id sid tid token lemma pos eurjchem-154 1 1 microsoft microsoft PROPN eurjchem-154 1 2 word word PROPN eurjchem-154 1 3 european_journal_of_chemistry_1_4_2010_388_396_154 european_journal_of_chemistry_1_4_2010_388_396_154 PROPN eurjchem-154 1 4 european european ADJ eurjchem-154 1 5     SPACE eurjchem-154 1 6 journal journal NOUN eurjchem-154 1 7     SPACE eurjchem-154 1 8 of of ADP eurjchem-154 1 9     SPACE eurjchem-154 1 10 chemistry chemistry NOUN eurjchem-154 1 11     SPACE eurjchem-154 1 12 1 1 NUM eurjchem-154 1 13     SPACE eurjchem-154 1 14 ( ( PUNCT eurjchem-154 1 15 4 4 NUM eurjchem-154 1 16 ) ) PUNCT eurjchem-154 1 17     SPACE eurjchem-154 1 18 ( ( PUNCT eurjchem-154 1 19 2010 2010 NUM eurjchem-154 1 20 ) ) PUNCT eurjchem-154 1 21     SPACE eurjchem-154 1 22 388‐396 388‐396 NUM eurjchem-154 1 23         SPACE eurjchem-154 1 24 european european ADJ eurjchem-154 1 25     SPACE eurjchem-154 1 26 journal journal NOUN eurjchem-154 1 27     SPACE eurjchem-154 1 28 of of ADP eurjchem-154 1 29     SPACE eurjchem-154 1 30 chemistry chemistry NOUN eurjchem-154 1 31     SPACE eurjchem-154 1 32 issn issn VERB eurjchem-154 1 33     SPACE eurjchem-154 1 34 2153‐2249 2153‐2249 NUM eurjchem-154 1 35     SPACE eurjchem-154 1 36 ( ( PUNCT eurjchem-154 1 37 print print NOUN eurjchem-154 1 38 ) ) PUNCT eurjchem-154 1 39     SPACE eurjchem-154 1 40 / / SYM eurjchem-154 1 41     SPACE eurjchem-154 1 42 issn issn VERB eurjchem-154 1 43     SPACE eurjchem-154 1 44 2153‐2257 2153‐2257 NUM eurjchem-154 1 45     SPACE eurjchem-154 1 46 ( ( PUNCT eurjchem-154 1 47 online online ADJ eurjchem-154 1 48 ) ) PUNCT eurjchem-154 1 49     SPACE eurjchem-154 1 50   NOUN eurjchem-154 1 51     SPACE eurjchem-154 1 52 2010 2010 NUM eurjchem-154 1 53     SPACE eurjchem-154 1 54 eurjchem eurjchem NOUN eurjchem-154 1 55     SPACE eurjchem-154 1 56 doi:10.5155 doi:10.5155 PROPN eurjchem-154 1 57 / / SYM eurjchem-154 1 58 eurjchem.1.4.388‐396.154 eurjchem.1.4.388‐396.154 NOUN eurjchem-154 1 59                 SPACE eurjchem-154 1 60 european european ADJ eurjchem-154 1 61     SPACE eurjchem-154 1 62 journal journal NOUN eurjchem-154 1 63     SPACE eurjchem-154 1 64 of of ADP eurjchem-154 1 65     SPACE eurjchem-154 1 66 chemistry chemistry NOUN eurjchem-154 1 67     SPACE eurjchem-154 1 68 journal journal NOUN eurjchem-154 1 69     SPACE eurjchem-154 1 70 homepage homepage NOUN eurjchem-154 1 71 : : PUNCT eurjchem-154 1 72     SPACE eurjchem-154 1 73 www.eurjchem.com www.eurjchem.com NOUN eurjchem-154 1 74                     SPACE eurjchem-154 1 75 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 1 76     SPACE eurjchem-154 1 77 chemistry chemistry NOUN eurjchem-154 1 78     SPACE eurjchem-154 1 79 part part NOUN eurjchem-154 1 80     SPACE eurjchem-154 1 81 ii ii PROPN eurjchem-154 1 82 : : PUNCT eurjchem-154 1 83     SPACE eurjchem-154 1 84 synthetic synthetic ADJ eurjchem-154 1 85     SPACE eurjchem-154 1 86 approaches approach NOUN eurjchem-154 1 87     SPACE eurjchem-154 1 88 for for ADP eurjchem-154 1 89     SPACE eurjchem-154 1 90 phosphorus phosphorus NOUN eurjchem-154 1 91     SPACE eurjchem-154 1 92 containing contain VERB eurjchem-154 1 93     SPACE eurjchem-154 1 94 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 1 95     SPACE eurjchem-154 1 96 derivatives derivative NOUN eurjchem-154 1 97     SPACE eurjchem-154 1 98 reda reda PROPN eurjchem-154 1 99     SPACE eurjchem-154 1 100 mohammady mohammady PROPN eurjchem-154 1 101     SPACE eurjchem-154 1 102 abdel‐rahman abdel‐rahman NOUN eurjchem-154 1 103 , , PUNCT eurjchem-154 1 104     SPACE eurjchem-154 1 105 magdy magdy NOUN eurjchem-154 1 106     SPACE eurjchem-154 1 107 ahmed ahmed PROPN eurjchem-154 1 108     SPACE eurjchem-154 1 109 ibrahim ibrahim PROPN eurjchem-154 1 110     SPACE eurjchem-154 1 111 and and CCONJ eurjchem-154 1 112     SPACE eurjchem-154 1 113 tarik tarik PROPN eurjchem-154 1 114     SPACE eurjchem-154 1 115 el‐sayed el‐saye VERB eurjchem-154 1 116     SPACE eurjchem-154 1 117 ali ali PROPN eurjchem-154 1 118 * * PROPN eurjchem-154 1 119     SPACE eurjchem-154 1 120 department department NOUN eurjchem-154 1 121     SPACE eurjchem-154 1 122 of of ADP eurjchem-154 1 123     SPACE eurjchem-154 1 124 chemistry chemistry NOUN eurjchem-154 1 125 , , PUNCT eurjchem-154 1 126     SPACE eurjchem-154 1 127 faculty faculty NOUN eurjchem-154 1 128     SPACE eurjchem-154 1 129 of of ADP eurjchem-154 1 130     SPACE eurjchem-154 1 131 education education NOUN eurjchem-154 1 132 , , PUNCT eurjchem-154 1 133     SPACE eurjchem-154 1 134 ain ain PROPN eurjchem-154 1 135     SPACE eurjchem-154 1 136 shams sham NOUN eurjchem-154 1 137     SPACE eurjchem-154 1 138 university university NOUN eurjchem-154 1 139 , , PUNCT eurjchem-154 1 140     SPACE eurjchem-154 1 141 roxy roxy PROPN eurjchem-154 1 142 , , PUNCT eurjchem-154 1 143     SPACE eurjchem-154 1 144 cairo cairo PROPN eurjchem-154 1 145 , , PUNCT eurjchem-154 1 146     SPACE eurjchem-154 1 147 eg­11711 eg­11711 PROPN eurjchem-154 1 148 , , PUNCT eurjchem-154 1 149     SPACE eurjchem-154 1 150 egypt egypt PROPN eurjchem-154 1 151     SPACE eurjchem-154 1 152 * * PROPN eurjchem-154 1 153 corresponding corresponding ADJ eurjchem-154 1 154     SPACE eurjchem-154 1 155 author author NOUN eurjchem-154 1 156     SPACE eurjchem-154 1 157 at at ADP eurjchem-154 1 158 : : PUNCT eurjchem-154 1 159     SPACE eurjchem-154 1 160 department department NOUN eurjchem-154 1 161     SPACE eurjchem-154 1 162 of of ADP eurjchem-154 1 163     SPACE eurjchem-154 1 164 chemistry chemistry NOUN eurjchem-154 1 165 , , PUNCT eurjchem-154 1 166     SPACE eurjchem-154 1 167 faculty faculty NOUN eurjchem-154 1 168     SPACE eurjchem-154 1 169 of of ADP eurjchem-154 1 170     SPACE eurjchem-154 1 171 education education NOUN eurjchem-154 1 172 , , PUNCT eurjchem-154 1 173     SPACE eurjchem-154 1 174 ain ain PROPN eurjchem-154 1 175     SPACE eurjchem-154 1 176 shams sham NOUN eurjchem-154 1 177     SPACE eurjchem-154 1 178 university university NOUN eurjchem-154 1 179 , , PUNCT eurjchem-154 1 180     SPACE eurjchem-154 1 181 cairo cairo PROPN eurjchem-154 1 182 , , PUNCT eurjchem-154 1 183     SPACE eurjchem-154 1 184 eg­11711 eg­11711 PROPN eurjchem-154 1 185 , , PUNCT eurjchem-154 1 186     SPACE eurjchem-154 1 187 egypt egypt PROPN eurjchem-154 1 188 . . PUNCT eurjchem-154 1 189     SPACE eurjchem-154 2 1 tel tel PROPN eurjchem-154 2 2 . . PUNCT eurjchem-154 2 3 : : PUNCT eurjchem-154 2 4     SPACE eurjchem-154 3 1 +2.010.3730144 +2.010.3730144 PROPN eurjchem-154 3 2 ; ; PUNCT eurjchem-154 3 3     SPACE eurjchem-154 3 4 fax fax NOUN eurjchem-154 3 5 : : PUNCT eurjchem-154 3 6     SPACE eurjchem-154 3 7 +2022581243 +2022581243 NOUN eurjchem-154 3 8 . . PUNCT eurjchem-154 3 9       SPACE eurjchem-154 3 10 e­mail e­mail NOUN eurjchem-154 3 11     SPACE eurjchem-154 3 12 address address NOUN eurjchem-154 3 13 : : PUNCT eurjchem-154 3 14     SPACE eurjchem-154 3 15 tarik_elsayed1975@yahoo.com tarik_elsayed1975@yahoo.com X eurjchem-154 3 16     SPACE eurjchem-154 3 17 ( ( PUNCT eurjchem-154 3 18 t.e t.e PROPN eurjchem-154 3 19 . . PROPN eurjchem-154 3 20     SPACE eurjchem-154 3 21 ali ali PROPN eurjchem-154 3 22 ) ) PUNCT eurjchem-154 3 23 . . PUNCT eurjchem-154 3 24                                 SPACE eurjchem-154 4 1 review review NOUN eurjchem-154 4 2     SPACE eurjchem-154 4 3 information information NOUN eurjchem-154 4 4         SPACE eurjchem-154 4 5 abstract abstract ADJ eurjchem-154 4 6 received receive VERB eurjchem-154 4 7 : : PUNCT eurjchem-154 4 8     SPACE eurjchem-154 4 9 06 06 NUM eurjchem-154 4 10     SPACE eurjchem-154 4 11 june june PROPN eurjchem-154 4 12     SPACE eurjchem-154 4 13 2010 2010 NUM eurjchem-154 4 14     SPACE eurjchem-154 4 15 received receive VERB eurjchem-154 4 16     SPACE eurjchem-154 4 17 in in ADP eurjchem-154 4 18     SPACE eurjchem-154 4 19 revised revise VERB eurjchem-154 4 20     SPACE eurjchem-154 4 21 form form NOUN eurjchem-154 4 22 : : PUNCT eurjchem-154 4 23     SPACE eurjchem-154 4 24 11 11 NUM eurjchem-154 4 25     SPACE eurjchem-154 4 26 august august PROPN eurjchem-154 4 27     SPACE eurjchem-154 4 28 2010 2010 NUM eurjchem-154 4 29     SPACE eurjchem-154 4 30 accepted accept VERB eurjchem-154 4 31 : : PUNCT eurjchem-154 4 32     SPACE eurjchem-154 4 33 14 14 NUM eurjchem-154 4 34     SPACE eurjchem-154 4 35 august august PROPN eurjchem-154 4 36     SPACE eurjchem-154 4 37 2010 2010 NUM eurjchem-154 4 38     SPACE eurjchem-154 4 39 online online NOUN eurjchem-154 4 40 : : PUNCT eurjchem-154 4 41     SPACE eurjchem-154 4 42 31 31 NUM eurjchem-154 4 43     SPACE eurjchem-154 4 44 december december PROPN eurjchem-154 4 45     SPACE eurjchem-154 4 46 2010 2010 NUM eurjchem-154 4 47     SPACE eurjchem-154 4 48 keywords keyword VERB eurjchem-154 4 49         SPACE eurjchem-154 4 50 this this DET eurjchem-154 4 51     SPACE eurjchem-154 4 52 review review NOUN eurjchem-154 4 53     SPACE eurjchem-154 4 54 represents represent VERB eurjchem-154 4 55     SPACE eurjchem-154 4 56 the the DET eurjchem-154 4 57     SPACE eurjchem-154 4 58 methods method NOUN eurjchem-154 4 59     SPACE eurjchem-154 4 60 developed develop VERB eurjchem-154 4 61     SPACE eurjchem-154 4 62 for for ADP eurjchem-154 4 63     SPACE eurjchem-154 4 64 the the DET eurjchem-154 4 65     SPACE eurjchem-154 4 66 synthesis synthesis NOUN eurjchem-154 4 67     SPACE eurjchem-154 4 68 of of ADP eurjchem-154 4 69     SPACE eurjchem-154 4 70 phosphorus phosphorus NOUN eurjchem-154 4 71     SPACE eurjchem-154 4 72 containing contain VERB eurjchem-154 4 73     SPACE eurjchem-154 4 74 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 4 75     SPACE eurjchem-154 4 76 moieties moiety NOUN eurjchem-154 4 77 . . PUNCT eurjchem-154 4 78     SPACE eurjchem-154 4 79 these these DET eurjchem-154 4 80     SPACE eurjchem-154 4 81 methods method NOUN eurjchem-154 4 82     SPACE eurjchem-154 4 83 depends depend VERB eurjchem-154 4 84     SPACE eurjchem-154 4 85 on on ADP eurjchem-154 4 86     SPACE eurjchem-154 4 87 the the DET eurjchem-154 4 88     SPACE eurjchem-154 4 89 phosphorylation phosphorylation NOUN eurjchem-154 4 90     SPACE eurjchem-154 4 91 of of ADP eurjchem-154 4 92     SPACE eurjchem-154 4 93 side side NOUN eurjchem-154 4 94     SPACE eurjchem-154 4 95 functional functional ADJ eurjchem-154 4 96     SPACE eurjchem-154 4 97 groups group NOUN eurjchem-154 4 98     SPACE eurjchem-154 4 99 of of ADP eurjchem-154 4 100     SPACE eurjchem-154 4 101 1,2,4‐triazines 1,2,4‐triazine NOUN eurjchem-154 4 102     SPACE eurjchem-154 4 103 and and CCONJ eurjchem-154 4 104     SPACE eurjchem-154 4 105 cyclization cyclization NOUN eurjchem-154 4 106     SPACE eurjchem-154 4 107 of of ADP eurjchem-154 4 108     SPACE eurjchem-154 4 109 side side NOUN eurjchem-154 4 110     SPACE eurjchem-154 4 111 functional functional ADJ eurjchem-154 4 112     SPACE eurjchem-154 4 113 groups group NOUN eurjchem-154 4 114     SPACE eurjchem-154 4 115 of of ADP eurjchem-154 4 116     SPACE eurjchem-154 4 117 1,2,4‐triazines 1,2,4‐triazine NOUN eurjchem-154 4 118     SPACE eurjchem-154 4 119 with with ADP eurjchem-154 4 120     SPACE eurjchem-154 4 121 phosphorus phosphorus NOUN eurjchem-154 4 122     SPACE eurjchem-154 4 123 reagents reagent NOUN eurjchem-154 4 124     SPACE eurjchem-154 4 125 to to PART eurjchem-154 4 126     SPACE eurjchem-154 4 127 give give VERB eurjchem-154 4 128     SPACE eurjchem-154 4 129 isolated isolate VERB eurjchem-154 4 130     SPACE eurjchem-154 4 131 and and CCONJ eurjchem-154 4 132     SPACE eurjchem-154 4 133 fused fuse VERB eurjchem-154 4 134     SPACE eurjchem-154 4 135 phosphorus phosphorus NOUN eurjchem-154 4 136     SPACE eurjchem-154 4 137 heterocyclic heterocyclic NOUN eurjchem-154 4 138     SPACE eurjchem-154 4 139 systems system NOUN eurjchem-154 4 140 . . PUNCT eurjchem-154 4 141     SPACE eurjchem-154 4 142 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 4 143       SPACE eurjchem-154 4 144 phosphorus phosphorus NOUN eurjchem-154 4 145       SPACE eurjchem-154 4 146 phosphorylation phosphorylation NOUN eurjchem-154 4 147     SPACE eurjchem-154 4 148 cyclization cyclization NOUN eurjchem-154 4 149       SPACE eurjchem-154 4 150 heterocyclization heterocyclization NOUN eurjchem-154 4 151         SPACE eurjchem-154 4 152 1 1 NUM eurjchem-154 4 153 . . PUNCT eurjchem-154 4 154     SPACE eurjchem-154 4 155 introduction introduction NOUN eurjchem-154 4 156         SPACE eurjchem-154 4 157 various various ADJ eurjchem-154 4 158     SPACE eurjchem-154 4 159 substituted substitute VERB eurjchem-154 4 160     SPACE eurjchem-154 4 161 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 4 162     SPACE eurjchem-154 4 163 derivatives derivative NOUN eurjchem-154 4 164     SPACE eurjchem-154 4 165 have have VERB eurjchem-154 4 166     SPACE eurjchem-154 4 167 a a DET eurjchem-154 4 168     SPACE eurjchem-154 4 169 great great ADJ eurjchem-154 4 170     SPACE eurjchem-154 4 171 importance importance NOUN eurjchem-154 4 172     SPACE eurjchem-154 4 173 as as ADP eurjchem-154 4 174     SPACE eurjchem-154 4 175 biological biological ADJ eurjchem-154 4 176     SPACE eurjchem-154 4 177 agents agent NOUN eurjchem-154 4 178     SPACE eurjchem-154 4 179 in in ADP eurjchem-154 4 180     SPACE eurjchem-154 4 181 medicinal medicinal ADJ eurjchem-154 4 182     SPACE eurjchem-154 4 183 and and CCONJ eurjchem-154 4 184     SPACE eurjchem-154 4 185 agricultural agricultural ADJ eurjchem-154 4 186     SPACE eurjchem-154 4 187 fields field NOUN eurjchem-154 4 188     SPACE eurjchem-154 5 1 [ [ X eurjchem-154 5 2 1–6 1–6 NUM eurjchem-154 5 3 ] ] X eurjchem-154 5 4 . . PUNCT eurjchem-154 5 5     SPACE eurjchem-154 5 6 recently recently ADV eurjchem-154 5 7 , , PUNCT eurjchem-154 5 8     SPACE eurjchem-154 5 9 this this DET eurjchem-154 5 10     SPACE eurjchem-154 5 11 class class NOUN eurjchem-154 5 12     SPACE eurjchem-154 5 13 of of ADP eurjchem-154 5 14     SPACE eurjchem-154 5 15 compounds compound NOUN eurjchem-154 5 16     SPACE eurjchem-154 5 17 have have AUX eurjchem-154 5 18     SPACE eurjchem-154 5 19 gained gain VERB eurjchem-154 5 20     SPACE eurjchem-154 5 21 considerable considerable ADJ eurjchem-154 5 22     SPACE eurjchem-154 5 23 interest interest NOUN eurjchem-154 5 24     SPACE eurjchem-154 5 25 because because SCONJ eurjchem-154 5 26     SPACE eurjchem-154 5 27 of of ADP eurjchem-154 5 28     SPACE eurjchem-154 5 29 their their PRON eurjchem-154 5 30     SPACE eurjchem-154 5 31 herbicidal herbicidal NOUN eurjchem-154 5 32     SPACE eurjchem-154 6 1 [ [ X eurjchem-154 6 2 7,8 7,8 NUM eurjchem-154 6 3 ] ] PUNCT eurjchem-154 6 4 , , PUNCT eurjchem-154 6 5     SPACE eurjchem-154 6 6 antimicrobial antimicrobial ADJ eurjchem-154 6 7     SPACE eurjchem-154 7 1 [ [ X eurjchem-154 7 2 9‐11 9‐11 NUM eurjchem-154 7 3 ] ] X eurjchem-154 7 4 , , PUNCT eurjchem-154 7 5     SPACE eurjchem-154 7 6 anti‐hiv anti‐hiv PROPN eurjchem-154 7 7     SPACE eurjchem-154 7 8 [ [ X eurjchem-154 7 9 12 12 NUM eurjchem-154 7 10 ] ] PUNCT eurjchem-154 7 11     SPACE eurjchem-154 7 12 and and CCONJ eurjchem-154 7 13     SPACE eurjchem-154 7 14 anticancer anticancer NOUN eurjchem-154 7 15     SPACE eurjchem-154 7 16 activities activity NOUN eurjchem-154 7 17     SPACE eurjchem-154 8 1 [ [ X eurjchem-154 8 2 13,14 13,14 NUM eurjchem-154 8 3 ] ] PUNCT eurjchem-154 8 4 . . PUNCT eurjchem-154 8 5     SPACE eurjchem-154 8 6 on on ADP eurjchem-154 8 7     SPACE eurjchem-154 8 8 the the DET eurjchem-154 8 9     SPACE eurjchem-154 8 10 other other ADJ eurjchem-154 8 11     SPACE eurjchem-154 8 12 hand hand NOUN eurjchem-154 8 13 , , PUNCT eurjchem-154 8 14     SPACE eurjchem-154 8 15 the the DET eurjchem-154 8 16     SPACE eurjchem-154 8 17 high high ADJ eurjchem-154 8 18     SPACE eurjchem-154 8 19 biological biological ADJ eurjchem-154 8 20     SPACE eurjchem-154 8 21 activity activity NOUN eurjchem-154 8 22     SPACE eurjchem-154 8 23 of of ADP eurjchem-154 8 24     SPACE eurjchem-154 8 25 organophosphorus organophosphorus NOUN eurjchem-154 8 26     SPACE eurjchem-154 8 27 compounds compound NOUN eurjchem-154 8 28 , , PUNCT eurjchem-154 8 29     SPACE eurjchem-154 8 30 such such ADJ eurjchem-154 8 31     SPACE eurjchem-154 8 32 as as ADV eurjchem-154 8 33     SPACE eurjchem-154 8 34 highly highly ADV eurjchem-154 8 35     SPACE eurjchem-154 8 36 active active ADJ eurjchem-154 8 37     SPACE eurjchem-154 8 38 anti‐tmv anti‐tmv ADJ eurjchem-154 8 39     SPACE eurjchem-154 8 40 activity activity NOUN eurjchem-154 8 41     SPACE eurjchem-154 8 42 [ [ X eurjchem-154 8 43 15 15 NUM eurjchem-154 8 44 ] ] PUNCT eurjchem-154 8 45 , , PUNCT eurjchem-154 8 46     SPACE eurjchem-154 8 47 herbicides herbicide NOUN eurjchem-154 8 48     SPACE eurjchem-154 8 49 [ [ X eurjchem-154 8 50 16,17 16,17 NUM eurjchem-154 8 51 ] ] PUNCT eurjchem-154 8 52 , , PUNCT eurjchem-154 8 53     SPACE eurjchem-154 8 54 insecticides insecticide NOUN eurjchem-154 8 55     SPACE eurjchem-154 9 1 [ [ X eurjchem-154 9 2 18,19 18,19 NUM eurjchem-154 9 3 ] ] X eurjchem-154 9 4 , , PUNCT eurjchem-154 9 5     SPACE eurjchem-154 9 6 antitumor antitumor PROPN eurjchem-154 9 7     SPACE eurjchem-154 9 8 [ [ X eurjchem-154 9 9 20 20 NUM eurjchem-154 9 10 ] ] SYM eurjchem-154 9 11     SPACE eurjchem-154 9 12 and and CCONJ eurjchem-154 9 13     SPACE eurjchem-154 9 14 war war NOUN eurjchem-154 9 15     SPACE eurjchem-154 9 16 gases gas NOUN eurjchem-154 9 17 , , PUNCT eurjchem-154 9 18     SPACE eurjchem-154 9 19 is be AUX eurjchem-154 9 20     SPACE eurjchem-154 9 21 well well ADV eurjchem-154 9 22     SPACE eurjchem-154 9 23 known know VERB eurjchem-154 9 24 . . PUNCT eurjchem-154 10 1 our our PRON eurjchem-154 10 2     SPACE eurjchem-154 10 3 last last ADJ eurjchem-154 10 4     SPACE eurjchem-154 10 5 review review NOUN eurjchem-154 10 6     SPACE eurjchem-154 11 1 [ [ X eurjchem-154 11 2 21 21 NUM eurjchem-154 11 3 ] ] PUNCT eurjchem-154 11 4     SPACE eurjchem-154 11 5 has have AUX eurjchem-154 11 6     SPACE eurjchem-154 11 7 been be AUX eurjchem-154 11 8     SPACE eurjchem-154 11 9 useful useful ADJ eurjchem-154 11 10     SPACE eurjchem-154 11 11 for for SCONJ eurjchem-154 11 12     SPACE eurjchem-154 11 13 the the DET eurjchem-154 11 14     SPACE eurjchem-154 11 15 chemists chemist NOUN eurjchem-154 11 16     SPACE eurjchem-154 11 17 engaged engage VERB eurjchem-154 11 18     SPACE eurjchem-154 11 19 in in ADP eurjchem-154 11 20     SPACE eurjchem-154 11 21 the the DET eurjchem-154 11 22     SPACE eurjchem-154 11 23 development development NOUN eurjchem-154 11 24     SPACE eurjchem-154 11 25 of of ADP eurjchem-154 11 26     SPACE eurjchem-154 11 27 synthesis synthesis NOUN eurjchem-154 11 28     SPACE eurjchem-154 11 29 and and CCONJ eurjchem-154 11 30     SPACE eurjchem-154 11 31 chemistry chemistry NOUN eurjchem-154 11 32     SPACE eurjchem-154 11 33 of of ADP eurjchem-154 11 34     SPACE eurjchem-154 11 35 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 11 36     SPACE eurjchem-154 11 37 systems system NOUN eurjchem-154 11 38 . . PUNCT eurjchem-154 11 39     SPACE eurjchem-154 12 1 the the DET eurjchem-154 12 2     SPACE eurjchem-154 12 3 intention intention NOUN eurjchem-154 12 4     SPACE eurjchem-154 12 5 of of ADP eurjchem-154 12 6     SPACE eurjchem-154 12 7 the the DET eurjchem-154 12 8     SPACE eurjchem-154 12 9 present present ADJ eurjchem-154 12 10     SPACE eurjchem-154 12 11 review review NOUN eurjchem-154 12 12     SPACE eurjchem-154 12 13 is be AUX eurjchem-154 12 14     SPACE eurjchem-154 12 15 to to PART eurjchem-154 12 16     SPACE eurjchem-154 12 17 cover cover VERB eurjchem-154 12 18     SPACE eurjchem-154 12 19 all all DET eurjchem-154 12 20     SPACE eurjchem-154 12 21 the the DET eurjchem-154 12 22     SPACE eurjchem-154 12 23 literature literature NOUN eurjchem-154 12 24     SPACE eurjchem-154 12 25 methods method NOUN eurjchem-154 12 26     SPACE eurjchem-154 12 27 developed develop VERB eurjchem-154 12 28     SPACE eurjchem-154 12 29 for for ADP eurjchem-154 12 30     SPACE eurjchem-154 12 31 the the DET eurjchem-154 12 32     SPACE eurjchem-154 12 33 synthesis synthesis NOUN eurjchem-154 12 34     SPACE eurjchem-154 12 35 of of ADP eurjchem-154 12 36     SPACE eurjchem-154 12 37 phosphorus phosphorus NOUN eurjchem-154 12 38     SPACE eurjchem-154 12 39 containing contain VERB eurjchem-154 12 40     SPACE eurjchem-154 12 41 1,2,4‐ 1,2,4‐ NUM eurjchem-154 12 42 triazine triazine NOUN eurjchem-154 12 43     SPACE eurjchem-154 12 44 moieties moiety NOUN eurjchem-154 12 45     SPACE eurjchem-154 12 46 starting start VERB eurjchem-154 12 47     SPACE eurjchem-154 12 48 from from ADP eurjchem-154 12 49     SPACE eurjchem-154 12 50 their their PRON eurjchem-154 12 51     SPACE eurjchem-154 12 52 appearance appearance NOUN eurjchem-154 12 53     SPACE eurjchem-154 12 54 up up ADV eurjchem-154 12 55     SPACE eurjchem-154 12 56 to to ADP eurjchem-154 12 57     SPACE eurjchem-154 12 58 the the DET eurjchem-154 12 59     SPACE eurjchem-154 12 60 2010 2010 NUM eurjchem-154 12 61 . . PUNCT eurjchem-154 12 62     SPACE eurjchem-154 13 1 although although SCONJ eurjchem-154 13 2     SPACE eurjchem-154 13 3 the the DET eurjchem-154 13 4     SPACE eurjchem-154 13 5 literature literature NOUN eurjchem-154 13 6     SPACE eurjchem-154 13 7 data datum NOUN eurjchem-154 13 8     SPACE eurjchem-154 13 9 for for ADP eurjchem-154 13 10     SPACE eurjchem-154 13 11 the the DET eurjchem-154 13 12     SPACE eurjchem-154 13 13 synthesis synthesis NOUN eurjchem-154 13 14     SPACE eurjchem-154 13 15 of of ADP eurjchem-154 13 16     SPACE eurjchem-154 13 17 phosphorus phosphorus NOUN eurjchem-154 13 18     SPACE eurjchem-154 13 19 containing contain VERB eurjchem-154 13 20     SPACE eurjchem-154 13 21 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 13 22     SPACE eurjchem-154 13 23 moieties moiety NOUN eurjchem-154 13 24     SPACE eurjchem-154 13 25 are be AUX eurjchem-154 13 26     SPACE eurjchem-154 13 27 few few ADJ eurjchem-154 13 28 , , PUNCT eurjchem-154 13 29     SPACE eurjchem-154 13 30 the the DET eurjchem-154 13 31     SPACE eurjchem-154 13 32 described describe VERB eurjchem-154 13 33     SPACE eurjchem-154 13 34 methods method NOUN eurjchem-154 13 35     SPACE eurjchem-154 13 36 can can AUX eurjchem-154 13 37     SPACE eurjchem-154 13 38 be be AUX eurjchem-154 13 39     SPACE eurjchem-154 13 40 divided divide VERB eurjchem-154 13 41     SPACE eurjchem-154 13 42 into into ADP eurjchem-154 13 43     SPACE eurjchem-154 13 44 three three NUM eurjchem-154 13 45     SPACE eurjchem-154 13 46 routes route NOUN eurjchem-154 13 47 : : PUNCT eurjchem-154 13 48     SPACE eurjchem-154 13 49 phosphorylation phosphorylation NOUN eurjchem-154 13 50     SPACE eurjchem-154 13 51 of of ADP eurjchem-154 13 52     SPACE eurjchem-154 13 53 1,2,4‐triazine 1,2,4‐triazine NOUN eurjchem-154 13 54     SPACE eurjchem-154 13 55 at at ADP eurjchem-154 13 56     SPACE eurjchem-154 13 57 position position NOUN eurjchem-154 13 58     SPACE eurjchem-154 13 59 3 3 NUM eurjchem-154 13 60     SPACE eurjchem-154 13 61 or or CCONJ eurjchem-154 13 62     SPACE eurjchem-154 13 63 its its PRON eurjchem-154 13 64     SPACE eurjchem-154 13 65 side side NOUN eurjchem-154 13 66     SPACE eurjchem-154 13 67 functional functional ADJ eurjchem-154 13 68     SPACE eurjchem-154 13 69 groups group NOUN eurjchem-154 13 70     SPACE eurjchem-154 13 71 at at ADP eurjchem-154 13 72     SPACE eurjchem-154 13 73 this this DET eurjchem-154 13 74     SPACE eurjchem-154 13 75 position position NOUN eurjchem-154 13 76     SPACE eurjchem-154 13 77 and and CCONJ eurjchem-154 13 78     SPACE eurjchem-154 13 79 cyclization cyclization NOUN eurjchem-154 13 80     SPACE eurjchem-154 13 81 of of ADP eurjchem-154 13 82     SPACE eurjchem-154 13 83 side side NOUN eurjchem-154 13 84     SPACE eurjchem-154 13 85 functional functional ADJ eurjchem-154 13 86     SPACE eurjchem-154 13 87 groups group NOUN eurjchem-154 13 88     SPACE eurjchem-154 13 89 of of ADP eurjchem-154 13 90     SPACE eurjchem-154 13 91 1,2,4‐ 1,2,4‐ NUM eurjchem-154 13 92 triazines triazine NOUN eurjchem-154 13 93     SPACE eurjchem-154 13 94 with with ADP eurjchem-154 13 95     SPACE eurjchem-154 13 96 phosphorus phosphorus NOUN eurjchem-154 13 97     SPACE eurjchem-154 13 98 reagents reagent NOUN eurjchem-154 13 99     SPACE eurjchem-154 13 100 to to PART eurjchem-154 13 101     SPACE eurjchem-154 13 102 give give VERB eurjchem-154 13 103     SPACE eurjchem-154 13 104 isolated isolate VERB eurjchem-154 13 105     SPACE eurjchem-154 13 106 and and CCONJ eurjchem-154 13 107     SPACE eurjchem-154 13 108 fused fuse VERB eurjchem-154 13 109     SPACE eurjchem-154 13 110 phosphorus phosphorus NOUN eurjchem-154 13 111     SPACE eurjchem-154 13 112 heterocyclic heterocyclic NOUN eurjchem-154 13 113     SPACE eurjchem-154 13 114 systems system NOUN eurjchem-154 13 115 . . PUNCT eurjchem-154 13 116     SPACE eurjchem-154 14 1 it it PRON eurjchem-154 14 2     SPACE eurjchem-154 14 3 is be AUX eurjchem-154 14 4     SPACE eurjchem-154 14 5 hoped hope VERB eurjchem-154 14 6     SPACE eurjchem-154 14 7 that that SCONJ eurjchem-154 14 8     SPACE eurjchem-154 14 9 this this DET eurjchem-154 14 10     SPACE eurjchem-154 14 11 review review NOUN eurjchem-154 14 12     SPACE eurjchem-154 14 13 will will AUX eurjchem-154 14 14     SPACE eurjchem-154 14 15 demonstrate demonstrate VERB eurjchem-154 14 16     SPACE eurjchem-154 14 17 the the DET eurjchem-154 14 18     SPACE eurjchem-154 14 19 synthetic synthetic ADJ eurjchem-154 14 20     SPACE eurjchem-154 14 21 potential potential NOUN eurjchem-154 14 22     SPACE eurjchem-154 14 23 of of ADP eurjchem-154 14 24     SPACE eurjchem-154 14 25 the the DET eurjchem-154 14 26     SPACE eurjchem-154 14 27 synthesis synthesis NOUN eurjchem-154 14 28     SPACE eurjchem-154 14 29 of of ADP eurjchem-154 14 30     SPACE eurjchem-154 14 31 phosphorus phosphorus NOUN eurjchem-154 14 32     SPACE eurjchem-154 14 33 containing contain VERB eurjchem-154 14 34     SPACE eurjchem-154 14 35 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 14 36     SPACE eurjchem-154 14 37 moieties moiety NOUN eurjchem-154 14 38     SPACE eurjchem-154 14 39 and and CCONJ eurjchem-154 14 40     SPACE eurjchem-154 14 41 generate generate VERB eurjchem-154 14 42     SPACE eurjchem-154 14 43 some some DET eurjchem-154 14 44     SPACE eurjchem-154 14 45 new new ADJ eurjchem-154 14 46     SPACE eurjchem-154 14 47 ideas idea NOUN eurjchem-154 14 48     SPACE eurjchem-154 14 49 in in ADP eurjchem-154 14 50     SPACE eurjchem-154 14 51 this this DET eurjchem-154 14 52     SPACE eurjchem-154 14 53 area area NOUN eurjchem-154 14 54 . . PUNCT eurjchem-154 14 55         SPACE eurjchem-154 15 1 2 2 NUM eurjchem-154 15 2 . . PUNCT eurjchem-154 15 3     SPACE eurjchem-154 15 4 synthetic synthetic ADJ eurjchem-154 15 5     SPACE eurjchem-154 15 6 approaches approach NOUN eurjchem-154 15 7         SPACE eurjchem-154 15 8 2.1 2.1 NUM eurjchem-154 15 9 . . PUNCT eurjchem-154 15 10     SPACE eurjchem-154 15 11 phosphorylation phosphorylation NOUN eurjchem-154 15 12     SPACE eurjchem-154 15 13 of of ADP eurjchem-154 15 14     SPACE eurjchem-154 15 15 1,2,4­triazines 1,2,4­triazine NOUN eurjchem-154 15 16         SPACE eurjchem-154 15 17 2.1.1 2.1.1 NUM eurjchem-154 15 18 . . PUNCT eurjchem-154 15 19     SPACE eurjchem-154 15 20 phosphorylation phosphorylation NOUN eurjchem-154 15 21     SPACE eurjchem-154 15 22 of of ADP eurjchem-154 15 23     SPACE eurjchem-154 15 24 1,2,4­triazine 1,2,4­triazine NOUN eurjchem-154 15 25     SPACE eurjchem-154 15 26 at at ADP eurjchem-154 15 27     SPACE eurjchem-154 15 28 position position NOUN eurjchem-154 15 29     SPACE eurjchem-154 15 30 3 3 NUM eurjchem-154 15 31         SPACE eurjchem-154 15 32 treatment treatment NOUN eurjchem-154 15 33     SPACE eurjchem-154 15 34 of of ADP eurjchem-154 15 35     SPACE eurjchem-154 15 36 3‐chloro‐5,6‐diphenyl‐1,2,4‐triazine 3‐chloro‐5,6‐diphenyl‐1,2,4‐triazine NOUN eurjchem-154 15 37     SPACE eurjchem-154 15 38 ( ( PUNCT eurjchem-154 15 39 1 1 NUM eurjchem-154 15 40 ) ) PUNCT eurjchem-154 15 41     SPACE eurjchem-154 15 42 with with ADP eurjchem-154 15 43     SPACE eurjchem-154 15 44 trimethyl trimethyl PRON eurjchem-154 15 45     SPACE eurjchem-154 15 46 phosphite phosphite NOUN eurjchem-154 15 47     SPACE eurjchem-154 15 48 yielded yield VERB eurjchem-154 15 49     SPACE eurjchem-154 15 50 1,2,4‐triazinyldimethylphos 1,2,4‐triazinyldimethylphos NUM eurjchem-154 15 51     SPACE eurjchem-154 15 52 phonate phonate ADJ eurjchem-154 15 53     SPACE eurjchem-154 15 54 3 3 NUM eurjchem-154 15 55 , , PUNCT eurjchem-154 15 56     SPACE eurjchem-154 15 57 via via ADP eurjchem-154 15 58     SPACE eurjchem-154 15 59 arbuzov arbuzov NOUN eurjchem-154 15 60     SPACE eurjchem-154 15 61 reaction reaction NOUN eurjchem-154 15 62     SPACE eurjchem-154 15 63 through through ADP eurjchem-154 15 64     SPACE eurjchem-154 15 65 the the DET eurjchem-154 15 66     SPACE eurjchem-154 15 67 nonisolable nonisolable ADJ eurjchem-154 15 68     SPACE eurjchem-154 15 69 intermediate intermediate ADJ eurjchem-154 15 70     SPACE eurjchem-154 15 71 2 2 NUM eurjchem-154 15 72     SPACE eurjchem-154 15 73 ( ( PUNCT eurjchem-154 15 74 scheme scheme NOUN eurjchem-154 15 75     SPACE eurjchem-154 15 76 1 1 NUM eurjchem-154 15 77 ) ) PUNCT eurjchem-154 15 78     SPACE eurjchem-154 16 1 [ [ X eurjchem-154 16 2 22 22 NUM eurjchem-154 16 3 ] ] PUNCT eurjchem-154 16 4 . . PUNCT eurjchem-154 16 5         SPACE eurjchem-154 16 6 scheme scheme NOUN eurjchem-154 16 7     SPACE eurjchem-154 16 8 1 1 NUM eurjchem-154 16 9         SPACE eurjchem-154 16 10 when when SCONJ eurjchem-154 16 11     SPACE eurjchem-154 16 12 3‐chloro‐5,6‐disubstituted‐1,2,4‐triazines 3‐chloro‐5,6‐disubstituted‐1,2,4‐triazine NOUN eurjchem-154 16 13     SPACE eurjchem-154 16 14 ( ( PUNCT eurjchem-154 16 15 1 1 NUM eurjchem-154 16 16 ) ) PUNCT eurjchem-154 16 17     SPACE eurjchem-154 16 18 were be AUX eurjchem-154 16 19     SPACE eurjchem-154 16 20 treated treat VERB eurjchem-154 16 21     SPACE eurjchem-154 16 22 with with ADP eurjchem-154 16 23     SPACE eurjchem-154 16 24 diethylcyanomethyl diethylcyanomethyl NOUN eurjchem-154 16 25     SPACE eurjchem-154 16 26 phosphonate phosphonate NOUN eurjchem-154 16 27     SPACE eurjchem-154 16 28 ( ( PUNCT eurjchem-154 16 29 three three NUM eurjchem-154 