eurjchem-124 136 70     SPACE eurjchem-124 136 71 z=2 z=2 PROPN eurjchem-124 136 72 , , PUNCT eurjchem-124 136 73     SPACE eurjchem-124 136 74 f f NOUN eurjchem-124 136 75     SPACE eurjchem-124 136 76 ( ( PUNCT eurjchem-124 136 77 000)=352 000)=352 PROPN eurjchem-124 136 78 , , PUNCT eurjchem-124 136 79     SPACE eurjchem-124 136 80 dx=1.412 dx=1.412 VERB eurjchem-124 136 81     SPACE eurjchem-124 136 82 g g NOUN eurjchem-124 136 83     SPACE eurjchem-124 136 84 cm–3 cm–3 PROPN eurjchem-124 136 85 , , PUNCT eurjchem-124 136 86     SPACE eurjchem-124 136 87 =3.0 =3.0 PROPN eurjchem-124 136 88     SPACE eurjchem-124 136 89 mm–1 mm–1 PROPN eurjchem-124 136 90 . . PUNCT eurjchem-124 136 91     SPACE eurjchem-124 136 92 single single ADJ eurjchem-124 136 93     SPACE eurjchem-124 136 94 crystals crystal NOUN eurjchem-124 136 95     SPACE eurjchem-124 136 96 suitable suitable ADJ eurjchem-124 136 97     SPACE eurjchem-124 136 98 for for ADP eurjchem-124 136 99     SPACE eurjchem-124 136 100 x‐ray x‐ray PROPN eurjchem-124 136 101     SPACE eurjchem-124 136 102 diffraction diffraction NOUN eurjchem-124 136 103     SPACE eurjchem-124 136 104 studies study NOUN eurjchem-124 136 105     SPACE eurjchem-124 136 106 were be AUX eurjchem-124 136 107     SPACE eurjchem-124 136 108 obtained obtain VERB eurjchem-124 136 109     SPACE eurjchem-124 136 110 from from ADP eurjchem-124 136 111     SPACE eurjchem-124 136 112 an an DET eurjchem-124 136 113     SPACE eurjchem-124 136 114 ethanol‐dichloromethane ethanol‐dichloromethane NOUN eurjchem-124 136 115     SPACE eurjchem-124 136 116 mixture mixture NOUN eurjchem-124 136 117 . . PUNCT eurjchem-124 136 118     SPACE eurjchem-124 137 1 a a DET eurjchem-124 137 2     SPACE eurjchem-124 137 3 yellow yellow ADJ eurjchem-124 137 4     SPACE eurjchem-124 137 5 lath lath NOUN eurjchem-124 137 6     SPACE eurjchem-124 137 7 0.15 0.15 NUM eurjchem-124 137 8     SPACE eurjchem-124 137 9 × × NOUN eurjchem-124 137 10     SPACE eurjchem-124 137 11 0.05 0.05 NUM eurjchem-124 137 12     SPACE eurjchem-124 137 13 × × NOUN eurjchem-124 137 14     SPACE eurjchem-124 137 15 0.02 0.02 NUM eurjchem-124 137 16     SPACE eurjchem-124 137 17 mm3 mm3 NOUN eurjchem-124 137 18     SPACE eurjchem-124 137 19 was be AUX eurjchem-124 137 20     SPACE eurjchem-124 137 21 mounted mount VERB eurjchem-124 137 22     SPACE eurjchem-124 137 23 on on ADP eurjchem-124 137 24     SPACE eurjchem-124 137 25 a a DET eurjchem-124 137 26     SPACE eurjchem-124 137 27 glass glass NOUN eurjchem-124 137 28     SPACE eurjchem-124 137 29 fibre fibre NOUN eurjchem-124 137 30     SPACE eurjchem-124 137 31 in in ADP eurjchem-124 137 32     SPACE eurjchem-124 137 33 inert inert NOUN eurjchem-124 137 34     SPACE eurjchem-124 137 35 oil oil NOUN eurjchem-124 137 36 . . PUNCT eurjchem-124 137 37     SPACE eurjchem-124 138 1 measurements measurement NOUN eurjchem-124 138 2     SPACE eurjchem-124 138 3 were be AUX eurjchem-124 138 4     SPACE eurjchem-124 138 5 performed perform VERB eurjchem-124 138 6     SPACE eurjchem-124 138 7 at at ADP eurjchem-124 138 8     SPACE eurjchem-124 138 9 100 100 NUM eurjchem-124 138 10     SPACE eurjchem-124 138 11 k k NOUN eurjchem-124 138 12     SPACE eurjchem-124 138 13 on on ADP eurjchem-124 138 14     SPACE eurjchem-124 138 15 an an DET eurjchem-124 138 16     SPACE eurjchem-124 138 17 oxford oxford ADJ eurjchem-124 138 18     SPACE eurjchem-124 138 19 diffraction diffraction PROPN eurjchem-124 138 20     SPACE eurjchem-124 138 21 xcalibur xcalibur PROPN eurjchem-124 138 22     SPACE eurjchem-124 138 23 nova nova PROPN eurjchem-124 138 24     SPACE eurjchem-124 138 25 diffractometer diffractometer NOUN eurjchem-124 138 26     SPACE eurjchem-124 138 27 with with ADP eurjchem-124 138 28     SPACE eurjchem-124 138 29 mirror‐ mirror‐ NOUN eurjchem-124 138 30 focused focus VERB eurjchem-124 138 31     SPACE eurjchem-124 138 32 cu‐kα cu‐kα ADJ eurjchem-124 138 33     SPACE eurjchem-124 138 34 radiation radiation NOUN eurjchem-124 138 35     SPACE eurjchem-124 138 36 to to ADP eurjchem-124 138 37     SPACE eurjchem-124 138 38 2max 2max NUM eurjchem-124 138 39     SPACE eurjchem-124 138 40 152 152 NUM eurjchem-124 138 41 ° ° NUM eurjchem-124 138 42     SPACE eurjchem-124 138 43 ( ( PUNCT eurjchem-124 138 44 99.3 99.3 NUM eurjchem-124 138 45 % % NOUN eurjchem-124 138 46     SPACE eurjchem-124 138 47 complete complete ADJ eurjchem-124 138 48     SPACE eurjchem-124 138 49 to to ADP eurjchem-124 138 50     SPACE eurjchem-124 138 51 72.50 72.50 NUM eurjchem-124 138 52 ° ° NUM eurjchem-124 138 53 ) ) PUNCT eurjchem-124 138 54 . . PUNCT eurjchem-124 138 55     SPACE eurjchem-124 139 1 the the DET eurjchem-124 139 2     SPACE eurjchem-124 139 3 data datum NOUN eurjchem-124 139 4     SPACE eurjchem-124 139 5 were be AUX eurjchem-124 139 6     SPACE eurjchem-124 139 7 corrected correct VERB eurjchem-124 139 8     SPACE eurjchem-124 139 9 for for ADP eurjchem-124 139 10     SPACE eurjchem-124 139 11 absorption absorption NOUN eurjchem-124 139 12     SPACE eurjchem-124 139 13 using use VERB eurjchem-124 139 14     SPACE eurjchem-124 139 15 the the DET eurjchem-124 139 16     SPACE eurjchem-124 139 17 multi‐scan multi‐scan ADJ eurjchem-124 139 18     SPACE eurjchem-124 139 19 method method NOUN eurjchem-124 139 20 . . PUNCT eurjchem-124 139 21     SPACE eurjchem-124 139 22 of of ADP eurjchem-124 139 23     SPACE eurjchem-124 139 24 17408 17408 NUM eurjchem-124 139 25     SPACE eurjchem-124 139 26 intensities intensity NOUN eurjchem-124 139 27 , , PUNCT eurjchem-124 139 28     SPACE eurjchem-124 139 29 3097 3097 NUM eurjchem-124 139 30     SPACE eurjchem-124 139 31 were be AUX eurjchem-124 139 32     SPACE eurjchem-124 139 33 independent independent ADJ eurjchem-124 139 34     SPACE eurjchem-124 139 35 ( ( PUNCT eurjchem-124 139 36 rint rint NOUN eurjchem-124 139 37     SPACE eurjchem-124 139 38 0.0404 0.0404 NUM eurjchem-124 139 39 ) ) PUNCT eurjchem-124 139 40 . . PUNCT eurjchem-124 139 41     SPACE eurjchem-124 140 1 the the DET eurjchem-124 140 2     SPACE eurjchem-124 140 3 structure structure NOUN eurjchem-124 140 4     SPACE eurjchem-124 140 5 was be AUX eurjchem-124 140 6     SPACE eurjchem-124 140 7 refined refine VERB eurjchem-124 140 8     SPACE eurjchem-124 140 9 anisotropically anisotropically ADV eurjchem-124 140 10     SPACE eurjchem-124 140 11 using use VERB eurjchem-124 140 12     SPACE eurjchem-124 140 13 shelxl‐97 shelxl‐97 NOUN eurjchem-124 140 14     SPACE eurjchem-124 141 1 [ [ X eurjchem-124 141 2 30 30 NUM eurjchem-124 141 3 ] ] PUNCT eurjchem-124 141 4 . . PUNCT eurjchem-124 141 5     SPACE eurjchem-124 141 6 the the DET eurjchem-124 141 7     SPACE eurjchem-124 141 8 nh nh NOUN eurjchem-124 141 9     SPACE eurjchem-124 141 10 hydrogen hydrogen NOUN eurjchem-124 141 11     SPACE eurjchem-124 141 12 was be AUX eurjchem-124 141 13     SPACE eurjchem-124 141 14 refined refine VERB eurjchem-124 141 15     SPACE eurjchem-124 141 16 freely freely ADV eurjchem-124 141 17 , , PUNCT eurjchem-124 141 18     SPACE eurjchem-124 141 19 other other ADJ eurjchem-124 141 20     SPACE eurjchem-124 141 21 h h NOUN eurjchem-124 141 22     SPACE eurjchem-124 141 23 atoms atom NOUN eurjchem-124 141 24     SPACE eurjchem-124 141 25 using use VERB eurjchem-124 141 26     SPACE eurjchem-124 141 27 a a DET eurjchem-124 141 28     SPACE eurjchem-124 141 29 riding ride VERB eurjchem-124 141 30     SPACE eurjchem-124 141 31 model model NOUN eurjchem-124 141 32 . . PUNCT eurjchem-124 141 33     SPACE eurjchem-124 142 1 the the DET eurjchem-124 142 2     SPACE eurjchem-124 142 3 final final ADJ eurjchem-124 142 4     SPACE eurjchem-124 142 5 wr2 wr2 PROPN eurjchem-124 142 6     SPACE eurjchem-124 142 7 was be AUX eurjchem-124 142 8     SPACE eurjchem-124 142 9 0.074 0.074 NUM eurjchem-124 142 10 , , PUNCT eurjchem-124 142 11     SPACE eurjchem-124 142 12 with with ADP eurjchem-124 142 13     SPACE eurjchem-124 142 14 a a DET eurjchem-124 142 15     SPACE eurjchem-124 142 16 conventional conventional ADJ eurjchem-124 142 17     SPACE eurjchem-124 142 18 r1 r1 NOUN eurjchem-124 142 19     SPACE eurjchem-124 142 20 of of ADP eurjchem-124 142 21     SPACE eurjchem-124 142 22 0.029 0.029 NUM eurjchem-124 142 23 , , PUNCT eurjchem-124 142 24     SPACE eurjchem-124 142 25 for for ADP eurjchem-124 142 26     SPACE eurjchem-124 142 27 212 212 NUM eurjchem-124 142 28     SPACE eurjchem-124 142 29 parameters parameter NOUN eurjchem-124 142 30 ; ; PUNCT eurjchem-124 142 31     SPACE eurjchem-124 142 32 s s X eurjchem-124 142 33     SPACE eurjchem-124 142 34 = = NOUN eurjchem-124 142 35     SPACE eurjchem-124 142 36 1.06 1.06 NUM eurjchem-124 142 37 ; ; PUNCT eurjchem-124 142 38     SPACE eurjchem-124 142 39 max max PROPN eurjchem-124 142 40 . . PUNCT eurjchem-124 142 41     SPACE eurjchem-124 143 1   PROPN eurjchem-124 143 2     SPACE eurjchem-124 143 3 = = NOUN eurjchem-124 143 4     SPACE eurjchem-124 143 5 0.23 0.23 NUM eurjchem-124 143 6     SPACE eurjchem-124 143 7 e e NOUN eurjchem-124 143 8     SPACE eurjchem-124 143 9 å–3 å–3 VERB eurjchem-124 143 10 . . PUNCT eurjchem-124 143 11     SPACE eurjchem-124 144 1 the the DET eurjchem-124 144 2     SPACE eurjchem-124 144 3 flack flack NOUN eurjchem-124 144 4     SPACE eurjchem-124 144 5 parameter parameter NOUN eurjchem-124 144 6     SPACE eurjchem-124 144 7 refined refine VERB eurjchem-124 144 8     SPACE eurjchem-124 144 9 to to ADP eurjchem-124 144 10     SPACE eurjchem-124 144 11 0.019(14 0.019(14 NOUN eurjchem-124 144 12 ) ) PUNCT eurjchem-124 144 13 ; ; PUNCT eurjchem-124 144 14     SPACE eurjchem-124 144 15 the the DET eurjchem-124 144 16     SPACE eurjchem-124 144 17 compound compound NOUN eurjchem-124 144 18     SPACE eurjchem-124 144 19 is be AUX eurjchem-124 144 20     SPACE eurjchem-124 144 21 achiral achiral ADJ eurjchem-124 144 22     SPACE eurjchem-124 144 23 but but CCONJ eurjchem-124 144 24     SPACE eurjchem-124 144 25 crystallizes crystallize NOUN eurjchem-124 144 26     SPACE eurjchem-124 144 27 by by ADP eurjchem-124 144 28     SPACE eurjchem-124 144 29 chance chance NOUN eurjchem-124 144 30     SPACE eurjchem-124 144 31 in in ADP eurjchem-124 144 32     SPACE eurjchem-124 144 33 a a DET eurjchem-124 144 34     SPACE eurjchem-124 144 35 chiral chiral ADJ eurjchem-124 144 36     SPACE eurjchem-124 144 37 space space NOUN eurjchem-124 144 38     SPACE eurjchem-124 144 39 group group NOUN eurjchem-124 144 40 . . PUNCT eurjchem-124 144 41         SPACE eurjchem-124 145 1 2.2.3 2.2.3 NUM eurjchem-124 145 2     SPACE eurjchem-124 145 3 antifungal antifungal ADJ eurjchem-124 145 4     SPACE eurjchem-124 145 5 screening screen VERB eurjchem-124 145 6               SPACE eurjchem-124 145 7 the the DET eurjchem-124 145 8     SPACE eurjchem-124 145 9 compounds compound NOUN eurjchem-124 145 10     SPACE eurjchem-124 145 11 were be AUX eurjchem-124 145 12     SPACE eurjchem-124 145 13 screened screen VERB eurjchem-124 145 14     SPACE eurjchem-124 145 15 for for ADP eurjchem-124 145 16     SPACE eurjchem-124 145 17 their their PRON eurjchem-124 145 18     SPACE eurjchem-124 145 19 in in ADP eurjchem-124 145 20     SPACE eurjchem-124 145 21 vitro vitro VERB eurjchem-124 145 22     SPACE eurjchem-124 145 23 antifungal antifungal ADJ eurjchem-124 145 24     SPACE eurjchem-124 145 25 activity activity NOUN eurjchem-124 145 26 . . PUNCT eurjchem-124 145 27     SPACE eurjchem-124 145 28 antifungal antifungal ADJ eurjchem-124 145 29     SPACE eurjchem-124 145 30 activity activity NOUN eurjchem-124 145 31     SPACE eurjchem-124 145 32 was be AUX eurjchem-124 145 33     SPACE eurjchem-124 145 34 determined determine VERB eurjchem-124 145 35     SPACE eurjchem-124 145 36 by by ADP eurjchem-124 145 37     SPACE eurjchem-124 145 38 the the DET eurjchem-124 145 39     SPACE eurjchem-124 145 40 broth broth NOUN eurjchem-124 145 41     SPACE eurjchem-124 145 42 micro‐ micro‐ NOUN eurjchem-124 145 43 dilution dilution NOUN eurjchem-124 145 44     SPACE eurjchem-124 145 45 procedures procedure NOUN eurjchem-124 145 46     SPACE eurjchem-124 145 47 and and CCONJ eurjchem-124 145 48     SPACE eurjchem-124 145 49 principles principle NOUN eurjchem-124 145 50     SPACE eurjchem-124 145 51 of of ADP eurjchem-124 145 52     SPACE eurjchem-124 145 53 the the DET eurjchem-124 145 54     SPACE eurjchem-124 145 55 clinical clinical NOUN eurjchem-124 145 56     SPACE eurjchem-124 145 57 and and CCONJ eurjchem-124 145 58     SPACE eurjchem-124 145 59 laboratory laboratory NOUN eurjchem-124 145 60     SPACE eurjchem-124 145 61 standards standard NOUN eurjchem-124 145 62     SPACE eurjchem-124 145 63 institute institute PROPN eurjchem-124 145 64     SPACE eurjchem-124 145 65 ( ( PUNCT eurjchem-124 145 66 clsi clsi NOUN eurjchem-124 145 67 ) ) PUNCT eurjchem-124 145 68     SPACE eurjchem-124 146 1 [ [ X eurjchem-124 146 2 31,32 31,32 NUM eurjchem-124 146 3 ] ] PUNCT eurjchem-124 146 4 . . PUNCT eurjchem-124 146 5     SPACE eurjchem-124 147 1 minimal minimal ADJ eurjchem-124 147 2     SPACE eurjchem-124 147 3 inhibitory inhibitory ADJ eurjchem-124 147 4     SPACE eurjchem-124 147 5 concentrations concentration NOUN eurjchem-124 147 6     SPACE eurjchem-124 147 7 for for ADP eurjchem-124 147 8     SPACE eurjchem-124 147 9 each each DET eurjchem-124 147 10     SPACE eurjchem-124 147 11 compound compound NOUN eurjchem-124 147 12     SPACE eurjchem-124 147 13 were be AUX eurjchem-124 147 14     SPACE eurjchem-124 147 15 investigated investigate VERB eurjchem-124 147 16     SPACE eurjchem-124 147 17 against against ADP eurjchem-124 147 18     SPACE eurjchem-124 147 19 standard standard ADJ eurjchem-124 147 20     SPACE eurjchem-124 147 21 yeast‐like yeast‐like PROPN eurjchem-124 147 22     SPACE eurjchem-124 147 23 fungi fungi PROPN eurjchem-124 147 24 , , PUNCT eurjchem-124 147 25     SPACE eurjchem-124 147 26 c. c. NOUN eurjchem-124 147 27     SPACE eurjchem-124 147 28 albicans albican NOUN eurjchem-124 147 29     SPACE eurjchem-124 147 30 ( ( PUNCT eurjchem-124 147 31 atcc90028 atcc90028 PROPN eurjchem-124 147 32 ) ) PUNCT eurjchem-124 147 33 , , PUNCT eurjchem-124 147 34     SPACE eurjchem-124 147 35 c. c. PROPN eurjchem-124 147 36     SPACE eurjchem-124 147 37 glabrata glabrata PROPN eurjchem-124 147 38     SPACE eurjchem-124 147 39 ( ( PUNCT eurjchem-124 147 40 atcc atcc NOUN eurjchem-124 147 41     SPACE eurjchem-124 147 42 32554 32554 NUM eurjchem-124 147 43 ) ) PUNCT eurjchem-124 147 44 , , PUNCT eurjchem-124 147 45     SPACE eurjchem-124 147 46 c. c. PROPN eurjchem-124 147 47     SPACE eurjchem-124 147 48 tropicalis tropicali VERB eurjchem-124 147 49     SPACE eurjchem-124 147 50 ( ( PUNCT eurjchem-124 147 51 atcc atcc NOUN eurjchem-124 147 52     SPACE eurjchem-124 147 53 20336 20336 NUM eurjchem-124 147 54 ) ) PUNCT eurjchem-124 147 55 . . PUNCT eurjchem-124 147 56     SPACE eurjchem-124 148 1 fungal fungal ADJ eurjchem-124 148 2     SPACE eurjchem-124 148 3 colonies colony NOUN eurjchem-124 148 4     SPACE eurjchem-124 148 5 of of ADP eurjchem-124 148 6     SPACE eurjchem-124 148 7 the the DET eurjchem-124 148 8     SPACE eurjchem-124 148 9 test test NOUN eurjchem-124 148 10     SPACE eurjchem-124 148 11 organisms organism NOUN eurjchem-124 148 12     SPACE eurjchem-124 148 13 were be AUX eurjchem-124 148 14     SPACE eurjchem-124 148 15 suspended suspend VERB eurjchem-124 148 16     SPACE eurjchem-124 148 17 directly directly ADV eurjchem-124 148 18     SPACE eurjchem-124 148 19 into into ADP eurjchem-124 148 20     SPACE eurjchem-124 148 21 a a DET eurjchem-124 148 22     SPACE eurjchem-124 148 23 small small ADJ eurjchem-124 148 24     SPACE eurjchem-124 148 25 volume volume NOUN eurjchem-124 148 26     SPACE eurjchem-124 148 27 of of ADP eurjchem-124 148 28     SPACE eurjchem-124 148 29 0.9 0.9 NUM eurjchem-124 148 30 % % NOUN eurjchem-124 148 31     SPACE eurjchem-124 148 32 saline saline NOUN eurjchem-124 148 33     SPACE eurjchem-124 148 34 and and CCONJ eurjchem-124 148 35     SPACE eurjchem-124 148 36 further far ADV eurjchem-124 148 37     SPACE eurjchem-124 148 38 diluted dilute VERB eurjchem-124 148 39     SPACE eurjchem-124 148 40 until until SCONJ eurjchem-124 148 41     SPACE eurjchem-124 148 42 turbidity turbidity NOUN eurjchem-124 148 43     SPACE eurjchem-124 148 44 matched match VERB eurjchem-124 148 45     SPACE eurjchem-124 148 46 the the DET eurjchem-124 148 47     SPACE eurjchem-124 148 48 mc mc PROPN eurjchem-124 148 49     SPACE eurjchem-124 148 50 farland farland NOUN eurjchem-124 148 51     SPACE eurjchem-124 148 52 standard standard NOUN eurjchem-124 148 53     SPACE eurjchem-124 148 54 no no NOUN eurjchem-124 148 55 : : PUNCT eurjchem-124 148 56     SPACE eurjchem-124 148 57 0.5 0.5 NUM eurjchem-124 148 58     SPACE eurjchem-124 148 59 petri petri ADJ eurjchem-124 148 60     SPACE eurjchem-124 148 61 dishes dish NOUN eurjchem-124 148 62     SPACE eurjchem-124 148 63 sabouraud sabouraud NOUN eurjchem-124 148 64     SPACE eurjchem-124 148 65 and and CCONJ eurjchem-124 148 66     SPACE eurjchem-124 148 67 dextrose dextrose NOUN eurjchem-124 148 68     SPACE eurjchem-124 148 69 agar agar NOUN eurjchem-124 148 70     SPACE eurjchem-124 148 71 for for ADP eurjchem-124 148 72     SPACE eurjchem-124 148 73 fungi fungus NOUN eurjchem-124 148 74     SPACE eurjchem-124 148 75 were be AUX eurjchem-124 148 76     SPACE eurjchem-124 148 77 impregnated impregnate VERB eurjchem-124 148 78     SPACE eurjchem-124 148 79 with with ADP eurjchem-124 148 80     SPACE eurjchem-124 148 81 these these DET eurjchem-124 148 82     SPACE eurjchem-124 148 83 microbial microbial ADJ eurjchem-124 148 84     SPACE eurjchem-124 148 85 suspensions suspension NOUN eurjchem-124 148 86 . . PUNCT eurjchem-124 148 87     SPACE eurjchem-124 149 1 the the DET eurjchem-124 149 2     SPACE eurjchem-124 149 3 stock stock NOUN eurjchem-124 149 4     SPACE eurjchem-124 149 5 solutions solution NOUN eurjchem-124 149 6     SPACE eurjchem-124 149 7 of of ADP eurjchem-124 149 8     SPACE eurjchem-124 149 9 the the DET eurjchem-124 149 10     SPACE eurjchem-124 149 11 synthesized synthesize VERB eurjchem-124 149 12     SPACE eurjchem-124 149 13 compounds compound NOUN eurjchem-124 149 14     SPACE eurjchem-124 149 15 were be AUX eurjchem-124 149 16     SPACE eurjchem-124 149 17 prepared prepare VERB eurjchem-124 149 18     SPACE eurjchem-124 149 19 in in ADP eurjchem-124 149 20     SPACE eurjchem-124 149 21 dimethyl dimethyl NOUN eurjchem-124 149 22     SPACE eurjchem-124 149 23 sulfoxide sulfoxide NOUN eurjchem-124 149 24     SPACE eurjchem-124 149 25 ( ( PUNCT eurjchem-124 149 26 dmso dmso NOUN eurjchem-124 149 27 ) ) PUNCT eurjchem-124 149 28 , , PUNCT eurjchem-124 149 29     SPACE eurjchem-124 149 30 which which PRON eurjchem-124 149 31     SPACE eurjchem-124 149 32 had have VERB eurjchem-124 149 33     SPACE eurjchem-124 149 34 no no DET eurjchem-124 149 35     SPACE eurjchem-124 149 36 effect effect NOUN eurjchem-124 149 37     SPACE eurjchem-124 149 38 on on ADP eurjchem-124 149 39     SPACE eurjchem-124 149 40 the the DET eurjchem-124 149 41     SPACE eurjchem-124 149 42 organisms organism NOUN eurjchem-124 149 43     SPACE eurjchem-124 149 44 in in ADP eurjchem-124 149 45     SPACE eurjchem-124 149 46 the the DET eurjchem-124 149 47     SPACE eurjchem-124 149 48 concentrations concentration NOUN eurjchem-124 149 49     SPACE eurjchem-124 149 50 studied study VERB eurjchem-124 149 51 . . PUNCT eurjchem-124 149 52     SPACE eurjchem-124 150 1 the the DET eurjchem-124 150 2     SPACE eurjchem-124 150 3 initial initial ADJ eurjchem-124 150 4     SPACE eurjchem-124 150 5 concentration concentration NOUN eurjchem-124 150 6     SPACE eurjchem-124 150 7 was be AUX eurjchem-124 150 8     SPACE eurjchem-124 150 9 200 200 NUM eurjchem-124 150 10     SPACE eurjchem-124 150 11 mg mg PROPN eurjchem-124 150 12 / / SYM eurjchem-124 150 13 ml ml NOUN eurjchem-124 150 14 . . PUNCT eurjchem-124 150 15     SPACE eurjchem-124 150 16 all all PRON eurjchem-124 150 17     SPACE eurjchem-124 150 18 of of ADP eurjchem-124 150 19     SPACE eurjchem-124 150 20 the the DET eurjchem-124 150 21     SPACE eurjchem-124 150 22 dilutions dilution NOUN eurjchem-124 150 23     SPACE eurjchem-124 150 24 were be AUX eurjchem-124 150 25     SPACE eurjchem-124 150 26 done do VERB eurjchem-124 150 27     SPACE eurjchem-124 150 28 with with ADP eurjchem-124 150 29     SPACE eurjchem-124 150 30 distillated distillate VERB eurjchem-124 150 31     SPACE eurjchem-124 150 32 water water NOUN eurjchem-124 150 33 . . PUNCT eurjchem-124 150 34     SPACE eurjchem-124 151 1 the the DET eurjchem-124 151 2     SPACE eurjchem-124 151 3 concentrations concentration NOUN eurjchem-124 151 4     SPACE eurjchem-124 151 5 of of ADP eurjchem-124 151 6     SPACE eurjchem-124 151 7 tested test VERB eurjchem-124 151 8     SPACE eurjchem-124 151 9 compounds compound NOUN eurjchem-124 151 10     SPACE eurjchem-124 151 11 were be AUX eurjchem-124 151 12     SPACE eurjchem-124 151 13 100 100 NUM eurjchem-124 151 14 , , PUNCT eurjchem-124 151 15     SPACE eurjchem-124 151 16 50 50 NUM eurjchem-124 151 17 , , PUNCT eurjchem-124 151 18     SPACE eurjchem-124 151 19 25 25 NUM eurjchem-124 151 20 , , PUNCT eurjchem-124 151 21     SPACE eurjchem-124 151 22 12.5 12.5 NUM eurjchem-124 151 23 , , PUNCT eurjchem-124 151 24     SPACE eurjchem-124 151 25 6.25 6.25 NUM eurjchem-124 151 26 , , PUNCT eurjchem-124 151 27     SPACE eurjchem-124 151 28 3.125 3.125 NUM eurjchem-124 151 29     SPACE eurjchem-124 151 30 μg μg NOUN eurjchem-124 151 31 / / SYM eurjchem-124 151 32 ml ml PROPN eurjchem-124 151 33 . . PUNCT eurjchem-124 151 34     SPACE eurjchem-124 151 35 dmso dmso NOUN eurjchem-124 151 36     SPACE eurjchem-124 151 37 was be AUX eurjchem-124 151 38     SPACE eurjchem-124 151 39 used use VERB eurjchem-124 151 40     SPACE eurjchem-124 151 41 as as ADP eurjchem-124 151 42     SPACE eurjchem-124 151 43 negative negative ADJ eurjchem-124 151 44     SPACE eurjchem-124 151 45 control control NOUN eurjchem-124 151 46 . . PUNCT eurjchem-124 151 47     SPACE eurjchem-124 151 48 nystatin nystatin PROPN eurjchem-124 151 49     SPACE eurjchem-124 151 50 was be AUX eurjchem-124 151 51     SPACE eurjchem-124 151 52 used use VERB eurjchem-124 151 53     SPACE eurjchem-124 151 54 as as ADP eurjchem-124 151 55     SPACE eurjchem-124 151 56 reference reference NOUN eurjchem-124 151 57     SPACE eurjchem-124 151 58 drug drug NOUN eurjchem-124 151 59     SPACE eurjchem-124 151 60 for for ADP eurjchem-124 151 61     SPACE eurjchem-124 151 62 anti‐fungal anti‐fungal ADJ eurjchem-124 151 63     SPACE eurjchem-124 151 64 activity activity NOUN eurjchem-124 151 65 . . PUNCT eurjchem-124 151 66     SPACE eurjchem-124 152 1 all all DET eurjchem-124 152 2     SPACE eurjchem-124 152 3 the the DET eurjchem-124 152 4     SPACE eurjchem-124 152 5 inoculated inoculate VERB eurjchem-124 152 6     SPACE eurjchem-124 152 7 plates plate NOUN eurjchem-124 152 8     SPACE eurjchem-124 152 9 were be AUX eurjchem-124 152 10     SPACE eurjchem-124 152 11 incubated incubate VERB eurjchem-124 152 12     SPACE eurjchem-124 152 13 at at ADP eurjchem-124 152 14     SPACE eurjchem-124 152 15 37oc 37oc NOUN eurjchem-124 152 16     SPACE eurjchem-124 152 17 and and CCONJ eurjchem-124 152 18     SPACE eurjchem-124 152 19 results result NOUN eurjchem-124 152 20     SPACE eurjchem-124 152 21 were be AUX eurjchem-124 152 22     SPACE eurjchem-124 152 23 evaluated evaluate VERB eurjchem-124 152 24     SPACE eurjchem-124 152 25 after after ADP eurjchem-124 152 26     SPACE eurjchem-124 152 27 48 48 NUM eurjchem-124 152 28     SPACE eurjchem-124 152 29 h h NOUN eurjchem-124 152 30     SPACE eurjchem-124 152 31 for for ADP eurjchem-124 152 32     SPACE eurjchem-124 152 33 fungi fungus NOUN eurjchem-124 152 34 . . PUNCT eurjchem-124 152 35     SPACE eurjchem-124 153 1 the the DET eurjchem-124 153 2     SPACE eurjchem-124 153 3 lowest low ADJ eurjchem-124 153 4     SPACE eurjchem-124 153 5 concentration concentration NOUN eurjchem-124 153 6     SPACE eurjchem-124 153 7 of of ADP eurjchem-124 153 8     SPACE eurjchem-124 153 9 the the DET eurjchem-124 153 10     SPACE eurjchem-124 153 11 compounds compound NOUN eurjchem-124 153 12     SPACE eurjchem-124 153 13 that that PRON eurjchem-124 153 14     SPACE eurjchem-124 153 15 prevented prevent VERB eurjchem-124 153 16     SPACE eurjchem-124 153 17 visible visible ADJ eurjchem-124 153 18     SPACE eurjchem-124 153 19 growth growth NOUN eurjchem-124 153 20     SPACE eurjchem-124 153 21 was be AUX eurjchem-124 153 22     SPACE eurjchem-124 