id	sid	tid	token	lemma	pos
eurjchem-1549	1	1	untitled	untitle	VERB
eurjchem-1549	1	2	european	european	PROPN
eurjchem-1549	1	3	journal	journal	PROPN
eurjchem-1549	1	4	of	of	ADP
eurjchem-1549	1	5	chemistry	chemistry	NOUN
eurjchem-1549	1	6	8	8	NUM
eurjchem-1549	1	7	(	(	PUNCT
eurjchem-1549	1	8	2	2	NUM
eurjchem-1549	1	9	)	)	PUNCT
eurjchem-1549	1	10	(	(	PUNCT
eurjchem-1549	1	11	2017	2017	NUM
eurjchem-1549	1	12	)	)	PUNCT
eurjchem-1549	1	13	119‐124	119‐124	PROPN
eurjchem-1549	1	14	european	european	PROPN
eurjchem-1549	1	15	journal	journal	PROPN
eurjchem-1549	1	16	of	of	ADP
eurjchem-1549	1	17	chemistry	chemistry	NOUN
eurjchem-1549	1	18	issn	issn	PROPN
eurjchem-1549	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-1549	1	20	(	(	PUNCT
eurjchem-1549	1	21	print	print	NOUN
eurjchem-1549	1	22	)	)	PUNCT
eurjchem-1549	1	23	/	/	SYM
eurjchem-1549	1	24	issn	issn	PROPN
eurjchem-1549	1	25	2153‐2257	2153‐2257	NUM
eurjchem-1549	1	26	(	(	PUNCT
eurjchem-1549	1	27	online	online	ADJ
eurjchem-1549	1	28	)	)	PUNCT
eurjchem-1549	1	29			NOUN
eurjchem-1549	1	30	2017	2017	NUM
eurjchem-1549	1	31	atlanta	atlanta	PROPN
eurjchem-1549	1	32	publishing	publishing	PROPN
eurjchem-1549	1	33	house	house	PROPN
eurjchem-1549	1	34	llc	llc	PROPN
eurjchem-1549	1	35	‐	‐	PUNCT
eurjchem-1549	1	36	all	all	DET
eurjchem-1549	1	37	rights	right	NOUN
eurjchem-1549	1	38	reserved	reserve	VERB
eurjchem-1549	1	39	‐	‐	NOUN
eurjchem-1549	1	40	printed	print	VERB
eurjchem-1549	1	41	in	in	ADP
eurjchem-1549	1	42	the	the	DET
eurjchem-1549	1	43	usa	usa	PROPN
eurjchem-1549	1	44	http://dx.doi.org/10.5155/eurjchem.8.2.119-124.1549	http://dx.doi.org/10.5155/eurjchem.8.2.119-124.1549	PROPN
eurjchem-1549	1	45	european	european	PROPN
eurjchem-1549	1	46	journal	journal	PROPN
eurjchem-1549	1	47	of	of	ADP
eurjchem-1549	1	48	chemistry	chemistry	PROPN
eurjchem-1549	1	49	journal	journal	PROPN
eurjchem-1549	1	50	webpage	webpage	NOUN
eurjchem-1549	1	51	:	:	PUNCT
eurjchem-1549	1	52	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1549	1	53	new	new	ADJ
eurjchem-1549	1	54	norfloxacin	norfloxacin	PROPN
eurjchem-1549	1	55	/	/	SYM
eurjchem-1549	1	56	nitric	nitric	ADJ
eurjchem-1549	1	57	oxide	oxide	NOUN
eurjchem-1549	1	58	donor	donor	NOUN
eurjchem-1549	1	59	hybrids	hybrid	NOUN
eurjchem-1549	1	60	:	:	PUNCT
eurjchem-1549	1	61	synthesis	synthesis	NOUN
eurjchem-1549	1	62	and	and	CCONJ
eurjchem-1549	1	63	nitric	nitric	ADJ
eurjchem-1549	1	64	oxide	oxide	NOUN
eurjchem-1549	1	65	release	release	NOUN
eurjchem-1549	1	66	measurement	measurement	NOUN
eurjchem-1549	1	67	using	use	VERB
eurjchem-1549	1	68	a	a	DET
eurjchem-1549	1	69	modified	modify	VERB
eurjchem-1549	1	70	griess	griess	NOUN
eurjchem-1549	1	71	colorimetric	colorimetric	ADJ
eurjchem-1549	1	72	method	method	NOUN
eurjchem-1549	1	73	hossameldin	hossameldin	VERB
eurjchem-1549	1	74	ali	ali	PROPN
eurjchem-1549	1	75	aziz	aziz	PROPN
eurjchem-1549	1	76	1	1	PROPN
eurjchem-1549	1	77	,	,	PUNCT
eurjchem-1549	1	78	gamal	gamal	PROPN
eurjchem-1549	1	79	abdeltawab	abdeltawab	PROPN
eurjchem-1549	1	80	idris	idris	PROPN
eurjchem-1549	1	81	moustafa	moustafa	PROPN
eurjchem-1549	1	82	1	1	NUM
eurjchem-1549	1	83	,	,	PUNCT
eurjchem-1549	1	84	*	*	PUNCT
eurjchem-1549	1	85	,	,	PUNCT
eurjchem-1549	1	86	samar	samar	PROPN
eurjchem-1549	1	87	hafez	hafez	PROPN
eurjchem-1549	1	88	abbas	abbas	PROPN
eurjchem-1549	1	89	1	1	NUM
eurjchem-1549	1	90	,	,	PUNCT
eurjchem-1549	1	91	sayed	say	VERB
eurjchem-1549	1	92	mohamed	mohamed	PROPN
eurjchem-1549	1	93	derayea	derayea	VERB
eurjchem-1549	1	94	2	2	NUM
eurjchem-1549	1	95	and	and	CCONJ
eurjchem-1549	1	96	gamal	gamal	PROPN
eurjchem-1549	1	97	el‐din	el‐din	PROPN
eurjchem-1549	1	98	ali	ali	PROPN
eurjchem-1549	1	99	ahmed	ahmed	PROPN
eurjchem-1549	1	100	abuo‐rahma	abuo‐rahma	PROPN
eurjchem-1549	1	101	1	1	NUM
eurjchem-1549	1	102	1	1	NUM
eurjchem-1549	1	103	department	department	NOUN
eurjchem-1549	1	104	of	of	ADP
eurjchem-1549	1	105	medicinal	medicinal	ADJ
eurjchem-1549	1	106	chemistry	chemistry	NOUN
eurjchem-1549	1	107	,	,	PUNCT
eurjchem-1549	1	108	faculty	faculty	NOUN
eurjchem-1549	1	109	of	of	ADP
eurjchem-1549	1	110	pharmacy	pharmacy	NOUN
eurjchem-1549	1	111	,	,	PUNCT
eurjchem-1549	1	112	minia	minia	NOUN
eurjchem-1549	1	113	university	university	NOUN
eurjchem-1549	1	114	,	,	PUNCT
eurjchem-1549	1	115	minia	minia	NOUN
eurjchem-1549	1	116	61519	61519	NUM
eurjchem-1549	1	117	,	,	PUNCT
eurjchem-1549	1	118	egypt	egypt	PROPN
eurjchem-1549	1	119	2	2	NUM
eurjchem-1549	1	120	department	department	NOUN
eurjchem-1549	1	121	of	of	ADP
eurjchem-1549	1	122	analytical	analytical	ADJ
eurjchem-1549	1	123	chemistry	chemistry	NOUN
eurjchem-1549	1	124	,	,	PUNCT
eurjchem-1549	1	125	faculty	faculty	NOUN
eurjchem-1549	1	126	of	of	ADP
eurjchem-1549	1	127	pharmacy	pharmacy	NOUN
eurjchem-1549	1	128	,	,	PUNCT
eurjchem-1549	1	129	minia	minia	NOUN
eurjchem-1549	1	130	university	university	NOUN
eurjchem-1549	1	131	,	,	PUNCT
eurjchem-1549	1	132	minia	minia	NOUN
eurjchem-1549	1	133	61519	61519	NUM
eurjchem-1549	1	134	,	,	PUNCT
eurjchem-1549	1	135	egypt	egypt	PROPN
eurjchem-1549	1	136	*	*	PUNCT
eurjchem-1549	1	137	corresponding	correspond	VERB
eurjchem-1549	1	138	author	author	NOUN
eurjchem-1549	1	139	at	at	ADP
eurjchem-1549	1	140	:	:	PUNCT
eurjchem-1549	1	141	department	department	NOUN
eurjchem-1549	1	142	of	of	ADP
eurjchem-1549	1	143	medicinal	medicinal	ADJ
eurjchem-1549	1	144	chemistry	chemistry	NOUN
eurjchem-1549	1	145	,	,	PUNCT
eurjchem-1549	1	146	faculty	faculty	NOUN
eurjchem-1549	1	147	of	of	ADP
eurjchem-1549	1	148	pharmacy	pharmacy	NOUN
eurjchem-1549	1	149	,	,	PUNCT
eurjchem-1549	1	150	minia	minia	NOUN
eurjchem-1549	1	151	university	university	NOUN
eurjchem-1549	1	152	,	,	PUNCT
eurjchem-1549	1	153	minia	minia	NOUN
eurjchem-1549	1	154	61519	61519	NUM
eurjchem-1549	1	155	,	,	PUNCT
eurjchem-1549	1	156	egypt	egypt	PROPN
eurjchem-1549	1	157	.	.	PUNCT
eurjchem-1549	2	1	tel	tel	PROPN
eurjchem-1549	2	2	.	.	PUNCT
eurjchem-1549	2	3	:	:	PUNCT
eurjchem-1549	3	1	+2.086.2369075	+2.086.2369075	X
eurjchem-1549	3	2	.	.	PUNCT
eurjchem-1549	4	1	fax	fax	NOUN
eurjchem-1549	4	2	:	:	PUNCT
eurjchem-1549	4	3	+2.086.2369075	+2.086.2369075	PROPN
eurjchem-1549	4	4	.	.	PUNCT
eurjchem-1549	4	5	e‐mail	e‐mail	PUNCT
eurjchem-1549	5	1	address	address	NOUN
eurjchem-1549	5	2	:	:	PUNCT
eurjchem-1549	5	3	gamal.moustafa@mu.edu.eg	gamal.moustafa@mu.edu.eg	X
eurjchem-1549	5	4	(	(	PUNCT
eurjchem-1549	5	5	g.a.i	g.a.i	PROPN
eurjchem-1549	5	6	.	.	PUNCT
eurjchem-1549	5	7	moustafa	moustafa	PROPN
eurjchem-1549	5	8	)	)	PUNCT
eurjchem-1549	5	9	.	.	PUNCT
eurjchem-1549	6	1	article	article	NOUN
eurjchem-1549	6	2	information	information	PROPN
eurjchem-1549	6	3	abstract	abstract	ADJ
eurjchem-1549	6	4	doi	doi	PROPN
eurjchem-1549	6	5	:	:	PUNCT
eurjchem-1549	6	6	 	 	SPACE
eurjchem-1549	6	7	10.5155	10.5155	NUM
eurjchem-1549	6	8	/	/	SYM
eurjchem-1549	6	9	eurjchem.8.2.119	eurjchem.8.2.119	PROPN
eurjchem-1549	6	10	-	-	PUNCT
eurjchem-1549	6	11	124.1549	124.1549	NUM
eurjchem-1549	6	12	received	receive	VERB
eurjchem-1549	6	13	:	:	PUNCT
eurjchem-1549	6	14	26	26	NUM
eurjchem-1549	6	15	january	january	PROPN
eurjchem-1549	6	16	2017	2017	NUM
eurjchem-1549	6	17	received	receive	VERB
eurjchem-1549	6	18	in	in	ADP
eurjchem-1549	6	19	revised	revise	VERB
eurjchem-1549	6	20	form	form	NOUN
eurjchem-1549	6	21	:	:	PUNCT
eurjchem-1549	6	22	12	12	NUM
eurjchem-1549	6	23	march	march	NOUN
eurjchem-1549	6	24	2017	2017	NUM
eurjchem-1549	6	25	accepted	accept	VERB
eurjchem-1549	6	26	:	:	PUNCT
eurjchem-1549	6	27	13	13	NUM
eurjchem-1549	6	28	march	march	NOUN
eurjchem-1549	6	29	2017	2017	NUM
eurjchem-1549	6	30	published	publish	VERB
eurjchem-1549	6	31	online	online	ADV
eurjchem-1549	6	32	:	:	PUNCT
eurjchem-1549	6	33	30	30	NUM
eurjchem-1549	6	34	june	june	PROPN
eurjchem-1549	6	35	2017	2017	NUM
eurjchem-1549	6	36	printed	print	VERB
eurjchem-1549	6	37	:	:	PUNCT
eurjchem-1549	6	38	30	30	NUM
eurjchem-1549	6	39	june	june	PROPN
eurjchem-1549	6	40	2017	2017	NUM
eurjchem-1549	6	41	  	  	SPACE
eurjchem-1549	6	42	oximes	oxime	NOUN
eurjchem-1549	6	43	and	and	CCONJ
eurjchem-1549	6	44	nitrate	nitrate	NOUN
eurjchem-1549	6	45	esters	ester	NOUN
eurjchem-1549	6	46	are	be	AUX
eurjchem-1549	6	47	considered	consider	VERB
eurjchem-1549	6	48	as	as	ADP
eurjchem-1549	6	49	important	important	ADJ
eurjchem-1549	6	50	nitric	nitric	ADJ
eurjchem-1549	6	51	oxide	oxide	NOUN
eurjchem-1549	6	52	(	(	PUNCT
eurjchem-1549	6	53	no	no	NOUN
eurjchem-1549	6	54	)	)	PUNCT
eurjchem-1549	6	55	donors	donor	NOUN
eurjchem-1549	6	56	with	with	ADP
eurjchem-1549	6	57	diverse	diverse	ADJ
eurjchem-1549	6	58	biological	biological	ADJ
eurjchem-1549	6	59	activities	activity	NOUN
eurjchem-1549	6	60	.	.	PUNCT
eurjchem-1549	7	1	herein	herein	NOUN
eurjchem-1549	7	2	,	,	PUNCT
eurjchem-1549	7	3	we	we	PRON
eurjchem-1549	7	4	report	report	VERB
eurjchem-1549	7	5	the	the	DET
eurjchem-1549	7	6	synthesis	synthesis	NOUN
eurjchem-1549	7	7	and	and	CCONJ
eurjchem-1549	7	8	characterization	characterization	NOUN
eurjchem-1549	7	9	of	of	ADP
eurjchem-1549	7	10	new	new	ADJ
eurjchem-1549	7	11	oxime	oxime	NOUN
eurjchem-1549	7	12	and	and	CCONJ
eurjchem-1549	7	13	nitrate	nitrate	NOUN
eurjchem-1549	7	14	ester	ester	NOUN
eurjchem-1549	7	15	derivatives	derivative	NOUN
eurjchem-1549	7	16	of	of	ADP
eurjchem-1549	7	17	norfloxacin	norfloxacin	PRON
eurjchem-1549	7	18	as	as	ADP
eurjchem-1549	7	19	potential	potential	ADJ
eurjchem-1549	7	20	no	no	DET
eurjchem-1549	7	21	donor	donor	NOUN
eurjchem-1549	7	22	hybrids	hybrid	NOUN
eurjchem-1549	7	23	with	with	ADP
eurjchem-1549	7	24	expected	expect	VERB
eurjchem-1549	7	25	synergistic	synergistic	ADJ
eurjchem-1549	7	26	antimicrobial	antimicrobial	ADJ
eurjchem-1549	7	27	activity	activity	NOUN
eurjchem-1549	7	28	.	.	PUNCT
eurjchem-1549	8	1	the	the	DET
eurjchem-1549	8	2	release	release	NOUN
eurjchem-1549	8	3	of	of	ADP
eurjchem-1549	8	4	no	no	PRON
eurjchem-1549	8	5	from	from	ADP
eurjchem-1549	8	6	those	those	DET
eurjchem-1549	8	7	hybrids	hybrid	NOUN
eurjchem-1549	8	8	was	be	AUX
eurjchem-1549	8	9	measured	measure	VERB
eurjchem-1549	8	10	by	by	ADP
eurjchem-1549	8	11	a	a	DET
eurjchem-1549	8	12	modified	modify	VERB
eurjchem-1549	8	13	griess	griess	NOUN
eurjchem-1549	8	14	method	method	NOUN
eurjchem-1549	8	15	in	in	ADP
eurjchem-1549	8	16	which	which	PRON
eurjchem-1549	8	17	p‐nitroaniline	p‐nitroaniline	PRON
eurjchem-1549	8	18	was	be	AUX
eurjchem-1549	8	19	employed	employ	VERB
eurjchem-1549	8	20	instead	instead	ADV
eurjchem-1549	8	21	of	of	ADP
eurjchem-1549	8	22	sulfanilamide	sulfanilamide	NOUN
eurjchem-1549	8	23	.	.	PUNCT
eurjchem-1549	9	1	the	the	DET
eurjchem-1549	9	2	increased	increase	VERB
eurjchem-1549	9	3	electrophilicity	electrophilicity	NOUN
eurjchem-1549	9	4	of	of	ADP
eurjchem-1549	9	5	the	the	DET
eurjchem-1549	9	6	intermediate	intermediate	ADJ
eurjchem-1549	9	7	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	9	8	diazonium	diazonium	NOUN
eurjchem-1549	9	9	salt	salt	NOUN
eurjchem-1549	9	10	accelerated	accelerate	VERB
eurjchem-1549	9	11	the	the	DET
eurjchem-1549	9	12	coupling	coupling	NOUN
eurjchem-1549	9	13	process	process	NOUN
eurjchem-1549	9	14	and	and	CCONJ
eurjchem-1549	9	15	shortened	shorten	VERB
eurjchem-1549	9	16	the	the	DET
eurjchem-1549	9	17	overall	overall	ADJ
eurjchem-1549	9	18	assessment	assessment	NOUN
eurjchem-1549	9	19	time	time	NOUN
eurjchem-1549	9	20	.	.	PUNCT
eurjchem-1549	10	1	the	the	DET
eurjchem-1549	10	2	improved	improve	VERB
eurjchem-1549	10	3	detection	detection	NOUN
eurjchem-1549	10	4	limits	limit	NOUN
eurjchem-1549	10	5	and	and	CCONJ
eurjchem-1549	10	6	enhanced	enhance	VERB
eurjchem-1549	10	7	sensitivity	sensitivity	NOUN
eurjchem-1549	10	8	would	would	AUX
eurjchem-1549	10	9	pave	pave	VERB
eurjchem-1549	10	10	the	the	DET
eurjchem-1549	10	11	way	way	NOUN
eurjchem-1549	10	12	for	for	ADP
eurjchem-1549	10	13	the	the	DET
eurjchem-1549	10	14	future	future	ADJ
eurjchem-1549	10	15	application	application	NOUN
eurjchem-1549	10	16	of	of	ADP
eurjchem-1549	10	17	this	this	DET
eurjchem-1549	10	18	method	method	NOUN
eurjchem-1549	10	19	in	in	ADP
eurjchem-1549	10	20	nitrite	nitrite	NOUN
eurjchem-1549	10	21	determination	determination	NOUN
eurjchem-1549	10	22	in	in	ADP
eurjchem-1549	10	23	biological	biological	ADJ
eurjchem-1549	10	24	or	or	CCONJ
eurjchem-1549	10	25	non‐biological	non‐biological	ADJ
eurjchem-1549	10	26	systems	system	NOUN
eurjchem-1549	10	27	.	.	PUNCT
eurjchem-1549	11	1	keywords	keyword	VERB
eurjchem-1549	11	2	nitrite	nitrite	NOUN
eurjchem-1549	11	3	norfloxacin	norfloxacin	PROPN
eurjchem-1549	11	4	diazotization	diazotization	NOUN
eurjchem-1549	11	5	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	11	6	nitric	nitric	ADJ
eurjchem-1549	11	7	oxide	oxide	NOUN
eurjchem-1549	11	8	donors	donor	NOUN
eurjchem-1549	11	9	griess	griess	VERB
eurjchem-1549	11	10	colorimetric	colorimetric	ADJ
eurjchem-1549	11	11	assay	assay	NOUN
eurjchem-1549	11	12	cite	cite	VERB
eurjchem-1549	11	13	this	this	PRON
eurjchem-1549	11	14	:	:	PUNCT
eurjchem-1549	11	15	eur	eur	PROPN
eurjchem-1549	11	16	.	.	PUNCT
eurjchem-1549	12	1	j.	j.	PROPN
eurjchem-1549	12	2	chem	chem	PROPN
eurjchem-1549	12	3	.	.	PUNCT
eurjchem-1549	13	1	2017	2017	NUM
eurjchem-1549	13	2	,	,	PUNCT
eurjchem-1549	13	3	8(2	8(2	NUM
eurjchem-1549	13	4	)	)	PUNCT
eurjchem-1549	13	5	,	,	PUNCT
eurjchem-1549	13	6	119‐124	119‐124	PROPN
eurjchem-1549	13	7	1	1	X
eurjchem-1549	13	8	.	.	PUNCT
eurjchem-1549	14	1	introduction	introduction	NOUN
eurjchem-1549	14	2	nitric	nitric	ADJ
eurjchem-1549	14	3	oxide	oxide	NOUN
eurjchem-1549	14	4	is	be	AUX
eurjchem-1549	14	5	a	a	DET
eurjchem-1549	14	6	key	key	ADJ
eurjchem-1549	14	7	signalling	signal	VERB
eurjchem-1549	14	8	molecule	molecule	NOUN
eurjchem-1549	14	9	regulating	regulate	VERB
eurjchem-1549	14	10	various	various	ADJ
eurjchem-1549	14	11	physiological	physiological	ADJ
eurjchem-1549	14	12	functions	function	NOUN
eurjchem-1549	14	13	such	such	ADJ
eurjchem-1549	14	14	as	as	ADP
eurjchem-1549	14	15	platelet	platelet	NOUN
eurjchem-1549	14	16	aggregation	aggregation	NOUN
eurjchem-1549	14	17	[	[	X
eurjchem-1549	14	18	1	1	NUM
eurjchem-1549	14	19	]	]	PUNCT
eurjchem-1549	14	20	,	,	PUNCT
eurjchem-1549	14	21	vascular	vascular	ADJ
eurjchem-1549	14	22	tone	tone	NOUN
eurjchem-1549	14	23	[	[	X
eurjchem-1549	14	24	2,3	2,3	NUM
eurjchem-1549	14	25	]	]	NUM
eurjchem-1549	14	26	,	,	PUNCT
eurjchem-1549	14	27	immune	immune	ADJ
eurjchem-1549	14	28	response	response	NOUN
eurjchem-1549	14	29	and	and	CCONJ
eurjchem-1549	14	30	neurotransmission	neurotransmission	NOUN
eurjchem-1549	14	31	[	[	X
eurjchem-1549	14	32	4‐8	4‐8	NOUN
eurjchem-1549	14	33	]	]	PUNCT
eurjchem-1549	14	34	.	.	PUNCT
eurjchem-1549	15	1	likewise	likewise	ADV
eurjchem-1549	15	2	,	,	PUNCT
eurjchem-1549	15	3	numerous	numerous	ADJ
eurjchem-1549	15	4	reports	report	NOUN
eurjchem-1549	15	5	demonstrated	demonstrate	VERB
eurjchem-1549	15	6	the	the	DET
eurjchem-1549	15	7	signifi‐	signifi‐	PROPN
eurjchem-1549	15	8	cance	cance	NOUN
eurjchem-1549	15	9	of	of	ADP
eurjchem-1549	15	10	no	no	PRON
eurjchem-1549	15	11	in	in	ADP
eurjchem-1549	15	12	mediating	mediate	VERB
eurjchem-1549	15	13	the	the	DET
eurjchem-1549	15	14	antiproliferative	antiproliferative	NOUN
eurjchem-1549	15	15	,	,	PUNCT
eurjchem-1549	15	16	antibacterial	antibacterial	ADJ
eurjchem-1549	15	17	,	,	PUNCT
eurjchem-1549	15	18	antiviral	antiviral	ADJ
eurjchem-1549	15	19	and	and	CCONJ
eurjchem-1549	15	20	antiprotozoal	antiprotozoal	ADJ
eurjchem-1549	15	21	properties	property	NOUN
eurjchem-1549	15	22	of	of	ADP
eurjchem-1549	15	23	activated	activate	VERB
eurjchem-1549	15	24	macro‐	macro‐	NOUN
eurjchem-1549	15	25	phages	phage	NOUN
eurjchem-1549	15	26	[	[	X
eurjchem-1549	15	27	9,10	9,10	NUM
eurjchem-1549	15	28	]	]	PUNCT
eurjchem-1549	15	29	.	.	PUNCT
eurjchem-1549	16	1	given	give	VERB
eurjchem-1549	16	2	the	the	DET
eurjchem-1549	16	3	aforementioned	aforementioned	ADJ
eurjchem-1549	16	4	diverse	diverse	ADJ
eurjchem-1549	16	5	and	and	CCONJ
eurjchem-1549	16	6	important	important	ADJ
eurjchem-1549	16	7	physio‐	physio‐	NOUN
eurjchem-1549	16	8	logical	logical	ADJ
eurjchem-1549	16	9	roles	role	NOUN
eurjchem-1549	16	10	of	of	ADP
eurjchem-1549	16	11	no	no	PRON
eurjchem-1549	16	12	and	and	CCONJ
eurjchem-1549	16	13	considering	consider	VERB
eurjchem-1549	16	14	the	the	DET
eurjchem-1549	16	15	difficulty	difficulty	NOUN
eurjchem-1549	16	16	of	of	ADP
eurjchem-1549	16	17	handling	handle	VERB
eurjchem-1549	16	18	no	no	INTJ
eurjchem-1549	16	19	as	as	ADP
eurjchem-1549	16	20	a	a	DET
eurjchem-1549	16	21	gas	gas	NOUN
eurjchem-1549	16	22	,	,	PUNCT
eurjchem-1549	16	23	a	a	DET
eurjchem-1549	16	24	great	great	ADJ
eurjchem-1549	16	25	research	research	NOUN
eurjchem-1549	16	26	interest	interest	NOUN
eurjchem-1549	16	27	has	have	AUX
eurjchem-1549	16	28	been	be	AUX
eurjchem-1549	16	29	directed	direct	VERB
eurjchem-1549	16	30	to	to	ADP
eurjchem-1549	16	31	the	the	DET
eurjchem-1549	16	32	modulation	modulation	NOUN
eurjchem-1549	16	33	of	of	ADP
eurjchem-1549	16	34	no	no	PRON
eurjchem-1549	16	35	in	in	ADP
eurjchem-1549	16	36	physiological	physiological	ADJ
eurjchem-1549	16	37	systems	system	NOUN
eurjchem-1549	16	38	by	by	ADP
eurjchem-1549	16	39	increasing	increase	VERB
eurjchem-1549	16	40	its	its	PRON
eurjchem-1549	16	41	concentration	concentration	NOUN
eurjchem-1549	16	42	through	through	ADP
eurjchem-1549	16	43	exogenous	exogenous	ADJ
eurjchem-1549	16	44	release	release	NOUN
eurjchem-1549	16	45	by	by	ADP
eurjchem-1549	16	46	no	no	DET
eurjchem-1549	16	47	donors	donor	NOUN
eurjchem-1549	16	48	.	.	PUNCT
eurjchem-1549	17	1	such	such	ADJ
eurjchem-1549	17	2	no	no	DET
eurjchem-1549	17	3	progenitors	progenitor	NOUN
eurjchem-1549	17	4	have	have	AUX
eurjchem-1549	17	5	now	now	ADV
eurjchem-1549	17	6	received	receive	VERB
eurjchem-1549	17	7	great	great	ADJ
eurjchem-1549	17	8	attention	attention	NOUN
eurjchem-1549	17	9	as	as	ADP
eurjchem-1549	17	10	promising	promise	VERB
eurjchem-1549	17	11	candidates	candidate	NOUN
eurjchem-1549	17	12	for	for	ADP
eurjchem-1549	17	13	the	the	DET
eurjchem-1549	17	14	treatment	treatment	NOUN
eurjchem-1549	17	15	of	of	ADP
eurjchem-1549	17	16	various	various	ADJ
eurjchem-1549	17	17	diseases	disease	NOUN
eurjchem-1549	17	18	associated	associate	VERB
eurjchem-1549	17	19	with	with	ADP
eurjchem-1549	17	20	no‐based	no‐base	VERB
eurjchem-1549	17	21	cellular	cellular	ADJ
eurjchem-1549	17	22	activities	activity	NOUN
eurjchem-1549	17	23	[	[	X
eurjchem-1549	17	24	11,12	11,12	NUM
eurjchem-1549	17	25	]	]	PUNCT
eurjchem-1549	17	26	.	.	PUNCT
eurjchem-1549	18	1	in	in	ADP
eurjchem-1549	18	2	this	this	DET
eurjchem-1549	18	3	regard	regard	NOUN
eurjchem-1549	18	4	,	,	PUNCT
eurjchem-1549	18	5	various	various	ADJ
eurjchem-1549	18	6	classes	class	NOUN
eurjchem-1549	18	7	of	of	ADP
eurjchem-1549	18	8	no	no	DET
eurjchem-1549	18	9	donors	donor	NOUN
eurjchem-1549	18	10	have	have	AUX
eurjchem-1549	18	11	been	be	AUX
eurjchem-1549	18	12	identified	identify	VERB
eurjchem-1549	18	13	as	as	ADP
eurjchem-1549	18	14	organic	organic	ADJ
eurjchem-1549	18	15	nitrates	nitrate	NOUN
eurjchem-1549	18	16	and	and	CCONJ
eurjchem-1549	18	17	nitrites	nitrite	NOUN
eurjchem-1549	18	18	,	,	PUNCT
eurjchem-1549	18	19	s‐nitrosothiols	s‐nitrosothiols	X
eurjchem-1549	18	20	,	,	PUNCT
eurjchem-1549	18	21	sydnonimines	sydnonimine	NOUN
eurjchem-1549	18	22	,	,	PUNCT
eurjchem-1549	18	23	metal	metal	PROPN
eurjchem-1549	18	24	nitrosyls	nitrosyls	ADJ
eurjchem-1549	18	25	,	,	PUNCT
eurjchem-1549	18	26	furoxans	furoxan	NOUN
eurjchem-1549	18	27	,	,	PUNCT
eurjchem-1549	18	28	diazeniumdiolates	diazeniumdiolate	NOUN
eurjchem-1549	18	29	and	and	CCONJ
eurjchem-1549	18	30	oximes	oxime	NOUN
eurjchem-1549	18	31	.	.	PUNCT
eurjchem-1549	19	1	of	of	ADP
eurjchem-1549	19	2	particular	particular	ADJ
eurjchem-1549	19	3	significance	significance	NOUN
eurjchem-1549	19	4	is	be	AUX
eurjchem-1549	19	5	the	the	DET
eurjchem-1549	19	6	proven	prove	VERB
eurjchem-1549	19	7	clinical	clinical	ADJ
eurjchem-1549	19	8	implication	implication	NOUN
eurjchem-1549	19	9	of	of	ADP
eurjchem-1549	19	10	organic	organic	ADJ
eurjchem-1549	19	11	nitrates	nitrate	NOUN
eurjchem-1549	19	12	as	as	ADP
eurjchem-1549	19	13	glyceryl	glyceryl	NOUN
eurjchem-1549	19	14	trinitrate	trinitrate	NOUN
eurjchem-1549	19	15	,	,	PUNCT
eurjchem-1549	19	16	isosorbide	isosorbide	NOUN
eurjchem-1549	19	17	dinitrate	dinitrate	VERB
eurjchem-1549	19	18	and	and	CCONJ
eurjchem-1549	19	19	isosorbide	isosorbide	ADJ
eurjchem-1549	19	20	mononitrate	mononitrate	NOUN
eurjchem-1549	19	21	as	as	ADP
eurjchem-1549	19	22	primary	primary	ADJ
eurjchem-1549	19	23	antianginal	antianginal	ADJ
eurjchem-1549	19	24	medications	medication	NOUN
eurjchem-1549	19	25	[	[	X
eurjchem-1549	19	26	13	13	NUM
eurjchem-1549	19	27	]	]	PUNCT
eurjchem-1549	19	28	.	.	PUNCT
eurjchem-1549	20	1	it	it	PRON
eurjchem-1549	20	2	is	be	AUX
eurjchem-1549	20	3	generally	generally	ADV
eurjchem-1549	20	4	accepted	accept	VERB
eurjchem-1549	20	5	that	that	SCONJ
eurjchem-1549	20	6	the	the	DET
eurjchem-1549	20	7	therapeutic	therapeutic	ADJ
eurjchem-1549	20	8	potential	potential	NOUN
eurjchem-1549	20	9	of	of	ADP
eurjchem-1549	20	10	the	the	DET
eurjchem-1549	20	11	no	no	DET
eurjchem-1549	20	12	donors	donor	NOUN
eurjchem-1549	20	13	largely	largely	ADV
eurjchem-1549	20	14	depends	depend	VERB
eurjchem-1549	20	15	on	on	ADP
eurjchem-1549	20	16	their	their	PRON
eurjchem-1549	20	17	ability	ability	NOUN
eurjchem-1549	20	18	to	to	PART
eurjchem-1549	20	19	release	release	VERB
eurjchem-1549	20	20	no	no	PRON
eurjchem-1549	20	21	in	in	ADP
eurjchem-1549	20	22	the	the	DET
eurjchem-1549	20	23	biological	biological	ADJ
eurjchem-1549	20	24	systems	system	NOUN
eurjchem-1549	20	25	.	.	PUNCT
eurjchem-1549	21	1	in	in	ADP
eurjchem-1549	21	2	order	order	NOUN
eurjchem-1549	21	3	to	to	PART
eurjchem-1549	21	4	correlate	correlate	VERB
eurjchem-1549	21	5	the	the	DET
eurjchem-1549	21	6	no	no	DET
eurjchem-1549	21	7	release	release	NOUN
eurjchem-1549	21	8	with	with	ADP
eurjchem-1549	21	9	biological	biological	ADJ
eurjchem-1549	21	10	effects	effect	NOUN
eurjchem-1549	21	11	,	,	PUNCT
eurjchem-1549	21	12	it	it	PRON
eurjchem-1549	21	13	is	be	AUX
eurjchem-1549	21	14	important	important	ADJ
eurjchem-1549	21	15	to	to	PART
eurjchem-1549	21	16	estimate	estimate	VERB
eurjchem-1549	21	17	no	no	DET
eurjchem-1549	21	18	concentrations	concentration	NOUN
eurjchem-1549	21	19	generated	generate	VERB
eurjchem-1549	21	20	from	from	ADP
eurjchem-1549	21	21	no	no	DET
eurjchem-1549	21	22	donors	donor	NOUN
eurjchem-1549	21	23	in	in	ADP
eurjchem-1549	21	24	vitro	vitro	X
eurjchem-1549	21	25	as	as	ADV
eurjchem-1549	21	26	well	well	ADV
eurjchem-1549	21	27	as	as	ADP
eurjchem-1549	21	28	the	the	DET
eurjchem-1549	21	29	time	time	NOUN
eurjchem-1549	21	30	course	course	NOUN
eurjchem-1549	21	31	of	of	ADP
eurjchem-1549	21	32	the	the	DET
eurjchem-1549	21	33	no	no	DET
eurjchem-1549	21	34	production	production	NOUN
eurjchem-1549	21	35	.	.	PUNCT
eurjchem-1549	22	1	generally	generally	ADV
eurjchem-1549	22	2	,	,	PUNCT
eurjchem-1549	22	3	various	various	ADJ
eurjchem-1549	22	4	methods	method	NOUN
eurjchem-1549	22	5	have	have	AUX
eurjchem-1549	22	6	been	be	AUX
eurjchem-1549	22	7	utilized	utilize	VERB
eurjchem-1549	22	8	to	to	PART
eurjchem-1549	22	9	analyze	analyze	VERB
eurjchem-1549	22	10	no	no	DET
eurjchem-1549	22	11	release	release	NOUN
eurjchem-1549	22	12	from	from	ADP
eurjchem-1549	22	13	no	no	DET
eurjchem-1549	22	14	donors	donor	NOUN
eurjchem-1549	22	15	.	.	PUNCT
eurjchem-1549	23	1	no	no	PRON
eurjchem-1549	23	2	can	can	AUX
eurjchem-1549	23	3	be	be	AUX
eurjchem-1549	23	4	estimated	estimate	VERB
eurjchem-1549	23	5	by	by	ADP
eurjchem-1549	23	6	gas	gas	NOUN
eurjchem-1549	23	7	chromatography‐mass	chromatography‐mass	NOUN
eurjchem-1549	23	8	spectrometry	spectrometry	NOUN
eurjchem-1549	24	1	[	[	X
eurjchem-1549	24	2	14	14	NUM
eurjchem-1549	24	3	]	]	PUNCT
eurjchem-1549	24	4	,	,	PUNCT
eurjchem-1549	24	5	chemiluminescence	chemiluminescence	NOUN
eurjchem-1549	24	6	[	[	X
eurjchem-1549	24	7	15	15	NUM
eurjchem-1549	24	8	]	]	PUNCT
eurjchem-1549	24	9	,	,	PUNCT
eurjchem-1549	24	10	or	or	CCONJ
eurjchem-1549	24	11	by	by	ADP
eurjchem-1549	24	12	fluorescent	fluorescent	ADJ
eurjchem-1549	24	13	probes	probe	NOUN
eurjchem-1549	24	14	such	such	ADJ
eurjchem-1549	24	15	as	as	ADP
eurjchem-1549	24	16	4,5‐diaminofluorescein	4,5‐diaminofluorescein	NOUN
eurjchem-1549	24	17	[	[	X
eurjchem-1549	24	18	16	16	NUM
eurjchem-1549	24	19	]	]	PUNCT
eurjchem-1549	24	20	,	,	PUNCT
eurjchem-1549	24	21	laser	laser	NOUN
eurjchem-1549	24	22	magnetic	magnetic	ADJ
eurjchem-1549	24	23	resonance	resonance	NOUN
eurjchem-1549	24	24	spectroscopy	spectroscopy	VERB
eurjchem-1549	24	25	[	[	X
eurjchem-1549	24	26	17	17	NUM
eurjchem-1549	24	27	]	]	PUNCT
eurjchem-1549	24	28	,	,	PUNCT
eurjchem-1549	24	29	electrochemical	electrochemical	ADJ
eurjchem-1549	24	30	methods	method	NOUN
eurjchem-1549	24	31	[	[	X
eurjchem-1549	24	32	18	18	NUM
eurjchem-1549	24	33	]	]	PUNCT
eurjchem-1549	24	34	and	and	CCONJ
eurjchem-1549	24	35	capillary	capillary	ADJ
eurjchem-1549	24	36	electrophoresis	electrophoresis	NOUN
eurjchem-1549	24	37	with	with	ADP
eurjchem-1549	24	38	laser	laser	NOUN
eurjchem-1549	24	39	induced	induce	VERB
eurjchem-1549	24	40	fluorescence	fluorescence	NOUN
eurjchem-1549	24	41	detection	detection	NOUN
