id sid tid token lemma pos eurjchem-1480 1 1 untitled untitle VERB eurjchem-1480 1 2 european european PROPN eurjchem-1480 1 3 journal journal PROPN eurjchem-1480 1 4 of of ADP eurjchem-1480 1 5 chemistry chemistry NOUN eurjchem-1480 1 6 7 7 NUM eurjchem-1480 1 7 ( ( PUNCT eurjchem-1480 1 8 4 4 NUM eurjchem-1480 1 9 ) ) PUNCT eurjchem-1480 1 10 ( ( PUNCT eurjchem-1480 1 11 2016 2016 NUM eurjchem-1480 1 12 ) ) PUNCT eurjchem-1480 1 13 405‐409 405‐409 NUM eurjchem-1480 1 14 european european PROPN eurjchem-1480 1 15 journal journal PROPN eurjchem-1480 1 16 of of ADP eurjchem-1480 1 17 chemistry chemistry NOUN eurjchem-1480 1 18 issn issn PROPN eurjchem-1480 1 19 2153‐2249 2153‐2249 PROPN eurjchem-1480 1 20 ( ( PUNCT eurjchem-1480 1 21 print print NOUN eurjchem-1480 1 22 ) ) PUNCT eurjchem-1480 1 23 / / SYM eurjchem-1480 1 24 issn issn PROPN eurjchem-1480 1 25 2153‐2257 2153‐2257 NUM eurjchem-1480 1 26 ( ( PUNCT eurjchem-1480 1 27 online online ADJ eurjchem-1480 1 28 ) ) PUNCT eurjchem-1480 1 29   NOUN eurjchem-1480 1 30 2016 2016 NUM eurjchem-1480 1 31 atlanta atlanta PROPN eurjchem-1480 1 32 publishing publishing PROPN eurjchem-1480 1 33 house house PROPN eurjchem-1480 1 34 llc llc PROPN eurjchem-1480 1 35 ‐ ‐ PUNCT eurjchem-1480 1 36 all all DET eurjchem-1480 1 37 rights right NOUN eurjchem-1480 1 38 reserved reserve VERB eurjchem-1480 1 39 ‐ ‐ NOUN eurjchem-1480 1 40 printed print VERB eurjchem-1480 1 41 in in ADP eurjchem-1480 1 42 the the DET eurjchem-1480 1 43 usa usa PROPN eurjchem-1480 1 44 http://dx.doi.org/10.5155/eurjchem.7.4.405-409.1480 http://dx.doi.org/10.5155/eurjchem.7.4.405-409.1480 PROPN eurjchem-1480 1 45 european european PROPN eurjchem-1480 1 46 journal journal PROPN eurjchem-1480 1 47 of of ADP eurjchem-1480 1 48 chemistry chemistry PROPN eurjchem-1480 1 49 journal journal PROPN eurjchem-1480 1 50 webpage webpage NOUN eurjchem-1480 1 51 : : PUNCT eurjchem-1480 1 52 www.eurjchem.com www.eurjchem.com X eurjchem-1480 1 53 synthesis synthesis NOUN eurjchem-1480 1 54 , , PUNCT eurjchem-1480 1 55 characterization characterization NOUN eurjchem-1480 1 56 and and CCONJ eurjchem-1480 1 57 thermal thermal ADJ eurjchem-1480 1 58 properties property NOUN eurjchem-1480 1 59 of of ADP eurjchem-1480 1 60 the the DET eurjchem-1480 1 61 nano nano NOUN eurjchem-1480 1 62 four four NUM eurjchem-1480 1 63 arms arm NOUN eurjchem-1480 1 64 poly(pentaerythritollactide‐b‐n poly(pentaerythritollactide‐b‐n PROPN eurjchem-1480 1 65 , , PUNCT eurjchem-1480 1 66 n‐dimethylaminoethyl n‐dimethylaminoethyl X eurjchem-1480 1 67 methacrylate methacrylate NOUN eurjchem-1480 1 68 ) ) PUNCT eurjchem-1480 1 69 derivatives derivative NOUN eurjchem-1480 1 70 baqer baqer NOUN eurjchem-1480 1 71 al‐mayyahi al‐mayyahi NOUN eurjchem-1480 1 72 , , PUNCT eurjchem-1480 1 73 hadi hadi PROPN eurjchem-1480 1 74 al‐lami al‐lami PROPN eurjchem-1480 1 75 * * PUNCT eurjchem-1480 1 76 and and CCONJ eurjchem-1480 1 77 athir athir PROPN eurjchem-1480 1 78 haddad haddad PROPN eurjchem-1480 1 79 department department PROPN eurjchem-1480 1 80 of of ADP eurjchem-1480 1 81 chemistry chemistry NOUN eurjchem-1480 1 82 , , PUNCT eurjchem-1480 1 83 college college NOUN eurjchem-1480 1 84 of of ADP eurjchem-1480 1 85 science science NOUN eurjchem-1480 1 86 , , PUNCT eurjchem-1480 1 87 university university NOUN eurjchem-1480 1 88 of of ADP eurjchem-1480 1 89 basrah basrah PROPN eurjchem-1480 1 90 , , PUNCT eurjchem-1480 1 91 basrah basrah PROPN eurjchem-1480 1 92 , , PUNCT eurjchem-1480 1 93 61001 61001 NUM eurjchem-1480 1 94 , , PUNCT eurjchem-1480 1 95 iraq iraq PROPN eurjchem-1480 1 96 * * PUNCT eurjchem-1480 1 97 corresponding correspond VERB eurjchem-1480 1 98 author author NOUN eurjchem-1480 1 99 at at ADP eurjchem-1480 1 100 : : PUNCT eurjchem-1480 1 101 department department NOUN eurjchem-1480 1 102 of of ADP eurjchem-1480 1 103 chemistry chemistry NOUN eurjchem-1480 1 104 , , PUNCT eurjchem-1480 1 105 college college NOUN eurjchem-1480 1 106 of of ADP eurjchem-1480 1 107 science science NOUN eurjchem-1480 1 108 , , PUNCT eurjchem-1480 1 109 university university NOUN eurjchem-1480 1 110 of of ADP eurjchem-1480 1 111 basrah basrah PROPN eurjchem-1480 1 112 , , PUNCT eurjchem-1480 1 113 basrah basrah PROPN eurjchem-1480 1 114 , , PUNCT eurjchem-1480 1 115 61001 61001 NUM eurjchem-1480 1 116 , , PUNCT eurjchem-1480 1 117 iraq iraq PROPN eurjchem-1480 1 118 . . PUNCT eurjchem-1480 2 1 tel tel PROPN eurjchem-1480 2 2 . . PUNCT eurjchem-1480 2 3 : : PUNCT eurjchem-1480 3 1 +964.790.1681631 +964.790.1681631 PROPN eurjchem-1480 3 2 . . PUNCT eurjchem-1480 4 1 fax fax NOUN eurjchem-1480 4 2 : : PUNCT eurjchem-1480 4 3 +964.770.7377488 +964.770.7377488 PROPN eurjchem-1480 4 4 . . PUNCT eurjchem-1480 4 5 e‐mail e‐mail PUNCT eurjchem-1480 5 1 address address NOUN eurjchem-1480 5 2 : : PUNCT eurjchem-1480 5 3 hadisalman54@yahoo.com hadisalman54@yahoo.com PROPN eurjchem-1480 5 4 ( ( PUNCT eurjchem-1480 5 5 h. h. PROPN eurjchem-1480 5 6 al‐lami al‐lami PROPN eurjchem-1480 5 7 ) ) PUNCT eurjchem-1480 5 8 . . PUNCT eurjchem-1480 6 1 article article NOUN eurjchem-1480 6 2 information information PROPN eurjchem-1480 6 3 abstract abstract ADJ eurjchem-1480 6 4 doi doi PROPN eurjchem-1480 6 5 : : PUNCT eurjchem-1480 6 6     SPACE eurjchem-1480 6 7 10.5155 10.5155 NUM eurjchem-1480 6 8 / / SYM eurjchem-1480 6 9 eurjchem.7.4.405 eurjchem.7.4.405 PROPN eurjchem-1480 6 10 - - PUNCT eurjchem-1480 6 11 409.1480 409.1480 NUM eurjchem-1480 6 12 received receive VERB eurjchem-1480 6 13 : : PUNCT eurjchem-1480 6 14 27 27 NUM eurjchem-1480 6 15 july july NOUN eurjchem-1480 6 16 2016 2016 NUM eurjchem-1480 6 17 received receive VERB eurjchem-1480 6 18 in in ADP eurjchem-1480 6 19 revised revise VERB eurjchem-1480 6 20 form form NOUN eurjchem-1480 6 21 : : PUNCT eurjchem-1480 6 22 05 05 NUM eurjchem-1480 6 23 september september PROPN eurjchem-1480 6 24 2016 2016 NUM eurjchem-1480 6 25 accepted accept VERB eurjchem-1480 6 26 : : PUNCT eurjchem-1480 6 27 10 10 NUM eurjchem-1480 6 28 september september PROPN eurjchem-1480 6 29 2016 2016 NUM eurjchem-1480 6 30 published publish VERB eurjchem-1480 6 31 online online ADV eurjchem-1480 6 32 : : PUNCT eurjchem-1480 6 33 31 31 NUM eurjchem-1480 6 34 december december PROPN eurjchem-1480 6 35 2016 2016 NUM eurjchem-1480 6 36 printed print VERB eurjchem-1480 6 37 : : PUNCT eurjchem-1480 6 38 31 31 NUM eurjchem-1480 6 39 december december PROPN eurjchem-1480 6 40 2016 2016 NUM eurjchem-1480 6 41     SPACE eurjchem-1480 6 42 the the DET eurjchem-1480 6 43 nano nano NOUN eurjchem-1480 6 44 four four NUM eurjchem-1480 6 45 arms arm NOUN eurjchem-1480 6 46 poly(lactide‐b‐n poly(lactide‐b‐n NOUN eurjchem-1480 6 47 , , PUNCT eurjchem-1480 6 48 n‐dimethylaminoethylmethacrylate n‐dimethylaminoethylmethacrylate NUM eurjchem-1480 6 49 ) ) PUNCT eurjchem-1480 6 50 were be AUX eurjchem-1480 6 51 prepared prepare VERB eurjchem-1480 6 52 by by ADP eurjchem-1480 6 53 pentaerythritol‐lactide pentaerythritol‐lactide ADP eurjchem-1480 6 54 atom atom NOUN eurjchem-1480 6 55 transfer transfer NOUN eurjchem-1480 6 56 radical radical ADJ eurjchem-1480 6 57 polymerization polymerization NOUN eurjchem-1480 6 58 initiators initiator NOUN eurjchem-1480 6 59 having have VERB eurjchem-1480 6 60 different different ADJ eurjchem-1480 6 61 repeating repeat VERB eurjchem-1480 6 62 units unit NOUN eurjchem-1480 6 63 ( ( PUNCT eurjchem-1480 6 64 10 10 NUM eurjchem-1480 6 65 , , PUNCT eurjchem-1480 6 66 25 25 NUM eurjchem-1480 6 67 , , PUNCT eurjchem-1480 6 68 50 50 NUM eurjchem-1480 6 69 and and CCONJ eurjchem-1480 6 70 100 100 NUM eurjchem-1480 6 71 ) ) PUNCT eurjchem-1480 6 72 of of ADP eurjchem-1480 6 73 l‐lactide l‐lactide PUNCT eurjchem-1480 6 74 with with ADP eurjchem-1480 6 75 the the DET eurjchem-1480 6 76 same same ADJ eurjchem-1480 6 77 amount amount NOUN eurjchem-1480 6 78 of of ADP eurjchem-1480 6 79 n n CCONJ eurjchem-1480 6 80 , , PUNCT eurjchem-1480 6 81 n‐ n‐ NOUN eurjchem-1480 6 82 dimethylaminoethyl dimethylaminoethyl PROPN eurjchem-1480 6 83 methacrylate methacrylate NOUN eurjchem-1480 6 84 by by ADP eurjchem-1480 6 85 atom atom NOUN eurjchem-1480 6 86 transfer transfer NOUN eurjchem-1480 6 87 radical radical ADJ eurjchem-1480 6 88 polymerization polymerization NOUN eurjchem-1480 6 89 reaction reaction NOUN eurjchem-1480 6 90 . . PUNCT eurjchem-1480 7 1 the the DET eurjchem-1480 7 2 copolymers copolymer NOUN eurjchem-1480 7 3 were be AUX eurjchem-1480 7 4 characterized characterize VERB eurjchem-1480 7 5 ft‐ir ft‐ir NOUN eurjchem-1480 7 6 , , PUNCT eurjchem-1480 7 7 1h 1h NUM eurjchem-1480 7 8 nmr nmr NOUN eurjchem-1480 7 9 , , PUNCT eurjchem-1480 7 10 13c 13c NOUN eurjchem-1480 7 11 nmr nmr NOUN eurjchem-1480 7 12 and and CCONJ eurjchem-1480 7 13 gel gel NOUN eurjchem-1480 7 14 permeation permeation NOUN eurjchem-1480 7 15 chromatography chromatography NOUN eurjchem-1480 7 16 . . PUNCT eurjchem-1480 8 1 these these DET eurjchem-1480 8 2 characterization characterization NOUN eurjchem-1480 8 3 methods method NOUN eurjchem-1480 8 4 confirmed confirm VERB eurjchem-1480 8 5 the the DET eurjchem-1480 8 6 structures structure NOUN eurjchem-1480 8 7 of of ADP eurjchem-1480 8 8 prepared prepared ADJ eurjchem-1480 8 9 copolymers copolymer NOUN eurjchem-1480 8 10 . . PUNCT eurjchem-1480 9 1 scanning scan VERB eurjchem-1480 9 2 electron electron NOUN eurjchem-1480 9 3 microscopy microscopy NOUN eurjchem-1480 9 4 , , PUNCT eurjchem-1480 9 5 on on ADP eurjchem-1480 9 6 the the DET eurjchem-1480 9 7 other other ADJ eurjchem-1480 9 8 hand hand NOUN eurjchem-1480 9 9 , , PUNCT eurjchem-1480 9 10 revealed reveal VERB eurjchem-1480 9 11 that that SCONJ eurjchem-1480 9 12 the the DET eurjchem-1480 9 13 presence presence NOUN eurjchem-1480 9 14 of of ADP eurjchem-1480 9 15 a a DET eurjchem-1480 9 16 nanostructure nanostructure NOUN eurjchem-1480 9 17 in in ADP eurjchem-1480 9 18 the the DET eurjchem-1480 9 19 prepared prepare VERB eurjchem-1480 9 20 copolymers copolymer NOUN eurjchem-1480 9 21 attributed attribute VERB eurjchem-1480 9 22 to to ADP eurjchem-1480 9 23 the the DET eurjchem-1480 9 24 lactide lactide ADJ eurjchem-1480 9 25 fibers fiber NOUN eurjchem-1480 9 26 . . PUNCT eurjchem-1480 10 1 then then ADV eurjchem-1480 10 2 , , PUNCT eurjchem-1480 10 3 the the DET eurjchem-1480 10 4 thermal thermal ADJ eurjchem-1480 10 5 study study NOUN eurjchem-1480 10 6 was be AUX eurjchem-1480 10 7 carried carry VERB eurjchem-1480 10 8 out out ADP eurjchem-1480 10 9 on on ADP eurjchem-1480 10 10 the the DET eurjchem-1480 10 11 copolymers copolymer NOUN eurjchem-1480 10 12 the the DET eurjchem-1480 10 13 results result NOUN eurjchem-1480 10 14 have have AUX eurjchem-1480 10 15 proven prove VERB eurjchem-1480 10 16 to to PART eurjchem-1480 10 17 increase increase VERB eurjchem-1480 10 18 the the DET eurjchem-1480 10 19 thermal thermal ADJ eurjchem-1480 10 20 stability stability NOUN eurjchem-1480 10 21 of of ADP eurjchem-1480 10 22 the the DET eurjchem-1480 10 23 copolymers copolymer NOUN eurjchem-1480 10 24 with with ADP eurjchem-1480 10 25 the the DET eurjchem-1480 10 26 increasing increase VERB eurjchem-1480 10 27 chain chain NOUN eurjchem-1480 10 28 length length NOUN eurjchem-1480 10 29 of of ADP eurjchem-1480 10 30 the the DET eurjchem-1480 10 31 lactide lactide NOUN eurjchem-1480 10 32 . . PUNCT eurjchem-1480 11 1 keywords keyword NOUN eurjchem-1480 11 2 atrp atrp ADV eurjchem-1480 11 3 l‐lactide l‐lactide VERB eurjchem-1480 11 4 lactide lactide ADJ eurjchem-1480 11 5 fibers fiber NOUN eurjchem-1480 11 6 nanostructure nanostructure VERB eurjchem-1480 11 7 nano nano NOUN eurjchem-1480 11 8 four four NUM eurjchem-1480 11 9 arms arm NOUN eurjchem-1480 11 10 n n CCONJ eurjchem-1480 11 11 , , PUNCT eurjchem-1480 11 12 n‐dimethylaminoethyl n‐dimethylaminoethyl X eurjchem-1480 11 13 methacrylate methacrylate NOUN eurjchem-1480 11 14 cite cite VERB eurjchem-1480 11 15 this this PRON eurjchem-1480 11 16 : : PUNCT eurjchem-1480 11 17 eur eur PROPN eurjchem-1480 11 18 . . PUNCT eurjchem-1480 12 1 j. j. PROPN eurjchem-1480 12 2 chem chem PROPN eurjchem-1480 12 3 . . PUNCT eurjchem-1480 13 1 2016 2016 NUM eurjchem-1480 13 2 , , PUNCT eurjchem-1480 13 3 7(4 7(4 NUM eurjchem-1480 13 4 ) ) PUNCT eurjchem-1480 13 5 , , PUNCT eurjchem-1480 13 6 405‐409 405‐409 NUM eurjchem-1480 13 7 1 1 NUM eurjchem-1480 13 8 . . PUNCT eurjchem-1480 13 9 introduction introduction NOUN eurjchem-1480 13 10 the the DET eurjchem-1480 13 11 first first ADJ eurjchem-1480 13 12 report report NOUN eurjchem-1480 13 13 in in ADP eurjchem-1480 13 14 atom atom NOUN eurjchem-1480 13 15 transfer transfer NOUN eurjchem-1480 13 16 radical radical ADJ eurjchem-1480 13 17 polymerization polymerization NOUN eurjchem-1480 13 18 ( ( PUNCT eurjchem-1480 13 19 atrp atrp NOUN eurjchem-1480 13 20 ) ) PUNCT eurjchem-1480 13 21 , , PUNCT eurjchem-1480 13 22 by by ADP eurjchem-1480 13 23 kato kato PROPN eurjchem-1480 13 24 et et PROPN eurjchem-1480 13 25 al al PROPN eurjchem-1480 13 26 . . PROPN eurjchem-1480 13 27 employed employ VERB eurjchem-1480 13 28 rucl2(pph3 rucl2(pph3 ADV eurjchem-1480 13 29 ) ) PUNCT eurjchem-1480 13 30 as as ADP eurjchem-1480 13 31 a a DET eurjchem-1480 13 32 catalyst catalyst NOUN eurjchem-1480 13 33 system system NOUN eurjchem-1480 13 34 in in ADP eurjchem-1480 13 35 the the DET eurjchem-1480 13 36 polymerization polymerization NOUN eurjchem-1480 13 37 of of ADP eurjchem-1480 13 38 methyl methyl NOUN eurjchem-1480 13 39 methacrylate methacrylate NOUN eurjchem-1480 13 40 ( ( PUNCT eurjchem-1480 13 41 mma mma PROPN eurjchem-1480 13 42 ) ) PUNCT eurjchem-1480 13 43 initiated initiate VERB eurjchem-1480 13 44 by by ADP eurjchem-1480 13 45 ccl4 ccl4 PROPN eurjchem-1480 14 1 [ [ X eurjchem-1480 14 2 1 1 NUM eurjchem-1480 14 3 ] ] PUNCT eurjchem-1480 14 4 . . PUNCT eurjchem-1480 15 1 the the DET eurjchem-1480 15 2 second second ADJ eurjchem-1480 15 3 system system NOUN eurjchem-1480 15 4 reported report VERB eurjchem-1480 15 5 by by ADP eurjchem-1480 15 6 matyjaszewski matyjaszewski PROPN eurjchem-1480 15 7 et et PROPN eurjchem-1480 15 8 al al PROPN eurjchem-1480 15 9 . . PROPN eurjchem-1480 15 10 is be AUX eurjchem-1480 15 11 the the DET eurjchem-1480 15 12 polymerization polymerization NOUN eurjchem-1480 15 13 of of ADP eurjchem-1480 15 14 styrene styrene NOUN eurjchem-1480 15 15 using use VERB eurjchem-1480 15 16 cucl/2,2’‐bipyridyl cucl/2,2’‐bipyridyl PROPN eurjchem-1480 15 17 ( ( PUNCT eurjchem-1480 15 18 bpy bpy PROPN eurjchem-1480 15 19 ) ) PUNCT eurjchem-1480 15 20 as as ADP eurjchem-1480 15 21 catalyst catalyst NOUN eurjchem-1480 15 22 and and CCONJ eurjchem-1480 15 23 1‐phenylethyl 1‐phenylethyl PROPN eurjchem-1480 15 24 chloride chloride NOUN eurjchem-1480 15 25 as as ADP eurjchem-1480 15 26 an an DET eurjchem-1480 15 27 initiator initiator NOUN eurjchem-1480 15 28 [ [ X eurjchem-1480 15 29 2 2 NUM eurjchem-1480 15 30 ] ] PUNCT eurjchem-1480 15 31 . . PUNCT eurjchem-1480 16 1 since since SCONJ eurjchem-1480 16 2 then then ADV eurjchem-1480 16 3 , , PUNCT eurjchem-1480 16 4 atrp atrp PROPN eurjchem-1480 16 5 of of ADP eurjchem-1480 16 6 styrene styrene NOUN eurjchem-1480 16 7 , , PUNCT eurjchem-1480 16 8 acrylates acrylate NOUN eurjchem-1480 16 9 , , PUNCT eurjchem-1480 16 10 methacrylates methacrylate NOUN eurjchem-1480 16 11 , , PUNCT eurjchem-1480 16 12 and and CCONJ eurjchem-1480 16 13 acrylonitrile acrylonitrile NOUN eurjchem-1480 16 14 was be AUX eurjchem-1480 16 15 carried carry VERB eurjchem-1480 16 16 out out ADP eurjchem-1480 16 17 using use VERB eurjchem-1480 16 18 various various ADJ eurjchem-1480 16 19 transition transition NOUN eurjchem-1480 16 20 metal metal NOUN eurjchem-1480 16 21 complexes complex NOUN eurjchem-1480 16 22 , , PUNCT eurjchem-1480 16 23 such such ADJ eurjchem-1480 16 24 as as ADP eurjchem-1480 16 25 nickel nickel NOUN eurjchem-1480 16 26 , , PUNCT eurjchem-1480 16 27 iron iron NOUN eurjchem-1480 16 28 , , PUNCT eurjchem-1480 16 29 palladium palladium NOUN eurjchem-1480 16 30 , , PUNCT eurjchem-1480 16 31 and and CCONJ eurjchem-1480 16 32 rhodium rhodium NOUN eurjchem-1480 16 33 . . PUNCT eurjchem-1480 17 1 compared compare VERB eurjchem-1480 17 2 to to ADP eurjchem-1480 17 3 other other ADJ eurjchem-1480 17 4 controlled control VERB eurjchem-1480 17 5 radical radical ADJ eurjchem-1480 17 6 polymerization polymerization NOUN eurjchem-1480 17 7 methods method NOUN eurjchem-1480 17 8 , , PUNCT eurjchem-1480 17 9 atrp atrp PROPN eurjchem-1480 17 10 is be AUX eurjchem-1480 17 11 very very ADV eurjchem-1480 17 12 versatile versatile ADJ eurjchem-1480 17 13 [ [ X eurjchem-1480 17 14 3‐6 3‐6 NUM eurjchem-1480 17 15 ] ] PUNCT eurjchem-1480 17 16 . . PUNCT eurjchem-1480 18 1 vivek vivek PROPN eurjchem-1480 18 2 and and CCONJ eurjchem-1480 18 3 dhamodharan dhamodharan VERB eurjchem-1480 18 4 [ [ X eurjchem-1480 18 5 7 7 X eurjchem-1480 18 6 ] ] PUNCT eurjchem-1480 18 7 synthesized synthesize VERB eurjchem-1480 18 8 polystyrene‐ polystyrene‐ ADP eurjchem-1480 18 9 graft‐poly(n graft‐poly(n PROPN eurjchem-1480 18 10 , , PUNCT eurjchem-1480 18 11 n‐dimethyl‐2‐aminoethyl n‐dimethyl‐2‐aminoethyl PROPN eurjchem-1480 18 12 methacrylate methacrylate PROPN eurjchem-1480 18 13 ) ) PUNCT eurjchem-1480 18 14 via via ADP eurjchem-1480 18 15 ambient ambient ADJ eurjchem-1480 18 16 temperature temperature NOUN eurjchem-1480 18 17 atrp atrp NOUN eurjchem-1480 18 18 from from ADP eurjchem-1480 18 19 polystyrene polystyrene NOUN eurjchem-1480 18 20 macro‐initiator macro‐initiator NOUN eurjchem-1480 18 