153 23 considered consider VERB eurjchem-124 153 24     SPACE eurjchem-124 153 25 minimal minimal ADJ eurjchem-124 153 26     SPACE eurjchem-124 153 27 inhibitor inhibitor NOUN eurjchem-124 153 28     SPACE eurjchem-124 153 29 concentrations concentration NOUN eurjchem-124 153 30     SPACE eurjchem-124 153 31 ( ( PUNCT eurjchem-124 153 32 mics mics PROPN eurjchem-124 153 33 ) ) PUNCT eurjchem-124 153 34 . . PUNCT eurjchem-124 153 35                 SPACE eurjchem-124 154 1 3 3 NUM eurjchem-124 154 2 . . PUNCT eurjchem-124 154 3     SPACE eurjchem-124 154 4 results result VERB eurjchem-124 154 5     SPACE eurjchem-124 154 6 and and CCONJ eurjchem-124 154 7     SPACE eurjchem-124 154 8 discussion discussion NOUN eurjchem-124 154 9           SPACE eurjchem-124 154 10 3.1 3.1 NUM eurjchem-124 154 11 . . PUNCT eurjchem-124 154 12     SPACE eurjchem-124 154 13 synthesis synthesis NOUN eurjchem-124 154 14     SPACE eurjchem-124 154 15 and and CCONJ eurjchem-124 154 16     SPACE eurjchem-124 154 17 spectral spectral ADJ eurjchem-124 154 18     SPACE eurjchem-124 154 19 studies study NOUN eurjchem-124 154 20         SPACE eurjchem-124 154 21 all all DET eurjchem-124 154 22     SPACE eurjchem-124 154 23 thioureas thiourea NOUN eurjchem-124 154 24     SPACE eurjchem-124 154 25 ( ( PUNCT eurjchem-124 154 26 1­12 1­12 NOUN eurjchem-124 154 27 ) ) PUNCT eurjchem-124 154 28     SPACE eurjchem-124 154 29 were be AUX eurjchem-124 154 30     SPACE eurjchem-124 154 31 synthesized synthesize VERB eurjchem-124 154 32     SPACE eurjchem-124 154 33 according accord VERB eurjchem-124 154 34     SPACE eurjchem-124 154 35 to to ADP eurjchem-124 154 36     SPACE eurjchem-124 154 37 the the DET eurjchem-124 154 38     SPACE eurjchem-124 154 39 method method NOUN eurjchem-124 154 40     SPACE eurjchem-124 154 41 of of ADP eurjchem-124 154 42     SPACE eurjchem-124 154 43 our our PRON eurjchem-124 154 44     SPACE eurjchem-124 154 45 published publish VERB eurjchem-124 154 46     SPACE eurjchem-124 154 47 papers paper NOUN eurjchem-124 154 48     SPACE eurjchem-124 155 1 [ [ X eurjchem-124 155 2 33,34 33,34 NOUN eurjchem-124 155 3 ] ] SYM eurjchem-124 155 4     SPACE eurjchem-124 155 5 and and CCONJ eurjchem-124 155 6     SPACE eurjchem-124 155 7 were be AUX eurjchem-124 155 8     SPACE eurjchem-124 155 9 obtained obtain VERB eurjchem-124 155 10     SPACE eurjchem-124 155 11 in in ADP eurjchem-124 155 12     SPACE eurjchem-124 155 13 yields yield NOUN eurjchem-124 155 14     SPACE eurjchem-124 155 15 ranging range VERB eurjchem-124 155 16     SPACE eurjchem-124 155 17 from from ADP eurjchem-124 155 18     SPACE eurjchem-124 155 19 86 86 NUM eurjchem-124 155 20     SPACE eurjchem-124 155 21 to to ADP eurjchem-124 155 22     SPACE eurjchem-124 155 23 95 95 NUM eurjchem-124 155 24 % % NOUN eurjchem-124 155 25 . . PUNCT eurjchem-124 155 26     SPACE eurjchem-124 156 1 the the DET eurjchem-124 156 2     SPACE eurjchem-124 156 3 synthesis synthesis NOUN eurjchem-124 156 4     SPACE eurjchem-124 156 5 involves involve VERB eurjchem-124 156 6     SPACE eurjchem-124 156 7 the the DET eurjchem-124 156 8     SPACE eurjchem-124 156 9 reaction reaction NOUN eurjchem-124 156 10     SPACE eurjchem-124 156 11 of of ADP eurjchem-124 156 12     SPACE eurjchem-124 156 13 thiophene‐2‐carbonyl thiophene‐2‐carbonyl NOUN eurjchem-124 156 14     SPACE eurjchem-124 156 15 chloride chloride NOUN eurjchem-124 156 16     SPACE eurjchem-124 156 17 with with ADP eurjchem-124 156 18     SPACE eurjchem-124 156 19 ammonium ammonium NOUN eurjchem-124 156 20     SPACE eurjchem-124 156 21 thiocyanate thiocyanate NOUN eurjchem-124 156 22     SPACE eurjchem-124 156 23 in in ADP eurjchem-124 156 24     SPACE eurjchem-124 156 25 dry dry ADJ eurjchem-124 156 26     SPACE eurjchem-124 156 27 acetone acetone NOUN eurjchem-124 156 28     SPACE eurjchem-124 156 29 followed follow VERB eurjchem-124 156 30     SPACE eurjchem-124 156 31 by by ADP eurjchem-124 156 32     SPACE eurjchem-124 156 33 condensation condensation NOUN eurjchem-124 156 34     SPACE eurjchem-124 156 35 of of ADP eurjchem-124 156 36     SPACE eurjchem-124 156 37 the the DET eurjchem-124 156 38     SPACE eurjchem-124 156 39 resulting result VERB eurjchem-124 156 40     SPACE eurjchem-124 156 41 thiophene‐2‐carbonyl thiophene‐2‐carbonyl NUM eurjchem-124 156 42     SPACE eurjchem-124 156 43 isothiocyanate isothiocyanate NOUN eurjchem-124 156 44     SPACE eurjchem-124 156 45 with with ADP eurjchem-124 156 46     SPACE eurjchem-124 156 47 an an DET eurjchem-124 156 48     SPACE eurjchem-124 156 49 appropriate appropriate ADJ eurjchem-124 156 50     SPACE eurjchem-124 156 51 primary primary NOUN eurjchem-124 156 52     SPACE eurjchem-124 156 53 and and CCONJ eurjchem-124 156 54     SPACE eurjchem-124 156 55 secondary secondary ADJ eurjchem-124 156 56     SPACE eurjchem-124 156 57 amine amine NOUN eurjchem-124 156 58 . . PUNCT eurjchem-124 156 59     SPACE eurjchem-124 156 60 the the DET eurjchem-124 156 61     SPACE eurjchem-124 156 62 reaction reaction NOUN eurjchem-124 156 63     SPACE eurjchem-124 156 64 proceeds proceed NOUN eurjchem-124 156 65     SPACE eurjchem-124 156 66 via via ADP eurjchem-124 156 67     SPACE eurjchem-124 156 68 a a DET eurjchem-124 156 69     SPACE eurjchem-124 156 70 nucleophilic nucleophilic ADJ eurjchem-124 156 71     SPACE eurjchem-124 156 72 addition addition NOUN eurjchem-124 156 73     SPACE eurjchem-124 156 74 of of ADP eurjchem-124 156 75     SPACE eurjchem-124 156 76 the the DET eurjchem-124 156 77     SPACE eurjchem-124 156 78 amine amine NOUN eurjchem-124 156 79     SPACE eurjchem-124 156 80 to to ADP eurjchem-124 156 81     SPACE eurjchem-124 156 82 the the DET eurjchem-124 156 83     SPACE eurjchem-124 156 84 isothiocyanate isothiocyanate NOUN eurjchem-124 156 85 . . PUNCT eurjchem-124 156 86     SPACE eurjchem-124 157 1 the the DET eurjchem-124 157 2     SPACE eurjchem-124 157 3 synthesized synthesize VERB eurjchem-124 157 4     SPACE eurjchem-124 157 5 compounds compound NOUN eurjchem-124 157 6     SPACE eurjchem-124 157 7 were be AUX eurjchem-124 157 8     SPACE eurjchem-124 157 9 purified purify VERB eurjchem-124 157 10     SPACE eurjchem-124 157 11 by by ADP eurjchem-124 157 12     SPACE eurjchem-124 157 13 recrystallization recrystallization NOUN eurjchem-124 157 14     SPACE eurjchem-124 157 15 from from ADP eurjchem-124 157 16     SPACE eurjchem-124 157 17 an an DET eurjchem-124 157 18     SPACE eurjchem-124 157 19 ethanol ethanol NOUN eurjchem-124 157 20 : : PUNCT eurjchem-124 157 21     SPACE eurjchem-124 157 22 dichloromethane dichloromethane NOUN eurjchem-124 157 23     SPACE eurjchem-124 157 24 mixture mixture NOUN eurjchem-124 157 25     SPACE eurjchem-124 157 26 ( ( PUNCT eurjchem-124 157 27 1:2 1:2 NUM eurjchem-124 157 28 ) ) PUNCT eurjchem-124 157 29     SPACE eurjchem-124 157 30 and and CCONJ eurjchem-124 157 31     SPACE eurjchem-124 157 32 characterized characterize VERB eurjchem-124 157 33     SPACE eurjchem-124 157 34 by by ADP eurjchem-124 157 35     SPACE eurjchem-124 157 36 elemental elemental ADJ eurjchem-124 157 37     SPACE eurjchem-124 157 38 analysis analysis NOUN eurjchem-124 157 39 , , PUNCT eurjchem-124 157 40     SPACE eurjchem-124 157 41 1h 1h NUM eurjchem-124 157 42     SPACE eurjchem-124 157 43 nmr nmr NOUN eurjchem-124 157 44 , , PUNCT eurjchem-124 157 45     SPACE eurjchem-124 157 46 13c 13c NOUN eurjchem-124 157 47     SPACE eurjchem-124 157 48 nmr nmr NOUN eurjchem-124 157 49 , , PUNCT eurjchem-124 157 50     SPACE eurjchem-124 157 51 and and CCONJ eurjchem-124 157 52     SPACE eurjchem-124 157 53 ft‐ir ft‐ir NOUN eurjchem-124 157 54     SPACE eurjchem-124 157 55 spectroscopy spectroscopy NOUN eurjchem-124 157 56 . . PUNCT eurjchem-124 157 57     SPACE eurjchem-124 158 1 the the DET eurjchem-124 158 2     SPACE eurjchem-124 158 3 1h 1h NUM eurjchem-124 158 4     SPACE eurjchem-124 158 5 nmr nmr NOUN eurjchem-124 158 6     SPACE eurjchem-124 158 7 data datum NOUN eurjchem-124 158 8     SPACE eurjchem-124 158 9 of of ADP eurjchem-124 158 10     SPACE eurjchem-124 158 11 the the DET eurjchem-124 158 12     SPACE eurjchem-124 158 13 compound compound NOUN eurjchem-124 158 14     SPACE eurjchem-124 158 15 obtained obtain VERB eurjchem-124 158 16     SPACE eurjchem-124 158 17 in in ADP eurjchem-124 158 18     SPACE eurjchem-124 158 19 dmso‐d6 dmso‐d6 NOUN eurjchem-124 158 20     SPACE eurjchem-124 158 21 solution solution NOUN eurjchem-124 158 22     SPACE eurjchem-124 158 23 is be AUX eurjchem-124 158 24     SPACE eurjchem-124 158 25 given give VERB eurjchem-124 158 26     SPACE eurjchem-124 158 27 in in ADP eurjchem-124 158 28     SPACE eurjchem-124 158 29 the the DET eurjchem-124 158 30     SPACE eurjchem-124 158 31 experimental experimental ADJ eurjchem-124 158 32     SPACE eurjchem-124 158 33 section section NOUN eurjchem-124 158 34     SPACE eurjchem-124 158 35 and and CCONJ eurjchem-124 158 36     SPACE eurjchem-124 158 37 is be AUX eurjchem-124 158 38     SPACE eurjchem-124 158 39 consistent consistent ADJ eurjchem-124 158 40     SPACE eurjchem-124 158 41 with with ADP eurjchem-124 158 42     SPACE eurjchem-124 158 43 the the DET eurjchem-124 158 44     SPACE eurjchem-124 158 45 structural structural ADJ eurjchem-124 158 46     SPACE eurjchem-124 158 47 results result NOUN eurjchem-124 158 48 . . PUNCT eurjchem-124 158 49     SPACE eurjchem-124 159 1 the the DET eurjchem-124 159 2     SPACE eurjchem-124 159 3 elemental elemental NOUN eurjchem-124 159 4     SPACE eurjchem-124 159 5 analyses analysis NOUN eurjchem-124 159 6     SPACE eurjchem-124 159 7 closely closely ADV eurjchem-124 159 8     SPACE eurjchem-124 159 9 corresponded correspond VERB eurjchem-124 159 10     SPACE eurjchem-124 159 11 to to PART eurjchem-124 159 12     SPACE eurjchem-124 159 13 calculated calculate VERB eurjchem-124 159 14     SPACE eurjchem-124 159 15 values value NOUN eurjchem-124 159 16 . . PUNCT eurjchem-124 159 17     SPACE eurjchem-124 160 1 the the DET eurjchem-124 160 2     SPACE eurjchem-124 160 3 analytical analytical NOUN eurjchem-124 160 4     SPACE eurjchem-124 160 5 and and CCONJ eurjchem-124 160 6     SPACE eurjchem-124 160 7 spectroscopic spectroscopic NOUN eurjchem-124 160 8     SPACE eurjchem-124 160 9 data datum NOUN eurjchem-124 160 10     SPACE eurjchem-124 160 11 are be AUX eurjchem-124 160 12     SPACE eurjchem-124 160 13 consistent consistent ADJ eurjchem-124 160 14     SPACE eurjchem-124 160 15 with with ADP eurjchem-124 160 16     SPACE eurjchem-124 160 17 the the DET eurjchem-124 160 18     SPACE eurjchem-124 160 19 proposed propose VERB eurjchem-124 160 20     SPACE eurjchem-124 160 21 structures structure NOUN eurjchem-124 160 22     SPACE eurjchem-124 160 23 [ [ X eurjchem-124 160 24 35 35 NUM eurjchem-124 160 25 ] ] PUNCT eurjchem-124 160 26 . . PUNCT eurjchem-124 160 27     SPACE eurjchem-124 161 1 the the DET eurjchem-124 161 2     SPACE eurjchem-124 161 3 synthesized synthesize VERB eurjchem-124 161 4     SPACE eurjchem-124 161 5 compounds compound NOUN eurjchem-124 161 6     SPACE eurjchem-124 161 7 are be AUX eurjchem-124 161 8     SPACE eurjchem-124 161 9 easily easily ADV eurjchem-124 161 10     SPACE eurjchem-124 161 11 dissolved dissolve VERB eurjchem-124 161 12     SPACE eurjchem-124 161 13 in in ADP eurjchem-124 161 14     SPACE eurjchem-124 161 15 dmf dmf PROPN eurjchem-124 161 16 , , PUNCT eurjchem-124 161 17     SPACE eurjchem-124 161 18 dmso dmso NOUN eurjchem-124 161 19 , , PUNCT eurjchem-124 161 20     SPACE eurjchem-124 161 21 ethanol ethanol NOUN eurjchem-124 161 22     SPACE eurjchem-124 161 23 and and CCONJ eurjchem-124 161 24     SPACE eurjchem-124 161 25 saeed saeed PROPN eurjchem-124 161 26     SPACE eurjchem-124 161 27 et et PROPN eurjchem-124 161 28     SPACE eurjchem-124 161 29 al al PROPN eurjchem-124 161 30 . . PROPN eurjchem-124 161 31     SPACE eurjchem-124 161 32 / / SYM eurjchem-124 161 33     SPACE eurjchem-124 161 34 european european ADJ eurjchem-124 161 35     SPACE eurjchem-124 161 36 journal journal NOUN eurjchem-124 161 37     SPACE eurjchem-124 161 38 of of ADP eurjchem-124 161 39     SPACE eurjchem-124 161 40 chemistry chemistry NOUN eurjchem-124 161 41     SPACE eurjchem-124 161 42 1 1 NUM eurjchem-124 161 43     SPACE eurjchem-124 161 44 ( ( PUNCT eurjchem-124 161 45 3 3 NUM eurjchem-124 161 46 ) ) PUNCT eurjchem-124 161 47     SPACE eurjchem-124 161 48 ( ( PUNCT eurjchem-124 161 49 2010 2010 NUM eurjchem-124 161 50 ) ) PUNCT eurjchem-124 161 51     SPACE eurjchem-124 161 52 221­227 221­227 NUM eurjchem-124 161 53     SPACE eurjchem-124 161 54 225 225 NUM eurjchem-124 161 55     SPACE eurjchem-124 161 56 ethyl ethyl PROPN eurjchem-124 161 57     SPACE eurjchem-124 161 58 acetate acetate NOUN eurjchem-124 161 59 . . PUNCT eurjchem-124 161 60     SPACE eurjchem-124 162 1 they they PRON eurjchem-124 162 2     SPACE eurjchem-124 162 3 are be AUX eurjchem-124 162 4     SPACE eurjchem-124 162 5 sparingly sparingly ADV eurjchem-124 162 6     SPACE eurjchem-124 162 7 soluble soluble ADJ eurjchem-124 162 8     SPACE eurjchem-124 162 9 in in ADP eurjchem-124 162 10     SPACE eurjchem-124 162 11 diethyl diethyl NOUN eurjchem-124 162 12     SPACE eurjchem-124 162 13 ether ether NOUN eurjchem-124 162 14 , , PUNCT eurjchem-124 162 15     SPACE eurjchem-124 162 16 dioxane dioxane NOUN eurjchem-124 162 17 , , PUNCT eurjchem-124 162 18     SPACE eurjchem-124 162 19 tetrahydrofurane tetrahydrofurane ADJ eurjchem-124 162 20     SPACE eurjchem-124 162 21 while while SCONJ eurjchem-124 162 22     SPACE eurjchem-124 162 23 insoluble insoluble ADJ eurjchem-124 162 24     SPACE eurjchem-124 162 25 in in ADP eurjchem-124 162 26     SPACE eurjchem-124 162 27 aliphatic aliphatic NOUN eurjchem-124 162 28     SPACE eurjchem-124 162 29 and and CCONJ eurjchem-124 162 30     SPACE eurjchem-124 162 31 aromatic aromatic ADJ eurjchem-124 162 32     SPACE eurjchem-124 162 33 hydrocarbons hydrocarbon NOUN eurjchem-124 162 34 . . PUNCT eurjchem-124 162 35     SPACE eurjchem-124 163 1 the the DET eurjchem-124 163 2     SPACE eurjchem-124 163 3 main main ADJ eurjchem-124 163 4     SPACE eurjchem-124 163 5 vibrational vibrational NOUN eurjchem-124 163 6     SPACE eurjchem-124 163 7 bands band NOUN eurjchem-124 163 8     SPACE eurjchem-124 163 9 of of ADP eurjchem-124 163 10     SPACE eurjchem-124 163 11 the the DET eurjchem-124 163 12     SPACE eurjchem-124 163 13 compounds compound NOUN eurjchem-124 163 14     SPACE eurjchem-124 163 15 1­12 1­12 NOUN eurjchem-124 163 16     SPACE eurjchem-124 163 17 are be AUX eurjchem-124 163 18     SPACE eurjchem-124 163 19 given give VERB eurjchem-124 163 20     SPACE eurjchem-124 163 21 in in ADP eurjchem-124 163 22     SPACE eurjchem-124 163 23 the the DET eurjchem-124 163 24     SPACE eurjchem-124 163 25 experimental experimental ADJ eurjchem-124 163 26     SPACE eurjchem-124 163 27 section section NOUN eurjchem-124 163 28 . . PUNCT eurjchem-124 163 29     SPACE eurjchem-124 164 1 ir ir PROPN eurjchem-124 164 2     SPACE eurjchem-124 164 3 ( ( PUNCT eurjchem-124 164 4 kbr kbr PROPN eurjchem-124 164 5 ) ) PUNCT eurjchem-124 164 6     SPACE eurjchem-124 164 7 spectra spectra NOUN eurjchem-124 164 8     SPACE eurjchem-124 164 9 of of ADP eurjchem-124 164 10     SPACE eurjchem-124 164 11 the the DET eurjchem-124 164 12     SPACE eurjchem-124 164 13 target target NOUN eurjchem-124 164 14     SPACE eurjchem-124 164 15 compounds compound NOUN eurjchem-124 164 16     SPACE eurjchem-124 164 17 had have VERB eurjchem-124 164 18     SPACE eurjchem-124 164 19 strong strong ADJ eurjchem-124 164 20     SPACE eurjchem-124 164 21 n‐h n‐h SYM eurjchem-124 164 22     SPACE eurjchem-124 164 23 absorptions absorption NOUN eurjchem-124 164 24     SPACE eurjchem-124 164 25 at at ADP eurjchem-124 164 26     SPACE eurjchem-124 164 27 about about ADP eurjchem-124 164 28     SPACE eurjchem-124 164 29 3345‐3200 3345‐3200 NUM eurjchem-124 164 30     SPACE eurjchem-124 164 31 cm‐1 cm‐1 NOUN eurjchem-124 164 32 , , PUNCT eurjchem-124 164 33     SPACE eurjchem-124 164 34 and and CCONJ eurjchem-124 164 35     SPACE eurjchem-124 164 36 displayed display VERB eurjchem-124 164 37     SPACE eurjchem-124 164 38 absorp‐ absorp‐ NOUN eurjchem-124 164 39 tions tion NOUN eurjchem-124 164 40     SPACE eurjchem-124 164 41 at at ADP eurjchem-124 164 42     SPACE eurjchem-124 164 43 about about ADV eurjchem-124 164 44     SPACE eurjchem-124 164 45 1680‐1670 1680‐1670 NUM eurjchem-124 164 46     SPACE eurjchem-124 164 47 cm‐1 cm‐1 NOUN eurjchem-124 164 48     SPACE eurjchem-124 164 49 and and CCONJ eurjchem-124 164 50     SPACE eurjchem-124 164 51 ~1240 ~1240 NOUN eurjchem-124 164 52     SPACE eurjchem-124 164 53 cm‐1 cm‐1 NOUN eurjchem-124 164 54     SPACE eurjchem-124 164 55 that that PRON eurjchem-124 164 56     SPACE eurjchem-124 164 57 were be AUX eurjchem-124 164 58     SPACE eurjchem-124 164 59 assigned assign VERB eurjchem-124 164 60     SPACE eurjchem-124 164 61 to to ADP eurjchem-124 164 62     SPACE eurjchem-124 164 63 c c NOUN eurjchem-124 164 64 = = VERB eurjchem-124 164 65 o o NOUN eurjchem-124 164 66     SPACE eurjchem-124 164 67 and and CCONJ eurjchem-124 164 68     SPACE eurjchem-124 164 69 c c PROPN eurjchem-124 164 70 = = SYM eurjchem-124 164 71 s s NOUN eurjchem-124 164 72     SPACE eurjchem-124 164 73 functions function NOUN eurjchem-124 164 74     SPACE eurjchem-124 164 75 respectively respectively ADV eurjchem-124 164 76 . . PUNCT eurjchem-124 164 77     SPACE eurjchem-124 165 1 the the DET eurjchem-124 165 2     SPACE eurjchem-124 165 3 medium‐ medium‐ X eurjchem-124 165 4 strong strong ADJ eurjchem-124 165 5     SPACE eurjchem-124 165 6 υc υc PROPN eurjchem-124 165 7 = = NOUN eurjchem-124 165 8 o o NOUN eurjchem-124 165 9     SPACE eurjchem-124 165 10 band band NOUN eurjchem-124 165 11     SPACE eurjchem-124 165 12 in in ADP eurjchem-124 165 13     SPACE eurjchem-124 165 14 the the DET eurjchem-124 165 15     SPACE eurjchem-124 165 16 ir ir PROPN eurjchem-124 165 17     SPACE eurjchem-124 165 18 spectra spectra NOUN eurjchem-124 165 19     SPACE eurjchem-124 165 20 of of ADP eurjchem-124 165 21     SPACE eurjchem-124 165 22 the the DET eurjchem-124 165 23     SPACE eurjchem-124 165 24 compound compound NOUN eurjchem-124 165 25     SPACE eurjchem-124 165 26 appeared appear VERB eurjchem-124 165 27     SPACE eurjchem-124 165 28 at at ADP eurjchem-124 165 29     SPACE eurjchem-124 165 30 1680 1680 NUM eurjchem-124 165 31     SPACE eurjchem-124 165 32 cm‐1 cm‐1 NOUN eurjchem-124 165 33 , , PUNCT eurjchem-124 165 34     SPACE eurjchem-124 165 35 which which PRON eurjchem-124 165 36     SPACE eurjchem-124 165 37 is be AUX eurjchem-124 165 38     SPACE eurjchem-124 165 39 lower low ADJ eurjchem-124 165 40     SPACE eurjchem-124 165 41 than than ADP eurjchem-124 165 42     SPACE eurjchem-124 165 43 that that SCONJ eurjchem-124 165 44     SPACE eurjchem-124 165 45 of of ADP eurjchem-124 165 46     SPACE eurjchem-124 165 47 the the DET eurjchem-124 165 48     SPACE eurjchem-124 165 49 ordinary ordinary ADJ eurjchem-124 165 50     SPACE eurjchem-124 165 51 carbonyl carbonyl NOUN eurjchem-124 165 52     SPACE eurjchem-124 165 53 absorption absorption NOUN eurjchem-124 165 54     SPACE eurjchem-124 165 55 ( ( PUNCT eurjchem-124 165 56 1730 1730 NUM eurjchem-124 165 57     SPACE eurjchem-124 165 58 cm‐1 cm‐1 NOUN eurjchem-124 165 59 ) ) PUNCT eurjchem-124 165 60 ; ; PUNCT eurjchem-124 165 61     SPACE eurjchem-124 165 62 this this PRON eurjchem-124 165 63     SPACE eurjchem-124 165 64 may may AUX eurjchem-124 165 65     SPACE eurjchem-124 165 66 be be AUX eurjchem-124 165 67     SPACE eurjchem-124 165 68 attributed attribute VERB eurjchem-124 165 69     SPACE eurjchem-124 165 70 to to ADP eurjchem-124 165 71     SPACE eurjchem-124 165 72 the the DET eurjchem-124 165 73     SPACE eurjchem-124 165 74 formation formation NOUN eurjchem-124 165 75     SPACE eurjchem-124 165 76 of of ADP eurjchem-124 165 77     SPACE eurjchem-124 165 78 hydrogen hydrogen NOUN eurjchem-124 165 79     SPACE eurjchem-124 165 80 bonds bond NOUN eurjchem-124 165 81 . . PUNCT eurjchem-124 165 82     SPACE eurjchem-124 166 1 these these DET eurjchem-124 166 2     SPACE eurjchem-124 166 3 results result NOUN eurjchem-124 166 4     SPACE eurjchem-124 166 5 agree agree VERB eurjchem-124 166 6     SPACE eurjchem-124 166 7 with with ADP eurjchem-124 166 8     SPACE eurjchem-124 166 9 the the DET eurjchem-124 166 10     SPACE eurjchem-124 166 11 data datum NOUN eurjchem-124 166 12     SPACE eurjchem-124 166 13 in in ADP eurjchem-124 166 14     SPACE eurjchem-124 166 15 the the DET eurjchem-124 166 16     SPACE eurjchem-124 166 17 literature literature NOUN eurjchem-124 166 18     SPACE eurjchem-124 167 1 [ [ X eurjchem-124 167 2 36 36 NUM eurjchem-124 167 3 ] ] PUNCT eurjchem-124 167 4 . . PUNCT eurjchem-124 167 5     SPACE eurjchem-124 167 6 in in ADP eurjchem-124 167 7     SPACE eurjchem-124 167 8 1h 1h NUM eurjchem-124 167 9     SPACE eurjchem-124 167 10 nmr nmr NOUN eurjchem-124 167 11 , , PUNCT eurjchem-124 167 12     SPACE eurjchem-124 167 13 the the DET eurjchem-124 167 14     SPACE eurjchem-124 167 15 compounds compound NOUN eurjchem-124 167 16     SPACE eurjchem-124 167 17 exhibited exhibit VERB eurjchem-124 167 18     SPACE eurjchem-124 167 19 broad broad ADJ eurjchem-124 167 20     SPACE eurjchem-124 167 21 signals signal NOUN eurjchem-124 167 22     SPACE eurjchem-124 167 23 in in ADP eurjchem-124 167 24     SPACE eurjchem-124 167 25 the the DET eurjchem-124 167 26     SPACE eurjchem-124 167 27 range range NOUN eurjchem-124 167 28     SPACE eurjchem-124 167 29 of of ADP eurjchem-124 167 30     SPACE eurjchem-124 167 31 12.78‐12.20 12.78‐12.20 NUM eurjchem-124 167 32     SPACE eurjchem-124 167 33 ppm ppm NOUN eurjchem-124 167 34     SPACE eurjchem-124 167 35 and and CCONJ eurjchem-124 167 36     SPACE eurjchem-124 167 37 11.92‐11.37 11.92‐11.37 NUM eurjchem-124 167 38     SPACE eurjchem-124 167 39 ppm ppm NOUN eurjchem-124 167 40 , , PUNCT eurjchem-124 167 41     SPACE eurjchem-124 167 42 which which PRON eurjchem-124 167 43     SPACE eurjchem-124 167 44 were be AUX eurjchem-124 167 45     SPACE eurjchem-124 167 46 assigned assign VERB eurjchem-124 167 47     SPACE eurjchem-124 167 48 to to ADP eurjchem-124 167 49     SPACE eurjchem-124 167 50 the the DET eurjchem-124 167 51     SPACE eurjchem-124 167 52 n‐h n‐h NOUN eurjchem-124 167 53     SPACE eurjchem-124 167 54 protons proton NOUN eurjchem-124 167 55 . . PUNCT eurjchem-124 167 56     SPACE eurjchem-124 168 1 generally generally ADV eurjchem-124 168 2     SPACE eurjchem-124 168 3 the the DET eurjchem-124 168 4     SPACE eurjchem-124 168 5 nmr nmr NOUN eurjchem-124 168 6     SPACE eurjchem-124 168 7 signals signal NOUN eurjchem-124 168 8     SPACE eurjchem-124 168 9 of of ADP eurjchem-124 168 10     SPACE eurjchem-124 168 11 nh nh PROPN eurjchem-124 168 12     SPACE eurjchem-124 168 13 protons proton NOUN eurjchem-124 168 14     SPACE eurjchem-124 168 15 for for ADP eurjchem-124 168 16     SPACE eurjchem-124 168 17 amides amide NOUN eurjchem-124 168 18     SPACE eurjchem-124 168 19 are be AUX eurjchem-124 168 20     SPACE eurjchem-124 168 21 observed observe VERB eurjchem-124 168 22     SPACE eurjchem-124 168 23 in in ADP eurjchem-124 168 24     SPACE eurjchem-124 168 25 the the DET eurjchem-124 168 26     SPACE eurjchem-124 168 27 range range NOUN eurjchem-124 168 28     SPACE eurjchem-124 168 29 of of ADP eurjchem-124 168 30     SPACE eurjchem-124 168 31 9‐10 9‐10 NUM eurjchem-124 168 32     SPACE eurjchem-124 168 33 ppm ppm NOUN eurjchem-124 168 34 . . PUNCT eurjchem-124 168 35     SPACE eurjchem-124 169 1 the the DET eurjchem-124 169 2     SPACE eurjchem-124 169 3 low‐field low‐field ADJ eurjchem-124 169 4     SPACE eurjchem-124 169 5 shift shift NOUN eurjchem-124 169 6     SPACE eurjchem-124 169 7 of of ADP eurjchem-124 169 8     SPACE eurjchem-124 169 9 the the DET eurjchem-124 169 10     SPACE eurjchem-124 169 11 signal signal NOUN eurjchem-124 169 12     SPACE eurjchem-124 169 13 for for ADP eurjchem-124 169 14     SPACE eurjchem-124 169 15 the the DET eurjchem-124 169 16     SPACE eurjchem-124 169 17 imine imine NOUN eurjchem-124 169 18     SPACE eurjchem-124 169 19 proton proton NOUN eurjchem-124 169 20     SPACE eurjchem-124 169 21 for for ADP eurjchem-124 169 22     SPACE eurjchem-124 169 23 synthesized synthesize VERB eurjchem-124 169 24     SPACE eurjchem-124 169 25 compounds compound NOUN eurjchem-124 169 26     SPACE eurjchem-124 169 27 can can AUX eurjchem-124 169 28     SPACE eurjchem-124 169 29 be be AUX eurjchem-124 