eurjchem-1549	24	42	[	[	X
eurjchem-1549	24	43	19	19	NUM
eurjchem-1549	24	44	]	]	PUNCT
eurjchem-1549	24	45	.	.	PUNCT
eurjchem-1549	25	1	in	in	ADP
eurjchem-1549	25	2	addition	addition	NOUN
eurjchem-1549	25	3	,	,	PUNCT
eurjchem-1549	25	4	griess	griess	NOUN
eurjchem-1549	25	5	colorimetric	colorimetric	ADJ
eurjchem-1549	25	6	assay	assay	NOUN
eurjchem-1549	25	7	[	[	X
eurjchem-1549	25	8	20,21	20,21	NUM
eurjchem-1549	25	9	]	]	PUNCT
eurjchem-1549	25	10	and	and	CCONJ
eurjchem-1549	25	11	its	its	PRON
eurjchem-1549	25	12	modifications	modification	NOUN
eurjchem-1549	25	13	[	[	X
eurjchem-1549	25	14	22,23	22,23	NOUN
eurjchem-1549	25	15	]	]	PUNCT
eurjchem-1549	25	16	represent	represent	VERB
eurjchem-1549	25	17	the	the	DET
eurjchem-1549	25	18	most	most	ADV
eurjchem-1549	25	19	commonly	commonly	ADV
eurjchem-1549	25	20	used	use	VERB
eurjchem-1549	25	21	methods	method	NOUN
eurjchem-1549	25	22	for	for	ADP
eurjchem-1549	25	23	the	the	DET
eurjchem-1549	25	24	analysis	analysis	NOUN
eurjchem-1549	25	25	of	of	ADP
eurjchem-1549	25	26	no	no	PRON
eurjchem-1549	25	27	in	in	ADP
eurjchem-1549	25	28	view	view	NOUN
eurjchem-1549	25	29	of	of	ADP
eurjchem-1549	25	30	the	the	DET
eurjchem-1549	25	31	simplicity	simplicity	NOUN
eurjchem-1549	25	32	and	and	CCONJ
eurjchem-1549	25	33	low	low	ADJ
eurjchem-1549	25	34	cost	cost	NOUN
eurjchem-1549	25	35	.	.	PUNCT
eurjchem-1549	26	1	the	the	DET
eurjchem-1549	26	2	method	method	NOUN
eurjchem-1549	26	3	relies	rely	VERB
eurjchem-1549	26	4	on	on	ADP
eurjchem-1549	26	5	indirect	indirect	ADJ
eurjchem-1549	26	6	determination	determination	NOUN
eurjchem-1549	26	7	of	of	ADP
eurjchem-1549	26	8	no	no	PRON
eurjchem-1549	26	9	via	via	ADP
eurjchem-1549	26	10	spectrophotometric	spectrophotometric	ADJ
eurjchem-1549	26	11	measurement	measurement	NOUN
eurjchem-1549	26	12	of	of	ADP
eurjchem-1549	26	13	its	its	PRON
eurjchem-1549	26	14	stable	stable	ADJ
eurjchem-1549	26	15	decomposition	decomposition	NOUN
eurjchem-1549	26	16	product	product	NOUN
eurjchem-1549	26	17	no2.	no2.	SCONJ
eurjchem-1549	26	18	the	the	DET
eurjchem-1549	26	19	reaction	reaction	NOUN
eurjchem-1549	26	20	involves	involve	VERB
eurjchem-1549	26	21	two	two	NUM
eurjchem-1549	26	22	steps	step	NOUN
eurjchem-1549	26	23	;	;	PUNCT
eurjchem-1549	26	24	the	the	DET
eurjchem-1549	26	25	first	first	ADJ
eurjchem-1549	26	26	step	step	NOUN
eurjchem-1549	26	27	is	be	AUX
eurjchem-1549	26	28	the	the	DET
eurjchem-1549	26	29	reaction	reaction	NOUN
eurjchem-1549	26	30	of	of	ADP
eurjchem-1549	26	31	dinitrogen	dinitrogen	NOUN
eurjchem-1549	26	32	trioxide	trioxide	NOUN
eurjchem-1549	26	33	,	,	PUNCT
eurjchem-1549	26	34	resulting	result	VERB
eurjchem-1549	26	35	from	from	ADP
eurjchem-1549	26	36	the	the	DET
eurjchem-1549	26	37	auto	auto	NOUN
eurjchem-1549	26	38	oxidation	oxidation	NOUN
eurjchem-1549	26	39	of	of	ADP
eurjchem-1549	26	40	no	no	NOUN
eurjchem-1549	26	41	,	,	PUNCT
eurjchem-1549	26	42	with	with	ADP
eurjchem-1549	26	43	sulfanilamide	sulfanilamide	NOUN
eurjchem-1549	26	44	to	to	PART
eurjchem-1549	26	45	produce	produce	VERB
eurjchem-1549	26	46	a	a	DET
eurjchem-1549	26	47	diazonium	diazonium	NOUN
eurjchem-1549	26	48	ion	ion	NOUN
eurjchem-1549	26	49	.	.	PUNCT
eurjchem-1549	27	1	the	the	DET
eurjchem-1549	27	2	second	second	ADJ
eurjchem-1549	27	3	step	step	NOUN
eurjchem-1549	27	4	is	be	AUX
eurjchem-1549	27	5	the	the	DET
eurjchem-1549	27	6	coupling	coupling	NOUN
eurjchem-1549	27	7	of	of	ADP
eurjchem-1549	27	8	diazonium	diazonium	NOUN
eurjchem-1549	27	9	120	120	NUM
eurjchem-1549	27	10	aziz	aziz	PROPN
eurjchem-1549	27	11	et	et	PROPN
eurjchem-1549	27	12	al	al	PROPN
eurjchem-1549	27	13	.	.	PUNCT
eurjchem-1549	27	14	/	/	SYM
eurjchem-1549	27	15	european	european	PROPN
eurjchem-1549	27	16	journal	journal	PROPN
eurjchem-1549	27	17	of	of	ADP
eurjchem-1549	27	18	chemistry	chemistry	NOUN
eurjchem-1549	27	19	8	8	NUM
eurjchem-1549	27	20	(	(	PUNCT
eurjchem-1549	27	21	2	2	NUM
eurjchem-1549	27	22	)	)	PUNCT
eurjchem-1549	27	23	(	(	PUNCT
eurjchem-1549	27	24	2017	2017	NUM
eurjchem-1549	27	25	)	)	PUNCT
eurjchem-1549	27	26	119‐124	119‐124	PROPN
eurjchem-1549	27	27	ion	ion	NOUN
eurjchem-1549	27	28	with	with	ADP
eurjchem-1549	27	29	n‐(1‐naphthyl)ethylenediamine	n‐(1‐naphthyl)ethylenediamine	PROPN
eurjchem-1549	27	30	(	(	PUNCT
eurjchem-1549	27	31	ned	ned	PROPN
eurjchem-1549	27	32	)	)	PUNCT
eurjchem-1549	27	33	to	to	PART
eurjchem-1549	27	34	form	form	VERB
eurjchem-1549	27	35	a	a	DET
eurjchem-1549	27	36	coloured	coloured	ADJ
eurjchem-1549	27	37	azo	azo	NOUN
eurjchem-1549	27	38	dye	dye	NOUN
eurjchem-1549	27	39	that	that	PRON
eurjchem-1549	27	40	absorbs	absorb	VERB
eurjchem-1549	27	41	at	at	ADP
eurjchem-1549	27	42	max	max	NUM
eurjchem-1549	27	43	546	546	NUM
eurjchem-1549	27	44	nm	nm	NOUN
eurjchem-1549	27	45	.	.	PUNCT
eurjchem-1549	28	1	despite	despite	SCONJ
eurjchem-1549	28	2	the	the	DET
eurjchem-1549	28	3	feasibility	feasibility	NOUN
eurjchem-1549	28	4	of	of	ADP
eurjchem-1549	28	5	the	the	DET
eurjchem-1549	28	6	method	method	NOUN
eurjchem-1549	28	7	,	,	PUNCT
eurjchem-1549	28	8	it	it	PRON
eurjchem-1549	28	9	sometimes	sometimes	ADV
eurjchem-1549	28	10	suffers	suffer	VERB
eurjchem-1549	28	11	from	from	ADP
eurjchem-1549	28	12	poor	poor	ADJ
eurjchem-1549	28	13	sensitivity	sensitivity	NOUN
eurjchem-1549	28	14	and	and	CCONJ
eurjchem-1549	28	15	inferior	inferior	ADJ
eurjchem-1549	28	16	reproducibility	reproducibility	NOUN
eurjchem-1549	28	17	at	at	ADP
eurjchem-1549	28	18	submicromolar	submicromolar	ADJ
eurjchem-1549	28	19	concentrations	concentration	NOUN
eurjchem-1549	28	20	of	of	ADP
eurjchem-1549	28	21	no	no	NOUN
eurjchem-1549	28	22	.	.	PUNCT
eurjchem-1549	29	1	in	in	ADP
eurjchem-1549	29	2	continuation	continuation	NOUN
eurjchem-1549	29	3	of	of	ADP
eurjchem-1549	29	4	our	our	PRON
eurjchem-1549	29	5	efforts	effort	NOUN
eurjchem-1549	29	6	to	to	PART
eurjchem-1549	29	7	discover	discover	VERB
eurjchem-1549	29	8	new	new	ADJ
eurjchem-1549	29	9	no‐based	no‐base	VERB
eurjchem-1549	29	10	drug	drug	NOUN
eurjchem-1549	29	11	candidates	candidate	NOUN
eurjchem-1549	29	12	,	,	PUNCT
eurjchem-1549	29	13	the	the	DET
eurjchem-1549	29	14	present	present	ADJ
eurjchem-1549	29	15	work	work	NOUN
eurjchem-1549	29	16	aims	aim	VERB
eurjchem-1549	29	17	at	at	ADP
eurjchem-1549	29	18	the	the	DET
eurjchem-1549	29	19	synthesis	synthesis	NOUN
eurjchem-1549	29	20	and	and	CCONJ
eurjchem-1549	29	21	characterization	characterization	NOUN
eurjchem-1549	29	22	of	of	ADP
eurjchem-1549	29	23	new	new	ADJ
eurjchem-1549	29	24	norfloxacin	norfloxacin	PROPN
eurjchem-1549	29	25	/	/	SYM
eurjchem-1549	29	26	no	no	DET
eurjchem-1549	29	27	donor	donor	NOUN
eurjchem-1549	29	28	hybrids	hybrid	NOUN
eurjchem-1549	29	29	with	with	ADP
eurjchem-1549	29	30	potential	potential	ADJ
eurjchem-1549	29	31	synergistic	synergistic	ADJ
eurjchem-1549	29	32	antimicrobial	antimicrobial	ADJ
eurjchem-1549	29	33	properties	property	NOUN
eurjchem-1549	29	34	.	.	PUNCT
eurjchem-1549	30	1	the	the	DET
eurjchem-1549	30	2	release	release	NOUN
eurjchem-1549	30	3	of	of	ADP
eurjchem-1549	30	4	no	no	PRON
eurjchem-1549	30	5	from	from	ADP
eurjchem-1549	30	6	the	the	DET
eurjchem-1549	30	7	prepared	prepared	ADJ
eurjchem-1549	30	8	hybrids	hybrid	NOUN
eurjchem-1549	30	9	is	be	AUX
eurjchem-1549	30	10	estimated	estimate	VERB
eurjchem-1549	30	11	by	by	ADP
eurjchem-1549	30	12	adapting	adapt	VERB
eurjchem-1549	30	13	a	a	DET
eurjchem-1549	30	14	modification	modification	NOUN
eurjchem-1549	30	15	to	to	ADP
eurjchem-1549	30	16	the	the	DET
eurjchem-1549	30	17	common	common	ADJ
eurjchem-1549	30	18	griess	griess	NOUN
eurjchem-1549	30	19	method	method	NOUN
eurjchem-1549	30	20	with	with	ADP
eurjchem-1549	30	21	a	a	DET
eurjchem-1549	30	22	view	view	NOUN
eurjchem-1549	30	23	to	to	ADP
eurjchem-1549	30	24	enhancing	enhance	VERB
eurjchem-1549	30	25	the	the	DET
eurjchem-1549	30	26	sensitivity	sensitivity	NOUN
eurjchem-1549	30	27	and	and	CCONJ
eurjchem-1549	30	28	shortening	shorten	VERB
eurjchem-1549	30	29	the	the	DET
eurjchem-1549	30	30	assessment	assessment	NOUN
eurjchem-1549	30	31	time	time	NOUN
eurjchem-1549	30	32	.	.	PUNCT
eurjchem-1549	31	1	2	2	X
eurjchem-1549	31	2	.	.	X
eurjchem-1549	31	3	experimental	experimental	ADJ
eurjchem-1549	31	4	2.1	2.1	NUM
eurjchem-1549	31	5	.	.	PUNCT
eurjchem-1549	32	1	instrumentations	instrumentation	NOUN
eurjchem-1549	32	2	all	all	DET
eurjchem-1549	32	3	chemicals	chemical	NOUN
eurjchem-1549	32	4	and	and	CCONJ
eurjchem-1549	32	5	solvents	solvent	NOUN
eurjchem-1549	32	6	used	use	VERB
eurjchem-1549	32	7	for	for	ADP
eurjchem-1549	32	8	the	the	DET
eurjchem-1549	32	9	preparation	preparation	NOUN
eurjchem-1549	32	10	of	of	ADP
eurjchem-1549	32	11	the	the	DET
eurjchem-1549	32	12	intermediates	intermediate	NOUN
eurjchem-1549	32	13	and	and	CCONJ
eurjchem-1549	32	14	target	target	NOUN
eurjchem-1549	32	15	compounds	compound	NOUN
eurjchem-1549	32	16	were	be	AUX
eurjchem-1549	32	17	purchased	purchase	VERB
eurjchem-1549	32	18	from	from	ADP
eurjchem-1549	32	19	commercial	commercial	ADJ
eurjchem-1549	32	20	resources	resource	NOUN
eurjchem-1549	32	21	and	and	CCONJ
eurjchem-1549	32	22	used	use	VERB
eurjchem-1549	32	23	without	without	ADP
eurjchem-1549	32	24	purification	purification	NOUN
eurjchem-1549	32	25	.	.	PUNCT
eurjchem-1549	33	1	the	the	DET
eurjchem-1549	33	2	reaction	reaction	NOUN
eurjchem-1549	33	3	progress	progress	NOUN
eurjchem-1549	33	4	was	be	AUX
eurjchem-1549	33	5	monitored	monitor	VERB
eurjchem-1549	33	6	using	use	VERB
eurjchem-1549	33	7	tlc	tlc	NOUN
eurjchem-1549	33	8	(	(	PUNCT
eurjchem-1549	33	9	kieselgel	kieselgel	NOUN
eurjchem-1549	33	10	60	60	NUM
eurjchem-1549	33	11	f254	f254	PROPN
eurjchem-1549	33	12	pre‐coated	pre‐coate	VERB
eurjchem-1549	33	13	plates	plate	NOUN
eurjchem-1549	33	14	,	,	PUNCT
eurjchem-1549	33	15	e.	e.	PROPN
eurjchem-1549	33	16	merck	merck	PROPN
eurjchem-1549	33	17	,	,	PUNCT
eurjchem-1549	33	18	darmstadt	darmstadt	PROPN
eurjchem-1549	33	19	,	,	PUNCT
eurjchem-1549	33	20	germany	germany	PROPN
eurjchem-1549	33	21	)	)	PUNCT
eurjchem-1549	33	22	and	and	CCONJ
eurjchem-1549	33	23	the	the	DET
eurjchem-1549	33	24	spots	spot	NOUN
eurjchem-1549	33	25	were	be	AUX
eurjchem-1549	33	26	detected	detect	VERB
eurjchem-1549	33	27	by	by	ADP
eurjchem-1549	33	28	exposure	exposure	NOUN
eurjchem-1549	33	29	to	to	ADP
eurjchem-1549	33	30	uv	uv	NOUN
eurjchem-1549	33	31	lamp	lamp	NOUN
eurjchem-1549	33	32	at	at	ADP
eurjchem-1549	33	33	λ	λ	PROPN
eurjchem-1549	33	34	254	254	NUM
eurjchem-1549	33	35	and	and	CCONJ
eurjchem-1549	33	36	365	365	NUM
eurjchem-1549	33	37	nm	nm	NOUN
eurjchem-1549	33	38	.	.	PUNCT
eurjchem-1549	34	1	melting	melt	VERB
eurjchem-1549	34	2	points	point	NOUN
eurjchem-1549	34	3	were	be	AUX
eurjchem-1549	34	4	determined	determine	VERB
eurjchem-1549	34	5	on	on	ADP
eurjchem-1549	34	6	stuart	stuart	PROPN
eurjchem-1549	34	7	electrothermal	electrothermal	ADJ
eurjchem-1549	34	8	melting	melting	NOUN
eurjchem-1549	34	9	point	point	NOUN
eurjchem-1549	34	10	apparatus	apparatus	NOUN
eurjchem-1549	34	11	and	and	CCONJ
eurjchem-1549	34	12	were	be	AUX
eurjchem-1549	34	13	uncorrected	uncorrecte	VERB
eurjchem-1549	34	14	.	.	PUNCT
eurjchem-1549	35	1	ir	ir	PROPN
eurjchem-1549	35	2	spectra	spectra	PROPN
eurjchem-1549	35	3	were	be	AUX
eurjchem-1549	35	4	recorded	record	VERB
eurjchem-1549	35	5	as	as	ADP
eurjchem-1549	35	6	kbr	kbr	PROPN
eurjchem-1549	35	7	disks	disk	NOUN
eurjchem-1549	35	8	on	on	ADP
eurjchem-1549	35	9	shimadzu	shimadzu	PROPN
eurjchem-1549	35	10	ir‐470	ir‐470	PROPN
eurjchem-1549	35	11	spectro‐	spectro‐	NOUN
eurjchem-1549	35	12	photometer	photometer	PROPN
eurjchem-1549	35	13	,	,	PUNCT
eurjchem-1549	35	14	at	at	ADP
eurjchem-1549	35	15	the	the	DET
eurjchem-1549	35	16	central	central	ADJ
eurjchem-1549	35	17	laboratory	laboratory	NOUN
eurjchem-1549	35	18	,	,	PUNCT
eurjchem-1549	35	19	faculty	faculty	NOUN
eurjchem-1549	35	20	of	of	ADP
eurjchem-1549	35	21	science	science	NOUN
eurjchem-1549	35	22	,	,	PUNCT
eurjchem-1549	35	23	sohag	sohag	NOUN
eurjchem-1549	35	24	university	university	NOUN
eurjchem-1549	35	25	.	.	PUNCT
eurjchem-1549	36	1	nmr	nmr	PROPN
eurjchem-1549	36	2	spectra	spectra	NOUN
eurjchem-1549	36	3	(	(	PUNCT
eurjchem-1549	36	4	400	400	NUM
eurjchem-1549	36	5	mhz	mhz	NOUN
eurjchem-1549	36	6	for	for	ADP
eurjchem-1549	36	7	1h	1h	NUM
eurjchem-1549	36	8	,	,	PUNCT
eurjchem-1549	36	9	100	100	NUM
eurjchem-1549	36	10	mhz	mhz	NOUN
eurjchem-1549	36	11	for	for	ADP
eurjchem-1549	36	12	13c	13c	NOUN
eurjchem-1549	36	13	)	)	PUNCT
eurjchem-1549	36	14	were	be	AUX
eurjchem-1549	36	15	recorded	record	VERB
eurjchem-1549	36	16	on	on	ADP
eurjchem-1549	36	17	a	a	DET
eurjchem-1549	36	18	bruker	bruker	PROPN
eurjchem-1549	36	19	avance	avance	PROPN
eurjchem-1549	36	20	iii	iii	PROPN
eurjchem-1549	36	21	spectrometer	spectrometer	NOUN
eurjchem-1549	36	22	at	at	ADP
eurjchem-1549	36	23	the	the	DET
eurjchem-1549	36	24	faculty	faculty	NOUN
eurjchem-1549	36	25	of	of	ADP
eurjchem-1549	36	26	science	science	NOUN
eurjchem-1549	36	27	,	,	PUNCT
eurjchem-1549	36	28	sohag	sohag	NOUN
eurjchem-1549	36	29	university	university	NOUN
eurjchem-1549	36	30	,	,	PUNCT
eurjchem-1549	36	31	using	use	VERB
eurjchem-1549	36	32	tms	tms	PROPN
eurjchem-1549	36	33	as	as	ADP
eurjchem-1549	36	34	an	an	DET
eurjchem-1549	36	35	internal	internal	ADJ
eurjchem-1549	36	36	standard	standard	NOUN
eurjchem-1549	36	37	and	and	CCONJ
eurjchem-1549	36	38	cdcl3	cdcl3	NOUN
eurjchem-1549	36	39	or	or	CCONJ
eurjchem-1549	36	40	dmso‐d6	dmso‐d6	NOUN
eurjchem-1549	36	41	as	as	ADP
eurjchem-1549	36	42	solvents	solvent	NOUN
eurjchem-1549	36	43	.	.	PUNCT
eurjchem-1549	37	1	chemical	chemical	ADJ
eurjchem-1549	37	2	shifts	shift	NOUN
eurjchem-1549	37	3	(	(	PUNCT
eurjchem-1549	37	4	δ	δ	NOUN
eurjchem-1549	37	5	)	)	PUNCT
eurjchem-1549	37	6	values	value	NOUN
eurjchem-1549	37	7	are	be	AUX
eurjchem-1549	37	8	expressed	express	VERB
eurjchem-1549	37	9	in	in	ADP
eurjchem-1549	37	10	parts	part	NOUN
eurjchem-1549	37	11	per	per	ADP
eurjchem-1549	37	12	million	million	NUM
eurjchem-1549	37	13	(	(	PUNCT
eurjchem-1549	37	14	ppm	ppm	NOUN
eurjchem-1549	37	15	)	)	PUNCT
eurjchem-1549	37	16	and	and	CCONJ
eurjchem-1549	37	17	coupling	couple	VERB
eurjchem-1549	37	18	constants	constant	NOUN
eurjchem-1549	37	19	(	(	PUNCT
eurjchem-1549	37	20	j	j	NOUN
eurjchem-1549	37	21	)	)	PUNCT
eurjchem-1549	37	22	in	in	ADP
eurjchem-1549	37	23	hertz	hertz	NOUN
eurjchem-1549	37	24	(	(	PUNCT
eurjchem-1549	37	25	hz	hz	PROPN
eurjchem-1549	37	26	)	)	PUNCT
eurjchem-1549	37	27	.	.	PUNCT
eurjchem-1549	38	1	the	the	DET
eurjchem-1549	38	2	signals	signal	NOUN
eurjchem-1549	38	3	are	be	AUX
eurjchem-1549	38	4	designated	designate	VERB
eurjchem-1549	38	5	as	as	SCONJ
eurjchem-1549	38	6	follows	follow	VERB
eurjchem-1549	38	7	:	:	PUNCT
eurjchem-1549	38	8	s	s	X
eurjchem-1549	38	9	,	,	PUNCT
eurjchem-1549	38	10	singlet	singlet	ADJ
eurjchem-1549	38	11	;	;	PUNCT
eurjchem-1549	38	12	d	d	X
eurjchem-1549	38	13	,	,	PUNCT
eurjchem-1549	38	14	doublet	doublet	PROPN
eurjchem-1549	38	15	;	;	PUNCT
eurjchem-1549	38	16	t	t	PROPN
eurjchem-1549	38	17	,	,	PUNCT
eurjchem-1549	38	18	triplet	triplet	NOUN
eurjchem-1549	38	19	;	;	PUNCT
eurjchem-1549	38	20	q	q	X
eurjchem-1549	38	21	,	,	PUNCT
eurjchem-1549	38	22	quartet	quartet	NOUN
eurjchem-1549	38	23	;	;	PUNCT
eurjchem-1549	38	24	m	m	PROPN
eurjchem-1549	38	25	,	,	PUNCT
eurjchem-1549	38	26	multiplet	multiplet	NOUN
eurjchem-1549	38	27	;	;	PUNCT
eurjchem-1549	38	28	brs	br	VERB
eurjchem-1549	38	29	,	,	PUNCT
eurjchem-1549	38	30	broad	broad	ADJ
eurjchem-1549	38	31	singlet	singlet	NOUN
eurjchem-1549	38	32	.	.	PUNCT
eurjchem-1549	39	1	elemental	elemental	ADJ
eurjchem-1549	39	2	microanalysis	microanalysis	NOUN
eurjchem-1549	39	3	was	be	AUX
eurjchem-1549	39	4	carried	carry	VERB
eurjchem-1549	39	5	out	out	ADP
eurjchem-1549	39	6	in	in	ADP
eurjchem-1549	39	7	al‐azhar	al‐azhar	PROPN
eurjchem-1549	39	8	university	university	NOUN
eurjchem-1549	39	9	at	at	ADP
eurjchem-1549	39	10	the	the	DET
eurjchem-1549	39	11	regional	regional	ADJ
eurjchem-1549	39	12	centre	centre	NOUN
eurjchem-1549	39	13	for	for	ADP
eurjchem-1549	39	14	mycology	mycology	NOUN
eurjchem-1549	39	15	and	and	CCONJ
eurjchem-1549	39	16	biotechnology	biotechnology	NOUN
eurjchem-1549	39	17	.	.	PUNCT
eurjchem-1549	40	1	high	high	ADJ
eurjchem-1549	40	2	resolution	resolution	NOUN
eurjchem-1549	40	3	mass	mass	PROPN
eurjchem-1549	40	4	spectra	spectra	PROPN
eurjchem-1549	40	5	were	be	AUX
eurjchem-1549	40	6	recorded	record	VERB
eurjchem-1549	40	7	on	on	ADP
eurjchem-1549	40	8	thermo	thermo	NOUN
eurjchem-1549	40	9	scientific	scientific	ADJ
eurjchem-1549	40	10	q	q	PROPN
eurjchem-1549	40	11	exactive	exactive	ADJ
eurjchem-1549	40	12	orbitrap	orbitrap	NOUN
eurjchem-1549	40	13	mass	mass	NOUN
eurjchem-1549	40	14	spectrometer	spectrometer	NOUN
eurjchem-1549	40	15	,	,	PUNCT
eurjchem-1549	40	16	faculty	faculty	NOUN
eurjchem-1549	40	17	of	of	ADP
eurjchem-1549	40	18	pharmaceutical	pharmaceutical	NOUN
eurjchem-1549	40	19	sciences	science	NOUN
eurjchem-1549	40	20	,	,	PUNCT
eurjchem-1549	40	21	university	university	NOUN
eurjchem-1549	40	22	of	of	ADP
eurjchem-1549	40	23	british	british	PROPN
eurjchem-1549	40	24	columbia	columbia	PROPN
eurjchem-1549	40	25	,	,	PUNCT
eurjchem-1549	40	26	vancouver	vancouver	PROPN
eurjchem-1549	40	27	,	,	PUNCT
eurjchem-1549	40	28	canada	canada	PROPN
eurjchem-1549	40	29	.	.	PUNCT
eurjchem-1549	41	1	2.2	2.2	NUM
eurjchem-1549	41	2	.	.	PUNCT
eurjchem-1549	42	1	synthesis	synthesis	NOUN
eurjchem-1549	42	2	2.2.1	2.2.1	NUM
eurjchem-1549	42	3	.	.	PUNCT
eurjchem-1549	42	4	synthesis	synthesis	NOUN
eurjchem-1549	42	5	of	of	ADP
eurjchem-1549	42	6	7‐(4‐(2‐bromoacetyl	7‐(4‐(2‐bromoacetyl	NUM
eurjchem-1549	42	7	)	)	PUNCT
eurjchem-1549	42	8	piperazin‐1‐yl)‐1‐	piperazin‐1‐yl)‐1‐	ADJ
eurjchem-1549	42	9	ethyl‐6‐fluoro‐1,4‐dihydro‐4‐oxoquinoline‐3‐carboxylic	ethyl‐6‐fluoro‐1,4‐dihydro‐4‐oxoquinoline‐3‐carboxylic	ADJ
eurjchem-1549	42	10	acid	acid	NOUN
eurjchem-1549	42	11	(	(	PUNCT
eurjchem-1549	42	12	2	2	NUM
eurjchem-1549	42	13	)	)	PUNCT
eurjchem-1549	42	14	to	to	ADP
eurjchem-1549	42	15	a	a	DET
eurjchem-1549	42	16	stirred	stir	VERB
eurjchem-1549	42	17	solution	solution	NOUN
eurjchem-1549	42	18	of	of	ADP
eurjchem-1549	42	19	norfloxacin	norfloxacin	PROPN
eurjchem-1549	42	20	(	(	PUNCT
eurjchem-1549	42	21	0.319	0.319	NUM
eurjchem-1549	42	22	g	g	NOUN
eurjchem-1549	42	23	,	,	PUNCT
eurjchem-1549	42	24	1.0	1.0	NUM
eurjchem-1549	42	25	mmol	mmol	NOUN
eurjchem-1549	42	26	)	)	PUNCT
eurjchem-1549	42	27	in	in	ADP
eurjchem-1549	42	28	dichloromethane	dichloromethane	NOUN
eurjchem-1549	42	29	(	(	PUNCT
eurjchem-1549	42	30	50	50	NUM
eurjchem-1549	42	31	ml	ml	NOUN
eurjchem-1549	42	32	)	)	PUNCT
eurjchem-1549	42	33	was	be	AUX
eurjchem-1549	42	34	added	add	VERB
eurjchem-1549	42	35	a	a	DET
eurjchem-1549	42	36	solution	solution	NOUN
eurjchem-1549	42	37	of	of	ADP
eurjchem-1549	42	38	potassium	potassium	NOUN
eurjchem-1549	42	39	carbonate	carbonate	NOUN
eurjchem-1549	42	40	(	(	PUNCT
eurjchem-1549	42	41	0.152	0.152	NUM
eurjchem-1549	42	42	g	g	NOUN
eurjchem-1549	42	43	,	,	PUNCT
eurjchem-1549	42	44	1.1	1.1	NUM
eurjchem-1549	42	45	mmol	mmol	NOUN
eurjchem-1549	42	46	)	)	PUNCT
eurjchem-1549	42	47	in	in	ADP
eurjchem-1549	42	48	distilled	distil	VERB
eurjchem-1549	42	49	water	water	NOUN
eurjchem-1549	42	50	(	(	PUNCT
eurjchem-1549	42	51	50	50	NUM
eurjchem-1549	42	52	ml	ml	NOUN
eurjchem-1549	42	53	)	)	PUNCT
eurjchem-1549	42	54	at	at	ADP
eurjchem-1549	42	55	0‐5	0‐5	NOUN
eurjchem-1549	42	56	°	°	ADP
eurjchem-1549	42	57	c	c	X
eurjchem-1549	42	58	.	.	PUNCT
eurjchem-1549	43	1	then	then	ADV
eurjchem-1549	43	2	,	,	PUNCT
eurjchem-1549	43	3	bromoacetyl	bromoacetyl	VERB
eurjchem-1549	43	4	bromide	bromide	NOUN
eurjchem-1549	43	5	(	(	PUNCT
eurjchem-1549	43	6	0.22	0.22	NUM
eurjchem-1549	43	7	g	g	NOUN
eurjchem-1549	43	8	,	,	PUNCT
eurjchem-1549	43	9	1.1	1.1	NUM
eurjchem-1549	43	10	mmol	mmol	NOUN
eurjchem-1549	43	11	)	)	PUNCT
eurjchem-1549	43	12	in	in	ADP
eurjchem-1549	43	13	dichloromethane	dichloromethane	NOUN
eurjchem-1549	43	14	(	(	PUNCT
eurjchem-1549	43	15	25	25	NUM
eurjchem-1549	43	16	ml	ml	NOUN
eurjchem-1549	43	17	)	)	PUNCT
eurjchem-1549	43	18	was	be	AUX
eurjchem-1549	43	19	slowly	slowly	ADV
eurjchem-1549	43	20	added	add	VERB
eurjchem-1549	43	21	over	over	ADP
eurjchem-1549	43	22	a	a	DET
eurjchem-1549	43	23	period	period	NOUN
eurjchem-1549	43	24	of	of	ADP
eurjchem-1549	43	25	30	30	NUM
eurjchem-1549	43	26	min	min	NOUN
eurjchem-1549	43	27	.	.	NOUN
eurjchem-1549	43	28	stirring	stirring	NOUN
eurjchem-1549	43	29	was	be	AUX
eurjchem-1549	43	30	continued	continue	VERB
eurjchem-1549	43	31	for	for	ADP
eurjchem-1549	43	32	2	2	NUM
eurjchem-1549	43	33	h	h	NOUN
eurjchem-1549	43	34	at	at	ADP
eurjchem-1549	43	35	0‐5	0‐5	NOUN
eurjchem-1549	43	36	°	°	SCONJ
eurjchem-1549	43	37	c	c	NOUN
eurjchem-1549	43	38	,	,	PUNCT
eurjchem-1549	43	39	then	then	ADV
eurjchem-1549	43	40	at	at	ADP
eurjchem-1549	43	41	room	room	NOUN
eurjchem-1549	43	42	temperature	temperature	NOUN
eurjchem-1549	43	43	for	for	ADP
eurjchem-1549	43	44	additional	additional	ADJ
eurjchem-1549	43	45	12	12	NUM
eurjchem-1549	43	46	h.	h.	NOUN
eurjchem-1549	43	47	the	the	DET
eurjchem-1549	43	48	whole	whole	ADJ
eurjchem-1549	43	49	mixture	mixture	NOUN
eurjchem-1549	43	50	was	be	AUX
eurjchem-1549	43	51	then	then	ADV
eurjchem-1549	43	52	transferred	transfer	VERB
eurjchem-1549	43	53	to	to	ADP
eurjchem-1549	43	54	a	a	DET
eurjchem-1549	43	55	separatory	separatory	ADJ
eurjchem-1549	43	56	funnel	funnel	NOUN
eurjchem-1549	43	57	where	where	SCONJ
eurjchem-1549	43	58	it	it	PRON
eurjchem-1549	43	59	was	be	AUX
eurjchem-1549	43	60	extracted	extract	VERB
eurjchem-1549	43	61	with	with	ADP
eurjchem-1549	43	62	dichloromethane	dichloromethane	NOUN
eurjchem-1549	43	63	and	and	CCONJ
eurjchem-1549	43	64	washed	wash	VERB
eurjchem-1549	43	65	successively	successively	ADV
eurjchem-1549	43	66	with	with	ADP
eurjchem-1549	43	67	1.0	1.0	NUM
eurjchem-1549	43	68	n	n	PRON
eurjchem-1549	43	69	hcl	hcl	PROPN
eurjchem-1549	43	70	(	(	PUNCT
eurjchem-1549	43	71	2×25	2×25	NUM
eurjchem-1549	43	72	ml	ml	NOUN
eurjchem-1549	43	73	)	)	PUNCT
eurjchem-1549	43	74	and	and	CCONJ
eurjchem-1549	43	75	water	water	NOUN
eurjchem-1549	43	76	(	(	PUNCT
eurjchem-1549	43	77	2×25	2×25	NUM
eurjchem-1549	43	78	ml	ml	NOUN
eurjchem-1549	43	79	)	)	PUNCT
eurjchem-1549	43	80	.	.	PUNCT
eurjchem-1549	44	1	the	the	DET
eurjchem-1549	44	2	organic	organic	ADJ
eurjchem-1549	44	3	layer	layer	NOUN
eurjchem-1549	44	4	was	be	AUX
eurjchem-1549	44	5	separated	separate	VERB
eurjchem-1549	44	6	,	,	PUNCT
eurjchem-1549	44	7	dried	dry	VERB
eurjchem-1549	44	8	over	over	ADP
eurjchem-1549	44	9	anhydrous	anhydrous	ADJ
eurjchem-1549	44	10	sodium	sodium	NOUN
eurjchem-1549	44	11	sulphate	sulphate	NOUN
eurjchem-1549	44	12	,	,	PUNCT
eurjchem-1549	44	13	filtered	filter	VERB
eurjchem-1549	44	14	and	and	CCONJ
eurjchem-1549	44	15	evaporated	evaporate	VERB
eurjchem-1549	44	16	under	under	ADP
eurjchem-1549	44	17	reduced	reduce	VERB
eurjchem-1549	44	18	pressure	pressure	NOUN
eurjchem-1549	44	19	to	to	PART
eurjchem-1549	44	20	give	give	VERB
eurjchem-1549	44	21	compound	compound	NOUN
eurjchem-1549	44	22	2	2	NUM
eurjchem-1549	44	23	in	in	ADP
eurjchem-1549	44	24	a	a	DET
eurjchem-1549	44	25	sufficiently	sufficiently	ADV
eurjchem-1549	44	26	pure	pure	ADJ
eurjchem-1549	44	27	form	form	NOUN
eurjchem-1549	44	28	suitable	suitable	ADJ
eurjchem-1549	44	29	for	for	ADP
eurjchem-1549	44	30	use	use	NOUN
eurjchem-1549	44	31	in	in	ADP
eurjchem-1549	44	32	the	the	DET
eurjchem-1549	44	33	next	next	ADJ
eurjchem-1549	44	34	reaction	reaction	NOUN
eurjchem-1549	44	35	without	without	ADP
eurjchem-1549	44	36	further	further	ADJ
eurjchem-1549	44	37	purification	purification	NOUN
eurjchem-1549	44	38	(	(	PUNCT
eurjchem-1549	44	39	scheme	scheme	NOUN
eurjchem-1549	44	40	1	1	NUM
eurjchem-1549	44	41	)	)	PUNCT
eurjchem-1549	44	42	.	.	PUNCT
eurjchem-1549	45	1	color	color	NOUN
eurjchem-1549	45	2	:	:	PUNCT
eurjchem-1549	45	3	white	white	ADJ
eurjchem-1549	45	4	powder	powder	NOUN
eurjchem-1549	45	5	.	.	PUNCT
eurjchem-1549	46	1	yield	yield	NOUN
eurjchem-1549	46	2	:	:	PUNCT
eurjchem-1549	46	3	0.370	0.370	NUM
eurjchem-1549	46	4	g	g	NOUN
eurjchem-1549	46	5	(	(	PUNCT
eurjchem-1549	46	6	84	84	NUM
eurjchem-1549	46	7	%	%	NOUN
eurjchem-1549	46	8	)	)	PUNCT
eurjchem-1549	46	9	.	.	PUNCT
eurjchem-1549	47	1	m.p	m.p	PROPN
eurjchem-1549	47	2	.	.	PROPN
eurjchem-1549	47	3	:	:	PUNCT
eurjchem-1549	48	1	247‐249	247‐249	PROPN
eurjchem-1549	48	2	°	°	ADP
eurjchem-1549	48	3	c	c	PROPN
eurjchem-1549	48	4	.	.	PUNCT
eurjchem-1549	49	1	ft‐ir	ft‐ir	NOUN
eurjchem-1549	49	2	(	(	PUNCT
eurjchem-1549	49	3	kbr	kbr	PROPN
eurjchem-1549	49	4	,	,	PUNCT
eurjchem-1549	49	5	ν	ν	PROPN
eurjchem-1549	49	6	,	,	PUNCT
eurjchem-1549	49	7	cm‐1	cm‐1	PROPN
eurjchem-1549	49	8	):	):	PUNCT
eurjchem-1549	49	9	1713	1713	NUM
eurjchem-1549	49	10	(	(	PUNCT
eurjchem-1549	49	11	carboxylic	carboxylic	ADJ
eurjchem-1549	49	12	c	c	NOUN
eurjchem-1549	49	13	=	=	NOUN
eurjchem-1549	49	14	o	o	NOUN
eurjchem-1549	49	15	)	)	PUNCT
eurjchem-1549	49	16	,	,	PUNCT
eurjchem-1549	49	17	1666	1666	NUM
eurjchem-1549	49	18	(	(	PUNCT
eurjchem-1549	49	19	amidic	amidic	PROPN
eurjchem-1549	49	20	c	c	PROPN
eurjchem-1549	49	21	=	=	NOUN
eurjchem-1549	49	22	o	o	NOUN
eurjchem-1549	49	23	)	)	PUNCT
eurjchem-1549	49	24	,	,	PUNCT