21 with with ADP eurjchem-1480 18 22 pendant pendant ADJ eurjchem-1480 18 23 bromo bromo NOUN eurjchem-1480 18 24 initiating initiate VERB eurjchem-1480 18 25 groups group NOUN eurjchem-1480 18 26 . . PUNCT eurjchem-1480 19 1 a a DET eurjchem-1480 19 2 cationic cationic ADJ eurjchem-1480 19 3 star star NOUN eurjchem-1480 19 4 polymer polymer NOUN eurjchem-1480 19 5 , , PUNCT eurjchem-1480 19 6 poly(2‐dimethylamino)ethyl poly(2‐dimethylamino)ethyl PROPN eurjchem-1480 19 7 methacrylate methacrylate NOUN eurjchem-1480 19 8 ( ( PUNCT eurjchem-1480 19 9 pdmaema pdmaema NOUN eurjchem-1480 19 10 ) ) PUNCT eurjchem-1480 19 11 , , PUNCT eurjchem-1480 19 12 was be AUX eurjchem-1480 19 13 prepared prepare VERB eurjchem-1480 19 14 via via ADP eurjchem-1480 19 15 atrp atrp NOUN eurjchem-1480 19 16 by by ADP eurjchem-1480 19 17 zheng zheng PROPN eurjchem-1480 19 18 et et PROPN eurjchem-1480 19 19 al al PROPN eurjchem-1480 19 20 . . PUNCT eurjchem-1480 20 1 [ [ X eurjchem-1480 20 2 8 8 NUM eurjchem-1480 20 3 ] ] PUNCT eurjchem-1480 20 4 , , PUNCT eurjchem-1480 20 5 they they PRON eurjchem-1480 20 6 are be AUX eurjchem-1480 20 7 used use VERB eurjchem-1480 20 8 brominated brominate VERB eurjchem-1480 20 9 calix[4]resorcinarene calix[4]resorcinarene NOUN eurjchem-1480 20 10 as as ADP eurjchem-1480 20 11 an an DET eurjchem-1480 20 12 initiator initiator NOUN eurjchem-1480 20 13 . . PUNCT eurjchem-1480 21 1 hydrophobic hydrophobic NOUN eurjchem-1480 21 2 moieties moiety NOUN eurjchem-1480 21 3 , , PUNCT eurjchem-1480 21 4 methyl methyl NOUN eurjchem-1480 21 5 methacrylate methacrylate NOUN eurjchem-1480 21 6 ( ( PUNCT eurjchem-1480 21 7 mma mma PROPN eurjchem-1480 21 8 ) ) PUNCT eurjchem-1480 21 9 and and CCONJ eurjchem-1480 21 10 butyl butyl NOUN eurjchem-1480 21 11 acrylate acrylate NOUN eurjchem-1480 21 12 ( ( PUNCT eurjchem-1480 21 13 ba ba PROPN eurjchem-1480 21 14 ) ) PUNCT eurjchem-1480 21 15 , , PUNCT eurjchem-1480 21 16 were be AUX eurjchem-1480 21 17 further far ADV eurjchem-1480 21 18 incorporated incorporate VERB eurjchem-1480 21 19 via via ADP eurjchem-1480 21 20 one‐pot one‐pot NOUN eurjchem-1480 21 21 method method NOUN eurjchem-1480 21 22 . . PUNCT eurjchem-1480 22 1 well‐defined well‐defined ADJ eurjchem-1480 22 2 eight‐armed eight‐arme VERB eurjchem-1480 22 3 star star NOUN eurjchem-1480 22 4 block block NOUN eurjchem-1480 22 5 copolymers copolymer NOUN eurjchem-1480 22 6 bearing bear VERB eurjchem-1480 22 7 hydrophilic hydrophilic ADJ eurjchem-1480 22 8 blocks block NOUN eurjchem-1480 22 9 inside inside ADV eurjchem-1480 22 10 and and CCONJ eurjchem-1480 22 11 hydrophobic hydrophobic NOUN eurjchem-1480 22 12 blocks block NOUN eurjchem-1480 22 13 outside outside ADV eurjchem-1480 22 14 were be AUX eurjchem-1480 22 15 synthesized synthesize VERB eurjchem-1480 22 16 . . PUNCT eurjchem-1480 23 1 atrp atrp PROPN eurjchem-1480 23 2 can can AUX eurjchem-1480 23 3 be be AUX eurjchem-1480 23 4 carried carry VERB eurjchem-1480 23 5 out out ADP eurjchem-1480 23 6 in in ADP eurjchem-1480 23 7 a a DET eurjchem-1480 23 8 wide wide ADJ eurjchem-1480 23 9 range range NOUN eurjchem-1480 23 10 of of ADP eurjchem-1480 23 11 polymerization polymerization NOUN eurjchem-1480 23 12 temperatures temperature NOUN eurjchem-1480 23 13 with with ADP eurjchem-1480 23 14 controlled control VERB eurjchem-1480 23 15 molecular molecular ADJ eurjchem-1480 23 16 weight weight NOUN eurjchem-1480 23 17 and and CCONJ eurjchem-1480 23 18 narrow narrow ADJ eurjchem-1480 23 19 ( ( PUNCT eurjchem-1480 23 20 molecular molecular ADJ eurjchem-1480 23 21 weight weight NOUN eurjchem-1480 23 22 distribution distribution NOUN eurjchem-1480 23 23 , , PUNCT eurjchem-1480 23 24 mwd mwd PROPN eurjchem-1480 23 25 ) ) PUNCT eurjchem-1480 23 26 , , PUNCT eurjchem-1480 23 27 and and CCONJ eurjchem-1480 23 28 it it PRON eurjchem-1480 23 29 is be AUX eurjchem-1480 23 30 not not PART eurjchem-1480 23 31 very very ADV eurjchem-1480 23 32 sensitive sensitive ADJ eurjchem-1480 23 33 to to ADP eurjchem-1480 23 34 the the DET eurjchem-1480 23 35 presence presence NOUN eurjchem-1480 23 36 of of ADP eurjchem-1480 23 37 oxygen oxygen NOUN eurjchem-1480 23 38 and and CCONJ eurjchem-1480 23 39 other other ADJ eurjchem-1480 23 40 inhibitors inhibitor NOUN eurjchem-1480 23 41 [ [ X eurjchem-1480 23 42 9 9 NUM eurjchem-1480 23 43 ] ] PUNCT eurjchem-1480 23 44 . . PUNCT eurjchem-1480 24 1 in in ADP eurjchem-1480 24 2 this this DET eurjchem-1480 24 3 work work NOUN eurjchem-1480 24 4 , , PUNCT eurjchem-1480 24 5 we we PRON eurjchem-1480 24 6 reported report VERB eurjchem-1480 24 7 to to ADP eurjchem-1480 24 8 the the DET eurjchem-1480 24 9 synthesis synthesis NOUN eurjchem-1480 24 10 of of ADP eurjchem-1480 24 11 nano nano NOUN eurjchem-1480 24 12 four four NUM eurjchem-1480 24 13 arm arm NOUN eurjchem-1480 24 14 poly(pentaerythritollactide‐b‐n poly(pentaerythritollactide‐b‐n PROPN eurjchem-1480 24 15 , , PUNCT eurjchem-1480 24 16 n‐dimethylaminoethylmetha‐ n‐dimethylaminoethylmetha‐ NOUN eurjchem-1480 24 17 crylate crylate NOUN eurjchem-1480 24 18 ) ) PUNCT eurjchem-1480 24 19 via via ADP eurjchem-1480 24 20 atrp atrp NOUN eurjchem-1480 24 21 and and CCONJ eurjchem-1480 24 22 evaluating evaluate VERB eurjchem-1480 24 23 some some PRON eurjchem-1480 24 24 of of ADP eurjchem-1480 24 25 their their PRON eurjchem-1480 24 26 thermal thermal ADJ eurjchem-1480 24 27 properties property NOUN eurjchem-1480 24 28 . . PUNCT eurjchem-1480 25 1 2 2 X eurjchem-1480 25 2 . . X eurjchem-1480 25 3 experimental experimental ADJ eurjchem-1480 25 4 2.1 2.1 NUM eurjchem-1480 25 5 . . PUNCT eurjchem-1480 25 6 materials material NOUN eurjchem-1480 25 7 n n CCONJ eurjchem-1480 25 8 , , PUNCT eurjchem-1480 25 9 n‐dimethylaminoethyl n‐dimethylaminoethyl X eurjchem-1480 25 10 methacrylate methacrylate NOUN eurjchem-1480 25 11 , , PUNCT eurjchem-1480 25 12 copper(i copper(i NOUN eurjchem-1480 25 13 ) ) PUNCT eurjchem-1480 25 14 bromide bromide NOUN eurjchem-1480 25 15 , , PUNCT eurjchem-1480 25 16 n n CCONJ eurjchem-1480 25 17 , , PUNCT eurjchem-1480 25 18 n n CCONJ eurjchem-1480 25 19 , , PUNCT eurjchem-1480 25 20 n′,n′′,n′′‐pentamethyldiethylenetriamine n′,n′′,n′′‐pentamethyldiethylenetriamine PROPN eurjchem-1480 25 21 , , PUNCT eurjchem-1480 25 22 magnesium magnesium NOUN eurjchem-1480 25 23 sul‐ sul‐ NOUN eurjchem-1480 25 24 fate fate NOUN eurjchem-1480 25 25 , , PUNCT eurjchem-1480 25 26 cdcl3 cdcl3 NOUN eurjchem-1480 25 27 and and CCONJ eurjchem-1480 25 28 dimethyl dimethyl PROPN eurjchem-1480 25 29 sulfoxide‐d6 sulfoxide‐d6 PROPN eurjchem-1480 25 30 were be AUX eurjchem-1480 25 31 supplied supply VERB eurjchem-1480 25 32 by by ADP eurjchem-1480 25 33 sigma‐ sigma‐ PROPN eurjchem-1480 25 34 aldrich aldrich PROPN eurjchem-1480 25 35 , , PUNCT eurjchem-1480 25 36 dichloromethane dichloromethane NOUN eurjchem-1480 25 37 ( ( PUNCT eurjchem-1480 25 38 dcm dcm PROPN eurjchem-1480 25 39 ) ) PUNCT eurjchem-1480 25 40 ( ( PUNCT eurjchem-1480 25 41 ≥ ≥ NUM eurjchem-1480 25 42 99.5 99.5 NUM eurjchem-1480 25 43 % % NOUN eurjchem-1480 25 44 ) ) PUNCT eurjchem-1480 25 45 , , PUNCT eurjchem-1480 25 46 dimethyl dimethyl PROPN eurjchem-1480 25 47 formamide formamide ADV eurjchem-1480 25 48 ( ( PUNCT eurjchem-1480 25 49 dmf dmf PROPN eurjchem-1480 25 50 ) ) PUNCT eurjchem-1480 25 51 ( ( PUNCT eurjchem-1480 25 52 ≥ ≥ NUM eurjchem-1480 25 53 99.8 99.8 NUM eurjchem-1480 25 54 % % NOUN eurjchem-1480 25 55 ) ) PUNCT eurjchem-1480 25 56 and and CCONJ eurjchem-1480 25 57 triethyl triethyl PROPN eurjchem-1480 25 58 amine amine PROPN eurjchem-1480 25 59 ( ( PUNCT eurjchem-1480 25 60 ≥ ≥ NUM eurjchem-1480 25 61 99.5 99.5 NUM eurjchem-1480 25 62 % % NOUN eurjchem-1480 25 63 ) ) PUNCT eurjchem-1480 25 64 were be AUX eurjchem-1480 25 65 supplied supply VERB eurjchem-1480 25 66 by by ADP eurjchem-1480 25 67 macron macron NOUN eurjchem-1480 25 68 company company NOUN eurjchem-1480 25 69 , , PUNCT eurjchem-1480 25 70 michigan michigan PROPN eurjchem-1480 25 71 , , PUNCT eurjchem-1480 25 72 usa usa PROPN eurjchem-1480 25 73 . . PROPN eurjchem-1480 25 74 2.2 2.2 NUM eurjchem-1480 25 75 . . PUNCT eurjchem-1480 26 1 instrumentation instrumentation NOUN eurjchem-1480 26 2 nicolet nicolet PROPN eurjchem-1480 26 3 ir‐42 ir‐42 PROPN eurjchem-1480 26 4 , , PUNCT eurjchem-1480 26 5 mid‐ir mid‐ir PROPN eurjchem-1480 26 6 spectrometer spectrometer NOUN eurjchem-1480 26 7 was be AUX eurjchem-1480 26 8 used use VERB eurjchem-1480 26 9 to to PART eurjchem-1480 26 10 record record VERB eurjchem-1480 26 11 ft‐ ft‐ PROPN eurjchem-1480 26 12 ir ir PROPN eurjchem-1480 26 13 spectra spectra PROPN eurjchem-1480 26 14 . . PUNCT eurjchem-1480 27 1 agilent agilent PROPN eurjchem-1480 27 2 ddr2 ddr2 PROPN eurjchem-1480 27 3 500 500 NUM eurjchem-1480 27 4 mhz mhz ADJ eurjchem-1480 27 5 nmr nmr NOUN eurjchem-1480 27 6 spectrometer spectrometer NOUN eurjchem-1480 27 7 was be AUX eurjchem-1480 27 8 used use VERB eurjchem-1480 27 9 406 406 NUM eurjchem-1480 27 10 al‐mayyahi al‐mayyahi NOUN eurjchem-1480 27 11 et et PROPN eurjchem-1480 27 12 al al PROPN eurjchem-1480 27 13 . . PUNCT eurjchem-1480 27 14 / / SYM eurjchem-1480 27 15 european european PROPN eurjchem-1480 27 16 journal journal PROPN eurjchem-1480 27 17 of of ADP eurjchem-1480 27 18 chemistry chemistry NOUN eurjchem-1480 27 19 7 7 NUM eurjchem-1480 27 20 ( ( PUNCT eurjchem-1480 27 21 4 4 NUM eurjchem-1480 27 22 ) ) PUNCT eurjchem-1480 27 23 ( ( PUNCT eurjchem-1480 27 24 2016 2016 NUM eurjchem-1480 27 25 ) ) PUNCT eurjchem-1480 27 26 405‐409 405‐409 NUM eurjchem-1480 27 27 table table NOUN eurjchem-1480 27 28 1 1 NUM eurjchem-1480 27 29 . . PUNCT eurjchem-1480 27 30 amount amount NOUN eurjchem-1480 27 31 of of ADP eurjchem-1480 27 32 reactants reactant NOUN eurjchem-1480 27 33 used use VERB eurjchem-1480 27 34 in in ADP eurjchem-1480 27 35 the the DET eurjchem-1480 27 36 preparation preparation NOUN eurjchem-1480 27 37 of of ADP eurjchem-1480 27 38 pl25br‐dm pl25br‐dm NOUN eurjchem-1480 27 39 , , PUNCT eurjchem-1480 27 40 pl50br‐dmand pl50br‐dmand NOUN eurjchem-1480 27 41 pl100br‐dm pl100br‐dm NOUN eurjchem-1480 27 42 copolymers copolymer NOUN eurjchem-1480 27 43 . . PUNCT eurjchem-1480 28 1 copolymer copolymer NOUN eurjchem-1480 28 2 code code NOUN eurjchem-1480 28 3 amount amount NOUN eurjchem-1480 28 4 of of ADP eurjchem-1480 28 5 plnbr plnbr NOUN eurjchem-1480 28 6 weight weight NOUN eurjchem-1480 28 7 of of ADP eurjchem-1480 28 8 dmaema dmaema NOUN eurjchem-1480 28 9 weight weight NOUN eurjchem-1480 28 10 of of ADP eurjchem-1480 28 11 cubr cubr NOUN eurjchem-1480 28 12 ( ( PUNCT eurjchem-1480 28 13 g g NOUN eurjchem-1480 28 14 ) ) PUNCT eurjchem-1480 28 15 volume volume NOUN eurjchem-1480 28 16 of of ADP eurjchem-1480 28 17 pmdeta pmdeta NOUN eurjchem-1480 28 18 ( ( PUNCT eurjchem-1480 28 19 µl µl NOUN eurjchem-1480 28 20 ) ) PUNCT eurjchem-1480 28 21 yield yield NOUN eurjchem-1480 28 22 ( ( PUNCT eurjchem-1480 28 23 % % INTJ eurjchem-1480 28 24 ) ) PUNCT eurjchem-1480 28 25 physical physical ADJ eurjchem-1480 28 26 state state NOUN eurjchem-1480 28 27 weight weight NOUN eurjchem-1480 28 28 ( ( PUNCT eurjchem-1480 28 29 g g NOUN eurjchem-1480 28 30 ) ) PUNCT eurjchem-1480 28 31 no no NOUN eurjchem-1480 28 32 . . NOUN eurjchem-1480 28 33 of of ADP eurjchem-1480 28 34 moles mole NOUN eurjchem-1480 28 35 weight weight NOUN eurjchem-1480 28 36 ( ( PUNCT eurjchem-1480 28 37 g g NOUN eurjchem-1480 28 38 ) ) PUNCT eurjchem-1480 28 39 no no NOUN eurjchem-1480 28 40 . . NOUN eurjchem-1480 28 41 of of ADP eurjchem-1480 28 42 moles mole NOUN eurjchem-1480 28 43 pl25brdm pl25brdm PROPN eurjchem-1480 28 44 0.4 0.4 NUM eurjchem-1480 28 45 0.00005 0.00005 NUM eurjchem-1480 28 46 0.8 0.8 NUM eurjchem-1480 28 47 0.005 0.005 NUM eurjchem-1480 28 48 0.05 0.05 NUM eurjchem-1480 28 49 20 20 NUM eurjchem-1480 28 50 67 67 NUM eurjchem-1480 28 51 solid solid ADJ eurjchem-1480 28 52 pl50brdm pl50brdm ADV eurjchem-1480 28 53 0.4 0.4 NUM eurjchem-1480 28 54 0.00003 0.00003 NUM eurjchem-1480 28 55 0.8 0.8 NUM eurjchem-1480 28 56 0.005 0.005 NUM eurjchem-1480 28 57 0.05 0.05 NUM eurjchem-1480 28 58 20 20 NUM eurjchem-1480 28 59 71 71 NUM eurjchem-1480 28 60 solid solid ADJ eurjchem-1480 28 61 pl100brdm pl100brdm NOUN eurjchem-1480 28 62 0.4 0.4 NUM eurjchem-1480 28 63 0.00001 0.00001 NUM eurjchem-1480 28 64 0.8 0.8 NUM eurjchem-1480 28 65 0.005 0.005 NUM eurjchem-1480 28 66 0.05 0.05 NUM eurjchem-1480 28 67 20 20 NUM eurjchem-1480 28 68 69 69 NUM eurjchem-1480 28 69 solid solid ADJ eurjchem-1480 28 70 + + CCONJ eurjchem-1480 28 71 dmf dmf PROPN eurjchem-1480 28 72 / / SYM eurjchem-1480 28 73 pmdeta pmdeta NOUN eurjchem-1480 28 74 cubr cubr NOUN eurjchem-1480 28 75 / / SYM eurjchem-1480 28 76 60 60 NUM eurjchem-1480 28 77 oc oc NOUN eurjchem-1480 28 78 / / SYM eurjchem-1480 28 79 15 15 NUM eurjchem-1480 28 80 h h NOUN eurjchem-1480 28 81 o o NOUN eurjchem-1480 28 82 n n CCONJ eurjchem-1480 29 1 o o NOUN eurjchem-1480 29 2 h3c h3c PROPN eurjchem-1480 29 3 ch3 ch3 PROPN eurjchem-1480 29 4 ch3 ch3 PROPN eurjchem-1480 29 5 n n PROPN eurjchem-1480 29 6 = = PROPN eurjchem-1480 29 7 10 10 NUM eurjchem-1480 29 8 , , PUNCT eurjchem-1480 29 9 25 25 NUM eurjchem-1480 29 10 , , PUNCT eurjchem-1480 29 11 50 50 NUM eurjchem-1480 29 12 and and CCONJ eurjchem-1480 29 13 100 100 NUM eurjchem-1480 30 1 c c NOUN eurjchem-1480 30 2 o o NOUN eurjchem-1480 31 1 o o X eurjchem-1480 32 1 o o X eurjchem-1480 32 2 o o X eurjchem-1480 32 3 c c NOUN eurjchem-1480 33 1 c c NOUN eurjchem-1480 33 2 c c NOUN eurjchem-1480 33 3 c c PROPN eurjchem-1480 33 4 ch ch PROPN eurjchem-1480 33 5 hc hc PROPN eurjchem-1480 33 6 ch ch NOUN eurjchem-1480 33 7 h h NOUN eurjchem-1480 34 1 c c NOUN eurjchem-1480 34 2 o o NOUN eurjchem-1480 35 1 o o X eurjchem-1480 35 2 o o X eurjchem-1480 35 3 o o X eurjchem-1480 35 4 ch3 ch3 PROPN eurjchem-1480 35 5 ch3 ch3 PROPN eurjchem-1480 35 6 ch3 ch3 PROPN eurjchem-1480 35 7 h3c h3c VERB eurjchem-1480 36 1 o o X eurjchem-1480 37 1 o o X eurjchem-1480 38 1 o o X eurjchem-1480 39 1 o o X eurjchem-1480 40 1 o o X eurjchem-1480 40 2 o o X eurjchem-1480 40 3 o o X eurjchem-1480 40 4 o o X eurjchem-1480 40 5 h3c h3c X eurjchem-1480 40 6 ch3 ch3 PROPN eurjchem-1480 40 7 br br PROPN eurjchem-1480 40 8 ch3 ch3 PROPN eurjchem-1480 40 9 h3c h3c VERB eurjchem-1480 40 10 br br PROPN eurjchem-1480 40 11 h3c h3c PROPN eurjchem-1480 40 12 ch3 ch3 PROPN eurjchem-1480 40 13 br br PROPN eurjchem-1480 40 14 ch3 ch3 PROPN eurjchem-1480 40 15 h3c h3c VERB eurjchem-1480 40 16 br br PROPN eurjchem-1480 40 17 n n CCONJ eurjchem-1480 40 18 n n CCONJ eurjchem-1480 40 19 n n CCONJ eurjchem-1480 40 20 n n NOUN eurjchem-1480 40 21 c c NOUN eurjchem-1480 41 1 o o NOUN eurjchem-1480 42 1 o o X eurjchem-1480 43 1 o o X eurjchem-1480 43 2 o o X eurjchem-1480 43 3 c c NOUN eurjchem-1480 44 1 c c NOUN eurjchem-1480 44 2 c c NOUN eurjchem-1480 44 3 c c PROPN eurjchem-1480 44 4 ch ch PROPN eurjchem-1480 44 5 h h PROPN eurjchem-1480 44 6 c c PROPN eurjchem-1480 44 7 ch ch NOUN eurjchem-1480 44 8 ch ch NOUN eurjchem-1480 45 1 oo oo INTJ eurjchem-1480 45 2 o o X eurjchem-1480 45 3 o o X eurjchem-1480 45 4 ch3 ch3 PROPN eurjchem-1480 45 5 h3c h3c VERB eurjchem-1480 45 6 h3c h3c PROPN eurjchem-1480 45 7 ch3 ch3 PROPN eurjchem-1480 46 1 o o NOUN eurjchem-1480 47 1 o o X eurjchem-1480 48 1 o o X eurjchem-1480 49 1 o o X eurjchem-1480 49 2 o o X eurjchem-1480 50 1 o o X eurjchem-1480 50 2 o o X eurjchem-1480 50 3 o o X eurjchem-1480 50 4 h3c h3c VERB eurjchem-1480 50 5 ch3 ch3 PROPN eurjchem-1480 50 6 ch3 ch3 PROPN eurjchem-1480 50 7 h3c h3c VERB eurjchem-1480 50 8 h3c h3c PROPN eurjchem-1480 50 9 h3c h3c PROPN eurjchem-1480 50 10 ch3 ch3 PROPN eurjchem-1480 50 11 ch3 ch3 PROPN eurjchem-1480 50 12 o o PROPN eurjchem-1480 50 13 n n PRON eurjchem-1480 50 14 o o NOUN eurjchem-1480 50 15 h3c h3c VERB eurjchem-1480 50 16 ch3 ch3 PROPN eurjchem-1480 50 17 h3c h3c VERB eurjchem-1480 50 18 br br PROPN eurjchem-1480 50 19 o o NOUN eurjchem-1480 50 20 n n CCONJ eurjchem-1480 50 21 o o PROPN eurjchem-1480 50 22 ch3 ch3 PROPN eurjchem-1480 50 23 h3c h3c VERB eurjchem-1480 50 24 ch3 ch3 PROPN eurjchem-1480 51 1 br br PROPN eurjchem-1480 51 2 o o PROPN eurjchem-1480 51 3 n n CCONJ eurjchem-1480 51 4 o o PROPN eurjchem-1480 51 5 ch3 ch3 PROPN eurjchem-1480 51 6 h3c h3c VERB eurjchem-1480 51 7 ch3 ch3 PROPN eurjchem-1480 51 8 br br PROPN eurjchem-1480 52 1 o o PROPN eurjchem-1480 52 2 n n CCONJ eurjchem-1480 52 3 o o PROPN eurjchem-1480 52 4 ch3 ch3 PROPN eurjchem-1480 52 5 ch3 ch3 PROPN eurjchem-1480 52 6 h3c h3c VERB eurjchem-1480 52 7 br br PROPN eurjchem-1480 52 8 m m NOUN eurjchem-1480 52 9 = = NOUN eurjchem-1480 52 10 10 10 NUM eurjchem-1480 52 11 , , PUNCT eurjchem-1480 52 12 25 25 NUM eurjchem-1480 52 13 , , PUNCT eurjchem-1480 52 14 50 50 NUM eurjchem-1480 52 15 and and CCONJ eurjchem-1480 52 16 100 100 NUM eurjchem-1480 52 17 n n CCONJ eurjchem-1480 52 18 n n CCONJ eurjchem-1480 52 19 n n CCONJ eurjchem-1480 52 20 n n ADV eurjchem-1480 52 21 m m VERB eurjchem-1480 52 22 m m VERB eurjchem-1480 52 23 m m VERB eurjchem-1480 52 24 m m NOUN eurjchem-1480 52 25 figure figure NOUN eurjchem-1480 52 26 1 1 NUM eurjchem-1480 52 27 . . PUNCT eurjchem-1480 53 1 synthesis synthesis NOUN eurjchem-1480 53 2 of of ADP eurjchem-1480 53 3 prepared prepare VERB eurjchem-1480 53 4 the the DET eurjchem-1480 53 5 copolymers copolymer NOUN eurjchem-1480 53 6 pl10brdm pl10brdm PROPN eurjchem-1480 53 7 , , PUNCT eurjchem-1480 53 8 pl25brdm pl25brdm PROPN eurjchem-1480 53 9 , , PUNCT eurjchem-1480 53 10 pl50brdm pl50brdm