id	sid	tid	token	lemma	pos
eurjchem-125	1	1	untitled	untitle	VERB
eurjchem-125	1	2	european	european	PROPN
eurjchem-125	1	3	journal	journal	PROPN
eurjchem-125	1	4	of	of	ADP
eurjchem-125	1	5	chemistry	chemistry	NOUN
eurjchem-125	1	6	2	2	NUM
eurjchem-125	1	7	(	(	PUNCT
eurjchem-125	1	8	1	1	NUM
eurjchem-125	1	9	)	)	PUNCT
eurjchem-125	1	10	(	(	PUNCT
eurjchem-125	1	11	2011	2011	NUM
eurjchem-125	1	12	)	)	PUNCT
eurjchem-125	1	13	18‐24	18‐24	PROPN
eurjchem-125	1	14	european	european	PROPN
eurjchem-125	1	15	journal	journal	PROPN
eurjchem-125	1	16	of	of	ADP
eurjchem-125	1	17	chemistry	chemistry	NOUN
eurjchem-125	1	18	issn	issn	PROPN
eurjchem-125	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-125	1	20	(	(	PUNCT
eurjchem-125	1	21	print	print	NOUN
eurjchem-125	1	22	)	)	PUNCT
eurjchem-125	1	23	/	/	SYM
eurjchem-125	1	24	issn	issn	PROPN
eurjchem-125	1	25	2153‐2257	2153‐2257	NUM
eurjchem-125	1	26	(	(	PUNCT
eurjchem-125	1	27	online	online	ADJ
eurjchem-125	1	28	)	)	PUNCT
eurjchem-125	1	29			NOUN
eurjchem-125	1	30	2011	2011	NUM
eurjchem-125	1	31	eurjchem	eurjchem	PROPN
eurjchem-125	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-125	1	33	/	/	SYM
eurjchem-125	1	34	eurjchem.2.1.18‐24.125	eurjchem.2.1.18‐24.125	PROPN
eurjchem-125	1	35	european	european	ADJ
eurjchem-125	1	36	journal	journal	PROPN
eurjchem-125	1	37	of	of	ADP
eurjchem-125	1	38	chemistry	chemistry	PROPN
eurjchem-125	1	39	journal	journal	PROPN
eurjchem-125	1	40	homepage	homepage	NOUN
eurjchem-125	1	41	:	:	PUNCT
eurjchem-125	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-125	1	43	synthesis	synthesis	NOUN
eurjchem-125	1	44	,	,	PUNCT
eurjchem-125	1	45	configuration	configuration	NOUN
eurjchem-125	1	46	and	and	CCONJ
eurjchem-125	1	47	properties	property	NOUN
eurjchem-125	1	48	of	of	ADP
eurjchem-125	1	49	some	some	DET
eurjchem-125	1	50	new	new	ADJ
eurjchem-125	1	51	3,4,5‐substituted	3,4,5‐substituted	PROPN
eurjchem-125	1	52	oxazolidin‐2‐ones	oxazolidin‐2‐ones	PROPN
eurjchem-125	1	53	anelia	anelia	PROPN
eurjchem-125	1	54	tsenova	tsenova	NOUN
eurjchem-125	1	55	mavrovaa	mavrovaa	NOUN
eurjchem-125	1	56	,	,	PUNCT
eurjchem-125	1	57	*	*	PUNCT
eurjchem-125	1	58	,	,	PUNCT
eurjchem-125	1	59	pavletta	pavletta	PROPN
eurjchem-125	1	60	stoyanova	stoyanova	PROPN
eurjchem-125	1	61	denkovab	denkovab	PROPN
eurjchem-125	1	62	and	and	CCONJ
eurjchem-125	1	63	jordan	jordan	PROPN
eurjchem-125	1	64	andreev	andreev	PROPN
eurjchem-125	1	65	tsenovb	tsenovb	PROPN
eurjchem-125	1	66	a	a	DET
eurjchem-125	1	67	university	university	NOUN
eurjchem-125	1	68	of	of	ADP
eurjchem-125	1	69	chemical	chemical	NOUN
eurjchem-125	1	70	technology	technology	NOUN
eurjchem-125	1	71	and	and	CCONJ
eurjchem-125	1	72	metallurgy	metallurgy	NOUN
eurjchem-125	1	73	,	,	PUNCT
eurjchem-125	1	74	sofia	sofia	PROPN
eurjchem-125	1	75	,	,	PUNCT
eurjchem-125	1	76	bg‐1756	bg‐1756	PROPN
eurjchem-125	1	77	,	,	PUNCT
eurjchem-125	1	78	bulgaria	bulgaria	PROPN
eurjchem-125	1	79	b	b	PROPN
eurjchem-125	1	80	institute	institute	PROPN
eurjchem-125	1	81	of	of	ADP
eurjchem-125	1	82	organic	organic	ADJ
eurjchem-125	1	83	chemistry	chemistry	NOUN
eurjchem-125	1	84	,	,	PUNCT
eurjchem-125	1	85	bulgarian	bulgarian	ADJ
eurjchem-125	1	86	academy	academy	PROPN
eurjchem-125	1	87	of	of	ADP
eurjchem-125	1	88	science	science	PROPN
eurjchem-125	1	89	,	,	PUNCT
eurjchem-125	1	90	sofia	sofia	PROPN
eurjchem-125	1	91	,	,	PUNCT
eurjchem-125	1	92	bg‐1113	bg‐1113	PROPN
eurjchem-125	1	93	,	,	PUNCT
eurjchem-125	1	94	bulgaria	bulgaria	PROPN
eurjchem-125	1	95	*	*	PUNCT
eurjchem-125	1	96	corresponding	correspond	VERB
eurjchem-125	1	97	author	author	NOUN
eurjchem-125	1	98	at	at	ADP
eurjchem-125	1	99	:	:	PUNCT
eurjchem-125	1	100	university	university	NOUN
eurjchem-125	1	101	of	of	ADP
eurjchem-125	1	102	chemical	chemical	NOUN
eurjchem-125	1	103	technology	technology	NOUN
eurjchem-125	1	104	and	and	CCONJ
eurjchem-125	1	105	metallurgy	metallurgy	NOUN
eurjchem-125	1	106	,	,	PUNCT
eurjchem-125	1	107	sofia	sofia	PROPN
eurjchem-125	1	108	,	,	PUNCT
eurjchem-125	1	109	bg‐1756	bg‐1756	PROPN
eurjchem-125	1	110	,	,	PUNCT
eurjchem-125	1	111	bulgaria	bulgaria	PROPN
eurjchem-125	1	112	.	.	PUNCT
eurjchem-125	2	1	tel	tel	PROPN
eurjchem-125	2	2	.	.	PUNCT
eurjchem-125	2	3	:	:	PUNCT
eurjchem-125	3	1	+359.28163207	+359.28163207	NOUN
eurjchem-125	3	2	;	;	PUNCT
eurjchem-125	3	3	fax	fax	NOUN
eurjchem-125	3	4	:	:	PUNCT
eurjchem-125	3	5	+359.2685488	+359.2685488	PROPN
eurjchem-125	3	6	.	.	PUNCT
eurjchem-125	3	7	e‐mail	e‐mail	PUNCT
eurjchem-125	4	1	address	address	NOUN
eurjchem-125	4	2	:	:	PUNCT
eurjchem-125	4	3	anmav@abv.bg	anmav@abv.bg	PROPN
eurjchem-125	4	4	(	(	PUNCT
eurjchem-125	4	5	a.t	a.t	PROPN
eurjchem-125	4	6	.	.	PROPN
eurjchem-125	4	7	mavrova	mavrova	PROPN
eurjchem-125	4	8	)	)	PUNCT
eurjchem-125	4	9	.	.	PUNCT
eurjchem-125	5	1	article	article	NOUN
eurjchem-125	5	2	information	information	PROPN
eurjchem-125	5	3	abstract	abstract	ADV
eurjchem-125	5	4	received	receive	VERB
eurjchem-125	5	5	:	:	PUNCT
eurjchem-125	5	6	25	25	NUM
eurjchem-125	5	7	may	may	PROPN
eurjchem-125	5	8	2010	2010	NUM
eurjchem-125	5	9	received	receive	VERB
eurjchem-125	5	10	in	in	ADP
eurjchem-125	5	11	revised	revise	VERB
eurjchem-125	5	12	form	form	NOUN
eurjchem-125	5	13	:	:	PUNCT
eurjchem-125	5	14	30	30	NUM
eurjchem-125	5	15	october	october	NOUN
eurjchem-125	5	16	2010	2010	NUM
eurjchem-125	5	17	accepted	accept	VERB
eurjchem-125	5	18	:	:	PUNCT
eurjchem-125	5	19	08	08	NUM
eurjchem-125	5	20	december	december	PROPN
eurjchem-125	5	21	2010	2010	NUM
eurjchem-125	5	22	online	online	NOUN
eurjchem-125	5	23	:	:	PUNCT
eurjchem-125	5	24	31	31	NUM
eurjchem-125	5	25	march	march	NOUN
eurjchem-125	5	26	2011	2011	NUM
eurjchem-125	5	27	keywords	keyword	NOUN
eurjchem-125	5	28	novel	novel	VERB
eurjchem-125	5	29	3,4,5‐substituted‐oxazolidin‐2‐ones	3,4,5‐substituted‐oxazolidin‐2‐one	NOUN
eurjchem-125	5	30	containing	contain	VERB
eurjchem-125	5	31	piperazine	piperazine	NOUN
eurjchem-125	5	32	,	,	PUNCT
eurjchem-125	5	33	1‐(4‐chlorophenyl	1‐(4‐chlorophenyl	NUM
eurjchem-125	5	34	)	)	PUNCT
eurjchem-125	5	35	piperazine	piperazine	NOUN
eurjchem-125	5	36	,	,	PUNCT
eurjchem-125	5	37	benzhydrylpiperazine	benzhydrylpiperazine	NOUN
eurjchem-125	5	38	,	,	PUNCT
eurjchem-125	5	39	morpholine	morpholine	ADJ
eurjchem-125	5	40	and	and	CCONJ
eurjchem-125	5	41	piperidine	piperidine	NOUN
eurjchem-125	5	42	rings	ring	NOUN
eurjchem-125	5	43	were	be	AUX
eurjchem-125	5	44	synthesized	synthesize	VERB
eurjchem-125	5	45	via	via	ADP
eurjchem-125	5	46	mannich	mannich	PRON
eurjchem-125	5	47	reaction	reaction	NOUN
eurjchem-125	5	48	.	.	PUNCT
eurjchem-125	6	1	the	the	DET
eurjchem-125	6	2	stereochemistry	stereochemistry	NOUN
eurjchem-125	6	3	of	of	ADP
eurjchem-125	6	4	syn	syn	PROPN
eurjchem-125	6	5	and	and	CCONJ
eurjchem-125	6	6	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	6	7	was	be	AUX
eurjchem-125	6	8	assigned	assign	VERB
eurjchem-125	6	9	using	use	VERB
eurjchem-125	6	10	the	the	DET
eurjchem-125	6	11	observed	observed	ADJ
eurjchem-125	6	12	differences	difference	NOUN
eurjchem-125	6	13	in	in	ADP
eurjchem-125	6	14	the	the	DET
eurjchem-125	6	15	chemical	chemical	ADJ
eurjchem-125	6	16	shifts	shift	NOUN
eurjchem-125	6	17	of	of	ADP
eurjchem-125	6	18	the	the	DET
eurjchem-125	6	19	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	6	20	ring	ring	NOUN
eurjchem-125	6	21	protons	proton	NOUN
eurjchem-125	6	22	and	and	CCONJ
eurjchem-125	6	23	the	the	DET
eurjchem-125	6	24	values	value	NOUN
eurjchem-125	6	25	of	of	ADP
eurjchem-125	6	26	vicinal	vicinal	ADJ
eurjchem-125	6	27	coupling	coupling	NOUN
eurjchem-125	6	28	constants	constant	NOUN
eurjchem-125	6	29	(	(	PUNCT
eurjchem-125	6	30	3j	3j	NOUN
eurjchem-125	6	31	)	)	PUNCT
eurjchem-125	6	32	between	between	ADP
eurjchem-125	6	33	the	the	DET
eurjchem-125	6	34	two	two	NUM
eurjchem-125	6	35	protons	proton	NOUN
eurjchem-125	6	36	of	of	ADP
eurjchem-125	6	37	the	the	DET
eurjchem-125	6	38	oxazolidin‐2‐one	oxazolidin‐2‐one	PROPN
eurjchem-125	6	39	ring	ring	NOUN
eurjchem-125	6	40	.	.	PUNCT
eurjchem-125	7	1	for	for	ADP
eurjchem-125	7	2	all	all	DET
eurjchem-125	7	3	compounds	compound	NOUN
eurjchem-125	7	4	noe	noe	INTJ
eurjchem-125	7	5	(	(	PUNCT
eurjchem-125	7	6	nuclear	nuclear	ADJ
eurjchem-125	7	7	overhauser	overhauser	NOUN
eurjchem-125	7	8	effect	effect	NOUN
eurjchem-125	7	9	)	)	PUNCT
eurjchem-125	7	10	nmr	nmr	NOUN
eurjchem-125	7	11	spectra	spectra	NOUN
eurjchem-125	7	12	were	be	AUX
eurjchem-125	7	13	measured	measure	VERB
eurjchem-125	7	14	in	in	ADP
eurjchem-125	7	15	order	order	NOUN
eurjchem-125	7	16	to	to	PART
eurjchem-125	7	17	prove	prove	VERB
eurjchem-125	7	18	additionally	additionally	ADV
eurjchem-125	7	19	the	the	DET
eurjchem-125	7	20	position	position	NOUN
eurjchem-125	7	21	of	of	ADP
eurjchem-125	7	22	the	the	DET
eurjchem-125	7	23	substituents	substituent	NOUN
eurjchem-125	7	24	in	in	ADP
eurjchem-125	7	25	the	the	DET
eurjchem-125	7	26	oxazolidin‐2‐one	oxazolidin‐2‐one	PROPN
eurjchem-125	7	27	ring	ring	NOUN
eurjchem-125	7	28	.	.	PUNCT
eurjchem-125	8	1	some	some	DET
eurjchem-125	8	2	physic	physic	ADJ
eurjchem-125	8	3	chemical	chemical	NOUN
eurjchem-125	8	4	,	,	PUNCT
eurjchem-125	8	5	steric	steric	ADJ
eurjchem-125	8	6	and	and	CCONJ
eurjchem-125	8	7	electronic	electronic	ADJ
eurjchem-125	8	8	properties	property	NOUN
eurjchem-125	8	9	of	of	ADP
eurjchem-125	8	10	the	the	DET
eurjchem-125	8	11	compounds	compound	NOUN
eurjchem-125	8	12	were	be	AUX
eurjchem-125	8	13	determined	determine	VERB
eurjchem-125	8	14	in	in	ADP
eurjchem-125	8	15	order	order	NOUN
eurjchem-125	8	16	to	to	PART
eurjchem-125	8	17	establish	establish	VERB
eurjchem-125	8	18	the	the	DET
eurjchem-125	8	19	similarity	similarity	NOUN
eurjchem-125	8	20	between	between	ADP
eurjchem-125	8	21	the	the	DET
eurjchem-125	8	22	synthesized	synthesize	VERB
eurjchem-125	8	23	and	and	CCONJ
eurjchem-125	8	24	reference	reference	NOUN
eurjchem-125	8	25	compounds	compound	NOUN
eurjchem-125	8	26	.	.	PUNCT
eurjchem-125	9	1	the	the	DET
eurjchem-125	9	2	performed	perform	VERB
eurjchem-125	9	3	computations	computation	NOUN
eurjchem-125	9	4	showed	show	VERB
eurjchem-125	9	5	that	that	SCONJ
eurjchem-125	9	6	the	the	DET
eurjchem-125	9	7	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	9	8	possessed	possess	VERB
eurjchem-125	9	9	lower	low	ADJ
eurjchem-125	9	10	electronic	electronic	ADJ
eurjchem-125	9	11	energies	energy	NOUN
eurjchem-125	9	12	in	in	ADP
eurjchem-125	9	13	comparison	comparison	NOUN
eurjchem-125	9	14	to	to	ADP
eurjchem-125	9	15	these	these	PRON
eurjchem-125	9	16	of	of	ADP
eurjchem-125	9	17	syn‐compounds	syn‐compound	NOUN
eurjchem-125	9	18	.	.	PUNCT
eurjchem-125	10	1	the	the	DET
eurjchem-125	10	2	nucleus‐nucleus	nucleus‐nucleus	NOUN
eurjchem-125	10	3	repulse	repulse	VERB
eurjchem-125	10	4	energies	energy	NOUN
eurjchem-125	10	5	(	(	PUNCT
eurjchem-125	10	6	nre	nre	PROPN
eurjchem-125	10	7	)	)	PUNCT
eurjchem-125	10	8	and	and	CCONJ
eurjchem-125	10	9	the	the	DET
eurjchem-125	10	10	highest	high	ADJ
eurjchem-125	10	11	occupied	occupy	VERB
eurjchem-125	10	12	molecular	molecular	ADJ
eurjchem-125	10	13	orbital	orbital	ADJ
eurjchem-125	10	14	energies	energy	NOUN
eurjchem-125	10	15	(	(	PUNCT
eurjchem-125	10	16	homo	homo	NOUN
eurjchem-125	10	17	)	)	PUNCT
eurjchem-125	10	18	of	of	ADP
eurjchem-125	10	19	the	the	DET
eurjchem-125	10	20	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	10	21	are	be	AUX
eurjchem-125	10	22	higher	high	ADJ
eurjchem-125	10	23	than	than	ADP
eurjchem-125	10	24	the	the	DET
eurjchem-125	10	25	homo	homo	NOUN
eurjchem-125	10	26	and	and	CCONJ
eurjchem-125	10	27	nre	nre	PROPN
eurjchem-125	10	28	energies	energy	NOUN
eurjchem-125	10	29	of	of	ADP
eurjchem-125	10	30	syn‐compounds	syn‐compound	NOUN
eurjchem-125	10	31	.	.	PUNCT
eurjchem-125	11	1	the	the	DET
eurjchem-125	11	2	connolly	connolly	PROPN
eurjchem-125	11	3	solvent	solvent	PROPN
eurjchem-125	11	4	accessible	accessible	ADJ
eurjchem-125	11	5	surface	surface	NOUN
eurjchem-125	11	6	area	area	NOUN
eurjchem-125	11	7	(	(	PUNCT
eurjchem-125	11	8	sas	sas	PROPN
eurjchem-125	11	9	)	)	PUNCT
eurjchem-125	11	10	and	and	CCONJ
eurjchem-125	11	11	connolly	connolly	PROPN
eurjchem-125	11	12	molecular	molecular	ADJ
eurjchem-125	11	13	surface	surface	NOUN
eurjchem-125	11	14	area	area	NOUN
eurjchem-125	11	15	(	(	PUNCT
eurjchem-125	11	16	ms	ms	NOUN
eurjchem-125	11	17	)	)	PUNCT
eurjchem-125	11	18	values	value	NOUN
eurjchem-125	11	19	of	of	ADP
eurjchem-125	11	20	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	11	21	are	be	AUX
eurjchem-125	11	22	lower	low	ADJ
eurjchem-125	11	23	than	than	ADP
eurjchem-125	11	24	these	these	PRON
eurjchem-125	11	25	of	of	ADP
eurjchem-125	11	26	syn‐isomers	syn‐isomer	NOUN
eurjchem-125	11	27	.	.	PUNCT
eurjchem-125	12	1	the	the	DET
eurjchem-125	12	2	same	same	ADJ
eurjchem-125	12	3	relations	relation	NOUN
eurjchem-125	12	4	were	be	AUX
eurjchem-125	12	5	observed	observe	VERB
eurjchem-125	12	6	for	for	ADP
eurjchem-125	12	7	the	the	DET
eurjchem-125	12	8	reference	reference	NOUN
eurjchem-125	12	9	compounds	compound	VERB
eurjchem-125	12	10	.	.	PUNCT
eurjchem-125	13	1	probably	probably	ADV
eurjchem-125	13	2	the	the	DET
eurjchem-125	13	3	differences	difference	NOUN
eurjchem-125	13	4	in	in	ADP
eurjchem-125	13	5	the	the	DET
eurjchem-125	13	6	electronic	electronic	ADJ
eurjchem-125	13	7	and	and	CCONJ
eurjchem-125	13	8	steric	steric	ADJ
eurjchem-125	13	9	properties	property	NOUN
eurjchem-125	13	10	are	be	AUX
eurjchem-125	13	11	responsible	responsible	ADJ
eurjchem-125	13	12	not	not	PART
eurjchem-125	13	13	only	only	ADV
eurjchem-125	13	14	for	for	ADP
eurjchem-125	13	15	the	the	DET
eurjchem-125	13	16	higher	high	ADJ
eurjchem-125	13	17	ld50	ld50	PROPN
eurjchem-125	13	18	value	value	NOUN
eurjchem-125	13	19	of	of	ADP
eurjchem-125	13	20	the	the	DET
eurjchem-125	13	21	reference	reference	NOUN
eurjchem-125	13	22	anti‐compound	anti‐compound	ADV
eurjchem-125	13	23	,	,	PUNCT
eurjchem-125	13	24	but	but	CCONJ
eurjchem-125	13	25	also	also	ADV
eurjchem-125	13	26	may	may	AUX
eurjchem-125	13	27	contribute	contribute	VERB
eurjchem-125	13	28	to	to	ADP
eurjchem-125	13	29	the	the	DET
eurjchem-125	13	30	higher	high	ADJ
eurjchem-125	13	31	toxicity	toxicity	NOUN
eurjchem-125	13	32	of	of	ADP
eurjchem-125	13	33	the	the	DET
eurjchem-125	13	34	prepared	prepared	ADJ
eurjchem-125	13	35	anti‐mannich	anti‐mannich	NOUN
eurjchem-125	13	36	bases	basis	NOUN
eurjchem-125	13	37	in	in	ADP
eurjchem-125	13	38	comparison	comparison	NOUN
eurjchem-125	13	39	to	to	ADP
eurjchem-125	13	40	that	that	PRON
eurjchem-125	13	41	of	of	ADP
eurjchem-125	13	42	the	the	DET
eurjchem-125	13	43	syn‐diastereoisomers	syn‐diastereoisomer	NOUN
eurjchem-125	13	44	.	.	PUNCT
eurjchem-125	14	1	oxazolidin‐2‐ones	oxazolidin‐2‐one	NOUN
eurjchem-125	14	2	stereochemistry	stereochemistry	NOUN
eurjchem-125	14	3	configuration	configuration	NOUN
eurjchem-125	14	4	mannich	mannich	DET
eurjchem-125	14	5	reaction	reaction	NOUN
eurjchem-125	14	6	analgesis	analgesis	NOUN
eurjchem-125	14	7	activity	activity	NOUN
eurjchem-125	14	8	drug	drug	NOUN
eurjchem-125	14	9	similarity	similarity	NOUN
eurjchem-125	14	10	1	1	NUM
eurjchem-125	14	11	.	.	PUNCT
eurjchem-125	15	1	introduction	introduction	NOUN
eurjchem-125	15	2	the	the	DET
eurjchem-125	15	3	oxazolidin‐2‐ones	oxazolidin‐2‐ones	PROPN
eurjchem-125	15	4	are	be	AUX
eurjchem-125	15	5	an	an	DET
eurjchem-125	15	6	important	important	ADJ
eurjchem-125	15	7	class	class	NOUN
eurjchem-125	15	8	of	of	ADP
eurjchem-125	15	9	heterocyclic	heterocyclic	ADJ
eurjchem-125	15	10	compounds	compound	NOUN
eurjchem-125	15	11	,	,	PUNCT
eurjchem-125	15	12	which	which	PRON
eurjchem-125	15	13	attract	attract	VERB
eurjchem-125	15	14	the	the	DET
eurjchem-125	15	15	attention	attention	NOUN
eurjchem-125	15	16	of	of	ADP
eurjchem-125	15	17	the	the	DET
eurjchem-125	15	18	investigators	investigator	NOUN
eurjchem-125	15	19	with	with	ADP
eurjchem-125	15	20	the	the	DET
eurjchem-125	15	21	possibilities	possibility	NOUN
eurjchem-125	15	22	they	they	PRON
eurjchem-125	15	23	give	give	VERB
eurjchem-125	15	24	both	both	PRON
eurjchem-125	15	25	for	for	ADP
eurjchem-125	15	26	total	total	ADJ
eurjchem-125	15	27	regio‐	regio‐	NOUN
eurjchem-125	15	28	and	and	CCONJ
eurjchem-125	15	29	stereocontrol	stereocontrol	NOUN
eurjchem-125	15	30	in	in	ADP
eurjchem-125	15	31	the	the	DET
eurjchem-125	15	32	synthesis	synthesis	NOUN
eurjchem-125	15	33	of	of	ADP
eurjchem-125	15	34	“	"	PUNCT
eurjchem-125	15	35	enantiomerically‐	enantiomerically‐	X
eurjchem-125	15	36	pure	pure	ADJ
eurjchem-125	15	37	”	"	PUNCT
eurjchem-125	15	38	compounds	compound	NOUN
eurjchem-125	15	39	like	like	ADP
eurjchem-125	15	40	β‐hydroxy‐carboxylic	β‐hydroxy‐carboxylic	NOUN
eurjchem-125	15	41	acids	acid	NOUN
eurjchem-125	15	42	,	,	PUNCT
eurjchem-125	15	43	amino	amino	NOUN
eurjchem-125	15	44	alcohols	alcohol	NOUN
eurjchem-125	15	45	,	,	PUNCT
eurjchem-125	15	46	aminophosphonic	aminophosphonic	ADJ
eurjchem-125	15	47	acids	acid	NOUN
eurjchem-125	15	48	and	and	CCONJ
eurjchem-125	15	49	for	for	ADP
eurjchem-125	15	50	the	the	DET
eurjchem-125	15	51	modifying	modifying	NOUN
eurjchem-125	15	52	of	of	ADP
eurjchem-125	15	53	complicated	complicated	ADJ
eurjchem-125	15	54	structures	structure	NOUN
eurjchem-125	15	55	of	of	ADP
eurjchem-125	15	56	natural	natural	ADJ
eurjchem-125	15	57	origin	origin	NOUN
eurjchem-125	15	58	[	[	X
eurjchem-125	15	59	1‐5	1‐5	NUM
eurjchem-125	15	60	]	]	X
eurjchem-125	15	61	.	.	PUNCT
eurjchem-125	16	1	moreover	moreover	ADV
eurjchem-125	16	2	,	,	PUNCT
eurjchem-125	16	3	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	16	4	derivatives	derivative	NOUN
eurjchem-125	16	5	are	be	AUX
eurjchem-125	16	6	particularly	particularly	ADV
eurjchem-125	16	7	versatile	versatile	ADJ
eurjchem-125	16	8	drugs	drug	NOUN
eurjchem-125	16	9	and	and	CCONJ
eurjchem-125	16	10	their	their	PRON
eurjchem-125	16	11	study	study	NOUN
eurjchem-125	16	12	is	be	AUX
eurjchem-125	16	13	extremely	extremely	ADV
eurjchem-125	16	14	relevant	relevant	ADJ
eurjchem-125	16	15	from	from	ADP
eurjchem-125	16	16	a	a	DET
eurjchem-125	16	17	pharmacological	pharmacological	ADJ
eurjchem-125	16	18	point	point	NOUN
eurjchem-125	16	19	of	of	ADP
eurjchem-125	16	20	view	view	NOUN
eurjchem-125	16	21	.	.	PUNCT
eurjchem-125	17	1	the	the	DET
eurjchem-125	17	2	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	17	3	compounds	compound	NOUN
eurjchem-125	17	4	represent	represent	VERB
eurjchem-125	17	5	a	a	DET
eurjchem-125	17	6	new	new	ADJ
eurjchem-125	17	7	class	class	NOUN
eurjchem-125	17	8	of	of	ADP
eurjchem-125	17	9	antibacterial	antibacterial	ADJ
eurjchem-125	17	10	agents	agent	NOUN
eurjchem-125	17	11	,	,	PUNCT
eurjchem-125	17	12	effective	effective	ADJ
eurjchem-125	17	13	against	against	ADP
eurjchem-125	17	14	virtually	virtually	ADV
eurjchem-125	17	15	all	all	PRON
eurjchem-125	17	16	important	important	ADJ
eurjchem-125	17	17	gram‐positive	gram‐positive	ADJ
eurjchem-125	17	18	pathogens	pathogen	NOUN
eurjchem-125	17	19	,	,	PUNCT
eurjchem-125	17	20	including	include	VERB
eurjchem-125	17	21	methicillin‐	methicillin‐	X
eurjchem-125	17	22	resistant	resistant	ADJ
eurjchem-125	17	23	staphylococci	staphylococci	PROPN
eurjchem-125	17	24	,	,	PUNCT
eurjchem-125	17	25	penicillin‐resistant	penicillin‐resistant	ADJ
eurjchem-125	17	26	pneumococci	pneumococci	NOUN
eurjchem-125	17	27	,	,	PUNCT
eurjchem-125	17	28	macrolide‐resistant	macrolide‐resistant	NOUN
eurjchem-125	17	29	streptococci	streptococci	NOUN
eurjchem-125	17	30	and	and	CCONJ
eurjchem-125	17	31	vancomycin‐resistant	vancomycin‐resistant	NOUN
eurjchem-125	17	32	enterococci	enterococci	NOUN
eurjchem-125	17	33	.	.	PUNCT
eurjchem-125	18	1	the	the	DET
eurjchem-125	18	2	pharmacokinetic	pharmacokinetic	ADJ
eurjchem-125	18	3	traits	trait	NOUN
eurjchem-125	18	4	of	of	ADP
eurjchem-125	18	5	linezolid	linezolid	NOUN
eurjchem-125	18	6	and	and	CCONJ
eurjchem-125	18	7	eperozolid	eperozolid	ADJ
eurjchem-125	18	8	encouraged	encourage	VERB
eurjchem-125	18	9	the	the	DET
eurjchem-125	18	10	further	further	ADJ
eurjchem-125	18	11	investigation	investigation	NOUN
eurjchem-125	18	12	for	for	ADP
eurjchem-125	18	13	improvement	improvement	NOUN
eurjchem-125	18	14	of	of	ADP
eurjchem-125	18	15	the	the	DET
eurjchem-125	18	16	characteristics	characteristic	NOUN
eurjchem-125	18	17	of	of	ADP
eurjchem-125	18	18	the	the	DET
eurjchem-125	18	19	oxazolidinones	oxazolidinone	NOUN
eurjchem-125	18	20	in	in	ADP
eurjchem-125	18	21	order	order	NOUN
eurjchem-125	18	22	to	to	PART
eurjchem-125	18	23	eliminate	eliminate	VERB
eurjchem-125	18	24	the	the	DET
eurjchem-125	18	25	early	early	ADJ
eurjchem-125	18	26	resistance	resistance	NOUN
eurjchem-125	18	27	development	development	NOUN
eurjchem-125	18	28	[	[	X
eurjchem-125	18	29	6‐9	6‐9	NOUN
eurjchem-125	18	30	]	]	PUNCT
eurjchem-125	18	31	.	.	PUNCT
eurjchem-125	19	1	depending	depend	VERB
eurjchem-125	19	2	on	on	ADP
eurjchem-125	19	3	the	the	DET
eurjchem-125	19	4	placement	placement	NOUN
eurjchem-125	19	5	of	of	ADP
eurjchem-125	19	6	the	the	DET
eurjchem-125	19	7	substituents	substituent	NOUN
eurjchem-125	19	8	,	,	PUNCT
eurjchem-125	19	9	oxazolidin‐2‐	oxazolidin‐2‐	NOUN
eurjchem-125	19	10	one	one	NUM
eurjchem-125	19	11	derivatives	derivative	NOUN
eurjchem-125	19	12	exhibit	exhibit	VERB
eurjchem-125	19	13	different	different	ADJ
eurjchem-125	19	14	activity	activity	NOUN
eurjchem-125	19	15	.	.	PUNCT
eurjchem-125	20	1	the	the	DET
eurjchem-125	20	2	3‐phenyl‐	3‐phenyl‐	NUM
eurjchem-125	20	3	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	20	4	derivatives	derivative	NOUN
eurjchem-125	20	5	substituted	substitute	VERB
eurjchem-125	20	6	at	at	ADP
eurjchem-125	20	7	position	position	NOUN
eurjchem-125	20	8	5	5	NUM
eurjchem-125	20	9	with	with	ADP
eurjchem-125	20	10	alcoholic	alcoholic	ADJ
eurjchem-125	20	11	or	or	CCONJ
eurjchem-125	20	12	ethereal	ethereal	ADJ
eurjchem-125	20	13	group	group	NOUN
eurjchem-125	20	14	as	as	ADP
eurjchem-125	20	15	toloxatone	toloxatone	PROPN
eurjchem-125	20	16	,	,	PUNCT
eurjchem-125	20	17	cimoxatone	cimoxatone	NOUN
eurjchem-125	20	18	are	be	AUX
eurjchem-125	20	19	proved	prove	VERB
eurjchem-125	20	20	to	to	PART
eurjchem-125	20	21	be	be	AUX
eurjchem-125	20	22	anti‐depressant	anti‐depressant	ADJ
eurjchem-125	20	23	agents	agent	NOUN
eurjchem-125	20	24	,	,	PUNCT
eurjchem-125	20	25	while	while	SCONJ
eurjchem-125	20	26	the	the	DET
eurjchem-125	20	27	5‐amino‐3‐	5‐amino‐3‐	NUM
eurjchem-125	20	28	phenyloxazolidin‐2‐one	phenyloxazolidin‐2‐one	NOUN
eurjchem-125	20	29	derivatives	derivative	NOUN
eurjchem-125	20	30	are	be	AUX
eurjchem-125	20	31	effective	effective	ADJ
eurjchem-125	20	32	as	as	ADP
eurjchem-125	20	33	anti‐	anti‐	PROPN
eurjchem-125	20	34	parkinson	parkinson	NOUN
eurjchem-125	20	35	agents	agent	NOUN
eurjchem-125	20	36	(	(	PUNCT
eurjchem-125	20	37	almoxatone	almoxatone	PROPN
eurjchem-125	20	38	,	,	PUNCT
eurjchem-125	20	39	md	md	PROPN
eurjchem-125	20	40	780236	780236	NUM
eurjchem-125	20	41	)	)	PUNCT
eurjchem-125	21	1	[	[	X
eurjchem-125	21	2	10‐12	10‐12	NUM
eurjchem-125	21	3	]	]	PUNCT
eurjchem-125	21	4	.	.	PUNCT
eurjchem-125	22	1	some	some	DET
eurjchem-125	22	2	oxazolidin‐2‐ones	oxazolidin‐2‐one	NOUN
eurjchem-125	22	3	are	be	AUX
eurjchem-125	22	4	useful	useful	ADJ
eurjchem-125	22	5	as	as	ADP
eurjchem-125	22	6	selective	selective	ADJ
eurjchem-125	22	7	alpha‐7	alpha‐7	ADP
eurjchem-125	22	8	nicotinic	nicotinic	ADJ
eurjchem-125	22	9	receptor	receptor	NOUN
eurjchem-125	22	10	agonist	agonist	NOUN
eurjchem-125	22	11	,	,	PUNCT
eurjchem-125	22	12	as	as	ADP
eurjchem-125	22	13	centrally	centrally	ADV
eurjchem-125	22	14	acting	act	VERB
eurjchem-125	22	15	muscarinic	muscarinic	ADJ
eurjchem-125	22	16	agents	agent	NOUN
eurjchem-125	22	17	and	and	CCONJ
eurjchem-125	22	18	as	as	ADP
eurjchem-125	22	19	analgesic	analgesic	ADJ
eurjchem-125	22	20	agents	agent	NOUN
eurjchem-125	22	21	for	for	ADP
eurjchem-125	22	22	the	the	DET
eurjchem-125	22	23	treatment	treatment	NOUN
eurjchem-125	22	24	of	of	ADP
eurjchem-125	22	25	pain	pain	NOUN
eurjchem-125	22	26	,	,	PUNCT
eurjchem-125	22	27	as	as	ADP
eurjchem-125	22	28	sleep	sleep	NOUN
eurjchem-125	22	29	aids	aid	NOUN
eurjchem-125	22	30	and	and	CCONJ
eurjchem-125	22	31	agents	agent	NOUN
eurjchem-125	22	32	for	for	ADP
eurjchem-125	22	33	treating	treat	VERB
eurjchem-125	22	34	the	the	DET
eurjchem-125	22	35	symptoms	symptom	NOUN
eurjchem-125	22	36	of	of	ADP
eurjchem-125	22	37	senile	senile	ADJ
eurjchem-125	22	38	dementia	dementia	NOUN
eurjchem-125	22	39	,	,	PUNCT
eurjchem-125	22	40	alzheimer	alzheimer	PROPN
eurjchem-125	22	41	's	's	PART
eurjchem-125	22	42	disease	disease	NOUN
eurjchem-125	22	43	[	[	X
eurjchem-125	22	44	13‐15	13‐15	NUM
eurjchem-125	22	45	]	]	PUNCT
eurjchem-125	22	46	.	.	PUNCT
eurjchem-125	23	1	in	in	ADP
eurjchem-125	23	2	this	this	DET
eurjchem-125	23	3	paper	paper	NOUN
eurjchem-125	23	4	,	,	PUNCT
eurjchem-125	23	5	we	we	PRON
eurjchem-125	23	6	describe	describe	VERB
eurjchem-125	23	7	the	the	DET
eurjchem-125	23	8	synthesis	synthesis	NOUN
eurjchem-125	23	9	of	of	ADP
eurjchem-125	23	10	some	some	DET
eurjchem-125	23	11	novel	novel	ADJ
eurjchem-125	23	12	3,4,5‐trisubstituted‐oxazolidin‐2‐ones	3,4,5‐trisubstituted‐oxazolidin‐2‐one	NOUN
eurjchem-125	23	13	containing	contain	VERB
eurjchem-125	23	14	piperazine	piperazine	NOUN
eurjchem-125	23	15	,	,	PUNCT
eurjchem-125	23	16	benzhydrylpiperazine	benzhydrylpiperazine	NOUN
eurjchem-125	23	17	,	,	PUNCT
eurjchem-125	23	18	morpholine	morpholine	ADJ
eurjchem-125	23	19	and	and	CCONJ
eurjchem-125	23	20	piperidine	piperidine	NOUN
eurjchem-125	23	21	rings	ring	NOUN
eurjchem-125	23	22	via	via	ADP
eurjchem-125	23	23	mannich	mannich	PRON
eurjchem-125	23	24	reaction	reaction	NOUN
eurjchem-125	23	25	as	as	ADP
eurjchem-125	23	26	potential	potential	ADJ
eurjchem-125	23	27	bioactive	bioactive	NOUN
eurjchem-125	23	28	compound	compound	NOUN
eurjchem-125	23	29	as	as	ADV
eurjchem-125	23	30	well	well	ADV
eurjchem-125	23	31	as	as	ADP
eurjchem-125	23	32	some	some	PRON
eurjchem-125	23	33	of	of	ADP
eurjchem-125	23	34	their	their	PRON
eurjchem-125	23	35	physicochemical	physicochemical	ADJ
eurjchem-125	23	36	,	,	PUNCT
eurjchem-125	23	37	steric	steric	ADJ
eurjchem-125	23	38	and	and	CCONJ
eurjchem-125	23	39	electronic	electronic	ADJ
eurjchem-125	23	40	properties	property	NOUN
eurjchem-125	23	41	in	in	ADP
eurjchem-125	23	42	order	order	NOUN
eurjchem-125	23	43	to	to	PART
eurjchem-125	23	44	estimate	estimate	VERB
eurjchem-125	23	45	the	the	DET
eurjchem-125	23	46	similarity	similarity	NOUN
eurjchem-125	23	47	between	between	ADP
eurjchem-125	23	48	these	these	DET
eurjchem-125	23	49	new	new	ADJ
eurjchem-125	23	50	oxazolidinones	oxazolidinone	NOUN
eurjchem-125	23	51	and	and	CCONJ
eurjchem-125	23	52	our	our	PRON
eurjchem-125	23	53	previously	previously	ADV
eurjchem-125	23	54	reported	report	VERB
eurjchem-125	23	55	.	.	PUNCT
eurjchem-125	24	1	the	the	DET
eurjchem-125	24	2	latter	latter	ADJ
eurjchem-125	24	3	compounds	compound	NOUN
eurjchem-125	24	4	were	be	AUX
eurjchem-125	24	5	found	find	VERB
eurjchem-125	24	6	to	to	PART
eurjchem-125	24	7	possess	possess	VERB
eurjchem-125	24	8	analgesic	analgesic	ADJ
eurjchem-125	24	9	activity	activity	NOUN
eurjchem-125	24	10	against	against	ADP
eurjchem-125	24	11	acetic	acetic	ADJ
eurjchem-125	24	12	acid‐induced	acid‐induce	VERB
eurjchem-125	24	13	pain	pain	NOUN
eurjchem-125	24	14	,	,	PUNCT
eurjchem-125	24	15	but	but	CCONJ
eurjchem-125	24	16	different	different	ADJ
eurjchem-125	24	17	ld50	ld50	PROPN
eurjchem-125	24	18	values	value	NOUN
eurjchem-125	24	19	[	[	X
eurjchem-125	24	20	16	16	NUM
eurjchem-125	24	21	]	]	PUNCT
eurjchem-125	24	22	.	.	PUNCT
eurjchem-125	25	1	the	the	DET
eurjchem-125	25	2	present	present	ADJ
eurjchem-125	25	3	paper	paper	NOUN
eurjchem-125	25	4	is	be	AUX
eurjchem-125	25	5	a	a	DET
eurjchem-125	25	6	continuation	continuation	NOUN
eurjchem-125	25	7	of	of	ADP
eurjchem-125	25	8	this	this	DET
eurjchem-125	25	9	work	work	NOUN
eurjchem-125	25	10	and	and	CCONJ
eurjchem-125	25	11	is	be	AUX
eurjchem-125	25	12	focused	focus	VERB
eurjchem-125	25	13	on	on	ADP
eurjchem-125	25	14	understanding	understanding	NOUN
eurjchem-125	25	15	in	in	ADP
eurjchem-125	25	16	more	more	ADJ
eurjchem-125	25	17	depth	depth	NOUN
eurjchem-125	25	18	the	the	DET
eurjchem-125	25	19	physical	physical	ADJ
eurjchem-125	25	20	properties	property	NOUN
eurjchem-125	25	21	of	of	ADP
eurjchem-125	25	22	3,4,5‐	3,4,5‐	NUM
eurjchem-125	25	23	substituted	substitute	VERB
eurjchem-125	25	24	oxazolidin‐2‐ones	oxazolidin‐2‐one	NOUN
eurjchem-125	25	25	as	as	ADP
eurjchem-125	25	26	a	a	DET
eurjchem-125	25	27	function	function	NOUN
eurjchem-125	25	28	of	of	ADP
eurjchem-125	25	29	their	their	PRON
eurjchem-125	25	30	ring	ring	NOUN
eurjchem-125	25	31	stereochemistry	stereochemistry	NOUN
eurjchem-125	25	32	.	.	PUNCT
eurjchem-125	26	1	the	the	DET
eurjchem-125	26	2	selection	selection	NOUN
eurjchem-125	26	3	of	of	ADP
eurjchem-125	26	4	these	these	DET
eurjchem-125	26	5	structures	structure	NOUN
eurjchem-125	26	6	used	use	VERB
eurjchem-125	26	7	in	in	ADP
eurjchem-125	26	8	this	this	DET
eurjchem-125	26	9	study	study	NOUN
eurjchem-125	26	10	was	be	AUX
eurjchem-125	26	11	done	do	VERB
eurjchem-125	26	12	in	in	ADP
eurjchem-125	26	13	accordance	accordance	NOUN
eurjchem-125	26	14	with	with	ADP
eurjchem-125	26	15	the	the	DET
eurjchem-125	26	16	fact	fact	NOUN
eurjchem-125	26	17	that	that	SCONJ
eurjchem-125	26	18	the	the	DET
eurjchem-125	26	19	thiophene	thiophene	NOUN
eurjchem-125	26	20	heterocycle	heterocycle	NOUN
eurjchem-125	26	21	takes	take	VERB
eurjchem-125	26	22	part	part	NOUN
eurjchem-125	26	23	in	in	ADP
eurjchem-125	26	24	the	the	DET
eurjchem-125	26	25	structure	structure	NOUN
eurjchem-125	26	26	of	of	ADP
eurjchem-125	26	27	some	some	DET
eurjchem-125	26	28	substances	substance	NOUN
eurjchem-125	26	29	,	,	PUNCT
eurjchem-125	26	30	possessing	possess	VERB
eurjchem-125	26	31	analgesic	analgesic	ADJ
eurjchem-125	26	32	activity	activity	NOUN
eurjchem-125	26	33	,	,	PUNCT
eurjchem-125	26	34	and	and	CCONJ
eurjchem-125	26	35	the	the	DET
eurjchem-125	26	36	piperazine	piperazine	NOUN
eurjchem-125	26	37	,	,	PUNCT
eurjchem-125	26	38	morpholine	morpholine	ADJ
eurjchem-125	26	39	and	and	CCONJ
eurjchem-125	26	40	piperidine	piperidine	NOUN
eurjchem-125	26	41	moieties	moiety	NOUN
eurjchem-125	26	42	occur	occur	VERB
eurjchem-125	26	43	as	as	ADP
eurjchem-125	26	44	a	a	DET
eurjchem-125	26	45	pharmacophore	pharmacophore	NOUN
eurjchem-125	26	46	in	in	ADP
eurjchem-125	26	47	many	many	ADJ
eurjchem-125	26	48	biological	biological	ADJ
eurjchem-125	26	49	active	active	ADJ
eurjchem-125	26	50	compounds	compound	NOUN
eurjchem-125	26	51	and	and	CCONJ
eurjchem-125	26	52	are	be	AUX
eurjchem-125	26	53	essential	essential	ADJ
eurjchem-125	26	54	elements	element	NOUN
eurjchem-125	26	55	in	in	ADP
eurjchem-125	26	56	drug	drug	NOUN
eurjchem-125	26	57	design	design	NOUN
eurjchem-125	26	58	[	[	X
eurjchem-125	26	59	17‐21	17‐21	X
eurjchem-125	26	60	]	]	X
eurjchem-125	26	61	.	.	PUNCT
eurjchem-125	27	1	mavrova	mavrova	PROPN
eurjchem-125	27	2	et	et	PROPN
eurjchem-125	27	3	al	al	PROPN
eurjchem-125	27	4	.	.	PUNCT
eurjchem-125	27	5	/	/	SYM
eurjchem-125	27	6	european	european	PROPN
eurjchem-125	27	7	journal	journal	PROPN
eurjchem-125	27	8	of	of	ADP
eurjchem-125	27	9	chemistry	chemistry	NOUN
eurjchem-125	27	10	2	2	NUM
eurjchem-125	27	11	(	(	PUNCT
eurjchem-125	27	12	1	1	NUM
eurjchem-125	27	13	)	)	PUNCT
eurjchem-125	27	14	(	(	PUNCT
eurjchem-125	27	15	2011	2011	NUM
eurjchem-125	27	16	)	)	PUNCT
eurjchem-125	27	17	18‐24	18‐24	NOUN
eurjchem-125	27	18	19	19	NUM
eurjchem-125	27	19	2	2	NUM
eurjchem-125	27	20	.	.	PUNCT
eurjchem-125	27	21	experimental	experimental	ADJ
eurjchem-125	27	22	melting	melting	NOUN
eurjchem-125	27	23	points	point	NOUN
eurjchem-125	27	24	were	be	AUX
eurjchem-125	27	25	determined	determine	VERB
eurjchem-125	27	26	on	on	ADP
eurjchem-125	27	27	an	an	DET
eurjchem-125	27	28	electrothermal	electrothermal	ADJ
eurjchem-125	27	29	az	az	NOUN
eurjchem-125	27	30	9000	9000	NUM
eurjchem-125	27	31	3mk4	3mk4	NUM
eurjchem-125	27	32	apparatus	apparatus	NOUN
eurjchem-125	27	33	and	and	CCONJ
eurjchem-125	27	34	were	be	AUX
eurjchem-125	27	35	uncorrected	uncorrecte	VERB
eurjchem-125	27	36	.	.	PUNCT
eurjchem-125	28	1	the	the	DET
eurjchem-125	28	2	thin	thin	ADJ
eurjchem-125	28	3	layer	layer	NOUN
eurjchem-125	28	4	chromatography	chromatography	NOUN
eurjchem-125	28	5	(	(	PUNCT
eurjchem-125	28	6	tlc	tlc	NOUN
eurjchem-125	28	7	,	,	PUNCT
eurjchem-125	28	8	rf	rf	NOUN
eurjchem-125	28	9	values	value	NOUN
eurjchem-125	28	10	)	)	PUNCT
eurjchem-125	28	11	was	be	AUX
eurjchem-125	28	12	performed	perform	VERB
eurjchem-125	28	13	on	on	ADP
eurjchem-125	28	14	silica	silica	NOUN
eurjchem-125	28	15	gel	gel	NOUN
eurjchem-125	28	16	60	60	NUM
eurjchem-125	28	17	plates	plate	NOUN
eurjchem-125	28	18	f254	f254	PROPN
eurjchem-125	28	19	and	and	CCONJ
eurjchem-125	28	20	al2o3‐plates	al2o3‐plates	PROPN
eurjchem-125	28	21	(	(	PUNCT
eurjchem-125	28	22	merck	merck	PROPN
eurjchem-125	28	23	,	,	PUNCT
eurjchem-125	28	24	0.2	0.2	NUM
eurjchem-125	28	25	mm	mm	NOUN
eurjchem-125	28	26	thick	thick	ADJ
eurjchem-125	28	27	)	)	PUNCT
eurjchem-125	28	28	using	use	VERB
eurjchem-125	28	29	mobile	mobile	ADJ
eurjchem-125	28	30	phase	phase	NOUN
eurjchem-125	28	31	benzene	benzene	NOUN
eurjchem-125	28	32	:	:	PUNCT
eurjchem-125	28	33	diethyl	diethyl	NOUN
eurjchem-125	28	34	ether	ether	NOUN
eurjchem-125	28	35	(	(	PUNCT
eurjchem-125	28	36	1:1	1:1	NUM
eurjchem-125	28	37	;)	;)	NOUN
eurjchem-125	28	38	,	,	PUNCT
eurjchem-125	28	39	benzene	benzene	NOUN
eurjchem-125	28	40	:	:	PUNCT
eurjchem-125	28	41	diethyl	diethyl	NOUN
eurjchem-125	28	42	ether	ether	NOUN
eurjchem-125	28	43	:	:	PUNCT
eurjchem-125	28	44	ethanol	ethanol	NOUN
eurjchem-125	28	45	(	(	PUNCT
eurjchem-125	28	46	4:1:3	4:1:3	NUM
eurjchem-125	28	47	;	;	PUNCT
eurjchem-125	28	48	4:1:2	4:1:2	NUM
eurjchem-125	28	49	)	)	PUNCT
eurjchem-125	28	50	and	and	CCONJ
eurjchem-125	28	51	visualization	visualization	NOUN
eurjchem-125	28	52	was	be	AUX
eurjchem-125	28	53	effected	effect	VERB
eurjchem-125	28	54	with	with	ADP
eurjchem-125	28	55	ultraviolet	ultraviolet	ADJ
eurjchem-125	28	56	light	light	NOUN
eurjchem-125	28	57	.	.	PUNCT
eurjchem-125	29	1	ir	ir	PROPN
eurjchem-125	29	2	spectra	spectra	PROPN
eurjchem-125	29	3	were	be	AUX
eurjchem-125	29	4	recorded	record	VERB
eurjchem-125	29	5	on	on	ADP
eurjchem-125	29	6	a	a	DET
eurjchem-125	29	7	bruker	bruker	NOUN
eurjchem-125	29	8	equinox	equinox	NOUN
eurjchem-125	29	9	55	55	NUM
eurjchem-125	29	10	spectrophotometer	spectrophotometer	NOUN
eurjchem-125	29	11	as	as	ADP
eurjchem-125	29	12	potassium	potassium	NOUN
eurjchem-125	29	13	bromide	bromide	NOUN
eurjchem-125	29	14	discs	disc	NOUN
eurjchem-125	29	15	.	.	PUNCT
eurjchem-125	30	1	1h	1h	NUM
eurjchem-125	30	2	nmr	nmr	PROPN
eurjchem-125	30	3	spectra	spectra	NOUN
eurjchem-125	30	4	were	be	AUX
eurjchem-125	30	5	obtained	obtain	VERB
eurjchem-125	30	6	on	on	ADP
eurjchem-125	30	7	a	a	DET
eurjchem-125	30	8	bruker	bruker	PROPN
eurjchem-125	30	9	avance	avance	PROPN
eurjchem-125	30	10	drx	drx	PROPN
eurjchem-125	30	11	250	250	NUM
eurjchem-125	30	12	mhz	mhz	NOUN
eurjchem-125	30	13	spectrometer	spectrometer	NOUN
eurjchem-125	30	14	(	(	PUNCT
eurjchem-125	30	15	bruker	bruker	PROPN
eurjchem-125	30	16	,	,	PUNCT
eurjchem-125	30	17	faelanden	faelanden	ADJ
eurjchem-125	30	18	,	,	PUNCT