16 30     SPACE eurjchem-154 16 31 equivalents equivalent NOUN eurjchem-154 16 32 ) ) PUNCT eurjchem-154 16 33     SPACE eurjchem-154 16 34 in in ADP eurjchem-154 16 35     SPACE eurjchem-154 16 36 refluxing refluxing NOUN eurjchem-154 16 37     SPACE eurjchem-154 16 38 dimethylformamide dimethylformamide NOUN eurjchem-154 16 39     SPACE eurjchem-154 16 40 containing contain VERB eurjchem-154 16 41     SPACE eurjchem-154 16 42 excess excess ADJ eurjchem-154 16 43     SPACE eurjchem-154 16 44 lithium lithium NOUN eurjchem-154 16 45     SPACE eurjchem-154 16 46 hydride hydride NOUN eurjchem-154 16 47     SPACE eurjchem-154 16 48 gave give VERB eurjchem-154 16 49     SPACE eurjchem-154 16 50 the the DET eurjchem-154 16 51     SPACE eurjchem-154 16 52 corresponding corresponding ADJ eurjchem-154 16 53     SPACE eurjchem-154 16 54 diethyl diethyl NOUN eurjchem-154 16 55     SPACE eurjchem-154 16 56 3‐cyanomethyl 3‐cyanomethyl ADJ eurjchem-154 16 57     SPACE eurjchem-154 16 58 phosphonates phosphonate NOUN eurjchem-154 16 59     SPACE eurjchem-154 16 60 ( ( PUNCT eurjchem-154 16 61 4 4 NUM eurjchem-154 16 62 ) ) PUNCT eurjchem-154 16 63     SPACE eurjchem-154 16 64 as as ADP eurjchem-154 16 65     SPACE eurjchem-154 16 66 the the DET eurjchem-154 16 67     SPACE eurjchem-154 16 68 sole sole ADJ eurjchem-154 16 69     SPACE eurjchem-154 16 70 reaction reaction NOUN eurjchem-154 16 71     SPACE eurjchem-154 16 72 product product NOUN eurjchem-154 16 73     SPACE eurjchem-154 16 74 ( ( PUNCT eurjchem-154 16 75 scheme scheme NOUN eurjchem-154 16 76     SPACE eurjchem-154 16 77 2 2 NUM eurjchem-154 16 78 ) ) PUNCT eurjchem-154 16 79 . . PUNCT eurjchem-154 16 80     SPACE eurjchem-154 17 1 structure structure NOUN eurjchem-154 17 2     SPACE eurjchem-154 17 3 4 4 NUM eurjchem-154 17 4     SPACE eurjchem-154 17 5 was be AUX eurjchem-154 17 6     SPACE eurjchem-154 17 7 found find VERB eurjchem-154 17 8     SPACE eurjchem-154 17 9 to to PART eurjchem-154 17 10     SPACE eurjchem-154 17 11 be be AUX eurjchem-154 17 12     SPACE eurjchem-154 17 13 present present ADJ eurjchem-154 17 14     SPACE eurjchem-154 17 15 in in ADP eurjchem-154 17 16     SPACE eurjchem-154 17 17 two two NUM eurjchem-154 17 18     SPACE eurjchem-154 17 19 tautomeric tautomeric ADJ eurjchem-154 17 20     SPACE eurjchem-154 17 21 isomers isomer NOUN eurjchem-154 17 22     SPACE eurjchem-154 17 23 4a 4a NOUN eurjchem-154 17 24     SPACE eurjchem-154 17 25 and and CCONJ eurjchem-154 17 26     SPACE eurjchem-154 17 27 4b 4b NOUN eurjchem-154 17 28     SPACE eurjchem-154 17 29 as as SCONJ eurjchem-154 17 30     SPACE eurjchem-154 17 31 indicated indicate VERB eurjchem-154 17 32     SPACE eurjchem-154 17 33 by by ADP eurjchem-154 17 34     SPACE eurjchem-154 17 35 the the DET eurjchem-154 17 36     SPACE eurjchem-154 17 37 nmr nmr NOUN eurjchem-154 17 38     SPACE eurjchem-154 17 39 spectra spectra NOUN eurjchem-154 17 40 . . PUNCT eurjchem-154 17 41     SPACE eurjchem-154 17 42 however however ADV eurjchem-154 17 43 , , PUNCT eurjchem-154 17 44     SPACE eurjchem-154 17 45 the the DET eurjchem-154 17 46     SPACE eurjchem-154 17 47 weak weak ADJ eurjchem-154 17 48     SPACE eurjchem-154 17 49 signals signal NOUN eurjchem-154 17 50     SPACE eurjchem-154 17 51 for for ADP eurjchem-154 17 52     SPACE eurjchem-154 17 53 the the DET eurjchem-154 17 54     SPACE eurjchem-154 17 55 nh nh NOUN eurjchem-154 17 56     SPACE eurjchem-154 17 57 in in ADP eurjchem-154 17 58     SPACE eurjchem-154 17 59 the the DET eurjchem-154 17 60     SPACE eurjchem-154 17 61 1h 1h NUM eurjchem-154 17 62     SPACE eurjchem-154 17 63 nmr nmr NOUN eurjchem-154 17 64     SPACE eurjchem-154 17 65 and and CCONJ eurjchem-154 17 66     SPACE eurjchem-154 17 67 ir ir PROPN eurjchem-154 17 68     SPACE eurjchem-154 17 69 spectra spectra NOUN eurjchem-154 17 70     SPACE eurjchem-154 17 71 indicated indicate VERB eurjchem-154 17 72     SPACE eurjchem-154 17 73 that that SCONJ eurjchem-154 17 74     SPACE eurjchem-154 17 75 4a 4a NOUN eurjchem-154 17 76     SPACE eurjchem-154 17 77 was be AUX eurjchem-154 17 78     SPACE eurjchem-154 17 79 the the DET eurjchem-154 17 80     SPACE eurjchem-154 17 81 predominant predominant ADJ eurjchem-154 17 82     SPACE eurjchem-154 17 83 tautomer tautomer NOUN eurjchem-154 17 84 . . PUNCT eurjchem-154 17 85     SPACE eurjchem-154 17 86 when when SCONJ eurjchem-154 17 87     SPACE eurjchem-154 17 88 phosphonate phosphonate VERB eurjchem-154 17 89     SPACE eurjchem-154 17 90 4 4 NUM eurjchem-154 17 91     SPACE eurjchem-154 17 92 was be AUX eurjchem-154 17 93     SPACE eurjchem-154 17 94 treated treat VERB eurjchem-154 17 95     SPACE eurjchem-154 17 96 with with ADP eurjchem-154 17 97     SPACE eurjchem-154 17 98 one one NUM eurjchem-154 17 99     SPACE eurjchem-154 17 100 equivalent equivalent NOUN eurjchem-154 17 101     SPACE eurjchem-154 17 102 of of ADP eurjchem-154 17 103     SPACE eurjchem-154 17 104 dimethyl dimethyl NOUN eurjchem-154 17 105     SPACE eurjchem-154 17 106 phosphonate phosphonate NOUN eurjchem-154 17 107 , , PUNCT eurjchem-154 17 108     SPACE eurjchem-154 17 109 the the DET eurjchem-154 17 110     SPACE eurjchem-154 17 111 reaction reaction NOUN eurjchem-154 17 112     SPACE eurjchem-154 17 113 was be AUX eurjchem-154 17 114     SPACE eurjchem-154 17 115 completed complete VERB eurjchem-154 17 116     SPACE eurjchem-154 17 117 by by ADP eurjchem-154 17 118     SPACE eurjchem-154 17 119 boiling boil VERB eurjchem-154 17 120     SPACE eurjchem-154 17 121 the the DET eurjchem-154 17 122     SPACE eurjchem-154 17 123 reactants reactant NOUN eurjchem-154 17 124     SPACE eurjchem-154 17 125 in in ADP eurjchem-154 17 126     SPACE eurjchem-154 17 127 toluene toluene NOUN eurjchem-154 17 128     SPACE eurjchem-154 17 129 containing contain VERB eurjchem-154 17 130     SPACE eurjchem-154 17 131 sodium sodium NOUN eurjchem-154 17 132     SPACE eurjchem-154 17 133 hydroxide hydroxide NOUN eurjchem-154 17 134     SPACE eurjchem-154 17 135 solution solution NOUN eurjchem-154 17 136     SPACE eurjchem-154 17 137 for for ADP eurjchem-154 17 138     SPACE eurjchem-154 17 139 24 24 NUM eurjchem-154 17 140     SPACE eurjchem-154 17 141 hours hour NOUN eurjchem-154 17 142 , , PUNCT eurjchem-154 17 143     SPACE eurjchem-154 17 144 a a DET eurjchem-154 17 145     SPACE eurjchem-154 17 146 colourless colourless ADJ eurjchem-154 17 147     SPACE eurjchem-154 17 148 crystalline crystalline NOUN eurjchem-154 17 149     SPACE eurjchem-154 17 150 material material NOUN eurjchem-154 17 151     SPACE eurjchem-154 17 152 of of ADP eurjchem-154 17 153     SPACE eurjchem-154 17 154 1,1‐bisphosphonate 1,1‐bisphosphonate NUM eurjchem-154 17 155     SPACE eurjchem-154 17 156 ( ( PUNCT eurjchem-154 17 157 5 5 NUM eurjchem-154 17 158 ) ) PUNCT eurjchem-154 17 159     SPACE eurjchem-154 17 160 was be AUX eurjchem-154 17 161     SPACE eurjchem-154 17 162 isolated isolate VERB eurjchem-154 17 163     SPACE eurjchem-154 17 164 via via ADP eurjchem-154 17 165     SPACE eurjchem-154 17 166 elimination elimination NOUN eurjchem-154 17 167     SPACE eurjchem-154 17 168 of of ADP eurjchem-154 17 169     SPACE eurjchem-154 17 170 hydrogen hydrogen NOUN eurjchem-154 17 171     SPACE eurjchem-154 17 172 cyanide cyanide NOUN eurjchem-154 17 173     SPACE eurjchem-154 17 174 as as SCONJ eurjchem-154 17 175     SPACE eurjchem-154 17 176 shown show VERB eurjchem-154 17 177     SPACE eurjchem-154 17 178 in in ADP eurjchem-154 17 179     SPACE eurjchem-154 17 180 abdel­rahman abdel­rahman NOUN eurjchem-154 17 181     SPACE eurjchem-154 17 182 et et NOUN eurjchem-154 17 183     SPACE eurjchem-154 17 184 al al PROPN eurjchem-154 17 185 . . PROPN eurjchem-154 17 186     SPACE eurjchem-154 17 187 / / SYM eurjchem-154 17 188     SPACE eurjchem-154 17 189 european european ADJ eurjchem-154 17 190     SPACE eurjchem-154 17 191 journal journal NOUN eurjchem-154 17 192     SPACE eurjchem-154 17 193 of of ADP eurjchem-154 17 194     SPACE eurjchem-154 17 195 chemistry chemistry NOUN eurjchem-154 17 196     SPACE eurjchem-154 17 197 1 1 NUM eurjchem-154 17 198     SPACE eurjchem-154 17 199 ( ( PUNCT eurjchem-154 17 200 4 4 NUM eurjchem-154 17 201 ) ) PUNCT eurjchem-154 17 202     SPACE eurjchem-154 17 203 ( ( PUNCT eurjchem-154 17 204 2010 2010 NUM eurjchem-154 17 205 ) ) PUNCT eurjchem-154 17 206     SPACE eurjchem-154 17 207 388­396 388­396 NUM eurjchem-154 17 208     SPACE eurjchem-154 17 209 389 389 NUM eurjchem-154 17 210     SPACE eurjchem-154 17 211 scheme scheme NOUN eurjchem-154 17 212     SPACE eurjchem-154 17 213 2 2 NUM eurjchem-154 17 214 . . PUNCT eurjchem-154 17 215     SPACE eurjchem-154 17 216 hydrolysis hydrolysis NOUN eurjchem-154 17 217     SPACE eurjchem-154 17 218 of of ADP eurjchem-154 17 219     SPACE eurjchem-154 17 220 the the DET eurjchem-154 17 221     SPACE eurjchem-154 17 222 1,1‐bisphosphonates 1,1‐bisphosphonate NOUN eurjchem-154 17 223     SPACE eurjchem-154 17 224 with with ADP eurjchem-154 17 225     SPACE eurjchem-154 17 226 concentrated concentrated ADJ eurjchem-154 17 227     SPACE eurjchem-154 17 228 hydrochloric hydrochloric ADJ eurjchem-154 17 229     SPACE eurjchem-154 17 230 acid acid NOUN eurjchem-154 17 231     SPACE eurjchem-154 17 232 gave give VERB eurjchem-154 17 233     SPACE eurjchem-154 17 234 the the DET eurjchem-154 17 235     SPACE eurjchem-154 17 236 corresponding corresponding ADJ eurjchem-154 17 237     SPACE eurjchem-154 17 238 1,1‐ 1,1‐ NUM eurjchem-154 17 239 bisphosphonic bisphosphonic ADJ eurjchem-154 17 240     SPACE eurjchem-154 17 241 acid acid NOUN eurjchem-154 17 242     SPACE eurjchem-154 17 243 ( ( PUNCT eurjchem-154 17 244 6 6 NUM eurjchem-154 17 245 ) ) PUNCT eurjchem-154 17 246     SPACE eurjchem-154 17 247 ( ( PUNCT eurjchem-154 17 248 scheme scheme NOUN eurjchem-154 17 249     SPACE eurjchem-154 17 250 2 2 NUM eurjchem-154 17 251 ) ) PUNCT eurjchem-154 17 252     SPACE eurjchem-154 18 1 [ [ X eurjchem-154 18 2 23 23 NUM eurjchem-154 18 3 ] ] PUNCT eurjchem-154 18 4 . . PUNCT eurjchem-154 18 5         SPACE eurjchem-154 19 1 n n CCONJ eurjchem-154 19 2 n n CCONJ eurjchem-154 19 3 nr nr NOUN eurjchem-154 19 4 r r NOUN eurjchem-154 19 5 cl cl NOUN eurjchem-154 19 6 n n CCONJ eurjchem-154 19 7 n n NOUN eurjchem-154 19 8 nr nr NOUN eurjchem-154 19 9 r r NOUN eurjchem-154 19 10 p(oet)2 p(oet)2 NOUN eurjchem-154 20 1 o o X eurjchem-154 20 2 cn cn X eurjchem-154 20 3 ( ( PUNCT eurjchem-154 20 4 eto)2p eto)2p PROPN eurjchem-154 20 5 - - PUNCT eurjchem-154 20 6 ch2cn ch2cn VERB eurjchem-154 20 7 o o PROPN eurjchem-154 20 8 n n CCONJ eurjchem-154 20 9 nh nh PROPN eurjchem-154 20 10 nr nr NOUN eurjchem-154 20 11 r r NOUN eurjchem-154 20 12 p(oet)2 p(oet)2 NOUN eurjchem-154 20 13 o o X eurjchem-154 20 14 cn cn INTJ eurjchem-154 20 15 ( ( PUNCT eurjchem-154 20 16 ro)2poh ro)2poh NOUN eurjchem-154 20 17 n n CCONJ eurjchem-154 20 18 n n CCONJ eurjchem-154 20 19 nr nr NOUN eurjchem-154 20 20 r r NOUN eurjchem-154 20 21 p(oet)2 p(oet)2 NOUN eurjchem-154 21 1 o o NOUN eurjchem-154 21 2 p(or)2o p(or)2o PROPN eurjchem-154 21 3 n n PROPN eurjchem-154 21 4 nh nh PROPN eurjchem-154 21 5 nr nr NOUN eurjchem-154 21 6 r r NOUN eurjchem-154 21 7 p(or)2 p(or)2 PUNCT eurjchem-154 21 8 o o NOUN eurjchem-154 22 1 p(oet)2o p(oet)2o PROPN eurjchem-154 22 2 n n CCONJ eurjchem-154 22 3 n n NOUN eurjchem-154 22 4 nr nr NOUN eurjchem-154 22 5 r r NOUN eurjchem-154 22 6 ch[p(oh)2]2 ch[p(oh)2]2 NOUN eurjchem-154 22 7 o o PROPN eurjchem-154 22 8 n n CCONJ eurjchem-154 22 9 nh nh PROPN eurjchem-154 22 10 nr nr NOUN eurjchem-154 22 11 r r NOUN eurjchem-154 22 12 c[p(oh)2]2 c[p(oh)2]2 NOUN eurjchem-154 22 13 o o NOUN eurjchem-154 22 14 1 1 NUM eurjchem-154 22 15 2 2 NUM eurjchem-154 22 16 1 1 NUM eurjchem-154 22 17 2 2 NUM eurjchem-154 22 18 r1 r1 NOUN eurjchem-154 22 19 = = NOUN eurjchem-154 22 20 r2 r2 NOUN eurjchem-154 22 21 = = SYM eurjchem-154 22 22 ph ph NOUN eurjchem-154 22 23 r1&r2 r1&r2 PROPN eurjchem-154 22 24 = = NOUN eurjchem-154 22 25 phenanthrene phenanthrene NOUN eurjchem-154 22 26 1 1 NUM eurjchem-154 22 27 4a 4a NOUN eurjchem-154 22 28 + + CCONJ eurjchem-154 22 29 1 1 NUM eurjchem-154 22 30 2 2 NUM eurjchem-154 22 31 4b 4b X eurjchem-154 22 32 aq aq NOUN eurjchem-154 22 33 . . PUNCT eurjchem-154 22 34 naoh naoh PROPN eurjchem-154 22 35 - - PUNCT eurjchem-154 22 36 toluene toluene NOUN eurjchem-154 22 37 lih lih PROPN eurjchem-154 22 38 dmf dmf PROPN eurjchem-154 22 39 2 2 NUM eurjchem-154 22 40 5a 5a NUM eurjchem-154 22 41 2 2 NUM eurjchem-154 22 42 5b 5b NUM eurjchem-154 22 43 conc conc NOUN eurjchem-154 22 44 . . PUNCT eurjchem-154 23 1 hcl hcl PROPN eurjchem-154 23 2 2 2 NUM eurjchem-154 23 3 1 1 NUM eurjchem-154 23 4 1 1 NUM eurjchem-154 23 5 6b 6b NOUN eurjchem-154 23 6 2 2 NUM eurjchem-154 23 7 1 1 NUM eurjchem-154 23 8 6a 6a NOUN eurjchem-154 23 9 r1 r1 NOUN eurjchem-154 23 10 = = SYM eurjchem-154 23 11 r2 r2 NOUN eurjchem-154 23 12 = = SYM eurjchem-154 23 13 ph ph PROPN eurjchem-154 23 14 r1&r2 r1&r2 PROPN eurjchem-154 23 15 = = NOUN eurjchem-154 23 16 phenanthrene phenanthrene NOUN eurjchem-154 23 17 r1&r2 r1&r2 NOUN eurjchem-154 23 18 = = NOUN eurjchem-154 23 19 phenanthrene phenanthrene NOUN eurjchem-154 23 20 r r NOUN eurjchem-154 23 21 = = NOUN eurjchem-154 23 22 me me PROPN eurjchem-154 23 23 , , PUNCT eurjchem-154 23 24 et et NOUN eurjchem-154 23 25 1 1 NUM eurjchem-154 23 26 72 72 NUM eurjchem-154 23 27 % % NOUN eurjchem-154 23 28 67 67 NUM eurjchem-154 23 29 % % NOUN eurjchem-154 23 30 59 59 NUM eurjchem-154 23 31 % % NOUN eurjchem-154 23 32           SPACE eurjchem-154 23 33 scheme scheme NOUN eurjchem-154 23 34     SPACE eurjchem-154 23 35 2 2 NUM eurjchem-154 23 36         SPACE eurjchem-154 23 37 2.1.2 2.1.2 NUM eurjchem-154 23 38 . . PUNCT eurjchem-154 23 39     SPACE eurjchem-154 23 40 phosphorylation phosphorylation NOUN eurjchem-154 23 41     SPACE eurjchem-154 23 42 of of ADP eurjchem-154 23 43     SPACE eurjchem-154 23 44 side side NOUN eurjchem-154 23 45     SPACE eurjchem-154 23 46 functional functional ADJ eurjchem-154 23 47     SPACE eurjchem-154 23 48 groups group NOUN eurjchem-154 23 49     SPACE eurjchem-154 23 50 at at ADP eurjchem-154 23 51     SPACE eurjchem-154 23 52 position position NOUN eurjchem-154 23 53     SPACE eurjchem-154 23 54 3 3 NUM eurjchem-154 23 55     SPACE eurjchem-154 23 56 of of ADP eurjchem-154 23 57     SPACE eurjchem-154 23 58 1,2,4­triazines 1,2,4­triazines NUM eurjchem-154 23 59         SPACE eurjchem-154 23 60 reaction reaction NOUN eurjchem-154 23 61     SPACE eurjchem-154 23 62 of of ADP eurjchem-154 23 63     SPACE eurjchem-154 23 64 3‐azido‐5,6‐disubstituted‐1,2,4‐triazines 3‐azido‐5,6‐disubstituted‐1,2,4‐triazine NOUN eurjchem-154 23 65     SPACE eurjchem-154 23 66 ( ( PUNCT eurjchem-154 23 67 7 7 NUM eurjchem-154 23 68 ) ) PUNCT eurjchem-154 23 69     SPACE eurjchem-154 23 70 with with ADP eurjchem-154 23 71     SPACE eurjchem-154 23 72 triphenyl triphenyl ADJ eurjchem-154 23 73     SPACE eurjchem-154 23 74 phosphine phosphine NOUN eurjchem-154 23 75     SPACE eurjchem-154 23 76 in in ADP eurjchem-154 23 77     SPACE eurjchem-154 23 78 refluxing refluxing NOUN eurjchem-154 23 79     SPACE eurjchem-154 23 80 dry dry ADJ eurjchem-154 23 81     SPACE eurjchem-154 23 82 benzene benzene NOUN eurjchem-154 23 83     SPACE eurjchem-154 23 84 gave give VERB eurjchem-154 23 85     SPACE eurjchem-154 23 86 a a DET eurjchem-154 23 87     SPACE eurjchem-154 23 88 yellow yellow ADJ eurjchem-154 23 89     SPACE eurjchem-154 23 90 crystalline crystalline NOUN eurjchem-154 23 91     SPACE eurjchem-154 23 92 product product NOUN eurjchem-154 23 93     SPACE eurjchem-154 23 94 formulated formulate VERB eurjchem-154 23 95     SPACE eurjchem-154 23 96 as as ADP eurjchem-154 23 97     SPACE eurjchem-154 23 98 8 8 NUM eurjchem-154 23 99 . . PUNCT eurjchem-154 23 100     SPACE eurjchem-154 23 101 also also ADV eurjchem-154 23 102 , , PUNCT eurjchem-154 23 103     SPACE eurjchem-154 23 104 the the DET eurjchem-154 23 105     SPACE eurjchem-154 23 106 reaction reaction NOUN eurjchem-154 23 107     SPACE eurjchem-154 23 108 of of ADP eurjchem-154 23 109     SPACE eurjchem-154 23 110 7 7 NUM eurjchem-154 23 111     SPACE eurjchem-154 23 112 with with ADP eurjchem-154 23 113     SPACE eurjchem-154 23 114 trialkyl trialkyl NOUN eurjchem-154 23 115     SPACE eurjchem-154 23 116 phosphite phosphite NOUN eurjchem-154 23 117     SPACE eurjchem-154 23 118 under under ADP eurjchem-154 23 119     SPACE eurjchem-154 23 120 the the DET eurjchem-154 23 121     SPACE eurjchem-154 23 122 same same ADJ eurjchem-154 23 123     SPACE eurjchem-154 23 124 condition condition NOUN eurjchem-154 23 125     SPACE eurjchem-154 23 126 afforded afford VERB eurjchem-154 23 127     SPACE eurjchem-154 23 128 the the DET eurjchem-154 23 129     SPACE eurjchem-154 23 130 phosphazene phosphazene NOUN eurjchem-154 23 131     SPACE eurjchem-154 23 132 derivative derivative NOUN eurjchem-154 23 133     SPACE eurjchem-154 23 134 9 9 NUM eurjchem-154 23 135 . . PUNCT eurjchem-154 23 136     SPACE eurjchem-154 23 137 the the DET eurjchem-154 23 138     SPACE eurjchem-154 23 139 structure structure NOUN eurjchem-154 23 140     SPACE eurjchem-154 23 141 of of ADP eurjchem-154 23 142     SPACE eurjchem-154 23 143 compound compound NOUN eurjchem-154 23 144     SPACE eurjchem-154 23 145 9 9 NUM eurjchem-154 23 146     SPACE eurjchem-154 23 147 may may AUX eurjchem-154 23 148     SPACE eurjchem-154 23 149 have have VERB eurjchem-154 23 150 , , PUNCT eurjchem-154 23 151     SPACE eurjchem-154 23 152 one one NUM eurjchem-154 23 153     SPACE eurjchem-154 23 154 of of ADP eurjchem-154 23 155     SPACE eurjchem-154 23 156 the the DET eurjchem-154 23 157     SPACE eurjchem-154 23 158 two two NUM eurjchem-154 23 159     SPACE eurjchem-154 23 160 dipolar dipolar ADJ eurjchem-154 23 161     SPACE eurjchem-154 23 162 resonance resonance NOUN eurjchem-154 23 163     SPACE eurjchem-154 23 164 forms form VERB eurjchem-154 23 165     SPACE eurjchem-154 23 166 a a PRON eurjchem-154 23 167     SPACE eurjchem-154 23 168 or or CCONJ eurjchem-154 23 169     SPACE eurjchem-154 23 170 b b NOUN eurjchem-154 23 171     SPACE eurjchem-154 23 172 ( ( PUNCT eurjchem-154 23 173 scheme scheme NOUN eurjchem-154 23 174     SPACE eurjchem-154 23 175 3 3 NUM eurjchem-154 23 176 ) ) PUNCT eurjchem-154 23 177     SPACE eurjchem-154 24 1 [ [ X eurjchem-154 24 2 24 24 NUM eurjchem-154 24 3 ] ] PUNCT eurjchem-154 24 4 . . PUNCT eurjchem-154 24 5             SPACE eurjchem-154 25 1 n n CCONJ eurjchem-154 25 2 n n CCONJ eurjchem-154 25 3 nr nr NOUN eurjchem-154 25 4 r r NOUN eurjchem-154 25 5 n n CCONJ eurjchem-154 25 6 n n CCONJ eurjchem-154 25 7 n n CCONJ eurjchem-154 25 8 n n CCONJ eurjchem-154 25 9 n n CCONJ eurjchem-154 25 10 nr nr NOUN eurjchem-154 25 11 r r NOUN eurjchem-154 25 12 n n CCONJ eurjchem-154 25 13 n n CCONJ eurjchem-154 25 14 n n CCONJ eurjchem-154 25 15 p(ph)3 p(ph)3 PROPN eurjchem-154 25 16 n n CCONJ eurjchem-154 25 17 n n CCONJ eurjchem-154 25 18 nr nr NOUN eurjchem-154 25 19 r r NOUN eurjchem-154 25 20 n n CCONJ eurjchem-154 25 21 n n CCONJ eurjchem-154 25 22 n n CCONJ eurjchem-154 25 23 p(r)3 p(r)3 PROPN eurjchem-154 25 24 n n CCONJ eurjchem-154 25 25 n n CCONJ eurjchem-154 25 26 nr nr NOUN eurjchem-154 25 27 r r NOUN eurjchem-154 25 28 n n CCONJ eurjchem-154 25 29 n n CCONJ eurjchem-154 25 30 n n PRON eurjchem-154 25 31 p(r)3 p(r)3 PROPN eurjchem-154 26 1 + + CCONJ eurjchem-154 26 2 1 1 NUM eurjchem-154 26 3 2 2 NUM eurjchem-154 26 4 + + CCONJ eurjchem-154 26 5 : : PUNCT eurjchem-154 26 6 p(r)3 p(r)3 PROPN eurjchem-154 26 7 r r NOUN eurjchem-154 26 8 = = NOUN eurjchem-154 26 9 ph ph ADJ eurjchem-154 26 10 r r NOUN eurjchem-154 26 11 = = SYM eurjchem-154 26 12 oet oet ADJ eurjchem-154 26 13 , , PUNCT eurjchem-154 26 14 ome ome PROPN eurjchem-154 26 15 1 1 NUM eurjchem-154 26 16 2 2 NUM eurjchem-154 26 17 1 1 NUM eurjchem-154 26 18 2 2 NUM eurjchem-154 26 19 1 1 NUM eurjchem-154 26 20 2 2 NUM eurjchem-154 26 21 + + CCONJ eurjchem-154 26 22 r1 r1 NOUN eurjchem-154 26 23 = = NOUN eurjchem-154 26 24 r2 r2 NOUN eurjchem-154 26 25 = = SYM eurjchem-154 26 26 ph ph NOUN eurjchem-154 26 27 r1&r2 r1&r2 PROPN eurjchem-154 26 28 = = PRON eurjchem-154 26 29 phenanthrene phenanthrene NOUN eurjchem-154 26 30 7 7 NUM eurjchem-154 26 31 8 8 NUM eurjchem-154 26 32 9a 9a NOUN eurjchem-154 26 33 9b 9b NOUN eurjchem-154 26 34 + + CCONJ eurjchem-154 26 35 62 62 NUM eurjchem-154 26 36 % % NOUN eurjchem-154 26 37 67 67 NUM eurjchem-154 26 38 - - SYM eurjchem-154 26 39 70 70 NUM eurjchem-154 26 40 % % NOUN eurjchem-154 26 41 : : PUNCT eurjchem-154 26 42 p(r)3 p(r)3 PROPN eurjchem-154 26 43     SPACE eurjchem-154 26 44 scheme scheme NOUN eurjchem-154 26 45     SPACE eurjchem-154 26 46 3 3 NUM eurjchem-154 26 47         SPACE eurjchem-154 26 48 phosphorylation phosphorylation NOUN eurjchem-154 26 49     SPACE eurjchem-154 26 50 of of ADP eurjchem-154 26 51     SPACE eurjchem-154 26 52 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐ 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐ NUM eurjchem-154 26 53 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 26 54     SPACE eurjchem-154 26 55 ( ( PUNCT eurjchem-154 26 56 10 10 NUM eurjchem-154 26 57 ) ) PUNCT eurjchem-154 26 58     SPACE eurjchem-154 26 59 via via ADP eurjchem-154 26 60     SPACE eurjchem-154 26 61 treatment treatment NOUN eurjchem-154 26 62     SPACE eurjchem-154 26 63 with with ADP eurjchem-154 26 64     SPACE eurjchem-154 26 65 acetonyltriphenyl acetonyltriphenyl NOUN eurjchem-154 26 66     SPACE eurjchem-154 26 67 phosphonium phosphonium NOUN eurjchem-154 26 68     SPACE eurjchem-154 26 69 chloride chloride NOUN eurjchem-154 26 70 , , PUNCT eurjchem-154 26 71     SPACE eurjchem-154 26 72 under under ADP eurjchem-154 26 73     SPACE eurjchem-154 26 74 stirring stirring NOUN eurjchem-154 26 75     SPACE eurjchem-154 26 76 in in ADP eurjchem-154 26 77     SPACE eurjchem-154 26 78 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 26 79     SPACE eurjchem-154 26 80 and and CCONJ eurjchem-154 26 81     SPACE eurjchem-154 26 82 few few ADJ eurjchem-154 26 83     SPACE eurjchem-154 26 84 drops drop VERB eurjchem-154 26 85     SPACE eurjchem-154 26 86 of of ADP eurjchem-154 26 87     SPACE eurjchem-154 26 88 piperidine piperidine NOUN eurjchem-154 26 89     SPACE eurjchem-154 26 90 for for ADP eurjchem-154 26 91     SPACE eurjchem-154 26 92 24 24 NUM eurjchem-154 26 93     SPACE eurjchem-154 26 94 hours hour NOUN eurjchem-154 26 95     SPACE eurjchem-154 26 96 at at ADP eurjchem-154 26 97     SPACE eurjchem-154 26 98 room room NOUN eurjchem-154 26 99     SPACE eurjchem-154 26 100 temperature temperature NOUN eurjchem-154 26 101 , , PUNCT eurjchem-154 26 102     SPACE eurjchem-154 26 103 achieved achieve VERB eurjchem-154 26 104     SPACE eurjchem-154 26 105 1‐[{2‐[5,6‐bis(4‐bromophenyl)‐1,2,4‐triazin‐3‐yl]hyd 1‐[{2‐[5,6‐bis(4‐bromophenyl)‐1,2,4‐triazin‐3‐yl]hyd NUM eurjchem-154 26 106     SPACE eurjchem-154 26 107 razino}(triphenylphosphoranyl)]acetone razino}(triphenylphosphoranyl)]acetone NOUN eurjchem-154 26 108     SPACE eurjchem-154 26 109 ( ( PUNCT eurjchem-154 26 110 12 12 NUM eurjchem-154 26 111 ) ) PUNCT eurjchem-154 26 112     SPACE eurjchem-154 26 113 ( ( PUNCT eurjchem-154 26 114 scheme scheme NOUN eurjchem-154 26 115     SPACE eurjchem-154 26 116 4 4 NUM eurjchem-154 26 117 ) ) PUNCT eurjchem-154 26 118 . . PUNCT eurjchem-154 26 119     SPACE eurjchem-154 27 1 formation formation NOUN eurjchem-154 27 2     SPACE eurjchem-154 27 3 of of ADP eurjchem-154 27 4     SPACE eurjchem-154 27 5 12 12 NUM eurjchem-154 27 6     SPACE eurjchem-154 27 7 may may AUX eurjchem-154 27 8     SPACE eurjchem-154 27 9 be be AUX eurjchem-154 27 10     SPACE eurjchem-154 27 11 due due ADJ eurjchem-154 27 12     SPACE eurjchem-154 27 13 to to ADP eurjchem-154 27 14     SPACE eurjchem-154 27 15 that that DET eurjchem-154 27 16     SPACE eurjchem-154 27 17 phosphorus phosphorus NOUN eurjchem-154 27 18     SPACE eurjchem-154 27 19 reagent reagent NOUN eurjchem-154 27 20     SPACE eurjchem-154 27 21 such such ADJ eurjchem-154 27 22     SPACE eurjchem-154 27 23 as as ADP eurjchem-154 27 24     SPACE eurjchem-154 27 25 phosphonium phosphonium NOUN eurjchem-154 27 26     SPACE eurjchem-154 27 27 salt salt NOUN eurjchem-154 27 28     SPACE eurjchem-154 27 29 in in ADP eurjchem-154 27 30     SPACE eurjchem-154 27 31 which which DET eurjchem-154 27 32     SPACE eurjchem-154 27 33 phosphorus phosphorus NOUN eurjchem-154 27 34     SPACE eurjchem-154 27 35 atom atom NOUN eurjchem-154 27 36     SPACE eurjchem-154 27 37 is be AUX eurjchem-154 27 38     SPACE eurjchem-154 27 39 more more ADJ eurjchem-154 27 40     SPACE eurjchem-154 27 41 electrophilic electrophilic NOUN eurjchem-154 27 42     SPACE eurjchem-154 27 43 than than ADP eurjchem-154 27 44     SPACE eurjchem-154 27 45 carbon carbon NOUN eurjchem-154 27 46     SPACE eurjchem-154 27 47 when when SCONJ eurjchem-154 27 48     SPACE eurjchem-154 27 49 one one NUM eurjchem-154 27 50     SPACE eurjchem-154 27 51 of of ADP eurjchem-154 27 52     SPACE eurjchem-154 27 53 the the DET eurjchem-154 27 54     SPACE eurjchem-154 27 55 five five NUM eurjchem-154 27 56     SPACE eurjchem-154 27 57 groups group NOUN eurjchem-154 27 58     SPACE eurjchem-154 27 59 is be AUX eurjchem-154 27 60     SPACE eurjchem-154 27 61 a a DET eurjchem-154 27 62     SPACE eurjchem-154 27 63 good good NOUN eurjchem-154 27 64     SPACE eurjchem-154 27 65 leaving leave VERB eurjchem-154 27 66     SPACE eurjchem-154 27 67 group group NOUN eurjchem-154 27 68 . . PUNCT eurjchem-154 27 69     SPACE eurjchem-154 28 1 also also ADV eurjchem-154 28 2 , , PUNCT eurjchem-154 28 3     SPACE eurjchem-154 28 4 the the DET eurjchem-154 28 5     SPACE eurjchem-154 28 6 reaction reaction NOUN eurjchem-154 28 7     SPACE eurjchem-154 28 8 of of ADP eurjchem-154 28 9     SPACE eurjchem-154 28 10 10 10 NUM eurjchem-154 28 11     SPACE eurjchem-154 28 12 with with ADP eurjchem-154 28 13     SPACE eurjchem-154 28 14 dibromotriphenylphosphorane dibromotriphenylphosphorane NOUN eurjchem-154 28 15 , , PUNCT eurjchem-154 28 16     SPACE eurjchem-154 28 17 in in ADP eurjchem-154 28 18     SPACE eurjchem-154 28 19 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 28 20     SPACE eurjchem-154 28 21 containing contain VERB eurjchem-154 28 22     SPACE eurjchem-154 28 23 piperidine piperidine NOUN eurjchem-154 28 24     SPACE eurjchem-154 28 25 under under ADP eurjchem-154 28 26     SPACE eurjchem-154 28 27 refluxing refluxing NOUN eurjchem-154 28 28     SPACE eurjchem-154 28 29 conditions condition NOUN eurjchem-154 28 30 , , PUNCT eurjchem-154 28 31     SPACE eurjchem-154 28 32 yielded yield VERB eurjchem-154 28 33     SPACE eurjchem-154 28 34 5,6‐bis(4‐ 5,6‐bis(4‐ NUM eurjchem-154 28 35 bromophenyl)‐3‐[2‐(triphenylphosphoranylidene)hydrazine]‐ bromophenyl)‐3‐[2‐(triphenylphosphoranylidene)hydrazine]‐ NOUN eurjchem-154 28 36 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 28 37     SPACE eurjchem-154 28 38 ( ( PUNCT eurjchem-154 28 39 14 14 NUM eurjchem-154 28 40 ) ) PUNCT eurjchem-154 28 41 , , PUNCT eurjchem-154 28 42     SPACE eurjchem-154 28 43 which which PRON eurjchem-154 28 44     SPACE eurjchem-154 28 45 was be AUX eurjchem-154 28 46     SPACE eurjchem-154 28 47 formed form VERB eurjchem-154 28 48     SPACE eurjchem-154 28 49 via via ADP eurjchem-154 28 50     SPACE eurjchem-154 28 51 iminophosphorane iminophosphorane ADJ eurjchem-154 28 52     SPACE eurjchem-154 28 53 mechanism mechanism NOUN eurjchem-154 28 54     SPACE eurjchem-154 28 55 ( ( PUNCT eurjchem-154 28 56 scheme scheme NOUN eurjchem-154 28 57     SPACE eurjchem-154 28 58 4 4 NUM eurjchem-154 28 59 ) ) PUNCT eurjchem-154 28 60     SPACE eurjchem-154 29 1 [ [ X eurjchem-154 29 2 25 25 NUM eurjchem-154 29 3 ] ] PUNCT eurjchem-154 29 4 . . PUNCT eurjchem-154 29 5             SPACE eurjchem-154 30 1 n n CCONJ eurjchem-154 30 2 n n PRON eurjchem-154 30 3 nar nar NOUN eurjchem-154 30 4 ar ar PROPN eurjchem-154 30 5 n n ADP eurjchem-154 30 6 h h NOUN eurjchem-154 30 7 n n NOUN eurjchem-154 30 8 + + CCONJ eurjchem-154 30 9 p p PROPN eurjchem-154 30 10 ch3 ch3 PROPN eurjchem-154 30 11 o o NOUN eurjchem-154 30 12 ph ph ADJ eurjchem-154 30 13 ph ph ADJ eurjchem-154 30 14 ph ph PROPN eurjchem-154 30 15 h h NOUN eurjchem-154 30 16 h h NOUN eurjchem-154 30 17 n n CCONJ eurjchem-154 30 18 n n ADV eurjchem-154 30 19 nar nar NOUN eurjchem-154 30 20 ar ar NOUN eurjchem-154 30 21 nhnh2 nhnh2 NOUN eurjchem-154 30 22 n n CCONJ eurjchem-154 30 23 n n PRON eurjchem-154 30 24 nar nar NOUN eurjchem-154 30 25 ar ar PROPN eurjchem-154 30 26 n n PROPN eurjchem-154 30 27 h h NOUN eurjchem-154 31 1 n n NOUN eurjchem-154 31 2 h h NOUN eurjchem-154 31 3 p p NOUN eurjchem-154 31 4 br br X eurjchem-154 31 5 ph ph X eurjchem-154 31 6 ph ph NOUN eurjchem-154 31 7 ph ph NOUN eurjchem-154 31 8 n n CCONJ eurjchem-154 31 9 n n PRON eurjchem-154 31 10 nar nar NOUN eurjchem-154 31 11 ar ar PROPN eurjchem-154 31 12 n n PROPN eurjchem-154 31 13 h h NOUN eurjchem-154 32 1 n n CCONJ eurjchem-154 32 2 p p NOUN eurjchem-154 32 3 ph ph ADJ eurjchem-154 32 4 ph ph ADJ eurjchem-154 32 5 ph ph NOUN eurjchem-154 32 6 -hbr -hbr PUNCT eurjchem-154 32 7 -hbr -hbr PUNCT eurjchem-154 33 1 n n CCONJ eurjchem-154 33 2 n n PRON eurjchem-154 33 3 nar nar NOUN eurjchem-154 33 4 ar ar PROPN eurjchem-154 33 5 n n PROPN eurjchem-154 33 6 h h NOUN eurjchem-154 34 1 n n NOUN eurjchem-154 34 2 h h NOUN eurjchem-154 34 3 p p PROPN eurjchem-154 34 4 ch3 ch3 PROPN eurjchem-154 34 5 o o NOUN eurjchem-154 34 6 ph ph PROPN eurjchem-154 34 7 phph phph PROPN eurjchem-154 34 8 p p PROPN eurjchem-154 34 9 ch3 ch3 PROPN eurjchem-154 34 10 o o PROPN eurjchem-154 34 11 ph ph ADJ eurjchem-154 34 12 ph ph NOUN eurjchem-154 34 13 ph ph NOUN eurjchem-154 34 14 p p NOUN eurjchem-154 34 15 br br NOUN eurjchem-154 34 16 br br X eurjchem-154 34 17 ph ph X eurjchem-154 34 18 ph ph NOUN eurjchem-154 34 19 ph ph NOUN eurjchem-154 34 20 -hcl -hcl ADJ eurjchem-154 34 21 thf thf NOUN eurjchem-154 34 22 - - PUNCT eurjchem-154 34 23 piperidine piperidine NOUN eurjchem-154 34 24 reflux reflux NOUN eurjchem-154 34 25 ar= ar= NOUN eurjchem-154 34 26 4 4 NUM eurjchem-154 34 27 - - PUNCT eurjchem-154 34 28 brc6h4 brc6h4 NOUN eurjchem-154 34 29 10 10 NUM eurjchem-154 34 30 11 11 NUM eurjchem-154 34 31 stirring stir VERB eurjchem-154 34 32 at at ADP eurjchem-154 34 33 rt rt PROPN