169 30     SPACE eurjchem-124 169 31 attributed attribute VERB eurjchem-124 169 32     SPACE eurjchem-124 169 33 to to ADP eurjchem-124 169 34     SPACE eurjchem-124 169 35 the the DET eurjchem-124 169 36     SPACE eurjchem-124 169 37 deshielding deshielding NOUN eurjchem-124 169 38     SPACE eurjchem-124 169 39 effect effect NOUN eurjchem-124 169 40     SPACE eurjchem-124 169 41 of of ADP eurjchem-124 169 42     SPACE eurjchem-124 169 43 the the DET eurjchem-124 169 44     SPACE eurjchem-124 169 45 electron‐withdrawing electron‐withdrawing NOUN eurjchem-124 169 46     SPACE eurjchem-124 169 47 carbonyl carbonyl NOUN eurjchem-124 169 48     SPACE eurjchem-124 169 49 and and CCONJ eurjchem-124 169 50     SPACE eurjchem-124 169 51 thiocarbonyl thiocarbonyl NOUN eurjchem-124 169 52     SPACE eurjchem-124 169 53 group group NOUN eurjchem-124 169 54 . . PUNCT eurjchem-124 169 55     SPACE eurjchem-124 169 56 13c 13c NOUN eurjchem-124 169 57     SPACE eurjchem-124 169 58 nmr nmr NOUN eurjchem-124 169 59     SPACE eurjchem-124 169 60 spectrum spectrum NOUN eurjchem-124 169 61     SPACE eurjchem-124 169 62 showed show VERB eurjchem-124 169 63     SPACE eurjchem-124 169 64 the the DET eurjchem-124 169 65     SPACE eurjchem-124 169 66 peaks peak NOUN eurjchem-124 169 67     SPACE eurjchem-124 169 68 at at ADP eurjchem-124 169 69     SPACE eurjchem-124 169 70 about about ADP eurjchem-124 169 71     SPACE eurjchem-124 169 72 δ δ PROPN eurjchem-124 169 73     SPACE eurjchem-124 169 74 180.0‐178 180.0‐178 NUM eurjchem-124 169 75     SPACE eurjchem-124 169 76 and and CCONJ eurjchem-124 169 77     SPACE eurjchem-124 169 78 170.1‐162.2 170.1‐162.2 NOUN eurjchem-124 169 79     SPACE eurjchem-124 169 80 for for ADP eurjchem-124 169 81     SPACE eurjchem-124 169 82 c c PROPN eurjchem-124 170 1 = = VERB eurjchem-124 170 2 s s NOUN eurjchem-124 170 3     SPACE eurjchem-124 170 4 ( ( PUNCT eurjchem-124 170 5 thioamide thioamide NOUN eurjchem-124 170 6 ) ) PUNCT eurjchem-124 170 7     SPACE eurjchem-124 170 8 and and CCONJ eurjchem-124 170 9     SPACE eurjchem-124 170 10 c c NOUN eurjchem-124 170 11 = = VERB eurjchem-124 170 12 o o NOUN eurjchem-124 170 13     SPACE eurjchem-124 170 14 ( ( PUNCT eurjchem-124 170 15 amide amide NOUN eurjchem-124 170 16 ) ) PUNCT eurjchem-124 170 17 , , PUNCT eurjchem-124 170 18     SPACE eurjchem-124 170 19 respectively respectively ADV eurjchem-124 170 20 . . PUNCT eurjchem-124 170 21     SPACE eurjchem-124 170 22 the the DET eurjchem-124 170 23     SPACE eurjchem-124 170 24 mass mass NOUN eurjchem-124 170 25     SPACE eurjchem-124 170 26 spectrum spectrum NOUN eurjchem-124 170 27     SPACE eurjchem-124 170 28 of of ADP eurjchem-124 170 29     SPACE eurjchem-124 170 30 compound compound NOUN eurjchem-124 170 31     SPACE eurjchem-124 170 32 6 6 NUM eurjchem-124 170 33     SPACE eurjchem-124 170 34 showed show VERB eurjchem-124 170 35     SPACE eurjchem-124 170 36 the the DET eurjchem-124 170 37     SPACE eurjchem-124 170 38 molecular molecular ADJ eurjchem-124 170 39     SPACE eurjchem-124 170 40 ion ion NOUN eurjchem-124 170 41     SPACE eurjchem-124 170 42 peak peak NOUN eurjchem-124 170 43     SPACE eurjchem-124 170 44 at at ADP eurjchem-124 170 45     SPACE eurjchem-124 170 46 m m PROPN eurjchem-124 170 47 / / PROPN eurjchem-124 170 48 z z NOUN eurjchem-124 170 49     SPACE eurjchem-124 170 50 338 338 NUM eurjchem-124 170 51     SPACE eurjchem-124 170 52 ( ( PUNCT eurjchem-124 170 53 scheme scheme NOUN eurjchem-124 170 54     SPACE eurjchem-124 170 55 2 2 NUM eurjchem-124 170 56 ) ) PUNCT eurjchem-124 170 57 . . PUNCT eurjchem-124 170 58     SPACE eurjchem-124 171 1 the the DET eurjchem-124 171 2     SPACE eurjchem-124 171 3 major major ADJ eurjchem-124 171 4     SPACE eurjchem-124 171 5 fragment fragment NOUN eurjchem-124 171 6     SPACE eurjchem-124 171 7 at at ADP eurjchem-124 171 8     SPACE eurjchem-124 171 9 m m PROPN eurjchem-124 171 10 / / PROPN eurjchem-124 171 11 z z NOUN eurjchem-124 171 12     SPACE eurjchem-124 171 13 127 127 NUM eurjchem-124 171 14     SPACE eurjchem-124 171 15 ( ( PUNCT eurjchem-124 171 16 7.5 7.5 NUM eurjchem-124 171 17 % % NOUN eurjchem-124 171 18 ) ) PUNCT eurjchem-124 171 19     SPACE eurjchem-124 171 20 was be AUX eurjchem-124 171 21     SPACE eurjchem-124 171 22 derived derive VERB eurjchem-124 171 23     SPACE eurjchem-124 171 24 from from ADP eurjchem-124 171 25     SPACE eurjchem-124 171 26 the the DET eurjchem-124 171 27     SPACE eurjchem-124 171 28 n‐mclafferty n‐mclafferty NOUN eurjchem-124 171 29     SPACE eurjchem-124 171 30 rearrangement rearrangement NOUN eurjchem-124 171 31     SPACE eurjchem-124 171 32 and and CCONJ eurjchem-124 171 33     SPACE eurjchem-124 171 34 the the DET eurjchem-124 171 35     SPACE eurjchem-124 171 36 base base NOUN eurjchem-124 171 37     SPACE eurjchem-124 171 38 peak peak NOUN eurjchem-124 171 39     SPACE eurjchem-124 171 40 at at ADP eurjchem-124 171 41     SPACE eurjchem-124 171 42 m m PROPN eurjchem-124 171 43 / / PROPN eurjchem-124 171 44 z z NOUN eurjchem-124 171 45     SPACE eurjchem-124 171 46 111 111 NUM eurjchem-124 171 47     SPACE eurjchem-124 171 48 ( ( PUNCT eurjchem-124 171 49 100 100 NUM eurjchem-124 171 50 % % NOUN eurjchem-124 171 51 ) ) PUNCT eurjchem-124 171 52     SPACE eurjchem-124 171 53 originated originate VERB eurjchem-124 171 54     SPACE eurjchem-124 171 55 from from ADP eurjchem-124 171 56     SPACE eurjchem-124 171 57 the the DET eurjchem-124 171 58     SPACE eurjchem-124 171 59 thiophenoyl thiophenoyl ADJ eurjchem-124 171 60     SPACE eurjchem-124 171 61 cation cation NOUN eurjchem-124 171 62     SPACE eurjchem-124 171 63 ( ( PUNCT eurjchem-124 171 64 scheme scheme NOUN eurjchem-124 171 65     SPACE eurjchem-124 171 66 2 2 NUM eurjchem-124 171 67 ) ) PUNCT eurjchem-124 171 68 . . PUNCT eurjchem-124 171 69     SPACE eurjchem-124 172 1 similarly similarly ADV eurjchem-124 172 2 , , PUNCT eurjchem-124 172 3     SPACE eurjchem-124 172 4 the the DET eurjchem-124 172 5     SPACE eurjchem-124 172 6 mass mass NOUN eurjchem-124 172 7     SPACE eurjchem-124 172 8 spectrum spectrum NOUN eurjchem-124 172 9     SPACE eurjchem-124 172 10 of of ADP eurjchem-124 172 11     SPACE eurjchem-124 172 12 compounds compound NOUN eurjchem-124 172 13     SPACE eurjchem-124 172 14 1 1 NUM eurjchem-124 172 15     SPACE eurjchem-124 172 16 and and CCONJ eurjchem-124 172 17     SPACE eurjchem-124 172 18 2 2 NUM eurjchem-124 172 19     SPACE eurjchem-124 172 20 showed show VERB eurjchem-124 172 21     SPACE eurjchem-124 172 22 the the DET eurjchem-124 172 23     SPACE eurjchem-124 172 24 molecular molecular ADJ eurjchem-124 172 25     SPACE eurjchem-124 172 26 ion ion NOUN eurjchem-124 172 27     SPACE eurjchem-124 172 28 peak peak NOUN eurjchem-124 172 29     SPACE eurjchem-124 172 30 at at ADP eurjchem-124 172 31     SPACE eurjchem-124 172 32 m m PROPN eurjchem-124 172 33 / / PROPN eurjchem-124 172 34 z z NOUN eurjchem-124 172 35     SPACE eurjchem-124 172 36 366 366 NUM eurjchem-124 172 37     SPACE eurjchem-124 172 38 and and CCONJ eurjchem-124 172 39     SPACE eurjchem-124 172 40 m m PROPN eurjchem-124 172 41 / / PROPN eurjchem-124 172 42 z z NOUN eurjchem-124 172 43     SPACE eurjchem-124 172 44 297 297 NUM eurjchem-124 172 45 , , PUNCT eurjchem-124 172 46     SPACE eurjchem-124 172 47 respectively respectively ADV eurjchem-124 172 48 . . PUNCT eurjchem-124 172 49     SPACE eurjchem-124 172 50 the the DET eurjchem-124 172 51     SPACE eurjchem-124 172 52 base base NOUN eurjchem-124 172 53     SPACE eurjchem-124 172 54 peak peak NOUN eurjchem-124 172 55     SPACE eurjchem-124 172 56 for for ADP eurjchem-124 172 57     SPACE eurjchem-124 172 58 all all PRON eurjchem-124 172 59     SPACE eurjchem-124 172 60 the the DET eurjchem-124 172 61     SPACE eurjchem-124 172 62 compounds compound NOUN eurjchem-124 172 63     SPACE eurjchem-124 172 64 ( ( PUNCT eurjchem-124 172 65 1­12 1­12 NUM eurjchem-124 172 66 ) ) PUNCT eurjchem-124 172 67     SPACE eurjchem-124 172 68 was be AUX eurjchem-124 172 69     SPACE eurjchem-124 172 70 m m PROPN eurjchem-124 172 71 / / PROPN eurjchem-124 172 72 z z NOUN eurjchem-124 172 73     SPACE eurjchem-124 172 74 111 111 NUM eurjchem-124 172 75     SPACE eurjchem-124 172 76 ( ( PUNCT eurjchem-124 172 77 100 100 NUM eurjchem-124 172 78 % % NOUN eurjchem-124 172 79 ) ) PUNCT eurjchem-124 172 80 , , PUNCT eurjchem-124 172 81     SPACE eurjchem-124 172 82 originated originate VERB eurjchem-124 172 83     SPACE eurjchem-124 172 84 from from ADP eurjchem-124 172 85     SPACE eurjchem-124 172 86 the the DET eurjchem-124 172 87     SPACE eurjchem-124 172 88 thiophenoyl thiophenoyl ADJ eurjchem-124 172 89     SPACE eurjchem-124 172 90 cation cation NOUN eurjchem-124 172 91     SPACE eurjchem-124 172 92 and and CCONJ eurjchem-124 172 93     SPACE eurjchem-124 172 94 the the DET eurjchem-124 172 95     SPACE eurjchem-124 172 96 fragmentation fragmentation NOUN eurjchem-124 172 97     SPACE eurjchem-124 172 98 pattern pattern NOUN eurjchem-124 172 99     SPACE eurjchem-124 172 100 was be AUX eurjchem-124 172 101     SPACE eurjchem-124 172 102 also also ADV eurjchem-124 172 103     SPACE eurjchem-124 172 104 same same ADJ eurjchem-124 172 105 . . PUNCT eurjchem-124 172 106         SPACE eurjchem-124 173 1 + + PROPN eurjchem-124 173 2 . . PUNCT eurjchem-124 173 3 c c NOUN eurjchem-124 173 4 o o PROPN eurjchem-124 173 5 n n CCONJ eurjchem-124 173 6 n n PROPN eurjchem-124 173 7 s s PART eurjchem-124 173 8 nh nh NOUN eurjchem-124 174 1 oh oh INTJ eurjchem-124 174 2 s s VERB eurjchem-124 174 3 c c NOUN eurjchem-124 174 4 n n PROPN eurjchem-124 174 5 s s NOUN eurjchem-124 174 6 s s X eurjchem-124 174 7 + + NOUN eurjchem-124 174 8 nh2 nh2 PROPN eurjchem-124 174 9 h h NOUN eurjchem-124 174 10 n n NOUN eurjchem-124 174 11 s s NOUN eurjchem-124 174 12 c c NOUN eurjchem-124 174 13 o o NOUN eurjchem-124 174 14 s s X eurjchem-124 174 15 o o X eurjchem-124 174 16 n n SYM eurjchem-124 174 17 s s PROPN eurjchem-124 175 1 n n PRON eurjchem-124 175 2 h h NOUN eurjchem-124 175 3 s s NOUN eurjchem-124 175 4 m m PROPN eurjchem-124 175 5 / / SYM eurjchem-124 175 6 z z PROPN eurjchem-124 175 7 338 338 NUM eurjchem-124 175 8 ( ( PUNCT eurjchem-124 175 9 23 23 NUM eurjchem-124 175 10 % % NOUN eurjchem-124 175 11 ) ) PUNCT eurjchem-124 175 12 m m PROPN eurjchem-124 175 13 / / SYM eurjchem-124 175 14 z z PROPN eurjchem-124 175 15 111 111 NUM eurjchem-124 175 16 ( ( PUNCT eurjchem-124 175 17 100 100 NUM eurjchem-124 175 18 % % NOUN eurjchem-124 175 19 ) ) PUNCT eurjchem-124 175 20 m m PROPN eurjchem-124 175 21 / / SYM eurjchem-124 175 22 z z NOUN eurjchem-124 175 23 84 84 NUM eurjchem-124 175 24 ( ( PUNCT eurjchem-124 175 25 62 62 NUM eurjchem-124 175 26 % % NOUN eurjchem-124 175 27 ) ) PUNCT eurjchem-124 176 1 m m VERB eurjchem-124 176 2 / / SYM eurjchem-124 176 3 z z PROPN eurjchem-124 176 4 228 228 NUM eurjchem-124 176 5 ( ( PUNCT eurjchem-124 176 6 4 4 NUM eurjchem-124 176 7 . . NOUN eurjchem-124 176 8 3 3 NUM eurjchem-124 176 9 % % NOUN eurjchem-124 176 10 ) ) PUNCT eurjchem-124 176 11 m m PROPN eurjchem-124 176 12 / / SYM eurjchem-124 176 13 z z PROPN eurjchem-124 176 14 127 127 NUM eurjchem-124 176 15 ( ( PUNCT eurjchem-124 176 16 7 7 NUM eurjchem-124 176 17 . . SYM eurjchem-124 176 18 5 5 NUM eurjchem-124 176 19 % % NOUN eurjchem-124 176 20 ) ) PUNCT eurjchem-124 177 1 m m PROPN eurjchem-124 177 2 / / SYM eurjchem-124 177 3 z z PROPN eurjchem-124 177 4 141 141 NUM eurjchem-124 177 5 ( ( PUNCT eurjchem-124 177 6 3 3 NUM eurjchem-124 177 7 % % NOUN eurjchem-124 177 8 ) ) PUNCT eurjchem-124 178 1 m m PROPN eurjchem-124 178 2 / / SYM eurjchem-124 178 3 z z PROPN eurjchem-124 178 4 169 169 NUM eurjchem-124 178 5 ( ( PUNCT eurjchem-124 178 6 52 52 NUM eurjchem-124 178 7 % % NOUN eurjchem-124 178 8 ) ) PUNCT eurjchem-124 178 9 m m VERB eurjchem-124 178 10 / / SYM eurjchem-124 178 11 z z PROPN eurjchem-124 178 12 93 93 NUM eurjchem-124 178 13 ( ( PUNCT eurjchem-124 178 14 29 29 NUM eurjchem-124 178 15 . . SYM eurjchem-124 178 16 1 1 NUM eurjchem-124 178 17 % % NOUN eurjchem-124 178 18 ) ) PUNCT eurjchem-124 178 19 co co VERB eurjchem-124 179 1 + + PROPN eurjchem-124 179 2 . . PUNCT eurjchem-124 180 1 + + ADJ eurjchem-124 180 2 . . PUNCT eurjchem-124 181 1 + + ADJ eurjchem-124 181 2 . . PUNCT eurjchem-124 182 1 + + ADJ eurjchem-124 182 2 . . PUNCT eurjchem-124 183 1 + + ADJ eurjchem-124 183 2 . . PUNCT eurjchem-124 184 1 + + ADJ eurjchem-124 184 2 . . PUNCT eurjchem-124 185 1 + + ADJ eurjchem-124 185 2 . . PUNCT eurjchem-124 185 3 scheme scheme NOUN eurjchem-124 185 4     SPACE eurjchem-124 185 5 2 2 NUM eurjchem-124 185 6         SPACE eurjchem-124 185 7 3.2 3.2 NUM eurjchem-124 185 8 . . PUNCT eurjchem-124 185 9     SPACE eurjchem-124 185 10 single single ADJ eurjchem-124 185 11     SPACE eurjchem-124 185 12 crystal crystal NOUN eurjchem-124 185 13     SPACE eurjchem-124 185 14 x­ray x­ray PROPN eurjchem-124 185 15     SPACE eurjchem-124 185 16 crystallography crystallography NOUN eurjchem-124 185 17         SPACE eurjchem-124 185 18 the the DET eurjchem-124 185 19     SPACE eurjchem-124 185 20 molecular molecular ADJ eurjchem-124 185 21     SPACE eurjchem-124 185 22 structure structure NOUN eurjchem-124 185 23     SPACE eurjchem-124 185 24 of of ADP eurjchem-124 185 25     SPACE eurjchem-124 185 26 n n CCONJ eurjchem-124 185 27 , , PUNCT eurjchem-124 185 28 n‐diphenyl‐n’‐(thiophene‐2‐ n‐diphenyl‐n’‐(thiophene‐2‐ NUM eurjchem-124 185 29 carbonyl)‐thiourea carbonyl)‐thiourea NOUN eurjchem-124 185 30     SPACE eurjchem-124 185 31 ( ( PUNCT eurjchem-124 185 32 6 6 NUM eurjchem-124 185 33 ) ) PUNCT eurjchem-124 185 34     SPACE eurjchem-124 185 35 is be AUX eurjchem-124 185 36     SPACE eurjchem-124 185 37 shown show VERB eurjchem-124 185 38     SPACE eurjchem-124 185 39 in in ADP eurjchem-124 185 40     SPACE eurjchem-124 185 41 figure figure NOUN eurjchem-124 185 42     SPACE eurjchem-124 185 43 1 1 NUM eurjchem-124 185 44 . . PUNCT eurjchem-124 185 45     SPACE eurjchem-124 186 1 the the DET eurjchem-124 186 2     SPACE eurjchem-124 186 3 c1‐s1 c1‐s1 NOUN eurjchem-124 186 4     SPACE eurjchem-124 186 5 and and CCONJ eurjchem-124 186 6     SPACE eurjchem-124 186 7 c2‐ c2‐ NOUN eurjchem-124 186 8 o o NOUN eurjchem-124 186 9     SPACE eurjchem-124 186 10 bonds bond NOUN eurjchem-124 186 11     SPACE eurjchem-124 186 12 show show VERB eurjchem-124 186 13     SPACE eurjchem-124 186 14 a a DET eurjchem-124 186 15     SPACE eurjchem-124 186 16 typical typical ADJ eurjchem-124 186 17     SPACE eurjchem-124 186 18 double double ADJ eurjchem-124 186 19     SPACE eurjchem-124 186 20 bond bond NOUN eurjchem-124 186 21     SPACE eurjchem-124 186 22 character character NOUN eurjchem-124 186 23     SPACE eurjchem-124 186 24 with with ADP eurjchem-124 186 25     SPACE eurjchem-124 186 26 bond bond NOUN eurjchem-124 186 27     SPACE eurjchem-124 186 28 lengths length NOUN eurjchem-124 186 29     SPACE eurjchem-124 186 30 of of ADP eurjchem-124 186 31     SPACE eurjchem-124 186 32 1.666(2 1.666(2 NUM eurjchem-124 186 33 ) ) PUNCT eurjchem-124 186 34     SPACE eurjchem-124 187 1 å å NOUN eurjchem-124 187 2     SPACE eurjchem-124 187 3 and and CCONJ eurjchem-124 187 4     SPACE eurjchem-124 187 5 1.215(3 1.215(3 NUM eurjchem-124 187 6 ) ) PUNCT eurjchem-124 187 7     SPACE eurjchem-124 187 8 å å PROPN eurjchem-124 187 9 , , PUNCT eurjchem-124 187 10     SPACE eurjchem-124 187 11 respectively respectively ADV eurjchem-124 187 12 . . PUNCT eurjchem-124 187 13     SPACE eurjchem-124 188 1 all all PRON eurjchem-124 188 2     SPACE eurjchem-124 188 3 of of ADP eurjchem-124 188 4     SPACE eurjchem-124 188 5 the the DET eurjchem-124 188 6     SPACE eurjchem-124 188 7 c‐ c‐ NOUN eurjchem-124 188 8 n n CCONJ eurjchem-124 188 9     SPACE eurjchem-124 188 10 bonds bond NOUN eurjchem-124 188 11 , , PUNCT eurjchem-124 188 12     SPACE eurjchem-124 188 13 c1‐n1 c1‐n1 ADV eurjchem-124 188 14     SPACE eurjchem-124 188 15 1.353(3 1.353(3 NUM eurjchem-124 188 16 ) ) PUNCT eurjchem-124 188 17     SPACE eurjchem-124 188 18 å å PROPN eurjchem-124 188 19 , , PUNCT eurjchem-124 188 20     SPACE eurjchem-124 188 21 c21‐n1 c21‐n1 NOUN eurjchem-124 188 22     SPACE eurjchem-124 188 23 1.442(2 1.442(2 NUM eurjchem-124 188 24 ) ) PUNCT eurjchem-124 188 25     SPACE eurjchem-124 188 26 å å PROPN eurjchem-124 188 27 , , PUNCT eurjchem-124 188 28     SPACE eurjchem-124 188 29 c11‐n1 c11‐n1 VERB eurjchem-124 188 30     SPACE eurjchem-124 188 31 1.442(2 1.442(2 NUM eurjchem-124 188 32 ) ) PUNCT eurjchem-124 188 33     SPACE eurjchem-124 188 34 å å PROPN eurjchem-124 188 35 , , PUNCT eurjchem-124 188 36     SPACE eurjchem-124 188 37 c2‐n2 c2‐n2 NOUN eurjchem-124 188 38     SPACE eurjchem-124 188 39 1.397(3 1.397(3 NUM eurjchem-124 188 40 ) ) PUNCT eurjchem-124 188 41     SPACE eurjchem-124 189 1 å å NOUN eurjchem-124 189 2     SPACE eurjchem-124 189 3 and and CCONJ eurjchem-124 189 4     SPACE eurjchem-124 189 5 c1‐n2 c1‐n2 NOUN eurjchem-124 189 6     SPACE eurjchem-124 189 7 1.400(2 1.400(2 NUM eurjchem-124 189 8 ) ) PUNCT eurjchem-124 189 9     SPACE eurjchem-124 189 10 å å NOUN eurjchem-124 189 11     SPACE eurjchem-124 189 12 also also ADV eurjchem-124 189 13     SPACE eurjchem-124 189 14 indicate indicate VERB eurjchem-124 189 15     SPACE eurjchem-124 189 16 a a DET eurjchem-124 189 17     SPACE eurjchem-124 189 18 partial partial ADJ eurjchem-124 189 19     SPACE eurjchem-124 189 20 double double ADJ eurjchem-124 189 21     SPACE eurjchem-124 189 22 bond bond NOUN eurjchem-124 189 23     SPACE eurjchem-124 189 24 character character NOUN eurjchem-124 189 25     SPACE eurjchem-124 189 26 ( ( PUNCT eurjchem-124 189 27 table table NOUN eurjchem-124 189 28     SPACE eurjchem-124 189 29 1 1 NUM eurjchem-124 189 30 ) ) PUNCT eurjchem-124 189 31 . . PUNCT eurjchem-124 189 32     SPACE eurjchem-124 190 1 the the DET eurjchem-124 190 2     SPACE eurjchem-124 190 3 c1‐n2 c1‐n2 NOUN eurjchem-124 190 4     SPACE eurjchem-124 190 5 bond bond NOUN eurjchem-124 190 6 , , PUNCT eurjchem-124 190 7     SPACE eurjchem-124 190 8 adjacent adjacent ADJ eurjchem-124 190 9     SPACE eurjchem-124 190 10 to to ADP eurjchem-124 190 11     SPACE eurjchem-124 190 12 the the DET eurjchem-124 190 13     SPACE eurjchem-124 190 14 carbonyl carbonyl NOUN eurjchem-124 190 15     SPACE eurjchem-124 190 16 group group NOUN eurjchem-124 190 17 , , PUNCT eurjchem-124 190 18     SPACE eurjchem-124 190 19 is be AUX eurjchem-124 190 20     SPACE eurjchem-124 190 21 slightly slightly ADV eurjchem-124 190 22     SPACE eurjchem-124 190 23 shorter short ADJ eurjchem-124 190 24     SPACE eurjchem-124 190 25 than than ADP eurjchem-124 190 26     SPACE eurjchem-124 190 27 c1‐n1 c1‐n1 NOUN eurjchem-124 190 28 . . PUNCT eurjchem-124 190 29     SPACE eurjchem-124 190 30 these these DET eurjchem-124 190 31     SPACE eurjchem-124 190 32 bond bond NOUN eurjchem-124 190 33     SPACE eurjchem-124 190 34 distances distance NOUN eurjchem-124 190 35     SPACE eurjchem-124 190 36 are be AUX eurjchem-124 190 37     SPACE eurjchem-124 190 38 in in ADP eurjchem-124 190 39     SPACE eurjchem-124 190 40 good good ADJ eurjchem-124 190 41     SPACE eurjchem-124 190 42 agreement agreement NOUN eurjchem-124 190 43     SPACE eurjchem-124 190 44 with with ADP eurjchem-124 190 45     SPACE eurjchem-124 190 46 those those PRON eurjchem-124 190 47     SPACE eurjchem-124 190 48 observed observe VERB eurjchem-124 190 49     SPACE eurjchem-124 190 50 in in ADP eurjchem-124 190 51     SPACE eurjchem-124 190 52 structures structure NOUN eurjchem-124 190 53     SPACE eurjchem-124 190 54 containing contain VERB eurjchem-124 190 55     SPACE eurjchem-124 190 56 the the DET eurjchem-124 190 57     SPACE eurjchem-124 190 58 n‐benzoyl‐n’‐ n‐benzoyl‐n’‐ NOUN eurjchem-124 190 59 phenylthiourea phenylthiourea NOUN eurjchem-124 190 60     SPACE eurjchem-124 190 61 moiety moiety NOUN eurjchem-124 190 62 , , PUNCT eurjchem-124 190 63     SPACE eurjchem-124 190 64 as as SCONJ eurjchem-124 190 65     SPACE eurjchem-124 190 66 reported report VERB eurjchem-124 190 67     SPACE eurjchem-124 190 68 in in ADP eurjchem-124 190 69     SPACE eurjchem-124 190 70 the the DET eurjchem-124 190 71     SPACE eurjchem-124 190 72 cambridge cambridge PROPN eurjchem-124 190 73     SPACE eurjchem-124 190 74 structural structural ADJ eurjchem-124 190 75     SPACE eurjchem-124 190 76 database database NOUN eurjchem-124 190 77     SPACE eurjchem-124 191 1 [ [ X eurjchem-124 191 2 37 37 NUM eurjchem-124 191 3 ] ] PUNCT eurjchem-124 191 4 . . PUNCT eurjchem-124 191 5     SPACE eurjchem-124 191 6 defining define VERB eurjchem-124 191 7     SPACE eurjchem-124 191 8 a a DET eurjchem-124 191 9     SPACE eurjchem-124 191 10 molecular molecular ADJ eurjchem-124 191 11     SPACE eurjchem-124 191 12 backbone backbone NOUN eurjchem-124 191 13     SPACE eurjchem-124 191 14 as as SCONJ eurjchem-124 191 15     SPACE eurjchem-124 191 16 s2‐c3‐c2‐n2‐ s2‐c3‐c2‐n2‐ VERB eurjchem-124 191 17 c1‐n1‐c11 c1‐n1‐c11 PROPN eurjchem-124 191 18 , , PUNCT eurjchem-124 191 19     SPACE eurjchem-124 191 20 the the DET eurjchem-124 191 21     SPACE eurjchem-124 191 22 geometry geometry NOUN eurjchem-124 191 23     SPACE eurjchem-124 191 24 is be AUX eurjchem-124 191 25     SPACE eurjchem-124 191 26 antiperiplanar antiperiplanar PROPN eurjchem-124 191 27     SPACE eurjchem-124 191 28 about about ADV eurjchem-124 191 29     SPACE eurjchem-124 191 30 all all DET eurjchem-124 191 31     SPACE eurjchem-124 191 32 bonds bond NOUN eurjchem-124 191 33     SPACE eurjchem-124 191 34 except except SCONJ eurjchem-124 191 35     SPACE eurjchem-124 191 36 c1‐n2 c1‐n2 NOUN eurjchem-124 191 37     SPACE eurjchem-124 191 38 ( ( PUNCT eurjchem-124 191 39 torsion torsion NOUN eurjchem-124 191 40     SPACE eurjchem-124 191 41 angles angle NOUN eurjchem-124 191 42     SPACE eurjchem-124 191 43 in in ADP eurjchem-124 191 44     SPACE eurjchem-124 191 45 the the DET eurjchem-124 191 46     SPACE eurjchem-124 191 47 same same ADJ eurjchem-124 191 48     SPACE eurjchem-124 191 49 order order NOUN eurjchem-124 191 50 : : PUNCT eurjchem-124 191 51     SPACE eurjchem-124 191 52 ‐174 ‐174 ADV eurjchem-124 191 53     SPACE eurjchem-124 191 54 ° ° NOUN eurjchem-124 191 55 , , PUNCT eurjchem-124 191 56     SPACE eurjchem-124 191 57 ‐177 ‐177 PROPN eurjchem-124 191 58     SPACE eurjchem-124 191 59 ° ° PROPN eurjchem-124 191 60 , , PUNCT eurjchem-124 191 61     SPACE eurjchem-124 191 62 45 45 NUM eurjchem-124 191 63     SPACE eurjchem-124 191 64 ° ° NOUN eurjchem-124 191 65     SPACE eurjchem-124 191 66 and and CCONJ eurjchem-124 191 67     SPACE eurjchem-124 191 68 ‐162 ‐162 NOUN eurjchem-124 191 69     SPACE eurjchem-124 191 70 ° ° NOUN eurjchem-124 191 71 ) ) PUNCT eurjchem-124 191 72 . . PUNCT eurjchem-124 191 73     SPACE eurjchem-124 192 1 the the DET eurjchem-124 192 2     SPACE eurjchem-124 192 3 phenyl phenyl NOUN eurjchem-124 192 4     SPACE eurjchem-124 192 5 rings ring NOUN eurjchem-124 192 6     SPACE eurjchem-124 192 7 subtend subtend VERB eurjchem-124 192 8     SPACE eurjchem-124 192 9 an an DET eurjchem-124 192 10     SPACE eurjchem-124 192 11 interplanar interplanar NOUN eurjchem-124 192 12     SPACE eurjchem-124 192 13 angle angle NOUN eurjchem-124 192 14     SPACE eurjchem-124 192 15 of of ADP eurjchem-124 192 16     SPACE eurjchem-124 192 17 81.6 81.6 NUM eurjchem-124 192 18     SPACE eurjchem-124 192 19 ° ° NOUN eurjchem-124 192 20 . . PUNCT eurjchem-124 192 21     SPACE eurjchem-124 192 22 the the DET eurjchem-124 192 23     SPACE eurjchem-124 192 24 molecular molecular ADJ eurjchem-124 192 25     SPACE eurjchem-124 192 26 packing packing NOUN eurjchem-124 192 27     SPACE eurjchem-124 192 28 ( ( PUNCT eurjchem-124 192 29 figure figure NOUN eurjchem-124 192 30     SPACE eurjchem-124 192 31 2 2 NUM eurjchem-124 192 32 ) ) PUNCT eurjchem-124 192 33     SPACE eurjchem-124 192 34 involves involve VERB eurjchem-124 192 35     SPACE eurjchem-124 192 36 layers layer NOUN eurjchem-124 192 37     SPACE eurjchem-124 192 38 parallel parallel NOUN eurjchem-124 192 39     SPACE eurjchem-124 192 40 to to ADP eurjchem-124 192 41     SPACE eurjchem-124 192 42 the the DET eurjchem-124 192 43     SPACE eurjchem-124 192 44 plane plane NOUN eurjchem-124 192 45     SPACE eurjchem-124 192 46 ( ( PUNCT eurjchem-124 192 47 101 101 NUM eurjchem-124 192 48 ) ) PUNCT eurjchem-124 192 49 . . PUNCT eurjchem-124 192 50     SPACE eurjchem-124 193 1 the the DET eurjchem-124 193 2     SPACE eurjchem-124 193 3 classical classical ADJ eurjchem-124 193 4     SPACE eurjchem-124 193 5 h h NOUN eurjchem-124 