id	sid	tid	token	lemma	pos
eurjchem-1508	1	1	untitled	untitle	VERB
eurjchem-1508	1	2	european	european	PROPN
eurjchem-1508	1	3	journal	journal	PROPN
eurjchem-1508	1	4	of	of	ADP
eurjchem-1508	1	5	chemistry	chemistry	NOUN
eurjchem-1508	1	6	7	7	NUM
eurjchem-1508	1	7	(	(	PUNCT
eurjchem-1508	1	8	4	4	NUM
eurjchem-1508	1	9	)	)	PUNCT
eurjchem-1508	1	10	(	(	PUNCT
eurjchem-1508	1	11	2016	2016	NUM
eurjchem-1508	1	12	)	)	PUNCT
eurjchem-1508	1	13	468‐472	468‐472	PROPN
eurjchem-1508	1	14	european	european	PROPN
eurjchem-1508	1	15	journal	journal	PROPN
eurjchem-1508	1	16	of	of	ADP
eurjchem-1508	1	17	chemistry	chemistry	NOUN
eurjchem-1508	1	18	issn	issn	PROPN
eurjchem-1508	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-1508	1	20	(	(	PUNCT
eurjchem-1508	1	21	print	print	NOUN
eurjchem-1508	1	22	)	)	PUNCT
eurjchem-1508	1	23	/	/	SYM
eurjchem-1508	1	24	issn	issn	PROPN
eurjchem-1508	1	25	2153‐2257	2153‐2257	NUM
eurjchem-1508	1	26	(	(	PUNCT
eurjchem-1508	1	27	online	online	ADJ
eurjchem-1508	1	28	)	)	PUNCT
eurjchem-1508	1	29			NOUN
eurjchem-1508	1	30	2016	2016	NUM
eurjchem-1508	1	31	atlanta	atlanta	PROPN
eurjchem-1508	1	32	publishing	publishing	PROPN
eurjchem-1508	1	33	house	house	PROPN
eurjchem-1508	1	34	llc	llc	PROPN
eurjchem-1508	1	35	‐	‐	PUNCT
eurjchem-1508	1	36	all	all	DET
eurjchem-1508	1	37	rights	right	NOUN
eurjchem-1508	1	38	reserved	reserve	VERB
eurjchem-1508	1	39	‐	‐	NOUN
eurjchem-1508	1	40	printed	print	VERB
eurjchem-1508	1	41	in	in	ADP
eurjchem-1508	1	42	the	the	DET
eurjchem-1508	1	43	usa	usa	PROPN
eurjchem-1508	1	44	http://dx.doi.org/10.5155/eurjchem.7.4.468-472.1508	http://dx.doi.org/10.5155/eurjchem.7.4.468-472.1508	PROPN
eurjchem-1508	1	45	european	european	PROPN
eurjchem-1508	1	46	journal	journal	PROPN
eurjchem-1508	1	47	of	of	ADP
eurjchem-1508	1	48	chemistry	chemistry	PROPN
eurjchem-1508	1	49	journal	journal	PROPN
eurjchem-1508	1	50	webpage	webpage	NOUN
eurjchem-1508	1	51	:	:	PUNCT
eurjchem-1508	1	52	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1508	1	53	multicomponent	multicomponent	PROPN
eurjchem-1508	1	54	reactions	reaction	NOUN
eurjchem-1508	1	55	under	under	ADP
eurjchem-1508	1	56	increased	increase	VERB
eurjchem-1508	1	57	pressure	pressure	NOUN
eurjchem-1508	1	58	:	:	PUNCT
eurjchem-1508	1	59	on	on	ADP
eurjchem-1508	1	60	the	the	DET
eurjchem-1508	1	61	reaction	reaction	NOUN
eurjchem-1508	1	62	of	of	ADP
eurjchem-1508	1	63	arylhydrazonals	arylhydrazonal	NOUN
eurjchem-1508	1	64	,	,	PUNCT
eurjchem-1508	1	65	aromatic	aromatic	ADJ
eurjchem-1508	1	66	aldehydes	aldehyde	NOUN
eurjchem-1508	1	67	and	and	CCONJ
eurjchem-1508	1	68	malononitrile	malononitrile	NOUN
eurjchem-1508	1	69	in	in	ADP
eurjchem-1508	1	70	q‐tube	q‐tube	NUM
eurjchem-1508	1	71	kamal	kamal	PROPN
eurjchem-1508	1	72	usef	usef	PROPN
eurjchem-1508	1	73	sadek	sadek	PROPN
eurjchem-1508	1	74	1	1	NUM
eurjchem-1508	1	75	,	,	PUNCT
eurjchem-1508	1	76	*	*	PROPN
eurjchem-1508	1	77	,	,	PUNCT
eurjchem-1508	1	78	maghraby	maghraby	PROPN
eurjchem-1508	1	79	ali	ali	PROPN
eurjchem-1508	1	80	selim	selim	PROPN
eurjchem-1508	1	81	2	2	NUM
eurjchem-1508	1	82	,	,	PUNCT
eurjchem-1508	1	83	abdul‐aziz	abdul‐aziz	PUNCT
eurjchem-1508	1	84	alnajjar	alnajjar	PROPN
eurjchem-1508	1	85	3	3	NUM
eurjchem-1508	1	86	,	,	PUNCT
eurjchem-1508	1	87	mohamed	mohamed	PROPN
eurjchem-1508	1	88	atallah	atallah	PROPN
eurjchem-1508	1	89	2	2	PROPN
eurjchem-1508	1	90	and	and	CCONJ
eurjchem-1508	1	91	mohamed	mohame	VERB
eurjchem-1508	1	92	hilmy	hilmy	PRON
eurjchem-1508	1	93	elnagdi	elnagdi	VERB
eurjchem-1508	1	94	4	4	NUM
eurjchem-1508	1	95	1	1	NUM
eurjchem-1508	1	96	chemistry	chemistry	NOUN
eurjchem-1508	1	97	department	department	NOUN
eurjchem-1508	1	98	,	,	PUNCT
eurjchem-1508	1	99	faculty	faculty	NOUN
eurjchem-1508	1	100	of	of	ADP
eurjchem-1508	1	101	science	science	NOUN
eurjchem-1508	1	102	,	,	PUNCT
eurjchem-1508	1	103	minia	minia	NOUN
eurjchem-1508	1	104	university	university	NOUN
eurjchem-1508	1	105	,	,	PUNCT
eurjchem-1508	1	106	61519	61519	NUM
eurjchem-1508	1	107	,	,	PUNCT
eurjchem-1508	1	108	minia	minia	NOUN
eurjchem-1508	1	109	,	,	PUNCT
eurjchem-1508	1	110	egypt	egypt	PROPN
eurjchem-1508	1	111	2	2	NUM
eurjchem-1508	1	112	chemistry	chemistry	NOUN
eurjchem-1508	1	113	department	department	NOUN
eurjchem-1508	1	114	,	,	PUNCT
eurjchem-1508	1	115	faculty	faculty	NOUN
eurjchem-1508	1	116	of	of	ADP
eurjchem-1508	1	117	science	science	NOUN
eurjchem-1508	1	118	at	at	ADP
eurjchem-1508	1	119	qena	qena	PROPN
eurjchem-1508	1	120	,	,	PUNCT
eurjchem-1508	1	121	south	south	PROPN
eurjchem-1508	1	122	valley	valley	PROPN
eurjchem-1508	1	123	university	university	PROPN
eurjchem-1508	1	124	,	,	PUNCT
eurjchem-1508	1	125	83512	83512	NUM
eurjchem-1508	1	126	,	,	PUNCT
eurjchem-1508	1	127	qena	qena	PROPN
eurjchem-1508	1	128	,	,	PUNCT
eurjchem-1508	1	129	egypt	egypt	PROPN
eurjchem-1508	1	130	3	3	NUM
eurjchem-1508	1	131	applied	apply	VERB
eurjchem-1508	1	132	science	science	NOUN
eurjchem-1508	1	133	department	department	NOUN
eurjchem-1508	1	134	,	,	PUNCT
eurjchem-1508	1	135	college	college	NOUN
eurjchem-1508	1	136	of	of	ADP
eurjchem-1508	1	137	technological	technological	ADJ
eurjchem-1508	1	138	studies	study	NOUN
eurjchem-1508	1	139	,	,	PUNCT
eurjchem-1508	1	140	public	public	ADJ
eurjchem-1508	1	141	authority	authority	NOUN
eurjchem-1508	1	142	for	for	ADP
eurjchem-1508	1	143	applied	apply	VERB
eurjchem-1508	1	144	education	education	NOUN
eurjchem-1508	1	145	and	and	CCONJ
eurjchem-1508	1	146	training	training	NOUN
eurjchem-1508	1	147	,	,	PUNCT
eurjchem-1508	1	148	13060	13060	NUM
eurjchem-1508	1	149	,	,	PUNCT
eurjchem-1508	1	150	safat	safat	NOUN
eurjchem-1508	1	151	,	,	PUNCT
eurjchem-1508	1	152	kuwait	kuwait	PROPN
eurjchem-1508	1	153	4	4	NUM
eurjchem-1508	1	154	chemistry	chemistry	NOUN
eurjchem-1508	1	155	department	department	NOUN
eurjchem-1508	1	156	,	,	PUNCT
eurjchem-1508	1	157	faculty	faculty	NOUN
eurjchem-1508	1	158	of	of	ADP
eurjchem-1508	1	159	science	science	NOUN
eurjchem-1508	1	160	,	,	PUNCT
eurjchem-1508	1	161	cairo	cairo	PROPN
eurjchem-1508	1	162	university	university	PROPN
eurjchem-1508	1	163	,	,	PUNCT
eurjchem-1508	1	164	12613	12613	NUM
eurjchem-1508	1	165	,	,	PUNCT
eurjchem-1508	1	166	giza	giza	PROPN
eurjchem-1508	1	167	,	,	PUNCT
eurjchem-1508	1	168	egypt	egypt	PROPN
eurjchem-1508	1	169	*	*	PUNCT
eurjchem-1508	1	170	corresponding	correspond	VERB
eurjchem-1508	1	171	author	author	NOUN
eurjchem-1508	1	172	at	at	ADP
eurjchem-1508	1	173	:	:	PUNCT
eurjchem-1508	1	174	chemistry	chemistry	NOUN
eurjchem-1508	1	175	department	department	NOUN
eurjchem-1508	1	176	,	,	PUNCT
eurjchem-1508	1	177	faculty	faculty	NOUN
eurjchem-1508	1	178	of	of	ADP
eurjchem-1508	1	179	science	science	NOUN
eurjchem-1508	1	180	,	,	PUNCT
eurjchem-1508	1	181	minia	minia	NOUN
eurjchem-1508	1	182	university	university	NOUN
eurjchem-1508	1	183	,	,	PUNCT
eurjchem-1508	1	184	61519	61519	NUM
eurjchem-1508	1	185	,	,	PUNCT
eurjchem-1508	1	186	minia	minia	NOUN
eurjchem-1508	1	187	,	,	PUNCT
eurjchem-1508	1	188	egypt	egypt	PROPN
eurjchem-1508	1	189	.	.	PUNCT
eurjchem-1508	2	1	tel	tel	PROPN
eurjchem-1508	2	2	.	.	PUNCT
eurjchem-1508	2	3	:	:	PUNCT
eurjchem-1508	3	1	+2.086.2364806	+2.086.2364806	PROPN
eurjchem-1508	3	2	.	.	PROPN
eurjchem-1508	3	3	fax	fax	NOUN
eurjchem-1508	3	4	:	:	PUNCT
eurjchem-1508	3	5	+2.086.2363011	+2.086.2363011	NUM
eurjchem-1508	3	6	.	.	PUNCT
eurjchem-1508	3	7	e‐mail	e‐mail	PUNCT
eurjchem-1508	4	1	address	address	NOUN
eurjchem-1508	4	2	:	:	PUNCT
eurjchem-1508	4	3	kusadek@yahoo.com	kusadek@yahoo.com	PROPN
eurjchem-1508	4	4	(	(	PUNCT
eurjchem-1508	4	5	k.u	k.u	PROPN
eurjchem-1508	4	6	.	.	PROPN
eurjchem-1508	4	7	sadek	sadek	PROPN
eurjchem-1508	4	8	)	)	PUNCT
eurjchem-1508	4	9	.	.	PUNCT
eurjchem-1508	5	1	article	article	NOUN
eurjchem-1508	5	2	information	information	PROPN
eurjchem-1508	5	3	abstract	abstract	ADJ
eurjchem-1508	5	4	doi	doi	PROPN
eurjchem-1508	5	5	:	:	PUNCT
eurjchem-1508	5	6	 	 	SPACE
eurjchem-1508	5	7	10.5155	10.5155	NUM
eurjchem-1508	5	8	/	/	SYM
eurjchem-1508	5	9	eurjchem.7.4.468	eurjchem.7.4.468	NOUN
eurjchem-1508	5	10	-	-	PUNCT
eurjchem-1508	5	11	472.1508	472.1508	NUM
eurjchem-1508	5	12	received	receive	VERB
eurjchem-1508	5	13	:	:	PUNCT
eurjchem-1508	5	14	11	11	NUM
eurjchem-1508	5	15	november	november	PROPN
eurjchem-1508	5	16	2016	2016	NUM
eurjchem-1508	5	17	received	receive	VERB
eurjchem-1508	5	18	in	in	ADP
eurjchem-1508	5	19	revised	revise	VERB
eurjchem-1508	5	20	form	form	NOUN
eurjchem-1508	5	21	:	:	PUNCT
eurjchem-1508	5	22	21	21	NUM
eurjchem-1508	5	23	november	november	PROPN
eurjchem-1508	5	24	2016	2016	NUM
eurjchem-1508	5	25	accepted	accept	VERB
eurjchem-1508	5	26	:	:	PUNCT
eurjchem-1508	5	27	03	03	NUM
eurjchem-1508	5	28	december	december	PROPN
eurjchem-1508	5	29	2016	2016	NUM
eurjchem-1508	5	30	published	publish	VERB
eurjchem-1508	5	31	online	online	ADV
eurjchem-1508	5	32	:	:	PUNCT
eurjchem-1508	5	33	31	31	NUM
eurjchem-1508	5	34	december	december	PROPN
eurjchem-1508	5	35	2016	2016	NUM
eurjchem-1508	5	36	printed	print	VERB
eurjchem-1508	5	37	:	:	PUNCT
eurjchem-1508	5	38	31	31	NUM
eurjchem-1508	5	39	december	december	PROPN
eurjchem-1508	5	40	2016	2016	NUM
eurjchem-1508	5	41	  	  	SPACE
eurjchem-1508	5	42	a	a	DET
eurjchem-1508	5	43	novel	novel	ADJ
eurjchem-1508	5	44	multi‐component	multi‐component	NOUN
eurjchem-1508	5	45	reaction	reaction	NOUN
eurjchem-1508	5	46	between	between	ADP
eurjchem-1508	5	47	arylhydrazonals	arylhydrazonal	NOUN
eurjchem-1508	5	48	,	,	PUNCT
eurjchem-1508	5	49	malononitrile	malononitrile	NOUN
eurjchem-1508	5	50	and	and	CCONJ
eurjchem-1508	5	51	aromatic	aromatic	ADJ
eurjchem-1508	5	52	aldehydes	aldehyde	NOUN
eurjchem-1508	5	53	under	under	ADP
eurjchem-1508	5	54	high	high	ADJ
eurjchem-1508	5	55	pressure	pressure	NOUN
eurjchem-1508	5	56	utilizing	utilize	VERB
eurjchem-1508	5	57	q‐tube	q‐tube	NUM
eurjchem-1508	5	58	was	be	AUX
eurjchem-1508	5	59	carried	carry	VERB
eurjchem-1508	5	60	out	out	ADP
eurjchem-1508	5	61	.	.	PUNCT
eurjchem-1508	6	1	the	the	DET
eurjchem-1508	6	2	reaction	reaction	NOUN
eurjchem-1508	6	3	of	of	ADP
eurjchem-1508	6	4	arylhydrazonal	arylhydrazonal	ADJ
eurjchem-1508	6	5	(	(	PUNCT
eurjchem-1508	6	6	1j	1j	NUM
eurjchem-1508	6	7	)	)	PUNCT
eurjchem-1508	6	8	with	with	ADP
eurjchem-1508	6	9	malononitrile	malononitrile	NOUN
eurjchem-1508	6	10	and	and	CCONJ
eurjchem-1508	6	11	aromatic	aromatic	ADJ
eurjchem-1508	6	12	aldehydes	aldehyde	NOUN
eurjchem-1508	6	13	afforded	afford	VERB
eurjchem-1508	6	14	the	the	DET
eurjchem-1508	6	15	corresponding	corresponding	ADJ
eurjchem-1508	6	16	biphenyl	biphenyl	NOUN
eurjchem-1508	6	17	derivatives	derivative	NOUN
eurjchem-1508	6	18	(	(	PUNCT
eurjchem-1508	6	19	4	4	NUM
eurjchem-1508	6	20	)	)	PUNCT
eurjchem-1508	6	21	.	.	PUNCT
eurjchem-1508	7	1	however	however	ADV
eurjchem-1508	7	2	,	,	PUNCT
eurjchem-1508	7	3	compound	compound	NOUN
eurjchem-1508	7	4	1h	1h	NUM
eurjchem-1508	7	5	reacted	react	VERB
eurjchem-1508	7	6	with	with	ADP
eurjchem-1508	7	7	malononitrile	malononitrile	NOUN
eurjchem-1508	7	8	and	and	CCONJ
eurjchem-1508	7	9	aromatic	aromatic	ADJ
eurjchem-1508	7	10	aldehydes	aldehyde	NOUN
eurjchem-1508	7	11	(	(	PUNCT
eurjchem-1508	7	12	7	7	NUM
eurjchem-1508	7	13	)	)	PUNCT
eurjchem-1508	7	14	to	to	PART
eurjchem-1508	7	15	afford	afford	VERB
eurjchem-1508	7	16	pyridazino[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	pyridazino[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	NOUN
eurjchem-1508	7	17	derivatives	derivative	NOUN
eurjchem-1508	7	18	(	(	PUNCT
eurjchem-1508	7	19	8)	8)	NUM
eurjchem-1508	7	20	.	.	PUNCT
eurjchem-1508	8	1	in	in	ADP
eurjchem-1508	8	2	contrast	contrast	NOUN
eurjchem-1508	8	3	,	,	PUNCT
eurjchem-1508	8	4	the	the	DET
eurjchem-1508	8	5	arylhydrazonal	arylhydrazonal	ADJ
eurjchem-1508	8	6	(	(	PUNCT
eurjchem-1508	8	7	1k	1k	NUM
eurjchem-1508	8	8	)	)	PUNCT
eurjchem-1508	8	9	at	at	ADP
eurjchem-1508	8	10	the	the	DET
eurjchem-1508	8	11	same	same	ADJ
eurjchem-1508	8	12	reaction	reaction	NOUN
eurjchem-1508	8	13	conditions	condition	NOUN
eurjchem-1508	8	14	afforded	afford	VERB
eurjchem-1508	8	15	the	the	DET
eurjchem-1508	8	16	corresponding	correspond	VERB
eurjchem-1508	8	17	pyridazinoquinazoline	pyridazinoquinazoline	NOUN
eurjchem-1508	8	18	derivative	derivative	NOUN
eurjchem-1508	8	19	(	(	PUNCT
eurjchem-1508	8	20	22	22	NUM
eurjchem-1508	8	21	)	)	PUNCT
eurjchem-1508	8	22	.	.	PUNCT
eurjchem-1508	9	1	a	a	DET
eurjchem-1508	9	2	rationalization	rationalization	NOUN
eurjchem-1508	9	3	for	for	ADP
eurjchem-1508	9	4	the	the	DET
eurjchem-1508	9	5	difference	difference	NOUN
eurjchem-1508	9	6	in	in	ADP
eurjchem-1508	9	7	behavior	behavior	NOUN
eurjchem-1508	9	8	for	for	ADP
eurjchem-1508	9	9	reaction	reaction	NOUN
eurjchem-1508	9	10	of	of	ADP
eurjchem-1508	9	11	compounds	compound	NOUN
eurjchem-1508	9	12	1h‐k	1h‐k	PROPN
eurjchem-1508	9	13	with	with	ADP
eurjchem-1508	9	14	malononitrile	malononitrile	NOUN
eurjchem-1508	9	15	and	and	CCONJ
eurjchem-1508	9	16	aromatic	aromatic	ADJ
eurjchem-1508	9	17	aldehydes	aldehyde	NOUN
eurjchem-1508	9	18	was	be	AUX
eurjchem-1508	9	19	postulated	postulate	VERB
eurjchem-1508	9	20	.	.	PUNCT
eurjchem-1508	10	1	based	base	VERB
eurjchem-1508	10	2	on	on	ADP
eurjchem-1508	10	3	these	these	DET
eurjchem-1508	10	4	findings	finding	NOUN
eurjchem-1508	10	5	a	a	DET
eurjchem-1508	10	6	mechanism	mechanism	NOUN
eurjchem-1508	10	7	to	to	PART
eurjchem-1508	10	8	account	account	VERB
eurjchem-1508	10	9	for	for	ADP
eurjchem-1508	10	10	the	the	DET
eurjchem-1508	10	11	formation	formation	NOUN
eurjchem-1508	10	12	of	of	ADP
eurjchem-1508	10	13	the	the	DET
eurjchem-1508	10	14	reaction	reaction	NOUN
eurjchem-1508	10	15	products	product	NOUN
eurjchem-1508	10	16	is	be	AUX
eurjchem-1508	10	17	suggested	suggest	VERB
eurjchem-1508	10	18	excluding	exclude	VERB
eurjchem-1508	10	19	possible	possible	ADJ
eurjchem-1508	10	20	initial	initial	ADJ
eurjchem-1508	10	21	dimerization	dimerization	NOUN
eurjchem-1508	10	22	of	of	ADP
eurjchem-1508	10	23	malononitrile	malononitrile	NOUN
eurjchem-1508	10	24	as	as	SCONJ
eurjchem-1508	10	25	has	have	AUX
eurjchem-1508	10	26	been	be	AUX
eurjchem-1508	10	27	previously	previously	ADV
eurjchem-1508	10	28	reported	report	VERB
eurjchem-1508	10	29	.	.	PUNCT
eurjchem-1508	11	1	keywords	keyword	NOUN
eurjchem-1508	11	2	q‐tubes	q‐tubes	PUNCT
eurjchem-1508	11	3	azaenamines	azaenamine	NOUN
eurjchem-1508	11	4	arylhydrazonals	arylhydrazonal	NOUN
eurjchem-1508	11	5	biphenyl	biphenyl	NOUN
eurjchem-1508	11	6	derivatives	derivative	NOUN
eurjchem-1508	11	7	pyridazino	pyridazino	VERB
eurjchem-1508	11	8	naphthyridine	naphthyridine	NOUN
eurjchem-1508	11	9	reactions	reaction	NOUN
eurjchem-1508	11	10	under	under	ADP
eurjchem-1508	11	11	high	high	ADJ
eurjchem-1508	11	12	pressure	pressure	NOUN
eurjchem-1508	11	13	cite	cite	VERB
eurjchem-1508	11	14	this	this	PRON
eurjchem-1508	11	15	:	:	PUNCT
eurjchem-1508	11	16	eur	eur	PROPN
eurjchem-1508	11	17	.	.	PUNCT
eurjchem-1508	12	1	j.	j.	PROPN
eurjchem-1508	12	2	chem	chem	PROPN
eurjchem-1508	12	3	.	.	PUNCT
eurjchem-1508	13	1	2016	2016	NUM
eurjchem-1508	13	2	,	,	PUNCT
eurjchem-1508	13	3	7(4	7(4	NUM
eurjchem-1508	13	4	)	)	PUNCT
eurjchem-1508	13	5	,	,	PUNCT
eurjchem-1508	13	6	468‐472	468‐472	NOUN
eurjchem-1508	13	7	1	1	X
eurjchem-1508	13	8	.	.	PUNCT
eurjchem-1508	13	9	introduction	introduction	NOUN
eurjchem-1508	13	10	for	for	ADP
eurjchem-1508	13	11	more	more	ADJ
eurjchem-1508	13	12	than	than	ADP
eurjchem-1508	13	13	fifty	fifty	NUM
eurjchem-1508	13	14	years	year	NOUN
eurjchem-1508	13	15	,	,	PUNCT
eurjchem-1508	13	16	we	we	PRON
eurjchem-1508	13	17	have	have	AUX
eurjchem-1508	13	18	emphasized	emphasize	VERB
eurjchem-1508	13	19	on	on	ADP
eurjchem-1508	13	20	devising	devise	VERB
eurjchem-1508	13	21	efficient	efficient	ADJ
eurjchem-1508	13	22	syntheses	synthesis	NOUN
eurjchem-1508	13	23	for	for	ADP
eurjchem-1508	13	24	biologically	biologically	ADV
eurjchem-1508	13	25	relevant	relevant	ADJ
eurjchem-1508	13	26	multifunctional	multifunctional	NOUN
eurjchem-1508	13	27	hetero‐aromatics	hetero‐aromatic	NOUN
eurjchem-1508	13	28	.	.	PUNCT
eurjchem-1508	14	1	our	our	PRON
eurjchem-1508	14	2	contributions	contribution	NOUN
eurjchem-1508	14	3	have	have	AUX
eurjchem-1508	14	4	been	be	AUX
eurjchem-1508	14	5	recently	recently	ADV
eurjchem-1508	14	6	surveyed	survey	VERB
eurjchem-1508	14	7	[	[	X
eurjchem-1508	14	8	1	1	NUM
eurjchem-1508	14	9	]	]	PUNCT
eurjchem-1508	14	10	.	.	PUNCT
eurjchem-1508	15	1	we	we	PRON
eurjchem-1508	15	2	have	have	AUX
eurjchem-1508	15	3	also	also	ADV
eurjchem-1508	15	4	recently	recently	ADV
eurjchem-1508	15	5	surveyed	survey	VERB
eurjchem-1508	15	6	utility	utility	NOUN
eurjchem-1508	15	7	of	of	ADP
eurjchem-1508	15	8	multicomponent	multicomponent	NOUN
eurjchem-1508	15	9	reactions	reaction	NOUN
eurjchem-1508	15	10	in	in	ADP
eurjchem-1508	15	11	our	our	PRON
eurjchem-1508	15	12	area	area	NOUN
eurjchem-1508	15	13	[	[	X
eurjchem-1508	15	14	2	2	NUM
eurjchem-1508	15	15	]	]	PUNCT
eurjchem-1508	15	16	.	.	PUNCT
eurjchem-1508	16	1	since	since	SCONJ
eurjchem-1508	16	2	1997	1997	NUM
eurjchem-1508	16	3	,	,	PUNCT
eurjchem-1508	16	4	we	we	PRON
eurjchem-1508	16	5	investigated	investigate	VERB
eurjchem-1508	16	6	extensively	extensively	ADV
eurjchem-1508	16	7	utility	utility	NOUN
eurjchem-1508	16	8	of	of	ADP
eurjchem-1508	16	9	microwave	microwave	NOUN
eurjchem-1508	16	10	to	to	PART
eurjchem-1508	16	11	accelerate	accelerate	VERB
eurjchem-1508	16	12	reaction	reaction	NOUN
eurjchem-1508	16	13	rates	rate	NOUN
eurjchem-1508	16	14	[	[	X
eurjchem-1508	16	15	3‐6	3‐6	NUM
eurjchem-1508	16	16	]	]	PUNCT
eurjchem-1508	16	17	.	.	PUNCT
eurjchem-1508	17	1	as	as	SCONJ
eurjchem-1508	17	2	we	we	PRON
eurjchem-1508	17	3	became	become	VERB
eurjchem-1508	17	4	convinced	convinced	ADJ
eurjchem-1508	17	5	that	that	SCONJ
eurjchem-1508	17	6	microwave	microwave	NOUN
eurjchem-1508	17	7	techniques	technique	NOUN
eurjchem-1508	17	8	is	be	AUX
eurjchem-1508	17	9	very	very	ADV
eurjchem-1508	17	10	expensive	expensive	ADJ
eurjchem-1508	17	11	to	to	PART
eurjchem-1508	17	12	scale	scale	VERB
eurjchem-1508	17	13	up	up	ADP
eurjchem-1508	17	14	and	and	CCONJ
eurjchem-1508	17	15	it	it	PRON
eurjchem-1508	17	16	is	be	AUX
eurjchem-1508	17	17	just	just	ADV
eurjchem-1508	17	18	allow	allow	VERB
eurjchem-1508	17	19	reactions	reaction	NOUN
eurjchem-1508	17	20	to	to	PART
eurjchem-1508	17	21	proceed	proceed	VERB
eurjchem-1508	17	22	at	at	ADP
eurjchem-1508	17	23	higher	high	ADJ
eurjchem-1508	17	24	temperature	temperature	NOUN
eurjchem-1508	17	25	than	than	ADP
eurjchem-1508	17	26	that	that	PRON
eurjchem-1508	17	27	of	of	ADP
eurjchem-1508	17	28	the	the	DET
eurjchem-1508	17	29	medium	medium	NOUN
eurjchem-1508	17	30	via	via	ADP
eurjchem-1508	17	31	formation	formation	NOUN
eurjchem-1508	17	32	of	of	ADP
eurjchem-1508	17	33	hot	hot	ADJ