PROPN eurjchem-1480 53 11 and and CCONJ eurjchem-1480 53 12 pl100brdm pl100brdm PROPN eurjchem-1480 53 13 ( ( PUNCT eurjchem-1480 53 14 m m PROPN eurjchem-1480 53 15 ≈ ≈ PROPN eurjchem-1480 53 16 10 10 NUM eurjchem-1480 53 17 , , PUNCT eurjchem-1480 53 18 25 25 NUM eurjchem-1480 53 19 , , PUNCT eurjchem-1480 53 20 50 50 NUM eurjchem-1480 53 21 and and CCONJ eurjchem-1480 53 22 100 100 NUM eurjchem-1480 53 23 ) ) PUNCT eurjchem-1480 53 24 . . PUNCT eurjchem-1480 54 1 to to PART eurjchem-1480 54 2 record record VERB eurjchem-1480 54 3 1h 1h NUM eurjchem-1480 54 4 nmr nmr NOUN eurjchem-1480 54 5 and and CCONJ eurjchem-1480 54 6 13c 13c NOUN eurjchem-1480 54 7 nmr nmr NOUN eurjchem-1480 54 8 spectra spectra NOUN eurjchem-1480 54 9 . . PUNCT eurjchem-1480 55 1 copolymers copolymer NOUN eurjchem-1480 55 2 molecular molecular VERB eurjchem-1480 55 3 weights weight NOUN eurjchem-1480 55 4 and and CCONJ eurjchem-1480 55 5 molecular molecular ADJ eurjchem-1480 55 6 weight weight NOUN eurjchem-1480 55 7 distributions distribution NOUN eurjchem-1480 55 8 ( ( PUNCT eurjchem-1480 55 9 mw mw PROPN eurjchem-1480 55 10 / / SYM eurjchem-1480 55 11 mn mn PROPN eurjchem-1480 55 12 ) ) PUNCT eurjchem-1480 55 13 were be AUX eurjchem-1480 55 14 determined determine VERB eurjchem-1480 55 15 using use VERB eurjchem-1480 55 16 a a DET eurjchem-1480 55 17 waters water NOUN eurjchem-1480 55 18 1515 1515 NUM eurjchem-1480 55 19 gel gel NOUN eurjchem-1480 55 20 permeation permeation NOUN eurjchem-1480 55 21 chromato‐ chromato‐ PROPN eurjchem-1480 55 22 graphy graphy PROPN eurjchem-1480 55 23 ( ( PUNCT eurjchem-1480 55 24 gpc gpc PROPN eurjchem-1480 55 25 ) ) PUNCT eurjchem-1480 55 26 equipped equip VERB eurjchem-1480 55 27 with with ADP eurjchem-1480 55 28 a a DET eurjchem-1480 55 29 refractive‐index refractive‐index NOUN eurjchem-1480 55 30 detector detector NOUN eurjchem-1480 55 31 ( ( PUNCT eurjchem-1480 55 32 waters water NOUN eurjchem-1480 55 33 2412 2412 NUM eurjchem-1480 55 34 ) ) PUNCT eurjchem-1480 55 35 , , PUNCT eurjchem-1480 55 36 dmf dmf PROPN eurjchem-1480 55 37 was be AUX eurjchem-1480 55 38 used use VERB eurjchem-1480 55 39 as as ADP eurjchem-1480 55 40 the the DET eurjchem-1480 55 41 eluent eluent NOUN eurjchem-1480 55 42 at at ADP eurjchem-1480 55 43 a a DET eurjchem-1480 55 44 flow flow NOUN eurjchem-1480 55 45 rate rate NOUN eurjchem-1480 55 46 of of ADP eurjchem-1480 55 47 1.0 1.0 NUM eurjchem-1480 55 48 ml ml NOUN eurjchem-1480 55 49 / / SYM eurjchem-1480 55 50 min min NOUN eurjchem-1480 55 51 and and CCONJ eurjchem-1480 55 52 calibrated calibrate VERB eurjchem-1480 55 53 with with ADP eurjchem-1480 55 54 poly(methyl poly(methyl PROPN eurjchem-1480 55 55 methacrylate methacrylate NOUN eurjchem-1480 55 56 ) ) PUNCT eurjchem-1480 55 57 standard standard NOUN eurjchem-1480 55 58 . . PUNCT eurjchem-1480 56 1 the the DET eurjchem-1480 56 2 prepared prepare VERB eurjchem-1480 56 3 copolymers copolymer NOUN eurjchem-1480 56 4 were be AUX eurjchem-1480 56 5 examined examine VERB eurjchem-1480 56 6 under under ADP eurjchem-1480 56 7 scanning scan VERB eurjchem-1480 56 8 electron electron NOUN eurjchem-1480 56 9 microscope microscope NOUN eurjchem-1480 56 10 type type NOUN eurjchem-1480 56 11 jeol jeol PROPN eurjchem-1480 56 12 7500f 7500f NUM eurjchem-1480 56 13 supplied supply VERB eurjchem-1480 56 14 by by ADP eurjchem-1480 56 15 jeol jeol PROPN eurjchem-1480 56 16 company company PROPN eurjchem-1480 56 17 , , PUNCT eurjchem-1480 56 18 usa usa PROPN eurjchem-1480 56 19 . . PROPN eurjchem-1480 56 20 computer computer PROPN eurjchem-1480 56 21 controlled control VERB eurjchem-1480 56 22 thermal thermal ADJ eurjchem-1480 56 23 analysis analysis NOUN eurjchem-1480 56 24 instrumentals instrumental NOUN eurjchem-1480 56 25 , , PUNCT eurjchem-1480 56 26 tga‐q500 tga‐q500 NOUN eurjchem-1480 56 27 v20.10 v20.10 NOUN eurjchem-1480 56 28 was be AUX eurjchem-1480 56 29 used use VERB eurjchem-1480 56 30 to to PART eurjchem-1480 56 31 study study VERB eurjchem-1480 56 32 the the DET eurjchem-1480 56 33 thermal thermal ADJ eurjchem-1480 56 34 stability stability NOUN eurjchem-1480 56 35 of of ADP eurjchem-1480 56 36 the the DET eurjchem-1480 56 37 prepared prepared ADJ eurjchem-1480 56 38 polymers polymer NOUN eurjchem-1480 56 39 . . PUNCT eurjchem-1480 57 1 2.3 2.3 NUM eurjchem-1480 57 2 . . PUNCT eurjchem-1480 57 3 preparation preparation NOUN eurjchem-1480 57 4 of of ADP eurjchem-1480 57 5 pentaerythritol‐lactide pentaerythritol‐lactide ADP eurjchem-1480 57 6 tetrakis tetraki NOUN eurjchem-1480 57 7 ( ( PUNCT eurjchem-1480 57 8 2‐bromoisobutyrate 2‐bromoisobutyrate NUM eurjchem-1480 57 9 ) ) PUNCT eurjchem-1480 57 10 ( ( PUNCT eurjchem-1480 57 11 tetrafunctional tetrafunctional ADJ eurjchem-1480 57 12 initiator initiator NOUN eurjchem-1480 57 13 ) ) PUNCT eurjchem-1480 57 14 ( ( PUNCT eurjchem-1480 57 15 plnbr plnbr NOUN eurjchem-1480 57 16 ) ) PUNCT eurjchem-1480 57 17 pentaerythritol‐lactideisobutyryl pentaerythritol‐lactideisobutyryl PROPN eurjchem-1480 57 18 bromide bromide NOUN eurjchem-1480 57 19 atrp atrp NOUN eurjchem-1480 57 20 initiators initiator NOUN eurjchem-1480 57 21 having have VERB eurjchem-1480 57 22 different different ADJ eurjchem-1480 57 23 repeating repeat VERB eurjchem-1480 57 24 units unit NOUN eurjchem-1480 57 25 ( ( PUNCT eurjchem-1480 57 26 10 10 NUM eurjchem-1480 57 27 , , PUNCT eurjchem-1480 57 28 25 25 NUM eurjchem-1480 57 29 , , PUNCT eurjchem-1480 57 30 50 50 NUM eurjchem-1480 57 31 and and CCONJ eurjchem-1480 57 32 100 100 NUM eurjchem-1480 57 33 ) ) PUNCT eurjchem-1480 57 34 of of ADP eurjchem-1480 57 35 l‐ l‐ PROPN eurjchem-1480 57 36 lactide lactide PROPN eurjchem-1480 57 37 have have AUX eurjchem-1480 57 38 been be AUX eurjchem-1480 57 39 prepared prepare VERB eurjchem-1480 57 40 according accord VERB eurjchem-1480 57 41 to to ADP eurjchem-1480 57 42 previous previous ADJ eurjchem-1480 57 43 works work NOUN eurjchem-1480 57 44 [ [ X eurjchem-1480 57 45 10 10 NUM eurjchem-1480 57 46 ] ] PUNCT eurjchem-1480 57 47 and and CCONJ eurjchem-1480 57 48 characterized characterize VERB eurjchem-1480 57 49 by by ADP eurjchem-1480 57 50 ft‐ir ft‐ir NOUN eurjchem-1480 57 51 and and CCONJ eurjchem-1480 57 52 nmr nmr NOUN eurjchem-1480 57 53 spectroscopy spectroscopy NOUN eurjchem-1480 57 54 . . PUNCT eurjchem-1480 58 1 copolymer copolymer NOUN eurjchem-1480 58 2 pl10br pl10br PROPN eurjchem-1480 58 3 : : PUNCT eurjchem-1480 58 4 color color NOUN eurjchem-1480 58 5 : : PUNCT eurjchem-1480 58 6 white white ADJ eurjchem-1480 58 7 . . PUNCT eurjchem-1480 59 1 yield yield NOUN eurjchem-1480 59 2 : : PUNCT eurjchem-1480 59 3 70 70 NUM eurjchem-1480 59 4 % % NOUN eurjchem-1480 59 5 . . PUNCT eurjchem-1480 60 1 ft‐ir ft‐ir NOUN eurjchem-1480 60 2 ( ( PUNCT eurjchem-1480 60 3 kbr kbr PROPN eurjchem-1480 60 4 , , PUNCT eurjchem-1480 60 5   PROPN eurjchem-1480 60 6 , , PUNCT eurjchem-1480 60 7 cm‐1 cm‐1 PROPN eurjchem-1480 60 8 ): ): PUNCT eurjchem-1480 60 9 2991 2991 NUM eurjchem-1480 60 10 ( ( PUNCT eurjchem-1480 60 11 c‐h c‐h NUM eurjchem-1480 60 12 ) ) PUNCT eurjchem-1480 60 13 , , PUNCT eurjchem-1480 60 14 1741 1741 NUM eurjchem-1480 60 15 ( ( PUNCT eurjchem-1480 60 16 c c NOUN eurjchem-1480 60 17 = = NOUN eurjchem-1480 60 18 o o NOUN eurjchem-1480 60 19 ) ) PUNCT eurjchem-1480 60 20 , , PUNCT eurjchem-1480 60 21 1195 1195 NUM eurjchem-1480 60 22 ( ( PUNCT eurjchem-1480 60 23 c‐o c‐o NOUN eurjchem-1480 60 24 ) ) PUNCT eurjchem-1480 60 25 , , PUNCT eurjchem-1480 60 26 649 649 NUM eurjchem-1480 60 27 ( ( PUNCT eurjchem-1480 60 28 c‐br c‐br NOUN eurjchem-1480 60 29 ) ) PUNCT eurjchem-1480 60 30 . . PUNCT eurjchem-1480 61 1 1h 1h NUM eurjchem-1480 61 2 nmr nmr NOUN eurjchem-1480 61 3 ( ( PUNCT eurjchem-1480 61 4 500 500 NUM eurjchem-1480 61 5 mhz mhz NOUN eurjchem-1480 61 6 , , PUNCT eurjchem-1480 61 7 cdcl3 cdcl3 PROPN eurjchem-1480 61 8 , , PUNCT eurjchem-1480 61 9 δ δ PROPN eurjchem-1480 61 10 , , PUNCT eurjchem-1480 61 11 ppm ppm NUM eurjchem-1480 61 12 ): ): PUNCT eurjchem-1480 61 13 5.3 5.3 NUM eurjchem-1480 61 14 ( ( PUNCT eurjchem-1480 61 15 o‐ch2 o‐ch2 PROPN eurjchem-1480 61 16 ) ) PUNCT eurjchem-1480 61 17 , , PUNCT eurjchem-1480 61 18 5.2 5.2 NUM eurjchem-1480 61 19 ( ( PUNCT eurjchem-1480 61 20 o‐ch o‐ch ADJ eurjchem-1480 61 21 groups group NOUN eurjchem-1480 61 22 of of ADP eurjchem-1480 61 23 repeating repeat VERB eurjchem-1480 61 24 unit unit NOUN eurjchem-1480 61 25 of of ADP eurjchem-1480 61 26 l‐lactide l‐lactide PROPN eurjchem-1480 61 27 ) ) PUNCT eurjchem-1480 61 28 , , PUNCT eurjchem-1480 61 29 1.6 1.6 NUM eurjchem-1480 61 30 ( ( PUNCT eurjchem-1480 61 31 ch3 ch3 NOUN eurjchem-1480 61 32 groups group NOUN eurjchem-1480 61 33 of of ADP eurjchem-1480 61 34 repeating repeat VERB eurjchem-1480 61 35 unit unit NOUN eurjchem-1480 61 36 of of ADP eurjchem-1480 61 37 l‐lactide l‐lactide PROPN eurjchem-1480 61 38 ) ) PUNCT eurjchem-1480 61 39 , , PUNCT eurjchem-1480 61 40 1.95 1.95 NUM eurjchem-1480 61 41 ( ( PUNCT eurjchem-1480 61 42 ch3‐c‐br ch3‐c‐br NOUN eurjchem-1480 61 43 ) ) PUNCT eurjchem-1480 61 44 . . PUNCT eurjchem-1480 62 1 13c 13c NOUN eurjchem-1480 62 2 nmr nmr NOUN eurjchem-1480 62 3 ( ( PUNCT eurjchem-1480 62 4 500 500 NUM eurjchem-1480 62 5 mhz mhz NOUN eurjchem-1480 62 6 , , PUNCT eurjchem-1480 62 7 cdcl3 cdcl3 PROPN eurjchem-1480 62 8 , , PUNCT eurjchem-1480 62 9 δ δ PROPN eurjchem-1480 62 10 , , PUNCT eurjchem-1480 62 11 ppm ppm NUM eurjchem-1480 62 12 ): ): PUNCT eurjchem-1480 62 13 170 170 NUM eurjchem-1480 62 14 ( ( PUNCT eurjchem-1480 62 15 c c X eurjchem-1480 62 16 = = NOUN eurjchem-1480 62 17 o o X eurjchem-1480 62 18 of of ADP eurjchem-1480 62 19 repeating repeat VERB eurjchem-1480 62 20 unit unit NOUN eurjchem-1480 62 21 of of ADP eurjchem-1480 62 22 l‐lactide l‐lactide PROPN eurjchem-1480 62 23 ) ) PUNCT eurjchem-1480 62 24 , , PUNCT eurjchem-1480 62 25 166 166 NUM eurjchem-1480 62 26 ( ( PUNCT eurjchem-1480 62 27 c c X eurjchem-1480 62 28 = = NOUN eurjchem-1480 62 29 o o X eurjchem-1480 62 30 of of ADP eurjchem-1480 62 31 isobutyryl isobutyryl PROPN eurjchem-1480 62 32 bromide bromide NOUN eurjchem-1480 62 33 ) ) PUNCT eurjchem-1480 62 34 , , PUNCT eurjchem-1480 62 35 69 69 NUM eurjchem-1480 62 36 ( ( PUNCT eurjchem-1480 62 37 ch3 ch3 PROPN eurjchem-1480 62 38 group group NOUN eurjchem-1480 62 39 in in ADP eurjchem-1480 62 40 repeating repeat VERB eurjchem-1480 62 41 unit unit NOUN eurjchem-1480 62 42 of of ADP eurjchem-1480 62 43 l‐ l‐ PROPN eurjchem-1480 62 44 lactide lactide ADJ eurjchem-1480 62 45 segments segment NOUN eurjchem-1480 62 46 ) ) PUNCT eurjchem-1480 62 47 , , PUNCT eurjchem-1480 62 48 67 67 NUM eurjchem-1480 62 49 ( ( PUNCT eurjchem-1480 62 50 carbon carbon NOUN eurjchem-1480 62 51 atom atom NOUN eurjchem-1480 62 52 in in ADP eurjchem-1480 62 53 methine methine ADJ eurjchem-1480 62 54 group group NOUN eurjchem-1480 62 55 of of ADP eurjchem-1480 62 56 pentaerythritol pentaerythritol NOUN eurjchem-1480 62 57 ) ) PUNCT eurjchem-1480 62 58 , , PUNCT eurjchem-1480 62 59 55 55 NUM eurjchem-1480 62 60 ( ( PUNCT eurjchem-1480 62 61 c‐br c‐br NOUN eurjchem-1480 62 62 ) ) PUNCT eurjchem-1480 62 63 , , PUNCT eurjchem-1480 62 64 41 41 NUM eurjchem-1480 62 65 ( ( PUNCT eurjchem-1480 62 66 center center NOUN eurjchem-1480 62 67 carbon carbon NOUN eurjchem-1480 62 68 atom atom NOUN eurjchem-1480 62 69 of of ADP eurjchem-1480 62 70 penta penta PROPN eurjchem-1480 62 71 erythritol erythritol NOUN eurjchem-1480 62 72 ) ) PUNCT eurjchem-1480 62 73 , , PUNCT eurjchem-1480 62 74 30 30 NUM eurjchem-1480 62 75 ( ( PUNCT eurjchem-1480 62 76 ch3 ch3 PROPN eurjchem-1480 62 77 of of ADP eurjchem-1480 62 78 end end NOUN eurjchem-1480 62 79 chains chain NOUN eurjchem-1480 62 80 ) ) PUNCT eurjchem-1480 62 81 , , PUNCT eurjchem-1480 62 82 17 17 NUM eurjchem-1480 62 83 ( ( PUNCT eurjchem-1480 62 84 o‐ch‐ch3 o‐ch‐ch3 ADJ eurjchem-1480 62 85 group group NOUN eurjchem-1480 62 86 in in ADP eurjchem-1480 62 87 repeating repeat VERB eurjchem-1480 62 88 unit unit NOUN eurjchem-1480 62 89 of of ADP eurjchem-1480 62 90 l‐lactide l‐lactide PUNCT eurjchem-1480 62 91 segments segment NOUN eurjchem-1480 62 92 ) ) PUNCT eurjchem-1480 62 93 . . PUNCT eurjchem-1480 63 1 copolymer copolymer NOUN eurjchem-1480 63 2 pl25br pl25br NOUN eurjchem-1480 63 3 : : PUNCT eurjchem-1480 63 4 color color NOUN eurjchem-1480 63 5 : : PUNCT eurjchem-1480 63 6 white white ADJ eurjchem-1480 63 7 . . PUNCT eurjchem-1480 64 1 yield yield NOUN eurjchem-1480 64 2 : : PUNCT eurjchem-1480 64 3 73 73 NUM eurjchem-1480 64 4 % % NOUN eurjchem-1480 64 5 . . PUNCT eurjchem-1480 65 1 ft‐ir ft‐ir NOUN eurjchem-1480 65 2 ( ( PUNCT eurjchem-1480 65 3 kbr kbr PROPN eurjchem-1480 65 4 , , PUNCT eurjchem-1480 65 5   PROPN eurjchem-1480 65 6 , , PUNCT eurjchem-1480 65 7 cm‐1 cm‐1 PROPN eurjchem-1480 65 8 ): ): PUNCT eurjchem-1480 65 9 2996 2996 NUM eurjchem-1480 65 10 ( ( PUNCT eurjchem-1480 65 11 c‐h c‐h NUM eurjchem-1480 65 12 ) ) PUNCT eurjchem-1480 65 13 , , PUNCT eurjchem-1480 65 14 1746 1746 NUM eurjchem-1480 65 15 ( ( PUNCT eurjchem-1480 65 16 c c NOUN eurjchem-1480 65 17 = = NOUN eurjchem-1480 65 18 o o NOUN eurjchem-1480 65 19 ) ) PUNCT eurjchem-1480 65 20 , , PUNCT eurjchem-1480 65 21 1197 1197 NUM eurjchem-1480 65 22 ( ( PUNCT eurjchem-1480 65 23 c‐o c‐o NOUN eurjchem-1480 65 24 ) ) PUNCT eurjchem-1480 65 25 , , PUNCT eurjchem-1480 65 26 647 647 NUM eurjchem-1480 65 27 ( ( PUNCT eurjchem-1480 65 28 c‐br c‐br NOUN eurjchem-1480 65 29 ) ) PUNCT eurjchem-1480 65 30 . . PUNCT eurjchem-1480 66 1 1h 1h NUM eurjchem-1480 66 2 nmr nmr NOUN eurjchem-1480 66 3 ( ( PUNCT eurjchem-1480 66 4 500 500 NUM eurjchem-1480 66 5 mhz mhz NOUN eurjchem-1480 66 6 , , PUNCT eurjchem-1480 66 7 cdcl3 cdcl3 PROPN eurjchem-1480 66 8 , , PUNCT eurjchem-1480 66 9 δ δ PROPN eurjchem-1480 66 10 , , PUNCT eurjchem-1480 66 11 ppm ppm NUM eurjchem-1480 66 12 ): ): PUNCT eurjchem-1480 66 13 5.3 5.3 NUM eurjchem-1480 66 14 ( ( PUNCT eurjchem-1480 66 15 o‐ch2 o‐ch2 PROPN eurjchem-1480 66 16 ) ) PUNCT eurjchem-1480 66 17 , , PUNCT eurjchem-1480 66 18 5.15 5.15 NUM eurjchem-1480 66 19 ( ( PUNCT eurjchem-1480 66 20 o‐ch o‐ch ADJ eurjchem-1480 66 21 groups group NOUN eurjchem-1480 66 22 of of ADP eurjchem-1480 66 23 repeating repeat VERB eurjchem-1480 66 24 unit unit NOUN eurjchem-1480 66 25 of of ADP eurjchem-1480 66 26 l‐lactide l‐lactide PROPN eurjchem-1480 66 27 ) ) PUNCT eurjchem-1480 66 28 , , PUNCT eurjchem-1480 66 29 1.97 1.97 NUM eurjchem-1480 66 30 ( ( PUNCT eurjchem-1480 66 31 ch3‐c‐br ch3‐c‐br NOUN eurjchem-1480 66 32 ) ) PUNCT eurjchem-1480 66 33 , , PUNCT eurjchem-1480 66 34 1.55 1.55 NUM eurjchem-1480 66 35 ( ( PUNCT eurjchem-1480 66 36 ch3 ch3 NOUN eurjchem-1480 66 37 groups group NOUN eurjchem-1480 66 38 of of ADP eurjchem-1480 66 39 repeating repeat VERB eurjchem-1480 66 40 unit unit NOUN eurjchem-1480 66 41 of of ADP eurjchem-1480 66 42 l‐lactide l‐lactide PROPN eurjchem-1480 66 43 ) ) PUNCT eurjchem-1480 66 44 . . PUNCT eurjchem-1480 67 1 copolymer copolymer NOUN eurjchem-1480 67 2 pl50br pl50br PROPN eurjchem-1480 67 3 : : PUNCT eurjchem-1480 67 4 color color NOUN eurjchem-1480 67 5 : : PUNCT eurjchem-1480 67 6 white white ADJ eurjchem-1480 67 7 . . PUNCT eurjchem-1480 68 1 yield yield NOUN eurjchem-1480 68 2 : : PUNCT eurjchem-1480 68 3 76 76 NUM eurjchem-1480 68 4 % % NOUN eurjchem-1480 68 5 . . PUNCT eurjchem-1480 69 1 ft‐ir ft‐ir NOUN eurjchem-1480 69 2 ( ( PUNCT eurjchem-1480 69 3 kbr kbr PROPN eurjchem-1480 69 4 , , PUNCT eurjchem-1480 69 5   PROPN eurjchem-1480 69 6 , , PUNCT eurjchem-1480 69 7 cm‐1 cm‐1 PROPN eurjchem-1480 69 8 ): ): PUNCT eurjchem-1480 69 9 2998 2998 NUM eurjchem-1480 69 10 ( ( PUNCT eurjchem-1480 69 11 c‐h c‐h NUM eurjchem-1480 69 12 ) ) PUNCT eurjchem-1480 69 13 , , PUNCT eurjchem-1480 69 14 1751 1751 NUM eurjchem-1480 69 15 ( ( PUNCT eurjchem-1480 69 16 c c NOUN eurjchem-1480 69 17 = = NOUN eurjchem-1480 69 18 o o NOUN eurjchem-1480 69 19 ) ) PUNCT eurjchem-1480 69 20 , , PUNCT eurjchem-1480 69 21 1198 1198 NUM eurjchem-1480 69 22 ( ( PUNCT eurjchem-1480 69 23 c‐o c‐o NOUN eurjchem-1480 69 24 ) ) PUNCT eurjchem-1480 69 25 , , PUNCT eurjchem-1480 69 26 641 641 NUM eurjchem-1480 69 27 ( ( PUNCT eurjchem-1480 69 28 c‐br c‐br NOUN eurjchem-1480 69 29 ) ) PUNCT eurjchem-1480 69 30 . . PUNCT eurjchem-1480 70 1 1h 1h NUM eurjchem-1480 70 2 nmr nmr NOUN eurjchem-1480 70 3 ( ( PUNCT eurjchem-1480 70 4 500 500 NUM eurjchem-1480 70 5 mhz mhz NOUN eurjchem-1480 70 6 , , PUNCT eurjchem-1480 70 7 cdcl3 cdcl3 PROPN eurjchem-1480 70 8 , , PUNCT eurjchem-1480 70 9 δ δ PROPN eurjchem-1480 70 10 , , PUNCT eurjchem-1480 70 11 ppm ppm NUM eurjchem-1480 70 12 ): ): PUNCT eurjchem-1480 70 13 5.3 5.3 NUM eurjchem-1480 70 14 ( ( PUNCT eurjchem-1480 70 15 o‐ch2 o‐ch2 PROPN eurjchem-1480 70 16 ) ) PUNCT eurjchem-1480 70 17 , , PUNCT eurjchem-1480 70 18 5.17 5.17 NUM eurjchem-1480 70 19 ( ( PUNCT eurjchem-1480 70 20 o‐ch o‐ch ADJ eurjchem-1480 70 21 groups group NOUN eurjchem-1480 70 22 of of ADP eurjchem-1480 70 23 repeating repeat VERB eurjchem-1480 70 24 unit unit NOUN eurjchem-1480 70 25 of of ADP eurjchem-1480 70 26 l‐lactide l‐lactide PROPN eurjchem-1480 70 27 ) ) PUNCT eurjchem-1480 70 28 , , PUNCT eurjchem-1480 70 29 1.96 1.96 NUM eurjchem-1480 70 30 ( ( PUNCT eurjchem-1480 70 31 ch3‐c‐br ch3‐c‐br NOUN eurjchem-1480 70 32 ) ) PUNCT eurjchem-1480 70 33 , , PUNCT eurjchem-1480 70 34 1.57 1.57 NUM eurjchem-1480 70 35 ( ( PUNCT eurjchem-1480 70 36 ch3 ch3 NOUN eurjchem-1480 70 37 groups group NOUN eurjchem-1480 70 38 of of ADP eurjchem-1480 70 39 repeating