id	sid	tid	token	lemma	pos
eurjchem-1564	1	1	untitled	untitle	VERB
eurjchem-1564	1	2	european	european	PROPN
eurjchem-1564	1	3	journal	journal	PROPN
eurjchem-1564	1	4	of	of	ADP
eurjchem-1564	1	5	chemistry	chemistry	NOUN
eurjchem-1564	1	6	8	8	NUM
eurjchem-1564	1	7	(	(	PUNCT
eurjchem-1564	1	8	2	2	NUM
eurjchem-1564	1	9	)	)	PUNCT
eurjchem-1564	1	10	(	(	PUNCT
eurjchem-1564	1	11	2017	2017	NUM
eurjchem-1564	1	12	)	)	PUNCT
eurjchem-1564	1	13	155‐161	155‐161	NUM
eurjchem-1564	1	14	european	european	PROPN
eurjchem-1564	1	15	journal	journal	PROPN
eurjchem-1564	1	16	of	of	ADP
eurjchem-1564	1	17	chemistry	chemistry	NOUN
eurjchem-1564	1	18	issn	issn	PROPN
eurjchem-1564	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-1564	1	20	(	(	PUNCT
eurjchem-1564	1	21	print	print	NOUN
eurjchem-1564	1	22	)	)	PUNCT
eurjchem-1564	1	23	/	/	SYM
eurjchem-1564	1	24	issn	issn	PROPN
eurjchem-1564	1	25	2153‐2257	2153‐2257	NUM
eurjchem-1564	1	26	(	(	PUNCT
eurjchem-1564	1	27	online	online	ADJ
eurjchem-1564	1	28	)	)	PUNCT
eurjchem-1564	1	29			NOUN
eurjchem-1564	1	30	2017	2017	NUM
eurjchem-1564	1	31	atlanta	atlanta	PROPN
eurjchem-1564	1	32	publishing	publishing	PROPN
eurjchem-1564	1	33	house	house	PROPN
eurjchem-1564	1	34	llc	llc	PROPN
eurjchem-1564	1	35	‐	‐	PUNCT
eurjchem-1564	1	36	all	all	DET
eurjchem-1564	1	37	rights	right	NOUN
eurjchem-1564	1	38	reserved	reserve	VERB
eurjchem-1564	1	39	‐	‐	NOUN
eurjchem-1564	1	40	printed	print	VERB
eurjchem-1564	1	41	in	in	ADP
eurjchem-1564	1	42	the	the	DET
eurjchem-1564	1	43	usa	usa	PROPN
eurjchem-1564	1	44	http://dx.doi.org/10.5155/eurjchem.8.2.155-161.1564	http://dx.doi.org/10.5155/eurjchem.8.2.155-161.1564	PROPN
eurjchem-1564	1	45	european	european	PROPN
eurjchem-1564	1	46	journal	journal	PROPN
eurjchem-1564	1	47	of	of	ADP
eurjchem-1564	1	48	chemistry	chemistry	PROPN
eurjchem-1564	1	49	journal	journal	PROPN
eurjchem-1564	1	50	webpage	webpage	NOUN
eurjchem-1564	1	51	:	:	PUNCT
eurjchem-1564	1	52	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1564	1	53	synthesis	synthesis	NOUN
eurjchem-1564	1	54	,	,	PUNCT
eurjchem-1564	1	55	characterization	characterization	NOUN
eurjchem-1564	1	56	and	and	CCONJ
eurjchem-1564	1	57	biological	biological	ADJ
eurjchem-1564	1	58	activity	activity	NOUN
eurjchem-1564	1	59	study	study	NOUN
eurjchem-1564	1	60	of	of	ADP
eurjchem-1564	1	61	some	some	DET
eurjchem-1564	1	62	new	new	ADJ
eurjchem-1564	1	63	palladium(ii	palladium(ii	NOUN
eurjchem-1564	1	64	)	)	PUNCT
eurjchem-1564	1	65	complexes	complex	NOUN
eurjchem-1564	1	66	containing	contain	VERB
eurjchem-1564	1	67	amine	amine	ADJ
eurjchem-1564	1	68	or	or	CCONJ
eurjchem-1564	1	69	azomethine	azomethine	NOUN
eurjchem-1564	1	70	groups	group	NOUN
eurjchem-1564	1	71	adil	adil	PROPN
eurjchem-1564	1	72	ali	ali	PROPN
eurjchem-1564	2	1	al‐fregi	al‐fregi	PROPN
eurjchem-1564	2	2	*	*	PROPN
eurjchem-1564	2	3	,	,	PUNCT
eurjchem-1564	2	4	ahmed	ahmed	PROPN
eurjchem-1564	2	5	laith	laith	PROPN
eurjchem-1564	2	6	al‐fadhly	al‐fadhly	ADV
eurjchem-1564	2	7	and	and	CCONJ
eurjchem-1564	2	8	bushra	bushra	PROPN
eurjchem-1564	2	9	kamel	kamel	PROPN
eurjchem-1564	2	10	al‐salami	al‐salami	PROPN
eurjchem-1564	2	11	department	department	PROPN
eurjchem-1564	2	12	of	of	ADP
eurjchem-1564	2	13	chemistry	chemistry	NOUN
eurjchem-1564	2	14	,	,	PUNCT
eurjchem-1564	2	15	college	college	NOUN
eurjchem-1564	2	16	of	of	ADP
eurjchem-1564	2	17	science	science	NOUN
eurjchem-1564	2	18	,	,	PUNCT
eurjchem-1564	2	19	university	university	NOUN
eurjchem-1564	2	20	of	of	ADP
eurjchem-1564	2	21	basrah	basrah	PROPN
eurjchem-1564	2	22	,	,	PUNCT
eurjchem-1564	2	23	61001	61001	NUM
eurjchem-1564	2	24	,	,	PUNCT
eurjchem-1564	2	25	basrah	basrah	PROPN
eurjchem-1564	2	26	,	,	PUNCT
eurjchem-1564	2	27	iraq	iraq	PROPN
eurjchem-1564	2	28	*	*	PUNCT
eurjchem-1564	2	29	corresponding	correspond	VERB
eurjchem-1564	2	30	author	author	NOUN
eurjchem-1564	2	31	at	at	ADP
eurjchem-1564	2	32	:	:	PUNCT
eurjchem-1564	2	33	department	department	NOUN
eurjchem-1564	2	34	of	of	ADP
eurjchem-1564	2	35	chemistry	chemistry	NOUN
eurjchem-1564	2	36	,	,	PUNCT
eurjchem-1564	2	37	college	college	NOUN
eurjchem-1564	2	38	of	of	ADP
eurjchem-1564	2	39	science	science	NOUN
eurjchem-1564	2	40	,	,	PUNCT
eurjchem-1564	2	41	university	university	NOUN
eurjchem-1564	2	42	of	of	ADP
eurjchem-1564	2	43	basrah	basrah	PROPN
eurjchem-1564	2	44	,	,	PUNCT
eurjchem-1564	2	45	61001	61001	NUM
eurjchem-1564	2	46	,	,	PUNCT
eurjchem-1564	2	47	basrah	basrah	PROPN
eurjchem-1564	2	48	,	,	PUNCT
eurjchem-1564	2	49	iraq	iraq	PROPN
eurjchem-1564	2	50	.	.	PUNCT
eurjchem-1564	3	1	tel	tel	PROPN
eurjchem-1564	3	2	.	.	PUNCT
eurjchem-1564	3	3	:	:	PUNCT
eurjchem-1564	4	1	+964.40.7707377383	+964.40.7707377383	PROPN
eurjchem-1564	4	2	.	.	PUNCT
eurjchem-1564	5	1	fax	fax	NOUN
eurjchem-1564	5	2	:	:	PUNCT
eurjchem-1564	5	3	+964.40.7707377383	+964.40.7707377383	PROPN
eurjchem-1564	5	4	.	.	PUNCT
eurjchem-1564	5	5	e‐mail	e‐mail	PUNCT
eurjchem-1564	6	1	address	address	NOUN
eurjchem-1564	6	2	:	:	PUNCT
eurjchem-1564	6	3	dr.adilalfregi@yahoo.com	dr.adilalfregi@yahoo.com	PROPN
eurjchem-1564	6	4	(	(	PUNCT
eurjchem-1564	6	5	a.a	a.a	PROPN
eurjchem-1564	6	6	.	.	PROPN
eurjchem-1564	6	7	al‐fregi	al‐fregi	PROPN
eurjchem-1564	6	8	)	)	PUNCT
eurjchem-1564	6	9	.	.	PUNCT
eurjchem-1564	7	1	article	article	NOUN
eurjchem-1564	7	2	information	information	PROPN
eurjchem-1564	7	3	abstract	abstract	ADJ
eurjchem-1564	7	4	doi	doi	PROPN
eurjchem-1564	7	5	:	:	PUNCT
eurjchem-1564	7	6	 	 	SPACE
eurjchem-1564	7	7	10.5155	10.5155	NUM
eurjchem-1564	7	8	/	/	SYM
eurjchem-1564	7	9	eurjchem.8.2.155	eurjchem.8.2.155	PROPN
eurjchem-1564	7	10	-	-	SYM
eurjchem-1564	7	11	161.1564	161.1564	NUM
eurjchem-1564	7	12	received	receive	VERB
eurjchem-1564	7	13	:	:	PUNCT
eurjchem-1564	7	14	09	09	NUM
eurjchem-1564	7	15	march	march	NOUN
eurjchem-1564	7	16	2017	2017	NUM
eurjchem-1564	7	17	received	receive	VERB
eurjchem-1564	7	18	in	in	ADP
eurjchem-1564	7	19	revised	revise	VERB
eurjchem-1564	7	20	form	form	NOUN
eurjchem-1564	7	21	:	:	PUNCT
eurjchem-1564	7	22	12	12	NUM
eurjchem-1564	7	23	april	april	PROPN
eurjchem-1564	7	24	2017	2017	NUM
eurjchem-1564	7	25	accepted	accept	VERB
eurjchem-1564	7	26	:	:	PUNCT
eurjchem-1564	7	27	19	19	NUM
eurjchem-1564	7	28	april	april	PROPN
eurjchem-1564	7	29	2017	2017	NUM
eurjchem-1564	7	30	published	publish	VERB
eurjchem-1564	7	31	online	online	ADV
eurjchem-1564	7	32	:	:	PUNCT
eurjchem-1564	7	33	30	30	NUM
eurjchem-1564	7	34	june	june	PROPN
eurjchem-1564	7	35	2017	2017	NUM
eurjchem-1564	7	36	printed	print	VERB
eurjchem-1564	7	37	:	:	PUNCT
eurjchem-1564	7	38	30	30	NUM
eurjchem-1564	7	39	june	june	PROPN
eurjchem-1564	7	40	2017	2017	NUM
eurjchem-1564	7	41	  	  	SPACE
eurjchem-1564	7	42	this	this	DET
eurjchem-1564	7	43	study	study	NOUN
eurjchem-1564	7	44	reports	report	VERB
eurjchem-1564	7	45	the	the	DET
eurjchem-1564	7	46	preparative	preparative	ADJ
eurjchem-1564	7	47	methods	method	NOUN
eurjchem-1564	7	48	of	of	ADP
eurjchem-1564	7	49	two	two	NUM
eurjchem-1564	7	50	types	type	NOUN
eurjchem-1564	7	51	of	of	ADP
eurjchem-1564	7	52	palladium(ii	palladium(ii	NOUN
eurjchem-1564	7	53	)	)	PUNCT
eurjchem-1564	7	54	complexes	complex	NOUN
eurjchem-1564	7	55	.	.	PUNCT
eurjchem-1564	8	1	the	the	DET
eurjchem-1564	8	2	first	first	ADJ
eurjchem-1564	8	3	method	method	NOUN
eurjchem-1564	8	4	revealed	reveal	VERB
eurjchem-1564	8	5	two	two	NUM
eurjchem-1564	8	6	newly	newly	ADV
eurjchem-1564	8	7	palladium	palladium	NOUN
eurjchem-1564	8	8	(	(	PUNCT
eurjchem-1564	8	9	ii	ii	NOUN
eurjchem-1564	8	10	)	)	PUNCT
eurjchem-1564	8	11	complexes	complex	NOUN
eurjchem-1564	8	12	derived	derive	VERB
eurjchem-1564	8	13	from	from	ADP
eurjchem-1564	8	14	bidentate	bidentate	ADJ
eurjchem-1564	8	15	amine	amine	ADJ
eurjchem-1564	8	16	ligands	ligand	NOUN
eurjchem-1564	8	17	,	,	PUNCT
eurjchem-1564	8	18	and	and	CCONJ
eurjchem-1564	8	19	the	the	DET
eurjchem-1564	8	20	second	second	ADJ
eurjchem-1564	8	21	one	one	NOUN
eurjchem-1564	8	22	describes	describe	VERB
eurjchem-1564	8	23	six	six	NUM
eurjchem-1564	8	24	newly	newly	ADV
eurjchem-1564	8	25	palladium(ii	palladium(ii	NOUN
eurjchem-1564	8	26	)	)	PUNCT
eurjchem-1564	8	27	complexes	complex	NOUN
eurjchem-1564	8	28	derived	derive	VERB
eurjchem-1564	8	29	from	from	ADP
eurjchem-1564	8	30	bidentate	bidentate	ADJ
eurjchem-1564	8	31	schiff	schiff	NOUN
eurjchem-1564	8	32	base	base	NOUN
eurjchem-1564	8	33	ligands	ligand	NOUN
eurjchem-1564	8	34	.	.	PUNCT
eurjchem-1564	9	1	all	all	DET
eurjchem-1564	9	2	the	the	DET
eurjchem-1564	9	3	synthesized	synthesize	VERB
eurjchem-1564	9	4	complexes	complex	NOUN
eurjchem-1564	9	5	have	have	AUX
eurjchem-1564	9	6	been	be	AUX
eurjchem-1564	9	7	characterized	characterize	VERB
eurjchem-1564	9	8	by	by	ADP
eurjchem-1564	9	9	elemental	elemental	ADJ
eurjchem-1564	9	10	analysis	analysis	NOUN
eurjchem-1564	9	11	,	,	PUNCT
eurjchem-1564	9	12	conductivity	conductivity	NOUN
eurjchem-1564	9	13	measurements	measurement	NOUN
eurjchem-1564	9	14	,	,	PUNCT
eurjchem-1564	9	15	uv‐visible	uv‐visible	ADJ
eurjchem-1564	9	16	,	,	PUNCT
eurjchem-1564	9	17	ft‐ir	ft‐ir	NOUN
eurjchem-1564	9	18	and	and	CCONJ
eurjchem-1564	9	19	1h	1h	NUM
eurjchem-1564	9	20	nmr	nmr	PROPN
eurjchem-1564	9	21	spectral	spectral	ADJ
eurjchem-1564	9	22	data	datum	NOUN
eurjchem-1564	9	23	.	.	PUNCT
eurjchem-1564	10	1	in	in	ADP
eurjchem-1564	10	2	vitro	vitro	X
eurjchem-1564	10	3	,	,	PUNCT
eurjchem-1564	10	4	all	all	DET
eurjchem-1564	10	5	the	the	DET
eurjchem-1564	10	6	synthesized	synthesize	VERB
eurjchem-1564	10	7	complexes	complex	NOUN
eurjchem-1564	10	8	have	have	AUX
eurjchem-1564	10	9	been	be	AUX
eurjchem-1564	10	10	tested	test	VERB
eurjchem-1564	10	11	for	for	ADP
eurjchem-1564	10	12	their	their	PRON
eurjchem-1564	10	13	growth	growth	NOUN
eurjchem-1564	10	14	inhibitory	inhibitory	ADJ
eurjchem-1564	10	15	activity	activity	NOUN
eurjchem-1564	10	16	against	against	ADP
eurjchem-1564	10	17	gram	gram	NOUN
eurjchem-1564	10	18	negative	negative	ADJ
eurjchem-1564	10	19	bacteria	bacteria	NOUN
eurjchem-1564	10	20	escherichia	escherichia	NOUN
eurjchem-1564	10	21	coli	coli	NOUN
eurjchem-1564	10	22	and	and	CCONJ
eurjchem-1564	10	23	gram	gram	NOUN
eurjchem-1564	10	24	positive	positive	ADJ
eurjchem-1564	10	25	staphylococcus	staphylococcus	NOUN
eurjchem-1564	10	26	aureus	aureus	NOUN
eurjchem-1564	10	27	as	as	ADV
eurjchem-1564	10	28	well	well	ADV
eurjchem-1564	10	29	as	as	ADP
eurjchem-1564	10	30	determining	determine	VERB
eurjchem-1564	10	31	the	the	DET
eurjchem-1564	10	32	minimum	minimum	ADJ
eurjchem-1564	10	33	inhibitory	inhibitory	ADJ
eurjchem-1564	10	34	concentration	concentration	NOUN
eurjchem-1564	10	35	.	.	PUNCT
eurjchem-1564	11	1	in	in	ADP
eurjchem-1564	11	2	addition	addition	NOUN
eurjchem-1564	11	3	,	,	PUNCT
eurjchem-1564	11	4	the	the	DET
eurjchem-1564	11	5	interactions	interaction	NOUN
eurjchem-1564	11	6	between	between	ADP
eurjchem-1564	11	7	compounded	compound	VERB
eurjchem-1564	11	8	complexes	complex	NOUN
eurjchem-1564	11	9	and	and	CCONJ
eurjchem-1564	11	10	human	human	ADJ
eurjchem-1564	11	11	dna	dna	PROPN
eurjchem-1564	11	12	were	be	AUX
eurjchem-1564	11	13	also	also	ADV
eurjchem-1564	11	14	studied	study	VERB
eurjchem-1564	11	15	.	.	PUNCT
eurjchem-1564	12	1	keywords	keyword	NOUN
eurjchem-1564	12	2	schiff	schiff	VERB
eurjchem-1564	12	3	base	base	NOUN
eurjchem-1564	12	4	amine	amine	ADJ
eurjchem-1564	12	5	ligands	ligand	NOUN
eurjchem-1564	12	6	antibacterial	antibacterial	ADJ
eurjchem-1564	12	7	activity	activity	NOUN
eurjchem-1564	12	8	bidentate	bidentate	VERB
eurjchem-1564	12	9	amine	amine	ADJ
eurjchem-1564	12	10	ligands	ligand	NOUN
eurjchem-1564	12	11	palladium(ii	palladium(ii	NOUN
eurjchem-1564	12	12	)	)	PUNCT
eurjchem-1564	12	13	complexes	complexe	VERB
eurjchem-1564	12	14	human	human	ADJ
eurjchem-1564	12	15	dna	dna	PROPN
eurjchem-1564	12	16	interactions	interaction	NOUN
eurjchem-1564	12	17	cite	cite	VERB
eurjchem-1564	12	18	this	this	PRON
eurjchem-1564	12	19	:	:	PUNCT
eurjchem-1564	12	20	eur	eur	PROPN
eurjchem-1564	12	21	.	.	PUNCT
eurjchem-1564	13	1	j.	j.	PROPN
eurjchem-1564	13	2	chem	chem	PROPN
eurjchem-1564	13	3	.	.	PUNCT
eurjchem-1564	14	1	2017	2017	NUM
eurjchem-1564	14	2	,	,	PUNCT
eurjchem-1564	14	3	8(2	8(2	NUM
eurjchem-1564	14	4	)	)	PUNCT
eurjchem-1564	14	5	,	,	PUNCT
eurjchem-1564	14	6	155‐161	155‐161	NUM
eurjchem-1564	14	7	1	1	NUM
eurjchem-1564	14	8	.	.	PUNCT
eurjchem-1564	15	1	introduction	introduction	NOUN
eurjchem-1564	15	2	cancer	cancer	NOUN
eurjchem-1564	15	3	may	may	AUX
eurjchem-1564	15	4	define	define	VERB
eurjchem-1564	15	5	as	as	ADP
eurjchem-1564	15	6	a	a	DET
eurjchem-1564	15	7	disease	disease	NOUN
eurjchem-1564	15	8	or	or	CCONJ
eurjchem-1564	15	9	a	a	DET
eurjchem-1564	15	10	group	group	NOUN
eurjchem-1564	15	11	of	of	ADP
eurjchem-1564	15	12	diseases	disease	NOUN
eurjchem-1564	15	13	,	,	PUNCT
eurjchem-1564	15	14	which	which	PRON
eurjchem-1564	15	15	has	have	VERB
eurjchem-1564	15	16	the	the	DET
eurjchem-1564	15	17	ability	ability	NOUN
eurjchem-1564	15	18	to	to	PART
eurjchem-1564	15	19	metastasize	metastasize	VERB
eurjchem-1564	15	20	into	into	ADP
eurjchem-1564	15	21	the	the	DET
eurjchem-1564	15	22	body	body	NOUN
eurjchem-1564	15	23	,	,	PUNCT
eurjchem-1564	15	24	destroy	destroy	VERB
eurjchem-1564	15	25	healthy	healthy	ADJ
eurjchem-1564	15	26	tissues	tissue	NOUN
eurjchem-1564	15	27	and	and	CCONJ
eurjchem-1564	15	28	endanger	endanger	VERB
eurjchem-1564	15	29	life	life	NOUN
eurjchem-1564	15	30	.	.	PUNCT
eurjchem-1564	16	1	therefore	therefore	ADV
eurjchem-1564	16	2	,	,	PUNCT
eurjchem-1564	16	3	it	it	PRON
eurjchem-1564	16	4	is	be	AUX
eurjchem-1564	16	5	the	the	DET
eurjchem-1564	16	6	one	one	NUM
eurjchem-1564	16	7	of	of	ADP
eurjchem-1564	16	8	major	major	ADJ
eurjchem-1564	16	9	causes	cause	NOUN
eurjchem-1564	16	10	of	of	ADP
eurjchem-1564	16	11	death	death	NOUN
eurjchem-1564	16	12	in	in	ADP
eurjchem-1564	16	13	many	many	ADJ
eurjchem-1564	16	14	countries	country	NOUN
eurjchem-1564	16	15	across	across	ADP
eurjchem-1564	16	16	the	the	DET
eurjchem-1564	16	17	world	world	NOUN
eurjchem-1564	16	18	.	.	PUNCT
eurjchem-1564	17	1	about	about	ADV
eurjchem-1564	17	2	20	20	NUM
eurjchem-1564	17	3	million	million	NUM
eurjchem-1564	17	4	cancer	cancer	NOUN
eurjchem-1564	17	5	cases	case	NOUN
eurjchem-1564	17	6	are	be	AUX
eurjchem-1564	17	7	expected	expect	VERB
eurjchem-1564	17	8	to	to	PART
eurjchem-1564	17	9	occur	occur	VERB
eurjchem-1564	17	10	in	in	ADP
eurjchem-1564	17	11	the	the	DET
eurjchem-1564	17	12	next	next	ADJ
eurjchem-1564	17	13	two	two	NUM
eurjchem-1564	17	14	decades	decade	NOUN
eurjchem-1564	17	15	,	,	PUNCT
eurjchem-1564	17	16	which	which	PRON
eurjchem-1564	17	17	render	render	VERB
eurjchem-1564	17	18	the	the	DET
eurjchem-1564	17	19	quest	quest	NOUN
eurjchem-1564	17	20	for	for	ADP
eurjchem-1564	17	21	new	new	ADJ
eurjchem-1564	17	22	antineoplastic	antineoplastic	ADJ
eurjchem-1564	17	23	agents	agent	NOUN
eurjchem-1564	18	1	[	[	X
eurjchem-1564	18	2	1	1	NUM
eurjchem-1564	18	3	]	]	PUNCT
eurjchem-1564	18	4	.	.	PUNCT
eurjchem-1564	19	1	although	although	SCONJ
eurjchem-1564	19	2	many	many	ADJ
eurjchem-1564	19	3	drug	drug	NOUN
eurjchem-1564	19	4	molecules	molecule	NOUN
eurjchem-1564	19	5	are	be	AUX
eurjchem-1564	19	6	naturally	naturally	ADV
eurjchem-1564	19	7	organic	organic	ADJ
eurjchem-1564	19	8	,	,	PUNCT
eurjchem-1564	19	9	there	there	PRON
eurjchem-1564	19	10	are	be	VERB
eurjchem-1564	19	11	also	also	ADV
eurjchem-1564	19	12	metal	metal	NOUN
eurjchem-1564	19	13	elements	element	NOUN
eurjchem-1564	19	14	,	,	PUNCT
eurjchem-1564	19	15	which	which	PRON
eurjchem-1564	19	16	offer	offer	VERB
eurjchem-1564	19	17	different	different	ADJ
eurjchem-1564	19	18	role	role	NOUN
eurjchem-1564	19	19	in	in	ADP
eurjchem-1564	19	20	chemistry	chemistry	NOUN
eurjchem-1564	19	21	and	and	CCONJ
eurjchem-1564	19	22	have	have	VERB
eurjchem-1564	19	23	important	important	ADJ
eurjchem-1564	19	24	therapeutic	therapeutic	ADJ
eurjchem-1564	19	25	applications	application	NOUN
eurjchem-1564	19	26	;	;	PUNCT
eurjchem-1564	19	27	such	such	ADJ
eurjchem-1564	19	28	as	as	ADP
eurjchem-1564	19	29	platinum	platinum	NOUN
eurjchem-1564	19	30	metal	metal	NOUN
eurjchem-1564	20	1	[	[	X
eurjchem-1564	20	2	1	1	NUM
eurjchem-1564	20	3	]	]	PUNCT
eurjchem-1564	20	4	.	.	PUNCT
eurjchem-1564	21	1	cis‐diamminedichloro	cis‐diamminedichloro	PROPN
eurjchem-1564	21	2	platinum(ii	platinum(ii	PROPN
eurjchem-1564	21	3	)	)	PUNCT
eurjchem-1564	21	4	,	,	PUNCT
eurjchem-1564	21	5	cis‐platin	cis‐platin	PROPN
eurjchem-1564	21	6	,	,	PUNCT
eurjchem-1564	21	7	is	be	AUX
eurjchem-1564	21	8	one	one	NUM
eurjchem-1564	21	9	of	of	ADP
eurjchem-1564	21	10	the	the	DET
eurjchem-1564	21	11	most	most	ADV
eurjchem-1564	21	12	potent	potent	ADJ
eurjchem-1564	21	13	and	and	CCONJ
eurjchem-1564	21	14	effective	effective	ADJ
eurjchem-1564	21	15	antitumor	antitumor	PROPN
eurjchem-1564	21	16	agent	agent	NOUN
eurjchem-1564	21	17	that	that	SCONJ
eurjchem-1564	21	18	it	it	PRON
eurjchem-1564	21	19	was	be	AUX
eurjchem-1564	21	20	introduced	introduce	VERB
eurjchem-1564	21	21	to	to	ADP
eurjchem-1564	21	22	chemotherapeutic	chemotherapeutic	ADJ
eurjchem-1564	21	23	treatment	treatment	NOUN
eurjchem-1564	21	24	in	in	ADP
eurjchem-1564	21	25	1978	1978	NUM
eurjchem-1564	21	26	[	[	X
eurjchem-1564	21	27	2	2	NUM
eurjchem-1564	21	28	]	]	PUNCT
eurjchem-1564	21	29	,	,	PUNCT
eurjchem-1564	21	30	its	its	PRON
eurjchem-1564	21	31	lack	lack	NOUN
eurjchem-1564	21	32	of	of	ADP
eurjchem-1564	21	33	selectivity	selectivity	NOUN
eurjchem-1564	21	34	through	through	ADP
eurjchem-1564	21	35	tumor	tumor	NOUN
eurjchem-1564	21	36	tissues	tissue	NOUN
eurjchem-1564	21	37	,	,	PUNCT
eurjchem-1564	21	38	however	however	ADV
eurjchem-1564	21	39	,	,	PUNCT
eurjchem-1564	21	40	many	many	ADJ
eurjchem-1564	21	41	tumors	tumor	NOUN
eurjchem-1564	21	42	have	have	AUX
eurjchem-1564	21	43	induced	induce	VERB
eurjchem-1564	21	44	a	a	DET
eurjchem-1564	21	45	resistance	resistance	NOUN
eurjchem-1564	21	46	to	to	ADP
eurjchem-1564	21	47	this	this	DET
eurjchem-1564	21	48	platinum	platinum	NOUN
eurjchem-1564	21	49	complex	complex	NOUN
eurjchem-1564	21	50	[	[	X
eurjchem-1564	21	51	3	3	NUM
eurjchem-1564	21	52	]	]	PUNCT
eurjchem-1564	21	53	.	.	PUNCT
eurjchem-1564	22	1	to	to	PART
eurjchem-1564	22	2	solve	solve	VERB
eurjchem-1564	22	3	this	this	DET
eurjchem-1564	22	4	problem	problem	NOUN
eurjchem-1564	22	5	though	though	ADV
eurjchem-1564	22	6	,	,	PUNCT
eurjchem-1564	22	7	modified	modified	ADJ
eurjchem-1564	22	8	versions	version	NOUN
eurjchem-1564	22	9	of	of	ADP
eurjchem-1564	22	10	cis‐platin	cis‐platin	NUM
eurjchem-1564	22	11	leading	lead	VERB
eurjchem-1564	22	12	to	to	ADP
eurjchem-1564	22	13	second	second	ADJ
eurjchem-1564	22	14	and	and	CCONJ
eurjchem-1564	22	15	third	third	ADJ
eurjchem-1564	22	16	generation	generation	NOUN
eurjchem-1564	22	17	platinum‐	platinum‐	NOUN
eurjchem-1564	22	18	based	base	VERB
eurjchem-1564	22	19	drugs	drug	NOUN
eurjchem-1564	22	20	have	have	AUX
eurjchem-1564	22	21	been	be	AUX
eurjchem-1564	22	22	synthesized	synthesize	VERB
eurjchem-1564	22	23	over	over	ADP
eurjchem-1564	22	24	the	the	DET
eurjchem-1564	22	25	past	past	ADJ
eurjchem-1564	22	26	30	30	NUM
eurjchem-1564	22	27	years	year	NOUN
eurjchem-1564	22	28	,	,	PUNCT
eurjchem-1564	22	29	and	and	CCONJ
eurjchem-1564	22	30	have	have	AUX
eurjchem-1564	22	31	got	get	VERB
eurjchem-1564	22	32	less	less	ADV
eurjchem-1564	22	33	toxic	toxic	ADJ
eurjchem-1564	22	34	effect	effect	NOUN
eurjchem-1564	22	35	to	to	ADP
eurjchem-1564	22	36	their	their	PRON
eurjchem-1564	22	37	host	host	NOUN
eurjchem-1564	22	38	tissue	tissue	NOUN
eurjchem-1564	23	1	[	[	X
eurjchem-1564	23	2	4	4	NUM
eurjchem-1564	23	3	]	]	PUNCT
eurjchem-1564	23	4	.	.	PUNCT
eurjchem-1564	24	1	in	in	ADP
eurjchem-1564	24	2	recent	recent	ADJ
eurjchem-1564	24	3	years	year	NOUN
eurjchem-1564	24	4	a	a	DET
eurjchem-1564	24	5	great	great	ADJ
eurjchem-1564	24	6	deal	deal	NOUN
eurjchem-1564	24	7	of	of	ADP
eurjchem-1564	24	8	effort	effort	NOUN
eurjchem-1564	24	9	has	have	AUX
eurjchem-1564	24	10	been	be	AUX
eurjchem-1564	24	11	devoted	devote	VERB
eurjchem-1564	24	12	for	for	ADP
eurjchem-1564	24	13	developing	develop	VERB
eurjchem-1564	24	14	transition	transition	NOUN
eurjchem-1564	24	15	metal	metal	NOUN
eurjchem-1564	24	16	as	as	ADP
eurjchem-1564	24	17	antitumor	antitumor	PROPN
eurjchem-1564	24	18	agents	agent	NOUN
eurjchem-1564	24	19	which	which	PRON
eurjchem-1564	24	20	have	have	VERB
eurjchem-1564	24	21	better	well	ADJ
eurjchem-1564	24	22	therapeutic	therapeutic	ADJ
eurjchem-1564	24	23	properties	property	NOUN
eurjchem-1564	24	24	than	than	ADP
eurjchem-1564	24	25	prototype	prototype	NOUN
eurjchem-1564	24	26	drug	drug	NOUN
eurjchem-1564	24	27	cis‐platin	cis‐platin	PROPN
eurjchem-1564	25	1	[	[	X
eurjchem-1564	25	2	4,5	4,5	NUM
eurjchem-1564	25	3	]	]	PUNCT
eurjchem-1564	25	4	.	.	PUNCT
eurjchem-1564	26	1	although	although	SCONJ
eurjchem-1564	26	2	the	the	DET
eurjchem-1564	26	3	bulk	bulk	NOUN
eurjchem-1564	26	4	of	of	ADP
eurjchem-1564	26	5	the	the	DET
eurjchem-1564	26	6	work	work	NOUN
eurjchem-1564	26	7	to	to	ADP
eurjchem-1564	26	8	date	date	NOUN
eurjchem-1564	26	9	has	have	AUX
eurjchem-1564	26	10	involved	involve	VERB
eurjchem-1564	26	11	investigations	investigation	NOUN
eurjchem-1564	26	12	of	of	ADP
eurjchem-1564	26	13	platinum(ii	platinum(ii	NOUN
eurjchem-1564	26	14	)	)	PUNCT
eurjchem-1564	26	15	complexes	complex	NOUN
eurjchem-1564	26	16	as	as	ADP
eurjchem-1564	26	17	potential	potential	ADJ
eurjchem-1564	26	18	anti‐	anti‐	PROPN
eurjchem-1564	26	19	tumor	tumor	NOUN
eurjchem-1564	26	20	agents	agent	NOUN
eurjchem-1564	26	21	[	[	X
eurjchem-1564	26	22	6‐8	6‐8	NOUN
eurjchem-1564	26	23	]	]	PUNCT
eurjchem-1564	26	24	,	,	PUNCT
eurjchem-1564	26	25	the	the	DET
eurjchem-1564	26	26	significant	significant	ADJ
eurjchem-1564	26	27	similarity	similarity	NOUN
eurjchem-1564	26	28	between	between	ADP
eurjchem-1564	26	29	the	the	DET
eurjchem-1564	26	30	coor‐	coor‐	NOUN
eurjchem-1564	26	31	dination	dination	NOUN
eurjchem-1564	26	32	chemistry	chemistry	NOUN
eurjchem-1564	26	33	of	of	ADP
eurjchem-1564	26	34	compounds	compound	NOUN
eurjchem-1564	26	35	has	have	AUX
eurjchem-1564	26	36	also	also	ADV
eurjchem-1564	26	37	advocated	advocate	VERB
eurjchem-1564	26	38	studies	study	NOUN
eurjchem-1564	26	39	of	of	ADP
eurjchem-1564	26	40	palladium(ii	palladium(ii	NOUN
eurjchem-1564	26	41	)	)	PUNCT
eurjchem-1564	26	42	complexes	complex	NOUN
eurjchem-1564	26	43	as	as	ADP
eurjchem-1564	26	44	anticancer	anticancer	NOUN
eurjchem-1564	26	45	drugs	drug	NOUN
eurjchem-1564	26	46	.	.	PUNCT
eurjchem-1564	27	1	a	a	DET
eurjchem-1564	27	2	key	key	ADJ
eurjchem-1564	27	3	factor	factor	NOUN
eurjchem-1564	27	4	that	that	PRON
eurjchem-1564	27	5	might	might	AUX
eurjchem-1564	27	6	explain	explain	VERB
eurjchem-1564	27	7	why	why	SCONJ
eurjchem-1564	27	8	platinum	platinum	NOUN
eurjchem-1564	27	9	is	be	AUX
eurjchem-1564	27	10	most	most	ADV
eurjchem-1564	27	11	useful	useful	ADJ
eurjchem-1564	27	12	comes	come	VERB
eurjchem-1564	27	13	from	from	ADP
eurjchem-1564	27	14	the	the	DET
eurjchem-1564	27	15	ligand‐exchange	ligand‐exchange	NOUN
eurjchem-1564	27	16	kinetics	kinetic	NOUN
eurjchem-1564	27	17	.	.	PUNCT
eurjchem-1564	28	1	the	the	DET
eurjchem-1564	28	2	hydrolysis	hydrolysis	NOUN
eurjchem-1564	28	3	in	in	ADP
eurjchem-1564	28	4	palladium	palladium	NOUN
eurjchem-1564	28	5	complexes	complex	NOUN
eurjchem-1564	28	6	is	be	AUX
eurjchem-1564	28	7	significantly	significantly	ADV
eurjchem-1564	28	8	rapid	rapid	ADJ
eurjchem-1564	28	9	;	;	PUNCT
eurjchem-1564	28	10	about	about	ADV
eurjchem-1564	28	11	105	105	NUM
eurjchem-1564	28	12	times	time	NOUN
eurjchem-1564	28	13	faster	fast	ADJ
eurjchem-1564	28	14	than	than	ADP
eurjchem-1564	28	15	their	their	PRON
eurjchem-1564	28	16	corresponding	correspond	VERB
eurjchem-1564	28	17	platinum	platinum	NOUN
eurjchem-1564	28	18	analogues	analogue	NOUN
eurjchem-1564	28	19	.	.	PUNCT
eurjchem-1564	29	1	the	the	DET
eurjchem-1564	29	2	lability	lability	NOUN
eurjchem-1564	29	3	of	of	ADP
eurjchem-1564	29	4	palladium	palladium	NOUN
eurjchem-1564	29	5	complexes	complex	NOUN
eurjchem-1564	29	6	for	for	ADP
eurjchem-1564	29	7	readily	readily	ADV
eurjchem-1564	29	8	dissociating	dissociate	VERB
eurjchem-1564	29	9	in	in	ADP
eurjchem-1564	29	10	solution	solution	NOUN
eurjchem-1564	29	11	lead	lead	VERB
eurjchem-1564	29	12	to	to	ADP
eurjchem-1564	29	13	every	every	DET
eurjchem-1564	29	14	reactive	reactive	ADJ
eurjchem-1564	29	15	species	specie	NOUN
eurjchem-1564	29	16	enabling	enable	VERB
eurjchem-1564	29	17	to	to	PART
eurjchem-1564	29	18	reach	reach	VERB
eurjchem-1564	29	19	their	their	PRON
eurjchem-1564	29	20	pharmacolo‐	pharmacolo‐	ADJ
eurjchem-1564	29	21	gical	gical	ADJ
eurjchem-1564	29	22	targets	target	NOUN
eurjchem-1564	29	23	[	[	X
eurjchem-1564	29	24	9	9	NUM
eurjchem-1564	29	25	]	]	PUNCT
eurjchem-1564	29	26	.	.	PUNCT
eurjchem-1564	30	1	one	one	NUM
eurjchem-1564	30	2	of	of	ADP
eurjchem-1564	30	3	the	the	DET
eurjchem-1564	30	4	main	main	ADJ
eurjchem-1564	30	5	challenges	challenge	NOUN
eurjchem-1564	30	6	in	in	ADP
eurjchem-1564	30	7	the	the	DET
eurjchem-1564	30	8	rational	rational	ADJ
eurjchem-1564	30	9	design	design	NOUN
eurjchem-1564	30	10	of	of	ADP
eurjchem-1564	30	11	metal‐	metal‐	NOUN
eurjchem-1564	30	12	containing	contain	VERB
eurjchem-1564	30	13	chemotherapy	chemotherapy	NOUN
eurjchem-1564	30	14	agents	agent	NOUN
eurjchem-1564	30	15	is	be	AUX
eurjchem-1564	30	16	to	to	PART
eurjchem-1564	30	17	enhance	enhance	VERB
eurjchem-1564	30	18	their	their	PRON
eurjchem-1564	30	19	cytostatic	cytostatic	ADJ
eurjchem-1564	30	20	activity	activity	NOUN
eurjchem-1564	30	21	while	while	SCONJ
eurjchem-1564	30	22	simultaneously	simultaneously	ADV
eurjchem-1564	30	23	reducing	reduce	VERB
eurjchem-1564	30	24	toxicity	toxicity	NOUN
eurjchem-1564	30	25	[	[	X
eurjchem-1564	30	26	10,11	10,11	NOUN
eurjchem-1564	30	27	]	]	X
eurjchem-1564	30	28	.	.	PUNCT
eurjchem-1564	31	1	for	for	ADP
eurjchem-1564	31	2	the	the	DET
eurjchem-1564	31	3	most	most	ADJ
eurjchem-1564	31	4	part	part	NOUN
eurjchem-1564	31	5	,	,	PUNCT
eurjchem-1564	31	6	palladium	palladium	NOUN
eurjchem-1564	31	7	complexes	complex	NOUN
eurjchem-1564	31	8	have	have	AUX
eurjchem-1564	31	9	shown	show	VERB
eurjchem-1564	31	10	little	little	ADJ
eurjchem-1564	31	11	or	or	CCONJ
eurjchem-1564	31	12	no	no	PRON
eurjchem-1564	31	13	anti‐	anti‐	PRON
eurjchem-1564	31	14	tumor	tumor	NOUN
eurjchem-1564	31	15	activity	activity	NOUN
eurjchem-1564	31	16	.	.	PUNCT
eurjchem-1564	32	1	this	this	PRON
eurjchem-1564	32	2	has	have	AUX
eurjchem-1564	32	3	been	be	AUX
eurjchem-1564	32	4	attributed	attribute	VERB
eurjchem-1564	32	5	to	to	ADP
eurjchem-1564	32	6	the	the	DET
eurjchem-1564	32	7	higher	high	ADJ
eurjchem-1564	32	8	lability	lability	NOUN
eurjchem-1564	32	9	and	and	CCONJ
eurjchem-1564	32	10	lack	lack	NOUN
eurjchem-1564	32	11	of	of	ADP
eurjchem-1564	32	12	stability	stability	NOUN
eurjchem-1564	32	13	comparatively	comparatively	ADV
eurjchem-1564	32	14	to	to	PART
eurjchem-1564	32	15	platinum(ii	platinum(ii	VERB
eurjchem-1564	32	16	)	)	PUNCT
eurjchem-1564	32	17	metal	metal	NOUN
eurjchem-1564	32	18	.	.	PUNCT
eurjchem-1564	33	1	unfortunately	unfortunately	ADV
eurjchem-1564	33	2	,	,	PUNCT
eurjchem-1564	33	3	there	there	PRON
eurjchem-1564	33	4	are	be	VERB
eurjchem-1564	33	5	no	no	DET
eurjchem-1564	33	6	antitumor	antitumor	NOUN
eurjchem-1564	33	7	activity	activity	NOUN
eurjchem-1564	33	8	for	for	ADP
eurjchem-1564	33	9	cis‐palla‐	cis‐palla‐	PROPN
eurjchem-1564	33	10	dium	dium	PROPN
eurjchem-1564	33	11	,	,	PUNCT
eurjchem-1564	33	12	cis‐[pdcl2(nh3)2	cis‐[pdcl2(nh3)2	PROPN
eurjchem-1564	33	13	]	]	PUNCT
eurjchem-1564	33	14	.	.	PUNCT
eurjchem-1564	34	1	it	it	PRON
eurjchem-1564	34	2	is	be	AUX
eurjchem-1564	34	3	well	well	ADV
eurjchem-1564	34	4	known	know	VERB
eurjchem-1564	34	5	that	that	SCONJ
eurjchem-1564	34	6	it	it	PRON
eurjchem-1564	34	7	undergoes	undergo	VERB
eurjchem-1564	34	8	into	into	ADP
eurjchem-1564	34	9	active	active	ADJ
eurjchem-1564	34	10	trans‐conformation	trans‐conformation	NOUN
eurjchem-1564	34	11	and	and	CCONJ
eurjchem-1564	34	12	fast	fast	ADJ
eurjchem-1564	34	13	hydrolyze	hydrolyze	NOUN
eurjchem-1564	34	14	as	as	ADP
eurjchem-1564	34	15	consequently	consequently	ADV
eurjchem-1564	34	16	,	,	PUNCT
eurjchem-1564	34	17	they	they	PRON
eurjchem-1564	34	18	interact	interact	VERB
eurjchem-1564	34	19	,	,	PUNCT
eurjchem-1564	34	20	in	in	ADP
eurjchem-1564	34	21	vivo	vivo	NOUN
eurjchem-1564	34	22	,	,	PUNCT
eurjchem-1564	34	23	with	with	ADP
eurjchem-1564	34	24	a	a	DET
eurjchem-1564	34	25	lot	lot	NOUN
eurjchem-1564	34	26	of	of	ADP
eurjchem-1564	34	27	molecules	molecule	NOUN
eurjchem-1564	34	28	particularly	particularly	ADV
eurjchem-1564	34	29	proteins	protein	NOUN
eurjchem-1564	34	30	preventing	prevent	VERB
eurjchem-1564	34	31	them	they	PRON
eurjchem-1564	34	32	to	to	PART
eurjchem-1564	34	33	reach	reach	VERB
eurjchem-1564	34	34	the	the	DET
eurjchem-1564	34	35	dna	dna	NOUN
eurjchem-1564	34	36	as	as	ADP
eurjchem-1564	34	37	their	their	PRON
eurjchem-1564	34	38	pharmaco‐	pharmaco‐	CCONJ
eurjchem-1564	34	39	logical	logical	ADJ
eurjchem-1564	34	40	target	target	NOUN
eurjchem-1564	34	41	[	[	X
eurjchem-1564	34	42	12	12	NUM
eurjchem-1564	34	43	]	]	PUNCT
eurjchem-1564	34	44	.	.	PUNCT
eurjchem-1564	35	1	thus	thus	ADV
eurjchem-1564	35	2	,	,	PUNCT
eurjchem-1564	35	3	whereas	whereas	SCONJ
eurjchem-1564	35	4	platinum	platinum	NOUN
eurjchem-1564	35	5	compounds	compound	NOUN
eurjchem-1564	35	6	such	such	ADJ
eurjchem-1564	35	7	as	as	ADP
eurjchem-1564	35	8	cis‐platin	cis‐platin	PROPN
eurjchem-1564	35	9	maintain	maintain	VERB
eurjchem-1564	35	10	their	their	PRON
eurjchem-1564	35	11	structural	structural	ADJ
eurjchem-1564	35	12	integrity	integrity	NOUN
eurjchem-1564	35	13	in	in	ADP
eurjchem-1564	35	14	vivo	vivo	NOUN
eurjchem-1564	35	15	long	long	ADV
eurjchem-1564	35	16	enough	enough	ADV
eurjchem-1564	35	17	to	to	PART
eurjchem-1564	35	18	reach	reach	VERB
eurjchem-1564	35	19	their	their	PRON
eurjchem-1564	35	20	cellular	cellular	ADJ
eurjchem-1564	35	21	targets	target	NOUN
eurjchem-1564	35	22	,	,	PUNCT
eurjchem-1564	35	23	analogous	analogous	ADJ
eurjchem-1564	35	24	palladium	palladium	NOUN
eurjchem-1564	35	25	compounds	compound	NOUN
eurjchem-1564	35	26	undergo	undergo	VERB
eurjchem-1564	35	27	hydrolysis	hydrolysis	NOUN
eurjchem-1564	35	28	and/or	and/or	CCONJ
eurjchem-1564	35	29	various	various	ADJ
eurjchem-1564	35	30	substitution	substitution	NOUN
eurjchem-1564	35	31	156	156	NUM
eurjchem-1564	35	32	al‐fregi	al‐fregi	PROPN
eurjchem-1564	35	33	et	et	PROPN
eurjchem-1564	35	34	al	al	PROPN
eurjchem-1564	35	35	.	.	PUNCT
eurjchem-1564	35	36	/	/	SYM
eurjchem-1564	35	37	european	european	PROPN
eurjchem-1564	35	38	journal	journal	PROPN
eurjchem-1564	35	39	of	of	ADP
eurjchem-1564	35	40	chemistry	chemistry	NOUN
eurjchem-1564	35	41	8	8	NUM
eurjchem-1564	35	42	(	(	PUNCT
eurjchem-1564	35	43	2	2	NUM
eurjchem-1564	35	44	)	)	PUNCT
eurjchem-1564	35	45	(	(	PUNCT
eurjchem-1564	35	46	2017	2017	NUM
eurjchem-1564	35	47	)	)	PUNCT
eurjchem-1564	35	48	155‐161	155‐161	NUM
eurjchem-1564	35	49	scheme	scheme	NOUN
eurjchem-1564	35	50	1	1	NUM
eurjchem-1564	35	51	reactions	reaction	NOUN
eurjchem-1564	35	52	more	more	ADV
eurjchem-1564	35	53	quickly	quickly	ADV
eurjchem-1564	35	54	to	to	PART
eurjchem-1564	35	55	be	be	AUX
eurjchem-1564	35	56	effective	effective	ADJ
eurjchem-1564	35	57	as	as	ADP
eurjchem-1564	35	58	antitumor	antitumor	PROPN
eurjchem-1564	35	59	agents	agent	NOUN
eurjchem-1564	35	60	.	.	PUNCT
eurjchem-1564	36	1	higher	high	ADJ
eurjchem-1564	36	2	activity	activity	NOUN
eurjchem-1564	36	3	of	of	ADP
eurjchem-1564	36	4	palladium	palladium	NOUN
eurjchem-1564	36	5	complexes	complex	NOUN
eurjchem-1564	36	6	implies	imply	VERB
eurjchem-1564	36	7	that	that	SCONJ
eurjchem-1564	36	8	if	if	SCONJ
eurjchem-1564	36	9	an	an	DET
eurjchem-1564	36	10	antitumor	antitumor	PROPN
eurjchem-1564	36	11	palladium	palladium	NOUN
eurjchem-1564	36	12	drug	drug	NOUN
eurjchem-1564	36	13	is	be	AUX
eurjchem-1564	36	14	to	to	PART
eurjchem-1564	36	15	be	be	AUX
