id sid tid token lemma pos eurjchem-131 1 1 microsoft microsoft PROPN eurjchem-131 1 2 word word NOUN eurjchem-131 1 3 european_journal_of_chemistry_1_4_2010_294_296_131 european_journal_of_chemistry_1_4_2010_294_296_131 PROPN eurjchem-131 1 4 european european ADJ eurjchem-131 1 5     SPACE eurjchem-131 1 6 journal journal NOUN eurjchem-131 1 7     SPACE eurjchem-131 1 8 of of ADP eurjchem-131 1 9     SPACE eurjchem-131 1 10 chemistry chemistry NOUN eurjchem-131 1 11     SPACE eurjchem-131 1 12 1 1 NUM eurjchem-131 1 13     SPACE eurjchem-131 1 14 ( ( PUNCT eurjchem-131 1 15 4 4 NUM eurjchem-131 1 16 ) ) PUNCT eurjchem-131 1 17     SPACE eurjchem-131 1 18 ( ( PUNCT eurjchem-131 1 19 2010 2010 NUM eurjchem-131 1 20 ) ) PUNCT eurjchem-131 1 21     SPACE eurjchem-131 1 22 294‐296 294‐296 NUM eurjchem-131 1 23         SPACE eurjchem-131 1 24 european european ADJ eurjchem-131 1 25     SPACE eurjchem-131 1 26 journal journal NOUN eurjchem-131 1 27     SPACE eurjchem-131 1 28 of of ADP eurjchem-131 1 29     SPACE eurjchem-131 1 30 chemistry chemistry NOUN eurjchem-131 1 31     SPACE eurjchem-131 1 32 issn issn VERB eurjchem-131 1 33     SPACE eurjchem-131 1 34 2153‐2249 2153‐2249 NUM eurjchem-131 1 35     SPACE eurjchem-131 1 36 ( ( PUNCT eurjchem-131 1 37 print print NOUN eurjchem-131 1 38 ) ) PUNCT eurjchem-131 1 39     SPACE eurjchem-131 1 40 / / SYM eurjchem-131 1 41     SPACE eurjchem-131 1 42 issn issn VERB eurjchem-131 1 43     SPACE eurjchem-131 1 44 2153‐2257 2153‐2257 NUM eurjchem-131 1 45     SPACE eurjchem-131 1 46 ( ( PUNCT eurjchem-131 1 47 online online ADJ eurjchem-131 1 48 ) ) PUNCT eurjchem-131 1 49     SPACE eurjchem-131 1 50   NOUN eurjchem-131 1 51     SPACE eurjchem-131 1 52 2010 2010 NUM eurjchem-131 1 53     SPACE eurjchem-131 1 54 eurjchem eurjchem NOUN eurjchem-131 1 55     SPACE eurjchem-131 1 56 doi:10.5155 doi:10.5155 PROPN eurjchem-131 1 57 / / SYM eurjchem-131 1 58 eurjchem.1.4.294‐296.131 eurjchem.1.4.294‐296.131 NOUN eurjchem-131 1 59                 SPACE eurjchem-131 1 60 european european ADJ eurjchem-131 1 61     SPACE eurjchem-131 1 62 journal journal NOUN eurjchem-131 1 63     SPACE eurjchem-131 1 64 of of ADP eurjchem-131 1 65     SPACE eurjchem-131 1 66 chemistry chemistry NOUN eurjchem-131 1 67     SPACE eurjchem-131 1 68 journal journal NOUN eurjchem-131 1 69     SPACE eurjchem-131 1 70 homepage homepage NOUN eurjchem-131 1 71 : : PUNCT eurjchem-131 1 72     SPACE eurjchem-131 1 73 www.eurjchem.com www.eurjchem.com NOUN eurjchem-131 1 74                     SPACE eurjchem-131 1 75 one one NUM eurjchem-131 1 76     SPACE eurjchem-131 1 77 new new ADJ eurjchem-131 1 78     SPACE eurjchem-131 1 79 cucurbitane cucurbitane NOUN eurjchem-131 1 80     SPACE eurjchem-131 1 81 triterpenoid triterpenoid NOUN eurjchem-131 1 82     SPACE eurjchem-131 1 83 from from ADP eurjchem-131 1 84     SPACE eurjchem-131 1 85 the the DET eurjchem-131 1 86     SPACE eurjchem-131 1 87 fruits fruit NOUN eurjchem-131 1 88     SPACE eurjchem-131 1 89 of of ADP eurjchem-131 1 90     SPACE eurjchem-131 1 91 momordica momordica PROPN eurjchem-131 1 92     SPACE eurjchem-131 1 93 charantia charantia PROPN eurjchem-131 1 94     SPACE eurjchem-131 1 95 jie‐qing jie‐qing PROPN eurjchem-131 1 96     SPACE eurjchem-131 1 97 liu liu PROPN eurjchem-131 1 98 , , PUNCT eurjchem-131 1 99     SPACE eurjchem-131 1 100 jian‐chao jian‐chao PROPN eurjchem-131 1 101     SPACE eurjchem-131 1 102 chen chen PROPN eurjchem-131 1 103 , , PUNCT eurjchem-131 1 104     SPACE eurjchem-131 1 105 cui‐fang cui‐fang PROPN eurjchem-131 1 106     SPACE eurjchem-131 1 107 wang wang PROPN eurjchem-131 1 108     SPACE eurjchem-131 1 109 and and CCONJ eurjchem-131 1 110     SPACE eurjchem-131 1 111 ming‐hua ming‐hua PROPN eurjchem-131 1 112     SPACE eurjchem-131 1 113 qiu qiu PROPN eurjchem-131 1 114 * * PUNCT eurjchem-131 1 115     SPACE eurjchem-131 1 116 state state NOUN eurjchem-131 1 117     SPACE eurjchem-131 1 118 key key ADJ eurjchem-131 1 119     SPACE eurjchem-131 1 120 laboratory laboratory NOUN eurjchem-131 1 121     SPACE eurjchem-131 1 122 of of ADP eurjchem-131 1 123     SPACE eurjchem-131 1 124 phytochemistry phytochemistry NOUN eurjchem-131 1 125     SPACE eurjchem-131 1 126 and and CCONJ eurjchem-131 1 127     SPACE eurjchem-131 1 128 plant plant NOUN eurjchem-131 1 129     SPACE eurjchem-131 1 130 resources resource NOUN eurjchem-131 1 131     SPACE eurjchem-131 1 132 in in ADP eurjchem-131 1 133     SPACE eurjchem-131 1 134 west west PROPN eurjchem-131 1 135     SPACE eurjchem-131 1 136 china china PROPN eurjchem-131 1 137 , , PUNCT eurjchem-131 1 138     SPACE eurjchem-131 1 139 kunming kunming PROPN eurjchem-131 1 140     SPACE eurjchem-131 1 141 institute institute PROPN eurjchem-131 1 142     SPACE eurjchem-131 1 143 of of ADP eurjchem-131 1 144     SPACE eurjchem-131 1 145 botany botany NOUN eurjchem-131 1 146 , , PUNCT eurjchem-131 1 147     SPACE eurjchem-131 1 148 chinese chinese PROPN eurjchem-131 1 149     SPACE eurjchem-131 1 150 academy academy PROPN eurjchem-131 1 151     SPACE eurjchem-131 1 152 of of ADP eurjchem-131 1 153     SPACE eurjchem-131 1 154 science science NOUN eurjchem-131 1 155 , , PUNCT eurjchem-131 1 156       SPACE eurjchem-131 1 157 kunming kunming NOUN eurjchem-131 1 158 , , PUNCT eurjchem-131 1 159     SPACE eurjchem-131 1 160 yunnan yunnan NOUN eurjchem-131 1 161 , , PUNCT eurjchem-131 1 162     SPACE eurjchem-131 1 163 cn­650204 cn­650204 PROPN eurjchem-131 1 164 , , PUNCT eurjchem-131 1 165     SPACE eurjchem-131 1 166 china china PROPN eurjchem-131 1 167     SPACE eurjchem-131 1 168 * * PROPN eurjchem-131 1 169 corresponding corresponding ADJ eurjchem-131 1 170     SPACE eurjchem-131 1 171 author author NOUN eurjchem-131 1 172     SPACE eurjchem-131 1 173 at at ADP eurjchem-131 1 174 : : PUNCT eurjchem-131 1 175     SPACE eurjchem-131 1 176 state state NOUN eurjchem-131 1 177     SPACE eurjchem-131 1 178 key key ADJ eurjchem-131 1 179     SPACE eurjchem-131 1 180 laboratory laboratory NOUN eurjchem-131 1 181     SPACE eurjchem-131 1 182 of of ADP eurjchem-131 1 183     SPACE eurjchem-131 1 184 phytochemistry phytochemistry NOUN eurjchem-131 1 185     SPACE eurjchem-131 1 186 and and CCONJ eurjchem-131 1 187     SPACE eurjchem-131 1 188 plant plant NOUN eurjchem-131 1 189     SPACE eurjchem-131 1 190 resources resource NOUN eurjchem-131 1 191     SPACE eurjchem-131 1 192 in in ADP eurjchem-131 1 193     SPACE eurjchem-131 1 194 west west PROPN eurjchem-131 1 195     SPACE eurjchem-131 1 196 china china PROPN eurjchem-131 1 197 , , PUNCT eurjchem-131 1 198     SPACE eurjchem-131 1 199 kunming kunming PROPN eurjchem-131 1 200     SPACE eurjchem-131 1 201 institute institute PROPN eurjchem-131 1 202     SPACE eurjchem-131 1 203 of of ADP eurjchem-131 1 204     SPACE eurjchem-131 1 205 botany botany NOUN eurjchem-131 1 206 , , PUNCT eurjchem-131 1 207     SPACE eurjchem-131 1 208 chinese chinese PROPN eurjchem-131 1 209     SPACE eurjchem-131 1 210 academy academy PROPN eurjchem-131 1 211     SPACE eurjchem-131 1 212 of of ADP eurjchem-131 1 213     SPACE eurjchem-131 1 214 science science NOUN eurjchem-131 1 215 , , PUNCT eurjchem-131 1 216       SPACE eurjchem-131 1 217 kunming kunming NOUN eurjchem-131 1 218 , , PUNCT eurjchem-131 1 219     SPACE eurjchem-131 1 220 yunnan yunnan NOUN eurjchem-131 1 221 , , PUNCT eurjchem-131 1 222     SPACE eurjchem-131 1 223 cn­650204 cn­650204 PROPN eurjchem-131 1 224 , , PUNCT eurjchem-131 1 225     SPACE eurjchem-131 1 226 china china PROPN eurjchem-131 1 227 . . PUNCT eurjchem-131 1 228     SPACE eurjchem-131 2 1 tel tel PROPN eurjchem-131 2 2 . . PUNCT eurjchem-131 2 3 : : PUNCT eurjchem-131 2 4     SPACE eurjchem-131 2 5 +86.871.5223257 +86.871.5223257 PROPN eurjchem-131 2 6 ; ; PUNCT eurjchem-131 2 7     SPACE eurjchem-131 2 8 fax fax NOUN eurjchem-131 2 9 : : PUNCT eurjchem-131 2 10     SPACE eurjchem-131 2 11 +86.871.5223255 +86.871.5223255 PROPN eurjchem-131 2 12 . . PUNCT eurjchem-131 2 13     SPACE eurjchem-131 2 14 e­mail e­mail NOUN eurjchem-131 2 15     SPACE eurjchem-131 2 16 address address NOUN eurjchem-131 2 17 : : PUNCT eurjchem-131 2 18     SPACE eurjchem-131 2 19 mhchiu@mail.kib.ac.cn mhchiu@mail.kib.ac.cn X eurjchem-131 2 20     SPACE eurjchem-131 2 21 ( ( PUNCT eurjchem-131 2 22 m.h m.h PROPN eurjchem-131 2 23 . . PROPN eurjchem-131 2 24     SPACE eurjchem-131 2 25 qui qui X eurjchem-131 2 26 ) ) PUNCT eurjchem-131 2 27 . . PUNCT eurjchem-131 2 28                                 SPACE eurjchem-131 2 29 article article NOUN eurjchem-131 2 30     SPACE eurjchem-131 2 31 information information NOUN eurjchem-131 2 32         SPACE eurjchem-131 2 33 abstract abstract ADJ eurjchem-131 2 34 received receive VERB eurjchem-131 2 35 : : PUNCT eurjchem-131 2 36     SPACE eurjchem-131 2 37 29 29 NUM eurjchem-131 2 38     SPACE eurjchem-131 2 39 may may AUX eurjchem-131 2 40     SPACE eurjchem-131 2 41 2010 2010 NUM eurjchem-131 2 42     SPACE eurjchem-131 2 43 received receive VERB eurjchem-131 2 44     SPACE eurjchem-131 2 45 in in ADP eurjchem-131 2 46     SPACE eurjchem-131 2 47 revised revise VERB eurjchem-131 2 48     SPACE eurjchem-131 2 49 form form NOUN eurjchem-131 2 50 : : PUNCT eurjchem-131 2 51     SPACE eurjchem-131 2 52 24 24 NUM eurjchem-131 2 53     SPACE eurjchem-131 2 54 september september PROPN eurjchem-131 2 55     SPACE eurjchem-131 2 56 2010 2010 NUM eurjchem-131 2 57     SPACE eurjchem-131 2 58 accepted accept VERB eurjchem-131 2 59 : : PUNCT eurjchem-131 2 60     SPACE eurjchem-131 2 61 18 18 NUM eurjchem-131 2 62     SPACE eurjchem-131 2 63 october october PROPN eurjchem-131 2 64     SPACE eurjchem-131 2 65 2010 2010 NUM eurjchem-131 2 66     SPACE eurjchem-131 2 67 online online NOUN eurjchem-131 2 68 : : PUNCT eurjchem-131 2 69     SPACE eurjchem-131 2 70 31 31 NUM eurjchem-131 2 71     SPACE eurjchem-131 2 72 december december PROPN eurjchem-131 2 73     SPACE eurjchem-131 2 74 2010 2010 NUM eurjchem-131 2 75     SPACE eurjchem-131 2 76 keywords keyword VERB eurjchem-131 2 77         SPACE eurjchem-131 2 78 one one NUM eurjchem-131 2 79     SPACE eurjchem-131 2 80 new new ADJ eurjchem-131 2 81     SPACE eurjchem-131 2 82 cucurbitane cucurbitane NOUN eurjchem-131 2 83     SPACE eurjchem-131 2 84 triterpenoid triterpenoid NOUN eurjchem-131 2 85     SPACE eurjchem-131 2 86 commonly commonly ADV eurjchem-131 2 87     SPACE eurjchem-131 2 88 named name VERB eurjchem-131 2 89     SPACE eurjchem-131 2 90 neokuguaglucoside neokuguaglucoside NOUN eurjchem-131 2 91 , , PUNCT eurjchem-131 2 92     SPACE eurjchem-131 2 93 together together ADV eurjchem-131 2 94     SPACE eurjchem-131 2 95 with with ADP eurjchem-131 2 96     SPACE eurjchem-131 2 97 three three NUM eurjchem-131 2 98     SPACE eurjchem-131 2 99 known know VERB eurjchem-131 2 100     SPACE eurjchem-131 2 101 compounds compound VERB eurjchem-131 2 102     SPACE eurjchem-131 2 103 momordicoside momordicoside NOUN eurjchem-131 2 104     SPACE eurjchem-131 2 105 m m PROPN eurjchem-131 2 106 , , PUNCT eurjchem-131 2 107     SPACE eurjchem-131 2 108 momordicoside momordicoside NOUN eurjchem-131 2 109     SPACE eurjchem-131 2 110 n n CCONJ eurjchem-131 2 111 , , PUNCT eurjchem-131 2 112     SPACE eurjchem-131 2 113 and and CCONJ eurjchem-131 2 114     SPACE eurjchem-131 2 115 momordicoside momordicoside NOUN eurjchem-131 2 116     SPACE eurjchem-131 2 117 a a PRON eurjchem-131 2 118     SPACE eurjchem-131 2 119 were be AUX eurjchem-131 2 120     SPACE eurjchem-131 2 121 isolated isolate VERB eurjchem-131 2 122     SPACE eurjchem-131 2 123 from from ADP eurjchem-131 2 124     SPACE eurjchem-131 2 125 the the DET eurjchem-131 2 126     SPACE eurjchem-131 2 127 fresh fresh ADJ eurjchem-131 2 128     SPACE eurjchem-131 2 129 fruits fruit NOUN eurjchem-131 2 130     SPACE eurjchem-131 2 131 of of ADP eurjchem-131 2 132     SPACE eurjchem-131 2 133 momordica momordica PROPN eurjchem-131 2 134     SPACE eurjchem-131 2 135 charantia charantia PROPN eurjchem-131 2 136 . . PUNCT eurjchem-131 2 137     SPACE eurjchem-131 3 1 the the DET eurjchem-131 3 2     SPACE eurjchem-131 3 3 new new ADJ eurjchem-131 3 4     SPACE eurjchem-131 3 5 one one NUM eurjchem-131 3 6 ’s ’s PART eurjchem-131 3 7     SPACE eurjchem-131 3 8 structure structure NOUN eurjchem-131 3 9     SPACE eurjchem-131 3 10 with with ADP eurjchem-131 3 11     SPACE eurjchem-131 3 12 an an DET eurjchem-131 3 13     SPACE eurjchem-131 3 14 interesting interesting ADJ eurjchem-131 3 15     SPACE eurjchem-131 3 16 sugar‐like sugar‐like ADJ eurjchem-131 3 17     SPACE eurjchem-131 3 18 groups group NOUN eurjchem-131 3 19     SPACE eurjchem-131 3 20 attached attach VERB eurjchem-131 3 21     SPACE eurjchem-131 3 22 to to ADP eurjchem-131 3 23     SPACE eurjchem-131 3 24 the the DET eurjchem-131 3 25     SPACE eurjchem-131 3 26 side side NOUN eurjchem-131 3 27     SPACE eurjchem-131 3 28 chain chain NOUN eurjchem-131 3 29     SPACE eurjchem-131 3 30 was be AUX eurjchem-131 3 31     SPACE eurjchem-131 3 32 elucidated elucidated ADJ eurjchem-131 3 33     SPACE eurjchem-131 3 34 by by ADP eurjchem-131 3 35     SPACE eurjchem-131 3 36 spectroscopic spectroscopic NOUN eurjchem-131 3 37     SPACE eurjchem-131 3 38 analysis analysis NOUN eurjchem-131 3 39     SPACE eurjchem-131 3 40 and and CCONJ eurjchem-131 3 41     SPACE eurjchem-131 3 42 semiepirical semiepirical ADJ eurjchem-131 3 43     SPACE eurjchem-131 3 44 ( ( PUNCT eurjchem-131 3 45 am1 am1 PROPN eurjchem-131 3 46 ) ) PUNCT eurjchem-131 3 47     SPACE eurjchem-131 3 48 quantum quantum NOUN eurjchem-131 3 49     SPACE eurjchem-131 3 50 chemical chemical NOUN eurjchem-131 3 51     SPACE eurjchem-131 3 52 method method NOUN eurjchem-131 3 53 . . PUNCT eurjchem-131 3 54     SPACE eurjchem-131 3 55 momordica momordica PROPN eurjchem-131 3 56     SPACE eurjchem-131 3 57 charantia charantia PROPN eurjchem-131 3 58     SPACE eurjchem-131 3 59 cucurbitane cucurbitane NOUN eurjchem-131 3 60     SPACE eurjchem-131 3 61 triterpenoids triterpenoids PROPN eurjchem-131 3 62     SPACE eurjchem-131 3 63 neokuguaglucoside neokuguaglucoside NOUN eurjchem-131 3 64     SPACE eurjchem-131 3 65 semi‐empirical semi‐empirical ADJ eurjchem-131 3 66     SPACE eurjchem-131 3 67 quantum quantum NOUN eurjchem-131 3 68     SPACE eurjchem-131 3 69 chemistry chemistry NOUN eurjchem-131 3 70     SPACE eurjchem-131 3 71 methods method NOUN eurjchem-131 3 72     SPACE eurjchem-131 4 1 am1 am1 PROPN eurjchem-131 4 2         SPACE eurjchem-131 4 3 1 1 NUM eurjchem-131 4 4 . . PUNCT eurjchem-131 4 5     SPACE eurjchem-131 4 6 introduction introduction NOUN eurjchem-131 4 7         SPACE eurjchem-131 4 8 the the DET eurjchem-131 4 9     SPACE eurjchem-131 4 10 plant plant NOUN eurjchem-131 4 11     SPACE eurjchem-131 4 12 momordica momordica PROPN eurjchem-131 4 13     SPACE eurjchem-131 4 14 charantia charantia PROPN eurjchem-131 4 15     SPACE eurjchem-131 4 16 l. l. PROPN eurjchem-131 4 17     SPACE eurjchem-131 4 18 is be AUX eurjchem-131 4 19     SPACE eurjchem-131 4 20 cultivated cultivate VERB eurjchem-131 4 21     SPACE eurjchem-131 4 22 in in ADP eurjchem-131 4 23     SPACE eurjchem-131 4 24 asian asian ADJ eurjchem-131 4 25     SPACE eurjchem-131 4 26 countries country NOUN eurjchem-131 4 27 . . PUNCT eurjchem-131 4 28     SPACE eurjchem-131 5 1 its its PRON eurjchem-131 5 2     SPACE eurjchem-131 5 3 fruit fruit NOUN eurjchem-131 5 4     SPACE eurjchem-131 5 5 was be AUX eurjchem-131 5 6     SPACE eurjchem-131 5 7 called call VERB eurjchem-131 5 8     SPACE eurjchem-131 5 9 “ " PUNCT eurjchem-131 5 10 kugua kugua PROPN eurjchem-131 5 11 ” " PUNCT eurjchem-131 5 12     SPACE eurjchem-131 5 13 in in ADP eurjchem-131 5 14     SPACE eurjchem-131 5 15 china china PROPN eurjchem-131 5 16     SPACE eurjchem-131 5 17 and and CCONJ eurjchem-131 5 18     SPACE eurjchem-131 5 19 bitter bitter ADJ eurjchem-131 5 20     SPACE eurjchem-131 5 21 melon melon NOUN eurjchem-131 5 22     SPACE eurjchem-131 5 23 in in ADP eurjchem-131 5 24     SPACE eurjchem-131 5 25 western western ADJ eurjchem-131 5 26     SPACE eurjchem-131 5 27 country country NOUN eurjchem-131 5 28 . . PUNCT eurjchem-131 5 29     SPACE eurjchem-131 6 1 it it PRON eurjchem-131 6 2     SPACE eurjchem-131 6 3 is be AUX eurjchem-131 6 4     SPACE eurjchem-131 6 5 a a DET eurjchem-131 6 6     SPACE eurjchem-131 6 7 favorable favorable ADJ eurjchem-131 6 8     SPACE eurjchem-131 6 9 vegetable vegetable NOUN eurjchem-131 6 10     SPACE eurjchem-131 6 11 in in ADP eurjchem-131 6 12     SPACE eurjchem-131 6 13 china china PROPN eurjchem-131 6 14     SPACE eurjchem-131 6 15 and and CCONJ eurjchem-131 6 16     SPACE eurjchem-131 6 17 becoming become VERB eurjchem-131 6 18     SPACE eurjchem-131 6 19 increasingly increasingly ADV eurjchem-131 6 20     SPACE eurjchem-131 6 21 popular popular ADJ eurjchem-131 6 22     SPACE eurjchem-131 6 23 as as ADP eurjchem-131 6 24     SPACE eurjchem-131 6 25 a a DET eurjchem-131 6 26     SPACE eurjchem-131 6 27 food food NOUN eurjchem-131 6 28     SPACE eurjchem-131 6 29 supplement supplement NOUN eurjchem-131 6 30     SPACE eurjchem-131 6 31 to to