eurjchem-1549	49	25	1620	1620	NUM
eurjchem-1549	49	26	(	(	PUNCT
eurjchem-1549	49	27	4‐keto	4‐keto	NOUN
eurjchem-1549	49	28	c	c	NOUN
eurjchem-1549	49	29	=	=	NOUN
eurjchem-1549	49	30	o	o	NOUN
eurjchem-1549	49	31	)	)	PUNCT
eurjchem-1549	49	32	.	.	PUNCT
eurjchem-1549	50	1	1h	1h	NUM
eurjchem-1549	50	2	nmr	nmr	NOUN
eurjchem-1549	50	3	(	(	PUNCT
eurjchem-1549	50	4	400	400	NUM
eurjchem-1549	50	5	mhz	mhz	NOUN
eurjchem-1549	50	6	,	,	PUNCT
eurjchem-1549	50	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	50	8	,	,	PUNCT
eurjchem-1549	50	9	δ	δ	PROPN
eurjchem-1549	50	10	,	,	PUNCT
eurjchem-1549	50	11	ppm	ppm	NUM
eurjchem-1549	50	12	):	):	PUNCT
eurjchem-1549	50	13	1.45	1.45	NUM
eurjchem-1549	50	14	(	(	PUNCT
eurjchem-1549	50	15	t	t	PROPN
eurjchem-1549	50	16	,	,	PUNCT
eurjchem-1549	50	17	3h	3h	NUM
eurjchem-1549	50	18	,	,	PUNCT
eurjchem-1549	50	19	j	j	PROPN
eurjchem-1549	50	20	=	=	SYM
eurjchem-1549	50	21	7.6	7.6	NUM
eurjchem-1549	50	22	hz	hz	NOUN
eurjchem-1549	50	23	,	,	PUNCT
eurjchem-1549	50	24	nch2ch3	nch2ch3	ADJ
eurjchem-1549	50	25	)	)	PUNCT
eurjchem-1549	50	26	,	,	PUNCT
eurjchem-1549	50	27	3.38‐3.42	3.38‐3.42	NUM
eurjchem-1549	50	28	(	(	PUNCT
eurjchem-1549	50	29	m	m	PROPN
eurjchem-1549	50	30	,	,	PUNCT
eurjchem-1549	50	31	4h	4h	NOUN
eurjchem-1549	50	32	,	,	PUNCT
eurjchem-1549	50	33	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	50	34	)	)	PUNCT
eurjchem-1549	50	35	,	,	PUNCT
eurjchem-1549	50	36	3.70‐3.74	3.70‐3.74	NUM
eurjchem-1549	50	37	(	(	PUNCT
eurjchem-1549	50	38	m	m	PROPN
eurjchem-1549	50	39	,	,	PUNCT
eurjchem-1549	50	40	4h	4h	NOUN
eurjchem-1549	50	41	,	,	PUNCT
eurjchem-1549	50	42	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	50	43	)	)	PUNCT
eurjchem-1549	50	44	,	,	PUNCT
eurjchem-1549	50	45	4.20	4.20	NUM
eurjchem-1549	50	46	(	(	PUNCT
eurjchem-1549	50	47	s	s	PROPN
eurjchem-1549	50	48	,	,	PUNCT
eurjchem-1549	50	49	2h	2h	NUM
eurjchem-1549	50	50	,	,	PUNCT
eurjchem-1549	50	51	brch2	brch2	PROPN
eurjchem-1549	50	52	)	)	PUNCT
eurjchem-1549	50	53	,	,	PUNCT
eurjchem-1549	50	54	4.59	4.59	NUM
eurjchem-1549	50	55	(	(	PUNCT
eurjchem-1549	50	56	q	q	NOUN
eurjchem-1549	50	57	,	,	PUNCT
eurjchem-1549	50	58	2h	2h	NUM
eurjchem-1549	50	59	,	,	PUNCT
eurjchem-1549	50	60	j	j	PROPN
eurjchem-1549	50	61	=	=	SYM
eurjchem-1549	50	62	7.6	7.6	NUM
eurjchem-1549	50	63	hz	hz	VERB
eurjchem-1549	50	64	,	,	PUNCT
eurjchem-1549	50	65	nch‐	nch‐	PROPN
eurjchem-1549	50	66	2ch3	2ch3	NUM
eurjchem-1549	50	67	)	)	PUNCT
eurjchem-1549	50	68	,	,	PUNCT
eurjchem-1549	50	69	7.22	7.22	NUM
eurjchem-1549	50	70	(	(	PUNCT
eurjchem-1549	50	71	d	d	PROPN
eurjchem-1549	50	72	,	,	PUNCT
eurjchem-1549	50	73	1h	1h	NUM
eurjchem-1549	50	74	,	,	PUNCT
eurjchem-1549	50	75	jh‐f	jh‐f	PROPN
eurjchem-1549	50	76	=	=	SYM
eurjchem-1549	50	77	7.6	7.6	NUM
eurjchem-1549	50	78	hz	hz	NOUN
eurjchem-1549	50	79	,	,	PUNCT
eurjchem-1549	50	80	h8	h8	PROPN
eurjchem-1549	50	81	)	)	PUNCT
eurjchem-1549	50	82	,	,	PUNCT
eurjchem-1549	50	83	7.96	7.96	NUM
eurjchem-1549	50	84	(	(	PUNCT
eurjchem-1549	50	85	d	d	PROPN
eurjchem-1549	50	86	,	,	PUNCT
eurjchem-1549	50	87	1h	1h	NUM
eurjchem-1549	50	88	,	,	PUNCT
eurjchem-1549	50	89	jh‐f	jh‐f	PROPN
eurjchem-1549	50	90	=	=	SYM
eurjchem-1549	50	91	13.6	13.6	NUM
eurjchem-1549	50	92	hz	hz	NOUN
eurjchem-1549	50	93	,	,	PUNCT
eurjchem-1549	50	94	h5	h5	PROPN
eurjchem-1549	50	95	)	)	PUNCT
eurjchem-1549	50	96	,	,	PUNCT
eurjchem-1549	50	97	8.94	8.94	NUM
eurjchem-1549	50	98	(	(	PUNCT
eurjchem-1549	50	99	s	s	PROPN
eurjchem-1549	50	100	,	,	PUNCT
eurjchem-1549	50	101	1h	1h	NUM
eurjchem-1549	50	102	,	,	PUNCT
eurjchem-1549	50	103	h2	h2	NOUN
eurjchem-1549	50	104	)	)	PUNCT
eurjchem-1549	50	105	,	,	PUNCT
eurjchem-1549	50	106	15.22	15.22	NUM
eurjchem-1549	50	107	(	(	PUNCT
eurjchem-1549	50	108	s	s	PROPN
eurjchem-1549	50	109	,	,	PUNCT
eurjchem-1549	50	110	1h	1h	NUM
eurjchem-1549	50	111	,	,	PUNCT
eurjchem-1549	50	112	cooh	cooh	NOUN
eurjchem-1549	50	113	)	)	PUNCT
eurjchem-1549	50	114	.	.	PUNCT
eurjchem-1549	51	1	13c	13c	NOUN
eurjchem-1549	51	2	nmr	nmr	NOUN
eurjchem-1549	51	3	(	(	PUNCT
eurjchem-1549	51	4	100	100	NUM
eurjchem-1549	51	5	mhz	mhz	NOUN
eurjchem-1549	51	6	,	,	PUNCT
eurjchem-1549	51	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	51	8	,	,	PUNCT
eurjchem-1549	51	9	δ	δ	PROPN
eurjchem-1549	51	10	,	,	PUNCT
eurjchem-1549	51	11	ppm	ppm	NOUN
eurjchem-1549	51	12	):	):	PUNCT
eurjchem-1549	51	13	14.86	14.86	NUM
eurjchem-1549	51	14	,	,	PUNCT
eurjchem-1549	51	15	28.29	28.29	NUM
eurjchem-1549	51	16	,	,	PUNCT
eurjchem-1549	51	17	41.76	41.76	NUM
eurjchem-1549	51	18	,	,	PUNCT
eurjchem-1549	51	19	46.11	46.11	NUM
eurjchem-1549	51	20	,	,	PUNCT
eurjchem-1549	51	21	49.56	49.56	NUM
eurjchem-1549	51	22	,	,	PUNCT
eurjchem-1549	51	23	106.86	106.86	NUM
eurjchem-1549	51	24	,	,	PUNCT
eurjchem-1549	51	25	107.58	107.58	NUM
eurjchem-1549	51	26	,	,	PUNCT
eurjchem-1549	51	27	111.73	111.73	NUM
eurjchem-1549	51	28	(	(	PUNCT
eurjchem-1549	51	29	d	d	NOUN
eurjchem-1549	51	30	,	,	PUNCT
eurjchem-1549	51	31	j	j	PROPN
eurjchem-1549	51	32	=	=	SYM
eurjchem-1549	51	33	23	23	NUM
eurjchem-1549	51	34	hz	hz	NOUN
eurjchem-1549	51	35	)	)	PUNCT
eurjchem-1549	51	36	,	,	PUNCT
eurjchem-1549	51	37	120.06	120.06	NUM
eurjchem-1549	51	38	(	(	PUNCT
eurjchem-1549	51	39	d	d	PROPN
eurjchem-1549	51	40	,	,	PUNCT
eurjchem-1549	51	41	j	j	PROPN
eurjchem-1549	51	42	=	=	SYM
eurjchem-1549	51	43	8	8	NUM
eurjchem-1549	51	44	hz	hz	NOUN
eurjchem-1549	51	45	)	)	PUNCT
eurjchem-1549	51	46	,	,	PUNCT
eurjchem-1549	51	47	137.62	137.62	NUM
eurjchem-1549	51	48	,	,	PUNCT
eurjchem-1549	51	49	145.56	145.56	NUM
eurjchem-1549	51	50	(	(	PUNCT
eurjchem-1549	51	51	d	d	PROPN
eurjchem-1549	51	52	,	,	PUNCT
eurjchem-1549	51	53	j	j	PROPN
eurjchem-1549	51	54	=	=	SYM
eurjchem-1549	51	55	11	11	NUM
eurjchem-1549	51	56	hz	hz	NOUN
eurjchem-1549	51	57	)	)	PUNCT
eurjchem-1549	51	58	,	,	PUNCT
eurjchem-1549	51	59	149.14	149.14	NUM
eurjchem-1549	51	60	,	,	PUNCT
eurjchem-1549	51	61	153.29	153.29	NUM
eurjchem-1549	51	62	(	(	PUNCT
eurjchem-1549	51	63	d	d	NOUN
eurjchem-1549	51	64	,	,	PUNCT
eurjchem-1549	51	65	j	j	PROPN
eurjchem-1549	51	66	=	=	SYM
eurjchem-1549	51	67	247	247	NUM
eurjchem-1549	51	68	hz	hz	NOUN
eurjchem-1549	51	69	)	)	PUNCT
eurjchem-1549	51	70	,	,	PUNCT
eurjchem-1549	51	71	165.49	165.49	NUM
eurjchem-1549	51	72	,	,	PUNCT
eurjchem-1549	51	73	166.57	166.57	NUM
eurjchem-1549	51	74	,	,	PUNCT
eurjchem-1549	51	75	176.67	176.67	NUM
eurjchem-1549	51	76	.	.	PUNCT
eurjchem-1549	51	77	anal	anal	ADJ
eurjchem-1549	51	78	.	.	PUNCT
eurjchem-1549	51	79	calcd	calcd	NOUN
eurjchem-1549	51	80	.	.	PUNCT
eurjchem-1549	52	1	for	for	ADP
eurjchem-1549	52	2	c18h19brfn3o4	c18h19brfn3o4	PROPN
eurjchem-1549	52	3	:	:	PUNCT
eurjchem-1549	52	4	c	c	NOUN
eurjchem-1549	52	5	,	,	PUNCT
eurjchem-1549	52	6	49.11	49.11	NUM
eurjchem-1549	52	7	;	;	PUNCT
eurjchem-1549	52	8	h	h	X
eurjchem-1549	52	9	,	,	PUNCT
eurjchem-1549	52	10	4.35	4.35	NUM
eurjchem-1549	52	11	;	;	PUNCT
eurjchem-1549	52	12	n	n	CCONJ
eurjchem-1549	52	13	,	,	PUNCT
eurjchem-1549	52	14	9.54	9.54	NUM
eurjchem-1549	52	15	.	.	PUNCT
eurjchem-1549	52	16	found	find	VERB
eurjchem-1549	52	17	:	:	PUNCT
eurjchem-1549	53	1	c	c	X
eurjchem-1549	53	2	,	,	PUNCT
eurjchem-1549	53	3	49.34	49.34	NUM
eurjchem-1549	53	4	;	;	PUNCT
eurjchem-1549	53	5	h	h	NOUN
eurjchem-1549	53	6	,	,	PUNCT
eurjchem-1549	53	7	4.31	4.31	NUM
eurjchem-1549	53	8	;	;	PUNCT
eurjchem-1549	53	9	n	n	CCONJ
eurjchem-1549	53	10	,	,	PUNCT
eurjchem-1549	53	11	9.78	9.78	NUM
eurjchem-1549	53	12	%	%	NOUN
eurjchem-1549	53	13	.	.	PUNCT
eurjchem-1549	54	1	2.2.2	2.2.2	X
eurjchem-1549	54	2	.	.	X
eurjchem-1549	55	1	synthesis	synthesis	NOUN
eurjchem-1549	55	2	of	of	ADP
eurjchem-1549	55	3	1‐ethyl‐6‐fluoro‐7‐((4‐(2‐nitrooxy)acetyl	1‐ethyl‐6‐fluoro‐7‐((4‐(2‐nitrooxy)acetyl	NUM
eurjchem-1549	55	4	)	)	PUNCT
eurjchem-1549	55	5	piperazin‐1‐yl)‐4‐oxo‐1,4‐dihydroquinoline‐3‐carboxylic	piperazin‐1‐yl)‐4‐oxo‐1,4‐dihydroquinoline‐3‐carboxylic	PROPN
eurjchem-1549	55	6	acid	acid	NOUN
eurjchem-1549	55	7	(	(	PUNCT
eurjchem-1549	55	8	3	3	NUM
eurjchem-1549	55	9	)	)	PUNCT
eurjchem-1549	55	10	to	to	ADP
eurjchem-1549	55	11	a	a	DET
eurjchem-1549	55	12	stirred	stir	VERB
eurjchem-1549	55	13	solution	solution	NOUN
eurjchem-1549	55	14	of	of	ADP
eurjchem-1549	55	15	bromide	bromide	NOUN
eurjchem-1549	55	16	2	2	NUM
eurjchem-1549	55	17	(	(	PUNCT
eurjchem-1549	55	18	0.44	0.44	NUM
eurjchem-1549	55	19	g	g	NOUN
eurjchem-1549	55	20	,	,	PUNCT
eurjchem-1549	55	21	1.0	1.0	NUM
eurjchem-1549	55	22	mmol	mmol	NOUN
eurjchem-1549	55	23	)	)	PUNCT
eurjchem-1549	55	24	in	in	ADP
eurjchem-1549	55	25	acetonitrile	acetonitrile	NOUN
eurjchem-1549	55	26	(	(	PUNCT
eurjchem-1549	55	27	10	10	NUM
eurjchem-1549	55	28	ml	ml	NOUN
eurjchem-1549	55	29	)	)	PUNCT
eurjchem-1549	55	30	,	,	PUNCT
eurjchem-1549	55	31	sliver	sliver	NOUN
eurjchem-1549	55	32	nitrate	nitrate	NOUN
eurjchem-1549	55	33	(	(	PUNCT
eurjchem-1549	55	34	4	4	NUM
eurjchem-1549	55	35	mmol	mmol	NOUN
eurjchem-1549	55	36	)	)	PUNCT
eurjchem-1549	55	37	in	in	ADP
eurjchem-1549	55	38	acetonitrile	acetonitrile	NOUN
eurjchem-1549	55	39	(	(	PUNCT
eurjchem-1549	55	40	10	10	NUM
eurjchem-1549	55	41	ml	ml	NOUN
eurjchem-1549	55	42	)	)	PUNCT
eurjchem-1549	55	43	was	be	AUX
eurjchem-1549	55	44	added	add	VERB
eurjchem-1549	55	45	portion	portion	NOUN
eurjchem-1549	55	46	wise	wise	ADJ
eurjchem-1549	55	47	and	and	CCONJ
eurjchem-1549	55	48	the	the	DET
eurjchem-1549	55	49	mixture	mixture	NOUN
eurjchem-1549	55	50	was	be	AUX
eurjchem-1549	55	51	heated	heat	VERB
eurjchem-1549	55	52	for	for	ADP
eurjchem-1549	55	53	16	16	NUM
eurjchem-1549	55	54	h	h	NOUN
eurjchem-1549	55	55	at	at	ADP
eurjchem-1549	55	56	80	80	NUM
eurjchem-1549	55	57	°	°	NOUN
eurjchem-1549	55	58	c	c	NOUN
eurjchem-1549	55	59	.	.	PUNCT
eurjchem-1549	56	1	the	the	DET
eurjchem-1549	56	2	formed	form	VERB
eurjchem-1549	56	3	precipitate	precipitate	NOUN
eurjchem-1549	56	4	of	of	ADP
eurjchem-1549	56	5	silver	silver	ADJ
eurjchem-1549	56	6	bromide	bromide	NOUN
eurjchem-1549	56	7	was	be	AUX
eurjchem-1549	56	8	filtered	filter	VERB
eurjchem-1549	56	9	off	off	ADP
eurjchem-1549	56	10	,	,	PUNCT
eurjchem-1549	56	11	and	and	CCONJ
eurjchem-1549	56	12	the	the	DET
eurjchem-1549	56	13	filtrate	filtrate	NOUN
eurjchem-1549	56	14	was	be	AUX
eurjchem-1549	56	15	evaporated	evaporate	VERB
eurjchem-1549	56	16	till	till	SCONJ
eurjchem-1549	56	17	dryness	dryness	NOUN
eurjchem-1549	56	18	,	,	PUNCT
eurjchem-1549	56	19	dissolved	dissolve	VERB
eurjchem-1549	56	20	in	in	ADP
eurjchem-1549	56	21	dichloromethane	dichloromethane	NOUN
eurjchem-1549	56	22	(	(	PUNCT
eurjchem-1549	56	23	30	30	NUM
eurjchem-1549	56	24	ml	ml	NOUN
eurjchem-1549	56	25	)	)	PUNCT
eurjchem-1549	56	26	and	and	CCONJ
eurjchem-1549	56	27	washed	wash	VERB
eurjchem-1549	56	28	with	with	ADP
eurjchem-1549	56	29	distilled	distil	VERB
eurjchem-1549	56	30	water	water	NOUN
eurjchem-1549	56	31	(	(	PUNCT
eurjchem-1549	56	32	2×25	2×25	NUM
eurjchem-1549	56	33	ml	ml	NOUN
eurjchem-1549	56	34	)	)	PUNCT
eurjchem-1549	56	35	and	and	CCONJ
eurjchem-1549	56	36	brine	brine	NOUN
eurjchem-1549	56	37	(	(	PUNCT
eurjchem-1549	56	38	2×25	2×25	NUM
eurjchem-1549	56	39	ml	ml	NOUN
eurjchem-1549	56	40	)	)	PUNCT
eurjchem-1549	56	41	.	.	PUNCT
eurjchem-1549	57	1	the	the	DET
eurjchem-1549	57	2	organic	organic	ADJ
eurjchem-1549	57	3	layer	layer	NOUN
eurjchem-1549	57	4	was	be	AUX
eurjchem-1549	57	5	dried	dry	VERB
eurjchem-1549	57	6	over	over	ADP
eurjchem-1549	57	7	anhydrous	anhydrous	ADJ
eurjchem-1549	57	8	sodium	sodium	NOUN
eurjchem-1549	57	9	sulfate	sulfate	NOUN
eurjchem-1549	57	10	,	,	PUNCT
eurjchem-1549	57	11	filtered	filter	VERB
eurjchem-1549	57	12	and	and	CCONJ
eurjchem-1549	57	13	concentrated	concentrate	VERB
eurjchem-1549	57	14	under	under	ADP
eurjchem-1549	57	15	reduced	reduced	ADJ
eurjchem-1549	57	16	pressure	pressure	NOUN
eurjchem-1549	57	17	.	.	PUNCT
eurjchem-1549	58	1	the	the	DET
eurjchem-1549	58	2	residue	residue	NOUN
eurjchem-1549	58	3	was	be	AUX
eurjchem-1549	58	4	crystallized	crystallize	VERB
eurjchem-1549	58	5	from	from	ADP
eurjchem-1549	58	6	acetonitrile	acetonitrile	NOUN
eurjchem-1549	58	7	to	to	PART
eurjchem-1549	58	8	give	give	VERB
eurjchem-1549	58	9	nitrate	nitrate	NOUN
eurjchem-1549	58	10	ester	ester	NOUN
eurjchem-1549	58	11	3	3	NUM
eurjchem-1549	58	12	(	(	PUNCT
eurjchem-1549	58	13	scheme	scheme	NOUN
eurjchem-1549	58	14	1	1	NUM
eurjchem-1549	58	15	)	)	PUNCT
eurjchem-1549	58	16	.	.	PUNCT
eurjchem-1549	59	1	color	color	NOUN
eurjchem-1549	59	2	:	:	PUNCT
eurjchem-1549	59	3	yellow	yellow	ADJ
eurjchem-1549	59	4	crystals	crystal	NOUN
eurjchem-1549	59	5	.	.	PUNCT
eurjchem-1549	60	1	yield	yield	NOUN
eurjchem-1549	60	2	:	:	PUNCT
eurjchem-1549	60	3	0.177	0.177	NUM
eurjchem-1549	60	4	g	g	NOUN
eurjchem-1549	60	5	(	(	PUNCT
eurjchem-1549	60	6	41.9	41.9	NUM
eurjchem-1549	60	7	%	%	NOUN
eurjchem-1549	60	8	)	)	PUNCT
eurjchem-1549	60	9	.	.	PUNCT
eurjchem-1549	61	1	m.p	m.p	PROPN
eurjchem-1549	61	2	.	.	PROPN
eurjchem-1549	61	3	:	:	PUNCT
eurjchem-1549	62	1	201‐	201‐	ADV
eurjchem-1549	62	2	203	203	NUM
eurjchem-1549	62	3	°	°	NOUN
eurjchem-1549	62	4	c	c	X
eurjchem-1549	62	5	.	.	PUNCT
eurjchem-1549	63	1	ft‐ir	ft‐ir	NOUN
eurjchem-1549	63	2	(	(	PUNCT
eurjchem-1549	63	3	kbr	kbr	PROPN
eurjchem-1549	63	4	,	,	PUNCT
eurjchem-1549	63	5	ν	ν	PROPN
eurjchem-1549	63	6	,	,	PUNCT
eurjchem-1549	63	7	cm‐1	cm‐1	PROPN
eurjchem-1549	63	8	):	):	PUNCT
eurjchem-1549	63	9	1715	1715	NUM
eurjchem-1549	63	10	(	(	PUNCT
eurjchem-1549	63	11	carboxylic	carboxylic	ADJ
eurjchem-1549	63	12	c	c	NOUN
eurjchem-1549	63	13	=	=	NOUN
eurjchem-1549	63	14	o	o	NOUN
eurjchem-1549	63	15	)	)	PUNCT
eurjchem-1549	63	16	,	,	PUNCT
eurjchem-1549	63	17	1668	1668	NUM
eurjchem-1549	63	18	(	(	PUNCT
eurjchem-1549	63	19	amidic	amidic	PROPN
eurjchem-1549	63	20	c	c	PROPN
eurjchem-1549	63	21	=	=	NOUN
eurjchem-1549	63	22	o	o	NOUN
eurjchem-1549	63	23	)	)	PUNCT
eurjchem-1549	63	24	,	,	PUNCT
eurjchem-1549	63	25	1623	1623	NUM
eurjchem-1549	63	26	(	(	PUNCT
eurjchem-1549	63	27	4‐keto	4‐keto	NOUN
eurjchem-1549	63	28	c	c	NOUN
eurjchem-1549	63	29	=	=	NOUN
eurjchem-1549	63	30	o	o	NOUN
eurjchem-1549	63	31	)	)	PUNCT
eurjchem-1549	63	32	.	.	PUNCT
eurjchem-1549	64	1	1h	1h	NUM
eurjchem-1549	64	2	nmr	nmr	NOUN
eurjchem-1549	64	3	(	(	PUNCT
eurjchem-1549	64	4	400	400	NUM
eurjchem-1549	64	5	mhz	mhz	NOUN
eurjchem-1549	64	6	,	,	PUNCT
eurjchem-1549	64	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	64	8	,	,	PUNCT
eurjchem-1549	64	9	δ	δ	PROPN
eurjchem-1549	64	10	,	,	PUNCT
eurjchem-1549	64	11	ppm	ppm	NUM
eurjchem-1549	64	12	):	):	PUNCT
eurjchem-1549	64	13	1.45	1.45	NUM
eurjchem-1549	64	14	(	(	PUNCT
eurjchem-1549	64	15	t	t	PROPN
eurjchem-1549	64	16	,	,	PUNCT
eurjchem-1549	64	17	3h	3h	NUM
eurjchem-1549	64	18	,	,	PUNCT
eurjchem-1549	64	19	j	j	PROPN
eurjchem-1549	64	20	=	=	SYM
eurjchem-1549	64	21	7.6	7.6	NUM
eurjchem-1549	64	22	hz	hz	NOUN
eurjchem-1549	64	23	,	,	PUNCT
eurjchem-1549	64	24	ch2ch3	ch2ch3	ADJ
eurjchem-1549	64	25	)	)	PUNCT
eurjchem-1549	64	26	,	,	PUNCT
eurjchem-1549	64	27	3.35‐3.45	3.35‐3.45	NUM
eurjchem-1549	64	28	(	(	PUNCT
eurjchem-1549	64	29	m	m	PROPN
eurjchem-1549	64	30	,	,	PUNCT
eurjchem-1549	64	31	4h	4h	NOUN
eurjchem-1549	64	32	,	,	PUNCT
eurjchem-1549	64	33	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	64	34	)	)	PUNCT
eurjchem-1549	64	35	,	,	PUNCT
eurjchem-1549	64	36	3.61‐3.71	3.61‐3.71	NUM
eurjchem-1549	64	37	(	(	PUNCT
eurjchem-1549	64	38	m	m	PROPN
eurjchem-1549	64	39	,	,	PUNCT
eurjchem-1549	64	40	4h	4h	NOUN
eurjchem-1549	64	41	,	,	PUNCT
eurjchem-1549	64	42	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	64	43	)	)	PUNCT
eurjchem-1549	64	44	,	,	PUNCT
eurjchem-1549	64	45	4.59	4.59	NUM
eurjchem-1549	64	46	(	(	PUNCT
eurjchem-1549	64	47	q	q	NOUN
eurjchem-1549	64	48	,	,	PUNCT
eurjchem-1549	64	49	2h	2h	NUM
eurjchem-1549	64	50	,	,	PUNCT
eurjchem-1549	64	51	j	j	PROPN
eurjchem-1549	64	52	=	=	SYM
eurjchem-1549	64	53	7.6	7.6	NUM
eurjchem-1549	64	54	hz	hz	NOUN
eurjchem-1549	64	55	,	,	PUNCT
eurjchem-1549	64	56	ch2ch3	ch2ch3	ADJ
eurjchem-1549	64	57	)	)	PUNCT
eurjchem-1549	64	58	,	,	PUNCT
eurjchem-1549	64	59	5.46	5.46	NUM
eurjchem-1549	64	60	(	(	PUNCT
eurjchem-1549	64	61	s	s	PROPN
eurjchem-1549	64	62	,	,	PUNCT
eurjchem-1549	64	63	2h	2h	NUM
eurjchem-1549	64	64	,	,	PUNCT
eurjchem-1549	64	65	ch2ono2	ch2ono2	PROPN
eurjchem-1549	64	66	)	)	PUNCT
eurjchem-1549	64	67	,	,	PUNCT
eurjchem-1549	64	68	7.22	7.22	NUM
eurjchem-1549	64	69	(	(	PUNCT
eurjchem-1549	64	70	d	d	PROPN
eurjchem-1549	64	71	,	,	PUNCT
eurjchem-1549	64	72	1h	1h	NUM
eurjchem-1549	64	73	,	,	PUNCT
eurjchem-1549	64	74	jh‐f	jh‐f	PROPN
eurjchem-1549	64	75	=	=	SYM
eurjchem-1549	65	1	6.8	6.8	NUM
eurjchem-1549	65	2	hz	hz	NOUN
eurjchem-1549	65	3	,	,	PUNCT
eurjchem-1549	65	4	h8	h8	PROPN
eurjchem-1549	65	5	)	)	PUNCT
eurjchem-1549	65	6	,	,	PUNCT
eurjchem-1549	65	7	7.96	7.96	NUM
eurjchem-1549	65	8	(	(	PUNCT
eurjchem-1549	65	9	d	d	PROPN
eurjchem-1549	65	10	,	,	PUNCT
eurjchem-1549	65	11	1h	1h	NUM
eurjchem-1549	65	12	,	,	PUNCT
eurjchem-1549	65	13	jh‐f	jh‐f	PROPN
eurjchem-1549	65	14	=	=	SYM
eurjchem-1549	65	15	13.6	13.6	NUM
eurjchem-1549	65	16	hz	hz	NOUN
eurjchem-1549	65	17	,	,	PUNCT
eurjchem-1549	65	18	h5	h5	PROPN
eurjchem-1549	65	19	)	)	PUNCT
eurjchem-1549	65	20	,	,	PUNCT
eurjchem-1549	65	21	8.94	8.94	NUM
eurjchem-1549	65	22	(	(	PUNCT
eurjchem-1549	65	23	s	s	PROPN
eurjchem-1549	65	24	,	,	PUNCT
eurjchem-1549	65	25	1h	1h	NUM
eurjchem-1549	65	26	,	,	PUNCT
eurjchem-1549	65	27	h2	h2	PROPN
eurjchem-1549	65	28	)	)	PUNCT
eurjchem-1549	65	29	,	,	PUNCT
eurjchem-1549	65	30	15.23	15.23	NUM
eurjchem-1549	65	31	(	(	PUNCT
eurjchem-1549	65	32	s	s	PROPN
eurjchem-1549	65	33	,	,	PUNCT
eurjchem-1549	65	34	1h	1h	NUM
eurjchem-1549	65	35	,	,	PUNCT
eurjchem-1549	65	36	cooh	cooh	NOUN
eurjchem-1549	65	37	)	)	PUNCT
eurjchem-1549	65	38	.	.	PUNCT
eurjchem-1549	66	1	13c	13c	NOUN
eurjchem-1549	66	2	nmr	nmr	NOUN
eurjchem-1549	66	3	(	(	PUNCT
eurjchem-1549	66	4	100	100	NUM
eurjchem-1549	66	5	mhz	mhz	NOUN
eurjchem-1549	66	6	,	,	PUNCT
eurjchem-1549	66	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	66	8	,	,	PUNCT
eurjchem-1549	66	9	δ	δ	PROPN
eurjchem-1549	66	10	,	,	PUNCT
eurjchem-1549	66	11	ppm	ppm	NOUN
eurjchem-1549	66	12	):	):	PUNCT
eurjchem-1549	66	13	14.76	14.76	NUM
eurjchem-1549	66	14	,	,	PUNCT
eurjchem-1549	66	15	41.61	41.61	NUM
eurjchem-1549	66	16	,	,	PUNCT
eurjchem-1549	66	17	44.00	44.00	NUM
eurjchem-1549	66	18	,	,	PUNCT
eurjchem-1549	66	19	49.54	49.54	NUM
eurjchem-1549	66	20	,	,	PUNCT
eurjchem-1549	66	21	50.03	50.03	NUM
eurjchem-1549	66	22	,	,	PUNCT
eurjchem-1549	66	23	69.32	69.32	NUM
eurjchem-1549	66	24	,	,	PUNCT
eurjchem-1549	66	25	106.70	106.70	NUM
eurjchem-1549	66	26	,	,	PUNCT
eurjchem-1549	66	27	107.76	107.76	NUM
eurjchem-1549	66	28	,	,	PUNCT
eurjchem-1549	66	29	111.79	111.79	NUM
eurjchem-1549	66	30	(	(	PUNCT
eurjchem-1549	66	31	d	d	PROPN
eurjchem-1549	66	32	,	,	PUNCT
eurjchem-1549	66	33	j	j	PROPN
eurjchem-1549	66	34	=	=	SYM
eurjchem-1549	66	35	23	23	NUM
eurjchem-1549	66	36	hz	hz	NOUN
eurjchem-1549	66	37	)	)	PUNCT
eurjchem-1549	66	38	,	,	PUNCT
eurjchem-1549	66	39	120.09	120.09	NUM
eurjchem-1549	66	40	,	,	PUNCT
eurjchem-1549	66	41	137.70	137.70	NUM
eurjchem-1549	66	42	,	,	PUNCT
eurjchem-1549	66	43	145.54	145.54	NUM
eurjchem-1549	66	44	,	,	PUNCT
eurjchem-1549	66	45	148.98	148.98	NUM
eurjchem-1549	66	46	,	,	PUNCT
eurjchem-1549	66	47	153.29	153.29	NUM
eurjchem-1549	66	48	(	(	PUNCT
eurjchem-1549	66	49	d	d	NOUN
eurjchem-1549	66	50	,	,	PUNCT
eurjchem-1549	66	51	j	j	PROPN
eurjchem-1549	66	52	=	=	PROPN
eurjchem-1549	66	53	248	248	NUM
eurjchem-1549	66	54	hz	hz	NOUN
eurjchem-1549	66	55	)	)	PUNCT
eurjchem-1549	66	56	,	,	PUNCT
eurjchem-1549	66	57	163.97	163.97	NUM
eurjchem-1549	66	58	,	,	PUNCT
eurjchem-1549	66	59	166.44	166.44	NUM
eurjchem-1549	66	60	,	,	PUNCT
eurjchem-1549	66	61	167.71	167.71	NUM
eurjchem-1549	66	62	.	.	PUNCT
eurjchem-1549	67	1	hrms	hrm	NOUN
eurjchem-1549	67	2	(	(	PUNCT
eurjchem-1549	67	3	esi	esi	PROPN
eurjchem-1549	67	4	,	,	PUNCT
eurjchem-1549	67	5	m	m	PROPN
eurjchem-1549	67	6	/	/	SYM
eurjchem-1549	67	7	z	z	ADJ
eurjchem-1549	67	8	)	)	PUNCT
eurjchem-1549	67	9	calcd	calcd	NOUN
eurjchem-1549	67	10	.	.	PUNCT
eurjchem-1549	68	1	for	for	ADP
eurjchem-1549	68	2	c18h18fn4o7	c18h18fn4o7	PROPN
eurjchem-1549	68	3	[	[	X
eurjchem-1549	68	4	m‐h]¯	m‐h]¯	NOUN
eurjchem-1549	68	5	:	:	PUNCT
eurjchem-1549	68	6	421.11650	421.11650	NUM
eurjchem-1549	68	7	,	,	PUNCT
eurjchem-1549	68	8	found	find	VERB
eurjchem-1549	68	9	:	:	PUNCT
eurjchem-1549	68	10	421.11700	421.11700	NUM
eurjchem-1549	68	11	.	.	X
eurjchem-1549	69	1	2.2.3	2.2.3	NUM
eurjchem-1549	69	2	.	.	X
eurjchem-1549	70	1	synthesis	synthesis	NOUN
eurjchem-1549	70	2	of	of	ADP
eurjchem-1549	70	3	n‐(4‐acetylphenyl)‐3‐bromopropan	n‐(4‐acetylphenyl)‐3‐bromopropan	NOUN
eurjchem-1549	70	4	amide	amide	NOUN
eurjchem-1549	70	5	(	(	PUNCT
eurjchem-1549	70	6	5	5	NUM
eurjchem-1549	70	7	)	)	PUNCT
eurjchem-1549	70	8	to	to	ADP
eurjchem-1549	70	9	a	a	DET
eurjchem-1549	70	10	stirred	stir	VERB
eurjchem-1549	70	11	solution	solution	NOUN
eurjchem-1549	70	12	of	of	ADP
eurjchem-1549	70	13	p‐aminoacetophenone	p‐aminoacetophenone	X
eurjchem-1549	70	14	(	(	PUNCT
eurjchem-1549	70	15	4	4	NUM
eurjchem-1549	70	16	)	)	PUNCT
eurjchem-1549	70	17	(	(	PUNCT
eurjchem-1549	70	18	0.675	0.675	NUM
eurjchem-1549	70	19	g	g	NOUN
eurjchem-1549	70	20	,	,	PUNCT
eurjchem-1549	70	21	5.0	5.0	NUM
eurjchem-1549	70	22	mmol	mmol	NOUN
eurjchem-1549	70	23	)	)	PUNCT
eurjchem-1549	70	24	in	in	ADP
eurjchem-1549	70	25	dichloromethane	dichloromethane	NOUN
eurjchem-1549	70	26	(	(	PUNCT
eurjchem-1549	70	27	30	30	NUM
eurjchem-1549	70	28	ml	ml	NOUN
eurjchem-1549	70	29	)	)	PUNCT
eurjchem-1549	70	30	was	be	AUX
eurjchem-1549	70	31	added	add	VERB
eurjchem-1549	70	32	a	a	DET
eurjchem-1549	70	33	solution	solution	NOUN
eurjchem-1549	70	34	of	of	ADP
eurjchem-1549	70	35	potassium	potassium	NOUN
eurjchem-1549	70	36	carbonate	carbonate	NOUN
eurjchem-1549	70	37	(	(	PUNCT
eurjchem-1549	70	38	0.76	0.76	NUM
eurjchem-1549	70	39	g	g	NOUN
eurjchem-1549	70	40	,	,	PUNCT
eurjchem-1549	70	41	5.5	5.5	NUM
eurjchem-1549	70	42	mmol	mmol	NOUN
eurjchem-1549	70	43	)	)	PUNCT
eurjchem-1549	70	44	in	in	ADP
eurjchem-1549	70	45	water	water	NOUN
eurjchem-1549	70	46	(	(	PUNCT
eurjchem-1549	70	47	30	30	NUM
eurjchem-1549	70	48	ml	ml	NOUN
eurjchem-1549	70	49	)	)	PUNCT
eurjchem-1549	70	50	at	at	ADP
eurjchem-1549	70	51	0‐5	0‐5	NOUN
eurjchem-1549	70	52	°	°	ADP
eurjchem-1549	70	53	c	c	X
eurjchem-1549	70	54	.	.	PUNCT
eurjchem-1549	71	1	then	then	ADV
eurjchem-1549	71	2	,	,	PUNCT
eurjchem-1549	71	3	3‐bromopropionyl	3‐bromopropionyl	NUM
eurjchem-1549	71	4	chloride	chloride	NOUN
eurjchem-1549	71	5	(	(	PUNCT
eurjchem-1549	71	6	0.94	0.94	NUM
eurjchem-1549	71	7	g	g	NOUN
eurjchem-1549	71	8	,	,	PUNCT
eurjchem-1549	71	9	5.5	5.5	NUM
eurjchem-1549	71	10	mmol	mmol	NOUN
eurjchem-1549	71	11	)	)	PUNCT
eurjchem-1549	71	12	in	in	ADP
eurjchem-1549	71	13	dichloromethane	dichloromethane	NOUN
eurjchem-1549	71	14	(	(	PUNCT
eurjchem-1549	71	15	30	30	NUM
eurjchem-1549	71	16	ml	ml	NOUN
eurjchem-1549	71	17	)	)	PUNCT
eurjchem-1549	71	18	was	be	AUX
eurjchem-1549	71	19	slowly	slowly	ADV
eurjchem-1549	71	20	added	add	VERB
eurjchem-1549	71	21	over	over	ADP
eurjchem-1549	71	22	a	a	DET
eurjchem-1549	71	23	period	period	NOUN
eurjchem-1549	71	24	of	of	ADP
eurjchem-1549	71	25	30	30	NUM
eurjchem-1549	71	26	min	min	NOUN
eurjchem-1549	71	27	.	.	NOUN
eurjchem-1549	71	28	stirring	stirring	NOUN
eurjchem-1549	71	29	was	be	AUX
eurjchem-1549	71	30	continued	continue	VERB
eurjchem-1549	71	31	for	for	ADP
eurjchem-1549	71	32	2	2	NUM
eurjchem-1549	71	33	h	h	NOUN
eurjchem-1549	71	34	at	at	ADP
eurjchem-1549	71	35	0‐5	0‐5	NOUN
eurjchem-1549	71	36	°	°	SCONJ
eurjchem-1549	71	37	c	c	NOUN
eurjchem-1549	71	38	,	,	PUNCT
eurjchem-1549	71	39	then	then	ADV
eurjchem-1549	71	40	at	at	ADP
eurjchem-1549	71	41	room	room	NOUN
eurjchem-1549	71	42	temperature	temperature	NOUN
eurjchem-1549	71	43	for	for	ADP
eurjchem-1549	71	44	additional	additional	ADJ
eurjchem-1549	71	45	12	12	NUM
eurjchem-1549	71	46	h.	h.	NOUN
eurjchem-1549	71	47	the	the	DET
eurjchem-1549	71	48	whole	whole	ADJ
eurjchem-1549	71	49	mixture	mixture	NOUN
eurjchem-1549	71	50	was	be	AUX
eurjchem-1549	71	51	then	then	ADV
eurjchem-1549	71	52	transferred	transfer	VERB
eurjchem-1549	71	53	to	to	ADP
eurjchem-1549	71	54	a	a	DET
eurjchem-1549	71	55	separatory	separatory	ADJ
eurjchem-1549	71	56	funnel	funnel	NOUN
eurjchem-1549	71	57	where	where	SCONJ
eurjchem-1549	71	58	it	it	PRON
eurjchem-1549	71	59	was	be	AUX
eurjchem-1549	71	60	extracted	extract	VERB
eurjchem-1549	71	61	with	with	ADP
eurjchem-1549	71	62	dichloromethane	dichloromethane	NOUN
eurjchem-1549	71	63	and	and	CCONJ
eurjchem-1549	71	64	washed	wash	VERB
eurjchem-1549	71	65	with	with	ADP
eurjchem-1549	71	66	water	water	NOUN
eurjchem-1549	71	67	(	(	PUNCT
eurjchem-1549	71	68	2×25	2×25	NUM
eurjchem-1549	71	69	ml	ml	NOUN
eurjchem-1549	71	70	)	)	PUNCT
eurjchem-1549	71	71	.	.	PUNCT
eurjchem-1549	72	1	the	the	DET
eurjchem-1549	72	2	organic	organic	ADJ
eurjchem-1549	72	3	layer	layer	NOUN
eurjchem-1549	72	4	was	be	AUX
eurjchem-1549	72	5	separated	separate	VERB
eurjchem-1549	72	6	,	,	PUNCT
eurjchem-1549	72	7	dried	dry	VERB
eurjchem-1549	72	8	over	over	ADP
eurjchem-1549	72	9	anhydrous	anhydrous	ADJ
eurjchem-1549	72	10	sodium	sodium	NOUN
eurjchem-1549	72	11	sulphate	sulphate	NOUN