eurjchem-1508	17	34	spots	spot	NOUN
eurjchem-1508	17	35	thus	thus	ADV
eurjchem-1508	17	36	increasing	increase	VERB
eurjchem-1508	17	37	the	the	DET
eurjchem-1508	17	38	rate	rate	NOUN
eurjchem-1508	17	39	.	.	PUNCT
eurjchem-1508	18	1	it	it	PRON
eurjchem-1508	18	2	is	be	AUX
eurjchem-1508	18	3	well	well	ADV
eurjchem-1508	18	4	accepted	accept	VERB
eurjchem-1508	18	5	that	that	SCONJ
eurjchem-1508	18	6	every	every	DET
eurjchem-1508	18	7	10	10	NUM
eurjchem-1508	18	8	°	°	NUM
eurjchem-1508	18	9	c	c	NOUN
eurjchem-1508	18	10	increase	increase	NOUN
eurjchem-1508	18	11	in	in	ADP
eurjchem-1508	18	12	temperature	temperature	NOUN
eurjchem-1508	18	13	of	of	ADP
eurjchem-1508	18	14	reaction	reaction	NOUN
eurjchem-1508	18	15	mixture	mixture	NOUN
eurjchem-1508	18	16	duplicate	duplicate	VERB
eurjchem-1508	18	17	the	the	DET
eurjchem-1508	18	18	rate	rate	NOUN
eurjchem-1508	18	19	[	[	X
eurjchem-1508	18	20	7,8	7,8	NUM
eurjchem-1508	18	21	]	]	PUNCT
eurjchem-1508	18	22	.	.	PUNCT
eurjchem-1508	19	1	we	we	PRON
eurjchem-1508	19	2	recently	recently	ADV
eurjchem-1508	19	3	turned	turn	VERB
eurjchem-1508	19	4	to	to	ADP
eurjchem-1508	19	5	application	application	NOUN
eurjchem-1508	19	6	of	of	ADP
eurjchem-1508	19	7	pressure	pressure	NOUN
eurjchem-1508	19	8	as	as	SCONJ
eurjchem-1508	19	9	the	the	DET
eurjchem-1508	19	10	latter	latter	NOUN
eurjchem-1508	19	11	also	also	ADV
eurjchem-1508	19	12	permit	permit	VERB
eurjchem-1508	19	13	conducting	conduct	VERB
eurjchem-1508	19	14	reactions	reaction	NOUN
eurjchem-1508	19	15	at	at	ADP
eurjchem-1508	19	16	temperatures	temperature	NOUN
eurjchem-1508	19	17	higher	high	ADJ
eurjchem-1508	19	18	than	than	ADP
eurjchem-1508	19	19	boiling	boil	VERB
eurjchem-1508	19	20	point	point	NOUN
eurjchem-1508	19	21	of	of	ADP
eurjchem-1508	19	22	the	the	DET
eurjchem-1508	19	23	medium	medium	NOUN
eurjchem-1508	19	24	.	.	PUNCT
eurjchem-1508	20	1	in	in	ADP
eurjchem-1508	20	2	addition	addition	NOUN
eurjchem-1508	20	3	,	,	PUNCT
eurjchem-1508	20	4	the	the	DET
eurjchem-1508	20	5	utility	utility	NOUN
eurjchem-1508	20	6	of	of	ADP
eurjchem-1508	20	7	high	high	ADJ
eurjchem-1508	20	8	pressure	pressure	NOUN
eurjchem-1508	20	9	in	in	ADP
eurjchem-1508	20	10	reactions	reaction	NOUN
eurjchem-1508	20	11	with	with	ADP
eurjchem-1508	20	12	large	large	ADJ
eurjchem-1508	20	13	negative	negative	ADJ
eurjchem-1508	20	14	volumes	volume	NOUN
eurjchem-1508	20	15	of	of	ADP
eurjchem-1508	20	16	activation	activation	NOUN
eurjchem-1508	20	17	(	(	PUNCT
eurjchem-1508	20	18	‐ve	‐ve	NOUN
eurjchem-1508	20	19	)	)	PUNCT
eurjchem-1508	20	20	possess	possess	VERB
eurjchem-1508	20	21	a	a	DET
eurjchem-1508	20	22	rate	rate	NOUN
eurjchem-1508	20	23	accelerating	accelerate	VERB
eurjchem-1508	20	24	effect	effect	NOUN
eurjchem-1508	20	25	[	[	X
eurjchem-1508	20	26	9,10	9,10	X
eurjchem-1508	20	27	]	]	X
eurjchem-1508	20	28	.	.	PUNCT
eurjchem-1508	21	1	our	our	PRON
eurjchem-1508	21	2	first	first	ADJ
eurjchem-1508	21	3	achieve‐	achieve‐	PROPN
eurjchem-1508	21	4	ment	ment	NOUN
eurjchem-1508	21	5	in	in	ADP
eurjchem-1508	21	6	this	this	DET
eurjchem-1508	21	7	area	area	NOUN
eurjchem-1508	21	8	utilizing	utilize	VERB
eurjchem-1508	21	9	q‐tube	q‐tube	PUNCT
eurjchem-1508	21	10	as	as	ADP
eurjchem-1508	21	11	safe	safe	ADJ
eurjchem-1508	21	12	pressure	pressure	NOUN
eurjchem-1508	21	13	reactor	reactor	NOUN
eurjchem-1508	21	14	to	to	PART
eurjchem-1508	21	15	enhance	enhance	VERB
eurjchem-1508	21	16	conducting	conduct	VERB
eurjchem-1508	21	17	reactions	reaction	NOUN
eurjchem-1508	21	18	under	under	ADP
eurjchem-1508	21	19	high	high	ADJ
eurjchem-1508	21	20	pressure	pressure	NOUN
eurjchem-1508	21	21	in	in	ADP
eurjchem-1508	21	22	labora‐	labora‐	PROPN
eurjchem-1508	21	23	tory	tory	NOUN
eurjchem-1508	21	24	has	have	AUX
eurjchem-1508	21	25	very	very	ADV
eurjchem-1508	21	26	recently	recently	ADV
eurjchem-1508	21	27	been	be	AUX
eurjchem-1508	21	28	reported	report	VERB
eurjchem-1508	21	29	[	[	X
eurjchem-1508	21	30	11,12	11,12	NOUN
eurjchem-1508	21	31	]	]	PUNCT
eurjchem-1508	21	32	.	.	PUNCT
eurjchem-1508	22	1	in	in	ADP
eurjchem-1508	22	2	the	the	DET
eurjchem-1508	22	3	present	present	ADJ
eurjchem-1508	22	4	article	article	NOUN
eurjchem-1508	22	5	,	,	PUNCT
eurjchem-1508	22	6	we	we	PRON
eurjchem-1508	22	7	report	report	VERB
eurjchem-1508	22	8	results	result	NOUN
eurjchem-1508	22	9	of	of	ADP
eurjchem-1508	22	10	our	our	PRON
eurjchem-1508	22	11	investigation	investigation	NOUN
eurjchem-1508	22	12	on	on	ADP
eurjchem-1508	22	13	the	the	DET
eurjchem-1508	22	14	reported	report	VERB
eurjchem-1508	22	15	3	3	NUM
eurjchem-1508	22	16	+	+	SYM
eurjchem-1508	22	17	3	3	NUM
eurjchem-1508	22	18	atom	atom	NOUN
eurjchem-1508	22	19	combination	combination	NOUN
eurjchem-1508	22	20	for	for	ADP
eurjchem-1508	22	21	the	the	DET
eurjchem-1508	22	22	synthesis	synthesis	NOUN
eurjchem-1508	22	23	of	of	ADP
eurjchem-1508	22	24	pyridazines	pyridazine	NOUN
eurjchem-1508	22	25	and	and	CCONJ
eurjchem-1508	22	26	condensed	condense	VERB
eurjchem-1508	22	27	pyridazines	pyridazine	NOUN
eurjchem-1508	22	28	[	[	X
eurjchem-1508	22	29	13‐15	13‐15	NUM
eurjchem-1508	22	30	]	]	X
eurjchem-1508	22	31	,	,	PUNCT
eurjchem-1508	22	32	under	under	ADP
eurjchem-1508	22	33	increased	increase	VERB
eurjchem-1508	22	34	pressure	pressure	NOUN
eurjchem-1508	22	35	.	.	PUNCT
eurjchem-1508	23	1	the	the	DET
eurjchem-1508	23	2	work	work	NOUN
eurjchem-1508	23	3	enabled	enable	VERB
eurjchem-1508	23	4	defining	define	VERB
eurjchem-1508	23	5	the	the	DET
eurjchem-1508	23	6	scope	scope	NOUN
eurjchem-1508	23	7	of	of	ADP
eurjchem-1508	23	8	this	this	DET
eurjchem-1508	23	9	synthesis	synthesis	NOUN
eurjchem-1508	23	10	and	and	CCONJ
eurjchem-1508	23	11	enabled	enable	VERB
eurjchem-1508	23	12	disclosing	disclose	VERB
eurjchem-1508	23	13	novel	novel	ADJ
eurjchem-1508	23	14	routes	route	NOUN
eurjchem-1508	23	15	to	to	ADP
eurjchem-1508	23	16	naphthyridine	naphthyridine	VERB
eurjchem-1508	23	17	,	,	PUNCT
eurjchem-1508	23	18	pyridazine	pyridazine	NOUN
eurjchem-1508	23	19	and	and	CCONJ
eurjchem-1508	23	20	biphenyl	biphenyl	NOUN
eurjchem-1508	23	21	derivatives	derivative	NOUN
eurjchem-1508	23	22	.	.	PUNCT
eurjchem-1508	24	1	in	in	ADP
eurjchem-1508	24	2	2007	2007	NUM
eurjchem-1508	24	3	,	,	PUNCT
eurjchem-1508	24	4	we	we	PRON
eurjchem-1508	24	5	reported	report	VERB
eurjchem-1508	24	6	what	what	PRON
eurjchem-1508	24	7	seemed	seem	VERB
eurjchem-1508	24	8	to	to	PART
eurjchem-1508	24	9	be	be	AUX
eurjchem-1508	24	10	a	a	DET
eurjchem-1508	24	11	new	new	ADJ
eurjchem-1508	24	12	general	general	NOUN
eurjchem-1508	24	13	3	3	NUM
eurjchem-1508	24	14	+	+	SYM
eurjchem-1508	24	15	3	3	NUM
eurjchem-1508	24	16	atom	atom	NOUN
eurjchem-1508	24	17	combination	combination	NOUN
eurjchem-1508	24	18	synthesis	synthesis	NOUN
eurjchem-1508	24	19	of	of	ADP
eurjchem-1508	24	20	6‐amino‐1,4‐dihydro	6‐amino‐1,4‐dihydro	NOUN
eurjchem-1508	24	21	pyridazines	pyridazine	NOUN
eurjchem-1508	24	22	(	(	PUNCT
eurjchem-1508	24	23	3	3	NUM
eurjchem-1508	24	24	)	)	PUNCT
eurjchem-1508	24	25	via	via	ADP
eurjchem-1508	24	26	reacting	react	VERB
eurjchem-1508	24	27	arylhydrazonals	arylhydrazonal	NOUN
eurjchem-1508	24	28	(	(	PUNCT
eurjchem-1508	24	29	1a‐e	1a‐e	INTJ
eurjchem-1508	24	30	)	)	PUNCT
eurjchem-1508	24	31	with	with	ADP
eurjchem-1508	24	32	α‐	α‐	NUM
eurjchem-1508	24	33	substituted	substitute	VERB
eurjchem-1508	24	34	cinnamonitrile	cinnamonitrile	NOUN
eurjchem-1508	24	35	(	(	PUNCT
eurjchem-1508	24	36	2a	2a	NUM
eurjchem-1508	24	37	)	)	PUNCT
eurjchem-1508	24	38	(	(	PUNCT
eurjchem-1508	24	39	scheme	scheme	NOUN
eurjchem-1508	24	40	1	1	NUM
eurjchem-1508	24	41	)	)	PUNCT
eurjchem-1508	25	1	[	[	X
eurjchem-1508	25	2	15	15	NUM
eurjchem-1508	25	3	]	]	PUNCT
eurjchem-1508	25	4	.	.	PUNCT
eurjchem-1508	26	1	these	these	PRON
eurjchem-1508	26	2	were	be	AUX
eurjchem-1508	26	3	also	also	ADV
eurjchem-1508	26	4	obtained	obtain	VERB
eurjchem-1508	26	5	via	via	ADP
eurjchem-1508	26	6	reacting	react	VERB
eurjchem-1508	26	7	compounds	compound	NOUN
eurjchem-1508	26	8	1a‐e	1a‐e	ADJ
eurjchem-1508	26	9	,	,	PUNCT
eurjchem-1508	26	10	aromatic	aromatic	ADJ
eurjchem-1508	26	11	aldehydes	aldehyde	NOUN
eurjchem-1508	26	12	(	(	PUNCT
eurjchem-1508	26	13	7	7	NUM
eurjchem-1508	26	14	)	)	PUNCT
eurjchem-1508	26	15	and	and	CCONJ
eurjchem-1508	26	16	active	active	ADJ
eurjchem-1508	26	17	methylene	methylene	NOUN
eurjchem-1508	26	18	nitriles	nitrile	NOUN
eurjchem-1508	26	19	(	(	PUNCT
eurjchem-1508	26	20	6	6	NUM
eurjchem-1508	26	21	)	)	PUNCT
eurjchem-1508	26	22	.	.	PUNCT
eurjchem-1508	27	1	however	however	ADV
eurjchem-1508	27	2	,	,	PUNCT
eurjchem-1508	27	3	subsequent	subsequent	ADJ
eurjchem-1508	27	4	investigations	investigation	NOUN
eurjchem-1508	27	5	indicated	indicate	VERB
eurjchem-1508	27	6	that	that	SCONJ
eurjchem-1508	27	7	the	the	DET
eurjchem-1508	27	8	reaction	reaction	NOUN
eurjchem-1508	27	9	product	product	NOUN
eurjchem-1508	27	10	is	be	AUX
eurjchem-1508	27	11	depending	depend	VERB
eurjchem-1508	27	12	on	on	ADP
eurjchem-1508	27	13	the	the	DET
eurjchem-1508	27	14	nature	nature	NOUN
eurjchem-1508	27	15	of	of	ADP
eurjchem-1508	27	16	aryl	aryl	NOUN
eurjchem-1508	27	17	substituent	substituent	NOUN
eurjchem-1508	27	18	in	in	ADP
eurjchem-1508	27	19	compound	compound	NOUN
eurjchem-1508	27	20	1	1	NUM
eurjchem-1508	27	21	.	.	PUNCT
eurjchem-1508	28	1	thus	thus	ADV
eurjchem-1508	28	2	,	,	PUNCT
eurjchem-1508	28	3	compounds	compound	VERB
eurjchem-1508	28	4	1f	1f	NUM
eurjchem-1508	28	5	,	,	PUNCT
eurjchem-1508	28	6	g	g	PROPN
eurjchem-1508	28	7	reacted	react	VERB
eurjchem-1508	28	8	with	with	ADP
eurjchem-1508	28	9	compound	compound	NOUN
eurjchem-1508	28	10	2a	2a	NUM
eurjchem-1508	28	11	to	to	PART
eurjchem-1508	28	12	yield	yield	VERB
eurjchem-1508	28	13	compound	compound	NOUN
eurjchem-1508	28	14	4	4	NUM
eurjchem-1508	29	1	[	[	SYM
eurjchem-1508	29	2	16	16	NUM
eurjchem-1508	29	3	]	]	PUNCT
eurjchem-1508	29	4	whereas	whereas	SCONJ
eurjchem-1508	29	5	compound	compound	NOUN
eurjchem-1508	29	6	1j	1j	NUM
eurjchem-1508	29	7	reacted	react	VERB
eurjchem-1508	29	8	with	with	ADP
eurjchem-1508	29	9	com‐	com‐	PROPN
eurjchem-1508	29	10	pound	pound	NOUN
eurjchem-1508	29	11	2a	2a	NUM
eurjchem-1508	29	12	to	to	PART
eurjchem-1508	29	13	yield	yield	VERB
eurjchem-1508	29	14	compound	compound	NOUN
eurjchem-1508	29	15	5	5	NUM
eurjchem-1508	30	1	[	[	SYM
eurjchem-1508	30	2	13	13	NUM
eurjchem-1508	30	3	]	]	PUNCT
eurjchem-1508	30	4	.	.	PUNCT
eurjchem-1508	31	1	recently	recently	ADV
eurjchem-1508	31	2	,	,	PUNCT
eurjchem-1508	31	3	abdelhamid	abdelhamid	INTJ
eurjchem-1508	31	4	et	et	PROPN
eurjchem-1508	31	5	al	al	PROPN
eurjchem-1508	31	6	.	.	PROPN
eurjchem-1508	31	7	reported	report	VERB
eurjchem-1508	31	8	that	that	SCONJ
eurjchem-1508	31	9	pyrazolyl‐azaenamines	pyrazolyl‐azaenamine	NOUN
eurjchem-1508	31	10	reacted	react	VERB
eurjchem-1508	31	11	with	with	ADP
eurjchem-1508	31	12	cinnamo	cinnamo	NOUN
eurjchem-1508	31	13	nitrile	nitrile	ADJ
eurjchem-1508	31	14	derivatives	derivative	NOUN
eurjchem-1508	31	15	yielding	yield	VERB
eurjchem-1508	31	16	pyrazolo[4",3"‐5,6]pyrimido[2,1‐	pyrazolo[4",3"‐5,6]pyrimido[2,1‐	NOUN
eurjchem-1508	32	1	a]phthalazine‐9‐carbonitrile	a]phthalazine‐9‐carbonitrile	PROPN
eurjchem-1508	32	2	derivatives	derivative	NOUN
eurjchem-1508	32	3	[	[	X
eurjchem-1508	32	4	17	17	NUM
eurjchem-1508	32	5	]	]	PUNCT
eurjchem-1508	32	6	.	.	PUNCT
eurjchem-1508	33	1	sadek	sadek	PROPN
eurjchem-1508	33	2	et	et	PROPN
eurjchem-1508	33	3	al	al	PROPN
eurjchem-1508	33	4	.	.	PUNCT
eurjchem-1508	33	5	/	/	SYM
eurjchem-1508	33	6	european	european	PROPN
eurjchem-1508	33	7	journal	journal	PROPN
eurjchem-1508	33	8	of	of	ADP
eurjchem-1508	33	9	chemistry	chemistry	NOUN
eurjchem-1508	33	10	7	7	NUM
eurjchem-1508	33	11	(	(	PUNCT
eurjchem-1508	33	12	4	4	NUM
eurjchem-1508	33	13	)	)	PUNCT
eurjchem-1508	33	14	(	(	PUNCT
eurjchem-1508	33	15	2016	2016	NUM
eurjchem-1508	33	16	)	)	PUNCT
eurjchem-1508	33	17	468‐472	468‐472	NOUN
eurjchem-1508	33	18	469	469	NUM
eurjchem-1508	33	19	scheme	scheme	NOUN
eurjchem-1508	33	20	1	1	NUM
eurjchem-1508	33	21	very	very	ADV
eurjchem-1508	33	22	recently	recently	ADV
eurjchem-1508	33	23	,	,	PUNCT
eurjchem-1508	33	24	moustafa	moustafa	PROPN
eurjchem-1508	33	25	et	et	PROPN
eurjchem-1508	33	26	al	al	PROPN
eurjchem-1508	33	27	.	.	PROPN
eurjchem-1508	33	28	have	have	AUX
eurjchem-1508	33	29	developed	develop	VERB
eurjchem-1508	33	30	a	a	DET
eurjchem-1508	33	31	novel	novel	ADJ
eurjchem-1508	33	32	synthesis	synthesis	NOUN
eurjchem-1508	33	33	of	of	ADP
eurjchem-1508	33	34	tricyclic	tricyclic	ADJ
eurjchem-1508	33	35	system	system	NOUN
eurjchem-1508	33	36	8	8	NUM
eurjchem-1508	33	37	via	via	ADP
eurjchem-1508	33	38	reacting	react	VERB
eurjchem-1508	33	39	2‐phenylhydrazono	2‐phenylhydrazono	NUM
eurjchem-1508	33	40	derivatives	derivative	NOUN
eurjchem-1508	33	41	with	with	ADP
eurjchem-1508	33	42	malononitrile	malononitrile	NOUN
eurjchem-1508	33	43	(	(	PUNCT
eurjchem-1508	33	44	6	6	NUM
eurjchem-1508	33	45	)	)	PUNCT
eurjchem-1508	33	46	and	and	CCONJ
eurjchem-1508	33	47	aromatic	aromatic	ADJ
eurjchem-1508	33	48	aldehyde	aldehyde	NOUN
eurjchem-1508	33	49	derivatives	derivative	NOUN
eurjchem-1508	33	50	(	(	PUNCT
eurjchem-1508	33	51	7	7	NUM
eurjchem-1508	33	52	)	)	PUNCT
eurjchem-1508	33	53	in	in	ADP
eurjchem-1508	33	54	q‐tube	q‐tube	NUM
eurjchem-1508	33	55	[	[	X
eurjchem-1508	33	56	18	18	NUM
eurjchem-1508	33	57	]	]	PUNCT
eurjchem-1508	33	58	.	.	PUNCT
eurjchem-1508	34	1	also	also	ADV
eurjchem-1508	34	2	abdelmoniem	abdelmoniem	PROPN
eurjchem-1508	34	3	et	et	PROPN
eurjchem-1508	34	4	al	al	PROPN
eurjchem-1508	34	5	.	.	PUNCT
eurjchem-1508	35	1	[	[	X
eurjchem-1508	35	2	19	19	NUM
eurjchem-1508	35	3	]	]	PUNCT
eurjchem-1508	35	4	reported	report	VERB
eurjchem-1508	35	5	different	different	ADJ
eurjchem-1508	35	6	synthetic	synthetic	ADJ
eurjchem-1508	35	7	routes	route	NOUN
eurjchem-1508	35	8	for	for	ADP
eurjchem-1508	35	9	the	the	DET
eurjchem-1508	35	10	synthesis	synthesis	NOUN
eurjchem-1508	35	11	of	of	ADP
eurjchem-1508	35	12	several	several	ADJ
eurjchem-1508	35	13	pyridazine	pyridazine	NOUN
eurjchem-1508	35	14	derivatives	derivative	NOUN
eurjchem-1508	35	15	utilizing	utilize	VERB
eurjchem-1508	35	16	arylhydrazonals	arylhydrazonal	NOUN
eurjchem-1508	35	17	as	as	ADP
eurjchem-1508	35	18	starting	start	VERB
eurjchem-1508	35	19	materials	material	NOUN
eurjchem-1508	35	20	as	as	SCONJ
eurjchem-1508	35	21	they	they	PRON
eurjchem-1508	35	22	possess	possess	VERB
eurjchem-1508	35	23	an	an	DET
eurjchem-1508	35	24	in	in	ADP
eurjchem-1508	35	25	vitro	vitro	X
eurjchem-1508	35	26	antitumor	antitumor	PROPN
eurjchem-1508	35	27	effect	effect	NOUN
eurjchem-1508	35	28	[	[	X
eurjchem-1508	35	29	20	20	NUM
eurjchem-1508	35	30	]	]	PUNCT
eurjchem-1508	35	31	.	.	PUNCT
eurjchem-1508	36	1	2	2	X
eurjchem-1508	36	2	.	.	X
eurjchem-1508	36	3	experimental	experimental	ADJ
eurjchem-1508	36	4	2.1	2.1	NUM
eurjchem-1508	36	5	.	.	PUNCT
eurjchem-1508	37	1	instrumentation	instrumentation	NOUN
eurjchem-1508	37	2	melting	melting	NOUN
eurjchem-1508	37	3	points	point	NOUN
eurjchem-1508	37	4	were	be	AUX
eurjchem-1508	37	5	recorded	record	VERB
eurjchem-1508	37	6	on	on	ADP
eurjchem-1508	37	7	a	a	DET
eurjchem-1508	37	8	griffin	griffin	NOUN
eurjchem-1508	37	9	melting	melting	NOUN
eurjchem-1508	37	10	point	point	NOUN
eurjchem-1508	37	11	apparatus	apparatus	NOUN
eurjchem-1508	37	12	and	and	CCONJ
eurjchem-1508	37	13	are	be	AUX
eurjchem-1508	37	14	reported	report	VERB
eurjchem-1508	37	15	uncorrected	uncorrecte	VERB
eurjchem-1508	37	16	.	.	PUNCT
eurjchem-1508	38	1	1h	1h	NUM
eurjchem-1508	38	2	nmr	nmr	NOUN
eurjchem-1508	38	3	(	(	PUNCT
eurjchem-1508	38	4	400	400	NUM
eurjchem-1508	38	5	mhz	mhz	NOUN
eurjchem-1508	38	6	)	)	PUNCT
eurjchem-1508	38	7	and	and	CCONJ
eurjchem-1508	38	8	13c	13c	NOUN
eurjchem-1508	38	9	nmr	nmr	NOUN
eurjchem-1508	38	10	(	(	PUNCT
eurjchem-1508	38	11	100	100	NUM
eurjchem-1508	38	12	mhz	mhz	NOUN
eurjchem-1508	38	13	)	)	PUNCT
eurjchem-1508	38	14	spectra	spectra	NOUN
eurjchem-1508	38	15	were	be	AUX
eurjchem-1508	38	16	recorded	record	VERB
eurjchem-1508	38	17	at	at	ADP
eurjchem-1508	38	18	25	25	NUM
eurjchem-1508	38	19	°	°	NOUN
eurjchem-1508	38	20	c	c	NOUN
eurjchem-1508	38	21	using	use	VERB
eurjchem-1508	38	22	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	38	23	as	as	ADP
eurjchem-1508	38	24	solvent	solvent	ADJ
eurjchem-1508	38	25	with	with	ADP
eurjchem-1508	38	26	tms	tms	PROPN
eurjchem-1508	38	27	as	as	ADP
eurjchem-1508	38	28	internal	internal	ADJ
eurjchem-1508	38	29	standard	standard	NOUN
eurjchem-1508	38	30	on	on	ADP
eurjchem-1508	38	31	a	a	DET
eurjchem-1508	38	32	bruker	bruker	NOUN
eurjchem-1508	38	33	dpx	dpx	PROPN
eurjchem-1508	38	34	400	400	NUM
eurjchem-1508	38	35	spectrometer	spectrometer	NOUN
eurjchem-1508	38	36	.	.	PUNCT
eurjchem-1508	39	1	chemical	chemical	ADJ
eurjchem-1508	39	2	shift	shift	NOUN
eurjchem-1508	39	3	are	be	AUX
eurjchem-1508	39	4	reported	report	VERB
eurjchem-1508	39	5	in	in	ADP
eurjchem-1508	39	6	ppm	ppm	PROPN
eurjchem-1508	39	7	.	.	PUNCT
eurjchem-1508	40	1	mass	mass	PROPN
eurjchem-1508	40	2	spectra	spectra	PROPN
eurjchem-1508	40	3	were	be	AUX
eurjchem-1508	40	4	performed	perform	VERB
eurjchem-1508	40	5	using	use	VERB
eurjchem-1508	40	6	shimadzu	shimadzu	ADJ
eurjchem-1508	40	7	gmss‐q‐1000	gmss‐q‐1000	PROPN
eurjchem-1508	40	8	ex	ex	ADJ
eurjchem-1508	40	9	mass	mass	NOUN
eurjchem-1508	40	10	spectrometer	spectrometer	NOUN
eurjchem-1508	40	11	with	with	ADP
eurjchem-1508	40	12	the	the	DET
eurjchem-1508	40	13	ei	ei	X
eurjchem-1508	40	14	(	(	PUNCT
eurjchem-1508	40	15	70	70	NUM
eurjchem-1508	40	16	ev	ev	NOUN
eurjchem-1508	40	17	)	)	PUNCT
eurjchem-1508	40	18	mode	mode	NOUN
eurjchem-1508	40	19	.	.	PUNCT
eurjchem-1508	41	1	all	all	DET
eurjchem-1508	41	2	reactions	reaction	NOUN
eurjchem-1508	41	3	were	be	AUX
eurjchem-1508	41	4	monitored	monitor	VERB
eurjchem-1508	41	5	by	by	ADP
eurjchem-1508	41	6	using	use	VERB
eurjchem-1508	41	7	thin	thin	ADJ
eurjchem-1508	41	8	layer	layer	NOUN
eurjchem-1508	41	9	chromatography	chromatography	NOUN
eurjchem-1508	41	10	(	(	PUNCT
eurjchem-1508	41	11	tlc	tlc	NOUN
eurjchem-1508	41	12	)	)	PUNCT
eurjchem-1508	41	13	.	.	PUNCT
eurjchem-1508	42	1	reactions	reaction	NOUN
eurjchem-1508	42	2	were	be	AUX
eurjchem-1508	42	3	conducted	conduct	VERB
eurjchem-1508	42	4	under	under	ADP
eurjchem-1508	42	5	reduced	reduced	ADJ
eurjchem-1508	42	6	pressure	pressure	NOUN
eurjchem-1508	42	7	in	in	ADP
eurjchem-1508	42	8	q‐tube	q‐tube	NUM
eurjchem-1508	42	9	safe	safe	ADJ
eurjchem-1508	42	10	pressure	pressure	NOUN
eurjchem-1508	42	11	reactor	reactor	NOUN
eurjchem-1508	42	12	from	from	ADP
eurjchem-1508	42	13	q‐labtech	q‐labtech	PUNCT
eurjchem-1508	42	14	with	with	ADP
eurjchem-1508	42	15	a	a	DET
eurjchem-1508	42	16	cap	cap	NOUN
eurjchem-1508	42	17	/	/	SYM
eurjchem-1508	42	18	sleeve	sleeve	NOUN