repeat VERB eurjchem-1480 70 40 unit unit NOUN eurjchem-1480 70 41 of of ADP eurjchem-1480 70 42 l‐lactide l‐lactide PROPN eurjchem-1480 70 43 ) ) PUNCT eurjchem-1480 70 44 . . PUNCT eurjchem-1480 71 1 copolymer copolymer NOUN eurjchem-1480 71 2 pl100br pl100br PROPN eurjchem-1480 71 3 : : PUNCT eurjchem-1480 71 4 color color NOUN eurjchem-1480 71 5 : : PUNCT eurjchem-1480 71 6 white white ADJ eurjchem-1480 71 7 . . PUNCT eurjchem-1480 72 1 yield yield NOUN eurjchem-1480 72 2 : : PUNCT eurjchem-1480 72 3 78 78 NUM eurjchem-1480 72 4 % % NOUN eurjchem-1480 72 5 . . PUNCT eurjchem-1480 73 1 ft‐ir ft‐ir NOUN eurjchem-1480 73 2 ( ( PUNCT eurjchem-1480 73 3 kbr kbr PROPN eurjchem-1480 73 4 , , PUNCT eurjchem-1480 73 5   PROPN eurjchem-1480 73 6 , , PUNCT eurjchem-1480 73 7 cm‐1 cm‐1 PROPN eurjchem-1480 73 8 ): ): PUNCT eurjchem-1480 73 9 3011 3011 NUM eurjchem-1480 73 10 ( ( PUNCT eurjchem-1480 73 11 c‐h c‐h NUM eurjchem-1480 73 12 ) ) PUNCT eurjchem-1480 73 13 , , PUNCT eurjchem-1480 73 14 1745 1745 NUM eurjchem-1480 73 15 ( ( PUNCT eurjchem-1480 73 16 c c NOUN eurjchem-1480 73 17 = = NOUN eurjchem-1480 73 18 o o NOUN eurjchem-1480 73 19 ) ) PUNCT eurjchem-1480 73 20 , , PUNCT eurjchem-1480 73 21 1191 1191 NUM eurjchem-1480 73 22 ( ( PUNCT eurjchem-1480 73 23 c‐o c‐o NOUN eurjchem-1480 73 24 ) ) PUNCT eurjchem-1480 73 25 , , PUNCT eurjchem-1480 73 26 635 635 NUM eurjchem-1480 73 27 ( ( PUNCT eurjchem-1480 73 28 c‐br c‐br NOUN eurjchem-1480 73 29 ) ) PUNCT eurjchem-1480 73 30 . . PUNCT eurjchem-1480 74 1 1h 1h NUM eurjchem-1480 74 2 nmr nmr NOUN eurjchem-1480 74 3 ( ( PUNCT eurjchem-1480 74 4 500 500 NUM eurjchem-1480 74 5 mhz mhz NOUN eurjchem-1480 74 6 , , PUNCT eurjchem-1480 74 7 cdcl3 cdcl3 PROPN eurjchem-1480 74 8 , , PUNCT eurjchem-1480 74 9 δ δ PROPN eurjchem-1480 74 10 , , PUNCT eurjchem-1480 74 11 ppm ppm NUM eurjchem-1480 74 12 ): ): PUNCT eurjchem-1480 74 13 5.3 5.3 NUM eurjchem-1480 74 14 ( ( PUNCT eurjchem-1480 74 15 o‐ch2 o‐ch2 PROPN eurjchem-1480 74 16 ) ) PUNCT eurjchem-1480 74 17 , , PUNCT eurjchem-1480 74 18 5.16 5.16 NUM eurjchem-1480 74 19 ( ( PUNCT eurjchem-1480 74 20 o‐ch o‐ch ADJ eurjchem-1480 74 21 groups group NOUN eurjchem-1480 74 22 of of ADP eurjchem-1480 74 23 repeating repeat VERB eurjchem-1480 74 24 unit unit NOUN eurjchem-1480 74 25 of of ADP eurjchem-1480 74 26 l‐lactide l‐lactide PROPN eurjchem-1480 74 27 ) ) PUNCT eurjchem-1480 74 28 , , PUNCT eurjchem-1480 74 29 1.96 1.96 NUM eurjchem-1480 74 30 ( ( PUNCT eurjchem-1480 74 31 ch3‐c‐br ch3‐c‐br PROPN eurjchem-1480 74 32 ) ) PUNCT eurjchem-1480 74 33 , , PUNCT eurjchem-1480 74 34 1.58 1.58 NUM eurjchem-1480 74 35 ( ( PUNCT eurjchem-1480 74 36 ch3 ch3 NOUN eurjchem-1480 74 37 groups group NOUN eurjchem-1480 74 38 of of ADP eurjchem-1480 74 39 repeating repeat VERB eurjchem-1480 74 40 unit unit NOUN eurjchem-1480 74 41 of of ADP eurjchem-1480 74 42 l‐lactide l‐lactide PROPN eurjchem-1480 74 43 ) ) PUNCT eurjchem-1480 74 44 . . PUNCT eurjchem-1480 75 1 2.4 2.4 NUM eurjchem-1480 75 2 . . PUNCT eurjchem-1480 75 3 synthesis synthesis NOUN eurjchem-1480 75 4 of of ADP eurjchem-1480 75 5 four four NUM eurjchem-1480 75 6 arms arm NOUN eurjchem-1480 75 7 poly(pentaerythrirol‐lactide‐b‐ poly(pentaerythrirol‐lactide‐b‐ NOUN eurjchem-1480 75 8 n n CCONJ eurjchem-1480 75 9 , , PUNCT eurjchem-1480 75 10 n‐dimethylaminoethylmethacrylate n‐dimethylaminoethylmethacrylate NUM eurjchem-1480 75 11 ) ) PUNCT eurjchem-1480 75 12 ( ( PUNCT eurjchem-1480 75 13 pl10brdm pl10brdm NOUN eurjchem-1480 75 14 ) ) PUNCT eurjchem-1480 75 15 pentaerythritol‐lactideisobutyryl pentaerythritol‐lactideisobutyryl NOUN eurjchem-1480 75 16 bromide bromide NOUN eurjchem-1480 75 17 ( ( PUNCT eurjchem-1480 75 18 pl10br pl10br PROPN eurjchem-1480 75 19 ) ) PUNCT eurjchem-1480 75 20 ( ( PUNCT eurjchem-1480 75 21 0.4 0.4 NUM eurjchem-1480 75 22 g g NOUN eurjchem-1480 75 23 , , PUNCT eurjchem-1480 75 24 0.11 0.11 NUM eurjchem-1480 75 25 mmol mmol NOUN eurjchem-1480 75 26 ) ) PUNCT eurjchem-1480 75 27 , , PUNCT eurjchem-1480 75 28 n n CCONJ eurjchem-1480 75 29 , , PUNCT eurjchem-1480 75 30 n‐dimethylaminoethyl n‐dimethylaminoethyl X eurjchem-1480 75 31 methacrylate methacrylate NOUN eurjchem-1480 75 32 ( ( PUNCT eurjchem-1480 75 33 dma dma PROPN eurjchem-1480 75 34 ema ema PROPN eurjchem-1480 75 35 ) ) PUNCT eurjchem-1480 75 36 ( ( PUNCT eurjchem-1480 75 37 0.8 0.8 NUM eurjchem-1480 75 38 g g NOUN eurjchem-1480 75 39 , , PUNCT eurjchem-1480 75 40 5.0 5.0 NUM eurjchem-1480 75 41 mmol mmol NOUN eurjchem-1480 75 42 ) ) PUNCT eurjchem-1480 75 43 , , PUNCT eurjchem-1480 75 44 copper(i copper(i NOUN eurjchem-1480 75 45 ) ) PUNCT eurjchem-1480 75 46 bromide bromide NOUN eurjchem-1480 75 47 ( ( PUNCT eurjchem-1480 75 48 0.05 0.05 NUM eurjchem-1480 75 49 g g NOUN eurjchem-1480 75 50 , , PUNCT eurjchem-1480 75 51 0.4 0.4 NUM eurjchem-1480 75 52 mmol mmol NOUN eurjchem-1480 75 53 ) ) PUNCT eurjchem-1480 75 54 and and CCONJ eurjchem-1480 75 55 n n CCONJ eurjchem-1480 75 56 , , PUNCT eurjchem-1480 75 57 n n CCONJ eurjchem-1480 75 58 , , PUNCT eurjchem-1480 75 59 n′,n′′,n′′‐pentamethyldiethylenetriamine n′,n′′,n′′‐pentamethyldiethylenetriamine PROPN eurjchem-1480 75 60 ( ( PUNCT eurjchem-1480 75 61 pmdeta pmdeta NOUN eurjchem-1480 75 62 ) ) PUNCT eurjchem-1480 75 63 ( ( PUNCT eurjchem-1480 75 64 20 20 NUM eurjchem-1480 75 65 μl μl DET eurjchem-1480 75 66 ) ) PUNCT eurjchem-1480 75 67 were be AUX eurjchem-1480 75 68 dissolved dissolve VERB eurjchem-1480 75 69 in in ADP eurjchem-1480 75 70 15 15 NUM eurjchem-1480 75 71 ml ml NOUN eurjchem-1480 75 72 dimethyl dimethyl PROPN eurjchem-1480 75 73 formamide formamide ADV eurjchem-1480 75 74 ( ( PUNCT eurjchem-1480 75 75 dmf dmf PROPN eurjchem-1480 75 76 ) ) PUNCT eurjchem-1480 75 77 at at ADP eurjchem-1480 75 78 60 60 NUM eurjchem-1480 75 79 ° ° NOUN eurjchem-1480 75 80 c c NOUN eurjchem-1480 75 81 . . PUNCT eurjchem-1480 76 1 after after ADP eurjchem-1480 76 2 stirring stir VERB eurjchem-1480 76 3 for for ADP eurjchem-1480 76 4 1 1 NUM eurjchem-1480 76 5 h h NOUN eurjchem-1480 76 6 under under ADP eurjchem-1480 76 7 nitrogen nitrogen NOUN eurjchem-1480 76 8 atmosphere atmosphere NOUN eurjchem-1480 76 9 , , PUNCT eurjchem-1480 76 10 the the DET eurjchem-1480 76 11 reaction reaction NOUN eurjchem-1480 76 12 was be AUX eurjchem-1480 76 13 stirred stir VERB eurjchem-1480 76 14 for for ADP eurjchem-1480 76 15 a a DET eurjchem-1480 76 16 further further ADJ eurjchem-1480 76 17 14 14 NUM eurjchem-1480 76 18 h h NOUN eurjchem-1480 76 19 at at ADP eurjchem-1480 76 20 60 60 NUM eurjchem-1480 76 21 ° ° NOUN eurjchem-1480 76 22 c c NOUN eurjchem-1480 76 23 . . PUNCT eurjchem-1480 77 1 afterwards afterwards ADV eurjchem-1480 77 2 , , PUNCT eurjchem-1480 77 3 the the DET eurjchem-1480 77 4 product product NOUN eurjchem-1480 77 5 was be AUX eurjchem-1480 77 6 added add VERB eurjchem-1480 77 7 slowly slowly ADV eurjchem-1480 77 8 to to ADP eurjchem-1480 77 9 500 500 NUM eurjchem-1480 77 10 ml ml NOUN eurjchem-1480 77 11 cold cold ADJ eurjchem-1480 77 12 diethyl diethyl NOUN eurjchem-1480 77 13 ether ether NOUN eurjchem-1480 77 14 to to PART eurjchem-1480 77 15 precipitate precipitate VERB eurjchem-1480 77 16 the the DET eurjchem-1480 77 17 copolymer copolymer NOUN eurjchem-1480 77 18 which which PRON eurjchem-1480 77 19 was be AUX eurjchem-1480 77 20 then then ADV eurjchem-1480 77 21 filtered filter VERB eurjchem-1480 77 22 on on ADP eurjchem-1480 77 23 a a DET eurjchem-1480 77 24 buchner buchner NOUN eurjchem-1480 77 25 funnel funnel NOUN eurjchem-1480 77 26 and and CCONJ eurjchem-1480 77 27 washed wash VERB eurjchem-1480 77 28 with with ADP eurjchem-1480 77 29 diethyl diethyl NOUN eurjchem-1480 77 30 ether ether NOUN eurjchem-1480 77 31 and and CCONJ eurjchem-1480 77 32 then then ADV eurjchem-1480 77 33 the the DET eurjchem-1480 77 34 filtrate filtrate NOUN eurjchem-1480 77 35 was be AUX eurjchem-1480 77 36 dissolved dissolve VERB eurjchem-1480 77 37 in in ADP eurjchem-1480 77 38 dmf dmf PROPN eurjchem-1480 77 39 ( ( PUNCT eurjchem-1480 77 40 15 15 NUM eurjchem-1480 77 41 ml ml NOUN eurjchem-1480 77 42 ) ) PUNCT eurjchem-1480 77 43 . . PUNCT eurjchem-1480 78 1 the the DET eurjchem-1480 78 2 copolymer copolymer NOUN eurjchem-1480 78 3 was be AUX eurjchem-1480 78 4 recovered recover VERB eurjchem-1480 78 5 through through ADP eurjchem-1480 78 6 the the DET eurjchem-1480 78 7 column column NOUN eurjchem-1480 78 8 chromatography chromatography NOUN eurjchem-1480 78 9 filled fill VERB eurjchem-1480 78 10 with with ADP eurjchem-1480 78 11 silica silica NOUN eurjchem-1480 78 12 gel gel NOUN eurjchem-1480 78 13 . . PUNCT eurjchem-1480 79 1 the the DET eurjchem-1480 79 2 solvent solvent PROPN eurjchem-1480 79 3 dmf dmf PROPN eurjchem-1480 79 4 was be AUX eurjchem-1480 79 5 removed remove VERB eurjchem-1480 79 6 by by ADP eurjchem-1480 79 7 rotary rotary ADJ eurjchem-1480 79 8 evaporator evaporator NOUN eurjchem-1480 79 9 and and CCONJ eurjchem-1480 79 10 the the DET eurjchem-1480 79 11 copolymer copolymer NOUN eurjchem-1480 79 12 was be AUX eurjchem-1480 79 13 dried dry VERB eurjchem-1480 79 14 in in ADP eurjchem-1480 79 15 vacuum vacuum PROPN eurjchem-1480 79 16 oven oven NOUN eurjchem-1480 79 17 at at ADP eurjchem-1480 79 18 25 25 NUM eurjchem-1480 79 19 ° ° NOUN eurjchem-1480 79 20 c c NOUN eurjchem-1480 79 21 for for ADP eurjchem-1480 79 22 24 24 NUM eurjchem-1480 79 23 hours hour NOUN eurjchem-1480 79 24 , , PUNCT eurjchem-1480 79 25 ( ( PUNCT eurjchem-1480 79 26 solid solid ADJ eurjchem-1480 79 27 , , PUNCT eurjchem-1480 79 28 yield yield NOUN eurjchem-1480 79 29 : : PUNCT eurjchem-1480 79 30 65 65 NUM eurjchem-1480 79 31 % % NOUN eurjchem-1480 79 32 ) ) PUNCT eurjchem-1480 79 33 . . PUNCT eurjchem-1480 80 1 the the DET eurjchem-1480 80 2 same same ADJ eurjchem-1480 80 3 procedure procedure NOUN eurjchem-1480 80 4 was be AUX eurjchem-1480 80 5 repeated repeat VERB eurjchem-1480 80 6 to to PART eurjchem-1480 80 7 prepare prepare VERB eurjchem-1480 80 8 the the DET eurjchem-1480 80 9 copolymers copolymer NOUN eurjchem-1480 80 10 pl25brdm pl25brdm PROPN eurjchem-1480 80 11 , , PUNCT eurjchem-1480 80 12 pl50brdm pl50brdm PROPN eurjchem-1480 80 13 and and CCONJ eurjchem-1480 80 14 pl100brdm pl100brdm PROPN eurjchem-1480 80 15 . . PROPN eurjchem-1480 80 16 table table NOUN eurjchem-1480 80 17 1 1 NUM eurjchem-1480 80 18 shows show VERB eurjchem-1480 80 19 the the DET eurjchem-1480 80 20 quantities quantity NOUN eurjchem-1480 80 21 of of ADP eurjchem-1480 80 22 reactants reactant NOUN eurjchem-1480 80 23 used use VERB eurjchem-1480 80 24 in in ADP eurjchem-1480 80 25 the the DET eurjchem-1480 80 26 preparation preparation NOUN eurjchem-1480 80 27 of of ADP eurjchem-1480 80 28 these these DET eurjchem-1480 80 29 copolymers copolymer NOUN eurjchem-1480 80 30 and and CCONJ eurjchem-1480 80 31 figure figure VERB eurjchem-1480 80 32 1 1 NUM eurjchem-1480 80 33 exhibits exhibit VERB eurjchem-1480 80 34 the the DET eurjchem-1480 80 35 chemical chemical ADJ eurjchem-1480 80 36 equations equation NOUN eurjchem-1480 80 37 of of ADP eurjchem-1480 80 38 the the DET eurjchem-1480 80 39 preparation preparation NOUN eurjchem-1480 80 40 method method NOUN eurjchem-1480 80 41 . . PUNCT eurjchem-1480 81 1 copolymer copolymer PROPN eurjchem-1480 81 2 pl10brdm pl10brdm PROPN eurjchem-1480 81 3 : : PUNCT eurjchem-1480 81 4 color color NOUN eurjchem-1480 81 5 : : PUNCT eurjchem-1480 81 6 light light ADJ eurjchem-1480 81 7 green green NOUN eurjchem-1480 81 8 . . PUNCT eurjchem-1480 82 1 yield yield NOUN eurjchem-1480 82 2 : : PUNCT eurjchem-1480 82 3 65 65 NUM eurjchem-1480 82 4 % % NOUN eurjchem-1480 82 5 . . PUNCT eurjchem-1480 83 1 ft‐ir ft‐ir NOUN eurjchem-1480 83 2 ( ( PUNCT eurjchem-1480 83 3 kbr kbr PROPN eurjchem-1480 83 4 , , PUNCT eurjchem-1480 83 5   PROPN eurjchem-1480 83 6 , , PUNCT eurjchem-1480 83 7 cm‐1 cm‐1 PROPN eurjchem-1480 83 8 ): ): PUNCT eurjchem-1480 83 9 1741 1741 NUM eurjchem-1480 83 10 ( ( PUNCT eurjchem-1480 83 11 c c NOUN eurjchem-1480 83 12 = = NOUN eurjchem-1480 83 13 o o NOUN eurjchem-1480 83 14 ) ) PUNCT eurjchem-1480 83 15 , , PUNCT eurjchem-1480 83 16 1133 1133 NUM eurjchem-1480 83 17 ( ( PUNCT eurjchem-1480 83 18 n‐c n‐c NUM eurjchem-1480 83 19 ) ) PUNCT eurjchem-1480 83 20 . . PUNCT eurjchem-1480 84 1 1h 1h NUM eurjchem-1480 84 2 nmr nmr NOUN eurjchem-1480 84 3 ( ( PUNCT eurjchem-1480 84 4 500 500 NUM eurjchem-1480 84 5 mhz mhz NOUN eurjchem-1480 84 6 , , PUNCT eurjchem-1480 84 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 84 8 , , PUNCT eurjchem-1480 84 9 δ δ PROPN eurjchem-1480 84 10 , , PUNCT eurjchem-1480 84 11 ppm ppm NOUN eurjchem-1480 84 12 ): ): PUNCT eurjchem-1480 84 13 5.19 5.19 NUM eurjchem-1480 84 14 ( ( PUNCT eurjchem-1480 84 15 o‐ch o‐ch ADJ eurjchem-1480 84 16 groups group NOUN eurjchem-1480 84 17 in in ADP eurjchem-1480 84 18 branched branched ADJ eurjchem-1480 84 19 part part NOUN eurjchem-1480 84 20 of of ADP eurjchem-1480 84 21 dmaema dmaema NOUN eurjchem-1480 84 22 ) ) PUNCT eurjchem-1480 84 23 , , PUNCT eurjchem-1480 84 24 4.2 4.2 NUM eurjchem-1480 84 25 ( ( PUNCT eurjchem-1480 84 26 o‐ch2 o‐ch2 PROPN eurjchem-1480 84 27 ) ) PUNCT eurjchem-1480 84 28 , , PUNCT eurjchem-1480 84 29 4.1 4.1 NUM eurjchem-1480 84 30 ( ( PUNCT eurjchem-1480 84 31 o‐ch2 o‐ch2 PROPN eurjchem-1480 84 32 ) ) PUNCT eurjchem-1480 84 33 , , PUNCT eurjchem-1480 84 34 3.4 3.4 NUM eurjchem-1480 84 35 ( ( PUNCT eurjchem-1480 84 36 n‐ch2 n‐ch2 NOUN eurjchem-1480 84 37 groups group NOUN eurjchem-1480 84 38 in in ADP eurjchem-1480 84 39 branched branched ADJ eurjchem-1480 84 40 part part NOUN eurjchem-1480 84 41 of of ADP eurjchem-1480 84 42 dmaema dmaema NOUN eurjchem-1480 84 43 ) ) PUNCT eurjchem-1480 84 44 , , PUNCT eurjchem-1480 84 45 2.9 2.9 NUM eurjchem-1480 84 46 ( ( PUNCT eurjchem-1480 84 47 n‐ch3 n‐ch3 ADJ eurjchem-1480 84 48 groups group NOUN eurjchem-1480 84 49 in in ADP eurjchem-1480 84 50 branched branched ADJ eurjchem-1480 84 51 part part NOUN eurjchem-1480 84 52 of of ADP eurjchem-1480 84 53 dmaema dmaema NOUN eurjchem-1480 84 54 ) ) PUNCT eurjchem-1480 84 55 , , PUNCT eurjchem-1480 84 56 2.7 2.7 NUM eurjchem-1480 84 57 ( ( PUNCT eurjchem-1480 84 58 ch2 ch2 NOUN eurjchem-1480 84 59 groups group NOUN eurjchem-1480 84 60 of of ADP eurjchem-1480 84 61 repeating repeat VERB eurjchem-1480 84 62 unit unit NOUN eurjchem-1480 84 63 of of ADP eurjchem-1480 84 64 dmaema dmaema NOUN eurjchem-1480 84 65 ) ) PUNCT eurjchem-1480 84 66 , , PUNCT eurjchem-1480 84 67 2.3 2.3 NUM eurjchem-1480 84 68 ( ( PUNCT eurjchem-1480 84 69 ch3 ch3 NOUN eurjchem-1480 84 70 groups group NOUN eurjchem-1480 84 71 of of ADP eurjchem-1480 84 72 repeating repeat VERB eurjchem-1480 84 73 unit unit NOUN eurjchem-1480 84 74 of of ADP eurjchem-1480 84 75 dmaema dmaema NOUN eurjchem-1480 84 76 ) ) PUNCT eurjchem-1480 84 77 , , PUNCT eurjchem-1480 84 78 1.45 1.45 NUM eurjchem-1480 84 79 ( ( PUNCT eurjchem-1480 84 80 o‐ch‐ch3 o‐ch‐ch3 NOUN eurjchem-1480 84 81 ) ) PUNCT eurjchem-1480 84 82 , , PUNCT eurjchem-1480 84 83 1.4 1.4 NUM eurjchem-1480 84 84 ( ( PUNCT eurjchem-1480 84 85 ch3 ch3 PROPN eurjchem-1480 84 86 ) ) PUNCT eurjchem-1480 84 87 . . PUNCT eurjchem-1480 85 1 al‐mayyahi al‐mayyahi NOUN eurjchem-1480 85 2 et et PROPN eurjchem-1480 85 3 al al PROPN eurjchem-1480 85 4 . . PUNCT eurjchem-1480 85 5 / / SYM eurjchem-1480 85 6 european european PROPN eurjchem-1480 85 7 journal journal PROPN eurjchem-1480 85 8 of of ADP eurjchem-1480 85 9 chemistry chemistry NOUN eurjchem-1480 85 10 7 7 NUM eurjchem-1480 85 11 ( ( PUNCT eurjchem-1480 85 12 4 4 NUM eurjchem-1480 85 13 ) ) PUNCT eurjchem-1480 85 14 ( ( PUNCT eurjchem-1480 85 15 2016 2016 NUM eurjchem-1480 85 16 ) ) PUNCT eurjchem-1480 85 17 405‐409 405‐409 NUM eurjchem-1480 85 18 407 407 NUM eurjchem-1480 85 19 table table NOUN eurjchem-1480 85 20 2 2 NUM eurjchem-1480 85 21 . . PUNCT eurjchem-1480 86 1 gpc gpc PROPN eurjchem-1480 86 2 results result VERB eurjchem-1480 86 3 for for ADP eurjchem-1480 86 4 prepared prepared ADJ eurjchem-1480 86 5 copolymers copolymer NOUN eurjchem-1480 86 6 . . PUNCT eurjchem-1480 87 1 no no DET eurjchem-1480 87 2 copolymer copolymer NOUN eurjchem-1480 87 3 value value NOUN eurjchem-1480 87 4 of of ADP eurjchem-1480 87 5 m m PROPN eurjchem-1480 87 6 mn mn PROPN eurjchem-1480 87 7 ( ( PUNCT eurjchem-1480 87 8 daltons dalton NOUN eurjchem-1480 87 9 ) ) PUNCT eurjchem-1480 87 10 mw mw PROPN eurjchem-1480 87 11 ( ( PUNCT eurjchem-1480 87 12 daltons dalton NOUN eurjchem-1480 87 13 ) ) PUNCT eurjchem-1480 87 14 polydispersity polydispersity NOUN eurjchem-1480 87 15 index index NOUN eurjchem-1480 87 16 ( ( PUNCT eurjchem-1480 87 17 pdi pdi PROPN eurjchem-1480 87 18 ) ) PUNCT eurjchem-1480 87 19 1 1 NUM eurjchem-1480 87 20 pl10brdm pl10brdm NOUN eurjchem-1480 87 21 13 13 NUM eurjchem-1480 87 22 11725 11725 NUM eurjchem-1480 87 23 12651 12651 NUM eurjchem-1480 87 24 1.08 1.08 NUM eurjchem-1480 87 25 2 2 NUM eurjchem-1480 87 26 pl25brdm pl25brdm NOUN eurjchem-1480 87 27 28 28 NUM eurjchem-1480 87 28 25475 25475 NUM eurjchem-1480 87 29 27339 27339 NUM eurjchem-1480 87 30 1.07 1.07 NUM eurjchem-1480 87 31 3 3 NUM eurjchem-1480 87 32 pl50brdm pl50brdm PROPN eurjchem-1480 87 33 57 57 NUM eurjchem-1480 87 34 50947 50947 NUM eurjchem-1480 87 35 58105 58105 NUM eurjchem-1480 87 36 1.14 1.14 NUM eurjchem-1480 87 37 4 4 NUM eurjchem-1480 87 38 pl100brdm pl100brdm NUM eurjchem-1480 87 39 115 115 NUM eurjchem-1480 87 40 101795 101795 NUM eurjchem-1480 87 41 110018 110018 NUM eurjchem-1480 87 42 1.08 1.08 NUM eurjchem-1480 87 43 table table