id	sid	tid	token	lemma	pos
eurjchem-1566	1	1	untitled	untitle	VERB
eurjchem-1566	1	2	european	european	PROPN
eurjchem-1566	1	3	journal	journal	PROPN
eurjchem-1566	1	4	of	of	ADP
eurjchem-1566	1	5	chemistry	chemistry	NOUN
eurjchem-1566	1	6	8	8	NUM
eurjchem-1566	1	7	(	(	PUNCT
eurjchem-1566	1	8	2	2	NUM
eurjchem-1566	1	9	)	)	PUNCT
eurjchem-1566	1	10	(	(	PUNCT
eurjchem-1566	1	11	2017	2017	NUM
eurjchem-1566	1	12	)	)	PUNCT
eurjchem-1566	1	13	162‐167	162‐167	NUM
eurjchem-1566	1	14	european	european	PROPN
eurjchem-1566	1	15	journal	journal	PROPN
eurjchem-1566	1	16	of	of	ADP
eurjchem-1566	1	17	chemistry	chemistry	NOUN
eurjchem-1566	1	18	issn	issn	PROPN
eurjchem-1566	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-1566	1	20	(	(	PUNCT
eurjchem-1566	1	21	print	print	NOUN
eurjchem-1566	1	22	)	)	PUNCT
eurjchem-1566	1	23	/	/	SYM
eurjchem-1566	1	24	issn	issn	PROPN
eurjchem-1566	1	25	2153‐2257	2153‐2257	NUM
eurjchem-1566	1	26	(	(	PUNCT
eurjchem-1566	1	27	online	online	ADJ
eurjchem-1566	1	28	)	)	PUNCT
eurjchem-1566	1	29			NOUN
eurjchem-1566	1	30	2017	2017	NUM
eurjchem-1566	1	31	atlanta	atlanta	PROPN
eurjchem-1566	1	32	publishing	publishing	PROPN
eurjchem-1566	1	33	house	house	PROPN
eurjchem-1566	1	34	llc	llc	PROPN
eurjchem-1566	1	35	‐	‐	PUNCT
eurjchem-1566	1	36	all	all	DET
eurjchem-1566	1	37	rights	right	NOUN
eurjchem-1566	1	38	reserved	reserve	VERB
eurjchem-1566	1	39	‐	‐	NOUN
eurjchem-1566	1	40	printed	print	VERB
eurjchem-1566	1	41	in	in	ADP
eurjchem-1566	1	42	the	the	DET
eurjchem-1566	1	43	usa	usa	PROPN
eurjchem-1566	1	44	http://dx.doi.org/10.5155/eurjchem.8.2.162-167.1566	http://dx.doi.org/10.5155/eurjchem.8.2.162-167.1566	PROPN
eurjchem-1566	1	45	european	european	PROPN
eurjchem-1566	1	46	journal	journal	PROPN
eurjchem-1566	1	47	of	of	ADP
eurjchem-1566	1	48	chemistry	chemistry	PROPN
eurjchem-1566	1	49	journal	journal	PROPN
eurjchem-1566	1	50	webpage	webpage	NOUN
eurjchem-1566	1	51	:	:	PUNCT
eurjchem-1566	1	52	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1566	1	53	correlation	correlation	NOUN
eurjchem-1566	1	54	analysis	analysis	NOUN
eurjchem-1566	1	55	of	of	ADP
eurjchem-1566	1	56	the	the	DET
eurjchem-1566	1	57	rates	rate	NOUN
eurjchem-1566	1	58	of	of	ADP
eurjchem-1566	1	59	solvolysis	solvolysis	NOUN
eurjchem-1566	1	60	of	of	ADP
eurjchem-1566	1	61	4‐bromopiperidine	4‐bromopiperidine	NOUN
eurjchem-1566	1	62	:	:	PUNCT
eurjchem-1566	1	63	a	a	DET
eurjchem-1566	1	64	reaction	reaction	NOUN
eurjchem-1566	1	65	following	follow	VERB
eurjchem-1566	1	66	a	a	DET
eurjchem-1566	1	67	grob	grob	PROPN
eurjchem-1566	1	68	fragmentation	fragmentation	NOUN
eurjchem-1566	1	69	pathway	pathway	NOUN
eurjchem-1566	1	70	dennis	dennis	PROPN
eurjchem-1566	1	71	neil	neil	PROPN
eurjchem-1566	1	72	kevill	kevill	PROPN
eurjchem-1566	1	73	1	1	NUM
eurjchem-1566	1	74	,	,	PUNCT
eurjchem-1566	1	75	zoon	zoon	PROPN
eurjchem-1566	1	76	ha	ha	X
eurjchem-1566	1	77	ryu	ryu	PROPN
eurjchem-1566	1	78	2	2	NUM
eurjchem-1566	1	79	and	and	CCONJ
eurjchem-1566	1	80	malcolm	malcolm	PROPN
eurjchem-1566	1	81	john	john	PROPN
eurjchem-1566	1	82	d’souza	d’souza	PROPN
eurjchem-1566	1	83	3	3	NUM
eurjchem-1566	1	84	,	,	PUNCT
eurjchem-1566	1	85	*	*	PROPN
eurjchem-1566	1	86	1	1	NUM
eurjchem-1566	1	87	department	department	NOUN
eurjchem-1566	1	88	of	of	ADP
eurjchem-1566	1	89	chemistry	chemistry	NOUN
eurjchem-1566	1	90	and	and	CCONJ
eurjchem-1566	1	91	biochemistry	biochemistry	NOUN
eurjchem-1566	1	92	,	,	PUNCT
eurjchem-1566	1	93	northern	northern	ADJ
eurjchem-1566	1	94	illinois	illinois	PROPN
eurjchem-1566	1	95	university	university	PROPN
eurjchem-1566	1	96	,	,	PUNCT
eurjchem-1566	1	97	dekalb	dekalb	PROPN
eurjchem-1566	1	98	,	,	PUNCT
eurjchem-1566	1	99	illinois	illinois	PROPN
eurjchem-1566	1	100	60115‐2862	60115‐2862	NUM
eurjchem-1566	1	101	,	,	PUNCT
eurjchem-1566	1	102	usa	usa	PROPN
eurjchem-1566	1	103	2	2	NUM
eurjchem-1566	1	104	department	department	NOUN
eurjchem-1566	1	105	of	of	ADP
eurjchem-1566	1	106	chemistry	chemistry	NOUN
eurjchem-1566	1	107	,	,	PUNCT
eurjchem-1566	1	108	dong‐eui	dong‐eui	PROPN
eurjchem-1566	1	109	university	university	NOUN
eurjchem-1566	1	110	,	,	PUNCT
eurjchem-1566	1	111	995	995	NUM
eurjchem-1566	1	112	eomgwango	eomgwango	NOUN
eurjchem-1566	1	113	,	,	PUNCT
eurjchem-1566	1	114	busan‐jin‐gu	busan‐jin‐gu	PROPN
eurjchem-1566	1	115	,	,	PUNCT
eurjchem-1566	1	116	busan	busan	PROPN
eurjchem-1566	1	117	614‐714	614‐714	PROPN
eurjchem-1566	1	118	,	,	PUNCT
eurjchem-1566	1	119	republic	republic	NOUN
eurjchem-1566	1	120	of	of	ADP
eurjchem-1566	1	121	korea	korea	PROPN
eurjchem-1566	1	122	3	3	PROPN
eurjchem-1566	1	123	department	department	PROPN
eurjchem-1566	1	124	of	of	ADP
eurjchem-1566	1	125	chemistry	chemistry	NOUN
eurjchem-1566	1	126	,	,	PUNCT
eurjchem-1566	1	127	wesley	wesley	PROPN
eurjchem-1566	1	128	college	college	PROPN
eurjchem-1566	1	129	,	,	PUNCT
eurjchem-1566	1	130	120	120	NUM
eurjchem-1566	1	131	north	north	NOUN
eurjchem-1566	1	132	state	state	PROPN
eurjchem-1566	1	133	street	street	PROPN
eurjchem-1566	1	134	,	,	PUNCT
eurjchem-1566	1	135	dover	dover	PROPN
eurjchem-1566	1	136	,	,	PUNCT
eurjchem-1566	1	137	delaware	delaware	PROPN
eurjchem-1566	1	138	19901‐3875	19901‐3875	NUM
eurjchem-1566	1	139	,	,	PUNCT
eurjchem-1566	1	140	usa	usa	PROPN
eurjchem-1566	1	141	*	*	PUNCT
eurjchem-1566	1	142	corresponding	correspond	VERB
eurjchem-1566	1	143	author	author	NOUN
eurjchem-1566	1	144	at	at	ADP
eurjchem-1566	1	145	:	:	PUNCT
eurjchem-1566	1	146	department	department	NOUN
eurjchem-1566	1	147	of	of	ADP
eurjchem-1566	1	148	chemistry	chemistry	NOUN
eurjchem-1566	1	149	,	,	PUNCT
eurjchem-1566	1	150	wesley	wesley	PROPN
eurjchem-1566	1	151	college	college	PROPN
eurjchem-1566	1	152	,	,	PUNCT
eurjchem-1566	1	153	120	120	NUM
eurjchem-1566	1	154	north	north	NOUN
eurjchem-1566	1	155	state	state	PROPN
eurjchem-1566	1	156	street	street	PROPN
eurjchem-1566	1	157	,	,	PUNCT
eurjchem-1566	1	158	dover	dover	PROPN
eurjchem-1566	1	159	,	,	PUNCT
eurjchem-1566	1	160	delaware	delaware	PROPN
eurjchem-1566	1	161	19901‐3875	19901‐3875	NUM
eurjchem-1566	1	162	,	,	PUNCT
eurjchem-1566	1	163	usa	usa	PROPN
eurjchem-1566	1	164	.	.	PROPN
eurjchem-1566	1	165	tel	tel	PROPN
eurjchem-1566	1	166	.	.	PUNCT
eurjchem-1566	1	167	:	:	PUNCT
eurjchem-1566	2	1	+1.302.7362528	+1.302.7362528	PROPN
eurjchem-1566	2	2	.	.	PUNCT
eurjchem-1566	3	1	fax	fax	NOUN
eurjchem-1566	3	2	:	:	PUNCT
eurjchem-1566	3	3	+1.302.7362301	+1.302.7362301	PROPN
eurjchem-1566	3	4	.	.	PUNCT
eurjchem-1566	3	5	e‐mail	e‐mail	PUNCT
eurjchem-1566	4	1	address	address	NOUN
eurjchem-1566	4	2	:	:	PUNCT
eurjchem-1566	4	3	malcolm.dsouza@wesley.edu	malcolm.dsouza@wesley.edu	PROPN
eurjchem-1566	4	4	(	(	PUNCT
eurjchem-1566	4	5	m.j	m.j	PROPN
eurjchem-1566	4	6	.	.	PROPN
eurjchem-1566	4	7	d’souza	d’souza	PROPN
eurjchem-1566	4	8	)	)	PUNCT
eurjchem-1566	4	9	.	.	PUNCT
eurjchem-1566	5	1	article	article	NOUN
eurjchem-1566	5	2	information	information	PROPN
eurjchem-1566	5	3	abstract	abstract	ADJ
eurjchem-1566	5	4	doi	doi	PROPN
eurjchem-1566	5	5	:	:	PUNCT
eurjchem-1566	5	6	 	 	SPACE
eurjchem-1566	5	7	10.5155	10.5155	NUM
eurjchem-1566	5	8	/	/	SYM
eurjchem-1566	5	9	eurjchem.8.2.162	eurjchem.8.2.162	PROPN
eurjchem-1566	5	10	-	-	SYM
eurjchem-1566	5	11	167.1566	167.1566	NUM
eurjchem-1566	5	12	received	receive	VERB
eurjchem-1566	5	13	:	:	PUNCT
eurjchem-1566	5	14	13	13	NUM
eurjchem-1566	5	15	march	march	NOUN
eurjchem-1566	5	16	2017	2017	NUM
eurjchem-1566	5	17	received	receive	VERB
eurjchem-1566	5	18	in	in	ADP
eurjchem-1566	5	19	revised	revise	VERB
eurjchem-1566	5	20	form	form	NOUN
eurjchem-1566	5	21	:	:	PUNCT
eurjchem-1566	5	22	11	11	NUM
eurjchem-1566	5	23	april	april	PROPN
eurjchem-1566	5	24	2017	2017	NUM
eurjchem-1566	5	25	accepted	accept	VERB
eurjchem-1566	5	26	:	:	PUNCT
eurjchem-1566	5	27	19	19	NUM
eurjchem-1566	5	28	april	april	PROPN
eurjchem-1566	5	29	2017	2017	NUM
eurjchem-1566	5	30	published	publish	VERB
eurjchem-1566	5	31	online	online	ADV
eurjchem-1566	5	32	:	:	PUNCT
eurjchem-1566	5	33	30	30	NUM
eurjchem-1566	5	34	june	june	PROPN
eurjchem-1566	5	35	2017	2017	NUM
eurjchem-1566	5	36	printed	print	VERB
eurjchem-1566	5	37	:	:	PUNCT
eurjchem-1566	5	38	30	30	NUM
eurjchem-1566	5	39	june	june	PROPN
eurjchem-1566	5	40	2017	2017	NUM
eurjchem-1566	5	41	  	  	SPACE
eurjchem-1566	5	42	a	a	DET
eurjchem-1566	5	43	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	5	44	treatment	treatment	NOUN
eurjchem-1566	5	45	of	of	ADP
eurjchem-1566	5	46	the	the	DET
eurjchem-1566	5	47	specific	specific	ADJ
eurjchem-1566	5	48	rates	rate	NOUN
eurjchem-1566	5	49	of	of	ADP
eurjchem-1566	5	50	solvolysis	solvolysis	NOUN
eurjchem-1566	5	51	of	of	ADP
eurjchem-1566	5	52	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	5	53	gives	give	VERB
eurjchem-1566	5	54	for	for	ADP
eurjchem-1566	5	55	aqueous	aqueous	ADJ
eurjchem-1566	5	56	ethanol	ethanol	NOUN
eurjchem-1566	5	57	,	,	PUNCT
eurjchem-1566	5	58	methanol	methanol	NOUN
eurjchem-1566	5	59	,	,	PUNCT
eurjchem-1566	5	60	acetone	acetone	NOUN
eurjchem-1566	5	61	,	,	PUNCT
eurjchem-1566	5	62	and	and	CCONJ
eurjchem-1566	5	63	dioxane	dioxane	VERB
eurjchem-1566	5	64	a	a	DET
eurjchem-1566	5	65	very	very	ADV
eurjchem-1566	5	66	good	good	ADJ
eurjchem-1566	5	67	logarithmic	logarithmic	ADJ
eurjchem-1566	5	68	correlation	correlation	NOUN
eurjchem-1566	5	69	against	against	ADP
eurjchem-1566	5	70	the	the	DET
eurjchem-1566	5	71	ybr	ybr	PROPN
eurjchem-1566	5	72	solvent	solvent	NOUN
eurjchem-1566	5	73	ionizing	ionize	VERB
eurjchem-1566	5	74	power	power	NOUN
eurjchem-1566	5	75	values	value	NOUN
eurjchem-1566	5	76	with	with	ADP
eurjchem-1566	5	77	a	a	DET
eurjchem-1566	5	78	slope	slope	NOUN
eurjchem-1566	5	79	(	(	PUNCT
eurjchem-1566	5	80	m	m	NOUN
eurjchem-1566	5	81	value	value	NOUN
eurjchem-1566	5	82	)	)	PUNCT
eurjchem-1566	5	83	of	of	ADP
eurjchem-1566	5	84	0.46±0.02	0.46±0.02	PROPN
eurjchem-1566	5	85	,	,	PUNCT
eurjchem-1566	5	86	consistent	consistent	ADJ
eurjchem-1566	5	87	with	with	ADP
eurjchem-1566	5	88	the	the	DET
eurjchem-1566	5	89	operation	operation	NOUN
eurjchem-1566	5	90	of	of	ADP
eurjchem-1566	5	91	a	a	DET
eurjchem-1566	5	92	synchronous	synchronous	ADJ
eurjchem-1566	5	93	grob	grob	PROPN
eurjchem-1566	5	94	fragmentation	fragmentation	NOUN
eurjchem-1566	5	95	mechanism	mechanism	NOUN
eurjchem-1566	5	96	.	.	PUNCT
eurjchem-1566	6	1	when	when	SCONJ
eurjchem-1566	6	2	the	the	DET
eurjchem-1566	6	3	organic	organic	ADJ
eurjchem-1566	6	4	component	component	NOUN
eurjchem-1566	6	5	of	of	ADP
eurjchem-1566	6	6	the	the	DET
eurjchem-1566	6	7	solvent	solvent	NOUN
eurjchem-1566	6	8	is	be	AUX
eurjchem-1566	6	9	2,2,2‐trifluoroethanol	2,2,2‐trifluoroethanol	NUM
eurjchem-1566	6	10	(	(	PUNCT
eurjchem-1566	6	11	tfe	tfe	NOUN
eurjchem-1566	6	12	)	)	PUNCT
eurjchem-1566	6	13	,	,	PUNCT
eurjchem-1566	6	14	the	the	DET
eurjchem-1566	6	15	data	data	NOUN
eurjchem-1566	6	16	points	point	NOUN
eurjchem-1566	6	17	show	show	VERB
eurjchem-1566	6	18	a	a	DET
eurjchem-1566	6	19	negative	negative	ADJ
eurjchem-1566	6	20	deviation	deviation	NOUN
eurjchem-1566	6	21	,	,	PUNCT
eurjchem-1566	6	22	consistent	consistent	ADJ
eurjchem-1566	6	23	with	with	ADP
eurjchem-1566	6	24	an	an	DET
eurjchem-1566	6	25	appreciable	appreciable	ADJ
eurjchem-1566	6	26	deactivating	deactivate	VERB
eurjchem-1566	6	27	interaction	interaction	NOUN
eurjchem-1566	6	28	of	of	ADP
eurjchem-1566	6	29	the	the	DET
eurjchem-1566	6	30	acidic	acidic	ADJ
eurjchem-1566	6	31	tfe	tfe	NOUN
eurjchem-1566	6	32	component	component	NOUN
eurjchem-1566	6	33	of	of	ADP
eurjchem-1566	6	34	the	the	DET
eurjchem-1566	6	35	solvent	solvent	NOUN
eurjchem-1566	6	36	with	with	ADP
eurjchem-1566	6	37	the	the	DET
eurjchem-1566	6	38	lone‐pair	lone‐pair	NOUN
eurjchem-1566	6	39	of	of	ADP
eurjchem-1566	6	40	electrons	electron	NOUN
eurjchem-1566	6	41	present	present	ADJ
eurjchem-1566	6	42	on	on	ADP
eurjchem-1566	6	43	the	the	DET
eurjchem-1566	6	44	nitrogen	nitrogen	NOUN
eurjchem-1566	6	45	.	.	PUNCT
eurjchem-1566	7	1	keywords	keyword	VERB
eurjchem-1566	7	2	solvolysis	solvolysis	NOUN
eurjchem-1566	7	3	mechanism	mechanism	NOUN
eurjchem-1566	7	4	correlation	correlation	NOUN
eurjchem-1566	7	5	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	7	6	grob	grob	PROPN
eurjchem-1566	7	7	fragmentation	fragmentation	NOUN
eurjchem-1566	7	8	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	7	9	equation	equation	NOUN
eurjchem-1566	7	10	cite	cite	VERB
eurjchem-1566	7	11	this	this	PRON
eurjchem-1566	7	12	:	:	PUNCT
eurjchem-1566	8	1	eur	eur	PROPN
eurjchem-1566	8	2	.	.	PUNCT
eurjchem-1566	9	1	j.	j.	PROPN
eurjchem-1566	9	2	chem	chem	PROPN
eurjchem-1566	9	3	.	.	PUNCT
eurjchem-1566	10	1	2017	2017	NUM
eurjchem-1566	10	2	,	,	PUNCT
eurjchem-1566	10	3	8(2	8(2	NUM
eurjchem-1566	10	4	)	)	PUNCT
eurjchem-1566	10	5	,	,	PUNCT
eurjchem-1566	10	6	162‐167	162‐167	NOUN
eurjchem-1566	10	7	1	1	NUM
eurjchem-1566	10	8	.	.	PUNCT
eurjchem-1566	10	9	introduction	introduction	NOUN
eurjchem-1566	10	10	a	a	DET
eurjchem-1566	10	11	study	study	NOUN
eurjchem-1566	10	12	by	by	ADP
eurjchem-1566	10	13	d’arcy	d’arcy	PROPN
eurjchem-1566	10	14	,	,	PUNCT
eurjchem-1566	10	15	grob	grob	PROPN
eurjchem-1566	10	16	,	,	PUNCT
eurjchem-1566	10	17	kaffenberger	kaffenberger	NOUN
eurjchem-1566	10	18	and	and	CCONJ
eurjchem-1566	10	19	krasnobajew	krasnobajew	NOUN
eurjchem-1566	11	1	[	[	X
eurjchem-1566	11	2	1	1	X
eurjchem-1566	11	3	]	]	PUNCT
eurjchem-1566	11	4	found	find	VERB
eurjchem-1566	11	5	that	that	SCONJ
eurjchem-1566	11	6	,	,	PUNCT
eurjchem-1566	11	7	in	in	ADP
eurjchem-1566	11	8	80	80	NUM
eurjchem-1566	11	9	%	%	NOUN
eurjchem-1566	11	10	ethanol‐20	ethanol‐20	NUM
eurjchem-1566	11	11	%	%	NOUN
eurjchem-1566	11	12	water	water	NOUN
eurjchem-1566	11	13	(	(	PUNCT
eurjchem-1566	11	14	volume	volume	NOUN
eurjchem-1566	11	15	/	/	SYM
eurjchem-1566	11	16	volume	volume	NOUN
eurjchem-1566	11	17	)	)	PUNCT
eurjchem-1566	11	18	,	,	PUNCT
eurjchem-1566	11	19	4‐chloropiperidine	4‐chloropiperidine	NOUN
eurjchem-1566	11	20	(	(	PUNCT
eurjchem-1566	11	21	1	1	X
eurjchem-1566	11	22	)	)	PUNCT
eurjchem-1566	11	23	undergoes	undergo	VERB
eurjchem-1566	11	24	solvolysis	solvolysis	NOUN
eurjchem-1566	11	25	by	by	ADP
eurjchem-1566	11	26	a	a	DET
eurjchem-1566	11	27	pathway	pathway	NOUN
eurjchem-1566	11	28	involving	involve	VERB
eurjchem-1566	11	29	fragmentation	fragmentation	NOUN
eurjchem-1566	11	30	,	,	PUNCT
eurjchem-1566	11	31	which	which	PRON
eurjchem-1566	11	32	was	be	AUX
eurjchem-1566	11	33	best	well	ADV
eurjchem-1566	11	34	described	describe	VERB
eurjchem-1566	11	35	as	as	ADP
eurjchem-1566	11	36	being	be	AUX
eurjchem-1566	11	37	synchronous	synchronous	ADJ
eurjchem-1566	11	38	in	in	ADP
eurjchem-1566	11	39	nature	nature	NOUN
eurjchem-1566	11	40	.	.	PUNCT
eurjchem-1566	12	1	this	this	PRON
eurjchem-1566	12	2	is	be	AUX
eurjchem-1566	12	3	a	a	DET
eurjchem-1566	12	4	reaction	reaction	NOUN
eurjchem-1566	12	5	where	where	SCONJ
eurjchem-1566	12	6	a	a	DET
eurjchem-1566	12	7	study	study	NOUN
eurjchem-1566	12	8	of	of	ADP
eurjchem-1566	12	9	the	the	DET
eurjchem-1566	12	10	variation	variation	NOUN
eurjchem-1566	12	11	of	of	ADP
eurjchem-1566	12	12	the	the	DET
eurjchem-1566	12	13	rate	rate	NOUN
eurjchem-1566	12	14	,	,	PUNCT
eurjchem-1566	12	15	with	with	ADP
eurjchem-1566	12	16	changes	change	NOUN
eurjchem-1566	12	17	in	in	ADP
eurjchem-1566	12	18	the	the	DET
eurjchem-1566	12	19	solvent	solvent	NOUN
eurjchem-1566	12	20	composition	composition	NOUN
eurjchem-1566	12	21	for	for	ADP
eurjchem-1566	12	22	the	the	DET
eurjchem-1566	12	23	solvolysis	solvolysis	NOUN
eurjchem-1566	12	24	,	,	PUNCT
eurjchem-1566	12	25	can	can	AUX
eurjchem-1566	12	26	give	give	VERB
eurjchem-1566	12	27	valuable	valuable	ADJ
eurjchem-1566	12	28	information	information	NOUN
eurjchem-1566	12	29	.	.	PUNCT
eurjchem-1566	13	1	in	in	ADP
eurjchem-1566	13	2	particular	particular	ADJ
eurjchem-1566	13	3	,	,	PUNCT
eurjchem-1566	13	4	analysis	analysis	NOUN
eurjchem-1566	13	5	in	in	ADP
eurjchem-1566	13	6	terms	term	NOUN
eurjchem-1566	13	7	of	of	ADP
eurjchem-1566	13	8	a	a	DET
eurjchem-1566	13	9	two‐term	two‐term	NOUN
eurjchem-1566	13	10	[	[	X
eurjchem-1566	13	11	equation	equation	NOUN
eurjchem-1566	13	12	1	1	NUM
eurjchem-1566	13	13	]	]	PUNCT
eurjchem-1566	13	14	or	or	CCONJ
eurjchem-1566	13	15	one‐term	one‐term	NOUN
eurjchem-1566	13	16	(	(	PUNCT
eurjchem-1566	13	17	lnt	lnt	NOUN
eurjchem-1566	13	18	or	or	CCONJ
eurjchem-1566	13	19	myx	myx	PROPN
eurjchem-1566	13	20	omitted	omit	VERB
eurjchem-1566	13	21	)	)	PUNCT
eurjchem-1566	13	22	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	13	23	equation	equation	NOUN
eurjchem-1566	13	24	[	[	X
eurjchem-1566	13	25	2,3	2,3	NUM
eurjchem-1566	13	26	]	]	PUNCT
eurjchem-1566	13	27	can	can	AUX
eurjchem-1566	13	28	indicate	indicate	VERB
eurjchem-1566	13	29	the	the	DET
eurjchem-1566	13	30	relative	relative	ADJ
eurjchem-1566	13	31	importance	importance	NOUN
eurjchem-1566	13	32	of	of	ADP
eurjchem-1566	13	33	solvent	solvent	ADJ
eurjchem-1566	13	34	ionizing	ionizing	NOUN
eurjchem-1566	13	35	power	power	NOUN
eurjchem-1566	13	36	[	[	X
eurjchem-1566	13	37	4	4	NUM
eurjchem-1566	13	38	]	]	PUNCT
eurjchem-1566	13	39	and	and	CCONJ
eurjchem-1566	13	40	solvent	solvent	ADJ
eurjchem-1566	13	41	nucleophilicity	nucleophilicity	NOUN
eurjchem-1566	13	42	[	[	X
eurjchem-1566	13	43	5	5	NUM
eurjchem-1566	13	44	]	]	PUNCT
eurjchem-1566	13	45	within	within	ADP
eurjchem-1566	13	46	the	the	DET
eurjchem-1566	13	47	mechanistic	mechanistic	ADJ
eurjchem-1566	13	48	pathway	pathway	NOUN
eurjchem-1566	13	49	.	.	PUNCT
eurjchem-1566	14	1	log	log	NOUN
eurjchem-1566	14	2	(	(	PUNCT
eurjchem-1566	14	3	k	k	NOUN
eurjchem-1566	14	4	/	/	SYM
eurjchem-1566	14	5	ko)rx	ko)rx	NOUN
eurjchem-1566	14	6	=	=	SYM
eurjchem-1566	14	7	lnt	lnt	NOUN
eurjchem-1566	14	8	+	+	CCONJ
eurjchem-1566	14	9	myx	myx	NOUN
eurjchem-1566	15	1	+	+	X
eurjchem-1566	15	2	c	c	X
eurjchem-1566	15	3	(	(	PUNCT
eurjchem-1566	15	4	1	1	NUM
eurjchem-1566	15	5	)	)	PUNCT
eurjchem-1566	15	6	in	in	ADP
eurjchem-1566	15	7	equation	equation	NOUN
eurjchem-1566	15	8	(	(	PUNCT
eurjchem-1566	15	9	1	1	NUM
eurjchem-1566	15	10	)	)	PUNCT
eurjchem-1566	15	11	,	,	PUNCT
eurjchem-1566	15	12	k	k	PROPN
eurjchem-1566	15	13	and	and	CCONJ
eurjchem-1566	15	14	ko	ko	PROPN
eurjchem-1566	15	15	are	be	AUX
eurjchem-1566	15	16	the	the	DET
eurjchem-1566	15	17	specific	specific	ADJ
eurjchem-1566	15	18	rates	rate	NOUN
eurjchem-1566	15	19	(	(	PUNCT
eurjchem-1566	15	20	first‐order	first‐order	NOUN
eurjchem-1566	15	21	rate	rate	NOUN
eurjchem-1566	15	22	coefficients	coefficient	NOUN
eurjchem-1566	15	23	)	)	PUNCT
eurjchem-1566	15	24	for	for	ADP
eurjchem-1566	15	25	solvolysis	solvolysis	NOUN
eurjchem-1566	15	26	rx	rx	VERB
eurjchem-1566	15	27	in	in	ADP
eurjchem-1566	15	28	a	a	DET
eurjchem-1566	15	29	given	give	VERB
eurjchem-1566	15	30	solvent	solvent	NOUN
eurjchem-1566	15	31	and	and	CCONJ
eurjchem-1566	15	32	in	in	ADP
eurjchem-1566	15	33	80	80	NUM
eurjchem-1566	15	34	%	%	NOUN
eurjchem-1566	15	35	ethanol	ethanol	NOUN
eurjchem-1566	15	36	(	(	PUNCT
eurjchem-1566	15	37	the	the	DET
eurjchem-1566	15	38	arbitrarily	arbitrarily	ADV
eurjchem-1566	15	39	chosen	choose	VERB
eurjchem-1566	15	40	standard	standard	ADJ
eurjchem-1566	15	41	solvent	solvent	NOUN
eurjchem-1566	15	42	)	)	PUNCT
eurjchem-1566	15	43	,	,	PUNCT
eurjchem-1566	15	44	respectively	respectively	ADV
eurjchem-1566	15	45	,	,	PUNCT
eurjchem-1566	15	46	l	l	PROPN
eurjchem-1566	15	47	is	be	AUX
eurjchem-1566	15	48	the	the	DET
eurjchem-1566	15	49	sensitivity	sensitivity	NOUN
eurjchem-1566	15	50	to	to	PART
eurjchem-1566	15	51	changes	change	NOUN
eurjchem-1566	15	52	in	in	ADP
eurjchem-1566	15	53	solvent	solvent	NOUN
eurjchem-1566	15	54	nucleo‐	nucleo‐	ADP
eurjchem-1566	15	55	philicity	philicity	NOUN
eurjchem-1566	15	56	(	(	PUNCT
eurjchem-1566	15	57	nt	not	PART
eurjchem-1566	15	58	)	)	PUNCT
eurjchem-1566	15	59	,	,	PUNCT
eurjchem-1566	15	60	m	m	PROPN
eurjchem-1566	15	61	is	be	AUX
eurjchem-1566	15	62	the	the	DET
eurjchem-1566	15	63	sensitivity	sensitivity	NOUN
eurjchem-1566	15	64	to	to	PART
eurjchem-1566	15	65	changes	change	NOUN
eurjchem-1566	15	66	in	in	ADP
eurjchem-1566	15	67	solvent	solvent	ADJ
eurjchem-1566	15	68	ionizing	ionizing	NOUN
eurjchem-1566	15	69	power	power	NOUN
eurjchem-1566	15	70	(	(	PUNCT
eurjchem-1566	15	71	yx	yx	NOUN
eurjchem-1566	15	72	for	for	ADP
eurjchem-1566	15	73	a	a	DET
eurjchem-1566	15	74	leaving	leave	VERB
eurjchem-1566	15	75	group	group	NOUN
eurjchem-1566	15	76	x	x	NOUN
eurjchem-1566	15	77	)	)	PUNCT
eurjchem-1566	15	78	and	and	CCONJ
eurjchem-1566	15	79	c	c	PROPN
eurjchem-1566	15	80	is	be	AUX
eurjchem-1566	15	81	a	a	DET
eurjchem-1566	15	82	constant	constant	ADJ
eurjchem-1566	15	83	(	(	PUNCT
eurjchem-1566	15	84	residual	residual	ADJ
eurjchem-1566	15	85	)	)	PUNCT
eurjchem-1566	15	86	value	value	NOUN
eurjchem-1566	15	87	.	.	PUNCT
eurjchem-1566	16	1	the	the	DET
eurjchem-1566	16	2	l	l	NOUN
eurjchem-1566	16	3	and	and	CCONJ
eurjchem-1566	16	4	m	m	PROPN
eurjchem-1566	16	5	values	value	NOUN
eurjchem-1566	16	6	reflect	reflect	VERB
eurjchem-1566	16	7	the	the	DET
eurjchem-1566	16	8	relative	relative	ADJ
eurjchem-1566	16	9	importance	importance	NOUN
eurjchem-1566	16	10	of	of	ADP
eurjchem-1566	16	11	nucleophilicity	nucleophilicity	NOUN
eurjchem-1566	16	12	and	and	CCONJ
eurjchem-1566	16	13	ionizing	ionize	VERB
eurjchem-1566	16	14	power	power	NOUN
eurjchem-1566	16	15	for	for	ADP
eurjchem-1566	16	16	a	a	DET
eurjchem-1566	16	17	given	give	VERB
eurjchem-1566	16	18	solvolysis	solvolysis	NOUN
eurjchem-1566	16	19	.	.	PUNCT
eurjchem-1566	17	1	grob	grob	PROPN
eurjchem-1566	17	2	and	and	CCONJ
eurjchem-1566	17	3	coworkers	coworker	NOUN
eurjchem-1566	17	4	have	have	AUX
eurjchem-1566	17	5	carried	carry	VERB
eurjchem-1566	17	6	out	out	ADP
eurjchem-1566	17	7	extensive	extensive	ADJ
eurjchem-1566	17	8	studies	study	NOUN
eurjchem-1566	17	9	of	of	ADP
eurjchem-1566	17	10	a	a	DET
eurjchem-1566	17	11	variety	variety	NOUN
eurjchem-1566	17	12	of	of	ADP
eurjchem-1566	17	13	fragmentation	fragmentation	NOUN
eurjchem-1566	17	14	reactions	reaction	NOUN
eurjchem-1566	17	15	with	with	ADP
eurjchem-1566	17	16	the	the	DET
eurjchem-1566	17	17	results	result	NOUN
eurjchem-1566	17	18	largely	largely	ADV
eurjchem-1566	17	19	published	publish	VERB
eurjchem-1566	17	20	in	in	ADP
eurjchem-1566	17	21	german	german	NOUN
eurjchem-1566	17	22	in	in	ADP
eurjchem-1566	17	23	helvetica	helvetica	PROPN
eurjchem-1566	17	24	chimica	chimica	PROPN
eurjchem-1566	17	25	acta	acta	PROPN
eurjchem-1566	17	26	.	.	PUNCT
eurjchem-1566	18	1	fortunately	fortunately	ADV
eurjchem-1566	18	2	,	,	PUNCT
eurjchem-1566	18	3	for	for	SCONJ
eurjchem-1566	18	4	readers	reader	NOUN
eurjchem-1566	18	5	not	not	PART
eurjchem-1566	18	6	well	well	ADV
eurjchem-1566	18	7	versed	verse	VERB
eurjchem-1566	18	8	in	in	ADP
eurjchem-1566	18	9	the	the	DET
eurjchem-1566	18	10	german	german	ADJ
eurjchem-1566	18	11	language	language	NOUN
eurjchem-1566	18	12	,	,	PUNCT
eurjchem-1566	18	13	there	there	PRON
eurjchem-1566	18	14	are	be	VERB
eurjchem-1566	18	15	two	two	NUM
eurjchem-1566	18	16	excellent	excellent	ADJ
eurjchem-1566	18	17	reviews	review	NOUN
eurjchem-1566	18	18	,	,	PUNCT
eurjchem-1566	18	19	which	which	PRON
eurjchem-1566	18	20	were	be	AUX
eurjchem-1566	18	21	published	publish	VERB
eurjchem-1566	18	22	in	in	ADP
eurjchem-1566	18	23	both	both	CCONJ
eurjchem-1566	18	24	german	german	ADJ
eurjchem-1566	18	25	and	and	CCONJ
eurjchem-1566	18	26	english	english	ADJ
eurjchem-1566	19	1	[	[	X
eurjchem-1566	19	2	6,7	6,7	NUM
eurjchem-1566	19	3	]	]	PUNCT
eurjchem-1566	19	4	.	.	PUNCT
eurjchem-1566	20	1	the	the	DET
eurjchem-1566	20	2	first	first	ADJ
eurjchem-1566	20	3	deals	deal	NOUN
eurjchem-1566	20	4	with	with	ADP
eurjchem-1566	20	5	the	the	DET
eurjchem-1566	20	6	general	general	ADJ
eurjchem-1566	20	7	principles	principle	NOUN
eurjchem-1566	20	8	of	of	ADP
eurjchem-1566	20	9	heterolytic	heterolytic	ADJ
eurjchem-1566	20	10	fragmentations	fragmentation	NOUN
eurjchem-1566	20	11	and	and	CCONJ
eurjchem-1566	20	12	the	the	DET
eurjchem-1566	20	13	second	second	ADJ
eurjchem-1566	20	14	reviews	review	NOUN
eurjchem-1566	20	15	the	the	DET
eurjchem-1566	20	16	mechanistic	mechanistic	ADJ
eurjchem-1566	20	17	and	and	CCONJ
eurjchem-1566	20	18	stereochemical	stereochemical	ADJ
eurjchem-1566	20	19	considerations	consideration	NOUN
eurjchem-1566	20	20	of	of	ADP
eurjchem-1566	20	21	the	the	DET
eurjchem-1566	20	22	fragmentations	fragmentation	NOUN
eurjchem-1566	20	23	.	.	PUNCT
eurjchem-1566	21	1	the	the	DET
eurjchem-1566	21	2	solvolyses	solvolyse	NOUN
eurjchem-1566	21	3	of	of	ADP
eurjchem-1566	21	4	4‐chloropiperidine	4‐chloropiperidine	NOUN
eurjchem-1566	21	5	(	(	PUNCT
eurjchem-1566	21	6	1	1	NUM
eurjchem-1566	21	7	)	)	PUNCT
eurjchem-1566	21	8	,	,	PUNCT
eurjchem-1566	21	9	although	although	SCONJ
eurjchem-1566	21	10	113	113	NUM
eurjchem-1566	21	11	times	time	NOUN
eurjchem-1566	21	12	as	as	ADV
eurjchem-1566	21	13	rapid	rapid	ADJ
eurjchem-1566	21	14	in	in	ADP
eurjchem-1566	21	15	80	80	NUM
eurjchem-1566	21	16	%	%	NOUN
eurjchem-1566	21	17	ethanol	ethanol	NOUN
eurjchem-1566	21	18	at	at	ADP
eurjchem-1566	21	19	100	100	NUM
eurjchem-1566	21	20	°	°	NOUN
eurjchem-1566	21	21	c	c	NOUN
eurjchem-1566	21	22	as	as	ADP
eurjchem-1566	21	23	the	the	DET
eurjchem-1566	21	24	corresponding	corresponding	ADJ
eurjchem-1566	21	25	solvolysis	solvolysis	NOUN
eurjchem-1566	21	26	of	of	ADP
eurjchem-1566	21	27	cyclohexyl	cyclohexyl	PROPN
eurjchem-1566	21	28	chloride	chloride	PROPN
eurjchem-1566	22	1	[	[	X
eurjchem-1566	22	2	1	1	NUM
eurjchem-1566	22	3	]	]	PUNCT
eurjchem-1566	22	4	,	,	PUNCT
eurjchem-1566	22	5	were	be	AUX
eurjchem-1566	22	6	still	still	ADV
eurjchem-1566	22	7	quite	quite	ADV
eurjchem-1566	22	8	slow	slow	ADJ
eurjchem-1566	22	9	and	and	CCONJ
eurjchem-1566	22	10	,	,	PUNCT
eurjchem-1566	22	11	to	to	PART
eurjchem-1566	22	12	lower	lower	VERB
eurjchem-1566	22	13	the	the	DET
eurjchem-1566	22	14	temperature	temperature	NOUN
eurjchem-1566	22	15	required	require	VERB
eurjchem-1566	22	16	,	,	PUNCT
eurjchem-1566	22	17	we	we	PRON
eurjchem-1566	22	18	substituted	substitute	VERB
eurjchem-1566	22	19	the	the	DET
eurjchem-1566	22	20	corresponding	correspond	VERB
eurjchem-1566	22	21	bromo‐derivative	bromo‐derivative	NOUN
eurjchem-1566	22	22	,	,	PUNCT
eurjchem-1566	22	23	which	which	PRON
eurjchem-1566	22	24	would	would	AUX
eurjchem-1566	22	25	be	be	AUX
eurjchem-1566	22	26	expected	expect	VERB