eurjchem-154 34 34 thf thf NOUN eurjchem-154 34 35 - - PUNCT eurjchem-154 34 36 piperidine piperidine NOUN eurjchem-154 34 37 12 12 NUM eurjchem-154 34 38 13 13 NUM eurjchem-154 34 39 14 14 NUM eurjchem-154 34 40 88 88 NUM eurjchem-154 34 41 % % NOUN eurjchem-154 34 42 42 42 NUM eurjchem-154 34 43 % % NOUN eurjchem-154 34 44 + + CCONJ eurjchem-154 34 45 cl cl NOUN eurjchem-154 34 46 cl cl NOUN eurjchem-154 34 47     SPACE eurjchem-154 34 48 scheme scheme NOUN eurjchem-154 34 49     SPACE eurjchem-154 34 50 4 4 NUM eurjchem-154 34 51         SPACE eurjchem-154 34 52 ali ali PROPN eurjchem-154 34 53     SPACE eurjchem-154 34 54 et et PROPN eurjchem-154 34 55     SPACE eurjchem-154 34 56 al al PROPN eurjchem-154 34 57 . . PROPN eurjchem-154 34 58     SPACE eurjchem-154 35 1 [ [ X eurjchem-154 35 2 25 25 NUM eurjchem-154 35 3 ] ] PUNCT eurjchem-154 35 4     SPACE eurjchem-154 35 5 reported report VERB eurjchem-154 35 6     SPACE eurjchem-154 35 7 that that SCONJ eurjchem-154 35 8     SPACE eurjchem-154 35 9 stirring stirring NOUN eurjchem-154 35 10     SPACE eurjchem-154 35 11 of of ADP eurjchem-154 35 12     SPACE eurjchem-154 35 13 5,6‐bis(4‐ 5,6‐bis(4‐ NUM eurjchem-154 35 14 bromophenyl)‐3‐hydrazino‐1,2,4‐triazine bromophenyl)‐3‐hydrazino‐1,2,4‐triazine NOUN eurjchem-154 35 15     SPACE eurjchem-154 35 16 ( ( PUNCT eurjchem-154 35 17 10 10 NUM eurjchem-154 35 18 ) ) PUNCT eurjchem-154 35 19     SPACE eurjchem-154 35 20 with with ADP eurjchem-154 35 21     SPACE eurjchem-154 35 22 tris‐(2‐ tris‐(2‐ NOUN eurjchem-154 35 23 chloroethoxy chloroethoxy ADJ eurjchem-154 35 24 ) ) PUNCT eurjchem-154 35 25     SPACE eurjchem-154 35 26 phosphine phosphine NOUN eurjchem-154 35 27 , , PUNCT eurjchem-154 35 28     SPACE eurjchem-154 35 29 in in ADP eurjchem-154 35 30     SPACE eurjchem-154 35 31 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 35 32     SPACE eurjchem-154 35 33 containing contain VERB eurjchem-154 35 34     SPACE eurjchem-154 35 35 piperidine piperidine NOUN eurjchem-154 35 36     SPACE eurjchem-154 35 37 at at ADP eurjchem-154 35 38     SPACE eurjchem-154 35 39 room room NOUN eurjchem-154 35 40     SPACE eurjchem-154 35 41 temperature temperature NOUN eurjchem-154 35 42 , , PUNCT eurjchem-154 35 43     SPACE eurjchem-154 35 44 gave give VERB eurjchem-154 35 45     SPACE eurjchem-154 35 46 the the DET eurjchem-154 35 47     SPACE eurjchem-154 35 48 corresponding corresponding ADJ eurjchem-154 35 49     SPACE eurjchem-154 35 50 hydrazidophosphite hydrazidophosphite NOUN eurjchem-154 35 51     SPACE eurjchem-154 35 52 15 15 NUM eurjchem-154 35 53 , , PUNCT eurjchem-154 35 54     SPACE eurjchem-154 35 55 while while SCONJ eurjchem-154 35 56     SPACE eurjchem-154 35 57 repeating repeat VERB eurjchem-154 35 58     SPACE eurjchem-154 35 59 this this DET eurjchem-154 35 60     SPACE eurjchem-154 35 61 reaction reaction NOUN eurjchem-154 35 62     SPACE eurjchem-154 35 63 under under ADP eurjchem-154 35 64     SPACE eurjchem-154 35 65 reflux reflux NOUN eurjchem-154 35 66     SPACE eurjchem-154 35 67 resulted result VERB eurjchem-154 35 68     SPACE eurjchem-154 35 69 iminophosphane iminophosphane NOUN eurjchem-154 35 70     SPACE eurjchem-154 35 71 derivative derivative NOUN eurjchem-154 35 72     SPACE eurjchem-154 35 73 17 17 NUM eurjchem-154 35 74     SPACE eurjchem-154 35 75 via via ADP eurjchem-154 35 76     SPACE eurjchem-154 35 77 the the DET eurjchem-154 35 78     SPACE eurjchem-154 35 79 nonisolable nonisolable ADJ eurjchem-154 35 80     SPACE eurjchem-154 35 81 intermediate intermediate ADJ eurjchem-154 35 82     SPACE eurjchem-154 35 83 16 16 NUM eurjchem-154 35 84     SPACE eurjchem-154 35 85 ( ( PUNCT eurjchem-154 35 86 scheme scheme NOUN eurjchem-154 35 87     SPACE eurjchem-154 35 88 5 5 NUM eurjchem-154 35 89 ) ) PUNCT eurjchem-154 35 90 . . PUNCT eurjchem-154 35 91     SPACE eurjchem-154 36 1 one one NUM eurjchem-154 36 2     SPACE eurjchem-154 36 3 of of ADP eurjchem-154 36 4     SPACE eurjchem-154 36 5 the the DET eurjchem-154 36 6     SPACE eurjchem-154 36 7 most most ADJ eurjchem-154 36 8     SPACE eurjchem-154 36 9 important important ADJ eurjchem-154 36 10     SPACE eurjchem-154 36 11 of of ADP eurjchem-154 36 12     SPACE eurjchem-154 36 13 the the DET eurjchem-154 36 14     SPACE eurjchem-154 36 15 present present ADJ eurjchem-154 36 16     SPACE eurjchem-154 36 17 investigation investigation NOUN eurjchem-154 36 18     SPACE eurjchem-154 36 19 was be AUX eurjchem-154 36 20     SPACE eurjchem-154 36 21 the the DET eurjchem-154 36 22     SPACE eurjchem-154 36 23 treatment treatment NOUN eurjchem-154 36 24     SPACE eurjchem-154 36 25 of of ADP eurjchem-154 36 26     SPACE eurjchem-154 36 27 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐1,2,4‐ 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐1,2,4‐ NUM eurjchem-154 36 28 triazine triazine NOUN eurjchem-154 36 29     SPACE eurjchem-154 36 30 ( ( PUNCT eurjchem-154 36 31 10 10 NUM eurjchem-154 36 32 ) ) PUNCT eurjchem-154 36 33     SPACE eurjchem-154 36 34 with with ADP eurjchem-154 36 35     SPACE eurjchem-154 36 36 chlorophenyldichlorothiophosphate chlorophenyldichlorothiophosphate NOUN eurjchem-154 36 37 , , PUNCT eurjchem-154 36 38     SPACE eurjchem-154 36 39 diethyl diethyl NOUN eurjchem-154 36 40     SPACE eurjchem-154 36 41 phosphite phosphite NOUN eurjchem-154 36 42     SPACE eurjchem-154 36 43 and and CCONJ eurjchem-154 36 44     SPACE eurjchem-154 36 45 diphenyl(2,4,6‐trimethylbenzoyl)phosphorus diphenyl(2,4,6‐trimethylbenzoyl)phosphoru NOUN eurjchem-154 36 46     SPACE eurjchem-154 36 47 oxide oxide NOUN eurjchem-154 36 48 , , PUNCT eurjchem-154 36 49     SPACE eurjchem-154 36 50 in in ADP eurjchem-154 36 51     SPACE eurjchem-154 36 52 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 36 53     SPACE eurjchem-154 36 54 containing contain VERB eurjchem-154 36 55     SPACE eurjchem-154 36 56 few few ADJ eurjchem-154 36 57     SPACE eurjchem-154 36 58 drops drop VERB eurjchem-154 36 59     SPACE eurjchem-154 36 60 of of ADP eurjchem-154 36 61     SPACE eurjchem-154 36 62 piperidine piperidine NOUN eurjchem-154 36 63     SPACE eurjchem-154 36 64 at at ADP eurjchem-154 36 65     SPACE eurjchem-154 36 66 room room NOUN eurjchem-154 36 67     SPACE eurjchem-154 36 68 temperature temperature NOUN eurjchem-154 36 69     SPACE eurjchem-154 36 70 to to PART eurjchem-154 36 71     SPACE eurjchem-154 36 72 yield yield VERB eurjchem-154 36 73     SPACE eurjchem-154 36 74 phosphonothiohydrazide phosphonothiohydrazide NOUN eurjchem-154 36 75     SPACE eurjchem-154 36 76 18 18 NUM eurjchem-154 36 77 , , PUNCT eurjchem-154 36 78     SPACE eurjchem-154 36 79 phosphonohydrazide phosphonohydrazide NOUN eurjchem-154 36 80     SPACE eurjchem-154 36 81 19 19 NUM eurjchem-154 36 82     SPACE eurjchem-154 36 83 and and CCONJ eurjchem-154 36 84     SPACE eurjchem-154 36 85 ( ( PUNCT eurjchem-154 36 86 diphenylphosphoryl){[2‐[5,6‐ diphenylphosphoryl){[2‐[5,6‐ PROPN eurjchem-154 36 87 bis(4‐bromophenyl)‐1,2,4‐triazin‐3‐yl]hydrazino}(2,4,6‐ bis(4‐bromophenyl)‐1,2,4‐triazin‐3‐yl]hydrazino}(2,4,6‐ PROPN eurjchem-154 36 88 trimethoxyphenyl)methanol trimethoxyphenyl)methanol PROPN eurjchem-154 36 89     SPACE eurjchem-154 36 90 ( ( PUNCT eurjchem-154 36 91 20 20 NUM eurjchem-154 36 92 ) ) PUNCT eurjchem-154 36 93 , , PUNCT eurjchem-154 36 94     SPACE eurjchem-154 36 95 respectively respectively ADV eurjchem-154 36 96     SPACE eurjchem-154 36 97 ( ( PUNCT eurjchem-154 36 98 scheme scheme NOUN eurjchem-154 36 99     SPACE eurjchem-154 36 100 6 6 NUM eurjchem-154 36 101 ) ) PUNCT eurjchem-154 36 102     SPACE eurjchem-154 37 1 [ [ X eurjchem-154 37 2 25 25 NUM eurjchem-154 37 3 ] ] PUNCT eurjchem-154 37 4 . . PUNCT eurjchem-154 37 5         SPACE eurjchem-154 38 1 2.2 2.2 NUM eurjchem-154 38 2 . . PUNCT eurjchem-154 38 3     SPACE eurjchem-154 39 1 synthesis synthesis NOUN eurjchem-154 39 2     SPACE eurjchem-154 39 3 of of ADP eurjchem-154 39 4     SPACE eurjchem-154 39 5 isolated isolate VERB eurjchem-154 39 6     SPACE eurjchem-154 39 7 phosphorus phosphorus NOUN eurjchem-154 39 8     SPACE eurjchem-154 39 9 heterocyclic heterocyclic NOUN eurjchem-154 39 10     SPACE eurjchem-154 39 11 systems system NOUN eurjchem-154 39 12     SPACE eurjchem-154 39 13 containing contain VERB eurjchem-154 39 14     SPACE eurjchem-154 39 15 1,2,4­triazines 1,2,4­triazines NUM eurjchem-154 39 16         SPACE eurjchem-154 39 17 2.2.1 2.2.1 NUM eurjchem-154 39 18 . . PUNCT eurjchem-154 39 19     SPACE eurjchem-154 39 20 five­membered five­membere VERB eurjchem-154 39 21     SPACE eurjchem-154 39 22 rings ring NOUN eurjchem-154 39 23         SPACE eurjchem-154 39 24 reaction reaction NOUN eurjchem-154 39 25     SPACE eurjchem-154 39 26 of of ADP eurjchem-154 39 27     SPACE eurjchem-154 39 28 5,6‐diphenyl‐1,2,4‐triazin‐3(2h)‐one 5,6‐diphenyl‐1,2,4‐triazin‐3(2h)‐one NUM eurjchem-154 39 29     SPACE eurjchem-154 39 30 ( ( PUNCT eurjchem-154 39 31 21 21 NUM eurjchem-154 39 32 ) ) PUNCT eurjchem-154 39 33     SPACE eurjchem-154 39 34 with with ADP eurjchem-154 39 35     SPACE eurjchem-154 39 36 2‐substituted‐1,3,2‐dioxaphospholanes 2‐substituted‐1,3,2‐dioxaphospholane NOUN eurjchem-154 39 37     SPACE eurjchem-154 39 38 ( ( PUNCT eurjchem-154 39 39 22 22 NUM eurjchem-154 39 40 ) ) PUNCT eurjchem-154 39 41     SPACE eurjchem-154 39 42 afforded afford VERB eurjchem-154 39 43     SPACE eurjchem-154 39 44 2‐(1,3,2‐ 2‐(1,3,2‐ PROPN eurjchem-154 39 45 dioxaphospholan‐2‐yl)‐5,6‐diphenyl‐1,2,4‐triazin‐3(2h)‐one dioxaphospholan‐2‐yl)‐5,6‐diphenyl‐1,2,4‐triazin‐3(2h)‐one PROPN eurjchem-154 39 46     SPACE eurjchem-154 39 47 ( ( PUNCT eurjchem-154 39 48 23 23 NUM eurjchem-154 39 49 ) ) PUNCT eurjchem-154 39 50     SPACE eurjchem-154 39 51 in in ADP eurjchem-154 39 52     SPACE eurjchem-154 39 53 moderate moderate ADJ eurjchem-154 39 54     SPACE eurjchem-154 39 55 yields yield NOUN eurjchem-154 39 56     SPACE eurjchem-154 39 57 ( ( PUNCT eurjchem-154 39 58 scheme scheme NOUN eurjchem-154 39 59     SPACE eurjchem-154 39 60 7 7 NUM eurjchem-154 39 61 ) ) PUNCT eurjchem-154 39 62     SPACE eurjchem-154 40 1 [ [ X eurjchem-154 40 2 22 22 NUM eurjchem-154 40 3 ] ] PUNCT eurjchem-154 40 4 . . PUNCT eurjchem-154 40 5       SPACE eurjchem-154 41 1 the the DET eurjchem-154 41 2     SPACE eurjchem-154 41 3 reaction reaction NOUN eurjchem-154 41 4     SPACE eurjchem-154 41 5 of of ADP eurjchem-154 41 6     SPACE eurjchem-154 41 7 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐1,2,4‐ 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐1,2,4‐ NUM eurjchem-154 41 8 triazine triazine NOUN eurjchem-154 41 9     SPACE eurjchem-154 41 10 ( ( PUNCT eurjchem-154 41 11 10 10 NUM eurjchem-154 41 12 ) ) PUNCT eurjchem-154 41 13     SPACE eurjchem-154 41 14 with with ADP eurjchem-154 41 15     SPACE eurjchem-154 41 16 acetonyltriphenylphosphonium acetonyltriphenylphosphonium NOUN eurjchem-154 41 17     SPACE eurjchem-154 41 18 chloride chloride NOUN eurjchem-154 41 19 , , PUNCT eurjchem-154 41 20     SPACE eurjchem-154 41 21 in in ADP eurjchem-154 41 22     SPACE eurjchem-154 41 23 boiling boiling NOUN eurjchem-154 41 24     SPACE eurjchem-154 41 25 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 41 26     SPACE eurjchem-154 41 27 containing contain VERB eurjchem-154 41 28     SPACE eurjchem-154 41 29 piperidine piperidine NOUN eurjchem-154 41 30 , , PUNCT eurjchem-154 41 31     SPACE eurjchem-154 41 32 furnished furnish VERB eurjchem-154 41 33     SPACE eurjchem-154 41 34 5,6‐ 5,6‐ NUM eurjchem-154 41 35 bis(4‐bromophenyl)‐3‐[(3,3,3‐triphenyl)‐5‐methyl‐3,4‐dihydro bis(4‐bromophenyl)‐3‐[(3,3,3‐triphenyl)‐5‐methyl‐3,4‐dihydro NOUN eurjchem-154 41 36     SPACE eurjchem-154 41 37 ‐2h‐1,2,3‐λ5‐diazaphosphol‐2‐yl]‐1,2,4‐triazine ‐2h‐1,2,3‐λ5‐diazaphosphol‐2‐yl]‐1,2,4‐triazine NOUN eurjchem-154 41 38     SPACE eurjchem-154 41 39 ( ( PUNCT eurjchem-154 41 40 25 25 NUM eurjchem-154 41 41 ) ) PUNCT eurjchem-154 41 42 . . PUNCT eurjchem-154 41 43     SPACE eurjchem-154 42 1 forma‐ forma‐ NOUN eurjchem-154 42 2 tion tion NOUN eurjchem-154 42 3     SPACE eurjchem-154 42 4 of of ADP eurjchem-154 42 5     SPACE eurjchem-154 42 6 25 25 NUM eurjchem-154 42 7     SPACE eurjchem-154 42 8 may may AUX eurjchem-154 42 9     SPACE eurjchem-154 42 10 occur occur VERB eurjchem-154 42 11     SPACE eurjchem-154 42 12 via via ADP eurjchem-154 42 13     SPACE eurjchem-154 42 14 nucleophilic nucleophilic ADJ eurjchem-154 42 15     SPACE eurjchem-154 42 16 attack attack NOUN eurjchem-154 42 17     SPACE eurjchem-154 42 18 of of ADP eurjchem-154 42 19     SPACE eurjchem-154 42 20 the the DET eurjchem-154 42 21     SPACE eurjchem-154 42 22 hydrazine hydrazine NOUN eurjchem-154 42 23     SPACE eurjchem-154 42 24 moiety moiety NOUN eurjchem-154 42 25     SPACE eurjchem-154 42 26 at at ADP eurjchem-154 42 27     SPACE eurjchem-154 42 28 carbonyl carbonyl NOUN eurjchem-154 42 29     SPACE eurjchem-154 42 30 group group NOUN eurjchem-154 42 31     SPACE eurjchem-154 42 32 with with ADP eurjchem-154 42 33     SPACE eurjchem-154 42 34 loss loss NOUN eurjchem-154 42 35     SPACE eurjchem-154 42 36 of of ADP eurjchem-154 42 37     SPACE eurjchem-154 42 38 one one NUM eurjchem-154 42 39     SPACE eurjchem-154 42 40 molecule molecule NOUN eurjchem-154 42 41     SPACE eurjchem-154 42 42 of of ADP eurjchem-154 42 43     SPACE eurjchem-154 42 44 water water NOUN eurjchem-154 42 45     SPACE eurjchem-154 42 46 to to PART eurjchem-154 42 47     SPACE eurjchem-154 42 48 yield yield VERB eurjchem-154 42 49     SPACE eurjchem-154 42 50 the the DET eurjchem-154 42 51     SPACE eurjchem-154 42 52 nonisolable nonisolable ADJ eurjchem-154 42 53     SPACE eurjchem-154 42 54 intermediate intermediate ADJ eurjchem-154 42 55     SPACE eurjchem-154 42 56 24 24 NUM eurjchem-154 42 57 , , PUNCT eurjchem-154 42 58     SPACE eurjchem-154 42 59 which which PRON eurjchem-154 42 60     SPACE eurjchem-154 42 61 underwent underwent NOUN eurjchem-154 42 62     SPACE eurjchem-154 42 63 losing lose VERB eurjchem-154 42 64     SPACE eurjchem-154 42 65 one one NUM eurjchem-154 42 66     SPACE eurjchem-154 42 67 molecule molecule NOUN eurjchem-154 42 68     SPACE eurjchem-154 42 69 of of ADP eurjchem-154 42 70     SPACE eurjchem-154 42 71 hydrogen hydrogen NOUN eurjchem-154 42 72     SPACE eurjchem-154 42 73 chloride chloride NOUN eurjchem-154 42 74     SPACE eurjchem-154 42 75 ( ( PUNCT eurjchem-154 42 76 scheme scheme NOUN eurjchem-154 42 77     SPACE eurjchem-154 42 78 8) 8) NOUN eurjchem-154 42 79     SPACE eurjchem-154 42 80 [ [ X eurjchem-154 42 81 25 25 NUM eurjchem-154 42 82 ] ] PUNCT eurjchem-154 42 83 . . PUNCT eurjchem-154 42 84         SPACE eurjchem-154 43 1 2.2.2 2.2.2 NUM eurjchem-154 43 2 . . PUNCT eurjchem-154 43 3     SPACE eurjchem-154 43 4 six­membered six­membere VERB eurjchem-154 43 5     SPACE eurjchem-154 43 6 rings ring NOUN eurjchem-154 43 7         SPACE eurjchem-154 43 8 a a DET eurjchem-154 43 9     SPACE eurjchem-154 43 10 facile facile ADJ eurjchem-154 43 11     SPACE eurjchem-154 43 12 synthesis synthesis NOUN eurjchem-154 43 13     SPACE eurjchem-154 43 14 of of ADP eurjchem-154 43 15     SPACE eurjchem-154 43 16 new new ADJ eurjchem-154 43 17     SPACE eurjchem-154 43 18 isolated isolate VERB eurjchem-154 43 19     SPACE eurjchem-154 43 20 phosphorus phosphorus NOUN eurjchem-154 43 21     SPACE eurjchem-154 43 22 heterocyclic heterocyclic NOUN eurjchem-154 43 23     SPACE eurjchem-154 43 24 nitrogen nitrogen NOUN eurjchem-154 43 25     SPACE eurjchem-154 43 26 system system NOUN eurjchem-154 43 27     SPACE eurjchem-154 43 28 containing contain VERB eurjchem-154 43 29     SPACE eurjchem-154 43 30 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 43 31     SPACE eurjchem-154 43 32 moiety moiety NOUN eurjchem-154 43 33     SPACE eurjchem-154 43 34 was be AUX eurjchem-154 43 35     SPACE eurjchem-154 43 36 reported report VERB eurjchem-154 43 37     SPACE eurjchem-154 43 38 by by ADP eurjchem-154 43 39     SPACE eurjchem-154 43 40 abdel‐rahman abdel‐rahman NOUN eurjchem-154 43 41     SPACE eurjchem-154 44 1 [ [ X eurjchem-154 44 2 26 26 NUM eurjchem-154 44 3 ] ] PUNCT eurjchem-154 44 4 . . PUNCT eurjchem-154 44 5     SPACE eurjchem-154 44 6 treatment treatment NOUN eurjchem-154 44 7     SPACE eurjchem-154 44 8 of of ADP eurjchem-154 44 9     SPACE eurjchem-154 44 10 n‐(5,6‐diphenyl‐1,2,4‐ n‐(5,6‐diphenyl‐1,2,4‐ NOUN eurjchem-154 44 11 triazin‐3‐yl)hydrazinecarbothioamide triazin‐3‐yl)hydrazinecarbothioamide NOUN eurjchem-154 44 12     SPACE eurjchem-154 44 13 ( ( PUNCT eurjchem-154 44 14 26 26 NUM eurjchem-154 44 15 ) ) PUNCT eurjchem-154 44 16     SPACE eurjchem-154 44 17 with with ADP eurjchem-154 44 18     SPACE eurjchem-154 44 19 diethyl diethyl NOUN eurjchem-154 44 20     SPACE eurjchem-154 44 21 benzoylphosphate benzoylphosphate NOUN eurjchem-154 44 22     SPACE eurjchem-154 44 23 and/or and/or CCONJ eurjchem-154 44 24     SPACE eurjchem-154 44 25 diphenyl(2,4,6‐trimethylbenzoyl diphenyl(2,4,6‐trimethylbenzoyl PROPN eurjchem-154 44 26 ) ) PUNCT eurjchem-154 44 27       SPACE eurjchem-154 44 28 390 390 NUM eurjchem-154 44 29     SPACE eurjchem-154 44 30 abdel­rahman abdel­rahman NOUN eurjchem-154 44 31     SPACE eurjchem-154 44 32 et et NOUN eurjchem-154 44 33     SPACE eurjchem-154 44 34 al al PROPN eurjchem-154 44 35 . . PROPN eurjchem-154 44 36     SPACE eurjchem-154 44 37 / / SYM eurjchem-154 44 38     SPACE eurjchem-154 44 39 european european ADJ eurjchem-154 44 40     SPACE eurjchem-154 44 41 journal journal NOUN eurjchem-154 44 42     SPACE eurjchem-154 44 43 of of ADP eurjchem-154 44 44     SPACE eurjchem-154 44 45 chemistry chemistry NOUN eurjchem-154 44 46     SPACE eurjchem-154 44 47 1 1 NUM eurjchem-154 44 48     SPACE eurjchem-154 44 49 ( ( PUNCT eurjchem-154 44 50 4 4 NUM eurjchem-154 44 51 ) ) PUNCT eurjchem-154 44 52     SPACE eurjchem-154 44 53 ( ( PUNCT eurjchem-154 44 54 2010 2010 NUM eurjchem-154 44 55 ) ) PUNCT eurjchem-154 44 56     SPACE eurjchem-154 44 57 388­396 388­396 NUM eurjchem-154 44 58                 SPACE eurjchem-154 44 59 n n CCONJ eurjchem-154 44 60 n n PRON eurjchem-154 44 61 nar nar NOUN eurjchem-154 44 62 ar ar NOUN eurjchem-154 44 63 nhnh2 nhnh2 NOUN eurjchem-154 44 64 p p X eurjchem-154 44 65 oclch2ch2o oclch2ch2o NOUN eurjchem-154 44 66 och2ch2cl och2ch2cl PROPN eurjchem-154 44 67 cl cl NOUN eurjchem-154 44 68 p p NOUN eurjchem-154 44 69 oclch2ch2o oclch2ch2o NOUN eurjchem-154 44 70 och2ch2cl och2ch2cl PROPN eurjchem-154 44 71 cl cl NOUN eurjchem-154 44 72 p p NOUN eurjchem-154 44 73 o o X eurjchem-154 44 74 och2ch2cl och2ch2cl PROPN eurjchem-154 44 75 och2ch2cln och2ch2cln NOUN eurjchem-154 44 76 n n CCONJ eurjchem-154 44 77 nar nar NOUN eurjchem-154 44 78 ar ar PROPN eurjchem-154 44 79 n n PROPN eurjchem-154 44 80 h h NOUN eurjchem-154 45 1 n n NOUN eurjchem-154 45 2 h h NOUN eurjchem-154 46 1 p p PRON eurjchem-154 46 2 och2ch2cl och2ch2cl PROPN eurjchem-154 46 3 och2ch2cl och2ch2cl PROPN eurjchem-154 46 4 n n CCONJ eurjchem-154 46 5 n n NOUN eurjchem-154 46 6 nar nar NOUN eurjchem-154 46 7 ar ar PROPN eurjchem-154 46 8 n n PROPN eurjchem-154 46 9 h h NOUN eurjchem-154 47 1 n n NOUN eurjchem-154 47 2 h h NOUN eurjchem-154 48 1 p p PRON eurjchem-154 48 2 och2ch2cl och2ch2cl PROPN eurjchem-154 48 3 n n CCONJ eurjchem-154 48 4 n n PRON eurjchem-154 48 5 nar nar NOUN eurjchem-154 48 6 ar ar PROPN eurjchem-154 48 7 n n ADP eurjchem-154 48 8 h h NOUN eurjchem-154 48 9 n n CCONJ eurjchem-154 48 10 -hcl -hcl ADJ eurjchem-154 48 11 hoch2ch2cl hoch2ch2cl NUM eurjchem-154 48 12 hoch2ch2cl hoch2ch2cl NOUN eurjchem-154 48 13 stirring stirring NOUN eurjchem-154 48 14 at at ADP eurjchem-154 48 15 r. r. PROPN eurjchem-154 48 16 tthf tthf NOUN eurjchem-154 48 17 - - PUNCT eurjchem-154 48 18 piperidinethf piperidinethf NOUN eurjchem-154 48 19 - - PUNCT eurjchem-154 48 20 piperidine piperidine NOUN eurjchem-154 48 21 reflux reflux NOUN eurjchem-154 48 22 ar= ar= NOUN eurjchem-154 48 23 4 4 NUM eurjchem-154 48 24 - - PUNCT eurjchem-154 48 25 brc6h4 brc6h4 NOUN eurjchem-154 48 26 10 10 NUM eurjchem-154 48 27 15 15 NUM eurjchem-154 48 28 17 17 NUM eurjchem-154 48 29 16 16 NUM eurjchem-154 48 30 35%36 35%36 NUM eurjchem-154 48 31 % % NOUN eurjchem-154 48 32     SPACE eurjchem-154 48 33 scheme scheme NOUN eurjchem-154 48 34     SPACE eurjchem-154 48 35 5 5 NUM eurjchem-154 48 36         SPACE eurjchem-154 48 37 n n CCONJ eurjchem-154 49 1 n n PRON eurjchem-154 49 2 nar nar NOUN eurjchem-154 49 3 ar ar NOUN eurjchem-154 49 4 nhnh2 nhnh2 NOUN eurjchem-154 50 1 o o NOUN eurjchem-154 51 1 p p X eurjchem-154 51 2 h h NOUN eurjchem-154 51 3 oeteto oeteto VERB eurjchem-154 51 4 sp sp ADP eurjchem-154 51 5 cln cln PROPN eurjchem-154 51 6 n n CCONJ eurjchem-154 51 7 nar nar PROPN eurjchem-154 51 8 ar ar PROPN eurjchem-154 51 9 nh nh PROPN eurjchem-154 51 10 nh nh PROPN eurjchem-154 51 11 cl cl NOUN eurjchem-154 51 12 op op NOUN eurjchem-154 51 13 n n CCONJ eurjchem-154 51 14 n n ADV eurjchem-154 51 15 nar nar NOUN eurjchem-154 51 16 ar ar PROPN eurjchem-154 51 17 nh nh PROPN eurjchem-154 51 18 nh nh PROPN eurjchem-154 51 19 och2ch3 och2ch3 PROPN eurjchem-154 51 20 h h NOUN eurjchem-154 51 21 p p X eurjchem-154 51 22 s s X eurjchem-154 51 23 cl cl NOUN eurjchem-154 51 24 cl cl NOUN eurjchem-154 51 25 cl cl NOUN eurjchem-154 52 1 p p NOUN eurjchem-154 52 2 o o X eurjchem-154 52 3 o o X eurjchem-154 52 4 ph ph PROPN eurjchem-154 52 5 ph ph PROPN eurjchem-154 52 6 ch3 ch3 PROPN eurjchem-154 52 7 ch3ch3 ch3ch3 PROPN eurjchem-154 52 8 n n CCONJ eurjchem-154 52 9 n n PRON eurjchem-154 52 10 nar nar NOUN eurjchem-154 52 11 ar ar PROPN eurjchem-154 52 12 n n PROPN eurjchem-154 52 13 h h NOUN eurjchem-154 53 1 n n NOUN eurjchem-154 53 2 h h NOUN eurjchem-154 54 1 p p NOUN eurjchem-154 55 1 oh oh INTJ eurjchem-154 55 2 o o INTJ eurjchem-154 55 3 ch3 ch3 PROPN eurjchem-154 55 4 ch3 ch3 PROPN eurjchem-154 55 5 ch3 ch3 PROPN eurjchem-154 55 6 ph ph PROPN eurjchem-154 55 7 ph ph ADJ eurjchem-154 55 8 ar= ar= NOUN eurjchem-154 55 9 4 4 NUM eurjchem-154 55 10 - - PUNCT eurjchem-154 55 11 brc6h4 brc6h4 NOUN eurjchem-154 55 12 stiring stiring NOUN eurjchem-154 55 13 at at ADP eurjchem-154 55 14 r.t r.t PROPN eurjchem-154 55 15 . . PROPN eurjchem-154 55 16 thf thf NOUN eurjchem-154 55 17 - - PUNCT eurjchem-154 55 18 piperidine piperidine NOUN eurjchem-154 55 19 stiring stiring NOUN eurjchem-154 55 20 at at ADP eurjchem-154 55 21 r.t r.t PROPN eurjchem-154 55 22 . . PROPN eurjchem-154 55 23 thf thf NOUN eurjchem-154 55 24 - - PUNCT eurjchem-154 55 25 piperidine piperidine NOUN eurjchem-154 55 26 10 10 NUM eurjchem-154 55 27 19 19 NUM eurjchem-154 55 28 18 18 NUM eurjchem-154 55 29 stirring stirring NOUN eurjchem-154 55 30 at at ADP eurjchem-154 55 31 r. r. PROPN eurjchem-154 55 32 t t PROPN eurjchem-154 55 33 thf thf NOUN eurjchem-154 55 34 - - PUNCT eurjchem-154 55 35 piperidine piperidine NOUN eurjchem-154 55 36 20 20 NUM eurjchem-154 55 37 25 25 NUM eurjchem-154 55 38 % % NOUN eurjchem-154 55 39 36 36 NUM eurjchem-154 55 40 % % NOUN eurjchem-154 55 41 33 33 NUM eurjchem-154 55 42 % % NOUN eurjchem-154 55 43           SPACE eurjchem-154 55 44 scheme scheme NOUN eurjchem-154 55 45     SPACE eurjchem-154 55 46 6 6 NUM eurjchem-154 55 47         SPACE eurjchem-154 55 48 phosphine phosphine NOUN eurjchem-154 55 49     SPACE eurjchem-154 55 50 oxide oxide NOUN eurjchem-154 55 51     SPACE eurjchem-154 55 52 in in ADP eurjchem-154 55 53     SPACE eurjchem-154 55 54 boiling boil VERB eurjchem-154 55 55     SPACE eurjchem-154 55 56 toluene toluene NOUN eurjchem-154 55 57     SPACE eurjchem-154 55 58 afforded afford VERB eurjchem-154 55 59     SPACE eurjchem-154 55 60 1,2,4,5‐ 1,2,4,5‐ NUM eurjchem-154 55 61 triazaphosphorine‐3(2h)thiones triazaphosphorine‐3(2h)thiones PROPN eurjchem-154 55 62     SPACE eurjchem-154 55 63 27 27 NUM eurjchem-154 55 64     SPACE eurjchem-154 55 65 and and CCONJ eurjchem-154 55 66     SPACE eurjchem-154 55 67 28 28 NUM eurjchem-154 55 68 , , PUNCT eurjchem-154 55 69     SPACE eurjchem-154 55 70 respectively respectively ADV eurjchem-154 55 71     SPACE eurjchem-154 55 72 ( ( PUNCT eurjchem-154 55 73 scheme scheme NOUN eurjchem-154 55 74     SPACE eurjchem-154 55 75 9 9 NUM eurjchem-154 55 76 ) ) PUNCT eurjchem-154 55 77 . . PUNCT eurjchem-154 55 78     SPACE eurjchem-154 56 1 refluxing refluxing NOUN eurjchem-154 56 2     SPACE eurjchem-154 56 3 the the DET eurjchem-154 56 4     SPACE eurjchem-154 56 5 latter latter ADJ eurjchem-154 56 6     SPACE eurjchem-154 56 7 compounds compound VERB eurjchem-154 56 8     SPACE eurjchem-154 56 9 in in ADP eurjchem-154 56 10     SPACE eurjchem-154 56 11 trifluoroacetic trifluoroacetic ADJ eurjchem-154 56 12     SPACE eurjchem-154 56 13 anhydride anhydride NOUN eurjchem-154 56 14     SPACE eurjchem-154 56 15 yielded yield VERB eurjchem-154 56 16     SPACE eurjchem-154 56 17 the the DET eurjchem-154 56 18     SPACE eurjchem-154 56 19 3‐trifluoroacetyl‐1,2,4,5‐triazaphos 3‐trifluoroacetyl‐1,2,4,5‐triazaphos NUM eurjchem-154 56 20     SPACE eurjchem-154 56 21 phorine‐3(2h)thiones phorine‐3(2h)thione NOUN eurjchem-154 56 22     SPACE eurjchem-154 56 23 29 29 NUM eurjchem-154 56 24     SPACE eurjchem-154 56 25 and and CCONJ eurjchem-154 56 26     SPACE eurjchem-154 56 27 30 30 NUM eurjchem-154 56 28 , , PUNCT eurjchem-154 56 29     SPACE eurjchem-154 56 30 respectively respectively ADV eurjchem-154 56 31     SPACE eurjchem-154 56 32 ( ( PUNCT eurjchem-154 56 33 scheme scheme NOUN eurjchem-154 56 34     SPACE eurjchem-154 56 35 9 9 NUM eurjchem-154 56 36 ) ) PUNCT eurjchem-154 56 37 . . PUNCT eurjchem-154 56 38             SPACE eurjchem-154 57 1 n n PROPN eurjchem-154 57 2 nh nh PROPN eurjchem-154 57 3 nph nph PROPN eurjchem-154 57 4 ph ph PROPN eurjchem-154 58 1 o o NOUN eurjchem-154 58 2 o o X eurjchem-154 59 1 o o X eurjchem-154 59 2 pr pr INTJ eurjchem-154 60 1 o o NOUN eurjchem-154 60 2 o o INTJ eurjchem-154 60 3 pn pn PROPN eurjchem-154 60 4 n n CCONJ eurjchem-154 60 5 nph nph PROPN eurjchem-154 60 6 ph ph PROPN eurjchem-154 60 7 o o NOUN eurjchem-154 60 8 k2co3 k2co3 NOUN eurjchem-154 60 9 21 21 NUM eurjchem-154 61 1 + + CCONJ eurjchem-154 61 2 2322 2322 NUM eurjchem-154 61 3 r r NOUN eurjchem-154 61 4 = = NOUN eurjchem-154 61 5 cl cl NOUN eurjchem-154 61 6 , , PUNCT eurjchem-154 61 7 ome ome PROPN eurjchem-154 61 8 , , PUNCT eurjchem-154 61 9 n(me)2 n(me)2 PROPN eurjchem-154 61 10 48 48 NUM eurjchem-154 61 11 - - SYM eurjchem-154 61 12 59 59 NUM eurjchem-154 61 13 % % NOUN eurjchem-154 61 14 scheme scheme NOUN eurjchem-154 61 15     SPACE eurjchem-154 61 16 7 7 NUM eurjchem-154 61 17         SPACE eurjchem-154 61 18 2.2.3 2.2.3 NUM eurjchem-154 61 19 . . PUNCT eurjchem-154 61 20     SPACE eurjchem-154 61 21 seven­membered seven­membere VERB eurjchem-154 61 22     SPACE eurjchem-154 61 23 rings ring NOUN eurjchem-154 61 24         SPACE eurjchem-154 61 25 similarly similarly ADV eurjchem-154 61 26 , , PUNCT eurjchem-154 61 27     SPACE eurjchem-154 61 28 cyclocondensation cyclocondensation NOUN eurjchem-154 61 29     SPACE eurjchem-154 61 30 of of ADP eurjchem-154 61 31     SPACE eurjchem-154 61 32 n‐(5,6‐diphenyl‐1,2,4‐ n‐(5,6‐diphenyl‐1,2,4‐ NOUN eurjchem-154 61 33 triazin‐3‐yl)hydrazinecarbothioamide triazin‐3‐yl)hydrazinecarbothioamide NOUN eurjchem-154 61 34     SPACE eurjchem-154 61 35 ( ( PUNCT eurjchem-154 61 36 26 26 NUM eurjchem-154 61 37 ) ) PUNCT eurjchem-154 61 38     SPACE eurjchem-154 61 39 with with ADP eurjchem-154 61 40     SPACE eurjchem-154 61 41 acetonyl acetonyl ADJ eurjchem-154 61 42     SPACE eurjchem-154 61 43 triphenyl‐phosphonium triphenyl‐phosphonium NOUN eurjchem-154 61 44     SPACE eurjchem-154 61 45 chloride chloride NOUN eurjchem-154 61 46     SPACE eurjchem-154 61 47 in in ADP eurjchem-154 61 48     SPACE eurjchem-154 61 49 boiling boiling NOUN eurjchem-154 61 50     SPACE eurjchem-154 61 51 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 61 52     SPACE eurjchem-154 61 53 and and CCONJ eurjchem-154 61 54     SPACE eurjchem-154 61 55 dimethylformamide dimethylformamide NOUN eurjchem-154 61 56     SPACE eurjchem-154 61 57 led lead VERB eurjchem-154 61 58     SPACE eurjchem-154 61 59 to to ADP eurjchem-154 61 60     SPACE eurjchem-154 61 61 the the DET eurjchem-154 61 62     SPACE eurjchem-154 61 63 direct direct ADJ eurjchem-154 61 64     SPACE eurjchem-154 61 65 formation formation NOUN eurjchem-154 61 66     SPACE eurjchem-154 61 67 of of ADP eurjchem-154 61 68     SPACE eurjchem-154 61 69 1,2,4,5‐ 1,2,4,5‐ NUM eurjchem-154 61 70 triazaphosphepine‐3‐(2h)thione triazaphosphepine‐3‐(2h)thione NOUN eurjchem-154 61 71     SPACE eurjchem-154 61 72 31 31 NUM eurjchem-154 61 73 . . PUNCT eurjchem-154 61 74     SPACE eurjchem-154 61 75 presence presence NOUN eurjchem-154 61 76     SPACE eurjchem-154 61 77 of of ADP eurjchem-154 61 78     SPACE eurjchem-154 61 79 both both DET eurjchem-154 61 80     SPACE eurjchem-154 61 81 nh nh PROPN eurjchem-154 61 82     SPACE eurjchem-154 61 83 and and CCONJ eurjchem-154 61 84     SPACE eurjchem-154 61 85 ch2 ch2 PROPN eurjchem-154 61 86     SPACE eurjchem-154 61 87 groups group NOUN eurjchem-154 61 88     SPACE eurjchem-154 61 89 in in ADP eurjchem-154 61 90     SPACE eurjchem-154 61 91 compound compound NOUN eurjchem-154 61 92     SPACE eurjchem-154 61 93 31 31 NUM eurjchem-154 61 94     SPACE eurjchem-154 61 95 was be AUX eurjchem-154 61 96     SPACE eurjchem-154 61 97 deduced deduce VERB eurjchem-154 61 98     SPACE eurjchem-154 61 99 from from ADP eurjchem-154 61 100     SPACE eurjchem-154 61 101 acylation acylation NOUN eurjchem-154 61 102     SPACE eurjchem-154 61 103 and and CCONJ eurjchem-154 61 104     SPACE eurjchem-154 61 105 condensation condensation NOUN eurjchem-154 61 106     SPACE eurjchem-154 61 107 with with ADP eurjchem-154 61 108     SPACE eurjchem-154 61 109 trifluoroacetic trifluoroacetic ADJ eurjchem-154 61 110     SPACE eurjchem-154 61 111 anhydride anhydride NOUN eurjchem-154 61 112     SPACE eurjchem-154 61 113 and and CCONJ eurjchem-154 61 114     SPACE eurjchem-154 61 115 trifluoro trifluoro VERB eurjchem-154 61 116     SPACE eurjchem-154 61 117 benzaldehyde benzaldehyde NOUN eurjchem-154 61 118 , , PUNCT eurjchem-154 61 119     SPACE eurjchem-154 61 120 respectively respectively ADV eurjchem-154 61 121 , , PUNCT eurjchem-154 61 122     SPACE eurjchem-154 61 123 and and CCONJ eurjchem-154 61 124     SPACE eurjchem-154 61 125 vice vice NOUN eurjchem-154 61 126     SPACE eurjchem-154 