eurjchem-125	30	19	switzerland	switzerland	PROPN
eurjchem-125	30	20	)	)	PUNCT
eurjchem-125	30	21	using	use	VERB
eurjchem-125	30	22	a	a	DET
eurjchem-125	30	23	dual	dual	ADJ
eurjchem-125	30	24	5	5	NUM
eurjchem-125	30	25	mm	mm	NOUN
eurjchem-125	30	26	probe	probe	NOUN
eurjchem-125	30	27	head	head	NOUN
eurjchem-125	30	28	and	and	CCONJ
eurjchem-125	30	29	cdcl3	cdcl3	NOUN
eurjchem-125	30	30	and	and	CCONJ
eurjchem-125	30	31	dmso‐d6	dmso‐d6	NOUN
eurjchem-125	30	32	as	as	ADP
eurjchem-125	30	33	solvents	solvent	NOUN
eurjchem-125	30	34	.	.	PUNCT
eurjchem-125	31	1	chemical	chemical	ADJ
eurjchem-125	31	2	shifts	shift	NOUN
eurjchem-125	31	3	were	be	AUX
eurjchem-125	31	4	expressed	express	VERB
eurjchem-125	31	5	relative	relative	ADJ
eurjchem-125	31	6	to	to	PART
eurjchem-125	31	7	tetramethylsilane	tetramethylsilane	VERB
eurjchem-125	31	8	(	(	PUNCT
eurjchem-125	31	9	tms	tms	PROPN
eurjchem-125	31	10	)	)	PUNCT
eurjchem-125	31	11	and	and	CCONJ
eurjchem-125	31	12	were	be	AUX
eurjchem-125	31	13	reported	report	VERB
eurjchem-125	31	14	as	as	ADP
eurjchem-125	31	15	δ	δ	PROPN
eurjchem-125	31	16	(	(	PUNCT
eurjchem-125	31	17	ppm	ppm	PROPN
eurjchem-125	31	18	)	)	PUNCT
eurjchem-125	31	19	.	.	PUNCT
eurjchem-125	32	1	the	the	DET
eurjchem-125	32	2	measurements	measurement	NOUN
eurjchem-125	32	3	were	be	AUX
eurjchem-125	32	4	carried	carry	VERB
eurjchem-125	32	5	out	out	ADP
eurjchem-125	32	6	at	at	ADP
eurjchem-125	32	7	ambient	ambient	ADJ
eurjchem-125	32	8	temperature	temperature	NOUN
eurjchem-125	32	9	(	(	PUNCT
eurjchem-125	32	10	300	300	NUM
eurjchem-125	32	11	k	k	NOUN
eurjchem-125	32	12	)	)	PUNCT
eurjchem-125	32	13	.	.	PUNCT
eurjchem-125	33	1	typical	typical	ADJ
eurjchem-125	33	2	conditions	condition	NOUN
eurjchem-125	33	3	for	for	ADP
eurjchem-125	33	4	1‐d	1‐d	NUM
eurjchem-125	33	5	1h	1h	NUM
eurjchem-125	33	6	spectra	spectra	PROPN
eurjchem-125	33	7	were	be	AUX
eurjchem-125	33	8	:	:	PUNCT
eurjchem-125	33	9	pulse	pulse	NOUN
eurjchem-125	33	10	width	width	ADJ
eurjchem-125	33	11	30	30	NUM
eurjchem-125	33	12	°	°	NUM
eurjchem-125	33	13	,	,	PUNCT
eurjchem-125	33	14	ft	ft	NOUN
eurjchem-125	33	15	size	size	NOUN
eurjchem-125	33	16	32	32	NUM
eurjchem-125	33	17	k	k	NOUN
eurjchem-125	33	18	and	and	CCONJ
eurjchem-125	33	19	digital	digital	ADJ
eurjchem-125	33	20	resolution	resolution	NOUN
eurjchem-125	33	21	0.2	0.2	NUM
eurjchem-125	33	22	hz	hz	VERB
eurjchem-125	33	23	per	per	ADP
eurjchem-125	33	24	point	point	NOUN
eurjchem-125	33	25	.	.	PUNCT
eurjchem-125	34	1	2	2	X
eurjchem-125	34	2	.	.	X
eurjchem-125	34	3	synthesis	synthesis	NOUN
eurjchem-125	34	4	compounds	compound	NOUN
eurjchem-125	34	5	1	1	NUM
eurjchem-125	34	6	,	,	PUNCT
eurjchem-125	34	7	2	2	NUM
eurjchem-125	34	8	and	and	CCONJ
eurjchem-125	34	9	3	3	NUM
eurjchem-125	34	10	were	be	AUX
eurjchem-125	34	11	prepared	prepare	VERB
eurjchem-125	34	12	according	accord	VERB
eurjchem-125	34	13	the	the	DET
eurjchem-125	34	14	procedure	procedure	NOUN
eurjchem-125	34	15	reported	report	VERB
eurjchem-125	34	16	in	in	ADP
eurjchem-125	34	17	[	[	X
eurjchem-125	34	18	22	22	NUM
eurjchem-125	34	19	]	]	PUNCT
eurjchem-125	34	20	.	.	PUNCT
eurjchem-125	35	1	2.1	2.1	NUM
eurjchem-125	35	2	.	.	PUNCT
eurjchem-125	35	3	general	general	ADJ
eurjchem-125	35	4	procedure	procedure	NOUN
eurjchem-125	35	5	for	for	ADP
eurjchem-125	35	6	compounds	compound	NOUN
eurjchem-125	35	7	4	4	NUM
eurjchem-125	35	8	and	and	CCONJ
eurjchem-125	35	9	6	6	NUM
eurjchem-125	35	10	a	a	DET
eurjchem-125	35	11	three‐necked	three‐necke	VERB
eurjchem-125	35	12	flask	flask	NOUN
eurjchem-125	35	13	equipped	equip	VERB
eurjchem-125	35	14	with	with	ADP
eurjchem-125	35	15	a	a	DET
eurjchem-125	35	16	stirrer	stirrer	NOUN
eurjchem-125	35	17	,	,	PUNCT
eurjchem-125	35	18	condenser	condenser	NOUN
eurjchem-125	35	19	and	and	CCONJ
eurjchem-125	35	20	thermometer	thermometer	NOUN
eurjchem-125	35	21	was	be	AUX
eurjchem-125	35	22	charged	charge	VERB
eurjchem-125	35	23	with	with	ADP
eurjchem-125	35	24	0.05	0.05	NUM
eurjchem-125	35	25	mol	mol	NOUN
eurjchem-125	35	26	(	(	PUNCT
eurjchem-125	35	27	2s,3r	2s,3r	NUM
eurjchem-125	35	28	)	)	PUNCT
eurjchem-125	35	29	or	or	CCONJ
eurjchem-125	35	30	(	(	PUNCT
eurjchem-125	35	31	2r	2r	NUM
eurjchem-125	35	32	,	,	PUNCT
eurjchem-125	35	33	3r)‐2‐methyl‐3‐(thien‐2‐yl)‐3‐hydroxypropanoyl	3r)‐2‐methyl‐3‐(thien‐2‐yl)‐3‐hydroxypropanoyl	NUM
eurjchem-125	35	34	hydrazide	hydrazide	ADJ
eurjchem-125	35	35	(	(	PUNCT
eurjchem-125	35	36	2	2	NUM
eurjchem-125	35	37	or	or	CCONJ
eurjchem-125	35	38	3	3	NUM
eurjchem-125	35	39	)	)	PUNCT
eurjchem-125	35	40	,	,	PUNCT
eurjchem-125	35	41	solution	solution	NOUN
eurjchem-125	35	42	of	of	ADP
eurjchem-125	35	43	3.2	3.2	NUM
eurjchem-125	35	44	ml	ml	ADV
eurjchem-125	35	45	acetic	acetic	ADJ
eurjchem-125	35	46	acid	acid	NOUN
eurjchem-125	35	47	in	in	ADP
eurjchem-125	35	48	100	100	NUM
eurjchem-125	35	49	ml	ml	NOUN
eurjchem-125	35	50	water	water	NOUN
eurjchem-125	35	51	and	and	CCONJ
eurjchem-125	35	52	120	120	NUM
eurjchem-125	35	53	ml	ml	NOUN
eurjchem-125	35	54	diethyl	diethyl	NOUN
eurjchem-125	35	55	ether	ether	NOUN
eurjchem-125	35	56	.	.	PUNCT
eurjchem-125	36	1	to	to	ADP
eurjchem-125	36	2	the	the	DET
eurjchem-125	36	3	formed	form	VERB
eurjchem-125	36	4	suspension	suspension	NOUN
eurjchem-125	36	5	a	a	DET
eurjchem-125	36	6	solution	solution	NOUN
eurjchem-125	36	7	of	of	ADP
eurjchem-125	36	8	3.8	3.8	NUM
eurjchem-125	36	9	g	g	NOUN
eurjchem-125	36	10	sodium	sodium	NOUN
eurjchem-125	36	11	nitrite	nitrite	NOUN
eurjchem-125	36	12	in	in	ADP
eurjchem-125	36	13	30	30	NUM
eurjchem-125	36	14	ml	ml	NOUN
eurjchem-125	36	15	water	water	NOUN
eurjchem-125	36	16	was	be	AUX
eurjchem-125	36	17	added	add	VERB
eurjchem-125	36	18	drop	drop	NOUN
eurjchem-125	36	19	wise	wise	ADJ
eurjchem-125	36	20	at	at	ADP
eurjchem-125	36	21	15‐20	15‐20	NUM
eurjchem-125	36	22	°	°	NOUN
eurjchem-125	36	23	c	c	NOUN
eurjchem-125	36	24	by	by	ADP
eurjchem-125	36	25	stirring	stir	VERB
eurjchem-125	36	26	for	for	ADP
eurjchem-125	36	27	20	20	NUM
eurjchem-125	36	28	minutes	minute	NOUN
eurjchem-125	36	29	.	.	PUNCT
eurjchem-125	37	1	the	the	DET
eurjchem-125	37	2	reaction	reaction	NOUN
eurjchem-125	37	3	mixture	mixture	NOUN
eurjchem-125	37	4	was	be	AUX
eurjchem-125	37	5	stirred	stir	VERB
eurjchem-125	37	6	at	at	ADP
eurjchem-125	37	7	the	the	DET
eurjchem-125	37	8	above	above	ADJ
eurjchem-125	37	9	mentioned	mention	VERB
eurjchem-125	37	10	temperature	temperature	NOUN
eurjchem-125	37	11	up	up	ADP
eurjchem-125	37	12	to	to	ADP
eurjchem-125	37	13	the	the	DET
eurjchem-125	37	14	full	full	ADJ
eurjchem-125	37	15	disappearance	disappearance	NOUN
eurjchem-125	37	16	of	of	ADP
eurjchem-125	37	17	the	the	DET
eurjchem-125	37	18	solid	solid	ADJ
eurjchem-125	37	19	phase	phase	NOUN
eurjchem-125	37	20	,	,	PUNCT
eurjchem-125	37	21	about	about	ADV
eurjchem-125	37	22	2	2	NUM
eurjchem-125	37	23	or	or	CCONJ
eurjchem-125	37	24	3	3	NUM
eurjchem-125	37	25	hours	hour	NOUN
eurjchem-125	37	26	.	.	PUNCT
eurjchem-125	38	1	after	after	SCONJ
eurjchem-125	38	2	neutralization	neutralization	NOUN
eurjchem-125	38	3	with	with	ADP
eurjchem-125	38	4	10	10	NUM
eurjchem-125	38	5	%	%	NOUN
eurjchem-125	38	6	solution	solution	NOUN
eurjchem-125	38	7	of	of	ADP
eurjchem-125	38	8	sodium	sodium	NOUN
eurjchem-125	38	9	hydrogen	hydrogen	NOUN
eurjchem-125	38	10	carbonate	carbonate	NOUN
eurjchem-125	38	11	the	the	DET
eurjchem-125	38	12	aqueous	aqueous	ADJ
eurjchem-125	38	13	and	and	CCONJ
eurjchem-125	38	14	organic	organic	ADJ
eurjchem-125	38	15	layers	layer	NOUN
eurjchem-125	38	16	were	be	AUX
eurjchem-125	38	17	separated	separate	VERB
eurjchem-125	38	18	.	.	PUNCT
eurjchem-125	39	1	the	the	DET
eurjchem-125	39	2	aqueous	aqueous	ADJ
eurjchem-125	39	3	layer	layer	NOUN
eurjchem-125	39	4	was	be	AUX
eurjchem-125	39	5	extracted	extract	VERB
eurjchem-125	39	6	several	several	ADJ
eurjchem-125	39	7	times	time	NOUN
eurjchem-125	39	8	with	with	ADP
eurjchem-125	39	9	benzene	benzene	NOUN
eurjchem-125	39	10	and	and	CCONJ
eurjchem-125	39	11	diethyl	diethyl	NOUN
eurjchem-125	39	12	ether	ether	NOUN
eurjchem-125	39	13	.	.	PUNCT
eurjchem-125	40	1	the	the	DET
eurjchem-125	40	2	collected	collect	VERB
eurjchem-125	40	3	organic	organic	ADJ
eurjchem-125	40	4	layers	layer	NOUN
eurjchem-125	40	5	were	be	AUX
eurjchem-125	40	6	dried	dry	VERB
eurjchem-125	40	7	with	with	ADP
eurjchem-125	40	8	sodium	sodium	NOUN
eurjchem-125	40	9	sulphate	sulphate	NOUN
eurjchem-125	40	10	and	and	CCONJ
eurjchem-125	40	11	after	after	ADP
eurjchem-125	40	12	filtering	filter	VERB
eurjchem-125	40	13	the	the	DET
eurjchem-125	40	14	solution	solution	NOUN
eurjchem-125	40	15	was	be	AUX
eurjchem-125	40	16	concentrated	concentrate	VERB
eurjchem-125	40	17	under	under	ADP
eurjchem-125	40	18	reduced	reduce	VERB
eurjchem-125	40	19	pressure	pressure	NOUN
eurjchem-125	40	20	to	to	ADP
eurjchem-125	40	21	20‐25	20‐25	NUM
eurjchem-125	40	22	ml	ml	NOUN
eurjchem-125	40	23	of	of	ADP
eurjchem-125	40	24	the	the	DET
eurjchem-125	40	25	original	original	ADJ
eurjchem-125	40	26	volume	volume	NOUN
eurjchem-125	40	27	.	.	PUNCT
eurjchem-125	41	1	4‐methyl‐5‐	4‐methyl‐5‐	PROPN
eurjchem-125	41	2	(	(	PUNCT
eurjchem-125	41	3	thien‐2‐yl)‐oxazolidine‐2‐ones	thien‐2‐yl)‐oxazolidine‐2‐one	NOUN
eurjchem-125	41	4	,	,	PUNCT
eurjchem-125	41	5	(	(	PUNCT
eurjchem-125	41	6	4	4	NUM
eurjchem-125	41	7	,	,	PUNCT
eurjchem-125	41	8	6	6	NUM
eurjchem-125	41	9	)	)	PUNCT
eurjchem-125	41	10	crystallized	crystallize	VERB
eurjchem-125	41	11	after	after	ADP
eurjchem-125	41	12	cooling	cool	VERB
eurjchem-125	41	13	of	of	ADP
eurjchem-125	41	14	the	the	DET
eurjchem-125	41	15	remained	remain	VERB
eurjchem-125	41	16	residue	residue	NOUN
eurjchem-125	41	17	.	.	PUNCT
eurjchem-125	42	1	the	the	DET
eurjchem-125	42	2	compounds	compound	NOUN
eurjchem-125	42	3	were	be	AUX
eurjchem-125	42	4	re‐crystallized	re‐crystallize	VERB
eurjchem-125	42	5	with	with	ADP
eurjchem-125	42	6	benzene	benzene	NOUN
eurjchem-125	42	7	.	.	PUNCT
eurjchem-125	43	1	anti‐4‐methyl‐5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	anti‐4‐methyl‐5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	43	2	,	,	PUNCT
eurjchem-125	43	3	4	4	NUM
eurjchem-125	43	4	:	:	PUNCT
eurjchem-125	43	5	yield	yield	NOUN
eurjchem-125	43	6	:	:	PUNCT
eurjchem-125	43	7	70	70	NUM
eurjchem-125	43	8	%	%	NOUN
eurjchem-125	43	9	.	.	PUNCT
eurjchem-125	44	1	m.p	m.p	PROPN
eurjchem-125	44	2	.	.	PROPN
eurjchem-125	44	3	:	:	PUNCT
eurjchem-125	44	4	87‐90	87‐90	PROPN
eurjchem-125	44	5	°	°	ADP
eurjchem-125	44	6	c	c	VERB
eurjchem-125	44	7	.	.	PUNCT
eurjchem-125	45	1	rf	rf	VERB
eurjchem-125	45	2	=	=	NOUN
eurjchem-125	45	3	0.66	0.66	NUM
eurjchem-125	45	4	,	,	PUNCT
eurjchem-125	45	5	mobile	mobile	ADJ
eurjchem-125	45	6	phase	phase	NOUN
eurjchem-125	45	7	:	:	PUNCT
eurjchem-125	45	8	benzene	benzene	NOUN
eurjchem-125	45	9	:	:	PUNCT
eurjchem-125	45	10	diethyl	diethyl	NOUN
eurjchem-125	45	11	ether	ether	NOUN
eurjchem-125	45	12	(	(	PUNCT
eurjchem-125	45	13	1:1	1:1	NUM
eurjchem-125	45	14	)	)	PUNCT
eurjchem-125	45	15	.	.	PUNCT
eurjchem-125	46	1	1h	1h	NUM
eurjchem-125	46	2	nmr	nmr	NOUN
eurjchem-125	46	3	(	(	PUNCT
eurjchem-125	46	4	cdcl3	cdcl3	NOUN
eurjchem-125	46	5	):	):	PUNCT
eurjchem-125	46	6	1.33	1.33	NUM
eurjchem-125	46	7	(	(	PUNCT
eurjchem-125	46	8	3h	3h	NUM
eurjchem-125	46	9	,	,	PUNCT
eurjchem-125	46	10	ch3	ch3	PROPN
eurjchem-125	46	11	,	,	PUNCT
eurjchem-125	46	12	d	d	PROPN
eurjchem-125	46	13	,	,	PUNCT
eurjchem-125	46	14	j=6.2	j=6.2	NOUN
eurjchem-125	46	15	hz	hz	NOUN
eurjchem-125	46	16	)	)	PUNCT
eurjchem-125	46	17	;	;	PUNCT
eurjchem-125	46	18	3.98	3.98	NUM
eurjchem-125	46	19	(	(	PUNCT
eurjchem-125	46	20	1h	1h	NUM
eurjchem-125	46	21	,	,	PUNCT
eurjchem-125	46	22	n‐ch	n‐ch	NOUN
eurjchem-125	46	23	,	,	PUNCT
eurjchem-125	46	24	dq	dq	NOUN
eurjchem-125	46	25	,	,	PUNCT
eurjchem-125	46	26	j=7.7	j=7.7	PROPN
eurjchem-125	46	27	,	,	PUNCT
eurjchem-125	46	28	j=6.2	j=6.2	NOUN
eurjchem-125	46	29	hz	hz	NOUN
eurjchem-125	46	30	)	)	PUNCT
eurjchem-125	46	31	;	;	PUNCT
eurjchem-125	46	32	5.16	5.16	NUM
eurjchem-125	46	33	(	(	PUNCT
eurjchem-125	46	34	1h	1h	NUM
eurjchem-125	46	35	,	,	PUNCT
eurjchem-125	46	36	och	och	NUM
eurjchem-125	46	37	,	,	PUNCT
eurjchem-125	46	38	d	d	NOUN
eurjchem-125	46	39	,	,	PUNCT
eurjchem-125	46	40	j=7.7	j=7.7	ADJ
eurjchem-125	46	41	)	)	PUNCT
eurjchem-125	46	42	,	,	PUNCT
eurjchem-125	46	43	6.66‐	6.66‐	NUM
eurjchem-125	46	44	6.64	6.64	NUM
eurjchem-125	46	45	(	(	PUNCT
eurjchem-125	46	46	2h	2h	NUM
eurjchem-125	46	47	,	,	PUNCT
eurjchem-125	46	48	2ch	2ch	ADJ
eurjchem-125	46	49	,	,	PUNCT
eurjchem-125	46	50	m	m	NOUN
eurjchem-125	46	51	,	,	PUNCT
eurjchem-125	46	52	thiophene	thiophene	NOUN
eurjchem-125	46	53	)	)	PUNCT
eurjchem-125	46	54	,	,	PUNCT
eurjchem-125	46	55	6.92	6.92	NUM
eurjchem-125	46	56	(	(	PUNCT
eurjchem-125	46	57	1h	1h	NUM
eurjchem-125	46	58	,	,	PUNCT
eurjchem-125	46	59	ch	ch	NOUN
eurjchem-125	46	60	,	,	PUNCT
eurjchem-125	46	61	d	d	PROPN
eurjchem-125	46	62	,	,	PUNCT
eurjchem-125	46	63	j=4.5	j=4.5	PROPN
eurjchem-125	46	64	hz	hz	NOUN
eurjchem-125	46	65	,	,	PUNCT
eurjchem-125	46	66	thiophene	thiophene	NOUN
eurjchem-125	46	67	)	)	PUNCT
eurjchem-125	46	68	.	.	PUNCT
eurjchem-125	47	1	13c	13c	NOUN
eurjchem-125	47	2	nmr	nmr	NOUN
eurjchem-125	47	3	(	(	PUNCT
eurjchem-125	47	4	cdcl3	cdcl3	NOUN
eurjchem-125	47	5	):	):	PUNCT
eurjchem-125	47	6	15.4	15.4	NUM
eurjchem-125	47	7	(	(	PUNCT
eurjchem-125	47	8	ch3	ch3	PROPN
eurjchem-125	47	9	)	)	PUNCT
eurjchem-125	47	10	,	,	PUNCT
eurjchem-125	47	11	56.5	56.5	NUM
eurjchem-125	47	12	(	(	PUNCT
eurjchem-125	47	13	nch	nch	NOUN
eurjchem-125	47	14	)	)	PUNCT
eurjchem-125	47	15	,	,	PUNCT
eurjchem-125	47	16	81.5	81.5	NUM
eurjchem-125	47	17	(	(	PUNCT
eurjchem-125	47	18	och	och	NOUN
eurjchem-125	47	19	)	)	PUNCT
eurjchem-125	47	20	,	,	PUNCT
eurjchem-125	47	21	125.0	125.0	NUM
eurjchem-125	47	22	,	,	PUNCT
eurjchem-125	47	23	126.0	126.0	NUM
eurjchem-125	47	24	,	,	PUNCT
eurjchem-125	47	25	127.2	127.2	NUM
eurjchem-125	47	26	(	(	PUNCT
eurjchem-125	47	27	3ch	3ch	ADJ
eurjchem-125	47	28	,	,	PUNCT
eurjchem-125	47	29	thiophene	thiophene	NOUN
eurjchem-125	47	30	)	)	PUNCT
eurjchem-125	47	31	,	,	PUNCT
eurjchem-125	47	32	136.8	136.8	NUM
eurjchem-125	47	33	,	,	PUNCT
eurjchem-125	47	34	137.2	137.2	NUM
eurjchem-125	47	35	(	(	PUNCT
eurjchem-125	47	36	c	c	NOUN
eurjchem-125	47	37	,	,	PUNCT
eurjchem-125	47	38	thiophene	thiophene	NOUN
eurjchem-125	47	39	)	)	PUNCT
eurjchem-125	47	40	;	;	PUNCT
eurjchem-125	47	41	158.7	158.7	NUM
eurjchem-125	47	42	(	(	PUNCT
eurjchem-125	47	43	c	c	NOUN
eurjchem-125	47	44	=	=	NOUN
eurjchem-125	47	45	o	o	NOUN
eurjchem-125	47	46	)	)	PUNCT
eurjchem-125	47	47	.	.	PUNCT
eurjchem-125	48	1	anal	anal	PROPN
eurjchem-125	48	2	.	.	PUNCT
eurjchem-125	48	3	calcd	calcd	NOUN
eurjchem-125	48	4	.	.	PUNCT
eurjchem-125	49	1	for	for	ADP
eurjchem-125	49	2	c8h9no2s	c8h9no2s	PROPN
eurjchem-125	49	3	:	:	PUNCT
eurjchem-125	49	4	c	c	NOUN
eurjchem-125	49	5	,	,	PUNCT
eurjchem-125	49	6	52.44	52.44	NUM
eurjchem-125	49	7	;	;	PUNCT
eurjchem-125	49	8	h	h	NOUN
eurjchem-125	49	9	,	,	PUNCT
eurjchem-125	49	10	4.95	4.95	NUM
eurjchem-125	49	11	;	;	PUNCT
eurjchem-125	49	12	n	n	CCONJ
eurjchem-125	49	13	,	,	PUNCT
eurjchem-125	49	14	7.64	7.64	NUM
eurjchem-125	49	15	;	;	PUNCT
eurjchem-125	49	16	s	s	NUM
eurjchem-125	49	17	,	,	PUNCT
eurjchem-125	49	18	17.50	17.50	NUM
eurjchem-125	49	19	;	;	PUNCT
eurjchem-125	49	20	found	find	VERB
eurjchem-125	49	21	:	:	PUNCT
eurjchem-125	49	22	c	c	X
eurjchem-125	49	23	,	,	PUNCT
eurjchem-125	49	24	52.40	52.40	NUM
eurjchem-125	49	25	;	;	PUNCT
eurjchem-125	49	26	h	h	NOUN
eurjchem-125	49	27	,	,	PUNCT
eurjchem-125	49	28	4.91	4.91	NUM
eurjchem-125	49	29	;	;	PUNCT
eurjchem-125	49	30	n	n	CCONJ
eurjchem-125	49	31	,	,	PUNCT
eurjchem-125	49	32	7.69	7.69	NUM
eurjchem-125	49	33	;	;	PUNCT
eurjchem-125	49	34	s	s	NUM
eurjchem-125	49	35	,	,	PUNCT
eurjchem-125	49	36	17.46	17.46	NUM
eurjchem-125	49	37	.	.	PUNCT
eurjchem-125	50	1	syn‐4‐methyl‐5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	syn‐4‐methyl‐5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	50	2	,	,	PUNCT
eurjchem-125	50	3	6	6	NUM
eurjchem-125	50	4	:	:	PUNCT
eurjchem-125	50	5	yield	yield	NOUN
eurjchem-125	50	6	:	:	PUNCT
eurjchem-125	50	7	65	65	NUM
eurjchem-125	50	8	%	%	NOUN
eurjchem-125	50	9	.	.	PUNCT
eurjchem-125	51	1	m.p	m.p	PROPN
eurjchem-125	51	2	.	.	PROPN
eurjchem-125	51	3	:	:	PUNCT
eurjchem-125	52	1	101‐102	101‐102	NUM
eurjchem-125	52	2	°	°	SYM
eurjchem-125	52	3	c	c	VERB
eurjchem-125	52	4	.	.	PUNCT
eurjchem-125	53	1	rf	rf	VERB
eurjchem-125	53	2	=	=	NOUN
eurjchem-125	53	3	0.50	0.50	NUM
eurjchem-125	53	4	,	,	PUNCT
eurjchem-125	53	5	mobile	mobile	ADJ
eurjchem-125	53	6	phase	phase	NOUN
eurjchem-125	53	7	:	:	PUNCT
eurjchem-125	53	8	benzene	benzene	NOUN
eurjchem-125	53	9	:	:	PUNCT
eurjchem-125	53	10	diethyl	diethyl	NOUN
eurjchem-125	53	11	ether	ether	NOUN
eurjchem-125	53	12	(	(	PUNCT
eurjchem-125	53	13	1:1	1:1	NUM
eurjchem-125	53	14	)	)	PUNCT
eurjchem-125	53	15	,	,	PUNCT
eurjchem-125	53	16	al2o3‐plates	al2o3‐plates	PROPN
eurjchem-125	53	17	.	.	PUNCT
eurjchem-125	54	1	1h	1h	NUM
eurjchem-125	54	2	nmr	nmr	NOUN
eurjchem-125	54	3	(	(	PUNCT
eurjchem-125	54	4	cdcl3	cdcl3	NOUN
eurjchem-125	54	5	):	):	PUNCT
eurjchem-125	54	6	0.99	0.99	NUM
eurjchem-125	54	7	(	(	PUNCT
eurjchem-125	54	8	3h	3h	NUM
eurjchem-125	54	9	,	,	PUNCT
eurjchem-125	54	10	ch3	ch3	PROPN
eurjchem-125	54	11	,	,	PUNCT
eurjchem-125	54	12	d	d	PROPN
eurjchem-125	54	13	,	,	PUNCT
eurjchem-125	54	14	j=6.60	j=6.60	PROPN
eurjchem-125	54	15	hz	hz	NOUN
eurjchem-125	54	16	)	)	PUNCT
eurjchem-125	54	17	;	;	PUNCT
eurjchem-125	54	18	4.22	4.22	NUM
eurjchem-125	54	19	(	(	PUNCT
eurjchem-125	54	20	1h	1h	NUM
eurjchem-125	54	21	,	,	PUNCT
eurjchem-125	54	22	n‐ch	n‐ch	NOUN
eurjchem-125	54	23	,	,	PUNCT
eurjchem-125	54	24	dq	dq	PROPN
eurjchem-125	54	25	,	,	PUNCT
eurjchem-125	54	26	j=8.07	j=8.07	X
eurjchem-125	54	27	hz	hz	PROPN
eurjchem-125	54	28	,	,	PUNCT
eurjchem-125	54	29	j=6.60	j=6.60	PROPN
eurjchem-125	54	30	hz	hz	NOUN
eurjchem-125	54	31	)	)	PUNCT
eurjchem-125	54	32	,	,	PUNCT
eurjchem-125	54	33	5.91	5.91	NUM
eurjchem-125	54	34	(	(	PUNCT
eurjchem-125	54	35	1h	1h	NUM
eurjchem-125	54	36	,	,	PUNCT
eurjchem-125	54	37	och	och	NUM
eurjchem-125	54	38	,	,	PUNCT
eurjchem-125	54	39	d	d	PROPN
eurjchem-125	54	40	,	,	PUNCT
eurjchem-125	54	41	j=8.07	j=8.07	X
eurjchem-125	54	42	hz	hz	PROPN
eurjchem-125	54	43	)	)	PUNCT
eurjchem-125	54	44	,	,	PUNCT
eurjchem-125	54	45	6.54	6.54	NUM
eurjchem-125	54	46	(	(	PUNCT
eurjchem-125	54	47	1h	1h	NUM
eurjchem-125	54	48	,	,	PUNCT
eurjchem-125	54	49	nh	nh	PROPN
eurjchem-125	54	50	,	,	PUNCT
eurjchem-125	54	51	bs	bs	NOUN
eurjchem-125	54	52	)	)	PUNCT
eurjchem-125	54	53	,	,	PUNCT
eurjchem-125	54	54	7.10–6.99	7.10–6.99	NUM
eurjchem-125	54	55	(	(	PUNCT
eurjchem-125	54	56	2h	2h	NUM
eurjchem-125	54	57	,	,	PUNCT
eurjchem-125	54	58	2ch	2ch	ADJ
eurjchem-125	54	59	,	,	PUNCT
eurjchem-125	54	60	m	m	NOUN
eurjchem-125	54	61	,	,	PUNCT
eurjchem-125	54	62	thiophene	thiophene	NOUN
eurjchem-125	54	63	)	)	PUNCT
eurjchem-125	54	64	,	,	PUNCT
eurjchem-125	54	65	7.34	7.34	NUM
eurjchem-125	54	66	(	(	PUNCT
eurjchem-125	54	67	1h	1h	NUM
eurjchem-125	54	68	,	,	PUNCT
eurjchem-125	54	69	ch	ch	NOUN
eurjchem-125	54	70	,	,	PUNCT
eurjchem-125	54	71	dd	dd	NOUN
eurjchem-125	54	72	,	,	PUNCT
eurjchem-125	54	73	j=1.71	j=1.71	PROPN
eurjchem-125	54	74	hz	hz	VERB
eurjchem-125	54	75	,	,	PUNCT
eurjchem-125	54	76	j=4.52	j=4.52	PROPN
eurjchem-125	54	77	hz	hz	PROPN
eurjchem-125	54	78	,	,	PUNCT
eurjchem-125	54	79	thiophene	thiophene	NOUN
eurjchem-125	54	80	)	)	PUNCT
eurjchem-125	54	81	.	.	PUNCT
eurjchem-125	55	1	13c	13c	NOUN
eurjchem-125	55	2	nmr	nmr	NOUN
eurjchem-125	55	3	(	(	PUNCT
eurjchem-125	55	4	cdcl3	cdcl3	NOUN
eurjchem-125	55	5	):	):	PUNCT
eurjchem-125	55	6	16.8	16.8	NUM
eurjchem-125	55	7	(	(	PUNCT
eurjchem-125	55	8	ch3	ch3	PROPN
eurjchem-125	55	9	)	)	PUNCT
eurjchem-125	55	10	,	,	PUNCT
eurjchem-125	55	11	52.5	52.5	NUM
eurjchem-125	55	12	(	(	PUNCT
eurjchem-125	55	13	nch	nch	NOUN
eurjchem-125	55	14	)	)	PUNCT
eurjchem-125	55	15	,	,	PUNCT
eurjchem-125	55	16	78.1	78.1	NUM
eurjchem-125	55	17	(	(	PUNCT
eurjchem-125	55	18	och	och	NOUN
eurjchem-125	55	19	)	)	PUNCT
eurjchem-125	55	20	,	,	PUNCT
eurjchem-125	55	21	125.8	125.8	NUM
eurjchem-125	55	22	,	,	PUNCT
eurjchem-125	55	23	126.0	126.0	NUM
eurjchem-125	55	24	,	,	PUNCT
eurjchem-125	55	25	126.8	126.8	NUM
eurjchem-125	55	26	(	(	PUNCT
eurjchem-125	55	27	3ch	3ch	ADJ
eurjchem-125	55	28	,	,	PUNCT
eurjchem-125	55	29	thiophene	thiophene	NOUN
eurjchem-125	55	30	)	)	PUNCT
eurjchem-125	55	31	,	,	PUNCT
eurjchem-125	55	32	137.2	137.2	NUM
eurjchem-125	55	33	(	(	PUNCT
eurjchem-125	55	34	c	c	NOUN
eurjchem-125	55	35	,	,	PUNCT
eurjchem-125	55	36	thiophene	thiophene	NOUN
eurjchem-125	55	37	)	)	PUNCT
eurjchem-125	55	38	,	,	PUNCT
eurjchem-125	55	39	159.1	159.1	NUM
eurjchem-125	55	40	(	(	PUNCT
eurjchem-125	55	41	c	c	NOUN
eurjchem-125	55	42	=	=	NOUN
eurjchem-125	55	43	o	o	NOUN
eurjchem-125	55	44	)	)	PUNCT
eurjchem-125	55	45	.	.	PUNCT
eurjchem-125	56	1	anal	anal	PROPN
eurjchem-125	56	2	.	.	PUNCT
eurjchem-125	56	3	calcd	calcd	NOUN
eurjchem-125	56	4	.	.	PUNCT
eurjchem-125	57	1	for	for	ADP
eurjchem-125	57	2	c8h9no2s	c8h9no2s	PROPN
eurjchem-125	57	3	:	:	PUNCT
eurjchem-125	57	4	c	c	NOUN
eurjchem-125	57	5	,	,	PUNCT
eurjchem-125	57	6	52.44	52.44	NUM
eurjchem-125	57	7	;	;	PUNCT
eurjchem-125	57	8	h	h	NOUN
eurjchem-125	57	9	,	,	PUNCT
eurjchem-125	57	10	4.95	4.95	NUM
eurjchem-125	57	11	;	;	PUNCT
eurjchem-125	57	12	n	n	CCONJ
eurjchem-125	57	13	,	,	PUNCT
eurjchem-125	57	14	7.64	7.64	NUM
eurjchem-125	57	15	;	;	PUNCT
eurjchem-125	57	16	s	s	NUM
eurjchem-125	57	17	,	,	PUNCT
eurjchem-125	57	18	17.50	17.50	NUM
eurjchem-125	57	19	;	;	PUNCT
eurjchem-125	57	20	found	find	VERB
eurjchem-125	57	21	:	:	PUNCT
eurjchem-125	57	22	c	c	X
eurjchem-125	57	23	,	,	PUNCT
eurjchem-125	57	24	52.38	52.38	NUM
eurjchem-125	57	25	;	;	PUNCT
eurjchem-125	57	26	h	h	NOUN
eurjchem-125	57	27	,	,	PUNCT
eurjchem-125	57	28	5.05	5.05	NUM
eurjchem-125	57	29	;	;	PUNCT
eurjchem-125	57	30	n	n	CCONJ
eurjchem-125	57	31	,	,	PUNCT
eurjchem-125	57	32	7.60	7.60	NUM
eurjchem-125	57	33	;	;	PUNCT
eurjchem-125	57	34	s	s	NUM
eurjchem-125	57	35	,	,	PUNCT
eurjchem-125	57	36	17.37	17.37	NUM
eurjchem-125	57	37	.	.	PUNCT
eurjchem-125	58	1	2.2	2.2	NUM
eurjchem-125	58	2	.	.	PUNCT
eurjchem-125	58	3	general	general	ADJ
eurjchem-125	58	4	procedure	procedure	NOUN
eurjchem-125	58	5	for	for	ADP
eurjchem-125	58	6	compounds	compound	NOUN
eurjchem-125	58	7	5e	5e	NOUN
eurjchem-125	58	8	and	and	CCONJ
eurjchem-125	58	9	7e	7e	NUM
eurjchem-125	58	10	to	to	ADP
eurjchem-125	58	11	a	a	DET
eurjchem-125	58	12	solution	solution	NOUN
eurjchem-125	58	13	of	of	ADP
eurjchem-125	58	14	1	1	NUM
eurjchem-125	58	15	g	g	NOUN
eurjchem-125	58	16	(	(	PUNCT
eurjchem-125	58	17	5.5	5.5	NUM
eurjchem-125	58	18	mmol	mmol	NOUN
eurjchem-125	58	19	)	)	PUNCT
eurjchem-125	58	20	of	of	ADP
eurjchem-125	58	21	the	the	DET
eurjchem-125	58	22	anti‐4‐methyl‐5‐	anti‐4‐methyl‐5‐	NOUN
eurjchem-125	58	23	thien‐2‐yl‐1,3‐oxazolidin‐2‐one	thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	58	24	4	4	NUM
eurjchem-125	58	25	or	or	CCONJ
eurjchem-125	58	26	to	to	ADP
eurjchem-125	58	27	a	a	DET
eurjchem-125	58	28	solution	solution	NOUN
eurjchem-125	58	29	of	of	ADP
eurjchem-125	58	30	1	1	NUM
eurjchem-125	58	31	g	g	NOUN
eurjchem-125	58	32	(	(	PUNCT
eurjchem-125	58	33	5.5	5.5	NUM
eurjchem-125	58	34	mmol	mmol	NOUN
eurjchem-125	58	35	)	)	PUNCT
eurjchem-125	58	36	of	of	ADP
eurjchem-125	58	37	the	the	DET
eurjchem-125	58	38	syn‐isomer	syn‐isomer	NOUN
eurjchem-125	58	39	6	6	NUM
eurjchem-125	58	40	in	in	ADP
eurjchem-125	58	41	40	40	NUM
eurjchem-125	58	42	ml	ml	NOUN
eurjchem-125	58	43	ethanol	ethanol	NOUN
eurjchem-125	58	44	were	be	AUX
eurjchem-125	58	45	added	add	VERB
eurjchem-125	58	46	0.53	0.53	NUM
eurjchem-125	58	47	g	g	NOUN
eurjchem-125	58	48	(	(	PUNCT
eurjchem-125	58	49	2.7	2.7	NUM
eurjchem-125	58	50	mmol	mmol	NOUN
eurjchem-125	58	51	)	)	PUNCT
eurjchem-125	58	52	piperazine	piperazine	NOUN
eurjchem-125	58	53	hexahydrate	hexahydrate	NOUN
eurjchem-125	58	54	and	and	CCONJ
eurjchem-125	58	55	0.54	0.54	NUM
eurjchem-125	58	56	ml	ml	NOUN
eurjchem-125	58	57	(	(	PUNCT
eurjchem-125	58	58	6.8	6.8	NUM
eurjchem-125	58	59	mmol	mmol	NOUN
eurjchem-125	58	60	)	)	PUNCT
eurjchem-125	58	61	formaldehyde	formaldehyde	NOUN
eurjchem-125	58	62	in	in	ADP
eurjchem-125	58	63	form	form	NOUN
eurjchem-125	58	64	of	of	ADP
eurjchem-125	58	65	35	35	NUM
eurjchem-125	58	66	%	%	NOUN
eurjchem-125	58	67	.	.	PUNCT
eurjchem-125	59	1	the	the	DET
eurjchem-125	59	2	solution	solution	NOUN
eurjchem-125	59	3	was	be	AUX
eurjchem-125	59	4	refluxed	refluxe	VERB
eurjchem-125	59	5	for	for	ADP
eurjchem-125	59	6	2	2	NUM
eurjchem-125	59	7	hours	hour	NOUN
eurjchem-125	59	8	and	and	CCONJ
eurjchem-125	59	9	after	after	SCONJ
eurjchem-125	59	10	that	that	DET
eurjchem-125	59	11	ethanol	ethanol	NOUN
eurjchem-125	59	12	was	be	AUX
eurjchem-125	59	13	distilled	distil	VERB
eurjchem-125	59	14	in	in	ADP
eurjchem-125	59	15	vacuum	vacuum	NOUN
eurjchem-125	59	16	to	to	ADP
eurjchem-125	59	17	5‐10	5‐10	NUM
eurjchem-125	59	18	ml	ml	NOUN
eurjchem-125	59	19	of	of	ADP
eurjchem-125	59	20	original	original	ADJ
eurjchem-125	59	21	volume	volume	NOUN
eurjchem-125	59	22	.	.	PUNCT
eurjchem-125	60	1	the	the	DET
eurjchem-125	60	2	obtained	obtain	VERB
eurjchem-125	60	3	mannich	mannich	DET
eurjchem-125	60	4	base	base	NOUN
eurjchem-125	60	5	crystallized	crystallize	VERB
eurjchem-125	60	6	upon	upon	SCONJ
eurjchem-125	60	7	cooling	cool	VERB
eurjchem-125	60	8	and	and	CCONJ
eurjchem-125	60	9	was	be	AUX
eurjchem-125	60	10	re‐crystallized	re‐crystallize	VERB
eurjchem-125	60	11	with	with	ADP
eurjchem-125	60	12	ethanol	ethanol	NOUN
eurjchem-125	60	13	.	.	PUNCT
eurjchem-125	61	1	anti‐1,4‐bis[(4‐methyl‐5‐thien‐2‐yl‐2‐oxo‐1,3‐oxazolidin‐3‐	anti‐1,4‐bis[(4‐methyl‐5‐thien‐2‐yl‐2‐oxo‐1,3‐oxazolidin‐3‐	PROPN
eurjchem-125	61	2	yl)methyl	yl)methyl	NOUN
eurjchem-125	61	3	]	]	PUNCT
eurjchem-125	61	4	piperazine	piperazine	NOUN
eurjchem-125	61	5	,	,	PUNCT
eurjchem-125	61	6	5e	5e	NOUN
eurjchem-125	61	7	:	:	PUNCT
eurjchem-125	61	8	yield	yield	NOUN
eurjchem-125	61	9	:	:	PUNCT
eurjchem-125	61	10	56	56	NUM
eurjchem-125	61	11	%	%	NOUN
eurjchem-125	61	12	.	.	PUNCT
eurjchem-125	62	1	m.p	m.p	PROPN
eurjchem-125	62	2	.	.	PROPN
eurjchem-125	62	3	:	:	PUNCT
eurjchem-125	63	1	145‐147	145‐147	PROPN
eurjchem-125	63	2	°	°	PROPN
eurjchem-125	63	3	c	c	X
eurjchem-125	63	4	(	(	PUNCT
eurjchem-125	63	5	decomp	decomp	NOUN
eurjchem-125	63	6	.	.	PUNCT
eurjchem-125	63	7	)	)	PUNCT
eurjchem-125	63	8	.	.	PUNCT
eurjchem-125	64	1	rf	rf	PRON
eurjchem-125	64	2	=	=	NOUN
eurjchem-125	64	3	0.65	0.65	NUM
eurjchem-125	64	4	,	,	PUNCT
eurjchem-125	64	5	mobile	mobile	ADJ
eurjchem-125	64	6	phase	phase	NOUN
eurjchem-125	64	7	:	:	PUNCT
eurjchem-125	64	8	bezene	bezene	NOUN
eurjchem-125	64	9	:	:	PUNCT
eurjchem-125	64	10	diethyl	diethyl	NOUN
eurjchem-125	64	11	ether	ether	NOUN
eurjchem-125	64	12	:	:	PUNCT
eurjchem-125	64	13	ethanol	ethanol	NOUN
eurjchem-125	64	14	(	(	PUNCT
eurjchem-125	64	15	4:1:3	4:1:3	NUM
eurjchem-125	64	16	)	)	PUNCT
eurjchem-125	64	17	,	,	PUNCT
eurjchem-125	64	18	al2o3‐plates	al2o3‐plates	PROPN
eurjchem-125	64	19	.	.	PUNCT
eurjchem-125	65	1	1h	1h	NUM
eurjchem-125	65	2	nmr	nmr	NOUN
eurjchem-125	65	3	(	(	PUNCT
eurjchem-125	65	4	cdcl3	cdcl3	PROPN
eurjchem-125	65	5	):	):	PUNCT
eurjchem-125	65	6	1.37	1.37	NUM
eurjchem-125	65	7	(	(	PUNCT
eurjchem-125	65	8	6h	6h	NUM
eurjchem-125	65	9	,	,	PUNCT
eurjchem-125	65	10	ch3	ch3	PROPN
eurjchem-125	65	11	,	,	PUNCT
eurjchem-125	65	12	d	d	PROPN
eurjchem-125	65	13	,	,	PUNCT
eurjchem-125	65	14	j=6.11	j=6.11	X
eurjchem-125	65	15	hz	hz	NOUN
eurjchem-125	65	16	)	)	PUNCT
eurjchem-125	65	17	,	,	PUNCT
eurjchem-125	65	18	2.45–2.67	2.45–2.67	NUM
eurjchem-125	65	19	(	(	PUNCT
eurjchem-125	65	20	8h	8h	NUM
eurjchem-125	65	21	,	,	PUNCT
eurjchem-125	65	22	4	4	NUM
eurjchem-125	65	23	nch2	nch2	NOUN
eurjchem-125	65	24	,	,	PUNCT
eurjchem-125	65	25	m	m	PROPN
eurjchem-125	65	26	,	,	PUNCT
eurjchem-125	65	27	piperazine	piperazine	NOUN
eurjchem-125	65	28	)	)	PUNCT
eurjchem-125	65	29	,	,	PUNCT
eurjchem-125	65	30	3.85	3.85	NUM
eurjchem-125	65	31	(	(	PUNCT
eurjchem-125	65	32	2h	2h	NUM
eurjchem-125	65	33	,	,	PUNCT
eurjchem-125	65	34	n(hch)n	n(hch)n	NOUN
eurjchem-125	65	35	,	,	PUNCT
eurjchem-125	65	36	n(hch)n	n(hch)n	NOUN
eurjchem-125	65	37	,	,	PUNCT
eurjchem-125	65	38	d	d	PROPN
eurjchem-125	65	39	,	,	PUNCT
eurjchem-125	65	40	j=12.47	j=12.47	PROPN
eurjchem-125	65	41	hz	hz	PROPN
eurjchem-125	65	42	)	)	PUNCT
eurjchem-125	65	43	,	,	PUNCT
eurjchem-125	65	44	3.99	3.99	NUM
eurjchem-125	65	45	(	(	PUNCT
eurjchem-125	65	46	2h	2h	NUM
eurjchem-125	65	47	,	,	PUNCT
eurjchem-125	65	48	two	two	NUM
eurjchem-125	65	49	n‐ch	n‐ch	NOUN
eurjchem-125	65	50	,	,	PUNCT
eurjchem-125	65	51	m	m	PROPN
eurjchem-125	65	52	,	,	PUNCT
eurjchem-125	65	53	from	from	ADP
eurjchem-125	65	54	two	two	NUM
eurjchem-125	65	55	oxazolidinone	oxazolidinone	NUM
eurjchem-125	65	56	rings	ring	NOUN
eurjchem-125	65	57	)	)	PUNCT
eurjchem-125	65	58	,	,	PUNCT
eurjchem-125	65	59	4.16	4.16	NUM
eurjchem-125	65	60	(	(	PUNCT
eurjchem-125	65	61	2h	2h	NUM
eurjchem-125	65	62	,	,	PUNCT
eurjchem-125	65	63	n(hch)n	n(hch)n	NOUN
eurjchem-125	65	64	,	,	PUNCT
eurjchem-125	65	65	n(hch)n	n(hch)n	NOUN
eurjchem-125	65	66	,	,	PUNCT
eurjchem-125	65	67	d	d	PROPN
eurjchem-125	65	68	,	,	PUNCT
eurjchem-125	65	69	j=12.47	j=12.47	PROPN
eurjchem-125	65	70	hz	hz	PROPN
eurjchem-125	65	71	)	)	PUNCT
eurjchem-125	65	72	,	,	PUNCT
eurjchem-125	65	73	5.19	5.19	NUM
eurjchem-125	65	74	(	(	PUNCT
eurjchem-125	65	75	2h	2h	NUM
eurjchem-125	65	76	,	,	PUNCT
eurjchem-125	65	77	two	two	NUM
eurjchem-125	65	78	och	och	ADJ
eurjchem-125	65	79	,	,	PUNCT
eurjchem-125	65	80	d	d	PROPN
eurjchem-125	65	81	,	,	PUNCT
eurjchem-125	65	82	j=7.34	j=7.34	NOUN
eurjchem-125	65	83	hz	hz	NOUN
eurjchem-125	65	84	)	)	PUNCT
eurjchem-125	65	85	,	,	PUNCT
eurjchem-125	65	86	7.02	7.02	NUM
eurjchem-125	65	87	(	(	PUNCT
eurjchem-125	65	88	2h	2h	NUM
eurjchem-125	65	89	,	,	PUNCT
eurjchem-125	65	90	sch‐	sch‐	NOUN
eurjchem-125	65	91	ch‐ch	ch‐ch	NOUN
eurjchem-125	65	92	,	,	PUNCT
eurjchem-125	65	93	dd	dd	NOUN
eurjchem-125	65	94	,	,	PUNCT
eurjchem-125	65	95	j=3.42	j=3.42	PRON
eurjchem-125	65	96	hz	hz	PROPN
eurjchem-125	65	97	,	,	PUNCT
eurjchem-125	65	98	j=4.89	j=4.89	NOUN
eurjchem-125	65	99	hz	hz	VERB
eurjchem-125	65	100	,	,	PUNCT
eurjchem-125	65	101	from	from	ADP
eurjchem-125	65	102	two	two	NUM
eurjchem-125	65	103	thiophene	thiophene	NOUN
eurjchem-125	65	104	rings	ring	NOUN
eurjchem-125	65	105	)	)	PUNCT
eurjchem-125	65	106	,	,	PUNCT
eurjchem-125	65	107	7.14	7.14	NUM
eurjchem-125	65	108	(	(	PUNCT
eurjchem-125	65	109	2h	2h	NUM
eurjchem-125	65	110	,	,	PUNCT
eurjchem-125	65	111	sch‐ch‐ch	sch‐ch‐ch	VERB
eurjchem-125	65	112	,	,	PUNCT
eurjchem-125	65	113	dd	dd	NOUN
eurjchem-125	65	114	,	,	PUNCT
eurjchem-125	65	115	j=3.42	j=3.42	PRON
eurjchem-125	65	116	hz	hz	PROPN
eurjchem-125	65	117	,	,	PUNCT
eurjchem-125	65	118	j=1.22	j=1.22	PROPN
eurjchem-125	65	119	hz	hz	VERB
eurjchem-125	65	120	from	from	ADP
eurjchem-125	65	121	two	two	NUM
eurjchem-125	65	122	thiophene	thiophene	NOUN
eurjchem-125	65	123	rings	ring	NOUN
eurjchem-125	65	124	)	)	PUNCT
eurjchem-125	65	125	,	,	PUNCT
eurjchem-125	65	126	7.37	7.37	NUM
eurjchem-125	65	127	(	(	PUNCT
eurjchem-125	65	128	2h	2h	NUM
eurjchem-125	65	129	,	,	PUNCT
eurjchem-125	65	130	sch	sch	INTJ
eurjchem-125	65	131	,	,	PUNCT
eurjchem-125	65	132	dd	dd	NOUN
eurjchem-125	65	133	,	,	PUNCT
eurjchem-125	65	134	j=1.22	j=1.22	PROPN
eurjchem-125	65	135	,	,	PUNCT
eurjchem-125	65	136	j=4.89	j=4.89	PROPN
eurjchem-125	65	137	hz	hz	VERB
eurjchem-125	65	138	from	from	ADP
eurjchem-125	65	139	two	two	NUM
eurjchem-125	65	140	thiophene	thiophene	NOUN
eurjchem-125	65	141	rings	ring	NOUN
eurjchem-125	65	142	)	)	PUNCT
eurjchem-125	65	143	.	.	PUNCT
eurjchem-125	66	1	13c	13c	NOUN
eurjchem-125	66	2	nmr	nmr	NOUN
eurjchem-125	66	3	(	(	PUNCT
eurjchem-125	66	4	cdcl3	cdcl3	NOUN
eurjchem-125	66	5	):	):	PUNCT
eurjchem-125	66	6	17.3	17.3	NUM
eurjchem-125	66	7	(	(	PUNCT
eurjchem-125	66	8	ch3	ch3	PROPN
eurjchem-125	66	9	)	)	PUNCT
eurjchem-125	66	10	,	,	PUNCT
eurjchem-125	66	11	50.2	50.2	NUM
eurjchem-125	66	12	(	(	PUNCT
eurjchem-125	66	13	nch2	nch2	PROPN
eurjchem-125	66	14	,	,	PUNCT
eurjchem-125	66	15	piperazine	piperazine	NOUN
eurjchem-125	66	16	)	)	PUNCT
eurjchem-125	66	17	,	,	PUNCT
eurjchem-125	66	18	58.6	58.6	NUM
eurjchem-125	66	19	(	(	PUNCT
eurjchem-125	66	20	nch	nch	NOUN
eurjchem-125	66	21	,	,	PUNCT
eurjchem-125	66	22	oxazolidinone	oxazolidinone	NUM
eurjchem-125	66	23	)	)	PUNCT
eurjchem-125	66	24	,	,	PUNCT
eurjchem-125	66	25	63.9	63.9	NUM
eurjchem-125	66	26	(	(	PUNCT
eurjchem-125	66	27	nch2n	nch2n	PROPN
eurjchem-125	66	28	)	)	PUNCT
eurjchem-125	66	29	,	,	PUNCT
eurjchem-125	66	30	78.4	78.4	NUM
eurjchem-125	66	31	(	(	PUNCT
eurjchem-125	66	32	och	och	NOUN
eurjchem-125	66	33	)	)	PUNCT
eurjchem-125	66	34	,	,	PUNCT
eurjchem-125	66	35	126.7	126.7	NUM
eurjchem-125	66	36	,	,	PUNCT
eurjchem-125	66	37	126	126	NUM
eurjchem-125	66	38	.	.	NOUN
eurjchem-125	66	39	8	8	NUM
eurjchem-125	66	40	,	,	PUNCT
eurjchem-125	66	41	127.0	127.0	NUM
eurjchem-125	66	42	(	(	PUNCT
eurjchem-125	66	43	ch	ch	NOUN
eurjchem-125	66	44	,	,	PUNCT
eurjchem-125	66	45	thiophene	thiophene	NOUN
eurjchem-125	66	46	)	)	PUNCT
eurjchem-125	66	47	,	,	PUNCT
eurjchem-125	66	48	140.0	140.0	NUM
eurjchem-125	66	49	(	(	PUNCT
eurjchem-125	66	50	c	c	NOUN
eurjchem-125	66	51	,	,	PUNCT
eurjchem-125	66	52	thiophene	thiophene	NOUN
eurjchem-125	66	53	)	)	PUNCT
eurjchem-125	66	54	,	,	PUNCT
eurjchem-125	66	55	157.1	157.1	NUM
eurjchem-125	66	56	(	(	PUNCT
eurjchem-125	66	57	c	c	NOUN
eurjchem-125	66	58	=	=	NOUN
eurjchem-125	66	59	o	o	NOUN
eurjchem-125	66	60	)	)	PUNCT
eurjchem-125	66	61	.	.	PUNCT
eurjchem-125	67	1	anal	anal	PROPN
eurjchem-125	67	2	.	.	PUNCT
eurjchem-125	67	3	calcd	calcd	NOUN
eurjchem-125	67	4	.	.	PUNCT
eurjchem-125	68	1	for	for	ADP
eurjchem-125	68	2	c22h28n4o4s2	c22h28n4o4s2	NOUN
eurjchem-125	68	3	:	:	PUNCT
eurjchem-125	68	4	c	c	X
eurjchem-125	68	5	,	,	PUNCT
eurjchem-125	68	6	56.30	56.30	NUM
eurjchem-125	68	7	;	;	PUNCT
eurjchem-125	68	8	h	h	NOUN
eurjchem-125	68	9	,	,	PUNCT
eurjchem-125	68	10	6.16	6.16	NUM
eurjchem-125	68	11	;	;	PUNCT
eurjchem-125	68	12	n	n	CCONJ
eurjchem-125	68	13	,	,	PUNCT
eurjchem-125	68	14	11.42	11.42	NUM
eurjchem-125	68	15	;	;	PUNCT
eurjchem-125	68	16	s	s	X
eurjchem-125	68	17	,	,	PUNCT
eurjchem-125	68	18	13.07	13.07	NUM
eurjchem-125	68	19	;	;	PUNCT
eurjchem-125	68	20	found	find	VERB
eurjchem-125	68	21	:	:	PUNCT
eurjchem-125	68	22	56.23	56.23	NUM
eurjchem-125	68	23	;	;	PUNCT
eurjchem-125	68	24	h	h	NOUN
eurjchem-125	68	25	,	,	PUNCT
eurjchem-125	68	26	6.19	6.19	NUM
eurjchem-125	68	27	;	;	PUNCT
eurjchem-125	68	28	n	n	CCONJ
eurjchem-125	68	29	,	,	PUNCT
eurjchem-125	68	30	11.37	11.37	NUM
eurjchem-125	68	31	;	;	PUNCT
eurjchem-125	68	32	s	s	PROPN
eurjchem-125	68	33	,	,	PUNCT
eurjchem-125	68	34	13.11	13.11	NUM
eurjchem-125	68	35	.	.	PUNCT
eurjchem-125	69	1	syn‐1,4‐bis[(4‐methyl‐5‐thien‐2‐yl‐2‐oxo‐1,3‐oxazolidin‐3‐	syn‐1,4‐bis[(4‐methyl‐5‐thien‐2‐yl‐2‐oxo‐1,3‐oxazolidin‐3‐	NOUN
eurjchem-125	69	2	yl)methyl	yl)methyl	NOUN
eurjchem-125	69	3	]	]	PUNCT
eurjchem-125	69	4	piperazine	piperazine	NOUN
eurjchem-125	69	5	,	,	PUNCT
eurjchem-125	69	6	7e	7e	NUM
eurjchem-125	69	7	:	:	PUNCT
eurjchem-125	69	8	yield	yield	NOUN
eurjchem-125	69	9	:	:	PUNCT