PART eurjchem-131 6 32     SPACE eurjchem-131 6 33 lower low ADJ eurjchem-131 6 34     SPACE eurjchem-131 6 35 blood blood NOUN eurjchem-131 6 36     SPACE eurjchem-131 6 37 glucose glucose NOUN eurjchem-131 6 38     SPACE eurjchem-131 6 39 in in ADP eurjchem-131 6 40     SPACE eurjchem-131 6 41 western western ADJ eurjchem-131 6 42     SPACE eurjchem-131 6 43 country country NOUN eurjchem-131 6 44     SPACE eurjchem-131 7 1 [ [ X eurjchem-131 7 2 1 1 NUM eurjchem-131 7 3 ] ] PUNCT eurjchem-131 7 4 . . PUNCT eurjchem-131 7 5     SPACE eurjchem-131 7 6 recently recently ADV eurjchem-131 7 7 , , PUNCT eurjchem-131 7 8     SPACE eurjchem-131 7 9 studies study NOUN eurjchem-131 7 10     SPACE eurjchem-131 7 11 discovered discover VERB eurjchem-131 7 12     SPACE eurjchem-131 7 13 that that SCONJ eurjchem-131 7 14     SPACE eurjchem-131 7 15 the the DET eurjchem-131 7 16     SPACE eurjchem-131 7 17 triterpenes triterpene NOUN eurjchem-131 7 18     SPACE eurjchem-131 7 19 from from ADP eurjchem-131 7 20     SPACE eurjchem-131 7 21 this this DET eurjchem-131 7 22     SPACE eurjchem-131 7 23 genus genus NOUN eurjchem-131 7 24     SPACE eurjchem-131 7 25 showed show VERB eurjchem-131 7 26     SPACE eurjchem-131 7 27 biological biological ADJ eurjchem-131 7 28     SPACE eurjchem-131 7 29 activities activity NOUN eurjchem-131 7 30     SPACE eurjchem-131 7 31 such such ADJ eurjchem-131 7 32     SPACE eurjchem-131 7 33 as as ADP eurjchem-131 7 34     SPACE eurjchem-131 7 35 antidiabetic antidiabetic ADJ eurjchem-131 7 36 , , PUNCT eurjchem-131 7 37     SPACE eurjchem-131 7 38 anti‐hiv anti‐hiv PROPN eurjchem-131 7 39 , , PUNCT eurjchem-131 7 40     SPACE eurjchem-131 7 41 anti‐cancer anti‐cancer NOUN eurjchem-131 7 42 , , PUNCT eurjchem-131 7 43     SPACE eurjchem-131 7 44 and and CCONJ eurjchem-131 7 45     SPACE eurjchem-131 7 46 so so ADV eurjchem-131 7 47     SPACE eurjchem-131 7 48 on on ADP eurjchem-131 7 49     SPACE eurjchem-131 7 50 [ [ X eurjchem-131 7 51 2‐4 2‐4 NUM eurjchem-131 7 52 ] ] PUNCT eurjchem-131 7 53 . . PUNCT eurjchem-131 7 54     SPACE eurjchem-131 8 1 in in ADP eurjchem-131 8 2     SPACE eurjchem-131 8 3 this this DET eurjchem-131 8 4     SPACE eurjchem-131 8 5 report report NOUN eurjchem-131 8 6 , , PUNCT eurjchem-131 8 7     SPACE eurjchem-131 8 8 we we PRON eurjchem-131 8 9     SPACE eurjchem-131 8 10 have have AUX eurjchem-131 8 11     SPACE eurjchem-131 8 12 examined examine VERB eurjchem-131 8 13     SPACE eurjchem-131 8 14 the the DET eurjchem-131 8 15     SPACE eurjchem-131 8 16 methanolic methanolic NOUN eurjchem-131 8 17     SPACE eurjchem-131 8 18 extract extract NOUN eurjchem-131 8 19     SPACE eurjchem-131 8 20 of of ADP eurjchem-131 8 21     SPACE eurjchem-131 8 22 the the DET eurjchem-131 8 23     SPACE eurjchem-131 8 24 fresh fresh ADJ eurjchem-131 8 25     SPACE eurjchem-131 8 26 fruits fruit NOUN eurjchem-131 8 27     SPACE eurjchem-131 8 28 of of ADP eurjchem-131 8 29     SPACE eurjchem-131 8 30 m. m. NOUN eurjchem-131 8 31     SPACE eurjchem-131 8 32 charantia charantia PROPN eurjchem-131 8 33     SPACE eurjchem-131 8 34 and and CCONJ eurjchem-131 8 35     SPACE eurjchem-131 8 36 have have AUX eurjchem-131 8 37     SPACE eurjchem-131 8 38 isolated isolate VERB eurjchem-131 8 39     SPACE eurjchem-131 8 40 one one NUM eurjchem-131 8 41     SPACE eurjchem-131 8 42 new new ADJ eurjchem-131 8 43     SPACE eurjchem-131 8 44 triterpenoid triterpenoid NOUN eurjchem-131 8 45     SPACE eurjchem-131 8 46 named name VERB eurjchem-131 8 47     SPACE eurjchem-131 8 48 neokuguaglucoside neokuguaglucoside NOUN eurjchem-131 8 49     SPACE eurjchem-131 8 50 ( ( PUNCT eurjchem-131 8 51 1 1 NUM eurjchem-131 8 52 ) ) PUNCT eurjchem-131 8 53     SPACE eurjchem-131 8 54 ( ( PUNCT eurjchem-131 8 55 figure figure NOUN eurjchem-131 8 56     SPACE eurjchem-131 8 57 1 1 NUM eurjchem-131 8 58 ) ) PUNCT eurjchem-131 8 59     SPACE eurjchem-131 8 60 together together ADV eurjchem-131 8 61     SPACE eurjchem-131 8 62 with with ADP eurjchem-131 8 63     SPACE eurjchem-131 8 64 three three NUM eurjchem-131 8 65     SPACE eurjchem-131 8 66 known know VERB eurjchem-131 8 67     SPACE eurjchem-131 8 68 compounds compound VERB eurjchem-131 8 69     SPACE eurjchem-131 8 70 momordicoside momordicoside NOUN eurjchem-131 8 71     SPACE eurjchem-131 8 72 m m VERB eurjchem-131 8 73     SPACE eurjchem-131 8 74 ( ( PUNCT eurjchem-131 8 75 2 2 NUM eurjchem-131 8 76 ) ) PUNCT eurjchem-131 8 77     SPACE eurjchem-131 9 1 [ [ X eurjchem-131 9 2 5 5 NUM eurjchem-131 9 3 ] ] PUNCT eurjchem-131 9 4 , , PUNCT eurjchem-131 9 5     SPACE eurjchem-131 9 6 momordicoside momordicoside NOUN eurjchem-131 9 7     SPACE eurjchem-131 9 8 n n CCONJ eurjchem-131 9 9     SPACE eurjchem-131 9 10 ( ( PUNCT eurjchem-131 9 11 3 3 NUM eurjchem-131 9 12 ) ) PUNCT eurjchem-131 9 13     SPACE eurjchem-131 10 1 [ [ X eurjchem-131 10 2 5 5 NUM eurjchem-131 10 3 ] ] PUNCT eurjchem-131 10 4 , , PUNCT eurjchem-131 10 5     SPACE eurjchem-131 10 6 momordi‐ momordi‐ PROPN eurjchem-131 10 7 coside coside PROPN eurjchem-131 10 8     SPACE eurjchem-131 10 9 a a DET eurjchem-131 10 10     SPACE eurjchem-131 10 11 ( ( PUNCT eurjchem-131 10 12 4 4 NUM eurjchem-131 10 13 ) ) PUNCT eurjchem-131 10 14     SPACE eurjchem-131 11 1 [ [ X eurjchem-131 11 2 6 6 NUM eurjchem-131 11 3 ] ] PUNCT eurjchem-131 11 4 . . PUNCT eurjchem-131 11 5     SPACE eurjchem-131 11 6 herein herein NOUN eurjchem-131 11 7 , , PUNCT eurjchem-131 11 8     SPACE eurjchem-131 11 9 we we PRON eurjchem-131 11 10     SPACE eurjchem-131 11 11 reported report VERB eurjchem-131 11 12     SPACE eurjchem-131 11 13 the the DET eurjchem-131 11 14     SPACE eurjchem-131 11 15 isolation isolation NOUN eurjchem-131 11 16     SPACE eurjchem-131 11 17 and and CCONJ eurjchem-131 11 18     SPACE eurjchem-131 11 19 structural structural ADJ eurjchem-131 11 20     SPACE eurjchem-131 11 21 elucidation elucidation NOUN eurjchem-131 11 22     SPACE eurjchem-131 11 23 of of ADP eurjchem-131 11 24     SPACE eurjchem-131 11 25 the the DET eurjchem-131 11 26     SPACE eurjchem-131 11 27 new new ADJ eurjchem-131 11 28     SPACE eurjchem-131 11 29 constituent constituent NOUN eurjchem-131 11 30     SPACE eurjchem-131 11 31 with with ADP eurjchem-131 11 32     SPACE eurjchem-131 11 33 an an DET eurjchem-131 11 34     SPACE eurjchem-131 11 35 interesting interesting ADJ eurjchem-131 11 36     SPACE eurjchem-131 11 37 sugar‐like sugar‐like ADJ eurjchem-131 11 38     SPACE eurjchem-131 11 39 group group NOUN eurjchem-131 11 40     SPACE eurjchem-131 11 41 attached attach VERB eurjchem-131 11 42     SPACE eurjchem-131 11 43 to to ADP eurjchem-131 11 44     SPACE eurjchem-131 11 45 the the DET eurjchem-131 11 46     SPACE eurjchem-131 11 47 side side NOUN eurjchem-131 11 48     SPACE eurjchem-131 11 49 chain chain NOUN eurjchem-131 11 50     SPACE eurjchem-131 11 51 based base VERB eurjchem-131 11 52     SPACE eurjchem-131 11 53 on on ADP eurjchem-131 11 54     SPACE eurjchem-131 11 55 spectroscopic spectroscopic NOUN eurjchem-131 11 56     SPACE eurjchem-131 11 57 analysis analysis NOUN eurjchem-131 11 58     SPACE eurjchem-131 11 59 and and CCONJ eurjchem-131 11 60     SPACE eurjchem-131 11 61 am1 am1 PROPN eurjchem-131 11 62     SPACE eurjchem-131 11 63 quantum quantum NOUN eurjchem-131 11 64     SPACE eurjchem-131 11 65 chemical chemical NOUN eurjchem-131 11 66     SPACE eurjchem-131 11 67 method method NOUN eurjchem-131 11 68 . . PUNCT eurjchem-131 11 69         SPACE eurjchem-131 11 70 figure figure NOUN eurjchem-131 11 71     SPACE eurjchem-131 11 72 1 1 NUM eurjchem-131 11 73 . . PUNCT eurjchem-131 11 74     SPACE eurjchem-131 11 75 structure structure NOUN eurjchem-131 11 76     SPACE eurjchem-131 11 77 of of ADP eurjchem-131 11 78 neokuguaglucoside neokuguaglucoside NOUN eurjchem-131 11 79     SPACE eurjchem-131 11 80 ( ( PUNCT eurjchem-131 11 81 1 1 NUM eurjchem-131 11 82 ) ) PUNCT eurjchem-131 11 83 . . PUNCT eurjchem-131 11 84         SPACE eurjchem-131 12 1 2 2 NUM eurjchem-131 12 2 . . PUNCT eurjchem-131 12 3     SPACE eurjchem-131 12 4 experimental experimental ADJ eurjchem-131 12 5         SPACE eurjchem-131 12 6 2.1 2.1 NUM eurjchem-131 12 7 . . PUNCT eurjchem-131 12 8     SPACE eurjchem-131 12 9 general general ADJ eurjchem-131 12 10     SPACE eurjchem-131 12 11 experimental experimental ADJ eurjchem-131 12 12     SPACE eurjchem-131 12 13 procedures procedure NOUN eurjchem-131 12 14         SPACE eurjchem-131 12 15 optical optical ADJ eurjchem-131 12 16     SPACE eurjchem-131 12 17 rotations rotation NOUN eurjchem-131 12 18     SPACE eurjchem-131 12 19 were be AUX eurjchem-131 12 20     SPACE eurjchem-131 12 21 recorded record VERB eurjchem-131 12 22     SPACE eurjchem-131 12 23 on on ADP eurjchem-131 12 24     SPACE eurjchem-131 12 25 a a DET eurjchem-131 12 26     SPACE eurjchem-131 12 27 horiba horiba PROPN eurjchem-131 12 28     SPACE eurjchem-131 12 29 sepa‐300 sepa‐300 ADJ eurjchem-131 12 30     SPACE eurjchem-131 12 31 digital digital ADJ eurjchem-131 12 32     SPACE eurjchem-131 12 33 polarimeter polarimeter NOUN eurjchem-131 12 34     SPACE eurjchem-131 12 35 using use VERB eurjchem-131 12 36     SPACE eurjchem-131 12 37 a a DET eurjchem-131 12 38     SPACE eurjchem-131 12 39 sodium sodium NOUN eurjchem-131 12 40     SPACE eurjchem-131 12 41 lamp lamp NOUN eurjchem-131 12 42 . . PUNCT eurjchem-131 12 43     SPACE eurjchem-131 13 1 ir ir PROPN eurjchem-131 13 2     SPACE eurjchem-131 13 3 spectra spectra NOUN eurjchem-131 13 4     SPACE eurjchem-131 13 5 were be AUX eurjchem-131 13 6     SPACE eurjchem-131 13 7 measured measure VERB eurjchem-131 13 8     SPACE eurjchem-131 13 9 using use VERB eurjchem-131 13 10     SPACE eurjchem-131 13 11 a a DET eurjchem-131 13 12     SPACE eurjchem-131 13 13 bio‐rad bio‐rad NOUN eurjchem-131 13 14     SPACE eurjchem-131 13 15 fts‐135 fts‐135 PROPN eurjchem-131 13 16     SPACE eurjchem-131 13 17 spectrometer spectrometer NOUN eurjchem-131 13 18 . . PUNCT eurjchem-131 13 19     SPACE eurjchem-131 13 20 fabms fabms VERB eurjchem-131 13 21     SPACE eurjchem-131 13 22 and and CCONJ eurjchem-131 13 23     SPACE eurjchem-131 13 24 hresims hresim NOUN eurjchem-131 13 25     SPACE eurjchem-131 13 26 were be AUX eurjchem-131 13 27     SPACE eurjchem-131 13 28 performed perform VERB eurjchem-131 13 29     SPACE eurjchem-131 13 30 on on ADP eurjchem-131 13 31     SPACE eurjchem-131 13 32 a a DET eurjchem-131 13 33     SPACE eurjchem-131 13 34 vg vg NOUN eurjchem-131 13 35     SPACE eurjchem-131 13 36 auto auto NOUN eurjchem-131 13 37     SPACE eurjchem-131 13 38 spec‐3000 spec‐3000 PROPN eurjchem-131 13 39     SPACE eurjchem-131 13 40 spectrometer spectrometer NOUN eurjchem-131 13 41 . . PUNCT eurjchem-131 13 42     SPACE eurjchem-131 13 43 column column NOUN eurjchem-131 13 44     SPACE eurjchem-131 13 45 chromatography chromatography NOUN eurjchem-131 13 46     SPACE eurjchem-131 13 47 was be AUX eurjchem-131 13 48     SPACE eurjchem-131 13 49 carried carry VERB eurjchem-131 13 50     SPACE eurjchem-131 13 51 out out ADP eurjchem-131 13 52     SPACE eurjchem-131 13 53 on on ADP eurjchem-131 13 54     SPACE eurjchem-131 13 55 normal normal ADJ eurjchem-131 13 56     SPACE eurjchem-131 13 57 phase phase NOUN eurjchem-131 13 58     SPACE eurjchem-131 13 59 chromatographic chromatographic ADJ eurjchem-131 13 60     SPACE eurjchem-131 13 61 ( ( PUNCT eurjchem-131 13 62 qingdao qingdao PROPN eurjchem-131 13 63     SPACE eurjchem-131 13 64 marine marine PROPN eurjchem-131 13 65     SPACE eurjchem-131 13 66 chemical chemical NOUN eurjchem-131 13 67 , , PUNCT eurjchem-131 13 68     SPACE eurjchem-131 13 69 china china PROPN eurjchem-131 13 70 ) ) PUNCT eurjchem-131 13 71 , , PUNCT eurjchem-131 13 72     SPACE eurjchem-131 13 73 sephadex sephadex NOUN eurjchem-131 13 74     SPACE eurjchem-131 13 75 lh‐20 lh‐20 PROPN eurjchem-131 13 76     SPACE eurjchem-131 13 77 ( ( PUNCT eurjchem-131 13 78 pharmacia pharmacia PROPN eurjchem-131 13 79     SPACE eurjchem-131 13 80 fine fine ADJ eurjchem-131 13 81     SPACE eurjchem-131 13 82 chemical chemical PROPN eurjchem-131 13 83     SPACE eurjchem-131 13 84 co. co. PROPN eurjchem-131 13 85     SPACE eurjchem-131 13 86 ltd ltd PROPN eurjchem-131 13 87 . . PROPN eurjchem-131 13 88 ) ) PUNCT eurjchem-131 13 89 , , PUNCT eurjchem-131 13 90     SPACE eurjchem-131 13 91 rp‐18 rp‐18 VERB eurjchem-131 13 92     SPACE eurjchem-131 13 93 ( ( PUNCT eurjchem-131 13 94 merck merck PROPN eurjchem-131 13 95 , , PUNCT eurjchem-131 13 96     SPACE eurjchem-131 13 97 darmstadt darmstadt PROPN eurjchem-131 13 98 , , PUNCT eurjchem-131 13 99     SPACE eurjchem-131 13 100 germany germany PROPN eurjchem-131 13 101 ) ) PUNCT eurjchem-131 13 102 . . PUNCT eurjchem-131 13 103     SPACE eurjchem-131 13 104 nmr nmr NOUN eurjchem-131 13 105     SPACE eurjchem-131 13 106 spectra spectra NOUN eurjchem-131 13 107     SPACE eurjchem-131 13 108 were be AUX eurjchem-131 13 109     SPACE eurjchem-131 13 110 recorded record VERB eurjchem-131 13 111     SPACE eurjchem-131 13 112 on on ADP eurjchem-131 13 113     SPACE eurjchem-131 13 114 bruker bruker NOUN eurjchem-131 13 115     SPACE eurjchem-131 13 116 av‐400 av‐400 PROPN eurjchem-131 13 117     SPACE eurjchem-131 13 118 spectrometers spectrometer NOUN eurjchem-131 13 119     SPACE eurjchem-131 13 120 with with ADP eurjchem-131 13 121     SPACE eurjchem-131 13 122 tms tms NOUN eurjchem-131 13 123     SPACE eurjchem-131 13 124 as as ADP eurjchem-131 13 125     SPACE eurjchem-131 13 126 internal internal ADJ eurjchem-131 13 127     SPACE eurjchem-131 13 128 standard standard NOUN eurjchem-131 13 129 . . PUNCT eurjchem-131 13 130         SPACE eurjchem-131 14 1 2.2 2.2 NUM eurjchem-131 14 2 . . PUNCT eurjchem-131 14 3     SPACE eurjchem-131 14 4 plant plant NOUN eurjchem-131 14 5     SPACE eurjchem-131 14 6 material material NOUN eurjchem-131 14 7         SPACE eurjchem-131 14 8 the the DET eurjchem-131 14 9     SPACE eurjchem-131 14 10 fresh fresh ADJ eurjchem-131 14 11     SPACE eurjchem-131 14 12 fruits fruit NOUN eurjchem-131 14 13     SPACE eurjchem-131 14 14 of of ADP eurjchem-131 14 15     SPACE eurjchem-131 14 16 m. m. NOUN eurjchem-131 14 17     SPACE eurjchem-131 14 18 charantia charantia PROPN eurjchem-131 14 19     SPACE eurjchem-131 14 20 were be AUX eurjchem-131 14 21     SPACE eurjchem-131 14 22 purchased purchase VERB eurjchem-131 14 23     SPACE eurjchem-131 14 24 from from ADP eurjchem-131 14 25     SPACE eurjchem-131 14 26 the the DET eurjchem-131 14 27     SPACE eurjchem-131 14 28 chengjiang chengjiang NOUN eurjchem-131 14 29 , , PUNCT eurjchem-131 14 30     SPACE eurjchem-131 14 31 yuxi yuxi NOUN eurjchem-131 14 32 , , PUNCT eurjchem-131 14 33     SPACE eurjchem-131 14 34 yunnan yunnan NOUN eurjchem-131 14 35     SPACE eurjchem-131 14 36 in in ADP eurjchem-131 14 37     SPACE eurjchem-131 14 38 august august PROPN eurjchem-131 14 39     SPACE eurjchem-131 14 40 2008 2008 NUM eurjchem-131 14 41 , , PUNCT eurjchem-131 14 42     SPACE eurjchem-131 14 43 and and CCONJ eurjchem-131 14 44     SPACE eurjchem-131 14 45 identified identify VERB eurjchem-131 14 46     SPACE eurjchem-131 14 47 by by ADP eurjchem-131 14 48     SPACE eurjchem-131 14 49 prof prof NOUN eurjchem-131 14 50 . . PUNCT eurjchem-131 14 51     SPACE eurjchem-131 15 1 shukun shukun PROPN eurjchem-131 15 2     SPACE eurjchem-131 15 3 chen chen PROPN eurjchem-131 15 4 . . PUNCT eurjchem-131 15 5         SPACE eurjchem-131 16 1 2.3 2.3 NUM eurjchem-131 16 2 . . PUNCT eurjchem-131 16 3     SPACE eurjchem-131 17 1 extraction extraction NOUN eurjchem-131 17 2     SPACE eurjchem-131 17 3 and and CCONJ eurjchem-131 17 4     SPACE eurjchem-131 17 5 isolation isolation NOUN eurjchem-131 17 6           SPACE eurjchem-131 17 7 dried dry VERB eurjchem-131 17 8     SPACE eurjchem-131 17 9 and and CCONJ eurjchem-131 17 10     SPACE eurjchem-131 17 11 powdered powdered ADJ eurjchem-131 17 12     SPACE eurjchem-131 17 13 fruits fruit NOUN eurjchem-131 17 14     SPACE eurjchem-131 17 15 of of ADP eurjchem-131 17 16     SPACE eurjchem-131 17 17 m. m. NOUN eurjchem-131 17 18     SPACE eurjchem-131 17 19 charantia charantia PROPN eurjchem-131 17 20     SPACE eurjchem-131 17 21 ( ( PUNCT eurjchem-131 17 22 35 35 NUM eurjchem-131 17 23     SPACE eurjchem-131 17 24 kg kg NOUN eurjchem-131 17 25 ) ) PUNCT eurjchem-131 17 26     SPACE eurjchem-131 17 27 were be AUX eurjchem-131 17 28     SPACE eurjchem-131 17 29 extracted extract VERB eurjchem-131 17 30     SPACE eurjchem-131 17 31 with with ADP eurjchem-131 17 32     SPACE eurjchem-131 17 33 meoh meoh PROPN eurjchem-131 17 34 . . PUNCT eurjchem-131 17 35     SPACE eurjchem-131 18 1 removal removal NOUN eurjchem-131 18 2     SPACE eurjchem-131 18 3 of of ADP eurjchem-131 18 4     SPACE eurjchem-131 18 5 solvent solvent NOUN eurjchem-131 18 6     SPACE eurjchem-131 18 7 in in ADP eurjchem-131 18 8     SPACE eurjchem-131 18 9 a a DET eurjchem-131 18 10     SPACE eurjchem-131 18 11 vacuum vacuum NOUN eurjchem-131 18 12     SPACE eurjchem-131 18 13 gave give VERB eurjchem-131 18 14     SPACE eurjchem-131 18 15 the the DET eurjchem-131 18 16     SPACE eurjchem-131 