61 127 versa versa ADV eurjchem-154 61 128     SPACE eurjchem-154 61 129 to to PART eurjchem-154 61 130     SPACE eurjchem-154 61 131 give give VERB eurjchem-154 61 132     SPACE eurjchem-154 61 133 the the DET eurjchem-154 61 134     SPACE eurjchem-154 61 135 fluorinated‐1,2,4,5‐triazaphosphepine‐3‐(2h)thione fluorinated‐1,2,4,5‐triazaphosphepine‐3‐(2h)thione NOUN eurjchem-154 61 136     SPACE eurjchem-154 61 137 34 34 NUM eurjchem-154 61 138     SPACE eurjchem-154 61 139 ( ( PUNCT eurjchem-154 61 140 scheme scheme NOUN eurjchem-154 61 141     SPACE eurjchem-154 61 142 10 10 NUM eurjchem-154 61 143 ) ) PUNCT eurjchem-154 61 144     SPACE eurjchem-154 62 1 [ [ X eurjchem-154 62 2 26 26 NUM eurjchem-154 62 3 ] ] PUNCT eurjchem-154 62 4 . . PUNCT eurjchem-154 62 5         SPACE eurjchem-154 63 1 n n CCONJ eurjchem-154 63 2 n n PRON eurjchem-154 63 3 nar nar NOUN eurjchem-154 63 4 ar ar NOUN eurjchem-154 63 5 nhnh2 nhnh2 NOUN eurjchem-154 63 6 p p PROPN eurjchem-154 63 7 ch3 ch3 PROPN eurjchem-154 63 8 ph ph ADJ eurjchem-154 63 9 ph ph NOUN eurjchem-154 63 10 ph ph NOUN eurjchem-154 63 11 n n CCONJ eurjchem-154 63 12 n n PRON eurjchem-154 63 13 nar nar NOUN eurjchem-154 63 14 ar ar PROPN eurjchem-154 63 15 n n PROPN eurjchem-154 63 16 h h NOUN eurjchem-154 63 17 n n CCONJ eurjchem-154 63 18 n n CCONJ eurjchem-154 63 19 n n ADV eurjchem-154 63 20 nar nar NOUN eurjchem-154 63 21 ar ar PROPN eurjchem-154 63 22 n n ADP eurjchem-154 63 23 n n PROPN eurjchem-154 63 24 p p PROPN eurjchem-154 63 25 ch3 ch3 PROPN eurjchem-154 63 26 phph phph PROPN eurjchem-154 63 27 ph ph PROPN eurjchem-154 63 28 p p PROPN eurjchem-154 63 29 ch3 ch3 PROPN eurjchem-154 63 30 o o NOUN eurjchem-154 63 31 ph ph ADJ eurjchem-154 63 32 ph ph ADJ eurjchem-154 63 33 ph ph NOUN eurjchem-154 63 34 ar= ar= NOUN eurjchem-154 63 35 4 4 NUM eurjchem-154 63 36 - - PUNCT eurjchem-154 63 37 brc6h4 brc6h4 NOUN eurjchem-154 63 38 reflux reflux NOUN eurjchem-154 63 39 , , PUNCT eurjchem-154 63 40 thf thf NOUN eurjchem-154 63 41 - - PUNCT eurjchem-154 63 42 piperidine piperidine NOUN eurjchem-154 63 43 10 10 NUM eurjchem-154 63 44 25 25 NUM eurjchem-154 63 45 + + NUM eurjchem-154 63 46 24 24 NUM eurjchem-154 63 47 -hcl -hcl ADJ eurjchem-154 63 48 -h2o -h2o NOUN eurjchem-154 63 49 22 22 NUM eurjchem-154 63 50 % % NOUN eurjchem-154 63 51 cl cl NOUN eurjchem-154 63 52 cl cl NOUN eurjchem-154 64 1 + + CCONJ eurjchem-154 64 2 + + NUM eurjchem-154 64 3 scheme scheme NOUN eurjchem-154 64 4     SPACE eurjchem-154 64 5 8 8 NUM eurjchem-154 64 6         SPACE eurjchem-154 64 7 abdel­rahman abdel­rahman NOUN eurjchem-154 64 8     SPACE eurjchem-154 64 9 et et NOUN eurjchem-154 64 10     SPACE eurjchem-154 64 11 al al PROPN eurjchem-154 64 12 . . PROPN eurjchem-154 64 13     SPACE eurjchem-154 64 14 / / SYM eurjchem-154 64 15     SPACE eurjchem-154 64 16 european european ADJ eurjchem-154 64 17     SPACE eurjchem-154 64 18 journal journal NOUN eurjchem-154 64 19     SPACE eurjchem-154 64 20 of of ADP eurjchem-154 64 21     SPACE eurjchem-154 64 22 chemistry chemistry NOUN eurjchem-154 64 23     SPACE eurjchem-154 64 24 1 1 NUM eurjchem-154 64 25     SPACE eurjchem-154 64 26 ( ( PUNCT eurjchem-154 64 27 4 4 NUM eurjchem-154 64 28 ) ) PUNCT eurjchem-154 64 29     SPACE eurjchem-154 64 30 ( ( PUNCT eurjchem-154 64 31 2010 2010 NUM eurjchem-154 64 32 ) ) PUNCT eurjchem-154 64 33     SPACE eurjchem-154 64 34 388­396 388­396 NUM eurjchem-154 64 35     SPACE eurjchem-154 64 36 391 391 NUM eurjchem-154 64 37         SPACE eurjchem-154 64 38 n n ADP eurjchem-154 64 39 n n ADV eurjchem-154 64 40 nph nph X eurjchem-154 64 41 ph ph PROPN eurjchem-154 64 42 n n PROPN eurjchem-154 64 43 h h NOUN eurjchem-154 65 1 n n DET eurjchem-154 65 2 h h NOUN eurjchem-154 65 3 s s VERB eurjchem-154 65 4 nh2 nh2 PROPN eurjchem-154 65 5 p p PROPN eurjchem-154 65 6 o o X eurjchem-154 65 7 ph ph ADJ eurjchem-154 65 8 o o NOUN eurjchem-154 65 9 oet oet ADJ eurjchem-154 65 10 oet oet VERB eurjchem-154 65 11 p p NOUN eurjchem-154 65 12 o o X eurjchem-154 65 13 o o X eurjchem-154 65 14 ph ph PROPN eurjchem-154 65 15 ph ph PROPN eurjchem-154 65 16 ch3 ch3 PROPN eurjchem-154 65 17 ch3ch3 ch3ch3 PROPN eurjchem-154 65 18 n n CCONJ eurjchem-154 65 19 n n ADV eurjchem-154 65 20 nph nph X eurjchem-154 65 21 ph ph PROPN eurjchem-154 65 22 s s NOUN eurjchem-154 65 23 n n PRON eurjchem-154 65 24 p p NOUN eurjchem-154 65 25 n n PROPN eurjchem-154 65 26 nh nh PROPN eurjchem-154 65 27 o o PROPN eurjchem-154 65 28 eto eto PROPN eurjchem-154 65 29 ph ph PROPN eurjchem-154 65 30 n n PROPN eurjchem-154 65 31 n n ADV eurjchem-154 65 32 nph nph X eurjchem-154 65 33 ph ph PROPN eurjchem-154 65 34 s s NOUN eurjchem-154 65 35 n n PRON eurjchem-154 65 36 p p PROPN eurjchem-154 65 37 n n PROPN eurjchem-154 65 38 nh nh NOUN eurjchem-154 65 39 o o PROPN eurjchem-154 65 40 ph ph PROPN eurjchem-154 65 41 ch3 ch3 PROPN eurjchem-154 65 42 ch3 ch3 PROPN eurjchem-154 65 43 ch3 ch3 PROPN eurjchem-154 65 44 n n CCONJ eurjchem-154 65 45 n n ADV eurjchem-154 65 46 nph nph X eurjchem-154 65 47 ph ph PROPN eurjchem-154 65 48 s s NOUN eurjchem-154 65 49 n n PRON eurjchem-154 65 50 p p NOUN eurjchem-154 65 51 n n CCONJ eurjchem-154 65 52 n n NOUN eurjchem-154 65 53 o o PROPN eurjchem-154 65 54 eto eto PROPN eurjchem-154 65 55 ph ph PROPN eurjchem-154 65 56 cocf3 cocf3 PROPN eurjchem-154 65 57 n n CCONJ eurjchem-154 65 58 n n ADV eurjchem-154 65 59 nph nph X eurjchem-154 65 60 ph ph PROPN eurjchem-154 65 61 s s NOUN eurjchem-154 65 62 n n PRON eurjchem-154 65 63 p p NOUN eurjchem-154 65 64 n n CCONJ eurjchem-154 65 65 n n ADV eurjchem-154 65 66 o o NOUN eurjchem-154 65 67 ph ph PROPN eurjchem-154 65 68 ch3 ch3 PROPN eurjchem-154 65 69 ch3 ch3 PROPN eurjchem-154 65 70 ch3 ch3 PROPN eurjchem-154 65 71 cocf3 cocf3 PROPN eurjchem-154 66 1 26 26 NUM eurjchem-154 66 2 28 28 NUM eurjchem-154 66 3 27 27 NUM eurjchem-154 66 4 30 30 NUM eurjchem-154 66 5 29 29 NUM eurjchem-154 66 6 ( ( PUNCT eurjchem-154 66 7 cf3co)2o cf3co)2o NOUN eurjchem-154 66 8 ( ( PUNCT eurjchem-154 66 9 cf3co)2o cf3co)2o NOUN eurjchem-154 66 10 toulene toulene NOUN eurjchem-154 66 11 touleneh2o touleneh2o VERB eurjchem-154 66 12 -etoh -etoh ADJ eurjchem-154 66 13 h2o h2o NOUN eurjchem-154 66 14 -phh66 -phh66 PUNCT eurjchem-154 66 15 % % NOUN eurjchem-154 66 16 87 87 NUM eurjchem-154 66 17 % % NOUN eurjchem-154 66 18 54 54 NUM eurjchem-154 66 19 % % NOUN eurjchem-154 66 20 48 48 NUM eurjchem-154 66 21 % % NOUN eurjchem-154 66 22     SPACE eurjchem-154 66 23 scheme scheme NOUN eurjchem-154 66 24     SPACE eurjchem-154 66 25 9 9 NUM eurjchem-154 66 26             SPACE eurjchem-154 66 27 n n CCONJ eurjchem-154 66 28 n n ADV eurjchem-154 66 29 nph nph X eurjchem-154 66 30 ph ph PROPN eurjchem-154 66 31 n n PROPN eurjchem-154 66 32 h h NOUN eurjchem-154 67 1 n n DET eurjchem-154 67 2 h h NOUN eurjchem-154 67 3 s s VERB eurjchem-154 67 4 nh2 nh2 PROPN eurjchem-154 67 5 p p PROPN eurjchem-154 67 6 ch3 ch3 PROPN eurjchem-154 67 7 o o NOUN eurjchem-154 67 8 ph ph PROPN eurjchem-154 67 9 phph phph PROPN eurjchem-154 67 10 n n CCONJ eurjchem-154 67 11 n n ADV eurjchem-154 67 12 nph nph PROPN eurjchem-154 67 13 ph ph PROPN eurjchem-154 67 14 n n PROPN eurjchem-154 67 15 nh nh PROPN eurjchem-154 67 16 p p PROPN eurjchem-154 67 17 n n PROPN eurjchem-154 67 18 s s PART eurjchem-154 67 19 ch3 ch3 PROPN eurjchem-154 67 20 ph ph ADJ eurjchem-154 67 21 ph ph NOUN eurjchem-154 67 22 ph ph PROPN eurjchem-154 67 23 n n CCONJ eurjchem-154 67 24 n n ADV eurjchem-154 67 25 nph nph X eurjchem-154 67 26 ph ph PROPN eurjchem-154 67 27 n n CCONJ eurjchem-154 67 28 n n PROPN eurjchem-154 67 29 p p NOUN eurjchem-154 67 30 n n PROPN eurjchem-154 67 31 s s PART eurjchem-154 67 32 ch3 ch3 PROPN eurjchem-154 67 33 ph ph ADJ eurjchem-154 67 34 ph ph ADJ eurjchem-154 67 35 ph ph NOUN eurjchem-154 67 36 cocf3 cocf3 PROPN eurjchem-154 67 37 n n CCONJ eurjchem-154 67 38 n n ADV eurjchem-154 67 39 nph nph PROPN eurjchem-154 67 40 ph ph PROPN eurjchem-154 67 41 n n PROPN eurjchem-154 67 42 nh nh PROPN eurjchem-154 67 43 p p PROPN eurjchem-154 67 44 n n PROPN eurjchem-154 67 45 s s PART eurjchem-154 67 46 ch3 ch3 PROPN eurjchem-154 67 47 ph ph ADJ eurjchem-154 67 48 ph ph PROPN eurjchem-154 67 49 ph ph PROPN eurjchem-154 67 50 f f PROPN eurjchem-154 67 51 n n CCONJ eurjchem-154 67 52 n n ADV eurjchem-154 67 53 nph nph X eurjchem-154 67 54 ph ph PROPN eurjchem-154 67 55 n n CCONJ eurjchem-154 67 56 n n PROPN eurjchem-154 67 57 p p NOUN eurjchem-154 67 58 n n PROPN eurjchem-154 67 59 s s PART eurjchem-154 67 60 ch3 ch3 PROPN eurjchem-154 67 61 ph ph ADJ eurjchem-154 67 62 ph ph PROPN eurjchem-154 67 63 ph ph PROPN eurjchem-154 68 1 f f X eurjchem-154 68 2 cocf3 cocf3 PROPN eurjchem-154 69 1 f f PROPN eurjchem-154 69 2 ohc ohc PROPN eurjchem-154 69 3 f f PROPN eurjchem-154 69 4 ohc ohc PROPN eurjchem-154 69 5 cl cl NOUN eurjchem-154 69 6 26 26 NUM eurjchem-154 69 7 31 31 NUM eurjchem-154 69 8 34 34 NUM eurjchem-154 69 9 ( ( PUNCT eurjchem-154 69 10 cf3co)2o cf3co)2o NOUN eurjchem-154 69 11 + + X eurjchem-154 70 1 + + NUM eurjchem-154 70 2 32 32 NUM eurjchem-154 70 3 33 33 NUM eurjchem-154 70 4 thf thf PROPN eurjchem-154 70 5 - - PUNCT eurjchem-154 70 6 dmf dmf PROPN eurjchem-154 70 7 ( ( PUNCT eurjchem-154 70 8 cf3co)2o cf3co)2o VERB eurjchem-154 70 9 56 56 NUM eurjchem-154 70 10 % % NOUN eurjchem-154 70 11 77 77 NUM eurjchem-154 70 12 % % NOUN eurjchem-154 70 13 57 57 NUM eurjchem-154 70 14 % % NOUN eurjchem-154 70 15 65 65 NUM eurjchem-154 70 16 % % NOUN eurjchem-154 70 17 59 59 NUM eurjchem-154 70 18 % % NOUN eurjchem-154 70 19     SPACE eurjchem-154 70 20 scheme scheme NOUN eurjchem-154 70 21     SPACE eurjchem-154 70 22 10 10 NUM eurjchem-154 70 23         SPACE eurjchem-154 70 24 392 392 NUM eurjchem-154 70 25     SPACE eurjchem-154 70 26 abdel­rahman abdel­rahman NOUN eurjchem-154 70 27     SPACE eurjchem-154 70 28 et et NOUN eurjchem-154 70 29     SPACE eurjchem-154 70 30 al al PROPN eurjchem-154 70 31 . . PROPN eurjchem-154 70 32     SPACE eurjchem-154 70 33 / / SYM eurjchem-154 70 34     SPACE eurjchem-154 70 35 european european ADJ eurjchem-154 70 36     SPACE eurjchem-154 70 37 journal journal NOUN eurjchem-154 70 38     SPACE eurjchem-154 70 39 of of ADP eurjchem-154 70 40     SPACE eurjchem-154 70 41 chemistry chemistry NOUN eurjchem-154 70 42     SPACE eurjchem-154 70 43 1 1 NUM eurjchem-154 70 44     SPACE eurjchem-154 70 45 ( ( PUNCT eurjchem-154 70 46 4 4 NUM eurjchem-154 70 47 ) ) PUNCT eurjchem-154 70 48     SPACE eurjchem-154 70 49 ( ( PUNCT eurjchem-154 70 50 2010 2010 NUM eurjchem-154 70 51 ) ) PUNCT eurjchem-154 70 52     SPACE eurjchem-154 70 53 388­396 388­396 NUM eurjchem-154 70 54         SPACE eurjchem-154 70 55 2.3 2.3 NUM eurjchem-154 70 56 . . PUNCT eurjchem-154 70 57     SPACE eurjchem-154 70 58 synthesis synthesis NOUN eurjchem-154 70 59     SPACE eurjchem-154 70 60 of of ADP eurjchem-154 70 61     SPACE eurjchem-154 70 62 fused fuse VERB eurjchem-154 70 63     SPACE eurjchem-154 70 64 phosphorus phosphorus NOUN eurjchem-154 70 65     SPACE eurjchem-154 70 66 heterocyclic heterocyclic NOUN eurjchem-154 70 67     SPACE eurjchem-154 70 68 systems system NOUN eurjchem-154 70 69     SPACE eurjchem-154 70 70 containing contain VERB eurjchem-154 70 71     SPACE eurjchem-154 70 72 1,2,4­triazines 1,2,4­triazines NUM eurjchem-154 70 73         SPACE eurjchem-154 70 74 2.3.1 2.3.1 NUM eurjchem-154 70 75 . . PUNCT eurjchem-154 70 76     SPACE eurjchem-154 70 77 four­membered four­membere VERB eurjchem-154 70 78     SPACE eurjchem-154 70 79 rings ring NOUN eurjchem-154 70 80         SPACE eurjchem-154 70 81 a a DET eurjchem-154 70 82     SPACE eurjchem-154 70 83 novel novel NOUN eurjchem-154 70 84     SPACE eurjchem-154 70 85 class class NOUN eurjchem-154 70 86     SPACE eurjchem-154 70 87 of of ADP eurjchem-154 70 88     SPACE eurjchem-154 70 89 four‐membered four‐membere VERB eurjchem-154 70 90     SPACE eurjchem-154 70 91 ring ring NOUN eurjchem-154 70 92     SPACE eurjchem-154 70 93 containing contain VERB eurjchem-154 70 94     SPACE eurjchem-154 70 95 phosphorus phosphorus NOUN eurjchem-154 70 96     SPACE eurjchem-154 70 97 such such ADJ eurjchem-154 70 98     SPACE eurjchem-154 70 99 as as ADP eurjchem-154 70 100     SPACE eurjchem-154 70 101 1,3,2‐diazaphospheto[3,4‐b][1,2,4 1,3,2‐diazaphospheto[3,4‐b][1,2,4 NUM eurjchem-154 70 102 ] ] X eurjchem-154 70 103     SPACE eurjchem-154 70 104 triazines triazine NOUN eurjchem-154 70 105     SPACE eurjchem-154 70 106 36 36 NUM eurjchem-154 70 107     SPACE eurjchem-154 70 108 and and CCONJ eurjchem-154 70 109     SPACE eurjchem-154 70 110 37 37 NUM eurjchem-154 70 111     SPACE eurjchem-154 70 112 were be AUX eurjchem-154 70 113     SPACE eurjchem-154 70 114 synthesized synthesize VERB eurjchem-154 70 115     SPACE eurjchem-154 70 116 by by ADP eurjchem-154 70 117     SPACE eurjchem-154 70 118 treating treat VERB eurjchem-154 70 119     SPACE eurjchem-154 70 120 3‐amino‐5,6‐ 3‐amino‐5,6‐ PROPN eurjchem-154 70 121 dimethyl‐1,2,4‐triazine dimethyl‐1,2,4‐triazine NOUN eurjchem-154 70 122     SPACE eurjchem-154 70 123 ( ( PUNCT eurjchem-154 70 124 35 35 NUM eurjchem-154 70 125 ) ) PUNCT eurjchem-154 70 126     SPACE eurjchem-154 70 127 with with ADP eurjchem-154 70 128     SPACE eurjchem-154 70 129 dibromotriphenylphos dibromotriphenylphos NOUN eurjchem-154 70 130     SPACE eurjchem-154 70 131 phorane phorane NOUN eurjchem-154 70 132     SPACE eurjchem-154 70 133 and and CCONJ eurjchem-154 70 134     SPACE eurjchem-154 70 135 triethyl triethyl NOUN eurjchem-154 70 136     SPACE eurjchem-154 70 137 phosphate phosphate NOUN eurjchem-154 70 138 , , PUNCT eurjchem-154 70 139     SPACE eurjchem-154 70 140 respectively respectively ADV eurjchem-154 70 141 , , PUNCT eurjchem-154 70 142     SPACE eurjchem-154 70 143 in in ADP eurjchem-154 70 144     SPACE eurjchem-154 70 145 toluene toluene NOUN eurjchem-154 70 146     SPACE eurjchem-154 70 147 containing contain VERB eurjchem-154 70 148     SPACE eurjchem-154 70 149 few few ADJ eurjchem-154 70 150     SPACE eurjchem-154 70 151 drops drop NOUN eurjchem-154 70 152     SPACE eurjchem-154 70 153 of of ADP eurjchem-154 70 154     SPACE eurjchem-154 70 155 triethylamine triethylamine NOUN eurjchem-154 70 156     SPACE eurjchem-154 70 157 ( ( PUNCT eurjchem-154 70 158 scheme scheme NOUN eurjchem-154 70 159     SPACE eurjchem-154 70 160 11 11 NUM eurjchem-154 70 161 ) ) PUNCT eurjchem-154 70 162     SPACE eurjchem-154 71 1 [ [ X eurjchem-154 71 2 26 26 NUM eurjchem-154 71 3 ] ] PUNCT eurjchem-154 71 4 . . PUNCT eurjchem-154 71 5             SPACE eurjchem-154 72 1 n n CCONJ eurjchem-154 72 2 n n PRON eurjchem-154 72 3 nch3 nch3 PROPN eurjchem-154 72 4 ch3 ch3 PROPN eurjchem-154 72 5 nh2 nh2 PROPN eurjchem-154 72 6 n n PROPN eurjchem-154 72 7 nch3 nch3 PROPN eurjchem-154 72 8 ch3 ch3 PROPN eurjchem-154 72 9 n n CCONJ eurjchem-154 72 10 n n CCONJ eurjchem-154 72 11 p(ph)3 p(ph)3 PROPN eurjchem-154 72 12 n n PRON eurjchem-154 72 13 nch3 nch3 PROPN eurjchem-154 72 14 ch3 ch3 PROPN eurjchem-154 72 15 n n CCONJ eurjchem-154 72 16 n n NUM eurjchem-154 72 17 p(o)(oet p(o)(oet VERB eurjchem-154 72 18 ) ) PUNCT eurjchem-154 72 19 ( ( PUNCT eurjchem-154 72 20 ph)3pbr2 ph)3pbr2 X eurjchem-154 72 21 ( ( PUNCT eurjchem-154 72 22 eto)3po eto)3po PROPN eurjchem-154 72 23 35 35 NUM eurjchem-154 72 24 37 37 NUM eurjchem-154 72 25 36 36 NUM eurjchem-154 72 26 toluenetoluene toluenetoluene NOUN eurjchem-154 72 27 68%81 68%81 NUM eurjchem-154 72 28 % % NOUN eurjchem-154 72 29 scheme scheme NOUN eurjchem-154 72 30     SPACE eurjchem-154 72 31 11 11 NUM eurjchem-154 72 32         SPACE eurjchem-154 72 33 similarly similarly ADV eurjchem-154 72 34 , , PUNCT eurjchem-154 72 35     SPACE eurjchem-154 72 36 reaction reaction NOUN eurjchem-154 72 37     SPACE eurjchem-154 72 38 of of ADP eurjchem-154 72 39     SPACE eurjchem-154 72 40 3‐amino‐5,6‐dimethyl‐1,2,4‐triazine 3‐amino‐5,6‐dimethyl‐1,2,4‐triazine NOUN eurjchem-154 72 41     SPACE eurjchem-154 72 42 ( ( PUNCT eurjchem-154 72 43 35 35 NUM eurjchem-154 72 44 ) ) PUNCT eurjchem-154 72 45     SPACE eurjchem-154 72 46 with with ADP eurjchem-154 72 47     SPACE eurjchem-154 72 48 diethylbenzyl diethylbenzyl NOUN eurjchem-154 72 49     SPACE eurjchem-154 72 50 phosphonate phosphonate NOUN eurjchem-154 72 51     SPACE eurjchem-154 72 52 and and CCONJ eurjchem-154 72 53     SPACE eurjchem-154 72 54 dibromo‐ dibromo‐ PROPN eurjchem-154 72 55 tris(diethyamino)‐5‐phosphane tris(diethyamino)‐5‐phosphane NOUN eurjchem-154 72 56     SPACE eurjchem-154 72 57 in in ADP eurjchem-154 72 58     SPACE eurjchem-154 72 59 dry dry ADJ eurjchem-154 72 60     SPACE eurjchem-154 72 61 toluene toluene NOUN eurjchem-154 72 62     SPACE eurjchem-154 72 63 gave give VERB eurjchem-154 72 64     SPACE eurjchem-154 72 65 the the DET eurjchem-154 72 66     SPACE eurjchem-154 72 67 1,3,2‐ 1,3,2‐ NUM eurjchem-154 72 68 diazaphospheto[3,4‐b][1,2,4]triazine diazaphospheto[3,4‐b][1,2,4]triazine NOUN eurjchem-154 72 69     SPACE eurjchem-154 72 70 derivatives derivative NOUN eurjchem-154 72 71     SPACE eurjchem-154 72 72 38 38 NUM eurjchem-154 72 73     SPACE eurjchem-154 72 74 and and CCONJ eurjchem-154 72 75     SPACE eurjchem-154 72 76 39 39 NUM eurjchem-154 72 77 , , PUNCT eurjchem-154 72 78     SPACE eurjchem-154 72 79 respectively respectively ADV eurjchem-154 72 80     SPACE eurjchem-154 72 81 ( ( PUNCT eurjchem-154 72 82 scheme scheme NOUN eurjchem-154 72 83     SPACE eurjchem-154 72 84 12 12 NUM eurjchem-154 72 85 ) ) PUNCT eurjchem-154 72 86     SPACE eurjchem-154 73 1 [ [ X eurjchem-154 73 2 26 26 NUM eurjchem-154 73 3 ] ] PUNCT eurjchem-154 73 4 . . PUNCT eurjchem-154 73 5         SPACE eurjchem-154 74 1 n n CCONJ eurjchem-154 74 2 n n PRON eurjchem-154 74 3 nch3 nch3 PROPN eurjchem-154 74 4 ch3 ch3 PROPN eurjchem-154 74 5 nh2 nh2 PROPN eurjchem-154 74 6 n n PROPN eurjchem-154 74 7 nch3 nch3 PROPN eurjchem-154 74 8 ch3 ch3 PROPN eurjchem-154 74 9 n n CCONJ eurjchem-154 74 10 n n PROPN eurjchem-154 74 11 p p NOUN eurjchem-154 74 12 o o X eurjchem-154 74 13 ch2ph ch2ph NOUN eurjchem-154 74 14 n n PRON eurjchem-154 74 15 nch3 nch3 PROPN eurjchem-154 74 16 ch3 ch3 PROPN eurjchem-154 74 17 n n CCONJ eurjchem-154 74 18 n n CCONJ eurjchem-154 74 19 p(net2)3 p(net2)3 PRON eurjchem-154 74 20 phch2p(o)(oet)2 phch2p(o)(oet)2 PROPN eurjchem-154 74 21 ( ( PUNCT eurjchem-154 74 22 net2)3pbr2 net2)3pbr2 NUM eurjchem-154 74 23 35 35 NUM eurjchem-154 74 24 38 38 NUM eurjchem-154 74 25 toluenetoluene toluenetoluene NOUN eurjchem-154 74 26 39 39 NUM eurjchem-154 74 27 85%67 85%67 NUM eurjchem-154 74 28 % % NOUN eurjchem-154 74 29 scheme scheme NOUN eurjchem-154 74 30     SPACE eurjchem-154 74 31 12 12 NUM eurjchem-154 74 32         SPACE eurjchem-154 74 33 2.3.2 2.3.2 NUM eurjchem-154 74 34 . . PUNCT eurjchem-154 74 35     SPACE eurjchem-154 74 36 five­membered five­membere VERB eurjchem-154 74 37     SPACE eurjchem-154 74 38 rings ring NOUN eurjchem-154 74 39         SPACE eurjchem-154 74 40 on on ADP eurjchem-154 74 41     SPACE eurjchem-154 74 42 the the DET eurjchem-154 74 43     SPACE eurjchem-154 74 44 other other ADJ eurjchem-154 74 45     SPACE eurjchem-154 74 46 hand hand NOUN eurjchem-154 74 47 , , PUNCT eurjchem-154 74 48     SPACE eurjchem-154 74 49 condensation condensation NOUN eurjchem-154 74 50     SPACE eurjchem-154 74 51 of of ADP eurjchem-154 74 52     SPACE eurjchem-154 74 53 3‐amino‐5,6‐dimethyl‐ 3‐amino‐5,6‐dimethyl‐ NUM eurjchem-154 74 54 1,2,4‐triazine 1,2,4‐triazine NUM eurjchem-154 74 55     SPACE eurjchem-154 74 56 ( ( PUNCT eurjchem-154 74 57 35 35 NUM eurjchem-154 74 58 ) ) PUNCT eurjchem-154 74 59     SPACE eurjchem-154 74 60 with with ADP eurjchem-154 74 61     SPACE eurjchem-154 74 62 5‐bromothiophene‐2‐carboxaldehyde 5‐bromothiophene‐2‐carboxaldehyde NOUN eurjchem-154 74 63     SPACE eurjchem-154 74 64 and/or and/or CCONJ eurjchem-154 74 65     SPACE eurjchem-154 74 66 acetophenonesulfonate acetophenonesulfonate NOUN eurjchem-154 74 67     SPACE eurjchem-154 74 68 in in ADP eurjchem-154 74 69     SPACE eurjchem-154 74 70 the the DET eurjchem-154 74 71     SPACE eurjchem-154 74 72 presence presence NOUN eurjchem-154 74 73     SPACE eurjchem-154 74 74 of of ADP eurjchem-154 74 75     SPACE eurjchem-154 74 76 tri(4‐ tri(4‐ PROPN eurjchem-154 74 77 chlorophenoxy)phosphine chlorophenoxy)phosphine NOUN eurjchem-154 74 78     SPACE eurjchem-154 74 79 in in ADP eurjchem-154 74 80     SPACE eurjchem-154 74 81 dry dry ADJ eurjchem-154 74 82     SPACE eurjchem-154 74 83 toluene toluene NOUN eurjchem-154 74 84     SPACE eurjchem-154 74 85 in in ADP eurjchem-154 74 86     SPACE eurjchem-154 74 87 presence presence NOUN eurjchem-154 74 88     SPACE eurjchem-154 74 89 of of ADP eurjchem-154 74 90     SPACE eurjchem-154 74 91 triethylamine triethylamine NOUN eurjchem-154 74 92     SPACE eurjchem-154 74 93 led lead VERB eurjchem-154 74 94     SPACE eurjchem-154 74 95 to to ADP eurjchem-154 74 96     SPACE eurjchem-154 74 97 the the DET eurjchem-154 74 98     SPACE eurjchem-154 74 99 direct direct ADJ eurjchem-154 74 100     SPACE eurjchem-154 74 101 formation formation NOUN eurjchem-154 74 102     SPACE eurjchem-154 74 103 of of ADP eurjchem-154 74 104     SPACE eurjchem-154 74 105 the the DET eurjchem-154 74 106     SPACE eurjchem-154 74 107 1,3,5‐ 1,3,5‐ PROPN eurjchem-154 74 108 diazaphospholo[3,2‐b][1,2,4]triazine diazaphospholo[3,2‐b][1,2,4]triazine NOUN eurjchem-154 74 109     SPACE eurjchem-154 74 110 systems system NOUN eurjchem-154 74 111     SPACE eurjchem-154 74 112 40 40 NUM eurjchem-154 74 113     SPACE eurjchem-154 74 114 and and CCONJ eurjchem-154 74 115     SPACE eurjchem-154 74 116 41 41 NUM eurjchem-154 74 117 , , PUNCT eurjchem-154 74 118     SPACE eurjchem-154 74 119 respectively respectively ADV eurjchem-154 74 120     SPACE eurjchem-154 74 121 ( ( PUNCT eurjchem-154 74 122 scheme scheme NOUN eurjchem-154 74 123     SPACE eurjchem-154 74 124 13 13 NUM eurjchem-154 74 125 ) ) PUNCT eurjchem-154 74 126     SPACE eurjchem-154 75 1 [ [ X eurjchem-154 75 2 26 26 NUM eurjchem-154 75 3 ] ] PUNCT eurjchem-154 75 4 . . PUNCT eurjchem-154 75 5             SPACE eurjchem-154 76 1 n n CCONJ eurjchem-154 76 2 n n PRON eurjchem-154 76 3 nch3 nch3 PROPN eurjchem-154 76 4 ch3 ch3 PROPN eurjchem-154 76 5 nh2 nh2 PROPN eurjchem-154 76 6 n n PROPN eurjchem-154 76 7 nch3 nch3 PROPN eurjchem-154 76 8 ch3 ch3 PROPN eurjchem-154 76 9 n n CCONJ eurjchem-154 76 10 n n PROPN eurjchem-154 76 11 p p NOUN eurjchem-154 76 12 o o PROPN eurjchem-154 76 13 ar ar PROPN eurjchem-154 76 14 h h PROPN eurjchem-154 76 15 s s PART eurjchem-154 76 16 br br PROPN eurjchem-154 76 17 n n PRON eurjchem-154 76 18 nch3 nch3 PROPN eurjchem-154 76 19 ch3 ch3 PROPN eurjchem-154 76 20 n n CCONJ eurjchem-154 76 21 n n PROPN eurjchem-154 76 22 p p NOUN eurjchem-154 76 23 o o PROPN eurjchem-154 76 24 ar ar PROPN eurjchem-154 76 25 ch3 ch3 PROPN eurjchem-154 76 26 pho2s pho2s PROPN eurjchem-154 77 1 sbr sbr PROPN eurjchem-154 77 2 cho cho PROPN eurjchem-154 77 3 pho2s pho2s PROPN eurjchem-154 77 4 h3coc h3coc PROPN eurjchem-154 77 5 35 35 NUM eurjchem-154 77 6 4140 4140 NUM eurjchem-154 77 7 toluenetoluene(4 toluenetoluene(4 PROPN eurjchem-154 77 8 - - PUNCT eurjchem-154 77 9 clc6h4o)3p clc6h4o)3p NOUN eurjchem-154 77 10 ar=4 ar=4 ADV eurjchem-154 77 11 - - PUNCT eurjchem-154 77 12 clc6h4 clc6h4 NOUN eurjchem-154 77 13 36 36 NUM eurjchem-154 77 14 % % NOUN eurjchem-154 77 15 44 44 NUM eurjchem-154 77 16 % % NOUN eurjchem-154 77 17 ( ( PUNCT eurjchem-154 77 18 4 4 NUM eurjchem-154 77 19 - - PUNCT eurjchem-154 77 20 clc6h4o)3p clc6h4o)3p NOUN eurjchem-154 77 21     SPACE eurjchem-154 77 22 scheme scheme NOUN eurjchem-154 77 23     SPACE eurjchem-154 77 24 13 13 NUM eurjchem-154 77 25         SPACE eurjchem-154 77 26 ibrahim ibrahim PROPN eurjchem-154 77 27     SPACE eurjchem-154 77 28 et et PROPN eurjchem-154 77 29     SPACE eurjchem-154 77 30 al al PROPN eurjchem-154 77 31 . . PROPN eurjchem-154 77 32     SPACE eurjchem-154 78 1 [ [ X eurjchem-154 78 2 27 27 NUM eurjchem-154 78 3 ] ] PUNCT eurjchem-154 78 4     SPACE eurjchem-154 78 5 reported report VERB eurjchem-154 78 6     SPACE eurjchem-154 78 7 the the DET eurjchem-154 78 8     SPACE eurjchem-154 78 9 synthesis synthesis NOUN eurjchem-154 78 10     SPACE eurjchem-154 78 11 of of ADP eurjchem-154 78 12     SPACE eurjchem-154 78 13 novel novel NOUN eurjchem-154 78 14     SPACE eurjchem-154 78 15 1,2‐ 1,2‐ NUM eurjchem-154 78 16 thiaphospholo[4,5‐e][1,2,4]triazines thiaphospholo[4,5‐e][1,2,4]triazine NOUN eurjchem-154 78 17     SPACE eurjchem-154 78 18 43 43 NUM eurjchem-154 78 19     SPACE eurjchem-154 78 20 from from ADP eurjchem-154 78 21     SPACE eurjchem-154 78 22 treatment treatment NOUN eurjchem-154 78 23     SPACE eurjchem-154 78 24 of of ADP eurjchem-154 78 25     SPACE eurjchem-154 78 26 5‐ 5‐ ADP eurjchem-154 78 27 arylmethyl‐3‐phenyl‐4,5‐dihydro‐1,2,4‐triazin‐6(1h)‐one arylmethyl‐3‐phenyl‐4,5‐dihydro‐1,2,4‐triazin‐6(1h)‐one NOUN eurjchem-154 78 28     SPACE eurjchem-154 78 29 ( ( PUNCT eurjchem-154 78 30 42 42 NUM eurjchem-154 78 31 ) ) PUNCT eurjchem-154 78 32     SPACE eurjchem-154 78 33 with with ADP eurjchem-154 78 34     SPACE eurjchem-154 78 35 lawesson lawesson PROPN eurjchem-154 78 36 's 's PART eurjchem-154 78 37     SPACE eurjchem-154 78 38 reagent reagent NOUN eurjchem-154 78 39     SPACE eurjchem-154 78 40 in in ADP eurjchem-154 78 41     SPACE eurjchem-154 78 42 boiling boil VERB eurjchem-154 78 43     SPACE eurjchem-154 78 44 toluene toluene NOUN eurjchem-154 78 45     SPACE eurjchem-154 78 46 ( ( PUNCT eurjchem-154 78 47 scheme scheme NOUN eurjchem-154 78 48     SPACE eurjchem-154 78 49 14 14 NUM eurjchem-154 78 50 ) ) PUNCT eurjchem-154 78 51 . . PUNCT eurjchem-154 78 52         SPACE eurjchem-154 79 1 n n PRON eurjchem-154 79 2 h h NOUN eurjchem-154 79 3 n n CCONJ eurjchem-154 80 1 n n NOUN eurjchem-154 80 2 h h NOUN eurjchem-154 81 1 o o NOUN eurjchem-154 81 2 ph ph PROPN eurjchem-154 81 3 ar ar PROPN eurjchem-154 81 4 p p PROPN eurjchem-154 81 5 s s PROPN eurjchem-154 81 6 p p NOUN eurjchem-154 81 7 ss ss PROPN eurjchem-154 81 8 s s NOUN eurjchem-154 81 9 omemeo omemeo NOUN eurjchem-154 81 10 p p PROPN eurjchem-154 81 11 s s PROPN eurjchem-154 81 12 s s X eurjchem-154 81 13 ome ome NOUN eurjchem-154 81 14 n n PRON eurjchem-154 81 15 h h NOUN eurjchem-154 81 16 n n CCONJ eurjchem-154 82 1 n n NOUN eurjchem-154 82 2 h h NOUN eurjchem-154 82 3 s s NOUN eurjchem-154 82 4 ph ph PROPN eurjchem-154 82 5 ar ar PROPN eurjchem-154 82 6 n n PROPN eurjchem-154 82 7 h h NOUN eurjchem-154 82 8 n n CCONJ eurjchem-154 82 9 n n ADV eurjchem-154 82 10 ph ph NOUN eurjchem-154 82 11 s s PROPN eurjchem-154 82 12 p p NOUN eurjchem-154 82 13 ar ar PROPN eurjchem-154 82 14 s s PART eurjchem-154 82 15 meo meo X eurjchem-154 82 16 + + CCONJ eurjchem-154 82 17 2 2 NUM eurjchem-154 82 18 + + SYM eurjchem-154 82 19 1:1.8 1:1.8 NUM eurjchem-154 82 20 by by ADP eurjchem-154 82 21 molestoluene42 molestoluene42 NOUN eurjchem-154 82 22 43 43 NUM eurjchem-154 82 23 61 61 NUM eurjchem-154 82 24 - - SYM eurjchem-154 82 25 68 68 NUM eurjchem-154 82 26 % % NOUN eurjchem-154 82 27 ar ar NOUN eurjchem-154 82 28 = = NOUN eurjchem-154 82 29 ph ph ADJ eurjchem-154 82 30 , , PUNCT eurjchem-154 82 31 4 4 NUM eurjchem-154 82 32 - - PUNCT eurjchem-154 82 33 brc6h4 brc6h4 NOUN eurjchem-154 82 34     SPACE eurjchem-154 82 35 scheme scheme NOUN eurjchem-154 82 36     SPACE eurjchem-154 82 37 14 14 NUM eurjchem-154 82 38         SPACE eurjchem-154 82 39 treatment treatment NOUN eurjchem-154 82 40     SPACE eurjchem-154 82 41 of of ADP eurjchem-154 82 42     SPACE eurjchem-154 82 43 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐1,2,4‐ 5,6‐bis(4‐bromophenyl)‐3‐hydrazino‐1,2,4‐ NUM eurjchem-154 82 44 triazine triazine NOUN eurjchem-154 82 45     SPACE eurjchem-154 82 46 ( ( PUNCT eurjchem-154 82 47 10 10 NUM eurjchem-154 82 48 ) ) PUNCT eurjchem-154 82 49     SPACE eurjchem-154 82 50 with with ADP eurjchem-154 82 51     SPACE eurjchem-154 82 52 diethyl diethyl NOUN eurjchem-154 82 53     SPACE eurjchem-154 82 54 phosphite phosphite NOUN eurjchem-154 82 55     SPACE eurjchem-154 82 56 and and CCONJ eurjchem-154 82 57     SPACE eurjchem-154 82 58 chlorophenyldichloro‐ chlorophenyldichloro‐ NOUN eurjchem-154 82 59 thiophosphate thiophosphate ADJ eurjchem-154 82 60 , , PUNCT eurjchem-154 82 61     SPACE eurjchem-154 82 62 in in ADP eurjchem-154 82 63     SPACE eurjchem-154 82 64 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 82 65     SPACE eurjchem-154 82 66 containing contain VERB eurjchem-154 82 67     SPACE eurjchem-154 82 68 few few ADJ eurjchem-154 82 69     SPACE eurjchem-154 82 70 drops drop VERB eurjchem-154 82 71     SPACE eurjchem-154 82 72 of of ADP eurjchem-154 82 73     SPACE eurjchem-154 82 74 piperidine piperidine NOUN eurjchem-154 82 75     SPACE eurjchem-154 82 76 under under ADP eurjchem-154 82 77     SPACE eurjchem-154 82 78 reflux reflux NOUN eurjchem-154 82 79 , , PUNCT eurjchem-154 82 80     SPACE eurjchem-154 82 81 led lead VERB eurjchem-154 82 82     SPACE eurjchem-154 82 83 to to ADP eurjchem-154 82 84     SPACE eurjchem-154 82 85 the the DET eurjchem-154 82 86     SPACE eurjchem-154 82 87 direct direct ADJ eurjchem-154 82 88     SPACE eurjchem-154 82 89 formation formation NOUN eurjchem-154 82 90     SPACE eurjchem-154 82 91 of of ADP eurjchem-154 82 92     SPACE eurjchem-154 82 93 the the DET eurjchem-154 82 94     SPACE eurjchem-154 82 95 1,2,4,3‐triazaphospholo[4,5‐b][1,2,4]triazine 1,2,4,3‐triazaphospholo[4,5‐b][1,2,4]triazine NUM eurjchem-154 82 96     SPACE eurjchem-154 82 97 derivatives derivative NOUN eurjchem-154 82 98     SPACE eurjchem-154 82 99 44 44 NUM eurjchem-154 82 100     SPACE eurjchem-154 82 101 and and CCONJ eurjchem-154 82 102     SPACE eurjchem-154 82 103 45 45 NUM eurjchem-154 82 104 , , PUNCT eurjchem-154 82 105     SPACE eurjchem-154 82 106 respectively respectively ADV eurjchem-154 82 107 . . PUNCT eurjchem-154 82 108     SPACE eurjchem-154 83 1 also also ADV eurjchem-154 83 2 , , PUNCT eurjchem-154 83 3     SPACE eurjchem-154 83 4 6,7‐bis(4‐bromophenyl)‐2,3‐ 6,7‐bis(4‐bromophenyl)‐2,3‐ NUM eurjchem-154 83 5 dihydro‐3,3,3‐triphenyl‐3‐λ5‐1,2,4,3‐triazaphospholino[4,5‐b dihydro‐3,3,3‐triphenyl‐3‐λ5‐1,2,4,3‐triazaphospholino[4,5‐b PROPN eurjchem-154 83 6 ] ] X eurjchem-154 83 7     SPACE eurjchem-154 83 8 [ [ X eurjchem-154 83 9 1,2,4]triazine 1,2,4]triazine NOUN