NOUN eurjchem-1480 87 44 3 3 NUM eurjchem-1480 87 45 . . PUNCT eurjchem-1480 88 1 tga tga PROPN eurjchem-1480 88 2 data datum NOUN eurjchem-1480 88 3 for for ADP eurjchem-1480 88 4 prepared prepared ADJ eurjchem-1480 88 5 copolymers copolymer NOUN eurjchem-1480 88 6 pl10brdm pl10brdm PROPN eurjchem-1480 88 7 , , PUNCT eurjchem-1480 88 8 pl25brdm pl25brdm PROPN eurjchem-1480 88 9 , , PUNCT eurjchem-1480 88 10 pl50brdm pl50brdm PROPN eurjchem-1480 88 11 and and CCONJ eurjchem-1480 88 12 pl100brdm pl100brdm NOUN eurjchem-1480 88 13 . . PUNCT eurjchem-1480 89 1 copolymer copolymer NOUN eurjchem-1480 89 2 first first ADJ eurjchem-1480 89 3 decomposition decomposition NOUN eurjchem-1480 89 4 step step NOUN eurjchem-1480 89 5 ti ti NOUN eurjchem-1480 89 6 ( ( PUNCT eurjchem-1480 89 7 ° ° ADP eurjchem-1480 89 8 c c NOUN eurjchem-1480 89 9 ) ) PUNCT eurjchem-1480 89 10 tf tf X eurjchem-1480 89 11 ( ( PUNCT eurjchem-1480 89 12 ° ° ADP eurjchem-1480 89 13 c c NOUN eurjchem-1480 89 14 ) ) PUNCT eurjchem-1480 89 15 rate rate NOUN eurjchem-1480 89 16 of of ADP eurjchem-1480 89 17 decomposition decomposition NOUN eurjchem-1480 89 18 activation activation NOUN eurjchem-1480 89 19 energy energy NOUN eurjchem-1480 89 20 weight weight NOUN eurjchem-1480 89 21 loss loss NOUN eurjchem-1480 89 22 ( ( PUNCT eurjchem-1480 89 23 % % INTJ eurjchem-1480 89 24 ) ) PUNCT eurjchem-1480 89 25 pl10brdm pl10brdm NOUN eurjchem-1480 89 26 145.82 145.82 NUM eurjchem-1480 89 27 216.80 216.80 NUM eurjchem-1480 89 28 0.38 0.38 NUM eurjchem-1480 89 29 0.015 0.015 NUM eurjchem-1480 89 30 27.77 27.77 NUM eurjchem-1480 89 31 pl25brdm pl25brdm NOUN eurjchem-1480 89 32 158.33 158.33 NUM eurjchem-1480 89 33 241.70 241.70 NUM eurjchem-1480 89 34 0.37 0.37 NUM eurjchem-1480 89 35 0.020 0.020 NUM eurjchem-1480 89 36 24.95 24.95 NUM eurjchem-1480 89 37 pl50brdm pl50brdm PROPN eurjchem-1480 89 38 173.92 173.92 NUM eurjchem-1480 89 39 246.26 246.26 NUM eurjchem-1480 89 40 0.32 0.32 NUM eurjchem-1480 89 41 0.023 0.023 NUM eurjchem-1480 89 42 32.71 32.71 NUM eurjchem-1480 89 43 pl100brdm pl100brdm X eurjchem-1480 89 44 190.03 190.03 NUM eurjchem-1480 89 45 253.74 253.74 NUM eurjchem-1480 89 46 0.31 0.31 NUM eurjchem-1480 89 47 0.044 0.044 NUM eurjchem-1480 89 48 20.97 20.97 NUM eurjchem-1480 89 49 copolymer copolymer NOUN eurjchem-1480 89 50 second second ADJ eurjchem-1480 89 51 decomposition decomposition NOUN eurjchem-1480 89 52 step step NOUN eurjchem-1480 89 53 ti ti NOUN eurjchem-1480 89 54 ( ( PUNCT eurjchem-1480 89 55 ° ° ADP eurjchem-1480 89 56 c c NOUN eurjchem-1480 89 57 ) ) PUNCT eurjchem-1480 89 58 tf tf X eurjchem-1480 89 59 ( ( PUNCT eurjchem-1480 89 60 ° ° ADP eurjchem-1480 89 61 c c NOUN eurjchem-1480 89 62 ) ) PUNCT eurjchem-1480 89 63 rate rate NOUN eurjchem-1480 89 64 of of ADP eurjchem-1480 89 65 decomposition decomposition NOUN eurjchem-1480 89 66 activation activation NOUN eurjchem-1480 89 67 energy energy NOUN eurjchem-1480 89 68 residue residue NOUN eurjchem-1480 89 69 ( ( PUNCT eurjchem-1480 89 70 % % INTJ eurjchem-1480 89 71 ) ) PUNCT eurjchem-1480 89 72 t50 t50 PROPN eurjchem-1480 89 73 ( ( PUNCT eurjchem-1480 89 74 ° ° ADP eurjchem-1480 89 75 c c NOUN eurjchem-1480 89 76 ) ) PUNCT eurjchem-1480 89 77 pl10brdm pl10brdm NOUN eurjchem-1480 89 78 289.74 289.74 NUM eurjchem-1480 89 79 356.11 356.11 NUM eurjchem-1480 89 80 0.67 0.67 NUM eurjchem-1480 89 81 0.016 0.016 NUM eurjchem-1480 89 82 18.39 18.39 NUM eurjchem-1480 89 83 294.05 294.05 NUM eurjchem-1480 89 84 pl25brdm pl25brdm NOUN eurjchem-1480 89 85 295.37 295.37 NUM eurjchem-1480 89 86 375.75 375.75 NUM eurjchem-1480 89 87 0.65 0.65 NUM eurjchem-1480 89 88 0.018 0.018 NUM eurjchem-1480 89 89 17.21 17.21 NUM eurjchem-1480 89 90 296.43 296.43 NUM eurjchem-1480 89 91 pl50brdm pl50brdm PROPN eurjchem-1480 89 92 291.71 291.71 NUM eurjchem-1480 89 93 388.38 388.38 NUM eurjchem-1480 89 94 0.63 0.63 NUM eurjchem-1480 89 95 0.021 0.021 NUM eurjchem-1480 89 96 19.09 19.09 NUM eurjchem-1480 89 97 292.32 292.32 NUM eurjchem-1480 89 98 pl100brdm pl100brdm PROPN eurjchem-1480 89 99 306.03 306.03 NUM eurjchem-1480 89 100 384.04 384.04 NUM eurjchem-1480 89 101 0.51 0.51 NUM eurjchem-1480 89 102 0.033 0.033 NUM eurjchem-1480 89 103 14.86 14.86 NUM eurjchem-1480 89 104 315.48 315.48 NUM eurjchem-1480 89 105 13c 13c NOUN eurjchem-1480 89 106 nmr nmr NOUN eurjchem-1480 89 107 ( ( PUNCT eurjchem-1480 89 108 500 500 NUM eurjchem-1480 89 109 mhz mhz NOUN eurjchem-1480 89 110 , , PUNCT eurjchem-1480 89 111 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 89 112 , , PUNCT eurjchem-1480 89 113 δ δ PROPN eurjchem-1480 89 114 , , PUNCT eurjchem-1480 89 115 ppm ppm NOUN eurjchem-1480 89 116 ): ): PUNCT eurjchem-1480 89 117 178 178 NUM eurjchem-1480 89 118 ( ( PUNCT eurjchem-1480 89 119 c c NOUN eurjchem-1480 89 120 = = NOUN eurjchem-1480 89 121 o o NOUN eurjchem-1480 89 122 ) ) PUNCT eurjchem-1480 89 123 , , PUNCT eurjchem-1480 89 124 174 174 NUM eurjchem-1480 89 125 ( ( PUNCT eurjchem-1480 89 126 c c NOUN eurjchem-1480 89 127 = = NOUN eurjchem-1480 89 128 o o NOUN eurjchem-1480 89 129 ) ) PUNCT eurjchem-1480 89 130 , , PUNCT eurjchem-1480 89 131 170 170 NUM eurjchem-1480 89 132 ( ( PUNCT eurjchem-1480 89 133 c c NOUN eurjchem-1480 89 134 = = NOUN eurjchem-1480 89 135 o o NOUN eurjchem-1480 89 136 ) ) PUNCT eurjchem-1480 89 137 , , PUNCT eurjchem-1480 89 138 69 69 NUM eurjchem-1480 89 139 ( ( PUNCT eurjchem-1480 89 140 ch‐o ch‐o PROPN eurjchem-1480 89 141 ) ) PUNCT eurjchem-1480 89 142 , , PUNCT eurjchem-1480 89 143 63 63 NUM eurjchem-1480 89 144 ( ( PUNCT eurjchem-1480 89 145 ch2‐o ch2‐o NOUN eurjchem-1480 89 146 ) ) PUNCT eurjchem-1480 89 147 , , PUNCT eurjchem-1480 89 148 59 59 NUM eurjchem-1480 89 149 ( ( PUNCT eurjchem-1480 89 150 ch2‐o ch2‐o NOUN eurjchem-1480 89 151 ) ) PUNCT eurjchem-1480 89 152 , , PUNCT eurjchem-1480 89 153 56 56 NUM eurjchem-1480 89 154 ( ( PUNCT eurjchem-1480 89 155 c‐ c‐ NOUN eurjchem-1480 89 156 quat quat NOUN eurjchem-1480 89 157 . . PUNCT eurjchem-1480 89 158 ) ) PUNCT eurjchem-1480 89 159 , , PUNCT eurjchem-1480 89 160 50 50 NUM eurjchem-1480 89 161 ( ( PUNCT eurjchem-1480 89 162 ch2 ch2 PROPN eurjchem-1480 89 163 ) ) PUNCT eurjchem-1480 89 164 , , PUNCT eurjchem-1480 89 165 47 47 NUM eurjchem-1480 89 166 ( ( PUNCT eurjchem-1480 89 167 ch3‐n ch3‐n PROPN eurjchem-1480 89 168 ) ) PUNCT eurjchem-1480 89 169 , , PUNCT eurjchem-1480 89 170 44 44 NUM eurjchem-1480 89 171 ( ( PUNCT eurjchem-1480 89 172 c‐quat c‐quat X eurjchem-1480 89 173 . . PUNCT eurjchem-1480 89 174 ) ) PUNCT eurjchem-1480 89 175 , , PUNCT eurjchem-1480 89 176 32 32 NUM eurjchem-1480 89 177 ( ( PUNCT eurjchem-1480 89 178 ch3 ch3 PROPN eurjchem-1480 89 179 ) ) PUNCT eurjchem-1480 89 180 , , PUNCT eurjchem-1480 89 181 20 20 NUM eurjchem-1480 89 182 ( ( PUNCT eurjchem-1480 89 183 ch3 ch3 PROPN eurjchem-1480 89 184 ) ) PUNCT eurjchem-1480 89 185 , , PUNCT eurjchem-1480 89 186 17 17 NUM eurjchem-1480 89 187 ( ( PUNCT eurjchem-1480 89 188 ch3 ch3 PROPN eurjchem-1480 89 189 ) ) PUNCT eurjchem-1480 89 190 . . PUNCT eurjchem-1480 90 1 copolymer copolymer PROPN eurjchem-1480 90 2 pl25brdm pl25brdm NOUN eurjchem-1480 90 3 : : PUNCT eurjchem-1480 90 4 color color NOUN eurjchem-1480 90 5 : : PUNCT eurjchem-1480 90 6 light light ADJ eurjchem-1480 90 7 green green NOUN eurjchem-1480 90 8 . . PUNCT eurjchem-1480 91 1 yield yield NOUN eurjchem-1480 91 2 : : PUNCT eurjchem-1480 91 3 67 67 NUM eurjchem-1480 91 4 % % NOUN eurjchem-1480 91 5 . . PUNCT eurjchem-1480 92 1 ft‐ir ft‐ir NOUN eurjchem-1480 92 2 ( ( PUNCT eurjchem-1480 92 3 kbr kbr PROPN eurjchem-1480 92 4 , , PUNCT eurjchem-1480 92 5   PROPN eurjchem-1480 92 6 , , PUNCT eurjchem-1480 92 7 cm‐1 cm‐1 PROPN eurjchem-1480 92 8 ): ): PUNCT eurjchem-1480 92 9 1746 1746 NUM eurjchem-1480 92 10 ( ( PUNCT eurjchem-1480 92 11 c c NOUN eurjchem-1480 92 12 = = NOUN eurjchem-1480 92 13 o o NOUN eurjchem-1480 92 14 ) ) PUNCT eurjchem-1480 92 15 , , PUNCT eurjchem-1480 92 16 1134 1134 NUM eurjchem-1480 92 17 ( ( PUNCT eurjchem-1480 92 18 n‐c n‐c NUM eurjchem-1480 92 19 ) ) PUNCT eurjchem-1480 92 20 . . PUNCT eurjchem-1480 93 1 1h 1h NUM eurjchem-1480 93 2 nmr nmr NOUN eurjchem-1480 93 3 ( ( PUNCT eurjchem-1480 93 4 500 500 NUM eurjchem-1480 93 5 mhz mhz NOUN eurjchem-1480 93 6 , , PUNCT eurjchem-1480 93 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 93 8 , , PUNCT eurjchem-1480 93 9 δ δ PROPN eurjchem-1480 93 10 , , PUNCT eurjchem-1480 93 11 ppm ppm NUM eurjchem-1480 93 12 ): ): PUNCT eurjchem-1480 93 13 5.2 5.2 NUM eurjchem-1480 93 14 ( ( PUNCT eurjchem-1480 93 15 o‐ch o‐ch ADJ eurjchem-1480 93 16 groups group NOUN eurjchem-1480 93 17 in in ADP eurjchem-1480 93 18 branched branched ADJ eurjchem-1480 93 19 part part NOUN eurjchem-1480 93 20 of of ADP eurjchem-1480 93 21 dmaema dmaema NOUN eurjchem-1480 93 22 ) ) PUNCT eurjchem-1480 93 23 , , PUNCT eurjchem-1480 93 24 4.2 4.2 NUM eurjchem-1480 93 25 ( ( PUNCT eurjchem-1480 93 26 o‐ch2 o‐ch2 PROPN eurjchem-1480 93 27 ) ) PUNCT eurjchem-1480 93 28 , , PUNCT eurjchem-1480 93 29 4 4 NUM eurjchem-1480 93 30 ( ( PUNCT eurjchem-1480 93 31 o‐ch2 o‐ch2 PROPN eurjchem-1480 93 32 ) ) PUNCT eurjchem-1480 93 33 , , PUNCT eurjchem-1480 93 34 3.35 3.35 NUM eurjchem-1480 93 35 ( ( PUNCT eurjchem-1480 93 36 n‐ch2 n‐ch2 NOUN eurjchem-1480 93 37 groups group NOUN eurjchem-1480 93 38 in in ADP eurjchem-1480 93 39 branched branched ADJ eurjchem-1480 93 40 part part NOUN eurjchem-1480 93 41 of of ADP eurjchem-1480 93 42 dmaema dmaema NOUN eurjchem-1480 93 43 ) ) PUNCT eurjchem-1480 93 44 , , PUNCT eurjchem-1480 93 45 2.88 2.88 NUM eurjchem-1480 93 46 ( ( PUNCT eurjchem-1480 93 47 n‐ch3 n‐ch3 ADJ eurjchem-1480 93 48 groups group NOUN eurjchem-1480 93 49 in in ADP eurjchem-1480 93 50 branched branched ADJ eurjchem-1480 93 51 part part NOUN eurjchem-1480 93 52 of of ADP eurjchem-1480 93 53 dmaema dmaema NOUN eurjchem-1480 93 54 ) ) PUNCT eurjchem-1480 93 55 , , PUNCT eurjchem-1480 93 56 2.71 2.71 NUM eurjchem-1480 93 57 ( ( PUNCT eurjchem-1480 93 58 ch2 ch2 NOUN eurjchem-1480 93 59 groups group NOUN eurjchem-1480 93 60 of of ADP eurjchem-1480 93 61 repeating repeat VERB eurjchem-1480 93 62 unit unit NOUN eurjchem-1480 93 63 of of ADP eurjchem-1480 93 64 dmaema dmaema NOUN eurjchem-1480 93 65 ) ) PUNCT eurjchem-1480 93 66 , , PUNCT eurjchem-1480 93 67 2.25 2.25 NUM eurjchem-1480 93 68 ( ( PUNCT eurjchem-1480 93 69 ch3 ch3 NOUN eurjchem-1480 93 70 groups group NOUN eurjchem-1480 93 71 of of ADP eurjchem-1480 93 72 repeating repeat VERB eurjchem-1480 93 73 unit unit NOUN eurjchem-1480 93 74 of of ADP eurjchem-1480 93 75 dmaema dmaema NOUN eurjchem-1480 93 76 ) ) PUNCT eurjchem-1480 93 77 , , PUNCT eurjchem-1480 93 78 1.45 1.45 NUM eurjchem-1480 93 79 ( ( PUNCT eurjchem-1480 93 80 o‐ch‐ch3 o‐ch‐ch3 ADJ eurjchem-1480 93 81 ) ) PUNCT eurjchem-1480 93 82 , , PUNCT eurjchem-1480 93 83 1.41 1.41 NUM eurjchem-1480 93 84 ( ( PUNCT eurjchem-1480 93 85 ch3 ch3 PROPN eurjchem-1480 93 86 ) ) PUNCT eurjchem-1480 93 87 . . PUNCT eurjchem-1480 94 1 13c 13c NOUN eurjchem-1480 94 2 nmr nmr NOUN eurjchem-1480 94 3 ( ( PUNCT eurjchem-1480 94 4 500 500 NUM eurjchem-1480 94 5 mhz mhz NOUN eurjchem-1480 94 6 , , PUNCT eurjchem-1480 94 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 94 8 , , PUNCT eurjchem-1480 94 9 δ δ PROPN eurjchem-1480 94 10 , , PUNCT eurjchem-1480 94 11 ppm ppm NUM eurjchem-1480 94 12 ): ): PUNCT eurjchem-1480 94 13 177 177 NUM eurjchem-1480 94 14 ( ( PUNCT eurjchem-1480 94 15 c c NOUN eurjchem-1480 94 16 = = NOUN eurjchem-1480 94 17 o o NOUN eurjchem-1480 94 18 ) ) PUNCT eurjchem-1480 94 19 , , PUNCT eurjchem-1480 94 20 174 174 NUM eurjchem-1480 94 21 ( ( PUNCT eurjchem-1480 94 22 c c NOUN eurjchem-1480 94 23 = = NOUN eurjchem-1480 94 24 o o NOUN eurjchem-1480 94 25 ) ) PUNCT eurjchem-1480 94 26 , , PUNCT eurjchem-1480 94 27 170 170 NUM eurjchem-1480 94 28 ( ( PUNCT eurjchem-1480 94 29 c c NOUN eurjchem-1480 94 30 = = NOUN eurjchem-1480 94 31 o o NOUN eurjchem-1480 94 32 ) ) PUNCT eurjchem-1480 94 33 , , PUNCT eurjchem-1480 94 34 70 70 NUM eurjchem-1480 94 35 ( ( PUNCT eurjchem-1480 94 36 ch‐o ch‐o PROPN eurjchem-1480 94 37 ) ) PUNCT eurjchem-1480 94 38 , , PUNCT eurjchem-1480 94 39 62 62 NUM eurjchem-1480 94 40 ( ( PUNCT eurjchem-1480 94 41 ch2‐ ch2‐ NOUN eurjchem-1480 94 42 o o NOUN eurjchem-1480 94 43 ) ) PUNCT eurjchem-1480 94 44 , , PUNCT eurjchem-1480 94 45 60 60 NUM eurjchem-1480 94 46 ( ( PUNCT eurjchem-1480 94 47 ch2‐o ch2‐o NOUN eurjchem-1480 94 48 ) ) PUNCT eurjchem-1480 94 49 , , PUNCT eurjchem-1480 94 50 58 58 NUM eurjchem-1480 94 51 ( ( PUNCT eurjchem-1480 94 52 c‐quat c‐quat X eurjchem-1480 94 53 . . PUNCT eurjchem-1480 94 54 ) ) PUNCT eurjchem-1480 94 55 , , PUNCT eurjchem-1480 94 56 50 50 NUM eurjchem-1480 94 57 ( ( PUNCT eurjchem-1480 94 58 ch2 ch2 PROPN eurjchem-1480 94 59 ) ) PUNCT eurjchem-1480 94 60 , , PUNCT eurjchem-1480 94 61 48(ch3‐n 48(ch3‐n X eurjchem-1480 94 62 ) ) PUNCT eurjchem-1480 94 63 , , PUNCT eurjchem-1480 94 64 44 44 NUM eurjchem-1480 94 65 ( ( PUNCT eurjchem-1480 94 66 c‐quat c‐quat X eurjchem-1480 94 67 . . PUNCT eurjchem-1480 94 68 ) ) PUNCT eurjchem-1480 94 69 , , PUNCT eurjchem-1480 94 70 30 30 NUM eurjchem-1480 94 71 ( ( PUNCT eurjchem-1480 94 72 ch3 ch3 PROPN eurjchem-1480 94 73 ) ) PUNCT eurjchem-1480 94 74 , , PUNCT eurjchem-1480 94 75 22 22 NUM eurjchem-1480 94 76 ( ( PUNCT eurjchem-1480 94 77 ch3 ch3 PROPN eurjchem-1480 94 78 ) ) PUNCT eurjchem-1480 94 79 , , PUNCT eurjchem-1480 94 80 17 17 NUM eurjchem-1480 94 81 ( ( PUNCT eurjchem-1480 94 82 ch3 ch3 PROPN eurjchem-1480 94 83 ) ) PUNCT eurjchem-1480 94 84 . . PUNCT eurjchem-1480 95 1 copolymer copolymer NOUN eurjchem-1480 95 2 pl50brdm pl50brdm PROPN eurjchem-1480 95 3 : : PUNCT eurjchem-1480 95 4 color color NOUN eurjchem-1480 95 5 : : PUNCT eurjchem-1480 95 6 light light ADJ eurjchem-1480 95 7 green green NOUN eurjchem-1480 95 8 . . PUNCT eurjchem-1480 96 1 yield yield NOUN eurjchem-1480 96 2 : : PUNCT eurjchem-1480 96 3 71 71 NUM eurjchem-1480 96 4 % % NOUN eurjchem-1480 96 5 . . PUNCT eurjchem-1480 97 1 ft‐ir ft‐ir NOUN eurjchem-1480 97 2 ( ( PUNCT eurjchem-1480 97 3 kbr kbr PROPN eurjchem-1480 97 4 , , PUNCT eurjchem-1480 97 5   PROPN eurjchem-1480 97 6 , , PUNCT eurjchem-1480 97 7 cm‐1 cm‐1 PROPN eurjchem-1480 97 8 ): ): PUNCT eurjchem-1480 97 9 1751 1751 NUM eurjchem-1480 97 10 ( ( PUNCT eurjchem-1480 97 11 c c NOUN eurjchem-1480 97 12 = = NOUN eurjchem-1480 97 13 o o NOUN eurjchem-1480 97 14 ) ) PUNCT eurjchem-1480 97 15 , , PUNCT eurjchem-1480 97 16 1136 1136 NUM eurjchem-1480 97 17 ( ( PUNCT eurjchem-1480 97 18 n‐c n‐c NUM eurjchem-1480 97 19 ) ) PUNCT eurjchem-1480 97 20 . . PUNCT eurjchem-1480 98 1 1h 1h NUM eurjchem-1480 98 2 nmr nmr NOUN eurjchem-1480 98 3 ( ( PUNCT eurjchem-1480 98 4 500 500 NUM eurjchem-1480 98 5 mhz mhz NOUN eurjchem-1480 98 6 , , PUNCT eurjchem-1480 98 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 98 8 , , PUNCT eurjchem-1480 98 9 δ δ PROPN eurjchem-1480 98 10 , , PUNCT eurjchem-1480 98 11 ppm ppm NUM eurjchem-1480 98 12 ): ): PUNCT eurjchem-1480 98 13 5.2 5.2 NUM eurjchem-1480 98 14 ( ( PUNCT eurjchem-1480 98 15 o‐ch o‐ch ADJ eurjchem-1480 98 16 groups group NOUN eurjchem-1480 98 17 in in ADP eurjchem-1480 98 18 branched branched ADJ eurjchem-1480 98 19 part part NOUN eurjchem-1480 98 20 of of ADP eurjchem-1480 98 21 dmaema dmaema NOUN eurjchem-1480 98 22 ) ) PUNCT eurjchem-1480 98 23 , , PUNCT eurjchem-1480 98 24 4.19 4.19 NUM eurjchem-1480 98 25 ( ( PUNCT eurjchem-1480 98 26 o‐ch2 o‐ch2 PROPN eurjchem-1480 98 27 ) ) PUNCT eurjchem-1480 98 28 , , PUNCT eurjchem-1480 98 29 4.0 4.0 NUM eurjchem-1480 98 30 ( ( PUNCT eurjchem-1480 98 31 o‐ch2 o‐ch2 PROPN eurjchem-1480 98 32 ) ) PUNCT eurjchem-1480 98 33 , , PUNCT eurjchem-1480 98 34 3.36 3.36 NUM eurjchem-1480 98 35 ( ( PUNCT eurjchem-1480 98 36 n‐ch2 n‐ch2 NOUN eurjchem-1480 98 37 groups group NOUN eurjchem-1480 98 38 in in ADP eurjchem-1480 98 39 branched branched ADJ eurjchem-1480 98 40 part part NOUN eurjchem-1480 98 41 of of ADP eurjchem-1480 98 42 dmaema dmaema NOUN eurjchem-1480 98 43 ) ) PUNCT eurjchem-1480 98 44 , , PUNCT eurjchem-1480 98 45 2.86 2.86 NUM eurjchem-1480 98 46 ( ( PUNCT eurjchem-1480 98 47 n‐ch3 n‐ch3 ADJ eurjchem-1480 98 48 groups group NOUN eurjchem-1480 98 49 in in ADP eurjchem-1480 98 50 branched branched ADJ eurjchem-1480 98 51 part part NOUN eurjchem-1480 98 52 of of ADP eurjchem-1480 98 53 dmaema dmaema NOUN eurjchem-1480 98 54 ) ) PUNCT eurjchem-1480 98 55 , , PUNCT eurjchem-1480 98 56 2.71 2.71 NUM eurjchem-1480 98 57 ( ( PUNCT eurjchem-1480 98 58 ch2 ch2 NOUN eurjchem-1480 98 59 groups group NOUN eurjchem-1480 98 60 of of ADP eurjchem-1480 98 61 repeating repeat VERB eurjchem-1480 98 62 unit unit NOUN eurjchem-1480 98 63 of of ADP eurjchem-1480 98 64 dmaema dmaema NOUN eurjchem-1480 98 65 ) ) PUNCT eurjchem-1480 98 66 , , PUNCT eurjchem-1480 98 67 2.24 2.24 NUM eurjchem-1480 98 68 ( ( PUNCT eurjchem-1480 98 69 ch3 ch3 NOUN eurjchem-1480 98 70 groups group NOUN eurjchem-1480 98 71 of of ADP eurjchem-1480 98 72 repeating repeat VERB eurjchem-1480 98 73 unit unit NOUN eurjchem-1480 98 74 of of ADP eurjchem-1480 98 75 dmaema dmaema NOUN eurjchem-1480 98 76 ) ) PUNCT eurjchem-1480 98 77 , , PUNCT eurjchem-1480 98 78 1.44 1.44 NUM eurjchem-1480 98 79 ( ( PUNCT eurjchem-1480 98 80 o‐ch‐ch3 o‐ch‐ch3 PROPN eurjchem-1480 98 81 ) ) PUNCT eurjchem-1480 98 82 , , PUNCT eurjchem-1480 98 83 1.41 1.41 NUM eurjchem-1480 98 84 ( ( PUNCT eurjchem-1480 98 85 ch3 ch3 PROPN eurjchem-1480 98 86 ) ) PUNCT eurjchem-1480 98 87 . . PUNCT eurjchem-1480 99 1 13c 