18 17 meoh meoh NOUN eurjchem-131 18 18     SPACE eurjchem-131 18 19 extract extract NOUN eurjchem-131 18 20     SPACE eurjchem-131 18 21 ( ( PUNCT eurjchem-131 18 22 700 700 NUM eurjchem-131 18 23     SPACE eurjchem-131 18 24 g g NOUN eurjchem-131 18 25 ) ) PUNCT eurjchem-131 18 26 , , PUNCT eurjchem-131 18 27     SPACE eurjchem-131 18 28 which which PRON eurjchem-131 18 29     SPACE eurjchem-131 18 30 was be AUX eurjchem-131 18 31     SPACE eurjchem-131 18 32 partitioned partition VERB eurjchem-131 18 33     SPACE eurjchem-131 18 34 in in ADP eurjchem-131 18 35     SPACE eurjchem-131 18 36 water water NOUN eurjchem-131 18 37     SPACE eurjchem-131 18 38 and and CCONJ eurjchem-131 18 39     SPACE eurjchem-131 18 40 extracted extract VERB eurjchem-131 18 41     SPACE eurjchem-131 18 42 with with ADP eurjchem-131 18 43     SPACE eurjchem-131 18 44 petroleum petroleum NOUN eurjchem-131 18 45     SPACE eurjchem-131 18 46 ether ether NOUN eurjchem-131 18 47 , , PUNCT eurjchem-131 18 48     SPACE eurjchem-131 18 49 ethyl ethyl PROPN eurjchem-131 18 50     SPACE eurjchem-131 18 51 acetate acetate NOUN eurjchem-131 18 52 , , PUNCT eurjchem-131 18 53     SPACE eurjchem-131 18 54 and and CCONJ eurjchem-131 18 55     SPACE eurjchem-131 18 56 n‐buoh n‐buoh PROPN eurjchem-131 18 57 . . PUNCT eurjchem-131 18 58     SPACE eurjchem-131 18 59 the the DET eurjchem-131 18 60     SPACE eurjchem-131 18 61 n‐buoh n‐buoh NOUN eurjchem-131 18 62     SPACE eurjchem-131 18 63 layer layer NOUN eurjchem-131 18 64     SPACE eurjchem-131 18 65 was be AUX eurjchem-131 18 66     SPACE eurjchem-131 18 67 concentrated concentrate VERB eurjchem-131 18 68     SPACE eurjchem-131 18 69 and and CCONJ eurjchem-131 18 70     SPACE eurjchem-131 18 71 the the DET eurjchem-131 18 72     SPACE eurjchem-131 18 73 residue residue NOUN eurjchem-131 18 74     SPACE eurjchem-131 18 75 ( ( PUNCT eurjchem-131 18 76 300 300 NUM eurjchem-131 18 77     SPACE eurjchem-131 18 78 g g NOUN eurjchem-131 18 79 ) ) PUNCT eurjchem-131 18 80     SPACE eurjchem-131 18 81 was be AUX eurjchem-131 18 82     SPACE eurjchem-131 18 83 chromatographed chromatographe VERB eurjchem-131 18 84     SPACE eurjchem-131 18 85 on on ADP eurjchem-131 18 86     SPACE eurjchem-131 18 87 a a DET eurjchem-131 18 88     SPACE eurjchem-131 18 89 d101 d101 PROPN eurjchem-131 18 90     SPACE eurjchem-131 18 91 resin resin NOUN eurjchem-131 18 92     SPACE eurjchem-131 18 93 column column NOUN eurjchem-131 18 94 , , PUNCT eurjchem-131 18 95     SPACE eurjchem-131 18 96 eluted elute VERB eurjchem-131 18 97     SPACE eurjchem-131 18 98 with with ADP eurjchem-131 18 99     SPACE eurjchem-131 18 100 water water NOUN eurjchem-131 18 101 , , PUNCT eurjchem-131 18 102     SPACE eurjchem-131 18 103 meoh meoh NOUN eurjchem-131 18 104 , , PUNCT eurjchem-131 18 105     SPACE eurjchem-131 18 106 and and CCONJ eurjchem-131 18 107     SPACE eurjchem-131 18 108 ( ( PUNCT eurjchem-131 18 109 me)2co me)2co AUX eurjchem-131 18 110 . . NOUN eurjchem-131 18 111     SPACE eurjchem-131 18 112 the the DET eurjchem-131 18 113     SPACE eurjchem-131 18 114 meoh meoh NOUN eurjchem-131 18 115     SPACE eurjchem-131 18 116 residue residue NOUN eurjchem-131 18 117     SPACE eurjchem-131 18 118 was be AUX eurjchem-131 18 119     SPACE eurjchem-131 18 120 fractionated fractionate VERB eurjchem-131 18 121     SPACE eurjchem-131 18 122 by by ADP eurjchem-131 18 123     SPACE eurjchem-131 18 124 column column NOUN eurjchem-131 18 125     SPACE eurjchem-131 18 126 chromatography chromatography NOUN eurjchem-131 18 127     SPACE eurjchem-131 18 128 on on ADP eurjchem-131 18 129     SPACE eurjchem-131 18 130 normal‐phase normal‐phase NOUN eurjchem-131 18 131     SPACE eurjchem-131 18 132 silica silica NOUN eurjchem-131 18 133     SPACE eurjchem-131 18 134 gel gel NOUN eurjchem-131 18 135 , , PUNCT eurjchem-131 18 136     SPACE eurjchem-131 18 137 eluted elute VERB eurjchem-131 18 138     SPACE eurjchem-131 18 139 with with ADP eurjchem-131 18 140     SPACE eurjchem-131 18 141 gradient gradient NOUN eurjchem-131 18 142     SPACE eurjchem-131 18 143 chcl3 chcl3 PROPN eurjchem-131 18 144 / / SYM eurjchem-131 18 145 meoh meoh PROPN eurjchem-131 18 146     SPACE eurjchem-131 18 147 ( ( PUNCT eurjchem-131 18 148 30:1 30:1 NUM eurjchem-131 18 149 , , PUNCT eurjchem-131 18 150     SPACE eurjchem-131 18 151 10:1 10:1 NUM eurjchem-131 18 152 , , PUNCT eurjchem-131 18 153     SPACE eurjchem-131 18 154 5:1 5:1 NUM eurjchem-131 18 155 , , PUNCT eurjchem-131 18 156     SPACE eurjchem-131 18 157 3:1 3:1 NOUN eurjchem-131 18 158 , , PUNCT eurjchem-131 18 159     SPACE eurjchem-131 18 160 1:1 1:1 NUM eurjchem-131 18 161 , , PUNCT eurjchem-131 18 162     SPACE eurjchem-131 18 163 0:1 0:1 NUM eurjchem-131 18 164 ) ) PUNCT eurjchem-131 18 165     SPACE eurjchem-131 18 166 afforded afford VERB eurjchem-131 18 167     SPACE eurjchem-131 18 168 six six NUM eurjchem-131 18 169     SPACE eurjchem-131 18 170 fractions fraction NOUN eurjchem-131 18 171     SPACE eurjchem-131 18 172 ( ( PUNCT eurjchem-131 18 173 fr.1‐fr.6 fr.1‐fr.6 PROPN eurjchem-131 18 174 ) ) PUNCT eurjchem-131 18 175 . . PUNCT eurjchem-131 18 176     SPACE eurjchem-131 19 1 compounds compound VERB eurjchem-131 19 2     SPACE eurjchem-131 19 3 1 1 NUM eurjchem-131 19 4     SPACE eurjchem-131 19 5 ( ( PUNCT eurjchem-131 19 6 23 23 NUM eurjchem-131 19 7     SPACE eurjchem-131 19 8 mg mg PROPN eurjchem-131 19 9 ) ) PUNCT eurjchem-131 19 10 , , PUNCT eurjchem-131 19 11     SPACE eurjchem-131 19 12 2 2 NUM eurjchem-131 19 13     SPACE eurjchem-131 19 14 ( ( PUNCT eurjchem-131 19 15 29 29 NUM eurjchem-131 19 16     SPACE eurjchem-131 19 17 mg mg NOUN eurjchem-131 19 18 ) ) PUNCT eurjchem-131 19 19 , , PUNCT eurjchem-131 19 20     SPACE eurjchem-131 19 21 3 3 NUM eurjchem-131 19 22     SPACE eurjchem-131 19 23 ( ( PUNCT eurjchem-131 19 24 30 30 NUM eurjchem-131 19 25     SPACE eurjchem-131 19 26 mg mg NOUN eurjchem-131 19 27 ) ) PUNCT eurjchem-131 19 28 , , PUNCT eurjchem-131 19 29     SPACE eurjchem-131 19 30 4 4 NUM eurjchem-131 19 31     SPACE eurjchem-131 19 32 ( ( PUNCT eurjchem-131 19 33 250 250 NUM eurjchem-131 19 34     SPACE eurjchem-131 19 35 mg mg NOUN eurjchem-131 19 36 ) ) PUNCT eurjchem-131 19 37     SPACE eurjchem-131 19 38 were be AUX eurjchem-131 19 39     SPACE eurjchem-131 19 40 isolated isolate VERB eurjchem-131 19 41     SPACE eurjchem-131 19 42 from from ADP eurjchem-131 19 43     SPACE eurjchem-131 19 44 fr.5 fr.5 PROPN eurjchem-131 19 45     SPACE eurjchem-131 19 46 by by ADP eurjchem-131 19 47     SPACE eurjchem-131 19 48 using use VERB eurjchem-131 19 49     SPACE eurjchem-131 19 50 chroma‐ chroma‐ NOUN eurjchem-131 19 51 tographic tographic ADJ eurjchem-131 19 52       SPACE eurjchem-131 19 53 column column NOUN eurjchem-131 19 54       SPACE eurjchem-131 19 55 on on ADP eurjchem-131 19 56       SPACE eurjchem-131 19 57 normal‐phase normal‐phase NOUN eurjchem-131 19 58     SPACE eurjchem-131 19 59 silica silica NOUN eurjchem-131 19 60       SPACE eurjchem-131 19 61 gel gel NOUN eurjchem-131 19 62       SPACE eurjchem-131 19 63 column column NOUN eurjchem-131 19 64       SPACE eurjchem-131 19 65 liu liu PROPN eurjchem-131 19 66     SPACE eurjchem-131 19 67 et et PROPN eurjchem-131 19 68     SPACE eurjchem-131 19 69 al al PROPN eurjchem-131 19 70 . . PROPN eurjchem-131 19 71       SPACE eurjchem-131 19 72 / / SYM eurjchem-131 19 73     SPACE eurjchem-131 19 74 european european ADJ eurjchem-131 19 75     SPACE eurjchem-131 19 76 journal journal NOUN eurjchem-131 19 77     SPACE eurjchem-131 19 78 of of ADP eurjchem-131 19 79     SPACE eurjchem-131 19 80 chemistry chemistry NOUN eurjchem-131 19 81     SPACE eurjchem-131 19 82 1 1 NUM eurjchem-131 19 83     SPACE eurjchem-131 19 84 ( ( PUNCT eurjchem-131 19 85 4 4 NUM eurjchem-131 19 86 ) ) PUNCT eurjchem-131 19 87     SPACE eurjchem-131 19 88 ( ( PUNCT eurjchem-131 19 89 2010 2010 NUM eurjchem-131 19 90 ) ) PUNCT eurjchem-131 19 91     SPACE eurjchem-131 19 92 294­296 294­296 NOUN eurjchem-131 19 93     SPACE eurjchem-131 19 94 295 295 NUM eurjchem-131 19 95     SPACE eurjchem-131 19 96 table table NOUN eurjchem-131 19 97     SPACE eurjchem-131 19 98 1 1 NUM eurjchem-131 19 99 . . PUNCT eurjchem-131 19 100     SPACE eurjchem-131 19 101 the the DET eurjchem-131 19 102     SPACE eurjchem-131 19 103 1h 1h NUM eurjchem-131 19 104     SPACE eurjchem-131 19 105 and and CCONJ eurjchem-131 19 106     SPACE eurjchem-131 19 107 13c 13c NOUN eurjchem-131 19 108     SPACE eurjchem-131 19 109 nmr nmr NOUN eurjchem-131 19 110     SPACE eurjchem-131 19 111 data datum NOUN eurjchem-131 19 112     SPACE eurjchem-131 19 113 of of ADP eurjchem-131 19 114     SPACE eurjchem-131 19 115 1 1 NUM eurjchem-131 19 116     SPACE eurjchem-131 19 117 ( ( PUNCT eurjchem-131 19 118   NUM eurjchem-131 19 119 , , PUNCT eurjchem-131 19 120     SPACE eurjchem-131 19 121 1h 1h NUM eurjchem-131 19 122 , , PUNCT eurjchem-131 19 123     SPACE eurjchem-131 19 124 400hz 400hz NOUN eurjchem-131 19 125 , , PUNCT eurjchem-131 19 126     SPACE eurjchem-131 19 127 13c 13c NOUN eurjchem-131 19 128 , , PUNCT eurjchem-131 19 129     SPACE eurjchem-131 19 130 125 125 NUM eurjchem-131 19 131     SPACE eurjchem-131 19 132 hz hz VERB eurjchem-131 19 133 , , PUNCT eurjchem-131 19 134     SPACE eurjchem-131 19 135 j j NOUN eurjchem-131 19 136     SPACE eurjchem-131 19 137 in in ADP eurjchem-131 19 138     SPACE eurjchem-131 19 139 hz hz NOUN eurjchem-131 19 140 , , PUNCT eurjchem-131 19 141     SPACE eurjchem-131 19 142 in in ADP eurjchem-131 19 143     SPACE eurjchem-131 19 144 pyridine‐d5 pyridine‐d5 PROPN eurjchem-131 19 145 ) ) PUNCT eurjchem-131 19 146 . . PUNCT eurjchem-131 19 147     SPACE eurjchem-131 20 1 position position NOUN eurjchem-131 20 2     SPACE eurjchem-131 20 3 c c NOUN eurjchem-131 20 4     SPACE eurjchem-131 20 5 h h NOUN eurjchem-131 20 6     SPACE eurjchem-131 20 7 position position NOUN eurjchem-131 20 8     SPACE eurjchem-131 20 9 c c NOUN eurjchem-131 20 10     SPACE eurjchem-131 20 11 h h NOUN eurjchem-131 20 12     SPACE eurjchem-131 20 13 1 1 NUM eurjchem-131 20 14     SPACE eurjchem-131 20 15 18.9 18.9 NUM eurjchem-131 20 16     SPACE eurjchem-131 20 17 ( ( PUNCT eurjchem-131 20 18 t t PROPN eurjchem-131 20 19 ) ) PUNCT eurjchem-131 20 20     SPACE eurjchem-131 20 21 1.29 1.29 NUM eurjchem-131 20 22 , , PUNCT eurjchem-131 20 23     SPACE eurjchem-131 20 24 ( ( PUNCT eurjchem-131 20 25 2h 2h NUM eurjchem-131 20 26 , , PUNCT eurjchem-131 20 27     SPACE eurjchem-131 20 28 m m NOUN eurjchem-131 20 29 ) ) PUNCT eurjchem-131 20 30 22 22 NUM eurjchem-131 20 31 72.8 72.8 NUM eurjchem-131 20 32 ( ( PUNCT eurjchem-131 20 33 d d NOUN eurjchem-131 20 34 ) ) PUNCT eurjchem-131 20 35 4.39 4.39 NUM eurjchem-131 20 36 , , PUNCT eurjchem-131 20 37     SPACE eurjchem-131 20 38 1h 1h NUM eurjchem-131 20 39 , , PUNCT eurjchem-131 20 40     SPACE eurjchem-131 20 41 m m PROPN eurjchem-131 20 42 2 2 NUM eurjchem-131 20 43     SPACE eurjchem-131 20 44 27.6 27.6 NUM eurjchem-131 20 45     SPACE eurjchem-131 20 46 ( ( PUNCT eurjchem-131 20 47 t t PROPN eurjchem-131 20 48 ) ) PUNCT eurjchem-131 20 49     SPACE eurjchem-131 20 50 2.30 2.30 NUM eurjchem-131 20 51 , , PUNCT eurjchem-131 20 52     SPACE eurjchem-131 20 53 1.70 1.70 NUM eurjchem-131 20 54 , , PUNCT eurjchem-131 20 55     SPACE eurjchem-131 20 56 ( ( PUNCT eurjchem-131 20 57 2h 2h NUM eurjchem-131 20 58 , , PUNCT eurjchem-131 20 59     SPACE eurjchem-131 20 60 m m NOUN eurjchem-131 20 61 ) ) PUNCT eurjchem-131 20 62 23 23 NUM eurjchem-131 20 63 75.3 75.3 NUM eurjchem-131 20 64 ( ( PUNCT eurjchem-131 20 65 d d NOUN eurjchem-131 20 66 ) ) PUNCT eurjchem-131 20 67 4.71 4.71 NUM eurjchem-131 20 68 , , PUNCT eurjchem-131 20 69     SPACE eurjchem-131 20 70 1h 1h NUM eurjchem-131 20 71 , , PUNCT eurjchem-131 20 72     SPACE eurjchem-131 20 73 m m PROPN eurjchem-131 20 74 3 3 NUM eurjchem-131 20 75     SPACE eurjchem-131 20 76 85.1 85.1 NUM eurjchem-131 20 77     SPACE eurjchem-131 20 78 ( ( PUNCT eurjchem-131 20 79 d d NOUN eurjchem-131 20 80 ) ) PUNCT eurjchem-131 20 81     SPACE eurjchem-131 20 82 3.62 3.62 NUM eurjchem-131 20 83 , , PUNCT eurjchem-131 20 84     SPACE eurjchem-131 20 85 1h 1h NUM eurjchem-131 20 86 , , PUNCT eurjchem-131 20 87     SPACE eurjchem-131 20 88 overlapped overlap VERB eurjchem-131 20 89 24 24 NUM eurjchem-131 20 90 122.7 122.7 NUM eurjchem-131 20 91 ( ( PUNCT eurjchem-131 20 92 d d NOUN eurjchem-131 20 93 ) ) PUNCT eurjchem-131 20 94 5.43 5.43 NUM eurjchem-131 20 95     SPACE eurjchem-131 20 96 ( ( PUNCT eurjchem-131 20 97 1h 1h NUM eurjchem-131 20 98 , , PUNCT eurjchem-131 20 99     SPACE eurjchem-131 20 100 d d PROPN eurjchem-131 20 101 , , PUNCT eurjchem-131 20 102     SPACE eurjchem-131 20 103 j j PROPN eurjchem-131 20 104     SPACE eurjchem-131 20 105 = = NOUN eurjchem-131 20 106     SPACE eurjchem-131 20 107 9.4 9.4 NUM eurjchem-131 20 108 ) ) PUNCT eurjchem-131 20 109 4 4 NUM eurjchem-131 20 110     SPACE eurjchem-131 20 111 39.1(s 39.1(s NUM eurjchem-131 20 112 ) ) PUNCT eurjchem-131 20 113     SPACE eurjchem-131 20 114 ‐ ‐ NOUN eurjchem-131 20 115     SPACE eurjchem-131 20 116 25 25 NUM eurjchem-131 20 117 137.4 137.4 NUM eurjchem-131 20 118 ( ( PUNCT eurjchem-131 20 119 s s NOUN eurjchem-131 20 120 ) ) PUNCT eurjchem-131 20 121 ‐ ‐ NOUN eurjchem-131 20 122     SPACE eurjchem-131 20 123 5 5 NUM eurjchem-131 20 124     SPACE eurjchem-131 20 125 86.0(s 86.0(s NUM eurjchem-131 20 126 ) ) PUNCT eurjchem-131 20 127     SPACE eurjchem-131 20 128 ‐ ‐ VERB eurjchem-131 20 129     SPACE eurjchem-131 20 130 26 26 NUM eurjchem-131 20 131 26.1 26.1 NUM eurjchem-131 20 132 ( ( PUNCT eurjchem-131 20 133 q q NOUN eurjchem-131 20 134 ) ) PUNCT eurjchem-131 20 135 1.66 1.66 NUM eurjchem-131 20 136 , , PUNCT eurjchem-131 20 137     SPACE eurjchem-131 20 138 3h 3h NUM eurjchem-131 20 139 , , PUNCT eurjchem-131 20 140     SPACE eurjchem-131 20 141 s s PART eurjchem-131 20 142 6 6 NUM eurjchem-131 20 143     SPACE eurjchem-131 20 144 134.2 134.2 NUM eurjchem-131 20 145     SPACE eurjchem-131 20 146 ( ( PUNCT eurjchem-131 20 147 d d NOUN eurjchem-131 20 148 ) ) PUNCT eurjchem-131 20 149     SPACE eurjchem-131 20 150 6.18 6.18 NUM eurjchem-131 20 151     SPACE eurjchem-131 20 152 ( ( PUNCT eurjchem-131 20 153 1h 1h NUM eurjchem-131 20 154 , , PUNCT eurjchem-131 20 155     SPACE eurjchem-131 20 156 d d PROPN eurjchem-131 20 157 , , PUNCT eurjchem-131 20 158     SPACE eurjchem-131 20 159 j j PROPN eurjchem-131 20 160     SPACE eurjchem-131 20 161 = = NOUN eurjchem-131 20 162     SPACE eurjchem-131 20 163 9.3 9.3 NUM eurjchem-131 20 164 ) ) PUNCT eurjchem-131 20 165 27 27 NUM eurjchem-131 20 166 18.9 18.9 NUM eurjchem-131 20 167 ( ( PUNCT eurjchem-131 20 168 q q X eurjchem-131 20 169 ) ) PUNCT eurjchem-131 20 170 1.83 1.83 NUM eurjchem-131 20 171 , , PUNCT eurjchem-131 20 172     SPACE eurjchem-131 20 173 3h 3h NUM eurjchem-131 20 174 , , PUNCT eurjchem-131 20 175     SPACE eurjchem-131 20 176 s s PART eurjchem-131 20 177 7 7 NUM eurjchem-131 20 178     SPACE eurjchem-131 20 179 130.0 130.0 NUM eurjchem-131 20 180     SPACE eurjchem-131 20 181 ( ( PUNCT eurjchem-131 20 182 d d NOUN eurjchem-131 20 183 ) ) PUNCT eurjchem-131 20 184     SPACE eurjchem-131 20 185 5.53 5.53 NUM eurjchem-131 20 186     SPACE eurjchem-131 20 187 ( ( PUNCT eurjchem-131 20 188 1h 1h NUM eurjchem-131 20 189 , , PUNCT eurjchem-131 20 190     SPACE eurjchem-131 20 191 dd dd NOUN eurjchem-131 20 192 , , PUNCT eurjchem-131 20 193     SPACE eurjchem-131 20 194 j j PROPN eurjchem-131 20 195     SPACE eurjchem-131 20 196 = = NOUN eurjchem-131 20 197     SPACE eurjchem-131 20 198 9.6 9.6 NUM eurjchem-131 20 199 , , PUNCT eurjchem-131 20 200     SPACE eurjchem-131 20 201 3.3 3.3 NUM eurjchem-131 20 202 ) ) PUNCT eurjchem-131 20 203 28 28 NUM eurjchem-131 20 204 21.1 21.1 NUM eurjchem-131 20 205 ( ( PUNCT eurjchem-131 20 206 q q NOUN eurjchem-131 20 207 ) ) PUNCT eurjchem-131 20 208 1.45 1.45 NUM eurjchem-131 20 209 , , PUNCT eurjchem-131 20 210     SPACE eurjchem-131 20 211 3h 3h NUM eurjchem-131 20 212 , , PUNCT eurjchem-131 20 213     SPACE eurjchem-131 20 214 s s PART eurjchem-131 20 215 8 8 NUM eurjchem-131 20 216     SPACE eurjchem-131 20 217 52.2 52.2 NUM eurjchem-131 20 218     SPACE eurjchem-131 20 219 ( ( PUNCT eurjchem-131 20 220 d d NOUN eurjchem-131 20 221 ) ) PUNCT eurjchem-131 20 222     SPACE eurjchem-131 20 223 2.26 2.26 NUM eurjchem-131 20 224 , , PUNCT eurjchem-131 20 225     SPACE eurjchem-131 20 226 1h 1h NUM eurjchem-131 20 227 , , PUNCT eurjchem-131 20 228     SPACE eurjchem-131 20 229 m m VERB eurjchem-131 20 230 29 29 NUM eurjchem-131 20 231 25.6 25.6 NUM eurjchem-131 20 232 ( ( PUNCT eurjchem-131 20 233 q q NOUN eurjchem-131 20 234 ) ) PUNCT eurjchem-131 20 235 0.86 0.86 NUM eurjchem-131 20 236 , , PUNCT eurjchem-131 20 237     SPACE eurjchem-131 20 238 3h 3h NUM eurjchem-131 20 239 , , PUNCT eurjchem-131 20 240     SPACE eurjchem-131 20 241 s s PART eurjchem-131 20 242 9 9 NUM eurjchem-131 20 243     SPACE eurjchem-131 20 244 45.3(s 45.3(s NUM eurjchem-131 20 245 ) ) PUNCT eurjchem-131 20 246     SPACE eurjchem-131 20 247 ‐ ‐ VERB eurjchem-131 20 