id	sid	tid	token	lemma	pos
eurjchem-1598	1	1	untitled	untitle	VERB
eurjchem-1598	1	2	european	european	PROPN
eurjchem-1598	1	3	journal	journal	PROPN
eurjchem-1598	1	4	of	of	ADP
eurjchem-1598	1	5	chemistry	chemistry	NOUN
eurjchem-1598	1	6	8	8	NUM
eurjchem-1598	1	7	(	(	PUNCT
eurjchem-1598	1	8	3	3	NUM
eurjchem-1598	1	9	)	)	PUNCT
eurjchem-1598	1	10	(	(	PUNCT
eurjchem-1598	1	11	2017	2017	NUM
eurjchem-1598	1	12	)	)	PUNCT
eurjchem-1598	1	13	252‐257	252‐257	NUM
eurjchem-1598	1	14	european	european	PROPN
eurjchem-1598	1	15	journal	journal	PROPN
eurjchem-1598	1	16	of	of	ADP
eurjchem-1598	1	17	chemistry	chemistry	NOUN
eurjchem-1598	1	18	issn	issn	PROPN
eurjchem-1598	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-1598	1	20	(	(	PUNCT
eurjchem-1598	1	21	print	print	NOUN
eurjchem-1598	1	22	)	)	PUNCT
eurjchem-1598	1	23	/	/	SYM
eurjchem-1598	1	24	issn	issn	PROPN
eurjchem-1598	1	25	2153‐2257	2153‐2257	NUM
eurjchem-1598	1	26	(	(	PUNCT
eurjchem-1598	1	27	online	online	ADJ
eurjchem-1598	1	28	)	)	PUNCT
eurjchem-1598	1	29			NOUN
eurjchem-1598	1	30	2017	2017	NUM
eurjchem-1598	1	31	atlanta	atlanta	PROPN
eurjchem-1598	1	32	publishing	publishing	PROPN
eurjchem-1598	1	33	house	house	PROPN
eurjchem-1598	1	34	llc	llc	PROPN
eurjchem-1598	1	35	‐	‐	PUNCT
eurjchem-1598	1	36	all	all	DET
eurjchem-1598	1	37	rights	right	NOUN
eurjchem-1598	1	38	reserved	reserve	VERB
eurjchem-1598	1	39	‐	‐	NOUN
eurjchem-1598	1	40	printed	print	VERB
eurjchem-1598	1	41	in	in	ADP
eurjchem-1598	1	42	the	the	DET
eurjchem-1598	1	43	usa	usa	PROPN
eurjchem-1598	1	44	http://dx.doi.org/10.5155/eurjchem.8.3.252-257.1598	http://dx.doi.org/10.5155/eurjchem.8.3.252-257.1598	PROPN
eurjchem-1598	1	45	european	european	PROPN
eurjchem-1598	1	46	journal	journal	PROPN
eurjchem-1598	1	47	of	of	ADP
eurjchem-1598	1	48	chemistry	chemistry	PROPN
eurjchem-1598	1	49	journal	journal	PROPN
eurjchem-1598	1	50	webpage	webpage	NOUN
eurjchem-1598	1	51	:	:	PUNCT
eurjchem-1598	1	52	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1598	1	53	synthesis	synthesis	NOUN
eurjchem-1598	1	54	,	,	PUNCT
eurjchem-1598	1	55	spectral	spectral	ADJ
eurjchem-1598	1	56	characterization	characterization	NOUN
eurjchem-1598	1	57	,	,	PUNCT
eurjchem-1598	1	58	thermal	thermal	ADJ
eurjchem-1598	1	59	analysis	analysis	NOUN
eurjchem-1598	1	60	and	and	CCONJ
eurjchem-1598	1	61	dft	dft	PROPN
eurjchem-1598	1	62	computational	computational	ADJ
eurjchem-1598	1	63	studies	study	NOUN
eurjchem-1598	1	64	of	of	ADP
eurjchem-1598	1	65	2‐(1h‐indole‐3‐yl)‐5‐methyl‐1h‐benzimidazole	2‐(1h‐indole‐3‐yl)‐5‐methyl‐1h‐benzimidazole	NUM
eurjchem-1598	1	66	and	and	CCONJ
eurjchem-1598	1	67	their	their	PRON
eurjchem-1598	1	68	cu(ii	cu(ii	PROPN
eurjchem-1598	1	69	)	)	PUNCT
eurjchem-1598	1	70	,	,	PUNCT
eurjchem-1598	1	71	zn(ii	zn(ii	NUM
eurjchem-1598	1	72	)	)	PUNCT
eurjchem-1598	1	73	and	and	CCONJ
eurjchem-1598	1	74	cd(ii	cd(ii	ADJ
eurjchem-1598	1	75	)	)	PUNCT
eurjchem-1598	1	76	complexes	complexe	VERB
eurjchem-1598	1	77	jabbar	jabbar	PROPN
eurjchem-1598	1	78	saleh	saleh	PROPN
eurjchem-1598	1	79	hadi	hadi	PROPN
eurjchem-1598	1	80	1	1	NUM
eurjchem-1598	1	81	,	,	PUNCT
eurjchem-1598	1	82	*	*	PROPN
eurjchem-1598	1	83	,	,	PUNCT
eurjchem-1598	1	84	zuhair	zuhair	PROPN
eurjchem-1598	1	85	ali	ali	PROPN
eurjchem-1598	1	86	abdulnabi	abdulnabi	PROPN
eurjchem-1598	1	87	2	2	NUM
eurjchem-1598	1	88	and	and	CCONJ
eurjchem-1598	1	89	adil	adil	PROPN
eurjchem-1598	1	90	muala	muala	PROPN
eurjchem-1598	1	91	dhumad	dhumad	VERB
eurjchem-1598	1	92	1	1	NUM
eurjchem-1598	1	93	1	1	NUM
eurjchem-1598	1	94	college	college	NOUN
eurjchem-1598	1	95	of	of	ADP
eurjchem-1598	1	96	education	education	NOUN
eurjchem-1598	1	97	for	for	ADP
eurjchem-1598	1	98	pure	pure	ADJ
eurjchem-1598	1	99	science	science	NOUN
eurjchem-1598	1	100	,	,	PUNCT
eurjchem-1598	1	101	basrah	basrah	PROPN
eurjchem-1598	1	102	university	university	PROPN
eurjchem-1598	1	103	,	,	PUNCT
eurjchem-1598	1	104	basrah	basrah	PROPN
eurjchem-1598	1	105	,	,	PUNCT
eurjchem-1598	1	106	61004	61004	NUM
eurjchem-1598	1	107	,	,	PUNCT
eurjchem-1598	1	108	iraq	iraq	PROPN
eurjchem-1598	1	109	2	2	NUM
eurjchem-1598	1	110	marine	marine	PROPN
eurjchem-1598	1	111	science	science	NOUN
eurjchem-1598	1	112	center	center	NOUN
eurjchem-1598	1	113	,	,	PUNCT
eurjchem-1598	1	114	basrah	basrah	PROPN
eurjchem-1598	1	115	university	university	PROPN
eurjchem-1598	1	116	,	,	PUNCT
eurjchem-1598	1	117	basrah	basrah	PROPN
eurjchem-1598	1	118	,	,	PUNCT
eurjchem-1598	1	119	61004	61004	NUM
eurjchem-1598	1	120	,	,	PUNCT
eurjchem-1598	1	121	iraq	iraq	PROPN
eurjchem-1598	1	122	*	*	PUNCT
eurjchem-1598	1	123	corresponding	correspond	VERB
eurjchem-1598	1	124	author	author	NOUN
eurjchem-1598	1	125	at	at	ADP
eurjchem-1598	1	126	:	:	PUNCT
eurjchem-1598	1	127	college	college	NOUN
eurjchem-1598	1	128	of	of	ADP
eurjchem-1598	1	129	education	education	NOUN
eurjchem-1598	1	130	for	for	ADP
eurjchem-1598	1	131	pure	pure	ADJ
eurjchem-1598	1	132	science	science	NOUN
eurjchem-1598	1	133	,	,	PUNCT
eurjchem-1598	1	134	basrah	basrah	PROPN
eurjchem-1598	1	135	university	university	PROPN
eurjchem-1598	1	136	,	,	PUNCT
eurjchem-1598	1	137	basrah	basrah	PROPN
eurjchem-1598	1	138	,	,	PUNCT
eurjchem-1598	1	139	61004	61004	NUM
eurjchem-1598	1	140	,	,	PUNCT
eurjchem-1598	1	141	iraq	iraq	PROPN
eurjchem-1598	1	142	.	.	PUNCT
eurjchem-1598	2	1	tel	tel	PROPN
eurjchem-1598	2	2	.	.	PUNCT
eurjchem-1598	2	3	:	:	PUNCT
eurjchem-1598	3	1	+964.771.0822193	+964.771.0822193	X
eurjchem-1598	3	2	.	.	PUNCT
eurjchem-1598	4	1	fax	fax	NOUN
eurjchem-1598	4	2	:	:	PUNCT
eurjchem-1598	4	3	+964.771.0822193	+964.771.0822193	NUM
eurjchem-1598	4	4	.	.	PUNCT
eurjchem-1598	4	5	e‐mail	e‐mail	PUNCT
eurjchem-1598	5	1	address	address	NOUN
eurjchem-1598	5	2	:	:	PUNCT
eurjchem-1598	5	3	jshalkabi2@gmail.com	jshalkabi2@gmail.com	X
eurjchem-1598	5	4	(	(	PUNCT
eurjchem-1598	5	5	j.s	j.s	PROPN
eurjchem-1598	5	6	.	.	PROPN
eurjchem-1598	5	7	hadi	hadi	PROPN
eurjchem-1598	5	8	)	)	PUNCT
eurjchem-1598	5	9	.	.	PUNCT
eurjchem-1598	6	1	article	article	NOUN
eurjchem-1598	6	2	information	information	PROPN
eurjchem-1598	6	3	abstract	abstract	ADJ
eurjchem-1598	6	4	doi	doi	PROPN
eurjchem-1598	6	5	:	:	PUNCT
eurjchem-1598	6	6	 	 	SPACE
eurjchem-1598	6	7	10.5155	10.5155	NUM
eurjchem-1598	6	8	/	/	SYM
eurjchem-1598	6	9	eurjchem.8.3.252	eurjchem.8.3.252	ADV
eurjchem-1598	6	10	-	-	PUNCT
eurjchem-1598	6	11	257.1598	257.1598	NUM
eurjchem-1598	6	12	received	receive	VERB
eurjchem-1598	6	13	:	:	PUNCT
eurjchem-1598	6	14	09	09	NUM
eurjchem-1598	6	15	june	june	PROPN
eurjchem-1598	6	16	2017	2017	NUM
eurjchem-1598	6	17	received	receive	VERB
eurjchem-1598	6	18	in	in	ADP
eurjchem-1598	6	19	revised	revise	VERB
eurjchem-1598	6	20	form	form	NOUN
eurjchem-1598	6	21	:	:	PUNCT
eurjchem-1598	6	22	02	02	NUM
eurjchem-1598	6	23	july	july	PROPN
eurjchem-1598	6	24	2017	2017	NUM
eurjchem-1598	6	25	accepted	accept	VERB
eurjchem-1598	6	26	:	:	PUNCT
eurjchem-1598	6	27	23	23	NUM
eurjchem-1598	6	28	july	july	PROPN
eurjchem-1598	6	29	2017	2017	NUM
eurjchem-1598	6	30	published	publish	VERB
eurjchem-1598	6	31	online	online	ADV
eurjchem-1598	6	32	:	:	PUNCT
eurjchem-1598	6	33	30	30	NUM
eurjchem-1598	6	34	september	september	PROPN
eurjchem-1598	6	35	2017	2017	NUM
eurjchem-1598	6	36	printed	print	VERB
eurjchem-1598	6	37	:	:	PUNCT
eurjchem-1598	6	38	30	30	NUM
eurjchem-1598	6	39	september	september	PROPN
eurjchem-1598	6	40	2017	2017	NUM
eurjchem-1598	6	41	  	  	SPACE
eurjchem-1598	6	42	cu(ii	cu(ii	PROPN
eurjchem-1598	6	43	)	)	PUNCT
eurjchem-1598	6	44	,	,	PUNCT
eurjchem-1598	6	45	zn(ii	zn(ii	NUM
eurjchem-1598	6	46	)	)	PUNCT
eurjchem-1598	6	47	and	and	CCONJ
eurjchem-1598	6	48	cd(ii	cd(ii	ADJ
eurjchem-1598	6	49	)	)	PUNCT
eurjchem-1598	6	50	metal	metal	NOUN
eurjchem-1598	6	51	complexes	complex	NOUN
eurjchem-1598	6	52	were	be	AUX
eurjchem-1598	6	53	obtained	obtain	VERB
eurjchem-1598	6	54	by	by	ADP
eurjchem-1598	6	55	using	use	VERB
eurjchem-1598	6	56	ligand	ligand	NOUN
eurjchem-1598	6	57	(	(	PUNCT
eurjchem-1598	6	58	2‐(1h‐indol‐3‐yl)‐5‐	2‐(1h‐indol‐3‐yl)‐5‐	NUM
eurjchem-1598	6	59	methyl‐1h‐benzo[d]imidazole	methyl‐1h‐benzo[d]imidazole	NOUN
eurjchem-1598	6	60	)	)	PUNCT
eurjchem-1598	6	61	derived	derive	VERB
eurjchem-1598	6	62	from	from	ADP
eurjchem-1598	6	63	4‐methyl‐1,2‐phenelyenediamine	4‐methyl‐1,2‐phenelyenediamine	PROPN
eurjchem-1598	6	64	and	and	CCONJ
eurjchem-1598	6	65	indole‐3‐	indole‐3‐	ADP
eurjchem-1598	6	66	carboxaldehyde	carboxaldehyde	PROPN
eurjchem-1598	6	67	.	.	PUNCT
eurjchem-1598	7	1	the	the	DET
eurjchem-1598	7	2	ligand	ligand	NOUN
eurjchem-1598	7	3	and	and	CCONJ
eurjchem-1598	7	4	its	its	PRON
eurjchem-1598	7	5	metal	metal	NOUN
eurjchem-1598	7	6	complexes	complex	NOUN
eurjchem-1598	7	7	were	be	AUX
eurjchem-1598	7	8	characterized	characterize	VERB
eurjchem-1598	7	9	by	by	ADP
eurjchem-1598	7	10	elemental	elemental	ADJ
eurjchem-1598	7	11	analysis	analysis	NOUN
eurjchem-1598	7	12	,	,	PUNCT
eurjchem-1598	7	13	mass	mass	ADJ
eurjchem-1598	7	14	spectrometry	spectrometry	NOUN
eurjchem-1598	7	15	,	,	PUNCT
eurjchem-1598	7	16	ft‐ir	ft‐ir	NOUN
eurjchem-1598	7	17	,	,	PUNCT
eurjchem-1598	7	18	1h	1h	NUM
eurjchem-1598	7	19	nmr	nmr	NOUN
eurjchem-1598	7	20	,	,	PUNCT
eurjchem-1598	7	21	13c	13c	NOUN
eurjchem-1598	7	22	nmr	nmr	NOUN
eurjchem-1598	7	23	,	,	PUNCT
eurjchem-1598	7	24	tg	tg	PRON
eurjchem-1598	7	25	and	and	CCONJ
eurjchem-1598	7	26	molar	molar	ADJ
eurjchem-1598	7	27	conductance	conductance	NOUN
eurjchem-1598	7	28	measure‐	measure‐	NOUN
eurjchem-1598	7	29	ments	ment	NOUN
eurjchem-1598	7	30	.	.	PUNCT
eurjchem-1598	8	1	the	the	DET
eurjchem-1598	8	2	non‐electrolytic	non‐electrolytic	ADJ
eurjchem-1598	8	3	behaviour	behaviour	NOUN
eurjchem-1598	8	4	of	of	ADP
eurjchem-1598	8	5	complexes	complex	NOUN
eurjchem-1598	8	6	is	be	AUX
eurjchem-1598	8	7	confirmed	confirm	VERB
eurjchem-1598	8	8	by	by	ADP
eurjchem-1598	8	9	low	low	ADJ
eurjchem-1598	8	10	molar	molar	ADJ
eurjchem-1598	8	11	conductance	conductance	NOUN
eurjchem-1598	8	12	value	value	NOUN
eurjchem-1598	8	13	.	.	PUNCT
eurjchem-1598	9	1	the	the	DET
eurjchem-1598	9	2	presence	presence	NOUN
eurjchem-1598	9	3	of	of	ADP
eurjchem-1598	9	4	lattice	lattice	NOUN
eurjchem-1598	9	5	and	and	CCONJ
eurjchem-1598	9	6	coordinated	coordinated	ADJ
eurjchem-1598	9	7	water	water	NOUN
eurjchem-1598	9	8	molecules	molecule	NOUN
eurjchem-1598	9	9	is	be	AUX
eurjchem-1598	9	10	confirmed	confirm	VERB
eurjchem-1598	9	11	by	by	ADP
eurjchem-1598	9	12	thermal	thermal	ADJ
eurjchem-1598	9	13	analysis	analysis	NOUN
eurjchem-1598	9	14	.	.	PUNCT
eurjchem-1598	10	1	thermodynamic	thermodynamic	ADJ
eurjchem-1598	10	2	parameters	parameter	NOUN
eurjchem-1598	10	3	(	(	PUNCT
eurjchem-1598	10	4	e	e	NOUN
eurjchem-1598	10	5	,	,	PUNCT
eurjchem-1598	10	6	δh	δh	NOUN
eurjchem-1598	10	7	,	,	PUNCT
eurjchem-1598	10	8	δs	δs	NOUN
eurjchem-1598	10	9	and	and	CCONJ
eurjchem-1598	10	10	δg	δg	VERB
eurjchem-1598	10	11	)	)	PUNCT
eurjchem-1598	10	12	were	be	AUX
eurjchem-1598	10	13	calculated	calculate	VERB
eurjchem-1598	10	14	by	by	ADP
eurjchem-1598	10	15	using	use	VERB
eurjchem-1598	10	16	coats‐	coats‐	PROPN
eurjchem-1598	10	17	redfern	redfern	PROPN
eurjchem-1598	10	18	method	method	PROPN
eurjchem-1598	10	19	.	.	PUNCT
eurjchem-1598	11	1	the	the	DET
eurjchem-1598	11	2	density	density	NOUN
eurjchem-1598	11	3	function	function	NOUN
eurjchem-1598	11	4	theory	theory	NOUN
eurjchem-1598	11	5	(	(	PUNCT
eurjchem-1598	11	6	dft	dft	NOUN
eurjchem-1598	11	7	)	)	PUNCT
eurjchem-1598	11	8	calculation	calculation	NOUN
eurjchem-1598	11	9	at	at	ADP
eurjchem-1598	11	10	the	the	DET
eurjchem-1598	11	11	b3lyp	b3lyp	NOUN
eurjchem-1598	11	12	/	/	SYM
eurjchem-1598	11	13	lanl2dz	lanl2dz	NOUN
eurjchem-1598	11	14	method	method	VERB
eurjchem-1598	11	15	with	with	ADP
eurjchem-1598	11	16	6‐311+g(d	6‐311+g(d	NUM
eurjchem-1598	11	17	,	,	PUNCT
eurjchem-1598	11	18	p	p	NOUN
eurjchem-1598	11	19	)	)	PUNCT
eurjchem-1598	11	20	basis	basis	NOUN
eurjchem-1598	11	21	set	set	NOUN
eurjchem-1598	11	22	are	be	AUX
eurjchem-1598	11	23	used	use	VERB
eurjchem-1598	11	24	to	to	PART
eurjchem-1598	11	25	investigate	investigate	VERB
eurjchem-1598	11	26	the	the	DET
eurjchem-1598	11	27	electronic	electronic	ADJ
eurjchem-1598	11	28	structure	structure	NOUN
eurjchem-1598	11	29	of	of	ADP
eurjchem-1598	11	30	the	the	DET
eurjchem-1598	11	31	ligand	ligand	NOUN
eurjchem-1598	11	32	and	and	CCONJ
eurjchem-1598	11	33	their	their	PRON
eurjchem-1598	11	34	complexes	complex	NOUN
eurjchem-1598	11	35	with	with	ADP
eurjchem-1598	11	36	cu(ii	cu(ii	PROPN
eurjchem-1598	11	37	)	)	PUNCT
eurjchem-1598	11	38	,	,	PUNCT
eurjchem-1598	11	39	zn(ii	zn(ii	NUM
eurjchem-1598	11	40	)	)	PUNCT
eurjchem-1598	11	41	and	and	CCONJ
eurjchem-1598	11	42	cd(ii	cd(ii	ADJ
eurjchem-1598	11	43	)	)	PUNCT
eurjchem-1598	11	44	metals	metal	NOUN
eurjchem-1598	11	45	.	.	PUNCT
eurjchem-1598	12	1	homo‐lumo	homo‐lumo	NOUN
eurjchem-1598	12	2	energies	energy	NOUN
eurjchem-1598	12	3	of	of	ADP
eurjchem-1598	12	4	the	the	DET
eurjchem-1598	12	5	mentioned	mention	VERB
eurjchem-1598	12	6	compounds	compound	NOUN
eurjchem-1598	12	7	have	have	AUX
eurjchem-1598	12	8	been	be	AUX
eurjchem-1598	12	9	computed	compute	VERB
eurjchem-1598	12	10	by	by	ADP
eurjchem-1598	12	11	using	use	VERB
eurjchem-1598	12	12	dft	dft	PROPN
eurjchem-1598	12	13	/	/	SYM
eurjchem-1598	12	14	b3lyp	b3lyp	PROPN
eurjchem-1598	12	15	calculation	calculation	NOUN
eurjchem-1598	12	16	method	method	NOUN
eurjchem-1598	12	17	with	with	ADP
eurjchem-1598	12	18	6‐	6‐	PROPN
eurjchem-1598	12	19	311+g(d	311+g(d	NUM
eurjchem-1598	12	20	,	,	PUNCT
eurjchem-1598	12	21	p	p	NOUN
eurjchem-1598	12	22	)	)	PUNCT
eurjchem-1598	12	23	basis	basis	NOUN
eurjchem-1598	12	24	set	set	NOUN
eurjchem-1598	12	25	and	and	CCONJ
eurjchem-1598	12	26	lanl2dz	lanl2dz	ADJ
eurjchem-1598	12	27	basis	basis	NOUN
eurjchem-1598	12	28	set	set	NOUN
eurjchem-1598	12	29	for	for	ADP
eurjchem-1598	12	30	cu(ii	cu(ii	PROPN
eurjchem-1598	12	31	)	)	PUNCT
eurjchem-1598	12	32	,	,	PUNCT
eurjchem-1598	12	33	zn(ii	zn(ii	NUM
eurjchem-1598	12	34	)	)	PUNCT
eurjchem-1598	12	35	and	and	CCONJ
eurjchem-1598	12	36	cd(ii	cd(ii	ADJ
eurjchem-1598	12	37	)	)	PUNCT
eurjchem-1598	12	38	metal	metal	NOUN
eurjchem-1598	12	39	complexes	complex	NOUN
eurjchem-1598	12	40	.	.	PUNCT
eurjchem-1598	13	1	mulliken	mulliken	NOUN
eurjchem-1598	13	2	charge	charge	NOUN
eurjchem-1598	13	3	distributions	distribution	NOUN
eurjchem-1598	13	4	of	of	ADP
eurjchem-1598	13	5	the	the	DET
eurjchem-1598	13	6	investigated	investigate	VERB
eurjchem-1598	13	7	compounds	compound	NOUN
eurjchem-1598	13	8	were	be	AUX
eurjchem-1598	13	9	also	also	ADV
eurjchem-1598	13	10	computed	compute	VERB
eurjchem-1598	13	11	with	with	ADP
eurjchem-1598	13	12	same	same	ADJ
eurjchem-1598	13	13	level	level	NOUN
eurjchem-1598	13	14	of	of	ADP
eurjchem-1598	13	15	method	method	NOUN
eurjchem-1598	13	16	.	.	PUNCT
eurjchem-1598	14	1	keywords	keyword	VERB
eurjchem-1598	14	2	metal	metal	NOUN
eurjchem-1598	14	3	complex	complex	ADJ
eurjchem-1598	14	4	benzamidazole	benzamidazole	NOUN
eurjchem-1598	14	5	indol	indol	VERB
eurjchem-1598	14	6	carboxaldehyde	carboxaldehyde	NOUN
eurjchem-1598	14	7	homo‐lumo	homo‐lumo	X
eurjchem-1598	14	8	energies	energy	NOUN
eurjchem-1598	14	9	coats‐redfern	coats‐redfern	ADJ
eurjchem-1598	14	10	method	method	NOUN
eurjchem-1598	14	11	density	density	NOUN
eurjchem-1598	14	12	function	function	NOUN
eurjchem-1598	14	13	theory	theory	NOUN
eurjchem-1598	14	14	cite	cite	VERB
eurjchem-1598	14	15	this	this	PRON
eurjchem-1598	14	16	:	:	PUNCT
eurjchem-1598	14	17	eur	eur	PROPN
eurjchem-1598	14	18	.	.	PUNCT
eurjchem-1598	15	1	j.	j.	PROPN
eurjchem-1598	15	2	chem	chem	PROPN
eurjchem-1598	15	3	.	.	PUNCT
eurjchem-1598	16	1	2017	2017	NUM
eurjchem-1598	16	2	,	,	PUNCT
eurjchem-1598	16	3	8(3	8(3	NUM
eurjchem-1598	16	4	)	)	PUNCT
eurjchem-1598	16	5	,	,	PUNCT
eurjchem-1598	16	6	252‐257	252‐257	NUM
eurjchem-1598	16	7	1	1	NUM
eurjchem-1598	16	8	.	.	PUNCT
eurjchem-1598	16	9	introduction	introduction	NOUN
eurjchem-1598	16	10	the	the	DET
eurjchem-1598	16	11	benzimidazole	benzimidazole	NOUN
eurjchem-1598	16	12	is	be	AUX
eurjchem-1598	16	13	as	as	ADP
eurjchem-1598	16	14	a	a	DET
eurjchem-1598	16	15	class	class	NOUN
eurjchem-1598	16	16	of	of	ADP
eurjchem-1598	16	17	heterocyclic	heterocyclic	ADJ
eurjchem-1598	16	18	compound	compound	NOUN
eurjchem-1598	16	19	,	,	PUNCT
eurjchem-1598	16	20	consisting	consist	VERB
eurjchem-1598	16	21	of	of	ADP
eurjchem-1598	16	22	a	a	DET
eurjchem-1598	16	23	benzene	benzene	NOUN
eurjchem-1598	16	24	ring	ring	NOUN
eurjchem-1598	16	25	fused	fuse	VERB
eurjchem-1598	16	26	to	to	ADP
eurjchem-1598	16	27	an	an	DET
eurjchem-1598	16	28	imidazole	imidazole	NOUN
eurjchem-1598	16	29	ring	ring	NOUN
eurjchem-1598	16	30	[	[	X
eurjchem-1598	16	31	1‐3	1‐3	NOUN
eurjchem-1598	16	32	]	]	PUNCT
eurjchem-1598	16	33	.	.	PUNCT
eurjchem-1598	17	1	there	there	PRON
eurjchem-1598	17	2	are	be	VERB
eurjchem-1598	17	3	different	different	ADJ
eurjchem-1598	17	4	methods	method	NOUN
eurjchem-1598	17	5	of	of	ADP
eurjchem-1598	17	6	preparing	prepare	VERB
eurjchem-1598	17	7	them	they	PRON
eurjchem-1598	17	8	using	use	VERB
eurjchem-1598	17	9	various	various	ADJ
eurjchem-1598	17	10	reagents	reagent	NOUN
eurjchem-1598	17	11	such	such	ADJ
eurjchem-1598	17	12	as	as	ADP
eurjchem-1598	17	13	,	,	PUNCT
eurjchem-1598	17	14	carboxylic	carboxylic	ADJ
eurjchem-1598	17	15	acid	acid	NOUN
eurjchem-1598	17	16	,	,	PUNCT
eurjchem-1598	17	17	esters	ester	NOUN
eurjchem-1598	17	18	,	,	PUNCT
eurjchem-1598	17	19	amides	amide	NOUN
eurjchem-1598	17	20	,	,	PUNCT
eurjchem-1598	17	21	aldehydes	aldehyde	NOUN
eurjchem-1598	17	22	etc	etc	X
eurjchem-1598	17	23	.	.	X
eurjchem-1598	17	24	,	,	PUNCT
eurjchem-1598	17	25	when	when	SCONJ
eurjchem-1598	17	26	reacted	react	VERB
eurjchem-1598	17	27	with	with	ADP
eurjchem-1598	17	28	o‐phenylenediamine	o‐phenylenediamine	PRON
eurjchem-1598	17	29	and	and	CCONJ
eurjchem-1598	17	30	their	their	PRON
eurjchem-1598	17	31	deriva‐	deriva‐	NOUN
eurjchem-1598	17	32	tives	tive	NOUN
eurjchem-1598	17	33	,	,	PUNCT
eurjchem-1598	17	34	afforded	afford	VERB