193 6     SPACE eurjchem-124 193 7 bond bond NOUN eurjchem-124 193 8     SPACE eurjchem-124 193 9 n2‐h02···s n2‐h02···s NOUN eurjchem-124 193 10 , , PUNCT eurjchem-124 193 11     SPACE eurjchem-124 193 12 with with ADP eurjchem-124 193 13     SPACE eurjchem-124 193 14 h···s h···s VERB eurjchem-124 193 15     SPACE eurjchem-124 193 16 2.71(3 2.71(3 NUM eurjchem-124 193 17 ) ) PUNCT eurjchem-124 193 18     SPACE eurjchem-124 193 19 å å PROPN eurjchem-124 193 20 , , PUNCT eurjchem-124 193 21     SPACE eurjchem-124 193 22 angle angle NOUN eurjchem-124 193 23     SPACE eurjchem-124 193 24 154(2 154(2 NUM eurjchem-124 193 25 ) ) PUNCT eurjchem-124 193 26     SPACE eurjchem-124 193 27 ° ° PROPN eurjchem-124 193 28 , , PUNCT eurjchem-124 193 29     SPACE eurjchem-124 193 30 is be AUX eurjchem-124 193 31     SPACE eurjchem-124 193 32 surprisingly surprisingly ADV eurjchem-124 193 33     SPACE eurjchem-124 193 34 long long ADV eurjchem-124 193 35 . . PUNCT eurjchem-124 193 36     SPACE eurjchem-124 193 37 also also ADV eurjchem-124 193 38     SPACE eurjchem-124 193 39 observed observe VERB eurjchem-124 193 40     SPACE eurjchem-124 193 41 are be AUX eurjchem-124 193 42     SPACE eurjchem-124 193 43 the the DET eurjchem-124 193 44     SPACE eurjchem-124 193 45 weak weak ADJ eurjchem-124 193 46     SPACE eurjchem-124 193 47 h h NOUN eurjchem-124 193 48     SPACE eurjchem-124 193 49 bonds bond NOUN eurjchem-124 193 50     SPACE eurjchem-124 193 51 h4···s1 h4···s1 NOUN eurjchem-124 193 52     SPACE eurjchem-124 193 53 ( ( PUNCT eurjchem-124 193 54 2.90 2.90 NUM eurjchem-124 193 55     SPACE eurjchem-124 193 56 å å NOUN eurjchem-124 193 57 ) ) PUNCT eurjchem-124 193 58 , , PUNCT eurjchem-124 193 59     SPACE eurjchem-124 193 60 h24···s2 h24···s2 NOUN eurjchem-124 193 61     SPACE eurjchem-124 193 62 ( ( PUNCT eurjchem-124 193 63 3.03 3.03 NUM eurjchem-124 193 64     SPACE eurjchem-124 193 65 å å NOUN eurjchem-124 193 66 ) ) PUNCT eurjchem-124 193 67     SPACE eurjchem-124 193 68 and and CCONJ eurjchem-124 193 69     SPACE eurjchem-124 193 70 h24···o h24···o NOUN eurjchem-124 193 71     SPACE eurjchem-124 193 72 ( ( PUNCT eurjchem-124 193 73 2.52 2.52 NUM eurjchem-124 193 74     SPACE eurjchem-124 193 75 å å NOUN eurjchem-124 193 76 ) ) PUNCT eurjchem-124 193 77 , , PUNCT eurjchem-124 193 78     SPACE eurjchem-124 193 79 the the DET eurjchem-124 193 80     SPACE eurjchem-124 193 81 latter latter ADJ eurjchem-124 193 82     SPACE eurjchem-124 193 83 two two NUM eurjchem-124 193 84     SPACE eurjchem-124 193 85 forming form VERB eurjchem-124 193 86     SPACE eurjchem-124 193 87 a a DET eurjchem-124 193 88     SPACE eurjchem-124 193 89 three‐centre three‐centre NOUN eurjchem-124 193 90     SPACE eurjchem-124 193 91 system system NOUN eurjchem-124 193 92     SPACE eurjchem-124 193 93 but but CCONJ eurjchem-124 193 94     SPACE eurjchem-124 193 95 with with ADP eurjchem-124 193 96     SPACE eurjchem-124 193 97 a a DET eurjchem-124 193 98     SPACE eurjchem-124 193 99 narrow narrow ADJ eurjchem-124 193 100     SPACE eurjchem-124 193 101 c24‐h24···s2 c24‐h24···s2 ADJ eurjchem-124 193 102     SPACE eurjchem-124 193 103 angle angle NOUN eurjchem-124 193 104     SPACE eurjchem-124 193 105 of of ADP eurjchem-124 193 106     SPACE eurjchem-124 193 107 114 114 NUM eurjchem-124 193 108     SPACE eurjchem-124 193 109 ° ° NOUN eurjchem-124 193 110 , , PUNCT eurjchem-124 193 111     SPACE eurjchem-124 193 112 and and CCONJ eurjchem-124 193 113     SPACE eurjchem-124 193 114 the the DET eurjchem-124 193 115     SPACE eurjchem-124 193 116 contact contact NOUN eurjchem-124 193 117     SPACE eurjchem-124 193 118 s1···o s1···o ADJ eurjchem-124 193 119     SPACE eurjchem-124 193 120 3.22 3.22 NUM eurjchem-124 193 121     SPACE eurjchem-124 193 122 å å NOUN eurjchem-124 193 123     SPACE eurjchem-124 193 124 ( ( PUNCT eurjchem-124 193 125 table table NOUN eurjchem-124 193 126     SPACE eurjchem-124 193 127 2 2 NUM eurjchem-124 193 128 ) ) PUNCT eurjchem-124 193 129 . . PUNCT eurjchem-124 193 130     SPACE eurjchem-124 194 1 the the DET eurjchem-124 194 2     SPACE eurjchem-124 194 3 intramolecular intramolecular ADJ eurjchem-124 194 4     SPACE eurjchem-124 194 5 hydrogen hydrogen NOUN eurjchem-124 194 6     SPACE eurjchem-124 194 7 bonding bonding NOUN eurjchem-124 194 8     SPACE eurjchem-124 194 9 will will AUX eurjchem-124 194 10     SPACE eurjchem-124 194 11 influence influence VERB eurjchem-124 194 12     SPACE eurjchem-124 194 13 the the DET eurjchem-124 194 14     SPACE eurjchem-124 194 15 coordination coordination NOUN eurjchem-124 194 16     SPACE eurjchem-124 194 17 behaviour behaviour NOUN eurjchem-124 194 18     SPACE eurjchem-124 194 19 of of ADP eurjchem-124 194 20     SPACE eurjchem-124 194 21 the the DET eurjchem-124 194 22     SPACE eurjchem-124 194 23 compounds compound NOUN eurjchem-124 194 24 . . PUNCT eurjchem-124 194 25     SPACE eurjchem-124 194 26 thiourea thiourea NOUN eurjchem-124 194 27     SPACE eurjchem-124 194 28 derivatives derivative NOUN eurjchem-124 194 29     SPACE eurjchem-124 194 30 such such ADJ eurjchem-124 194 31     SPACE eurjchem-124 194 32 as as ADP eurjchem-124 194 33     SPACE eurjchem-124 194 34 n n CCONJ eurjchem-124 194 35 , , PUNCT eurjchem-124 194 36 n’‐dialkyl‐n’‐ n’‐dialkyl‐n’‐ PROPN eurjchem-124 194 37 benzoylthiourea benzoylthiourea NOUN eurjchem-124 194 38     SPACE eurjchem-124 194 39 easily easily ADV eurjchem-124 194 40     SPACE eurjchem-124 194 41 coordinate coordinate NOUN eurjchem-124 194 42     SPACE eurjchem-124 194 43 to to ADP eurjchem-124 194 44     SPACE eurjchem-124 194 45 a a DET eurjchem-124 194 46     SPACE eurjchem-124 194 47 metal metal NOUN eurjchem-124 194 48     SPACE eurjchem-124 194 49 atom atom NOUN eurjchem-124 194 50     SPACE eurjchem-124 194 51 to to PART eurjchem-124 194 52     SPACE eurjchem-124 194 53 participate participate VERB eurjchem-124 194 54     SPACE eurjchem-124 194 55 in in ADP eurjchem-124 194 56     SPACE eurjchem-124 194 57 the the DET eurjchem-124 194 58     SPACE eurjchem-124 194 59 coordination coordination NOUN eurjchem-124 194 60     SPACE eurjchem-124 194 61 with with ADP eurjchem-124 194 62     SPACE eurjchem-124 194 63 transition transition NOUN eurjchem-124 194 64     SPACE eurjchem-124 194 65 metal metal NOUN eurjchem-124 194 66     SPACE eurjchem-124 194 67 atoms atom NOUN eurjchem-124 194 68     SPACE eurjchem-124 194 69 because because SCONJ eurjchem-124 194 70     SPACE eurjchem-124 194 71 it it PRON eurjchem-124 194 72     SPACE eurjchem-124 194 73 is be AUX eurjchem-124 194 74     SPACE eurjchem-124 194 75 involved involve VERB eurjchem-124 194 76     SPACE eurjchem-124 194 77 in in ADP eurjchem-124 194 78     SPACE eurjchem-124 194 79 intramolecular intramolecular ADJ eurjchem-124 194 80     SPACE eurjchem-124 194 81 hydrogen hydrogen NOUN eurjchem-124 194 82     SPACE eurjchem-124 194 83 bonding bonding NOUN eurjchem-124 194 84 . . PUNCT eurjchem-124 194 85         SPACE eurjchem-124 194 86 figure figure NOUN eurjchem-124 194 87     SPACE eurjchem-124 194 88 1 1 NUM eurjchem-124 194 89 . . PUNCT eurjchem-124 194 90     SPACE eurjchem-124 194 91 the the DET eurjchem-124 194 92     SPACE eurjchem-124 194 93 molecule molecule NOUN eurjchem-124 194 94     SPACE eurjchem-124 194 95 of of ADP eurjchem-124 194 96     SPACE eurjchem-124 194 97 the the DET eurjchem-124 194 98     SPACE eurjchem-124 194 99 compound compound NOUN eurjchem-124 194 100     SPACE eurjchem-124 194 101 6 6 NUM eurjchem-124 194 102     SPACE eurjchem-124 194 103 in in ADP eurjchem-124 194 104     SPACE eurjchem-124 194 105 the the DET eurjchem-124 194 106     SPACE eurjchem-124 194 107 crystal crystal NOUN eurjchem-124 194 108 ; ; PUNCT eurjchem-124 194 109     SPACE eurjchem-124 194 110 ellipsoids ellipsoid NOUN eurjchem-124 194 111     SPACE eurjchem-124 194 112 represent represent VERB eurjchem-124 194 113     SPACE eurjchem-124 194 114 50 50 NUM eurjchem-124 194 115 % % NOUN eurjchem-124 194 116     SPACE eurjchem-124 194 117 probability probability NOUN eurjchem-124 194 118     SPACE eurjchem-124 194 119 levels level NOUN eurjchem-124 194 120 . . PUNCT eurjchem-124 194 121             SPACE eurjchem-124 194 122 figure figure NOUN eurjchem-124 194 123     SPACE eurjchem-124 194 124 2 2 NUM eurjchem-124 194 125 . . PUNCT eurjchem-124 194 126     SPACE eurjchem-124 194 127 packing pack VERB eurjchem-124 194 128     SPACE eurjchem-124 194 129 diagram diagram NOUN eurjchem-124 194 130     SPACE eurjchem-124 194 131 of of ADP eurjchem-124 194 132     SPACE eurjchem-124 194 133 the the DET eurjchem-124 194 134     SPACE eurjchem-124 194 135 compound compound NOUN eurjchem-124 194 136     SPACE eurjchem-124 194 137 6 6 NUM eurjchem-124 194 138     SPACE eurjchem-124 194 139 viewed view VERB eurjchem-124 194 140     SPACE eurjchem-124 194 141 perpendicular perpendicular NOUN eurjchem-124 194 142     SPACE eurjchem-124 194 143 to to ADP eurjchem-124 194 144     SPACE eurjchem-124 194 145 the the DET eurjchem-124 194 146     SPACE eurjchem-124 194 147 plane plane NOUN eurjchem-124 194 148     SPACE eurjchem-124 194 149 ( ( PUNCT eurjchem-124 194 150 101 101 NUM eurjchem-124 194 151 ) ) PUNCT eurjchem-124 194 152 . . PUNCT eurjchem-124 194 153     SPACE eurjchem-124 195 1 the the DET eurjchem-124 195 2     SPACE eurjchem-124 195 3 ring ring NOUN eurjchem-124 195 4     SPACE eurjchem-124 195 5 c11‐16 c11‐16 NOUN eurjchem-124 195 6     SPACE eurjchem-124 195 7 is be AUX eurjchem-124 195 8     SPACE eurjchem-124 195 9 represented represent VERB eurjchem-124 195 10     SPACE eurjchem-124 195 11 only only ADV eurjchem-124 195 12     SPACE eurjchem-124 195 13 be be AUX eurjchem-124 195 14     SPACE eurjchem-124 195 15 the the DET eurjchem-124 195 16     SPACE eurjchem-124 195 17 ipso ipso NOUN eurjchem-124 195 18     SPACE eurjchem-124 195 19 c c NOUN eurjchem-124 195 20     SPACE eurjchem-124 195 21 atom atom NOUN eurjchem-124 195 22 . . PUNCT eurjchem-124 195 23     SPACE eurjchem-124 196 1 thick thick ADJ eurjchem-124 196 2     SPACE eurjchem-124 196 3 dashed dash VERB eurjchem-124 196 4     SPACE eurjchem-124 196 5 lines line NOUN eurjchem-124 196 6     SPACE eurjchem-124 196 7 represent represent VERB eurjchem-124 196 8     SPACE eurjchem-124 196 9 h···s h···s NOUN eurjchem-124 196 10     SPACE eurjchem-124 196 11 hydrogen hydrogen NOUN eurjchem-124 196 12     SPACE eurjchem-124 196 13 bonds bond NOUN eurjchem-124 196 14 , , PUNCT eurjchem-124 196 15     SPACE eurjchem-124 196 16 thin thin ADJ eurjchem-124 196 17     SPACE eurjchem-124 196 18 dashed dash VERB eurjchem-124 196 19     SPACE eurjchem-124 196 20 lines line NOUN eurjchem-124 196 21     SPACE eurjchem-124 196 22 represent represent VERB eurjchem-124 196 23     SPACE eurjchem-124 196 24 " " PUNCT eurjchem-124 196 25 weak weak ADJ eurjchem-124 196 26 " " PUNCT eurjchem-124 196 27     SPACE eurjchem-124 196 28 hydrogen hydrogen NOUN eurjchem-124 196 29     SPACE eurjchem-124 196 30 bonds bond NOUN eurjchem-124 196 31     SPACE eurjchem-124 196 32 or or CCONJ eurjchem-124 196 33     SPACE eurjchem-124 196 34 s···o s···o NOUN eurjchem-124 196 35     SPACE eurjchem-124 196 36 contacts contact NOUN eurjchem-124 196 37     SPACE eurjchem-124 196 38 ( ( PUNCT eurjchem-124 196 39 see see VERB eurjchem-124 196 40     SPACE eurjchem-124 196 41 text text NOUN eurjchem-124 196 42 ) ) PUNCT eurjchem-124 196 43 . . PUNCT eurjchem-124 196 44         SPACE eurjchem-124 196 45 3.3 3.3 NUM eurjchem-124 196 46 . . PUNCT eurjchem-124 196 47     SPACE eurjchem-124 196 48 biological biological ADJ eurjchem-124 196 49     SPACE eurjchem-124 196 50 activity activity NOUN eurjchem-124 196 51     SPACE eurjchem-124 196 52 studies study NOUN eurjchem-124 196 53         SPACE eurjchem-124 196 54 primary primary ADJ eurjchem-124 196 55     SPACE eurjchem-124 196 56 bioassay bioassay NOUN eurjchem-124 196 57     SPACE eurjchem-124 196 58 screening screening NOUN eurjchem-124 196 59     SPACE eurjchem-124 196 60 provides provide VERB eurjchem-124 196 61     SPACE eurjchem-124 196 62 the the DET eurjchem-124 196 63     SPACE eurjchem-124 196 64 first first ADJ eurjchem-124 196 65     SPACE eurjchem-124 196 66 indication indication NOUN eurjchem-124 196 67     SPACE eurjchem-124 196 68 of of ADP eurjchem-124 196 69     SPACE eurjchem-124 196 70 bioactivities bioactivitie NOUN eurjchem-124 196 71     SPACE eurjchem-124 196 72 and and CCONJ eurjchem-124 196 73     SPACE eurjchem-124 196 74 helps help VERB eurjchem-124 196 75     SPACE eurjchem-124 196 76 in in ADP eurjchem-124 196 77     SPACE eurjchem-124 196 78 the the DET eurjchem-124 196 79     SPACE eurjchem-124 196 80 selection selection NOUN eurjchem-124 196 81     SPACE eurjchem-124 196 82 of of ADP eurjchem-124 196 83     SPACE eurjchem-124 196 84 lead lead NOUN eurjchem-124 196 85     SPACE eurjchem-124 196 86 compounds compound NOUN eurjchem-124 196 87     SPACE eurjchem-124 196 88 for for ADP eurjchem-124 196 89     SPACE eurjchem-124 196 90 secondary secondary ADJ eurjchem-124 196 91     SPACE eurjchem-124 196 92 screening screening NOUN eurjchem-124 196 93     SPACE eurjchem-124 196 94 for for ADP eurjchem-124 196 95     SPACE eurjchem-124 196 96 detailed detailed ADJ eurjchem-124 196 97     SPACE eurjchem-124 196 98 pharmacological pharmacological NOUN eurjchem-124 196 99     SPACE eurjchem-124 196 100 evaluation evaluation NOUN eurjchem-124 196 101 . . PUNCT eurjchem-124 196 102     SPACE eurjchem-124 197 1 the the DET eurjchem-124 197 2     SPACE eurjchem-124 197 3 synthesized synthesize VERB eurjchem-124 197 4     SPACE eurjchem-124 197 5 thiourea thiourea NOUN eurjchem-124 197 6     SPACE eurjchem-124 197 7 derivatives derivative NOUN eurjchem-124 197 8     SPACE eurjchem-124 197 9 ( ( PUNCT eurjchem-124 197 10 1­12 1­12 NOUN eurjchem-124 197 11 ) ) PUNCT eurjchem-124 197 12     SPACE eurjchem-124 197 13 were be AUX eurjchem-124 197 14     SPACE eurjchem-124 197 15 checked check VERB eurjchem-124 197 16     SPACE eurjchem-124 197 17 for for ADP eurjchem-124 197 18     SPACE eurjchem-124 197 19 their their PRON eurjchem-124 197 20     SPACE eurjchem-124 197 21 antifungal antifungal ADJ eurjchem-124 197 22     SPACE eurjchem-124 197 23 activity activity NOUN eurjchem-124 197 24     SPACE eurjchem-124 197 25 against against ADP eurjchem-124 197 26     SPACE eurjchem-124 197 27 3 3 NUM eurjchem-124 197 28     SPACE eurjchem-124 197 29 fungal fungal ADJ eurjchem-124 197 30     SPACE eurjchem-124 197 31 strains strain NOUN eurjchem-124 197 32 : : PUNCT eurjchem-124 197 33     SPACE eurjchem-124 197 34 c. c. PROPN eurjchem-124 197 35     SPACE eurjchem-124 197 36 glabrata glabrata PROPN eurjchem-124 197 37 , , PUNCT eurjchem-124 197 38     SPACE eurjchem-124 197 39 c. c. NOUN eurjchem-124 197 40     SPACE eurjchem-124 197 41 albicans albican NOUN eurjchem-124 197 42     SPACE eurjchem-124 197 43 and and CCONJ eurjchem-124 197 44     SPACE eurjchem-124 197 45 c. c. NOUN eurjchem-124 197 46     SPACE eurjchem-124 197 47 tropicalis tropicalis PROPN eurjchem-124 197 48 . . PUNCT eurjchem-124 197 49     SPACE eurjchem-124 198 1 the the DET eurjchem-124 198 2     SPACE eurjchem-124 198 3 antifungal antifungal ADJ eurjchem-124 198 4     SPACE eurjchem-124 198 5 activity activity NOUN eurjchem-124 198 6     SPACE eurjchem-124 198 7 was be AUX eurjchem-124 198 8     SPACE eurjchem-124 198 9 carried carry VERB eurjchem-124 198 10     SPACE eurjchem-124 198 11 out out ADP eurjchem-124 198 12     SPACE eurjchem-124 198 13 in in ADP eurjchem-124 198 14     SPACE eurjchem-124 198 15 dmso dmso NOUN eurjchem-124 198 16     SPACE eurjchem-124 198 17 using use VERB eurjchem-124 198 18     SPACE eurjchem-124 198 19 the the DET eurjchem-124 198 20     SPACE eurjchem-124 198 21 broth broth NOUN eurjchem-124 198 22     SPACE eurjchem-124 198 23 micro‐dilution micro‐dilution NOUN eurjchem-124 198 24     SPACE eurjchem-124 198 25 procedure procedure NOUN eurjchem-124 198 26     SPACE eurjchem-124 199 1 [ [ X eurjchem-124 199 2 31 31 NUM eurjchem-124 199 3 ] ] PUNCT eurjchem-124 199 4 . . PUNCT eurjchem-124 199 5     SPACE eurjchem-124 200 1 all all DET eurjchem-124 200 2     SPACE eurjchem-124 200 3 the the DET eurjchem-124 200 4     SPACE eurjchem-124 200 5 compounds compound NOUN eurjchem-124 200 6     SPACE eurjchem-124 200 7 inhibited inhibit VERB eurjchem-124 200 8     SPACE eurjchem-124 200 9 the the DET eurjchem-124 200 10     SPACE eurjchem-124 200 11 growth growth NOUN eurjchem-124 200 12     SPACE eurjchem-124 200 13 of of ADP eurjchem-124 200 14     SPACE eurjchem-124 200 15 fungi fungus NOUN eurjchem-124 200 16     SPACE eurjchem-124 200 17 with with ADP eurjchem-124 200 18     SPACE eurjchem-124 200 19 mic mic ADJ eurjchem-124 200 20     SPACE eurjchem-124 200 21 values value NOUN eurjchem-124 200 22     SPACE eurjchem-124 200 23 ranging range VERB eurjchem-124 200 24     SPACE eurjchem-124 200 25 between between ADP eurjchem-124 200 26     SPACE eurjchem-124 200 27 20 20 NUM eurjchem-124 200 28     SPACE eurjchem-124 200 29 and and CCONJ eurjchem-124 200 30     SPACE eurjchem-124 200 31 > > X eurjchem-124 200 32 100μg 100μg PROPN eurjchem-124 200 33 / / SYM eurjchem-124 200 34 ml ml PROPN eurjchem-124 200 35 . . PUNCT eurjchem-124 200 36     SPACE eurjchem-124 200 37 when when SCONJ eurjchem-124 200 38     SPACE eurjchem-124 200 39 all all DET eurjchem-124 200 40     SPACE eurjchem-124 200 41 the the DET eurjchem-124 200 42     SPACE eurjchem-124 200 43 anti‐yeast anti‐yeast NOUN eurjchem-124 200 44     SPACE eurjchem-124 200 45 mic mic ADJ eurjchem-124 200 46     SPACE eurjchem-124 200 47 values value NOUN eurjchem-124 200 48     SPACE eurjchem-124 200 49 are be AUX eurjchem-124 200 50     SPACE eurjchem-124 200 51 compared compare VERB eurjchem-124 200 52 , , PUNCT eurjchem-124 200 53     SPACE eurjchem-124 200 54 three three NUM eurjchem-124 200 55     SPACE eurjchem-124 200 56 out out ADP eurjchem-124 200 57     SPACE eurjchem-124 200 58 of of ADP eurjchem-124 200 59     SPACE eurjchem-124 200 60 twelve twelve NOUN eurjchem-124 200 61     SPACE eurjchem-124 200 62 compounds compound NOUN eurjchem-124 200 63     SPACE eurjchem-124 200 64 show show NOUN eurjchem-124 200 65     SPACE eurjchem-124 200 66 good good ADJ eurjchem-124 200 67     SPACE eurjchem-124 200 68 activity activity NOUN eurjchem-124 200 69     SPACE eurjchem-124 200 70 against against ADP eurjchem-124 200 71     SPACE eurjchem-124 200 72 c. c. NOUN eurjchem-124 200 73     SPACE eurjchem-124 200 74 glabrata glabrata NOUN eurjchem-124 200 75     SPACE eurjchem-124 200 76 and and CCONJ eurjchem-124 200 77     SPACE eurjchem-124 200 78 three three NUM eurjchem-124 200 79     SPACE eurjchem-124 200 80 against against ADP eurjchem-124 200 81     SPACE eurjchem-124 200 82 c. c. NOUN eurjchem-124 200 83     SPACE eurjchem-124 200 84 tropicalis tropicali VERB eurjchem-124 200 85     SPACE eurjchem-124 200 86 ( ( PUNCT eurjchem-124 200 87 table table NOUN eurjchem-124 200 88     SPACE eurjchem-124 200 89 3 3 NUM eurjchem-124 200 90 ) ) PUNCT eurjchem-124 200 91 . . PUNCT eurjchem-124 200 92     SPACE eurjchem-124 201 1 lipophilicity lipophilicity NOUN eurjchem-124 201 2     SPACE eurjchem-124 201 3 is be AUX eurjchem-124 201 4     SPACE eurjchem-124 201 5 a a DET eurjchem-124 201 6     SPACE eurjchem-124 201 7 factor factor NOUN eurjchem-124 201 8 , , PUNCT eurjchem-124 201 9     SPACE eurjchem-124 201 10 which which PRON eurjchem-124 201 11     SPACE eurjchem-124 201 12 correlates correlate VERB eurjchem-124 201 13     SPACE eurjchem-124 201 14 well well ADV eurjchem-124 201 15     SPACE eurjchem-124 201 16 with with ADP eurjchem-124 201 17     SPACE eurjchem-124 201 18 the the DET eurjchem-124 201 19     SPACE eurjchem-124 201 20 bioactivity bioactivity NOUN eurjchem-124 201 21     SPACE eurjchem-124 201 22 of of ADP eurjchem-124 201 23     SPACE eurjchem-124 201 24 chemicals chemical NOUN eurjchem-124 201 25 , , PUNCT eurjchem-124 201 26     SPACE eurjchem-124 201 27 is be AUX eurjchem-124 201 28     SPACE eurjchem-124 201 29 a a DET eurjchem-124 201 30     SPACE eurjchem-124 201 31 very very ADV eurjchem-124 201 32     SPACE eurjchem-124 201 33 important important ADJ eurjchem-124 201 34     SPACE eurjchem-124 201 35 molecular molecular ADJ eurjchem-124 201 36     SPACE eurjchem-124 201 37 descriptor descriptor NOUN eurjchem-124 201 38     SPACE eurjchem-124 201 39 and and CCONJ eurjchem-124 201 40     SPACE eurjchem-124 201 41 different different ADJ eurjchem-124 201 42     SPACE eurjchem-124 201 43 lipophilic lipophilic ADJ eurjchem-124 201 44     SPACE eurjchem-124 201 45 behaviour behaviour NOUN eurjchem-124 201 46     SPACE eurjchem-124 201 47 of of ADP eurjchem-124 201 48     SPACE eurjchem-124 201 49 compounds compound NOUN eurjchem-124 201 50     SPACE eurjchem-124 201 51 plays play VERB eurjchem-124 201 52     SPACE eurjchem-124 201 53 an an DET eurjchem-124 201 54     SPACE eurjchem-124 201 55 important important ADJ eurjchem-124 201 56     SPACE eurjchem-124 201 57 role role NOUN eurjchem-124 201 58     SPACE eurjchem-124 201 59 in in ADP eurjchem-124 201 60     SPACE eurjchem-124 201 61 their their PRON eurjchem-124 201 62     SPACE eurjchem-124 201 63 biological biological ADJ eurjchem-124 201 64     SPACE eurjchem-124 201 65 activity activity NOUN eurjchem-124 201 66     SPACE eurjchem-124 201 67 mechanisms mechanism NOUN eurjchem-124 201 68 . . PUNCT eurjchem-124 201 69     SPACE eurjchem-124 202 1 226 226 NUM eurjchem-124 202 2     SPACE eurjchem-124 202 3 saeed saeed PROPN eurjchem-124 202 4     SPACE eurjchem-124 202 5 et et PROPN eurjchem-124 202 6     SPACE eurjchem-124 202 7 al al PROPN eurjchem-124 202 8 . . PROPN eurjchem-124 202 9     SPACE eurjchem-124 202 10 / / SYM eurjchem-124 202 11     SPACE eurjchem-124 202 12 european european ADJ eurjchem-124 202 13     SPACE eurjchem-124 202 14 journal journal NOUN eurjchem-124 202 15     SPACE eurjchem-124 202 16 of of ADP eurjchem-124 202 17     SPACE eurjchem-124 202 18 chemistry chemistry NOUN eurjchem-124 202 19     SPACE eurjchem-124 202 20 1 1 NUM eurjchem-124 202 21     SPACE eurjchem-124 202 22 ( ( PUNCT eurjchem-124 202 23 3 3 NUM eurjchem-124 202 24 ) ) PUNCT eurjchem-124 202 25     SPACE eurjchem-124 202 26 ( ( PUNCT eurjchem-124 202 27 2010 2010 NUM eurjchem-124 202 28 ) ) PUNCT eurjchem-124 202 29     SPACE eurjchem-124 203 1 221­227 221­227 NUM eurjchem-124 203 2         SPACE eurjchem-124 203 3 the the DET eurjchem-124 203 4     SPACE eurjchem-124 203 5 n‐octanol n‐octanol NUM eurjchem-124 203 6 / / SYM eurjchem-124 203 7 water water NOUN eurjchem-124 203 8     SPACE eurjchem-124 203 9 partition partition NOUN eurjchem-124 203 10     SPACE eurjchem-124 203 11 coefficient coefficient NOUN eurjchem-124 203 12     SPACE eurjchem-124 203 13 ( ( PUNCT eurjchem-124 203 14 log log NOUN eurjchem-124 203 15     SPACE eurjchem-124 203 16 pow pow NOUN eurjchem-124 203 17 ) ) PUNCT eurjchem-124 203 18     SPACE eurjchem-124 203 19 is be AUX eurjchem-124 203 20     SPACE eurjchem-124 203 21 widely widely ADV eurjchem-124 203 22     SPACE eurjchem-124 203 23 used use VERB eurjchem-124 203 24     SPACE eurjchem-124 203 25 as as ADP eurjchem-124 203 26     SPACE eurjchem-124 203 27 a a DET eurjchem-124 203 28     SPACE eurjchem-124 203 29 general general ADJ eurjchem-124 203 30     SPACE eurjchem-124 203 31 measure measure NOUN eurjchem-124 203 32     SPACE eurjchem-124 203 33 of of ADP eurjchem-124 203 34     SPACE eurjchem-124 203 35 lipophilicity lipophilicity NOUN eurjchem-124 203 36     SPACE eurjchem-124 203 37 [ [ X eurjchem-124 203 38 18,38 18,38 NUM eurjchem-124 203 39 ] ] PUNCT eurjchem-124 203 40 . . PUNCT eurjchem-124 203 41     SPACE eurjchem-124 204 1 the the DET eurjchem-124 204 2     SPACE eurjchem-124 204 3 compounds compound NOUN eurjchem-124 204 4     SPACE eurjchem-124 204 5 3 3 NUM eurjchem-124 204 6 , , PUNCT eurjchem-124 204 7     SPACE eurjchem-124 204 8 5 5 NUM eurjchem-124 204 9 , , PUNCT eurjchem-124 204 10     SPACE eurjchem-124 204 11 8 8 NUM eurjchem-124 204 12 , , PUNCT eurjchem-124 204 13     SPACE eurjchem-124 204 14 10 10 NUM eurjchem-124 204 15     SPACE eurjchem-124 204 16 and and CCONJ eurjchem-124 204 17     SPACE eurjchem-124 204 18 12 12 NUM eurjchem-124 204 19     SPACE eurjchem-124 204 20 have have VERB eurjchem-124 204 21     SPACE eurjchem-124 204 22 relatively relatively ADV eurjchem-124 204 23     SPACE eurjchem-124 204 24 higher high ADJ eurjchem-124 204 25     SPACE eurjchem-124 204 26 log log NOUN eurjchem-124 204 27     SPACE eurjchem-124 204 28 pow pow