248     SPACE eurjchem-131 20 249 30 30 NUM eurjchem-131 20 250 20.1 20.1 NUM eurjchem-131 20 251 ( ( PUNCT eurjchem-131 20 252 q q NOUN eurjchem-131 20 253 ) ) PUNCT eurjchem-131 20 254 0.79 0.79 NUM eurjchem-131 20 255 , , PUNCT eurjchem-131 20 256     SPACE eurjchem-131 20 257 3h 3h NUM eurjchem-131 20 258 , , PUNCT eurjchem-131 20 259     SPACE eurjchem-131 20 260 s s PART eurjchem-131 20 261 10 10 NUM eurjchem-131 20 262     SPACE eurjchem-131 20 263 40.0 40.0 NUM eurjchem-131 20 264     SPACE eurjchem-131 20 265 ( ( PUNCT eurjchem-131 20 266 d d NOUN eurjchem-131 20 267 ) ) PUNCT eurjchem-131 20 268     SPACE eurjchem-131 20 269 2.23 2.23 NUM eurjchem-131 20 270 , , PUNCT eurjchem-131 20 271     SPACE eurjchem-131 20 272 1h 1h NUM eurjchem-131 20 273 , , PUNCT eurjchem-131 20 274     SPACE eurjchem-131 20 275 m m PROPN eurjchem-131 20 276 1′ 1′ NUM eurjchem-131 20 277 103.9 103.9 NUM eurjchem-131 20 278 ( ( PUNCT eurjchem-131 20 279 d d NOUN eurjchem-131 20 280 ) ) PUNCT eurjchem-131 20 281 5.39 5.39 NUM eurjchem-131 20 282     SPACE eurjchem-131 20 283 ( ( PUNCT eurjchem-131 20 284 1h 1h NUM eurjchem-131 20 285 , , PUNCT eurjchem-131 20 286     SPACE eurjchem-131 20 287 d d PROPN eurjchem-131 20 288 , , PUNCT eurjchem-131 20 289     SPACE eurjchem-131 20 290 j j PROPN eurjchem-131 20 291     SPACE eurjchem-131 20 292 = = NOUN eurjchem-131 20 293     SPACE eurjchem-131 20 294 7.7 7.7 NUM eurjchem-131 20 295 ) ) PUNCT eurjchem-131 20 296 11 11 NUM eurjchem-131 20 297     SPACE eurjchem-131 20 298 23.9 23.9 NUM eurjchem-131 20 299     SPACE eurjchem-131 20 300 ( ( PUNCT eurjchem-131 20 301 t t PROPN eurjchem-131 20 302 ) ) PUNCT eurjchem-131 20 303     SPACE eurjchem-131 20 304 1.61 1.61 NUM eurjchem-131 20 305 , , PUNCT eurjchem-131 20 306     SPACE eurjchem-131 20 307 1.29 1.29 NUM eurjchem-131 20 308 , , PUNCT eurjchem-131 20 309     SPACE eurjchem-131 20 310 2h 2h NUM eurjchem-131 20 311 , , PUNCT eurjchem-131 20 312     SPACE eurjchem-131 20 313 overlapped overlap VERB eurjchem-131 20 314 2′ 2′ NUM eurjchem-131 20 315 73.1 73.1 NUM eurjchem-131 20 316 ( ( PUNCT eurjchem-131 20 317 d d NOUN eurjchem-131 20 318 ) ) PUNCT eurjchem-131 20 319 3.95 3.95 NUM eurjchem-131 20 320     SPACE eurjchem-131 20 321 ( ( PUNCT eurjchem-131 20 322 1h 1h NUM eurjchem-131 20 323 , , PUNCT eurjchem-131 20 324     SPACE eurjchem-131 20 325 dd dd NOUN eurjchem-131 20 326 , , PUNCT eurjchem-131 20 327     SPACE eurjchem-131 20 328 j j PROPN eurjchem-131 20 329     SPACE eurjchem-131 21 1 = = NOUN eurjchem-131 21 2     SPACE eurjchem-131 21 3 7.6 7.6 NUM eurjchem-131 21 4 , , PUNCT eurjchem-131 21 5     SPACE eurjchem-131 21 6 2.2 2.2 NUM eurjchem-131 21 7 ) ) PUNCT eurjchem-131 21 8 12 12 NUM eurjchem-131 21 9     SPACE eurjchem-131 21 10 31.2 31.2 NUM eurjchem-131 21 11     SPACE eurjchem-131 21 12 ( ( PUNCT eurjchem-131 21 13 t t PROPN eurjchem-131 21 14 ) ) PUNCT eurjchem-131 21 15     SPACE eurjchem-131 21 16 1.51 1.51 NUM eurjchem-131 21 17 , , PUNCT eurjchem-131 21 18     SPACE eurjchem-131 21 19 1.44 1.44 NUM eurjchem-131 21 20 , , PUNCT eurjchem-131 21 21     SPACE eurjchem-131 21 22 2h 2h NUM eurjchem-131 21 23 , , PUNCT eurjchem-131 21 24     SPACE eurjchem-131 21 25 overlapped overlap VERB eurjchem-131 21 26 3′ 3′ NUM eurjchem-131 21 27 72.5 72.5 NUM eurjchem-131 21 28 ( ( PUNCT eurjchem-131 21 29 d d NOUN eurjchem-131 21 30 ) ) PUNCT eurjchem-131 21 31 4.69 4.69 NUM eurjchem-131 21 32 , , PUNCT eurjchem-131 21 33     SPACE eurjchem-131 21 34 1h 1h NUM eurjchem-131 21 35 , , PUNCT eurjchem-131 21 36     SPACE eurjchem-131 21 37 m m PROPN eurjchem-131 21 38 13 13 NUM eurjchem-131 21 39     SPACE eurjchem-131 21 40 45.6(s 45.6(s NUM eurjchem-131 21 41 ) ) PUNCT eurjchem-131 21 42     SPACE eurjchem-131 21 43 ‐ ‐ VERB eurjchem-131 21 44     SPACE eurjchem-131 21 45 4′ 4′ NUM eurjchem-131 21 46 69.3 69.3 NUM eurjchem-131 21 47 ( ( PUNCT eurjchem-131 21 48 d d NOUN eurjchem-131 21 49 ) ) PUNCT eurjchem-131 21 50 4.17 4.17 NUM eurjchem-131 21 51     SPACE eurjchem-131 21 52 1h 1h NUM eurjchem-131 21 53 , , PUNCT eurjchem-131 21 54     SPACE eurjchem-131 21 55 m m PROPN eurjchem-131 21 56 14 14 NUM eurjchem-131 21 57     SPACE eurjchem-131 21 58 48.6(s 48.6(s NUM eurjchem-131 21 59 ) ) PUNCT eurjchem-131 21 60     SPACE eurjchem-131 21 61 ‐ ‐ VERB eurjchem-131 21 62     SPACE eurjchem-131 21 63 5′ 5′ NUM eurjchem-131 21 64 76.2 76.2 NUM eurjchem-131 21 65 ( ( PUNCT eurjchem-131 21 66 d d NOUN eurjchem-131 21 67 ) ) PUNCT eurjchem-131 21 68 4.45 4.45 NUM eurjchem-131 21 69 , , PUNCT eurjchem-131 21 70     SPACE eurjchem-131 21 71 1h 1h NUM eurjchem-131 21 72 , , PUNCT eurjchem-131 21 73     SPACE eurjchem-131 21 74 m m VERB eurjchem-131 21 75 15 15 NUM eurjchem-131 21 76     SPACE eurjchem-131 21 77 33.5 33.5 NUM eurjchem-131 21 78     SPACE eurjchem-131 21 79 ( ( PUNCT eurjchem-131 21 80 t t PROPN eurjchem-131 21 81 ) ) PUNCT eurjchem-131 21 82     SPACE eurjchem-131 21 83 1.14 1.14 NUM eurjchem-131 21 84 , , PUNCT eurjchem-131 21 85     SPACE eurjchem-131 21 86 1.03 1.03 NUM eurjchem-131 21 87 , , PUNCT eurjchem-131 21 88     SPACE eurjchem-131 21 89 2h 2h NUM eurjchem-131 21 90 , , PUNCT eurjchem-131 21 91     SPACE eurjchem-131 21 92 overlapped overlap VERB eurjchem-131 21 93 6′ 6′ NUM eurjchem-131 21 94 63.3 63.3 NUM eurjchem-131 21 95 ( ( PUNCT eurjchem-131 21 96 t t PROPN eurjchem-131 21 97 ) ) PUNCT eurjchem-131 21 98 4.33,4.48 4.33,4.48 NUM eurjchem-131 21 99 , , PUNCT eurjchem-131 21 100     SPACE eurjchem-131 21 101 2h 2h NUM eurjchem-131 21 102 , , PUNCT eurjchem-131 21 103     SPACE eurjchem-131 21 104 2 2 NUM eurjchem-131 21 105 m m NOUN eurjchem-131 21 106 16 16 NUM eurjchem-131 21 107     SPACE eurjchem-131 21 108 27.9 27.9 NUM eurjchem-131 21 109     SPACE eurjchem-131 21 110 ( ( PUNCT eurjchem-131 21 111 t t PROPN eurjchem-131 21 112 ) ) PUNCT eurjchem-131 21 113     SPACE eurjchem-131 21 114 1.13 1.13 NUM eurjchem-131 21 115 , , PUNCT eurjchem-131 21 116     SPACE eurjchem-131 21 117 2h 2h NUM eurjchem-131 21 118 , , PUNCT eurjchem-131 21 119     SPACE eurjchem-131 21 120 m m VERB eurjchem-131 21 121 1′′ 1′′ NUM eurjchem-131 21 122 99.5 99.5 NUM eurjchem-131 21 123 ( ( PUNCT eurjchem-131 21 124 d d NOUN eurjchem-131 21 125 ) ) PUNCT eurjchem-131 21 126 4.93 4.93 NUM eurjchem-131 21 127 , , PUNCT eurjchem-131 21 128     SPACE eurjchem-131 21 129 1h 1h NUM eurjchem-131 21 130 , , PUNCT eurjchem-131 21 131     SPACE eurjchem-131 21 132 s s PART eurjchem-131 21 133 17 17 NUM eurjchem-131 21 134     SPACE eurjchem-131 21 135 46.9 46.9 NUM eurjchem-131 21 136     SPACE eurjchem-131 21 137 ( ( PUNCT eurjchem-131 21 138 d d NOUN eurjchem-131 21 139 ) ) PUNCT eurjchem-131 21 140     SPACE eurjchem-131 21 141 1.69 1.69 NUM eurjchem-131 21 142 , , PUNCT eurjchem-131 21 143     SPACE eurjchem-131 21 144 1h 1h NUM eurjchem-131 21 145 , , PUNCT eurjchem-131 21 146     SPACE eurjchem-131 21 147 m m PROPN eurjchem-131 21 148 2′′ 2′′ NUM eurjchem-131 21 149 93.3(s 93.3( NOUN eurjchem-131 21 150 ) ) PUNCT eurjchem-131 21 151 ‐ ‐ NOUN eurjchem-131 21 152     SPACE eurjchem-131 21 153 18 18 NUM eurjchem-131 21 154     SPACE eurjchem-131 21 155 14.4 14.4 NUM eurjchem-131 21 156     SPACE eurjchem-131 21 157 ( ( PUNCT eurjchem-131 21 158 q q NOUN eurjchem-131 21 159 ) ) PUNCT eurjchem-131 21 160     SPACE eurjchem-131 21 161 0.60 0.60 NUM eurjchem-131 21 162     SPACE eurjchem-131 21 163 3h 3h NUM eurjchem-131 21 164 , , PUNCT eurjchem-131 21 165     SPACE eurjchem-131 21 166 s s PART eurjchem-131 21 167     SPACE eurjchem-131 22 1 3′′ 3′′ NUM eurjchem-131 22 2 77.6 77.6 NUM eurjchem-131 22 3 ( ( PUNCT eurjchem-131 22 4 d d NOUN eurjchem-131 22 5 ) ) PUNCT eurjchem-131 22 6 4.29 4.29 NUM eurjchem-131 22 7     SPACE eurjchem-131 22 8 ( ( PUNCT eurjchem-131 22 9 1h 1h NUM eurjchem-131 22 10 , , PUNCT eurjchem-131 22 11     SPACE eurjchem-131 22 12 d d PROPN eurjchem-131 22 13 , , PUNCT eurjchem-131 22 14     SPACE eurjchem-131 22 15 j j PROPN eurjchem-131 22 16     SPACE eurjchem-131 22 17 = = NOUN eurjchem-131 22 18     SPACE eurjchem-131 22 19 8.7 8.7 NUM eurjchem-131 22 20 ) ) PUNCT eurjchem-131 22 21 19 19 NUM eurjchem-131 22 22     SPACE eurjchem-131 22 23 80.2 80.2 NUM eurjchem-131 22 24     SPACE eurjchem-131 22 25 ( ( PUNCT eurjchem-131 22 26 t t PROPN eurjchem-131 22 27 ) ) PUNCT eurjchem-131 22 28     SPACE eurjchem-131 22 29 3.76 3.76 NUM eurjchem-131 22 30     SPACE eurjchem-131 22 31 ( ( PUNCT eurjchem-131 22 32 1h 1h NUM eurjchem-131 22 33 , , PUNCT eurjchem-131 22 34     SPACE eurjchem-131 22 35 d d PROPN eurjchem-131 22 36 , , PUNCT eurjchem-131 22 37     SPACE eurjchem-131 22 38 j j PROPN eurjchem-131 22 39     SPACE eurjchem-131 22 40 = = NOUN eurjchem-131 22 41     SPACE eurjchem-131 22 42 7.8 7.8 NUM eurjchem-131 22 43 ) ) PUNCT eurjchem-131 22 44 , , PUNCT eurjchem-131 22 45     SPACE eurjchem-131 22 46 3.57 3.57 NUM eurjchem-131 22 47     SPACE eurjchem-131 22 48 ( ( PUNCT eurjchem-131 22 49 1h 1h NUM eurjchem-131 22 50 , , PUNCT eurjchem-131 22 51     SPACE eurjchem-131 22 52 d d PROPN eurjchem-131 22 53 , , PUNCT eurjchem-131 22 54     SPACE eurjchem-131 22 55 j j PROPN eurjchem-131 22 56     SPACE eurjchem-131 22 57 = = NOUN eurjchem-131 22 58     SPACE eurjchem-131 22 59 7.8 7.8 NUM eurjchem-131 22 60 ) ) PUNCT eurjchem-131 22 61 4′′ 4′′ NOUN eurjchem-131 22 62 71.4 71.4 NUM eurjchem-131 22 63 ( ( PUNCT eurjchem-131 22 64 d d NOUN eurjchem-131 22 65 ) ) PUNCT eurjchem-131 22 66 4.49 4.49 NUM eurjchem-131 22 67 , , PUNCT eurjchem-131 22 68     SPACE eurjchem-131 22 69 1h 1h NUM eurjchem-131 22 70 , , PUNCT eurjchem-131 22 71     SPACE eurjchem-131 22 72 m m VERB eurjchem-131 22 73 20 20 NUM eurjchem-131 22 74     SPACE eurjchem-131 22 75 40.1 40.1 NUM eurjchem-131 22 76     SPACE eurjchem-131 22 77 ( ( PUNCT eurjchem-131 22 78 d d NOUN eurjchem-131 22 79 ) ) PUNCT eurjchem-131 22 80     SPACE eurjchem-131 22 81 1.83 1.83 NUM eurjchem-131 22 82 , , PUNCT eurjchem-131 22 83     SPACE eurjchem-131 22 84 1h 1h NUM eurjchem-131 22 85 , , PUNCT eurjchem-131 22 86     SPACE eurjchem-131 22 87 m m VERB eurjchem-131 22 88 5′′ 5′′ NUM eurjchem-131 22 89 80.9 80.9 NUM eurjchem-131 22 90 ( ( PUNCT eurjchem-131 22 91 d d NOUN eurjchem-131 22 92 ) ) PUNCT eurjchem-131 22 93 4.18 4.18 NUM eurjchem-131 22 94 , , PUNCT eurjchem-131 22 95     SPACE eurjchem-131 22 96 1h 1h NUM eurjchem-131 22 97 , , PUNCT eurjchem-131 22 98     SPACE eurjchem-131 22 99 m m VERB eurjchem-131 22 100 21 21 NUM eurjchem-131 22 101     SPACE eurjchem-131 22 102 15.0 15.0 NUM eurjchem-131 22 103     SPACE eurjchem-131 22 104 ( ( PUNCT eurjchem-131 22 105 q q NOUN eurjchem-131 22 106 ) ) PUNCT eurjchem-131 22 107     SPACE eurjchem-131 22 108 1.08 1.08 NUM eurjchem-131 22 109     SPACE eurjchem-131 22 110 ( ( PUNCT eurjchem-131 22 111 3 3 NUM eurjchem-131 22 112     SPACE eurjchem-131 22 113 h h NOUN eurjchem-131 22 114 , , PUNCT eurjchem-131 22 115     SPACE eurjchem-131 22 116 d d PROPN eurjchem-131 22 117 , , PUNCT eurjchem-131 22 118     SPACE eurjchem-131 22 119 j j PROPN eurjchem-131 22 120     SPACE eurjchem-131 22 121 = = NOUN eurjchem-131 22 122     SPACE eurjchem-131 22 123 6.5 6.5 NUM eurjchem-131 22 124 ) ) PUNCT eurjchem-131 22 125 6′′ 6′′ NOUN eurjchem-131 22 126 63.2 63.2 NUM eurjchem-131 22 127 ( ( PUNCT eurjchem-131 22 128 t t PROPN eurjchem-131 22 129 ) ) PUNCT eurjchem-131 22 130 4.48 4.48 NUM eurjchem-131 22 131 , , PUNCT eurjchem-131 22 132     SPACE eurjchem-131 22 133 4.60 4.60 NUM eurjchem-131 22 134 , , PUNCT eurjchem-131 22 135     SPACE eurjchem-131 22 136 2h 2h NUM eurjchem-131 22 137 , , PUNCT eurjchem-131 22 138     SPACE eurjchem-131 22 139 2 2 NUM eurjchem-131 22 140 m m AUX eurjchem-131 22 141         SPACE eurjchem-131 22 142 eluted elute VERB eurjchem-131 22 143     SPACE eurjchem-131 22 144 with with ADP eurjchem-131 22 145     SPACE eurjchem-131 22 146 n‐buoh n‐buoh ADV eurjchem-131 22 147 / / SYM eurjchem-131 22 148 acoet acoet ADJ eurjchem-131 22 149 / / SYM eurjchem-131 22 150 h2o h2o PROPN eurjchem-131 22 151     SPACE eurjchem-131 22 152 ( ( PUNCT eurjchem-131 22 153 4:4:1 4:4:1 NOUN eurjchem-131 22 154     SPACE eurjchem-131 22 155 upper upper ADJ eurjchem-131 22 156     SPACE eurjchem-131 22 157 layer layer NOUN eurjchem-131 22 158 ) ) PUNCT eurjchem-131 22 159     SPACE eurjchem-131 22 160 and and CCONJ eurjchem-131 22 161     SPACE eurjchem-131 22 162 on on ADP eurjchem-131 22 163     SPACE eurjchem-131 22 164 reversed‐phase reversed‐phase NOUN eurjchem-131 22 165     SPACE eurjchem-131 22 166 silica silica NOUN eurjchem-131 22 167     SPACE eurjchem-131 22 168 gel gel NOUN eurjchem-131 22 169     SPACE eurjchem-131 22 170 column column NOUN eurjchem-131 22 171     SPACE eurjchem-131 22 172 eluted elute VERB eurjchem-131 22 173     SPACE eurjchem-131 22 174 with with ADP eurjchem-131 22 175     SPACE eurjchem-131 22 176 meoh meoh PROPN eurjchem-131 22 177 / / SYM eurjchem-131 22 178 h2o h2o PROPN eurjchem-131 22 179     SPACE eurjchem-131 22 180 ( ( PUNCT eurjchem-131 22 181 45 45 NUM eurjchem-131 22 182 % % NOUN eurjchem-131 22 183 ) ) PUNCT eurjchem-131 22 184     SPACE eurjchem-131 22 185 as as ADV eurjchem-131 22 186     SPACE eurjchem-131 22 187 well well ADV eurjchem-131 22 188     SPACE eurjchem-131 22 189 as as ADP eurjchem-131 22 190     SPACE eurjchem-131 22 191 on on ADP eurjchem-131 22 192     SPACE eurjchem-131 22 193 sephadex sephadex NOUN eurjchem-131 22 194     SPACE eurjchem-131 22 195 lh‐20 lh‐20 PROPN eurjchem-131 22 196     SPACE eurjchem-131 22 197 column column NOUN eurjchem-131 22 198     SPACE eurjchem-131 22 199 using use VERB eurjchem-131 22 200     SPACE eurjchem-131 22 201 meoh meoh NOUN eurjchem-131 22 202     SPACE eurjchem-131 22 203 as as ADP eurjchem-131 22 204     SPACE eurjchem-131 22 205 fluent fluent ADJ eurjchem-131 22 206 . . PUNCT eurjchem-131 22 207         SPACE eurjchem-131 23 1 2.4 2.4 NUM eurjchem-131 23 2 . . PUNCT eurjchem-131 23 3     SPACE eurjchem-131 23 4 spectral spectral ADJ eurjchem-131 23 5     SPACE eurjchem-131 23 6 data data PROPN eurjchem-131 23 7         SPACE eurjchem-131 23 8 neokuguaglucoside neokuguaglucoside NOUN eurjchem-131 23 9     SPACE eurjchem-131 23 10 ( ( PUNCT eurjchem-131 23 11 1 1 NUM eurjchem-131 23 12 ): ): PUNCT eurjchem-131 23 13     SPACE eurjchem-131 23 14 c42h66o14 c42h66o14 NOUN eurjchem-131 23 15 ; ; PUNCT eurjchem-131 23 16     SPACE eurjchem-131 23 17 white white ADJ eurjchem-131 23 18     SPACE eurjchem-131 23 19 powder powder NOUN eurjchem-131 23 20 ; ; PUNCT eurjchem-131 23 21     SPACE eurjchem-131 24 1 [ [ X eurjchem-131 24 2 α]d25 α]d25 NOUN eurjchem-131 24 3     SPACE eurjchem-131 24 4 = = NOUN eurjchem-131 24 5     SPACE eurjchem-131 24 6 80.8 80.8 NOUN eurjchem-131 24 7     SPACE eurjchem-131 24 8 ( ( PUNCT eurjchem-131 24 9 c=0.1 c=0.1 NOUN eurjchem-131 24 10 , , PUNCT eurjchem-131 24 11     SPACE eurjchem-131 24 12 meoh meoh PROPN eurjchem-131 24 13 ) ) PUNCT eurjchem-131 24 14 ; ; PUNCT eurjchem-131 24 15     SPACE eurjchem-131 24 16 negative negative ADJ eurjchem-131 24 17     SPACE eurjchem-131 24 18 fabms fabms NOUN eurjchem-131 24 19 : : PUNCT eurjchem-131 24 20     SPACE eurjchem-131 24 21 m m PROPN eurjchem-131 24 22 / / SYM eurjchem-131 24 23 z z NOUN eurjchem-131 24 24     SPACE eurjchem-131 24 25 793 793 NUM eurjchem-131 24 26     SPACE eurjchem-131 24 27 [ [ X eurjchem-131 24 28 mh] mh] ADJ eurjchem-131 24 29 ; ; PUNCT eurjchem-131 24 30     SPACE eurjchem-131 24 31 hresims hresim NOUN eurjchem-131 24 32 : : PUNCT eurjchem-131 24 33     SPACE eurjchem-131 24 34 m m PROPN eurjchem-131 24 35 / / SYM eurjchem-131 24 36 z z NOUN eurjchem-131 24 37     SPACE eurjchem-131 24 38 829.4129 829.4129 NUM eurjchem-131 24 39     SPACE eurjchem-131 24 40 [ [ PUNCT eurjchem-131 24 41 m+cl] m+cl] PROPN eurjchem-131 24 42     SPACE eurjchem-131 24 43 ( ( PUNCT eurjchem-131 24 44 calcd calcd NOUN eurjchem-131 24 45 . . PUNCT eurjchem-131 24 46     SPACE eurjchem-131 24 47 829.4141 829.4141 NUM eurjchem-131 24 48 ) ) PUNCT eurjchem-131 24 49 ; ; PUNCT eurjchem-131 24 50     SPACE eurjchem-131 24 51 ir ir PROPN eurjchem-131 24 52     SPACE eurjchem-131 24 53 ( ( PUNCT eurjchem-131 24 54 kbr kbr PROPN eurjchem-131 24 55 , , PUNCT eurjchem-131 24 56     SPACE eurjchem-131 24 57 cm‐1 cm‐1 NOUN eurjchem-131 24 58 ) ) PUNCT eurjchem-131 24 59     SPACE eurjchem-131 24 60 max max PROPN eurjchem-131 24 61 : : PUNCT eurjchem-131 24 62     SPACE eurjchem-131 24 63 3410 3410 NUM eurjchem-131 24 64 , , PUNCT eurjchem-131 24 65     SPACE eurjchem-131 24 66 2929 2929 NUM eurjchem-131 24 67 , , PUNCT eurjchem-131 24 68     SPACE eurjchem-131 24 69 1630 1630 NUM eurjchem-131 24 70 , , PUNCT eurjchem-131 24 71     SPACE eurjchem-131 24 72 1452 1452 NUM eurjchem-131 24 73 , , PUNCT eurjchem-131 24 74     SPACE eurjchem-131 24 75 1371 1371 NUM eurjchem-131 24 76 , , PUNCT eurjchem-131 24 77     SPACE eurjchem-131 24 78 1072 1072 NUM eurjchem-131 24 79 , , PUNCT eurjchem-131 24 80     SPACE eurjchem-131 24 81 998 998 NUM eurjchem-131 24 82 ; ; PUNCT eurjchem-131 24 83     SPACE eurjchem-131 24 84 1h‐nmr 1h‐nmr NUM eurjchem-131 24 85     SPACE eurjchem-131 24 