eurjchem-125	69	10	62	62	NUM
eurjchem-125	69	11	%	%	NOUN
eurjchem-125	69	12	.	.	PUNCT
eurjchem-125	70	1	m.p	m.p	PROPN
eurjchem-125	70	2	.	.	PROPN
eurjchem-125	70	3	:	:	PUNCT
eurjchem-125	71	1	196‐197	196‐197	NUM
eurjchem-125	71	2	°	°	ADP
eurjchem-125	71	3	c	c	X
eurjchem-125	71	4	(	(	PUNCT
eurjchem-125	71	5	decomp	decomp	PROPN
eurjchem-125	71	6	.	.	PUNCT
eurjchem-125	71	7	)	)	PUNCT
eurjchem-125	71	8	.	.	PUNCT
eurjchem-125	72	1	rf	rf	PRON
eurjchem-125	72	2	=	=	NOUN
eurjchem-125	72	3	0.48	0.48	NUM
eurjchem-125	72	4	,	,	PUNCT
eurjchem-125	72	5	mobile	mobile	ADJ
eurjchem-125	72	6	phase	phase	NOUN
eurjchem-125	72	7	:	:	PUNCT
eurjchem-125	72	8	benzene	benzene	NOUN
eurjchem-125	72	9	:	:	PUNCT
eurjchem-125	72	10	diethyl	diethyl	NOUN
eurjchem-125	72	11	ether	ether	NOUN
eurjchem-125	72	12	:	:	PUNCT
eurjchem-125	72	13	ethanol	ethanol	NOUN
eurjchem-125	72	14	(	(	PUNCT
eurjchem-125	72	15	4:1:3	4:1:3	NUM
eurjchem-125	72	16	)	)	PUNCT
eurjchem-125	72	17	,	,	PUNCT
eurjchem-125	72	18	al2o3‐plates	al2o3‐plates	PROPN
eurjchem-125	72	19	.	.	PUNCT
eurjchem-125	73	1	1h	1h	NUM
eurjchem-125	73	2	nmr	nmr	NOUN
eurjchem-125	73	3	(	(	PUNCT
eurjchem-125	73	4	cdcl3	cdcl3	NOUN
eurjchem-125	73	5	):	):	PUNCT
eurjchem-125	73	6	0.97	0.97	NUM
eurjchem-125	73	7	(	(	PUNCT
eurjchem-125	73	8	6h	6h	NUM
eurjchem-125	73	9	,	,	PUNCT
eurjchem-125	73	10	2	2	NUM
eurjchem-125	73	11	ch3	ch3	PROPN
eurjchem-125	73	12	,	,	PUNCT
eurjchem-125	73	13	d	d	PROPN
eurjchem-125	73	14	,	,	PUNCT
eurjchem-125	73	15	j=6.60	j=6.60	PROPN
eurjchem-125	73	16	hz	hz	NOUN
eurjchem-125	73	17	)	)	PUNCT
eurjchem-125	73	18	;	;	PUNCT
eurjchem-125	73	19	2.59	2.59	NUM
eurjchem-125	73	20	(	(	PUNCT
eurjchem-125	73	21	8h	8h	NUM
eurjchem-125	73	22	,	,	PUNCT
eurjchem-125	73	23	4	4	NUM
eurjchem-125	73	24	n‐ch2	n‐ch2	NOUN
eurjchem-125	73	25	,	,	PUNCT
eurjchem-125	73	26	m	m	NOUN
eurjchem-125	73	27	,	,	PUNCT
eurjchem-125	73	28	piperazine	piperazine	NOUN
eurjchem-125	73	29	)	)	PUNCT
eurjchem-125	73	30	,	,	PUNCT
eurjchem-125	73	31	3.81	3.81	NUM
eurjchem-125	73	32	(	(	PUNCT
eurjchem-125	73	33	2h	2h	NUM
eurjchem-125	73	34	,	,	PUNCT
eurjchem-125	73	35	n(hch)n	n(hch)n	NOUN
eurjchem-125	73	36	,	,	PUNCT
eurjchem-125	73	37	n(hch)n	n(hch)n	NOUN
eurjchem-125	73	38	,	,	PUNCT
eurjchem-125	73	39	d	d	PROPN
eurjchem-125	73	40	,	,	PUNCT
eurjchem-125	73	41	j=12.62	j=12.62	PROPN
eurjchem-125	73	42	hz	hz	NOUN
eurjchem-125	73	43	)	)	PUNCT
eurjchem-125	73	44	,	,	PUNCT
eurjchem-125	73	45	4.23	4.23	NUM
eurjchem-125	73	46	(	(	PUNCT
eurjchem-125	73	47	4h	4h	NOUN
eurjchem-125	73	48	,	,	PUNCT
eurjchem-125	73	49	n(hch)n	n(hch)n	NOUN
eurjchem-125	73	50	,	,	PUNCT
eurjchem-125	73	51	n(hch)n	n(hch)n	NOUN
eurjchem-125	73	52	,	,	PUNCT
eurjchem-125	73	53	d	d	PROPN
eurjchem-125	73	54	,	,	PUNCT
eurjchem-125	73	55	j=12.62	j=12.62	PROPN
eurjchem-125	73	56	hz	hz	NOUN
eurjchem-125	73	57	;	;	PUNCT
eurjchem-125	73	58	overlapped	overlap	VERB
eurjchem-125	73	59	with	with	ADP
eurjchem-125	73	60	two	two	NUM
eurjchem-125	73	61	n‐ch	n‐ch	ADJ
eurjchem-125	73	62	,	,	PUNCT
eurjchem-125	73	63	dq	dq	PROPN
eurjchem-125	73	64	,	,	PUNCT
eurjchem-125	73	65	j=8.07	j=8.07	X
eurjchem-125	73	66	hz	hz	PROPN
eurjchem-125	73	67	,	,	PUNCT
eurjchem-125	73	68	j=6.60	j=6.60	PROPN
eurjchem-125	73	69	hz	hz	VERB
eurjchem-125	73	70	from	from	ADP
eurjchem-125	73	71	the	the	DET
eurjchem-125	73	72	two	two	NUM
eurjchem-125	73	73	oxazolidinone	oxazolidinone	NUM
eurjchem-125	73	74	rings	ring	NOUN
eurjchem-125	73	75	)	)	PUNCT
eurjchem-125	73	76	,	,	PUNCT
eurjchem-125	73	77	5.82	5.82	NUM
eurjchem-125	73	78	(	(	PUNCT
eurjchem-125	73	79	2h	2h	NUM
eurjchem-125	73	80	,	,	PUNCT
eurjchem-125	73	81	two	two	NUM
eurjchem-125	73	82	och	och	ADJ
eurjchem-125	73	83	,	,	PUNCT
eurjchem-125	73	84	d	d	PROPN
eurjchem-125	73	85	,	,	PUNCT
eurjchem-125	73	86	j=8.07	j=8.07	X
eurjchem-125	73	87	hz	hz	PROPN
eurjchem-125	73	88	)	)	PUNCT
eurjchem-125	73	89	,	,	PUNCT
eurjchem-125	73	90	7.11–6.99	7.11–6.99	NUM
eurjchem-125	73	91	(	(	PUNCT
eurjchem-125	73	92	4h	4h	NUM
eurjchem-125	73	93	,	,	PUNCT
eurjchem-125	73	94	2	2	NUM
eurjchem-125	73	95	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	73	96	and	and	CCONJ
eurjchem-125	73	97	2	2	NUM
eurjchem-125	73	98	sch‐ch‐	sch‐ch‐	NOUN
eurjchem-125	73	99	ch	ch	NOUN
eurjchem-125	73	100	,	,	PUNCT
eurjchem-125	73	101	m	m	PROPN
eurjchem-125	73	102	,	,	PUNCT
eurjchem-125	73	103	from	from	ADP
eurjchem-125	73	104	two	two	NUM
eurjchem-125	73	105	thiophene	thiophene	NOUN
eurjchem-125	73	106	rings	ring	NOUN
eurjchem-125	73	107	)	)	PUNCT
eurjchem-125	73	108	,	,	PUNCT
eurjchem-125	73	109	7.33	7.33	NUM
eurjchem-125	73	110	(	(	PUNCT
eurjchem-125	73	111	2h	2h	NUM
eurjchem-125	73	112	,	,	PUNCT
eurjchem-125	73	113	2	2	NUM
eurjchem-125	73	114	sch	sch	PROPN
eurjchem-125	73	115	,	,	PUNCT
eurjchem-125	73	116	m	m	PROPN
eurjchem-125	73	117	,	,	PUNCT
eurjchem-125	73	118	from	from	ADP
eurjchem-125	73	119	two	two	NUM
eurjchem-125	73	120	thiophene	thiophene	NOUN
eurjchem-125	73	121	rings	ring	NOUN
eurjchem-125	73	122	)	)	PUNCT
eurjchem-125	73	123	.	.	PUNCT
eurjchem-125	74	1	13c	13c	NOUN
eurjchem-125	74	2	nmr	nmr	NOUN
eurjchem-125	74	3	(	(	PUNCT
eurjchem-125	74	4	cdcl3	cdcl3	NOUN
eurjchem-125	74	5	):	):	PUNCT
eurjchem-125	74	6	13.8	13.8	NUM
eurjchem-125	74	7	(	(	PUNCT
eurjchem-125	74	8	ch3	ch3	PROPN
eurjchem-125	74	9	)	)	PUNCT
eurjchem-125	74	10	,	,	PUNCT
eurjchem-125	74	11	50.2	50.2	NUM
eurjchem-125	74	12	(	(	PUNCT
eurjchem-125	74	13	nch2	nch2	PROPN
eurjchem-125	74	14	,	,	PUNCT
eurjchem-125	74	15	piperazine	piperazine	NOUN
eurjchem-125	74	16	)	)	PUNCT
eurjchem-125	74	17	,	,	PUNCT
eurjchem-125	74	18	54.9	54.9	NUM
eurjchem-125	74	19	(	(	PUNCT
eurjchem-125	74	20	nch	nch	NOUN
eurjchem-125	74	21	,	,	PUNCT
eurjchem-125	74	22	oxazolidinone	oxazolidinone	NUM
eurjchem-125	74	23	)	)	PUNCT
eurjchem-125	74	24	,	,	PUNCT
eurjchem-125	74	25	64.0	64.0	NUM
eurjchem-125	74	26	(	(	PUNCT
eurjchem-125	74	27	nch2n	nch2n	PROPN
eurjchem-125	74	28	)	)	PUNCT
eurjchem-125	74	29	,	,	PUNCT
eurjchem-125	74	30	75.8	75.8	NUM
eurjchem-125	74	31	(	(	PUNCT
eurjchem-125	74	32	och	och	NOUN
eurjchem-125	74	33	)	)	PUNCT
eurjchem-125	74	34	,	,	PUNCT
eurjchem-125	74	35	125.9	125.9	NUM
eurjchem-125	74	36	,	,	PUNCT
eurjchem-125	74	37	126.20	126.20	NUM
eurjchem-125	74	38	,	,	PUNCT
eurjchem-125	74	39	126.8	126.8	NUM
eurjchem-125	74	40	(	(	PUNCT
eurjchem-125	74	41	ch	ch	NOUN
eurjchem-125	74	42	,	,	PUNCT
eurjchem-125	74	43	thiophene	thiophene	NOUN
eurjchem-125	74	44	)	)	PUNCT
eurjchem-125	74	45	,	,	PUNCT
eurjchem-125	74	46	137.4	137.4	NUM
eurjchem-125	74	47	(	(	PUNCT
eurjchem-125	74	48	c	c	NOUN
eurjchem-125	74	49	,	,	PUNCT
eurjchem-125	74	50	thiophene	thiophene	NOUN
eurjchem-125	74	51	)	)	PUNCT
eurjchem-125	74	52	,	,	PUNCT
eurjchem-125	74	53	159.4	159.4	NUM
eurjchem-125	74	54	(	(	PUNCT
eurjchem-125	74	55	c	c	NOUN
eurjchem-125	74	56	=	=	NOUN
eurjchem-125	74	57	o	o	NOUN
eurjchem-125	74	58	)	)	PUNCT
eurjchem-125	74	59	.	.	PUNCT
eurjchem-125	75	1	anal	anal	PROPN
eurjchem-125	75	2	.	.	PUNCT
eurjchem-125	75	3	calcd	calcd	NOUN
eurjchem-125	75	4	.	.	PUNCT
eurjchem-125	76	1	for	for	ADP
eurjchem-125	76	2	c22h28n4o4s2	c22h28n4o4s2	NOUN
eurjchem-125	76	3	:	:	PUNCT
eurjchem-125	76	4	c	c	X
eurjchem-125	76	5	,	,	PUNCT
eurjchem-125	76	6	56.30	56.30	NUM
eurjchem-125	76	7	;	;	PUNCT
eurjchem-125	76	8	h	h	NOUN
eurjchem-125	76	9	,	,	PUNCT
eurjchem-125	76	10	6.16	6.16	NUM
eurjchem-125	76	11	;	;	PUNCT
eurjchem-125	76	12	n	n	CCONJ
eurjchem-125	76	13	,	,	PUNCT
eurjchem-125	76	14	11.42	11.42	NUM
eurjchem-125	76	15	;	;	PUNCT
eurjchem-125	76	16	s	s	X
eurjchem-125	76	17	,	,	PUNCT
eurjchem-125	76	18	13.07	13.07	NUM
eurjchem-125	76	19	;	;	PUNCT
eurjchem-125	76	20	found	find	VERB
eurjchem-125	76	21	:	:	PUNCT
eurjchem-125	76	22	56.35	56.35	NUM
eurjchem-125	76	23	;	;	PUNCT
eurjchem-125	76	24	h	h	NOUN
eurjchem-125	76	25	,	,	PUNCT
eurjchem-125	76	26	6.11	6.11	NUM
eurjchem-125	76	27	;	;	PUNCT
eurjchem-125	76	28	n	n	CCONJ
eurjchem-125	76	29	,	,	PUNCT
eurjchem-125	76	30	11.47	11.47	NUM
eurjchem-125	76	31	;	;	PUNCT
eurjchem-125	76	32	s	s	NOUN
eurjchem-125	76	33	,	,	PUNCT
eurjchem-125	76	34	13.0	13.0	NUM
eurjchem-125	76	35	.	.	PUNCT
eurjchem-125	77	1	2.3	2.3	NUM
eurjchem-125	77	2	.	.	PUNCT
eurjchem-125	77	3	general	general	ADJ
eurjchem-125	77	4	procedure	procedure	NOUN
eurjchem-125	77	5	for	for	ADP
eurjchem-125	77	6	compounds	compound	NOUN
eurjchem-125	77	7	5a‐d	5a‐d	INTJ
eurjchem-125	78	1	and	and	CCONJ
eurjchem-125	78	2	7a‐d	7a‐d	PROPN
eurjchem-125	78	3	a	a	DET
eurjchem-125	78	4	one	one	NUM
eurjchem-125	78	5	necked	neck	VERB
eurjchem-125	78	6	flask	flask	NOUN
eurjchem-125	78	7	equipped	equip	VERB
eurjchem-125	78	8	with	with	ADP
eurjchem-125	78	9	a	a	DET
eurjchem-125	78	10	stirrer	stirrer	NOUN
eurjchem-125	78	11	and	and	CCONJ
eurjchem-125	78	12	condenser	condenser	NOUN
eurjchem-125	78	13	was	be	AUX
eurjchem-125	78	14	charged	charge	VERB
eurjchem-125	78	15	with	with	ADP
eurjchem-125	78	16	1.2	1.2	NUM
eurjchem-125	78	17	g	g	NOUN
eurjchem-125	78	18	(	(	PUNCT
eurjchem-125	78	19	6.6	6.6	NUM
eurjchem-125	78	20	mmol	mmol	NOUN
eurjchem-125	78	21	)	)	PUNCT
eurjchem-125	78	22	of	of	ADP
eurjchem-125	78	23	anti‐4‐methyl‐5‐thien‐2‐	anti‐4‐methyl‐5‐thien‐2‐	NOUN
eurjchem-125	78	24	yl‐1,3‐oxazolidine‐2‐one	yl‐1,3‐oxazolidine‐2‐one	NOUN
eurjchem-125	78	25	4	4	NUM
eurjchem-125	78	26	,	,	PUNCT
eurjchem-125	78	27	respectively	respectively	ADV
eurjchem-125	78	28	,	,	PUNCT
eurjchem-125	78	29	the	the	DET
eurjchem-125	78	30	syn‐isomer	syn‐isomer	NOUN
eurjchem-125	78	31	6	6	NUM
eurjchem-125	78	32	,	,	PUNCT
eurjchem-125	78	33	50	50	NUM
eurjchem-125	78	34	ml	ml	NOUN
eurjchem-125	78	35	ethanol	ethanol	NOUN
eurjchem-125	78	36	,	,	PUNCT
eurjchem-125	78	37	0.46	0.46	NUM
eurjchem-125	78	38	ml	ml	NOUN
eurjchem-125	78	39	(	(	PUNCT
eurjchem-125	78	40	5.3	5.3	NUM
eurjchem-125	78	41	mmol	mmol	NOUN
eurjchem-125	78	42	)	)	PUNCT
eurjchem-125	78	43	of	of	ADP
eurjchem-125	78	44	the	the	DET
eurjchem-125	78	45	appropriate	appropriate	ADJ
eurjchem-125	78	46	amine	amine	NOUN
eurjchem-125	78	47	and	and	CCONJ
eurjchem-125	78	48	0.7	0.7	NUM
eurjchem-125	78	49	ml	ml	NOUN
eurjchem-125	78	50	(	(	PUNCT
eurjchem-125	78	51	9	9	NUM
eurjchem-125	78	52	mmol	mmol	NOUN
eurjchem-125	78	53	)	)	PUNCT
eurjchem-125	78	54	formaldehyde	formaldehyde	NOUN
eurjchem-125	78	55	in	in	ADP
eurjchem-125	78	56	form	form	NOUN
eurjchem-125	78	57	of	of	ADP
eurjchem-125	78	58	35	35	NUM
eurjchem-125	78	59	%	%	NOUN
eurjchem-125	78	60	formalin	formalin	NOUN
eurjchem-125	78	61	.	.	PUNCT
eurjchem-125	79	1	after	after	ADP
eurjchem-125	79	2	refluxing	refluxe	VERB
eurjchem-125	79	3	for	for	ADP
eurjchem-125	79	4	2	2	NUM
eurjchem-125	79	5	hours	hour	NOUN
eurjchem-125	79	6	,	,	PUNCT
eurjchem-125	79	7	the	the	DET
eurjchem-125	79	8	solvent	solvent	NOUN
eurjchem-125	79	9	was	be	AUX
eurjchem-125	79	10	removed	remove	VERB
eurjchem-125	79	11	by	by	ADP
eurjchem-125	79	12	reduced	reduced	ADJ
eurjchem-125	79	13	pressure	pressure	NOUN
eurjchem-125	79	14	and	and	CCONJ
eurjchem-125	79	15	the	the	DET
eurjchem-125	79	16	remaining	remain	VERB
eurjchem-125	79	17	light	light	ADJ
eurjchem-125	79	18	yellow	yellow	ADJ
eurjchem-125	79	19	oil	oil	NOUN
eurjchem-125	79	20	crystallized	crystallize	VERB
eurjchem-125	79	21	after	after	ADP
eurjchem-125	79	22	cooling	cool	VERB
eurjchem-125	79	23	.	.	PUNCT
eurjchem-125	80	1	anti‐4‐methyl‐3‐(morpholin‐1‐ylmethyl)‐5‐thien‐2‐yl‐1,3‐	anti‐4‐methyl‐3‐(morpholin‐1‐ylmethyl)‐5‐thien‐2‐yl‐1,3‐	PROPN
eurjchem-125	80	2	oxazolidin‐2‐one	oxazolidin‐2‐one	PROPN
eurjchem-125	80	3	,	,	PUNCT
eurjchem-125	80	4	5a	5a	NUM
eurjchem-125	80	5	:	:	PUNCT
eurjchem-125	80	6	after	after	ADP
eurjchem-125	80	7	removing	remove	VERB
eurjchem-125	80	8	of	of	ADP
eurjchem-125	80	9	the	the	DET
eurjchem-125	80	10	solvent	solvent	NOUN
eurjchem-125	80	11	to	to	ADP
eurjchem-125	80	12	the	the	DET
eurjchem-125	80	13	remaining	remain	VERB
eurjchem-125	80	14	oil	oil	NOUN
eurjchem-125	80	15	diethyl	diethyl	NOUN
eurjchem-125	80	16	ether	ether	NOUN
eurjchem-125	80	17	was	be	AUX
eurjchem-125	80	18	added	add	VERB
eurjchem-125	80	19	and	and	CCONJ
eurjchem-125	80	20	compound	compound	VERB
eurjchem-125	80	21	5a	5a	NUM
eurjchem-125	80	22	was	be	AUX
eurjchem-125	80	23	crystallized	crystallize	VERB
eurjchem-125	80	24	.	.	PUNCT
eurjchem-125	81	1	re‐crystallization	re‐crystallization	NOUN
eurjchem-125	81	2	was	be	AUX
eurjchem-125	81	3	carried	carry	VERB
eurjchem-125	81	4	out	out	ADP
eurjchem-125	81	5	with	with	ADP
eurjchem-125	81	6	ethanol	ethanol	NOUN
eurjchem-125	81	7	.	.	PUNCT
eurjchem-125	82	1	yield	yield	NOUN
eurjchem-125	82	2	:	:	PUNCT
eurjchem-125	82	3	62	62	NUM
eurjchem-125	82	4	%	%	NOUN
eurjchem-125	82	5	.	.	PUNCT
eurjchem-125	83	1	m.p	m.p	PROPN
eurjchem-125	83	2	.	.	PROPN
eurjchem-125	83	3	:	:	PUNCT
eurjchem-125	84	1	166‐169	166‐169	NUM
eurjchem-125	84	2	°	°	PROPN
eurjchem-125	84	3	c	c	X
eurjchem-125	84	4	(	(	PUNCT
eurjchem-125	84	5	decomp	decomp	PROPN
eurjchem-125	84	6	.	.	PUNCT
eurjchem-125	84	7	)	)	PUNCT
eurjchem-125	84	8	.	.	PUNCT
eurjchem-125	85	1	rf	rf	PRON
eurjchem-125	85	2	=	=	NOUN
eurjchem-125	85	3	0.61	0.61	NUM
eurjchem-125	85	4	,	,	PUNCT
eurjchem-125	85	5	mobile	mobile	ADJ
eurjchem-125	85	6	phase	phase	NOUN
eurjchem-125	85	7	:	:	PUNCT
eurjchem-125	85	8	benzene	benzene	NOUN
eurjchem-125	85	9	:	:	PUNCT
eurjchem-125	85	10	diethyl	diethyl	NOUN
eurjchem-125	85	11	ether	ether	NOUN
eurjchem-125	85	12	:	:	PUNCT
eurjchem-125	85	13	ethanol	ethanol	NOUN
eurjchem-125	85	14	(	(	PUNCT
eurjchem-125	85	15	4:1:2	4:1:2	NOUN
eurjchem-125	85	16	)	)	PUNCT
eurjchem-125	85	17	,	,	PUNCT
eurjchem-125	85	18	silica	silica	NOUN
eurjchem-125	85	19	gel	gel	NOUN
eurjchem-125	85	20	f254	f254	PROPN
eurjchem-125	85	21	.	.	PROPN
eurjchem-125	86	1	1h	1h	NUM
eurjchem-125	86	2	nmr(cdcl3	nmr(cdcl3	PROPN
eurjchem-125	86	3	):	):	PUNCT
eurjchem-125	86	4	1.38	1.38	NUM
eurjchem-125	86	5	(	(	PUNCT
eurjchem-125	86	6	3h	3h	NUM
eurjchem-125	86	7	,	,	PUNCT
eurjchem-125	86	8	ch3	ch3	PROPN
eurjchem-125	86	9	,	,	PUNCT
eurjchem-125	86	10	d	d	PROPN
eurjchem-125	86	11	,	,	PUNCT
eurjchem-125	86	12	j=6.24	j=6.24	NOUN
eurjchem-125	86	13	hz	hz	NOUN
eurjchem-125	86	14	)	)	PUNCT
eurjchem-125	86	15	,	,	PUNCT
eurjchem-125	86	16	3.1–3.3	3.1–3.3	NUM
eurjchem-125	86	17	(	(	PUNCT
eurjchem-125	86	18	4h	4h	NOUN
eurjchem-125	86	19	,	,	PUNCT
eurjchem-125	86	20	2	2	NUM
eurjchem-125	86	21	nch2,m	nch2,m	ADJ
eurjchem-125	86	22	,	,	PUNCT
eurjchem-125	86	23	morpholine	morpholine	NOUN
eurjchem-125	86	24	)	)	PUNCT
eurjchem-125	86	25	,	,	PUNCT
eurjchem-125	86	26	3.8–4.0	3.8–4.0	NUM
eurjchem-125	86	27	(	(	PUNCT
eurjchem-125	86	28	4h	4h	NUM
eurjchem-125	86	29	,	,	PUNCT
eurjchem-125	86	30	2	2	NUM
eurjchem-125	86	31	och2	och2	PROPN
eurjchem-125	86	32	,	,	PUNCT
eurjchem-125	86	33	m	m	PROPN
eurjchem-125	86	34	,	,	PUNCT
eurjchem-125	86	35	morpholine	morpholine	ADJ
eurjchem-125	86	36	)	)	PUNCT
eurjchem-125	86	37	,	,	PUNCT
eurjchem-125	86	38	4.43–4.56	4.43–4.56	NUM
eurjchem-125	86	39	(	(	PUNCT
eurjchem-125	86	40	1h	1h	NUM
eurjchem-125	86	41	,	,	PUNCT
eurjchem-125	86	42	nch	nch	NOUN
eurjchem-125	86	43	,	,	PUNCT
eurjchem-125	86	44	m	m	PROPN
eurjchem-125	86	45	,	,	PUNCT
eurjchem-125	86	46	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	86	47	)	)	PUNCT
eurjchem-125	86	48	,	,	PUNCT
eurjchem-125	86	49	4.58	4.58	NUM
eurjchem-125	86	50	(	(	PUNCT
eurjchem-125	86	51	1h	1h	NUM
eurjchem-125	86	52	,	,	PUNCT
eurjchem-125	86	53	nhchn	nhchn	NOUN
eurjchem-125	86	54	,	,	PUNCT
eurjchem-125	86	55	d	d	PROPN
eurjchem-125	86	56	,	,	PUNCT
eurjchem-125	86	57	j=13.45	j=13.45	PROPN
eurjchem-125	86	58	hz	hz	PROPN
eurjchem-125	86	59	)	)	PUNCT
eurjchem-125	86	60	,	,	PUNCT
eurjchem-125	86	61	4.72	4.72	NUM
eurjchem-125	86	62	(	(	PUNCT
eurjchem-125	86	63	1h	1h	NUM
eurjchem-125	86	64	,	,	PUNCT
eurjchem-125	86	65	nhchn	nhchn	NOUN
eurjchem-125	86	66	,	,	PUNCT
eurjchem-125	86	67	d	d	PROPN
eurjchem-125	86	68	,	,	PUNCT
eurjchem-125	86	69	j=13.45	j=13.45	PROPN
eurjchem-125	86	70	hz	hz	PROPN
eurjchem-125	86	71	)	)	PUNCT
eurjchem-125	86	72	,	,	PUNCT
eurjchem-125	86	73	5.55	5.55	NUM
eurjchem-125	86	74	(	(	PUNCT
eurjchem-125	86	75	1h	1h	NUM
eurjchem-125	86	76	,	,	PUNCT
eurjchem-125	86	77	och	och	NUM
eurjchem-125	86	78	,	,	PUNCT
eurjchem-125	86	79	d	d	PROPN
eurjchem-125	86	80	,	,	PUNCT
eurjchem-125	86	81	j=6.66	j=6.66	NOUN
eurjchem-125	86	82	hz	hz	NOUN
eurjchem-125	86	83	)	)	PUNCT
eurjchem-125	86	84	,	,	PUNCT
eurjchem-125	86	85	7.10	7.10	NUM
eurjchem-125	86	86	(	(	PUNCT
eurjchem-125	86	87	1h	1h	NUM
eurjchem-125	86	88	,	,	PUNCT
eurjchem-125	86	89	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	86	90	,	,	PUNCT
eurjchem-125	86	91	dd	dd	NOUN
eurjchem-125	86	92	,	,	PUNCT
eurjchem-125	86	93	j=3.55	j=3.55	NOUN
eurjchem-125	86	94	hz	hz	PART
eurjchem-125	86	95	,	,	PUNCT
eurjchem-125	86	96	j=5.01	j=5.01	NOUN
eurjchem-125	86	97	hz	hz	NOUN
eurjchem-125	86	98	)	)	PUNCT
eurjchem-125	86	99	,	,	PUNCT
eurjchem-125	86	100	7.39	7.39	NUM
eurjchem-125	86	101	(	(	PUNCT
eurjchem-125	86	102	1h	1h	NUM
eurjchem-125	86	103	,	,	PUNCT
eurjchem-125	86	104	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	86	105	,	,	PUNCT
eurjchem-125	86	106	dd	dd	NOUN
eurjchem-125	86	107	,	,	PUNCT
eurjchem-125	86	108	j=3.55	j=3.55	NOUN
eurjchem-125	86	109	hz	hz	VERB
eurjchem-125	86	110	,	,	PUNCT
eurjchem-125	86	111	j=1.22	j=1.22	PROPN
eurjchem-125	86	112	hz	hz	PROPN
eurjchem-125	86	113	)	)	PUNCT
eurjchem-125	86	114	,	,	PUNCT
eurjchem-125	86	115	7.67	7.67	NUM
eurjchem-125	86	116	(	(	PUNCT
eurjchem-125	86	117	1h	1h	NUM
eurjchem-125	86	118	,	,	PUNCT
eurjchem-125	86	119	sch	sch	INTJ
eurjchem-125	86	120	,	,	PUNCT
eurjchem-125	86	121	dd	dd	VERB
eurjchem-125	86	122	,	,	PUNCT
eurjchem-125	86	123	j=1.22	j=1.22	PROPN
eurjchem-125	86	124	hz	hz	NOUN
eurjchem-125	86	125	,	,	PUNCT
eurjchem-125	86	126	j=5.01	j=5.01	NOUN
eurjchem-125	86	127	hz	hz	VERB
eurjchem-125	86	128	)	)	PUNCT
eurjchem-125	86	129	.	.	PUNCT
eurjchem-125	87	1	13c	13c	NOUN
eurjchem-125	87	2	nmr	nmr	NOUN
eurjchem-125	87	3	(	(	PUNCT
eurjchem-125	87	4	cdcl3	cdcl3	PROPN
eurjchem-125	87	5	):	):	PUNCT
eurjchem-125	87	6	17.0	17.0	NUM
eurjchem-125	87	7	(	(	PUNCT
eurjchem-125	87	8	ch3	ch3	PROPN
eurjchem-125	87	9	)	)	PUNCT
eurjchem-125	87	10	,	,	PUNCT
eurjchem-125	87	11	43.0	43.0	NUM
eurjchem-125	87	12	(	(	PUNCT
eurjchem-125	87	13	nch2	nch2	PROPN
eurjchem-125	87	14	,	,	PUNCT
eurjchem-125	87	15	morpholine	morpholine	PROPN
eurjchem-125	87	16	)	)	PUNCT
eurjchem-125	87	17	,	,	PUNCT
eurjchem-125	87	18	49.1	49.1	NUM
eurjchem-125	87	19	(	(	PUNCT
eurjchem-125	87	20	nch2	nch2	PROPN
eurjchem-125	87	21	,	,	PUNCT
eurjchem-125	87	22	morpholine	morpholine	PROPN
eurjchem-125	87	23	)	)	PUNCT
eurjchem-125	87	24	,	,	PUNCT
eurjchem-125	87	25	58.4	58.4	NUM
eurjchem-125	87	26	(	(	PUNCT
eurjchem-125	87	27	nch	nch	NOUN
eurjchem-125	87	28	,	,	PUNCT
eurjchem-125	87	29	oxazolidin	oxazolidin	VERB
eurjchem-125	87	30	one	one	NUM
eurjchem-125	87	31	)	)	PUNCT
eurjchem-125	87	32	,	,	PUNCT
eurjchem-125	87	33	61.2	61.2	NUM
eurjchem-125	87	34	(	(	PUNCT
eurjchem-125	87	35	nch2n	nch2n	PROPN
eurjchem-125	87	36	)	)	PUNCT
eurjchem-125	87	37	,	,	PUNCT
eurjchem-125	87	38	63.1	63.1	NUM
eurjchem-125	87	39	(	(	PUNCT
eurjchem-125	87	40	och2	och2	PROPN
eurjchem-125	87	41	,	,	PUNCT
eurjchem-125	87	42	morpholine	morpholine	NOUN
eurjchem-125	87	43	)	)	PUNCT
eurjchem-125	87	44	,	,	PUNCT
eurjchem-125	87	45	63.6	63.6	NUM
eurjchem-125	87	46	(	(	PUNCT
eurjchem-125	87	47	och2	och2	PROPN
eurjchem-125	87	48	,	,	PUNCT
eurjchem-125	87	49	morpholine	morpholine	NOUN
eurjchem-125	87	50	)	)	PUNCT
eurjchem-125	87	51	,	,	PUNCT
eurjchem-125	87	52	78.4	78.4	NUM
eurjchem-125	87	53	(	(	PUNCT
eurjchem-125	87	54	och	och	NOUN
eurjchem-125	87	55	)	)	PUNCT
eurjchem-125	87	56	,	,	PUNCT
eurjchem-125	87	57	127.7	127.7	NUM
eurjchem-125	87	58	,	,	PUNCT
eurjchem-125	87	59	128.4	128.4	NUM
eurjchem-125	87	60	,	,	PUNCT
eurjchem-125	87	61	128.5	128.5	NUM
eurjchem-125	87	62	(	(	PUNCT
eurjchem-125	87	63	ch	ch	NOUN
eurjchem-125	87	64	,	,	PUNCT
eurjchem-125	87	65	thiophene	thiophene	NOUN
eurjchem-125	87	66	)	)	PUNCT
eurjchem-125	87	67	,	,	PUNCT
eurjchem-125	87	68	139.2	139.2	NUM
eurjchem-125	87	69	(	(	PUNCT
eurjchem-125	87	70	c	c	NOUN
eurjchem-125	87	71	,	,	PUNCT
eurjchem-125	87	72	thiophene	thiophene	NOUN
eurjchem-125	87	73	)	)	PUNCT
eurjchem-125	87	74	,	,	PUNCT
eurjchem-125	87	75	156.5	156.5	NUM
eurjchem-125	87	76	(	(	PUNCT
eurjchem-125	87	77	c	c	NOUN
eurjchem-125	87	78	=	=	NOUN
eurjchem-125	87	79	o	o	NOUN
eurjchem-125	87	80	)	)	PUNCT
eurjchem-125	87	81	.	.	PUNCT
eurjchem-125	88	1	anal	anal	PROPN
eurjchem-125	88	2	.	.	PUNCT
eurjchem-125	88	3	calcd	calcd	NOUN
eurjchem-125	88	4	.	.	PUNCT
eurjchem-125	89	1	for	for	ADP
eurjchem-125	89	2	c13h18n2o3s	c13h18n2o3s	NUM
eurjchem-125	89	3	:	:	PUNCT
eurjchem-125	89	4	c	c	X
eurjchem-125	89	5	,	,	PUNCT
eurjchem-125	89	6	55.30	55.30	NUM
eurjchem-125	89	7	;	;	PUNCT
eurjchem-125	89	8	h	h	NOUN
eurjchem-125	89	9	,	,	PUNCT
eurjchem-125	89	10	6.43	6.43	NUM
eurjchem-125	89	11	;	;	PUNCT
eurjchem-125	89	12	n	n	CCONJ
eurjchem-125	89	13	,	,	PUNCT
eurjchem-125	89	14	9.92	9.92	NUM
eurjchem-125	89	15	;	;	PUNCT
eurjchem-125	89	16	s	s	NOUN
eurjchem-125	89	17	,	,	PUNCT
eurjchem-125	89	18	11.37	11.37	NUM
eurjchem-125	89	19	;	;	PUNCT
eurjchem-125	89	20	found	find	VERB
eurjchem-125	89	21	:	:	PUNCT
eurjchem-125	89	22	c	c	X
eurjchem-125	89	23	,	,	PUNCT
eurjchem-125	89	24	55.24	55.24	NUM
eurjchem-125	89	25	;	;	PUNCT
eurjchem-125	90	1	h	h	NOUN
eurjchem-125	90	2	,	,	PUNCT
eurjchem-125	90	3	6.48	6.48	NUM
eurjchem-125	90	4	;	;	PUNCT
eurjchem-125	90	5	n	n	CCONJ
eurjchem-125	90	6	,	,	PUNCT
eurjchem-125	90	7	9.86	9.86	NUM
eurjchem-125	90	8	;	;	PUNCT
eurjchem-125	90	9	s	s	NOUN
eurjchem-125	90	10	,	,	PUNCT
eurjchem-125	90	11	11.43	11.43	NUM
eurjchem-125	90	12	.	.	X
eurjchem-125	91	1	20	20	NUM
eurjchem-125	91	2	mavrova	mavrova	NOUN
eurjchem-125	91	3	et	et	PROPN
eurjchem-125	91	4	al	al	PROPN
eurjchem-125	91	5	.	.	PUNCT
eurjchem-125	91	6	/	/	SYM
eurjchem-125	91	7	european	european	PROPN
eurjchem-125	91	8	journal	journal	PROPN
eurjchem-125	91	9	of	of	ADP
eurjchem-125	91	10	chemistry	chemistry	NOUN
eurjchem-125	91	11	2	2	NUM
eurjchem-125	91	12	(	(	PUNCT
eurjchem-125	91	13	1	1	NUM
eurjchem-125	91	14	)	)	PUNCT
eurjchem-125	91	15	(	(	PUNCT
eurjchem-125	91	16	2011	2011	NUM
eurjchem-125	91	17	)	)	PUNCT
eurjchem-125	91	18	18‐24	18‐24	PROPN
eurjchem-125	91	19	syn‐4‐methyl‐3‐(morpholin‐1‐ylmethyl)‐5‐thien‐2‐yl‐1,3‐	syn‐4‐methyl‐3‐(morpholin‐1‐ylmethyl)‐5‐thien‐2‐yl‐1,3‐	PROPN
eurjchem-125	91	20	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	91	21	,	,	PUNCT
eurjchem-125	91	22	7a	7a	NUM
eurjchem-125	91	23	:	:	PUNCT
eurjchem-125	91	24	after	after	ADP
eurjchem-125	91	25	removing	remove	VERB
eurjchem-125	91	26	the	the	DET
eurjchem-125	91	27	solvent	solvent	NOUN
eurjchem-125	91	28	,	,	PUNCT
eurjchem-125	91	29	diethyl	diethyl	NOUN
eurjchem-125	91	30	ether	ether	NOUN
eurjchem-125	91	31	was	be	AUX
eurjchem-125	91	32	added	add	VERB
eurjchem-125	91	33	and	and	CCONJ
eurjchem-125	91	34	the	the	DET
eurjchem-125	91	35	compound	compound	NOUN
eurjchem-125	91	36	crystallized	crystallize	VERB
eurjchem-125	91	37	.	.	PUNCT
eurjchem-125	92	1	recrystallization	recrystallization	NOUN
eurjchem-125	92	2	was	be	AUX
eurjchem-125	92	3	carried	carry	VERB
eurjchem-125	92	4	out	out	ADP
eurjchem-125	92	5	with	with	ADP
eurjchem-125	92	6	ethanol	ethanol	NOUN
eurjchem-125	92	7	.	.	PUNCT
eurjchem-125	93	1	yield	yield	NOUN
eurjchem-125	93	2	:	:	PUNCT
eurjchem-125	93	3	64	64	NUM
eurjchem-125	93	4	%	%	NOUN
eurjchem-125	93	5	.	.	PUNCT
eurjchem-125	94	1	m.p	m.p	PROPN
eurjchem-125	94	2	.	.	PROPN
eurjchem-125	94	3	:	:	PUNCT
eurjchem-125	95	1	83‐85	83‐85	NUM
eurjchem-125	95	2	°	°	PUNCT
eurjchem-125	95	3	c	c	X
eurjchem-125	95	4	.	.	PUNCT
eurjchem-125	96	1	rf	rf	VERB
eurjchem-125	96	2	=	=	NOUN
eurjchem-125	96	3	0.61	0.61	NUM
eurjchem-125	96	4	,	,	PUNCT
eurjchem-125	96	5	mobile	mobile	ADJ
eurjchem-125	96	6	phase	phase	NOUN
eurjchem-125	96	7	:	:	PUNCT
eurjchem-125	96	8	benzene	benzene	NOUN
eurjchem-125	96	9	:	:	PUNCT
eurjchem-125	96	10	diethyl	diethyl	NOUN
eurjchem-125	96	11	ether	ether	NOUN
eurjchem-125	96	12	:	:	PUNCT
eurjchem-125	96	13	ethanol	ethanol	NOUN
eurjchem-125	96	14	(	(	PUNCT
eurjchem-125	96	15	4:1:2	4:1:2	NOUN
eurjchem-125	96	16	)	)	PUNCT
eurjchem-125	96	17	,	,	PUNCT
eurjchem-125	96	18	silica	silica	NOUN
eurjchem-125	96	19	gel	gel	NOUN
eurjchem-125	96	20	f254	f254	PROPN
eurjchem-125	96	21	.	.	PROPN
eurjchem-125	97	1	1h	1h	NUM
eurjchem-125	97	2	nmr	nmr	NOUN
eurjchem-125	97	3	(	(	PUNCT
eurjchem-125	97	4	cdcl3	cdcl3	NOUN
eurjchem-125	97	5	):	):	PUNCT
eurjchem-125	97	6	0.98	0.98	NUM
eurjchem-125	97	7	(	(	PUNCT
eurjchem-125	97	8	3h	3h	NUM
eurjchem-125	97	9	,	,	PUNCT
eurjchem-125	97	10	ch3	ch3	PROPN
eurjchem-125	97	11	,	,	PUNCT
eurjchem-125	97	12	d	d	PROPN
eurjchem-125	97	13	,	,	PUNCT
eurjchem-125	97	14	j=6.60	j=6.60	PROPN
eurjchem-125	97	15	hz	hz	NOUN
eurjchem-125	97	16	)	)	PUNCT
eurjchem-125	97	17	,	,	PUNCT
eurjchem-125	97	18	2.69–2.49	2.69–2.49	NUM
eurjchem-125	97	19	(	(	PUNCT
eurjchem-125	97	20	4h	4h	NUM
eurjchem-125	97	21	,	,	PUNCT
eurjchem-125	97	22	2	2	NUM
eurjchem-125	97	23	nch2	nch2	NOUN
eurjchem-125	97	24	,	,	PUNCT
eurjchem-125	97	25	m	m	PROPN
eurjchem-125	97	26	,	,	PUNCT
eurjchem-125	97	27	morpholine	morpholine	ADJ
eurjchem-125	97	28	)	)	PUNCT
eurjchem-125	97	29	,	,	PUNCT
eurjchem-125	97	30	3.75–3.66	3.75–3.66	NUM
eurjchem-125	97	31	(	(	PUNCT
eurjchem-125	97	32	4h	4h	NUM
eurjchem-125	97	33	,	,	PUNCT
eurjchem-125	97	34	2	2	NUM
eurjchem-125	97	35	och2	och2	PROPN
eurjchem-125	97	36	,	,	PUNCT
eurjchem-125	97	37	m	m	PROPN
eurjchem-125	97	38	,	,	PUNCT
eurjchem-125	97	39	morpholine	morpholine	ADJ
eurjchem-125	97	40	)	)	PUNCT
eurjchem-125	97	41	,	,	PUNCT
eurjchem-125	97	42	3.79	3.79	NUM
eurjchem-125	97	43	(	(	PUNCT
eurjchem-125	97	44	1h	1h	NUM
eurjchem-125	97	45	,	,	PUNCT
eurjchem-125	97	46	n(hch)n	n(hch)n	NOUN
eurjchem-125	97	47	,	,	PUNCT
eurjchem-125	97	48	d	d	PROPN
eurjchem-125	97	49	,	,	PUNCT
eurjchem-125	97	50	j=12.47	j=12.47	PROPN
eurjchem-125	97	51	hz	hz	PROPN
eurjchem-125	97	52	)	)	PUNCT
eurjchem-125	97	53	,	,	PUNCT
eurjchem-125	97	54	4.21	4.21	NUM
eurjchem-125	97	55	(	(	PUNCT
eurjchem-125	97	56	1h	1h	NUM
eurjchem-125	97	57	,	,	PUNCT
eurjchem-125	97	58	n(hch)n	n(hch)n	NOUN
eurjchem-125	97	59	,	,	PUNCT
eurjchem-125	97	60	d	d	PROPN
eurjchem-125	97	61	,	,	PUNCT
eurjchem-125	97	62	j=12.47	j=12.47	PROPN
eurjchem-125	97	63	hz	hz	PROPN
eurjchem-125	97	64	)	)	PUNCT
eurjchem-125	97	65	,	,	PUNCT
eurjchem-125	97	66	4.25	4.25	NUM
eurjchem-125	97	67	(	(	PUNCT
eurjchem-125	97	68	1h	1h	NUM
eurjchem-125	97	69	,	,	PUNCT
eurjchem-125	97	70	nch	nch	NOUN
eurjchem-125	97	71	,	,	PUNCT
eurjchem-125	97	72	dq	dq	PROPN
eurjchem-125	97	73	,	,	PUNCT
eurjchem-125	97	74	j=8.07	j=8.07	X
eurjchem-125	97	75	hz	hz	PROPN
eurjchem-125	97	76	,	,	PUNCT
eurjchem-125	97	77	j=6.60	j=6.60	PROPN
eurjchem-125	97	78	hz	hz	NOUN
eurjchem-125	97	79	)	)	PUNCT
eurjchem-125	97	80	,	,	PUNCT
eurjchem-125	97	81	5.82	5.82	NUM
eurjchem-125	97	82	(	(	PUNCT
eurjchem-125	97	83	1h	1h	NUM
eurjchem-125	97	84	,	,	PUNCT
eurjchem-125	97	85	och	och	NUM
eurjchem-125	97	86	,	,	PUNCT
eurjchem-125	97	87	d	d	PROPN
eurjchem-125	97	88	,	,	PUNCT
eurjchem-125	97	89	j=8.07	j=8.07	X
eurjchem-125	97	90	hz	hz	PROPN
eurjchem-125	97	91	)	)	PUNCT
eurjchem-125	97	92	,	,	PUNCT
eurjchem-125	97	93	7.07–6.99	7.07–6.99	NUM
eurjchem-125	97	94	(	(	PUNCT
eurjchem-125	97	95	2h	2h	NUM
eurjchem-125	97	96	,	,	PUNCT
eurjchem-125	97	97	two	two	NUM
eurjchem-125	97	98	ch	ch	NOUN
eurjchem-125	97	99	,	,	PUNCT
eurjchem-125	97	100	m	m	NOUN
eurjchem-125	97	101	,	,	PUNCT
eurjchem-125	97	102	thiophene	thiophene	NOUN
eurjchem-125	97	103	)	)	PUNCT
eurjchem-125	97	104	,	,	PUNCT
eurjchem-125	97	105	7.34	7.34	NUM
eurjchem-125	97	106	(	(	PUNCT
eurjchem-125	97	107	1h	1h	NUM
eurjchem-125	97	108	,	,	PUNCT
eurjchem-125	97	109	sch	sch	INTJ
eurjchem-125	97	110	,	,	PUNCT
eurjchem-125	97	111	dd	dd	NOUN
eurjchem-125	97	112	,	,	PUNCT
eurjchem-125	97	113	j=2.20	j=2.20	NOUN
eurjchem-125	97	114	hz	hz	NOUN
eurjchem-125	97	115	,	,	PUNCT
eurjchem-125	97	116	j=4.16	j=4.16	PROPN
eurjchem-125	97	117	hz	hz	NOUN
eurjchem-125	97	118	,	,	PUNCT
eurjchem-125	97	119	thiophene	thiophene	NOUN
eurjchem-125	97	120	)	)	PUNCT
eurjchem-125	97	121	.	.	PUNCT
eurjchem-125	98	1	13c	13c	NOUN
eurjchem-125	98	2	nmr	nmr	NOUN
eurjchem-125	98	3	(	(	PUNCT
eurjchem-125	98	4	cdcl3	cdcl3	NOUN
eurjchem-125	98	5	):	):	PUNCT
eurjchem-125	98	6	13.8	13.8	NUM
eurjchem-125	98	7	(	(	PUNCT
eurjchem-125	98	8	ch3	ch3	PROPN
eurjchem-125	98	9	)	)	PUNCT
eurjchem-125	98	10	,	,	PUNCT
eurjchem-125	98	11	50.9	50.9	NUM
eurjchem-125	98	12	(	(	PUNCT
eurjchem-125	98	13	nch2	nch2	PROPN
eurjchem-125	98	14	,	,	PUNCT
eurjchem-125	98	15	morpholine	morpholine	PROPN
eurjchem-125	98	16	)	)	PUNCT
eurjchem-125	98	17	,	,	PUNCT
eurjchem-125	98	18	54.9	54.9	NUM
eurjchem-125	98	19	(	(	PUNCT
eurjchem-125	98	20	nch	nch	NOUN
eurjchem-125	98	21	,	,	PUNCT
eurjchem-125	98	22	oxazolidinone	oxazolidinone	NUM
eurjchem-125	98	23	)	)	PUNCT
eurjchem-125	98	24	,	,	PUNCT
eurjchem-125	98	25	64.4	64.4	NUM
eurjchem-125	98	26	(	(	PUNCT
eurjchem-125	98	27	nch2n	nch2n	PROPN
eurjchem-125	98	28	)	)	PUNCT
eurjchem-125	98	29	,	,	PUNCT
eurjchem-125	98	30	66.7	66.7	NUM
eurjchem-125	98	31	(	(	PUNCT
eurjchem-125	98	32	och2	och2	PROPN
eurjchem-125	98	33	,	,	PUNCT
eurjchem-125	98	34	morpholine	morpholine	NOUN
eurjchem-125	98	35	)	)	PUNCT
eurjchem-125	98	36	,	,	PUNCT
eurjchem-125	98	37	75.8	75.8	NUM
eurjchem-125	98	38	(	(	PUNCT
eurjchem-125	98	39	och	och	NOUN
eurjchem-125	98	40	)	)	PUNCT
eurjchem-125	98	41	,	,	PUNCT
eurjchem-125	98	42	125.9	125.9	NUM
eurjchem-125	98	43	,	,	PUNCT
eurjchem-125	98	44	126.2	126.2	NUM
eurjchem-125	98	45	,	,	PUNCT
eurjchem-125	98	46	126.8	126.8	NUM
eurjchem-125	98	47	(	(	PUNCT
eurjchem-125	98	48	ch	ch	NOUN
eurjchem-125	98	49	,	,	PUNCT
eurjchem-125	98	50	thiophene	thiophene	NOUN
eurjchem-125	98	51	)	)	PUNCT
eurjchem-125	98	52	,	,	PUNCT
eurjchem-125	98	53	137.4	137.4	NUM
eurjchem-125	98	54	(	(	PUNCT
eurjchem-125	98	55	c	c	NOUN
eurjchem-125	98	56	,	,	PUNCT
eurjchem-125	98	57	thiophene	thiophene	NOUN
eurjchem-125	98	58	)	)	PUNCT
eurjchem-125	98	59	,	,	PUNCT
eurjchem-125	98	60	157.4	157.4	NUM
eurjchem-125	98	61	(	(	PUNCT
eurjchem-125	98	62	c	c	NOUN
eurjchem-125	98	63	=	=	NOUN
eurjchem-125	98	64	o	o	NOUN
eurjchem-125	98	65	)	)	PUNCT
eurjchem-125	98	66	.	.	PUNCT
eurjchem-125	99	1	anal	anal	PROPN
eurjchem-125	99	2	.	.	PUNCT
eurjchem-125	99	3	calcd	calcd	NOUN
eurjchem-125	99	4	.	.	PUNCT
eurjchem-125	100	1	for	for	ADP
eurjchem-125	100	2	c13h18n2o3s	c13h18n2o3s	NUM
eurjchem-125	100	3	c	c	NOUN
eurjchem-125	100	4	,	,	PUNCT
eurjchem-125	100	5	55.30	55.30	NUM
eurjchem-125	100	6	;	;	PUNCT
eurjchem-125	100	7	h	h	NOUN
eurjchem-125	100	8	,	,	PUNCT
eurjchem-125	100	9	6.43	6.43	NUM
eurjchem-125	100	10	;	;	PUNCT
eurjchem-125	100	11	n	n	CCONJ
eurjchem-125	100	12	,	,	PUNCT
eurjchem-125	100	13	9.92	9.92	NUM
eurjchem-125	100	14	;	;	PUNCT
eurjchem-125	100	15	s	s	NOUN
eurjchem-125	100	16	,	,	PUNCT
eurjchem-125	100	17	11.37	11.37	NUM
eurjchem-125	100	18	;	;	PUNCT
eurjchem-125	100	19	found	find	VERB
eurjchem-125	100	20	:	:	PUNCT
eurjchem-125	100	21	c	c	X
eurjchem-125	100	22	,	,	PUNCT
eurjchem-125	100	23	55.35	55.35	NUM
eurjchem-125	100	24	;	;	PUNCT
eurjchem-125	100	25	h	h	NOUN
eurjchem-125	100	26	,	,	PUNCT
eurjchem-125	100	27	6.37	6.37	NUM
eurjchem-125	100	28	;	;	PUNCT
eurjchem-125	100	29	n	n	CCONJ
eurjchem-125	100	30	,	,	PUNCT
eurjchem-125	100	31	9.85	9.85	NUM
eurjchem-125	100	32	;	;	PUNCT
eurjchem-125	100	33	s	s	X
eurjchem-125	100	34	,	,	PUNCT
eurjchem-125	100	35	11.29	11.29	NUM
eurjchem-125	100	36	.	.	PUNCT
eurjchem-125	101	1	anti‐1‐{[4‐methyl‐2‐oxo‐5‐thien‐2‐yl‐1,3‐oxazolidin‐3‐	anti‐1‐{[4‐methyl‐2‐oxo‐5‐thien‐2‐yl‐1,3‐oxazolidin‐3‐	NUM
eurjchem-125	101	2	yl]methyl}piperidinium	yl]methyl}piperidinium	NOUN
eurjchem-125	101	3	chloride	chloride	NOUN
eurjchem-125	101	4	,	,	PUNCT
eurjchem-125	101	5	5b	5b	NUM
eurjchem-125	101	6	:	:	PUNCT
eurjchem-125	101	7	after	after	ADP
eurjchem-125	101	8	removing	remove	VERB
eurjchem-125	101	9	ethanol	ethanol	NOUN
eurjchem-125	101	10	and	and	CCONJ
eurjchem-125	101	11	water	water	NOUN
eurjchem-125	101	12	under	under	ADP
eurjchem-125	101	13	reduced	reduce	VERB
eurjchem-125	101	14	pressure	pressure	NOUN
eurjchem-125	101	15	dry	dry	ADJ
eurjchem-125	101	16	diethyl	diethyl	NOUN
eurjchem-125	101	17	ether	ether	NOUN
eurjchem-125	101	18	was	be	AUX
eurjchem-125	101	19	added	add	VERB
eurjchem-125	101	20	to	to	ADP
eurjchem-125	101	21	the	the	DET
eurjchem-125	101	22	oil	oil	NOUN
eurjchem-125	101	23	residue	residue	NOUN
eurjchem-125	101	24	.	.	PUNCT
eurjchem-125	102	1	saturating	saturate	VERB
eurjchem-125	102	2	ether	ether	ADJ
eurjchem-125	102	3	solution	solution	NOUN
eurjchem-125	102	4	with	with	ADP
eurjchem-125	102	5	dry	dry	ADJ
eurjchem-125	102	6	hcl	hcl	PROPN
eurjchem-125	102	7	gas	gas	NOUN
eurjchem-125	102	8	resulted	result	VERB
eurjchem-125	102	9	in	in	ADP
eurjchem-125	102	10	the	the	DET
eurjchem-125	102	11	formation	formation	NOUN
eurjchem-125	102	12	of	of	ADP
eurjchem-125	102	13	hydrogen	hydrogen	NOUN
eurjchem-125	102	14	chloride	chloride	NOUN
eurjchem-125	102	15	of	of	ADP
eurjchem-125	102	16	the	the	DET
eurjchem-125	102	17	mannich	mannich	NOUN
eurjchem-125	102	18	base	base	NOUN
eurjchem-125	102	19	.	.	PUNCT
eurjchem-125	103	1	yield	yield	VERB
eurjchem-125	103	2	68	68	NUM
eurjchem-125	103	3	%	%	NOUN
eurjchem-125	103	4	,	,	PUNCT
eurjchem-125	103	5	recrystallization	recrystallization	NOUN
eurjchem-125	103	6	with	with	ADP
eurjchem-125	103	7	ether	ether	NOUN
eurjchem-125	103	8	:	:	PUNCT
eurjchem-125	103	9	ethanol	ethanol	NOUN
eurjchem-125	103	10	(	(	PUNCT
eurjchem-125	103	11	2:1	2:1	NUM
eurjchem-125	103	12	)	)	PUNCT
eurjchem-125	103	13	.	.	PUNCT
eurjchem-125	104	1	m.p	m.p	PROPN
eurjchem-125	104	2	.	.	PROPN
eurjchem-125	104	3	:	:	PUNCT
eurjchem-125	105	1	156‐158	156‐158	NUM
eurjchem-125	105	2	°	°	NUM
eurjchem-125	105	3	c	c	VERB
eurjchem-125	105	4	.	.	PUNCT
eurjchem-125	106	1	rf	rf	NOUN
eurjchem-125	106	2	=	=	NOUN
eurjchem-125	106	3	0.5	0.5	NUM
eurjchem-125	106	4	,	,	PUNCT
eurjchem-125	106	5	mobile	mobile	ADJ
eurjchem-125	106	6	phase	phase	NOUN
eurjchem-125	106	7	benzene	benzene	NOUN
eurjchem-125	106	8	:	:	PUNCT
eurjchem-125	106	9	diethyl	diethyl	NOUN
eurjchem-125	106	10	ether	ether	NOUN
eurjchem-125	106	11	:	:	PUNCT
eurjchem-125	106	12	ethanol	ethanol	NOUN
eurjchem-125	106	13	(	(	PUNCT
eurjchem-125	106	14	4:1:3	4:1:3	NUM
eurjchem-125	106	15	)	)	PUNCT
eurjchem-125	106	16	,	,	PUNCT
eurjchem-125	106	17	silica	silica	NOUN
eurjchem-125	106	18	gel	gel	NOUN
eurjchem-125	106	19	f254	f254	PROPN
eurjchem-125	106	20	.	.	PROPN
eurjchem-125	107	1	1h	1h	NUM
eurjchem-125	107	2	nmr	nmr	NOUN
eurjchem-125	107	3	(	(	PUNCT
eurjchem-125	107	4	dmso‐d6	dmso‐d6	NOUN
eurjchem-125	107	5	):	):	PUNCT
eurjchem-125	107	6	1.38	1.38	NUM
eurjchem-125	107	7	(	(	PUNCT
eurjchem-125	107	8	3h	3h	NUM
eurjchem-125	107	9	,	,	PUNCT
eurjchem-125	107	10	ch3	ch3	PROPN
eurjchem-125	107	11	,	,	PUNCT
eurjchem-125	107	12	d	d	PROPN
eurjchem-125	107	13	,	,	PUNCT
eurjchem-125	107	14	j=6.60	j=6.60	PROPN
eurjchem-125	107	15	hz	hz	NOUN
eurjchem-125	107	16	)	)	PUNCT
eurjchem-125	107	17	,	,	PUNCT
eurjchem-125	107	18	1.60‐1.98	1.60‐1.98	NUM
eurjchem-125	107	19	(	(	PUNCT
eurjchem-125	107	20	6h	6h	NUM