eurjchem-1598	17	35	the	the	DET
eurjchem-1598	17	36	benzimidazoles	benzimidazole	NOUN
eurjchem-1598	17	37	.	.	PUNCT
eurjchem-1598	18	1	methods	method	NOUN
eurjchem-1598	18	2	of	of	ADP
eurjchem-1598	18	3	benzimidazoles	benzimidazole	NOUN
eurjchem-1598	18	4	synthesis	synthesis	NOUN
eurjchem-1598	18	5	from	from	ADP
eurjchem-1598	18	6	the	the	DET
eurjchem-1598	18	7	condensation	condensation	NOUN
eurjchem-1598	18	8	of	of	ADP
eurjchem-1598	18	9	1,2‐phenylenediamine	1,2‐phenylenediamine	NUM
eurjchem-1598	18	10	with	with	ADP
eurjchem-1598	18	11	aromatic	aromatic	ADJ
eurjchem-1598	18	12	aldehydes	aldehyde	NOUN
eurjchem-1598	18	13	under	under	ADP
eurjchem-1598	18	14	oxidative	oxidative	ADJ
eurjchem-1598	18	15	condition	condition	NOUN
eurjchem-1598	18	16	are	be	AUX
eurjchem-1598	18	17	simple	simple	ADJ
eurjchem-1598	18	18	and	and	CCONJ
eurjchem-1598	18	19	efficient	efficient	ADJ
eurjchem-1598	18	20	method	method	NOUN
eurjchem-1598	18	21	and	and	CCONJ
eurjchem-1598	18	22	the	the	DET
eurjchem-1598	18	23	reactions	reaction	NOUN
eurjchem-1598	18	24	give	give	VERB
eurjchem-1598	18	25	high	high	ADJ
eurjchem-1598	18	26	yields	yield	NOUN
eurjchem-1598	18	27	in	in	ADP
eurjchem-1598	18	28	short	short	ADJ
eurjchem-1598	18	29	time	time	NOUN
eurjchem-1598	18	30	and	and	CCONJ
eurjchem-1598	18	31	easy	easy	ADJ
eurjchem-1598	18	32	in	in	ADP
eurjchem-1598	18	33	isolation	isolation	NOUN
eurjchem-1598	18	34	.	.	PUNCT
eurjchem-1598	19	1	the	the	DET
eurjchem-1598	19	2	reaction	reaction	NOUN
eurjchem-1598	19	3	carried	carry	VERB
eurjchem-1598	19	4	out	out	ADP
eurjchem-1598	19	5	in	in	ADP
eurjchem-1598	19	6	air	air	NOUN
eurjchem-1598	19	7	under	under	ADP
eurjchem-1598	19	8	reflux	reflux	NOUN
eurjchem-1598	19	9	or	or	CCONJ
eurjchem-1598	19	10	in	in	ADP
eurjchem-1598	19	11	room	room	NOUN
eurjchem-1598	19	12	temperature	temperature	NOUN
eurjchem-1598	19	13	in	in	ADP
eurjchem-1598	19	14	presence	presence	NOUN
eurjchem-1598	19	15	an	an	DET
eurjchem-1598	19	16	oxative	oxative	ADJ
eurjchem-1598	19	17	reagent	reagent	NOUN
eurjchem-1598	19	18	such	such	ADJ
eurjchem-1598	19	19	as	as	ADP
eurjchem-1598	19	20	h2o2	h2o2	NOUN
eurjchem-1598	19	21	[	[	X
eurjchem-1598	19	22	3	3	NUM
eurjchem-1598	19	23	]	]	PUNCT
eurjchem-1598	19	24	,	,	PUNCT
eurjchem-1598	19	25	pb(oac)2	pb(oac)2	VERB
eurjchem-1598	19	26	[	[	X
eurjchem-1598	19	27	4	4	NUM
eurjchem-1598	19	28	]	]	PUNCT
eurjchem-1598	19	29	,	,	PUNCT
eurjchem-1598	19	30	or	or	CCONJ
eurjchem-1598	19	31	in	in	ADP
eurjchem-1598	19	32	presence	presence	NOUN
eurjchem-1598	19	33	a	a	DET
eurjchem-1598	19	34	catalyst	catalyst	NOUN
eurjchem-1598	19	35	such	such	ADJ
eurjchem-1598	19	36	as	as	ADP
eurjchem-1598	19	37	cupric	cupric	ADJ
eurjchem-1598	19	38	acetate	acetate	NOUN
eurjchem-1598	20	1	[	[	X
eurjchem-1598	20	2	5	5	NUM
eurjchem-1598	20	3	]	]	PUNCT
eurjchem-1598	20	4	.	.	PUNCT
eurjchem-1598	21	1	the	the	DET
eurjchem-1598	21	2	complexes	complex	NOUN
eurjchem-1598	21	3	of	of	ADP
eurjchem-1598	21	4	transition	transition	NOUN
eurjchem-1598	21	5	metals	metal	NOUN
eurjchem-1598	21	6	with	with	ADP
eurjchem-1598	21	7	benzimidazole	benzimidazole	NOUN
eurjchem-1598	21	8	have	have	AUX
eurjchem-1598	21	9	been	be	AUX
eurjchem-1598	21	10	extensively	extensively	ADV
eurjchem-1598	21	11	studied	study	VERB
eurjchem-1598	21	12	due	due	ADP
eurjchem-1598	21	13	to	to	ADP
eurjchem-1598	21	14	the	the	DET
eurjchem-1598	21	15	ability	ability	NOUN
eurjchem-1598	21	16	of	of	ADP
eurjchem-1598	21	17	benzimidazoles	benzimidazole	NOUN
eurjchem-1598	21	18	as	as	ADP
eurjchem-1598	21	19	excellent	excellent	ADJ
eurjchem-1598	21	20	n‐donor	n‐donor	X
eurjchem-1598	21	21	ligands	ligand	NOUN
eurjchem-1598	21	22	[	[	X
eurjchem-1598	21	23	6	6	NUM
eurjchem-1598	21	24	]	]	PUNCT
eurjchem-1598	21	25	.	.	PUNCT
eurjchem-1598	22	1	most	most	ADJ
eurjchem-1598	22	2	of	of	ADP
eurjchem-1598	22	3	benzimidazoles	benzimidazole	NOUN
eurjchem-1598	22	4	possess	possess	VERB
eurjchem-1598	22	5	antibacterial	antibacterial	ADJ
eurjchem-1598	22	6	,	,	PUNCT
eurjchem-1598	22	7	fungicide	fungicide	NOUN
eurjchem-1598	22	8	,	,	PUNCT
eurjchem-1598	22	9	antihelmintic	antihelmintic	ADJ
eurjchem-1598	22	10	and	and	CCONJ
eurjchem-1598	22	11	antitumor	antitumor	PROPN
eurjchem-1598	22	12	activity	activity	NOUN
eurjchem-1598	23	1	[	[	X
eurjchem-1598	23	2	7	7	NUM
eurjchem-1598	23	3	]	]	PUNCT
eurjchem-1598	23	4	.	.	PUNCT
eurjchem-1598	24	1	the	the	DET
eurjchem-1598	24	2	numbering	numbering	NOUN
eurjchem-1598	24	3	system	system	NOUN
eurjchem-1598	24	4	for	for	ADP
eurjchem-1598	24	5	benzimidazoles	benzimidazole	NOUN
eurjchem-1598	24	6	is	be	AUX
eurjchem-1598	24	7	given	give	VERB
eurjchem-1598	24	8	in	in	ADP
eurjchem-1598	24	9	scheme	scheme	NOUN
eurjchem-1598	24	10	1	1	NUM
eurjchem-1598	24	11	[	[	X
eurjchem-1598	24	12	3	3	NUM
eurjchem-1598	24	13	]	]	PUNCT
eurjchem-1598	24	14	.	.	PUNCT
eurjchem-1598	25	1	substi‐	substi‐	PROPN
eurjchem-1598	25	2	tution	tution	PROPN
eurjchem-1598	25	3	at	at	ADP
eurjchem-1598	25	4	2	2	NUM
eurjchem-1598	25	5	position	position	NOUN
eurjchem-1598	25	6	of	of	ADP
eurjchem-1598	25	7	benzimidazole	benzimidazole	ADJ
eurjchem-1598	25	8	ring	ring	NOUN
eurjchem-1598	25	9	is	be	AUX
eurjchem-1598	25	10	very	very	ADV
eurjchem-1598	25	11	important	important	ADJ
eurjchem-1598	25	12	for	for	ADP
eurjchem-1598	25	13	their	their	PRON
eurjchem-1598	25	14	pharmacological	pharmacological	ADJ
eurjchem-1598	25	15	effect	effect	NOUN
eurjchem-1598	25	16	[	[	X
eurjchem-1598	25	17	8	8	NUM
eurjchem-1598	25	18	]	]	PUNCT
eurjchem-1598	25	19	.	.	PUNCT
eurjchem-1598	26	1	scheme	scheme	NOUN
eurjchem-1598	26	2	1	1	NUM
eurjchem-1598	26	3	2	2	NUM
eurjchem-1598	26	4	.	.	PUNCT
eurjchem-1598	26	5	experimental	experimental	ADJ
eurjchem-1598	26	6	2.1	2.1	NUM
eurjchem-1598	26	7	.	.	PUNCT
eurjchem-1598	27	1	apparatus	apparatus	NOUN
eurjchem-1598	27	2	ft‐ir	ft‐ir	NOUN
eurjchem-1598	27	3	spectra	spectra	PROPN
eurjchem-1598	27	4	were	be	AUX
eurjchem-1598	27	5	recorded	record	VERB
eurjchem-1598	27	6	in	in	ADP
eurjchem-1598	27	7	the	the	DET
eurjchem-1598	27	8	range	range	NOUN
eurjchem-1598	27	9	4000‐500	4000‐500	NUM
eurjchem-1598	27	10	cm‐1	cm‐1	NOUN
eurjchem-1598	27	11	using	use	VERB
eurjchem-1598	27	12	kbr	kbr	PROPN
eurjchem-1598	27	13	disc	disc	NOUN
eurjchem-1598	27	14	on	on	ADP
eurjchem-1598	27	15	shimadzu	shimadzu	ADJ
eurjchem-1598	27	16	ft‐ir	ft‐ir	ADJ
eurjchem-1598	27	17	8400s	8400	NOUN
eurjchem-1598	27	18	spectrometer	spectrometer	NOUN
eurjchem-1598	27	19	.	.	PUNCT
eurjchem-1598	28	1	1hand	1hand	NUM
eurjchem-1598	28	2	13c	13c	NOUN
eurjchem-1598	28	3	nmr	nmr	NOUN
eurjchem-1598	28	4	spectra	spectra	NOUN
eurjchem-1598	28	5	were	be	AUX
eurjchem-1598	28	6	recorded	record	VERB
eurjchem-1598	28	7	on	on	ADP
eurjchem-1598	28	8	bruker	bruker	NOUN
eurjchem-1598	28	9	400	400	NUM
eurjchem-1598	28	10	spectrometer	spectrometer	NOUN
eurjchem-1598	28	11	(	(	PUNCT
eurjchem-1598	28	12	400	400	NUM
eurjchem-1598	28	13	mhz	mhz	NOUN
eurjchem-1598	28	14	for	for	ADP
eurjchem-1598	28	15	1h	1h	NUM
eurjchem-1598	28	16	nmr	nmr	NOUN
eurjchem-1598	28	17	and	and	CCONJ
eurjchem-1598	28	18	100	100	NUM
eurjchem-1598	28	19	mhz	mhz	NOUN
eurjchem-1598	28	20	for	for	ADP
eurjchem-1598	28	21	13c	13c	NOUN
eurjchem-1598	28	22	nmr	nmr	NOUN
eurjchem-1598	28	23	)	)	PUNCT
eurjchem-1598	28	24	using	use	VERB
eurjchem-1598	28	25	dmso‐	dmso‐	NUM
eurjchem-1598	28	26	d6	d6	NOUN
eurjchem-1598	28	27	as	as	ADP
eurjchem-1598	28	28	a	a	DET
eurjchem-1598	28	29	solvent	solvent	NOUN
eurjchem-1598	28	30	and	and	CCONJ
eurjchem-1598	28	31	tms	tms	PROPN
eurjchem-1598	28	32	as	as	ADP
eurjchem-1598	28	33	an	an	DET
eurjchem-1598	28	34	internal	internal	ADJ
eurjchem-1598	28	35	reference	reference	NOUN
eurjchem-1598	28	36	.	.	PUNCT
eurjchem-1598	29	1	mass	mass	PROPN
eurjchem-1598	29	2	spectrum	spectrum	NOUN
eurjchem-1598	29	3	for	for	ADP
eurjchem-1598	29	4	the	the	DET
eurjchem-1598	29	5	ligand	ligand	NOUN
eurjchem-1598	29	6	was	be	AUX
eurjchem-1598	29	7	recorded	record	VERB
eurjchem-1598	29	8	on	on	ADP
eurjchem-1598	29	9	agilent	agilent	PROPN
eurjchem-1598	29	10	technologies‐	technologies‐	PROPN
eurjchem-1598	29	11	5975c	5975c	PROPN
eurjchem-1598	29	12	(	(	PUNCT
eurjchem-1598	29	13	ei	ei	PROPN
eurjchem-1598	29	14	,	,	PUNCT
eurjchem-1598	29	15	70	70	NUM
eurjchem-1598	29	16	ev	ev	NOUN
eurjchem-1598	29	17	)	)	PUNCT
eurjchem-1598	29	18	.	.	PUNCT
eurjchem-1598	30	1	the	the	DET
eurjchem-1598	30	2	thermal	thermal	ADJ
eurjchem-1598	30	3	analyses	analysis	NOUN
eurjchem-1598	30	4	(	(	PUNCT
eurjchem-1598	30	5	tg	tg	PROPN
eurjchem-1598	30	6	and	and	CCONJ
eurjchem-1598	30	7	dtg	dtg	PROPN
eurjchem-1598	30	8	)	)	PUNCT
eurjchem-1598	30	9	were	be	AUX
eurjchem-1598	30	10	carried	carry	VERB
eurjchem-1598	30	11	out	out	ADP
eurjchem-1598	30	12	in	in	ADP
eurjchem-1598	30	13	dynamic	dynamic	ADJ
eurjchem-1598	30	14	nitrogen	nitrogen	NOUN
eurjchem-1598	30	15	atmosphere	atmosphere	NOUN
eurjchem-1598	30	16	(	(	PUNCT
eurjchem-1598	30	17	20	20	NUM
eurjchem-1598	30	18	ml	ml	NOUN
eurjchem-1598	30	19	/	/	SYM
eurjchem-1598	30	20	min	min	NOUN
eurjchem-1598	30	21	)	)	PUNCT
eurjchem-1598	30	22	with	with	ADP
eurjchem-1598	30	23	a	a	DET
eurjchem-1598	30	24	heating	heating	NOUN
eurjchem-1598	30	25	rate	rate	NOUN
eurjchem-1598	30	26	of	of	ADP
eurjchem-1598	30	27	10	10	NUM
eurjchem-1598	30	28	°	°	NOUN
eurjchem-1598	30	29	c	c	NOUN
eurjchem-1598	30	30	/	/	SYM
eurjchem-1598	30	31	min	min	NOUN
eurjchem-1598	30	32	using	use	VERB
eurjchem-1598	30	33	a	a	DET
eurjchem-1598	30	34	perkin‐elmer	perkin‐elmer	ADJ
eurjchem-1598	30	35	thermal	thermal	ADJ
eurjchem-1598	30	36	analyzer	analyzer	NOUN
eurjchem-1598	30	37	.	.	PUNCT
eurjchem-1598	31	1	hadi	hadi	PROPN
eurjchem-1598	31	2	et	et	PROPN
eurjchem-1598	31	3	al	al	PROPN
eurjchem-1598	31	4	.	.	PUNCT
eurjchem-1598	31	5	/	/	SYM
eurjchem-1598	31	6	european	european	PROPN
eurjchem-1598	31	7	journal	journal	PROPN
eurjchem-1598	31	8	of	of	ADP
eurjchem-1598	31	9	chemistry	chemistry	NOUN
eurjchem-1598	31	10	8	8	NUM
eurjchem-1598	31	11	(	(	PUNCT
eurjchem-1598	31	12	3	3	NUM
eurjchem-1598	31	13	)	)	PUNCT
eurjchem-1598	31	14	(	(	PUNCT
eurjchem-1598	31	15	2017	2017	NUM
eurjchem-1598	31	16	)	)	PUNCT
eurjchem-1598	31	17	252‐257	252‐257	NOUN
eurjchem-1598	31	18	253	253	NUM
eurjchem-1598	31	19	scheme	scheme	NOUN
eurjchem-1598	31	20	2	2	NUM
eurjchem-1598	31	21	the	the	DET
eurjchem-1598	31	22	tlc	tlc	NOUN
eurjchem-1598	31	23	type	type	NOUN
eurjchem-1598	31	24	silica	silica	NOUN
eurjchem-1598	31	25	gel	gel	NOUN
eurjchem-1598	31	26	60f254	60f254	NOUN
eurjchem-1598	31	27	was	be	AUX
eurjchem-1598	31	28	used	use	VERB
eurjchem-1598	31	29	to	to	PART
eurjchem-1598	31	30	monitor	monitor	VERB
eurjchem-1598	31	31	the	the	DET
eurjchem-1598	31	32	reaction	reaction	NOUN
eurjchem-1598	31	33	and	and	CCONJ
eurjchem-1598	31	34	the	the	DET
eurjchem-1598	31	35	spots	spot	NOUN
eurjchem-1598	31	36	were	be	AUX
eurjchem-1598	31	37	visualized	visualize	VERB
eurjchem-1598	31	38	by	by	ADP
eurjchem-1598	31	39	uv	uv	NOUN
eurjchem-1598	31	40	lamp	lamp	NOUN
eurjchem-1598	31	41	black‐ray‐	black‐ray‐	VERB
eurjchem-1598	31	42	b‐100a	b‐100a	PROPN
eurjchem-1598	31	43	.	.	PUNCT
eurjchem-1598	32	1	molar	molar	ADJ
eurjchem-1598	32	2	conductance	conductance	NOUN
eurjchem-1598	32	3	of	of	ADP
eurjchem-1598	32	4	the	the	DET
eurjchem-1598	32	5	freshly	freshly	ADV
eurjchem-1598	32	6	prepared	prepare	VERB
eurjchem-1598	32	7	solutions	solution	NOUN
eurjchem-1598	32	8	(	(	PUNCT
eurjchem-1598	32	9	1×10‐3	1×10‐3	NUM
eurjchem-1598	32	10	m	m	PROPN
eurjchem-1598	32	11	in	in	ADP
eurjchem-1598	32	12	dmso	dmso	NOUN
eurjchem-1598	32	13	)	)	PUNCT
eurjchem-1598	32	14	was	be	AUX
eurjchem-1598	32	15	measured	measure	VERB
eurjchem-1598	32	16	at	at	ADP
eurjchem-1598	32	17	room	room	NOUN
eurjchem-1598	32	18	temperature	temperature	NOUN
eurjchem-1598	32	19	using	use	VERB
eurjchem-1598	32	20	w.t.w‐conductivity	w.t.w‐conductivity	NOUN
eurjchem-1598	32	21	meter	meter	NOUN
eurjchem-1598	32	22	.	.	PUNCT
eurjchem-1598	33	1	the	the	DET
eurjchem-1598	33	2	metal	metal	NOUN
eurjchem-1598	33	3	content	content	NOUN
eurjchem-1598	33	4	of	of	ADP
eurjchem-1598	33	5	the	the	DET
eurjchem-1598	33	6	prepared	prepared	ADJ
eurjchem-1598	33	7	complex	complex	NOUN
eurjchem-1598	33	8	was	be	AUX
eurjchem-1598	33	9	found	find	VERB
eurjchem-1598	33	10	by	by	ADP
eurjchem-1598	33	11	a	a	DET
eurjchem-1598	33	12	buck	buck	NOUN
eurjchem-1598	33	13	210	210	NUM
eurjchem-1598	33	14	bgp	bgp	PROPN
eurjchem-1598	33	15	model	model	NOUN
eurjchem-1598	33	16	atomic	atomic	PROPN
eurjchem-1598	33	17	absorption	absorption	NOUN
eurjchem-1598	33	18	spectrometer	spectrometer	NOUN
eurjchem-1598	33	19	after	after	ADP
eurjchem-1598	33	20	digestion	digestion	NOUN
eurjchem-1598	33	21	in	in	ADP
eurjchem-1598	33	22	nitric	nitric	ADJ
eurjchem-1598	33	23	acid	acid	NOUN
eurjchem-1598	33	24	.	.	PUNCT
eurjchem-1598	34	1	elemental	elemental	ADJ
eurjchem-1598	34	2	analyses	analysis	NOUN
eurjchem-1598	34	3	for	for	ADP
eurjchem-1598	34	4	c	c	NOUN
eurjchem-1598	34	5	,	,	PUNCT
eurjchem-1598	34	6	h	h	NOUN
eurjchem-1598	34	7	and	and	CCONJ
eurjchem-1598	34	8	n	n	PROPN
eurjchem-1598	34	9	were	be	AUX
eurjchem-1598	34	10	performed	perform	VERB
eurjchem-1598	34	11	using	use	VERB
eurjchem-1598	34	12	a	a	DET
eurjchem-1598	34	13	leco	leco	PROPN
eurjchem-1598	34	14	chns‐932	chns‐932	NOUN
eurjchem-1598	34	15	analyzer	analyzer	NOUN
eurjchem-1598	34	16	.	.	PUNCT
eurjchem-1598	35	1	2.2	2.2	NUM
eurjchem-1598	35	2	.	.	PUNCT
eurjchem-1598	35	3	materials	material	NOUN
eurjchem-1598	35	4	and	and	CCONJ
eurjchem-1598	35	5	methods	method	NOUN
eurjchem-1598	35	6	2.2.1	2.2.1	NUM
eurjchem-1598	35	7	.	.	PUNCT
eurjchem-1598	35	8	material	material	PROPN
eurjchem-1598	35	9	4‐methyl‐1,2‐phenelyenediamine	4‐methyl‐1,2‐phenelyenediamine	PROPN
eurjchem-1598	35	10	from	from	ADP
eurjchem-1598	35	11	merck	merck	PROPN
eurjchem-1598	35	12	and	and	CCONJ
eurjchem-1598	35	13	used	use	VERB
eurjchem-1598	35	14	after	after	ADP
eurjchem-1598	35	15	recrystallization	recrystallization	NOUN
eurjchem-1598	35	16	from	from	ADP
eurjchem-1598	35	17	hexane	hexane	NOUN
eurjchem-1598	35	18	.	.	PUNCT
eurjchem-1598	36	1	indol‐3‐carboxaldehyde	indol‐3‐carboxaldehyde	NUM
eurjchem-1598	36	2	from	from	ADP
eurjchem-1598	36	3	himedia	himedia	NOUN
eurjchem-1598	36	4	and	and	CCONJ
eurjchem-1598	36	5	used	use	VERB
eurjchem-1598	36	6	as	as	SCONJ
eurjchem-1598	36	7	supplied	supply	VERB
eurjchem-1598	36	8	various	various	ADJ
eurjchem-1598	36	9	metal	metal	NOUN
eurjchem-1598	36	10	(	(	PUNCT
eurjchem-1598	36	11	ii	ii	NOUN
eurjchem-1598	36	12	)	)	PUNCT
eurjchem-1598	36	13	acetate	acetate	NOUN
eurjchem-1598	36	14	were	be	AUX
eurjchem-1598	36	15	of	of	ADP
eurjchem-1598	36	16	fluka	fluka	NOUN
eurjchem-1598	36	17	,	,	PUNCT
eurjchem-1598	36	18	all	all	DET
eurjchem-1598	36	19	other	other	ADJ
eurjchem-1598	36	20	solvents	solvent	NOUN
eurjchem-1598	36	21	are	be	AUX
eurjchem-1598	36	22	of	of	ADP
eurjchem-1598	36	23	analytical	analytical	ADJ
eurjchem-1598	36	24	grade	grade	NOUN
eurjchem-1598	36	25	.	.	PUNCT
eurjchem-1598	37	1	2.2.2	2.2.2	X
eurjchem-1598	37	2	.	.	X
eurjchem-1598	37	3	synthesis	synthesis	NOUN
eurjchem-1598	37	4	2.2.2.1	2.2.2.1	NUM
eurjchem-1598	37	5	.	.	PUNCT
eurjchem-1598	37	6	synthesis	synthesis	NOUN
eurjchem-1598	37	7	of	of	ADP
eurjchem-1598	37	8	ligand	ligand	NOUN
eurjchem-1598	37	9	,	,	PUNCT
eurjchem-1598	37	10	2‐(1h‐indol‐3‐yl)‐5‐methyl‐1h‐	2‐(1h‐indol‐3‐yl)‐5‐methyl‐1h‐	NUM
eurjchem-1598	37	11	benzo[d]imidazole	benzo[d]imidazole	NOUN
eurjchem-1598	37	12	an	an	DET
eurjchem-1598	37	13	ethanolic	ethanolic	ADJ
eurjchem-1598	37	14	solution	solution	NOUN
eurjchem-1598	37	15	(	(	PUNCT
eurjchem-1598	37	16	15	15	NUM
eurjchem-1598	37	17	ml	ml	NOUN
eurjchem-1598	37	18	)	)	PUNCT
eurjchem-1598	37	19	of	of	ADP
eurjchem-1598	37	20	5	5	NUM
eurjchem-1598	37	21	mmole	mmole	NOUN
eurjchem-1598	37	22	(	(	PUNCT
eurjchem-1598	37	23	0.725	0.725	NUM
eurjchem-1598	37	24	g	g	NOUN
eurjchem-1598	37	25	)	)	PUNCT
eurjchem-1598	37	26	of	of	ADP
eurjchem-1598	37	27	indole‐3‐carboxaldehyde	indole‐3‐carboxaldehyde	PROPN
eurjchem-1598	37	28	and	and	CCONJ
eurjchem-1598	37	29	ethanolic	ethanolic	ADJ
eurjchem-1598	37	30	solution	solution	NOUN
eurjchem-1598	37	31	(	(	PUNCT
eurjchem-1598	37	32	10	10	NUM
eurjchem-1598	37	33	ml	ml	NOUN
eurjchem-1598	37	34	)	)	PUNCT
eurjchem-1598	37	35	of	of	ADP
eurjchem-1598	37	36	5	5	NUM
eurjchem-1598	37	37	mmole	mmole	NOUN
eurjchem-1598	37	38	(	(	PUNCT
eurjchem-1598	37	39	0.61	0.61	NUM
eurjchem-1598	37	40	g	g	NOUN
eurjchem-1598	37	41	)	)	PUNCT
eurjchem-1598	37	42	of	of	ADP
eurjchem-1598	37	43	4‐methyl‐1,2‐phenelyene	4‐methyl‐1,2‐phenelyene	ADJ
eurjchem-1598	37	44	diamine	diamine	NOUN
eurjchem-1598	37	45	mixed	mix	VERB
eurjchem-1598	37	46	and	and	CCONJ
eurjchem-1598	37	47	refluxed	refluxe	VERB
eurjchem-1598	37	48	in	in	ADP
eurjchem-1598	37	49	presence	presence	NOUN
eurjchem-1598	37	50	of	of	ADP
eurjchem-1598	37	51	2	2	NUM
eurjchem-1598	37	52	drops	drop	NOUN
eurjchem-1598	37	53	of	of	ADP
eurjchem-1598	37	54	concentrated	concentrated	ADJ
eurjchem-1598	37	55	sulphuric	sulphuric	ADJ
eurjchem-1598	37	56	acid	acid	NOUN
eurjchem-1598	38	1	[	[	X
eurjchem-1598	38	2	2	2	NUM
eurjchem-1598	38	3	]	]	PUNCT
eurjchem-1598	38	4	for	for	ADP
eurjchem-1598	38	5	2h	2h	NUM
eurjchem-1598	38	6	with	with	ADP
eurjchem-1598	38	7	continuous	continuous	ADJ
eurjchem-1598	38	8	stirring	stirring	NOUN
eurjchem-1598	38	9	.	.	PUNCT
eurjchem-1598	39	1	the	the	DET
eurjchem-1598	39	2	orange	orange	PROPN
eurjchem-1598	39	3	precipitate	precipitate	PROPN
eurjchem-1598	39	4	which	which	PRON
eurjchem-1598	39	5	separated	separate	VERB
eurjchem-1598	39	6	filtered	filter	VERB
eurjchem-1598	39	7	hot	hot	ADJ
eurjchem-1598	39	8	and	and	CCONJ
eurjchem-1598	39	9	washed	wash	VERB
eurjchem-1598	39	10	with	with	ADP
eurjchem-1598	39	11	hot	hot	ADJ
eurjchem-1598	39	12	ethanol	ethanol	NOUN
eurjchem-1598	39	13	and	and	CCONJ
eurjchem-1598	39	14	then	then	ADV
eurjchem-1598	39	15	with	with	ADP
eurjchem-1598	39	16	ether	ether	NOUN
eurjchem-1598	39	17	several	several	ADJ
eurjchem-1598	39	18	times	time	NOUN
eurjchem-1598	39	19	and	and	CCONJ