eurjchem-1549	72	12	,	,	PUNCT
eurjchem-1549	72	13	filtered	filter	VERB
eurjchem-1549	72	14	and	and	CCONJ
eurjchem-1549	72	15	evaporated	evaporate	VERB
eurjchem-1549	72	16	under	under	ADP
eurjchem-1549	72	17	reduced	reduced	ADJ
eurjchem-1549	72	18	pressure	pressure	NOUN
eurjchem-1549	72	19	.	.	PUNCT
eurjchem-1549	73	1	the	the	DET
eurjchem-1549	73	2	residue	residue	NOUN
eurjchem-1549	73	3	was	be	AUX
eurjchem-1549	73	4	crystallized	crystallize	VERB
eurjchem-1549	73	5	from	from	ADP
eurjchem-1549	73	6	95	95	NUM
eurjchem-1549	73	7	%	%	NOUN
eurjchem-1549	73	8	ethanol	ethanol	NOUN
eurjchem-1549	73	9	to	to	PART
eurjchem-1549	73	10	give	give	VERB
eurjchem-1549	73	11	bromide	bromide	NOUN
eurjchem-1549	73	12	5	5	NUM
eurjchem-1549	73	13	in	in	ADP
eurjchem-1549	73	14	a	a	DET
eurjchem-1549	73	15	sufficiently	sufficiently	ADV
eurjchem-1549	73	16	pure	pure	ADJ
eurjchem-1549	73	17	form	form	NOUN
eurjchem-1549	73	18	suitable	suitable	ADJ
eurjchem-1549	73	19	for	for	ADP
eurjchem-1549	73	20	use	use	NOUN
eurjchem-1549	73	21	in	in	ADP
eurjchem-1549	73	22	the	the	DET
eurjchem-1549	73	23	next	next	ADJ
eurjchem-1549	73	24	reaction	reaction	NOUN
eurjchem-1549	73	25	without	without	ADP
eurjchem-1549	73	26	further	further	ADJ
eurjchem-1549	73	27	purification	purification	NOUN
eurjchem-1549	73	28	(	(	PUNCT
eurjchem-1549	73	29	scheme	scheme	NOUN
eurjchem-1549	73	30	1	1	NUM
eurjchem-1549	73	31	)	)	PUNCT
eurjchem-1549	73	32	.	.	PUNCT
eurjchem-1549	74	1	color	color	NOUN
eurjchem-1549	74	2	:	:	PUNCT
eurjchem-1549	74	3	white	white	ADJ
eurjchem-1549	74	4	crystals	crystal	NOUN
eurjchem-1549	74	5	.	.	PUNCT
eurjchem-1549	75	1	yield	yield	NOUN
eurjchem-1549	75	2	:	:	PUNCT
eurjchem-1549	75	3	1.25	1.25	NUM
eurjchem-1549	75	4	g	g	NOUN
eurjchem-1549	75	5	(	(	PUNCT
eurjchem-1549	75	6	93	93	NUM
eurjchem-1549	75	7	%	%	NOUN
eurjchem-1549	75	8	)	)	PUNCT
eurjchem-1549	75	9	.	.	PUNCT
eurjchem-1549	76	1	m.p	m.p	PROPN
eurjchem-1549	76	2	:	:	PUNCT
eurjchem-1549	76	3	175‐176	175‐176	PROPN
eurjchem-1549	76	4	°	°	PROPN
eurjchem-1549	76	5	c	c	X
eurjchem-1549	76	6	.	.	PUNCT
eurjchem-1549	77	1	ft‐ir	ft‐ir	NOUN
eurjchem-1549	77	2	(	(	PUNCT
eurjchem-1549	77	3	kbr	kbr	PROPN
eurjchem-1549	77	4	,	,	PUNCT
eurjchem-1549	77	5	ν	ν	PROPN
eurjchem-1549	77	6	,	,	PUNCT
eurjchem-1549	77	7	cm‐1	cm‐1	PROPN
eurjchem-1549	77	8	):	):	PUNCT
eurjchem-1549	77	9	3323	3323	NUM
eurjchem-1549	77	10	(	(	PUNCT
eurjchem-1549	77	11	nh	nh	NOUN
eurjchem-1549	77	12	)	)	PUNCT
eurjchem-1549	77	13	,	,	PUNCT
eurjchem-1549	77	14	1692	1692	NUM
eurjchem-1549	77	15	(	(	PUNCT
eurjchem-1549	77	16	nhcoch2	nhcoch2	NOUN
eurjchem-1549	77	17	)	)	PUNCT
eurjchem-1549	77	18	,	,	PUNCT
eurjchem-1549	77	19	1654	1654	NUM
eurjchem-1549	77	20	(	(	PUNCT
eurjchem-1549	77	21	coch3	coch3	NOUN
eurjchem-1549	77	22	)	)	PUNCT
eurjchem-1549	77	23	.	.	PUNCT
eurjchem-1549	78	1	1h	1h	NUM
eurjchem-1549	78	2	nmr	nmr	NOUN
eurjchem-1549	78	3	(	(	PUNCT
eurjchem-1549	78	4	400	400	NUM
eurjchem-1549	78	5	mhz	mhz	NOUN
eurjchem-1549	78	6	,	,	PUNCT
eurjchem-1549	78	7	cdcl3	cdcl3	PROPN
eurjchem-1549	78	8	,	,	PUNCT
eurjchem-1549	78	9	δ	δ	PROPN
eurjchem-1549	78	10	,	,	PUNCT
eurjchem-1549	78	11	ppm	ppm	NOUN
eurjchem-1549	78	12	):	):	PUNCT
eurjchem-1549	78	13	2.61	2.61	NUM
eurjchem-1549	78	14	(	(	PUNCT
eurjchem-1549	78	15	s	s	PROPN
eurjchem-1549	78	16	,	,	PUNCT
eurjchem-1549	78	17	3h	3h	NUM
eurjchem-1549	78	18	,	,	PUNCT
eurjchem-1549	78	19	coch3	coch3	NOUN
eurjchem-1549	78	20	)	)	PUNCT
eurjchem-1549	78	21	,	,	PUNCT
eurjchem-1549	78	22	3.00	3.00	NUM
eurjchem-1549	78	23	(	(	PUNCT
eurjchem-1549	78	24	t	t	PROPN
eurjchem-1549	78	25	,	,	PUNCT
eurjchem-1549	78	26	2h	2h	NUM
eurjchem-1549	78	27	,	,	PUNCT
eurjchem-1549	78	28	j	j	PROPN
eurjchem-1549	78	29	=	=	SYM
eurjchem-1549	78	30	8.0	8.0	NUM
eurjchem-1549	78	31	hz	hz	NOUN
eurjchem-1549	78	32	,	,	PUNCT
eurjchem-1549	78	33	ch2ch2br	ch2ch2br	PROPN
eurjchem-1549	78	34	)	)	PUNCT
eurjchem-1549	78	35	,	,	PUNCT
eurjchem-1549	78	36	3.73	3.73	NUM
eurjchem-1549	78	37	(	(	PUNCT
eurjchem-1549	78	38	t	t	PROPN
eurjchem-1549	78	39	,	,	PUNCT
eurjchem-1549	78	40	2h	2h	NUM
eurjchem-1549	78	41	,	,	PUNCT
eurjchem-1549	78	42	j	j	PROPN
eurjchem-1549	79	1	=	=	SYM
eurjchem-1549	79	2	8.0	8.0	NUM
eurjchem-1549	79	3	hz	hz	NOUN
eurjchem-1549	79	4	,	,	PUNCT
eurjchem-1549	79	5	ch2ch2br	ch2ch2br	PROPN
eurjchem-1549	79	6	)	)	PUNCT
eurjchem-1549	79	7	,	,	PUNCT
eurjchem-1549	79	8	7.64	7.64	NUM
eurjchem-1549	79	9	(	(	PUNCT
eurjchem-1549	79	10	d	d	PROPN
eurjchem-1549	79	11	,	,	PUNCT
eurjchem-1549	79	12	2h	2h	NUM
eurjchem-1549	79	13	,	,	PUNCT
eurjchem-1549	79	14	j	j	PROPN
eurjchem-1549	79	15	=	=	SYM
eurjchem-1549	79	16	8.8	8.8	NUM
eurjchem-1549	79	17	hz	hz	NOUN
eurjchem-1549	79	18	,	,	PUNCT
eurjchem-1549	79	19	ar‐h	ar‐h	PROPN
eurjchem-1549	79	20	)	)	PUNCT
eurjchem-1549	79	21	,	,	PUNCT
eurjchem-1549	79	22	7.96	7.96	NUM
eurjchem-1549	79	23	(	(	PUNCT
eurjchem-1549	79	24	d	d	PROPN
eurjchem-1549	79	25	,	,	PUNCT
eurjchem-1549	79	26	2h	2h	NUM
eurjchem-1549	79	27	,	,	PUNCT
eurjchem-1549	79	28	j	j	PROPN
eurjchem-1549	79	29	=	=	SYM
eurjchem-1549	79	30	8.8	8.8	NUM
eurjchem-1549	79	31	hz	hz	NOUN
eurjchem-1549	79	32	,	,	PUNCT
eurjchem-1549	79	33	ar‐h	ar‐h	PROPN
eurjchem-1549	79	34	)	)	PUNCT
eurjchem-1549	79	35	,	,	PUNCT
eurjchem-1549	79	36	10.70	10.70	NUM
eurjchem-1549	79	37	(	(	PUNCT
eurjchem-1549	79	38	s	s	PROPN
eurjchem-1549	79	39	,	,	PUNCT
eurjchem-1549	79	40	1h	1h	NUM
eurjchem-1549	79	41	,	,	PUNCT
eurjchem-1549	79	42	nhco	nhco	ADJ
eurjchem-1549	79	43	)	)	PUNCT
eurjchem-1549	79	44	.	.	PUNCT
eurjchem-1549	80	1	2.2.4	2.2.4	NUM
eurjchem-1549	80	2	.	.	X
eurjchem-1549	80	3	synthesis	synthesis	NOUN
eurjchem-1549	80	4	of	of	ADP
eurjchem-1549	80	5	7‐(4‐(3‐((4‐acetylphenyl)amino)‐3‐oxo	7‐(4‐(3‐((4‐acetylphenyl)amino)‐3‐oxo	NUM
eurjchem-1549	80	6	propyl)piperazin‐1‐yl)‐1‐ethyl‐6‐fluoro‐4‐oxo‐1,4‐dihydro	propyl)piperazin‐1‐yl)‐1‐ethyl‐6‐fluoro‐4‐oxo‐1,4‐dihydro	NOUN
eurjchem-1549	80	7	quinoline‐3‐carboxylic	quinoline‐3‐carboxylic	PROPN
eurjchem-1549	80	8	acid	acid	NOUN
eurjchem-1549	80	9	(	(	PUNCT
eurjchem-1549	80	10	6	6	NUM
eurjchem-1549	80	11	)	)	PUNCT
eurjchem-1549	80	12	to	to	ADP
eurjchem-1549	80	13	a	a	DET
eurjchem-1549	80	14	stirred	stir	VERB
eurjchem-1549	80	15	solution	solution	NOUN
eurjchem-1549	80	16	of	of	ADP
eurjchem-1549	80	17	compound	compound	NOUN
eurjchem-1549	80	18	5	5	NUM
eurjchem-1549	80	19	(	(	PUNCT
eurjchem-1549	80	20	0.297	0.297	NUM
eurjchem-1549	80	21	g	g	NOUN
eurjchem-1549	80	22	,	,	PUNCT
eurjchem-1549	80	23	1.1	1.1	NUM
eurjchem-1549	80	24	mmol	mmol	NOUN
eurjchem-1549	80	25	)	)	PUNCT
eurjchem-1549	80	26	in	in	ADP
eurjchem-1549	80	27	acetonitrile	acetonitrile	NOUN
eurjchem-1549	80	28	(	(	PUNCT
eurjchem-1549	80	29	10	10	NUM
eurjchem-1549	80	30	ml	ml	NOUN
eurjchem-1549	80	31	)	)	PUNCT
eurjchem-1549	80	32	was	be	AUX
eurjchem-1549	80	33	added	add	VERB
eurjchem-1549	80	34	norfloxacin	norfloxacin	PROPN
eurjchem-1549	80	35	(	(	PUNCT
eurjchem-1549	80	36	0.319	0.319	NUM
eurjchem-1549	80	37	g	g	NOUN
eurjchem-1549	80	38	,	,	PUNCT
eurjchem-1549	80	39	1.0	1.0	NUM
eurjchem-1549	80	40	mmol	mmol	NOUN
eurjchem-1549	80	41	)	)	PUNCT
eurjchem-1549	80	42	.	.	PUNCT
eurjchem-1549	81	1	then	then	ADV
eurjchem-1549	81	2	,	,	PUNCT
eurjchem-1549	81	3	triethyamine	triethyamine	NOUN
eurjchem-1549	81	4	(	(	PUNCT
eurjchem-1549	81	5	0.202	0.202	NUM
eurjchem-1549	81	6	g	g	NOUN
eurjchem-1549	81	7	,	,	PUNCT
eurjchem-1549	81	8	2.0	2.0	NUM
eurjchem-1549	81	9	mmol	mmol	NOUN
eurjchem-1549	81	10	)	)	PUNCT
eurjchem-1549	81	11	was	be	AUX
eurjchem-1549	81	12	added	add	VERB
eurjchem-1549	81	13	and	and	CCONJ
eurjchem-1549	81	14	the	the	DET
eurjchem-1549	81	15	mixture	mixture	NOUN
eurjchem-1549	81	16	was	be	AUX
eurjchem-1549	81	17	heated	heat	VERB
eurjchem-1549	81	18	under	under	ADP
eurjchem-1549	81	19	reflux	reflux	NOUN
eurjchem-1549	81	20	for	for	ADP
eurjchem-1549	81	21	18	18	NUM
eurjchem-1549	81	22	h.	h.	NOUN
eurjchem-1549	81	23	the	the	DET
eurjchem-1549	81	24	formed	form	VERB
eurjchem-1549	81	25	precipitate	precipitate	NOUN
eurjchem-1549	81	26	was	be	AUX
eurjchem-1549	81	27	filtered	filter	VERB
eurjchem-1549	81	28	while	while	SCONJ
eurjchem-1549	81	29	hot	hot	ADJ
eurjchem-1549	81	30	,	,	PUNCT
eurjchem-1549	81	31	washed	wash	VERB
eurjchem-1549	81	32	with	with	ADP
eurjchem-1549	81	33	acetonitrile	acetonitrile	NOUN
eurjchem-1549	81	34	and	and	CCONJ
eurjchem-1549	81	35	dried	dry	VERB
eurjchem-1549	81	36	under	under	ADP
eurjchem-1549	81	37	vacuum	vacuum	NOUN
eurjchem-1549	81	38	to	to	PART
eurjchem-1549	81	39	give	give	VERB
eurjchem-1549	81	40	compound	compound	NOUN
eurjchem-1549	81	41	6	6	NUM
eurjchem-1549	81	42	(	(	PUNCT
eurjchem-1549	81	43	scheme	scheme	NOUN
eurjchem-1549	81	44	1	1	NUM
eurjchem-1549	81	45	)	)	PUNCT
eurjchem-1549	81	46	.	.	PUNCT
eurjchem-1549	82	1	color	color	NOUN
eurjchem-1549	82	2	:	:	PUNCT
eurjchem-1549	82	3	white	white	ADJ
eurjchem-1549	82	4	powder	powder	NOUN
eurjchem-1549	82	5	.	.	PUNCT
eurjchem-1549	83	1	yield	yield	NOUN
eurjchem-1549	83	2	:	:	PUNCT
eurjchem-1549	83	3	0.274	0.274	NUM
eurjchem-1549	83	4	g	g	NOUN
eurjchem-1549	83	5	(	(	PUNCT
eurjchem-1549	83	6	54	54	NUM
eurjchem-1549	83	7	%	%	NOUN
eurjchem-1549	83	8	)	)	PUNCT
eurjchem-1549	83	9	.	.	PUNCT
eurjchem-1549	84	1	m.p	m.p	PROPN
eurjchem-1549	84	2	.	.	PROPN
eurjchem-1549	84	3	:	:	PUNCT
eurjchem-1549	85	1	275‐276	275‐276	NUM
eurjchem-1549	85	2	°	°	ADP
eurjchem-1549	85	3	c	c	X
eurjchem-1549	85	4	.	.	PUNCT
eurjchem-1549	86	1	ft‐ir	ft‐ir	NOUN
eurjchem-1549	86	2	(	(	PUNCT
eurjchem-1549	86	3	kbr	kbr	PROPN
eurjchem-1549	86	4	,	,	PUNCT
eurjchem-1549	86	5	ν	ν	PROPN
eurjchem-1549	86	6	,	,	PUNCT
eurjchem-1549	86	7	cm‐1	cm‐1	PROPN
eurjchem-1549	86	8	):	):	PUNCT
eurjchem-1549	86	9	3271(nh	3271(nh	NUM
eurjchem-1549	86	10	)	)	PUNCT
eurjchem-1549	86	11	,	,	PUNCT
eurjchem-1549	86	12	1725	1725	NUM
eurjchem-1549	86	13	(	(	PUNCT
eurjchem-1549	86	14	carboxylic	carboxylic	ADJ
eurjchem-1549	86	15	c	c	NOUN
eurjchem-1549	86	16	=	=	NOUN
eurjchem-1549	86	17	o	o	NOUN
eurjchem-1549	86	18	)	)	PUNCT
eurjchem-1549	86	19	,	,	PUNCT
eurjchem-1549	86	20	1675	1675	NUM
eurjchem-1549	86	21	(	(	PUNCT
eurjchem-1549	86	22	amidic	amidic	PROPN
eurjchem-1549	86	23	c	c	PROPN
eurjchem-1549	86	24	=	=	NOUN
eurjchem-1549	86	25	o	o	NOUN
eurjchem-1549	86	26	)	)	PUNCT
eurjchem-1549	86	27	,	,	PUNCT
eurjchem-1549	86	28	1652	1652	NUM
eurjchem-1549	86	29	(	(	PUNCT
eurjchem-1549	86	30	ch3c	ch3c	NOUN
eurjchem-1549	86	31	=	=	SYM
eurjchem-1549	86	32	o	o	NOUN
eurjchem-1549	86	33	)	)	PUNCT
eurjchem-1549	86	34	,	,	PUNCT
eurjchem-1549	86	35	1617	1617	NUM
eurjchem-1549	86	36	(	(	PUNCT
eurjchem-1549	86	37	4‐keto	4‐keto	NOUN
eurjchem-1549	86	38	c	c	NOUN
eurjchem-1549	86	39	=	=	NOUN
eurjchem-1549	86	40	o	o	NOUN
eurjchem-1549	86	41	)	)	PUNCT
eurjchem-1549	86	42	.	.	PUNCT
eurjchem-1549	87	1	1h	1h	NUM
eurjchem-1549	87	2	nmr	nmr	NOUN
eurjchem-1549	87	3	(	(	PUNCT
eurjchem-1549	87	4	400	400	NUM
eurjchem-1549	87	5	mhz	mhz	NOUN
eurjchem-1549	87	6	,	,	PUNCT
eurjchem-1549	87	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	87	8	,	,	PUNCT
eurjchem-1549	87	9	δ	δ	PROPN
eurjchem-1549	87	10	,	,	PUNCT
eurjchem-1549	87	11	ppm	ppm	NUM
eurjchem-1549	87	12	):	):	PUNCT
eurjchem-1549	87	13	1.44	1.44	NUM
eurjchem-1549	87	14	(	(	PUNCT
eurjchem-1549	87	15	t	t	PROPN
eurjchem-1549	87	16	,	,	PUNCT
eurjchem-1549	87	17	3h	3h	NUM
eurjchem-1549	87	18	,	,	PUNCT
eurjchem-1549	87	19	j	j	PROPN
eurjchem-1549	87	20	=	=	SYM
eurjchem-1549	87	21	7.6	7.6	NUM
eurjchem-1549	87	22	hz	hz	NOUN
eurjchem-1549	87	23	,	,	PUNCT
eurjchem-1549	87	24	nch2ch3	nch2ch3	PROPN
eurjchem-1549	87	25	)	)	PUNCT
eurjchem-1549	87	26	,	,	PUNCT
eurjchem-1549	87	27	2.52	2.52	NUM
eurjchem-1549	87	28	(	(	PUNCT
eurjchem-1549	87	29	s	s	PROPN
eurjchem-1549	87	30	,	,	PUNCT
eurjchem-1549	87	31	3h	3h	NUM
eurjchem-1549	87	32	,	,	PUNCT
eurjchem-1549	87	33	coch3	coch3	NOUN
eurjchem-1549	87	34	)	)	PUNCT
eurjchem-1549	87	35	,	,	PUNCT
eurjchem-1549	87	36	2.59	2.59	NUM
eurjchem-1549	87	37	(	(	PUNCT
eurjchem-1549	87	38	t	t	PROPN
eurjchem-1549	87	39	,	,	PUNCT
eurjchem-1549	87	40	2h	2h	NUM
eurjchem-1549	87	41	,	,	PUNCT
eurjchem-1549	87	42	j	j	PROPN
eurjchem-1549	88	1	=	=	NOUN
eurjchem-1549	88	2	7.6	7.6	NUM
eurjchem-1549	88	3	hz	hz	NOUN
eurjchem-1549	88	4	,	,	PUNCT
eurjchem-1549	88	5	coch2ch2	coch2ch2	NOUN
eurjchem-1549	88	6	)	)	PUNCT
eurjchem-1549	88	7	,	,	PUNCT
eurjchem-1549	88	8	2.65‐	2.65‐	NUM
eurjchem-1549	88	9	2.68	2.68	NUM
eurjchem-1549	88	10	(	(	PUNCT
eurjchem-1549	88	11	m	m	PROPN
eurjchem-1549	88	12	,	,	PUNCT
eurjchem-1549	88	13	4h	4h	NOUN
eurjchem-1549	88	14	,	,	PUNCT
eurjchem-1549	88	15	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	88	16	)	)	PUNCT
eurjchem-1549	88	17	,	,	PUNCT
eurjchem-1549	88	18	2.78	2.78	NUM
eurjchem-1549	88	19	(	(	PUNCT
eurjchem-1549	88	20	t	t	PROPN
eurjchem-1549	88	21	,	,	PUNCT
eurjchem-1549	88	22	2h	2h	NUM
eurjchem-1549	88	23	,	,	PUNCT
eurjchem-1549	88	24	j	j	PROPN
eurjchem-1549	89	1	=	=	SYM
eurjchem-1549	89	2	7.6	7.6	NUM
eurjchem-1549	89	3	hz	hz	NOUN
eurjchem-1549	89	4	,	,	PUNCT
eurjchem-1549	89	5	coch2ch2	coch2ch2	NOUN
eurjchem-1549	89	6	)	)	PUNCT
eurjchem-1549	89	7	,	,	PUNCT
eurjchem-1549	89	8	3.34‐3.42	3.34‐3.42	NUM
eurjchem-1549	89	9	(	(	PUNCT
eurjchem-1549	89	10	m	m	PROPN
eurjchem-1549	89	11	,	,	PUNCT
eurjchem-1549	89	12	4h	4h	NOUN
eurjchem-1549	89	13	,	,	PUNCT
eurjchem-1549	89	14	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	89	15	)	)	PUNCT
eurjchem-1549	89	16	,	,	PUNCT
eurjchem-1549	89	17	4.58	4.58	NUM
eurjchem-1549	89	18	(	(	PUNCT
eurjchem-1549	89	19	q	q	NOUN
eurjchem-1549	89	20	,	,	PUNCT
eurjchem-1549	89	21	2h	2h	NUM
eurjchem-1549	89	22	,	,	PUNCT
eurjchem-1549	89	23	j	j	PROPN
eurjchem-1549	89	24	=	=	SYM
eurjchem-1549	89	25	7.6	7.6	NUM
eurjchem-1549	89	26	,	,	PUNCT
eurjchem-1549	89	27	nch2ch3	nch2ch3	PROPN
eurjchem-1549	89	28	)	)	PUNCT
eurjchem-1549	89	29	,	,	PUNCT
eurjchem-1549	89	30	aziz	aziz	PROPN
eurjchem-1549	89	31	et	et	PROPN
eurjchem-1549	89	32	al	al	PROPN
eurjchem-1549	89	33	.	.	PUNCT
eurjchem-1549	89	34	/	/	SYM
eurjchem-1549	89	35	european	european	PROPN
eurjchem-1549	89	36	journal	journal	PROPN
eurjchem-1549	89	37	of	of	ADP
eurjchem-1549	89	38	chemistry	chemistry	NOUN
eurjchem-1549	89	39	8	8	NUM
eurjchem-1549	89	40	(	(	PUNCT
eurjchem-1549	89	41	2	2	NUM
eurjchem-1549	89	42	)	)	PUNCT
eurjchem-1549	89	43	(	(	PUNCT
eurjchem-1549	89	44	2017	2017	NUM
eurjchem-1549	89	45	)	)	PUNCT
eurjchem-1549	89	46	119‐124	119‐124	PROPN
eurjchem-1549	89	47	121	121	NUM
eurjchem-1549	89	48	scheme	scheme	NOUN
eurjchem-1549	89	49	1	1	NUM
eurjchem-1549	89	50	7.18	7.18	NUM
eurjchem-1549	89	51	(	(	PUNCT
eurjchem-1549	89	52	d	d	PROPN
eurjchem-1549	89	53	,	,	PUNCT
eurjchem-1549	89	54	1h	1h	NUM
eurjchem-1549	89	55	,	,	PUNCT
eurjchem-1549	89	56	jh‐f	jh‐f	PROPN
eurjchem-1549	90	1	=	=	SYM
eurjchem-1549	90	2	7.6	7.6	NUM
eurjchem-1549	90	3	hz	hz	NOUN
eurjchem-1549	90	4	,	,	PUNCT
eurjchem-1549	90	5	h8	h8	PROPN
eurjchem-1549	90	6	)	)	PUNCT
eurjchem-1549	90	7	,	,	PUNCT
eurjchem-1549	90	8	7.73	7.73	NUM
eurjchem-1549	90	9	(	(	PUNCT
eurjchem-1549	90	10	d	d	PROPN
eurjchem-1549	90	11	,	,	PUNCT
eurjchem-1549	90	12	2h	2h	NUM
eurjchem-1549	90	13	,	,	PUNCT
eurjchem-1549	90	14	j	j	PROPN
eurjchem-1549	90	15	=	=	SYM
eurjchem-1549	90	16	8.8	8.8	NUM
eurjchem-1549	90	17	hz	hz	NOUN
eurjchem-1549	90	18	,	,	PUNCT
eurjchem-1549	90	19	ar‐	ar‐	PROPN
eurjchem-1549	90	20	h	h	NOUN
eurjchem-1549	90	21	)	)	PUNCT
eurjchem-1549	90	22	,	,	PUNCT
eurjchem-1549	90	23	7.91‐7.93	7.91‐7.93	PROPN
eurjchem-1549	90	24	(	(	PUNCT
eurjchem-1549	90	25	m	m	PROPN
eurjchem-1549	90	26	,	,	PUNCT
eurjchem-1549	90	27	3h	3h	NUM
eurjchem-1549	90	28	,	,	PUNCT
eurjchem-1549	90	29	ar‐2h	ar‐2h	PRON
eurjchem-1549	90	30	+	+	NUM
eurjchem-1549	90	31	h5	h5	NOUN
eurjchem-1549	90	32	)	)	PUNCT
eurjchem-1549	90	33	,	,	PUNCT
eurjchem-1549	90	34	8.91	8.91	NUM
eurjchem-1549	90	35	(	(	PUNCT
eurjchem-1549	90	36	s	s	PROPN
eurjchem-1549	90	37	,	,	PUNCT
eurjchem-1549	90	38	1h	1h	NUM
eurjchem-1549	90	39	,	,	PUNCT
eurjchem-1549	90	40	h2	h2	NOUN
eurjchem-1549	90	41	)	)	PUNCT
eurjchem-1549	90	42	,	,	PUNCT
eurjchem-1549	90	43	10.28	10.28	NUM
eurjchem-1549	90	44	(	(	PUNCT
eurjchem-1549	90	45	s	s	PROPN
eurjchem-1549	90	46	,	,	PUNCT
eurjchem-1549	90	47	1h	1h	NUM
eurjchem-1549	90	48	,	,	PUNCT
eurjchem-1549	90	49	nhco	nhco	ADJ
eurjchem-1549	90	50	)	)	PUNCT
eurjchem-1549	90	51	,	,	PUNCT
eurjchem-1549	90	52	15.22	15.22	NUM
eurjchem-1549	90	53	(	(	PUNCT
eurjchem-1549	90	54	s	s	PROPN
eurjchem-1549	90	55	,	,	PUNCT
eurjchem-1549	90	56	1h	1h	NUM
eurjchem-1549	90	57	,	,	PUNCT
eurjchem-1549	90	58	cooh	cooh	NOUN
eurjchem-1549	90	59	)	)	PUNCT
eurjchem-1549	90	60	.	.	PUNCT
eurjchem-1549	91	1	13c	13c	NOUN
eurjchem-1549	91	2	nmr	nmr	NOUN
eurjchem-1549	91	3	(	(	PUNCT
eurjchem-1549	91	4	100	100	NUM
eurjchem-1549	91	5	mhz	mhz	NOUN
eurjchem-1549	91	6	,	,	PUNCT
eurjchem-1549	91	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	91	8	,	,	PUNCT
eurjchem-1549	91	9	δ	δ	PROPN
eurjchem-1549	91	10	,	,	PUNCT
eurjchem-1549	91	11	ppm	ppm	NUM
eurjchem-1549	91	12	):	):	PUNCT
eurjchem-1549	91	13	14.74	14.74	NUM
eurjchem-1549	91	14	,	,	PUNCT
eurjchem-1549	91	15	26.76	26.76	NUM
eurjchem-1549	91	16	,	,	PUNCT
eurjchem-1549	91	17	34.80	34.80	NUM
eurjchem-1549	91	18	,	,	PUNCT
eurjchem-1549	91	19	49.49	49.49	NUM
eurjchem-1549	91	20	,	,	PUNCT
eurjchem-1549	91	21	50.01	50.01	NUM
eurjchem-1549	91	22	,	,	PUNCT
eurjchem-1549	91	23	52.63	52.63	NUM
eurjchem-1549	91	24	,	,	PUNCT
eurjchem-1549	91	25	53.92	53.92	NUM
eurjchem-1549	91	26	,	,	PUNCT
eurjchem-1549	91	27	106.25	106.25	NUM
eurjchem-1549	91	28	,	,	PUNCT
eurjchem-1549	91	29	107.69	107.69	NUM
eurjchem-1549	91	30	,	,	PUNCT
eurjchem-1549	91	31	111.65	111.65	NUM
eurjchem-1549	91	32	(	(	PUNCT
eurjchem-1549	91	33	d	d	PROPN
eurjchem-1549	91	34	,	,	PUNCT
eurjchem-1549	91	35	j	j	PROPN
eurjchem-1549	91	36	=	=	SYM
eurjchem-1549	91	37	23hz	23hz	NOUN
eurjchem-1549	91	38	)	)	PUNCT
eurjchem-1549	91	39	,	,	PUNCT
eurjchem-1549	91	40	118.85	118.85	NUM
eurjchem-1549	91	41	,	,	PUNCT
eurjchem-1549	91	42	119.78	119.78	NUM
eurjchem-1549	91	43	,	,	PUNCT
eurjchem-1549	91	44	129.85	129.85	NUM
eurjchem-1549	91	45	,	,	PUNCT
eurjchem-1549	91	46	132.23	132.23	NUM
eurjchem-1549	91	47	,	,	PUNCT
eurjchem-1549	91	48	137.75	137.75	NUM
eurjchem-1549	91	49	,	,	PUNCT
eurjchem-1549	91	50	143.99	143.99	NUM
eurjchem-1549	91	51	,	,	PUNCT
eurjchem-1549	91	52	145.95	145.95	NUM
eurjchem-1549	91	53	,	,	PUNCT
eurjchem-1549	91	54	148.84	148.84	NUM
eurjchem-1549	91	55	,	,	PUNCT
eurjchem-1549	91	56	153.37	153.37	NUM
eurjchem-1549	91	57	(	(	PUNCT
eurjchem-1549	91	58	d	d	PROPN
eurjchem-1549	91	59	,	,	PUNCT
eurjchem-1549	91	60	j	j	PROPN
eurjchem-1549	91	61	=	=	SYM
eurjchem-1549	91	62	247	247	NUM
eurjchem-1549	91	63	hz	hz	NOUN
eurjchem-1549	91	64	)	)	PUNCT
eurjchem-1549	91	65	,	,	PUNCT
eurjchem-1549	91	66	166.48	166.48	NUM
eurjchem-1549	91	67	,	,	PUNCT
eurjchem-1549	91	68	171.14	171.14	NUM
eurjchem-1549	91	69	,	,	PUNCT
eurjchem-1549	91	70	176.67	176.67	NUM
eurjchem-1549	91	71	,	,	PUNCT
eurjchem-1549	91	72	196.81	196.81	NUM
eurjchem-1549	91	73	.	.	PUNCT
eurjchem-1549	92	1	hrms	hrm	NOUN
eurjchem-1549	92	2	(	(	PUNCT
eurjchem-1549	92	3	esi	esi	PROPN
eurjchem-1549	92	4	,	,	PUNCT
eurjchem-1549	92	5	m	m	PROPN
eurjchem-1549	92	6	/	/	SYM
eurjchem-1549	92	7	z	z	ADJ
eurjchem-1549	92	8	)	)	PUNCT
eurjchem-1549	92	9	calcd	calcd	NOUN
eurjchem-1549	92	10	.	.	PUNCT
eurjchem-1549	93	1	for	for	ADP
eurjchem-1549	93	2	c27h28fn4o5	c27h28fn4o5	PROPN
eurjchem-1549	93	3	[	[	X
eurjchem-1549	93	4	m‐h]	m‐h]	ADJ
eurjchem-1549	93	5	:	:	PUNCT
eurjchem-1549	93	6	507.20492	507.20492	NUM
eurjchem-1549	93	7	,	,	PUNCT
eurjchem-1549	93	8	found	find	VERB
eurjchem-1549	93	9	:	:	PUNCT
eurjchem-1549	93	10	507.20514	507.20514	NUM
eurjchem-1549	93	11	.	.	NOUN
eurjchem-1549	93	12	2.2.5	2.2.5	NUM
eurjchem-1549	93	13	.	.	PUNCT
eurjchem-1549	94	1	synthesis	synthesis	NOUN
eurjchem-1549	94	2	of	of	ADP
eurjchem-1549	94	3	(	(	PUNCT
eurjchem-1549	94	4	e)‐1‐cyclopropyl‐6‐fluoro‐7‐(4‐(3‐((4‐(1‐	e)‐1‐cyclopropyl‐6‐fluoro‐7‐(4‐(3‐((4‐(1‐	PROPN
eurjchem-1549	94	5	(	(	PUNCT
eurjchem-1549	94	6	hydroxyimino)ethyl)phenyl)amino)‐3‐oxopropyl)pipera	hydroxyimino)ethyl)phenyl)amino)‐3‐oxopropyl)pipera	PROPN
eurjchem-1549	94	7	zin‐1‐yl)‐4‐oxo‐1,4‐dihydroquinoline‐3‐carboxylic	zin‐1‐yl)‐4‐oxo‐1,4‐dihydroquinoline‐3‐carboxylic	NOUN
eurjchem-1549	94	8	acid	acid	PROPN
eurjchem-1549	94	9	(	(	PUNCT
eurjchem-1549	94	10	7	7	NUM
eurjchem-1549	94	11	)	)	PUNCT
eurjchem-1549	94	12	to	to	ADP
eurjchem-1549	94	13	a	a	DET
eurjchem-1549	94	14	stirred	stirred	ADJ
eurjchem-1549	94	15	suspension	suspension	NOUN
eurjchem-1549	94	16	of	of	ADP
eurjchem-1549	94	17	the	the	DET
eurjchem-1549	94	18	ketone	ketone	NOUN
eurjchem-1549	94	19	6	6	NUM
eurjchem-1549	94	20	(	(	PUNCT
eurjchem-1549	94	21	0.508	0.508	NUM
eurjchem-1549	94	22	g	g	NOUN
eurjchem-1549	94	23	,	,	PUNCT
eurjchem-1549	94	24	1.0	1.0	NUM
eurjchem-1549	94	25	mmol	mmol	NOUN
eurjchem-1549	94	26	)	)	PUNCT
eurjchem-1549	94	27	in	in	ADP
eurjchem-1549	94	28	absolute	absolute	ADJ
eurjchem-1549	94	29	ethanol	ethanol	NOUN
eurjchem-1549	94	30	(	(	PUNCT
eurjchem-1549	94	31	10	10	NUM
eurjchem-1549	94	32	ml	ml	NOUN
eurjchem-1549	94	33	)	)	PUNCT
eurjchem-1549	94	34	were	be	AUX
eurjchem-1549	94	35	added	add	VERB
eurjchem-1549	94	36	hydroxylamine	hydroxylamine	PROPN
eurjchem-1549	94	37	hydro‐chloride	hydro‐chloride	NOUN
eurjchem-1549	94	38	(	(	PUNCT
eurjchem-1549	94	39	0.278	0.278	NUM
eurjchem-1549	94	40	g	g	NOUN
eurjchem-1549	94	41	,	,	PUNCT
eurjchem-1549	94	42	4.0	4.0	NUM
eurjchem-1549	94	43	mmol	mmol	NOUN
eurjchem-1549	94	44	)	)	PUNCT
eurjchem-1549	94	45	and	and	CCONJ
eurjchem-1549	94	46	anhydrous	anhydrous	ADJ
eurjchem-1549	94	47	sodium	sodium	NOUN
eurjchem-1549	94	48	acetate	acetate	NOUN
eurjchem-1549	94	49	(	(	PUNCT
eurjchem-1549	94	50	0.328	0.328	NUM
eurjchem-1549	94	51	g	g	NOUN
eurjchem-1549	94	52	,	,	PUNCT
eurjchem-1549	94	53	4.0	4.0	NUM
eurjchem-1549	94	54	mmol	mmol	NOUN
eurjchem-1549	94	55	)	)	PUNCT
eurjchem-1549	94	56	.	.	PUNCT
eurjchem-1549	95	1	the	the	DET
eurjchem-1549	95	2	mixture	mixture	NOUN
eurjchem-1549	95	3	was	be	AUX
eurjchem-1549	95	4	heated	heat	VERB
eurjchem-1549	95	5	under	under	ADP
eurjchem-1549	95	6	reflux	reflux	NOUN
eurjchem-1549	95	7	for	for	ADP
eurjchem-1549	95	8	12	12	NUM
eurjchem-1549	95	9	h.	h.	NOUN
eurjchem-1549	95	10	the	the	DET
eurjchem-1549	95	11	formed	form	VERB
eurjchem-1549	95	12	precipitate	precipitate	NOUN
eurjchem-1549	95	13	was	be	AUX
eurjchem-1549	95	14	filtered	filter	VERB
eurjchem-1549	95	15	while	while	SCONJ
eurjchem-1549	95	16	hot	hot	ADJ
eurjchem-1549	95	17	,	,	PUNCT
eurjchem-1549	95	18	washed	wash	VERB
eurjchem-1549	95	19	with	with	ADP
eurjchem-1549	95	20	ethanol	ethanol	NOUN
eurjchem-1549	95	21	,	,	PUNCT
eurjchem-1549	95	22	dried	dry	VERB
eurjchem-1549	95	23	and	and	CCONJ
eurjchem-1549	95	24	crystallized	crystallize	VERB
eurjchem-1549	95	25	from	from	ADP
eurjchem-1549	95	26	acetonitrile	acetonitrile	NOUN
eurjchem-1549	95	27	to	to	PART
eurjchem-1549	95	28	afford	afford	VERB
eurjchem-1549	95	29	oxime	oxime	NOUN
eurjchem-1549	95	30	7	7	NUM
eurjchem-1549	95	31	(	(	PUNCT
eurjchem-1549	95	32	scheme	scheme	NOUN
eurjchem-1549	95	33	1	1	NUM
eurjchem-1549	95	34	)	)	PUNCT
eurjchem-1549	95	35	.	.	PUNCT
eurjchem-1549	96	1	color	color	NOUN
eurjchem-1549	96	2	:	:	PUNCT
eurjchem-1549	96	3	white	white	ADJ
eurjchem-1549	96	4	crystals	crystal	NOUN
eurjchem-1549	96	5	.	.	PUNCT
eurjchem-1549	97	1	yield	yield	NOUN
eurjchem-1549	97	2	:	:	PUNCT
eurjchem-1549	97	3	0.334	0.334	NUM
eurjchem-1549	97	4	g	g	NOUN
eurjchem-1549	97	5	(	(	PUNCT
eurjchem-1549	97	6	65.8	65.8	NUM
eurjchem-1549	97	7	%	%	NOUN
eurjchem-1549	97	8	)	)	PUNCT
eurjchem-1549	97	9	.	.	PUNCT
eurjchem-1549	98	1	m.p	m.p	PROPN
eurjchem-1549	98	2	.	.	PROPN
eurjchem-1549	98	3	:	:	PUNCT
eurjchem-1549	99	1	290‐292	290‐292	NUM
eurjchem-1549	99	2	°	°	ADP
eurjchem-1549	99	3	c	c	NOUN
eurjchem-1549	99	4	.	.	PUNCT
eurjchem-1549	99	5	ft‐ir	ft‐ir	NOUN
eurjchem-1549	99	6	(	(	PUNCT
eurjchem-1549	99	7	kbr	kbr	PROPN
eurjchem-1549	99	8	,	,	PUNCT
eurjchem-1549	99	9	ν	ν	PROPN
eurjchem-1549	99	10	,	,	PUNCT
eurjchem-1549	99	11	cm‐1	cm‐1	PROPN
eurjchem-1549	99	12	):	):	PUNCT
eurjchem-1549	99	13	1679	1679	NUM
eurjchem-1549	99	14	(	(	PUNCT
eurjchem-1549	99	15	carboxylic	carboxylic	ADJ
eurjchem-1549	99	16	c	c	NOUN
eurjchem-1549	99	17	=	=	NOUN
eurjchem-1549	99	18	o	o	NOUN
eurjchem-1549	99	19	)	)	PUNCT
eurjchem-1549	99	20	,	,	PUNCT
eurjchem-1549	99	21	1627	1627	NUM
eurjchem-1549	99	22	(	(	PUNCT
eurjchem-1549	99	23	4‐keto	4‐keto	NOUN
eurjchem-1549	99	24	c	c	NOUN
eurjchem-1549	99	25	=	=	NOUN
eurjchem-1549	99	26	o	o	NOUN
eurjchem-1549	99	27	)	)	PUNCT
eurjchem-1549	99	28	,	,	PUNCT
eurjchem-1549	99	29	1601	1601	NUM
eurjchem-1549	99	30	(	(	PUNCT
eurjchem-1549	99	31	c	c	NOUN
eurjchem-1549	99	32	=	=	SYM
eurjchem-1549	99	33	n	n	NUM
eurjchem-1549	99	34	)	)	PUNCT
eurjchem-1549	99	35	.	.	PUNCT
eurjchem-1549	100	1	1h	1h	NUM
eurjchem-1549	100	2	nmr	nmr	NOUN
eurjchem-1549	100	3	(	(	PUNCT
eurjchem-1549	100	4	400	400	NUM
eurjchem-1549	100	5	mhz	mhz	NOUN
eurjchem-1549	100	6	,	,	PUNCT
eurjchem-1549	100	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	100	8	,	,	PUNCT
eurjchem-1549	100	9	δ	δ	PROPN
eurjchem-1549	100	10	,	,	PUNCT
eurjchem-1549	100	11	ppm	ppm	NUM