eurjchem-154 83 10     SPACE eurjchem-154 83 11 ( ( PUNCT eurjchem-154 83 12 46 46 NUM eurjchem-154 83 13 ) ) PUNCT eurjchem-154 83 14     SPACE eurjchem-154 83 15 was be AUX eurjchem-154 83 16     SPACE eurjchem-154 83 17 obtained obtain VERB eurjchem-154 83 18     SPACE eurjchem-154 83 19 from from ADP eurjchem-154 83 20     SPACE eurjchem-154 83 21 stirring stirring NOUN eurjchem-154 83 22     SPACE eurjchem-154 83 23 of of ADP eurjchem-154 83 24     SPACE eurjchem-154 83 25 compound compound NOUN eurjchem-154 83 26     SPACE eurjchem-154 83 27 10 10 NUM eurjchem-154 83 28     SPACE eurjchem-154 83 29 with with ADP eurjchem-154 83 30     SPACE eurjchem-154 83 31 dibromo‐triphenylphosphorane dibromo‐triphenylphosphorane PROPN eurjchem-154 83 32 , , PUNCT eurjchem-154 83 33     SPACE eurjchem-154 83 34 in in ADP eurjchem-154 83 35     SPACE eurjchem-154 83 36 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 83 37     SPACE eurjchem-154 83 38 containing contain VERB eurjchem-154 83 39     SPACE eurjchem-154 83 40 piperidine piperidine NOUN eurjchem-154 83 41     SPACE eurjchem-154 83 42 at at ADP eurjchem-154 83 43     SPACE eurjchem-154 83 44 room room NOUN eurjchem-154 83 45     SPACE eurjchem-154 83 46 temperature temperature NOUN eurjchem-154 83 47     SPACE eurjchem-154 83 48 for for ADP eurjchem-154 83 49     SPACE eurjchem-154 83 50 24 24 NUM eurjchem-154 83 51     SPACE eurjchem-154 83 52 hours hour NOUN eurjchem-154 83 53     SPACE eurjchem-154 83 54 ( ( PUNCT eurjchem-154 83 55 scheme scheme NOUN eurjchem-154 83 56     SPACE eurjchem-154 83 57 15 15 NUM eurjchem-154 83 58 ) ) PUNCT eurjchem-154 83 59     SPACE eurjchem-154 84 1 [ [ X eurjchem-154 84 2 25 25 NUM eurjchem-154 84 3 ] ] PUNCT eurjchem-154 84 4 . . PUNCT eurjchem-154 84 5     SPACE eurjchem-154 84 6 4‐{(4‐chlorophenyl)methylidene]amino}‐3‐mercapto‐ 4‐{(4‐chlorophenyl)methylidene]amino}‐3‐mercapto‐ NOUN eurjchem-154 85 1 6‐methyl‐1,2,4‐triazin‐5(4h)‐one 6‐methyl‐1,2,4‐triazin‐5(4h)‐one NUM eurjchem-154 85 2     SPACE eurjchem-154 85 3 ( ( PUNCT eurjchem-154 85 4 48 48 NUM eurjchem-154 85 5 ) ) PUNCT eurjchem-154 85 6     SPACE eurjchem-154 85 7 was be AUX eurjchem-154 85 8     SPACE eurjchem-154 85 9 heated heated ADJ eurjchem-154 85 10     SPACE eurjchem-154 85 11 under under ADP eurjchem-154 85 12     SPACE eurjchem-154 85 13 reflux reflux NOUN eurjchem-154 85 14     SPACE eurjchem-154 85 15 with with ADP eurjchem-154 85 16     SPACE eurjchem-154 85 17 diphenylphosphoryl diphenylphosphoryl NOUN eurjchem-154 85 18     SPACE eurjchem-154 85 19 acetonitrile acetonitrile NOUN eurjchem-154 85 20 , , PUNCT eurjchem-154 85 21     SPACE eurjchem-154 85 22 for for ADP eurjchem-154 85 23     SPACE eurjchem-154 85 24 12 12 NUM eurjchem-154 85 25     SPACE eurjchem-154 85 26 hours hour NOUN eurjchem-154 85 27     SPACE eurjchem-154 85 28 in in ADP eurjchem-154 85 29     SPACE eurjchem-154 85 30 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 85 31     SPACE eurjchem-154 85 32 in in ADP eurjchem-154 85 33     SPACE eurjchem-154 85 34 the the DET eurjchem-154 85 35     SPACE eurjchem-154 85 36 presence presence NOUN eurjchem-154 85 37     SPACE eurjchem-154 85 38 of of ADP eurjchem-154 85 39     SPACE eurjchem-154 85 40 sodium sodium NOUN eurjchem-154 85 41     SPACE eurjchem-154 85 42 hydride hydride NOUN eurjchem-154 85 43     SPACE eurjchem-154 85 44 as as ADP eurjchem-154 85 45     SPACE eurjchem-154 85 46 a a DET eurjchem-154 85 47     SPACE eurjchem-154 85 48 catalyst catalyst NOUN eurjchem-154 85 49 , , PUNCT eurjchem-154 85 50     SPACE eurjchem-154 85 51 to to PART eurjchem-154 85 52     SPACE eurjchem-154 85 53 afford afford VERB eurjchem-154 85 54     SPACE eurjchem-154 85 55 7‐(4‐chlorophenyl)‐8‐(diphenylphosphoryl)‐ 7‐(4‐chlorophenyl)‐8‐(diphenylphosphoryl)‐ NOUN eurjchem-154 85 56 3‐methyl‐4‐oxo‐4,8‐dihydropyrazolo[5,1‐c][1,2,4]triazine‐8‐ 3‐methyl‐4‐oxo‐4,8‐dihydropyrazolo[5,1‐c][1,2,4]triazine‐8‐ NUM eurjchem-154 85 57 carbonitrile carbonitrile NOUN eurjchem-154 85 58     SPACE eurjchem-154 85 59 ( ( PUNCT eurjchem-154 85 60 52 52 NUM eurjchem-154 85 61 ) ) PUNCT eurjchem-154 85 62     SPACE eurjchem-154 85 63 and and CCONJ eurjchem-154 85 64     SPACE eurjchem-154 85 65 not not PART eurjchem-154 85 66     SPACE eurjchem-154 85 67 the the DET eurjchem-154 85 68     SPACE eurjchem-154 85 69 other other ADJ eurjchem-154 85 70     SPACE eurjchem-154 85 71 expected expect VERB eurjchem-154 85 72     SPACE eurjchem-154 85 73 product product NOUN eurjchem-154 85 74     SPACE eurjchem-154 85 75 1,3,4‐ 1,3,4‐ NUM eurjchem-154 85 76 thiadiazaphosphepine thiadiazaphosphepine NOUN eurjchem-154 85 77     SPACE eurjchem-154 85 78 derivative derivative ADJ eurjchem-154 85 79     SPACE eurjchem-154 85 80 50 50 NUM eurjchem-154 85 81 . . PUNCT eurjchem-154 85 82     SPACE eurjchem-154 86 1 the the DET eurjchem-154 86 2     SPACE eurjchem-154 86 3 reaction reaction NOUN eurjchem-154 86 4     SPACE eurjchem-154 86 5 pathway pathway NOUN eurjchem-154 86 6     SPACE eurjchem-154 86 7 proceeded proceed VERB eurjchem-154 86 8     SPACE eurjchem-154 86 9 via via ADP eurjchem-154 86 10     SPACE eurjchem-154 86 11 c‐nucleophilic c‐nucleophilic ADJ eurjchem-154 86 12     SPACE eurjchem-154 86 13 attack attack NOUN eurjchem-154 86 14     SPACE eurjchem-154 86 15 by by ADP eurjchem-154 86 16     SPACE eurjchem-154 86 17 the the DET eurjchem-154 86 18     SPACE eurjchem-154 86 19 active active ADJ eurjchem-154 86 20     SPACE eurjchem-154 86 21 methylene methylene NOUN eurjchem-154 86 22     SPACE eurjchem-154 86 23 of of ADP eurjchem-154 86 24     SPACE eurjchem-154 86 25 diphenylphosphoryl diphenylphosphoryl NOUN eurjchem-154 86 26     SPACE eurjchem-154 86 27 acetonitrile acetonitrile NOUN eurjchem-154 86 28     SPACE eurjchem-154 86 29 on on ADP eurjchem-154 86 30     SPACE eurjchem-154 86 31 the the PRON eurjchem-154 86 32     SPACE eurjchem-154 86 33 n n CCONJ eurjchem-154 86 34 – – PUNCT eurjchem-154 86 35 n n CCONJ eurjchem-154 86 36 = = SYM eurjchem-154 86 37 ch ch NOUN eurjchem-154 86 38 – – PUNCT eurjchem-154 86 39 ar ar NOUN eurjchem-154 86 40     SPACE eurjchem-154 86 41 moiety moiety NOUN eurjchem-154 86 42     SPACE eurjchem-154 86 43 to to PART eurjchem-154 86 44     SPACE eurjchem-154 86 45 give give VERB eurjchem-154 86 46     SPACE eurjchem-154 86 47 the the DET eurjchem-154 86 48     SPACE eurjchem-154 86 49 intermediate intermediate ADJ eurjchem-154 86 50     SPACE eurjchem-154 86 51 49 49 NUM eurjchem-154 86 52 , , PUNCT eurjchem-154 86 53     SPACE eurjchem-154 86 54 which which DET eurjchem-154 86 55     SPACE eurjchem-154 86 56 underwent underwent NOUN eurjchem-154 86 57     SPACE eurjchem-154 86 58 cyclization cyclization NOUN eurjchem-154 86 59     SPACE eurjchem-154 86 60 by by ADP eurjchem-154 86 61     SPACE eurjchem-154 86 62 elimination elimination NOUN eurjchem-154 86 63     SPACE eurjchem-154 86 64 of of ADP eurjchem-154 86 65     SPACE eurjchem-154 86 66 one one NUM eurjchem-154 86 67     SPACE eurjchem-154 86 68 molecule molecule NOUN eurjchem-154 86 69     SPACE eurjchem-154 86 70 of of ADP eurjchem-154 86 71     SPACE eurjchem-154 86 72 hydrogen hydrogen NOUN eurjchem-154 86 73     SPACE eurjchem-154 86 74 sulfide sulfide NOUN eurjchem-154 86 75     SPACE eurjchem-154 86 76 followed follow VERB eurjchem-154 86 77     SPACE eurjchem-154 86 78 by by ADP eurjchem-154 86 79     SPACE eurjchem-154 86 80 an an DET eurjchem-154 86 81     SPACE eurjchem-154 86 82 air air NOUN eurjchem-154 86 83     SPACE eurjchem-154 86 84 oxidation oxidation NOUN eurjchem-154 86 85     SPACE eurjchem-154 86 86 ( ( PUNCT eurjchem-154 86 87 route route NOUN eurjchem-154 86 88     SPACE eurjchem-154 86 89 b b NOUN eurjchem-154 86 90 ) ) PUNCT eurjchem-154 86 91     SPACE eurjchem-154 86 92 ( ( PUNCT eurjchem-154 86 93 scheme scheme NOUN eurjchem-154 86 94     SPACE eurjchem-154 86 95 16 16 NUM eurjchem-154 86 96 ) ) PUNCT eurjchem-154 86 97     SPACE eurjchem-154 87 1 [ [ X eurjchem-154 87 2 28 28 NUM eurjchem-154 87 3 ] ] PUNCT eurjchem-154 87 4 . . PUNCT eurjchem-154 87 5     SPACE eurjchem-154 87 6 on on ADP eurjchem-154 87 7     SPACE eurjchem-154 87 8 the the DET eurjchem-154 87 9     SPACE eurjchem-154 87 10 other other ADJ eurjchem-154 87 11     SPACE eurjchem-154 87 12 hand hand NOUN eurjchem-154 87 13 , , PUNCT eurjchem-154 87 14     SPACE eurjchem-154 87 15 4‐amino‐3‐hydrazino‐1,2,4‐triazin‐ 4‐amino‐3‐hydrazino‐1,2,4‐triazin‐ NOUN eurjchem-154 87 16 5(4h)‐one 5(4h)‐one NUM eurjchem-154 87 17     SPACE eurjchem-154 87 18 ( ( PUNCT eurjchem-154 87 19 53 53 NUM eurjchem-154 87 20 ) ) PUNCT eurjchem-154 87 21     SPACE eurjchem-154 87 22 was be AUX eurjchem-154 87 23     SPACE eurjchem-154 87 24 used use VERB eurjchem-154 87 25     SPACE eurjchem-154 87 26 as as ADP eurjchem-154 87 27     SPACE eurjchem-154 87 28 starting start VERB eurjchem-154 87 29     SPACE eurjchem-154 87 30 material material NOUN eurjchem-154 87 31     SPACE eurjchem-154 87 32 in in ADP eurjchem-154 87 33     SPACE eurjchem-154 87 34 one‐pot one‐pot NOUN eurjchem-154 87 35     SPACE eurjchem-154 87 36 three three NUM eurjchem-154 87 37     SPACE eurjchem-154 87 38 components component NOUN eurjchem-154 87 39     SPACE eurjchem-154 87 40 reaction reaction NOUN eurjchem-154 87 41     SPACE eurjchem-154 87 42 with with ADP eurjchem-154 87 43     SPACE eurjchem-154 87 44 acetaldehyde acetaldehyde NOUN eurjchem-154 87 45     SPACE eurjchem-154 87 46 and and CCONJ eurjchem-154 87 47     SPACE eurjchem-154 87 48 phenylphosphonic phenylphosphonic NOUN eurjchem-154 87 49     SPACE eurjchem-154 87 50 dichloride dichloride NOUN eurjchem-154 87 51 , , PUNCT eurjchem-154 87 52     SPACE eurjchem-154 87 53 in in ADP eurjchem-154 87 54     SPACE eurjchem-154 87 55 boiling boiling NOUN eurjchem-154 87 56     SPACE eurjchem-154 87 57 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 87 58     SPACE eurjchem-154 87 59 containing contain VERB eurjchem-154 87 60     SPACE eurjchem-154 87 61 a a DET eurjchem-154 87 62     SPACE eurjchem-154 87 63 catalytic catalytic ADJ eurjchem-154 87 64     SPACE eurjchem-154 87 65 amount amount NOUN eurjchem-154 87 66     SPACE eurjchem-154 87 67 of of ADP eurjchem-154 87 68     SPACE eurjchem-154 87 69 triethylamine triethylamine NOUN eurjchem-154 87 70 , , PUNCT eurjchem-154 87 71     SPACE eurjchem-154 87 72 to to PART eurjchem-154 87 73     SPACE eurjchem-154 87 74 yield yield VERB eurjchem-154 87 75     SPACE eurjchem-154 87 76 1,2,4,3‐triazaphospholo[5,1‐ 1,2,4,3‐triazaphospholo[5,1‐ NUM eurjchem-154 87 77 c][1,2,4]triazinone c][1,2,4]triazinone ADJ eurjchem-154 87 78     SPACE eurjchem-154 87 79 derivative derivative NOUN eurjchem-154 87 80     SPACE eurjchem-154 87 81 54 54 NUM eurjchem-154 87 82     SPACE eurjchem-154 87 83 ( ( PUNCT eurjchem-154 87 84 scheme scheme NOUN eurjchem-154 87 85     SPACE eurjchem-154 87 86 17 17 NUM eurjchem-154 87 87 ) ) PUNCT eurjchem-154 87 88     SPACE eurjchem-154 88 1 [ [ X eurjchem-154 88 2 28 28 NUM eurjchem-154 88 3 ] ] PUNCT eurjchem-154 88 4 . . PUNCT eurjchem-154 88 5     SPACE eurjchem-154 89 1 6‐methyl‐2‐oxido‐2‐phenyl‐1,2‐dihydro‐7h‐[1,3,4,2]thiadi 6‐methyl‐2‐oxido‐2‐phenyl‐1,2‐dihydro‐7h‐[1,3,4,2]thiadi NOUN eurjchem-154 89 2     SPACE eurjchem-154 89 3 azaphospholo[5,4‐c][1,2,4 azaphospholo[5,4‐c][1,2,4 PRON eurjchem-154 89 4 ] ] X eurjchem-154 89 5     SPACE eurjchem-154 89 6 triazin‐5‐one triazin‐5‐one NOUN eurjchem-154 89 7     SPACE eurjchem-154 89 8 ( ( PUNCT eurjchem-154 89 9 55 55 NUM eurjchem-154 89 10 ) ) PUNCT eurjchem-154 89 11     SPACE eurjchem-154 89 12 was be AUX eurjchem-154 89 13     SPACE eurjchem-154 89 14 synthe‐sized synthe‐size VERB eurjchem-154 89 15     SPACE eurjchem-154 89 16 by by ADP eurjchem-154 89 17     SPACE eurjchem-154 89 18 the the DET eurjchem-154 89 19     SPACE eurjchem-154 89 20 reaction reaction NOUN eurjchem-154 89 21     SPACE eurjchem-154 89 22 of of ADP eurjchem-154 89 23     SPACE eurjchem-154 89 24 4‐amino‐3‐mercapto‐6‐methyl‐1,2,4‐triazin‐ 4‐amino‐3‐mercapto‐6‐methyl‐1,2,4‐triazin‐ NOUN eurjchem-154 89 25 5(4h)‐one 5(4h)‐one NUM eurjchem-154 89 26     SPACE eurjchem-154 89 27 ( ( PUNCT eurjchem-154 89 28 47 47 NUM eurjchem-154 89 29 ) ) PUNCT eurjchem-154 89 30     SPACE eurjchem-154 89 31 with with ADP eurjchem-154 89 32     SPACE eurjchem-154 89 33 phenylphosphonic phenylphosphonic VERB eurjchem-154 89 34     SPACE eurjchem-154 89 35 dichloride dichloride NOUN eurjchem-154 89 36     SPACE eurjchem-154 89 37 in in ADP eurjchem-154 89 38     SPACE eurjchem-154 89 39 tetra tetra NOUN eurjchem-154 89 40     SPACE eurjchem-154 89 41 hydrofuran hydrofuran NOUN eurjchem-154 89 42     SPACE eurjchem-154 89 43 containing contain VERB eurjchem-154 89 44     SPACE eurjchem-154 89 45 two two NUM eurjchem-154 89 46     SPACE eurjchem-154 89 47 equivalent equivalent ADJ eurjchem-154 89 48     SPACE eurjchem-154 89 49 amounts amount NOUN eurjchem-154 89 50     SPACE eurjchem-154 89 51 of of ADP eurjchem-154 89 52     SPACE eurjchem-154 89 53 triethyl triethyl NOUN eurjchem-154 89 54     SPACE eurjchem-154 89 55 amine amine NOUN eurjchem-154 89 56     SPACE eurjchem-154 89 57 to to PART eurjchem-154 89 58     SPACE eurjchem-154 89 59 remove remove VERB eurjchem-154 89 60     SPACE eurjchem-154 89 61 hydrogen hydrogen NOUN eurjchem-154 89 62     SPACE eurjchem-154 89 63 chloride chloride NOUN eurjchem-154 89 64     SPACE eurjchem-154 89 65 ( ( PUNCT eurjchem-154 89 66 scheme scheme NOUN eurjchem-154 89 67     SPACE eurjchem-154 89 68 18 18 NUM eurjchem-154 89 69 ) ) PUNCT eurjchem-154 89 70     SPACE eurjchem-154 90 1 [ [ X eurjchem-154 90 2 28 28 NUM eurjchem-154 90 3 ] ] PUNCT eurjchem-154 90 4 . . PUNCT eurjchem-154 90 5         SPACE eurjchem-154 91 1 2.3.3 2.3.3 NUM eurjchem-154 91 2 . . PUNCT eurjchem-154 91 3     SPACE eurjchem-154 91 4 six­membered six­membere VERB eurjchem-154 91 5     SPACE eurjchem-154 91 6 rings ring NOUN eurjchem-154 91 7         SPACE eurjchem-154 91 8 the the DET eurjchem-154 91 9     SPACE eurjchem-154 91 10 interaction interaction NOUN eurjchem-154 91 11     SPACE eurjchem-154 91 12 between between ADP eurjchem-154 91 13     SPACE eurjchem-154 91 14 5,6‐bis(4‐bromophenyl)‐3‐ 5,6‐bis(4‐bromophenyl)‐3‐ NUM eurjchem-154 91 15 hydrazino‐1,2,4‐triazine hydrazino‐1,2,4‐triazine NOUN eurjchem-154 91 16     SPACE eurjchem-154 91 17 ( ( PUNCT eurjchem-154 91 18 10 10 NUM eurjchem-154 91 19 ) ) PUNCT eurjchem-154 91 20     SPACE eurjchem-154 91 21 and and CCONJ eurjchem-154 91 22     SPACE eurjchem-154 91 23 diphenyl(2,4,6‐ diphenyl(2,4,6‐ PROPN eurjchem-154 91 24 trimethylbenzoyl trimethylbenzoyl PROPN eurjchem-154 91 25 ) ) PUNCT eurjchem-154 91 26     SPACE eurjchem-154 91 27 phosphorus phosphorus NOUN eurjchem-154 91 28     SPACE eurjchem-154 91 29 oxide oxide NOUN eurjchem-154 91 30     SPACE eurjchem-154 91 31 under under ADP eurjchem-154 91 32     SPACE eurjchem-154 91 33 reflux reflux NOUN eurjchem-154 91 34     SPACE eurjchem-154 91 35 in in ADP eurjchem-154 91 36     SPACE eurjchem-154 91 37 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 91 38     SPACE eurjchem-154 91 39 resulted result VERB eurjchem-154 91 40     SPACE eurjchem-154 91 41 7,8‐bis‐(4‐bromophenyl)‐4,4‐diphen 7,8‐bis‐(4‐bromophenyl)‐4,4‐diphen NOUN eurjchem-154 91 42     SPACE eurjchem-154 91 43 yl‐3‐(2,4,6‐trimethylphenyl)‐4h‐4‐λ5‐1,2,4‐triazino[3,2‐c yl‐3‐(2,4,6‐trimethylphenyl)‐4h‐4‐λ5‐1,2,4‐triazino[3,2‐c PROPN eurjchem-154 91 44 ] ] X eurjchem-154 91 45       SPACE eurjchem-154 91 46 abdel­rahman abdel­rahman ADJ eurjchem-154 91 47     SPACE eurjchem-154 91 48 et et NOUN eurjchem-154 91 49     SPACE eurjchem-154 91 50 al al PROPN eurjchem-154 91 51 . . PROPN eurjchem-154 91 52     SPACE eurjchem-154 91 53 / / SYM eurjchem-154 91 54     SPACE eurjchem-154 91 55 european european ADJ eurjchem-154 91 56     SPACE eurjchem-154 91 57 journal journal NOUN eurjchem-154 91 58     SPACE eurjchem-154 91 59 of of ADP eurjchem-154 91 60     SPACE eurjchem-154 91 61 chemistry chemistry NOUN eurjchem-154 91 62     SPACE eurjchem-154 91 63 1 1 NUM eurjchem-154 91 64     SPACE eurjchem-154 91 65 ( ( PUNCT eurjchem-154 91 66 4 4 NUM eurjchem-154 91 67 ) ) PUNCT eurjchem-154 91 68     SPACE eurjchem-154 91 69 ( ( PUNCT eurjchem-154 91 70 2010 2010 NUM eurjchem-154 91 71 ) ) PUNCT eurjchem-154 91 72     SPACE eurjchem-154 91 73 388­396 388­396 NUM eurjchem-154 91 74     SPACE eurjchem-154 91 75 393 393 NUM eurjchem-154 91 76     SPACE eurjchem-154 91 77 n n CCONJ eurjchem-154 91 78 n n PRON eurjchem-154 91 79 nar nar NOUN eurjchem-154 91 80 ar ar NOUN eurjchem-154 91 81 nhnh2 nhnh2 NOUN eurjchem-154 92 1 o o NOUN eurjchem-154 93 1 p p X eurjchem-154 93 2 h h NOUN eurjchem-154 93 3 oeteto oeteto NOUN eurjchem-154 93 4 n n ADP eurjchem-154 93 5 nar nar NOUN eurjchem-154 93 6 ar ar PROPN eurjchem-154 93 7 n n PROPN eurjchem-154 93 8 n n PROPN eurjchem-154 93 9 nh nh PROPN eurjchem-154 93 10 p p X eurjchem-154 93 11 o o NOUN eurjchem-154 93 12 h h NOUN eurjchem-154 93 13 n n ADP eurjchem-154 93 14 nar nar NOUN eurjchem-154 93 15 ar ar PROPN eurjchem-154 93 16 n n PROPN eurjchem-154 93 17 n n PROPN eurjchem-154 93 18 nh nh PROPN eurjchem-154 93 19 p p X eurjchem-154 93 20 s s PROPN eurjchem-154 93 21 cl cl NOUN eurjchem-154 93 22 p p X eurjchem-154 93 23 s s NOUN eurjchem-154 93 24 cl cl NOUN eurjchem-154 93 25 cl cl NOUN eurjchem-154 93 26 cl cl NOUN eurjchem-154 93 27 n n CCONJ eurjchem-154 93 28 nar nar NOUN eurjchem-154 93 29 ar ar PROPN eurjchem-154 93 30 n n CCONJ eurjchem-154 93 31 n n PROPN eurjchem-154 93 32 nh nh NOUN eurjchem-154 93 33 p p X eurjchem-154 93 34 ph ph ADJ eurjchem-154 93 35 ph ph ADJ eurjchem-154 93 36 ph ph NOUN eurjchem-154 93 37 ( ( PUNCT eurjchem-154 93 38 ph)3pbr2 ph)3pbr2 NOUN eurjchem-154 93 39 ar= ar= VERB eurjchem-154 93 40 4 4 NUM eurjchem-154 93 41 - - PUNCT eurjchem-154 93 42 brc6h4 brc6h4 NOUN eurjchem-154 93 43 reflux reflux NOUN eurjchem-154 93 44 thf thf NOUN eurjchem-154 93 45 - - PUNCT eurjchem-154 93 46 piperidine piperidine NOUN eurjchem-154 93 47 10 10 NUM eurjchem-154 93 48 44 44 NUM eurjchem-154 93 49 45 45 NUM eurjchem-154 93 50 reflux reflux NOUN eurjchem-154 93 51 thf thf NOUN eurjchem-154 93 52 - - PUNCT eurjchem-154 93 53 piperidine piperidine NOUN eurjchem-154 93 54 stirring stirring NOUN eurjchem-154 93 55 thf thf NOUN eurjchem-154 93 56 - - PUNCT eurjchem-154 93 57 piperidine piperidine NOUN eurjchem-154 93 58 46 46 NUM eurjchem-154 93 59 19%38 19%38 NUM eurjchem-154 93 60 % % NOUN eurjchem-154 93 61 23 23 NUM eurjchem-154 93 62 % % NOUN eurjchem-154 93 63         SPACE eurjchem-154 93 64 scheme scheme NOUN eurjchem-154 93 65     SPACE eurjchem-154 93 66 15 15 NUM eurjchem-154 93 67             SPACE eurjchem-154 93 68 n n CCONJ eurjchem-154 93 69 n n PRON eurjchem-154 93 70 nch3 nch3 PROPN eurjchem-154 93 71 o o INTJ eurjchem-154 94 1 sh sh PROPN eurjchem-154 94 2 nh2 nh2 PROPN eurjchem-154 94 3 n n CCONJ eurjchem-154 94 4 n n PRON eurjchem-154 94 5 nch3 nch3 PROPN eurjchem-154 95 1 o o NOUN eurjchem-154 95 2 sh sh PROPN eurjchem-154 95 3 n n PROPN eurjchem-154 95 4 ar ar PROPN eurjchem-154 95 5 n n CCONJ eurjchem-154 95 6 n n PRON eurjchem-154 95 7 nch3 nch3 PROPN eurjchem-154 95 8 o o X eurjchem-154 95 9 s s NOUN eurjchem-154 95 10 na na PROPN eurjchem-154 95 11 nh nh PROPN eurjchem-154 95 12 ar ar PROPN eurjchem-154 95 13 h h PROPN eurjchem-154 95 14 p p NOUN eurjchem-154 95 15 o o X eurjchem-154 95 16 ph ph NOUN eurjchem-154 95 17 ph ph NOUN eurjchem-154 95 18 cn cn PROPN eurjchem-154 95 19 h h PROPN eurjchem-154 95 20 n n PROPN eurjchem-154 95 21 nch3 nch3 PROPN eurjchem-154 96 1 o o PROPN eurjchem-154 96 2 n n CCONJ eurjchem-154 96 3 s s PROPN eurjchem-154 96 4 nh nh PROPN eurjchem-154 96 5 nh2 nh2 PROPN eurjchem-154 96 6 p p PROPN eurjchem-154 96 7 o o X eurjchem-154 96 8 ph ph ADJ eurjchem-154 96 9 ph ph PROPN eurjchem-154 96 10 h h PROPN eurjchem-154 96 11 ar ar PROPN eurjchem-154 96 12 n n PROPN eurjchem-154 96 13 nch3 nch3 PROPN eurjchem-154 96 14 o o PROPN eurjchem-154 96 15 n n CCONJ eurjchem-154 96 16 n n PROPN eurjchem-154 96 17 p p NOUN eurjchem-154 96 18 o o X eurjchem-154 96 19 ph ph NOUN eurjchem-154 96 20 ph ph PROPN eurjchem-154 96 21 cn cn PROPN eurjchem-154 96 22 ar ar PROPN eurjchem-154 96 23 ( ( PUNCT eurjchem-154 96 24 ph)2p(o)ch2cnthf ph)2p(o)ch2cnthf PROPN eurjchem-154 96 25 - - PUNCT eurjchem-154 96 26 nah nah NOUN eurjchem-154 96 27 archo archo NOUN eurjchem-154 96 28 etoh etoh PROPN eurjchem-154 96 29 n n CCONJ eurjchem-154 96 30 nch3 nch3 PROPN eurjchem-154 96 31 o o NOUN eurjchem-154 96 32 n n CCONJ eurjchem-154 96 33 n n PROPN eurjchem-154 96 34 p p NOUN eurjchem-154 96 35 o o X eurjchem-154 96 36 ph ph NOUN eurjchem-154 96 37 ph ph NOUN eurjchem-154 96 38 cn cn PROPN eurjchem-154 96 39 arh arh PROPN eurjchem-154 97 1 h h PROPN eurjchem-154 97 2 47 47 NUM eurjchem-154 97 3 route route NOUN eurjchem-154 97 4 a a DET eurjchem-154 97 5 route route NOUN eurjchem-154 97 6 b b PROPN eurjchem-154 97 7 ab ab PROPN eurjchem-154 97 8 48 48 NUM eurjchem-154 97 9 4950 4950 NUM eurjchem-154 97 10 51 51 NUM eurjchem-154 97 11 -h2s -h2s INTJ eurjchem-154 97 12 -h2 -h2 ADP eurjchem-154 97 13 52 52 NUM eurjchem-154 97 14 ar= ar= NOUN eurjchem-154 97 15 4 4 NUM eurjchem-154 97 16 - - PUNCT eurjchem-154 97 17 clc6h4 clc6h4 NOUN eurjchem-154 97 18 air air NOUN eurjchem-154 97 19 oxidation oxidation NOUN eurjchem-154 98 1 + + CCONJ eurjchem-154 98 2 46 46 NUM eurjchem-154 98 3 % % NOUN eurjchem-154 98 4     SPACE eurjchem-154 98 5 scheme scheme NOUN eurjchem-154 98 6     SPACE eurjchem-154 98 7 16 16 NUM eurjchem-154 98 8                 SPACE eurjchem-154 98 9 n n CCONJ eurjchem-154 98 10 n n PRON eurjchem-154 98 11 nch3 nch3 PROPN eurjchem-154 98 12 o o PROPN eurjchem-154 98 13 nh nh PROPN eurjchem-154 98 14 nh2 nh2 PROPN eurjchem-154 98 15 nh2 nh2 PROPN eurjchem-154 98 16 n n PRON eurjchem-154 98 17 nch3 nch3 PROPN eurjchem-154 98 18 o o PROPN eurjchem-154 98 19 n n CCONJ eurjchem-154 98 20 n n NOUN eurjchem-154 98 21 h h NOUN eurjchem-154 99 1 p p NOUN eurjchem-154 99 2 n n INTJ eurjchem-154 99 3 o o NOUN eurjchem-154 99 4 n n CCONJ eurjchem-154 99 5 ch3 ch3 PROPN eurjchem-154 99 6 ph ph PROPN eurjchem-154 99 7 thf thf PROPN eurjchem-154 99 8 - - PUNCT eurjchem-154 99 9 et3n et3n PROPN eurjchem-154 99 10 53 53 NUM eurjchem-154 99 11 i i NOUN eurjchem-154 99 12 ) ) PUNCT eurjchem-154 99 13 ch3cho ch3cho PROPN eurjchem-154 99 14 ii ii PROPN eurjchem-154 99 15 ) ) PUNCT eurjchem-154 99 16 php(o)cl2 php(o)cl2 NOUN eurjchem-154 99 17 54 54 NUM eurjchem-154 99 18 77 77 NUM eurjchem-154 99 19 % % NOUN eurjchem-154 99 20 scheme scheme NOUN eurjchem-154 99 21     SPACE eurjchem-154 99 22 17 17 NUM eurjchem-154 99 23             SPACE eurjchem-154 99 24 n n CCONJ eurjchem-154 99 25 n n PRON eurjchem-154 99 26 nch3 nch3 PROPN eurjchem-154 100 1 o o INTJ eurjchem-154 100 2 sh sh PROPN eurjchem-154 100 3 nh2 nh2 PROPN eurjchem-154 100 4 n n PRON eurjchem-154 100 5 nch3 nch3 PROPN eurjchem-154 100 6 o o PROPN eurjchem-154 100 7 n n CCONJ eurjchem-154 100 8 n n NOUN eurjchem-154 100 9 h h NOUN eurjchem-154 101 1 p p NOUN eurjchem-154 101 2 s s X eurjchem-154 101 3 o o X eurjchem-154 101 4 ph ph PROPN eurjchem-154 101 5 php(o)cl2 php(o)cl2 NOUN eurjchem-154 101 6 47 47 NUM eurjchem-154 101 7 55 55 NUM eurjchem-154 101 8 thf thf NOUN eurjchem-154 101 9 , , PUNCT eurjchem-154 101 10 et3n et3n PROPN eurjchem-154 101 11 75 75 NUM eurjchem-154 101 12 % % NOUN eurjchem-154 101 13 scheme scheme NOUN eurjchem-154 101 14     SPACE eurjchem-154 101 15 18 18 NUM eurjchem-154 101 16         SPACE eurjchem-154 101 17 394 394 NUM eurjchem-154 101 18     SPACE eurjchem-154 101 19 abdel­rahman abdel­rahman ADJ eurjchem-154 101 20     SPACE eurjchem-154 101 21 et et NOUN eurjchem-154 101 22     SPACE eurjchem-154 101 23 al al PROPN eurjchem-154 101 24 . . PROPN eurjchem-154 101 25     SPACE eurjchem-154 101 26 / / SYM eurjchem-154 101 27     SPACE eurjchem-154 101 28 european european ADJ eurjchem-154 101 29     SPACE eurjchem-154 101 30 journal journal NOUN eurjchem-154 101 31     SPACE eurjchem-154 101 32 of of ADP eurjchem-154 101 33     SPACE eurjchem-154 101 34 chemistry chemistry NOUN eurjchem-154 101 35     SPACE eurjchem-154 101 36 1 1 NUM eurjchem-154 101 37     SPACE eurjchem-154 101 38 ( ( PUNCT eurjchem-154 101 39 4 4 NUM eurjchem-154 101 40 ) ) PUNCT eurjchem-154 101 41     SPACE eurjchem-154 101 42 ( ( PUNCT eurjchem-154 101 43 2010 2010 NUM eurjchem-154 101 44 ) ) PUNCT eurjchem-154 101 45     SPACE eurjchem-154 101 46 388­396 388­396 NUM eurjchem-154 101 47             SPACE eurjchem-154 101 48 n n CCONJ eurjchem-154 101 49 n n PRON eurjchem-154 101 50 nar nar NOUN eurjchem-154 101 51 ar ar NOUN eurjchem-154 101 52 nhnh2 nhnh2 NOUN eurjchem-154 102 1 p p X eurjchem-154 102 2 o o X eurjchem-154 102 3 o o X eurjchem-154 102 4 ph ph NOUN eurjchem-154 102 5 ph ph PROPN eurjchem-154 102 6 ch3 ch3 PROPN eurjchem-154 102 7 ch3 ch3 PROPN eurjchem-154 102 8 ch3 ch3 PROPN eurjchem-154 102 9 n n PROPN eurjchem-154 102 10 nar nar PROPN eurjchem-154 102 11 ar ar PROPN eurjchem-154 102 12 n n CCONJ eurjchem-154 102 13 n n CCONJ eurjchem-154 102 14 n n ADV eurjchem-154 102 15 p p NOUN eurjchem-154 103 1 oh oh INTJ eurjchem-154 103 2 phph phph PROPN eurjchem-154 103 3 ch3 ch3 PROPN eurjchem-154 103 4 ch3 ch3 PROPN eurjchem-154 103 5 ch3 ch3 PROPN eurjchem-154 103 6 + + CCONJ eurjchem-154 103 7 reflux reflux PROPN eurjchem-154 103 8 thf thf NOUN eurjchem-154 103 9 - - PUNCT eurjchem-154 103 10 piperidine piperidine NOUN eurjchem-154 103 11 ar= ar= NOUN eurjchem-154 103 12 4 4 NUM eurjchem-154 103 13 - - PUNCT eurjchem-154 103 14 brc6h4 brc6h4 NOUN eurjchem-154 103 15 10 10 NUM eurjchem-154 103 16 56 56 NUM eurjchem-154 103 17 33 33 NUM eurjchem-154 103 18 % % NOUN eurjchem-154 103 19     SPACE eurjchem-154 103 20 scheme scheme NOUN eurjchem-154 103 21     SPACE eurjchem-154 103 22 19 19 NUM eurjchem-154 103 23         SPACE eurjchem-154 103 24 n n CCONJ eurjchem-154 103 25 n n CCONJ eurjchem-154 103 26 n n CCONJ eurjchem-154 103 27 n n PROPN eurjchem-154 103 28 h h PROPN eurjchem-154 103 29 ch3 ch3 PROPN eurjchem-154 103 30 ar ar PROPN eurjchem-154 104 1 sh sh PROPN eurjchem-154 104 2 s s PROPN eurjchem-154 104 3 n n CCONJ eurjchem-154 104 4 n n CCONJ eurjchem-154 104 5 n n CCONJ eurjchem-154 104 6 n n PROPN eurjchem-154 104 7 ch3 ch3 PROPN eurjchem-154 104 8 ar ar PROPN eurjchem-154 104 9 s s PROPN eurjchem-154 104 10 s s PART eurjchem-154 104 11 p p NOUN eurjchem-154 104 12 net2 net2 PROPN eurjchem-154 104 13 n n CCONJ eurjchem-154 104 14 n n CCONJ eurjchem-154 104 15 n n CCONJ eurjchem-154 104 16 n n PROPN eurjchem-154 104 17 ch3 ch3 PROPN eurjchem-154 104 18 ar ar PROPN eurjchem-154 104 19 s s PROPN eurjchem-154 104 20 s s PROPN eurjchem-154 104 21 p p X eurjchem-154 104 22 oeto oeto VERB eurjchem-154 104 23 n n CCONJ eurjchem-154 104 24 n n CCONJ eurjchem-154 104 25 n n CCONJ eurjchem-154 104 26 n n PROPN eurjchem-154 104 27 ch3 ch3 PROPN eurjchem-154 104 28 ar ar PROPN eurjchem-154 104 29 s s PROPN eurjchem-154 104 30 s s PROPN eurjchem-154 104 31 p p NOUN eurjchem-154 104 32 phph phph ADJ eurjchem-154 104 33 ph ph PROPN eurjchem-154 104 34 p(net2)3p(o)(oet)3 p(net2)3p(o)(oet)3 NOUN eurjchem-154 104 35 ( ( PUNCT eurjchem-154 104 36 ph)3pbr2 ph)3pbr2 NOUN eurjchem-154 104 37 oh oh INTJ eurjchem-154 104 38 57 57 NUM eurjchem-154 104 39 605958 605958 NUM eurjchem-154 104 40 dry dry ADJ eurjchem-154 104 41 toluene toluene NOUN eurjchem-154 104 42 ar= ar= NOUN eurjchem-154 104 43 46 46 NUM eurjchem-154 104 44 % % NOUN eurjchem-154 104 45 54%61 54%61 NUM eurjchem-154 104 46 % % NOUN eurjchem-154 104 47     SPACE eurjchem-154 104 48 scheme scheme NOUN eurjchem-154 104 49     SPACE eurjchem-154 104 50 20 20 NUM eurjchem-154 104 51         SPACE eurjchem-154 104 52 n n CCONJ eurjchem-154 104 53 n n CCONJ eurjchem-154 104 54 n n CCONJ eurjchem-154 104 55 n n PROPN eurjchem-154 104 56 h h PROPN eurjchem-154 104 57 ch3 ch3 PROPN eurjchem-154 104 58 ar ar PROPN eurjchem-154 104 59 sh sh PROPN eurjchem-154 104 60 s s PROPN eurjchem-154 104 61 n n CCONJ eurjchem-154 104 62 n n CCONJ eurjchem-154 104 63 n n CCONJ eurjchem-154 104 64 n n PROPN eurjchem-154 104 65 ch3 ch3 PROPN eurjchem-154 104 66 ar ar PROPN eurjchem-154 104 67 s s PROPN eurjchem-154 104 68 s s PROPN eurjchem-154 104 69 p p X eurjchem-154 104 70 ( ( PUNCT eurjchem-154 104 71 net2)3 net2)3 PROPN eurjchem-154 104 72 n n CCONJ eurjchem-154 104 73 n n CCONJ eurjchem-154 104 74 n n CCONJ eurjchem-154 104 75 n n PROPN eurjchem-154 104 76 ch3 ch3 PROPN eurjchem-154 104 77 ar ar PROPN eurjchem-154 104 78 s s PROPN eurjchem-154 104 79 s s PART eurjchem-154 104 80 p p NOUN eurjchem-154 104 81 ch2pho ch2pho NOUN eurjchem-154 104 82 ( ( PUNCT eurjchem-154 104 83 net2)3pbr2 net2)3pbr2 NUM eurjchem-154 104 84 oh oh INTJ eurjchem-154 104 85 phch2p(o)(oet)2 phch2p(o)(oet)2 PROPN eurjchem-154 104 86 n n CCONJ eurjchem-154 104 87 n n CCONJ eurjchem-154 104 88 n n CCONJ eurjchem-154 104 89 n n PROPN eurjchem-154 104 90 ch3 ch3 PROPN eurjchem-154 104 91 ar ar PROPN eurjchem-154 104 92 s s PROPN eurjchem-154 104 93 s s PART eurjchem-154 104 94 p p VERB eurjchem-154 104 95 ch2cno ch2cno PROPN eurjchem-154 104 96 ncch2p(o)(oet)2 ncch2p(o)(oet)2 ADP eurjchem-154 104 97 57 57 NUM eurjchem-154 104 98 6362 6362 NUM eurjchem-154 104 99 dry dry ADJ eurjchem-154 104 100 toluene toluene NOUN eurjchem-154 104 101 ar= ar= PROPN eurjchem-154 104 102 61 61 NUM eurjchem-154 104 103 39 39 NUM eurjchem-154 104 104 % % NOUN eurjchem-154 104 105 58 58 NUM eurjchem-154 104 106 % % NOUN eurjchem-154 104 107 62 62 NUM eurjchem-154 104 108 % % NOUN eurjchem-154 104 109         SPACE eurjchem-154 104 110 scheme scheme NOUN eurjchem-154 104 111     SPACE eurjchem-154 104 112 21 21 NUM eurjchem-154 104 113         SPACE eurjchem-154 104 114 [ [ X eurjchem-154 104 115 1,2,4,5]triazaphosphinin‐4‐ol 1,2,4,5]triazaphosphinin‐4‐ol NUM eurjchem-154 104 116     SPACE eurjchem-154 104 117 ( ( PUNCT eurjchem-154 104 118 56 56 NUM eurjchem-154 104 119 ) ) PUNCT eurjchem-154 104 120     SPACE eurjchem-154 104 121 ( ( PUNCT eurjchem-154 104 122 scheme scheme NOUN eurjchem-154 104 123     SPACE eurjchem-154 104 124 19 19 NUM eurjchem-154 104 125 ) ) PUNCT eurjchem-154 104 126 . . PUNCT eurjchem-154 104 127     SPACE eurjchem-154 105 1 due due ADJ eurjchem-154 105 2     SPACE eurjchem-154 105 3 to to ADP eurjchem-154 105 4     SPACE eurjchem-154 105 5 