eurjchem-1598	39	20	dried	dry	VERB
eurjchem-1598	39	21	at	at	ADP
eurjchem-1598	39	22	70	70	NUM
eurjchem-1598	39	23	°	°	ADP
eurjchem-1598	39	24	c	c	NOUN
eurjchem-1598	39	25	in	in	ADP
eurjchem-1598	39	26	oven	oven	PROPN
eurjchem-1598	39	27	.	.	PUNCT
eurjchem-1598	40	1	the	the	DET
eurjchem-1598	40	2	crude	crude	ADJ
eurjchem-1598	40	3	product	product	NOUN
eurjchem-1598	40	4	was	be	AUX
eurjchem-1598	40	5	recrystallized	recrystallize	VERB
eurjchem-1598	40	6	from	from	ADP
eurjchem-1598	40	7	dmf	dmf	PROPN
eurjchem-1598	40	8	:	:	PUNCT
eurjchem-1598	40	9	h2o	h2o	PROPN
eurjchem-1598	40	10	(	(	PUNCT
eurjchem-1598	40	11	1:10	1:10	NUM
eurjchem-1598	40	12	,	,	PUNCT
eurjchem-1598	40	13	v	v	NOUN
eurjchem-1598	40	14	:	:	PUNCT
eurjchem-1598	40	15	v	v	NOUN
eurjchem-1598	40	16	)	)	PUNCT
eurjchem-1598	40	17	.	.	PUNCT
eurjchem-1598	41	1	color	color	NOUN
eurjchem-1598	41	2	:	:	PUNCT
eurjchem-1598	41	3	reddish	reddish	ADJ
eurjchem-1598	41	4	orange	orange	PROPN
eurjchem-1598	41	5	.	.	PUNCT
eurjchem-1598	42	1	yield	yield	NOUN
eurjchem-1598	42	2	:	:	PUNCT
eurjchem-1598	42	3	70	70	NUM
eurjchem-1598	42	4	%	%	NOUN
eurjchem-1598	42	5	.	.	PUNCT
eurjchem-1598	43	1	m.p	m.p	PROPN
eurjchem-1598	43	2	.	.	PROPN
eurjchem-1598	43	3	:	:	PUNCT
eurjchem-1598	44	1	235‐237	235‐237	NUM
eurjchem-1598	44	2	°	°	SYM
eurjchem-1598	44	3	c	c	X
eurjchem-1598	44	4	.	.	PUNCT
eurjchem-1598	45	1	ft‐ir	ft‐ir	NOUN
eurjchem-1598	45	2	(	(	PUNCT
eurjchem-1598	45	3	kbr	kbr	PROPN
eurjchem-1598	45	4	,	,	PUNCT
eurjchem-1598	45	5			PROPN
eurjchem-1598	45	6	,	,	PUNCT
eurjchem-1598	45	7	cm‐1	cm‐1	PROPN
eurjchem-1598	45	8	):	):	PUNCT
eurjchem-1598	45	9	3400	3400	NUM
eurjchem-1598	45	10	(	(	PUNCT
eurjchem-1598	45	11	n‐h	n‐h	PROPN
eurjchem-1598	45	12	,	,	PUNCT
eurjchem-1598	45	13	benz	benz	PROPN
eurjchem-1598	45	14	.	.	PUNCT
eurjchem-1598	45	15	)	)	PUNCT
eurjchem-1598	45	16	,	,	PUNCT
eurjchem-1598	45	17	3128	3128	NUM
eurjchem-1598	45	18	(	(	PUNCT
eurjchem-1598	45	19	n‐h	n‐h	SYM
eurjchem-1598	45	20	,	,	PUNCT
eurjchem-1598	45	21	indole	indole	NOUN
eurjchem-1598	45	22	)	)	PUNCT
eurjchem-1598	45	23	,	,	PUNCT
eurjchem-1598	45	24	3047	3047	NUM
eurjchem-1598	45	25	(	(	PUNCT
eurjchem-1598	45	26	ar‐h	ar‐h	NOUN
eurjchem-1598	45	27	)	)	PUNCT
eurjchem-1598	45	28	,	,	PUNCT
eurjchem-1598	45	29	2920	2920	NUM
eurjchem-1598	45	30	,	,	PUNCT
eurjchem-1598	45	31	2866	2866	NUM
eurjchem-1598	45	32	(	(	PUNCT
eurjchem-1598	45	33	ch3	ch3	PROPN
eurjchem-1598	45	34	)	)	PUNCT
eurjchem-1598	45	35	,	,	PUNCT
eurjchem-1598	45	36	1633	1633	NUM
eurjchem-1598	45	37	(	(	PUNCT
eurjchem-1598	45	38	c	c	NOUN
eurjchem-1598	45	39	=	=	SYM
eurjchem-1598	45	40	n	n	NUM
eurjchem-1598	45	41	)	)	PUNCT
eurjchem-1598	45	42	.	.	PUNCT
eurjchem-1598	46	1	1h	1h	NUM
eurjchem-1598	46	2	nmr	nmr	NOUN
eurjchem-1598	46	3	(	(	PUNCT
eurjchem-1598	46	4	400	400	NUM
eurjchem-1598	46	5	mhz	mhz	NOUN
eurjchem-1598	46	6	,	,	PUNCT
eurjchem-1598	46	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1598	46	8	,	,	PUNCT
eurjchem-1598	46	9	δ	δ	PROPN
eurjchem-1598	46	10	,	,	PUNCT
eurjchem-1598	46	11	ppm	ppm	NUM
eurjchem-1598	46	12	):	):	PUNCT
eurjchem-1598	46	13	2.30	2.30	NUM
eurjchem-1598	46	14	(	(	PUNCT
eurjchem-1598	46	15	s	s	PROPN
eurjchem-1598	46	16	,	,	PUNCT
eurjchem-1598	46	17	3h	3h	NUM
eurjchem-1598	46	18	,	,	PUNCT
eurjchem-1598	46	19	ch3	ch3	PROPN
eurjchem-1598	46	20	)	)	PUNCT
eurjchem-1598	46	21	,	,	PUNCT
eurjchem-1598	46	22	7.05‐8.33	7.05‐8.33	PROPN
eurjchem-1598	46	23	(	(	PUNCT
eurjchem-1598	46	24	m	m	PROPN
eurjchem-1598	46	25	,	,	PUNCT
eurjchem-1598	46	26	8h	8h	NUM
eurjchem-1598	46	27	,	,	PUNCT
eurjchem-1598	46	28	ar‐h	ar‐h	PROPN
eurjchem-1598	46	29	)	)	PUNCT
eurjchem-1598	46	30	,	,	PUNCT
eurjchem-1598	46	31	11.00	11.00	NUM
eurjchem-1598	46	32	(	(	PUNCT
eurjchem-1598	46	33	s	s	PROPN
eurjchem-1598	46	34	,	,	PUNCT
eurjchem-1598	46	35	1h	1h	NUM
eurjchem-1598	46	36	,	,	PUNCT
eurjchem-1598	46	37	nh‐indole	nh‐indole	NUM
eurjchem-1598	46	38	)	)	PUNCT
eurjchem-1598	46	39	,	,	PUNCT
eurjchem-1598	46	40	11.86	11.86	NUM
eurjchem-1598	46	41	(	(	PUNCT
eurjchem-1598	46	42	s	s	PROPN
eurjchem-1598	46	43	,	,	PUNCT
eurjchem-1598	46	44	1h	1h	NUM
eurjchem-1598	46	45	,	,	PUNCT
eurjchem-1598	46	46	nh‐imidazole	nh‐imidazole	NOUN
eurjchem-1598	46	47	)	)	PUNCT
eurjchem-1598	46	48	.	.	PUNCT
eurjchem-1598	47	1	13c	13c	NOUN
eurjchem-1598	47	2	nmr	nmr	NOUN
eurjchem-1598	47	3	(	(	PUNCT
eurjchem-1598	47	4	100	100	NUM
eurjchem-1598	47	5	mhz	mhz	NOUN
eurjchem-1598	47	6	,	,	PUNCT
eurjchem-1598	47	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1598	47	8	,	,	PUNCT
eurjchem-1598	47	9	δ	δ	PROPN
eurjchem-1598	47	10	,	,	PUNCT
eurjchem-1598	47	11	ppm	ppm	NUM
eurjchem-1598	47	12	):	):	PUNCT
eurjchem-1598	47	13	149.50	149.50	NUM
eurjchem-1598	47	14	(	(	PUNCT
eurjchem-1598	47	15	c16	c16	PROPN
eurjchem-1598	47	16	)	)	PUNCT
eurjchem-1598	47	17	,	,	PUNCT
eurjchem-1598	47	18	136.29	136.29	NUM
eurjchem-1598	47	19	(	(	PUNCT
eurjchem-1598	47	20	c2	c2	PROPN
eurjchem-1598	47	21	)	)	PUNCT
eurjchem-1598	47	22	,	,	PUNCT
eurjchem-1598	47	23	135.99	135.99	NUM
eurjchem-1598	47	24	(	(	PUNCT
eurjchem-1598	47	25	c10	c10	PROPN
eurjchem-1598	47	26	)	)	PUNCT
eurjchem-1598	47	27	,	,	PUNCT
eurjchem-1598	47	28	133.71	133.71	NUM
eurjchem-1598	47	29	(	(	PUNCT
eurjchem-1598	47	30	c14	c14	NOUN
eurjchem-1598	47	31	)	)	PUNCT
eurjchem-1598	47	32	,	,	PUNCT
eurjchem-1598	47	33	130.22	130.22	NUM
eurjchem-1598	47	34	(	(	PUNCT
eurjchem-1598	47	35	c11	c11	NOUN
eurjchem-1598	47	36	)	)	PUNCT
eurjchem-1598	47	37	,	,	PUNCT
eurjchem-1598	47	38	126.16	126.16	NUM
eurjchem-1598	47	39	(	(	PUNCT
eurjchem-1598	47	40	c3	c3	PROPN
eurjchem-1598	47	41	)	)	PUNCT
eurjchem-1598	47	42	,	,	PUNCT
eurjchem-1598	47	43	125.98	125.98	NUM
eurjchem-1598	47	44	(	(	PUNCT
eurjchem-1598	47	45	c7	c7	PROPN
eurjchem-1598	47	46	)	)	PUNCT
eurjchem-1598	47	47	,	,	PUNCT
eurjchem-1598	47	48	125.51	125.51	NUM
eurjchem-1598	47	49	(	(	PUNCT
eurjchem-1598	47	50	c13	c13	PROPN
eurjchem-1598	47	51	)	)	PUNCT
eurjchem-1598	47	52	,	,	PUNCT
eurjchem-1598	47	53	122.22	122.22	NUM
eurjchem-1598	47	54	(	(	PUNCT
eurjchem-1598	47	55	c6	c6	PROPN
eurjchem-1598	47	56	)	)	PUNCT
eurjchem-1598	47	57	,	,	PUNCT
eurjchem-1598	47	58	121.31	121.31	NUM
eurjchem-1598	47	59	(	(	PUNCT
eurjchem-1598	47	60	c4	c4	NOUN
eurjchem-1598	47	61	)	)	PUNCT
eurjchem-1598	47	62	,	,	PUNCT
eurjchem-1598	47	63	120.13	120.13	NUM
eurjchem-1598	47	64	(	(	PUNCT
eurjchem-1598	47	65	c5	c5	PROPN
eurjchem-1598	47	66	)	)	PUNCT
eurjchem-1598	47	67	,	,	PUNCT
eurjchem-1598	47	68	118.74	118.74	NUM
eurjchem-1598	47	69	(	(	PUNCT
eurjchem-1598	47	70	c9	c9	NOUN
eurjchem-1598	47	71	)	)	PUNCT
eurjchem-1598	47	72	,	,	PUNCT
eurjchem-1598	47	73	118.18	118.18	NUM
eurjchem-1598	47	74	(	(	PUNCT
eurjchem-1598	47	75	c12	c12	PROPN
eurjchem-1598	47	76	)	)	PUNCT
eurjchem-1598	47	77	,	,	PUNCT
eurjchem-1598	47	78	111.62	111.62	NUM
eurjchem-1598	47	79	(	(	PUNCT
eurjchem-1598	47	80	c1	c1	PROPN
eurjchem-1598	47	81	)	)	PUNCT
eurjchem-1598	47	82	,	,	PUNCT
eurjchem-1598	47	83	105.22	105.22	NUM
eurjchem-1598	47	84	(	(	PUNCT
eurjchem-1598	47	85	c8	c8	PROPN
eurjchem-1598	47	86	)	)	PUNCT
eurjchem-1598	47	87	,	,	PUNCT
eurjchem-1598	47	88	21.19	21.19	NUM
eurjchem-1598	47	89	(	(	PUNCT
eurjchem-1598	47	90	c15	c15	PROPN
eurjchem-1598	47	91	)	)	PUNCT
eurjchem-1598	47	92	.	.	PUNCT
eurjchem-1598	48	1	ms	ms	NOUN
eurjchem-1598	48	2	(	(	PUNCT
eurjchem-1598	48	3	ei	ei	PROPN
eurjchem-1598	48	4	,	,	PUNCT
eurjchem-1598	48	5	m	m	PROPN
eurjchem-1598	48	6	/	/	SYM
eurjchem-1598	48	7	z	z	PROPN
eurjchem-1598	48	8	(	(	PUNCT
eurjchem-1598	48	9	%	%	NOUN
eurjchem-1598	48	10	)	)	PUNCT
eurjchem-1598	48	11	):	):	PUNCT
eurjchem-1598	48	12	247.2	247.2	NUM
eurjchem-1598	48	13	(	(	PUNCT
eurjchem-1598	48	14	m+	m+	NUM
eurjchem-1598	48	15	,	,	PUNCT
eurjchem-1598	48	16	100	100	NUM
eurjchem-1598	48	17	)	)	PUNCT
eurjchem-1598	48	18	.	.	PUNCT
eurjchem-1598	49	1	anal	anal	PROPN
eurjchem-1598	49	2	.	.	PUNCT
eurjchem-1598	49	3	calcd	calcd	NOUN
eurjchem-1598	49	4	.	.	PUNCT
eurjchem-1598	50	1	for	for	ADP
eurjchem-1598	50	2	c16h13n3	c16h13n3	PROPN
eurjchem-1598	50	3	:	:	PUNCT
eurjchem-1598	50	4	c	c	X
eurjchem-1598	50	5	,	,	PUNCT
eurjchem-1598	50	6	77.71	77.71	NUM
eurjchem-1598	50	7	;	;	PUNCT
eurjchem-1598	50	8	h	h	NOUN
eurjchem-1598	50	9	,	,	PUNCT
eurjchem-1598	50	10	5.30	5.30	NUM
eurjchem-1598	50	11	;	;	PUNCT
eurjchem-1598	50	12	n	n	CCONJ
eurjchem-1598	50	13	,	,	PUNCT
eurjchem-1598	50	14	16.99	16.99	NUM
eurjchem-1598	50	15	.	.	PUNCT
eurjchem-1598	50	16	found	find	VERB
eurjchem-1598	50	17	:	:	PUNCT
eurjchem-1598	51	1	c	c	X
eurjchem-1598	51	2	,	,	PUNCT
eurjchem-1598	51	3	77.63	77.63	NUM
eurjchem-1598	51	4	;	;	PUNCT
eurjchem-1598	51	5	h	h	X
eurjchem-1598	51	6	,	,	PUNCT
eurjchem-1598	51	7	5.44	5.44	NUM
eurjchem-1598	51	8	;	;	PUNCT
eurjchem-1598	51	9	n	n	CCONJ
eurjchem-1598	51	10	,	,	PUNCT
eurjchem-1598	51	11	17.04	17.04	NUM
eurjchem-1598	51	12	%	%	NOUN
eurjchem-1598	51	13	.	.	PUNCT
eurjchem-1598	52	1	2.2.2.2	2.2.2.2	X
eurjchem-1598	52	2	.	.	NOUN
eurjchem-1598	52	3	synthesis	synthesis	NOUN
eurjchem-1598	52	4	of	of	ADP
eurjchem-1598	52	5	[	[	PUNCT
eurjchem-1598	52	6	cu(l)h2o.ch3coo].h2o	cu(l)h2o.ch3coo].h2o	NOUN
eurjchem-1598	52	7	(	(	PUNCT
eurjchem-1598	52	8	lcu	lcu	NOUN
eurjchem-1598	52	9	)	)	PUNCT
eurjchem-1598	52	10	ethanolic	ethanolic	ADJ
eurjchem-1598	52	11	solution	solution	NOUN
eurjchem-1598	52	12	(	(	PUNCT
eurjchem-1598	52	13	20	20	NUM
eurjchem-1598	52	14	ml	ml	NOUN
eurjchem-1598	52	15	)	)	PUNCT
eurjchem-1598	52	16	of	of	ADP
eurjchem-1598	52	17	1	1	NUM
eurjchem-1598	52	18	mmole	mmole	NOUN
eurjchem-1598	52	19	(	(	PUNCT
eurjchem-1598	52	20	0.247	0.247	NUM
eurjchem-1598	52	21	g	g	NOUN
eurjchem-1598	52	22	)	)	PUNCT
eurjchem-1598	52	23	of	of	ADP
eurjchem-1598	52	24	ligand	ligand	NOUN
eurjchem-1598	52	25	was	be	AUX
eurjchem-1598	52	26	add	add	VERB
eurjchem-1598	52	27	to	to	ADP
eurjchem-1598	52	28	a	a	DET
eurjchem-1598	52	29	hot	hot	ADJ
eurjchem-1598	52	30	ethanolic	ethanolic	ADJ
eurjchem-1598	52	31	solution	solution	NOUN
eurjchem-1598	52	32	(	(	PUNCT
eurjchem-1598	52	33	20	20	NUM
eurjchem-1598	52	34	ml	ml	NOUN
eurjchem-1598	52	35	)	)	PUNCT
eurjchem-1598	52	36	of	of	ADP
eurjchem-1598	52	37	cu(ch3coo)2	cu(ch3coo)2	PROPN
eurjchem-1598	52	38	(	(	PUNCT
eurjchem-1598	52	39	0.199	0.199	NUM
eurjchem-1598	52	40	g	g	NOUN
eurjchem-1598	52	41	)	)	PUNCT
eurjchem-1598	52	42	.	.	PUNCT
eurjchem-1598	53	1	the	the	DET
eurjchem-1598	53	2	resulting	result	VERB
eurjchem-1598	53	3	mixture	mixture	NOUN
eurjchem-1598	53	4	color	color	NOUN
eurjchem-1598	53	5	change	change	NOUN
eurjchem-1598	53	6	immediately	immediately	ADV
eurjchem-1598	53	7	to	to	ADP
eurjchem-1598	53	8	black	black	ADJ
eurjchem-1598	53	9	and	and	CCONJ
eurjchem-1598	53	10	then	then	ADV
eurjchem-1598	53	11	refluxing	refluxe	VERB
eurjchem-1598	53	12	for	for	ADP
eurjchem-1598	53	13	3	3	NUM
eurjchem-1598	53	14	h.	h.	NOUN
eurjchem-1598	53	15	,	,	PUNCT
eurjchem-1598	53	16	the	the	DET
eurjchem-1598	53	17	precipitate	precipitate	NOUN
eurjchem-1598	53	18	was	be	AUX
eurjchem-1598	53	19	filtered	filter	VERB
eurjchem-1598	53	20	and	and	CCONJ
eurjchem-1598	53	21	washed	wash	VERB
eurjchem-1598	53	22	with	with	ADP
eurjchem-1598	53	23	hot	hot	ADJ
eurjchem-1598	53	24	ethanol	ethanol	NOUN
eurjchem-1598	53	25	several	several	ADJ
eurjchem-1598	53	26	time	time	NOUN
eurjchem-1598	53	27	,	,	PUNCT
eurjchem-1598	53	28	then	then	ADV
eurjchem-1598	53	29	dried	dry	VERB
eurjchem-1598	53	30	to	to	PART
eurjchem-1598	53	31	afford	afford	VERB
eurjchem-1598	53	32	green	green	ADJ
eurjchem-1598	53	33	powder	powder	NOUN
eurjchem-1598	53	34	.	.	PUNCT
eurjchem-1598	54	1	color	color	NOUN
eurjchem-1598	54	2	:	:	PUNCT
eurjchem-1598	54	3	green	green	ADJ
eurjchem-1598	54	4	.	.	PUNCT
eurjchem-1598	55	1	yield	yield	NOUN
eurjchem-1598	55	2	:	:	PUNCT
eurjchem-1598	55	3	72	72	NUM
eurjchem-1598	55	4	%	%	NOUN
eurjchem-1598	55	5	.	.	PUNCT
eurjchem-1598	56	1	m.p	m.p	PROPN
eurjchem-1598	56	2	.	.	PROPN
eurjchem-1598	56	3	:	:	PUNCT
eurjchem-1598	57	1	>	>	X
eurjchem-1598	57	2	300	300	NUM
eurjchem-1598	57	3	°	°	SYM
eurjchem-1598	57	4	c	c	NOUN
eurjchem-1598	57	5	.	.	PUNCT
eurjchem-1598	58	1	ft‐ir	ft‐ir	NOUN
eurjchem-1598	58	2	(	(	PUNCT
eurjchem-1598	58	3	kbr	kbr	PROPN
eurjchem-1598	58	4	,	,	PUNCT
eurjchem-1598	58	5			PROPN
eurjchem-1598	58	6	,	,	PUNCT
eurjchem-1598	58	7	cm‐1	cm‐1	PROPN
eurjchem-1598	58	8	):	):	PUNCT
eurjchem-1598	58	9	3400	3400	NUM
eurjchem-1598	58	10	(	(	PUNCT
eurjchem-1598	58	11	n‐h	n‐h	PROPN
eurjchem-1598	58	12	,	,	PUNCT
eurjchem-1598	58	13	benz	benz	PROPN
eurjchem-1598	58	14	.	.	PUNCT
eurjchem-1598	58	15	)	)	PUNCT
eurjchem-1598	58	16	,	,	PUNCT
eurjchem-1598	58	17	1616	1616	NUM
eurjchem-1598	58	18	(	(	PUNCT
eurjchem-1598	58	19	c	c	NOUN
eurjchem-1598	58	20	=	=	SYM
eurjchem-1598	58	21	n	n	NUM
eurjchem-1598	58	22	)	)	PUNCT
eurjchem-1598	58	23	.	.	PUNCT
eurjchem-1598	59	1	anal	anal	PROPN
eurjchem-1598	59	2	.	.	PUNCT
eurjchem-1598	59	3	calcd	calcd	NOUN
eurjchem-1598	59	4	.	.	PUNCT
eurjchem-1598	60	1	for	for	ADP
eurjchem-1598	60	2	c18h19n3o4cu	c18h19n3o4cu	PROPN
eurjchem-1598	60	3	:	:	PUNCT
eurjchem-1598	60	4	c	c	NUM
eurjchem-1598	60	5	,	,	PUNCT
eurjchem-1598	60	6	53.39	53.39	NUM
eurjchem-1598	60	7	,	,	PUNCT
eurjchem-1598	60	8	h	h	NOUN
eurjchem-1598	60	9	,	,	PUNCT
eurjchem-1598	60	10	4.73	4.73	NUM
eurjchem-1598	60	11	,	,	PUNCT
eurjchem-1598	60	12	n	n	CCONJ
eurjchem-1598	60	13	,	,	PUNCT
eurjchem-1598	60	14	10.38	10.38	NUM
eurjchem-1598	60	15	,	,	PUNCT
eurjchem-1598	60	16	cu	cu	PROPN
eurjchem-1598	60	17	,	,	PUNCT
eurjchem-1598	60	18	15.69	15.69	NUM
eurjchem-1598	60	19	.	.	PUNCT
eurjchem-1598	61	1	found	find	VERB
eurjchem-1598	61	2	:	:	PUNCT
eurjchem-1598	62	1	c	c	X
eurjchem-1598	62	2	,	,	PUNCT
eurjchem-1598	62	3	51.97	51.97	NUM
eurjchem-1598	62	4	;	;	PUNCT
eurjchem-1598	62	5	h	h	NOUN
eurjchem-1598	62	6	,	,	PUNCT
eurjchem-1598	62	7	4.87	4.87	NUM
eurjchem-1598	62	8	;	;	PUNCT
eurjchem-1598	62	9	n	n	CCONJ
eurjchem-1598	62	10	,	,	PUNCT
eurjchem-1598	62	11	10.69	10.69	NUM
eurjchem-1598	62	12	;	;	PUNCT
eurjchem-1598	62	13	cu	cu	PROPN
eurjchem-1598	62	14	,	,	PUNCT
eurjchem-1598	62	15	16.43	16.43	NUM
eurjchem-1598	62	16	%	%	NOUN
eurjchem-1598	62	17	.	.	PUNCT
eurjchem-1598	63	1	λm	λm	X
eurjchem-1598	63	2	(	(	PUNCT
eurjchem-1598	63	3	s.m2.mol‐1	s.m2.mol‐1	PROPN
eurjchem-1598	63	4	):	):	PUNCT
eurjchem-1598	63	5	6.1	6.1	NUM
eurjchem-1598	63	6	.	.	PUNCT
eurjchem-1598	64	1	2.2.2.3	2.2.2.3	NUM
eurjchem-1598	64	2	.	.	PUNCT
eurjchem-1598	65	1	synthesis	synthesis	NOUN
eurjchem-1598	65	2	of	of	ADP
eurjchem-1598	65	3	[	[	X
eurjchem-1598	65	4	zn(l)h2o.ch3coo	zn(l)h2o.ch3coo	NOUN
eurjchem-1598	65	5	]	]	X
eurjchem-1598	65	6	(	(	PUNCT
eurjchem-1598	65	7	lzn	lzn	NOUN
eurjchem-1598	65	8	)	)	PUNCT
eurjchem-1598	65	9	ethanolic	ethanolic	ADJ
eurjchem-1598	65	10	solution	solution	NOUN
eurjchem-1598	65	11	of	of	ADP
eurjchem-1598	65	12	1	1	NUM
eurjchem-1598	65	13	mmole	mmole	NOUN
eurjchem-1598	65	14	(	(	PUNCT
eurjchem-1598	65	15	20	20	NUM
eurjchem-1598	65	16	ml	ml	NOUN
eurjchem-1598	65	17	)	)	PUNCT
eurjchem-1598	65	18	of	of	ADP
eurjchem-1598	65	19	ligand	ligand	NOUN
eurjchem-1598	65	20	and	and	CCONJ
eurjchem-1598	65	21	a	a	DET
eurjchem-1598	65	22	hot	hot	ADJ
eurjchem-1598	65	23	ethanolic	ethanolic	ADJ
eurjchem-1598	65	24	solution	solution	NOUN
eurjchem-1598	65	25	of	of	ADP
eurjchem-1598	65	26	1	1	NUM
eurjchem-1598	65	27	mmole	mmole	NOUN
eurjchem-1598	65	28	zn(ch3coo)2	zn(ch3coo)2	PROPN
eurjchem-1598	65	29	(	(	PUNCT
eurjchem-1598	65	30	0.219	0.219	NUM
eurjchem-1598	65	31	g	g	NOUN
eurjchem-1598	65	32	)	)	PUNCT
eurjchem-1598	65	33	was	be	AUX
eurjchem-1598	65	34	refluxed	refluxe	VERB
eurjchem-1598	65	35	for	for	ADP
eurjchem-1598	65	36	6	6	NUM
eurjchem-1598	65	37	h	h	NOUN
eurjchem-1598	65	38	,	,	PUNCT
eurjchem-1598	65	39	the	the	DET
eurjchem-1598	65	40	precipitate	precipitate	NOUN
eurjchem-1598	65	41	was	be	AUX
eurjchem-1598	65	42	filtered	filter	VERB
eurjchem-1598	65	43	and	and	CCONJ
eurjchem-1598	65	44	washed	wash	VERB
eurjchem-1598	65	45	with	with	ADP
eurjchem-1598	65	46	hot	hot	ADJ
eurjchem-1598	65	47	ethanol	ethanol	NOUN
eurjchem-1598	65	48	several	several	ADJ
eurjchem-1598	65	49	time	time	NOUN
eurjchem-1598	65	50	.	.	PUNCT
eurjchem-1598	66	1	the	the	DET
eurjchem-1598	66	2	brown	brown	ADJ
eurjchem-1598	66	3	precipitate	precipitate	NOUN
eurjchem-1598	66	4	was	be	AUX
eurjchem-1598	66	5	collected	collect	VERB
eurjchem-1598	66	6	and	and	CCONJ
eurjchem-1598	66	7	dried	dry	VERB
eurjchem-1598	66	8	.	.	PUNCT
eurjchem-1598	67	1	color	color	NOUN
eurjchem-1598	67	2	:	:	PUNCT
eurjchem-1598	67	3	brown	brown	ADJ
eurjchem-1598	67	4	.	.	PUNCT
eurjchem-1598	68	1	yield	yield	NOUN
eurjchem-1598	68	2	:	:	PUNCT
eurjchem-1598	68	3	45	45	NUM
eurjchem-1598	68	4	%	%	NOUN
eurjchem-1598	68	5	.	.	PUNCT
eurjchem-1598	69	1	m.p	m.p	PROPN
eurjchem-1598	69	2	.	.	PROPN
eurjchem-1598	69	3	:	:	PUNCT
eurjchem-1598	70	1	>	>	PUNCT
eurjchem-1598	70	2	300	300	NUM
eurjchem-1598	70	3	°	°	SYM
eurjchem-1598	70	4	c	c	NOUN
eurjchem-1598	70	5	.	.	PUNCT
eurjchem-1598	71	1	ft‐ir	ft‐ir	NOUN
eurjchem-1598	71	2	(	(	PUNCT
eurjchem-1598	71	3	kbr	kbr	PROPN
eurjchem-1598	71	4	,	,	PUNCT
eurjchem-1598	71	5			PROPN
eurjchem-1598	71	6	,	,	PUNCT
eurjchem-1598	71	7	cm‐1	cm‐1	PROPN
eurjchem-1598	71	8	):	):	PUNCT
eurjchem-1598	71	9	3400	3400	NUM
eurjchem-1598	71	10	(	(	PUNCT
eurjchem-1598	71	11	nh	nh	PROPN
eurjchem-1598	71	12	,	,	PUNCT
eurjchem-1598	71	13	benzimidazole	benzimidazole	NOUN
eurjchem-1598	71	14	)	)	PUNCT
eurjchem-1598	71	15	,	,	PUNCT
eurjchem-1598	71	16	1627	1627	NUM
eurjchem-1598	71	17	(	(	PUNCT
eurjchem-1598	71	18	c	c	NOUN
eurjchem-1598	71	19	=	=	SYM
eurjchem-1598	71	20	n	n	NUM
eurjchem-1598	71	21	)	)	PUNCT
eurjchem-1598	71	22	.	.	PUNCT
eurjchem-1598	72	1	anal	anal	PROPN
eurjchem-1598	72	2	.	.	PUNCT
eurjchem-1598	72	3	calcd	calcd	NOUN
eurjchem-1598	72	4	.	.	PUNCT
eurjchem-1598	73	1	for	for	ADP
eurjchem-1598	73	2	c18h21n3o5zn	c18h21n3o5zn	PROPN
eurjchem-1598	73	3	:	:	PUNCT
eurjchem-1598	73	4	c	c	X
eurjchem-1598	73	5	,	,	PUNCT
eurjchem-1598	73	6	50.90	50.90	NUM
eurjchem-1598	73	7	;	;	PUNCT
eurjchem-1598	73	8	h	h	NOUN