eurjchem-1564	36	16	developed	develop	VERB
eurjchem-1564	36	17	,	,	PUNCT
eurjchem-1564	36	18	it	it	PRON
eurjchem-1564	36	19	must	must	AUX
eurjchem-1564	36	20	ideally	ideally	ADV
eurjchem-1564	36	21	be	be	AUX
eurjchem-1564	36	22	stabilized	stabilize	VERB
eurjchem-1564	36	23	by	by	ADP
eurjchem-1564	36	24	a	a	DET
eurjchem-1564	36	25	chelate	chelate	NOUN
eurjchem-1564	36	26	or	or	CCONJ
eurjchem-1564	36	27	strongly	strongly	ADV
eurjchem-1564	36	28	coordinated	coordinate	VERB
eurjchem-1564	36	29	with	with	ADP
eurjchem-1564	36	30	bulky	bulky	ADJ
eurjchem-1564	36	31	monodentate	monodentate	NOUN
eurjchem-1564	36	32	nitrogen	nitrogen	NOUN
eurjchem-1564	36	33	ligand	ligand	NOUN
eurjchem-1564	36	34	and	and	CCONJ
eurjchem-1564	36	35	suitable	suitable	ADJ
eurjchem-1564	36	36	leaving	leave	VERB
eurjchem-1564	36	37	groups	group	NOUN
eurjchem-1564	36	38	[	[	X
eurjchem-1564	36	39	8,13	8,13	NUM
eurjchem-1564	36	40	]	]	PUNCT
eurjchem-1564	36	41	.	.	PUNCT
eurjchem-1564	37	1	due	due	ADP
eurjchem-1564	37	2	to	to	ADP
eurjchem-1564	37	3	the	the	DET
eurjchem-1564	37	4	steric	steric	ADJ
eurjchem-1564	37	5	effect	effect	NOUN
eurjchem-1564	37	6	resulted	result	VERB
eurjchem-1564	37	7	from	from	ADP
eurjchem-1564	37	8	the	the	DET
eurjchem-1564	37	9	bulk	bulk	NOUN
eurjchem-1564	37	10	of	of	ADP
eurjchem-1564	37	11	donor	donor	NOUN
eurjchem-1564	37	12	atoms	atom	NOUN
eurjchem-1564	37	13	;	;	PUNCT
eurjchem-1564	37	14	these	these	DET
eurjchem-1564	37	15	ligands	ligand	NOUN
eurjchem-1564	37	16	could	could	AUX
eurjchem-1564	37	17	minimize	minimize	VERB
eurjchem-1564	37	18	any	any	DET
eurjchem-1564	37	19	possible	possible	ADJ
eurjchem-1564	37	20	cis‐trans	cis‐tran	NOUN
eurjchem-1564	37	21	isomerism	isomerism	NOUN
eurjchem-1564	37	22	[	[	X
eurjchem-1564	37	23	14	14	NUM
eurjchem-1564	37	24	]	]	PUNCT
eurjchem-1564	37	25	.	.	PUNCT
eurjchem-1564	38	1	in	in	ADP
eurjchem-1564	38	2	fact	fact	NOUN
eurjchem-1564	38	3	,	,	PUNCT
eurjchem-1564	38	4	carefully	carefully	ADV
eurjchem-1564	38	5	designed	design	VERB
eurjchem-1564	38	6	platinum	platinum	NOUN
eurjchem-1564	38	7	and	and	CCONJ
eurjchem-1564	38	8	palladium	palladium	NOUN
eurjchem-1564	38	9	complexes	complex	NOUN
eurjchem-1564	38	10	structurally	structurally	ADV
eurjchem-1564	38	11	different	different	ADJ
eurjchem-1564	38	12	from	from	ADP
eurjchem-1564	38	13	cis‐platin	cis‐platin	PROPN
eurjchem-1564	38	14	and	and	CCONJ
eurjchem-1564	38	15	its	its	PRON
eurjchem-1564	38	16	second‐generation	second‐generation	NOUN
eurjchem-1564	38	17	analogues	analogue	NOUN
eurjchem-1564	38	18	are	be	AUX
eurjchem-1564	38	19	prone	prone	ADJ
eurjchem-1564	38	20	to	to	PART
eurjchem-1564	38	21	display	display	VERB
eurjchem-1564	38	22	an	an	DET
eurjchem-1564	38	23	altered	altered	ADJ
eurjchem-1564	38	24	spectrum	spectrum	NOUN
eurjchem-1564	38	25	of	of	ADP
eurjchem-1564	38	26	clinical	clinical	ADJ
eurjchem-1564	38	27	activity	activity	NOUN
eurjchem-1564	38	28	and	and	CCONJ
eurjchem-1564	38	29	toxicity	toxicity	NOUN
eurjchem-1564	38	30	,	,	PUNCT
eurjchem-1564	38	31	due	due	ADP
eurjchem-1564	38	32	to	to	ADP
eurjchem-1564	38	33	differences	difference	NOUN
eurjchem-1564	38	34	in	in	ADP
eurjchem-1564	38	35	cellular	cellular	ADJ
eurjchem-1564	38	36	biochemical	biochemical	ADJ
eurjchem-1564	38	37	pharmacology	pharmacology	NOUN
eurjchem-1564	38	38	[	[	X
eurjchem-1564	38	39	15	15	NUM
eurjchem-1564	38	40	]	]	PUNCT
eurjchem-1564	38	41	.	.	PUNCT
eurjchem-1564	39	1	there‐	there‐	NOUN
eurjchem-1564	39	2	fore	fore	NOUN
eurjchem-1564	39	3	,	,	PUNCT
eurjchem-1564	39	4	parameters	parameter	NOUN
eurjchem-1564	39	5	ruling	rule	VERB
eurjchem-1564	39	6	their	their	PRON
eurjchem-1564	39	7	cytotoxicity	cytotoxicity	NOUN
eurjchem-1564	39	8	may	may	AUX
eurjchem-1564	39	9	not	not	PART
eurjchem-1564	39	10	follow	follow	VERB
eurjchem-1564	39	11	the	the	DET
eurjchem-1564	39	12	patterns	pattern	NOUN
eurjchem-1564	39	13	applied	apply	VERB
eurjchem-1564	39	14	to	to	ADP
eurjchem-1564	39	15	cisplatin‐like	cisplatin‐like	ADJ
eurjchem-1564	39	16	agents	agent	NOUN
eurjchem-1564	39	17	.	.	PUNCT
eurjchem-1564	40	1	in	in	ADP
eurjchem-1564	40	2	fact	fact	NOUN
eurjchem-1564	40	3	to	to	PART
eurjchem-1564	40	4	solve	solve	VERB
eurjchem-1564	40	5	this	this	DET
eurjchem-1564	40	6	problem	problem	NOUN
eurjchem-1564	40	7	,	,	PUNCT
eurjchem-1564	40	8	the	the	DET
eurjchem-1564	40	9	gill	gill	NOUN
eurjchem-1564	40	10	’s	’s	PART
eurjchem-1564	40	11	approach	approach	NOUN
eurjchem-1564	40	12	was	be	AUX
eurjchem-1564	40	13	adopted	adopt	VERB
eurjchem-1564	40	14	by	by	ADP
eurjchem-1564	40	15	using	use	VERB
eurjchem-1564	40	16	the	the	DET
eurjchem-1564	40	17	chelating	chelating	NOUN
eurjchem-1564	40	18	ligands	ligand	NOUN
eurjchem-1564	40	19	in	in	ADP
eurjchem-1564	40	20	order	order	NOUN
eurjchem-1564	40	21	to	to	PART
eurjchem-1564	40	22	stabilize	stabilize	VERB
eurjchem-1564	40	23	the	the	DET
eurjchem-1564	40	24	palladium	palladium	NOUN
eurjchem-1564	40	25	complex	complex	NOUN
eurjchem-1564	41	1	[	[	X
eurjchem-1564	41	2	16	16	NUM
eurjchem-1564	41	3	]	]	PUNCT
eurjchem-1564	41	4	.	.	PUNCT
eurjchem-1564	42	1	on	on	ADP
eurjchem-1564	42	2	the	the	DET
eurjchem-1564	42	3	other	other	ADJ
eurjchem-1564	42	4	hand	hand	NOUN
eurjchem-1564	42	5	,	,	PUNCT
eurjchem-1564	42	6	amines	amine	NOUN
eurjchem-1564	42	7	are	be	AUX
eurjchem-1564	42	8	suitable	suitable	ADJ
eurjchem-1564	42	9	chelating	chelating	NOUN
eurjchem-1564	42	10	ligands	ligand	NOUN
eurjchem-1564	42	11	for	for	ADP
eurjchem-1564	42	12	transition	transition	NOUN
eurjchem-1564	42	13	metal	metal	NOUN
eurjchem-1564	42	14	ions	ion	NOUN
eurjchem-1564	42	15	such	such	ADJ
eurjchem-1564	42	16	as	as	ADP
eurjchem-1564	42	17	palladium	palladium	NOUN
eurjchem-1564	42	18	,	,	PUNCT
eurjchem-1564	42	19	yielding	yield	VERB
eurjchem-1564	42	20	stability	stability	NOUN
eurjchem-1564	42	21	and	and	CCONJ
eurjchem-1564	42	22	solubility	solubility	NOUN
eurjchem-1564	42	23	of	of	ADP
eurjchem-1564	42	24	coordinated	coordinate	VERB
eurjchem-1564	42	25	compounds	compound	NOUN
eurjchem-1564	42	26	.	.	PUNCT
eurjchem-1564	43	1	the	the	DET
eurjchem-1564	43	2	linear	linear	ADJ
eurjchem-1564	43	3	aliphatic	aliphatic	ADJ
eurjchem-1564	43	4	amines	amine	NOUN
eurjchem-1564	43	5	,	,	PUNCT
eurjchem-1564	43	6	in	in	ADP
eurjchem-1564	43	7	particular	particular	ADJ
eurjchem-1564	43	8	,	,	PUNCT
eurjchem-1564	43	9	are	be	AUX
eurjchem-1564	43	10	recognized	recognize	VERB
eurjchem-1564	43	11	to	to	PART
eurjchem-1564	43	12	highly	highly	ADV
eurjchem-1564	43	13	have	have	VERB
eurjchem-1564	43	14	a	a	DET
eurjchem-1564	43	15	confor‐	confor‐	NOUN
eurjchem-1564	43	16	mational	mational	ADJ
eurjchem-1564	43	17	freedom	freedom	NOUN
eurjchem-1564	43	18	,	,	PUNCT
eurjchem-1564	43	19	and	and	CCONJ
eurjchem-1564	43	20	conveniently	conveniently	ADV
eurjchem-1564	43	21	,	,	PUNCT
eurjchem-1564	43	22	they	they	PRON
eurjchem-1564	43	23	could	could	AUX
eurjchem-1564	43	24	be	be	AUX
eurjchem-1564	43	25	designed	design	VERB
eurjchem-1564	43	26	for	for	ADP
eurjchem-1564	43	27	displaying	display	VERB
eurjchem-1564	43	28	suitable	suitable	ADJ
eurjchem-1564	43	29	flexibility	flexibility	NOUN
eurjchem-1564	43	30	and	and	CCONJ
eurjchem-1564	43	31	polydenticity	polydenticity	NOUN
eurjchem-1564	43	32	features	feature	NOUN
eurjchem-1564	43	33	,	,	PUNCT
eurjchem-1564	43	34	which	which	PRON
eurjchem-1564	43	35	constitute	constitute	VERB
eurjchem-1564	43	36	an	an	DET
eurjchem-1564	43	37	advantage	advantage	NOUN
eurjchem-1564	43	38	for	for	ADP
eurjchem-1564	43	39	an	an	DET
eurjchem-1564	43	40	efficient	efficient	ADJ
eurjchem-1564	43	41	interaction	interaction	NOUN
eurjchem-1564	43	42	with	with	ADP
eurjchem-1564	43	43	metal	metal	NOUN
eurjchem-1564	43	44	ions	ion	NOUN
eurjchem-1564	43	45	and	and	CCONJ
eurjchem-1564	43	46	biological	biological	ADJ
eurjchem-1564	43	47	receptors	receptor	NOUN
eurjchem-1564	43	48	[	[	X
eurjchem-1564	43	49	17	17	NUM
eurjchem-1564	43	50	]	]	PUNCT
eurjchem-1564	43	51	.	.	PUNCT
eurjchem-1564	44	1	in	in	ADP
eurjchem-1564	44	2	fact	fact	NOUN
eurjchem-1564	44	3	,	,	PUNCT
eurjchem-1564	44	4	the	the	DET
eurjchem-1564	44	5	high	high	ADJ
eurjchem-1564	44	6	conformational	conformational	ADJ
eurjchem-1564	44	7	freedom	freedom	NOUN
eurjchem-1564	44	8	and	and	CCONJ
eurjchem-1564	44	9	the	the	DET
eurjchem-1564	44	10	dual	dual	ADJ
eurjchem-1564	44	11	hydrophilic‐lipophilic	hydrophilic‐lipophilic	ADJ
eurjchem-1564	44	12	character	character	NOUN
eurjchem-1564	44	13	of	of	ADP
eurjchem-1564	44	14	the	the	DET
eurjchem-1564	44	15	amine	amine	ADJ
eurjchem-1564	44	16	or	or	CCONJ
eurjchem-1564	44	17	schiff	schiff	NOUN
eurjchem-1564	44	18	bases	basis	NOUN
eurjchem-1564	44	19	ligands	ligand	NOUN
eurjchem-1564	44	20	,	,	PUNCT
eurjchem-1564	44	21	comprising	comprise	VERB
eurjchem-1564	44	22	both	both	CCONJ
eurjchem-1564	44	23	cationic	cationic	ADJ
eurjchem-1564	44	24	amine	amine	ADJ
eurjchem-1564	44	25	and	and	CCONJ
eurjchem-1564	44	26	imine	imine	ADJ
eurjchem-1564	44	27	groups	group	NOUN
eurjchem-1564	44	28	and	and	CCONJ
eurjchem-1564	44	29	variable	variable	ADJ
eurjchem-1564	44	30	length	length	NOUN
eurjchem-1564	44	31	hydrophobic	hydrophobic	NOUN
eurjchem-1564	44	32	alkyl	alkyl	NOUN
eurjchem-1564	44	33	linkers	linker	NOUN
eurjchem-1564	44	34	allow	allow	VERB
eurjchem-1564	44	35	these	these	DET
eurjchem-1564	44	36	metal	metal	NOUN
eurjchem-1564	44	37	complexes	complex	NOUN
eurjchem-1564	44	38	to	to	PART
eurjchem-1564	44	39	interact	interact	VERB
eurjchem-1564	44	40	with	with	ADP
eurjchem-1564	44	41	dna	dna	PROPN
eurjchem-1564	44	42	through	through	ADP
eurjchem-1564	44	43	a	a	DET
eurjchem-1564	44	44	nonconventional	nonconventional	ADJ
eurjchem-1564	44	45	way	way	NOUN
eurjchem-1564	44	46	both	both	CCONJ
eurjchem-1564	44	47	covalently	covalently	ADV
eurjchem-1564	44	48	(	(	PUNCT
eurjchem-1564	44	49	through	through	ADP
eurjchem-1564	44	50	direct	direct	ADJ
eurjchem-1564	44	51	binding	binding	NOUN
eurjchem-1564	44	52	of	of	ADP
eurjchem-1564	44	53	the	the	DET
eurjchem-1564	44	54	metal	metal	NOUN
eurjchem-1564	44	55	center	center	NOUN
eurjchem-1564	44	56	to	to	ADP
eurjchem-1564	44	57	the	the	DET
eurjchem-1564	44	58	purine	purine	NOUN
eurjchem-1564	44	59	bases	basis	NOUN
eurjchem-1564	44	60	)	)	PUNCT
eurjchem-1564	44	61	and	and	CCONJ
eurjchem-1564	44	62	non‐covalently	non‐covalently	ADV
eurjchem-1564	44	63	(	(	PUNCT
eurjchem-1564	44	64	via	via	ADP
eurjchem-1564	44	65	hydrophobic	hydrophobic	NOUN
eurjchem-1564	44	66	and	and	CCONJ
eurjchem-1564	44	67	hydrogen‐bonding	hydrogen‐bonding	NOUN
eurjchem-1564	44	68	close	close	ADJ
eurjchem-1564	44	69	contacts	contact	NOUN
eurjchem-1564	44	70	)	)	PUNCT
eurjchem-1564	44	71	.	.	PUNCT
eurjchem-1564	45	1	studies	study	NOUN
eurjchem-1564	45	2	of	of	ADP
eurjchem-1564	45	3	palladium	palladium	NOUN
eurjchem-1564	45	4	complexes	complex	NOUN
eurjchem-1564	45	5	with	with	ADP
eurjchem-1564	45	6	biologically	biologically	ADV
eurjchem-1564	45	7	active	active	ADJ
eurjchem-1564	45	8	carriers	carrier	NOUN
eurjchem-1564	45	9	are	be	AUX
eurjchem-1564	45	10	yielding	yield	VERB
eurjchem-1564	45	11	promising	promising	ADJ
eurjchem-1564	45	12	results	result	NOUN
eurjchem-1564	45	13	in	in	ADP
eurjchem-1564	45	14	the	the	DET
eurjchem-1564	45	15	field	field	NOUN
eurjchem-1564	45	16	of	of	ADP
eurjchem-1564	45	17	anticancer	anticancer	NOUN
eurjchem-1564	45	18	chemistry	chemistry	NOUN
eurjchem-1564	45	19	.	.	PUNCT
eurjchem-1564	46	1	many	many	ADJ
eurjchem-1564	46	2	reports	report	NOUN
eurjchem-1564	46	3	have	have	AUX
eurjchem-1564	46	4	been	be	AUX
eurjchem-1564	46	5	demonstrated	demonstrate	VERB
eurjchem-1564	46	6	some	some	DET
eurjchem-1564	46	7	complexes	complex	NOUN
eurjchem-1564	46	8	which	which	PRON
eurjchem-1564	46	9	contain	contain	VERB
eurjchem-1564	46	10	schiff	schiff	NOUN
eurjchem-1564	46	11	base	base	NOUN
eurjchem-1564	46	12	or	or	CCONJ
eurjchem-1564	46	13	ferrocenyl	ferrocenyl	ADJ
eurjchem-1564	46	14	derivatives	derivative	NOUN
eurjchem-1564	46	15	are	be	AUX
eurjchem-1564	46	16	highly	highly	ADV
eurjchem-1564	46	17	active	active	ADJ
eurjchem-1564	46	18	against	against	ADP
eurjchem-1564	46	19	several	several	ADJ
eurjchem-1564	46	20	diseases	disease	NOUN
eurjchem-1564	46	21	including	include	VERB
eurjchem-1564	46	22	cancer	cancer	NOUN
eurjchem-1564	46	23	[	[	X
eurjchem-1564	46	24	18‐20	18‐20	NUM
eurjchem-1564	46	25	]	]	PUNCT
eurjchem-1564	46	26	.	.	PUNCT
eurjchem-1564	47	1	2	2	X
eurjchem-1564	47	2	.	.	X
eurjchem-1564	47	3	experimental	experimental	ADJ
eurjchem-1564	47	4	2.1	2.1	NUM
eurjchem-1564	47	5	.	.	PUNCT
eurjchem-1564	48	1	instrumentation	instrumentation	NOUN
eurjchem-1564	48	2	elemental	elemental	ADJ
eurjchem-1564	48	3	analyses	analysis	NOUN
eurjchem-1564	48	4	were	be	AUX
eurjchem-1564	48	5	performed	perform	VERB
eurjchem-1564	48	6	by	by	ADP
eurjchem-1564	48	7	university	university	PROPN
eurjchem-1564	48	8	of	of	ADP
eurjchem-1564	48	9	al	al	PROPN
eurjchem-1564	48	10	al‐	al‐	PROPN
eurjchem-1564	48	11	bayt	bayt	VERB
eurjchem-1564	48	12	,	,	PUNCT
eurjchem-1564	48	13	al‐mafraq	al‐mafraq	PROPN
eurjchem-1564	48	14	,	,	PUNCT
eurjchem-1564	48	15	jordan	jordan	PROPN
eurjchem-1564	48	16	using	use	VERB
eurjchem-1564	48	17	a	a	DET
eurjchem-1564	48	18	euro	euro	NOUN
eurjchem-1564	48	19	vector	vector	NOUN
eurjchem-1564	48	20	ea	ea	X
eurjchem-1564	48	21	3000a	3000a	NUM
eurjchem-1564	48	22	elemental	elemental	ADJ
eurjchem-1564	48	23	analysis	analysis	NOUN
eurjchem-1564	48	24	(	(	PUNCT
eurjchem-1564	48	25	italy	italy	PROPN
eurjchem-1564	48	26	)	)	PUNCT
eurjchem-1564	48	27	.	.	PUNCT
eurjchem-1564	49	1	infrared	infrared	PROPN
eurjchem-1564	49	2	(	(	PUNCT
eurjchem-1564	49	3	ir	ir	NOUN
eurjchem-1564	49	4	)	)	PUNCT
eurjchem-1564	49	5	spectra	spectra	NOUN
eurjchem-1564	49	6	were	be	AUX
eurjchem-1564	49	7	recorded	record	VERB
eurjchem-1564	49	8	for	for	ADP
eurjchem-1564	49	9	kbr	kbr	PROPN
eurjchem-1564	49	10	pellets	pellet	NOUN
eurjchem-1564	49	11	on	on	ADP
eurjchem-1564	49	12	a	a	DET
eurjchem-1564	49	13	ft‐ir	ft‐ir	ADJ
eurjchem-1564	49	14	spectrophotometer	spectrophotometer	NOUN
eurjchem-1564	49	15	shimadzu	shimadzu	NOUN
eurjchem-1564	49	16	model	model	NOUN
eurjchem-1564	49	17	8400s	8400	NOUN
eurjchem-1564	49	18	in	in	ADP
eurjchem-1564	49	19	range	range	NOUN
eurjchem-1564	49	20	4000‐400	4000‐400	NUM
eurjchem-1564	49	21	cm‐1	cm‐1	NOUN
eurjchem-1564	49	22	at	at	ADP
eurjchem-1564	49	23	department	department	PROPN
eurjchem-1564	49	24	of	of	ADP
eurjchem-1564	49	25	chemistry	chemistry	NOUN
eurjchem-1564	49	26	,	,	PUNCT
eurjchem-1564	49	27	college	college	NOUN
eurjchem-1564	49	28	of	of	ADP
eurjchem-1564	49	29	education	education	NOUN
eurjchem-1564	49	30	for	for	ADP
eurjchem-1564	49	31	pure	pure	ADJ
eurjchem-1564	49	32	science	science	NOUN
eurjchem-1564	49	33	,	,	PUNCT
eurjchem-1564	49	34	university	university	NOUN
eurjchem-1564	49	35	of	of	ADP
eurjchem-1564	49	36	basrah	basrah	PROPN
eurjchem-1564	49	37	.	.	PUNCT
eurjchem-1564	50	1	uv‐vis	uv‐vis	PROPN
eurjchem-1564	50	2	spectra	spectra	PROPN
eurjchem-1564	50	3	for	for	ADP
eurjchem-1564	50	4	the	the	DET
eurjchem-1564	50	5	synthesized	synthesize	VERB
eurjchem-1564	50	6	complexes	complex	NOUN
eurjchem-1564	50	7	were	be	AUX
eurjchem-1564	50	8	recorded	record	VERB
eurjchem-1564	50	9	at	at	ADP
eurjchem-1564	50	10	department	department	NOUN
eurjchem-1564	50	11	of	of	ADP
eurjchem-1564	50	12	chemistry	chemistry	NOUN
eurjchem-1564	50	13	,	,	PUNCT
eurjchem-1564	50	14	college	college	NOUN
eurjchem-1564	50	15	of	of	ADP
eurjchem-1564	50	16	science	science	NOUN
eurjchem-1564	50	17	,	,	PUNCT
eurjchem-1564	50	18	university	university	NOUN
eurjchem-1564	50	19	of	of	ADP
eurjchem-1564	50	20	basrah	basrah	NOUN
eurjchem-1564	50	21	by	by	ADP
eurjchem-1564	50	22	using	use	VERB
eurjchem-1564	50	23	scan	scan	PROPN
eurjchem-1564	50	24	80d	80d	X
eurjchem-1564	50	25	(	(	PUNCT
eurjchem-1564	50	26	england	england	PROPN
eurjchem-1564	50	27	)	)	PUNCT
eurjchem-1564	50	28	at	at	ADP
eurjchem-1564	50	29	range	range	NOUN
eurjchem-1564	50	30	200‐800	200‐800	NUM
eurjchem-1564	50	31	nm	nm	NOUN
eurjchem-1564	50	32	using	use	VERB
eurjchem-1564	50	33	chloroform	chloroform	NOUN
eurjchem-1564	50	34	as	as	ADP
eurjchem-1564	50	35	a	a	DET
eurjchem-1564	50	36	solvents	solvent	NOUN
eurjchem-1564	50	37	and	and	CCONJ
eurjchem-1564	50	38	1	1	NUM
eurjchem-1564	50	39	cm3	cm3	NOUN
eurjchem-1564	50	40	pathway	pathway	NOUN
eurjchem-1564	50	41	quartz	quartz	NOUN
eurjchem-1564	50	42	cells	cell	NOUN
eurjchem-1564	50	43	.	.	PUNCT
eurjchem-1564	51	1	1h	1h	NUM
eurjchem-1564	51	2	nuclear	nuclear	PROPN
eurjchem-1564	51	3	magnetic	magnetic	ADJ
eurjchem-1564	51	4	resonance	resonance	NOUN
eurjchem-1564	51	5	(	(	PUNCT
eurjchem-1564	51	6	nmr	nmr	NOUN
eurjchem-1564	51	7	)	)	PUNCT
eurjchem-1564	51	8	spectra	spectra	NOUN
eurjchem-1564	51	9	were	be	AUX
eurjchem-1564	51	10	recorded	record	VERB
eurjchem-1564	51	11	at	at	ADP
eurjchem-1564	51	12	al	al	PROPN
eurjchem-1564	51	13	al‐bayt	al‐bayt	PROPN
eurjchem-1564	51	14	university	university	PROPN
eurjchem-1564	51	15	,	,	PUNCT
eurjchem-1564	51	16	jordan	jordan	PROPN
eurjchem-1564	51	17	,	,	PUNCT
eurjchem-1564	51	18	by	by	ADP
eurjchem-1564	51	19	using	use	VERB
eurjchem-1564	51	20	a	a	DET
eurjchem-1564	51	21	bruker	bruker	NOUN
eurjchem-1564	51	22	300	300	NUM
eurjchem-1564	51	23	mhz	mhz	NOUN
eurjchem-1564	51	24	(	(	PUNCT
eurjchem-1564	51	25	germany	germany	PROPN
eurjchem-1564	51	26	)	)	PUNCT
eurjchem-1564	51	27	.	.	PUNCT
eurjchem-1564	52	1	chemical	chemical	NOUN
eurjchem-1564	52	2	shift	shift	NOUN
eurjchem-1564	52	3	of	of	ADP
eurjchem-1564	52	4	all	all	DET
eurjchem-1564	52	5	1h	1h	NUM
eurjchem-1564	52	6	nmr	nmr	NOUN
eurjchem-1564	52	7	spectra	spectra	NOUN
eurjchem-1564	52	8	were	be	AUX
eurjchem-1564	52	9	recor‐	recor‐	NOUN
eurjchem-1564	52	10	ded	de	VERB
eurjchem-1564	52	11	in	in	ADP
eurjchem-1564	52	12	δ	δ	PROPN
eurjchem-1564	52	13	(	(	PUNCT
eurjchem-1564	52	14	ppm	ppm	NOUN
eurjchem-1564	52	15	)	)	PUNCT
eurjchem-1564	52	16	unit	unit	NOUN
eurjchem-1564	52	17	downfield	downfield	VERB
eurjchem-1564	52	18	from	from	ADP
eurjchem-1564	52	19	the	the	DET
eurjchem-1564	52	20	internal	internal	ADJ
eurjchem-1564	52	21	reference	reference	NOUN
eurjchem-1564	52	22	tetramethylsilane	tetramethylsilane	NOUN
eurjchem-1564	52	23	(	(	PUNCT
eurjchem-1564	52	24	tms	tms	PROPN
eurjchem-1564	52	25	)	)	PUNCT
eurjchem-1564	52	26	,	,	PUNCT
eurjchem-1564	52	27	using	use	VERB
eurjchem-1564	52	28	dimethylsulfoxide	dimethylsulfoxide	ADP
eurjchem-1564	52	29	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	52	30	solvent	solvent	NOUN
eurjchem-1564	52	31	.	.	PUNCT
eurjchem-1564	53	1	conductivity	conductivity	NOUN
eurjchem-1564	53	2	measurements	measurement	NOUN
eurjchem-1564	53	3	were	be	AUX
eurjchem-1564	53	4	measured	measure	VERB
eurjchem-1564	53	5	in	in	ADP
eurjchem-1564	53	6	1×10‐3	1×10‐3	NUM
eurjchem-1564	53	7	m	m	PROPN
eurjchem-1564	53	8	solutions	solution	NOUN
eurjchem-1564	53	9	of	of	ADP
eurjchem-1564	53	10	dimethyl	dimethyl	NOUN
eurjchem-1564	53	11	sulfoxide	sulfoxide	NOUN
eurjchem-1564	53	12	(	(	PUNCT
eurjchem-1564	53	13	dmso	dmso	NOUN
eurjchem-1564	53	14	)	)	PUNCT
eurjchem-1564	53	15	solvent	solvent	NOUN
eurjchem-1564	53	16	at	at	ADP
eurjchem-1564	53	17	room	room	NOUN
eurjchem-1564	53	18	temperature	temperature	NOUN
eurjchem-1564	53	19	using	use	VERB
eurjchem-1564	53	20	a	a	DET
eurjchem-1564	53	21	konduktoskop	konduktoskop	NOUN
eurjchem-1564	53	22	model	model	NOUN
eurjchem-1564	53	23	365b	365b	PROPN
eurjchem-1564	53	24	using	use	VERB
eurjchem-1564	53	25	standard	standard	ADJ
eurjchem-1564	53	26	conductivity	conductivity	NOUN
eurjchem-1564	53	27	cell	cell	NOUN
eurjchem-1564	53	28	with	with	ADP
eurjchem-1564	53	29	constant	constant	ADJ
eurjchem-1564	53	30	equal	equal	ADJ
eurjchem-1564	53	31	to	to	ADP
eurjchem-1564	53	32	0.81	0.81	NUM
eurjchem-1564	53	33	cm‐1	cm‐1	NOUN
eurjchem-1564	53	34	.	.	PUNCT
eurjchem-1564	54	1	2.2	2.2	NUM
eurjchem-1564	54	2	.	.	PUNCT
eurjchem-1564	54	3	synthesis	synthesis	NOUN
eurjchem-1564	54	4	n‐(3‐phenylpropyl)ethane‐1,2‐diamine	n‐(3‐phenylpropyl)ethane‐1,2‐diamine	NOUN
eurjchem-1564	54	5	,	,	PUNCT
eurjchem-1564	54	6	n	n	CCONJ
eurjchem-1564	54	7	,	,	PUNCT
eurjchem-1564	54	8	n'‐bis(3‐phenyl	n'‐bis(3‐phenyl	PROPN
eurjchem-1564	54	9	propyl)ethane‐1,2‐diamine	propyl)ethane‐1,2‐diamine	NOUN
eurjchem-1564	54	10	,	,	PUNCT
eurjchem-1564	54	11	n‐2‐furan	n‐2‐furan	PROPN
eurjchem-1564	54	12	methyledinebenzene‐	methyledinebenzene‐	PROPN
eurjchem-1564	54	13	1,2‐diamine	1,2‐diamine	PROPN
eurjchem-1564	54	14	,	,	PUNCT
eurjchem-1564	54	15	n	n	CCONJ
eurjchem-1564	54	16	,	,	PUNCT
eurjchem-1564	54	17	n'‐bis(2‐furanmethyledine)benzene‐1,2‐diami	n'‐bis(2‐furanmethyledine)benzene‐1,2‐diami	NOUN
eurjchem-1564	54	18	ne	ne	PROPN
eurjchem-1564	54	19	,	,	PUNCT
eurjchem-1564	54	20	n‐ferrocenmethyledinebenzene‐1,2‐diamine	n‐ferrocenmethyledinebenzene‐1,2‐diamine	PROPN
eurjchem-1564	54	21	,	,	PUNCT
eurjchem-1564	54	22	n	n	CCONJ
eurjchem-1564	54	23	,	,	PUNCT
eurjchem-1564	54	24	n'‐bis(ferro	n'‐bis(ferro	ADJ
eurjchem-1564	54	25	cenmethyledine	cenmethyledine	NOUN
eurjchem-1564	54	26	)	)	PUNCT
eurjchem-1564	54	27	benzene‐1,2‐diamine	benzene‐1,2‐diamine	PROPN
eurjchem-1564	54	28	,	,	PUNCT
eurjchem-1564	54	29	n‐1‐ferrocenethyli	n‐1‐ferrocenethyli	PROPN
eurjchem-1564	54	30	denebenzene‐1,2‐diamin	denebenzene‐1,2‐diamin	PROPN
eurjchem-1564	54	31	,	,	PUNCT
eurjchem-1564	54	32	n	n	CCONJ
eurjchem-1564	54	33	,	,	PUNCT
eurjchem-1564	54	34	n'‐bis(ferrocenethylidene	n'‐bis(ferrocenethylidene	ADJ
eurjchem-1564	54	35	)	)	PUNCT
eurjchem-1564	54	36	benze	benze	NOUN
eurjchem-1564	54	37	ne‐1,2‐diamine	ne‐1,2‐diamine	PROPN
eurjchem-1564	54	38	were	be	AUX
eurjchem-1564	54	39	prepared	prepare	VERB
eurjchem-1564	54	40	in	in	ADP
eurjchem-1564	54	41	our	our	PRON
eurjchem-1564	54	42	previously	previously	ADV
eurjchem-1564	54	43	paper	paper	NOUN
eurjchem-1564	54	44	[	[	X
eurjchem-1564	54	45	21	21	NUM
eurjchem-1564	54	46	]	]	PUNCT
eurjchem-1564	54	47	.	.	PUNCT
eurjchem-1564	55	1	dichloro‐bis(benzonitrile)palladium(ii	dichloro‐bis(benzonitrile)palladium(ii	NOUN
eurjchem-1564	55	2	)	)	PUNCT
eurjchem-1564	55	3	was	be	AUX
eurjchem-1564	55	4	prepared	prepare	VERB
eurjchem-1564	55	5	by	by	ADP
eurjchem-1564	55	6	the	the	DET
eurjchem-1564	55	7	literature	literature	NOUN
eurjchem-1564	55	8	method	method	NOUN
eurjchem-1564	55	9	[	[	X
eurjchem-1564	55	10	22	22	NUM
eurjchem-1564	55	11	]	]	PUNCT
eurjchem-1564	55	12	.	.	PUNCT
eurjchem-1564	56	1	2.2.1	2.2.1	NUM
eurjchem-1564	56	2	.	.	PUNCT
eurjchem-1564	56	3	synthesis	synthesis	NOUN
eurjchem-1564	56	4	of	of	ADP
eurjchem-1564	56	5	complexes	complex	NOUN
eurjchem-1564	56	6	2.2.1.1	2.2.1.1	NUM
eurjchem-1564	56	7	.	.	PUNCT
eurjchem-1564	57	1	synthesis	synthesis	NOUN
eurjchem-1564	57	2	of	of	ADP
eurjchem-1564	57	3	dichloro[n‐(3‐phenylpropyl)ethane‐1,2‐	dichloro[n‐(3‐phenylpropyl)ethane‐1,2‐	PROPN
eurjchem-1564	57	4	diamine]palladium(ii	diamine]palladium(ii	PROPN
eurjchem-1564	57	5	)	)	PUNCT
eurjchem-1564	57	6	(	(	PUNCT
eurjchem-1564	57	7	1	1	X
eurjchem-1564	57	8	)	)	PUNCT
eurjchem-1564	57	9	to	to	ADP
eurjchem-1564	57	10	dibenzonitriledichloro	dibenzonitriledichloro	ADV
eurjchem-1564	57	11	palladium(ii	palladium(ii	PROPN
eurjchem-1564	57	12	)	)	PUNCT
eurjchem-1564	57	13	,	,	PUNCT
eurjchem-1564	57	14	pdcl2(phcn)2	pdcl2(phcn)2	PROPN
eurjchem-1564	57	15	,	,	PUNCT
eurjchem-1564	57	16	(	(	PUNCT
eurjchem-1564	57	17	0.383	0.383	NUM
eurjchem-1564	57	18	g	g	NOUN
eurjchem-1564	57	19	;	;	PUNCT
eurjchem-1564	57	20	1	1	NUM
eurjchem-1564	57	21	mmol	mmol	NOUN
eurjchem-1564	57	22	)	)	PUNCT
eurjchem-1564	57	23	(	(	PUNCT
eurjchem-1564	57	24	15	15	NUM
eurjchem-1564	57	25	ml	ml	NOUN
eurjchem-1564	57	26	)	)	PUNCT
eurjchem-1564	57	27	,	,	PUNCT
eurjchem-1564	57	28	n‐(3‐phenylpropyl)ethane‐1,2‐	n‐(3‐phenylpropyl)ethane‐1,2‐	NOUN
eurjchem-1564	57	29	diamine	diamine	NOUN
eurjchem-1564	57	30	(	(	PUNCT
eurjchem-1564	57	31	0.355	0.355	NUM
eurjchem-1564	57	32	g	g	NOUN
eurjchem-1564	57	33	,	,	PUNCT
eurjchem-1564	57	34	1	1	NUM
eurjchem-1564	57	35	mmol	mmol	NOUN
eurjchem-1564	57	36	)	)	PUNCT
eurjchem-1564	57	37	dissolved	dissolve	VERB
eurjchem-1564	57	38	in	in	ADP
eurjchem-1564	57	39	absolute	absolute	ADJ
eurjchem-1564	57	40	ethanol	ethanol	NOUN
eurjchem-1564	57	41	(	(	PUNCT
eurjchem-1564	57	42	15	15	NUM
eurjchem-1564	57	43	ml	ml	NOUN
eurjchem-1564	57	44	)	)	PUNCT
eurjchem-1564	57	45	was	be	AUX
eurjchem-1564	57	46	slowly	slowly	ADV
eurjchem-1564	57	47	added	add	VERB
eurjchem-1564	57	48	.	.	PUNCT
eurjchem-1564	58	1	after	after	ADP
eurjchem-1564	58	2	stirring	stir	VERB
eurjchem-1564	58	3	48	48	NUM
eurjchem-1564	58	4	h	h	NOUN
eurjchem-1564	58	5	at	at	ADP
eurjchem-1564	58	6	room	room	NOUN
eurjchem-1564	58	7	tempe‐	tempe‐	PUNCT
eurjchem-1564	59	1	rature	rature	NOUN
eurjchem-1564	60	1	,	,	PUNCT
eurjchem-1564	60	2	the	the	DET
eurjchem-1564	60	3	product	product	NOUN
eurjchem-1564	60	4	was	be	AUX
eurjchem-1564	60	5	isolated	isolate	VERB
eurjchem-1564	60	6	by	by	ADP
eurjchem-1564	60	7	filtration	filtration	NOUN
eurjchem-1564	60	8	.	.	PUNCT
eurjchem-1564	61	1	then	then	ADV
eurjchem-1564	61	2	,	,	PUNCT
eurjchem-1564	61	3	the	the	DET
eurjchem-1564	61	4	solid	solid	ADJ
eurjchem-1564	61	5	product	product	NOUN
eurjchem-1564	61	6	was	be	AUX
eurjchem-1564	61	7	washed	wash	VERB
eurjchem-1564	61	8	with	with	ADP
eurjchem-1564	61	9	water	water	NOUN
eurjchem-1564	61	10	,	,	PUNCT
eurjchem-1564	61	11	ethanol	ethanol	NOUN
eurjchem-1564	61	12	,	,	PUNCT
eurjchem-1564	61	13	and	and	CCONJ
eurjchem-1564	61	14	finally	finally	ADV
eurjchem-1564	61	15	,	,	PUNCT
eurjchem-1564	61	16	dried	dry	VERB
eurjchem-1564	61	17	in	in	ADP
eurjchem-1564	61	18	vacuum	vacuum	NOUN
eurjchem-1564	61	19	(	(	PUNCT
eurjchem-1564	61	20	scheme	scheme	NOUN
eurjchem-1564	61	21	1	1	NUM
eurjchem-1564	61	22	)	)	PUNCT
eurjchem-1564	61	23	.	.	PUNCT
eurjchem-1564	62	1	color	color	NOUN
eurjchem-1564	62	2	:	:	PUNCT
eurjchem-1564	62	3	pale	pale	ADJ
eurjchem-1564	62	4	yellow	yellow	ADJ
eurjchem-1564	62	5	.	.	PUNCT
eurjchem-1564	63	1	yield	yield	NOUN
eurjchem-1564	63	2	:	:	PUNCT
eurjchem-1564	63	3	62	62	NUM
eurjchem-1564	63	4	%	%	NOUN
eurjchem-1564	63	5	.	.	PUNCT
eurjchem-1564	64	1	m.p	m.p	PROPN
eurjchem-1564	64	2	.	.	PROPN
eurjchem-1564	64	3	:	:	PUNCT
eurjchem-1564	65	1	75‐77	75‐77	NUM
eurjchem-1564	65	2	°	°	SYM
eurjchem-1564	65	3	c	c	NOUN
eurjchem-1564	65	4	.	.	PUNCT
eurjchem-1564	66	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	66	2	(	(	PUNCT
eurjchem-1564	66	3	kbr	kbr	PROPN
eurjchem-1564	66	4	,	,	PUNCT
eurjchem-1564	66	5			PROPN
eurjchem-1564	66	6	,	,	PUNCT
eurjchem-1564	66	7	cm‐1	cm‐1	PROPN
eurjchem-1564	66	8	):	):	PUNCT
eurjchem-1564	66	9	3346	3346	NUM
eurjchem-1564	66	10	,	,	PUNCT
eurjchem-1564	66	11	3066	3066	NUM
eurjchem-1564	66	12	,	,	PUNCT
eurjchem-1564	66	13	2929	2929	NUM
eurjchem-1564	66	14	,	,	PUNCT
eurjchem-1564	66	15	2861	2861	NUM
eurjchem-1564	66	16	,	,	PUNCT
eurjchem-1564	66	17	1494	1494	NUM
eurjchem-1564	66	18	,	,	PUNCT
eurjchem-1564	66	19	1454	1454	NUM
eurjchem-1564	66	20	,	,	PUNCT
eurjchem-1564	66	21	1239	1239	NUM
eurjchem-1564	66	22	,	,	PUNCT
eurjchem-1564	66	23	752	752	NUM
eurjchem-1564	66	24	,	,	PUNCT
eurjchem-1564	66	25	686	686	NUM
eurjchem-1564	66	26	,	,	PUNCT
eurjchem-1564	66	27	666	666	NUM
eurjchem-1564	66	28	.	.	PUNCT
eurjchem-1564	66	29	1h	1h	NUM
eurjchem-1564	66	30	nmr	nmr	NOUN
eurjchem-1564	66	31	(	(	PUNCT
eurjchem-1564	66	32	300	300	NUM
eurjchem-1564	66	33	mhz	mhz	NOUN
eurjchem-1564	66	34	,	,	PUNCT
eurjchem-1564	66	35	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	66	36	,	,	PUNCT
eurjchem-1564	66	37	δ	δ	PROPN
eurjchem-1564	66	38	,	,	PUNCT
eurjchem-1564	66	39	ppm	ppm	NUM
eurjchem-1564	66	40	):	):	PUNCT
eurjchem-1564	66	41	1.14	1.14	NUM
eurjchem-1564	66	42	(	(	PUNCT
eurjchem-1564	66	43	t	t	PROPN
eurjchem-1564	66	44	,	,	PUNCT
eurjchem-1564	66	45	2h	2h	NUM
eurjchem-1564	66	46	,	,	PUNCT
eurjchem-1564	66	47	ch2ph	ch2ph	NOUN
eurjchem-1564	66	48	)	)	PUNCT
eurjchem-1564	66	49	,	,	PUNCT
eurjchem-1564	66	50	1.80	1.80	NUM
eurjchem-1564	66	51	(	(	PUNCT
eurjchem-1564	66	52	q	q	NOUN
eurjchem-1564	66	53	,	,	PUNCT
eurjchem-1564	66	54	2h	2h	NUM
eurjchem-1564	66	55	,	,	PUNCT
eurjchem-1564	66	56	ch2ch2ch2	ch2ch2ch2	NOUN
eurjchem-1564	66	57	)	)	PUNCT
eurjchem-1564	66	58	,	,	PUNCT
eurjchem-1564	66	59	2.60	2.60	NUM
eurjchem-1564	66	60	(	(	PUNCT
eurjchem-1564	66	61	t	t	PROPN
eurjchem-1564	66	62	,	,	PUNCT
eurjchem-1564	66	63	2h	2h	NUM
eurjchem-1564	66	64	,	,	PUNCT
eurjchem-1564	66	65	ch2ch2ch2nh	ch2ch2ch2nh	NOUN
eurjchem-1564	66	66	)	)	PUNCT
eurjchem-1564	66	67	,	,	PUNCT
eurjchem-1564	66	68	3.79	3.79	NUM
eurjchem-1564	66	69	(	(	PUNCT
eurjchem-1564	66	70	t	t	PROPN
eurjchem-1564	66	71	,	,	PUNCT
eurjchem-1564	66	72	2h	2h	NUM
eurjchem-1564	66	73	,	,	PUNCT
eurjchem-1564	66	74	ch2ch2nh2	ch2ch2nh2	PROPN
eurjchem-1564	66	75	)	)	PUNCT
eurjchem-1564	66	76	,	,	PUNCT
eurjchem-1564	66	77	4.46	4.46	NUM
eurjchem-1564	66	78	(	(	PUNCT
eurjchem-1564	66	79	t	t	PROPN
eurjchem-1564	66	80	,	,	PUNCT
eurjchem-1564	66	81	2h	2h	NUM
eurjchem-1564	66	82	,	,	PUNCT
eurjchem-1564	66	83	ch2ch2nh2	ch2ch2nh2	PROPN
eurjchem-1564	66	84	)	)	PUNCT
eurjchem-1564	66	85	,	,	PUNCT
eurjchem-1564	66	86	5.80	5.80	NUM
eurjchem-1564	66	87	(	(	PUNCT
eurjchem-1564	66	88	s	s	PROPN
eurjchem-1564	66	89	,	,	PUNCT
eurjchem-1564	66	90	1h	1h	NUM
eurjchem-1564	66	91	,	,	PUNCT
eurjchem-1564	66	92	nh	nh	PROPN
eurjchem-1564	66	93	)	)	PUNCT
eurjchem-1564	66	94	,	,	PUNCT
eurjchem-1564	66	95	5.90	5.90	NUM
eurjchem-1564	66	96	(	(	PUNCT
eurjchem-1564	66	97	s	s	PROPN
eurjchem-1564	66	98	,	,	PUNCT
eurjchem-1564	66	99	2h	2h	NUM
eurjchem-1564	66	100	,	,	PUNCT
eurjchem-1564	66	101	nh2	nh2	PROPN
eurjchem-1564	66	102	)	)	PUNCT
eurjchem-1564	66	103	,	,	PUNCT
eurjchem-1564	66	104	7.19‐7.35	7.19‐7.35	PROPN
eurjchem-1564	66	105	(	(	PUNCT
eurjchem-1564	66	106	m	m	PROPN
eurjchem-1564	66	107	,	,	PUNCT
eurjchem-1564	66	108	5h	5h	NUM
eurjchem-1564	66	109	,	,	PUNCT
eurjchem-1564	66	110	ar‐h	ar‐h	NOUN
eurjchem-1564	66	111	)	)	PUNCT
eurjchem-1564	66	112	.	.	PUNCT
eurjchem-1564	67	1	anal	anal	PROPN
eurjchem-1564	67	2	.	.	PUNCT
eurjchem-1564	67	3	calcd	calcd	NOUN
eurjchem-1564	67	4	.	.	PUNCT
eurjchem-1564	68	1	for	for	ADP
eurjchem-1564	68	2	c11h18cl2n2pd	c11h18cl2n2pd	PROPN
eurjchem-1564	68	3	:	:	PUNCT
eurjchem-1564	68	4	c	c	X
eurjchem-1564	68	5	,	,	PUNCT
eurjchem-1564	68	6	37.15	37.15	NUM
eurjchem-1564	68	7	;	;	PUNCT
eurjchem-1564	68	8	h	h	NOUN
eurjchem-1564	68	9	,	,	PUNCT
eurjchem-1564	68	10	5.10	5.10	NUM
eurjchem-1564	68	11	;	;	PUNCT
eurjchem-1564	68	12	n	n	CCONJ
eurjchem-1564	68	13	,	,	PUNCT
eurjchem-1564	68	14	7.88	7.88	NUM
eurjchem-1564	68	15	.	.	PUNCT
eurjchem-1564	68	16	found	find	VERB
eurjchem-1564	68	17	:	:	PUNCT
eurjchem-1564	69	1	c	c	X
eurjchem-1564	69	2	,	,	PUNCT
eurjchem-1564	69	3	37.17	37.17	NUM
eurjchem-1564	69	4	;	;	PUNCT
eurjchem-1564	69	5	h	h	NOUN
eurjchem-1564	69	6	,	,	PUNCT
eurjchem-1564	69	7	5.19	5.19	NUM
eurjchem-1564	69	8	;	;	PUNCT
eurjchem-1564	69	9	n	n	CCONJ
eurjchem-1564	69	10	,	,	PUNCT
eurjchem-1564	69	11	7.91	7.91	NUM
eurjchem-1564	69	12	%	%	NOUN
eurjchem-1564	69	13	.	.	PUNCT
eurjchem-1564	70	1	λm	λm	X
eurjchem-1564	70	2	(	(	PUNCT
eurjchem-1564	70	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	70	4	):	):	PUNCT
eurjchem-1564	70	5	7.91	7.91	NUM
eurjchem-1564	70	6	.	.	PUNCT
eurjchem-1564	71	1	2.2.1.2	2.2.1.2	NUM
eurjchem-1564	71	2	.	.	NOUN
eurjchem-1564	71	3	synthesis	synthesis	NOUN
eurjchem-1564	71	4	of	of	ADP
eurjchem-1564	71	5	dichloro[n	dichloro[n	PROPN
eurjchem-1564	71	6	,	,	PUNCT
eurjchem-1564	71	7	n'‐bis(3‐phenylpropyl	n'‐bis(3‐phenylpropyl	PROPN
eurjchem-1564	71	8	)	)	PUNCT
eurjchem-1564	71	9	ethane‐1,2‐diamine]palladium(ii	ethane‐1,2‐diamine]palladium(ii	PROPN
eurjchem-1564	71	10	)	)	PUNCT
eurjchem-1564	71	11	(	(	PUNCT
eurjchem-1564	71	12	2	2	X
eurjchem-1564	71	13	)	)	PUNCT
eurjchem-1564	71	14	to	to	ADP
eurjchem-1564	71	15	a	a	DET
eurjchem-1564	71	16	stirring	stirring	ADJ
eurjchem-1564	71	17	solution	solution	NOUN
eurjchem-1564	71	18	of	of	ADP
eurjchem-1564	71	19	dibenzonitriledichloropalladium	dibenzonitriledichloropalladium	NOUN