the the DET eurjchem-154 105 6     SPACE eurjchem-154 105 7 driving drive VERB eurjchem-154 105 8     SPACE eurjchem-154 105 9 force force NOUN eurjchem-154 105 10     SPACE eurjchem-154 105 11 of of ADP eurjchem-154 105 12     SPACE eurjchem-154 105 13 p p PART eurjchem-154 105 14 = = ADJ eurjchem-154 105 15 o o NOUN eurjchem-154 105 16     SPACE eurjchem-154 105 17 bond bond NOUN eurjchem-154 105 18     SPACE eurjchem-154 105 19 is be AUX eurjchem-154 105 20     SPACE eurjchem-154 105 21 strong strong ADJ eurjchem-154 105 22     SPACE eurjchem-154 105 23 and and CCONJ eurjchem-154 105 24     SPACE eurjchem-154 105 25 phenyl phenyl NOUN eurjchem-154 105 26     SPACE eurjchem-154 105 27 groups group NOUN eurjchem-154 105 28     SPACE eurjchem-154 105 29 are be AUX eurjchem-154 105 30     SPACE eurjchem-154 105 31 bad bad ADJ eurjchem-154 105 32     SPACE eurjchem-154 105 33 leaving leave VERB eurjchem-154 105 34     SPACE eurjchem-154 105 35 groups group NOUN eurjchem-154 105 36 , , PUNCT eurjchem-154 105 37     SPACE eurjchem-154 105 38 the the DET eurjchem-154 105 39     SPACE eurjchem-154 105 40 nucleophilic nucleophilic ADJ eurjchem-154 105 41     SPACE eurjchem-154 105 42 attack attack NOUN eurjchem-154 105 43     SPACE eurjchem-154 105 44 of of ADP eurjchem-154 105 45     SPACE eurjchem-154 105 46 hydrazino hydrazino NOUN eurjchem-154 105 47     SPACE eurjchem-154 105 48 moiety moiety NOUN eurjchem-154 105 49     SPACE eurjchem-154 105 50 may may AUX eurjchem-154 105 51     SPACE eurjchem-154 105 52 be be AUX eurjchem-154 105 53     SPACE eurjchem-154 105 54 carried carry VERB eurjchem-154 105 55     SPACE eurjchem-154 105 56 out out ADP eurjchem-154 105 57     SPACE eurjchem-154 105 58 at at ADP eurjchem-154 105 59     SPACE eurjchem-154 105 60 carbonyl carbonyl NOUN eurjchem-154 105 61     SPACE eurjchem-154 105 62 group group NOUN eurjchem-154 105 63     SPACE eurjchem-154 105 64 rather rather ADV eurjchem-154 105 65     SPACE eurjchem-154 105 66 than than ADP eurjchem-154 105 67     SPACE eurjchem-154 105 68 the the DET eurjchem-154 105 69     SPACE eurjchem-154 105 70 p p NOUN eurjchem-154 105 71 = = PROPN eurjchem-154 105 72 o o NOUN eurjchem-154 105 73     SPACE eurjchem-154 105 74 group group NOUN eurjchem-154 105 75     SPACE eurjchem-154 106 1 [ [ X eurjchem-154 106 2 25 25 NUM eurjchem-154 106 3 ] ] PUNCT eurjchem-154 106 4 . . PUNCT eurjchem-154 106 5     SPACE eurjchem-154 106 6 on on ADP eurjchem-154 106 7     SPACE eurjchem-154 106 8 the the DET eurjchem-154 106 9     SPACE eurjchem-154 106 10 other other ADJ eurjchem-154 106 11     SPACE eurjchem-154 106 12 hand hand NOUN eurjchem-154 106 13 , , PUNCT eurjchem-154 106 14     SPACE eurjchem-154 106 15 ( ( PUNCT eurjchem-154 106 16 6‐methyl‐5‐styryl‐1,2,4‐triazin‐3‐ 6‐methyl‐5‐styryl‐1,2,4‐triazin‐3‐ NUM eurjchem-154 106 17 yl)dithiocarbamic yl)dithiocarbamic ADJ eurjchem-154 106 18     SPACE eurjchem-154 106 19 acid acid NOUN eurjchem-154 106 20     SPACE eurjchem-154 106 21 ( ( PUNCT eurjchem-154 106 22 57 57 NUM eurjchem-154 106 23 ) ) PUNCT eurjchem-154 106 24     SPACE eurjchem-154 106 25 can can AUX eurjchem-154 106 26     SPACE eurjchem-154 106 27 be be AUX eurjchem-154 106 28     SPACE eurjchem-154 106 29 used use VERB eurjchem-154 106 30     SPACE eurjchem-154 106 31 as as ADP eurjchem-154 106 32     SPACE eurjchem-154 106 33 starting start VERB eurjchem-154 106 34     SPACE eurjchem-154 106 35 material material NOUN eurjchem-154 106 36     SPACE eurjchem-154 106 37 for for ADP eurjchem-154 106 38     SPACE eurjchem-154 106 39 the the DET eurjchem-154 106 40     SPACE eurjchem-154 106 41 building building NOUN eurjchem-154 106 42     SPACE eurjchem-154 106 43 of of ADP eurjchem-154 106 44     SPACE eurjchem-154 106 45 fused fuse VERB eurjchem-154 106 46     SPACE eurjchem-154 106 47 phosphorus phosphorus NOUN eurjchem-154 106 48     SPACE eurjchem-154 106 49 containing contain VERB eurjchem-154 106 50     SPACE eurjchem-154 106 51 nitrogen‐sulfur nitrogen‐sulfur NOUN eurjchem-154 106 52     SPACE eurjchem-154 106 53 heterocyclic heterocyclic ADJ eurjchem-154 106 54     SPACE eurjchem-154 106 55 systems system NOUN eurjchem-154 106 56 . . PUNCT eurjchem-154 106 57     SPACE eurjchem-154 107 1 thus thus ADV eurjchem-154 107 2 , , PUNCT eurjchem-154 107 3     SPACE eurjchem-154 107 4 treatment treatment NOUN eurjchem-154 107 5     SPACE eurjchem-154 107 6 of of ADP eurjchem-154 107 7     SPACE eurjchem-154 107 8 57 57 NUM eurjchem-154 107 9     SPACE eurjchem-154 107 10 with with ADP eurjchem-154 107 11     SPACE eurjchem-154 107 12 some some DET eurjchem-154 107 13     SPACE eurjchem-154 107 14 phosphorus phosphorus NOUN eurjchem-154 107 15     SPACE eurjchem-154 107 16 reagents reagent NOUN eurjchem-154 107 17     SPACE eurjchem-154 107 18 such such ADJ eurjchem-154 107 19     SPACE eurjchem-154 107 20 as as ADP eurjchem-154 107 21     SPACE eurjchem-154 107 22 dibromotriphenylphosphorane dibromotriphenylphosphorane NOUN eurjchem-154 107 23 , , PUNCT eurjchem-154 107 24     SPACE eurjchem-154 107 25 triethyl triethyl NOUN eurjchem-154 107 26     SPACE eurjchem-154 107 27 phosphate phosphate NOUN eurjchem-154 107 28     SPACE eurjchem-154 107 29 and and CCONJ eurjchem-154 107 30     SPACE eurjchem-154 107 31 tris(diethylamino)phosphine tris(diethylamino)phosphine NOUN eurjchem-154 107 32     SPACE eurjchem-154 107 33 under under ADP eurjchem-154 107 34     SPACE eurjchem-154 107 35 reflux reflux NOUN eurjchem-154 107 36 , , PUNCT eurjchem-154 107 37     SPACE eurjchem-154 107 38 in in ADP eurjchem-154 107 39     SPACE eurjchem-154 107 40 dry dry ADJ eurjchem-154 107 41     SPACE eurjchem-154 107 42 toluene toluene NOUN eurjchem-154 107 43     SPACE eurjchem-154 107 44 containing contain VERB eurjchem-154 107 45     SPACE eurjchem-154 107 46 drops drop NOUN eurjchem-154 107 47     SPACE eurjchem-154 107 48 of of ADP eurjchem-154 107 49     SPACE eurjchem-154 107 50 triethylamine triethylamine NOUN eurjchem-154 107 51 , , PUNCT eurjchem-154 107 52     SPACE eurjchem-154 107 53 afforded afford VERB eurjchem-154 107 54     SPACE eurjchem-154 107 55 1,2,4‐triazino[2,3‐c][1,3,5,2]thiadiazaphosphinines 1,2,4‐triazino[2,3‐c][1,3,5,2]thiadiazaphosphinines NUM eurjchem-154 107 56     SPACE eurjchem-154 107 57 58­60 58­60 NOUN eurjchem-154 107 58 , , PUNCT eurjchem-154 107 59     SPACE eurjchem-154 107 60 respectively respectively ADV eurjchem-154 107 61     SPACE eurjchem-154 107 62 ( ( PUNCT eurjchem-154 107 63 scheme scheme NOUN eurjchem-154 107 64     SPACE eurjchem-154 107 65 20 20 NUM eurjchem-154 107 66 ) ) PUNCT eurjchem-154 107 67     SPACE eurjchem-154 108 1 [ [ X eurjchem-154 108 2 26 26 NUM eurjchem-154 108 3 ] ] PUNCT eurjchem-154 108 4 . . PUNCT eurjchem-154 108 5     SPACE eurjchem-154 109 1 also also ADV eurjchem-154 109 2 , , PUNCT eurjchem-154 109 3     SPACE eurjchem-154 109 4 three three NUM eurjchem-154 109 5     SPACE eurjchem-154 109 6 isomers isomer NOUN eurjchem-154 109 7     SPACE eurjchem-154 109 8 of of ADP eurjchem-154 109 9     SPACE eurjchem-154 109 10 1,2,4‐triazino[2,3‐c][1,3,5,2]thiadiaza 1,2,4‐triazino[2,3‐c][1,3,5,2]thiadiaza NUM eurjchem-154 109 11     SPACE eurjchem-154 109 12 phosphinines phosphinine NOUN eurjchem-154 109 13     SPACE eurjchem-154 109 14 61‐63 61‐63 NOUN eurjchem-154 109 15     SPACE eurjchem-154 109 16 were be AUX eurjchem-154 109 17     SPACE eurjchem-154 109 18 obtained obtain VERB eurjchem-154 109 19     SPACE eurjchem-154 109 20 under under ADP eurjchem-154 109 21     SPACE eurjchem-154 109 22 the the DET eurjchem-154 109 23     SPACE eurjchem-154 109 24 same same ADJ eurjchem-154 109 25     SPACE eurjchem-154 109 26 reaction reaction NOUN eurjchem-154 109 27     SPACE eurjchem-154 109 28 conditions condition NOUN eurjchem-154 109 29     SPACE eurjchem-154 109 30 via via ADP eurjchem-154 109 31     SPACE eurjchem-154 109 32 reaction reaction NOUN eurjchem-154 109 33     SPACE eurjchem-154 109 34 of of ADP eurjchem-154 109 35     SPACE eurjchem-154 109 36 1,2,4‐triazinyldithiocarbamic 1,2,4‐triazinyldithiocarbamic NUM eurjchem-154 109 37     SPACE eurjchem-154 109 38 acid acid NOUN eurjchem-154 109 39     SPACE eurjchem-154 109 40 derivative derivative NOUN eurjchem-154 109 41     SPACE eurjchem-154 109 42 57 57 NUM eurjchem-154 109 43     SPACE eurjchem-154 109 44 with with ADP eurjchem-154 109 45     SPACE eurjchem-154 109 46 cyanomethyl cyanomethyl NOUN eurjchem-154 109 47     SPACE eurjchem-154 109 48 phosphonate phosphonate VERB eurjchem-154 109 49 , , PUNCT eurjchem-154 109 50     SPACE eurjchem-154 109 51 diethylbenzyl diethylbenzyl NOUN eurjchem-154 109 52     SPACE eurjchem-154 109 53 phosphate phosphate NOUN eurjchem-154 109 54     SPACE eurjchem-154 109 55 and and CCONJ eurjchem-154 109 56     SPACE eurjchem-154 109 57 dibromo‐tris(diethyamino)‐5‐phosphane dibromo‐tris(diethyamino)‐5‐phosphane PROPN eurjchem-154 109 58 , , PUNCT eurjchem-154 109 59     SPACE eurjchem-154 109 60 res‐ res‐ NOUN eurjchem-154 109 61 pectively pectively ADV eurjchem-154 109 62     SPACE eurjchem-154 109 63 ( ( PUNCT eurjchem-154 109 64 scheme scheme NOUN eurjchem-154 109 65     SPACE eurjchem-154 109 66 21 21 NUM eurjchem-154 109 67 ) ) PUNCT eurjchem-154 109 68     SPACE eurjchem-154 110 1 [ [ X eurjchem-154 110 2 26 26 NUM eurjchem-154 110 3 ] ] PUNCT eurjchem-154 110 4 . . PUNCT eurjchem-154 110 5     SPACE eurjchem-154 111 1 the the DET eurjchem-154 111 2     SPACE eurjchem-154 111 3 behaviour behaviour NOUN eurjchem-154 111 4     SPACE eurjchem-154 111 5 of of ADP eurjchem-154 111 6     SPACE eurjchem-154 111 7 sh sh PROPN eurjchem-154 111 8     SPACE eurjchem-154 111 9 group group NOUN eurjchem-154 111 10     SPACE eurjchem-154 111 11 in in ADP eurjchem-154 111 12     SPACE eurjchem-154 111 13 compound compound NOUN eurjchem-154 111 14     SPACE eurjchem-154 111 15 57 57 NUM eurjchem-154 111 16     SPACE eurjchem-154 111 17 towards towards ADP eurjchem-154 111 18     SPACE eurjchem-154 111 19 these these DET eurjchem-154 111 20     SPACE eurjchem-154 111 21 phosphorus phosphorus NOUN eurjchem-154 111 22     SPACE eurjchem-154 111 23 reagents reagent NOUN eurjchem-154 111 24     SPACE eurjchem-154 111 25 to to PART eurjchem-154 111 26     SPACE eurjchem-154 111 27 produce produce VERB eurjchem-154 111 28     SPACE eurjchem-154 111 29 compounds compound NOUN eurjchem-154 111 30     SPACE eurjchem-154 111 31 58‐63 58‐63 NOUN eurjchem-154 111 32     SPACE eurjchem-154 111 33 is be AUX eurjchem-154 111 34     SPACE eurjchem-154 111 35 similar similar ADJ eurjchem-154 111 36     SPACE eurjchem-154 111 37 to to ADP eurjchem-154 111 38     SPACE eurjchem-154 111 39 its its PRON eurjchem-154 111 40     SPACE eurjchem-154 111 41 reaction reaction NOUN eurjchem-154 111 42     SPACE eurjchem-154 111 43 with with ADP eurjchem-154 111 44     SPACE eurjchem-154 111 45 various various ADJ eurjchem-154 111 46     SPACE eurjchem-154 111 47 alkylating alkylate VERB eurjchem-154 111 48     SPACE eurjchem-154 111 49 agents agent NOUN eurjchem-154 111 50     SPACE eurjchem-154 111 51 and/or and/or CCONJ eurjchem-154 111 52     SPACE eurjchem-154 111 53 ketonic ketonic ADJ eurjchem-154 111 54     SPACE eurjchem-154 111 55 agents agent NOUN eurjchem-154 111 56 . . PUNCT eurjchem-154 111 57     SPACE eurjchem-154 112 1 it it PRON eurjchem-154 112 2     SPACE eurjchem-154 112 3 is be AUX eurjchem-154 112 4     SPACE eurjchem-154 112 5 worthy worthy ADJ eurjchem-154 112 6     SPACE eurjchem-154 112 7 to to PART eurjchem-154 112 8     SPACE eurjchem-154 112 9 mention mention VERB eurjchem-154 112 10     SPACE eurjchem-154 112 11 that that SCONJ eurjchem-154 112 12     SPACE eurjchem-154 112 13 nucleophilic nucleophilic ADJ eurjchem-154 112 14     SPACE eurjchem-154 112 15 attack attack NOUN eurjchem-154 112 16     SPACE eurjchem-154 112 17 on on ADP eurjchem-154 112 18     SPACE eurjchem-154 112 19 sh sh NOUN eurjchem-154 112 20     SPACE eurjchem-154 112 21 is be AUX eurjchem-154 112 22     SPACE eurjchem-154 112 23 more more ADJ eurjchem-154 112 24     SPACE eurjchem-154 112 25 preferred preferred ADJ eurjchem-154 112 26     SPACE eurjchem-154 112 27 than than ADP eurjchem-154 112 28     SPACE eurjchem-154 112 29 nh nh PROPN eurjchem-154 112 30     SPACE eurjchem-154 112 31 group group NOUN eurjchem-154 112 32     SPACE eurjchem-154 112 33 towards towards ADP eurjchem-154 112 34     SPACE eurjchem-154 112 35 the the DET eurjchem-154 112 36     SPACE eurjchem-154 112 37 phosphorus phosphorus NOUN eurjchem-154 112 38     SPACE eurjchem-154 112 39 reagents reagent NOUN eurjchem-154 112 40     SPACE eurjchem-154 112 41 [ [ X eurjchem-154 112 42 29 29 NUM eurjchem-154 112 43 ] ] PUNCT eurjchem-154 112 44 . . PUNCT eurjchem-154 112 45     SPACE eurjchem-154 112 46 reaction reaction NOUN eurjchem-154 112 47     SPACE eurjchem-154 112 48 of of ADP eurjchem-154 112 49     SPACE eurjchem-154 112 50 4‐amino‐3‐mercapto‐6‐methyl‐1,2,4‐triazin‐ 4‐amino‐3‐mercapto‐6‐methyl‐1,2,4‐triazin‐ NOUN eurjchem-154 112 51 5(4h)‐one 5(4h)‐one NUM eurjchem-154 112 52     SPACE eurjchem-154 112 53 ( ( PUNCT eurjchem-154 112 54 47 47 NUM eurjchem-154 112 55 ) ) PUNCT eurjchem-154 112 56     SPACE eurjchem-154 112 57 with with ADP eurjchem-154 112 58     SPACE eurjchem-154 112 59 acetyltriphenylphosphonium acetyltriphenylphosphonium NOUN eurjchem-154 112 60     SPACE eurjchem-154 112 61 chloride chloride NOUN eurjchem-154 112 62 , , PUNCT eurjchem-154 112 63     SPACE eurjchem-154 112 64 in in ADP eurjchem-154 112 65     SPACE eurjchem-154 112 66 boiling boil VERB eurjchem-154 112 67     SPACE eurjchem-154 112 68 dimethylformamide dimethylformamide NOUN eurjchem-154 112 69     SPACE eurjchem-154 112 70 containing contain VERB eurjchem-154 112 71     SPACE eurjchem-154 112 72 a a DET eurjchem-154 112 73     SPACE eurjchem-154 112 74 catalytic catalytic ADJ eurjchem-154 112 75     SPACE eurjchem-154 112 76 amount amount NOUN eurjchem-154 112 77     SPACE eurjchem-154 112 78 of of ADP eurjchem-154 112 79     SPACE eurjchem-154 112 80 piperidine piperidine NOUN eurjchem-154 112 81 , , PUNCT eurjchem-154 112 82     SPACE eurjchem-154 112 83 afforded afford VERB eurjchem-154 112 84     SPACE eurjchem-154 112 85 1,2,4‐triazino[4,3‐e][1,4,5,2]thiadiaza 1,2,4‐triazino[4,3‐e][1,4,5,2]thiadiaza NUM eurjchem-154 112 86     SPACE eurjchem-154 112 87 phosphinine phosphinine NOUN eurjchem-154 112 88     SPACE eurjchem-154 112 89 65 65 NUM eurjchem-154 112 90     SPACE eurjchem-154 112 91 ( ( PUNCT eurjchem-154 112 92 scheme scheme NOUN eurjchem-154 112 93     SPACE eurjchem-154 112 94 22 22 NUM eurjchem-154 112 95 ) ) PUNCT eurjchem-154 112 96 . . PUNCT eurjchem-154 112 97     SPACE eurjchem-154 113 1 formation formation NOUN eurjchem-154 113 2     SPACE eurjchem-154 113 3 of of ADP eurjchem-154 113 4     SPACE eurjchem-154 113 5 the the DET eurjchem-154 113 6     SPACE eurjchem-154 113 7 latter latter ADJ eurjchem-154 113 8     SPACE eurjchem-154 113 9 compound compound NOUN eurjchem-154 113 10     SPACE eurjchem-154 113 11 65 65 NUM eurjchem-154 113 12     SPACE eurjchem-154 113 13 may may AUX eurjchem-154 113 14     SPACE eurjchem-154 113 15 occur occur VERB eurjchem-154 113 16     SPACE eurjchem-154 113 17 through through ADP eurjchem-154 113 18     SPACE eurjchem-154 113 19 the the DET eurjchem-154 113 20     SPACE eurjchem-154 113 21 attack attack NOUN eurjchem-154 113 22     SPACE eurjchem-154 113 23 of of ADP eurjchem-154 113 24     SPACE eurjchem-154 113 25 the the DET eurjchem-154 113 26     SPACE eurjchem-154 113 27 lone lone ADJ eurjchem-154 113 28     SPACE eurjchem-154 113 29 pair pair NOUN eurjchem-154 113 30     SPACE eurjchem-154 113 31 electrons electron NOUN eurjchem-154 113 32     SPACE eurjchem-154 113 33 of of ADP eurjchem-154 113 34     SPACE eurjchem-154 113 35 the the DET eurjchem-154 113 36     SPACE eurjchem-154 113 37 sh sh PROPN eurjchem-154 113 38     SPACE eurjchem-154 113 39 group group NOUN eurjchem-154 113 40     SPACE eurjchem-154 113 41 on on ADP eurjchem-154 113 42     SPACE eurjchem-154 113 43 phosphorus phosphorus NOUN eurjchem-154 113 44     SPACE eurjchem-154 113 45 atom atom NOUN eurjchem-154 113 46     SPACE eurjchem-154 113 47 of of ADP eurjchem-154 113 48     SPACE eurjchem-154 113 49 the the DET eurjchem-154 113 50     SPACE eurjchem-154 113 51 abdel­rahman abdel­rahman NOUN eurjchem-154 113 52     SPACE eurjchem-154 113 53 et et NOUN eurjchem-154 113 54     SPACE eurjchem-154 113 55 al al PROPN eurjchem-154 113 56 . . PROPN eurjchem-154 113 57     SPACE eurjchem-154 113 58 / / SYM eurjchem-154 113 59     SPACE eurjchem-154 113 60 european european ADJ eurjchem-154 113 61     SPACE eurjchem-154 113 62 journal journal NOUN eurjchem-154 113 63     SPACE eurjchem-154 113 64 of of ADP eurjchem-154 113 65     SPACE eurjchem-154 113 66 chemistry chemistry NOUN eurjchem-154 113 67     SPACE eurjchem-154 113 68 1 1 NUM eurjchem-154 113 69     SPACE eurjchem-154 113 70 ( ( PUNCT eurjchem-154 113 71 4 4 NUM eurjchem-154 113 72 ) ) PUNCT eurjchem-154 113 73     SPACE eurjchem-154 113 74 ( ( PUNCT eurjchem-154 113 75 2010 2010 NUM eurjchem-154 113 76 ) ) PUNCT eurjchem-154 113 77     SPACE eurjchem-154 113 78 388­396 388­396 NUM eurjchem-154 113 79     SPACE eurjchem-154 113 80 395 395 NUM eurjchem-154 113 81     SPACE eurjchem-154 113 82 phosphonium phosphonium NOUN eurjchem-154 113 83     SPACE eurjchem-154 113 84 salt salt NOUN eurjchem-154 113 85     SPACE eurjchem-154 113 86 to to PART eurjchem-154 113 87     SPACE eurjchem-154 113 88 remove remove VERB eurjchem-154 113 89     SPACE eurjchem-154 113 90 hydrogen hydrogen NOUN eurjchem-154 113 91     SPACE eurjchem-154 113 92 halide halide NOUN eurjchem-154 113 93     SPACE eurjchem-154 113 94 which which PRON eurjchem-154 113 95     SPACE eurjchem-154 113 96 may may AUX eurjchem-154 113 97     SPACE eurjchem-154 113 98 afford afford VERB eurjchem-154 113 99     SPACE eurjchem-154 113 100 the the DET eurjchem-154 113 101     SPACE eurjchem-154 113 102 intermediate intermediate ADJ eurjchem-154 113 103     SPACE eurjchem-154 113 104 64 64 NUM eurjchem-154 113 105 , , PUNCT eurjchem-154 113 106     SPACE eurjchem-154 113 107 followed follow VERB eurjchem-154 113 108     SPACE eurjchem-154 113 109 by by ADP eurjchem-154 113 110     SPACE eurjchem-154 113 111 an an DET eurjchem-154 113 112     SPACE eurjchem-154 113 113 intramolecular intramolecular ADJ eurjchem-154 113 114     SPACE eurjchem-154 113 115 nucleophilic nucleophilic ADJ eurjchem-154 113 116     SPACE eurjchem-154 113 117 attack attack NOUN eurjchem-154 113 118     SPACE eurjchem-154 113 119 of of ADP eurjchem-154 113 120     SPACE eurjchem-154 113 121 the the DET eurjchem-154 113 122     SPACE eurjchem-154 113 123 amino amino NOUN eurjchem-154 113 124     SPACE eurjchem-154 113 125 group group NOUN eurjchem-154 113 126     SPACE eurjchem-154 113 127 on on ADP eurjchem-154 113 128     SPACE eurjchem-154 113 129 carbonyl carbonyl NOUN eurjchem-154 113 130     SPACE eurjchem-154 113 131 group group NOUN eurjchem-154 113 132     SPACE eurjchem-154 113 133 with with ADP eurjchem-154 113 134     SPACE eurjchem-154 113 135 elimination elimination NOUN eurjchem-154 113 136     SPACE eurjchem-154 113 137 of of ADP eurjchem-154 113 138     SPACE eurjchem-154 113 139 water water NOUN eurjchem-154 113 140     SPACE eurjchem-154 113 141 to to PART eurjchem-154 113 142     SPACE eurjchem-154 113 143 give give VERB eurjchem-154 113 144     SPACE eurjchem-154 113 145 65 65 NUM eurjchem-154 113 146 . . PUNCT eurjchem-154 113 147     SPACE eurjchem-154 113 148 also also ADV eurjchem-154 113 149 , , PUNCT eurjchem-154 113 150     SPACE eurjchem-154 113 151 condensation condensation NOUN eurjchem-154 113 152     SPACE eurjchem-154 113 153 of of ADP eurjchem-154 113 154     SPACE eurjchem-154 113 155 47 47 NUM eurjchem-154 113 156     SPACE eurjchem-154 113 157 with with ADP eurjchem-154 113 158     SPACE eurjchem-154 113 159 4‐chlorobenzaldehyde 4‐chlorobenzaldehyde NOUN eurjchem-154 113 160     SPACE eurjchem-154 113 161 followed follow VERB eurjchem-154 113 162     SPACE eurjchem-154 113 163 by by ADP eurjchem-154 113 164     SPACE eurjchem-154 113 165 reaction reaction NOUN eurjchem-154 113 166     SPACE eurjchem-154 113 167 with with ADP eurjchem-154 113 168     SPACE eurjchem-154 113 169 diethyl diethyl NOUN eurjchem-154 113 170     SPACE eurjchem-154 113 171 phosphite phosphite NOUN eurjchem-154 113 172 , , PUNCT eurjchem-154 113 173     SPACE eurjchem-154 113 174 in in ADP eurjchem-154 113 175     SPACE eurjchem-154 113 176 boiling boiling NOUN eurjchem-154 113 177     SPACE eurjchem-154 113 178 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 113 179     SPACE eurjchem-154 113 180 containing contain VERB eurjchem-154 113 181     SPACE eurjchem-154 113 182 a a DET eurjchem-154 113 183     SPACE eurjchem-154 113 184 catalytic catalytic ADJ eurjchem-154 113 185     SPACE eurjchem-154 113 186 amount amount NOUN eurjchem-154 113 187     SPACE eurjchem-154 113 188 of of ADP eurjchem-154 113 189     SPACE eurjchem-154 113 190 sodium sodium NOUN eurjchem-154 113 191     SPACE eurjchem-154 113 192 hydride hydride NOUN eurjchem-154 113 193 , , PUNCT eurjchem-154 113 194     SPACE eurjchem-154 113 195 produced produce VERB eurjchem-154 113 196     SPACE eurjchem-154 113 197 a a DET eurjchem-154 113 198     SPACE eurjchem-154 113 199 cyclic cyclic ADJ eurjchem-154 113 200     SPACE eurjchem-154 113 201 ‐amino ‐amino PROPN eurjchem-154 113 202     SPACE eurjchem-154 113 203 phosphonate phosphonate VERB eurjchem-154 113 204     SPACE eurjchem-154 113 205 ester ester NOUN eurjchem-154 113 206     SPACE eurjchem-154 113 207 67 67 NUM eurjchem-154 113 208     SPACE eurjchem-154 113 209 as as ADP eurjchem-154 113 210     SPACE eurjchem-154 113 211 only only ADV eurjchem-154 113 212     SPACE eurjchem-154 113 213 one one NUM eurjchem-154 113 214     SPACE eurjchem-154 113 215 isomer isomer NOUN eurjchem-154 113 216     SPACE eurjchem-154 113 217 ( ( PUNCT eurjchem-154 113 218 scheme scheme NOUN eurjchem-154 113 219     SPACE eurjchem-154 113 220 22 22 NUM eurjchem-154 113 221 ) ) PUNCT eurjchem-154 113 222     SPACE eurjchem-154 114 1 [ [ X eurjchem-154 114 2 28 28 NUM eurjchem-154 114 3 ] ] PUNCT eurjchem-154 114 4 . . PUNCT eurjchem-154 114 5             SPACE eurjchem-154 115 1 n n CCONJ eurjchem-154 115 2 n n PRON eurjchem-154 115 3 nch3 nch3 PROPN eurjchem-154 116 1 o o INTJ eurjchem-154 116 2 sh sh PROPN eurjchem-154 116 3 nh2 nh2 PROPN eurjchem-154 116 4 n n PRON eurjchem-154 116 5 nch3 nch3 PROPN eurjchem-154 116 6 o o PROPN eurjchem-154 116 7 n n CCONJ eurjchem-154 116 8 n n CCONJ eurjchem-154 117 1 p(ph)3 p(ph)3 PROPN eurjchem-154 117 2 s s PROPN eurjchem-154 117 3 ch3 ch3 PROPN eurjchem-154 117 4 ( ( PUNCT eurjchem-154 117 5 ph)3p ph)3p ADP eurjchem-154 117 6 coch3 coch3 PROPN eurjchem-154 117 7 cl cl PROPN eurjchem-154 117 8 n n CCONJ eurjchem-154 117 9 nch3 nch3 PROPN eurjchem-154 117 10 o o PROPN eurjchem-154 117 11 n n CCONJ eurjchem-154 117 12 nh2 nh2 PROPN eurjchem-154 117 13 p(ph)3 p(ph)3 PROPN eurjchem-154 117 14 s s PART eurjchem-154 117 15 o o PROPN eurjchem-154 117 16 ch3 ch3 PROPN eurjchem-154 117 17 n n CCONJ eurjchem-154 117 18 n n PRON eurjchem-154 117 19 nch3 nch3 PROPN eurjchem-154 117 20 o o X eurjchem-154 117 21 s s NOUN eurjchem-154 117 22 na na PROPN eurjchem-154 117 23 nh nh PROPN eurjchem-154 117 24 ar ar PROPN eurjchem-154 117 25 p p PROPN eurjchem-154 118 1 o o PROPN eurjchem-154 119 1 oet oet VERB eurjchem-154 119 2 oet oet ADJ eurjchem-154 119 3 h h NOUN eurjchem-154 119 4 n n PROPN eurjchem-154 119 5 nh nh PROPN eurjchem-154 119 6 p p NOUN eurjchem-154 119 7 s s PROPN eurjchem-154 119 8 n n PRON eurjchem-154 119 9 nch3 nch3 PROPN eurjchem-154 119 10 o o PROPN eurjchem-154 119 11 ar ar PROPN eurjchem-154 119 12 h h NOUN eurjchem-154 120 1 o o PROPN eurjchem-154 120 2 oet oet ADJ eurjchem-154 120 3 + + CCONJ eurjchem-154 120 4 -h2o -h2o PROPN eurjchem-154 120 5 dmf dmf X eurjchem-154 120 6 -hcl -hcl NUM eurjchem-154 120 7 47 47 NUM eurjchem-154 120 8 64 64 NUM eurjchem-154 120 9 65 65 NUM eurjchem-154 120 10 -etoh -etoh NOUN eurjchem-154 120 11 66 66 NUM eurjchem-154 120 12 67 67 NUM eurjchem-154 120 13 ar= ar= NOUN eurjchem-154 120 14 4 4 NUM eurjchem-154 120 15 - - NOUN eurjchem-154 120 16 clc6h4 clc6h4 NOUN eurjchem-154 120 17 + + CCONJ eurjchem-154 120 18 i i PROPN eurjchem-154 120 19 ) ) PUNCT eurjchem-154 120 20 archo archo NOUN eurjchem-154 120 21 - - PUNCT eurjchem-154 120 22 etoh etoh PROPN eurjchem-154 120 23 ii ii NOUN eurjchem-154 120 24 ) ) PUNCT eurjchem-154 120 25 h h NOUN eurjchem-154 120 26 - - PUNCT eurjchem-154 120 27 p(o)(oet)2 p(o)(oet)2 NOUN eurjchem-154 120 28 thf thf PROPN eurjchem-154 120 29 - - PUNCT eurjchem-154 120 30 nah nah INTJ eurjchem-154 120 31 85 85 NUM eurjchem-154 120 32 % % NOUN eurjchem-154 120 33 46 46 NUM eurjchem-154 120 34 % % NOUN eurjchem-154 120 35 scheme scheme NOUN eurjchem-154 120 36     SPACE eurjchem-154 120 37 22 22 NUM eurjchem-154 120 38         SPACE eurjchem-154 120 39 the the DET eurjchem-154 120 40     SPACE eurjchem-154 120 41 kabachnik kabachnik NOUN eurjchem-154 120 42 – – PUNCT eurjchem-154 120 43 fields field NOUN eurjchem-154 120 44     SPACE eurjchem-154 120 45 reaction reaction NOUN eurjchem-154 120 46     SPACE eurjchem-154 121 1 [ [ X eurjchem-154 121 2 20 20 NUM eurjchem-154 121 3 ] ] PUNCT eurjchem-154 121 4     SPACE eurjchem-154 121 5 using use VERB eurjchem-154 121 6     SPACE eurjchem-154 121 7 3,4‐diamino‐6‐ 3,4‐diamino‐6‐ NUM eurjchem-154 121 8 methyl‐1,2,4‐triazin‐5(4h)‐one methyl‐1,2,4‐triazin‐5(4h)‐one PROPN eurjchem-154 121 9     SPACE eurjchem-154 121 10 ( ( PUNCT eurjchem-154 121 11 68 68 NUM eurjchem-154 121 12 ) ) PUNCT eurjchem-154 121 13 , , PUNCT eurjchem-154 121 14     SPACE eurjchem-154 121 15 acetaldehyde acetaldehyde NOUN eurjchem-154 121 16     SPACE eurjchem-154 121 17 and and CCONJ eurjchem-154 121 18     SPACE eurjchem-154 121 19 diethyl diethyl NOUN eurjchem-154 121 20     SPACE eurjchem-154 121 21 phosphite phosphite NOUN eurjchem-154 121 22     SPACE eurjchem-154 121 23 in in ADP eurjchem-154 121 24     SPACE eurjchem-154 121 25 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 121 26     SPACE eurjchem-154 121 27 in in ADP eurjchem-154 121 28     SPACE eurjchem-154 121 29 the the DET eurjchem-154 121 30     SPACE eurjchem-154 121 31 presence presence NOUN eurjchem-154 121 32     SPACE eurjchem-154 121 33 of of ADP eurjchem-154 121 34     SPACE eurjchem-154 121 35 sodium sodium NOUN eurjchem-154 121 36     SPACE eurjchem-154 121 37 hydride hydride NOUN eurjchem-154 121 38     SPACE eurjchem-154 121 39 as as ADP eurjchem-154 121 40     SPACE eurjchem-154 121 41 a a DET eurjchem-154 121 42     SPACE eurjchem-154 121 43 catalyst catalyst NOUN eurjchem-154 121 44     SPACE eurjchem-154 121 45 led lead VERB eurjchem-154 121 46     SPACE eurjchem-154 121 47 to to ADP eurjchem-154 121 48     SPACE eurjchem-154 121 49 only only ADV eurjchem-154 121 50     SPACE eurjchem-154 121 51 one one NUM eurjchem-154 121 52     SPACE eurjchem-154 121 53 isomer isomer NOUN eurjchem-154 121 54     SPACE eurjchem-154 121 55 of of ADP eurjchem-154 121 56     SPACE eurjchem-154 121 57 1,2,4‐ 1,2,4‐ NUM eurjchem-154 121 58 triazino[4,3‐b][1,2,4,5 triazino[4,3‐b][1,2,4,5 NOUN eurjchem-154 121 59 ] ] PUNCT eurjchem-154 121 60     SPACE eurjchem-154 121 61 triazaphosphinine triazaphosphinine ADJ eurjchem-154 121 62     SPACE eurjchem-154 121 63 derivative derivative ADJ eurjchem-154 121 64     SPACE eurjchem-154 121 65 70 70 NUM eurjchem-154 121 66     SPACE eurjchem-154 121 67 ( ( PUNCT eurjchem-154 121 68 scheme scheme NOUN eurjchem-154 121 69     SPACE eurjchem-154 121 70 23 23 NUM eurjchem-154 121 71 ) ) PUNCT eurjchem-154 121 72     SPACE eurjchem-154 122 1 [ [ X eurjchem-154 122 2 27 27 NUM eurjchem-154 122 3 ] ] PUNCT eurjchem-154 122 4 . . PUNCT eurjchem-154 122 5             SPACE eurjchem-154 123 1 n n CCONJ eurjchem-154 123 2 n n PRON eurjchem-154 123 3 nch3 nch3 PROPN eurjchem-154 123 4 o o PROPN eurjchem-154 123 5 nh2 nh2 PROPN eurjchem-154 123 6 nh2 nh2 PROPN eurjchem-154 123 7 n n PROPN eurjchem-154 123 8 nh nh PROPN eurjchem-154 123 9 p p PROPN eurjchem-154 123 10 nh nh PROPN eurjchem-154 123 11 n n CCONJ eurjchem-154 123 12 nch3 nch3 PROPN eurjchem-154 124 1 o o PROPN eurjchem-154 124 2 ch3 ch3 PROPN eurjchem-154 124 3 h h NOUN eurjchem-154 125 1 o o PROPN eurjchem-154 125 2 oet oet VERB eurjchem-154 125 3 thf thf NOUN eurjchem-154 125 4 - - PROPN eurjchem-154 125 5 nah nah INTJ eurjchem-154 125 6 n n PROPN eurjchem-154 125 7 nh nh PROPN eurjchem-154 125 8 p p PROPN eurjchem-154 125 9 nh2 nh2 PROPN eurjchem-154 125 10 n n PRON eurjchem-154 125 11 nch3 nch3 PROPN eurjchem-154 126 1 o o PROPN eurjchem-154 126 2 ch3 ch3 PROPN eurjchem-154 126 3 h h NOUN eurjchem-154 127 1 o o PROPN eurjchem-154 127 2 oet oet VERB eurjchem-154 127 3 oet oet VERB eurjchem-154 127 4 68 68 NUM eurjchem-154 127 5 6970 6970 NUM eurjchem-154 127 6 -etoh -etoh PROPN eurjchem-154 127 7 i i NOUN eurjchem-154 127 8 ) ) PUNCT eurjchem-154 127 9 ch3cho ch3cho PROPN eurjchem-154 127 10 ii ii PROPN eurjchem-154 127 11 ) ) PUNCT eurjchem-154 127 12 h h NOUN eurjchem-154 127 13 - - PUNCT eurjchem-154 127 14 p(o)(oet)255 p(o)(oet)255 ADJ eurjchem-154 127 15 % % NOUN eurjchem-154 127 16 scheme scheme NOUN eurjchem-154 127 17     SPACE eurjchem-154 127 18 23 23 NUM eurjchem-154 127 19         SPACE eurjchem-154 127 20 2,7‐dimethyl‐2‐oxido‐1,2,3,4‐tetrahydro‐8h‐[1,2,4]triazino 2,7‐dimethyl‐2‐oxido‐1,2,3,4‐tetrahydro‐8h‐[1,2,4]triazino NOUN eurjchem-154 127 21     SPACE eurjchem-154 127 22 [ [ X eurjchem-154 127 23 4,3‐e][1,2,4,5,3]tetrazaphosphinin‐8‐one 4,3‐e][1,2,4,5,3]tetrazaphosphinin‐8‐one NUM eurjchem-154 127 24     SPACE eurjchem-154 127 25 ( ( PUNCT eurjchem-154 127 26 71 71 NUM eurjchem-154 127 27 ) ) PUNCT eurjchem-154 127 28     SPACE eurjchem-154 127 29 was be AUX eurjchem-154 127 30     SPACE eurjchem-154 127 31 obtained obtain VERB eurjchem-154 127 32     SPACE eurjchem-154 127 33 by by ADP eurjchem-154 127 34     SPACE eurjchem-154 127 35 cyclocondensation cyclocondensation NOUN eurjchem-154 127 36     SPACE eurjchem-154 127 37 reaction reaction NOUN eurjchem-154 127 38     SPACE eurjchem-154 127 39 of of ADP eurjchem-154 127 40     SPACE eurjchem-154 127 41 compound compound NOUN eurjchem-154 127 42     SPACE eurjchem-154 127 43 53 53 NUM eurjchem-154 