eurjchem-1508	42	19	,	,	PUNCT
eurjchem-1508	42	20	pressure	pressure	NOUN
eurjchem-1508	42	21	adaptor	adaptor	NOUN
eurjchem-1508	42	22	(	(	PUNCT
eurjchem-1508	42	23	120	120	NUM
eurjchem-1508	42	24	psi	psi	NOUN
eurjchem-1508	42	25	)	)	PUNCT
eurjchem-1508	42	26	,	,	PUNCT
eurjchem-1508	42	27	needle	needle	NOUN
eurjchem-1508	42	28	adaptor	adaptor	NOUN
eurjchem-1508	42	29	,	,	PUNCT
eurjchem-1508	42	30	needle	needle	NOUN
eurjchem-1508	42	31	,	,	PUNCT
eurjchem-1508	42	32	borosilicate	borosilicate	ADJ
eurjchem-1508	42	33	glass	glass	NOUN
eurjchem-1508	42	34	tube	tube	NOUN
eurjchem-1508	42	35	,	,	PUNCT
eurjchem-1508	42	36	teflon	teflon	NOUN
eurjchem-1508	42	37	septum	septum	NOUN
eurjchem-1508	42	38	and	and	CCONJ
eurjchem-1508	42	39	catch	catch	NOUN
eurjchem-1508	42	40	bottle	bottle	NOUN
eurjchem-1508	42	41	.	.	PUNCT
eurjchem-1508	43	1	2.2	2.2	NUM
eurjchem-1508	43	2	.	.	PUNCT
eurjchem-1508	43	3	synthesis	synthesis	NOUN
eurjchem-1508	43	4	2.2.1	2.2.1	NUM
eurjchem-1508	43	5	.	.	PUNCT
eurjchem-1508	44	1	general	general	ADJ
eurjchem-1508	44	2	procedures	procedure	NOUN
eurjchem-1508	44	3	for	for	ADP
eurjchem-1508	44	4	q‐tube‐assisted	q‐tube‐assiste	VERB
eurjchem-1508	44	5	synthesis	synthesis	NOUN
eurjchem-1508	44	6	of	of	ADP
eurjchem-1508	44	7	compounds	compound	NOUN
eurjchem-1508	44	8	4	4	NUM
eurjchem-1508	44	9	,	,	PUNCT
eurjchem-1508	44	10	8	8	NUM
eurjchem-1508	44	11	and	and	CCONJ
eurjchem-1508	44	12	22	22	NUM
eurjchem-1508	44	13	independed	independe	VERB
eurjchem-1508	44	14	azaenamines	azaenamine	NOUN
eurjchem-1508	44	15	derivative	derivative	NOUN
eurjchem-1508	44	16	(	(	PUNCT
eurjchem-1508	44	17	1h‐k	1h‐k	NOUN
eurjchem-1508	44	18	)	)	PUNCT
eurjchem-1508	44	19	(	(	PUNCT
eurjchem-1508	44	20	0.01	0.01	NUM
eurjchem-1508	44	21	mol	mol	NOUN
eurjchem-1508	44	22	)	)	PUNCT
eurjchem-1508	44	23	,	,	PUNCT
eurjchem-1508	44	24	malononitrile	malononitrile	NOUN
eurjchem-1508	44	25	(	(	PUNCT
eurjchem-1508	44	26	6	6	NUM
eurjchem-1508	44	27	)	)	PUNCT
eurjchem-1508	44	28	(	(	PUNCT
eurjchem-1508	44	29	0.02	0.02	NUM
eurjchem-1508	44	30	mol	mol	NOUN
eurjchem-1508	44	31	)	)	PUNCT
eurjchem-1508	44	32	and	and	CCONJ
eurjchem-1508	44	33	aromatic	aromatic	ADJ
eurjchem-1508	44	34	aldehydes	aldehyde	NOUN
eurjchem-1508	44	35	(	(	PUNCT
eurjchem-1508	44	36	7a‐e	7a‐e	PROPN
eurjchem-1508	44	37	)	)	PUNCT
eurjchem-1508	44	38	(	(	PUNCT
eurjchem-1508	44	39	0.01	0.01	NUM
eurjchem-1508	44	40	mol	mol	NOUN
eurjchem-1508	44	41	)	)	PUNCT
eurjchem-1508	44	42	in	in	ADP
eurjchem-1508	44	43	dioxane	dioxane	NOUN
eurjchem-1508	44	44	(	(	PUNCT
eurjchem-1508	44	45	10	10	NUM
eurjchem-1508	44	46	ml	ml	NOUN
eurjchem-1508	44	47	)	)	PUNCT
eurjchem-1508	44	48	and	and	CCONJ
eurjchem-1508	44	49	catalytic	catalytic	ADJ
eurjchem-1508	44	50	amount	amount	NOUN
eurjchem-1508	44	51	of	of	ADP
eurjchem-1508	44	52	either	either	DET
eurjchem-1508	44	53	piperidine	piperidine	NOUN
eurjchem-1508	44	54	(	(	PUNCT
eurjchem-1508	44	55	1	1	NUM
eurjchem-1508	44	56	ml	ml	NOUN
eurjchem-1508	44	57	)	)	PUNCT
eurjchem-1508	44	58	or	or	CCONJ
eurjchem-1508	44	59	zeolite	zeolite	NOUN
eurjchem-1508	44	60	(	(	PUNCT
eurjchem-1508	44	61	0.25	0.25	NUM
eurjchem-1508	44	62	g	g	NOUN
eurjchem-1508	44	63	)	)	PUNCT
eurjchem-1508	44	64	were	be	AUX
eurjchem-1508	44	65	sequentially	sequentially	ADV
eurjchem-1508	44	66	added	add	VERB
eurjchem-1508	44	67	in	in	ADP
eurjchem-1508	44	68	a	a	DET
eurjchem-1508	44	69	35	35	NUM
eurjchem-1508	44	70	ml	ml	NOUN
eurjchem-1508	44	71	q‐tube	q‐tube	NOUN
eurjchem-1508	44	72	pressure	pressure	NOUN
eurjchem-1508	44	73	tube	tube	NOUN
eurjchem-1508	44	74	,	,	PUNCT
eurjchem-1508	44	75	the	the	DET
eurjchem-1508	44	76	mixture	mixture	NOUN
eurjchem-1508	44	77	was	be	AUX
eurjchem-1508	44	78	heated	heat	VERB
eurjchem-1508	44	79	in	in	ADP
eurjchem-1508	44	80	an	an	DET
eurjchem-1508	44	81	oil	oil	NOUN
eurjchem-1508	44	82	bath	bath	NOUN
eurjchem-1508	44	83	at	at	ADP
eurjchem-1508	44	84	150	150	NUM
eurjchem-1508	44	85	°	°	NOUN
eurjchem-1508	44	86	c	c	NOUN
eurjchem-1508	44	87	.	.	PUNCT
eurjchem-1508	45	1	after	after	ADP
eurjchem-1508	45	2	about	about	ADV
eurjchem-1508	45	3	60	60	NUM
eurjchem-1508	45	4	min	min	NOUN
eurjchem-1508	45	5	,	,	PUNCT
eurjchem-1508	45	6	the	the	DET
eurjchem-1508	45	7	reaction	reaction	NOUN
eurjchem-1508	45	8	mixture	mixture	NOUN
eurjchem-1508	45	9	was	be	AUX
eurjchem-1508	45	10	monitored	monitor	VERB
eurjchem-1508	45	11	by	by	ADP
eurjchem-1508	45	12	tlc	tlc	NOUN
eurjchem-1508	45	13	and	and	CCONJ
eurjchem-1508	45	14	stopped	stop	VERB
eurjchem-1508	45	15	.	.	PUNCT
eurjchem-1508	46	1	the	the	DET
eurjchem-1508	46	2	hot	hot	ADJ
eurjchem-1508	46	3	reaction	reaction	NOUN
eurjchem-1508	46	4	mixture	mixture	NOUN
eurjchem-1508	46	5	was	be	AUX
eurjchem-1508	46	6	cooled	cool	VERB
eurjchem-1508	46	7	and	and	CCONJ
eurjchem-1508	46	8	poured	pour	VERB
eurjchem-1508	46	9	into	into	ADP
eurjchem-1508	46	10	ice‐water	ice‐water	NOUN
eurjchem-1508	46	11	.	.	PUNCT
eurjchem-1508	47	1	the	the	DET
eurjchem-1508	47	2	separated	separate	VERB
eurjchem-1508	47	3	solid	solid	ADJ
eurjchem-1508	47	4	products	product	NOUN
eurjchem-1508	47	5	obtained	obtain	VERB
eurjchem-1508	47	6	on	on	ADP
eurjchem-1508	47	7	standing	stand	VERB
eurjchem-1508	47	8	at	at	ADP
eurjchem-1508	47	9	room	room	NOUN
eurjchem-1508	47	10	temperature	temperature	NOUN
eurjchem-1508	47	11	were	be	AUX
eurjchem-1508	47	12	collected	collect	VERB
eurjchem-1508	47	13	by	by	ADP
eurjchem-1508	47	14	filtration	filtration	NOUN
eurjchem-1508	47	15	and	and	CCONJ
eurjchem-1508	47	16	purified	purify	VERB
eurjchem-1508	47	17	by	by	ADP
eurjchem-1508	47	18	column	column	NOUN
eurjchem-1508	47	19	chromatography	chromatography	NOUN
eurjchem-1508	47	20	utilizing	utilize	VERB
eurjchem-1508	47	21	appropriate	appropriate	ADJ
eurjchem-1508	47	22	solvents	solvent	NOUN
eurjchem-1508	47	23	mixture	mixture	NOUN
eurjchem-1508	47	24	to	to	PART
eurjchem-1508	47	25	give	give	VERB
eurjchem-1508	47	26	analytical	analytical	ADJ
eurjchem-1508	47	27	pure	pure	ADJ
eurjchem-1508	47	28	products	product	NOUN
eurjchem-1508	47	29	(	(	PUNCT
eurjchem-1508	47	30	scheme	scheme	NOUN
eurjchem-1508	47	31	2	2	NUM
eurjchem-1508	47	32	)	)	PUNCT
eurjchem-1508	47	33	.	.	PUNCT
eurjchem-1508	48	1	8‐amino‐5‐phenyl‐4‐methyl‐1‐(2‐nitrophenyl)‐1h‐pyridazi	8‐amino‐5‐phenyl‐4‐methyl‐1‐(2‐nitrophenyl)‐1h‐pyridazi	NUM
eurjchem-1508	48	2	no[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	no[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	PRON
eurjchem-1508	48	3	(	(	PUNCT
eurjchem-1508	48	4	8a	8a	NUM
eurjchem-1508	48	5	):	):	PUNCT
eurjchem-1508	48	6	recrystal‐	recrystal‐	NUM
eurjchem-1508	48	7	lized	lize	VERB
eurjchem-1508	48	8	from	from	ADP
eurjchem-1508	48	9	acetic	acetic	ADJ
eurjchem-1508	48	10	acid	acid	NOUN
eurjchem-1508	48	11	.	.	PUNCT
eurjchem-1508	49	1	color	color	NOUN
eurjchem-1508	49	2	:	:	PUNCT
eurjchem-1508	49	3	brown	brown	ADJ
eurjchem-1508	49	4	.	.	PUNCT
eurjchem-1508	50	1	m.p	m.p	PROPN
eurjchem-1508	50	2	.	.	PROPN
eurjchem-1508	50	3	:	:	PUNCT
eurjchem-1508	51	1	219‐220	219‐220	PROPN
eurjchem-1508	51	2	°	°	ADP
eurjchem-1508	51	3	c	c	PROPN
eurjchem-1508	51	4	.	.	PUNCT
eurjchem-1508	51	5	yield	yield	NOUN
eurjchem-1508	51	6	:	:	PUNCT
eurjchem-1508	51	7	83	83	NUM
eurjchem-1508	51	8	%	%	NOUN
eurjchem-1508	51	9	.	.	PUNCT
eurjchem-1508	52	1	1h	1h	NUM
eurjchem-1508	52	2	nmr	nmr	NOUN
eurjchem-1508	52	3	(	(	PUNCT
eurjchem-1508	52	4	400	400	NUM
eurjchem-1508	52	5	mhz	mhz	NOUN
eurjchem-1508	52	6	,	,	PUNCT
eurjchem-1508	52	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	52	8	,	,	PUNCT
eurjchem-1508	52	9	δ	δ	PROPN
eurjchem-1508	52	10	,	,	PUNCT
eurjchem-1508	52	11	ppm	ppm	NUM
eurjchem-1508	52	12	):	):	PUNCT
eurjchem-1508	52	13	2.36	2.36	NUM
eurjchem-1508	52	14	(	(	PUNCT
eurjchem-1508	52	15	s	s	PROPN
eurjchem-1508	52	16	,	,	PUNCT
eurjchem-1508	52	17	3h	3h	NUM
eurjchem-1508	52	18	,	,	PUNCT
eurjchem-1508	52	19	ch3	ch3	PROPN
eurjchem-1508	52	20	)	)	PUNCT
eurjchem-1508	52	21	,	,	PUNCT
eurjchem-1508	52	22	7.0	7.0	NUM
eurjchem-1508	52	23	(	(	PUNCT
eurjchem-1508	52	24	s	s	PROPN
eurjchem-1508	52	25	,	,	PUNCT
eurjchem-1508	52	26	2h	2h	NUM
eurjchem-1508	52	27	,	,	PUNCT
eurjchem-1508	52	28	nh2	nh2	PROPN
eurjchem-1508	52	29	,	,	PUNCT
eurjchem-1508	52	30	d2o	d2o	NOUN
eurjchem-1508	52	31	exchangeable	exchangeable	ADJ
eurjchem-1508	52	32	)	)	PUNCT
eurjchem-1508	52	33	,	,	PUNCT
eurjchem-1508	52	34	7.50‐7.52	7.50‐7.52	NUM
eurjchem-1508	52	35	(	(	PUNCT
eurjchem-1508	52	36	m	m	PROPN
eurjchem-1508	52	37	,	,	PUNCT
eurjchem-1508	52	38	3h	3h	NUM
eurjchem-1508	52	39	,	,	PUNCT
eurjchem-1508	52	40	ar‐h	ar‐h	NOUN
eurjchem-1508	52	41	)	)	PUNCT
eurjchem-1508	52	42	,	,	PUNCT
eurjchem-1508	52	43	7.54‐	7.54‐	NUM
eurjchem-1508	52	44	7.58	7.58	NUM
eurjchem-1508	52	45	(	(	PUNCT
eurjchem-1508	52	46	m	m	PROPN
eurjchem-1508	52	47	,	,	PUNCT
eurjchem-1508	52	48	2h	2h	NUM
eurjchem-1508	52	49	,	,	PUNCT
eurjchem-1508	52	50	ar‐h	ar‐h	NOUN
eurjchem-1508	52	51	)	)	PUNCT
eurjchem-1508	52	52	,	,	PUNCT
eurjchem-1508	52	53	7.78‐7.80	7.78‐7.80	NUM
eurjchem-1508	52	54	(	(	PUNCT
eurjchem-1508	52	55	m	m	PROPN
eurjchem-1508	52	56	,	,	PUNCT
eurjchem-1508	52	57	1h	1h	NUM
eurjchem-1508	52	58	,	,	PUNCT
eurjchem-1508	52	59	ar‐h	ar‐h	NOUN
eurjchem-1508	52	60	)	)	PUNCT
eurjchem-1508	52	61	,	,	PUNCT
eurjchem-1508	52	62	7.88‐7.90	7.88‐7.90	NUM
eurjchem-1508	52	63	(	(	PUNCT
eurjchem-1508	52	64	dd	dd	NOUN
eurjchem-1508	52	65	,	,	PUNCT
eurjchem-1508	52	66	j	j	NOUN
eurjchem-1508	52	67	=	=	PROPN
eurjchem-1508	52	68	0.8	0.8	NUM
eurjchem-1508	52	69	hz	hz	NOUN
eurjchem-1508	52	70	,	,	PUNCT
eurjchem-1508	52	71	1h	1h	NUM
eurjchem-1508	52	72	,	,	PUNCT
eurjchem-1508	52	73	ar‐h	ar‐h	NOUN
eurjchem-1508	52	74	)	)	PUNCT
eurjchem-1508	52	75	,	,	PUNCT
eurjchem-1508	52	76	7.95‐7.98	7.95‐7.98	NUM
eurjchem-1508	52	77	(	(	PUNCT
eurjchem-1508	52	78	m	m	PROPN
eurjchem-1508	52	79	,	,	PUNCT
eurjchem-1508	52	80	1h	1h	NUM
eurjchem-1508	52	81	,	,	PUNCT
eurjchem-1508	52	82	ar‐h	ar‐h	NOUN
eurjchem-1508	52	83	)	)	PUNCT
eurjchem-1508	52	84	,	,	PUNCT
eurjchem-1508	52	85	8.23‐8.24	8.23‐8.24	NUM
eurjchem-1508	52	86	(	(	PUNCT
eurjchem-1508	52	87	dd	dd	PROPN
eurjchem-1508	52	88	,	,	PUNCT
eurjchem-1508	52	89	j	j	NOUN
eurjchem-1508	53	1	=	=	PROPN
eurjchem-1508	53	2	0.8	0.8	NUM
eurjchem-1508	53	3	hz	hz	NOUN
eurjchem-1508	53	4	,	,	PUNCT
eurjchem-1508	53	5	1h	1h	NUM
eurjchem-1508	53	6	,	,	PUNCT
eurjchem-1508	53	7	ar‐h	ar‐h	NOUN
eurjchem-1508	53	8	)	)	PUNCT
eurjchem-1508	53	9	,	,	PUNCT
eurjchem-1508	53	10	8.63	8.63	NUM
eurjchem-1508	53	11	(	(	PUNCT
eurjchem-1508	53	12	s	s	PROPN
eurjchem-1508	53	13	,	,	PUNCT
eurjchem-1508	53	14	1h	1h	NUM
eurjchem-1508	53	15	,	,	PUNCT
eurjchem-1508	53	16	pyridazine‐h	pyridazine‐h	NOUN
eurjchem-1508	53	17	)	)	PUNCT
eurjchem-1508	53	18	.	.	PUNCT
eurjchem-1508	54	1	ms	ms	NOUN
eurjchem-1508	54	2	(	(	PUNCT
eurjchem-1508	54	3	ei	ei	PROPN
eurjchem-1508	54	4	,	,	PUNCT
eurjchem-1508	54	5	m	m	PROPN
eurjchem-1508	54	6	/	/	SYM
eurjchem-1508	54	7	z	z	PROPN
eurjchem-1508	54	8	(	(	PUNCT
eurjchem-1508	54	9	%	%	NOUN
eurjchem-1508	54	10	)	)	PUNCT
eurjchem-1508	54	11	):	):	PUNCT
eurjchem-1508	54	12	422	422	NUM
eurjchem-1508	54	13	(	(	PUNCT
eurjchem-1508	54	14	m+1	m+1	NUM
eurjchem-1508	54	15	,	,	PUNCT
eurjchem-1508	54	16	27.5	27.5	NUM
eurjchem-1508	54	17	)	)	PUNCT
eurjchem-1508	54	18	,	,	PUNCT
eurjchem-1508	54	19	421	421	NUM
eurjchem-1508	54	20	(	(	PUNCT
eurjchem-1508	54	21	m+	m+	NUM
eurjchem-1508	54	22	,	,	PUNCT
eurjchem-1508	54	23	100	100	NUM
eurjchem-1508	54	24	)	)	PUNCT
eurjchem-1508	54	25	.	.	PUNCT
eurjchem-1508	55	1	anal	anal	PROPN
eurjchem-1508	55	2	.	.	PUNCT
eurjchem-1508	55	3	calcd	calcd	NOUN
eurjchem-1508	55	4	.	.	PUNCT
eurjchem-1508	56	1	for	for	ADP
eurjchem-1508	56	2	c23h15n7o2	c23h15n7o2	PROPN
eurjchem-1508	56	3	:	:	PUNCT
eurjchem-1508	56	4	c	c	NOUN
eurjchem-1508	56	5	,	,	PUNCT
eurjchem-1508	56	6	65.55	65.55	NUM
eurjchem-1508	56	7	;	;	PUNCT
eurjchem-1508	56	8	h	h	NOUN
eurjchem-1508	56	9	,	,	PUNCT
eurjchem-1508	56	10	3.59	3.59	NUM
eurjchem-1508	56	11	;	;	PUNCT
eurjchem-1508	56	12	n	n	CCONJ
eurjchem-1508	56	13	,	,	PUNCT
eurjchem-1508	56	14	23.27	23.27	NUM
eurjchem-1508	56	15	.	.	PUNCT
eurjchem-1508	56	16	found	find	VERB
eurjchem-1508	56	17	:	:	PUNCT
eurjchem-1508	56	18	65.43	65.43	NUM
eurjchem-1508	56	19	;	;	PUNCT
eurjchem-1508	56	20	h	h	NOUN
eurjchem-1508	56	21	,	,	PUNCT
eurjchem-1508	56	22	3.55	3.55	NUM
eurjchem-1508	56	23	;	;	PUNCT
eurjchem-1508	56	24	n	n	CCONJ
eurjchem-1508	56	25	,	,	PUNCT
eurjchem-1508	56	26	23.33	23.33	NUM
eurjchem-1508	56	27	%	%	NOUN
eurjchem-1508	56	28	.	.	PUNCT
eurjchem-1508	57	1	8‐amino‐5‐(2‐chlorophenyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐	8‐amino‐5‐(2‐chlorophenyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐	NOUN
eurjchem-1508	57	2	1h‐pyridazino[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	1h‐pyridazino[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	NUM
eurjchem-1508	58	1	(	(	PUNCT
eurjchem-1508	58	2	8b	8b	NUM
eurjchem-1508	58	3	):	):	PUNCT
eurjchem-1508	58	4	recrystallized	recrystallize	VERB
eurjchem-1508	58	5	from	from	ADP
eurjchem-1508	58	6	acetic	acetic	ADJ
eurjchem-1508	58	7	acid	acid	NOUN
eurjchem-1508	58	8	.	.	PUNCT
eurjchem-1508	59	1	color	color	NOUN
eurjchem-1508	59	2	:	:	PUNCT
eurjchem-1508	59	3	yellow	yellow	ADJ
eurjchem-1508	59	4	.	.	PUNCT
eurjchem-1508	60	1	m.p	m.p	PROPN
eurjchem-1508	60	2	.	.	PROPN
eurjchem-1508	60	3	:	:	PUNCT
eurjchem-1508	61	1	240‐241	240‐241	PROPN
eurjchem-1508	61	2	°	°	ADP
eurjchem-1508	61	3	c	c	X
eurjchem-1508	61	4	.	.	PUNCT
eurjchem-1508	62	1	yield	yield	NOUN
eurjchem-1508	62	2	:	:	PUNCT
eurjchem-1508	62	3	71	71	NUM
eurjchem-1508	62	4	%	%	NOUN
eurjchem-1508	62	5	.	.	PUNCT
eurjchem-1508	63	1	1h	1h	NUM
eurjchem-1508	63	2	nmr	nmr	NOUN
eurjchem-1508	63	3	(	(	PUNCT
eurjchem-1508	63	4	400	400	NUM
eurjchem-1508	63	5	mhz	mhz	NOUN
eurjchem-1508	63	6	,	,	PUNCT
eurjchem-1508	63	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	63	8	,	,	PUNCT
eurjchem-1508	63	9	δ	δ	PROPN
eurjchem-1508	63	10	,	,	PUNCT
eurjchem-1508	63	11	ppm	ppm	NUM
eurjchem-1508	63	12	):	):	PUNCT
eurjchem-1508	63	13	2.49	2.49	NUM
eurjchem-1508	63	14	(	(	PUNCT
eurjchem-1508	63	15	s	s	PROPN
eurjchem-1508	63	16	,	,	PUNCT
eurjchem-1508	63	17	3h	3h	NUM
eurjchem-1508	63	18	,	,	PUNCT
eurjchem-1508	63	19	ch3	ch3	PROPN
eurjchem-1508	63	20	)	)	PUNCT
eurjchem-1508	63	21	,	,	PUNCT
eurjchem-1508	63	22	7.06	7.06	NUM
eurjchem-1508	63	23	(	(	PUNCT
eurjchem-1508	63	24	s	s	PROPN
eurjchem-1508	63	25	,	,	PUNCT
eurjchem-1508	63	26	2h	2h	NUM
eurjchem-1508	63	27	,	,	PUNCT
eurjchem-1508	63	28	nh2	nh2	PROPN
eurjchem-1508	63	29	,	,	PUNCT
eurjchem-1508	63	30	d2o	d2o	NOUN
eurjchem-1508	63	31	exchangeable	exchangeable	ADJ
eurjchem-1508	63	32	)	)	PUNCT
eurjchem-1508	63	33	,	,	PUNCT
eurjchem-1508	63	34	7.46‐7.54	7.46‐7.54	NUM
eurjchem-1508	63	35	(	(	PUNCT
eurjchem-1508	63	36	m	m	PROPN
eurjchem-1508	63	37	,	,	PUNCT
eurjchem-1508	63	38	4h	4h	NUM
eurjchem-1508	63	39	,	,	PUNCT
eurjchem-1508	63	40	ar‐h	ar‐h	PROPN
eurjchem-1508	63	41	)	)	PUNCT
eurjchem-1508	63	42	,	,	PUNCT
eurjchem-1508	63	43	7.77‐7.99	7.77‐7.99	NUM
eurjchem-1508	63	44	(	(	PUNCT
eurjchem-1508	63	45	m	m	PROPN
eurjchem-1508	63	46	,	,	PUNCT
eurjchem-1508	63	47	3h	3h	NUM
eurjchem-1508	63	48	,	,	PUNCT
eurjchem-1508	63	49	ar‐h	ar‐h	NOUN
eurjchem-1508	63	50	)	)	PUNCT
eurjchem-1508	63	51	,	,	PUNCT
eurjchem-1508	63	52	8.23‐8.25	8.23‐8.25	PROPN
eurjchem-1508	63	53	(	(	PUNCT
eurjchem-1508	63	54	dd	dd	PROPN
eurjchem-1508	63	55	,	,	PUNCT
eurjchem-1508	63	56	j	j	NOUN
eurjchem-1508	63	57	=	=	PROPN
eurjchem-1508	63	58	0.8	0.8	NUM
eurjchem-1508	63	59	hz	hz	NOUN
eurjchem-1508	63	60	,	,	PUNCT
eurjchem-1508	63	61	1h	1h	NUM
eurjchem-1508	63	62	,	,	PUNCT
eurjchem-1508	63	63	ar‐h	ar‐h	NOUN
eurjchem-1508	63	64	)	)	PUNCT
eurjchem-1508	63	65	,	,	PUNCT
eurjchem-1508	63	66	8.63	8.63	NUM
eurjchem-1508	63	67	(	(	PUNCT
eurjchem-1508	63	68	s	s	PROPN
eurjchem-1508	63	69	,	,	PUNCT
eurjchem-1508	63	70	1h	1h	NUM
eurjchem-1508	63	71	,	,	PUNCT
eurjchem-1508	63	72	pyridazine‐h	pyridazine‐h	NOUN
eurjchem-1508	63	73	)	)	PUNCT
eurjchem-1508	63	74	.	.	PUNCT
eurjchem-1508	64	1	ms	ms	NOUN
eurjchem-1508	64	2	(	(	PUNCT
eurjchem-1508	64	3	ei	ei	PROPN
eurjchem-1508	64	4	,	,	PUNCT
eurjchem-1508	64	5	m	m	PROPN
eurjchem-1508	64	6	/	/	SYM
eurjchem-1508	64	7	z	z	PROPN
eurjchem-1508	64	8	(	(	PUNCT
eurjchem-1508	64	9	%	%	NOUN
eurjchem-1508	64	10	)	)	PUNCT
eurjchem-1508	64	11	):	):	PUNCT
eurjchem-1508	64	12	457	457	NUM
eurjchem-1508	64	13	(	(	PUNCT
eurjchem-1508	64	14	m+	m+	NUM
eurjchem-1508	64	15	2	2	NUM
eurjchem-1508	64	16	,	,	PUNCT
eurjchem-1508	64	17	40.3	40.3	NUM
eurjchem-1508	64	18	)	)	PUNCT
eurjchem-1508	64	19	,	,	PUNCT
eurjchem-1508	64	20	456	456	NUM
eurjchem-1508	64	21	(	(	PUNCT
eurjchem-1508	64	22	m+1	m+1	PROPN
eurjchem-1508	64	23	,	,	PUNCT
eurjchem-1508	64	24	28.7	28.7	NUM
eurjchem-1508	64	25	)	)	PUNCT
eurjchem-1508	64	26	.	.	PUNCT
eurjchem-1508	65	1	anal	anal	PROPN
eurjchem-1508	65	2	.	.	PUNCT
eurjchem-1508	65	3	calcd	calcd	NOUN
eurjchem-1508	65	4	.	.	PUNCT
eurjchem-1508	66	1	for	for	SCONJ
eurjchem-1508	66	2	c23h14cln7o2	c23h14cln7o2	PROPN
eurjchem-1508	66	3	:	:	PUNCT
eurjchem-1508	66	4	c	c	X
eurjchem-1508	66	5	,	,	PUNCT
eurjchem-1508	66	6	60.60	60.60	NUM
eurjchem-1508	66	7	;	;	PUNCT
eurjchem-1508	66	8	h	h	NOUN
eurjchem-1508	66	9	,	,	PUNCT
eurjchem-1508	66	10	3.10	3.10	NUM
eurjchem-1508	66	11	;	;	PUNCT
eurjchem-1508	66	12	n	n	CCONJ
eurjchem-1508	66	13	,	,	PUNCT
eurjchem-1508	66	14	21.51	21.51	NUM
eurjchem-1508	66	15	.	.	PUNCT
eurjchem-1508	66	16	found	find	VERB
eurjchem-1508	66	17	:	:	PUNCT
eurjchem-1508	67	1	c	c	X
eurjchem-1508	67	2	,	,	PUNCT
eurjchem-1508	67	3	60.55	60.55	NUM
eurjchem-1508	67	4	;	;	PUNCT
eurjchem-1508	67	5	h	h	X
eurjchem-1508	67	6	,	,	PUNCT
eurjchem-1508	67	7	3.22	3.22	NUM
eurjchem-1508	67	8	;	;	PUNCT
eurjchem-1508	67	9	n	n	CCONJ
eurjchem-1508	67	10	,	,	PUNCT
eurjchem-1508	67	11	21.55	21.55	NUM
eurjchem-1508	67	12	%	%	NOUN
eurjchem-1508	67	13	.	.	PUNCT
eurjchem-1508	68	1	8‐amino‐5‐(4‐chlorophenyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐	8‐amino‐5‐(4‐chlorophenyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐	PROPN
eurjchem-1508	68	2	1h‐pyridazino[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	1h‐pyridazino[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	NUM
eurjchem-1508	68	3	(	(	PUNCT
eurjchem-1508	68	4	8c	8c	NUM
eurjchem-1508	68	5	):	):	PUNCT
eurjchem-1508	68	6	recrystallized	recrystallize	VERB
eurjchem-1508	68	7	from	from	ADP
eurjchem-1508	68	8	etoh	etoh	NOUN
eurjchem-1508	68	9	.	.	PUNCT
eurjchem-1508	69	1	color	color	NOUN
eurjchem-1508	69	2	:	:	PUNCT
eurjchem-1508	69	3	yellow	yellow	ADJ
eurjchem-1508	69	4	.	.	PUNCT
eurjchem-1508	70	1	m.p	m.p	PROPN
eurjchem-1508	70	2	.	.	PROPN
eurjchem-1508	70	3	:	:	PUNCT