eurjchem-1564	71	20	(	(	PUNCT
eurjchem-1564	71	21	ii	ii	NOUN
eurjchem-1564	71	22	)	)	PUNCT
eurjchem-1564	71	23	,	,	PUNCT
eurjchem-1564	71	24	pdcl2(phcn)2	pdcl2(phcn)2	PROPN
eurjchem-1564	71	25	,	,	PUNCT
eurjchem-1564	71	26	(	(	PUNCT
eurjchem-1564	71	27	0.383	0.383	NUM
eurjchem-1564	71	28	g	g	NOUN
eurjchem-1564	71	29	,	,	PUNCT
eurjchem-1564	71	30	1	1	NUM
eurjchem-1564	71	31	mmol	mmol	NOUN
eurjchem-1564	71	32	)	)	PUNCT
eurjchem-1564	71	33	in	in	ADP
eurjchem-1564	71	34	absolute	absolute	ADJ
eurjchem-1564	71	35	ethanol	ethanol	NOUN
eurjchem-1564	71	36	(	(	PUNCT
eurjchem-1564	71	37	15	15	NUM
eurjchem-1564	71	38	ml	ml	NOUN
eurjchem-1564	71	39	)	)	PUNCT
eurjchem-1564	71	40	with	with	ADP
eurjchem-1564	71	41	n	n	CCONJ
eurjchem-1564	71	42	,	,	PUNCT
eurjchem-1564	71	43	n'‐bis(3‐phenylpropyl)ethane‐1,2‐diamine	n'‐bis(3‐phenylpropyl)ethane‐1,2‐diamine	NUM
eurjchem-1564	71	44	(	(	PUNCT
eurjchem-1564	71	45	0.489	0.489	NUM
eurjchem-1564	71	46	g	g	NOUN
eurjchem-1564	71	47	,	,	PUNCT
eurjchem-1564	71	48	1	1	NUM
eurjchem-1564	71	49	mmol	mmol	NOUN
eurjchem-1564	71	50	)	)	PUNCT
eurjchem-1564	71	51	in	in	ADP
eurjchem-1564	71	52	25	25	NUM
eurjchem-1564	71	53	ml	ml	NOUN
eurjchem-1564	71	54	of	of	ADP
eurjchem-1564	71	55	absolute	absolute	ADJ
eurjchem-1564	71	56	ethanol	ethanol	NOUN
eurjchem-1564	71	57	were	be	AUX
eurjchem-1564	71	58	stirring	stir	VERB
eurjchem-1564	71	59	for	for	ADP
eurjchem-1564	71	60	48	48	NUM
eurjchem-1564	71	61	h	h	NOUN
eurjchem-1564	71	62	at	at	ADP
eurjchem-1564	71	63	room	room	NOUN
eurjchem-1564	71	64	temperature	temperature	NOUN
eurjchem-1564	71	65	,	,	PUNCT
eurjchem-1564	71	66	and	and	CCONJ
eurjchem-1564	71	67	a	a	DET
eurjchem-1564	71	68	brown	brown	ADJ
eurjchem-1564	71	69	precipitate	precipitate	NOUN
eurjchem-1564	71	70	had	have	AUX
eurjchem-1564	71	71	formed	form	VERB
eurjchem-1564	71	72	.	.	PUNCT
eurjchem-1564	72	1	the	the	DET
eurjchem-1564	72	2	crude	crude	ADJ
eurjchem-1564	72	3	solid	solid	NOUN
eurjchem-1564	72	4	was	be	AUX
eurjchem-1564	72	5	filtered	filter	VERB
eurjchem-1564	72	6	,	,	PUNCT
eurjchem-1564	72	7	washed	wash	VERB
eurjchem-1564	72	8	with	with	ADP
eurjchem-1564	72	9	water	water	NOUN
eurjchem-1564	72	10	,	,	PUNCT
eurjchem-1564	72	11	ethanol	ethanol	NOUN
eurjchem-1564	72	12	,	,	PUNCT
eurjchem-1564	72	13	and	and	CCONJ
eurjchem-1564	72	14	dried	dry	VERB
eurjchem-1564	72	15	in	in	ADP
eurjchem-1564	72	16	vacuum	vacuum	NOUN
eurjchem-1564	72	17	to	to	PART
eurjchem-1564	72	18	afford	afford	VERB
eurjchem-1564	72	19	the	the	DET
eurjchem-1564	72	20	complex	complex	ADJ
eurjchem-1564	72	21	2	2	NUM
eurjchem-1564	72	22	(	(	PUNCT
eurjchem-1564	72	23	scheme	scheme	NOUN
eurjchem-1564	72	24	2	2	NUM
eurjchem-1564	72	25	)	)	PUNCT
eurjchem-1564	72	26	.	.	PUNCT
eurjchem-1564	73	1	color	color	PROPN
eurjchem-1564	73	2	:	:	PUNCT
eurjchem-1564	73	3	orange	orange	PROPN
eurjchem-1564	73	4	solid	solid	PROPN
eurjchem-1564	73	5	.	.	PUNCT
eurjchem-1564	74	1	yield	yield	NOUN
eurjchem-1564	74	2	:	:	PUNCT
eurjchem-1564	74	3	71	71	NUM
eurjchem-1564	74	4	%	%	NOUN
eurjchem-1564	74	5	.	.	PUNCT
eurjchem-1564	75	1	m.p	m.p	PROPN
eurjchem-1564	75	2	.	.	PROPN
eurjchem-1564	75	3	:	:	PUNCT
eurjchem-1564	76	1	90‐92	90‐92	NUM
eurjchem-1564	76	2	°	°	ADP
eurjchem-1564	76	3	c	c	NOUN
eurjchem-1564	76	4	(	(	PUNCT
eurjchem-1564	76	5	dec	dec	PROPN
eurjchem-1564	76	6	.	.	PROPN
eurjchem-1564	76	7	)	)	PUNCT
eurjchem-1564	76	8	.	.	PUNCT
eurjchem-1564	77	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	77	2	(	(	PUNCT
eurjchem-1564	77	3	kbr	kbr	PROPN
eurjchem-1564	77	4	,	,	PUNCT
eurjchem-1564	77	5			PROPN
eurjchem-1564	77	6	,	,	PUNCT
eurjchem-1564	77	7	cm‐1	cm‐1	PROPN
eurjchem-1564	77	8	):	):	PUNCT
eurjchem-1564	77	9	3390	3390	NUM
eurjchem-1564	77	10	,	,	PUNCT
eurjchem-1564	77	11	3022	3022	NUM
eurjchem-1564	77	12	,	,	PUNCT
eurjchem-1564	77	13	2924	2924	NUM
eurjchem-1564	77	14	,	,	PUNCT
eurjchem-1564	77	15	2854	2854	NUM
eurjchem-1564	77	16	,	,	PUNCT
eurjchem-1564	77	17	1496	1496	NUM
eurjchem-1564	77	18	,	,	PUNCT
eurjchem-1564	77	19	1452	1452	NUM
eurjchem-1564	77	20	,	,	PUNCT
eurjchem-1564	77	21	1266	1266	NUM
eurjchem-1564	77	22	,	,	PUNCT
eurjchem-1564	77	23	750	750	NUM
eurjchem-1564	77	24	,	,	PUNCT
eurjchem-1564	77	25	698	698	NUM
eurjchem-1564	77	26	,	,	PUNCT
eurjchem-1564	77	27	617	617	NUM
eurjchem-1564	77	28	.	.	NOUN
eurjchem-1564	77	29	1h	1h	NUM
eurjchem-1564	77	30	nmr	nmr	NOUN
eurjchem-1564	77	31	(	(	PUNCT
eurjchem-1564	77	32	300	300	NUM
eurjchem-1564	77	33	mhz	mhz	NOUN
eurjchem-1564	77	34	,	,	PUNCT
eurjchem-1564	77	35	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	77	36	,	,	PUNCT
eurjchem-1564	77	37	δ	δ	PROPN
eurjchem-1564	77	38	,	,	PUNCT
eurjchem-1564	77	39	ppm	ppm	NUM
eurjchem-1564	77	40	):	):	PUNCT
eurjchem-1564	77	41	1.23	1.23	NUM
eurjchem-1564	77	42	(	(	PUNCT
eurjchem-1564	77	43	t	t	PROPN
eurjchem-1564	77	44	,	,	PUNCT
eurjchem-1564	77	45	4h	4h	NUM
eurjchem-1564	77	46	,	,	PUNCT
eurjchem-1564	77	47	2ch2ph	2ch2ph	PROPN
eurjchem-1564	77	48	)	)	PUNCT
eurjchem-1564	77	49	,	,	PUNCT
eurjchem-1564	77	50	1.79	1.79	NUM
eurjchem-1564	77	51	(	(	PUNCT
eurjchem-1564	77	52	qu	qu	PROPN
eurjchem-1564	77	53	,	,	PUNCT
eurjchem-1564	77	54	4h	4h	NOUN
eurjchem-1564	77	55	,	,	PUNCT
eurjchem-1564	77	56	2	2	NUM
eurjchem-1564	77	57	ch2ch2ch2	ch2ch2ch2	NOUN
eurjchem-1564	77	58	)	)	PUNCT
eurjchem-1564	77	59	,	,	PUNCT
eurjchem-1564	77	60	2.60	2.60	NUM
eurjchem-1564	77	61	(	(	PUNCT
eurjchem-1564	77	62	t	t	PROPN
eurjchem-1564	77	63	,	,	PUNCT
eurjchem-1564	77	64	4h	4h	NUM
eurjchem-1564	77	65	,	,	PUNCT
eurjchem-1564	77	66	2	2	NUM
eurjchem-1564	77	67	ch2ch2ch2nh	ch2ch2ch2nh	NOUN
eurjchem-1564	77	68	)	)	PUNCT
eurjchem-1564	77	69	,	,	PUNCT
eurjchem-1564	77	70	3.01	3.01	NUM
eurjchem-1564	77	71	(	(	PUNCT
eurjchem-1564	77	72	t	t	PROPN
eurjchem-1564	77	73	,	,	PUNCT
eurjchem-1564	77	74	4h	4h	NUM
eurjchem-1564	77	75	,	,	PUNCT
eurjchem-1564	77	76	2	2	NUM
eurjchem-1564	77	77	ch2nh	ch2nh	NOUN
eurjchem-1564	77	78	)	)	PUNCT
eurjchem-1564	77	79	,	,	PUNCT
eurjchem-1564	77	80	5.95	5.95	NUM
eurjchem-1564	77	81	(	(	PUNCT
eurjchem-1564	77	82	s	s	PROPN
eurjchem-1564	77	83	,	,	PUNCT
eurjchem-1564	77	84	2h	2h	NUM
eurjchem-1564	77	85	,	,	PUNCT
eurjchem-1564	77	86	2nh	2nh	NOUN
eurjchem-1564	77	87	)	)	PUNCT
eurjchem-1564	77	88	,	,	PUNCT
eurjchem-1564	77	89	7.10‐	7.10‐	NUM
eurjchem-1564	77	90	7.40	7.40	NUM
eurjchem-1564	77	91	(	(	PUNCT
eurjchem-1564	77	92	m	m	PROPN
eurjchem-1564	77	93	,	,	PUNCT
eurjchem-1564	77	94	10h	10h	NUM
eurjchem-1564	77	95	,	,	PUNCT
eurjchem-1564	77	96	ar‐h	ar‐h	NOUN
eurjchem-1564	77	97	)	)	PUNCT
eurjchem-1564	77	98	.	.	PUNCT
eurjchem-1564	78	1	λm	λm	X
eurjchem-1564	78	2	(	(	PUNCT
eurjchem-1564	78	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	78	4	):	):	PUNCT
eurjchem-1564	78	5	5.10	5.10	NUM
eurjchem-1564	78	6	.	.	PUNCT
eurjchem-1564	79	1	al‐fregi	al‐fregi	NUM
eurjchem-1564	79	2	et	et	VERB
eurjchem-1564	79	3	al	al	PROPN
eurjchem-1564	79	4	.	.	PUNCT
eurjchem-1564	79	5	/	/	SYM
eurjchem-1564	79	6	european	european	PROPN
eurjchem-1564	79	7	journal	journal	PROPN
eurjchem-1564	79	8	of	of	ADP
eurjchem-1564	79	9	chemistry	chemistry	NOUN
eurjchem-1564	79	10	8	8	NUM
eurjchem-1564	79	11	(	(	PUNCT
eurjchem-1564	79	12	2	2	NUM
eurjchem-1564	79	13	)	)	PUNCT
eurjchem-1564	79	14	(	(	PUNCT
eurjchem-1564	79	15	2017	2017	NUM
eurjchem-1564	79	16	)	)	PUNCT
eurjchem-1564	79	17	155‐161	155‐161	NUM
eurjchem-1564	79	18	157	157	NUM
eurjchem-1564	79	19	scheme	scheme	NOUN
eurjchem-1564	79	20	2	2	NUM
eurjchem-1564	79	21	etoh	etoh	NOUN
eurjchem-1564	79	22	48	48	NUM
eurjchem-1564	79	23	h	h	NOUN
eurjchem-1564	79	24	(	(	PUNCT
eurjchem-1564	79	25	7	7	NUM
eurjchem-1564	79	26	)	)	PUNCT
eurjchem-1564	79	27	n	n	NOUN
eurjchem-1564	79	28	nh2ar	nh2ar	NOUN
eurjchem-1564	79	29	pd(phcn)2cl2	pd(phcn)2cl2	NOUN
eurjchem-1564	79	30	n	n	CCONJ
eurjchem-1564	79	31	nh2ar	nh2ar	NOUN
eurjchem-1564	79	32	pd	pd	NOUN
eurjchem-1564	79	33	cl	cl	NOUN
eurjchem-1564	79	34	cl	cl	NOUN
eurjchem-1564	79	35	2	2	NUM
eurjchem-1564	79	36	phcn	phcn	PROPN
eurjchem-1564	79	37	ar	ar	PROPN
eurjchem-1564	79	38	:	:	PUNCT
eurjchem-1564	79	39	o	o	PROPN
eurjchem-1564	79	40	ch	ch	PROPN
eurjchem-1564	79	41	fe	fe	PROPN
eurjchem-1564	79	42	ch	ch	PROPN
eurjchem-1564	79	43	fe	fe	PROPN
eurjchem-1564	79	44	c	c	PROPN
eurjchem-1564	79	45	ch3	ch3	PROPN
eurjchem-1564	79	46	(	(	PUNCT
eurjchem-1564	79	47	3	3	NUM
eurjchem-1564	79	48	)	)	PUNCT
eurjchem-1564	79	49	(	(	PUNCT
eurjchem-1564	79	50	5	5	X
eurjchem-1564	79	51	)	)	PUNCT
eurjchem-1564	79	52	scheme	scheme	NOUN
eurjchem-1564	79	53	3	3	NUM
eurjchem-1564	79	54	anal	anal	NOUN
eurjchem-1564	79	55	.	.	PUNCT
eurjchem-1564	80	1	calcd	calcd	NOUN
eurjchem-1564	80	2	.	.	PUNCT
eurjchem-1564	81	1	for	for	ADP
eurjchem-1564	81	2	c20h28cl2n2pd	c20h28cl2n2pd	NOUN
eurjchem-1564	81	3	:	:	PUNCT
eurjchem-1564	81	4	c	c	X
eurjchem-1564	81	5	,	,	PUNCT
eurjchem-1564	81	6	50.70	50.70	NUM
eurjchem-1564	81	7	;	;	PUNCT
eurjchem-1564	81	8	h	h	NOUN
eurjchem-1564	81	9	,	,	PUNCT
eurjchem-1564	81	10	5.96	5.96	NUM
eurjchem-1564	81	11	;	;	PUNCT
eurjchem-1564	81	12	n	n	CCONJ
eurjchem-1564	81	13	,	,	PUNCT
eurjchem-1564	81	14	5.91	5.91	NUM
eurjchem-1564	81	15	.	.	PUNCT
eurjchem-1564	81	16	found	find	VERB
eurjchem-1564	81	17	:	:	PUNCT
eurjchem-1564	82	1	c	c	X
eurjchem-1564	82	2	,	,	PUNCT
eurjchem-1564	82	3	50.65	50.65	NUM
eurjchem-1564	82	4	;	;	PUNCT
eurjchem-1564	82	5	h	h	NOUN
eurjchem-1564	82	6	,	,	PUNCT
eurjchem-1564	82	7	5.87	5.87	NUM
eurjchem-1564	82	8	;	;	PUNCT
eurjchem-1564	82	9	n	n	CCONJ
eurjchem-1564	82	10	,	,	PUNCT
eurjchem-1564	82	11	5.88	5.88	NUM
eurjchem-1564	82	12	%	%	NOUN
eurjchem-1564	82	13	.	.	PUNCT
eurjchem-1564	83	1	2.2.1.3	2.2.1.3	X
eurjchem-1564	83	2	.	.	PUNCT
eurjchem-1564	83	3	synthesis	synthesis	NOUN
eurjchem-1564	83	4	of	of	ADP
eurjchem-1564	83	5	dichloro[n‐(2‐furanmethyledine	dichloro[n‐(2‐furanmethyledine	PROPN
eurjchem-1564	83	6	)	)	PUNCT
eurjchem-1564	83	7	benzene‐1,2‐diamine]palladium(ii	benzene‐1,2‐diamine]palladium(ii	NOUN
eurjchem-1564	83	8	)	)	PUNCT
eurjchem-1564	83	9	(	(	PUNCT
eurjchem-1564	83	10	3	3	X
eurjchem-1564	83	11	)	)	PUNCT
eurjchem-1564	83	12	to	to	ADP
eurjchem-1564	83	13	a	a	DET
eurjchem-1564	83	14	freshly	freshly	ADV
eurjchem-1564	83	15	prepared	prepare	VERB
eurjchem-1564	83	16	absolute	absolute	ADJ
eurjchem-1564	83	17	ethanol	ethanol	NOUN
eurjchem-1564	83	18	(	(	PUNCT
eurjchem-1564	83	19	15	15	NUM
eurjchem-1564	83	20	ml	ml	NOUN
eurjchem-1564	83	21	)	)	PUNCT
eurjchem-1564	83	22	solution	solution	NOUN
eurjchem-1564	83	23	of	of	ADP
eurjchem-1564	83	24	pdcl2(phcn)2	pdcl2(phcn)2	NOUN
eurjchem-1564	83	25	(	(	PUNCT
eurjchem-1564	83	26	0.383	0.383	NUM
eurjchem-1564	83	27	g	g	NOUN
eurjchem-1564	83	28	,	,	PUNCT
eurjchem-1564	83	29	1	1	NUM
eurjchem-1564	83	30	mmol	mmol	NOUN
eurjchem-1564	83	31	)	)	PUNCT
eurjchem-1564	83	32	was	be	AUX
eurjchem-1564	83	33	added	add	VERB
eurjchem-1564	83	34	n‐(2‐furfuraly	n‐(2‐furfuraly	PRON
eurjchem-1564	83	35	dine)benzene‐1,2‐diamine	dine)benzene‐1,2‐diamine	X
eurjchem-1564	83	36	(	(	PUNCT
eurjchem-1564	83	37	0.377	0.377	NUM
eurjchem-1564	83	38	g	g	NOUN
eurjchem-1564	83	39	,	,	PUNCT
eurjchem-1564	83	40	1	1	NUM
eurjchem-1564	83	41	mmol	mmol	NOUN
eurjchem-1564	83	42	)	)	PUNCT
eurjchem-1564	83	43	.	.	PUNCT
eurjchem-1564	84	1	the	the	DET
eurjchem-1564	84	2	mixture	mixture	NOUN
eurjchem-1564	84	3	was	be	AUX
eurjchem-1564	84	4	stirred	stir	VERB
eurjchem-1564	84	5	at	at	ADP
eurjchem-1564	84	6	room	room	NOUN
eurjchem-1564	84	7	temperature	temperature	NOUN
eurjchem-1564	84	8	for	for	ADP
eurjchem-1564	84	9	48	48	NUM
eurjchem-1564	84	10	h.	h.	NOUN
eurjchem-1564	84	11	a	a	DET
eurjchem-1564	84	12	dark	dark	ADJ
eurjchem-1564	84	13	brown	brown	ADJ
eurjchem-1564	84	14	participate	participate	NOUN
eurjchem-1564	84	15	was	be	AUX
eurjchem-1564	84	16	formed	form	VERB
eurjchem-1564	84	17	and	and	CCONJ
eurjchem-1564	84	18	was	be	AUX
eurjchem-1564	84	19	collected	collect	VERB
eurjchem-1564	84	20	by	by	ADP
eurjchem-1564	84	21	filtration	filtration	NOUN
eurjchem-1564	84	22	.	.	PUNCT
eurjchem-1564	85	1	the	the	DET
eurjchem-1564	85	2	solid	solid	ADJ
eurjchem-1564	85	3	product	product	NOUN
eurjchem-1564	85	4	was	be	AUX
eurjchem-1564	85	5	recrystallized	recrystallize	VERB
eurjchem-1564	85	6	by	by	ADP
eurjchem-1564	85	7	chloroform	chloroform	NOUN
eurjchem-1564	85	8	to	to	PART
eurjchem-1564	85	9	afford	afford	VERB
eurjchem-1564	85	10	the	the	DET
eurjchem-1564	85	11	complex	complex	ADJ
eurjchem-1564	85	12	3	3	NUM
eurjchem-1564	85	13	(	(	PUNCT
eurjchem-1564	85	14	scheme	scheme	NOUN
eurjchem-1564	85	15	3	3	NUM
eurjchem-1564	85	16	)	)	PUNCT
eurjchem-1564	85	17	.	.	PUNCT
eurjchem-1564	86	1	color	color	NOUN
eurjchem-1564	86	2	:	:	PUNCT
eurjchem-1564	86	3	dark	dark	PROPN
eurjchem-1564	86	4	brown	brown	PROPN
eurjchem-1564	86	5	.	.	PUNCT
eurjchem-1564	87	1	yield	yield	NOUN
eurjchem-1564	87	2	:	:	PUNCT
eurjchem-1564	87	3	60	60	NUM
eurjchem-1564	87	4	%	%	NOUN
eurjchem-1564	87	5	.	.	PUNCT
eurjchem-1564	88	1	m.p	m.p	PROPN
eurjchem-1564	88	2	.	.	PROPN
eurjchem-1564	88	3	:	:	PUNCT
eurjchem-1564	89	1	129‐131	129‐131	NUM
eurjchem-1564	89	2	°	°	ADP
eurjchem-1564	89	3	c	c	PROPN
eurjchem-1564	89	4	(	(	PUNCT
eurjchem-1564	89	5	dec	dec	PROPN
eurjchem-1564	89	6	.	.	PROPN
eurjchem-1564	89	7	)	)	PUNCT
eurjchem-1564	89	8	.	.	PUNCT
eurjchem-1564	90	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	90	2	(	(	PUNCT
eurjchem-1564	90	3	kbr	kbr	PROPN
eurjchem-1564	90	4	,	,	PUNCT
eurjchem-1564	90	5			PROPN
eurjchem-1564	90	6	,	,	PUNCT
eurjchem-1564	90	7	cm‐1	cm‐1	PROPN
eurjchem-1564	90	8	):	):	PUNCT
eurjchem-1564	90	9	3359	3359	NUM
eurjchem-1564	90	10	,	,	PUNCT
eurjchem-1564	90	11	3068	3068	NUM
eurjchem-1564	90	12	,	,	PUNCT
eurjchem-1564	90	13	2926	2926	NUM
eurjchem-1564	90	14	,	,	PUNCT
eurjchem-1564	90	15	2852	2852	NUM
eurjchem-1564	90	16	,	,	PUNCT
eurjchem-1564	90	17	1656	1656	NUM
eurjchem-1564	90	18	,	,	PUNCT
eurjchem-1564	90	19	1500	1500	NUM
eurjchem-1564	90	20	,	,	PUNCT
eurjchem-1564	90	21	1454	1454	NUM
eurjchem-1564	90	22	,	,	PUNCT
eurjchem-1564	90	23	1234	1234	NUM
eurjchem-1564	90	24	,	,	PUNCT
eurjchem-1564	90	25	746	746	NUM
eurjchem-1564	90	26	,	,	PUNCT
eurjchem-1564	90	27	673	673	NUM
eurjchem-1564	90	28	,	,	PUNCT
eurjchem-1564	90	29	602	602	NUM
eurjchem-1564	90	30	.	.	PUNCT
eurjchem-1564	91	1	1h	1h	NUM
eurjchem-1564	91	2	nmr	nmr	NOUN
eurjchem-1564	91	3	(	(	PUNCT
eurjchem-1564	91	4	300	300	NUM
eurjchem-1564	91	5	mhz	mhz	NOUN
eurjchem-1564	91	6	,	,	PUNCT
eurjchem-1564	91	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	91	8	,	,	PUNCT
eurjchem-1564	91	9	δ	δ	PROPN
eurjchem-1564	91	10	,	,	PUNCT
eurjchem-1564	91	11	ppm	ppm	NUM
eurjchem-1564	91	12	):	):	PUNCT
eurjchem-1564	91	13	6.38‐7.78	6.38‐7.78	PROPN
eurjchem-1564	91	14	(	(	PUNCT
eurjchem-1564	91	15	m	m	PROPN
eurjchem-1564	91	16	,	,	PUNCT
eurjchem-1564	91	17	7h	7h	PROPN
eurjchem-1564	91	18	,	,	PUNCT
eurjchem-1564	91	19	ar‐h	ar‐h	PROPN
eurjchem-1564	91	20	)	)	PUNCT
eurjchem-1564	91	21	,	,	PUNCT
eurjchem-1564	91	22	8.45	8.45	NUM
eurjchem-1564	91	23	(	(	PUNCT
eurjchem-1564	91	24	s	s	PROPN
eurjchem-1564	91	25	,	,	PUNCT
eurjchem-1564	91	26	1h	1h	NUM
eurjchem-1564	91	27	,	,	PUNCT
eurjchem-1564	91	28	ch	ch	NOUN
eurjchem-1564	91	29	=	=	NOUN
eurjchem-1564	91	30	n	n	CCONJ
eurjchem-1564	91	31	)	)	PUNCT
eurjchem-1564	91	32	,	,	PUNCT
eurjchem-1564	91	33	8.81	8.81	NUM
eurjchem-1564	91	34	(	(	PUNCT
eurjchem-1564	91	35	s	s	PROPN
eurjchem-1564	91	36	,	,	PUNCT
eurjchem-1564	91	37	2h	2h	NUM
eurjchem-1564	91	38	,	,	PUNCT
eurjchem-1564	91	39	nh2	nh2	PROPN
eurjchem-1564	91	40	)	)	PUNCT
eurjchem-1564	91	41	.	.	PUNCT
eurjchem-1564	92	1	anal	anal	PROPN
eurjchem-1564	92	2	.	.	PUNCT
eurjchem-1564	92	3	calcd	calcd	NOUN
eurjchem-1564	92	4	.	.	PUNCT
eurjchem-1564	93	1	for	for	ADP
eurjchem-1564	93	2	c11h10cl2n2opd	c11h10cl2n2opd	NOUN
eurjchem-1564	93	3	:	:	PUNCT
eurjchem-1564	93	4	c	c	X
eurjchem-1564	93	5	,	,	PUNCT
eurjchem-1564	93	6	36.34	36.34	NUM
eurjchem-1564	93	7	,	,	PUNCT
eurjchem-1564	93	8	h	h	NOUN
eurjchem-1564	93	9	,	,	PUNCT
eurjchem-1564	93	10	2.77	2.77	NUM
eurjchem-1564	93	11	;	;	PUNCT
eurjchem-1564	93	12	n	n	CCONJ
eurjchem-1564	93	13	,	,	PUNCT
eurjchem-1564	93	14	7.71	7.71	NUM
eurjchem-1564	93	15	.	.	PUNCT
eurjchem-1564	93	16	found	find	VERB
eurjchem-1564	93	17	:	:	PUNCT
eurjchem-1564	94	1	c	c	X
eurjchem-1564	94	2	,	,	PUNCT
eurjchem-1564	94	3	36.34	36.34	NUM
eurjchem-1564	94	4	;	;	PUNCT
eurjchem-1564	94	5	h	h	NOUN
eurjchem-1564	94	6	,	,	PUNCT
eurjchem-1564	94	7	2.50	2.50	NUM
eurjchem-1564	94	8	;	;	PUNCT
eurjchem-1564	94	9	n	n	CCONJ
eurjchem-1564	94	10	,	,	PUNCT
eurjchem-1564	94	11	7.73	7.73	NUM
eurjchem-1564	94	12	%	%	NOUN
eurjchem-1564	94	13	.	.	PUNCT
eurjchem-1564	95	1	λm	λm	X
eurjchem-1564	95	2	(	(	PUNCT
eurjchem-1564	95	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	95	4	):	):	PUNCT
eurjchem-1564	95	5	5.40	5.40	NUM
eurjchem-1564	95	6	.	.	PUNCT
eurjchem-1564	96	1	2.2.1.4	2.2.1.4	NUM
eurjchem-1564	96	2	.	.	PUNCT
eurjchem-1564	96	3	synthesis	synthesis	NOUN
eurjchem-1564	96	4	of	of	ADP
eurjchem-1564	96	5	dichloro[n	dichloro[n	PROPN
eurjchem-1564	96	6	,	,	PUNCT
eurjchem-1564	96	7	n'‐bis(2‐furanmethyledine	n'‐bis(2‐furanmethyledine	ADJ
eurjchem-1564	96	8	)	)	PUNCT
eurjchem-1564	96	9	benzene‐1,2‐diamine]palladium	benzene‐1,2‐diamine]palladium	PROPN
eurjchem-1564	96	10	(	(	PUNCT
eurjchem-1564	96	11	ii	ii	NOUN
eurjchem-1564	96	12	)	)	PUNCT
eurjchem-1564	96	13	(	(	PUNCT
eurjchem-1564	96	14	4	4	X
eurjchem-1564	96	15	)	)	PUNCT
eurjchem-1564	96	16	to	to	ADP
eurjchem-1564	96	17	an	an	DET
eurjchem-1564	96	18	absolute	absolute	ADJ
eurjchem-1564	96	19	ethanol	ethanol	NOUN
eurjchem-1564	96	20	solution	solution	NOUN
eurjchem-1564	96	21	of	of	ADP
eurjchem-1564	96	22	pdcl2(phcn)2	pdcl2(phcn)2	NOUN
eurjchem-1564	96	23	(	(	PUNCT
eurjchem-1564	96	24	0.383	0.383	NUM
eurjchem-1564	96	25	g	g	NOUN
eurjchem-1564	96	26	,	,	PUNCT
eurjchem-1564	96	27	1	1	NUM
eurjchem-1564	96	28	mmol	mmol	NOUN
eurjchem-1564	96	29	)	)	PUNCT
eurjchem-1564	96	30	was	be	AUX
eurjchem-1564	96	31	n	n	CCONJ
eurjchem-1564	96	32	,	,	PUNCT
eurjchem-1564	96	33	n'‐bis(2‐furfuralydine)benzene‐1	n'‐bis(2‐furfuralydine)benzene‐1	ADJ
eurjchem-1564	96	34	,	,	PUNCT
eurjchem-1564	96	35	2‐diamine	2‐diamine	NUM
eurjchem-1564	96	36	(	(	PUNCT
eurjchem-1564	96	37	0.455	0.455	NUM
eurjchem-1564	96	38	g	g	NOUN
eurjchem-1564	96	39	,	,	PUNCT
eurjchem-1564	96	40	1	1	NUM
eurjchem-1564	96	41	mmol	mmol	NOUN
eurjchem-1564	96	42	)	)	PUNCT
eurjchem-1564	96	43	.	.	PUNCT
eurjchem-1564	97	1	the	the	DET
eurjchem-1564	97	2	mixture	mixture	NOUN
eurjchem-1564	97	3	was	be	AUX
eurjchem-1564	97	4	stirred	stir	VERB
eurjchem-1564	97	5	at	at	ADP
eurjchem-1564	97	6	room	room	NOUN
eurjchem-1564	97	7	tempe‐	tempe‐	PUNCT
eurjchem-1564	98	1	rature	rature	NOUN
eurjchem-1564	98	2	for	for	ADP
eurjchem-1564	98	3	48	48	NUM
eurjchem-1564	98	4	h.	h.	NOUN
eurjchem-1564	98	5	a	a	DET
eurjchem-1564	98	6	brown	brown	ADJ
eurjchem-1564	98	7	participate	participate	NOUN
eurjchem-1564	98	8	was	be	AUX
eurjchem-1564	98	9	formed	form	VERB
eurjchem-1564	98	10	and	and	CCONJ
eurjchem-1564	98	11	was	be	AUX
eurjchem-1564	98	12	collected	collect	VERB
eurjchem-1564	98	13	by	by	ADP
eurjchem-1564	98	14	filtration	filtration	NOUN
eurjchem-1564	98	15	.	.	PUNCT
eurjchem-1564	99	1	the	the	DET
eurjchem-1564	99	2	solid	solid	ADJ
eurjchem-1564	99	3	was	be	AUX
eurjchem-1564	99	4	then	then	ADV
eurjchem-1564	99	5	recrystallized	recrystallize	VERB
eurjchem-1564	99	6	from	from	ADP
eurjchem-1564	99	7	chloroform	chloroform	NOUN
eurjchem-1564	99	8	to	to	PART
eurjchem-1564	99	9	afford	afford	VERB
eurjchem-1564	99	10	complex	complex	ADJ
eurjchem-1564	99	11	4	4	NUM
eurjchem-1564	99	12	(	(	PUNCT
eurjchem-1564	99	13	scheme	scheme	NOUN
eurjchem-1564	99	14	4	4	NUM
eurjchem-1564	99	15	)	)	PUNCT
eurjchem-1564	99	16	.	.	PUNCT
eurjchem-1564	100	1	color	color	NOUN
eurjchem-1564	100	2	:	:	PUNCT
eurjchem-1564	100	3	brown	brown	ADJ
eurjchem-1564	100	4	solid	solid	ADJ
eurjchem-1564	100	5	.	.	PUNCT
eurjchem-1564	101	1	yield	yield	NOUN
eurjchem-1564	101	2	:	:	PUNCT
eurjchem-1564	101	3	69	69	NUM
eurjchem-1564	101	4	%	%	NOUN
eurjchem-1564	101	5	.	.	PUNCT
eurjchem-1564	102	1	m.p	m.p	PROPN
eurjchem-1564	102	2	.	.	PROPN
eurjchem-1564	102	3	:	:	PUNCT
eurjchem-1564	103	1	168‐179	168‐179	PROPN
eurjchem-1564	103	2	°	°	PROPN
eurjchem-1564	103	3	c	c	PROPN
eurjchem-1564	103	4	(	(	PUNCT
eurjchem-1564	103	5	dec	dec	PROPN
eurjchem-1564	103	6	.	.	PROPN
eurjchem-1564	103	7	)	)	PUNCT
eurjchem-1564	103	8	.	.	PUNCT
eurjchem-1564	104	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	104	2	(	(	PUNCT
eurjchem-1564	104	3	kbr	kbr	PROPN
eurjchem-1564	104	4	,	,	PUNCT
eurjchem-1564	104	5			PROPN
eurjchem-1564	104	6	,	,	PUNCT
eurjchem-1564	104	7	cm‐1	cm‐1	PROPN
eurjchem-1564	104	8	):	):	PUNCT
eurjchem-1564	104	9	3022	3022	NUM
eurjchem-1564	104	10	,	,	PUNCT
eurjchem-1564	104	11	2926	2926	NUM
eurjchem-1564	104	12	,	,	PUNCT
eurjchem-1564	104	13	2862	2862	NUM
eurjchem-1564	104	14	,	,	PUNCT
eurjchem-1564	104	15	1610	1610	NUM
eurjchem-1564	104	16	,	,	PUNCT
eurjchem-1564	104	17	1510	1510	NUM
eurjchem-1564	104	18	,	,	PUNCT
eurjchem-1564	104	19	1462	1462	NUM
eurjchem-1564	104	20	,	,	PUNCT
eurjchem-1564	104	21	1226	1226	NUM
eurjchem-1564	104	22	,	,	PUNCT
eurjchem-1564	104	23	748	748	NUM
eurjchem-1564	104	24	,	,	PUNCT
eurjchem-1564	104	25	666	666	NUM
eurjchem-1564	104	26	,	,	PUNCT
eurjchem-1564	104	27	602	602	NUM
eurjchem-1564	104	28	.	.	PUNCT
eurjchem-1564	105	1	1h	1h	NUM
eurjchem-1564	105	2	nmr	nmr	NOUN
eurjchem-1564	105	3	(	(	PUNCT
eurjchem-1564	105	4	300	300	NUM
eurjchem-1564	105	5	mhz	mhz	NOUN
eurjchem-1564	105	6	,	,	PUNCT
eurjchem-1564	105	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	105	8	,	,	PUNCT
eurjchem-1564	105	9	δ	δ	PROPN
eurjchem-1564	105	10	,	,	PUNCT
eurjchem-1564	105	11	ppm	ppm	NUM
eurjchem-1564	105	12	):	):	PUNCT
eurjchem-1564	105	13	6.38‐8.02	6.38‐8.02	NUM
eurjchem-1564	105	14	(	(	PUNCT
eurjchem-1564	105	15	m	m	PROPN
eurjchem-1564	105	16	,	,	PUNCT
eurjchem-1564	105	17	10h	10h	NUM
eurjchem-1564	105	18	,	,	PUNCT
eurjchem-1564	105	19	ar‐h	ar‐h	PROPN
eurjchem-1564	105	20	)	)	PUNCT
eurjchem-1564	105	21	,	,	PUNCT
eurjchem-1564	105	22	8.66	8.66	NUM
eurjchem-1564	105	23	(	(	PUNCT
eurjchem-1564	105	24	s	s	PROPN
eurjchem-1564	105	25	,	,	PUNCT
eurjchem-1564	105	26	2h	2h	NUM
eurjchem-1564	105	27	,	,	PUNCT
eurjchem-1564	105	28	2ch	2ch	ADJ
eurjchem-1564	105	29	=	=	NOUN
eurjchem-1564	105	30	n	n	NUM
eurjchem-1564	105	31	)	)	PUNCT
eurjchem-1564	105	32	.	.	PUNCT
eurjchem-1564	106	1	anal	anal	PROPN
eurjchem-1564	106	2	.	.	PUNCT
eurjchem-1564	106	3	calcd	calcd	NOUN
eurjchem-1564	106	4	.	.	PUNCT
eurjchem-1564	107	1	for	for	ADP
eurjchem-1564	107	2	c16h12cl2n2o2pd	c16h12cl2n2o2pd	PROPN
eurjchem-1564	107	3	:	:	PUNCT
eurjchem-1564	107	4	c	c	X
eurjchem-1564	107	5	,	,	PUNCT
eurjchem-1564	107	6	43.52	43.52	NUM
eurjchem-1564	107	7	;	;	PUNCT
eurjchem-1564	107	8	h	h	NOUN
eurjchem-1564	107	9	,	,	PUNCT
eurjchem-1564	107	10	2.74	2.74	NUM
eurjchem-1564	107	11	;	;	PUNCT
eurjchem-1564	107	12	n	n	CCONJ
eurjchem-1564	107	13	,	,	PUNCT
eurjchem-1564	107	14	6.34	6.34	NUM
eurjchem-1564	107	15	.	.	PUNCT
eurjchem-1564	107	16	found	find	VERB
eurjchem-1564	107	17	:	:	PUNCT
eurjchem-1564	108	1	c	c	X
eurjchem-1564	108	2	,	,	PUNCT
eurjchem-1564	108	3	43.53	43.53	NUM
eurjchem-1564	108	4	;	;	PUNCT
eurjchem-1564	108	5	h	h	NOUN
eurjchem-1564	108	6	,	,	PUNCT
eurjchem-1564	108	7	2.78	2.78	NUM
eurjchem-1564	108	8	;	;	PUNCT
eurjchem-1564	108	9	n	n	CCONJ
eurjchem-1564	108	10	,	,	PUNCT
eurjchem-1564	108	11	6.49	6.49	NUM
eurjchem-1564	108	12	%	%	NOUN
eurjchem-1564	108	13	.	.	PUNCT
eurjchem-1564	109	1	λm	λm	X
eurjchem-1564	109	2	(	(	PUNCT
eurjchem-1564	109	3	ohm‐	ohm‐	NOUN
eurjchem-1564	109	4	1.cm2.mol‐1	1.cm2.mol‐1	NUM
eurjchem-1564	109	5	):	):	PUNCT
eurjchem-1564	109	6	5.00	5.00	NUM
eurjchem-1564	109	7	.	.	PUNCT
eurjchem-1564	110	1	2.2.1.5	2.2.1.5	NUM
eurjchem-1564	110	2	.	.	X
eurjchem-1564	111	1	synthesis	synthesis	NOUN
eurjchem-1564	111	2	of	of	ADP
eurjchem-1564	111	3	dichloro[n‐(ferrocenmethyledine	dichloro[n‐(ferrocenmethyledine	NOUN
eurjchem-1564	111	4	)	)	PUNCT
eurjchem-1564	111	5	benzene‐1,2‐diamine]palladium(ii	benzene‐1,2‐diamine]palladium(ii	NOUN
eurjchem-1564	111	6	)	)	PUNCT
eurjchem-1564	111	7	(	(	PUNCT
eurjchem-1564	111	8	5	5	X
eurjchem-1564	111	9	)	)	PUNCT
eurjchem-1564	111	10	a	a	DET
eurjchem-1564	111	11	filtered	filter	VERB
eurjchem-1564	111	12	n‐(ferrocenylidene)benzene‐1,2‐diamine	n‐(ferrocenylidene)benzene‐1,2‐diamine	PUNCT
eurjchem-1564	111	13	(	(	PUNCT
eurjchem-1564	111	14	0.524	0.524	NUM
eurjchem-1564	111	15	g	g	NOUN
eurjchem-1564	111	16	,	,	PUNCT
eurjchem-1564	111	17	1	1	NUM
eurjchem-1564	111	18	mmol	mmol	NOUN
eurjchem-1564	111	19	)	)	PUNCT
eurjchem-1564	111	20	dissolved	dissolve	VERB
eurjchem-1564	111	21	into	into	ADP
eurjchem-1564	111	22	absolute	absolute	ADJ
eurjchem-1564	111	23	ethanol	ethanol	NOUN
eurjchem-1564	111	24	(	(	PUNCT
eurjchem-1564	111	25	20	20	NUM
eurjchem-1564	111	26	ml	ml	NOUN
eurjchem-1564	111	27	)	)	PUNCT
eurjchem-1564	111	28	was	be	AUX
eurjchem-1564	111	29	conti‐	conti‐	NOUN
eurjchem-1564	111	30	nuously	nuously	ADV
eurjchem-1564	111	31	added	add	VERB
eurjchem-1564	111	32	to	to	ADP
eurjchem-1564	111	33	a	a	DET
eurjchem-1564	111	34	dissolved‐pdcl2(phcn)2	dissolved‐pdcl2(phcn)2	NOUN
eurjchem-1564	111	35	(	(	PUNCT
eurjchem-1564	111	36	0.383	0.383	NUM
eurjchem-1564	111	37	g	g	NOUN
eurjchem-1564	111	38	,	,	PUNCT
eurjchem-1564	111	39	1	1	NUM
eurjchem-1564	111	40	mmol	mmol	NOUN
eurjchem-1564	111	41	)	)	PUNCT
eurjchem-1564	111	42	in	in	ADP
eurjchem-1564	111	43	absolute	absolute	ADJ
eurjchem-1564	111	44	ethanol	ethanol	NOUN
eurjchem-1564	111	45	(	(	PUNCT
eurjchem-1564	111	46	15	15	NUM
eurjchem-1564	111	47	ml	ml	NOUN
eurjchem-1564	111	48	)	)	PUNCT
eurjchem-1564	111	49	in	in	ADP
eurjchem-1564	111	50	stirring	stir	VERB
eurjchem-1564	111	51	condition	condition	NOUN
eurjchem-1564	111	52	.	.	PUNCT
eurjchem-1564	112	1	after	after	ADP
eurjchem-1564	112	2	48	48	NUM
eurjchem-1564	112	3	h	h	NOUN
eurjchem-1564	112	4	stirring	stir	VERB
eurjchem-1564	112	5	at	at	ADP
eurjchem-1564	112	6	room	room	NOUN
eurjchem-1564	112	7	temperature	temperature	NOUN
eurjchem-1564	112	8	,	,	PUNCT
eurjchem-1564	112	9	a	a	DET
eurjchem-1564	112	10	brown	brown	ADJ
eurjchem-1564	112	11	solid	solid	NOUN
eurjchem-1564	112	12	was	be	AUX
eurjchem-1564	112	13	formed	form	VERB
eurjchem-1564	112	14	.	.	PUNCT
eurjchem-1564	113	1	the	the	DET
eurjchem-1564	113	2	solid	solid	ADJ
eurjchem-1564	113	3	product	product	NOUN
eurjchem-1564	113	4	was	be	AUX
eurjchem-1564	113	5	purified	purify	VERB
eurjchem-1564	113	6	by	by	ADP
eurjchem-1564	113	7	extraction	extraction	NOUN
eurjchem-1564	113	8	with	with	ADP
eurjchem-1564	113	9	diethyl	diethyl	NOUN
eurjchem-1564	113	10	ether	ether	NOUN
eurjchem-1564	113	11	(	(	PUNCT
eurjchem-1564	113	12	5×4	5×4	PROPN
eurjchem-1564	113	13	ml	ml	NOUN
eurjchem-1564	113	14	)	)	PUNCT
eurjchem-1564	113	15	,	,	PUNCT
eurjchem-1564	113	16	and	and	CCONJ
eurjchem-1564	113	17	then	then	ADV
eurjchem-1564	113	18	dried	dry	VERB
eurjchem-1564	113	19	in	in	ADP
eurjchem-1564	113	20	vacuum	vacuum	NOUN
eurjchem-1564	113	21	(	(	PUNCT
eurjchem-1564	113	22	scheme	scheme	NOUN
eurjchem-1564	113	23	3	3	NUM
eurjchem-1564	113	24	)	)	PUNCT
eurjchem-1564	113	25	.	.	PUNCT
eurjchem-1564	114	1	color	color	NOUN
eurjchem-1564	114	2	:	:	PUNCT
eurjchem-1564	114	3	orange	orange	ADJ
eurjchem-1564	114	4	.	.	PUNCT
eurjchem-1564	115	1	yield	yield	NOUN
eurjchem-1564	115	2	:	:	PUNCT
eurjchem-1564	115	3	67	67	NUM
eurjchem-1564	115	4	%	%	NOUN
eurjchem-1564	115	5	.	.	PUNCT
eurjchem-1564	116	1	m.p	m.p	PROPN
eurjchem-1564	116	2	.	.	PROPN
eurjchem-1564	116	3	:	:	PUNCT
eurjchem-1564	117	1	115‐117	115‐117	NUM
eurjchem-1564	117	2	°	°	ADP
eurjchem-1564	117	3	c	c	PROPN
eurjchem-1564	117	4	(	(	PUNCT
eurjchem-1564	117	5	dec	dec	PROPN
eurjchem-1564	117	6	.	.	PROPN
eurjchem-1564	117	7	)	)	PUNCT
eurjchem-1564	117	8	.	.	PUNCT
eurjchem-1564	118	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	118	2	(	(	PUNCT
eurjchem-1564	118	3	kbr	kbr	PROPN
eurjchem-1564	118	4	,	,	PUNCT
eurjchem-1564	118	5			PROPN
eurjchem-1564	118	6	,	,	PUNCT
eurjchem-1564	118	7	cm‐1	cm‐1	PROPN
eurjchem-1564	118	8	):	):	PUNCT
eurjchem-1564	118	9	3350	3350	NUM
eurjchem-1564	118	10	,	,	PUNCT
eurjchem-1564	118	11	3030	3030	NUM
eurjchem-1564	118	12	,	,	PUNCT
eurjchem-1564	118	13	2930	2930	NUM
eurjchem-1564	118	14	,	,	PUNCT
eurjchem-1564	118	15	2853	2853	NUM
eurjchem-1564	118	16	,	,	PUNCT
eurjchem-1564	118	17	1656	1656	NUM
eurjchem-1564	118	18	,	,	PUNCT
eurjchem-1564	118	19	1566	1566	NUM
eurjchem-1564	118	20	,	,	PUNCT
eurjchem-1564	118	21	1462	1462	NUM
eurjchem-1564	118	22	,	,	PUNCT
eurjchem-1564	118	23	1274	1274	NUM
eurjchem-1564	118	24	,	,	PUNCT
eurjchem-1564	118	25	746	746	NUM
eurjchem-1564	118	26	,	,	PUNCT
eurjchem-1564	118	27	666	666	NUM
eurjchem-1564	118	28	,	,	PUNCT
eurjchem-1564	118	29	613	613	NUM
eurjchem-1564	118	30	.	.	PUNCT
eurjchem-1564	118	31	anal	anal	PROPN
eurjchem-1564	118	32	.	.	PUNCT
eurjchem-1564	118	33	calcd	calcd	NOUN
eurjchem-1564	118	34	.	.	PUNCT
eurjchem-1564	119	1	for	for	SCONJ
eurjchem-1564	119	2	c17h16cl2n2fepd	c17h16cl2n2fepd	PROPN
eurjchem-1564	119	3	:	:	PUNCT
eurjchem-1564	119	4	c	c	X
eurjchem-1564	119	5	,	,	PUNCT
eurjchem-1564	119	6	42.41	42.41	NUM
eurjchem-1564	119	7	;	;	PUNCT
eurjchem-1564	119	8	h	h	NOUN
eurjchem-1564	119	9	,	,	PUNCT
eurjchem-1564	119	10	3.35	3.35	NUM
eurjchem-1564	119	11	;	;	PUNCT
eurjchem-1564	119	12	n	n	CCONJ
eurjchem-1564	119	13	,	,	PUNCT
eurjchem-1564	119	14	5.82	5.82	NUM
eurjchem-1564	119	15	.	.	PUNCT
eurjchem-1564	119	16	found	find	VERB
eurjchem-1564	119	17	:	:	PUNCT
eurjchem-1564	120	1	c	c	X
eurjchem-1564	120	2	,	,	PUNCT
eurjchem-1564	120	3	42.41	42.41	NUM
eurjchem-1564	120	4	;	;	PUNCT
eurjchem-1564	120	5	h	h	NOUN
eurjchem-1564	120	6	,	,	PUNCT
eurjchem-1564	120	7	3.39	3.39	NUM
eurjchem-1564	120	8	;	;	PUNCT
eurjchem-1564	120	9	n	n	CCONJ
eurjchem-1564	120	10	,	,	PUNCT
eurjchem-1564	120	11	5.89	5.89	NUM
eurjchem-1564	120	12	%	%	NOUN
eurjchem-1564	120	13	.	.	PUNCT
eurjchem-1564	121	1	1h	1h	NUM
eurjchem-1564	121	2	nmr	nmr	NOUN
eurjchem-1564	121	3	(	(	PUNCT
eurjchem-1564	121	4	300	300	NUM
eurjchem-1564	121	5	mhz	mhz	NOUN
eurjchem-1564	121	6	,	,	PUNCT
eurjchem-1564	121	7	dmso‐	dmso‐	NUM
eurjchem-1564	121	8	d6	d6	NOUN
eurjchem-1564	121	9	,	,	PUNCT
eurjchem-1564	121	10	δ	δ	PROPN
eurjchem-1564	121	11	,	,	PUNCT
eurjchem-1564	121	12	ppm	ppm	NUM
eurjchem-1564	121	13	):	):	PUNCT
eurjchem-1564	121	14	4.20	4.20	NUM
eurjchem-1564	121	15	(	(	PUNCT
eurjchem-1564	121	16	s	s	PROPN
eurjchem-1564	121	17	,	,	PUNCT
eurjchem-1564	121	18	5h	5h	NUM
eurjchem-1564	121	19	,	,	PUNCT
eurjchem-1564	121	20	c5h5	c5h5	NOUN
eurjchem-1564	121	21	)	)	PUNCT
eurjchem-1564	121	22	,	,	PUNCT
eurjchem-1564	121	23	4.28	4.28	NUM
eurjchem-1564	121	24	(	(	PUNCT
eurjchem-1564	121	25	d	d	PROPN
eurjchem-1564	121	26	,	,	PUNCT
eurjchem-1564	121	27	2h	2h	NUM
eurjchem-1564	121	28	,	,	PUNCT
eurjchem-1564	121	29	h2	h2	NOUN
eurjchem-1564	121	30	and	and	CCONJ
eurjchem-1564	121	31	h5	h5	PROPN
eurjchem-1564	121	32	)	)	PUNCT
eurjchem-1564	121	33	,	,	PUNCT
eurjchem-1564	121	34	4.35	4.35	NUM
eurjchem-1564	121	35	(	(	PUNCT
eurjchem-1564	121	36	d	d	PROPN
eurjchem-1564	121	37	,	,	PUNCT
eurjchem-1564	121	38	2h	2h	NUM
eurjchem-1564	121	39	,	,	PUNCT
eurjchem-1564	121	40	h3	h3	NOUN
eurjchem-1564	121	41	and	and	CCONJ
eurjchem-1564	121	42	h4	h4	NOUN
eurjchem-1564	121	43	)	)	PUNCT
eurjchem-1564	121	44	,	,	PUNCT
eurjchem-1564	121	45	6.15‐7.96	6.15‐7.96	NUM
eurjchem-1564	121	46	(	(	PUNCT
eurjchem-1564	121	47	m	m	PROPN
eurjchem-1564	121	48	,	,	PUNCT
eurjchem-1564	121	49	4h	4h	NOUN
eurjchem-1564	121	50	,	,	PUNCT
eurjchem-1564	121	51	ar‐h	ar‐h	PROPN
eurjchem-1564	121	52	)	)	PUNCT
eurjchem-1564	121	53	,	,	PUNCT
eurjchem-1564	121	54	8.45	8.45	NUM
eurjchem-1564	121	55	(	(	PUNCT
eurjchem-1564	121	56	s	s	PROPN
eurjchem-1564	121	57	,	,	PUNCT
eurjchem-1564	121	58	1h	1h	NUM
eurjchem-1564	121	59	,	,	PUNCT
eurjchem-1564	121	60	ch	ch	NOUN
eurjchem-1564	121	61	=	=	NOUN