eurjchem-1566	22	27	to	to	PART
eurjchem-1566	22	28	react	react	VERB
eurjchem-1566	22	29	some	some	DET
eurjchem-1566	22	30	one	one	NUM
eurjchem-1566	22	31	or	or	CCONJ
eurjchem-1566	22	32	two	two	NUM
eurjchem-1566	22	33	orders	order	NOUN
eurjchem-1566	22	34	of	of	ADP
eurjchem-1566	22	35	magnitude	magnitude	NOUN
eurjchem-1566	22	36	faster	fast	ADV
eurjchem-1566	22	37	at	at	ADP
eurjchem-1566	22	38	a	a	DET
eurjchem-1566	22	39	given	give	VERB
eurjchem-1566	22	40	temperature	temperature	NOUN
eurjchem-1566	22	41	[	[	X
eurjchem-1566	22	42	8	8	NUM
eurjchem-1566	22	43	]	]	PUNCT
eurjchem-1566	22	44	.	.	PUNCT
eurjchem-1566	23	1	in	in	ADP
eurjchem-1566	23	2	this	this	DET
eurjchem-1566	23	3	way	way	NOUN
eurjchem-1566	23	4	,	,	PUNCT
eurjchem-1566	23	5	the	the	DET
eurjchem-1566	23	6	solvolysis	solvolysis	NOUN
eurjchem-1566	23	7	rates	rate	NOUN
eurjchem-1566	23	8	in	in	ADP
eurjchem-1566	23	9	a	a	DET
eurjchem-1566	23	10	wide	wide	ADJ
eurjchem-1566	23	11	variety	variety	NOUN
eurjchem-1566	23	12	of	of	ADP
eurjchem-1566	23	13	hydroxylic	hydroxylic	ADJ
eurjchem-1566	23	14	solvents	solvent	NOUN
eurjchem-1566	23	15	could	could	AUX
eurjchem-1566	23	16	be	be	AUX
eurjchem-1566	23	17	conveniently	conveniently	ADV
eurjchem-1566	23	18	studied	study	VERB
eurjchem-1566	23	19	at	at	ADP
eurjchem-1566	23	20	55	55	NUM
eurjchem-1566	23	21	°	°	NOUN
eurjchem-1566	23	22	c	c	NOUN
eurjchem-1566	23	23	.	.	PUNCT
eurjchem-1566	24	1	the	the	DET
eurjchem-1566	24	2	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	24	3	(	(	PUNCT
eurjchem-1566	24	4	2	2	NUM
eurjchem-1566	24	5	)	)	PUNCT
eurjchem-1566	24	6	is	be	AUX
eurjchem-1566	24	7	commercially	commercially	ADV
eurjchem-1566	24	8	available	available	ADJ
eurjchem-1566	24	9	as	as	ADP
eurjchem-1566	24	10	its	its	PRON
eurjchem-1566	24	11	hydrobromide	hydrobromide	NOUN
eurjchem-1566	24	12	and	and	CCONJ
eurjchem-1566	24	13	,	,	PUNCT
eurjchem-1566	24	14	since	since	SCONJ
eurjchem-1566	24	15	we	we	PRON
eurjchem-1566	24	16	add	add	VERB
eurjchem-1566	24	17	triethylamine	triethylamine	NOUN
eurjchem-1566	24	18	and/or	and/or	CCONJ
eurjchem-1566	24	19	hydroxide	hydroxide	ADJ
eurjchem-1566	24	20	ion	ion	NOUN
eurjchem-1566	24	21	to	to	PART
eurjchem-1566	24	22	neutralize	neutralize	VERB
eurjchem-1566	24	23	the	the	DET
eurjchem-1566	24	24	acid	acid	NOUN
eurjchem-1566	24	25	produced	produce	VERB
eurjchem-1566	24	26	in	in	ADP
eurjchem-1566	24	27	the	the	DET
eurjchem-1566	24	28	solvolysis	solvolysis	NOUN
eurjchem-1566	24	29	[	[	X
eurjchem-1566	24	30	1	1	NUM
eurjchem-1566	24	31	]	]	PUNCT
eurjchem-1566	24	32	(	(	PUNCT
eurjchem-1566	24	33	so	so	SCONJ
eurjchem-1566	24	34	as	as	SCONJ
eurjchem-1566	24	35	to	to	PART
eurjchem-1566	24	36	prevent	prevent	VERB
eurjchem-1566	24	37	protonation	protonation	NOUN
eurjchem-1566	24	38	of	of	ADP
eurjchem-1566	24	39	the	the	DET
eurjchem-1566	24	40	nitrogen	nitrogen	NOUN
eurjchem-1566	24	41	of	of	ADP
eurjchem-1566	24	42	the	the	DET
eurjchem-1566	24	43	kevill	kevill	NOUN
eurjchem-1566	24	44	et	et	PROPN
eurjchem-1566	24	45	al	al	PROPN
eurjchem-1566	24	46	.	.	PUNCT
eurjchem-1566	24	47	/	/	SYM
eurjchem-1566	24	48	european	european	PROPN
eurjchem-1566	24	49	journal	journal	PROPN
eurjchem-1566	24	50	of	of	ADP
eurjchem-1566	24	51	chemistry	chemistry	NOUN
eurjchem-1566	24	52	8	8	NUM
eurjchem-1566	24	53	(	(	PUNCT
eurjchem-1566	24	54	2	2	NUM
eurjchem-1566	24	55	)	)	PUNCT
eurjchem-1566	24	56	(	(	PUNCT
eurjchem-1566	24	57	2017	2017	NUM
eurjchem-1566	24	58	)	)	PUNCT
eurjchem-1566	24	59	162‐167	162‐167	NUM
eurjchem-1566	24	60	163	163	NUM
eurjchem-1566	24	61	table	table	NOUN
eurjchem-1566	24	62	1	1	NUM
eurjchem-1566	24	63	.	.	PUNCT
eurjchem-1566	24	64	effect	effect	NOUN
eurjchem-1566	24	65	of	of	ADP
eurjchem-1566	24	66	varying	vary	VERB
eurjchem-1566	24	67	the	the	DET
eurjchem-1566	24	68	concentration	concentration	NOUN
eurjchem-1566	24	69	of	of	ADP
eurjchem-1566	24	70	triethylamine	triethylamine	NOUN
eurjchem-1566	24	71	,	,	PUNCT
eurjchem-1566	24	72	in	in	ADP
eurjchem-1566	24	73	the	the	DET
eurjchem-1566	24	74	presence	presence	NOUN
eurjchem-1566	24	75	or	or	CCONJ
eurjchem-1566	24	76	absence	absence	NOUN
eurjchem-1566	24	77	of	of	ADP
eurjchem-1566	24	78	one	one	NUM
eurjchem-1566	24	79	equivalent	equivalent	NOUN
eurjchem-1566	24	80	of	of	ADP
eurjchem-1566	24	81	tetraethylammonium	tetraethylammonium	NOUN
eurjchem-1566	24	82	hydroxide	hydroxide	NOUN
eurjchem-1566	24	83	,	,	PUNCT
eurjchem-1566	24	84	on	on	ADP
eurjchem-1566	24	85	the	the	DET
eurjchem-1566	24	86	first‐order	first‐order	NOUN
eurjchem-1566	24	87	rate	rate	NOUN
eurjchem-1566	24	88	coefficient	coefficient	NOUN
eurjchem-1566	24	89	(	(	PUNCT
eurjchem-1566	24	90	k	k	NOUN
eurjchem-1566	24	91	,	,	PUNCT
eurjchem-1566	24	92	s‐1	s‐1	X
eurjchem-1566	24	93	)	)	PUNCT
eurjchem-1566	24	94	a	a	PRON
eurjchem-1566	24	95	for	for	ADP
eurjchem-1566	24	96	solvolysis	solvolysis	NOUN
eurjchem-1566	24	97	of	of	ADP
eurjchem-1566	24	98	2.0×10‐4	2.0×10‐4	NUM
eurjchem-1566	24	99	mol	mol	ADP
eurjchem-1566	24	100	/	/	SYM
eurjchem-1566	24	101	dm3	dm3	NOUN
eurjchem-1566	24	102	4‐bromopiperidine	4‐bromopiperidine	NOUN
eurjchem-1566	24	103	,	,	PUNCT
eurjchem-1566	24	104	as	as	SCONJ
eurjchem-1566	24	105	formed	form	VERB
eurjchem-1566	24	106	in	in	ADP
eurjchem-1566	24	107	situ	situ	NOUN
eurjchem-1566	24	108	from	from	ADP
eurjchem-1566	24	109	the	the	DET
eurjchem-1566	24	110	hydrobromide	hydrobromide	NOUN
eurjchem-1566	24	111	at	at	ADP
eurjchem-1566	24	112	55.0	55.0	NUM
eurjchem-1566	24	113	°	°	NOUN
eurjchem-1566	24	114	c	c	NOUN
eurjchem-1566	24	115	,	,	PUNCT
eurjchem-1566	24	116	tabulated	tabulate	VERB
eurjchem-1566	24	117	as	as	ADP
eurjchem-1566	24	118	104	104	NUM
eurjchem-1566	24	119	k	k	PROPN
eurjchem-1566	24	120	values	value	NOUN
eurjchem-1566	24	121	.	.	PUNCT
eurjchem-1566	25	1	solvent	solvent	PROPN
eurjchem-1566	25	2	b	b	PROPN
eurjchem-1566	25	3	,	,	PUNCT
eurjchem-1566	25	4	c	c	PROPN
eurjchem-1566	26	1	[	[	X
eurjchem-1566	26	2	et3n	et3n	X
eurjchem-1566	26	3	]	]	X
eurjchem-1566	26	4	,	,	PUNCT
eurjchem-1566	26	5	mol	mol	PROPN
eurjchem-1566	26	6	/	/	SYM
eurjchem-1566	26	7	dm3	dm3	NOUN
eurjchem-1566	26	8	0.00040	0.00040	NUM
eurjchem-1566	26	9	0.00060	0.00060	NUM
eurjchem-1566	26	10	0.00040	0.00040	NUM
eurjchem-1566	26	11	(	(	PUNCT
eurjchem-1566	26	12	+0.00020	+0.00020	X
eurjchem-1566	26	13	net4oh	net4oh	NOUN
eurjchem-1566	26	14	)	)	PUNCT
eurjchem-1566	26	15	0.00080	0.00080	NUM
eurjchem-1566	26	16	80e‐20w	80e‐20w	NUM
eurjchem-1566	26	17	(	(	PUNCT
eurjchem-1566	26	18	v	v	NOUN
eurjchem-1566	26	19	/	/	SYM
eurjchem-1566	26	20	v	v	NOUN
eurjchem-1566	26	21	)	)	PUNCT
eurjchem-1566	26	22	1.03±0.02	1.03±0.02	NUM
eurjchem-1566	26	23	0.99±0.02	0.99±0.02	NOUN
eurjchem-1566	26	24	1.06±0.06	1.06±0.06	PROPN
eurjchem-1566	26	25	1.08±0.02	1.08±0.02	NUM
eurjchem-1566	26	26	30m‐70w	30m‐70w	NUM
eurjchem-1566	26	27	(	(	PUNCT
eurjchem-1566	26	28	v	v	NOUN
eurjchem-1566	26	29	/	/	SYM
eurjchem-1566	26	30	v	v	NOUN
eurjchem-1566	26	31	)	)	PUNCT
eurjchem-1566	26	32	32.1±0.90	32.1±0.90	NUM
eurjchem-1566	26	33	32.7±0.70	32.7±0.70	NUM
eurjchem-1566	26	34	37.3±0.50	37.3±0.50	NUM
eurjchem-1566	26	35	40.4±0.30	40.4±0.30	NUM
eurjchem-1566	26	36	80t‐20w	80t‐20w	NUM
eurjchem-1566	26	37	(	(	PUNCT
eurjchem-1566	26	38	w	w	PROPN
eurjchem-1566	26	39	/	/	SYM
eurjchem-1566	26	40	w	w	NOUN
eurjchem-1566	26	41	)	)	PUNCT
eurjchem-1566	26	42	1.10±0.05	1.10±0.05	PROPN
eurjchem-1566	26	43	1.08±0.08	1.08±0.08	NUM
eurjchem-1566	26	44	1.14±0.06	1.14±0.06	NUM
eurjchem-1566	26	45	1.22±0.01	1.22±0.01	NUM
eurjchem-1566	26	46	70t‐30w	70t‐30w	NUM
eurjchem-1566	26	47	(	(	PUNCT
eurjchem-1566	26	48	w	w	PROPN
eurjchem-1566	26	49	/	/	SYM
eurjchem-1566	26	50	w	w	NOUN
eurjchem-1566	26	51	)	)	PUNCT
eurjchem-1566	26	52	1.31±0.03	1.31±0.03	NUM
eurjchem-1566	26	53	1.79±0.08	1.79±0.08	NUM
eurjchem-1566	26	54	1.84±0.04	1.84±0.04	PROPN
eurjchem-1566	26	55	1.94±0.04	1.94±0.04	NUM
eurjchem-1566	26	56	a	a	DET
eurjchem-1566	26	57	average	average	NOUN
eurjchem-1566	26	58	of	of	ADP
eurjchem-1566	26	59	at	at	ADV
eurjchem-1566	26	60	least	least	ADJ
eurjchem-1566	26	61	duplicate	duplicate	ADJ
eurjchem-1566	26	62	determinations	determination	NOUN
eurjchem-1566	26	63	,	,	PUNCT
eurjchem-1566	26	64	reported	report	VERB
eurjchem-1566	26	65	together	together	ADV
eurjchem-1566	26	66	with	with	ADP
eurjchem-1566	26	67	the	the	DET
eurjchem-1566	26	68	standard	standard	ADJ
eurjchem-1566	26	69	deviation	deviation	NOUN
eurjchem-1566	26	70	.	.	PUNCT
eurjchem-1566	27	1	b	b	X
eurjchem-1566	27	2	e	e	NOUN
eurjchem-1566	27	3	,	,	PUNCT
eurjchem-1566	27	4	w	w	PROPN
eurjchem-1566	27	5	,	,	PUNCT
eurjchem-1566	27	6	m	m	PROPN
eurjchem-1566	27	7	,	,	PUNCT
eurjchem-1566	27	8	t	t	PROPN
eurjchem-1566	27	9	represent	represent	VERB
eurjchem-1566	27	10	ethanol	ethanol	NOUN
eurjchem-1566	27	11	,	,	PUNCT
eurjchem-1566	27	12	water	water	NOUN
eurjchem-1566	27	13	,	,	PUNCT
eurjchem-1566	27	14	methanol	methanol	NOUN
eurjchem-1566	27	15	,	,	PUNCT
eurjchem-1566	27	16	2,2,2‐trifluorethanol	2,2,2‐trifluorethanol	NOUN
eurjchem-1566	27	17	.	.	PUNCT
eurjchem-1566	28	1	c	c	NOUN
eurjchem-1566	28	2	the	the	DET
eurjchem-1566	28	3	(	(	PUNCT
eurjchem-1566	28	4	v	v	NOUN
eurjchem-1566	28	5	/	/	SYM
eurjchem-1566	28	6	v	v	NOUN
eurjchem-1566	28	7	)	)	PUNCT
eurjchem-1566	28	8	indicates	indicate	VERB
eurjchem-1566	28	9	volume‐volume	volume‐volume	NOUN
eurjchem-1566	28	10	(	(	PUNCT
eurjchem-1566	28	11	at	at	ADP
eurjchem-1566	28	12	25.0	25.0	NUM
eurjchem-1566	28	13	°	°	NOUN
eurjchem-1566	28	14	c	c	NOUN
eurjchem-1566	28	15	)	)	PUNCT
eurjchem-1566	28	16	and	and	CCONJ
eurjchem-1566	28	17	the	the	DET
eurjchem-1566	28	18	(	(	PUNCT
eurjchem-1566	28	19	w	w	PROPN
eurjchem-1566	28	20	/	/	SYM
eurjchem-1566	28	21	w	w	NOUN
eurjchem-1566	28	22	)	)	PUNCT
eurjchem-1566	28	23	indicates	indicate	VERB
eurjchem-1566	28	24	weight‐weight	weight‐weight	PROPN
eurjchem-1566	28	25	.	.	PUNCT
eurjchem-1566	29	1	unreacted	unreacted	ADJ
eurjchem-1566	29	2	4‐halopiperidine	4‐halopiperidine	NOUN
eurjchem-1566	29	3	)	)	PUNCT
eurjchem-1566	30	1	,	,	PUNCT
eurjchem-1566	30	2	we	we	PRON
eurjchem-1566	30	3	added	add	VERB
eurjchem-1566	30	4	the	the	DET
eurjchem-1566	30	5	substrate	substrate	NOUN
eurjchem-1566	30	6	to	to	ADP
eurjchem-1566	30	7	the	the	DET
eurjchem-1566	30	8	solvent	solvent	NOUN
eurjchem-1566	30	9	under	under	ADP
eurjchem-1566	30	10	consideration	consideration	NOUN
eurjchem-1566	30	11	as	as	ADP
eurjchem-1566	30	12	the	the	DET
eurjchem-1566	30	13	hydrobromide	hydrobromide	NOUN
eurjchem-1566	30	14	and	and	CCONJ
eurjchem-1566	30	15	emp‐	emp‐	PROPN
eurjchem-1566	30	16	loyed	loye	VERB
eurjchem-1566	30	17	sufficient	sufficient	ADJ
eurjchem-1566	30	18	base	base	NOUN
eurjchem-1566	30	19	to	to	AUX
eurjchem-1566	30	20	both	both	PRON
eurjchem-1566	30	21	liberate	liberate	VERB
eurjchem-1566	30	22	2	2	NUM
eurjchem-1566	30	23	and	and	CCONJ
eurjchem-1566	30	24	to	to	PART
eurjchem-1566	30	25	neutralize	neutralize	VERB
eurjchem-1566	30	26	all	all	PRON
eurjchem-1566	30	27	of	of	ADP
eurjchem-1566	30	28	the	the	DET
eurjchem-1566	30	29	acid	acid	NOUN
eurjchem-1566	30	30	subsequently	subsequently	ADV
eurjchem-1566	30	31	produced	produce	VERB
eurjchem-1566	30	32	during	during	ADP
eurjchem-1566	30	33	its	its	PRON
eurjchem-1566	30	34	solvolysis	solvolysis	NOUN
eurjchem-1566	30	35	.	.	PUNCT
eurjchem-1566	31	1	a	a	DET
eurjchem-1566	31	2	general	general	ADJ
eurjchem-1566	31	3	scheme	scheme	NOUN
eurjchem-1566	31	4	for	for	ADP
eurjchem-1566	31	5	a	a	DET
eurjchem-1566	31	6	grob	grob	PROPN
eurjchem-1566	31	7	fragmentation	fragmentation	NOUN
eurjchem-1566	31	8	[	[	X
eurjchem-1566	31	9	1,6,7	1,6,7	NUM
eurjchem-1566	31	10	]	]	PUNCT
eurjchem-1566	31	11	is	be	AUX
eurjchem-1566	31	12	shown	show	VERB
eurjchem-1566	31	13	in	in	ADP
eurjchem-1566	31	14	equation	equation	NOUN
eurjchem-1566	31	15	(	(	PUNCT
eurjchem-1566	31	16	2	2	NUM
eurjchem-1566	31	17	)	)	PUNCT
eurjchem-1566	31	18	.	.	PUNCT
eurjchem-1566	32	1	(	(	PUNCT
eurjchem-1566	32	2	2	2	X
eurjchem-1566	32	3	)	)	PUNCT
eurjchem-1566	32	4	this	this	PRON
eurjchem-1566	32	5	is	be	AUX
eurjchem-1566	32	6	the	the	DET
eurjchem-1566	32	7	mechanism	mechanism	NOUN
eurjchem-1566	32	8	that	that	PRON
eurjchem-1566	32	9	was	be	AUX
eurjchem-1566	32	10	applied	apply	VERB
eurjchem-1566	32	11	[	[	X
eurjchem-1566	32	12	1,6,7	1,6,7	NUM
eurjchem-1566	32	13	]	]	PUNCT
eurjchem-1566	32	14	to	to	ADP
eurjchem-1566	32	15	the	the	DET
eurjchem-1566	32	16	fragmentation	fragmentation	NOUN
eurjchem-1566	32	17	of	of	ADP
eurjchem-1566	32	18	4‐chloropiperidine	4‐chloropiperidine	NOUN
eurjchem-1566	32	19	in	in	ADP
eurjchem-1566	32	20	80	80	NUM
eurjchem-1566	32	21	%	%	NOUN
eurjchem-1566	32	22	ethanol‐20	ethanol‐20	NUM
eurjchem-1566	32	23	%	%	NOUN
eurjchem-1566	32	24	water	water	NOUN
eurjchem-1566	32	25	,	,	PUNCT
eurjchem-1566	32	26	equation	equation	NOUN
eurjchem-1566	32	27	(	(	PUNCT
eurjchem-1566	32	28	3	3	NUM
eurjchem-1566	32	29	)	)	PUNCT
eurjchem-1566	32	30	.	.	PUNCT
eurjchem-1566	33	1	(	(	PUNCT
eurjchem-1566	33	2	3	3	X
eurjchem-1566	33	3	)	)	PUNCT
eurjchem-1566	33	4	the	the	DET
eurjchem-1566	33	5	carbimonium	carbimonium	NOUN
eurjchem-1566	33	6	ion	ion	NOUN
eurjchem-1566	33	7	formed	form	VERB
eurjchem-1566	33	8	is	be	AUX
eurjchem-1566	33	9	then	then	ADV
eurjchem-1566	33	10	spontaneously	spontaneously	ADV
eurjchem-1566	33	11	hydrolyzed	hydrolyze	VERB
eurjchem-1566	33	12	to	to	ADP
eurjchem-1566	33	13	1‐amino‐3‐butene	1‐amino‐3‐butene	NUM
eurjchem-1566	33	14	which	which	PRON
eurjchem-1566	33	15	,	,	PUNCT
eurjchem-1566	33	16	after	after	ADP
eurjchem-1566	33	17	treatment	treatment	NOUN
eurjchem-1566	33	18	with	with	ADP
eurjchem-1566	33	19	p‐toluenesulfonyl	p‐toluenesulfonyl	PUNCT
eurjchem-1566	33	20	chloride	chloride	NOUN
eurjchem-1566	33	21	and	and	CCONJ
eurjchem-1566	33	22	sodium	sodium	NOUN
eurjchem-1566	33	23	hydroxide	hydroxide	NOUN
eurjchem-1566	33	24	,	,	PUNCT
eurjchem-1566	33	25	was	be	AUX
eurjchem-1566	33	26	isolated	isolate	VERB
eurjchem-1566	34	1	[	[	X
eurjchem-1566	34	2	1	1	NUM
eurjchem-1566	34	3	]	]	PUNCT
eurjchem-1566	34	4	as	as	ADP
eurjchem-1566	34	5	the	the	DET
eurjchem-1566	34	6	ditosyl	ditosyl	ADJ
eurjchem-1566	34	7	derivative	derivative	NOUN
eurjchem-1566	34	8	[	[	X
eurjchem-1566	34	9	ch2	ch2	NOUN
eurjchem-1566	34	10	=	=	NOUN
eurjchem-1566	34	11	ch‐ch2‐ch2‐n(so2c6h4‐p‐	ch‐ch2‐ch2‐n(so2c6h4‐p‐	NOUN
eurjchem-1566	34	12	ch3)2	ch3)2	PROPN
eurjchem-1566	34	13	]	]	PUNCT
eurjchem-1566	34	14	,	,	PUNCT
eurjchem-1566	34	15	which	which	PRON
eurjchem-1566	34	16	could	could	AUX
eurjchem-1566	34	17	be	be	AUX
eurjchem-1566	34	18	stabilized	stabilize	VERB
eurjchem-1566	34	19	by	by	ADP
eurjchem-1566	34	20	hydrogenation	hydrogenation	NOUN
eurjchem-1566	34	21	of	of	ADP
eurjchem-1566	34	22	the	the	DET
eurjchem-1566	34	23	double	double	ADJ
eurjchem-1566	34	24	bond	bond	NOUN
eurjchem-1566	34	25	.	.	PUNCT
eurjchem-1566	35	1	in	in	ADP
eurjchem-1566	35	2	a	a	DET
eurjchem-1566	35	3	study	study	NOUN
eurjchem-1566	35	4	of	of	ADP
eurjchem-1566	35	5	the	the	DET
eurjchem-1566	35	6	trifluoroacetolysis	trifluoroacetolysis	NOUN
eurjchem-1566	35	7	of	of	ADP
eurjchem-1566	35	8	variously	variously	ADV
eurjchem-1566	35	9	substi‐	substi‐	ADP
eurjchem-1566	35	10	tuted	tut	VERB
eurjchem-1566	35	11	tetrahydropyranyl	tetrahydropyranyl	NOUN
eurjchem-1566	35	12	methanesulfonates	methanesulfonate	NOUN
eurjchem-1566	35	13	(	(	PUNCT
eurjchem-1566	35	14	mesylates	mesylate	NOUN
eurjchem-1566	35	15	)	)	PUNCT
eurjchem-1566	36	1	[	[	X
eurjchem-1566	36	2	9	9	NUM
eurjchem-1566	36	3	]	]	PUNCT
eurjchem-1566	36	4	,	,	PUNCT
eurjchem-1566	36	5	it	it	PRON
eurjchem-1566	36	6	was	be	AUX
eurjchem-1566	36	7	demonstrated	demonstrate	VERB
eurjchem-1566	36	8	that	that	SCONJ
eurjchem-1566	36	9	the	the	DET
eurjchem-1566	36	10	tetrahydropyranyl	tetrahydropyranyl	NOUN
eurjchem-1566	36	11	cation	cation	NOUN
eurjchem-1566	36	12	was	be	AUX
eurjchem-1566	36	13	a	a	DET
eurjchem-1566	36	14	common	common	ADJ
eurjchem-1566	36	15	intermediate	intermediate	NOUN
eurjchem-1566	36	16	for	for	ADP
eurjchem-1566	36	17	grob	grob	PROPN
eurjchem-1566	36	18	fragmentation	fragmentation	NOUN
eurjchem-1566	37	1	[	[	X
eurjchem-1566	37	2	following	follow	VERB
eurjchem-1566	37	3	the	the	DET
eurjchem-1566	37	4	upper	upper	ADJ
eurjchem-1566	37	5	pathway	pathway	NOUN
eurjchem-1566	37	6	of	of	ADP
eurjchem-1566	37	7	equation	equation	NOUN
eurjchem-1566	37	8	(	(	PUNCT
eurjchem-1566	37	9	4	4	NUM
eurjchem-1566	37	10	)	)	PUNCT
eurjchem-1566	37	11	]	]	PUNCT
eurjchem-1566	37	12	,	,	PUNCT
eurjchem-1566	37	13	prins	prin	VERB
eurjchem-1566	37	14	cyclizations	cyclization	NOUN
eurjchem-1566	37	15	[	[	X
eurjchem-1566	37	16	10	10	NUM
eurjchem-1566	37	17	]	]	PUNCT
eurjchem-1566	37	18	and	and	CCONJ
eurjchem-1566	37	19	2‐	2‐	NUM
eurjchem-1566	37	20	oxonia‐cope	oxonia‐cope	NOUN
eurjchem-1566	37	21	rearrangements	rearrangement	NOUN
eurjchem-1566	37	22	[	[	X
eurjchem-1566	37	23	11	11	NUM
eurjchem-1566	37	24	]	]	PUNCT
eurjchem-1566	37	25	.	.	PUNCT
eurjchem-1566	38	1	this	this	PRON
eurjchem-1566	38	2	suggested	suggest	VERB
eurjchem-1566	38	3	that	that	SCONJ
eurjchem-1566	38	4	it	it	PRON
eurjchem-1566	38	5	would	would	AUX
eurjchem-1566	38	6	be	be	AUX
eurjchem-1566	38	7	worthwhile	worthwhile	ADJ
eurjchem-1566	38	8	to	to	PART
eurjchem-1566	38	9	see	see	VERB
eurjchem-1566	38	10	if	if	SCONJ
eurjchem-1566	38	11	any	any	DET
eurjchem-1566	38	12	evidence	evidence	NOUN
eurjchem-1566	38	13	for	for	ADP
eurjchem-1566	38	14	this	this	DET
eurjchem-1566	38	15	type	type	NOUN
eurjchem-1566	38	16	of	of	ADP
eurjchem-1566	38	17	non‐synchronous	non‐synchronous	ADJ
eurjchem-1566	38	18	pathway	pathway	NOUN
eurjchem-1566	38	19	could	could	AUX
eurjchem-1566	38	20	be	be	AUX
eurjchem-1566	38	21	found	find	VERB
eurjchem-1566	38	22	in	in	ADP
eurjchem-1566	38	23	the	the	DET
eurjchem-1566	38	24	solvolyses	solvolyse	NOUN
eurjchem-1566	38	25	of	of	ADP
eurjchem-1566	38	26	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	38	27	(	(	PUNCT
eurjchem-1566	38	28	2	2	NUM
eurjchem-1566	38	29	)	)	PUNCT
eurjchem-1566	38	30	.	.	PUNCT
eurjchem-1566	39	1	(	(	PUNCT
eurjchem-1566	39	2	4	4	X
eurjchem-1566	39	3	)	)	PUNCT
eurjchem-1566	39	4	2	2	NUM
eurjchem-1566	39	5	.	.	X
eurjchem-1566	39	6	experimental	experimental	VERB
eurjchem-1566	39	7	the	the	DET
eurjchem-1566	39	8	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	39	9	hydrobromide	hydrobromide	NOUN
eurjchem-1566	39	10	(	(	PUNCT
eurjchem-1566	39	11	aldrich	aldrich	NOUN
eurjchem-1566	39	12	,	,	PUNCT
eurjchem-1566	39	13	98	98	NUM
eurjchem-1566	39	14	%	%	NOUN
eurjchem-1566	39	15	)	)	PUNCT
eurjchem-1566	39	16	,	,	PUNCT
eurjchem-1566	39	17	triethylamine	triethylamine	NOUN
eurjchem-1566	39	18	(	(	PUNCT
eurjchem-1566	39	19	aldrich	aldrich	PROPN
eurjchem-1566	39	20	≥	≥	NUM
eurjchem-1566	39	21	99.5	99.5	NUM
eurjchem-1566	39	22	%	%	NOUN
eurjchem-1566	39	23	)	)	PUNCT
eurjchem-1566	39	24	and	and	CCONJ
eurjchem-1566	39	25	tetraethylammonium	tetraethylammonium	NOUN
eurjchem-1566	39	26	hydroxide	hydroxide	NOUN
eurjchem-1566	39	27	(	(	PUNCT
eurjchem-1566	39	28	aldrich	aldrich	PROPN
eurjchem-1566	39	29	,	,	PUNCT
eurjchem-1566	39	30	35	35	NUM
eurjchem-1566	39	31	%	%	NOUN
eurjchem-1566	39	32	by	by	ADP
eurjchem-1566	39	33	weight	weight	NOUN
eurjchem-1566	39	34	in	in	ADP
eurjchem-1566	39	35	water	water	NOUN
eurjchem-1566	39	36	)	)	PUNCT
eurjchem-1566	39	37	were	be	AUX
eurjchem-1566	39	38	used	use	VERB
eurjchem-1566	39	39	as	as	SCONJ
eurjchem-1566	39	40	received	receive	VERB
eurjchem-1566	39	41	.	.	PUNCT
eurjchem-1566	40	1	the	the	DET
eurjchem-1566	40	2	purifications	purification	NOUN
eurjchem-1566	40	3	of	of	ADP
eurjchem-1566	40	4	acetone	acetone	NOUN
eurjchem-1566	40	5	[	[	X
eurjchem-1566	40	6	12	12	NUM
eurjchem-1566	40	7	]	]	PUNCT
eurjchem-1566	40	8	,	,	PUNCT
eurjchem-1566	40	9	acetonitrile	acetonitrile	NOUN
eurjchem-1566	40	10	[	[	X
eurjchem-1566	40	11	13	13	NUM
eurjchem-1566	40	12	]	]	PUNCT
eurjchem-1566	40	13	,	,	PUNCT
eurjchem-1566	40	14	dioxane	dioxane	NOUN
eurjchem-1566	40	15	[	[	X
eurjchem-1566	40	16	12	12	NUM
eurjchem-1566	40	17	]	]	PUNCT
eurjchem-1566	40	18	,	,	PUNCT
eurjchem-1566	40	19	ethanol	ethanol	NOUN
eurjchem-1566	40	20	[	[	X
eurjchem-1566	40	21	12	12	NUM
eurjchem-1566	40	22	]	]	PUNCT
eurjchem-1566	40	23	,	,	PUNCT
eurjchem-1566	40	24	methanol	methanol	NOUN
eurjchem-1566	40	25	[	[	X
eurjchem-1566	40	26	12	12	NUM
eurjchem-1566	40	27	]	]	PUNCT
eurjchem-1566	40	28	,	,	PUNCT
eurjchem-1566	40	29	and	and	CCONJ
eurjchem-1566	40	30	2,2,2‐trifluoro	2,2,2‐trifluoro	NUM
eurjchem-1566	40	31	ethanol	ethanol	NOUN
eurjchem-1566	40	32	[	[	X
eurjchem-1566	40	33	14	14	NUM
eurjchem-1566	40	34	]	]	PUNCT
eurjchem-1566	40	35	were	be	AUX
eurjchem-1566	40	36	carried	carry	VERB
eurjchem-1566	40	37	out	out	ADP
eurjchem-1566	40	38	as	as	ADV
eurjchem-1566	40	39	previously	previously	ADV
eurjchem-1566	40	40	described	describe	VERB
eurjchem-1566	40	41	.	.	PUNCT
eurjchem-1566	41	1	the	the	DET
eurjchem-1566	41	2	aqueous‐organic	aqueous‐organic	ADJ
eurjchem-1566	41	3	solvents	solvent	NOUN
eurjchem-1566	41	4	were	be	AUX
eurjchem-1566	41	5	prepared	prepare	VERB
eurjchem-1566	41	6	by	by	ADP
eurjchem-1566	41	7	the	the	DET
eurjchem-1566	41	8	mixing	mixing	NOUN
eurjchem-1566	41	9	of	of	ADP
eurjchem-1566	41	10	appropriate	appropriate	ADJ
eurjchem-1566	41	11	volumes	volume	NOUN
eurjchem-1566	41	12	of	of	ADP
eurjchem-1566	41	13	the	the	DET
eurjchem-1566	41	14	purified	purified	ADJ
eurjchem-1566	41	15	organic	organic	ADJ
eurjchem-1566	41	16	solvent	solvent	NOUN
eurjchem-1566	41	17	and	and	CCONJ
eurjchem-1566	41	18	water	water	NOUN
eurjchem-1566	41	19	at	at	ADP
eurjchem-1566	41	20	25	25	NUM
eurjchem-1566	41	21	°	°	NOUN
eurjchem-1566	41	22	c	c	NOUN
eurjchem-1566	41	23	,	,	PUNCT
eurjchem-1566	41	24	except	except	SCONJ
eurjchem-1566	41	25	for	for	ADP
eurjchem-1566	41	26	the	the	DET
eurjchem-1566	41	27	aqueous	aqueous	ADJ
eurjchem-1566	41	28	tfe	tfe	NOUN
eurjchem-1566	41	29	solvents	solvent	NOUN
eurjchem-1566	41	30	,	,	PUNCT
eurjchem-1566	41	31	of	of	ADP
eurjchem-1566	41	32	known	know	VERB
eurjchem-1566	41	33	nt	not	PART
eurjchem-1566	41	34	[	[	X
eurjchem-1566	41	35	5	5	NUM
eurjchem-1566	41	36	]	]	PUNCT
eurjchem-1566	41	37	and	and	CCONJ
eurjchem-1566	41	38	ybr	ybr	PROPN
eurjchem-1566	42	1	[	[	X
eurjchem-1566	42	2	4,15	4,15	NOUN
eurjchem-1566	42	3	]	]	X
eurjchem-1566	42	4	values	value	NOUN
eurjchem-1566	42	5	,	,	PUNCT
eurjchem-1566	42	6	which	which	PRON
eurjchem-1566	42	7	were	be	AUX
eurjchem-1566	42	8	prepared	prepare	VERB
eurjchem-1566	42	9	on	on	ADP
eurjchem-1566	42	10	a	a	DET
eurjchem-1566	42	11	weight‐weight	weight‐weight	ADJ
eurjchem-1566	42	12	basis	basis	NOUN
eurjchem-1566	42	13	.	.	PUNCT
eurjchem-1566	43	1	initial	initial	ADJ
eurjchem-1566	43	2	experiments	experiment	NOUN
eurjchem-1566	43	3	to	to	PART
eurjchem-1566	43	4	determine	determine	VERB
eurjchem-1566	43	5	the	the	DET
eurjchem-1566	43	6	best	good	ADJ
eurjchem-1566	43	7	reaction	reaction	NOUN
eurjchem-1566	43	8	condi‐	condi‐	PROPN
eurjchem-1566	43	9	tions	tion	NOUN
eurjchem-1566	43	10	as	as	SCONJ
eurjchem-1566	43	11	regards	regard	VERB
eurjchem-1566	43	12	the	the	DET
eurjchem-1566	43	13	amount	amount	NOUN
eurjchem-1566	43	14	of	of	ADP
eurjchem-1566	43	15	excess	excess	ADJ
eurjchem-1566	43	16	base	base	NOUN
eurjchem-1566	43	17	are	be	AUX
eurjchem-1566	43	18	summarized	summarize	VERB
eurjchem-1566	43	19	in	in	ADP
eurjchem-1566	43	20	table	table	NOUN
eurjchem-1566	43	21	1	1	NUM
eurjchem-1566	43	22	.	.	PUNCT
eurjchem-1566	44	1	both	both	DET
eurjchem-1566	44	2	triethylamine	triethylamine	NOUN
eurjchem-1566	44	3	alone	alone	ADJ
eurjchem-1566	44	4	and	and	CCONJ
eurjchem-1566	44	5	triethylamine	triethylamine	NOUN
eurjchem-1566	44	6	plus	plus	CCONJ
eurjchem-1566	44	7	one	one	NUM
eurjchem-1566	44	8	equivalent	equivalent	NOUN
eurjchem-1566	44	9	(	(	PUNCT
eurjchem-1566	44	10	as	as	SCONJ
eurjchem-1566	44	11	regards	regard	VERB
eurjchem-1566	44	12	the	the	DET
eurjchem-1566	44	13	concentration	concentration	NOUN
eurjchem-1566	44	14	of	of	ADP
eurjchem-1566	44	15	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	44	16	(	(	PUNCT
eurjchem-1566	44	17	2	2	NUM
eurjchem-1566	44	18	)	)	PUNCT
eurjchem-1566	44	19	)	)	PUNCT
eurjchem-1566	44	20	tetraethylammonium	tetraethylammonium	NOUN
eurjchem-1566	44	21	hydroxide	hydroxide	NOUN
eurjchem-1566	44	22	were	be	AUX
eurjchem-1566	44	23	considered	consider	VERB
eurjchem-1566	44	24	.	.	PUNCT
eurjchem-1566	45	1	it	it	PRON
eurjchem-1566	45	2	was	be	AUX
eurjchem-1566	45	3	found	find	VERB
eurjchem-1566	45	4	that	that	SCONJ
eurjchem-1566	45	5	,	,	PUNCT
eurjchem-1566	45	6	within	within	ADP
eurjchem-1566	45	7	reasonable	reasonable	ADJ
eurjchem-1566	45	8	limits	limit	NOUN
eurjchem-1566	45	9	,	,	PUNCT
eurjchem-1566	45	10	the	the	DET
eurjchem-1566	45	11	amount	amount	NOUN
eurjchem-1566	45	12	of	of	ADP
eurjchem-1566	45	13	excess	excess	ADJ
eurjchem-1566	45	14	base	base	NOUN
eurjchem-1566	45	15	was	be	AUX
eurjchem-1566	45	16	not	not	PART
eurjchem-1566	45	17	critical	critical	ADJ
eurjchem-1566	45	18	.	.	PUNCT
eurjchem-1566	46	1	the	the	DET
eurjchem-1566	46	2	concentration	concentration	NOUN
eurjchem-1566	46	3	chosen	choose	VERB
eurjchem-1566	46	4	for	for	ADP
eurjchem-1566	46	5	the	the	DET
eurjchem-1566	46	6	conducto‐	conducto‐	PROPN
eurjchem-1566	46	7	metric	metric	ADJ
eurjchem-1566	46	8	determination	determination	NOUN
eurjchem-1566	46	9	of	of	ADP
eurjchem-1566	46	10	the	the	DET
eurjchem-1566	46	11	specific	specific	ADJ
eurjchem-1566	46	12	rates	rate	NOUN
eurjchem-1566	46	13	of	of	ADP
eurjchem-1566	46	14	solvolysis	solvolysis	NOUN
eurjchem-1566	46	15	of	of	ADP
eurjchem-1566	46	16	4‐	4‐	PROPN
eurjchem-1566	46	17	bromopiperidine	bromopiperidine	NOUN
eurjchem-1566	46	18	at	at	ADP
eurjchem-1566	46	19	55.0	55.0	NUM
eurjchem-1566	46	20	°	°	NOUN
eurjchem-1566	46	21	c	c	NOUN
eurjchem-1566	46	22	and	and	CCONJ
eurjchem-1566	46	23	the	the	DET
eurjchem-1566	46	24	procedure	procedure	NOUN
eurjchem-1566	46	25	for	for	ADP
eurjchem-1566	46	26	preparing	prepare	VERB
eurjchem-1566	46	27	2.0	2.0	NUM
eurjchem-1566	46	28	ml	ml	NOUN
eurjchem-1566	46	29	of	of	ADP
eurjchem-1566	46	30	solution	solution	NOUN
eurjchem-1566	46	31	are	be	AUX
eurjchem-1566	46	32	presented	present	VERB
eurjchem-1566	46	33	in	in	ADP
eurjchem-1566	46	34	footnote	footnote	NOUN
eurjchem-1566	46	35	(	(	PUNCT
eurjchem-1566	46	36	a	a	NOUN