eurjchem-1598	73	9	,	,	PUNCT
eurjchem-1598	73	10	4.98	4.98	NUM
eurjchem-1598	73	11	;	;	PUNCT
eurjchem-1598	73	12	n	n	CCONJ
eurjchem-1598	73	13	,	,	PUNCT
eurjchem-1598	73	14	9.89	9.89	NUM
eurjchem-1598	73	15	;	;	PUNCT
eurjchem-1598	73	16	zn	zn	NUM
eurjchem-1598	73	17	,	,	PUNCT
eurjchem-1598	73	18	15.39	15.39	NUM
eurjchem-1598	73	19	.	.	PUNCT
eurjchem-1598	73	20	found	find	VERB
eurjchem-1598	73	21	:	:	PUNCT
eurjchem-1598	74	1	c	c	X
eurjchem-1598	74	2	,	,	PUNCT
eurjchem-1598	74	3	49.47	49.47	NUM
eurjchem-1598	74	4	;	;	PUNCT
eurjchem-1598	74	5	h	h	NOUN
eurjchem-1598	74	6	,	,	PUNCT
eurjchem-1598	74	7	5.13	5.13	NUM
eurjchem-1598	74	8	;	;	PUNCT
eurjchem-1598	74	9	n	n	CCONJ
eurjchem-1598	74	10	,	,	PUNCT
eurjchem-1598	74	11	10.18	10.18	NUM
eurjchem-1598	74	12	;	;	PUNCT
eurjchem-1598	74	13	zn	zn	NUM
eurjchem-1598	74	14	,	,	PUNCT
eurjchem-1598	74	15	16.07	16.07	NUM
eurjchem-1598	74	16	%	%	NOUN
eurjchem-1598	74	17	.	.	PUNCT
eurjchem-1598	75	1	λm	λm	X
eurjchem-1598	75	2	(	(	PUNCT
eurjchem-1598	75	3	s.m2.mol‐1	s.m2.mol‐1	PROPN
eurjchem-1598	75	4	):	):	PUNCT
eurjchem-1598	75	5	3.2	3.2	NUM
eurjchem-1598	75	6	.	.	PUNCT
eurjchem-1598	76	1	1h	1h	NUM
eurjchem-1598	76	2	nmr	nmr	NOUN
eurjchem-1598	76	3	(	(	PUNCT
eurjchem-1598	76	4	400	400	NUM
eurjchem-1598	76	5	mhz	mhz	NOUN
eurjchem-1598	76	6	,	,	PUNCT
eurjchem-1598	76	7	dmso‐d6	dmso‐d6	PROPN
eurjchem-1598	76	8	,	,	PUNCT
eurjchem-1598	76	9	δ	δ	PROPN
eurjchem-1598	76	10	,	,	PUNCT
eurjchem-1598	76	11	ppm	ppm	NUM
eurjchem-1598	76	12	):	):	PUNCT
eurjchem-1598	76	13	11.63	11.63	NUM
eurjchem-1598	76	14	(	(	PUNCT
eurjchem-1598	76	15	s	s	PROPN
eurjchem-1598	76	16	,	,	PUNCT
eurjchem-1598	76	17	1h	1h	NUM
eurjchem-1598	76	18	,	,	PUNCT
eurjchem-1598	76	19	nh‐	nh‐	NOUN
eurjchem-1598	76	20	benzimidazole	benzimidazole	NOUN
eurjchem-1598	76	21	)	)	PUNCT
eurjchem-1598	76	22	,	,	PUNCT
eurjchem-1598	76	23	8.72‐6.97	8.72‐6.97	NUM
eurjchem-1598	76	24	(	(	PUNCT
eurjchem-1598	76	25	m	m	PROPN
eurjchem-1598	76	26	,	,	PUNCT
eurjchem-1598	76	27	8h	8h	NUM
eurjchem-1598	76	28	,	,	PUNCT
eurjchem-1598	76	29	ar‐h	ar‐h	PROPN
eurjchem-1598	76	30	)	)	PUNCT
eurjchem-1598	76	31	,	,	PUNCT
eurjchem-1598	76	32	2.35	2.35	NUM
eurjchem-1598	76	33	(	(	PUNCT
eurjchem-1598	76	34	s	s	PROPN
eurjchem-1598	76	35	,	,	PUNCT
eurjchem-1598	76	36	3h	3h	NUM
eurjchem-1598	76	37	,	,	PUNCT
eurjchem-1598	76	38	ch3	ch3	PROPN
eurjchem-1598	76	39	)	)	PUNCT
eurjchem-1598	76	40	.	.	PUNCT
eurjchem-1598	77	1	2.2.2.4	2.2.2.4	NUM
eurjchem-1598	77	2	.	.	X
eurjchem-1598	77	3	synthesis	synthesis	NOUN
eurjchem-1598	77	4	of	of	ADP
eurjchem-1598	77	5	[	[	X
eurjchem-1598	77	6	cd(l)h2o.ch3coo	cd(l)h2o.ch3coo	NOUN
eurjchem-1598	77	7	]	]	X
eurjchem-1598	77	8	(	(	PUNCT
eurjchem-1598	77	9	lcd	lcd	NOUN
eurjchem-1598	77	10	)	)	PUNCT
eurjchem-1598	77	11	ethanolic	ethanolic	ADJ
eurjchem-1598	77	12	solution	solution	NOUN
eurjchem-1598	77	13	of	of	ADP
eurjchem-1598	77	14	1	1	NUM
eurjchem-1598	77	15	mmole	mmole	NOUN
eurjchem-1598	77	16	of	of	ADP
eurjchem-1598	77	17	ligand	ligand	NOUN
eurjchem-1598	77	18	and	and	CCONJ
eurjchem-1598	77	19	a	a	DET
eurjchem-1598	77	20	hot	hot	ADJ
eurjchem-1598	77	21	ethanolic	ethanolic	ADJ
eurjchem-1598	77	22	solution	solution	NOUN
eurjchem-1598	77	23	of	of	ADP
eurjchem-1598	77	24	cd(ch3coo)2	cd(ch3coo)2	SYM
eurjchem-1598	77	25	1	1	NUM
eurjchem-1598	77	26	mmole	mmole	NOUN
eurjchem-1598	77	27	(	(	PUNCT
eurjchem-1598	77	28	0.266	0.266	NUM
eurjchem-1598	77	29	g	g	NOUN
eurjchem-1598	77	30	)	)	PUNCT
eurjchem-1598	77	31	was	be	AUX
eurjchem-1598	77	32	refluxed	refluxe	VERB
eurjchem-1598	77	33	for	for	ADP
eurjchem-1598	77	34	4	4	NUM
eurjchem-1598	77	35	h	h	NOUN
eurjchem-1598	77	36	and	and	CCONJ
eurjchem-1598	77	37	the	the	DET
eurjchem-1598	77	38	mixture	mixture	NOUN
eurjchem-1598	77	39	filtered	filter	VERB
eurjchem-1598	77	40	hot	hot	ADJ
eurjchem-1598	77	41	,	,	PUNCT
eurjchem-1598	77	42	the	the	DET
eurjchem-1598	77	43	precipitate	precipitate	NOUN
eurjchem-1598	77	44	washed	wash	VERB
eurjchem-1598	77	45	with	with	ADP
eurjchem-1598	77	46	hot	hot	ADJ
eurjchem-1598	77	47	ethanol	ethanol	NOUN
eurjchem-1598	77	48	and	and	CCONJ
eurjchem-1598	77	49	the	the	PRON
eurjchem-1598	77	50	obtained	obtain	VERB
eurjchem-1598	77	51	solid	solid	ADJ
eurjchem-1598	77	52	dried	dry	VERB
eurjchem-1598	77	53	.	.	PUNCT
eurjchem-1598	78	1	color	color	NOUN
eurjchem-1598	78	2	:	:	PUNCT
eurjchem-1598	78	3	brown	brown	ADJ
eurjchem-1598	78	4	.	.	PUNCT
eurjchem-1598	79	1	yield	yield	NOUN
eurjchem-1598	79	2	:	:	PUNCT
eurjchem-1598	79	3	37	37	NUM
eurjchem-1598	79	4	%	%	NOUN
eurjchem-1598	79	5	.	.	PUNCT
eurjchem-1598	80	1	m.p	m.p	PROPN
eurjchem-1598	80	2	.	.	PROPN
eurjchem-1598	80	3	:	:	PUNCT
eurjchem-1598	81	1	>	>	X
eurjchem-1598	81	2	300	300	NUM
eurjchem-1598	81	3	°	°	SYM
eurjchem-1598	81	4	c	c	NOUN
eurjchem-1598	81	5	.	.	PUNCT
eurjchem-1598	82	1	ft‐ir	ft‐ir	NOUN
eurjchem-1598	82	2	(	(	PUNCT
eurjchem-1598	82	3	kbr	kbr	PROPN
eurjchem-1598	82	4	,	,	PUNCT
eurjchem-1598	82	5			PROPN
eurjchem-1598	82	6	,	,	PUNCT
eurjchem-1598	82	7	cm‐1	cm‐1	PROPN
eurjchem-1598	82	8	):	):	PUNCT
eurjchem-1598	82	9	3400	3400	NUM
eurjchem-1598	82	10	(	(	PUNCT
eurjchem-1598	82	11	nh	nh	PROPN
eurjchem-1598	82	12	,	,	PUNCT
eurjchem-1598	82	13	benzimi‐dazole	benzimi‐dazole	PROPN
eurjchem-1598	82	14	)	)	PUNCT
eurjchem-1598	82	15	,	,	PUNCT
eurjchem-1598	82	16	1621	1621	NUM
eurjchem-1598	82	17	(	(	PUNCT
eurjchem-1598	82	18	c	c	NOUN
eurjchem-1598	82	19	=	=	SYM
eurjchem-1598	82	20	n	n	NUM
eurjchem-1598	82	21	)	)	PUNCT
eurjchem-1598	82	22	.	.	PUNCT
eurjchem-1598	83	1	anal	anal	PROPN
eurjchem-1598	83	2	.	.	PUNCT
eurjchem-1598	83	3	calcd	calcd	NOUN
eurjchem-1598	83	4	.	.	PUNCT
eurjchem-1598	84	1	for	for	SCONJ
eurjchem-1598	84	2	c18h19n3o4cd	c18h19n3o4cd	PROPN
eurjchem-1598	84	3	:	:	PUNCT
eurjchem-1598	84	4	c	c	X
eurjchem-1598	84	5	,	,	PUNCT
eurjchem-1598	84	6	47.64	47.64	NUM
eurjchem-1598	84	7	;	;	PUNCT
eurjchem-1598	84	8	h	h	NOUN
eurjchem-1598	84	9	,	,	PUNCT
eurjchem-1598	84	10	4.22	4.22	NUM
eurjchem-1598	84	11	;	;	PUNCT
eurjchem-1598	84	12	n	n	CCONJ
eurjchem-1598	84	13	,	,	PUNCT
eurjchem-1598	84	14	9.26;cd	9.26;cd	NOUN
eurjchem-1598	84	15	,	,	PUNCT
eurjchem-1598	84	16	24.77	24.77	NUM
eurjchem-1598	84	17	.	.	PUNCT
eurjchem-1598	84	18	found	find	VERB
eurjchem-1598	84	19	:	:	PUNCT
eurjchem-1598	85	1	c	c	X
eurjchem-1598	85	2	,	,	PUNCT
eurjchem-1598	85	3	46.22	46.22	NUM
eurjchem-1598	85	4	;	;	PUNCT
eurjchem-1598	85	5	h	h	NOUN
eurjchem-1598	85	6	,	,	PUNCT
eurjchem-1598	85	7	4.34	4.34	NUM
eurjchem-1598	85	8	;	;	PUNCT
eurjchem-1598	85	9	n	n	CCONJ
eurjchem-1598	85	10	,	,	PUNCT
eurjchem-1598	85	11	9.51	9.51	NUM
eurjchem-1598	85	12	;	;	PUNCT
eurjchem-1598	85	13	cd	cd	PROPN
eurjchem-1598	85	14	,	,	PUNCT
eurjchem-1598	85	15	24.81	24.81	NUM
eurjchem-1598	85	16	%	%	NOUN
eurjchem-1598	85	17	.	.	PUNCT
eurjchem-1598	86	1	λm	λm	X
eurjchem-1598	86	2	(	(	PUNCT
eurjchem-1598	86	3	s.m2.mol‐1	s.m2.mol‐1	PROPN
eurjchem-1598	86	4	):	):	PUNCT
eurjchem-1598	86	5	4.6	4.6	NUM
eurjchem-1598	86	6	.	.	PUNCT
eurjchem-1598	87	1	2.2.3	2.2.3	NUM
eurjchem-1598	87	2	.	.	PUNCT
eurjchem-1598	88	1	computational	computational	ADJ
eurjchem-1598	88	2	details	detail	NOUN
eurjchem-1598	88	3	all	all	DET
eurjchem-1598	88	4	computations	computation	NOUN
eurjchem-1598	88	5	were	be	AUX
eurjchem-1598	88	6	performed	perform	VERB
eurjchem-1598	88	7	using	use	VERB
eurjchem-1598	88	8	the	the	DET
eurjchem-1598	88	9	gaussian09	gaussian09	NOUN
eurjchem-1598	88	10	software	software	NOUN
eurjchem-1598	88	11	package	package	NOUN
eurjchem-1598	88	12	[	[	X
eurjchem-1598	88	13	9	9	NUM
eurjchem-1598	88	14	]	]	PUNCT
eurjchem-1598	88	15	.	.	PUNCT
eurjchem-1598	89	1	full	full	ADJ
eurjchem-1598	89	2	geometry	geometry	NOUN
eurjchem-1598	89	3	optimizations	optimization	NOUN
eurjchem-1598	89	4	were	be	AUX
eurjchem-1598	89	5	carried	carry	VERB
eurjchem-1598	89	6	out	out	ADP
eurjchem-1598	89	7	using	use	VERB
eurjchem-1598	89	8	the	the	DET
eurjchem-1598	89	9	density	density	NOUN
eurjchem-1598	89	10	function	function	NOUN
eurjchem-1598	89	11	theory	theory	NOUN
eurjchem-1598	89	12	at	at	ADP
eurjchem-1598	89	13	b3lyplevel	b3lyplevel	NOUN
eurjchem-1598	89	14	for	for	ADP
eurjchem-1598	89	15	studied	study	VERB
eurjchem-1598	89	16	ligand	ligand	NOUN
eurjchem-1598	89	17	and	and	CCONJ
eurjchem-1598	89	18	their	their	PRON
eurjchem-1598	89	19	cd(ii	cd(ii	NOUN
eurjchem-1598	89	20	)	)	PUNCT
eurjchem-1598	89	21	,	,	PUNCT
eurjchem-1598	89	22	cu(ii	cu(ii	PROPN
eurjchem-1598	89	23	)	)	PUNCT
eurjchem-1598	89	24	and	and	CCONJ
eurjchem-1598	89	25	zn(ii	zn(ii	NUM
eurjchem-1598	89	26	)	)	PUNCT
eurjchem-1598	89	27	complexes	complexe	VERB
eurjchem-1598	90	1	[	[	X
eurjchem-1598	90	2	10,11	10,11	NOUN
eurjchem-1598	90	3	]	]	PUNCT
eurjchem-1598	90	4	.	.	PUNCT
eurjchem-1598	91	1	lanl2dz	lanl2dz	NOUN
eurjchem-1598	91	2	is	be	AUX
eurjchem-1598	91	3	a	a	DET
eurjchem-1598	91	4	basis	basis	NOUN
eurjchem-1598	91	5	set	set	VERB
eurjchem-1598	91	6	for	for	ADP
eurjchem-1598	91	7	post‐third‐row	post‐third‐row	PROPN
eurjchem-1598	91	8	atoms	atom	NOUN
eurjchem-1598	91	9	which	which	PRON
eurjchem-1598	91	10	uses	use	VERB
eurjchem-1598	91	11	effective	effective	ADJ
eurjchem-1598	91	12	core	core	NOUN
eurjchem-1598	91	13	potentials	potential	NOUN
eurjchem-1598	91	14	in	in	ADP
eurjchem-1598	91	15	order	order	NOUN
eurjchem-1598	91	16	to	to	PART
eurjchem-1598	91	17	reduce	reduce	VERB
eurjchem-1598	91	18	computational	computational	ADJ
eurjchem-1598	91	19	cost	cost	NOUN
eurjchem-1598	91	20	[	[	X
eurjchem-1598	91	21	12	12	NUM
eurjchem-1598	91	22	]	]	PUNCT
eurjchem-1598	91	23	.	.	PUNCT
eurjchem-1598	92	1	properties	property	NOUN
eurjchem-1598	92	2	and	and	CCONJ
eurjchem-1598	92	3	homo‐lumo	homo‐lumo	VERB
eurjchem-1598	92	4	energies	energy	NOUN
eurjchem-1598	92	5	of	of	ADP
eurjchem-1598	92	6	the	the	DET
eurjchem-1598	92	7	ligand	ligand	NOUN
eurjchem-1598	92	8	and	and	CCONJ
eurjchem-1598	92	9	their	their	PRON
eurjchem-1598	92	10	complexes	complex	NOUN
eurjchem-1598	92	11	was	be	AUX
eurjchem-1598	92	12	calculated	calculate	VERB
eurjchem-1598	92	13	by	by	ADP
eurjchem-1598	92	14	the	the	DET
eurjchem-1598	92	15	lanl2dz	lanl2dz	NOUN
eurjchem-1598	92	16	basis	basis	NOUN
eurjchem-1598	92	17	set	set	NOUN
eurjchem-1598	92	18	for	for	ADP
eurjchem-1598	92	19	the	the	DET
eurjchem-1598	92	20	cd	cd	PROPN
eurjchem-1598	92	21	,	,	PUNCT
eurjchem-1598	92	22	cu	cu	PROPN
eurjchem-1598	92	23	and	and	CCONJ
eurjchem-1598	92	24	zn	zn	NUM
eurjchem-1598	92	25	atoms	atom	NOUN
eurjchem-1598	92	26	and	and	CCONJ
eurjchem-1598	92	27	the	the	DET
eurjchem-1598	92	28	6‐	6‐	NUM
eurjchem-1598	92	29	311+g(d	311+g(d	NUM
eurjchem-1598	92	30	,	,	PUNCT
eurjchem-1598	92	31	p	p	NOUN
eurjchem-1598	92	32	)	)	PUNCT
eurjchem-1598	92	33	higher	high	ADJ
eurjchem-1598	92	34	basis	basis	NOUN
eurjchem-1598	92	35	set	set	NOUN
eurjchem-1598	92	36	level	level	NOUN
eurjchem-1598	92	37	for	for	ADP
eurjchem-1598	92	38	n	n	CCONJ
eurjchem-1598	92	39	,	,	PUNCT
eurjchem-1598	92	40	o	o	NOUN
eurjchem-1598	92	41	,	,	PUNCT
eurjchem-1598	92	42	c	c	NOUN
eurjchem-1598	92	43	and	and	CCONJ
eurjchem-1598	92	44	h	h	NOUN
eurjchem-1598	92	45	atoms	atom	NOUN
eurjchem-1598	92	46	.	.	PUNCT
eurjchem-1598	93	1	mulliken	mulliken	NOUN
eurjchem-1598	93	2	charge	charge	NOUN
eurjchem-1598	93	3	distributions	distribution	NOUN
eurjchem-1598	93	4	of	of	ADP
eurjchem-1598	93	5	the	the	DET
eurjchem-1598	93	6	investigated	investigate	VERB
eurjchem-1598	93	7	compounds	compound	NOUN
eurjchem-1598	93	8	were	be	AUX
eurjchem-1598	93	9	also	also	ADV
eurjchem-1598	93	10	computed	compute	VERB
eurjchem-1598	93	11	at	at	ADP
eurjchem-1598	93	12	same	same	ADJ
eurjchem-1598	93	13	level	level	NOUN
eurjchem-1598	93	14	of	of	ADP
eurjchem-1598	93	15	method	method	NOUN
eurjchem-1598	93	16	.	.	PUNCT
eurjchem-1598	94	1	3	3	X
eurjchem-1598	94	2	.	.	NOUN
eurjchem-1598	94	3	results	result	NOUN
eurjchem-1598	94	4	and	and	CCONJ
eurjchem-1598	94	5	discussion	discussion	NOUN
eurjchem-1598	94	6	3.1	3.1	NUM
eurjchem-1598	94	7	.	.	PUNCT
eurjchem-1598	95	1	characterization	characterization	NOUN
eurjchem-1598	95	2	of	of	ADP
eurjchem-1598	95	3	ligand	ligand	NOUN
eurjchem-1598	95	4	the	the	DET
eurjchem-1598	95	5	benzimidazole	benzimidazole	PROPN
eurjchem-1598	95	6	ligand	ligand	NOUN
eurjchem-1598	95	7	,	,	PUNCT
eurjchem-1598	95	8	2‐(1h‐indol‐3‐yl)‐5‐methyl‐1h‐	2‐(1h‐indol‐3‐yl)‐5‐methyl‐1h‐	NUM
eurjchem-1598	95	9	benzo[d]imidazole	benzo[d]imidazole	NOUN
eurjchem-1598	95	10	,	,	PUNCT
eurjchem-1598	95	11	was	be	AUX
eurjchem-1598	95	12	formed	form	VERB
eurjchem-1598	95	13	according	accord	VERB
eurjchem-1598	95	14	to	to	ADP
eurjchem-1598	95	15	the	the	DET
eurjchem-1598	95	16	mechanism	mechanism	NOUN
eurjchem-1598	95	17	of	of	ADP
eurjchem-1598	95	18	scheme	scheme	NOUN
eurjchem-1598	95	19	2	2	NUM
eurjchem-1598	95	20	.	.	PUNCT
eurjchem-1598	96	1	the	the	DET
eurjchem-1598	96	2	ligand	ligand	ADJ
eurjchem-1598	96	3	insoluble	insoluble	ADJ
eurjchem-1598	96	4	in	in	ADP
eurjchem-1598	96	5	hexane	hexane	NOUN
eurjchem-1598	96	6	,	,	PUNCT
eurjchem-1598	96	7	benzene	benzene	NOUN
eurjchem-1598	96	8	,	,	PUNCT
eurjchem-1598	96	9	toluene	toluene	NOUN
eurjchem-1598	96	10	,	,	PUNCT
eurjchem-1598	96	11	diethyl	diethyl	NOUN
eurjchem-1598	96	12	ether	ether	NOUN
eurjchem-1598	96	13	and	and	CCONJ
eurjchem-1598	96	14	chloroform	chloroform	NOUN
eurjchem-1598	96	15	;	;	PUNCT
eurjchem-1598	96	16	sparingly	sparingly	ADV
eurjchem-1598	96	17	soluble	soluble	ADJ
eurjchem-1598	96	18	in	in	ADP
eurjchem-1598	96	19	methanol	methanol	NOUN
eurjchem-1598	96	20	and	and	CCONJ
eurjchem-1598	96	21	ethanol	ethanol	NOUN
eurjchem-1598	96	22	and	and	CCONJ
eurjchem-1598	96	23	very	very	ADV
eurjchem-1598	96	24	soluble	soluble	ADJ
eurjchem-1598	96	25	in	in	ADP
eurjchem-1598	96	26	dmso	dmso	NOUN
eurjchem-1598	96	27	and	and	CCONJ
eurjchem-1598	96	28	dmf	dmf	PROPN
eurjchem-1598	96	29	.	.	PUNCT
eurjchem-1598	97	1	the	the	DET
eurjchem-1598	97	2	ligand	ligand	NOUN
eurjchem-1598	97	3	exhibits	exhibit	VERB
eurjchem-1598	97	4	two	two	NUM
eurjchem-1598	97	5	bands	band	NOUN
eurjchem-1598	97	6	for	for	ADP
eurjchem-1598	97	7	νn‐h	νn‐h	NOUN
eurjchem-1598	97	8	the	the	DET
eurjchem-1598	97	9	first	first	ADJ
eurjchem-1598	97	10	is	be	AUX
eurjchem-1598	97	11	a	a	DET
eurjchem-1598	97	12	strong	strong	ADJ
eurjchem-1598	97	13	and	and	CCONJ
eurjchem-1598	97	14	a	a	DET
eurjchem-1598	97	15	broad	broad	NOUN
eurjchem-1598	97	16	at	at	ADP
eurjchem-1598	97	17	3400	3400	NUM
eurjchem-1598	97	18	cm‐1	cm‐1	NOUN
eurjchem-1598	97	19	attributed	attribute	VERB
eurjchem-1598	97	20	to	to	ADP
eurjchem-1598	97	21	νn‐h	νn‐h	PROPN
eurjchem-1598	97	22	of	of	ADP
eurjchem-1598	97	23	benzimidazole	benzimidazole	ADJ
eurjchem-1598	97	24	moiety	moiety	NOUN
eurjchem-1598	98	1	[	[	X
eurjchem-1598	98	2	13,14	13,14	NUM
eurjchem-1598	98	3	]	]	PUNCT
eurjchem-1598	98	4	,	,	PUNCT
eurjchem-1598	98	5	the	the	DET
eurjchem-1598	98	6	second	second	ADJ
eurjchem-1598	98	7	at	at	ADP
eurjchem-1598	98	8	3128	3128	NUM
eurjchem-1598	98	9	cm‐1	cm‐1	NOUN
eurjchem-1598	98	10	weak	weak	ADJ
eurjchem-1598	98	11	and	and	CCONJ
eurjchem-1598	98	12	broad	broad	ADJ
eurjchem-1598	98	13	attributed	attribute	VERB
eurjchem-1598	98	14	to	to	ADP
eurjchem-1598	98	15	νn‐h	νn‐h	PROPN
eurjchem-1598	98	16	of	of	ADP
eurjchem-1598	98	17	indole	indole	ADJ
eurjchem-1598	98	18	moiety	moiety	NOUN
eurjchem-1598	98	19	.	.	PUNCT
eurjchem-1598	99	1	the	the	DET
eurjchem-1598	99	2	weak	weak	ADJ
eurjchem-1598	99	3	band	band	NOUN
eurjchem-1598	99	4	at	at	ADP
eurjchem-1598	99	5	3047	3047	NUM
eurjchem-1598	99	6	cm‐1	cm‐1	NOUN
eurjchem-1598	99	7	attributed	attribute	VERB
eurjchem-1598	99	8	to	to	ADP
eurjchem-1598	99	9	νc‐h	νc‐h	ADV
eurjchem-1598	99	10	aromatic	aromatic	ADJ
eurjchem-1598	99	11	and	and	CCONJ
eurjchem-1598	99	12	the	the	DET
eurjchem-1598	99	13	bands	band	NOUN
eurjchem-1598	99	14	at	at	ADP
eurjchem-1598	99	15	2920	2920	NUM
eurjchem-1598	99	16	and	and	CCONJ
eurjchem-1598	99	17	2866	2866	NUM
eurjchem-1598	99	18	cm‐1	cm‐1	NOUN
eurjchem-1598	99	19	attributed	attribute	VERB
eurjchem-1598	99	20	to	to	ADP
eurjchem-1598	99	21	νc‐h	νc‐h	PROPN
eurjchem-1598	99	22	asym	asym	PROPN
eurjchem-1598	99	23	and	and	CCONJ
eurjchem-1598	99	24	sym	sym	NOUN
eurjchem-1598	99	25	stretching	stretching	NOUN
eurjchem-1598	99	26	of	of	ADP
eurjchem-1598	99	27	ch3	ch3	PROPN
eurjchem-1598	99	28	group	group	NOUN
eurjchem-1598	99	29	.	.	PUNCT
eurjchem-1598	100	1	the	the	DET
eurjchem-1598	100	2	strong	strong	ADJ
eurjchem-1598	100	3	band	band	NOUN
eurjchem-1598	100	4	at	at	ADP
eurjchem-1598	100	5	1633	1633	NUM
eurjchem-1598	100	6	cm‐1	cm‐1	NOUN
eurjchem-1598	100	7	attributed	attribute	VERB
eurjchem-1598	100	8	to	to	ADP
eurjchem-1598	100	9	νc	νc	NOUN
eurjchem-1598	100	10	=	=	PRON
eurjchem-1598	100	11	n	n	NOUN
eurjchem-1598	100	12	stretching	stretch	VERB
eurjchem-1598	100	13	mode	mode	NOUN
eurjchem-1598	100	14	.	.	PUNCT
eurjchem-1598	101	1	the	the	DET
eurjchem-1598	101	2	mass	mass	PROPN
eurjchem-1598	101	3	spectrum	spectrum	PROPN
eurjchem-1598	101	4	confirms	confirm	VERB
eurjchem-1598	101	5	the	the	DET
eurjchem-1598	101	6	proposed	propose	VERB
eurjchem-1598	101	7	formula	formula	NOUN
eurjchem-1598	101	8	where	where	SCONJ
eurjchem-1598	101	9	the	the	DET
eurjchem-1598	101	10	molecular	molecular	ADJ
eurjchem-1598	101	11	ion	ion	NOUN
eurjchem-1598	101	12	peak	peak	NOUN
eurjchem-1598	101	13	(	(	PUNCT
eurjchem-1598	101	14	100	100	NUM
eurjchem-1598	101	15	%	%	NOUN
eurjchem-1598	101	16	)	)	PUNCT
eurjchem-1598	101	17	at	at	ADP
eurjchem-1598	101	18	247.2	247.2	NUM
eurjchem-1598	101	19	m	m	NOUN
eurjchem-1598	101	20	/	/	SYM
eurjchem-1598	101	21	z	z	NOUN
eurjchem-1598	101	22	,	,	PUNCT
eurjchem-1598	101	23	which	which	PRON
eurjchem-1598	101	24	is	be	AUX
eurjchem-1598	101	25	fit	fit	ADJ
eurjchem-1598	101	26	the	the	DET
eurjchem-1598	101	27	molecular	molecular	ADJ
eurjchem-1598	101	28	weight	weight	NOUN
eurjchem-1598	101	29	and	and	CCONJ
eurjchem-1598	101	30	the	the	DET
eurjchem-1598	101	31	high	high	ADJ
eurjchem-1598	101	32	relative	relative	ADJ
eurjchem-1598	101	33	abundance	abundance	NOUN