eurjchem-1564	121	62	n	n	CCONJ
eurjchem-1564	121	63	)	)	PUNCT
eurjchem-1564	121	64	,	,	PUNCT
eurjchem-1564	121	65	9.09	9.09	NUM
eurjchem-1564	121	66	(	(	PUNCT
eurjchem-1564	121	67	s	s	PROPN
eurjchem-1564	121	68	,	,	PUNCT
eurjchem-1564	121	69	2h	2h	NUM
eurjchem-1564	121	70	,	,	PUNCT
eurjchem-1564	121	71	nh2	nh2	PROPN
eurjchem-1564	121	72	)	)	PUNCT
eurjchem-1564	121	73	.	.	PUNCT
eurjchem-1564	122	1	λm	λm	X
eurjchem-1564	122	2	(	(	PUNCT
eurjchem-1564	122	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	122	4	):	):	PUNCT
eurjchem-1564	122	5	7.45	7.45	NUM
eurjchem-1564	122	6	2.2.1.6	2.2.1.6	NUM
eurjchem-1564	122	7	.	.	PUNCT
eurjchem-1564	123	1	synthesis	synthesis	NOUN
eurjchem-1564	123	2	of	of	ADP
eurjchem-1564	123	3	dichloro[n	dichloro[n	PROPN
eurjchem-1564	123	4	,	,	PUNCT
eurjchem-1564	123	5	n'‐bis(ferrocenmethyledine	n'‐bis(ferrocenmethyledine	PROPN
eurjchem-1564	123	6	)	)	PUNCT
eurjchem-1564	123	7	benzene‐1,2‐diamine	benzene‐1,2‐diamine	NOUN
eurjchem-1564	123	8	]	]	PUNCT
eurjchem-1564	123	9	palladium(ii	palladium(ii	NOUN
eurjchem-1564	123	10	)	)	PUNCT
eurjchem-1564	123	11	(	(	PUNCT
eurjchem-1564	123	12	6	6	NUM
eurjchem-1564	123	13	)	)	PUNCT
eurjchem-1564	123	14	a	a	DET
eurjchem-1564	123	15	filtered	filter	VERB
eurjchem-1564	123	16	n	n	CCONJ
eurjchem-1564	123	17	,	,	PUNCT
eurjchem-1564	123	18	n'‐bis(ferrocenmethyledine)benzene‐1	n'‐bis(ferrocenmethyledine)benzene‐1	PROPN
eurjchem-1564	123	19	,	,	PUNCT
eurjchem-1564	123	20	2‐	2‐	NUM
eurjchem-1564	123	21	diamine	diamine	NOUN
eurjchem-1564	123	22	(	(	PUNCT
eurjchem-1564	123	23	0.749	0.749	NUM
eurjchem-1564	123	24	g	g	NOUN
eurjchem-1564	123	25	,	,	PUNCT
eurjchem-1564	123	26	1	1	NUM
eurjchem-1564	123	27	mmol	mmol	NOUN
eurjchem-1564	123	28	)	)	PUNCT
eurjchem-1564	123	29	dissolved	dissolve	VERB
eurjchem-1564	123	30	in	in	ADP
eurjchem-1564	123	31	absolute	absolute	ADJ
eurjchem-1564	123	32	ethanol	ethanol	NOUN
eurjchem-1564	123	33	(	(	PUNCT
eurjchem-1564	123	34	20	20	NUM
eurjchem-1564	123	35	ml	ml	NOUN
eurjchem-1564	123	36	)	)	PUNCT
eurjchem-1564	123	37	was	be	AUX
eurjchem-1564	123	38	continuously	continuously	ADV
eurjchem-1564	123	39	added	add	VERB
eurjchem-1564	123	40	to	to	ADP
eurjchem-1564	123	41	pdcl2(phcn)2	pdcl2(phcn)2	NOUN
eurjchem-1564	123	42	(	(	PUNCT
eurjchem-1564	123	43	0.383	0.383	NUM
eurjchem-1564	123	44	g	g	NOUN
eurjchem-1564	123	45	,	,	PUNCT
eurjchem-1564	123	46	1	1	NUM
eurjchem-1564	123	47	mmol	mmol	NOUN
eurjchem-1564	123	48	)	)	PUNCT
eurjchem-1564	123	49	in	in	ADP
eurjchem-1564	123	50	absolute	absolute	ADJ
eurjchem-1564	123	51	ethanol	ethanol	NOUN
eurjchem-1564	123	52	(	(	PUNCT
eurjchem-1564	123	53	15	15	NUM
eurjchem-1564	123	54	ml	ml	NOUN
eurjchem-1564	123	55	)	)	PUNCT
eurjchem-1564	123	56	in	in	ADP
eurjchem-1564	123	57	stirring	stir	VERB
eurjchem-1564	123	58	condition	condition	NOUN
eurjchem-1564	123	59	during	during	ADP
eurjchem-1564	123	60	48	48	NUM
eurjchem-1564	123	61	h	h	NOUN
eurjchem-1564	123	62	at	at	ADP
eurjchem-1564	123	63	room	room	NOUN
eurjchem-1564	123	64	temperature	temperature	NOUN
eurjchem-1564	123	65	.	.	PUNCT
eurjchem-1564	124	1	as	as	ADP
eurjchem-1564	124	2	result	result	NOUN
eurjchem-1564	124	3	,	,	PUNCT
eurjchem-1564	124	4	the	the	DET
eurjchem-1564	124	5	orange	orange	PROPN
eurjchem-1564	124	6	solid	solid	PROPN
eurjchem-1564	124	7	was	be	AUX
eurjchem-1564	124	8	formed	form	VERB
eurjchem-1564	124	9	.	.	PUNCT
eurjchem-1564	125	1	the	the	DET
eurjchem-1564	125	2	solid	solid	ADJ
eurjchem-1564	125	3	product	product	NOUN
eurjchem-1564	125	4	was	be	AUX
eurjchem-1564	125	5	purified	purify	VERB
eurjchem-1564	125	6	by	by	ADP
eurjchem-1564	125	7	extraction	extraction	NOUN
eurjchem-1564	125	8	with	with	ADP
eurjchem-1564	125	9	diethyl	diethyl	NOUN
eurjchem-1564	125	10	ether	ether	NOUN
eurjchem-1564	125	11	(	(	PUNCT
eurjchem-1564	125	12	5×4	5×4	PROPN
eurjchem-1564	125	13	ml	ml	NOUN
eurjchem-1564	125	14	)	)	PUNCT
eurjchem-1564	125	15	,	,	PUNCT
eurjchem-1564	125	16	and	and	CCONJ
eurjchem-1564	125	17	then	then	ADV
eurjchem-1564	125	18	dried	dry	VERB
eurjchem-1564	125	19	in	in	ADP
eurjchem-1564	125	20	vacuum	vacuum	NOUN
eurjchem-1564	125	21	(	(	PUNCT
eurjchem-1564	125	22	scheme	scheme	NOUN
eurjchem-1564	125	23	4	4	NUM
eurjchem-1564	125	24	)	)	PUNCT
eurjchem-1564	125	25	.	.	PUNCT
eurjchem-1564	126	1	color	color	NOUN
eurjchem-1564	126	2	:	:	PUNCT
eurjchem-1564	126	3	orange	orange	ADJ
eurjchem-1564	126	4	.	.	PUNCT
eurjchem-1564	127	1	yield	yield	NOUN
eurjchem-1564	127	2	:	:	PUNCT
eurjchem-1564	127	3	72	72	NUM
eurjchem-1564	127	4	%	%	NOUN
eurjchem-1564	127	5	.	.	PUNCT
eurjchem-1564	128	1	m.p	m.p	PROPN
eurjchem-1564	128	2	.	.	PROPN
eurjchem-1564	128	3	:	:	PUNCT
eurjchem-1564	129	1	117‐119	117‐119	NUM
eurjchem-1564	129	2	°	°	ADP
eurjchem-1564	129	3	c	c	NOUN
eurjchem-1564	129	4	(	(	PUNCT
eurjchem-1564	129	5	dec	dec	PROPN
eurjchem-1564	129	6	.	.	PROPN
eurjchem-1564	129	7	)	)	PUNCT
eurjchem-1564	129	8	.	.	PUNCT
eurjchem-1564	130	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	130	2	(	(	PUNCT
eurjchem-1564	130	3	kbr	kbr	PROPN
eurjchem-1564	130	4	,	,	PUNCT
eurjchem-1564	130	5			PROPN
eurjchem-1564	130	6	,	,	PUNCT
eurjchem-1564	130	7	cm‐1	cm‐1	PROPN
eurjchem-1564	130	8	):	):	PUNCT
eurjchem-1564	130	9	3066	3066	NUM
eurjchem-1564	130	10	,	,	PUNCT
eurjchem-1564	130	11	2924	2924	NUM
eurjchem-1564	130	12	,	,	PUNCT
eurjchem-1564	130	13	2852	2852	NUM
eurjchem-1564	130	14	,	,	PUNCT
eurjchem-1564	130	15	1653	1653	NUM
eurjchem-1564	130	16	,	,	PUNCT
eurjchem-1564	130	17	1493	1493	NUM
eurjchem-1564	130	18	,	,	PUNCT
eurjchem-1564	130	19	1466	1466	NUM
eurjchem-1564	130	20	,	,	PUNCT
eurjchem-1564	130	21	1266	1266	NUM
eurjchem-1564	130	22	,	,	PUNCT
eurjchem-1564	130	23	772	772	NUM
eurjchem-1564	130	24	,	,	PUNCT
eurjchem-1564	130	25	746	746	NUM
eurjchem-1564	130	26	,	,	PUNCT
eurjchem-1564	130	27	666	666	NUM
eurjchem-1564	130	28	.	.	NOUN
eurjchem-1564	130	29	158	158	NUM
eurjchem-1564	130	30	al‐fregi	al‐fregi	NOUN
eurjchem-1564	130	31	et	et	VERB
eurjchem-1564	130	32	al	al	PROPN
eurjchem-1564	130	33	.	.	PUNCT
eurjchem-1564	130	34	/	/	SYM
eurjchem-1564	130	35	european	european	PROPN
eurjchem-1564	130	36	journal	journal	PROPN
eurjchem-1564	130	37	of	of	ADP
eurjchem-1564	130	38	chemistry	chemistry	NOUN
eurjchem-1564	130	39	8	8	NUM
eurjchem-1564	130	40	(	(	PUNCT
eurjchem-1564	130	41	2	2	NUM
eurjchem-1564	130	42	)	)	PUNCT
eurjchem-1564	130	43	(	(	PUNCT
eurjchem-1564	130	44	2017	2017	NUM
eurjchem-1564	130	45	)	)	PUNCT
eurjchem-1564	130	46	155‐161	155‐161	NUM
eurjchem-1564	130	47	scheme	scheme	NOUN
eurjchem-1564	130	48	4	4	NUM
eurjchem-1564	130	49	1h	1h	NUM
eurjchem-1564	130	50	nmr	nmr	NOUN
eurjchem-1564	130	51	(	(	PUNCT
eurjchem-1564	130	52	300	300	NUM
eurjchem-1564	130	53	mhz	mhz	NOUN
eurjchem-1564	130	54	,	,	PUNCT
eurjchem-1564	130	55	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	130	56	,	,	PUNCT
eurjchem-1564	130	57	δ	δ	PROPN
eurjchem-1564	130	58	,	,	PUNCT
eurjchem-1564	130	59	ppm	ppm	NOUN
eurjchem-1564	130	60	):	):	PUNCT
eurjchem-1564	130	61	4.16	4.16	NUM
eurjchem-1564	130	62	(	(	PUNCT
eurjchem-1564	130	63	s	s	PROPN
eurjchem-1564	130	64	,	,	PUNCT
eurjchem-1564	130	65	10h	10h	NUM
eurjchem-1564	130	66	,	,	PUNCT
eurjchem-1564	130	67	2×c5h5	2×c5h5	NUM
eurjchem-1564	130	68	)	)	PUNCT
eurjchem-1564	130	69	,	,	PUNCT
eurjchem-1564	130	70	4.35	4.35	NUM
eurjchem-1564	130	71	(	(	PUNCT
eurjchem-1564	130	72	d	d	PROPN
eurjchem-1564	130	73	,	,	PUNCT
eurjchem-1564	130	74	4h	4h	NUM
eurjchem-1564	130	75	,	,	PUNCT
eurjchem-1564	130	76	2h2	2h2	NUM
eurjchem-1564	130	77	and	and	CCONJ
eurjchem-1564	130	78	2h5	2h5	NUM
eurjchem-1564	130	79	)	)	PUNCT
eurjchem-1564	130	80	,	,	PUNCT
eurjchem-1564	130	81	4.85	4.85	NUM
eurjchem-1564	130	82	(	(	PUNCT
eurjchem-1564	130	83	d	d	PROPN
eurjchem-1564	130	84	,	,	PUNCT
eurjchem-1564	130	85	4h	4h	NUM
eurjchem-1564	130	86	,	,	PUNCT
eurjchem-1564	130	87	2h3	2h3	NUM
eurjchem-1564	130	88	and	and	CCONJ
eurjchem-1564	130	89	2h4	2h4	NUM
eurjchem-1564	130	90	)	)	PUNCT
eurjchem-1564	130	91	,	,	PUNCT
eurjchem-1564	130	92	6.20‐7.91	6.20‐7.91	NUM
eurjchem-1564	130	93	(	(	PUNCT
eurjchem-1564	130	94	m	m	PROPN
eurjchem-1564	130	95	,	,	PUNCT
eurjchem-1564	130	96	4h	4h	NOUN
eurjchem-1564	130	97	,	,	PUNCT
eurjchem-1564	130	98	ar‐h	ar‐h	PROPN
eurjchem-1564	130	99	)	)	PUNCT
eurjchem-1564	130	100	,	,	PUNCT
eurjchem-1564	130	101	8.60	8.60	NUM
eurjchem-1564	130	102	(	(	PUNCT
eurjchem-1564	130	103	s	s	PROPN
eurjchem-1564	130	104	,	,	PUNCT
eurjchem-1564	130	105	2h	2h	NUM
eurjchem-1564	130	106	,	,	PUNCT
eurjchem-1564	130	107	2×ch	2×ch	NUM
eurjchem-1564	130	108	=	=	SYM
eurjchem-1564	130	109	n	n	NUM
eurjchem-1564	130	110	)	)	PUNCT
eurjchem-1564	130	111	.	.	PUNCT
eurjchem-1564	131	1	anal	anal	PROPN
eurjchem-1564	131	2	.	.	PUNCT
eurjchem-1564	131	3	calcd	calcd	NOUN
eurjchem-1564	131	4	.	.	PUNCT
eurjchem-1564	132	1	for	for	ADP
eurjchem-1564	132	2	c28h24cl2n2fe2pd	c28h24cl2n2fe2pd	NOUN
eurjchem-1564	132	3	:	:	PUNCT
eurjchem-1564	132	4	c	c	X
eurjchem-1564	132	5	,	,	PUNCT
eurjchem-1564	132	6	49.64	49.64	NUM
eurjchem-1564	132	7	;	;	PUNCT
eurjchem-1564	132	8	h	h	NOUN
eurjchem-1564	132	9	,	,	PUNCT
eurjchem-1564	132	10	3.57	3.57	NUM
eurjchem-1564	132	11	;	;	PUNCT
eurjchem-1564	132	12	n	n	CCONJ
eurjchem-1564	132	13	,	,	PUNCT
eurjchem-1564	132	14	4.13	4.13	NUM
eurjchem-1564	132	15	.	.	PUNCT
eurjchem-1564	132	16	found	find	VERB
eurjchem-1564	132	17	:	:	PUNCT
eurjchem-1564	133	1	c	c	X
eurjchem-1564	133	2	,	,	PUNCT
eurjchem-1564	133	3	49.79	49.79	NUM
eurjchem-1564	133	4	;	;	PUNCT
eurjchem-1564	134	1	h	h	NOUN
eurjchem-1564	134	2	,	,	PUNCT
eurjchem-1564	134	3	3.68	3.68	NUM
eurjchem-1564	134	4	;	;	PUNCT
eurjchem-1564	134	5	n	n	CCONJ
eurjchem-1564	134	6	,	,	PUNCT
eurjchem-1564	134	7	4.33	4.33	NUM
eurjchem-1564	134	8	%	%	NOUN
eurjchem-1564	134	9	.	.	PUNCT
eurjchem-1564	135	1	λm	λm	X
eurjchem-1564	135	2	(	(	PUNCT
eurjchem-1564	135	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	135	4	):	):	PUNCT
eurjchem-1564	135	5	6.30	6.30	NUM
eurjchem-1564	135	6	.	.	PUNCT
eurjchem-1564	136	1	2.2.1.7	2.2.1.7	NUM
eurjchem-1564	136	2	.	.	PUNCT
eurjchem-1564	137	1	synthesis	synthesis	NOUN
eurjchem-1564	137	2	of	of	ADP
eurjchem-1564	137	3	dichloro[n‐(1‐ferrocenylethylidine	dichloro[n‐(1‐ferrocenylethylidine	NUM
eurjchem-1564	137	4	)	)	PUNCT
eurjchem-1564	138	1	benzene‐1,2‐diamine]palladium(ii	benzene‐1,2‐diamine]palladium(ii	NOUN
eurjchem-1564	138	2	)	)	PUNCT
eurjchem-1564	138	3	(	(	PUNCT
eurjchem-1564	138	4	7	7	X
eurjchem-1564	138	5	)	)	PUNCT
eurjchem-1564	138	6	a	a	DET
eurjchem-1564	138	7	mixture	mixture	NOUN
eurjchem-1564	138	8	of	of	ADP
eurjchem-1564	138	9	n‐(1‐ferrocenylethylidine)benzene‐1	n‐(1‐ferrocenylethylidine)benzene‐1	PROPN
eurjchem-1564	138	10	,	,	PUNCT
eurjchem-1564	138	11	2‐	2‐	NUM
eurjchem-1564	138	12	diamine	diamine	NOUN
eurjchem-1564	138	13	(	(	PUNCT
eurjchem-1564	138	14	0.537	0.537	NUM
eurjchem-1564	138	15	g	g	NOUN
eurjchem-1564	138	16	,	,	PUNCT
eurjchem-1564	138	17	1	1	NUM
eurjchem-1564	138	18	mmol	mmol	NOUN
eurjchem-1564	138	19	)	)	PUNCT
eurjchem-1564	138	20	and	and	CCONJ
eurjchem-1564	138	21	pdcl2(phcn)2	pdcl2(phcn)2	NOUN
eurjchem-1564	138	22	(	(	PUNCT
eurjchem-1564	138	23	0.383	0.383	NUM
eurjchem-1564	138	24	g	g	NOUN
eurjchem-1564	138	25	,	,	PUNCT
eurjchem-1564	138	26	1	1	NUM
eurjchem-1564	138	27	mmol	mmol	NOUN
eurjchem-1564	138	28	)	)	PUNCT
eurjchem-1564	138	29	in	in	ADP
eurjchem-1564	138	30	30	30	NUM
eurjchem-1564	138	31	ml	ml	NOUN
eurjchem-1564	138	32	of	of	ADP
eurjchem-1564	138	33	absolute	absolute	ADJ
eurjchem-1564	138	34	ethanol	ethanol	NOUN
eurjchem-1564	138	35	was	be	AUX
eurjchem-1564	138	36	stirred	stir	VERB
eurjchem-1564	138	37	at	at	ADP
eurjchem-1564	138	38	room	room	NOUN
eurjchem-1564	138	39	temperature	temperature	NOUN
eurjchem-1564	138	40	for	for	ADP
eurjchem-1564	138	41	48	48	NUM
eurjchem-1564	138	42	h.	h.	NOUN
eurjchem-1564	138	43	a	a	DET
eurjchem-1564	138	44	brown	brown	ADJ
eurjchem-1564	138	45	precipitate	precipitate	NOUN
eurjchem-1564	138	46	was	be	AUX
eurjchem-1564	138	47	formed	form	VERB
eurjchem-1564	138	48	and	and	CCONJ
eurjchem-1564	138	49	then	then	ADV
eurjchem-1564	138	50	purified	purify	VERB
eurjchem-1564	138	51	by	by	ADP
eurjchem-1564	138	52	extraction	extraction	NOUN
eurjchem-1564	138	53	with	with	ADP
eurjchem-1564	138	54	diethyl	diethyl	NOUN
eurjchem-1564	138	55	ether	ether	NOUN
eurjchem-1564	138	56	(	(	PUNCT
eurjchem-1564	138	57	10	10	NUM
eurjchem-1564	138	58	×	×	NOUN
eurjchem-1564	138	59	4	4	NUM
eurjchem-1564	138	60	ml	ml	NOUN
eurjchem-1564	138	61	)	)	PUNCT
eurjchem-1564	138	62	,	,	PUNCT
eurjchem-1564	138	63	and	and	CCONJ
eurjchem-1564	138	64	then	then	ADV
eurjchem-1564	138	65	dried	dry	VERB
eurjchem-1564	138	66	in	in	ADP
eurjchem-1564	138	67	vacuum	vacuum	NOUN
eurjchem-1564	138	68	(	(	PUNCT
eurjchem-1564	138	69	scheme	scheme	NOUN
eurjchem-1564	138	70	3	3	NUM
eurjchem-1564	138	71	)	)	PUNCT
eurjchem-1564	138	72	.	.	PUNCT
eurjchem-1564	139	1	color	color	NOUN
eurjchem-1564	139	2	:	:	PUNCT
eurjchem-1564	139	3	reddish	reddish	PROPN
eurjchem-1564	139	4	brown	brown	NOUN
eurjchem-1564	139	5	.	.	PUNCT
eurjchem-1564	140	1	yield	yield	NOUN
eurjchem-1564	140	2	:	:	PUNCT
eurjchem-1564	140	3	64	64	NUM
eurjchem-1564	140	4	%	%	NOUN
eurjchem-1564	140	5	.	.	PUNCT
eurjchem-1564	141	1	m.p	m.p	PROPN
eurjchem-1564	141	2	.	.	PROPN
eurjchem-1564	141	3	:	:	PUNCT
eurjchem-1564	142	1	129‐131	129‐131	NUM
eurjchem-1564	142	2	°	°	ADP
eurjchem-1564	142	3	c	c	PROPN
eurjchem-1564	142	4	(	(	PUNCT
eurjchem-1564	142	5	dec	dec	PROPN
eurjchem-1564	142	6	.	.	PROPN
eurjchem-1564	142	7	)	)	PUNCT
eurjchem-1564	142	8	.	.	PUNCT
eurjchem-1564	143	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	143	2	(	(	PUNCT
eurjchem-1564	143	3	kbr	kbr	PROPN
eurjchem-1564	143	4	,	,	PUNCT
eurjchem-1564	143	5			PROPN
eurjchem-1564	143	6	,	,	PUNCT
eurjchem-1564	143	7	cm‐1	cm‐1	PROPN
eurjchem-1564	143	8	):	):	PUNCT
eurjchem-1564	143	9	3333	3333	NUM
eurjchem-1564	143	10	,	,	PUNCT
eurjchem-1564	143	11	3066	3066	NUM
eurjchem-1564	143	12	,	,	PUNCT
eurjchem-1564	143	13	2933	2933	NUM
eurjchem-1564	143	14	,	,	PUNCT
eurjchem-1564	143	15	2856	2856	NUM
eurjchem-1564	143	16	,	,	PUNCT
eurjchem-1564	143	17	1653	1653	NUM
eurjchem-1564	143	18	,	,	PUNCT
eurjchem-1564	143	19	1513	1513	NUM
eurjchem-1564	143	20	,	,	PUNCT
eurjchem-1564	143	21	1466	1466	NUM
eurjchem-1564	143	22	,	,	PUNCT
eurjchem-1564	143	23	1226	1226	NUM
eurjchem-1564	143	24	,	,	PUNCT
eurjchem-1564	143	25	759	759	NUM
eurjchem-1564	143	26	,	,	PUNCT
eurjchem-1564	143	27	746	746	NUM
eurjchem-1564	143	28	,	,	PUNCT
eurjchem-1564	143	29	666	666	NUM
eurjchem-1564	143	30	.	.	PUNCT
eurjchem-1564	143	31	1h	1h	NUM
eurjchem-1564	143	32	nmr	nmr	NOUN
eurjchem-1564	143	33	(	(	PUNCT
eurjchem-1564	143	34	300	300	NUM
eurjchem-1564	143	35	mhz	mhz	NOUN
eurjchem-1564	143	36	,	,	PUNCT
eurjchem-1564	143	37	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	143	38	,	,	PUNCT
eurjchem-1564	143	39	δ	δ	PROPN
eurjchem-1564	143	40	,	,	PUNCT
eurjchem-1564	143	41	ppm	ppm	NUM
eurjchem-1564	143	42	):	):	PUNCT
eurjchem-1564	143	43	2.50	2.50	NUM
eurjchem-1564	143	44	(	(	PUNCT
eurjchem-1564	143	45	s	s	PROPN
eurjchem-1564	143	46	,	,	PUNCT
eurjchem-1564	143	47	3h	3h	NUM
eurjchem-1564	143	48	,	,	PUNCT
eurjchem-1564	143	49	ch3	ch3	PROPN
eurjchem-1564	143	50	)	)	PUNCT
eurjchem-1564	143	51	,	,	PUNCT
eurjchem-1564	143	52	4.40	4.40	NUM
eurjchem-1564	143	53	(	(	PUNCT
eurjchem-1564	143	54	s	s	PROPN
eurjchem-1564	143	55	,	,	PUNCT
eurjchem-1564	143	56	5h	5h	NUM
eurjchem-1564	143	57	,	,	PUNCT
eurjchem-1564	143	58	c5h5	c5h5	NOUN
eurjchem-1564	143	59	)	)	PUNCT
eurjchem-1564	143	60	,	,	PUNCT
eurjchem-1564	143	61	4.71	4.71	NUM
eurjchem-1564	143	62	(	(	PUNCT
eurjchem-1564	143	63	s	s	PROPN
eurjchem-1564	143	64	,	,	PUNCT
eurjchem-1564	143	65	2h	2h	NUM
eurjchem-1564	143	66	,	,	PUNCT
eurjchem-1564	143	67	h2	h2	NOUN
eurjchem-1564	143	68	and	and	CCONJ
eurjchem-1564	143	69	h5	h5	PROPN
eurjchem-1564	143	70	)	)	PUNCT
eurjchem-1564	143	71	,	,	PUNCT
eurjchem-1564	143	72	4.90	4.90	NUM
eurjchem-1564	143	73	(	(	PUNCT
eurjchem-1564	143	74	s	s	PROPN
eurjchem-1564	143	75	,	,	PUNCT
eurjchem-1564	143	76	2h	2h	NUM
eurjchem-1564	143	77	,	,	PUNCT
eurjchem-1564	143	78	h3	h3	NOUN
eurjchem-1564	143	79	and	and	CCONJ
eurjchem-1564	143	80	h4	h4	NOUN
eurjchem-1564	143	81	)	)	PUNCT
eurjchem-1564	143	82	,	,	PUNCT
eurjchem-1564	143	83	6.55‐7.68	6.55‐7.68	PROPN
eurjchem-1564	143	84	(	(	PUNCT
eurjchem-1564	143	85	m	m	PROPN
eurjchem-1564	143	86	,	,	PUNCT
eurjchem-1564	143	87	4h	4h	NOUN
eurjchem-1564	143	88	,	,	PUNCT
eurjchem-1564	143	89	ar‐h	ar‐h	PROPN
eurjchem-1564	143	90	)	)	PUNCT
eurjchem-1564	143	91	,	,	PUNCT
eurjchem-1564	143	92	9.54	9.54	NUM
eurjchem-1564	143	93	(	(	PUNCT
eurjchem-1564	143	94	s	s	PROPN
eurjchem-1564	143	95	,	,	PUNCT
eurjchem-1564	143	96	2h	2h	NUM
eurjchem-1564	143	97	,	,	PUNCT
eurjchem-1564	143	98	nh2	nh2	PROPN
eurjchem-1564	143	99	)	)	PUNCT
eurjchem-1564	143	100	.	.	PUNCT
eurjchem-1564	144	1	anal	anal	PROPN
eurjchem-1564	144	2	.	.	PUNCT
eurjchem-1564	144	3	calcd	calcd	NOUN
eurjchem-1564	144	4	.	.	PUNCT
eurjchem-1564	145	1	for	for	ADP
eurjchem-1564	145	2	c18h18cl2n2fepd	c18h18cl2n2fepd	PROPN
eurjchem-1564	145	3	:	:	PUNCT
eurjchem-1564	145	4	c	c	X
eurjchem-1564	145	5	,	,	PUNCT
eurjchem-1564	145	6	43.63	43.63	NUM
eurjchem-1564	145	7	;	;	PUNCT
eurjchem-1564	145	8	h	h	NOUN
eurjchem-1564	145	9	,	,	PUNCT
eurjchem-1564	145	10	3.66	3.66	NUM
eurjchem-1564	145	11	;	;	PUNCT
eurjchem-1564	145	12	n	n	CCONJ
eurjchem-1564	145	13	,	,	PUNCT
eurjchem-1564	145	14	5.65	5.65	NUM
eurjchem-1564	145	15	.	.	PUNCT
eurjchem-1564	145	16	found	find	VERB
eurjchem-1564	145	17	:	:	PUNCT
eurjchem-1564	146	1	c	c	X
eurjchem-1564	146	2	,	,	PUNCT
eurjchem-1564	146	3	43.79	43.79	NUM
eurjchem-1564	146	4	;	;	PUNCT
eurjchem-1564	146	5	h	h	NOUN
eurjchem-1564	146	6	,	,	PUNCT
eurjchem-1564	146	7	2.65	2.65	NUM
eurjchem-1564	146	8	;	;	PUNCT
eurjchem-1564	146	9	n	n	CCONJ
eurjchem-1564	146	10	,	,	PUNCT
eurjchem-1564	146	11	4.90	4.90	NUM
eurjchem-1564	146	12	%	%	NOUN
eurjchem-1564	146	13	.	.	PUNCT
eurjchem-1564	147	1	λm	λm	X
eurjchem-1564	147	2	(	(	PUNCT
eurjchem-1564	147	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	147	4	):	):	PUNCT
eurjchem-1564	147	5	8.50	8.50	NUM
eurjchem-1564	147	6	.	.	PUNCT
eurjchem-1564	148	1	2.2.1.8	2.2.1.8	X
eurjchem-1564	148	2	.	.	NOUN
eurjchem-1564	148	3	synthesis	synthesis	NOUN
eurjchem-1564	148	4	of	of	ADP
eurjchem-1564	148	5	dichloro[n	dichloro[n	PROPN
eurjchem-1564	148	6	,	,	PUNCT
eurjchem-1564	148	7	n'‐bis(1‐ferrocenyl	n'‐bis(1‐ferrocenyl	PROPN
eurjchem-1564	148	8	ethylidine)benzene‐1,2‐diamine]palladium(ii	ethylidine)benzene‐1,2‐diamine]palladium(ii	PROPN
eurjchem-1564	148	9	)	)	PUNCT
eurjchem-1564	148	10	(	(	PUNCT
eurjchem-1564	148	11	8)	8)	NUM
eurjchem-1564	148	12	a	a	DET
eurjchem-1564	148	13	mixture	mixture	NOUN
eurjchem-1564	148	14	of	of	ADP
eurjchem-1564	148	15	n	n	CCONJ
eurjchem-1564	148	16	,	,	PUNCT
eurjchem-1564	148	17	n'‐bis(1‐ferrocenylethylidine)benzene‐1,2‐	n'‐bis(1‐ferrocenylethylidine)benzene‐1,2‐	PROPN
eurjchem-1564	148	18	diamine	diamine	NOUN
eurjchem-1564	148	19	(	(	PUNCT
eurjchem-1564	148	20	0.775	0.775	NUM
eurjchem-1564	148	21	g	g	NOUN
eurjchem-1564	148	22	,	,	PUNCT
eurjchem-1564	148	23	1	1	NUM
eurjchem-1564	148	24	mmol	mmol	NOUN
eurjchem-1564	148	25	)	)	PUNCT
eurjchem-1564	148	26	and	and	CCONJ
eurjchem-1564	148	27	pdcl2(phcn)2	pdcl2(phcn)2	NOUN
eurjchem-1564	148	28	(	(	PUNCT
eurjchem-1564	148	29	0.383	0.383	NUM
eurjchem-1564	148	30	g	g	NOUN
eurjchem-1564	148	31	,	,	PUNCT
eurjchem-1564	148	32	1	1	NUM
eurjchem-1564	148	33	mmol	mmol	NOUN
eurjchem-1564	148	34	)	)	PUNCT
eurjchem-1564	148	35	in	in	ADP
eurjchem-1564	148	36	30	30	NUM
eurjchem-1564	148	37	ml	ml	NOUN
eurjchem-1564	148	38	of	of	ADP
eurjchem-1564	148	39	absolute	absolute	ADJ
eurjchem-1564	148	40	ethanol	ethanol	NOUN
eurjchem-1564	148	41	was	be	AUX
eurjchem-1564	148	42	stirred	stir	VERB
eurjchem-1564	148	43	for	for	ADP
eurjchem-1564	148	44	48	48	NUM
eurjchem-1564	148	45	h	h	NOUN
eurjchem-1564	148	46	at	at	ADP
eurjchem-1564	148	47	room	room	NOUN
eurjchem-1564	148	48	temperature	temperature	NOUN
eurjchem-1564	148	49	.	.	PUNCT
eurjchem-1564	149	1	a	a	DET
eurjchem-1564	149	2	brown	brown	ADJ
eurjchem-1564	149	3	solid	solid	NOUN
eurjchem-1564	149	4	was	be	AUX
eurjchem-1564	149	5	obtained	obtain	VERB
eurjchem-1564	149	6	and	and	CCONJ
eurjchem-1564	149	7	purified	purify	VERB
eurjchem-1564	149	8	by	by	ADP
eurjchem-1564	149	9	extraction	extraction	NOUN
eurjchem-1564	149	10	with	with	ADP
eurjchem-1564	149	11	diethyl	diethyl	NOUN
eurjchem-1564	149	12	ether	ether	NOUN
eurjchem-1564	149	13	(	(	PUNCT
eurjchem-1564	149	14	10×4	10×4	PROPN
eurjchem-1564	149	15	ml	ml	NOUN
eurjchem-1564	149	16	)	)	PUNCT
eurjchem-1564	149	17	and	and	CCONJ
eurjchem-1564	149	18	then	then	ADV
eurjchem-1564	149	19	dried	dry	VERB
eurjchem-1564	149	20	in	in	ADP
eurjchem-1564	149	21	vacuum	vacuum	NOUN
eurjchem-1564	149	22	(	(	PUNCT
eurjchem-1564	149	23	scheme	scheme	NOUN
eurjchem-1564	149	24	4	4	NUM
eurjchem-1564	149	25	)	)	PUNCT
eurjchem-1564	149	26	.	.	PUNCT
eurjchem-1564	150	1	color	color	NOUN
eurjchem-1564	150	2	:	:	PUNCT
eurjchem-1564	150	3	brown	brown	ADJ
eurjchem-1564	150	4	solid	solid	ADJ
eurjchem-1564	150	5	.	.	PUNCT
eurjchem-1564	151	1	yield	yield	NOUN
eurjchem-1564	151	2	:	:	PUNCT
eurjchem-1564	151	3	60	60	NUM
eurjchem-1564	151	4	%	%	NOUN
eurjchem-1564	151	5	.	.	PUNCT
eurjchem-1564	152	1	m.p	m.p	PROPN
eurjchem-1564	152	2	.	.	PROPN
eurjchem-1564	152	3	:	:	PUNCT
eurjchem-1564	153	1	91‐	91‐	NUM
eurjchem-1564	153	2	93	93	NUM
eurjchem-1564	153	3	°	°	NUM
eurjchem-1564	153	4	c	c	X
eurjchem-1564	153	5	(	(	PUNCT
eurjchem-1564	153	6	dec	dec	PROPN
eurjchem-1564	153	7	.	.	PROPN
eurjchem-1564	153	8	)	)	PUNCT
eurjchem-1564	153	9	.	.	PUNCT
eurjchem-1564	154	1	ft‐ir	ft‐ir	NOUN
eurjchem-1564	154	2	(	(	PUNCT
eurjchem-1564	154	3	kbr	kbr	PROPN
eurjchem-1564	154	4	,	,	PUNCT
eurjchem-1564	154	5			PROPN
eurjchem-1564	154	6	,	,	PUNCT
eurjchem-1564	154	7	cm‐1	cm‐1	PROPN
eurjchem-1564	154	8	):	):	PUNCT
eurjchem-1564	154	9	3092	3092	NUM
eurjchem-1564	154	10	,	,	PUNCT
eurjchem-1564	154	11	2933	2933	NUM
eurjchem-1564	154	12	,	,	PUNCT
eurjchem-1564	154	13	2853	2853	NUM
eurjchem-1564	154	14	,	,	PUNCT
eurjchem-1564	154	15	1653	1653	NUM
eurjchem-1564	154	16	,	,	PUNCT
eurjchem-1564	154	17	1458	1458	NUM
eurjchem-1564	154	18	,	,	PUNCT
eurjchem-1564	154	19	1375	1375	NUM
eurjchem-1564	154	20	,	,	PUNCT
eurjchem-1564	154	21	1280	1280	NUM
eurjchem-1564	154	22	,	,	PUNCT
eurjchem-1564	154	23	693	693	NUM
eurjchem-1564	154	24	,	,	PUNCT
eurjchem-1564	154	25	666	666	NUM
eurjchem-1564	154	26	,	,	PUNCT
eurjchem-1564	154	27	626	626	NUM
eurjchem-1564	154	28	.	.	PUNCT
eurjchem-1564	155	1	1h	1h	NUM
eurjchem-1564	155	2	nmr	nmr	NOUN
eurjchem-1564	155	3	(	(	PUNCT
eurjchem-1564	155	4	300	300	NUM
eurjchem-1564	155	5	mhz	mhz	NOUN
eurjchem-1564	155	6	,	,	PUNCT
eurjchem-1564	155	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1564	155	8	,	,	PUNCT
eurjchem-1564	155	9	δ	δ	PROPN
eurjchem-1564	155	10	,	,	PUNCT
eurjchem-1564	155	11	ppm	ppm	NUM
eurjchem-1564	155	12	):	):	PUNCT
eurjchem-1564	155	13	2.98	2.98	NUM
eurjchem-1564	155	14	(	(	PUNCT
eurjchem-1564	155	15	s	s	PROPN
eurjchem-1564	155	16	,	,	PUNCT
eurjchem-1564	155	17	6h	6h	NUM
eurjchem-1564	155	18	,	,	PUNCT
eurjchem-1564	155	19	2ch3	2ch3	NUM
eurjchem-1564	155	20	)	)	PUNCT
eurjchem-1564	155	21	,	,	PUNCT
eurjchem-1564	155	22	4.40	4.40	NUM
eurjchem-1564	155	23	(	(	PUNCT
eurjchem-1564	155	24	s	s	PROPN
eurjchem-1564	155	25	,	,	PUNCT
eurjchem-1564	155	26	10h	10h	NUM
eurjchem-1564	155	27	,	,	PUNCT
eurjchem-1564	155	28	2×c5h5	2×c5h5	NUM
eurjchem-1564	155	29	)	)	PUNCT
eurjchem-1564	155	30	,	,	PUNCT
eurjchem-1564	155	31	4.71	4.71	NUM
eurjchem-1564	155	32	(	(	PUNCT
eurjchem-1564	155	33	s	s	PROPN
eurjchem-1564	155	34	,	,	PUNCT
eurjchem-1564	155	35	4h	4h	NUM
eurjchem-1564	155	36	,	,	PUNCT
eurjchem-1564	155	37	2h2	2h2	NUM
eurjchem-1564	155	38	and	and	CCONJ
eurjchem-1564	155	39	2h5	2h5	NUM
eurjchem-1564	155	40	)	)	PUNCT
eurjchem-1564	155	41	,	,	PUNCT
eurjchem-1564	155	42	4.92	4.92	NUM
eurjchem-1564	155	43	(	(	PUNCT
eurjchem-1564	155	44	s	s	PROPN
eurjchem-1564	155	45	,	,	PUNCT
eurjchem-1564	155	46	4h	4h	NUM
eurjchem-1564	155	47	,	,	PUNCT
eurjchem-1564	155	48	2h3	2h3	NUM
eurjchem-1564	155	49	and	and	CCONJ
eurjchem-1564	155	50	2h4	2h4	NUM
eurjchem-1564	155	51	)	)	PUNCT
eurjchem-1564	155	52	,	,	PUNCT
eurjchem-1564	155	53	6.60‐7.49	6.60‐7.49	NUM
eurjchem-1564	155	54	(	(	PUNCT
eurjchem-1564	155	55	m	m	PROPN
eurjchem-1564	155	56	,	,	PUNCT
eurjchem-1564	155	57	4h	4h	NUM
eurjchem-1564	155	58	,	,	PUNCT
eurjchem-1564	155	59	ar‐	ar‐	PROPN
eurjchem-1564	155	60	h	h	NOUN
eurjchem-1564	155	61	)	)	PUNCT
eurjchem-1564	155	62	.	.	PUNCT
eurjchem-1564	156	1	anal	anal	PROPN
eurjchem-1564	156	2	.	.	PUNCT
eurjchem-1564	156	3	calcd	calcd	NOUN
eurjchem-1564	156	4	.	.	PUNCT
eurjchem-1564	157	1	for	for	ADP
eurjchem-1564	157	2	c30h28cl2n2fe2pd	c30h28cl2n2fe2pd	NOUN
eurjchem-1564	157	3	:	:	PUNCT
eurjchem-1564	157	4	c	c	X
eurjchem-1564	157	5	,	,	PUNCT
eurjchem-1564	157	6	51.07	51.07	NUM
eurjchem-1564	157	7	;	;	PUNCT
eurjchem-1564	157	8	h	h	NOUN
eurjchem-1564	157	9	,	,	PUNCT
eurjchem-1564	157	10	4.00	4.00	NUM
eurjchem-1564	157	11	;	;	PUNCT
eurjchem-1564	157	12	n	n	CCONJ
eurjchem-1564	157	13	,	,	PUNCT
eurjchem-1564	157	14	3.97	3.97	NUM
eurjchem-1564	157	15	.	.	PUNCT
eurjchem-1564	157	16	found	find	VERB
eurjchem-1564	157	17	:	:	PUNCT
eurjchem-1564	158	1	c	c	X
eurjchem-1564	158	2	,	,	PUNCT
eurjchem-1564	158	3	51.06	51.06	NUM
eurjchem-1564	158	4	;	;	PUNCT
eurjchem-1564	158	5	h	h	NOUN
eurjchem-1564	158	6	,	,	PUNCT
eurjchem-1564	158	7	4.19	4.19	NUM
eurjchem-1564	158	8	;	;	PUNCT
eurjchem-1564	158	9	n	n	CCONJ
eurjchem-1564	158	10	,	,	PUNCT
eurjchem-1564	158	11	4.00	4.00	NUM
eurjchem-1564	158	12	%	%	NOUN
eurjchem-1564	158	13	.	.	PUNCT
eurjchem-1564	159	1	λm	λm	X
eurjchem-1564	159	2	(	(	PUNCT
eurjchem-1564	159	3	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	ADV
eurjchem-1564	159	4	):	):	PUNCT
eurjchem-1564	159	5	8.40	8.40	NUM
eurjchem-1564	159	6	.	.	NOUN
eurjchem-1564	160	1	2.3	2.3	NUM
eurjchem-1564	160	2	.	.	PUNCT
eurjchem-1564	161	1	antimicrobial	antimicrobial	ADJ
eurjchem-1564	161	2	activity	activity	NOUN
eurjchem-1564	161	3	for	for	ADP
eurjchem-1564	161	4	all	all	DET
eurjchem-1564	161	5	biological	biological	ADJ
eurjchem-1564	161	6	experiments	experiment	NOUN
eurjchem-1564	161	7	,	,	PUNCT
eurjchem-1564	161	8	stock	stock	NOUN
eurjchem-1564	161	9	solution	solution	NOUN
eurjchem-1564	161	10	of	of	ADP
eurjchem-1564	161	11	com‐	com‐	PRON
eurjchem-1564	161	12	pounds	pound	NOUN
eurjchem-1564	161	13	1‐8	1‐8	PROPN
eurjchem-1564	161	14	(	(	PUNCT
eurjchem-1564	161	15	1000	1000	NUM
eurjchem-1564	161	16	µg	µg	NOUN
eurjchem-1564	161	17	/	/	SYM
eurjchem-1564	161	18	ml	ml	NOUN
eurjchem-1564	161	19	)	)	PUNCT
eurjchem-1564	161	20	were	be	AUX
eurjchem-1564	161	21	prepared	prepare	VERB
eurjchem-1564	161	22	as	as	ADP
eurjchem-1564	161	23	follow	follow	VERB
eurjchem-1564	161	24	:	:	PUNCT
eurjchem-1564	161	25	for	for	ADP
eurjchem-1564	161	26	pd(ii	pd(ii	ADJ
eurjchem-1564	161	27	)	)	PUNCT
eurjchem-1564	161	28	complexes	complex	NOUN
eurjchem-1564	161	29	,	,	PUNCT
eurjchem-1564	161	30	dmso	dmso	NOUN
eurjchem-1564	161	31	was	be	AUX
eurjchem-1564	161	32	used	use	VERB
eurjchem-1564	161	33	as	as	ADP
eurjchem-1564	161	34	a	a	DET
eurjchem-1564	161	35	solvent	solvent	NOUN
eurjchem-1564	161	36	to	to	PART
eurjchem-1564	161	37	prepare	prepare	VERB
eurjchem-1564	161	38	their	their	PRON
eurjchem-1564	161	39	stock	stock	NOUN
eurjchem-1564	161	40	solutions	solution	NOUN
eurjchem-1564	161	41	(	(	PUNCT
eurjchem-1564	161	42	the	the	DET
eurjchem-1564	161	43	final	final	ADJ
eurjchem-1564	161	44	concentration	concentration	NOUN
eurjchem-1564	161	45	of	of	ADP
eurjchem-1564	161	46	the	the	DET
eurjchem-1564	161	47	solvent	solvent	NOUN
eurjchem-1564	161	48	should	should	AUX
eurjchem-1564	161	49	be	be	AUX
eurjchem-1564	161	50	1	1	NUM
eurjchem-1564	161	51	%	%	NOUN
eurjchem-1564	161	52	)	)	PUNCT
eurjchem-1564	161	53	.	.	PUNCT
eurjchem-1564	162	1	in	in	ADP
eurjchem-1564	162	2	vitro	vitro	X
eurjchem-1564	162	3	antibacterial	antibacterial	ADJ
eurjchem-1564	162	4	screening	screening	NOUN
eurjchem-1564	162	5	is	be	AUX
eurjchem-1564	162	6	generally	generally	ADV
eurjchem-1564	162	7	performed	perform	VERB
eurjchem-1564	162	8	by	by	ADP
eurjchem-1564	162	9	the	the	DET
eurjchem-1564	162	10	agar	agar	NOUN
eurjchem-1564	162	11	diffusion	diffusion	NOUN
eurjchem-1564	162	12	method	method	NOUN
eurjchem-1564	162	13	for	for	ADP
eurjchem-1564	162	14	testing	test	VERB
eurjchem-1564	162	15	antibacterial	antibacterial	ADJ
eurjchem-1564	162	16	activity	activity	NOUN
eurjchem-1564	162	17	of	of	ADP
eurjchem-1564	162	18	the	the	DET
eurjchem-1564	162	19	prepared	prepare	VERB
eurjchem-1564	162	20	palladium(ii	palladium(ii	NOUN
eurjchem-1564	162	21	)	)	PUNCT
eurjchem-1564	162	22	complexes	complex	NOUN
eurjchem-1564	162	23	(	(	PUNCT
eurjchem-1564	162	24	table	table	NOUN
eurjchem-1564	162	25	1	1	NUM
eurjchem-1564	162	26	)	)	PUNCT
eurjchem-1564	162	27	.	.	PUNCT
eurjchem-1564	163	1	this	this	DET
eurjchem-1564	163	2	method	method	NOUN
eurjchem-1564	163	3	includes	include	VERB
eurjchem-1564	163	4	agar	agar	NOUN
eurjchem-1564	163	5	well	well	ADJ
eurjchem-1564	163	6	diffusion	diffusion	NOUN
eurjchem-1564	163	7	assay	assay	NOUN
eurjchem-1564	163	8	and	and	CCONJ
eurjchem-1564	163	9	disc	disc	NOUN
eurjchem-1564	163	10	assay	assay	NOUN
eurjchem-1564	163	11	.	.	PUNCT
eurjchem-1564	164	1	in	in	ADP
eurjchem-1564	164	2	this	this	DET
eurjchem-1564	164	3	test	test	NOUN
eurjchem-1564	164	4	,	,	PUNCT
eurjchem-1564	164	5	the	the	DET
eurjchem-1564	164	6	antimicrobial	antimicrobial	ADJ
eurjchem-1564	164	7	compound	compound	NOUN
eurjchem-1564	164	8	is	be	AUX
eurjchem-1564	164	9	applied	apply	VERB
eurjchem-1564	164	10	to	to	ADP
eurjchem-1564	164	11	an	an	DET
eurjchem-1564	164	12	agar	agar	NOUN
eurjchem-1564	164	13	plate	plate	NOUN
eurjchem-1564	164	14	on	on	ADP
eurjchem-1564	164	15	a	a	DET
eurjchem-1564	164	16	paper	paper	NOUN
eurjchem-1564	164	17	disc	disc	NOUN
eurjchem-1564	164	18	or	or	CCONJ
eurjchem-1564	164	19	in	in	ADP
eurjchem-1564	164	20	a	a	DET
eurjchem-1564	164	21	well	well	NOUN
eurjchem-1564	164	22	.	.	PUNCT
eurjchem-1564	165	1	the	the	DET
eurjchem-1564	165	2	compound	compound	NOUN
eurjchem-1564	165	3	diffuses	diffuse	VERB
eurjchem-1564	165	4	into	into	ADP
eurjchem-1564	165	5	agar	agar	NOUN
eurjchem-1564	165	6	resulting	result	VERB
eurjchem-1564	165	7	in	in	ADP
eurjchem-1564	165	8	a	a	DET
eurjchem-1564	165	9	concentration	concentration	NOUN
eurjchem-1564	165	10	gradient	gradient	NOUN
eurjchem-1564	165	11	that	that	PRON
eurjchem-1564	165	12	is	be	AUX
eurjchem-1564	165	13	inversely	inversely	ADV
eurjchem-1564	165	14	propor‐	propor‐	VERB
eurjchem-1564	165	15	tional	tional	ADJ
eurjchem-1564	165	16	to	to	ADP
eurjchem-1564	165	17	the	the	DET
eurjchem-1564	165	18	distance	distance	NOUN
eurjchem-1564	165	19	from	from	ADP
eurjchem-1564	165	20	the	the	DET
eurjchem-1564	165	21	disc	disc	NOUN
eurjchem-1564	165	22	or	or	CCONJ
eurjchem-1564	165	23	well	well	ADV
eurjchem-1564	165	24	.	.	PUNCT
eurjchem-1564	166	1	the	the	DET
eurjchem-1564	166	2	diameter	diameter	NOUN
eurjchem-1564	166	3	of	of	ADP
eurjchem-1564	166	4	the	the	DET
eurjchem-1564	166	5	inhibition	inhibition	NOUN
eurjchem-1564	166	6	zone	zone	NOUN
eurjchem-1564	166	7	around	around	ADP
eurjchem-1564	166	8	the	the	DET
eurjchem-1564	166	9	disc	disc	NOUN
eurjchem-1564	166	10	or	or	CCONJ
eurjchem-1564	166	11	well	well	ADV
eurjchem-1564	166	12	is	be	AUX
eurjchem-1564	166	13	a	a	DET
eurjchem-1564	166	14	measure	measure	NOUN
eurjchem-1564	166	15	of	of	ADP
eurjchem-1564	166	16	the	the	DET
eurjchem-1564	166	17	degree	degree	NOUN
eurjchem-1564	166	18	of	of	ADP
eurjchem-1564	166	19	degree	degree	NOUN
eurjchem-1564	166	20	of	of	ADP
eurjchem-1564	166	21	inhibition	inhibition	NOUN
eurjchem-1564	166	22	.	.	PUNCT
eurjchem-1564	167	1	the	the	DET