eurjchem-125	107	21	,	,	PUNCT
eurjchem-125	107	22	m	m	PROPN
eurjchem-125	107	23	,	,	PUNCT
eurjchem-125	107	24	3	3	NUM
eurjchem-125	107	25	ch2	ch2	NOUN
eurjchem-125	107	26	,	,	PUNCT
eurjchem-125	107	27	piperidine	piperidine	NOUN
eurjchem-125	107	28	)	)	PUNCT
eurjchem-125	107	29	,	,	PUNCT
eurjchem-125	107	30	2.68‐3.10	2.68‐3.10	NUM
eurjchem-125	107	31	(	(	PUNCT
eurjchem-125	107	32	2h	2h	NUM
eurjchem-125	107	33	,	,	PUNCT
eurjchem-125	107	34	m	m	PROPN
eurjchem-125	107	35	,	,	PUNCT
eurjchem-125	107	36	nch2	nch2	NOUN
eurjchem-125	107	37	,	,	PUNCT
eurjchem-125	107	38	piperidine	piperidine	NOUN
eurjchem-125	107	39	)	)	PUNCT
eurjchem-125	107	40	,	,	PUNCT
eurjchem-125	107	41	3.17‐3.48	3.17‐3.48	NUM
eurjchem-125	107	42	(	(	PUNCT
eurjchem-125	107	43	2h	2h	NUM
eurjchem-125	107	44	,	,	PUNCT
eurjchem-125	107	45	m	m	PROPN
eurjchem-125	107	46	,	,	PUNCT
eurjchem-125	107	47	nch2	nch2	NOUN
eurjchem-125	107	48	,	,	PUNCT
eurjchem-125	107	49	piperidine	piperidine	NOUN
eurjchem-125	107	50	)	)	PUNCT
eurjchem-125	107	51	,	,	PUNCT
eurjchem-125	107	52	4.43‐4.67	4.43‐4.67	NUM
eurjchem-125	107	53	(	(	PUNCT
eurjchem-125	107	54	3h	3h	NUM
eurjchem-125	107	55	,	,	PUNCT
eurjchem-125	107	56	m	m	PROPN
eurjchem-125	107	57	,	,	PUNCT
eurjchem-125	107	58	nch2n	nch2n	PROPN
eurjchem-125	107	59	,	,	PUNCT
eurjchem-125	107	60	overlapped	overlap	VERB
eurjchem-125	107	61	with	with	ADP
eurjchem-125	107	62	nch	nch	PROPN
eurjchem-125	107	63	from	from	ADP
eurjchem-125	107	64	oxazolidinone	oxazolidinone	NUM
eurjchem-125	107	65	)	)	PUNCT
eurjchem-125	107	66	,	,	PUNCT
eurjchem-125	107	67	5.56	5.56	NUM
eurjchem-125	107	68	(	(	PUNCT
eurjchem-125	107	69	1h	1h	NUM
eurjchem-125	107	70	,	,	PUNCT
eurjchem-125	107	71	och	och	NUM
eurjchem-125	107	72	,	,	PUNCT
eurjchem-125	107	73	d	d	PROPN
eurjchem-125	107	74	,	,	PUNCT
eurjchem-125	107	75	j=6.11	j=6.11	PROPN
eurjchem-125	107	76	hz	hz	VERB
eurjchem-125	107	77	,	,	PUNCT
eurjchem-125	107	78	oxazolidin	oxazolidin	VERB
eurjchem-125	107	79	one	one	NUM
eurjchem-125	107	80	)	)	PUNCT
eurjchem-125	107	81	,	,	PUNCT
eurjchem-125	107	82	7.10	7.10	NUM
eurjchem-125	107	83	(	(	PUNCT
eurjchem-125	107	84	1h	1h	NUM
eurjchem-125	107	85	,	,	PUNCT
eurjchem-125	107	86	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	107	87	,	,	PUNCT
eurjchem-125	107	88	dd	dd	NOUN
eurjchem-125	107	89	,	,	PUNCT
eurjchem-125	107	90	j=3.42	j=3.42	PRON
eurjchem-125	107	91	hz	hz	PROPN
eurjchem-125	107	92	,	,	PUNCT
eurjchem-125	107	93	j=5.14	j=5.14	PROPN
eurjchem-125	107	94	hz	hz	NOUN
eurjchem-125	107	95	)	)	PUNCT
eurjchem-125	107	96	,	,	PUNCT
eurjchem-125	107	97	7.41	7.41	NUM
eurjchem-125	107	98	(	(	PUNCT
eurjchem-125	107	99	1h	1h	NUM
eurjchem-125	107	100	,	,	PUNCT
eurjchem-125	107	101	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	107	102	,	,	PUNCT
eurjchem-125	107	103	dd	dd	NOUN
eurjchem-125	107	104	,	,	PUNCT
eurjchem-125	107	105	j=3.42	j=3.42	PRON
eurjchem-125	107	106	hz	hz	PROPN
eurjchem-125	107	107	,	,	PUNCT
eurjchem-125	107	108	j=1.22	j=1.22	PROPN
eurjchem-125	107	109	hz	hz	PROPN
eurjchem-125	107	110	)	)	PUNCT
eurjchem-125	107	111	,	,	PUNCT
eurjchem-125	107	112	7.68	7.68	NUM
eurjchem-125	107	113	(	(	PUNCT
eurjchem-125	107	114	1h	1h	NUM
eurjchem-125	107	115	,	,	PUNCT
eurjchem-125	107	116	sch	sch	INTJ
eurjchem-125	107	117	,	,	PUNCT
eurjchem-125	107	118	dd	dd	VERB
eurjchem-125	107	119	,	,	PUNCT
eurjchem-125	107	120	j=1.22	j=1.22	PROPN
eurjchem-125	107	121	hz	hz	PROPN
eurjchem-125	107	122	,	,	PUNCT
eurjchem-125	107	123	j=5.14	j=5.14	PROPN
eurjchem-125	107	124	hz	hz	NOUN
eurjchem-125	107	125	)	)	PUNCT
eurjchem-125	107	126	,	,	PUNCT
eurjchem-125	107	127	11.29	11.29	NUM
eurjchem-125	107	128	(	(	PUNCT
eurjchem-125	107	129	1h	1h	NUM
eurjchem-125	107	130	,	,	PUNCT
eurjchem-125	107	131	nh	nh	PROPN
eurjchem-125	107	132	,	,	PUNCT
eurjchem-125	107	133	bs	bs	NOUN
eurjchem-125	107	134	)	)	PUNCT
eurjchem-125	107	135	.	.	PUNCT
eurjchem-125	108	1	13c	13c	NOUN
eurjchem-125	108	2	nmr	nmr	NOUN
eurjchem-125	108	3	(	(	PUNCT
eurjchem-125	108	4	dmso‐d6	dmso‐d6	NOUN
eurjchem-125	108	5	):	):	PUNCT
eurjchem-125	108	6	16.7	16.7	NUM
eurjchem-125	108	7	(	(	PUNCT
eurjchem-125	108	8	ch3	ch3	PROPN
eurjchem-125	108	9	)	)	PUNCT
eurjchem-125	108	10	,	,	PUNCT
eurjchem-125	108	11	21.4	21.4	NUM
eurjchem-125	108	12	(	(	PUNCT
eurjchem-125	108	13	ch2	ch2	PROPN
eurjchem-125	108	14	,	,	PUNCT
eurjchem-125	108	15	piperidine	piperidine	NOUN
eurjchem-125	108	16	)	)	PUNCT
eurjchem-125	108	17	,	,	PUNCT
eurjchem-125	108	18	21.7	21.7	NUM
eurjchem-125	108	19	(	(	PUNCT
eurjchem-125	108	20	ch2	ch2	PROPN
eurjchem-125	108	21	,	,	PUNCT
eurjchem-125	108	22	piperidine	piperidine	NOUN
eurjchem-125	108	23	)	)	PUNCT
eurjchem-125	108	24	,	,	PUNCT
eurjchem-125	108	25	48.9	48.9	NUM
eurjchem-125	108	26	(	(	PUNCT
eurjchem-125	108	27	nch2	nch2	NOUN
eurjchem-125	108	28	,	,	PUNCT
eurjchem-125	108	29	piperidine	piperidine	NOUN
eurjchem-125	108	30	)	)	PUNCT
eurjchem-125	108	31	,	,	PUNCT
eurjchem-125	108	32	49.9	49.9	NUM
eurjchem-125	108	33	(	(	PUNCT
eurjchem-125	108	34	nch2	nch2	NOUN
eurjchem-125	108	35	,	,	PUNCT
eurjchem-125	108	36	piperidine	piperidine	NOUN
eurjchem-125	108	37	)	)	PUNCT
eurjchem-125	108	38	,	,	PUNCT
eurjchem-125	108	39	57.8	57.8	NUM
eurjchem-125	108	40	(	(	PUNCT
eurjchem-125	108	41	nch	nch	NOUN
eurjchem-125	108	42	,	,	PUNCT
eurjchem-125	108	43	oxazolidinone	oxazolidinone	NUM
eurjchem-125	108	44	)	)	PUNCT
eurjchem-125	108	45	,	,	PUNCT
eurjchem-125	108	46	60.5	60.5	NUM
eurjchem-125	108	47	(	(	PUNCT
eurjchem-125	108	48	nch2n	nch2n	PROPN
eurjchem-125	108	49	)	)	PUNCT
eurjchem-125	108	50	,	,	PUNCT
eurjchem-125	108	51	77.8	77.8	NUM
eurjchem-125	108	52	(	(	PUNCT
eurjchem-125	108	53	och	och	ADJ
eurjchem-125	108	54	,	,	PUNCT
eurjchem-125	108	55	oxazolidinone	oxazolidinone	NUM
eurjchem-125	108	56	)	)	PUNCT
eurjchem-125	108	57	,	,	PUNCT
eurjchem-125	108	58	127.2	127.2	NUM
eurjchem-125	108	59	,	,	PUNCT
eurjchem-125	108	60	127.8	127.8	NUM
eurjchem-125	108	61	,	,	PUNCT
eurjchem-125	108	62	128.0	128.0	NUM
eurjchem-125	108	63	(	(	PUNCT
eurjchem-125	108	64	ch	ch	NOUN
eurjchem-125	108	65	,	,	PUNCT
eurjchem-125	108	66	thiophene	thiophene	NOUN
eurjchem-125	108	67	)	)	PUNCT
eurjchem-125	108	68	.	.	PUNCT
eurjchem-125	109	1	anal	anal	PROPN
eurjchem-125	109	2	.	.	PUNCT
eurjchem-125	109	3	calcd	calcd	NOUN
eurjchem-125	109	4	.	.	PUNCT
eurjchem-125	110	1	for	for	ADP
eurjchem-125	110	2	c14h21cln2o2s	c14h21cln2o2s	NOUN
eurjchem-125	110	3	:	:	PUNCT
eurjchem-125	110	4	c	c	X
eurjchem-125	110	5	,	,	PUNCT
eurjchem-125	110	6	53.07	53.07	NUM
eurjchem-125	110	7	;	;	PUNCT
eurjchem-125	110	8	h	h	X
eurjchem-125	110	9	,	,	PUNCT
eurjchem-125	110	10	6.68	6.68	NUM
eurjchem-125	110	11	;	;	PUNCT
eurjchem-125	110	12	cl	cl	NOUN
eurjchem-125	110	13	,	,	PUNCT
eurjchem-125	110	14	11.19	11.19	NUM
eurjchem-125	110	15	;	;	PUNCT
eurjchem-125	110	16	n	n	CCONJ
eurjchem-125	110	17	,	,	PUNCT
eurjchem-125	110	18	8.84	8.84	NUM
eurjchem-125	110	19	;	;	PUNCT
eurjchem-125	110	20	s	s	X
eurjchem-125	110	21	,	,	PUNCT
eurjchem-125	110	22	10.12	10.12	NUM
eurjchem-125	110	23	;	;	PUNCT
eurjchem-125	110	24	found	find	VERB
eurjchem-125	110	25	:	:	PUNCT
eurjchem-125	110	26	c	c	X
eurjchem-125	110	27	,	,	PUNCT
eurjchem-125	110	28	53.11	53.11	NUM
eurjchem-125	110	29	;	;	PUNCT
eurjchem-125	110	30	h	h	NOUN
eurjchem-125	110	31	,	,	PUNCT
eurjchem-125	110	32	6.62	6.62	NUM
eurjchem-125	110	33	;	;	PUNCT
eurjchem-125	110	34	cl	cl	NOUN
eurjchem-125	110	35	,	,	PUNCT
eurjchem-125	110	36	11.26	11.26	NUM
eurjchem-125	110	37	;	;	PUNCT
eurjchem-125	110	38	n	n	CCONJ
eurjchem-125	110	39	,	,	PUNCT
eurjchem-125	110	40	8.78	8.78	NUM
eurjchem-125	110	41	;	;	PUNCT
eurjchem-125	110	42	s	s	NUM
eurjchem-125	110	43	,	,	PUNCT
eurjchem-125	110	44	10.17	10.17	NUM
eurjchem-125	110	45	.	.	PUNCT
eurjchem-125	111	1	syn‐1‐{[(4‐methyl‐2‐oxo‐5‐thien‐2‐yl‐1,3‐oxazolidin‐3‐	syn‐1‐{[(4‐methyl‐2‐oxo‐5‐thien‐2‐yl‐1,3‐oxazolidin‐3‐	NOUN
eurjchem-125	111	2	yl]methyl}piperidinium	yl]methyl}piperidinium	NOUN
eurjchem-125	111	3	chloride	chloride	NOUN
eurjchem-125	111	4	,	,	PUNCT
eurjchem-125	111	5	7b	7b	NOUN
eurjchem-125	111	6	:	:	PUNCT
eurjchem-125	111	7	after	after	ADP
eurjchem-125	111	8	removing	remove	VERB
eurjchem-125	111	9	ethanol	ethanol	NOUN
eurjchem-125	111	10	and	and	CCONJ
eurjchem-125	111	11	water	water	NOUN
eurjchem-125	111	12	under	under	ADP
eurjchem-125	111	13	reduced	reduce	VERB
eurjchem-125	111	14	pressure	pressure	NOUN
eurjchem-125	111	15	dry	dry	ADJ
eurjchem-125	111	16	diethyl	diethyl	NOUN
eurjchem-125	111	17	ether	ether	NOUN
eurjchem-125	111	18	was	be	AUX
eurjchem-125	111	19	added	add	VERB
eurjchem-125	111	20	to	to	ADP
eurjchem-125	111	21	the	the	DET
eurjchem-125	111	22	oil	oil	NOUN
eurjchem-125	111	23	residue	residue	NOUN
eurjchem-125	111	24	.	.	PUNCT
eurjchem-125	112	1	saturating	saturate	VERB
eurjchem-125	112	2	of	of	ADP
eurjchem-125	112	3	ether	ether	ADJ
eurjchem-125	112	4	solution	solution	NOUN
eurjchem-125	112	5	with	with	ADP
eurjchem-125	112	6	dry	dry	ADJ
eurjchem-125	112	7	hcl	hcl	PROPN
eurjchem-125	112	8	gas	gas	NOUN
eurjchem-125	112	9	resulted	result	VERB
eurjchem-125	112	10	to	to	ADP
eurjchem-125	112	11	the	the	DET
eurjchem-125	112	12	formation	formation	NOUN
eurjchem-125	112	13	of	of	ADP
eurjchem-125	112	14	hydrogen	hydrogen	NOUN
eurjchem-125	112	15	chloride	chloride	NOUN
eurjchem-125	112	16	of	of	ADP
eurjchem-125	112	17	mannich	mannich	PRON
eurjchem-125	112	18	base	base	NOUN
eurjchem-125	112	19	.	.	PUNCT
eurjchem-125	113	1	yield	yield	VERB
eurjchem-125	113	2	68	68	NUM
eurjchem-125	113	3	%	%	NOUN
eurjchem-125	113	4	,	,	PUNCT
eurjchem-125	113	5	after	after	ADP
eurjchem-125	113	6	recrystallization	recrystallization	NOUN
eurjchem-125	113	7	with	with	ADP
eurjchem-125	113	8	ether	ether	NOUN
eurjchem-125	113	9	:	:	PUNCT
eurjchem-125	113	10	ethanol	ethanol	NOUN
eurjchem-125	113	11	(	(	PUNCT
eurjchem-125	113	12	2:1	2:1	NUM
eurjchem-125	113	13	)	)	PUNCT
eurjchem-125	113	14	.	.	PUNCT
eurjchem-125	114	1	m.p	m.p	PROPN
eurjchem-125	114	2	.	.	PROPN
eurjchem-125	114	3	:	:	PUNCT
eurjchem-125	115	1	181‐182	181‐182	NUM
eurjchem-125	115	2	°	°	NUM
eurjchem-125	115	3	c	c	VERB
eurjchem-125	115	4	.	.	PUNCT
eurjchem-125	116	1	rf	rf	VERB
eurjchem-125	116	2	=	=	NOUN
eurjchem-125	116	3	0.68	0.68	NUM
eurjchem-125	116	4	,	,	PUNCT
eurjchem-125	116	5	mobile	mobile	ADJ
eurjchem-125	116	6	phase	phase	NOUN
eurjchem-125	116	7	benzene	benzene	NOUN
eurjchem-125	116	8	:	:	PUNCT
eurjchem-125	116	9	diethyl	diethyl	NOUN
eurjchem-125	116	10	ether	ether	NOUN
eurjchem-125	116	11	:	:	PUNCT
eurjchem-125	116	12	ethanol	ethanol	NOUN
eurjchem-125	116	13	(	(	PUNCT
eurjchem-125	116	14	4:1:3	4:1:3	NUM
eurjchem-125	116	15	)	)	PUNCT
eurjchem-125	116	16	,	,	PUNCT
eurjchem-125	116	17	silica	silica	NOUN
eurjchem-125	116	18	gel	gel	NOUN
eurjchem-125	116	19	f254	f254	PROPN
eurjchem-125	116	20	.	.	PROPN
eurjchem-125	117	1	1h	1h	NUM
eurjchem-125	117	2	nmr	nmr	NOUN
eurjchem-125	117	3	(	(	PUNCT
eurjchem-125	117	4	dmso‐d6	dmso‐d6	NOUN
eurjchem-125	117	5	):	):	PUNCT
eurjchem-125	117	6	0.93	0.93	NUM
eurjchem-125	117	7	(	(	PUNCT
eurjchem-125	117	8	3h	3h	NUM
eurjchem-125	117	9	,	,	PUNCT
eurjchem-125	117	10	ch3	ch3	PROPN
eurjchem-125	117	11	,	,	PUNCT
eurjchem-125	117	12	d	d	PROPN
eurjchem-125	117	13	,	,	PUNCT
eurjchem-125	117	14	j=6.60	j=6.60	PROPN
eurjchem-125	117	15	hz	hz	NOUN
eurjchem-125	117	16	)	)	PUNCT
eurjchem-125	117	17	,	,	PUNCT
eurjchem-125	117	18	1.62‐1.96	1.62‐1.96	NUM
eurjchem-125	117	19	(	(	PUNCT
eurjchem-125	117	20	6h	6h	NUM
eurjchem-125	117	21	,	,	PUNCT
eurjchem-125	117	22	m	m	PROPN
eurjchem-125	117	23	,	,	PUNCT
eurjchem-125	117	24	3	3	NUM
eurjchem-125	117	25	ch2	ch2	NOUN
eurjchem-125	117	26	from	from	ADP
eurjchem-125	117	27	piperidine	piperidine	NOUN
eurjchem-125	117	28	)	)	PUNCT
eurjchem-125	117	29	,	,	PUNCT
eurjchem-125	117	30	2.67‐3.11	2.67‐3.11	NUM
eurjchem-125	117	31	(	(	PUNCT
eurjchem-125	117	32	2h	2h	NUM
eurjchem-125	117	33	,	,	PUNCT
eurjchem-125	117	34	m	m	PROPN
eurjchem-125	117	35	,	,	PUNCT
eurjchem-125	117	36	nch2	nch2	NOUN
eurjchem-125	117	37	,	,	PUNCT
eurjchem-125	117	38	piperidine	piperidine	NOUN
eurjchem-125	117	39	)	)	PUNCT
eurjchem-125	117	40	,	,	PUNCT
eurjchem-125	117	41	3.31‐3.58	3.31‐3.58	NUM
eurjchem-125	117	42	(	(	PUNCT
eurjchem-125	117	43	2h	2h	NUM
eurjchem-125	117	44	,	,	PUNCT
eurjchem-125	117	45	m	m	PROPN
eurjchem-125	117	46	,	,	PUNCT
eurjchem-125	117	47	nch2	nch2	NOUN
eurjchem-125	117	48	,	,	PUNCT
eurjchem-125	117	49	piperidine	piperidine	NOUN
eurjchem-125	117	50	)	)	PUNCT
eurjchem-125	117	51	,	,	PUNCT
eurjchem-125	117	52	4.42‐4.54	4.42‐4.54	NUM
eurjchem-125	117	53	(	(	PUNCT
eurjchem-125	117	54	1h	1h	NUM
eurjchem-125	117	55	,	,	PUNCT
eurjchem-125	117	56	nhchn	nhchn	NOUN
eurjchem-125	117	57	,	,	PUNCT
eurjchem-125	117	58	d	d	PROPN
eurjchem-125	117	59	,	,	PUNCT
eurjchem-125	117	60	j=13.45	j=13.45	PROPN
eurjchem-125	117	61	hz	hz	PROPN
eurjchem-125	117	62	)	)	PUNCT
eurjchem-125	117	63	,	,	PUNCT
eurjchem-125	117	64	4.54‐4.80	4.54‐4.80	NUM
eurjchem-125	117	65	(	(	PUNCT
eurjchem-125	117	66	2h	2h	NUM
eurjchem-125	117	67	,	,	PUNCT
eurjchem-125	117	68	m	m	PRON
eurjchem-125	117	69	,	,	PUNCT
eurjchem-125	117	70	nhchn	nhchn	PROPN
eurjchem-125	117	71	overlapped	overlapped	ADJ
eurjchem-125	117	72	with	with	ADP
eurjchem-125	117	73	nch	nch	PROPN
eurjchem-125	117	74	from	from	ADP
eurjchem-125	117	75	oxazolidinone	oxazolidinone	NUM
eurjchem-125	117	76	)	)	PUNCT
eurjchem-125	117	77	,	,	PUNCT
eurjchem-125	117	78	6.18	6.18	NUM
eurjchem-125	117	79	(	(	PUNCT
eurjchem-125	117	80	1h	1h	NUM
eurjchem-125	117	81	,	,	PUNCT
eurjchem-125	117	82	och	och	NUM
eurjchem-125	117	83	,	,	PUNCT
eurjchem-125	117	84	d	d	PROPN
eurjchem-125	117	85	,	,	PUNCT
eurjchem-125	117	86	j=7.58	j=7.58	PROPN
eurjchem-125	117	87	hz	hz	NOUN
eurjchem-125	117	88	)	)	PUNCT
eurjchem-125	117	89	,	,	PUNCT
eurjchem-125	117	90	7.11	7.11	NUM
eurjchem-125	117	91	(	(	PUNCT
eurjchem-125	117	92	1h	1h	NUM
eurjchem-125	117	93	,	,	PUNCT
eurjchem-125	117	94	sch‐ch‐	sch‐ch‐	PROPN
eurjchem-125	117	95	ch	ch	NOUN
eurjchem-125	117	96	,	,	PUNCT
eurjchem-125	117	97	dd	dd	NOUN
eurjchem-125	117	98	,	,	PUNCT
eurjchem-125	117	99	j=3.55	j=3.55	NOUN
eurjchem-125	117	100	hz	hz	PART
eurjchem-125	117	101	,	,	PUNCT
eurjchem-125	117	102	j=5.14	j=5.14	PROPN
eurjchem-125	117	103	hz	hz	NOUN
eurjchem-125	117	104	)	)	PUNCT
eurjchem-125	117	105	,	,	PUNCT
eurjchem-125	117	106	7.18	7.18	NUM
eurjchem-125	117	107	(	(	PUNCT
eurjchem-125	117	108	1h	1h	NUM
eurjchem-125	117	109	,	,	PUNCT
eurjchem-125	117	110	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	117	111	,	,	PUNCT
eurjchem-125	117	112	dd	dd	NOUN
eurjchem-125	117	113	,	,	PUNCT
eurjchem-125	117	114	j=3.42	j=3.42	PRON
eurjchem-125	117	115	hz	hz	PROPN
eurjchem-125	117	116	,	,	PUNCT
eurjchem-125	117	117	j=1.22	j=1.22	PROPN
eurjchem-125	117	118	hz	hz	PROPN
eurjchem-125	117	119	)	)	PUNCT
eurjchem-125	117	120	,	,	PUNCT
eurjchem-125	117	121	7.63	7.63	NUM
eurjchem-125	117	122	(	(	PUNCT
eurjchem-125	117	123	1h	1h	NUM
eurjchem-125	117	124	,	,	PUNCT
eurjchem-125	117	125	sch	sch	INTJ
eurjchem-125	117	126	,	,	PUNCT
eurjchem-125	117	127	dd	dd	VERB
eurjchem-125	117	128	,	,	PUNCT
eurjchem-125	117	129	j=1.22	j=1.22	PROPN
eurjchem-125	117	130	hz	hz	PROPN
eurjchem-125	117	131	,	,	PUNCT
eurjchem-125	117	132	j=5.14	j=5.14	PROPN
eurjchem-125	117	133	hz	hz	NOUN
eurjchem-125	117	134	)	)	PUNCT
eurjchem-125	117	135	,	,	PUNCT
eurjchem-125	117	136	11.29	11.29	NUM
eurjchem-125	117	137	(	(	PUNCT
eurjchem-125	117	138	1h	1h	NUM
eurjchem-125	117	139	,	,	PUNCT
eurjchem-125	117	140	nh	nh	PROPN
eurjchem-125	117	141	,	,	PUNCT
eurjchem-125	117	142	bs	bs	NOUN
eurjchem-125	117	143	)	)	PUNCT
eurjchem-125	117	144	.	.	PUNCT
eurjchem-125	118	1	13c	13c	NOUN
eurjchem-125	118	2	nmr	nmr	NOUN
eurjchem-125	118	3	(	(	PUNCT
eurjchem-125	118	4	dmso‐d6	dmso‐d6	NOUN
eurjchem-125	118	5	):	):	PUNCT
eurjchem-125	118	6	13.7	13.7	NUM
eurjchem-125	118	7	(	(	PUNCT
eurjchem-125	118	8	ch3	ch3	PROPN
eurjchem-125	118	9	)	)	PUNCT
eurjchem-125	118	10	,	,	PUNCT
eurjchem-125	118	11	22.0	22.0	NUM
eurjchem-125	118	12	(	(	PUNCT
eurjchem-125	118	13	ch2	ch2	PROPN
eurjchem-125	118	14	,	,	PUNCT
eurjchem-125	118	15	piperidine	piperidine	NOUN
eurjchem-125	118	16	)	)	PUNCT
eurjchem-125	118	17	,	,	PUNCT
eurjchem-125	118	18	22.1	22.1	NUM
eurjchem-125	118	19	(	(	PUNCT
eurjchem-125	118	20	ch2	ch2	PROPN
eurjchem-125	118	21	,	,	PUNCT
eurjchem-125	118	22	piperidine	piperidine	NOUN
eurjchem-125	118	23	)	)	PUNCT
eurjchem-125	118	24	,	,	PUNCT
eurjchem-125	118	25	49.6	49.6	NUM
eurjchem-125	118	26	(	(	PUNCT
eurjchem-125	118	27	nch2	nch2	NOUN
eurjchem-125	118	28	,	,	PUNCT
eurjchem-125	118	29	piperidine	piperidine	NOUN
eurjchem-125	118	30	)	)	PUNCT
eurjchem-125	118	31	,	,	PUNCT
eurjchem-125	118	32	51.5	51.5	NUM
eurjchem-125	118	33	(	(	PUNCT
eurjchem-125	118	34	nch2	nch2	NOUN
eurjchem-125	118	35	,	,	PUNCT
eurjchem-125	118	36	piperidine	piperidine	NOUN
eurjchem-125	118	37	)	)	PUNCT
eurjchem-125	118	38	,	,	PUNCT
eurjchem-125	118	39	55.9	55.9	NUM
eurjchem-125	118	40	(	(	PUNCT
eurjchem-125	118	41	nch	nch	NOUN
eurjchem-125	118	42	,	,	PUNCT
eurjchem-125	118	43	oxazolidinone	oxazolidinone	NUM
eurjchem-125	118	44	)	)	PUNCT
eurjchem-125	118	45	,	,	PUNCT
eurjchem-125	118	46	61.6	61.6	NUM
eurjchem-125	118	47	(	(	PUNCT
eurjchem-125	118	48	nch2n	nch2n	PROPN
eurjchem-125	118	49	)	)	PUNCT
eurjchem-125	118	50	,	,	PUNCT
eurjchem-125	118	51	77.0	77.0	NUM
eurjchem-125	118	52	(	(	PUNCT
eurjchem-125	118	53	och	och	ADJ
eurjchem-125	118	54	,	,	PUNCT
eurjchem-125	118	55	oxazolidinone	oxazolidinone	NUM
eurjchem-125	118	56	)	)	PUNCT
eurjchem-125	118	57	,	,	PUNCT
eurjchem-125	118	58	126.2	126.2	NUM
eurjchem-125	118	59	,	,	PUNCT
eurjchem-125	118	60	126.6	126.6	NUM
eurjchem-125	118	61	,	,	PUNCT
eurjchem-125	118	62	127.0	127.0	NUM
eurjchem-125	118	63	(	(	PUNCT
eurjchem-125	118	64	ch	ch	NOUN
eurjchem-125	118	65	,	,	PUNCT
eurjchem-125	118	66	thiophene	thiophene	NOUN
eurjchem-125	118	67	)	)	PUNCT
eurjchem-125	118	68	,	,	PUNCT
eurjchem-125	118	69	135.7	135.7	NUM
eurjchem-125	118	70	(	(	PUNCT
eurjchem-125	118	71	c	c	NOUN
eurjchem-125	118	72	,	,	PUNCT
eurjchem-125	118	73	thiophene	thiophene	NOUN
eurjchem-125	118	74	)	)	PUNCT
eurjchem-125	118	75	,	,	PUNCT
eurjchem-125	118	76	157.4	157.4	NUM
eurjchem-125	118	77	(	(	PUNCT
eurjchem-125	118	78	c	c	NOUN
eurjchem-125	118	79	=	=	NOUN
eurjchem-125	118	80	o	o	NOUN
eurjchem-125	118	81	)	)	PUNCT
eurjchem-125	118	82	.	.	PUNCT
eurjchem-125	119	1	anal	anal	PROPN
eurjchem-125	119	2	.	.	PUNCT
eurjchem-125	119	3	calcd	calcd	NOUN
eurjchem-125	119	4	.	.	PUNCT
eurjchem-125	120	1	for	for	ADP
eurjchem-125	120	2	c14h21cln2o2s	c14h21cln2o2s	NOUN
eurjchem-125	120	3	:	:	PUNCT
eurjchem-125	120	4	c	c	X
eurjchem-125	120	5	,	,	PUNCT
eurjchem-125	120	6	53.07	53.07	NUM
eurjchem-125	120	7	;	;	PUNCT
eurjchem-125	120	8	h	h	X
eurjchem-125	120	9	,	,	PUNCT
eurjchem-125	120	10	6.68	6.68	NUM
eurjchem-125	120	11	;	;	PUNCT
eurjchem-125	120	12	cl	cl	NOUN
eurjchem-125	120	13	,	,	PUNCT
eurjchem-125	120	14	11.19	11.19	NUM
eurjchem-125	120	15	;	;	PUNCT
eurjchem-125	120	16	n	n	CCONJ
eurjchem-125	120	17	,	,	PUNCT
eurjchem-125	120	18	8.84	8.84	NUM
eurjchem-125	120	19	;	;	PUNCT
eurjchem-125	120	20	s	s	X
eurjchem-125	120	21	,	,	PUNCT
eurjchem-125	120	22	10.12	10.12	NUM
eurjchem-125	120	23	;	;	PUNCT
eurjchem-125	120	24	found	find	VERB
eurjchem-125	120	25	:	:	PUNCT
eurjchem-125	120	26	c	c	X
eurjchem-125	120	27	,	,	PUNCT
eurjchem-125	120	28	53.01	53.01	NUM
eurjchem-125	120	29	;	;	PUNCT
eurjchem-125	120	30	h	h	NOUN
eurjchem-125	120	31	,	,	PUNCT
eurjchem-125	120	32	6.74	6.74	NUM
eurjchem-125	120	33	;	;	PUNCT
eurjchem-125	120	34	cl	cl	NOUN
eurjchem-125	120	35	,	,	PUNCT
eurjchem-125	120	36	11.13	11.13	NUM
eurjchem-125	120	37	;	;	PUNCT
eurjchem-125	120	38	n	n	CCONJ
eurjchem-125	120	39	,	,	PUNCT
eurjchem-125	120	40	8.77	8.77	NUM
eurjchem-125	120	41	;	;	PUNCT
eurjchem-125	120	42	s	s	NOUN
eurjchem-125	120	43	,	,	PUNCT
eurjchem-125	120	44	10.05	10.05	NUM
eurjchem-125	120	45	.	.	PUNCT
eurjchem-125	120	46	anti‐3‐{[4‐(4‐chlorophenyl)piperazin‐1‐yl]methyl}‐4‐methyl‐	anti‐3‐{[4‐(4‐chlorophenyl)piperazin‐1‐yl]methyl}‐4‐methyl‐	PROPN
eurjchem-125	120	47	5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NUM
eurjchem-125	120	48	,	,	PUNCT
eurjchem-125	120	49	5c	5c	NUM
eurjchem-125	120	50	:	:	PUNCT
eurjchem-125	120	51	yield	yield	VERB
eurjchem-125	120	52	67	67	NUM
eurjchem-125	120	53	%	%	NOUN
eurjchem-125	120	54	.	.	PUNCT
eurjchem-125	121	1	m.p	m.p	PROPN
eurjchem-125	121	2	.	.	PROPN
eurjchem-125	121	3	:	:	PUNCT
eurjchem-125	122	1	130‐131	130‐131	NUM
eurjchem-125	122	2	°	°	SYM
eurjchem-125	122	3	c	c	NOUN
eurjchem-125	122	4	,	,	PUNCT
eurjchem-125	122	5	re‐crystallization	re‐crystallization	NOUN
eurjchem-125	122	6	with	with	ADP
eurjchem-125	122	7	ethanol	ethanol	NOUN
eurjchem-125	122	8	.	.	PUNCT
eurjchem-125	123	1	rf	rf	VERB
eurjchem-125	123	2	=	=	NOUN
eurjchem-125	123	3	0.54	0.54	NUM
eurjchem-125	123	4	,	,	PUNCT
eurjchem-125	123	5	mobile	mobile	ADJ
eurjchem-125	123	6	phase	phase	NOUN
eurjchem-125	123	7	:	:	PUNCT
eurjchem-125	123	8	benzene	benzene	NOUN
eurjchem-125	123	9	:	:	PUNCT
eurjchem-125	123	10	diethyl	diethyl	NOUN
eurjchem-125	123	11	ether	ether	NOUN
eurjchem-125	123	12	(	(	PUNCT
eurjchem-125	123	13	4:1	4:1	NUM
eurjchem-125	123	14	)	)	PUNCT
eurjchem-125	123	15	,	,	PUNCT
eurjchem-125	123	16	silica	silica	NOUN
eurjchem-125	123	17	gel	gel	NOUN
eurjchem-125	123	18	f254	f254	PROPN
eurjchem-125	123	19	.	.	PROPN
eurjchem-125	124	1	1h	1h	NUM
eurjchem-125	124	2	nmr	nmr	NOUN
eurjchem-125	124	3	(	(	PUNCT
eurjchem-125	124	4	cdcl3	cdcl3	NOUN
eurjchem-125	124	5	):	):	PUNCT
eurjchem-125	124	6	1.39	1.39	NUM
eurjchem-125	124	7	(	(	PUNCT
eurjchem-125	124	8	d	d	PROPN
eurjchem-125	124	9	,	,	PUNCT
eurjchem-125	124	10	3h	3h	NUM
eurjchem-125	124	11	,	,	PUNCT
eurjchem-125	124	12	ch3	ch3	PROPN
eurjchem-125	124	13	,	,	PUNCT
eurjchem-125	124	14	j=6.2	j=6.2	NOUN
eurjchem-125	124	15	hz	hz	NOUN
eurjchem-125	124	16	)	)	PUNCT
eurjchem-125	124	17	;	;	PUNCT
eurjchem-125	124	18	2.72	2.72	NUM
eurjchem-125	124	19	(	(	PUNCT
eurjchem-125	124	20	m	m	PROPN
eurjchem-125	124	21	,	,	PUNCT
eurjchem-125	124	22	4h	4h	NUM
eurjchem-125	124	23	,	,	PUNCT
eurjchem-125	124	24	2	2	NUM
eurjchem-125	124	25	nch2	nch2	NOUN
eurjchem-125	124	26	,	,	PUNCT
eurjchem-125	124	27	piperazine	piperazine	NOUN
eurjchem-125	124	28	)	)	PUNCT
eurjchem-125	124	29	;	;	PUNCT
eurjchem-125	124	30	3.15	3.15	NUM
eurjchem-125	124	31	(	(	PUNCT
eurjchem-125	124	32	m	m	PROPN
eurjchem-125	124	33	,	,	PUNCT
eurjchem-125	124	34	4h	4h	NUM
eurjchem-125	124	35	,	,	PUNCT
eurjchem-125	124	36	2	2	NUM
eurjchem-125	124	37	nch2	nch2	NOUN
eurjchem-125	124	38	,	,	PUNCT
eurjchem-125	124	39	piperazine	piperazine	NOUN
eurjchem-125	124	40	)	)	PUNCT
eurjchem-125	124	41	;	;	PUNCT
eurjchem-125	124	42	3.91	3.91	NUM
eurjchem-125	124	43	(	(	PUNCT
eurjchem-125	124	44	d	d	PROPN
eurjchem-125	124	45	,	,	PUNCT
eurjchem-125	124	46	1h	1h	NUM
eurjchem-125	124	47	,	,	PUNCT
eurjchem-125	124	48	n(hch)n	n(hch)n	NOUN
eurjchem-125	124	49	,	,	PUNCT
eurjchem-125	124	50	j=12.6	j=12.6	PROPN
eurjchem-125	124	51	hz	hz	NOUN
eurjchem-125	124	52	)	)	PUNCT
eurjchem-125	124	53	;	;	PUNCT
eurjchem-125	124	54	4.03	4.03	NUM
eurjchem-125	124	55	(	(	PUNCT
eurjchem-125	124	56	m	m	PROPN
eurjchem-125	124	57	,	,	PUNCT
eurjchem-125	124	58	1h	1h	NUM
eurjchem-125	124	59	,	,	PUNCT
eurjchem-125	124	60	nch	nch	NOUN
eurjchem-125	124	61	,	,	PUNCT
eurjchem-125	124	62	qd	qd	PROPN
eurjchem-125	124	63	,	,	PUNCT
eurjchem-125	124	64	j=6.2	j=6.2	NOUN
eurjchem-125	124	65	hz	hz	NOUN
eurjchem-125	124	66	,	,	PUNCT
eurjchem-125	124	67	j=7.2	j=7.2	NOUN
eurjchem-125	124	68	hz	hz	VERB
eurjchem-125	124	69	,	,	PUNCT
eurjchem-125	124	70	oxazolidinone	oxazolidinone	NUM
eurjchem-125	124	71	)	)	PUNCT
eurjchem-125	124	72	;	;	PUNCT
eurjchem-125	124	73	4.24	4.24	NUM
eurjchem-125	124	74	(	(	PUNCT
eurjchem-125	124	75	d	d	PROPN
eurjchem-125	124	76	,	,	PUNCT
eurjchem-125	124	77	1h	1h	NUM
eurjchem-125	124	78	,	,	PUNCT
eurjchem-125	124	79	n(hch)n	n(hch)n	NOUN
eurjchem-125	124	80	,	,	PUNCT
eurjchem-125	124	81	j=12.6	j=12.6	PROPN
eurjchem-125	124	82	hz	hz	NOUN
eurjchem-125	124	83	)	)	PUNCT
eurjchem-125	124	84	;	;	PUNCT
eurjchem-125	124	85	5.20	5.20	NUM
eurjchem-125	124	86	(	(	PUNCT
eurjchem-125	124	87	d	d	PROPN
eurjchem-125	124	88	,	,	PUNCT
eurjchem-125	124	89	1h	1h	NUM
eurjchem-125	124	90	,	,	PUNCT
eurjchem-125	124	91	cho	cho	NOUN
eurjchem-125	124	92	,	,	PUNCT
eurjchem-125	124	93	j=7.2	j=7.2	NOUN
eurjchem-125	124	94	hz	hz	VERB
eurjchem-125	124	95	,	,	PUNCT
eurjchem-125	124	96	oxazolidinone	oxazolidinone	NUM
eurjchem-125	124	97	)	)	PUNCT
eurjchem-125	124	98	;	;	PUNCT
eurjchem-125	124	99	6.83	6.83	NUM
eurjchem-125	124	100	(	(	PUNCT
eurjchem-125	124	101	m	m	PROPN
eurjchem-125	124	102	,	,	PUNCT
eurjchem-125	124	103	2h	2h	NUM
eurjchem-125	124	104	,	,	PUNCT
eurjchem-125	124	105	ch‐ph	ch‐ph	NOUN
eurjchem-125	124	106	,	,	PUNCT
eurjchem-125	124	107	aa’bb	aa’bb	PROPN
eurjchem-125	124	108	’	'	PUNCT
eurjchem-125	124	109	system	system	NOUN
eurjchem-125	124	110	)	)	PUNCT
eurjchem-125	124	111	;	;	PUNCT
eurjchem-125	124	112	7.02	7.02	NUM
eurjchem-125	124	113	(	(	PUNCT
eurjchem-125	124	114	dd	dd	PROPN
eurjchem-125	124	115	,	,	PUNCT
eurjchem-125	124	116	1h	1h	NUM
eurjchem-125	124	117	,	,	PUNCT
eurjchem-125	124	118	sch‐ch‐ch	sch‐ch‐ch	PROPN
eurjchem-125	124	119	,	,	PUNCT
eurjchem-125	124	120	j=5.1	j=5.1	PROPN
eurjchem-125	124	121	hz	hz	NOUN
eurjchem-125	124	122	,	,	PUNCT
eurjchem-125	124	123	j=3.7	j=3.7	NOUN
eurjchem-125	124	124	hz	hz	NOUN
eurjchem-125	124	125	,	,	PUNCT
eurjchem-125	124	126	thiophene	thiophene	NOUN
eurjchem-125	124	127	)	)	PUNCT
eurjchem-125	124	128	;	;	PUNCT
eurjchem-125	124	129	7.14	7.14	NUM
eurjchem-125	124	130	(	(	PUNCT
eurjchem-125	124	131	1h	1h	NUM
eurjchem-125	124	132	,	,	PUNCT
eurjchem-125	124	133	dd	dd	NOUN
eurjchem-125	124	134	,	,	PUNCT
eurjchem-125	124	135	j=1.2	j=1.2	NOUN
eurjchem-125	124	136	hz	hz	NOUN
eurjchem-125	124	137	,	,	PUNCT
eurjchem-125	124	138	j=3.7	j=3.7	NOUN
eurjchem-125	124	139	hz	hz	VERB
eurjchem-125	124	140	,	,	PUNCT
eurjchem-125	124	141	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	124	142	,	,	PUNCT
eurjchem-125	124	143	thiophene	thiophene	NOUN
eurjchem-125	124	144	)	)	PUNCT
eurjchem-125	124	145	,	,	PUNCT
eurjchem-125	124	146	7.20	7.20	NUM
eurjchem-125	124	147	(	(	PUNCT
eurjchem-125	124	148	m	m	PROPN
eurjchem-125	124	149	,	,	PUNCT
eurjchem-125	124	150	2h	2h	NUM
eurjchem-125	124	151	,	,	PUNCT
eurjchem-125	124	152	ch‐ph	ch‐ph	NOUN
eurjchem-125	124	153	,	,	PUNCT
eurjchem-125	124	154	aa’bb	aa’bb	PROPN
eurjchem-125	124	155	’	'	PUNCT
eurjchem-125	124	156	system	system	NOUN
eurjchem-125	124	157	)	)	PUNCT
eurjchem-125	124	158	;	;	PUNCT
eurjchem-125	124	159	7.37	7.37	NUM
eurjchem-125	124	160	(	(	PUNCT
eurjchem-125	124	161	dd	dd	PROPN
eurjchem-125	124	162	,	,	PUNCT
eurjchem-125	124	163	1h	1h	NUM
eurjchem-125	124	164	,	,	PUNCT
eurjchem-125	124	165	sch	sch	INTJ
eurjchem-125	124	166	,	,	PUNCT
eurjchem-125	124	167	j=1.2	j=1.2	NOUN
eurjchem-125	124	168	hz	hz	NOUN
eurjchem-125	124	169	,	,	PUNCT
eurjchem-125	124	170	j=5.1	j=5.1	PROPN
eurjchem-125	124	171	hz	hz	NOUN
eurjchem-125	124	172	,	,	PUNCT
eurjchem-125	124	173	thiophene	thiophene	NOUN
eurjchem-125	124	174	)	)	PUNCT
eurjchem-125	124	175	.	.	PUNCT
eurjchem-125	125	1	13c	13c	NOUN
eurjchem-125	125	2	nmr	nmr	NOUN
eurjchem-125	125	3	(	(	PUNCT
eurjchem-125	125	4	cdcl3	cdcl3	NOUN
eurjchem-125	125	5	):	):	PUNCT
eurjchem-125	125	6	17.3	17.3	NUM
eurjchem-125	125	7	(	(	PUNCT
eurjchem-125	125	8	ch3	ch3	PROPN
eurjchem-125	125	9	)	)	PUNCT
eurjchem-125	125	10	,	,	PUNCT
eurjchem-125	125	11	48.9	48.9	NUM
eurjchem-125	125	12	,	,	PUNCT
eurjchem-125	125	13	50.3	50.3	NUM
eurjchem-125	125	14	,	,	PUNCT
eurjchem-125	125	15	58.7	58.7	NUM
eurjchem-125	125	16	,	,	PUNCT
eurjchem-125	125	17	63.8	63.8	NUM
eurjchem-125	125	18	,	,	PUNCT
eurjchem-125	125	19	78.5	78.5	NUM
eurjchem-125	125	20	,	,	PUNCT
eurjchem-125	125	21	117.3	117.3	NUM
eurjchem-125	125	22	(	(	PUNCT
eurjchem-125	125	23	ch	ch	NOUN
eurjchem-125	125	24	,	,	PUNCT
eurjchem-125	125	25	ph	ph	NOUN
eurjchem-125	125	26	)	)	PUNCT
eurjchem-125	125	27	,	,	PUNCT
eurjchem-125	125	28	124.6	124.6	NUM
eurjchem-125	125	29	(	(	PUNCT
eurjchem-125	125	30	c	c	NOUN
eurjchem-125	125	31	,	,	PUNCT
eurjchem-125	125	32	ph	ph	NOUN
eurjchem-125	125	33	)	)	PUNCT
eurjchem-125	125	34	,	,	PUNCT
eurjchem-125	125	35	126.8	126.8	NUM
eurjchem-125	125	36	(	(	PUNCT
eurjchem-125	125	37	ch	ch	NOUN
eurjchem-125	125	38	,	,	PUNCT
eurjchem-125	125	39	thiophene	thiophene	NOUN
eurjchem-125	125	40	)	)	PUNCT
eurjchem-125	125	41	,	,	PUNCT
eurjchem-125	125	42	126.8	126.8	NUM
eurjchem-125	125	43	(	(	PUNCT
eurjchem-125	125	44	ch	ch	NOUN
eurjchem-125	125	45	,	,	PUNCT
eurjchem-125	125	46	thiophene	thiophene	NOUN
eurjchem-125	125	47	)	)	PUNCT
eurjchem-125	125	48	,	,	PUNCT
eurjchem-125	125	49	127.0	127.0	NUM
eurjchem-125	125	50	(	(	PUNCT
eurjchem-125	125	51	ch	ch	NOUN
eurjchem-125	125	52	,	,	PUNCT
eurjchem-125	125	53	thiophene	thiophene	NOUN
eurjchem-125	125	54	)	)	PUNCT
eurjchem-125	125	55	,	,	PUNCT
eurjchem-125	125	56	128.9	128.9	NUM
eurjchem-125	125	57	(	(	PUNCT
eurjchem-125	125	58	ch	ch	NOUN
eurjchem-125	125	59	,	,	PUNCT
eurjchem-125	125	60	ph	ph	NOUN
eurjchem-125	125	61	)	)	PUNCT
eurjchem-125	125	62	,	,	PUNCT
eurjchem-125	125	63	139.9	139.9	NUM
eurjchem-125	125	64	(	(	PUNCT
eurjchem-125	125	65	c	c	NOUN
eurjchem-125	125	66	,	,	PUNCT
eurjchem-125	125	67	thiophene	thiophene	NOUN
eurjchem-125	125	68	)	)	PUNCT
eurjchem-125	125	69	,	,	PUNCT
eurjchem-125	125	70	149.7	149.7	NUM
eurjchem-125	125	71	(	(	PUNCT
eurjchem-125	125	72	c	c	NOUN
eurjchem-125	125	73	,	,	PUNCT
eurjchem-125	125	74	ph	ph	NOUN
eurjchem-125	125	75	)	)	PUNCT
eurjchem-125	125	76	,	,	PUNCT
eurjchem-125	125	77	157.1	157.1	NUM
eurjchem-125	125	78	(	(	PUNCT
eurjchem-125	125	79	c	c	NOUN
eurjchem-125	125	80	=	=	NOUN
eurjchem-125	125	81	o	o	NOUN
eurjchem-125	125	82	)	)	PUNCT
eurjchem-125	125	83	.	.	PUNCT
eurjchem-125	126	1	anal	anal	PROPN
eurjchem-125	126	2	.	.	PUNCT
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eurjchem-125	126	4	.	.	PUNCT
eurjchem-125	127	1	for	for	ADP
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eurjchem-125	127	3	:	:	PUNCT
eurjchem-125	127	4	c	c	X
eurjchem-125	127	5	,	,	PUNCT
eurjchem-125	127	6	62.95	62.95	NUM
eurjchem-125	127	7	;	;	PUNCT
eurjchem-125	127	8	h	h	X
eurjchem-125	127	9	,	,	PUNCT
eurjchem-125	127	10	6.16	6.16	NUM
eurjchem-125	127	11	;	;	PUNCT
eurjchem-125	127	12	n	n	CCONJ
eurjchem-125	127	13	,	,	PUNCT
eurjchem-125	127	14	12.23	12.23	NUM
eurjchem-125	127	15	;	;	PUNCT
eurjchem-125	127	16	s	s	X
eurjchem-125	127	17	,	,	PUNCT
eurjchem-125	127	18	9.34	9.34	NUM
eurjchem-125	127	19	;	;	PUNCT
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eurjchem-125	127	21	:	:	PUNCT
eurjchem-125	127	22	c	c	X
eurjchem-125	127	23	,	,	PUNCT
eurjchem-125	127	24	62.87	62.87	NUM
eurjchem-125	127	25	;	;	PUNCT
eurjchem-125	127	26	h	h	X
eurjchem-125	127	27	,	,	PUNCT
eurjchem-125	127	28	6.12	6.12	NUM
eurjchem-125	127	29	;	;	PUNCT
eurjchem-125	127	30	n	n	CCONJ
eurjchem-125	127	31	,	,	PUNCT
eurjchem-125	127	32	12.28	12.28	NUM
eurjchem-125	127	33	;	;	PUNCT
eurjchem-125	127	34	s	s	X
eurjchem-125	127	35	,	,	PUNCT
eurjchem-125	127	36	9.40	9.40	NUM
eurjchem-125	127	37	.	.	PUNCT
eurjchem-125	128	1	syn‐3‐{[4‐(4‐chlorophenyl)piperazin‐1‐yl]methyl}‐4‐methyl‐	syn‐3‐{[4‐(4‐chlorophenyl)piperazin‐1‐yl]methyl}‐4‐methyl‐	PROPN
eurjchem-125	128	2	5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NUM
eurjchem-125	128	3	,	,	PUNCT
eurjchem-125	128	4	7c	7c	NUM
eurjchem-125	128	5	:	:	PUNCT
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eurjchem-125	128	7	64	64	NUM
eurjchem-125	128	8	%	%	NOUN
eurjchem-125	128	9	.	.	PUNCT
eurjchem-125	129	1	m.p	m.p	PROPN
eurjchem-125	129	2	.	.	PROPN
eurjchem-125	129	3	:	:	PUNCT
eurjchem-125	130	1	118‐120	118‐120	NUM
eurjchem-125	131	1	°	°	PROPN
eurjchem-125	131	2	c	c	NOUN
eurjchem-125	131	3	,	,	PUNCT
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eurjchem-125	131	5	with	with	ADP
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eurjchem-125	131	7	.	.	PUNCT
eurjchem-125	132	1	rf	rf	VERB
eurjchem-125	132	2	=	=	NOUN
eurjchem-125	132	3	0.48	0.48	NUM
eurjchem-125	132	4	,	,	PUNCT
eurjchem-125	132	5	mobile	mobile	ADJ
eurjchem-125	132	6	phase	phase	NOUN
eurjchem-125	132	7	:	:	PUNCT
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eurjchem-125	132	9	:	:	PUNCT
eurjchem-125	132	10	diethyl	diethyl	NOUN
eurjchem-125	132	11	ether	ether	NOUN
eurjchem-125	132	12	(	(	PUNCT
eurjchem-125	132	13	4:1	4:1	NUM
eurjchem-125	132	14	)	)	PUNCT
eurjchem-125	132	15	,	,	PUNCT
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eurjchem-125	132	17	gel	gel	NOUN
eurjchem-125	132	18	f254	f254	PROPN
eurjchem-125	132	19	.	.	PROPN
eurjchem-125	133	1	1h	1h	NUM
eurjchem-125	133	2	nmr	nmr	NOUN
eurjchem-125	133	3	(	(	PUNCT
eurjchem-125	133	4	cdcl3	cdcl3	NOUN
eurjchem-125	133	5	):	):	PUNCT
eurjchem-125	133	6	1.02	1.02	NUM
eurjchem-125	133	7	(	(	PUNCT
eurjchem-125	133	8	d	d	PROPN
eurjchem-125	133	9	,	,	PUNCT
eurjchem-125	133	10	3h	3h	NUM
eurjchem-125	133	11	,	,	PUNCT
eurjchem-125	133	12	ch3	ch3	PROPN
eurjchem-125	133	13	,	,	PUNCT
eurjchem-125	133	14	j=6.60	j=6.60	PROPN
eurjchem-125	133	15	hz	hz	NOUN
eurjchem-125	133	16	)	)	PUNCT
eurjchem-125	133	17	;	;	PUNCT
eurjchem-125	133	18	2.75	2.75	NUM
eurjchem-125	133	19	(	(	PUNCT
eurjchem-125	133	20	m	m	PROPN
eurjchem-125	133	21	,	,	PUNCT
eurjchem-125	133	22	4h	4h	NUM
eurjchem-125	133	23	,	,	PUNCT
eurjchem-125	133	24	2	2	NUM
eurjchem-125	133	25	nch2	nch2	NOUN
eurjchem-125	133	26	,	,	PUNCT
eurjchem-125	133	27	piperazin	piperazin	PROPN
eurjchem-125	133	28	)	)	PUNCT
eurjchem-125	133	29	;	;	PUNCT
eurjchem-125	133	30	3.16	3.16	NUM
eurjchem-125	133	31	(	(	PUNCT
eurjchem-125	133	32	m	m	PROPN
eurjchem-125	133	33	,	,	PUNCT
eurjchem-125	133	34	4h	4h	NUM
eurjchem-125	133	35	,	,	PUNCT
eurjchem-125	133	36	2	2	NUM
eurjchem-125	133	37	nch2	nch2	NOUN
eurjchem-125	133	38	)	)	PUNCT
eurjchem-125	133	39	;	;	PUNCT
eurjchem-125	133	40	3.88	3.88	NUM
eurjchem-125	133	41	(	(	PUNCT
eurjchem-125	133	42	1h	1h	NUM
eurjchem-125	133	43	,	,	PUNCT
eurjchem-125	133	44	d	d	NOUN
eurjchem-125	133	45	,	,	PUNCT
eurjchem-125	133	46	n(hch)n	n(hch)n	NOUN
eurjchem-125	133	47	,	,	PUNCT
eurjchem-125	133	48	j=12.72	j=12.72	PROPN
eurjchem-125	133	49	hz	hz	NOUN
eurjchem-125	133	50	)	)	PUNCT
eurjchem-125	133	51	;	;	PUNCT
eurjchem-125	133	52	4.29	4.29	NUM
eurjchem-125	133	53	(	(	PUNCT
eurjchem-125	133	54	2h	2h	NUM
eurjchem-125	133	55	,	,	PUNCT
eurjchem-125	133	56	n(hch)n	n(hch)n	NOUN
eurjchem-125	133	57	,	,	PUNCT
eurjchem-125	133	58	d	d	PROPN
eurjchem-125	133	59	,	,	PUNCT
eurjchem-125	133	60	j=12.72	j=12.72	PROPN
eurjchem-125	133	61	hz	hz	VERB
eurjchem-125	133	62	,	,	PUNCT
eurjchem-125	133	63	overlapped	overlap	VERB
eurjchem-125	133	64	with	with	ADP
eurjchem-125	133	65	nch	nch	PROPN
eurjchem-125	133	66	from	from	ADP
eurjchem-125	133	67	oxazolidinone	oxazolidinone	NUM
eurjchem-125	133	68	)	)	PUNCT
eurjchem-125	133	69	;	;	PUNCT
eurjchem-125	133	70	5.83	5.83	NUM
eurjchem-125	133	71	(	(	PUNCT
eurjchem-125	133	72	1h	1h	NUM
eurjchem-125	133	73	,	,	PUNCT
eurjchem-125	133	74	d	d	PROPN
eurjchem-125	133	75	,	,	PUNCT
eurjchem-125	133	76	cho	cho	PROPN
eurjchem-125	133	77	,	,	PUNCT
eurjchem-125	133	78	j=7.83	j=7.83	PROPN
eurjchem-125	133	79	hz	hz	PROPN