eurjchem-1508	71	1	275‐276	275‐276	NUM
eurjchem-1508	71	2	°	°	ADP
eurjchem-1508	71	3	c	c	NOUN
eurjchem-1508	71	4	.	.	PUNCT
eurjchem-1508	71	5	yield	yield	NOUN
eurjchem-1508	71	6	:	:	PUNCT
eurjchem-1508	71	7	68	68	NUM
eurjchem-1508	71	8	%	%	NOUN
eurjchem-1508	71	9	.	.	PUNCT
eurjchem-1508	72	1	1h	1h	NUM
eurjchem-1508	72	2	nmr	nmr	NOUN
eurjchem-1508	72	3	(	(	PUNCT
eurjchem-1508	72	4	400	400	NUM
eurjchem-1508	72	5	mhz	mhz	NOUN
eurjchem-1508	72	6	,	,	PUNCT
eurjchem-1508	72	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	72	8	,	,	PUNCT
eurjchem-1508	72	9	δ	δ	PROPN
eurjchem-1508	72	10	,	,	PUNCT
eurjchem-1508	72	11	ppm	ppm	NOUN
eurjchem-1508	72	12	):	):	PUNCT
eurjchem-1508	72	13	2.35	2.35	NUM
eurjchem-1508	72	14	(	(	PUNCT
eurjchem-1508	72	15	s	s	PROPN
eurjchem-1508	72	16	,	,	PUNCT
eurjchem-1508	72	17	3h	3h	NUM
eurjchem-1508	72	18	,	,	PUNCT
eurjchem-1508	72	19	ch3	ch3	PROPN
eurjchem-1508	72	20	)	)	PUNCT
eurjchem-1508	72	21	,	,	PUNCT
eurjchem-1508	72	22	7.02	7.02	NUM
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eurjchem-1508	72	24	s	s	PROPN
eurjchem-1508	72	25	,	,	PUNCT
eurjchem-1508	72	26	2h	2h	NUM
eurjchem-1508	72	27	,	,	PUNCT
eurjchem-1508	72	28	nh2	nh2	PROPN
eurjchem-1508	72	29	,	,	PUNCT
eurjchem-1508	72	30	d2o	d2o	NOUN
eurjchem-1508	72	31	exchangeable	exchangeable	ADJ
eurjchem-1508	72	32	)	)	PUNCT
eurjchem-1508	72	33	,	,	PUNCT
eurjchem-1508	72	34	7.57‐7.61	7.57‐7.61	NUM
eurjchem-1508	72	35	(	(	PUNCT
eurjchem-1508	72	36	m	m	PROPN
eurjchem-1508	72	37	,	,	PUNCT
eurjchem-1508	72	38	4h	4h	NUM
eurjchem-1508	72	39	,	,	PUNCT
eurjchem-1508	72	40	ar‐h	ar‐h	PROPN
eurjchem-1508	72	41	)	)	PUNCT
eurjchem-1508	72	42	,	,	PUNCT
eurjchem-1508	72	43	7.77‐7.80	7.77‐7.80	NUM
eurjchem-1508	72	44	(	(	PUNCT
eurjchem-1508	72	45	m	m	PROPN
eurjchem-1508	72	46	,	,	PUNCT
eurjchem-1508	72	47	1h	1h	NUM
eurjchem-1508	72	48	,	,	PUNCT
eurjchem-1508	72	49	ar‐h	ar‐h	NOUN
eurjchem-1508	72	50	)	)	PUNCT
eurjchem-1508	72	51	,	,	PUNCT
eurjchem-1508	72	52	7.87‐7.88	7.87‐7.88	NUM
eurjchem-1508	72	53	(	(	PUNCT
eurjchem-1508	72	54	dd	dd	PROPN
eurjchem-1508	72	55	,	,	PUNCT
eurjchem-1508	72	56	j	j	NOUN
eurjchem-1508	72	57	=	=	PROPN
eurjchem-1508	72	58	0.8	0.8	NUM
eurjchem-1508	72	59	hz	hz	NOUN
eurjchem-1508	72	60	,	,	PUNCT
eurjchem-1508	72	61	1h	1h	NUM
eurjchem-1508	72	62	,	,	PUNCT
eurjchem-1508	72	63	ar‐h	ar‐h	NOUN
eurjchem-1508	72	64	)	)	PUNCT
eurjchem-1508	72	65	,	,	PUNCT
eurjchem-1508	72	66	7.93‐7.95	7.93‐7.95	NUM
eurjchem-1508	72	67	(	(	PUNCT
eurjchem-1508	72	68	m	m	PROPN
eurjchem-1508	72	69	,	,	PUNCT
eurjchem-1508	72	70	1h	1h	NUM
eurjchem-1508	72	71	,	,	PUNCT
eurjchem-1508	72	72	ar‐h	ar‐h	NOUN
eurjchem-1508	72	73	)	)	PUNCT
eurjchem-1508	72	74	,	,	PUNCT
eurjchem-1508	72	75	8.22‐8.24	8.22‐8.24	NUM
eurjchem-1508	72	76	(	(	PUNCT
eurjchem-1508	72	77	dd	dd	PROPN
eurjchem-1508	72	78	,	,	PUNCT
eurjchem-1508	72	79	j	j	NOUN
eurjchem-1508	73	1	=	=	PROPN
eurjchem-1508	73	2	0.8	0.8	NUM
eurjchem-1508	73	3	hz	hz	NOUN
eurjchem-1508	73	4	,	,	PUNCT
eurjchem-1508	73	5	1h	1h	NUM
eurjchem-1508	73	6	,	,	PUNCT
eurjchem-1508	73	7	ar‐h	ar‐h	NOUN
eurjchem-1508	73	8	)	)	PUNCT
eurjchem-1508	73	9	,	,	PUNCT
eurjchem-1508	73	10	8.62	8.62	NUM
eurjchem-1508	73	11	(	(	PUNCT
eurjchem-1508	73	12	s	s	PROPN
eurjchem-1508	73	13	,	,	PUNCT
eurjchem-1508	73	14	1h	1h	NUM
eurjchem-1508	73	15	,	,	PUNCT
eurjchem-1508	73	16	pyridazine‐h	pyridazine‐h	NOUN
eurjchem-1508	73	17	)	)	PUNCT
eurjchem-1508	73	18	.	.	PUNCT
eurjchem-1508	74	1	ms	ms	NOUN
eurjchem-1508	74	2	(	(	PUNCT
eurjchem-1508	74	3	ei	ei	PROPN
eurjchem-1508	74	4	,	,	PUNCT
eurjchem-1508	74	5	m	m	PROPN
eurjchem-1508	74	6	/	/	SYM
eurjchem-1508	74	7	z	z	PROPN
eurjchem-1508	74	8	(	(	PUNCT
eurjchem-1508	74	9	%	%	NOUN
eurjchem-1508	74	10	)	)	PUNCT
eurjchem-1508	74	11	):	):	PUNCT
eurjchem-1508	74	12	457	457	NUM
eurjchem-1508	74	13	(	(	PUNCT
eurjchem-1508	74	14	m+2	m+2	NOUN
eurjchem-1508	74	15	,	,	PUNCT
eurjchem-1508	74	16	37.2	37.2	NUM
eurjchem-1508	74	17	)	)	PUNCT
eurjchem-1508	74	18	,	,	PUNCT
eurjchem-1508	74	19	456	456	NUM
eurjchem-1508	74	20	(	(	PUNCT
eurjchem-1508	74	21	m+1	m+1	NUM
eurjchem-1508	74	22	,	,	PUNCT
eurjchem-1508	74	23	38.3	38.3	NUM
eurjchem-1508	74	24	)	)	PUNCT
eurjchem-1508	74	25	,	,	PUNCT
eurjchem-1508	74	26	455	455	NUM
eurjchem-1508	74	27	(	(	PUNCT
eurjchem-1508	74	28	m+	m+	NUM
eurjchem-1508	74	29	,	,	PUNCT
eurjchem-1508	74	30	100	100	NUM
eurjchem-1508	74	31	)	)	PUNCT
eurjchem-1508	74	32	.	.	PUNCT
eurjchem-1508	75	1	anal	anal	PROPN
eurjchem-1508	75	2	.	.	PUNCT
eurjchem-1508	75	3	calcd	calcd	NOUN
eurjchem-1508	75	4	.	.	PUNCT
eurjchem-1508	76	1	for	for	SCONJ
eurjchem-1508	76	2	c23h14cln7o2	c23h14cln7o2	PROPN
eurjchem-1508	76	3	:	:	PUNCT
eurjchem-1508	76	4	c	c	X
eurjchem-1508	76	5	,	,	PUNCT
eurjchem-1508	76	6	60.60	60.60	NUM
eurjchem-1508	76	7	;	;	PUNCT
eurjchem-1508	76	8	h	h	NOUN
eurjchem-1508	76	9	,	,	PUNCT
eurjchem-1508	76	10	3.10	3.10	NUM
eurjchem-1508	76	11	,	,	PUNCT
eurjchem-1508	76	12	n	n	CCONJ
eurjchem-1508	76	13	,	,	PUNCT
eurjchem-1508	76	14	21.51	21.51	NUM
eurjchem-1508	76	15	.	.	PUNCT
eurjchem-1508	76	16	found	find	VERB
eurjchem-1508	76	17	:	:	PUNCT
eurjchem-1508	77	1	c	c	X
eurjchem-1508	77	2	,	,	PUNCT
eurjchem-1508	77	3	60.62	60.62	NUM
eurjchem-1508	77	4	;	;	PUNCT
eurjchem-1508	77	5	h	h	NOUN
eurjchem-1508	77	6	,	,	PUNCT
eurjchem-1508	77	7	3.12	3.12	NUM
eurjchem-1508	77	8	,	,	PUNCT
eurjchem-1508	77	9	n	n	CCONJ
eurjchem-1508	77	10	,	,	PUNCT
eurjchem-1508	77	11	21.49	21.49	NUM
eurjchem-1508	77	12	%	%	NOUN
eurjchem-1508	77	13	.	.	PUNCT
eurjchem-1508	78	1	470	470	NUM
eurjchem-1508	78	2	sadek	sadek	PROPN
eurjchem-1508	78	3	et	et	PROPN
eurjchem-1508	78	4	al	al	PROPN
eurjchem-1508	78	5	.	.	PUNCT
eurjchem-1508	78	6	/	/	SYM
eurjchem-1508	78	7	european	european	PROPN
eurjchem-1508	78	8	journal	journal	PROPN
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eurjchem-1508	78	10	chemistry	chemistry	NOUN
eurjchem-1508	78	11	7	7	NUM
eurjchem-1508	78	12	(	(	PUNCT
eurjchem-1508	78	13	4	4	NUM
eurjchem-1508	78	14	)	)	PUNCT
eurjchem-1508	78	15	(	(	PUNCT
eurjchem-1508	78	16	2016	2016	NUM
eurjchem-1508	78	17	)	)	PUNCT
eurjchem-1508	78	18	468‐472	468‐472	PROPN
eurjchem-1508	78	19	scheme	scheme	VERB
eurjchem-1508	78	20	2	2	NUM
eurjchem-1508	78	21	8‐amino‐5‐(2‐tolyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐1h‐pyridazi	8‐amino‐5‐(2‐tolyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐1h‐pyridazi	NUM
eurjchem-1508	78	22	no[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	no[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	NOUN
eurjchem-1508	78	23	(	(	PUNCT
eurjchem-1508	78	24	8d	8d	NUM
eurjchem-1508	78	25	):	):	PUNCT
eurjchem-1508	78	26	recrystal‐	recrystal‐	NUM
eurjchem-1508	78	27	lized	lize	VERB
eurjchem-1508	78	28	from	from	ADP
eurjchem-1508	78	29	dimethylformamide	dimethylformamide	NOUN
eurjchem-1508	78	30	.	.	PUNCT
eurjchem-1508	79	1	color	color	NOUN
eurjchem-1508	79	2	:	:	PUNCT
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eurjchem-1508	79	4	.	.	PUNCT
eurjchem-1508	80	1	m.p	m.p	PROPN
eurjchem-1508	80	2	.	.	PROPN
eurjchem-1508	80	3	:	:	PUNCT
eurjchem-1508	81	1	310‐312	310‐312	NUM
eurjchem-1508	81	2	°	°	PROPN
eurjchem-1508	81	3	c	c	X
eurjchem-1508	81	4	.	.	PUNCT
eurjchem-1508	81	5	yield	yield	NOUN
eurjchem-1508	81	6	:	:	PUNCT
eurjchem-1508	81	7	80	80	NUM
eurjchem-1508	81	8	%	%	NOUN
eurjchem-1508	81	9	.	.	PUNCT
eurjchem-1508	82	1	1h	1h	NUM
eurjchem-1508	82	2	nmr	nmr	NOUN
eurjchem-1508	82	3	(	(	PUNCT
eurjchem-1508	82	4	400	400	NUM
eurjchem-1508	82	5	mhz	mhz	NOUN
eurjchem-1508	82	6	,	,	PUNCT
eurjchem-1508	82	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	82	8	,	,	PUNCT
eurjchem-1508	82	9	δ	δ	PROPN
eurjchem-1508	82	10	,	,	PUNCT
eurjchem-1508	82	11	ppm	ppm	NOUN
eurjchem-1508	82	12	):	):	PUNCT
eurjchem-1508	82	13	2.09	2.09	NUM
eurjchem-1508	82	14	(	(	PUNCT
eurjchem-1508	82	15	s	s	PROPN
eurjchem-1508	82	16	,	,	PUNCT
eurjchem-1508	82	17	3h	3h	NUM
eurjchem-1508	82	18	,	,	PUNCT
eurjchem-1508	82	19	ch3	ch3	PROPN
eurjchem-1508	82	20	)	)	PUNCT
eurjchem-1508	82	21	,	,	PUNCT
eurjchem-1508	82	22	2.14	2.14	NUM
eurjchem-1508	82	23	(	(	PUNCT
eurjchem-1508	82	24	s	s	PROPN
eurjchem-1508	82	25	,	,	PUNCT
eurjchem-1508	82	26	3h	3h	NUM
eurjchem-1508	82	27	,	,	PUNCT
eurjchem-1508	82	28	ch3	ch3	PROPN
eurjchem-1508	82	29	)	)	PUNCT
eurjchem-1508	82	30	,	,	PUNCT
eurjchem-1508	82	31	7.00	7.00	NUM
eurjchem-1508	82	32	(	(	PUNCT
eurjchem-1508	82	33	s	s	PROPN
eurjchem-1508	82	34	,	,	PUNCT
eurjchem-1508	82	35	2h	2h	NUM
eurjchem-1508	82	36	,	,	PUNCT
eurjchem-1508	82	37	nh2	nh2	PROPN
eurjchem-1508	82	38	,	,	PUNCT
eurjchem-1508	82	39	d2o	d2o	NOUN
eurjchem-1508	82	40	exchange‐	exchange‐	NOUN
eurjchem-1508	82	41	able	able	ADJ
eurjchem-1508	82	42	)	)	PUNCT
eurjchem-1508	82	43	,	,	PUNCT
eurjchem-1508	82	44	7.21‐8.24	7.21‐8.24	NUM
eurjchem-1508	82	45	(	(	PUNCT
eurjchem-1508	82	46	m	m	PROPN
eurjchem-1508	82	47	,	,	PUNCT
eurjchem-1508	82	48	8h	8h	NUM
eurjchem-1508	82	49	,	,	PUNCT
eurjchem-1508	82	50	ar‐h	ar‐h	PROPN
eurjchem-1508	82	51	)	)	PUNCT
eurjchem-1508	82	52	,	,	PUNCT
eurjchem-1508	82	53	8.60	8.60	NUM
eurjchem-1508	82	54	(	(	PUNCT
eurjchem-1508	82	55	s	s	PROPN
eurjchem-1508	82	56	,	,	PUNCT
eurjchem-1508	82	57	1h	1h	NUM
eurjchem-1508	82	58	,	,	PUNCT
eurjchem-1508	82	59	pyridazine‐h	pyridazine‐h	NOUN
eurjchem-1508	82	60	)	)	PUNCT
eurjchem-1508	82	61	.	.	PUNCT
eurjchem-1508	83	1	13c	13c	NOUN
eurjchem-1508	83	2	nmr	nmr	NOUN
eurjchem-1508	83	3	(	(	PUNCT
eurjchem-1508	83	4	100	100	NUM
eurjchem-1508	83	5	mhz	mhz	NOUN
eurjchem-1508	83	6	,	,	PUNCT
eurjchem-1508	83	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	83	8	,	,	PUNCT
eurjchem-1508	83	9	δ	δ	PROPN
eurjchem-1508	83	10	,	,	PUNCT
eurjchem-1508	83	11	ppm	ppm	NOUN
eurjchem-1508	83	12	):	):	PUNCT
eurjchem-1508	83	13	13.11	13.11	NUM
eurjchem-1508	83	14	,	,	PUNCT
eurjchem-1508	83	15	19.08	19.08	NUM
eurjchem-1508	83	16	,	,	PUNCT
eurjchem-1508	83	17	73.00	73.00	NUM
eurjchem-1508	83	18	,	,	PUNCT
eurjchem-1508	83	19	108.10	108.10	NUM
eurjchem-1508	83	20	,	,	PUNCT
eurjchem-1508	83	21	115.76	115.76	NUM
eurjchem-1508	83	22	,	,	PUNCT
eurjchem-1508	83	23	116.78	116.78	NUM
eurjchem-1508	83	24	,	,	PUNCT
eurjchem-1508	83	25	125.24	125.24	NUM
eurjchem-1508	83	26	,	,	PUNCT
eurjchem-1508	83	27	125.65	125.65	NUM
eurjchem-1508	83	28	,	,	PUNCT
eurjchem-1508	83	29	128.17	128.17	NUM
eurjchem-1508	83	30	,	,	PUNCT
eurjchem-1508	83	31	128.22	128.22	NUM
eurjchem-1508	83	32	,	,	PUNCT
eurjchem-1508	83	33	130.04	130.04	NUM
eurjchem-1508	83	34	,	,	PUNCT
eurjchem-1508	83	35	130.10	130.10	NUM
eurjchem-1508	83	36	,	,	PUNCT
eurjchem-1508	83	37	130.26	130.26	NUM
eurjchem-1508	83	38	,	,	PUNCT
eurjchem-1508	83	39	130.46	130.46	NUM
eurjchem-1508	83	40	,	,	PUNCT
eurjchem-1508	83	41	134.26	134.26	NUM
eurjchem-1508	83	42	,	,	PUNCT
eurjchem-1508	83	43	134.82	134.82	NUM
eurjchem-1508	83	44	,	,	PUNCT
eurjchem-1508	83	45	134.94	134.94	NUM
eurjchem-1508	83	46	,	,	PUNCT
eurjchem-1508	83	47	137.95	137.95	NUM
eurjchem-1508	83	48	,	,	PUNCT
eurjchem-1508	83	49	139.68	139.68	NUM
eurjchem-1508	83	50	,	,	PUNCT
eurjchem-1508	83	51	137.95	137.95	NUM
eurjchem-1508	83	52	,	,	PUNCT
eurjchem-1508	83	53	139.68	139.68	NUM
eurjchem-1508	83	54	,	,	PUNCT
eurjchem-1508	83	55	144.60	144.60	NUM
eurjchem-1508	83	56	,	,	PUNCT
eurjchem-1508	83	57	150.39	150.39	NUM
eurjchem-1508	83	58	,	,	PUNCT
eurjchem-1508	83	59	152.17	152.17	NUM
eurjchem-1508	83	60	,	,	PUNCT
eurjchem-1508	83	61	161.39	161.39	NUM
eurjchem-1508	83	62	,	,	PUNCT
eurjchem-1508	83	63	166.42	166.42	NUM
eurjchem-1508	83	64	.	.	PUNCT
eurjchem-1508	84	1	ms	ms	NOUN
eurjchem-1508	84	2	(	(	PUNCT
eurjchem-1508	84	3	ei	ei	PROPN
eurjchem-1508	84	4	,	,	PUNCT
eurjchem-1508	84	5	m	m	PROPN
eurjchem-1508	84	6	/	/	SYM
eurjchem-1508	84	7	z	z	PROPN
eurjchem-1508	84	8	(	(	PUNCT
eurjchem-1508	84	9	%	%	NOUN
eurjchem-1508	84	10	)	)	PUNCT
eurjchem-1508	84	11	):	):	PUNCT
eurjchem-1508	84	12	435	435	NUM
eurjchem-1508	84	13	(	(	PUNCT
eurjchem-1508	84	14	m+	m+	NUM
eurjchem-1508	84	15	,	,	PUNCT
eurjchem-1508	84	16	50	50	NUM
eurjchem-1508	84	17	)	)	PUNCT
eurjchem-1508	84	18	.	.	PUNCT
eurjchem-1508	85	1	anal	anal	PROPN
eurjchem-1508	85	2	.	.	PUNCT
eurjchem-1508	85	3	calcd	calcd	NOUN
eurjchem-1508	85	4	.	.	PUNCT
eurjchem-1508	86	1	for	for	ADP
eurjchem-1508	86	2	c24h17n7o2	c24h17n7o2	PROPN
eurjchem-1508	86	3	:	:	PUNCT
eurjchem-1508	86	4	c	c	X
eurjchem-1508	86	5	,	,	PUNCT
eurjchem-1508	86	6	66.20	66.20	NUM
eurjchem-1508	86	7	;	;	PUNCT
eurjchem-1508	86	8	h	h	NOUN
eurjchem-1508	86	9	,	,	PUNCT
eurjchem-1508	86	10	3.94	3.94	NUM
eurjchem-1508	86	11	;	;	PUNCT
eurjchem-1508	86	12	n	n	CCONJ
eurjchem-1508	86	13	,	,	PUNCT
eurjchem-1508	86	14	22.52	22.52	NUM
eurjchem-1508	86	15	.	.	PUNCT
eurjchem-1508	86	16	found	find	VERB
eurjchem-1508	86	17	:	:	PUNCT
eurjchem-1508	87	1	c	c	X
eurjchem-1508	87	2	,	,	PUNCT
eurjchem-1508	87	3	66.23	66.23	NUM
eurjchem-1508	87	4	;	;	PUNCT
eurjchem-1508	87	5	h	h	NOUN
eurjchem-1508	87	6	,	,	PUNCT
eurjchem-1508	87	7	3.88	3.88	NUM
eurjchem-1508	87	8	;	;	PUNCT
eurjchem-1508	87	9	n	n	CCONJ
eurjchem-1508	87	10	,	,	PUNCT
eurjchem-1508	87	11	22.55	22.55	NUM
eurjchem-1508	87	12	%	%	NOUN
eurjchem-1508	87	13	.	.	PUNCT
eurjchem-1508	88	1	8‐amino‐5‐(4‐tolyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐1h‐pyridazi	8‐amino‐5‐(4‐tolyl)‐4‐methyl‐1‐(2‐nitrophenyl)‐1h‐pyridazi	NUM
eurjchem-1508	88	2	no[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	no[5,4,3‐de]1,6‐naphthyridine‐7‐carbonitrile	PROPN
eurjchem-1508	88	3	(	(	PUNCT
eurjchem-1508	88	4	8e	8e	NUM
eurjchem-1508	88	5	):	):	PUNCT
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eurjchem-1508	88	7	lized	lize	VERB
eurjchem-1508	88	8	from	from	ADP
eurjchem-1508	88	9	acetic	acetic	ADJ
eurjchem-1508	88	10	acid	acid	NOUN
eurjchem-1508	88	11	.	.	PUNCT
eurjchem-1508	89	1	color	color	NOUN
eurjchem-1508	89	2	:	:	PUNCT
eurjchem-1508	89	3	orange	orange	PROPN
eurjchem-1508	89	4	.	.	PUNCT
eurjchem-1508	90	1	m.p	m.p	PROPN
eurjchem-1508	90	2	.	.	PROPN
eurjchem-1508	90	3	:	:	PUNCT
eurjchem-1508	91	1	299‐300	299‐300	NUM
eurjchem-1508	91	2	°	°	NUM
eurjchem-1508	91	3	c	c	X
eurjchem-1508	91	4	.	.	PUNCT
eurjchem-1508	91	5	yield	yield	NOUN
eurjchem-1508	91	6	:	:	PUNCT
eurjchem-1508	91	7	70	70	NUM
eurjchem-1508	91	8	%	%	NOUN
eurjchem-1508	91	9	.	.	PUNCT
eurjchem-1508	92	1	1h	1h	NUM
eurjchem-1508	92	2	nmr	nmr	NOUN
eurjchem-1508	92	3	(	(	PUNCT
eurjchem-1508	92	4	400	400	NUM
eurjchem-1508	92	5	mhz	mhz	NOUN
eurjchem-1508	92	6	,	,	PUNCT
eurjchem-1508	92	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	92	8	,	,	PUNCT
eurjchem-1508	92	9	δ	δ	PROPN
eurjchem-1508	92	10	,	,	PUNCT
eurjchem-1508	92	11	ppm	ppm	NUM
eurjchem-1508	92	12	):	):	PUNCT
eurjchem-1508	92	13	2.36	2.36	NUM
eurjchem-1508	92	14	(	(	PUNCT
eurjchem-1508	92	15	s	s	PROPN
eurjchem-1508	92	16	,	,	PUNCT
eurjchem-1508	92	17	3h	3h	NUM
eurjchem-1508	92	18	,	,	PUNCT
eurjchem-1508	92	19	ch3	ch3	PROPN
eurjchem-1508	92	20	)	)	PUNCT
eurjchem-1508	92	21	,	,	PUNCT
eurjchem-1508	92	22	2.50	2.50	NUM
eurjchem-1508	92	23	(	(	PUNCT
eurjchem-1508	92	24	s	s	PROPN
eurjchem-1508	92	25	,	,	PUNCT
eurjchem-1508	92	26	3h	3h	NUM
eurjchem-1508	92	27	,	,	PUNCT
eurjchem-1508	92	28	ch3	ch3	PROPN
eurjchem-1508	92	29	)	)	PUNCT
eurjchem-1508	92	30	,	,	PUNCT
eurjchem-1508	92	31	6.90	6.90	NUM
eurjchem-1508	92	32	(	(	PUNCT
eurjchem-1508	92	33	s	s	NOUN
eurjchem-1508	92	34	,	,	PUNCT
eurjchem-1508	92	35	2h	2h	NUM
eurjchem-1508	92	36	,	,	PUNCT
eurjchem-1508	92	37	nh2	nh2	PROPN
eurjchem-1508	92	38	,	,	PUNCT
eurjchem-1508	92	39	d2o	d2o	NOUN
eurjchem-1508	92	40	exchangeable	exchangeable	ADJ
eurjchem-1508	92	41	)	)	PUNCT
eurjchem-1508	92	42	,	,	PUNCT
eurjchem-1508	92	43	7.34	7.34	NUM
eurjchem-1508	92	44	(	(	PUNCT
eurjchem-1508	92	45	d	d	PROPN
eurjchem-1508	92	46	,	,	PUNCT
eurjchem-1508	92	47	j	j	PROPN
eurjchem-1508	92	48	=	=	SYM
eurjchem-1508	92	49	5.2	5.2	NUM
eurjchem-1508	92	50	,	,	PUNCT
eurjchem-1508	92	51	2h	2h	NUM
eurjchem-1508	92	52	,	,	PUNCT
eurjchem-1508	92	53	ar‐h	ar‐h	NOUN
eurjchem-1508	92	54	)	)	PUNCT
eurjchem-1508	92	55	,	,	PUNCT
eurjchem-1508	92	56	7.48	7.48	NUM
eurjchem-1508	92	57	(	(	PUNCT
eurjchem-1508	92	58	d	d	PROPN
eurjchem-1508	92	59	,	,	PUNCT
eurjchem-1508	92	60	j	j	PROPN
eurjchem-1508	92	61	=	=	SYM
eurjchem-1508	92	62	5.2	5.2	NUM
eurjchem-1508	92	63	,	,	PUNCT
eurjchem-1508	92	64	2h	2h	NUM
eurjchem-1508	92	65	,	,	PUNCT
eurjchem-1508	92	66	ar‐h	ar‐h	NOUN
eurjchem-1508	92	67	)	)	PUNCT
eurjchem-1508	92	68	,	,	PUNCT
eurjchem-1508	92	69	7.77‐7.80	7.77‐7.80	NUM
eurjchem-1508	92	70	(	(	PUNCT
eurjchem-1508	92	71	m	m	PROPN
eurjchem-1508	92	72	,	,	PUNCT
eurjchem-1508	92	73	1h	1h	NUM
eurjchem-1508	92	74	,	,	PUNCT
eurjchem-1508	92	75	ar‐h	ar‐h	NOUN
eurjchem-1508	92	76	)	)	PUNCT
eurjchem-1508	92	77	,	,	PUNCT
eurjchem-1508	92	78	7.88‐7.89	7.88‐7.89	NUM
eurjchem-1508	92	79	(	(	PUNCT
eurjchem-1508	92	80	dd	dd	PROPN
eurjchem-1508	92	81	,	,	PUNCT
eurjchem-1508	92	82	j	j	NOUN
eurjchem-1508	92	83	=	=	PROPN
eurjchem-1508	92	84	0.8	0.8	NUM
eurjchem-1508	92	85	hz	hz	NOUN
eurjchem-1508	92	86	,	,	PUNCT
eurjchem-1508	92	87	1h	1h	NUM
eurjchem-1508	92	88	,	,	PUNCT
eurjchem-1508	92	89	ar‐h	ar‐h	NOUN
eurjchem-1508	92	90	)	)	PUNCT
eurjchem-1508	92	91	,	,	PUNCT
eurjchem-1508	92	92	7.96‐7.98	7.96‐7.98	NUM
eurjchem-1508	92	93	(	(	PUNCT
eurjchem-1508	92	94	m	m	PROPN
eurjchem-1508	92	95	,	,	PUNCT
eurjchem-1508	92	96	1h	1h	NUM
eurjchem-1508	92	97	,	,	PUNCT
eurjchem-1508	92	98	ar‐h	ar‐h	NOUN
eurjchem-1508	92	99	)	)	PUNCT
eurjchem-1508	92	100	,	,	PUNCT
eurjchem-1508	92	101	8.23‐8.24	8.23‐8.24	NUM
eurjchem-1508	92	102	(	(	PUNCT
eurjchem-1508	92	103	dd	dd	PROPN
eurjchem-1508	92	104	,	,	PUNCT
eurjchem-1508	92	105	j	j	NOUN
eurjchem-1508	93	1	=	=	PROPN
eurjchem-1508	93	2	0.8	0.8	NUM
eurjchem-1508	93	3	hz	hz	NOUN
eurjchem-1508	93	4	,	,	PUNCT
eurjchem-1508	93	5	1h	1h	NUM
eurjchem-1508	93	6	,	,	PUNCT
eurjchem-1508	93	7	ar‐h	ar‐h	NOUN
eurjchem-1508	93	8	)	)	PUNCT
eurjchem-1508	93	9	,	,	PUNCT
eurjchem-1508	93	10	8.61	8.61	NUM
eurjchem-1508	93	11	(	(	PUNCT
eurjchem-1508	93	12	s	s	PROPN
eurjchem-1508	93	13	,	,	PUNCT
eurjchem-1508	93	14	1h	1h	NUM
eurjchem-1508	93	15	,	,	PUNCT
eurjchem-1508	93	16	pyridazine‐h	pyridazine‐h	NOUN
eurjchem-1508	93	17	)	)	PUNCT
eurjchem-1508	93	18	.	.	PUNCT
eurjchem-1508	94	1	ms	ms	NOUN
eurjchem-1508	94	2	(	(	PUNCT
eurjchem-1508	94	3	ei	ei	PROPN
eurjchem-1508	94	4	,	,	PUNCT
eurjchem-1508	94	5	m	m	PROPN
eurjchem-1508	94	6	/	/	SYM
eurjchem-1508	94	7	z	z	PROPN
eurjchem-1508	94	8	(	(	PUNCT
eurjchem-1508	94	9	%	%	NOUN
eurjchem-1508	94	10	)	)	PUNCT
eurjchem-1508	94	11	):	):	PUNCT
eurjchem-1508	94	12	437	437	NUM
eurjchem-1508	94	13	(	(	PUNCT
eurjchem-1508	94	14	m+2	m+2	NOUN
eurjchem-1508	94	15	,	,	PUNCT
eurjchem-1508	94	16	28.2	28.2	NUM
eurjchem-1508	94	17	)	)	PUNCT
eurjchem-1508	94	18	,	,	PUNCT