eurjchem-1564	167	2	resulting	resulting	NOUN
eurjchem-1564	167	3	of	of	ADP
eurjchem-1564	167	4	the	the	DET
eurjchem-1564	167	5	tests	test	NOUN
eurjchem-1564	167	6	are	be	AUX
eurjchem-1564	167	7	mostly	mostly	ADV
eurjchem-1564	167	8	qualitative	qualitative	VERB
eurjchem-1564	167	9	[	[	X
eurjchem-1564	167	10	23	23	NUM
eurjchem-1564	167	11	]	]	PUNCT
eurjchem-1564	167	12	.	.	PUNCT
eurjchem-1564	168	1	for	for	ADP
eurjchem-1564	168	2	antimicrobial	antimicrobial	ADJ
eurjchem-1564	168	3	activity	activity	NOUN
eurjchem-1564	168	4	,	,	PUNCT
eurjchem-1564	168	5	compound	compound	NOUN
eurjchem-1564	168	6	stock	stock	NOUN
eurjchem-1564	168	7	solutions	solution	NOUN
eurjchem-1564	168	8	(	(	PUNCT
eurjchem-1564	168	9	1000	1000	NUM
eurjchem-1564	168	10	µg	µg	NOUN
eurjchem-1564	168	11	/	/	SYM
eurjchem-1564	168	12	ml	ml	NOUN
eurjchem-1564	168	13	)	)	PUNCT
eurjchem-1564	168	14	from	from	ADP
eurjchem-1564	168	15	which	which	PRON
eurjchem-1564	168	16	,	,	PUNCT
eurjchem-1564	168	17	serial	serial	ADJ
eurjchem-1564	168	18	dilutions	dilution	NOUN
eurjchem-1564	168	19	of	of	ADP
eurjchem-1564	168	20	work	work	NOUN
eurjchem-1564	168	21	concentrations	concentration	NOUN
eurjchem-1564	168	22	were	be	AUX
eurjchem-1564	168	23	diluted	dilute	VERB
eurjchem-1564	168	24	sufficiently	sufficiently	ADV
eurjchem-1564	168	25	for	for	ADP
eurjchem-1564	168	26	this	this	DET
eurjchem-1564	168	27	assay	assay	NOUN
eurjchem-1564	168	28	with	with	ADP
eurjchem-1564	168	29	sterilized	sterilize	VERB
eurjchem-1564	168	30	water	water	NOUN
eurjchem-1564	168	31	to	to	PART
eurjchem-1564	168	32	avoid	avoid	VERB
eurjchem-1564	168	33	solvent	solvent	ADJ
eurjchem-1564	168	34	interferences	interference	NOUN
eurjchem-1564	168	35	.	.	PUNCT
eurjchem-1564	169	1	the	the	DET
eurjchem-1564	169	2	solvent	solvent	NOUN
eurjchem-1564	169	3	was	be	AUX
eurjchem-1564	169	4	used	use	VERB
eurjchem-1564	169	5	as	as	ADP
eurjchem-1564	169	6	a	a	DET
eurjchem-1564	169	7	negative	negative	ADJ
eurjchem-1564	169	8	control	control	NOUN
eurjchem-1564	169	9	in	in	ADP
eurjchem-1564	169	10	each	each	DET
eurjchem-1564	169	11	separated	separate	VERB
eurjchem-1564	169	12	assay	assay	NOUN
eurjchem-1564	169	13	.	.	PUNCT
eurjchem-1564	170	1	the	the	DET
eurjchem-1564	170	2	primary	primary	ADJ
eurjchem-1564	170	3	screening	screening	NOUN
eurjchem-1564	170	4	of	of	ADP
eurjchem-1564	170	5	antibacterial	antibacterial	ADJ
eurjchem-1564	170	6	activity	activity	NOUN
eurjchem-1564	170	7	of	of	ADP
eurjchem-1564	170	8	the	the	DET
eurjchem-1564	170	9	palla‐	palla‐	NOUN
eurjchem-1564	170	10	dium(ii	dium(ii	NOUN
eurjchem-1564	170	11	)	)	PUNCT
eurjchem-1564	170	12	complexes	complex	NOUN
eurjchem-1564	170	13	compared	compare	VERB
eurjchem-1564	170	14	to	to	ADP
eurjchem-1564	170	15	cis‐platin	cis‐platin	PROPN
eurjchem-1564	170	16	were	be	AUX
eurjchem-1564	170	17	determined	determine	VERB
eurjchem-1564	170	18	at	at	ADP
eurjchem-1564	170	19	concentration	concentration	NOUN
eurjchem-1564	170	20	of	of	ADP
eurjchem-1564	170	21	250	250	NUM
eurjchem-1564	170	22	µg	µg	NOUN
eurjchem-1564	170	23	/	/	SYM
eurjchem-1564	170	24	disc	disc	NOUN
eurjchem-1564	170	25	against	against	ADP
eurjchem-1564	170	26	to	to	ADP
eurjchem-1564	170	27	gram‐positive	gram‐positive	ADJ
eurjchem-1564	170	28	(	(	PUNCT
eurjchem-1564	170	29	staphylococcus	staphylococcus	NOUN
eurjchem-1564	170	30	aureus	aureus	NOUN
eurjchem-1564	170	31	(	(	PUNCT
eurjchem-1564	170	32	atcc	atcc	NOUN
eurjchem-1564	170	33	25923	25923	NUM
eurjchem-1564	170	34	)	)	PUNCT
eurjchem-1564	170	35	)	)	PUNCT
eurjchem-1564	170	36	,	,	PUNCT
eurjchem-1564	170	37	and	and	CCONJ
eurjchem-1564	170	38	gram‐negative	gram‐negative	PROPN
eurjchem-1564	170	39	(	(	PUNCT
eurjchem-1564	170	40	eschericha	eschericha	NOUN
eurjchem-1564	170	41	coli	coli	NOUN
eurjchem-1564	170	42	(	(	PUNCT
eurjchem-1564	170	43	atcc25922	atcc25922	PROPN
eurjchem-1564	170	44	)	)	PUNCT
eurjchem-1564	170	45	)	)	PUNCT
eurjchem-1564	170	46	bacteria	bacteria	NOUN
eurjchem-1564	170	47	as	as	SCONJ
eurjchem-1564	170	48	described	describe	VERB
eurjchem-1564	170	49	by	by	ADP
eurjchem-1564	170	50	the	the	DET
eurjchem-1564	170	51	disc	disc	NOUN
eurjchem-1564	170	52	diffusion	diffusion	NOUN
eurjchem-1564	170	53	method	method	NOUN
eurjchem-1564	170	54	[	[	X
eurjchem-1564	170	55	23	23	NUM
eurjchem-1564	170	56	]	]	PUNCT
eurjchem-1564	170	57	.	.	PUNCT
eurjchem-1564	171	1	whatman	whatman	PROPN
eurjchem-1564	171	2	no.4	no.4	PROPN
eurjchem-1564	171	3	filter	filter	NOUN
eurjchem-1564	171	4	paper	paper	NOUN
eurjchem-1564	171	5	was	be	AUX
eurjchem-1564	171	6	used	use	VERB
eurjchem-1564	171	7	for	for	ADP
eurjchem-1564	171	8	the	the	DET
eurjchem-1564	171	9	preparation	preparation	NOUN
eurjchem-1564	171	10	of	of	ADP
eurjchem-1564	171	11	diffusion	diffusion	NOUN
eurjchem-1564	171	12	disc	disc	NOUN
eurjchem-1564	171	13	(	(	PUNCT
eurjchem-1564	171	14	7	7	NUM
eurjchem-1564	171	15	mm	mm	NOUN
eurjchem-1564	171	16	in	in	ADP
eurjchem-1564	171	17	diameter	diameter	NOUN
eurjchem-1564	171	18	)	)	PUNCT
eurjchem-1564	171	19	and	and	CCONJ
eurjchem-1564	171	20	the	the	DET
eurjchem-1564	171	21	discs	disc	NOUN
eurjchem-1564	171	22	were	be	AUX
eurjchem-1564	171	23	saturated	saturate	VERB
eurjchem-1564	171	24	with	with	ADP
eurjchem-1564	171	25	pd(ii	pd(ii	ADJ
eurjchem-1564	171	26	)	)	PUNCT
eurjchem-1564	171	27	complexes	complex	NOUN
eurjchem-1564	171	28	and	and	CCONJ
eurjchem-1564	171	29	other	other	ADJ
eurjchem-1564	171	30	standard	standard	ADJ
eurjchem-1564	171	31	complexes	complex	NOUN
eurjchem-1564	171	32	at	at	ADP
eurjchem-1564	171	33	a	a	DET
eurjchem-1564	171	34	concentration	concentration	NOUN
eurjchem-1564	171	35	of	of	ADP
eurjchem-1564	171	36	250	250	NUM
eurjchem-1564	171	37	µg	µg	ADV
eurjchem-1564	171	38	/	/	SYM
eurjchem-1564	171	39	ml	ml	NOUN
eurjchem-1564	171	40	.	.	PUNCT
eurjchem-1564	172	1	the	the	DET
eurjchem-1564	172	2	medium	medium	NOUN
eurjchem-1564	172	3	used	use	VERB
eurjchem-1564	172	4	in	in	ADP
eurjchem-1564	172	5	this	this	DET
eurjchem-1564	172	6	respect	respect	NOUN
eurjchem-1564	172	7	was	be	AUX
eurjchem-1564	172	8	nutrient	nutrient	ADJ
eurjchem-1564	172	9	agar	agar	NOUN
eurjchem-1564	172	10	,	,	PUNCT
eurjchem-1564	172	11	the	the	DET
eurjchem-1564	172	12	plates	plate	NOUN
eurjchem-1564	172	13	were	be	AUX
eurjchem-1564	172	14	inoculated	inoculate	VERB
eurjchem-1564	172	15	with	with	ADP
eurjchem-1564	172	16	tested	test	VERB
eurjchem-1564	172	17	bacteria	bacteria	NOUN
eurjchem-1564	172	18	,	,	PUNCT
eurjchem-1564	172	19	and	and	CCONJ
eurjchem-1564	172	20	the	the	DET
eurjchem-1564	172	21	complexes‐impreg‐	complexes‐impreg‐	PROPN
eurjchem-1564	172	22	nated	nate	VERB
eurjchem-1564	172	23	disc	disc	NOUN
eurjchem-1564	172	24	was	be	AUX
eurjchem-1564	172	25	a	a	DET
eurjchem-1564	172	26	specially	specially	ADV
eurjchem-1564	172	27	placed	place	VERB
eurjchem-1564	172	28	on	on	ADP
eurjchem-1564	172	29	the	the	DET
eurjchem-1564	172	30	agar	agar	NOUN
eurjchem-1564	172	31	surface	surface	NOUN
eurjchem-1564	172	32	,	,	PUNCT
eurjchem-1564	172	33	and	and	CCONJ
eurjchem-1564	172	34	the	the	DET
eurjchem-1564	172	35	plates	plate	NOUN
eurjchem-1564	172	36	were	be	AUX
eurjchem-1564	172	37	incubated	incubate	VERB
eurjchem-1564	172	38	for	for	ADP
eurjchem-1564	172	39	24	24	NUM
eurjchem-1564	172	40	hrs	hrs	NOUN
eurjchem-1564	172	41	,	,	PUNCT
eurjchem-1564	172	42	zone	zone	NOUN
eurjchem-1564	172	43	diameter	diameter	NOUN
eurjchem-1564	172	44	were	be	AUX
eurjchem-1564	172	45	measured	measure	VERB
eurjchem-1564	172	46	,	,	PUNCT
eurjchem-1564	172	47	and	and	CCONJ
eurjchem-1564	172	48	the	the	DET
eurjchem-1564	172	49	results	result	NOUN
eurjchem-1564	172	50	were	be	AUX
eurjchem-1564	172	51	compared	compare	VERB
eurjchem-1564	172	52	with	with	ADP
eurjchem-1564	172	53	cis‐platin	cis‐platin	PROPN
eurjchem-1564	172	54	.	.	PUNCT
eurjchem-1564	173	1	2.3.1	2.3.1	NUM
eurjchem-1564	173	2	.	.	PUNCT
eurjchem-1564	174	1	in	in	ADP
eurjchem-1564	174	2	vitro	vitro	X
eurjchem-1564	174	3	antimicrobial	antimicrobial	ADJ
eurjchem-1564	174	4	activity	activity	NOUN
eurjchem-1564	174	5	1‐2	1‐2	PROPN
eurjchem-1564	174	6	ml	ml	X
eurjchem-1564	174	7	of	of	ADP
eurjchem-1564	174	8	nutrient	nutrient	ADJ
eurjchem-1564	174	9	broth	broth	NOUN
eurjchem-1564	174	10	was	be	AUX
eurjchem-1564	174	11	inoculated	inoculate	VERB
eurjchem-1564	174	12	with	with	ADP
eurjchem-1564	174	13	the	the	DET
eurjchem-1564	174	14	test	test	NOUN
eurjchem-1564	174	15	organisms	organism	NOUN
eurjchem-1564	174	16	and	and	CCONJ
eurjchem-1564	174	17	incubated	incubate	VERB
eurjchem-1564	174	18	at	at	ADP
eurjchem-1564	174	19	37	37	NUM
eurjchem-1564	174	20	°	°	NOUN
eurjchem-1564	174	21	c	c	NOUN
eurjchem-1564	174	22	for	for	ADP
eurjchem-1564	174	23	24	24	NUM
eurjchem-1564	174	24	hr	hr	NOUN
eurjchem-1564	174	25	.	.	PUNCT
eurjchem-1564	175	1	sterile	sterile	ADJ
eurjchem-1564	175	2	nutrient	nutrient	NOUN
eurjchem-1564	175	3	agar	agar	NOUN
eurjchem-1564	175	4	plates	plate	NOUN
eurjchem-1564	175	5	were	be	AUX
eurjchem-1564	175	6	also	also	ADV
eurjchem-1564	175	7	prepared	prepared	ADJ
eurjchem-1564	175	8	and	and	CCONJ
eurjchem-1564	175	9	holes	hole	NOUN
eurjchem-1564	175	10	of	of	ADP
eurjchem-1564	175	11	5	5	NUM
eurjchem-1564	175	12	mm	mm	NOUN
eurjchem-1564	175	13	diameter	diameter	NOUN
eurjchem-1564	175	14	were	be	AUX
eurjchem-1564	175	15	cut	cut	VERB
eurjchem-1564	175	16	.	.	PUNCT
eurjchem-1564	176	1	the	the	DET
eurjchem-1564	176	2	test	test	NOUN
eurjchem-1564	176	3	organisms	organism	NOUN
eurjchem-1564	176	4	after	after	ADP
eurjchem-1564	176	5	24	24	NUM
eurjchem-1564	176	6	hr	hr	NOUN
eurjchem-1564	176	7	of	of	ADP
eurjchem-1564	176	8	incubation	incubation	NOUN
eurjchem-1564	176	9	were	be	AUX
eurjchem-1564	176	10	spread	spread	VERB
eurjchem-1564	176	11	onto	onto	ADP
eurjchem-1564	176	12	separate	separate	ADJ
eurjchem-1564	176	13	agar	agar	NOUN
eurjchem-1564	176	14	plates	plate	NOUN
eurjchem-1564	176	15	.	.	PUNCT
eurjchem-1564	177	1	the	the	DET
eurjchem-1564	177	2	compounds	compound	NOUN
eurjchem-1564	177	3	which	which	PRON
eurjchem-1564	177	4	dissolved	dissolve	VERB
eurjchem-1564	177	5	in	in	ADP
eurjchem-1564	177	6	dmso	dmso	NOUN
eurjchem-1564	177	7	were	be	AUX
eurjchem-1564	177	8	poured	pour	VERB
eurjchem-1564	177	9	into	into	ADP
eurjchem-1564	177	10	labeled	label	VERB
eurjchem-1564	177	11	holes	hole	NOUN
eurjchem-1564	177	12	.	.	PUNCT
eurjchem-1564	178	1	the	the	DET
eurjchem-1564	178	2	plates	plate	NOUN
eurjchem-1564	178	3	of	of	ADP
eurjchem-1564	178	4	each	each	DET
eurjchem-1564	178	5	bacterial	bacterial	ADJ
eurjchem-1564	178	6	strain	strain	NOUN
eurjchem-1564	178	7	were	be	AUX
eurjchem-1564	178	8	prepared	prepare	VERB
eurjchem-1564	178	9	.	.	PUNCT
eurjchem-1564	179	1	the	the	DET
eurjchem-1564	179	2	plates	plate	NOUN
eurjchem-1564	179	3	were	be	AUX
eurjchem-1564	179	4	incubated	incubate	VERB
eurjchem-1564	179	5	aerobically	aerobically	ADV
eurjchem-1564	179	6	at	at	ADP
eurjchem-1564	179	7	37	37	NUM
eurjchem-1564	179	8	°	°	ADP
eurjchem-1564	179	9	c	c	NOUN
eurjchem-1564	179	10	for	for	ADP
eurjchem-1564	179	11	24	24	NUM
eurjchem-1564	179	12	hr	hr	NOUN
eurjchem-1564	179	13	.	.	PUNCT
eurjchem-1564	180	1	the	the	DET
eurjchem-1564	180	2	antimicrobial	antimicrobial	ADJ
eurjchem-1564	180	3	activity	activity	NOUN
eurjchem-1564	180	4	was	be	AUX
eurjchem-1564	180	5	determined	determine	VERB
eurjchem-1564	180	6	by	by	ADP
eurjchem-1564	180	7	measuring	measure	VERB
eurjchem-1564	180	8	the	the	DET
eurjchem-1564	180	9	diameter	diameter	NOUN
eurjchem-1564	180	10	of	of	ADP
eurjchem-1564	180	11	the	the	DET
eurjchem-1564	180	12	zone	zone	NOUN
eurjchem-1564	180	13	(	(	PUNCT
eurjchem-1564	180	14	mm	mm	NOUN
eurjchem-1564	180	15	)	)	PUNCT
eurjchem-1564	180	16	showing	show	VERB
eurjchem-1564	180	17	a	a	DET
eurjchem-1564	180	18	complete	complete	ADJ
eurjchem-1564	180	19	inhibition	inhibition	NOUN
eurjchem-1564	180	20	with	with	ADP
eurjchem-1564	180	21	respect	respect	NOUN
eurjchem-1564	180	22	to	to	ADP
eurjchem-1564	180	23	control	control	NOUN
eurjchem-1564	180	24	(	(	PUNCT
eurjchem-1564	180	25	dmso	dmso	NOUN
eurjchem-1564	180	26	)	)	PUNCT
eurjchem-1564	180	27	.	.	PUNCT
eurjchem-1564	181	1	2.4	2.4	NUM
eurjchem-1564	181	2	.	.	PUNCT
eurjchem-1564	182	1	dna	dna	PROPN
eurjchem-1564	182	2	concentration	concentration	NOUN
eurjchem-1564	182	3	dna	dna	PROPN
eurjchem-1564	182	4	concentration	concentration	NOUN
eurjchem-1564	182	5	per	per	ADP
eurjchem-1564	182	6	nucleotides	nucleotide	NOUN
eurjchem-1564	182	7	was	be	AUX
eurjchem-1564	182	8	determined	determine	VERB
eurjchem-1564	182	9	by	by	ADP
eurjchem-1564	182	10	electronic	electronic	ADJ
eurjchem-1564	182	11	absorption	absorption	NOUN
eurjchem-1564	182	12	spectroscopy	spectroscopy	NOUN
eurjchem-1564	182	13	at	at	ADP
eurjchem-1564	182	14	λmax	λmax	NOUN
eurjchem-1564	182	15	=	=	SYM
eurjchem-1564	182	16	260	260	NUM
eurjchem-1564	182	17	nm	nm	NOUN
eurjchem-1564	182	18	in	in	ADP
eurjchem-1564	182	19	human	human	ADJ
eurjchem-1564	182	20	blood	blood	NOUN
eurjchem-1564	182	21	,	,	PUNCT
eurjchem-1564	182	22	and	and	CCONJ
eurjchem-1564	182	23	each	each	DET
eurjchem-1564	182	24	1	1	NUM
eurjchem-1564	182	25	absorption	absorption	NOUN
eurjchem-1564	182	26	unit	unit	NOUN
eurjchem-1564	182	27	(	(	PUNCT
eurjchem-1564	182	28	au	au	PROPN
eurjchem-1564	182	29	)	)	PUNCT
eurjchem-1564	182	30	=	=	SYM
eurjchem-1564	182	31	50	50	NUM
eurjchem-1564	182	32	µg	µg	ADV
eurjchem-1564	182	33	dna	dna	PROPN
eurjchem-1564	182	34	/	/	SYM
eurjchem-1564	182	35	ml	ml	X
eurjchem-1564	182	36	at	at	ADP
eurjchem-1564	182	37	258	258	NUM
eurjchem-1564	182	38	nm	nm	NOUN
eurjchem-1564	182	39	.	.	PUNCT
eurjchem-1564	183	1	al‐fregi	al‐fregi	NUM
eurjchem-1564	183	2	et	et	VERB
eurjchem-1564	183	3	al	al	PROPN
eurjchem-1564	183	4	.	.	PUNCT
eurjchem-1564	183	5	/	/	SYM
eurjchem-1564	183	6	european	european	PROPN
eurjchem-1564	183	7	journal	journal	PROPN
eurjchem-1564	183	8	of	of	ADP
eurjchem-1564	183	9	chemistry	chemistry	NOUN
eurjchem-1564	183	10	8	8	NUM
eurjchem-1564	183	11	(	(	PUNCT
eurjchem-1564	183	12	2	2	NUM
eurjchem-1564	183	13	)	)	PUNCT
eurjchem-1564	183	14	(	(	PUNCT
eurjchem-1564	183	15	2017	2017	NUM
eurjchem-1564	183	16	)	)	PUNCT
eurjchem-1564	183	17	155‐161	155‐161	NUM
eurjchem-1564	183	18	159	159	NUM
eurjchem-1564	183	19	2.4.1	2.4.1	NUM
eurjchem-1564	183	20	.	.	PUNCT
eurjchem-1564	184	1	study	study	NOUN
eurjchem-1564	184	2	of	of	ADP
eurjchem-1564	184	3	palladium	palladium	NOUN
eurjchem-1564	184	4	(	(	PUNCT
eurjchem-1564	184	5	ii	ii	NOUN
eurjchem-1564	184	6	)	)	PUNCT
eurjchem-1564	184	7	complexes‐human	complexes‐human	NOUN
eurjchem-1564	184	8	dna	dna	PROPN
eurjchem-1564	184	9	interaction	interaction	NOUN
eurjchem-1564	184	10	the	the	DET
eurjchem-1564	184	11	binding	binding	NOUN
eurjchem-1564	184	12	of	of	ADP
eurjchem-1564	184	13	the	the	DET
eurjchem-1564	184	14	prepared	prepare	VERB
eurjchem-1564	184	15	palladium(ii	palladium(ii	NOUN
eurjchem-1564	184	16	)	)	PUNCT
eurjchem-1564	184	17	complexes	complex	NOUN
eurjchem-1564	184	18	1‐8	1‐8	PROPN
eurjchem-1564	184	19	with	with	ADP
eurjchem-1564	184	20	dna	dna	PROPN
eurjchem-1564	184	21	were	be	AUX
eurjchem-1564	184	22	studied	study	VERB
eurjchem-1564	184	23	by	by	ADP
eurjchem-1564	184	24	following	follow	VERB
eurjchem-1564	184	25	of	of	ADP
eurjchem-1564	184	26	the	the	DET
eurjchem-1564	184	27	change	change	NOUN
eurjchem-1564	184	28	of	of	ADP
eurjchem-1564	184	29	their	their	PRON
eurjchem-1564	184	30	absorbance	absorbance	NOUN
eurjchem-1564	184	31	(	(	PUNCT
eurjchem-1564	184	32	concentrations	concentration	NOUN
eurjchem-1564	184	33	)	)	PUNCT
eurjchem-1564	184	34	over	over	ADP
eurjchem-1564	184	35	time	time	NOUN
eurjchem-1564	184	36	with	with	ADP
eurjchem-1564	184	37	u.v.‐visible	u.v.‐visible	ADJ
eurjchem-1564	184	38	spect‐	spect‐	PUNCT
eurjchem-1564	184	39	roscopy	roscopy	VERB
eurjchem-1564	184	40	technique	technique	NOUN
eurjchem-1564	184	41	as	as	ADP
eurjchem-1564	184	42	following	follow	VERB
eurjchem-1564	184	43	:	:	PUNCT
eurjchem-1564	184	44	(	(	PUNCT
eurjchem-1564	184	45	i	i	NOUN
eurjchem-1564	184	46	)	)	PUNCT
eurjchem-1564	184	47	absorbance	absorbance	NOUN
eurjchem-1564	184	48	of	of	ADP
eurjchem-1564	184	49	dmso	dmso	ADJ
eurjchem-1564	184	50	solutions	solution	NOUN
eurjchem-1564	184	51	(	(	PUNCT
eurjchem-1564	184	52	80	80	NUM
eurjchem-1564	184	53	µm	µm	NOUN
eurjchem-1564	184	54	)	)	PUNCT
eurjchem-1564	184	55	of	of	ADP
eurjchem-1564	184	56	complexes	complex	NOUN
eurjchem-1564	184	57	1‐8	1‐8	PROPN
eurjchem-1564	184	58	were	be	AUX
eurjchem-1564	184	59	measured	measure	VERB
eurjchem-1564	184	60	at	at	ADP
eurjchem-1564	184	61	200‐	200‐	NUM
eurjchem-1564	184	62	800	800	NUM
eurjchem-1564	184	63	nm	nm	NOUN
eurjchem-1564	184	64	.	.	PUNCT
eurjchem-1564	185	1	(	(	PUNCT
eurjchem-1564	185	2	ii	ii	NOUN
eurjchem-1564	185	3	)	)	PUNCT
eurjchem-1564	185	4	absorbance	absorbance	NOUN
eurjchem-1564	185	5	of	of	ADP
eurjchem-1564	185	6	mixture	mixture	NOUN
eurjchem-1564	185	7	(	(	PUNCT
eurjchem-1564	185	8	0.1	0.1	NUM
eurjchem-1564	185	9	ml	ml	NOUN
eurjchem-1564	185	10	of	of	ADP
eurjchem-1564	185	11	human	human	ADJ
eurjchem-1564	185	12	dna	dna	PROPN
eurjchem-1564	185	13	and	and	CCONJ
eurjchem-1564	185	14	3	3	NUM
eurjchem-1564	185	15	ml	ml	NOUN
eurjchem-1564	185	16	of	of	ADP
eurjchem-1564	185	17	80	80	NUM
eurjchem-1564	185	18	µm	µm	NOUN
eurjchem-1564	185	19	of	of	ADP
eurjchem-1564	185	20	the	the	DET
eurjchem-1564	185	21	prepared	prepared	ADJ
eurjchem-1564	185	22	complexes	complex	NOUN
eurjchem-1564	185	23	1‐8	1‐8	NUM
eurjchem-1564	185	24	,	,	PUNCT
eurjchem-1564	185	25	respectively	respectively	ADV
eurjchem-1564	185	26	)	)	PUNCT
eurjchem-1564	185	27	were	be	AUX
eurjchem-1564	185	28	measured	measure	VERB
eurjchem-1564	185	29	at	at	ADP
eurjchem-1564	185	30	200‐800	200‐800	NUM
eurjchem-1564	185	31	nm	nm	ADJ
eurjchem-1564	185	32	range	range	NOUN
eurjchem-1564	185	33	at	at	ADP
eurjchem-1564	185	34	different	different	ADJ
eurjchem-1564	185	35	period	period	NOUN
eurjchem-1564	185	36	of	of	ADP
eurjchem-1564	185	37	time	time	NOUN
eurjchem-1564	185	38	(	(	PUNCT
eurjchem-1564	185	39	i.e.	i.e.	X
eurjchem-1564	185	40	at	at	ADP
eurjchem-1564	185	41	time	time	NOUN
eurjchem-1564	185	42	=	=	SYM
eurjchem-1564	185	43	0	0	NUM
eurjchem-1564	185	44	,	,	PUNCT
eurjchem-1564	185	45	1	1	NUM
eurjchem-1564	185	46	,	,	PUNCT
eurjchem-1564	185	47	2	2	NUM
eurjchem-1564	185	48	,	,	PUNCT
eurjchem-1564	185	49	and	and	CCONJ
eurjchem-1564	185	50	24	24	NUM
eurjchem-1564	185	51	h	h	NOUN
eurjchem-1564	185	52	)	)	PUNCT
eurjchem-1564	185	53	(	(	PUNCT
eurjchem-1564	185	54	table	table	NOUN
eurjchem-1564	185	55	2	2	NUM
eurjchem-1564	185	56	)	)	PUNCT
eurjchem-1564	186	1	[	[	X
eurjchem-1564	186	2	24	24	NUM
eurjchem-1564	186	3	]	]	PUNCT
eurjchem-1564	186	4	.	.	PUNCT
eurjchem-1564	187	1	2.4.2	2.4.2	NUM
eurjchem-1564	187	2	.	.	PUNCT
eurjchem-1564	187	3	extraction	extraction	NOUN
eurjchem-1564	187	4	of	of	ADP
eurjchem-1564	187	5	human	human	ADJ
eurjchem-1564	187	6	dna	dna	PROPN
eurjchem-1564	187	7	human	human	PROPN
eurjchem-1564	187	8	dna	dna	PROPN
eurjchem-1564	187	9	was	be	AUX
eurjchem-1564	187	10	extracted	extract	VERB
eurjchem-1564	187	11	from	from	ADP
eurjchem-1564	187	12	human	human	ADJ
eurjchem-1564	187	13	blood	blood	NOUN
eurjchem-1564	187	14	by	by	ADP
eurjchem-1564	187	15	sambrook	sambrook	NOUN
eurjchem-1564	187	16	method	method	NOUN
eurjchem-1564	187	17	[	[	X
eurjchem-1564	187	18	25	25	NUM
eurjchem-1564	187	19	]	]	PUNCT
eurjchem-1564	187	20	:	:	PUNCT
eurjchem-1564	187	21	to	to	ADP
eurjchem-1564	187	22	special	special	ADJ
eurjchem-1564	187	23	test	test	NOUN
eurjchem-1564	187	24	tube	tube	NOUN
eurjchem-1564	187	25	containing	contain	VERB
eurjchem-1564	187	26	1.0	1.0	NUM
eurjchem-1564	187	27	ml	ml	NOUN
eurjchem-1564	187	28	of	of	ADP
eurjchem-1564	187	29	human	human	ADJ
eurjchem-1564	187	30	blood	blood	NOUN
eurjchem-1564	187	31	,	,	PUNCT
eurjchem-1564	187	32	0.6	0.6	NUM
eurjchem-1564	187	33	ml	ml	NOUN
eurjchem-1564	187	34	of	of	ADP
eurjchem-1564	187	35	rbc	rbc	PROPN
eurjchem-1564	187	36	buffer	buffer	NOUN
eurjchem-1564	187	37	was	be	AUX
eurjchem-1564	187	38	added	add	VERB
eurjchem-1564	187	39	,	,	PUNCT
eurjchem-1564	187	40	and	and	CCONJ
eurjchem-1564	187	41	then	then	ADV
eurjchem-1564	187	42	the	the	DET
eurjchem-1564	187	43	result	result	NOUN
eurjchem-1564	187	44	mixture	mixture	NOUN
eurjchem-1564	187	45	was	be	AUX
eurjchem-1564	187	46	centrifuged	centrifuge	VERB
eurjchem-1564	187	47	at	at	ADP
eurjchem-1564	187	48	5000	5000	NUM
eurjchem-1564	187	49	cycle	cycle	NOUN
eurjchem-1564	187	50	/	/	SYM
eurjchem-1564	187	51	min	min	NOUN
eurjchem-1564	187	52	for	for	ADP
eurjchem-1564	187	53	15	15	NUM
eurjchem-1564	187	54	min	min	NOUN
eurjchem-1564	187	55	repeatedly	repeatedly	ADV
eurjchem-1564	187	56	.	.	PUNCT
eurjchem-1564	188	1	several	several	ADJ
eurjchem-1564	188	2	times	time	NOUN
eurjchem-1564	188	3	and	and	CCONJ
eurjchem-1564	188	4	then	then	ADV
eurjchem-1564	188	5	the	the	DET
eurjchem-1564	188	6	white	white	PROPN
eurjchem-1564	188	7	precipitate	precipitate	NOUN
eurjchem-1564	188	8	were	be	AUX
eurjchem-1564	188	9	obtained	obtain	VERB
eurjchem-1564	188	10	.	.	PUNCT
eurjchem-1564	189	1	to	to	ADP
eurjchem-1564	189	2	the	the	DET
eurjchem-1564	189	3	formed	form	VERB
eurjchem-1564	189	4	precipitate	precipitate	NOUN
eurjchem-1564	189	5	though	though	ADV
eurjchem-1564	189	6	,	,	PUNCT
eurjchem-1564	189	7	a	a	DET
eurjchem-1564	189	8	mixture	mixture	NOUN
eurjchem-1564	189	9	of	of	ADP
eurjchem-1564	189	10	0.6	0.6	NUM
eurjchem-1564	189	11	ml	ml	NOUN
eurjchem-1564	189	12	of	of	ADP
eurjchem-1564	189	13	sodium	sodium	NOUN
eurjchem-1564	189	14	dodecyl	dodecyl	NOUN
eurjchem-1564	189	15	sulfate	sulfate	NOUN
eurjchem-1564	189	16	and	and	CCONJ
eurjchem-1564	189	17	0.03	0.03	NUM
eurjchem-1564	189	18	ml	ml	NOUN
eurjchem-1564	189	19	of	of	ADP
eurjchem-1564	189	20	proteinase	proteinase	PROPN
eurjchem-1564	189	21	k	k	PROPN
eurjchem-1564	189	22	and	and	CCONJ
eurjchem-1564	189	23	0.03	0.03	NUM
eurjchem-1564	189	24	ml	ml	NOUN
eurjchem-1564	189	25	of	of	ADP
eurjchem-1564	189	26	nlb	nlb	PROPN
eurjchem-1564	189	27	was	be	AUX
eurjchem-1564	189	28	added	add	VERB
eurjchem-1564	189	29	,	,	PUNCT
eurjchem-1564	189	30	then	then	ADV
eurjchem-1564	189	31	after	after	ADP
eurjchem-1564	189	32	that	that	SCONJ
eurjchem-1564	189	33	it	it	PRON
eurjchem-1564	189	34	was	be	AUX
eurjchem-1564	189	35	occupied	occupy	VERB
eurjchem-1564	189	36	in	in	ADP
eurjchem-1564	189	37	water	water	NOUN
eurjchem-1564	189	38	bath	bath	NOUN
eurjchem-1564	189	39	at	at	ADP
eurjchem-1564	189	40	65	65	NUM
eurjchem-1564	189	41	°	°	NOUN
eurjchem-1564	189	42	c	c	NOUN
eurjchem-1564	189	43	for	for	ADP
eurjchem-1564	189	44	2h	2h	NUM
eurjchem-1564	189	45	.	.	PUNCT
eurjchem-1564	190	1	after	after	SCONJ
eurjchem-1564	190	2	the	the	DET
eurjchem-1564	190	3	incubating	incubate	VERB
eurjchem-1564	190	4	time	time	NOUN
eurjchem-1564	190	5	was	be	AUX
eurjchem-1564	190	6	ended	end	VERB
eurjchem-1564	190	7	up	up	ADP
eurjchem-1564	190	8	,	,	PUNCT
eurjchem-1564	190	9	0.1	0.1	NUM
eurjchem-1564	190	10	ml	ml	NOUN
eurjchem-1564	190	11	of	of	ADP
eurjchem-1564	190	12	5	5	NUM
eurjchem-1564	190	13	m	m	PROPN
eurjchem-1564	190	14	nacl	nacl	ADJ
eurjchem-1564	190	15	solution	solution	NOUN
eurjchem-1564	190	16	was	be	AUX
eurjchem-1564	190	17	added	add	VERB
eurjchem-1564	190	18	and	and	CCONJ
eurjchem-1564	190	19	re‐	re‐	NOUN
eurjchem-1564	190	20	incubated	incubate	VERB
eurjchem-1564	190	21	in	in	ADP
eurjchem-1564	190	22	water	water	NOUN
eurjchem-1564	190	23	bath	bath	NOUN
eurjchem-1564	190	24	at	at	ADP
eurjchem-1564	190	25	65	65	NUM
eurjchem-1564	190	26	°	°	NOUN
eurjchem-1564	190	27	c	c	NOUN
eurjchem-1564	190	28	for	for	ADP
eurjchem-1564	190	29	10	10	NUM
eurjchem-1564	190	30	min	min	NOUN
eurjchem-1564	190	31	.	.	NOUN
eurjchem-1564	191	1	after	after	ADP
eurjchem-1564	191	2	that	that	PRON
eurjchem-1564	191	3	,	,	PUNCT
eurjchem-1564	191	4	0.75	0.75	NUM
eurjchem-1564	191	5	ml	ml	NOUN
eurjchem-1564	191	6	of	of	ADP
eurjchem-1564	191	7	chloroform‐isopropyl	chloroform‐isopropyl	PROPN
eurjchem-1564	191	8	alcohol	alcohol	NOUN
eurjchem-1564	191	9	(	(	PUNCT
eurjchem-1564	191	10	24:1	24:1	NUM
eurjchem-1564	191	11	)	)	PUNCT
eurjchem-1564	191	12	was	be	AUX
eurjchem-1564	191	13	added	add	VERB
eurjchem-1564	191	14	for	for	ADP
eurjchem-1564	191	15	every	every	DET
eurjchem-1564	191	16	sample	sample	NOUN
eurjchem-1564	191	17	,	,	PUNCT
eurjchem-1564	191	18	and	and	CCONJ
eurjchem-1564	191	19	then	then	ADV
eurjchem-1564	191	20	it	it	PRON
eurjchem-1564	191	21	was	be	AUX
eurjchem-1564	191	22	centrifuged	centrifuge	VERB
eurjchem-1564	191	23	at	at	ADP
eurjchem-1564	191	24	12000	12000	NUM
eurjchem-1564	191	25	cycle	cycle	NOUN
eurjchem-1564	191	26	/	/	SYM
eurjchem-1564	191	27	min	min	NOUN
eurjchem-1564	191	28	for	for	ADP
eurjchem-1564	191	29	8	8	NUM
eurjchem-1564	191	30	min	min	NOUN
eurjchem-1564	191	31	.	.	PROPN
eurjchem-1564	191	32	therefore	therefore	ADV
eurjchem-1564	191	33	,	,	PUNCT
eurjchem-1564	191	34	three	three	NUM
eurjchem-1564	191	35	layers	layer	NOUN
eurjchem-1564	191	36	were	be	AUX
eurjchem-1564	191	37	obtained	obtain	VERB
eurjchem-1564	191	38	,	,	PUNCT
eurjchem-1564	191	39	the	the	DET
eurjchem-1564	191	40	upper	upper	ADJ
eurjchem-1564	191	41	layer	layer	NOUN
eurjchem-1564	191	42	was	be	AUX
eurjchem-1564	191	43	selected	select	VERB
eurjchem-1564	191	44	and	and	CCONJ
eurjchem-1564	191	45	then	then	ADV
eurjchem-1564	191	46	0.55	0.55	NUM
eurjchem-1564	191	47	ml	ml	NOUN
eurjchem-1564	191	48	of	of	ADP
eurjchem-1564	191	49	cold	cold	ADJ
eurjchem-1564	191	50	absolute	absolute	ADJ
eurjchem-1564	191	51	ethanol	ethanol	NOUN
eurjchem-1564	191	52	was	be	AUX
eurjchem-1564	191	53	added	add	VERB
eurjchem-1564	191	54	and	and	CCONJ
eurjchem-1564	191	55	was	be	AUX
eurjchem-1564	191	56	kept	keep	VERB
eurjchem-1564	191	57	deep	deep	ADJ
eurjchem-1564	191	58	freezer	freezer	NOUN
eurjchem-1564	191	59	at	at	ADP
eurjchem-1564	191	60	‐20	‐20	PROPN
eurjchem-1564	191	61	°	°	PROPN
eurjchem-1564	191	62	c	c	NOUN
eurjchem-1564	191	63	.	.	PUNCT
eurjchem-1564	192	1	3	3	X
eurjchem-1564	192	2	.	.	NOUN
eurjchem-1564	192	3	results	result	NOUN
eurjchem-1564	192	4	and	and	CCONJ
eurjchem-1564	192	5	discussion	discussion	NOUN
eurjchem-1564	192	6	eight	eight	NUM
eurjchem-1564	192	7	complexes	complex	NOUN
eurjchem-1564	192	8	of	of	ADP
eurjchem-1564	192	9	palladium(ii	palladium(ii	NOUN
eurjchem-1564	192	10	)	)	PUNCT
eurjchem-1564	192	11	were	be	AUX
eurjchem-1564	192	12	synthesized	synthesize	VERB
eurjchem-1564	192	13	by	by	ADP
eurjchem-1564	192	14	reacting	react	VERB
eurjchem-1564	192	15	of	of	ADP
eurjchem-1564	192	16	dibenzonitrile	dibenzonitrile	ADJ
eurjchem-1564	192	17	dichloropalladium(ii	dichloropalladium(ii	NOUN
eurjchem-1564	192	18	)	)	PUNCT
eurjchem-1564	192	19	with	with	ADP
eurjchem-1564	192	20	n‐(3‐	n‐(3‐	PROPN
eurjchem-1564	192	21	phenyl	phenyl	PROPN
eurjchem-1564	192	22	propyl)ethane‐1	propyl)ethane‐1	PROPN
eurjchem-1564	192	23	,	,	PUNCT
eurjchem-1564	192	24	2‐diamine	2‐diamine	NUM
eurjchem-1564	192	25	,	,	PUNCT
eurjchem-1564	192	26	n	n	CCONJ
eurjchem-1564	192	27	,	,	PUNCT
eurjchem-1564	192	28	n'‐bis(3‐phenylpropyl	n'‐bis(3‐phenylpropyl	ADJ
eurjchem-1564	192	29	)	)	PUNCT
eurjchem-1564	192	30	ethane‐1	ethane‐1	PROPN
eurjchem-1564	192	31	,	,	PUNCT
eurjchem-1564	192	32	2‐diamine	2‐diamine	NUM
eurjchem-1564	192	33	,	,	PUNCT
eurjchem-1564	192	34	n‐2‐furan	n‐2‐furan	PROPN
eurjchem-1564	192	35	methyledinebenzene‐1	methyledinebenzene‐1	PROPN
eurjchem-1564	192	36	,	,	PUNCT
eurjchem-1564	192	37	2‐di‐	2‐di‐	NUM
eurjchem-1564	192	38	amine	amine	NOUN
eurjchem-1564	192	39	,	,	PUNCT
eurjchem-1564	192	40	n	n	CCONJ
eurjchem-1564	192	41	,	,	PUNCT
eurjchem-1564	192	42	n'‐bis(2‐furanmethyledine)benzene‐1	n'‐bis(2‐furanmethyledine)benzene‐1	PROPN
eurjchem-1564	192	43	,	,	PUNCT
eurjchem-1564	192	44	2‐diamine	2‐diamine	NUM
eurjchem-1564	192	45	,	,	PUNCT
eurjchem-1564	192	46	n‐	n‐	PROPN
eurjchem-1564	192	47	ferrocen	ferrocen	PROPN
eurjchem-1564	192	48	methyledinebenzene‐1,2‐diamine	methyledinebenzene‐1,2‐diamine	PROPN
eurjchem-1564	192	49	,	,	PUNCT
eurjchem-1564	192	50	n	n	CCONJ
eurjchem-1564	192	51	,	,	PUNCT
eurjchem-1564	192	52	n'‐bis(ferrocene	n'‐bis(ferrocene	PROPN
eurjchem-1564	192	53	methyledine)benzene‐1	methyledine)benzene‐1	PROPN
eurjchem-1564	192	54	,	,	PUNCT
eurjchem-1564	192	55	2‐diamine	2‐diamine	NUM
eurjchem-1564	192	56	,	,	PUNCT
eurjchem-1564	192	57	n‐1‐ferrocenethylidene	n‐1‐ferrocenethylidene	PROPN
eurjchem-1564	192	58	benzene‐1	benzene‐1	PROPN
eurjchem-1564	192	59	,	,	PUNCT
eurjchem-1564	192	60	2‐diamin	2‐diamin	NUM
eurjchem-1564	192	61	,	,	PUNCT
eurjchem-1564	192	62	n	n	CCONJ
eurjchem-1564	192	63	,	,	PUNCT
eurjchem-1564	192	64	n'‐bis(ferrocenethylidene	n'‐bis(ferrocenethylidene	ADJ
eurjchem-1564	192	65	)	)	PUNCT
eurjchem-1564	192	66	benzene‐	benzene‐	NUM
eurjchem-1564	192	67	1,2‐diamine	1,2‐diamine	NUM
eurjchem-1564	192	68	,	,	PUNCT
eurjchem-1564	192	69	respectively	respectively	ADV
eurjchem-1564	192	70	,	,	PUNCT
eurjchem-1564	192	71	in	in	ADP
eurjchem-1564	192	72	absolute	absolute	ADJ
eurjchem-1564	192	73	ethanol	ethanol	NOUN
eurjchem-1564	192	74	at	at	ADP
eurjchem-1564	192	75	room	room	NOUN
eurjchem-1564	192	76	temperature	temperature	NOUN
eurjchem-1564	192	77	for	for	ADP
eurjchem-1564	192	78	48	48	NUM
eurjchem-1564	192	79	h	h	NOUN
eurjchem-1564	192	80	,	,	PUNCT
eurjchem-1564	192	81	scheme	scheme	NOUN
eurjchem-1564	192	82	1‐4	1‐4	NOUN
eurjchem-1564	192	83	.	.	PUNCT
eurjchem-1564	193	1	in	in	ADP
eurjchem-1564	193	2	general	general	ADJ
eurjchem-1564	193	3	,	,	PUNCT
eurjchem-1564	193	4	all	all	DET
eurjchem-1564	193	5	the	the	DET
eurjchem-1564	193	6	prepared	prepare	VERB
eurjchem-1564	193	7	palladium(ii	palladium(ii	NOUN
eurjchem-1564	193	8	)	)	PUNCT
eurjchem-1564	193	9	complexes	complex	NOUN
eurjchem-1564	193	10	v1‐8	v1‐8	NOUN
eurjchem-1564	193	11	are	be	AUX
eurjchem-1564	193	12	pale	pale	ADJ
eurjchem-1564	193	13	yellow	yellow	ADJ
eurjchem-1564	193	14	to	to	ADP
eurjchem-1564	193	15	orange	orange	PROPN
eurjchem-1564	193	16	solids	solid	NOUN
eurjchem-1564	193	17	with	with	ADP
eurjchem-1564	193	18	moderate	moderate	ADJ
eurjchem-1564	193	19	melting	melting	NOUN
eurjchem-1564	193	20	points	point	NOUN
eurjchem-1564	193	21	(	(	PUNCT
eurjchem-1564	193	22	dec	dec	PROPN
eurjchem-1564	193	23	.	.	PROPN
eurjchem-1564	193	24	)	)	PUNCT
eurjchem-1564	194	1	ranged	range	VERB
eurjchem-1564	194	2	at	at	ADP
eurjchem-1564	194	3	75‐168	75‐168	NUM
eurjchem-1564	194	4	°	°	ADP
eurjchem-1564	194	5	c	c	NOUN
eurjchem-1564	194	6	,	,	PUNCT
eurjchem-1564	194	7	and	and	CCONJ
eurjchem-1564	194	8	they	they	PRON
eurjchem-1564	194	9	are	be	AUX
eurjchem-1564	194	10	soluble	soluble	ADJ
eurjchem-1564	194	11	in	in	ADP
eurjchem-1564	194	12	common	common	ADJ
eurjchem-1564	194	13	organic	organic	ADJ
eurjchem-1564	194	14	solvents	solvent	NOUN
eurjchem-1564	194	15	like	like	ADP
eurjchem-1564	194	16	carbon	carbon	NOUN
eurjchem-1564	194	17	tetrachloride	tetrachloride	NOUN
eurjchem-1564	194	18	,	,	PUNCT
eurjchem-1564	194	19	chloroform	chloroform	NOUN
eurjchem-1564	194	20	,	,	PUNCT
eurjchem-1564	194	21	dichloromethane	dichloromethane	NOUN
eurjchem-1564	194	22	,	,	PUNCT
eurjchem-1564	194	23	dimethylformamide	dimethylformamide	NOUN
eurjchem-1564	194	24	and	and	CCONJ
eurjchem-1564	194	25	dimethylsulfoxide	dimethylsulfoxide	ADV
eurjchem-1564	194	26	which	which	PRON
eurjchem-1564	194	27	indicate	indicate	VERB
eurjchem-1564	194	28	that	that	SCONJ
eurjchem-1564	194	29	these	these	DET
eurjchem-1564	194	30	complexes	complex	NOUN
eurjchem-1564	194	31	are	be	AUX
eurjchem-1564	194	32	neutral	neutral	ADJ
eurjchem-1564	194	33	.	.	PUNCT
eurjchem-1564	195	1	the	the	DET
eurjchem-1564	195	2	carbon	carbon	NOUN
eurjchem-1564	195	3	,	,	PUNCT
eurjchem-1564	195	4	hydrogen	hydrogen	NOUN
eurjchem-1564	195	5	,	,	PUNCT
eurjchem-1564	195	6	and	and	CCONJ
eurjchem-1564	195	7	nitrogen	nitrogen	NOUN
eurjchem-1564	195	8	analyses	analysis	NOUN
eurjchem-1564	195	9	for	for	ADP
eurjchem-1564	195	10	palladium(ii	palladium(ii	NOUN
eurjchem-1564	195	11	)	)	PUNCT
eurjchem-1564	195	12	complexes	complex	NOUN