eurjchem-125	133	80	,	,	PUNCT
eurjchem-125	133	81	oxazolidinone	oxazolidinone	NUM
eurjchem-125	133	82	)	)	PUNCT
eurjchem-125	133	83	;	;	PUNCT
eurjchem-125	133	84	6.84	6.84	NUM
eurjchem-125	133	85	(	(	PUNCT
eurjchem-125	133	86	m	m	PROPN
eurjchem-125	133	87	,	,	PUNCT
eurjchem-125	133	88	2h	2h	NUM
eurjchem-125	133	89	,	,	PUNCT
eurjchem-125	133	90	ch‐ph	ch‐ph	NOUN
eurjchem-125	133	91	,	,	PUNCT
eurjchem-125	133	92	aa’bb	aa’bb	PROPN
eurjchem-125	133	93	’	'	PUNCT
eurjchem-125	133	94	system	system	NOUN
eurjchem-125	133	95	)	)	PUNCT
eurjchem-125	133	96	;	;	PUNCT
eurjchem-125	133	97	7.01‐7.06	7.01‐7.06	X
eurjchem-125	133	98	(	(	PUNCT
eurjchem-125	133	99	2h	2h	NUM
eurjchem-125	133	100	,	,	PUNCT
eurjchem-125	133	101	m	m	PROPN
eurjchem-125	133	102	,	,	PUNCT
eurjchem-125	133	103	sch‐ch‐	sch‐ch‐	NOUN
eurjchem-125	133	104	ch	ch	NOUN
eurjchem-125	133	105	and	and	CCONJ
eurjchem-125	133	106	sch‐ch‐ch	sch‐ch‐ch	NOUN
eurjchem-125	133	107	,	,	PUNCT
eurjchem-125	133	108	thiophene	thiophene	NOUN
eurjchem-125	133	109	)	)	PUNCT
eurjchem-125	133	110	;	;	PUNCT
eurjchem-125	133	111	7.17‐7.24	7.17‐7.24	NUM
eurjchem-125	133	112	(	(	PUNCT
eurjchem-125	133	113	m	m	PROPN
eurjchem-125	133	114	,	,	PUNCT
eurjchem-125	133	115	2h	2h	NUM
eurjchem-125	133	116	,	,	PUNCT
eurjchem-125	133	117	ch‐ph	ch‐ph	NOUN
eurjchem-125	133	118	,	,	PUNCT
eurjchem-125	133	119	aa’bb	aa’bb	PROPN
eurjchem-125	133	120	’	'	PUNCT
eurjchem-125	133	121	system	system	NOUN
eurjchem-125	133	122	)	)	PUNCT
eurjchem-125	133	123	;	;	PUNCT
eurjchem-125	133	124	7.33	7.33	NUM
eurjchem-125	133	125	(	(	PUNCT
eurjchem-125	133	126	1h	1h	NUM
eurjchem-125	133	127	,	,	PUNCT
eurjchem-125	133	128	dd	dd	NOUN
eurjchem-125	133	129	,	,	PUNCT
eurjchem-125	133	130	sch	sch	INTJ
eurjchem-125	133	131	,	,	PUNCT
eurjchem-125	133	132	j=2.20	j=2.20	PROPN
eurjchem-125	133	133	hz	hz	VERB
eurjchem-125	133	134	,	,	PUNCT
eurjchem-125	133	135	j=4.16	j=4.16	PROPN
eurjchem-125	133	136	hz	hz	NOUN
eurjchem-125	133	137	,	,	PUNCT
eurjchem-125	133	138	thiophene	thiophene	NOUN
eurjchem-125	133	139	)	)	PUNCT
eurjchem-125	133	140	.	.	PUNCT
eurjchem-125	134	1	anal	anal	PROPN
eurjchem-125	134	2	.	.	PUNCT
eurjchem-125	134	3	calcd	calcd	NOUN
eurjchem-125	134	4	.	.	PUNCT
eurjchem-125	135	1	for	for	ADP
eurjchem-125	135	2	c19h22cln3o2s	c19h22cln3o2s	NOUN
eurjchem-125	135	3	:	:	PUNCT
eurjchem-125	135	4	c	c	X
eurjchem-125	135	5	,	,	PUNCT
eurjchem-125	135	6	62.95	62.95	NUM
eurjchem-125	135	7	;	;	PUNCT
eurjchem-125	135	8	h	h	X
eurjchem-125	135	9	,	,	PUNCT
eurjchem-125	135	10	6.16	6.16	NUM
eurjchem-125	135	11	;	;	PUNCT
eurjchem-125	135	12	n	n	CCONJ
eurjchem-125	135	13	,	,	PUNCT
eurjchem-125	135	14	12.23	12.23	NUM
eurjchem-125	135	15	;	;	PUNCT
eurjchem-125	135	16	s	s	X
eurjchem-125	135	17	,	,	PUNCT
eurjchem-125	135	18	9.34	9.34	NUM
eurjchem-125	135	19	;	;	PUNCT
eurjchem-125	135	20	found	find	VERB
eurjchem-125	135	21	:	:	PUNCT
eurjchem-125	135	22	c	c	X
eurjchem-125	135	23	,	,	PUNCT
eurjchem-125	135	24	62.89	62.89	NUM
eurjchem-125	135	25	;	;	PUNCT
eurjchem-125	135	26	h	h	NOUN
eurjchem-125	135	27	,	,	PUNCT
eurjchem-125	135	28	6.20	6.20	NUM
eurjchem-125	135	29	;	;	PUNCT
eurjchem-125	135	30	n	n	CCONJ
eurjchem-125	135	31	,	,	PUNCT
eurjchem-125	135	32	12.16	12.16	NUM
eurjchem-125	135	33	;	;	PUNCT
eurjchem-125	135	34	s	s	X
eurjchem-125	135	35	,	,	PUNCT
eurjchem-125	135	36	9.38	9.38	NUM
eurjchem-125	135	37	.	.	PUNCT
eurjchem-125	136	1	anti‐4‐methyl‐3‐[(4‐benzhydrylpiperazin‐1‐yl)methyl]‐5‐	anti‐4‐methyl‐3‐[(4‐benzhydrylpiperazin‐1‐yl)methyl]‐5‐	NOUN
eurjchem-125	136	2	thien‐2‐yl‐1,3‐oxazolidin‐2‐one	thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	136	3	,	,	PUNCT
eurjchem-125	136	4	5d	5d	NUM
eurjchem-125	136	5	:	:	PUNCT
eurjchem-125	136	6	yield	yield	VERB
eurjchem-125	136	7	70	70	NUM
eurjchem-125	136	8	%	%	NOUN
eurjchem-125	136	9	.	.	PUNCT
eurjchem-125	137	1	m.p	m.p	PROPN
eurjchem-125	137	2	.	.	PROPN
eurjchem-125	137	3	:	:	PUNCT
eurjchem-125	138	1	133‐134	133‐134	NUM
eurjchem-125	138	2	°	°	PRON
eurjchem-125	138	3	c	c	NOUN
eurjchem-125	138	4	,	,	PUNCT
eurjchem-125	138	5	recrystallization	recrystallization	NOUN
eurjchem-125	138	6	with	with	ADP
eurjchem-125	138	7	ethanol	ethanol	NOUN
eurjchem-125	138	8	.	.	PUNCT
eurjchem-125	139	1	rf	rf	VERB
eurjchem-125	139	2	=	=	NOUN
eurjchem-125	139	3	0.62	0.62	NUM
eurjchem-125	139	4	,	,	PUNCT
eurjchem-125	139	5	mobile	mobile	ADJ
eurjchem-125	139	6	phase	phase	NOUN
eurjchem-125	139	7	:	:	PUNCT
eurjchem-125	139	8	benzene	benzene	NOUN
eurjchem-125	139	9	:	:	PUNCT
eurjchem-125	139	10	diethyl	diethyl	NOUN
eurjchem-125	139	11	ether	ether	NOUN
eurjchem-125	139	12	:	:	PUNCT
eurjchem-125	139	13	ethanol	ethanol	NOUN
eurjchem-125	139	14	(	(	PUNCT
eurjchem-125	139	15	4:1:3	4:1:3	NUM
eurjchem-125	139	16	)	)	PUNCT
eurjchem-125	139	17	,	,	PUNCT
eurjchem-125	139	18	silica	silica	NOUN
eurjchem-125	139	19	gel	gel	NOUN
eurjchem-125	139	20	f254	f254	PROPN
eurjchem-125	139	21	.	.	PROPN
eurjchem-125	140	1	1h	1h	NUM
eurjchem-125	140	2	nmr	nmr	NOUN
eurjchem-125	140	3	(	(	PUNCT
eurjchem-125	140	4	cdcl3	cdcl3	NOUN
eurjchem-125	140	5	):	):	PUNCT
eurjchem-125	140	6	1.34	1.34	NUM
eurjchem-125	140	7	(	(	PUNCT
eurjchem-125	140	8	3h	3h	NUM
eurjchem-125	140	9	,	,	PUNCT
eurjchem-125	140	10	ch3	ch3	PROPN
eurjchem-125	140	11	,	,	PUNCT
eurjchem-125	140	12	d	d	PROPN
eurjchem-125	140	13	,	,	PUNCT
eurjchem-125	140	14	j=6.06	j=6.06	PROPN
eurjchem-125	140	15	hz	hz	NOUN
eurjchem-125	140	16	)	)	PUNCT
eurjchem-125	140	17	,	,	PUNCT
eurjchem-125	140	18	2.22‐2.41	2.22‐2.41	NUM
eurjchem-125	140	19	(	(	PUNCT
eurjchem-125	140	20	8h	8h	NUM
eurjchem-125	140	21	,	,	PUNCT
eurjchem-125	140	22	4ch2	4ch2	NUM
eurjchem-125	140	23	,	,	PUNCT
eurjchem-125	140	24	m	m	NOUN
eurjchem-125	140	25	,	,	PUNCT
eurjchem-125	140	26	piperazine	piperazine	NOUN
eurjchem-125	140	27	)	)	PUNCT
eurjchem-125	140	28	,	,	PUNCT
eurjchem-125	140	29	3.71	3.71	NUM
eurjchem-125	140	30	(	(	PUNCT
eurjchem-125	140	31	1h	1h	NUM
eurjchem-125	140	32	,	,	PUNCT
eurjchem-125	140	33	n(hch)n	n(hch)n	NOUN
eurjchem-125	140	34	,	,	PUNCT
eurjchem-125	140	35	d	d	PROPN
eurjchem-125	140	36	,	,	PUNCT
eurjchem-125	140	37	j=12.62	j=12.62	PROPN
eurjchem-125	140	38	hz	hz	NOUN
eurjchem-125	140	39	)	)	PUNCT
eurjchem-125	140	40	,	,	PUNCT
eurjchem-125	140	41	4.16‐4.01	4.16‐4.01	NUM
eurjchem-125	140	42	(	(	PUNCT
eurjchem-125	140	43	3h	3h	NUM
eurjchem-125	140	44	,	,	PUNCT
eurjchem-125	140	45	n(hch)n	n(hch)n	NOUN
eurjchem-125	140	46	,	,	PUNCT
eurjchem-125	140	47	overlapped	overlap	VERB
eurjchem-125	140	48	with	with	ADP
eurjchem-125	140	49	ch(ph)2	ch(ph)2	NOUN
eurjchem-125	140	50	and	and	CCONJ
eurjchem-125	140	51	n‐ch	n‐ch	NOUN
eurjchem-125	140	52	from	from	ADP
eurjchem-125	140	53	oxazolidinone	oxazolidinone	NUM
eurjchem-125	140	54	)	)	PUNCT
eurjchem-125	140	55	,	,	PUNCT
eurjchem-125	140	56	5.19	5.19	NUM
eurjchem-125	140	57	(	(	PUNCT
eurjchem-125	140	58	1h	1h	NUM
eurjchem-125	140	59	,	,	PUNCT
eurjchem-125	140	60	och	och	NUM
eurjchem-125	140	61	,	,	PUNCT
eurjchem-125	140	62	d	d	PROPN
eurjchem-125	140	63	,	,	PUNCT
eurjchem-125	140	64	j=6.65	j=6.65	PROPN
eurjchem-125	140	65	hz	hz	NOUN
eurjchem-125	140	66	)	)	PUNCT
eurjchem-125	140	67	,	,	PUNCT
eurjchem-125	140	68	7.42‐6.92	7.42‐6.92	NUM
eurjchem-125	140	69	(	(	PUNCT
eurjchem-125	140	70	13h	13h	NOUN
eurjchem-125	140	71	,	,	PUNCT
eurjchem-125	140	72	2ph	2ph	NOUN
eurjchem-125	140	73	and	and	CCONJ
eurjchem-125	140	74	ch	ch	NOUN
eurjchem-125	140	75	from	from	ADP
eurjchem-125	140	76	thiophene	thiophene	NOUN
eurjchem-125	140	77	)	)	PUNCT
eurjchem-125	140	78	.	.	PUNCT
eurjchem-125	141	1	anal	anal	PROPN
eurjchem-125	141	2	.	.	PUNCT
eurjchem-125	141	3	calcd	calcd	NOUN
eurjchem-125	141	4	.	.	PUNCT
eurjchem-125	142	1	for	for	ADP
eurjchem-125	142	2	c26h29n3o2s	c26h29n3o2s	NOUN
eurjchem-125	142	3	:	:	PUNCT
eurjchem-125	142	4	c	c	X
eurjchem-125	142	5	,	,	PUNCT
eurjchem-125	142	6	69.77	69.77	NUM
eurjchem-125	142	7	;	;	PUNCT
eurjchem-125	142	8	h	h	NOUN
eurjchem-125	142	9	,	,	PUNCT
eurjchem-125	142	10	6.53	6.53	NUM
eurjchem-125	142	11	;	;	PUNCT
eurjchem-125	142	12	n	n	CCONJ
eurjchem-125	142	13	,	,	PUNCT
eurjchem-125	142	14	9.39	9.39	NUM
eurjchem-125	142	15	;	;	PUNCT
eurjchem-125	142	16	s	s	X
eurjchem-125	142	17	,	,	PUNCT
eurjchem-125	142	18	7.16	7.16	NUM
eurjchem-125	142	19	;	;	PUNCT
eurjchem-125	142	20	found	find	VERB
eurjchem-125	142	21	:	:	PUNCT
eurjchem-125	142	22	c	c	X
eurjchem-125	142	23	,	,	PUNCT
eurjchem-125	142	24	69.70	69.70	NUM
eurjchem-125	142	25	;	;	PUNCT
eurjchem-125	142	26	h	h	NOUN
eurjchem-125	142	27	,	,	PUNCT
eurjchem-125	142	28	6.48	6.48	NUM
eurjchem-125	142	29	;	;	PUNCT
eurjchem-125	142	30	n	n	CCONJ
eurjchem-125	142	31	,	,	PUNCT
eurjchem-125	142	32	9.29	9.29	NUM
eurjchem-125	142	33	;	;	PUNCT
eurjchem-125	142	34	s	s	X
eurjchem-125	142	35	,	,	PUNCT
eurjchem-125	142	36	7.22	7.22	NUM
eurjchem-125	142	37	.	.	PUNCT
eurjchem-125	143	1	syn‐4‐methyl‐3‐[(4‐benzhydrylpiperazin‐1‐yl)methyl]‐5‐	syn‐4‐methyl‐3‐[(4‐benzhydrylpiperazin‐1‐yl)methyl]‐5‐	NOUN
eurjchem-125	143	2	thien‐2‐yl‐1,3‐oxazolidin‐2‐one	thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	143	3	,	,	PUNCT
eurjchem-125	143	4	7d	7d	NUM
eurjchem-125	143	5	:	:	PUNCT
eurjchem-125	143	6	yield	yield	NOUN
eurjchem-125	143	7	65	65	NUM
eurjchem-125	143	8	%	%	NOUN
eurjchem-125	143	9	.	.	PUNCT
eurjchem-125	144	1	m.p	m.p	PROPN
eurjchem-125	144	2	.	.	PROPN
eurjchem-125	144	3	:	:	PUNCT
eurjchem-125	144	4	163‐164	163‐164	NUM
eurjchem-125	144	5	°	°	ADP
eurjchem-125	144	6	c	c	NOUN
eurjchem-125	144	7	,	,	PUNCT
eurjchem-125	144	8	recrystallization	recrystallization	NOUN
eurjchem-125	144	9	with	with	ADP
eurjchem-125	144	10	ethanol	ethanol	NOUN
eurjchem-125	144	11	.	.	PUNCT
eurjchem-125	145	1	rf	rf	VERB
eurjchem-125	145	2	=	=	NOUN
eurjchem-125	145	3	0.41	0.41	NUM
eurjchem-125	145	4	,	,	PUNCT
eurjchem-125	145	5	mobile	mobile	ADJ
eurjchem-125	145	6	phase	phase	NOUN
eurjchem-125	145	7	:	:	PUNCT
eurjchem-125	145	8	benzene	benzene	NOUN
eurjchem-125	145	9	:	:	PUNCT
eurjchem-125	145	10	diethyl	diethyl	NOUN
eurjchem-125	145	11	ether	ether	NOUN
eurjchem-125	145	12	:	:	PUNCT
eurjchem-125	145	13	ethanol	ethanol	NOUN
eurjchem-125	145	14	(	(	PUNCT
eurjchem-125	145	15	4:1:3	4:1:3	NUM
eurjchem-125	145	16	)	)	PUNCT
eurjchem-125	145	17	,	,	PUNCT
eurjchem-125	145	18	silica	silica	NOUN
eurjchem-125	145	19	gel	gel	NOUN
eurjchem-125	145	20	f254	f254	PROPN
eurjchem-125	145	21	.	.	PROPN
eurjchem-125	146	1	1h	1h	NUM
eurjchem-125	146	2	nmr	nmr	NOUN
eurjchem-125	146	3	(	(	PUNCT
eurjchem-125	146	4	cdcl3	cdcl3	PROPN
eurjchem-125	146	5	):	):	PUNCT
eurjchem-125	146	6	0.94	0.94	NUM
eurjchem-125	146	7	(	(	PUNCT
eurjchem-125	146	8	3h	3h	NUM
eurjchem-125	146	9	,	,	PUNCT
eurjchem-125	146	10	ch3	ch3	PROPN
eurjchem-125	146	11	,	,	PUNCT
eurjchem-125	146	12	d	d	PROPN
eurjchem-125	146	13	,	,	PUNCT
eurjchem-125	146	14	j=6.46	j=6.46	PROPN
eurjchem-125	146	15	hz	hz	NOUN
eurjchem-125	146	16	)	)	PUNCT
eurjchem-125	146	17	,	,	PUNCT
eurjchem-125	146	18	2.61‐2.41	2.61‐2.41	NUM
eurjchem-125	146	19	(	(	PUNCT
eurjchem-125	146	20	8h	8h	NUM
eurjchem-125	146	21	,	,	PUNCT
eurjchem-125	146	22	4ch2	4ch2	NUM
eurjchem-125	146	23	,	,	PUNCT
eurjchem-125	146	24	m	m	NOUN
eurjchem-125	146	25	,	,	PUNCT
eurjchem-125	146	26	piperazine	piperazine	NOUN
eurjchem-125	146	27	)	)	PUNCT
eurjchem-125	146	28	,	,	PUNCT
eurjchem-125	146	29	3.79	3.79	NUM
eurjchem-125	146	30	(	(	PUNCT
eurjchem-125	146	31	1h	1h	NUM
eurjchem-125	146	32	,	,	PUNCT
eurjchem-125	146	33	n(hch)n	n(hch)n	NOUN
eurjchem-125	146	34	,	,	PUNCT
eurjchem-125	146	35	d	d	NOUN
eurjchem-125	146	36	,	,	PUNCT
eurjchem-125	146	37	j=12.62	j=12.62	PROPN
eurjchem-125	146	38	)	)	PUNCT
eurjchem-125	146	39	,	,	PUNCT
eurjchem-125	146	40	4.27‐4.16	4.27‐4.16	NUM
eurjchem-125	146	41	(	(	PUNCT
eurjchem-125	146	42	3h	3h	NUM
eurjchem-125	146	43	,	,	PUNCT
eurjchem-125	146	44	n(hch)n	n(hch)n	NOUN
eurjchem-125	146	45	,	,	PUNCT
eurjchem-125	146	46	overlapped	overlap	VERB
eurjchem-125	146	47	with	with	ADP
eurjchem-125	146	48	ch(ph)2	ch(ph)2	NOUN
eurjchem-125	146	49	and	and	CCONJ
eurjchem-125	146	50	n‐ch	n‐ch	NOUN
eurjchem-125	146	51	from	from	ADP
eurjchem-125	146	52	oxazolidinone	oxazolidinone	NUM
eurjchem-125	146	53	)	)	PUNCT
eurjchem-125	146	54	,	,	PUNCT
eurjchem-125	146	55	5.79	5.79	NUM
eurjchem-125	146	56	(	(	PUNCT
eurjchem-125	146	57	1h	1h	NUM
eurjchem-125	146	58	,	,	PUNCT
eurjchem-125	146	59	och	och	NUM
eurjchem-125	146	60	,	,	PUNCT
eurjchem-125	146	61	d	d	PROPN
eurjchem-125	146	62	,	,	PUNCT
eurjchem-125	146	63	j=7.81	j=7.81	PROPN
eurjchem-125	146	64	hz	hz	PROPN
eurjchem-125	146	65	)	)	PUNCT
eurjchem-125	146	66	,	,	PUNCT
eurjchem-125	146	67	7.42‐7.02	7.42‐7.02	NUM
eurjchem-125	146	68	(	(	PUNCT
eurjchem-125	146	69	13h	13h	NOUN
eurjchem-125	146	70	,	,	PUNCT
eurjchem-125	146	71	2ph	2ph	NOUN
eurjchem-125	146	72	and	and	CCONJ
eurjchem-125	146	73	3	3	NUM
eurjchem-125	146	74	ch	ch	NOUN
eurjchem-125	146	75	from	from	ADP
eurjchem-125	146	76	thiophene	thiophene	NOUN
eurjchem-125	146	77	)	)	PUNCT
eurjchem-125	146	78	.	.	PUNCT
eurjchem-125	147	1	13c	13c	NOUN
eurjchem-125	147	2	nmr	nmr	NOUN
eurjchem-125	147	3	,	,	PUNCT
eurjchem-125	147	4	(	(	PUNCT
eurjchem-125	147	5	cdcl3	cdcl3	NOUN
eurjchem-125	147	6	):	):	PUNCT
eurjchem-125	147	7	13.8	13.8	NUM
eurjchem-125	147	8	(	(	PUNCT
eurjchem-125	147	9	ch3	ch3	PROPN
eurjchem-125	147	10	)	)	PUNCT
eurjchem-125	147	11	,	,	PUNCT
eurjchem-125	147	12	50.7	50.7	NUM
eurjchem-125	147	13	(	(	PUNCT
eurjchem-125	147	14	n‐ch2	n‐ch2	PROPN
eurjchem-125	147	15	,	,	PUNCT
eurjchem-125	147	16	piperazine	piperazine	NOUN
eurjchem-125	147	17	)	)	PUNCT
eurjchem-125	147	18	,	,	PUNCT
eurjchem-125	147	19	51.5	51.5	NUM
eurjchem-125	147	20	(	(	PUNCT
eurjchem-125	147	21	n‐ch2	n‐ch2	PROPN
eurjchem-125	147	22	,	,	PUNCT
eurjchem-125	147	23	piperazine	piperazine	NOUN
eurjchem-125	147	24	)	)	PUNCT
eurjchem-125	147	25	,	,	PUNCT
eurjchem-125	147	26	55.1	55.1	NUM
eurjchem-125	147	27	(	(	PUNCT
eurjchem-125	147	28	nch	nch	NOUN
eurjchem-125	147	29	,	,	PUNCT
eurjchem-125	147	30	oxazolidinone	oxazolidinone	NUM
eurjchem-125	147	31	)	)	PUNCT
eurjchem-125	147	32	,	,	PUNCT
eurjchem-125	147	33	64.0	64.0	NUM
eurjchem-125	147	34	(	(	PUNCT
eurjchem-125	147	35	nch2n	nch2n	PROPN
eurjchem-125	147	36	)	)	PUNCT
eurjchem-125	147	37	,	,	PUNCT
eurjchem-125	147	38	75.7	75.7	NUM
eurjchem-125	147	39	(	(	PUNCT
eurjchem-125	147	40	ch(ph)2	ch(ph)2	PROPN
eurjchem-125	147	41	)	)	PUNCT
eurjchem-125	147	42	,	,	PUNCT
eurjchem-125	147	43	76.0	76.0	NUM
eurjchem-125	147	44	(	(	PUNCT
eurjchem-125	147	45	och	och	NOUN
eurjchem-125	147	46	)	)	PUNCT
eurjchem-125	147	47	,	,	PUNCT
eurjchem-125	147	48	125.8	125.8	NUM
eurjchem-125	147	49	,	,	PUNCT
eurjchem-125	147	50	126.1	126.1	NUM
eurjchem-125	147	51	,	,	PUNCT
eurjchem-125	147	52	126.8	126.8	NUM
eurjchem-125	147	53	(	(	PUNCT
eurjchem-125	147	54	ch	ch	NOUN
eurjchem-125	147	55	,	,	PUNCT
eurjchem-125	147	56	thiophene	thiophene	NOUN
eurjchem-125	147	57	)	)	PUNCT
eurjchem-125	147	58	,	,	PUNCT
eurjchem-125	147	59	126.9	126.9	NUM
eurjchem-125	147	60	(	(	PUNCT
eurjchem-125	147	61	para	para	PROPN
eurjchem-125	147	62	ch	ch	NOUN
eurjchem-125	147	63	from	from	ADP
eurjchem-125	147	64	ph	ph	ADJ
eurjchem-125	147	65	rings	ring	NOUN
eurjchem-125	147	66	)	)	PUNCT
eurjchem-125	147	67	,	,	PUNCT
eurjchem-125	147	68	127.8	127.8	NUM
eurjchem-125	147	69	(	(	PUNCT
eurjchem-125	147	70	ortho	ortho	PROPN
eurjchem-125	147	71	ch	ch	PROPN
eurjchem-125	147	72	from	from	ADP
eurjchem-125	147	73	ph	ph	ADJ
eurjchem-125	147	74	rings	ring	NOUN
eurjchem-125	147	75	)	)	PUNCT
eurjchem-125	147	76	,	,	PUNCT
eurjchem-125	147	77	128.4	128.4	NUM
eurjchem-125	147	78	(	(	PUNCT
eurjchem-125	147	79	meta	meta	PROPN
eurjchem-125	147	80	ch	ch	NOUN
eurjchem-125	147	81	from	from	ADP
eurjchem-125	147	82	ph	ph	ADJ
eurjchem-125	147	83	rings	ring	NOUN
eurjchem-125	147	84	)	)	PUNCT
eurjchem-125	147	85	,	,	PUNCT
eurjchem-125	147	86	137.5	137.5	NUM
eurjchem-125	147	87	(	(	PUNCT
eurjchem-125	147	88	c	c	NOUN
eurjchem-125	147	89	,	,	PUNCT
eurjchem-125	147	90	thiophene	thiophene	NOUN
eurjchem-125	147	91	)	)	PUNCT
eurjchem-125	147	92	,	,	PUNCT
eurjchem-125	147	93	142.5	142.5	NUM
eurjchem-125	147	94	(	(	PUNCT
eurjchem-125	147	95	c	c	AUX
eurjchem-125	147	96	form	form	VERB
eurjchem-125	147	97	ph	ph	NOUN
eurjchem-125	147	98	rings	ring	NOUN
eurjchem-125	147	99	)	)	PUNCT
eurjchem-125	147	100	,	,	PUNCT
eurjchem-125	147	101	157.4	157.4	NUM
eurjchem-125	147	102	(	(	PUNCT
eurjchem-125	147	103	c	c	NOUN
eurjchem-125	147	104	=	=	NOUN
eurjchem-125	147	105	o	o	NOUN
eurjchem-125	147	106	)	)	PUNCT
eurjchem-125	147	107	.	.	PUNCT
eurjchem-125	148	1	anal	anal	PROPN
eurjchem-125	148	2	.	.	PUNCT
eurjchem-125	148	3	calcd	calcd	NOUN
eurjchem-125	148	4	.	.	PUNCT
eurjchem-125	149	1	for	for	ADP
eurjchem-125	149	2	c26h29n3o2s	c26h29n3o2s	NOUN
eurjchem-125	149	3	:	:	PUNCT
eurjchem-125	149	4	c	c	X
eurjchem-125	149	5	,	,	PUNCT
eurjchem-125	149	6	69.77	69.77	NUM
eurjchem-125	149	7	;	;	PUNCT
eurjchem-125	149	8	h	h	NOUN
eurjchem-125	149	9	,	,	PUNCT
eurjchem-125	149	10	6.53	6.53	NUM
eurjchem-125	149	11	;	;	PUNCT
eurjchem-125	149	12	n	n	CCONJ
eurjchem-125	149	13	,	,	PUNCT
eurjchem-125	149	14	9.39	9.39	NUM
eurjchem-125	149	15	;	;	PUNCT
eurjchem-125	149	16	s	s	X
eurjchem-125	149	17	,	,	PUNCT
eurjchem-125	149	18	7.16	7.16	NUM
eurjchem-125	149	19	;	;	PUNCT
eurjchem-125	149	20	found	find	VERB
eurjchem-125	149	21	:	:	PUNCT
eurjchem-125	149	22	c	c	X
eurjchem-125	149	23	,	,	PUNCT
eurjchem-125	149	24	69.69	69.69	NUM
eurjchem-125	149	25	;	;	PUNCT
eurjchem-125	150	1	h	h	NOUN
eurjchem-125	150	2	,	,	PUNCT
eurjchem-125	150	3	6.60	6.60	NUM
eurjchem-125	150	4	;	;	PUNCT
eurjchem-125	150	5	n	n	CCONJ
eurjchem-125	150	6	,	,	PUNCT
eurjchem-125	150	7	9.34	9.34	NUM
eurjchem-125	150	8	;	;	PUNCT
eurjchem-125	150	9	s	s	X
eurjchem-125	150	10	,	,	PUNCT
eurjchem-125	150	11	7.19	7.19	NUM
eurjchem-125	150	12	.	.	PUNCT
eurjchem-125	151	1	3	3	X
eurjchem-125	151	2	.	.	NOUN
eurjchem-125	151	3	results	result	NOUN
eurjchem-125	151	4	and	and	CCONJ
eurjchem-125	151	5	discussion	discussion	VERB
eurjchem-125	151	6	the	the	DET
eurjchem-125	151	7	mannich	mannich	PROPN
eurjchem-125	151	8	bases	basis	NOUN
eurjchem-125	151	9	of	of	ADP
eurjchem-125	151	10	syn	syn	NOUN
eurjchem-125	151	11	and	and	CCONJ
eurjchem-125	151	12	anti‐4‐methyl‐5‐thien‐2‐yl‐	anti‐4‐methyl‐5‐thien‐2‐yl‐	PROPN
eurjchem-125	151	13	1,3‐oxazolidin‐2‐ones	1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	151	14	were	be	AUX
eurjchem-125	151	15	thesized	thesize	VERB
eurjchem-125	151	16	as	as	SCONJ
eurjchem-125	151	17	depicted	depict	VERB
eurjchem-125	151	18	in	in	ADP
eurjchem-125	151	19	scheme	scheme	NOUN
eurjchem-125	151	20	1	1	NUM
eurjchem-125	151	21	.	.	PUNCT
eurjchem-125	152	1	the	the	DET
eurjchem-125	152	2	starting	starting	NOUN
eurjchem-125	152	3	(	(	PUNCT
eurjchem-125	152	4	2s,3r	2s,3r	NUM
eurjchem-125	152	5	)	)	PUNCT
eurjchem-125	152	6	and	and	CCONJ
eurjchem-125	152	7	(	(	PUNCT
eurjchem-125	152	8	2r,3r)‐3‐hydroxy‐2‐methyl‐3‐thien‐	2r,3r)‐3‐hydroxy‐2‐methyl‐3‐thien‐	NUM
eurjchem-125	152	9	2‐ylpropanohydrazides	2‐ylpropanohydrazide	NOUN
eurjchem-125	152	10	2	2	NUM
eurjchem-125	152	11	and	and	CCONJ
eurjchem-125	152	12	3	3	NUM
eurjchem-125	152	13	were	be	AUX
eurjchem-125	152	14	prepared	prepare	VERB
eurjchem-125	152	15	in	in	ADP
eurjchem-125	152	16	ethanol	ethanol	NOUN
eurjchem-125	152	17	using	use	VERB
eurjchem-125	152	18	hydrazine	hydrazine	NOUN
eurjchem-125	152	19	hydrate	hydrate	NOUN
eurjchem-125	152	20	and	and	CCONJ
eurjchem-125	152	21	the	the	DET
eurjchem-125	152	22	diastereoisomeric	diastereoisomeric	ADJ
eurjchem-125	152	23	mixture	mixture	NOUN
eurjchem-125	152	24	of	of	ADP
eurjchem-125	152	25	(	(	PUNCT
eurjchem-125	152	26	2r	2r	NUM
eurjchem-125	152	27	,	,	PUNCT
eurjchem-125	152	28	3r	3r	NUM
eurjchem-125	152	29	)	)	PUNCT
eurjchem-125	152	30	and	and	CCONJ
eurjchem-125	152	31	(	(	PUNCT
eurjchem-125	152	32	2s,3r)‐ethyl	2s,3r)‐ethyl	NUM
eurjchem-125	152	33	3‐hydroxy‐2‐methyl‐3‐thien‐2‐ylpropan‐	3‐hydroxy‐2‐methyl‐3‐thien‐2‐ylpropan‐	NUM
eurjchem-125	152	34	oate	oate	NOUN
eurjchem-125	152	35	1	1	NUM
eurjchem-125	152	36	,	,	PUNCT
eurjchem-125	152	37	obtained	obtain	VERB
eurjchem-125	152	38	through	through	ADP
eurjchem-125	152	39	the	the	DET
eurjchem-125	152	40	reformatsky	reformatsky	ADJ
eurjchem-125	152	41	reaction	reaction	NOUN
eurjchem-125	152	42	.	.	PUNCT
eurjchem-125	153	1	the	the	DET
eurjchem-125	153	2	(	(	PUNCT
eurjchem-125	153	3	2s,3r	2s,3r	NUM
eurjchem-125	153	4	)	)	PUNCT
eurjchem-125	153	5	and	and	CCONJ
eurjchem-125	153	6	(	(	PUNCT
eurjchem-125	153	7	2r,3r)‐3‐hydroxy‐2‐methyl‐3‐thien‐2‐ylpropano‐hydrazi‐	2r,3r)‐3‐hydroxy‐2‐methyl‐3‐thien‐2‐ylpropano‐hydrazi‐	NUM
eurjchem-125	153	8	des	de	NOUN
eurjchem-125	153	9	were	be	AUX
eurjchem-125	153	10	separated	separate	VERB
eurjchem-125	153	11	as	as	SCONJ
eurjchem-125	153	12	we	we	PRON
eurjchem-125	153	13	described	describe	VERB
eurjchem-125	153	14	early	early	ADV
eurjchem-125	153	15	[	[	X
eurjchem-125	153	16	22	22	NUM
eurjchem-125	153	17	]	]	PUNCT
eurjchem-125	153	18	.	.	PUNCT
eurjchem-125	154	1	the	the	DET
eurjchem-125	154	2	treatment	treatment	NOUN
eurjchem-125	154	3	of	of	ADP
eurjchem-125	154	4	the	the	DET
eurjchem-125	154	5	corresponding	correspond	VERB
eurjchem-125	154	6	(	(	PUNCT
eurjchem-125	154	7	2s,3r	2s,3r	NUM
eurjchem-125	154	8	)	)	PUNCT
eurjchem-125	154	9	or	or	CCONJ
eurjchem-125	154	10	(	(	PUNCT
eurjchem-125	154	11	2r,5r)‐3‐	2r,5r)‐3‐	NUM
eurjchem-125	154	12	hydroxy‐2‐methyl‐3‐thien‐2‐ylpropano‐hydrazides	hydroxy‐2‐methyl‐3‐thien‐2‐ylpropano‐hydrazide	NOUN
eurjchem-125	154	13	with	with	ADP
eurjchem-125	154	14	water	water	NOUN
eurjchem-125	154	15	solution	solution	NOUN
eurjchem-125	154	16	of	of	ADP
eurjchem-125	154	17	sodium	sodium	NOUN
eurjchem-125	154	18	nitrite	nitrite	NOUN
eurjchem-125	154	19	in	in	ADP
eurjchem-125	154	20	acetic	acetic	ADJ
eurjchem-125	154	21	acid	acid	NOUN
eurjchem-125	154	22	/	/	SYM
eurjchem-125	154	23	diethyl	diethyl	NOUN
eurjchem-125	154	24	ether	ether	NOUN
eurjchem-125	154	25	medium	medium	NOUN
eurjchem-125	154	26	via	via	ADP
eurjchem-125	154	27	β‐hydroxy‐azides	β‐hydroxy‐azide	NOUN
eurjchem-125	154	28	at	at	ADP
eurjchem-125	154	29	15‐20	15‐20	NUM
eurjchem-125	154	30	°	°	ADP
eurjchem-125	154	31	c	c	NOUN
eurjchem-125	154	32	and	and	CCONJ
eurjchem-125	154	33	followed	follow	VERB
eurjchem-125	154	34	by	by	ADP
eurjchem-125	154	35	curtius	curtius	NOUN
eurjchem-125	154	36	rearrangement	rearrangement	NOUN
eurjchem-125	154	37	of	of	ADP
eurjchem-125	154	38	β‐hydroxy‐isocyanates	β‐hydroxy‐isocyanate	NOUN
eurjchem-125	154	39	at	at	ADP
eurjchem-125	154	40	refluxing	refluxing	NOUN
eurjchem-125	154	41	of	of	ADP
eurjchem-125	154	42	the	the	DET
eurjchem-125	154	43	separated	separate	VERB
eurjchem-125	154	44	organic	organic	ADJ
eurjchem-125	154	45	solution	solution	NOUN
eurjchem-125	154	46	led	lead	VERB
eurjchem-125	154	47	to	to	ADP
eurjchem-125	154	48	forming	form	VERB
eurjchem-125	154	49	the	the	DET
eurjchem-125	154	50	1,3‐oxazolidin‐2‐	1,3‐oxazolidin‐2‐	NUM
eurjchem-125	154	51	one	one	NUM
eurjchem-125	154	52	cycle	cycle	NOUN
eurjchem-125	154	53	4	4	NUM
eurjchem-125	154	54	or	or	CCONJ
eurjchem-125	154	55	6	6	NUM
eurjchem-125	154	56	.	.	PUNCT
eurjchem-125	155	1	the	the	DET
eurjchem-125	155	2	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	155	3	4	4	NUM
eurjchem-125	155	4	or	or	CCONJ
eurjchem-125	155	5	6	6	NUM
eurjchem-125	155	6	,	,	PUNCT
eurjchem-125	155	7	morpholine	morpholine	ADJ
eurjchem-125	155	8	,	,	PUNCT
eurjchem-125	155	9	piperidine	piperidine	NOUN
eurjchem-125	155	10	,	,	PUNCT
eurjchem-125	155	11	benzhydrylpiperazine	benzhydrylpiperazine	NOUN
eurjchem-125	155	12	and	and	CCONJ
eurjchem-125	155	13	35	35	NUM
eurjchem-125	155	14	%	%	NOUN
eurjchem-125	155	15	formalin	formalin	NOUN
eurjchem-125	155	16	were	be	AUX
eurjchem-125	155	17	used	use	VERB
eurjchem-125	155	18	in	in	ADP
eurjchem-125	155	19	the	the	DET
eurjchem-125	155	20	mannich	mannich	NOUN
eurjchem-125	155	21	reaction	reaction	NOUN
eurjchem-125	155	22	in	in	ADP
eurjchem-125	155	23	ratio	ratio	NOUN
eurjchem-125	155	24	1:0.8:1.3	1:0.8:1.3	PROPN
eurjchem-125	155	25	and	and	CCONJ
eurjchem-125	155	26	by	by	ADP
eurjchem-125	155	27	the	the	DET
eurjchem-125	155	28	use	use	NOUN
eurjchem-125	155	29	of	of	ADP
eurjchem-125	155	30	piperazine	piperazine	NOUN
eurjchem-125	155	31	the	the	DET
eurjchem-125	155	32	ratio	ratio	NOUN
eurjchem-125	155	33	was	be	AUX
eurjchem-125	155	34	2:1:2.5	2:1:2.5	NUM
eurjchem-125	155	35	.	.	PUNCT
eurjchem-125	156	1	the	the	DET
eurjchem-125	156	2	process	process	NOUN
eurjchem-125	156	3	was	be	AUX
eurjchem-125	156	4	carried	carry	VERB
eurjchem-125	156	5	out	out	ADP
eurjchem-125	156	6	by	by	ADP
eurjchem-125	156	7	refluxing	refluxe	VERB
eurjchem-125	156	8	in	in	ADP
eurjchem-125	156	9	ethanol	ethanol	NOUN
eurjchem-125	156	10	for	for	ADP
eurjchem-125	156	11	2‐3	2‐3	NUM
eurjchem-125	156	12	hours	hour	NOUN
eurjchem-125	156	13	.	.	PUNCT
eurjchem-125	157	1	mavrova	mavrova	PROPN
eurjchem-125	157	2	et	et	PROPN
eurjchem-125	157	3	al	al	PROPN
eurjchem-125	157	4	.	.	PUNCT
eurjchem-125	157	5	/	/	SYM
eurjchem-125	157	6	european	european	PROPN
eurjchem-125	157	7	journal	journal	PROPN
eurjchem-125	157	8	of	of	ADP
eurjchem-125	157	9	chemistry	chemistry	NOUN
eurjchem-125	157	10	2	2	NUM
eurjchem-125	157	11	(	(	PUNCT
eurjchem-125	157	12	1	1	NUM
eurjchem-125	157	13	)	)	PUNCT
eurjchem-125	157	14	(	(	PUNCT
eurjchem-125	157	15	2011	2011	NUM
eurjchem-125	157	16	)	)	PUNCT
eurjchem-125	157	17	18‐24	18‐24	NOUN
eurjchem-125	157	18	21	21	NUM
eurjchem-125	157	19	  	  	SPACE
eurjchem-125	157	20	scheme	scheme	NOUN
eurjchem-125	157	21	1	1	NUM
eurjchem-125	157	22	it	it	PRON
eurjchem-125	157	23	is	be	AUX
eurjchem-125	157	24	known	know	VERB
eurjchem-125	157	25	that	that	SCONJ
eurjchem-125	157	26	the	the	DET
eurjchem-125	157	27	nucleophilic	nucleophilic	ADJ
eurjchem-125	157	28	properties	property	NOUN
eurjchem-125	157	29	of	of	ADP
eurjchem-125	157	30	the	the	DET
eurjchem-125	157	31	reagents	reagent	NOUN
eurjchem-125	157	32	participating	participate	VERB
eurjchem-125	157	33	in	in	ADP
eurjchem-125	157	34	the	the	DET
eurjchem-125	157	35	mannich	mannich	NOUN
eurjchem-125	157	36	reaction	reaction	NOUN
eurjchem-125	157	37	are	be	AUX
eurjchem-125	157	38	of	of	ADP
eurjchem-125	157	39	a	a	DET
eurjchem-125	157	40	significant	significant	ADJ
eurjchem-125	157	41	importance	importance	NOUN
eurjchem-125	157	42	for	for	ADP
eurjchem-125	157	43	the	the	DET
eurjchem-125	157	44	successful	successful	ADJ
eurjchem-125	157	45	performing	performing	NOUN
eurjchem-125	157	46	of	of	ADP
eurjchem-125	157	47	the	the	DET
eurjchem-125	157	48	synthesis	synthesis	NOUN
eurjchem-125	157	49	.	.	PUNCT
eurjchem-125	158	1	it	it	PRON
eurjchem-125	158	2	was	be	AUX
eurjchem-125	158	3	estimated	estimate	VERB
eurjchem-125	158	4	that	that	SCONJ
eurjchem-125	158	5	by	by	ADP
eurjchem-125	158	6	the	the	DET
eurjchem-125	158	7	reaction	reaction	NOUN
eurjchem-125	158	8	between	between	ADP
eurjchem-125	158	9	anti‐	anti‐	PROPN
eurjchem-125	158	10	and	and	CCONJ
eurjchem-125	158	11	syn‐4‐	syn‐4‐	PROPN
eurjchem-125	158	12	methyl‐5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐ones	methyl‐5‐thien‐2‐yl‐1,3‐oxazolidin‐2‐one	NOUN
eurjchem-125	158	13	and	and	CCONJ
eurjchem-125	158	14	the	the	DET
eurjchem-125	158	15	above	above	ADV
eurjchem-125	158	16	mentioned	mention	VERB
eurjchem-125	158	17	secondary	secondary	ADJ
eurjchem-125	158	18	cyclic	cyclic	ADJ
eurjchem-125	158	19	amines	amine	NOUN
eurjchem-125	158	20	it	it	PRON
eurjchem-125	158	21	is	be	AUX
eurjchem-125	158	22	enough	enough	ADJ
eurjchem-125	158	23	to	to	PART
eurjchem-125	158	24	use	use	VERB
eurjchem-125	158	25	a	a	DET
eurjchem-125	158	26	low	low	ADJ
eurjchem-125	158	27	access	access	NOUN
eurjchem-125	158	28	of	of	ADP
eurjchem-125	158	29	the	the	DET
eurjchem-125	158	30	amines	amine	NOUN
eurjchem-125	158	31	to	to	PART
eurjchem-125	158	32	complete	complete	VERB
eurjchem-125	158	33	the	the	DET
eurjchem-125	158	34	synthesis	synthesis	NOUN
eurjchem-125	158	35	successfully	successfully	ADV
eurjchem-125	158	36	.	.	PUNCT
eurjchem-125	159	1	because	because	SCONJ
eurjchem-125	159	2	the	the	DET
eurjchem-125	159	3	asymmetrical	asymmetrical	ADJ
eurjchem-125	159	4	centers	center	NOUN
eurjchem-125	159	5	were	be	AUX
eurjchem-125	159	6	not	not	PART
eurjchem-125	159	7	involved	involve	VERB
eurjchem-125	159	8	in	in	ADP
eurjchem-125	159	9	the	the	DET
eurjchem-125	159	10	reaction	reaction	NOUN
eurjchem-125	159	11	,	,	PUNCT
eurjchem-125	159	12	the	the	DET
eurjchem-125	159	13	c‐atoms	c‐atom	NOUN
eurjchem-125	159	14	at	at	ADP
eurjchem-125	159	15	4th	4th	ADJ
eurjchem-125	159	16	and	and	CCONJ
eurjchem-125	159	17	5th	5th	ADJ
eurjchem-125	159	18	position	position	NOUN
eurjchem-125	159	19	of	of	ADP
eurjchem-125	159	20	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	159	21	cycle	cycle	NOUN
eurjchem-125	159	22	in	in	ADP
eurjchem-125	159	23	the	the	DET
eurjchem-125	159	24	corresponding	corresponding	ADJ
eurjchem-125	159	25	compounds	compound	NOUN
eurjchem-125	159	26	5a‐e	5a‐e	PROPN
eurjchem-125	159	27	and	and	CCONJ
eurjchem-125	159	28	7a‐e	7a‐e	PROPN
eurjchem-125	159	29	preserved	preserve	VERB
eurjchem-125	159	30	the	the	DET
eurjchem-125	159	31	same	same	ADJ
eurjchem-125	159	32	configuration	configuration	NOUN
eurjchem-125	159	33	as	as	ADP
eurjchem-125	159	34	these	these	PRON
eurjchem-125	159	35	in	in	ADP
eurjchem-125	159	36	the	the	DET
eurjchem-125	159	37	starting	start	VERB
eurjchem-125	159	38	oxazolidin‐2‐ones	oxazolidin‐2‐one	NOUN
eurjchem-125	159	39	.	.	PUNCT
eurjchem-125	160	1	some	some	DET
eurjchem-125	160	2	physical	physical	ADJ
eurjchem-125	160	3	data	datum	NOUN
eurjchem-125	160	4	are	be	AUX
eurjchem-125	160	5	given	give	VERB
eurjchem-125	160	6	in	in	ADP
eurjchem-125	160	7	table	table	NOUN
eurjchem-125	160	8	1	1	NUM
eurjchem-125	160	9	.	.	PUNCT
eurjchem-125	161	1	in	in	ADP
eurjchem-125	161	2	order	order	NOUN
eurjchem-125	161	3	to	to	PART
eurjchem-125	161	4	determine	determine	VERB
eurjchem-125	161	5	,	,	PUNCT
eurjchem-125	161	6	the	the	DET
eurjchem-125	161	7	geometry	geometry	NOUN
eurjchem-125	161	8	and	and	CCONJ
eurjchem-125	161	9	the	the	DET
eurjchem-125	161	10	dihedral	dihedral	ADJ
eurjchem-125	161	11	angels	angel	NOUN
eurjchem-125	161	12	of	of	ADP
eurjchem-125	161	13	compounds	compound	NOUN
eurjchem-125	161	14	4	4	NUM
eurjchem-125	161	15	and	and	CCONJ
eurjchem-125	161	16	6	6	NUM
eurjchem-125	161	17	,	,	PUNCT
eurjchem-125	161	18	dft	dft	PROPN
eurjchem-125	161	19	computations	computation	NOUN
eurjchem-125	161	20	were	be	AUX
eurjchem-125	161	21	performed	perform	VERB
eurjchem-125	161	22	with	with	ADP
eurjchem-125	161	23	standard	standard	ADJ
eurjchem-125	161	24	gaussian	gaussian	ADJ
eurjchem-125	161	25	98	98	NUM
eurjchem-125	161	26	program	program	NOUN
eurjchem-125	161	27	package	package	NOUN
eurjchem-125	161	28	.	.	PUNCT
eurjchem-125	162	1	we	we	PRON
eurjchem-125	162	2	employed	employ	VERB
eurjchem-125	162	3	the	the	DET
eurjchem-125	162	4	b3lyp	b3lyp	X
eurjchem-125	162	5	hybrid	hybrid	ADJ
eurjchem-125	162	6	functional	functional	ADJ
eurjchem-125	162	7	with	with	ADP
eurjchem-125	162	8	6‐31	6‐31	NUM
eurjchem-125	162	9	g	g	NOUN
eurjchem-125	162	10	basis	basis	NOUN
eurjchem-125	162	11	set	set	NOUN
eurjchem-125	162	12	.	.	PUNCT
eurjchem-125	163	1	furthermore	furthermore	ADV
eurjchem-125	163	2	for	for	ADP
eurjchem-125	163	3	the	the	DET
eurjchem-125	163	4	calculation	calculation	NOUN
eurjchem-125	163	5	of	of	ADP
eurjchem-125	163	6	some	some	DET
eurjchem-125	163	7	steric	steric	ADJ
eurjchem-125	163	8	,	,	PUNCT
eurjchem-125	163	9	physicochemical	physicochemical	ADJ
eurjchem-125	163	10	and	and	CCONJ
eurjchem-125	163	11	electronic	electronic	ADJ
eurjchem-125	163	12	parameters	parameter	NOUN
eurjchem-125	163	13	of	of	ADP
eurjchem-125	163	14	compounds	compound	NOUN
eurjchem-125	163	15	5a‐e	5a‐e	PROPN
eurjchem-125	163	16	and	and	CCONJ
eurjchem-125	163	17	7a‐e	7a‐e	PROPN
eurjchem-125	163	18	chem3d	chem3d	PROPN
eurjchem-125	163	19	ultra	ultra	ADJ
eurjchem-125	163	20	,	,	PUNCT
eurjchem-125	163	21	chemdraw	chemdraw	ADJ
eurjchem-125	163	22	ultra	ultra	ADJ
eurjchem-125	163	23	,	,	PUNCT
eurjchem-125	163	24	version	version	NOUN
eurjchem-125	163	25	11.0.1	11.0.1	NUM
eurjchem-125	163	26	was	be	AUX
eurjchem-125	163	27	used	use	VERB
eurjchem-125	163	28	[	[	X
eurjchem-125	163	29	23	23	NUM
eurjchem-125	163	30	]	]	PUNCT
eurjchem-125	163	31	.	.	PUNCT
eurjchem-125	164	1	structures	structure	NOUN
eurjchem-125	164	2	of	of	ADP
eurjchem-125	164	3	the	the	DET
eurjchem-125	164	4	compounds	compound	NOUN
eurjchem-125	164	5	were	be	AUX
eurjchem-125	164	6	confirmed	confirm	VERB
eurjchem-125	164	7	by	by	ADP
eurjchem-125	164	8	1h	1h	NUM
eurjchem-125	164	9	and	and	CCONJ
eurjchem-125	164	10	13c	13c	NOUN
eurjchem-125	164	11	nmr	nmr	NOUN
eurjchem-125	164	12	spectra	spectra	NOUN
eurjchem-125	164	13	.	.	PUNCT
eurjchem-125	165	1	the	the	DET
eurjchem-125	165	2	stereochemistry	stereochemistry	NOUN
eurjchem-125	165	3	of	of	ADP
eurjchem-125	165	4	anti‐	anti‐	PROPN
eurjchem-125	165	5	and	and	CCONJ
eurjchem-125	165	6	syn‐isomers	syn‐isomer	NOUN
eurjchem-125	165	7	was	be	AUX
eurjchem-125	165	8	assigned	assign	VERB
eurjchem-125	165	9	using	use	VERB
eurjchem-125	165	10	the	the	DET
eurjchem-125	165	11	observed	observed	ADJ
eurjchem-125	165	12	differences	difference	NOUN
eurjchem-125	165	13	in	in	ADP
eurjchem-125	165	14	the	the	DET
eurjchem-125	165	15	chemical	chemical	ADJ
eurjchem-125	165	16	shifts	shift	NOUN
eurjchem-125	165	17	of	of	ADP
eurjchem-125	165	18	some	some	DET
eurjchem-125	165	19	key	key	ADJ
eurjchem-125	165	20	signals	signal	NOUN
eurjchem-125	165	21	and	and	CCONJ
eurjchem-125	165	22	the	the	DET
eurjchem-125	165	23	values	value	NOUN
eurjchem-125	165	24	of	of	ADP
eurjchem-125	165	25	vicinal	vicinal	ADJ
eurjchem-125	165	26	coupling	coupling	NOUN
eurjchem-125	165	27	constants	constant	NOUN
eurjchem-125	165	28	(	(	PUNCT
eurjchem-125	165	29	3j	3j	NOUN
eurjchem-125	165	30	)	)	PUNCT
eurjchem-125	165	31	between	between	ADP
eurjchem-125	165	32	the	the	DET
eurjchem-125	165	33	two	two	NUM
eurjchem-125	165	34	protons	proton	NOUN
eurjchem-125	165	35	from	from	ADP
eurjchem-125	165	36	the	the	DET
eurjchem-125	165	37	oxazolidin‐2‐one	oxazolidin‐2‐one	PROPN
eurjchem-125	165	38	ring	ring	NOUN
eurjchem-125	165	39	.	.	PUNCT
eurjchem-125	166	1	for	for	ADP
eurjchem-125	166	2	all	all	DET
eurjchem-125	166	3	compounds	compound	NOUN
eurjchem-125	166	4	noe	noe	INTJ
eurjchem-125	166	5	(	(	PUNCT
eurjchem-125	166	6	nuclear	nuclear	ADJ
eurjchem-125	166	7	overhauser	overhauser	NOUN
eurjchem-125	166	8	effect	effect	NOUN
eurjchem-125	166	9	)	)	PUNCT
eurjchem-125	166	10	nmr	nmr	NOUN
eurjchem-125	166	11	spectra	spectra	NOUN
eurjchem-125	166	12	were	be	AUX
eurjchem-125	166	13	measured	measure	VERB
eurjchem-125	166	14	in	in	ADP
eurjchem-125	166	15	order	order	NOUN
eurjchem-125	166	16	to	to	PART
eurjchem-125	166	17	prove	prove	VERB
eurjchem-125	166	18	additionally	additionally	ADV
eurjchem-125	166	19	the	the	DET
eurjchem-125	166	20	position	position	NOUN
eurjchem-125	166	21	of	of	ADP
eurjchem-125	166	22	the	the	DET
eurjchem-125	166	23	substituents	substituent	NOUN
eurjchem-125	166	24	in	in	ADP
eurjchem-125	166	25	the	the	DET
eurjchem-125	166	26	oxazolidin‐2‐one	oxazolidin‐2‐one	NUM
eurjchem-125	166	27	ring	ring	NOUN
eurjchem-125	166	28	.	.	PUNCT