eurjchem-1549	100	12	):	):	PUNCT
eurjchem-1549	100	13	1.43	1.43	NUM
eurjchem-1549	100	14	(	(	PUNCT
eurjchem-1549	100	15	t	t	PROPN
eurjchem-1549	100	16	,	,	PUNCT
eurjchem-1549	100	17	3h	3h	NUM
eurjchem-1549	100	18	,	,	PUNCT
eurjchem-1549	100	19	j	j	PROPN
eurjchem-1549	100	20	=	=	SYM
eurjchem-1549	100	21	7.6	7.6	NUM
eurjchem-1549	100	22	hz	hz	NOUN
eurjchem-1549	100	23	,	,	PUNCT
eurjchem-1549	100	24	nch2ch3	nch2ch3	PROPN
eurjchem-1549	100	25	)	)	PUNCT
eurjchem-1549	100	26	,	,	PUNCT
eurjchem-1549	100	27	2.13	2.13	NUM
eurjchem-1549	100	28	(	(	PUNCT
eurjchem-1549	100	29	s	s	PROPN
eurjchem-1549	100	30	,	,	PUNCT
eurjchem-1549	100	31	3h	3h	NUM
eurjchem-1549	100	32	,	,	PUNCT
eurjchem-1549	100	33	ch3c	ch3c	PROPN
eurjchem-1549	100	34	=	=	SYM
eurjchem-1549	100	35	noh	noh	PROPN
eurjchem-1549	100	36	)	)	PUNCT
eurjchem-1549	100	37	,	,	PUNCT
eurjchem-1549	100	38	2.55	2.55	NUM
eurjchem-1549	100	39	(	(	PUNCT
eurjchem-1549	100	40	t	t	PROPN
eurjchem-1549	100	41	,	,	PUNCT
eurjchem-1549	100	42	2h	2h	NUM
eurjchem-1549	100	43	,	,	PUNCT
eurjchem-1549	100	44	j	j	PROPN
eurjchem-1549	100	45	=	=	SYM
eurjchem-1549	100	46	7.6	7.6	NUM
eurjchem-1549	100	47	hz	hz	NOUN
eurjchem-1549	100	48	,	,	PUNCT
eurjchem-1549	100	49	nhcoch2ch2	nhcoch2ch2	ADJ
eurjchem-1549	100	50	)	)	PUNCT
eurjchem-1549	100	51	,	,	PUNCT
eurjchem-1549	100	52	2.63‐2.71	2.63‐2.71	NUM
eurjchem-1549	100	53	(	(	PUNCT
eurjchem-1549	100	54	m	m	PROPN
eurjchem-1549	100	55	,	,	PUNCT
eurjchem-1549	100	56	4h	4h	NOUN
eurjchem-1549	100	57	,	,	PUNCT
eurjchem-1549	100	58	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	100	59	)	)	PUNCT
eurjchem-1549	100	60	,	,	PUNCT
eurjchem-1549	100	61	2.76	2.76	NUM
eurjchem-1549	100	62	(	(	PUNCT
eurjchem-1549	100	63	t	t	PROPN
eurjchem-1549	100	64	,	,	PUNCT
eurjchem-1549	100	65	2h	2h	NUM
eurjchem-1549	100	66	,	,	PUNCT
eurjchem-1549	100	67	j	j	PROPN
eurjchem-1549	100	68	=	=	SYM
eurjchem-1549	100	69	7.6	7.6	NUM
eurjchem-1549	100	70	hz	hz	NOUN
eurjchem-1549	100	71	,	,	PUNCT
eurjchem-1549	100	72	nhcoch2ch2	nhcoch2ch2	ADJ
eurjchem-1549	100	73	)	)	PUNCT
eurjchem-1549	100	74	,	,	PUNCT
eurjchem-1549	100	75	3.33‐3.41	3.33‐3.41	NUM
eurjchem-1549	100	76	(	(	PUNCT
eurjchem-1549	100	77	m	m	PROPN
eurjchem-1549	100	78	,	,	PUNCT
eurjchem-1549	100	79	4h	4h	NOUN
eurjchem-1549	100	80	,	,	PUNCT
eurjchem-1549	100	81	piperazinyl‐h	piperazinyl‐h	NOUN
eurjchem-1549	100	82	)	)	PUNCT
eurjchem-1549	100	83	,	,	PUNCT
eurjchem-1549	100	84	4.58	4.58	NUM
eurjchem-1549	100	85	(	(	PUNCT
eurjchem-1549	100	86	q	q	NOUN
eurjchem-1549	100	87	,	,	PUNCT
eurjchem-1549	100	88	2h	2h	NUM
eurjchem-1549	100	89	,	,	PUNCT
eurjchem-1549	100	90	j	j	PROPN
eurjchem-1549	101	1	=	=	SYM
eurjchem-1549	101	2	7.6	7.6	NUM
eurjchem-1549	101	3	hz	hz	NOUN
eurjchem-1549	101	4	,	,	PUNCT
eurjchem-1549	101	5	nch2ch3	nch2ch3	PROPN
eurjchem-1549	101	6	)	)	PUNCT
eurjchem-1549	101	7	,	,	PUNCT
eurjchem-1549	101	8	7.18	7.18	NUM
eurjchem-1549	101	9	(	(	PUNCT
eurjchem-1549	101	10	d	d	PROPN
eurjchem-1549	101	11	,	,	PUNCT
eurjchem-1549	101	12	1h	1h	NUM
eurjchem-1549	101	13	,	,	PUNCT
eurjchem-1549	101	14	jh‐f	jh‐f	PROPN
eurjchem-1549	101	15	=	=	SYM
eurjchem-1549	101	16	7.6	7.6	NUM
eurjchem-1549	101	17	hz	hz	NOUN
eurjchem-1549	101	18	,	,	PUNCT
eurjchem-1549	101	19	h8	h8	PROPN
eurjchem-1549	101	20	)	)	PUNCT
eurjchem-1549	101	21	,	,	PUNCT
eurjchem-1549	101	22	7.60	7.60	NUM
eurjchem-1549	101	23	(	(	PUNCT
eurjchem-1549	101	24	m	m	PROPN
eurjchem-1549	101	25	,	,	PUNCT
eurjchem-1549	101	26	4h	4h	NUM
eurjchem-1549	101	27	,	,	PUNCT
eurjchem-1549	101	28	ar‐h	ar‐h	PROPN
eurjchem-1549	101	29	)	)	PUNCT
eurjchem-1549	101	30	,	,	PUNCT
eurjchem-1549	101	31	7.91	7.91	NUM
eurjchem-1549	101	32	(	(	PUNCT
eurjchem-1549	101	33	d	d	PROPN
eurjchem-1549	101	34	,	,	PUNCT
eurjchem-1549	101	35	1h	1h	NUM
eurjchem-1549	101	36	,	,	PUNCT
eurjchem-1549	101	37	jh‐f	jh‐f	PROPN
eurjchem-1549	101	38	=	=	SYM
eurjchem-1549	101	39	13.6	13.6	NUM
eurjchem-1549	101	40	hz	hz	NOUN
eurjchem-1549	101	41	,	,	PUNCT
eurjchem-1549	101	42	h5	h5	PROPN
eurjchem-1549	101	43	)	)	PUNCT
eurjchem-1549	101	44	,	,	PUNCT
eurjchem-1549	101	45	8.92	8.92	NUM
eurjchem-1549	101	46	(	(	PUNCT
eurjchem-1549	101	47	s	s	PROPN
eurjchem-1549	101	48	,	,	PUNCT
eurjchem-1549	101	49	1h	1h	NUM
eurjchem-1549	101	50	,	,	PUNCT
eurjchem-1549	101	51	h2	h2	NOUN
eurjchem-1549	101	52	)	)	PUNCT
eurjchem-1549	101	53	,	,	PUNCT
eurjchem-1549	101	54	10.06	10.06	NUM
eurjchem-1549	101	55	(	(	PUNCT
eurjchem-1549	101	56	s	s	PROPN
eurjchem-1549	101	57	,	,	PUNCT
eurjchem-1549	101	58	1h	1h	NUM
eurjchem-1549	101	59	,	,	PUNCT
eurjchem-1549	101	60	nhco	nhco	ADJ
eurjchem-1549	101	61	)	)	PUNCT
eurjchem-1549	101	62	,	,	PUNCT
eurjchem-1549	101	63	10.94	10.94	NUM
eurjchem-1549	101	64	(	(	PUNCT
eurjchem-1549	101	65	s	s	PROPN
eurjchem-1549	101	66	,	,	PUNCT
eurjchem-1549	101	67	1h	1h	NUM
eurjchem-1549	101	68	,	,	PUNCT
eurjchem-1549	101	69	c	c	PROPN
eurjchem-1549	101	70	=	=	SYM
eurjchem-1549	101	71	noh	noh	PROPN
eurjchem-1549	101	72	)	)	PUNCT
eurjchem-1549	101	73	,	,	PUNCT
eurjchem-1549	101	74	15.27	15.27	NUM
eurjchem-1549	101	75	(	(	PUNCT
eurjchem-1549	101	76	s	s	PROPN
eurjchem-1549	101	77	,	,	PUNCT
eurjchem-1549	101	78	1h	1h	NUM
eurjchem-1549	101	79	,	,	PUNCT
eurjchem-1549	101	80	cooh	cooh	NOUN
eurjchem-1549	101	81	)	)	PUNCT
eurjchem-1549	101	82	.	.	PUNCT
eurjchem-1549	102	1	13c	13c	NOUN
eurjchem-1549	102	2	nmr	nmr	NOUN
eurjchem-1549	102	3	(	(	PUNCT
eurjchem-1549	102	4	100	100	NUM
eurjchem-1549	102	5	mhz	mhz	NOUN
eurjchem-1549	102	6	,	,	PUNCT
eurjchem-1549	102	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1549	102	8	,	,	PUNCT
eurjchem-1549	102	9	δ	δ	PROPN
eurjchem-1549	102	10	,	,	PUNCT
eurjchem-1549	102	11	ppm	ppm	NOUN
eurjchem-1549	102	12	):	):	PUNCT
eurjchem-1549	102	13	11.80	11.80	NUM
eurjchem-1549	102	14	,	,	PUNCT
eurjchem-1549	102	15	14.76	14.76	NUM
eurjchem-1549	102	16	,	,	PUNCT
eurjchem-1549	102	17	34.69	34.69	NUM
eurjchem-1549	102	18	,	,	PUNCT
eurjchem-1549	102	19	49.50	49.50	NUM
eurjchem-1549	102	20	,	,	PUNCT
eurjchem-1549	102	21	50.01	50.01	NUM
eurjchem-1549	102	22	,	,	PUNCT
eurjchem-1549	102	23	52.63	52.63	NUM
eurjchem-1549	102	24	,	,	PUNCT
eurjchem-1549	102	25	54.06	54.06	NUM
eurjchem-1549	102	26	,	,	PUNCT
eurjchem-1549	102	27	106.27	106.27	NUM
eurjchem-1549	102	28	,	,	PUNCT
eurjchem-1549	102	29	107.65	107.65	NUM
eurjchem-1549	102	30	,	,	PUNCT
eurjchem-1549	102	31	111.64	111.64	NUM
eurjchem-1549	102	32	(	(	PUNCT
eurjchem-1549	102	33	d	d	PROPN
eurjchem-1549	102	34	,	,	PUNCT
eurjchem-1549	102	35	j	j	PROPN
eurjchem-1549	102	36	=	=	SYM
eurjchem-1549	102	37	23hz	23hz	NOUN
eurjchem-1549	102	38	)	)	PUNCT
eurjchem-1549	102	39	,	,	PUNCT
eurjchem-1549	102	40	119.51	119.51	NUM
eurjchem-1549	102	41	(	(	PUNCT
eurjchem-1549	102	42	d	d	NOUN
eurjchem-1549	102	43	,	,	PUNCT
eurjchem-1549	102	44	j	j	PROPN
eurjchem-1549	102	45	=	=	SYM
eurjchem-1549	102	46	49	49	NUM
eurjchem-1549	102	47	hz	hz	NOUN
eurjchem-1549	102	48	)	)	PUNCT
eurjchem-1549	102	49	,	,	PUNCT
eurjchem-1549	102	50	126.43	126.43	NUM
eurjchem-1549	102	51	,	,	PUNCT
eurjchem-1549	102	52	129.87	129.87	NUM
eurjchem-1549	102	53	,	,	PUNCT
eurjchem-1549	102	54	132.20	132.20	NUM
eurjchem-1549	102	55	,	,	PUNCT
eurjchem-1549	102	56	137.73	137.73	NUM
eurjchem-1549	102	57	,	,	PUNCT
eurjchem-1549	102	58	140.06	140.06	NUM
eurjchem-1549	102	59	,	,	PUNCT
eurjchem-1549	102	60	145.96	145.96	NUM
eurjchem-1549	102	61	,	,	PUNCT
eurjchem-1549	102	62	148.85	148.85	NUM
eurjchem-1549	102	63	,	,	PUNCT
eurjchem-1549	102	64	153.38	153.38	NUM
eurjchem-1549	102	65	(	(	PUNCT
eurjchem-1549	102	66	d	d	PROPN
eurjchem-1549	102	67	,	,	PUNCT
eurjchem-1549	102	68	j	j	PROPN
eurjchem-1549	102	69	=	=	SYM
eurjchem-1549	102	70	246	246	NUM
eurjchem-1549	102	71	hz	hz	NOUN
eurjchem-1549	102	72	)	)	PUNCT
eurjchem-1549	102	73	,	,	PUNCT
eurjchem-1549	102	74	166.50	166.50	NUM
eurjchem-1549	102	75	,	,	PUNCT
eurjchem-1549	102	76	170.61	170.61	NUM
eurjchem-1549	102	77	,	,	PUNCT
eurjchem-1549	102	78	176.65	176.65	NUM
eurjchem-1549	102	79	.	.	PUNCT
eurjchem-1549	103	1	hrms	hrm	NOUN
eurjchem-1549	103	2	(	(	PUNCT
eurjchem-1549	103	3	esi	esi	PROPN
eurjchem-1549	103	4	,	,	PUNCT
eurjchem-1549	103	5	m	m	PROPN
eurjchem-1549	103	6	/	/	SYM
eurjchem-1549	103	7	z	z	ADJ
eurjchem-1549	103	8	)	)	PUNCT
eurjchem-1549	103	9	calcd	calcd	NOUN
eurjchem-1549	103	10	.	.	PUNCT
eurjchem-1549	104	1	for	for	ADP
eurjchem-1549	104	2	c27h29fn5o5	c27h29fn5o5	NOUN
eurjchem-1549	104	3	[	[	X
eurjchem-1549	104	4	m‐h]¯	m‐h]¯	NOUN
eurjchem-1549	104	5	:	:	PUNCT
eurjchem-1549	104	6	522.21582	522.21582	NUM
eurjchem-1549	104	7	,	,	PUNCT
eurjchem-1549	104	8	found	find	VERB
eurjchem-1549	104	9	:	:	PUNCT
eurjchem-1549	104	10	522.21606	522.21606	NUM
eurjchem-1549	104	11	.	.	PUNCT
eurjchem-1549	105	1	2.3	2.3	NUM
eurjchem-1549	105	2	.	.	PUNCT
eurjchem-1549	106	1	in	in	ADP
eurjchem-1549	106	2	vitro	vitro	X
eurjchem-1549	106	3	determination	determination	NOUN
eurjchem-1549	106	4	of	of	ADP
eurjchem-1549	106	5	nitric	nitric	ADJ
eurjchem-1549	106	6	oxide	oxide	NOUN
eurjchem-1549	106	7	release	release	NOUN
eurjchem-1549	106	8	2.3.1	2.3.1	NUM
eurjchem-1549	106	9	.	.	PUNCT
eurjchem-1549	106	10	materials	material	NOUN
eurjchem-1549	106	11	and	and	CCONJ
eurjchem-1549	106	12	methods	method	NOUN
eurjchem-1549	106	13	all	all	DET
eurjchem-1549	106	14	measurements	measurement	NOUN
eurjchem-1549	106	15	were	be	AUX
eurjchem-1549	106	16	carried	carry	VERB
eurjchem-1549	106	17	out	out	ADP
eurjchem-1549	106	18	using	use	VERB
eurjchem-1549	106	19	uv‐visible	uv‐visible	ADJ
eurjchem-1549	106	20	spectrophotometer	spectrophotometer	NOUN
eurjchem-1549	106	21	(	(	PUNCT
eurjchem-1549	106	22	implen	implen	PROPN
eurjchem-1549	106	23	nanophotometer	nanophotometer	PROPN
eurjchem-1549	106	24	,	,	PUNCT
eurjchem-1549	106	25	germany	germany	PROPN
eurjchem-1549	106	26	)	)	PUNCT
eurjchem-1549	106	27	.	.	PUNCT
eurjchem-1549	107	1	nitrite	nitrite	NOUN
eurjchem-1549	107	2	stock	stock	NOUN
eurjchem-1549	107	3	aqueous	aqueous	ADJ
eurjchem-1549	107	4	solution	solution	NOUN
eurjchem-1549	107	5	(	(	PUNCT
eurjchem-1549	107	6	0.1	0.1	NUM
eurjchem-1549	107	7	m	m	NOUN
eurjchem-1549	107	8	sodium	sodium	NOUN
eurjchem-1549	107	9	nitrite	nitrite	NOUN
eurjchem-1549	107	10	in	in	ADP
eurjchem-1549	107	11	water	water	NOUN
eurjchem-1549	107	12	)	)	PUNCT
eurjchem-1549	107	13	was	be	AUX
eurjchem-1549	107	14	prepared	prepare	VERB
eurjchem-1549	107	15	from	from	ADP
eurjchem-1549	107	16	which	which	PRON
eurjchem-1549	107	17	a	a	DET
eurjchem-1549	107	18	dilute	dilute	NOUN
eurjchem-1549	107	19	solution	solution	NOUN
eurjchem-1549	107	20	of	of	ADP
eurjchem-1549	107	21	100	100	NUM
eurjchem-1549	107	22	μm	μm	NUM
eurjchem-1549	107	23	nitrite	nitrite	NOUN
eurjchem-1549	107	24	solution	solution	NOUN
eurjchem-1549	107	25	was	be	AUX
eurjchem-1549	107	26	prepared	prepare	VERB
eurjchem-1549	107	27	by	by	ADP
eurjchem-1549	107	28	diluting	dilute	VERB
eurjchem-1549	107	29	1	1	NUM
eurjchem-1549	107	30	ml	ml	NOUN
eurjchem-1549	107	31	of	of	ADP
eurjchem-1549	107	32	the	the	DET
eurjchem-1549	107	33	stock	stock	NOUN
eurjchem-1549	107	34	solution	solution	NOUN
eurjchem-1549	107	35	to	to	ADP
eurjchem-1549	107	36	1000	1000	NUM
eurjchem-1549	107	37	ml	ml	NOUN
eurjchem-1549	107	38	with	with	ADP
eurjchem-1549	107	39	phosphate	phosphate	ADJ
eurjchem-1549	107	40	buffer	buffer	NOUN
eurjchem-1549	107	41	of	of	ADP
eurjchem-1549	107	42	ph	ph	NOUN
eurjchem-1549	107	43	=	=	NOUN
eurjchem-1549	107	44	7.4	7.4	NUM
eurjchem-1549	107	45	.	.	PUNCT
eurjchem-1549	108	1	working	work	VERB
eurjchem-1549	108	2	standard	standard	ADJ
eurjchem-1549	108	3	solutions	solution	NOUN
eurjchem-1549	108	4	containing	contain	VERB
eurjchem-1549	108	5	different	different	ADJ
eurjchem-1549	108	6	concentrations	concentration	NOUN
eurjchem-1549	108	7	of	of	ADP
eurjchem-1549	108	8	the	the	DET
eurjchem-1549	108	9	nitrite	nitrite	NOUN
eurjchem-1549	108	10	(	(	PUNCT
eurjchem-1549	108	11	100	100	NUM
eurjchem-1549	108	12	,	,	PUNCT
eurjchem-1549	108	13	50	50	NUM
eurjchem-1549	108	14	,	,	PUNCT
eurjchem-1549	108	15	25.00	25.00	NUM
eurjchem-1549	108	16	,	,	PUNCT
eurjchem-1549	108	17	12.50	12.50	NUM
eurjchem-1549	108	18	,	,	PUNCT
eurjchem-1549	108	19	6.25	6.25	NUM
eurjchem-1549	108	20	,	,	PUNCT
eurjchem-1549	108	21	3.125	3.125	NUM
eurjchem-1549	108	22	,	,	PUNCT
eurjchem-1549	108	23	1.56	1.56	NUM
eurjchem-1549	108	24	,	,	PUNCT
eurjchem-1549	108	25	0.78	0.78	NUM
eurjchem-1549	108	26	and	and	CCONJ
eurjchem-1549	108	27	0.39	0.39	NUM
eurjchem-1549	108	28	μm	μm	NUM
eurjchem-1549	108	29	)	)	PUNCT
eurjchem-1549	108	30	were	be	AUX
eurjchem-1549	108	31	prepared	prepare	VERB
eurjchem-1549	108	32	by	by	ADP
eurjchem-1549	108	33	further	further	ADJ
eurjchem-1549	108	34	dilution	dilution	NOUN
eurjchem-1549	108	35	of	of	ADP
eurjchem-1549	108	36	the	the	DET
eurjchem-1549	108	37	later	later	ADJ
eurjchem-1549	108	38	solution	solution	NOUN
eurjchem-1549	108	39	with	with	ADP
eurjchem-1549	108	40	phosphate	phosphate	ADJ
eurjchem-1549	108	41	buffer	buffer	NOUN
eurjchem-1549	108	42	.	.	PUNCT
eurjchem-1549	109	1	the	the	DET
eurjchem-1549	109	2	tested	test	VERB
eurjchem-1549	109	3	compounds	compound	NOUN
eurjchem-1549	109	4	were	be	AUX
eurjchem-1549	109	5	dissolved	dissolve	VERB
eurjchem-1549	109	6	in	in	ADP
eurjchem-1549	109	7	dmf	dmf	PROPN
eurjchem-1549	109	8	and	and	CCONJ
eurjchem-1549	109	9	diluted	dilute	VERB
eurjchem-1549	109	10	with	with	ADP
eurjchem-1549	109	11	the	the	DET
eurjchem-1549	109	12	buffer	buffer	NOUN
eurjchem-1549	109	13	system	system	NOUN
eurjchem-1549	109	14	to	to	PART
eurjchem-1549	109	15	afford	afford	VERB
eurjchem-1549	109	16	a	a	DET
eurjchem-1549	109	17	concentration	concentration	NOUN
eurjchem-1549	109	18	of	of	ADP
eurjchem-1549	109	19	100	100	NUM
eurjchem-1549	109	20	μm	μm	NUM
eurjchem-1549	109	21	.	.	PUNCT
eurjchem-1549	109	22	n‐acetyl	n‐acetyl	PUNCT
eurjchem-1549	109	23	cysteine	cysteine	NOUN
eurjchem-1549	109	24	solution	solution	NOUN
eurjchem-1549	109	25	was	be	AUX
eurjchem-1549	109	26	prepared	prepare	VERB
eurjchem-1549	109	27	in	in	ADP
eurjchem-1549	109	28	a	a	DET
eurjchem-1549	109	29	concentration	concentration	NOUN
eurjchem-1549	109	30	of	of	ADP
eurjchem-1549	109	31	500	500	NUM
eurjchem-1549	109	32	μm	μm	NOUN
eurjchem-1549	109	33	in	in	ADP
eurjchem-1549	109	34	methanol	methanol	NOUN
eurjchem-1549	109	35	.	.	PUNCT
eurjchem-1549	110	1	122	122	NUM
eurjchem-1549	110	2	aziz	aziz	PROPN
eurjchem-1549	110	3	et	et	PROPN
eurjchem-1549	110	4	al	al	PROPN
eurjchem-1549	110	5	.	.	PUNCT
eurjchem-1549	110	6	/	/	SYM
eurjchem-1549	110	7	european	european	PROPN
eurjchem-1549	110	8	journal	journal	PROPN
eurjchem-1549	110	9	of	of	ADP
eurjchem-1549	110	10	chemistry	chemistry	NOUN
eurjchem-1549	110	11	8	8	NUM
eurjchem-1549	110	12	(	(	PUNCT
eurjchem-1549	110	13	2	2	NUM
eurjchem-1549	110	14	)	)	PUNCT
eurjchem-1549	110	15	(	(	PUNCT
eurjchem-1549	110	16	2017	2017	NUM
eurjchem-1549	110	17	)	)	PUNCT
eurjchem-1549	110	18	119‐124	119‐124	PROPN
eurjchem-1549	110	19	figure	figure	NOUN
eurjchem-1549	110	20	1	1	NUM
eurjchem-1549	110	21	.	.	PUNCT
eurjchem-1549	110	22	resonance	resonance	NOUN
eurjchem-1549	110	23	stabilization	stabilization	NOUN
eurjchem-1549	110	24	and	and	CCONJ
eurjchem-1549	110	25	increased	increase	VERB
eurjchem-1549	110	26	diazonium	diazonium	NOUN
eurjchem-1549	110	27	cations	cation	NOUN
eurjchem-1549	110	28	'	'	PART
eurjchem-1549	110	29	electrophilicity	electrophilicity	NOUN
eurjchem-1549	110	30	by	by	ADP
eurjchem-1549	110	31	electron‐withdrawing	electron‐withdrawe	VERB
eurjchem-1549	110	32	substituents	substituent	NOUN
eurjchem-1549	110	33	.	.	PUNCT
eurjchem-1549	111	1	the	the	DET
eurjchem-1549	111	2	modified	modify	VERB
eurjchem-1549	111	3	griess	griess	NOUN
eurjchem-1549	111	4	reagent	reagent	NOUN
eurjchem-1549	111	5	consists	consist	VERB
eurjchem-1549	111	6	of	of	ADP
eurjchem-1549	111	7	0.1	0.1	NUM
eurjchem-1549	111	8	%	%	NOUN
eurjchem-1549	111	9	(	(	PUNCT
eurjchem-1549	111	10	w	w	NOUN
eurjchem-1549	111	11	:	:	SYM
eurjchem-1549	111	12	v	v	NOUN
eurjchem-1549	111	13	)	)	PUNCT
eurjchem-1549	111	14	n‐(1‐	n‐(1‐	PROPN
eurjchem-1549	111	15	naphthyl)ethylenediamine	naphthyl)ethylenediamine	PROPN
eurjchem-1549	111	16	(	(	PUNCT
eurjchem-1549	111	17	ned	ned	ADJ
eurjchem-1549	111	18	)	)	PUNCT
eurjchem-1549	111	19	solution	solution	NOUN
eurjchem-1549	111	20	in	in	ADP
eurjchem-1549	111	21	water	water	NOUN
eurjchem-1549	111	22	and	and	CCONJ
eurjchem-1549	111	23	4‐	4‐	NUM
eurjchem-1549	111	24	nitroaniline	nitroaniline	NOUN
eurjchem-1549	111	25	solution	solution	NOUN
eurjchem-1549	111	26	(	(	PUNCT
eurjchem-1549	111	27	0.5	0.5	NUM
eurjchem-1549	111	28	%	%	NOUN
eurjchem-1549	111	29	w	w	NOUN
eurjchem-1549	111	30	:	:	PUNCT
eurjchem-1549	111	31	v	v	NOUN
eurjchem-1549	111	32	of	of	ADP
eurjchem-1549	111	33	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	111	34	in	in	ADP
eurjchem-1549	111	35	5	5	NUM
eurjchem-1549	111	36	%	%	NOUN
eurjchem-1549	111	37	w	w	NOUN
eurjchem-1549	111	38	:	:	PUNCT
eurjchem-1549	111	39	v	v	ADJ
eurjchem-1549	111	40	phosphoric	phosphoric	NOUN
eurjchem-1549	111	41	acid	acid	NOUN
eurjchem-1549	111	42	)	)	PUNCT
eurjchem-1549	111	43	.	.	PUNCT
eurjchem-1549	112	1	2.3.2	2.3.2	X
eurjchem-1549	112	2	.	.	PUNCT
eurjchem-1549	112	3	preparation	preparation	NOUN
eurjchem-1549	112	4	of	of	ADP
eurjchem-1549	112	5	nitrite	nitrite	PROPN
eurjchem-1549	112	6	standard	standard	PROPN
eurjchem-1549	112	7	curve	curve	VERB
eurjchem-1549	112	8	an	an	DET
eurjchem-1549	112	9	aliquot	aliquot	NOUN
eurjchem-1549	112	10	of	of	ADP
eurjchem-1549	112	11	100	100	NUM
eurjchem-1549	112	12	μl	μl	ADP
eurjchem-1549	112	13	of	of	ADP
eurjchem-1549	112	14	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	112	15	solution	solution	NOUN
eurjchem-1549	112	16	was	be	AUX
eurjchem-1549	112	17	added	add	VERB
eurjchem-1549	112	18	to	to	ADP
eurjchem-1549	112	19	the	the	DET
eurjchem-1549	112	20	working	work	VERB
eurjchem-1549	112	21	standard	standard	ADJ
eurjchem-1549	112	22	nitrite	nitrite	NOUN
eurjchem-1549	112	23	solution	solution	NOUN
eurjchem-1549	112	24	.	.	PUNCT
eurjchem-1549	113	1	after	after	ADP
eurjchem-1549	113	2	1	1	NUM
eurjchem-1549	113	3	minute	minute	NOUN
eurjchem-1549	113	4	,	,	PUNCT
eurjchem-1549	113	5	100	100	NUM
eurjchem-1549	113	6	μl	μl	ADP
eurjchem-1549	113	7	of	of	ADP
eurjchem-1549	113	8	the	the	DET
eurjchem-1549	113	9	ned	ned	ADJ
eurjchem-1549	113	10	solution	solution	NOUN
eurjchem-1549	113	11	was	be	AUX
eurjchem-1549	113	12	added	add	VERB
eurjchem-1549	113	13	and	and	CCONJ
eurjchem-1549	113	14	absorbance	absorbance	NOUN
eurjchem-1549	113	15	of	of	ADP
eurjchem-1549	113	16	the	the	DET
eurjchem-1549	113	17	formed	form	VERB
eurjchem-1549	113	18	purple	purple	ADJ
eurjchem-1549	113	19	colour	colour	NOUN
eurjchem-1549	113	20	was	be	AUX
eurjchem-1549	113	21	measured	measure	VERB
eurjchem-1549	113	22	after	after	ADP
eurjchem-1549	113	23	10	10	NUM
eurjchem-1549	113	24	minutes	minute	NOUN
eurjchem-1549	113	25	at	at	ADP
eurjchem-1549	113	26	max	max	NUM
eurjchem-1549	113	27	539	539	NUM
eurjchem-1549	113	28	nm	nm	NOUN
eurjchem-1549	113	29	.	.	PUNCT
eurjchem-1549	114	1	a	a	DET
eurjchem-1549	114	2	blank	blank	ADJ
eurjchem-1549	114	3	experiment	experiment	NOUN
eurjchem-1549	114	4	was	be	AUX
eurjchem-1549	114	5	performed	perform	VERB
eurjchem-1549	114	6	under	under	ADP
eurjchem-1549	114	7	the	the	DET
eurjchem-1549	114	8	same	same	ADJ
eurjchem-1549	114	9	conditions	condition	NOUN
eurjchem-1549	114	10	.	.	PUNCT
eurjchem-1549	115	1	the	the	DET
eurjchem-1549	115	2	procedure	procedure	NOUN
eurjchem-1549	115	3	was	be	AUX
eurjchem-1549	115	4	repeated	repeat	VERB
eurjchem-1549	115	5	three	three	NUM
eurjchem-1549	115	6	times	time	NOUN
eurjchem-1549	115	7	for	for	ADP
eurjchem-1549	115	8	each	each	DET
eurjchem-1549	115	9	concentration	concentration	NOUN
eurjchem-1549	115	10	of	of	ADP
eurjchem-1549	115	11	the	the	DET
eurjchem-1549	115	12	nitrite	nitrite	NOUN
eurjchem-1549	115	13	and	and	CCONJ
eurjchem-1549	115	14	the	the	DET
eurjchem-1549	115	15	average	average	ADJ
eurjchem-1549	115	16	absorbance	absorbance	NOUN
eurjchem-1549	115	17	was	be	AUX
eurjchem-1549	115	18	calculated	calculate	VERB
eurjchem-1549	115	19	.	.	PUNCT
eurjchem-1549	116	1	the	the	DET
eurjchem-1549	116	2	calibration	calibration	NOUN
eurjchem-1549	116	3	curve	curve	NOUN
eurjchem-1549	116	4	was	be	AUX
eurjchem-1549	116	5	constructed	construct	VERB
eurjchem-1549	116	6	by	by	ADP
eurjchem-1549	116	7	plotting	plot	VERB
eurjchem-1549	116	8	the	the	DET
eurjchem-1549	116	9	average	average	ADJ
eurjchem-1549	116	10	absorbance	absorbance	NOUN
eurjchem-1549	116	11	value	value	NOUN
eurjchem-1549	116	12	against	against	ADP
eurjchem-1549	116	13	the	the	DET
eurjchem-1549	116	14	corresponding	corresponding	ADJ
eurjchem-1549	116	15	nitrite	nitrite	NOUN
eurjchem-1549	116	16	concentration	concentration	NOUN
eurjchem-1549	116	17	.	.	PUNCT
eurjchem-1549	117	1	2.3.3	2.3.3	X
eurjchem-1549	117	2	.	.	PUNCT
eurjchem-1549	118	1	no	no	DET
eurjchem-1549	118	2	release	release	NOUN
eurjchem-1549	118	3	assay	assay	NOUN
eurjchem-1549	118	4	solutions	solution	NOUN
eurjchem-1549	118	5	of	of	ADP
eurjchem-1549	118	6	the	the	DET
eurjchem-1549	118	7	tested	test	VERB
eurjchem-1549	118	8	compounds	compound	NOUN
eurjchem-1549	118	9	3	3	NUM
eurjchem-1549	118	10	and	and	CCONJ
eurjchem-1549	118	11	7	7	NUM
eurjchem-1549	118	12	in	in	ADP
eurjchem-1549	118	13	dmf	dmf	PROPN
eurjchem-1549	118	14	were	be	AUX
eurjchem-1549	118	15	diluted	dilute	VERB
eurjchem-1549	118	16	with	with	ADP
eurjchem-1549	118	17	phosphate	phosphate	ADJ
eurjchem-1549	118	18	buffer	buffer	NOUN
eurjchem-1549	118	19	of	of	ADP
eurjchem-1549	118	20	ph	ph	NOUN
eurjchem-1549	118	21	=	=	NOUN
eurjchem-1549	118	22	7.4	7.4	NUM
eurjchem-1549	118	23	to	to	PART
eurjchem-1549	118	24	give	give	VERB
eurjchem-1549	118	25	a	a	DET
eurjchem-1549	118	26	final	final	ADJ
eurjchem-1549	118	27	concentration	concentration	NOUN
eurjchem-1549	118	28	of	of	ADP
eurjchem-1549	118	29	100	100	NUM
eurjchem-1549	118	30	μm	μm	NOUN
eurjchem-1549	118	31	(	(	PUNCT
eurjchem-1549	118	32	test	test	NOUN
eurjchem-1549	118	33	solutions	solution	NOUN
eurjchem-1549	118	34	)	)	PUNCT
eurjchem-1549	118	35	.	.	PUNCT
eurjchem-1549	119	1	to	to	ADP
eurjchem-1549	119	2	100	100	NUM
eurjchem-1549	119	3	μl	μl	ADP
eurjchem-1549	119	4	of	of	ADP
eurjchem-1549	119	5	each	each	DET
eurjchem-1549	119	6	test	test	NOUN
eurjchem-1549	119	7	solutions	solution	NOUN
eurjchem-1549	119	8	,	,	PUNCT
eurjchem-1549	119	9	100	100	NUM
eurjchem-1549	119	10	μl	μl	ADP
eurjchem-1549	119	11	of	of	ADP
eurjchem-1549	119	12	n‐acetyl	n‐acetyl	PUNCT
eurjchem-1549	119	13	cysteine	cysteine	NOUN
eurjchem-1549	119	14	solution	solution	NOUN
eurjchem-1549	119	15	was	be	AUX
eurjchem-1549	119	16	added	add	VERB
eurjchem-1549	119	17	and	and	CCONJ
eurjchem-1549	119	18	the	the	DET
eurjchem-1549	119	19	obtained	obtain	VERB
eurjchem-1549	119	20	solution	solution	NOUN
eurjchem-1549	119	21	was	be	AUX
eurjchem-1549	119	22	kept	keep	VERB
eurjchem-1549	119	23	in	in	ADP
eurjchem-1549	119	24	an	an	DET
eurjchem-1549	119	25	incubator	incubator	NOUN
eurjchem-1549	119	26	at	at	ADP
eurjchem-1549	119	27	37	37	NUM
eurjchem-1549	119	28	c	c	NOUN
eurjchem-1549	119	29	(	(	PUNCT
eurjchem-1549	119	30	treated	treat	VERB
eurjchem-1549	119	31	solutions	solution	NOUN
eurjchem-1549	119	32	)	)	PUNCT
eurjchem-1549	119	33	.	.	PUNCT
eurjchem-1549	120	1	the	the	DET
eurjchem-1549	120	2	solutions	solution	NOUN
eurjchem-1549	120	3	were	be	AUX
eurjchem-1549	120	4	treated	treat	VERB
eurjchem-1549	120	5	similarly	similarly	ADV
eurjchem-1549	120	6	;	;	PUNCT
eurjchem-1549	120	7	as	as	ADP
eurjchem-1549	120	8	for	for	ADP
eurjchem-1549	120	9	nitrite	nitrite	NOUN
eurjchem-1549	120	10	standard	standard	ADJ
eurjchem-1549	120	11	solution	solution	NOUN
eurjchem-1549	120	12	;	;	PUNCT
eurjchem-1549	120	13	with	with	ADP
eurjchem-1549	120	14	100	100	NUM
eurjchem-1549	120	15	μl	μl	ADP
eurjchem-1549	120	16	of	of	ADP
eurjchem-1549	120	17	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	120	18	.	.	PUNCT
eurjchem-1549	121	1	then	then	ADV
eurjchem-1549	121	2	,	,	PUNCT
eurjchem-1549	121	3	we	we	PRON
eurjchem-1549	121	4	just	just	ADV
eurjchem-1549	121	5	waited	wait	VERB
eurjchem-1549	121	6	for	for	ADP
eurjchem-1549	121	7	one	one	NUM
eurjchem-1549	121	8	minute	minute	NOUN
eurjchem-1549	121	9	after	after	ADP
eurjchem-1549	121	10	adding	add	VERB
eurjchem-1549	121	11	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	121	12	and	and	CCONJ
eurjchem-1549	121	13	for	for	ADP
eurjchem-1549	121	14	additional	additional	ADJ
eurjchem-1549	121	15	10	10	NUM
eurjchem-1549	121	16	minute	minute	NOUN
eurjchem-1549	121	17	after	after	ADP
eurjchem-1549	121	18	adding	add	VERB
eurjchem-1549	121	19	ned	ned	ADJ
eurjchem-1549	121	20	reagent	reagent	NOUN
eurjchem-1549	121	21	and	and	CCONJ
eurjchem-1549	121	22	the	the	DET
eurjchem-1549	121	23	absorbance	absorbance	NOUN
eurjchem-1549	121	24	were	be	AUX
eurjchem-1549	121	25	as	as	ADP
eurjchem-1549	121	26	recorded	record	VERB
eurjchem-1549	121	27	at	at	ADP
eurjchem-1549	121	28	max	max	NUM
eurjchem-1549	121	29	539	539	NUM
eurjchem-1549	121	30	nm	nm	NOUN
eurjchem-1549	121	31	every	every	DET
eurjchem-1549	121	32	10	10	NUM
eurjchem-1549	121	33	minutes	minute	NOUN
eurjchem-1549	121	34	over	over	ADP
eurjchem-1549	121	35	a	a	DET