eurjchem-1564	195	13	1‐8	1‐8	PROPN
eurjchem-1564	195	14	agreed	agree	VERB
eurjchem-1564	195	15	well	well	ADV
eurjchem-1564	195	16	with	with	ADP
eurjchem-1564	195	17	the	the	DET
eurjchem-1564	195	18	calculated	calculated	ADJ
eurjchem-1564	195	19	values	value	NOUN
eurjchem-1564	195	20	.	.	PUNCT
eurjchem-1564	196	1	elemental	elemental	ADJ
eurjchem-1564	196	2	analysis	analysis	NOUN
eurjchem-1564	196	3	of	of	ADP
eurjchem-1564	196	4	these	these	DET
eurjchem-1564	196	5	complexes	complex	NOUN
eurjchem-1564	196	6	showed	show	VERB
eurjchem-1564	196	7	that	that	SCONJ
eurjchem-1564	196	8	all	all	DET
eurjchem-1564	196	9	the	the	DET
eurjchem-1564	196	10	palladium(ii	palladium(ii	NOUN
eurjchem-1564	196	11	)	)	PUNCT
eurjchem-1564	196	12	ion	ion	NOUN
eurjchem-1564	196	13	to	to	ADP
eurjchem-1564	196	14	the	the	DET
eurjchem-1564	196	15	ligand	ligand	ADJ
eurjchem-1564	196	16	ratio	ratio	NOUN
eurjchem-1564	196	17	in	in	ADP
eurjchem-1564	196	18	the	the	DET
eurjchem-1564	196	19	dichloro	dichloro	NOUN
eurjchem-1564	196	20	complexes	complex	NOUN
eurjchem-1564	196	21	is	be	AUX
eurjchem-1564	196	22	1:1	1:1	NUM
eurjchem-1564	196	23	.	.	PUNCT
eurjchem-1564	197	1	due	due	ADP
eurjchem-1564	197	2	to	to	ADP
eurjchem-1564	197	3	geometrical	geometrical	ADJ
eurjchem-1564	197	4	reasons	reason	NOUN
eurjchem-1564	197	5	and	and	CCONJ
eurjchem-1564	197	6	the	the	DET
eurjchem-1564	197	7	nature	nature	NOUN
eurjchem-1564	197	8	of	of	ADP
eurjchem-1564	197	9	ligands	ligand	NOUN
eurjchem-1564	197	10	which	which	PRON
eurjchem-1564	197	11	are	be	AUX
eurjchem-1564	197	12	bidentate	bidentate	ADJ
eurjchem-1564	197	13	,	,	PUNCT
eurjchem-1564	197	14	we	we	PRON
eurjchem-1564	197	15	believe	believe	VERB
eurjchem-1564	197	16	that	that	SCONJ
eurjchem-1564	197	17	all	all	DET
eurjchem-1564	197	18	the	the	DET
eurjchem-1564	197	19	synthesized	synthesize	VERB
eurjchem-1564	197	20	complexes	complex	NOUN
eurjchem-1564	197	21	adapted	adapt	VERB
eurjchem-1564	197	22	to	to	ADP
eurjchem-1564	197	23	cis‐form	cis‐form	NOUN
eurjchem-1564	197	24	.	.	PUNCT
eurjchem-1564	198	1	the	the	DET
eurjchem-1564	198	2	molar	molar	ADJ
eurjchem-1564	198	3	conductivities	conductivity	NOUN
eurjchem-1564	198	4	were	be	AUX
eurjchem-1564	198	5	measured	measure	VERB
eurjchem-1564	198	6	for	for	ADP
eurjchem-1564	198	7	the	the	DET
eurjchem-1564	198	8	complexes	complex	NOUN
eurjchem-1564	198	9	1‐8	1‐8	PROPN
eurjchem-1564	198	10	in	in	ADP
eurjchem-1564	198	11	1×10‐3	1×10‐3	NUM
eurjchem-1564	198	12	m	m	PROPN
eurjchem-1564	198	13	solutions	solution	NOUN
eurjchem-1564	198	14	of	of	ADP
eurjchem-1564	198	15	dmso	dmso	ADJ
eurjchem-1564	198	16	solvents	solvent	NOUN
eurjchem-1564	198	17	at	at	ADP
eurjchem-1564	198	18	room	room	NOUN
eurjchem-1564	198	19	temperature	temperature	NOUN
eurjchem-1564	198	20	.	.	PUNCT
eurjchem-1564	199	1	the	the	DET
eurjchem-1564	199	2	molar	molar	ADJ
eurjchem-1564	199	3	conductance	conductance	NOUN
eurjchem-1564	199	4	of	of	ADP
eurjchem-1564	199	5	complexes	complex	NOUN
eurjchem-1564	199	6	1‐8	1‐8	PROPN
eurjchem-1564	199	7	were	be	AUX
eurjchem-1564	199	8	found	find	VERB
eurjchem-1564	199	9	at	at	ADP
eurjchem-1564	199	10	range	range	NOUN
eurjchem-1564	199	11	5.00‐8.50	5.00‐8.50	NUM
eurjchem-1564	199	12	ohm‐1.cm2.mol‐1	ohm‐1.cm2.mol‐1	NOUN
eurjchem-1564	199	13	.	.	PUNCT
eurjchem-1564	200	1	this	this	PRON
eurjchem-1564	200	2	indicates	indicate	VERB
eurjchem-1564	200	3	that	that	SCONJ
eurjchem-1564	200	4	these	these	DET
eurjchem-1564	200	5	complexes	complex	NOUN
eurjchem-1564	200	6	behave	behave	VERB
eurjchem-1564	200	7	as	as	ADP
eurjchem-1564	200	8	non‐electrolytes	non‐electrolyte	NOUN
eurjchem-1564	200	9	which	which	PRON
eurjchem-1564	200	10	are	be	AUX
eurjchem-1564	200	11	in	in	ADP
eurjchem-1564	200	12	agree	agree	ADJ
eurjchem-1564	200	13	well	well	ADV
eurjchem-1564	200	14	with	with	ADP
eurjchem-1564	200	15	previous	previous	ADJ
eurjchem-1564	200	16	literatures	literature	NOUN
eurjchem-1564	200	17	[	[	X
eurjchem-1564	200	18	26	26	NUM
eurjchem-1564	200	19	]	]	PUNCT
eurjchem-1564	200	20	.	.	PUNCT
eurjchem-1564	201	1	the	the	DET
eurjchem-1564	201	2	ir	ir	PROPN
eurjchem-1564	201	3	spectra	spectra	NOUN
eurjchem-1564	201	4	of	of	ADP
eurjchem-1564	201	5	all	all	DET
eurjchem-1564	201	6	new	new	ADJ
eurjchem-1564	201	7	synthesized	synthesize	VERB
eurjchem-1564	201	8	complexes	complex	NOUN
eurjchem-1564	201	9	1‐8	1‐8	PROPN
eurjchem-1564	201	10	display	display	NOUN
eurjchem-1564	201	11	common	common	ADJ
eurjchem-1564	201	12	feature	feature	NOUN
eurjchem-1564	201	13	in	in	ADP
eurjchem-1564	201	14	certain	certain	ADJ
eurjchem-1564	201	15	region	region	NOUN
eurjchem-1564	201	16	and	and	CCONJ
eurjchem-1564	201	17	characteristic	characteristic	ADJ
eurjchem-1564	201	18	bands	band	NOUN
eurjchem-1564	201	19	in	in	ADP
eurjchem-1564	201	20	the	the	DET
eurjchem-1564	201	21	fingerprint	fingerprint	NOUN
eurjchem-1564	201	22	and	and	CCONJ
eurjchem-1564	201	23	other	other	ADJ
eurjchem-1564	201	24	regions	region	NOUN
eurjchem-1564	201	25	.	.	PUNCT
eurjchem-1564	202	1	the	the	DET
eurjchem-1564	202	2	ir	ir	PROPN
eurjchem-1564	202	3	spectra	spectra	NOUN
eurjchem-1564	202	4	of	of	ADP
eurjchem-1564	202	5	complexes	complex	NOUN
eurjchem-1564	202	6	1	1	NUM
eurjchem-1564	202	7	,	,	PUNCT
eurjchem-1564	202	8	2	2	NUM
eurjchem-1564	202	9	,	,	PUNCT
eurjchem-1564	202	10	3	3	NUM
eurjchem-1564	202	11	,	,	PUNCT
eurjchem-1564	202	12	5	5	NUM
eurjchem-1564	202	13	and	and	CCONJ
eurjchem-1564	202	14	7	7	NUM
eurjchem-1564	202	15	show	show	VERB
eurjchem-1564	202	16	a	a	DET
eurjchem-1564	202	17	broad	broad	ADJ
eurjchem-1564	202	18	band	band	NOUN
eurjchem-1564	202	19	at	at	ADP
eurjchem-1564	202	20	3333‐3390	3333‐3390	NUM
eurjchem-1564	202	21	cm‐1	cm‐1	NOUN
eurjchem-1564	202	22	range	range	NOUN
eurjchem-1564	202	23	which	which	PRON
eurjchem-1564	202	24	attributed	attribute	VERB
eurjchem-1564	202	25	to	to	ADP
eurjchem-1564	202	26	n‐h	n‐h	PRON
eurjchem-1564	202	27	stretching	stretch	VERB
eurjchem-1564	202	28	[	[	X
eurjchem-1564	202	29	27,28	27,28	NOUN
eurjchem-1564	202	30	]	]	X
eurjchem-1564	202	31	.	.	PUNCT
eurjchem-1564	203	1	the	the	DET
eurjchem-1564	203	2	shift	shift	NOUN
eurjchem-1564	203	3	was	be	AUX
eurjchem-1564	203	4	observed	observe	VERB
eurjchem-1564	203	5	toward	toward	ADP
eurjchem-1564	203	6	low	low	ADJ
eurjchem-1564	203	7	frequency	frequency	NOUN
eurjchem-1564	203	8	for	for	ADP
eurjchem-1564	203	9	amino	amino	NOUN
eurjchem-1564	203	10	groups	group	NOUN
eurjchem-1564	203	11	than	than	ADP
eurjchem-1564	203	12	the	the	DET
eurjchem-1564	203	13	free	free	ADJ
eurjchem-1564	203	14	ligands	ligand	NOUN
eurjchem-1564	203	15	[	[	X
eurjchem-1564	203	16	21	21	NUM
eurjchem-1564	203	17	]	]	PUNCT
eurjchem-1564	203	18	at	at	ADP
eurjchem-1564	203	19	range	range	NOUN
eurjchem-1564	203	20	8‐58	8‐58	NUM
eurjchem-1564	203	21	cm‐1	cm‐1	NOUN
eurjchem-1564	203	22	due	due	ADP
eurjchem-1564	203	23	to	to	ADP
eurjchem-1564	203	24	the	the	DET
eurjchem-1564	203	25	coordination	coordination	NOUN
eurjchem-1564	203	26	of	of	ADP
eurjchem-1564	203	27	the	the	DET
eurjchem-1564	203	28	palladium(ii	palladium(ii	NOUN
eurjchem-1564	203	29	)	)	PUNCT
eurjchem-1564	203	30	ion	ion	NOUN
eurjchem-1564	203	31	with	with	ADP
eurjchem-1564	203	32	the	the	DET
eurjchem-1564	203	33	amino	amino	NOUN
eurjchem-1564	203	34	groups	group	NOUN
eurjchem-1564	203	35	.	.	PUNCT
eurjchem-1564	204	1	the	the	DET
eurjchem-1564	204	2	ir	ir	PROPN
eurjchem-1564	204	3	spectra	spectra	NOUN
eurjchem-1564	204	4	of	of	ADP
eurjchem-1564	204	5	complexes	complex	NOUN
eurjchem-1564	204	6	3‐8	3‐8	PROPN
eurjchem-1564	204	7	indicate	indicate	VERB
eurjchem-1564	204	8	a	a	DET
eurjchem-1564	204	9	strong	strong	ADJ
eurjchem-1564	204	10	band	band	NOUN
eurjchem-1564	204	11	at	at	ADP
eurjchem-1564	204	12	1610‐1656	1610‐1656	PROPN
eurjchem-1564	204	13	cm‐1	cm‐1	NOUN
eurjchem-1564	204	14	attributed	attribute	VERB
eurjchem-1564	204	15	to	to	ADP
eurjchem-1564	204	16	ch	ch	NOUN
eurjchem-1564	204	17	=	=	NOUN
eurjchem-1564	204	18	n	n	NOUN
eurjchem-1564	204	19	stretching	stretch	VERB
eurjchem-1564	204	20	[	[	X
eurjchem-1564	204	21	27,28	27,28	NUM
eurjchem-1564	204	22	]	]	X
eurjchem-1564	204	23	.	.	PUNCT
eurjchem-1564	205	1	this	this	DET
eurjchem-1564	205	2	band	band	NOUN
eurjchem-1564	205	3	shifted	shift	VERB
eurjchem-1564	205	4	to	to	ADP
eurjchem-1564	205	5	higher	high	ADJ
eurjchem-1564	205	6	frequency	frequency	NOUN
eurjchem-1564	205	7	at	at	ADP
eurjchem-1564	205	8	range	range	NOUN
eurjchem-1564	205	9	9‐45	9‐45	NUM
eurjchem-1564	205	10	cm‐1	cm‐1	NOUN
eurjchem-1564	205	11	compared	compare	VERB
eurjchem-1564	205	12	with	with	ADP
eurjchem-1564	205	13	the	the	DET
eurjchem-1564	205	14	corresponding	correspond	VERB
eurjchem-1564	205	15	ligands	ligand	NOUN
eurjchem-1564	205	16	could	could	AUX
eurjchem-1564	205	17	be	be	AUX
eurjchem-1564	205	18	considered	consider	VERB
eurjchem-1564	205	19	as	as	ADP
eurjchem-1564	205	20	coordinated	coordinated	ADJ
eurjchem-1564	205	21	azomethine	azomethine	NOUN
eurjchem-1564	205	22	groups	group	NOUN
eurjchem-1564	205	23	in	in	ADP
eurjchem-1564	205	24	these	these	DET
eurjchem-1564	205	25	ligands	ligand	NOUN
eurjchem-1564	205	26	with	with	ADP
eurjchem-1564	205	27	palladium	palladium	NOUN
eurjchem-1564	205	28	ion	ion	NOUN
eurjchem-1564	205	29	[	[	X
eurjchem-1564	205	30	27,28	27,28	NOUN
eurjchem-1564	205	31	]	]	X
eurjchem-1564	205	32	.	.	PUNCT
eurjchem-1564	206	1	these	these	DET
eurjchem-1564	206	2	shift	shift	NOUN
eurjchem-1564	206	3	can	can	AUX
eurjchem-1564	206	4	be	be	AUX
eurjchem-1564	206	5	attributed	attribute	VERB
eurjchem-1564	206	6	to	to	ADP
eurjchem-1564	206	7	the	the	DET
eurjchem-1564	206	8	π‐	π‐	ADJ
eurjchem-1564	206	9	back	back	NOUN
eurjchem-1564	206	10	donation	donation	NOUN
eurjchem-1564	206	11	between	between	ADP
eurjchem-1564	206	12	empty	empty	ADJ
eurjchem-1564	206	13	π	π	PROPN
eurjchem-1564	206	14	*	*	NOUN
eurjchem-1564	206	15	of	of	ADP
eurjchem-1564	206	16	ch	ch	NOUN
eurjchem-1564	206	17	=	=	NOUN
eurjchem-1564	206	18	n	n	NOUN
eurjchem-1564	206	19	and	and	CCONJ
eurjchem-1564	206	20	d‐orbitals	d‐orbital	NOUN
eurjchem-1564	206	21	of	of	ADP
eurjchem-1564	206	22	palladium(ii	palladium(ii	NOUN
eurjchem-1564	206	23	)	)	PUNCT
eurjchem-1564	206	24	ion	ion	NOUN
eurjchem-1564	206	25	.	.	PUNCT
eurjchem-1564	207	1	two	two	NUM
eurjchem-1564	207	2	strong	strong	ADJ
eurjchem-1564	207	3	bands	band	NOUN
eurjchem-1564	207	4	appeared	appear	VERB
eurjchem-1564	207	5	at	at	ADP
eurjchem-1564	207	6	the	the	DET
eurjchem-1564	207	7	range1458‐1566	range1458‐1566	ADJ
eurjchem-1564	207	8	and	and	CCONJ
eurjchem-1564	207	9	1375‐1466	1375‐1466	NUM
eurjchem-1564	207	10	cm‐1	cm‐1	NOUN
eurjchem-1564	207	11	which	which	PRON
eurjchem-1564	207	12	reveal	reveal	VERB
eurjchem-1564	207	13	that	that	SCONJ
eurjchem-1564	207	14	they	they	PRON
eurjchem-1564	207	15	attributed	attribute	VERB
eurjchem-1564	207	16	to	to	ADP
eurjchem-1564	207	17	asymmetrical	asymmetrical	ADJ
eurjchem-1564	207	18	and	and	CCONJ
eurjchem-1564	207	19	symmetrical	symmetrical	ADJ
eurjchem-1564	207	20	stretching	stretching	NOUN
eurjchem-1564	207	21	of	of	ADP
eurjchem-1564	207	22	aromatic	aromatic	ADJ
eurjchem-1564	207	23	c	c	NOUN
eurjchem-1564	207	24	=	=	SYM
eurjchem-1564	207	25	c	c	NOUN
eurjchem-1564	207	26	,	,	PUNCT
eurjchem-1564	207	27	respectively	respectively	ADV
eurjchem-1564	207	28	[	[	X
eurjchem-1564	207	29	27,28	27,28	NOUN
eurjchem-1564	207	30	]	]	X
eurjchem-1564	207	31	.	.	PUNCT
eurjchem-1564	208	1	the	the	DET
eurjchem-1564	208	2	ir	ir	PROPN
eurjchem-1564	208	3	spectra	spectra	NOUN
eurjchem-1564	208	4	of	of	ADP
eurjchem-1564	208	5	comp‐	comp‐	NOUN
eurjchem-1564	208	6	lexes	lexe	NOUN
eurjchem-1564	208	7	1‐8	1‐8	PROPN
eurjchem-1564	208	8	show	show	VERB
eurjchem-1564	208	9	a	a	DET
eurjchem-1564	208	10	weak	weak	ADJ
eurjchem-1564	208	11	band	band	NOUN
eurjchem-1564	208	12	in	in	ADP
eurjchem-1564	208	13	the	the	DET
eurjchem-1564	208	14	range	range	NOUN
eurjchem-1564	208	15	3022‐3092	3022‐3092	NUM
eurjchem-1564	208	16	cm‐1	cm‐1	NOUN
eurjchem-1564	208	17	due	due	ADP
eurjchem-1564	208	18	to	to	ADP
eurjchem-1564	208	19	aromatic	aromatic	ADJ
eurjchem-1564	208	20	c‐h	c‐h	PROPN
eurjchem-1564	208	21	stretching	stretch	VERB
eurjchem-1564	208	22	[	[	X
eurjchem-1564	208	23	28,29	28,29	NUM
eurjchem-1564	208	24	]	]	X
eurjchem-1564	208	25	.	.	PUNCT
eurjchem-1564	209	1	two	two	NUM
eurjchem-1564	209	2	weak	weak	ADJ
eurjchem-1564	209	3	bands	band	NOUN
eurjchem-1564	209	4	were	be	AUX
eurjchem-1564	209	5	appeared	appear	VERB
eurjchem-1564	209	6	at	at	ADP
eurjchem-1564	209	7	2924‐2933	2924‐2933	NUM
eurjchem-1564	209	8	and	and	CCONJ
eurjchem-1564	209	9	2853‐2862	2853‐2862	NUM
eurjchem-1564	209	10	cm‐1	cm‐1	NOUN
eurjchem-1564	209	11	due	due	ADP
eurjchem-1564	209	12	to	to	ADP
eurjchem-1564	209	13	asym‐	asym‐	CCONJ
eurjchem-1564	209	14	metrical	metrical	ADJ
eurjchem-1564	209	15	and	and	CCONJ
eurjchem-1564	209	16	symmetrical	symmetrical	ADJ
eurjchem-1564	209	17	stretching	stretching	NOUN
eurjchem-1564	209	18	of	of	ADP
eurjchem-1564	209	19	aliphatic	aliphatic	ADJ
eurjchem-1564	209	20	c‐h	c‐h	PROPN
eurjchem-1564	209	21	bands	band	NOUN
eurjchem-1564	209	22	,	,	PUNCT
eurjchem-1564	209	23	respectively	respectively	ADV
eurjchem-1564	209	24	[	[	X
eurjchem-1564	209	25	28,29	28,29	NUM
eurjchem-1564	209	26	]	]	PUNCT
eurjchem-1564	209	27	.	.	PUNCT
eurjchem-1564	210	1	furthermore	furthermore	ADV
eurjchem-1564	210	2	,	,	PUNCT
eurjchem-1564	210	3	three	three	NUM
eurjchem-1564	210	4	variable	variable	ADJ
eurjchem-1564	210	5	bands	band	NOUN
eurjchem-1564	210	6	between	between	ADP
eurjchem-1564	210	7	695‐772	695‐772	PROPN
eurjchem-1564	210	8	cm‐1	cm‐1	NOUN
eurjchem-1564	210	9	range	range	NOUN
eurjchem-1564	210	10	can	can	AUX
eurjchem-1564	210	11	be	be	AUX
eurjchem-1564	210	12	assigned	assign	VERB
eurjchem-1564	210	13	to	to	ADP
eurjchem-1564	210	14	aromatic	aromatic	ADJ
eurjchem-1564	210	15	c‐h	c‐h	PROPN
eurjchem-1564	210	16	bending	bending	NOUN
eurjchem-1564	210	17	while	while	SCONJ
eurjchem-1564	210	18	the	the	DET
eurjchem-1564	210	19	band	band	NOUN
eurjchem-1564	210	20	at	at	ADP
eurjchem-1564	210	21	1226‐1280	1226‐1280	PROPN
eurjchem-1564	210	22	cm‐1	cm‐1	NOUN
eurjchem-1564	210	23	due	due	ADP
eurjchem-1564	210	24	to	to	ADP
eurjchem-1564	210	25	aliphatic	aliphatic	ADJ
eurjchem-1564	210	26	c‐h	c‐h	NUM
eurjchem-1564	210	27	bending	bend	VERB
eurjchem-1564	210	28	[	[	X
eurjchem-1564	210	29	27,28	27,28	NUM
eurjchem-1564	210	30	]	]	X
eurjchem-1564	210	31	.	.	PUNCT
eurjchem-1564	211	1	two	two	NUM
eurjchem-1564	211	2	well	well	ADV
eurjchem-1564	211	3	defined	define	VERB
eurjchem-1564	211	4	bands	band	NOUN
eurjchem-1564	211	5	were	be	AUX
eurjchem-1564	211	6	appeared	appear	VERB
eurjchem-1564	211	7	at	at	ADP
eurjchem-1564	211	8	range	range	NOUN
eurjchem-1564	211	9	628‐	628‐	NUM
eurjchem-1564	211	10	620	620	NUM
eurjchem-1564	211	11	cm‐1	cm‐1	NOUN
eurjchem-1564	211	12	can	can	AUX
eurjchem-1564	211	13	be	be	AUX
eurjchem-1564	211	14	assigned	assign	VERB
eurjchem-1564	211	15	to	to	ADP
eurjchem-1564	211	16	ν(pd‐n	ν(pd‐n	X
eurjchem-1564	211	17	)	)	PUNCT
eurjchem-1564	211	18	which	which	PRON
eurjchem-1564	211	19	are	be	AUX
eurjchem-1564	211	20	confirm	confirm	VERB
eurjchem-1564	211	21	that	that	SCONJ
eurjchem-1564	211	22	palladium	palladium	NOUN
eurjchem-1564	211	23	ion	ion	NOUN
eurjchem-1564	211	24	coordinate	coordinate	NOUN
eurjchem-1564	211	25	to	to	ADP
eurjchem-1564	211	26	the	the	DET
eurjchem-1564	211	27	corresponding	correspond	VERB
eurjchem-1564	211	28	ligand	ligand	NOUN
eurjchem-1564	211	29	through	through	ADP
eurjchem-1564	211	30	nitrogen	nitrogen	NOUN
eurjchem-1564	211	31	atoms	atom	NOUN
eurjchem-1564	211	32	of	of	ADP
eurjchem-1564	211	33	amine	amine	ADJ
eurjchem-1564	211	34	and	and	CCONJ
eurjchem-1564	211	35	imine	imine	ADJ
eurjchem-1564	211	36	groups	group	NOUN
eurjchem-1564	211	37	and	and	CCONJ
eurjchem-1564	211	38	in	in	ADP
eurjchem-1564	211	39	cis	cis	NOUN
eurjchem-1564	211	40	geometry	geometry	NOUN
eurjchem-1564	212	1	[	[	X
eurjchem-1564	212	2	30,31	30,31	PROPN
eurjchem-1564	212	3	]	]	PUNCT
eurjchem-1564	212	4	.	.	PUNCT
eurjchem-1564	213	1	the	the	DET
eurjchem-1564	213	2	uv‐visible	uv‐visible	ADJ
eurjchem-1564	213	3	spectra	spectra	NOUN
eurjchem-1564	213	4	of	of	ADP
eurjchem-1564	213	5	all	all	DET
eurjchem-1564	213	6	palladium(ii	palladium(ii	NOUN
eurjchem-1564	213	7	)	)	PUNCT
eurjchem-1564	213	8	complexes	complex	NOUN
eurjchem-1564	213	9	1‐8	1‐8	PROPN
eurjchem-1564	213	10	were	be	AUX
eurjchem-1564	213	11	recorded	record	VERB
eurjchem-1564	213	12	at	at	ADP
eurjchem-1564	213	13	1×10‐4	1×10‐4	PROPN
eurjchem-1564	213	14	m	m	PROPN
eurjchem-1564	213	15	solution	solution	NOUN
eurjchem-1564	213	16	of	of	ADP
eurjchem-1564	213	17	dmso	dmso	ADJ
eurjchem-1564	213	18	solvent	solvent	NOUN
eurjchem-1564	213	19	at	at	ADP
eurjchem-1564	213	20	range	range	NOUN
eurjchem-1564	213	21	200‐	200‐	NUM
eurjchem-1564	213	22	800	800	NUM
eurjchem-1564	213	23	nm	nm	NOUN
eurjchem-1564	213	24	by	by	ADP
eurjchem-1564	213	25	using	use	VERB
eurjchem-1564	213	26	quartz	quartz	NOUN
eurjchem-1564	213	27	cells	cell	NOUN
eurjchem-1564	213	28	.	.	PUNCT
eurjchem-1564	214	1	the	the	DET
eurjchem-1564	214	2	uv‐vis	uv‐vis	PROPN
eurjchem-1564	214	3	.	.	PUNCT
eurjchem-1564	214	4	spectra	spectra	PROPN
eurjchem-1564	214	5	for	for	ADP
eurjchem-1564	214	6	complexes	complex	NOUN
eurjchem-1564	214	7	1	1	NUM
eurjchem-1564	214	8	and	and	CCONJ
eurjchem-1564	214	9	2	2	NUM
eurjchem-1564	214	10	showed	show	VERB
eurjchem-1564	214	11	one	one	NUM
eurjchem-1564	214	12	absorption	absorption	NOUN
eurjchem-1564	214	13	region	region	NOUN
eurjchem-1564	214	14	at	at	ADP
eurjchem-1564	214	15	300	300	NUM
eurjchem-1564	214	16	nm	nm	NOUN
eurjchem-1564	214	17	with	with	ADP
eurjchem-1564	214	18	molar	molar	ADJ
eurjchem-1564	214	19	extinction	extinction	NOUN
eurjchem-1564	214	20	ranged	range	VERB
eurjchem-1564	214	21	(	(	PUNCT
eurjchem-1564	214	22	ε	ε	X
eurjchem-1564	214	23	=	=	SYM
eurjchem-1564	214	24	1050‐1820	1050‐1820	NUM
eurjchem-1564	214	25	m‐1.cm‐1	m‐1.cm‐1	NOUN
eurjchem-1564	214	26	)	)	PUNCT
eurjchem-1564	214	27	which	which	PRON
eurjchem-1564	214	28	may	may	AUX
eurjchem-1564	214	29	be	be	AUX
eurjchem-1564	214	30	attributed	attribute	VERB
eurjchem-1564	214	31	to	to	ADP
eurjchem-1564	214	32	π‐π	π‐π	PROPN
eurjchem-1564	214	33	*	*	PROPN
eurjchem-1564	214	34	transition	transition	NOUN
eurjchem-1564	214	35	of	of	ADP
eurjchem-1564	214	36	phenyl	phenyl	NOUN
eurjchem-1564	214	37	group	group	NOUN
eurjchem-1564	215	1	[	[	X
eurjchem-1564	215	2	32,33	32,33	NUM
eurjchem-1564	215	3	]	]	PUNCT
eurjchem-1564	215	4	.	.	PUNCT
eurjchem-1564	216	1	the	the	DET
eurjchem-1564	216	2	uv‐vis	uv‐vis	PROPN
eurjchem-1564	216	3	.	.	PUNCT
eurjchem-1564	216	4	spectra	spectra	PROPN
eurjchem-1564	216	5	for	for	ADP
eurjchem-1564	216	6	palladium(ii	palladium(ii	NOUN
eurjchem-1564	216	7	)	)	PUNCT
eurjchem-1564	216	8	complexes	complex	NOUN
eurjchem-1564	216	9	3‐8	3‐8	PROPN
eurjchem-1564	216	10	showed	show	VERB
eurjchem-1564	216	11	three	three	NUM
eurjchem-1564	216	12	electronic	electronic	ADJ
eurjchem-1564	216	13	transitions	transition	NOUN
eurjchem-1564	216	14	,	,	PUNCT
eurjchem-1564	216	15	the	the	DET
eurjchem-1564	216	16	first	first	ADJ
eurjchem-1564	216	17	band	band	NOUN
eurjchem-1564	216	18	appeared	appear	VERB
eurjchem-1564	216	19	at	at	ADP
eurjchem-1564	216	20	range	range	NOUN
eurjchem-1564	216	21	300‐312	300‐312	NUM
eurjchem-1564	216	22	nm	nm	NOUN
eurjchem-1564	216	23	with	with	SCONJ
eurjchem-1564	216	24	molar	molar	ADJ
eurjchem-1564	216	25	extinction	extinction	NOUN
eurjchem-1564	216	26	ranged	range	VERB
eurjchem-1564	216	27	2280‐6100	2280‐6100	NUM
eurjchem-1564	216	28	m‐1.cm‐1	m‐1.cm‐1	NOUN
eurjchem-1564	216	29	might	might	AUX
eurjchem-1564	216	30	be	be	AUX
eurjchem-1564	216	31	attributed	attribute	VERB
eurjchem-1564	216	32	to	to	ADP
eurjchem-1564	216	33	π‐π	π‐π	PROPN
eurjchem-1564	216	34	*	*	PROPN
eurjchem-1564	216	35	transition	transition	NOUN
eurjchem-1564	216	36	of	of	ADP
eurjchem-1564	216	37	phenylene	phenylene	ADJ
eurjchem-1564	216	38	group	group	NOUN
eurjchem-1564	217	1	[	[	X
eurjchem-1564	217	2	32,33	32,33	NUM
eurjchem-1564	217	3	]	]	PUNCT
eurjchem-1564	217	4	.	.	PUNCT
eurjchem-1564	218	1	the	the	DET
eurjchem-1564	218	2	second	second	ADJ
eurjchem-1564	218	3	band	band	NOUN
eurjchem-1564	218	4	was	be	AUX
eurjchem-1564	218	5	observed	observe	VERB
eurjchem-1564	218	6	at	at	ADP
eurjchem-1564	218	7	range	range	NOUN
eurjchem-1564	218	8	322‐390	322‐390	NUM
eurjchem-1564	218	9	nm	nm	NOUN
eurjchem-1564	218	10	with	with	ADP
eurjchem-1564	218	11	molar	molar	ADJ
eurjchem-1564	218	12	extinction	extinction	NOUN
eurjchem-1564	218	13	2670‐4011	2670‐4011	NUM
eurjchem-1564	218	14	m‐1.cm‐1	m‐1.cm‐1	NOUN
eurjchem-1564	218	15	which	which	PRON
eurjchem-1564	218	16	is	be	AUX
eurjchem-1564	218	17	due	due	ADJ
eurjchem-1564	218	18	to	to	ADP
eurjchem-1564	218	19	π‐π	π‐π	PROPN
eurjchem-1564	218	20	*	*	PROPN
eurjchem-1564	218	21	transition	transition	NOUN
eurjchem-1564	218	22	of	of	ADP
eurjchem-1564	218	23	the	the	DET
eurjchem-1564	218	24	aromatic	aromatic	ADJ
eurjchem-1564	218	25	rings	ring	NOUN
eurjchem-1564	218	26	(	(	PUNCT
eurjchem-1564	218	27	for	for	ADP
eurjchem-1564	218	28	instance	instance	NOUN
eurjchem-1564	218	29	likely	likely	ADV
eurjchem-1564	218	30	furan	furan	PROPN
eurjchem-1564	218	31	ring	ring	NOUN
eurjchem-1564	218	32	for	for	ADP
eurjchem-1564	218	33	complexes	complex	NOUN
eurjchem-1564	218	34	3	3	NUM
eurjchem-1564	218	35	and	and	CCONJ
eurjchem-1564	218	36	4	4	NUM
eurjchem-1564	218	37	;	;	PUNCT
eurjchem-1564	218	38	ferrocenyl	ferrocenyl	ADJ
eurjchem-1564	218	39	groups	group	NOUN
eurjchem-1564	218	40	for	for	ADP
eurjchem-1564	218	41	complexes	complex	NOUN
eurjchem-1564	218	42	5‐8	5‐8	NOUN
eurjchem-1564	218	43	)	)	PUNCT
eurjchem-1564	219	1	[	[	X
eurjchem-1564	219	2	32‐35	32‐35	NUM
eurjchem-1564	219	3	]	]	X
eurjchem-1564	219	4	.	.	PUNCT
eurjchem-1564	220	1	the	the	DET
eurjchem-1564	220	2	third	third	ADJ
eurjchem-1564	220	3	band	band	NOUN
eurjchem-1564	220	4	was	be	AUX
eurjchem-1564	220	5	observed	observe	VERB
eurjchem-1564	220	6	between	between	ADP
eurjchem-1564	220	7	450	450	NUM
eurjchem-1564	220	8	and	and	CCONJ
eurjchem-1564	220	9	460	460	NUM
eurjchem-1564	220	10	nm	nm	NOUN
eurjchem-1564	220	11	(	(	PUNCT
eurjchem-1564	220	12	ε	ε	PROPN
eurjchem-1564	220	13	=	=	SYM
eurjchem-1564	220	14	2409‐4041	2409‐4041	NUM
eurjchem-1564	220	15	m‐1.cm‐1	m‐1.cm‐1	NOUN
eurjchem-1564	220	16	)	)	PUNCT
eurjchem-1564	220	17	which	which	PRON
eurjchem-1564	220	18	is	be	AUX
eurjchem-1564	220	19	attributed	attribute	VERB
eurjchem-1564	220	20	to	to	ADP
eurjchem-1564	220	21	π‐π	π‐π	PROPN
eurjchem-1564	220	22	*	*	PROPN
eurjchem-1564	220	23	of	of	ADP
eurjchem-1564	220	24	the	the	DET
eurjchem-1564	220	25	azomethine	azomethine	NOUN
eurjchem-1564	220	26	(	(	PUNCT
eurjchem-1564	220	27	ch	ch	NOUN
eurjchem-1564	220	28	=	=	NOUN
eurjchem-1564	220	29	n	n	CCONJ
eurjchem-1564	220	30	)	)	PUNCT
eurjchem-1564	220	31	groups	group	NOUN
eurjchem-1564	220	32	[	[	X
eurjchem-1564	220	33	32‐34	32‐34	NUM
eurjchem-1564	220	34	]	]	PUNCT
eurjchem-1564	220	35	.	.	PUNCT
eurjchem-1564	221	1	the	the	DET
eurjchem-1564	221	2	azomethine	azomethine	NOUN
eurjchem-1564	221	3	band	band	NOUN
eurjchem-1564	221	4	were	be	AUX
eurjchem-1564	221	5	observed	observe	VERB
eurjchem-1564	221	6	to	to	PART
eurjchem-1564	221	7	be	be	AUX
eurjchem-1564	221	8	red	red	ADJ
eurjchem-1564	221	9	shifted	shift	VERB
eurjchem-1564	221	10	at	at	ADP
eurjchem-1564	221	11	range	range	NOUN
eurjchem-1564	221	12	14‐30	14‐30	NUM
eurjchem-1564	221	13	nm	nm	ADV
eurjchem-1564	221	14	compara‐	compara‐	PROPN
eurjchem-1564	221	15	tively	tively	ADV
eurjchem-1564	221	16	to	to	AUX
eurjchem-1564	221	17	complexes	complexe	VERB
eurjchem-1564	221	18	3‐8	3‐8	PROPN
eurjchem-1564	221	19	with	with	ADP
eurjchem-1564	221	20	the	the	DET
eurjchem-1564	221	21	corresponding	corresponding	ADJ
eurjchem-1564	221	22	ligands	ligand	NOUN
eurjchem-1564	221	23	which	which	PRON
eurjchem-1564	221	24	can	can	AUX
eurjchem-1564	221	25	be	be	AUX
eurjchem-1564	221	26	attributed	attribute	VERB
eurjchem-1564	221	27	to	to	PART
eurjchem-1564	221	28	coordinate	coordinate	VERB
eurjchem-1564	221	29	this	this	DET
eurjchem-1564	221	30	groups	group	NOUN
eurjchem-1564	221	31	with	with	ADP
eurjchem-1564	221	32	palladium(ii	palladium(ii	NOUN
eurjchem-1564	221	33	)	)	PUNCT
eurjchem-1564	221	34	ion	ion	NOUN
eurjchem-1564	221	35	.	.	PUNCT
eurjchem-1564	222	1	no	no	DET
eurjchem-1564	222	2	d‐d	d‐d	NOUN
eurjchem-1564	222	3	transitions	transition	NOUN
eurjchem-1564	222	4	were	be	AUX
eurjchem-1564	222	5	observed	observe	VERB
eurjchem-1564	222	6	for	for	ADP
eurjchem-1564	222	7	all	all	DET
eurjchem-1564	222	8	complexes	complex	NOUN
eurjchem-1564	222	9	1‐8	1‐8	NUM
eurjchem-1564	222	10	,	,	PUNCT
eurjchem-1564	222	11	this	this	PRON
eurjchem-1564	222	12	may	may	AUX
eurjchem-1564	222	13	be	be	AUX
eurjchem-1564	222	14	due	due	ADJ
eurjchem-1564	222	15	to	to	ADP
eurjchem-1564	222	16	their	their	PRON
eurjchem-1564	222	17	overlap	overlap	NOUN
eurjchem-1564	222	18	with	with	ADP
eurjchem-1564	222	19	π‐π	π‐π	PROPN
eurjchem-1564	222	20	*	*	PROPN
eurjchem-1564	222	21	transition	transition	NOUN
eurjchem-1564	222	22	of	of	ADP
eurjchem-1564	222	23	the	the	DET
eurjchem-1564	222	24	phenylene	phenylene	ADJ
eurjchem-1564	222	25	group	group	NOUN
eurjchem-1564	222	26	which	which	PRON
eurjchem-1564	222	27	lead	lead	VERB
eurjchem-1564	222	28	to	to	AUX
eurjchem-1564	222	29	masked	mask	VERB
eurjchem-1564	222	30	it	it	PRON
eurjchem-1564	222	31	.	.	PUNCT
eurjchem-1564	223	1	the	the	DET
eurjchem-1564	223	2	1h	1h	NUM
eurjchem-1564	223	3	nmr	nmr	NOUN
eurjchem-1564	223	4	spectra	spectra	NOUN
eurjchem-1564	223	5	of	of	ADP
eurjchem-1564	223	6	all	all	DET
eurjchem-1564	223	7	the	the	DET
eurjchem-1564	223	8	synthesized	synthesize	VERB
eurjchem-1564	223	9	complexes	complex	NOUN
eurjchem-1564	223	10	1‐	1‐	NUM
eurjchem-1564	223	11	8	8	NUM
eurjchem-1564	223	12	were	be	AUX
eurjchem-1564	223	13	taken	take	VERB
eurjchem-1564	223	14	in	in	ADP
eurjchem-1564	223	15	dmso‐d6	dmso‐d6	NOUN
eurjchem-1564	223	16	solvent	solvent	NOUN
eurjchem-1564	223	17	.	.	PUNCT
eurjchem-1564	224	1	in	in	ADP
eurjchem-1564	224	2	general	general	ADJ
eurjchem-1564	224	3	,	,	PUNCT
eurjchem-1564	224	4	1h	1h	NUM
eurjchem-1564	224	5	nmr	nmr	NOUN
eurjchem-1564	224	6	spectra	spectra	NOUN
eurjchem-1564	224	7	of	of	ADP
eurjchem-1564	224	8	the	the	DET
eurjchem-1564	224	9	recorded	record	VERB
eurjchem-1564	224	10	complexes	complex	NOUN
eurjchem-1564	224	11	show	show	VERB
eurjchem-1564	224	12	the	the	DET
eurjchem-1564	224	13	expected	expect	VERB
eurjchem-1564	224	14	signals	signal	NOUN
eurjchem-1564	224	15	in	in	ADP
eurjchem-1564	224	16	proper	proper	ADJ
eurjchem-1564	224	17	intensity	intensity	NOUN
eurjchem-1564	224	18	ratio	ratio	NOUN
eurjchem-1564	224	19	.	.	PUNCT
eurjchem-1564	225	1	the	the	DET
eurjchem-1564	225	2	1h	1h	NUM
eurjchem-1564	225	3	nmr	nmr	PROPN
eurjchem-1564	225	4	spectra	spectra	NOUN
eurjchem-1564	225	5	of	of	ADP
eurjchem-1564	225	6	palladium(ii	palladium(ii	NOUN
eurjchem-1564	225	7	)	)	PUNCT
eurjchem-1564	225	8	complexes	complex	NOUN
eurjchem-1564	225	9	1	1	NUM
eurjchem-1564	225	10	and	and	CCONJ
eurjchem-1564	225	11	2	2	NUM
eurjchem-1564	225	12	display	display	NOUN
eurjchem-1564	225	13	singlet	singlet	NOUN
eurjchem-1564	225	14	signal	signal	NOUN
eurjchem-1564	225	15	in	in	ADP
eurjchem-1564	225	16	the	the	DET
eurjchem-1564	225	17	range	range	NOUN
eurjchem-1564	225	18	between	between	ADP
eurjchem-1564	225	19	δ	δ	PROPN
eurjchem-1564	225	20	5.80	5.80	NUM
eurjchem-1564	225	21	and	and	CCONJ
eurjchem-1564	225	22	5.95	5.95	NUM
eurjchem-1564	225	23	ppm	ppm	NOUN
eurjchem-1564	225	24	due	due	ADJ
eurjchem-1564	225	25	to	to	ADP
eurjchem-1564	225	26	protons	proton	NOUN
eurjchem-1564	225	27	of	of	ADP
eurjchem-1564	225	28	n‐h	n‐h	PRON
eurjchem-1564	225	29	[	[	X
eurjchem-1564	225	30	36	36	NUM
eurjchem-1564	225	31	]	]	PUNCT
eurjchem-1564	225	32	.	.	PUNCT
eurjchem-1564	226	1	these	these	DET
eurjchem-1564	226	2	protons	proton	NOUN
eurjchem-1564	226	3	shifted	shift	VERB
eurjchem-1564	226	4	toward	toward	ADP
eurjchem-1564	226	5	higher	high	ADJ
eurjchem-1564	226	6	chemical	chemical	NOUN
eurjchem-1564	226	7	shift	shift	NOUN
eurjchem-1564	226	8	(	(	PUNCT
eurjchem-1564	226	9	downfield	downfield	PROPN
eurjchem-1564	226	10	)	)	PUNCT
eurjchem-1564	226	11	compared	compare	VERB
eurjchem-1564	226	12	to	to	ADP
eurjchem-1564	226	13	their	their	PRON
eurjchem-1564	226	14	free	free	ADJ
eurjchem-1564	226	15	ligands	ligand	NOUN
eurjchem-1564	226	16	[	[	X
eurjchem-1564	226	17	21	21	NUM
eurjchem-1564	226	18	]	]	PUNCT
eurjchem-1564	226	19	at	at	ADP
eurjchem-1564	226	20	range	range	NOUN
eurjchem-1564	226	21	δ	δ	PROPN
eurjchem-1564	226	22	1.05‐1.34	1.05‐1.34	NUM
eurjchem-1564	226	23	ppm	ppm	NOUN
eurjchem-1564	226	24	,	,	PUNCT
eurjchem-1564	226	25	which	which	PRON
eurjchem-1564	226	26	are	be	AUX
eurjchem-1564	226	27	confirm	confirm	VERB
eurjchem-1564	226	28	the	the	DET
eurjchem-1564	226	29	coordination	coordination	NOUN
eurjchem-1564	226	30	between	between	ADP
eurjchem-1564	226	31	palladium(ii	palladium(ii	NOUN
eurjchem-1564	226	32	)	)	PUNCT
eurjchem-1564	226	33	ion	ion	NOUN
eurjchem-1564	226	34	with	with	ADP
eurjchem-1564	226	35	correspond‐	correspond‐	ADV
eurjchem-1564	226	36	ding	de	VERB
eurjchem-1564	226	37	ligands	ligand	NOUN
eurjchem-1564	226	38	through	through	ADP
eurjchem-1564	226	39	nitrogen	nitrogen	NOUN
eurjchem-1564	226	40	atoms	atom	NOUN
eurjchem-1564	226	41	of	of	ADP
eurjchem-1564	226	42	amine	amine	ADJ
eurjchem-1564	226	43	groups	group	NOUN
eurjchem-1564	226	44	.	.	PUNCT
eurjchem-1564	227	1	due	due	ADP
eurjchem-1564	227	2	to	to	ADP
eurjchem-1564	227	3	phenyl	phenyl	NOUN
eurjchem-1564	227	4	group	group	NOUN
eurjchem-1564	227	5	,	,	PUNCT
eurjchem-1564	227	6	the	the	DET
eurjchem-1564	227	7	protons	proton	NOUN
eurjchem-1564	227	8	were	be	AUX
eurjchem-1564	227	9	found	find	VERB
eurjchem-1564	227	10	in	in	ADP
eurjchem-1564	227	11	their	their	PRON
eurjchem-1564	227	12	expected	expect	VERB
eurjchem-1564	227	13	regions	region	NOUN
eurjchem-1564	227	14	as	as	ADP
eurjchem-1564	227	15	multiple	multiple	ADJ
eurjchem-1564	227	16	signals	signal	NOUN
eurjchem-1564	227	17	at	at	ADP
eurjchem-1564	227	18	δ	δ	PROPN
eurjchem-1564	227	19	7.10‐7.40	7.10‐7.40	NUM
eurjchem-1564	227	20	ppm	ppm	NOUN
eurjchem-1564	228	1	[	[	X
eurjchem-1564	228	2	35,36	35,36	NUM
eurjchem-1564	228	3	]	]	PUNCT
eurjchem-1564	228	4	.	.	PUNCT
eurjchem-1564	229	1	also	also	ADV
eurjchem-1564	229	2	,	,	PUNCT
eurjchem-1564	229	3	1h	1h	NUM
eurjchem-1564	229	4	nmr	nmr	NOUN
eurjchem-1564	229	5	spectra	spectra	NOUN
eurjchem-1564	229	6	of	of	ADP
eurjchem-1564	229	7	complexes	complex	NOUN
eurjchem-1564	229	8	1	1	NUM
eurjchem-1564	229	9	and	and	CCONJ
eurjchem-1564	229	10	2	2	NUM
eurjchem-1564	229	11	show	show	VERB
eurjchem-1564	229	12	several	several	ADJ
eurjchem-1564	229	13	signals	signal	NOUN
eurjchem-1564	229	14	at	at	ADP
eurjchem-1564	229	15	range	range	NOUN
eurjchem-1564	229	16	δ	δ	PROPN
eurjchem-1564	229	17	1.14	1.14	NUM
eurjchem-1564	229	18	‐	‐	NOUN
eurjchem-1564	229	19	3.41	3.41	NUM
eurjchem-1564	229	20	ppm	ppm	NOUN
eurjchem-1564	229	21	due	due	ADP
eurjchem-1564	229	22	to	to	ADP
eurjchem-1564	229	23	different	different	ADJ
eurjchem-1564	229	24	methylene	methylene	NOUN
eurjchem-1564	229	25	groups	group	NOUN
eurjchem-1564	229	26	ch2	ch2	VERB
eurjchem-1564	229	27	.	.	PUNCT
eurjchem-1564	230	1	on	on	ADP
eurjchem-1564	230	2	the	the	DET
eurjchem-1564	230	3	other	other	ADJ
eurjchem-1564	230	4	hand	hand	NOUN
eurjchem-1564	230	5	,	,	PUNCT
eurjchem-1564	230	6	the	the	DET
eurjchem-1564	230	7	1h	1h	NUM
eurjchem-1564	230	8	nmr	nmr	NOUN
eurjchem-1564	230	9	spectra	spectra	NOUN
eurjchem-1564	230	10	of	of	ADP
eurjchem-1564	230	11	complexes	complex	NOUN
eurjchem-1564	230	12	3‐6	3‐6	PROPN
eurjchem-1564	230	13	showed	show	VERB
eurjchem-1564	230	14	a	a	DET
eurjchem-1564	230	15	singlet	singlet	ADJ
eurjchem-1564	230	16	signal	signal	NOUN
eurjchem-1564	230	17	in	in	ADP