eurjchem-1598	101	34	gives	give	VERB
eurjchem-1598	101	35	an	an	DET
eurjchem-1598	101	36	idea	idea	NOUN
eurjchem-1598	101	37	of	of	ADP
eurjchem-1598	101	38	the	the	DET
eurjchem-1598	101	39	stability	stability	NOUN
eurjchem-1598	101	40	of	of	ADP
eurjchem-1598	101	41	molecular	molecular	ADJ
eurjchem-1598	101	42	ion	ion	NOUN
eurjchem-1598	101	43	(	(	PUNCT
eurjchem-1598	101	44	figure	figure	NOUN
eurjchem-1598	101	45	1	1	NUM
eurjchem-1598	101	46	)	)	PUNCT
eurjchem-1598	101	47	.	.	PUNCT
eurjchem-1598	102	1	the	the	DET
eurjchem-1598	102	2	1h	1h	NUM
eurjchem-1598	102	3	nmr	nmr	NOUN
eurjchem-1598	102	4	spectrum	spectrum	NOUN
eurjchem-1598	102	5	of	of	ADP
eurjchem-1598	102	6	ligand	ligand	PROPN
eurjchem-1598	102	7	shows	show	VERB
eurjchem-1598	102	8	a	a	DET
eurjchem-1598	102	9	signal	signal	NOUN
eurjchem-1598	102	10	at	at	ADP
eurjchem-1598	102	11	δ	δ	PROPN
eurjchem-1598	102	12	11.86	11.86	NUM
eurjchem-1598	102	13	ppm	ppm	NOUN
eurjchem-1598	102	14	attributed	attribute	VERB
eurjchem-1598	102	15	to	to	ADP
eurjchem-1598	102	16	nh	nh	PROPN
eurjchem-1598	102	17	proton	proton	NOUN
eurjchem-1598	102	18	of	of	ADP
eurjchem-1598	102	19	benzimidazole	benzimidazole	ADJ
eurjchem-1598	102	20	moiety	moiety	PROPN
eurjchem-1598	103	1	[	[	X
eurjchem-1598	103	2	14,15	14,15	NUM
eurjchem-1598	103	3	]	]	PUNCT
eurjchem-1598	103	4	,	,	PUNCT
eurjchem-1598	103	5	another	another	DET
eurjchem-1598	103	6	single	single	ADJ
eurjchem-1598	103	7	signal	signal	NOUN
eurjchem-1598	103	8	at	at	ADP
eurjchem-1598	103	9	δ	δ	PROPN
eurjchem-1598	103	10	11.00	11.00	NUM
eurjchem-1598	103	11	ppm	ppm	NOUN
eurjchem-1598	103	12	attributed	attribute	VERB
eurjchem-1598	103	13	to	to	ADP
eurjchem-1598	103	14	nh	nh	PROPN
eurjchem-1598	103	15	proton	proton	NOUN
eurjchem-1598	103	16	of	of	ADP
eurjchem-1598	103	17	indole	indole	ADJ
eurjchem-1598	103	18	moiety	moiety	NOUN
eurjchem-1598	104	1	[	[	X
eurjchem-1598	104	2	16,17	16,17	NUM
eurjchem-1598	104	3	]	]	PUNCT
eurjchem-1598	104	4	.	.	PUNCT
eurjchem-1598	105	1	254	254	NUM
eurjchem-1598	105	2	hadi	hadi	PROPN
eurjchem-1598	105	3	et	et	PROPN
eurjchem-1598	105	4	al	al	PROPN
eurjchem-1598	105	5	.	.	PUNCT
eurjchem-1598	105	6	/	/	SYM
eurjchem-1598	105	7	european	european	PROPN
eurjchem-1598	105	8	journal	journal	PROPN
eurjchem-1598	105	9	of	of	ADP
eurjchem-1598	105	10	chemistry	chemistry	NOUN
eurjchem-1598	105	11	8	8	NUM
eurjchem-1598	105	12	(	(	PUNCT
eurjchem-1598	105	13	3	3	NUM
eurjchem-1598	105	14	)	)	PUNCT
eurjchem-1598	105	15	(	(	PUNCT
eurjchem-1598	105	16	2017	2017	NUM
eurjchem-1598	105	17	)	)	PUNCT
eurjchem-1598	105	18	252‐257	252‐257	NOUN
eurjchem-1598	105	19	figure	figure	VERB
eurjchem-1598	105	20	1	1	NUM
eurjchem-1598	105	21	.	.	PUNCT
eurjchem-1598	106	1	the	the	DET
eurjchem-1598	106	2	mass	mass	NOUN
eurjchem-1598	106	3	spectrum	spectrum	NOUN
eurjchem-1598	106	4	of	of	ADP
eurjchem-1598	106	5	ligand	ligand	NOUN
eurjchem-1598	106	6	.	.	PUNCT
eurjchem-1598	107	1	figure	figure	NOUN
eurjchem-1598	107	2	2	2	NUM
eurjchem-1598	107	3	.	.	PUNCT
eurjchem-1598	108	1	the	the	DET
eurjchem-1598	108	2	1h	1h	NUM
eurjchem-1598	108	3	nmr‐d6	nmr‐d6	PROPN
eurjchem-1598	108	4	spectrum	spectrum	NOUN
eurjchem-1598	108	5	of	of	ADP
eurjchem-1598	108	6	ligand	ligand	NOUN
eurjchem-1598	108	7	.	.	PUNCT
eurjchem-1598	109	1	figure	figure	VERB
eurjchem-1598	109	2	3	3	NUM
eurjchem-1598	109	3	.	.	PUNCT
eurjchem-1598	110	1	the	the	DET
eurjchem-1598	110	2	13c	13c	NUM
eurjchem-1598	110	3	nmr	nmr	NOUN
eurjchem-1598	110	4	spectrum	spectrum	NOUN
eurjchem-1598	110	5	of	of	ADP
eurjchem-1598	110	6	ligand	ligand	NOUN
eurjchem-1598	110	7	.	.	PUNCT
eurjchem-1598	111	1	the	the	DET
eurjchem-1598	111	2	aromatic	aromatic	ADJ
eurjchem-1598	111	3	protons	proton	NOUN
eurjchem-1598	111	4	appear	appear	VERB
eurjchem-1598	111	5	in	in	ADP
eurjchem-1598	111	6	the	the	DET
eurjchem-1598	111	7	expected	expect	VERB
eurjchem-1598	111	8	region	region	NOUN
eurjchem-1598	111	9	as	as	SCONJ
eurjchem-1598	111	10	multiples	multiple	NOUN
eurjchem-1598	111	11	signals	signal	NOUN
eurjchem-1598	111	12	in	in	ADP
eurjchem-1598	111	13	the	the	DET
eurjchem-1598	111	14	range	range	NOUN
eurjchem-1598	111	15	δ	δ	PROPN
eurjchem-1598	111	16	7.05‐8.33	7.05‐8.33	PROPN
eurjchem-1598	111	17	ppm	ppm	NOUN
eurjchem-1598	111	18	.	.	PUNCT
eurjchem-1598	112	1	the	the	DET
eurjchem-1598	112	2	methyl	methyl	NOUN
eurjchem-1598	112	3	protons	proton	NOUN
eurjchem-1598	112	4	appear	appear	VERB
eurjchem-1598	112	5	as	as	ADP
eurjchem-1598	112	6	a	a	DET
eurjchem-1598	112	7	singlet	singlet	ADJ
eurjchem-1598	112	8	signal	signal	NOUN
eurjchem-1598	112	9	at	at	ADP
eurjchem-1598	112	10	δ	δ	PROPN
eurjchem-1598	112	11	2.30	2.30	NUM
eurjchem-1598	112	12	ppm	ppm	NOUN
eurjchem-1598	112	13	.	.	PUNCT
eurjchem-1598	113	1	the	the	DET
eurjchem-1598	113	2	1h	1h	NUM
eurjchem-1598	113	3	nmr	nmr	NOUN
eurjchem-1598	113	4	spectrum	spectrum	NOUN
eurjchem-1598	113	5	of	of	ADP
eurjchem-1598	113	6	ligand	ligand	NOUN
eurjchem-1598	113	7	as	as	SCONJ
eurjchem-1598	113	8	shown	show	VERB
eurjchem-1598	113	9	in	in	ADP
eurjchem-1598	113	10	figure	figure	NOUN
eurjchem-1598	113	11	2	2	NUM
eurjchem-1598	113	12	.	.	PUNCT
eurjchem-1598	114	1	the	the	DET
eurjchem-1598	114	2	13c	13c	NUM
eurjchem-1598	114	3	nmr	nmr	NOUN
eurjchem-1598	114	4	spectrum	spectrum	NOUN
eurjchem-1598	114	5	shows	show	VERB
eurjchem-1598	114	6	a	a	DET
eurjchem-1598	114	7	signal	signal	NOUN
eurjchem-1598	114	8	at	at	ADP
eurjchem-1598	114	9	δ	δ	PROPN
eurjchem-1598	114	10	21.19	21.19	NUM
eurjchem-1598	114	11	ppm	ppm	NOUN
eurjchem-1598	114	12	attributed	attribute	VERB
eurjchem-1598	114	13	to	to	ADP
eurjchem-1598	114	14	methyl	methyl	NOUN
eurjchem-1598	114	15	carbon	carbon	NOUN
eurjchem-1598	114	16	and	and	CCONJ
eurjchem-1598	114	17	a	a	DET
eurjchem-1598	114	18	signal	signal	NOUN
eurjchem-1598	114	19	at	at	ADP
eurjchem-1598	114	20	δ	δ	PROPN
eurjchem-1598	114	21	149.5	149.5	NUM
eurjchem-1598	114	22	ppm	ppm	NOUN
eurjchem-1598	114	23	to	to	ADP
eurjchem-1598	114	24	c	c	NOUN
eurjchem-1598	114	25	=	=	SYM
eurjchem-1598	114	26	n	n	PRON
eurjchem-1598	114	27	(	(	PUNCT
eurjchem-1598	114	28	figure	figure	NOUN
eurjchem-1598	114	29	3	3	NUM
eurjchem-1598	114	30	)	)	PUNCT
eurjchem-1598	114	31	[	[	X
eurjchem-1598	114	32	18	18	NUM
eurjchem-1598	114	33	]	]	PUNCT
eurjchem-1598	114	34	.	.	PUNCT
eurjchem-1598	115	1	all	all	DET
eurjchem-1598	115	2	signals	signal	NOUN
eurjchem-1598	115	3	attributed	attribute	VERB
eurjchem-1598	115	4	to	to	ADP
eurjchem-1598	115	5	aromatic	aromatic	ADJ
eurjchem-1598	115	6	carbon	carbon	NOUN
eurjchem-1598	115	7	are	be	AUX
eurjchem-1598	115	8	listed	list	VERB
eurjchem-1598	115	9	experimental	experimental	ADJ
eurjchem-1598	115	10	section	section	NOUN
eurjchem-1598	115	11	together	together	ADV
eurjchem-1598	115	12	with	with	ADP
eurjchem-1598	115	13	the	the	DET
eurjchem-1598	115	14	numbering	number	VERB
eurjchem-1598	115	15	system	system	NOUN
eurjchem-1598	115	16	of	of	ADP
eurjchem-1598	115	17	the	the	DET
eurjchem-1598	115	18	ligand	ligand	NOUN
eurjchem-1598	115	19	.	.	PUNCT
eurjchem-1598	116	1	3.2	3.2	NUM
eurjchem-1598	116	2	.	.	PUNCT
eurjchem-1598	116	3	characterization	characterization	NOUN
eurjchem-1598	116	4	of	of	ADP
eurjchem-1598	116	5	the	the	DET
eurjchem-1598	116	6	metal	metal	NOUN
eurjchem-1598	116	7	complexes	complexe	VERB
eurjchem-1598	116	8	the	the	DET
eurjchem-1598	116	9	zn(ii	zn(ii	NOUN
eurjchem-1598	116	10	)	)	PUNCT
eurjchem-1598	116	11	,	,	PUNCT
eurjchem-1598	116	12	cu(ii	cu(ii	PROPN
eurjchem-1598	116	13	)	)	PUNCT
eurjchem-1598	116	14	and	and	CCONJ
eurjchem-1598	116	15	cd(ii	cd(ii	ADJ
eurjchem-1598	116	16	)	)	PUNCT
eurjchem-1598	116	17	complexes	complex	NOUN
eurjchem-1598	116	18	are	be	AUX
eurjchem-1598	116	19	stable	stable	ADJ
eurjchem-1598	116	20	,	,	PUNCT
eurjchem-1598	116	21	non‐	non‐	NOUN
eurjchem-1598	116	22	hygroscopic	hygroscopic	NOUN
eurjchem-1598	116	23	and	and	CCONJ
eurjchem-1598	116	24	having	have	VERB
eurjchem-1598	116	25	high	high	ADJ
eurjchem-1598	116	26	melting	melting	NOUN
eurjchem-1598	116	27	points	point	NOUN
eurjchem-1598	116	28	(	(	PUNCT
eurjchem-1598	116	29	>	>	X
eurjchem-1598	116	30	300	300	NUM
eurjchem-1598	116	31	°	°	NOUN
eurjchem-1598	116	32	c	c	NOUN
eurjchem-1598	116	33	)	)	PUNCT
eurjchem-1598	116	34	.	.	PUNCT
eurjchem-1598	117	1	these	these	DET
eurjchem-1598	117	2	complexes	complex	NOUN
eurjchem-1598	117	3	are	be	AUX
eurjchem-1598	117	4	insoluble	insoluble	ADJ
eurjchem-1598	117	5	in	in	ADP
eurjchem-1598	117	6	common	common	ADJ
eurjchem-1598	117	7	organic	organic	ADJ
eurjchem-1598	117	8	solvent	solvent	NOUN
eurjchem-1598	117	9	but	but	CCONJ
eurjchem-1598	117	10	they	they	PRON
eurjchem-1598	117	11	soluble	soluble	ADJ
eurjchem-1598	117	12	in	in	ADP
eurjchem-1598	117	13	dmf	dmf	PROPN
eurjchem-1598	117	14	and	and	CCONJ
eurjchem-1598	117	15	dmso	dmso	NOUN
eurjchem-1598	117	16	except	except	SCONJ
eurjchem-1598	117	17	cd(ii	cd(ii	PROPN
eurjchem-1598	117	18	)	)	PUNCT
eurjchem-1598	117	19	complex	complex	NOUN
eurjchem-1598	117	20	also	also	ADV
eurjchem-1598	117	21	insoluble	insoluble	ADJ
eurjchem-1598	117	22	in	in	ADP
eurjchem-1598	117	23	dmso	dmso	NOUN
eurjchem-1598	117	24	.	.	PUNCT
eurjchem-1598	118	1	the	the	DET
eurjchem-1598	118	2	elemental	elemental	ADJ
eurjchem-1598	118	3	analysis	analysis	NOUN
eurjchem-1598	118	4	chn	chn	NOUN
eurjchem-1598	118	5	and	and	CCONJ
eurjchem-1598	118	6	the	the	DET
eurjchem-1598	118	7	metal	metal	NOUN
eurjchem-1598	118	8	ratio	ratio	NOUN
eurjchem-1598	118	9	in	in	ADP
eurjchem-1598	118	10	the	the	DET
eurjchem-1598	118	11	complexes	complex	NOUN
eurjchem-1598	118	12	are	be	AUX
eurjchem-1598	118	13	in	in	ADP
eurjchem-1598	118	14	agreement	agreement	NOUN
eurjchem-1598	118	15	with	with	ADP
eurjchem-1598	118	16	suggested	suggest	VERB
eurjchem-1598	118	17	formula	formula	NOUN
eurjchem-1598	118	18	which	which	PRON
eurjchem-1598	118	19	indicates	indicate	VERB
eurjchem-1598	118	20	that	that	SCONJ
eurjchem-1598	118	21	the	the	DET
eurjchem-1598	118	22	ligand	ligand	ADJ
eurjchem-1598	118	23	associates	associate	NOUN
eurjchem-1598	118	24	with	with	ADP
eurjchem-1598	118	25	metal	metal	NOUN
eurjchem-1598	118	26	(	(	PUNCT
eurjchem-1598	118	27	ions	ion	NOUN
eurjchem-1598	118	28	)	)	PUNCT
eurjchem-1598	118	29	in	in	ADP
eurjchem-1598	118	30	1:1	1:1	NUM
eurjchem-1598	118	31	molar	molar	ADJ
eurjchem-1598	118	32	ratio	ratio	NOUN
eurjchem-1598	118	33	.	.	PUNCT
eurjchem-1598	119	1	the	the	DET
eurjchem-1598	119	2	molar	molar	ADJ
eurjchem-1598	119	3	conductance	conductance	NOUN
eurjchem-1598	119	4	measurements	measurement	NOUN
eurjchem-1598	119	5	indicate	indicate	VERB
eurjchem-1598	119	6	their	their	PRON
eurjchem-1598	119	7	non‐electrolytic	non‐electrolytic	ADJ
eurjchem-1598	119	8	nature	nature	NOUN
eurjchem-1598	119	9	.	.	PUNCT
eurjchem-1598	120	1	to	to	PART
eurjchem-1598	120	2	elucidation	elucidation	VERB
eurjchem-1598	120	3	the	the	DET
eurjchem-1598	120	4	site	site	NOUN
eurjchem-1598	120	5	of	of	ADP
eurjchem-1598	120	6	binding	bind	VERB
eurjchem-1598	120	7	between	between	ADP
eurjchem-1598	120	8	ligand	ligand	ADJ
eurjchem-1598	120	9	and	and	CCONJ
eurjchem-1598	120	10	metal	metal	NOUN
eurjchem-1598	120	11	ions	ion	NOUN
eurjchem-1598	120	12	,	,	PUNCT
eurjchem-1598	120	13	ir	ir	PROPN
eurjchem-1598	120	14	spectroscopy	spectroscopy	NOUN
eurjchem-1598	120	15	gives	give	VERB
eurjchem-1598	120	16	good	good	ADJ
eurjchem-1598	120	17	evidence	evidence	NOUN
eurjchem-1598	120	18	when	when	SCONJ
eurjchem-1598	120	19	com‐	com‐	NOUN
eurjchem-1598	120	20	pared	pare	VERB
eurjchem-1598	120	21	the	the	DET
eurjchem-1598	120	22	ir	ir	PROPN
eurjchem-1598	120	23	spectrum	spectrum	NOUN
eurjchem-1598	120	24	of	of	ADP
eurjchem-1598	120	25	ligand	ligand	NOUN
eurjchem-1598	120	26	with	with	ADP
eurjchem-1598	120	27	ir	ir	PROPN
eurjchem-1598	120	28	spectra	spectra	NOUN
eurjchem-1598	120	29	of	of	ADP
eurjchem-1598	120	30	complexes	complex	NOUN
eurjchem-1598	120	31	,	,	PUNCT
eurjchem-1598	120	32	the	the	DET
eurjchem-1598	120	33	band	band	NOUN
eurjchem-1598	120	34	at	at	ADP
eurjchem-1598	120	35	3400	3400	NUM
eurjchem-1598	120	36	cm‐1	cm‐1	NOUN
eurjchem-1598	120	37	which	which	PRON
eurjchem-1598	120	38	attributed	attribute	VERB
eurjchem-1598	120	39	to	to	ADP
eurjchem-1598	120	40	stretching	stretch	VERB
eurjchem-1598	120	41	vibration	vibration	NOUN
eurjchem-1598	120	42	of	of	ADP
eurjchem-1598	120	43	n‐h	n‐h	PRON
eurjchem-1598	120	44	(	(	PUNCT
eurjchem-1598	120	45	benzimidazole	benzimidazole	NOUN
eurjchem-1598	120	46	)	)	PUNCT
eurjchem-1598	120	47	in	in	ADP
eurjchem-1598	120	48	free	free	ADJ
eurjchem-1598	120	49	ligand	ligand	NOUN
eurjchem-1598	120	50	,	,	PUNCT
eurjchem-1598	120	51	this	this	PRON
eurjchem-1598	120	52	remain	remain	VERB
eurjchem-1598	120	53	unchanged	unchanged	ADJ
eurjchem-1598	120	54	in	in	ADP
eurjchem-1598	120	55	the	the	DET
eurjchem-1598	120	56	complexes	complex	NOUN
eurjchem-1598	120	57	spectra	spectra	NOUN
eurjchem-1598	120	58	,	,	PUNCT
eurjchem-1598	120	59	indicating	indicate	VERB
eurjchem-1598	120	60	that	that	SCONJ
eurjchem-1598	120	61	this	this	DET
eurjchem-1598	120	62	group	group	NOUN
eurjchem-1598	120	63	in	in	ADP
eurjchem-1598	120	64	not	not	PART
eurjchem-1598	120	65	participating	participate	VERB
eurjchem-1598	120	66	in	in	ADP
eurjchem-1598	120	67	coordination	coordination	NOUN
eurjchem-1598	120	68	but	but	CCONJ
eurjchem-1598	120	69	the	the	DET
eurjchem-1598	120	70	band	band	NOUN
eurjchem-1598	120	71	at	at	ADP
eurjchem-1598	120	72	3128	3128	NUM
eurjchem-1598	120	73	cm‐1	cm‐1	NOUN
eurjchem-1598	120	74	which	which	PRON
eurjchem-1598	120	75	attributed	attribute	VERB
eurjchem-1598	120	76	to	to	ADP
eurjchem-1598	120	77	n‐h	n‐h	PRON
eurjchem-1598	120	78	of	of	ADP
eurjchem-1598	120	79	indol	indol	ADJ
eurjchem-1598	120	80	moiety	moiety	NOUN
eurjchem-1598	120	81	in	in	ADP
eurjchem-1598	120	82	free	free	ADJ
eurjchem-1598	120	83	ligand	ligand	NOUN
eurjchem-1598	120	84	is	be	AUX
eurjchem-1598	120	85	totally	totally	ADV
eurjchem-1598	120	86	disappearance	disappearance	NOUN
eurjchem-1598	120	87	.	.	PUNCT
eurjchem-1598	121	1	this	this	DET
eurjchem-1598	121	2	data	data	NOUN
eurjchem-1598	121	3	is	be	AUX
eurjchem-1598	121	4	suggested	suggest	VERB
eurjchem-1598	121	5	that	that	SCONJ
eurjchem-1598	121	6	the	the	DET
eurjchem-1598	121	7	deprotonation	deprotonation	NOUN
eurjchem-1598	121	8	and	and	CCONJ
eurjchem-1598	121	9	participating	participate	VERB
eurjchem-1598	121	10	through	through	ADP
eurjchem-1598	121	11	the	the	DET
eurjchem-1598	121	12	nitrogen	nitrogen	NOUN
eurjchem-1598	121	13	atom	atom	NOUN
eurjchem-1598	121	14	of	of	ADP
eurjchem-1598	121	15	indole	indole	NOUN
eurjchem-1598	121	16	.	.	PUNCT
eurjchem-1598	122	1	the	the	DET
eurjchem-1598	122	2	band	band	NOUN
eurjchem-1598	122	3	at	at	ADP
eurjchem-1598	122	4	1633	1633	NUM
eurjchem-1598	122	5	cm‐1	cm‐1	NOUN
eurjchem-1598	122	6	which	which	PRON
eurjchem-1598	122	7	attributed	attribute	VERB
eurjchem-1598	122	8	to	to	ADP
eurjchem-1598	122	9	c	c	NOUN
eurjchem-1598	122	10	=	=	NOUN
eurjchem-1598	122	11	n	n	X
eurjchem-1598	122	12	in	in	ADP
eurjchem-1598	122	13	free	free	ADJ
eurjchem-1598	122	14	ligand	ligand	NOUN
eurjchem-1598	122	15	is	be	AUX
eurjchem-1598	122	16	shifted	shift	VERB
eurjchem-1598	122	17	to	to	ADP
eurjchem-1598	122	18	a	a	DET
eurjchem-1598	122	19	lower	low	ADJ
eurjchem-1598	122	20	wave	wave	NOUN
eurjchem-1598	122	21	number	number	NOUN
eurjchem-1598	122	22	side	side	NOUN
eurjchem-1598	122	23	(	(	PUNCT
eurjchem-1598	122	24	∆ν	∆ν	NOUN
eurjchem-1598	122	25	=	=	SYM
eurjchem-1598	122	26	6‐17	6‐17	NUM
eurjchem-1598	122	27	cm‐1	cm‐1	NOUN
eurjchem-1598	122	28	)	)	PUNCT
eurjchem-1598	122	29	in	in	ADP
eurjchem-1598	122	30	all	all	DET
eurjchem-1598	122	31	complexes	complex	NOUN
eurjchem-1598	122	32	indicates	indicate	VERB
eurjchem-1598	122	33	the	the	DET
eurjchem-1598	122	34	participation	participation	NOUN
eurjchem-1598	122	35	of	of	ADP
eurjchem-1598	122	36	the	the	DET
eurjchem-1598	122	37	c	c	PROPN
eurjchem-1598	122	38	=	=	NOUN
eurjchem-1598	122	39	n	n	PRON
eurjchem-1598	122	40	group	group	NOUN
eurjchem-1598	122	41	in	in	ADP
eurjchem-1598	122	42	coordination	coordination	NOUN
eurjchem-1598	122	43	to	to	ADP
eurjchem-1598	122	44	the	the	DET
eurjchem-1598	122	45	metal	metal	NOUN
eurjchem-1598	122	46	ions	ion	NOUN
eurjchem-1598	122	47	through	through	ADP
eurjchem-1598	122	48	the	the	DET
eurjchem-1598	122	49	lone	lone	ADJ
eurjchem-1598	122	50	pair	pair	NOUN
eurjchem-1598	122	51	of	of	ADP
eurjchem-1598	122	52	electrons	electron	NOUN
eurjchem-1598	122	53	on	on	ADP
eurjchem-1598	122	54	the	the	DET
eurjchem-1598	122	55	nitrogen	nitrogen	NOUN
eurjchem-1598	122	56	atom	atom	NOUN
eurjchem-1598	123	1	[	[	X
eurjchem-1598	123	2	17	17	NUM
eurjchem-1598	123	3	]	]	PUNCT
eurjchem-1598	123	4	.	.	PUNCT
eurjchem-1598	124	1	the	the	DET
eurjchem-1598	124	2	1h	1h	NUM
eurjchem-1598	124	3	nmr	nmr	NOUN
eurjchem-1598	124	4	spectrum	spectrum	NOUN
eurjchem-1598	124	5	of	of	ADP
eurjchem-1598	124	6	zn	zn	PROPN
eurjchem-1598	124	7	complex	complex	ADJ
eurjchem-1598	124	8	(	(	PUNCT
eurjchem-1598	124	9	diamagnetic	diamagnetic	ADJ
eurjchem-1598	124	10	)	)	PUNCT
eurjchem-1598	124	11	(	(	PUNCT
eurjchem-1598	124	12	figure	figure	NOUN
eurjchem-1598	124	13	4	4	NUM
eurjchem-1598	124	14	)	)	PUNCT
eurjchem-1598	124	15	when	when	SCONJ
eurjchem-1598	124	16	compared	compare	VERB
eurjchem-1598	124	17	with	with	ADP
eurjchem-1598	124	18	the	the	DET
eurjchem-1598	124	19	ligand	ligand	NOUN
eurjchem-1598	124	20	spectrum	spectrum	NOUN
eurjchem-1598	124	21	,	,	PUNCT
eurjchem-1598	124	22	shows	show	VERB
eurjchem-1598	124	23	only	only	ADV
eurjchem-1598	124	24	the	the	DET
eurjchem-1598	124	25	signal	signal	NOUN
eurjchem-1598	124	26	of	of	ADP
eurjchem-1598	124	27	benzamidazole	benzamidazole	NOUN
eurjchem-1598	124	28	n‐h	n‐h	PRON
eurjchem-1598	124	29	at	at	ADP
eurjchem-1598	124	30	δ	δ	PROPN
eurjchem-1598	124	31	11.63	11.63	NUM
eurjchem-1598	124	32	ppm	ppm	NUM
eurjchem-1598	124	33	which	which	DET
eurjchem-1598	124	34	hadi	hadi	PROPN
eurjchem-1598	124	35	et	et	PROPN
eurjchem-1598	124	36	al	al	PROPN
eurjchem-1598	124	37	.	.	PUNCT