13c NOUN eurjchem-1480 99 2 nmr nmr NOUN eurjchem-1480 99 3 ( ( PUNCT eurjchem-1480 99 4 500 500 NUM eurjchem-1480 99 5 mhz mhz NOUN eurjchem-1480 99 6 , , PUNCT eurjchem-1480 99 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 99 8 , , PUNCT eurjchem-1480 99 9 δ δ PROPN eurjchem-1480 99 10 , , PUNCT eurjchem-1480 99 11 ppm ppm NOUN eurjchem-1480 99 12 ): ): PUNCT eurjchem-1480 99 13 176 176 NUM eurjchem-1480 99 14 ( ( PUNCT eurjchem-1480 99 15 c c NOUN eurjchem-1480 99 16 = = NOUN eurjchem-1480 99 17 o o NOUN eurjchem-1480 99 18 ) ) PUNCT eurjchem-1480 99 19 , , PUNCT eurjchem-1480 99 20 174 174 NUM eurjchem-1480 99 21 ( ( PUNCT eurjchem-1480 99 22 c c NOUN eurjchem-1480 99 23 = = NOUN eurjchem-1480 99 24 o o NOUN eurjchem-1480 99 25 ) ) PUNCT eurjchem-1480 99 26 , , PUNCT eurjchem-1480 99 27 170 170 NUM eurjchem-1480 99 28 ( ( PUNCT eurjchem-1480 99 29 c c NOUN eurjchem-1480 99 30 = = NOUN eurjchem-1480 99 31 o o NOUN eurjchem-1480 99 32 ) ) PUNCT eurjchem-1480 99 33 , , PUNCT eurjchem-1480 99 34 69 69 NUM eurjchem-1480 99 35 ( ( PUNCT eurjchem-1480 99 36 ch‐o ch‐o PROPN eurjchem-1480 99 37 ) ) PUNCT eurjchem-1480 99 38 , , PUNCT eurjchem-1480 99 39 64 64 NUM eurjchem-1480 99 40 ( ( PUNCT eurjchem-1480 99 41 ch2‐ ch2‐ NOUN eurjchem-1480 99 42 o o NOUN eurjchem-1480 99 43 ) ) PUNCT eurjchem-1480 99 44 , , PUNCT eurjchem-1480 99 45 62 62 NUM eurjchem-1480 99 46 ( ( PUNCT eurjchem-1480 99 47 ch2‐o ch2‐o NOUN eurjchem-1480 99 48 ) ) PUNCT eurjchem-1480 99 49 , , PUNCT eurjchem-1480 99 50 58 58 NUM eurjchem-1480 99 51 ( ( PUNCT eurjchem-1480 99 52 c‐quat c‐quat X eurjchem-1480 99 53 . . PUNCT eurjchem-1480 99 54 ) ) PUNCT eurjchem-1480 99 55 , , PUNCT eurjchem-1480 99 56 54 54 NUM eurjchem-1480 99 57 ( ( PUNCT eurjchem-1480 99 58 ch2 ch2 PROPN eurjchem-1480 99 59 ) ) PUNCT eurjchem-1480 99 60 , , PUNCT eurjchem-1480 99 61 50 50 NUM eurjchem-1480 99 62 ( ( PUNCT eurjchem-1480 99 63 ch3‐n ch3‐n PROPN eurjchem-1480 99 64 ) ) PUNCT eurjchem-1480 99 65 , , PUNCT eurjchem-1480 99 66 44 44 NUM eurjchem-1480 99 67 ( ( PUNCT eurjchem-1480 99 68 c‐quat c‐quat X eurjchem-1480 99 69 . . PUNCT eurjchem-1480 99 70 ) ) PUNCT eurjchem-1480 99 71 , , PUNCT eurjchem-1480 99 72 32 32 NUM eurjchem-1480 99 73 ( ( PUNCT eurjchem-1480 99 74 ch3 ch3 PROPN eurjchem-1480 99 75 ) ) PUNCT eurjchem-1480 99 76 , , PUNCT eurjchem-1480 99 77 20 20 NUM eurjchem-1480 99 78 ( ( PUNCT eurjchem-1480 99 79 ch3 ch3 PROPN eurjchem-1480 99 80 ) ) PUNCT eurjchem-1480 99 81 , , PUNCT eurjchem-1480 99 82 16 16 NUM eurjchem-1480 99 83 ( ( PUNCT eurjchem-1480 99 84 ch3 ch3 PROPN eurjchem-1480 99 85 ) ) PUNCT eurjchem-1480 99 86 . . PUNCT eurjchem-1480 100 1 copolymer copolymer NOUN eurjchem-1480 100 2 pl100brdm pl100brdm PROPN eurjchem-1480 100 3 : : PUNCT eurjchem-1480 100 4 color color NOUN eurjchem-1480 100 5 : : PUNCT eurjchem-1480 100 6 light light ADJ eurjchem-1480 100 7 green green NOUN eurjchem-1480 100 8 . . PUNCT eurjchem-1480 101 1 yield yield NOUN eurjchem-1480 101 2 : : PUNCT eurjchem-1480 101 3 69 69 NUM eurjchem-1480 101 4 % % NOUN eurjchem-1480 101 5 . . PUNCT eurjchem-1480 102 1 ft‐ir ft‐ir NOUN eurjchem-1480 102 2 ( ( PUNCT eurjchem-1480 102 3 kbr kbr PROPN eurjchem-1480 102 4 , , PUNCT eurjchem-1480 102 5   PROPN eurjchem-1480 102 6 , , PUNCT eurjchem-1480 102 7 cm‐1 cm‐1 PROPN eurjchem-1480 102 8 ): ): PUNCT eurjchem-1480 102 9 1745 1745 NUM eurjchem-1480 102 10 ( ( PUNCT eurjchem-1480 102 11 c c NOUN eurjchem-1480 102 12 = = NOUN eurjchem-1480 102 13 o o NOUN eurjchem-1480 102 14 ) ) PUNCT eurjchem-1480 102 15 , , PUNCT eurjchem-1480 102 16 1133 1133 NUM eurjchem-1480 102 17 ( ( PUNCT eurjchem-1480 102 18 n‐c n‐c NUM eurjchem-1480 102 19 ) ) PUNCT eurjchem-1480 102 20 . . PUNCT eurjchem-1480 103 1 1h 1h NUM eurjchem-1480 103 2 nmr nmr NOUN eurjchem-1480 103 3 ( ( PUNCT eurjchem-1480 103 4 500 500 NUM eurjchem-1480 103 5 mhz mhz NOUN eurjchem-1480 103 6 , , PUNCT eurjchem-1480 103 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 103 8 , , PUNCT eurjchem-1480 103 9 δ δ PROPN eurjchem-1480 103 10 , , PUNCT eurjchem-1480 103 11 ppm ppm NOUN eurjchem-1480 103 12 ): ): PUNCT eurjchem-1480 103 13 5.19 5.19 NUM eurjchem-1480 103 14 ( ( PUNCT eurjchem-1480 103 15 o‐ch o‐ch ADJ eurjchem-1480 103 16 groups group NOUN eurjchem-1480 103 17 in in ADP eurjchem-1480 103 18 branched branched ADJ eurjchem-1480 103 19 part part NOUN eurjchem-1480 103 20 of of ADP eurjchem-1480 103 21 dmaema dmaema NOUN eurjchem-1480 103 22 ) ) PUNCT eurjchem-1480 103 23 , , PUNCT eurjchem-1480 103 24 4.19 4.19 NUM eurjchem-1480 103 25 ( ( PUNCT eurjchem-1480 103 26 o‐ch2 o‐ch2 PROPN eurjchem-1480 103 27 ) ) PUNCT eurjchem-1480 103 28 , , PUNCT eurjchem-1480 103 29 4.1 4.1 NUM eurjchem-1480 103 30 ( ( PUNCT eurjchem-1480 103 31 o‐ch2 o‐ch2 PROPN eurjchem-1480 103 32 ) ) PUNCT eurjchem-1480 103 33 , , PUNCT eurjchem-1480 103 34 3.34 3.34 NUM eurjchem-1480 103 35 ( ( PUNCT eurjchem-1480 103 36 n‐ch2 n‐ch2 NOUN eurjchem-1480 103 37 groups group NOUN eurjchem-1480 103 38 in in ADP eurjchem-1480 103 39 branched branched ADJ eurjchem-1480 103 40 part part NOUN eurjchem-1480 103 41 of of ADP eurjchem-1480 103 42 dmaema dmaema NOUN eurjchem-1480 103 43 ) ) PUNCT eurjchem-1480 103 44 , , PUNCT eurjchem-1480 103 45 2.86 2.86 NUM eurjchem-1480 103 46 ( ( PUNCT eurjchem-1480 103 47 n‐ch3 n‐ch3 ADJ eurjchem-1480 103 48 groups group NOUN eurjchem-1480 103 49 in in ADP eurjchem-1480 103 50 branched branched ADJ eurjchem-1480 103 51 part part NOUN eurjchem-1480 103 52 of of ADP eurjchem-1480 103 53 dmaema dmaema NOUN eurjchem-1480 103 54 ) ) PUNCT eurjchem-1480 103 55 , , PUNCT eurjchem-1480 103 56 2.72 2.72 NUM eurjchem-1480 103 57 ( ( PUNCT eurjchem-1480 103 58 ch2 ch2 NOUN eurjchem-1480 103 59 groups group NOUN eurjchem-1480 103 60 of of ADP eurjchem-1480 103 61 repeating repeat VERB eurjchem-1480 103 62 unit unit NOUN eurjchem-1480 103 63 of of ADP eurjchem-1480 103 64 dmaema dmaema NOUN eurjchem-1480 103 65 ) ) PUNCT eurjchem-1480 103 66 , , PUNCT eurjchem-1480 103 67 2.26 2.26 NUM eurjchem-1480 103 68 ( ( PUNCT eurjchem-1480 103 69 ch3 ch3 NOUN eurjchem-1480 103 70 groups group NOUN eurjchem-1480 103 71 of of ADP eurjchem-1480 103 72 repeating repeat VERB eurjchem-1480 103 73 unit unit NOUN eurjchem-1480 103 74 of of ADP eurjchem-1480 103 75 dmaema dmaema NOUN eurjchem-1480 103 76 ) ) PUNCT eurjchem-1480 103 77 , , PUNCT eurjchem-1480 103 78 1.45 1.45 NUM eurjchem-1480 103 79 ( ( PUNCT eurjchem-1480 103 80 o‐ch‐ch3 o‐ch‐ch3 ADJ eurjchem-1480 103 81 ) ) PUNCT eurjchem-1480 103 82 , , PUNCT eurjchem-1480 103 83 1.41 1.41 NUM eurjchem-1480 103 84 ( ( PUNCT eurjchem-1480 103 85 ch3 ch3 PROPN eurjchem-1480 103 86 ) ) PUNCT eurjchem-1480 103 87 . . PUNCT eurjchem-1480 104 1 13c 13c NOUN eurjchem-1480 104 2 nmr nmr NOUN eurjchem-1480 104 3 ( ( PUNCT eurjchem-1480 104 4 500 500 NUM eurjchem-1480 104 5 mhz mhz NOUN eurjchem-1480 104 6 , , PUNCT eurjchem-1480 104 7 dmso‐d6 dmso‐d6 PROPN eurjchem-1480 104 8 , , PUNCT eurjchem-1480 104 9 δ δ PROPN eurjchem-1480 104 10 , , PUNCT eurjchem-1480 104 11 ppm ppm NUM eurjchem-1480 104 12 ): ): PUNCT eurjchem-1480 104 13 175 175 NUM eurjchem-1480 104 14 ( ( PUNCT eurjchem-1480 104 15 c c NOUN eurjchem-1480 104 16 = = NOUN eurjchem-1480 104 17 o o NOUN eurjchem-1480 104 18 ) ) PUNCT eurjchem-1480 104 19 , , PUNCT eurjchem-1480 104 20 174 174 NUM eurjchem-1480 104 21 ( ( PUNCT eurjchem-1480 104 22 c c NOUN eurjchem-1480 104 23 = = NOUN eurjchem-1480 104 24 o o NOUN eurjchem-1480 104 25 ) ) PUNCT eurjchem-1480 104 26 , , PUNCT eurjchem-1480 104 27 169 169 NUM eurjchem-1480 104 28 ( ( PUNCT eurjchem-1480 104 29 c c NOUN eurjchem-1480 104 30 = = NOUN eurjchem-1480 104 31 o o NOUN eurjchem-1480 104 32 ) ) PUNCT eurjchem-1480 104 33 , , PUNCT eurjchem-1480 104 34 69 69 NUM eurjchem-1480 104 35 ( ( PUNCT eurjchem-1480 104 36 ch‐o ch‐o PROPN eurjchem-1480 104 37 ) ) PUNCT eurjchem-1480 104 38 , , PUNCT eurjchem-1480 104 39 64 64 NUM eurjchem-1480 104 40 ( ( PUNCT eurjchem-1480 104 41 ch2‐ ch2‐ NOUN eurjchem-1480 104 42 o o NOUN eurjchem-1480 104 43 ) ) PUNCT eurjchem-1480 104 44 , , PUNCT eurjchem-1480 104 45 62 62 NUM eurjchem-1480 104 46 ( ( PUNCT eurjchem-1480 104 47 ch2‐o ch2‐o NOUN eurjchem-1480 104 48 ) ) PUNCT eurjchem-1480 104 49 , , PUNCT eurjchem-1480 104 50 59 59 NUM eurjchem-1480 104 51 ( ( PUNCT eurjchem-1480 104 52 c‐quat c‐quat X eurjchem-1480 104 53 . . PUNCT eurjchem-1480 104 54 ) ) PUNCT eurjchem-1480 104 55 , , PUNCT eurjchem-1480 104 56 51 51 NUM eurjchem-1480 104 57 ( ( PUNCT eurjchem-1480 104 58 ch2 ch2 PROPN eurjchem-1480 104 59 ) ) PUNCT eurjchem-1480 104 60 , , PUNCT eurjchem-1480 104 61 48 48 NUM eurjchem-1480 104 62 ( ( PUNCT eurjchem-1480 104 63 ch3‐n ch3‐n PROPN eurjchem-1480 104 64 ) ) PUNCT eurjchem-1480 104 65 , , PUNCT eurjchem-1480 104 66 44 44 NUM eurjchem-1480 104 67 ( ( PUNCT eurjchem-1480 104 68 c‐quat c‐quat X eurjchem-1480 104 69 . . PUNCT eurjchem-1480 104 70 ) ) PUNCT eurjchem-1480 104 71 , , PUNCT eurjchem-1480 104 72 31 31 NUM eurjchem-1480 104 73 ( ( PUNCT eurjchem-1480 104 74 ch3 ch3 PROPN eurjchem-1480 104 75 ) ) PUNCT eurjchem-1480 104 76 , , PUNCT eurjchem-1480 104 77 20 20 NUM eurjchem-1480 104 78 ( ( PUNCT eurjchem-1480 104 79 ch3 ch3 PROPN eurjchem-1480 104 80 ) ) PUNCT eurjchem-1480 104 81 , , PUNCT eurjchem-1480 104 82 17 17 NUM eurjchem-1480 104 83 ( ( PUNCT eurjchem-1480 104 84 ch3 ch3 PROPN eurjchem-1480 104 85 ) ) PUNCT eurjchem-1480 104 86 . . PUNCT eurjchem-1480 105 1 3 3 X eurjchem-1480 105 2 . . NOUN eurjchem-1480 105 3 results result NOUN eurjchem-1480 105 4 and and CCONJ eurjchem-1480 105 5 discussion discussion NOUN eurjchem-1480 105 6 3.1 3.1 NUM eurjchem-1480 105 7 . . PUNCT eurjchem-1480 106 1 characterization characterization NOUN eurjchem-1480 106 2 of of ADP eurjchem-1480 106 3 new new ADJ eurjchem-1480 106 4 copolymers copolymer NOUN eurjchem-1480 106 5 by by ADP eurjchem-1480 106 6 ft‐ir ft‐ir NOUN eurjchem-1480 106 7 the the DET eurjchem-1480 106 8 prepared prepared ADJ eurjchem-1480 106 9 solid solid ADJ eurjchem-1480 106 10 copolymers copolymer NOUN eurjchem-1480 106 11 were be AUX eurjchem-1480 106 12 characterized characterize VERB eurjchem-1480 106 13 as as ADP eurjchem-1480 106 14 kbr kbr PROPN eurjchem-1480 106 15 discs disc NOUN eurjchem-1480 106 16 . . PUNCT eurjchem-1480 107 1 the the DET eurjchem-1480 107 2 ft‐ir ft‐ir ADJ eurjchem-1480 107 3 spectra spectra NOUN eurjchem-1480 107 4 of of ADP eurjchem-1480 107 5 copolymers copolymer NOUN eurjchem-1480 107 6 pl10brdm pl10brdm PROPN eurjchem-1480 107 7 , , PUNCT eurjchem-1480 107 8 pl25brdm pl25brdm PROPN eurjchem-1480 107 9 , , PUNCT eurjchem-1480 107 10 pl50brdm pl50brdm PROPN eurjchem-1480 107 11 and and CCONJ eurjchem-1480 107 12 pl100brdm pl100brdm PRON eurjchem-1480 107 13 showed show VERB eurjchem-1480 107 14 characteristic characteristic ADJ eurjchem-1480 107 15 intense intense ADJ eurjchem-1480 107 16 absorption absorption NOUN eurjchem-1480 107 17 bands band NOUN eurjchem-1480 107 18 due due ADP eurjchem-1480 107 19 to to ADP eurjchem-1480 107 20 the the DET eurjchem-1480 107 21 ν(n‐c ν(n‐c NUM eurjchem-1480 107 22 ) ) PUNCT eurjchem-1480 107 23 groups group NOUN eurjchem-1480 107 24 at at ADP eurjchem-1480 107 25 1133 1133 NUM eurjchem-1480 107 26 , , PUNCT eurjchem-1480 107 27 1134 1134 NUM eurjchem-1480 107 28 , , PUNCT eurjchem-1480 107 29 1136 1136 NUM eurjchem-1480 107 30 and and CCONJ eurjchem-1480 107 31 1133 1133 NUM eurjchem-1480 107 32 cm‐1 cm‐1 NOUN eurjchem-1480 107 33 , , PUNCT eurjchem-1480 107 34 respectively respectively ADV eurjchem-1480 107 35 , , PUNCT eurjchem-1480 107 36 and and CCONJ eurjchem-1480 107 37 the the DET eurjchem-1480 107 38 ν(c ν(c PROPN eurjchem-1480 107 39 = = SYM eurjchem-1480 107 40 o o NOUN eurjchem-1480 107 41 ) ) PUNCT eurjchem-1480 107 42 groups group NOUN eurjchem-1480 107 43 at at ADP eurjchem-1480 107 44 1741 1741 NUM eurjchem-1480 107 45 , , PUNCT eurjchem-1480 107 46 1746 1746 NUM eurjchem-1480 107 47 , , PUNCT eurjchem-1480 107 48 1751 1751 NUM eurjchem-1480 107 49 and and CCONJ eurjchem-1480 107 50 1745 1745 NUM eurjchem-1480 107 51 cm‐1 cm‐1 NOUN eurjchem-1480 107 52 , , PUNCT eurjchem-1480 107 53 respectively respectively ADV eurjchem-1480 107 54 . . PUNCT eurjchem-1480 108 1 3.2 3.2 NUM eurjchem-1480 108 2 . . PUNCT eurjchem-1480 108 3 characterization characterization NOUN eurjchem-1480 108 4 of of ADP eurjchem-1480 108 5 new new ADJ eurjchem-1480 108 6 copolymer copolymer NOUN eurjchem-1480 108 7 by by ADP eurjchem-1480 108 8 nmr nmr NOUN eurjchem-1480 108 9 1h 1h NUM eurjchem-1480 108 10 nmr nmr NOUN eurjchem-1480 108 11 and and CCONJ eurjchem-1480 108 12 13c 13c NOUN eurjchem-1480 108 13 nmr nmr NOUN eurjchem-1480 108 14 of of ADP eurjchem-1480 108 15 pl10brdm pl10brdm PROPN eurjchem-1480 108 16 , , PUNCT eurjchem-1480 108 17 pl25brdm pl25brdm PROPN eurjchem-1480 108 18 , , PUNCT eurjchem-1480 108 19 pl50brdm pl50brdm PROPN eurjchem-1480 108 20 and and CCONJ eurjchem-1480 108 21 pl100brdm pl100brdm PROPN eurjchem-1480 108 22 copolymers copolymer NOUN eurjchem-1480 108 23 was be AUX eurjchem-1480 108 24 recorded record VERB eurjchem-1480 108 25 by by ADP eurjchem-1480 108 26 using use VERB eurjchem-1480 108 27 dimethyl dimethyl PROPN eurjchem-1480 108 28 sulfoxide‐d6 sulfoxide‐d6 PROPN eurjchem-1480 108 29 as as ADP eurjchem-1480 108 30 solvent solvent VERB eurjchem-1480 108 31 . . PUNCT eurjchem-1480 109 1 the the DET eurjchem-1480 109 2 signals signal NOUN eurjchem-1480 109 3 belong belong VERB eurjchem-1480 109 4 to to ADP eurjchem-1480 109 5 the the DET eurjchem-1480 109 6 o‐ch‐co o‐ch‐co NOUN eurjchem-1480 109 7 , , PUNCT eurjchem-1480 109 8 o‐ o‐ PROPN eurjchem-1480 109 9 ch2 ch2 PROPN eurjchem-1480 109 10 , , PUNCT eurjchem-1480 109 11 o‐ch‐ch3 o‐ch‐ch3 ADJ eurjchem-1480 109 12 and and CCONJ eurjchem-1480 109 13 ch3 ch3 PROPN eurjchem-1480 109 14 groups group NOUN eurjchem-1480 109 15 in in ADP eurjchem-1480 109 16 repeating repeat VERB eurjchem-1480 109 17 unit unit NOUN eurjchem-1480 109 18 of of ADP eurjchem-1480 109 19 l‐lactide l‐lactide PUNCT eurjchem-1480 109 20 segments segment NOUN eurjchem-1480 109 21 of of ADP eurjchem-1480 109 22 the the DET eurjchem-1480 109 23 synthesized synthesize VERB eurjchem-1480 109 24 all all DET eurjchem-1480 109 25 copolymers copolymer NOUN eurjchem-1480 109 26 were be AUX eurjchem-1480 109 27 observed observe VERB eurjchem-1480 109 28 approximately approximately ADV eurjchem-1480 109 29 at at ADP eurjchem-1480 109 30 δ δ PROPN eurjchem-1480 109 31 5.2 5.2 NUM eurjchem-1480 109 32 , , PUNCT eurjchem-1480 109 33 4.0 4.0 NUM eurjchem-1480 109 34 1.5 1.5 NUM eurjchem-1480 109 35 and and CCONJ eurjchem-1480 109 36 1.4 1.4 NUM eurjchem-1480 109 37 ppm ppm NOUN eurjchem-1480 109 38 in in ADP eurjchem-1480 109 39 the the DET eurjchem-1480 109 40 1h 1h NUM eurjchem-1480 109 41 nmr nmr NOUN eurjchem-1480 109 42 spectra spectra NOUN eurjchem-1480 109 43 , , PUNCT eurjchem-1480 109 44 respectively respectively ADV eurjchem-1480 109 45 . . PUNCT eurjchem-1480 110 1 also also ADV eurjchem-1480 110 2 , , PUNCT eurjchem-1480 110 3 the the DET eurjchem-1480 110 4 signals signal NOUN eurjchem-1480 110 5 belong belong VERB eurjchem-1480 110 6 to to ADP eurjchem-1480 110 7 the the DET eurjchem-1480 110 8 ch2 ch2 PROPN eurjchem-1480 110 9 and and CCONJ eurjchem-1480 110 10 ch3 ch3 PROPN eurjchem-1480 110 11 groups group NOUN eurjchem-1480 110 12 in in ADP eurjchem-1480 110 13 repeating repeat VERB eurjchem-1480 110 14 unit unit NOUN eurjchem-1480 110 15 of of ADP eurjchem-1480 110 16 dmaema dmaema NOUN eurjchem-1480 110 17 and and CCONJ eurjchem-1480 110 18 o‐ch2 o‐ch2 PROPN eurjchem-1480 110 19 , , PUNCT eurjchem-1480 110 20 n‐ch2 n‐ch2 PROPN eurjchem-1480 110 21 n‐ n‐ PROPN eurjchem-1480 110 22 ch3 ch3 PROPN eurjchem-1480 110 23 groups group NOUN eurjchem-1480 110 24 in in ADP eurjchem-1480 110 25 branched branched ADJ eurjchem-1480 110 26 part part NOUN eurjchem-1480 110 27 of of ADP eurjchem-1480 110 28 dmaema dmaema NOUN eurjchem-1480 110 29 were be AUX eurjchem-1480 110 30 showed show VERB eurjchem-1480 110 31 around around ADP eurjchem-1480 110 32 at at ADP eurjchem-1480 110 33 δ δ PROPN eurjchem-1480 110 34 2.7 2.7 NUM eurjchem-1480 110 35 , , PUNCT eurjchem-1480 110 36 2.3 2.3 NUM eurjchem-1480 110 37 , , PUNCT eurjchem-1480 110 38 4.1 4.1 NUM eurjchem-1480 110 39 , , PUNCT eurjchem-1480 110 40 3.4 3.4 NUM eurjchem-1480 110 41 and and CCONJ eurjchem-1480 110 42 2.9 2.9 NUM eurjchem-1480 110 43 ppm ppm NOUN eurjchem-1480 110 44 , , PUNCT eurjchem-1480 110 45 respectively respectively ADV eurjchem-1480 110 46 . . PUNCT eurjchem-1480 111 1 in in ADP eurjchem-1480 111 2 the the DET eurjchem-1480 111 3 13c 13c NOUN eurjchem-1480 111 4 nmr nmr NOUN eurjchem-1480 111 5 spectra spectra NOUN eurjchem-1480 111 6 , , PUNCT eurjchem-1480 111 7 the the DET eurjchem-1480 111 8 signals signal NOUN eurjchem-1480 111 9 belong belong VERB eurjchem-1480 111 10 to to ADP eurjchem-1480 111 11 the the DET eurjchem-1480 111 12 c c PROPN eurjchem-1480 111 13 = = PROPN eurjchem-1480 111 14 o o PROPN eurjchem-1480 111 15 group group NOUN eurjchem-1480 111 16 of of ADP eurjchem-1480 111 17 dmaema dmaema NOUN eurjchem-1480 111 18 segments segment NOUN eurjchem-1480 111 19 of of ADP eurjchem-1480 111 20 the the DET eurjchem-1480 111 21 synthesized synthesize VERB eurjchem-1480 111 22 all all DET eurjchem-1480 111 23 copolymers copolymer NOUN eurjchem-1480 111 24 were be AUX eurjchem-1480 111 25 observed observe VERB eurjchem-1480 111 26 approximately