eurjchem-1564	230	18	the	the	DET
eurjchem-1564	230	19	range	range	NOUN
eurjchem-1564	230	20	between	between	ADP
eurjchem-1564	230	21	δ	δ	PROPN
eurjchem-1564	230	22	8.45	8.45	NUM
eurjchem-1564	230	23	and	and	CCONJ
eurjchem-1564	230	24	8.66	8.66	NUM
eurjchem-1564	230	25	ppm	ppm	NOUN
eurjchem-1564	230	26	which	which	PRON
eurjchem-1564	230	27	may	may	AUX
eurjchem-1564	230	28	be	be	AUX
eurjchem-1564	230	29	attributed	attribute	VERB
eurjchem-1564	230	30	to	to	ADP
eurjchem-1564	230	31	the	the	DET
eurjchem-1564	230	32	imines	imine	NOUN
eurjchem-1564	230	33	protons	proton	NOUN
eurjchem-1564	230	34	ch	ch	NOUN
eurjchem-1564	230	35	=	=	PROPN
eurjchem-1564	230	36	n	n	NOUN
eurjchem-1564	230	37	[	[	X
eurjchem-1564	230	38	35‐	35‐	NUM
eurjchem-1564	230	39	37	37	NUM
eurjchem-1564	230	40	]	]	PUNCT
eurjchem-1564	230	41	.	.	PUNCT
eurjchem-1564	231	1	these	these	DET
eurjchem-1564	231	2	signals	signal	NOUN
eurjchem-1564	231	3	also	also	ADV
eurjchem-1564	231	4	shifted	shift	VERB
eurjchem-1564	231	5	toward	toward	ADP
eurjchem-1564	231	6	higher	high	ADJ
eurjchem-1564	231	7	chemical	chemical	NOUN
eurjchem-1564	231	8	shift	shift	NOUN
eurjchem-1564	231	9	(	(	PUNCT
eurjchem-1564	231	10	downfield	downfield	PROPN
eurjchem-1564	231	11	)	)	PUNCT
eurjchem-1564	231	12	than	than	ADP
eurjchem-1564	231	13	their	their	PRON
eurjchem-1564	231	14	free	free	ADJ
eurjchem-1564	231	15	ligands	ligand	NOUN
eurjchem-1564	231	16	signals	signal	NOUN
eurjchem-1564	231	17	at	at	ADP
eurjchem-1564	231	18	the	the	DET
eurjchem-1564	231	19	range	range	NOUN
eurjchem-1564	231	20	δ	δ	PROPN
eurjchem-1564	231	21	0.10‐	0.10‐	NUM
eurjchem-1564	231	22	0.44	0.44	NUM
eurjchem-1564	231	23	ppm	ppm	NOUN
eurjchem-1564	231	24	which	which	PRON
eurjchem-1564	231	25	indicate	indicate	VERB
eurjchem-1564	231	26	an	an	DET
eurjchem-1564	231	27	evidence	evidence	NOUN
eurjchem-1564	231	28	of	of	ADP
eurjchem-1564	231	29	coordinated	coordinated	ADJ
eurjchem-1564	231	30	palla‐	palla‐	NOUN
eurjchem-1564	231	31	dium(ii	dium(ii	NOUN
eurjchem-1564	231	32	)	)	PUNCT
eurjchem-1564	231	33	ion	ion	NOUN
eurjchem-1564	231	34	with	with	ADP
eurjchem-1564	231	35	the	the	DET
eurjchem-1564	231	36	corresponding	correspond	VERB
eurjchem-1564	231	37	ligand	ligand	NOUN
eurjchem-1564	231	38	via	via	ADP
eurjchem-1564	231	39	nitrogen	nitrogen	NOUN
eurjchem-1564	231	40	atom	atom	NOUN
eurjchem-1564	231	41	of	of	ADP
eurjchem-1564	231	42	azomethine	azomethine	PROPN
eurjchem-1564	231	43	groups	group	NOUN
eurjchem-1564	231	44	.	.	PUNCT
eurjchem-1564	232	1	1h	1h	NUM
eurjchem-1564	232	2	nmr	nmr	NOUN
eurjchem-1564	232	3	spectra	spectra	NOUN
eurjchem-1564	232	4	of	of	ADP
eurjchem-1564	232	5	complexes	complex	NOUN
eurjchem-1564	232	6	3	3	NUM
eurjchem-1564	232	7	,	,	PUNCT
eurjchem-1564	232	8	5	5	NUM
eurjchem-1564	232	9	and	and	CCONJ
eurjchem-1564	232	10	7	7	NUM
eurjchem-1564	232	11	showed	show	VERB
eurjchem-1564	232	12	a	a	DET
eurjchem-1564	232	13	singlet	singlet	ADJ
eurjchem-1564	232	14	signals	signal	NOUN
eurjchem-1564	232	15	at	at	ADP
eurjchem-1564	232	16	δ	δ	PROPN
eurjchem-1564	232	17	8.81	8.81	NUM
eurjchem-1564	232	18	,	,	PUNCT
eurjchem-1564	232	19	9.09	9.09	NUM
eurjchem-1564	232	20	,	,	PUNCT
eurjchem-1564	232	21	9.54	9.54	NUM
eurjchem-1564	232	22	ppm	ppm	NOUN
eurjchem-1564	232	23	,	,	PUNCT
eurjchem-1564	232	24	respectively	respectively	ADV
eurjchem-1564	232	25	,	,	PUNCT
eurjchem-1564	232	26	which	which	PRON
eurjchem-1564	232	27	were	be	AUX
eurjchem-1564	232	28	pointed	point	VERB
eurjchem-1564	232	29	out	out	ADP
eurjchem-1564	232	30	by	by	ADP
eurjchem-1564	232	31	protons	proton	NOUN
eurjchem-1564	232	32	of	of	ADP
eurjchem-1564	232	33	terminal	terminal	ADJ
eurjchem-1564	232	34	amine	amine	ADJ
eurjchem-1564	232	35	group	group	NOUN
eurjchem-1564	232	36	nh2	nh2	PROPN
eurjchem-1564	232	37	[	[	X
eurjchem-1564	232	38	35	35	NUM
eurjchem-1564	232	39	]	]	SYM
eurjchem-1564	232	40	.	.	PUNCT
eurjchem-1564	233	1	160	160	NUM
eurjchem-1564	233	2	al‐fregi	al‐fregi	NOUN
eurjchem-1564	233	3	et	et	VERB
eurjchem-1564	233	4	al	al	PROPN
eurjchem-1564	233	5	.	.	PUNCT
eurjchem-1564	233	6	/	/	SYM
eurjchem-1564	233	7	european	european	PROPN
eurjchem-1564	233	8	journal	journal	PROPN
eurjchem-1564	233	9	of	of	ADP
eurjchem-1564	233	10	chemistry	chemistry	NOUN
eurjchem-1564	233	11	8	8	NUM
eurjchem-1564	233	12	(	(	PUNCT
eurjchem-1564	233	13	2	2	NUM
eurjchem-1564	233	14	)	)	PUNCT
eurjchem-1564	233	15	(	(	PUNCT
eurjchem-1564	233	16	2017	2017	NUM
eurjchem-1564	233	17	)	)	PUNCT
eurjchem-1564	233	18	155‐161	155‐161	NUM
eurjchem-1564	233	19	table	table	NOUN
eurjchem-1564	233	20	1	1	NUM
eurjchem-1564	233	21	.	.	PUNCT
eurjchem-1564	234	1	in	in	ADP
eurjchem-1564	234	2	vitro	vitro	X
eurjchem-1564	234	3	antibacterial	antibacterial	ADJ
eurjchem-1564	234	4	activity	activity	NOUN
eurjchem-1564	234	5	and	and	CCONJ
eurjchem-1564	234	6	minimum	minimum	ADJ
eurjchem-1564	234	7	inhibitory	inhibitory	ADJ
eurjchem-1564	234	8	concentration	concentration	NOUN
eurjchem-1564	234	9	(	(	PUNCT
eurjchem-1564	234	10	mic	mic	ADJ
eurjchem-1564	234	11	)	)	PUNCT
eurjchem-1564	234	12	values	value	NOUN
eurjchem-1564	234	13	of	of	ADP
eurjchem-1564	234	14	the	the	DET
eurjchem-1564	234	15	palladium(ii	palladium(ii	NOUN
eurjchem-1564	234	16	)	)	PUNCT
eurjchem-1564	234	17	complexes	complex	NOUN
eurjchem-1564	234	18	and	and	CCONJ
eurjchem-1564	234	19	cis‐platin	cis‐platin	NUM
eurjchem-1564	234	20	against	against	ADP
eurjchem-1564	234	21	staphylococcus	staphylococcus	NOUN
eurjchem-1564	234	22	aureus	aureus	NOUN
eurjchem-1564	234	23	and	and	CCONJ
eurjchem-1564	234	24	escherichia	escherichia	NOUN
eurjchem-1564	234	25	coli	coli	NOUN
eurjchem-1564	234	26	bacteria	bacteria	NOUN
eurjchem-1564	234	27	.	.	PUNCT
eurjchem-1564	235	1	complex	complex	ADJ
eurjchem-1564	235	2	concentration	concentration	NOUN
eurjchem-1564	235	3	(	(	PUNCT
eurjchem-1564	235	4	µg	µg	NOUN
eurjchem-1564	235	5	/	/	SYM
eurjchem-1564	235	6	ml	ml	NOUN
eurjchem-1564	235	7	)	)	PUNCT
eurjchem-1564	235	8	mic	mic	ADJ
eurjchem-1564	235	9	250	250	NUM
eurjchem-1564	235	10	200	200	NUM
eurjchem-1564	235	11	150	150	NUM
eurjchem-1564	235	12	100	100	NUM
eurjchem-1564	235	13	50	50	NUM
eurjchem-1564	235	14	25	25	NUM
eurjchem-1564	235	15	10	10	NUM
eurjchem-1564	235	16	1	1	NUM
eurjchem-1564	235	17	staphylococcus	staphylococcus	NOUN
eurjchem-1564	235	18	aureus	aureus	NOUN
eurjchem-1564	235	19	1	1	NUM
eurjchem-1564	235	20	28	28	NUM
eurjchem-1564	235	21	24	24	NUM
eurjchem-1564	235	22	17	17	NUM
eurjchem-1564	235	23	13	13	NUM
eurjchem-1564	235	24	7	7	NUM
eurjchem-1564	235	25	ni	ni	PROPN
eurjchem-1564	235	26	ni	ni	PROPN
eurjchem-1564	235	27	ni	ni	PROPN
eurjchem-1564	235	28	*	*	PROPN
eurjchem-1564	235	29	50	50	NUM
eurjchem-1564	235	30	2	2	NUM
eurjchem-1564	235	31	27	27	NUM
eurjchem-1564	235	32	23	23	NUM
eurjchem-1564	235	33	15	15	NUM
eurjchem-1564	235	34	12	12	NUM
eurjchem-1564	235	35	5	5	NUM
eurjchem-1564	235	36	ni	ni	PROPN
eurjchem-1564	235	37	ni	ni	PROPN
eurjchem-1564	235	38	ni	ni	PROPN
eurjchem-1564	235	39	50	50	NUM
eurjchem-1564	235	40	3	3	NUM
eurjchem-1564	235	41	34	34	NUM
eurjchem-1564	235	42	30	30	NUM
eurjchem-1564	235	43	21	21	NUM
eurjchem-1564	235	44	15	15	NUM
eurjchem-1564	235	45	11	11	NUM
eurjchem-1564	235	46	7	7	NUM
eurjchem-1564	235	47	ni	ni	PROPN
eurjchem-1564	235	48	ni	ni	PROPN
eurjchem-1564	235	49	25	25	NUM
eurjchem-1564	235	50	4	4	NUM
eurjchem-1564	235	51	32	32	NUM
eurjchem-1564	235	52	30	30	NUM
eurjchem-1564	235	53	19	19	NUM
eurjchem-1564	235	54	14	14	NUM
eurjchem-1564	235	55	9	9	NUM
eurjchem-1564	235	56	5	5	NUM
eurjchem-1564	235	57	ni	ni	PROPN
eurjchem-1564	235	58	ni	ni	PROPN
eurjchem-1564	235	59	25	25	NUM
eurjchem-1564	235	60	5	5	NUM
eurjchem-1564	235	61	50	50	NUM
eurjchem-1564	235	62	43	43	NUM
eurjchem-1564	235	63	34	34	NUM
eurjchem-1564	235	64	28	28	NUM
eurjchem-1564	235	65	20	20	NUM
eurjchem-1564	235	66	13	13	NUM
eurjchem-1564	235	67	9	9	NUM
eurjchem-1564	235	68	7	7	NUM
eurjchem-1564	235	69	1	1	NUM
eurjchem-1564	235	70	6	6	NUM
eurjchem-1564	235	71	38	38	NUM
eurjchem-1564	235	72	28	28	NUM
eurjchem-1564	235	73	20	20	NUM
eurjchem-1564	235	74	17	17	NUM
eurjchem-1564	235	75	13	13	NUM
eurjchem-1564	235	76	10	10	NUM
eurjchem-1564	235	77	5	5	NUM
eurjchem-1564	235	78	ni	ni	PROPN
eurjchem-1564	235	79	10	10	NUM
eurjchem-1564	235	80	7	7	NUM
eurjchem-1564	235	81	48	48	NUM
eurjchem-1564	235	82	40	40	NUM
eurjchem-1564	235	83	34	34	NUM
eurjchem-1564	235	84	28	28	NUM
eurjchem-1564	235	85	19	19	NUM
eurjchem-1564	235	86	11	11	NUM
eurjchem-1564	235	87	6	6	NUM
eurjchem-1564	235	88	ni	ni	PROPN
eurjchem-1564	235	89	10	10	NUM
eurjchem-1564	235	90	8	8	NUM
eurjchem-1564	235	91	47	47	NUM
eurjchem-1564	235	92	36	36	NUM
eurjchem-1564	235	93	28	28	NUM
eurjchem-1564	235	94	20	20	NUM
eurjchem-1564	235	95	11	11	NUM
eurjchem-1564	235	96	8	8	NUM
eurjchem-1564	235	97	ni	ni	PROPN
eurjchem-1564	235	98	ni	ni	PROPN
eurjchem-1564	235	99	25	25	NUM
eurjchem-1564	235	100	escherichia	escherichia	NOUN
eurjchem-1564	235	101	coli	coli	NOUN
eurjchem-1564	235	102	1	1	NUM
eurjchem-1564	235	103	12	12	NUM
eurjchem-1564	235	104	8	8	NUM
eurjchem-1564	235	105	ni	ni	PROPN
eurjchem-1564	235	106	ni	ni	PROPN
eurjchem-1564	235	107	ni	ni	PROPN
eurjchem-1564	235	108	ni	ni	PROPN
eurjchem-1564	235	109	ni	ni	PROPN
eurjchem-1564	235	110	ni	ni	PROPN
eurjchem-1564	235	111	200	200	NUM
eurjchem-1564	235	112	2	2	NUM
eurjchem-1564	235	113	8	8	NUM
eurjchem-1564	235	114	5	5	NUM
eurjchem-1564	235	115	ni	ni	PROPN
eurjchem-1564	235	116	ni	ni	PROPN
eurjchem-1564	235	117	ni	ni	PROPN
eurjchem-1564	235	118	ni	ni	PROPN
eurjchem-1564	235	119	ni	ni	PROPN
eurjchem-1564	235	120	ni	ni	PROPN
eurjchem-1564	235	121	200	200	NUM
eurjchem-1564	235	122	3	3	NUM
eurjchem-1564	235	123	17	17	NUM
eurjchem-1564	235	124	14	14	NUM
eurjchem-1564	235	125	11	11	NUM
eurjchem-1564	235	126	8	8	NUM
eurjchem-1564	235	127	ni	ni	PROPN
eurjchem-1564	235	128	ni	ni	PROPN
eurjchem-1564	235	129	ni	ni	PROPN
eurjchem-1564	235	130	ni	ni	PROPN
eurjchem-1564	235	131	100	100	NUM
eurjchem-1564	235	132	4	4	NUM
eurjchem-1564	235	133	14	14	NUM
eurjchem-1564	235	134	12	12	NUM
eurjchem-1564	235	135	10	10	NUM
eurjchem-1564	235	136	8	8	NUM
eurjchem-1564	235	137	ni	ni	PROPN
eurjchem-1564	235	138	ni	ni	PROPN
eurjchem-1564	235	139	ni	ni	PROPN
eurjchem-1564	235	140	ni	ni	PROPN
eurjchem-1564	235	141	100	100	NUM
eurjchem-1564	235	142	5	5	NUM
eurjchem-1564	235	143	40	40	NUM
eurjchem-1564	235	144	32	32	NUM
eurjchem-1564	235	145	26	26	NUM
eurjchem-1564	235	146	18	18	NUM
eurjchem-1564	235	147	13	13	NUM
eurjchem-1564	235	148	9	9	NUM
eurjchem-1564	235	149	6	6	NUM
eurjchem-1564	235	150	ni	ni	PROPN
eurjchem-1564	235	151	10	10	NUM
eurjchem-1564	235	152	6	6	NUM
eurjchem-1564	235	153	21	21	NUM
eurjchem-1564	235	154	17	17	NUM
eurjchem-1564	235	155	14	14	NUM
eurjchem-1564	235	156	10	10	NUM
eurjchem-1564	235	157	7	7	NUM
eurjchem-1564	235	158	ni	ni	PROPN
eurjchem-1564	235	159	ni	ni	PROPN
eurjchem-1564	235	160	ni	ni	PROPN
eurjchem-1564	235	161	50	50	NUM
eurjchem-1564	235	162	7	7	NUM
eurjchem-1564	235	163	35	35	NUM
eurjchem-1564	235	164	26	26	NUM
eurjchem-1564	235	165	17	17	NUM
eurjchem-1564	235	166	12	12	NUM
eurjchem-1564	235	167	8	8	NUM
eurjchem-1564	235	168	6	6	NUM
eurjchem-1564	235	169	ni	ni	PROPN
eurjchem-1564	235	170	ni	ni	PROPN
eurjchem-1564	235	171	25	25	NUM
eurjchem-1564	235	172	8	8	NUM
eurjchem-1564	235	173	18	18	NUM
eurjchem-1564	235	174	15	15	NUM
eurjchem-1564	235	175	13	13	NUM
eurjchem-1564	235	176	9	9	NUM
eurjchem-1564	235	177	6	6	NUM
eurjchem-1564	235	178	ni	ni	PROPN
eurjchem-1564	235	179	ni	ni	PROPN
eurjchem-1564	235	180	ni	ni	PROPN
eurjchem-1564	235	181	50	50	NUM
eurjchem-1564	235	182	cis‐platin	cis‐platin	NUM
eurjchem-1564	235	183	28	28	NUM
eurjchem-1564	235	184	21	21	NUM
eurjchem-1564	235	185	18	18	NUM
eurjchem-1564	235	186	13	13	NUM
eurjchem-1564	235	187	9	9	NUM
eurjchem-1564	235	188	7	7	NUM
eurjchem-1564	235	189	ni	ni	PROPN
eurjchem-1564	235	190	ni	ni	PROPN
eurjchem-1564	235	191	25	25	NUM
eurjchem-1564	235	192	*	*	PUNCT
eurjchem-1564	235	193	ni	ni	NOUN
eurjchem-1564	235	194	:	:	PUNCT
eurjchem-1564	235	195	no	no	DET
eurjchem-1564	235	196	inhibition	inhibition	NOUN
eurjchem-1564	235	197	.	.	PUNCT
eurjchem-1564	235	198	table	table	NOUN
eurjchem-1564	235	199	2	2	NUM
eurjchem-1564	235	200	.	.	PUNCT
eurjchem-1564	235	201	molar	molar	ADJ
eurjchem-1564	235	202	absorptivity	absorptivity	NOUN
eurjchem-1564	235	203	of	of	ADP
eurjchem-1564	235	204	complexes	complex	NOUN
eurjchem-1564	235	205	1‐8	1‐8	PROPN
eurjchem-1564	235	206	with	with	ADP
eurjchem-1564	235	207	human	human	ADJ
eurjchem-1564	235	208	dna	dna	NOUN
eurjchem-1564	235	209	at	at	ADP
eurjchem-1564	235	210	different	different	ADJ
eurjchem-1564	235	211	times	time	NOUN
eurjchem-1564	235	212	.	.	PUNCT
eurjchem-1564	236	1	absorbance	absorbance	PROPN
eurjchem-1564	236	2	complex	complex	PROPN
eurjchem-1564	236	3	t	t	NOUN
eurjchem-1564	236	4	=	=	SYM
eurjchem-1564	236	5	1	1	NUM
eurjchem-1564	236	6	week	week	NOUN
eurjchem-1564	236	7	t	t	NOUN
eurjchem-1564	236	8	=	=	SYM
eurjchem-1564	236	9	2	2	NUM
eurjchem-1564	236	10	h	h	NOUN
eurjchem-1564	236	11	t	t	NOUN
eurjchem-1564	236	12	=	=	SYM
eurjchem-1564	236	13	1	1	NUM
eurjchem-1564	236	14	h	h	NOUN
eurjchem-1564	236	15	t	t	NOUN
eurjchem-1564	236	16	=	=	SYM
eurjchem-1564	236	17	1	1	NUM
eurjchem-1564	236	18	min	min	NOUN
eurjchem-1564	236	19	t	t	NOUN
eurjchem-1564	236	20	=	=	SYM
eurjchem-1564	236	21	0	0	NUM
eurjchem-1564	236	22	1.000	1.000	NUM
eurjchem-1564	236	23	1.0901.1801.307	1.0901.1801.307	NUM
eurjchem-1564	236	24	1.561	1.561	NUM
eurjchem-1564	236	25	1	1	NUM
eurjchem-1564	236	26	1.211	1.211	NUM
eurjchem-1564	236	27	1.3021.4001.509	1.3021.4001.509	NUM
eurjchem-1564	236	28	1.742	1.742	NUM
eurjchem-1564	236	29	2	2	NUM
eurjchem-1564	236	30	1.300	1.300	NUM
eurjchem-1564	236	31	1.270	1.270	NUM
eurjchem-1564	236	32	1.400	1.400	NUM
eurjchem-1564	236	33	1.360	1.360	NUM
eurjchem-1564	236	34	1.500	1.500	NUM
eurjchem-1564	236	35	1.459	1.459	NUM
eurjchem-1564	236	36	1.633	1.633	NUM
eurjchem-1564	236	37	1.550	1.550	NUM
eurjchem-1564	236	38	1.900	1.900	NUM
eurjchem-1564	236	39	1.730	1.730	NUM
eurjchem-1564	236	40	3	3	NUM
eurjchem-1564	236	41	1.140	1.140	NUM
eurjchem-1564	236	42	1.120	1.120	NUM
eurjchem-1564	236	43	1.263	1.263	NUM
eurjchem-1564	236	44	1.200	1.200	NUM
eurjchem-1564	236	45	1.350	1.350	NUM
eurjchem-1564	236	46	1.277	1.277	NUM
eurjchem-1564	236	47	1.455	1.455	NUM
eurjchem-1564	236	48	1.377	1.377	NUM
eurjchem-1564	236	49	1.716	1.716	NUM
eurjchem-1564	236	50	1.520	1.520	NUM
eurjchem-1564	236	51	4	4	NUM
eurjchem-1564	236	52	1.219	1.219	NUM
eurjchem-1564	236	53	1.223	1.223	NUM
eurjchem-1564	236	54	1.240	1.240	NUM
eurjchem-1564	236	55	1.310	1.310	NUM
eurjchem-1564	236	56	1.302	1.302	NUM
eurjchem-1564	236	57	1.343	1.343	NUM
eurjchem-1564	236	58	1.420	1.420	NUM
eurjchem-1564	236	59	1.400	1.400	NUM
eurjchem-1564	236	60	1.426	1.426	NUM
eurjchem-1564	236	61	1.525	1.525	NUM
eurjchem-1564	236	62	1.500	1.500	NUM
eurjchem-1564	236	63	1.537	1.537	NUM
eurjchem-1564	236	64	1.888	1.888	NUM
eurjchem-1564	236	65	1.639	1.639	NUM
eurjchem-1564	236	66	1.750	1.750	NUM
eurjchem-1564	236	67	5	5	NUM
eurjchem-1564	236	68	1.215	1.215	NUM
eurjchem-1564	236	69	1.205	1.205	NUM
eurjchem-1564	236	70	1.241	1.241	NUM
eurjchem-1564	236	71	1.300	1.300	NUM
eurjchem-1564	236	72	1.271	1.271	NUM
eurjchem-1564	236	73	1.318	1.318	NUM
eurjchem-1564	236	74	1.400	1.400	NUM
eurjchem-1564	236	75	1.345	1.345	NUM
eurjchem-1564	236	76	1.411	1.411	NUM
eurjchem-1564	236	77	1.500	1.500	NUM
eurjchem-1564	236	78	1.450	1.450	NUM
eurjchem-1564	236	79	1.510	1.510	NUM
eurjchem-1564	236	80	1.747	1.747	NUM
eurjchem-1564	236	81	1.600	1.600	NUM
eurjchem-1564	236	82	1.650	1.650	NUM
eurjchem-1564	236	83	6	6	NUM
eurjchem-1564	236	84	1.221	1.221	NUM
eurjchem-1564	236	85	1.155	1.155	NUM
eurjchem-1564	236	86	1.237	1.237	NUM
eurjchem-1564	236	87	1.311	1.311	NUM
eurjchem-1564	236	88	1.300	1.300	NUM
eurjchem-1564	236	89	1.333	1.333	NUM
eurjchem-1564	236	90	1.430	1.430	NUM
eurjchem-1564	236	91	1.300	1.300	NUM
eurjchem-1564	236	92	1.430	1.430	NUM
eurjchem-1564	236	93	1.527	1.527	NUM
eurjchem-1564	236	94	1.424	1.424	NUM
eurjchem-1564	236	95	1.534	1.534	NUM
eurjchem-1564	236	96	1.833	1.833	NUM
eurjchem-1564	236	97	1.690	1.690	NUM
eurjchem-1564	236	98	1.740	1.740	NUM
eurjchem-1564	236	99	7	7	NUM
eurjchem-1564	236	100	1.240	1.240	NUM
eurjchem-1564	236	101	1.210	1.210	NUM
eurjchem-1564	236	102	1.255	1.255	NUM
eurjchem-1564	236	103	1.330	1.330	NUM
eurjchem-1564	236	104	1.300	1.300	NUM
eurjchem-1564	236	105	1.349	1.349	NUM
eurjchem-1564	236	106	1.430	1.430	NUM
eurjchem-1564	236	107	1.400	1.400	NUM
eurjchem-1564	236	108	1.432	1.432	NUM
eurjchem-1564	236	109	1.530	1.530	NUM
eurjchem-1564	236	110	1.500	1.500	NUM
eurjchem-1564	236	111	1.521	1.521	NUM
eurjchem-1564	236	112	1.880	1.880	NUM
eurjchem-1564	236	113	1.700	1.700	NUM
eurjchem-1564	236	114	1.727	1.727	NUM
eurjchem-1564	236	115	8	8	NUM
eurjchem-1564	236	116	multiple	multiple	ADJ
eurjchem-1564	236	117	signals	signal	NOUN
eurjchem-1564	236	118	were	be	AUX
eurjchem-1564	236	119	observed	observe	VERB
eurjchem-1564	236	120	at	at	ADP
eurjchem-1564	236	121	1h	1h	NUM
eurjchem-1564	236	122	nmr	nmr	NOUN
eurjchem-1564	236	123	spectra	spectra	NOUN
eurjchem-1564	236	124	of	of	ADP
eurjchem-1564	236	125	complexes	complex	NOUN
eurjchem-1564	236	126	3‐8	3‐8	PROPN
eurjchem-1564	236	127	between	between	ADP
eurjchem-1564	236	128	the	the	DET
eurjchem-1564	236	129	range	range	NOUN
eurjchem-1564	236	130	of	of	ADP
eurjchem-1564	236	131	δ	δ	PROPN
eurjchem-1564	236	132	6.20	6.20	NUM
eurjchem-1564	236	133	and	and	CCONJ
eurjchem-1564	236	134	8.02	8.02	NUM
eurjchem-1564	236	135	ppm	ppm	NOUN
eurjchem-1564	236	136	designed	design	VERB
eurjchem-1564	236	137	by	by	ADP
eurjchem-1564	236	138	aromatic	aromatic	ADJ
eurjchem-1564	236	139	protons	proton	NOUN
eurjchem-1564	236	140	[	[	X
eurjchem-1564	236	141	35‐37	35‐37	NUM
eurjchem-1564	236	142	]	]	PUNCT
eurjchem-1564	236	143	.	.	PUNCT
eurjchem-1564	237	1	on	on	ADP
eurjchem-1564	237	2	the	the	DET
eurjchem-1564	237	3	other	other	ADJ
eurjchem-1564	237	4	hand	hand	NOUN
eurjchem-1564	237	5	,	,	PUNCT
eurjchem-1564	237	6	the	the	DET
eurjchem-1564	237	7	complexes	complex	NOUN
eurjchem-1564	237	8	which	which	PRON
eurjchem-1564	237	9	contain	contain	VERB
eurjchem-1564	237	10	ferrocenyl	ferrocenyl	ADJ
eurjchem-1564	237	11	moiety	moiety	NOUN
eurjchem-1564	237	12	(	(	PUNCT
eurjchem-1564	237	13	i.e.	i.e.	X
eurjchem-1564	237	14	complexes	complex	NOUN
eurjchem-1564	237	15	5‐	5‐	PRON
eurjchem-1564	237	16	8)	8)	NUM
eurjchem-1564	237	17	showed	show	VERB
eurjchem-1564	237	18	all	all	DET
eurjchem-1564	237	19	the	the	DET
eurjchem-1564	237	20	expected	expect	VERB
eurjchem-1564	237	21	proton	proton	NOUN
eurjchem-1564	237	22	signals	signal	NOUN
eurjchem-1564	237	23	which	which	PRON
eurjchem-1564	237	24	are	be	AUX
eurjchem-1564	237	25	in	in	ADP
eurjchem-1564	237	26	a	a	DET
eurjchem-1564	237	27	good	good	ADJ
eurjchem-1564	237	28	agreement	agreement	NOUN
eurjchem-1564	237	29	with	with	ADP
eurjchem-1564	237	30	the	the	DET
eurjchem-1564	237	31	previously	previously	ADV
eurjchem-1564	237	32	literatures	literature	NOUN
eurjchem-1564	237	33	[	[	X
eurjchem-1564	237	34	35‐38	35‐38	X
eurjchem-1564	237	35	]	]	X
eurjchem-1564	237	36	.	.	PUNCT
eurjchem-1564	238	1	these	these	DET
eurjchem-1564	238	2	spectra	spectra	PROPN
eurjchem-1564	238	3	showed	show	VERB
eurjchem-1564	238	4	a	a	DET
eurjchem-1564	238	5	singlet	singlet	ADJ
eurjchem-1564	238	6	signal	signal	NOUN
eurjchem-1564	238	7	in	in	ADP
eurjchem-1564	238	8	the	the	DET
eurjchem-1564	238	9	range	range	NOUN
eurjchem-1564	238	10	δ	δ	PROPN
eurjchem-1564	238	11	4.16‐4.40	4.16‐4.40	NUM
eurjchem-1564	238	12	ppm	ppm	NOUN
eurjchem-1564	238	13	attributed	attribute	VERB
eurjchem-1564	238	14	by	by	ADP
eurjchem-1564	238	15	protons	proton	NOUN
eurjchem-1564	238	16	of	of	ADP
eurjchem-1564	238	17	unsubstituted	unsubstituted	ADJ
eurjchem-1564	238	18	cyclo‐pentadienyl	cyclo‐pentadienyl	NOUN
eurjchem-1564	238	19	ring	ring	NOUN
eurjchem-1564	238	20	because	because	SCONJ
eurjchem-1564	238	21	all	all	DET
eurjchem-1564	238	22	these	these	DET
eurjchem-1564	238	23	protons	proton	NOUN
eurjchem-1564	238	24	are	be	AUX
eurjchem-1564	238	25	magnetically	magnetically	ADV
eurjchem-1564	238	26	equivalent	equivalent	ADJ
eurjchem-1564	238	27	.	.	PUNCT
eurjchem-1564	239	1	the	the	DET
eurjchem-1564	239	2	substituted	substitute	VERB
eurjchem-1564	239	3	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-1564	239	4	ring	ring	NOUN
eurjchem-1564	239	5	appeared	appear	VERB
eurjchem-1564	239	6	two	two	NUM
eurjchem-1564	239	7	singlet	singlet	ADJ
eurjchem-1564	239	8	singles	single	NOUN
eurjchem-1564	239	9	at	at	ADP
eurjchem-1564	239	10	the	the	DET
eurjchem-1564	239	11	ranges	range	NOUN
eurjchem-1564	239	12	δ	δ	PROPN
eurjchem-1564	239	13	4.28‐4.71	4.28‐4.71	NUM
eurjchem-1564	239	14	ppm	ppm	ADJ
eurjchem-1564	239	15	due	due	ADP
eurjchem-1564	239	16	to	to	PART
eurjchem-1564	239	17	(	(	PUNCT
eurjchem-1564	239	18	h2	h2	NOUN
eurjchem-1564	239	19	and	and	CCONJ
eurjchem-1564	239	20	h5	h5	PROPN
eurjchem-1564	239	21	)	)	PUNCT
eurjchem-1564	239	22	;	;	PUNCT
eurjchem-1564	239	23	while	while	SCONJ
eurjchem-1564	239	24	the	the	DET
eurjchem-1564	239	25	second	second	ADJ
eurjchem-1564	239	26	signal	signal	NOUN
eurjchem-1564	239	27	at	at	ADP
eurjchem-1564	239	28	the	the	DET
eurjchem-1564	239	29	range	range	NOUN
eurjchem-1564	239	30	δ	δ	PROPN
eurjchem-1564	239	31	4.35‐4.92	4.35‐4.92	NUM
eurjchem-1564	239	32	ppm	ppm	PROPN
eurjchem-1564	239	33	due	due	ADP
eurjchem-1564	239	34	to	to	ADP
eurjchem-1564	239	35	h3	h3	NOUN
eurjchem-1564	239	36	and	and	CCONJ
eurjchem-1564	239	37	h4	h4	NOUN
eurjchem-1564	239	38	.	.	PUNCT
eurjchem-1564	240	1	these	these	DET
eurjchem-1564	240	2	protons	proton	NOUN
eurjchem-1564	240	3	shifted	shift	VERB
eurjchem-1564	240	4	downfield	downfield	VERB
eurjchem-1564	240	5	because	because	SCONJ
eurjchem-1564	240	6	increasing	increase	VERB
eurjchem-1564	240	7	the	the	DET
eurjchem-1564	240	8	resonance	resonance	NOUN
eurjchem-1564	240	9	due	due	ADP
eurjchem-1564	240	10	to	to	ADP
eurjchem-1564	240	11	the	the	DET
eurjchem-1564	240	12	coordination	coordination	NOUN
eurjchem-1564	240	13	between	between	ADP
eurjchem-1564	240	14	the	the	DET
eurjchem-1564	240	15	corresponding	correspond	VERB
eurjchem-1564	240	16	ligands	ligand	NOUN
eurjchem-1564	240	17	and	and	CCONJ
eurjchem-1564	240	18	the	the	DET
eurjchem-1564	240	19	palladium	palladium	NOUN
eurjchem-1564	240	20	ion	ion	NOUN
eurjchem-1564	240	21	.	.	PUNCT
eurjchem-1564	241	1	furthermore	furthermore	ADV
eurjchem-1564	241	2	,	,	PUNCT
eurjchem-1564	241	3	1h	1h	NUM
eurjchem-1564	241	4	nmr	nmr	NOUN
eurjchem-1564	241	5	spectra	spectra	NOUN
eurjchem-1564	241	6	of	of	ADP
eurjchem-1564	241	7	complexes	complex	NOUN
eurjchem-1564	241	8	7	7	NUM
eurjchem-1564	241	9	and	and	CCONJ
eurjchem-1564	241	10	8	8	NUM
eurjchem-1564	241	11	showed	show	VERB
eurjchem-1564	241	12	a	a	DET
eurjchem-1564	241	13	singlet	singlet	ADJ
eurjchem-1564	241	14	signal	signal	NOUN
eurjchem-1564	241	15	at	at	ADP
eurjchem-1564	241	16	δ	δ	PROPN
eurjchem-1564	241	17	2.50	2.50	NUM
eurjchem-1564	241	18	and	and	CCONJ
eurjchem-1564	241	19	2.98	2.98	NUM
eurjchem-1564	241	20	ppm	ppm	NOUN
eurjchem-1564	241	21	,	,	PUNCT
eurjchem-1564	241	22	respectively	respectively	ADV
eurjchem-1564	241	23	attributed	attribute	VERB
eurjchem-1564	241	24	to	to	ADP
eurjchem-1564	241	25	methyl	methyl	NOUN
eurjchem-1564	241	26	group	group	NOUN
eurjchem-1564	241	27	with	with	ADP
eurjchem-1564	241	28	only	only	ADV
eurjchem-1564	241	29	a	a	DET
eurjchem-1564	241	30	minor	minor	ADJ
eurjchem-1564	241	31	shift	shift	NOUN
eurjchem-1564	241	32	for	for	ADP
eurjchem-1564	241	33	this	this	DET
eurjchem-1564	241	34	signal	signal	NOUN
eurjchem-1564	241	35	could	could	AUX
eurjchem-1564	241	36	be	be	AUX
eurjchem-1564	241	37	observed	observe	VERB
eurjchem-1564	241	38	compared	compare	VERB
eurjchem-1564	241	39	with	with	ADP
eurjchem-1564	241	40	the	the	DET
eurjchem-1564	241	41	corresponding	corresponding	ADJ
eurjchem-1564	241	42	free	free	ADJ
eurjchem-1564	241	43	ligands	ligand	NOUN
eurjchem-1564	241	44	[	[	X
eurjchem-1564	241	45	21	21	NUM
eurjchem-1564	241	46	]	]	PUNCT
eurjchem-1564	241	47	.	.	PUNCT
eurjchem-1564	242	1	in	in	ADP
eurjchem-1564	242	2	vitro	vitro	X
eurjchem-1564	242	3	,	,	PUNCT
eurjchem-1564	242	4	antibacterial	antibacterial	ADJ
eurjchem-1564	242	5	screening	screening	NOUN
eurjchem-1564	242	6	was	be	AUX
eurjchem-1564	242	7	performed	perform	VERB
eurjchem-1564	242	8	by	by	ADP
eurjchem-1564	242	9	the	the	DET
eurjchem-1564	242	10	disc	disc	NOUN
eurjchem-1564	242	11	diffusion	diffusion	NOUN
eurjchem-1564	242	12	method	method	NOUN
eurjchem-1564	242	13	against	against	ADP
eurjchem-1564	242	14	two	two	NUM
eurjchem-1564	242	15	types	type	NOUN
eurjchem-1564	242	16	of	of	ADP
eurjchem-1564	242	17	bacteria	bacteria	NOUN
eurjchem-1564	242	18	:	:	PUNCT
eurjchem-1564	242	19	gram	gram	NUM
eurjchem-1564	242	20	positive	positive	ADJ
eurjchem-1564	242	21	staphylococcus	staphylococcus	NOUN
eurjchem-1564	242	22	aureus	aureus	NOUN
eurjchem-1564	242	23	(	(	PUNCT
eurjchem-1564	242	24	atcc	atcc	NOUN
eurjchem-1564	242	25	25923	25923	NUM
eurjchem-1564	242	26	)	)	PUNCT
eurjchem-1564	242	27	and	and	CCONJ
eurjchem-1564	242	28	gram	gram	NOUN
eurjchem-1564	242	29	negative	negative	ADJ
eurjchem-1564	242	30	escherichia	escherichia	NOUN
eurjchem-1564	242	31	coli	coli	NOUN
eurjchem-1564	242	32	(	(	PUNCT
eurjchem-1564	242	33	atcc	atcc	NOUN
eurjchem-1564	242	34	25922	25922	NUM
eurjchem-1564	242	35	)	)	PUNCT
eurjchem-1564	242	36	bacteria	bacteria	NOUN
eurjchem-1564	242	37	for	for	ADP
eurjchem-1564	242	38	the	the	DET
eurjchem-1564	242	39	primary	primary	ADJ
eurjchem-1564	242	40	selection	selection	NOUN
eurjchem-1564	242	41	of	of	ADP
eurjchem-1564	242	42	the	the	DET
eurjchem-1564	242	43	complexes	complex	NOUN
eurjchem-1564	242	44	as	as	ADP
eurjchem-1564	242	45	a	a	DET
eurjchem-1564	242	46	therapeutic	therapeutic	ADJ
eurjchem-1564	242	47	agents	agent	NOUN
eurjchem-1564	242	48	and	and	CCONJ
eurjchem-1564	242	49	compared	compare	VERB
eurjchem-1564	242	50	with	with	ADP
eurjchem-1564	242	51	commercial	commercial	ADJ
eurjchem-1564	242	52	drug	drug	NOUN
eurjchem-1564	242	53	,	,	PUNCT
eurjchem-1564	242	54	cis‐platin	cis‐platin	PROPN
eurjchem-1564	242	55	.	.	PUNCT
eurjchem-1564	243	1	the	the	DET
eurjchem-1564	243	2	results	result	NOUN
eurjchem-1564	243	3	of	of	ADP
eurjchem-1564	243	4	antibacterial	antibacterial	ADJ
eurjchem-1564	243	5	activity	activity	NOUN
eurjchem-1564	243	6	of	of	ADP
eurjchem-1564	243	7	pd(ii	pd(ii	NOUN
eurjchem-1564	243	8	)	)	PUNCT
eurjchem-1564	243	9	complexes	complex	NOUN
eurjchem-1564	243	10	were	be	AUX
eurjchem-1564	243	11	at	at	ADP
eurjchem-1564	243	12	250	250	NUM
eurjchem-1564	243	13	µg	µg	ADV
eurjchem-1564	243	14	/	/	SYM
eurjchem-1564	243	15	ml	ml	NOUN
eurjchem-1564	243	16	and	and	CCONJ
eurjchem-1564	243	17	minimum	minimum	ADJ
eurjchem-1564	243	18	inhibitory	inhibitory	ADJ
eurjchem-1564	243	19	concentration	concentration	NOUN
eurjchem-1564	243	20	(	(	PUNCT
eurjchem-1564	243	21	mic	mic	ADJ
eurjchem-1564	243	22	)	)	PUNCT
eurjchem-1564	243	23	define	define	NOUN
eurjchem-1564	243	24	as	as	SCONJ
eurjchem-1564	243	25	the	the	DET
eurjchem-1564	243	26	lowest	low	ADJ
eurjchem-1564	243	27	concentration	concentration	NOUN
eurjchem-1564	243	28	of	of	ADP
eurjchem-1564	243	29	the	the	DET
eurjchem-1564	243	30	compound	compound	NOUN
eurjchem-1564	243	31	in	in	ADP
eurjchem-1564	243	32	a	a	DET
eurjchem-1564	243	33	medium	medium	NOUN
eurjchem-1564	243	34	without	without	ADP
eurjchem-1564	243	35	visible	visible	ADJ
eurjchem-1564	243	36	growth	growth	NOUN
eurjchem-1564	243	37	of	of	ADP
eurjchem-1564	243	38	the	the	DET
eurjchem-1564	243	39	test	test	NOUN
eurjchem-1564	243	40	organisms	organism	NOUN
eurjchem-1564	243	41	in	in	ADP
eurjchem-1564	243	42	concentration	concentration	NOUN
eurjchem-1564	243	43	ranging	range	VERB
eurjchem-1564	243	44	from	from	ADP
eurjchem-1564	243	45	1‐250	1‐250	PROPN
eurjchem-1564	243	46	µg	µg	NOUN
eurjchem-1564	243	47	/	/	SYM
eurjchem-1564	243	48	ml	ml	NOUN
eurjchem-1564	243	49	are	be	AUX
eurjchem-1564	243	50	shown	show	VERB
eurjchem-1564	243	51	in	in	ADP
eurjchem-1564	243	52	table	table	NOUN
eurjchem-1564	243	53	1	1	NUM
eurjchem-1564	243	54	.	.	PUNCT
eurjchem-1564	244	1	in	in	ADP
eurjchem-1564	244	2	fact	fact	NOUN
eurjchem-1564	244	3	,	,	PUNCT
eurjchem-1564	244	4	the	the	DET
eurjchem-1564	244	5	results	result	NOUN
eurjchem-1564	244	6	of	of	ADP
eurjchem-1564	244	7	this	this	DET
eurjchem-1564	244	8	study	study	NOUN
eurjchem-1564	244	9	indicate	indicate	VERB
eurjchem-1564	244	10	that	that	SCONJ
eurjchem-1564	244	11	all	all	DET
eurjchem-1564	244	12	palladium(ii	palladium(ii	NOUN
eurjchem-1564	244	13	)	)	PUNCT
eurjchem-1564	244	14	complexes	complex	NOUN
eurjchem-1564	244	15	have	have	VERB
eurjchem-1564	244	16	variable	variable	ADJ
eurjchem-1564	244	17	antibacterial	antibacterial	ADJ
eurjchem-1564	244	18	activity	activity	NOUN
eurjchem-1564	244	19	against	against	ADP
eurjchem-1564	244	20	both	both	DET
eurjchem-1564	244	21	staphylococcus	staphylococcus	NOUN
eurjchem-1564	244	22	aureus	aureus	NOUN
eurjchem-1564	244	23	and	and	CCONJ
eurjchem-1564	244	24	escherichia	escherichia	NOUN
eurjchem-1564	244	25	coli	coli	NOUN
eurjchem-1564	244	26	bacteria	bacteria	NOUN
eurjchem-1564	244	27	.	.	PUNCT
eurjchem-1564	245	1	in	in	ADP
eurjchem-1564	245	2	comparison	comparison	NOUN
eurjchem-1564	245	3	with	with	ADP
eurjchem-1564	245	4	the	the	DET
eurjchem-1564	245	5	ligands	ligand	NOUN
eurjchem-1564	245	6	[	[	X
eurjchem-1564	245	7	21	21	NUM
eurjchem-1564	245	8	]	]	PUNCT
eurjchem-1564	245	9	,	,	PUNCT
eurjchem-1564	245	10	the	the	DET
eurjchem-1564	245	11	palladium(ii	palladium(ii	NOUN
eurjchem-1564	245	12	)	)	PUNCT
eurjchem-1564	245	13	complexes	complex	NOUN
eurjchem-1564	245	14	were	be	AUX
eurjchem-1564	245	15	found	find	VERB
eurjchem-1564	245	16	to	to	PART
eurjchem-1564	245	17	be	be	AUX
eurjchem-1564	245	18	more	more	ADV
eurjchem-1564	245	19	antimicrobial	antimicrobial	ADJ
eurjchem-1564	245	20	activity	activity	NOUN
eurjchem-1564	245	21	.	.	PUNCT
eurjchem-1564	246	1	in	in	ADP
eurjchem-1564	246	2	general	general	ADJ
eurjchem-1564	246	3	,	,	PUNCT
eurjchem-1564	246	4	the	the	DET
eurjchem-1564	246	5	results	result	NOUN
eurjchem-1564	246	6	of	of	ADP
eurjchem-1564	246	7	screening	screen	VERB
eurjchem-1564	246	8	show	show	VERB
eurjchem-1564	246	9	that	that	SCONJ
eurjchem-1564	246	10	most	most	ADJ
eurjchem-1564	246	11	of	of	ADP
eurjchem-1564	246	12	palladium(ii	palladium(ii	NOUN
eurjchem-1564	246	13	)	)	PUNCT
eurjchem-1564	246	14	complexes	complex	NOUN
eurjchem-1564	246	15	which	which	PRON
eurjchem-1564	246	16	contain	contain	VERB
eurjchem-1564	246	17	imino	imino	NOUN
eurjchem-1564	246	18	groups	group	NOUN
eurjchem-1564	246	19	complexes	complexe	VERB
eurjchem-1564	246	20	3‐8	3‐8	PROPN
eurjchem-1564	246	21	are	be	AUX
eurjchem-1564	246	22	more	more	ADV
eurjchem-1564	246	23	antibacterial	antibacterial	ADJ
eurjchem-1564	246	24	active	active	ADJ
eurjchem-1564	246	25	than	than	ADP
eurjchem-1564	246	26	those	those	PRON
eurjchem-1564	246	27	which	which	PRON
eurjchem-1564	246	28	contain	contain	VERB
eurjchem-1564	246	29	amine	amine	ADJ
eurjchem-1564	246	30	groups	group	NOUN
eurjchem-1564	246	31	complexes	complexe	VERB
eurjchem-1564	246	32	1	1	NUM
eurjchem-1564	246	33	and	and	CCONJ
eurjchem-1564	246	34	2	2	NUM
eurjchem-1564	246	35	.	.	PUNCT
eurjchem-1564	247	1	on	on	ADP
eurjchem-1564	247	2	the	the	DET
eurjchem-1564	247	3	other	other	ADJ
eurjchem-1564	247	4	hand	hand	NOUN
eurjchem-1564	247	5	,	,	PUNCT
eurjchem-1564	247	6	the	the	DET
eurjchem-1564	247	7	antibacterial	antibacterial	ADJ
eurjchem-1564	247	8	activity	activity	NOUN
eurjchem-1564	247	9	of	of	ADP
eurjchem-1564	247	10	palladium(ii	palladium(ii	NOUN
eurjchem-1564	247	11	)	)	PUNCT
eurjchem-1564	247	12	complexes	complex	NOUN
eurjchem-1564	247	13	which	which	PRON
eurjchem-1564	247	14	contain	contain	VERB
eurjchem-1564	247	15	ferrocenyl	ferrocenyl	ADJ