eurjchem-1508	94	19	435	435	NUM
eurjchem-1508	94	20	(	(	PUNCT
eurjchem-1508	94	21	m+	m+	NUM
eurjchem-1508	94	22	,	,	PUNCT
eurjchem-1508	94	23	100	100	NUM
eurjchem-1508	94	24	)	)	PUNCT
eurjchem-1508	94	25	.	.	PUNCT
eurjchem-1508	95	1	anal	anal	PROPN
eurjchem-1508	95	2	.	.	PUNCT
eurjchem-1508	95	3	calcd	calcd	NOUN
eurjchem-1508	95	4	.	.	PUNCT
eurjchem-1508	96	1	for	for	ADP
eurjchem-1508	96	2	c24h17n7o2	c24h17n7o2	PROPN
eurjchem-1508	96	3	:	:	PUNCT
eurjchem-1508	96	4	c	c	X
eurjchem-1508	96	5	,	,	PUNCT
eurjchem-1508	96	6	66.20	66.20	NUM
eurjchem-1508	96	7	;	;	PUNCT
eurjchem-1508	96	8	h	h	NOUN
eurjchem-1508	96	9	,	,	PUNCT
eurjchem-1508	96	10	3.94	3.94	NUM
eurjchem-1508	96	11	;	;	PUNCT
eurjchem-1508	96	12	n	n	CCONJ
eurjchem-1508	96	13	,	,	PUNCT
eurjchem-1508	96	14	22.52	22.52	NUM
eurjchem-1508	96	15	.	.	PUNCT
eurjchem-1508	96	16	found	find	VERB
eurjchem-1508	96	17	:	:	PUNCT
eurjchem-1508	97	1	c	c	X
eurjchem-1508	97	2	,	,	PUNCT
eurjchem-1508	97	3	66.31	66.31	NUM
eurjchem-1508	97	4	;	;	PUNCT
eurjchem-1508	97	5	h	h	NOUN
eurjchem-1508	97	6	,	,	PUNCT
eurjchem-1508	97	7	3.88	3.88	NUM
eurjchem-1508	97	8	;	;	PUNCT
eurjchem-1508	97	9	n	n	CCONJ
eurjchem-1508	97	10	,	,	PUNCT
eurjchem-1508	97	11	22.56	22.56	NUM
eurjchem-1508	97	12	%	%	NOUN
eurjchem-1508	97	13	.	.	PUNCT
eurjchem-1508	98	1	ethyl	ethyl	PROPN
eurjchem-1508	98	2	2‐(2‐((5‐amino‐4,6‐dicyano[1,1'‐biphenyl]‐3‐yl)met‐	2‐(2‐((5‐amino‐4,6‐dicyano[1,1'‐biphenyl]‐3‐yl)met‐	NUM
eurjchem-1508	98	3	hylene)hydrazinyl)benzoate	hylene)hydrazinyl)benzoate	NOUN
eurjchem-1508	98	4	(	(	PUNCT
eurjchem-1508	98	5	4a	4a	NOUN
eurjchem-1508	98	6	):	):	PUNCT
eurjchem-1508	98	7	recrystallized	recrystallize	VERB
eurjchem-1508	98	8	from	from	ADP
eurjchem-1508	98	9	dimethyl	dimethyl	PROPN
eurjchem-1508	98	10	formamide	formamide	ADV
eurjchem-1508	98	11	.	.	PUNCT
eurjchem-1508	99	1	color	color	NOUN
eurjchem-1508	99	2	:	:	PUNCT
eurjchem-1508	99	3	brown	brown	ADJ
eurjchem-1508	99	4	.	.	PUNCT
eurjchem-1508	100	1	m.p	m.p	PROPN
eurjchem-1508	100	2	.	.	PROPN
eurjchem-1508	100	3	:	:	PUNCT
eurjchem-1508	101	1	>	>	PUNCT
eurjchem-1508	101	2	350	350	NUM
eurjchem-1508	101	3	°	°	NOUN
eurjchem-1508	101	4	c	c	X
eurjchem-1508	101	5	.	.	PUNCT
eurjchem-1508	101	6	yield	yield	NOUN
eurjchem-1508	101	7	:	:	PUNCT
eurjchem-1508	101	8	80	80	NUM
eurjchem-1508	101	9	%	%	NOUN
eurjchem-1508	101	10	.	.	PUNCT
eurjchem-1508	102	1	1h	1h	NUM
eurjchem-1508	102	2	nmr	nmr	NOUN
eurjchem-1508	102	3	(	(	PUNCT
eurjchem-1508	102	4	400	400	NUM
eurjchem-1508	102	5	mhz	mhz	NOUN
eurjchem-1508	102	6	,	,	PUNCT
eurjchem-1508	102	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	102	8	,	,	PUNCT
eurjchem-1508	102	9	δ	δ	PROPN
eurjchem-1508	102	10	,	,	PUNCT
eurjchem-1508	102	11	ppm	ppm	NUM
eurjchem-1508	102	12	):	):	PUNCT
eurjchem-1508	102	13	1.35	1.35	NUM
eurjchem-1508	102	14	(	(	PUNCT
eurjchem-1508	102	15	t	t	PROPN
eurjchem-1508	102	16	,	,	PUNCT
eurjchem-1508	102	17	j	j	PROPN
eurjchem-1508	102	18	=	=	SYM
eurjchem-1508	102	19	4.8	4.8	NUM
eurjchem-1508	102	20	hz	hz	NOUN
eurjchem-1508	102	21	,	,	PUNCT
eurjchem-1508	102	22	3h	3h	NUM
eurjchem-1508	102	23	,	,	PUNCT
eurjchem-1508	102	24	ch3	ch3	PROPN
eurjchem-1508	102	25	)	)	PUNCT
eurjchem-1508	102	26	,	,	PUNCT
eurjchem-1508	102	27	4.32‐	4.32‐	NUM
eurjchem-1508	102	28	4.35	4.35	NUM
eurjchem-1508	102	29	(	(	PUNCT
eurjchem-1508	102	30	q	q	NOUN
eurjchem-1508	102	31	,	,	PUNCT
eurjchem-1508	102	32	j	j	PROPN
eurjchem-1508	103	1	=	=	SYM
eurjchem-1508	103	2	4.8	4.8	NUM
eurjchem-1508	103	3	hz	hz	VERB
eurjchem-1508	103	4	,	,	PUNCT
eurjchem-1508	103	5	2h	2h	NUM
eurjchem-1508	103	6	,	,	PUNCT
eurjchem-1508	103	7	ch2	ch2	PROPN
eurjchem-1508	103	8	)	)	PUNCT
eurjchem-1508	103	9	6.73	6.73	NUM
eurjchem-1508	103	10	(	(	PUNCT
eurjchem-1508	103	11	s	s	PROPN
eurjchem-1508	103	12	,	,	PUNCT
eurjchem-1508	103	13	2h	2h	NUM
eurjchem-1508	103	14	,	,	PUNCT
eurjchem-1508	103	15	nh2	nh2	PROPN
eurjchem-1508	103	16	,	,	PUNCT
eurjchem-1508	103	17	d2o	d2o	NOUN
eurjchem-1508	103	18	exchange‐	exchange‐	NOUN
eurjchem-1508	103	19	able	able	ADJ
eurjchem-1508	103	20	)	)	PUNCT
eurjchem-1508	103	21	,	,	PUNCT
eurjchem-1508	103	22	6.93	6.93	NUM
eurjchem-1508	103	23	(	(	PUNCT
eurjchem-1508	103	24	m	m	PROPN
eurjchem-1508	103	25	,	,	PUNCT
eurjchem-1508	103	26	1h	1h	NUM
eurjchem-1508	103	27	,	,	PUNCT
eurjchem-1508	103	28	ar‐h	ar‐h	NOUN
eurjchem-1508	103	29	)	)	PUNCT
eurjchem-1508	103	30	,	,	PUNCT
eurjchem-1508	103	31	7.13	7.13	NUM
eurjchem-1508	103	32	(	(	PUNCT
eurjchem-1508	103	33	s	s	PROPN
eurjchem-1508	103	34	,	,	PUNCT
eurjchem-1508	103	35	1h	1h	NUM
eurjchem-1508	103	36	,	,	PUNCT
eurjchem-1508	103	37	hydrazinyl‐ch	hydrazinyl‐ch	NOUN
eurjchem-1508	103	38	)	)	PUNCT
eurjchem-1508	103	39	,	,	PUNCT
eurjchem-1508	103	40	7.53‐	7.53‐	NUM
eurjchem-1508	103	41	7.56	7.56	NUM
eurjchem-1508	103	42	(	(	PUNCT
eurjchem-1508	103	43	m	m	PROPN
eurjchem-1508	103	44	,	,	PUNCT
eurjchem-1508	103	45	4h	4h	NUM
eurjchem-1508	103	46	,	,	PUNCT
eurjchem-1508	103	47	ar‐h	ar‐h	NOUN
eurjchem-1508	103	48	)	)	PUNCT
eurjchem-1508	103	49	,	,	PUNCT
eurjchem-1508	103	50	7.58‐7.60	7.58‐7.60	NUM
eurjchem-1508	103	51	(	(	PUNCT
eurjchem-1508	103	52	m	m	PROPN
eurjchem-1508	103	53	,	,	PUNCT
eurjchem-1508	103	54	2h	2h	NUM
eurjchem-1508	103	55	,	,	PUNCT
eurjchem-1508	103	56	ar‐h	ar‐h	NOUN
eurjchem-1508	103	57	)	)	PUNCT
eurjchem-1508	103	58	,	,	PUNCT
eurjchem-1508	103	59	7.80‐7.81	7.80‐7.81	NUM
eurjchem-1508	103	60	(	(	PUNCT
eurjchem-1508	103	61	dd	dd	PROPN
eurjchem-1508	103	62	,	,	PUNCT
eurjchem-1508	103	63	j	j	NOUN
eurjchem-1508	103	64	=	=	PROPN
eurjchem-1508	103	65	0.8	0.8	NUM
eurjchem-1508	103	66	hz	hz	NOUN
eurjchem-1508	103	67	,	,	PUNCT
eurjchem-1508	103	68	1h	1h	NUM
eurjchem-1508	103	69	,	,	PUNCT
eurjchem-1508	103	70	ar‐h	ar‐h	NOUN
eurjchem-1508	103	71	)	)	PUNCT
eurjchem-1508	103	72	,	,	PUNCT
eurjchem-1508	103	73	7.86‐7.88	7.86‐7.88	NUM
eurjchem-1508	103	74	(	(	PUNCT
eurjchem-1508	103	75	m	m	PROPN
eurjchem-1508	103	76	,	,	PUNCT
eurjchem-1508	103	77	1h	1h	NUM
eurjchem-1508	103	78	,	,	PUNCT
eurjchem-1508	103	79	ar‐h	ar‐h	NOUN
eurjchem-1508	103	80	)	)	PUNCT
eurjchem-1508	103	81	,	,	PUNCT
eurjchem-1508	103	82	8.31	8.31	NUM
eurjchem-1508	103	83	(	(	PUNCT
eurjchem-1508	103	84	s	s	PROPN
eurjchem-1508	103	85	,	,	PUNCT
eurjchem-1508	103	86	1h	1h	NUM
eurjchem-1508	103	87	,	,	PUNCT
eurjchem-1508	103	88	ar‐h	ar‐h	NOUN
eurjchem-1508	103	89	)	)	PUNCT
eurjchem-1508	103	90	,	,	PUNCT
eurjchem-1508	103	91	11.45	11.45	NUM
eurjchem-1508	103	92	(	(	PUNCT
eurjchem-1508	103	93	s	s	PROPN
eurjchem-1508	103	94	,	,	PUNCT
eurjchem-1508	103	95	1h	1h	NUM
eurjchem-1508	103	96	,	,	PUNCT
eurjchem-1508	103	97	nh	nh	PROPN
eurjchem-1508	103	98	,	,	PUNCT
eurjchem-1508	103	99	d2o	d2o	PROPN
eurjchem-1508	103	100	exchangeable	exchangeable	ADJ
eurjchem-1508	103	101	)	)	PUNCT
eurjchem-1508	103	102	.	.	PUNCT
eurjchem-1508	104	1	13c	13c	NOUN
eurjchem-1508	104	2	nmr	nmr	NOUN
eurjchem-1508	104	3	(	(	PUNCT
eurjchem-1508	104	4	100	100	NUM
eurjchem-1508	104	5	mhz	mhz	NOUN
eurjchem-1508	104	6	,	,	PUNCT
eurjchem-1508	104	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	104	8	,	,	PUNCT
eurjchem-1508	104	9	δ	δ	PROPN
eurjchem-1508	104	10	,	,	PUNCT
eurjchem-1508	104	11	ppm	ppm	NOUN
eurjchem-1508	104	12	):	):	PUNCT
eurjchem-1508	104	13	14.56	14.56	NUM
eurjchem-1508	104	14	,	,	PUNCT
eurjchem-1508	104	15	61.38	61.38	NUM
eurjchem-1508	104	16	,	,	PUNCT
eurjchem-1508	104	17	91.72	91.72	NUM
eurjchem-1508	104	18	,	,	PUNCT
eurjchem-1508	104	19	94.56	94.56	NUM
eurjchem-1508	104	20	,	,	PUNCT
eurjchem-1508	104	21	111.54	111.54	NUM
eurjchem-1508	104	22	,	,	PUNCT
eurjchem-1508	104	23	114.81	114.81	NUM
eurjchem-1508	104	24	,	,	PUNCT
eurjchem-1508	104	25	116.14	116.14	NUM
eurjchem-1508	104	26	,	,	PUNCT
eurjchem-1508	104	27	116.62	116.62	NUM
eurjchem-1508	104	28	,	,	PUNCT
eurjchem-1508	104	29	120.01	120.01	NUM
eurjchem-1508	104	30	,	,	PUNCT
eurjchem-1508	104	31	128.87	128.87	NUM
eurjchem-1508	104	32	,	,	PUNCT
eurjchem-1508	104	33	129.21	129.21	NUM
eurjchem-1508	104	34	,	,	PUNCT
eurjchem-1508	104	35	129.84	129.84	NUM
eurjchem-1508	104	36	,	,	PUNCT
eurjchem-1508	104	37	131.11	131.11	NUM
eurjchem-1508	104	38	,	,	PUNCT
eurjchem-1508	104	39	131.11	131.11	NUM
eurjchem-1508	104	40	,	,	PUNCT
eurjchem-1508	104	41	135.20	135.20	NUM
eurjchem-1508	104	42	,	,	PUNCT
eurjchem-1508	104	43	136.75	136.75	NUM
eurjchem-1508	104	44	,	,	PUNCT
eurjchem-1508	104	45	138.12	138.12	NUM
eurjchem-1508	104	46	,	,	PUNCT
eurjchem-1508	104	47	142.61	142.61	NUM
eurjchem-1508	104	48	,	,	PUNCT
eurjchem-1508	104	49	146.01	146.01	NUM
eurjchem-1508	104	50	,	,	PUNCT
eurjchem-1508	104	51	150.05	150.05	NUM
eurjchem-1508	104	52	,	,	PUNCT
eurjchem-1508	104	53	154.66	154.66	NUM
eurjchem-1508	104	54	,	,	PUNCT
eurjchem-1508	104	55	167.42	167.42	NUM
eurjchem-1508	104	56	.	.	PUNCT
eurjchem-1508	105	1	ms	ms	NOUN
eurjchem-1508	105	2	(	(	PUNCT
eurjchem-1508	105	3	ei	ei	PROPN
eurjchem-1508	105	4	,	,	PUNCT
eurjchem-1508	105	5	m	m	PROPN
eurjchem-1508	105	6	/	/	SYM
eurjchem-1508	105	7	z	z	PROPN
eurjchem-1508	105	8	(	(	PUNCT
eurjchem-1508	105	9	%	%	NOUN
eurjchem-1508	105	10	)	)	PUNCT
eurjchem-1508	105	11	):	):	PUNCT
eurjchem-1508	105	12	410	410	NUM
eurjchem-1508	105	13	(	(	PUNCT
eurjchem-1508	105	14	m+1	m+1	PROPN
eurjchem-1508	105	15	,	,	PUNCT
eurjchem-1508	105	16	4.8	4.8	NUM
eurjchem-1508	105	17	)	)	PUNCT
eurjchem-1508	105	18	,	,	PUNCT
eurjchem-1508	105	19	409	409	NUM
eurjchem-1508	105	20	(	(	PUNCT
eurjchem-1508	105	21	m+	m+	NUM
eurjchem-1508	105	22	,	,	PUNCT
eurjchem-1508	105	23	65.6	65.6	NUM
eurjchem-1508	105	24	)	)	PUNCT
eurjchem-1508	105	25	.	.	PUNCT
eurjchem-1508	106	1	anal	anal	PROPN
eurjchem-1508	106	2	.	.	PUNCT
eurjchem-1508	106	3	calcd	calcd	NOUN
eurjchem-1508	106	4	.	.	PUNCT
eurjchem-1508	107	1	for	for	ADP
eurjchem-1508	107	2	c24h19n5o2	c24h19n5o2	PROPN
eurjchem-1508	107	3	:	:	PUNCT
eurjchem-1508	107	4	c	c	X
eurjchem-1508	107	5	,	,	PUNCT
eurjchem-1508	107	6	70.40	70.40	NUM
eurjchem-1508	107	7	;	;	PUNCT
eurjchem-1508	107	8	h	h	NOUN
eurjchem-1508	107	9	,	,	PUNCT
eurjchem-1508	107	10	4.68	4.68	NUM
eurjchem-1508	107	11	;	;	PUNCT
eurjchem-1508	107	12	n	n	CCONJ
eurjchem-1508	107	13	,	,	PUNCT
eurjchem-1508	107	14	17.10	17.10	NUM
eurjchem-1508	107	15	.	.	PUNCT
eurjchem-1508	107	16	found	find	VERB
eurjchem-1508	107	17	:	:	PUNCT
eurjchem-1508	108	1	c	c	X
eurjchem-1508	108	2	,	,	PUNCT
eurjchem-1508	108	3	70.44	70.44	NUM
eurjchem-1508	108	4	;	;	PUNCT
eurjchem-1508	108	5	h	h	NOUN
eurjchem-1508	108	6	,	,	PUNCT
eurjchem-1508	108	7	4.70	4.70	NUM
eurjchem-1508	108	8	,	,	PUNCT
eurjchem-1508	108	9	n	n	CCONJ
eurjchem-1508	108	10	,	,	PUNCT
eurjchem-1508	108	11	17.22	17.22	NUM
eurjchem-1508	108	12	%	%	NOUN
eurjchem-1508	108	13	.	.	PUNCT
eurjchem-1508	109	1	ethyl	ethyl	PROPN
eurjchem-1508	109	2	2‐(2‐((5‐amino‐4‐chloro‐4,6‐dicyano[1,1'‐biphenyl]‐3‐	2‐(2‐((5‐amino‐4‐chloro‐4,6‐dicyano[1,1'‐biphenyl]‐3‐	PROPN
eurjchem-1508	109	3	yl)methylene)hydrazineyl)benzoate	yl)methylene)hydrazineyl)benzoate	PROPN
eurjchem-1508	109	4	(	(	PUNCT
eurjchem-1508	109	5	4b	4b	PROPN
eurjchem-1508	109	6	):	):	PUNCT
eurjchem-1508	109	7	recrystallized	recrystallize	VERB
eurjchem-1508	109	8	from	from	ADP
eurjchem-1508	109	9	dimethylformamide	dimethylformamide	NOUN
eurjchem-1508	109	10	.	.	PUNCT
eurjchem-1508	110	1	color	color	NOUN
eurjchem-1508	110	2	:	:	PUNCT
eurjchem-1508	110	3	dark	dark	PROPN
eurjchem-1508	110	4	brown	brown	PROPN
eurjchem-1508	110	5	.	.	PUNCT
eurjchem-1508	111	1	m.p	m.p	PROPN
eurjchem-1508	111	2	.	.	PROPN
eurjchem-1508	111	3	:	:	PUNCT
eurjchem-1508	112	1	291‐292	291‐292	NUM
eurjchem-1508	112	2	°	°	PRON
eurjchem-1508	112	3	c	c	X
eurjchem-1508	112	4	.	.	PUNCT
eurjchem-1508	112	5	yield	yield	NOUN
eurjchem-1508	112	6	:	:	PUNCT
eurjchem-1508	112	7	72	72	NUM
eurjchem-1508	112	8	%	%	NOUN
eurjchem-1508	112	9	.	.	PUNCT
eurjchem-1508	113	1	1h	1h	NUM
eurjchem-1508	113	2	nmr	nmr	NOUN
eurjchem-1508	113	3	(	(	PUNCT
eurjchem-1508	113	4	400	400	NUM
eurjchem-1508	113	5	mhz	mhz	NOUN
eurjchem-1508	113	6	,	,	PUNCT
eurjchem-1508	113	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	113	8	,	,	PUNCT
eurjchem-1508	113	9	δ	δ	PROPN
eurjchem-1508	113	10	,	,	PUNCT
eurjchem-1508	113	11	ppm	ppm	NUM
eurjchem-1508	113	12	):	):	PUNCT
eurjchem-1508	113	13	1.35	1.35	NUM
eurjchem-1508	113	14	(	(	PUNCT
eurjchem-1508	113	15	t	t	PROPN
eurjchem-1508	113	16	,	,	PUNCT
eurjchem-1508	113	17	j	j	PROPN
eurjchem-1508	113	18	=	=	SYM
eurjchem-1508	113	19	7.2	7.2	NUM
eurjchem-1508	113	20	hz	hz	NOUN
eurjchem-1508	113	21	,	,	PUNCT
eurjchem-1508	113	22	3h	3h	NUM
eurjchem-1508	113	23	,	,	PUNCT
eurjchem-1508	113	24	ch3	ch3	PROPN
eurjchem-1508	113	25	)	)	PUNCT
eurjchem-1508	113	26	,	,	PUNCT
eurjchem-1508	113	27	4.33‐4.36	4.33‐4.36	NUM
eurjchem-1508	113	28	(	(	PUNCT
eurjchem-1508	113	29	q	q	NOUN
eurjchem-1508	113	30	,	,	PUNCT
eurjchem-1508	113	31	j	j	PROPN
eurjchem-1508	113	32	=	=	SYM
eurjchem-1508	113	33	4.8	4.8	NUM
eurjchem-1508	113	34	hz	hz	VERB
eurjchem-1508	113	35	,	,	PUNCT
eurjchem-1508	113	36	2h	2h	NUM
eurjchem-1508	113	37	,	,	PUNCT
eurjchem-1508	113	38	ch2	ch2	PROPN
eurjchem-1508	113	39	)	)	PUNCT
eurjchem-1508	113	40	,	,	PUNCT
eurjchem-1508	113	41	6.78	6.78	NUM
eurjchem-1508	113	42	(	(	PUNCT
eurjchem-1508	113	43	s	s	PROPN
eurjchem-1508	113	44	,	,	PUNCT
eurjchem-1508	113	45	2h	2h	NUM
eurjchem-1508	113	46	,	,	PUNCT
eurjchem-1508	113	47	nh2	nh2	PROPN
eurjchem-1508	113	48	,	,	PUNCT
eurjchem-1508	113	49	d2o	d2o	NOUN
eurjchem-1508	113	50	exchangeable	exchangeable	ADJ
eurjchem-1508	113	51	)	)	PUNCT
eurjchem-1508	113	52	,	,	PUNCT
eurjchem-1508	113	53	6.93‐6.95	6.93‐6.95	X
eurjchem-1508	113	54	(	(	PUNCT
eurjchem-1508	113	55	m	m	PROPN
eurjchem-1508	113	56	,	,	PUNCT
eurjchem-1508	113	57	1h	1h	NUM
eurjchem-1508	113	58	,	,	PUNCT
eurjchem-1508	113	59	ar‐h	ar‐h	NOUN
eurjchem-1508	113	60	)	)	PUNCT
eurjchem-1508	113	61	,	,	PUNCT
eurjchem-1508	113	62	7.15	7.15	NUM
eurjchem-1508	113	63	(	(	PUNCT
eurjchem-1508	113	64	s	s	PROPN
eurjchem-1508	113	65	,	,	PUNCT
eurjchem-1508	113	66	1h	1h	NUM
eurjchem-1508	113	67	,	,	PUNCT
eurjchem-1508	113	68	hydrazinyl‐ch	hydrazinyl‐ch	NOUN
eurjchem-1508	113	69	)	)	PUNCT
eurjchem-1508	113	70	,	,	PUNCT
eurjchem-1508	113	71	7.53‐7.62	7.53‐7.62	NUM
eurjchem-1508	113	72	(	(	PUNCT
eurjchem-1508	113	73	m	m	PROPN
eurjchem-1508	113	74	,	,	PUNCT
eurjchem-1508	113	75	5h	5h	NUM
eurjchem-1508	113	76	,	,	PUNCT
eurjchem-1508	113	77	ar‐h	ar‐h	NOUN
eurjchem-1508	113	78	)	)	PUNCT
eurjchem-1508	113	79	,	,	PUNCT
eurjchem-1508	113	80	7.81	7.81	NUM
eurjchem-1508	113	81	(	(	PUNCT
eurjchem-1508	113	82	d	d	PROPN
eurjchem-1508	113	83	,	,	PUNCT
eurjchem-1508	113	84	j	j	PROPN
eurjchem-1508	113	85	=	=	SYM
eurjchem-1508	113	86	5.6	5.6	NUM
eurjchem-1508	113	87	hz	hz	NOUN
eurjchem-1508	113	88	,	,	PUNCT
eurjchem-1508	113	89	1h	1h	NUM
eurjchem-1508	113	90	,	,	PUNCT
eurjchem-1508	113	91	ar‐h	ar‐h	NOUN
eurjchem-1508	113	92	)	)	PUNCT
eurjchem-1508	113	93	,	,	PUNCT
eurjchem-1508	113	94	7.87‐7.88	7.87‐7.88	NUM
eurjchem-1508	113	95	(	(	PUNCT
eurjchem-1508	113	96	dd	dd	PROPN
eurjchem-1508	113	97	,	,	PUNCT
eurjchem-1508	113	98	1h	1h	NUM
eurjchem-1508	113	99	,	,	PUNCT
eurjchem-1508	113	100	ar‐h	ar‐h	NOUN
eurjchem-1508	113	101	)	)	PUNCT
eurjchem-1508	113	102	,	,	PUNCT
eurjchem-1508	113	103	8.33	8.33	NUM
eurjchem-1508	113	104	(	(	PUNCT
eurjchem-1508	113	105	s	s	PROPN
eurjchem-1508	113	106	,	,	PUNCT
eurjchem-1508	113	107	1h	1h	NUM
eurjchem-1508	113	108	,	,	PUNCT
eurjchem-1508	113	109	ar‐h	ar‐h	NOUN
eurjchem-1508	113	110	)	)	PUNCT
eurjchem-1508	113	111	,	,	PUNCT
eurjchem-1508	113	112	11.47	11.47	NUM
eurjchem-1508	113	113	(	(	PUNCT
eurjchem-1508	113	114	s	s	PROPN
eurjchem-1508	113	115	,	,	PUNCT
eurjchem-1508	113	116	1h	1h	NUM
eurjchem-1508	113	117	,	,	PUNCT
eurjchem-1508	113	118	nh	nh	PROPN
eurjchem-1508	113	119	,	,	PUNCT
eurjchem-1508	113	120	d2o	d2o	PROPN
eurjchem-1508	113	121	exchangeable	exchangeable	ADJ
eurjchem-1508	113	122	)	)	PUNCT
eurjchem-1508	113	123	.	.	PUNCT
eurjchem-1508	114	1	13c	13c	NOUN
eurjchem-1508	114	2	nmr	nmr	NOUN
eurjchem-1508	114	3	(	(	PUNCT
eurjchem-1508	114	4	400	400	NUM
eurjchem-1508	114	5	mhz	mhz	NOUN
eurjchem-1508	114	6	,	,	PUNCT
eurjchem-1508	114	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	114	8	,	,	PUNCT
eurjchem-1508	114	9	δ	δ	PROPN
eurjchem-1508	114	10	,	,	PUNCT
eurjchem-1508	114	11	ppm	ppm	NOUN
eurjchem-1508	114	12	):	):	PUNCT
eurjchem-1508	114	13	14.55	14.55	NUM
eurjchem-1508	114	14	,	,	PUNCT
eurjchem-1508	114	15	61.37	61.37	NUM
eurjchem-1508	114	16	,	,	PUNCT
eurjchem-1508	114	17	92.04	92.04	NUM
eurjchem-1508	114	18	,	,	PUNCT
eurjchem-1508	114	19	94.35	94.35	NUM
eurjchem-1508	114	20	,	,	PUNCT
eurjchem-1508	114	21	111.58	111.58	NUM
eurjchem-1508	114	22	,	,	PUNCT
eurjchem-1508	114	23	114.86	114.86	NUM
eurjchem-1508	114	24	,	,	PUNCT
eurjchem-1508	114	25	116.01	116.01	NUM
eurjchem-1508	114	26	,	,	PUNCT
eurjchem-1508	114	27	116.49	116.49	NUM
eurjchem-1508	114	28	,	,	PUNCT
eurjchem-1508	114	29	120.03	120.03	NUM
eurjchem-1508	114	30	,	,	PUNCT
eurjchem-1508	114	31	129.27	129.27	NUM
eurjchem-1508	114	32	,	,	PUNCT
eurjchem-1508	114	33	130.82	130.82	NUM
eurjchem-1508	114	34	,	,	PUNCT
eurjchem-1508	114	35	131.11	131.11	NUM
eurjchem-1508	114	36	,	,	PUNCT
eurjchem-1508	114	37	134.80	134.80	NUM
eurjchem-1508	114	38	,	,	PUNCT
eurjchem-1508	114	39	135.18	135.18	NUM
eurjchem-1508	114	40	,	,	PUNCT
eurjchem-1508	114	41	136.62	136.62	NUM
eurjchem-1508	114	42	,	,	PUNCT
eurjchem-1508	114	43	139.91	139.91	NUM
eurjchem-1508	114	44	,	,	PUNCT
eurjchem-1508	114	45	142.75	142.75	NUM
eurjchem-1508	114	46	,	,	PUNCT
eurjchem-1508	114	47	145.97	145.97	NUM
eurjchem-1508	114	48	,	,	PUNCT
eurjchem-1508	114	49	148.74	148.74	NUM
eurjchem-1508	114	50	,	,	PUNCT
eurjchem-1508	114	51	154.61	154.61	NUM
eurjchem-1508	114	52	,	,	PUNCT
eurjchem-1508	114	53	167.40	167.40	NUM
eurjchem-1508	114	54	.	.	PUNCT
eurjchem-1508	115	1	ms	ms	NOUN
eurjchem-1508	115	2	(	(	PUNCT
eurjchem-1508	115	3	ei	ei	PROPN
eurjchem-1508	115	4	,	,	PUNCT
eurjchem-1508	115	5	m	m	PROPN
eurjchem-1508	115	6	/	/	SYM
eurjchem-1508	115	7	z	z	PROPN
eurjchem-1508	115	8	(	(	PUNCT
eurjchem-1508	115	9	%	%	NOUN
eurjchem-1508	115	10	)	)	PUNCT
eurjchem-1508	115	11	):	):	PUNCT
eurjchem-1508	115	12	443	443	NUM
eurjchem-1508	115	13	(	(	PUNCT
eurjchem-1508	115	14	m+	m+	NUM
eurjchem-1508	115	15	,	,	PUNCT
eurjchem-1508	115	16	100	100	NUM
eurjchem-1508	115	17	)	)	PUNCT
eurjchem-1508	115	18	.	.	PUNCT
eurjchem-1508	116	1	anal	anal	PROPN
eurjchem-1508	116	2	.	.	PUNCT
eurjchem-1508	116	3	calcd	calcd	NOUN
eurjchem-1508	116	4	.	.	PUNCT
eurjchem-1508	117	1	for	for	ADP
eurjchem-1508	117	2	c24h18cln3o2	c24h18cln3o2	NOUN
eurjchem-1508	117	3	:	:	PUNCT
eurjchem-1508	117	4	c	c	X
eurjchem-1508	117	5	,	,	PUNCT
eurjchem-1508	117	6	64.94	64.94	NUM
eurjchem-1508	117	7	;	;	PUNCT
eurjchem-1508	117	8	h	h	NOUN
eurjchem-1508	117	9	,	,	PUNCT