86 ( ( PUNCT eurjchem-131 24 87 c5d5n c5d5n X eurjchem-131 24 88 , , PUNCT eurjchem-131 24 89     SPACE eurjchem-131 24 90 400 400 NUM eurjchem-131 24 91     SPACE eurjchem-131 24 92 mhz mhz NOUN eurjchem-131 24 93 ) ) PUNCT eurjchem-131 24 94     SPACE eurjchem-131 24 95 and and CCONJ eurjchem-131 24 96     SPACE eurjchem-131 24 97 13c‐nmr 13c‐nmr NOUN eurjchem-131 24 98     SPACE eurjchem-131 24 99 ( ( PUNCT eurjchem-131 24 100 c5d5n c5d5n NUM eurjchem-131 24 101 , , PUNCT eurjchem-131 24 102     SPACE eurjchem-131 24 103 125 125 NUM eurjchem-131 24 104     SPACE eurjchem-131 24 105 mhz mhz NOUN eurjchem-131 24 106 ): ): PUNCT eurjchem-131 24 107     SPACE eurjchem-131 24 108 see see VERB eurjchem-131 24 109     SPACE eurjchem-131 24 110 table table NOUN eurjchem-131 24 111     SPACE eurjchem-131 24 112 1 1 NUM eurjchem-131 24 113 . . PUNCT eurjchem-131 24 114         SPACE eurjchem-131 24 115 3 3 NUM eurjchem-131 24 116 . . PUNCT eurjchem-131 24 117     SPACE eurjchem-131 24 118 results result VERB eurjchem-131 24 119     SPACE eurjchem-131 24 120 and and CCONJ eurjchem-131 24 121     SPACE eurjchem-131 24 122 discussion discussion NOUN eurjchem-131 24 123         SPACE eurjchem-131 24 124 compound compound NOUN eurjchem-131 24 125     SPACE eurjchem-131 24 126 1 1 NUM eurjchem-131 24 127     SPACE eurjchem-131 24 128 was be AUX eurjchem-131 24 129     SPACE eurjchem-131 24 130 obtained obtain VERB eurjchem-131 24 131     SPACE eurjchem-131 24 132 as as ADP eurjchem-131 24 133     SPACE eurjchem-131 24 134 a a DET eurjchem-131 24 135     SPACE eurjchem-131 24 136 white white ADJ eurjchem-131 24 137     SPACE eurjchem-131 24 138 powder powder NOUN eurjchem-131 24 139 . . PUNCT eurjchem-131 24 140     SPACE eurjchem-131 25 1 [ [ X eurjchem-131 25 2 α]d25 α]d25 NOUN eurjchem-131 25 3     SPACE eurjchem-131 25 4   NUM eurjchem-131 25 5     SPACE eurjchem-131 25 6 80.8 80.8 NOUN eurjchem-131 25 7     SPACE eurjchem-131 25 8 ( ( PUNCT eurjchem-131 25 9 c=0.1 c=0.1 NOUN eurjchem-131 25 10 , , PUNCT eurjchem-131 25 11     SPACE eurjchem-131 25 12 meoh meoh NOUN eurjchem-131 25 13 ) ) PUNCT eurjchem-131 25 14 . . PUNCT eurjchem-131 25 15     SPACE eurjchem-131 26 1 in in ADP eurjchem-131 26 2     SPACE eurjchem-131 26 3 the the DET eurjchem-131 26 4     SPACE eurjchem-131 26 5 negative‐ion negative‐ion NOUN eurjchem-131 26 6     SPACE eurjchem-131 26 7 fab‐ms fab‐ms PROPN eurjchem-131 26 8     SPACE eurjchem-131 26 9 of of ADP eurjchem-131 26 10     SPACE eurjchem-131 26 11 1 1 NUM eurjchem-131 26 12 , , PUNCT eurjchem-131 26 13     SPACE eurjchem-131 26 14 quasi‐ quasi‐ VERB eurjchem-131 26 15 molecular molecular ADJ eurjchem-131 26 16     SPACE eurjchem-131 26 17 ion ion NOUN eurjchem-131 26 18     SPACE eurjchem-131 26 19 peaks peak NOUN eurjchem-131 26 20     SPACE eurjchem-131 26 21 were be AUX eurjchem-131 26 22     SPACE eurjchem-131 26 23 observed observe VERB eurjchem-131 26 24     SPACE eurjchem-131 26 25 at at ADP eurjchem-131 26 26     SPACE eurjchem-131 26 27 m m PROPN eurjchem-131 26 28 / / PROPN eurjchem-131 27 1 z z NOUN eurjchem-131 27 2     SPACE eurjchem-131 27 3 793 793 NUM eurjchem-131 27 4     SPACE eurjchem-131 27 5 [ [ X eurjchem-131 27 6 m m X eurjchem-131 27 7 – – PUNCT eurjchem-131 27 8 h]–. h]–. PRON eurjchem-131 27 9     SPACE eurjchem-131 27 10 hresims hresim NOUN eurjchem-131 27 11     SPACE eurjchem-131 27 12 afforded afford VERB eurjchem-131 27 13     SPACE eurjchem-131 27 14 a a DET eurjchem-131 27 15     SPACE eurjchem-131 27 16 possible possible ADJ eurjchem-131 27 17     SPACE eurjchem-131 27 18 molecular molecular ADJ eurjchem-131 27 19     SPACE eurjchem-131 27 20 formula formula NOUN eurjchem-131 27 21     SPACE eurjchem-131 27 22 of of ADP eurjchem-131 27 23     SPACE eurjchem-131 27 24 1 1 NUM eurjchem-131 27 25     SPACE eurjchem-131 27 26 as as ADP eurjchem-131 27 27     SPACE eurjchem-131 27 28 c42h66o14 c42h66o14 NOUN eurjchem-131 27 29     SPACE eurjchem-131 27 30 ( ( PUNCT eurjchem-131 27 31 [ [ X eurjchem-131 27 32 m+cl] m+cl] PROPN eurjchem-131 27 33 , , PUNCT eurjchem-131 27 34     SPACE eurjchem-131 27 35 m m PROPN eurjchem-131 27 36 / / PROPN eurjchem-131 27 37 z z NOUN eurjchem-131 27 38     SPACE eurjchem-131 27 39 829.4129 829.4129 NUM eurjchem-131 27 40 , , PUNCT eurjchem-131 27 41     SPACE eurjchem-131 27 42 calcd calcd NOUN eurjchem-131 27 43 . . PUNCT eurjchem-131 27 44     SPACE eurjchem-131 27 45 829.4141 829.4141 NUM eurjchem-131 27 46 ) ) PUNCT eurjchem-131 27 47 . . PUNCT eurjchem-131 27 48     SPACE eurjchem-131 28 1 the the DET eurjchem-131 28 2     SPACE eurjchem-131 28 3 ir ir NOUN eurjchem-131 28 4     SPACE eurjchem-131 28 5 spectrum spectrum NOUN eurjchem-131 28 6     SPACE eurjchem-131 28 7 exhibited exhibit VERB eurjchem-131 28 8     SPACE eurjchem-131 28 9 the the DET eurjchem-131 28 10     SPACE eurjchem-131 28 11 presence presence NOUN eurjchem-131 28 12     SPACE eurjchem-131 28 13 of of ADP eurjchem-131 28 14     SPACE eurjchem-131 28 15 hydroxyl hydroxyl NOUN eurjchem-131 28 16     SPACE eurjchem-131 28 17 groups group NOUN eurjchem-131 28 18     SPACE eurjchem-131 28 19 ( ( PUNCT eurjchem-131 28 20 3402 3402 NUM eurjchem-131 28 21 , , PUNCT eurjchem-131 28 22     SPACE eurjchem-131 28 23 3315 3315 NUM eurjchem-131 28 24 , , PUNCT eurjchem-131 28 25     SPACE eurjchem-131 28 26 3267 3267 NUM eurjchem-131 28 27     SPACE eurjchem-131 28 28 cm–1 cm–1 NOUN eurjchem-131 28 29 ) ) PUNCT eurjchem-131 28 30 . . PUNCT eurjchem-131 28 31     SPACE eurjchem-131 29 1 the the DET eurjchem-131 29 2     SPACE eurjchem-131 29 3 1h‐nmr 1h‐nmr NUM eurjchem-131 29 4     SPACE eurjchem-131 29 5 ( ( PUNCT eurjchem-131 29 6 table table NOUN eurjchem-131 29 7     SPACE eurjchem-131 29 8 1 1 NUM eurjchem-131 29 9 ) ) PUNCT eurjchem-131 29 10     SPACE eurjchem-131 29 11 spectrum spectrum NOUN eurjchem-131 29 12     SPACE eurjchem-131 29 13 of of ADP eurjchem-131 29 14     SPACE eurjchem-131 29 15 1 1 NUM eurjchem-131 29 16     SPACE eurjchem-131 29 17 showed show VERB eurjchem-131 29 18     SPACE eurjchem-131 29 19 signals signal NOUN eurjchem-131 29 20     SPACE eurjchem-131 29 21 for for ADP eurjchem-131 29 22     SPACE eurjchem-131 29 23 six six NUM eurjchem-131 29 24     SPACE eurjchem-131 29 25 tertiary tertiary ADJ eurjchem-131 29 26     SPACE eurjchem-131 29 27 methyls methyls NOUN eurjchem-131 29 28 , , PUNCT eurjchem-131 29 29     SPACE eurjchem-131 29 30 a a DET eurjchem-131 29 31     SPACE eurjchem-131 29 32 secondary secondary ADJ eurjchem-131 29 33     SPACE eurjchem-131 29 34 methyl methyl NOUN eurjchem-131 29 35     SPACE eurjchem-131 29 36 at at ADP eurjchem-131 29 37     SPACE eurjchem-131 29 38   NOUN eurjchem-131 29 39     SPACE eurjchem-131 29 40 1.08 1.08 NUM eurjchem-131 29 41     SPACE eurjchem-131 29 42 ( ( PUNCT eurjchem-131 29 43 3h 3h NUM eurjchem-131 29 44 , , PUNCT eurjchem-131 29 45     SPACE eurjchem-131 29 46 d d PROPN eurjchem-131 29 47 , , PUNCT eurjchem-131 29 48     SPACE eurjchem-131 29 49 j j PROPN eurjchem-131 29 50     SPACE eurjchem-131 29 51 = = NOUN eurjchem-131 29 52     SPACE eurjchem-131 29 53 6.5 6.5 NUM eurjchem-131 29 54     SPACE eurjchem-131 29 55 hz hz NOUN eurjchem-131 29 56 ) ) PUNCT eurjchem-131 29 57 , , PUNCT eurjchem-131 29 58     SPACE eurjchem-131 29 59 two two NUM eurjchem-131 29 60     SPACE eurjchem-131 29 61 vinyl vinyl NOUN eurjchem-131 29 62     SPACE eurjchem-131 29 63 methyls methyls NOUN eurjchem-131 29 64     SPACE eurjchem-131 29 65 at at ADP eurjchem-131 29 66     SPACE eurjchem-131 29 67   NOUN eurjchem-131 29 68     SPACE eurjchem-131 29 69 1.66 1.66 NUM eurjchem-131 29 70 , , PUNCT eurjchem-131 29 71     SPACE eurjchem-131 29 72 1.83 1.83 NUM eurjchem-131 29 73 , , PUNCT eurjchem-131 29 74     SPACE eurjchem-131 29 75 and and CCONJ eurjchem-131 29 76     SPACE eurjchem-131 29 77 three three NUM eurjchem-131 29 78     SPACE eurjchem-131 29 79 olefinic olefinic ADJ eurjchem-131 29 80     SPACE eurjchem-131 29 81 protons proton NOUN eurjchem-131 29 82     SPACE eurjchem-131 29 83 at at ADP eurjchem-131 29 84     SPACE eurjchem-131 29 85   NUM eurjchem-131 29 86     SPACE eurjchem-131 29 87 6.18 6.18 NUM eurjchem-131 29 88     SPACE eurjchem-131 29 89 ( ( PUNCT eurjchem-131 29 90 1h 1h NUM eurjchem-131 29 91 , , PUNCT eurjchem-131 29 92     SPACE eurjchem-131 29 93 d d PROPN eurjchem-131 29 94 , , PUNCT eurjchem-131 29 95     SPACE eurjchem-131 29 96 j j PROPN eurjchem-131 29 97     SPACE eurjchem-131 29 98 = = NOUN eurjchem-131 29 99     SPACE eurjchem-131 29 100 9.3 9.3 NUM eurjchem-131 29 101     SPACE eurjchem-131 29 102 hz hz NOUN eurjchem-131 29 103 ) ) PUNCT eurjchem-131 29 104 , , PUNCT eurjchem-131 29 105     SPACE eurjchem-131 29 106 5.53 5.53 NUM eurjchem-131 29 107     SPACE eurjchem-131 29 108 ( ( PUNCT eurjchem-131 29 109 1h 1h NUM eurjchem-131 29 110 , , PUNCT eurjchem-131 29 111     SPACE eurjchem-131 29 112 dd dd NOUN eurjchem-131 29 113 , , PUNCT eurjchem-131 29 114     SPACE eurjchem-131 29 115 j j PROPN eurjchem-131 29 116     SPACE eurjchem-131 29 117 = = NOUN eurjchem-131 29 118     SPACE eurjchem-131 29 119 9.6 9.6 NUM eurjchem-131 29 120 , , PUNCT eurjchem-131 29 121     SPACE eurjchem-131 29 122 3.3 3.3 NUM eurjchem-131 29 123     SPACE eurjchem-131 29 124 hz hz NOUN eurjchem-131 29 125 ) ) PUNCT eurjchem-131 29 126 , , PUNCT eurjchem-131 29 127     SPACE eurjchem-131 29 128 5.43 5.43 NUM eurjchem-131 29 129     SPACE eurjchem-131 29 130 ( ( PUNCT eurjchem-131 29 131 1h 1h NUM eurjchem-131 29 132 , , PUNCT eurjchem-131 29 133     SPACE eurjchem-131 29 134 d d PROPN eurjchem-131 29 135 , , PUNCT eurjchem-131 29 136     SPACE eurjchem-131 29 137 j j PROPN eurjchem-131 29 138     SPACE eurjchem-131 29 139 = = NOUN eurjchem-131 29 140     SPACE eurjchem-131 29 141 9.4 9.4 NUM eurjchem-131 29 142     SPACE eurjchem-131 29 143 hz hz VERB eurjchem-131 29 144 ) ) PUNCT eurjchem-131 29 145     SPACE eurjchem-131 29 146 as as ADV eurjchem-131 29 147     SPACE eurjchem-131 29 148 well well ADV eurjchem-131 29 149     SPACE eurjchem-131 29 150 as as ADP eurjchem-131 29 151     SPACE eurjchem-131 29 152 one one NUM eurjchem-131 29 153     SPACE eurjchem-131 29 154 anomeric anomeric ADJ eurjchem-131 29 155     SPACE eurjchem-131 29 156 protons proton NOUN eurjchem-131 29 157     SPACE eurjchem-131 29 158 at at ADP eurjchem-131 29 159     SPACE eurjchem-131 29 160   VERB eurjchem-131 29 161     SPACE eurjchem-131 29 162 5.39 5.39 NUM eurjchem-131 29 163     SPACE eurjchem-131 29 164 ( ( PUNCT eurjchem-131 29 165 1h 1h NUM eurjchem-131 29 166 , , PUNCT eurjchem-131 29 167     SPACE eurjchem-131 29 168 d d PROPN eurjchem-131 29 169 , , PUNCT eurjchem-131 29 170     SPACE eurjchem-131 29 171 j j PROPN eurjchem-131 29 172     SPACE eurjchem-131 29 173 = = NOUN eurjchem-131 29 174     SPACE eurjchem-131 29 175 7.7 7.7 NUM eurjchem-131 29 176     SPACE eurjchem-131 29 177 hz hz NOUN eurjchem-131 29 178 ) ) PUNCT eurjchem-131 29 179 . . PUNCT eurjchem-131 29 180     SPACE eurjchem-131 30 1 the the DET eurjchem-131 30 2     SPACE eurjchem-131 30 3 13c‐nmr 13c‐nmr NOUN eurjchem-131 30 4     SPACE eurjchem-131 30 5 ( ( PUNCT eurjchem-131 30 6 table table NOUN eurjchem-131 30 7     SPACE eurjchem-131 30 8 1 1 NUM eurjchem-131 30 9 ) ) PUNCT eurjchem-131 30 10     SPACE eurjchem-131 30 11 of of ADP eurjchem-131 30 12     SPACE eurjchem-131 30 13 1 1 NUM eurjchem-131 30 14     SPACE eurjchem-131 30 15 showed show VERB eurjchem-131 30 16     SPACE eurjchem-131 30 17 42 42 NUM eurjchem-131 30 18     SPACE eurjchem-131 30 19 carbon carbon NOUN eurjchem-131 30 20     SPACE eurjchem-131 30 21 signals signal NOUN eurjchem-131 30 22     SPACE eurjchem-131 30 23 including include VERB eurjchem-131 30 24     SPACE eurjchem-131 30 25 30 30 NUM eurjchem-131 30 26     SPACE eurjchem-131 30 27 of of ADP eurjchem-131 30 28     SPACE eurjchem-131 30 29 aglycone aglycone NOUN eurjchem-131 30 30 , , PUNCT eurjchem-131 30 31     SPACE eurjchem-131 30 32 six six NUM eurjchem-131 30 33     SPACE eurjchem-131 30 34 signals signal NOUN eurjchem-131 30 35     SPACE eurjchem-131 30 36 of of ADP eurjchem-131 30 37     SPACE eurjchem-131 30 38 one one NUM eurjchem-131 30 39     SPACE eurjchem-131 30 40 sugar sugar NOUN eurjchem-131 30 41 , , PUNCT eurjchem-131 30 42     SPACE eurjchem-131 30 43 and and CCONJ eurjchem-131 30 44     SPACE eurjchem-131 30 45 six six NUM eurjchem-131 30 46     SPACE eurjchem-131 30 47 signals signal NOUN eurjchem-131 30 48     SPACE eurjchem-131 30 49 of of ADP eurjchem-131 30 50     SPACE eurjchem-131 30 51 one one NUM eurjchem-131 30 52     SPACE eurjchem-131 30 53 sugar‐like sugar‐like NOUN eurjchem-131 30 54     SPACE eurjchem-131 30 55 group group NOUN eurjchem-131 30 56 , , PUNCT eurjchem-131 30 57     SPACE eurjchem-131 30 58 which which PRON eurjchem-131 30 59     SPACE eurjchem-131 30 60 indicated indicate VERB eurjchem-131 30 61     SPACE eurjchem-131 30 62 that that SCONJ eurjchem-131 30 63     SPACE eurjchem-131 30 64 1 1 NUM eurjchem-131 30 65     SPACE eurjchem-131 30 66 was be AUX eurjchem-131 30 67     SPACE eurjchem-131 30 68 a a DET eurjchem-131 30 69     SPACE eurjchem-131 30 70 cucurtriterpene cucurtriterpene NOUN eurjchem-131 30 71     SPACE eurjchem-131 30 72 saponin saponin NOUN eurjchem-131 30 73 . . PUNCT eurjchem-131 30 74     SPACE eurjchem-131 31 1 comparison comparison NOUN eurjchem-131 31 2     SPACE eurjchem-131 31 3 of of ADP eurjchem-131 31 4     SPACE eurjchem-131 31 5 the the DET eurjchem-131 31 6     SPACE eurjchem-131 31 7 13c‐nmr 13c‐nmr NOUN eurjchem-131 31 8     SPACE eurjchem-131 31 9 data datum NOUN eurjchem-131 31 10     SPACE eurjchem-131 31 11 of of ADP eurjchem-131 31 12     SPACE eurjchem-131 31 13 1 1 NUM eurjchem-131 31 14     SPACE eurjchem-131 31 15 with with ADP eurjchem-131 31 16     SPACE eurjchem-131 31 17 karaviloside karaviloside NOUN eurjchem-131 31 18     SPACE eurjchem-131 31 19 x x NOUN eurjchem-131 31 20     SPACE eurjchem-131 32 1 [ [ X eurjchem-131 32 2 7 7 NUM eurjchem-131 32 3 ] ] PUNCT eurjchem-131 32 4     SPACE eurjchem-131 32 5 showed show VERB eurjchem-131 32 6     SPACE eurjchem-131 32 7 that that SCONJ eurjchem-131 32 8     SPACE eurjchem-131 32 9 they they PRON eurjchem-131 32 10     SPACE eurjchem-131 32 11 have have VERB eurjchem-131 32 12     SPACE eurjchem-131 32 13 the the DET eurjchem-131 32 14     SPACE eurjchem-131 32 15 same same ADJ eurjchem-131 32 16     SPACE eurjchem-131 32 17 aglycone aglycone NOUN eurjchem-131 32 18     SPACE eurjchem-131 32 19 with with ADP eurjchem-131 32 20     SPACE eurjchem-131 32 21 an an DET eurjchem-131 32 22     SPACE eurjchem-131 32 23 allopyranose allopyranose NOUN eurjchem-131 32 24     SPACE eurjchem-131 32 25 attached attach VERB eurjchem-131 32 26     SPACE eurjchem-131 32 27 to to ADP eurjchem-131 32 28     SPACE eurjchem-131 32 29 c‐3 c‐3 NOUN eurjchem-131 32 30     SPACE eurjchem-131 32 31 of of ADP eurjchem-131 32 32     SPACE eurjchem-131 32 33 aglycone aglycone NOUN eurjchem-131 32 34 . . PUNCT eurjchem-131 32 35     SPACE eurjchem-131 33 1 furthermore furthermore ADV eurjchem-131 33 2 , , PUNCT eurjchem-131 33 3     SPACE eurjchem-131 33 4 the the DET eurjchem-131 33 5     SPACE eurjchem-131 33 6 hmbc hmbc NOUN eurjchem-131 33 7     SPACE eurjchem-131 33 8 ( ( PUNCT eurjchem-131 33 9 figure figure NOUN eurjchem-131 33 10     SPACE eurjchem-131 33 11 2 2 NUM eurjchem-131 33 12 ) ) PUNCT eurjchem-131 33 13     SPACE eurjchem-131 33 14 permitted permit VERB eurjchem-131 33 15     SPACE eurjchem-131 33 16 the the DET eurjchem-131 33 17     SPACE eurjchem-131 33 18 above above ADP eurjchem-131 33 19     SPACE eurjchem-131 33 20 deduction deduction NOUN eurjchem-131 33 21 . . PUNCT eurjchem-131 33 22       SPACE eurjchem-131 34 1 intriguingly intriguingly ADV eurjchem-131 34 2 , , PUNCT eurjchem-131 34 3     SPACE eurjchem-131 34 4 there there PRON eurjchem-131 34 5     SPACE eurjchem-131 34 6 were be AUX eurjchem-131 34 7     SPACE eurjchem-131 34 8 six six NUM eurjchem-131 34 9     SPACE eurjchem-131 34 10 sugar‐like sugar‐like ADJ eurjchem-131 34 11     SPACE eurjchem-131 34 12 carbon carbon NOUN eurjchem-131 34 13     SPACE eurjchem-131 34 14 signals signal NOUN eurjchem-131 34 15     SPACE eurjchem-131 34 16 at at ADP eurjchem-131 34 17     SPACE eurjchem-131 34 18   NOUN eurjchem-131 34 19     SPACE eurjchem-131 34 20 99.5 99.5 NUM eurjchem-131 34 21     SPACE eurjchem-131 34 22 ( ( PUNCT eurjchem-131 34 23 d d NOUN eurjchem-131 34 24 ) ) PUNCT eurjchem-131 34 25 , , PUNCT eurjchem-131 34 26     SPACE eurjchem-131 34 27 93.3 93.3 NUM eurjchem-131 34 28     SPACE eurjchem-131 34 29 ( ( PUNCT eurjchem-131 34 30 s s NOUN eurjchem-131 34 31 ) ) PUNCT eurjchem-131 34 32 , , PUNCT eurjchem-131 34 33     SPACE eurjchem-131 34 34 77.6 77.6 NUM eurjchem-131 34 35     SPACE eurjchem-131 34 36 ( ( PUNCT eurjchem-131 34 37 d d NOUN eurjchem-131 34 38 ) ) PUNCT eurjchem-131 34 39 , , PUNCT eurjchem-131 34 40     SPACE eurjchem-131 34 41 71.4 71.4 NUM eurjchem-131 34 42     SPACE eurjchem-131 34 43 ( ( PUNCT eurjchem-131 34 44 d d NOUN eurjchem-131 34 45 ) ) PUNCT eurjchem-131 34 46 , , PUNCT eurjchem-131 34 