eurjchem-1549	121	36	period	period	NOUN
eurjchem-1549	121	37	of	of	ADP
eurjchem-1549	121	38	one	one	NUM
eurjchem-1549	121	39	hr	hr	NOUN
eurjchem-1549	121	40	.	.	PUNCT
eurjchem-1549	122	1	a	a	DET
eurjchem-1549	122	2	blank	blank	ADJ
eurjchem-1549	122	3	experiment	experiment	NOUN
eurjchem-1549	122	4	was	be	AUX
eurjchem-1549	122	5	performed	perform	VERB
eurjchem-1549	122	6	under	under	ADP
eurjchem-1549	122	7	the	the	DET
eurjchem-1549	122	8	same	same	ADJ
eurjchem-1549	122	9	conditions	condition	NOUN
eurjchem-1549	122	10	,	,	PUNCT
eurjchem-1549	122	11	the	the	DET
eurjchem-1549	122	12	procedure	procedure	NOUN
eurjchem-1549	122	13	was	be	AUX
eurjchem-1549	122	14	repeated	repeat	VERB
eurjchem-1549	122	15	three	three	NUM
eurjchem-1549	122	16	times	time	NOUN
eurjchem-1549	122	17	for	for	ADP
eurjchem-1549	122	18	each	each	DET
eurjchem-1549	122	19	tested	test	VERB
eurjchem-1549	122	20	compound	compound	NOUN
eurjchem-1549	122	21	and	and	CCONJ
eurjchem-1549	122	22	the	the	DET
eurjchem-1549	122	23	average	average	ADJ
eurjchem-1549	122	24	absorbance	absorbance	NOUN
eurjchem-1549	122	25	was	be	AUX
eurjchem-1549	122	26	calculated	calculate	VERB
eurjchem-1549	122	27	.	.	PUNCT
eurjchem-1549	123	1	the	the	DET
eurjchem-1549	123	2	corresponding	corresponding	ADJ
eurjchem-1549	123	3	concentration	concentration	NOUN
eurjchem-1549	123	4	of	of	ADP
eurjchem-1549	123	5	nitrite	nitrite	NOUN
eurjchem-1549	123	6	was	be	AUX
eurjchem-1549	123	7	determined	determine	VERB
eurjchem-1549	123	8	by	by	ADP
eurjchem-1549	123	9	comparison	comparison	NOUN
eurjchem-1549	123	10	to	to	ADP
eurjchem-1549	123	11	the	the	DET
eurjchem-1549	123	12	nitrite	nitrite	NOUN
eurjchem-1549	123	13	standard	standard	ADJ
eurjchem-1549	123	14	calibration	calibration	NOUN
eurjchem-1549	123	15	curve	curve	NOUN
eurjchem-1549	123	16	and	and	CCONJ
eurjchem-1549	123	17	the	the	DET
eurjchem-1549	123	18	amount	amount	NOUN
eurjchem-1549	123	19	of	of	ADP
eurjchem-1549	123	20	no	no	DET
eurjchem-1549	123	21	released	release	VERB
eurjchem-1549	123	22	(	(	PUNCT
eurjchem-1549	123	23	revealed	reveal	VERB
eurjchem-1549	123	24	by	by	ADP
eurjchem-1549	123	25	the	the	DET
eurjchem-1549	123	26	corresponding	corresponding	ADJ
eurjchem-1549	123	27	nitrite	nitrite	NOUN
eurjchem-1549	123	28	concentration	concentration	NOUN
eurjchem-1549	123	29	)	)	PUNCT
eurjchem-1549	123	30	was	be	AUX
eurjchem-1549	123	31	calculated	calculate	VERB
eurjchem-1549	123	32	as	as	ADP
eurjchem-1549	123	33	percentage	percentage	NOUN
eurjchem-1549	123	34	of	of	ADP
eurjchem-1549	123	35	moles	mole	NOUN
eurjchem-1549	123	36	of	of	ADP
eurjchem-1549	123	37	no	no	PRON
eurjchem-1549	123	38	released	release	VERB
eurjchem-1549	123	39	from	from	ADP
eurjchem-1549	123	40	1	1	NUM
eurjchem-1549	123	41	mole	mole	NOUN
eurjchem-1549	123	42	of	of	ADP
eurjchem-1549	123	43	tested	test	VERB
eurjchem-1549	123	44	compound	compound	NOUN
eurjchem-1549	123	45	.	.	PUNCT
eurjchem-1549	124	1	3	3	X
eurjchem-1549	124	2	.	.	X
eurjchem-1549	124	3	results	result	NOUN
eurjchem-1549	124	4	and	and	CCONJ
eurjchem-1549	124	5	discussion	discussion	NOUN
eurjchem-1549	124	6	3.1	3.1	NUM
eurjchem-1549	124	7	.	.	PUNCT
eurjchem-1549	125	1	synthesis	synthesis	NOUN
eurjchem-1549	125	2	of	of	ADP
eurjchem-1549	125	3	norfloxacin‐no	norfloxacin‐no	PROPN
eurjchem-1549	125	4	donor	donor	NOUN
eurjchem-1549	125	5	hybrids	hybrid	NOUN
eurjchem-1549	125	6	the	the	DET
eurjchem-1549	125	7	synthesis	synthesis	NOUN
eurjchem-1549	125	8	of	of	ADP
eurjchem-1549	125	9	the	the	DET
eurjchem-1549	125	10	target	target	NOUN
eurjchem-1549	125	11	hybrids	hybrid	NOUN
eurjchem-1549	125	12	3	3	NUM
eurjchem-1549	125	13	and	and	CCONJ
eurjchem-1549	125	14	7	7	NUM
eurjchem-1549	125	15	(	(	PUNCT
eurjchem-1549	125	16	scheme	scheme	NOUN
eurjchem-1549	125	17	1	1	NUM
eurjchem-1549	125	18	)	)	PUNCT
eurjchem-1549	125	19	commenced	commence	VERB
eurjchem-1549	125	20	with	with	ADP
eurjchem-1549	125	21	the	the	DET
eurjchem-1549	125	22	base‐promoted	base‐promote	VERB
eurjchem-1549	125	23	acylation	acylation	NOUN
eurjchem-1549	125	24	of	of	ADP
eurjchem-1549	125	25	norfloxacin	norfloxacin	PROPN
eurjchem-1549	125	26	(	(	PUNCT
eurjchem-1549	125	27	1	1	NUM
eurjchem-1549	125	28	)	)	PUNCT
eurjchem-1549	125	29	with	with	ADP
eurjchem-1549	125	30	bromoacetyl	bromoacetyl	PROPN
eurjchem-1549	125	31	bromide	bromide	NOUN
eurjchem-1549	125	32	followed	follow	VERB
eurjchem-1549	125	33	by	by	ADP
eurjchem-1549	125	34	treating	treat	VERB
eurjchem-1549	125	35	the	the	DET
eurjchem-1549	125	36	resultant	resultant	NOUN
eurjchem-1549	125	37	bromide	bromide	NOUN
eurjchem-1549	125	38	2	2	NUM
eurjchem-1549	125	39	with	with	ADP
eurjchem-1549	125	40	silver	silver	ADJ
eurjchem-1549	125	41	nitrate	nitrate	NOUN
eurjchem-1549	125	42	to	to	PART
eurjchem-1549	125	43	afford	afford	VERB
eurjchem-1549	125	44	nitrate	nitrate	NOUN
eurjchem-1549	125	45	ester	ester	NOUN
eurjchem-1549	125	46	3	3	NUM
eurjchem-1549	125	47	.	.	PUNCT
eurjchem-1549	126	1	the	the	DET
eurjchem-1549	126	2	ir	ir	PROPN
eurjchem-1549	126	3	spectrum	spectrum	NOUN
eurjchem-1549	126	4	of	of	ADP
eurjchem-1549	126	5	nitrate	nitrate	NOUN
eurjchem-1549	126	6	ester	ester	NOUN
eurjchem-1549	126	7	3	3	NUM
eurjchem-1549	126	8	showed	show	VERB
eurjchem-1549	126	9	asymmetric	asymmetric	ADJ
eurjchem-1549	126	10	stretching	stretch	VERB
eurjchem-1549	126	11	band	band	NOUN
eurjchem-1549	126	12	of	of	ADP
eurjchem-1549	126	13	ono2	ono2	PROPN
eurjchem-1549	126	14	at	at	ADP
eurjchem-1549	126	15	1544	1544	NUM
eurjchem-1549	126	16	cm‐1	cm‐1	NOUN
eurjchem-1549	126	17	and	and	CCONJ
eurjchem-1549	126	18	symmetric	symmetric	ADJ
eurjchem-1549	126	19	stretching	stretch	VERB
eurjchem-1549	126	20	at	at	ADP
eurjchem-1549	126	21	1294	1294	NUM
eurjchem-1549	126	22	cm‐1	cm‐1	NOUN
eurjchem-1549	126	23	.	.	PUNCT
eurjchem-1549	127	1	comparison	comparison	NOUN
eurjchem-1549	127	2	of	of	ADP
eurjchem-1549	127	3	1h	1h	NUM
eurjchem-1549	127	4	nmr	nmr	NOUN
eurjchem-1549	127	5	spectra	spectra	NOUN
eurjchem-1549	127	6	of	of	ADP
eurjchem-1549	127	7	the	the	DET
eurjchem-1549	127	8	prepared	prepared	ADJ
eurjchem-1549	127	9	nitrate	nitrate	NOUN
eurjchem-1549	127	10	ester	ester	NOUN
eurjchem-1549	127	11	3	3	NUM
eurjchem-1549	127	12	with	with	ADP
eurjchem-1549	127	13	its	its	PRON
eurjchem-1549	127	14	corresponding	corresponding	ADJ
eurjchem-1549	127	15	bromide	bromide	NOUN
eurjchem-1549	127	16	2	2	NUM
eurjchem-1549	127	17	showed	show	VERB
eurjchem-1549	127	18	that	that	DET
eurjchem-1549	127	19	replacement	replacement	NOUN
eurjchem-1549	127	20	of	of	ADP
eurjchem-1549	127	21	bromine	bromine	NOUN
eurjchem-1549	127	22	in	in	ADP
eurjchem-1549	127	23	compound	compound	NOUN
eurjchem-1549	127	24	2	2	NUM
eurjchem-1549	127	25	by	by	ADP
eurjchem-1549	127	26	nitrate	nitrate	NOUN
eurjchem-1549	127	27	in	in	ADP
eurjchem-1549	127	28	compound	compound	NOUN
eurjchem-1549	127	29	3	3	NUM
eurjchem-1549	127	30	leads	lead	VERB
eurjchem-1549	127	31	to	to	ADP
eurjchem-1549	127	32	a	a	DET
eurjchem-1549	127	33	remarkable	remarkable	ADJ
eurjchem-1549	127	34	downfield	downfield	NOUN
eurjchem-1549	127	35	shift	shift	NOUN
eurjchem-1549	127	36	of	of	ADP
eurjchem-1549	127	37	methylene	methylene	ADJ
eurjchem-1549	127	38	ch2ono2	ch2ono2	PROPN
eurjchem-1549	127	39	protons	proton	NOUN
eurjchem-1549	127	40	by	by	ADP
eurjchem-1549	127	41	δ	δ	PROPN
eurjchem-1549	127	42	1.26	1.26	NUM
eurjchem-1549	127	43	ppm	ppm	NOUN
eurjchem-1549	127	44	,	,	PUNCT
eurjchem-1549	127	45	13c	13c	NOUN
eurjchem-1549	127	46	nmr	nmr	NOUN
eurjchem-1549	127	47	spectrum	spectrum	NOUN
eurjchem-1549	127	48	of	of	ADP
eurjchem-1549	127	49	compound	compound	NOUN
eurjchem-1549	127	50	3	3	NUM
eurjchem-1549	127	51	showed	show	VERB
eurjchem-1549	127	52	shift	shift	NOUN
eurjchem-1549	127	53	of	of	ADP
eurjchem-1549	127	54	carbon	carbon	NOUN
eurjchem-1549	127	55	by	by	ADP
eurjchem-1549	127	56	δ	δ	PROPN
eurjchem-1549	127	57	41.03	41.03	NUM
eurjchem-1549	127	58	ppm	ppm	NOUN
eurjchem-1549	127	59	due	due	ADP
eurjchem-1549	127	60	to	to	ADP
eurjchem-1549	127	61	replacement	replacement	NOUN
eurjchem-1549	127	62	of	of	ADP
eurjchem-1549	127	63	bromine	bromine	NOUN
eurjchem-1549	127	64	with	with	ADP
eurjchem-1549	127	65	ono2	ono2	PROPN
eurjchem-1549	127	66	.	.	PUNCT
eurjchem-1549	128	1	alkylation	alkylation	NOUN
eurjchem-1549	128	2	of	of	ADP
eurjchem-1549	128	3	norfloxacin	norfloxacin	NOUN
eurjchem-1549	128	4	(	(	PUNCT
eurjchem-1549	128	5	1	1	NUM
eurjchem-1549	128	6	)	)	PUNCT
eurjchem-1549	128	7	with	with	ADP
eurjchem-1549	128	8	alkyl	alkyl	PROPN
eurjchem-1549	128	9	halide	halide	NOUN
eurjchem-1549	128	10	5	5	NUM
eurjchem-1549	128	11	;	;	PUNCT
eurjchem-1549	128	12	generated	generate	VERB
eurjchem-1549	128	13	from	from	ADP
eurjchem-1549	128	14	the	the	DET
eurjchem-1549	128	15	reaction	reaction	NOUN
eurjchem-1549	128	16	of	of	ADP
eurjchem-1549	128	17	p‐aminoacetophenone	p‐aminoacetophenone	X
eurjchem-1549	128	18	(	(	PUNCT
eurjchem-1549	128	19	4	4	NUM
eurjchem-1549	128	20	)	)	PUNCT
eurjchem-1549	128	21	with	with	ADP
eurjchem-1549	128	22	3‐	3‐	NUM
eurjchem-1549	128	23	bromopropionyl	bromopropionyl	NOUN
eurjchem-1549	128	24	chloride	chloride	NOUN
eurjchem-1549	128	25	;	;	PUNCT
eurjchem-1549	128	26	afforded	afford	VERB
eurjchem-1549	128	27	the	the	DET
eurjchem-1549	128	28	corresponding	correspond	VERB
eurjchem-1549	128	29	ketone	ketone	NOUN
eurjchem-1549	128	30	intermediate	intermediate	ADJ
eurjchem-1549	128	31	6	6	NUM
eurjchem-1549	128	32	that	that	PRON
eurjchem-1549	128	33	was	be	AUX
eurjchem-1549	128	34	treated	treat	VERB
eurjchem-1549	128	35	with	with	ADP
eurjchem-1549	128	36	hydroxylamine	hydroxylamine	ADJ
eurjchem-1549	128	37	hydrochloride	hydrochloride	NOUN
eurjchem-1549	128	38	to	to	PART
eurjchem-1549	128	39	deliver	deliver	VERB
eurjchem-1549	128	40	the	the	DET
eurjchem-1549	128	41	target	target	NOUN
eurjchem-1549	128	42	oxime	oxime	NOUN
eurjchem-1549	128	43	7	7	NUM
eurjchem-1549	128	44	.	.	PUNCT
eurjchem-1549	129	1	the	the	DET
eurjchem-1549	129	2	structures	structure	NOUN
eurjchem-1549	129	3	of	of	ADP
eurjchem-1549	129	4	the	the	DET
eurjchem-1549	129	5	target	target	NOUN
eurjchem-1549	129	6	oxime	oxime	NOUN
eurjchem-1549	129	7	7	7	NUM
eurjchem-1549	129	8	and	and	CCONJ
eurjchem-1549	129	9	its	its	PRON
eurjchem-1549	129	10	corresponding	correspond	VERB
eurjchem-1549	129	11	ketone	ketone	NOUN
eurjchem-1549	129	12	intermediate	intermediate	ADJ
eurjchem-1549	129	13	6	6	NUM
eurjchem-1549	129	14	were	be	AUX
eurjchem-1549	129	15	unambiguously	unambiguously	ADV
eurjchem-1549	129	16	confirmed	confirm	VERB
eurjchem-1549	129	17	by	by	ADP
eurjchem-1549	129	18	various	various	ADJ
eurjchem-1549	129	19	spectroscopic	spectroscopic	ADJ
eurjchem-1549	129	20	tools	tool	NOUN
eurjchem-1549	129	21	.	.	PUNCT
eurjchem-1549	130	1	in	in	ADP
eurjchem-1549	130	2	addition	addition	NOUN
eurjchem-1549	130	3	to	to	ADP
eurjchem-1549	130	4	the	the	DET
eurjchem-1549	130	5	basic	basic	ADJ
eurjchem-1549	130	6	skeleton	skeleton	NOUN
eurjchem-1549	130	7	of	of	ADP
eurjchem-1549	130	8	norfloxacin	norfloxacin	PROPN
eurjchem-1549	130	9	,	,	PUNCT
eurjchem-1549	130	10	the	the	DET
eurjchem-1549	130	11	ketone	ketone	NOUN
eurjchem-1549	130	12	intermediate	intermediate	NOUN
eurjchem-1549	130	13	6	6	NUM
eurjchem-1549	130	14	showed	show	VERB
eurjchem-1549	130	15	additional	additional	ADJ
eurjchem-1549	130	16	pair	pair	NOUN
eurjchem-1549	130	17	of	of	ADP
eurjchem-1549	130	18	doublets	doublet	NOUN
eurjchem-1549	130	19	in	in	ADP
eurjchem-1549	130	20	the	the	DET
eurjchem-1549	130	21	aromatic	aromatic	ADJ
eurjchem-1549	130	22	region	region	NOUN
eurjchem-1549	130	23	at	at	ADP
eurjchem-1549	130	24	δ	δ	PROPN
eurjchem-1549	130	25	7.73	7.73	NUM
eurjchem-1549	130	26	ppm	ppm	NOUN
eurjchem-1549	130	27	and	and	CCONJ
eurjchem-1549	130	28	at	at	ADP
eurjchem-1549	130	29	7.92	7.92	NUM
eurjchem-1549	130	30	ppm	ppm	NOUN
eurjchem-1549	130	31	related	relate	VERB
eurjchem-1549	130	32	to	to	ADP
eurjchem-1549	130	33	p‐aminoacetophenone	p‐aminoacetophenone	PUNCT
eurjchem-1549	130	34	and	and	CCONJ
eurjchem-1549	130	35	two	two	NUM
eurjchem-1549	130	36	singlet	singlet	ADJ
eurjchem-1549	130	37	peaks	peak	NOUN
eurjchem-1549	130	38	at	at	ADP
eurjchem-1549	130	39	δ	δ	PROPN
eurjchem-1549	130	40	10.28	10.28	NUM
eurjchem-1549	130	41	ppm	ppm	NOUN
eurjchem-1549	130	42	(	(	PUNCT
eurjchem-1549	130	43	related	relate	VERB
eurjchem-1549	130	44	to	to	ADP
eurjchem-1549	130	45	nh	nh	PROPN
eurjchem-1549	130	46	proton	proton	NOUN
eurjchem-1549	130	47	)	)	PUNCT
eurjchem-1549	130	48	and	and	CCONJ
eurjchem-1549	130	49	at	at	ADP
eurjchem-1549	130	50	δ	δ	PROPN
eurjchem-1549	130	51	2.52	2.52	NUM
eurjchem-1549	130	52	ppm	ppm	NOUN
eurjchem-1549	130	53	(	(	PUNCT
eurjchem-1549	130	54	related	relate	VERB
eurjchem-1549	130	55	to	to	ADP
eurjchem-1549	130	56	coch3	coch3	ADJ
eurjchem-1549	130	57	)	)	PUNCT
eurjchem-1549	130	58	.	.	PUNCT
eurjchem-1549	131	1	moreover	moreover	ADV
eurjchem-1549	131	2	,	,	PUNCT
eurjchem-1549	131	3	the	the	DET
eurjchem-1549	131	4	appearance	appearance	NOUN
eurjchem-1549	131	5	of	of	ADP
eurjchem-1549	131	6	two	two	NUM
eurjchem-1549	131	7	triplet	triplet	NOUN
eurjchem-1549	131	8	signals	signal	NOUN
eurjchem-1549	131	9	at	at	ADP
eurjchem-1549	131	10	δ	δ	PROPN
eurjchem-1549	131	11	2.59	2.59	NUM
eurjchem-1549	131	12	ppm	ppm	NOUN
eurjchem-1549	131	13	and	and	CCONJ
eurjchem-1549	131	14	at	at	ADP
eurjchem-1549	131	15	δ	δ	PROPN
eurjchem-1549	131	16	2.78	2.78	NUM
eurjchem-1549	131	17	ppm	ppm	NUM
eurjchem-1549	131	18	related	relate	VERB
eurjchem-1549	131	19	to	to	ADP
eurjchem-1549	131	20	(	(	PUNCT
eurjchem-1549	131	21	nhcoch2ch2n	nhcoch2ch2n	ADJ
eurjchem-1549	131	22	)	)	PUNCT
eurjchem-1549	131	23	further	far	ADV
eurjchem-1549	131	24	confirmed	confirm	VERB
eurjchem-1549	131	25	the	the	DET
eurjchem-1549	131	26	formation	formation	NOUN
eurjchem-1549	131	27	of	of	ADP
eurjchem-1549	131	28	ketone	ketone	NOUN
eurjchem-1549	131	29	intermediate	intermediate	ADJ
eurjchem-1549	131	30	6	6	NUM
eurjchem-1549	131	31	.	.	NOUN
eurjchem-1549	131	32	13c	13c	NOUN
eurjchem-1549	131	33	nmr	nmr	NOUN
eurjchem-1549	131	34	and	and	CCONJ
eurjchem-1549	131	35	hrms	hrm	NOUN
eurjchem-1549	131	36	were	be	AUX
eurjchem-1549	131	37	additional	additional	ADJ
eurjchem-1549	131	38	evidences	evidence	NOUN
eurjchem-1549	131	39	for	for	ADP
eurjchem-1549	131	40	the	the	DET
eurjchem-1549	131	41	formation	formation	NOUN
eurjchem-1549	131	42	of	of	ADP
eurjchem-1549	131	43	compounds	compound	NOUN
eurjchem-1549	131	44	6	6	NUM
eurjchem-1549	131	45	.	.	PUNCT
eurjchem-1549	132	1	the	the	DET
eurjchem-1549	132	2	conversion	conversion	NOUN
eurjchem-1549	132	3	of	of	ADP
eurjchem-1549	132	4	the	the	DET
eurjchem-1549	132	5	ketone	ketone	NOUN
eurjchem-1549	132	6	intermediate	intermediate	ADJ
eurjchem-1549	132	7	6	6	NUM
eurjchem-1549	132	8	into	into	ADP
eurjchem-1549	132	9	oxime	oxime	NOUN
eurjchem-1549	132	10	7	7	NUM
eurjchem-1549	132	11	was	be	AUX
eurjchem-1549	132	12	confirmed	confirm	VERB
eurjchem-1549	132	13	by	by	ADP
eurjchem-1549	132	14	ir	ir	PROPN
eurjchem-1549	132	15	,	,	PUNCT
eurjchem-1549	132	16	1h	1h	NUM
eurjchem-1549	132	17	nmr	nmr	NOUN
eurjchem-1549	132	18	,	,	PUNCT
eurjchem-1549	132	19	13c	13c	NOUN
eurjchem-1549	132	20	nmr	nmr	NOUN
eurjchem-1549	132	21	and	and	CCONJ
eurjchem-1549	132	22	hrms	hrm	NOUN
eurjchem-1549	132	23	.	.	PUNCT
eurjchem-1549	133	1	the	the	DET
eurjchem-1549	133	2	ir	ir	PROPN
eurjchem-1549	133	3	spectrum	spectrum	NOUN
eurjchem-1549	133	4	of	of	ADP
eurjchem-1549	133	5	compound	compound	NOUN
eurjchem-1549	133	6	7	7	NUM
eurjchem-1549	133	7	showed	show	VERB
eurjchem-1549	133	8	disappearance	disappearance	NOUN
eurjchem-1549	133	9	of	of	ADP
eurjchem-1549	133	10	ketonic	ketonic	ADJ
eurjchem-1549	133	11	carbonyl	carbonyl	NOUN
eurjchem-1549	133	12	(	(	PUNCT
eurjchem-1549	133	13	coch3	coch3	NOUN
eurjchem-1549	133	14	)	)	PUNCT
eurjchem-1549	133	15	due	due	ADP
eurjchem-1549	133	16	to	to	ADP
eurjchem-1549	133	17	its	its	PRON
eurjchem-1549	133	18	conversion	conversion	NOUN
eurjchem-1549	133	19	to	to	ADP
eurjchem-1549	133	20	ketoxime	ketoxime	PROPN
eurjchem-1549	133	21	group	group	NOUN
eurjchem-1549	133	22	(	(	PUNCT
eurjchem-1549	133	23	c	c	NOUN
eurjchem-1549	133	24	=	=	SYM
eurjchem-1549	133	25	n‐oh	n‐oh	NOUN
eurjchem-1549	133	26	)	)	PUNCT
eurjchem-1549	133	27	.	.	PUNCT
eurjchem-1549	134	1	1h	1h	NUM
eurjchem-1549	134	2	nmr	nmr	NOUN
eurjchem-1549	134	3	spectrum	spectrum	NOUN
eurjchem-1549	134	4	of	of	ADP
eurjchem-1549	134	5	compound	compound	NOUN
eurjchem-1549	134	6	7	7	NUM
eurjchem-1549	134	7	was	be	AUX
eurjchem-1549	134	8	characterized	characterize	VERB
eurjchem-1549	134	9	by	by	ADP
eurjchem-1549	134	10	the	the	DET
eurjchem-1549	134	11	appearance	appearance	NOUN
eurjchem-1549	134	12	of	of	ADP
eurjchem-1549	134	13	new	new	ADJ
eurjchem-1549	134	14	singlet	singlet	NOUN
eurjchem-1549	134	15	signal	signal	NOUN
eurjchem-1549	134	16	at	at	ADP
eurjchem-1549	134	17	about	about	ADP
eurjchem-1549	134	18	δ	δ	PROPN
eurjchem-1549	134	19	10.94	10.94	NUM
eurjchem-1549	134	20	ppm	ppm	NOUN
eurjchem-1549	134	21	assigned	assign	VERB
eurjchem-1549	134	22	to	to	ADP
eurjchem-1549	134	23	oh	oh	INTJ
eurjchem-1549	134	24	of	of	ADP
eurjchem-1549	134	25	the	the	DET
eurjchem-1549	134	26	oxime	oxime	NOUN
eurjchem-1549	134	27	,	,	PUNCT
eurjchem-1549	134	28	and	and	CCONJ
eurjchem-1549	134	29	a	a	DET
eurjchem-1549	134	30	singlet	singlet	ADJ
eurjchem-1549	134	31	signal	signal	NOUN
eurjchem-1549	134	32	for	for	ADP
eurjchem-1549	134	33	ch3c	ch3c	PROPN
eurjchem-1549	134	34	=	=	SYM
eurjchem-1549	134	35	noh	noh	PROPN
eurjchem-1549	134	36	that	that	PRON
eurjchem-1549	134	37	was	be	AUX
eurjchem-1549	134	38	up‐field	up‐field	PROPN
eurjchem-1549	134	39	shifted	shift	VERB
eurjchem-1549	134	40	by	by	ADP
eurjchem-1549	134	41	δ0.38	δ0.38	PROPN
eurjchem-1549	134	42	ppm	ppm	VERB
eurjchem-1549	134	43	from	from	ADP
eurjchem-1549	134	44	the	the	DET
eurjchem-1549	134	45	original	original	ADJ
eurjchem-1549	134	46	ch3	ch3	NOUN
eurjchem-1549	134	47	of	of	ADP
eurjchem-1549	134	48	the	the	DET
eurjchem-1549	134	49	ketone	ketone	NOUN
eurjchem-1549	134	50	precursor	precursor	NOUN
eurjchem-1549	134	51	6	6	NUM
eurjchem-1549	134	52	.	.	NOUN
eurjchem-1549	134	53	13c	13c	NOUN
eurjchem-1549	134	54	nmr	nmr	NOUN
eurjchem-1549	134	55	spectrum	spectrum	NOUN
eurjchem-1549	134	56	of	of	ADP
eurjchem-1549	134	57	compound	compound	NOUN
eurjchem-1549	134	58	7	7	NUM
eurjchem-1549	134	59	showed	show	VERB
eurjchem-1549	134	60	the	the	DET
eurjchem-1549	134	61	disappearance	disappearance	NOUN
eurjchem-1549	134	62	of	of	ADP
eurjchem-1549	134	63	the	the	DET
eurjchem-1549	134	64	ketonic	ketonic	ADJ
eurjchem-1549	134	65	carbonyl	carbonyl	NOUN
eurjchem-1549	134	66	(	(	PUNCT
eurjchem-1549	134	67	coch3	coch3	NOUN
eurjchem-1549	134	68	)	)	PUNCT
eurjchem-1549	134	69	due	due	ADJ
eurjchem-1549	134	70	its	its	PRON
eurjchem-1549	134	71	conversion	conversion	NOUN
eurjchem-1549	134	72	to	to	ADP
eurjchem-1549	134	73	ketoxime	ketoxime	PROPN
eurjchem-1549	134	74	group	group	NOUN
eurjchem-1549	134	75	(	(	PUNCT
eurjchem-1549	134	76	c	c	PROPN
eurjchem-1549	134	77	=	=	SYM
eurjchem-1549	134	78	noh	noh	PROPN
eurjchem-1549	134	79	)	)	PUNCT
eurjchem-1549	134	80	which	which	PRON
eurjchem-1549	134	81	appeared	appear	VERB
eurjchem-1549	134	82	at	at	ADP
eurjchem-1549	134	83	δ	δ	PROPN
eurjchem-1549	134	84	152.91	152.91	NUM
eurjchem-1549	134	85	ppm	ppm	NOUN
eurjchem-1549	134	86	.	.	PUNCT
eurjchem-1549	135	1	moreover	moreover	ADV
eurjchem-1549	135	2	,	,	PUNCT
eurjchem-1549	135	3	the	the	DET
eurjchem-1549	135	4	methyl	methyl	NOUN
eurjchem-1549	135	5	of	of	ADP
eurjchem-1549	135	6	(	(	PUNCT
eurjchem-1549	135	7	ch3c	ch3c	PROPN
eurjchem-1549	135	8	=	=	SYM
eurjchem-1549	135	9	noh	noh	PROPN
eurjchem-1549	135	10	)	)	PUNCT
eurjchem-1549	135	11	appeared	appear	VERB
eurjchem-1549	135	12	at	at	ADP
eurjchem-1549	135	13	δ	δ	PROPN
eurjchem-1549	135	14	11.80	11.80	NUM
eurjchem-1549	135	15	ppm	ppm	NOUN
eurjchem-1549	135	16	with	with	ADP
eurjchem-1549	135	17	up‐field	up‐field	PROPN
eurjchem-1549	135	18	shifting	shift	VERB
eurjchem-1549	135	19	by	by	ADP
eurjchem-1549	135	20	δ	δ	PROPN
eurjchem-1549	135	21	15	15	NUM
eurjchem-1549	135	22	ppm	ppm	NOUN
eurjchem-1549	135	23	from	from	ADP
eurjchem-1549	135	24	the	the	DET
eurjchem-1549	135	25	original	original	ADJ
eurjchem-1549	135	26	ch3c	ch3c	NOUN
eurjchem-1549	135	27	=	=	NOUN
eurjchem-1549	135	28	o	o	NOUN
eurjchem-1549	135	29	in	in	ADP
eurjchem-1549	135	30	the	the	DET
eurjchem-1549	135	31	ketone	ketone	NOUN
eurjchem-1549	135	32	precursor	precursor	NOUN
eurjchem-1549	135	33	6	6	NUM
eurjchem-1549	135	34	.	.	NOUN
eurjchem-1549	135	35	3.2	3.2	NUM
eurjchem-1549	135	36	.	.	PUNCT
eurjchem-1549	136	1	no	no	DET
eurjchem-1549	136	2	release	release	NOUN
eurjchem-1549	136	3	measurement	measurement	NOUN
eurjchem-1549	136	4	our	our	PRON
eurjchem-1549	136	5	next	next	ADJ
eurjchem-1549	136	6	task	task	NOUN
eurjchem-1549	136	7	was	be	AUX
eurjchem-1549	136	8	to	to	PART
eurjchem-1549	136	9	estimate	estimate	VERB
eurjchem-1549	136	10	the	the	DET
eurjchem-1549	136	11	ability	ability	NOUN
eurjchem-1549	136	12	of	of	ADP
eurjchem-1549	136	13	no	no	DET
eurjchem-1549	136	14	donor	donor	NOUN
eurjchem-1549	136	15	hybrids	hybrid	NOUN
eurjchem-1549	136	16	3	3	NUM
eurjchem-1549	136	17	and	and	CCONJ
eurjchem-1549	136	18	7	7	NUM
eurjchem-1549	136	19	to	to	PART
eurjchem-1549	136	20	release	release	VERB
eurjchem-1549	136	21	no	no	PRON
eurjchem-1549	136	22	.	.	PUNCT
eurjchem-1549	137	1	disappointingly	disappointingly	ADV
eurjchem-1549	137	2	,	,	PUNCT
eurjchem-1549	137	3	we	we	PRON
eurjchem-1549	137	4	could	could	AUX
eurjchem-1549	137	5	not	not	PART
eurjchem-1549	137	6	detect	detect	VERB
eurjchem-1549	137	7	measurable	measurable	ADJ
eurjchem-1549	137	8	amounts	amount	NOUN
eurjchem-1549	137	9	of	of	ADP
eurjchem-1549	137	10	no	no	PRON
eurjchem-1549	137	11	from	from	ADP
eurjchem-1549	137	12	our	our	PRON
eurjchem-1549	137	13	compounds	compound	NOUN
eurjchem-1549	137	14	by	by	ADP
eurjchem-1549	137	15	the	the	DET
eurjchem-1549	137	16	conventional	conventional	ADJ
eurjchem-1549	137	17	griess	griess	NOUN
eurjchem-1549	137	18	method	method	NOUN
eurjchem-1549	137	19	.	.	PUNCT
eurjchem-1549	138	1	in	in	ADP
eurjchem-1549	138	2	an	an	DET
eurjchem-1549	138	3	effort	effort	NOUN
eurjchem-1549	138	4	to	to	PART
eurjchem-1549	138	5	overcome	overcome	VERB
eurjchem-1549	138	6	the	the	DET
eurjchem-1549	138	7	problem	problem	NOUN
eurjchem-1549	138	8	,	,	PUNCT
eurjchem-1549	138	9	we	we	PRON
eurjchem-1549	138	10	adapted	adapt	VERB
eurjchem-1549	138	11	a	a	DET
eurjchem-1549	138	12	modification	modification	NOUN
eurjchem-1549	138	13	to	to	ADP
eurjchem-1549	138	14	the	the	DET
eurjchem-1549	138	15	griess	griess	NOUN
eurjchem-1549	138	16	method	method	NOUN
eurjchem-1549	138	17	by	by	ADP
eurjchem-1549	138	18	replacing	replace	VERB
eurjchem-1549	138	19	sulphanilamide	sulphanilamide	ADV
eurjchem-1549	138	20	with	with	ADP
eurjchem-1549	138	21	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	138	22	aiming	aim	VERB
eurjchem-1549	138	23	to	to	PART
eurjchem-1549	138	24	enhance	enhance	VERB
eurjchem-1549	138	25	the	the	DET
eurjchem-1549	138	26	sensitivity	sensitivity	NOUN
eurjchem-1549	138	27	of	of	ADP
eurjchem-1549	138	28	no	no	DET
eurjchem-1549	138	29	measurement	measurement	NOUN
eurjchem-1549	138	30	.	.	PUNCT
eurjchem-1549	139	1	we	we	PRON
eurjchem-1549	139	2	envisioned	envision	VERB
eurjchem-1549	139	3	that	that	SCONJ
eurjchem-1549	139	4	the	the	DET
eurjchem-1549	139	5	transiently	transiently	ADV
eurjchem-1549	139	6	generated	generate	VERB
eurjchem-1549	139	7	no2‐	no2‐	NOUN
eurjchem-1549	139	8	requires	require	VERB
eurjchem-1549	139	9	immediate	immediate	ADJ
eurjchem-1549	139	10	capturing	capturing	NOUN
eurjchem-1549	139	11	by	by	ADP
eurjchem-1549	139	12	an	an	DET
eurjchem-1549	139	13	appropriate	appropriate	ADJ
eurjchem-1549	139	14	aromatic	aromatic	ADJ
eurjchem-1549	139	15	amine	amine	NOUN
eurjchem-1549	139	16	that	that	PRON
eurjchem-1549	139	17	would	would	AUX
eurjchem-1549	139	18	generate	generate	VERB
eurjchem-1549	139	19	a	a	DET
eurjchem-1549	139	20	highly	highly	ADV
eurjchem-1549	139	21	reactive	reactive	ADJ
eurjchem-1549	139	22	diazonium	diazonium	NOUN
eurjchem-1549	139	23	salt	salt	NOUN
eurjchem-1549	139	24	before	before	ADP
eurjchem-1549	139	25	the	the	DET
eurjchem-1549	139	26	nitrous	nitrous	ADJ
eurjchem-1549	139	27	acid	acid	NOUN
eurjchem-1549	139	28	undergoes	undergoe	NOUN
eurjchem-1549	139	29	decomposition	decomposition	NOUN
eurjchem-1549	139	30	.	.	PUNCT
eurjchem-1549	140	1	the	the	DET
eurjchem-1549	140	2	presence	presence	NOUN
eurjchem-1549	140	3	of	of	ADP
eurjchem-1549	140	4	nitro	nitro	NOUN
eurjchem-1549	140	5	group	group	NOUN
eurjchem-1549	140	6	in	in	ADP
eurjchem-1549	140	7	para	para	PROPN
eurjchem-1549	140	8	position	position	NOUN
eurjchem-1549	140	9	to	to	ADP
eurjchem-1549	140	10	the	the	DET
eurjchem-1549	140	11	diazonium	diazonium	NOUN
eurjchem-1549	140	12	group	group	NOUN
eurjchem-1549	140	13	,	,	PUNCT
eurjchem-1549	140	14	by	by	ADP
eurjchem-1549	140	15	virtue	virtue	NOUN
eurjchem-1549	140	16	of	of	ADP
eurjchem-1549	140	17	its	its	PRON
eurjchem-1549	140	18	powerful	powerful	ADJ
eurjchem-1549	140	19	electron‐withdrawing	electron‐withdrawing	NOUN
eurjchem-1549	140	20	and	and	CCONJ