eurjchem-1508	117	10	4.09	4.09	NUM
eurjchem-1508	117	11	;	;	PUNCT
eurjchem-1508	117	12	n	n	CCONJ
eurjchem-1508	117	13	,	,	PUNCT
eurjchem-1508	117	14	15.78	15.78	NUM
eurjchem-1508	117	15	.	.	PUNCT
eurjchem-1508	117	16	found	find	VERB
eurjchem-1508	117	17	:	:	PUNCT
eurjchem-1508	118	1	c	c	X
eurjchem-1508	118	2	,	,	PUNCT
eurjchem-1508	118	3	64.96	64.96	NUM
eurjchem-1508	118	4	;	;	PUNCT
eurjchem-1508	118	5	h	h	NOUN
eurjchem-1508	118	6	,	,	PUNCT
eurjchem-1508	118	7	4.12	4.12	NUM
eurjchem-1508	118	8	;	;	PUNCT
eurjchem-1508	118	9	n	n	CCONJ
eurjchem-1508	118	10	,	,	PUNCT
eurjchem-1508	118	11	15.88	15.88	NUM
eurjchem-1508	118	12	%	%	NOUN
eurjchem-1508	118	13	.	.	PUNCT
eurjchem-1508	119	1	ethyl	ethyl	PROPN
eurjchem-1508	119	2	2‐(2‐((5‐amino‐4‐nitro‐4,6‐dicyano[1,1‐biphenyl]‐3‐	2‐(2‐((5‐amino‐4‐nitro‐4,6‐dicyano[1,1‐biphenyl]‐3‐	NUM
eurjchem-1508	119	3	yl)methylene)hydrazinyl)benzoate	yl)methylene)hydrazinyl)benzoate	X
eurjchem-1508	119	4	(	(	PUNCT
eurjchem-1508	119	5	4c	4c	NOUN
eurjchem-1508	119	6	):	):	PUNCT
eurjchem-1508	119	7	recrystallized	recrystallize	VERB
eurjchem-1508	119	8	from	from	ADP
eurjchem-1508	119	9	acetic	acetic	ADJ
eurjchem-1508	119	10	acid	acid	NOUN
eurjchem-1508	119	11	.	.	PUNCT
eurjchem-1508	120	1	color	color	NOUN
eurjchem-1508	120	2	:	:	PUNCT
eurjchem-1508	120	3	brown	brown	ADJ
eurjchem-1508	120	4	.	.	PUNCT
eurjchem-1508	121	1	m.p	m.p	PROPN
eurjchem-1508	121	2	.	.	PROPN
eurjchem-1508	121	3	:	:	PUNCT
eurjchem-1508	122	1	280‐281	280‐281	NUM
eurjchem-1508	122	2	°	°	SYM
eurjchem-1508	122	3	c	c	NOUN
eurjchem-1508	122	4	.	.	PUNCT
eurjchem-1508	122	5	yield	yield	NOUN
eurjchem-1508	122	6	:	:	PUNCT
eurjchem-1508	122	7	75	75	NUM
eurjchem-1508	122	8	%	%	NOUN
eurjchem-1508	122	9	.	.	PUNCT
eurjchem-1508	123	1	1h	1h	NUM
eurjchem-1508	123	2	nmr	nmr	NOUN
eurjchem-1508	123	3	(	(	PUNCT
eurjchem-1508	123	4	400	400	NUM
eurjchem-1508	123	5	mhz	mhz	NOUN
eurjchem-1508	123	6	,	,	PUNCT
eurjchem-1508	123	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	123	8	,	,	PUNCT
eurjchem-1508	123	9	δ	δ	PROPN
eurjchem-1508	123	10	,	,	PUNCT
eurjchem-1508	123	11	ppm	ppm	NUM
eurjchem-1508	123	12	):	):	PUNCT
eurjchem-1508	123	13	1.34	1.34	NUM
eurjchem-1508	123	14	(	(	PUNCT
eurjchem-1508	123	15	t	t	PROPN
eurjchem-1508	123	16	,	,	PUNCT
eurjchem-1508	123	17	j	j	PROPN
eurjchem-1508	123	18	=	=	SYM
eurjchem-1508	123	19	4.8	4.8	NUM
eurjchem-1508	123	20	hz	hz	NOUN
eurjchem-1508	123	21	,	,	PUNCT
eurjchem-1508	123	22	3h	3h	NUM
eurjchem-1508	123	23	,	,	PUNCT
eurjchem-1508	123	24	ch3	ch3	PROPN
eurjchem-1508	123	25	)	)	PUNCT
eurjchem-1508	123	26	,	,	PUNCT
eurjchem-1508	123	27	4.31‐4.35	4.31‐4.35	NOUN
eurjchem-1508	123	28	(	(	PUNCT
eurjchem-1508	123	29	q	q	NOUN
eurjchem-1508	123	30	,	,	PUNCT
eurjchem-1508	123	31	j	j	PROPN
eurjchem-1508	123	32	=	=	SYM
eurjchem-1508	123	33	4.8	4.8	NUM
eurjchem-1508	123	34	hz	hz	VERB
eurjchem-1508	123	35	,	,	PUNCT
eurjchem-1508	123	36	2h	2h	NUM
eurjchem-1508	123	37	,	,	PUNCT
eurjchem-1508	123	38	ch2	ch2	PROPN
eurjchem-1508	123	39	)	)	PUNCT
eurjchem-1508	123	40	,	,	PUNCT
eurjchem-1508	123	41	6.82	6.82	NUM
eurjchem-1508	123	42	(	(	PUNCT
eurjchem-1508	123	43	s	s	PROPN
eurjchem-1508	123	44	,	,	PUNCT
eurjchem-1508	123	45	2h	2h	NUM
eurjchem-1508	123	46	,	,	PUNCT
eurjchem-1508	123	47	nh2	nh2	PROPN
eurjchem-1508	123	48	,	,	PUNCT
eurjchem-1508	123	49	d2o	d2o	NOUN
eurjchem-1508	123	50	exchangeable	exchangeable	ADJ
eurjchem-1508	123	51	)	)	PUNCT
eurjchem-1508	123	52	,	,	PUNCT
eurjchem-1508	123	53	6.93	6.93	NUM
eurjchem-1508	123	54	(	(	PUNCT
eurjchem-1508	123	55	t	t	PROPN
eurjchem-1508	123	56	,	,	PUNCT
eurjchem-1508	123	57	j	j	PROPN
eurjchem-1508	124	1	=	=	SYM
eurjchem-1508	124	2	4.8	4.8	NUM
eurjchem-1508	124	3	hz	hz	NOUN
eurjchem-1508	124	4	,	,	PUNCT
eurjchem-1508	124	5	1h	1h	NUM
eurjchem-1508	124	6	,	,	PUNCT
eurjchem-1508	124	7	ar‐h	ar‐h	NOUN
eurjchem-1508	124	8	)	)	PUNCT
eurjchem-1508	124	9	,	,	PUNCT
eurjchem-1508	124	10	7.19	7.19	NUM
eurjchem-1508	124	11	(	(	PUNCT
eurjchem-1508	124	12	s	s	PROPN
eurjchem-1508	124	13	,	,	PUNCT
eurjchem-1508	124	14	1h	1h	NUM
eurjchem-1508	124	15	,	,	PUNCT
eurjchem-1508	124	16	hydrazinyl‐ch	hydrazinyl‐ch	NOUN
eurjchem-1508	124	17	)	)	PUNCT
eurjchem-1508	124	18	,	,	PUNCT
eurjchem-1508	124	19	7.52	7.52	NUM
eurjchem-1508	124	20	(	(	PUNCT
eurjchem-1508	124	21	t	t	PROPN
eurjchem-1508	124	22	,	,	PUNCT
eurjchem-1508	124	23	j	j	PROPN
eurjchem-1508	125	1	=	=	SYM
eurjchem-1508	125	2	4.8	4.8	NUM
eurjchem-1508	125	3	hz	hz	NOUN
eurjchem-1508	125	4	,	,	PUNCT
eurjchem-1508	125	5	1h	1h	NUM
eurjchem-1508	125	6	,	,	PUNCT
eurjchem-1508	125	7	ar‐h	ar‐h	NOUN
eurjchem-1508	125	8	)	)	PUNCT
eurjchem-1508	125	9	,	,	PUNCT
eurjchem-1508	125	10	7.79‐7.96	7.79‐7.96	NUM
eurjchem-1508	125	11	(	(	PUNCT
eurjchem-1508	125	12	m	m	PROPN
eurjchem-1508	125	13	,	,	PUNCT
eurjchem-1508	125	14	5h	5h	NUM
eurjchem-1508	125	15	,	,	PUNCT
eurjchem-1508	125	16	ar‐h	ar‐h	NOUN
eurjchem-1508	125	17	)	)	PUNCT
eurjchem-1508	125	18	,	,	PUNCT
eurjchem-1508	125	19	8.30	8.30	NUM
eurjchem-1508	125	20	(	(	PUNCT
eurjchem-1508	125	21	s	s	PROPN
eurjchem-1508	125	22	,	,	PUNCT
eurjchem-1508	125	23	1h	1h	NUM
eurjchem-1508	125	24	,	,	PUNCT
eurjchem-1508	125	25	ar‐h	ar‐h	NOUN
eurjchem-1508	125	26	)	)	PUNCT
eurjchem-1508	125	27	,	,	PUNCT
eurjchem-1508	125	28	8.39	8.39	NUM
eurjchem-1508	125	29	(	(	PUNCT
eurjchem-1508	125	30	s	s	PROPN
eurjchem-1508	125	31	,	,	PUNCT
eurjchem-1508	125	32	1h	1h	NUM
eurjchem-1508	125	33	,	,	PUNCT
eurjchem-1508	125	34	ar‐h	ar‐h	NOUN
eurjchem-1508	125	35	)	)	PUNCT
eurjchem-1508	125	36	,	,	PUNCT
eurjchem-1508	125	37	11.47	11.47	NUM
eurjchem-1508	125	38	(	(	PUNCT
eurjchem-1508	125	39	s	s	PROPN
eurjchem-1508	125	40	,	,	PUNCT
eurjchem-1508	125	41	1h	1h	NUM
eurjchem-1508	125	42	,	,	PUNCT
eurjchem-1508	125	43	nh	nh	PROPN
eurjchem-1508	125	44	,	,	PUNCT
eurjchem-1508	125	45	d2o	d2o	PROPN
eurjchem-1508	125	46	exchangeable	exchangeable	ADJ
eurjchem-1508	125	47	)	)	PUNCT
eurjchem-1508	125	48	.	.	PUNCT
eurjchem-1508	126	1	ms	ms	NOUN
eurjchem-1508	126	2	(	(	PUNCT
eurjchem-1508	126	3	ei	ei	PROPN
eurjchem-1508	126	4	,	,	PUNCT
eurjchem-1508	126	5	m	m	PROPN
eurjchem-1508	126	6	/	/	SYM
eurjchem-1508	126	7	z	z	PROPN
eurjchem-1508	126	8	(	(	PUNCT
eurjchem-1508	126	9	%	%	NOUN
eurjchem-1508	126	10	)	)	PUNCT
eurjchem-1508	126	11	):	):	PUNCT
eurjchem-1508	126	12	456	456	NUM
eurjchem-1508	126	13	(	(	PUNCT
eurjchem-1508	126	14	m+2	m+2	NOUN
eurjchem-1508	126	15	,	,	PUNCT
eurjchem-1508	126	16	17.2	17.2	NUM
eurjchem-1508	126	17	)	)	PUNCT
eurjchem-1508	126	18	,	,	PUNCT
eurjchem-1508	126	19	454	454	NUM
eurjchem-1508	126	20	(	(	PUNCT
eurjchem-1508	126	21	m+	m+	NUM
eurjchem-1508	126	22	)	)	PUNCT
eurjchem-1508	126	23	.	.	PUNCT
eurjchem-1508	127	1	anal	anal	PROPN
eurjchem-1508	127	2	.	.	PUNCT
eurjchem-1508	127	3	calcd	calcd	NOUN
eurjchem-1508	127	4	.	.	PUNCT
eurjchem-1508	128	1	for	for	ADP
eurjchem-1508	128	2	c24h18n6o4	c24h18n6o4	PROPN
eurjchem-1508	128	3	:	:	PUNCT
eurjchem-1508	128	4	c	c	X
eurjchem-1508	128	5	,	,	PUNCT
eurjchem-1508	128	6	63.43	63.43	NUM
eurjchem-1508	128	7	;	;	PUNCT
eurjchem-1508	128	8	h	h	NOUN
eurjchem-1508	128	9	,	,	PUNCT
eurjchem-1508	128	10	3.99	3.99	NUM
eurjchem-1508	128	11	;	;	PUNCT
eurjchem-1508	128	12	n	n	CCONJ
eurjchem-1508	128	13	,	,	PUNCT
eurjchem-1508	128	14	18.49	18.49	NUM
eurjchem-1508	128	15	.	.	PUNCT
eurjchem-1508	128	16	found	find	VERB
eurjchem-1508	128	17	:	:	PUNCT
eurjchem-1508	129	1	c	c	X
eurjchem-1508	129	2	,	,	PUNCT
eurjchem-1508	129	3	63.44	63.44	NUM
eurjchem-1508	129	4	;	;	PUNCT
eurjchem-1508	129	5	h	h	NOUN
eurjchem-1508	129	6	,	,	PUNCT
eurjchem-1508	129	7	3.88	3.88	NUM
eurjchem-1508	129	8	;	;	PUNCT
eurjchem-1508	129	9	n	n	CCONJ
eurjchem-1508	129	10	,	,	PUNCT
eurjchem-1508	129	11	18.55	18.55	NUM
eurjchem-1508	129	12	%	%	NOUN
eurjchem-1508	129	13	.	.	PUNCT
eurjchem-1508	130	1	2‐acetyl‐6‐amino‐3‐phenyl‐3h‐pyridazino[1,6‐a]quinazoli	2‐acetyl‐6‐amino‐3‐phenyl‐3h‐pyridazino[1,6‐a]quinazoli	NUM
eurjchem-1508	130	2	ne‐4‐carbonitrile	ne‐4‐carbonitrile	PROPN
eurjchem-1508	130	3	(	(	PUNCT
eurjchem-1508	130	4	22	22	NUM
eurjchem-1508	130	5	):	):	PUNCT
eurjchem-1508	130	6	recrystallized	recrystallize	VERB
eurjchem-1508	130	7	from	from	ADP
eurjchem-1508	130	8	etoh	etoh	NOUN
eurjchem-1508	130	9	.	.	PUNCT
eurjchem-1508	131	1	color	color	NOUN
eurjchem-1508	131	2	:	:	PUNCT
eurjchem-1508	131	3	green	green	ADJ
eurjchem-1508	131	4	.	.	PUNCT
eurjchem-1508	132	1	m.p	m.p	PROPN
eurjchem-1508	132	2	.	.	PROPN
eurjchem-1508	132	3	:	:	PUNCT
eurjchem-1508	133	1	285‐286	285‐286	NUM
eurjchem-1508	133	2	°	°	PROPN
eurjchem-1508	133	3	c	c	X
eurjchem-1508	133	4	.	.	PUNCT
eurjchem-1508	133	5	yield	yield	NOUN
eurjchem-1508	133	6	:	:	PUNCT
eurjchem-1508	133	7	83	83	NUM
eurjchem-1508	133	8	%	%	NOUN
eurjchem-1508	133	9	.	.	PUNCT
eurjchem-1508	134	1	1h	1h	NUM
eurjchem-1508	134	2	nmr	nmr	NOUN
eurjchem-1508	134	3	(	(	PUNCT
eurjchem-1508	134	4	400	400	NUM
eurjchem-1508	134	5	mhz	mhz	NOUN
eurjchem-1508	134	6	,	,	PUNCT
eurjchem-1508	134	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	134	8	,	,	PUNCT
eurjchem-1508	134	9	δ	δ	PROPN
eurjchem-1508	134	10	,	,	PUNCT
eurjchem-1508	134	11	ppm	ppm	NOUN
eurjchem-1508	134	12	):	):	PUNCT
eurjchem-1508	134	13	2.48	2.48	NUM
eurjchem-1508	134	14	(	(	PUNCT
eurjchem-1508	134	15	s	s	PROPN
eurjchem-1508	134	16	,	,	PUNCT
eurjchem-1508	134	17	3h	3h	NUM
eurjchem-1508	134	18	,	,	PUNCT
eurjchem-1508	134	19	ch3	ch3	PROPN
eurjchem-1508	134	20	)	)	PUNCT
eurjchem-1508	134	21	,	,	PUNCT
eurjchem-1508	134	22	8.44	8.44	NUM
eurjchem-1508	134	23	(	(	PUNCT
eurjchem-1508	134	24	s	s	PROPN
eurjchem-1508	134	25	,	,	PUNCT
eurjchem-1508	134	26	1h	1h	NUM
eurjchem-1508	134	27	,	,	PUNCT
eurjchem-1508	134	28	pyridazin‐h	pyridazin‐h	NOUN
eurjchem-1508	134	29	)	)	PUNCT
eurjchem-1508	134	30	,	,	PUNCT
eurjchem-1508	134	31	7.15‐8.05	7.15‐8.05	NUM
eurjchem-1508	134	32	(	(	PUNCT
eurjchem-1508	134	33	m	m	PROPN
eurjchem-1508	134	34	,	,	PUNCT
eurjchem-1508	134	35	9h	9h	NUM
eurjchem-1508	134	36	,	,	PUNCT
eurjchem-1508	134	37	ar‐h	ar‐h	NOUN
eurjchem-1508	134	38	)	)	PUNCT
eurjchem-1508	134	39	,	,	PUNCT
eurjchem-1508	134	40	8.16	8.16	NUM
eurjchem-1508	134	41	(	(	PUNCT
eurjchem-1508	134	42	s	s	PROPN
eurjchem-1508	134	43	,	,	PUNCT
eurjchem-1508	134	44	2h	2h	NUM
eurjchem-1508	134	45	,	,	PUNCT
eurjchem-1508	134	46	nh2	nh2	PROPN
eurjchem-1508	134	47	,	,	PUNCT
eurjchem-1508	134	48	d2o	d2o	NOUN
eurjchem-1508	134	49	exchangeable	exchangeable	ADJ
eurjchem-1508	134	50	)	)	PUNCT
eurjchem-1508	134	51	.	.	PUNCT
eurjchem-1508	135	1	13c	13c	NOUN
eurjchem-1508	135	2	nmr	nmr	NOUN
eurjchem-1508	135	3	(	(	PUNCT
eurjchem-1508	135	4	100	100	NUM
eurjchem-1508	135	5	mhz	mhz	NOUN
eurjchem-1508	135	6	,	,	PUNCT
eurjchem-1508	135	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1508	135	8	,	,	PUNCT
eurjchem-1508	135	9	δ	δ	PROPN
eurjchem-1508	135	10	,	,	PUNCT
eurjchem-1508	135	11	ppm	ppm	NUM
eurjchem-1508	135	12	):	):	PUNCT
eurjchem-1508	135	13	25.17	25.17	NUM
eurjchem-1508	135	14	,	,	PUNCT
eurjchem-1508	135	15	37.50	37.50	NUM
eurjchem-1508	135	16	,	,	PUNCT
eurjchem-1508	135	17	67.82	67.82	NUM
eurjchem-1508	135	18	,	,	PUNCT
eurjchem-1508	135	19	111.99	111.99	NUM
eurjchem-1508	135	20	,	,	PUNCT
eurjchem-1508	135	21	114.44	114.44	NUM
eurjchem-1508	135	22	,	,	PUNCT
eurjchem-1508	135	23	120.58	120.58	NUM
eurjchem-1508	135	24	,	,	PUNCT
eurjchem-1508	135	25	124.09	124.09	NUM
eurjchem-1508	135	26	,	,	PUNCT
eurjchem-1508	135	27	124.68	124.68	NUM
eurjchem-1508	135	28	,	,	PUNCT
eurjchem-1508	135	29	127.13	127.13	NUM
eurjchem-1508	135	30	,	,	PUNCT
eurjchem-1508	135	31	127.35	127.35	NUM
eurjchem-1508	135	32	,	,	PUNCT
eurjchem-1508	135	33	128.92	128.92	NUM
eurjchem-1508	135	34	,	,	PUNCT
eurjchem-1508	135	35	134.42	134.42	NUM
eurjchem-1508	135	36	,	,	PUNCT
eurjchem-1508	135	37	139.91	139.91	NUM
eurjchem-1508	135	38	,	,	PUNCT
eurjchem-1508	135	39	142.30	142.30	NUM
eurjchem-1508	135	40	,	,	PUNCT
eurjchem-1508	135	41	145.06	145.06	NUM
eurjchem-1508	135	42	,	,	PUNCT
eurjchem-1508	135	43	147.26	147.26	NUM
eurjchem-1508	135	44	,	,	PUNCT
eurjchem-1508	135	45	156.22	156.22	NUM
eurjchem-1508	135	46	.	.	PUNCT
eurjchem-1508	136	1	ms	ms	NOUN
eurjchem-1508	136	2	(	(	PUNCT
eurjchem-1508	136	3	ei	ei	PROPN
eurjchem-1508	136	4	,	,	PUNCT
eurjchem-1508	136	5	m	m	PROPN
eurjchem-1508	136	6	/	/	SYM
eurjchem-1508	136	7	z	z	PROPN
eurjchem-1508	136	8	(	(	PUNCT
eurjchem-1508	136	9	%	%	NOUN
eurjchem-1508	136	10	)	)	PUNCT
eurjchem-1508	136	11	):	):	PUNCT
eurjchem-1508	136	12	341	341	NUM
eurjchem-1508	136	13	(	(	PUNCT
eurjchem-1508	136	14	m+	m+	NUM
eurjchem-1508	136	15	,	,	PUNCT
eurjchem-1508	136	16	45	45	NUM
eurjchem-1508	136	17	)	)	PUNCT
eurjchem-1508	136	18	.	.	PUNCT
eurjchem-1508	137	1	anal	anal	PROPN
eurjchem-1508	137	2	.	.	PUNCT
eurjchem-1508	137	3	calcd	calcd	NOUN
eurjchem-1508	137	4	.	.	PUNCT
eurjchem-1508	138	1	for	for	ADP
eurjchem-1508	138	2	c20h15n5o	c20h15n5o	PROPN
eurjchem-1508	138	3	:	:	PUNCT
eurjchem-1508	138	4	c	c	X
eurjchem-1508	138	5	,	,	PUNCT
eurjchem-1508	138	6	70.37	70.37	NUM
eurjchem-1508	138	7	;	;	PUNCT
eurjchem-1508	138	8	h	h	NOUN
eurjchem-1508	138	9	,	,	PUNCT
eurjchem-1508	138	10	4.43	4.43	NUM
eurjchem-1508	138	11	;	;	PUNCT
eurjchem-1508	138	12	n	n	CCONJ
eurjchem-1508	138	13	,	,	PUNCT
eurjchem-1508	138	14	20.52	20.52	NUM
eurjchem-1508	138	15	.	.	PUNCT
eurjchem-1508	138	16	found	find	VERB
eurjchem-1508	138	17	:	:	PUNCT
eurjchem-1508	139	1	c	c	X
eurjchem-1508	139	2	,	,	PUNCT
eurjchem-1508	139	3	70.25	70.25	NUM
eurjchem-1508	139	4	;	;	PUNCT
eurjchem-1508	139	5	h	h	NOUN
eurjchem-1508	139	6	,	,	PUNCT
eurjchem-1508	139	7	4.32	4.32	NUM
eurjchem-1508	139	8	;	;	PUNCT
eurjchem-1508	139	9	n	n	CCONJ
eurjchem-1508	139	10	,	,	PUNCT
eurjchem-1508	139	11	20.44	20.44	NUM
eurjchem-1508	139	12	%	%	NOUN
eurjchem-1508	139	13	.	.	PUNCT
eurjchem-1508	140	1	3	3	X
eurjchem-1508	140	2	.	.	NOUN
eurjchem-1508	140	3	results	result	NOUN
eurjchem-1508	140	4	and	and	CCONJ
eurjchem-1508	140	5	discussion	discussion	NOUN
eurjchem-1508	140	6	in	in	ADP
eurjchem-1508	140	7	conjunction	conjunction	NOUN
eurjchem-1508	140	8	to	to	ADP
eurjchem-1508	140	9	our	our	PRON
eurjchem-1508	140	10	interest	interest	NOUN
eurjchem-1508	140	11	in	in	ADP
eurjchem-1508	140	12	pyridazines	pyridazine	NOUN
eurjchem-1508	140	13	and	and	CCONJ
eurjchem-1508	140	14	condensed	condense	VERB
eurjchem-1508	140	15	pyridazines	pyridazine	NOUN
eurjchem-1508	140	16	we	we	PRON
eurjchem-1508	140	17	report	report	VERB
eurjchem-1508	140	18	here	here	ADV
eurjchem-1508	140	19	on	on	ADP
eurjchem-1508	140	20	the	the	DET
eurjchem-1508	140	21	reaction	reaction	NOUN
eurjchem-1508	140	22	of	of	ADP
eurjchem-1508	140	23	arylhydrazonal	arylhydrazonal	ADJ
eurjchem-1508	140	24	derivatives	derivative	NOUN
eurjchem-1508	140	25	(	(	PUNCT
eurjchem-1508	140	26	1h‐k	1h‐k	NOUN
eurjchem-1508	140	27	)	)	PUNCT
eurjchem-1508	140	28	,	,	PUNCT
eurjchem-1508	140	29	malononitrile	malononitrile	NOUN
eurjchem-1508	140	30	(	(	PUNCT
eurjchem-1508	140	31	6	6	NUM
eurjchem-1508	140	32	)	)	PUNCT
eurjchem-1508	140	33	and	and	CCONJ
eurjchem-1508	140	34	aromatic	aromatic	ADJ
eurjchem-1508	140	35	aldehyde	aldehyde	NOUN
eurjchem-1508	140	36	derivatives	derivative	NOUN
eurjchem-1508	140	37	(	(	PUNCT
eurjchem-1508	140	38	7a‐e	7a‐e	PROPN
eurjchem-1508	140	39	)	)	PUNCT
eurjchem-1508	140	40	.	.	PUNCT
eurjchem-1508	141	1	we	we	PRON
eurjchem-1508	141	2	have	have	AUX
eurjchem-1508	141	3	found	find	VERB
eurjchem-1508	141	4	that	that	SCONJ
eurjchem-1508	141	5	arylhydrazonal	arylhydrazonal	ADJ
eurjchem-1508	141	6	derivative	derivative	ADJ
eurjchem-1508	141	7	(	(	PUNCT
eurjchem-1508	141	8	1h	1h	NUM
eurjchem-1508	141	9	)	)	PUNCT
eurjchem-1508	141	10	reacts	react	NOUN
eurjchem-1508	141	11	with	with	ADP
eurjchem-1508	141	12	malononitrile	malononitrile	NOUN
eurjchem-1508	141	13	(	(	PUNCT
eurjchem-1508	141	14	6	6	NUM
eurjchem-1508	141	15	)	)	PUNCT
eurjchem-1508	141	16	and	and	CCONJ
eurjchem-1508	141	17	aromatic	aromatic	ADJ
eurjchem-1508	141	18	aldehyde	aldehyde	NOUN
eurjchem-1508	141	19	(	(	PUNCT
eurjchem-1508	141	20	7a‐e	7a‐e	PROPN
eurjchem-1508	141	21	)	)	PUNCT
eurjchem-1508	141	22	to	to	PART
eurjchem-1508	141	23	yield	yield	VERB
eurjchem-1508	141	24	the	the	DET
eurjchem-1508	141	25	pyridazino‐	pyridazino‐	NOUN
eurjchem-1508	141	26	naphthyridine	naphthyridine	NOUN
eurjchem-1508	141	27	derivatives	derivative	NOUN
eurjchem-1508	141	28	(	(	PUNCT
eurjchem-1508	141	29	8a‐e	8a‐e	NOUN
eurjchem-1508	141	30	)	)	PUNCT
eurjchem-1508	141	31	(	(	PUNCT
eurjchem-1508	141	32	scheme	scheme	NOUN
eurjchem-1508	141	33	2	2	NUM
eurjchem-1508	141	34	)	)	PUNCT
eurjchem-1508	141	35	.	.	PUNCT
eurjchem-1508	142	1	two	two	NUM
eurjchem-1508	142	2	routs	rout	NOUN
eurjchem-1508	142	3	can	can	AUX
eurjchem-1508	142	4	lead	lead	VERB
eurjchem-1508	142	5	to	to	ADP
eurjchem-1508	142	6	the	the	DET
eurjchem-1508	142	7	formed	form	VERB
eurjchem-1508	142	8	end	end	NOUN
eurjchem-1508	142	9	product	product	NOUN
eurjchem-1508	142	10	.	.	PUNCT
eurjchem-1508	143	1	thus	thus	ADV
eurjchem-1508	143	2	,	,	PUNCT
eurjchem-1508	143	3	initial	initial	ADJ
eurjchem-1508	143	4	condensation	condensation	NOUN
eurjchem-1508	143	5	of	of	ADP
eurjchem-1508	143	6	compound	compound	NOUN
eurjchem-1508	143	7	1h	1h	NUM
eurjchem-1508	143	8	with	with	ADP
eurjchem-1508	143	9	malononitrile	malononitrile	NOUN
eurjchem-1508	143	10	(	(	PUNCT
eurjchem-1508	143	11	6	6	NUM
eurjchem-1508	143	12	)	)	PUNCT
eurjchem-1508	143	13	can	can	AUX
eurjchem-1508	143	14	afford	afford	VERB
eurjchem-1508	143	15	compound	compound	VERB
eurjchem-1508	143	16	14	14	NUM
eurjchem-1508	143	17	that	that	PRON
eurjchem-1508	143	18	then	then	ADV
eurjchem-1508	143	19	cyclized	cyclize	VERB
eurjchem-1508	143	20	to	to	PART
eurjchem-1508	143	21	compound	compound	VERB
eurjchem-1508	143	22	15	15	NUM
eurjchem-1508	143	23	which	which	PRON
eurjchem-1508	143	24	reacted	react	VERB
eurjchem-1508	143	25	further	far	ADV
eurjchem-1508	143	26	with	with	ADP
eurjchem-1508	143	27	aromatic	aromatic	ADJ
eurjchem-1508	143	28	aldehydes	aldehyde	NOUN
eurjchem-1508	143	29	to	to	PART
eurjchem-1508	143	30	yield	yield	VERB
eurjchem-1508	143	31	compound	compound	NOUN
eurjchem-1508	143	32	16	16	NUM
eurjchem-1508	143	33	that	that	PRON
eurjchem-1508	143	34	added	add	VERB
eurjchem-1508	143	35	further	further	ADJ
eurjchem-1508	143	36	malononitrile	malononitrile	NOUN
eurjchem-1508	143	37	molecule	molecule	NOUN
eurjchem-1508	143	38	and	and	CCONJ
eurjchem-1508	143	39	cyclized	cyclize	VERB
eurjchem-1508	143	40	then	then	ADV
eurjchem-1508	143	41	aromatized	aromatize	VERB
eurjchem-1508	143	42	to	to	PART
eurjchem-1508	143	43	yield	yield	VERB
eurjchem-1508	143	44	compound	compound	NOUN
eurjchem-1508	143	45	8	8	NUM
eurjchem-1508	143	46	(	(	PUNCT
eurjchem-1508	143	47	pathway	pathway	NOUN
eurjchem-1508	143	48	a	a	NOUN