eurjchem-1566	46	37	)	)	PUNCT
eurjchem-1566	46	38	to	to	PART
eurjchem-1566	46	39	table	table	VERB
eurjchem-1566	46	40	2	2	NUM
eurjchem-1566	46	41	.	.	PUNCT
eurjchem-1566	47	1	details	detail	NOUN
eurjchem-1566	47	2	of	of	ADP
eurjchem-1566	47	3	the	the	DET
eurjchem-1566	47	4	conductivity	conductivity	NOUN
eurjchem-1566	47	5	apparatus	apparatus	NOUN
eurjchem-1566	47	6	and	and	CCONJ
eurjchem-1566	47	7	the	the	DET
eurjchem-1566	47	8	computer	computer	NOUN
eurjchem-1566	47	9	procedure	procedure	NOUN
eurjchem-1566	47	10	for	for	ADP
eurjchem-1566	47	11	calculation	calculation	NOUN
eurjchem-1566	47	12	of	of	ADP
eurjchem-1566	47	13	the	the	DET
eurjchem-1566	47	14	specific	specific	ADJ
eurjchem-1566	47	15	rates	rate	NOUN
eurjchem-1566	47	16	have	have	AUX
eurjchem-1566	47	17	previously	previously	ADV
eurjchem-1566	47	18	been	be	AUX
eurjchem-1566	47	19	reported	report	VERB
eurjchem-1566	47	20	[	[	X
eurjchem-1566	47	21	16,17	16,17	NUM
eurjchem-1566	47	22	]	]	PUNCT
eurjchem-1566	47	23	.	.	PUNCT
eurjchem-1566	48	1	the	the	DET
eurjchem-1566	48	2	regression	regression	NOUN
eurjchem-1566	48	3	analyses	analysis	NOUN
eurjchem-1566	48	4	were	be	AUX
eurjchem-1566	48	5	perfor‐	perfor‐	NOUN
eurjchem-1566	48	6	med	med	ADJ
eurjchem-1566	48	7	using	use	VERB
eurjchem-1566	48	8	commercially	commercially	ADV
eurjchem-1566	48	9	available	available	ADJ
eurjchem-1566	48	10	statistical	statistical	ADJ
eurjchem-1566	48	11	packages	package	NOUN
eurjchem-1566	48	12	.	.	PUNCT
eurjchem-1566	49	1	3	3	X
eurjchem-1566	49	2	.	.	NOUN
eurjchem-1566	49	3	results	result	NOUN
eurjchem-1566	49	4	and	and	CCONJ
eurjchem-1566	49	5	discussion	discussion	NOUN
eurjchem-1566	49	6	in	in	ADP
eurjchem-1566	49	7	table	table	NOUN
eurjchem-1566	49	8	1	1	NUM
eurjchem-1566	49	9	is	be	AUX
eurjchem-1566	49	10	shown	show	VERB
eurjchem-1566	49	11	the	the	DET
eurjchem-1566	49	12	effect	effect	NOUN
eurjchem-1566	49	13	of	of	ADP
eurjchem-1566	49	14	varying	vary	VERB
eurjchem-1566	49	15	the	the	DET
eurjchem-1566	49	16	triethylamine	triethylamine	NOUN
eurjchem-1566	49	17	concentration	concentration	NOUN
eurjchem-1566	49	18	on	on	ADP
eurjchem-1566	49	19	the	the	DET
eurjchem-1566	49	20	first‐order	first‐order	NOUN
eurjchem-1566	49	21	rate	rate	NOUN
eurjchem-1566	49	22	coefficient	coefficient	NOUN
eurjchem-1566	49	23	(	(	PUNCT
eurjchem-1566	49	24	specific	specific	ADJ
eurjchem-1566	49	25	rate	rate	NOUN
eurjchem-1566	49	26	)	)	PUNCT
eurjchem-1566	49	27	for	for	ADP
eurjchem-1566	49	28	solvolysis	solvolysis	NOUN
eurjchem-1566	49	29	when	when	SCONJ
eurjchem-1566	49	30	the	the	DET
eurjchem-1566	49	31	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	49	32	(	(	PUNCT
eurjchem-1566	49	33	2	2	NUM
eurjchem-1566	49	34	)	)	PUNCT
eurjchem-1566	49	35	is	be	AUX
eurjchem-1566	49	36	introduced	introduce	VERB
eurjchem-1566	49	37	as	as	ADP
eurjchem-1566	49	38	its	its	PRON
eurjchem-1566	49	39	hydrobromide	hydrobromide	NOUN
eurjchem-1566	49	40	to	to	ADP
eurjchem-1566	49	41	four	four	NUM
eurjchem-1566	49	42	typical	typical	ADJ
eurjchem-1566	49	43	aqueous‐organic	aqueous‐organic	ADJ
eurjchem-1566	49	44	solvents	solvent	NOUN
eurjchem-1566	49	45	at	at	ADP
eurjchem-1566	49	46	55.0	55.0	NUM
eurjchem-1566	49	47	°	°	NOUN
eurjchem-1566	49	48	c	c	NOUN
eurjchem-1566	49	49	.	.	PUNCT
eurjchem-1566	50	1	also	also	ADV
eurjchem-1566	50	2	shown	show	VERB
eurjchem-1566	50	3	is	be	AUX
eurjchem-1566	50	4	the	the	DET
eurjchem-1566	50	5	effect	effect	NOUN
eurjchem-1566	50	6	of	of	ADP
eurjchem-1566	50	7	including	include	VERB
eurjchem-1566	50	8	one	one	NUM
eurjchem-1566	50	9	equivalent	equivalent	NOUN
eurjchem-1566	50	10	of	of	ADP
eurjchem-1566	50	11	tetraethylammonium	tetraethylammonium	NOUN
eurjchem-1566	50	12	hydroxide	hydroxide	NOUN
eurjchem-1566	50	13	for	for	ADP
eurjchem-1566	50	14	the	the	DET
eurjchem-1566	50	15	initial	initial	ADJ
eurjchem-1566	50	16	deprotonation	deprotonation	NOUN
eurjchem-1566	50	17	of	of	ADP
eurjchem-1566	50	18	the	the	DET
eurjchem-1566	50	19	4‐bromopiperidinium	4‐bromopiperidinium	PROPN
eurjchem-1566	50	20	ion	ion	NOUN
eurjchem-1566	50	21	,	,	PUNCT
eurjchem-1566	50	22	to	to	PART
eurjchem-1566	50	23	liberate	liberate	VERB
eurjchem-1566	50	24	the	the	DET
eurjchem-1566	50	25	free	free	ADJ
eurjchem-1566	50	26	2	2	NUM
eurjchem-1566	50	27	.	.	PUNCT
eurjchem-1566	51	1	the	the	DET
eurjchem-1566	51	2	first	first	ADJ
eurjchem-1566	51	3	vertical	vertical	ADJ
eurjchem-1566	51	4	column	column	NOUN
eurjchem-1566	51	5	in	in	ADP
eurjchem-1566	51	6	the	the	DET
eurjchem-1566	51	7	table	table	NOUN
eurjchem-1566	51	8	is	be	AUX
eurjchem-1566	51	9	for	for	ADP
eurjchem-1566	51	10	addition	addition	NOUN
eurjchem-1566	51	11	of	of	ADP
eurjchem-1566	51	12	two	two	NUM
eurjchem-1566	51	13	equivalents	equivalent	NOUN
eurjchem-1566	51	14	of	of	ADP
eurjchem-1566	51	15	triethylamine	triethylamine	NOUN
eurjchem-1566	51	16	,	,	PUNCT
eurjchem-1566	51	17	the	the	DET
eurjchem-1566	51	18	minimum	minimum	NOUN
eurjchem-1566	51	19	amount	amount	NOUN
eurjchem-1566	51	20	for	for	ADP
eurjchem-1566	51	21	the	the	DET
eurjchem-1566	51	22	initial	initial	ADJ
eurjchem-1566	51	23	deproto‐	deproto‐	PROPN
eurjchem-1566	51	24	nation	nation	NOUN
eurjchem-1566	51	25	followed	follow	VERB
eurjchem-1566	51	26	by	by	ADP
eurjchem-1566	51	27	complete	complete	ADJ
eurjchem-1566	51	28	neutralization	neutralization	NOUN
eurjchem-1566	51	29	of	of	ADP
eurjchem-1566	51	30	the	the	DET
eurjchem-1566	51	31	acid	acid	NOUN
eurjchem-1566	51	32	produ‐	produ‐	NOUN
eurjchem-1566	51	33	ced	ce	VERB
eurjchem-1566	51	34	during	during	ADP
eurjchem-1566	51	35	the	the	DET
eurjchem-1566	51	36	solvolysis	solvolysis	NOUN
eurjchem-1566	51	37	.	.	PUNCT
eurjchem-1566	52	1	the	the	DET
eurjchem-1566	52	2	next	next	ADJ
eurjchem-1566	52	3	two	two	NUM
eurjchem-1566	52	4	vertical	vertical	ADJ
eurjchem-1566	52	5	columns	column	NOUN
eurjchem-1566	52	6	would	would	AUX
eurjchem-1566	52	7	each	each	PRON
eurjchem-1566	52	8	have	have	VERB
eurjchem-1566	52	9	an	an	DET
eurjchem-1566	52	10	excess	excess	NOUN
eurjchem-1566	52	11	of	of	ADP
eurjchem-1566	52	12	one	one	NUM
eurjchem-1566	52	13	equivalent	equivalent	NOUN
eurjchem-1566	52	14	of	of	ADP
eurjchem-1566	52	15	triethylamine	triethylamine	NOUN
eurjchem-1566	52	16	and	and	CCONJ
eurjchem-1566	52	17	the	the	DET
eurjchem-1566	52	18	final	final	ADJ
eurjchem-1566	52	19	vertical	vertical	ADJ
eurjchem-1566	52	20	column	column	NOUN
eurjchem-1566	52	21	is	be	AUX
eurjchem-1566	52	22	for	for	ADP
eurjchem-1566	52	23	an	an	DET
eurjchem-1566	52	24	excess	excess	NOUN
eurjchem-1566	52	25	of	of	ADP
eurjchem-1566	52	26	two	two	NUM
eurjchem-1566	52	27	equivalents	equivalent	NOUN
eurjchem-1566	52	28	of	of	ADP
eurjchem-1566	52	29	triethylamine	triethylamine	NOUN
eurjchem-1566	52	30	over	over	ADP
eurjchem-1566	52	31	the	the	DET
eurjchem-1566	52	32	minimum	minimum	NOUN
eurjchem-1566	52	33	required	require	VERB
eurjchem-1566	52	34	to	to	PART
eurjchem-1566	52	35	allow	allow	VERB
eurjchem-1566	52	36	a	a	DET
eurjchem-1566	52	37	complete	complete	ADJ
eurjchem-1566	52	38	solvolysis	solvolysis	NOUN
eurjchem-1566	52	39	of	of	ADP
eurjchem-1566	52	40	the	the	DET
eurjchem-1566	52	41	unprotonated	unprotonated	ADJ
eurjchem-1566	52	42	2	2	NUM
eurjchem-1566	52	43	.	.	PUNCT
eurjchem-1566	53	1	in	in	ADP
eurjchem-1566	53	2	all	all	DET
eurjchem-1566	53	3	four	four	NUM
eurjchem-1566	53	4	solvent	solvent	NOUN
eurjchem-1566	53	5	systems	system	NOUN
eurjchem-1566	53	6	,	,	PUNCT
eurjchem-1566	53	7	the	the	DET
eurjchem-1566	53	8	highest	high	ADJ
eurjchem-1566	53	9	specific	specific	ADJ
eurjchem-1566	53	10	rate	rate	NOUN
eurjchem-1566	53	11	values	value	NOUN
eurjchem-1566	53	12	are	be	AUX
eurjchem-1566	53	13	for	for	ADP
eurjchem-1566	53	14	the	the	DET
eurjchem-1566	53	15	runs	run	NOUN
eurjchem-1566	53	16	with	with	ADP
eurjchem-1566	53	17	the	the	DET
eurjchem-1566	53	18	largest	large	ADJ
eurjchem-1566	53	19	triethylamine	triethylamine	NOUN
eurjchem-1566	53	20	concentration	concentration	NOUN
eurjchem-1566	53	21	,	,	PUNCT
eurjchem-1566	53	22	but	but	CCONJ
eurjchem-1566	53	23	the	the	DET
eurjchem-1566	53	24	increases	increase	NOUN
eurjchem-1566	53	25	in	in	ADP
eurjchem-1566	53	26	specific	specific	ADJ
eurjchem-1566	53	27	rate	rate	NOUN
eurjchem-1566	53	28	with	with	ADP
eurjchem-1566	53	29	increases	increase	NOUN
eurjchem-1566	53	30	in	in	ADP
eurjchem-1566	53	31	excess	excess	ADJ
eurjchem-1566	53	32	amine	amine	ADJ
eurjchem-1566	53	33	concentration	concentration	NOUN
eurjchem-1566	53	34	are	be	AUX
eurjchem-1566	53	35	small	small	ADJ
eurjchem-1566	53	36	.	.	PUNCT
eurjchem-1566	54	1	this	this	DET
eurjchem-1566	54	2	aspect	aspect	NOUN
eurjchem-1566	54	3	of	of	ADP
eurjchem-1566	54	4	the	the	DET
eurjchem-1566	54	5	study	study	NOUN
eurjchem-1566	54	6	indica‐	indica‐	VERB
eurjchem-1566	54	7	tes	tes	NOUN
eurjchem-1566	54	8	that	that	PRON
eurjchem-1566	54	9	a	a	DET
eurjchem-1566	54	10	modest	modest	ADJ
eurjchem-1566	54	11	excess	excess	NOUN
eurjchem-1566	54	12	of	of	ADP
eurjchem-1566	54	13	triethylamine	triethylamine	NOUN
eurjchem-1566	54	14	,	,	PUNCT
eurjchem-1566	54	15	assuring	assure	VERB
eurjchem-1566	54	16	an	an	DET
eurjchem-1566	54	17	essentially	essentially	ADV
eurjchem-1566	54	18	complete	complete	ADJ
eurjchem-1566	54	19	deprotonation	deprotonation	NOUN
eurjchem-1566	54	20	of	of	ADP
eurjchem-1566	54	21	the	the	DET
eurjchem-1566	54	22	4‐bromopiperidine	4‐bromopiperidine	NOUN
eurjchem-1566	54	23	throughout	throughout	ADP
eurjchem-1566	54	24	the	the	DET
eurjchem-1566	54	25	solvolysis	solvolysis	NOUN
eurjchem-1566	54	26	,	,	PUNCT
eurjchem-1566	54	27	would	would	AUX
eurjchem-1566	54	28	afford	afford	VERB
eurjchem-1566	54	29	the	the	DET
eurjchem-1566	54	30	best	good	ADJ
eurjchem-1566	54	31	conditions	condition	NOUN
eurjchem-1566	54	32	for	for	ADP
eurjchem-1566	54	33	a	a	DET
eurjchem-1566	54	34	study	study	NOUN
eurjchem-1566	54	35	of	of	ADP
eurjchem-1566	54	36	its	its	PRON
eurjchem-1566	54	37	solvolysis	solvolysis	NOUN
eurjchem-1566	54	38	reactions	reaction	NOUN
eurjchem-1566	54	39	.	.	PUNCT
eurjchem-1566	55	1	in	in	ADP
eurjchem-1566	55	2	table	table	NOUN
eurjchem-1566	55	3	2	2	NUM
eurjchem-1566	55	4	,	,	PUNCT
eurjchem-1566	55	5	the	the	DET
eurjchem-1566	55	6	specific	specific	ADJ
eurjchem-1566	55	7	rates	rate	NOUN
eurjchem-1566	55	8	(	(	PUNCT
eurjchem-1566	55	9	first‐order	first‐order	NOUN
eurjchem-1566	55	10	rate	rate	NOUN
eurjchem-1566	55	11	coefficients	coefficient	NOUN
eurjchem-1566	55	12	)	)	PUNCT
eurjchem-1566	55	13	are	be	AUX
eurjchem-1566	55	14	presented	present	VERB
eurjchem-1566	55	15	for	for	ADP
eurjchem-1566	55	16	the	the	DET
eurjchem-1566	55	17	solvolysis	solvolysis	NOUN
eurjchem-1566	55	18	of	of	ADP
eurjchem-1566	55	19	2.0×10‐4	2.0×10‐4	NUM
eurjchem-1566	55	20	mol	mol	ADP
eurjchem-1566	55	21	/	/	SYM
eurjchem-1566	55	22	dm	dm	PROPN
eurjchem-1566	55	23	2	2	NUM
eurjchem-1566	55	24	,	,	PUNCT
eurjchem-1566	55	25	in	in	ADP
eurjchem-1566	55	26	the	the	DET
eurjchem-1566	55	27	presence	presence	NOUN
eurjchem-1566	55	28	of	of	ADP
eurjchem-1566	55	29	6.0×10‐4	6.0×10‐4	NUM
eurjchem-1566	55	30	mol	mol	PROPN
eurjchem-1566	55	31	/	/	SYM
eurjchem-1566	55	32	dm	dm	PROPN
eurjchem-1566	55	33	triethylamine	triethylamine	NOUN
eurjchem-1566	55	34	,	,	PUNCT
eurjchem-1566	55	35	in	in	ADP
eurjchem-1566	55	36	100	100	NUM
eurjchem-1566	55	37	%	%	NOUN
eurjchem-1566	55	38	h20	h20	NOUN
eurjchem-1566	55	39	and	and	CCONJ
eurjchem-1566	55	40	in	in	ADP
eurjchem-1566	55	41	thirty‐two	thirty‐two	NOUN
eurjchem-1566	55	42	aqueous‐organic	aqueous‐organic	ADJ
eurjchem-1566	55	43	solvents	solvent	NOUN
eurjchem-1566	55	44	,	,	PUNCT
eurjchem-1566	55	45	all	all	PRON
eurjchem-1566	55	46	of	of	ADP
eurjchem-1566	55	47	which	which	PRON
eurjchem-1566	55	48	have	have	AUX
eurjchem-1566	55	49	tabulated	tabulate	VERB
eurjchem-1566	55	50	values	value	NOUN
eurjchem-1566	55	51	for	for	ADP
eurjchem-1566	55	52	both	both	PRON
eurjchem-1566	55	53	nt	not	PART
eurjchem-1566	55	54	and	and	CCONJ
eurjchem-1566	55	55	ybr	ybr	PROPN
eurjchem-1566	55	56	available	available	ADJ
eurjchem-1566	55	57	.	.	PUNCT
eurjchem-1566	56	1	these	these	DET
eurjchem-1566	56	2	known	know	VERB
eurjchem-1566	56	3	nt	not	PART
eurjchem-1566	56	4	and	and	CCONJ
eurjchem-1566	56	5	ybr	ybr	PROPN
eurjchem-1566	56	6	values	value	NOUN
eurjchem-1566	56	7	are	be	AUX
eurjchem-1566	56	8	also	also	ADV
eurjchem-1566	56	9	tabulated	tabulate	VERB
eurjchem-1566	56	10	in	in	ADP
eurjchem-1566	56	11	table	table	NOUN
eurjchem-1566	56	12	2	2	NUM
eurjchem-1566	56	13	,	,	PUNCT
eurjchem-1566	56	14	and	and	CCONJ
eurjchem-1566	56	15	their	their	PRON
eurjchem-1566	56	16	sources	source	NOUN
eurjchem-1566	56	17	indicated	indicate	VERB
eurjchem-1566	56	18	as	as	ADP
eurjchem-1566	56	19	footnotes	footnote	NOUN
eurjchem-1566	56	20	.	.	PUNCT
eurjchem-1566	57	1	when	when	SCONJ
eurjchem-1566	57	2	the	the	DET
eurjchem-1566	57	3	original	original	ADJ
eurjchem-1566	57	4	(	(	PUNCT
eurjchem-1566	57	5	one‐term	one‐term	NOUN
eurjchem-1566	57	6	)	)	PUNCT
eurjchem-1566	57	7	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	57	8	equation	equation	NOUN
eurjchem-1566	57	9	[	[	X
eurjchem-1566	57	10	4,18	4,18	X
eurjchem-1566	57	11	]	]	X
eurjchem-1566	58	1	[	[	X
eurjchem-1566	58	2	equation	equation	NOUN
eurjchem-1566	58	3	(	(	PUNCT
eurjchem-1566	58	4	1	1	NUM
eurjchem-1566	58	5	)	)	PUNCT
eurjchem-1566	58	6	without	without	ADP
eurjchem-1566	58	7	the	the	DET
eurjchem-1566	58	8	l	l	NOUN
eurjchem-1566	58	9	nt	not	PART
eurjchem-1566	58	10	term	term	NOUN
eurjchem-1566	58	11	]	]	PUNCT
eurjchem-1566	58	12	is	be	AUX
eurjchem-1566	58	13	applied	apply	VERB
eurjchem-1566	58	14	to	to	ADP
eurjchem-1566	58	15	the	the	DET
eurjchem-1566	58	16	data	datum	NOUN
eurjchem-1566	58	17	of	of	ADP
eurjchem-1566	58	18	table	table	NOUN
eurjchem-1566	58	19	2	2	NUM
eurjchem-1566	58	20	,	,	PUNCT
eurjchem-1566	58	21	it	it	PRON
eurjchem-1566	58	22	is	be	AUX
eurjchem-1566	58	23	found	find	VERB
eurjchem-1566	58	24	that	that	SCONJ
eurjchem-1566	58	25	the	the	DET
eurjchem-1566	58	26	specific	specific	ADJ
eurjchem-1566	58	27	rates	rate	NOUN
eurjchem-1566	58	28	of	of	ADP
eurjchem-1566	58	29	solvolysis	solvolysis	NOUN
eurjchem-1566	58	30	in	in	ADP
eurjchem-1566	58	31	the	the	DET
eurjchem-1566	58	32	29	29	NUM
eurjchem-1566	58	33	solvents	solvent	NOUN
eurjchem-1566	58	34	not	not	PART
eurjchem-1566	58	35	containing	contain	VERB
eurjchem-1566	58	36	a	a	DET
eurjchem-1566	58	37	2,2,2‐trifluoro	2,2,2‐trifluoro	NUM
eurjchem-1566	58	38	fluoroethanol	fluoroethanol	NOUN
eurjchem-1566	58	39	(	(	PUNCT
eurjchem-1566	58	40	tfe)‐component	tfe)‐component	VERB
eurjchem-1566	58	41	give	give	VERB
eurjchem-1566	58	42	a	a	DET
eurjchem-1566	58	43	linear	linear	ADJ
eurjchem-1566	58	44	plot	plot	NOUN
eurjchem-1566	58	45	(	(	PUNCT
eurjchem-1566	58	46	figure	figure	NOUN
eurjchem-1566	58	47	1	1	NUM
eurjchem-1566	58	48	)	)	PUNCT
eurjchem-1566	58	49	and	and	CCONJ
eurjchem-1566	58	50	correlation	correlation	NOUN
eurjchem-1566	58	51	analysis	analysis	NOUN
eurjchem-1566	58	52	leads	lead	VERB
eurjchem-1566	58	53	to	to	ADP
eurjchem-1566	58	54	equation	equation	NOUN
eurjchem-1566	58	55	(	(	PUNCT
eurjchem-1566	58	56	5	5	NUM
eurjchem-1566	58	57	)	)	PUNCT
eurjchem-1566	58	58	.	.	PUNCT
eurjchem-1566	59	1	log	log	NOUN
eurjchem-1566	59	2	(	(	PUNCT
eurjchem-1566	59	3	k	k	NOUN
eurjchem-1566	59	4	/	/	SYM
eurjchem-1566	59	5	ko)2	ko)2	PROPN
eurjchem-1566	59	6	=	=	SYM
eurjchem-1566	59	7	(	(	PUNCT
eurjchem-1566	59	8	0.46	0.46	NUM
eurjchem-1566	59	9	±	±	NUM
eurjchem-1566	59	10	0.02	0.02	NUM
eurjchem-1566	59	11	)	)	PUNCT
eurjchem-1566	59	12	ybr	ybr	PROPN
eurjchem-1566	59	13	–	–	PUNCT
eurjchem-1566	59	14	(	(	PUNCT
eurjchem-1566	59	15	0.02	0.02	NUM
eurjchem-1566	59	16	±	±	NUM
eurjchem-1566	59	17	0.04	0.04	NUM
eurjchem-1566	59	18	)	)	PUNCT
eurjchem-1566	59	19	(	(	PUNCT
eurjchem-1566	59	20	5	5	NUM
eurjchem-1566	59	21	)	)	PUNCT
eurjchem-1566	59	22	n	n	NOUN
eurjchem-1566	59	23	=	=	SYM
eurjchem-1566	59	24	29	29	NUM
eurjchem-1566	59	25	;	;	PUNCT
eurjchem-1566	59	26	correlation	correlation	NOUN
eurjchem-1566	59	27	coefficient	coefficient	NOUN
eurjchem-1566	59	28	(	(	PUNCT
eurjchem-1566	59	29	r	r	NOUN
eurjchem-1566	59	30	)	)	PUNCT
eurjchem-1566	59	31	of	of	ADP
eurjchem-1566	59	32	0.987	0.987	NUM
eurjchem-1566	59	33	;	;	PUNCT
eurjchem-1566	59	34	f‐test	f‐test	PUNCT
eurjchem-1566	59	35	value	value	NOUN
eurjchem-1566	59	36	of	of	ADP
eurjchem-1566	59	37	967	967	NUM
eurjchem-1566	59	38	.	.	PUNCT
eurjchem-1566	60	1	164	164	NUM
eurjchem-1566	60	2	kevill	kevill	NOUN
eurjchem-1566	60	3	et	et	PROPN
eurjchem-1566	60	4	al	al	PROPN
eurjchem-1566	60	5	.	.	PUNCT
eurjchem-1566	60	6	/	/	SYM
eurjchem-1566	60	7	european	european	PROPN
eurjchem-1566	60	8	journal	journal	PROPN
eurjchem-1566	60	9	of	of	ADP
eurjchem-1566	60	10	chemistry	chemistry	NOUN
eurjchem-1566	60	11	8	8	NUM
eurjchem-1566	60	12	(	(	PUNCT
eurjchem-1566	60	13	2	2	NUM
eurjchem-1566	60	14	)	)	PUNCT
eurjchem-1566	60	15	(	(	PUNCT
eurjchem-1566	60	16	2017	2017	NUM
eurjchem-1566	60	17	)	)	PUNCT
eurjchem-1566	60	18	162‐167	162‐167	NUM
eurjchem-1566	60	19	table	table	NOUN
eurjchem-1566	60	20	2	2	NUM
eurjchem-1566	60	21	.	.	X
eurjchem-1566	60	22	first‐order	first‐order	NOUN
eurjchem-1566	60	23	rate	rate	NOUN
eurjchem-1566	60	24	coefficients	coefficient	NOUN
eurjchem-1566	60	25	for	for	ADP
eurjchem-1566	60	26	the	the	DET
eurjchem-1566	60	27	solvolyses	solvolyse	NOUN
eurjchem-1566	60	28	of	of	ADP
eurjchem-1566	60	29	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	60	30	at	at	ADP
eurjchem-1566	60	31	55.0	55.0	NUM
eurjchem-1566	60	32	°	°	NOUN
eurjchem-1566	60	33	c	c	NOUN
eurjchem-1566	60	34	a	a	PRON
eurjchem-1566	60	35	and	and	CCONJ
eurjchem-1566	60	36	the	the	DET
eurjchem-1566	60	37	appropriate	appropriate	ADJ
eurjchem-1566	60	38	solvent	solvent	NOUN
eurjchem-1566	60	39	nucleophilicity	nucleophilicity	NOUN
eurjchem-1566	60	40	(	(	PUNCT
eurjchem-1566	60	41	nt	not	PART
eurjchem-1566	60	42	)	)	PUNCT
eurjchem-1566	60	43	and	and	CCONJ
eurjchem-1566	60	44	solvent	solvent	ADJ
eurjchem-1566	60	45	ionizing	ionizing	NOUN
eurjchem-1566	60	46	power	power	NOUN
eurjchem-1566	60	47	(	(	PUNCT
eurjchem-1566	60	48	ybr	ybr	PROPN
eurjchem-1566	60	49	)	)	PUNCT
eurjchem-1566	60	50	values	value	NOUN
eurjchem-1566	60	51	.	.	PUNCT
eurjchem-1566	61	1	solvent	solvent	NOUN
eurjchem-1566	61	2	b	b	NOUN
eurjchem-1566	61	3	104	104	NUM
eurjchem-1566	61	4	k	k	NOUN
eurjchem-1566	61	5	/	/	SYM
eurjchem-1566	61	6	s‐1	s‐1	VERB
eurjchem-1566	61	7	c	c	NOUN
eurjchem-1566	62	1	nt	not	PART
eurjchem-1566	62	2	d	d	X
eurjchem-1566	62	3	ybr	ybr	NOUN
eurjchem-1566	62	4	e	e	PROPN
eurjchem-1566	62	5	90	90	NUM
eurjchem-1566	62	6	%	%	NOUN
eurjchem-1566	62	7	etoh	etoh	NOUN
eurjchem-1566	62	8	0.72±0.01	0.72±0.01	VERB
eurjchem-1566	62	9	0.16	0.16	NUM
eurjchem-1566	62	10	‐0.84	‐0.84	NUM
eurjchem-1566	62	11	80	80	NUM
eurjchem-1566	62	12	%	%	NOUN
eurjchem-1566	62	13	etoh	etoh	NOUN
eurjchem-1566	62	14	0.99±0.02	0.99±0.02	NOUN
eurjchem-1566	62	15	0.00	0.00	NUM
eurjchem-1566	62	16	f	f	NOUN
eurjchem-1566	62	17	0.00	0.00	NUM
eurjchem-1566	62	18	f	f	NUM
eurjchem-1566	62	19	70	70	NUM
eurjchem-1566	62	20	%	%	NOUN
eurjchem-1566	62	21	etoh	etoh	PROPN
eurjchem-1566	62	22	1.72±0.02	1.72±0.02	PROPN
eurjchem-1566	62	23	‐0.20	‐0.20	NUM
eurjchem-1566	62	24	0.68	0.68	NUM
eurjchem-1566	62	25	60	60	NUM
eurjchem-1566	62	26	%	%	NOUN
eurjchem-1566	62	27	etoh	etoh	NOUN
eurjchem-1566	62	28	4.40±0.04	4.40±0.04	NOUN
eurjchem-1566	62	29	‐0.38	‐0.38	NUM
eurjchem-1566	62	30	1.26	1.26	NUM
eurjchem-1566	62	31	50	50	NUM
eurjchem-1566	62	32	%	%	NOUN
eurjchem-1566	62	33	etoh	etoh	PROPN
eurjchem-1566	62	34	8.98±0.11	8.98±0.11	PROPN
eurjchem-1566	62	35	‐0.58	‐0.58	NUM
eurjchem-1566	62	36	1.88	1.88	NUM
eurjchem-1566	62	37	40	40	NUM
eurjchem-1566	62	38	%	%	NOUN
eurjchem-1566	62	39	etoh	etoh	NOUN
eurjchem-1566	62	40	16.7±0.3	16.7±0.3	NUM
eurjchem-1566	62	41	‐0.74	‐0.74	NUM
eurjchem-1566	62	42	2.62	2.62	NUM
eurjchem-1566	62	43	30	30	NUM
eurjchem-1566	62	44	%	%	NOUN
eurjchem-1566	62	45	etoh	etoh	NOUN
eurjchem-1566	62	46	29.3±0.5	29.3±0.5	NUM
eurjchem-1566	62	47	g	g	NOUN
eurjchem-1566	62	48	‐0.93	‐0.93	NOUN
eurjchem-1566	62	49	3.40	3.40	NUM
eurjchem-1566	62	50	20	20	NUM
eurjchem-1566	62	51	%	%	NOUN
eurjchem-1566	62	52	etoh	etoh	NOUN
eurjchem-1566	62	53	54.9±0.6	54.9±0.6	NUM
eurjchem-1566	62	54	g	g	NOUN
eurjchem-1566	62	55	‐1.16	‐1.16	PROPN
eurjchem-1566	62	56	3.92	3.92	NUM
eurjchem-1566	62	57	10	10	NUM
eurjchem-1566	62	58	%	%	NOUN
eurjchem-1566	62	59	etoh	etoh	NOUN
eurjchem-1566	62	60	82.9±0.6	82.9±0.6	NUM
eurjchem-1566	62	61	‐1.31	‐1.31	NOUN
eurjchem-1566	62	62	4.17	4.17	NUM
eurjchem-1566	62	63	100	100	NUM
eurjchem-1566	62	64	%	%	NOUN
eurjchem-1566	62	65	h2o	h2o	PROPN
eurjchem-1566	62	66	181±7	181±7	NUM
eurjchem-1566	62	67	h	h	NOUN
eurjchem-1566	62	68	‐1.38	‐1.38	NOUN
eurjchem-1566	62	69	4.44	4.44	NUM
eurjchem-1566	62	70	90	90	NUM
eurjchem-1566	62	71	%	%	NOUN
eurjchem-1566	62	72	meoh	meoh	NOUN
eurjchem-1566	62	73	0.53±0.01	0.53±0.01	ADJ
eurjchem-1566	62	74	‐0.01	‐0.01	ADV
eurjchem-1566	62	75	‐0.14	‐0.14	DET
eurjchem-1566	62	76	80	80	NUM
eurjchem-1566	62	77	%	%	NOUN
eurjchem-1566	62	78	meoh	meoh	NOUN
eurjchem-1566	62	79	1.32±0.02	1.32±0.02	NUM
eurjchem-1566	62	80	‐0.06	‐0.06	NOUN
eurjchem-1566	62	81	0.70	0.70	NUM
eurjchem-1566	62	82	70	70	NUM
eurjchem-1566	62	83	%	%	NOUN
eurjchem-1566	62	84	meoh	meoh	NOUN
eurjchem-1566	62	85	3.30±0.04	3.30±0.04	NOUN
eurjchem-1566	62	86	‐0.40	‐0.40	NOUN
eurjchem-1566	62	87	1.42	1.42	NUM
eurjchem-1566	62	88	60	60	NUM
eurjchem-1566	62	89	%	%	NOUN
eurjchem-1566	62	90	meoh	meoh	NOUN
eurjchem-1566	63	1	6.62±0.13	6.62±0.13	NUM
eurjchem-1566	63	2	‐0.54	‐0.54	PROPN
eurjchem-1566	63	3	2.04	2.04	NUM
eurjchem-1566	63	4	50	50	NUM
eurjchem-1566	63	5	%	%	NOUN
eurjchem-1566	63	6	meoh	meoh	NOUN
eurjchem-1566	63	7	11.7±0.2	11.7±0.2	NUM
eurjchem-1566	63	8	‐0.57	‐0.57	NOUN
eurjchem-1566	63	9	2.61	2.61	NUM
eurjchem-1566	63	10	40	40	NUM
eurjchem-1566	63	11	%	%	NOUN
eurjchem-1566	63	12	meoh	meoh	NOUN
eurjchem-1566	63	13	25.2±0.5	25.2±0.5	NUM
eurjchem-1566	63	14	g	g	NOUN
eurjchem-1566	63	15	‐0.87	‐0.87	ADV
eurjchem-1566	63	16	3.14	3.14	NUM
eurjchem-1566	63	17	30	30	NUM
eurjchem-1566	63	18	%	%	NOUN
eurjchem-1566	63	19	meoh	meoh	NOUN
eurjchem-1566	63	20	32.7±0.7	32.7±0.7	NUM
eurjchem-1566	63	21	h	h	NOUN
eurjchem-1566	63	22	‐1.06	‐1.06	NOUN
eurjchem-1566	63	23	3.61	3.61	NUM
eurjchem-1566	63	24	20	20	NUM
eurjchem-1566	63	25	%	%	NOUN
eurjchem-1566	63	26	meoh	meoh	NOUN
eurjchem-1566	63	27	53.3±0.6	53.3±0.6	NUM
eurjchem-1566	63	28	g	g	NOUN
eurjchem-1566	63	29	‐1.23	‐1.23	PROPN
eurjchem-1566	63	30	3.94	3.94	NUM
eurjchem-1566	63	31	10	10	NUM
eurjchem-1566	63	32	%	%	NOUN
eurjchem-1566	63	33	meoh	meoh	NOUN
eurjchem-1566	63	34	90.1±1.5	90.1±1.5	NUM
eurjchem-1566	63	35	g	g	NOUN
eurjchem-1566	63	36	‐1.36	‐1.36	ADV
eurjchem-1566	63	37	4.17	4.17	NUM
eurjchem-1566	63	38	70	70	NUM
eurjchem-1566	63	39	%	%	NOUN
eurjchem-1566	63	40	acetone	acetone	NOUN
eurjchem-1566	63	41	1.88±0.01	1.88±0.01	PROPN
eurjchem-1566	63	42	‐0.42	‐0.42	ADV
eurjchem-1566	63	43	0.20	0.20	NUM
eurjchem-1566	63	44	60	60	NUM
eurjchem-1566	63	45	%	%	NOUN
eurjchem-1566	63	46	acetone	acetone	NOUN
eurjchem-1566	63	47	3.64±0.02	3.64±0.02	NUM
eurjchem-1566	63	48	‐0.52	‐0.52	NUM
eurjchem-1566	63	49	1.20	1.20	NUM
eurjchem-1566	63	50	50	50	NUM
eurjchem-1566	63	51	%	%	NOUN
eurjchem-1566	63	52	acetone	acetone	NOUN
eurjchem-1566	63	53	9.50±0.08	9.50±0.08	NOUN
eurjchem-1566	63	54	‐0.70	‐0.70	NUM
eurjchem-1566	63	55	1.82	1.82	NUM
eurjchem-1566	63	56	40	40	NUM
eurjchem-1566	63	57	%	%	NOUN
eurjchem-1566	63	58	acetone	acetone	NOUN
eurjchem-1566	63	59	22.6±0.8	22.6±0.8	NUM
eurjchem-1566	63	60	‐0.83	‐0.83	ADJ
eurjchem-1566	63	61	2.43	2.43	NUM
eurjchem-1566	63	62	30	30	NUM
eurjchem-1566	63	63	%	%	NOUN
eurjchem-1566	63	64	acetone	acetone	NOUN
eurjchem-1566	63	65	31.4±0.2	31.4±0.2	NUM
eurjchem-1566	63	66	‐0.96	‐0.96	NUM
eurjchem-1566	63	67	2.99	2.99	NUM
eurjchem-1566	63	68	20	20	NUM
eurjchem-1566	63	69	%	%	NOUN
eurjchem-1566	63	70	acetone	acetone	NOUN
eurjchem-1566	63	71	49.1±0.8	49.1±0.8	NUM
eurjchem-1566	63	72	‐1.11	‐1.11	DET
eurjchem-1566	63	73	3.66	3.66	NUM
eurjchem-1566	63	74	10	10	NUM
eurjchem-1566	63	75	%	%	NOUN
eurjchem-1566	63	76	acetone	acetone	NOUN
eurjchem-1566	63	77	85.1±0.7	85.1±0.7	NUM
eurjchem-1566	63	78	‐1.23	‐1.23	PROPN
eurjchem-1566	63	79	4.05	4.05	NUM
eurjchem-1566	63	80	80	80	NUM
eurjchem-1566	63	81	%	%	NOUN
eurjchem-1566	63	82	dioxane	dioxane	NOUN
eurjchem-1566	63	83	0.60±0.01	0.60±0.01	NOUN
eurjchem-1566	63	84	‐0.46	‐0.46	NOUN
eurjchem-1566	63	85	‐0.60	‐0.60	NUM
eurjchem-1566	63	86	70	70	NUM
eurjchem-1566	63	87	%	%	NOUN
eurjchem-1566	63	88	dioxane	dioxane	NOUN
eurjchem-1566	63	89	0.95±0.01	0.95±0.01	NOUN
eurjchem-1566	63	90	‐0.37	‐0.37	NUM
eurjchem-1566	63	91	‐0.01	‐0.01	ADV
eurjchem-1566	63	92	60	60	NUM
eurjchem-1566	63	93	%	%	NOUN
eurjchem-1566	63	94	dioxane	dioxane	NOUN
eurjchem-1566	63	95	2.68±0.06	2.68±0.06	NOUN
eurjchem-1566	63	96	‐0.54	‐0.54	PROPN
eurjchem-1566	63	97	0.82	0.82	NUM
eurjchem-1566	63	98	80	80	NUM
eurjchem-1566	63	99	%	%	NOUN
eurjchem-1566	63	100	tfe	tfe	NOUN
eurjchem-1566	63	101	1.08±0.08	1.08±0.08	PROPN
eurjchem-1566	63	102	‐2.19	‐2.19	X
eurjchem-1566	63	103	1.95	1.95	NUM
eurjchem-1566	63	104	70	70	NUM
eurjchem-1566	63	105	%	%	NOUN
eurjchem-1566	63	106	tfe	tfe	NOUN
eurjchem-1566	63	107	1.79±0.08	1.79±0.08	NUM
eurjchem-1566	63	108	g	g	PROPN
eurjchem-1566	63	109	‐1.98	‐1.98	NUM
eurjchem-1566	63	110	2.21	2.21	NUM
eurjchem-1566	63	111	60	60	NUM
eurjchem-1566	63	112	%	%	NOUN
eurjchem-1566	63	113	tfe	tfe	NOUN
eurjchem-1566	63	114	2.62±0.02	2.62±0.02	PROPN
eurjchem-1566	63	115	‐1.85	‐1.85	NUM
eurjchem-1566	63	116	2.53	2.53	NUM
eurjchem-1566	63	117	50	50	NUM
eurjchem-1566	63	118	%	%	NOUN
eurjchem-1566	63	119	tfe	tfe	NOUN
eurjchem-1566	63	120	4.23±0.05	4.23±0.05	NOUN
eurjchem-1566	63	121	‐1.73	‐1.73	NOUN
eurjchem-1566	63	122	2.97	2.97	NUM
eurjchem-1566	63	123	a	a	DET
eurjchem-1566	63	124	determined	determined	ADJ
eurjchem-1566	63	125	conductimetrically	conductimetrically	ADV
eurjchem-1566	63	126	after	after	ADP
eurjchem-1566	63	127	injecting	inject	VERB
eurjchem-1566	63	128	20	20	NUM
eurjchem-1566	63	129	l	l	NOUN
eurjchem-1566	63	130	of	of	ADP
eurjchem-1566	63	131	a	a	DET
eurjchem-1566	63	132	solution	solution	NOUN
eurjchem-1566	63	133	in	in	ADP