eurjchem-1564	247	16	moiety	moiety	NOUN
eurjchem-1564	247	17	,	,	PUNCT
eurjchem-1564	247	18	and	and	CCONJ
eurjchem-1564	247	19	have	have	VERB
eurjchem-1564	247	20	a	a	DET
eurjchem-1564	247	21	better	well	ADJ
eurjchem-1564	247	22	activity	activity	NOUN
eurjchem-1564	247	23	against	against	ADP
eurjchem-1564	247	24	both	both	DET
eurjchem-1564	247	25	staphylococcus	staphylococcus	NOUN
eurjchem-1564	247	26	aureus	aureus	NOUN
eurjchem-1564	247	27	and	and	CCONJ
eurjchem-1564	247	28	escherichia	escherichia	NOUN
eurjchem-1564	247	29	coli	coli	NOUN
eurjchem-1564	247	30	bacteria	bacteria	NOUN
eurjchem-1564	247	31	,	,	PUNCT
eurjchem-1564	247	32	in	in	ADP
eurjchem-1564	247	33	particular	particular	ADJ
eurjchem-1564	247	34	the	the	DET
eurjchem-1564	247	35	complex	complex	NOUN
eurjchem-1564	247	36	5	5	NUM
eurjchem-1564	247	37	showed	show	VERB
eurjchem-1564	247	38	a	a	DET
eurjchem-1564	247	39	maximum	maximum	ADJ
eurjchem-1564	247	40	activity	activity	NOUN
eurjchem-1564	247	41	against	against	ADP
eurjchem-1564	247	42	tested	test	VERB
eurjchem-1564	247	43	bacterial	bacterial	ADJ
eurjchem-1564	247	44	strains	strain	NOUN
eurjchem-1564	247	45	,	,	PUNCT
eurjchem-1564	247	46	whereas	whereas	SCONJ
eurjchem-1564	247	47	complex	complex	ADJ
eurjchem-1564	247	48	4	4	NUM
eurjchem-1564	247	49	which	which	PRON
eurjchem-1564	247	50	contain	contain	VERB
eurjchem-1564	247	51	furan	furan	PROPN
eurjchem-1564	247	52	moiety	moiety	NOUN
eurjchem-1564	247	53	has	have	AUX
eurjchem-1564	247	54	worst	bad	ADJ
eurjchem-1564	247	55	against	against	ADP
eurjchem-1564	247	56	them	they	PRON
eurjchem-1564	247	57	.	.	PUNCT
eurjchem-1564	248	1	finally	finally	ADV
eurjchem-1564	248	2	,	,	PUNCT
eurjchem-1564	248	3	based	base	VERB
eurjchem-1564	248	4	on	on	ADP
eurjchem-1564	248	5	antibacterial	antibacterial	ADJ
eurjchem-1564	248	6	activity	activity	NOUN
eurjchem-1564	248	7	study	study	NOUN
eurjchem-1564	248	8	,	,	PUNCT
eurjchem-1564	248	9	the	the	DET
eurjchem-1564	248	10	palladium(ii	palladium(ii	NOUN
eurjchem-1564	248	11	)	)	PUNCT
eurjchem-1564	248	12	complexes	complex	NOUN
eurjchem-1564	248	13	were	be	AUX
eurjchem-1564	248	14	actively	actively	ADV
eurjchem-1564	248	15	ordered	order	VERB
eurjchem-1564	248	16	against	against	ADP
eurjchem-1564	248	17	both	both	DET
eurjchem-1564	248	18	staphylococcus	staphylococcus	NOUN
eurjchem-1564	248	19	aureus	aureus	NOUN
eurjchem-1564	248	20	and	and	CCONJ
eurjchem-1564	248	21	escherichia	escherichia	NOUN
eurjchem-1564	248	22	coli	coli	NOUN
eurjchem-1564	248	23	bacteria	bacteria	NOUN
eurjchem-1564	248	24	this	this	DET
eurjchem-1564	248	25	way	way	NOUN
eurjchem-1564	248	26	:	:	PUNCT
eurjchem-1564	248	27	5	5	NUM
eurjchem-1564	248	28	>	>	SYM
eurjchem-1564	248	29	7	7	NUM
eurjchem-1564	248	30	>	>	SYM
eurjchem-1564	248	31	6	6	NUM
eurjchem-1564	248	32	>	>	SYM
eurjchem-1564	248	33	8	8	NUM
eurjchem-1564	248	34	>	>	SYM
eurjchem-1564	248	35	3	3	NUM
eurjchem-1564	248	36	>	>	SYM
eurjchem-1564	248	37	4	4	NUM
eurjchem-1564	248	38	>	>	SYM
eurjchem-1564	248	39	1	1	NUM
eurjchem-1564	248	40	>	>	SYM
eurjchem-1564	248	41	2	2	NUM
eurjchem-1564	248	42	.	.	PUNCT
eurjchem-1564	249	1	it	it	PRON
eurjchem-1564	249	2	is	be	AUX
eurjchem-1564	249	3	well	well	ADV
eurjchem-1564	249	4	known	know	VERB
eurjchem-1564	249	5	that	that	SCONJ
eurjchem-1564	249	6	the	the	DET
eurjchem-1564	249	7	complexes	complex	NOUN
eurjchem-1564	249	8	containing	contain	VERB
eurjchem-1564	249	9	schiff	schiff	NOUN
eurjchem-1564	249	10	base	base	NOUN
eurjchem-1564	249	11	ligands	ligand	NOUN
eurjchem-1564	249	12	tend	tend	VERB
eurjchem-1564	249	13	to	to	PART
eurjchem-1564	249	14	powerfully	powerfully	ADV
eurjchem-1564	249	15	act	act	VERB
eurjchem-1564	249	16	as	as	ADP
eurjchem-1564	249	17	potent	potent	ADJ
eurjchem-1564	249	18	bactericidal	bactericidal	ADJ
eurjchem-1564	249	19	agents	agent	NOUN
eurjchem-1564	249	20	to	to	PART
eurjchem-1564	249	21	kill	kill	VERB
eurjchem-1564	249	22	microorganisms	microorganism	NOUN
eurjchem-1564	249	23	.	.	PUNCT
eurjchem-1564	250	1	this	this	PRON
eurjchem-1564	250	2	is	be	AUX
eurjchem-1564	250	3	due	due	ADJ
eurjchem-1564	250	4	the	the	DET
eurjchem-1564	250	5	fact	fact	NOUN
eurjchem-1564	250	6	that	that	SCONJ
eurjchem-1564	250	7	the	the	DET
eurjchem-1564	250	8	metal	metal	NOUN
eurjchem-1564	250	9	has	have	AUX
eurjchem-1564	250	10	partially	partially	ADV
eurjchem-1564	250	11	positive	positive	ADJ
eurjchem-1564	250	12	charge	charge	NOUN
eurjchem-1564	250	13	coordinate	coordinate	NOUN
eurjchem-1564	250	14	with	with	ADP
eurjchem-1564	250	15	the	the	DET
eurjchem-1564	250	16	donor	donor	NOUN
eurjchem-1564	250	17	atom	atom	NOUN
eurjchem-1564	250	18	of	of	ADP
eurjchem-1564	250	19	ligand	ligand	NOUN
eurjchem-1564	250	20	as	as	ADV
eurjchem-1564	250	21	well	well	ADV
eurjchem-1564	250	22	as	as	ADP
eurjchem-1564	250	23	there	there	PRON
eurjchem-1564	250	24	is	be	VERB
eurjchem-1564	250	25	π‐electron	π‐electron	PUNCT
eurjchem-1564	250	26	delocalize	delocalize	NOUN
eurjchem-1564	250	27	over	over	ADP
eurjchem-1564	250	28	the	the	DET
eurjchem-1564	250	29	whole	whole	ADJ
eurjchem-1564	250	30	chelate	chelate	NOUN
eurjchem-1564	250	31	ring	ring	NOUN
eurjchem-1564	250	32	.	.	PUNCT
eurjchem-1564	251	1	as	as	ADP
eurjchem-1564	251	2	a	a	DET
eurjchem-1564	251	3	result	result	NOUN
eurjchem-1564	251	4	,	,	PUNCT
eurjchem-1564	251	5	this	this	PRON
eurjchem-1564	251	6	increases	increase	VERB
eurjchem-1564	251	7	the	the	DET
eurjchem-1564	251	8	lipophilic	lipophilic	ADJ
eurjchem-1564	251	9	character	character	NOUN
eurjchem-1564	251	10	of	of	ADP
eurjchem-1564	251	11	the	the	DET
eurjchem-1564	251	12	metal	metal	NOUN
eurjchem-1564	251	13	chelate	chelate	NOUN
eurjchem-1564	251	14	,	,	PUNCT
eurjchem-1564	251	15	which	which	PRON
eurjchem-1564	251	16	favors	favor	VERB
eurjchem-1564	251	17	its	its	PRON
eurjchem-1564	251	18	permeation	permeation	NOUN
eurjchem-1564	251	19	through	through	ADP
eurjchem-1564	251	20	the	the	DET
eurjchem-1564	251	21	lipoid	lipoid	ADJ
eurjchem-1564	251	22	layers	layer	NOUN
eurjchem-1564	251	23	of	of	ADP
eurjchem-1564	251	24	the	the	DET
eurjchem-1564	251	25	microorganism	microorganism	NOUN
eurjchem-1564	251	26	membranes	membrane	NOUN
eurjchem-1564	251	27	.	.	PUNCT
eurjchem-1564	252	1	in	in	ADP
eurjchem-1564	252	2	addition	addition	NOUN
eurjchem-1564	252	3	,	,	PUNCT
eurjchem-1564	252	4	other	other	ADJ
eurjchem-1564	252	5	factors	factor	NOUN
eurjchem-1564	252	6	such	such	ADJ
eurjchem-1564	252	7	as	as	ADP
eurjchem-1564	252	8	solubility	solubility	NOUN
eurjchem-1564	252	9	conductivity	conductivity	NOUN
eurjchem-1564	252	10	and	and	CCONJ
eurjchem-1564	252	11	dipole	dipole	NOUN
eurjchem-1564	252	12	al‐fregi	al‐fregi	PROPN
eurjchem-1564	252	13	et	et	NOUN
eurjchem-1564	252	14	al	al	PROPN
eurjchem-1564	252	15	.	.	PUNCT
eurjchem-1564	252	16	/	/	SYM
eurjchem-1564	252	17	european	european	PROPN
eurjchem-1564	252	18	journal	journal	PROPN
eurjchem-1564	252	19	of	of	ADP
eurjchem-1564	252	20	chemistry	chemistry	NOUN
eurjchem-1564	252	21	8	8	NUM
eurjchem-1564	252	22	(	(	PUNCT
eurjchem-1564	252	23	2	2	NUM
eurjchem-1564	252	24	)	)	PUNCT
eurjchem-1564	252	25	(	(	PUNCT
eurjchem-1564	252	26	2017	2017	NUM
eurjchem-1564	252	27	)	)	PUNCT
eurjchem-1564	252	28	155‐161	155‐161	NUM
eurjchem-1564	252	29	161	161	NUM
eurjchem-1564	252	30	moment	moment	NOUN
eurjchem-1564	252	31	may	may	AUX
eurjchem-1564	252	32	also	also	ADV
eurjchem-1564	252	33	be	be	AUX
eurjchem-1564	252	34	the	the	DET
eurjchem-1564	252	35	possible	possible	ADJ
eurjchem-1564	252	36	reasons	reason	NOUN
eurjchem-1564	252	37	of	of	ADP
eurjchem-1564	252	38	increasing	increase	VERB
eurjchem-1564	252	39	activity	activity	NOUN
eurjchem-1564	252	40	.	.	PUNCT
eurjchem-1564	253	1	the	the	DET
eurjchem-1564	253	2	interaction	interaction	NOUN
eurjchem-1564	253	3	between	between	ADP
eurjchem-1564	253	4	the	the	DET
eurjchem-1564	253	5	prepared	prepare	VERB
eurjchem-1564	253	6	complexes	complex	NOUN
eurjchem-1564	253	7	1‐8	1‐8	PROPN
eurjchem-1564	253	8	and	and	CCONJ
eurjchem-1564	253	9	human	human	ADJ
eurjchem-1564	253	10	dna	dna	PROPN
eurjchem-1564	253	11	was	be	AUX
eurjchem-1564	253	12	studied	study	VERB
eurjchem-1564	253	13	by	by	ADP
eurjchem-1564	253	14	using	use	VERB
eurjchem-1564	253	15	uv.‐visible	uv.‐visible	ADJ
eurjchem-1564	253	16	spectroscopy	spectroscopy	NOUN
eurjchem-1564	253	17	.	.	PUNCT
eurjchem-1564	254	1	the	the	DET
eurjchem-1564	254	2	change	change	NOUN
eurjchem-1564	254	3	complexes	complex	NOUN
eurjchem-1564	254	4	’	'	PUNCT
eurjchem-1564	254	5	concentrations	concentration	NOUN
eurjchem-1564	254	6	(	(	PUNCT
eurjchem-1564	254	7	2	2	NUM
eurjchem-1564	254	8	ml	ml	NOUN
eurjchem-1564	254	9	of	of	ADP
eurjchem-1564	254	10	80	80	NUM
eurjchem-1564	254	11	µm	µm	NOUN
eurjchem-1564	254	12	)	)	PUNCT
eurjchem-1564	254	13	with	with	ADP
eurjchem-1564	254	14	the	the	DET
eurjchem-1564	254	15	time	time	NOUN
eurjchem-1564	254	16	(	(	PUNCT
eurjchem-1564	254	17	0	0	NUM
eurjchem-1564	254	18	,	,	PUNCT
eurjchem-1564	254	19	1	1	NUM
eurjchem-1564	254	20	,	,	PUNCT
eurjchem-1564	254	21	2	2	NUM
eurjchem-1564	254	22	,	,	PUNCT
eurjchem-1564	254	23	24	24	NUM
eurjchem-1564	254	24	h	h	NOUN
eurjchem-1564	254	25	and	and	CCONJ
eurjchem-1564	254	26	1	1	NUM
eurjchem-1564	254	27	week	week	NOUN
eurjchem-1564	254	28	)	)	PUNCT
eurjchem-1564	254	29	were	be	AUX
eurjchem-1564	254	30	followed	follow	VERB
eurjchem-1564	254	31	by	by	ADP
eurjchem-1564	254	32	adding	add	VERB
eurjchem-1564	254	33	the	the	DET
eurjchem-1564	254	34	human	human	ADJ
eurjchem-1564	254	35	dna	dna	NOUN
eurjchem-1564	254	36	(	(	PUNCT
eurjchem-1564	254	37	2	2	NUM
eurjchem-1564	254	38	ml	ml	NOUN
eurjchem-1564	254	39	of	of	ADP
eurjchem-1564	254	40	80	80	NUM
eurjchem-1564	254	41	µg	µg	NOUN
eurjchem-1564	254	42	)	)	PUNCT
eurjchem-1564	254	43	.	.	PUNCT
eurjchem-1564	255	1	these	these	DET
eurjchem-1564	255	2	data	datum	NOUN
eurjchem-1564	255	3	confirm	confirm	VERB
eurjchem-1564	255	4	the	the	DET
eurjchem-1564	255	5	interaction	interaction	NOUN
eurjchem-1564	255	6	between	between	ADP
eurjchem-1564	255	7	the	the	DET
eurjchem-1564	255	8	complexes	complex	NOUN
eurjchem-1564	255	9	1‐8	1‐8	PROPN
eurjchem-1564	255	10	and	and	CCONJ
eurjchem-1564	255	11	human	human	ADJ
eurjchem-1564	255	12	dna	dna	NOUN
eurjchem-1564	255	13	by	by	ADP
eurjchem-1564	255	14	decreasing	decrease	VERB
eurjchem-1564	255	15	the	the	DET
eurjchem-1564	255	16	band	band	NOUN
eurjchem-1564	255	17	absorbance	absorbance	NOUN
eurjchem-1564	255	18	,	,	PUNCT
eurjchem-1564	255	19	table	table	NOUN
eurjchem-1564	255	20	2	2	NUM
eurjchem-1564	255	21	,	,	PUNCT
eurjchem-1564	255	22	figure	figure	NOUN
eurjchem-1564	255	23	1	1	NUM
eurjchem-1564	255	24	(	(	PUNCT
eurjchem-1564	255	25	as	as	ADP
eurjchem-1564	255	26	an	an	DET
eurjchem-1564	255	27	example	example	NOUN
eurjchem-1564	255	28	)	)	PUNCT
eurjchem-1564	255	29	.	.	PUNCT
eurjchem-1564	256	1	0.0	0.0	NUM
eurjchem-1564	256	2	0.2	0.2	NUM
eurjchem-1564	256	3	0.4	0.4	NUM
eurjchem-1564	256	4	0.6	0.6	NUM
eurjchem-1564	256	5	0.8	0.8	NUM
eurjchem-1564	256	6	1.0	1.0	NUM
eurjchem-1564	256	7	1.2	1.2	NUM
eurjchem-1564	256	8	1.4	1.4	NUM
eurjchem-1564	256	9	1.6	1.6	NUM
eurjchem-1564	256	10	1.8	1.8	NUM
eurjchem-1564	256	11	2.0	2.0	NUM
eurjchem-1564	256	12	200	200	NUM
eurjchem-1564	256	13	300	300	NUM
eurjchem-1564	256	14	400	400	NUM
eurjchem-1564	256	15	500	500	NUM
eurjchem-1564	256	16	600	600	NUM
eurjchem-1564	256	17	700	700	NUM
eurjchem-1564	256	18	800	800	NUM
eurjchem-1564	256	19	a	a	DET
eurjchem-1564	256	20	b	b	NOUN
eurjchem-1564	256	21	so	so	SCONJ
eurjchem-1564	256	22	rb	rb	VERB
eurjchem-1564	256	23	an	an	DET
eurjchem-1564	256	24	c	c	NOUN
eurjchem-1564	256	25	e	e	NOUN
eurjchem-1564	256	26	wavelength	wavelength	NOUN
eurjchem-1564	256	27	(	(	PUNCT
eurjchem-1564	256	28	nm	nm	NOUN
eurjchem-1564	256	29	)	)	PUNCT
eurjchem-1564	256	30	before	before	ADP
eurjchem-1564	256	31	mix	mix	NOUN
eurjchem-1564	256	32	with	with	ADP
eurjchem-1564	256	33	human	human	ADJ
eurjchem-1564	256	34	dna	dna	PROPN
eurjchem-1564	256	35	after	after	ADP
eurjchem-1564	256	36	1	1	NUM
eurjchem-1564	256	37	min	min	NOUN
eurjchem-1564	256	38	mix	mix	NOUN
eurjchem-1564	256	39	with	with	ADP
eurjchem-1564	256	40	human	human	ADJ
eurjchem-1564	256	41	dna	dna	PROPN
eurjchem-1564	256	42	after	after	ADP
eurjchem-1564	256	43	1	1	NUM
eurjchem-1564	256	44	h	h	NOUN
eurjchem-1564	256	45	mix	mix	NOUN
eurjchem-1564	256	46	with	with	ADP
eurjchem-1564	256	47	human	human	ADJ
eurjchem-1564	256	48	dna	dna	PROPN
eurjchem-1564	256	49	after	after	ADP
eurjchem-1564	256	50	24	24	NUM
eurjchem-1564	256	51	h	h	NOUN
eurjchem-1564	256	52	mix	mix	NOUN
eurjchem-1564	256	53	with	with	ADP
eurjchem-1564	256	54	human	human	ADJ
eurjchem-1564	256	55	dna	dna	PROPN
eurjchem-1564	256	56	after	after	ADP
eurjchem-1564	256	57	1	1	NUM
eurjchem-1564	256	58	week	week	NOUN
eurjchem-1564	256	59	mix	mix	NOUN
eurjchem-1564	256	60	with	with	ADP
eurjchem-1564	256	61	human	human	ADJ
eurjchem-1564	256	62	dna	dna	PROPN
eurjchem-1564	256	63	figure	figure	NOUN
eurjchem-1564	256	64	1	1	NUM
eurjchem-1564	256	65	.	.	PUNCT
eurjchem-1564	257	1	uv‐visible	uv‐visible	ADJ
eurjchem-1564	257	2	spectrum	spectrum	NOUN
eurjchem-1564	257	3	of	of	ADP
eurjchem-1564	257	4	complex	complex	ADJ
eurjchem-1564	257	5	1	1	NUM
eurjchem-1564	257	6	with	with	ADP
eurjchem-1564	257	7	human	human	ADJ
eurjchem-1564	257	8	dna	dna	NOUN
eurjchem-1564	257	9	at	at	ADP
eurjchem-1564	257	10	different	different	ADJ
eurjchem-1564	257	11	times	time	NOUN
eurjchem-1564	257	12	.	.	PUNCT
eurjchem-1564	258	1	4	4	X
eurjchem-1564	258	2	.	.	X
eurjchem-1564	258	3	conclusions	conclusion	NOUN
eurjchem-1564	258	4	in	in	ADP
eurjchem-1564	258	5	summary	summary	NOUN
eurjchem-1564	258	6	,	,	PUNCT
eurjchem-1564	258	7	we	we	PRON
eurjchem-1564	258	8	have	have	AUX
eurjchem-1564	258	9	prepared	prepare	VERB
eurjchem-1564	258	10	eight	eight	NUM
eurjchem-1564	258	11	of	of	ADP
eurjchem-1564	258	12	bidentate	bidentate	NOUN
eurjchem-1564	258	13	amine	amine	ADJ
eurjchem-1564	258	14	and	and	CCONJ
eurjchem-1564	258	15	schiff	schiff	NOUN
eurjchem-1564	258	16	base	base	NOUN
eurjchem-1564	258	17	palladium(ii	palladium(ii	PROPN
eurjchem-1564	258	18	)	)	PUNCT
eurjchem-1564	258	19	complexes	complex	NOUN
eurjchem-1564	258	20	.	.	PUNCT
eurjchem-1564	259	1	the	the	DET
eurjchem-1564	259	2	resulting	result	VERB
eurjchem-1564	259	3	complexes	complex	NOUN
eurjchem-1564	259	4	assume	assume	VERB
eurjchem-1564	259	5	a	a	DET
eurjchem-1564	259	6	neutral	neutral	ADJ
eurjchem-1564	259	7	square	square	ADJ
eurjchem-1564	259	8	planar	planar	ADJ
eurjchem-1564	259	9	configuration	configuration	NOUN
eurjchem-1564	259	10	in	in	ADP
eurjchem-1564	259	11	cis‐	cis‐	NOUN
eurjchem-1564	259	12	form	form	NOUN
eurjchem-1564	259	13	.	.	PUNCT
eurjchem-1564	260	1	we	we	PRON
eurjchem-1564	260	2	are	be	AUX
eurjchem-1564	260	3	examining	examine	VERB
eurjchem-1564	260	4	the	the	DET
eurjchem-1564	260	5	biological	biological	ADJ
eurjchem-1564	260	6	activity	activity	NOUN
eurjchem-1564	260	7	for	for	ADP
eurjchem-1564	260	8	antibacterial	antibacterial	ADJ
eurjchem-1564	260	9	activity	activity	NOUN
eurjchem-1564	260	10	of	of	ADP
eurjchem-1564	260	11	all	all	DET
eurjchem-1564	260	12	the	the	DET
eurjchem-1564	260	13	prepared	prepared	ADJ
eurjchem-1564	260	14	complexes	complex	NOUN
eurjchem-1564	260	15	1‐8	1‐8	PROPN
eurjchem-1564	260	16	beside	beside	ADP
eurjchem-1564	260	17	their	their	PRON
eurjchem-1564	260	18	interaction	interaction	NOUN
eurjchem-1564	260	19	with	with	ADP
eurjchem-1564	260	20	human	human	ADJ
eurjchem-1564	260	21	dna	dna	PROPN
eurjchem-1564	260	22	.	.	PUNCT
eurjchem-1564	261	1	the	the	DET
eurjchem-1564	261	2	antibacterial	antibacterial	ADJ
eurjchem-1564	261	3	activity	activity	NOUN
eurjchem-1564	261	4	of	of	ADP
eurjchem-1564	261	5	compounds	compound	NOUN
eurjchem-1564	261	6	1‐8	1‐8	PROPN
eurjchem-1564	261	7	against	against	ADP
eurjchem-1564	261	8	two	two	NUM
eurjchem-1564	261	9	types	type	NOUN
eurjchem-1564	261	10	of	of	ADP
eurjchem-1564	261	11	bacterial	bacterial	ADJ
eurjchem-1564	261	12	:	:	PUNCT
eurjchem-1564	261	13	the	the	DET
eurjchem-1564	261	14	first	first	ADJ
eurjchem-1564	261	15	negative	negative	ADJ
eurjchem-1564	261	16	towards	towards	ADP
eurjchem-1564	261	17	gram	gram	NOUN
eurjchem-1564	261	18	stain	stain	NOUN
eurjchem-1564	261	19	(	(	PUNCT
eurjchem-1564	261	20	escherichia	escherichia	NOUN
eurjchem-1564	261	21	coli	coli	NOUN
eurjchem-1564	261	22	)	)	PUNCT
eurjchem-1564	261	23	and	and	CCONJ
eurjchem-1564	261	24	against	against	ADP
eurjchem-1564	261	25	positive	positive	ADJ
eurjchem-1564	261	26	towards	towards	ADP
eurjchem-1564	261	27	gram	gram	NOUN
eurjchem-1564	261	28	stain	stain	NOUN
eurjchem-1564	261	29	(	(	PUNCT
eurjchem-1564	261	30	staphylococcus	staphylococcus	NOUN
eurjchem-1564	261	31	aureus	aureus	NOUN
eurjchem-1564	261	32	)	)	PUNCT
eurjchem-1564	261	33	was	be	AUX
eurjchem-1564	261	34	tested	test	VERB
eurjchem-1564	261	35	.	.	PUNCT
eurjchem-1564	262	1	these	these	DET
eurjchem-1564	262	2	data	datum	NOUN
eurjchem-1564	262	3	proved	prove	VERB
eurjchem-1564	262	4	that	that	SCONJ
eurjchem-1564	262	5	all	all	DET
eurjchem-1564	262	6	palladium(ii	palladium(ii	NOUN
eurjchem-1564	262	7	)	)	PUNCT
eurjchem-1564	262	8	complexes	complex	NOUN
eurjchem-1564	262	9	show	show	VERB
eurjchem-1564	262	10	a	a	DET
eurjchem-1564	262	11	significant	significant	ADJ
eurjchem-1564	262	12	antibacterial	antibacterial	ADJ
eurjchem-1564	262	13	activity	activity	NOUN
eurjchem-1564	262	14	for	for	ADP
eurjchem-1564	262	15	growth	growth	NOUN
eurjchem-1564	262	16	inhibition	inhibition	NOUN
eurjchem-1564	262	17	of	of	ADP
eurjchem-1564	262	18	staphylococcus	staphylococcus	NOUN
eurjchem-1564	262	19	aureus	aureus	NOUN
eurjchem-1564	262	20	and	and	CCONJ
eurjchem-1564	262	21	escherichia	escherichia	NOUN
eurjchem-1564	262	22	coli	coli	NOUN
eurjchem-1564	262	23	bacteria	bacteria	NOUN
eurjchem-1564	262	24	.	.	PUNCT
eurjchem-1564	263	1	antibacterial	antibacterial	ADJ
eurjchem-1564	263	2	activity	activity	NOUN
eurjchem-1564	263	3	of	of	ADP
eurjchem-1564	263	4	all	all	DET
eurjchem-1564	263	5	palladium(ii	palladium(ii	NOUN
eurjchem-1564	263	6	)	)	PUNCT
eurjchem-1564	263	7	complexes	complex	NOUN
eurjchem-1564	263	8	show	show	VERB
eurjchem-1564	263	9	slightly	slightly	ADV
eurjchem-1564	263	10	active	active	ADJ
eurjchem-1564	263	11	against	against	ADP
eurjchem-1564	263	12	gram	gram	NOUN
eurjchem-1564	263	13	negative	negative	ADJ
eurjchem-1564	263	14	bacteria	bacteria	NOUN
eurjchem-1564	263	15	and	and	CCONJ
eurjchem-1564	263	16	has	have	VERB
eurjchem-1564	263	17	a	a	DET
eurjchem-1564	263	18	better	well	ADJ
eurjchem-1564	263	19	activity	activity	NOUN
eurjchem-1564	263	20	against	against	ADP
eurjchem-1564	263	21	gram	gram	NOUN
eurjchem-1564	263	22	positive	positive	ADJ
eurjchem-1564	263	23	bacteria	bacteria	NOUN
eurjchem-1564	263	24	which	which	DET
eurjchem-1564	263	25	complex	complex	ADJ
eurjchem-1564	263	26	5	5	NUM
eurjchem-1564	263	27	showed	show	VERB
eurjchem-1564	263	28	a	a	DET
eurjchem-1564	263	29	maximum	maximum	ADJ
eurjchem-1564	263	30	activity	activity	NOUN
eurjchem-1564	263	31	against	against	ADP
eurjchem-1564	263	32	both	both	DET
eurjchem-1564	263	33	tested	test	VERB
eurjchem-1564	263	34	bacteria	bacteria	NOUN
eurjchem-1564	263	35	strains	strain	VERB
eurjchem-1564	263	36	40	40	NUM
eurjchem-1564	263	37	and	and	CCONJ
eurjchem-1564	263	38	50	50	NUM
eurjchem-1564	263	39	mm	mm	NOUN
eurjchem-1564	263	40	,	,	PUNCT
eurjchem-1564	263	41	respectively	respectively	ADV
eurjchem-1564	263	42	.	.	PUNCT
eurjchem-1564	264	1	on	on	ADP
eurjchem-1564	264	2	the	the	DET
eurjchem-1564	264	3	other	other	ADJ
eurjchem-1564	264	4	hand	hand	NOUN
eurjchem-1564	264	5	,	,	PUNCT
eurjchem-1564	264	6	dna	dna	NOUN
eurjchem-1564	264	7	interaction	interaction	NOUN
eurjchem-1564	264	8	study	study	NOUN
eurjchem-1564	264	9	of	of	ADP
eurjchem-1564	264	10	complexes	complex	NOUN
eurjchem-1564	264	11	1‐8	1‐8	PROPN
eurjchem-1564	264	12	with	with	ADP
eurjchem-1564	264	13	human	human	ADJ
eurjchem-1564	264	14	dna	dna	PROPN
eurjchem-1564	264	15	showed	show	VERB
eurjchem-1564	264	16	that	that	SCONJ
eurjchem-1564	264	17	all	all	DET
eurjchem-1564	264	18	these	these	DET
eurjchem-1564	264	19	complexes	complex	NOUN
eurjchem-1564	264	20	are	be	AUX
eurjchem-1564	264	21	binding	bind	VERB
eurjchem-1564	264	22	with	with	ADP
eurjchem-1564	264	23	dna	dna	NOUN
eurjchem-1564	264	24	which	which	PRON
eurjchem-1564	264	25	is	be	AUX
eurjchem-1564	264	26	enhances	enhance	VERB
eurjchem-1564	264	27	the	the	DET
eurjchem-1564	264	28	probability	probability	NOUN
eurjchem-1564	264	29	of	of	ADP
eurjchem-1564	264	30	using	use	VERB
eurjchem-1564	264	31	these	these	DET
eurjchem-1564	264	32	complexes	complex	NOUN
eurjchem-1564	264	33	as	as	ADP
eurjchem-1564	264	34	drug	drug	NOUN
eurjchem-1564	264	35	.	.	PUNCT
eurjchem-1564	265	1	acknowledgements	acknowledgement	NOUN
eurjchem-1564	265	2	authors	author	NOUN
eurjchem-1564	265	3	are	be	AUX
eurjchem-1564	265	4	grateful	grateful	ADJ
eurjchem-1564	265	5	for	for	ADP
eurjchem-1564	265	6	department	department	NOUN
eurjchem-1564	265	7	of	of	ADP
eurjchem-1564	265	8	chemistry	chemistry	NOUN
eurjchem-1564	265	9	,	,	PUNCT
eurjchem-1564	265	10	college	college	NOUN
eurjchem-1564	265	11	of	of	ADP
eurjchem-1564	265	12	science	science	NOUN
eurjchem-1564	265	13	,	,	PUNCT
eurjchem-1564	265	14	university	university	NOUN
eurjchem-1564	265	15	of	of	ADP
eurjchem-1564	265	16	basra	basra	PROPN
eurjchem-1564	265	17	for	for	ADP
eurjchem-1564	265	18	supporting	support	VERB
eurjchem-1564	265	19	this	this	DET
eurjchem-1564	265	20	work	work	NOUN
eurjchem-1564	265	21	.	.	PUNCT
eurjchem-1564	266	1	we	we	PRON
eurjchem-1564	266	2	also	also	ADV
eurjchem-1564	266	3	thank	thank	VERB
eurjchem-1564	266	4	dr	dr	PROPN
eurjchem-1564	266	5	.	.	PROPN
eurjchem-1564	266	6	afrodet	afrodet	PROPN
eurjchem-1564	266	7	abdul‐razaq	abdul‐razaq	PROPN
eurjchem-1564	266	8	for	for	ADP
eurjchem-1564	266	9	providing	provide	VERB
eurjchem-1564	266	10	human	human	ADJ
eurjchem-1564	266	11	dna	dna	PROPN
eurjchem-1564	266	12	.	.	PUNCT
eurjchem-1564	267	1	reference	reference	NOUN
eurjchem-1564	268	1	[	[	X
eurjchem-1564	268	2	1	1	NUM
eurjchem-1564	268	3	]	]	PUNCT
eurjchem-1564	268	4	.	.	PUNCT
eurjchem-1564	269	1	cragg	cragg	PROPN
eurjchem-1564	269	2	,	,	PUNCT
eurjchem-1564	269	3	g.	g.	PROPN
eurjchem-1564	269	4	m.	m.	PROPN
eurjchem-1564	269	5	;	;	PUNCT
eurjchem-1564	269	6	grothaus	grothaus	PROPN
eurjchem-1564	269	7	,	,	PUNCT
eurjchem-1564	269	8	p.	p.	PROPN
eurjchem-1564	269	9	g.	g.	PROPN
eurjchem-1564	269	10	;	;	PUNCT
eurjchem-1564	269	11	newman	newman	PROPN
eurjchem-1564	269	12	,	,	PUNCT
eurjchem-1564	269	13	d.	d.	PROPN
eurjchem-1564	269	14	j.	j.	PROPN
eurjchem-1564	269	15	chem	chem	PROPN
eurjchem-1564	269	16	.	.	PUNCT
eurjchem-1564	270	1	rev	rev	PROPN
eurjchem-1564	270	2	.	.	PROPN
eurjchem-1564	270	3	2009	2009	NUM
eurjchem-1564	270	4	,	,	PUNCT
eurjchem-1564	270	5	109	109	NUM
eurjchem-1564	270	6	,	,	PUNCT
eurjchem-1564	270	7	3012‐3043	3012‐3043	NUM
eurjchem-1564	270	8	.	.	PUNCT
eurjchem-1564	271	1	[	[	X
eurjchem-1564	271	2	2	2	NUM
eurjchem-1564	271	3	]	]	PUNCT
eurjchem-1564	271	4	.	.	PUNCT
eurjchem-1564	272	1	fuertes	fuertes	PROPN
eurjchem-1564	272	2	,	,	PUNCT
eurjchem-1564	272	3	a.	a.	NOUN
eurjchem-1564	272	4	m.	m.	PROPN
eurjchem-1564	272	5	a.	a.	PROPN
eurjchem-1564	272	6	;	;	PUNCT
eurjchem-1564	272	7	perez	perez	PROPN
eurjchem-1564	272	8	,	,	PUNCT
eurjchem-1564	272	9	j.	j.	PROPN
eurjchem-1564	272	10	m.	m.	PROPN
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eurjchem-1564	273	4	,	,	PUNCT
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eurjchem-1564	273	7	,	,	PUNCT
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eurjchem-1564	273	9	.	.	PUNCT
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eurjchem-1564	274	2	3	3	NUM
eurjchem-1564	274	3	]	]	PUNCT
eurjchem-1564	274	4	.	.	PUNCT
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eurjchem-1564	275	2	,	,	PUNCT
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eurjchem-1564	275	4	;	;	PUNCT
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eurjchem-1564	276	3	,	,	PUNCT
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eurjchem-1564	276	7	.	.	PUNCT
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eurjchem-1564	277	2	4	4	NUM
eurjchem-1564	277	3	]	]	PUNCT
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eurjchem-1564	278	2	5	5	NUM
eurjchem-1564	278	3	]	]	PUNCT
eurjchem-1564	278	4	.	.	PUNCT
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eurjchem-1564	278	24	.	.	PUNCT
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eurjchem-1564	279	2	.	.	PUNCT
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eurjchem-1564	280	3	,	,	PUNCT
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eurjchem-1564	280	5	)	)	PUNCT
eurjchem-1564	280	6	,	,	PUNCT
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eurjchem-1564	280	8	.	.	PUNCT
eurjchem-1564	281	1	[	[	X
eurjchem-1564	281	2	6	6	NUM
eurjchem-1564	281	3	]	]	PUNCT
eurjchem-1564	281	4	.	.	PUNCT
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eurjchem-1564	282	3	a.	a.	PROPN
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eurjchem-1564	282	5	;	;	PUNCT
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eurjchem-1564	283	2	:	:	PUNCT
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eurjchem-1564	284	2	7	7	NUM
eurjchem-1564	284	3	]	]	PUNCT
eurjchem-1564	284	4	.	.	PUNCT
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eurjchem-1564	284	6	,	,	PUNCT
eurjchem-1564	284	7	h.	h.	PROPN
eurjchem-1564	284	8	;	;	PUNCT
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eurjchem-1564	284	20	a.	a.	NOUN
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eurjchem-1564	287	4	,	,	PUNCT
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eurjchem-1564	288	4	.	.	PUNCT
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eurjchem-1564	289	5	;	;	PUNCT
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eurjchem-1564	290	4	.	.	PUNCT
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eurjchem-1564	291	5	;	;	PUNCT
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eurjchem-1564	292	4	.	.	PUNCT
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eurjchem-1564	293	2	,	,	PUNCT
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eurjchem-1564	293	4	,	,	PUNCT
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eurjchem-1564	294	4	.	.	PUNCT
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eurjchem-1564	295	5	;	;	PUNCT
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eurjchem-1564	296	2	,	,	PUNCT
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eurjchem-1564	298	42	,	,	PUNCT
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eurjchem-1564	299	1	[	[	X
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eurjchem-1564	299	4	.	.	PUNCT
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eurjchem-1564	301	2	.	.	PUNCT
eurjchem-1564	302	1	[	[	X
eurjchem-1564	302	2	13	13	NUM
eurjchem-1564	302	3	]	]	PUNCT
eurjchem-1564	302	4	.	.	PUNCT
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eurjchem-1564	303	9	;	;	PUNCT
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eurjchem-1564	303	12	h.	h.	PROPN
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eurjchem-1564	303	14	;	;	PUNCT
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eurjchem-1564	303	21	.	.	PUNCT
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eurjchem-1564	304	2	.	.	PUNCT
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eurjchem-1564	306	4	.	.	PUNCT
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eurjchem-1564	307	5	;	;	PUNCT
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eurjchem-1564	308	5	.	.	PUNCT
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eurjchem-1564	309	2	,	,	PUNCT
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eurjchem-1564	309	4	,	,	PUNCT
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eurjchem-1564	309	6	.	.	PUNCT
eurjchem-1564	310	1	[	[	X
eurjchem-1564	310	2	15	15	NUM
eurjchem-1564	310	3	]	]	PUNCT
eurjchem-1564	310	4	.	.	PUNCT
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eurjchem-1564	310	6	,	,	PUNCT
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eurjchem-1564	310	9	.	.	PUNCT
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eurjchem-1564	311	2	.	.	PUNCT
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eurjchem-1564	312	3	,	,	PUNCT
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eurjchem-1564	312	5	,	,	PUNCT
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eurjchem-1564	312	7	.	.	PUNCT
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eurjchem-1564	313	3	]	]	PUNCT
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eurjchem-1564	315	2	.	.	PROPN
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eurjchem-1564	316	2	,	,	PUNCT
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eurjchem-1564	316	4	,	,	PUNCT
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eurjchem-1564	317	3	]	]	PUNCT
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eurjchem-1564	318	8	.	.	PUNCT
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eurjchem-1564	319	2	,	,	PUNCT
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eurjchem-1564	319	4	,	,	PUNCT
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eurjchem-1564	319	6	.	.	PUNCT
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eurjchem-1564	320	3	]	]	PUNCT
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eurjchem-1564	322	4	,	,	PUNCT
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eurjchem-1564	322	6	,	,	PUNCT
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eurjchem-1564	323	3	]	]	PUNCT
eurjchem-1564	323	4	.	.	PUNCT
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eurjchem-1564	324	2	,	,	PUNCT
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eurjchem-1564	325	2	.	.	PUNCT
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eurjchem-1564	327	2	20	20	NUM
eurjchem-1564	327	3	]	]	PUNCT
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eurjchem-1564	328	2	,	,	PUNCT
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eurjchem-1564	331	3	]	]	PUNCT
eurjchem-1564	331	4	.	.	PUNCT
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eurjchem-1564	332	2	,	,	PUNCT
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eurjchem-1564	333	3	]	]	PUNCT
eurjchem-1564	333	4	.	.	PUNCT
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eurjchem-1564	334	5	;	;	PUNCT
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eurjchem-1564	334	7	,	,	PUNCT
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eurjchem-1564	335	2	.	.	PUNCT
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eurjchem-1564	336	2	,	,	PUNCT
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eurjchem-1564	340	2	.	.	PROPN
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eurjchem-1564	341	4	.	.	PUNCT
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eurjchem-1564	343	2	,	,	PUNCT
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eurjchem-1564	350	4	.	.	PUNCT
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eurjchem-1564	351	5	;	;	PUNCT
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eurjchem-1564	357	7	,	,	PUNCT
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eurjchem-1564	360	3	]	]	PUNCT
eurjchem-1564	360	4	.	.	PUNCT
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eurjchem-1564	362	3	,	,	PUNCT
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eurjchem-1564	365	3	]	]	PUNCT
eurjchem-1564	365	4	.	.	PUNCT
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eurjchem-1564	367	4	.	.	PUNCT
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eurjchem-1564	368	2	,	,	PUNCT
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eurjchem-1564	368	5	;	;	PUNCT
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eurjchem-1564	374	4	.	.	PUNCT
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eurjchem-1564	377	7	.	.	PUNCT
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