NOUN eurjchem-124 204 29     SPACE eurjchem-124 204 30 values value NOUN eurjchem-124 204 31     SPACE eurjchem-124 204 32 of of ADP eurjchem-124 204 33     SPACE eurjchem-124 204 34 3.36 3.36 NUM eurjchem-124 204 35     SPACE eurjchem-124 204 36 ± ± NOUN eurjchem-124 204 37     SPACE eurjchem-124 204 38 0.61 0.61 NUM eurjchem-124 204 39 , , PUNCT eurjchem-124 204 40     SPACE eurjchem-124 204 41 3.41 3.41 NUM eurjchem-124 204 42     SPACE eurjchem-124 204 43 ± ± NOUN eurjchem-124 204 44     SPACE eurjchem-124 204 45 0.6 0.6 NUM eurjchem-124 204 46 , , PUNCT eurjchem-124 204 47     SPACE eurjchem-124 204 48 3.65 3.65 NUM eurjchem-124 204 49     SPACE eurjchem-124 204 50 ± ± NOUN eurjchem-124 204 51     SPACE eurjchem-124 204 52 0.60 0.60 NUM eurjchem-124 204 53 , , PUNCT eurjchem-124 204 54     SPACE eurjchem-124 204 55 5.45 5.45 NUM eurjchem-124 204 56     SPACE eurjchem-124 204 57 ± ± NOUN eurjchem-124 204 58     SPACE eurjchem-124 204 59 0.60 0.60 NUM eurjchem-124 204 60 , , PUNCT eurjchem-124 204 61     SPACE eurjchem-124 204 62 and and CCONJ eurjchem-124 204 63     SPACE eurjchem-124 204 64 3.15 3.15 NUM eurjchem-124 204 65     SPACE eurjchem-124 204 66 ± ± NOUN eurjchem-124 204 67     SPACE eurjchem-124 204 68 0.93 0.93 NUM eurjchem-124 204 69 , , PUNCT eurjchem-124 204 70     SPACE eurjchem-124 204 71 respectively respectively ADV eurjchem-124 204 72 , , PUNCT eurjchem-124 204 73     SPACE eurjchem-124 204 74 and and CCONJ eurjchem-124 204 75     SPACE eurjchem-124 204 76 hence hence ADV eurjchem-124 204 77     SPACE eurjchem-124 204 78 show show VERB eurjchem-124 204 79     SPACE eurjchem-124 204 80 more more ADJ eurjchem-124 204 81     SPACE eurjchem-124 204 82 lipophilic lipophilic ADJ eurjchem-124 204 83     SPACE eurjchem-124 204 84 character character NOUN eurjchem-124 204 85 . . PUNCT eurjchem-124 204 86     SPACE eurjchem-124 204 87 antifungal antifungal ADJ eurjchem-124 204 88     SPACE eurjchem-124 204 89 activity activity NOUN eurjchem-124 204 90     SPACE eurjchem-124 204 91 ( ( PUNCT eurjchem-124 204 92 mic mic ADJ eurjchem-124 204 93     SPACE eurjchem-124 204 94 values value NOUN eurjchem-124 204 95 ) ) PUNCT eurjchem-124 204 96     SPACE eurjchem-124 204 97 for for SCONJ eurjchem-124 204 98     SPACE eurjchem-124 204 99 these these DET eurjchem-124 204 100     SPACE eurjchem-124 204 101 compounds compound NOUN eurjchem-124 204 102     SPACE eurjchem-124 204 103 is be AUX eurjchem-124 204 104     SPACE eurjchem-124 204 105 comparatively comparatively ADV eurjchem-124 204 106     SPACE eurjchem-124 204 107 lower low ADJ eurjchem-124 204 108     SPACE eurjchem-124 204 109 than than ADP eurjchem-124 204 110     SPACE eurjchem-124 204 111 those those PRON eurjchem-124 204 112     SPACE eurjchem-124 204 113 which which PRON eurjchem-124 204 114     SPACE eurjchem-124 204 115 are be AUX eurjchem-124 204 116     SPACE eurjchem-124 204 117 less less ADJ eurjchem-124 204 118     SPACE eurjchem-124 204 119 lipophilic lipophilic NOUN eurjchem-124 204 120 . . PUNCT eurjchem-124 204 121     SPACE eurjchem-124 205 1 the the DET eurjchem-124 205 2     SPACE eurjchem-124 205 3 compounds compound NOUN eurjchem-124 205 4     SPACE eurjchem-124 205 5 1 1 NUM eurjchem-124 205 6 , , PUNCT eurjchem-124 205 7     SPACE eurjchem-124 205 8 2 2 NUM eurjchem-124 205 9     SPACE eurjchem-124 205 10 and and CCONJ eurjchem-124 205 11     SPACE eurjchem-124 205 12 9 9 NUM eurjchem-124 205 13     SPACE eurjchem-124 205 14 which which PRON eurjchem-124 205 15     SPACE eurjchem-124 205 16 have have VERB eurjchem-124 205 17     SPACE eurjchem-124 205 18 the the DET eurjchem-124 205 19     SPACE eurjchem-124 205 20 log log NOUN eurjchem-124 205 21     SPACE eurjchem-124 205 22 pow pow NOUN eurjchem-124 205 23     SPACE eurjchem-124 205 24 values value NOUN eurjchem-124 205 25     SPACE eurjchem-124 205 26 of of ADP eurjchem-124 205 27     SPACE eurjchem-124 205 28 ‐2.51 ‐2.51 NOUN eurjchem-124 205 29     SPACE eurjchem-124 205 30 ± ± NOUN eurjchem-124 205 31     SPACE eurjchem-124 205 32 0.81 0.81 NUM eurjchem-124 205 33 , , PUNCT eurjchem-124 205 34     SPACE eurjchem-124 205 35 0.49 0.49 NUM eurjchem-124 205 36     SPACE eurjchem-124 205 37 ± ± NOUN eurjchem-124 205 38     SPACE eurjchem-124 205 39 0.91 0.91 NUM eurjchem-124 205 40     SPACE eurjchem-124 205 41 and and CCONJ eurjchem-124 205 42     SPACE eurjchem-124 205 43 1.69 1.69 NUM eurjchem-124 205 44     SPACE eurjchem-124 205 45 ± ± NOUN eurjchem-124 205 46     SPACE eurjchem-124 205 47 0.61 0.61 NUM eurjchem-124 205 48 , , PUNCT eurjchem-124 205 49     SPACE eurjchem-124 205 50 respectively respectively ADV eurjchem-124 205 51     SPACE eurjchem-124 205 52 show show NOUN eurjchem-124 205 53     SPACE eurjchem-124 205 54 higher high ADJ eurjchem-124 205 55     SPACE eurjchem-124 205 56 antifungal antifungal ADJ eurjchem-124 205 57     SPACE eurjchem-124 205 58 activity activity NOUN eurjchem-124 205 59     SPACE eurjchem-124 205 60 than than ADP eurjchem-124 205 61     SPACE eurjchem-124 205 62 other other ADJ eurjchem-124 205 63     SPACE eurjchem-124 205 64 investigated investigate VERB eurjchem-124 205 65     SPACE eurjchem-124 205 66 compounds compound NOUN eurjchem-124 205 67     SPACE eurjchem-124 205 68 due due ADJ eurjchem-124 205 69     SPACE eurjchem-124 205 70 probability probability NOUN eurjchem-124 205 71     SPACE eurjchem-124 205 72 to to ADP eurjchem-124 205 73     SPACE eurjchem-124 205 74 their their PRON eurjchem-124 205 75     SPACE eurjchem-124 205 76 lower low ADJ eurjchem-124 205 77     SPACE eurjchem-124 205 78 lipophilic lipophilic ADJ eurjchem-124 205 79     SPACE eurjchem-124 205 80 character character NOUN eurjchem-124 205 81 . . PUNCT eurjchem-124 205 82         SPACE eurjchem-124 206 1 table table NOUN eurjchem-124 206 2     SPACE eurjchem-124 206 3 1 1 NUM eurjchem-124 206 4 . . PUNCT eurjchem-124 206 5     SPACE eurjchem-124 206 6 bond bond NOUN eurjchem-124 206 7     SPACE eurjchem-124 206 8 lengths length NOUN eurjchem-124 206 9     SPACE eurjchem-124 207 1 [ [ X eurjchem-124 207 2 å å X eurjchem-124 207 3 ] ] X eurjchem-124 207 4 , , PUNCT eurjchem-124 207 5     SPACE eurjchem-124 207 6 angles angle VERB eurjchem-124 207 7     SPACE eurjchem-124 207 8 [ [ X eurjchem-124 207 9 ° ° X eurjchem-124 207 10 ] ] X eurjchem-124 207 11     SPACE eurjchem-124 207 12 and and CCONJ eurjchem-124 207 13     SPACE eurjchem-124 207 14 torsion torsion NOUN eurjchem-124 207 15     SPACE eurjchem-124 207 16 angles angle NOUN eurjchem-124 207 17     SPACE eurjchem-124 208 1 [ [ X eurjchem-124 208 2 ° ° X eurjchem-124 208 3 ] ] X eurjchem-124 208 4     SPACE eurjchem-124 208 5 of of ADP eurjchem-124 208 6     SPACE eurjchem-124 208 7 n n CCONJ eurjchem-124 208 8 , , PUNCT eurjchem-124 208 9 n‐diphenyl‐ n‐diphenyl‐ PROPN eurjchem-124 208 10 n’‐(thiophene‐2‐carbonyl)‐thiourea n’‐(thiophene‐2‐carbonyl)‐thiourea X eurjchem-124 208 11     SPACE eurjchem-124 208 12 ( ( PUNCT eurjchem-124 208 13 6 6 NUM eurjchem-124 208 14 ) ) PUNCT eurjchem-124 208 15 . . PUNCT eurjchem-124 208 16     SPACE eurjchem-124 209 1 bond bond NOUN eurjchem-124 209 2     SPACE eurjchem-124 209 3 lengths length NOUN eurjchem-124 209 4         SPACE eurjchem-124 209 5 s1‐c1 s1‐c1 NOUN eurjchem-124 209 6           SPACE eurjchem-124 209 7 1.666(2 1.666(2 NUM eurjchem-124 209 8 ) ) PUNCT eurjchem-124 209 9     SPACE eurjchem-124 209 10 s2‐c6 s2‐c6 VERB eurjchem-124 209 11           SPACE eurjchem-124 209 12 1.696(2 1.696(2 NUM eurjchem-124 209 13 ) ) PUNCT eurjchem-124 209 14     SPACE eurjchem-124 209 15 s2‐c3 s2‐c3 NOUN eurjchem-124 209 16           SPACE eurjchem-124 209 17 1.722(2 1.722(2 NUM eurjchem-124 209 18 ) ) PUNCT eurjchem-124 209 19     SPACE eurjchem-124 209 20 o1‐c2 o1‐c2 NOUN eurjchem-124 209 21           SPACE eurjchem-124 209 22 1.215(3 1.215(3 NUM eurjchem-124 209 23 ) ) PUNCT eurjchem-124 209 24     SPACE eurjchem-124 209 25 n1‐c1 n1‐c1 DET eurjchem-124 209 26           SPACE eurjchem-124 209 27 1.353(3 1.353(3 NUM eurjchem-124 209 28 ) ) PUNCT eurjchem-124 209 29     SPACE eurjchem-124 209 30 n1‐c21 n1‐c21 NOUN eurjchem-124 209 31           SPACE eurjchem-124 209 32 1.442(2 1.442(2 NUM eurjchem-124 209 33 ) ) PUNCT eurjchem-124 209 34     SPACE eurjchem-124 209 35 n1‐c11 n1‐c11 NOUN eurjchem-124 209 36           SPACE eurjchem-124 209 37 1.442(2 1.442(2 NUM eurjchem-124 209 38 ) ) PUNCT eurjchem-124 209 39     SPACE eurjchem-124 209 40 n2‐c1 n2‐c1 NOUN eurjchem-124 209 41           SPACE eurjchem-124 209 42 1.400(2 1.400(2 NUM eurjchem-124 209 43 ) ) PUNCT eurjchem-124 209 44     SPACE eurjchem-124 209 45 c2‐c3 c2‐c3 VERB eurjchem-124 209 46           SPACE eurjchem-124 209 47 1.473(3 1.473(3 NUM eurjchem-124 209 48 ) ) PUNCT eurjchem-124 209 49         SPACE eurjchem-124 209 50 bond bond NOUN eurjchem-124 209 51     SPACE eurjchem-124 209 52 angles angle NOUN eurjchem-124 209 53         SPACE eurjchem-124 209 54 c6‐s2‐c3 c6‐s2‐c3 PROPN eurjchem-124 209 55                                       SPACE eurjchem-124 209 56 91.76(11 91.76(11 NUM eurjchem-124 209 57 ) ) PUNCT eurjchem-124 209 58 c1‐n1‐c21 c1‐n1‐c21 NOUN eurjchem-124 209 59         SPACE eurjchem-124 209 60 124.57(16 124.57(16 NOUN eurjchem-124 209 61 ) ) PUNCT eurjchem-124 209 62 c1‐n1‐c11 c1‐n1‐c11 ADJ eurjchem-124 209 63         SPACE eurjchem-124 209 64 119.70(16 119.70(16 NOUN eurjchem-124 209 65 ) ) PUNCT eurjchem-124 209 66 c21‐n1‐c11 c21‐n1‐c11 ADJ eurjchem-124 209 67         SPACE eurjchem-124 209 68 115.68(15 115.68(15 NUM eurjchem-124 209 69 ) ) PUNCT eurjchem-124 209 70 n1‐c1‐n2 n1‐c1‐n2 PROPN eurjchem-124 209 71         SPACE eurjchem-124 209 72 116.15(16 116.15(16 NOUN eurjchem-124 209 73 ) ) PUNCT eurjchem-124 209 74 n1‐c1‐s1 n1‐c1‐s1 PROPN eurjchem-124 209 75         SPACE eurjchem-124 209 76 124.73(15 124.73(15 NUM eurjchem-124 209 77 ) ) PUNCT eurjchem-124 209 78 n2‐c1‐s1 n2‐c1‐s1 PROPN eurjchem-124 209 79         SPACE eurjchem-124 209 80 119.07(14 119.07(14 NOUN eurjchem-124 209 81 ) ) PUNCT eurjchem-124 209 82 o1‐c2‐n2 o1‐c2‐n2 NOUN eurjchem-124 209 83         SPACE eurjchem-124 209 84 122.93(18 122.93(18 NOUN eurjchem-124 209 85 ) ) PUNCT eurjchem-124 210 1 o1‐c2‐c3 o1‐c2‐c3 PROPN eurjchem-124 210 2         SPACE eurjchem-124 210 3 122.28(19 122.28(19 NUM eurjchem-124 210 4 ) ) PUNCT eurjchem-124 210 5 n2‐c2‐c3 n2‐c2‐c3 NOUN eurjchem-124 210 6         SPACE eurjchem-124 210 7 114.78(18 114.78(18 NUM eurjchem-124 210 8 ) ) PUNCT eurjchem-124 210 9 c4‐c3‐c2 c4‐c3‐c2 PROPN eurjchem-124 210 10         SPACE eurjchem-124 210 11 131.51(19 131.51(19 NUM eurjchem-124 210 12 ) ) PUNCT eurjchem-124 211 1 c4‐c3‐s2 c4‐c3‐s2 PROPN eurjchem-124 211 2         SPACE eurjchem-124 211 3 112.17(14 112.17(14 NUM eurjchem-124 211 4 ) ) PUNCT eurjchem-124 212 1 c3‐c4‐c5 c3‐c4‐c5 PROPN eurjchem-124 212 2         SPACE eurjchem-124 212 3 109.8(2 109.8(2 NUM eurjchem-124 212 4 ) ) PUNCT eurjchem-124 212 5     SPACE eurjchem-124 212 6 c5‐c6‐s2 c5‐c6‐s2 PROPN eurjchem-124 212 7         SPACE eurjchem-124 212 8 112.80(15 112.80(15 NUM eurjchem-124 212 9 ) ) PUNCT eurjchem-124 212 10     SPACE eurjchem-124 212 11 torsion torsion NOUN eurjchem-124 212 12     SPACE eurjchem-124 212 13 angles angles PROPN eurjchem-124 212 14         SPACE eurjchem-124 212 15 c21‐n1‐c1‐n2 c21‐n1‐c1‐n2 NOUN eurjchem-124 212 16                             SPACE eurjchem-124 212 17 21.2(3 21.2(3 NUM eurjchem-124 212 18 ) ) PUNCT eurjchem-124 212 19     SPACE eurjchem-124 212 20 c11‐n1‐c1‐n2 c11‐n1‐c1‐n2 NOUN eurjchem-124 212 21               SPACE eurjchem-124 212 22 ‐161.53(18 ‐161.53(18 NOUN eurjchem-124 212 23 ) ) PUNCT eurjchem-124 212 24 c21‐n1‐c1‐s1 c21‐n1‐c1‐s1 NOUN eurjchem-124 212 25           SPACE eurjchem-124 212 26 ‐156.10(16 ‐156.10(16 NUM eurjchem-124 212 27 ) ) PUNCT eurjchem-124 212 28 c11‐n1‐c1‐s1 c11‐n1‐c1‐s1 NOUN eurjchem-124 212 29                               SPACE eurjchem-124 212 30 21.1(3 21.1(3 NUM eurjchem-124 212 31 ) ) PUNCT eurjchem-124 212 32     SPACE eurjchem-124 212 33 c2‐n2‐c1‐n1 c2‐n2‐c1‐n1 NOUN eurjchem-124 212 34                                 SPACE eurjchem-124 212 35 45.2(3 45.2(3 NOUN eurjchem-124 212 36 ) ) PUNCT eurjchem-124 212 37     SPACE eurjchem-124 212 38 c2‐n2‐c1‐s1 c2‐n2‐c1‐s1 NOUN eurjchem-124 212 39           SPACE eurjchem-124 212 40 ‐137.27(16 ‐137.27(16 NOUN eurjchem-124 212 41 ) ) PUNCT eurjchem-124 212 42 c1‐n2‐c2‐c3 c1‐n2‐c2‐c3 PROPN eurjchem-124 212 43         SPACE eurjchem-124 212 44 ‐177.42(17 ‐177.42(17 NUM eurjchem-124 212 45 ) ) PUNCT eurjchem-124 212 46 o1‐c2‐c3‐c4 o1‐c2‐c3‐c4 VERB eurjchem-124 212 47                                         SPACE eurjchem-124 212 48 ‐169.6(2 ‐169.6(2 ADJ eurjchem-124 212 49 ) ) PUNCT eurjchem-124 212 50 n2‐c2‐c3‐c4 n2‐c2‐c3‐c4 ADV eurjchem-124 212 51                                 SPACE eurjchem-124 212 52 9.7(3 9.7(3 NUM eurjchem-124 212 53 ) ) PUNCT eurjchem-124 212 54     SPACE eurjchem-124 212 55 o1‐c2‐c3‐s2 o1‐c2‐c3‐s2 VERB eurjchem-124 212 56                                             SPACE eurjchem-124 212 57 7.0(2 7.0(2 NUM eurjchem-124 212 58 ) ) PUNCT eurjchem-124 212 59     SPACE eurjchem-124 212 60 n2‐c2‐c3‐s2 n2‐c2‐c3‐s2 NOUN eurjchem-124 212 61           SPACE eurjchem-124 212 62 ‐173.70(13 ‐173.70(13 NOUN eurjchem-124 212 63 ) ) PUNCT eurjchem-124 212 64 c6‐s2‐c3‐c4 c6‐s2‐c3‐c4 NOUN eurjchem-124 212 65                                 SPACE eurjchem-124 212 66 ‐0.59(16 ‐0.59(16 NUM eurjchem-124 212 67 ) ) PUNCT eurjchem-124 212 68 c6‐s2‐c3‐c2 c6‐s2‐c3‐c2 ADJ eurjchem-124 212 69           SPACE eurjchem-124 212 70 ‐177.85(15 ‐177.85(15 NOUN eurjchem-124 212 71 ) ) PUNCT eurjchem-124 212 72 s2‐c3‐c4‐c5 s2‐c3‐c4‐c5 NOUN eurjchem-124 212 73                                 SPACE eurjchem-124 212 74 0.5(2 0.5(2 NOUN eurjchem-124 212 75 ) ) PUNCT eurjchem-124 212 76     SPACE eurjchem-124 212 77 c3‐s2‐c6‐c5 c3‐s2‐c6‐c5 NOUN eurjchem-124 212 78                                 SPACE eurjchem-124 212 79 0.48(17 0.48(17 NUM eurjchem-124 212 80 ) ) PUNCT eurjchem-124 212 81         SPACE eurjchem-124 212 82 table table NOUN eurjchem-124 212 83     SPACE eurjchem-124 212 84 2 2 NUM eurjchem-124 212 85 . . PUNCT eurjchem-124 212 86     SPACE eurjchem-124 212 87 hydrogen hydrogen NOUN eurjchem-124 212 88     SPACE eurjchem-124 212 89 bonds bond NOUN eurjchem-124 212 90     SPACE eurjchem-124 213 1 [ [ X eurjchem-124 213 2 å å X eurjchem-124 213 3     SPACE eurjchem-124 213 4 and and CCONJ eurjchem-124 213 5     SPACE eurjchem-124 213 6 ° ° NOUN eurjchem-124 213 7 ] ] X eurjchem-124 213 8     SPACE eurjchem-124 213 9 of of ADP eurjchem-124 213 10     SPACE eurjchem-124 213 11 n n CCONJ eurjchem-124 213 12 , , PUNCT eurjchem-124 213 13 n‐diphenyl‐n’‐(thiophene‐2‐ n‐diphenyl‐n’‐(thiophene‐2‐ NUM eurjchem-124 213 14 carbonyl)‐thiourea carbonyl)‐thiourea NOUN eurjchem-124 213 15     SPACE eurjchem-124 213 16 ( ( PUNCT eurjchem-124 213 17 6 6 NUM eurjchem-124 213 18 ) ) PUNCT eurjchem-124 213 19 . . PUNCT eurjchem-124 213 20     SPACE eurjchem-124 214 1 d­h d­h X eurjchem-124 214 2 ... ... PUNCT eurjchem-124 214 3 a a DET eurjchem-124 214 4     SPACE eurjchem-124 214 5 d d NOUN eurjchem-124 214 6     SPACE eurjchem-124 214 7 ( ( PUNCT eurjchem-124 214 8 d­h d­h SYM eurjchem-124 214 9 ) ) PUNCT eurjchem-124 214 10     SPACE eurjchem-124 214 11 d d NOUN eurjchem-124 214 12     SPACE eurjchem-124 214 13 ( ( PUNCT eurjchem-124 214 14 h h NOUN eurjchem-124 214 15 ... ... PUNCT eurjchem-124 214 16 a a X eurjchem-124 214 17 ) ) PUNCT eurjchem-124 214 18     SPACE eurjchem-124 215 1 d d NOUN eurjchem-124 215 2     SPACE eurjchem-124 215 3 ( ( PUNCT eurjchem-124 215 4 d d NOUN eurjchem-124 215 5 ... ... PUNCT eurjchem-124 215 6 a a X eurjchem-124 215 7 ) ) PUNCT eurjchem-124 215 8     SPACE eurjchem-124 215 9 < < X eurjchem-124 215 10     SPACE eurjchem-124 215 11 ( ( PUNCT eurjchem-124 215 12 dha dha PROPN eurjchem-124 215 13 ) ) PUNCT eurjchem-124 215 14     SPACE eurjchem-124 215 15 n2‐h02 n2‐h02 PROPN eurjchem-124 215 16 ... ... PUNCT eurjchem-124 215 17 s1i s1i PROPN eurjchem-124 215 18     SPACE eurjchem-124 215 19 0.86(3 0.86(3 NOUN eurjchem-124 215 20 ) ) PUNCT eurjchem-124 215 21     SPACE eurjchem-124 215 22 2.71(3 2.71(3 NUM eurjchem-124 215 23 ) ) PUNCT eurjchem-124 215 24 3.5022(19 3.5022(19 NUM eurjchem-124 215 25 ) ) PUNCT eurjchem-124 215 26       SPACE eurjchem-124 215 27 154(2 154(2 NUM eurjchem-124 215 28 ) ) PUNCT eurjchem-124 215 29 c4‐h4 c4‐h4 NOUN eurjchem-124 215 30 ... ... PUNCT eurjchem-124 216 1 s1i s1i PROPN eurjchem-124 216 2     SPACE eurjchem-124 216 3 0.95 0.95 NUM eurjchem-124 216 4     SPACE eurjchem-124 216 5 2.90 2.90 NUM eurjchem-124 216 6     SPACE eurjchem-124 216 7 3.770(2 3.770(2 NUM eurjchem-124 216 8 ) ) PUNCT eurjchem-124 216 9     SPACE eurjchem-124 216 10 153.3 153.3 NUM eurjchem-124 216 11 c24‐h24 c24‐h24 PROPN eurjchem-124 216 12 ... ... PUNCT eurjchem-124 216 13 s2 s2 PROPN eurjchem-124 216 14     SPACE eurjchem-124 216 15 ii ii NOUN eurjchem-124 216 16     SPACE eurjchem-124 216 17 0.95 0.95 NUM eurjchem-124 216 18     SPACE eurjchem-124 216 19 3.03 3.03 NUM eurjchem-124 216 20     SPACE eurjchem-124 216 21 3.516(2 3.516(2 NUM eurjchem-124 216 22 ) ) PUNCT eurjchem-124 216 23     SPACE eurjchem-124 216 24 113.7 113.7 NUM eurjchem-124 216 25 c24‐h24 c24‐h24 PROPN eurjchem-124 216 26 ... ... PUNCT eurjchem-124 216 27 o o NOUN eurjchem-124 216 28     SPACE eurjchem-124 216 29 ii ii NOUN eurjchem-124 216 30     SPACE eurjchem-124 216 31 0.95 0.95 NUM eurjchem-124 216 32     SPACE eurjchem-124 216 33 2.52 2.52 NUM eurjchem-124 216 34     SPACE eurjchem-124 216 35 3.390(3 3.390(3 NUM eurjchem-124 216 36 ) ) PUNCT eurjchem-124 216 37     SPACE eurjchem-124 216 38 151.7 151.7 NUM eurjchem-124 216 39 symmetry symmetry NOUN eurjchem-124 216 40     SPACE eurjchem-124 216 41 transformations transformation NOUN eurjchem-124 216 42     SPACE eurjchem-124 216 43 used use VERB eurjchem-124 216 44     SPACE eurjchem-124 216 45 to to PART eurjchem-124 216 46     SPACE eurjchem-124 216 47 generate generate VERB eurjchem-124 216 48     SPACE eurjchem-124 216 49 equivalent equivalent ADJ eurjchem-124 216 50     SPACE eurjchem-124 216 51 atoms atom NOUN eurjchem-124 216 52 : : PUNCT eurjchem-124 216 53     SPACE eurjchem-124 216 54 ( ( PUNCT eurjchem-124 216 55 i i NOUN eurjchem-124 216 56 ) ) PUNCT eurjchem-124 216 57     SPACE eurjchem-124 216 58 ‐x ‐x NOUN eurjchem-124 216 59 , , PUNCT eurjchem-124 216 60     SPACE eurjchem-124 216 61 y+1/2 y+1/2 ADJ eurjchem-124 216 62 , , PUNCT eurjchem-124 216 63           SPACE eurjchem-124 216 64 ‐z ‐z NOUN eurjchem-124 216 65 ; ; PUNCT eurjchem-124 216 66     SPACE eurjchem-124 216 67 ( ( PUNCT eurjchem-124 216 68 ii ii NOUN eurjchem-124 216 69 ) ) PUNCT eurjchem-124 216 70     SPACE eurjchem-124 217 1 ‐x+1 ‐x+1 PROPN eurjchem-124 217 2 , , PUNCT eurjchem-124 217 3     SPACE eurjchem-124 217 4 y+1/2 y+1/2 PROPN eurjchem-124 217 5 , , PUNCT eurjchem-124 217 6     SPACE eurjchem-124 217 7 ‐z+1 ‐z+1 PROPN eurjchem-124 217 8 . . PUNCT eurjchem-124 217 9                           SPACE eurjchem-124 218 1 4 4 NUM eurjchem-124 218 2 . . PUNCT eurjchem-124 218 3     SPACE eurjchem-124 218 4 conclusion conclusion NOUN eurjchem-124 218 5         SPACE eurjchem-124 218 6 to to PART eurjchem-124 218 7     SPACE eurjchem-124 218 8 summarize summarize VERB eurjchem-124 218 9 , , PUNCT eurjchem-124 218 10     SPACE eurjchem-124 218 11 we we PRON eurjchem-124 218 12     SPACE eurjchem-124 218 13 have have AUX eurjchem-124 218 14     SPACE eurjchem-124 218 15 described describe VERB eurjchem-124 218 16     SPACE eurjchem-124 218 17 a a DET eurjchem-124 218 18     SPACE eurjchem-124 218 19 simple simple NOUN eurjchem-124 218 20     SPACE eurjchem-124 218 21 and and CCONJ eurjchem-124 218 22     SPACE eurjchem-124 218 23 efficient efficient ADJ eurjchem-124 218 24     SPACE eurjchem-124 218 25 method method NOUN eurjchem-124 218 26     SPACE eurjchem-124 218 27 for for ADP eurjchem-124 218 28     SPACE eurjchem-124 218 29 the the DET eurjchem-124 218 30     SPACE eurjchem-124 218 31 synthesis synthesis NOUN eurjchem-124 218 32     SPACE eurjchem-124 218 33 of of ADP eurjchem-124 218 34     SPACE eurjchem-124 218 35 thiourea thiourea NOUN eurjchem-124 218 36     SPACE eurjchem-124 218 37 derivatives derivative NOUN eurjchem-124 218 38     SPACE eurjchem-124 218 39 in in ADP eurjchem-124 218 40     SPACE eurjchem-124 218 41 high high ADJ eurjchem-124 218 42     SPACE eurjchem-124 218 43 purity purity NOUN eurjchem-124 218 44     SPACE eurjchem-124 218 45 and and CCONJ eurjchem-124 218 46     SPACE eurjchem-124 218 47 high high ADJ eurjchem-124 218 48     SPACE eurjchem-124 218 49 yield yield NOUN eurjchem-124 218 50     SPACE eurjchem-124 218 51 using use VERB eurjchem-124 218 52     SPACE eurjchem-124 218 53 tetrabutylammonium tetrabutylammonium NOUN eurjchem-124 218 54     SPACE eurjchem-124 218 55 bromide bromide NOUN eurjchem-124 218 56     SPACE eurjchem-124 218 57 ( ( PUNCT eurjchem-124 218 58 tbab tbab PROPN eurjchem-124 218 59 ) ) PUNCT eurjchem-124 218 60     SPACE eurjchem-124 218 61 as as ADP eurjchem-124 218 62     SPACE eurjchem-124 218 63 phase‐transfer phase‐transfer NOUN eurjchem-124 218 64     SPACE eurjchem-124 218 65 catalyst catalyst NOUN eurjchem-124 218 66     SPACE eurjchem-124 218 67 ( ( PUNCT eurjchem-124 218 68 pta pta PROPN eurjchem-124 218 69 ) ) PUNCT eurjchem-124 218 70 . . PUNCT eurjchem-124 218 71     SPACE eurjchem-124 219 1 products product NOUN eurjchem-124 219 2     SPACE eurjchem-124 219 3 yield yield NOUN eurjchem-124 219 4     SPACE eurjchem-124 219 5 was be AUX eurjchem-124 219 6     SPACE eurjchem-124 219 7 improved improve VERB eurjchem-124 219 8     SPACE eurjchem-124 219 9 from from ADP eurjchem-124 219 10     SPACE eurjchem-124 219 11 4‐5 4‐5 NOUN eurjchem-124 219 12 % % NOUN eurjchem-124 219 13     SPACE eurjchem-124 219 14 as as SCONJ eurjchem-124 219 15     SPACE eurjchem-124 219 16 compared compare VERB eurjchem-124 219 17     SPACE eurjchem-124 219 18 to to ADP eurjchem-124 219 19     SPACE eurjchem-124 219 20 reactions reaction NOUN eurjchem-124 219 21     SPACE eurjchem-124 219 22 when when SCONJ eurjchem-124 219 23     SPACE eurjchem-124 219 24 carried carry VERB eurjchem-124 219 25     SPACE eurjchem-124 219 26 out out ADP eurjchem-124 219 27     SPACE eurjchem-124 219 28 without without ADP eurjchem-124 219 29     SPACE eurjchem-124 219 30 tbab tbab PROPN eurjchem-124 219 31 . . PUNCT eurjchem-124 219 32     SPACE eurjchem-124 219 33 finally finally ADV eurjchem-124 219 34 , , PUNCT eurjchem-124 219 35     SPACE eurjchem-124 219 36 the the DET eurjchem-124 219 37     SPACE eurjchem-124 219 38 structure structure NOUN eurjchem-124 219 39     SPACE eurjchem-124 219 40 of of ADP eurjchem-124 219 41     SPACE eurjchem-124 219 42 compound compound NOUN eurjchem-124 219 43     SPACE eurjchem-124 219 44 6 6 NUM eurjchem-124 219 45     SPACE eurjchem-124 219 46 was be AUX eurjchem-124 219 47     SPACE eurjchem-124 219 48 determined determine VERB eurjchem-124 219 49     SPACE eurjchem-124 219 50 by by ADP eurjchem-124 219 51     SPACE eurjchem-124 219 52 x‐ray x‐ray ADJ eurjchem-124 219 53     SPACE eurjchem-124 219 54 crystallographic crystallographic ADJ eurjchem-124 219 55     SPACE eurjchem-124 219 56 studies study NOUN eurjchem-124 219 57 . . PUNCT eurjchem-124 219 58     SPACE eurjchem-124 220 1 the the DET eurjchem-124 220 2     SPACE eurjchem-124 220 3 antifungal antifungal ADJ eurjchem-124 220 4     SPACE eurjchem-124 220 5 activity activity NOUN eurjchem-124 220 6     SPACE eurjchem-124 220 7 of of ADP eurjchem-124 220 8     SPACE eurjchem-124 220 9 this this DET eurjchem-124 220 10     SPACE eurjchem-124 220 11 series series NOUN eurjchem-124 220 12     SPACE eurjchem-124 220 13 suggests suggest VERB eurjchem-124 220 14     SPACE eurjchem-124 220 15 the the DET eurjchem-124 220 16     SPACE eurjchem-124 220 17 thiophene‐thiourea thiophene‐thiourea NOUN eurjchem-124 220 18     SPACE eurjchem-124 220 19 core core NOUN eurjchem-124 220 20     SPACE eurjchem-124 220 21 offers offer VERB eurjchem-124 220 22     SPACE eurjchem-124 220 23 a a DET eurjchem-124 220 24     SPACE eurjchem-124 220 25 novel novel NOUN eurjchem-124 220 26     SPACE eurjchem-124 220 27 template template NOUN eurjchem-124 220 28     SPACE eurjchem-124 220 29 for for ADP eurjchem-124 220 30     SPACE eurjchem-124 220 31 the the DET eurjchem-124 220 32     SPACE eurjchem-124 220 33 development development NOUN eurjchem-124 220 34     SPACE eurjchem-124 220 35 of of ADP eurjchem-124 220 36     SPACE eurjchem-124 220 