eurjchem-1598	124	38	/	/	SYM
eurjchem-1598	124	39	european	european	PROPN
eurjchem-1598	124	40	journal	journal	PROPN
eurjchem-1598	124	41	of	of	ADP
eurjchem-1598	124	42	chemistry	chemistry	NOUN
eurjchem-1598	124	43	8	8	NUM
eurjchem-1598	124	44	(	(	PUNCT
eurjchem-1598	124	45	3	3	NUM
eurjchem-1598	124	46	)	)	PUNCT
eurjchem-1598	124	47	(	(	PUNCT
eurjchem-1598	124	48	2017	2017	NUM
eurjchem-1598	124	49	)	)	PUNCT
eurjchem-1598	124	50	252‐257	252‐257	NOUN
eurjchem-1598	124	51	255	255	NUM
eurjchem-1598	124	52	table	table	NOUN
eurjchem-1598	124	53	1	1	NUM
eurjchem-1598	124	54	.	.	PUNCT
eurjchem-1598	125	1	kinetic	kinetic	ADJ
eurjchem-1598	125	2	parameters	parameter	NOUN
eurjchem-1598	125	3	of	of	ADP
eurjchem-1598	125	4	the	the	DET
eurjchem-1598	125	5	complexes	complex	NOUN
eurjchem-1598	125	6	using	use	VERB
eurjchem-1598	125	7	the	the	DET
eurjchem-1598	125	8	coats‐redfern	coats‐redfern	ADJ
eurjchem-1598	125	9	equation	equation	NOUN
eurjchem-1598	125	10	.	.	PUNCT
eurjchem-1598	126	1	r2δg(kj	r2δg(kj	NOUN
eurjchem-1598	126	2	/	/	SYM
eurjchem-1598	126	3	mol	mol	NOUN
eurjchem-1598	126	4	)	)	PUNCT
eurjchem-1598	126	5	δs(kj	δs(kj	NOUN
eurjchem-1598	126	6	/	/	SYM
eurjchem-1598	126	7	mol.k)δh	mol.k)δh	NOUN
eurjchem-1598	126	8	(	(	PUNCT
eurjchem-1598	126	9	kj	kj	PROPN
eurjchem-1598	126	10	/	/	SYM
eurjchem-1598	126	11	mol)e	mol)e	PROPN
eurjchem-1598	126	12	(	(	PUNCT
eurjchem-1598	126	13	kj	kj	PROPN
eurjchem-1598	126	14	/	/	SYM
eurjchem-1598	126	15	mol	mol	PROPN
eurjchem-1598	126	16	)	)	PUNCT
eurjchem-1598	126	17	a	a	DET
eurjchem-1598	126	18	(	(	PUNCT
eurjchem-1598	126	19	1	1	NUM
eurjchem-1598	126	20	/	/	SYM
eurjchem-1598	126	21	s	s	NOUN
eurjchem-1598	126	22	)	)	PUNCT
eurjchem-1598	126	23	step	step	NOUN
eurjchem-1598	126	24	compound	compound	NOUN
eurjchem-1598	126	25	0.937109.469	0.937109.469	X
eurjchem-1598	126	26	‐0.244419.51822.5781.307891st	‐0.244419.51822.5781.307891st	NOUN
eurjchem-1598	126	27	[	[	AUX
eurjchem-1598	126	28	cu(l)h2o.ch3coo].h2o	cu(l)h2o.ch3coo].h2o	VERB
eurjchem-1598	126	29	0.945	0.945	NUM
eurjchem-1598	126	30	157.319	157.319	NUM
eurjchem-1598	126	31	‐0.2046	‐0.2046	NOUN
eurjchem-1598	126	32	47.234	47.234	NUM
eurjchem-1598	126	33	51.707	51.707	NUM
eurjchem-1598	126	34	2.2971×1022nd	2.2971×1022nd	NUM
eurjchem-1598	126	35	0.917177.180	0.917177.180	NUM
eurjchem-1598	127	1	‐0.234239.46844.3567.151073rd	‐0.234239.46844.3567.151073rd	PROPN
eurjchem-1598	127	2	0.944287.944	0.944287.944	NUM
eurjchem-1598	128	1	‐0.1341159.444167.4091.9666×106	‐0.1341159.444167.4091.9666×106	NUM
eurjchem-1598	128	2	4th	4th	ADJ
eurjchem-1598	128	3	0.949	0.949	NUM
eurjchem-1598	128	4	111.267	111.267	NUM
eurjchem-1598	128	5	‐0.2631	‐0.2631	NUM
eurjchem-1598	128	6	13.129	13.129	NUM
eurjchem-1598	128	7	16.230	16.230	NUM
eurjchem-1598	128	8	0.14027	0.14027	NUM
eurjchem-1598	128	9	1st	1st	NOUN
eurjchem-1598	129	1	[	[	X
eurjchem-1598	129	2	zn(l)h2o.ch3coo	zn(l)h2o.ch3coo	X
eurjchem-1598	129	3	]	]	X
eurjchem-1598	129	4	0.959158.006	0.959158.006	NUM
eurjchem-1598	129	5	‐0.206749.89754.2451.7367×102	‐0.206749.89754.2451.7367×102	VERB
eurjchem-1598	129	6	2nd	2nd	ADJ
eurjchem-1598	129	7	0.977221.018	0.977221.018	NUM
eurjchem-1598	129	8	‐0.1374115.608121.6199.9223×105	‐0.1374115.608121.6199.9223×105	NOUN
eurjchem-1598	129	9	3rd	3rd	ADJ
eurjchem-1598	129	10	0.966109.760	0.966109.760	NUM
eurjchem-1598	129	11	‐0.218928.09631.19728.45531st	‐0.218928.09631.19728.45531st	NOUN
eurjchem-1598	130	1	[	[	X
eurjchem-1598	130	2	cd(l)h2o.ch3coo	cd(l)h2o.ch3coo	NOUN
eurjchem-1598	130	3	]	]	PUNCT
eurjchem-1598	130	4	0.980	0.980	NUM
eurjchem-1598	130	5	134.777	134.777	NUM
eurjchem-1598	130	6	0.0600	0.0600	NUM
eurjchem-1598	130	7	163.501	163.501	NUM
eurjchem-1598	130	8	167.475	167.475	NUM
eurjchem-1598	130	9	1.372×1016	1.372×1016	NUM
eurjchem-1598	130	10	2nd	2nd	ADJ
eurjchem-1598	130	11	0.956174.745	0.956174.745	NOUN
eurjchem-1598	130	12	‐0.29407.743612.4665.187×10‐3	‐0.29407.743612.4665.187×10‐3	NUM
eurjchem-1598	130	13	3rd	3rd	NOUN
eurjchem-1598	130	14	0.949219.254	0.949219.254	PROPN
eurjchem-1598	130	15	‐0.173195.818101.7461.3452×104	‐0.173195.818101.7461.3452×104	PROPN
eurjchem-1598	130	16	4th	4th	PROPN
eurjchem-1598	130	17	indicated	indicate	VERB
eurjchem-1598	130	18	that	that	SCONJ
eurjchem-1598	130	19	this	this	DET
eurjchem-1598	130	20	group	group	NOUN
eurjchem-1598	130	21	not	not	PART
eurjchem-1598	130	22	participation	participation	NOUN
eurjchem-1598	130	23	in	in	ADP
eurjchem-1598	130	24	complex	complex	ADJ
eurjchem-1598	130	25	formation	formation	NOUN
eurjchem-1598	130	26	while	while	SCONJ
eurjchem-1598	130	27	the	the	DET
eurjchem-1598	130	28	signal	signal	NOUN
eurjchem-1598	130	29	at	at	ADP
eurjchem-1598	130	30	δ	δ	PROPN
eurjchem-1598	130	31	11.00	11.00	NUM
eurjchem-1598	130	32	ppm	ppm	NOUN
eurjchem-1598	130	33	in	in	ADP
eurjchem-1598	130	34	ligand	ligand	NOUN
eurjchem-1598	130	35	spectrum	spectrum	NOUN
eurjchem-1598	130	36	which	which	PRON
eurjchem-1598	130	37	attributed	attribute	VERB
eurjchem-1598	130	38	to	to	ADP
eurjchem-1598	130	39	nh	nh	PROPN
eurjchem-1598	130	40	proton	proton	NOUN
eurjchem-1598	130	41	(	(	PUNCT
eurjchem-1598	130	42	indole	indole	ADJ
eurjchem-1598	130	43	moiety	moiety	NOUN
eurjchem-1598	130	44	)	)	PUNCT
eurjchem-1598	130	45	is	be	AUX
eurjchem-1598	130	46	totally	totally	ADV
eurjchem-1598	130	47	absent	absent	ADJ
eurjchem-1598	130	48	in	in	ADP
eurjchem-1598	130	49	the	the	DET
eurjchem-1598	130	50	complex	complex	ADJ
eurjchem-1598	130	51	spectrum	spectrum	NOUN
eurjchem-1598	130	52	which	which	PRON
eurjchem-1598	130	53	indicated	indicate	VERB
eurjchem-1598	130	54	the	the	DET
eurjchem-1598	130	55	deprotonation	deprotonation	NOUN
eurjchem-1598	130	56	of	of	ADP
eurjchem-1598	130	57	nh	nh	PROPN
eurjchem-1598	130	58	group	group	NOUN
eurjchem-1598	130	59	and	and	CCONJ
eurjchem-1598	130	60	subsequently	subsequently	ADV
eurjchem-1598	130	61	the	the	DET
eurjchem-1598	130	62	replacement	replacement	NOUN
eurjchem-1598	130	63	of	of	ADP
eurjchem-1598	130	64	proton	proton	NOUN
eurjchem-1598	130	65	by	by	ADP
eurjchem-1598	130	66	metal	metal	NOUN
eurjchem-1598	130	67	.	.	PUNCT
eurjchem-1598	131	1	figure	figure	NOUN
eurjchem-1598	131	2	4	4	NUM
eurjchem-1598	131	3	.	.	PUNCT
eurjchem-1598	132	1	the	the	DET
eurjchem-1598	132	2	1h	1h	NUM
eurjchem-1598	132	3	nmr	nmr	NOUN
eurjchem-1598	132	4	spectrum	spectrum	NOUN
eurjchem-1598	132	5	of	of	ADP
eurjchem-1598	132	6	zn	zn	PROPN
eurjchem-1598	132	7	complex	complex	NOUN
eurjchem-1598	132	8	.	.	PUNCT
eurjchem-1598	133	1	3.3	3.3	NUM
eurjchem-1598	133	2	.	.	PUNCT
eurjchem-1598	134	1	thermal	thermal	ADJ
eurjchem-1598	134	2	degradation	degradation	NOUN
eurjchem-1598	134	3	3.3.1	3.3.1	NUM
eurjchem-1598	134	4	.	.	PUNCT
eurjchem-1598	134	5	thermal	thermal	ADJ
eurjchem-1598	134	6	degradation	degradation	NOUN
eurjchem-1598	134	7	of	of	ADP
eurjchem-1598	134	8	[	[	PUNCT
eurjchem-1598	134	9	cu(l)(h2o)(ch3coo)].h2o	cu(l)(h2o)(ch3coo)].h2o	NOUN
eurjchem-1598	134	10	the	the	DET
eurjchem-1598	134	11	tg	tg	PROPN
eurjchem-1598	134	12	/	/	SYM
eurjchem-1598	134	13	dtg	dtg	PROPN
eurjchem-1598	134	14	curve	curve	NOUN
eurjchem-1598	134	15	of	of	ADP
eurjchem-1598	134	16	the	the	PRON
eurjchem-1598	134	17	[	[	NOUN
eurjchem-1598	134	18	cu(l)(h2o)(ch3coo)].h2o	cu(l)(h2o)(ch3coo)].h2o	NOUN
eurjchem-1598	134	19	shows	show	VERB
eurjchem-1598	134	20	the	the	DET
eurjchem-1598	134	21	four	four	NUM
eurjchem-1598	134	22	steps	step	NOUN
eurjchem-1598	134	23	decomposition	decomposition	NOUN
eurjchem-1598	134	24	.	.	PUNCT
eurjchem-1598	135	1	the	the	DET
eurjchem-1598	135	2	first	first	ADJ
eurjchem-1598	135	3	step	step	NOUN
eurjchem-1598	135	4	in	in	ADP
eurjchem-1598	135	5	the	the	DET
eurjchem-1598	135	6	range	range	NOUN
eurjchem-1598	135	7	50‐125	50‐125	NOUN
eurjchem-1598	136	1	°	°	NUM
eurjchem-1598	136	2	c	c	X
eurjchem-1598	136	3	(	(	PUNCT
eurjchem-1598	136	4	dtgmax	dtgmax	NOUN
eurjchem-1598	136	5	=	=	SYM
eurjchem-1598	136	6	95	95	NUM
eurjchem-1598	136	7	°	°	NUM
eurjchem-1598	136	8	c	c	NOUN
eurjchem-1598	136	9	)	)	PUNCT
eurjchem-1598	136	10	with	with	ADP
eurjchem-1598	136	11	mass	mass	ADJ
eurjchem-1598	136	12	loss	loss	NOUN
eurjchem-1598	136	13	4.93	4.93	NUM
eurjchem-1598	136	14	%	%	NOUN
eurjchem-1598	136	15	(	(	PUNCT
eurjchem-1598	136	16	theoretical	theoretical	ADJ
eurjchem-1598	136	17	4.45	4.45	NUM
eurjchem-1598	136	18	%	%	NOUN
eurjchem-1598	136	19	)	)	PUNCT
eurjchem-1598	136	20	which	which	PRON
eurjchem-1598	136	21	indicates	indicate	VERB
eurjchem-1598	136	22	the	the	DET
eurjchem-1598	136	23	presence	presence	NOUN
eurjchem-1598	136	24	of	of	ADP
eurjchem-1598	136	25	one	one	NUM
eurjchem-1598	136	26	lattice	lattice	NOUN
eurjchem-1598	136	27	water	water	NOUN
eurjchem-1598	136	28	molecule	molecule	NOUN
eurjchem-1598	136	29	.	.	PUNCT
eurjchem-1598	137	1	the	the	DET
eurjchem-1598	137	2	second	second	ADJ
eurjchem-1598	137	3	step	step	NOUN
eurjchem-1598	137	4	with	with	ADP
eurjchem-1598	137	5	mass	mass	ADJ
eurjchem-1598	137	6	loss	loss	NOUN
eurjchem-1598	137	7	4.89	4.89	NUM
eurjchem-1598	137	8	%	%	NOUN
eurjchem-1598	137	9	(	(	PUNCT
eurjchem-1598	137	10	theoretical	theoretical	ADJ
eurjchem-1598	137	11	4.66	4.66	NUM
eurjchem-1598	137	12	%	%	NOUN
eurjchem-1598	137	13	)	)	PUNCT
eurjchem-1598	137	14	which	which	PRON
eurjchem-1598	137	15	attributed	attribute	VERB
eurjchem-1598	137	16	to	to	ADP
eurjchem-1598	137	17	one	one	NUM
eurjchem-1598	137	18	coordinated	coordinate	VERB
eurjchem-1598	137	19	water	water	NOUN
eurjchem-1598	137	20	molecule	molecule	NOUN
eurjchem-1598	137	21	[	[	X
eurjchem-1598	137	22	19	19	NUM
eurjchem-1598	137	23	]	]	PUNCT
eurjchem-1598	137	24	.	.	PUNCT
eurjchem-1598	138	1	the	the	DET
eurjchem-1598	138	2	third	third	ADJ
eurjchem-1598	138	3	and	and	CCONJ
eurjchem-1598	138	4	fourth	fourth	ADJ
eurjchem-1598	138	5	steps	step	NOUN
eurjchem-1598	138	6	take	take	VERB
eurjchem-1598	138	7	place	place	NOUN
eurjchem-1598	138	8	in	in	ADP
eurjchem-1598	138	9	fast	fast	ADJ
eurjchem-1598	138	10	rate	rate	NOUN
eurjchem-1598	138	11	(	(	PUNCT
eurjchem-1598	138	12	figure	figure	NOUN
eurjchem-1598	138	13	5	5	NUM
eurjchem-1598	138	14	)	)	PUNCT
eurjchem-1598	138	15	starting	start	VERB
eurjchem-1598	138	16	from	from	ADP
eurjchem-1598	138	17	275	275	NUM
eurjchem-1598	138	18	°	°	NOUN
eurjchem-1598	138	19	c	c	NOUN
eurjchem-1598	138	20	to	to	ADP
eurjchem-1598	138	21	the	the	DET
eurjchem-1598	138	22	final	final	ADJ
eurjchem-1598	138	23	temperature	temperature	NOUN
eurjchem-1598	138	24	800	800	NUM
eurjchem-1598	138	25	°	°	NOUN
eurjchem-1598	138	26	c	c	NOUN
eurjchem-1598	138	27	.	.	PUNCT
eurjchem-1598	139	1	the	the	DET
eurjchem-1598	139	2	residual	residual	ADJ
eurjchem-1598	139	3	part	part	NOUN
eurjchem-1598	139	4	28	28	NUM
eurjchem-1598	139	5	%	%	NOUN
eurjchem-1598	139	6	,	,	PUNCT
eurjchem-1598	139	7	may	may	AUX
eurjchem-1598	139	8	be	be	AUX
eurjchem-1598	139	9	attributed	attribute	VERB
eurjchem-1598	139	10	to	to	ADP
eurjchem-1598	139	11	the	the	DET
eurjchem-1598	139	12	cuo	cuo	PROPN
eurjchem-1598	139	13	polluted	pollute	VERB
eurjchem-1598	139	14	with	with	ADP
eurjchem-1598	139	15	carbon	carbon	NOUN
eurjchem-1598	139	16	[	[	X
eurjchem-1598	139	17	19,20	19,20	NOUN
eurjchem-1598	139	18	]	]	PUNCT
eurjchem-1598	139	19	.	.	PUNCT
eurjchem-1598	140	1	figure	figure	NOUN
eurjchem-1598	140	2	5	5	NUM
eurjchem-1598	140	3	.	.	PUNCT
eurjchem-1598	140	4	tg	tg	PROPN
eurjchem-1598	140	5	/	/	SYM
eurjchem-1598	140	6	dtg	dtg	PROPN
eurjchem-1598	140	7	curve	curve	NOUN
eurjchem-1598	140	8	of	of	ADP
eurjchem-1598	140	9	copper	copper	NOUN
eurjchem-1598	140	10	complex	complex	NOUN
eurjchem-1598	140	11	.	.	PUNCT
eurjchem-1598	141	1	3.3.2	3.3.2	X
eurjchem-1598	141	2	.	.	PUNCT
eurjchem-1598	141	3	thermal	thermal	ADJ
eurjchem-1598	141	4	degradation	degradation	NOUN
eurjchem-1598	141	5	of	of	ADP
eurjchem-1598	141	6	[	[	X
eurjchem-1598	141	7	zn(l)(h2o)(ch3coo)].2h2o	zn(l)(h2o)(ch3coo)].2h2o	NOUN
eurjchem-1598	141	8	the	the	DET
eurjchem-1598	141	9	tg	tg	PROPN
eurjchem-1598	141	10	/	/	SYM
eurjchem-1598	141	11	dtg	dtg	PROPN
eurjchem-1598	141	12	curve	curve	NOUN
eurjchem-1598	141	13	of	of	ADP
eurjchem-1598	141	14	the	the	DET
eurjchem-1598	141	15	zinc	zinc	NOUN
eurjchem-1598	141	16	complex	complex	NOUN
eurjchem-1598	141	17	shows	show	VERB
eurjchem-1598	141	18	three	three	NUM
eurjchem-1598	141	19	steps	step	NOUN
eurjchem-1598	141	20	of	of	ADP
eurjchem-1598	141	21	degradation	degradation	NOUN
eurjchem-1598	141	22	,	,	PUNCT
eurjchem-1598	141	23	the	the	DET
eurjchem-1598	141	24	first	first	ADJ
eurjchem-1598	141	25	step	step	NOUN
eurjchem-1598	141	26	8.49	8.49	NUM
eurjchem-1598	141	27	%	%	NOUN
eurjchem-1598	141	28	(	(	PUNCT
eurjchem-1598	141	29	theoretical	theoretical	ADJ
eurjchem-1598	141	30	8.49	8.49	NUM
eurjchem-1598	141	31	%	%	NOUN
eurjchem-1598	141	32	)	)	PUNCT
eurjchem-1598	141	33	weight	weight	NOUN
eurjchem-1598	141	34	loss	loss	NOUN
eurjchem-1598	141	35	in	in	ADP
eurjchem-1598	141	36	the	the	DET
eurjchem-1598	141	37	range	range	NOUN
eurjchem-1598	141	38	50‐169	50‐169	NUM
eurjchem-1598	141	39	°	°	NOUN
eurjchem-1598	141	40	c	c	NOUN
eurjchem-1598	141	41	corresponds	correspond	VERB
eurjchem-1598	141	42	to	to	ADP
eurjchem-1598	141	43	two	two	NUM
eurjchem-1598	141	44	lattice	lattice	NOUN
eurjchem-1598	141	45	water	water	NOUN
eurjchem-1598	141	46	molecules	molecule	NOUN
eurjchem-1598	141	47	[	[	X
eurjchem-1598	141	48	20	20	NUM
eurjchem-1598	141	49	]	]	PUNCT
eurjchem-1598	141	50	.	.	PUNCT
eurjchem-1598	142	1	the	the	DET
eurjchem-1598	142	2	second	second	ADJ
eurjchem-1598	142	3	step	step	NOUN
eurjchem-1598	142	4	in	in	ADP
eurjchem-1598	142	5	the	the	DET
eurjchem-1598	142	6	range	range	NOUN
eurjchem-1598	142	7	185‐345	185‐345	NUM
eurjchem-1598	142	8	°	°	ADP
eurjchem-1598	142	9	c	c	PROPN
eurjchem-1598	142	10	with	with	ADP
eurjchem-1598	142	11	mass	mass	ADJ
eurjchem-1598	142	12	loss	loss	NOUN
eurjchem-1598	142	13	20.2	20.2	NUM
eurjchem-1598	142	14	%	%	NOUN
eurjchem-1598	142	15	(	(	PUNCT
eurjchem-1598	142	16	theoretical	theoretical	ADJ
eurjchem-1598	142	17	20.1	20.1	NUM
eurjchem-1598	142	18	%	%	NOUN
eurjchem-1598	142	19	)	)	PUNCT
eurjchem-1598	142	20	which	which	PRON
eurjchem-1598	142	21	represent	represent	VERB
eurjchem-1598	142	22	the	the	DET
eurjchem-1598	142	23	loss	loss	NOUN
eurjchem-1598	142	24	of	of	ADP
eurjchem-1598	142	25	both	both	CCONJ
eurjchem-1598	142	26	acetate	acetate	NOUN
eurjchem-1598	142	27	and	and	CCONJ
eurjchem-1598	142	28	coordinated	coordinated	ADJ
eurjchem-1598	142	29	water	water	NOUN
eurjchem-1598	142	30	together	together	ADV
eurjchem-1598	142	31	.	.	PUNCT
eurjchem-1598	143	1	the	the	DET
eurjchem-1598	143	2	last	last	ADJ
eurjchem-1598	143	3	step	step	NOUN
eurjchem-1598	143	4	begin	begin	VERB
eurjchem-1598	143	5	at	at	ADP
eurjchem-1598	143	6	350	350	NUM
eurjchem-1598	143	7	°	°	NOUN
eurjchem-1598	143	8	c	c	NOUN
eurjchem-1598	143	9	and	and	CCONJ
eurjchem-1598	143	10	end	end	VERB
eurjchem-1598	143	11	at	at	ADP
eurjchem-1598	143	12	600	600	NUM
eurjchem-1598	143	13	°	°	NOUN
eurjchem-1598	143	14	c	c	NOUN
eurjchem-1598	143	15	to	to	PART
eurjchem-1598	143	16	afford	afford	VERB
eurjchem-1598	143	17	the	the	DET
eurjchem-1598	143	18	final	final	ADJ
eurjchem-1598	143	19	degradation	degradation	NOUN
eurjchem-1598	143	20	of	of	ADP
eurjchem-1598	143	21	ligand	ligand	NOUN
eurjchem-1598	143	22	and	and	CCONJ
eurjchem-1598	143	23	the	the	DET
eurjchem-1598	143	24	final	final	ADJ
eurjchem-1598	143	25	product	product	NOUN
eurjchem-1598	143	26	is	be	AUX
eurjchem-1598	143	27	zno	zno	NOUN
eurjchem-1598	143	28	19.72	19.72	NUM
eurjchem-1598	143	29	%	%	NOUN
eurjchem-1598	143	30	(	(	PUNCT
eurjchem-1598	143	31	theoretical	theoretical	ADJ
eurjchem-1598	143	32	19	19	NUM
eurjchem-1598	143	33	%	%	NOUN
eurjchem-1598	143	34	)	)	PUNCT
eurjchem-1598	144	1	[	[	X
eurjchem-1598	144	2	19,20	19,20	X
eurjchem-1598	144	3	]	]	PUNCT
eurjchem-1598	144	4	.	.	PUNCT
eurjchem-1598	145	1	3.3.3	3.3.3	NUM
eurjchem-1598	145	2	.	.	PUNCT
eurjchem-1598	145	3	thermal	thermal	ADJ
eurjchem-1598	145	4	degradation	degradation	NOUN
eurjchem-1598	145	5	of	of	ADP
eurjchem-1598	145	6	[	[	X
eurjchem-1598	145	7	cd(l)(h2o)(ch3coo)].h2o	cd(l)(h2o)(ch3coo)].h2o	NOUN
eurjchem-1598	145	8	the	the	DET
eurjchem-1598	145	9	tg	tg	PROPN
eurjchem-1598	145	10	/	/	SYM
eurjchem-1598	145	11	dtg	dtg	PROPN
eurjchem-1598	145	12	curve	curve	NOUN
eurjchem-1598	145	13	of	of	ADP
eurjchem-1598	145	14	the	the	DET
eurjchem-1598	145	15	cadmium	cadmium	NOUN
eurjchem-1598	145	16	complex	complex	NOUN
eurjchem-1598	145	17	shows	show	VERB
eurjchem-1598	145	18	four	four	NUM
eurjchem-1598	145	19	steps	step	NOUN
eurjchem-1598	145	20	decomposition	decomposition	NOUN
eurjchem-1598	145	21	and	and	CCONJ
eurjchem-1598	145	22	similar	similar	ADJ
eurjchem-1598	145	23	to	to	ADP
eurjchem-1598	145	24	the	the	DET
eurjchem-1598	145	25	cu	cu	PROPN
eurjchem-1598	145	26	complex	complex	NOUN
eurjchem-1598	145	27	,	,	PUNCT
eurjchem-1598	145	28	where	where	SCONJ
eurjchem-1598	145	29	the	the	DET
eurjchem-1598	145	30	first	first	ADJ
eurjchem-1598	145	31	step	step	NOUN
eurjchem-1598	145	32	50‐150	50‐150	PROPN
eurjchem-1598	145	33	°	°	ADP
eurjchem-1598	145	34	c	c	X
eurjchem-1598	145	35	(	(	PUNCT
eurjchem-1598	145	36	dtgmax	dtgmax	NOUN
eurjchem-1598	145	37	=	=	SYM
eurjchem-1598	145	38	100	100	NUM
eurjchem-1598	145	39	°	°	NUM
eurjchem-1598	145	40	c	c	NOUN
eurjchem-1598	145	41	)	)	PUNCT
eurjchem-1598	145	42	with	with	ADP
eurjchem-1598	145	43	mass	mass	ADJ
eurjchem-1598	145	44	loss	loss	NOUN
eurjchem-1598	145	45	3.83	3.83	NUM
eurjchem-1598	145	46	%	%	NOUN
eurjchem-1598	145	47	(	(	PUNCT
eurjchem-1598	145	48	theoretical	theoretical	ADJ
eurjchem-1598	145	49	3.97	3.97	NUM
eurjchem-1598	145	50	%	%	NOUN
eurjchem-1598	145	51	)	)	PUNCT
eurjchem-1598	145	52	which	which	PRON
eurjchem-1598	145	53	indicated	indicate	VERB
eurjchem-1598	145	54	the	the	DET
eurjchem-1598	145	55	presence	presence	NOUN
eurjchem-1598	145	56	of	of	ADP
eurjchem-1598	145	57	one	one	NUM
eurjchem-1598	145	58	lattice	lattice	NOUN
eurjchem-1598	145	59	water	water	NOUN
eurjchem-1598	145	60	molecule	molecule	NOUN