eurjchem-1566	63	134	acetonitrile	acetonitrile	NOUN
eurjchem-1566	63	135	that	that	PRON
eurjchem-1566	63	136	was	be	AUX
eurjchem-1566	63	137	2×10‐2	2×10‐2	ADJ
eurjchem-1566	63	138	mol	mol	ADP
eurjchem-1566	63	139	/	/	SYM
eurjchem-1566	63	140	dm3	dm3	NOUN
eurjchem-1566	63	141	in	in	ADP
eurjchem-1566	63	142	the	the	DET
eurjchem-1566	63	143	hydrobromide	hydrobromide	NOUN
eurjchem-1566	63	144	of	of	ADP
eurjchem-1566	63	145	the	the	DET
eurjchem-1566	63	146	substrate	substrate	NOUN
eurjchem-1566	63	147	and	and	CCONJ
eurjchem-1566	63	148	6×10‐2	6×10‐2	ADJ
eurjchem-1566	63	149	mol	mol	PROPN
eurjchem-1566	63	150	/	/	SYM
eurjchem-1566	63	151	dm3	dm3	NOUN
eurjchem-1566	63	152	in	in	ADP
eurjchem-1566	63	153	triethylamine	triethylamine	NOUN
eurjchem-1566	63	154	into	into	ADP
eurjchem-1566	63	155	2.0	2.0	NUM
eurjchem-1566	63	156	ml	ml	NOUN
eurjchem-1566	63	157	of	of	ADP
eurjchem-1566	63	158	the	the	DET
eurjchem-1566	63	159	indicated	indicate	VERB
eurjchem-1566	63	160	solvent	solvent	NOUN
eurjchem-1566	63	161	maintained	maintain	VERB
eurjchem-1566	63	162	at	at	ADP
eurjchem-1566	63	163	55.0	55.0	NUM
eurjchem-1566	63	164	°	°	NOUN
eurjchem-1566	63	165	c	c	NOUN
eurjchem-1566	63	166	,	,	PUNCT
eurjchem-1566	63	167	to	to	PART
eurjchem-1566	63	168	give	give	VERB
eurjchem-1566	63	169	an	an	DET
eurjchem-1566	63	170	initial	initial	ADJ
eurjchem-1566	63	171	substrate	substrate	NOUN
eurjchem-1566	63	172	concentration	concentration	NOUN
eurjchem-1566	63	173	of	of	ADP
eurjchem-1566	63	174	2.0×10‐4	2.0×10‐4	NUM
eurjchem-1566	63	175	mol	mol	ADP
eurjchem-1566	63	176	/	/	SYM
eurjchem-1566	63	177	dm3	dm3	NOUN
eurjchem-1566	63	178	in	in	ADP
eurjchem-1566	63	179	the	the	DET
eurjchem-1566	63	180	presence	presence	NOUN
eurjchem-1566	63	181	of	of	ADP
eurjchem-1566	63	182	4.0×10‐4	4.0×10‐4	PROPN
eurjchem-1566	63	183	mol	mol	PROPN
eurjchem-1566	63	184	/	/	SYM
eurjchem-1566	63	185	dm3	dm3	NOUN
eurjchem-1566	63	186	of	of	ADP
eurjchem-1566	63	187	triethylamine	triethylamine	NOUN
eurjchem-1566	63	188	.	.	PUNCT
eurjchem-1566	64	1	b	b	X
eurjchem-1566	64	2	binary	binary	ADJ
eurjchem-1566	64	3	solvents	solvent	NOUN
eurjchem-1566	64	4	on	on	ADP
eurjchem-1566	64	5	a	a	DET
eurjchem-1566	64	6	volume‐volume	volume‐volume	NOUN
eurjchem-1566	64	7	basis	basis	NOUN
eurjchem-1566	64	8	at	at	ADP
eurjchem-1566	64	9	25.0	25.0	NUM
eurjchem-1566	64	10	°	°	NOUN
eurjchem-1566	64	11	c	c	NOUN
eurjchem-1566	64	12	,	,	PUNCT
eurjchem-1566	64	13	except	except	SCONJ
eurjchem-1566	64	14	for	for	ADP
eurjchem-1566	64	15	the	the	DET
eurjchem-1566	64	16	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	64	17	mixtures	mixture	NOUN
eurjchem-1566	64	18	,	,	PUNCT
eurjchem-1566	64	19	which	which	PRON
eurjchem-1566	64	20	are	be	AUX
eurjchem-1566	64	21	on	on	ADP
eurjchem-1566	64	22	a	a	DET
eurjchem-1566	64	23	weight‐weight	weight‐weight	ADJ
eurjchem-1566	64	24	basis	basis	NOUN
eurjchem-1566	64	25	.	.	PUNCT
eurjchem-1566	65	1	the	the	DET
eurjchem-1566	65	2	second	second	ADJ
eurjchem-1566	65	3	component	component	NOUN
eurjchem-1566	65	4	in	in	ADP
eurjchem-1566	65	5	addition	addition	NOUN
eurjchem-1566	65	6	to	to	ADP
eurjchem-1566	65	7	that	that	PRON
eurjchem-1566	65	8	indicated	indicate	VERB
eurjchem-1566	65	9	,	,	PUNCT
eurjchem-1566	65	10	is	be	AUX
eurjchem-1566	65	11	water	water	NOUN
eurjchem-1566	65	12	.	.	PUNCT
eurjchem-1566	66	1	c	c	NOUN
eurjchem-1566	66	2	with	with	ADP
eurjchem-1566	66	3	standard	standard	ADJ
eurjchem-1566	66	4	deviations	deviation	NOUN
eurjchem-1566	66	5	and	and	CCONJ
eurjchem-1566	66	6	,	,	PUNCT
eurjchem-1566	66	7	unless	unless	SCONJ
eurjchem-1566	66	8	otherwise	otherwise	ADV
eurjchem-1566	66	9	indicated	indicate	VERB
eurjchem-1566	66	10	,	,	PUNCT
eurjchem-1566	66	11	the	the	DET
eurjchem-1566	66	12	average	average	NOUN
eurjchem-1566	66	13	of	of	ADP
eurjchem-1566	66	14	duplicate	duplicate	ADJ
eurjchem-1566	66	15	determinations	determination	NOUN
eurjchem-1566	66	16	.	.	PUNCT
eurjchem-1566	67	1	d	d	PRON
eurjchem-1566	67	2	values	value	NOUN
eurjchem-1566	67	3	from	from	ADP
eurjchem-1566	67	4	refs	ref	NOUN
eurjchem-1566	67	5	.	.	PUNCT
eurjchem-1566	68	1	[	[	X
eurjchem-1566	68	2	5	5	NUM
eurjchem-1566	68	3	]	]	PUNCT
eurjchem-1566	68	4	and	and	CCONJ
eurjchem-1566	68	5	[	[	X
eurjchem-1566	68	6	20	20	NUM
eurjchem-1566	68	7	]	]	PUNCT
eurjchem-1566	68	8	.	.	PUNCT
eurjchem-1566	69	1	e	e	NOUN
eurjchem-1566	69	2	values	value	NOUN
eurjchem-1566	69	3	from	from	ADP
eurjchem-1566	69	4	refs	ref	NOUN
eurjchem-1566	69	5	.	.	PUNCT
eurjchem-1566	70	1	[	[	X
eurjchem-1566	70	2	4	4	X
eurjchem-1566	70	3	]	]	PUNCT
eurjchem-1566	70	4	and	and	CCONJ
eurjchem-1566	70	5	[	[	X
eurjchem-1566	70	6	15	15	NUM
eurjchem-1566	70	7	]	]	PUNCT
eurjchem-1566	70	8	.	.	PUNCT
eurjchem-1566	71	1	f	f	PROPN
eurjchem-1566	71	2	by	by	ADP
eurjchem-1566	71	3	definition	definition	NOUN
eurjchem-1566	71	4	.	.	PUNCT
eurjchem-1566	72	1	g	g	PROPN
eurjchem-1566	72	2	average	average	NOUN
eurjchem-1566	72	3	of	of	ADP
eurjchem-1566	72	4	four	four	NUM
eurjchem-1566	72	5	determinations	determination	NOUN
eurjchem-1566	72	6	.	.	PUNCT
eurjchem-1566	73	1	h	h	PROPN
eurjchem-1566	73	2	average	average	NOUN
eurjchem-1566	73	3	of	of	ADP
eurjchem-1566	73	4	six	six	NUM
eurjchem-1566	73	5	determinations	determination	NOUN
eurjchem-1566	73	6	.	.	PUNCT
eurjchem-1566	74	1	-0.5	-0.5	X
eurjchem-1566	74	2	0.0	0.0	NUM
eurjchem-1566	74	3	0.5	0.5	NUM
eurjchem-1566	74	4	1.0	1.0	NUM
eurjchem-1566	74	5	1.5	1.5	NUM
eurjchem-1566	74	6	2.0	2.0	NUM
eurjchem-1566	74	7	2.5	2.5	NUM
eurjchem-1566	74	8	3.0	3.0	NUM
eurjchem-1566	74	9	-1	-1	SYM
eurjchem-1566	74	10	0	0	NUM
eurjchem-1566	74	11	1	1	NUM
eurjchem-1566	74	12	2	2	NUM
eurjchem-1566	74	13	3	3	NUM
eurjchem-1566	74	14	4	4	NUM
eurjchem-1566	74	15	5	5	NUM
eurjchem-1566	74	16	lo	lo	NOUN
eurjchem-1566	74	17	g	g	PROPN
eurjchem-1566	74	18	(	(	PUNCT
eurjchem-1566	74	19	k	k	X
eurjchem-1566	74	20	/k	/k	PROPN
eurjchem-1566	74	21	o	o	NOUN
eurjchem-1566	74	22	)	)	PUNCT
eurjchem-1566	74	23	ybr	ybr	PROPN
eurjchem-1566	74	24	etoh	etoh	PROPN
eurjchem-1566	74	25	(	(	PUNCT
eurjchem-1566	74	26	aq	aq	NOUN
eurjchem-1566	74	27	)	)	PUNCT
eurjchem-1566	74	28	meoh	meoh	NOUN
eurjchem-1566	74	29	(	(	PUNCT
eurjchem-1566	74	30	aq	aq	NOUN
eurjchem-1566	74	31	)	)	PUNCT
eurjchem-1566	74	32	acetone	acetone	NOUN
eurjchem-1566	74	33	(	(	PUNCT
eurjchem-1566	74	34	aq	aq	NOUN
eurjchem-1566	74	35	)	)	PUNCT
eurjchem-1566	74	36	dioxane	dioxane	NOUN
eurjchem-1566	74	37	(	(	PUNCT
eurjchem-1566	74	38	aq	aq	NOUN
eurjchem-1566	74	39	)	)	PUNCT
eurjchem-1566	74	40	tfe	tfe	NOUN
eurjchem-1566	74	41	(	(	PUNCT
eurjchem-1566	74	42	aq	aq	NOUN
eurjchem-1566	74	43	)	)	PUNCT
eurjchem-1566	74	44	100	100	NUM
eurjchem-1566	74	45	%	%	NOUN
eurjchem-1566	74	46	water	water	NOUN
eurjchem-1566	74	47	figure	figure	NOUN
eurjchem-1566	74	48	1	1	NUM
eurjchem-1566	74	49	.	.	PUNCT
eurjchem-1566	74	50	plot	plot	NOUN
eurjchem-1566	74	51	of	of	ADP
eurjchem-1566	74	52	log	log	NOUN
eurjchem-1566	74	53	(	(	PUNCT
eurjchem-1566	74	54	k	k	NOUN
eurjchem-1566	74	55	/	/	SYM
eurjchem-1566	74	56	ko	ko	PROPN
eurjchem-1566	74	57	)	)	PUNCT
eurjchem-1566	74	58	for	for	ADP
eurjchem-1566	74	59	solvolyses	solvolyse	NOUN
eurjchem-1566	74	60	of	of	ADP
eurjchem-1566	74	61	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	74	62	(	(	PUNCT
eurjchem-1566	74	63	2	2	NUM
eurjchem-1566	74	64	)	)	PUNCT
eurjchem-1566	74	65	in	in	ADP
eurjchem-1566	74	66	29	29	NUM
eurjchem-1566	74	67	solvents	solvent	NOUN
eurjchem-1566	74	68	against	against	ADP
eurjchem-1566	74	69	ybr	ybr	PROPN
eurjchem-1566	74	70	values	value	NOUN
eurjchem-1566	74	71	(	(	PUNCT
eurjchem-1566	74	72	slope	slope	NOUN
eurjchem-1566	74	73	of	of	ADP
eurjchem-1566	74	74	0.46±0.02	0.46±0.02	PROPN
eurjchem-1566	74	75	)	)	PUNCT
eurjchem-1566	74	76	.	.	PUNCT
eurjchem-1566	75	1	the	the	DET
eurjchem-1566	75	2	four	four	NUM
eurjchem-1566	75	3	data	datum	NOUN
eurjchem-1566	75	4	points	point	NOUN
eurjchem-1566	75	5	for	for	ADP
eurjchem-1566	75	6	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	75	7	are	be	AUX
eurjchem-1566	75	8	not	not	PART
eurjchem-1566	75	9	included	include	VERB
eurjchem-1566	75	10	in	in	ADP
eurjchem-1566	75	11	the	the	DET
eurjchem-1566	75	12	correlation	correlation	NOUN
eurjchem-1566	75	13	but	but	CCONJ
eurjchem-1566	75	14	are	be	AUX
eurjchem-1566	75	15	added	add	VERB
eurjchem-1566	75	16	to	to	ADP
eurjchem-1566	75	17	the	the	DET
eurjchem-1566	75	18	plot	plot	NOUN
eurjchem-1566	75	19	to	to	PART
eurjchem-1566	75	20	show	show	VERB
eurjchem-1566	75	21	the	the	DET
eurjchem-1566	75	22	extent	extent	NOUN
eurjchem-1566	75	23	of	of	ADP
eurjchem-1566	75	24	their	their	PRON
eurjchem-1566	75	25	deviation	deviation	NOUN
eurjchem-1566	75	26	from	from	ADP
eurjchem-1566	75	27	the	the	DET
eurjchem-1566	75	28	regression	regression	NOUN
eurjchem-1566	75	29	line	line	NOUN
eurjchem-1566	75	30	.	.	PUNCT
eurjchem-1566	76	1	application	application	NOUN
eurjchem-1566	76	2	of	of	ADP
eurjchem-1566	76	3	the	the	DET
eurjchem-1566	76	4	two‐term	two‐term	NOUN
eurjchem-1566	76	5	equation	equation	NOUN
eurjchem-1566	76	6	[	[	X
eurjchem-1566	76	7	2,4,5,19,20	2,4,5,19,20	NUM
eurjchem-1566	76	8	]	]	X
eurjchem-1566	77	1	[	[	X
eurjchem-1566	77	2	equation	equation	NOUN
eurjchem-1566	77	3	(	(	PUNCT
eurjchem-1566	77	4	1	1	NUM
eurjchem-1566	77	5	)	)	PUNCT
eurjchem-1566	77	6	]	]	PUNCT
eurjchem-1566	77	7	to	to	ADP
eurjchem-1566	77	8	the	the	DET
eurjchem-1566	77	9	same	same	ADJ
eurjchem-1566	77	10	29	29	NUM
eurjchem-1566	77	11	solvents	solvent	NOUN
eurjchem-1566	77	12	leads	lead	VERB
eurjchem-1566	77	13	to	to	ADP
eurjchem-1566	77	14	equation	equation	NOUN
eurjchem-1566	77	15	(	(	PUNCT
eurjchem-1566	77	16	6	6	NUM
eurjchem-1566	77	17	)	)	PUNCT
eurjchem-1566	77	18	.	.	PUNCT
eurjchem-1566	78	1	log	log	NOUN
eurjchem-1566	78	2	(	(	PUNCT
eurjchem-1566	78	3	k	k	NOUN
eurjchem-1566	78	4	/	/	SYM
eurjchem-1566	78	5	ko	ko	PROPN
eurjchem-1566	78	6	)	)	PUNCT
eurjchem-1566	78	7	=	=	PUNCT
eurjchem-1566	79	1	(	(	PUNCT
eurjchem-1566	79	2	−0.38	−0.38	INTJ
eurjchem-1566	79	3	±	±	NUM
eurjchem-1566	79	4	0.14)nt	0.14)nt	NOUN
eurjchem-1566	79	5	+	+	CCONJ
eurjchem-1566	79	6	(	(	PUNCT
eurjchem-1566	79	7	0.36	0.36	NUM
eurjchem-1566	79	8	±	±	NUM
eurjchem-1566	79	9	0.04)ybr	0.04)ybr	NUM
eurjchem-1566	79	10	–	–	PUNCT
eurjchem-1566	79	11	(	(	PUNCT
eurjchem-1566	79	12	0.05	0.05	NUM
eurjchem-1566	79	13	±	±	NUM
eurjchem-1566	79	14	0.04	0.04	NUM
eurjchem-1566	79	15	)	)	PUNCT
eurjchem-1566	79	16	(	(	PUNCT
eurjchem-1566	79	17	6	6	NUM
eurjchem-1566	79	18	)	)	PUNCT
eurjchem-1566	79	19	n	n	NOUN
eurjchem-1566	79	20	=	=	SYM
eurjchem-1566	79	21	29	29	NUM
eurjchem-1566	79	22	;	;	PUNCT
eurjchem-1566	79	23	multiple	multiple	ADJ
eurjchem-1566	79	24	correlation	correlation	NOUN
eurjchem-1566	79	25	coefficient	coefficient	NOUN
eurjchem-1566	79	26	(	(	PUNCT
eurjchem-1566	79	27	r	r	NOUN
eurjchem-1566	79	28	)	)	PUNCT
eurjchem-1566	79	29	of	of	ADP
eurjchem-1566	79	30	0.989	0.989	NUM
eurjchem-1566	79	31	;	;	PUNCT
eurjchem-1566	79	32	f‐test	f‐test	PUNCT
eurjchem-1566	79	33	value	value	NOUN
eurjchem-1566	79	34	of	of	ADP
eurjchem-1566	79	35	600	600	NUM
eurjchem-1566	79	36	.	.	PUNCT
eurjchem-1566	80	1	the	the	DET
eurjchem-1566	80	2	negative	negative	ADJ
eurjchem-1566	80	3	l	l	NOUN
eurjchem-1566	80	4	values	value	NOUN
eurjchem-1566	80	5	in	in	ADP
eurjchem-1566	80	6	equation	equation	NOUN
eurjchem-1566	80	7	(	(	PUNCT
eurjchem-1566	80	8	6	6	NUM
eurjchem-1566	80	9	)	)	PUNCT
eurjchem-1566	80	10	almost	almost	ADV
eurjchem-1566	80	11	certainly	certainly	ADV
eurjchem-1566	80	12	result	result	VERB
eurjchem-1566	80	13	from	from	ADP
eurjchem-1566	80	14	the	the	DET
eurjchem-1566	80	15	29	29	NUM
eurjchem-1566	80	16	solvents	solvent	NOUN
eurjchem-1566	80	17	showing	show	VERB
eurjchem-1566	80	18	appreciable	appreciable	ADJ
eurjchem-1566	80	19	multicolli‐	multicolli‐	ADJ
eurjchem-1566	80	20	nearity	nearity	NOUN
eurjchem-1566	80	21	as	as	SCONJ
eurjchem-1566	80	22	regards	regard	VERB
eurjchem-1566	80	23	the	the	DET
eurjchem-1566	80	24	nt	not	PART
eurjchem-1566	80	25	and	and	CCONJ
eurjchem-1566	80	26	ybr	ybr	PROPN
eurjchem-1566	80	27	values	value	NOUN
eurjchem-1566	80	28	.	.	PUNCT
eurjchem-1566	81	1	moving	move	VERB
eurjchem-1566	81	2	from	from	ADP
eurjchem-1566	81	3	use	use	NOUN
eurjchem-1566	81	4	of	of	ADP
eurjchem-1566	81	5	the	the	DET
eurjchem-1566	81	6	one‐term	one‐term	NOUN
eurjchem-1566	81	7	to	to	ADP
eurjchem-1566	81	8	the	the	DET
eurjchem-1566	81	9	two‐term	two‐term	NOUN
eurjchem-1566	81	10	equation	equation	NOUN
eurjchem-1566	81	11	(	(	PUNCT
eurjchem-1566	81	12	equation	equation	NOUN
eurjchem-1566	81	13	(	(	PUNCT
eurjchem-1566	81	14	5	5	NUM
eurjchem-1566	81	15	)	)	PUNCT
eurjchem-1566	81	16	to	to	ADP
eurjchem-1566	81	17	equation	equation	NOUN
eurjchem-1566	81	18	(	(	PUNCT
eurjchem-1566	81	19	6	6	NUM
eurjchem-1566	81	20	)	)	PUNCT
eurjchem-1566	81	21	)	)	PUNCT
eurjchem-1566	81	22	leads	lead	VERB
eurjchem-1566	81	23	to	to	ADP
eurjchem-1566	81	24	only	only	ADV
eurjchem-1566	81	25	a	a	DET
eurjchem-1566	81	26	very	very	ADV
eurjchem-1566	81	27	modest	modest	ADJ
eurjchem-1566	81	28	increase	increase	NOUN
eurjchem-1566	81	29	in	in	ADP
eurjchem-1566	81	30	the	the	DET
eurjchem-1566	81	31	correlation	correlation	NOUN
eurjchem-1566	81	32	coefficient	coefficient	NOUN
eurjchem-1566	81	33	,	,	PUNCT
eurjchem-1566	81	34	coupled	couple	VERB
eurjchem-1566	81	35	with	with	ADP
eurjchem-1566	81	36	an	an	DET
eurjchem-1566	81	37	appreciable	appreciable	ADJ
eurjchem-1566	81	38	reduction	reduction	NOUN
eurjchem-1566	81	39	in	in	ADP
eurjchem-1566	81	40	the	the	DET
eurjchem-1566	81	41	m	m	NOUN
eurjchem-1566	81	42	value	value	NOUN
eurjchem-1566	81	43	and	and	CCONJ
eurjchem-1566	81	44	an	an	DET
eurjchem-1566	81	45	appreciably	appreciably	ADV
eurjchem-1566	81	46	negative	negative	ADJ
eurjchem-1566	81	47	l	l	NOUN
eurjchem-1566	81	48	value	value	NOUN
eurjchem-1566	81	49	.	.	PUNCT
eurjchem-1566	82	1	these	these	PRON
eurjchem-1566	82	2	are	be	AUX
eurjchem-1566	82	3	exactly	exactly	ADV
eurjchem-1566	82	4	the	the	DET
eurjchem-1566	82	5	effects	effect	NOUN
eurjchem-1566	82	6	to	to	PART
eurjchem-1566	82	7	be	be	AUX
eurjchem-1566	82	8	expected	expect	VERB
eurjchem-1566	82	9	from	from	ADP
eurjchem-1566	82	10	the	the	DET
eurjchem-1566	82	11	presence	presence	NOUN
eurjchem-1566	82	12	of	of	ADP
eurjchem-1566	82	13	an	an	DET
eurjchem-1566	82	14	appreciable	appreciable	ADJ
eurjchem-1566	82	15	degree	degree	NOUN
eurjchem-1566	82	16	of	of	ADP
eurjchem-1566	82	17	multicollinearity	multicollinearity	NOUN
eurjchem-1566	82	18	in	in	ADP
eurjchem-1566	82	19	the	the	DET
eurjchem-1566	82	20	absence	absence	NOUN
eurjchem-1566	82	21	of	of	ADP
eurjchem-1566	82	22	fluoroalcohol‐containing	fluoroalcohol‐containing	NOUN
eurjchem-1566	82	23	solvents	solvent	NOUN
eurjchem-1566	82	24	.	.	PUNCT
eurjchem-1566	83	1	kevill	kevill	AUX
eurjchem-1566	83	2	et	et	PROPN
eurjchem-1566	83	3	al	al	PROPN
eurjchem-1566	83	4	.	.	PUNCT
eurjchem-1566	83	5	/	/	SYM
eurjchem-1566	83	6	european	european	PROPN
eurjchem-1566	83	7	journal	journal	PROPN
eurjchem-1566	83	8	of	of	ADP
eurjchem-1566	83	9	chemistry	chemistry	NOUN
eurjchem-1566	83	10	8	8	NUM
eurjchem-1566	83	11	(	(	PUNCT
eurjchem-1566	83	12	2	2	NUM
eurjchem-1566	83	13	)	)	PUNCT
eurjchem-1566	83	14	(	(	PUNCT
eurjchem-1566	83	15	2017	2017	NUM
eurjchem-1566	83	16	)	)	PUNCT
eurjchem-1566	83	17	162‐167	162‐167	NUM
eurjchem-1566	83	18	165	165	NUM
eurjchem-1566	83	19	table	table	NOUN
eurjchem-1566	83	20	3	3	NUM
eurjchem-1566	83	21	.	.	PUNCT
eurjchem-1566	83	22	correlation	correlation	NOUN
eurjchem-1566	83	23	of	of	ADP
eurjchem-1566	83	24	the	the	DET
eurjchem-1566	83	25	specific	specific	ADJ
eurjchem-1566	83	26	rates	rate	NOUN
eurjchem-1566	83	27	of	of	ADP
eurjchem-1566	83	28	solvolyses	solvolyse	NOUN
eurjchem-1566	83	29	of	of	ADP
eurjchem-1566	83	30	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	83	31	(	(	PUNCT
eurjchem-1566	83	32	2	2	NUM
eurjchem-1566	83	33	)	)	PUNCT
eurjchem-1566	83	34	and	and	CCONJ
eurjchem-1566	83	35	other	other	ADJ
eurjchem-1566	83	36	compounds	compound	NOUN
eurjchem-1566	83	37	solvolyzing	solvolyze	VERB
eurjchem-1566	83	38	with	with	ADP
eurjchem-1566	83	39	an	an	DET
eurjchem-1566	83	40	internal	internal	ADJ
eurjchem-1566	83	41	nucleophilic	nucleophilic	ADJ
eurjchem-1566	83	42	assistance	assistance	NOUN
eurjchem-1566	83	43	,	,	PUNCT
eurjchem-1566	83	44	plus	plus	CCONJ
eurjchem-1566	83	45	cyclohexyl	cyclohexyl	PROPN
eurjchem-1566	83	46	tosylate	tosylate	VERB
eurjchem-1566	83	47	,	,	PUNCT
eurjchem-1566	83	48	against	against	ADP
eurjchem-1566	83	49	yx	yx	NOUN
eurjchem-1566	83	50	values	value	NOUN
eurjchem-1566	83	51	a	a	PRON
eurjchem-1566	83	52	and	and	CCONJ
eurjchem-1566	83	53	yx	yx	PROPN
eurjchem-1566	83	54	plus	plus	CCONJ
eurjchem-1566	83	55	nt	not	PART
eurjchem-1566	83	56	values	value	NOUN
eurjchem-1566	83	57	,	,	PUNCT
eurjchem-1566	83	58	using	use	VERB
eurjchem-1566	83	59	the	the	DET
eurjchem-1566	83	60	one‐and‐two‐term	one‐and‐two‐term	NOUN
eurjchem-1566	83	61	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	83	62	equations	equation	NOUN
eurjchem-1566	83	63	.	.	PUNCT
eurjchem-1566	84	1	b	b	X
eurjchem-1566	84	2	compound	compound	NOUN
eurjchem-1566	84	3	n	n	VERB
eurjchem-1566	84	4	c	c	NOUN
eurjchem-1566	84	5	l	l	NOUN
eurjchem-1566	85	1	d	d	NOUN
eurjchem-1566	85	2	,	,	PUNCT
eurjchem-1566	85	3	e	e	PROPN
eurjchem-1566	85	4	m	m	NOUN
eurjchem-1566	85	5	d	d	PROPN
eurjchem-1566	85	6	,	,	PUNCT
eurjchem-1566	85	7	e	e	PROPN
eurjchem-1566	85	8	r	r	NOUN
eurjchem-1566	85	9	f	f	PROPN
eurjchem-1566	85	10	2	2	NUM
eurjchem-1566	85	11	29	29	NUM
eurjchem-1566	85	12	g	g	NOUN
eurjchem-1566	85	13	0.46±0.02	0.46±0.02	NOUN
eurjchem-1566	85	14	0.986	0.986	NUM
eurjchem-1566	85	15	h	h	NOUN
eurjchem-1566	85	16	‐0.38±0.14	‐0.38±0.14	NUM
eurjchem-1566	85	17	0.36±0.04	0.36±0.04	PROPN
eurjchem-1566	85	18	0.989	0.989	NUM
eurjchem-1566	85	19	h	h	NOUN
eurjchem-1566	85	20	mes(ch2)2cli	mes(ch2)2cli	ADJ
eurjchem-1566	85	21	11	11	NUM
eurjchem-1566	85	22	0.41±0.04	0.41±0.04	NOUN
eurjchem-1566	85	23	0.964	0.964	NUM
eurjchem-1566	85	24	0.11±0.07	0.11±0.07	PROPN
eurjchem-1566	85	25	0.47±0.05	0.47±0.05	NOUN
eurjchem-1566	85	26	0.973	0.973	NUM
eurjchem-1566	85	27	phs(ch2)2cli	phs(ch2)2cli	NOUN
eurjchem-1566	85	28	6	6	NUM
eurjchem-1566	85	29	0.39±0.04	0.39±0.04	NOUN
eurjchem-1566	85	30	0.984	0.984	NUM
eurjchem-1566	85	31	0.07±0.05	0.07±0.05	NOUN
eurjchem-1566	85	32	0.44±0.05	0.44±0.05	NOUN
eurjchem-1566	85	33	0.990	0.990	NUM
eurjchem-1566	85	34	phs(ch2)2otsi	phs(ch2)2otsi	PROPN
eurjchem-1566	85	35	8	8	NUM
eurjchem-1566	85	36	0.52±0.04	0.52±0.04	NOUN
eurjchem-1566	85	37	0.984	0.984	NUM
eurjchem-1566	85	38	‐0.10±0.02	‐0.10±0.02	NUM
eurjchem-1566	85	39	0.44±0.02	0.44±0.02	NUM
eurjchem-1566	85	40	0.997	0.997	NUM
eurjchem-1566	85	41	phse(ch2)2cli	phse(ch2)2cli	NUM
eurjchem-1566	85	42	7	7	NUM
eurjchem-1566	85	43	0.42±0.03	0.42±0.03	NUM
eurjchem-1566	85	44	0.991	0.991	NUM
eurjchem-1566	85	45	‐0.01±0.05	‐0.01±0.05	NUM
eurjchem-1566	85	46	0.42±0.04	0.42±0.04	NOUN
eurjchem-1566	85	47	0.991	0.991	NUM
eurjchem-1566	85	48	ph2p(ch2)3cli	ph2p(ch2)3cli	ADJ
eurjchem-1566	85	49	8	8	NUM
eurjchem-1566	85	50	0.47±0.04	0.47±0.04	NOUN
eurjchem-1566	85	51	0.980	0.980	NUM
eurjchem-1566	85	52	‐0.05±0.06	‐0.05±0.06	NUM
eurjchem-1566	85	53	0.43±0.06	0.43±0.06	NUM
eurjchem-1566	85	54	0.983	0.983	NUM
eurjchem-1566	85	55	phs(ch2)4cli	phs(ch2)4cli	PROPN
eurjchem-1566	85	56	6	6	NUM
eurjchem-1566	85	57	0.34±0.02	0.34±0.02	NUM
eurjchem-1566	85	58	0.993	0.993	NUM
eurjchem-1566	85	59	0.01±0.03	0.01±0.03	ADJ
eurjchem-1566	85	60	0.36±0.04	0.36±0.04	NOUN
eurjchem-1566	85	61	0.993	0.993	NUM
eurjchem-1566	85	62	c6h11ots	c6h11ot	NOUN
eurjchem-1566	85	63	j	j	PROPN
eurjchem-1566	85	64	18	18	NUM
eurjchem-1566	85	65	0.59±0.07	0.59±0.07	NUM
eurjchem-1566	85	66	0.914	0.914	NUM
eurjchem-1566	85	67	0.35±0.03	0.35±0.03	NUM
eurjchem-1566	85	68	0.81±0.03	0.81±0.03	NOUN
eurjchem-1566	85	69	0.991	0.991	NUM
eurjchem-1566	85	70	a	a	DET
eurjchem-1566	85	71	the	the	DET
eurjchem-1566	85	72	yx	yx	NOUN
eurjchem-1566	85	73	scale	scale	NOUN
eurjchem-1566	85	74	used	use	VERB
eurjchem-1566	85	75	is	be	AUX
eurjchem-1566	85	76	the	the	DET
eurjchem-1566	85	77	appropriate	appropriate	ADJ
eurjchem-1566	85	78	one	one	NUM
eurjchem-1566	85	79	for	for	ADP
eurjchem-1566	85	80	x	x	NOUN
eurjchem-1566	85	81	=	=	NOUN
eurjchem-1566	85	82	br	br	NOUN
eurjchem-1566	85	83	,	,	PUNCT
eurjchem-1566	85	84	cl	cl	NOUN
eurjchem-1566	85	85	,	,	PUNCT
eurjchem-1566	85	86	or	or	CCONJ
eurjchem-1566	85	87	ots	ots	PROPN
eurjchem-1566	85	88	(	(	PUNCT
eurjchem-1566	85	89	ots	ots	PROPN
eurjchem-1566	85	90	is	be	AUX
eurjchem-1566	85	91	the	the	DET
eurjchem-1566	85	92	p‐toluenesulfonate	p‐toluenesulfonate	PUNCT
eurjchem-1566	85	93	leaving	leave	VERB
eurjchem-1566	85	94	group	group	NOUN
eurjchem-1566	85	95	)	)	PUNCT
eurjchem-1566	85	96	.	.	PUNCT
eurjchem-1566	86	1	b	b	X
eurjchem-1566	86	2	equation	equation	NOUN
eurjchem-1566	86	3	(	(	PUNCT
eurjchem-1566	86	4	1	1	NUM
eurjchem-1566	86	5	)	)	PUNCT
eurjchem-1566	86	6	,	,	PUNCT
eurjchem-1566	86	7	without	without	ADP
eurjchem-1566	86	8	and	and	CCONJ
eurjchem-1566	86	9	with	with	ADP
eurjchem-1566	86	10	the	the	DET
eurjchem-1566	86	11	nt	nt	ADJ
eurjchem-1566	86	12	term	term	NOUN
eurjchem-1566	86	13	.	.	PUNCT
eurjchem-1566	87	1	c	c	NOUN
eurjchem-1566	87	2	number	number	NOUN
eurjchem-1566	87	3	of	of	ADP
eurjchem-1566	87	4	solvents	solvent	NOUN
eurjchem-1566	87	5	.	.	PUNCT
eurjchem-1566	88	1	d	d	DET
eurjchem-1566	88	2	sensitivity	sensitivity	NOUN
eurjchem-1566	88	3	to	to	PART
eurjchem-1566	88	4	changes	change	NOUN
eurjchem-1566	88	5	in	in	ADP
eurjchem-1566	88	6	solvent	solvent	ADJ
eurjchem-1566	88	7	nucleophilicity	nucleophilicity	NOUN
eurjchem-1566	88	8	and	and	CCONJ
eurjchem-1566	88	9	solvent	solvent	ADJ
eurjchem-1566	88	10	ionizing	ionizing	NOUN
eurjchem-1566	88	11	power	power	NOUN
eurjchem-1566	88	12	.	.	PUNCT
eurjchem-1566	89	1	e	e	X
eurjchem-1566	89	2	with	with	ADP
eurjchem-1566	89	3	associated	associated	ADJ
eurjchem-1566	89	4	standard	standard	ADJ
eurjchem-1566	89	5	error	error	NOUN
eurjchem-1566	89	6	.	.	PUNCT
eurjchem-1566	90	1	f	f	PROPN
eurjchem-1566	90	2	correlation	correlation	NOUN
eurjchem-1566	90	3	coefficient	coefficient	NOUN
eurjchem-1566	90	4	.	.	PUNCT
eurjchem-1566	91	1	g	g	NOUN
eurjchem-1566	91	2	with	with	ADP
eurjchem-1566	91	3	the	the	DET
eurjchem-1566	91	4	fluoroalcohol‐containing	fluoroalcohol‐containing	NOUN
eurjchem-1566	91	5	solvents	solvent	NOUN
eurjchem-1566	91	6	omitted	omit	VERB
eurjchem-1566	91	7	.	.	PUNCT
eurjchem-1566	92	1	h	h	PROPN
eurjchem-1566	92	2	with	with	ADP
eurjchem-1566	92	3	constant	constant	ADJ
eurjchem-1566	92	4	(	(	PUNCT
eurjchem-1566	92	5	residual	residual	ADJ
eurjchem-1566	92	6	)	)	PUNCT
eurjchem-1566	92	7	c	c	NOUN
eurjchem-1566	92	8	values	value	NOUN
eurjchem-1566	92	9	of	of	ADP
eurjchem-1566	92	10	0.02±0.04	0.02±0.04	NOUN
eurjchem-1566	92	11	and	and	CCONJ
eurjchem-1566	92	12	0.05±0.04	0.05±0.04	NOUN
eurjchem-1566	92	13	.	.	PUNCT
eurjchem-1566	93	1	i	i	PRON
eurjchem-1566	93	2	values	value	VERB
eurjchem-1566	93	3	from	from	ADP
eurjchem-1566	93	4	tables	table	NOUN
eurjchem-1566	93	5	1	1	NUM
eurjchem-1566	93	6	and	and	CCONJ
eurjchem-1566	93	7	2	2	NUM
eurjchem-1566	93	8	of	of	ADP
eurjchem-1566	93	9	ref	ref	NOUN
eurjchem-1566	93	10	.	.	PUNCT
eurjchem-1566	94	1	[	[	X
eurjchem-1566	94	2	25	25	NUM
eurjchem-1566	94	3	]	]	PUNCT
eurjchem-1566	94	4	.	.	PUNCT
eurjchem-1566	95	1	j	j	PROPN
eurjchem-1566	95	2	from	from	ADP
eurjchem-1566	95	3	ref	ref	NOUN
eurjchem-1566	95	4	.	.	PUNCT
eurjchem-1566	96	1	[	[	X
eurjchem-1566	96	2	32	32	NUM
eurjchem-1566	96	3	]	]	PUNCT
eurjchem-1566	96	4	.	.	PUNCT
eurjchem-1566	97	1	the	the	DET
eurjchem-1566	97	2	desirability	desirability	NOUN
eurjchem-1566	97	3	of	of	ADP
eurjchem-1566	97	4	a	a	DET
eurjchem-1566	97	5	wide	wide	ADJ
eurjchem-1566	97	6	variety	variety	NOUN
eurjchem-1566	97	7	of	of	ADP
eurjchem-1566	97	8	solvents	solvent	NOUN
eurjchem-1566	97	9	being	be	AUX
eurjchem-1566	97	10	employed	employ	VERB
eurjchem-1566	97	11	during	during	ADP
eurjchem-1566	97	12	applications	application	NOUN
eurjchem-1566	97	13	of	of	ADP
eurjchem-1566	97	14	the	the	DET
eurjchem-1566	97	15	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	97	16	equation	equation	NOUN
eurjchem-1566	97	17	has	have	AUX
eurjchem-1566	97	18	previously	previously	ADV
eurjchem-1566	97	19	been	be	AUX
eurjchem-1566	97	20	emphasized	emphasize	VERB
eurjchem-1566	97	21	[	[	X
eurjchem-1566	97	22	21	21	NUM
eurjchem-1566	97	23	]	]	PUNCT
eurjchem-1566	97	24	.	.	PUNCT
eurjchem-1566	98	1	unfortunately	unfortunately	ADV
eurjchem-1566	98	2	,	,	PUNCT
eurjchem-1566	98	3	changes	change	NOUN
eurjchem-1566	98	4	in	in	ADP
eurjchem-1566	98	5	mechanisms	mechanism	NOUN
eurjchem-1566	98	6	from	from	ADP
eurjchem-1566	98	7	one	one	NUM
eurjchem-1566	98	8	involving	involve	VERB
eurjchem-1566	98	9	a	a	DET
eurjchem-1566	98	10	dominant	dominant	ADJ
eurjchem-1566	98	11	nucleo‐	nucleo‐	ADP
eurjchem-1566	98	12	philic	philic	ADJ
eurjchem-1566	98	13	attack	attack	NOUN
eurjchem-1566	98	14	by	by	ADP
eurjchem-1566	98	15	solvent	solvent	NOUN
eurjchem-1566	98	16	towards	towards	ADP
eurjchem-1566	98	17	one	one	NUM
eurjchem-1566	98	18	involving	involve	VERB
eurjchem-1566	98	19	ionization	ionization	NOUN
eurjchem-1566	98	20	of	of	ADP
eurjchem-1566	98	21	the	the	DET
eurjchem-1566	98	22	substrate	substrate	NOUN
eurjchem-1566	98	23	as	as	SCONJ
eurjchem-1566	98	24	the	the	DET
eurjchem-1566	98	25	solvent	solvent	ADJ
eurjchem-1566	98	26	nucleophilicity	nucleophilicity	NOUN
eurjchem-1566	98	27	is	be	AUX
eurjchem-1566	98	28	decreased	decrease	VERB
eurjchem-1566	98	29	and	and	CCONJ
eurjchem-1566	98	30	the	the	DET
eurjchem-1566	98	31	solvent	solvent	ADJ
eurjchem-1566	98	32	ionization	ionization	NOUN
eurjchem-1566	98	33	power	power	NOUN
eurjchem-1566	98	34	is	be	AUX
eurjchem-1566	98	35	increased	increase	VERB
eurjchem-1566	98	36	,	,	PUNCT
eurjchem-1566	98	37	by	by	ADP
eurjchem-1566	98	38	a	a	DET
eurjchem-1566	98	39	fluoroalcohol	fluoroalcohol	NOUN
eurjchem-1566	98	40	being	be	AUX
eurjchem-1566	98	41	incorporated	incorporate	VERB
eurjchem-1566	98	42	within	within	ADP
eurjchem-1566	98	43	the	the	DET
eurjchem-1566	98	44	solvent	solvent	NOUN
eurjchem-1566	98	45	,	,	PUNCT
eurjchem-1566	98	46	can	can	AUX
eurjchem-1566	98	47	complicate	complicate	VERB