approximately ADV eurjchem-1480 111 27 at at ADP eurjchem-1480 111 28 δ δ PROPN eurjchem-1480 111 29 175 175 NUM eurjchem-1480 111 30 ppm ppm NOUN eurjchem-1480 111 31 . . PUNCT eurjchem-1480 112 1 also also ADV eurjchem-1480 112 2 , , PUNCT eurjchem-1480 112 3 the the DET eurjchem-1480 112 4 signals signal NOUN eurjchem-1480 112 5 belong belong VERB eurjchem-1480 112 6 to to ADP eurjchem-1480 112 7 the the DET eurjchem-1480 112 8 ch2 ch2 PROPN eurjchem-1480 112 9 and and CCONJ eurjchem-1480 112 10 ch3 ch3 PROPN eurjchem-1480 112 11 groups group NOUN eurjchem-1480 112 12 in in ADP eurjchem-1480 112 13 repeating repeat VERB eurjchem-1480 112 14 unit unit NOUN eurjchem-1480 112 15 of of ADP eurjchem-1480 112 16 dmaema dmaema NOUN eurjchem-1480 112 17 and and CCONJ eurjchem-1480 112 18 o‐ch2 o‐ch2 PROPN eurjchem-1480 112 19 , , PUNCT eurjchem-1480 112 20 n‐ch2 n‐ch2 PROPN eurjchem-1480 112 21 n‐ch3 n‐ch3 ADJ eurjchem-1480 112 22 groups group NOUN eurjchem-1480 112 23 in in ADP eurjchem-1480 112 24 branched branched ADJ eurjchem-1480 112 25 part part NOUN eurjchem-1480 112 26 of of ADP eurjchem-1480 112 27 dmaema dmaema NOUN eurjchem-1480 112 28 were be AUX eurjchem-1480 112 29 showed show VERB eurjchem-1480 112 30 around around ADP eurjchem-1480 112 31 at at ADP eurjchem-1480 112 32 δ δ PROPN eurjchem-1480 112 33 50 50 NUM eurjchem-1480 112 34 , , PUNCT eurjchem-1480 112 35 59 59 NUM eurjchem-1480 112 36 , , PUNCT eurjchem-1480 112 37 62 62 NUM eurjchem-1480 112 38 , , PUNCT eurjchem-1480 112 39 62 62 NUM eurjchem-1480 112 40 and and CCONJ eurjchem-1480 112 41 46 46 NUM eurjchem-1480 112 42 ppm ppm NOUN eurjchem-1480 112 43 , , PUNCT eurjchem-1480 112 44 respectively respectively ADV eurjchem-1480 112 45 . . PUNCT eurjchem-1480 113 1 3.3 3.3 NUM eurjchem-1480 113 2 . . PUNCT eurjchem-1480 114 1 copolymers copolymer NOUN eurjchem-1480 114 2 molecular molecular ADJ eurjchem-1480 114 3 weight weight NOUN eurjchem-1480 114 4 and and CCONJ eurjchem-1480 114 5 polydispersity polydispersity NOUN eurjchem-1480 114 6 index index NOUN eurjchem-1480 114 7 the the DET eurjchem-1480 114 8 molecular molecular ADJ eurjchem-1480 114 9 weight weight NOUN eurjchem-1480 114 10 and and CCONJ eurjchem-1480 114 11 the the DET eurjchem-1480 114 12 polydispersity polydispersity NOUN eurjchem-1480 114 13 index index NOUN eurjchem-1480 114 14 ( ( PUNCT eurjchem-1480 114 15 mw mw PROPN eurjchem-1480 114 16 / / SYM eurjchem-1480 114 17 mn mn PROPN eurjchem-1480 114 18 ) ) PUNCT eurjchem-1480 114 19 were be AUX eurjchem-1480 114 20 determined determine VERB eurjchem-1480 114 21 by by ADP eurjchem-1480 114 22 gpc gpc PROPN eurjchem-1480 114 23 for for ADP eurjchem-1480 114 24 all all DET eurjchem-1480 114 25 prepared prepared ADJ eurjchem-1480 114 26 copolymers copolymer NOUN eurjchem-1480 114 27 and and CCONJ eurjchem-1480 114 28 table table NOUN eurjchem-1480 114 29 2 2 NUM eurjchem-1480 114 30 shows show VERB eurjchem-1480 114 31 the the DET eurjchem-1480 114 32 results result NOUN eurjchem-1480 114 33 . . PUNCT eurjchem-1480 115 1 the the DET eurjchem-1480 115 2 results result NOUN eurjchem-1480 115 3 of of ADP eurjchem-1480 115 4 gpc gpc PROPN eurjchem-1480 115 5 showed show VERB eurjchem-1480 115 6 that that SCONJ eurjchem-1480 115 7 the the DET eurjchem-1480 115 8 prepared prepare VERB eurjchem-1480 115 9 copolymers copolymer NOUN eurjchem-1480 115 10 had have VERB eurjchem-1480 115 11 a a DET eurjchem-1480 115 12 polydispersity polydispersity NOUN eurjchem-1480 115 13 index index NOUN eurjchem-1480 115 14 ( ( PUNCT eurjchem-1480 115 15 pdi pdi PROPN eurjchem-1480 115 16 ) ) PUNCT eurjchem-1480 115 17 close close ADJ eurjchem-1480 115 18 to to ADP eurjchem-1480 115 19 unity unity NOUN eurjchem-1480 115 20 . . PUNCT eurjchem-1480 116 1 this this PRON eurjchem-1480 116 2 implies imply VERB eurjchem-1480 116 3 that that SCONJ eurjchem-1480 116 4 the the DET eurjchem-1480 116 5 correctness correctness NOUN eurjchem-1480 116 6 of of ADP eurjchem-1480 116 7 the the DET eurjchem-1480 116 8 suggested suggest VERB eurjchem-1480 116 9 structure structure NOUN eurjchem-1480 116 10 for for ADP eurjchem-1480 116 11 the the DET eurjchem-1480 116 12 prepared prepare VERB eurjchem-1480 116 13 copolymers copolymer NOUN eurjchem-1480 116 14 . . PUNCT eurjchem-1480 117 1 3.4 3.4 NUM eurjchem-1480 117 2 . . PUNCT eurjchem-1480 117 3 scaning scaning NOUN eurjchem-1480 117 4 electron electron PROPN eurjchem-1480 117 5 microcsopy microcsopy NOUN eurjchem-1480 117 6 ( ( PUNCT eurjchem-1480 117 7 sem sem NOUN eurjchem-1480 117 8 ) ) PUNCT eurjchem-1480 117 9 all all DET eurjchem-1480 117 10 the the DET eurjchem-1480 117 11 spectroscopic spectroscopic ADJ eurjchem-1480 117 12 examinations examination NOUN eurjchem-1480 117 13 of of ADP eurjchem-1480 117 14 the the DET eurjchem-1480 117 15 prepared prepare VERB eurjchem-1480 117 16 copolymers copolymer NOUN eurjchem-1480 117 17 , , PUNCT eurjchem-1480 117 18 ft‐ir ft‐ir NOUN eurjchem-1480 117 19 , , PUNCT eurjchem-1480 117 20 1h 1h NUM eurjchem-1480 117 21 nmr nmr NOUN eurjchem-1480 117 22 and and CCONJ eurjchem-1480 117 23 13c 13c NOUN eurjchem-1480 117 24 nmr nmr NOUN eurjchem-1480 117 25 proved prove VERB eurjchem-1480 117 26 the the DET eurjchem-1480 117 27 suggested suggest VERB eurjchem-1480 117 28 structure structure NOUN eurjchem-1480 117 29 for for ADP eurjchem-1480 117 30 the the DET eurjchem-1480 117 31 prepared prepared ADJ eurjchem-1480 117 32 copolymers copolymer NOUN eurjchem-1480 117 33 and and CCONJ eurjchem-1480 117 34 promoted promote VERB eurjchem-1480 117 35 this this DET eurjchem-1480 117 36 matter matter NOUN eurjchem-1480 117 37 with with ADP eurjchem-1480 117 38 greater great ADJ eurjchem-1480 117 39 accuracy accuracy NOUN eurjchem-1480 117 40 results result NOUN eurjchem-1480 117 41 of of ADP eurjchem-1480 117 42 gpc gpc PROPN eurjchem-1480 117 43 as as SCONJ eurjchem-1480 117 44 they they PRON eurjchem-1480 117 45 are be AUX eurjchem-1480 117 46 shown show VERB eurjchem-1480 117 47 a a DET eurjchem-1480 117 48 significant significant ADJ eurjchem-1480 117 49 matching matching NOUN eurjchem-1480 117 50 to to ADP eurjchem-1480 117 51 the the DET eurjchem-1480 117 52 molecular molecular ADJ eurjchem-1480 117 53 weight weight NOUN eurjchem-1480 117 54 calculated calculate VERB eurjchem-1480 117 55 theoretically theoretically ADV eurjchem-1480 117 56 and and CCONJ eurjchem-1480 117 57 result result VERB eurjchem-1480 117 58 the the DET eurjchem-1480 117 59 awesome awesome ADJ eurjchem-1480 117 60 polydispersity polydispersity NOUN eurjchem-1480 117 61 index index NOUN eurjchem-1480 117 62 ( ( PUNCT eurjchem-1480 117 63 pdi pdi PROPN eurjchem-1480 117 64 ) ) PUNCT eurjchem-1480 117 65 is be AUX eurjchem-1480 117 66 close close ADJ eurjchem-1480 117 67 to to ADP eurjchem-1480 117 68 one one NUM eurjchem-1480 117 69 . . PUNCT eurjchem-1480 118 1 the the DET eurjchem-1480 118 2 examination examination NOUN eurjchem-1480 118 3 of of ADP eurjchem-1480 118 4 the the DET eurjchem-1480 118 5 morphology morphology NOUN eurjchem-1480 118 6 and and CCONJ eurjchem-1480 118 7 the the DET eurjchem-1480 118 8 nanoparticles nanoparticle NOUN eurjchem-1480 118 9 geometry geometry NOUN eurjchem-1480 118 10 of of ADP eurjchem-1480 118 11 the the DET eurjchem-1480 118 12 prepared prepare VERB eurjchem-1480 118 13 copolymers copolymer NOUN eurjchem-1480 118 14 was be AUX eurjchem-1480 118 15 performed perform VERB eurjchem-1480 118 16 by by ADP eurjchem-1480 118 17 using use VERB eurjchem-1480 118 18 sem sem NOUN eurjchem-1480 118 19 at at ADP eurjchem-1480 118 20 different different ADJ eurjchem-1480 118 21 amplifications amplification NOUN eurjchem-1480 118 22 ( ( PUNCT eurjchem-1480 118 23 10 10 NUM eurjchem-1480 118 24 µm µm NOUN eurjchem-1480 118 25 and and CCONJ eurjchem-1480 118 26 100 100 NUM eurjchem-1480 118 27 nm nm NOUN eurjchem-1480 118 28 ) ) PUNCT eurjchem-1480 118 29 . . PUNCT eurjchem-1480 119 1 figures figure NOUN eurjchem-1480 119 2 2 2 NUM eurjchem-1480 119 3 and and CCONJ eurjchem-1480 119 4 3 3 NUM eurjchem-1480 119 5 are be AUX eurjchem-1480 119 6 show show VERB eurjchem-1480 119 7 the the DET eurjchem-1480 119 8 sem sem NOUN eurjchem-1480 119 9 micrographs micrograph NOUN eurjchem-1480 119 10 of of ADP eurjchem-1480 119 11 examined examine VERB eurjchem-1480 119 12 pl25brdm pl25brdm PROPN eurjchem-1480 119 13 and and CCONJ eurjchem-1480 119 14 pl100brdm pl100brdm NOUN eurjchem-1480 119 15 copolymers copolymer NOUN eurjchem-1480 119 16 . . PUNCT eurjchem-1480 120 1 the the DET eurjchem-1480 120 2 images image NOUN eurjchem-1480 120 3 obtained obtain VERB eurjchem-1480 120 4 from from ADP eurjchem-1480 120 5 scanning scan VERB eurjchem-1480 120 6 electronic electronic ADJ eurjchem-1480 120 7 microscopy microscopy NOUN eurjchem-1480 120 8 revealed reveal VERB eurjchem-1480 120 9 the the DET eurjchem-1480 120 10 existence existence NOUN eurjchem-1480 120 11 of of ADP eurjchem-1480 120 12 nano‐structures nano‐structure NOUN eurjchem-1480 120 13 in in ADP eurjchem-1480 120 14 the the DET eurjchem-1480 120 15 prepared prepare VERB eurjchem-1480 120 16 copolymers copolymer NOUN eurjchem-1480 120 17 due due ADP eurjchem-1480 120 18 to to ADP eurjchem-1480 120 19 the the DET eurjchem-1480 120 20 presence presence NOUN eurjchem-1480 120 21 of of ADP eurjchem-1480 120 22 the the DET eurjchem-1480 120 23 lactide lactide ADJ eurjchem-1480 120 24 array array NOUN eurjchem-1480 120 25 to to PART eurjchem-1480 120 26 give give VERB eurjchem-1480 120 27 nanofiber nanofiber NOUN eurjchem-1480 120 28 within within ADP eurjchem-1480 120 29 the the DET eurjchem-1480 120 30 final final ADJ eurjchem-1480 120 31 compositions composition NOUN eurjchem-1480 120 32 . . PUNCT eurjchem-1480 121 1 3.5 3.5 NUM eurjchem-1480 121 2 . . PUNCT eurjchem-1480 122 1 thermogravimetric thermogravimetric ADJ eurjchem-1480 122 2 analysis analysis NOUN eurjchem-1480 122 3 ( ( PUNCT eurjchem-1480 122 4 tga tga NOUN eurjchem-1480 122 5 ) ) PUNCT eurjchem-1480 122 6 thermal thermal ADJ eurjchem-1480 122 7 stability stability NOUN eurjchem-1480 122 8 of of ADP eurjchem-1480 122 9 the the DET eurjchem-1480 122 10 prepared prepare VERB eurjchem-1480 122 11 copolymers copolymer NOUN eurjchem-1480 122 12 was be AUX eurjchem-1480 122 13 studied study VERB eurjchem-1480 122 14 and and CCONJ eurjchem-1480 122 15 figure figure VERB eurjchem-1480 122 16 4 4 NUM eurjchem-1480 122 17 shows show VERB eurjchem-1480 122 18 the the DET eurjchem-1480 122 19 resulted resulted ADJ eurjchem-1480 122 20 thermograms thermogram NOUN eurjchem-1480 122 21 . . PUNCT eurjchem-1480 123 1 table table NOUN eurjchem-1480 123 2 3 3 NUM eurjchem-1480 123 3 shows show VERB eurjchem-1480 123 4 some some DET eurjchem-1480 123 5 thermal thermal ADJ eurjchem-1480 123 6 functions function NOUN eurjchem-1480 123 7 resulted result VERB eurjchem-1480 123 8 from from ADP eurjchem-1480 123 9 the the DET eurjchem-1480 123 10 thermal thermal ADJ eurjchem-1480 123 11 analysis analysis NOUN eurjchem-1480 123 12 , , PUNCT eurjchem-1480 123 13 namely namely ADV eurjchem-1480 123 14 initiation initiation NOUN eurjchem-1480 123 15 and and CCONJ eurjchem-1480 123 16 final final ADJ eurjchem-1480 123 17 decomposition decomposition NOUN eurjchem-1480 123 18 temperatures temperature NOUN eurjchem-1480 123 19 ti ti NOUN eurjchem-1480 123 20 and and CCONJ eurjchem-1480 123 21 tf tf NOUN eurjchem-1480 123 22 , , PUNCT eurjchem-1480 123 23 rate rate NOUN eurjchem-1480 123 24 of of ADP eurjchem-1480 123 25 decomposition decomposition NOUN eurjchem-1480 123 26 , , PUNCT eurjchem-1480 123 27 the the DET eurjchem-1480 123 28 activation activation NOUN eurjchem-1480 123 29 energy energy NOUN eurjchem-1480 123 30 of of ADP eurjchem-1480 123 31 the the DET eurjchem-1480 123 32 decomposition decomposition NOUN eurjchem-1480 123 33 , , PUNCT eurjchem-1480 123 34 temperature temperature NOUN eurjchem-1480 123 35 of of ADP eurjchem-1480 123 36 50 50 NUM eurjchem-1480 123 37 % % NOUN eurjchem-1480 123 38 weight weight NOUN eurjchem-1480 123 39 loss loss NOUN eurjchem-1480 123 40 ( ( PUNCT eurjchem-1480 123 41 t50 t50 NOUN eurjchem-1480 123 42 ) ) PUNCT eurjchem-1480 123 43 , , PUNCT eurjchem-1480 123 44 and and CCONJ eurjchem-1480 123 45 char char NOUN eurjchem-1480 123 46 content content NOUN eurjchem-1480 123 47 for for ADP eurjchem-1480 123 48 first first ADJ eurjchem-1480 123 49 and and CCONJ eurjchem-1480 123 50 second second ADJ eurjchem-1480 123 51 decomposition decomposition NOUN eurjchem-1480 123 52 step step NOUN eurjchem-1480 123 53 . . PUNCT eurjchem-1480 124 1 408 408 NUM eurjchem-1480 124 2 al‐mayyahi al‐mayyahi NOUN eurjchem-1480 124 3 et et PROPN eurjchem-1480 124 4 al al PROPN eurjchem-1480 124 5 . . PUNCT eurjchem-1480 124 6 / / SYM eurjchem-1480 124 7 european european PROPN eurjchem-1480 124 8 journal journal PROPN eurjchem-1480 124 9 of of ADP eurjchem-1480 124 10 chemistry chemistry NOUN eurjchem-1480 124 11 7 7 NUM eurjchem-1480 124 12 ( ( PUNCT eurjchem-1480 124 13 4 4 NUM eurjchem-1480 124 14 ) ) PUNCT eurjchem-1480 124 15 ( ( PUNCT eurjchem-1480 124 16 2016 2016 NUM eurjchem-1480 124 17 ) ) PUNCT eurjchem-1480 124 18 405‐409 405‐409 NUM eurjchem-1480 124 19 figure figure NOUN eurjchem-1480 124 20 2 2 NUM eurjchem-1480 124 21 . . PUNCT eurjchem-1480 124 22 sem sem ADJ eurjchem-1480 124 23 image image NOUN eurjchem-1480 124 24 of of ADP eurjchem-1480 124 25 pl25brdm pl25brdm PROPN eurjchem-1480 124 26 . . PUNCT eurjchem-1480 125 1 figure figure NOUN eurjchem-1480 125 2 3 3 NUM eurjchem-1480 125 3 . . PUNCT eurjchem-1480 125 4 sem sem ADJ eurjchem-1480 125 5 image image NOUN eurjchem-1480 125 6 of of ADP eurjchem-1480 125 7 pl100brdm pl100brdm PROPN eurjchem-1480 125 8 . . PUNCT eurjchem-1480 126 1 figure figure NOUN eurjchem-1480 126 2 4 4 NUM eurjchem-1480 126 3 . . PUNCT eurjchem-1480 127 1 thermogram thermogram NOUN eurjchem-1480 127 2 of of ADP eurjchem-1480 127 3 pl10brdm pl10brdm PROPN eurjchem-1480 127 4 , , PUNCT eurjchem-1480 127 5 pl25brdm pl25brdm PROPN eurjchem-1480 127 6 , , PUNCT eurjchem-1480 127 7 pl50brdm pl50brdm PROPN eurjchem-1480 127 8 and and CCONJ eurjchem-1480 127 9 pl100brdm pl100brdm NOUN eurjchem-1480 127 10 copolymers copolymer NOUN eurjchem-1480 127 11 . . PUNCT eurjchem-1480 128 1 thermal thermal ADJ eurjchem-1480 128 2 gravimetric gravimetric ADJ eurjchem-1480 128 3 results result NOUN eurjchem-1480 128 4 indicates indicate VERB eurjchem-1480 128 5 that that SCONJ eurjchem-1480 128 6 the the DET eurjchem-1480 128 7 initial initial ADJ eurjchem-1480 128 8 decomposition decomposition NOUN eurjchem-1480 128 9 temperature temperature NOUN eurjchem-1480 128 10 ( ( PUNCT eurjchem-1480 128 11 ti ti NOUN eurjchem-1480 128 12 ) ) PUNCT eurjchem-1480 128 13 ranging range VERB eurjchem-1480 128 14 between between ADP eurjchem-1480 128 15 145 145 NUM eurjchem-1480 128 16 and and CCONJ eurjchem-1480 128 17 190 190 NUM eurjchem-1480 128 18 ° ° NOUN eurjchem-1480 128 19 c c NOUN eurjchem-1480 128 20 for for ADP eurjchem-1480 128 21 first first ADJ eurjchem-1480 128 22 decomposition decomposition NOUN eurjchem-1480 128 23 and and CCONJ eurjchem-1480 128 24 between between ADP eurjchem-1480 128 25 289‐306 289‐306 PROPN eurjchem-1480 128 26 ° ° PROPN eurjchem-1480 128 27 c c NOUN eurjchem-1480 128 28 for for ADP eurjchem-1480 128 29 second second ADJ eurjchem-1480 128 30 decomposition decomposition NOUN eurjchem-1480 128 31 . . PUNCT eurjchem-1480 129 1 table table NOUN eurjchem-1480 129 2 3 3 NUM eurjchem-1480 129 3 indicates indicate VERB eurjchem-1480 129 4 that that SCONJ eurjchem-1480 129 5 the the DET eurjchem-1480 129 6 initial initial ADJ eurjchem-1480 129 7 decomposition decomposition NOUN eurjchem-1480 129 8 temperature temperature NOUN eurjchem-1480 129 9 for for ADP eurjchem-1480 129 10 prepared prepared ADJ eurjchem-1480 129 11 polymers polymer NOUN eurjchem-1480 129 12 were be AUX eurjchem-1480 129 13 increased increase VERB eurjchem-1480 129 14 with with ADP eurjchem-1480 129 15 increasing increase VERB eurjchem-1480 129 16 of of ADP eurjchem-1480 129 17 repeating repeat VERB eurjchem-1480 129 18 units unit NOUN eurjchem-1480 129 19 of of ADP eurjchem-1480 129 20 lactide lactide NOUN eurjchem-1480 129 21 and and CCONJ eurjchem-1480 129 22 the the DET eurjchem-1480 129 23 rate rate NOUN eurjchem-1480 129 24 of of ADP eurjchem-1480 129 25 decomposition decomposition NOUN eurjchem-1480 129 26 were be AUX eurjchem-1480 129 27 decreased decrease VERB eurjchem-1480 129 28 with with ADP eurjchem-1480 129 29 increasing increase VERB eurjchem-1480 129 30 of of ADP eurjchem-1480 129 31 repeating repeat VERB eurjchem-1480 129 32 units unit NOUN eurjchem-1480 129 33 , , PUNCT eurjchem-1480 129 34 this this PRON eurjchem-1480 129 35 is be AUX eurjchem-1480 129 36 an an DET eurjchem-1480 129 37 expected expect VERB eurjchem-1480 129 38 result result NOUN eurjchem-1480 129 39 because because SCONJ eurjchem-1480 129 40 with with ADP eurjchem-1480 129 41 increasing increase VERB eurjchem-1480 129 42 molecular molecular ADJ eurjchem-1480 129 43 weight weight NOUN eurjchem-1480 129 44 of of ADP eurjchem-1480 129 45 the the DET eurjchem-1480 129 46 copolymers copolymer NOUN eurjchem-1480 129 47 will will AUX eurjchem-1480 129 48 increase increase VERB eurjchem-1480 129 49 the the DET eurjchem-1480 129 50 thermal thermal ADJ eurjchem-1480 129 51 stability stability NOUN eurjchem-1480 129 52 . . PUNCT eurjchem-1480 130 1 4 4 X eurjchem-1480 130 2 . . X eurjchem-1480 130 3 conclusions