127 44     SPACE eurjchem-154 127 45 with with ADP eurjchem-154 127 46     SPACE eurjchem-154 127 47 bis(dimethylamino)methylphosphonate bis(dimethylamino)methylphosphonate NUM eurjchem-154 127 48 , , PUNCT eurjchem-154 127 49     SPACE eurjchem-154 127 50 in in ADP eurjchem-154 127 51     SPACE eurjchem-154 127 52 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 127 53     SPACE eurjchem-154 127 54 in in ADP eurjchem-154 127 55     SPACE eurjchem-154 127 56 the the DET eurjchem-154 127 57     SPACE eurjchem-154 127 58 presence presence NOUN eurjchem-154 127 59     SPACE eurjchem-154 127 60 of of ADP eurjchem-154 127 61     SPACE eurjchem-154 127 62 few few ADJ eurjchem-154 127 63     SPACE eurjchem-154 127 64 drops drop VERB eurjchem-154 127 65     SPACE eurjchem-154 127 66 of of ADP eurjchem-154 127 67     SPACE eurjchem-154 127 68 hydrochloric hydrochloric ADJ eurjchem-154 127 69     SPACE eurjchem-154 127 70 acid acid NOUN eurjchem-154 127 71     SPACE eurjchem-154 127 72 ( ( PUNCT eurjchem-154 127 73 scheme scheme NOUN eurjchem-154 127 74     SPACE eurjchem-154 127 75 24 24 NUM eurjchem-154 127 76 ) ) PUNCT eurjchem-154 127 77 . . PUNCT eurjchem-154 127 78     SPACE eurjchem-154 128 1 also also ADV eurjchem-154 128 2 , , PUNCT eurjchem-154 128 3     SPACE eurjchem-154 128 4 the the DET eurjchem-154 128 5     SPACE eurjchem-154 128 6 one‐pot one‐pot NOUN eurjchem-154 128 7     SPACE eurjchem-154 128 8 kabachnik‐fields kabachnik‐field NOUN eurjchem-154 128 9     SPACE eurjchem-154 128 10 reaction reaction NOUN eurjchem-154 128 11     SPACE eurjchem-154 128 12 of of ADP eurjchem-154 128 13     SPACE eurjchem-154 128 14 compound compound NOUN eurjchem-154 128 15     SPACE eurjchem-154 128 16 53 53 NUM eurjchem-154 128 17 , , PUNCT eurjchem-154 128 18     SPACE eurjchem-154 128 19 acetaldehyde acetaldehyde NOUN eurjchem-154 128 20     SPACE eurjchem-154 128 21 and and CCONJ eurjchem-154 128 22     SPACE eurjchem-154 128 23 diethyl diethyl NOUN eurjchem-154 128 24     SPACE eurjchem-154 128 25 phosphite phosphite NOUN eurjchem-154 128 26 , , PUNCT eurjchem-154 128 27     SPACE eurjchem-154 128 28 in in ADP eurjchem-154 128 29     SPACE eurjchem-154 128 30 tetrahydrofuran tetrahydrofuran NOUN eurjchem-154 128 31     SPACE eurjchem-154 128 32 containing contain VERB eurjchem-154 128 33     SPACE eurjchem-154 128 34 sodium sodium NOUN eurjchem-154 128 35     SPACE eurjchem-154 128 36 hydride hydride NOUN eurjchem-154 128 37     SPACE eurjchem-154 128 38 as as ADP eurjchem-154 128 39     SPACE eurjchem-154 128 40 a a DET eurjchem-154 128 41     SPACE eurjchem-154 128 42 catalyst catalyst NOUN eurjchem-154 128 43 , , PUNCT eurjchem-154 128 44     SPACE eurjchem-154 128 45 produced produce VERB eurjchem-154 128 46     SPACE eurjchem-154 128 47 one one NUM eurjchem-154 128 48     SPACE eurjchem-154 128 49 isomer isomer NOUN eurjchem-154 128 50     SPACE eurjchem-154 128 51 identified identify VERB eurjchem-154 128 52     SPACE eurjchem-154 128 53 as as ADP eurjchem-154 128 54     SPACE eurjchem-154 128 55 1,2,4‐triazino[3,2‐c 1,2,4‐triazino[3,2‐c NUM eurjchem-154 128 56 ] ] X eurjchem-154 128 57     SPACE eurjchem-154 129 1 [ [ X eurjchem-154 129 2 1,2,4,5]triazaphosphinine 1,2,4,5]triazaphosphinine NUM eurjchem-154 129 3     SPACE eurjchem-154 129 4 74 74 NUM eurjchem-154 129 5 , , PUNCT eurjchem-154 129 6     SPACE eurjchem-154 129 7 likely likely ADJ eurjchem-154 129 8     SPACE eurjchem-154 129 9 through through ADP eurjchem-154 129 10     SPACE eurjchem-154 129 11 the the DET eurjchem-154 129 12     SPACE eurjchem-154 129 13 nonisolable nonisolable ADJ eurjchem-154 129 14     SPACE eurjchem-154 129 15 intermediate intermediate ADJ eurjchem-154 129 16     SPACE eurjchem-154 129 17 72 72 NUM eurjchem-154 129 18 , , PUNCT eurjchem-154 129 19     SPACE eurjchem-154 129 20 which which PRON eurjchem-154 129 21     SPACE eurjchem-154 129 22 spontaneously spontaneously ADV eurjchem-154 129 23     SPACE eurjchem-154 129 24 cyclized cyclize VERB eurjchem-154 129 25     SPACE eurjchem-154 129 26 through through ADP eurjchem-154 129 27     SPACE eurjchem-154 129 28 n‐2 n‐2 NOUN eurjchem-154 129 29     SPACE eurjchem-154 129 30 of of ADP eurjchem-154 129 31     SPACE eurjchem-154 129 32 the the DET eurjchem-154 129 33     SPACE eurjchem-154 129 34 triazine triazine NOUN eurjchem-154 129 35     SPACE eurjchem-154 129 36 ring ring NOUN eurjchem-154 129 37     SPACE eurjchem-154 129 38 and and CCONJ eurjchem-154 129 39     SPACE eurjchem-154 129 40 not not PART eurjchem-154 129 41     SPACE eurjchem-154 129 42 the the DET eurjchem-154 129 43     SPACE eurjchem-154 129 44 exocyclic exocyclic NOUN eurjchem-154 129 45     SPACE eurjchem-154 129 46 n‐amino n‐amino ADP eurjchem-154 129 47 , , PUNCT eurjchem-154 129 48     SPACE eurjchem-154 129 49 with with ADP eurjchem-154 129 50     SPACE eurjchem-154 129 51 elimination elimination NOUN eurjchem-154 129 52     SPACE eurjchem-154 129 53 of of ADP eurjchem-154 129 54     SPACE eurjchem-154 129 55 one one NUM eurjchem-154 129 56     SPACE eurjchem-154 129 57 molecule molecule NOUN eurjchem-154 129 58     SPACE eurjchem-154 129 59 of of ADP eurjchem-154 129 60     SPACE eurjchem-154 129 61 ethanol ethanol NOUN eurjchem-154 129 62     SPACE eurjchem-154 129 63 ( ( PUNCT eurjchem-154 129 64 route route NOUN eurjchem-154 129 65     SPACE eurjchem-154 129 66 b b NOUN eurjchem-154 129 67 , , PUNCT eurjchem-154 129 68     SPACE eurjchem-154 129 69 scheme scheme NOUN eurjchem-154 129 70     SPACE eurjchem-154 129 71 24 24 NUM eurjchem-154 129 72 ) ) PUNCT eurjchem-154 129 73     SPACE eurjchem-154 130 1 [ [ X eurjchem-154 130 2 28 28 NUM eurjchem-154 130 3 ] ] PUNCT eurjchem-154 130 4 . . PUNCT eurjchem-154 130 5         SPACE eurjchem-154 131 1 n n CCONJ eurjchem-154 131 2 n n PRON eurjchem-154 131 3 nch3 nch3 PROPN eurjchem-154 131 4 o o PROPN eurjchem-154 131 5 nh nh PROPN eurjchem-154 131 6 nh2 nh2 PROPN eurjchem-154 131 7 nh2 nh2 PROPN eurjchem-154 131 8 n n PRON eurjchem-154 131 9 nch3 nch3 PROPN eurjchem-154 131 10 o o PROPN eurjchem-154 131 11 nh2 nh2 PROPN eurjchem-154 131 12 nh nh PROPN eurjchem-154 131 13 n n CCONJ eurjchem-154 131 14 n n PROPN eurjchem-154 132 1 h h NOUN eurjchem-154 132 2 ch3 ch3 PROPN eurjchem-154 132 3 p p PROPN eurjchem-154 132 4 o o PROPN eurjchem-154 132 5 oet oet ADJ eurjchem-154 132 6 eto eto PROPN eurjchem-154 132 7 h h PROPN eurjchem-154 132 8 thf thf PROPN eurjchem-154 132 9 - - PUNCT eurjchem-154 132 10 nah nah INTJ eurjchem-154 132 11 n n CCONJ eurjchem-154 132 12 n n PROPN eurjchem-154 132 13 nh nh PROPN eurjchem-154 132 14 p p PROPN eurjchem-154 132 15 n n PRON eurjchem-154 132 16 nch3 nch3 PROPN eurjchem-154 132 17 o o PROPN eurjchem-154 132 18 nh2 nh2 PROPN eurjchem-154 133 1 o o PROPN eurjchem-154 133 2 h h PROPN eurjchem-154 133 3 ch3 ch3 PROPN eurjchem-154 133 4 eto eto PROPN eurjchem-154 133 5 n n PROPN eurjchem-154 133 6 nch3 nch3 PROPN eurjchem-154 133 7 o o PROPN eurjchem-154 133 8 n n CCONJ eurjchem-154 133 9 n n PROPN eurjchem-154 133 10 h h PROPN eurjchem-154 133 11 nh nh PROPN eurjchem-154 133 12 nh nh PROPN eurjchem-154 134 1 p p PROPN eurjchem-154 134 2 o o PROPN eurjchem-154 134 3 oeth oeth PROPN eurjchem-154 134 4 ch3 ch3 PROPN eurjchem-154 134 5 n n PROPN eurjchem-154 134 6 nh nh PROPN eurjchem-154 134 7 p p PROPN eurjchem-154 134 8 nh nh PROPN eurjchem-154 134 9 nh nh PROPN eurjchem-154 134 10 n n PRON eurjchem-154 134 11 nch3 nch3 PROPN eurjchem-154 135 1 o o X eurjchem-154 135 2 o o X eurjchem-154 135 3 ch3 ch3 PROPN eurjchem-154 135 4 thf thf PROPN eurjchem-154 135 5 - - PUNCT eurjchem-154 135 6 hcl hcl PROPN eurjchem-154 135 7 ch3p(o)(nme2)2 ch3p(o)(nme2)2 PROPN eurjchem-154 135 8 53 53 NUM eurjchem-154 135 9 a a DET eurjchem-154 135 10 b b PROPN eurjchem-154 135 11 route route NOUN eurjchem-154 135 12 a a DET eurjchem-154 135 13 route route NOUN eurjchem-154 135 14 b b PROPN eurjchem-154 135 15 72 72 NUM eurjchem-154 135 16 73 73 NUM eurjchem-154 135 17 i i NOUN eurjchem-154 135 18 ) ) PUNCT eurjchem-154 135 19 ch3cho ch3cho PROPN eurjchem-154 135 20 ii ii PROPN eurjchem-154 135 21 ) ) PUNCT eurjchem-154 135 22 h h NOUN eurjchem-154 135 23 - - PUNCT eurjchem-154 135 24 p(o)(oet)2 p(o)(oet)2 NOUN eurjchem-154 135 25 71 71 NUM eurjchem-154 135 26 74 74 NUM eurjchem-154 135 27 59 59 NUM eurjchem-154 135 28 % % NOUN eurjchem-154 135 29 scheme scheme NOUN eurjchem-154 135 30     SPACE eurjchem-154 135 31 24 24 NUM eurjchem-154 135 32         SPACE eurjchem-154 135 33 2.3.4 2.3.4 NUM eurjchem-154 135 34 . . PUNCT eurjchem-154 135 35     SPACE eurjchem-154 135 36 seven­membered seven­membere VERB eurjchem-154 135 37     SPACE eurjchem-154 135 38 rings ring NOUN eurjchem-154 135 39         SPACE eurjchem-154 135 40 also also ADV eurjchem-154 135 41 , , PUNCT eurjchem-154 135 42     SPACE eurjchem-154 135 43 novel novel NOUN eurjchem-154 135 44     SPACE eurjchem-154 135 45 seven‐membered seven‐membere VERB eurjchem-154 135 46     SPACE eurjchem-154 135 47 phosphorus phosphorus NOUN eurjchem-154 135 48     SPACE eurjchem-154 135 49 heterocycles heterocycle NOUN eurjchem-154 135 50     SPACE eurjchem-154 135 51 was be AUX eurjchem-154 135 52     SPACE eurjchem-154 135 53 achieved achieve VERB eurjchem-154 135 54     SPACE eurjchem-154 135 55 by by ADP eurjchem-154 135 56     SPACE eurjchem-154 135 57 reaction reaction NOUN eurjchem-154 135 58     SPACE eurjchem-154 135 59 of of ADP eurjchem-154 135 60     SPACE eurjchem-154 135 61 4‐amino‐3‐mercapto‐6‐methyl‐1,2,4‐ 4‐amino‐3‐mercapto‐6‐methyl‐1,2,4‐ NUM eurjchem-154 135 62 triazin‐5(4h)‐one triazin‐5(4h)‐one NOUN eurjchem-154 135 63     SPACE eurjchem-154 135 64 ( ( PUNCT eurjchem-154 135 65 47 47 NUM eurjchem-154 135 66 ) ) PUNCT eurjchem-154 135 67     SPACE eurjchem-154 135 68 with with ADP eurjchem-154 135 69     SPACE eurjchem-154 135 70 phenacyl phenacyl NOUN eurjchem-154 135 71     SPACE eurjchem-154 135 72 triphenylphosphonium triphenylphosphonium NOUN eurjchem-154 135 73     SPACE eurjchem-154 135 74 bromide bromide NOUN eurjchem-154 135 75     SPACE eurjchem-154 135 76 in in ADP eurjchem-154 135 77     SPACE eurjchem-154 135 78 boiling boil VERB eurjchem-154 135 79     SPACE eurjchem-154 135 80 dimethylformamide dimethylformamide NOUN eurjchem-154 135 81     SPACE eurjchem-154 135 82 containing contain VERB eurjchem-154 135 83     SPACE eurjchem-154 135 84 a a DET eurjchem-154 135 85     SPACE eurjchem-154 135 86 catalytic catalytic ADJ eurjchem-154 135 87     SPACE eurjchem-154 135 88 amount amount NOUN eurjchem-154 135 89     SPACE eurjchem-154 135 90 of of ADP eurjchem-154 135 91     SPACE eurjchem-154 135 92 piperidine piperidine NOUN eurjchem-154 135 93     SPACE eurjchem-154 135 94 to to PART eurjchem-154 135 95     SPACE eurjchem-154 135 96 afford afford VERB eurjchem-154 135 97     SPACE eurjchem-154 135 98 1,2,4‐triazino[4,3‐f][1,5,6,2 1,2,4‐triazino[4,3‐f][1,5,6,2 NUM eurjchem-154 135 99 ] ] NOUN eurjchem-154 135 100     SPACE eurjchem-154 135 101 thiadiazaphosphepine thiadiazaphosphepine NOUN eurjchem-154 135 102     SPACE eurjchem-154 135 103 76 76 NUM eurjchem-154 135 104     SPACE eurjchem-154 135 105 derivative derivative NOUN eurjchem-154 135 106     SPACE eurjchem-154 135 107 ( ( PUNCT eurjchem-154 135 108 scheme scheme NOUN eurjchem-154 135 109     SPACE eurjchem-154 135 110 25 25 NUM eurjchem-154 135 111 ) ) PUNCT eurjchem-154 135 112     SPACE eurjchem-154 136 1 [ [ X eurjchem-154 136 2 28 28 NUM eurjchem-154 136 3 ] ] PUNCT eurjchem-154 136 4 . . PUNCT eurjchem-154 136 5     SPACE eurjchem-154 136 6 formation formation NOUN eurjchem-154 136 7     SPACE eurjchem-154 136 8 of of ADP eurjchem-154 136 9     SPACE eurjchem-154 136 10 compound compound NOUN eurjchem-154 136 11     SPACE eurjchem-154 136 12 76 76 NUM eurjchem-154 136 13     SPACE eurjchem-154 136 14 may may AUX eurjchem-154 136 15     SPACE eurjchem-154 136 16 occur occur VERB eurjchem-154 136 17     SPACE eurjchem-154 136 18 through through ADP eurjchem-154 136 19     SPACE eurjchem-154 136 20 the the DET eurjchem-154 136 21     SPACE eurjchem-154 136 22 attack attack NOUN eurjchem-154 136 23     SPACE eurjchem-154 136 24 of of ADP eurjchem-154 136 25     SPACE eurjchem-154 136 26 the the DET eurjchem-154 136 27     SPACE eurjchem-154 136 28 electron electron NOUN eurjchem-154 136 29     SPACE eurjchem-154 136 30 pairs pair NOUN eurjchem-154 136 31     SPACE eurjchem-154 136 32 of of ADP eurjchem-154 136 33     SPACE eurjchem-154 136 34 the the DET eurjchem-154 136 35     SPACE eurjchem-154 136 36 sh sh PROPN eurjchem-154 136 37     SPACE eurjchem-154 136 38 group group NOUN eurjchem-154 136 39     SPACE eurjchem-154 136 40 on on ADP eurjchem-154 136 41     SPACE eurjchem-154 136 42 phosphorus phosphorus NOUN eurjchem-154 136 43     SPACE eurjchem-154 136 44 atom atom NOUN eurjchem-154 136 45     SPACE eurjchem-154 136 46 of of ADP eurjchem-154 136 47     SPACE eurjchem-154 136 48 the the DET eurjchem-154 136 49     SPACE eurjchem-154 136 50 phosphonium phosphonium NOUN eurjchem-154 136 51     SPACE eurjchem-154 136 52 salt salt NOUN eurjchem-154 136 53     SPACE eurjchem-154 136 54 to to PART eurjchem-154 136 55     SPACE eurjchem-154 136 56 remove remove VERB eurjchem-154 136 57     SPACE eurjchem-154 136 58 hydrogen hydrogen NOUN eurjchem-154 136 59     SPACE eurjchem-154 136 60 halide halide NOUN eurjchem-154 136 61     SPACE eurjchem-154 136 62 which which PRON eurjchem-154 136 63     SPACE eurjchem-154 136 64 may may AUX eurjchem-154 136 65     SPACE eurjchem-154 136 66 afford afford VERB eurjchem-154 136 67     SPACE eurjchem-154 136 68 the the DET eurjchem-154 136 69     SPACE eurjchem-154 136 70 intermediates intermediate NOUN eurjchem-154 136 71     SPACE eurjchem-154 136 72 75 75 NUM eurjchem-154 136 73 , , PUNCT eurjchem-154 136 74     SPACE eurjchem-154 136 75 followed follow VERB eurjchem-154 136 76     SPACE eurjchem-154 136 77 by by ADP eurjchem-154 136 78     SPACE eurjchem-154 136 79 an an DET eurjchem-154 136 80     SPACE eurjchem-154 136 81 intramolecular intramolecular ADJ eurjchem-154 136 82     SPACE eurjchem-154 136 83 nucleophilic nucleophilic ADJ eurjchem-154 136 84     SPACE eurjchem-154 136 85 attack attack NOUN eurjchem-154 136 86     SPACE eurjchem-154 136 87 of of ADP eurjchem-154 136 88     SPACE eurjchem-154 136 89 the the DET eurjchem-154 136 90     SPACE eurjchem-154 136 91 amino amino NOUN eurjchem-154 136 92     SPACE eurjchem-154 136 93 group group NOUN eurjchem-154 136 94     SPACE eurjchem-154 136 95 on on ADP eurjchem-154 136 96     SPACE eurjchem-154 136 97 carbonyl carbonyl NOUN eurjchem-154 136 98     SPACE eurjchem-154 136 99 group group NOUN eurjchem-154 136 100     SPACE eurjchem-154 136 101 with with ADP eurjchem-154 136 102     SPACE eurjchem-154 136 103 elimination elimination NOUN eurjchem-154 136 104     SPACE eurjchem-154 136 105 of of ADP eurjchem-154 136 106     SPACE eurjchem-154 136 107 water water NOUN eurjchem-154 136 108     SPACE eurjchem-154 136 109 to to ADP eurjchem-154 136 110     SPACE eurjchem-154 136 111 76 76 NUM eurjchem-154 136 112     SPACE eurjchem-154 137 1 [ [ X eurjchem-154 137 2 28 28 NUM eurjchem-154 137 3 ] ] PUNCT eurjchem-154 137 4 . . PUNCT eurjchem-154 137 5     SPACE eurjchem-154 137 6 finally finally ADV eurjchem-154 137 7 , , PUNCT eurjchem-154 137 8     SPACE eurjchem-154 137 9 1,2,4‐triazino 1,2,4‐triazino NOUN eurjchem-154 137 10     SPACE eurjchem-154 138 1 [ [ X eurjchem-154 138 2 4,3‐e][1,2,5,6,3]tetrazaphosphepine 4,3‐e][1,2,5,6,3]tetrazaphosphepine NUM eurjchem-154 138 3     SPACE eurjchem-154 138 4 derivative derivative NOUN eurjchem-154 138 5     SPACE eurjchem-154 138 6 77 77 NUM eurjchem-154 138 7     SPACE eurjchem-154 138 8 was be AUX eurjchem-154 138 9     SPACE eurjchem-154 138 10 obtained obtain VERB eurjchem-154 138 11     SPACE eurjchem-154 138 12 by by ADP eurjchem-154 138 13     SPACE eurjchem-154 138 14 cyclocondensation cyclocondensation NOUN eurjchem-154 138 15     SPACE eurjchem-154 138 16 of of ADP eurjchem-154 138 17     SPACE eurjchem-154 138 18 4‐amino‐3‐ 4‐amino‐3‐ PROPN eurjchem-154 138 19 hydrazino‐1,2,4‐triazin‐5(4h)‐one hydrazino‐1,2,4‐triazin‐5(4h)‐one NOUN eurjchem-154 138 20     SPACE eurjchem-154 138 21 ( ( PUNCT eurjchem-154 138 22 53 53 NUM eurjchem-154 138 23 ) ) PUNCT eurjchem-154 138 24     SPACE eurjchem-154 138 25 with with ADP eurjchem-154 138 26     SPACE eurjchem-154 138 27 acetyl acetyl NOUN eurjchem-154 138 28     SPACE eurjchem-154 138 29 triphenyl triphenyl NOUN eurjchem-154 138 30     SPACE eurjchem-154 138 31 phosphonium phosphonium NOUN eurjchem-154 138 32     SPACE eurjchem-154 138 33 chloride chloride NOUN eurjchem-154 138 34     SPACE eurjchem-154 138 35 in in ADP eurjchem-154 138 36     SPACE eurjchem-154 138 37 dimethylformamide dimethylformamide NOUN eurjchem-154 138 38     SPACE eurjchem-154 138 39 containing contain VERB eurjchem-154 138 40     SPACE eurjchem-154 138 41 few few ADJ eurjchem-154 138 42     SPACE eurjchem-154 138 43 drops drop NOUN eurjchem-154 138 44     SPACE eurjchem-154 138 45 of of ADP eurjchem-154 138 46     SPACE eurjchem-154 138 47 piperidine piperidine NOUN eurjchem-154 138 48     SPACE eurjchem-154 138 49 ( ( PUNCT eurjchem-154 138 50 scheme scheme NOUN eurjchem-154 138 51     SPACE eurjchem-154 138 52 26 26 NUM eurjchem-154 138 53 ) ) PUNCT eurjchem-154 138 54     SPACE eurjchem-154 139 1 [ [ X eurjchem-154 139 2 28 28 NUM eurjchem-154 139 3 ] ] PUNCT eurjchem-154 139 4 . . PUNCT eurjchem-154 139 5         SPACE eurjchem-154 140 1 n n CCONJ eurjchem-154 140 2 n n PRON eurjchem-154 140 3 nch3 nch3 PROPN eurjchem-154 141 1 o o INTJ eurjchem-154 141 2 sh sh PROPN eurjchem-154 141 3 nh2 nh2 PROPN eurjchem-154 141 4 n n PRON eurjchem-154 141 5 nch3 nch3 PROPN eurjchem-154 141 6 o o PROPN eurjchem-154 141 7 n n CCONJ eurjchem-154 141 8 s s NOUN eurjchem-154 141 9 n n CCONJ eurjchem-154 141 10 p(ph)3 p(ph)3 PROPN eurjchem-154 141 11 ph ph NOUN eurjchem-154 141 12 ( ( PUNCT eurjchem-154 141 13 ph)3p ph)3p NOUN eurjchem-154 141 14 ch2coph ch2coph PUNCT eurjchem-154 141 15 n n PRON eurjchem-154 141 16 nch3 nch3 PROPN eurjchem-154 141 17 o o PROPN eurjchem-154 142 1 n n CCONJ eurjchem-154 142 2 s s PART eurjchem-154 142 3 nh2 nh2 NOUN eurjchem-154 142 4 p(ph)3 p(ph)3 PROPN eurjchem-154 142 5 o o NOUN eurjchem-154 142 6 ph ph PROPN eurjchem-154 142 7 + + CCONJ eurjchem-154 142 8 dmf dmf PROPN eurjchem-154 142 9 -hbr -hbr PUNCT eurjchem-154 142 10 -h2o -h2o VERB eurjchem-154 142 11 47 47 NUM eurjchem-154 142 12 75 75 NUM eurjchem-154 142 13 76 76 NUM eurjchem-154 142 14 65 65 NUM eurjchem-154 142 15 % % NOUN eurjchem-154 142 16 br br NOUN eurjchem-154 142 17 scheme scheme NOUN eurjchem-154 142 18     SPACE eurjchem-154 142 19 25 25 NUM eurjchem-154 142 20     SPACE eurjchem-154 142 21 396 396 NUM eurjchem-154 142 22     SPACE eurjchem-154 142 23 abdel­rahman abdel­rahman NOUN eurjchem-154 142 24     SPACE eurjchem-154 142 25 et et NOUN eurjchem-154 142 26     SPACE eurjchem-154 142 27 al al PROPN eurjchem-154 142 28 . . PROPN eurjchem-154 142 29     SPACE eurjchem-154 142 30 / / SYM eurjchem-154 142 31     SPACE eurjchem-154 142 32 european european ADJ eurjchem-154 142 33     SPACE eurjchem-154 142 34 journal journal NOUN eurjchem-154 142 35     SPACE eurjchem-154 142 36 of of ADP eurjchem-154 142 37     SPACE eurjchem-154 142 38 chemistry chemistry NOUN eurjchem-154 142 39     SPACE eurjchem-154 142 40 1 1 NUM eurjchem-154 142 41     SPACE eurjchem-154 142 42 ( ( PUNCT eurjchem-154 142 43 4 4 NUM eurjchem-154 142 44 ) ) PUNCT eurjchem-154 142 45     SPACE eurjchem-154 142 46 ( ( PUNCT eurjchem-154 142 47 2010 2010 NUM eurjchem-154 142 48 ) ) PUNCT eurjchem-154 142 49     SPACE eurjchem-154 142 50 388­396 388­396 NUM eurjchem-154 142 51             SPACE eurjchem-154 142 52 n n ADP eurjchem-154 142 53 n n PRON eurjchem-154 142 54 nch3 nch3 PROPN eurjchem-154 142 55 o o PROPN eurjchem-154 142 56 nh nh PROPN eurjchem-154 142 57 nh2 nh2 PROPN eurjchem-154 142 58 nh2 nh2 PROPN eurjchem-154 142 59 n n PRON eurjchem-154 142 60 nch3 nch3 PROPN eurjchem-154 142 61 o o PROPN eurjchem-154 142 62 n n CCONJ eurjchem-154 143 1 n n PROPN eurjchem-154 143 2 h h NOUN eurjchem-154 143 3 n n CCONJ eurjchem-154 143 4 nh nh PROPN eurjchem-154 143 5 p(ph)3 p(ph)3 PROPN eurjchem-154 143 6 ch3 ch3 PROPN eurjchem-154 143 7 ( ( PUNCT eurjchem-154 143 8 ph)3p ph)3p ADP eurjchem-154 143 9 coch3 coch3 PROPN eurjchem-154 143 10 52 52 NUM eurjchem-154 143 11 + + CCONJ eurjchem-154 143 12 dmf dmf X eurjchem-154 143 13 76 76 NUM eurjchem-154 143 14 43 43 NUM eurjchem-154 143 15 % % NOUN eurjchem-154 143 16 cl cl NOUN eurjchem-154 143 17 scheme scheme NOUN eurjchem-154 143 18     SPACE eurjchem-154 143 19 26 26 NUM eurjchem-154 143 20         SPACE eurjchem-154 143 21 references reference NOUN eurjchem-154 143 22         SPACE eurjchem-154 143 23 [ [ X eurjchem-154 143 24 1 1 NUM eurjchem-154 143 25 ] ] PUNCT eurjchem-154 143 26 . . PUNCT eurjchem-154 144 1 holla holla PROPN eurjchem-154 144 2 , , PUNCT eurjchem-154 144 3     SPACE eurjchem-154 144 4 b. b. PROPN eurjchem-154 144 5     SPACE eurjchem-154 144 6 s. s. PROPN eurjchem-154 144 7 ; ; PUNCT eurjchem-154 144 8     SPACE eurjchem-154 144 9 sarojini sarojini NOUN eurjchem-154 144 10 , , PUNCT eurjchem-154 144 11     SPACE eurjchem-154 144 12 b. b. PROPN eurjchem-154 144 13     SPACE eurjchem-154 144 14 k. k. PROPN eurjchem-154 144 15 ; ; PUNCT eurjchem-154 144 16     SPACE eurjchem-154 144 17 gonsalves gonsalve NOUN eurjchem-154 144 18 , , PUNCT eurjchem-154 144 19     SPACE eurjchem-154 144 20 r. r. PROPN eurjchem-154 144 21     SPACE eurjchem-154 144 22 farmaco farmaco PROPN eurjchem-154 144 23     SPACE eurjchem-154 144 24 1998 1998 NUM eurjchem-154 144 25 , , PUNCT eurjchem-154 144 26     SPACE eurjchem-154 144 27 53 53 NUM eurjchem-154 144 28 , , PUNCT eurjchem-154 144 29     SPACE eurjchem-154 144 30 395‐398 395‐398 NUM eurjchem-154 144 31 . . PUNCT eurjchem-154 144 32     SPACE eurjchem-154 145 1 [ [ X eurjchem-154 145 2 2 2 NUM eurjchem-154 145 3 ] ] PUNCT eurjchem-154 145 4 . . PUNCT eurjchem-154 145 5 holla holla PROPN eurjchem-154 145 6 , , PUNCT eurjchem-154 145 7     SPACE eurjchem-154 145 8 b. b. PROPN eurjchem-154 145 9     SPACE eurjchem-154 145 10 s. s. PROPN eurjchem-154 145 11 ; ; PUNCT eurjchem-154 145 12     SPACE eurjchem-154 145 13 sarojini sarojini NOUN eurjchem-154 145 14 , , PUNCT eurjchem-154 145 15     SPACE eurjchem-154 145 16 b. b. PROPN eurjchem-154 145 17     SPACE eurjchem-154 145 18 k. k. PROPN eurjchem-154 145 19 ; ; PUNCT eurjchem-154 145 20     SPACE eurjchem-154 145 21 shridhara shridhara PROPN eurjchem-154 145 22 , , PUNCT eurjchem-154 145 23     SPACE eurjchem-154 145 24 k. k. PROPN eurjchem-154 145 25 ; ; PUNCT eurjchem-154 145 26     SPACE eurjchem-154 145 27 antong antong NOUN eurjchem-154 145 28 , , PUNCT eurjchem-154 145 29     SPACE eurjchem-154 145 30 g. g. NOUN eurjchem-154 145 31     SPACE eurjchem-154 145 32 farmaco farmaco PROPN eurjchem-154 145 33     SPACE eurjchem-154 145 34 1999 1999 NUM eurjchem-154 145 35 , , PUNCT eurjchem-154 145 36     SPACE eurjchem-154 145 37 54 54 NUM eurjchem-154 145 38 , , PUNCT eurjchem-154 145 39     SPACE eurjchem-154 145 40 149‐151 149‐151 NUM eurjchem-154 145 41 . . PUNCT eurjchem-154 145 42     SPACE eurjchem-154 146 1 [ [ X eurjchem-154 146 2 3 3 NUM eurjchem-154 146 3 ] ] PUNCT eurjchem-154 146 4 . . PUNCT eurjchem-154 147 1 deeb deeb PROPN eurjchem-154 147 2 , , PUNCT eurjchem-154 147 3     SPACE eurjchem-154 147 4 a. a. NOUN eurjchem-154 147 5 ; ; PUNCT eurjchem-154 147 6     SPACE eurjchem-154 147 7 el‐mariah el‐mariah PROPN eurjchem-154 147 8 , , PUNCT eurjchem-154 147 9     SPACE eurjchem-154 147 10 f. f. PROPN eurjchem-154 147 11 ; ; PUNCT eurjchem-154 147 12     SPACE eurjchem-154 147 13 hosny hosny PROPN eurjchem-154 147 14 , , PUNCT eurjchem-154 147 15     SPACE eurjchem-154 147 16 m. m. NOUN eurjchem-154 147 17     SPACE eurjchem-154 147 18 bioorg bioorg PROPN eurjchem-154 147 19 . . PUNCT eurjchem-154 147 20     SPACE eurjchem-154 147 21 med med PROPN eurjchem-154 147 22 . . PUNCT eurjchem-154 147 23     SPACE eurjchem-154 147 24 chem chem NOUN eurjchem-154 147 25 . . PUNCT eurjchem-154 147 26     SPACE eurjchem-154 148 1 lett lett PROPN eurjchem-154 148 2 . . PUNCT eurjchem-154 148 3     SPACE eurjchem-154 149 1 2004 2004 NUM eurjchem-154 149 2 , , PUNCT eurjchem-154 149 3     SPACE eurjchem-154 149 4 14 14 NUM eurjchem-154 149 5 , , PUNCT eurjchem-154 149 6     SPACE eurjchem-154 149 7 5013‐5017 5013‐5017 NUM eurjchem-154 149 8 . . PUNCT eurjchem-154 149 9     SPACE eurjchem-154 150 1 [ [ X eurjchem-154 150 2 4 4 NUM eurjchem-154 150 3 ] ] PUNCT eurjchem-154 150 4 . . PUNCT eurjchem-154 151 1 el‐badawi el‐badawi ADJ eurjchem-154 151 2 , , PUNCT eurjchem-154 151 3     SPACE eurjchem-154 151 4 m. m. NOUN eurjchem-154 151 5     SPACE eurjchem-154 151 6 a. a. NOUN eurjchem-154 151 7 ; ; PUNCT eurjchem-154 151 8     SPACE eurjchem-154 151 9 el‐barbary el‐barbary NOUN eurjchem-154 151 10 , , PUNCT eurjchem-154 151 11     SPACE eurjchem-154 151 12 a. a. NOUN eurjchem-154 151 13     SPACE eurjchem-154 151 14 a. a. NOUN eurjchem-154 151 15 ; ; PUNCT eurjchem-154 151 16     SPACE eurjchem-154 151 17 loksha loksha NOUN eurjchem-154 151 18 , , PUNCT eurjchem-154 151 19     SPACE eurjchem-154 151 20 y. y. NOUN eurjchem-154 151 21     SPACE eurjchem-154 151 22 m. m. NOUN eurjchem-154 151 23 ; ; PUNCT eurjchem-154 151 24     SPACE eurjchem-154 151 25 el‐daly el‐daly PROPN eurjchem-154 151 26 , , PUNCT eurjchem-154 151 27     SPACE eurjchem-154 151 28 m. m. NOUN eurjchem-154 151 29     SPACE eurjchem-154 151 30 phosphorus phosphorus NOUN eurjchem-154 151 31     SPACE eurjchem-154 151 32 sulfur sulfur NOUN eurjchem-154 151 33     SPACE eurjchem-154 151 34 silicon silicon NOUN eurjchem-154 151 35     SPACE eurjchem-154 151 36 relat relat NOUN eurjchem-154 151 37 . . PUNCT eurjchem-154 151 38     SPACE eurjchem-154 151 39 elem elem NOUN eurjchem-154 151 40 . . PUNCT eurjchem-154 151 41     SPACE eurjchem-154 152 1 2002 2002 NUM eurjchem-154 152 2 , , PUNCT eurjchem-154 152 3     SPACE eurjchem-154 152 4 177 177 NUM eurjchem-154 152 5 , , PUNCT eurjchem-154 152 6     SPACE eurjchem-154 152 7 587‐596 587‐596 NUM eurjchem-154 152 8 . . PUNCT eurjchem-154 152 9     SPACE eurjchem-154 153 1 [ [ X eurjchem-154 153 2 5 5 NUM eurjchem-154 153 3 ] ] PUNCT eurjchem-154 153 4 . . PUNCT eurjchem-154 154 1 ibrahim ibrahim PROPN eurjchem-154 154 2 , , PUNCT eurjchem-154 154 3     SPACE eurjchem-154 154 4 m. m. NOUN eurjchem-154 154 5     SPACE eurjchem-154 154 6 a. a. NOUN eurjchem-154 154 7     SPACE eurjchem-154 154 8 heterocycles heterocycle NOUN eurjchem-154 154 9     SPACE eurjchem-154 154 10 2010 2010 NUM eurjchem-154 154 11 , , PUNCT eurjchem-154 154 12     SPACE eurjchem-154 154 13 81 81 NUM eurjchem-154 154 14 , , PUNCT eurjchem-154 154 15     SPACE eurjchem-154 154 16 1393‐1418 1393‐1418 NUM eurjchem-154 154 17 . . PUNCT eurjchem-154 154 18       SPACE eurjchem-154 155 1 [ [ X eurjchem-154 155 2 6 6 NUM eurjchem-154 155 3 ] ] PUNCT eurjchem-154 155 4 . . PUNCT eurjchem-154 156 1 oganisyan oganisyan ADJ eurjchem-154 156 2 , , PUNCT eurjchem-154 156 3     SPACE eurjchem-154 156 4 a. a. NOUN eurjchem-154 156 5     SPACE eurjchem-154 156 6 s. s. PROPN eurjchem-154 156 7 ; ; PUNCT eurjchem-154 156 8     SPACE eurjchem-154 156 9 grigoryan grigoryan ADJ eurjchem-154 156 10 , , PUNCT eurjchem-154 156 11     SPACE eurjchem-154 156 12 g. g. NOUN eurjchem-154 156 13     SPACE eurjchem-154 156 14 o. o. PROPN eurjchem-154 156 15 ; ; PUNCT eurjchem-154 156 16     SPACE eurjchem-154 156 17 noravyan noravyan NOUN eurjchem-154 156 18 , , PUNCT eurjchem-154 156 19     SPACE eurjchem-154 156 20 a. a. NOUN eurjchem-154 156 21     SPACE eurjchem-154 156 22 s. s. PROPN eurjchem-154 156 23 ; ; PUNCT eurjchem-154 156 24     SPACE eurjchem-154 156 25 dzhagatspanyan dzhagatspanyan ADJ eurjchem-154 156 26 , , PUNCT eurjchem-154 156 27     SPACE eurjchem-154 156 28 i. i. NOUN eurjchem-154 156 29     SPACE eurjchem-154 156 30 a. a. NOUN eurjchem-154 156 31 ; ; PUNCT eurjchem-154 156 32     SPACE eurjchem-154 156 33 melikyan melikyan NOUN eurjchem-154 156 34 , , PUNCT eurjchem-154 156 35     SPACE eurjchem-154 156 36 g. g. PROPN eurjchem-154 156 37     SPACE eurjchem-154 156 38 g. g. PROPN eurjchem-154 156 39     SPACE eurjchem-154 156 40 pharm pharm PROPN eurjchem-154 156 41 . . PUNCT eurjchem-154 156 42     SPACE eurjchem-154 156 43 chem chem NOUN eurjchem-154 156 44 . . PUNCT eurjchem-154 156 45     SPACE eurjchem-154 157 1 j. j. PROPN eurjchem-154 157 2 , , PUNCT eurjchem-154 157 3     SPACE eurjchem-154 157 4 2001 2001 NUM eurjchem-154 157 5 , , PUNCT eurjchem-154 157 6     SPACE eurjchem-154 157 7 35 35 NUM eurjchem-154 157 8 , , PUNCT eurjchem-154 157 9     SPACE eurjchem-154 157 10 124‐126 124‐126 NOUN eurjchem-154 157 11 . . PUNCT eurjchem-154 157 12     SPACE eurjchem-154 158 1 [ [ X eurjchem-154 158 2 7 7 NUM eurjchem-154 158 3 ] ] PUNCT eurjchem-154 158 4 . . PUNCT eurjchem-154 159 1 boehner boehner PROPN eurjchem-154 159 2 , , PUNCT eurjchem-154 159 3     SPACE eurjchem-154 159 4 b. b. PROPN eurjchem-154 159 5 ; ; PUNCT eurjchem-154 159 6     SPACE eurjchem-154 159 7 ciba‐geigy ciba‐geigy NOUN eurjchem-154 159 8 , , PUNCT eurjchem-154 159 9     SPACE eurjchem-154 159 10 a. a. NOUN eurjchem-154 159 11     SPACE eurjchem-154 159 12 g. g. PROPN eurjchem-154 159 13     SPACE eurjchem-154 159 14 eur eur PROPN eurjchem-154 159 15 . . PUNCT eurjchem-154 159 16     SPACE eurjchem-154 160 1 pat pat PROPN eurjchem-154 160 2 . . PROPN eurjchem-154 160 3     SPACE eurjchem-154 160 4 1986 1986 NUM eurjchem-154 160 5 ; ; PUNCT eurjchem-154 160 6     SPACE eurjchem-154 160 7 chem chem NOUN eurjchem-154 160 8 . . PUNCT eurjchem-154 160 9     SPACE eurjchem-154 160 10 abstr abstr PROPN eurjchem-154 160 11 . . PUNCT eurjchem-154 160 12     SPACE eurjchem-154 161 1 1986 1986 NUM eurjchem-154 161 2 , , PUNCT eurjchem-154 161 3     SPACE eurjchem-154 161 4 105 105 NUM eurjchem-154 161 5 , , PUNCT eurjchem-154 161 6     SPACE eurjchem-154 161 7 6522e 6522e NOUN eurjchem-154 161 8 . . PUNCT eurjchem-154 161 9     SPACE eurjchem-154 162 1 [ [ X eurjchem-154 162 2 8 8 NUM eurjchem-154 162 3 ] ] PUNCT eurjchem-154 162 4 . . PUNCT eurjchem-154 163 1 timer timer NOUN eurjchem-154 163 2 , , PUNCT eurjchem-154 163 3     SPACE eurjchem-154 163 4 m. m. NOUN eurjchem-154 163 5 ; ; PUNCT