eurjchem-125	167	1	in	in	ADP
eurjchem-125	167	2	five	five	NUM
eurjchem-125	167	3	membered	membere	VERB
eurjchem-125	167	4	rings	ring	NOUN
eurjchem-125	167	5	,	,	PUNCT
eurjchem-125	167	6	due	due	ADP
eurjchem-125	167	7	to	to	ADP
eurjchem-125	167	8	their	their	PRON
eurjchem-125	167	9	higher	high	ADJ
eurjchem-125	167	10	conformational	conformational	ADJ
eurjchem-125	167	11	flexibility	flexibility	NOUN
eurjchem-125	167	12	,	,	PUNCT
eurjchem-125	167	13	the	the	DET
eurjchem-125	167	14	dihedral	dihedral	ADJ
eurjchem-125	167	15	angles	angle	NOUN
eurjchem-125	167	16	(	(	PUNCT
eurjchem-125	167	17			PROPN
eurjchem-125	167	18	)	)	PUNCT
eurjchem-125	167	19	are	be	AUX
eurjchem-125	167	20	less	less	ADV
eurjchem-125	167	21	well	well	ADV
eurjchem-125	167	22	defined	define	VERB
eurjchem-125	167	23	and	and	CCONJ
eurjchem-125	167	24	the	the	DET
eurjchem-125	167	25	vicinal	vicinal	ADJ
eurjchem-125	167	26	coupling	coupling	NOUN
eurjchem-125	167	27	constants	constant	NOUN
eurjchem-125	167	28	are	be	AUX
eurjchem-125	167	29	not	not	PART
eurjchem-125	167	30	characteristic	characteristic	ADJ
eurjchem-125	167	31	in	in	ADP
eurjchem-125	167	32	general	general	ADJ
eurjchem-125	167	33	.	.	PUNCT
eurjchem-125	168	1	the	the	DET
eurjchem-125	168	2	conformation	conformation	NOUN
eurjchem-125	168	3	of	of	ADP
eurjchem-125	168	4	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	168	5	ring	ring	NOUN
eurjchem-125	168	6	in	in	ADP
eurjchem-125	168	7	the	the	DET
eurjchem-125	168	8	studied	study	VERB
eurjchem-125	168	9	compounds	compound	NOUN
eurjchem-125	168	10	is	be	AUX
eurjchem-125	168	11	relatively	relatively	ADV
eurjchem-125	168	12	fixed	fix	VERB
eurjchem-125	168	13	due	due	ADP
eurjchem-125	168	14	to	to	ADP
eurjchem-125	168	15	the	the	DET
eurjchem-125	168	16	presence	presence	NOUN
eurjchem-125	168	17	of	of	ADP
eurjchem-125	168	18	two	two	NUM
eurjchem-125	168	19	bulky	bulky	ADJ
eurjchem-125	168	20	substituents	substituent	NOUN
eurjchem-125	168	21	at	at	ADP
eurjchem-125	168	22	c4	c4	NOUN
eurjchem-125	168	23	and	and	CCONJ
eurjchem-125	168	24	c5	c5	PROPN
eurjchem-125	168	25	atoms	atom	NOUN
eurjchem-125	168	26	.	.	PUNCT
eurjchem-125	169	1	the	the	DET
eurjchem-125	169	2	theoretical	theoretical	ADJ
eurjchem-125	169	3	values	value	NOUN
eurjchem-125	169	4	of	of	ADP
eurjchem-125	169	5	the	the	DET
eurjchem-125	169	6	dihedral	dihedral	ADJ
eurjchem-125	169	7	angle	angle	NOUN
eurjchem-125	169	8	defined	define	VERB
eurjchem-125	169	9	by	by	ADP
eurjchem-125	169	10	h5‐c5‐c4‐h4	h5‐c5‐c4‐h4	NOUN
eurjchem-125	169	11	atoms	atom	NOUN
eurjchem-125	169	12	of	of	ADP
eurjchem-125	169	13	the	the	DET
eurjchem-125	169	14	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	169	15	ring	ring	NOUN
eurjchem-125	169	16	in	in	ADP
eurjchem-125	169	17	the	the	DET
eurjchem-125	169	18	optimized	optimize	VERB
eurjchem-125	169	19	structures	structure	NOUN
eurjchem-125	169	20	of	of	ADP
eurjchem-125	169	21	the	the	DET
eurjchem-125	169	22	studied	study	VERB
eurjchem-125	169	23	compounds	compound	NOUN
eurjchem-125	169	24	are	be	AUX
eurjchem-125	169	25	between	between	ADP
eurjchem-125	169	26	3.4	3.4	NUM
eurjchem-125	169	27	and	and	CCONJ
eurjchem-125	169	28	17.3	17.3	NUM
eurjchem-125	169	29	degrees	degree	NOUN
eurjchem-125	169	30	for	for	ADP
eurjchem-125	169	31	syn‐isomers	syn‐isomer	NOUN
eurjchem-125	169	32	and	and	CCONJ
eurjchem-125	169	33	between	between	ADP
eurjchem-125	169	34	124.2	124.2	NUM
eurjchem-125	169	35	and	and	CCONJ
eurjchem-125	169	36	140.3	140.3	NUM
eurjchem-125	169	37	degrees	degree	NOUN
eurjchem-125	169	38	for	for	ADP
eurjchem-125	169	39	anti‐compounds	anti‐compound	NOUN
eurjchem-125	169	40	,	,	PUNCT
eurjchem-125	169	41	depending	depend	VERB
eurjchem-125	169	42	on	on	ADP
eurjchem-125	169	43	the	the	DET
eurjchem-125	169	44	substituents	substituent	NOUN
eurjchem-125	169	45	.	.	PUNCT
eurjchem-125	170	1	the	the	DET
eurjchem-125	170	2	experimental	experimental	ADJ
eurjchem-125	170	3	3j	3j	PROPN
eurjchem-125	170	4	constants	constant	NOUN
eurjchem-125	170	5	of	of	ADP
eurjchem-125	170	6	syn‐derivatives	syn‐derivative	NOUN
eurjchem-125	170	7	are	be	AUX
eurjchem-125	170	8	systematically	systematically	ADV
eurjchem-125	170	9	higher	high	ADJ
eurjchem-125	170	10	as	as	SCONJ
eurjchem-125	170	11	compared	compare	VERB
eurjchem-125	170	12	with	with	ADP
eurjchem-125	170	13	those	those	PRON
eurjchem-125	170	14	in	in	ADP
eurjchem-125	170	15	the	the	DET
eurjchem-125	170	16	respective	respective	ADJ
eurjchem-125	170	17	anti‐compounds	anti‐compound	NOUN
eurjchem-125	170	18	.	.	PUNCT
eurjchem-125	171	1	the	the	DET
eurjchem-125	171	2	experimental	experimental	ADJ
eurjchem-125	171	3	3j	3j	NUM
eurjchem-125	171	4	constant	constant	ADJ
eurjchem-125	171	5	for	for	ADP
eurjchem-125	171	6	syn‐isomers	syn‐isomer	NOUN
eurjchem-125	171	7	was	be	AUX
eurjchem-125	171	8	found	find	VERB
eurjchem-125	171	9	to	to	PART
eurjchem-125	171	10	be	be	AUX
eurjchem-125	171	11	7.88	7.88	NUM
eurjchem-125	171	12	hz	hz	NOUN
eurjchem-125	171	13	,	,	PUNCT
eurjchem-125	171	14	averaged	average	VERB
eurjchem-125	171	15	over	over	ADP
eurjchem-125	171	16	six	six	NUM
eurjchem-125	171	17	compounds	compound	NOUN
eurjchem-125	171	18	,	,	PUNCT
eurjchem-125	171	19	while	while	SCONJ
eurjchem-125	171	20	for	for	ADP
eurjchem-125	171	21	the	the	DET
eurjchem-125	171	22	trans‐derivatives	trans‐derivative	NOUN
eurjchem-125	171	23	the	the	DET
eurjchem-125	171	24	value	value	NOUN
eurjchem-125	171	25	is	be	AUX
eurjchem-125	171	26	6.77	6.77	NUM
eurjchem-125	171	27	hz	hz	PRON
eurjchem-125	171	28	averaged	average	VERB
eurjchem-125	171	29	over	over	ADP
eurjchem-125	171	30	five	five	NUM
eurjchem-125	171	31	compounds	compound	NOUN
eurjchem-125	171	32	.	.	PUNCT
eurjchem-125	172	1	these	these	DET
eurjchem-125	172	2	results	result	NOUN
eurjchem-125	172	3	follow	follow	VERB
eurjchem-125	172	4	the	the	DET
eurjchem-125	172	5	tendency	tendency	NOUN
eurjchem-125	172	6	and	and	CCONJ
eurjchem-125	172	7	are	be	AUX
eurjchem-125	172	8	in	in	ADP
eurjchem-125	172	9	a	a	DET
eurjchem-125	172	10	very	very	ADV
eurjchem-125	172	11	good	good	ADJ
eurjchem-125	172	12	agreement	agreement	NOUN
eurjchem-125	172	13	with	with	ADP
eurjchem-125	172	14	the	the	DET
eurjchem-125	172	15	3j	3j	NOUN
eurjchem-125	172	16	values	value	NOUN
eurjchem-125	172	17	theoretically	theoretically	ADV
eurjchem-125	172	18	predicted	predict	VERB
eurjchem-125	172	19	by	by	ADP
eurjchem-125	172	20	karplus	karplus	ADJ
eurjchem-125	172	21	curve	curve	NOUN
eurjchem-125	172	22	simulated	simulate	VERB
eurjchem-125	172	23	using	use	VERB
eurjchem-125	172	24	the	the	DET
eurjchem-125	172	25	karplus	karplus	ADJ
eurjchem-125	172	26	equation	equation	NOUN
eurjchem-125	172	27	with	with	ADP
eurjchem-125	172	28	coefficients	coefficient	NOUN
eurjchem-125	172	29	applicable	applicable	ADJ
eurjchem-125	172	30	for	for	ADP
eurjchem-125	172	31	h‐c‐c‐h	h‐c‐c‐h	ADJ
eurjchem-125	172	32	fragments	fragment	NOUN
eurjchem-125	172	33	and	and	CCONJ
eurjchem-125	172	34	above	above	ADV
eurjchem-125	172	35	given	give	VERB
eurjchem-125	172	36	values	value	NOUN
eurjchem-125	172	37	of	of	ADP
eurjchem-125	172	38	the	the	DET
eurjchem-125	172	39	dihedral	dihedral	ADJ
eurjchem-125	172	40	angles	angle	NOUN
eurjchem-125	172	41	[	[	X
eurjchem-125	172	42	24	24	NUM
eurjchem-125	172	43	]	]	PUNCT
eurjchem-125	172	44	.	.	PUNCT
eurjchem-125	173	1	the	the	DET
eurjchem-125	173	2	chemical	chemical	ADJ
eurjchem-125	173	3	shift	shift	NOUN
eurjchem-125	173	4	values	value	NOUN
eurjchem-125	173	5	for	for	ADP
eurjchem-125	173	6	the	the	DET
eurjchem-125	173	7	methyl	methyl	NOUN
eurjchem-125	173	8	protons	proton	NOUN
eurjchem-125	173	9	in	in	ADP
eurjchem-125	173	10	anti‐	anti‐	PROPN
eurjchem-125	173	11	compounds	compound	NOUN
eurjchem-125	173	12	are	be	AUX
eurjchem-125	173	13	systematically	systematically	ADV
eurjchem-125	173	14	higher	high	ADJ
eurjchem-125	173	15	(	(	PUNCT
eurjchem-125	173	16	av	av	NOUN
eurjchem-125	173	17	.	.	NOUN
eurjchem-125	173	18	value	value	PROPN
eurjchem-125	173	19	1.38	1.38	NUM
eurjchem-125	173	20	ppm	ppm	NOUN
eurjchem-125	173	21	)	)	PUNCT
eurjchem-125	173	22	as	as	SCONJ
eurjchem-125	173	23	compared	compare	VERB
eurjchem-125	173	24	with	with	ADP
eurjchem-125	173	25	those	those	PRON
eurjchem-125	173	26	for	for	ADP
eurjchem-125	173	27	the	the	DET
eurjchem-125	173	28	respective	respective	ADJ
eurjchem-125	173	29	syn‐	syn‐	PUNCT
eurjchem-125	173	30	isomers	isomer	NOUN
eurjchem-125	173	31	(	(	PUNCT
eurjchem-125	173	32	av	av	NOUN
eurjchem-125	173	33	.	.	NOUN
eurjchem-125	173	34	value	value	NOUN
eurjchem-125	173	35	0.97	0.97	NUM
eurjchem-125	173	36	ppm	ppm	NOUN
eurjchem-125	173	37	)	)	PUNCT
eurjchem-125	173	38	.	.	PUNCT
eurjchem-125	174	1	the	the	DET
eurjchem-125	174	2	differences	difference	NOUN
eurjchem-125	174	3	(ch3	(ch3	PROPN
eurjchem-125	174	4	)	)	PUNCT
eurjchem-125	174	5	=	=	PUNCT
eurjchem-125	175	1	[	[	X
eurjchem-125	175	2	(ch3‐anti	(ch3‐anti	NOUN
eurjchem-125	175	3	)	)	PUNCT
eurjchem-125	175	4	–	–	PUNCT
eurjchem-125	175	5	(ch3‐syn	(ch3‐syn	NOUN
eurjchem-125	175	6	)	)	PUNCT
eurjchem-125	175	7	]	]	PUNCT
eurjchem-125	175	8	,	,	PUNCT
eurjchem-125	175	9	for	for	ADP
eurjchem-125	175	10	a	a	DET
eurjchem-125	175	11	given	give	VERB
eurjchem-125	175	12	diastereomeric	diastereomeric	ADJ
eurjchem-125	175	13	pair	pair	NOUN
eurjchem-125	175	14	are	be	AUX
eurjchem-125	175	15	in	in	ADP
eurjchem-125	175	16	the	the	DET
eurjchem-125	175	17	range	range	NOUN
eurjchem-125	175	18	0.45	0.45	NUM
eurjchem-125	175	19	–	–	PUNCT
eurjchem-125	175	20	0.40	0.40	NUM
eurjchem-125	175	21	ppm	ppm	NOUN
eurjchem-125	175	22	.	.	PUNCT
eurjchem-125	176	1	figure	figure	NOUN
eurjchem-125	176	2	1	1	NUM
eurjchem-125	176	3	represents	represent	VERB
eurjchem-125	176	4	the	the	DET
eurjchem-125	176	5	1h	1h	NUM
eurjchem-125	176	6	spectra	spectra	NOUN
eurjchem-125	176	7	of	of	ADP
eurjchem-125	176	8	the	the	DET
eurjchem-125	176	9	two	two	NUM
eurjchem-125	176	10	isomers	isomer	NOUN
eurjchem-125	176	11	7b	7b	NOUN
eurjchem-125	176	12	and	and	CCONJ
eurjchem-125	176	13	5b	5b	NUM
eurjchem-125	176	14	.	.	PUNCT
eurjchem-125	177	1	figure	figure	NOUN
eurjchem-125	177	2	1	1	NUM
eurjchem-125	177	3	.	.	NUM
eurjchem-125	177	4	1h	1h	NUM
eurjchem-125	177	5	nmr	nmr	NOUN
eurjchem-125	177	6	spectra	spectra	NOUN
eurjchem-125	177	7	of	of	ADP
eurjchem-125	177	8	the	the	DET
eurjchem-125	177	9	two	two	NUM
eurjchem-125	177	10	isomers	isomer	NOUN
eurjchem-125	177	11	:	:	PUNCT
eurjchem-125	177	12	(	(	PUNCT
eurjchem-125	177	13	a	a	X
eurjchem-125	177	14	)	)	PUNCT
eurjchem-125	177	15	7b	7b	NOUN
eurjchem-125	177	16	(	(	PUNCT
eurjchem-125	177	17	syn	syn	NOUN
eurjchem-125	177	18	)	)	PUNCT
eurjchem-125	177	19	and	and	CCONJ
eurjchem-125	177	20	(	(	PUNCT
eurjchem-125	177	21	b	b	NOUN
eurjchem-125	177	22	)	)	PUNCT
eurjchem-125	177	23	5b	5b	NOUN
eurjchem-125	177	24	(	(	PUNCT
eurjchem-125	177	25	anti	anti	ADJ
eurjchem-125	177	26	)	)	PUNCT
eurjchem-125	177	27	.	.	PUNCT
eurjchem-125	178	1	this	this	DET
eurjchem-125	178	2	observation	observation	NOUN
eurjchem-125	178	3	could	could	AUX
eurjchem-125	178	4	be	be	AUX
eurjchem-125	178	5	explained	explain	VERB
eurjchem-125	178	6	by	by	ADP
eurjchem-125	178	7	the	the	DET
eurjchem-125	178	8	magnetic	magnetic	ADJ
eurjchem-125	178	9	anisotropy	anisotropy	NOUN
eurjchem-125	178	10	effect	effect	NOUN
eurjchem-125	178	11	of	of	ADP
eurjchem-125	178	12	the	the	DET
eurjchem-125	178	13	double	double	ADJ
eurjchem-125	178	14	bonds	bond	NOUN
eurjchem-125	178	15	from	from	ADP
eurjchem-125	178	16	the	the	DET
eurjchem-125	178	17	thiophen	thiophen	PROPN
eurjchem-125	178	18	ring	ring	NOUN
eurjchem-125	178	19	.	.	PUNCT
eurjchem-125	179	1	in	in	ADP
eurjchem-125	179	2	syn‐compounds	syn‐compound	NOUN
eurjchem-125	179	3	the	the	DET
eurjchem-125	179	4	ch3	ch3	PROPN
eurjchem-125	179	5	group	group	NOUN
eurjchem-125	179	6	is	be	AUX
eurjchem-125	179	7	oriented	orient	VERB
eurjchem-125	179	8	parallel	parallel	NOUN
eurjchem-125	179	9	to	to	ADP
eurjchem-125	179	10	the	the	DET
eurjchem-125	179	11	thiophen	thiophen	PROPN
eurjchem-125	179	12	ring	ring	NOUN
eurjchem-125	179	13	and	and	CCONJ
eurjchem-125	179	14	the	the	DET
eurjchem-125	179	15	protons	proton	NOUN
eurjchem-125	179	16	are	be	AUX
eurjchem-125	179	17	in	in	ADP
eurjchem-125	179	18	the	the	DET
eurjchem-125	179	19	vicinity	vicinity	NOUN
eurjchem-125	179	20	of	of	ADP
eurjchem-125	179	21	the	the	DET
eurjchem-125	179	22	shielding	shielding	NOUN
eurjchem-125	179	23	zone	zone	NOUN
eurjchem-125	179	24	above	above	ADP
eurjchem-125	179	25	the	the	DET
eurjchem-125	179	26	double	double	ADJ
eurjchem-125	179	27	bonds	bond	NOUN
eurjchem-125	179	28	plane	plane	NOUN
eurjchem-125	179	29	.	.	PUNCT
eurjchem-125	180	1	another	another	DET
eurjchem-125	180	2	characteristic	characteristic	ADJ
eurjchem-125	180	3	signal	signal	NOUN
eurjchem-125	180	4	is	be	AUX
eurjchem-125	180	5	the	the	DET
eurjchem-125	180	6	one	one	NUM
eurjchem-125	180	7	for	for	ADP
eurjchem-125	180	8	och	och	NOUN
eurjchem-125	180	9	from	from	ADP
eurjchem-125	180	10	the	the	DET
eurjchem-125	180	11	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	180	12	ring	ring	NOUN
eurjchem-125	180	13	,	,	PUNCT
eurjchem-125	180	14	which	which	PRON
eurjchem-125	180	15	is	be	AUX
eurjchem-125	180	16	systematically	systematically	ADV
eurjchem-125	180	17	deshielded	deshielde	VERB
eurjchem-125	180	18	in	in	ADP
eurjchem-125	180	19	syn‐compounds	syn‐compound	NOUN
eurjchem-125	180	20	by	by	ADP
eurjchem-125	180	21	0.52	0.52	NUM
eurjchem-125	180	22	ppm	ppm	NOUN
eurjchem-125	180	23	in	in	ADP
eurjchem-125	180	24	average	average	ADJ
eurjchem-125	180	25	–	–	PUNCT
eurjchem-125	180	26	see	see	NOUN
eurjchem-125	180	27	figure	figure	NOUN
eurjchem-125	180	28	1	1	NUM
eurjchem-125	180	29	as	as	ADP
eurjchem-125	180	30	an	an	DET
eurjchem-125	180	31	example	example	NOUN
eurjchem-125	180	32	.	.	PUNCT
eurjchem-125	181	1	this	this	DET
eurjchem-125	181	2	finding	finding	NOUN
eurjchem-125	181	3	is	be	AUX
eurjchem-125	181	4	attributed	attribute	VERB
eurjchem-125	181	5	to	to	ADP
eurjchem-125	181	6	the	the	DET
eurjchem-125	181	7	‐effect	‐effect	PROPN
eurjchem-125	181	8	,	,	PUNCT
eurjchem-125	181	9	which	which	PRON
eurjchem-125	181	10	in	in	ADP
eurjchem-125	181	11	ch3	ch3	PROPN
eurjchem-125	181	12	–	–	PUNCT
eurjchem-125	181	13	c	c	NOUN
eurjchem-125	181	14	–	–	PUNCT
eurjchem-125	181	15	c	c	NOUN
eurjchem-125	181	16	–	–	PUNCT
eurjchem-125	181	17	h	h	NOUN
eurjchem-125	181	18	molecular	molecular	ADJ
eurjchem-125	181	19	fragments	fragment	NOUN
eurjchem-125	181	20	leads	lead	VERB
eurjchem-125	181	21	to	to	PART
eurjchem-125	181	22	downfield	downfield	NOUN
eurjchem-125	181	23	shift	shift	NOUN
eurjchem-125	181	24	if	if	SCONJ
eurjchem-125	181	25	the	the	DET
eurjchem-125	181	26	proton	proton	NOUN
eurjchem-125	181	27	and	and	CCONJ
eurjchem-125	181	28	the	the	DET
eurjchem-125	181	29	methyl	methyl	NOUN
eurjchem-125	181	30	group	group	NOUN
eurjchem-125	181	31	are	be	AUX
eurjchem-125	181	32	in	in	ADP
eurjchem-125	181	33	antiperiplanar	antiperiplanar	NOUN
eurjchem-125	181	34	position	position	NOUN
eurjchem-125	181	35	,	,	PUNCT
eurjchem-125	181	36	as	as	ADP
eurjchem-125	181	37	in	in	ADP
eurjchem-125	181	38	the	the	DET
eurjchem-125	181	39	case	case	NOUN
eurjchem-125	181	40	of	of	ADP
eurjchem-125	181	41	syn‐	syn‐	NOUN
eurjchem-125	181	42	isomers	isomer	NOUN
eurjchem-125	181	43	,	,	PUNCT
eurjchem-125	181	44	and	and	CCONJ
eurjchem-125	181	45	to	to	PART
eurjchem-125	181	46	upfield	upfield	VERB
eurjchem-125	181	47	shift	shift	NOUN
eurjchem-125	181	48	if	if	SCONJ
eurjchem-125	181	49	the	the	DET
eurjchem-125	181	50	proton	proton	NOUN
eurjchem-125	181	51	is	be	AUX
eurjchem-125	181	52	in	in	ADP
eurjchem-125	181	53	syn	syn	NOUN
eurjchem-125	181	54	position	position	NOUN
eurjchem-125	181	55	with	with	ADP
eurjchem-125	181	56	respect	respect	NOUN
eurjchem-125	181	57	to	to	ADP
eurjchem-125	181	58	methyl	methyl	NOUN
eurjchem-125	181	59	group	group	NOUN
eurjchem-125	181	60	as	as	ADP
eurjchem-125	181	61	in	in	ADP
eurjchem-125	181	62	the	the	DET
eurjchem-125	181	63	case	case	NOUN
eurjchem-125	181	64	of	of	ADP
eurjchem-125	181	65	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	181	66	.	.	PUNCT
eurjchem-125	182	1	the	the	DET
eurjchem-125	182	2	above	above	ADJ
eurjchem-125	182	3	conclusions	conclusion	NOUN
eurjchem-125	182	4	were	be	AUX
eurjchem-125	182	5	based	base	VERB
eurjchem-125	182	6	on	on	ADP
eurjchem-125	182	7	general	general	ADJ
eurjchem-125	182	8	considerations	consideration	NOUN
eurjchem-125	182	9	of	of	ADP
eurjchem-125	182	10	different	different	ADJ
eurjchem-125	182	11	factors	factor	NOUN
eurjchem-125	182	12	that	that	PRON
eurjchem-125	182	13	influence	influence	VERB
eurjchem-125	182	14	chemical	chemical	NOUN
eurjchem-125	182	15	shifts	shift	NOUN
eurjchem-125	182	16	and	and	CCONJ
eurjchem-125	182	17	coupling	couple	VERB
eurjchem-125	182	18	constants	constant	NOUN
eurjchem-125	182	19	and	and	CCONJ
eurjchem-125	182	20	were	be	AUX
eurjchem-125	182	21	made	make	VERB
eurjchem-125	182	22	by	by	ADP
eurjchem-125	182	23	comparison	comparison	NOUN
eurjchem-125	182	24	of	of	ADP
eurjchem-125	182	25	these	these	DET
eurjchem-125	182	26	nmr	nmr	NOUN
eurjchem-125	182	27	parameters	parameter	NOUN
eurjchem-125	182	28	for	for	ADP
eurjchem-125	182	29	the	the	DET
eurjchem-125	182	30	two	two	NUM
eurjchem-125	182	31	isomers	isomer	NOUN
eurjchem-125	182	32	.	.	PUNCT
eurjchem-125	183	1	to	to	PART
eurjchem-125	183	2	give	give	VERB
eurjchem-125	183	3	another	another	DET
eurjchem-125	183	4	independent	independent	ADJ
eurjchem-125	183	5	evidence	evidence	NOUN
eurjchem-125	183	6	for	for	ADP
eurjchem-125	183	7	the	the	DET
eurjchem-125	183	8	structure	structure	NOUN
eurjchem-125	183	9	of	of	ADP
eurjchem-125	183	10	the	the	DET
eurjchem-125	183	11	diastereomeric	diastereomeric	ADJ
eurjchem-125	183	12	pairs	pair	NOUN
eurjchem-125	183	13	and	and	CCONJ
eurjchem-125	183	14	to	to	PART
eurjchem-125	183	15	additionally	additionally	ADV
eurjchem-125	183	16	prove	prove	VERB
eurjchem-125	183	17	their	their	PRON
eurjchem-125	183	18	stereochemistry	stereochemistry	NOUN
eurjchem-125	183	19	we	we	PRON
eurjchem-125	183	20	measured	measure	VERB
eurjchem-125	183	21	the	the	DET
eurjchem-125	183	22	noe	noe	PROPN
eurjchem-125	183	23	enhancements	enhancement	NOUN
eurjchem-125	183	24	observed	observe	VERB
eurjchem-125	183	25	in	in	ADP
eurjchem-125	183	26	the	the	DET
eurjchem-125	183	27	noe	noe	PROPN
eurjchem-125	183	28	difference	difference	NOUN
eurjchem-125	183	29	spectra	spectra	NOUN
eurjchem-125	183	30	after	after	ADP
eurjchem-125	183	31	the	the	DET
eurjchem-125	183	32	irradiation	irradiation	NOUN
eurjchem-125	183	33	of	of	ADP
eurjchem-125	183	34	some	some	DET
eurjchem-125	183	35	key	key	ADJ
eurjchem-125	183	36	signals	signal	NOUN
eurjchem-125	183	37	.	.	PUNCT
eurjchem-125	184	1	noe	noe	PROPN
eurjchem-125	184	2	gives	give	VERB
eurjchem-125	184	3	information	information	NOUN
eurjchem-125	184	4	about	about	ADP
eurjchem-125	184	5	molecular	molecular	ADJ
eurjchem-125	184	6	fragments	fragment	NOUN
eurjchem-125	184	7	that	that	PRON
eurjchem-125	184	8	are	be	AUX
eurjchem-125	184	9	in	in	ADP
eurjchem-125	184	10	space	space	NOUN
eurjchem-125	184	11	proximity	proximity	NOUN
eurjchem-125	184	12	and	and	CCONJ
eurjchem-125	184	13	is	be	AUX
eurjchem-125	184	14	an	an	DET
eurjchem-125	184	15	effective	effective	ADJ
eurjchem-125	184	16	method	method	NOUN
eurjchem-125	184	17	to	to	PART
eurjchem-125	184	18	study	study	VERB
eurjchem-125	184	19	the	the	DET
eurjchem-125	184	20	relative	relative	ADJ
eurjchem-125	184	21	arrangement	arrangement	NOUN
eurjchem-125	184	22	of	of	ADP
eurjchem-125	184	23	different	different	ADJ
eurjchem-125	184	24	molecular	molecular	ADJ
eurjchem-125	184	25	fragments	fragment	NOUN
eurjchem-125	184	26	,	,	PUNCT
eurjchem-125	184	27	e.g.	e.g.	ADV
eurjchem-125	184	28	the	the	DET
eurjchem-125	184	29	stereochemistry	stereochemistry	NOUN
eurjchem-125	184	30	[	[	X
eurjchem-125	184	31	25	25	NUM
eurjchem-125	184	32	]	]	PUNCT
eurjchem-125	184	33	.	.	PUNCT
eurjchem-125	185	1	figure	figure	NOUN
eurjchem-125	185	2	2	2	NUM
eurjchem-125	185	3	represents	represent	VERB
eurjchem-125	185	4	the	the	DET
eurjchem-125	185	5	optimized	optimize	VERB
eurjchem-125	185	6	structures	structure	NOUN
eurjchem-125	185	7	of	of	ADP
eurjchem-125	185	8	the	the	DET
eurjchem-125	185	9	two	two	NUM
eurjchem-125	185	10	isomers	isomer	NOUN
eurjchem-125	185	11	with	with	ADP
eurjchem-125	185	12	some	some	DET
eurjchem-125	185	13	key	key	ADJ
eurjchem-125	185	14	noe	noe	PROPN
eurjchem-125	185	15	contacts	contact	NOUN
eurjchem-125	185	16	indicated	indicate	VERB
eurjchem-125	185	17	with	with	ADP
eurjchem-125	185	18	arrows	arrow	NOUN
eurjchem-125	185	19	.	.	PUNCT
eurjchem-125	186	1	for	for	ADP
eurjchem-125	186	2	all	all	DET
eurjchem-125	186	3	syn‐compounds	syn‐compound	NOUN
eurjchem-125	186	4	(	(	PUNCT
eurjchem-125	186	5	6	6	NUM
eurjchem-125	186	6	,	,	PUNCT
eurjchem-125	186	7	7a	7a	NUM
eurjchem-125	186	8	,	,	PUNCT
eurjchem-125	186	9	7b	7b	NOUN
eurjchem-125	186	10	,	,	PUNCT
eurjchem-125	186	11	7c	7c	NUM
eurjchem-125	186	12	,	,	PUNCT
eurjchem-125	186	13	7d	7d	NUM
eurjchem-125	186	14	,	,	PUNCT
eurjchem-125	186	15	7e	7e	NUM
eurjchem-125	186	16	)	)	PUNCT
eurjchem-125	186	17	the	the	DET
eurjchem-125	186	18	irradiation	irradiation	NOUN
eurjchem-125	186	19	of	of	ADP
eurjchem-125	186	20	the	the	DET
eurjchem-125	186	21	och	och	PROPN
eurjchem-125	186	22	proton	proton	NOUN
eurjchem-125	186	23	from	from	ADP
eurjchem-125	186	24	the	the	DET
eurjchem-125	186	25	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	186	26	ring	ring	NOUN
eurjchem-125	186	27	gives	give	VERB
eurjchem-125	186	28	a	a	DET
eurjchem-125	186	29	very	very	ADV
eurjchem-125	186	30	strong	strong	ADJ
eurjchem-125	186	31	noe	noe	NOUN
eurjchem-125	186	32	of	of	ADP
eurjchem-125	186	33	the	the	DET
eurjchem-125	186	34	signal	signal	NOUN
eurjchem-125	186	35	for	for	ADP
eurjchem-125	186	36	the	the	DET
eurjchem-125	186	37	ch‐4	ch‐4	NOUN
eurjchem-125	186	38	proton	proton	NOUN
eurjchem-125	186	39	from	from	ADP
eurjchem-125	186	40	the	the	DET
eurjchem-125	186	41	oxazolidinone	oxazolidinone	NOUN
eurjchem-125	186	42	ring	ring	NOUN
eurjchem-125	186	43	.	.	PUNCT
eurjchem-125	187	1	the	the	DET
eurjchem-125	187	2	irradiation	irradiation	NOUN
eurjchem-125	187	3	of	of	ADP
eurjchem-125	187	4	the	the	DET
eurjchem-125	187	5	ch3	ch3	PROPN
eurjchem-125	187	6	group	group	NOUN
eurjchem-125	187	7	leads	lead	VERB
eurjchem-125	187	8	to	to	ADP
eurjchem-125	187	9	noe	noe	PROPN
eurjchem-125	187	10	for	for	ADP
eurjchem-125	187	11	the	the	DET
eurjchem-125	187	12	ch‐4	ch‐4	PROPN
eurjchem-125	187	13	proton	proton	NOUN
eurjchem-125	187	14	attached	attach	VERB
eurjchem-125	187	15	to	to	ADP
eurjchem-125	187	16	the	the	DET
eurjchem-125	187	17	same	same	ADJ
eurjchem-125	187	18	carbon	carbon	NOUN
eurjchem-125	187	19	atom	atom	NOUN
eurjchem-125	187	20	and	and	CCONJ
eurjchem-125	187	21	for	for	ADP
eurjchem-125	187	22	one	one	NUM
eurjchem-125	187	23	of	of	ADP
eurjchem-125	187	24	the	the	DET
eurjchem-125	187	25	22	22	NUM
eurjchem-125	187	26	mavrova	mavrova	X
eurjchem-125	187	27	et	et	PROPN
eurjchem-125	187	28	al	al	PROPN
eurjchem-125	187	29	.	.	PUNCT
eurjchem-125	187	30	/	/	SYM
eurjchem-125	187	31	european	european	PROPN
eurjchem-125	187	32	journal	journal	PROPN
eurjchem-125	187	33	of	of	ADP
eurjchem-125	187	34	chemistry	chemistry	NOUN
eurjchem-125	187	35	2	2	NUM
eurjchem-125	187	36	(	(	PUNCT
eurjchem-125	187	37	1	1	NUM
eurjchem-125	187	38	)	)	PUNCT
eurjchem-125	187	39	(	(	PUNCT
eurjchem-125	187	40	2011	2011	NUM
eurjchem-125	187	41	)	)	PUNCT
eurjchem-125	187	42	18‐24	18‐24	NUM
eurjchem-125	187	43	table	table	NOUN
eurjchem-125	187	44	1	1	NUM
eurjchem-125	187	45	.	.	PUNCT
eurjchem-125	188	1	yields	yield	NOUN
eurjchem-125	188	2	and	and	CCONJ
eurjchem-125	188	3	physical	physical	ADJ
eurjchem-125	188	4	data	datum	NOUN
eurjchem-125	188	5	of	of	ADP
eurjchem-125	188	6	the	the	DET
eurjchem-125	188	7	synthesized	synthesize	VERB
eurjchem-125	188	8	compounds	compound	NOUN
eurjchem-125	188	9	.	.	PUNCT
eurjchem-125	189	1	compound	compound	NOUN
eurjchem-125	189	2	configuration	configuration	NOUN
eurjchem-125	189	3	x	x	PUNCT
eurjchem-125	189	4	yield	yield	NOUN
eurjchem-125	189	5	(	(	PUNCT
eurjchem-125	189	6	%	%	INTJ
eurjchem-125	189	7	)	)	PUNCT
eurjchem-125	190	1	m.p	m.p	PROPN
eurjchem-125	190	2	.	.	PROPN
eurjchem-125	190	3	(	(	PUNCT
eurjchem-125	190	4	°	°	ADP
eurjchem-125	190	5	c	c	NOUN
eurjchem-125	190	6	)	)	PUNCT
eurjchem-125	190	7	formula	formula	NOUN
eurjchem-125	190	8	4	4	NUM
eurjchem-125	190	9	anti	anti	NOUN
eurjchem-125	190	10	‐	‐	VERB
eurjchem-125	190	11	70.0	70.0	NUM
eurjchem-125	190	12	87‐90	87‐90	NUM
eurjchem-125	190	13	c8h9no2s	c8h9no2s	PROPN
eurjchem-125	190	14	5a	5a	NUM
eurjchem-125	190	15	anti	anti	NOUN
eurjchem-125	190	16	o	o	PROPN
eurjchem-125	190	17	62.0	62.0	NUM
eurjchem-125	190	18	166‐169	166‐169	PROPN
eurjchem-125	190	19	c13h18n2o3s	c13h18n2o3s	NUM
eurjchem-125	190	20	5b	5b	NUM
eurjchem-125	190	21	anti	anti	X
eurjchem-125	190	22	ch2	ch2	PROPN
eurjchem-125	190	23	68.0	68.0	NUM
eurjchem-125	190	24	156‐158	156‐158	NUM
eurjchem-125	190	25	c14h21cln2o2s	c14h21cln2o2s	VERB
eurjchem-125	190	26	5c	5c	NUM
eurjchem-125	190	27	anti	anti	X
eurjchem-125	190	28	n‐(4‐cl‐ph	n‐(4‐cl‐ph	PROPN
eurjchem-125	190	29	)	)	PUNCT
eurjchem-125	190	30	67.0	67.0	NUM
eurjchem-125	190	31	130‐131	130‐131	NOUN
eurjchem-125	190	32	c19h22cln3o2s	c19h22cln3o2	VERB
eurjchem-125	190	33	5d	5d	NUM
eurjchem-125	190	34	anti	anti	ADJ
eurjchem-125	190	35	n‐ch(c6h5)2	n‐ch(c6h5)2	PROPN
eurjchem-125	190	36	70.0	70.0	NUM
eurjchem-125	190	37	133‐134	133‐134	NUM
eurjchem-125	190	38	c26h29n3o2s	c26h29n3o2s	PUNCT
eurjchem-125	190	39	5e	5e	NOUN
eurjchem-125	190	40	anti	anti	X
eurjchem-125	190	41	  	  	SPACE
eurjchem-125	190	42	56.0	56.0	NUM
eurjchem-125	190	43	145‐147	145‐147	PROPN
eurjchem-125	190	44	(	(	PUNCT
eurjchem-125	190	45	decomp	decomp	NOUN
eurjchem-125	190	46	.	.	PUNCT
eurjchem-125	190	47	)	)	PUNCT
eurjchem-125	191	1	c22h28n4o4s2	c22h28n4o4s2	VERB
eurjchem-125	191	2	6	6	NUM
eurjchem-125	191	3	syn	syn	NOUN
eurjchem-125	191	4	‐	‐	VERB
eurjchem-125	191	5	65.0	65.0	NUM
eurjchem-125	191	6	101‐102	101‐102	NUM
eurjchem-125	191	7	c8h9no2s	c8h9no2s	NUM
eurjchem-125	191	8	7a	7a	NUM
eurjchem-125	191	9	syn	syn	NOUN
eurjchem-125	191	10	o	o	PROPN
eurjchem-125	191	11	64.0	64.0	NUM
eurjchem-125	191	12	83‐85	83‐85	NUM
eurjchem-125	191	13	c13h18n2o3s	c13h18n2o3s	NOUN
eurjchem-125	191	14	:	:	PUNCT
eurjchem-125	191	15	7b	7b	PROPN
eurjchem-125	191	16	syn	syn	PROPN
eurjchem-125	191	17	ch2	ch2	PROPN
eurjchem-125	191	18	68.0	68.0	NUM
eurjchem-125	191	19	181‐182	181‐182	PROPN
eurjchem-125	191	20	c14h21cln2o2s	c14h21cln2o2s	PROPN
eurjchem-125	191	21	7c	7c	PROPN
eurjchem-125	191	22	syn	syn	PROPN
eurjchem-125	191	23	n‐(4‐cl‐ph	n‐(4‐cl‐ph	PROPN
eurjchem-125	191	24	)	)	PUNCT
eurjchem-125	191	25	64.0	64.0	NUM
eurjchem-125	191	26	118‐120	118‐120	NUM
eurjchem-125	191	27	c19h22cln3o2s	c19h22cln3o2s	NOUN
eurjchem-125	191	28	7d	7d	NUM
eurjchem-125	191	29	syn	syn	PROPN
eurjchem-125	191	30	n‐ch(c6h5)2	n‐ch(c6h5)2	PROPN
eurjchem-125	191	31	65.0	65.0	NUM
eurjchem-125	191	32	163‐165	163‐165	NUM
eurjchem-125	191	33	c26h29n3o2s	c26h29n3o2s	PROPN
eurjchem-125	192	1	7e	7e	PROPN
eurjchem-125	192	2	syn	syn	PROPN
eurjchem-125	192	3	  	  	SPACE
eurjchem-125	192	4	62.0	62.0	NUM
eurjchem-125	192	5	196‐197	196‐197	NUM
eurjchem-125	192	6	(	(	PUNCT
eurjchem-125	192	7	decomp	decomp	PROPN
eurjchem-125	192	8	.	.	PUNCT
eurjchem-125	192	9	)	)	PUNCT
eurjchem-125	193	1	c22h28n4o4s2	c22h28n4o4s2	NOUN
eurjchem-125	193	2	thiophene	thiophene	NOUN
eurjchem-125	193	3	protons	proton	NOUN
eurjchem-125	193	4	,	,	PUNCT
eurjchem-125	193	5	however	however	ADV
eurjchem-125	193	6	no	no	DET
eurjchem-125	193	7	noe	noe	NOUN
eurjchem-125	193	8	is	be	AUX
eurjchem-125	193	9	observed	observe	VERB
eurjchem-125	193	10	for	for	ADP
eurjchem-125	193	11	the	the	DET
eurjchem-125	193	12	och	och	NOUN
eurjchem-125	193	13	.	.	PUNCT
eurjchem-125	194	1	these	these	DET
eurjchem-125	194	2	observations	observation	NOUN
eurjchem-125	194	3	imply	imply	VERB
eurjchem-125	194	4	that	that	SCONJ
eurjchem-125	194	5	the	the	DET
eurjchem-125	194	6	ch3	ch3	PROPN
eurjchem-125	194	7	group	group	NOUN
eurjchem-125	194	8	and	and	CCONJ
eurjchem-125	194	9	the	the	DET
eurjchem-125	194	10	thiophene	thiophene	NOUN
eurjchem-125	194	11	ring	ring	NOUN
eurjchem-125	194	12	are	be	AUX
eurjchem-125	194	13	in	in	ADP
eurjchem-125	194	14	syn‐orientation	syn‐orientation	NOUN
eurjchem-125	194	15	.	.	PUNCT
eurjchem-125	195	1	for	for	ADP
eurjchem-125	195	2	trans‐compounds	trans‐compound	NOUN
eurjchem-125	195	3	(	(	PUNCT
eurjchem-125	195	4	4	4	NUM
eurjchem-125	195	5	,	,	PUNCT
eurjchem-125	195	6	5a	5a	NUM
eurjchem-125	195	7	,	,	PUNCT
eurjchem-125	195	8	5b	5b	NUM
eurjchem-125	195	9	,	,	PUNCT
eurjchem-125	195	10	5c	5c	NUM
eurjchem-125	195	11	,	,	PUNCT
eurjchem-125	195	12	5d	5d	NUM
eurjchem-125	195	13	and	and	CCONJ
eurjchem-125	195	14	5e	5e	NUM
eurjchem-125	195	15	)	)	PUNCT
eurjchem-125	195	16	the	the	DET
eurjchem-125	195	17	irradiation	irradiation	NOUN
eurjchem-125	195	18	of	of	ADP
eurjchem-125	195	19	the	the	DET
eurjchem-125	195	20	proton	proton	NOUN
eurjchem-125	195	21	from	from	ADP
eurjchem-125	195	22	och	och	NOUN
eurjchem-125	195	23	gives	give	VERB
eurjchem-125	195	24	very	very	ADV
eurjchem-125	195	25	strong	strong	ADJ
eurjchem-125	195	26	noe	noe	NOUN
eurjchem-125	195	27	for	for	ADP
eurjchem-125	195	28	the	the	DET
eurjchem-125	195	29	signal	signal	NOUN
eurjchem-125	195	30	of	of	ADP
eurjchem-125	195	31	the	the	DET
eurjchem-125	195	32	ch3	ch3	PROPN
eurjchem-125	195	33	group	group	NOUN
eurjchem-125	195	34	,	,	PUNCT
eurjchem-125	195	35	while	while	SCONJ
eurjchem-125	195	36	no	no	DET
eurjchem-125	195	37	effect	effect	NOUN
eurjchem-125	195	38	on	on	ADP
eurjchem-125	195	39	the	the	DET
eurjchem-125	195	40	other	other	ADJ
eurjchem-125	195	41	proton	proton	NOUN
eurjchem-125	195	42	from	from	ADP
eurjchem-125	195	43	the	the	DET
eurjchem-125	195	44	oxazolidin‐2‐one	oxazolidin‐2‐one	PROPN
eurjchem-125	195	45	ring	ring	NOUN
eurjchem-125	195	46	was	be	AUX
eurjchem-125	195	47	observed	observe	VERB
eurjchem-125	195	48	.	.	PUNCT
eurjchem-125	196	1	an	an	DET
eurjchem-125	196	2	example	example	NOUN
eurjchem-125	196	3	of	of	ADP
eurjchem-125	196	4	noe	noe	PROPN
eurjchem-125	196	5	’s	’s	PART
eurjchem-125	196	6	observed	observe	VERB
eurjchem-125	196	7	for	for	ADP
eurjchem-125	196	8	compounds	compound	NOUN
eurjchem-125	196	9	5b	5b	NOUN
eurjchem-125	196	10	and	and	CCONJ
eurjchem-125	196	11	7b	7b	NOUN
eurjchem-125	196	12	is	be	AUX
eurjchem-125	196	13	presented	present	VERB
eurjchem-125	196	14	on	on	ADP
eurjchem-125	196	15	figure	figure	NOUN
eurjchem-125	196	16	3	3	NUM
eurjchem-125	196	17	.	.	PUNCT
eurjchem-125	197	1	all	all	DET
eurjchem-125	197	2	the	the	DET
eurjchem-125	197	3	noe	noe	PROPN
eurjchem-125	197	4	data	datum	NOUN
eurjchem-125	197	5	obtained	obtain	VERB
eurjchem-125	197	6	for	for	ADP
eurjchem-125	197	7	the	the	DET
eurjchem-125	197	8	compounds	compound	NOUN
eurjchem-125	197	9	are	be	AUX
eurjchem-125	197	10	included	include	VERB
eurjchem-125	197	11	in	in	ADP
eurjchem-125	197	12	tables	table	NOUN
eurjchem-125	197	13	2	2	NUM
eurjchem-125	197	14	and	and	CCONJ
eurjchem-125	197	15	3	3	NUM
eurjchem-125	197	16	.	.	X
eurjchem-125	197	17	figure	figure	NOUN
eurjchem-125	197	18	2	2	NUM
eurjchem-125	197	19	.	.	PUNCT
eurjchem-125	197	20	key	key	ADJ
eurjchem-125	197	21	noe	noe	PROPN
eurjchem-125	197	22	contacts	contact	NOUN
eurjchem-125	197	23	observed	observe	VERB
eurjchem-125	197	24	for	for	ADP
eurjchem-125	197	25	:	:	PUNCT
eurjchem-125	197	26	(	(	PUNCT
eurjchem-125	197	27	a	a	NOUN
eurjchem-125	197	28	)	)	PUNCT
eurjchem-125	197	29	syn‐compounds	syn‐compound	NOUN
eurjchem-125	197	30	and	and	CCONJ
eurjchem-125	197	31	(	(	PUNCT
eurjchem-125	197	32	b	b	X
eurjchem-125	197	33	)	)	PUNCT
eurjchem-125	197	34	anti‐	anti‐	PROPN
eurjchem-125	197	35	compounds	compound	NOUN
eurjchem-125	197	36	.	.	PUNCT
eurjchem-125	198	1	figure	figure	NOUN
eurjchem-125	198	2	3	3	NUM
eurjchem-125	198	3	.	.	PUNCT
eurjchem-125	199	1	noe	noe	PROPN
eurjchem-125	199	2	difference	difference	NOUN
eurjchem-125	199	3	spectra	spectra	NOUN
eurjchem-125	199	4	of	of	ADP
eurjchem-125	199	5	the	the	DET
eurjchem-125	199	6	two	two	NUM
eurjchem-125	199	7	isomers	isomer	NOUN
eurjchem-125	199	8	:	:	PUNCT
eurjchem-125	199	9	7	7	NUM
eurjchem-125	199	10	b	b	X
eurjchem-125	199	11	(	(	PUNCT
eurjchem-125	199	12	syn	syn	NOUN
eurjchem-125	199	13	)	)	PUNCT
eurjchem-125	199	14	and	and	CCONJ
eurjchem-125	199	15	5	5	NUM
eurjchem-125	199	16	b	b	PROPN
eurjchem-125	199	17	(	(	PUNCT
eurjchem-125	199	18	anti	anti	ADJ
eurjchem-125	199	19	):	):	PUNCT
eurjchem-125	199	20	(	(	PUNCT
eurjchem-125	199	21	a	a	X
eurjchem-125	199	22	)	)	PUNCT
eurjchem-125	199	23	irradiation	irradiation	NOUN
eurjchem-125	199	24	of	of	ADP
eurjchem-125	199	25	och	och	ADJ
eurjchem-125	199	26	proton	proton	NOUN
eurjchem-125	199	27	from	from	ADP
eurjchem-125	199	28	oxazolidinone	oxazolidinone	NUM
eurjchem-125	199	29	;	;	PUNCT
eurjchem-125	199	30	(	(	PUNCT
eurjchem-125	199	31	b	b	X
eurjchem-125	199	32	)	)	PUNCT
eurjchem-125	199	33	irradiation	irradiation	NOUN
eurjchem-125	199	34	of	of	ADP
eurjchem-125	199	35	ch3	ch3	PROPN
eurjchem-125	199	36	group	group	NOUN
eurjchem-125	199	37	in	in	ADP
eurjchem-125	199	38	position	position	NOUN
eurjchem-125	199	39	4	4	NUM
eurjchem-125	199	40	.	.	PUNCT
eurjchem-125	200	1	in	in	ADP
eurjchem-125	200	2	the	the	DET
eurjchem-125	200	3	case	case	NOUN
eurjchem-125	200	4	of	of	ADP
eurjchem-125	200	5	drug	drug	NOUN
eurjchem-125	200	6	discovery	discovery	NOUN
eurjchem-125	200	7	,	,	PUNCT
eurjchem-125	200	8	the	the	DET
eurjchem-125	200	9	likeness	likeness	NOUN
eurjchem-125	200	10	in	in	ADP
eurjchem-125	200	11	the	the	DET
eurjchem-125	200	12	structures	structure	NOUN
eurjchem-125	200	13	of	of	ADP
eurjchem-125	200	14	compounds	compound	NOUN
eurjchem-125	200	15	is	be	AUX
eurjchem-125	200	16	a	a	DET
eurjchem-125	200	17	widely	widely	ADV
eurjchem-125	200	18	used	use	VERB
eurjchem-125	200	19	approach	approach	NOUN
eurjchem-125	200	20	,	,	PUNCT
eurjchem-125	200	21	but	but	CCONJ
eurjchem-125	200	22	chemically	chemically	ADV
eurjchem-125	200	23	similar	similar	ADJ
eurjchem-125	200	24	compounds	compound	NOUN
eurjchem-125	200	25	may	may	AUX
eurjchem-125	200	26	have	have	VERB
eurjchem-125	200	27	different	different	ADJ
eurjchem-125	200	28	biological	biological	ADJ
eurjchem-125	200	29	actions	action	NOUN
eurjchem-125	200	30	and	and	CCONJ
eurjchem-125	200	31	different	different	ADJ
eurjchem-125	200	32	molecules	molecule	NOUN
eurjchem-125	200	33	can	can	AUX
eurjchem-125	200	34	have	have	VERB
eurjchem-125	200	35	similar	similar	ADJ
eurjchem-125	200	36	biological	biological	ADJ
eurjchem-125	200	37	properties	property	NOUN
eurjchem-125	200	38	[	[	X
eurjchem-125	200	39	27	27	NUM
eurjchem-125	200	40	]	]	PUNCT
eurjchem-125	200	41	.	.	PUNCT
eurjchem-125	201	1	the	the	DET
eurjchem-125	201	2	similarity	similarity	NOUN
eurjchem-125	201	3	between	between	ADP
eurjchem-125	201	4	compounds	compound	NOUN
eurjchem-125	201	5	can	can	AUX
eurjchem-125	201	6	be	be	AUX
eurjchem-125	201	7	expressed	express	VERB
eurjchem-125	201	8	as	as	ADP
eurjchem-125	201	9	a	a	DET
eurjchem-125	201	10	distance	distance	NOUN
eurjchem-125	201	11	in	in	ADP