conclusion NOUN eurjchem-1480 130 4 a a DET eurjchem-1480 130 5 series series NOUN eurjchem-1480 130 6 of of ADP eurjchem-1480 130 7 block block NOUN eurjchem-1480 130 8 copolymers copolymer NOUN eurjchem-1480 130 9 are be AUX eurjchem-1480 130 10 obtained obtain VERB eurjchem-1480 130 11 by by ADP eurjchem-1480 130 12 reaction reaction NOUN eurjchem-1480 130 13 of of ADP eurjchem-1480 130 14 pentaerythritol‐lactide pentaerythritol‐lactide NOUN eurjchem-1480 130 15 and and CCONJ eurjchem-1480 130 16 dimethylamino dimethylamino PROPN eurjchem-1480 130 17 ethyl ethyl PROPN eurjchem-1480 130 18 methacrylate methacrylate NOUN eurjchem-1480 130 19 by by ADP eurjchem-1480 130 20 atom atom NOUN eurjchem-1480 130 21 transfer transfer NOUN eurjchem-1480 130 22 radical radical ADJ eurjchem-1480 130 23 polymerization polymerization NOUN eurjchem-1480 130 24 . . PUNCT eurjchem-1480 131 1 spectroscopic spectroscopic ADJ eurjchem-1480 131 2 examination examination NOUN eurjchem-1480 131 3 of of ADP eurjchem-1480 131 4 the the DET eurjchem-1480 131 5 preparedness preparedness NOUN eurjchem-1480 131 6 copolymers copolymer NOUN eurjchem-1480 131 7 by by ADP eurjchem-1480 131 8 ft‐ir ft‐ir NOUN eurjchem-1480 131 9 , , PUNCT eurjchem-1480 131 10 1h 1h NUM eurjchem-1480 131 11 nmr nmr NOUN eurjchem-1480 131 12 and and CCONJ eurjchem-1480 131 13 13c 13c NOUN eurjchem-1480 131 14 nmr nmr NOUN eurjchem-1480 131 15 proved prove VERB eurjchem-1480 131 16 the the DET eurjchem-1480 131 17 suggested suggest VERB eurjchem-1480 131 18 structure structure NOUN eurjchem-1480 131 19 for for ADP eurjchem-1480 131 20 the the DET eurjchem-1480 131 21 prepared prepare VERB eurjchem-1480 131 22 copolymers copolymer NOUN eurjchem-1480 131 23 , , PUNCT eurjchem-1480 131 24 also also ADV eurjchem-1480 131 25 gpc gpc PROPN eurjchem-1480 131 26 results result NOUN eurjchem-1480 131 27 revealed reveal VERB eurjchem-1480 131 28 that that SCONJ eurjchem-1480 131 29 all all DET eurjchem-1480 131 30 the the DET eurjchem-1480 131 31 preparations preparation NOUN eurjchem-1480 131 32 copolymers copolymer NOUN eurjchem-1480 131 33 are be AUX eurjchem-1480 131 34 of of ADP eurjchem-1480 131 35 nearly nearly ADV eurjchem-1480 131 36 monodispers monodisper NOUN eurjchem-1480 131 37 polymer polymer NOUN eurjchem-1480 131 38 with with ADP eurjchem-1480 131 39 very very ADV eurjchem-1480 131 40 narrow narrow ADJ eurjchem-1480 131 41 distributions distribution NOUN eurjchem-1480 131 42 accompanied accompany VERB eurjchem-1480 131 43 by by ADP eurjchem-1480 131 44 nano nano NOUN eurjchem-1480 131 45 al‐mayyahi al‐mayyahi PROPN eurjchem-1480 131 46 et et PROPN eurjchem-1480 131 47 al al PROPN eurjchem-1480 131 48 . . PUNCT eurjchem-1480 131 49 / / SYM eurjchem-1480 131 50 european european PROPN eurjchem-1480 131 51 journal journal PROPN eurjchem-1480 131 52 of of ADP eurjchem-1480 131 53 chemistry chemistry NOUN eurjchem-1480 131 54 7 7 NUM eurjchem-1480 131 55 ( ( PUNCT eurjchem-1480 131 56 4 4 NUM eurjchem-1480 131 57 ) ) PUNCT eurjchem-1480 131 58 ( ( PUNCT eurjchem-1480 131 59 2016 2016 NUM eurjchem-1480 131 60 ) ) PUNCT eurjchem-1480 131 61 405‐409 405‐409 NUM eurjchem-1480 131 62 409 409 NUM eurjchem-1480 131 63 structures structure NOUN eurjchem-1480 131 64 were be AUX eurjchem-1480 131 65 obtained obtain VERB eurjchem-1480 131 66 as as SCONJ eurjchem-1480 131 67 shown show VERB eurjchem-1480 131 68 by by ADP eurjchem-1480 131 69 sem sem NOUN eurjchem-1480 131 70 micrographs micrograph NOUN eurjchem-1480 131 71 due due ADP eurjchem-1480 131 72 to to ADP eurjchem-1480 131 73 the the DET eurjchem-1480 131 74 presence presence NOUN eurjchem-1480 131 75 of of ADP eurjchem-1480 131 76 lactide lactide ADJ eurjchem-1480 131 77 polymer polymer NOUN eurjchem-1480 131 78 chains chain NOUN eurjchem-1480 131 79 . . PUNCT eurjchem-1480 132 1 the the DET eurjchem-1480 132 2 thermal thermal ADJ eurjchem-1480 132 3 gravimetric gravimetric ADJ eurjchem-1480 132 4 results result NOUN eurjchem-1480 132 5 showed show VERB eurjchem-1480 132 6 that that SCONJ eurjchem-1480 132 7 the the DET eurjchem-1480 132 8 initial initial ADJ eurjchem-1480 132 9 and and CCONJ eurjchem-1480 132 10 final final ADJ eurjchem-1480 132 11 decomposition decomposition NOUN eurjchem-1480 132 12 temperatures temperature NOUN eurjchem-1480 132 13 for for ADP eurjchem-1480 132 14 preparing prepare VERB eurjchem-1480 132 15 polymers polymer NOUN eurjchem-1480 132 16 were be AUX eurjchem-1480 132 17 increased increase VERB eurjchem-1480 132 18 with with ADP eurjchem-1480 132 19 the the DET eurjchem-1480 132 20 increasing increasing NOUN eurjchem-1480 132 21 of of ADP eurjchem-1480 132 22 repeating repeat VERB eurjchem-1480 132 23 units unit NOUN eurjchem-1480 132 24 of of ADP eurjchem-1480 132 25 lactide lactide NOUN eurjchem-1480 132 26 whereas whereas SCONJ eurjchem-1480 132 27 the the DET eurjchem-1480 132 28 rate rate NOUN eurjchem-1480 132 29 of of ADP eurjchem-1480 132 30 decompositions decomposition NOUN eurjchem-1480 132 31 decreased decrease VERB eurjchem-1480 132 32 with with ADP eurjchem-1480 132 33 the the DET eurjchem-1480 132 34 increasing increasing NOUN eurjchem-1480 132 35 of of ADP eurjchem-1480 132 36 repeating repeat VERB eurjchem-1480 132 37 units unit NOUN eurjchem-1480 132 38 . . PUNCT eurjchem-1480 133 1 acknowledgement acknowledgement NOUN eurjchem-1480 133 2 the the DET eurjchem-1480 133 3 authors author NOUN eurjchem-1480 133 4 would would AUX eurjchem-1480 133 5 like like VERB eurjchem-1480 133 6 to to PART eurjchem-1480 133 7 thank thank VERB eurjchem-1480 133 8 prof prof PROPN eurjchem-1480 133 9 . . PUNCT eurjchem-1480 134 1 babak babak NOUN eurjchem-1480 134 2 borhan borhan NOUN eurjchem-1480 134 3 and and CCONJ eurjchem-1480 134 4 dr dr PROPN eurjchem-1480 134 5 . . PROPN eurjchem-1480 134 6 kumar kumar PROPN eurjchem-1480 134 7 ashtekar ashtekar PROPN eurjchem-1480 134 8 from from ADP eurjchem-1480 134 9 chemistry chemistry NOUN eurjchem-1480 134 10 department department PROPN eurjchem-1480 134 11 , , PUNCT eurjchem-1480 134 12 michigan michigan PROPN eurjchem-1480 134 13 state state PROPN eurjchem-1480 134 14 university university PROPN eurjchem-1480 134 15 , , PUNCT eurjchem-1480 134 16 usa usa PROPN eurjchem-1480 134 17 , , PUNCT eurjchem-1480 134 18 for for ADP eurjchem-1480 134 19 their their PRON eurjchem-1480 134 20 help help NOUN eurjchem-1480 134 21 in in ADP eurjchem-1480 134 22 spectroscopic spectroscopic NOUN eurjchem-1480 134 23 and and CCONJ eurjchem-1480 134 24 gpc gpc PROPN eurjchem-1480 134 25 measurements measurement NOUN eurjchem-1480 134 26 and and CCONJ eurjchem-1480 134 27 their their PRON eurjchem-1480 134 28 kindness kindness NOUN eurjchem-1480 134 29 to to ADP eurjchem-1480 134 30 dr dr PROPN eurjchem-1480 134 31 . . PROPN eurjchem-1480 134 32 baqer baqer PROPN eurjchem-1480 134 33 al‐mayyahi al‐mayyahi PROPN eurjchem-1480 134 34 during during ADP eurjchem-1480 134 35 his his PRON eurjchem-1480 134 36 staying staying NOUN eurjchem-1480 134 37 time time NOUN eurjchem-1480 134 38 at at ADP eurjchem-1480 134 39 the the DET eurjchem-1480 134 40 michigan michigan PROPN eurjchem-1480 134 41 state state PROPN eurjchem-1480 134 42 university university PROPN eurjchem-1480 134 43 , , PUNCT eurjchem-1480 134 44 usa usa PROPN eurjchem-1480 134 45 . . PROPN eurjchem-1480 134 46 references reference NOUN eurjchem-1480 135 1 [ [ X eurjchem-1480 135 2 1 1 NUM eurjchem-1480 135 3 ] ] PUNCT eurjchem-1480 135 4 . . PUNCT eurjchem-1480 136 1 kato kato PROPN eurjchem-1480 136 2 , , PUNCT eurjchem-1480 136 3 m. m. NOUN eurjchem-1480 136 4 ; ; PUNCT eurjchem-1480 136 5 kamigaito kamigaito PROPN eurjchem-1480 136 6 , , PUNCT eurjchem-1480 136 7 m. m. NOUN eurjchem-1480 136 8 ; ; PUNCT eurjchem-1480 136 9 sawamoto sawamoto NOUN eurjchem-1480 136 10 , , PUNCT eurjchem-1480 136 11 m. m. NOUN eurjchem-1480 136 12 ; ; PUNCT eurjchem-1480 136 13 higashimura higashimura NOUN eurjchem-1480 136 14 , , PUNCT eurjchem-1480 136 15 t. t. NOUN eurjchem-1480 136 16 macromolecules macromolecule NOUN eurjchem-1480 136 17 1995 1995 NUM eurjchem-1480 136 18 , , PUNCT eurjchem-1480 136 19 28(5 28(5 NUM eurjchem-1480 136 20 ) ) PUNCT eurjchem-1480 136 21 , , PUNCT eurjchem-1480 136 22 1721‐1723 1721‐1723 NUM eurjchem-1480 136 23 . . PUNCT eurjchem-1480 137 1 [ [ X eurjchem-1480 137 2 2 2 NUM eurjchem-1480 137 3 ] ] PUNCT eurjchem-1480 137 4 . . PUNCT eurjchem-1480 138 1 wang wang PROPN eurjchem-1480 138 2 , , PUNCT eurjchem-1480 138 3 j. j. PROPN eurjchem-1480 138 4 s. s. PROPN eurjchem-1480 138 5 ; ; PUNCT eurjchem-1480 138 6 matyjaszewski matyjaszewski PROPN eurjchem-1480 138 7 , , PUNCT eurjchem-1480 138 8 k. k. PROPN eurjchem-1480 138 9 amer amer PROPN eurjchem-1480 138 10 . . PROPN eurjchem-1480 138 11 chem chem PROPN eurjchem-1480 138 12 . . PUNCT eurjchem-1480 139 1 soc soc PROPN eurjchem-1480 139 2 . . PUNCT eurjchem-1480 140 1 1995 1995 NUM eurjchem-1480 140 2 , , PUNCT eurjchem-1480 140 3 117(20 117(20 NUM eurjchem-1480 140 4 ) ) PUNCT eurjchem-1480 140 5 , , PUNCT eurjchem-1480 140 6 5614‐ 5614‐ NUM eurjchem-1480 140 7 5615 5615 NUM eurjchem-1480 140 8 . . PUNCT eurjchem-1480 141 1 [ [ X eurjchem-1480 141 2 3 3 NUM eurjchem-1480 141 3 ] ] PUNCT eurjchem-1480 141 4 . . PUNCT eurjchem-1480 142 1 matyjaszewski matyjaszewski PROPN eurjchem-1480 142 2 , , PUNCT eurjchem-1480 142 3 k. k. PROPN eurjchem-1480 142 4 controlled‐living controlled‐live VERB eurjchem-1480 142 5 radical radical ADJ eurjchem-1480 142 6 polymerization polymerization NOUN eurjchem-1480 142 7 : : PUNCT eurjchem-1480 142 8 progress progress NOUN eurjchem-1480 142 9 in in ADP eurjchem-1480 142 10 atrp atrp NOUN eurjchem-1480 142 11 , , PUNCT eurjchem-1480 143 1 american american PROPN eurjchem-1480 143 2 chemical chemical PROPN eurjchem-1480 143 3 society society PROPN eurjchem-1480 143 4 ( ( PUNCT eurjchem-1480 143 5 publisher publisher NOUN eurjchem-1480 143 6 ) ) PUNCT eurjchem-1480 143 7 ; ; PUNCT eurjchem-1480 143 8 washington washington PROPN eurjchem-1480 143 9 , , PUNCT eurjchem-1480 143 10 d.c d.c PROPN eurjchem-1480 143 11 . . PROPN eurjchem-1480 143 12 , , PUNCT eurjchem-1480 143 13 2009 2009 NUM eurjchem-1480 143 14 , , PUNCT eurjchem-1480 143 15 isbn isbn NOUN eurjchem-1480 143 16 : : PUNCT eurjchem-1480 143 17 978‐0‐8412‐6995‐8 978‐0‐8412‐6995‐8 NUM eurjchem-1480 144 1 . . PUNCT eurjchem-1480 145 1 [ [ X eurjchem-1480 145 2 4 4 NUM eurjchem-1480 145 3 ] ] PUNCT eurjchem-1480 145 4 . . PUNCT eurjchem-1480 145 5 bharathwaj bharathwaj PROPN eurjchem-1480 145 6 , , PUNCT eurjchem-1480 145 7 r. r. PROPN eurjchem-1480 145 8 ; ; PUNCT eurjchem-1480 145 9 natarajan natarajan PROPN eurjchem-1480 145 10 , , PUNCT eurjchem-1480 145 11 u. u. PROPN eurjchem-1480 145 12 ; ; PUNCT eurjchem-1480 145 13 dhamodharan dhamodharan VERB eurjchem-1480 145 14 , , PUNCT eurjchem-1480 145 15 r. r. PROPN eurjchem-1480 145 16 appl appl PROPN eurjchem-1480 145 17 . . PROPN eurjchem-1480 146 1 clay clay PROPN eurjchem-1480 146 2 sci sci PROPN eurjchem-1480 146 3 . . PROPN eurjchem-1480 146 4 2010 2010 NUM eurjchem-1480 146 5 , , PUNCT eurjchem-1480 146 6 48(3 48(3 NOUN eurjchem-1480 146 7 ) ) PUNCT eurjchem-1480 146 8 , , PUNCT eurjchem-1480 146 9 300‐306 300‐306 NUM eurjchem-1480 146 10 . . PUNCT eurjchem-1480 147 1 [ [ X eurjchem-1480 147 2 5 5 NUM eurjchem-1480 147 3 ] ] PUNCT eurjchem-1480 147 4 . . PUNCT eurjchem-1480 148 1 he he PRON eurjchem-1480 148 2 , , PUNCT eurjchem-1480 148 3 w. w. PROPN eurjchem-1480 148 4 ; ; PUNCT eurjchem-1480 148 5 zhang zhang PROPN eurjchem-1480 148 6 , , PUNCT eurjchem-1480 148 7 l. l. PROPN eurjchem-1480 148 8 ; ; PUNCT eurjchem-1480 148 9 zhu zhu PROPN eurjchem-1480 148 10 , , PUNCT eurjchem-1480 148 11 g. g. PROPN eurjchem-1480 148 12 ; ; PUNCT eurjchem-1480 148 13 zhang zhang PROPN eurjchem-1480 148 14 , , PUNCT eurjchem-1480 148 15 z. z. PROPN eurjchem-1480 148 16 ; ; PUNCT eurjchem-1480 148 17 zhou zhou PROPN eurjchem-1480 148 18 , , PUNCT eurjchem-1480 148 19 n. n. PROPN eurjchem-1480 148 20 ; ; PUNCT eurjchem-1480 148 21 cheng cheng PROPN eurjchem-1480 148 22 , , PUNCT eurjchem-1480 148 23 z. z. PROPN eurjchem-1480 148 24 ; ; PUNCT eurjchem-1480 148 25 zhu zhu PROPN eurjchem-1480 148 26 , , PUNCT eurjchem-1480 148 27 x. x. PROPN eurjchem-1480 148 28 j. j. PROPN eurjchem-1480 148 29 control control PROPN eurjchem-1480 148 30 . . PUNCT eurjchem-1480 149 1 release release VERB eurjchem-1480 149 2 2011 2011 NUM eurjchem-1480 149 3 , , PUNCT eurjchem-1480 149 4 152 152 NUM eurjchem-1480 149 5 , , PUNCT eurjchem-1480 149 6 192‐269 192‐269 NUM eurjchem-1480 149 7 . . PUNCT eurjchem-1480 150 1 [ [ X eurjchem-1480 150 2 6 6 NUM eurjchem-1480 150 3 ] ] PUNCT eurjchem-1480 150 4 . . PUNCT eurjchem-1480 151 1 fu fu PROPN eurjchem-1480 151 2 , , PUNCT eurjchem-1480 151 3 y. y. PROPN eurjchem-1480 151 4 ; ; PUNCT eurjchem-1480 151 5 li li PROPN eurjchem-1480 151 6 , , PUNCT eurjchem-1480 151 7 g. g. PROPN eurjchem-1480 151 8 ; ; PUNCT eurjchem-1480 151 9 yu yu PROPN eurjchem-1480 151 10 , , PUNCT eurjchem-1480 151 11 h. h. PROPN eurjchem-1480 151 12 ; ; PUNCT eurjchem-1480 151 13 liu liu PROPN eurjchem-1480 151 14 , , PUNCT eurjchem-1480 151 15 y. y. PROPN eurjchem-1480 151 16 appl appl PROPN eurjchem-1480 151 17 . . PUNCT eurjchem-1480 152 1 surf surf PROPN eurjchem-1480 152 2 . . PUNCT eurjchem-1480 153 1 sci sci PROPN eurjchem-1480 153 2 . . PROPN eurjchem-1480 153 3 2012 2012 NUM eurjchem-1480 153 4 , , PUNCT eurjchem-1480 153 5 258(7 258(7 NUM eurjchem-1480 153 6 ) ) PUNCT eurjchem-1480 153 7 , , PUNCT eurjchem-1480 153 8 2529‐2533 2529‐2533 NUM eurjchem-1480 153 9 . . PUNCT eurjchem-1480 154 1 [ [ X eurjchem-1480 154 2 7 7 NUM eurjchem-1480 154 3 ] ] PUNCT eurjchem-1480 154 4 . . PUNCT eurjchem-1480 155 1 vivek vivek PROPN eurjchem-1480 155 2 , , PUNCT eurjchem-1480 155 3 a. a. NOUN eurjchem-1480 155 4 v. v. PROPN eurjchem-1480 155 5 ; ; PUNCT eurjchem-1480 155 6 dhamodharan dhamodharan VERB eurjchem-1480 155 7 , , PUNCT eurjchem-1480 155 8 r. r. PROPN eurjchem-1480 155 9 react react PROPN eurjchem-1480 155 10 . . PUNCT eurjchem-1480 156 1 funct funct INTJ eurjchem-1480 156 2 . . PUNCT eurjchem-1480 157 1 polym polym NOUN eurjchem-1480 157 2 . . PUNCT eurjchem-1480 158 1 2008 2008 NUM eurjchem-1480 158 2 , , PUNCT eurjchem-1480 158 3 68(5 68(5 NUM eurjchem-1480 158 4 ) ) PUNCT eurjchem-1480 158 5 , , PUNCT eurjchem-1480 159 1 967‐ 967‐ NUM eurjchem-1480 159 2 973 973 NUM eurjchem-1480 159 3 . . PUNCT eurjchem-1480 160 1 [ [ X eurjchem-1480 160 2 8 8 NUM eurjchem-1480 160 3 ] ] PUNCT eurjchem-1480 160 4 . . PUNCT eurjchem-1480 161 1 zheng zheng PROPN eurjchem-1480 161 2 , , PUNCT eurjchem-1480 161 3 a. a. PROPN eurjchem-1480 161 4 ; ; PUNCT eurjchem-1480 161 5 xue xue PROPN eurjchem-1480 161 6 , , PUNCT eurjchem-1480 161 7 y. y. PROPN eurjchem-1480 161 8 ; ; PUNCT eurjchem-1480 161 9 wei wei PROPN eurjchem-1480 161 10 , , PUNCT eurjchem-1480 161 11 d. d. PROPN eurjchem-1480 161 12 ; ; PUNCT eurjchem-1480 161 13 guan guan PROPN eurjchem-1480 161 14 , , PUNCT eurjchem-1480 161 15 y. y. PROPN eurjchem-1480 161 16 ; ; PUNCT eurjchem-1480 161 17 xiao xiao PROPN eurjchem-1480 161 18 , , PUNCT eurjchem-1480 161 19 h. h. PROPN eurjchem-1480 161 20 mater mater PROPN eurjchem-1480 161 21 . . PUNCT eurjchem-1480 162 1 sci sci PROPN eurjchem-1480 162 2 . . PUNCT eurjchem-1480 163 1 eng eng PROPN eurjchem-1480 163 2 . . PROPN eurjchem-1480 163 3 2013 2013 NUM eurjchem-1480 163 4 , , PUNCT eurjchem-1480 163 5 33(1 33(1 NUM eurjchem-1480 163 6 ) ) PUNCT eurjchem-1480 163 7 , , PUNCT eurjchem-1480 163 8 519‐526 519‐526 NUM eurjchem-1480 163 9 . . PUNCT eurjchem-1480 164 1 [ [ X eurjchem-1480 164 2 9 9 NUM eurjchem-1480 164 3 ] ] PUNCT eurjchem-1480 164 4 . . PUNCT eurjchem-1480 165 1 matyjaszewski matyjaszewski PROPN eurjchem-1480 165 2 , , PUNCT eurjchem-1480 165 3 k. k. PROPN eurjchem-1480 165 4 ; ; PUNCT eurjchem-1480 165 5 xia xia PROPN eurjchem-1480 165 6 , , PUNCT eurjchem-1480 165 7 j. j. PROPN eurjchem-1480 165 8 chem chem PROPN eurjchem-1480 165 9 . . PUNCT eurjchem-1480 166 1 rev rev PROPN eurjchem-1480 166 2 . . PROPN eurjchem-1480 166 3 2001 2001 NUM eurjchem-1480 166 4 , , PUNCT eurjchem-1480 166 5 101(9 101(9 NUM eurjchem-1480 166 6 ) ) PUNCT eurjchem-1480 166 7 , , PUNCT eurjchem-1480 166 8 2921‐2990 2921‐2990 X eurjchem-1480 166 9 . . PUNCT eurjchem-1480 167 1 [ [ X eurjchem-1480 167 2 10 10 NUM eurjchem-1480 167 3 ] ] PUNCT eurjchem-1480 167 4 . . PUNCT eurjchem-1480 168 1 al‐mayahi al‐mayahi PROPN eurjchem-1480 168 2 , , PUNCT eurjchem-1480 168 3 b. b. PROPN eurjchem-1480 168 4 a. a. PROPN eurjchem-1480 168 5 ; ; PUNCT eurjchem-1480 168 6 al‐lami al‐lami PROPN eurjchem-1480 168 7 , , PUNCT eurjchem-1480 168 8 h. h. PROPN eurjchem-1480 168 9 s. s. PROPN eurjchem-1480 168 10 ; ; PUNCT eurjchem-1480 168 11 haddad haddad PROPN eurjchem-1480 168 12 , , PUNCT eurjchem-1480 168 13 a. a. NOUN eurjchem-1480 168 14 m. m. NOUN eurjchem-1480 168 15 res res PROPN eurjchem-1480 168 16 . . PUNCT eurjchem-1480 169 1 j. j. PROPN eurjchem-1480 169 2 pharm pharm PROPN eurjchem-1480 169 3 . . PUNCT eurjchem-1480 170 1 biol biol PROPN eurjchem-1480 170 2 . . PUNCT eurjchem-1480 171 1 chem chem PROPN eurjchem-1480 171 2 . . PUNCT eurjchem-1480 172 1 sci sci PROPN eurjchem-1480 172 2 . . PROPN eurjchem-1480 172 3 2015 2015 NUM eurjchem-1480 172 4 , , PUNCT eurjchem-1480 172 5 6(6 6(6 NOUN eurjchem-1480 172 6 ) ) PUNCT eurjchem-1480 172 7 , , PUNCT eurjchem-1480 172 8 1269‐1273 1269‐1273 NUM eurjchem-1480 172 9 . . PUNCT