47     SPACE eurjchem-131 34 48 80.9 80.9 NUM eurjchem-131 34 49     SPACE eurjchem-131 34 50 ( ( PUNCT eurjchem-131 34 51 d d NOUN eurjchem-131 34 52 ) ) PUNCT eurjchem-131 34 53 , , PUNCT eurjchem-131 34 54     SPACE eurjchem-131 34 55 63.2 63.2 NUM eurjchem-131 34 56     SPACE eurjchem-131 34 57 ( ( PUNCT eurjchem-131 34 58 t t PROPN eurjchem-131 34 59 ) ) PUNCT eurjchem-131 34 60 . . PUNCT eurjchem-131 34 61     SPACE eurjchem-131 35 1 the the DET eurjchem-131 35 2     SPACE eurjchem-131 35 3 hmbc hmbc NOUN eurjchem-131 35 4     SPACE eurjchem-131 35 5 spectrum spectrum NOUN eurjchem-131 35 6     SPACE eurjchem-131 35 7 of of ADP eurjchem-131 35 8     SPACE eurjchem-131 35 9 1 1 NUM eurjchem-131 35 10     SPACE eurjchem-131 35 11 displayed display VERB eurjchem-131 35 12     SPACE eurjchem-131 35 13 the the DET eurjchem-131 35 14     SPACE eurjchem-131 35 15 following follow VERB eurjchem-131 35 16     SPACE eurjchem-131 35 17 correlations correlation NOUN eurjchem-131 35 18 : : PUNCT eurjchem-131 35 19     SPACE eurjchem-131 35 20 h‐21 h‐21 PROPN eurjchem-131 35 21                         SPACE eurjchem-131 35 22 ( ( PUNCT eurjchem-131 35 23   NOUN eurjchem-131 35 24     SPACE eurjchem-131 35 25 1.08 1.08 NUM eurjchem-131 35 26 , , PUNCT eurjchem-131 35 27     SPACE eurjchem-131 35 28 1h 1h NUM eurjchem-131 35 29 , , PUNCT eurjchem-131 35 30     SPACE eurjchem-131 35 31 d d PROPN eurjchem-131 35 32 , , PUNCT eurjchem-131 35 33     SPACE eurjchem-131 35 34 j j PROPN eurjchem-131 35 35     SPACE eurjchem-131 35 36 = = NOUN eurjchem-131 35 37     SPACE eurjchem-131 35 38 6.5 6.5 NUM eurjchem-131 35 39     SPACE eurjchem-131 35 40 hz hz VERB eurjchem-131 35 41 ) ) PUNCT eurjchem-131 35 42     SPACE eurjchem-131 35 43 with with ADP eurjchem-131 35 44     SPACE eurjchem-131 35 45 c‐20 c‐20 ADJ eurjchem-131 35 46 , , PUNCT eurjchem-131 35 47     SPACE eurjchem-131 35 48 c‐22 c‐22 NOUN eurjchem-131 35 49 ; ; PUNCT eurjchem-131 35 50     SPACE eurjchem-131 35 51 h‐22 h‐22 PROPN eurjchem-131 35 52     SPACE eurjchem-131 35 53 ( ( PUNCT eurjchem-131 35 54   NOUN eurjchem-131 35 55     SPACE eurjchem-131 35 56 4.39 4.39 NUM eurjchem-131 35 57 , , PUNCT eurjchem-131 35 58     SPACE eurjchem-131 35 59 1h 1h NUM eurjchem-131 35 60 , , PUNCT eurjchem-131 35 61     SPACE eurjchem-131 35 62 m m NOUN eurjchem-131 35 63 ) ) PUNCT eurjchem-131 35 64     SPACE eurjchem-131 35 65 with with ADP eurjchem-131 35 66     SPACE eurjchem-131 35 67 c‐2 c‐2 NOUN eurjchem-131 35 68     SPACE eurjchem-131 35 69 ( ( PUNCT eurjchem-131 35 70   NOUN eurjchem-131 35 71     SPACE eurjchem-131 35 72 93.3 93.3 NUM eurjchem-131 35 73 ) ) PUNCT eurjchem-131 35 74 ; ; PUNCT eurjchem-131 35 75     SPACE eurjchem-131 35 76 h‐23 h‐23 PROPN eurjchem-131 35 77     SPACE eurjchem-131 35 78 ( ( PUNCT eurjchem-131 35 79   NOUN eurjchem-131 35 80     SPACE eurjchem-131 35 81 4.71 4.71 NUM eurjchem-131 35 82 , , PUNCT eurjchem-131 35 83     SPACE eurjchem-131 35 84 1h 1h NUM eurjchem-131 35 85 , , PUNCT eurjchem-131 35 86     SPACE eurjchem-131 35 87 m m NOUN eurjchem-131 35 88 ) ) PUNCT eurjchem-131 35 89     SPACE eurjchem-131 35 90 with with ADP eurjchem-131 35 91     SPACE eurjchem-131 35 92 c‐1 c‐1 NOUN eurjchem-131 35 93     SPACE eurjchem-131 35 94 ( ( PUNCT eurjchem-131 35 95   NOUN eurjchem-131 35 96     SPACE eurjchem-131 35 97 99.5 99.5 NUM eurjchem-131 35 98 ) ) PUNCT eurjchem-131 35 99 ; ; PUNCT eurjchem-131 35 100     SPACE eurjchem-131 35 101 h‐ h‐ PROPN eurjchem-131 35 102 24 24 NUM eurjchem-131 35 103     SPACE eurjchem-131 35 104 ( ( PUNCT eurjchem-131 35 105   NOUN eurjchem-131 35 106     SPACE eurjchem-131 35 107 5.43 5.43 NUM eurjchem-131 35 108 , , PUNCT eurjchem-131 35 109     SPACE eurjchem-131 35 110 1h 1h NUM eurjchem-131 35 111 , , PUNCT eurjchem-131 35 112     SPACE eurjchem-131 35 113 d d PROPN eurjchem-131 35 114 , , PUNCT eurjchem-131 35 115     SPACE eurjchem-131 35 116 j j PROPN eurjchem-131 35 117     SPACE eurjchem-131 35 118 = = NOUN eurjchem-131 35 119     SPACE eurjchem-131 35 120 9.4 9.4 NUM eurjchem-131 35 121     SPACE eurjchem-131 35 122 hz hz VERB eurjchem-131 35 123 ) ) PUNCT eurjchem-131 35 124     SPACE eurjchem-131 35 125 with with ADP eurjchem-131 35 126     SPACE eurjchem-131 35 127 c‐23 c‐23 PROPN eurjchem-131 35 128 , , PUNCT eurjchem-131 35 129     SPACE eurjchem-131 35 130 c‐25 c‐25 PROPN eurjchem-131 35 131 ; ; PUNCT eurjchem-131 35 132     SPACE eurjchem-131 35 133 h‐26 h‐26 PROPN eurjchem-131 35 134     SPACE eurjchem-131 35 135 ( ( PUNCT eurjchem-131 35 136   NOUN eurjchem-131 35 137     SPACE eurjchem-131 35 138 1.66 1.66 NUM eurjchem-131 35 139 , , PUNCT eurjchem-131 35 140     SPACE eurjchem-131 35 141 3h 3h NUM eurjchem-131 35 142 , , PUNCT eurjchem-131 35 143     SPACE eurjchem-131 35 144 s s PART eurjchem-131 35 145 ) ) PUNCT eurjchem-131 35 146     SPACE eurjchem-131 35 147 with with ADP eurjchem-131 35 148     SPACE eurjchem-131 35 149 c‐27 c‐27 NOUN eurjchem-131 35 150 , , PUNCT eurjchem-131 35 151     SPACE eurjchem-131 35 152 c‐25 c‐25 PROPN eurjchem-131 35 153 , , PUNCT eurjchem-131 35 154     SPACE eurjchem-131 35 155 c‐24 c‐24 NOUN eurjchem-131 35 156 ; ; PUNCT eurjchem-131 35 157     SPACE eurjchem-131 35 158 h‐1 h‐1 NOUN eurjchem-131 35 159     SPACE eurjchem-131 35 160 ( ( PUNCT eurjchem-131 35 161   NOUN eurjchem-131 35 162     SPACE eurjchem-131 35 163 4.93 4.93 NUM eurjchem-131 35 164 , , PUNCT eurjchem-131 35 165     SPACE eurjchem-131 35 166 1h 1h NUM eurjchem-131 35 167 , , PUNCT eurjchem-131 35 168     SPACE eurjchem-131 35 169 s s PART eurjchem-131 35 170 ) ) PUNCT eurjchem-131 35 171     SPACE eurjchem-131 35 172 with with ADP eurjchem-131 35 173     SPACE eurjchem-131 35 174 c‐5 c‐5 PROPN eurjchem-131 35 175     SPACE eurjchem-131 35 176 ( ( PUNCT eurjchem-131 35 177   NOUN eurjchem-131 35 178     SPACE eurjchem-131 35 179 80.9 80.9 NUM eurjchem-131 35 180 ) ) PUNCT eurjchem-131 35 181 ; ; PUNCT eurjchem-131 35 182     SPACE eurjchem-131 35 183 h‐5 h‐5 NOUN eurjchem-131 35 184     SPACE eurjchem-131 35 185 ( ( PUNCT eurjchem-131 35 186   NOUN eurjchem-131 35 187     SPACE eurjchem-131 35 188 4.18 4.18 NUM eurjchem-131 35 189 , , PUNCT eurjchem-131 35 190     SPACE eurjchem-131 35 191 1h 1h NUM eurjchem-131 35 192 , , PUNCT eurjchem-131 35 193     SPACE eurjchem-131 35 194 m m NOUN eurjchem-131 35 195 ) ) PUNCT eurjchem-131 35 196     SPACE eurjchem-131 35 197 with with ADP eurjchem-131 35 198     SPACE eurjchem-131 35 199 c‐4 c‐4 PROPN eurjchem-131 35 200 , , PUNCT eurjchem-131 35 201     SPACE eurjchem-131 35 202 c‐3 c‐3 NOUN eurjchem-131 35 203 ; ; PUNCT eurjchem-131 35 204     SPACE eurjchem-131 35 205 h‐6 h‐6 NOUN eurjchem-131 35 206     SPACE eurjchem-131 35 207 ( ( PUNCT eurjchem-131 35 208   NOUN eurjchem-131 35 209     SPACE eurjchem-131 35 210 4.48 4.48 NUM eurjchem-131 35 211 , , PUNCT eurjchem-131 35 212     SPACE eurjchem-131 35 213 4.60 4.60 NUM eurjchem-131 35 214 , , PUNCT eurjchem-131 35 215     SPACE eurjchem-131 35 216 2h 2h NUM eurjchem-131 35 217 , , PUNCT eurjchem-131 35 218     SPACE eurjchem-131 35 219 2 2 NUM eurjchem-131 35 220 m m NOUN eurjchem-131 35 221 ) ) PUNCT eurjchem-131 35 222     SPACE eurjchem-131 35 223 with with ADP eurjchem-131 35 224     SPACE eurjchem-131 35 225 c‐4. c‐4. VERB eurjchem-131 35 226     SPACE eurjchem-131 35 227 the the DET eurjchem-131 35 228     SPACE eurjchem-131 35 229 above above ADP eurjchem-131 35 230     SPACE eurjchem-131 35 231 evidence evidence NOUN eurjchem-131 35 232 , , PUNCT eurjchem-131 35 233     SPACE eurjchem-131 35 234 along along ADP eurjchem-131 35 235     SPACE eurjchem-131 35 236 with with ADP eurjchem-131 35 237     SPACE eurjchem-131 35 238 two two NUM eurjchem-131 35 239     SPACE eurjchem-131 35 240 proton proton NOUN eurjchem-131 35 241     SPACE eurjchem-131 35 242 spin spin NOUN eurjchem-131 35 243     SPACE eurjchem-131 35 244 systems system NOUN eurjchem-131 35 245     SPACE eurjchem-131 35 246 observed observe VERB eurjchem-131 35 247     SPACE eurjchem-131 35 248 from from ADP eurjchem-131 35 249     SPACE eurjchem-131 35 250 the the DET eurjchem-131 35 251     SPACE eurjchem-131 35 252 1h‐1h 1h‐1h NUM eurjchem-131 35 253     SPACE eurjchem-131 35 254 cosy cosy NOUN eurjchem-131 35 255     SPACE eurjchem-131 35 256 spectrum spectrum NOUN eurjchem-131 35 257 , , PUNCT eurjchem-131 35 258     SPACE eurjchem-131 35 259 h‐17 h‐17 ADJ eurjchem-131 35 260 , , PUNCT eurjchem-131 35 261     SPACE eurjchem-131 35 262 h‐ h‐ PROPN eurjchem-131 35 263 21 21 NUM eurjchem-131 35 264 / / SYM eurjchem-131 35 265 h‐20 h‐20 NOUN eurjchem-131 35 266 / / SYM eurjchem-131 35 267 h‐22 h‐22 NOUN eurjchem-131 35 268 / / SYM eurjchem-131 35 269 h‐23 h‐23 PROPN eurjchem-131 35 270 / / SYM eurjchem-131 35 271 h‐24 h‐24 NOUN eurjchem-131 35 272 , , PUNCT eurjchem-131 35 273     SPACE eurjchem-131 35 274 and and CCONJ eurjchem-131 35 275     SPACE eurjchem-131 35 276 h‐3/h‐4/h‐5/h‐6 h‐3/h‐4/h‐5/h‐6 ADJ eurjchem-131 35 277 , , PUNCT eurjchem-131 35 278     SPACE eurjchem-131 35 279 showed show VERB eurjchem-131 35 280     SPACE eurjchem-131 35 281 the the DET eurjchem-131 35 282     SPACE eurjchem-131 35 283 existence existence NOUN eurjchem-131 35 284     SPACE eurjchem-131 35 285 of of ADP eurjchem-131 35 286     SPACE eurjchem-131 35 287 fragment fragment NOUN eurjchem-131 35 288     SPACE eurjchem-131 35 289 1b 1b NUM eurjchem-131 35 290     SPACE eurjchem-131 35 291 ( ( PUNCT eurjchem-131 35 292 figure figure NOUN eurjchem-131 35 293     SPACE eurjchem-131 35 294 2 2 NUM eurjchem-131 35 295 ) ) PUNCT eurjchem-131 35 296 . . PUNCT eurjchem-131 35 297             SPACE eurjchem-131 36 1 figure figure VERB eurjchem-131 36 2     SPACE eurjchem-131 36 3 2 2 NUM eurjchem-131 36 4 . . PUNCT eurjchem-131 36 5     SPACE eurjchem-131 36 6 the the DET eurjchem-131 36 7     SPACE eurjchem-131 36 8 key key ADJ eurjchem-131 36 9     SPACE eurjchem-131 36 10 hmbc hmbc NOUN eurjchem-131 36 11     SPACE eurjchem-131 36 12 and and CCONJ eurjchem-131 36 13     SPACE eurjchem-131 36 14 1h‐1h 1h‐1h NOUN eurjchem-131 36 15     SPACE eurjchem-131 36 16 cosy cosy NOUN eurjchem-131 36 17     SPACE eurjchem-131 36 18 correlations correlation NOUN eurjchem-131 36 19     SPACE eurjchem-131 36 20 of of ADP eurjchem-131 36 21     SPACE eurjchem-131 36 22 1 1 NUM eurjchem-131 36 23         SPACE eurjchem-131 36 24 the the DET eurjchem-131 36 25     SPACE eurjchem-131 36 26 stereochemistry stereochemistry NOUN eurjchem-131 36 27     SPACE eurjchem-131 36 28 of of ADP eurjchem-131 36 29     SPACE eurjchem-131 36 30 1b 1b NUM eurjchem-131 36 31     SPACE eurjchem-131 36 32 was be AUX eurjchem-131 36 33     SPACE eurjchem-131 36 34 characterized characterize VERB eurjchem-131 36 35     SPACE eurjchem-131 36 36 by by ADP eurjchem-131 36 37     SPACE eurjchem-131 36 38 roesy roesy ADJ eurjchem-131 36 39     SPACE eurjchem-131 36 40 experiment experiment NOUN eurjchem-131 36 41     SPACE eurjchem-131 36 42 ( ( PUNCT eurjchem-131 36 43 figure figure NOUN eurjchem-131 36 44     SPACE eurjchem-131 36 45 3 3 NUM eurjchem-131 36 46 ) ) PUNCT eurjchem-131 36 47     SPACE eurjchem-131 36 48 and and CCONJ eurjchem-131 36 49     SPACE eurjchem-131 36 50 theoretical theoretical ADJ eurjchem-131 36 51     SPACE eurjchem-131 36 52 calculations calculation NOUN eurjchem-131 36 53     SPACE eurjchem-131 36 54 using use VERB eurjchem-131 36 55     SPACE eurjchem-131 36 56 a a DET eurjchem-131 36 57     SPACE eurjchem-131 36 58 semiempirical semiempirical NOUN eurjchem-131 36 59     SPACE eurjchem-131 36 60 ( ( PUNCT eurjchem-131 36 61 am1 am1 PROPN eurjchem-131 36 62 ) ) PUNCT eurjchem-131 36 63     SPACE eurjchem-131 36 64 quantum quantum NOUN eurjchem-131 36 65     SPACE eurjchem-131 36 66 chemical chemical NOUN eurjchem-131 36 67     SPACE eurjchem-131 36 68 method method NOUN eurjchem-131 36 69     SPACE eurjchem-131 36 70 ( ( PUNCT eurjchem-131 36 71 table table NOUN eurjchem-131 36 72     SPACE eurjchem-131 36 73 2 2 NUM eurjchem-131 36 74 ) ) PUNCT eurjchem-131 36 75 . . PUNCT eurjchem-131 36 76     SPACE eurjchem-131 37 1 the the DET eurjchem-131 37 2     SPACE eurjchem-131 37 3 usual usual ADJ eurjchem-131 37 4     SPACE eurjchem-131 37 5 h‐20 h‐20 NOUN eurjchem-131 37 6     SPACE eurjchem-131 37 7 β­configuration β­configuration NOUN eurjchem-131 37 8     SPACE eurjchem-131 37 9 of of ADP eurjchem-131 37 10     SPACE eurjchem-131 37 11 cucurbitane cucurbitane ADJ eurjchem-131 37 12     SPACE eurjchem-131 37 13 derivatives derivative NOUN eurjchem-131 37 14     SPACE eurjchem-131 37 15 was be AUX eurjchem-131 37 16     SPACE eurjchem-131 37 17 established establish VERB eurjchem-131 37 18     SPACE eurjchem-131 37 19 for for ADP eurjchem-131 37 20     SPACE eurjchem-131 37 21 1 1 NUM eurjchem-131 37 22     SPACE eurjchem-131 37 23 by by ADP eurjchem-131 37 24     SPACE eurjchem-131 37 25 the the DET eurjchem-131 37 26     SPACE eurjchem-131 37 27 noesy noesy NOUN eurjchem-131 37 28     SPACE eurjchem-131 37 29 correlations correlation NOUN eurjchem-131 37 30     SPACE eurjchem-131 37 31 18β‐me/20β‐h 18β‐me/20β‐h NUM eurjchem-131 37 32     SPACE eurjchem-131 37 33 and and CCONJ eurjchem-131 37 34     SPACE eurjchem-131 37 35 21α‐me/17α‐h 21α‐me/17α‐h NUM eurjchem-131 37 36 . . PUNCT eurjchem-131 37 37         SPACE eurjchem-131 37 38 figure figure NOUN eurjchem-131 37 39     SPACE eurjchem-131 37 40 3 3 NUM eurjchem-131 37 41 . . PUNCT eurjchem-131 37 42     SPACE eurjchem-131 37 43 key key ADJ eurjchem-131 37 44     SPACE eurjchem-131 37 45 roesy roesy ADJ eurjchem-131 37 46     SPACE eurjchem-131 37 47 correlations correlation NOUN eurjchem-131 37 48     SPACE eurjchem-131 37 49 of of ADP eurjchem-131 37 50     SPACE eurjchem-131 37 51 1b 1b NUM eurjchem-131 37 52     SPACE eurjchem-131 37 53 and and CCONJ eurjchem-131 37 54     SPACE eurjchem-131 37 55 corresponding corresponding ADJ eurjchem-131 37 56     SPACE eurjchem-131 37 57 ineteratomic ineteratomic ADJ eurjchem-131 37 58     SPACE eurjchem-131 37 59 distance distance NOUN eurjchem-131 37 60     SPACE eurjchem-131 37 61 ( ( PUNCT eurjchem-131 37 62 å å NOUN eurjchem-131 37 63 ) ) PUNCT eurjchem-131 37 64 . . PUNCT eurjchem-131 37 65         SPACE eurjchem-131 38 1 the the DET eurjchem-131 38 2     SPACE eurjchem-131 38 3 usual usual ADJ eurjchem-131 38 4     SPACE eurjchem-131 38 5 h‐20 h‐20 NOUN eurjchem-131 38 6     SPACE eurjchem-131 38 7 β­configuration β­configuration NOUN eurjchem-131 38 8     SPACE eurjchem-131 38 9 of of ADP eurjchem-131 38 10     SPACE eurjchem-131 38 11 cucurbitane cucurbitane ADJ eurjchem-131 38 12     SPACE eurjchem-131 38 13 derivatives derivative NOUN eurjchem-131 38 14     SPACE eurjchem-131 38 15 was be AUX eurjchem-131 38 16     SPACE eurjchem-131 38 17 established establish VERB eurjchem-131 38 18     SPACE eurjchem-131 38 19 for for ADP eurjchem-131 38 20     SPACE eurjchem-131 38 21 1 1 NUM eurjchem-131 38 22     SPACE eurjchem-131 38 23 by by ADP eurjchem-131 38 24     SPACE eurjchem-131 38 25 the the DET eurjchem-131 38 26     SPACE eurjchem-131 38 27 noesy noesy NOUN eurjchem-131 38 28     SPACE eurjchem-131 38 29 correlations correlation NOUN eurjchem-131 38 30     SPACE eurjchem-131 38 31 18β‐me/20β‐h 18β‐me/20β‐h NUM eurjchem-131 38 32     SPACE eurjchem-131 38 33 and and CCONJ eurjchem-131 38 34     SPACE eurjchem-131 38 35 21α‐me/17α‐h 21α‐me/17α‐h NUM eurjchem-131 38 36 . . PUNCT eurjchem-131 38 37     SPACE eurjchem-131 38 38 correlation correlation NOUN eurjchem-131 38 39     SPACE eurjchem-131 38 40 contours contours NOUN eurjchem-131 38 41     SPACE eurjchem-131 38 42 were be AUX eurjchem-131 38 43     SPACE eurjchem-131 38 44 exhibited exhibit VERB eurjchem-131 38 45     SPACE eurjchem-131 38 46 in in ADP eurjchem-131 38 47     SPACE eurjchem-131 38 48 the the DET eurjchem-131 38 49     SPACE eurjchem-131 38 50 noesy noesy NOUN eurjchem-131 38 51     SPACE eurjchem-131 38 52 spectrum spectrum NOUN eurjchem-131 38 53     SPACE eurjchem-131 38 54 of of ADP eurjchem-131 38 55     SPACE eurjchem-131 38 56 1b 1b NUM eurjchem-131 38 57     SPACE eurjchem-131 38 58 between between ADP eurjchem-131 38 59     SPACE eurjchem-131 38 60 h‐22 h‐22 NOUN eurjchem-131 38 61     SPACE eurjchem-131 38 62 and and CCONJ eurjchem-131 38 63     SPACE eurjchem-131 38 64 h‐23 h‐23 PROPN eurjchem-131 38 65 , , PUNCT eurjchem-131 38 66     SPACE eurjchem-131 38 67 h‐1 h‐1 NOUN eurjchem-131 38 68 ; ; PUNCT eurjchem-131 38 69     SPACE eurjchem-131 38 70 h‐1 h‐1 NOUN eurjchem-131 38 71     SPACE eurjchem-131 38 72 and and CCONJ eurjchem-131 38 73     SPACE eurjchem-131 38 74 h‐3 h‐3 NOUN eurjchem-131 38 75 , , PUNCT eurjchem-131 38 76     SPACE eurjchem-131 38 77 h‐5 h‐5 PROPN eurjchem-131 38 78 ; ; PUNCT eurjchem-131 38 79     SPACE eurjchem-131 38 80 h‐3 h‐3 NOUN eurjchem-131 38 81     SPACE eurjchem-131 38 82 and and CCONJ eurjchem-131 38 83     SPACE eurjchem-131 38 84 h‐5. h‐5. NOUN eurjchem-131 38 85     SPACE eurjchem-131 38 86 in in ADP eurjchem-131 38 87     SPACE eurjchem-131 38 88 the the DET eurjchem-131 38 89     SPACE eurjchem-131 38 90 noesy noesy NOUN eurjchem-131 38 91     SPACE eurjchem-131 