eurjchem-154 163 6     SPACE eurjchem-154 163 7 sauvard sauvard NOUN eurjchem-154 163 8 , , PUNCT eurjchem-154 163 9     SPACE eurjchem-154 163 10 s. s. PROPN eurjchem-154 163 11 ; ; PUNCT eurjchem-154 163 12     SPACE eurjchem-154 163 13 georgescu georgescu NOUN eurjchem-154 163 14 , , PUNCT eurjchem-154 163 15     SPACE eurjchem-154 163 16 c. c. PROPN eurjchem-154 163 17     SPACE eurjchem-154 163 18 m. m. NOUN eurjchem-154 163 19     SPACE eurjchem-154 163 20 biochem biochem PROPN eurjchem-154 163 21 . . PUNCT eurjchem-154 163 22     SPACE eurjchem-154 163 23 pharmacol pharmacol PROPN eurjchem-154 163 24 . . PUNCT eurjchem-154 163 25     SPACE eurjchem-154 163 26 1996 1996 NUM eurjchem-154 163 27 , , PUNCT eurjchem-154 163 28     SPACE eurjchem-154 163 29 15 15 NUM eurjchem-154 163 30 , , PUNCT eurjchem-154 163 31     SPACE eurjchem-154 163 32 408‐410 408‐410 PROPN eurjchem-154 163 33 . . PUNCT eurjchem-154 163 34     SPACE eurjchem-154 164 1 [ [ X eurjchem-154 164 2 9 9 NUM eurjchem-154 164 3 ] ] PUNCT eurjchem-154 164 4 . . PUNCT eurjchem-154 165 1 singh singh PROPN eurjchem-154 165 2 , , PUNCT eurjchem-154 165 3     SPACE eurjchem-154 165 4 k. k. PROPN eurjchem-154 165 5 ; ; PUNCT eurjchem-154 165 6     SPACE eurjchem-154 165 7 barwa barwa NOUN eurjchem-154 165 8 , , PUNCT eurjchem-154 165 9     SPACE eurjchem-154 165 10 m. m. NOUN eurjchem-154 165 11     SPACE eurjchem-154 165 12 s. s. PROPN eurjchem-154 165 13 ; ; PUNCT eurjchem-154 165 14     SPACE eurjchem-154 165 15 tyagi tyagi PROPN eurjchem-154 165 16 , , PUNCT eurjchem-154 165 17     SPACE eurjchem-154 165 18 p. p. NOUN eurjchem-154 165 19     SPACE eurjchem-154 165 20 eur eur PROPN eurjchem-154 165 21 . . PUNCT eurjchem-154 165 22     SPACE eurjchem-154 165 23 j. j. PROPN eurjchem-154 165 24     SPACE eurjchem-154 165 25 med med PROPN eurjchem-154 165 26 . . PUNCT eurjchem-154 165 27     SPACE eurjchem-154 165 28 chem chem NOUN eurjchem-154 165 29 . . PUNCT eurjchem-154 165 30     SPACE eurjchem-154 166 1 2007 2007 NUM eurjchem-154 166 2 , , PUNCT eurjchem-154 166 3     SPACE eurjchem-154 166 4 42 42 NUM eurjchem-154 166 5 , , PUNCT eurjchem-154 166 6     SPACE eurjchem-154 166 7 394‐402 394‐402 NUM eurjchem-154 166 8 . . PUNCT eurjchem-154 166 9     SPACE eurjchem-154 167 1 [ [ X eurjchem-154 167 2 10 10 NUM eurjchem-154 167 3 ] ] PUNCT eurjchem-154 167 4 . . PUNCT eurjchem-154 168 1 ali ali PROPN eurjchem-154 168 2 , , PUNCT eurjchem-154 168 3     SPACE eurjchem-154 168 4 t. t. PROPN eurjchem-154 168 5     SPACE eurjchem-154 168 6 e. e. PROPN eurjchem-154 168 7     SPACE eurjchem-154 168 8 phosphorus phosphorus NOUN eurjchem-154 168 9     SPACE eurjchem-154 168 10 sulfur sulfur NOUN eurjchem-154 168 11     SPACE eurjchem-154 168 12 silicon silicon NOUN eurjchem-154 168 13     SPACE eurjchem-154 168 14 relat relat NOUN eurjchem-154 168 15 . . PUNCT eurjchem-154 168 16     SPACE eurjchem-154 168 17 elem elem NOUN eurjchem-154 168 18 . . PUNCT eurjchem-154 168 19     SPACE eurjchem-154 169 1 2007 2007 NUM eurjchem-154 169 2 , , PUNCT eurjchem-154 169 3     SPACE eurjchem-154 169 4 182 182 NUM eurjchem-154 169 5 , , PUNCT eurjchem-154 169 6     SPACE eurjchem-154 169 7 1717‐1726 1717‐1726 NUM eurjchem-154 169 8 . . PUNCT eurjchem-154 169 9     SPACE eurjchem-154 170 1 [ [ X eurjchem-154 170 2 11 11 NUM eurjchem-154 170 3 ] ] PUNCT eurjchem-154 170 4 . . PUNCT eurjchem-154 171 1 ibrahim ibrahim PROPN eurjchem-154 171 2 , , PUNCT eurjchem-154 171 3     SPACE eurjchem-154 171 4 m. m. NOUN eurjchem-154 171 5     SPACE eurjchem-154 171 6 a. a. NOUN eurjchem-154 171 7 ; ; PUNCT eurjchem-154 171 8     SPACE eurjchem-154 171 9 el‐mahdy el‐mahdy NOUN eurjchem-154 171 10 , , PUNCT eurjchem-154 171 11     SPACE eurjchem-154 171 12 k. k. PROPN eurjchem-154 171 13     SPACE eurjchem-154 171 14 m. m. NOUN eurjchem-154 171 15     SPACE eurjchem-154 171 16 phosphorus phosphorus NOUN eurjchem-154 171 17     SPACE eurjchem-154 171 18 sulfur sulfur NOUN eurjchem-154 171 19     SPACE eurjchem-154 171 20 silicon silicon NOUN eurjchem-154 171 21     SPACE eurjchem-154 171 22 relat relat NOUN eurjchem-154 171 23 . . PUNCT eurjchem-154 171 24     SPACE eurjchem-154 171 25 elem elem NOUN eurjchem-154 171 26 . . PUNCT eurjchem-154 171 27     SPACE eurjchem-154 171 28 2009 2009 NUM eurjchem-154 171 29 , , PUNCT eurjchem-154 171 30     SPACE eurjchem-154 171 31 184 184 NUM eurjchem-154 171 32 , , PUNCT eurjchem-154 171 33     SPACE eurjchem-154 171 34 2945‐2958 2945‐2958 NOUN eurjchem-154 171 35 . . PUNCT eurjchem-154 171 36     SPACE eurjchem-154 172 1 [ [ X eurjchem-154 172 2 12 12 NUM eurjchem-154 172 3 ] ] PUNCT eurjchem-154 172 4 . . PUNCT eurjchem-154 173 1 el‐barbary el‐barbary NOUN eurjchem-154 173 2 , , PUNCT eurjchem-154 173 3     SPACE eurjchem-154 173 4 a. a. NOUN eurjchem-154 173 5     SPACE eurjchem-154 173 6 a. a. NOUN eurjchem-154 173 7 ; ; PUNCT eurjchem-154 173 8     SPACE eurjchem-154 173 9 sakran sakran NOUN eurjchem-154 173 10 , , PUNCT eurjchem-154 173 11     SPACE eurjchem-154 173 12 a. a. NOUN eurjchem-154 173 13     SPACE eurjchem-154 173 14 m. m. NOUN eurjchem-154 173 15 ; ; PUNCT eurjchem-154 173 16     SPACE eurjchem-154 173 17 el‐madani el‐madani ADJ eurjchem-154 173 18 , , PUNCT eurjchem-154 173 19     SPACE eurjchem-154 173 20 a. a. NOUN eurjchem-154 173 21     SPACE eurjchem-154 173 22 m. m. NOUN eurjchem-154 173 23 ; ; PUNCT eurjchem-154 173 24     SPACE eurjchem-154 173 25 claus claus NOUN eurjchem-154 173 26 , , PUNCT eurjchem-154 173 27     SPACE eurjchem-154 173 28 n. n. PROPN eurjchem-154 173 29     SPACE eurjchem-154 173 30 j. j. PROPN eurjchem-154 173 31     SPACE eurjchem-154 173 32 heterocycl heterocycl PROPN eurjchem-154 173 33 . . PUNCT eurjchem-154 173 34     SPACE eurjchem-154 173 35 chem chem NOUN eurjchem-154 173 36 . . PUNCT eurjchem-154 173 37     SPACE eurjchem-154 174 1 2005 2005 NUM eurjchem-154 174 2 , , PUNCT eurjchem-154 174 3     SPACE eurjchem-154 174 4 42 42 NUM eurjchem-154 174 5 , , PUNCT eurjchem-154 174 6     SPACE eurjchem-154 174 7 935‐941 935‐941 NUM eurjchem-154 174 8 . . PUNCT eurjchem-154 174 9     SPACE eurjchem-154 175 1 [ [ X eurjchem-154 175 2 13 13 NUM eurjchem-154 175 3 ] ] PUNCT eurjchem-154 175 4 . . PUNCT eurjchem-154 176 1 el‐gendy el‐gendy PROPN eurjchem-154 176 2 , , PUNCT eurjchem-154 176 3     SPACE eurjchem-154 176 4 z. z. PROPN eurjchem-154 176 5 ; ; PUNCT eurjchem-154 176 6     SPACE eurjchem-154 176 7 morsy morsy NOUN eurjchem-154 176 8 , , PUNCT eurjchem-154 176 9     SPACE eurjchem-154 176 10 j. j. PROPN eurjchem-154 176 11     SPACE eurjchem-154 176 12 m. m. NOUN eurjchem-154 176 13 ; ; PUNCT eurjchem-154 176 14     SPACE eurjchem-154 176 15 allimony allimony ADJ eurjchem-154 176 16 , , PUNCT eurjchem-154 176 17     SPACE eurjchem-154 176 18 h. h. PROPN eurjchem-154 176 19     SPACE eurjchem-154 176 20 a. a. NOUN eurjchem-154 176 21 ; ; PUNCT eurjchem-154 176 22     SPACE eurjchem-154 176 23 abdel‐monem abdel‐monem PROPN eurjchem-154 176 24 , , PUNCT eurjchem-154 176 25     SPACE eurjchem-154 176 26 w. w. PROPN eurjchem-154 176 27     SPACE eurjchem-154 176 28 r. r. PROPN eurjchem-154 176 29 ; ; PUNCT eurjchem-154 176 30     SPACE eurjchem-154 176 31 abdel‐ abdel‐ PROPN eurjchem-154 176 32 rahman rahman PROPN eurjchem-154 176 33 , , PUNCT eurjchem-154 176 34     SPACE eurjchem-154 176 35 r. r. NOUN eurjchem-154 176 36     SPACE eurjchem-154 176 37 m. m. NOUN eurjchem-154 176 38     SPACE eurjchem-154 176 39 pharmazie pharmazie PROPN eurjchem-154 176 40     SPACE eurjchem-154 176 41 2001 2001 NUM eurjchem-154 176 42 , , PUNCT eurjchem-154 176 43     SPACE eurjchem-154 176 44 56 56 NUM eurjchem-154 176 45 , , PUNCT eurjchem-154 176 46     SPACE eurjchem-154 176 47 376‐384 376‐384 PROPN eurjchem-154 176 48 . . PUNCT eurjchem-154 176 49     SPACE eurjchem-154 177 1 [ [ X eurjchem-154 177 2 14 14 NUM eurjchem-154 177 3 ] ] PUNCT eurjchem-154 177 4 . . PUNCT eurjchem-154 178 1 abdel‐rahman abdel‐rahman NOUN eurjchem-154 178 2 , , PUNCT eurjchem-154 178 3     SPACE eurjchem-154 178 4 r. r. NOUN eurjchem-154 178 5     SPACE eurjchem-154 178 6 m. m. NOUN eurjchem-154 178 7 ; ; PUNCT eurjchem-154 178 8     SPACE eurjchem-154 178 9 morsy morsy NOUN eurjchem-154 178 10 , , PUNCT eurjchem-154 178 11     SPACE eurjchem-154 178 12 j. j. PROPN eurjchem-154 178 13     SPACE eurjchem-154 178 14 m. m. NOUN eurjchem-154 178 15 ; ; PUNCT eurjchem-154 178 16     SPACE eurjchem-154 178 17 hanafy hanafy NOUN eurjchem-154 178 18 , , PUNCT eurjchem-154 178 19     SPACE eurjchem-154 178 20 f. f. PROPN eurjchem-154 178 21 ; ; PUNCT eurjchem-154 178 22     SPACE eurjchem-154 178 23 amene amene NOUN eurjchem-154 178 24 , , PUNCT eurjchem-154 178 25     SPACE eurjchem-154 178 26 h. h. PROPN eurjchem-154 178 27     SPACE eurjchem-154 178 28 a. a. PROPN eurjchem-154 178 29     SPACE eurjchem-154 178 30 pharmazie pharmazie PROPN eurjchem-154 178 31     SPACE eurjchem-154 178 32 1999 1999 NUM eurjchem-154 178 33 , , PUNCT eurjchem-154 178 34     SPACE eurjchem-154 178 35 54 54 NUM eurjchem-154 178 36 , , PUNCT eurjchem-154 178 37     SPACE eurjchem-154 178 38 347‐355 347‐355 NUM eurjchem-154 178 39 . . PUNCT eurjchem-154 178 40     SPACE eurjchem-154 179 1 [ [ X eurjchem-154 179 2 15 15 NUM eurjchem-154 179 3 ] ] PUNCT eurjchem-154 179 4 . . PUNCT eurjchem-154 180 1 dai dai PROPN eurjchem-154 180 2 , , PUNCT eurjchem-154 180 3     SPACE eurjchem-154 180 4 q. q. PROPN eurjchem-154 180 5 ; ; PUNCT eurjchem-154 180 6     SPACE eurjchem-154 180 7 chen chen PROPN eurjchem-154 180 8 , , PUNCT eurjchem-154 180 9     SPACE eurjchem-154 180 10 r. r. NOUN eurjchem-154 180 11     SPACE eurjchem-154 180 12 phosphorus phosphorus NOUN eurjchem-154 180 13     SPACE eurjchem-154 180 14 sulfur sulfur NOUN eurjchem-154 180 15     SPACE eurjchem-154 180 16 silicon silicon NOUN eurjchem-154 180 17     SPACE eurjchem-154 180 18 relat relat NOUN eurjchem-154 180 19 . . PUNCT eurjchem-154 180 20     SPACE eurjchem-154 180 21 elem elem NOUN eurjchem-154 180 22 . . PUNCT eurjchem-154 180 23     SPACE eurjchem-154 180 24 1997 1997 NUM eurjchem-154 180 25 , , PUNCT eurjchem-154 180 26     SPACE eurjchem-154 180 27 122 122 NUM eurjchem-154 180 28 , , PUNCT eurjchem-154 180 29     SPACE eurjchem-154 180 30 261‐ 261‐ NUM eurjchem-154 180 31 267 267 NUM eurjchem-154 180 32 . . PUNCT eurjchem-154 180 33     SPACE eurjchem-154 181 1 [ [ X eurjchem-154 181 2 16 16 NUM eurjchem-154 181 3 ] ] PUNCT eurjchem-154 181 4 . . PUNCT eurjchem-154 182 1 he he PRON eurjchem-154 182 2 , , PUNCT eurjchem-154 182 3     SPACE eurjchem-154 182 4 l. l. PROPN eurjchem-154 182 5     SPACE eurjchem-154 182 6 n. n. PROPN eurjchem-154 182 7 ; ; PUNCT eurjchem-154 182 8     SPACE eurjchem-154 182 9 cai cai X eurjchem-154 182 10 , , PUNCT eurjchem-154 182 11     SPACE eurjchem-154 182 12 f. f. PROPN eurjchem-154 182 13 ; ; PUNCT eurjchem-154 182 14     SPACE eurjchem-154 182 15 chen chen PROPN eurjchem-154 182 16 , , PUNCT eurjchem-154 182 17     SPACE eurjchem-154 182 18 r. r. PROPN eurjchem-154 182 19     SPACE eurjchem-154 182 20 y. y. PROPN eurjchem-154 182 21 , , PUNCT eurjchem-154 182 22     SPACE eurjchem-154 182 23 zhou zhou PROPN eurjchem-154 182 24 , , PUNCT eurjchem-154 182 25     SPACE eurjchem-154 182 26 j. j. PROPN eurjchem-154 182 27     SPACE eurjchem-154 182 28 phosphorus phosphorus NOUN eurjchem-154 182 29     SPACE eurjchem-154 182 30 sulfur sulfur NOUN eurjchem-154 182 31     SPACE eurjchem-154 182 32 silicon silicon NOUN eurjchem-154 182 33     SPACE eurjchem-154 182 34 relat relat NOUN eurjchem-154 182 35 . . PUNCT eurjchem-154 182 36     SPACE eurjchem-154 182 37 elem elem NOUN eurjchem-154 182 38 . . PUNCT eurjchem-154 182 39     SPACE eurjchem-154 182 40 1997 1997 NUM eurjchem-154 182 41 , , PUNCT eurjchem-154 182 42     SPACE eurjchem-154 182 43 130 130 NUM eurjchem-154 182 44 , , PUNCT eurjchem-154 182 45     SPACE eurjchem-154 182 46 65‐71 65‐71 VERB eurjchem-154 182 47     SPACE eurjchem-154 183 1 [ [ X eurjchem-154 183 2 17 17 NUM eurjchem-154 183 3 ] ] SYM eurjchem-154 183 4 . . PUNCT eurjchem-154 183 5 tang tang PROPN eurjchem-154 183 6 , , PUNCT eurjchem-154 183 7     SPACE eurjchem-154 183 8 j. j. PROPN eurjchem-154 183 9     SPACE eurjchem-154 183 10 s. s. PROPN eurjchem-154 183 11 ; ; PUNCT eurjchem-154 183 12     SPACE eurjchem-154 184 1 verkade verkade ADJ eurjchem-154 184 2 , , PUNCT eurjchem-154 184 3     SPACE eurjchem-154 184 4 j. j. PROPN eurjchem-154 184 5     SPACE eurjchem-154 184 6 g. g. PROPN eurjchem-154 184 7 ; ; PUNCT eurjchem-154 184 8     SPACE eurjchem-154 184 9 u u NOUN eurjchem-154 184 10     SPACE eurjchem-154 184 11 s s PART eurjchem-154 184 12     SPACE eurjchem-154 184 13 patent patent NOUN eurjchem-154 184 14     SPACE eurjchem-154 184 15 no no INTJ eurjchem-154 184 16 . . PUNCT eurjchem-154 184 17     SPACE eurjchem-154 185 1 5 5 NUM eurjchem-154 185 2     SPACE eurjchem-154 185 3 260 260 NUM eurjchem-154 185 4     SPACE eurjchem-154 185 5 436 436 NUM eurjchem-154 185 6     SPACE eurjchem-154 185 7 1993 1993 NUM eurjchem-154 185 8 ; ; PUNCT eurjchem-154 185 9     SPACE eurjchem-154 185 10 chem chem NOUN eurjchem-154 185 11 . . PUNCT eurjchem-154 185 12     SPACE eurjchem-154 185 13 abstr abstr PROPN eurjchem-154 185 14 . . PUNCT eurjchem-154 185 15     SPACE eurjchem-154 185 16 1993 1993 NUM eurjchem-154 185 17 , , PUNCT eurjchem-154 185 18     SPACE eurjchem-154 185 19 120 120 NUM eurjchem-154 185 20 , , PUNCT eurjchem-154 185 21     SPACE eurjchem-154 185 22 218836v 218836v NUM eurjchem-154 185 23 . . PUNCT eurjchem-154 185 24     SPACE eurjchem-154 186 1 [ [ X eurjchem-154 186 2 18 18 NUM eurjchem-154 186 3 ] ] PUNCT eurjchem-154 186 4 . . PUNCT eurjchem-154 187 1 tiwari tiwari PROPN eurjchem-154 187 2 , , PUNCT eurjchem-154 187 3     SPACE eurjchem-154 187 4 a. a. NOUN eurjchem-154 187 5     SPACE eurjchem-154 187 6 k. k. PROPN eurjchem-154 187 7 ; ; PUNCT eurjchem-154 187 8     SPACE eurjchem-154 187 9 dubey dubey PROPN eurjchem-154 187 10 , , PUNCT eurjchem-154 187 11     SPACE eurjchem-154 187 12 b. b. PROPN eurjchem-154 187 13     SPACE eurjchem-154 187 14 k. k. PROPN eurjchem-154 187 15 ; ; PUNCT eurjchem-154 187 16     SPACE eurjchem-154 187 17 shukla shukla NOUN eurjchem-154 187 18 , , PUNCT eurjchem-154 187 19     SPACE eurjchem-154 187 20 i. i. NOUN eurjchem-154 187 21     SPACE eurjchem-154 187 22 c. c. PROPN eurjchem-154 187 23     SPACE eurjchem-154 187 24 j. j. PROPN eurjchem-154 187 25     SPACE eurjchem-154 187 26 indian indian PROPN eurjchem-154 187 27     SPACE eurjchem-154 187 28 chem chem NOUN eurjchem-154 187 29 . . PUNCT eurjchem-154 187 30     SPACE eurjchem-154 187 31 soc soc PROPN eurjchem-154 187 32 . . PUNCT eurjchem-154 187 33     SPACE eurjchem-154 187 34 2003 2003 NUM eurjchem-154 187 35 , , PUNCT eurjchem-154 187 36     SPACE eurjchem-154 187 37 80 80 NUM eurjchem-154 187 38 , , PUNCT eurjchem-154 187 39     SPACE eurjchem-154 187 40 717‐722 717‐722 NOUN eurjchem-154 187 41 . . PUNCT eurjchem-154 187 42     SPACE eurjchem-154 188 1 [ [ X eurjchem-154 188 2 19 19 NUM eurjchem-154 188 3 ] ] PUNCT eurjchem-154 188 4 . . PUNCT eurjchem-154 188 5 shukla shukla NOUN eurjchem-154 188 6 , , PUNCT eurjchem-154 188 7     SPACE eurjchem-154 188 8 i. i. NOUN eurjchem-154 188 9     SPACE eurjchem-154 188 10 c. c. PROPN eurjchem-154 188 11 ; ; PUNCT eurjchem-154 188 12     SPACE eurjchem-154 188 13 dwived dwive VERB eurjchem-154 188 14 , , PUNCT eurjchem-154 188 15     SPACE eurjchem-154 188 16 p. p. NOUN eurjchem-154 188 17     SPACE eurjchem-154 188 18 k. k. PROPN eurjchem-154 188 19     SPACE eurjchem-154 188 20 j. j. PROPN eurjchem-154 188 21     SPACE eurjchem-154 188 22 indian indian PROPN eurjchem-154 188 23     SPACE eurjchem-154 188 24 chem chem NOUN eurjchem-154 188 25 . . PUNCT eurjchem-154 188 26     SPACE eurjchem-154 188 27 soc soc PROPN eurjchem-154 188 28 . . PUNCT eurjchem-154 188 29     SPACE eurjchem-154 189 1 2005 2005 NUM eurjchem-154 189 2 , , PUNCT eurjchem-154 189 3     SPACE eurjchem-154 189 4 82 82 NUM eurjchem-154 189 5 , , PUNCT eurjchem-154 189 6     SPACE eurjchem-154 189 7 670‐675 670‐675 NUM eurjchem-154 189 8 . . PUNCT eurjchem-154 189 9     SPACE eurjchem-154 190 1 [ [ X eurjchem-154 190 2 20 20 NUM eurjchem-154 190 3 ] ] PUNCT eurjchem-154 190 4 . . PUNCT eurjchem-154 191 1 caruso caruso PROPN eurjchem-154 191 2 , , PUNCT eurjchem-154 191 3     SPACE eurjchem-154 191 4 f. f. PROPN eurjchem-154 191 5 ; ; PUNCT eurjchem-154 191 6     SPACE eurjchem-154 191 7 rossi rossi ADJ eurjchem-154 191 8 , , PUNCT eurjchem-154 191 9     SPACE eurjchem-154 191 10 m. m. NOUN eurjchem-154 191 11 ; ; PUNCT eurjchem-154 191 12     SPACE eurjchem-154 191 13 tanski tanski NOUN eurjchem-154 191 14 , , PUNCT eurjchem-154 191 15     SPACE eurjchem-154 191 16 j. j. PROPN eurjchem-154 191 17 ; ; PUNCT eurjchem-154 191 18     SPACE eurjchem-154 191 19 pettinari pettinari NOUN eurjchem-154 191 20 , , PUNCT eurjchem-154 191 21     SPACE eurjchem-154 191 22 c. c. NOUN eurjchem-154 191 23 ; ; PUNCT eurjchem-154 191 24     SPACE eurjchem-154 191 25 marchetti marchetti PROPN eurjchem-154 191 26 , , PUNCT eurjchem-154 191 27     SPACE eurjchem-154 191 28 f. f. PROPN eurjchem-154 191 29     SPACE eurjchem-154 191 30 j. j. PROPN eurjchem-154 191 31     SPACE eurjchem-154 191 32 med med PROPN eurjchem-154 191 33 . . PUNCT eurjchem-154 191 34     SPACE eurjchem-154 191 35 chem chem NOUN eurjchem-154 191 36 . . PUNCT eurjchem-154 191 37     SPACE eurjchem-154 191 38 2003 2003 NUM eurjchem-154 191 39 , , PUNCT eurjchem-154 191 40     SPACE eurjchem-154 191 41 46 46 NUM eurjchem-154 191 42 , , PUNCT eurjchem-154 191 43     SPACE eurjchem-154 191 44 1737‐1742 1737‐1742 NUM eurjchem-154 191 45 . . PUNCT eurjchem-154 191 46     SPACE eurjchem-154 192 1 [ [ X eurjchem-154 192 2 21 21 NUM eurjchem-154 192 3 ] ] PUNCT eurjchem-154 192 4 . . PUNCT eurjchem-154 193 1 ali ali PROPN eurjchem-154 193 2 , , PUNCT eurjchem-154 193 3     SPACE eurjchem-154 193 4 t. t. PROPN eurjchem-154 193 5     SPACE eurjchem-154 193 6 e. e. PROPN eurjchem-154 193 7 ; ; PUNCT eurjchem-154 193 8     SPACE eurjchem-154 193 9 abdel‐rahman abdel‐rahman NOUN eurjchem-154 193 10 , , PUNCT eurjchem-154 193 11     SPACE eurjchem-154 193 12 r. r. NOUN eurjchem-154 193 13     SPACE eurjchem-154 193 14 m. m. NOUN eurjchem-154 193 15 ; ; PUNCT eurjchem-154 193 16     SPACE eurjchem-154 193 17 makki makki NOUN eurjchem-154 193 18 , , PUNCT eurjchem-154 193 19     SPACE eurjchem-154 193 20 m. m. NOUN eurjchem-154 193 21     SPACE eurjchem-154 193 22 s. s. PROPN eurjchem-154 193 23     SPACE eurjchem-154 193 24 t. t. PROPN eurjchem-154 193 25 ; ; PUNCT eurjchem-154 193 26     SPACE eurjchem-154 193 27 ibrahim ibrahim NOUN eurjchem-154 193 28 , , PUNCT eurjchem-154 193 29     SPACE eurjchem-154 193 30 m. m. NOUN eurjchem-154 193 31     SPACE eurjchem-154 193 32 a. a. NOUN eurjchem-154 193 33     SPACE eurjchem-154 193 34 eur eur PROPN eurjchem-154 193 35 . . PUNCT eurjchem-154 193 36     SPACE eurjchem-154 193 37 j. j. PROPN eurjchem-154 193 38     SPACE eurjchem-154 193 39 chem chem NOUN eurjchem-154 193 40 . . PUNCT eurjchem-154 193 41     SPACE eurjchem-154 193 42 2010 2010 NUM eurjchem-154 193 43 , , PUNCT eurjchem-154 193 44     SPACE eurjchem-154 193 45 1(3 1(3 NUM eurjchem-154 193 46 ) ) PUNCT eurjchem-154 193 47 , , PUNCT eurjchem-154 193 48     SPACE eurjchem-154 193 49 236‐245 236‐245 NUM eurjchem-154 193 50 . . PUNCT eurjchem-154 193 51     SPACE eurjchem-154 194 1 [ [ X eurjchem-154 194 2 22 22 NUM eurjchem-154 194 3 ] ] PUNCT eurjchem-154 194 4 . . PUNCT eurjchem-154 195 1 el‐khoshnieh el‐khoshnieh PROPN eurjchem-154 195 2 , , PUNCT eurjchem-154 195 3     SPACE eurjchem-154 195 4 y. y. NOUN eurjchem-154 195 5     SPACE eurjchem-154 195 6 o. o. PROPN eurjchem-154 195 7     SPACE eurjchem-154 195 8 phosphorus phosphorus NOUN eurjchem-154 195 9     SPACE eurjchem-154 195 10 sulfur sulfur NOUN eurjchem-154 195 11     SPACE eurjchem-154 195 12 silicon silicon NOUN eurjchem-154 195 13     SPACE eurjchem-154 195 14 relat relat NOUN eurjchem-154 195 15 . . PUNCT eurjchem-154 195 16     SPACE eurjchem-154 195 17 elem elem NOUN eurjchem-154 195 18 . . PUNCT eurjchem-154 195 19     SPACE eurjchem-154 196 1 1998 1998 NUM eurjchem-154 196 2 , , PUNCT eurjchem-154 196 3     SPACE eurjchem-154 196 4 139 139 NUM eurjchem-154 196 5 , , PUNCT eurjchem-154 196 6     SPACE eurjchem-154 196 7 163‐172 163‐172 NOUN eurjchem-154 196 8 . . PUNCT eurjchem-154 196 9     SPACE eurjchem-154 197 1 [ [ X eurjchem-154 197 2 23 23 NUM eurjchem-154 197 3 ] ] PUNCT eurjchem-154 197 4 . . PUNCT eurjchem-154 198 1 abdou abdou PROPN eurjchem-154 198 2 , , PUNCT eurjchem-154 198 3     SPACE eurjchem-154 198 4 w. w. PROPN eurjchem-154 198 5     SPACE eurjchem-154 198 6 m. m. NOUN eurjchem-154 198 7 ; ; PUNCT eurjchem-154 198 8     SPACE eurjchem-154 198 9 ganoub ganoub NOUN eurjchem-154 198 10 , , PUNCT eurjchem-154 198 11     SPACE eurjchem-154 198 12 n. n. NOUN eurjchem-154 198 13     SPACE eurjchem-154 198 14 a. a. NOUN eurjchem-154 198 15 ; ; PUNCT eurjchem-154 198 16     SPACE eurjchem-154 198 17 fahmy fahmy NOUN eurjchem-154 198 18 , , PUNCT eurjchem-154 198 19     SPACE eurjchem-154 198 20 a. a. NOUN eurjchem-154 198 21     SPACE eurjchem-154 198 22 f. f. PROPN eurjchem-154 198 23 ; ; PUNCT eurjchem-154 198 24     SPACE eurjchem-154 198 25 shaddy shaddy ADJ eurjchem-154 198 26 , , PUNCT eurjchem-154 198 27     SPACE eurjchem-154 198 28 a. a. NOUN eurjchem-154 198 29     SPACE eurjchem-154 198 30 a. a. NOUN eurjchem-154 198 31     SPACE eurjchem-154 198 32 monatsch monatsch PROPN eurjchem-154 198 33 . . PUNCT eurjchem-154 198 34     SPACE eurjchem-154 198 35 fur fur NOUN eurjchem-154 198 36     SPACE eurjchem-154 198 37 chem chem NOUN eurjchem-154 198 38 . . PUNCT eurjchem-154 198 39     SPACE eurjchem-154 198 40 2006 2006 NUM eurjchem-154 198 41 , , PUNCT eurjchem-154 198 42     SPACE eurjchem-154 198 43 137 137 NUM eurjchem-154 198 44 , , PUNCT eurjchem-154 198 45     SPACE eurjchem-154 198 46 105‐116 105‐116 NUM eurjchem-154 198 47 . . PUNCT eurjchem-154 198 48     SPACE eurjchem-154 199 1 [ [ X eurjchem-154 199 2 24 24 NUM eurjchem-154 199 3 ] ] PUNCT eurjchem-154 199 4 . . PUNCT eurjchem-154 200 1 el‐khoshnieh el‐khoshnieh PROPN eurjchem-154 200 2 , , PUNCT eurjchem-154 200 3     SPACE eurjchem-154 200 4 y. y. NOUN eurjchem-154 200 5     SPACE eurjchem-154 200 6 o. o. PROPN eurjchem-154 200 7 ; ; PUNCT eurjchem-154 200 8     SPACE eurjchem-154 200 9 ibrahim ibrahim NOUN eurjchem-154 200 10 , , PUNCT eurjchem-154 200 11     SPACE eurjchem-154 200 12 y. y. NOUN eurjchem-154 200 13     SPACE eurjchem-154 200 14 a. a. NOUN eurjchem-154 200 15     SPACE eurjchem-154 200 16 phosphorus phosphorus NOUN eurjchem-154 200 17     SPACE eurjchem-154 200 18 sulfur sulfur NOUN eurjchem-154 200 19     SPACE eurjchem-154 200 20 silicon silicon NOUN eurjchem-154 200 21     SPACE eurjchem-154 200 22 relat relat NOUN eurjchem-154 200 23 . . PUNCT eurjchem-154 200 24     SPACE eurjchem-154 200 25 elem elem NOUN eurjchem-154 200 26 . . PUNCT eurjchem-154 200 27     SPACE eurjchem-154 200 28 1995 1995 NUM eurjchem-154 200 29 , , PUNCT eurjchem-154 200 30     SPACE eurjchem-154 200 31 101 101 NUM eurjchem-154 200 32 , , PUNCT eurjchem-154 200 33     SPACE eurjchem-154 200 34 67‐73 67‐73 NOUN eurjchem-154 200 35 . . PUNCT eurjchem-154 200 36       SPACE eurjchem-154 201 1 [ [ X eurjchem-154 201 2 25 25 NUM eurjchem-154 201 3 ] ] PUNCT eurjchem-154 201 4 . . PUNCT eurjchem-154 201 5 ali ali PROPN eurjchem-154 201 6 , , PUNCT eurjchem-154 201 7     SPACE eurjchem-154 201 8 t. t. PROPN eurjchem-154 201 9     SPACE eurjchem-154 201 10 e. e. PROPN eurjchem-154 201 11 ; ; PUNCT eurjchem-154 201 12     SPACE eurjchem-154 201 13 abdel‐rahman abdel‐rahman NOUN eurjchem-154 201 14 , , PUNCT eurjchem-154 201 15     SPACE eurjchem-154 201 16 r. r. PROPN eurjchem-154 201 17     SPACE eurjchem-154 201 18 m. m. NOUN eurjchem-154 201 19 ; ; PUNCT eurjchem-154 201 20     SPACE eurjchem-154 201 21 hanafy hanafy NOUN eurjchem-154 201 22 , , PUNCT eurjchem-154 201 23     SPACE eurjchem-154 201 24 f. f. PROPN eurjchem-154 201 25     SPACE eurjchem-154 201 26 i. i. PROPN eurjchem-154 201 27 ; ; PUNCT eurjchem-154 201 28     SPACE eurjchem-154 201 29 el‐edfawy el‐edfawy NOUN eurjchem-154 201 30 , , PUNCT eurjchem-154 201 31     SPACE eurjchem-154 201 32 s. s. PROPN eurjchem-154 201 33     SPACE eurjchem-154 201 34 m. m. NOUN eurjchem-154 201 35     SPACE eurjchem-154 201 36 phosphorus phosphorus NOUN eurjchem-154 201 37 , , PUNCT eurjchem-154 201 38     SPACE eurjchem-154 201 39 sulfur sulfur NOUN eurjchem-154 201 40     SPACE eurjchem-154 201 41 silicon silicon NOUN eurjchem-154 201 42     SPACE eurjchem-154 201 43 relat relat NOUN eurjchem-154 201 44 . . PUNCT eurjchem-154 201 45     SPACE eurjchem-154 201 46 elem elem NOUN eurjchem-154 201 47 . . PUNCT eurjchem-154 201 48     SPACE eurjchem-154 202 1 2008 2008 NUM eurjchem-154 202 2 , , PUNCT eurjchem-154 202 3     SPACE eurjchem-154 202 4 183 183 NUM eurjchem-154 202 5 , , PUNCT eurjchem-154 202 6     SPACE eurjchem-154 202 7 2565‐2577 2565‐2577 NUM eurjchem-154 202 8 . . PUNCT eurjchem-154 202 9       SPACE eurjchem-154 203 1 [ [ X eurjchem-154 203 2 26 26 NUM eurjchem-154 203 3 ] ] PUNCT eurjchem-154 203 4 . . PUNCT eurjchem-154 203 5 abdel‐rahman abdel‐rahman NOUN eurjchem-154 203 6 , , PUNCT eurjchem-154 203 7     SPACE eurjchem-154 203 8 r. r. NOUN eurjchem-154 203 9     SPACE eurjchem-154 203 10 m. m. NOUN eurjchem-154 203 11     SPACE eurjchem-154 203 12 trends trend NOUN eurjchem-154 203 13     SPACE eurjchem-154 203 14 in in ADP eurjchem-154 203 15     SPACE eurjchem-154 203 16 heterocycl heterocycl NOUN eurjchem-154 203 17 . . PUNCT eurjchem-154 203 18     SPACE eurjchem-154 203 19 chem chem NOUN eurjchem-154 203 20 . . PUNCT eurjchem-154 203 21     SPACE eurjchem-154 203 22 2002 2002 NUM eurjchem-154 203 23 , , PUNCT eurjchem-154 203 24     SPACE eurjchem-154 203 25 8 8 NUM eurjchem-154 203 26 , , PUNCT eurjchem-154 203 27     SPACE eurjchem-154 203 28 187‐194 187‐194 NUM eurjchem-154 203 29 . . PUNCT eurjchem-154 203 30     SPACE eurjchem-154 204 1 [ [ X eurjchem-154 204 2 27 27 NUM eurjchem-154 204 3 ] ] PUNCT eurjchem-154 204 4 . . PUNCT eurjchem-154 205 1 ibrahim ibrahim PROPN eurjchem-154 205 2 , , PUNCT eurjchem-154 205 3     SPACE eurjchem-154 205 4 y. y. NOUN eurjchem-154 205 5     SPACE eurjchem-154 205 6 a. a. NOUN eurjchem-154 205 7 ; ; PUNCT eurjchem-154 205 8     SPACE eurjchem-154 205 9 kadry kadry NOUN eurjchem-154 205 10 , , PUNCT eurjchem-154 205 11     SPACE eurjchem-154 205 12 a. a. NOUN eurjchem-154 205 13     SPACE eurjchem-154 205 14 m. m. NOUN eurjchem-154 205 15 ; ; PUNCT eurjchem-154 205 16     SPACE eurjchem-154 205 17 ibrahim ibrahim NOUN eurjchem-154 205 18 , , PUNCT eurjchem-154 205 19     SPACE eurjchem-154 205 20 m. m. NOUN eurjchem-154 205 21     SPACE eurjchem-154 205 22 r. r. PROPN eurjchem-154 205 23 ; ; PUNCT eurjchem-154 205 24     SPACE eurjchem-154 205 25 lisgarten lisgarten VERB eurjchem-154 205 26 , , PUNCT eurjchem-154 205 27     SPACE eurjchem-154 205 28 j. j. PROPN eurjchem-154 205 29     SPACE eurjchem-154 205 30 n. n. PROPN eurjchem-154 205 31 ; ; PUNCT eurjchem-154 205 32     SPACE eurjchem-154 205 33 potfer potfer NOUN eurjchem-154 205 34 , , PUNCT eurjchem-154 205 35     SPACE eurjchem-154 205 36 b. b. PROPN eurjchem-154 205 37     SPACE eurjchem-154 206 1 s. s. PROPN eurjchem-154 206 2 ; ; PUNCT eurjchem-154 206 3     SPACE eurjchem-154 206 4 palmer palmer NOUN eurjchem-154 206 5 , , PUNCT eurjchem-154 206 6     SPACE eurjchem-154 206 7 r. r. PROPN eurjchem-154 206 8     SPACE eurjchem-154 206 9 a. a. NOUN eurjchem-154 206 10     SPACE eurjchem-154 206 11 tetrahedron tetrahedron NOUN eurjchem-154 206 12     SPACE eurjchem-154 206 13 1999 1999 NUM eurjchem-154 206 14 , , PUNCT eurjchem-154 206 15     SPACE eurjchem-154 206 16 55 55 NUM eurjchem-154 206 17 , , PUNCT eurjchem-154 206 18     SPACE eurjchem-154 206 19 13457‐13462 13457‐13462 NOUN eurjchem-154 206 20 . . PUNCT eurjchem-154 206 21     SPACE eurjchem-154 207 1 [ [ X eurjchem-154 207 2 28 28 NUM eurjchem-154 207 3 ] ] PUNCT eurjchem-154 207 4 . . PUNCT eurjchem-154 208 1 ali ali PROPN eurjchem-154 208 2 , , PUNCT eurjchem-154 208 3     SPACE eurjchem-154 208 4 t. t. PROPN eurjchem-154 208 5     SPACE eurjchem-154 208 6 e. e. PROPN eurjchem-154 208 7     SPACE eurjchem-154 208 8 eur eur PROPN eurjchem-154 208 9 . . PUNCT eurjchem-154 208 10     SPACE eurjchem-154 208 11 j. j. PROPN eurjchem-154 208 12     SPACE eurjchem-154 208 13 med med PROPN eurjchem-154 208 14 . . PUNCT eurjchem-154 208 15     SPACE eurjchem-154 208 16 chem chem NOUN eurjchem-154 208 17 . . PUNCT eurjchem-154 208 18     SPACE eurjchem-154 208 19 2009 2009 NUM eurjchem-154 208 20 , , PUNCT eurjchem-154 208 21     SPACE eurjchem-154 208 22 44 44 NUM eurjchem-154 208 23 , , PUNCT eurjchem-154 208 24     SPACE eurjchem-154 208 25 4539‐4546 4539‐4546 NUM eurjchem-154 208 26 . . PUNCT eurjchem-154 208 27     SPACE eurjchem-154 209 1 [ [ X eurjchem-154 209 2 29 29 NUM eurjchem-154 209 3 ] ] PUNCT eurjchem-154 209 4 . . PUNCT eurjchem-154 210 1 tandura tandura PROPN eurjchem-154 210 2 , , PUNCT eurjchem-154 210 3     SPACE eurjchem-154 210 4 s. s. PROPN eurjchem-154 210 5     SPACE eurjchem-154 210 6 n. n. PROPN eurjchem-154 210 7 ; ; PUNCT eurjchem-154 210 8     SPACE eurjchem-154 210 9 voronkov voronkov NOUN eurjchem-154 210 10 , , PUNCT eurjchem-154 210 11     SPACE eurjchem-154 210 12 m. m. NOUN eurjchem-154 210 13     SPACE eurjchem-154 210 14 g. g. PROPN eurjchem-154 210 15 ; ; PUNCT eurjchem-154 210 16     SPACE eurjchem-154 210 17 alekseer alekseer ADJ eurjchem-154 210 18 , , PUNCT eurjchem-154 210 19     SPACE eurjchem-154 210 20 n. n. NOUN eurjchem-154 210 21     SPACE eurjchem-154 210 22 v. v. PROPN eurjchem-154 210 23     SPACE eurjchem-154 210 24 top top NOUN eurjchem-154 210 25 . . PUNCT eurjchem-154 210 26     SPACE eurjchem-154 211 1 curr curr PROPN eurjchem-154 211 2 . . PUNCT eurjchem-154 211 3     SPACE eurjchem-154 211 4 chem chem NOUN eurjchem-154 211 5 . . PUNCT eurjchem-154 211 6     SPACE eurjchem-154 211 7 1986 1986 NUM eurjchem-154 211 8 , , PUNCT eurjchem-154 211 9     SPACE eurjchem-154 211 10 131 131 NUM eurjchem-154 211 11 , , PUNCT eurjchem-154 211 12     SPACE eurjchem-154 211 13 99‐189 99‐189 NOUN eurjchem-154 211 14 . . PUNCT eurjchem-154 211 15     SPACE