37 a a DET eurjchem-124 220 38     SPACE eurjchem-124 220 39 new new ADJ eurjchem-124 220 40     SPACE eurjchem-124 220 41 class class NOUN eurjchem-124 220 42     SPACE eurjchem-124 220 43 of of ADP eurjchem-124 220 44     SPACE eurjchem-124 220 45 antifungal antifungal ADJ eurjchem-124 220 46     SPACE eurjchem-124 220 47 agents agent NOUN eurjchem-124 220 48 . . PUNCT eurjchem-124 220 49     SPACE eurjchem-124 221 1 the the DET eurjchem-124 221 2     SPACE eurjchem-124 221 3 structure structure NOUN eurjchem-124 221 4     SPACE eurjchem-124 221 5 of of ADP eurjchem-124 221 6     SPACE eurjchem-124 221 7 compounds compound NOUN eurjchem-124 221 8     SPACE eurjchem-124 221 9 1 1 NUM eurjchem-124 221 10 , , PUNCT eurjchem-124 221 11     SPACE eurjchem-124 221 12 2 2 NUM eurjchem-124 221 13     SPACE eurjchem-124 221 14 and and CCONJ eurjchem-124 221 15     SPACE eurjchem-124 221 16 9 9 NUM eurjchem-124 221 17     SPACE eurjchem-124 221 18 waits wait NOUN eurjchem-124 221 19     SPACE eurjchem-124 221 20 for for ADP eurjchem-124 221 21     SPACE eurjchem-124 221 22 further further ADJ eurjchem-124 221 23     SPACE eurjchem-124 221 24 modification modification NOUN eurjchem-124 221 25 , , PUNCT eurjchem-124 221 26     SPACE eurjchem-124 221 27 in in ADP eurjchem-124 221 28     SPACE eurjchem-124 221 29 expectation expectation NOUN eurjchem-124 221 30     SPACE eurjchem-124 221 31 of of ADP eurjchem-124 221 32     SPACE eurjchem-124 221 33 getting get VERB eurjchem-124 221 34     SPACE eurjchem-124 221 35 better well ADJ eurjchem-124 221 36     SPACE eurjchem-124 221 37 biological biological ADJ eurjchem-124 221 38     SPACE eurjchem-124 221 39 activities activity NOUN eurjchem-124 221 40 . . PUNCT eurjchem-124 221 41         SPACE eurjchem-124 221 42 table table NOUN eurjchem-124 221 43     SPACE eurjchem-124 221 44 3 3 NUM eurjchem-124 221 45 . . PUNCT eurjchem-124 221 46     SPACE eurjchem-124 221 47 mic mic ADJ eurjchem-124 221 48     SPACE eurjchem-124 221 49 values value NOUN eurjchem-124 221 50     SPACE eurjchem-124 221 51 ( ( PUNCT eurjchem-124 221 52 μg μg PROPN eurjchem-124 221 53 / / SYM eurjchem-124 221 54 ml ml NOUN eurjchem-124 221 55 ) ) PUNCT eurjchem-124 221 56     SPACE eurjchem-124 221 57 of of ADP eurjchem-124 221 58     SPACE eurjchem-124 221 59 the the DET eurjchem-124 221 60     SPACE eurjchem-124 221 61 synthesized synthesize VERB eurjchem-124 221 62     SPACE eurjchem-124 221 63 thiourea thiourea NOUN eurjchem-124 221 64     SPACE eurjchem-124 221 65 derivatives derivative NOUN eurjchem-124 221 66     SPACE eurjchem-124 221 67 against against ADP eurjchem-124 221 68     SPACE eurjchem-124 221 69 the the DET eurjchem-124 221 70     SPACE eurjchem-124 221 71 tested test VERB eurjchem-124 221 72     SPACE eurjchem-124 221 73 fungi fungi PROPN eurjchem-124 221 74 . . PUNCT eurjchem-124 221 75     SPACE eurjchem-124 221 76 compound compound PROPN eurjchem-124 221 77         SPACE eurjchem-124 221 78 c. c. PROPN eurjchem-124 221 79     SPACE eurjchem-124 221 80 glabrata glabrata PROPN eurjchem-124 221 81     SPACE eurjchem-124 221 82 ( ( PUNCT eurjchem-124 221 83 atcc32554 atcc32554 PROPN eurjchem-124 221 84 ) ) PUNCT eurjchem-124 221 85                   SPACE eurjchem-124 221 86 c. c. NOUN eurjchem-124 221 87     SPACE eurjchem-124 221 88 albicans albican NOUN eurjchem-124 221 89     SPACE eurjchem-124 221 90 ( ( PUNCT eurjchem-124 221 91 atcc atcc NOUN eurjchem-124 221 92     SPACE eurjchem-124 221 93 90028 90028 NUM eurjchem-124 221 94 ) ) PUNCT eurjchem-124 221 95             SPACE eurjchem-124 221 96 c. c. PROPN eurjchem-124 221 97     SPACE eurjchem-124 221 98 tropicalis tropicali VERB eurjchem-124 221 99     SPACE eurjchem-124 221 100 ( ( PUNCT eurjchem-124 221 101 atcc atcc NOUN eurjchem-124 221 102     SPACE eurjchem-124 221 103 20336 20336 NUM eurjchem-124 221 104 ) ) PUNCT eurjchem-124 221 105               SPACE eurjchem-124 221 106 1 1 NUM eurjchem-124 221 107     SPACE eurjchem-124 221 108 20 20 NUM eurjchem-124 221 109     SPACE eurjchem-124 221 110 20 20 NUM eurjchem-124 221 111       SPACE eurjchem-124 221 112 25 25 NUM eurjchem-124 221 113                       SPACE eurjchem-124 221 114 2 2 NUM eurjchem-124 221 115 25 25 NUM eurjchem-124 221 116 25 25 NUM eurjchem-124 221 117                             SPACE eurjchem-124 221 118 25 25 NUM eurjchem-124 221 119                             SPACE eurjchem-124 221 120 3 3 NUM eurjchem-124 221 121         SPACE eurjchem-124 221 122 100 100 NUM eurjchem-124 221 123     SPACE eurjchem-124 221 124 100 100 NUM eurjchem-124 221 125                               SPACE eurjchem-124 221 126 50 50 NUM eurjchem-124 221 127                 SPACE eurjchem-124 221 128 4 4 NUM eurjchem-124 221 129     SPACE eurjchem-124 221 130 50 50 NUM eurjchem-124 221 131     SPACE eurjchem-124 221 132 50 50 NUM eurjchem-124 221 133       SPACE eurjchem-124 221 134 50 50 NUM eurjchem-124 221 135     SPACE eurjchem-124 221 136 5 5 NUM eurjchem-124 221 137     SPACE eurjchem-124 221 138 100 100 NUM eurjchem-124 221 139           SPACE eurjchem-124 221 140 100 100 NUM eurjchem-124 221 141               SPACE eurjchem-124 221 142 100 100 NUM eurjchem-124 221 143                   SPACE eurjchem-124 221 144 6 6 NUM eurjchem-124 221 145     SPACE eurjchem-124 221 146 50 50 NUM eurjchem-124 221 147     SPACE eurjchem-124 221 148 100 100 NUM eurjchem-124 221 149       SPACE eurjchem-124 221 150 100 100 NUM eurjchem-124 221 151 7 7 NUM eurjchem-124 221 152     SPACE eurjchem-124 221 153 50 50 NUM eurjchem-124 221 154     SPACE eurjchem-124 221 155 50 50 NUM eurjchem-124 221 156       SPACE eurjchem-124 221 157 50 50 NUM eurjchem-124 221 158     SPACE eurjchem-124 221 159 8 8 NUM eurjchem-124 221 160     SPACE eurjchem-124 221 161 100 100 NUM eurjchem-124 221 162     SPACE eurjchem-124 221 163 100 100 NUM eurjchem-124 221 164       SPACE eurjchem-124 221 165 100 100 NUM eurjchem-124 221 166 9 9 NUM eurjchem-124 221 167     SPACE eurjchem-124 221 168 25 25 NUM eurjchem-124 221 169     SPACE eurjchem-124 221 170 25 25 NUM eurjchem-124 221 171       SPACE eurjchem-124 221 172 20 20 NUM eurjchem-124 221 173     SPACE eurjchem-124 221 174 10 10 NUM eurjchem-124 221 175     SPACE eurjchem-124 221 176 > > ADV eurjchem-124 221 177 100 100 NUM eurjchem-124 221 178     SPACE eurjchem-124 221 179 > > X eurjchem-124 221 180 100 100 NUM eurjchem-124 221 181       SPACE eurjchem-124 221 182 > > SYM eurjchem-124 221 183 100 100 NUM eurjchem-124 221 184 11 11 NUM eurjchem-124 221 185     SPACE eurjchem-124 221 186 100 100 NUM eurjchem-124 221 187     SPACE eurjchem-124 221 188 50 50 NUM eurjchem-124 221 189       SPACE eurjchem-124 221 190 50 50 NUM eurjchem-124 221 191     SPACE eurjchem-124 221 192 12 12 NUM eurjchem-124 221 193     SPACE eurjchem-124 221 194 100 100 NUM eurjchem-124 221 195     SPACE eurjchem-124 221 196 50 50 NUM eurjchem-124 221 197       SPACE eurjchem-124 221 198 100 100 NUM eurjchem-124 221 199 nystatin nystatin NOUN eurjchem-124 221 200                                   SPACE eurjchem-124 221 201 2 2 NUM eurjchem-124 221 202     SPACE eurjchem-124 221 203 1 1 NUM eurjchem-124 221 204       SPACE eurjchem-124 221 205 4 4 NUM eurjchem-124 221 206         SPACE eurjchem-124 221 207 acknowledgement acknowledgement NOUN eurjchem-124 221 208         SPACE eurjchem-124 221 209 the the DET eurjchem-124 221 210     SPACE eurjchem-124 221 211 authors author NOUN eurjchem-124 221 212     SPACE eurjchem-124 221 213 are be AUX eurjchem-124 221 214     SPACE eurjchem-124 221 215 grateful grateful ADJ eurjchem-124 221 216     SPACE eurjchem-124 221 217 to to ADP eurjchem-124 221 218     SPACE eurjchem-124 221 219 national national ADJ eurjchem-124 221 220     SPACE eurjchem-124 221 221 engineering engineering NOUN eurjchem-124 221 222     SPACE eurjchem-124 221 223 & & CCONJ eurjchem-124 221 224     SPACE eurjchem-124 221 225 scientific scientific ADJ eurjchem-124 221 226     SPACE eurjchem-124 221 227 commission commission NOUN eurjchem-124 221 228 , , PUNCT eurjchem-124 221 229     SPACE eurjchem-124 221 230 islamabad islamabad NOUN eurjchem-124 221 231     SPACE eurjchem-124 221 232 for for ADP eurjchem-124 221 233     SPACE eurjchem-124 221 234 providing provide VERB eurjchem-124 221 235     SPACE eurjchem-124 221 236 the the DET eurjchem-124 221 237     SPACE eurjchem-124 221 238 facility facility NOUN eurjchem-124 221 239     SPACE eurjchem-124 221 240 of of ADP eurjchem-124 221 241     SPACE eurjchem-124 221 242 spectroscopic spectroscopic NOUN eurjchem-124 221 243     SPACE eurjchem-124 221 244 techniques technique NOUN eurjchem-124 221 245 , , PUNCT eurjchem-124 221 246     SPACE eurjchem-124 221 247 elemental elemental NOUN eurjchem-124 221 248     SPACE eurjchem-124 221 249 analyzer analyzer NOUN eurjchem-124 221 250     SPACE eurjchem-124 221 251 and and CCONJ eurjchem-124 221 252     SPACE eurjchem-124 221 253 chemicals chemical NOUN eurjchem-124 221 254     SPACE eurjchem-124 221 255 free free ADJ eurjchem-124 221 256     SPACE eurjchem-124 221 257 of of ADP eurjchem-124 221 258     SPACE eurjchem-124 221 259 cost cost NOUN eurjchem-124 221 260 . . PUNCT eurjchem-124 221 261           SPACE eurjchem-124 221 262 supplementary supplementary ADJ eurjchem-124 221 263     SPACE eurjchem-124 221 264 material material NOUN eurjchem-124 221 265         SPACE eurjchem-124 221 266 ccdc‐755273 ccdc‐755273 PROPN eurjchem-124 221 267     SPACE eurjchem-124 221 268 contains contain VERB eurjchem-124 221 269     SPACE eurjchem-124 221 270 the the DET eurjchem-124 221 271     SPACE eurjchem-124 221 272 supplementary supplementary ADJ eurjchem-124 221 273     SPACE eurjchem-124 221 274 crystallographic crystallographic ADJ eurjchem-124 221 275     SPACE eurjchem-124 221 276 data datum NOUN eurjchem-124 221 277     SPACE eurjchem-124 221 278 for for ADP eurjchem-124 221 279     SPACE eurjchem-124 221 280 this this DET eurjchem-124 221 281     SPACE eurjchem-124 221 282 paper paper NOUN eurjchem-124 221 283 . . PUNCT eurjchem-124 221 284     SPACE eurjchem-124 222 1 these these DET eurjchem-124 222 2     SPACE eurjchem-124 222 3 data datum NOUN eurjchem-124 222 4     SPACE eurjchem-124 222 5 can can AUX eurjchem-124 222 6     SPACE eurjchem-124 222 7 be be AUX eurjchem-124 222 8     SPACE eurjchem-124 222 9 obtained obtain VERB eurjchem-124 222 10     SPACE eurjchem-124 222 11 free free ADJ eurjchem-124 222 12     SPACE eurjchem-124 222 13 of of ADP eurjchem-124 222 14     SPACE eurjchem-124 222 15 charge charge NOUN eurjchem-124 222 16     SPACE eurjchem-124 222 17 via via ADP eurjchem-124 222 18     SPACE eurjchem-124 222 19 www.ccdc.cam.ac.uk/data_request/cif www.ccdc.cam.ac.uk/data_request/cif NOUN eurjchem-124 222 20 , , PUNCT eurjchem-124 222 21     SPACE eurjchem-124 222 22 or or CCONJ eurjchem-124 222 23     SPACE eurjchem-124 222 24 by by ADP eurjchem-124 222 25     SPACE eurjchem-124 222 26 e‐mailing e‐mailing NOUN eurjchem-124 222 27     SPACE eurjchem-124 222 28 data_request@ccdc.cam.ac.uk data_request@ccdc.cam.ac.uk PROPN eurjchem-124 222 29 , , PUNCT eurjchem-124 222 30     SPACE eurjchem-124 222 31 or or CCONJ eurjchem-124 222 32     SPACE eurjchem-124 222 33 by by ADP eurjchem-124 222 34     SPACE eurjchem-124 222 35 contacting contact VERB eurjchem-124 222 36     SPACE eurjchem-124 222 37 the the DET eurjchem-124 222 38     SPACE eurjchem-124 222 39 cambridge cambridge PROPN eurjchem-124 222 40     SPACE eurjchem-124 222 41 crystallographic crystallographic ADJ eurjchem-124 222 42     SPACE eurjchem-124 222 43 data data NOUN eurjchem-124 222 44     SPACE eurjchem-124 222 45 centre centre NOUN eurjchem-124 222 46 , , PUNCT eurjchem-124 222 47     SPACE eurjchem-124 222 48 12 12 NUM eurjchem-124 222 49     SPACE eurjchem-124 222 50 union union NOUN eurjchem-124 222 51     SPACE eurjchem-124 222 52 road road NOUN eurjchem-124 222 53 , , PUNCT eurjchem-124 222 54     SPACE eurjchem-124 222 55 cambridge cambridge PROPN eurjchem-124 222 56     SPACE eurjchem-124 222 57 cb2 cb2 PROPN eurjchem-124 222 58     SPACE eurjchem-124 222 59 1ez 1ez NOUN eurjchem-124 222 60 , , PUNCT eurjchem-124 222 61     SPACE eurjchem-124 222 62 uk uk PROPN eurjchem-124 222 63 ; ; PUNCT eurjchem-124 222 64     SPACE eurjchem-124 222 65 fax fax NOUN eurjchem-124 222 66 : : PUNCT eurjchem-124 222 67     SPACE eurjchem-124 222 68 +44(0)1223‐336033 +44(0)1223‐336033 ADJ eurjchem-124 222 69 . . PUNCT eurjchem-124 222 70         SPACE eurjchem-124 222 71 references reference NOUN eurjchem-124 222 72         SPACE eurjchem-124 223 1 [ [ X eurjchem-124 223 2 1 1 NUM eurjchem-124 223 3 ] ] PUNCT eurjchem-124 223 4 . . PUNCT eurjchem-124 224 1 verma verma PROPN eurjchem-124 224 2 , , PUNCT eurjchem-124 224 3     SPACE eurjchem-124 224 4 r. r. PROPN eurjchem-124 224 5     SPACE eurjchem-124 224 6 k. k. PROPN eurjchem-124 224 7 ; ; PUNCT eurjchem-124 224 8     SPACE eurjchem-124 224 9 verma verma PROPN eurjchem-124 224 10 , , PUNCT eurjchem-124 224 11     SPACE eurjchem-124 224 12 l. l. PROPN eurjchem-124 224 13 ; ; PUNCT eurjchem-124 224 14     SPACE eurjchem-124 224 15 ranjan ranjan PROPN eurjchem-124 224 16 , , PUNCT eurjchem-124 224 17     SPACE eurjchem-124 224 18 m. m. NOUN eurjchem-124 224 19 ; ; PUNCT eurjchem-124 224 20     SPACE eurjchem-124 224 21 verma verma PROPN eurjchem-124 224 22 , , PUNCT eurjchem-124 224 23     SPACE eurjchem-124 224 24 b. b. PROPN eurjchem-124 224 25     SPACE eurjchem-124 224 26 p. p. NOUN eurjchem-124 224 27 ; ; PUNCT eurjchem-124 224 28     SPACE eurjchem-124 224 29 mojumdar mojumdar PROPN eurjchem-124 224 30 , , PUNCT eurjchem-124 224 31     SPACE eurjchem-124 224 32 s. s. PROPN eurjchem-124 224 33     SPACE eurjchem-124 224 34 c. c. PROPN eurjchem-124 224 35     SPACE eurjchem-124 224 36 j. j. PROPN eurjchem-124 224 37     SPACE eurjchem-124 224 38 therm therm PROPN eurjchem-124 224 39 . . PUNCT eurjchem-124 224 40     SPACE eurjchem-124 224 41 anal anal ADJ eurjchem-124 224 42 . . PUNCT eurjchem-124 224 43     SPACE eurjchem-124 224 44 cal cal PROPN eurjchem-124 224 45 . . PUNCT eurjchem-124 224 46     SPACE eurjchem-124 224 47 2008 2008 NUM eurjchem-124 224 48 , , PUNCT eurjchem-124 224 49     SPACE eurjchem-124 224 50 94 94 NUM eurjchem-124 224 51 , , PUNCT eurjchem-124 224 52     SPACE eurjchem-124 224 53 27‐31 27‐31 NUM eurjchem-124 224 54 . . PUNCT eurjchem-124 224 55     SPACE eurjchem-124 225 1 [ [ X eurjchem-124 225 2 2 2 NUM eurjchem-124 225 3 ] ] PUNCT eurjchem-124 225 4 . . PUNCT eurjchem-124 226 1 stiffel stiffel PROPN eurjchem-124 226 2 , , PUNCT eurjchem-124 226 3     SPACE eurjchem-124 226 4 e. e. PROPN eurjchem-124 226 5     SPACE eurjchem-124 226 6 i. i. PROPN eurjchem-124 226 7 ; ; PUNCT eurjchem-124 226 8     SPACE eurjchem-124 226 9 george george PROPN eurjchem-124 226 10 , , PUNCT eurjchem-124 226 11     SPACE eurjchem-124 226 12 g. g. PROPN eurjchem-124 226 13     SPACE eurjchem-124 226 14 n. n. NOUN eurjchem-124 226 15 ; ; PUNCT eurjchem-124 226 16     SPACE eurjchem-124 226 17 bertini bertini NOUN eurjchem-124 226 18 , , PUNCT eurjchem-124 226 19     SPACE eurjchem-124 226 20 i. i. NOUN eurjchem-124 226 21 ; ; PUNCT eurjchem-124 226 22     SPACE eurjchem-124 226 23 gray gray ADJ eurjchem-124 226 24 , , PUNCT eurjchem-124 226 25     SPACE eurjchem-124 226 26 h. h. PROPN eurjchem-124 226 27     SPACE eurjchem-124 226 28 b. b. PROPN eurjchem-124 226 29 ; ; PUNCT eurjchem-124 226 30     SPACE eurjchem-124 226 31 lippard lippard ADJ eurjchem-124 226 32 , , PUNCT eurjchem-124 226 33     SPACE eurjchem-124 226 34 s. s. PROPN eurjchem-124 226 35     SPACE eurjchem-124 226 36 j. j. PROPN eurjchem-124 226 37 ; ; PUNCT eurjchem-124 226 38     SPACE eurjchem-124 226 39 valentine valentine NOUN eurjchem-124 226 40 , , PUNCT eurjchem-124 226 41     SPACE eurjchem-124 226 42 j. j. PROPN eurjchem-124 226 43     SPACE eurjchem-124 226 44 s. s. PROPN eurjchem-124 226 45     SPACE eurjchem-124 226 46 bioinorganic bioinorganic PROPN eurjchem-124 226 47     SPACE eurjchem-124 226 48 chemistry chemistry NOUN eurjchem-124 226 49 , , PUNCT eurjchem-124 226 50     SPACE eurjchem-124 226 51 university university NOUN eurjchem-124 226 52     SPACE eurjchem-124 226 53 science science NOUN eurjchem-124 226 54     SPACE eurjchem-124 226 55 books book NOUN eurjchem-124 226 56 , , PUNCT eurjchem-124 226 57     SPACE eurjchem-124 226 58 1998 1998 NUM eurjchem-124 226 59 . . PUNCT eurjchem-124 226 60     SPACE eurjchem-124 227 1 [ [ X eurjchem-124 227 2 3 3 NUM eurjchem-124 227 3 ] ] PUNCT eurjchem-124 227 4 . . PUNCT eurjchem-124 228 1 cotton cotton NOUN eurjchem-124 228 2 , , PUNCT eurjchem-124 228 3     SPACE eurjchem-124 228 4 f. f. PROPN eurjchem-124 228 5     SPACE eurjchem-124 228 6 a. a. NOUN eurjchem-124 228 7 ; ; PUNCT eurjchem-124 228 8     SPACE eurjchem-124 228 9 wilkinson wilkinson PROPN eurjchem-124 228 10 , , PUNCT eurjchem-124 228 11     SPACE eurjchem-124 228 12 g. g. NOUN eurjchem-124 228 13 ; ; PUNCT eurjchem-124 228 14     SPACE eurjchem-124 228 15 murillo murillo PROPN eurjchem-124 228 16 , , PUNCT eurjchem-124 228 17     SPACE eurjchem-124 228 18 a. a. NOUN eurjchem-124 228 19 ; ; PUNCT eurjchem-124 228 20     SPACE eurjchem-124 228 21 bochman bochman NOUN eurjchem-124 228 22 , , PUNCT eurjchem-124 228 23     SPACE eurjchem-124 228 24 m. m. NOUN eurjchem-124 228 25     SPACE eurjchem-124 228 26 advanced advanced ADJ eurjchem-124 228 27     SPACE eurjchem-124 228 28 inorganic inorganic ADJ eurjchem-124 228 29     SPACE eurjchem-124 228 30 chemistry chemistry NOUN eurjchem-124 228 31 , , PUNCT eurjchem-124 228 32     SPACE eurjchem-124 228 33 6th 6th ADJ eurjchem-124 228 34     SPACE eurjchem-124 228 35 edition edition NOUN eurjchem-124 228 36 , , PUNCT eurjchem-124 228 37     SPACE eurjchem-124 228 38 john john PROPN eurjchem-124 228 39     SPACE eurjchem-124 228 40 wiley wiley PROPN eurjchem-124 228 41     SPACE eurjchem-124 228 42 & & CCONJ eurjchem-124 228 43     SPACE eurjchem-124 228 44 sons son NOUN eurjchem-124 228 45 , , PUNCT eurjchem-124 228 46     SPACE eurjchem-124 228 47 1999 1999 NUM eurjchem-124 228 48 . . PUNCT eurjchem-124 228 49     SPACE eurjchem-124 229 1 [ [ X eurjchem-124 229 2 4 4 NUM eurjchem-124 229 3 ] ] PUNCT eurjchem-124 229 4 . . PUNCT eurjchem-124 230 1 d’hooghe d’hooghe PROPN eurjchem-124 230 2 , , PUNCT eurjchem-124 230 3     SPACE eurjchem-124 230 4 m. m. NOUN eurjchem-124 230 5 ; ; PUNCT eurjchem-124 230 6     SPACE eurjchem-124 230 7 waterinckx waterinckx VERB eurjchem-124 230 8 , , PUNCT eurjchem-124 230 9     SPACE eurjchem-124 230 10 a. a. NOUN eurjchem-124 230 11 ; ; PUNCT eurjchem-124 230 12     SPACE eurjchem-124 230 13 de de X eurjchem-124 230 14     SPACE eurjchem-124 230 15 kimpe kimpe VERB eurjchem-124 230 16 , , PUNCT eurjchem-124 230 17     SPACE eurjchem-124 230 18 n. n. PROPN eurjchem-124 230 19       SPACE eurjchem-124 230 20 j. j. PROPN eurjchem-124 230 21     SPACE eurjchem-124 230 22 org org PROPN eurjchem-124 230 23 . . PUNCT eurjchem-124 230 24     SPACE eurjchem-124 230 25 chem chem NOUN eurjchem-124 230 26 . . PUNCT eurjchem-124 230 27     SPACE eurjchem-124 230 28 2005 2005 NUM eurjchem-124 230 29 , , PUNCT eurjchem-124 230 30     SPACE eurjchem-124 230 31 70 70 NUM eurjchem-124 230 32 , , PUNCT eurjchem-124 230 33     SPACE eurjchem-124 230 34 227‐232 227‐232 NUM eurjchem-124 230 35 . . PUNCT eurjchem-124 230 36     SPACE eurjchem-124 231 1 [ [ X eurjchem-124 231 2 5 5 NUM eurjchem-124 231 3 ] ] PUNCT eurjchem-124 231 4 . . PUNCT eurjchem-124 232 1 handerson handerson PROPN eurjchem-124 232 2 , , PUNCT eurjchem-124 232 3     SPACE eurjchem-124 232 4 w. w. PROPN eurjchem-124 232 5 ; ; PUNCT eurjchem-124 232 6     SPACE eurjchem-124 232 7 nicholson nicholson PROPN eurjchem-124 232 8 , , PUNCT eurjchem-124 232 9     SPACE eurjchem-124 232 10 b. b. PROPN eurjchem-124 232 11     SPACE eurjchem-124 232 12 k. k. PROPN eurjchem-124 232 13 ; ; PUNCT eurjchem-124 232 14     SPACE eurjchem-124 232 15 dinger dinger NOUN eurjchem-124 232 16 , , PUNCT eurjchem-124 232 17     SPACE eurjchem-124 232 18 m. m. NOUN eurjchem-124 232 19     SPACE eurjchem-124 232 20 b. b. PROPN eurjchem-124 232 21 ; ; PUNCT eurjchem-124 232 22     SPACE eurjchem-124 232 23 bennett bennett PROPN eurjchem-124 232 24 , , PUNCT eurjchem-124 232 25     SPACE eurjchem-124 232 26 r. r. PROPN eurjchem-124 232 27     SPACE eurjchem-124 232 28 l. l. PROPN eurjchem-124 232 29     SPACE eurjchem-124 232 30 inorg inorg PROPN eurjchem-124 232 31 . . PUNCT eurjchem-124 232 32     SPACE eurjchem-124 233 1 chim chim PROPN eurjchem-124 233 2 . . PUNCT eurjchem-124 233 3     SPACE eurjchem-124 234 1 acta acta PROPN eurjchem-124 234 2     SPACE eurjchem-124 234 3 2002 2002 NUM eurjchem-124 234 4 , , PUNCT eurjchem-124 234 5     SPACE eurjchem-124 234 6 338 338 NUM eurjchem-124 234 7 , , PUNCT eurjchem-124 234 8     SPACE eurjchem-124 234 9 210‐218 210‐218 NUM eurjchem-124 234 10 . . PUNCT eurjchem-124 234 11     SPACE eurjchem-124 235 1 [ [ X eurjchem-124 235 2 6 6 NUM eurjchem-124 235 3 ] ] PUNCT eurjchem-124 235 4 . . PUNCT eurjchem-124 236 1 sacht sacht PROPN eurjchem-124 236 2 , , PUNCT eurjchem-124 236 3     SPACE eurjchem-124 236 4 c. c. NOUN eurjchem-124 236 5 ; ; PUNCT eurjchem-124 236 6     SPACE eurjchem-124 236 7 datt datt PROPN eurjchem-124 236 8 , , PUNCT eurjchem-124 236 9     SPACE eurjchem-124 236 10 m. m. NOUN eurjchem-124 236 11     SPACE eurjchem-124 236 12 s. s. PROPN eurjchem-124 236 13 ; ; PUNCT eurjchem-124 236 14     SPACE eurjchem-124 236 15 otto otto PROPN eurjchem-124 236 16 , , PUNCT eurjchem-124 236 17     SPACE eurjchem-124 236 18 s. s. PROPN eurjchem-124 236 19 ; ; PUNCT eurjchem-124 236 20     SPACE eurjchem-124 236 21 roodt roodt NOUN eurjchem-124 236 22 , , PUNCT eurjchem-124 236 23     SPACE eurjchem-124 236 24 a. a. NOUN eurjchem-124 236 25     SPACE eurjchem-124 236 26 j. j. PROPN eurjchem-124 236 27     SPACE eurjchem-124 236 28 chem chem NOUN eurjchem-124 236 29 . . PUNCT eurjchem-124 236 30     SPACE eurjchem-124 236 31 soc soc NOUN eurjchem-124 236 32 . . PUNCT eurjchem-124 236 33     SPACE eurjchem-124 236 34 dalton dalton PROPN eurjchem-124 236 35     SPACE eurjchem-124 236 36 trans tran NOUN eurjchem-124 236 37 . . PUNCT eurjchem-124 236 38     SPACE eurjchem-124 236 39 2000 2000 NUM eurjchem-124 236 40 , , PUNCT eurjchem-124 236 41     SPACE eurjchem-124 236 42 24 24 NUM eurjchem-124 236 43 , , PUNCT eurjchem-124 236 44     SPACE eurjchem-124 236 45 4579‐4586 4579‐4586 NOUN eurjchem-124 236 46 . . PUNCT eurjchem-124 236 47     SPACE eurjchem-124 237 1 [ [ X eurjchem-124 237 2 7 7 NUM eurjchem-124 237 3 ] ] PUNCT eurjchem-124 237 4 . . PUNCT eurjchem-124 238 1 lipowska lipowska NOUN eurjchem-124 238 2 , , PUNCT eurjchem-124 238 3     SPACE eurjchem-124 238 4 m. m. NOUN eurjchem-124 238 5 ; ; PUNCT eurjchem-124 238 6     SPACE eurjchem-124 238 7 hayes hayes PROPN eurjchem-124 238 8 , , PUNCT eurjchem-124 238 9     SPACE eurjchem-124 238 10 b. b. PROPN eurjchem-124 238 11     SPACE eurjchem-124 238 12 l. l. PROPN eurjchem-124 238 13 ; ; PUNCT eurjchem-124 238 14     SPACE eurjchem-124 238 15 hansen hansen PROPN eurjchem-124 238 16 , , PUNCT eurjchem-124 238 17     SPACE eurjchem-124 238 18 l. l. PROPN eurjchem-124 238 19 ; ; PUNCT eurjchem-124 238 20     SPACE eurjchem-124 238 21 taylor taylor PROPN eurjchem-124 238 22 , , PUNCT eurjchem-124 238 23     SPACE eurjchem-124 238 24 a. a. NOUN eurjchem-124 238 25 ; ; PUNCT eurjchem-124 238 26     SPACE eurjchem-124 238 27 marzilli marzilli PROPN eurjchem-124 238 28 , , PUNCT eurjchem-124 238 29     SPACE eurjchem-124 238 30 l. l. PROPN eurjchem-124 238 31     SPACE eurjchem-124 238 32 g. g. PROPN eurjchem-124 238 33     SPACE eurjchem-124 238 34 inorg inorg PROPN eurjchem-124 238 35 . . PUNCT eurjchem-124 238 36     SPACE eurjchem-124 238 37 chem chem NOUN eurjchem-124 238 38 . . PUNCT eurjchem-124 238 39     SPACE eurjchem-124 238 40 1996 1996 NUM eurjchem-124 238 41 , , PUNCT eurjchem-124 238 42     SPACE eurjchem-124 238 43 35 35 NUM eurjchem-124 238 44 , , PUNCT eurjchem-124 238 45     SPACE eurjchem-124 238 46 4227‐4231 4227‐4231 NUM eurjchem-124 238 47 . . PUNCT eurjchem-124 238 48     SPACE eurjchem-124 239 1 [ [ X eurjchem-124 239 2 8 8 NUM eurjchem-124 239 3 ] ] PUNCT eurjchem-124 239 4 . . PUNCT eurjchem-124 240 1 zuckerman zuckerman PROPN eurjchem-124 240 2 , , PUNCT eurjchem-124 240 3     SPACE eurjchem-124 240 4 r. r. PROPN eurjchem-124 240 5     SPACE eurjchem-124 240 6 l. l. PROPN eurjchem-124 240 7 ; ; PUNCT eurjchem-124 240 8     SPACE eurjchem-124 240 9 bergman bergman PROPN