38 92 spectrum spectrum NOUN eurjchem-131 38 93     SPACE eurjchem-131 38 94 of of ADP eurjchem-131 38 95     SPACE eurjchem-131 38 96 1 1 NUM eurjchem-131 38 97 , , PUNCT eurjchem-131 38 98     SPACE eurjchem-131 38 99 there there PRON eurjchem-131 38 100     SPACE eurjchem-131 38 101 was be AUX eurjchem-131 38 102     SPACE eurjchem-131 38 103 no no DET eurjchem-131 38 104     SPACE eurjchem-131 38 105 correlation correlation NOUN eurjchem-131 38 106     SPACE eurjchem-131 38 107 of of ADP eurjchem-131 38 108     SPACE eurjchem-131 38 109 20β‐h 20β‐h NOUN eurjchem-131 38 110     SPACE eurjchem-131 38 111 with with ADP eurjchem-131 38 112     SPACE eurjchem-131 38 113 22‐h 22‐h NUM eurjchem-131 38 114 , , PUNCT eurjchem-131 38 115     SPACE eurjchem-131 38 116 therefore therefore ADV eurjchem-131 38 117 , , PUNCT eurjchem-131 38 118     SPACE eurjchem-131 38 119 h‐22 h‐22 PROPN eurjchem-131 38 120 , , PUNCT eurjchem-131 38 121     SPACE eurjchem-131 38 122 h‐23 h‐23 VERB eurjchem-131 38 123 , , PUNCT eurjchem-131 38 124     SPACE eurjchem-131 38 125 h‐1 h‐1 PROPN eurjchem-131 38 126 , , PUNCT eurjchem-131 38 127     SPACE eurjchem-131 38 128 h‐3 h‐3 NOUN eurjchem-131 38 129     SPACE eurjchem-131 38 130 and and CCONJ eurjchem-131 38 131     SPACE eurjchem-131 38 132 h‐5 h‐5 NOUN eurjchem-131 38 133     SPACE eurjchem-131 38 134 were be AUX eurjchem-131 38 135     SPACE eurjchem-131 38 136 α­configuration α­configuration NOUN eurjchem-131 38 137     SPACE eurjchem-131 38 138 in in ADP eurjchem-131 38 139     SPACE eurjchem-131 38 140 1b 1b NUM eurjchem-131 38 141 . . PUNCT eurjchem-131 38 142     SPACE eurjchem-131 39 1 moreover moreover ADV eurjchem-131 39 2 , , PUNCT eurjchem-131 39 3     SPACE eurjchem-131 39 4 in in ADP eurjchem-131 39 5     SPACE eurjchem-131 39 6 order order NOUN eurjchem-131 39 7     SPACE eurjchem-131 39 8 to to PART eurjchem-131 39 9     SPACE eurjchem-131 39 10 deduce deduce VERB eurjchem-131 39 11     SPACE eurjchem-131 39 12 the the DET eurjchem-131 39 13     SPACE eurjchem-131 39 14 configuration configuration NOUN eurjchem-131 39 15     SPACE eurjchem-131 39 16 of of ADP eurjchem-131 39 17     SPACE eurjchem-131 39 18 2‐oh 2‐oh NOUN eurjchem-131 39 19 , , PUNCT eurjchem-131 39 20     SPACE eurjchem-131 39 21 we we PRON eurjchem-131 39 22     SPACE eurjchem-131 39 23 hypothesis hypothesis NOUN eurjchem-131 39 24     SPACE eurjchem-131 39 25 four four NUM eurjchem-131 39 26       SPACE eurjchem-131 39 27 296 296 NUM eurjchem-131 39 28     SPACE eurjchem-131 39 29 liu liu PROPN eurjchem-131 39 30     SPACE eurjchem-131 39 31 et et PROPN eurjchem-131 39 32     SPACE eurjchem-131 39 33 al al PROPN eurjchem-131 39 34 . . PROPN eurjchem-131 39 35     SPACE eurjchem-131 39 36 / / SYM eurjchem-131 39 37     SPACE eurjchem-131 39 38 european european ADJ eurjchem-131 39 39     SPACE eurjchem-131 39 40 journal journal NOUN eurjchem-131 39 41     SPACE eurjchem-131 39 42 of of ADP eurjchem-131 39 43     SPACE eurjchem-131 39 44 chemistry chemistry NOUN eurjchem-131 39 45     SPACE eurjchem-131 39 46 1 1 NUM eurjchem-131 39 47     SPACE eurjchem-131 39 48 ( ( PUNCT eurjchem-131 39 49 4 4 NUM eurjchem-131 39 50 ) ) PUNCT eurjchem-131 39 51     SPACE eurjchem-131 39 52 ( ( PUNCT eurjchem-131 39 53 2010 2010 NUM eurjchem-131 39 54 ) ) PUNCT eurjchem-131 39 55     SPACE eurjchem-131 39 56 294­296 294­296 NUM eurjchem-131 39 57         SPACE eurjchem-131 39 58 table table NOUN eurjchem-131 39 59     SPACE eurjchem-131 39 60 2 2 NUM eurjchem-131 39 61 . . PUNCT eurjchem-131 39 62     SPACE eurjchem-131 39 63 main main ADJ eurjchem-131 39 64     SPACE eurjchem-131 39 65 noesy noesy NOUN eurjchem-131 39 66     SPACE eurjchem-131 39 67 correlations correlation NOUN eurjchem-131 39 68     SPACE eurjchem-131 39 69 and and CCONJ eurjchem-131 39 70     SPACE eurjchem-131 39 71 semiemperical semiemperical ADJ eurjchem-131 39 72     SPACE eurjchem-131 39 73 calculations calculation NOUN eurjchem-131 39 74     SPACE eurjchem-131 39 75 results result NOUN eurjchem-131 39 76     SPACE eurjchem-131 39 77 of of ADP eurjchem-131 39 78     SPACE eurjchem-131 39 79 1 1 NUM eurjchem-131 39 80 . . PUNCT eurjchem-131 39 81     SPACE eurjchem-131 40 1 no no DET eurjchem-131 40 2     SPACE eurjchem-131 40 3 the the DET eurjchem-131 40 4     SPACE eurjchem-131 40 5 minimum minimum ADJ eurjchem-131 40 6     SPACE eurjchem-131 40 7 spatial spatial ADJ eurjchem-131 40 8     SPACE eurjchem-131 40 9 distance distance NOUN eurjchem-131 40 10     SPACE eurjchem-131 40 11 between between VERB eurjchem-131 40 12     SPACE eurjchem-131 40 13 restrict restrict VERB eurjchem-131 40 14     SPACE eurjchem-131 40 15 protons proton NOUN eurjchem-131 40 16     SPACE eurjchem-131 40 17 ( ( PUNCT eurjchem-131 40 18 å å NOUN eurjchem-131 40 19 ) ) PUNCT eurjchem-131 40 20     SPACE eurjchem-131 40 21 h­20 h­20 NOUN eurjchem-131 40 22     SPACE eurjchem-131 40 23 with with ADP eurjchem-131 40 24     SPACE eurjchem-131 40 25 h­22 h­22 PROPN eurjchem-131 40 26 , , PUNCT eurjchem-131 40 27     SPACE eurjchem-131 40 28 23a 23a NOUN eurjchem-131 40 29     SPACE eurjchem-131 40 30 h­22 h­22 NOUN eurjchem-131 40 31     SPACE eurjchem-131 40 32 with with ADP eurjchem-131 40 33     SPACE eurjchem-131 40 34 h­23b h­23b NOUN eurjchem-131 40 35     SPACE eurjchem-131 40 36 h­1"with h­1"with PROPN eurjchem-131 40 37     SPACE eurjchem-131 40 38 h­22,23,3",5"b h­22,23,3",5"b NOUN eurjchem-131 40 39     SPACE eurjchem-131 40 40 h­3"with h­3"with PROPN eurjchem-131 40 41     SPACE eurjchem-131 40 42 h­5"b h­5"b NOUN eurjchem-131 40 43     SPACE eurjchem-131 40 44 1 1 NUM eurjchem-131 40 45     SPACE eurjchem-131 40 46 3.51 3.51 NUM eurjchem-131 40 47 , , PUNCT eurjchem-131 40 48     SPACE eurjchem-131 40 49 3.60 3.60 NUM eurjchem-131 40 50     SPACE eurjchem-131 40 51 2.45 2.45 NUM eurjchem-131 40 52 3.70 3.70 NUM eurjchem-131 40 53 , , PUNCT eurjchem-131 40 54     SPACE eurjchem-131 40 55 4.01 4.01 NUM eurjchem-131 40 56 , , PUNCT eurjchem-131 40 57     SPACE eurjchem-131 40 58 2.84 2.84 NUM eurjchem-131 40 59 , , PUNCT eurjchem-131 40 60     SPACE eurjchem-131 40 61 2.61 2.61 NUM eurjchem-131 40 62 2.52 2.52 NUM eurjchem-131 40 63 2 2 NUM eurjchem-131 40 64     SPACE eurjchem-131 40 65 3.51 3.51 NUM eurjchem-131 40 66 , , PUNCT eurjchem-131 40 67     SPACE eurjchem-131 40 68 3.59 3.59 NUM eurjchem-131 40 69     SPACE eurjchem-131 40 70 2.45 2.45 NUM eurjchem-131 40 71 2.26 2.26 NUM eurjchem-131 40 72 , , PUNCT eurjchem-131 40 73     SPACE eurjchem-131 40 74 3.36 3.36 NUM eurjchem-131 40 75 , , PUNCT eurjchem-131 40 76     SPACE eurjchem-131 40 77 2.44 2.44 NUM eurjchem-131 40 78 , , PUNCT eurjchem-131 40 79     SPACE eurjchem-131 40 80 2.43 2.43 NUM eurjchem-131 40 81 2.79 2.79 NUM eurjchem-131 40 82 3 3 NUM eurjchem-131 40 83     SPACE eurjchem-131 40 84 2.37 2.37 NUM eurjchem-131 40 85 , , PUNCT eurjchem-131 40 86     SPACE eurjchem-131 40 87 3.82 3.82 NUM eurjchem-131 40 88     SPACE eurjchem-131 40 89 2.44 2.44 NUM eurjchem-131 40 90 2.27 2.27 NUM eurjchem-131 40 91 , , PUNCT eurjchem-131 40 92     SPACE eurjchem-131 40 93 3.44 3.44 NUM eurjchem-131 40 94 , , PUNCT eurjchem-131 40 95     SPACE eurjchem-131 40 96 2.57 2.57 NUM eurjchem-131 40 97 , , PUNCT eurjchem-131 40 98     SPACE eurjchem-131 40 99 2.41 2.41 NUM eurjchem-131 40 100 2.96 2.96 NUM eurjchem-131 40 101 4 4 NUM eurjchem-131 40 102     SPACE eurjchem-131 40 103 2.41 2.41 NUM eurjchem-131 40 104 , , PUNCT eurjchem-131 40 105     SPACE eurjchem-131 40 106 3.88 3.88 NUM eurjchem-131 40 107     SPACE eurjchem-131 40 108 2.44 2.44 NUM eurjchem-131 40 109 3.99 3.99 NUM eurjchem-131 40 110 , , PUNCT eurjchem-131 40 111     SPACE eurjchem-131 40 112 3.57 3.57 NUM eurjchem-131 40 113 , , PUNCT eurjchem-131 40 114     SPACE eurjchem-131 40 115 3.69 3.69 NUM eurjchem-131 40 116 , , PUNCT eurjchem-131 40 117     SPACE eurjchem-131 40 118 2.55 2.55 NUM eurjchem-131 40 119 4.22 4.22 NUM eurjchem-131 40 120 a a PRON eurjchem-131 40 121     SPACE eurjchem-131 40 122 without without ADP eurjchem-131 40 123     SPACE eurjchem-131 40 124 noesy noesy NOUN eurjchem-131 40 125     SPACE eurjchem-131 40 126 contours contours PROPN eurjchem-131 40 127 . . PUNCT eurjchem-131 40 128     SPACE eurjchem-131 41 1 b b X eurjchem-131 41 2     SPACE eurjchem-131 41 3 exhibited exhibit VERB eurjchem-131 41 4     SPACE eurjchem-131 41 5 noesy noesy PROPN eurjchem-131 41 6     SPACE eurjchem-131 41 7 contours contours PROPN eurjchem-131 41 8 . . PUNCT eurjchem-131 41 9         SPACE eurjchem-131 42 1 molecular molecular ADJ eurjchem-131 42 2     SPACE eurjchem-131 42 3 modeling modeling NOUN eurjchem-131 42 4 : : PUNCT eurjchem-131 42 5     SPACE eurjchem-131 42 6 1 1 NUM eurjchem-131 42 7 ) ) PUNCT eurjchem-131 42 8     SPACE eurjchem-131 42 9 the the DET eurjchem-131 42 10     SPACE eurjchem-131 42 11 configurations configuration NOUN eurjchem-131 42 12     SPACE eurjchem-131 42 13 of of ADP eurjchem-131 42 14     SPACE eurjchem-131 42 15 h‐22 h‐22 PROPN eurjchem-131 42 16 , , PUNCT eurjchem-131 42 17     SPACE eurjchem-131 42 18 h‐23 h‐23 PROPN eurjchem-131 42 19 , , PUNCT eurjchem-131 42 20     SPACE eurjchem-131 42 21 h‐1 h‐1 PROPN eurjchem-131 42 22 , , PUNCT eurjchem-131 42 23     SPACE eurjchem-131 42 24 h‐3 h‐3 NOUN eurjchem-131 42 25     SPACE eurjchem-131 42 26 and and CCONJ eurjchem-131 42 27     SPACE eurjchem-131 42 28 h‐5 h‐5 NOUN eurjchem-131 42 29     SPACE eurjchem-131 42 30 were be AUX eurjchem-131 42 31     SPACE eurjchem-131 42 32 α α NOUN eurjchem-131 42 33 , , PUNCT eurjchem-131 42 34     SPACE eurjchem-131 42 35 the the DET eurjchem-131 42 36     SPACE eurjchem-131 42 37 configuration configuration NOUN eurjchem-131 42 38     SPACE eurjchem-131 42 39 of of ADP eurjchem-131 42 40     SPACE eurjchem-131 42 41 2‐oh 2‐oh NOUN eurjchem-131 42 42     SPACE eurjchem-131 42 43 was be AUX eurjchem-131 42 44     SPACE eurjchem-131 42 45 α α NOUN eurjchem-131 42 46 ; ; PUNCT eurjchem-131 42 47     SPACE eurjchem-131 42 48 2 2 NUM eurjchem-131 42 49 ) ) PUNCT eurjchem-131 42 50     SPACE eurjchem-131 42 51 the the DET eurjchem-131 42 52     SPACE eurjchem-131 42 53 configurations configuration NOUN eurjchem-131 42 54     SPACE eurjchem-131 42 55 of of ADP eurjchem-131 42 56     SPACE eurjchem-131 42 57 h‐22 h‐22 PROPN eurjchem-131 42 58 , , PUNCT eurjchem-131 42 59     SPACE eurjchem-131 42 60 h‐23 h‐23 PROPN eurjchem-131 42 61 , , PUNCT eurjchem-131 42 62     SPACE eurjchem-131 42 63 h‐1 h‐1 PROPN eurjchem-131 42 64 , , PUNCT eurjchem-131 42 65     SPACE eurjchem-131 42 66 h‐3 h‐3 NOUN eurjchem-131 42 67     SPACE eurjchem-131 42 68 and and CCONJ eurjchem-131 42 69     SPACE eurjchem-131 42 70 h‐5 h‐5 NOUN eurjchem-131 42 71     SPACE eurjchem-131 42 72 were be AUX eurjchem-131 42 73     SPACE eurjchem-131 42 74 α α NOUN eurjchem-131 42 75 , , PUNCT eurjchem-131 42 76     SPACE eurjchem-131 42 77 the the DET eurjchem-131 42 78     SPACE eurjchem-131 42 79 configuration configuration NOUN eurjchem-131 42 80     SPACE eurjchem-131 42 81 of of ADP eurjchem-131 42 82     SPACE eurjchem-131 42 83 2‐oh 2‐oh NOUN eurjchem-131 42 84     SPACE eurjchem-131 42 85 was be AUX eurjchem-131 42 86     SPACE eurjchem-131 42 87 β β X eurjchem-131 42 88 ; ; PUNCT eurjchem-131 42 89     SPACE eurjchem-131 42 90 3 3 NUM eurjchem-131 42 91 ) ) PUNCT eurjchem-131 42 92     SPACE eurjchem-131 42 93 the the DET eurjchem-131 42 94     SPACE eurjchem-131 42 95 configurations configuration NOUN eurjchem-131 42 96     SPACE eurjchem-131 42 97 of of ADP eurjchem-131 42 98     SPACE eurjchem-131 42 99 h‐22 h‐22 PROPN eurjchem-131 42 100 , , PUNCT eurjchem-131 42 101     SPACE eurjchem-131 42 102 h‐ h‐ PROPN eurjchem-131 42 103 23 23 NUM eurjchem-131 42 104 , , PUNCT eurjchem-131 42 105     SPACE eurjchem-131 42 106 h‐1 h‐1 PROPN eurjchem-131 42 107 , , PUNCT eurjchem-131 42 108     SPACE eurjchem-131 42 109 h‐3 h‐3 NOUN eurjchem-131 42 110     SPACE eurjchem-131 42 111 and and CCONJ eurjchem-131 42 112     SPACE eurjchem-131 42 113 h‐5 h‐5 NOUN eurjchem-131 42 114     SPACE eurjchem-131 42 115 were be AUX eurjchem-131 42 116     SPACE eurjchem-131 42 117 β β NOUN eurjchem-131 42 118 , , PUNCT eurjchem-131 42 119     SPACE eurjchem-131 42 120 the the DET eurjchem-131 42 121     SPACE eurjchem-131 42 122 configuration configuration NOUN eurjchem-131 42 123     SPACE eurjchem-131 42 124 of of ADP eurjchem-131 42 125     SPACE eurjchem-131 42 126 2‐oh 2‐oh NOUN eurjchem-131 42 127     SPACE eurjchem-131 42 128 was be AUX eurjchem-131 42 129     SPACE eurjchem-131 42 130 α α NOUN eurjchem-131 42 131 ; ; PUNCT eurjchem-131 42 132     SPACE eurjchem-131 42 133 4 4 NUM eurjchem-131 42 134 ) ) PUNCT eurjchem-131 42 135     SPACE eurjchem-131 42 136 the the DET eurjchem-131 42 137     SPACE eurjchem-131 42 138 configurations configuration NOUN eurjchem-131 42 139     SPACE eurjchem-131 42 140 of of ADP eurjchem-131 42 141     SPACE eurjchem-131 42 142 h‐22 h‐22 PROPN eurjchem-131 42 143 , , PUNCT eurjchem-131 42 144     SPACE eurjchem-131 42 145 h‐23 h‐23 VERB eurjchem-131 42 146 , , PUNCT eurjchem-131 42 147     SPACE eurjchem-131 42 148 h‐1 h‐1 PROPN eurjchem-131 42 149 , , PUNCT eurjchem-131 42 150     SPACE eurjchem-131 42 151 h‐3 h‐3 NOUN eurjchem-131 42 152     SPACE eurjchem-131 42 153 and and CCONJ eurjchem-131 42 154     SPACE eurjchem-131 42 155 h‐5 h‐5 NOUN eurjchem-131 42 156     SPACE eurjchem-131 42 157 were be AUX eurjchem-131 42 158     SPACE eurjchem-131 42 159 β β NOUN eurjchem-131 42 160 , , PUNCT eurjchem-131 42 161     SPACE eurjchem-131 42 162 the the DET eurjchem-131 42 163     SPACE eurjchem-131 42 164 configuration configuration NOUN eurjchem-131 42 165     SPACE eurjchem-131 42 166 of of ADP eurjchem-131 42 167     SPACE eurjchem-131 42 168 2‐oh 2‐oh NOUN eurjchem-131 42 169     SPACE eurjchem-131 42 170 was be AUX eurjchem-131 42 171     SPACE eurjchem-131 42 172 β β X eurjchem-131 42 173 . . PUNCT eurjchem-131 42 174     SPACE eurjchem-131 42 175 theoretical theoretical ADJ eurjchem-131 42 176     SPACE eurjchem-131 42 177 calculations calculation NOUN eurjchem-131 42 178     SPACE eurjchem-131 42 179 using use VERB eurjchem-131 42 180     SPACE eurjchem-131 42 181 am1 am1 PROPN eurjchem-131 42 182     SPACE eurjchem-131 42 183 quantum quantum NOUN eurjchem-131 42 184     SPACE eurjchem-131 42 185 chemical chemical NOUN eurjchem-131 42 186     SPACE eurjchem-131 42 187 method method NOUN eurjchem-131 42 188     SPACE eurjchem-131 42 189 for for ADP eurjchem-131 42 190     SPACE eurjchem-131 42 191 above above ADP eurjchem-131 42 192     SPACE eurjchem-131 42 193 modeling modeling NOUN eurjchem-131 42 194     SPACE eurjchem-131 42 195 yield yield NOUN eurjchem-131 42 196     SPACE eurjchem-131 42 197 very very ADV eurjchem-131 42 198     SPACE eurjchem-131 42 199 interesting interesting ADJ eurjchem-131 42 200     SPACE eurjchem-131 42 201 information information NOUN eurjchem-131 42 202     SPACE eurjchem-131 42 203 to to PART eurjchem-131 42 204     SPACE eurjchem-131 42 205 support support VERB eurjchem-131 42 206     SPACE eurjchem-131 42 207 the the DET eurjchem-131 42 208     SPACE eurjchem-131 42 209 configurations configuration NOUN eurjchem-131 42 210     SPACE eurjchem-131 42 211 of of ADP eurjchem-131 42 212     SPACE eurjchem-131 42 213 h‐22 h‐22 PROPN eurjchem-131 42 214 , , PUNCT eurjchem-131 42 215     SPACE eurjchem-131 42 216 h‐23 h‐23 VERB eurjchem-131 42 217 , , PUNCT eurjchem-131 42 218     SPACE eurjchem-131 42 219 h‐1 h‐1 PROPN eurjchem-131 42 220 , , PUNCT eurjchem-131 42 221     SPACE eurjchem-131 42 222 h‐3 h‐3 NOUN eurjchem-131 42 223 , , PUNCT eurjchem-131 42 224     SPACE eurjchem-131 42 225 h‐5 h‐5 NOUN eurjchem-131 42 226     SPACE eurjchem-131 42 227 and and CCONJ eurjchem-131 42 228     SPACE eurjchem-131 42 229 2‐oh 2‐oh NOUN eurjchem-131 42 230 . . PUNCT eurjchem-131 42 231     SPACE eurjchem-131 43 1 according accord VERB eurjchem-131 43 2     SPACE eurjchem-131 43 3 to to ADP eurjchem-131 43 4     SPACE eurjchem-131 43 5 the the DET eurjchem-131 43 6     SPACE eurjchem-131 43 7 distance distance NOUN eurjchem-131 43 8     SPACE eurjchem-131 43 9 between between ADP eurjchem-131 43 10     SPACE eurjchem-131 43 11 two two NUM eurjchem-131 43 12     SPACE eurjchem-131 43 13 protons proton NOUN eurjchem-131 43 14     SPACE eurjchem-131 43 15 with with ADP eurjchem-131 43 16     SPACE eurjchem-131 43 17 noesy noesy NOUN eurjchem-131 43 18     SPACE eurjchem-131 43 19 correlations correlation NOUN eurjchem-131 43 20     SPACE eurjchem-131 43 21 less less ADJ eurjchem-131 43 22     SPACE eurjchem-131 43 23 than than ADP eurjchem-131 43 24     SPACE eurjchem-131 43 25 3.5 3.5 NUM eurjchem-131 43 26     SPACE eurjchem-131 43 27 å å NOUN eurjchem-131 43 28 , , PUNCT eurjchem-131 43 29     SPACE eurjchem-131 43 30 only only ADV eurjchem-131 43 31     SPACE eurjchem-131 43 32 the the DET eurjchem-131 43 33     SPACE eurjchem-131 43 34 second second ADJ eurjchem-131 43 35     SPACE eurjchem-131 43 36 modeling modeling NOUN eurjchem-131 43 37     SPACE eurjchem-131 43 38 was be AUX eurjchem-131 43 39     SPACE eurjchem-131 43 