eurjchem-125	201	12	real	real	ADJ
eurjchem-125	201	13	valued	value	VERB
eurjchem-125	201	14	descriptors	descriptor	NOUN
eurjchem-125	201	15	such	such	ADJ
eurjchem-125	201	16	as	as	ADP
eurjchem-125	201	17	topological	topological	ADJ
eurjchem-125	201	18	,	,	PUNCT
eurjchem-125	201	19	physicochemical	physicochemical	ADJ
eurjchem-125	201	20	or	or	CCONJ
eurjchem-125	201	21	quantum	quantum	ADJ
eurjchem-125	201	22	chemical	chemical	NOUN
eurjchem-125	201	23	ones	one	NOUN
eurjchem-125	201	24	[	[	X
eurjchem-125	201	25	28	28	NUM
eurjchem-125	201	26	]	]	PUNCT
eurjchem-125	201	27	.	.	PUNCT
eurjchem-125	202	1	the	the	DET
eurjchem-125	202	2	distance	distance	NOUN
eurjchem-125	202	3	between	between	ADP
eurjchem-125	202	4	two	two	NUM
eurjchem-125	202	5	points	point	NOUN
eurjchem-125	202	6	can	can	AUX
eurjchem-125	202	7	be	be	AUX
eurjchem-125	202	8	a	a	DET
eurjchem-125	202	9	measure	measure	NOUN
eurjchem-125	202	10	for	for	ADP
eurjchem-125	202	11	the	the	DET
eurjchem-125	202	12	similarity	similarity	NOUN
eurjchem-125	202	13	between	between	ADP
eurjchem-125	202	14	two	two	NUM
eurjchem-125	202	15	compounds	compound	NOUN
eurjchem-125	202	16	.	.	PUNCT
eurjchem-125	203	1	therefore	therefore	ADV
eurjchem-125	203	2	the	the	DET
eurjchem-125	203	3	distance	distance	NOUN
eurjchem-125	203	4	di	di	NOUN
eurjchem-125	203	5	of	of	ADP
eurjchem-125	203	6	a	a	DET
eurjchem-125	203	7	particular	particular	ADJ
eurjchem-125	203	8	compound	compound	NOUN
eurjchem-125	203	9	“	"	PUNCT
eurjchem-125	203	10	i	i	NOUN
eurjchem-125	203	11	”	"	PUNCT
eurjchem-125	203	12	to	to	ADP
eurjchem-125	203	13	the	the	DET
eurjchem-125	203	14	model	model	NOUN
eurjchem-125	203	15	compound	compound	VERB
eurjchem-125	203	16	a	a	PRON
eurjchem-125	203	17	respectively	respectively	ADV
eurjchem-125	203	18	to	to	ADP
eurjchem-125	203	19	b	b	NOUN
eurjchem-125	203	20	(	(	PUNCT
eurjchem-125	203	21	figure	figure	NOUN
eurjchem-125	203	22	4	4	NUM
eurjchem-125	203	23	)	)	PUNCT
eurjchem-125	203	24	could	could	AUX
eurjchem-125	203	25	be	be	AUX
eurjchem-125	203	26	calculated	calculate	VERB
eurjchem-125	203	27	according	accord	VERB
eurjchem-125	203	28	to	to	ADP
eurjchem-125	203	29	equation	equation	NOUN
eurjchem-125	203	30	1	1	NUM
eurjchem-125	203	31	as	as	SCONJ
eurjchem-125	203	32	described	describe	VERB
eurjchem-125	203	33	in	in	ADP
eurjchem-125	203	34	[	[	X
eurjchem-125	203	35	29	29	NUM
eurjchem-125	203	36	]	]	SYM
eurjchem-125	203	37	:	:	PUNCT
eurjchem-125	204	1	d	d	X
eurjchem-125	204	2	i	i	NOUN
eurjchem-125	204	3	2	2	NUM
eurjchem-125	204	4	=	=	SYM
eurjchem-125	204	5	xi	xi	PROPN
eurjchem-125	204	6	,	,	PUNCT
eurjchem-125	204	7	j	j	PROPN
eurjchem-125	204	8	xi	xi	PROPN
eurjchem-125	204	9	,	,	PUNCT
eurjchem-125	204	10	m	m	VERB
eurjchem-125	204	11			ADJ
eurjchem-125	204	12	j=1	j=1	NOUN
eurjchem-125	204	13	1	1	NUM
eurjchem-125	204	14	n	n	NUM
eurjchem-125	204	15	n	n	ADV
eurjchem-125	204	16	2	2	NUM
eurjchem-125	204	17	(	(	PUNCT
eurjchem-125	204	18	1	1	NUM
eurjchem-125	204	19	)	)	PUNCT
eurjchem-125	204	20	where	where	SCONJ
eurjchem-125	204	21	xi	xi	PROPN
eurjchem-125	204	22	,	,	PUNCT
eurjchem-125	204	23	j	j	PROPN
eurjchem-125	204	24	is	be	AUX
eurjchem-125	204	25	the	the	DET
eurjchem-125	204	26	value	value	NOUN
eurjchem-125	204	27	of	of	ADP
eurjchem-125	204	28	molecular	molecular	ADJ
eurjchem-125	204	29	descriptor	descriptor	NOUN
eurjchem-125	204	30	“	"	PUNCT
eurjchem-125	204	31	i	i	PROPN
eurjchem-125	204	32	”	"	PUNCT
eurjchem-125	204	33	for	for	ADP
eurjchem-125	204	34	compound	compound	NOUN
eurjchem-125	204	35	“	"	PUNCT
eurjchem-125	204	36	j	j	NOUN
eurjchem-125	204	37	”	"	PUNCT
eurjchem-125	204	38	,	,	PUNCT
eurjchem-125	204	39	xi	xi	PROPN
eurjchem-125	204	40	,	,	PUNCT
eurjchem-125	204	41	m	m	VERB
eurjchem-125	204	42	is	be	AUX
eurjchem-125	204	43	the	the	DET
eurjchem-125	204	44	value	value	NOUN
eurjchem-125	204	45	of	of	ADP
eurjchem-125	204	46	the	the	DET
eurjchem-125	204	47	equivalent	equivalent	ADJ
eurjchem-125	204	48	descriptor	descriptor	NOUN
eurjchem-125	204	49	“	"	PUNCT
eurjchem-125	204	50	i	i	PROPN
eurjchem-125	204	51	”	"	PUNCT
eurjchem-125	204	52	for	for	ADP
eurjchem-125	204	53	the	the	DET
eurjchem-125	204	54	model	model	NOUN
eurjchem-125	204	55	compound	compound	VERB
eurjchem-125	204	56	a	a	PRON
eurjchem-125	204	57	respectively	respectively	ADV
eurjchem-125	204	58	for	for	ADP
eurjchem-125	204	59	b	b	NOUN
eurjchem-125	204	60	and	and	CCONJ
eurjchem-125	204	61	“	"	PUNCT
eurjchem-125	204	62	n	n	CCONJ
eurjchem-125	204	63	”	"	PUNCT
eurjchem-125	204	64	is	be	AUX
eurjchem-125	204	65	the	the	DET
eurjchem-125	204	66	total	total	ADJ
eurjchem-125	204	67	number	number	NOUN
eurjchem-125	204	68	of	of	ADP
eurjchem-125	204	69	the	the	DET
eurjchem-125	204	70	considered	consider	VERB
eurjchem-125	204	71	molecular	molecular	ADJ
eurjchem-125	204	72	parameters	parameter	NOUN
eurjchem-125	204	73	.	.	PUNCT
eurjchem-125	205	1	then	then	ADV
eurjchem-125	205	2	the	the	DET
eurjchem-125	205	3	similarity	similarity	NOUN
eurjchem-125	205	4	of	of	ADP
eurjchem-125	205	5	compound	compound	NOUN
eurjchem-125	205	6	“	"	PUNCT
eurjchem-125	205	7	j	j	NOUN
eurjchem-125	205	8	”	"	PUNCT
eurjchem-125	205	9	to	to	ADP
eurjchem-125	205	10	the	the	DET
eurjchem-125	205	11	refer	refer	NOUN
eurjchem-125	205	12	compound	compound	NOUN
eurjchem-125	205	13	a	a	DET
eurjchem-125	205	14	(	(	PUNCT
eurjchem-125	205	15	b	b	NOUN
eurjchem-125	205	16	)	)	PUNCT
eurjchem-125	205	17	is	be	AUX
eurjchem-125	205	18	to	to	PART
eurjchem-125	205	19	be	be	AUX
eurjchem-125	205	20	calculated	calculate	VERB
eurjchem-125	205	21	according	accord	VERB
eurjchem-125	205	22	to	to	ADP
eurjchem-125	205	23	equation	equation	NOUN
eurjchem-125	205	24	2	2	NUM
eurjchem-125	205	25	:	:	PUNCT
eurjchem-125	205	26	similarity	similarity	NOUN
eurjchem-125	205	27	(	(	PUNCT
eurjchem-125	205	28	%	%	INTJ
eurjchem-125	205	29	)	)	PUNCT
eurjchem-125	205	30	=	=	SYM
eurjchem-125	205	31	(	(	PUNCT
eurjchem-125	205	32	1‐r	1‐r	NOUN
eurjchem-125	205	33	)	)	PUNCT
eurjchem-125	205	34	×	×	NOUN
eurjchem-125	205	35	100	100	NUM
eurjchem-125	205	36	(	(	PUNCT
eurjchem-125	205	37	2	2	NUM
eurjchem-125	205	38	)	)	PUNCT
eurjchem-125	205	39	where	where	SCONJ
eurjchem-125	205	40	r	r	NOUN
eurjchem-125	205	41	=	=	PUNCT
eurjchem-125	206	1	√	√	PROPN
eurjchem-125	206	2	d	d	SYM
eurjchem-125	206	3	2	2	NUM
eurjchem-125	206	4	is	be	AUX
eurjchem-125	206	5	the	the	DET
eurjchem-125	206	6	quadratic	quadratic	ADJ
eurjchem-125	206	7	mean	mean	NOUN
eurjchem-125	206	8	and	and	CCONJ
eurjchem-125	206	9	is	be	AUX
eurjchem-125	206	10	a	a	DET
eurjchem-125	206	11	measure	measure	NOUN
eurjchem-125	206	12	of	of	ADP
eurjchem-125	206	13	a	a	DET
eurjchem-125	206	14	central	central	ADJ
eurjchem-125	206	15	tendency	tendency	NOUN
eurjchem-125	206	16	.	.	PUNCT
eurjchem-125	207	1	figure	figure	NOUN
eurjchem-125	207	2	4	4	NUM
eurjchem-125	207	3	.	.	PUNCT
eurjchem-125	208	1	reference	reference	NOUN
eurjchem-125	208	2	compounds	compound	VERB
eurjchem-125	208	3	a	a	PRON
eurjchem-125	208	4	and	and	CCONJ
eurjchem-125	208	5	b.	b.	PROPN
eurjchem-125	208	6	the	the	DET
eurjchem-125	208	7	model	model	NOUN
eurjchem-125	208	8	compounds	compound	VERB
eurjchem-125	208	9	a	a	PRON
eurjchem-125	208	10	and	and	CCONJ
eurjchem-125	208	11	b	b	NOUN
eurjchem-125	208	12	were	be	AUX
eurjchem-125	208	13	found	find	VERB
eurjchem-125	208	14	to	to	PART
eurjchem-125	208	15	possess	possess	VERB
eurjchem-125	208	16	analgesic	analgesic	ADJ
eurjchem-125	208	17	activity	activity	NOUN
eurjchem-125	208	18	against	against	ADP
eurjchem-125	208	19	acetic	acetic	ADJ
eurjchem-125	208	20	acid‐induced	acid‐induce	VERB
eurjchem-125	208	21	pain	pain	NOUN
eurjchem-125	208	22	.	.	PUNCT
eurjchem-125	209	1	compound	compound	VERB
eurjchem-125	209	2	a	a	DET
eurjchem-125	209	3	revealed	reveal	VERB
eurjchem-125	209	4	96	96	NUM
eurjchem-125	209	5	%	%	NOUN
eurjchem-125	209	6	and	and	CCONJ
eurjchem-125	209	7	compound	compound	NOUN
eurjchem-125	209	8	b	b	PROPN
eurjchem-125	209	9	98	98	NUM
eurjchem-125	209	10	%	%	NOUN
eurjchem-125	209	11	activity	activity	NOUN
eurjchem-125	209	12	,	,	PUNCT
eurjchem-125	209	13	but	but	CCONJ
eurjchem-125	209	14	their	their	PRON
eurjchem-125	209	15	ld50	ld50	PROPN
eurjchem-125	209	16	values	value	NOUN
eurjchem-125	209	17	were	be	AUX
eurjchem-125	209	18	quite	quite	ADV
eurjchem-125	209	19	different	different	ADJ
eurjchem-125	209	20	‐	‐	ADV
eurjchem-125	209	21	800	800	NUM
eurjchem-125	209	22	mg	mg	NUM
eurjchem-125	209	23	/	/	SYM
eurjchem-125	209	24	kg	kg	PROPN
eurjchem-125	209	25	and	and	CCONJ
eurjchem-125	209	26	2000	2000	NUM
eurjchem-125	209	27	mg	mg	PROPN
eurjchem-125	209	28	/	/	SYM
eurjchem-125	209	29	kg	kg	PROPN
eurjchem-125	209	30	,	,	PUNCT
eurjchem-125	209	31	respectively	respectively	ADV
eurjchem-125	209	32	[	[	X
eurjchem-125	209	33	16	16	NUM
eurjchem-125	209	34	]	]	PUNCT
eurjchem-125	209	35	.	.	PUNCT
eurjchem-125	210	1	therefore	therefore	ADV
eurjchem-125	210	2	it	it	PRON
eurjchem-125	210	3	is	be	AUX
eurjchem-125	210	4	of	of	ADP
eurjchem-125	210	5	interest	interest	NOUN
eurjchem-125	210	6	to	to	PART
eurjchem-125	210	7	determine	determine	VERB
eurjchem-125	210	8	the	the	DET
eurjchem-125	210	9	similarity	similarity	NOUN
eurjchem-125	210	10	between	between	ADP
eurjchem-125	210	11	the	the	DET
eurjchem-125	210	12	model	model	NOUN
eurjchem-125	210	13	compounds	compound	NOUN
eurjchem-125	210	14	and	and	CCONJ
eurjchem-125	210	15	the	the	DET
eurjchem-125	210	16	newly	newly	ADV
eurjchem-125	210	17	synthesized	synthesize	VERB
eurjchem-125	210	18	,	,	PUNCT
eurjchem-125	210	19	and	and	CCONJ
eurjchem-125	210	20	to	to	PART
eurjchem-125	210	21	compare	compare	VERB
eurjchem-125	210	22	their	their	PRON
eurjchem-125	210	23	steric	steric	ADJ
eurjchem-125	210	24	,	,	PUNCT
eurjchem-125	210	25	electronic	electronic	ADJ
eurjchem-125	210	26	and	and	CCONJ
eurjchem-125	210	27	physicochemical	physicochemical	ADJ
eurjchem-125	210	28	properties	property	NOUN
eurjchem-125	210	29	.	.	PUNCT
eurjchem-125	211	1	mavrova	mavrova	PROPN
eurjchem-125	211	2	et	et	PROPN
eurjchem-125	211	3	al	al	PROPN
eurjchem-125	211	4	.	.	PUNCT
eurjchem-125	211	5	/	/	SYM
eurjchem-125	211	6	european	european	PROPN
eurjchem-125	211	7	journal	journal	PROPN
eurjchem-125	211	8	of	of	ADP
eurjchem-125	211	9	chemistry	chemistry	NOUN
eurjchem-125	211	10	2	2	NUM
eurjchem-125	211	11	(	(	PUNCT
eurjchem-125	211	12	1	1	NUM
eurjchem-125	211	13	)	)	PUNCT
eurjchem-125	211	14	(	(	PUNCT
eurjchem-125	211	15	2011	2011	NUM
eurjchem-125	211	16	)	)	PUNCT
eurjchem-125	211	17	18‐24	18‐24	NOUN
eurjchem-125	211	18	23	23	NUM
eurjchem-125	211	19	table	table	NOUN
eurjchem-125	211	20	2	2	NUM
eurjchem-125	211	21	.	.	X
eurjchem-125	211	22	noe	noe	PROPN
eurjchem-125	211	23	data	datum	NOUN
eurjchem-125	211	24	(	(	PUNCT
eurjchem-125	211	25	%	%	INTJ
eurjchem-125	211	26	)	)	PUNCT
eurjchem-125	211	27	for	for	ADP
eurjchem-125	211	28	compounds	compound	NOUN
eurjchem-125	211	29	6	6	NUM
eurjchem-125	211	30	and	and	CCONJ
eurjchem-125	211	31	7a‐e	7a‐e	PROPN
eurjchem-125	211	32	.	.	PUNCT
eurjchem-125	212	1	irradiated	irradiate	VERB
eurjchem-125	212	2	signal	signal	NOUN
eurjchem-125	212	3	noe	noe	PROPN
eurjchem-125	212	4	%	%	NOUN
eurjchem-125	212	5	compound	compound	NOUN
eurjchem-125	212	6	6	6	NUM
eurjchem-125	212	7	7a	7a	NUM
eurjchem-125	212	8	7b	7b	NOUN
eurjchem-125	212	9	7c	7c	NOUN
eurjchem-125	212	10	7d	7d	PROPN
eurjchem-125	212	11	7e	7e	PROPN
eurjchem-125	212	12	och	och	NOUN
eurjchem-125	212	13	4.8	4.8	NUM
eurjchem-125	212	14	–	–	PUNCT
eurjchem-125	212	15	nch	nch	NOUN
eurjchem-125	212	16	3.3	3.3	NUM
eurjchem-125	212	17	–	–	PUNCT
eurjchem-125	212	18	th	th	NUM
eurjchem-125	212	19	6.2	6.2	NUM
eurjchem-125	212	20	–	–	PUNCT
eurjchem-125	212	21	nch	nch	NOUN
eurjchem-125	212	22	7.3	7.3	NUM
eurjchem-125	212	23	–	–	PUNCT
eurjchem-125	212	24	th	th	NUM
eurjchem-125	212	25	13	13	NUM
eurjchem-125	212	26	–	–	PUNCT
eurjchem-125	212	27	nch	nch	NOUN
eurjchem-125	212	28	4.5	4.5	NUM
eurjchem-125	212	29	–	–	PUNCT
eurjchem-125	212	30	th	th	SYM
eurjchem-125	212	31	8.7	8.7	NUM
eurjchem-125	212	32	–	–	PUNCT
eurjchem-125	212	33	nch	nch	NOUN
eurjchem-125	212	34	6.7	6.7	NUM
eurjchem-125	212	35	–	–	PUNCT
eurjchem-125	212	36	th	th	NUM
eurjchem-125	212	37	9.6	9.6	NUM
eurjchem-125	212	38	–	–	PUNCT
eurjchem-125	212	39	nch	nch	NOUN
eurjchem-125	212	40	4.5	4.5	NUM
eurjchem-125	212	41	–	–	PUNCT
eurjchem-125	212	42	th	th	NUM
eurjchem-125	212	43	9.4	9.4	NUM
eurjchem-125	212	44	–	–	PUNCT
eurjchem-125	212	45	nch	nch	PROPN
eurjchem-125	212	46	ch3	ch3	PROPN
eurjchem-125	212	47	3.2	3.2	NUM
eurjchem-125	212	48	–	–	PUNCT
eurjchem-125	212	49	nch	nch	NOUN
eurjchem-125	212	50	2.5	2.5	NUM
eurjchem-125	212	51	–	–	PUNCT
eurjchem-125	212	52	nch	nch	NOUN
eurjchem-125	212	53	3.7	3.7	NUM
eurjchem-125	212	54	–	–	PUNCT
eurjchem-125	212	55	nch	nch	PROPN
eurjchem-125	212	56	n.a	n.a	PROPN
eurjchem-125	212	57	.	.	PROPN
eurjchem-125	212	58	n.a	n.a	PROPN
eurjchem-125	212	59	.	.	PROPN
eurjchem-125	212	60	1.5	1.5	NUM
eurjchem-125	212	61	–	–	PUNCT
eurjchem-125	212	62	th	th	SYM
eurjchem-125	212	63	4.2	4.2	NUM
eurjchem-125	212	64	–	–	PUNCT
eurjchem-125	212	65	nch	nch	PROPN
eurjchem-125	212	66	n.a	n.a	PROPN
eurjchem-125	212	67	.	.	PROPN
eurjchem-125	212	68	:	:	PUNCT
eurjchem-125	212	69	not	not	PART
eurjchem-125	212	70	available	available	ADJ
eurjchem-125	212	71	table	table	NOUN
eurjchem-125	212	72	3	3	NUM
eurjchem-125	212	73	.	.	PUNCT
eurjchem-125	212	74	noe	noe	PROPN
eurjchem-125	212	75	data	datum	NOUN
eurjchem-125	212	76	(	(	PUNCT
eurjchem-125	212	77	%	%	INTJ
eurjchem-125	212	78	)	)	PUNCT
eurjchem-125	212	79	for	for	ADP
eurjchem-125	212	80	compounds	compound	NOUN
eurjchem-125	212	81	4	4	NUM
eurjchem-125	212	82	and	and	CCONJ
eurjchem-125	212	83	5a‐e	5a‐e	PROPN
eurjchem-125	212	84	.	.	PUNCT
eurjchem-125	213	1	irradiated	irradiate	VERB
eurjchem-125	213	2	signal	signal	NOUN
eurjchem-125	213	3	noe	noe	PROPN
eurjchem-125	213	4	%	%	NOUN
eurjchem-125	213	5	compound	compound	NOUN
eurjchem-125	213	6	4	4	NUM
eurjchem-125	213	7	5a	5a	NUM
eurjchem-125	213	8	5b	5b	NUM
eurjchem-125	213	9	5c	5c	NUM
eurjchem-125	213	10	5d	5d	NUM
eurjchem-125	213	11	5e	5e	NOUN
eurjchem-125	213	12	och	och	NUM
eurjchem-125	213	13	3.3	3.3	NUM
eurjchem-125	213	14	–	–	PUNCT
eurjchem-125	213	15	ch3	ch3	PROPN
eurjchem-125	213	16	3.6	3.6	NUM
eurjchem-125	213	17	–	–	PUNCT
eurjchem-125	213	18	ch3	ch3	PROPN
eurjchem-125	213	19	4.4	4.4	NUM
eurjchem-125	213	20	–	–	PUNCT
eurjchem-125	213	21	ch3	ch3	PROPN
eurjchem-125	213	22	3.5	3.5	NUM
eurjchem-125	213	23	–	–	PUNCT
eurjchem-125	213	24	ch3	ch3	PROPN
eurjchem-125	213	25	3.2	3.2	NUM
eurjchem-125	213	26	–	–	PUNCT
eurjchem-125	213	27	ch3	ch3	PROPN
eurjchem-125	213	28	3.3	3.3	NUM
eurjchem-125	213	29	–	–	PUNCT
eurjchem-125	213	30	th	th	X
eurjchem-125	213	31	3.9	3.9	NUM
eurjchem-125	213	32	–	–	PUNCT
eurjchem-125	213	33	ch3	ch3	PROPN
eurjchem-125	213	34	for	for	ADP
eurjchem-125	213	35	the	the	DET
eurjchem-125	213	36	assessment	assessment	NOUN
eurjchem-125	213	37	of	of	ADP
eurjchem-125	213	38	the	the	DET
eurjchem-125	213	39	similarity	similarity	NOUN
eurjchem-125	213	40	between	between	ADP
eurjchem-125	213	41	the	the	DET
eurjchem-125	213	42	synthesized	synthesize	VERB
eurjchem-125	213	43	compounds	compound	NOUN
eurjchem-125	213	44	and	and	CCONJ
eurjchem-125	213	45	reference	reference	NOUN
eurjchem-125	213	46	compounds	compound	VERB
eurjchem-125	213	47	a	a	PRON
eurjchem-125	213	48	and	and	CCONJ
eurjchem-125	213	49	b	b	NOUN
eurjchem-125	213	50	,	,	PUNCT
eurjchem-125	213	51	we	we	PRON
eurjchem-125	213	52	used	use	VERB
eurjchem-125	213	53	4	4	NUM
eurjchem-125	213	54	steric	steric	ADJ
eurjchem-125	213	55	molecular	molecular	ADJ
eurjchem-125	213	56	surface	surface	NOUN
eurjchem-125	213	57	descriptors	descriptor	NOUN
eurjchem-125	213	58	,	,	PUNCT
eurjchem-125	213	59	6	6	NUM
eurjchem-125	213	60	electronic	electronic	ADJ
eurjchem-125	213	61	and	and	CCONJ
eurjchem-125	213	62	3	3	NUM
eurjchem-125	213	63	physicochemical	physicochemical	ADJ
eurjchem-125	213	64	molecular	molecular	ADJ
eurjchem-125	213	65	parameters	parameter	NOUN
eurjchem-125	213	66	.	.	PUNCT
eurjchem-125	214	1	the	the	DET
eurjchem-125	214	2	steric	steric	ADJ
eurjchem-125	214	3	and	and	CCONJ
eurjchem-125	214	4	molecular	molecular	ADJ
eurjchem-125	214	5	surface	surface	NOUN
eurjchem-125	214	6	descriptors	descriptor	NOUN
eurjchem-125	214	7	are	be	AUX
eurjchem-125	214	8	as	as	SCONJ
eurjchem-125	214	9	follows	follow	VERB
eurjchem-125	214	10	:	:	PUNCT
eurjchem-125	214	11	clsc‐(cluster	clsc‐(cluster	NOUN
eurjchem-125	214	12	count)‐topology	count)‐topology	NOUN
eurjchem-125	214	13	indice	indice	NOUN
eurjchem-125	214	14	;	;	PUNCT
eurjchem-125	214	15	‐	‐	ADJ
eurjchem-125	214	16	sas	sas	PROPN
eurjchem-125	214	17	(	(	PUNCT
eurjchem-125	214	18	connolly	connolly	PROPN
eurjchem-125	214	19	solvent	solvent	PROPN
eurjchem-125	214	20	accessible	accessible	ADJ
eurjchem-125	214	21	surface	surface	NOUN
eurjchem-125	214	22	area	area	NOUN
eurjchem-125	214	23	)	)	PUNCT
eurjchem-125	214	24	‐	‐	NOUN
eurjchem-125	214	25	å2	å2	PROPN
eurjchem-125	214	26	,	,	PUNCT
eurjchem-125	214	27	the	the	DET
eurjchem-125	214	28	focus	focus	NOUN
eurjchem-125	214	29	of	of	ADP
eurjchem-125	214	30	the	the	DET
eurjchem-125	214	31	center	center	NOUN
eurjchem-125	214	32	of	of	ADP
eurjchem-125	214	33	a	a	DET
eurjchem-125	214	34	spherical	spherical	ADJ
eurjchem-125	214	35	probe	probe	NOUN
eurjchem-125	214	36	(	(	PUNCT
eurjchem-125	214	37	representing	represent	VERB
eurjchem-125	214	38	the	the	DET
eurjchem-125	214	39	solvent	solvent	NOUN
eurjchem-125	214	40	)	)	PUNCT
eurjchem-125	214	41	as	as	SCONJ
eurjchem-125	214	42	it	it	PRON
eurjchem-125	214	43	is	be	AUX
eurjchem-125	214	44	rolled	roll	VERB
eurjchem-125	214	45	over	over	ADP
eurjchem-125	214	46	the	the	DET
eurjchem-125	214	47	molecular	molecular	ADJ
eurjchem-125	214	48	model	model	NOUN
eurjchem-125	214	49	;	;	PUNCT
eurjchem-125	214	50	‐	‐	PROPN
eurjchem-125	214	51	ms	ms	PROPN
eurjchem-125	214	52	(	(	PUNCT
eurjchem-125	214	53	connolly	connolly	ADV
eurjchem-125	214	54	molecular	molecular	ADJ
eurjchem-125	214	55	surface	surface	NOUN
eurjchem-125	214	56	area	area	NOUN
eurjchem-125	214	57	)	)	PUNCT
eurjchem-125	214	58	‐	‐	NOUN
eurjchem-125	214	59	å2	å2	PROPN
eurjchem-125	214	60	,	,	PUNCT
eurjchem-125	214	61	the	the	DET
eurjchem-125	214	62	contact	contact	NOUN
eurjchem-125	214	63	surface	surface	NOUN
eurjchem-125	214	64	created	create	VERB
eurjchem-125	214	65	when	when	SCONJ
eurjchem-125	214	66	a	a	DET
eurjchem-125	214	67	sphere	sphere	NOUN
eurjchem-125	214	68	(	(	PUNCT
eurjchem-125	214	69	representing	represent	VERB
eurjchem-125	214	70	the	the	DET
eurjchem-125	214	71	solvent	solvent	NOUN
eurjchem-125	214	72	)	)	PUNCT
eurjchem-125	214	73	is	be	AUX
eurjchem-125	214	74	rolled	roll	VERB
eurjchem-125	214	75	over	over	ADP
eurjchem-125	214	76	the	the	DET
eurjchem-125	214	77	molecular	molecular	ADJ
eurjchem-125	214	78	model	model	NOUN
eurjchem-125	214	79	;	;	PUNCT
eurjchem-125	214	80	‐	‐	ADJ
eurjchem-125	214	81	sev	sev	NOUN
eurjchem-125	214	82	(	(	PUNCT
eurjchem-125	214	83	connolly	connolly	ADV
eurjchem-125	214	84	solvent‐excluded	solvent‐exclude	VERB
eurjchem-125	214	85	volume	volume	NOUN
eurjchem-125	214	86	)	)	PUNCT
eurjchem-125	214	87	‐	‐	ADP
eurjchem-125	214	88	å	å	PROPN
eurjchem-125	214	89	3	3	NUM
eurjchem-125	214	90	,	,	PUNCT
eurjchem-125	214	91	the	the	DET
eurjchem-125	214	92	volume	volume	NOUN
eurjchem-125	214	93	contained	contain	VERB
eurjchem-125	214	94	within	within	ADP
eurjchem-125	214	95	the	the	DET
eurjchem-125	214	96	contact	contact	NOUN
eurjchem-125	214	97	molecular	molecular	ADJ
eurjchem-125	214	98	surface	surface	NOUN
eurjchem-125	214	99	created	create	VERB
eurjchem-125	214	100	when	when	SCONJ
eurjchem-125	214	101	a	a	DET
eurjchem-125	214	102	sphere	sphere	NOUN
eurjchem-125	214	103	(	(	PUNCT
eurjchem-125	214	104	representing	represent	VERB
eurjchem-125	214	105	the	the	DET
eurjchem-125	214	106	solvent	solvent	NOUN
eurjchem-125	214	107	)	)	PUNCT
eurjchem-125	214	108	is	be	AUX
eurjchem-125	214	109	rolled	roll	VERB
eurjchem-125	214	110	over	over	ADP
eurjchem-125	214	111	the	the	DET
eurjchem-125	214	112	molecular	molecular	ADJ
eurjchem-125	214	113	model	model	NOUN
eurjchem-125	214	114	.	.	PUNCT
eurjchem-125	215	1	the	the	DET
eurjchem-125	215	2	followed	follow	VERB
eurjchem-125	215	3	global	global	ADJ
eurjchem-125	215	4	physicochemical	physicochemical	ADJ
eurjchem-125	215	5	parameters	parameter	NOUN
eurjchem-125	215	6	were	be	AUX
eurjchem-125	215	7	calculated	calculate	VERB
eurjchem-125	215	8	:	:	PUNCT
eurjchem-125	215	9	‐	‐	NUM
eurjchem-125	215	10	log	log	NOUN
eurjchem-125	215	11	p	p	NOUN
eurjchem-125	215	12	(	(	PUNCT
eurjchem-125	215	13	hydrophobic	hydrophobic	NOUN
eurjchem-125	215	14	parameter	parameter	NOUN
eurjchem-125	215	15	‐	‐	VERB
eurjchem-125	215	16	octanol‐water	octanol‐water	ADP
eurjchem-125	215	17	partition	partition	NOUN
eurjchem-125	215	18	coefficient	coefficient	NOUN
eurjchem-125	215	19	)	)	PUNCT
eurjchem-125	215	20	;	;	PUNCT
eurjchem-125	215	21	‐	‐	PROPN
eurjchem-125	215	22	mr	mr	PROPN
eurjchem-125	215	23	(	(	PUNCT
eurjchem-125	215	24	molar	molar	ADJ
eurjchem-125	215	25	refractivity	refractivity	NOUN
eurjchem-125	215	26	)	)	PUNCT
eurjchem-125	215	27	‐	‐	ADP
eurjchem-125	215	28	kcal	kcal	PROPN
eurjchem-125	215	29	/	/	SYM
eurjchem-125	215	30	mol	mol	PROPN
eurjchem-125	215	31	;	;	PUNCT
eurjchem-125	215	32	‐	‐	ADJ
eurjchem-125	215	33	e	e	NOUN
eurjchem-125	215	34	(	(	PUNCT
eurjchem-125	215	35	total	total	ADJ
eurjchem-125	215	36	energy	energy	NOUN
eurjchem-125	215	37	)	)	PUNCT
eurjchem-125	215	38	‐	‐	ADP
eurjchem-125	215	39	kcal	kcal	PROPN
eurjchem-125	215	40	/	/	SYM
eurjchem-125	215	41	mol	mol	PROPN
eurjchem-125	215	42	.	.	PUNCT
eurjchem-125	216	1	the	the	DET
eurjchem-125	216	2	quantum	quantum	ADJ
eurjchem-125	216	3	chemical	chemical	NOUN
eurjchem-125	216	4	descriptors	descriptor	NOUN
eurjchem-125	216	5	used	use	VERB
eurjchem-125	216	6	by	by	ADP
eurjchem-125	216	7	determination	determination	NOUN
eurjchem-125	216	8	of	of	ADP
eurjchem-125	216	9	similarity	similarity	NOUN
eurjchem-125	216	10	were	be	AUX
eurjchem-125	216	11	:	:	PUNCT
eurjchem-125	216	12	‐	‐	NUM
eurjchem-125	216	13	homo‐energy	homo‐energy	NOUN
eurjchem-125	216	14	(	(	PUNCT
eurjchem-125	216	15	the	the	DET
eurjchem-125	216	16	highest	high	ADJ
eurjchem-125	216	17	occupied	occupy	VERB
eurjchem-125	216	18	molecular	molecular	ADJ
eurjchem-125	216	19	orbital	orbital	ADJ
eurjchem-125	216	20	energy	energy	NOUN
eurjchem-125	216	21	)	)	PUNCT
eurjchem-125	216	22	‐	‐	VERB
eurjchem-125	216	23	ev	ev	X
eurjchem-125	216	24	;	;	PUNCT
eurjchem-125	216	25	‐	‐	NUM
eurjchem-125	216	26	lumo	lumo	NOUN
eurjchem-125	216	27	‐	‐	NOUN
eurjchem-125	216	28	energy	energy	NOUN
eurjchem-125	216	29	(	(	PUNCT
eurjchem-125	216	30	the	the	DET
eurjchem-125	216	31	lowest	low	ADJ
eurjchem-125	216	32	occupied	occupy	VERB
eurjchem-125	216	33	molecular	molecular	ADJ
eurjchem-125	216	34	orbital	orbital	ADJ
eurjchem-125	216	35	energy	energy	NOUN
eurjchem-125	216	36	)	)	PUNCT
eurjchem-125	216	37	‐	‐	VERB
eurjchem-125	216	38	ev	ev	PROPN
eurjchem-125	216	39	;	;	PUNCT
eurjchem-125	216	40	‐	‐	PROPN
eurjchem-125	216	41	elce	elce	PROPN
eurjchem-125	216	42	(	(	PUNCT
eurjchem-125	216	43	electronic	electronic	ADJ
eurjchem-125	216	44	energy	energy	NOUN
eurjchem-125	216	45	)	)	PUNCT
eurjchem-125	216	46	‐	‐	VERB
eurjchem-125	216	47	ev	ev	X
eurjchem-125	216	48	;	;	PUNCT
eurjchem-125	216	49	‐	‐	ADJ
eurjchem-125	216	50	tote	tote	NOUN
eurjchem-125	216	51	(	(	PUNCT
eurjchem-125	216	52	total	total	ADJ
eurjchem-125	216	53	energy	energy	NOUN
eurjchem-125	216	54	)	)	PUNCT
eurjchem-125	216	55	‐	‐	NOUN
eurjchem-125	216	56	(	(	PUNCT
eurjchem-125	216	57	ev	ev	PROPN
eurjchem-125	216	58	)	)	PUNCT
eurjchem-125	216	59	;	;	PUNCT
eurjchem-125	216	60	‐dpl	‐dpl	NUM
eurjchem-125	216	61	(	(	PUNCT
eurjchem-125	216	62	dipole	dipole	NOUN
eurjchem-125	216	63	)	)	PUNCT
eurjchem-125	216	64	‐	‐	NOUN
eurjchem-125	216	65	(	(	PUNCT
eurjchem-125	216	66	debye	debye	ADJ
eurjchem-125	216	67	)	)	PUNCT
eurjchem-125	216	68	;	;	PUNCT
eurjchem-125	216	69	‐	‐	PROPN
eurjchem-125	216	70	nre	nre	PROPN
eurjchem-125	216	71	nucleus‐nucleus	nucleus‐nucleus	PROPN
eurjchem-125	216	72	repulse	repulse	VERB
eurjchem-125	216	73	energy	energy	NOUN
eurjchem-125	216	74	‐	‐	NOUN
eurjchem-125	216	75	(	(	PUNCT
eurjchem-125	216	76	ev	ev	PROPN
eurjchem-125	216	77	)	)	PUNCT
eurjchem-125	216	78	.	.	PUNCT
eurjchem-125	217	1	after	after	ADP
eurjchem-125	217	2	the	the	DET
eurjchem-125	217	3	computation	computation	NOUN
eurjchem-125	217	4	of	of	ADP
eurjchem-125	217	5	descriptors	descriptor	NOUN
eurjchem-125	217	6	,	,	PUNCT
eurjchem-125	217	7	it	it	PRON
eurjchem-125	217	8	was	be	AUX
eurjchem-125	217	9	established	establish	VERB
eurjchem-125	217	10	that	that	SCONJ
eurjchem-125	217	11	the	the	DET
eurjchem-125	217	12	likeness	likeness	NOUN
eurjchem-125	217	13	between	between	ADP
eurjchem-125	217	14	5d	5d	PROPN
eurjchem-125	217	15	,	,	PUNCT
eurjchem-125	217	16	respectively	respectively	ADV
eurjchem-125	217	17	,	,	PUNCT
eurjchem-125	217	18	7d	7d	NUM
eurjchem-125	217	19	and	and	CCONJ
eurjchem-125	217	20	the	the	DET
eurjchem-125	217	21	reference	reference	NOUN
eurjchem-125	217	22	compounds	compound	VERB
eurjchem-125	217	23	had	have	VERB
eurjchem-125	217	24	the	the	DET
eurjchem-125	217	25	highest	high	ADJ
eurjchem-125	217	26	value	value	NOUN
eurjchem-125	217	27	‐	‐	NOUN
eurjchem-125	217	28	90.53	90.53	NUM
eurjchem-125	217	29	and	and	CCONJ
eurjchem-125	217	30	94.53	94.53	NUM
eurjchem-125	217	31	%	%	NOUN
eurjchem-125	217	32	,	,	PUNCT
eurjchem-125	217	33	followed	follow	VERB
eurjchem-125	217	34	by	by	ADP
eurjchem-125	217	35	5e	5e	NOUN
eurjchem-125	217	36	‐	‐	VERB
eurjchem-125	217	37	80.4	80.4	NUM
eurjchem-125	217	38	and	and	CCONJ
eurjchem-125	217	39	7e	7e	NUM
eurjchem-125	217	40	86.01	86.01	NUM
eurjchem-125	217	41	as	as	ADV
eurjchem-125	217	42	well	well	ADV
eurjchem-125	217	43	as	as	ADP
eurjchem-125	217	44	by	by	ADP
eurjchem-125	217	45	5c	5c	NUM
eurjchem-125	217	46	and	and	CCONJ
eurjchem-125	217	47	7c	7c	PROPN
eurjchem-125	217	48	80.54	80.54	NUM
eurjchem-125	217	49	and	and	CCONJ
eurjchem-125	217	50	76.30	76.30	NUM
eurjchem-125	217	51	%	%	NOUN
eurjchem-125	217	52	respectively	respectively	ADV
eurjchem-125	217	53	,	,	PUNCT
eurjchem-125	217	54	as	as	SCONJ
eurjchem-125	217	55	it	it	PRON
eurjchem-125	217	56	can	can	AUX
eurjchem-125	217	57	be	be	AUX
eurjchem-125	217	58	seen	see	VERB
eurjchem-125	217	59	from	from	ADP
eurjchem-125	217	60	the	the	DET
eurjchem-125	217	61	data	datum	NOUN
eurjchem-125	217	62	given	give	VERB
eurjchem-125	217	63	in	in	ADP
eurjchem-125	217	64	table	table	NOUN
eurjchem-125	217	65	4	4	NUM
eurjchem-125	217	66	.	.	PUNCT
eurjchem-125	218	1	the	the	DET
eurjchem-125	218	2	values	value	NOUN
eurjchem-125	218	3	of	of	ADP
eurjchem-125	218	4	the	the	DET
eurjchem-125	218	5	descriptors	descriptor	NOUN
eurjchem-125	218	6	and	and	CCONJ
eurjchem-125	218	7	the	the	DET
eurjchem-125	218	8	calculation	calculation	NOUN
eurjchem-125	218	9	of	of	ADP
eurjchem-125	218	10	equation	equation	NOUN
eurjchem-125	218	11	1	1	NUM
eurjchem-125	218	12	for	for	ADP
eurjchem-125	218	13	compound	compound	NOUN
eurjchem-125	218	14	5d	5d	NUM
eurjchem-125	218	15	are	be	AUX
eurjchem-125	218	16	as	as	SCONJ
eurjchem-125	218	17	follows	follow	VERB
eurjchem-125	218	18	:	:	PUNCT
eurjchem-125	218	19	d2	d2	PROPN
eurjchem-125	218	20	=	=	PUNCT
eurjchem-125	219	1	[	[	X
eurjchem-125	219	2	(	(	PUNCT
eurjchem-125	219	3	1‐clc5d	1‐clc5d	NUM
eurjchem-125	219	4	/	/	SYM
eurjchem-125	219	5	clca	clca	NOUN
eurjchem-125	219	6	)	)	PUNCT
eurjchem-125	219	7	2	2	NUM
eurjchem-125	220	1	+	+	CCONJ
eurjchem-125	220	2	(	(	PUNCT
eurjchem-125	220	3	1	1	NUM
eurjchem-125	220	4	‐	‐	ADJ
eurjchem-125	220	5	sas	sas	VERB
eurjchem-125	220	6	5d/	5d/	PROPN
eurjchem-125	220	7	sas	sas	VERB
eurjchem-125	220	8	a	a	PRON
eurjchem-125	220	9	)	)	PUNCT
eurjchem-125	220	10	2	2	NUM
eurjchem-125	221	1	+	+	CCONJ
eurjchem-125	221	2	(	(	PUNCT
eurjchem-125	221	3	1‐	1‐	NUM
eurjchem-125	221	4	ms	ms	PROPN
eurjchem-125	221	5	5d/	5d/	NUM
eurjchem-125	221	6	ms	ms	NOUN
eurjchem-125	221	7	a	a	PRON
eurjchem-125	221	8	)	)	PUNCT
eurjchem-125	221	9	2	2	NUM
eurjchem-125	221	10	+	+	CCONJ
eurjchem-125	221	11	(	(	PUNCT
eurjchem-125	221	12	1	1	NUM
eurjchem-125	221	13	‐	‐	NOUN
eurjchem-125	221	14	sev5d/	sev5d/	PROPN
eurjchem-125	221	15	sev	sev	NOUN
eurjchem-125	221	16	a	a	PRON
eurjchem-125	221	17	)	)	PUNCT
eurjchem-125	221	18	2	2	NUM
eurjchem-125	221	19	+	+	CCONJ
eurjchem-125	221	20	(	(	PUNCT
eurjchem-125	221	21	1	1	NUM
eurjchem-125	221	22	‐	‐	ADJ
eurjchem-125	221	23	dpl	dpl	NOUN
eurjchem-125	221	24	5d/	5d/	NUM
eurjchem-125	221	25	dpl	dpl	PROPN
eurjchem-125	221	26	a	a	PRON
eurjchem-125	221	27	)	)	PUNCT
eurjchem-125	221	28	2	2	NUM
eurjchem-125	221	29	+	+	CCONJ
eurjchem-125	221	30	(	(	PUNCT
eurjchem-125	221	31	1	1	NUM
eurjchem-125	221	32	‐	‐	NOUN
eurjchem-125	221	33	elce5d	elce5d	PROPN
eurjchem-125	221	34	/	/	SYM
eurjchem-125	221	35	elce	elce	VERB
eurjchem-125	221	36	a	a	PRON
eurjchem-125	221	37	)	)	PUNCT
eurjchem-125	221	38	2	2	NUM
eurjchem-125	222	1	+	+	CCONJ
eurjchem-125	222	2	(	(	PUNCT
eurjchem-125	222	3	1‐	1‐	PROPN
eurjchem-125	222	4	homo5d	homo5d	NUM
eurjchem-125	222	5	/	/	SYM
eurjchem-125	222	6	homoa	homoa	ADJ
eurjchem-125	222	7	)	)	PUNCT
eurjchem-125	222	8	2	2	NUM
eurjchem-125	223	1	+	+	CCONJ
eurjchem-125	223	2	(	(	PUNCT
eurjchem-125	223	3	1‐	1‐	NUM
eurjchem-125	223	4	lumo5d	lumo5d	ADJ
eurjchem-125	223	5	/	/	SYM
eurjchem-125	223	6	lumoa	lumoa	NOUN
eurjchem-125	223	7	)	)	PUNCT
eurjchem-125	223	8	2	2	NUM
eurjchem-125	224	1	+	+	CCONJ
eurjchem-125	224	2	(	(	PUNCT
eurjchem-125	224	3	1	1	NUM
eurjchem-125	224	4	‐	‐	NOUN
eurjchem-125	224	5	logp5d/	logp5d/	PROPN
eurjchem-125	224	6	logp	logp	NOUN
eurjchem-125	224	7	a	a	PRON
eurjchem-125	224	8	)	)	PUNCT
eurjchem-125	224	9	2	2	NUM
eurjchem-125	225	1	+	+	CCONJ
eurjchem-125	225	2	(	(	PUNCT
eurjchem-125	225	3	1	1	NUM
eurjchem-125	225	4	‐	‐	VERB
eurjchem-125	225	5	mr5d/	mr5d/	NOUN
eurjchem-125	225	6	mr	mr	PROPN
eurjchem-125	225	7	a	a	PRON
eurjchem-125	225	8	)	)	PUNCT
eurjchem-125	225	9	2	2	NUM
eurjchem-125	225	10	+	+	CCONJ
eurjchem-125	225	11	(	(	PUNCT
eurjchem-125	225	12	1‐	1‐	X
eurjchem-125	225	13	e5d/	e5d/	ADJ
eurjchem-125	225	14	e	e	NOUN
eurjchem-125	225	15	a	a	PRON
eurjchem-125	225	16	)	)	PUNCT
eurjchem-125	225	17	2	2	NUM
eurjchem-125	226	1	+	+	CCONJ
eurjchem-125	226	2	(	(	PUNCT
eurjchem-125	226	3	1‐	1‐	NUM
eurjchem-125	226	4	nre5d/	nre5d/	PROPN
eurjchem-125	226	5	nre	nre	NOUN
eurjchem-125	226	6	a	a	PRON
eurjchem-125	226	7	)	)	PUNCT
eurjchem-125	226	8	2	2	NUM
eurjchem-125	227	1	+	+	CCONJ
eurjchem-125	227	2	(	(	PUNCT
eurjchem-125	227	3	1‐	1‐	PROPN
eurjchem-125	227	4	tote5d	tote5d	PROPN
eurjchem-125	227	5	/	/	SYM
eurjchem-125	227	6	totea	totea	ADJ
eurjchem-125	227	7	)	)	PUNCT
eurjchem-125	227	8	2]/13	2]/13	NOUN
eurjchem-125	227	9	=	=	PUNCT
eurjchem-125	228	1	[	[	X
eurjchem-125	228	2	(	(	PUNCT
eurjchem-125	228	3	1‐32/33)2	1‐32/33)2	NUM
eurjchem-125	228	4	+	+	SYM
eurjchem-125	228	5	(	(	PUNCT
eurjchem-125	228	6	1‐	1‐	PROPN
eurjchem-125	228	7	629.609/646.879)2	629.609/646.879)2	NUM
eurjchem-125	228	8	+	+	CCONJ
eurjchem-125	228	9	(	(	PUNCT
eurjchem-125	228	10	1	1	NUM
eurjchem-125	228	11	‐	‐	ADJ
eurjchem-125	228	12	410.135/425.959)2	410.135/425.959)2	NUM
eurjchem-125	228	13	+	+	CCONJ
eurjchem-125	228	14	(	(	PUNCT
eurjchem-125	228	15	1	1	NUM
eurjchem-125	228	16	‐	‐	ADP
eurjchem-125	228	17	383.254/401.380)2	383.254/401.380)2	NUM
eurjchem-125	229	1	+	+	CCONJ
eurjchem-125	229	2	(	(	PUNCT
eurjchem-125	229	3	1‐	1‐	PROPN
eurjchem-125	229	4	5.2213/4.4871)2	5.2213/4.4871)2	NUM
eurjchem-125	229	5	+	+	CCONJ
eurjchem-125	229	6	(	(	PUNCT
eurjchem-125	229	7	1	1	NUM
eurjchem-125	229	8	‐	‐	NOUN
eurjchem-125	229	9	45972.9/49035.5)2	45972.9/49035.5)2	NUM
eurjchem-125	230	1	+	+	CCONJ
eurjchem-125	230	2	(	(	PUNCT
eurjchem-125	230	3	1	1	NUM
eurjchem-125	230	4	‐	‐	NOUN
eurjchem-125	230	5	9.19889/8.99577)2	9.19889/8.99577)2	NUM
eurjchem-125	230	6	+	+	CCONJ
eurjchem-125	230	7	(	(	PUNCT
eurjchem-125	230	8	1	1	NUM
eurjchem-125	230	9	‐	‐	NOUN
eurjchem-125	230	10	0.143672/	0.143672/	PROPN
eurjchem-125	230	11	0.112407)2	0.112407)2	X
eurjchem-125	230	12	+	+	CCONJ
eurjchem-125	230	13	(	(	PUNCT
eurjchem-125	230	14	1	1	NUM
eurjchem-125	230	15	‐	‐	ADP
eurjchem-125	230	16	5.346/5.682)2	5.346/5.682)2	NUM
eurjchem-125	230	17	+	+	CCONJ
eurjchem-125	230	18	(	(	PUNCT
eurjchem-125	230	19	1	1	NUM
eurjchem-125	230	20	‐	‐	ADP
eurjchem-125	230	21	129.21/134.32)2	129.21/134.32)2	NUM
eurjchem-125	230	22	+	+	CCONJ
eurjchem-125	230	23	(	(	PUNCT
eurjchem-125	230	24	1	1	NUM
eurjchem-125	230	25	‐	‐	ADP
eurjchem-125	230	26	129.338/127.465)2	129.338/127.465)2	NUM
eurjchem-125	230	27	+	+	CCONJ
eurjchem-125	230	28	(	(	PUNCT
eurjchem-125	230	29	1	1	NUM
eurjchem-125	230	30	‐	‐	ADP
eurjchem-125	230	31	40790.9/43697.8)2	40790.9/43697.8)2	PROPN
eurjchem-125	231	1	+	+	CCONJ
eurjchem-125	231	2	(	(	PUNCT
eurjchem-125	231	3	1	1	NUM
eurjchem-125	231	4	‐	‐	ADJ
eurjchem-125	231	5	5182/5338)2]/13	5182/5338)2]/13	NUM
eurjchem-125	231	6	=	=	SYM
eurjchem-125	231	7	0.09473	0.09473	NUM
eurjchem-125	231	8	because	because	SCONJ
eurjchem-125	231	9	the	the	DET
eurjchem-125	231	10	frontier	frontier	NOUN
eurjchem-125	231	11	molecular	molecular	ADJ
eurjchem-125	231	12	orbital	orbital	NOUN
eurjchem-125	231	13	are	be	AUX
eurjchem-125	231	14	involved	involve	VERB
eurjchem-125	231	15	in	in	ADP
eurjchem-125	231	16	the	the	DET
eurjchem-125	231	17	activity	activity	NOUN
eurjchem-125	231	18	properties	property	NOUN
eurjchem-125	231	19	of	of	ADP
eurjchem-125	231	20	the	the	DET
eurjchem-125	231	21	compounds	compound	NOUN
eurjchem-125	231	22	,	,	PUNCT
eurjchem-125	231	23	the	the	DET
eurjchem-125	231	24	highest	high	ADJ
eurjchem-125	231	25	occupied	occupy	VERB
eurjchem-125	231	26	molecular	molecular	ADJ
eurjchem-125	231	27	orbital	orbital	ADJ
eurjchem-125	231	28	(	(	PUNCT
eurjchem-125	231	29	homo	homo	NOUN
eurjchem-125	231	30	)	)	PUNCT
eurjchem-125	231	31	energy	energy	NOUN
eurjchem-125	231	32	and	and	CCONJ
eurjchem-125	231	33	the	the	DET
eurjchem-125	231	34	lowest	low	ADJ
eurjchem-125	231	35	unoccupied	unoccupied	ADJ
eurjchem-125	231	36	molecular	molecular	ADJ
eurjchem-125	231	37	orbital	orbital	ADJ
eurjchem-125	231	38	(	(	PUNCT
eurjchem-125	231	39	lumo	lumo	NOUN
eurjchem-125	231	40	)	)	PUNCT
eurjchem-125	231	41	energy	energy	NOUN
eurjchem-125	231	42	is	be	AUX
eurjchem-125	231	43	discussed	discuss	VERB
eurjchem-125	231	44	.	.	PUNCT
eurjchem-125	232	1	the	the	DET
eurjchem-125	232	2	homo	homo	NOUN
eurjchem-125	232	3	energy	energy	NOUN
eurjchem-125	232	4	relates	relate	VERB
eurjchem-125	232	5	to	to	ADP
eurjchem-125	232	6	the	the	DET
eurjchem-125	232	7	ionization	ionization	NOUN
eurjchem-125	232	8	potential	potential	NOUN
eurjchem-125	232	9	and	and	CCONJ
eurjchem-125	232	10	the	the	DET
eurjchem-125	232	11	reactivity	reactivity	NOUN
eurjchem-125	232	12	of	of	ADP
eurjchem-125	232	13	a	a	DET
eurjchem-125	232	14	molecule	molecule	NOUN
eurjchem-125	232	15	as	as	ADP
eurjchem-125	232	16	a	a	DET
eurjchem-125	232	17	nucleophile	nucleophile	NOUN
eurjchem-125	232	18	.	.	PUNCT
eurjchem-125	233	1	the	the	DET
eurjchem-125	233	2	lumo	lumo	NOUN
eurjchem-125	233	3	energy	energy	NOUN
eurjchem-125	233	4	represents	represent	VERB
eurjchem-125	233	5	the	the	DET