eurjchem-1508	143	49	)	)	PUNCT
eurjchem-1508	143	50	(	(	PUNCT
eurjchem-1508	143	51	scheme	scheme	NOUN
eurjchem-1508	143	52	3	3	NUM
eurjchem-1508	143	53	)	)	PUNCT
eurjchem-1508	143	54	.	.	PUNCT
eurjchem-1508	144	1	alternately	alternately	ADV
eurjchem-1508	144	2	initial	initial	ADJ
eurjchem-1508	144	3	formation	formation	NOUN
eurjchem-1508	144	4	of	of	ADP
eurjchem-1508	144	5	dimer	dimer	NOUN
eurjchem-1508	144	6	9	9	NUM
eurjchem-1508	144	7	that	that	DET
eurjchem-1508	144	8	condense	condense	NOUN
eurjchem-1508	144	9	with	with	ADP
eurjchem-1508	144	10	compound	compound	NOUN
eurjchem-1508	144	11	1h	1h	NUM
eurjchem-1508	144	12	yielding	yield	VERB
eurjchem-1508	144	13	compound	compound	NOUN
eurjchem-1508	144	14	10	10	NUM
eurjchem-1508	144	15	that	that	PRON
eurjchem-1508	144	16	afford	afford	AUX
eurjchem-1508	144	17	compound	compound	VERB
eurjchem-1508	144	18	11	11	NUM
eurjchem-1508	144	19	then	then	ADV
eurjchem-1508	144	20	compound	compound	VERB
eurjchem-1508	144	21	12	12	NUM
eurjchem-1508	144	22	and	and	CCONJ
eurjchem-1508	144	23	finally	finally	ADV
eurjchem-1508	144	24	compound	compound	VERB
eurjchem-1508	144	25	8	8	NUM
eurjchem-1508	144	26	(	(	PUNCT
eurjchem-1508	144	27	pathway	pathway	NOUN
eurjchem-1508	144	28	b	b	NOUN
eurjchem-1508	144	29	,	,	PUNCT
eurjchem-1508	144	30	scheme	scheme	NOUN
eurjchem-1508	144	31	3	3	NUM
eurjchem-1508	144	32	)	)	PUNCT
eurjchem-1508	144	33	can	can	AUX
eurjchem-1508	144	34	also	also	ADV
eurjchem-1508	144	35	occur	occur	VERB
eurjchem-1508	144	36	.	.	PUNCT
eurjchem-1508	145	1	under	under	ADP
eurjchem-1508	145	2	the	the	DET
eurjchem-1508	145	3	same	same	ADJ
eurjchem-1508	145	4	reaction	reaction	NOUN
eurjchem-1508	145	5	condition	condition	NOUN
eurjchem-1508	145	6	,	,	PUNCT
eurjchem-1508	145	7	compound	compound	NOUN
eurjchem-1508	145	8	1j	1j	NUM
eurjchem-1508	145	9	reacted	react	VERB
eurjchem-1508	145	10	with	with	ADP
eurjchem-1508	145	11	malononitrile	malononitrile	NOUN
eurjchem-1508	145	12	(	(	PUNCT
eurjchem-1508	145	13	6	6	NUM
eurjchem-1508	145	14	)	)	PUNCT
eurjchem-1508	145	15	and	and	CCONJ
eurjchem-1508	145	16	aromatic	aromatic	ADJ
eurjchem-1508	145	17	aldehyde	aldehyde	NOUN
eurjchem-1508	145	18	7	7	NUM
eurjchem-1508	145	19	to	to	PART
eurjchem-1508	145	20	afford	afford	VERB
eurjchem-1508	145	21	the	the	DET
eurjchem-1508	145	22	benzene	benzene	NOUN
eurjchem-1508	145	23	derivative	derivative	ADJ
eurjchem-1508	145	24	4	4	NUM
eurjchem-1508	145	25	via	via	ADP
eurjchem-1508	145	26	sequence	sequence	NOUN
eurjchem-1508	145	27	shown	show	VERB
eurjchem-1508	145	28	in	in	ADP
eurjchem-1508	145	29	scheme	scheme	NOUN
eurjchem-1508	145	30	4	4	NUM
eurjchem-1508	146	1	[	[	X
eurjchem-1508	146	2	16	16	NUM
eurjchem-1508	146	3	]	]	PUNCT
eurjchem-1508	146	4	.	.	PUNCT
eurjchem-1508	147	1	in	in	ADP
eurjchem-1508	147	2	contrast	contrast	NOUN
eurjchem-1508	147	3	the	the	DET
eurjchem-1508	147	4	arylhydrazonal	arylhydrazonal	ADJ
eurjchem-1508	147	5	1k	1k	NUM
eurjchem-1508	147	6	reacted	react	VERB
eurjchem-1508	147	7	with	with	ADP
eurjchem-1508	147	8	malono‐	malono‐	NOUN
eurjchem-1508	147	9	nitrile	nitrile	PROPN
eurjchem-1508	147	10	(	(	PUNCT
eurjchem-1508	147	11	6	6	NUM
eurjchem-1508	147	12	)	)	PUNCT
eurjchem-1508	147	13	and	and	CCONJ
eurjchem-1508	147	14	aromatic	aromatic	ADJ
eurjchem-1508	147	15	aldehyde	aldehyde	NOUN
eurjchem-1508	147	16	7a	7a	NOUN
eurjchem-1508	147	17	at	at	ADP
eurjchem-1508	147	18	the	the	DET
eurjchem-1508	147	19	same	same	ADJ
eurjchem-1508	147	20	conditions	condition	NOUN
eurjchem-1508	147	21	to	to	PART
eurjchem-1508	147	22	afford	afford	VERB
eurjchem-1508	147	23	the	the	DET
eurjchem-1508	147	24	pyridazine	pyridazine	NOUN
eurjchem-1508	147	25	derivative	derivative	ADJ
eurjchem-1508	147	26	22	22	NUM
eurjchem-1508	147	27	(	(	PUNCT
eurjchem-1508	147	28	scheme	scheme	NOUN
eurjchem-1508	147	29	5	5	NUM
eurjchem-1508	147	30	)	)	PUNCT
eurjchem-1508	147	31	.	.	PUNCT
eurjchem-1508	148	1	although	although	SCONJ
eurjchem-1508	148	2	,	,	PUNCT
eurjchem-1508	148	3	in	in	ADP
eurjchem-1508	148	4	a	a	DET
eurjchem-1508	148	5	previous	previous	ADJ
eurjchem-1508	148	6	article	article	NOUN
eurjchem-1508	148	7	,	,	PUNCT
eurjchem-1508	148	8	moustafa	moustafa	PROPN
eurjchem-1508	148	9	et	et	PROPN
eurjchem-1508	148	10	al	al	PROPN
eurjchem-1508	148	11	.	.	PUNCT
eurjchem-1508	149	1	[	[	X
eurjchem-1508	149	2	18	18	NUM
eurjchem-1508	149	3	]	]	PUNCT
eurjchem-1508	149	4	reported	report	VERB
eurjchem-1508	149	5	the	the	DET
eurjchem-1508	149	6	formation	formation	NOUN
eurjchem-1508	149	7	of	of	ADP
eurjchem-1508	149	8	pyridazino[5,4,3‐de][1,6]napht‐	pyridazino[5,4,3‐de][1,6]napht‐	VERB
eurjchem-1508	149	9	hyridine	hyridine	NOUN
eurjchem-1508	149	10	derivatives	derivative	NOUN
eurjchem-1508	149	11	via	via	ADP
eurjchem-1508	149	12	reaction	reaction	NOUN
eurjchem-1508	149	13	of	of	ADP
eurjchem-1508	149	14	ethyl	ethyl	PROPN
eurjchem-1508	149	15	3‐oxo‐2‐arylhydra‐	3‐oxo‐2‐arylhydra‐	PROPN
eurjchem-1508	149	16	zono	zono	NOUN
eurjchem-1508	149	17	butanoate	butanoate	VERB
eurjchem-1508	149	18	,	,	PUNCT
eurjchem-1508	149	19	malononitrile	malononitrile	NOUN
eurjchem-1508	149	20	and	and	CCONJ
eurjchem-1508	149	21	aromatic	aromatic	ADJ
eurjchem-1508	149	22	aldehydes	aldehyde	NOUN
eurjchem-1508	149	23	under	under	ADP
eurjchem-1508	149	24	high	high	ADJ
eurjchem-1508	149	25	pressure	pressure	NOUN
eurjchem-1508	149	26	but	but	CCONJ
eurjchem-1508	149	27	they	they	PRON
eurjchem-1508	149	28	could	could	AUX
eurjchem-1508	149	29	not	not	PART
eurjchem-1508	149	30	conclude	conclude	VERB
eurjchem-1508	149	31	exact	exact	ADJ
eurjchem-1508	149	32	mechanism	mechanism	NOUN
eurjchem-1508	149	33	of	of	ADP
eurjchem-1508	149	34	the	the	DET
eurjchem-1508	149	35	process	process	NOUN
eurjchem-1508	149	36	leading	lead	VERB
eurjchem-1508	149	37	to	to	ADP
eurjchem-1508	149	38	the	the	DET
eurjchem-1508	149	39	formation	formation	NOUN
eurjchem-1508	149	40	of	of	ADP
eurjchem-1508	149	41	the	the	DET
eurjchem-1508	149	42	tricyclic	tricyclic	ADJ
eurjchem-1508	149	43	system	system	NOUN
eurjchem-1508	149	44	.	.	PUNCT
eurjchem-1508	150	1	sadek	sadek	PROPN
eurjchem-1508	150	2	et	et	PROPN
eurjchem-1508	150	3	al	al	PROPN
eurjchem-1508	150	4	.	.	PUNCT
eurjchem-1508	150	5	/	/	SYM
eurjchem-1508	150	6	european	european	PROPN
eurjchem-1508	150	7	journal	journal	PROPN
eurjchem-1508	150	8	of	of	ADP
eurjchem-1508	150	9	chemistry	chemistry	NOUN
eurjchem-1508	150	10	7	7	NUM
eurjchem-1508	150	11	(	(	PUNCT
eurjchem-1508	150	12	4	4	NUM
eurjchem-1508	150	13	)	)	PUNCT
eurjchem-1508	150	14	(	(	PUNCT
eurjchem-1508	150	15	2016	2016	NUM
eurjchem-1508	150	16	)	)	PUNCT
eurjchem-1508	150	17	468‐472	468‐472	NOUN
eurjchem-1508	151	1	471	471	NUM
eurjchem-1508	151	2	o	o	NOUN
eurjchem-1508	151	3	n	n	CCONJ
eurjchem-1508	151	4	n	n	PROPN
eurjchem-1508	151	5	h	h	NOUN
eurjchem-1508	151	6	ar	ar	PROPN
eurjchem-1508	151	7	2	2	NUM
eurjchem-1508	151	8	ch2(cn)2	ch2(cn)2	ADP
eurjchem-1508	151	9	high	high	ADJ
eurjchem-1508	151	10	pressure	pressure	NOUN
eurjchem-1508	151	11	20	20	NUM
eurjchem-1508	151	12	min	min	NOUN
eurjchem-1508	151	13	cn	cn	PROPN
eurjchem-1508	152	1	cn	cn	PROPN
eurjchem-1508	152	2	h2n	h2n	PROPN
eurjchem-1508	153	1	cn	cn	PROPN
eurjchem-1508	153	2	cn	cn	PROPN
eurjchem-1508	153	3	cnnc	cnnc	PROPN
eurjchem-1508	153	4	h2n	h2n	PROPN
eurjchem-1508	153	5	n	n	CCONJ
eurjchem-1508	153	6	n	n	PROPN
eurjchem-1508	153	7	h	h	PROPN
eurjchem-1508	153	8	ar	ar	PROPN
eurjchem-1508	153	9	pathway	pathway	PROPN
eurjchem-1508	153	10	b	b	PROPN
eurjchem-1508	153	11	pathway	pathway	NOUN
eurjchem-1508	153	12	a	a	DET
eurjchem-1508	153	13	cnnc	cnnc	PROPN
eurjchem-1508	153	14	h2n	h2n	PROPN
eurjchem-1508	153	15	n	n	CCONJ
eurjchem-1508	153	16	n	n	PROPN
eurjchem-1508	153	17	nh	nh	PROPN
eurjchem-1508	153	18	ar	ar	PROPN
eurjchem-1508	153	19	ar'cho	ar'cho	PROPN
eurjchem-1508	153	20	cnc	cnc	PROPN
eurjchem-1508	153	21	h2n	h2n	PROPN
eurjchem-1508	153	22	n	n	CCONJ
eurjchem-1508	153	23	n	n	PROPN
eurjchem-1508	153	24	nh	nh	PROPN
eurjchem-1508	153	25	ar	ar	PROPN
eurjchem-1508	153	26	ar	ar	PROPN
eurjchem-1508	153	27	'	'	PUNCT
eurjchem-1508	153	28	n	n	CCONJ
eurjchem-1508	153	29	n	n	DET
eurjchem-1508	153	30	ar	ar	NOUN
eurjchem-1508	153	31	'	'	PUNCT
eurjchem-1508	153	32	n	n	PRON
eurjchem-1508	153	33	ar	ar	PROPN
eurjchem-1508	153	34	n	n	PROPN
eurjchem-1508	153	35	nh	nh	PROPN
eurjchem-1508	153	36	h2n	h2n	PROPN
eurjchem-1508	153	37	nc	nc	PROPN
eurjchem-1508	153	38	n	n	PROPN
eurjchem-1508	153	39	ar	ar	PROPN
eurjchem-1508	153	40	'	'	PUNCT
eurjchem-1508	153	41	n	n	PRON
eurjchem-1508	153	42	ar	ar	PROPN
eurjchem-1508	153	43	n	n	PROPN
eurjchem-1508	153	44	nh2	nh2	PROPN
eurjchem-1508	153	45	n	n	PROPN
eurjchem-1508	153	46	nc	nc	PROPN
eurjchem-1508	153	47	ch3	ch3	PROPN
eurjchem-1508	153	48	+	+	CCONJ
eurjchem-1508	153	49	ar'cho+	ar'cho+	PROPN
eurjchem-1508	153	50	ch3	ch3	PROPN
eurjchem-1508	153	51	ch3	ch3	PROPN
eurjchem-1508	153	52	ch3	ch3	PROPN
eurjchem-1508	153	53	ch3	ch3	PROPN
eurjchem-1508	153	54	ch3	ch3	PROPN
eurjchem-1508	153	55	n	n	PROPN
eurjchem-1508	153	56	nh	nh	PROPN
eurjchem-1508	153	57	ar	ar	PROPN
eurjchem-1508	153	58	h3c	h3c	PROPN
eurjchem-1508	153	59	cnnc	cnnc	PROPN
eurjchem-1508	154	1	ar'cho	ar'cho	PROPN
eurjchem-1508	154	2	n	n	PROPN
eurjchem-1508	154	3	n	n	PROPN
eurjchem-1508	154	4	nc	nc	PROPN
eurjchem-1508	154	5	nh	nh	PROPN
eurjchem-1508	154	6	ar	ar	PROPN
eurjchem-1508	154	7	n	n	PROPN
eurjchem-1508	154	8	n	n	PROPN
eurjchem-1508	154	9	nc	nc	PROPN
eurjchem-1508	154	10	nh	nh	PROPN
eurjchem-1508	154	11	ar	ar	PROPN
eurjchem-1508	154	12	ch3	ch3	PROPN
eurjchem-1508	154	13	ar	ar	PROPN
eurjchem-1508	154	14	'	'	PROPN
eurjchem-1508	154	15	ch3	ch3	PROPN
eurjchem-1508	154	16	cnnc	cnnc	PROPN
eurjchem-1508	154	17	1h	1h	NUM
eurjchem-1508	154	18	6	6	NUM
eurjchem-1508	154	19	7	7	NUM
eurjchem-1508	154	20	9	9	NUM
eurjchem-1508	154	21	10	10	NUM
eurjchem-1508	154	22	11	11	NUM
eurjchem-1508	154	23	12	12	NUM
eurjchem-1508	154	24	13	13	NUM
eurjchem-1508	154	25	8	8	NUM
eurjchem-1508	154	26	14	14	NUM
eurjchem-1508	154	27	15	15	NUM
eurjchem-1508	154	28	16	16	NUM
eurjchem-1508	154	29	n	n	CCONJ
eurjchem-1508	154	30	n	n	CCONJ
eurjchem-1508	154	31	n	n	PROPN
eurjchem-1508	154	32	ar	ar	PROPN
eurjchem-1508	154	33	ar	ar	PROPN
eurjchem-1508	154	34	'	'	PUNCT
eurjchem-1508	154	35	ch3	ch3	PROPN
eurjchem-1508	154	36	17	17	NUM
eurjchem-1508	154	37	hn	hn	PROPN
eurjchem-1508	154	38	nh	nh	PROPN
eurjchem-1508	154	39	nc	nc	PROPN
eurjchem-1508	154	40	scheme	scheme	PROPN
eurjchem-1508	154	41	3	3	NUM
eurjchem-1508	154	42	scheme	scheme	NOUN
eurjchem-1508	154	43	4	4	NUM
eurjchem-1508	154	44	472	472	NUM
eurjchem-1508	154	45	sadek	sadek	PROPN
eurjchem-1508	154	46	et	et	PROPN
eurjchem-1508	154	47	al	al	PROPN
eurjchem-1508	154	48	.	.	PUNCT
eurjchem-1508	154	49	/	/	SYM
eurjchem-1508	154	50	european	european	PROPN
eurjchem-1508	154	51	journal	journal	PROPN
eurjchem-1508	154	52	of	of	ADP
eurjchem-1508	154	53	chemistry	chemistry	NOUN
eurjchem-1508	154	54	7	7	NUM
eurjchem-1508	154	55	(	(	PUNCT
eurjchem-1508	154	56	4	4	NUM
eurjchem-1508	154	57	)	)	PUNCT
eurjchem-1508	154	58	(	(	PUNCT
eurjchem-1508	154	59	2016	2016	NUM
eurjchem-1508	154	60	)	)	PUNCT
eurjchem-1508	154	61	468‐472	468‐472	PROPN
eurjchem-1508	154	62	scheme	scheme	NOUN
eurjchem-1508	154	63	5	5	NUM
eurjchem-1508	154	64	in	in	ADP
eurjchem-1508	154	65	our	our	PRON
eurjchem-1508	154	66	efforts	effort	NOUN
eurjchem-1508	154	67	described	describe	VERB
eurjchem-1508	154	68	above	above	ADP
eurjchem-1508	154	69	the	the	DET
eurjchem-1508	154	70	reactions	reaction	NOUN
eurjchem-1508	154	71	are	be	AUX
eurjchem-1508	154	72	also	also	ADV
eurjchem-1508	154	73	conducted	conduct	VERB
eurjchem-1508	154	74	in	in	ADP
eurjchem-1508	154	75	a	a	DET
eurjchem-1508	154	76	q‐tube	q‐tube	NOUN
eurjchem-1508	154	77	,	,	PUNCT
eurjchem-1508	154	78	as	as	ADP
eurjchem-1508	154	79	in	in	ADP
eurjchem-1508	154	80	more	more	ADJ
eurjchem-1508	154	81	than	than	ADP
eurjchem-1508	154	82	one	one	NUM
eurjchem-1508	154	83	situation	situation	NOUN
eurjchem-1508	154	84	,	,	PUNCT
eurjchem-1508	154	85	products	product	NOUN
eurjchem-1508	154	86	resulting	result	VERB
eurjchem-1508	154	87	from	from	ADP
eurjchem-1508	154	88	initial	initial	ADJ
eurjchem-1508	154	89	condensation	condensation	NOUN
eurjchem-1508	154	90	with	with	ADP
eurjchem-1508	154	91	malononitrile	malononitrile	NOUN
eurjchem-1508	154	92	as	as	ADP
eurjchem-1508	154	93	the	the	DET
eurjchem-1508	154	94	case	case	NOUN
eurjchem-1508	154	95	of	of	ADP
eurjchem-1508	154	96	compound	compound	NOUN
eurjchem-1508	154	97	1j	1j	NUM
eurjchem-1508	154	98	and	and	CCONJ
eurjchem-1508	154	99	1k	1k	NUM
eurjchem-1508	154	100	and	and	CCONJ
eurjchem-1508	154	101	subsequent	subsequent	ADJ
eurjchem-1508	154	102	reaction	reaction	NOUN
eurjchem-1508	154	103	with	with	ADP
eurjchem-1508	154	104	arylidene	arylidene	NOUN
eurjchem-1508	154	105	malononitrile	malononitrile	NOUN
eurjchem-1508	154	106	have	have	AUX
eurjchem-1508	154	107	been	be	AUX
eurjchem-1508	154	108	observed	observe	VERB
eurjchem-1508	154	109	which	which	PRON
eurjchem-1508	154	110	decisively	decisively	ADV
eurjchem-1508	154	111	excluded	exclude	VERB
eurjchem-1508	154	112	the	the	DET
eurjchem-1508	154	113	initial	initial	ADJ
eurjchem-1508	154	114	dimerization	dimerization	NOUN
eurjchem-1508	154	115	of	of	ADP
eurjchem-1508	154	116	malononitrile	malononitrile	NOUN
eurjchem-1508	154	117	.	.	PUNCT
eurjchem-1508	155	1	it	it	PRON
eurjchem-1508	155	2	is	be	AUX
eurjchem-1508	155	3	almost	almost	ADV
eurjchem-1508	155	4	certain	certain	ADJ
eurjchem-1508	155	5	that	that	SCONJ
eurjchem-1508	155	6	formation	formation	NOUN
eurjchem-1508	155	7	of	of	ADP
eurjchem-1508	155	8	the	the	DET
eurjchem-1508	155	9	tricyclic	tricyclic	ADJ
eurjchem-1508	155	10	system	system	NOUN
eurjchem-1508	155	11	proceed	proceed	VERB
eurjchem-1508	155	12	in	in	ADP
eurjchem-1508	155	13	the	the	DET
eurjchem-1508	155	14	same	same	ADJ
eurjchem-1508	155	15	way	way	NOUN
eurjchem-1508	155	16	operating	operate	VERB
eurjchem-1508	155	17	in	in	ADP
eurjchem-1508	155	18	case	case	NOUN
eurjchem-1508	155	19	of	of	ADP
eurjchem-1508	155	20	compound	compound	NOUN
eurjchem-1508	155	21	1j	1j	NUM
eurjchem-1508	155	22	,	,	PUNCT
eurjchem-1508	155	23	k	k	PROPN
eurjchem-1508	155	24	establishing	establish	VERB
eurjchem-1508	155	25	route	route	NOUN
eurjchem-1508	155	26	a	a	PRON
eurjchem-1508	155	27	for	for	ADP
eurjchem-1508	155	28	the	the	DET
eurjchem-1508	155	29	reaction	reaction	NOUN
eurjchem-1508	155	30	mechanism	mechanism	NOUN
eurjchem-1508	155	31	.	.	PUNCT
eurjchem-1508	156	1	4	4	X
eurjchem-1508	156	2	.	.	X
eurjchem-1508	156	3	conclusions	conclusion	NOUN
eurjchem-1508	156	4	we	we	PRON
eurjchem-1508	156	5	do	do	AUX
eurjchem-1508	156	6	conclude	conclude	VERB
eurjchem-1508	156	7	that	that	PRON
eurjchem-1508	156	8	,	,	PUNCT
eurjchem-1508	156	9	3	3	NUM
eurjchem-1508	156	10	+	+	SYM
eurjchem-1508	156	11	3	3	NUM
eurjchem-1508	156	12	atom	atom	NOUN
eurjchem-1508	156	13	combination	combination	NOUN
eurjchem-1508	156	14	synthesis	synthesis	NOUN
eurjchem-1508	156	15	of	of	ADP
eurjchem-1508	156	16	dihydropyridazines	dihydropyridazine	NOUN
eurjchem-1508	156	17	is	be	AUX
eurjchem-1508	156	18	in	in	ADP
eurjchem-1508	156	19	fact	fact	NOUN
eurjchem-1508	156	20	very	very	ADV
eurjchem-1508	156	21	limited	limited	ADJ
eurjchem-1508	156	22	scope	scope	NOUN
eurjchem-1508	156	23	.	.	PUNCT
eurjchem-1508	157	1	efficient	efficient	ADJ
eurjchem-1508	157	2	electron	electron	NOUN
eurjchem-1508	157	3	donating	donate	VERB
eurjchem-1508	157	4	substituents	substituent	NOUN
eurjchem-1508	157	5	at	at	ADP
eurjchem-1508	157	6	the	the	DET
eurjchem-1508	157	7	hydrazone	hydrazone	NOUN
eurjchem-1508	157	8	aryl	aryl	NOUN
eurjchem-1508	157	9	moiety	moiety	NOUN
eurjchem-1508	157	10	renders	render	VERB
eurjchem-1508	157	11	hydrazone	hydrazone	NOUN
eurjchem-1508	157	12	c‐1	c‐1	NOUN
eurjchem-1508	157	13	the	the	DET
eurjchem-1508	157	14	most	most	ADV
eurjchem-1508	157	15	reactive	reactive	ADJ
eurjchem-1508	157	16	center	center	NOUN
eurjchem-1508	157	17	.	.	PUNCT
eurjchem-1508	158	1	electron	electron	NOUN
eurjchem-1508	158	2	attracting	attract	VERB
eurjchem-1508	158	3	substituents	substituent	NOUN
eurjchem-1508	158	4	reverse	reverse	VERB
eurjchem-1508	158	5	the	the	DET
eurjchem-1508	158	6	situation	situation	NOUN
eurjchem-1508	158	7	rendering	render	VERB
eurjchem-1508	158	8	the	the	DET
eurjchem-1508	158	9	acyl	acyl	NOUN
eurjchem-1508	158	10	carbonyl	carbonyl	NOUN
eurjchem-1508	158	11	the	the	DET
eurjchem-1508	158	12	most	most	ADV
eurjchem-1508	158	13	reactive	reactive	ADJ
eurjchem-1508	158	14	center	center	NOUN
eurjchem-1508	158	15	and	and	CCONJ
eurjchem-1508	158	16	the	the	DET
eurjchem-1508	158	17	active	active	ADJ
eurjchem-1508	158	18	methylene	methylene	NOUN
eurjchem-1508	158	19	initially	initially	ADV
eurjchem-1508	158	20	condense	condense	VERB
eurjchem-1508	158	21	with	with	ADP
eurjchem-1508	158	22	yielding	yield	VERB
eurjchem-1508	158	23	the	the	DET
eurjchem-1508	158	24	corresponding	corresponding	ADJ
eurjchem-1508	158	25	ylidene	ylidene	ADJ
eurjchem-1508	158	26	derivative	derivative	NOUN
eurjchem-1508	158	27	that	that	PRON
eurjchem-1508	158	28	react	react	VERB
eurjchem-1508	158	29	further	far	ADV
eurjchem-1508	158	30	with	with	ADP
eurjchem-1508	158	31	another	another	PRON
eurjchem-1508	158	32	of	of	ADP
eurjchem-1508	158	33	the	the	DET
eurjchem-1508	158	34	reagent	reagent	NOUN
eurjchem-1508	158	35	to	to	PART
eurjchem-1508	158	36	yield	yield	VERB
eurjchem-1508	158	37	biaryl	biaryl	NOUN
eurjchem-1508	158	38	derivatives	derivative	NOUN
eurjchem-1508	158	39	(	(	PUNCT
eurjchem-1508	158	40	4	4	NUM
eurjchem-1508	158	41	)	)	PUNCT
eurjchem-1508	158	42	as	as	ADP
eurjchem-1508	158	43	with	with	ADP
eurjchem-1508	158	44	ortho‐ester	ortho‐ester	PROPN
eurjchem-1508	158	45	group	group	NOUN
eurjchem-1508	158	46	,	,	PUNCT
eurjchem-1508	158	47	where	where	SCONJ
eurjchem-1508	158	48	hydrogen	hydrogen	NOUN
eurjchem-1508	158	49	bonding	bonding	NOUN
eurjchem-1508	158	50	of	of	ADP
eurjchem-1508	158	51	hydrazine	hydrazine	NOUN
eurjchem-1508	158	52	nh	nh	PROPN
eurjchem-1508	158	53	with	with	ADP
eurjchem-1508	158	54	ester	ester	NOUN
eurjchem-1508	158	55	group	group	NOUN
eurjchem-1508	158	56	enhances	enhance	VERB
eurjchem-1508	158	57	this	this	DET
eurjchem-1508	158	58	process	process	NOUN
eurjchem-1508	158	59	.	.	PUNCT
eurjchem-1508	159	1	if	if	SCONJ
eurjchem-1508	159	2	alternate	alternate	ADJ
eurjchem-1508	159	3	cyclization	cyclization	NOUN
eurjchem-1508	159	4	products	product	NOUN
eurjchem-1508	159	5	are	be	AUX
eurjchem-1508	159	6	either	either	CCONJ
eurjchem-1508	159	7	more	more	ADV
eurjchem-1508	159	8	stable	stable	ADJ
eurjchem-1508	159	9	or	or	CCONJ
eurjchem-1508	159	10	less	less	ADV
eurjchem-1508	159	11	soluble	soluble	ADJ
eurjchem-1508	159	12	product	product	NOUN