eurjchem-124 240 10 , , PUNCT eurjchem-124 240 11     SPACE eurjchem-124 240 12 r. r. PROPN eurjchem-124 240 13     SPACE eurjchem-124 240 14 g. g. PROPN eurjchem-124 240 15     SPACE eurjchem-124 240 16 organometallics organometallic NOUN eurjchem-124 240 17     SPACE eurjchem-124 240 18 2000 2000 NUM eurjchem-124 240 19 , , PUNCT eurjchem-124 240 20     SPACE eurjchem-124 240 21 19 19 NUM eurjchem-124 240 22 , , PUNCT eurjchem-124 240 23     SPACE eurjchem-124 240 24 4795‐ 4795‐ NUM eurjchem-124 240 25 4809 4809 NUM eurjchem-124 240 26 . . PUNCT eurjchem-124 240 27       SPACE eurjchem-124 241 1 [ [ X eurjchem-124 241 2 9 9 NUM eurjchem-124 241 3 ] ] PUNCT eurjchem-124 241 4 . . PUNCT eurjchem-124 242 1 henderson henderson PROPN eurjchem-124 242 2 , , PUNCT eurjchem-124 242 3     SPACE eurjchem-124 242 4 w. w. PROPN eurjchem-124 242 5 ; ; PUNCT eurjchem-124 242 6     SPACE eurjchem-124 242 7 kemmitt kemmitt VERB eurjchem-124 242 8 , , PUNCT eurjchem-124 242 9     SPACE eurjchem-124 242 10 r. r. PROPN eurjchem-124 242 11     SPACE eurjchem-124 242 12 d. d. PROPN eurjchem-124 242 13     SPACE eurjchem-124 242 14 w. w. PROPN eurjchem-124 242 15 ; ; PUNCT eurjchem-124 242 16     SPACE eurjchem-124 242 17 mason mason PROPN eurjchem-124 242 18 , , PUNCT eurjchem-124 242 19     SPACE eurjchem-124 242 20 s. s. PROPN eurjchem-124 242 21 ; ; PUNCT eurjchem-124 242 22     SPACE eurjchem-124 242 23 moore moore PROPN eurjchem-124 242 24 , , PUNCT eurjchem-124 242 25     SPACE eurjchem-124 242 26 m. m. NOUN eurjchem-124 242 27     SPACE eurjchem-124 242 28 r. r. PROPN eurjchem-124 242 29 ; ; PUNCT eurjchem-124 242 30     SPACE eurjchem-124 242 31 fawcett fawcett PROPN eurjchem-124 242 32 , , PUNCT eurjchem-124 242 33     SPACE eurjchem-124 242 34 j. j. PROPN eurjchem-124 242 35 ; ; PUNCT eurjchem-124 242 36     SPACE eurjchem-124 242 37 russell russell PROPN eurjchem-124 242 38 , , PUNCT eurjchem-124 242 39     SPACE eurjchem-124 242 40 d. d. PROPN eurjchem-124 242 41     SPACE eurjchem-124 242 42 r. r. PROPN eurjchem-124 242 43     SPACE eurjchem-124 242 44 j. j. PROPN eurjchem-124 242 45     SPACE eurjchem-124 242 46 chem chem NOUN eurjchem-124 242 47 . . PUNCT eurjchem-124 242 48     SPACE eurjchem-124 242 49 soc soc PROPN eurjchem-124 242 50 . . PUNCT eurjchem-124 242 51     SPACE eurjchem-124 242 52 dalton dalton PROPN eurjchem-124 242 53     SPACE eurjchem-124 242 54 trans trans PROPN eurjchem-124 242 55 . . PUNCT eurjchem-124 242 56     SPACE eurjchem-124 242 57 1992 1992 NUM eurjchem-124 242 58 , , PUNCT eurjchem-124 242 59     SPACE eurjchem-124 242 60 1 1 NUM eurjchem-124 242 61 , , PUNCT eurjchem-124 242 62     SPACE eurjchem-124 242 63 59‐66 59‐66 NOUN eurjchem-124 242 64 . . PUNCT eurjchem-124 242 65       SPACE eurjchem-124 243 1 [ [ X eurjchem-124 243 2 10 10 NUM eurjchem-124 243 3 ] ] PUNCT eurjchem-124 243 4 . . PUNCT eurjchem-124 244 1 arslan arslan PROPN eurjchem-124 244 2 , , PUNCT eurjchem-124 244 3     SPACE eurjchem-124 244 4 h. h. PROPN eurjchem-124 244 5 ; ; PUNCT eurjchem-124 244 6     SPACE eurjchem-124 244 7 külcü külcü NOUN eurjchem-124 244 8 , , PUNCT eurjchem-124 244 9     SPACE eurjchem-124 244 10 n. n. NOUN eurjchem-124 244 11 ; ; PUNCT eurjchem-124 244 12     SPACE eurjchem-124 244 13 flörke flörke NOUN eurjchem-124 244 14 , , PUNCT eurjchem-124 244 15     SPACE eurjchem-124 244 16 u. u. NOUN eurjchem-124 244 17     SPACE eurjchem-124 244 18 trans trans PROPN eurjchem-124 244 19 . . PUNCT eurjchem-124 244 20     SPACE eurjchem-124 244 21 metal metal NOUN eurjchem-124 244 22     SPACE eurjchem-124 244 23 chem chem NOUN eurjchem-124 244 24 . . PUNCT eurjchem-124 244 25     SPACE eurjchem-124 244 26 2003 2003 NUM eurjchem-124 244 27 , , PUNCT eurjchem-124 244 28     SPACE eurjchem-124 244 29 32(7 32(7 NOUN eurjchem-124 244 30 ) ) PUNCT eurjchem-124 244 31 , , PUNCT eurjchem-124 244 32     SPACE eurjchem-124 244 33 816‐ 816‐ NUM eurjchem-124 244 34 819 819 NUM eurjchem-124 244 35 . . PUNCT eurjchem-124 244 36       SPACE eurjchem-124 245 1 [ [ X eurjchem-124 245 2 11 11 NUM eurjchem-124 245 3 ] ] PUNCT eurjchem-124 245 4 . . PUNCT eurjchem-124 246 1 binzet binzet PROPN eurjchem-124 246 2 , , PUNCT eurjchem-124 246 3     SPACE eurjchem-124 246 4 g. g. NOUN eurjchem-124 246 5 ; ; PUNCT eurjchem-124 246 6     SPACE eurjchem-124 246 7 arslan arslan NOUN eurjchem-124 246 8 , , PUNCT eurjchem-124 246 9     SPACE eurjchem-124 246 10 h. h. PROPN eurjchem-124 246 11 ; ; PUNCT eurjchem-124 246 12     SPACE eurjchem-124 246 13 flörke flörke NOUN eurjchem-124 246 14 , , PUNCT eurjchem-124 246 15     SPACE eurjchem-124 246 16 u. u. NOUN eurjchem-124 246 17 ; ; PUNCT eurjchem-124 246 18     SPACE eurjchem-124 246 19 külcü külcü NOUN eurjchem-124 246 20 , , PUNCT eurjchem-124 246 21     SPACE eurjchem-124 246 22 n. n. NOUN eurjchem-124 246 23 ; ; PUNCT eurjchem-124 246 24     SPACE eurjchem-124 246 25 duran duran NOUN eurjchem-124 246 26 , , PUNCT eurjchem-124 246 27     SPACE eurjchem-124 246 28 n. n. PROPN eurjchem-124 246 29     SPACE eurjchem-124 246 30 j. j. PROPN eurjchem-124 246 31     SPACE eurjchem-124 246 32 cood cood PROPN eurjchem-124 246 33 . . PUNCT eurjchem-124 246 34     SPACE eurjchem-124 246 35 chem chem NOUN eurjchem-124 246 36 . . PUNCT eurjchem-124 246 37     SPACE eurjchem-124 246 38 2006 2006 NUM eurjchem-124 246 39 , , PUNCT eurjchem-124 246 40     SPACE eurjchem-124 246 41 59(12 59(12 NUM eurjchem-124 246 42 ) ) PUNCT eurjchem-124 246 43 , , PUNCT eurjchem-124 246 44     SPACE eurjchem-124 246 45 1395‐1406 1395‐1406 NUM eurjchem-124 246 46 . . PUNCT eurjchem-124 246 47       SPACE eurjchem-124 247 1 [ [ X eurjchem-124 247 2 12 12 NUM eurjchem-124 247 3 ] ] PUNCT eurjchem-124 247 4 . . PUNCT eurjchem-124 248 1 ugur ugur PROPN eurjchem-124 248 2 , , PUNCT eurjchem-124 248 3     SPACE eurjchem-124 248 4 d. d. PROPN eurjchem-124 248 5 ; ; PUNCT eurjchem-124 248 6     SPACE eurjchem-124 248 7 arslan arslan PROPN eurjchem-124 248 8 , , PUNCT eurjchem-124 248 9     SPACE eurjchem-124 248 10 h. h. PROPN eurjchem-124 248 11 ; ; PUNCT eurjchem-124 248 12     SPACE eurjchem-124 248 13 külcü külcü NOUN eurjchem-124 248 14 , , PUNCT eurjchem-124 248 15     SPACE eurjchem-124 248 16 n. n. NOUN eurjchem-124 248 17     SPACE eurjchem-124 248 18 russ russ PROPN eurjchem-124 248 19 . . PUNCT eurjchem-124 248 20     SPACE eurjchem-124 248 21 j. j. PROPN eurjchem-124 248 22     SPACE eurjchem-124 248 23 coord coord NOUN eurjchem-124 248 24 . . PUNCT eurjchem-124 248 25     SPACE eurjchem-124 248 26 chem chem NOUN eurjchem-124 248 27 . . PUNCT eurjchem-124 248 28     SPACE eurjchem-124 249 1 2006 2006 NUM eurjchem-124 249 2 , , PUNCT eurjchem-124 249 3     SPACE eurjchem-124 249 4 32(9 32(9 NUM eurjchem-124 249 5 ) ) PUNCT eurjchem-124 249 6 , , PUNCT eurjchem-124 249 7     SPACE eurjchem-124 249 8 669‐ 669‐ NUM eurjchem-124 249 9 675 675 NUM eurjchem-124 249 10 . . PUNCT eurjchem-124 249 11       SPACE eurjchem-124 250 1 [ [ X eurjchem-124 250 2 13 13 NUM eurjchem-124 250 3 ] ] PUNCT eurjchem-124 250 4 . . PUNCT eurjchem-124 251 1 emen eman NOUN eurjchem-124 251 2 , , PUNCT eurjchem-124 251 3     SPACE eurjchem-124 251 4 m. m. NOUN eurjchem-124 251 5     SPACE eurjchem-124 251 6 f. f. PROPN eurjchem-124 251 7 ; ; PUNCT eurjchem-124 251 8     SPACE eurjchem-124 251 9 arslan arslan NOUN eurjchem-124 251 10 , , PUNCT eurjchem-124 251 11     SPACE eurjchem-124 251 12 h. h. PROPN eurjchem-124 251 13 ; ; PUNCT eurjchem-124 251 14     SPACE eurjchem-124 251 15 külcü külcü NOUN eurjchem-124 251 16 , , PUNCT eurjchem-124 251 17     SPACE eurjchem-124 251 18 n. n. NOUN eurjchem-124 251 19 ; ; PUNCT eurjchem-124 251 20     SPACE eurjchem-124 251 21 flörke flörke NOUN eurjchem-124 251 22 , , PUNCT eurjchem-124 251 23     SPACE eurjchem-124 251 24 u. u. NOUN eurjchem-124 251 25 ; ; PUNCT eurjchem-124 251 26     SPACE eurjchem-124 251 27 duran duran NOUN eurjchem-124 251 28 , , PUNCT eurjchem-124 251 29     SPACE eurjchem-124 251 30 n. n. NOUN eurjchem-124 251 31     SPACE eurjchem-124 251 32 polish polish NOUN eurjchem-124 251 33 . . PUNCT eurjchem-124 251 34     SPACE eurjchem-124 251 35 j. j. PROPN eurjchem-124 251 36     SPACE eurjchem-124 251 37 chem chem NOUN eurjchem-124 251 38 . . PUNCT eurjchem-124 251 39     SPACE eurjchem-124 251 40 2005 2005 NUM eurjchem-124 251 41 , , PUNCT eurjchem-124 251 42     SPACE eurjchem-124 251 43 79(10 79(10 NUM eurjchem-124 251 44 ) ) PUNCT eurjchem-124 251 45 , , PUNCT eurjchem-124 251 46     SPACE eurjchem-124 251 47 1615‐1626 1615‐1626 NUM eurjchem-124 251 48 . . PUNCT eurjchem-124 251 49       SPACE eurjchem-124 252 1 [ [ X eurjchem-124 252 2 14 14 NUM eurjchem-124 252 3 ] ] PUNCT eurjchem-124 252 4 . . PUNCT eurjchem-124 253 1 yesilkaynak yesilkaynak NOUN eurjchem-124 253 2 , , PUNCT eurjchem-124 253 3     SPACE eurjchem-124 253 4 t. t. PROPN eurjchem-124 253 5 ; ; PUNCT eurjchem-124 253 6     SPACE eurjchem-124 253 7 binzet binzet NOUN eurjchem-124 253 8 , , PUNCT eurjchem-124 253 9     SPACE eurjchem-124 253 10 g. g. NOUN eurjchem-124 253 11 ; ; PUNCT eurjchem-124 253 12     SPACE eurjchem-124 253 13 emen eman NOUN eurjchem-124 253 14 , , PUNCT eurjchem-124 253 15     SPACE eurjchem-124 253 16 f. f. PROPN eurjchem-124 253 17     SPACE eurjchem-124 253 18 m. m. NOUN eurjchem-124 253 19 ; ; PUNCT eurjchem-124 253 20     SPACE eurjchem-124 253 21 flörke flörke NOUN eurjchem-124 253 22 , , PUNCT eurjchem-124 253 23     SPACE eurjchem-124 253 24 u. u. NOUN eurjchem-124 253 25 ; ; PUNCT eurjchem-124 253 26     SPACE eurjchem-124 253 27 külcü külcü PROPN eurjchem-124 253 28 , , PUNCT eurjchem-124 253 29     SPACE eurjchem-124 253 30 n. n. NOUN eurjchem-124 253 31 ; ; PUNCT eurjchem-124 253 32     SPACE eurjchem-124 253 33 arslan arslan NOUN eurjchem-124 253 34 , , PUNCT eurjchem-124 253 35     SPACE eurjchem-124 253 36 h. h. PROPN eurjchem-124 253 37     SPACE eurjchem-124 253 38 eur eur PROPN eurjchem-124 253 39 . . PUNCT eurjchem-124 253 40     SPACE eurjchem-124 253 41 j. j. PROPN eurjchem-124 253 42     SPACE eurjchem-124 253 43 chem chem NOUN eurjchem-124 253 44 . . PUNCT eurjchem-124 253 45     SPACE eurjchem-124 253 46 2010 2010 NUM eurjchem-124 253 47 , , PUNCT eurjchem-124 253 48     SPACE eurjchem-124 253 49 1(1 1(1 NUM eurjchem-124 253 50 ) ) PUNCT eurjchem-124 253 51 , , PUNCT eurjchem-124 253 52     SPACE eurjchem-124 253 53 1‐5 1‐5 NUM eurjchem-124 253 54 . . PUNCT eurjchem-124 253 55       SPACE eurjchem-124 254 1 [ [ X eurjchem-124 254 2 15 15 NUM eurjchem-124 254 3 ] ] PUNCT eurjchem-124 254 4 . . PUNCT eurjchem-124 255 1 koch koch PROPN eurjchem-124 255 2 , , PUNCT eurjchem-124 255 3     SPACE eurjchem-124 255 4 k. k. PROPN eurjchem-124 255 5     SPACE eurjchem-124 255 6 r. r. PROPN eurjchem-124 255 7 ; ; PUNCT eurjchem-124 255 8     SPACE eurjchem-124 255 9 sacht sacht NOUN eurjchem-124 255 10 , , PUNCT eurjchem-124 255 11     SPACE eurjchem-124 255 12 c. c. NOUN eurjchem-124 255 13 ; ; PUNCT eurjchem-124 255 14     SPACE eurjchem-124 255 15 grimmbacher grimmbacher NOUN eurjchem-124 255 16 , , PUNCT eurjchem-124 255 17     SPACE eurjchem-124 255 18 t. t. PROPN eurjchem-124 255 19 ; ; PUNCT eurjchem-124 255 20     SPACE eurjchem-124 255 21 bourne bourne NOUN eurjchem-124 255 22 , , PUNCT eurjchem-124 255 23     SPACE eurjchem-124 255 24 s. s. PROPN eurjchem-124 255 25     SPACE eurjchem-124 255 26 s. s. PROPN eurjchem-124 255 27     SPACE eurjchem-124 255 28 afr afr PROPN eurjchem-124 255 29 . . PUNCT eurjchem-124 255 30     SPACE eurjchem-124 255 31 j. j. PROPN eurjchem-124 255 32     SPACE eurjchem-124 255 33 chem chem NOUN eurjchem-124 255 34 . . PUNCT eurjchem-124 255 35     SPACE eurjchem-124 255 36 1995 1995 NUM eurjchem-124 255 37 , , PUNCT eurjchem-124 255 38     SPACE eurjchem-124 255 39 48 48 NUM eurjchem-124 255 40     SPACE eurjchem-124 255 41 ( ( PUNCT eurjchem-124 255 42 1­2 1­2 PROPN eurjchem-124 255 43 ) ) PUNCT eurjchem-124 255 44 , , PUNCT eurjchem-124 255 45     SPACE eurjchem-124 255 46 71‐77 71‐77 NUM eurjchem-124 255 47 . . PUNCT eurjchem-124 255 48       SPACE eurjchem-124 256 1 [ [ X eurjchem-124 256 2 16 16 NUM eurjchem-124 256 3 ] ] PUNCT eurjchem-124 256 4 . . PUNCT eurjchem-124 257 1 saeed saeed PROPN eurjchem-124 257 2 , , PUNCT eurjchem-124 257 3     SPACE eurjchem-124 257 4 s. s. PROPN eurjchem-124 257 5 ; ; PUNCT eurjchem-124 257 6     SPACE eurjchem-124 257 7 rashid rashid PROPN eurjchem-124 257 8 , , PUNCT eurjchem-124 257 9     SPACE eurjchem-124 257 10 n. n. NOUN eurjchem-124 257 11 ; ; PUNCT eurjchem-124 257 12     SPACE eurjchem-124 257 13 hussain hussain PROPN eurjchem-124 257 14 , , PUNCT eurjchem-124 257 15     SPACE eurjchem-124 257 16 r. r. PROPN eurjchem-124 257 17 ; ; PUNCT eurjchem-124 257 18     SPACE eurjchem-124 257 19 ali ali PROPN eurjchem-124 257 20 , , PUNCT eurjchem-124 257 21     SPACE eurjchem-124 257 22 m. m. NOUN eurjchem-124 257 23 ; ; PUNCT eurjchem-124 257 24     SPACE eurjchem-124 257 25 jones jone NOUN eurjchem-124 257 26 , , PUNCT eurjchem-124 257 27     SPACE eurjchem-124 257 28 p. p. NOUN eurjchem-124 257 29     SPACE eurjchem-124 257 30 g. g. PROPN eurjchem-124 257 31     SPACE eurjchem-124 257 32 eur eur PROPN eurjchem-124 257 33 . . PUNCT eurjchem-124 257 34     SPACE eurjchem-124 257 35 j. j. PROPN eurjchem-124 257 36     SPACE eurjchem-124 257 37 med med PROPN eurjchem-124 257 38 . . PUNCT eurjchem-124 257 39     SPACE eurjchem-124 257 40 chem chem NOUN eurjchem-124 257 41 . . PUNCT eurjchem-124 257 42     SPACE eurjchem-124 258 1 2010 2010 NUM eurjchem-124 258 2 , , PUNCT eurjchem-124 258 3     SPACE eurjchem-124 258 4 45 45 NUM eurjchem-124 258 5 , , PUNCT eurjchem-124 258 6     SPACE eurjchem-124 258 7 1323‐1331 1323‐1331 NUM eurjchem-124 258 8 . . PUNCT eurjchem-124 258 9       SPACE eurjchem-124 259 1 [ [ X eurjchem-124 259 2 17 17 NUM eurjchem-124 259 3 ] ] PUNCT eurjchem-124 259 4 . . PUNCT eurjchem-124 260 1 zhang zhang PROPN eurjchem-124 260 2 , , PUNCT eurjchem-124 260 3     SPACE eurjchem-124 260 4 y. y. NOUN eurjchem-124 260 5     SPACE eurjchem-124 260 6 m. m. NOUN eurjchem-124 260 7 ; ; PUNCT eurjchem-124 260 8     SPACE eurjchem-124 260 9 wei wei PROPN eurjchem-124 260 10 , , PUNCT eurjchem-124 260 11     SPACE eurjchem-124 260 12 t. t. PROPN eurjchem-124 260 13     SPACE eurjchem-124 260 14 b. b. PROPN eurjchem-124 260 15 ; ; PUNCT eurjchem-124 260 16     SPACE eurjchem-124 260 17 xian xian NOUN eurjchem-124 260 18 , , PUNCT eurjchem-124 260 19     SPACE eurjchem-124 260 20 l. l. PROPN eurjchem-124 260 21 ; ; PUNCT eurjchem-124 260 22     SPACE eurjchem-124 260 23 gao gao PROPN eurjchem-124 260 24 , , PUNCT eurjchem-124 260 25     SPACE eurjchem-124 260 26 l. l. PROPN eurjchem-124 260 27     SPACE eurjchem-124 260 28 m. m. NOUN eurjchem-124 260 29     SPACE eurjchem-124 260 30 phosphorus phosphorus NOUN eurjchem-124 260 31     SPACE eurjchem-124 260 32 sulfur sulfur NOUN eurjchem-124 260 33     SPACE eurjchem-124 260 34 silicon silicon NOUN eurjchem-124 260 35     SPACE eurjchem-124 260 36 relat relat NOUN eurjchem-124 260 37 . . PUNCT eurjchem-124 260 38     SPACE eurjchem-124 260 39 elem elem NOUN eurjchem-124 260 40 . . PUNCT eurjchem-124 260 41     SPACE eurjchem-124 260 42 2004 2004 NUM eurjchem-124 260 43 , , PUNCT eurjchem-124 260 44     SPACE eurjchem-124 260 45 179 179 NUM eurjchem-124 260 46 , , PUNCT eurjchem-124 260 47     SPACE eurjchem-124 260 48 2007‐2013 2007‐2013 NOUN eurjchem-124 260 49 . . PUNCT eurjchem-124 260 50       SPACE eurjchem-124 261 1 [ [ X eurjchem-124 261 2 18 18 NUM eurjchem-124 261 3 ] ] PUNCT eurjchem-124 261 4 . . PUNCT eurjchem-124 262 1 arslan arslan PROPN eurjchem-124 262 2 , , PUNCT eurjchem-124 262 3     SPACE eurjchem-124 262 4 h. h. PROPN eurjchem-124 262 5 ; ; PUNCT eurjchem-124 262 6     SPACE eurjchem-124 262 7 duran duran NOUN eurjchem-124 262 8 , , PUNCT eurjchem-124 262 9     SPACE eurjchem-124 262 10 n. n. NOUN eurjchem-124 262 11 ; ; PUNCT eurjchem-124 262 12     SPACE eurjchem-124 262 13 borekci borekci ADJ eurjchem-124 262 14 , , PUNCT eurjchem-124 262 15     SPACE eurjchem-124 262 16 g. g. NOUN eurjchem-124 262 17 ; ; PUNCT eurjchem-124 262 18     SPACE eurjchem-124 262 19 ozer ozer NOUN eurjchem-124 262 20 , , PUNCT eurjchem-124 262 21     SPACE eurjchem-124 262 22 c. c. PROPN eurjchem-124 262 23     SPACE eurjchem-124 262 24 k. k. PROPN eurjchem-124 262 25 ; ; PUNCT eurjchem-124 262 26     SPACE eurjchem-124 262 27 akbay akbay PROPN eurjchem-124 262 28 , , PUNCT eurjchem-124 262 29     SPACE eurjchem-124 262 30 c. c. NOUN eurjchem-124 262 31     SPACE eurjchem-124 262 32 molecules molecule NOUN eurjchem-124 262 33     SPACE eurjchem-124 262 34 2009 2009 NUM eurjchem-124 262 35 , , PUNCT eurjchem-124 262 36     SPACE eurjchem-124 262 37 14 14 NUM eurjchem-124 262 38 , , PUNCT eurjchem-124 262 39     SPACE eurjchem-124 262 40 519‐527 519‐527 NUM eurjchem-124 262 41 . . PUNCT eurjchem-124 262 42       SPACE eurjchem-124 263 1 [ [ X eurjchem-124 263 2 19 19 NUM eurjchem-124 263 3 ] ] PUNCT eurjchem-124 263 4 . . PUNCT eurjchem-124 264 1 gu gu NOUN eurjchem-124 264 2 , , PUNCT eurjchem-124 264 3     SPACE eurjchem-124 264 4 c. c. PROPN eurjchem-124 264 5     SPACE eurjchem-124 264 6 l l NOUN eurjchem-124 264 7     SPACE eurjchem-124 264 8 . . PUNCT eurjchem-124 265 1 ; ; PUNCT eurjchem-124 265 2     SPACE eurjchem-124 265 3 liu liu PROPN eurjchem-124 265 4 , , PUNCT eurjchem-124 265 5     SPACE eurjchem-124 265 6 l. l. PROPN eurjchem-124 265 7 ; ; PUNCT eurjchem-124 265 8     SPACE eurjchem-124 265 9 zhao zhao PROPN eurjchem-124 265 10 , , PUNCT eurjchem-124 265 11     SPACE eurjchem-124 265 12 j. j. PROPN eurjchem-124 265 13     SPACE eurjchem-124 265 14 l. l. PROPN eurjchem-124 265 15 ; ; PUNCT eurjchem-124 265 16     SPACE eurjchem-124 265 17 wang wang PROPN eurjchem-124 265 18 , , PUNCT eurjchem-124 265 19     SPACE eurjchem-124 265 20 d. d. PROPN eurjchem-124 265 21 ; ; PUNCT eurjchem-124 265 22     SPACE eurjchem-124 265 23 chen chen PROPN eurjchem-124 265 24 , , PUNCT eurjchem-124 265 25     SPACE eurjchem-124 265 26 y. y. PROPN eurjchem-124 265 27     SPACE eurjchem-124 265 28 j. j. PROPN eurjchem-124 265 29     SPACE eurjchem-124 265 30 tetrahedron tetrahedron NOUN eurjchem-124 265 31     SPACE eurjchem-124 265 32 2007 2007 NUM eurjchem-124 265 33 , , PUNCT eurjchem-124 265 34     SPACE eurjchem-124 265 35 18 18 NUM eurjchem-124 265 36 , , PUNCT eurjchem-124 265 37     SPACE eurjchem-124 265 38 455‐463 455‐463 NUM eurjchem-124 265 39 . . PUNCT eurjchem-124 265 40       SPACE eurjchem-124 266 1 [ [ X eurjchem-124 266 2 20 20 NUM eurjchem-124 266 3 ] ] PUNCT eurjchem-124 266 4 . . PUNCT eurjchem-124 267 1 saeed saeed PROPN eurjchem-124 267 2 , , PUNCT eurjchem-124 267 3     SPACE eurjchem-124 267 4 s. s. PROPN eurjchem-124 267 5 ; ; PUNCT eurjchem-124 267 6     SPACE eurjchem-124 267 7 bhatti bhatti ADJ eurjchem-124 267 8 , , PUNCT eurjchem-124 267 9     SPACE eurjchem-124 267 10 m. m. NOUN eurjchem-124 267 11     SPACE eurjchem-124 267 12 h. h. PROPN eurjchem-124 267 13 ; ; PUNCT eurjchem-124 267 14     SPACE eurjchem-124 267 15 yunus yunus PROPN eurjchem-124 267 16 , , PUNCT eurjchem-124 267 17     SPACE eurjchem-124 267 18 u. u. PROPN eurjchem-124 267 19 ; ; PUNCT eurjchem-124 267 20     SPACE eurjchem-124 267 21 jones jone NOUN eurjchem-124 267 22 , , PUNCT eurjchem-124 267 23     SPACE eurjchem-124 267 24 p. p. NOUN eurjchem-124 267 25     SPACE eurjchem-124 267 26 g. g. PROPN eurjchem-124 267 27     SPACE eurjchem-124 267 28 acta acta PROPN eurjchem-124 267 29     SPACE eurjchem-124 267 30 crystallogr crystallogr NOUN eurjchem-124 267 31 . . PUNCT eurjchem-124 267 32     SPACE eurjchem-124 268 1 e e VERB eurjchem-124 268 2     SPACE eurjchem-124 268 3 2008 2008 NUM eurjchem-124 268 4 , , PUNCT eurjchem-124 268 5     SPACE eurjchem-124 268 6 64 64 NUM eurjchem-124 268 7 , , PUNCT eurjchem-124 268 8     SPACE eurjchem-124 268 9 o1369‐o1369 o1369‐o1369 PROPN eurjchem-124 268 10 . . PUNCT eurjchem-124 268 11       SPACE eurjchem-124 268 12 saeed saeed PROPN eurjchem-124 268 13     SPACE eurjchem-124 268 14 et et PROPN eurjchem-124 268 15     SPACE eurjchem-124 268 16 al al PROPN eurjchem-124 268 17 . . PROPN eurjchem-124 268 18     SPACE eurjchem-124 268 19 / / SYM eurjchem-124 268 20     SPACE eurjchem-124 268 21 european european ADJ eurjchem-124 268 22     SPACE eurjchem-124 268 23 journal journal NOUN eurjchem-124 268 24     SPACE eurjchem-124 268 25 of of ADP eurjchem-124 268 26     SPACE eurjchem-124 268 27 chemistry chemistry NOUN eurjchem-124 268 28     SPACE eurjchem-124 268 29 1 1 NUM eurjchem-124 268 30     SPACE eurjchem-124 268 31 ( ( PUNCT eurjchem-124 268 32 3 3 NUM eurjchem-124 268 33 ) ) PUNCT eurjchem-124 268 34     SPACE eurjchem-124 268 35 ( ( PUNCT eurjchem-124 268 36 2010 2010 NUM eurjchem-124 268 37 ) ) PUNCT eurjchem-124 268 38     SPACE eurjchem-124 268 39 221­227 221­227 NUM eurjchem-124 268 40     SPACE eurjchem-124 268 41 227 227 NUM eurjchem-124 268 42     SPACE eurjchem-124 268 43 [ [ X eurjchem-124 268 44 21 21 NUM eurjchem-124 268 45 ] ] PUNCT eurjchem-124 268 46 . . PUNCT eurjchem-124 269 1 d’hooghe d’hooghe PROPN eurjchem-124 269 2 , , PUNCT eurjchem-124 269 3     SPACE eurjchem-124 269 4 m. m. NOUN eurjchem-124 269 5 ; ; PUNCT eurjchem-124 269 6     SPACE eurjchem-124 269 7 waterinckx waterinckx VERB eurjchem-124 269 8 , , PUNCT eurjchem-124 269 9     SPACE eurjchem-124 269 10 a. a. NOUN eurjchem-124 269 11 ; ; PUNCT eurjchem-124 269 12     SPACE eurjchem-124 269 13 de de PRON eurjchem-124 269 14     SPACE eurjchem-124 269 15 kimpe kimpe VERB eurjchem-124 269 16 , , PUNCT eurjchem-124 269 17     SPACE eurjchem-124 269 18 n. n. PROPN eurjchem-124 269 19     SPACE eurjchem-124 269 20 j. j. PROPN eurjchem-124 269 21     SPACE eurjchem-124 269 22 org org PROPN eurjchem-124 269 23 . . PUNCT eurjchem-124 269 24     SPACE eurjchem-124 269 25 chem chem NOUN eurjchem-124 269 26 . . PUNCT eurjchem-124 269 27     SPACE eurjchem-124 269 28 2005 2005 NUM eurjchem-124 269 29 , , PUNCT eurjchem-124 269 30     SPACE eurjchem-124 269 31 70 70 NUM eurjchem-124 269 32 , , PUNCT eurjchem-124 269 33     SPACE eurjchem-124 269 34 227‐232 227‐232 NUM eurjchem-124 269 35 . . PUNCT eurjchem-124 269 36       SPACE eurjchem-124 270 1 [ [ X eurjchem-124 270 2 22 22 NUM eurjchem-124 270 3 ] ] PUNCT eurjchem-124 270 4 . . PUNCT eurjchem-124 271 1 jain jain PROPN eurjchem-124 271 2 , , PUNCT eurjchem-124 271 3     SPACE eurjchem-124 271 4 v. v. ADP eurjchem-124 271 5     SPACE eurjchem-124 271 6 k. k. PROPN eurjchem-124 271 7 ; ; PUNCT eurjchem-124 271 8     SPACE eurjchem-124 271 9 rao rao PROPN eurjchem-124 271 10 , , PUNCT eurjchem-124 271 11     SPACE eurjchem-124 271 12 j. j. PROPN eurjchem-124 271 13     SPACE eurjchem-124 271 14 t. t. PROPN eurjchem-124 271 15     SPACE eurjchem-124 271 16 j. j. PROPN eurjchem-124 271 17     SPACE eurjchem-124 271 18 institute institute PROPN eurjchem-124 271 19     SPACE eurjchem-124 271 20 chem chem NOUN eurjchem-124 271 21 . . PUNCT eurjchem-124 271 22     SPACE eurjchem-124 271 23 ( ( PUNCT eurjchem-124 271 24 india india PROPN eurjchem-124 271 25 ) ) PUNCT eurjchem-124 271 26 , , PUNCT eurjchem-124 271 27     SPACE eurjchem-124 271 28 2003 2003 NUM eurjchem-124 271 29 , , PUNCT eurjchem-124 271 30     SPACE eurjchem-124 271 31 75 75 NUM eurjchem-124 271 32 , , PUNCT eurjchem-124 271 33     SPACE eurjchem-124 271 34 24‐28 24‐28 NUM eurjchem-124 271 35 . . PUNCT eurjchem-124 271 36       SPACE eurjchem-124 272 1 [ [ X eurjchem-124 272 2 23 23 NUM eurjchem-124 272 3 ] ] PUNCT eurjchem-124 272 4 . . PUNCT eurjchem-124 273 1 lakhan lakhan PROPN eurjchem-124 273 2 , , PUNCT eurjchem-124 273 3     SPACE eurjchem-124 273 4 r. r. PROPN eurjchem-124 273 5 ; ; PUNCT eurjchem-124 273 6     SPACE eurjchem-124 273 7 ral ral ADJ eurjchem-124 273 8 , , PUNCT eurjchem-124 273 9     SPACE eurjchem-124 273 10 b. b. PROPN eurjchem-124 273 11     SPACE eurjchem-124 273 12 j. j. PROPN eurjchem-124 273 13     SPACE eurjchem-124 273 14 j. j. PROPN eurjchem-124 273 15     SPACE eurjchem-124 273 16 chem chem NOUN eurjchem-124 273 17 . . PUNCT eurjchem-124 273 18     SPACE eurjchem-124 274 1 eng eng PROPN eurjchem-124 274 2 . . PUNCT eurjchem-124 274 3     SPACE eurjchem-124 274 4 data data PROPN eurjchem-124 274 5     SPACE eurjchem-124 274 6 1986 1986 NUM eurjchem-124 274 7 , , PUNCT eurjchem-124 274 8     SPACE eurjchem-124 274 9 31 31 NUM eurjchem-124 274 10 , , PUNCT eurjchem-124 274 11     SPACE eurjchem-124 274 12 501‐508 501‐508 NUM eurjchem-124 274 13 . . PUNCT eurjchem-124 274 14       SPACE eurjchem-124 275 1 [ [ X eurjchem-124 