eurjchem-1549	140	21	resonance	resonance	NOUN
eurjchem-1549	140	22	properties	property	NOUN
eurjchem-1549	140	23	,	,	PUNCT
eurjchem-1549	140	24	would	would	AUX
eurjchem-1549	140	25	potentially	potentially	ADV
eurjchem-1549	140	26	enhance	enhance	VERB
eurjchem-1549	140	27	the	the	DET
eurjchem-1549	140	28	electrophilicity	electrophilicity	NOUN
eurjchem-1549	140	29	of	of	ADP
eurjchem-1549	140	30	the	the	DET
eurjchem-1549	140	31	diazonium	diazonium	NOUN
eurjchem-1549	140	32	salt	salt	NOUN
eurjchem-1549	140	33	[	[	X
eurjchem-1549	140	34	24	24	NUM
eurjchem-1549	140	35	]	]	PUNCT
eurjchem-1549	140	36	(	(	PUNCT
eurjchem-1549	140	37	figure	figure	NOUN
eurjchem-1549	140	38	1	1	NUM
eurjchem-1549	140	39	)	)	PUNCT
eurjchem-1549	140	40	and	and	CCONJ
eurjchem-1549	140	41	accelerate	accelerate	VERB
eurjchem-1549	140	42	the	the	DET
eurjchem-1549	140	43	coupling	coupling	NOUN
eurjchem-1549	140	44	with	with	ADP
eurjchem-1549	140	45	ned	ned	ADJ
eurjchem-1549	140	46	(	(	PUNCT
eurjchem-1549	140	47	scheme	scheme	NOUN
eurjchem-1549	140	48	2	2	NUM
eurjchem-1549	140	49	)	)	PUNCT
eurjchem-1549	140	50	leading	lead	VERB
eurjchem-1549	140	51	to	to	ADP
eurjchem-1549	140	52	enhanced	enhance	VERB
eurjchem-1549	140	53	sensitivity	sensitivity	NOUN
eurjchem-1549	140	54	and	and	CCONJ
eurjchem-1549	140	55	improved	improved	ADJ
eurjchem-1549	140	56	detection	detection	NOUN
eurjchem-1549	140	57	limits	limit	NOUN
eurjchem-1549	140	58	.	.	PUNCT
eurjchem-1549	141	1	moreover	moreover	ADV
eurjchem-1549	141	2	,	,	PUNCT
eurjchem-1549	141	3	the	the	DET
eurjchem-1549	141	4	relative	relative	ADJ
eurjchem-1549	141	5	resonance	resonance	NOUN
eurjchem-1549	141	6	stabilization	stabilization	NOUN
eurjchem-1549	141	7	of	of	ADP
eurjchem-1549	141	8	the	the	DET
eurjchem-1549	141	9	diazonium	diazonium	NOUN
eurjchem-1549	141	10	salt	salt	NOUN
eurjchem-1549	141	11	is	be	AUX
eurjchem-1549	141	12	predicted	predict	VERB
eurjchem-1549	141	13	to	to	PART
eurjchem-1549	141	14	hasten	hasten	VERB
eurjchem-1549	141	15	the	the	DET
eurjchem-1549	141	16	diazotization	diazotization	NOUN
eurjchem-1549	141	17	step	step	NOUN
eurjchem-1549	141	18	via	via	ADP
eurjchem-1549	141	19	the	the	DET
eurjchem-1549	141	20	intermediacy	intermediacy	NOUN
eurjchem-1549	141	21	of	of	ADP
eurjchem-1549	141	22	a	a	DET
eurjchem-1549	141	23	resonance‐stabilized	resonance‐stabilize	VERB
eurjchem-1549	141	24	species	specie	NOUN
eurjchem-1549	141	25	(	(	PUNCT
eurjchem-1549	141	26	scheme	scheme	NOUN
eurjchem-1549	141	27	2	2	NUM
eurjchem-1549	141	28	)	)	PUNCT
eurjchem-1549	141	29	.	.	PUNCT
eurjchem-1549	142	1	the	the	DET
eurjchem-1549	142	2	release	release	NOUN
eurjchem-1549	142	3	of	of	ADP
eurjchem-1549	142	4	no	no	PRON
eurjchem-1549	142	5	from	from	ADP
eurjchem-1549	142	6	the	the	DET
eurjchem-1549	142	7	prepared	prepare	VERB
eurjchem-1549	142	8	compounds	compound	NOUN
eurjchem-1549	142	9	was	be	AUX
eurjchem-1549	142	10	measured	measure	VERB
eurjchem-1549	142	11	on	on	ADP
eurjchem-1549	142	12	the	the	DET
eurjchem-1549	142	13	basis	basis	NOUN
eurjchem-1549	142	14	of	of	ADP
eurjchem-1549	142	15	the	the	DET
eurjchem-1549	142	16	produced	produce	VERB
eurjchem-1549	142	17	nitrite	nitrite	NOUN
eurjchem-1549	142	18	,	,	PUNCT
eurjchem-1549	142	19	which	which	PRON
eurjchem-1549	142	20	is	be	AUX
eurjchem-1549	142	21	a	a	DET
eurjchem-1549	142	22	convenient	convenient	ADJ
eurjchem-1549	142	23	index	index	NOUN
eurjchem-1549	142	24	of	of	ADP
eurjchem-1549	142	25	nitric	nitric	ADJ
eurjchem-1549	142	26	oxide	oxide	NOUN
eurjchem-1549	142	27	production	production	NOUN
eurjchem-1549	142	28	.	.	PUNCT
eurjchem-1549	143	1	in	in	ADP
eurjchem-1549	143	2	this	this	DET
eurjchem-1549	143	3	context	context	NOUN
eurjchem-1549	143	4	,	,	PUNCT
eurjchem-1549	143	5	the	the	DET
eurjchem-1549	143	6	newly	newly	ADV
eurjchem-1549	143	7	proposed	propose	VERB
eurjchem-1549	143	8	griess	griess	NOUN
eurjchem-1549	143	9	modification	modification	NOUN
eurjchem-1549	143	10	was	be	AUX
eurjchem-1549	143	11	first	first	ADV
eurjchem-1549	143	12	validated	validate	VERB
eurjchem-1549	143	13	by	by	ADP
eurjchem-1549	143	14	constructing	construct	VERB
eurjchem-1549	143	15	a	a	DET
eurjchem-1549	143	16	standard	standard	ADJ
eurjchem-1549	143	17	sodium	sodium	NOUN
eurjchem-1549	143	18	nitrite	nitrite	NOUN
eurjchem-1549	143	19	curve	curve	NOUN
eurjchem-1549	143	20	obtained	obtain	VERB
eurjchem-1549	143	21	by	by	ADP
eurjchem-1549	143	22	measuring	measure	VERB
eurjchem-1549	143	23	the	the	DET
eurjchem-1549	143	24	absorbance	absorbance	NOUN
eurjchem-1549	143	25	of	of	ADP
eurjchem-1549	143	26	various	various	ADJ
eurjchem-1549	143	27	concentrations	concentration	NOUN
eurjchem-1549	143	28	of	of	ADP
eurjchem-1549	143	29	sodium	sodium	NOUN
eurjchem-1549	143	30	nitrite	nitrite	NOUN
eurjchem-1549	143	31	solution	solution	NOUN
eurjchem-1549	143	32	.	.	PUNCT
eurjchem-1549	144	1	initially	initially	ADV
eurjchem-1549	144	2	,	,	PUNCT
eurjchem-1549	144	3	sodium	sodium	NOUN
eurjchem-1549	144	4	nitrite	nitrite	NOUN
eurjchem-1549	144	5	solutions	solution	NOUN
eurjchem-1549	144	6	were	be	AUX
eurjchem-1549	144	7	treated	treat	VERB
eurjchem-1549	144	8	with	with	ADP
eurjchem-1549	144	9	a	a	DET
eurjchem-1549	144	10	solution	solution	NOUN
eurjchem-1549	144	11	of	of	ADP
eurjchem-1549	144	12	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	144	13	to	to	PART
eurjchem-1549	144	14	form	form	VERB
eurjchem-1549	144	15	the	the	DET
eurjchem-1549	144	16	diazonium	diazonium	NOUN
eurjchem-1549	144	17	slat	slat	NOUN
eurjchem-1549	144	18	followed	follow	VERB
eurjchem-1549	144	19	by	by	ADP
eurjchem-1549	144	20	treating	treat	VERB
eurjchem-1549	144	21	the	the	DET
eurjchem-1549	144	22	resultant	resultant	NOUN
eurjchem-1549	144	23	diazonium	diazonium	NOUN
eurjchem-1549	144	24	salt	salt	NOUN
eurjchem-1549	144	25	with	with	ADP
eurjchem-1549	144	26	ned	ned	NOUN
eurjchem-1549	144	27	to	to	PART
eurjchem-1549	144	28	afford	afford	VERB
eurjchem-1549	144	29	the	the	DET
eurjchem-1549	144	30	purple	purple	ADJ
eurjchem-1549	144	31	azo	azo	NOUN
eurjchem-1549	144	32	dye	dye	NOUN
eurjchem-1549	144	33	that	that	PRON
eurjchem-1549	144	34	was	be	AUX
eurjchem-1549	144	35	measured	measure	VERB
eurjchem-1549	144	36	at	at	ADP
eurjchem-1549	144	37	max	max	NUM
eurjchem-1549	144	38	539	539	NUM
eurjchem-1549	144	39	nm	nm	NOUN
eurjchem-1549	144	40	.	.	PUNCT
eurjchem-1549	145	1	we	we	PRON
eurjchem-1549	145	2	were	be	AUX
eurjchem-1549	145	3	delighted	delighted	ADJ
eurjchem-1549	145	4	to	to	PART
eurjchem-1549	145	5	find	find	VERB
eurjchem-1549	145	6	the	the	DET
eurjchem-1549	145	7	short	short	ADJ
eurjchem-1549	145	8	time	time	NOUN
eurjchem-1549	145	9	needed	need	VERB
eurjchem-1549	145	10	for	for	ADP
eurjchem-1549	145	11	the	the	DET
eurjchem-1549	145	12	diazocoupling	diazocoupling	ADJ
eurjchem-1549	145	13	process	process	NOUN
eurjchem-1549	145	14	;	;	PUNCT
eurjchem-1549	145	15	the	the	DET
eurjchem-1549	145	16	overall	overall	ADJ
eurjchem-1549	145	17	reaction	reaction	NOUN
eurjchem-1549	145	18	time	time	NOUN
eurjchem-1549	145	19	was	be	AUX
eurjchem-1549	145	20	10	10	NUM
eurjchem-1549	145	21	minutes	minute	NOUN
eurjchem-1549	145	22	beyond	beyond	ADP
eurjchem-1549	145	23	which	which	PRON
eurjchem-1549	145	24	a	a	DET
eurjchem-1549	145	25	stable	stable	ADJ
eurjchem-1549	145	26	plateau	plateau	NOUN
eurjchem-1549	145	27	absorbance	absorbance	NOUN
eurjchem-1549	145	28	was	be	AUX
eurjchem-1549	145	29	achieved	achieve	VERB
eurjchem-1549	145	30	(	(	PUNCT
eurjchem-1549	145	31	figure	figure	NOUN
eurjchem-1549	145	32	2	2	NUM
eurjchem-1549	145	33	)	)	PUNCT
eurjchem-1549	145	34	.	.	PUNCT
eurjchem-1549	146	1	conversely	conversely	ADV
eurjchem-1549	146	2	,	,	PUNCT
eurjchem-1549	146	3	the	the	DET
eurjchem-1549	146	4	classical	classical	ADJ
eurjchem-1549	146	5	griess	griess	NOUN
eurjchem-1549	146	6	method	method	NOUN
eurjchem-1549	146	7	usually	usually	ADV
eurjchem-1549	146	8	requires	require	VERB
eurjchem-1549	146	9	longer	long	ADJ
eurjchem-1549	146	10	time	time	NOUN
eurjchem-1549	146	11	(	(	PUNCT
eurjchem-1549	146	12	30	30	NUM
eurjchem-1549	146	13	minutes	minute	NOUN
eurjchem-1549	146	14	)	)	PUNCT
eurjchem-1549	146	15	for	for	ADP
eurjchem-1549	146	16	completing	complete	VERB
eurjchem-1549	146	17	the	the	DET
eurjchem-1549	146	18	reaction	reaction	NOUN
eurjchem-1549	146	19	.	.	PUNCT
eurjchem-1549	147	1	aziz	aziz	PROPN
eurjchem-1549	147	2	et	et	PROPN
eurjchem-1549	147	3	al	al	PROPN
eurjchem-1549	147	4	.	.	PUNCT
eurjchem-1549	147	5	/	/	SYM
eurjchem-1549	147	6	european	european	PROPN
eurjchem-1549	147	7	journal	journal	PROPN
eurjchem-1549	147	8	of	of	ADP
eurjchem-1549	147	9	chemistry	chemistry	NOUN
eurjchem-1549	147	10	8	8	NUM
eurjchem-1549	147	11	(	(	PUNCT
eurjchem-1549	147	12	2	2	NUM
eurjchem-1549	147	13	)	)	PUNCT
eurjchem-1549	147	14	(	(	PUNCT
eurjchem-1549	147	15	2017	2017	NUM
eurjchem-1549	147	16	)	)	PUNCT
eurjchem-1549	147	17	119‐124	119‐124	PROPN
eurjchem-1549	147	18	123	123	NUM
eurjchem-1549	147	19	table	table	NOUN
eurjchem-1549	147	20	1	1	NUM
eurjchem-1549	147	21	.	.	PUNCT
eurjchem-1549	147	22	comparison	comparison	NOUN
eurjchem-1549	147	23	of	of	ADP
eurjchem-1549	147	24	the	the	DET
eurjchem-1549	147	25	analytical	analytical	ADJ
eurjchem-1549	147	26	parameters	parameter	NOUN
eurjchem-1549	147	27	to	to	PART
eurjchem-1549	147	28	validate	validate	VERB
eurjchem-1549	147	29	the	the	DET
eurjchem-1549	147	30	proposed	propose	VERB
eurjchem-1549	147	31	method	method	NOUN
eurjchem-1549	147	32	.	.	PUNCT
eurjchem-1549	148	1	parameters	parameter	NOUN
eurjchem-1549	148	2	conventional	conventional	ADJ
eurjchem-1549	148	3	griess	griess	NOUN
eurjchem-1549	148	4	method	method	NOUN
eurjchem-1549	148	5	(	(	PUNCT
eurjchem-1549	148	6	using	use	VERB
eurjchem-1549	148	7	sulfanilamide	sulfanilamide	NOUN
eurjchem-1549	148	8	)	)	PUNCT
eurjchem-1549	148	9	newly	newly	ADV
eurjchem-1549	148	10	modified	modify	VERB
eurjchem-1549	148	11	method	method	NOUN
eurjchem-1549	148	12	(	(	PUNCT
eurjchem-1549	148	13	using	use	VERB
eurjchem-1549	148	14	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	148	15	)	)	PUNCT
eurjchem-1549	148	16	concentration	concentration	NOUN
eurjchem-1549	148	17	range	range	NOUN
eurjchem-1549	148	18	(	(	PUNCT
eurjchem-1549	148	19	µg	µg	NOUN
eurjchem-1549	148	20	/	/	SYM
eurjchem-1549	148	21	ml	ml	NOUN
eurjchem-1549	148	22	)	)	PUNCT
eurjchem-1549	148	23	100‐6.25	100‐6.25	NOUN
eurjchem-1549	148	24	25‐0.39	25‐0.39	NOUN
eurjchem-1549	148	25	intercept	intercept	VERB
eurjchem-1549	148	26	0.1495	0.1495	NUM
eurjchem-1549	148	27	0.145	0.145	NUM
eurjchem-1549	148	28	correlation	correlation	NOUN
eurjchem-1549	148	29	coefficient	coefficient	NOUN
eurjchem-1549	148	30	(	(	PUNCT
eurjchem-1549	148	31	r2	r2	PROPN
eurjchem-1549	148	32	)	)	PUNCT
eurjchem-1549	148	33	0.999	0.999	NUM
eurjchem-1549	148	34	0.998	0.998	NUM
eurjchem-1549	148	35	limit	limit	NOUN
eurjchem-1549	148	36	of	of	ADP
eurjchem-1549	148	37	detection	detection	NOUN
eurjchem-1549	148	38	(	(	PUNCT
eurjchem-1549	148	39	µg	µg	NOUN
eurjchem-1549	148	40	/	/	SYM
eurjchem-1549	148	41	ml	ml	VERB
eurjchem-1549	148	42	)	)	PUNCT
eurjchem-1549	148	43	3.125	3.125	NUM
eurjchem-1549	148	44	0.39	0.39	NUM
eurjchem-1549	148	45	limit	limit	NOUN
eurjchem-1549	148	46	of	of	ADP
eurjchem-1549	148	47	quantitation	quantitation	NOUN
eurjchem-1549	148	48	(	(	PUNCT
eurjchem-1549	148	49	µg	µg	NOUN
eurjchem-1549	148	50	/	/	SYM
eurjchem-1549	148	51	ml	ml	NOUN
eurjchem-1549	148	52	)	)	PUNCT
eurjchem-1549	148	53	6.25	6.25	NUM
eurjchem-1549	148	54	0.78	0.78	NUM
eurjchem-1549	148	55	reaction	reaction	NOUN
eurjchem-1549	148	56	time	time	NOUN
eurjchem-1549	148	57	(	(	PUNCT
eurjchem-1549	148	58	minutes	minute	NOUN
eurjchem-1549	148	59	)	)	PUNCT
eurjchem-1549	148	60	30	30	NUM
eurjchem-1549	148	61	10	10	NUM
eurjchem-1549	148	62	scheme	scheme	NOUN
eurjchem-1549	148	63	2	2	NUM
eurjchem-1549	148	64	0.00	0.00	NUM
eurjchem-1549	148	65	0.40	0.40	NUM
eurjchem-1549	148	66	0.80	0.80	NUM
eurjchem-1549	148	67	1.20	1.20	NUM
eurjchem-1549	148	68	1	1	NUM
eurjchem-1549	148	69	3	3	NUM
eurjchem-1549	148	70	5	5	NUM
eurjchem-1549	148	71	7	7	NUM
eurjchem-1549	148	72	9	9	NUM
eurjchem-1549	148	73	11	11	NUM
eurjchem-1549	148	74	13	13	NUM
eurjchem-1549	148	75	a	a	DET
eurjchem-1549	148	76	b	b	NOUN
eurjchem-1549	148	77	s	s	PART
eurjchem-1549	148	78	o	o	NOUN
eurjchem-1549	148	79	rb	rb	NOUN
eurjchem-1549	148	80	an	an	DET
eurjchem-1549	148	81	c	c	NOUN
eurjchem-1549	148	82	e	e	NOUN
eurjchem-1549	148	83	time	time	NOUN
eurjchem-1549	148	84	(	(	PUNCT
eurjchem-1549	148	85	min	min	NOUN
eurjchem-1549	148	86	.	.	PUNCT
eurjchem-1549	148	87	)	)	PUNCT
eurjchem-1549	148	88	3.125	3.125	NUM
eurjchem-1549	148	89	μm	μm	NOUN
eurjchem-1549	148	90	12.5	12.5	NUM
eurjchem-1549	148	91	μm	μm	NUM
eurjchem-1549	148	92	25	25	NUM
eurjchem-1549	148	93	μm	μm	NUM
eurjchem-1549	148	94	figure	figure	NOUN
eurjchem-1549	148	95	2	2	NUM
eurjchem-1549	148	96	.	.	NOUN
eurjchem-1549	148	97	effect	effect	NOUN
eurjchem-1549	148	98	of	of	ADP
eurjchem-1549	148	99	time	time	NOUN
eurjchem-1549	148	100	on	on	ADP
eurjchem-1549	148	101	the	the	DET
eurjchem-1549	148	102	absorbance	absorbance	NOUN
eurjchem-1549	148	103	of	of	ADP
eurjchem-1549	148	104	reaction	reaction	NOUN
eurjchem-1549	148	105	product	product	NOUN
eurjchem-1549	148	106	of	of	ADP
eurjchem-1549	148	107	nitrite	nitrite	NOUN
eurjchem-1549	148	108	with	with	ADP
eurjchem-1549	148	109	the	the	DET
eurjchem-1549	148	110	modified	modified	ADJ
eurjchem-1549	148	111	griess	griess	NOUN
eurjchem-1549	148	112	reagent	reagent	NOUN
eurjchem-1549	148	113	.	.	PUNCT
eurjchem-1549	149	1	moreover	moreover	ADV
eurjchem-1549	149	2	,	,	PUNCT
eurjchem-1549	149	3	the	the	DET
eurjchem-1549	149	4	newly	newly	ADV
eurjchem-1549	149	5	modified	modify	VERB
eurjchem-1549	149	6	method	method	NOUN
eurjchem-1549	149	7	showed	show	VERB
eurjchem-1549	149	8	an	an	DET
eurjchem-1549	149	9	excellent	excellent	ADJ
eurjchem-1549	149	10	reproducibility	reproducibility	NOUN
eurjchem-1549	149	11	and	and	CCONJ
eurjchem-1549	149	12	linearity	linearity	NOUN
eurjchem-1549	149	13	of	of	ADP
eurjchem-1549	149	14	the	the	DET
eurjchem-1549	149	15	standard	standard	ADJ
eurjchem-1549	149	16	nitrite	nitrite	NOUN
eurjchem-1549	149	17	curve	curve	NOUN
eurjchem-1549	149	18	particularly	particularly	ADV
eurjchem-1549	149	19	at	at	ADP
eurjchem-1549	149	20	submicromolar	submicromolar	ADJ
eurjchem-1549	149	21	concentrations	concentration	NOUN
eurjchem-1549	149	22	(	(	PUNCT
eurjchem-1549	149	23	table	table	NOUN
eurjchem-1549	149	24	1	1	NUM
eurjchem-1549	149	25	)	)	PUNCT
eurjchem-1549	149	26	.	.	PUNCT
eurjchem-1549	150	1	a	a	DET
eurjchem-1549	150	2	detection	detection	NOUN
eurjchem-1549	150	3	limit	limit	NOUN
eurjchem-1549	150	4	of	of	ADP
eurjchem-1549	150	5	0.39	0.39	NUM
eurjchem-1549	150	6	μm	μm	NOUN
eurjchem-1549	150	7	was	be	AUX
eurjchem-1549	150	8	realized	realize	VERB
eurjchem-1549	150	9	suggesting	suggest	VERB
eurjchem-1549	150	10	the	the	DET
eurjchem-1549	150	11	reliable	reliable	ADJ
eurjchem-1549	150	12	sensitivity	sensitivity	NOUN
eurjchem-1549	150	13	of	of	ADP
eurjchem-1549	150	14	the	the	DET
eurjchem-1549	150	15	new	new	ADJ
eurjchem-1549	150	16	method	method	NOUN
eurjchem-1549	150	17	in	in	ADP
eurjchem-1549	150	18	comparison	comparison	NOUN
eurjchem-1549	150	19	to	to	ADP
eurjchem-1549	150	20	the	the	DET
eurjchem-1549	150	21	classical	classical	ADJ
eurjchem-1549	150	22	one	one	NUM
eurjchem-1549	150	23	in	in	ADP
eurjchem-1549	150	24	which	which	PRON
eurjchem-1549	150	25	the	the	DET
eurjchem-1549	150	26	sensitivity	sensitivity	NOUN
eurjchem-1549	150	27	for	for	ADP
eurjchem-1549	150	28	the	the	DET
eurjchem-1549	150	29	nitrite	nitrite	NOUN
eurjchem-1549	150	30	concentrations	concentration	NOUN
eurjchem-1549	150	31	below	below	ADP
eurjchem-1549	150	32	3.125	3.125	NUM
eurjchem-1549	150	33	μm	μm	NOUN
eurjchem-1549	150	34	was	be	AUX
eurjchem-1549	150	35	markedly	markedly	ADV
eurjchem-1549	150	36	reduced	reduce	VERB
eurjchem-1549	150	37	(	(	PUNCT
eurjchem-1549	150	38	table	table	NOUN
eurjchem-1549	150	39	1	1	NUM
eurjchem-1549	150	40	)	)	PUNCT
eurjchem-1549	150	41	.	.	PUNCT
eurjchem-1549	151	1	these	these	DET
eurjchem-1549	151	2	outcomes	outcome	NOUN
eurjchem-1549	151	3	suggest	suggest	VERB
eurjchem-1549	151	4	that	that	SCONJ
eurjchem-1549	151	5	the	the	DET
eurjchem-1549	151	6	newly	newly	ADV
eurjchem-1549	151	7	developed	develop	VERB
eurjchem-1549	151	8	method	method	NOUN
eurjchem-1549	151	9	would	would	AUX
eurjchem-1549	151	10	pave	pave	VERB
eurjchem-1549	151	11	the	the	DET
eurjchem-1549	151	12	way	way	NOUN
eurjchem-1549	151	13	for	for	ADP
eurjchem-1549	151	14	potential	potential	ADJ
eurjchem-1549	151	15	applications	application	NOUN
eurjchem-1549	151	16	in	in	ADP
eurjchem-1549	151	17	the	the	DET
eurjchem-1549	151	18	precise	precise	ADJ
eurjchem-1549	151	19	determination	determination	NOUN
eurjchem-1549	151	20	of	of	ADP
eurjchem-1549	151	21	nitrite	nitrite	NOUN
eurjchem-1549	151	22	levels	level	NOUN
eurjchem-1549	151	23	in	in	ADP
eurjchem-1549	151	24	water	water	NOUN
eurjchem-1549	151	25	or	or	CCONJ
eurjchem-1549	151	26	biological	biological	ADJ
eurjchem-1549	151	27	fluids	fluid	NOUN
eurjchem-1549	151	28	or	or	CCONJ
eurjchem-1549	151	29	even	even	ADV
eurjchem-1549	151	30	foodstuffs	foodstuff	NOUN
eurjchem-1549	151	31	.	.	PUNCT
eurjchem-1549	152	1	motivated	motivate	VERB
eurjchem-1549	152	2	by	by	ADP
eurjchem-1549	152	3	the	the	DET
eurjchem-1549	152	4	above‐mentioned	above‐mentione	VERB
eurjchem-1549	152	5	results	result	NOUN
eurjchem-1549	152	6	,	,	PUNCT
eurjchem-1549	152	7	we	we	PRON
eurjchem-1549	152	8	applied	apply	VERB
eurjchem-1549	152	9	the	the	DET
eurjchem-1549	152	10	new	new	ADJ
eurjchem-1549	152	11	method	method	NOUN
eurjchem-1549	152	12	to	to	PART
eurjchem-1549	152	13	estimate	estimate	VERB
eurjchem-1549	152	14	the	the	DET
eurjchem-1549	152	15	no	no	DET
eurjchem-1549	152	16	release	release	NOUN
eurjchem-1549	152	17	from	from	ADP
eurjchem-1549	152	18	no	no	DET
eurjchem-1549	152	19	donor	donor	NOUN
eurjchem-1549	152	20	hybrids	hybrid	NOUN
eurjchem-1549	152	21	3	3	NUM
eurjchem-1549	152	22	and	and	CCONJ
eurjchem-1549	152	23	7	7	NUM
eurjchem-1549	152	24	.	.	PUNCT
eurjchem-1549	153	1	the	the	DET
eurjchem-1549	153	2	reaction	reaction	NOUN
eurjchem-1549	153	3	was	be	AUX
eurjchem-1549	153	4	carried	carry	VERB
eurjchem-1549	153	5	out	out	ADP
eurjchem-1549	153	6	in	in	ADP
eurjchem-1549	153	7	the	the	DET
eurjchem-1549	153	8	presence	presence	NOUN
eurjchem-1549	153	9	of	of	ADP
eurjchem-1549	153	10	n‐acetylcysteine	n‐acetylcysteine	PUNCT
eurjchem-1549	153	11	as	as	ADP
eurjchem-1549	153	12	a	a	DET
eurjchem-1549	153	13	source	source	NOUN
eurjchem-1549	153	14	of	of	ADP
eurjchem-1549	153	15	thiol	thiol	NOUN
eurjchem-1549	153	16	to	to	PART
eurjchem-1549	153	17	facilitate	facilitate	VERB
eurjchem-1549	153	18	the	the	DET
eurjchem-1549	153	19	release	release	NOUN
eurjchem-1549	153	20	of	of	ADP
eurjchem-1549	153	21	no	no	PRON
eurjchem-1549	153	22	from	from	ADP
eurjchem-1549	153	23	the	the	DET
eurjchem-1549	153	24	compounds	compound	NOUN
eurjchem-1549	153	25	.	.	PUNCT
eurjchem-1549	154	1	the	the	DET
eurjchem-1549	154	2	no	no	DET
eurjchem-1549	154	3	release	release	NOUN
eurjchem-1549	154	4	was	be	AUX
eurjchem-1549	154	5	measured	measure	VERB
eurjchem-1549	154	6	at	at	ADP
eurjchem-1549	154	7	100	100	NUM
eurjchem-1549	154	8	μm	μm	NOUN
eurjchem-1549	154	9	concentration	concentration	NOUN
eurjchem-1549	154	10	of	of	ADP
eurjchem-1549	154	11	the	the	DET
eurjchem-1549	154	12	tested	test	VERB
eurjchem-1549	154	13	compounds	compound	NOUN
eurjchem-1549	154	14	and	and	CCONJ
eurjchem-1549	154	15	assessed	assess	VERB
eurjchem-1549	154	16	in	in	ADP
eurjchem-1549	154	17	the	the	DET
eurjchem-1549	154	18	stable	stable	ADJ
eurjchem-1549	154	19	nitrite	nitrite	NOUN
eurjchem-1549	154	20	form	form	NOUN
eurjchem-1549	154	21	relative	relative	ADJ
eurjchem-1549	154	22	to	to	ADP
eurjchem-1549	154	23	that	that	PRON
eurjchem-1549	154	24	of	of	ADP
eurjchem-1549	154	25	standard	standard	ADJ
eurjchem-1549	154	26	sodium	sodium	NOUN
eurjchem-1549	154	27	nitrite	nitrite	NOUN
eurjchem-1549	154	28	solution	solution	NOUN
eurjchem-1549	154	29	and	and	CCONJ
eurjchem-1549	154	30	calculated	calculate	VERB
eurjchem-1549	154	31	as	as	ADP
eurjchem-1549	154	32	amount	amount	NOUN
eurjchem-1549	154	33	of	of	ADP
eurjchem-1549	154	34	no	no	DET
eurjchem-1549	154	35	released	release	VERB
eurjchem-1549	154	36	(	(	PUNCT
eurjchem-1549	154	37	mol	mol	PROPN
eurjchem-1549	154	38	/	/	SYM
eurjchem-1549	154	39	mol	mol	NOUN
eurjchem-1549	154	40	)	)	PUNCT
eurjchem-1549	154	41	as	as	SCONJ
eurjchem-1549	154	42	shown	show	VERB
eurjchem-1549	154	43	in	in	ADP
eurjchem-1549	154	44	figure	figure	NOUN
eurjchem-1549	154	45	3	3	NUM
eurjchem-1549	154	46	.	.	PUNCT
eurjchem-1549	155	1	the	the	DET
eurjchem-1549	155	2	results	result	NOUN
eurjchem-1549	155	3	indicated	indicate	VERB
eurjchem-1549	155	4	that	that	SCONJ
eurjchem-1549	155	5	oxime	oxime	NOUN
eurjchem-1549	155	6	7	7	NUM
eurjchem-1549	155	7	and	and	CCONJ
eurjchem-1549	155	8	nitrate	nitrate	NOUN
eurjchem-1549	155	9	ester	ester	NOUN
eurjchem-1549	155	10	3	3	NUM
eurjchem-1549	155	11	had	have	VERB
eurjchem-1549	155	12	the	the	DET
eurjchem-1549	155	13	ability	ability	NOUN
eurjchem-1549	155	14	to	to	PART
eurjchem-1549	155	15	release	release	VERB
eurjchem-1549	155	16	no	no	INTJ
eurjchem-1549	155	17	,	,	PUNCT
eurjchem-1549	155	18	albeit	albeit	SCONJ
eurjchem-1549	155	19	in	in	ADP
eurjchem-1549	155	20	low	low	ADJ
eurjchem-1549	155	21	amounts	amount	NOUN
eurjchem-1549	155	22	;	;	PUNCT
eurjchem-1549	155	23	9	9	NUM
eurjchem-1549	155	24	and	and	CCONJ
eurjchem-1549	155	25	5	5	NUM
eurjchem-1549	155	26	μm	μm	NUM
eurjchem-1549	155	27	,	,	PUNCT
eurjchem-1549	155	28	respectively	respectively	ADV
eurjchem-1549	155	29	,	,	PUNCT
eurjchem-1549	155	30	as	as	ADP
eurjchem-1549	155	31	maximum	maximum	ADJ
eurjchem-1549	155	32	release	release	NOUN
eurjchem-1549	155	33	after	after	ADP
eurjchem-1549	155	34	30	30	NUM
eurjchem-1549	155	35	minutes	minute	NOUN
eurjchem-1549	155	36	.	.	PUNCT
eurjchem-1549	156	1	in	in	ADP
eurjchem-1549	156	2	contrast	contrast	NOUN
eurjchem-1549	156	3	,	,	PUNCT
eurjchem-1549	156	4	the	the	DET
eurjchem-1549	156	5	classical	classical	ADJ
eurjchem-1549	156	6	griess	griess	NOUN
eurjchem-1549	156	7	method	method	NOUN
eurjchem-1549	156	8	did	do	AUX
eurjchem-1549	156	9	not	not	PART
eurjchem-1549	156	10	allow	allow	VERB
eurjchem-1549	156	11	the	the	DET
eurjchem-1549	156	12	detection	detection	NOUN
eurjchem-1549	156	13	of	of	ADP
eurjchem-1549	156	14	measurable	measurable	ADJ
eurjchem-1549	156	15	amounts	amount	NOUN
eurjchem-1549	156	16	of	of	ADP
eurjchem-1549	156	17	no	no	PRON
eurjchem-1549	156	18	released	release	VERB
eurjchem-1549	156	19	from	from	ADP
eurjchem-1549	156	20	our	our	PRON
eurjchem-1549	156	21	compounds	compound	NOUN
eurjchem-1549	156	22	.	.	PUNCT
eurjchem-1549	157	1	this	this	PRON
eurjchem-1549	157	2	could	could	AUX
eurjchem-1549	157	3	probably	probably	ADV
eurjchem-1549	157	4	be	be	AUX
eurjchem-1549	157	5	explained	explain	VERB
eurjchem-1549	157	6	by	by	ADP
eurjchem-1549	157	7	considering	consider	VERB
eurjchem-1549	157	8	a	a	DET
eurjchem-1549	157	9	faster	fast	ADJ
eurjchem-1549	157	10	coupling	coupling	NOUN
eurjchem-1549	157	11	rate	rate	NOUN
eurjchem-1549	157	12	between	between	ADP
eurjchem-1549	157	13	ned	ned	NOUN
eurjchem-1549	157	14	and	and	CCONJ
eurjchem-1549	157	15	the	the	DET
eurjchem-1549	157	16	highly	highly	ADV
eurjchem-1549	157	17	electrophilic	electrophilic	ADJ
eurjchem-1549	157	18	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	157	19	diazonium	diazonium	NOUN
eurjchem-1549	157	20	salt	salt	NOUN
eurjchem-1549	157	21	in	in	ADP
eurjchem-1549	157	22	our	our	PRON
eurjchem-1549	157	23	new	new	ADJ
eurjchem-1549	157	24	method	method	NOUN
eurjchem-1549	157	25	in	in	ADP
eurjchem-1549	157	26	comparison	comparison	NOUN
eurjchem-1549	157	27	to	to	ADP
eurjchem-1549	157	28	the	the	DET
eurjchem-1549	157	29	relatively	relatively	ADV
eurjchem-1549	157	30	slower	slow	ADJ
eurjchem-1549	157	31	reaction	reaction	NOUN
eurjchem-1549	157	32	between	between	ADP
eurjchem-1549	157	33	ned	ned	ADJ
eurjchem-1549	157	34	and	and	CCONJ
eurjchem-1549	157	35	sulphanilamide	sulphanilamide	ADJ
eurjchem-1549	157	36	diazonium	diazonium	NOUN
eurjchem-1549	157	37	salt	salt	NOUN
eurjchem-1549	157	38	in	in	ADP
eurjchem-1549	157	39	the	the	DET
eurjchem-1549	157	40	conventional	conventional	ADJ
eurjchem-1549	157	41	method	method	NOUN
eurjchem-1549	157	42	.	.	PUNCT
eurjchem-1549	158	1	0	0	NUM
eurjchem-1549	159	1	1	1	NUM
eurjchem-1549	159	2	2	2	NUM
eurjchem-1549	159	3	3	3	NUM
eurjchem-1549	159	4	4	4	NUM
eurjchem-1549	159	5	5	5	NUM
eurjchem-1549	159	6	6	6	NUM
eurjchem-1549	159	7	7	7	NUM
eurjchem-1549	159	8	8	8	NUM
eurjchem-1549	159	9	9	9	NUM
eurjchem-1549	159	10	10	10	NUM
eurjchem-1549	159	11	10	10	NUM
eurjchem-1549	159	12	20	20	NUM
eurjchem-1549	159	13	30	30	NUM
eurjchem-1549	159	14	40	40	NUM
eurjchem-1549	159	15	50	50	NUM
eurjchem-1549	159	16	60	60	NUM
eurjchem-1549	159	17	n	n	NUM
eurjchem-1549	159	18	o	o	NOUN
eurjchem-1549	159	19	r	r	NOUN
eurjchem-1549	159	20	el	el	PROPN
eurjchem-1549	159	21	ea	ea	PROPN
eurjchem-1549	159	22	se	se	X
eurjchem-1549	159	23	(	(	PUNCT
eurjchem-1549	159	24	m	m	VERB