eurjchem-125	233	6	electron	electron	NOUN
eurjchem-125	233	7	affinity	affinity	NOUN
eurjchem-125	233	8	of	of	ADP
eurjchem-125	233	9	a	a	DET
eurjchem-125	233	10	molecule	molecule	NOUN
eurjchem-125	233	11	or	or	CCONJ
eurjchem-125	233	12	its	its	PRON
eurjchem-125	233	13	reactivity	reactivity	NOUN
eurjchem-125	233	14	as	as	ADP
eurjchem-125	233	15	an	an	DET
eurjchem-125	233	16	electrophile.the	electrophile.the	PRON
eurjchem-125	233	17	performed	perform	VERB
eurjchem-125	233	18	computation	computation	NOUN
eurjchem-125	233	19	showed	show	VERB
eurjchem-125	233	20	lower	low	ADJ
eurjchem-125	233	21	electronic	electronic	ADJ
eurjchem-125	233	22	energies	energy	NOUN
eurjchem-125	233	23	(	(	PUNCT
eurjchem-125	233	24	elce	elce	PROPN
eurjchem-125	233	25	)	)	PUNCT
eurjchem-125	233	26	of	of	ADP
eurjchem-125	233	27	the	the	DET
eurjchem-125	233	28	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	233	29	in	in	ADP
eurjchem-125	233	30	comparison	comparison	NOUN
eurjchem-125	233	31	to	to	ADP
eurjchem-125	233	32	those	those	PRON
eurjchem-125	233	33	of	of	ADP
eurjchem-125	233	34	the	the	DET
eurjchem-125	233	35	syn‐diastereoisomers	syn‐diastereoisomer	NOUN
eurjchem-125	233	36	,	,	PUNCT
eurjchem-125	233	37	but	but	CCONJ
eurjchem-125	233	38	regarding	regard	VERB
eurjchem-125	233	39	to	to	ADP
eurjchem-125	233	40	the	the	DET
eurjchem-125	233	41	homo	homo	NOUN
eurjchem-125	233	42	energies	energy	NOUN
eurjchem-125	233	43	and	and	CCONJ
eurjchem-125	233	44	the	the	DET
eurjchem-125	233	45	repulse	repulse	ADJ
eurjchem-125	233	46	energies	energy	NOUN
eurjchem-125	233	47	(	(	PUNCT
eurjchem-125	233	48	nre	nre	PROPN
eurjchem-125	233	49	)	)	PUNCT
eurjchem-125	233	50	,	,	PUNCT
eurjchem-125	233	51	the	the	DET
eurjchem-125	233	52	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	233	53	possessed	possess	VERB
eurjchem-125	233	54	higher	high	ADJ
eurjchem-125	233	55	values	value	NOUN
eurjchem-125	233	56	than	than	ADP
eurjchem-125	233	57	syn‐diastereoisomers	syn‐diastereoisomer	NOUN
eurjchem-125	233	58	.	.	PUNCT
eurjchem-125	234	1	if	if	SCONJ
eurjchem-125	234	2	the	the	DET
eurjchem-125	234	3	steric	steric	ADJ
eurjchem-125	234	4	descriptors	descriptor	NOUN
eurjchem-125	234	5	are	be	AUX
eurjchem-125	234	6	taken	take	VERB
eurjchem-125	234	7	in	in	ADP
eurjchem-125	234	8	consideration	consideration	NOUN
eurjchem-125	234	9	it	it	PRON
eurjchem-125	234	10	is	be	AUX
eurjchem-125	234	11	pointed	point	VERB
eurjchem-125	234	12	out	out	ADP
eurjchem-125	234	13	that	that	SCONJ
eurjchem-125	234	14	the	the	DET
eurjchem-125	234	15	sas	sa	NOUN
eurjchem-125	234	16	and	and	CCONJ
eurjchem-125	234	17	ms	ms	ADJ
eurjchem-125	234	18	values	value	NOUN
eurjchem-125	234	19	of	of	ADP
eurjchem-125	234	20	anti‐isomers	anti‐isomer	NOUN
eurjchem-125	234	21	are	be	AUX
eurjchem-125	234	22	lower	low	ADJ
eurjchem-125	234	23	than	than	ADP
eurjchem-125	234	24	these	these	PRON
eurjchem-125	234	25	of	of	ADP
eurjchem-125	234	26	syn‐	syn‐	ADP
eurjchem-125	234	27	isomers	isomer	NOUN
eurjchem-125	234	28	.	.	PUNCT
eurjchem-125	235	1	the	the	DET
eurjchem-125	235	2	same	same	ADJ
eurjchem-125	235	3	relations	relation	NOUN
eurjchem-125	235	4	are	be	AUX
eurjchem-125	235	5	observed	observe	VERB
eurjchem-125	235	6	for	for	ADP
eurjchem-125	235	7	compound	compound	NOUN
eurjchem-125	235	8	a	a	PRON
eurjchem-125	235	9	and	and	CCONJ
eurjchem-125	235	10	compound	compound	NOUN
eurjchem-125	235	11	b.	b.	PROPN
eurjchem-125	236	1	probably	probably	ADV
eurjchem-125	236	2	,	,	PUNCT
eurjchem-125	236	3	the	the	DET
eurjchem-125	236	4	differences	difference	NOUN
eurjchem-125	236	5	in	in	ADP
eurjchem-125	236	6	the	the	DET
eurjchem-125	236	7	steric	steric	ADJ
eurjchem-125	236	8	and	and	CCONJ
eurjchem-125	236	9	electronic	electronic	ADJ
eurjchem-125	236	10	properties	property	NOUN
eurjchem-125	236	11	of	of	ADP
eurjchem-125	236	12	the	the	DET
eurjchem-125	236	13	compounds	compound	NOUN
eurjchem-125	236	14	are	be	AUX
eurjchem-125	236	15	responsible	responsible	ADJ
eurjchem-125	236	16	for	for	ADP
eurjchem-125	236	17	the	the	DET
eurjchem-125	236	18	different	different	ADJ
eurjchem-125	236	19	ld50	ld50	PROPN
eurjchem-125	236	20	values	value	NOUN
eurjchem-125	236	21	of	of	ADP
eurjchem-125	236	22	the	the	DET
eurjchem-125	236	23	both	both	DET
eurjchem-125	236	24	isomers	isomer	NOUN
eurjchem-125	236	25	.	.	PUNCT
eurjchem-125	237	1	it	it	PRON
eurjchem-125	237	2	may	may	AUX
eurjchem-125	237	3	be	be	AUX
eurjchem-125	237	4	expected	expect	VERB
eurjchem-125	237	5	that	that	SCONJ
eurjchem-125	237	6	the	the	DET
eurjchem-125	237	7	new	new	ADJ
eurjchem-125	237	8	synthesized	synthesize	VERB
eurjchem-125	237	9	compounds	compound	NOUN
eurjchem-125	237	10	would	would	AUX
eurjchem-125	237	11	act	act	VERB
eurjchem-125	237	12	in	in	ADP
eurjchem-125	237	13	a	a	DET
eurjchem-125	237	14	similar	similar	ADJ
eurjchem-125	237	15	way	way	NOUN
eurjchem-125	237	16	.	.	PUNCT
eurjchem-125	238	1	the	the	DET
eurjchem-125	238	2	biological	biological	ADJ
eurjchem-125	238	3	study	study	NOUN
eurjchem-125	238	4	of	of	ADP
eurjchem-125	238	5	the	the	DET
eurjchem-125	238	6	reported	report	VERB
eurjchem-125	238	7	compounds	compound	NOUN
eurjchem-125	238	8	is	be	AUX
eurjchem-125	238	9	in	in	ADP
eurjchem-125	238	10	progress	progress	NOUN
eurjchem-125	238	11	.	.	PUNCT
eurjchem-125	239	1	table	table	NOUN
eurjchem-125	239	2	4	4	NUM
eurjchem-125	239	3	.	.	PUNCT
eurjchem-125	239	4	calculated	calculate	VERB
eurjchem-125	239	5	value	value	NOUN
eurjchem-125	239	6	of	of	ADP
eurjchem-125	239	7	the	the	DET
eurjchem-125	239	8	distances	distance	NOUN
eurjchem-125	239	9	and	and	CCONJ
eurjchem-125	239	10	the	the	DET
eurjchem-125	239	11	similarity	similarity	NOUN
eurjchem-125	239	12	of	of	ADP
eurjchem-125	239	13	the	the	DET
eurjchem-125	239	14	compounds	compound	NOUN
eurjchem-125	239	15	.	.	PUNCT
eurjchem-125	240	1	compound	compound	NOUN
eurjchem-125	240	2	d2	d2	PROPN
eurjchem-125	240	3	r	r	NOUN
eurjchem-125	240	4	similarity%	similarity%	PROPN
eurjchem-125	240	5	5a	5a	NUM
eurjchem-125	240	6	0.1587	0.1587	NUM
eurjchem-125	240	7	0.3983	0.3983	NUM
eurjchem-125	240	8	61.16	61.16	NUM
eurjchem-125	240	9	7a	7a	NOUN
eurjchem-125	240	10	0.1788	0.1788	NUM
eurjchem-125	240	11	0.4229	0.4229	NUM
eurjchem-125	240	12	57,71	57,71	NUM
eurjchem-125	240	13	5b	5b	NUM
eurjchem-125	240	14	0,1331	0,1331	NOUN
eurjchem-125	240	15	0.3649	0.3649	NUM
eurjchem-125	240	16	63,51	63,51	NUM
eurjchem-125	240	17	7b	7b	NOUN
eurjchem-125	240	18	0,3581	0,3581	NUM
eurjchem-125	240	19	0.3581	0.3581	NUM
eurjchem-125	240	20	64,19	64,19	NUM
eurjchem-125	240	21	5c	5c	NUM
eurjchem-125	240	22	0,0379	0,0379	NOUN
eurjchem-125	240	23	0.1946	0.1946	NUM
eurjchem-125	240	24	80,54	80,54	NUM
eurjchem-125	240	25	7c	7c	PROPN
eurjchem-125	240	26	0,0562	0,0562	NOUN
eurjchem-125	240	27	0.2370	0.2370	NUM
eurjchem-125	240	28	76.30	76.30	NUM
eurjchem-125	240	29	5d	5d	NUM
eurjchem-125	240	30	0,0090	0,0090	PROPN
eurjchem-125	241	1	0.0947	0.0947	NUM
eurjchem-125	241	2	90.53	90.53	NUM
eurjchem-125	241	3	7d	7d	NUM
eurjchem-125	241	4	0,0030	0,0030	NOUN
eurjchem-125	241	5	0.0547	0.0547	NUM
eurjchem-125	241	6	94.53	94.53	NUM
eurjchem-125	241	7	5e	5e	NOUN
eurjchem-125	241	8	0,0399	0,0399	NOUN
eurjchem-125	241	9	0.1996	0.1996	NUM
eurjchem-125	241	10	80.04	80.04	NUM
eurjchem-125	241	11	7e	7e	NOUN
eurjchem-125	241	12	0,0196	0,0196	NOUN
eurjchem-125	241	13	0.1399	0.1399	NUM
eurjchem-125	241	14	86.01	86.01	NUM
eurjchem-125	241	15	acknowledgement	acknowledgement	NOUN
eurjchem-125	241	16	thanks	thank	NOUN
eurjchem-125	241	17	are	be	AUX
eurjchem-125	241	18	due	due	ADJ
eurjchem-125	241	19	to	to	ADP
eurjchem-125	241	20	national	national	ADJ
eurjchem-125	241	21	science	science	PROPN
eurjchem-125	241	22	fund	fund	PROPN
eurjchem-125	241	23	/	/	SYM
eurjchem-125	241	24	ministry	ministry	PROPN
eurjchem-125	241	25	of	of	ADP
eurjchem-125	241	26	education	education	PROPN
eurjchem-125	241	27	and	and	CCONJ
eurjchem-125	241	28	science	science	NOUN
eurjchem-125	241	29	grant	grant	NOUN
eurjchem-125	241	30	x1408	x1408	PROPN
eurjchem-125	241	31	and	and	CCONJ
eurjchem-125	241	32	science	science	PROPN
eurjchem-125	241	33	fund	fund	PROPN
eurjchem-125	241	34	/	/	SYM
eurjchem-125	241	35	chemical	chemical	NOUN
eurjchem-125	241	36	technology	technology	NOUN
eurjchem-125	241	37	and	and	CCONJ
eurjchem-125	241	38	metallurgy	metallurgy	NOUN
eurjchem-125	241	39	university	university	NOUN
eurjchem-125	241	40	grant	grant	NOUN
eurjchem-125	241	41	10580	10580	NUM
eurjchem-125	241	42	for	for	ADP
eurjchem-125	241	43	the	the	DET
eurjchem-125	241	44	financial	financial	ADJ
eurjchem-125	241	45	support	support	NOUN
eurjchem-125	241	46	of	of	ADP
eurjchem-125	241	47	this	this	DET
eurjchem-125	241	48	work	work	NOUN
eurjchem-125	241	49	.	.	PUNCT
eurjchem-125	242	1	references	reference	NOUN
eurjchem-125	242	2	[	[	X
eurjchem-125	242	3	1	1	NUM
eurjchem-125	242	4	]	]	PUNCT
eurjchem-125	242	5	.	.	PUNCT
eurjchem-125	243	1	narasaka	narasaka	PROPN
eurjchem-125	243	2	,	,	PUNCT
eurjchem-125	243	3	k.	k.	PROPN
eurjchem-125	243	4	pure	pure	ADJ
eurjchem-125	243	5	and	and	CCONJ
eurjchem-125	243	6	appl	appl	ADJ
eurjchem-125	243	7	.	.	PROPN
eurjchem-125	243	8	chem	chem	PROPN
eurjchem-125	243	9	.	.	PUNCT
eurjchem-125	244	1	1992	1992	NUM
eurjchem-125	244	2	,	,	PUNCT
eurjchem-125	244	3	64	64	NUM
eurjchem-125	244	4	(	(	PUNCT
eurjchem-125	244	5	12	12	NUM
eurjchem-125	244	6	)	)	PUNCT
eurjchem-125	244	7	,	,	PUNCT
eurjchem-125	244	8	1889‐1896	1889‐1896	NOUN
eurjchem-125	244	9	.	.	PUNCT
eurjchem-125	245	1	[	[	X
eurjchem-125	245	2	2	2	NUM
eurjchem-125	245	3	]	]	PUNCT
eurjchem-125	245	4	.	.	PUNCT
eurjchem-125	246	1	dixon	dixon	PROPN
eurjchem-125	246	2	,	,	PUNCT
eurjchem-125	246	3	d.	d.	PROPN
eurjchem-125	246	4	j.	j.	PROPN
eurjchem-125	246	5	;	;	PUNCT
eurjchem-125	246	6	horan	horan	PROPN
eurjchem-125	246	7	,	,	PUNCT
eurjchem-125	246	8	r.	r.	PROPN
eurjchem-125	246	9	a.	a.	PROPN
eurjchem-125	246	10	;	;	PUNCT
eurjchem-125	246	11	monck	monck	NOUN
eurjchem-125	246	12	,	,	PUNCT
eurjchem-125	246	13	n.	n.	PROPN
eurjchem-125	246	14	j	j	PROPN
eurjchem-125	246	15	;	;	PUNCT
eurjchem-125	246	16	berg	berg	PROPN
eurjchem-125	246	17	,	,	PUNCT
eurjchem-125	246	18	p.	p.	PROPN
eurjchem-125	246	19	org	org	PROPN
eurjchem-125	246	20	.	.	PUNCT
eurjchem-125	247	1	lett	lett	PROPN
eurjchem-125	247	2	.	.	PUNCT
eurjchem-125	248	1	2004	2004	NUM
eurjchem-125	248	2	,	,	PUNCT
eurjchem-125	248	3	6(24	6(24	NUM
eurjchem-125	248	4	)	)	PUNCT
eurjchem-125	248	5	,	,	PUNCT
eurjchem-125	248	6	4427‐4429	4427‐4429	NOUN
eurjchem-125	248	7	.	.	PUNCT
eurjchem-125	249	1	[	[	X
eurjchem-125	249	2	3	3	NUM
eurjchem-125	249	3	]	]	PUNCT
eurjchem-125	249	4	.	.	PUNCT
eurjchem-125	250	1	palomo	palomo	PROPN
eurjchem-125	250	2	,	,	PUNCT
eurjchem-125	250	3	c.	c.	NOUN
eurjchem-125	250	4	;	;	PUNCT
eurjchem-125	250	5	oiarbide	oiarbide	ADJ
eurjchem-125	250	6	,	,	PUNCT
eurjchem-125	250	7	m.	m.	NOUN
eurjchem-125	250	8	;	;	PUNCT
eurjchem-125	250	9	garcia	garcia	PROPN
eurjchem-125	250	10	,	,	PUNCT
eurjchem-125	250	11	j.	j.	PROPN
eurjchem-125	250	12	m.	m.	PROPN
eurjchem-125	250	13	chem	chem	PROPN
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eurjchem-125	251	1	eur	eur	PROPN
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eurjchem-125	252	1	j.	j.	PROPN
eurjchem-125	252	2	2002	2002	PROPN
eurjchem-125	252	3	,	,	PUNCT
eurjchem-125	252	4	8	8	NUM
eurjchem-125	252	5	,	,	PUNCT
eurjchem-125	252	6	36‐44	36‐44	NUM
eurjchem-125	252	7	.	.	PUNCT
eurjchem-125	253	1	[	[	X
eurjchem-125	253	2	4	4	NUM
eurjchem-125	253	3	]	]	PUNCT
eurjchem-125	253	4	.	.	PUNCT
eurjchem-125	254	1	davies	davy	NOUN
eurjchem-125	254	2	,	,	PUNCT
eurjchem-125	254	3	s.	s.	PROPN
eurjchem-125	254	4	g.	g.	PROPN
eurjchem-125	254	5	;	;	PUNCT
eurjchem-125	254	6	garner	garner	PROPN
eurjchem-125	254	7	a.	a.	PROPN
eurjchem-125	254	8	c.	c.	PROPN
eurjchem-125	254	9	;	;	PUNCT
eurjchem-125	254	10	roberts	roberts	PROPN
eurjchem-125	254	11	p	p	PROPN
eurjchem-125	254	12	,	,	PUNCT
eurjchem-125	254	13	m.	m.	NOUN
eurjchem-125	254	14	;	;	PUNCT
eurjchem-125	255	1	smith	smith	PROPN
eurjchem-125	255	2	a.	a.	PROPN
eurjchem-125	255	3	d	d	PROPN
eurjchem-125	255	4	;	;	PUNCT
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eurjchem-125	255	6	m.	m.	NOUN
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eurjchem-125	255	11	e.	e.	PROPN
eurjchem-125	255	12	org	org	PROPN
eurjchem-125	255	13	.	.	PUNCT
eurjchem-125	255	14	biomol	biomol	PROPN
eurjchem-125	255	15	.	.	PUNCT
eurjchem-125	256	1	chem	chem	PROPN
eurjchem-125	256	2	.	.	PUNCT
eurjchem-125	257	1	2006	2006	NUM
eurjchem-125	257	2	,	,	PUNCT
eurjchem-125	257	3	4(14	4(14	NUM
eurjchem-125	257	4	)	)	PUNCT
eurjchem-125	257	5	,	,	PUNCT
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eurjchem-125	257	7	.	.	PUNCT
eurjchem-125	258	1	[	[	X
eurjchem-125	258	2	5	5	NUM
eurjchem-125	258	3	]	]	PUNCT
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eurjchem-125	259	2	,	,	PUNCT
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eurjchem-125	259	11	h.	h.	PROPN
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eurjchem-125	259	14	,	,	PUNCT
eurjchem-125	259	15	j.	j.	PROPN
eurjchem-125	259	16	k.	k.	PROPN
eurjchem-125	259	17	;	;	PUNCT
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eurjchem-125	259	20	k.	k.	PROPN
eurjchem-125	259	21	m.	m.	PROPN
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eurjchem-125	259	24	k.	k.	PROPN
eurjchem-125	259	25	h.	h.	PROPN
eurjchem-125	259	26	synlett	synlett	PROPN
eurjchem-125	259	27	.	.	PUNCT
eurjchem-125	260	1	2005	2005	NUM
eurjchem-125	260	2	,	,	PUNCT
eurjchem-125	260	3	15	15	NUM
eurjchem-125	260	4	,	,	PUNCT
eurjchem-125	260	5	2289‐2292	2289‐2292	NUM
eurjchem-125	260	6	.	.	PUNCT
eurjchem-125	261	1	[	[	X
eurjchem-125	261	2	6	6	NUM
eurjchem-125	261	3	]	]	PUNCT
eurjchem-125	261	4	.	.	PUNCT
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eurjchem-125	261	6	,	,	PUNCT
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eurjchem-125	261	10	,	,	PUNCT
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eurjchem-125	261	12	;	;	PUNCT
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eurjchem-125	261	14	,	,	PUNCT
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eurjchem-125	261	27	,	,	PUNCT
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eurjchem-125	261	31	,	,	PUNCT
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eurjchem-125	261	33	;	;	PUNCT
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eurjchem-125	261	35	,	,	PUNCT
eurjchem-125	261	36	d.	d.	PROPN
eurjchem-125	261	37	;	;	PUNCT
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eurjchem-125	261	39	,	,	PUNCT
eurjchem-125	261	40	m.	m.	PROPN
eurjchem-125	261	41	l.	l.	PROPN
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eurjchem-125	261	44	2004	2004	NUM
eurjchem-125	261	45	,	,	PUNCT
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eurjchem-125	261	47	(	(	PUNCT
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eurjchem-125	261	50	,	,	PUNCT
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eurjchem-125	262	3	]	]	PUNCT
eurjchem-125	262	4	.	.	PUNCT
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eurjchem-125	263	2	s.	s.	PROPN
eurjchem-125	263	3	y.	y.	PROPN
eurjchem-125	263	4	;	;	PUNCT
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eurjchem-125	263	6	y.	y.	PROPN
eurjchem-125	263	7	h.	h.	PROPN
eurjchem-125	263	8	;	;	PUNCT
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eurjchem-125	263	10	s.	s.	PROPN
eurjchem-125	263	11	w.	w.	PROPN
eurjchem-125	263	12	;	;	PUNCT
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eurjchem-125	263	15	;	;	PUNCT
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eurjchem-125	263	18	;	;	PUNCT
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eurjchem-125	263	20	s	s	PROPN
eurjchem-125	263	21	;	;	PUNCT
eurjchem-125	263	22	kim	kim	PROPN
eurjchem-125	263	23	y.	y.	PROPN
eurjchem-125	263	24	w	w	PROPN
eurjchem-125	263	25	;	;	PUNCT
eurjchem-125	263	26	lee	lee	PROPN
eurjchem-125	263	27	w.	w.	PROPN
eurjchem-125	263	28	k.	k.	PROPN
eurjchem-125	263	29	;	;	PUNCT
eurjchem-125	263	30	ha	ha	PROPN
eurjchem-125	263	31	h.	h.	PROPN
eurjchem-125	263	32	j.	j.	PROPN
eurjchem-125	263	33	bioorg	bioorg	PROPN
eurjchem-125	263	34	&	&	CCONJ
eurjchem-125	263	35	med	med	PROPN
eurjchem-125	263	36	chem	chem	PROPN
eurjchem-125	263	37	lett	lett	PROPN
eurjchem-125	263	38	.	.	PUNCT
eurjchem-125	264	1	2004	2004	NUM
eurjchem-125	264	2	,	,	PUNCT
eurjchem-125	264	3	14(15	14(15	NUM
eurjchem-125	264	4	)	)	PUNCT
eurjchem-125	264	5	,	,	PUNCT
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eurjchem-125	264	7	.	.	PUNCT
eurjchem-125	265	1	[	[	X
eurjchem-125	265	2	8	8	NUM
eurjchem-125	265	3	]	]	PUNCT
eurjchem-125	265	4	.	.	PUNCT
eurjchem-125	266	1	mishra	mishra	PROPN
eurjchem-125	266	2	,	,	PUNCT
eurjchem-125	266	3	r.	r.	PROPN
eurjchem-125	266	4	k.	k.	PROPN
eurjchem-125	266	5	;	;	PUNCT
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eurjchem-125	266	7	,	,	PUNCT
eurjchem-125	266	8	k.	k.	PROPN
eurjchem-125	266	9	d.	d.	PROPN
eurjchem-125	266	10	;	;	PUNCT
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eurjchem-125	266	12	c.	c.	PROPN
eurjchem-125	266	13	m.	m.	PROPN
eurjchem-125	266	14	;	;	PUNCT
eurjchem-125	266	15	turos	turos	PROPN
eurjchem-125	266	16	,	,	PUNCT
eurjchem-125	266	17	e.	e.	PROPN
eurjchem-125	266	18	;	;	PUNCT
eurjchem-125	266	19	dickey	dickey	PROPN
eurjchem-125	266	20	,	,	PUNCT
eurjchem-125	266	21	s.	s.	PROPN
eurjchem-125	266	22	;	;	PUNCT
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eurjchem-125	266	24	,	,	PUNCT
eurjchem-125	266	25	d.	d.	PROPN
eurjchem-125	266	26	v.	v.	PROPN
eurjchem-125	266	27	bioor	bioor	PROPN
eurjchem-125	266	28	&	&	CCONJ
eurjchem-125	266	29	med	med	PROPN
eurjchem-125	266	30	.	.	PROPN
eurjchem-125	266	31	chem	chem	PROPN
eurjchem-125	266	32	.	.	PUNCT
eurjchem-125	267	1	letts	letts	PROPN
eurjchem-125	267	2	,	,	PUNCT
eurjchem-125	267	3	2006	2006	NUM
eurjchem-125	267	4	,	,	PUNCT
eurjchem-125	267	5	16(8	16(8	NUM
eurjchem-125	267	6	)	)	PUNCT
eurjchem-125	267	7	,	,	PUNCT
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eurjchem-125	267	9	.	.	PUNCT
eurjchem-125	268	1	[	[	X
eurjchem-125	268	2	9	9	NUM
eurjchem-125	268	3	]	]	PUNCT
eurjchem-125	268	4	.	.	PUNCT
eurjchem-125	269	1	zappia	zappia	PROPN
eurjchem-125	269	2	,	,	PUNCT
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eurjchem-125	269	4	;	;	PUNCT
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eurjchem-125	269	6	,	,	PUNCT
eurjchem-125	269	7	p.	p.	PROPN
eurjchem-125	269	8	;	;	PUNCT
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eurjchem-125	269	10	,	,	PUNCT
eurjchem-125	269	11	d.	d.	PROPN
eurjchem-125	269	12	m.	m.	PROPN
eurjchem-125	269	13	;	;	PUNCT
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eurjchem-125	269	15	,	,	PUNCT
eurjchem-125	269	16	d.	d.	PROPN
eurjchem-125	269	17	;	;	PUNCT
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eurjchem-125	269	19	,	,	PUNCT
eurjchem-125	269	20	l.	l.	PROPN
eurjchem-125	269	21	;	;	PUNCT
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eurjchem-125	269	23	,	,	PUNCT
eurjchem-125	269	24	b.	b.	PROPN
eurjchem-125	269	25	mini	mini	PROPN
eurjchem-125	269	26	rev	rev	PROPN
eurjchem-125	269	27	.	.	PROPN
eurjchem-125	269	28	med	med	PROPN
eurjchem-125	269	29	.	.	PROPN
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eurjchem-125	269	31	.	.	PUNCT
eurjchem-125	270	1	2007	2007	NUM
eurjchem-125	270	2	,	,	PUNCT
eurjchem-125	270	3	7(4	7(4	NUM
eurjchem-125	270	4	)	)	PUNCT
eurjchem-125	270	5	,	,	PUNCT
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eurjchem-125	270	7	.	.	PUNCT
eurjchem-125	271	1	[	[	X
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eurjchem-125	271	3	]	]	PUNCT
eurjchem-125	271	4	.	.	PUNCT
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eurjchem-125	272	2	,	,	PUNCT
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eurjchem-125	272	4	;	;	PUNCT
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eurjchem-125	272	7	;	;	PUNCT
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eurjchem-125	272	9	,	,	PUNCT
eurjchem-125	272	10	s.	s.	PROPN
eurjchem-125	272	11	;	;	PUNCT
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eurjchem-125	272	13	,	,	PUNCT
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eurjchem-125	272	15	;	;	PUNCT
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eurjchem-125	272	17	,	,	PUNCT
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eurjchem-125	272	19	;	;	PUNCT
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eurjchem-125	272	21	,	,	PUNCT
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eurjchem-125	272	25	,	,	PUNCT
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eurjchem-125	272	27	;	;	PUNCT
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eurjchem-125	272	29	l.	l.	PROPN
eurjchem-125	272	30	d.	d.	PROPN
eurjchem-125	272	31	;	;	PUNCT
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eurjchem-125	272	33	,	,	PUNCT
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eurjchem-125	272	35	;	;	PUNCT
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eurjchem-125	273	2	,	,	PUNCT
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eurjchem-125	273	4	)	)	PUNCT
eurjchem-125	273	5	,	,	PUNCT
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eurjchem-125	273	8	.	.	PUNCT
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eurjchem-125	274	3	]	]	PUNCT
eurjchem-125	274	4	.	.	PUNCT
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eurjchem-125	275	2	,	,	PUNCT
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eurjchem-125	275	4	;	;	PUNCT
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eurjchem-125	276	4	.	.	PUNCT
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eurjchem-125	277	31	e.	e.	PROPN
eurjchem-125	277	32	arkivoc	arkivoc	PROPN
eurjchem-125	277	33	,	,	PUNCT
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eurjchem-125	277	35	,	,	PUNCT
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eurjchem-125	277	39	.	.	PUNCT
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eurjchem-125	278	14	)	)	PUNCT
eurjchem-125	278	15	(	(	PUNCT
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eurjchem-125	278	17	)	)	PUNCT
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eurjchem-125	279	2	13	13	NUM
eurjchem-125	279	3	]	]	PUNCT
eurjchem-125	279	4	.	.	PUNCT
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eurjchem-125	280	2	,	,	PUNCT
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eurjchem-125	280	4	;	;	PUNCT
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eurjchem-125	280	6	.	.	PUNCT
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eurjchem-125	280	8	;	;	PUNCT
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eurjchem-125	280	10	,	,	PUNCT
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eurjchem-125	280	12	;	;	PUNCT
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eurjchem-125	280	14	,	,	PUNCT
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eurjchem-125	280	18	,	,	PUNCT
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eurjchem-125	280	20	;	;	PUNCT
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eurjchem-125	280	22	,	,	PUNCT
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eurjchem-125	280	26	,	,	PUNCT
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eurjchem-125	280	28	;	;	PUNCT
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eurjchem-125	280	30	,	,	PUNCT
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eurjchem-125	280	34	,	,	PUNCT
eurjchem-125	280	35	l.	l.	PROPN
eurjchem-125	280	36	;	;	PUNCT
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eurjchem-125	280	38	,	,	PUNCT
eurjchem-125	280	39	g.	g.	PROPN
eurjchem-125	280	40	;	;	PUNCT
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eurjchem-125	280	42	,	,	PUNCT
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eurjchem-125	280	45	&	&	CCONJ
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eurjchem-125	280	47	.	.	PROPN
eurjchem-125	281	1	chem	chem	PROPN
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eurjchem-125	282	2	.	.	PUNCT
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eurjchem-125	283	2	,	,	PUNCT
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eurjchem-125	283	4	)	)	PUNCT
eurjchem-125	283	5	,	,	PUNCT
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eurjchem-125	283	7	.	.	PUNCT
eurjchem-125	284	1	[	[	X
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eurjchem-125	284	3	]	]	SYM
eurjchem-125	284	4	.	.	PUNCT
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eurjchem-125	285	2	,	,	PUNCT
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eurjchem-125	285	6	,	,	PUNCT
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eurjchem-125	285	38	,	,	PUNCT
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eurjchem-125	285	42	,	,	PUNCT
eurjchem-125	285	43	t.	t.	PROPN
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eurjchem-125	285	50	,	,	PUNCT
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eurjchem-125	285	52	j.	j.	PROPN
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eurjchem-125	285	56	.	.	PUNCT
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eurjchem-125	286	2	,	,	PUNCT
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eurjchem-125	286	4	)	)	PUNCT
eurjchem-125	286	5	,	,	PUNCT
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eurjchem-125	286	7	.	.	PUNCT
eurjchem-125	287	1	[	[	X
eurjchem-125	287	2	15	15	NUM
eurjchem-125	287	3	]	]	PUNCT
eurjchem-125	287	4	.	.	PUNCT
eurjchem-125	288	1	hobbs	hobbs	PROPN
eurjchem-125	288	2	,	,	PUNCT
eurjchem-125	288	3	s.	s.	PROPN
eurjchem-125	288	4	h.	h.	PROPN
eurjchem-125	288	5	,	,	PUNCT
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eurjchem-125	288	7	,	,	PUNCT
eurjchem-125	288	8	s.	s.	PROPN
eurjchem-125	288	9	j.	j.	PROPN
eurjchem-125	288	10	us	us	PROPN
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eurjchem-125	288	12	,	,	PUNCT
eurjchem-125	288	13	1991	1991	NUM
eurjchem-125	288	14	,	,	PUNCT
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eurjchem-125	288	17	.	.	PUNCT
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eurjchem-125	289	3	]	]	PUNCT
eurjchem-125	289	4	.	.	PUNCT
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eurjchem-125	289	6	,	,	PUNCT
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eurjchem-125	289	10	,	,	PUNCT
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eurjchem-125	289	12	;	;	PUNCT
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eurjchem-125	289	14	,	,	PUNCT
eurjchem-125	289	15	l.	l.	PROPN
eurjchem-125	289	16	;	;	PUNCT
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eurjchem-125	289	18	,	,	PUNCT
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eurjchem-125	289	20	bg	bg	PROPN
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eurjchem-125	289	22	,	,	PUNCT
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eurjchem-125	289	24	,	,	PUNCT
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eurjchem-125	289	27	,	,	PUNCT
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eurjchem-125	290	2	17	17	NUM
eurjchem-125	290	3	]	]	PUNCT
eurjchem-125	290	4	.	.	PUNCT
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eurjchem-125	290	6	,	,	PUNCT
eurjchem-125	290	7	w.	w.	PROPN
eurjchem-125	290	8	w.	w.	PROPN
eurjchem-125	290	9	;	;	PUNCT
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eurjchem-125	290	11	o.	o.	PROPN
eurjchem-125	290	12	m	m	PROPN
eurjchem-125	290	13	;	;	PUNCT
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eurjchem-125	290	15	g.	g.	PROPN
eurjchem-125	290	16	a.	a.	PROPN
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eurjchem-125	290	19	.	.	PUNCT
eurjchem-125	291	1	2008	2008	NUM
eurjchem-125	291	2	,	,	PUNCT
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eurjchem-125	291	4	)	)	PUNCT
eurjchem-125	291	5	,	,	PUNCT
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eurjchem-125	291	7	.	.	PUNCT
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eurjchem-125	292	3	]	]	PUNCT
eurjchem-125	292	4	.	.	PUNCT
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eurjchem-125	292	6	,	,	PUNCT
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eurjchem-125	292	10	;	;	PUNCT
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eurjchem-125	292	12	,	,	PUNCT
eurjchem-125	292	13	sh	sh	PROPN
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eurjchem-125	292	17	,	,	PUNCT
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eurjchem-125	292	26	.	.	PUNCT
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eurjchem-125	293	2	,	,	PUNCT
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eurjchem-125	293	4	)	)	PUNCT
eurjchem-125	293	5	,	,	PUNCT
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eurjchem-125	293	7	.	.	PUNCT
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eurjchem-125	294	3	]	]	PUNCT
eurjchem-125	294	4	.	.	PUNCT
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eurjchem-125	295	2	kh	kh	PROPN
eurjchem-125	295	3	.	.	PROPN
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eurjchem-125	295	5	;	;	PUNCT
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eurjchem-125	295	7	,	,	PUNCT
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eurjchem-125	296	1	s.	s.	PROPN
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eurjchem-125	296	3	a.	a.	PROPN
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eurjchem-125	296	5	n.	n.	PROPN
eurjchem-125	296	6	j.	j.	PROPN
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eurjchem-125	296	10	.	.	PUNCT
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eurjchem-125	297	4	.	.	PUNCT
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eurjchem-125	298	2	,	,	PUNCT
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eurjchem-125	298	6	)	)	PUNCT
eurjchem-125	298	7	,	,	PUNCT
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eurjchem-125	299	4	.	.	PUNCT
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eurjchem-125	300	6	,	,	PUNCT
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eurjchem-125	301	4	.	.	PUNCT
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eurjchem-125	304	2	,	,	PUNCT
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eurjchem-125	305	4	.	.	PUNCT
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eurjchem-125	307	2	.	.	PUNCT
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eurjchem-125	310	3	]	]	PUNCT
eurjchem-125	310	4	.	.	PUNCT
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eurjchem-125	313	8	,	,	PUNCT
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eurjchem-125	313	10	and	and	CCONJ
eurjchem-125	313	11	applications	application	NOUN
eurjchem-125	313	12	in	in	ADP
eurjchem-125	313	13	chemistry	chemistry	NOUN
eurjchem-125	313	14	,	,	PUNCT
eurjchem-125	313	15	wiley	wiley	PROPN
eurjchem-125	313	16	,	,	PUNCT
eurjchem-125	313	17	chichester	chichester	PROPN
eurjchem-125	313	18	,	,	PUNCT
eurjchem-125	313	19	england	england	PROPN
eurjchem-125	313	20	,	,	PUNCT
eurjchem-125	313	21	1995	1995	NUM
eurjchem-125	313	22	.	.	PUNCT
eurjchem-125	314	1	[	[	X
eurjchem-125	314	2	25	25	NUM
eurjchem-125	314	3	]	]	PUNCT
eurjchem-125	314	4	.	.	PUNCT
eurjchem-125	315	1	pretsch	pretsch	PROPN
eurjchem-125	315	2	e.	e.	PROPN
eurjchem-125	315	3	,	,	PUNCT
eurjchem-125	315	4	clerc	clerc	PROPN
eurjchem-125	315	5	j.	j.	PROPN
eurjchem-125	315	6	t.	t.	PROPN
eurjchem-125	315	7	spectra	spectra	PROPN
eurjchem-125	315	8	interpretation	interpretation	NOUN
eurjchem-125	315	9	of	of	ADP
eurjchem-125	315	10	organic	organic	ADJ
eurjchem-125	315	11	compounds	compound	NOUN
eurjchem-125	315	12	,	,	PUNCT
eurjchem-125	315	13	weinheim	weinheim	PROPN
eurjchem-125	315	14	,	,	PUNCT
eurjchem-125	315	15	germany	germany	PROPN
eurjchem-125	315	16	,	,	PUNCT
eurjchem-125	315	17	vch	vch	PROPN
eurjchem-125	315	18	,	,	PUNCT
eurjchem-125	315	19	1997	1997	NUM
eurjchem-125	315	20	.	.	PUNCT
eurjchem-125	316	1	[	[	X
eurjchem-125	316	2	26	26	NUM
eurjchem-125	316	3	]	]	PUNCT
eurjchem-125	316	4	.	.	PUNCT
eurjchem-125	317	1	neuhaus	neuhaus	PROPN
eurjchem-125	317	2	,	,	PUNCT
eurjchem-125	317	3	d.	d.	PROPN
eurjchem-125	317	4	;	;	PUNCT
eurjchem-125	317	5	williamson	williamson	PROPN
eurjchem-125	317	6	,	,	PUNCT
eurjchem-125	317	7	m.	m.	NOUN
eurjchem-125	317	8	the	the	DET
eurjchem-125	317	9	nuclear	nuclear	ADJ
eurjchem-125	317	10	overhauser	overhauser	PROPN
eurjchem-125	317	11	effect	effect	NOUN
eurjchem-125	317	12	in	in	ADP
eurjchem-125	317	13	structural	structural	ADJ
eurjchem-125	317	14	and	and	CCONJ
eurjchem-125	317	15	conformational	conformational	ADJ
eurjchem-125	317	16	analysis	analysis	NOUN
eurjchem-125	317	17	,	,	PUNCT
eurjchem-125	317	18	wiley	wiley	PROPN
eurjchem-125	317	19	–	–	PUNCT
eurjchem-125	317	20	vch	vch	PROPN
eurjchem-125	317	21	:	:	PUNCT
eurjchem-125	317	22	new	new	PROPN
eurjchem-125	317	23	york	york	PROPN
eurjchem-125	317	24	,	,	PUNCT
eurjchem-125	317	25	2000	2000	NUM
eurjchem-125	317	26	.	.	PUNCT
eurjchem-125	318	1	[	[	X
eurjchem-125	318	2	27	27	NUM
eurjchem-125	318	3	]	]	PUNCT
eurjchem-125	318	4	.	.	PUNCT
eurjchem-125	319	1	nikolova	nikolova	PROPN
eurjchem-125	319	2	,	,	PUNCT
eurjchem-125	319	3	n.	n.	NOUN
eurjchem-125	319	4	,	,	PUNCT
eurjchem-125	319	5	javorska	javorska	PROPN
eurjchem-125	319	6	,	,	PUNCT
eurjchem-125	319	7	j.	j.	PROPN
eurjchem-125	319	8	qsar	qsar	PROPN
eurjchem-125	319	9	comb	comb	PROPN
eurjchem-125	319	10	sci	sci	PROPN
eurjchem-125	319	11	.	.	PROPN
eurjchem-125	319	12	2003	2003	NUM
eurjchem-125	319	13	,	,	PUNCT
eurjchem-125	319	14	22	22	NUM
eurjchem-125	319	15	,	,	PUNCT
eurjchem-125	319	16	1006‐1026	1006‐1026	NUM
eurjchem-125	319	17	.	.	PUNCT
eurjchem-125	320	1	[	[	X
eurjchem-125	320	2	28	28	NUM
eurjchem-125	320	3	]	]	PUNCT
eurjchem-125	320	4	.	.	PUNCT
eurjchem-125	321	1	karelson	karelson	PROPN
eurjchem-125	321	2	,	,	PUNCT
eurjchem-125	321	3	m.	m.	NOUN
eurjchem-125	321	4	;	;	PUNCT
eurjchem-125	321	5	lobanov	lobanov	PROPN
eurjchem-125	321	6	v.	v.	ADP
eurjchem-125	321	7	s.	s.	PROPN
eurjchem-125	321	8	;	;	PUNCT
eurjchem-125	321	9	katritzky	katritzky	PROPN
eurjchem-125	321	10	,	,	PUNCT
eurjchem-125	321	11	a.	a.	PROPN
eurjchem-125	321	12	r.	r.	PROPN
eurjchem-125	321	13	chem	chem	PROPN
eurjchem-125	321	14	.	.	PUNCT
eurjchem-125	322	1	rev	rev	PROPN
eurjchem-125	322	2	.	.	PROPN
eurjchem-125	322	3	1996	1996	NUM
eurjchem-125	322	4	,	,	PUNCT
eurjchem-125	322	5	96	96	NUM
eurjchem-125	322	6	,	,	PUNCT
eurjchem-125	322	7	1027‐	1027‐	NUM
eurjchem-125	322	8	1044	1044	NUM
eurjchem-125	322	9	.	.	PUNCT
eurjchem-125	323	1	[	[	X
eurjchem-125	323	2	29	29	NUM
eurjchem-125	323	3	]	]	PUNCT
eurjchem-125	323	4	.	.	PUNCT
eurjchem-125	324	1	bijev	bijev	PROPN
eurjchem-125	324	2	,	,	PUNCT
eurjchem-125	324	3	a.	a.	NOUN
eurjchem-125	324	4	,	,	PUNCT
eurjchem-125	324	5	yaneva	yaneva	PROPN
eurjchem-125	324	6	,	,	PUNCT
eurjchem-125	324	7	d.	d.	PROPN
eurjchem-125	324	8	,	,	PUNCT
eurjchem-125	324	9	bocheva	bocheva	PROPN
eurjchem-125	324	10	,	,	PUNCT
eurjchem-125	324	11	a.	a.	NOUN
eurjchem-125	324	12	arzneimittel‐forsch	arzneimittel‐forsch	PROPN
eurjchem-125	324	13	.	.	PUNCT
eurjchem-125	325	1	2006	2006	NUM
eurjchem-125	325	2	,	,	PUNCT
eurjchem-125	325	3	56(11	56(11	NUM
eurjchem-125	325	4	)	)	PUNCT
eurjchem-125	325	5	,	,	PUNCT
eurjchem-125	325	6	753‐759	753‐759	NUM
eurjchem-125	325	7	.	.	PUNCT