275 2 24 24 NUM eurjchem-124 275 3 ] ] PUNCT eurjchem-124 275 4 . . PUNCT eurjchem-124 276 1 saeed saeed PROPN eurjchem-124 276 2 , , PUNCT eurjchem-124 276 3     SPACE eurjchem-124 276 4 a. a. NOUN eurjchem-124 276 5 ; ; PUNCT eurjchem-124 276 6     SPACE eurjchem-124 276 7 parvez parvez ADJ eurjchem-124 276 8 , , PUNCT eurjchem-124 276 9     SPACE eurjchem-124 276 10 m. m. NOUN eurjchem-124 276 11     SPACE eurjchem-124 276 12 cent cent NOUN eurjchem-124 276 13 . . PUNCT eurjchem-124 276 14     SPACE eurjchem-124 276 15 eur eur PROPN eurjchem-124 276 16 . . PUNCT eurjchem-124 276 17     SPACE eurjchem-124 276 18 j. j. PROPN eurjchem-124 276 19     SPACE eurjchem-124 276 20 chem chem NOUN eurjchem-124 276 21 . . PUNCT eurjchem-124 276 22     SPACE eurjchem-124 276 23 2005 2005 NUM eurjchem-124 276 24 , , PUNCT eurjchem-124 276 25     SPACE eurjchem-124 276 26 3(4 3(4 NUM eurjchem-124 276 27 ) ) PUNCT eurjchem-124 276 28 , , PUNCT eurjchem-124 276 29     SPACE eurjchem-124 276 30 780‐791 780‐791 NOUN eurjchem-124 276 31 . . PUNCT eurjchem-124 276 32       SPACE eurjchem-124 277 1 [ [ X eurjchem-124 277 2 25 25 NUM eurjchem-124 277 3 ] ] PUNCT eurjchem-124 277 4 . . PUNCT eurjchem-124 277 5 nie nie PROPN eurjchem-124 277 6 , , PUNCT eurjchem-124 277 7     SPACE eurjchem-124 277 8 l. l. PROPN eurjchem-124 277 9 ; ; PUNCT eurjchem-124 277 10     SPACE eurjchem-124 277 11 li li PROPN eurjchem-124 277 12 , , PUNCT eurjchem-124 277 13     SPACE eurjchem-124 277 14 z. z. PROPN eurjchem-124 277 15 ; ; PUNCT eurjchem-124 277 16     SPACE eurjchem-124 277 17 han han PROPN eurjchem-124 277 18 , , PUNCT eurjchem-124 277 19     SPACE eurjchem-124 277 20 j. j. PROPN eurjchem-124 277 21 ; ; PUNCT eurjchem-124 277 22     SPACE eurjchem-124 277 23 zhang zhang PROPN eurjchem-124 277 24 , , PUNCT eurjchem-124 277 25     SPACE eurjchem-124 277 26 x. x. NOUN eurjchem-124 277 27 ; ; PUNCT eurjchem-124 277 28     SPACE eurjchem-124 277 29 yang yang PROPN eurjchem-124 277 30 , , PUNCT eurjchem-124 277 31     SPACE eurjchem-124 277 32 r. r. PROPN eurjchem-124 277 33 ; ; PUNCT eurjchem-124 277 34     SPACE eurjchem-124 277 35 liu liu PROPN eurjchem-124 277 36 , , PUNCT eurjchem-124 277 37     SPACE eurjchem-124 277 38 w. w. PROPN eurjchem-124 277 39     SPACE eurjchem-124 277 40 x. x. PROPN eurjchem-124 277 41 ; ; PUNCT eurjchem-124 277 42     SPACE eurjchem-124 277 43 wu wu PROPN eurjchem-124 277 44 , , PUNCT eurjchem-124 277 45     SPACE eurjchem-124 277 46 f. f. PROPN eurjchem-124 277 47     SPACE eurjchem-124 277 48 y. y. PROPN eurjchem-124 277 49 ; ; PUNCT eurjchem-124 277 50     SPACE eurjchem-124 277 51 xie xie PROPN eurjchem-124 277 52 , , PUNCT eurjchem-124 277 53     SPACE eurjchem-124 277 54 j. j. PROPN eurjchem-124 277 55     SPACE eurjchem-124 277 56 w. w. PROPN eurjchem-124 277 57 ; ; PUNCT eurjchem-124 277 58     SPACE eurjchem-124 277 59 zhao zhao NOUN eurjchem-124 277 60     SPACE eurjchem-124 277 61 , , PUNCT eurjchem-124 277 62     SPACE eurjchem-124 277 63 y. y. NOUN eurjchem-124 277 64     SPACE eurjchem-124 277 65 f. f. PROPN eurjchem-124 277 66 ; ; PUNCT eurjchem-124 277 67     SPACE eurjchem-124 277 68 jiang jiang PROPN eurjchem-124 277 69 , , PUNCT eurjchem-124 277 70     SPACE eurjchem-124 277 71 y. y. PROPN eurjchem-124 277 72     SPACE eurjchem-124 277 73 b. b. PROPN eurjchem-124 277 74     SPACE eurjchem-124 277 75 j. j. PROPN eurjchem-124 277 76     SPACE eurjchem-124 277 77 org org PROPN eurjchem-124 277 78 . . PUNCT eurjchem-124 277 79     SPACE eurjchem-124 277 80 chem chem NOUN eurjchem-124 277 81 . . PUNCT eurjchem-124 277 82     SPACE eurjchem-124 277 83 2004 2004 NUM eurjchem-124 277 84 , , PUNCT eurjchem-124 277 85     SPACE eurjchem-124 277 86 69 69 NUM eurjchem-124 277 87 , , PUNCT eurjchem-124 277 88     SPACE eurjchem-124 277 89 6449‐6454 6449‐6454 NUM eurjchem-124 277 90 . . PUNCT eurjchem-124 277 91       SPACE eurjchem-124 278 1 [ [ X eurjchem-124 278 2 26 26 NUM eurjchem-124 278 3 ] ] PUNCT eurjchem-124 278 4 . . PUNCT eurjchem-124 279 1 park park PROPN eurjchem-124 279 2 , , PUNCT eurjchem-124 279 3     SPACE eurjchem-124 279 4 h. h. PROPN eurjchem-124 279 5 ; ; PUNCT eurjchem-124 279 6     SPACE eurjchem-124 279 7 choi choi NOUN eurjchem-124 279 8 , , PUNCT eurjchem-124 279 9     SPACE eurjchem-124 279 10 j. j. PROPN eurjchem-124 279 11 ; ; PUNCT eurjchem-124 279 12     SPACE eurjchem-124 279 13 choi choi NOUN eurjchem-124 279 14 , , PUNCT eurjchem-124 279 15     SPACE eurjchem-124 279 16 s. s. PROPN eurjchem-124 279 17 ; ; PUNCT eurjchem-124 279 18     SPACE eurjchem-124 279 19 park park NOUN eurjchem-124 279 20 , , PUNCT eurjchem-124 279 21     SPACE eurjchem-124 279 22 m. m. NOUN eurjchem-124 279 23 ; ; PUNCT eurjchem-124 279 24     SPACE eurjchem-124 279 25 lee lee PROPN eurjchem-124 279 26 , , PUNCT eurjchem-124 279 27     SPACE eurjchem-124 279 28 j. j. PROPN eurjchem-124 279 29 ; ; PUNCT eurjchem-124 279 30     SPACE eurjchem-124 279 31 suh suh PROPN eurjchem-124 279 32 , , PUNCT eurjchem-124 279 33     SPACE eurjchem-124 279 34 j. j. PROPN eurjchem-124 279 35     SPACE eurjchem-124 279 36 y. y. PROPN eurjchem-124 279 37 ; ; PUNCT eurjchem-124 279 38     SPACE eurjchem-124 279 39 cho cho PROPN eurjchem-124 279 40 , , PUNCT eurjchem-124 279 41     SPACE eurjchem-124 279 42 h. h. PROPN eurjchem-124 279 43 ; ; PUNCT eurjchem-124 279 44     SPACE eurjchem-124 279 45 oh oh INTJ eurjchem-124 279 46 , , PUNCT eurjchem-124 279 47     SPACE eurjchem-124 279 48 h. h. PROPN eurjchem-124 279 49     SPACE eurjchem-124 279 50 u. u. PROPN eurjchem-124 279 51 ; ; PUNCT eurjchem-124 279 52     SPACE eurjchem-124 279 53 lee lee PROPN eurjchem-124 279 54 , , PUNCT eurjchem-124 279 55     SPACE eurjchem-124 279 56 j. j. PROPN eurjchem-124 279 57 ; ; PUNCT eurjchem-124 279 58     SPACE eurjchem-124 279 59 kang kang PROPN eurjchem-124 279 60 , , PUNCT eurjchem-124 279 61     SPACE eurjchem-124 279 62 s. s. PROPN eurjchem-124 279 63     SPACE eurjchem-124 279 64 u. u. PROPN eurjchem-124 279 65 ; ; PUNCT eurjchem-124 279 66     SPACE eurjchem-124 279 67 lee lee PROPN eurjchem-124 279 68 , , PUNCT eurjchem-124 279 69     SPACE eurjchem-124 279 70 j. j. PROPN eurjchem-124 279 71 ; ; PUNCT eurjchem-124 279 72     SPACE eurjchem-124 279 73 kim kim PROPN eurjchem-124 279 74 , , PUNCT eurjchem-124 279 75     SPACE eurjchem-124 279 76 h. h. PROPN eurjchem-124 279 77     SPACE eurjchem-124 279 78 d. d. PROPN eurjchem-124 279 79 ; ; PUNCT eurjchem-124 279 80     SPACE eurjchem-124 279 81 park park NOUN eurjchem-124 279 82 , , PUNCT eurjchem-124 279 83     SPACE eurjchem-124 279 84 y. y. PROPN eurjchem-124 279 85     SPACE eurjchem-124 279 86 h. h. PROPN eurjchem-124 279 87 ; ; PUNCT eurjchem-124 279 88     SPACE eurjchem-124 279 89 jeong jeong PROPN eurjchem-124 279 90 , , PUNCT eurjchem-124 279 91     SPACE eurjchem-124 279 92 y. y. NOUN eurjchem-124 279 93     SPACE eurjchem-124 279 94 s. s. PROPN eurjchem-124 279 95 ; ; PUNCT eurjchem-124 279 96     SPACE eurjchem-124 279 97 j. j. PROPN eurjchem-124 279 98     SPACE eurjchem-124 279 99 k. k. PROPN eurjchem-124 279 100     SPACE eurjchem-124 279 101 choi choi NOUN eurjchem-124 279 102 , , PUNCT eurjchem-124 279 103     SPACE eurjchem-124 279 104 j. j. PROPN eurjchem-124 279 105     SPACE eurjchem-124 279 106 k. k. PROPN eurjchem-124 279 107 ; ; PUNCT eurjchem-124 279 108     SPACE eurjchem-124 279 109 jew jew PROPN eurjchem-124 279 110 , , PUNCT eurjchem-124 279 111     SPACE eurjchem-124 279 112 j. j. PROPN eurjchem-124 279 113     SPACE eurjchem-124 279 114 s. s. PROPN eurjchem-124 279 115     SPACE eurjchem-124 279 116 bioorg bioorg PROPN eurjchem-124 279 117 . . PUNCT eurjchem-124 279 118     SPACE eurjchem-124 279 119 med med PROPN eurjchem-124 279 120 . . PUNCT eurjchem-124 279 121     SPACE eurjchem-124 279 122 chem chem NOUN eurjchem-124 279 123 . . PUNCT eurjchem-124 279 124     SPACE eurjchem-124 280 1 lett lett PROPN eurjchem-124 280 2 . . PUNCT eurjchem-124 280 3     SPACE eurjchem-124 281 1 2004 2004 NUM eurjchem-124 281 2 , , PUNCT eurjchem-124 281 3     SPACE eurjchem-124 281 4 14 14 NUM eurjchem-124 281 5 , , PUNCT eurjchem-124 281 6     SPACE eurjchem-124 281 7 787‐791 787‐791 NUM eurjchem-124 281 8 . . PUNCT eurjchem-124 281 9       SPACE eurjchem-124 282 1 [ [ X eurjchem-124 282 2 27 27 NUM eurjchem-124 282 3 ] ] PUNCT eurjchem-124 282 4 . . PUNCT eurjchem-124 283 1 maquoi maquoi PROPN eurjchem-124 283 2 , , PUNCT eurjchem-124 283 3     SPACE eurjchem-124 283 4 e. e. PROPN eurjchem-124 283 5 ; ; PUNCT eurjchem-124 283 6     SPACE eurjchem-124 283 7 sounni sounni VERB eurjchem-124 283 8 , , PUNCT eurjchem-124 283 9     SPACE eurjchem-124 283 10 n. n. PROPN eurjchem-124 283 11     SPACE eurjchem-124 283 12 e. e. PROPN eurjchem-124 283 13 ; ; PUNCT eurjchem-124 283 14     SPACE eurjchem-124 283 15 devy devy NOUN eurjchem-124 283 16 , , PUNCT eurjchem-124 283 17     SPACE eurjchem-124 283 18 l. l. PROPN eurjchem-124 283 19 ; ; PUNCT eurjchem-124 283 20     SPACE eurjchem-124 283 21 olivier olivier NOUN eurjchem-124 283 22 , , PUNCT eurjchem-124 283 23     SPACE eurjchem-124 283 24 f. f. PROPN eurjchem-124 283 25 ; ; PUNCT eurjchem-124 283 26     SPACE eurjchem-124 283 27 frankenne frankenne NOUN eurjchem-124 283 28 , , PUNCT eurjchem-124 283 29     SPACE eurjchem-124 283 30 f. f. PROPN eurjchem-124 283 31 ; ; PUNCT eurjchem-124 283 32     SPACE eurjchem-124 283 33 krell krell PROPN eurjchem-124 283 34 , , PUNCT eurjchem-124 283 35     SPACE eurjchem-124 283 36 h. h. PROPN eurjchem-124 283 37     SPACE eurjchem-124 283 38 w. w. PROPN eurjchem-124 283 39 ; ; PUNCT eurjchem-124 283 40     SPACE eurjchem-124 283 41 grams gram NOUN eurjchem-124 283 42 , , PUNCT eurjchem-124 283 43     SPACE eurjchem-124 283 44 f. f. PROPN eurjchem-124 283 45 ; ; PUNCT eurjchem-124 283 46     SPACE eurjchem-124 283 47 foidart foidart NOUN eurjchem-124 283 48 , , PUNCT eurjchem-124 283 49     SPACE eurjchem-124 283 50 j. j. PROPN eurjchem-124 283 51     SPACE eurjchem-124 283 52 m. m. NOUN eurjchem-124 283 53     SPACE eurjchem-124 283 54 agnes agnes PROPN eurjchem-124 283 55 . . PUNCT eurjchem-124 283 56     SPACE eurjchem-124 283 57 noel noel PROPN eurjchem-124 283 58 . . PUNCT eurjchem-124 283 59     SPACE eurjchem-124 283 60 clin clin PROPN eurjchem-124 283 61 . . PUNCT eurjchem-124 283 62     SPACE eurjchem-124 283 63 cancer cancer NOUN eurjchem-124 283 64     SPACE eurjchem-124 283 65 res re NOUN eurjchem-124 283 66 . . PUNCT eurjchem-124 283 67     SPACE eurjchem-124 283 68 2004 2004 NUM eurjchem-124 283 69 , , PUNCT eurjchem-124 283 70     SPACE eurjchem-124 283 71 10 10 NUM eurjchem-124 283 72 , , PUNCT eurjchem-124 283 73     SPACE eurjchem-124 283 74 4038‐4042 4038‐4042 NUM eurjchem-124 283 75 . . PUNCT eurjchem-124 283 76       SPACE eurjchem-124 284 1 [ [ X eurjchem-124 284 2 28 28 NUM eurjchem-124 284 3 ] ] PUNCT eurjchem-124 284 4 . . PUNCT eurjchem-124 284 5 merck merck PROPN eurjchem-124 284 6     SPACE eurjchem-124 284 7 index index NOUN eurjchem-124 284 8 , , PUNCT eurjchem-124 284 9     SPACE eurjchem-124 284 10 13th 13th NOUN eurjchem-124 284 11     SPACE eurjchem-124 284 12 edition edition NOUN eurjchem-124 284 13 , , PUNCT eurjchem-124 284 14     SPACE eurjchem-124 284 15 merck merck PROPN eurjchem-124 284 16     SPACE eurjchem-124 284 17 & & CCONJ eurjchem-124 284 18 co co NOUN eurjchem-124 284 19 , , PUNCT eurjchem-124 284 20     SPACE eurjchem-124 284 21 inc inc PROPN eurjchem-124 284 22 . . PROPN eurjchem-124 284 23 , , PUNCT eurjchem-124 284 24     SPACE eurjchem-124 284 25 whitehouse whitehouse NOUN eurjchem-124 284 26     SPACE eurjchem-124 284 27 station station NOUN eurjchem-124 284 28 , , PUNCT eurjchem-124 284 29     SPACE eurjchem-124 284 30 new new ADJ eurjchem-124 284 31     SPACE eurjchem-124 284 32 jersery jersery NOUN eurjchem-124 284 33 , , PUNCT eurjchem-124 284 34     SPACE eurjchem-124 284 35 2001 2001 NUM eurjchem-124 284 36 . . PUNCT eurjchem-124 284 37       SPACE eurjchem-124 285 1 [ [ X eurjchem-124 285 2 29 29 NUM eurjchem-124 285 3 ] ] PUNCT eurjchem-124 285 4 . . PUNCT eurjchem-124 286 1 varbanov varbanov PROPN eurjchem-124 286 2 , , PUNCT eurjchem-124 286 3     SPACE eurjchem-124 286 4 s. s. PROPN eurjchem-124 286 5 ; ; PUNCT eurjchem-124 286 6     SPACE eurjchem-124 286 7 tosheva tosheva PROPN eurjchem-124 286 8 , , PUNCT eurjchem-124 286 9     SPACE eurjchem-124 286 10 t. t. PROPN eurjchem-124 286 11 ; ; PUNCT eurjchem-124 286 12     SPACE eurjchem-124 286 13 russeva russeva NOUN eurjchem-124 286 14 , , PUNCT eurjchem-124 286 15     SPACE eurjchem-124 286 16 e. e. PROPN eurjchem-124 286 17     SPACE eurjchem-124 286 18 phosphorus phosphorus NOUN eurjchem-124 286 19     SPACE eurjchem-124 286 20 sulfur sulfur NOUN eurjchem-124 286 21     SPACE eurjchem-124 286 22 silicon silicon NOUN eurjchem-124 286 23     SPACE eurjchem-124 286 24 relat relat NOUN eurjchem-124 286 25 . . PUNCT eurjchem-124 286 26     SPACE eurjchem-124 287 1 elem elem NOUN eurjchem-124 287 2 . . PUNCT eurjchem-124 287 3     SPACE eurjchem-124 288 1 1997 1997 NUM eurjchem-124 288 2 , , PUNCT eurjchem-124 288 3     SPACE eurjchem-124 288 4 127 127 NUM eurjchem-124 288 5 , , PUNCT eurjchem-124 288 6     SPACE eurjchem-124 288 7 27‐35 27‐35 NUM eurjchem-124 288 8 . . PUNCT eurjchem-124 288 9       SPACE eurjchem-124 289 1 [ [ X eurjchem-124 289 2 30 30 NUM eurjchem-124 289 3 ] ] PUNCT eurjchem-124 289 4 . . PUNCT eurjchem-124 290 1 sheldrick sheldrick VERB eurjchem-124 290 2 , , PUNCT eurjchem-124 290 3     SPACE eurjchem-124 290 4 g. g. NOUN eurjchem-124 290 5     SPACE eurjchem-124 290 6 m. m. NOUN eurjchem-124 290 7     SPACE eurjchem-124 290 8 acta acta PROPN eurjchem-124 290 9     SPACE eurjchem-124 290 10 crystallogr crystallogr NOUN eurjchem-124 290 11 . . PUNCT eurjchem-124 290 12     SPACE eurjchem-124 291 1 a a DET eurjchem-124 291 2     SPACE eurjchem-124 291 3 2008 2008 NUM eurjchem-124 291 4 , , PUNCT eurjchem-124 291 5     SPACE eurjchem-124 291 6 64 64 NUM eurjchem-124 291 7 , , PUNCT eurjchem-124 291 8     SPACE eurjchem-124 291 9 112‐122 112‐122 NUM eurjchem-124 291 10 . . PUNCT eurjchem-124 291 11       SPACE eurjchem-124 292 1 [ [ X eurjchem-124 292 2 31 31 NUM eurjchem-124 292 3 ] ] PUNCT eurjchem-124 292 4 . . PUNCT eurjchem-124 292 5 national national PROPN eurjchem-124 292 6     SPACE eurjchem-124 292 7 committee committee NOUN eurjchem-124 292 8     SPACE eurjchem-124 292 9 for for ADP eurjchem-124 292 10     SPACE eurjchem-124 292 11 clinical clinical ADJ eurjchem-124 292 12     SPACE eurjchem-124 292 13 laboratory laboratory NOUN eurjchem-124 292 14     SPACE eurjchem-124 292 15 standards standard NOUN eurjchem-124 292 16 , , PUNCT eurjchem-124 292 17     SPACE eurjchem-124 292 18 m7‐a4 m7‐a4 X eurjchem-124 292 19     SPACE eurjchem-124 292 20 ( ( PUNCT eurjchem-124 292 21 nccls nccls NOUN eurjchem-124 292 22 , , PUNCT eurjchem-124 292 23     SPACE eurjchem-124 292 24 viallanova viallanova NOUN eurjchem-124 292 25 , , PUNCT eurjchem-124 292 26     SPACE eurjchem-124 292 27 pa pa PROPN eurjchem-124 292 28 , , PUNCT eurjchem-124 292 29     SPACE eurjchem-124 292 30 usa usa PROPN eurjchem-124 292 31 , , PUNCT eurjchem-124 292 32     SPACE eurjchem-124 292 33 1997 1997 NUM eurjchem-124 292 34 ) ) PUNCT eurjchem-124 292 35 . . PUNCT eurjchem-124 292 36       SPACE eurjchem-124 293 1 [ [ X eurjchem-124 293 2 32 32 NUM eurjchem-124 293 3 ] ] PUNCT eurjchem-124 293 4 . . PUNCT eurjchem-124 293 5 national national PROPN eurjchem-124 293 6     SPACE eurjchem-124 293 7 committee committee NOUN eurjchem-124 293 8     SPACE eurjchem-124 293 9 for for ADP eurjchem-124 293 10     SPACE eurjchem-124 293 11 clinical clinical ADJ eurjchem-124 293 12     SPACE eurjchem-124 293 13 laboratory laboratory NOUN eurjchem-124 293 14     SPACE eurjchem-124 293 15 standards standard NOUN eurjchem-124 293 16 , , PUNCT eurjchem-124 293 17     SPACE eurjchem-124 293 18 m27‐a2 m27‐a2 PROPN eurjchem-124 293 19     SPACE eurjchem-124 293 20 ( ( PUNCT eurjchem-124 293 21 nccls nccls PROPN eurjchem-124 293 22 , , PUNCT eurjchem-124 293 23     SPACE eurjchem-124 293 24 wayne wayne PROPN eurjchem-124 293 25 , , PUNCT eurjchem-124 293 26     SPACE eurjchem-124 293 27 pa pa PROPN eurjchem-124 293 28 , , PUNCT eurjchem-124 293 29     SPACE eurjchem-124 293 30 usa usa PROPN eurjchem-124 293 31 , , PUNCT eurjchem-124 293 32     SPACE eurjchem-124 293 33 2002 2002 NUM eurjchem-124 293 34 ) ) PUNCT eurjchem-124 293 35 . . PUNCT eurjchem-124 293 36       SPACE eurjchem-124 294 1 [ [ X eurjchem-124 294 2 33 33 NUM eurjchem-124 294 3 ] ] PUNCT eurjchem-124 294 4 . . PUNCT eurjchem-124 295 1 saeed saeed PROPN eurjchem-124 295 2 , , PUNCT eurjchem-124 295 3     SPACE eurjchem-124 295 4 s. s. PROPN eurjchem-124 295 5 ; ; PUNCT eurjchem-124 295 6     SPACE eurjchem-124 295 7 rashid rashid PROPN eurjchem-124 295 8 , , PUNCT eurjchem-124 295 9     SPACE eurjchem-124 295 10 n n CCONJ eurjchem-124 295 11 ; ; PUNCT eurjchem-124 295 12     SPACE eurjchem-124 295 13 jones jone NOUN eurjchem-124 295 14 , , PUNCT eurjchem-124 295 15     SPACE eurjchem-124 295 16 p. p. NOUN eurjchem-124 295 17     SPACE eurjchem-124 295 18 g. g. PROPN eurjchem-124 295 19 ; ; PUNCT eurjchem-124 295 20     SPACE eurjchem-124 295 21 hussain hussain PROPN eurjchem-124 295 22 , , PUNCT eurjchem-124 295 23     SPACE eurjchem-124 295 24 r. r. PROPN eurjchem-124 295 25 ; ; PUNCT eurjchem-124 295 26     SPACE eurjchem-124 295 27 bhatti bhatti ADJ eurjchem-124 295 28 , , PUNCT eurjchem-124 295 29     SPACE eurjchem-124 295 30 m. m. NOUN eurjchem-124 295 31     SPACE eurjchem-124 295 32 h. h. PROPN eurjchem-124 295 33     SPACE eurjchem-124 295 34 cent cent NOUN eurjchem-124 295 35 . . PUNCT eurjchem-124 295 36     SPACE eurjchem-124 295 37 eur eur PROPN eurjchem-124 295 38 . . PUNCT eurjchem-124 295 39     SPACE eurjchem-124 295 40 j. j. PROPN eurjchem-124 295 41     SPACE eurjchem-124 295 42 chem chem NOUN eurjchem-124 295 43 . . PUNCT eurjchem-124 295 44     SPACE eurjchem-124 295 45 2010 2010 NUM eurjchem-124 295 46 , , PUNCT eurjchem-124 295 47     SPACE eurjchem-124 295 48 8(3 8(3 NUM eurjchem-124 295 49 ) ) PUNCT eurjchem-124 295 50 , , PUNCT eurjchem-124 295 51     SPACE eurjchem-124 295 52 550‐558 550‐558 NUM eurjchem-124 295 53 . . PUNCT eurjchem-124 295 54       SPACE eurjchem-124 296 1 [ [ X eurjchem-124 296 2 34 34 NUM eurjchem-124 296 3 ] ] PUNCT eurjchem-124 296 4 . . PUNCT eurjchem-124 297 1 saeed saeed PROPN eurjchem-124 297 2 , , PUNCT eurjchem-124 297 3     SPACE eurjchem-124 297 4 s. s. PROPN eurjchem-124 297 5 ; ; PUNCT eurjchem-124 297 6     SPACE eurjchem-124 297 7 rashid rashid PROPN eurjchem-124 297 8 , , PUNCT eurjchem-124 297 9     SPACE eurjchem-124 297 10 n. n. NOUN eurjchem-124 297 11 ; ; PUNCT eurjchem-124 297 12     SPACE eurjchem-124 297 13 wong wong PROPN eurjchem-124 297 14 , , PUNCT eurjchem-124 297 15     SPACE eurjchem-124 297 16 w. w. PROPN eurjchem-124 297 17     SPACE eurjchem-124 297 18 t. t. PROPN eurjchem-124 297 19     SPACE eurjchem-124 297 20 acta acta PROPN eurjchem-124 297 21     SPACE eurjchem-124 297 22 crystallogr crystallogr PROPN eurjchem-124 297 23 . . PUNCT eurjchem-124 297 24     SPACE eurjchem-124 298 1 e e VERB eurjchem-124 298 2     SPACE eurjchem-124 298 3 2010 2010 NUM eurjchem-124 298 4 , , PUNCT eurjchem-124 298 5     SPACE eurjchem-124 298 6 66 66 NUM eurjchem-124 298 7 , , PUNCT eurjchem-124 298 8     SPACE eurjchem-124 298 9 o980‐ o980‐ PROPN eurjchem-124 298 10 o980 o980 PROPN eurjchem-124 298 11 . . PUNCT eurjchem-124 298 12       SPACE eurjchem-124 299 1 [ [ X eurjchem-124 299 2 35 35 NUM eurjchem-124 299 3 ] ] PUNCT eurjchem-124 299 4 . . PUNCT eurjchem-124 300 1 sacht sacht PROPN eurjchem-124 300 2 , , PUNCT eurjchem-124 300 3     SPACE eurjchem-124 300 4 c. c. NOUN eurjchem-124 300 5 ; ; PUNCT eurjchem-124 300 6     SPACE eurjchem-124 300 7 datt datt PROPN eurjchem-124 300 8 , , PUNCT eurjchem-124 300 9     SPACE eurjchem-124 300 10 m. m. NOUN eurjchem-124 300 11     SPACE eurjchem-124 300 12 s. s. PROPN eurjchem-124 300 13     SPACE eurjchem-124 300 14 polyhedron polyhedron NOUN eurjchem-124 300 15     SPACE eurjchem-124 300 16 2000 2000 NUM eurjchem-124 300 17 , , PUNCT eurjchem-124 300 18     SPACE eurjchem-124 300 19 19 19 NUM eurjchem-124 300 20 , , PUNCT eurjchem-124 300 21     SPACE eurjchem-124 300 22 1347‐1355 1347‐1355 NUM eurjchem-124 300 23 . . PUNCT eurjchem-124 300 24       SPACE eurjchem-124 301 1 [ [ X eurjchem-124 301 2 36 36 NUM eurjchem-124 301 3 ] ] PUNCT eurjchem-124 301 4 . . PUNCT eurjchem-124 302 1 zhang zhang PROPN eurjchem-124 302 2 , , PUNCT eurjchem-124 302 3     SPACE eurjchem-124 302 4 y. y. NOUN eurjchem-124 302 5     SPACE eurjchem-124 302 6 m. m. NOUN eurjchem-124 302 7 ; ; PUNCT eurjchem-124 302 8     SPACE eurjchem-124 302 9 wei wei PROPN eurjchem-124 302 10 , , PUNCT eurjchem-124 302 11     SPACE eurjchem-124 302 12 t. t. PROPN eurjchem-124 302 13     SPACE eurjchem-124 302 14 b. b. PROPN eurjchem-124 302 15 ; ; PUNCT eurjchem-124 302 16     SPACE eurjchem-124 302 17 xian xian NOUN eurjchem-124 302 18 , , PUNCT eurjchem-124 302 19     SPACE eurjchem-124 302 20 l. l. PROPN eurjchem-124 302 21 ; ; PUNCT eurjchem-124 302 22     SPACE eurjchem-124 302 23 gao gao PROPN eurjchem-124 302 24 , , PUNCT eurjchem-124 302 25     SPACE eurjchem-124 302 26 l. l. PROPN eurjchem-124 302 27     SPACE eurjchem-124 302 28 m. m. NOUN eurjchem-124 302 29     SPACE eurjchem-124 302 30 phosphorus phosphorus NOUN eurjchem-124 302 31     SPACE eurjchem-124 302 32 sulfur sulfur NOUN eurjchem-124 302 33     SPACE eurjchem-124 302 34 silicon silicon NOUN eurjchem-124 302 35     SPACE eurjchem-124 302 36 relat relat NOUN eurjchem-124 302 37 . . PUNCT eurjchem-124 302 38     SPACE eurjchem-124 302 39 elem elem NOUN eurjchem-124 302 40 . . PUNCT eurjchem-124 302 41     SPACE eurjchem-124 302 42 2007 2007 NUM eurjchem-124 302 43 , , PUNCT eurjchem-124 302 44     SPACE eurjchem-124 302 45 179 179 NUM eurjchem-124 302 46 , , PUNCT eurjchem-124 302 47     SPACE eurjchem-124 302 48 2007‐2013 2007‐2013 NOUN eurjchem-124 302 49 . . PUNCT eurjchem-124 302 50       SPACE eurjchem-124 303 1 [ [ X eurjchem-124 303 2 37 37 NUM eurjchem-124 303 3 ] ] PUNCT eurjchem-124 303 4 . . PUNCT eurjchem-124 304 1 allen allen PROPN eurjchem-124 304 2 , , PUNCT eurjchem-124 304 3     SPACE eurjchem-124 304 4 f. f. PROPN eurjchem-124 304 5     SPACE eurjchem-124 304 6 h. h. PROPN eurjchem-124 304 7     SPACE eurjchem-124 304 8 acta acta PROPN eurjchem-124 304 9     SPACE eurjchem-124 304 10 crystallogr crystallogr NOUN eurjchem-124 304 11 . . PUNCT eurjchem-124 304 12     SPACE eurjchem-124 305 1 b b X eurjchem-124 305 2     SPACE eurjchem-124 305 3 2002 2002 NUM eurjchem-124 305 4 , , PUNCT eurjchem-124 305 5     SPACE eurjchem-124 305 6 58 58 NUM eurjchem-124 305 7 , , PUNCT eurjchem-124 305 8     SPACE eurjchem-124 305 9 380‐388 380‐388 NUM eurjchem-124 305 10 . . PUNCT eurjchem-124 305 11       SPACE eurjchem-124 306 1 [ [ X eurjchem-124 306 2 38 38 NUM eurjchem-124 306 3 ] ] PUNCT eurjchem-124 306 4 . . PUNCT eurjchem-124 307 1 hoey hoey PROPN eurjchem-124 307 2 , , PUNCT eurjchem-124 307 3     SPACE eurjchem-124 307 4 a. a. NOUN eurjchem-124 307 5     SPACE eurjchem-124 307 6 j. j. PROPN eurjchem-124 307 7 ; ; PUNCT eurjchem-124 307 8     SPACE eurjchem-124 307 9 jackson jackson PROPN eurjchem-124 307 10 , , PUNCT eurjchem-124 307 11     SPACE eurjchem-124 307 12 c. c. PROPN eurjchem-124 307 13     SPACE eurjchem-124 307 14 m. m. NOUN eurjchem-124 307 15 ; ; PUNCT eurjchem-124 307 16     SPACE eurjchem-124 307 17 pegg pegg NOUN eurjchem-124 307 18 , , PUNCT eurjchem-124 307 19     SPACE eurjchem-124 307 20 g. g. PROPN eurjchem-124 307 21     SPACE eurjchem-124 307 22 g. g. PROPN eurjchem-124 307 23 ; ; PUNCT eurjchem-124 307 24     SPACE eurjchem-124 307 25 sillence sillence NOUN eurjchem-124 307 26 , , PUNCT eurjchem-124 307 27     SPACE eurjchem-124 307 28 m. m. NOUN eurjchem-124 307 29     SPACE eurjchem-124 307 30 n. n. PROPN eurjchem-124 307 31     SPACE eurjchem-124 307 32 br br PROPN eurjchem-124 307 33 . . PUNCT eurjchem-124 307 34     SPACE eurjchem-124 307 35 j. j. PROPN eurjchem-124 307 36     SPACE eurjchem-124 307 37 pharmacol pharmacol PROPN eurjchem-124 307 38 . . PUNCT eurjchem-124 307 39     SPACE eurjchem-124 307 40 1996 1996 NUM eurjchem-124 307 41 , , PUNCT eurjchem-124 307 42     SPACE eurjchem-124 307 43 119 119 NUM eurjchem-124 307 44 , , PUNCT eurjchem-124 307 45     SPACE eurjchem-124 307 46 564‐571 564‐571 NUM eurjchem-124 307 47 . . PUNCT eurjchem-124 307 48     SPACE