eurjchem-1598	145	61	[	[	X
eurjchem-1598	145	62	20	20	NUM
eurjchem-1598	145	63	]	]	PUNCT
eurjchem-1598	145	64	.	.	PUNCT
eurjchem-1598	146	1	the	the	DET
eurjchem-1598	146	2	second	second	ADJ
eurjchem-1598	146	3	and	and	CCONJ
eurjchem-1598	146	4	third	third	ADJ
eurjchem-1598	146	5	steps	step	NOUN
eurjchem-1598	146	6	in	in	ADP
eurjchem-1598	146	7	the	the	DET
eurjchem-1598	146	8	range	range	NOUN
eurjchem-1598	146	9	170‐410	170‐410	NUM
eurjchem-1598	146	10	°	°	ADP
eurjchem-1598	146	11	c	c	PROPN
eurjchem-1598	146	12	with	with	ADP
eurjchem-1598	146	13	total	total	ADJ
eurjchem-1598	146	14	mass	mass	ADJ
eurjchem-1598	146	15	loss	loss	NOUN
eurjchem-1598	146	16	17.77	17.77	NUM
eurjchem-1598	146	17	%	%	NOUN
eurjchem-1598	146	18	(	(	PUNCT
eurjchem-1598	146	19	theoretical	theoretical	ADJ
eurjchem-1598	146	20	17.93	17.93	NUM
eurjchem-1598	146	21	%	%	NOUN
eurjchem-1598	146	22	)	)	PUNCT
eurjchem-1598	146	23	equivalent	equivalent	ADJ
eurjchem-1598	146	24	to	to	ADP
eurjchem-1598	146	25	one	one	NUM
eurjchem-1598	146	26	coordinated	coordinate	VERB
eurjchem-1598	146	27	water	water	NOUN
eurjchem-1598	146	28	molecule	molecule	NOUN
eurjchem-1598	146	29	and	and	CCONJ
eurjchem-1598	146	30	acetate	acetate	NOUN
eurjchem-1598	146	31	.	.	PUNCT
eurjchem-1598	147	1	the	the	DET
eurjchem-1598	147	2	fourth	fourth	ADJ
eurjchem-1598	147	3	step	step	NOUN
eurjchem-1598	147	4	starting	start	VERB
eurjchem-1598	147	5	from	from	ADP
eurjchem-1598	147	6	415	415	NUM
eurjchem-1598	147	7	to	to	PART
eurjchem-1598	147	8	800	800	NUM
eurjchem-1598	147	9	°	°	NOUN
eurjchem-1598	147	10	c	c	NOUN
eurjchem-1598	147	11	and	and	CCONJ
eurjchem-1598	147	12	the	the	DET
eurjchem-1598	147	13	final	final	ADJ
eurjchem-1598	147	14	residue	residue	NOUN
eurjchem-1598	147	15	27.85	27.85	NUM
eurjchem-1598	147	16	%	%	NOUN
eurjchem-1598	147	17	(	(	PUNCT
eurjchem-1598	147	18	theoretical	theoretical	ADJ
eurjchem-1598	147	19	28.25	28.25	NUM
eurjchem-1598	147	20	%	%	NOUN
eurjchem-1598	147	21	)	)	PUNCT
eurjchem-1598	147	22	which	which	PRON
eurjchem-1598	147	23	indicated	indicate	VERB
eurjchem-1598	147	24	that	that	SCONJ
eurjchem-1598	147	25	the	the	DET
eurjchem-1598	147	26	final	final	ADJ
eurjchem-1598	147	27	product	product	NOUN
eurjchem-1598	147	28	is	be	AUX
eurjchem-1598	147	29	cadmium	cadmium	NOUN
eurjchem-1598	147	30	(	(	PUNCT
eurjchem-1598	147	31	ii	ii	NOUN
eurjchem-1598	147	32	)	)	PUNCT
eurjchem-1598	147	33	oxide	oxide	NOUN
eurjchem-1598	147	34	.	.	PUNCT
eurjchem-1598	148	1	3.4	3.4	NUM
eurjchem-1598	148	2	.	.	PUNCT
eurjchem-1598	149	1	kinetic	kinetic	ADJ
eurjchem-1598	149	2	and	and	CCONJ
eurjchem-1598	149	3	thermodynamic	thermodynamic	ADJ
eurjchem-1598	149	4	analysis	analysis	NOUN
eurjchem-1598	149	5	the	the	DET
eurjchem-1598	149	6	thermal	thermal	ADJ
eurjchem-1598	149	7	dehydration	dehydration	NOUN
eurjchem-1598	149	8	and	and	CCONJ
eurjchem-1598	149	9	decomposition	decomposition	NOUN
eurjchem-1598	149	10	of	of	ADP
eurjchem-1598	149	11	the	the	DET
eurjchem-1598	149	12	complexes	complex	NOUN
eurjchem-1598	149	13	were	be	AUX
eurjchem-1598	149	14	studied	study	VERB
eurjchem-1598	149	15	using	use	VERB
eurjchem-1598	149	16	coats‐redfern	coats‐redfern	ADJ
eurjchem-1598	149	17	method	method	NOUN
eurjchem-1598	149	18	[	[	X
eurjchem-1598	149	19	20,21	20,21	NUM
eurjchem-1598	149	20	]	]	PUNCT
eurjchem-1598	149	21	.	.	PUNCT
eurjchem-1598	150	1	2	2	NUM
eurjchem-1598	150	2	wf	wf	NOUN
eurjchem-1598	150	3	log	log	VERB
eurjchem-1598	150	4	a×r	a×r	NOUN
eurjchem-1598	150	5	2×r×t	2×r×t	NUM
eurjchem-1598	150	6	ewf‐wtlog	ewf‐wtlog	NUM
eurjchem-1598	150	7	=	=	AUX
eurjchem-1598	150	8	log	log	VERB
eurjchem-1598	150	9	1‐	1‐	NUM
eurjchem-1598	150	10	‐	‐	NOUN
eurjchem-1598	150	11	t	t	NOUN
eurjchem-1598	150	12	θ×e	θ×e	PUNCT
eurjchem-1598	151	1	e	e	PROPN
eurjchem-1598	151	2	2.303×r×t	2.303×r×t	NUM
eurjchem-1598	151	3			NUM
eurjchem-1598	151	4			ADJ
eurjchem-1598	151	5			NOUN
eurjchem-1598	152	1			NOUN
eurjchem-1598	152	2			PROPN
eurjchem-1598	153	1			PROPN
eurjchem-1598	153	2			PROPN
eurjchem-1598	153	3			VERB
eurjchem-1598	153	4			PROPN
eurjchem-1598	153	5			PROPN
eurjchem-1598	153	6			PROPN
eurjchem-1598	153	7			NOUN
eurjchem-1598	154	1			PROPN
eurjchem-1598	154	2			NOUN
eurjchem-1598	154	3			PROPN
eurjchem-1598	154	4			NOUN
eurjchem-1598	154	5			PROPN
eurjchem-1598	154	6	(	(	PUNCT
eurjchem-1598	154	7	1	1	NUM
eurjchem-1598	154	8	)	)	PUNCT
eurjchem-1598	154	9	where	where	SCONJ
eurjchem-1598	154	10	wf	wf	PROPN
eurjchem-1598	154	11	and	and	CCONJ
eurjchem-1598	154	12	wt	wt	PROPN
eurjchem-1598	154	13	are	be	AUX
eurjchem-1598	154	14	weight	weight	NOUN
eurjchem-1598	154	15	at	at	ADP
eurjchem-1598	154	16	the	the	DET
eurjchem-1598	154	17	end	end	NOUN
eurjchem-1598	154	18	step	step	NOUN
eurjchem-1598	154	19	and	and	CCONJ
eurjchem-1598	154	20	at	at	ADP
eurjchem-1598	154	21	any	any	DET
eurjchem-1598	154	22	temperature	temperature	NOUN
eurjchem-1598	154	23	,	,	PUNCT
eurjchem-1598	154	24	respectively	respectively	ADV
eurjchem-1598	154	25	;	;	PUNCT
eurjchem-1598	154	26	e	e	X
eurjchem-1598	154	27	,	,	PUNCT
eurjchem-1598	154	28	activation	activation	NOUN
eurjchem-1598	154	29	energy	energy	NOUN
eurjchem-1598	154	30	;	;	PUNCT
eurjchem-1598	154	31	r	r	NOUN
eurjchem-1598	154	32	,	,	PUNCT
eurjchem-1598	154	33	gas	gas	NOUN
eurjchem-1598	154	34	constant	constant	ADJ
eurjchem-1598	154	35	(	(	PUNCT
eurjchem-1598	154	36	8.314×10‐3	8.314×10‐3	NUM
eurjchem-1598	154	37	kj	kj	NOUN
eurjchem-1598	154	38	/	/	SYM
eurjchem-1598	154	39	mole	mole	NOUN
eurjchem-1598	154	40	)	)	PUNCT
eurjchem-1598	154	41	;	;	PUNCT
eurjchem-1598	154	42	ɵ	ɵ	X
eurjchem-1598	154	43	,	,	PUNCT
eurjchem-1598	154	44	heating	heating	NOUN
eurjchem-1598	154	45	rate	rate	NOUN
eurjchem-1598	154	46	and	and	CCONJ
eurjchem-1598	154	47	a	a	PRON
eurjchem-1598	154	48	,	,	PUNCT
eurjchem-1598	154	49	pre‐	pre‐	NOUN
eurjchem-1598	154	50	exponential	exponential	ADJ
eurjchem-1598	154	51	factor	factor	NOUN
eurjchem-1598	154	52	.	.	PUNCT
eurjchem-1598	155	1	the	the	DET
eurjchem-1598	155	2	decomposition	decomposition	NOUN
eurjchem-1598	155	3	steps	step	NOUN
eurjchem-1598	155	4	of	of	ADP
eurjchem-1598	155	5	all	all	DET
eurjchem-1598	155	6	complexes	complex	NOUN
eurjchem-1598	155	7	show	show	VERB
eurjchem-1598	155	8	a	a	DET
eurjchem-1598	155	9	best	good	ADJ
eurjchem-1598	155	10	fit	fit	NOUN
eurjchem-1598	155	11	for	for	ADP
eurjchem-1598	155	12	first	first	ADJ
eurjchem-1598	155	13	order	order	NOUN
eurjchem-1598	155	14	in	in	ADP
eurjchem-1598	155	15	all	all	DET
eurjchem-1598	155	16	steps	step	NOUN
eurjchem-1598	155	17	.	.	PUNCT
eurjchem-1598	156	1	the	the	DET
eurjchem-1598	156	2	correlation	correlation	NOUN
eurjchem-1598	156	3	coefficient	coefficient	NOUN
eurjchem-1598	156	4	(	(	PUNCT
eurjchem-1598	156	5	r2	r2	PROPN
eurjchem-1598	156	6	)	)	PUNCT
eurjchem-1598	156	7	was	be	AUX
eurjchem-1598	156	8	computed	compute	VERB
eurjchem-1598	156	9	using	use	VERB
eurjchem-1598	156	10	the	the	DET
eurjchem-1598	156	11	least	least	ADJ
eurjchem-1598	156	12	square	square	ADJ
eurjchem-1598	156	13	method	method	NOUN
eurjchem-1598	156	14	by	by	ADP
eurjchem-1598	156	15	plotting	plot	VERB
eurjchem-1598	156	16	the	the	DET
eurjchem-1598	156	17	left	left	ADJ
eurjchem-1598	156	18	hand	hand	NOUN
eurjchem-1598	156	19	side	side	NOUN
eurjchem-1598	156	20	of	of	ADP
eurjchem-1598	156	21	coats‐redfern	coats‐redfern	ADJ
eurjchem-1598	156	22	equation	equation	NOUN
eurjchem-1598	156	23	versus	versus	ADP
eurjchem-1598	156	24	1000	1000	NUM
eurjchem-1598	156	25	/	/	SYM
eurjchem-1598	156	26	t	t	NOUN
eurjchem-1598	156	27	(	(	PUNCT
eurjchem-1598	156	28	figure	figure	NOUN
eurjchem-1598	156	29	6	6	NUM
eurjchem-1598	156	30	)	)	PUNCT
eurjchem-1598	156	31	.	.	PUNCT
eurjchem-1598	157	1	the	the	DET
eurjchem-1598	157	2	activation	activation	NOUN
eurjchem-1598	157	3	energy	energy	NOUN
eurjchem-1598	157	4	and	and	CCONJ
eurjchem-1598	157	5	the	the	DET
eurjchem-1598	157	6	exponential	exponential	ADJ
eurjchem-1598	157	7	factor	factor	NOUN
eurjchem-1598	157	8	were	be	AUX
eurjchem-1598	157	9	calculated	calculate	VERB
eurjchem-1598	157	10	from	from	ADP
eurjchem-1598	157	11	the	the	DET
eurjchem-1598	157	12	slope	slope	NOUN
eurjchem-1598	157	13	and	and	CCONJ
eurjchem-1598	157	14	intercept	intercept	NOUN
eurjchem-1598	157	15	,	,	PUNCT
eurjchem-1598	157	16	respectively	respectively	ADV
eurjchem-1598	157	17	.	.	PUNCT
eurjchem-1598	158	1	∆h	∆h	NUM
eurjchem-1598	158	2	,	,	PUNCT
eurjchem-1598	158	3	∆s	∆s	NOUN
eurjchem-1598	158	4	and	and	CCONJ
eurjchem-1598	158	5	∆g	∆g	PROPN
eurjchem-1598	158	6	for	for	ADP
eurjchem-1598	158	7	all	all	DET
eurjchem-1598	158	8	steps	step	NOUN
eurjchem-1598	158	9	were	be	AUX
eurjchem-1598	158	10	calculated	calculate	VERB
eurjchem-1598	158	11	by	by	ADP
eurjchem-1598	158	12	using	use	VERB
eurjchem-1598	158	13	the	the	DET
eurjchem-1598	158	14	equation	equation	NOUN
eurjchem-1598	158	15	(	(	PUNCT
eurjchem-1598	158	16	2‐4	2‐4	NUM
eurjchem-1598	158	17	)	)	PUNCT
eurjchem-1598	158	18	.	.	PUNCT
eurjchem-1598	159	1	δh	δh	ADP
eurjchem-1598	159	2	=	=	PUNCT
eurjchem-1598	159	3	δe	δe	X
eurjchem-1598	159	4	–	–	PUNCT
eurjchem-1598	159	5	r×t	r×t	PROPN
eurjchem-1598	159	6	(	(	PUNCT
eurjchem-1598	159	7	2	2	NUM
eurjchem-1598	159	8	)	)	PUNCT
eurjchem-1598	159	9	δs	δs	NOUN
eurjchem-1598	159	10	=	=	NOUN
eurjchem-1598	159	11	r	r	NOUN
eurjchem-1598	159	12	×	×	NOUN
eurjchem-1598	159	13	ln	ln	ADJ
eurjchem-1598	159	14	(	(	PUNCT
eurjchem-1598	159	15	a×h	a×h	PROPN
eurjchem-1598	159	16	/	/	SYM
eurjchem-1598	159	17	kb×ts	kb×ts	PROPN
eurjchem-1598	159	18	)	)	PUNCT
eurjchem-1598	159	19	(	(	PUNCT
eurjchem-1598	159	20	3	3	X
eurjchem-1598	159	21	)	)	PUNCT
eurjchem-1598	159	22	δg	δg	NOUN
eurjchem-1598	159	23	=	=	PUNCT
eurjchem-1598	159	24	δh	δh	NOUN
eurjchem-1598	159	25	–	–	PUNCT
eurjchem-1598	159	26	t×δs	t×δs	PRON
eurjchem-1598	159	27	(	(	PUNCT
eurjchem-1598	159	28	4	4	NUM
eurjchem-1598	159	29	)	)	PUNCT
eurjchem-1598	159	30	whereas	whereas	ADV
eurjchem-1598	159	31	,	,	PUNCT
eurjchem-1598	159	32	h	h	NOUN
eurjchem-1598	159	33	,	,	PUNCT
eurjchem-1598	159	34	planck	planck	NOUN
eurjchem-1598	159	35	constant	constant	ADJ
eurjchem-1598	159	36	(	(	PUNCT
eurjchem-1598	159	37	6.6262×10‐34	6.6262×10‐34	NUM
eurjchem-1598	159	38	j.s);kb	j.s);kb	NOUN
eurjchem-1598	159	39	,	,	PUNCT
eurjchem-1598	159	40	boltzman	boltzman	NOUN
eurjchem-1598	159	41	constant	constant	ADJ
eurjchem-1598	159	42	(	(	PUNCT
eurjchem-1598	159	43	1.3806×10‐23	1.3806×10‐23	NUM
eurjchem-1598	159	44	j	j	PROPN
eurjchem-1598	159	45	/	/	SYM
eurjchem-1598	159	46	k	k	NOUN
eurjchem-1598	159	47	)	)	PUNCT
eurjchem-1598	159	48	and	and	CCONJ
eurjchem-1598	159	49	ts	ts	X
eurjchem-1598	159	50	(	(	PUNCT
eurjchem-1598	159	51	tmax	tmax	ADV
eurjchem-1598	159	52	from	from	ADP
eurjchem-1598	159	53	dtg	dtg	PROPN
eurjchem-1598	159	54	curve	curve	NOUN
eurjchem-1598	159	55	)	)	PUNCT
eurjchem-1598	159	56	.	.	PUNCT
eurjchem-1598	160	1	the	the	DET
eurjchem-1598	160	2	thermokinetic	thermokinetic	ADJ
eurjchem-1598	160	3	data	datum	NOUN
eurjchem-1598	160	4	are	be	AUX
eurjchem-1598	160	5	summarized	summarize	VERB
eurjchem-1598	160	6	in	in	ADP
eurjchem-1598	160	7	table	table	NOUN
eurjchem-1598	160	8	1	1	NUM
eurjchem-1598	160	9	.	.	PUNCT
eurjchem-1598	161	1	from	from	ADP
eurjchem-1598	161	2	this	this	DET
eurjchem-1598	161	3	result	result	NOUN
eurjchem-1598	161	4	,	,	PUNCT
eurjchem-1598	161	5	the	the	DET
eurjchem-1598	161	6	high	high	ADJ
eurjchem-1598	161	7	activation	activation	NOUN
eurjchem-1598	161	8	energy	energy	NOUN
eurjchem-1598	161	9	for	for	ADP
eurjchem-1598	161	10	all	all	DET
eurjchem-1598	161	11	complexes	complex	NOUN
eurjchem-1598	161	12	indicated	indicate	VERB
eurjchem-1598	161	13	the	the	DET
eurjchem-1598	161	14	high	high	ADJ
eurjchem-1598	161	15	stability	stability	NOUN
eurjchem-1598	161	16	of	of	ADP
eurjchem-1598	161	17	the	the	DET
eurjchem-1598	161	18	complexes	complex	NOUN
eurjchem-1598	161	19	.	.	PUNCT
eurjchem-1598	162	1	in	in	ADP
eurjchem-1598	162	2	general	general	ADJ
eurjchem-1598	162	3	,	,	PUNCT
eurjchem-1598	162	4	the	the	DET
eurjchem-1598	162	5	activation	activation	NOUN
eurjchem-1598	162	6	energy	energy	NOUN
eurjchem-1598	162	7	of	of	ADP
eurjchem-1598	162	8	the	the	DET
eurjchem-1598	162	9	second	second	ADJ
eurjchem-1598	162	10	steps	step	NOUN
eurjchem-1598	162	11	are	be	AUX
eurjchem-1598	162	12	higher	high	ADJ
eurjchem-1598	162	13	than	than	ADP
eurjchem-1598	162	14	first	first	ADJ
eurjchem-1598	162	15	step	step	NOUN
eurjchem-1598	162	16	,	,	PUNCT
eurjchem-1598	162	17	this	this	PRON
eurjchem-1598	162	18	indicated	indicate	VERB
eurjchem-1598	162	19	that	that	SCONJ
eurjchem-1598	162	20	the	the	DET
eurjchem-1598	162	21	dehydrated	dehydrate	VERB
eurjchem-1598	162	22	complexes	complex	NOUN
eurjchem-1598	162	23	are	be	AUX
eurjchem-1598	162	24	more	more	ADV
eurjchem-1598	162	25	stable	stable	ADJ
eurjchem-1598	162	26	,	,	PUNCT
eurjchem-1598	162	27	in	in	ADP
eurjchem-1598	162	28	addition	addition	NOUN
eurjchem-1598	162	29	the	the	DET
eurjchem-1598	162	30	positive	positive	ADJ
eurjchem-1598	162	31	value	value	NOUN
eurjchem-1598	162	32	of	of	ADP
eurjchem-1598	162	33	∆h	∆h	PROPN
eurjchem-1598	162	34	means	mean	VERB
eurjchem-1598	162	35	that	that	SCONJ
eurjchem-1598	162	36	the	the	DET
eurjchem-1598	162	37	decompo‐	decompo‐	NOUN
eurjchem-1598	162	38	sition	sition	NOUN
eurjchem-1598	162	39	process	process	NOUN
eurjchem-1598	162	40	are	be	AUX
eurjchem-1598	162	41	endothermic	endothermic	ADJ
eurjchem-1598	162	42	.	.	PUNCT
eurjchem-1598	163	1	the	the	DET
eurjchem-1598	163	2	negative	negative	ADJ
eurjchem-1598	163	3	values	value	NOUN
eurjchem-1598	163	4	of	of	ADP
eurjchem-1598	163	5	∆s	∆s	NOUN
eurjchem-1598	163	6	indicated	indicate	VERB
eurjchem-1598	163	7	that	that	SCONJ
eurjchem-1598	163	8	the	the	DET
eurjchem-1598	163	9	complexes	complex	NOUN
eurjchem-1598	163	10	more	more	ADV
eurjchem-1598	163	11	ordered	order	VERB
eurjchem-1598	163	12	than	than	ADP
eurjchem-1598	163	13	the	the	DET
eurjchem-1598	163	14	reactants	reactant	NOUN
eurjchem-1598	163	15	.	.	PUNCT
eurjchem-1598	164	1	all	all	DET
eurjchem-1598	164	2	values	value	NOUN
eurjchem-1598	164	3	of	of	ADP
eurjchem-1598	164	4	∆g	∆g	PROPN
eurjchem-1598	164	5	are	be	AUX
eurjchem-1598	164	6	positive	positive	ADJ
eurjchem-1598	164	7	which	which	PRON
eurjchem-1598	164	8	indicate	indicate	VERB
eurjchem-1598	164	9	that	that	SCONJ
eurjchem-1598	164	10	all	all	DET
eurjchem-1598	164	11	steps	step	NOUN
eurjchem-1598	164	12	are	be	AUX
eurjchem-1598	164	13	non‐spontaneous	non‐spontaneous	ADJ
eurjchem-1598	164	14	[	[	X
eurjchem-1598	164	15	20	20	NUM
eurjchem-1598	164	16	]	]	PUNCT
eurjchem-1598	164	17	.	.	PUNCT
eurjchem-1598	165	1	256	256	NUM
eurjchem-1598	165	2	hadi	hadi	NOUN
eurjchem-1598	165	3	et	et	PROPN
eurjchem-1598	165	4	al	al	PROPN
eurjchem-1598	165	5	.	.	PUNCT
eurjchem-1598	165	6	/	/	SYM
eurjchem-1598	165	7	european	european	PROPN
eurjchem-1598	165	8	journal	journal	PROPN
eurjchem-1598	165	9	of	of	ADP
eurjchem-1598	165	10	chemistry	chemistry	NOUN
eurjchem-1598	165	11	8	8	NUM
eurjchem-1598	165	12	(	(	PUNCT
eurjchem-1598	165	13	3	3	NUM
eurjchem-1598	165	14	)	)	PUNCT
eurjchem-1598	165	15	(	(	PUNCT
eurjchem-1598	165	16	2017	2017	NUM
eurjchem-1598	165	17	)	)	PUNCT
eurjchem-1598	165	18	252‐257	252‐257	NOUN
eurjchem-1598	165	19	table	table	NOUN
eurjchem-1598	165	20	2	2	NUM
eurjchem-1598	165	21	.	.	NUM
eurjchem-1598	165	22	selected	select	VERB
eurjchem-1598	165	23	bond	bond	NOUN
eurjchem-1598	165	24	lengths	length	NOUN
eurjchem-1598	165	25	and	and	CCONJ
eurjchem-1598	165	26	angles	angle	NOUN
eurjchem-1598	165	27	for	for	ADP
eurjchem-1598	165	28	ligand	ligand	NOUN
eurjchem-1598	165	29	and	and	CCONJ
eurjchem-1598	165	30	(	(	PUNCT
eurjchem-1598	165	31	cd	cd	PROPN
eurjchem-1598	165	32	,	,	PUNCT
eurjchem-1598	165	33	cu	cu	PROPN
eurjchem-1598	165	34	and	and	CCONJ
eurjchem-1598	165	35	zn	zn	NUM
eurjchem-1598	165	36	)	)	PUNCT
eurjchem-1598	165	37	complexes	complex	NOUN
eurjchem-1598	165	38	from	from	ADP
eurjchem-1598	165	39	the	the	DET
eurjchem-1598	165	40	b3lyp	b3lyp	PROPN
eurjchem-1598	165	41	and	and	CCONJ
eurjchem-1598	165	42	(	(	PUNCT
eurjchem-1598	165	43	b3lyp	b3lyp	X
eurjchem-1598	165	44	/	/	SYM
eurjchem-1598	165	45	lanl2dz/6‐311+g(d	lanl2dz/6‐311+g(d	PROPN
eurjchem-1598	165	46	,	,	PUNCT
eurjchem-1598	165	47	p	p	NOUN
eurjchem-1598	165	48	)	)	PUNCT
eurjchem-1598	165	49	basis	basis	NOUN
eurjchem-1598	165	50	set	set	NOUN
eurjchem-1598	165	51	)	)	PUNCT
eurjchem-1598	165	52	calculations	calculation	NOUN
eurjchem-1598	165	53	.	.	PUNCT
eurjchem-1598	166	1	parameters	parameter	NOUN
eurjchem-1598	166	2	[	[	X
eurjchem-1598	166	3	cd(l).h2o.ch3coo	cd(l).h2o.ch3coo	X
eurjchem-1598	166	4	]	]	X
eurjchem-1598	167	1	[	[	X
eurjchem-1598	167	2	cu(l).h2o.ch3coo].h2o	cu(l).h2o.ch3coo].h2o	X
eurjchem-1598	167	3	[	[	X
eurjchem-1598	167	4	zn(l).h2o.ch3coo	zn(l).h2o.ch3coo	X
eurjchem-1598	167	5	]	]	X
eurjchem-1598	167	6	l	l	NOUN
eurjchem-1598	167	7	calc	calc	NOUN
eurjchem-1598	167	8	.	.	PUNCT
eurjchem-1598	168	1	exp	exp	PROPN
eurjchem-1598	168	2	.	.	PUNCT
eurjchem-1598	168	3	calc	calc	PROPN
eurjchem-1598	168	4	.	.	PUNCT
eurjchem-1598	169	1	exp	exp	PROPN
eurjchem-1598	169	2	.	.	PUNCT
eurjchem-1598	169	3	calc	calc	PROPN
eurjchem-1598	169	4	.	.	PUNCT
eurjchem-1598	170	1	exp	exp	NOUN
eurjchem-1598	170	2	.	.	PUNCT
eurjchem-1598	171	1	[	[	X
eurjchem-1598	171	2	22‐24	22‐24	NUM
eurjchem-1598	171	3	]	]	X
eurjchem-1598	171	4	calc	calc	NOUN
eurjchem-1598	171	5	.	.	PUNCT
eurjchem-1598	172	1	exp	exp	NOUN
eurjchem-1598	172	2	.	.	PUNCT
eurjchem-1598	173	1	bond	bond	NOUN
eurjchem-1598	173	2	lengths	length	NOUN
eurjchem-1598	173	3	(	(	PUNCT
eurjchem-1598	173	4	å	å	NOUN
eurjchem-1598	173	5	)	)	PUNCT
eurjchem-1598	173	6	m‐n25	m‐n25	PROPN
eurjchem-1598	173	7	2.242	2.242	NUM
eurjchem-1598	173	8	2.226	2.226	NUM
eurjchem-1598	173	9	1.916	1.916	NUM
eurjchem-1598	173	10	1.982	1.982	NUM
eurjchem-1598	173	11	2.023	2.023	NUM
eurjchem-1598	173	12	2.037	2.037	NUM
eurjchem-1598	173	13	‐	‐	NOUN
eurjchem-1598	173	14	‐	‐	ADP
eurjchem-1598	173	15	m‐n13	m‐n13	PROPN
eurjchem-1598	173	16	3.503	3.503	NUM