eurjchem-1549	159	25	o	o	X
eurjchem-1549	159	26	l	l	NOUN
eurjchem-1549	159	27	/	/	SYM
eurjchem-1549	159	28	m	m	PROPN
eurjchem-1549	159	29	o	o	NOUN
eurjchem-1549	159	30	l	l	NOUN
eurjchem-1549	159	31	)	)	PUNCT
eurjchem-1549	159	32	time	time	NOUN
eurjchem-1549	159	33	(	(	PUNCT
eurjchem-1549	159	34	min	min	NOUN
eurjchem-1549	159	35	.	.	PUNCT
eurjchem-1549	159	36	)	)	PUNCT
eurjchem-1549	160	1	compound	compound	NOUN
eurjchem-1549	160	2	3	3	NUM
eurjchem-1549	160	3	compound	compound	NOUN
eurjchem-1549	160	4	7	7	NUM
eurjchem-1549	160	5	figure	figure	NOUN
eurjchem-1549	160	6	3	3	NUM
eurjchem-1549	160	7	.	.	PUNCT
eurjchem-1549	161	1	no	no	DET
eurjchem-1549	161	2	release	release	NOUN
eurjchem-1549	161	3	from	from	ADP
eurjchem-1549	161	4	compounds	compound	NOUN
eurjchem-1549	161	5	3	3	NUM
eurjchem-1549	161	6	and	and	CCONJ
eurjchem-1549	161	7	7	7	NUM
eurjchem-1549	161	8	by	by	ADP
eurjchem-1549	161	9	the	the	DET
eurjchem-1549	161	10	newly	newly	ADV
eurjchem-1549	161	11	developed	develop	VERB
eurjchem-1549	161	12	griess	griess	NOUN
eurjchem-1549	161	13	method	method	NOUN
eurjchem-1549	161	14	.	.	PUNCT
eurjchem-1549	162	1	4	4	X
eurjchem-1549	162	2	.	.	X
eurjchem-1549	162	3	conclusion	conclusion	VERB
eurjchem-1549	162	4	new	new	ADJ
eurjchem-1549	162	5	norfloxacin	norfloxacin	PROPN
eurjchem-1549	162	6	/	/	SYM
eurjchem-1549	162	7	no	no	DET
eurjchem-1549	162	8	donor	donor	NOUN
eurjchem-1549	162	9	hybrids	hybrid	NOUN
eurjchem-1549	162	10	were	be	AUX
eurjchem-1549	162	11	synthesized	synthesize	VERB
eurjchem-1549	162	12	and	and	CCONJ
eurjchem-1549	162	13	characterized	characterize	VERB
eurjchem-1549	162	14	by	by	ADP
eurjchem-1549	162	15	various	various	ADJ
eurjchem-1549	162	16	spectroscopic	spectroscopic	ADJ
eurjchem-1549	162	17	tools	tool	NOUN
eurjchem-1549	162	18	.	.	PUNCT
eurjchem-1549	163	1	the	the	DET
eurjchem-1549	163	2	no	no	DET
eurjchem-1549	163	3	release	release	NOUN
eurjchem-1549	163	4	from	from	ADP
eurjchem-1549	163	5	the	the	DET
eurjchem-1549	163	6	target	target	NOUN
eurjchem-1549	163	7	compounds	compound	NOUN
eurjchem-1549	163	8	was	be	AUX
eurjchem-1549	163	9	estimated	estimate	VERB
eurjchem-1549	163	10	by	by	ADP
eurjchem-1549	163	11	a	a	DET
eurjchem-1549	163	12	modified	modify	VERB
eurjchem-1549	163	13	griess	griess	NOUN
eurjchem-1549	163	14	method	method	NOUN
eurjchem-1549	163	15	in	in	ADP
eurjchem-1549	163	16	which	which	PRON
eurjchem-1549	163	17	4‐nitroaniline	4‐nitroaniline	NUM
eurjchem-1549	163	18	was	be	AUX
eurjchem-1549	163	19	used	use	VERB
eurjchem-1549	163	20	instead	instead	ADV
eurjchem-1549	163	21	of	of	ADP
eurjchem-1549	163	22	sulfanilamide	sulfanilamide	NOUN
eurjchem-1549	163	23	.	.	PUNCT
eurjchem-1549	164	1	the	the	DET
eurjchem-1549	164	2	modified	modify	VERB
eurjchem-1549	164	3	method	method	NOUN
eurjchem-1549	164	4	led	lead	VERB
eurjchem-1549	164	5	to	to	ADP
eurjchem-1549	164	6	a	a	DET
eurjchem-1549	164	7	faster	fast	ADJ
eurjchem-1549	164	8	reaction	reaction	NOUN
eurjchem-1549	164	9	and	and	CCONJ
eurjchem-1549	164	10	improved	improved	ADJ
eurjchem-1549	164	11	sensitivity	sensitivity	NOUN
eurjchem-1549	164	12	for	for	ADP
eurjchem-1549	164	13	nitrite	nitrite	NOUN
eurjchem-1549	164	14	determination	determination	NOUN
eurjchem-1549	164	15	in	in	ADP
eurjchem-1549	164	16	comparison	comparison	NOUN
eurjchem-1549	164	17	to	to	ADP
eurjchem-1549	164	18	the	the	DET
eurjchem-1549	164	19	classical	classical	ADJ
eurjchem-1549	164	20	method	method	NOUN
eurjchem-1549	164	21	.	.	PUNCT
eurjchem-1549	165	1	despite	despite	SCONJ
eurjchem-1549	165	2	the	the	DET
eurjchem-1549	165	3	modest	modest	ADJ
eurjchem-1549	165	4	no	no	DET
eurjchem-1549	165	5	release	release	NOUN
eurjchem-1549	165	6	from	from	ADP
eurjchem-1549	165	7	our	our	PRON
eurjchem-1549	165	8	synthesized	synthesize	VERB
eurjchem-1549	165	9	hybrids	hybrid	NOUN
eurjchem-1549	165	10	,	,	PUNCT
eurjchem-1549	165	11	it	it	PRON
eurjchem-1549	165	12	is	be	AUX
eurjchem-1549	165	13	anticipated	anticipate	VERB
eurjchem-1549	165	14	that	that	SCONJ
eurjchem-1549	165	15	the	the	DET
eurjchem-1549	165	16	new	new	ADJ
eurjchem-1549	165	17	protocol	protocol	NOUN
eurjchem-1549	165	18	would	would	AUX
eurjchem-1549	165	19	find	find	VERB
eurjchem-1549	165	20	great	great	ADJ
eurjchem-1549	165	21	potential	potential	NOUN
eurjchem-1549	165	22	for	for	ADP
eurjchem-1549	165	23	the	the	DET
eurjchem-1549	165	24	analysis	analysis	NOUN
eurjchem-1549	165	25	of	of	ADP
eurjchem-1549	165	26	nitrites	nitrite	NOUN
eurjchem-1549	165	27	in	in	ADP
eurjchem-1549	165	28	various	various	ADJ
eurjchem-1549	165	29	systems	system	NOUN
eurjchem-1549	165	30	.	.	PUNCT
eurjchem-1549	166	1	acknowledgements	acknowledgement	NOUN
eurjchem-1549	166	2	we	we	PRON
eurjchem-1549	166	3	thank	thank	VERB
eurjchem-1549	166	4	dr	dr	PROPN
eurjchem-1549	166	5	safwat	safwat	PROPN
eurjchem-1549	166	6	rabea	rabea	ADJ
eurjchem-1549	166	7	(	(	PUNCT
eurjchem-1549	166	8	faculty	faculty	NOUN
eurjchem-1549	166	9	of	of	ADP
eurjchem-1549	166	10	pharmaceutical	pharmaceutical	NOUN
eurjchem-1549	166	11	sciences	science	NOUN
eurjchem-1549	166	12	,	,	PUNCT
eurjchem-1549	166	13	the	the	DET
eurjchem-1549	166	14	university	university	NOUN
eurjchem-1549	166	15	of	of	ADP
eurjchem-1549	166	16	british	british	PROPN
eurjchem-1549	166	17	columbia	columbia	PROPN
eurjchem-1549	166	18	,	,	PUNCT
eurjchem-1549	166	19	canada	canada	PROPN
eurjchem-1549	166	20	)	)	PUNCT
eurjchem-1549	166	21	,	,	PUNCT
eurjchem-1549	166	22	for	for	ADP
eurjchem-1549	166	23	measuring	measure	VERB
eurjchem-1549	166	24	the	the	DET
eurjchem-1549	166	25	high	high	ADJ
eurjchem-1549	166	26	resolution	resolution	NOUN
eurjchem-1549	166	27	mass	mass	NOUN
eurjchem-1549	166	28	spectra	spectra	NOUN
eurjchem-1549	166	29	for	for	ADP
eurjchem-1549	166	30	the	the	DET
eurjchem-1549	166	31	synthesized	synthesize	VERB
eurjchem-1549	166	32	compounds	compound	NOUN
eurjchem-1549	166	33	.	.	PUNCT
eurjchem-1549	167	1	references	reference	NOUN
eurjchem-1549	167	2	[	[	X
eurjchem-1549	167	3	1	1	NUM
eurjchem-1549	167	4	]	]	PUNCT
eurjchem-1549	167	5	.	.	PUNCT
eurjchem-1549	168	1	böhmer	böhmer	PROPN
eurjchem-1549	168	2	,	,	PUNCT
eurjchem-1549	168	3	a.	a.	NOUN
eurjchem-1549	168	4	;	;	PUNCT
eurjchem-1549	168	5	gambaryan	gambaryan	PROPN
eurjchem-1549	168	6	,	,	PUNCT
eurjchem-1549	168	7	s.	s.	PROPN
eurjchem-1549	168	8	;	;	PUNCT
eurjchem-1549	168	9	tsikas	tsikas	PROPN
eurjchem-1549	168	10	,	,	PUNCT
eurjchem-1549	168	11	d.	d.	NOUN
eurjchem-1549	168	12	platelets	platelet	VERB
eurjchem-1549	168	13	2015	2015	NUM
eurjchem-1549	168	14	,	,	PUNCT
eurjchem-1549	168	15	26	26	NUM
eurjchem-1549	168	16	(	(	PUNCT
eurjchem-1549	168	17	6	6	NUM
eurjchem-1549	168	18	)	)	PUNCT
eurjchem-1549	168	19	,	,	PUNCT
eurjchem-1549	168	20	583‐588	583‐588	PROPN
eurjchem-1549	168	21	.	.	PUNCT
eurjchem-1549	169	1	[	[	X
eurjchem-1549	169	2	2	2	NUM
eurjchem-1549	169	3	]	]	PUNCT
eurjchem-1549	169	4	.	.	PUNCT
eurjchem-1549	170	1	hirst	hirst	PROPN
eurjchem-1549	170	2	,	,	PUNCT
eurjchem-1549	170	3	d.	d.	PROPN
eurjchem-1549	170	4	g.	g.	PROPN
eurjchem-1549	170	5	;	;	PUNCT
eurjchem-1549	170	6	robson	robson	NOUN
eurjchem-1549	170	7	,	,	PUNCT
eurjchem-1549	170	8	t.	t.	NOUN
eurjchem-1549	170	9	nitric	nitric	ADJ
eurjchem-1549	170	10	oxide	oxide	NOUN
eurjchem-1549	170	11	:	:	PUNCT
eurjchem-1549	170	12	methods	method	NOUN
eurjchem-1549	170	13	and	and	CCONJ
eurjchem-1549	170	14	protocols	protocol	NOUN
eurjchem-1549	170	15	,	,	PUNCT
eurjchem-1549	170	16	humana	humana	PROPN
eurjchem-1549	170	17	press	press	PROPN
eurjchem-1549	170	18	,	,	PUNCT
eurjchem-1549	170	19	nj	nj	PROPN
eurjchem-1549	170	20	,	,	PUNCT
eurjchem-1549	170	21	usa	usa	PROPN
eurjchem-1549	170	22	,	,	PUNCT
eurjchem-1549	170	23	2011	2011	NUM
eurjchem-1549	170	24	,	,	PUNCT
eurjchem-1549	170	25	pp	pp	ADV
eurjchem-1549	170	26	.	.	PUNCT
eurjchem-1549	171	1	1‐13	1‐13	NUM
eurjchem-1549	171	2	.	.	PUNCT
eurjchem-1549	172	1	[	[	X
eurjchem-1549	172	2	3	3	NUM
eurjchem-1549	172	3	]	]	PUNCT
eurjchem-1549	172	4	.	.	PUNCT
eurjchem-1549	173	1	lundberg	lundberg	PROPN
eurjchem-1549	173	2	,	,	PUNCT
eurjchem-1549	173	3	j.	j.	PROPN
eurjchem-1549	173	4	o.	o.	PROPN
eurjchem-1549	173	5	;	;	PUNCT
eurjchem-1549	173	6	gladwin	gladwin	PROPN
eurjchem-1549	173	7	,	,	PUNCT
eurjchem-1549	173	8	m.	m.	NOUN
eurjchem-1549	173	9	t.	t.	PROPN
eurjchem-1549	173	10	;	;	PUNCT
eurjchem-1549	173	11	weitzberg	weitzberg	PROPN
eurjchem-1549	173	12	,	,	PUNCT
eurjchem-1549	173	13	e.	e.	PROPN
eurjchem-1549	173	14	nat	nat	PROPN
eurjchem-1549	173	15	.	.	PUNCT
eurjchem-1549	174	1	rev	rev	PROPN
eurjchem-1549	174	2	.	.	PROPN
eurjchem-1549	174	3	drug	drug	NOUN
eurjchem-1549	174	4	discov	discov	NOUN
eurjchem-1549	174	5	.	.	PUNCT
eurjchem-1549	175	1	2015	2015	NUM
eurjchem-1549	175	2	,	,	PUNCT
eurjchem-1549	175	3	14(9	14(9	NUM
eurjchem-1549	175	4	)	)	PUNCT
eurjchem-1549	175	5	,	,	PUNCT
eurjchem-1549	175	6	623‐641	623‐641	PROPN
eurjchem-1549	175	7	.	.	PUNCT
eurjchem-1549	176	1	[	[	X
eurjchem-1549	176	2	4	4	NUM
eurjchem-1549	176	3	]	]	PUNCT
eurjchem-1549	176	4	.	.	PUNCT
eurjchem-1549	176	5	kone	kone	PROPN
eurjchem-1549	176	6	,	,	PUNCT
eurjchem-1549	176	7	b.	b.	PROPN
eurjchem-1549	176	8	c.	c.	PROPN
eurjchem-1549	176	9	;	;	PUNCT
eurjchem-1549	176	10	baylis	baylis	PROPN
eurjchem-1549	176	11	,	,	PUNCT
eurjchem-1549	176	12	c.	c.	PROPN
eurjchem-1549	176	13	am	am	PROPN
eurjchem-1549	176	14	.	.	PUNCT
eurjchem-1549	177	1	j.	j.	PROPN
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eurjchem-1549	177	3	.	.	PUNCT
eurjchem-1549	178	1	renal	renal	PROPN
eurjchem-1549	178	2	physiol	physiol	PROPN
eurjchem-1549	178	3	.	.	PUNCT
eurjchem-1549	179	1	1997	1997	NUM
eurjchem-1549	179	2	,	,	PUNCT
eurjchem-1549	179	3	272(5	272(5	NUM
eurjchem-1549	179	4	)	)	PUNCT
eurjchem-1549	179	5	,	,	PUNCT
eurjchem-1549	179	6	f561‐	f561‐	VERB
eurjchem-1549	179	7	f578	f578	PROPN
eurjchem-1549	179	8	.	.	PUNCT
eurjchem-1549	180	1	124	124	NUM
eurjchem-1549	180	2	aziz	aziz	PROPN
eurjchem-1549	180	3	et	et	PROPN
eurjchem-1549	180	4	al	al	PROPN
eurjchem-1549	180	5	.	.	PUNCT
eurjchem-1549	180	6	/	/	SYM
eurjchem-1549	180	7	european	european	PROPN
eurjchem-1549	180	8	journal	journal	PROPN
eurjchem-1549	180	9	of	of	ADP
eurjchem-1549	180	10	chemistry	chemistry	NOUN
eurjchem-1549	180	11	8	8	NUM
eurjchem-1549	180	12	(	(	PUNCT
eurjchem-1549	180	13	2	2	NUM
eurjchem-1549	180	14	)	)	PUNCT
eurjchem-1549	180	15	(	(	PUNCT
eurjchem-1549	180	16	2017	2017	NUM
eurjchem-1549	180	17	)	)	PUNCT
eurjchem-1549	180	18	119‐124	119‐124	PROPN
eurjchem-1549	181	1	[	[	X
eurjchem-1549	181	2	5	5	NUM
eurjchem-1549	181	3	]	]	PUNCT
eurjchem-1549	181	4	.	.	PUNCT
eurjchem-1549	182	1	burke	burke	PROPN
eurjchem-1549	182	2	,	,	PUNCT
eurjchem-1549	182	3	a.	a.	PROPN
eurjchem-1549	182	4	j.	j.	PROPN
eurjchem-1549	182	5	;	;	PUNCT
eurjchem-1549	182	6	sullivan	sullivan	PROPN
eurjchem-1549	182	7	,	,	PUNCT
eurjchem-1549	182	8	f.	f.	PROPN
eurjchem-1549	182	9	j.	j.	PROPN
eurjchem-1549	182	10	;	;	PUNCT
eurjchem-1549	182	11	giles	giles	PROPN
eurjchem-1549	182	12	,	,	PUNCT
eurjchem-1549	182	13	f.	f.	PROPN
eurjchem-1549	182	14	j.	j.	PROPN
eurjchem-1549	182	15	;	;	PUNCT
eurjchem-1549	182	16	glynn	glynn	PROPN
eurjchem-1549	182	17	,	,	PUNCT
eurjchem-1549	182	18	s.	s.	PROPN
eurjchem-1549	182	19	a.	a.	NOUN
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eurjchem-1549	182	21	2013	2013	NUM
eurjchem-1549	182	22	,	,	PUNCT
eurjchem-1549	182	23	34(3	34(3	NUM
eurjchem-1549	182	24	)	)	PUNCT
eurjchem-1549	182	25	,	,	PUNCT
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eurjchem-1549	182	27	.	.	PUNCT
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eurjchem-1549	183	2	6	6	NUM
eurjchem-1549	183	3	]	]	PUNCT
eurjchem-1549	183	4	.	.	PUNCT
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eurjchem-1549	184	2	,	,	PUNCT
eurjchem-1549	184	3	h.	h.	PROPN
eurjchem-1549	184	4	;	;	PUNCT
eurjchem-1549	184	5	khan	khan	PROPN
eurjchem-1549	184	6	,	,	PUNCT
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eurjchem-1549	184	8	a.	a.	NOUN
eurjchem-1549	184	9	;	;	PUNCT
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eurjchem-1549	184	11	,	,	PUNCT
eurjchem-1549	184	12	u.	u.	PROPN
eurjchem-1549	184	13	;	;	PUNCT
eurjchem-1549	184	14	hussain	hussain	PROPN
eurjchem-1549	184	15	,	,	PUNCT
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eurjchem-1549	184	17	j.	j.	PROPN
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eurjchem-1549	184	20	.	.	PROPN
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eurjchem-1549	184	22	,	,	PUNCT
eurjchem-1549	184	23	21(1	21(1	NUM
eurjchem-1549	184	24	)	)	PUNCT
eurjchem-1549	184	25	,	,	PUNCT
eurjchem-1549	184	26	1‐12	1‐12	NUM
eurjchem-1549	184	27	.	.	PUNCT
eurjchem-1549	185	1	[	[	X
eurjchem-1549	185	2	7	7	NUM
eurjchem-1549	185	3	]	]	PUNCT
eurjchem-1549	185	4	.	.	PUNCT
eurjchem-1549	186	1	balez	balez	PROPN
eurjchem-1549	186	2	,	,	PUNCT
eurjchem-1549	186	3	r.	r.	PROPN
eurjchem-1549	186	4	;	;	PUNCT
eurjchem-1549	186	5	ooi	ooi	PROPN
eurjchem-1549	186	6	,	,	PUNCT
eurjchem-1549	186	7	l.	l.	PROPN
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eurjchem-1549	186	9	.	.	PUNCT
eurjchem-1549	187	1	med	med	PROPN
eurjchem-1549	187	2	.	.	PUNCT
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eurjchem-1549	187	4	.	.	PUNCT
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eurjchem-1549	188	2	.	.	PUNCT
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eurjchem-1549	188	4	,	,	PUNCT
eurjchem-1549	188	5	3806157	3806157	NUM
eurjchem-1549	188	6	.	.	PUNCT
eurjchem-1549	189	1	[	[	X
eurjchem-1549	189	2	8	8	NUM
eurjchem-1549	189	3	]	]	PUNCT
eurjchem-1549	189	4	.	.	PUNCT
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eurjchem-1549	190	2	,	,	PUNCT
eurjchem-1549	190	3	n.	n.	PROPN
eurjchem-1549	190	4	eur	eur	PROPN
eurjchem-1549	190	5	.	.	PUNCT
eurjchem-1549	191	1	j.	j.	PROPN
eurjchem-1549	191	2	pharmacol	pharmacol	PROPN
eurjchem-1549	191	3	.	.	PROPN
eurjchem-1549	192	1	2015	2015	NUM
eurjchem-1549	192	2	,	,	PUNCT
eurjchem-1549	192	3	766	766	NUM
eurjchem-1549	192	4	,	,	PUNCT
eurjchem-1549	192	5	106‐113	106‐113	NOUN
eurjchem-1549	192	6	.	.	PUNCT
eurjchem-1549	193	1	[	[	X
eurjchem-1549	193	2	9	9	NUM
eurjchem-1549	193	3	]	]	PUNCT
eurjchem-1549	193	4	.	.	PUNCT
eurjchem-1549	194	1	bi	bi	PROPN
eurjchem-1549	194	2	,	,	PUNCT
eurjchem-1549	194	3	y.	y.	PROPN
eurjchem-1549	194	4	;	;	PUNCT
eurjchem-1549	194	5	yang	yang	PROPN
eurjchem-1549	194	6	,	,	PUNCT
eurjchem-1549	194	7	x.	x.	PROPN
eurjchem-1549	194	8	;	;	PUNCT
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eurjchem-1549	194	10	,	,	PUNCT
eurjchem-1549	194	11	t.	t.	PROPN
eurjchem-1549	194	12	;	;	PUNCT
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eurjchem-1549	194	14	,	,	PUNCT
eurjchem-1549	194	15	z.	z.	PROPN
eurjchem-1549	194	16	;	;	PUNCT
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eurjchem-1549	194	18	,	,	PUNCT
eurjchem-1549	194	19	x.	x.	PROPN
eurjchem-1549	194	20	;	;	PUNCT
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eurjchem-1549	194	22	,	,	PUNCT
eurjchem-1549	194	23	j.	j.	PROPN
eurjchem-1549	194	24	;	;	PUNCT
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eurjchem-1549	194	26	,	,	PUNCT
eurjchem-1549	194	27	k.	k.	PROPN
eurjchem-1549	194	28	;	;	PUNCT
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eurjchem-1549	194	30	,	,	PUNCT
eurjchem-1549	194	31	j.	j.	PROPN
eurjchem-1549	194	32	;	;	PUNCT
eurjchem-1549	194	33	wang	wang	PROPN
eurjchem-1549	194	34	,	,	PUNCT
eurjchem-1549	194	35	h.	h.	PROPN
eurjchem-1549	194	36	;	;	PUNCT
eurjchem-1549	194	37	lv	lv	PROPN
eurjchem-1549	194	38	,	,	PUNCT
eurjchem-1549	194	39	g.	g.	PROPN
eurjchem-1549	194	40	eur	eur	PROPN
eurjchem-1549	194	41	.	.	PUNCT
eurjchem-1549	195	1	j.	j.	PROPN
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eurjchem-1549	195	3	.	.	PROPN
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eurjchem-1549	195	5	.	.	PUNCT
eurjchem-1549	196	1	2015	2015	NUM
eurjchem-1549	196	2	,	,	PUNCT
eurjchem-1549	196	3	101	101	NUM
eurjchem-1549	196	4	,	,	PUNCT
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eurjchem-1549	196	6	.	.	PUNCT
eurjchem-1549	197	1	[	[	X
eurjchem-1549	197	2	10	10	NUM
eurjchem-1549	197	3	]	]	PUNCT
eurjchem-1549	197	4	.	.	PUNCT
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eurjchem-1549	198	2	,	,	PUNCT
eurjchem-1549	198	3	l.	l.	PROPN
eurjchem-1549	198	4	j.	j.	PROPN
eurjchem-1549	198	5	nitric	nitric	PROPN
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eurjchem-1549	198	7	:	:	PUNCT
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eurjchem-1549	198	11	,	,	PUNCT
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eurjchem-1549	198	14	,	,	PUNCT
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eurjchem-1549	198	16	,	,	PUNCT
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eurjchem-1549	198	20	.	.	PUNCT
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eurjchem-1549	199	3	]	]	SYM
eurjchem-1549	199	4	.	.	PUNCT
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eurjchem-1549	200	2	,	,	PUNCT
eurjchem-1549	200	3	j.	j.	PROPN
eurjchem-1549	200	4	;	;	PUNCT
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eurjchem-1549	200	6	,	,	PUNCT
eurjchem-1549	200	7	h.	h.	PROPN
eurjchem-1549	200	8	;	;	PUNCT
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eurjchem-1549	200	10	,	,	PUNCT
eurjchem-1549	200	11	x.	x.	PROPN
eurjchem-1549	200	12	;	;	PUNCT
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eurjchem-1549	200	14	,	,	PUNCT
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eurjchem-1549	200	16	;	;	PUNCT
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eurjchem-1549	200	18	,	,	PUNCT
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eurjchem-1549	200	20	f.	f.	PROPN
eurjchem-1549	200	21	;	;	PUNCT
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eurjchem-1549	200	23	,	,	PUNCT
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eurjchem-1549	200	27	.	.	PUNCT
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eurjchem-1549	201	3	.	.	PUNCT
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eurjchem-1549	202	2	.	.	PROPN
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eurjchem-1549	202	4	,	,	PUNCT
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eurjchem-1549	202	6	)	)	PUNCT
eurjchem-1549	202	7	,	,	PUNCT
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eurjchem-1549	202	9	.	.	PUNCT
eurjchem-1549	203	1	[	[	X
eurjchem-1549	203	2	12	12	NUM
eurjchem-1549	203	3	]	]	PUNCT
eurjchem-1549	203	4	.	.	PUNCT
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eurjchem-1549	204	2	,	,	PUNCT
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eurjchem-1549	204	8	,	,	PUNCT
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eurjchem-1549	204	10	)	)	PUNCT
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eurjchem-1549	204	13	.	.	PUNCT
eurjchem-1549	205	1	[	[	X
eurjchem-1549	205	2	13	13	NUM
eurjchem-1549	205	3	]	]	SYM
eurjchem-1549	205	4	.	.	PUNCT
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eurjchem-1549	205	6	,	,	PUNCT
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eurjchem-1549	205	8	;	;	PUNCT
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eurjchem-1549	205	10	,	,	PUNCT
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eurjchem-1549	205	14	.	.	PUNCT
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eurjchem-1549	206	2	.	.	PROPN
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eurjchem-1549	206	4	.	.	PUNCT
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eurjchem-1549	207	2	.	.	PUNCT
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eurjchem-1549	208	2	,	,	PUNCT
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eurjchem-1549	208	4	)	)	PUNCT
eurjchem-1549	208	5	,	,	PUNCT
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eurjchem-1549	208	7	.	.	PUNCT
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eurjchem-1549	209	2	14	14	NUM
eurjchem-1549	209	3	]	]	PUNCT
eurjchem-1549	209	4	.	.	PUNCT
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eurjchem-1549	210	5	;	;	PUNCT
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eurjchem-1549	210	13	,	,	PUNCT
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eurjchem-1549	210	20	,	,	PUNCT
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eurjchem-1549	210	22	,	,	PUNCT
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eurjchem-1549	210	24	.	.	PUNCT
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eurjchem-1549	211	2	.	.	PUNCT
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eurjchem-1549	212	2	15	15	NUM
eurjchem-1549	212	3	]	]	PUNCT
eurjchem-1549	212	4	.	.	PUNCT
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eurjchem-1549	213	2	,	,	PUNCT
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eurjchem-1549	213	4	;	;	PUNCT
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eurjchem-1549	213	8	;	;	PUNCT
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eurjchem-1549	213	12	;	;	PUNCT
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eurjchem-1549	213	17	;	;	PUNCT
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eurjchem-1549	213	19	,	,	PUNCT
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eurjchem-1549	213	21	;	;	PUNCT
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eurjchem-1549	214	2	.	.	PUNCT
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eurjchem-1549	215	2	.	.	PUNCT
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eurjchem-1549	216	2	.	.	PROPN
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eurjchem-1549	216	4	,	,	PUNCT
eurjchem-1549	216	5	104(7	104(7	NUM
eurjchem-1549	216	6	)	)	PUNCT
eurjchem-1549	216	7	,	,	PUNCT
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eurjchem-1549	216	9	.	.	PUNCT
eurjchem-1549	217	1	[	[	X
eurjchem-1549	217	2	16	16	NUM
eurjchem-1549	217	3	]	]	PUNCT
eurjchem-1549	217	4	.	.	PUNCT
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eurjchem-1549	218	2	,	,	PUNCT
eurjchem-1549	218	3	h.	h.	PROPN
eurjchem-1549	218	4	;	;	PUNCT
eurjchem-1549	218	5	urano	urano	PROPN
eurjchem-1549	218	6	,	,	PUNCT
eurjchem-1549	218	7	y.	y.	PROPN
eurjchem-1549	218	8	;	;	PUNCT
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eurjchem-1549	218	20	;	;	PUNCT
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eurjchem-1549	218	22	,	,	PUNCT
eurjchem-1549	218	23	t.	t.	PROPN
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eurjchem-1549	218	25	.	.	PUNCT
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eurjchem-1549	219	2	.	.	PUNCT
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eurjchem-1549	220	2	.	.	PUNCT
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eurjchem-1549	221	4	,	,	PUNCT
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eurjchem-1549	221	6	)	)	PUNCT
eurjchem-1549	221	7	,	,	PUNCT
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eurjchem-1549	221	9	.	.	PUNCT
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eurjchem-1549	222	3	]	]	PUNCT
eurjchem-1549	222	4	.	.	PUNCT
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eurjchem-1549	223	5	;	;	PUNCT
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eurjchem-1549	225	2	.	.	PROPN
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eurjchem-1549	226	2	,	,	PUNCT
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eurjchem-1549	226	4	)	)	PUNCT
eurjchem-1549	226	5	,	,	PUNCT
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eurjchem-1549	226	7	657	657	NUM
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eurjchem-1549	227	2	18	18	NUM
eurjchem-1549	227	3	]	]	PUNCT
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eurjchem-1549	228	2	,	,	PUNCT
eurjchem-1549	228	3	k.	k.	PROPN
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eurjchem-1549	229	4	,	,	PUNCT
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eurjchem-1549	229	6	)	)	PUNCT
eurjchem-1549	229	7	,	,	PUNCT
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eurjchem-1549	229	9	.	.	PUNCT
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eurjchem-1549	230	3	]	]	PUNCT
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eurjchem-1549	231	12	s.	s.	PROPN
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eurjchem-1549	233	2	,	,	PUNCT
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eurjchem-1549	233	4	)	)	PUNCT
eurjchem-1549	233	5	,	,	PUNCT
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eurjchem-1549	234	2	20	20	NUM
eurjchem-1549	234	3	]	]	PUNCT
eurjchem-1549	234	4	.	.	PUNCT
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eurjchem-1549	235	2	,	,	PUNCT
eurjchem-1549	235	3	i.	i.	PROPN
eurjchem-1549	235	4	;	;	PUNCT
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eurjchem-1549	237	5	)	)	PUNCT
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eurjchem-1549	238	3	]	]	PUNCT
eurjchem-1549	238	4	.	.	PUNCT
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eurjchem-1549	242	2	.	.	PROPN
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eurjchem-1549	244	9	;	;	PUNCT
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eurjchem-1549	245	2	,	,	PUNCT
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eurjchem-1549	251	5	;	;	PUNCT
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eurjchem-1549	251	7	,	,	PUNCT
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