eurjchem-1566	98	48	this	this	DET
eurjchem-1566	98	49	goal	goal	NOUN
eurjchem-1566	99	1	[	[	X
eurjchem-1566	99	2	22,23	22,23	NOUN
eurjchem-1566	99	3	]	]	X
eurjchem-1566	99	4	.	.	PUNCT
eurjchem-1566	100	1	for	for	SCONJ
eurjchem-1566	100	2	the	the	DET
eurjchem-1566	100	3	29	29	NUM
eurjchem-1566	100	4	solvents	solvent	NOUN
eurjchem-1566	100	5	incorporated	incorporate	VERB
eurjchem-1566	100	6	,	,	PUNCT
eurjchem-1566	100	7	the	the	DET
eurjchem-1566	100	8	specific	specific	ADJ
eurjchem-1566	100	9	rates	rate	NOUN
eurjchem-1566	100	10	can	can	AUX
eurjchem-1566	100	11	be	be	AUX
eurjchem-1566	100	12	adequately	adequately	ADV
eurjchem-1566	100	13	correlated	correlate	VERB
eurjchem-1566	100	14	by	by	ADP
eurjchem-1566	100	15	the	the	DET
eurjchem-1566	100	16	one‐term	one‐term	NOUN
eurjchem-1566	100	17	equation	equation	NOUN
eurjchem-1566	100	18	and	and	CCONJ
eurjchem-1566	100	19	there	there	PRON
eurjchem-1566	100	20	is	be	VERB
eurjchem-1566	100	21	only	only	ADV
eurjchem-1566	100	22	a	a	DET
eurjchem-1566	100	23	negligible	negligible	ADJ
eurjchem-1566	100	24	increase	increase	NOUN
eurjchem-1566	100	25	in	in	ADP
eurjchem-1566	100	26	the	the	DET
eurjchem-1566	100	27	correlation	correlation	NOUN
eurjchem-1566	100	28	coefficient	coefficient	NOUN
eurjchem-1566	100	29	on	on	ADP
eurjchem-1566	100	30	going	go	VERB
eurjchem-1566	100	31	to	to	ADP
eurjchem-1566	100	32	the	the	DET
eurjchem-1566	100	33	two‐term	two‐term	NOUN
eurjchem-1566	100	34	equation	equation	NOUN
eurjchem-1566	100	35	,	,	PUNCT
eurjchem-1566	100	36	accompanied	accompany	VERB
eurjchem-1566	100	37	by	by	ADP
eurjchem-1566	100	38	an	an	DET
eurjchem-1566	100	39	appreciable	appreciable	ADJ
eurjchem-1566	100	40	reduction	reduction	NOUN
eurjchem-1566	100	41	in	in	ADP
eurjchem-1566	100	42	the	the	DET
eurjchem-1566	100	43	f‐test	f‐test	PUNCT
eurjchem-1566	100	44	value	value	NOUN
eurjchem-1566	100	45	.	.	PUNCT
eurjchem-1566	101	1	a	a	DET
eurjchem-1566	101	2	plot	plot	NOUN
eurjchem-1566	101	3	of	of	ADP
eurjchem-1566	101	4	log	log	NOUN
eurjchem-1566	101	5	(	(	PUNCT
eurjchem-1566	101	6	k	k	NOUN
eurjchem-1566	101	7	/	/	SYM
eurjchem-1566	101	8	ko	ko	PROPN
eurjchem-1566	101	9	)	)	PUNCT
eurjchem-1566	101	10	against	against	ADP
eurjchem-1566	101	11	ybr	ybr	PROPN
eurjchem-1566	101	12	is	be	AUX
eurjchem-1566	101	13	shown	show	VERB
eurjchem-1566	101	14	in	in	ADP
eurjchem-1566	101	15	figure	figure	NOUN
eurjchem-1566	101	16	1	1	NUM
eurjchem-1566	101	17	.	.	PUNCT
eurjchem-1566	102	1	the	the	DET
eurjchem-1566	102	2	correlations	correlation	NOUN
eurjchem-1566	102	3	reported	report	VERB
eurjchem-1566	102	4	in	in	ADP
eurjchem-1566	102	5	equation	equation	NOUN
eurjchem-1566	102	6	(	(	PUNCT
eurjchem-1566	102	7	5	5	NUM
eurjchem-1566	102	8	)	)	PUNCT
eurjchem-1566	102	9	and	and	CCONJ
eurjchem-1566	102	10	(	(	PUNCT
eurjchem-1566	102	11	6	6	NUM
eurjchem-1566	102	12	)	)	PUNCT
eurjchem-1566	102	13	,	,	PUNCT
eurjchem-1566	102	14	and	and	CCONJ
eurjchem-1566	102	15	shown	show	VERB
eurjchem-1566	102	16	graphically	graphically	ADV
eurjchem-1566	102	17	for	for	ADP
eurjchem-1566	102	18	application	application	NOUN
eurjchem-1566	102	19	of	of	ADP
eurjchem-1566	102	20	equation	equation	NOUN
eurjchem-1566	102	21	(	(	PUNCT
eurjchem-1566	102	22	5	5	NUM
eurjchem-1566	102	23	)	)	PUNCT
eurjchem-1566	102	24	in	in	ADP
eurjchem-1566	102	25	figure	figure	NOUN
eurjchem-1566	102	26	1	1	NUM
eurjchem-1566	102	27	,	,	PUNCT
eurjchem-1566	102	28	exclude	exclude	VERB
eurjchem-1566	102	29	the	the	DET
eurjchem-1566	102	30	tfe‐containing	tfe‐containe	VERB
eurjchem-1566	102	31	solvents	solvent	NOUN
eurjchem-1566	102	32	.	.	PUNCT
eurjchem-1566	103	1	the	the	DET
eurjchem-1566	103	2	data	data	NOUN
eurjchem-1566	103	3	points	point	VERB
eurjchem-1566	103	4	for	for	ADP
eurjchem-1566	103	5	the	the	DET
eurjchem-1566	103	6	tfe‐containing	tfe‐containe	VERB
eurjchem-1566	103	7	solvents	solvent	NOUN
eurjchem-1566	103	8	are	be	AUX
eurjchem-1566	103	9	added	add	VERB
eurjchem-1566	103	10	to	to	PART
eurjchem-1566	103	11	figure	figure	VERB
eurjchem-1566	103	12	1	1	NUM
eurjchem-1566	103	13	to	to	PART
eurjchem-1566	103	14	show	show	VERB
eurjchem-1566	103	15	the	the	DET
eurjchem-1566	103	16	extent	extent	NOUN
eurjchem-1566	103	17	and	and	CCONJ
eurjchem-1566	103	18	nature	nature	NOUN
eurjchem-1566	103	19	of	of	ADP
eurjchem-1566	103	20	their	their	PRON
eurjchem-1566	103	21	deviation	deviation	NOUN
eurjchem-1566	103	22	from	from	ADP
eurjchem-1566	103	23	the	the	DET
eurjchem-1566	103	24	plot	plot	NOUN
eurjchem-1566	103	25	.	.	PUNCT
eurjchem-1566	104	1	they	they	PRON
eurjchem-1566	104	2	gave	give	VERB
eurjchem-1566	104	3	a	a	DET
eurjchem-1566	104	4	separate	separate	ADJ
eurjchem-1566	104	5	,	,	PUNCT
eurjchem-1566	104	6	and	and	CCONJ
eurjchem-1566	104	7	almost	almost	ADV
eurjchem-1566	104	8	linear	linear	ADJ
eurjchem-1566	104	9	,	,	PUNCT
eurjchem-1566	104	10	plot	plot	NOUN
eurjchem-1566	104	11	lying	lie	VERB
eurjchem-1566	104	12	at	at	ADP
eurjchem-1566	104	13	about	about	ADV
eurjchem-1566	104	14	one	one	NUM
eurjchem-1566	104	15	log	log	NOUN
eurjchem-1566	104	16	k	k	PROPN
eurjchem-1566	104	17	unit	unit	NOUN
eurjchem-1566	104	18	below	below	ADP
eurjchem-1566	104	19	the	the	DET
eurjchem-1566	104	20	above	above	ADJ
eurjchem-1566	104	21	discussed	discuss	VERB
eurjchem-1566	104	22	plot	plot	NOUN
eurjchem-1566	104	23	.	.	PUNCT
eurjchem-1566	105	1	in	in	ADP
eurjchem-1566	105	2	table	table	NOUN
eurjchem-1566	105	3	3	3	NUM
eurjchem-1566	105	4	,	,	PUNCT
eurjchem-1566	105	5	the	the	DET
eurjchem-1566	105	6	values	value	NOUN
eurjchem-1566	105	7	in	in	ADP
eurjchem-1566	105	8	the	the	DET
eurjchem-1566	105	9	29	29	NUM
eurjchem-1566	105	10	solvents	solvent	NOUN
eurjchem-1566	105	11	are	be	AUX
eurjchem-1566	105	12	compared	compare	VERB
eurjchem-1566	105	13	with	with	ADP
eurjchem-1566	105	14	the	the	DET
eurjchem-1566	105	15	values	value	NOUN
eurjchem-1566	105	16	for	for	ADP
eurjchem-1566	105	17	other	other	ADJ
eurjchem-1566	105	18	substrates	substrate	NOUN
eurjchem-1566	105	19	also	also	ADV
eurjchem-1566	105	20	believed	believe	VERB
eurjchem-1566	105	21	to	to	PART
eurjchem-1566	105	22	involve	involve	VERB
eurjchem-1566	105	23	an	an	DET
eurjchem-1566	105	24	internal	internal	ADJ
eurjchem-1566	105	25	nucleophilic	nucleophilic	ADJ
eurjchem-1566	105	26	assistance	assistance	NOUN
eurjchem-1566	105	27	.	.	PUNCT
eurjchem-1566	106	1	what	what	PRON
eurjchem-1566	106	2	is	be	AUX
eurjchem-1566	106	3	unusual	unusual	ADJ
eurjchem-1566	106	4	as	as	SCONJ
eurjchem-1566	106	5	regards	regard	NOUN
eurjchem-1566	106	6	figure	figure	NOUN
eurjchem-1566	106	7	1	1	NUM
eurjchem-1566	106	8	is	be	AUX
eurjchem-1566	106	9	that	that	SCONJ
eurjchem-1566	106	10	the	the	DET
eurjchem-1566	106	11	points	point	NOUN
eurjchem-1566	106	12	for	for	ADP
eurjchem-1566	106	13	the	the	DET
eurjchem-1566	106	14	solvolyses	solvolyse	NOUN
eurjchem-1566	106	15	in	in	ADP
eurjchem-1566	106	16	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	106	17	solvents	solvent	NOUN
eurjchem-1566	106	18	of	of	ADP
eurjchem-1566	106	19	high	high	ADJ
eurjchem-1566	106	20	ionizing	ionizing	NOUN
eurjchem-1566	106	21	power	power	NOUN
eurjchem-1566	106	22	,	,	PUNCT
eurjchem-1566	106	23	lie	lie	VERB
eurjchem-1566	106	24	below	below	ADP
eurjchem-1566	106	25	the	the	DET
eurjchem-1566	106	26	correlation	correlation	NOUN
eurjchem-1566	106	27	line	line	NOUN
eurjchem-1566	106	28	based	base	VERB
eurjchem-1566	106	29	on	on	ADP
eurjchem-1566	106	30	the	the	DET
eurjchem-1566	106	31	solvents	solvent	NOUN
eurjchem-1566	106	32	not	not	PART
eurjchem-1566	106	33	containing	contain	VERB
eurjchem-1566	106	34	fluoroalcohol	fluoroalcohol	NOUN
eurjchem-1566	106	35	.	.	PUNCT
eurjchem-1566	107	1	the	the	DET
eurjchem-1566	107	2	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	107	3	measure	measure	NOUN
eurjchem-1566	107	4	of	of	ADP
eurjchem-1566	107	5	solvent	solvent	ADJ
eurjchem-1566	107	6	ionizing	ionizing	NOUN
eurjchem-1566	107	7	power	power	NOUN
eurjchem-1566	107	8	will	will	AUX
eurjchem-1566	107	9	be	be	AUX
eurjchem-1566	107	10	a	a	DET
eurjchem-1566	107	11	composite	composite	NOUN
eurjchem-1566	107	12	of	of	ADP
eurjchem-1566	107	13	several	several	ADJ
eurjchem-1566	107	14	components	component	NOUN
eurjchem-1566	107	15	,	,	PUNCT
eurjchem-1566	107	16	with	with	SCONJ
eurjchem-1566	107	17	the	the	DET
eurjchem-1566	107	18	major	major	ADJ
eurjchem-1566	107	19	ones	one	NOUN
eurjchem-1566	107	20	expected	expect	VERB
eurjchem-1566	107	21	to	to	PART
eurjchem-1566	107	22	be	be	AUX
eurjchem-1566	107	23	that	that	SCONJ
eurjchem-1566	107	24	a	a	DET
eurjchem-1566	107	25	generalized	generalize	VERB
eurjchem-1566	107	26	increased	increase	VERB
eurjchem-1566	107	27	polarity	polarity	NOUN
eurjchem-1566	107	28	will	will	AUX
eurjchem-1566	107	29	favor	favor	VERB
eurjchem-1566	107	30	ionization	ionization	NOUN
eurjchem-1566	107	31	and	and	CCONJ
eurjchem-1566	107	32	specific	specific	ADJ
eurjchem-1566	107	33	electrophilic	electrophilic	ADJ
eurjchem-1566	107	34	solvation	solvation	NOUN
eurjchem-1566	107	35	effects	effect	NOUN
eurjchem-1566	107	36	will	will	AUX
eurjchem-1566	107	37	assist	assist	VERB
eurjchem-1566	107	38	the	the	DET
eurjchem-1566	107	39	departure	departure	NOUN
eurjchem-1566	107	40	of	of	ADP
eurjchem-1566	107	41	an	an	DET
eurjchem-1566	107	42	anionic	anionic	ADJ
eurjchem-1566	107	43	leaving	leaving	NOUN
eurjchem-1566	107	44	group	group	NOUN
eurjchem-1566	107	45	.	.	PUNCT
eurjchem-1566	108	1	however	however	ADV
eurjchem-1566	108	2	,	,	PUNCT
eurjchem-1566	108	3	with	with	ADP
eurjchem-1566	108	4	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	108	5	as	as	ADP
eurjchem-1566	108	6	the	the	DET
eurjchem-1566	108	7	substrate	substrate	NOUN
eurjchem-1566	108	8	,	,	PUNCT
eurjchem-1566	108	9	the	the	DET
eurjchem-1566	108	10	electrophilic	electrophilic	ADJ
eurjchem-1566	108	11	solvation	solvation	NOUN
eurjchem-1566	108	12	aspect	aspect	NOUN
eurjchem-1566	108	13	can	can	AUX
eurjchem-1566	108	14	also	also	ADV
eurjchem-1566	108	15	involve	involve	VERB
eurjchem-1566	108	16	an	an	DET
eurjchem-1566	108	17	interaction	interaction	NOUN
eurjchem-1566	108	18	with	with	ADP
eurjchem-1566	108	19	the	the	DET
eurjchem-1566	108	20	lone‐pair	lone‐pair	NOUN
eurjchem-1566	108	21	of	of	ADP
eurjchem-1566	108	22	electrons	electron	NOUN
eurjchem-1566	108	23	on	on	ADP
eurjchem-1566	108	24	the	the	DET
eurjchem-1566	108	25	nitrogen	nitrogen	NOUN
eurjchem-1566	108	26	and	and	CCONJ
eurjchem-1566	108	27	here	here	ADV
eurjchem-1566	108	28	the	the	DET
eurjchem-1566	108	29	influence	influence	NOUN
eurjchem-1566	108	30	will	will	AUX
eurjchem-1566	108	31	be	be	AUX
eurjchem-1566	108	32	to	to	PART
eurjchem-1566	108	33	make	make	VERB
eurjchem-1566	108	34	this	this	DET
eurjchem-1566	108	35	lone‐pair	lone‐pair	NOUN
eurjchem-1566	108	36	less	less	ADV
eurjchem-1566	108	37	effective	effective	ADJ
eurjchem-1566	108	38	in	in	ADP
eurjchem-1566	108	39	promoting	promote	VERB
eurjchem-1566	108	40	the	the	DET
eurjchem-1566	108	41	concerted	concert	VERB
eurjchem-1566	108	42	grob	grob	PROPN
eurjchem-1566	108	43	fragmentation	fragmentation	NOUN
eurjchem-1566	108	44	,	,	PUNCT
eurjchem-1566	108	45	with	with	ADP
eurjchem-1566	108	46	a	a	DET
eurjchem-1566	108	47	reduction	reduction	NOUN
eurjchem-1566	108	48	in	in	ADP
eurjchem-1566	108	49	the	the	DET
eurjchem-1566	108	50	specific	specific	ADJ
eurjchem-1566	108	51	rate	rate	NOUN
eurjchem-1566	108	52	of	of	ADP
eurjchem-1566	108	53	the	the	DET
eurjchem-1566	108	54	concerted	concerted	ADJ
eurjchem-1566	108	55	process	process	NOUN
eurjchem-1566	108	56	.	.	PUNCT
eurjchem-1566	109	1	this	this	PRON
eurjchem-1566	109	2	is	be	AUX
eurjchem-1566	109	3	consistent	consistent	ADJ
eurjchem-1566	109	4	with	with	ADP
eurjchem-1566	109	5	the	the	DET
eurjchem-1566	109	6	positioning	positioning	NOUN
eurjchem-1566	109	7	of	of	ADP
eurjchem-1566	109	8	the	the	DET
eurjchem-1566	109	9	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	109	10	data	data	NOUN
eurjchem-1566	109	11	points	point	NOUN
eurjchem-1566	109	12	in	in	ADP
eurjchem-1566	109	13	figure	figure	NOUN
eurjchem-1566	109	14	1	1	NUM
eurjchem-1566	109	15	.	.	PUNCT
eurjchem-1566	110	1	the	the	DET
eurjchem-1566	110	2	four	four	NUM
eurjchem-1566	110	3	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	110	4	solvent	solvent	NOUN
eurjchem-1566	110	5	mixtures	mixture	NOUN
eurjchem-1566	110	6	together	together	ADV
eurjchem-1566	110	7	with	with	ADP
eurjchem-1566	110	8	the	the	DET
eurjchem-1566	110	9	100	100	NUM
eurjchem-1566	110	10	%	%	NOUN
eurjchem-1566	110	11	h2o	h2o	NOUN
eurjchem-1566	110	12	have	have	AUX
eurjchem-1566	110	13	been	be	AUX
eurjchem-1566	110	14	plotted	plot	VERB
eurjchem-1566	110	15	using	use	VERB
eurjchem-1566	110	16	equation	equation	NOUN
eurjchem-1566	110	17	7	7	NUM
eurjchem-1566	110	18	,	,	PUNCT
eurjchem-1566	110	19	where	where	SCONJ
eurjchem-1566	110	20	ko	ko	PROPN
eurjchem-1566	110	21	refers	refer	VERB
eurjchem-1566	110	22	to	to	ADP
eurjchem-1566	110	23	the	the	DET
eurjchem-1566	110	24	value	value	NOUN
eurjchem-1566	110	25	which	which	PRON
eurjchem-1566	110	26	would	would	AUX
eurjchem-1566	110	27	apply	apply	VERB
eurjchem-1566	110	28	in	in	ADP
eurjchem-1566	110	29	80	80	NUM
eurjchem-1566	110	30	%	%	NOUN
eurjchem-1566	110	31	ethanol	ethanol	NOUN
eurjchem-1566	110	32	if	if	SCONJ
eurjchem-1566	110	33	the	the	DET
eurjchem-1566	110	34	same	same	ADJ
eurjchem-1566	110	35	pathway	pathway	NOUN
eurjchem-1566	110	36	as	as	ADP
eurjchem-1566	110	37	in	in	ADP
eurjchem-1566	110	38	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	110	39	was	be	AUX
eurjchem-1566	110	40	followed	follow	VERB
eurjchem-1566	110	41	.	.	PUNCT
eurjchem-1566	111	1	log	log	VERB
eurjchem-1566	111	2	k	k	NOUN
eurjchem-1566	112	1	=	=	PUNCT
eurjchem-1566	112	2	mybr	mybr	PROPN
eurjchem-1566	112	3	+	+	CCONJ
eurjchem-1566	112	4	(	(	PUNCT
eurjchem-1566	112	5	c	c	NOUN
eurjchem-1566	112	6	+	+	CCONJ
eurjchem-1566	112	7	log	log	PROPN
eurjchem-1566	112	8	ko	ko	PROPN
eurjchem-1566	112	9	)	)	PUNCT
eurjchem-1566	112	10	(	(	PUNCT
eurjchem-1566	112	11	7	7	X
eurjchem-1566	112	12	)	)	PUNCT
eurjchem-1566	112	13	the	the	DET
eurjchem-1566	112	14	value	value	NOUN
eurjchem-1566	112	15	for	for	ADP
eurjchem-1566	112	16	m	m	PROPN
eurjchem-1566	112	17	was	be	AUX
eurjchem-1566	112	18	found	find	VERB
eurjchem-1566	112	19	to	to	PART
eurjchem-1566	112	20	be	be	AUX
eurjchem-1566	112	21	0.89±0.08	0.89±0.08	ADJ
eurjchem-1566	112	22	and	and	CCONJ
eurjchem-1566	112	23	for	for	ADP
eurjchem-1566	112	24	c+log	c+log	PROPN
eurjchem-1566	112	25	k0	k0	PROPN
eurjchem-1566	112	26	a	a	DET
eurjchem-1566	112	27	value	value	NOUN
eurjchem-1566	112	28	of	of	ADP
eurjchem-1566	112	29	‐5.80±0.24	‐5.80±0.24	NUM
eurjchem-1566	112	30	.	.	PUNCT
eurjchem-1566	113	1	since	since	SCONJ
eurjchem-1566	113	2	c	c	PROPN
eurjchem-1566	113	3	is	be	AUX
eurjchem-1566	113	4	a	a	DET
eurjchem-1566	113	5	,	,	PUNCT
eurjchem-1566	113	6	usually	usually	ADV
eurjchem-1566	113	7	small	small	ADJ
eurjchem-1566	113	8	,	,	PUNCT
eurjchem-1566	113	9	residual	residual	ADJ
eurjchem-1566	113	10	term	term	NOUN
eurjchem-1566	113	11	,	,	PUNCT
eurjchem-1566	113	12	the	the	DET
eurjchem-1566	113	13	‐5.80	‐5.80	NOUN
eurjchem-1566	113	14	will	will	AUX
eurjchem-1566	113	15	closely	closely	ADV
eurjchem-1566	113	16	approximate	approximate	VERB
eurjchem-1566	113	17	the	the	DET
eurjchem-1566	113	18	predicted	predict	VERB
eurjchem-1566	113	19	log	log	NOUN
eurjchem-1566	113	20	ko	ko	PROPN
eurjchem-1566	113	21	value	value	NOUN
eurjchem-1566	113	22	in	in	ADP
eurjchem-1566	113	23	80	80	NUM
eurjchem-1566	113	24	%	%	NOUN
eurjchem-1566	113	25	ethanol	ethanol	NOUN
eurjchem-1566	113	26	,	,	PUNCT
eurjchem-1566	113	27	leading	lead	VERB
eurjchem-1566	113	28	to	to	ADP
eurjchem-1566	113	29	a	a	DET
eurjchem-1566	113	30	ko	ko	NOUN
eurjchem-1566	113	31	value	value	NOUN
eurjchem-1566	113	32	of	of	ADP
eurjchem-1566	113	33	1.58×10‐6	1.58×10‐6	NUM
eurjchem-1566	113	34	.	.	PUNCT
eurjchem-1566	114	1	this	this	DET
eurjchem-1566	114	2	value	value	NOUN
eurjchem-1566	114	3	is	be	AUX
eurjchem-1566	114	4	lower	low	ADJ
eurjchem-1566	114	5	than	than	ADP
eurjchem-1566	114	6	the	the	DET
eurjchem-1566	114	7	experimental	experimental	ADJ
eurjchem-1566	114	8	value	value	NOUN
eurjchem-1566	114	9	(	(	PUNCT
eurjchem-1566	114	10	table	table	NOUN
eurjchem-1566	114	11	2	2	NUM
eurjchem-1566	114	12	)	)	PUNCT
eurjchem-1566	114	13	in	in	ADP
eurjchem-1566	114	14	ethanol	ethanol	NOUN
eurjchem-1566	114	15	of	of	ADP
eurjchem-1566	114	16	9.9×10‐5	9.9×10‐5	NUM
eurjchem-1566	114	17	.	.	PUNCT
eurjchem-1566	115	1	the	the	DET
eurjchem-1566	115	2	slope	slope	NOUN
eurjchem-1566	115	3	of	of	ADP
eurjchem-1566	115	4	0.89	0.89	NUM
eurjchem-1566	115	5	is	be	AUX
eurjchem-1566	115	6	within	within	ADP
eurjchem-1566	115	7	the	the	DET
eurjchem-1566	115	8	region	region	NOUN
eurjchem-1566	115	9	commonly	commonly	ADV
eurjchem-1566	115	10	observed	observe	VERB
eurjchem-1566	115	11	for	for	ADP
eurjchem-1566	115	12	a	a	DET
eurjchem-1566	115	13	unimolecular	unimolecular	ADJ
eurjchem-1566	115	14	ionization	ionization	NOUN
eurjchem-1566	115	15	reaction	reaction	NOUN
eurjchem-1566	115	16	.	.	PUNCT
eurjchem-1566	116	1	when	when	SCONJ
eurjchem-1566	116	2	all	all	PRON
eurjchem-1566	116	3	of	of	ADP
eurjchem-1566	116	4	the	the	DET
eurjchem-1566	116	5	33	33	NUM
eurjchem-1566	116	6	solvents	solvent	NOUN
eurjchem-1566	116	7	of	of	ADP
eurjchem-1566	116	8	table	table	NOUN
eurjchem-1566	116	9	1	1	NUM
eurjchem-1566	116	10	are	be	AUX
eurjchem-1566	116	11	correlated	correlate	VERB
eurjchem-1566	116	12	using	use	VERB
eurjchem-1566	116	13	equation	equation	NOUN
eurjchem-1566	116	14	(	(	PUNCT
eurjchem-1566	116	15	1	1	NUM
eurjchem-1566	116	16	)	)	PUNCT
eurjchem-1566	116	17	,	,	PUNCT
eurjchem-1566	116	18	with	with	ADP
eurjchem-1566	116	19	and	and	CCONJ
eurjchem-1566	116	20	without	without	ADP
eurjchem-1566	116	21	the	the	DET
eurjchem-1566	116	22	lnt	lnt	NOUN
eurjchem-1566	116	23	term	term	NOUN
eurjchem-1566	116	24	,	,	PUNCT
eurjchem-1566	116	25	the	the	DET
eurjchem-1566	116	26	one‐term	one‐term	NOUN
eurjchem-1566	116	27	equation	equation	NOUN
eurjchem-1566	116	28	gives	give	VERB
eurjchem-1566	116	29	a	a	DET
eurjchem-1566	116	30	correlation	correlation	NOUN
eurjchem-1566	116	31	coefficient	coefficient	NOUN
eurjchem-1566	116	32	of	of	ADP
eurjchem-1566	116	33	0.923	0.923	NUM
eurjchem-1566	116	34	,	,	PUNCT
eurjchem-1566	116	35	which	which	PRON
eurjchem-1566	116	36	increases	increase	VERB
eurjchem-1566	116	37	to	to	ADP
eurjchem-1566	116	38	0.971	0.971	NUM
eurjchem-1566	116	39	when	when	SCONJ
eurjchem-1566	116	40	the	the	DET
eurjchem-1566	116	41	two‐term	two‐term	NOUN
eurjchem-1566	116	42	equation	equation	NOUN
eurjchem-1566	116	43	is	be	AUX
eurjchem-1566	116	44	used	use	VERB
eurjchem-1566	116	45	.	.	PUNCT
eurjchem-1566	117	1	these	these	DET
eurjchem-1566	117	2	values	value	NOUN
eurjchem-1566	117	3	are	be	AUX
eurjchem-1566	117	4	considerably	considerably	ADV
eurjchem-1566	117	5	lower	low	ADJ
eurjchem-1566	117	6	the	the	DET
eurjchem-1566	117	7	values	value	NOUN
eurjchem-1566	117	8	of	of	ADP
eurjchem-1566	117	9	0.986	0.986	NUM
eurjchem-1566	117	10	and	and	CCONJ
eurjchem-1566	117	11	0.989	0.989	NUM
eurjchem-1566	117	12	for	for	ADP
eurjchem-1566	117	13	the	the	DET
eurjchem-1566	117	14	29	29	NUM
eurjchem-1566	117	15	solvents	solvent	NOUN
eurjchem-1566	117	16	,	,	PUNCT
eurjchem-1566	117	17	excluding	exclude	VERB
eurjchem-1566	117	18	the	the	DET
eurjchem-1566	117	19	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	117	20	solvents	solvent	NOUN
eurjchem-1566	117	21	.	.	PUNCT
eurjchem-1566	118	1	further	far	ADV
eurjchem-1566	118	2	,	,	PUNCT
eurjchem-1566	118	3	the	the	DET
eurjchem-1566	118	4	values	value	NOUN
eurjchem-1566	118	5	for	for	ADP
eurjchem-1566	118	6	l	l	NOUN
eurjchem-1566	118	7	and	and	CCONJ
eurjchem-1566	118	8	m	m	PROPN
eurjchem-1566	118	9	would	would	AUX
eurjchem-1566	118	10	vary	vary	VERB
eurjchem-1566	118	11	as	as	ADP
eurjchem-1566	118	12	the	the	DET
eurjchem-1566	118	13	mix	mix	NOUN
eurjchem-1566	118	14	of	of	ADP
eurjchem-1566	118	15	solvents	solvent	NOUN
eurjchem-1566	118	16	following	follow	VERB
eurjchem-1566	118	17	the	the	DET
eurjchem-1566	118	18	upper	upper	ADJ
eurjchem-1566	118	19	and	and	CCONJ
eurjchem-1566	118	20	lower	low	ADJ
eurjchem-1566	118	21	correlations	correlation	NOUN
eurjchem-1566	118	22	of	of	ADP
eurjchem-1566	118	23	figure	figure	NOUN
eurjchem-1566	118	24	1	1	NUM
eurjchem-1566	118	25	was	be	AUX
eurjchem-1566	118	26	varied	varied	ADJ
eurjchem-1566	118	27	and	and	CCONJ
eurjchem-1566	118	28	the	the	DET
eurjchem-1566	118	29	composite	composite	ADJ
eurjchem-1566	118	30	(	(	PUNCT
eurjchem-1566	118	31	averaged	averaged	ADJ
eurjchem-1566	118	32	)	)	PUNCT
eurjchem-1566	118	33	values	value	NOUN
eurjchem-1566	118	34	obtained	obtain	VERB
eurjchem-1566	118	35	are	be	AUX
eurjchem-1566	118	36	of	of	ADP
eurjchem-1566	118	37	little	little	ADJ
eurjchem-1566	118	38	assistance	assistance	NOUN
eurjchem-1566	118	39	in	in	ADP
eurjchem-1566	118	40	the	the	DET
eurjchem-1566	118	41	establishment	establishment	NOUN
eurjchem-1566	118	42	of	of	ADP
eurjchem-1566	118	43	a	a	DET
eurjchem-1566	118	44	mechanistic	mechanistic	ADJ
eurjchem-1566	118	45	framework	framework	NOUN
eurjchem-1566	118	46	.	.	PUNCT
eurjchem-1566	119	1	the	the	DET
eurjchem-1566	119	2	low	low	ADJ
eurjchem-1566	119	3	value	value	NOUN
eurjchem-1566	119	4	for	for	ADP
eurjchem-1566	119	5	m	m	PROPN
eurjchem-1566	119	6	of	of	ADP
eurjchem-1566	119	7	0.46±0.02	0.46±0.02	NOUN
eurjchem-1566	119	8	using	use	VERB
eurjchem-1566	119	9	the	the	DET
eurjchem-1566	119	10	simple	simple	ADJ
eurjchem-1566	119	11	(	(	PUNCT
eurjchem-1566	119	12	one‐	one‐	NOUN
eurjchem-1566	119	13	term	term	NOUN
eurjchem-1566	119	14	)	)	PUNCT
eurjchem-1566	119	15	equation	equation	NOUN
eurjchem-1566	119	16	for	for	ADP
eurjchem-1566	119	17	29	29	NUM
eurjchem-1566	119	18	solvents	solvent	NOUN
eurjchem-1566	119	19	(	(	PUNCT
eurjchem-1566	119	20	table	table	NOUN
eurjchem-1566	119	21	3	3	NUM
eurjchem-1566	119	22	)	)	PUNCT
eurjchem-1566	119	23	is	be	AUX
eurjchem-1566	119	24	consistent	consistent	ADJ
eurjchem-1566	119	25	with	with	ADP
eurjchem-1566	119	26	the	the	DET
eurjchem-1566	119	27	“	"	PUNCT
eurjchem-1566	119	28	internal	internal	ADJ
eurjchem-1566	119	29	”	"	PUNCT
eurjchem-1566	119	30	sn2	sn2	PROPN
eurjchem-1566	119	31	nature	nature	NOUN
eurjchem-1566	119	32	proposed	propose	VERB
eurjchem-1566	119	33	for	for	ADP
eurjchem-1566	119	34	synchronous	synchronous	ADJ
eurjchem-1566	119	35	grob	grob	PROPN
eurjchem-1566	119	36	fragmen‐	fragmen‐	NOUN
eurjchem-1566	119	37	tation	tation	NOUN
eurjchem-1566	119	38	.	.	PUNCT
eurjchem-1566	120	1	the	the	DET
eurjchem-1566	120	2	solvolysis	solvolysis	NOUN
eurjchem-1566	120	3	of	of	ADP
eurjchem-1566	120	4	methyl	methyl	NOUN
eurjchem-1566	120	5	p‐toluenesulfonate	p‐toluenesulfonate	PUNCT
eurjchem-1566	120	6	is	be	AUX
eurjchem-1566	120	7	the	the	DET
eurjchem-1566	120	8	usual	usual	ADJ
eurjchem-1566	120	9	model	model	NOUN
eurjchem-1566	120	10	chosen	choose	VERB
eurjchem-1566	120	11	for	for	ADP
eurjchem-1566	120	12	a	a	DET
eurjchem-1566	120	13	bimolecular	bimolecular	ADJ
eurjchem-1566	120	14	sn2	sn2	PROPN
eurjchem-1566	120	15	solvolysis	solvolysis	NOUN
eurjchem-1566	120	16	and	and	CCONJ
eurjchem-1566	120	17	,	,	PUNCT
eurjchem-1566	120	18	when	when	SCONJ
eurjchem-1566	120	19	nt	not	PART
eurjchem-1566	120	20	and	and	CCONJ
eurjchem-1566	120	21	yots	yot	NOUN
eurjchem-1566	120	22	values	value	NOUN
eurjchem-1566	120	23	are	be	AUX
eurjchem-1566	120	24	incorporated	incorporate	VERB
eurjchem-1566	120	25	into	into	ADP
eurjchem-1566	120	26	the	the	DET
eurjchem-1566	120	27	extended	extended	ADJ
eurjchem-1566	120	28	(	(	PUNCT
eurjchem-1566	120	29	two‐term	two‐term	NOUN
eurjchem-1566	120	30	)	)	PUNCT
eurjchem-1566	120	31	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	120	32	equation	equation	NOUN
eurjchem-1566	120	33	[	[	X
eurjchem-1566	120	34	equation	equation	NOUN
eurjchem-1566	120	35	(	(	PUNCT
eurjchem-1566	120	36	1	1	NUM
eurjchem-1566	120	37	)	)	PUNCT
eurjchem-1566	120	38	]	]	PUNCT
eurjchem-1566	120	39	an	an	DET
eurjchem-1566	120	40	l	l	NOUN
eurjchem-1566	120	41	value	value	NOUN
eurjchem-1566	120	42	of	of	ADP
eurjchem-1566	120	43	0.96±0.04	0.96±0.04	NOUN
eurjchem-1566	120	44	and	and	CCONJ
eurjchem-1566	120	45	an	an	DET
eurjchem-1566	120	46	m	m	NOUN
eurjchem-1566	120	47	value	value	NOUN
eurjchem-1566	120	48	of	of	ADP
eurjchem-1566	120	49	0.53±0.04	0.53±0.04	NOUN
eurjchem-1566	120	50	have	have	AUX
eurjchem-1566	120	51	been	be	AUX
eurjchem-1566	120	52	obtained	obtain	VERB
eurjchem-1566	120	53	[	[	X
eurjchem-1566	120	54	3,24	3,24	X
eurjchem-1566	120	55	]	]	X
eurjchem-1566	120	56	,	,	PUNCT
eurjchem-1566	120	57	this	this	DET
eurjchem-1566	120	58	m	m	NOUN
eurjchem-1566	120	59	value	value	NOUN
eurjchem-1566	120	60	is	be	AUX
eurjchem-1566	120	61	similar	similar	ADJ
eurjchem-1566	120	62	to	to	ADP
eurjchem-1566	120	63	that	that	PRON
eurjchem-1566	120	64	obtained	obtain	VERB
eurjchem-1566	120	65	in	in	ADP
eurjchem-1566	120	66	the	the	DET
eurjchem-1566	120	67	present	present	ADJ
eurjchem-1566	120	68	study	study	NOUN
eurjchem-1566	120	69	.	.	PUNCT
eurjchem-1566	121	1	it	it	PRON
eurjchem-1566	121	2	is	be	AUX
eurjchem-1566	121	3	useful	useful	ADJ
eurjchem-1566	121	4	to	to	PART
eurjchem-1566	121	5	compare	compare	VERB
eurjchem-1566	121	6	the	the	DET
eurjchem-1566	121	7	conclusions	conclusion	NOUN
eurjchem-1566	121	8	from	from	ADP
eurjchem-1566	121	9	the	the	DET
eurjchem-1566	121	10	present	present	ADJ
eurjchem-1566	121	11	study	study	NOUN
eurjchem-1566	121	12	with	with	ADP
eurjchem-1566	121	13	those	those	PRON
eurjchem-1566	121	14	from	from	ADP
eurjchem-1566	121	15	other	other	ADJ
eurjchem-1566	121	16	studies	study	NOUN
eurjchem-1566	121	17	of	of	ADP
eurjchem-1566	121	18	the	the	DET
eurjchem-1566	121	19	influence	influence	NOUN
eurjchem-1566	121	20	of	of	ADP
eurjchem-1566	121	21	solvent	solvent	ADJ
eurjchem-1566	121	22	variation	variation	NOUN
eurjchem-1566	121	23	on	on	ADP
eurjchem-1566	121	24	the	the	DET
eurjchem-1566	121	25	specific	specific	ADJ
eurjchem-1566	121	26	rates	rate	NOUN
eurjchem-1566	121	27	of	of	ADP
eurjchem-1566	121	28	“	"	PUNCT
eurjchem-1566	121	29	internal	internal	ADJ
eurjchem-1566	121	30	sn2‐type	sn2‐type	PROPN
eurjchem-1566	121	31	”	"	PUNCT
eurjchem-1566	121	32	nucleophilic	nucleophilic	ADJ