eurjchem-1508	159	13	,	,	PUNCT
eurjchem-1508	159	14	then	then	ADV
eurjchem-1508	159	15	another	another	DET
eurjchem-1508	159	16	cyclization	cyclization	NOUN
eurjchem-1508	159	17	course	course	NOUN
eurjchem-1508	159	18	took	take	VERB
eurjchem-1508	159	19	place	place	NOUN
eurjchem-1508	159	20	.	.	PUNCT
eurjchem-1508	160	1	in	in	ADP
eurjchem-1508	160	2	case	case	NOUN
eurjchem-1508	160	3	of	of	ADP
eurjchem-1508	160	4	compound	compound	NOUN
eurjchem-1508	160	5	1k	1k	NOUN
eurjchem-1508	160	6	,	,	PUNCT
eurjchem-1508	160	7	the	the	DET
eurjchem-1508	160	8	produced	produce	VERB
eurjchem-1508	160	9	enamino‐	enamino‐	PROPN
eurjchem-1508	160	10	nitrile	nitrile	NOUN
eurjchem-1508	160	11	is	be	AUX
eurjchem-1508	160	12	more	more	ADV
eurjchem-1508	160	13	reactive	reactive	ADJ
eurjchem-1508	160	14	than	than	ADP
eurjchem-1508	160	15	the	the	DET
eurjchem-1508	160	16	start	start	NOUN
eurjchem-1508	160	17	and	and	CCONJ
eurjchem-1508	160	18	further	far	ADV
eurjchem-1508	160	19	reacted	react	VERB
eurjchem-1508	160	20	yielding	yield	VERB
eurjchem-1508	160	21	the	the	DET
eurjchem-1508	160	22	tricyclic	tricyclic	ADJ
eurjchem-1508	160	23	system	system	NOUN
eurjchem-1508	160	24	.	.	PUNCT
eurjchem-1508	161	1	steric	steric	ADJ
eurjchem-1508	161	2	hindrance	hindrance	NOUN
eurjchem-1508	161	3	of	of	ADP
eurjchem-1508	161	4	the	the	DET
eurjchem-1508	161	5	acyl	acyl	NOUN
eurjchem-1508	161	6	carbonyl	carbonyl	NOUN
eurjchem-1508	161	7	also	also	ADV
eurjchem-1508	161	8	plays	play	VERB
eurjchem-1508	161	9	a	a	DET
eurjchem-1508	161	10	role	role	NOUN
eurjchem-1508	161	11	in	in	ADP
eurjchem-1508	161	12	such	such	ADJ
eurjchem-1508	161	13	reaction	reaction	NOUN
eurjchem-1508	161	14	.	.	PUNCT
eurjchem-1508	162	1	in	in	ADP
eurjchem-1508	162	2	case	case	NOUN
eurjchem-1508	162	3	of	of	ADP
eurjchem-1508	162	4	com‐	com‐	PROPN
eurjchem-1508	162	5	pound	pound	NOUN
eurjchem-1508	162	6	1	1	NUM
eurjchem-1508	162	7	,	,	PUNCT
eurjchem-1508	162	8	the	the	DET
eurjchem-1508	162	9	propanoyl	propanoyl	PROPN
eurjchem-1508	162	10	groups	group	NOUN
eurjchem-1508	162	11	render	render	VERB
eurjchem-1508	162	12	the	the	DET
eurjchem-1508	162	13	carbonyl	carbonyl	NOUN
eurjchem-1508	162	14	group	group	NOUN
eurjchem-1508	162	15	less	less	ADV
eurjchem-1508	162	16	reactive	reactive	ADJ
eurjchem-1508	162	17	for	for	ADP
eurjchem-1508	162	18	further	further	ADJ
eurjchem-1508	162	19	cyclization	cyclization	NOUN
eurjchem-1508	162	20	.	.	PUNCT
eurjchem-1508	163	1	moreover	moreover	ADV
eurjchem-1508	163	2	,	,	PUNCT
eurjchem-1508	163	3	in	in	ADP
eurjchem-1508	163	4	a	a	DET
eurjchem-1508	163	5	multicompo‐	multicompo‐	NOUN
eurjchem-1508	163	6	nent	nent	NOUN
eurjchem-1508	163	7	reaction	reaction	NOUN
eurjchem-1508	163	8	the	the	DET
eurjchem-1508	163	9	active	active	ADJ
eurjchem-1508	163	10	methylene	methylene	NOUN
eurjchem-1508	163	11	reagent	reagent	NOUN
eurjchem-1508	163	12	initially	initially	ADV
eurjchem-1508	163	13	condense	condense	VERB
eurjchem-1508	163	14	with	with	ADP
eurjchem-1508	163	15	acyl	acyl	NOUN
eurjchem-1508	163	16	carbonyl	carbonyl	NOUN
eurjchem-1508	163	17	moiety	moiety	NOUN
eurjchem-1508	163	18	rather	rather	ADV
eurjchem-1508	163	19	than	than	ADP
eurjchem-1508	163	20	initial	initial	ADJ
eurjchem-1508	163	21	formation	formation	NOUN
eurjchem-1508	163	22	of	of	ADP
eurjchem-1508	163	23	arylidene	arylidene	NOUN
eurjchem-1508	163	24	derivative	derivative	NOUN
eurjchem-1508	163	25	that	that	PRON
eurjchem-1508	163	26	has	have	VERB
eurjchem-1508	163	27	the	the	DET
eurjchem-1508	163	28	potentiality	potentiality	NOUN
eurjchem-1508	163	29	to	to	PART
eurjchem-1508	163	30	add	add	VERB
eurjchem-1508	163	31	to	to	PART
eurjchem-1508	163	32	aryl‐	aryl‐	VERB
eurjchem-1508	163	33	hydrazonal	hydrazonal	ADJ
eurjchem-1508	163	34	c‐1	c‐1	NOUN
eurjchem-1508	163	35	,	,	PUNCT
eurjchem-1508	163	36	establishing	establish	VERB
eurjchem-1508	163	37	that	that	DET
eurjchem-1508	163	38	initial	initial	ADJ
eurjchem-1508	163	39	dimerization	dimerization	NOUN
eurjchem-1508	163	40	of	of	ADP
eurjchem-1508	163	41	malononitrile	malononitrile	NOUN
eurjchem-1508	163	42	does	do	AUX
eurjchem-1508	163	43	not	not	PART
eurjchem-1508	163	44	occur	occur	VERB
eurjchem-1508	163	45	.	.	PUNCT
eurjchem-1508	164	1	references	reference	NOUN
eurjchem-1508	164	2	[	[	X
eurjchem-1508	164	3	1	1	NUM
eurjchem-1508	164	4	]	]	PUNCT
eurjchem-1508	164	5	.	.	PUNCT
eurjchem-1508	165	1	elnagdi	elnagdi	PROPN
eurjchem-1508	165	2	,	,	PUNCT
eurjchem-1508	165	3	m.	m.	PROPN
eurjchem-1508	165	4	h.	h.	PROPN
eurjchem-1508	165	5	;	;	PUNCT
eurjchem-1508	165	6	sadek	sadek	PROPN
eurjchem-1508	165	7	,	,	PUNCT
eurjchem-1508	165	8	k.	k.	PROPN
eurjchem-1508	165	9	u.	u.	PROPN
eurjchem-1508	165	10	;	;	PUNCT
eurjchem-1508	165	11	moustafa	moustafa	PROPN
eurjchem-1508	165	12	,	,	PUNCT
eurjchem-1508	165	13	m.	m.	NOUN
eurjchem-1508	165	14	s.	s.	PROPN
eurjchem-1508	165	15	adv	adv	PROPN
eurjchem-1508	165	16	.	.	PUNCT
eurjchem-1508	166	1	heterocycl	heterocycl	PROPN
eurjchem-1508	166	2	.	.	PUNCT
eurjchem-1508	166	3	chem	chem	PROPN
eurjchem-1508	166	4	.	.	PUNCT
eurjchem-1508	167	1	2013	2013	NUM
eurjchem-1508	167	2	,	,	PUNCT
eurjchem-1508	167	3	103	103	NUM
eurjchem-1508	167	4	,	,	PUNCT
eurjchem-1508	167	5	241‐312	241‐312	NUM
eurjchem-1508	167	6	.	.	PUNCT
eurjchem-1508	168	1	[	[	X
eurjchem-1508	168	2	2	2	NUM
eurjchem-1508	168	3	]	]	PUNCT
eurjchem-1508	168	4	.	.	PUNCT
eurjchem-1508	169	1	elnagdi	elnagdi	PROPN
eurjchem-1508	169	2	,	,	PUNCT
eurjchem-1508	169	3	m.	m.	PROPN
eurjchem-1508	169	4	h.	h.	PROPN
eurjchem-1508	169	5	;	;	PUNCT
eurjchem-1508	169	6	moustafa	moustafa	PROPN
eurjchem-1508	169	7	,	,	PUNCT
eurjchem-1508	169	8	m.	m.	NOUN
eurjchem-1508	169	9	s.	s.	PROPN
eurjchem-1508	169	10	;	;	PUNCT
eurjchem-1508	169	11	al‐mousawi	al‐mousawi	PROPN
eurjchem-1508	169	12	,	,	PUNCT
eurjchem-1508	169	13	s.	s.	PROPN
eurjchem-1508	169	14	m.	m.	PROPN
eurjchem-1508	169	15	;	;	PUNCT
eurjchem-1508	169	16	mekheimer	mekheimer	PROPN
eurjchem-1508	169	17	,	,	PUNCT
eurjchem-1508	169	18	r.	r.	PROPN
eurjchem-1508	169	19	a.	a.	PROPN
eurjchem-1508	169	20	;	;	PUNCT
eurjchem-1508	169	21	sadek	sadek	PROPN
eurjchem-1508	169	22	,	,	PUNCT
eurjchem-1508	169	23	k.	k.	PROPN
eurjchem-1508	169	24	u.	u.	PROPN
eurjchem-1508	169	25	mol	mol	PROPN
eurjchem-1508	169	26	.	.	PUNCT
eurjchem-1508	170	1	divers	diver	NOUN
eurjchem-1508	170	2	.	.	PUNCT
eurjchem-1508	171	1	2015	2015	NUM
eurjchem-1508	171	2	,	,	PUNCT
eurjchem-1508	171	3	19(3	19(3	NUM
eurjchem-1508	171	4	)	)	PUNCT
eurjchem-1508	171	5	,	,	PUNCT
eurjchem-1508	172	1	625‐651	625‐651	PROPN
eurjchem-1508	172	2	.	.	PUNCT
eurjchem-1508	173	1	[	[	X
eurjchem-1508	173	2	3	3	NUM
eurjchem-1508	173	3	]	]	PUNCT
eurjchem-1508	173	4	.	.	PUNCT
eurjchem-1508	174	1	mekhaeimer	mekhaeimer	PROPN
eurjchem-1508	174	2	,	,	PUNCT
eurjchem-1508	174	3	r.	r.	PROPN
eurjchem-1508	174	4	a.	a.	PROPN
eurjchem-1508	174	5	;	;	PUNCT
eurjchem-1508	174	6	shaker	shaker	PROPN
eurjchem-1508	174	7	,	,	PUNCT
eurjchem-1508	174	8	r.	r.	PROPN
eurjchem-1508	174	9	m.	m.	PROPN
eurjchem-1508	174	10	;	;	PUNCT
eurjchem-1508	174	11	sadek	sadek	PROPN
eurjchem-1508	174	12	,	,	PUNCT
eurjchem-1508	174	13	k.	k.	PROPN
eurjchem-1508	174	14	u.	u.	PROPN
eurjchem-1508	174	15	;	;	PUNCT
eurjchem-1508	174	16	otto	otto	PROPN
eurjchem-1508	174	17	,	,	PUNCT
eurjchem-1508	174	18	h.	h.	PROPN
eurjchem-1508	174	19	h.	h.	PROPN
eurjchem-1508	174	20	heterocycl	heterocycl	PROPN
eurjchem-1508	174	21	.	.	PUNCT
eurjchem-1508	175	1	commun	commun	PROPN
eurjchem-1508	175	2	.	.	PUNCT
eurjchem-1508	176	1	1997	1997	NUM
eurjchem-1508	176	2	,	,	PUNCT
eurjchem-1508	176	3	3	3	NUM
eurjchem-1508	176	4	,	,	PUNCT
eurjchem-1508	176	5	217‐221	217‐221	NOUN
eurjchem-1508	176	6	.	.	PUNCT
eurjchem-1508	177	1	[	[	X
eurjchem-1508	177	2	4	4	NUM
eurjchem-1508	177	3	]	]	PUNCT
eurjchem-1508	177	4	.	.	PUNCT
eurjchem-1508	178	1	abd	abd	PROPN
eurjchem-1508	178	2	el	el	PROPN
eurjchem-1508	178	3	latif	latif	PROPN
eurjchem-1508	178	4	,	,	PUNCT
eurjchem-1508	178	5	f.	f.	PROPN
eurjchem-1508	178	6	m.	m.	PROPN
eurjchem-1508	178	7	;	;	PUNCT
eurjchem-1508	178	8	barsy	barsy	NOUN
eurjchem-1508	178	9	,	,	PUNCT
eurjchem-1508	178	10	m.	m.	NOUN
eurjchem-1508	178	11	a.	a.	PROPN
eurjchem-1508	178	12	;	;	PUNCT
eurjchem-1508	178	13	aref	aref	PROPN
eurjchem-1508	178	14	,	,	PUNCT
eurjchem-1508	178	15	a.	a.	NOUN
eurjchem-1508	178	16	m.	m.	NOUN
eurjchem-1508	178	17	;	;	PUNCT
eurjchem-1508	178	18	sadek	sadek	PROPN
eurjchem-1508	178	19	,	,	PUNCT
eurjchem-1508	178	20	k.	k.	PROPN
eurjchem-1508	178	21	u.	u.	PROPN
eurjchem-1508	178	22	green	green	PROPN
eurjchem-1508	178	23	chem	chem	PROPN
eurjchem-1508	178	24	.	.	PUNCT
eurjchem-1508	179	1	2002	2002	NUM
eurjchem-1508	179	2	,	,	PUNCT
eurjchem-1508	179	3	4	4	NUM
eurjchem-1508	179	4	,	,	PUNCT
eurjchem-1508	179	5	196‐198	196‐198	NUM
eurjchem-1508	179	6	.	.	PUNCT
eurjchem-1508	180	1	[	[	X
eurjchem-1508	180	2	5	5	NUM
eurjchem-1508	180	3	]	]	PUNCT
eurjchem-1508	180	4	.	.	PUNCT
eurjchem-1508	181	1	al‐zaydi	al‐zaydi	PROPN
eurjchem-1508	181	2	,	,	PUNCT
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eurjchem-1508	181	5	;	;	PUNCT
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eurjchem-1508	181	22	.	.	PUNCT
eurjchem-1508	182	1	[	[	X
eurjchem-1508	182	2	6	6	NUM
eurjchem-1508	182	3	]	]	PUNCT
eurjchem-1508	182	4	.	.	PUNCT
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eurjchem-1508	183	5	hilmy	hilmy	INTJ
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eurjchem-1508	184	2	,	,	PUNCT
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eurjchem-1508	184	4	,	,	PUNCT
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eurjchem-1508	184	6	.	.	PUNCT
eurjchem-1508	185	1	[	[	X
eurjchem-1508	185	2	7	7	NUM
eurjchem-1508	185	3	]	]	PUNCT
eurjchem-1508	185	4	.	.	PUNCT
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eurjchem-1508	186	2	,	,	PUNCT
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eurjchem-1508	186	4	;	;	PUNCT
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eurjchem-1508	186	6	,	,	PUNCT
eurjchem-1508	186	7	a.	a.	NOUN
eurjchem-1508	186	8	;	;	PUNCT
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eurjchem-1508	186	17	.	.	PUNCT
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eurjchem-1508	187	2	.	.	PUNCT
eurjchem-1508	188	1	a‐	a‐	PROPN
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eurjchem-1508	188	5	,	,	PUNCT
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eurjchem-1508	188	8	52‐60	52‐60	NUM
eurjchem-1508	188	9	.	.	PUNCT
eurjchem-1508	189	1	[	[	X
eurjchem-1508	189	2	8	8	NUM
eurjchem-1508	189	3	]	]	PUNCT
eurjchem-1508	189	4	.	.	PUNCT
eurjchem-1508	190	1	kappe	kappe	PROPN
eurjchem-1508	190	2	,	,	PUNCT
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eurjchem-1508	190	5	;	;	PUNCT
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eurjchem-1508	190	7	,	,	PUNCT
eurjchem-1508	190	8	a.	a.	NOUN
eurjchem-1508	190	9	;	;	PUNCT
eurjchem-1508	190	10	dallingea	dallingea	PROPN
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eurjchem-1508	190	12	d.	d.	PROPN
eurjchem-1508	190	13	;	;	PUNCT
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eurjchem-1508	190	16	r.	r.	PROPN
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eurjchem-1508	190	24	2nd	2nd	PROPN
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eurjchem-1508	191	1	[	[	X
eurjchem-1508	191	2	9	9	NUM
eurjchem-1508	191	3	]	]	PUNCT
eurjchem-1508	191	4	.	.	PUNCT
eurjchem-1508	192	1	kiselev	kiselev	PROPN
eurjchem-1508	192	2	,	,	PUNCT
eurjchem-1508	192	3	v.	v.	PROPN
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eurjchem-1508	192	5	;	;	PUNCT
eurjchem-1508	192	6	kornilov	kornilov	PROPN
eurjchem-1508	192	7	,	,	PUNCT
eurjchem-1508	192	8	d.	d.	PROPN
eurjchem-1508	192	9	a.	a.	PROPN
eurjchem-1508	192	10	;	;	PUNCT
eurjchem-1508	192	11	lekomtseva	lekomtseva	PROPN
eurjchem-1508	192	12	,	,	PUNCT
eurjchem-1508	192	13	i.	i.	PROPN
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eurjchem-1508	192	15	;	;	PUNCT
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eurjchem-1508	192	17	,	,	PUNCT
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eurjchem-1508	192	19	i.	i.	PROPN
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eurjchem-1508	192	21	.	.	PUNCT
eurjchem-1508	193	1	j.	j.	PROPN
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eurjchem-1508	193	3	.	.	PUNCT
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eurjchem-1508	194	2	.	.	PUNCT
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eurjchem-1508	195	2	,	,	PUNCT
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eurjchem-1508	195	4	,	,	PUNCT
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eurjchem-1508	195	6	.	.	PUNCT
eurjchem-1508	196	1	[	[	X
eurjchem-1508	196	2	10	10	NUM
eurjchem-1508	196	3	]	]	PUNCT
eurjchem-1508	196	4	.	.	PUNCT
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eurjchem-1508	197	2	,	,	PUNCT
eurjchem-1508	197	3	m.	m.	NOUN
eurjchem-1508	197	4	;	;	PUNCT
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eurjchem-1508	197	6	,	,	PUNCT
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eurjchem-1508	197	8	;	;	PUNCT
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eurjchem-1508	197	10	,	,	PUNCT
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eurjchem-1508	197	12	;	;	PUNCT
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eurjchem-1508	197	14	,	,	PUNCT
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eurjchem-1508	197	22	.	.	PUNCT
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eurjchem-1508	198	2	.	.	PUNCT
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eurjchem-1508	199	2	.	.	PROPN
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eurjchem-1508	199	5	2(5	2(5	NUM
eurjchem-1508	199	6	)	)	PUNCT
eurjchem-1508	199	7	,	,	PUNCT
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eurjchem-1508	199	9	.	.	PUNCT
eurjchem-1508	200	1	[	[	X
eurjchem-1508	200	2	11	11	NUM
eurjchem-1508	200	3	]	]	PUNCT
eurjchem-1508	200	4	.	.	PUNCT
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eurjchem-1508	200	6	,	,	PUNCT
eurjchem-1508	200	7	k.	k.	PROPN
eurjchem-1508	200	8	m.	m.	PROPN
eurjchem-1508	200	9	;	;	PUNCT
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eurjchem-1508	200	14	;	;	PUNCT
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eurjchem-1508	201	2	,	,	PUNCT
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eurjchem-1508	201	4	,	,	PUNCT
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eurjchem-1508	201	6	.	.	PUNCT
eurjchem-1508	202	1	[	[	X
eurjchem-1508	202	2	12	12	NUM
eurjchem-1508	202	3	]	]	PUNCT
eurjchem-1508	202	4	.	.	PUNCT
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eurjchem-1508	203	2	,	,	PUNCT
eurjchem-1508	203	3	d.	d.	PROPN
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eurjchem-1508	203	5	;	;	PUNCT
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eurjchem-1508	203	7	,	,	PUNCT
eurjchem-1508	203	8	o.	o.	PROPN
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eurjchem-1508	203	10	;	;	PUNCT
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eurjchem-1508	203	21	.	.	PUNCT
eurjchem-1508	204	1	j.	j.	PROPN
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eurjchem-1508	204	3	.	.	PUNCT
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eurjchem-1508	205	2	,	,	PUNCT
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eurjchem-1508	205	4	,	,	PUNCT
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eurjchem-1508	205	6	.	.	PUNCT
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eurjchem-1508	206	4	.	.	PUNCT
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eurjchem-1508	207	5	;	;	PUNCT
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eurjchem-1508	208	2	,	,	PUNCT
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eurjchem-1508	208	4	,	,	PUNCT
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eurjchem-1508	208	6	.	.	PUNCT
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eurjchem-1508	209	4	.	.	PUNCT
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eurjchem-1508	210	6	;	;	PUNCT
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eurjchem-1508	210	20	,	,	PUNCT
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eurjchem-1508	210	22	.	.	PUNCT
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eurjchem-1508	211	3	]	]	PUNCT
eurjchem-1508	211	4	.	.	PUNCT
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eurjchem-1508	212	6	;	;	PUNCT
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eurjchem-1508	212	8	,	,	PUNCT
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eurjchem-1508	212	11	;	;	PUNCT
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eurjchem-1508	212	13	,	,	PUNCT
eurjchem-1508	212	14	h.	h.	PROPN
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eurjchem-1508	212	16	;	;	PUNCT
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eurjchem-1508	212	18	,	,	PUNCT
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eurjchem-1508	212	20	h.	h.	PROPN
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eurjchem-1508	212	22	heterocyclic	heterocyclic	PROPN
eurjchem-1508	212	23	.	.	PUNCT
eurjchem-1508	213	1	chem	chem	PROPN
eurjchem-1508	213	2	.	.	PUNCT
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eurjchem-1508	214	2	,	,	PUNCT
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eurjchem-1508	214	4	,	,	PUNCT
eurjchem-1508	214	5	1‐4	1‐4	NUM
eurjchem-1508	214	6	.	.	PUNCT
eurjchem-1508	215	1	[	[	X
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eurjchem-1508	215	3	]	]	PUNCT
eurjchem-1508	215	4	.	.	PUNCT
eurjchem-1508	216	1	al‐mousawi	al‐mousawi	PROPN
eurjchem-1508	216	2	,	,	PUNCT
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eurjchem-1508	216	5	;	;	PUNCT
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eurjchem-1508	216	7	,	,	PUNCT
eurjchem-1508	216	8	m.	m.	NOUN
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eurjchem-1508	216	10	;	;	PUNCT
eurjchem-1508	216	11	elnagdi	elnagdi	PROPN
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eurjchem-1508	216	17	.	.	PUNCT
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eurjchem-1508	217	2	,	,	PUNCT
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eurjchem-1508	217	4	,	,	PUNCT
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eurjchem-1508	217	6	.	.	PUNCT
eurjchem-1508	218	1	[	[	X
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eurjchem-1508	218	3	]	]	PUNCT
eurjchem-1508	218	4	.	.	PUNCT
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eurjchem-1508	219	5	s.	s.	PROPN
eurjchem-1508	219	6	;	;	PUNCT
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eurjchem-1508	219	8	,	,	PUNCT
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eurjchem-1508	219	11	;	;	PUNCT
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