40 agreement agreement NOUN eurjchem-131 43 41     SPACE eurjchem-131 43 42 with with ADP eurjchem-131 43 43     SPACE eurjchem-131 43 44 the the DET eurjchem-131 43 45     SPACE eurjchem-131 43 46 noesy noesy NOUN eurjchem-131 43 47     SPACE eurjchem-131 43 48 experiment experiment NOUN eurjchem-131 43 49     SPACE eurjchem-131 43 50 ( ( PUNCT eurjchem-131 43 51 table table NOUN eurjchem-131 43 52     SPACE eurjchem-131 43 53 2 2 NUM eurjchem-131 43 54 ) ) PUNCT eurjchem-131 43 55 . . PUNCT eurjchem-131 43 56     SPACE eurjchem-131 44 1 thus thus ADV eurjchem-131 44 2 , , PUNCT eurjchem-131 44 3     SPACE eurjchem-131 44 4 the the DET eurjchem-131 44 5     SPACE eurjchem-131 44 6 configurations configuration NOUN eurjchem-131 44 7     SPACE eurjchem-131 44 8 of of ADP eurjchem-131 44 9     SPACE eurjchem-131 44 10 h‐22 h‐22 PROPN eurjchem-131 44 11 , , PUNCT eurjchem-131 44 12     SPACE eurjchem-131 44 13 h‐23 h‐23 PROPN eurjchem-131 44 14 , , PUNCT eurjchem-131 44 15     SPACE eurjchem-131 44 16 h‐1 h‐1 PROPN eurjchem-131 44 17 , , PUNCT eurjchem-131 44 18     SPACE eurjchem-131 44 19 h‐3 h‐3 NOUN eurjchem-131 44 20     SPACE eurjchem-131 44 21 and and CCONJ eurjchem-131 44 22     SPACE eurjchem-131 44 23 h‐5 h‐5 NOUN eurjchem-131 44 24     SPACE eurjchem-131 44 25 were be AUX eurjchem-131 44 26     SPACE eurjchem-131 44 27 α α NOUN eurjchem-131 44 28 , , PUNCT eurjchem-131 44 29     SPACE eurjchem-131 44 30 and and CCONJ eurjchem-131 44 31     SPACE eurjchem-131 44 32 the the DET eurjchem-131 44 33     SPACE eurjchem-131 44 34 configuration configuration NOUN eurjchem-131 44 35     SPACE eurjchem-131 44 36 of of ADP eurjchem-131 44 37     SPACE eurjchem-131 44 38 2‐oh 2‐oh NOUN eurjchem-131 44 39     SPACE eurjchem-131 44 40 was be AUX eurjchem-131 44 41     SPACE eurjchem-131 44 42 β β X eurjchem-131 44 43 . . PUNCT eurjchem-131 44 44         SPACE eurjchem-131 44 45 acknowledgement acknowledgement NOUN eurjchem-131 44 46         SPACE eurjchem-131 44 47 this this DET eurjchem-131 44 48     SPACE eurjchem-131 44 49 work work NOUN eurjchem-131 44 50     SPACE eurjchem-131 44 51 was be AUX eurjchem-131 44 52     SPACE eurjchem-131 44 53 financially financially ADV eurjchem-131 44 54     SPACE eurjchem-131 44 55 supported support VERB eurjchem-131 44 56     SPACE eurjchem-131 44 57 by by ADP eurjchem-131 44 58     SPACE eurjchem-131 44 59 the the DET eurjchem-131 44 60     SPACE eurjchem-131 44 61 natural natural ADJ eurjchem-131 44 62     SPACE eurjchem-131 44 63 science science NOUN eurjchem-131 44 64     SPACE eurjchem-131 44 65 foundation foundation NOUN eurjchem-131 44 66     SPACE eurjchem-131 44 67 of of ADP eurjchem-131 44 68     SPACE eurjchem-131 44 69 yunnan yunnan NOUN eurjchem-131 44 70     SPACE eurjchem-131 44 71 province province NOUN eurjchem-131 44 72     SPACE eurjchem-131 44 73 ( ( PUNCT eurjchem-131 44 74 2008cd158 2008cd158 NUM eurjchem-131 44 75 ) ) PUNCT eurjchem-131 44 76 , , PUNCT eurjchem-131 44 77     SPACE eurjchem-131 44 78 the the DET eurjchem-131 44 79     SPACE eurjchem-131 44 80 western western ADJ eurjchem-131 44 81     SPACE eurjchem-131 44 82 doctoral doctoral ADJ eurjchem-131 44 83     SPACE eurjchem-131 44 84 foundation foundation NOUN eurjchem-131 44 85     SPACE eurjchem-131 44 86 of of ADP eurjchem-131 44 87     SPACE eurjchem-131 44 88 chinese chinese ADJ eurjchem-131 44 89     SPACE eurjchem-131 44 90 academy academy NOUN eurjchem-131 44 91     SPACE eurjchem-131 44 92 of of ADP eurjchem-131 44 93     SPACE eurjchem-131 44 94 sciences science NOUN eurjchem-131 44 95     SPACE eurjchem-131 44 96 ( ( PUNCT eurjchem-131 44 97 j.‐c.c j.‐c.c PROPN eurjchem-131 44 98 ) ) PUNCT eurjchem-131 44 99 , , PUNCT eurjchem-131 44 100     SPACE eurjchem-131 44 101 the the DET eurjchem-131 44 102     SPACE eurjchem-131 44 103 foundation foundation NOUN eurjchem-131 44 104     SPACE eurjchem-131 44 105 of of ADP eurjchem-131 44 106     SPACE eurjchem-131 44 107 state state NOUN eurjchem-131 44 108     SPACE eurjchem-131 44 109 key key ADJ eurjchem-131 44 110     SPACE eurjchem-131 44 111 laboratory laboratory NOUN eurjchem-131 44 112     SPACE eurjchem-131 44 113 of of ADP eurjchem-131 44 114     SPACE eurjchem-131 44 115 phytochemistry phytochemistry NOUN eurjchem-131 44 116     SPACE eurjchem-131 44 117 and and CCONJ eurjchem-131 44 118     SPACE eurjchem-131 44 119 plant plant NOUN eurjchem-131 44 120     SPACE eurjchem-131 44 121 resources resource NOUN eurjchem-131 44 122     SPACE eurjchem-131 44 123 in in ADP eurjchem-131 44 124     SPACE eurjchem-131 44 125 west west PROPN eurjchem-131 44 126     SPACE eurjchem-131 44 127 china china PROPN eurjchem-131 44 128 , , PUNCT eurjchem-131 44 129     SPACE eurjchem-131 44 130 kunming kunming PROPN eurjchem-131 44 131     SPACE eurjchem-131 44 132 institute institute NOUN eurjchem-131 44 133     SPACE eurjchem-131 44 134 of of ADP eurjchem-131 44 135     SPACE eurjchem-131 44 136 botany botany NOUN eurjchem-131 44 137 , , PUNCT eurjchem-131 44 138     SPACE eurjchem-131 44 139 chinese chinese PROPN eurjchem-131 44 140     SPACE eurjchem-131 44 141 academy academy NOUN eurjchem-131 44 142     SPACE eurjchem-131 44 143 of of ADP eurjchem-131 44 144     SPACE eurjchem-131 44 145 sciences science NOUN eurjchem-131 44 146     SPACE eurjchem-131 44 147 ( ( PUNCT eurjchem-131 44 148 p2008zz23 p2008zz23 PROPN eurjchem-131 44 149 , , PUNCT eurjchem-131 44 150     SPACE eurjchem-131 44 151 p2010zz14 p2010zz14 NOUN eurjchem-131 44 152 ) ) PUNCT eurjchem-131 44 153 , , PUNCT eurjchem-131 44 154     SPACE eurjchem-131 44 155 and and CCONJ eurjchem-131 44 156     SPACE eurjchem-131 44 157 the the DET eurjchem-131 44 158     SPACE eurjchem-131 44 159 cooperative cooperative ADJ eurjchem-131 44 160     SPACE eurjchem-131 44 161 project project NOUN eurjchem-131 44 162     SPACE eurjchem-131 44 163 of of ADP eurjchem-131 44 164     SPACE eurjchem-131 44 165 guangdong guangdong PROPN eurjchem-131 44 166     SPACE eurjchem-131 44 167 province province NOUN eurjchem-131 44 168     SPACE eurjchem-131 44 169 and and CCONJ eurjchem-131 44 170     SPACE eurjchem-131 44 171 cas cas PROPN eurjchem-131 44 172     SPACE eurjchem-131 44 173 ( ( PUNCT eurjchem-131 44 174 2009b091300135 2009b091300135 PROPN eurjchem-131 44 175 ) ) PUNCT eurjchem-131 44 176 . . PUNCT eurjchem-131 44 177           SPACE eurjchem-131 45 1 references reference NOUN eurjchem-131 45 2         SPACE eurjchem-131 45 3 [ [ X eurjchem-131 45 4 1 1 NUM eurjchem-131 45 5 ] ] PUNCT eurjchem-131 45 6 . . PUNCT eurjchem-131 46 1 basch basch PROPN eurjchem-131 46 2 , , PUNCT eurjchem-131 46 3     SPACE eurjchem-131 46 4 e. e. PROPN eurjchem-131 46 5 ; ; PUNCT eurjchem-131 46 6     SPACE eurjchem-131 46 7 gabardi gabardi PROPN eurjchem-131 46 8 , , PUNCT eurjchem-131 46 9     SPACE eurjchem-131 46 10 s. s. PROPN eurjchem-131 46 11 ; ; PUNCT eurjchem-131 46 12     SPACE eurjchem-131 46 13 ulbricht ulbricht NOUN eurjchem-131 46 14 , , PUNCT eurjchem-131 46 15     SPACE eurjchem-131 46 16 c. c. PROPN eurjchem-131 46 17     SPACE eurjchem-131 46 18 am be AUX eurjchem-131 46 19 . . PUNCT eurjchem-131 46 20     SPACE eurjchem-131 46 21 j. j. PROPN eurjchem-131 46 22     SPACE eurjchem-131 46 23 health­syst health­syst NOUN eurjchem-131 46 24 . . PUNCT eurjchem-131 46 25     SPACE eurjchem-131 46 26 pharm pharm PROPN eurjchem-131 46 27 . . PUNCT eurjchem-131 46 28     SPACE eurjchem-131 46 29 2003 2003 NUM eurjchem-131 46 30 , , PUNCT eurjchem-131 46 31     SPACE eurjchem-131 46 32 60 60 NUM eurjchem-131 46 33 , , PUNCT eurjchem-131 46 34     SPACE eurjchem-131 46 35 356‐359 356‐359 NUM eurjchem-131 46 36 . . PUNCT eurjchem-131 46 37     SPACE eurjchem-131 47 1 [ [ X eurjchem-131 47 2 2 2 NUM eurjchem-131 47 3 ] ] PUNCT eurjchem-131 47 4 . . PUNCT eurjchem-131 48 1 tan tan PROPN eurjchem-131 48 2 , , PUNCT eurjchem-131 48 3     SPACE eurjchem-131 48 4 m. m. NOUN eurjchem-131 48 5     SPACE eurjchem-131 48 6 j. j. PROPN eurjchem-131 48 7 ; ; PUNCT eurjchem-131 48 8     SPACE eurjchem-131 48 9 ye ye PROPN eurjchem-131 48 10 , , PUNCT eurjchem-131 48 11     SPACE eurjchem-131 48 12 j. j. PROPN eurjchem-131 48 13     SPACE eurjchem-131 48 14 m. m. NOUN eurjchem-131 48 15 ; ; PUNCT eurjchem-131 48 16     SPACE eurjchem-131 48 17 turner turner NOUN eurjchem-131 48 18 , , PUNCT eurjchem-131 48 19     SPACE eurjchem-131 48 20 n. n. NOUN eurjchem-131 48 21 ; ; PUNCT eurjchem-131 48 22     SPACE eurjchem-131 48 23 cordula cordula NOUN eurjchem-131 48 24 , , PUNCT eurjchem-131 48 25     SPACE eurjchem-131 48 26 h. h. PROPN eurjchem-131 48 27     SPACE eurjchem-131 48 28 b. b. PROPN eurjchem-131 48 29 ; ; PUNCT eurjchem-131 48 30     SPACE eurjchem-131 48 31 ke ke PROPN eurjchem-131 48 32 , , PUNCT eurjchem-131 48 33     SPACE eurjchem-131 48 34 c. c. PROPN eurjchem-131 48 35     SPACE eurjchem-131 48 36 q. q. PROPN eurjchem-131 48 37     SPACE eurjchem-131 48 38 chem chem NOUN eurjchem-131 48 39 . . PUNCT eurjchem-131 48 40     SPACE eurjchem-131 48 41 biol biol PROPN eurjchem-131 48 42 . . PUNCT eurjchem-131 48 43     SPACE eurjchem-131 48 44 2008 2008 NUM eurjchem-131 48 45 , , PUNCT eurjchem-131 48 46     SPACE eurjchem-131 48 47 15 15 NUM eurjchem-131 48 48 , , PUNCT eurjchem-131 48 49     SPACE eurjchem-131 48 50 263‐273 263‐273 NUM eurjchem-131 48 51 . . PUNCT eurjchem-131 48 52     SPACE eurjchem-131 49 1 [ [ X eurjchem-131 49 2 3 3 NUM eurjchem-131 49 3 ] ] PUNCT eurjchem-131 49 4 . . PUNCT eurjchem-131 50 1 chen chen PROPN eurjchem-131 50 2 , , PUNCT eurjchem-131 50 3     SPACE eurjchem-131 50 4 j. j. PROPN eurjchem-131 50 5     SPACE eurjchem-131 50 6 c. c. PROPN eurjchem-131 50 7 ; ; PUNCT eurjchem-131 50 8     SPACE eurjchem-131 50 9 tian tian ADJ eurjchem-131 50 10 , , PUNCT eurjchem-131 50 11     SPACE eurjchem-131 50 12 r. r. PROPN eurjchem-131 50 13     SPACE eurjchem-131 50 14 r. r. PROPN eurjchem-131 50 15 ; ; PUNCT eurjchem-131 50 16     SPACE eurjchem-131 50 17 qiu qiu PROPN eurjchem-131 50 18 , , PUNCT eurjchem-131 50 19     SPACE eurjchem-131 50 20 m. m. NOUN eurjchem-131 50 21     SPACE eurjchem-131 50 22 h. h. PROPN eurjchem-131 50 23 ; ; PUNCT eurjchem-131 50 24     SPACE eurjchem-131 50 25 lu lu PROPN eurjchem-131 50 26 , , PUNCT eurjchem-131 50 27     SPACE eurjchem-131 50 28 l. l. PROPN eurjchem-131 50 29 ; ; PUNCT eurjchem-131 50 30     SPACE eurjchem-131 50 31 zheng zheng PROPN eurjchem-131 50 32 , , PUNCT eurjchem-131 50 33     SPACE eurjchem-131 50 34 y. y. NOUN eurjchem-131 50 35     SPACE eurjchem-131 50 36 t. t. PROPN eurjchem-131 50 37 ; ; PUNCT eurjchem-131 50 38     SPACE eurjchem-131 50 39 zhang zhang PROPN eurjchem-131 50 40 , , PUNCT eurjchem-131 50 41     SPACE eurjchem-131 50 42 z. z. PROPN eurjchem-131 50 43     SPACE eurjchem-131 50 44 q. q. PROPN eurjchem-131 50 45     SPACE eurjchem-131 50 46 phytochemistry phytochemistry PROPN eurjchem-131 50 47     SPACE eurjchem-131 50 48 2008 2008 NUM eurjchem-131 50 49 , , PUNCT eurjchem-131 50 50     SPACE eurjchem-131 50 51 69 69 NUM eurjchem-131 50 52 , , PUNCT eurjchem-131 50 53     SPACE eurjchem-131 50 54 1043‐1048 1043‐1048 NUM eurjchem-131 50 55 . . PUNCT eurjchem-131 50 56     SPACE eurjchem-131 51 1 [ [ X eurjchem-131 51 2 4 4 NUM eurjchem-131 51 3 ] ] PUNCT eurjchem-131 51 4 . . PUNCT eurjchem-131 51 5 akihisa akihisa PROPN eurjchem-131 51 6 , , PUNCT eurjchem-131 51 7     SPACE eurjchem-131 51 8 t. t. NOUN eurjchem-131 51 9 ; ; PUNCT eurjchem-131 51 10     SPACE eurjchem-131 51 11 higo higo ADJ eurjchem-131 51 12 , , PUNCT eurjchem-131 51 13     SPACE eurjchem-131 51 14 n. n. NOUN eurjchem-131 51 15 ; ; PUNCT eurjchem-131 51 16     SPACE eurjchem-131 51 17 tokuda tokuda NOUN eurjchem-131 51 18 , , PUNCT eurjchem-131 51 19     SPACE eurjchem-131 51 20 h. h. PROPN eurjchem-131 51 21 ; ; PUNCT eurjchem-131 51 22     SPACE eurjchem-131 51 23 ukiya ukiya PROPN eurjchem-131 51 24 , , PUNCT eurjchem-131 51 25     SPACE eurjchem-131 51 26 m. m. NOUN eurjchem-131 51 27 ; ; PUNCT eurjchem-131 51 28     SPACE eurjchem-131 51 29 akazawa akazawa PROPN eurjchem-131 51 30 , , PUNCT eurjchem-131 51 31     SPACE eurjchem-131 51 32 h. h. PROPN eurjchem-131 51 33 ; ; PUNCT eurjchem-131 51 34     SPACE eurjchem-131 51 35 tochigi tochigi NOUN eurjchem-131 51 36 , , PUNCT eurjchem-131 51 37     SPACE eurjchem-131 51 38 y. y. PROPN eurjchem-131 51 39     SPACE eurjchem-131 51 40 j. j. PROPN eurjchem-131 51 41     SPACE eurjchem-131 51 42 nat nat PROPN eurjchem-131 51 43 . . PUNCT eurjchem-131 51 44     SPACE eurjchem-131 51 45 prod prod NOUN eurjchem-131 51 46 . . PUNCT eurjchem-131 51 47     SPACE eurjchem-131 52 1 2007 2007 NUM eurjchem-131 52 2 , , PUNCT eurjchem-131 52 3     SPACE eurjchem-131 52 4 70 70 NUM eurjchem-131 52 5 , , PUNCT eurjchem-131 52 6     SPACE eurjchem-131 52 7 1233‐1239 1233‐1239 NUM eurjchem-131 52 8 . . PUNCT eurjchem-131 52 9     SPACE eurjchem-131 53 1 [ [ X eurjchem-131 53 2 5 5 NUM eurjchem-131 53 3 ] ] PUNCT eurjchem-131 53 4 . . PUNCT eurjchem-131 54 1 li li PROPN eurjchem-131 54 2 , , PUNCT eurjchem-131 54 3     SPACE eurjchem-131 54 4 q. q. PROPN eurjchem-131 54 5     SPACE eurjchem-131 54 6 y. y. PROPN eurjchem-131 54 7 ; ; PUNCT eurjchem-131 54 8     SPACE eurjchem-131 54 9 chen chen PROPN eurjchem-131 54 10 , , PUNCT eurjchem-131 54 11     SPACE eurjchem-131 54 12 h. h. PROPN eurjchem-131 54 13     SPACE eurjchem-131 54 14 b. b. PROPN eurjchem-131 54 15 ; ; PUNCT eurjchem-131 54 16     SPACE eurjchem-131 54 17 liu liu PROPN eurjchem-131 54 18 , , PUNCT eurjchem-131 54 19     SPACE eurjchem-131 54 20 z. z. PROPN eurjchem-131 54 21     SPACE eurjchem-131 54 22 m. m. NOUN eurjchem-131 54 23 ; ; PUNCT eurjchem-131 54 24     SPACE eurjchem-131 54 25 wang wang PROPN eurjchem-131 54 26 , , PUNCT eurjchem-131 54 27     SPACE eurjchem-131 54 28 b. b. PROPN eurjchem-131 54 29 ; ; PUNCT eurjchem-131 54 30     SPACE eurjchem-131 54 31 zhao zhao NOUN eurjchem-131 54 32 , , PUNCT eurjchem-131 54 33     SPACE eurjchem-131 54 34 y. y. NOUN eurjchem-131 54 35     SPACE eurjchem-131 54 36 y. y. PROPN eurjchem-131 54 37     SPACE eurjchem-131 54 38 magn magn PROPN eurjchem-131 54 39 . . PUNCT eurjchem-131 54 40     SPACE eurjchem-131 55 1 reson reson PROPN eurjchem-131 55 2 . . PUNCT eurjchem-131 55 3     SPACE eurjchem-131 56 1 chem chem NOUN eurjchem-131 56 2 . . PUNCT eurjchem-131 56 3     SPACE eurjchem-131 57 1 2007 2007 NUM eurjchem-131 57 2 , , PUNCT eurjchem-131 57 3     SPACE eurjchem-131 57 4 45 45 NUM eurjchem-131 57 5 , , PUNCT eurjchem-131 57 6     SPACE eurjchem-131 57 7 451‐456 451‐456 PROPN eurjchem-131 57 8 . . PUNCT eurjchem-131 57 9     SPACE eurjchem-131 58 1 [ [ X eurjchem-131 58 2 6 6 NUM eurjchem-131 58 3 ] ] PUNCT eurjchem-131 58 4 . . PUNCT eurjchem-131 59 1 okabe okabe PROPN eurjchem-131 59 2 , , PUNCT eurjchem-131 59 3     SPACE eurjchem-131 59 4 h. h. PROPN eurjchem-131 59 5 ; ; PUNCT eurjchem-131 59 6     SPACE eurjchem-131 59 7 miyahara miyahara PROPN eurjchem-131 59 8 , , PUNCT eurjchem-131 59 9     SPACE eurjchem-131 59 10 y. y. NOUN eurjchem-131 59 11 ; ; PUNCT eurjchem-131 59 12     SPACE eurjchem-131 59 13 yamauchi yamauchi NOUN eurjchem-131 59 14 , , PUNCT eurjchem-131 59 15     SPACE eurjchem-131 59 16 t. t. PROPN eurjchem-131 59 17 ; ; PUNCT eurjchem-131 59 18     SPACE eurjchem-131 59 19 mirahara mirahara NOUN eurjchem-131 59 20 , , PUNCT eurjchem-131 59 21     SPACE eurjchem-131 59 22 k. k. NOUN eurjchem-131 59 23     SPACE eurjchem-131 59 24 chem chem NOUN eurjchem-131 59 25 . . PUNCT eurjchem-131 59 26     SPACE eurjchem-131 60 1 pharm pharm PROPN eurjchem-131 60 2 . . PUNCT eurjchem-131 60 3     SPACE eurjchem-131 61 1 bull bull NOUN eurjchem-131 61 2 . . PUNCT eurjchem-131 61 3     SPACE eurjchem-131 62 1 1980 1980 NUM eurjchem-131 62 2 , , PUNCT eurjchem-131 62 3     SPACE eurjchem-131 62 4 28 28 NUM eurjchem-131 62 5 , , PUNCT eurjchem-131 62 6     SPACE eurjchem-131 62 7 2753‐2762 2753‐2762 NUM eurjchem-131 62 8 . . PUNCT eurjchem-131 62 9     SPACE eurjchem-131 63 1 [ [ X eurjchem-131 63 2 7 7 NUM eurjchem-131 63 3 ] ] PUNCT eurjchem-131 63 4 . . PUNCT eurjchem-131 63 5 matsuda matsuda PROPN eurjchem-131 63 6 , , PUNCT eurjchem-131 63 7     SPACE eurjchem-131 63 8 h. h. PROPN eurjchem-131 63 9 ; ; PUNCT eurjchem-131 63 10     SPACE eurjchem-131 63 11 nakamura nakamura NOUN eurjchem-131 63 12 , , PUNCT eurjchem-131 63 13     SPACE eurjchem-131 63 14 s. s. PROPN eurjchem-131 63 15 ; ; PUNCT eurjchem-131 63 16     SPACE eurjchem-131 63 17 murakami murakami NOUN eurjchem-131 63 18 , , PUNCT eurjchem-131 63 19     SPACE eurjchem-131 63 20 t. t. NOUN eurjchem-131 63 21 ; ; PUNCT eurjchem-131 63 22     SPACE eurjchem-131 63 23 yoshikawa yoshikawa PROPN eurjchem-131 63 24 , , PUNCT eurjchem-131 63 25     SPACE eurjchem-131 63 26 m. m. NOUN eurjchem-131 63 27     SPACE eurjchem-131 63 28 heterocycles heterocycle NOUN eurjchem-131 63 29     SPACE eurjchem-131 63 30 2007 2007 NUM eurjchem-131 63 31 , , PUNCT eurjchem-131 63 32     SPACE eurjchem-131 63 33 71 71 NUM eurjchem-131 63 34 , , PUNCT eurjchem-131 63 35     SPACE eurjchem-131 63 36 331‐341 331‐341 NUM eurjchem-131 63 37 . . PUNCT eurjchem-131 63 38     SPACE