eurjchem-1566	121	33	substitution	substitution	NOUN
eurjchem-1566	121	34	reactions	reaction	NOUN
eurjchem-1566	121	35	.	.	PUNCT
eurjchem-1566	122	1	one	one	NUM
eurjchem-1566	122	2	such	such	ADJ
eurjchem-1566	122	3	reaction	reaction	NOUN
eurjchem-1566	122	4	,	,	PUNCT
eurjchem-1566	122	5	which	which	PRON
eurjchem-1566	122	6	we	we	PRON
eurjchem-1566	122	7	have	have	AUX
eurjchem-1566	122	8	analyzed	analyze	VERB
eurjchem-1566	122	9	earlier	early	ADV
eurjchem-1566	122	10	[	[	X
eurjchem-1566	122	11	25	25	NUM
eurjchem-1566	122	12	]	]	PUNCT
eurjchem-1566	122	13	in	in	ADP
eurjchem-1566	122	14	terms	term	NOUN
eurjchem-1566	122	15	of	of	ADP
eurjchem-1566	122	16	the	the	DET
eurjchem-1566	122	17	grunwald‐	grunwald‐	PROPN
eurjchem-1566	122	18	winstein	winstein	PROPN
eurjchem-1566	122	19	equation	equation	NOUN
eurjchem-1566	122	20	approach	approach	NOUN
eurjchem-1566	122	21	involves	involve	VERB
eurjchem-1566	122	22	the	the	DET
eurjchem-1566	122	23	ring	ring	NOUN
eurjchem-1566	122	24	closure	closure	NOUN
eurjchem-1566	122	25	reaction	reaction	NOUN
eurjchem-1566	122	26	of	of	ADP
eurjchem-1566	122	27	substrates	substrate	NOUN
eurjchem-1566	122	28	related	relate	VERB
eurjchem-1566	122	29	to	to	ADP
eurjchem-1566	122	30	mustard	mustard	NOUN
eurjchem-1566	122	31	chlorohydrin	chlorohydrin	NOUN
eurjchem-1566	122	32	.	.	PUNCT
eurjchem-1566	123	1	the	the	DET
eurjchem-1566	123	2	specific	specific	ADJ
eurjchem-1566	123	3	rates	rate	NOUN
eurjchem-1566	123	4	as	as	SCONJ
eurjchem-1566	123	5	the	the	DET
eurjchem-1566	123	6	solvent	solvent	NOUN
eurjchem-1566	123	7	is	be	AUX
eurjchem-1566	123	8	varied	varied	ADJ
eurjchem-1566	123	9	at	at	ADP
eurjchem-1566	123	10	constant	constant	ADJ
eurjchem-1566	123	11	temperature	temperature	NOUN
eurjchem-1566	123	12	have	have	AUX
eurjchem-1566	123	13	previously	previously	ADV
eurjchem-1566	123	14	been	be	AUX
eurjchem-1566	123	15	reported	report	VERB
eurjchem-1566	123	16	,	,	PUNCT
eurjchem-1566	123	17	for	for	ADP
eurjchem-1566	123	18	several	several	ADJ
eurjchem-1566	123	19	substrates	substrate	NOUN
eurjchem-1566	123	20	of	of	ADP
eurjchem-1566	123	21	this	this	DET
eurjchem-1566	123	22	type	type	NOUN
eurjchem-1566	123	23	[	[	X
eurjchem-1566	123	24	26‐31	26‐31	NOUN
eurjchem-1566	123	25	]	]	PUNCT
eurjchem-1566	123	26	.	.	PUNCT
eurjchem-1566	124	1	these	these	DET
eurjchem-1566	124	2	reactions	reaction	NOUN
eurjchem-1566	124	3	are	be	AUX
eurjchem-1566	124	4	of	of	ADP
eurjchem-1566	124	5	the	the	DET
eurjchem-1566	124	6	general	general	ADJ
eurjchem-1566	124	7	type	type	NOUN
eurjchem-1566	124	8	illustrated	illustrate	VERB
eurjchem-1566	124	9	in	in	ADP
eurjchem-1566	124	10	equation	equation	NOUN
eurjchem-1566	124	11	(	(	PUNCT
eurjchem-1566	124	12	8)	8)	NUM
eurjchem-1566	124	13	.	.	NOUN
eurjchem-1566	124	14	166	166	NUM
eurjchem-1566	124	15	kevill	kevill	NOUN
eurjchem-1566	124	16	et	et	PROPN
eurjchem-1566	124	17	al	al	PROPN
eurjchem-1566	124	18	.	.	PUNCT
eurjchem-1566	124	19	/	/	SYM
eurjchem-1566	124	20	european	european	PROPN
eurjchem-1566	124	21	journal	journal	PROPN
eurjchem-1566	124	22	of	of	ADP
eurjchem-1566	124	23	chemistry	chemistry	NOUN
eurjchem-1566	124	24	8	8	NUM
eurjchem-1566	124	25	(	(	PUNCT
eurjchem-1566	124	26	2	2	NUM
eurjchem-1566	124	27	)	)	PUNCT
eurjchem-1566	124	28	(	(	PUNCT
eurjchem-1566	124	29	2017	2017	NUM
eurjchem-1566	124	30	)	)	PUNCT
eurjchem-1566	124	31	162‐167	162‐167	NUM
eurjchem-1566	124	32	(	(	PUNCT
eurjchem-1566	124	33	8)	8)	NUM
eurjchem-1566	124	34	it	it	PRON
eurjchem-1566	124	35	was	be	AUX
eurjchem-1566	124	36	found	find	VERB
eurjchem-1566	124	37	[	[	X
eurjchem-1566	124	38	25	25	NUM
eurjchem-1566	124	39	]	]	PUNCT
eurjchem-1566	124	40	for	for	ADP
eurjchem-1566	124	41	six	six	NUM
eurjchem-1566	124	42	substrates	substrate	NOUN
eurjchem-1566	124	43	of	of	ADP
eurjchem-1566	124	44	this	this	DET
eurjchem-1566	124	45	general	general	ADJ
eurjchem-1566	124	46	type	type	NOUN
eurjchem-1566	124	47	that	that	PRON
eurjchem-1566	124	48	the	the	DET
eurjchem-1566	124	49	m	m	VERB
eurjchem-1566	124	50	values	value	NOUN
eurjchem-1566	124	51	of	of	ADP
eurjchem-1566	124	52	the	the	DET
eurjchem-1566	124	53	simple	simple	ADJ
eurjchem-1566	124	54	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	124	55	equation	equation	NOUN
eurjchem-1566	124	56	were	be	AUX
eurjchem-1566	124	57	in	in	ADP
eurjchem-1566	124	58	the	the	DET
eurjchem-1566	124	59	range	range	NOUN
eurjchem-1566	124	60	of	of	ADP
eurjchem-1566	124	61	0.34±0.02	0.34±0.02	NUM
eurjchem-1566	124	62	to	to	ADP
eurjchem-1566	124	63	0.52±0.04	0.52±0.04	NOUN
eurjchem-1566	124	64	and	and	CCONJ
eurjchem-1566	124	65	with	with	ADP
eurjchem-1566	124	66	appli‐	appli‐	ADJ
eurjchem-1566	124	67	cation	cation	NOUN
eurjchem-1566	124	68	of	of	ADP
eurjchem-1566	124	69	the	the	DET
eurjchem-1566	124	70	extended	extended	ADJ
eurjchem-1566	124	71	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	124	72	equation	equation	NOUN
eurjchem-1566	124	73	,	,	PUNCT
eurjchem-1566	124	74	negligible	negligible	ADJ
eurjchem-1566	124	75	l	l	NOUN
eurjchem-1566	124	76	values	value	NOUN
eurjchem-1566	124	77	were	be	AUX
eurjchem-1566	124	78	observed	observe	VERB
eurjchem-1566	124	79	(	(	PUNCT
eurjchem-1566	124	80	‐0.10±0.02	‐0.10±0.02	NUM
eurjchem-1566	124	81	to	to	ADP
eurjchem-1566	124	82	0.11±0.07	0.11±0.07	NUM
eurjchem-1566	124	83	)	)	PUNCT
eurjchem-1566	124	84	,	,	PUNCT
eurjchem-1566	124	85	with	with	ADP
eurjchem-1566	124	86	little	little	ADJ
eurjchem-1566	124	87	change	change	NOUN
eurjchem-1566	124	88	in	in	ADP
eurjchem-1566	124	89	the	the	DET
eurjchem-1566	124	90	m	m	NOUN
eurjchem-1566	124	91	values	value	NOUN
eurjchem-1566	124	92	.	.	PUNCT
eurjchem-1566	125	1	these	these	DET
eurjchem-1566	125	2	results	result	NOUN
eurjchem-1566	125	3	are	be	AUX
eurjchem-1566	125	4	summarized	summarize	VERB
eurjchem-1566	125	5	and	and	CCONJ
eurjchem-1566	125	6	compared	compare	VERB
eurjchem-1566	125	7	to	to	ADP
eurjchem-1566	125	8	those	those	PRON
eurjchem-1566	125	9	for	for	ADP
eurjchem-1566	125	10	solvolyses	solvolyse	NOUN
eurjchem-1566	125	11	of	of	ADP
eurjchem-1566	125	12	2	2	NUM
eurjchem-1566	125	13	in	in	ADP
eurjchem-1566	125	14	table	table	NOUN
eurjchem-1566	125	15	3	3	NUM
eurjchem-1566	125	16	,	,	PUNCT
eurjchem-1566	125	17	where	where	SCONJ
eurjchem-1566	125	18	it	it	PRON
eurjchem-1566	125	19	is	be	AUX
eurjchem-1566	125	20	also	also	ADV
eurjchem-1566	125	21	shown	show	VERB
eurjchem-1566	125	22	that	that	SCONJ
eurjchem-1566	125	23	solvolyses	solvolyse	NOUN
eurjchem-1566	125	24	of	of	ADP
eurjchem-1566	125	25	cyclohexyl	cyclohexyl	PROPN
eurjchem-1566	125	26	tosylate	tosylate	VERB
eurjchem-1566	125	27	,	,	PUNCT
eurjchem-1566	125	28	with	with	ADP
eurjchem-1566	125	29	no	no	DET
eurjchem-1566	125	30	electron	electron	NOUN
eurjchem-1566	125	31	pairs	pair	NOUN
eurjchem-1566	125	32	available	available	ADJ
eurjchem-1566	125	33	for	for	ADP
eurjchem-1566	125	34	participation	participation	NOUN
eurjchem-1566	125	35	in	in	ADP
eurjchem-1566	125	36	an	an	DET
eurjchem-1566	125	37	intramolecular	intramolecular	ADJ
eurjchem-1566	125	38	process	process	NOUN
eurjchem-1566	125	39	,	,	PUNCT
eurjchem-1566	125	40	involve	involve	VERB
eurjchem-1566	125	41	l	l	NOUN
eurjchem-1566	125	42	and	and	CCONJ
eurjchem-1566	125	43	m	m	PROPN
eurjchem-1566	125	44	values	value	NOUN
eurjchem-1566	125	45	typical	typical	ADJ
eurjchem-1566	125	46	for	for	ADP
eurjchem-1566	125	47	a	a	DET
eurjchem-1566	125	48	reaction	reaction	NOUN
eurjchem-1566	125	49	proceeding	proceed	VERB
eurjchem-1566	125	50	with	with	ADP
eurjchem-1566	125	51	a	a	DET
eurjchem-1566	125	52	developing	develop	VERB
eurjchem-1566	125	53	carbocation	carbocation	NOUN
eurjchem-1566	125	54	,	,	PUNCT
eurjchem-1566	125	55	which	which	PRON
eurjchem-1566	125	56	is	be	AUX
eurjchem-1566	125	57	assisted	assist	VERB
eurjchem-1566	125	58	by	by	ADP
eurjchem-1566	125	59	nucleophilic	nucleophilic	ADJ
eurjchem-1566	125	60	solvation	solvation	NOUN
eurjchem-1566	125	61	in	in	ADP
eurjchem-1566	125	62	the	the	DET
eurjchem-1566	125	63	rate‐determining	rate‐determining	NOUN
eurjchem-1566	125	64	step	step	NOUN
eurjchem-1566	125	65	[	[	X
eurjchem-1566	125	66	32	32	NUM
eurjchem-1566	125	67	]	]	PUNCT
eurjchem-1566	125	68	.	.	PUNCT
eurjchem-1566	126	1	alternatively	alternatively	ADV
eurjchem-1566	126	2	,	,	PUNCT
eurjchem-1566	126	3	the	the	DET
eurjchem-1566	126	4	transition	transition	NOUN
eurjchem-1566	126	5	rate	rate	NOUN
eurjchem-1566	126	6	of	of	ADP
eurjchem-1566	126	7	the	the	DET
eurjchem-1566	126	8	rate‐determining	rate‐determining	NOUN
eurjchem-1566	126	9	step	step	NOUN
eurjchem-1566	126	10	can	can	AUX
eurjchem-1566	126	11	be	be	AUX
eurjchem-1566	126	12	considered	consider	VERB
eurjchem-1566	126	13	in	in	ADP
eurjchem-1566	126	14	terms	term	NOUN
eurjchem-1566	126	15	of	of	ADP
eurjchem-1566	126	16	lying	lie	VERB
eurjchem-1566	126	17	towards	towards	ADP
eurjchem-1566	126	18	the	the	DET
eurjchem-1566	126	19	(	(	PUNCT
eurjchem-1566	126	20	sn1+e1	sn1+e1	PROPN
eurjchem-1566	126	21	)	)	PUNCT
eurjchem-1566	126	22	extreme	extreme	NOUN
eurjchem-1566	126	23	of	of	ADP
eurjchem-1566	126	24	an	an	DET
eurjchem-1566	126	25	(	(	PUNCT
eurjchem-1566	126	26	sn1+e1	sn1+e1	PROPN
eurjchem-1566	126	27	)	)	PUNCT
eurjchem-1566	126	28	to	to	ADP
eurjchem-1566	126	29	(	(	PUNCT
eurjchem-1566	126	30	sn2+e2	sn2+e2	NOUN
eurjchem-1566	126	31	)	)	PUNCT
eurjchem-1566	126	32	spectrum	spectrum	NOUN
eurjchem-1566	126	33	of	of	ADP
eurjchem-1566	126	34	mechanisms	mechanism	NOUN
eurjchem-1566	126	35	[	[	X
eurjchem-1566	126	36	19,33	19,33	X
eurjchem-1566	126	37	]	]	PUNCT
eurjchem-1566	126	38	.	.	PUNCT
eurjchem-1566	127	1	grob	grob	PROPN
eurjchem-1566	127	2	defined	define	VERB
eurjchem-1566	127	3	a	a	DET
eurjchem-1566	127	4	measure	measure	NOUN
eurjchem-1566	127	5	of	of	ADP
eurjchem-1566	127	6	the	the	DET
eurjchem-1566	127	7	assistance	assistance	NOUN
eurjchem-1566	127	8	given	give	VERB
eurjchem-1566	127	9	by	by	ADP
eurjchem-1566	127	10	fragmentation	fragmentation	NOUN
eurjchem-1566	127	11	,	,	PUNCT
eurjchem-1566	127	12	termed	term	VERB
eurjchem-1566	127	13	the	the	DET
eurjchem-1566	127	14	frangomeric	frangomeric	ADJ
eurjchem-1566	127	15	effect	effect	NOUN
eurjchem-1566	127	16	,	,	PUNCT
eurjchem-1566	127	17	from	from	ADP
eurjchem-1566	127	18	a	a	DET
eurjchem-1566	127	19	conside‐	conside‐	PROPN
eurjchem-1566	127	20	ration	ration	NOUN
eurjchem-1566	127	21	of	of	ADP
eurjchem-1566	127	22	the	the	DET
eurjchem-1566	127	23	ratio	ratio	NOUN
eurjchem-1566	127	24	of	of	ADP
eurjchem-1566	127	25	the	the	DET
eurjchem-1566	127	26	specific	specific	ADJ
eurjchem-1566	127	27	rates	rate	NOUN
eurjchem-1566	127	28	of	of	ADP
eurjchem-1566	127	29	solvolysis	solvolysis	NOUN
eurjchem-1566	127	30	for	for	ADP
eurjchem-1566	127	31	the	the	DET
eurjchem-1566	127	32	compound	compound	NOUN
eurjchem-1566	127	33	with	with	ADP
eurjchem-1566	127	34	the	the	DET
eurjchem-1566	127	35	leaving	leave	VERB
eurjchem-1566	127	36	group	group	NOUN
eurjchem-1566	127	37	at	at	ADP
eurjchem-1566	127	38	the	the	DET
eurjchem-1566	127	39	4‐position	4‐position	PROPN
eurjchem-1566	127	40	of	of	ADP
eurjchem-1566	127	41	a	a	DET
eurjchem-1566	127	42	piperidine	piperidine	NOUN
eurjchem-1566	127	43	ring	ring	NOUN
eurjchem-1566	127	44	relative	relative	ADJ
eurjchem-1566	127	45	to	to	ADP
eurjchem-1566	127	46	the	the	DET
eurjchem-1566	127	47	leaving	leave	VERB
eurjchem-1566	127	48	group	group	NOUN
eurjchem-1566	127	49	departing	depart	VERB
eurjchem-1566	127	50	from	from	ADP
eurjchem-1566	127	51	the	the	DET
eurjchem-1566	127	52	molecule	molecule	NOUN
eurjchem-1566	127	53	with	with	ADP
eurjchem-1566	127	54	the	the	DET
eurjchem-1566	127	55	nitrogen	nitrogen	NOUN
eurjchem-1566	127	56	atom	atom	NOUN
eurjchem-1566	127	57	replaced	replace	VERB
eurjchem-1566	127	58	by	by	ADP
eurjchem-1566	127	59	a	a	DET
eurjchem-1566	127	60	ch	ch	NOUN
eurjchem-1566	127	61	grouping	grouping	NOUN
eurjchem-1566	127	62	.	.	PUNCT
eurjchem-1566	128	1	for	for	ADP
eurjchem-1566	128	2	example	example	NOUN
eurjchem-1566	128	3	,	,	PUNCT
eurjchem-1566	128	4	in	in	ADP
eurjchem-1566	128	5	80	80	NUM
eurjchem-1566	128	6	%	%	NOUN
eurjchem-1566	128	7	ethanol	ethanol	NOUN
eurjchem-1566	128	8	at	at	ADP
eurjchem-1566	128	9	100	100	NUM
eurjchem-1566	128	10	°	°	NOUN
eurjchem-1566	128	11	c	c	NOUN
eurjchem-1566	128	12	,	,	PUNCT
eurjchem-1566	128	13	the	the	DET
eurjchem-1566	128	14	ratio	ratio	NOUN
eurjchem-1566	128	15	favoring	favor	VERB
eurjchem-1566	128	16	4‐chloropiperidine	4‐chloropiperidine	NOUN
eurjchem-1566	128	17	(	(	PUNCT
eurjchem-1566	128	18	2	2	NUM
eurjchem-1566	128	19	)	)	PUNCT
eurjchem-1566	128	20	relative	relative	ADJ
eurjchem-1566	128	21	to	to	ADP
eurjchem-1566	128	22	cyclohexyl	cyclohexyl	PROPN
eurjchem-1566	128	23	chloride	chloride	PROPN
eurjchem-1566	128	24	is	be	AUX
eurjchem-1566	128	25	113	113	NUM
eurjchem-1566	128	26	[	[	X
eurjchem-1566	128	27	1,7	1,7	NUM
eurjchem-1566	128	28	]	]	PUNCT
eurjchem-1566	128	29	.	.	PUNCT
eurjchem-1566	129	1	since	since	SCONJ
eurjchem-1566	129	2	we	we	PRON
eurjchem-1566	129	3	have	have	AUX
eurjchem-1566	129	4	demonstrated	demonstrate	VERB
eurjchem-1566	129	5	that	that	SCONJ
eurjchem-1566	129	6	,	,	PUNCT
eurjchem-1566	129	7	in	in	ADP
eurjchem-1566	129	8	terms	term	NOUN
eurjchem-1566	129	9	of	of	ADP
eurjchem-1566	129	10	the	the	DET
eurjchem-1566	129	11	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	129	12	correlations	correlation	NOUN
eurjchem-1566	129	13	,	,	PUNCT
eurjchem-1566	129	14	the	the	DET
eurjchem-1566	129	15	response	response	NOUN
eurjchem-1566	129	16	to	to	ADP
eurjchem-1566	129	17	the	the	DET
eurjchem-1566	129	18	solvent	solvent	ADJ
eurjchem-1566	129	19	variations	variation	NOUN
eurjchem-1566	129	20	is	be	AUX
eurjchem-1566	129	21	very	very	ADV
eurjchem-1566	129	22	different	different	ADJ
eurjchem-1566	129	23	for	for	ADP
eurjchem-1566	129	24	the	the	DET
eurjchem-1566	129	25	cyclohexyl	cyclohexyl	PROPN
eurjchem-1566	129	26	and	and	CCONJ
eurjchem-1566	129	27	the	the	DET
eurjchem-1566	129	28	corresponding	corresponding	ADJ
eurjchem-1566	129	29	4‐substituted	4‐substituted	ADJ
eurjchem-1566	129	30	piperidine	piperidine	NOUN
eurjchem-1566	129	31	derivatives	derivative	NOUN
eurjchem-1566	129	32	,	,	PUNCT
eurjchem-1566	129	33	one	one	PRON
eurjchem-1566	129	34	would	would	AUX
eurjchem-1566	129	35	expect	expect	VERB
eurjchem-1566	129	36	this	this	DET
eurjchem-1566	129	37	value	value	NOUN
eurjchem-1566	129	38	for	for	ADP
eurjchem-1566	129	39	the	the	DET
eurjchem-1566	129	40	frangomeric	frangomeric	ADJ
eurjchem-1566	129	41	effect	effect	NOUN
eurjchem-1566	129	42	to	to	PART
eurjchem-1566	129	43	vary	vary	VERB
eurjchem-1566	129	44	appreciably	appreciably	ADV
eurjchem-1566	129	45	as	as	SCONJ
eurjchem-1566	129	46	the	the	DET
eurjchem-1566	129	47	solvent	solvent	NOUN
eurjchem-1566	129	48	is	be	AUX
eurjchem-1566	129	49	varied	varied	ADJ
eurjchem-1566	129	50	.	.	PUNCT
eurjchem-1566	130	1	in	in	ADP
eurjchem-1566	130	2	comparing	compare	VERB
eurjchem-1566	130	3	the	the	DET
eurjchem-1566	130	4	grob	grob	PROPN
eurjchem-1566	130	5	fragmentation	fragmentation	NOUN
eurjchem-1566	130	6	of	of	ADP
eurjchem-1566	130	7	2	2	NUM
eurjchem-1566	130	8	to	to	ADP
eurjchem-1566	130	9	the	the	DET
eurjchem-1566	130	10	ring	ring	NOUN
eurjchem-1566	130	11	closure	closure	NOUN
eurjchem-1566	130	12	reactions	reaction	NOUN
eurjchem-1566	130	13	of	of	ADP
eurjchem-1566	130	14	the	the	DET
eurjchem-1566	130	15	mustard‐type	mustard‐type	NOUN
eurjchem-1566	130	16	compounds	compound	VERB
eurjchem-1566	130	17	[	[	X
eurjchem-1566	130	18	25	25	NUM
eurjchem-1566	130	19	]	]	PUNCT
eurjchem-1566	130	20	the	the	DET
eurjchem-1566	130	21	lack	lack	NOUN
eurjchem-1566	130	22	of	of	ADP
eurjchem-1566	130	23	a	a	DET
eurjchem-1566	130	24	statistically	statistically	ADV
eurjchem-1566	130	25	significant	significant	ADJ
eurjchem-1566	130	26	response	response	NOUN
eurjchem-1566	130	27	(	(	PUNCT
eurjchem-1566	130	28	l	l	NOUN
eurjchem-1566	130	29	)	)	PUNCT
eurjchem-1566	130	30	to	to	PART
eurjchem-1566	130	31	changes	change	NOUN
eurjchem-1566	130	32	in	in	ADP
eurjchem-1566	130	33	solvent	solvent	ADJ
eurjchem-1566	130	34	nucleophilicity	nucleophilicity	NOUN
eurjchem-1566	130	35	in	in	ADP
eurjchem-1566	130	36	both	both	DET
eurjchem-1566	130	37	cases	case	NOUN
eurjchem-1566	130	38	,	,	PUNCT
eurjchem-1566	130	39	supports	support	VERB
eurjchem-1566	130	40	the	the	DET
eurjchem-1566	130	41	pathways	pathway	NOUN
eurjchem-1566	130	42	outlined	outline	VERB
eurjchem-1566	130	43	in	in	ADP
eurjchem-1566	130	44	equations	equation	NOUN
eurjchem-1566	130	45	(	(	PUNCT
eurjchem-1566	130	46	3	3	NUM
eurjchem-1566	130	47	)	)	PUNCT
eurjchem-1566	130	48	and	and	CCONJ
eurjchem-1566	130	49	(	(	PUNCT
eurjchem-1566	130	50	8)	8)	NUM
eurjchem-1566	130	51	.	.	PUNCT
eurjchem-1566	131	1	one	one	NUM
eurjchem-1566	131	2	further	further	ADJ
eurjchem-1566	131	3	point	point	NOUN
eurjchem-1566	131	4	of	of	ADP
eurjchem-1566	131	5	similarity	similarity	NOUN
eurjchem-1566	131	6	is	be	AUX
eurjchem-1566	131	7	that	that	SCONJ
eurjchem-1566	131	8	a	a	DET
eurjchem-1566	131	9	plot	plot	NOUN
eurjchem-1566	131	10	of	of	ADP
eurjchem-1566	131	11	log	log	NOUN
eurjchem-1566	131	12	k	k	PROPN
eurjchem-1566	131	13	for	for	ADP
eurjchem-1566	131	14	the	the	DET
eurjchem-1566	131	15	solvolyses	solvolyse	NOUN
eurjchem-1566	131	16	of	of	ADP
eurjchem-1566	131	17	the	the	DET
eurjchem-1566	131	18	mustard	mustard	NOUN
eurjchem-1566	131	19	compound	compound	NOUN
eurjchem-1566	131	20	ch3sch2ch2cl	ch3sch2ch2cl	PROPN
eurjchem-1566	131	21	against	against	ADP
eurjchem-1566	131	22	log	log	PROPN
eurjchem-1566	131	23	k	k	PROPN
eurjchem-1566	131	24	for	for	ADP
eurjchem-1566	131	25	the	the	DET
eurjchem-1566	131	26	solvolyses	solvolyse	NOUN
eurjchem-1566	131	27	of	of	ADP
eurjchem-1566	131	28	1‐adcl	1‐adcl	PROPN
eurjchem-1566	131	29	(	(	PUNCT
eurjchem-1566	131	30	equivalent	equivalent	ADJ
eurjchem-1566	131	31	to	to	ADP
eurjchem-1566	131	32	plotting	plot	VERB
eurjchem-1566	131	33	against	against	ADP
eurjchem-1566	131	34	ycl	ycl	PROPN
eurjchem-1566	131	35	values	value	NOUN
eurjchem-1566	131	36	)	)	PUNCT
eurjchem-1566	131	37	shows	show	VERB
eurjchem-1566	131	38	that	that	SCONJ
eurjchem-1566	131	39	the	the	DET
eurjchem-1566	131	40	specific	specific	ADJ
eurjchem-1566	131	41	rates	rate	NOUN
eurjchem-1566	131	42	in	in	ADP
eurjchem-1566	131	43	tfe‐h20	tfe‐h20	PROPN
eurjchem-1566	131	44	mixtures	mixture	NOUN
eurjchem-1566	131	45	,	,	PUNCT
eurjchem-1566	131	46	lie	lie	VERB
eurjchem-1566	131	47	below	below	ADP
eurjchem-1566	131	48	the	the	DET
eurjchem-1566	131	49	linear	linear	ADJ
eurjchem-1566	131	50	plot	plot	NOUN
eurjchem-1566	131	51	of	of	ADP
eurjchem-1566	131	52	the	the	DET
eurjchem-1566	131	53	specific	specific	ADJ
eurjchem-1566	131	54	rates	rate	NOUN
eurjchem-1566	131	55	in	in	ADP
eurjchem-1566	131	56	etoh‐h2o	etoh‐h2o	NOUN
eurjchem-1566	131	57	and	and	CCONJ
eurjchem-1566	131	58	acetone‐h2o	acetone‐h2o	NOUN
eurjchem-1566	131	59	mixtures	mixture	NOUN
eurjchem-1566	131	60	[	[	X
eurjchem-1566	131	61	34	34	NUM
eurjchem-1566	131	62	]	]	PUNCT
eurjchem-1566	131	63	,	,	PUNCT
eurjchem-1566	131	64	paralleling	parallel	VERB
eurjchem-1566	131	65	the	the	DET
eurjchem-1566	131	66	observation	observation	NOUN
eurjchem-1566	131	67	for	for	ADP
eurjchem-1566	131	68	the	the	DET
eurjchem-1566	131	69	data	datum	NOUN
eurjchem-1566	131	70	plotted	plot	VERB
eurjchem-1566	131	71	in	in	ADP
eurjchem-1566	131	72	figure	figure	NOUN
eurjchem-1566	131	73	1	1	NUM
eurjchem-1566	131	74	of	of	ADP
eurjchem-1566	131	75	the	the	DET
eurjchem-1566	131	76	present	present	ADJ
eurjchem-1566	131	77	manuscript	manuscript	NOUN
eurjchem-1566	131	78	.	.	PUNCT
eurjchem-1566	132	1	in	in	ADP
eurjchem-1566	132	2	the	the	DET
eurjchem-1566	132	3	consideration	consideration	NOUN
eurjchem-1566	132	4	of	of	ADP
eurjchem-1566	132	5	the	the	DET
eurjchem-1566	132	6	influence	influence	NOUN
eurjchem-1566	132	7	of	of	ADP
eurjchem-1566	132	8	solvent	solvent	NOUN
eurjchem-1566	132	9	on	on	ADP
eurjchem-1566	132	10	a	a	DET
eurjchem-1566	132	11	methoxy	methoxy	ADJ
eurjchem-1566	132	12	group	group	NOUN
eurjchem-1566	132	13	,	,	PUNCT
eurjchem-1566	132	14	it	it	PRON
eurjchem-1566	132	15	has	have	AUX
eurjchem-1566	132	16	been	be	AUX
eurjchem-1566	132	17	convincingly	convincingly	ADV
eurjchem-1566	132	18	shown	show	VERB
eurjchem-1566	132	19	[	[	X
eurjchem-1566	132	20	35	35	NUM
eurjchem-1566	132	21	]	]	PUNCT
eurjchem-1566	132	22	that	that	SCONJ
eurjchem-1566	132	23	the	the	DET
eurjchem-1566	132	24	electron‐withdrawing	electron‐withdrawing	NOUN
eurjchem-1566	132	25	capacity	capacity	NOUN
eurjchem-1566	132	26	of	of	ADP
eurjchem-1566	132	27	a	a	DET
eurjchem-1566	132	28	non‐partici‐	non‐partici‐	NOUN
eurjchem-1566	132	29	pating	pat	VERB
eurjchem-1566	132	30	methoxy	methoxy	NOUN
eurjchem-1566	132	31	in	in	ADP
eurjchem-1566	132	32	the	the	DET
eurjchem-1566	132	33	solvolysis	solvolysis	NOUN
eurjchem-1566	132	34	of	of	ADP
eurjchem-1566	132	35	a	a	DET
eurjchem-1566	132	36	2‐methoxy	2‐methoxy	NUM
eurjchem-1566	132	37	substituted	substitute	VERB
eurjchem-1566	132	38	2‐	2‐	NUM
eurjchem-1566	132	39	cyclohexenyl	cyclohexenyl	NOUN
eurjchem-1566	132	40	p‐nitrobenzoate	p‐nitrobenzoate	PUNCT
eurjchem-1566	132	41	is	be	AUX
eurjchem-1566	132	42	strongly	strongly	ADV
eurjchem-1566	132	43	influenced	influence	VERB
eurjchem-1566	132	44	by	by	ADP
eurjchem-1566	132	45	the	the	DET
eurjchem-1566	132	46	hydrogen‐bond	hydrogen‐bond	NOUN
eurjchem-1566	132	47	donation	donation	NOUN
eurjchem-1566	132	48	from	from	ADP
eurjchem-1566	132	49	the	the	DET
eurjchem-1566	132	50	solvent	solvent	NOUN
eurjchem-1566	132	51	to	to	ADP
eurjchem-1566	132	52	the	the	DET
eurjchem-1566	132	53	oxygen	oxygen	NOUN
eurjchem-1566	132	54	of	of	ADP
eurjchem-1566	132	55	the	the	DET
eurjchem-1566	132	56	substituent	substituent	NOUN
eurjchem-1566	132	57	,	,	PUNCT
eurjchem-1566	132	58	and	and	CCONJ
eurjchem-1566	132	59	the	the	DET
eurjchem-1566	132	60	effect	effect	NOUN
eurjchem-1566	132	61	is	be	AUX
eurjchem-1566	132	62	much	much	ADV
eurjchem-1566	132	63	greater	great	ADJ
eurjchem-1566	132	64	in	in	ADP
eurjchem-1566	132	65	solvents	solvent	NOUN
eurjchem-1566	132	66	rich	rich	ADJ
eurjchem-1566	132	67	in	in	ADP
eurjchem-1566	132	68	tfe	tfe	NOUN
eurjchem-1566	132	69	than	than	ADP
eurjchem-1566	132	70	in	in	ADP
eurjchem-1566	132	71	aqueous	aqueous	ADJ
eurjchem-1566	132	72	acetone	acetone	NOUN
eurjchem-1566	132	73	or	or	CCONJ
eurjchem-1566	132	74	aqueous	aqueous	ADJ
eurjchem-1566	132	75	ethanol	ethanol	NOUN
eurjchem-1566	132	76	.	.	PUNCT
eurjchem-1566	133	1	there	there	PRON
eurjchem-1566	133	2	have	have	AUX
eurjchem-1566	133	3	also	also	ADV
eurjchem-1566	133	4	been	be	AUX
eurjchem-1566	133	5	studies	study	NOUN
eurjchem-1566	133	6	of	of	ADP
eurjchem-1566	133	7	ring	ring	NOUN
eurjchem-1566	133	8	closure	closure	NOUN
eurjchem-1566	133	9	reactions	reaction	NOUN
eurjchem-1566	133	10	based	base	VERB
eurjchem-1566	133	11	on	on	ADP
eurjchem-1566	133	12	the	the	DET
eurjchem-1566	133	13	intramolecular	intramolecular	ADJ
eurjchem-1566	133	14	attack	attack	NOUN
eurjchem-1566	133	15	by	by	ADP
eurjchem-1566	133	16	the	the	DET
eurjchem-1566	133	17	lone‐pair	lone‐pair	NOUN
eurjchem-1566	133	18	of	of	ADP
eurjchem-1566	133	19	elect‐	elect‐	PROPN
eurjchem-1566	133	20	rons	ron	NOUN
eurjchem-1566	133	21	on	on	ADP
eurjchem-1566	133	22	the	the	DET
eurjchem-1566	133	23	nitrogen	nitrogen	NOUN
eurjchem-1566	133	24	atom	atom	NOUN
eurjchem-1566	133	25	of	of	ADP
eurjchem-1566	133	26	2‐halogenoethylamines	2‐halogenoethylamine	NOUN
eurjchem-1566	133	27	to	to	PART
eurjchem-1566	133	28	give	give	VERB
eurjchem-1566	133	29	the	the	DET
eurjchem-1566	133	30	aziridinium	aziridinium	NOUN
eurjchem-1566	133	31	halide	halide	NOUN
eurjchem-1566	134	1	[	[	X
eurjchem-1566	134	2	36,37	36,37	X
eurjchem-1566	134	3	]	]	PUNCT
eurjchem-1566	134	4	.	.	PUNCT
eurjchem-1566	135	1	correlation	correlation	NOUN
eurjchem-1566	135	2	analysis	analysis	NOUN
eurjchem-1566	135	3	of	of	ADP
eurjchem-1566	135	4	the	the	DET
eurjchem-1566	135	5	kinetic	kinetic	ADJ
eurjchem-1566	135	6	response	response	NOUN
eurjchem-1566	135	7	to	to	ADP
eurjchem-1566	135	8	changes	change	NOUN
eurjchem-1566	135	9	in	in	ADP
eurjchem-1566	135	10	solvent	solvent	ADJ
eurjchem-1566	135	11	composition	composition	NOUN
eurjchem-1566	135	12	was	be	AUX
eurjchem-1566	135	13	considered	consider	VERB
eurjchem-1566	135	14	[	[	X
eurjchem-1566	135	15	36	36	NUM
eurjchem-1566	135	16	]	]	PUNCT
eurjchem-1566	135	17	to	to	PART
eurjchem-1566	135	18	show	show	VERB
eurjchem-1566	135	19	substantial	substantial	ADJ
eurjchem-1566	135	20	carbon‐nitrogen	carbon‐nitrogen	ADJ
eurjchem-1566	135	21	bond	bond	NOUN
eurjchem-1566	135	22	formation	formation	NOUN
eurjchem-1566	135	23	at	at	ADP
eurjchem-1566	135	24	the	the	DET
eurjchem-1566	135	25	transition	transition	NOUN
eurjchem-1566	135	26	state	state	NOUN
eurjchem-1566	135	27	,	,	PUNCT
eurjchem-1566	135	28	consistent	consistent	ADJ
eurjchem-1566	135	29	with	with	ADP
eurjchem-1566	135	30	the	the	DET
eurjchem-1566	135	31	low	low	ADJ
eurjchem-1566	135	32	m‐	m‐	NOUN
eurjchem-1566	135	33	value	value	NOUN
eurjchem-1566	135	34	observed	observe	VERB
eurjchem-1566	135	35	in	in	ADP
eurjchem-1566	135	36	the	the	DET
eurjchem-1566	135	37	present	present	ADJ
eurjchem-1566	135	38	study	study	NOUN
eurjchem-1566	135	39	of	of	ADP
eurjchem-1566	135	40	a	a	DET
eurjchem-1566	135	41	grob	grob	PROPN
eurjchem-1566	135	42	fragmentation	fragmentation	NOUN
eurjchem-1566	135	43	and	and	CCONJ
eurjchem-1566	135	44	in	in	ADP
eurjchem-1566	135	45	earlier	early	ADJ
eurjchem-1566	135	46	analyses	analysis	NOUN
eurjchem-1566	135	47	[	[	X
eurjchem-1566	135	48	25	25	NUM
eurjchem-1566	135	49	]	]	PUNCT
eurjchem-1566	135	50	of	of	ADP
eurjchem-1566	135	51	the	the	DET
eurjchem-1566	135	52	kinetic	kinetic	ADJ
eurjchem-1566	135	53	data	datum	NOUN
eurjchem-1566	135	54	available	available	ADJ
eurjchem-1566	135	55	[	[	X
eurjchem-1566	135	56	26‐	26‐	NUM
eurjchem-1566	135	57	31	31	NUM
eurjchem-1566	135	58	]	]	PUNCT
eurjchem-1566	135	59	for	for	ADP
eurjchem-1566	135	60	the	the	DET
eurjchem-1566	135	61	influence	influence	NOUN
eurjchem-1566	135	62	of	of	ADP
eurjchem-1566	135	63	solvent	solvent	ADJ
eurjchem-1566	135	64	variation	variation	NOUN
eurjchem-1566	135	65	on	on	ADP
eurjchem-1566	135	66	the	the	DET
eurjchem-1566	135	67	ring‐closing	ring‐closing	ADJ
eurjchem-1566	135	68	intramolecular	intramolecular	ADJ
eurjchem-1566	135	69	nucleophilic	nucleophilic	ADJ
eurjchem-1566	135	70	attack	attack	NOUN
eurjchem-1566	135	71	which	which	PRON
eurjchem-1566	135	72	is	be	AUX
eurjchem-1566	135	73	initiated	initiate	VERB
eurjchem-1566	135	74	by	by	ADP
eurjchem-1566	135	75	attack	attack	NOUN
eurjchem-1566	135	76	of	of	ADP
eurjchem-1566	135	77	a	a	DET
eurjchem-1566	135	78	neighboring	neighboring	NOUN
eurjchem-1566	135	79	sulfur	sulfur	NOUN
eurjchem-1566	135	80	,	,	PUNCT
eurjchem-1566	135	81	selenium	selenium	NOUN
eurjchem-1566	135	82	,	,	PUNCT
eurjchem-1566	135	83	or	or	CCONJ
eurjchem-1566	135	84	phosphorus	phosphorus	NOUN
eurjchem-1566	135	85	.	.	PUNCT
eurjchem-1566	136	1	4	4	X
eurjchem-1566	136	2	.	.	X
eurjchem-1566	136	3	conclusions	conclusion	NOUN
eurjchem-1566	136	4	the	the	DET
eurjchem-1566	136	5	first‐order	first‐order	PROPN
eurjchem-1566	136	6	rate	rate	NOUN
eurjchem-1566	136	7	coefficients	coefficient	NOUN
eurjchem-1566	136	8	(	(	PUNCT
eurjchem-1566	136	9	specific	specific	ADJ
eurjchem-1566	136	10	rates	rate	NOUN
eurjchem-1566	136	11	)	)	PUNCT
eurjchem-1566	136	12	for	for	ADP
eurjchem-1566	136	13	solvolysis	solvolysis	NOUN
eurjchem-1566	136	14	of	of	ADP
eurjchem-1566	136	15	4‐bromopiperidine	4‐bromopiperidine	NUM
eurjchem-1566	136	16	in	in	ADP
eurjchem-1566	136	17	a	a	DET
eurjchem-1566	136	18	wide	wide	ADJ
eurjchem-1566	136	19	variety	variety	NOUN
eurjchem-1566	136	20	of	of	ADP
eurjchem-1566	136	21	aqueous‐	aqueous‐	NOUN
eurjchem-1566	136	22	organic	organic	ADJ
eurjchem-1566	136	23	solvents	solvent	NOUN
eurjchem-1566	136	24	have	have	AUX
eurjchem-1566	136	25	been	be	AUX
eurjchem-1566	136	26	determined	determine	VERB
eurjchem-1566	136	27	at	at	ADP
eurjchem-1566	136	28	55.0	55.0	NUM
eurjchem-1566	136	29	°	°	NOUN
eurjchem-1566	136	30	c	c	NOUN
eurjchem-1566	136	31	.	.	PUNCT
eurjchem-1566	137	1	application	application	NOUN
eurjchem-1566	137	2	of	of	ADP
eurjchem-1566	137	3	the	the	DET
eurjchem-1566	137	4	simple	simple	ADJ
eurjchem-1566	137	5	(	(	PUNCT
eurjchem-1566	137	6	one‐term	one‐term	NOUN
eurjchem-1566	137	7	)	)	PUNCT
eurjchem-1566	137	8	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-1566	137	9	equation	equation	NOUN
eurjchem-1566	137	10	shows	show	VERB
eurjchem-1566	137	11	that	that	SCONJ
eurjchem-1566	137	12	,	,	PUNCT
eurjchem-1566	137	13	when	when	SCONJ
eurjchem-1566	137	14	the	the	DET
eurjchem-1566	137	15	organic	organic	ADJ
eurjchem-1566	137	16	component	component	NOUN
eurjchem-1566	137	17	is	be	AUX
eurjchem-1566	137	18	acetone	acetone	NOUN
eurjchem-1566	137	19	,	,	PUNCT
eurjchem-1566	137	20	dioxane	dioxane	NOUN
eurjchem-1566	137	21	,	,	PUNCT
eurjchem-1566	137	22	ethanol	ethanol	NOUN
eurjchem-1566	137	23	or	or	CCONJ
eurjchem-1566	137	24	methanol	methanol	VERB
eurjchem-1566	137	25	a	a	DET
eurjchem-1566	137	26	good	good	ADJ
eurjchem-1566	137	27	correlation	correlation	NOUN
eurjchem-1566	137	28	against	against	ADP
eurjchem-1566	137	29	ybr	ybr	PROPN
eurjchem-1566	137	30	values	value	NOUN
eurjchem-1566	137	31	is	be	AUX
eurjchem-1566	137	32	obtained	obtain	VERB
eurjchem-1566	137	33	,	,	PUNCT
eurjchem-1566	137	34	with	with	ADP
eurjchem-1566	137	35	a	a	DET
eurjchem-1566	137	36	slope	slope	NOUN
eurjchem-1566	137	37	of	of	ADP
eurjchem-1566	137	38	0.46±0.02	0.46±0.02	PROPN
eurjchem-1566	137	39	,	,	PUNCT
eurjchem-1566	137	40	consistent	consistent	ADJ
eurjchem-1566	137	41	with	with	ADP
eurjchem-1566	137	42	a	a	DET
eurjchem-1566	137	43	synchronous	synchronous	ADJ
eurjchem-1566	137	44	grob	grob	PROPN
eurjchem-1566	137	45	fragmentation	fragmentation	NOUN
eurjchem-1566	137	46	pathway	pathway	NOUN
eurjchem-1566	137	47	.	.	PUNCT
eurjchem-1566	138	1	when	when	SCONJ
eurjchem-1566	138	2	the	the	DET
eurjchem-1566	138	3	organic	organic	ADJ
eurjchem-1566	138	4	component	component	NOUN
eurjchem-1566	138	5	is	be	AUX
eurjchem-1566	138	6	2,2,2‐trifluoroethanol	2,2,2‐trifluoroethanol	NUM
eurjchem-1566	138	7	(	(	PUNCT
eurjchem-1566	138	8	tfe	tfe	NOUN
eurjchem-1566	138	9	)	)	PUNCT
eurjchem-1566	138	10	,	,	PUNCT
eurjchem-1566	138	11	the	the	DET
eurjchem-1566	138	12	data	data	NOUN
eurjchem-1566	138	13	points	point	VERB
eurjchem-1566	138	14	for	for	ADP
eurjchem-1566	138	15	this	this	DET
eurjchem-1566	138	16	mixed	mixed	ADJ
eurjchem-1566	138	17	solvent	solvent	NOUN
eurjchem-1566	138	18	show	show	VERB
eurjchem-1566	138	19	a	a	DET
eurjchem-1566	138	20	negative	negative	ADJ
eurjchem-1566	138	21	deviation	deviation	NOUN
eurjchem-1566	138	22	from	from	ADP
eurjchem-1566	138	23	the	the	DET
eurjchem-1566	138	24	plot	plot	NOUN
eurjchem-1566	138	25	.	.	PUNCT
eurjchem-1566	139	1	this	this	DET
eurjchem-1566	139	2	deviation	deviation	NOUN
eurjchem-1566	139	3	can	can	AUX
eurjchem-1566	139	4	be	be	AUX
eurjchem-1566	139	5	considered	consider	VERB
eurjchem-1566	139	6	to	to	PART
eurjchem-1566	139	7	result	result	VERB
eurjchem-1566	139	8	from	from	ADP
eurjchem-1566	139	9	a	a	DET
eurjchem-1566	139	10	hydrogen‐bonding	hydrogen‐bonde	VERB
eurjchem-1566	139	11	interaction	interaction	NOUN
eurjchem-1566	139	12	of	of	ADP
eurjchem-1566	139	13	the	the	DET
eurjchem-1566	139	14	acidic	acidic	ADJ
eurjchem-1566	139	15	tfe	tfe	NOUN
eurjchem-1566	139	16	component	component	NOUN
eurjchem-1566	139	17	of	of	ADP
eurjchem-1566	139	18	the	the	DET
eurjchem-1566	139	19	solvent	solvent	NOUN
eurjchem-1566	139	20	with	with	ADP
eurjchem-1566	139	21	the	the	DET
eurjchem-1566	139	22	lone	lone	ADJ
eurjchem-1566	139	23	pair	pair	NOUN
eurjchem-1566	139	24	of	of	ADP
eurjchem-1566	139	25	electrons	electron	NOUN
eurjchem-1566	139	26	on	on	ADP
eurjchem-1566	139	27	the	the	DET
eurjchem-1566	139	28	nitrogen	nitrogen	NOUN
eurjchem-1566	139	29	,	,	PUNCT
eurjchem-1566	139	30	reducing	reduce	VERB
eurjchem-1566	139	31	their	their	PRON
eurjchem-1566	139	32	ability	ability	NOUN
eurjchem-1566	139	33	to	to	PART
eurjchem-1566	139	34	promote	promote	VERB
eurjchem-1566	139	35	a	a	DET
eurjchem-1566	139	36	synchronous	synchronous	ADJ
eurjchem-1566	139	37	grob	grob	PROPN
eurjchem-1566	139	38	fragmentation	fragmentation	NOUN
eurjchem-1566	139	39	.	.	PUNCT
eurjchem-1566	140	1	parallel	parallel	ADJ
eurjchem-1566	140	2	behavior	behavior	NOUN
eurjchem-1566	140	3	in	in	ADP
eurjchem-1566	140	4	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-1566	140	5	solvents	solvent	NOUN
eurjchem-1566	140	6	has	have	AUX
eurjchem-1566	140	7	been	be	AUX
eurjchem-1566	140	8	observed	observe	VERB
eurjchem-1566	140	9	for	for	ADP
eurjchem-1566	140	10	internal	internal	ADJ
eurjchem-1566	140	11	nucleophilic	nucleophilic	ADJ
eurjchem-1566	140	12	attack	attack	NOUN
eurjchem-1566	140	13	leading	lead	VERB
eurjchem-1566	140	14	to	to	ADP
eurjchem-1566	140	15	ring	re	VERB
eurjchem-1566	140	16	formation	formation	NOUN
eurjchem-1566	140	17	[	[	X
eurjchem-1566	140	18	34	34	NUM
eurjchem-1566	140	19	]	]	PUNCT
eurjchem-1566	140	20	.	.	PUNCT
eurjchem-1566	141	1	examples	example	NOUN
eurjchem-1566	141	2	of	of	ADP
eurjchem-1566	141	3	nucleophilic	nucleophilic	ADJ
eurjchem-1566	141	4	substitution	substitution	NOUN
eurjchem-1566	141	5	reactions	reaction	NOUN
eurjchem-1566	141	6	changing	change	VERB
eurjchem-1566	141	7	from	from	ADP
eurjchem-1566	141	8	bimolecular	bimolecular	ADJ
eurjchem-1566	141	9	to	to	ADP
eurjchem-1566	141	10	unimolecular	unimolecular	ADJ
eurjchem-1566	141	11	character	character	NOUN
eurjchem-1566	141	12	on	on	ADP
eurjchem-1566	141	13	going	go	VERB
eurjchem-1566	141	14	to	to	ADP
eurjchem-1566	141	15	solvents	solvent	NOUN
eurjchem-1566	141	16	of	of	ADP
eurjchem-1566	141	17	high	high	ADJ
eurjchem-1566	141	18	yx	yx	NOUN
eurjchem-1566	141	19	value	value	NOUN
eurjchem-1566	141	20	are	be	AUX
eurjchem-1566	141	21	quite	quite	ADV
eurjchem-1566	141	22	common	common	ADJ
eurjchem-1566	141	23	[	[	X
eurjchem-1566	141	24	38	38	NUM
eurjchem-1566	141	25	]	]	PUNCT
eurjchem-1566	141	26	.	.	PUNCT
eurjchem-1566	142	1	the	the	DET
eurjchem-1566	142	2	observation	observation	NOUN
eurjchem-1566	142	3	[	[	X
eurjchem-1566	142	4	9	9	NUM
eurjchem-1566	142	5	]	]	PUNCT
eurjchem-1566	142	6	of	of	ADP
eurjchem-1566	142	7	a	a	DET
eurjchem-1566	142	8	non‐synchronous	non‐synchronous	ADJ
eurjchem-1566	142	9	route	route	NOUN
eurjchem-1566	142	10	via	via	ADP
eurjchem-1566	142	11	a	a	DET
eurjchem-1566	142	12	carbocation	carbocation	NOUN
eurjchem-1566	142	13	for	for	ADP
eurjchem-1566	142	14	the	the	DET
eurjchem-1566	142	15	grob	grob	PROPN
eurjchem-1566	142	16	fragmentation	fragmentation	NOUN
eurjchem-1566	142	17	within	within	ADP
eurjchem-1566	142	18	the	the	DET
eurjchem-1566	142	19	solvolysis	solvolysis	NOUN
eurjchem-1566	142	20	in	in	ADP
eurjchem-1566	142	21	trifluoroacetic	trifluoroacetic	ADJ
eurjchem-1566	142	22	acid	acid	NOUN
eurjchem-1566	142	23	(	(	PUNCT
eurjchem-1566	142	24	a	a	DET
eurjchem-1566	142	25	solvent	solvent	NOUN
eurjchem-1566	142	26	of	of	ADP
eurjchem-1566	142	27	very	very	ADV
eurjchem-1566	142	28	high	high	ADJ
eurjchem-1566	142	29	ionizing	ionizing	NOUN
eurjchem-1566	142	30	power	power	NOUN
eurjchem-1566	142	31	)	)	PUNCT
eurjchem-1566	142	32	of	of	ADP
eurjchem-1566	142	33	a	a	DET
eurjchem-1566	142	34	derivative	derivative	NOUN
eurjchem-1566	142	35	of	of	ADP
eurjchem-1566	142	36	tetra‐	tetra‐	PROPN
eurjchem-1566	142	37	hydropyranyl	hydropyranyl	NOUN
eurjchem-1566	142	38	mesylate	mesylate	NOUN
eurjchem-1566	142	39	is	be	AUX
eurjchem-1566	142	40	consistent	consistent	ADJ
eurjchem-1566	142	41	with	with	ADP
eurjchem-1566	142	42	such	such	DET
eurjchem-1566	142	43	a	a	DET
eurjchem-1566	142	44	dichotomy	dichotomy	NOUN
eurjchem-1566	142	45	of	of	ADP
eurjchem-1566	142	46	mechanism	mechanism	NOUN
eurjchem-1566	142	47	.	.	PUNCT
eurjchem-1566	143	1	acknowledgments	acknowledgment	NOUN
eurjchem-1566	143	2	support	support	NOUN
eurjchem-1566	143	3	is	be	AUX
eurjchem-1566	143	4	acknowledged	acknowledge	VERB
eurjchem-1566	143	5	from	from	ADP
eurjchem-1566	143	6	the	the	DET
eurjchem-1566	143	7	donors	donor	NOUN
eurjchem-1566	143	8	of	of	ADP
eurjchem-1566	143	9	the	the	DET
eurjchem-1566	143	10	american	american	PROPN
eurjchem-1566	143	11	chemical	chemical	PROPN
eurjchem-1566	143	12	society	society	PROPN
eurjchem-1566	143	13	petroleum	petroleum	PROPN
eurjchem-1566	143	14	research	research	NOUN
eurjchem-1566	143	15	fund	fund	NOUN
eurjchem-1566	143	16	(	(	PUNCT
eurjchem-1566	143	17	prf	prf	PROPN
eurjchem-1566	143	18	#	#	NOUN
eurjchem-1566	143	19	38163‐	38163‐	NUM
eurjchem-1566	143	20	ac4	ac4	PROPN
eurjchem-1566	143	21	)	)	PUNCT
eurjchem-1566	143	22	;	;	PUNCT
eurjchem-1566	143	23	the	the	DET
eurjchem-1566	143	24	national	national	PROPN
eurjchem-1566	143	25	institute	institute	PROPN
eurjchem-1566	143	26	of	of	ADP
eurjchem-1566	143	27	general	general	PROPN
eurjchem-1566	143	28	medical	medical	ADJ
eurjchem-1566	143	29	sciences‐	sciences‐	NUM
eurjchem-1566	143	30	nigms	nigms	NOUN
eurjchem-1566	143	31	(	(	PUNCT
eurjchem-1566	143	32	p20gm103446	p20gm103446	NOUN
eurjchem-1566	143	33	)	)	PUNCT
eurjchem-1566	143	34	idea	idea	NOUN
eurjchem-1566	143	35	program	program	NOUN
eurjchem-1566	143	36	from	from	ADP
eurjchem-1566	143	37	the	the	DET
eurjchem-1566	143	38	national	national	PROPN
eurjchem-1566	143	39	institutes	institutes	PROPN
eurjchem-1566	143	40	of	of	ADP
eurjchem-1566	143	41	health	health	PROPN
eurjchem-1566	143	42	(	(	PUNCT
eurjchem-1566	143	43	de‐inbre	de‐inbre	PROPN
eurjchem-1566	143	44	)	)	PUNCT
eurjchem-1566	143	45	;	;	PUNCT
eurjchem-1566	143	46	the	the	DET
eurjchem-1566	143	47	national	national	PROPN
eurjchem-1566	143	48	science	science	PROPN
eurjchem-1566	143	49	foundation	foundation	PROPN
eurjchem-1566	143	50	(	(	PUNCT
eurjchem-1566	143	51	nsf	nsf	NOUN
eurjchem-1566	143	52	)	)	PUNCT
eurjchem-1566	143	53	epscor	epscor	NOUN
eurjchem-1566	143	54	grant	grant	VERB
eurjchem-1566	143	55	iia‐1301765	iia‐1301765	PROPN
eurjchem-1566	143	56	(	(	PUNCT
eurjchem-1566	143	57	de‐epscor	de‐epscor	PROPN
eurjchem-1566	143	58	program	program	NOUN
eurjchem-1566	143	59	)	)	PUNCT
eurjchem-1566	143	60	;	;	PUNCT
eurjchem-1566	143	61	and	and	CCONJ
eurjchem-1566	143	62	the	the	DET
eurjchem-1566	143	63	delaware	delaware	PROPN
eurjchem-1566	143	64	(	(	PUNCT
eurjchem-1566	143	65	de	de	ADJ
eurjchem-1566	143	66	)	)	PUNCT
eurjchem-1566	143	67	economic	economic	ADJ
eurjchem-1566	143	68	development	development	NOUN
eurjchem-1566	143	69	office	office	PROPN
eurjchem-1566	143	70	(	(	PUNCT
eurjchem-1566	143	71	dedo	dedo	PROPN
eurjchem-1566	143	72	program	program	PROPN
eurjchem-1566	143	73	)	)	PUNCT
eurjchem-1566	143	74	.	.	PUNCT
eurjchem-1566	144	1	in	in	ADP
eurjchem-1566	144	2	addition	addition	NOUN
eurjchem-1566	144	3	,	,	PUNCT
eurjchem-1566	144	4	zoon	zoon	PROPN
eurjchem-1566	144	5	ha	ha	INTJ
eurjchem-1566	144	6	ryu	ryu	PROPN
eurjchem-1566	144	7	thanks	thanks	PROPN
eurjchem-1566	144	8	dong‐	dong‐	PROPN
eurjchem-1566	144	9	eui	eui	PROPN
eurjchem-1566	144	10	university	university	PROPN
eurjchem-1566	144	11	for	for	ADP
eurjchem-1566	144	12	support	support	NOUN
eurjchem-1566	144	13	of	of	ADP
eurjchem-1566	144	14	this	this	DET
eurjchem-1566	144	15	work	work	NOUN
eurjchem-1566	144	16	by	by	ADP
eurjchem-1566	144	17	grant	grant	PROPN
eurjchem-1566	144	18	2006aa089	2006aa089	NUM
eurjchem-1566	144	19	.	.	PUNCT
eurjchem-1566	145	1	the	the	DET
eurjchem-1566	145	2	content	content	NOUN
eurjchem-1566	145	3	is	be	AUX
eurjchem-1566	145	4	solely	solely	ADV
eurjchem-1566	145	5	the	the	DET
eurjchem-1566	145	6	responsibility	responsibility	NOUN
eurjchem-1566	145	7	of	of	ADP
eurjchem-1566	145	8	the	the	DET
eurjchem-1566	145	9	authors	author	NOUN
eurjchem-1566	145	10	and	and	CCONJ
eurjchem-1566	145	11	does	do	AUX
eurjchem-1566	145	12	not	not	PART
eurjchem-1566	145	13	necessarily	necessarily	ADV
eurjchem-1566	145	14	represent	represent	VERB
eurjchem-1566	145	15	the	the	DET
eurjchem-1566	145	16	official	official	ADJ
eurjchem-1566	145	17	views	view	NOUN
eurjchem-1566	145	18	of	of	ADP
eurjchem-1566	145	19	the	the	DET
eurjchem-1566	145	20	granting	grant	VERB
eurjchem-1566	145	21	agencies	agency	NOUN
eurjchem-1566	145	22	.	.	PUNCT
eurjchem-1566	146	1	references	reference	NOUN
eurjchem-1566	146	2	[	[	X
eurjchem-1566	146	3	1	1	NUM
eurjchem-1566	146	4	]	]	PUNCT
eurjchem-1566	146	5	.	.	PUNCT
eurjchem-1566	147	1	d'arcy	d'arcy	PROPN
eurjchem-1566	147	2	,	,	PUNCT
eurjchem-1566	147	3	r.	r.	PROPN
eurjchem-1566	147	4	;	;	PUNCT
eurjchem-1566	147	5	grob	grob	PROPN
eurjchem-1566	147	6	,	,	PUNCT
eurjchem-1566	147	7	c.	c.	PROPN
eurjchem-1566	147	8	a.	a.	PROPN
eurjchem-1566	147	9	;	;	PUNCT
eurjchem-1566	147	10	kaffenberger	kaffenberger	NOUN
eurjchem-1566	147	11	,	,	PUNCT
eurjchem-1566	147	12	t.	t.	PROPN
eurjchem-1566	147	13	;	;	PUNCT
eurjchem-1566	147	14	krasnobajew	krasnobajew	PROPN
eurjchem-1566	147	15	,	,	PUNCT
eurjchem-1566	147	16	v.	v.	PROPN
eurjchem-1566	147	17	helv	helv	PROPN
eurjchem-1566	147	18	.	.	PUNCT
eurjchem-1566	148	1	chim	chim	PROPN
eurjchem-1566	148	2	.	.	PUNCT
eurjchem-1566	149	1	acta	acta	PROPN
eurjchem-1566	149	2	.	.	PUNCT
eurjchem-1566	150	1	1966	1966	NUM
eurjchem-1566	150	2	,	,	PUNCT
eurjchem-1566	150	3	49	49	NUM
eurjchem-1566	150	4	,	,	PUNCT
eurjchem-1566	150	5	185‐203	185‐203	NUM
eurjchem-1566	150	6	.	.	PUNCT
eurjchem-1566	151	1	[	[	X
eurjchem-1566	151	2	2	2	NUM
eurjchem-1566	151	3	]	]	PUNCT
eurjchem-1566	151	4	.	.	PUNCT
eurjchem-1566	151	5	winstein	winstein	PROPN
eurjchem-1566	151	6	,	,	PUNCT
eurjchem-1566	151	7	s.	s.	PROPN
eurjchem-1566	151	8	;	;	PUNCT
eurjchem-1566	151	9	grunwald	grunwald	PROPN
eurjchem-1566	151	10	,	,	PUNCT
eurjchem-1566	151	11	e.	e.	PROPN
eurjchem-1566	151	12	;	;	PUNCT
eurjchem-1566	151	13	jones	jones	PROPN
eurjchem-1566	151	14	,	,	PUNCT
eurjchem-1566	151	15	h.	h.	PROPN
eurjchem-1566	151	16	w.	w.	PROPN
eurjchem-1566	151	17	j.	j.	PROPN
eurjchem-1566	151	18	am	am	PROPN
eurjchem-1566	151	19	.	.	PUNCT
eurjchem-1566	152	1	chem	chem	PROPN
eurjchem-1566	152	2	.	.	PUNCT
eurjchem-1566	153	1	soc	soc	PROPN
eurjchem-1566	153	2	.	.	PUNCT
eurjchem-1566	154	1	1951	1951	NUM
eurjchem-1566	154	2	,	,	PUNCT
eurjchem-1566	154	3	73	73	NUM
eurjchem-1566	154	4	,	,	PUNCT
eurjchem-1566	154	5	2700‐2707	2700‐2707	NOUN
eurjchem-1566	154	6	.	.	PUNCT
eurjchem-1566	155	1	[	[	X
eurjchem-1566	155	2	3	3	NUM
eurjchem-1566	155	3	]	]	PUNCT
eurjchem-1566	155	4	.	.	PUNCT
eurjchem-1566	156	1	kevill	kevill	PROPN
eurjchem-1566	156	2	,	,	PUNCT
eurjchem-1566	156	3	d.	d.	PROPN
eurjchem-1566	156	4	n.	n.	PROPN
eurjchem-1566	156	5	;	;	PUNCT
eurjchem-1566	156	6	d’souza	d’souza	PROPN
eurjchem-1566	156	7	,	,	PUNCT
eurjchem-1566	156	8	m.	m.	NOUN
eurjchem-1566	156	9	j.	j.	PROPN
eurjchem-1566	156	10	j.	j.	PROPN
eurjchem-1566	156	11	chem	chem	PROPN
eurjchem-1566	156	12	.	.	PUNCT
eurjchem-1566	157	1	res	re	NOUN
eurjchem-1566	157	2	.	.	PROPN
eurjchem-1566	157	3	2008	2008	NUM
eurjchem-1566	157	4	,	,	PUNCT
eurjchem-1566	157	5	61‐66	61‐66	NOUN
eurjchem-1566	157	6	.	.	PUNCT
eurjchem-1566	158	1	[	[	X
eurjchem-1566	158	2	4	4	NUM
eurjchem-1566	158	3	]	]	PUNCT
eurjchem-1566	158	4	.	.	PUNCT
eurjchem-1566	159	1	bentley	bentley	PROPN
eurjchem-1566	159	2	,	,	PUNCT
eurjchem-1566	159	3	t.	t.	PROPN
eurjchem-1566	159	4	w.	w.	PROPN
eurjchem-1566	159	5	;	;	PUNCT
eurjchem-1566	159	6	llewellyn	llewellyn	PROPN
eurjchem-1566	159	7	,	,	PUNCT
eurjchem-1566	159	8	g.	g.	PROPN
eurjchem-1566	159	9	prog	prog	PROPN
eurjchem-1566	159	10	.	.	PUNCT
eurjchem-1566	160	1	phys	phy	NOUN
eurjchem-1566	160	2	.	.	PUNCT
eurjchem-1566	161	1	org	org	PROPN
eurjchem-1566	161	2	.	.	PUNCT
eurjchem-1566	161	3	chem	chem	PROPN
eurjchem-1566	161	4	.	.	PUNCT
eurjchem-1566	162	1	1990	1990	NUM
eurjchem-1566	162	2	,	,	PUNCT
eurjchem-1566	162	3	17	17	NUM
eurjchem-1566	162	4	,	,	PUNCT
eurjchem-1566	162	5	121‐158	121‐158	NUM
eurjchem-1566	162	6	.	.	PUNCT
eurjchem-1566	163	1	[	[	X
eurjchem-1566	163	2	5	5	NUM
eurjchem-1566	163	3	]	]	PUNCT
eurjchem-1566	163	4	.	.	PUNCT
eurjchem-1566	164	1	kevill	kevill	PROPN
eurjchem-1566	164	2	,	,	PUNCT
eurjchem-1566	164	3	d.	d.	PROPN
eurjchem-1566	164	4	n.	n.	PROPN
eurjchem-1566	164	5	in	in	ADP
eurjchem-1566	164	6	advances	advance	NOUN
eurjchem-1566	164	7	in	in	ADP
eurjchem-1566	164	8	quantitative	quantitative	ADJ
eurjchem-1566	164	9	structure‐property	structure‐property	NOUN
eurjchem-1566	164	10	relationships	relationship	NOUN
eurjchem-1566	164	11	;	;	PUNCT
eurjchem-1566	164	12	charton	charton	NOUN
eurjchem-1566	164	13	,	,	PUNCT
eurjchem-1566	164	14	m.	m.	NOUN
eurjchem-1566	164	15	ed	ed	NOUN
eurjchem-1566	164	16	.	.	PUNCT
eurjchem-1566	164	17	;	;	PUNCT
eurjchem-1566	164	18	jai	jai	PROPN
eurjchem-1566	164	19	press	press	PROPN
eurjchem-1566	164	20	:	:	PUNCT
eurjchem-1566	164	21	greenwich	greenwich	PROPN
eurjchem-1566	164	22	,	,	PUNCT
eurjchem-1566	164	23	ct	ct	PROPN
eurjchem-1566	164	24	,	,	PUNCT
eurjchem-1566	164	25	usa	usa	PROPN
eurjchem-1566	164	26	,	,	PUNCT
eurjchem-1566	164	27	1996	1996	NUM
eurjchem-1566	164	28	;	;	PUNCT
eurjchem-1566	164	29	volume	volume	NOUN
eurjchem-1566	164	30	1	1	NUM
eurjchem-1566	164	31	,	,	PUNCT
eurjchem-1566	164	32	pp	pp	PROPN
eurjchem-1566	164	33	.	.	PUNCT
eurjchem-1566	164	34	81‐115	81‐115	NUM
eurjchem-1566	164	35	.	.	PUNCT
eurjchem-1566	165	1	[	[	X
eurjchem-1566	165	2	6	6	NUM
eurjchem-1566	165	3	]	]	PUNCT
eurjchem-1566	165	4	.	.	PUNCT
eurjchem-1566	166	1	grob	grob	PROPN
eurjchem-1566	166	2	,	,	PUNCT
eurjchem-1566	166	3	c.	c.	PROPN
eurjchem-1566	166	4	a.	a.	PROPN
eurjchem-1566	166	5	;	;	PUNCT
eurjchem-1566	166	6	schiess	schiess	PROPN
eurjchem-1566	166	7	,	,	PUNCT
eurjchem-1566	166	8	p.	p.	PROPN
eurjchem-1566	166	9	w.	w.	PROPN
eurjchem-1566	166	10	angew	angew	PROPN
eurjchem-1566	166	11	.	.	PUNCT
eurjchem-1566	167	1	chem	chem	PROPN
eurjchem-1566	167	2	.	.	PUNCT
eurjchem-1566	168	1	1967	1967	NUM
eurjchem-1566	168	2	,	,	PUNCT
eurjchem-1566	168	3	79	79	NUM
eurjchem-1566	168	4	,	,	PUNCT
eurjchem-1566	168	5	1‐14	1‐14	NUM
eurjchem-1566	168	6	;	;	PUNCT
eurjchem-1566	168	7	angew	angew	NOUN
eurjchem-1566	168	8	.	.	PUNCT
eurjchem-1566	169	1	chem	chem	PROPN
eurjchem-1566	169	2	.	.	PUNCT
eurjchem-1566	170	1	int	int	NOUN
eurjchem-1566	170	2	.	.	PUNCT
eurjchem-1566	171	1	ed	ed	NOUN
eurjchem-1566	171	2	.	.	PROPN
eurjchem-1566	171	3	1967	1967	NUM
eurjchem-1566	171	4	,	,	PUNCT
eurjchem-1566	171	5	6	6	NUM
eurjchem-1566	171	6	,	,	PUNCT
eurjchem-1566	171	7	1‐15	1‐15	NUM
eurjchem-1566	171	8	.	.	PUNCT
eurjchem-1566	172	1	[	[	X
eurjchem-1566	172	2	7	7	NUM
eurjchem-1566	172	3	]	]	PUNCT
eurjchem-1566	172	4	.	.	PUNCT
eurjchem-1566	173	1	grob	grob	PROPN
eurjchem-1566	173	2	,	,	PUNCT
eurjchem-1566	173	3	c.	c.	PROPN
eurjchem-1566	173	4	a.	a.	PROPN
eurjchem-1566	173	5	angew	angew	PROPN
eurjchem-1566	173	6	.	.	PUNCT
eurjchem-1566	174	1	chem	chem	PROPN
eurjchem-1566	174	2	.	.	PUNCT
eurjchem-1566	175	1	1969	1969	NUM
eurjchem-1566	175	2	,	,	PUNCT
eurjchem-1566	175	3	81	81	NUM
eurjchem-1566	175	4	,	,	PUNCT
eurjchem-1566	175	5	543‐554	543‐554	NUM
eurjchem-1566	175	6	;	;	PUNCT
eurjchem-1566	175	7	angew	angew	NOUN
eurjchem-1566	175	8	.	.	PUNCT
eurjchem-1566	176	1	chem	chem	PROPN
eurjchem-1566	176	2	.	.	PUNCT
eurjchem-1566	177	1	int	int	NOUN
eurjchem-1566	177	2	.	.	PUNCT
eurjchem-1566	178	1	ed	ed	NOUN
eurjchem-1566	178	2	.	.	PROPN
eurjchem-1566	178	3	1969	1969	NUM
eurjchem-1566	178	4	,	,	PUNCT
eurjchem-1566	178	5	8	8	NUM
eurjchem-1566	178	6	,	,	PUNCT
eurjchem-1566	178	7	535‐546	535‐546	NUM
eurjchem-1566	178	8	.	.	PUNCT
eurjchem-1566	179	1	[	[	X
eurjchem-1566	179	2	8	8	NUM
eurjchem-1566	179	3	]	]	PUNCT
eurjchem-1566	179	4	.	.	PUNCT
eurjchem-1566	180	1	lowry	lowry	PROPN
eurjchem-1566	180	2	,	,	PUNCT
eurjchem-1566	180	3	t.	t.	PROPN
eurjchem-1566	180	4	h.	h.	PROPN
eurjchem-1566	180	5	;	;	PUNCT
eurjchem-1566	180	6	richardson	richardson	PROPN
eurjchem-1566	180	7	,	,	PUNCT
eurjchem-1566	180	8	k.	k.	PROPN
eurjchem-1566	180	9	s.	s.	PROPN
eurjchem-1566	180	10	mechanism	mechanism	NOUN
eurjchem-1566	180	11	and	and	CCONJ
eurjchem-1566	180	12	theory	theory	NOUN
eurjchem-1566	180	13	in	in	ADP
eurjchem-1566	180	14	organic	organic	ADJ
eurjchem-1566	180	15	chemistry	chemistry	NOUN
eurjchem-1566	180	16	,	,	PUNCT
eurjchem-1566	180	17	3rd	3rd	NOUN
eurjchem-1566	180	18	.	.	PUNCT
eurjchem-1566	181	1	ed	ed	NOUN
eurjchem-1566	181	2	.	.	PUNCT
eurjchem-1566	181	3	;	;	PUNCT
eurjchem-1566	181	4	harper	harper	NOUN
eurjchem-1566	181	5	and	and	CCONJ
eurjchem-1566	181	6	row	row	NOUN
eurjchem-1566	181	7	:	:	PUNCT
eurjchem-1566	181	8	new	new	PROPN
eurjchem-1566	181	9	york	york	PROPN
eurjchem-1566	181	10	,	,	PUNCT
eurjchem-1566	181	11	ny	ny	PROPN
eurjchem-1566	181	12	,	,	PUNCT
eurjchem-1566	181	13	usa	usa	PROPN
eurjchem-1566	181	14	,	,	PUNCT
eurjchem-1566	181	15	1987	1987	NUM
eurjchem-1566	181	16	;	;	PUNCT
eurjchem-1566	181	17	pp	pp	X
eurjchem-1566	181	18	.	.	PUNCT
eurjchem-1566	182	1	373‐375	373‐375	NUM
eurjchem-1566	182	2	.	.	PUNCT
eurjchem-1566	183	1	[	[	X
eurjchem-1566	183	2	9	9	NUM
eurjchem-1566	183	3	]	]	PUNCT
eurjchem-1566	183	4	.	.	PUNCT
eurjchem-1566	183	5	jasti	jasti	PROPN
eurjchem-1566	183	6	,	,	PUNCT
eurjchem-1566	183	7	r.	r.	PROPN
eurjchem-1566	183	8	;	;	PUNCT
eurjchem-1566	183	9	rychonovsky	rychonovsky	ADJ
eurjchem-1566	183	10	,	,	PUNCT
eurjchem-1566	183	11	s.	s.	PROPN
eurjchem-1566	183	12	d.	d.	PROPN
eurjchem-1566	183	13	org	org	PROPN
eurjchem-1566	183	14	.	.	PUNCT
eurjchem-1566	184	1	lett	lett	PROPN
eurjchem-1566	184	2	.	.	PUNCT
eurjchem-1566	185	1	2006	2006	NUM
eurjchem-1566	185	2	,	,	PUNCT
eurjchem-1566	185	3	8	8	NUM
eurjchem-1566	185	4	,	,	PUNCT
eurjchem-1566	185	5	2175‐2178	2175‐2178	NUM
eurjchem-1566	185	6	.	.	PUNCT
eurjchem-1566	186	1	[	[	X
eurjchem-1566	186	2	10	10	NUM
eurjchem-1566	186	3	]	]	PUNCT
eurjchem-1566	186	4	.	.	PUNCT
eurjchem-1566	187	1	snider	snider	PROPN
eurjchem-1566	187	2	,	,	PUNCT
eurjchem-1566	187	3	b.	b.	PROPN
eurjchem-1566	187	4	b.	b.	PROPN
eurjchem-1566	188	1	the	the	DET
eurjchem-1566	188	2	prins	prins	PROPN
eurjchem-1566	188	3	reaction	reaction	NOUN
eurjchem-1566	188	4	and	and	CCONJ
eurjchem-1566	188	5	carbonyl	carbonyl	NOUN
eurjchem-1566	188	6	ene	ene	NOUN
eurjchem-1566	188	7	reactions	reaction	NOUN
eurjchem-1566	188	8	,	,	PUNCT
eurjchem-1566	188	9	eds	ed	NOUN
eurjchem-1566	188	10	.	.	PUNCT
eurjchem-1566	188	11	trost	trost	PROPN
eurjchem-1566	188	12	,	,	PUNCT
eurjchem-1566	188	13	b.	b.	PROPN
eurjchem-1566	188	14	m.	m.	PROPN
eurjchem-1566	188	15	,	,	PUNCT
eurjchem-1566	188	16	fleming	fleming	PROPN
eurjchem-1566	188	17	,	,	PUNCT
eurjchem-1566	188	18	i.	i.	NOUN
eurjchem-1566	188	19	,	,	PUNCT
eurjchem-1566	188	20	and	and	CCONJ
eurjchem-1566	188	21	heathcock	heathcock	PROPN
eurjchem-1566	188	22	,	,	PUNCT
eurjchem-1566	188	23	c.	c.	PROPN
eurjchem-1566	188	24	h.	h.	PROPN
eurjchem-1566	188	25	pergamon	pergamon	PROPN
eurjchem-1566	188	26	press	press	PROPN
eurjchem-1566	188	27	,	,	PUNCT
eurjchem-1566	188	28	new	new	PROPN
eurjchem-1566	188	29	york	york	PROPN
eurjchem-1566	188	30	,	,	PUNCT
eurjchem-1566	188	31	ny	ny	PROPN
eurjchem-1566	188	32	,	,	PUNCT
eurjchem-1566	188	33	1991	1991	NUM
eurjchem-1566	188	34	,	,	PUNCT
eurjchem-1566	188	35	vol	vol	NOUN
eurjchem-1566	188	36	.	.	PROPN
eurjchem-1566	188	37	2	2	NUM
eurjchem-1566	188	38	,	,	PUNCT
eurjchem-1566	188	39	pp	pp	ADJ
eurjchem-1566	188	40	.	.	PUNCT
eurjchem-1566	189	1	527‐561	527‐561	PROPN
eurjchem-1566	189	2	.	.	PUNCT
eurjchem-1566	190	1	kevill	kevill	AUX
eurjchem-1566	190	2	et	et	PROPN
eurjchem-1566	190	3	al	al	PROPN
eurjchem-1566	190	4	.	.	PUNCT
eurjchem-1566	190	5	/	/	SYM
eurjchem-1566	190	6	european	european	PROPN
eurjchem-1566	190	7	journal	journal	PROPN
eurjchem-1566	190	8	of	of	ADP
eurjchem-1566	190	9	chemistry	chemistry	NOUN
eurjchem-1566	190	10	8	8	NUM
eurjchem-1566	190	11	(	(	PUNCT
eurjchem-1566	190	12	2	2	NUM
eurjchem-1566	190	13	)	)	PUNCT
eurjchem-1566	190	14	(	(	PUNCT
eurjchem-1566	190	15	2017	2017	NUM
eurjchem-1566	190	16	)	)	PUNCT
eurjchem-1566	190	17	162‐167	162‐167	NUM
eurjchem-1566	190	18	167	167	NUM
eurjchem-1566	191	1	[	[	X
eurjchem-1566	191	2	11	11	NUM
eurjchem-1566	191	3	]	]	PUNCT
eurjchem-1566	191	4	.	.	PUNCT
eurjchem-1566	192	1	lee	lee	PROPN
eurjchem-1566	192	2	,	,	PUNCT
eurjchem-1566	192	3	c.	c.	PROPN
eurjchem-1566	192	4	l.	l.	PROPN
eurjchem-1566	192	5	k.	k.	PROPN
eurjchem-1566	192	6	;	;	PUNCT
eurjchem-1566	192	7	lee	lee	PROPN
eurjchem-1566	192	8	,	,	PUNCT
eurjchem-1566	192	9	c.	c.	PROPN
eurjchem-1566	192	10	h.	h.	PROPN
eurjchem-1566	192	11	a.	a.	PROPN
eurjchem-1566	192	12	;	;	PUNCT
eurjchem-1566	192	13	tan	tan	PROPN
eurjchem-1566	192	14	k.	k.	PROPN
eurjchem-1566	192	15	t.	t.	PROPN
eurjchem-1566	192	16	;	;	PUNCT
eurjchem-1566	192	17	loh	loh	PROPN
eurjchem-1566	192	18	,	,	PUNCT
eurjchem-1566	192	19	t.	t.	PROPN
eurjchem-1566	192	20	p.	p.	PROPN
eurjchem-1566	192	21	org	org	PROPN
eurjchem-1566	192	22	.	.	PUNCT
eurjchem-1566	193	1	lett	lett	PROPN
eurjchem-1566	193	2	.	.	PUNCT
eurjchem-1566	194	1	2004	2004	NUM
eurjchem-1566	194	2	,	,	PUNCT
eurjchem-1566	194	3	6	6	NUM
eurjchem-1566	194	4	,	,	PUNCT
eurjchem-1566	194	5	1281‐	1281‐	NUM
eurjchem-1566	194	6	1283	1283	NUM
eurjchem-1566	194	7	.	.	PUNCT
eurjchem-1566	195	1	[	[	X
eurjchem-1566	195	2	12	12	NUM
eurjchem-1566	195	3	]	]	PUNCT
eurjchem-1566	195	4	.	.	PUNCT
eurjchem-1566	196	1	kevill	kevill	PROPN
eurjchem-1566	196	2	,	,	PUNCT
eurjchem-1566	196	3	d.	d.	PROPN
eurjchem-1566	196	4	n.	n.	PROPN
eurjchem-1566	196	5	;	;	PUNCT
eurjchem-1566	196	6	kolwyck	kolwyck	PROPN
eurjchem-1566	196	7	k.	k.	PROPN
eurjchem-1566	196	8	c.	c.	PROPN
eurjchem-1566	196	9	;	;	PUNCT
eurjchem-1566	196	10	weitl	weitl	PROPN
eurjchem-1566	196	11	,	,	PUNCT
eurjchem-1566	196	12	f.	f.	PROPN
eurjchem-1566	196	13	l.	l.	PROPN
eurjchem-1566	196	14	j.	j.	PROPN
eurjchem-1566	196	15	am	am	PROPN
eurjchem-1566	196	16	.	.	PUNCT
eurjchem-1566	197	1	chem	chem	PROPN
eurjchem-1566	197	2	.	.	PUNCT
eurjchem-1566	198	1	soc	soc	PROPN
eurjchem-1566	198	2	.	.	PUNCT
eurjchem-1566	199	1	1970	1970	NUM
eurjchem-1566	199	2	,	,	PUNCT
eurjchem-1566	199	3	92	92	NUM
eurjchem-1566	199	4	,	,	PUNCT
eurjchem-1566	199	5	7300‐7306	7300‐7306	NOUN
eurjchem-1566	199	6	.	.	PUNCT
eurjchem-1566	200	1	[	[	X
eurjchem-1566	200	2	13	13	NUM
eurjchem-1566	200	3	]	]	PUNCT
eurjchem-1566	200	4	.	.	PUNCT
eurjchem-1566	201	1	kevill	kevill	PROPN
eurjchem-1566	201	2	,	,	PUNCT
eurjchem-1566	201	3	d.	d.	PROPN
eurjchem-1566	201	4	n.	n.	PROPN
eurjchem-1566	201	5	;	;	PUNCT
eurjchem-1566	201	6	dorsey	dorsey	PROPN
eurjchem-1566	201	7	,	,	PUNCT
eurjchem-1566	201	8	j.	j.	PROPN
eurjchem-1566	201	9	e.	e.	PROPN
eurjchem-1566	201	10	j.	j.	PROPN
eurjchem-1566	201	11	org	org	PROPN
eurjchem-1566	201	12	.	.	PUNCT
eurjchem-1566	201	13	chem	chem	PROPN
eurjchem-1566	201	14	.	.	PUNCT
eurjchem-1566	202	1	1969	1969	NUM
eurjchem-1566	202	2	,	,	PUNCT
eurjchem-1566	202	3	34	34	NUM
eurjchem-1566	202	4	,	,	PUNCT
eurjchem-1566	202	5	1985‐1987	1985‐1987	NUM
eurjchem-1566	202	6	.	.	PUNCT
eurjchem-1566	203	1	[	[	X
eurjchem-1566	203	2	14	14	NUM
eurjchem-1566	203	3	]	]	PUNCT
eurjchem-1566	203	4	.	.	PUNCT
eurjchem-1566	204	1	rappoport	rappoport	PROPN
eurjchem-1566	204	2	,	,	PUNCT
eurjchem-1566	204	3	z.	z.	PROPN
eurjchem-1566	204	4	;	;	PUNCT
eurjchem-1566	204	5	kaspi	kaspi	PROPN
eurjchem-1566	204	6	,	,	PUNCT
eurjchem-1566	204	7	j.	j.	PROPN
eurjchem-1566	204	8	j.	j.	PROPN
eurjchem-1566	204	9	am	am	PROPN
eurjchem-1566	204	10	.	.	PUNCT
eurjchem-1566	205	1	chem	chem	PROPN
eurjchem-1566	205	2	.	.	PUNCT
eurjchem-1566	206	1	soc	soc	PROPN
eurjchem-1566	206	2	.	.	PUNCT
eurjchem-1566	207	1	1974	1974	NUM
eurjchem-1566	207	2	,	,	PUNCT
eurjchem-1566	207	3	96	96	NUM
eurjchem-1566	207	4	,	,	PUNCT
eurjchem-1566	207	5	4518‐4530	4518‐4530	NUM
eurjchem-1566	207	6	.	.	PUNCT
eurjchem-1566	208	1	[	[	X
eurjchem-1566	208	2	15	15	NUM
eurjchem-1566	208	3	]	]	PUNCT
eurjchem-1566	208	4	.	.	PUNCT
eurjchem-1566	208	5	bentley	bentley	PROPN
eurjchem-1566	208	6	,	,	PUNCT
eurjchem-1566	208	7	t.	t.	PROPN
eurjchem-1566	208	8	w.	w.	PROPN
eurjchem-1566	208	9	;	;	PUNCT
eurjchem-1566	208	10	carter	carter	PROPN
eurjchem-1566	208	11	,	,	PUNCT
eurjchem-1566	208	12	g.	g.	PROPN
eurjchem-1566	208	13	e.	e.	PROPN
eurjchem-1566	208	14	j.	j.	PROPN
eurjchem-1566	208	15	am	am	PROPN
eurjchem-1566	208	16	.	.	PUNCT
eurjchem-1566	209	1	chem	chem	PROPN
eurjchem-1566	209	2	.	.	PUNCT
eurjchem-1566	210	1	soc	soc	PROPN
eurjchem-1566	210	2	.	.	PUNCT
eurjchem-1566	211	1	1982	1982	NUM
eurjchem-1566	211	2	,	,	PUNCT
eurjchem-1566	211	3	104	104	NUM
eurjchem-1566	211	4	,	,	PUNCT
eurjchem-1566	211	5	5741‐5747	5741‐5747	PROPN
eurjchem-1566	211	6	.	.	PUNCT
eurjchem-1566	212	1	[	[	X
eurjchem-1566	212	2	16	16	NUM
eurjchem-1566	212	3	]	]	PUNCT
eurjchem-1566	212	4	.	.	PUNCT
eurjchem-1566	213	1	lee	lee	PROPN
eurjchem-1566	213	2	,	,	PUNCT
eurjchem-1566	213	3	i.	i.	PROPN
eurjchem-1566	213	4	;	;	PUNCT
eurjchem-1566	213	5	lee	lee	PROPN
eurjchem-1566	213	6	,	,	PUNCT
eurjchem-1566	213	7	h.	h.	PROPN
eurjchem-1566	213	8	w.	w.	PROPN
eurjchem-1566	213	9	;	;	PUNCT
eurjchem-1566	213	10	uhm	uhm	PROPN
eurjchem-1566	213	11	,	,	PUNCT
eurjchem-1566	213	12	t.	t.	PROPN
eurjchem-1566	213	13	s.	s.	PROPN
eurjchem-1566	213	14	;	;	PUNCT
eurjchem-1566	213	15	sung	sung	PROPN
eurjchem-1566	213	16	d.	d.	PROPN
eurjchem-1566	213	17	d.	d.	PROPN
eurjchem-1566	213	18	;	;	PUNCT
eurjchem-1566	213	19	ryu	ryu	PROPN
eurjchem-1566	213	20	,	,	PUNCT
eurjchem-1566	213	21	z.	z.	PROPN
eurjchem-1566	213	22	h.	h.	PROPN
eurjchem-1566	213	23	j.	j.	PROPN
eurjchem-1566	213	24	korean	korean	PROPN
eurjchem-1566	213	25	chem	chem	PROPN
eurjchem-1566	213	26	.	.	PUNCT
eurjchem-1566	214	1	soc	soc	PROPN
eurjchem-1566	214	2	.	.	PUNCT
eurjchem-1566	215	1	1988	1988	NUM
eurjchem-1566	215	2	,	,	PUNCT
eurjchem-1566	215	3	32	32	NUM
eurjchem-1566	215	4	,	,	PUNCT
eurjchem-1566	215	5	85‐93	85‐93	NUM
eurjchem-1566	215	6	.	.	PUNCT
eurjchem-1566	216	1	[	[	X
eurjchem-1566	216	2	17	17	NUM
eurjchem-1566	216	3	]	]	PUNCT
eurjchem-1566	216	4	.	.	PUNCT
eurjchem-1566	217	1	koh	koh	PROPN
eurjchem-1566	217	2	,	,	PUNCT
eurjchem-1566	217	3	h.	h.	PROPN
eurjchem-1566	217	4	j.	j.	PROPN
eurjchem-1566	217	5	;	;	PUNCT
eurjchem-1566	217	6	han	han	PROPN
eurjchem-1566	217	7	,	,	PUNCT
eurjchem-1566	217	8	k.	k.	PROPN
eurjchem-1566	217	9	l.	l.	PROPN
eurjchem-1566	217	10	;	;	PUNCT
eurjchem-1566	217	11	lee	lee	PROPN
eurjchem-1566	217	12	h.	h.	PROPN
eurjchem-1566	217	13	w.	w.	PROPN
eurjchem-1566	217	14	;	;	PUNCT
eurjchem-1566	217	15	lee	lee	PROPN
eurjchem-1566	217	16	,	,	PUNCT
eurjchem-1566	217	17	i.	i.	PROPN
eurjchem-1566	217	18	j.	j.	PROPN
eurjchem-1566	217	19	org	org	PROPN
eurjchem-1566	217	20	.	.	PUNCT
eurjchem-1566	217	21	chem	chem	PROPN
eurjchem-1566	217	22	.	.	PUNCT
eurjchem-1566	218	1	1998	1998	NUM
eurjchem-1566	218	2	,	,	PUNCT
eurjchem-1566	218	3	63	63	NUM
eurjchem-1566	218	4	,	,	PUNCT
eurjchem-1566	218	5	9834‐	9834‐	NUM
eurjchem-1566	218	6	9839	9839	NUM
eurjchem-1566	218	7	.	.	PUNCT
eurjchem-1566	219	1	[	[	X
eurjchem-1566	219	2	18	18	NUM
eurjchem-1566	219	3	]	]	PUNCT
eurjchem-1566	219	4	.	.	PUNCT
eurjchem-1566	220	1	grunwald	grunwald	PROPN
eurjchem-1566	220	2	,	,	PUNCT
eurjchem-1566	220	3	e.	e.	PROPN
eurjchem-1566	220	4	;	;	PUNCT
eurjchem-1566	220	5	winstein	winstein	PROPN
eurjchem-1566	220	6	,	,	PUNCT
eurjchem-1566	220	7	s.	s.	PROPN
eurjchem-1566	220	8	j.	j.	PROPN
eurjchem-1566	220	9	am	am	PROPN
eurjchem-1566	220	10	.	.	PUNCT
eurjchem-1566	221	1	chem	chem	PROPN
eurjchem-1566	221	2	.	.	PUNCT
eurjchem-1566	222	1	soc	soc	PROPN
eurjchem-1566	222	2	.	.	PUNCT
eurjchem-1566	223	1	1948	1948	NUM
eurjchem-1566	223	2	,	,	PUNCT
eurjchem-1566	223	3	70	70	NUM
eurjchem-1566	223	4	,	,	PUNCT
eurjchem-1566	223	5	846‐854	846‐854	NUM
eurjchem-1566	223	6	.	.	PUNCT
eurjchem-1566	224	1	[	[	X
eurjchem-1566	224	2	19	19	NUM
eurjchem-1566	224	3	]	]	PUNCT
eurjchem-1566	224	4	.	.	PUNCT
eurjchem-1566	224	5	schadt	schadt	PROPN
eurjchem-1566	224	6	,	,	PUNCT
eurjchem-1566	224	7	f.	f.	PROPN
eurjchem-1566	224	8	l.	l.	PROPN
eurjchem-1566	224	9	;	;	PUNCT
eurjchem-1566	224	10	bentley	bentley	PROPN
eurjchem-1566	224	11	,	,	PUNCT
eurjchem-1566	224	12	t.	t.	PROPN
eurjchem-1566	224	13	w.	w.	PROPN
eurjchem-1566	224	14	;	;	PUNCT
eurjchem-1566	224	15	schleyer	schleyer	PROPN
eurjchem-1566	224	16	,	,	PUNCT
eurjchem-1566	224	17	p.	p.	NOUN
eurjchem-1566	224	18	v.	v.	PROPN
eurjchem-1566	224	19	r.	r.	PROPN
eurjchem-1566	224	20	j.	j.	PROPN
eurjchem-1566	224	21	am	am	PROPN
eurjchem-1566	224	22	.	.	PUNCT
eurjchem-1566	225	1	chem	chem	PROPN
eurjchem-1566	225	2	.	.	PUNCT
eurjchem-1566	226	1	soc	soc	PROPN
eurjchem-1566	226	2	.	.	PUNCT
eurjchem-1566	227	1	1976	1976	NUM
eurjchem-1566	227	2	,	,	PUNCT
eurjchem-1566	227	3	98	98	NUM
eurjchem-1566	227	4	,	,	PUNCT
eurjchem-1566	227	5	7667‐7675	7667‐7675	NUM
eurjchem-1566	227	6	.	.	PUNCT
eurjchem-1566	228	1	[	[	X
eurjchem-1566	228	2	20	20	NUM
eurjchem-1566	228	3	]	]	PUNCT
eurjchem-1566	228	4	.	.	PUNCT
eurjchem-1566	229	1	kevill	kevill	PROPN
eurjchem-1566	229	2	,	,	PUNCT
eurjchem-1566	229	3	d.	d.	PROPN
eurjchem-1566	229	4	n.	n.	PROPN
eurjchem-1566	229	5	;	;	PUNCT
eurjchem-1566	230	1	anderson	anderson	PROPN
eurjchem-1566	230	2	,	,	PUNCT
eurjchem-1566	230	3	s.	s.	PROPN
eurjchem-1566	230	4	w.	w.	PROPN
eurjchem-1566	230	5	j.	j.	PROPN
eurjchem-1566	230	6	org	org	PROPN
eurjchem-1566	230	7	.	.	PUNCT
eurjchem-1566	230	8	chem	chem	PROPN
eurjchem-1566	230	9	.	.	PUNCT
eurjchem-1566	230	10	1991	1991	NUM
eurjchem-1566	230	11	,	,	PUNCT
eurjchem-1566	230	12	56	56	NUM
eurjchem-1566	230	13	,	,	PUNCT
eurjchem-1566	230	14	1845‐1850	1845‐1850	NUM
eurjchem-1566	230	15	.	.	PUNCT
eurjchem-1566	231	1	[	[	X
eurjchem-1566	231	2	21	21	NUM
eurjchem-1566	231	3	]	]	PUNCT
eurjchem-1566	231	4	.	.	PUNCT
eurjchem-1566	231	5	kevill	kevill	PROPN
eurjchem-1566	231	6	,	,	PUNCT
eurjchem-1566	231	7	d.	d.	PROPN
eurjchem-1566	231	8	n.	n.	PROPN
eurjchem-1566	231	9	;	;	PUNCT
eurjchem-1566	231	10	rissmann	rissmann	PROPN
eurjchem-1566	231	11	,	,	PUNCT
eurjchem-1566	231	12	t.	t.	PROPN
eurjchem-1566	231	13	j.	j.	PROPN
eurjchem-1566	231	14	j.	j.	PROPN
eurjchem-1566	231	15	chem	chem	PROPN
eurjchem-1566	231	16	.	.	PUNCT
eurjchem-1566	232	1	soc	soc	PROPN
eurjchem-1566	232	2	.	.	PUNCT
eurjchem-1566	232	3	,	,	PUNCT
eurjchem-1566	232	4	perkin	perkin	PROPN
eurjchem-1566	232	5	trans	trans	PROPN
eurjchem-1566	232	6	.	.	PROPN
eurjchem-1566	233	1	2	2	NUM
eurjchem-1566	233	2	1984	1984	NUM
eurjchem-1566	233	3	,	,	PUNCT
eurjchem-1566	233	4	717‐	717‐	NUM
eurjchem-1566	233	5	720	720	NUM
eurjchem-1566	233	6	.	.	PUNCT
eurjchem-1566	234	1	[	[	X
eurjchem-1566	234	2	22	22	NUM
eurjchem-1566	234	3	]	]	PUNCT
eurjchem-1566	234	4	.	.	PUNCT
eurjchem-1566	235	1	kevill	kevill	PROPN
eurjchem-1566	235	2	,	,	PUNCT
eurjchem-1566	235	3	d.	d.	PROPN
eurjchem-1566	235	4	n.	n.	PROPN
eurjchem-1566	235	5	;	;	PUNCT
eurjchem-1566	235	6	d’souza	d’souza	PROPN
eurjchem-1566	235	7	,	,	PUNCT
eurjchem-1566	235	8	m.	m.	NOUN
eurjchem-1566	235	9	j.	j.	PROPN
eurjchem-1566	235	10	j.	j.	PROPN
eurjchem-1566	235	11	org	org	PROPN
eurjchem-1566	235	12	.	.	PUNCT
eurjchem-1566	235	13	chem	chem	PROPN
eurjchem-1566	235	14	.	.	PUNCT
eurjchem-1566	236	1	1998	1998	NUM
eurjchem-1566	236	2	,	,	PUNCT
eurjchem-1566	236	3	63	63	NUM
eurjchem-1566	236	4	,	,	PUNCT
eurjchem-1566	236	5	2120‐2128	2120‐2128	NUM
eurjchem-1566	236	6	.	.	PUNCT
eurjchem-1566	237	1	[	[	X
eurjchem-1566	237	2	23	23	NUM
eurjchem-1566	237	3	]	]	PUNCT
eurjchem-1566	237	4	.	.	PUNCT
eurjchem-1566	238	1	d’souza	d’souza	PROPN
eurjchem-1566	238	2	,	,	PUNCT
eurjchem-1566	238	3	m.	m.	NOUN
eurjchem-1566	238	4	j.	j.	PROPN
eurjchem-1566	238	5	;	;	PUNCT
eurjchem-1566	238	6	sandosky	sandosky	PROPN
eurjchem-1566	238	7	,	,	PUNCT
eurjchem-1566	238	8	b.	b.	PROPN
eurjchem-1566	238	9	;	;	PUNCT
eurjchem-1566	238	10	fernandez‐bueno	fernandez‐bueno	PROPN
eurjchem-1566	238	11	,	,	PUNCT
eurjchem-1566	238	12	g.	g.	PROPN
eurjchem-1566	238	13	a.	a.	PROPN
eurjchem-1566	238	14	;	;	PUNCT
eurjchem-1566	238	15	mcaneny	mcaneny	PROPN
eurjchem-1566	238	16	m.	m.	PROPN
eurjchem-1566	238	17	j.	j.	PROPN
eurjchem-1566	238	18	;	;	PUNCT
eurjchem-1566	238	19	kevill	kevill	PROPN
eurjchem-1566	238	20	,	,	PUNCT
eurjchem-1566	238	21	d.	d.	PROPN
eurjchem-1566	238	22	n.	n.	PROPN
eurjchem-1566	238	23	can	can	AUX
eurjchem-1566	238	24	.	.	PUNCT
eurjchem-1566	239	1	chem	chem	PROPN
eurjchem-1566	239	2	.	.	PUNCT
eurjchem-1566	240	1	trans	trans	PROPN
eurjchem-1566	240	2	.	.	PROPN
eurjchem-1566	240	3	2014	2014	NUM
eurjchem-1566	240	4	,	,	PUNCT
eurjchem-1566	240	5	2	2	NUM
eurjchem-1566	240	6	,	,	PUNCT
eurjchem-1566	240	7	160‐174	160‐174	NUM
eurjchem-1566	240	8	.	.	PUNCT
eurjchem-1566	241	1	[	[	X
eurjchem-1566	241	2	24	24	NUM
eurjchem-1566	241	3	]	]	PUNCT
eurjchem-1566	241	4	.	.	PUNCT
eurjchem-1566	242	1	kevill	kevill	PROPN
eurjchem-1566	242	2	,	,	PUNCT
eurjchem-1566	242	3	d.	d.	PROPN
eurjchem-1566	242	4	n.	n.	PROPN
eurjchem-1566	242	5	;	;	PUNCT
eurjchem-1566	242	6	d’souza	d’souza	PROPN
eurjchem-1566	242	7	m.	m.	NOUN
eurjchem-1566	242	8	j.	j.	PROPN
eurjchem-1566	242	9	;	;	PUNCT
eurjchem-1566	242	10	ren	ren	PROPN
eurjchem-1566	242	11	,	,	PUNCT
eurjchem-1566	242	12	h.	h.	PROPN
eurjchem-1566	242	13	can	can	AUX
eurjchem-1566	242	14	.	.	PUNCT
eurjchem-1566	243	1	j.	j.	PROPN
eurjchem-1566	243	2	chem	chem	PROPN
eurjchem-1566	243	3	.	.	PUNCT
eurjchem-1566	244	1	1998	1998	NUM
eurjchem-1566	244	2	,	,	PUNCT
eurjchem-1566	244	3	76	76	NUM
eurjchem-1566	244	4	,	,	PUNCT
eurjchem-1566	244	5	751‐757	751‐757	PROPN
eurjchem-1566	244	6	.	.	PUNCT
eurjchem-1566	245	1	[	[	X
eurjchem-1566	245	2	25	25	NUM
eurjchem-1566	245	3	]	]	PUNCT
eurjchem-1566	245	4	.	.	PUNCT
eurjchem-1566	246	1	kevill	kevill	PROPN
eurjchem-1566	246	2	,	,	PUNCT
eurjchem-1566	246	3	d.	d.	PROPN
eurjchem-1566	246	4	n.	n.	PROPN
eurjchem-1566	246	5	;	;	PUNCT
eurjchem-1566	246	6	d’souza	d’souza	PROPN
eurjchem-1566	246	7	,	,	PUNCT
eurjchem-1566	246	8	m.	m.	NOUN
eurjchem-1566	246	9	j.	j.	PROPN
eurjchem-1566	246	10	j.	j.	PROPN
eurjchem-1566	246	11	chem	chem	PROPN
eurjchem-1566	246	12	res	re	NOUN
eurjchem-1566	246	13	.	.	PUNCT
eurjchem-1566	247	1	(	(	PUNCT
eurjchem-1566	247	2	s	s	NOUN
eurjchem-1566	247	3	)	)	PUNCT
eurjchem-1566	247	4	1994	1994	NUM
eurjchem-1566	247	5	,	,	PUNCT
eurjchem-1566	247	6	190‐191	190‐191	NUM
eurjchem-1566	247	7	.	.	PUNCT
eurjchem-1566	248	1	[	[	X
eurjchem-1566	248	2	26	26	NUM
eurjchem-1566	248	3	]	]	PUNCT
eurjchem-1566	248	4	.	.	PUNCT
eurjchem-1566	249	1	mcmanus	mcmanus	PROPN
eurjchem-1566	249	2	,	,	PUNCT
eurjchem-1566	249	3	s.	s.	PROPN
eurjchem-1566	249	4	p.	p.	PROPN
eurjchem-1566	249	5	;	;	PUNCT
eurjchem-1566	249	6	neamati‐mazrach	neamati‐mazrach	PROPN
eurjchem-1566	249	7	,	,	PUNCT
eurjchem-1566	249	8	n.	n.	NOUN
eurjchem-1566	249	9	;	;	PUNCT
eurjchem-1566	249	10	hovanes	hovane	NOUN
eurjchem-1566	249	11	,	,	PUNCT
eurjchem-1566	249	12	b.	b.	PROPN
eurjchem-1566	249	13	a.	a.	PROPN
eurjchem-1566	249	14	;	;	PUNCT
eurjchem-1566	249	15	paley	paley	PROPN
eurjchem-1566	249	16	m.	m.	PROPN
eurjchem-1566	249	17	s.	s.	PROPN
eurjchem-1566	249	18	;	;	PUNCT
eurjchem-1566	249	19	harris	harris	PROPN
eurjchem-1566	249	20	,	,	PUNCT
eurjchem-1566	249	21	j.	j.	PROPN
eurjchem-1566	249	22	m.	m.	PROPN
eurjchem-1566	249	23	j.	j.	PROPN
eurjchem-1566	249	24	am	am	PROPN
eurjchem-1566	249	25	.	.	PUNCT
eurjchem-1566	250	1	chem	chem	PROPN
eurjchem-1566	250	2	.	.	PUNCT
eurjchem-1566	251	1	soc	soc	PROPN
eurjchem-1566	251	2	.	.	PUNCT
eurjchem-1566	252	1	1985	1985	NUM
eurjchem-1566	252	2	,	,	PUNCT
eurjchem-1566	252	3	107	107	NUM
eurjchem-1566	252	4	,	,	PUNCT
eurjchem-1566	252	5	3392‐3393	3392‐3393	NUM
eurjchem-1566	252	6	.	.	PUNCT
eurjchem-1566	253	1	[	[	X
eurjchem-1566	253	2	27	27	NUM
eurjchem-1566	253	3	]	]	PUNCT
eurjchem-1566	253	4	.	.	PUNCT
eurjchem-1566	254	1	mcmanus	mcmanus	PROPN
eurjchem-1566	254	2	,	,	PUNCT
eurjchem-1566	254	3	s.	s.	PROPN
eurjchem-1566	254	4	p.	p.	PROPN
eurjchem-1566	254	5	;	;	PUNCT
eurjchem-1566	254	6	sedaghat‐herati	sedaghat‐herati	PROPN
eurjchem-1566	254	7	,	,	PUNCT
eurjchem-1566	254	8	m.	m.	PROPN
eurjchem-1566	254	9	r.	r.	PROPN
eurjchem-1566	254	10	;	;	PUNCT
eurjchem-1566	254	11	karaman	karaman	PROPN
eurjchem-1566	254	12	,	,	PUNCT
eurjchem-1566	254	13	r.	r.	PROPN
eurjchem-1566	254	14	m.	m.	PROPN
eurjchem-1566	254	15	;	;	PUNCT
eurjchem-1566	254	16	neamati‐	neamati‐	PROPN
eurjchem-1566	254	17	mazrach	mazrach	PROPN
eurjchem-1566	254	18	,	,	PUNCT
eurjchem-1566	254	19	n.	n.	PROPN
eurjchem-1566	254	20	;	;	PUNCT
eurjchem-1566	254	21	cowell	cowell	PROPN
eurjchem-1566	254	22	,	,	PUNCT
eurjchem-1566	254	23	s.	s.	PROPN
eurjchem-1566	254	24	m.	m.	PROPN
eurjchem-1566	254	25	;	;	PUNCT
eurjchem-1566	254	26	harris	harris	PROPN
eurjchem-1566	254	27	,	,	PUNCT
eurjchem-1566	254	28	j.	j.	PROPN
eurjchem-1566	254	29	m.	m.	PROPN
eurjchem-1566	254	30	j.	j.	PROPN
eurjchem-1566	254	31	org	org	PROPN
eurjchem-1566	254	32	.	.	PUNCT
eurjchem-1566	254	33	chem	chem	PROPN
eurjchem-1566	254	34	.	.	PUNCT
eurjchem-1566	255	1	1989	1989	NUM
eurjchem-1566	255	2	,	,	PUNCT
eurjchem-1566	255	3	54	54	NUM
eurjchem-1566	255	4	,	,	PUNCT
eurjchem-1566	255	5	1911‐	1911‐	NUM
eurjchem-1566	255	6	1918	1918	NUM
eurjchem-1566	255	7	.	.	PUNCT
eurjchem-1566	256	1	[	[	X
eurjchem-1566	256	2	28	28	NUM
eurjchem-1566	256	3	]	]	PUNCT
eurjchem-1566	256	4	.	.	PUNCT
eurjchem-1566	257	1	mcmanus	mcmanus	PROPN
eurjchem-1566	257	2	,	,	PUNCT
eurjchem-1566	257	3	s.	s.	PROPN
eurjchem-1566	257	4	p.	p.	PROPN
eurjchem-1566	257	5	;	;	PUNCT
eurjchem-1566	257	6	sedaghat‐herati	sedaghat‐herati	PROPN
eurjchem-1566	257	7	,	,	PUNCT
eurjchem-1566	257	8	m.	m.	PROPN
eurjchem-1566	257	9	r.	r.	PROPN
eurjchem-1566	257	10	;	;	PUNCT
eurjchem-1566	257	11	harris	harris	PROPN
eurjchem-1566	257	12	,	,	PUNCT
eurjchem-1566	257	13	j.	j.	PROPN
eurjchem-1566	257	14	m.	m.	PROPN
eurjchem-1566	257	15	tetrahedron	tetrahedron	PROPN
eurjchem-1566	257	16	lett	lett	PROPN
eurjchem-1566	257	17	.	.	PUNCT
eurjchem-1566	258	1	1987	1987	NUM
eurjchem-1566	258	2	,	,	PUNCT
eurjchem-1566	258	3	28	28	NUM
eurjchem-1566	258	4	,	,	PUNCT
eurjchem-1566	258	5	5299‐5300	5299‐5300	NUM
eurjchem-1566	258	6	.	.	PUNCT
eurjchem-1566	259	1	[	[	X
eurjchem-1566	259	2	29	29	NUM
eurjchem-1566	259	3	]	]	PUNCT
eurjchem-1566	259	4	.	.	PUNCT
eurjchem-1566	260	1	mcmanus	mcmanus	PROPN
eurjchem-1566	260	2	,	,	PUNCT
eurjchem-1566	260	3	s.	s.	PROPN
eurjchem-1566	260	4	p.	p.	PROPN
eurjchem-1566	260	5	;	;	PUNCT
eurjchem-1566	260	6	neamati‐mazrach	neamati‐mazrach	PROPN
eurjchem-1566	260	7	,	,	PUNCT
eurjchem-1566	260	8	n.	n.	NOUN
eurjchem-1566	260	9	;	;	PUNCT
eurjchem-1566	260	10	karaman	karaman	PROPN
eurjchem-1566	260	11	,	,	PUNCT
eurjchem-1566	260	12	r.	r.	PROPN
eurjchem-1566	260	13	m.	m.	PROPN
eurjchem-1566	260	14	;	;	PUNCT
eurjchem-1566	260	15	harris	harris	PROPN
eurjchem-1566	260	16	,	,	PUNCT
eurjchem-1566	260	17	j.	j.	PROPN
eurjchem-1566	260	18	m.	m.	PROPN
eurjchem-1566	260	19	j.	j.	PROPN
eurjchem-1566	260	20	org	org	PROPN
eurjchem-1566	260	21	.	.	PUNCT
eurjchem-1566	260	22	chem	chem	PROPN
eurjchem-1566	260	23	.	.	PUNCT
eurjchem-1566	261	1	1986	1986	NUM
eurjchem-1566	261	2	,	,	PUNCT
eurjchem-1566	261	3	51	51	NUM
eurjchem-1566	261	4	,	,	PUNCT
eurjchem-1566	261	5	4876‐4878	4876‐4878	NUM
eurjchem-1566	261	6	.	.	PUNCT
eurjchem-1566	262	1	[	[	X
eurjchem-1566	262	2	30	30	NUM
eurjchem-1566	262	3	]	]	PUNCT
eurjchem-1566	262	4	.	.	PUNCT
eurjchem-1566	263	1	mcmanus	mcmanus	PROPN
eurjchem-1566	263	2	,	,	PUNCT
eurjchem-1566	263	3	s.	s.	PROPN
eurjchem-1566	263	4	p.	p.	PROPN
eurjchem-1566	263	5	;	;	PUNCT
eurjchem-1566	263	6	lam	lam	PROPN
eurjchem-1566	263	7	,	,	PUNCT
eurjchem-1566	263	8	d.	d.	PROPN
eurjchem-1566	263	9	h.	h.	PROPN
eurjchem-1566	263	10	j.	j.	PROPN
eurjchem-1566	263	11	org	org	PROPN
eurjchem-1566	263	12	.	.	PUNCT
eurjchem-1566	263	13	chem	chem	PROPN
eurjchem-1566	263	14	.	.	PUNCT
eurjchem-1566	264	1	1978	1978	NUM
eurjchem-1566	264	2	,	,	PUNCT
eurjchem-1566	264	3	43	43	NUM
eurjchem-1566	264	4	,	,	PUNCT
eurjchem-1566	264	5	650‐651	650‐651	NUM
eurjchem-1566	264	6	.	.	PUNCT
eurjchem-1566	265	1	[	[	X
eurjchem-1566	265	2	31	31	NUM
eurjchem-1566	265	3	]	]	PUNCT
eurjchem-1566	265	4	.	.	PUNCT
eurjchem-1566	266	1	neamati‐mazrach	neamati‐mazrach	PROPN
eurjchem-1566	266	2	,	,	PUNCT
eurjchem-1566	266	3	n.	n.	NOUN
eurjchem-1566	266	4	;	;	PUNCT
eurjchem-1566	266	5	mcmanus	mcmanus	PROPN
eurjchem-1566	266	6	,	,	PUNCT
eurjchem-1566	266	7	s.	s.	PROPN
eurjchem-1566	266	8	p.	p.	PROPN
eurjchem-1566	266	9	tetrahedron	tetrahedron	PROPN
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eurjchem-1566	266	11	.	.	PUNCT
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eurjchem-1566	266	13	,	,	PUNCT
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eurjchem-1566	266	15	,	,	PUNCT
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eurjchem-1566	266	17	.	.	PUNCT
eurjchem-1566	267	1	[	[	X
eurjchem-1566	267	2	32	32	NUM
eurjchem-1566	267	3	]	]	PUNCT
eurjchem-1566	267	4	.	.	PUNCT
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eurjchem-1566	268	2	,	,	PUNCT
eurjchem-1566	268	3	d.	d.	PROPN
eurjchem-1566	268	4	n.	n.	PROPN
eurjchem-1566	268	5	;	;	PUNCT
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eurjchem-1566	268	7	,	,	PUNCT
eurjchem-1566	268	8	m.	m.	PROPN
eurjchem-1566	268	9	h.	h.	PROPN
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eurjchem-1566	268	12	acta	acta	PROPN
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eurjchem-1566	268	14	,	,	PUNCT
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eurjchem-1566	268	16	,	,	PUNCT
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eurjchem-1566	268	19	.	.	PUNCT
eurjchem-1566	269	1	[	[	X
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eurjchem-1566	269	3	]	]	PUNCT
eurjchem-1566	269	4	.	.	PUNCT
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eurjchem-1566	270	2	,	,	PUNCT
eurjchem-1566	270	3	t.	t.	PROPN
eurjchem-1566	270	4	w.	w.	PROPN
eurjchem-1566	270	5	;	;	PUNCT
eurjchem-1566	270	6	schleyer	schleyer	PROPN
eurjchem-1566	270	7	,	,	PUNCT
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eurjchem-1566	270	10	r.	r.	PROPN
eurjchem-1566	270	11	j.	j.	PROPN
eurjchem-1566	270	12	am	am	PROPN
eurjchem-1566	270	13	chem	chem	NOUN
eurjchem-1566	270	14	.	.	PUNCT
eurjchem-1566	271	1	soc	soc	PROPN
eurjchem-1566	271	2	.	.	PUNCT
eurjchem-1566	272	1	1976	1976	NUM
eurjchem-1566	272	2	,	,	PUNCT
eurjchem-1566	272	3	98	98	NUM
eurjchem-1566	272	4	,	,	PUNCT
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eurjchem-1566	272	6	.	.	PUNCT
eurjchem-1566	273	1	[	[	X
eurjchem-1566	273	2	34	34	NUM
eurjchem-1566	273	3	]	]	PUNCT
eurjchem-1566	273	4	.	.	PUNCT
eurjchem-1566	273	5	harris	harris	PROPN
eurjchem-1566	273	6	,	,	PUNCT
eurjchem-1566	273	7	j.	j.	PROPN
eurjchem-1566	273	8	m.	m.	PROPN
eurjchem-1566	273	9	;	;	PUNCT
eurjchem-1566	273	10	mcmanus	mcmanus	PROPN
eurjchem-1566	273	11	,	,	PUNCT
eurjchem-1566	273	12	s.	s.	PROPN
eurjchem-1566	273	13	p.	p.	PROPN
eurjchem-1566	273	14	;	;	PUNCT
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eurjchem-1566	273	16	,	,	PUNCT
eurjchem-1566	273	17	m.	m.	PROPN
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eurjchem-1566	273	19	;	;	PUNCT
eurjchem-1566	273	20	neamati‐	neamati‐	PROPN
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eurjchem-1566	273	22	,	,	PUNCT
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eurjchem-1566	273	24	;	;	PUNCT
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eurjchem-1566	273	26	,	,	PUNCT
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eurjchem-1566	273	30	doherty	doherty	PROPN
eurjchem-1566	273	31	,	,	PUNCT
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eurjchem-1566	273	34	;	;	PUNCT
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eurjchem-1566	273	45	,	,	PUNCT
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eurjchem-1566	273	50	j.	j.	PROPN
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eurjchem-1566	274	2	.	.	PUNCT
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eurjchem-1566	275	3	]	]	SYM
eurjchem-1566	275	4	.	.	PUNCT
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eurjchem-1566	276	2	,	,	PUNCT
eurjchem-1566	276	3	b.	b.	PROPN
eurjchem-1566	276	4	;	;	PUNCT
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eurjchem-1566	276	6	,	,	PUNCT
eurjchem-1566	276	7	m.	m.	NOUN
eurjchem-1566	276	8	;	;	PUNCT
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eurjchem-1566	276	10	,	,	PUNCT
eurjchem-1566	276	11	d.	d.	PROPN
eurjchem-1566	276	12	e.	e.	PROPN
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eurjchem-1566	276	15	,	,	PUNCT
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eurjchem-1566	276	17	,	,	PUNCT
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eurjchem-1566	276	19	.	.	PUNCT
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eurjchem-1566	277	3	]	]	PUNCT
eurjchem-1566	277	4	.	.	PUNCT
eurjchem-1566	278	1	chechik	chechik	NOUN
eurjchem-1566	278	2	,	,	PUNCT
eurjchem-1566	278	3	v.	v.	PROPN
eurjchem-1566	278	4	o.	o.	NOUN
eurjchem-1566	278	5	;	;	PUNCT
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eurjchem-1566	278	7	,	,	PUNCT
eurjchem-1566	278	8	v.	v.	ADP
eurjchem-1566	278	9	a.	a.	PROPN
eurjchem-1566	278	10	j.	j.	PROPN
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eurjchem-1566	278	14	.	.	PUNCT
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eurjchem-1566	279	2	.	.	PUNCT
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eurjchem-1566	280	8	,	,	PUNCT
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eurjchem-1566	280	10	,	,	PUNCT
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eurjchem-1566	280	12	.	.	PUNCT
eurjchem-1566	281	1	[	[	X
eurjchem-1566	281	2	37	37	NUM
eurjchem-1566	281	3	]	]	PUNCT
eurjchem-1566	281	4	.	.	PUNCT
eurjchem-1566	282	1	chechik	chechik	NOUN
eurjchem-1566	282	2	,	,	PUNCT
eurjchem-1566	282	3	v.	v.	PROPN
eurjchem-1566	282	4	o.	o.	NOUN
eurjchem-1566	282	5	;	;	PUNCT
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eurjchem-1566	282	7	,	,	PUNCT
eurjchem-1566	282	8	v.	v.	ADP
eurjchem-1566	282	9	a.	a.	PROPN
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eurjchem-1566	282	11	.	.	PUNCT
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eurjchem-1566	284	2	.	.	PROPN
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eurjchem-1566	285	2	,	,	PUNCT
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eurjchem-1566	285	4	,	,	PUNCT
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eurjchem-1566	285	6	.	.	PUNCT
eurjchem-1566	286	1	[	[	X
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eurjchem-1566	286	4	.	.	PUNCT
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eurjchem-1566	287	5	;	;	PUNCT
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eurjchem-1566	287	7	,	,	PUNCT
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eurjchem-1566	287	14	.	.	PUNCT
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eurjchem-1566	289	2	,	,	PUNCT
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