eurjchem-1598	173	17	‐	‐	VERB
eurjchem-1598	173	18	4.515	4.515	NUM
eurjchem-1598	173	19	‐	‐	NOUN
eurjchem-1598	173	20	3.581	3.581	NUM
eurjchem-1598	173	21	‐	‐	NOUN
eurjchem-1598	173	22	‐	‐	ADV
eurjchem-1598	173	23	‐	‐	ADV
eurjchem-1598	173	24	m‐o37	m‐o37	NOUN
eurjchem-1598	173	25	2.165	2.165	NUM
eurjchem-1598	173	26	‐	‐	NOUN
eurjchem-1598	173	27	1.991	1.991	NUM
eurjchem-1598	173	28	‐	‐	NOUN
eurjchem-1598	173	29	2.122	2.122	NUM
eurjchem-1598	173	30	2.111	2.111	NUM
eurjchem-1598	173	31	‐	‐	NOUN
eurjchem-1598	173	32	‐	‐	ADV
eurjchem-1598	173	33	m‐o32	m‐o32	NOUN
eurjchem-1598	173	34	2.200	2.200	NUM
eurjchem-1598	173	35	‐	‐	NOUN
eurjchem-1598	173	36	1.982	1.982	NUM
eurjchem-1598	173	37	‐	‐	NOUN
eurjchem-1598	173	38	2.025	2.025	NUM
eurjchem-1598	173	39	‐	‐	NOUN
eurjchem-1598	173	40	‐	‐	ADV
eurjchem-1598	173	41	‐	‐	ADP
eurjchem-1598	173	42	n25‐c26	n25‐c26	NOUN
eurjchem-1598	173	43	1.368	1.368	NUM
eurjchem-1598	173	44	1.365	1.365	NUM
eurjchem-1598	173	45	1.382	1.382	NUM
eurjchem-1598	173	46	1.368	1.368	NUM
eurjchem-1598	173	47	1.368	1.368	NUM
eurjchem-1598	173	48	1.370	1.370	NUM
eurjchem-1598	173	49	1.317	1.317	NUM
eurjchem-1598	173	50	‐	‐	NOUN
eurjchem-1598	173	51	n25‐c14	n25‐c14	ADP
eurjchem-1598	173	52	1.381	1.381	NUM
eurjchem-1598	173	53	1.367	1.367	NUM
eurjchem-1598	173	54	1.397	1.397	NUM
eurjchem-1598	173	55	1.367	1.367	NUM
eurjchem-1598	173	56	1.389	1.389	NUM
eurjchem-1598	173	57	1.360	1.360	NUM
eurjchem-1598	173	58	1.383	1.383	NUM
eurjchem-1598	173	59	‐	‐	NOUN
eurjchem-1598	173	60	n13‐c12	n13‐c12	PROPN
eurjchem-1598	173	61	1.367	1.367	NUM
eurjchem-1598	173	62	1.325	1.325	NUM
eurjchem-1598	173	63	1.332	1.332	NUM
eurjchem-1598	173	64	1.329	1.329	NUM
eurjchem-1598	173	65	1.371	1.371	NUM
eurjchem-1598	173	66	1.320	1.320	NUM
eurjchem-1598	173	67	1.372	1.372	NUM
eurjchem-1598	173	68	‐	‐	NOUN
eurjchem-1598	173	69	c11‐c26	c11‐c26	PROPN
eurjchem-1598	173	70	1.432	1.432	NUM
eurjchem-1598	173	71	‐	‐	NOUN
eurjchem-1598	173	72	1.412	1.412	NUM
eurjchem-1598	173	73	‐	‐	NOUN
eurjchem-1598	173	74	1.433	1.433	NUM
eurjchem-1598	173	75	‐	‐	NOUN
eurjchem-1598	173	76	1.450	1.450	NUM
eurjchem-1598	173	77	‐	‐	NOUN
eurjchem-1598	173	78	c11‐c12	c11‐c12	NOUN
eurjchem-1598	173	79	1.455	1.455	NUM
eurjchem-1598	173	80	‐	‐	NOUN
eurjchem-1598	173	81	1.461	1.461	NUM
eurjchem-1598	173	82	‐	‐	NOUN
eurjchem-1598	173	83	1.421	1.421	NUM
eurjchem-1598	173	84	‐	‐	NOUN
eurjchem-1598	173	85	1.376	1.376	NUM
eurjchem-1598	173	86	‐	‐	ADJ
eurjchem-1598	173	87	c11‐c3	c11‐c3	NOUN
eurjchem-1598	173	88	1.436	1.436	NUM
eurjchem-1598	173	89	‐	‐	ADP
eurjchem-1598	173	90	1.462	1.462	NUM
eurjchem-1598	173	91	‐	‐	NOUN
eurjchem-1598	173	92	1.451	1.451	NUM
eurjchem-1598	173	93	‐	‐	NOUN
eurjchem-1598	173	94	1.447	1.447	NUM
eurjchem-1598	173	95	‐	‐	ADJ
eurjchem-1598	173	96	bond	bond	NOUN
eurjchem-1598	173	97	angle	angle	NOUN
eurjchem-1598	173	98	(	(	PUNCT
eurjchem-1598	173	99	°	°	NOUN
eurjchem-1598	173	100	)	)	PUNCT
eurjchem-1598	173	101	c14‐n25‐m	c14‐n25‐m	ADP
eurjchem-1598	173	102	146.23	146.23	NUM
eurjchem-1598	173	103	133.60	133.60	NUM
eurjchem-1598	173	104	122.56	122.56	NUM
eurjchem-1598	173	105	131.80	131.80	NUM
eurjchem-1598	173	106	133.13	133.13	NUM
eurjchem-1598	173	107	130.30	130.30	NUM
eurjchem-1598	173	108	‐	‐	NOUN
eurjchem-1598	173	109	‐	‐	PUNCT
eurjchem-1598	173	110	c26‐n25‐m	c26‐n25‐m	NOUN
eurjchem-1598	173	111	104.94	104.94	NUM
eurjchem-1598	173	112	119.20	119.20	NUM
eurjchem-1598	173	113	130.36	130.36	NUM
eurjchem-1598	173	114	117.50	117.50	NUM
eurjchem-1598	173	115	119.06	119.06	NUM
eurjchem-1598	173	116	121.10	121.10	NUM
eurjchem-1598	173	117	‐	‐	NOUN
eurjchem-1598	173	118	‐	‐	ADJ
eurjchem-1598	173	119	c26‐n25‐c14	c26‐n25‐c14	NOUN
eurjchem-1598	173	120	107.30	107.30	NUM
eurjchem-1598	173	121	107.30	107.30	NUM
eurjchem-1598	173	122	107.009	107.009	NUM
eurjchem-1598	173	123	107.10	107.10	NUM
eurjchem-1598	173	124	107.46	107.46	NUM
eurjchem-1598	173	125	107.70	107.70	NUM
eurjchem-1598	173	126	105.60	105.60	NUM
eurjchem-1598	173	127	‐	‐	ADJ
eurjchem-1598	173	128	figure	figure	NOUN
eurjchem-1598	173	129	6	6	NUM
eurjchem-1598	173	130	.	.	PUNCT
eurjchem-1598	174	1	coats‐redfern	coats‐redfern	ADJ
eurjchem-1598	175	1	[	[	X
eurjchem-1598	175	2	cu(l)h2o.ch3coo].h2o	cu(l)h2o.ch3coo].h2o	VERB
eurjchem-1598	175	3	step1st	step1st	ADV
eurjchem-1598	175	4	..	..	PUNCT
eurjchem-1598	175	5	3.5	3.5	NUM
eurjchem-1598	175	6	.	.	PUNCT
eurjchem-1598	176	1	computational	computational	ADJ
eurjchem-1598	176	2	results	result	NOUN
eurjchem-1598	176	3	3.5.1	3.5.1	NUM
eurjchem-1598	176	4	.	.	PUNCT
eurjchem-1598	177	1	geometrical	geometrical	ADJ
eurjchem-1598	177	2	optimization	optimization	NOUN
eurjchem-1598	177	3	the	the	DET
eurjchem-1598	177	4	visualization	visualization	NOUN
eurjchem-1598	177	5	of	of	ADP
eurjchem-1598	177	6	the	the	DET
eurjchem-1598	177	7	optimized	optimize	VERB
eurjchem-1598	177	8	geometrical	geometrical	ADJ
eurjchem-1598	177	9	structure	structure	NOUN
eurjchem-1598	177	10	and	and	CCONJ
eurjchem-1598	177	11	atomic	atomic	ADJ
eurjchem-1598	177	12	labeling	labeling	NOUN
eurjchem-1598	177	13	of	of	ADP
eurjchem-1598	177	14	[	[	X
eurjchem-1598	177	15	cd(l)h2o.ch3coo	cd(l)h2o.ch3coo	NOUN
eurjchem-1598	177	16	]	]	X
eurjchem-1598	177	17	complex	complex	NOUN
eurjchem-1598	177	18	calculated	calculate	VERB
eurjchem-1598	177	19	by	by	ADP
eurjchem-1598	177	20	the	the	DET
eurjchem-1598	177	21	b3lyp	b3lyp	NOUN
eurjchem-1598	177	22	/	/	SYM
eurjchem-1598	177	23	lanl2dz	lanl2dz	NOUN
eurjchem-1598	177	24	method	method	VERB
eurjchem-1598	177	25	with	with	ADP
eurjchem-1598	177	26	6‐311+g(d	6‐311+g(d	NUM
eurjchem-1598	177	27	,	,	PUNCT
eurjchem-1598	177	28	p	p	NOUN
eurjchem-1598	177	29	)	)	PUNCT
eurjchem-1598	177	30	basis	basis	NOUN
eurjchem-1598	177	31	set	set	NOUN
eurjchem-1598	177	32	are	be	AUX
eurjchem-1598	177	33	given	give	VERB
eurjchem-1598	177	34	in	in	ADP
eurjchem-1598	177	35	figure	figure	NOUN
eurjchem-1598	177	36	7	7	NUM
eurjchem-1598	177	37	.	.	PUNCT
eurjchem-1598	177	38	figure	figure	NOUN
eurjchem-1598	177	39	7	7	NUM
eurjchem-1598	177	40	.	.	PUNCT
eurjchem-1598	177	41	optimized	optimize	VERB
eurjchem-1598	177	42	structures	structure	NOUN
eurjchem-1598	177	43	of	of	ADP
eurjchem-1598	177	44	[	[	X
eurjchem-1598	177	45	cd(l).h2o.ch3coo	cd(l).h2o.ch3coo	NOUN
eurjchem-1598	177	46	]	]	X
eurjchem-1598	177	47	complex	complex	NOUN
eurjchem-1598	177	48	calculated	calculate	VERB
eurjchem-1598	177	49	by	by	ADP
eurjchem-1598	177	50	the	the	DET
eurjchem-1598	177	51	b3lyp	b3lyp	NOUN
eurjchem-1598	177	52	/	/	SYM
eurjchem-1598	177	53	lanl2dz	lanl2dz	NOUN
eurjchem-1598	177	54	method	method	VERB
eurjchem-1598	177	55	with	with	ADP
eurjchem-1598	177	56	6‐311+g(d	6‐311+g(d	NUM
eurjchem-1598	177	57	,	,	PUNCT
eurjchem-1598	177	58	p	p	NOUN
eurjchem-1598	177	59	)	)	PUNCT
eurjchem-1598	177	60	basis	basis	NOUN
eurjchem-1598	177	61	set	set	VERB
eurjchem-1598	177	62	with	with	ADP
eurjchem-1598	177	63	atom	atom	NOUN
eurjchem-1598	177	64	numbering	numbering	NOUN
eurjchem-1598	177	65	.	.	PUNCT
eurjchem-1598	178	1	the	the	DET
eurjchem-1598	178	2	optimized	optimize	VERB
eurjchem-1598	178	3	geometric	geometric	ADJ
eurjchem-1598	178	4	parameters	parameter	NOUN
eurjchem-1598	178	5	are	be	AUX
eurjchem-1598	178	6	listed	list	VERB
eurjchem-1598	178	7	in	in	ADP
eurjchem-1598	178	8	table	table	NOUN
eurjchem-1598	178	9	2	2	NUM
eurjchem-1598	178	10	.	.	PUNCT
eurjchem-1598	179	1	the	the	DET
eurjchem-1598	179	2	crystallographic	crystallographic	ADJ
eurjchem-1598	179	3	structures	structure	NOUN
eurjchem-1598	179	4	of	of	ADP
eurjchem-1598	179	5	2‐(1h‐indol‐3‐yl)‐5‐methyl‐	2‐(1h‐indol‐3‐yl)‐5‐methyl‐	PROPN
eurjchem-1598	179	6	1h‐benzo[d]imidazole	1h‐benzo[d]imidazole	NOUN
eurjchem-1598	179	7	and	and	CCONJ
eurjchem-1598	179	8	their	their	PRON
eurjchem-1598	179	9	cu(ii	cu(ii	PROPN
eurjchem-1598	179	10	)	)	PUNCT
eurjchem-1598	179	11	,	,	PUNCT
eurjchem-1598	179	12	zn(ii	zn(ii	NUM
eurjchem-1598	179	13	)	)	PUNCT
eurjchem-1598	179	14	and	and	CCONJ
eurjchem-1598	179	15	cd(ii	cd(ii	PROPN
eurjchem-1598	179	16	)	)	PUNCT
eurjchem-1598	179	17	comp‐	comp‐	NOUN
eurjchem-1598	179	18	lexes	lexe	NOUN
eurjchem-1598	179	19	is	be	AUX
eurjchem-1598	179	20	not	not	PART
eurjchem-1598	179	21	available	available	ADJ
eurjchem-1598	179	22	in	in	ADP
eurjchem-1598	179	23	the	the	DET
eurjchem-1598	179	24	literature	literature	NOUN
eurjchem-1598	179	25	,	,	PUNCT
eurjchem-1598	179	26	therefore	therefore	ADV
eurjchem-1598	179	27	we	we	PRON
eurjchem-1598	179	28	compared	compare	VERB
eurjchem-1598	179	29	some	some	DET
eurjchem-1598	179	30	bond	bond	NOUN
eurjchem-1598	179	31	lengths	length	NOUN
eurjchem-1598	179	32	and	and	CCONJ
eurjchem-1598	179	33	bond	bond	NOUN
eurjchem-1598	179	34	angles	angle	NOUN
eurjchem-1598	179	35	with	with	ADP
eurjchem-1598	179	36	x‐ray	x‐ray	PROPN
eurjchem-1598	179	37	diffraction	diffraction	NOUN
eurjchem-1598	179	38	data	datum	NOUN
eurjchem-1598	179	39	of	of	ADP
eurjchem-1598	179	40	m‐n	m‐n	PROPN
eurjchem-1598	179	41	and	and	CCONJ
eurjchem-1598	179	42	n‐c	n‐c	PROPN
eurjchem-1598	179	43	as	as	ADP
eurjchem-1598	179	44	a	a	DET
eurjchem-1598	179	45	general	general	NOUN
eurjchem-1598	179	46	.	.	PUNCT
eurjchem-1598	180	1	the	the	DET
eurjchem-1598	180	2	optimized	optimize	VERB
eurjchem-1598	180	3	bond	bond	NOUN
eurjchem-1598	180	4	lengths	length	NOUN
eurjchem-1598	180	5	and	and	CCONJ
eurjchem-1598	180	6	bond	bond	NOUN
eurjchem-1598	180	7	angles	angle	NOUN
eurjchem-1598	180	8	of	of	ADP
eurjchem-1598	180	9	title	title	NOUN
eurjchem-1598	180	10	ligand	ligand	NOUN
eurjchem-1598	180	11	and	and	CCONJ
eurjchem-1598	180	12	complexes	complex	NOUN
eurjchem-1598	180	13	are	be	AUX
eurjchem-1598	180	14	in	in	ADP
eurjchem-1598	180	15	good	good	ADJ
eurjchem-1598	180	16	agreement	agreement	NOUN
eurjchem-1598	180	17	with	with	ADP
eurjchem-1598	180	18	x‐ray	x‐ray	PROPN
eurjchem-1598	180	19	data	datum	NOUN
eurjchem-1598	180	20	[	[	X
eurjchem-1598	180	21	22‐24	22‐24	NOUN
eurjchem-1598	180	22	]	]	X
eurjchem-1598	180	23	.	.	PUNCT
eurjchem-1598	181	1	n25‐c26	n25‐c26	NOUN
eurjchem-1598	181	2	in	in	ADP
eurjchem-1598	181	3	l‐zn	l‐zn	NOUN
eurjchem-1598	181	4	complex	complex	NOUN
eurjchem-1598	181	5	is	be	AUX
eurjchem-1598	181	6	shorter	short	ADJ
eurjchem-1598	181	7	and	and	CCONJ
eurjchem-1598	181	8	c25‐n14	c25‐n14	NOUN
eurjchem-1598	181	9	is	be	AUX
eurjchem-1598	181	10	longer	long	ADJ
eurjchem-1598	181	11	than	than	SCONJ
eurjchem-1598	181	12	as	as	SCONJ
eurjchem-1598	181	13	expected	expect	VERB
eurjchem-1598	181	14	(	(	PUNCT
eurjchem-1598	181	15	1.368	1.368	NUM
eurjchem-1598	181	16	and	and	CCONJ
eurjchem-1598	181	17	1.389	1.389	NUM
eurjchem-1598	181	18	å	å	NOUN
eurjchem-1598	181	19	,	,	PUNCT
eurjchem-1598	181	20	respectively	respectively	ADV
eurjchem-1598	181	21	)	)	PUNCT
eurjchem-1598	181	22	.	.	PUNCT
eurjchem-1598	182	1	the	the	DET
eurjchem-1598	182	2	angles	angle	NOUN
eurjchem-1598	182	3	c14‐n25‐m	c14‐n25‐m	PROPN
eurjchem-1598	182	4	and	and	CCONJ
eurjchem-1598	182	5	c26‐n25	c26‐n25	PROPN
eurjchem-1598	182	6	were	be	AUX
eurjchem-1598	182	7	calculated	calculate	VERB
eurjchem-1598	182	8	as	as	ADP
eurjchem-1598	182	9	146.23	146.23	NUM
eurjchem-1598	182	10	°	°	NUM
eurjchem-1598	182	11	and	and	CCONJ
eurjchem-1598	182	12	104.94	104.94	NUM
eurjchem-1598	182	13	°	°	NOUN
eurjchem-1598	182	14	for	for	ADP
eurjchem-1598	182	15	cd	cd	NOUN
eurjchem-1598	182	16	complex	complex	NOUN
eurjchem-1598	182	17	,	,	PUNCT
eurjchem-1598	182	18	while	while	SCONJ
eurjchem-1598	182	19	the	the	DET
eurjchem-1598	182	20	corresponding	correspond	VERB
eurjchem-1598	182	21	angles	angle	NOUN
eurjchem-1598	182	22	for	for	ADP
eurjchem-1598	182	23	cu	cu	PROPN
eurjchem-1598	182	24	and	and	CCONJ
eurjchem-1598	182	25	zn	zn	PROPN
eurjchem-1598	182	26	complexes	complex	NOUN
eurjchem-1598	182	27	are	be	AUX
eurjchem-1598	182	28	122.56	122.56	NUM
eurjchem-1598	182	29	°	°	NUM
eurjchem-1598	182	30	and	and	CCONJ
eurjchem-1598	182	31	130.36	130.36	NUM
eurjchem-1598	182	32	°	°	NOUN
eurjchem-1598	182	33	and	and	CCONJ
eurjchem-1598	182	34	133.13	133.13	NUM
eurjchem-1598	182	35	°	°	NOUN
eurjchem-1598	182	36	,	,	PUNCT
eurjchem-1598	182	37	119.06	119.06	NUM
eurjchem-1598	182	38	°	°	NOUN
eurjchem-1598	182	39	,	,	PUNCT
eurjchem-1598	182	40	respectively	respectively	ADV
eurjchem-1598	182	41	.	.	PUNCT
eurjchem-1598	183	1	3.5.2	3.5.2	X
eurjchem-1598	183	2	.	.	PUNCT
eurjchem-1598	183	3	mulliken	mulliken	ADJ
eurjchem-1598	183	4	population	population	NOUN
eurjchem-1598	183	5	analysis	analysis	NOUN
eurjchem-1598	183	6	dipole	dipole	NOUN
eurjchem-1598	183	7	moment	moment	NOUN
eurjchem-1598	183	8	,	,	PUNCT
eurjchem-1598	183	9	molecular	molecular	ADJ
eurjchem-1598	183	10	polarizability	polarizability	NOUN
eurjchem-1598	183	11	and	and	CCONJ
eurjchem-1598	183	12	bond	bond	NOUN
eurjchem-1598	183	13	proper‐	proper‐	NOUN
eurjchem-1598	183	14	ties	tie	NOUN
eurjchem-1598	183	15	are	be	AUX
eurjchem-1598	183	16	affected	affect	VERB
eurjchem-1598	183	17	by	by	ADP
eurjchem-1598	183	18	atomic	atomic	ADJ
eurjchem-1598	183	19	charges	charge	NOUN
eurjchem-1598	183	20	,	,	PUNCT
eurjchem-1598	183	21	therefore	therefore	ADV
eurjchem-1598	183	22	,	,	PUNCT
eurjchem-1598	183	23	the	the	DET
eurjchem-1598	183	24	mulliken	mulliken	PROPN
eurjchem-1598	183	25	atomic	atomic	ADJ
eurjchem-1598	183	26	charge	charge	NOUN
eurjchem-1598	183	27	calculation	calculation	NOUN
eurjchem-1598	183	28	has	have	VERB
eurjchem-1598	183	29	an	an	DET
eurjchem-1598	183	30	important	important	ADJ
eurjchem-1598	183	31	role	role	NOUN
eurjchem-1598	183	32	in	in	ADP
eurjchem-1598	183	33	quantum	quantum	ADJ
eurjchem-1598	183	34	chemistry	chemistry	NOUN
eurjchem-1598	183	35	[	[	X
eurjchem-1598	183	36	25‐27	25‐27	NOUN
eurjchem-1598	183	37	]	]	PUNCT
eurjchem-1598	183	38	.	.	PUNCT
eurjchem-1598	184	1	mulliken	mulliken	ADJ
eurjchem-1598	184	2	population	population	NOUN
eurjchem-1598	184	3	analysis	analysis	NOUN
eurjchem-1598	184	4	was	be	AUX
eurjchem-1598	184	5	perfor‐	perfor‐	NOUN
eurjchem-1598	184	6	med	med	ADJ
eurjchem-1598	184	7	using	use	VERB
eurjchem-1598	184	8	dft	dft	PROPN
eurjchem-1598	184	9	/	/	SYM
eurjchem-1598	184	10	b3lyp	b3lyp	PROPN
eurjchem-1598	184	11	calculation	calculation	NOUN
eurjchem-1598	184	12	method	method	NOUN
eurjchem-1598	184	13	with	with	ADP
eurjchem-1598	184	14	6‐311+g(d	6‐311+g(d	NUM
eurjchem-1598	184	15	,	,	PUNCT
eurjchem-1598	184	16	p	p	NOUN
eurjchem-1598	184	17	)	)	PUNCT
eurjchem-1598	184	18	basis	basis	NOUN
eurjchem-1598	184	19	set	set	NOUN
eurjchem-1598	184	20	and	and	CCONJ
eurjchem-1598	184	21	lanl2dz	lanl2dz	ADJ
eurjchem-1598	184	22	basis	basis	NOUN
eurjchem-1598	184	23	set	set	NOUN
eurjchem-1598	184	24	for	for	ADP
eurjchem-1598	184	25	cu(ii	cu(ii	PROPN
eurjchem-1598	184	26	)	)	PUNCT
eurjchem-1598	184	27	,	,	PUNCT
eurjchem-1598	184	28	zn(ii	zn(ii	NUM
eurjchem-1598	184	29	)	)	PUNCT
eurjchem-1598	184	30	and	and	CCONJ
eurjchem-1598	184	31	cd(ii	cd(ii	ADJ
eurjchem-1598	184	32	)	)	PUNCT
eurjchem-1598	184	33	metal	metal	NOUN
eurjchem-1598	184	34	complexes	complex	NOUN
eurjchem-1598	184	35	.	.	PUNCT
eurjchem-1598	185	1	graphical	graphical	ADJ
eurjchem-1598	185	2	reorientations	reorientation	NOUN
eurjchem-1598	185	3	of	of	ADP
eurjchem-1598	185	4	mulliken	mulliken	NOUN
eurjchem-1598	185	5	charge	charge	NOUN
eurjchem-1598	185	6	distributions	distribution	NOUN
eurjchem-1598	185	7	of	of	ADP
eurjchem-1598	185	8	ligand	ligand	NOUN
eurjchem-1598	185	9	and	and	CCONJ
eurjchem-1598	185	10	l‐cd	l‐cd	NOUN
eurjchem-1598	185	11	,	,	PUNCT
eurjchem-1598	185	12	l‐cu	l‐cu	NOUN
eurjchem-1598	185	13	,	,	PUNCT
eurjchem-1598	185	14	l‐zn	l‐zn	NOUN
eurjchem-1598	185	15	complexes	complex	NOUN
eurjchem-1598	185	16	is	be	AUX
eurjchem-1598	185	17	shown	show	VERB
eurjchem-1598	185	18	in	in	ADP
eurjchem-1598	185	19	figure	figure	NOUN
eurjchem-1598	185	20	8	8	NUM
eurjchem-1598	185	21	.	.	PUNCT
eurjchem-1598	186	1	as	as	SCONJ
eurjchem-1598	186	2	can	can	AUX
eurjchem-1598	186	3	be	be	AUX
eurjchem-1598	186	4	seen	see	VERB
eurjchem-1598	186	5	in	in	ADP
eurjchem-1598	186	6	table	table	NOUN
eurjchem-1598	186	7	3	3	NUM
eurjchem-1598	186	8	,	,	PUNCT
eurjchem-1598	186	9	all	all	DET
eurjchem-1598	186	10	the	the	DET
eurjchem-1598	186	11	hydrogen	hydrogen	NOUN
eurjchem-1598	186	12	atoms	atom	NOUN
eurjchem-1598	186	13	have	have	VERB
eurjchem-1598	186	14	a	a	DET
eurjchem-1598	186	15	net	net	ADJ
eurjchem-1598	186	16	positive	positive	ADJ
eurjchem-1598	186	17	charge	charge	NOUN
eurjchem-1598	186	18	.	.	PUNCT
eurjchem-1598	187	1	the	the	DET
eurjchem-1598	187	2	obtained	obtain	VERB
eurjchem-1598	187	3	atomic	atomic	ADJ
eurjchem-1598	187	4	charge	charge	NOUN
eurjchem-1598	187	5	shows	show	VERB
eurjchem-1598	187	6	that	that	SCONJ
eurjchem-1598	187	7	the	the	DET
eurjchem-1598	187	8	cu	cu	PROPN
eurjchem-1598	187	9	atom	atom	NOUN
eurjchem-1598	187	10	of	of	ADP
eurjchem-1598	187	11	[	[	NOUN
eurjchem-1598	187	12	cu(l)(h2o)(ch3coo)].h2o	cu(l)(h2o)(ch3coo)].h2o	NOUN
eurjchem-1598	187	13	has	have	VERB
eurjchem-1598	187	14	lower	low	ADJ
eurjchem-1598	187	15	positive	positive	ADJ
eurjchem-1598	187	16	atomic	atomic	ADJ
eurjchem-1598	187	17	charge	charge	NOUN
eurjchem-1598	187	18	(	(	PUNCT
eurjchem-1598	187	19	0.494	0.494	NUM
eurjchem-1598	187	20	)	)	PUNCT
eurjchem-1598	187	21	than	than	ADP
eurjchem-1598	187	22	the	the	DET
eurjchem-1598	187	23	cd	cd	PROPN
eurjchem-1598	187	24	and	and	CCONJ
eurjchem-1598	187	25	zn	zn	NUM
eurjchem-1598	187	26	atoms	atom	NOUN
eurjchem-1598	187	27	in	in	ADP
eurjchem-1598	187	28	the	the	DET
eurjchem-1598	187	29	other	other	ADJ
eurjchem-1598	187	30	studied	studied	ADJ
eurjchem-1598	187	31	complexes	complex	NOUN
eurjchem-1598	187	32	[	[	PUNCT
eurjchem-1598	187	33	cd(l)(h2o)(ch3coo)].h2o	cd(l)(h2o)(ch3coo)].h2o	NOUN
eurjchem-1598	187	34	and	and	CCONJ
eurjchem-1598	187	35	cd(l)(h2o)(ch3coo)].h2o	cd(l)(h2o)(ch3coo)].h2o	NOUN
eurjchem-1598	187	36	which	which	PRON
eurjchem-1598	187	37	obtained	obtain	VERB
eurjchem-1598	187	38	1.032	1.032	NUM
eurjchem-1598	187	39	and	and	CCONJ
eurjchem-1598	187	40	1.033	1.033	NUM
eurjchem-1598	187	41	,	,	PUNCT
eurjchem-1598	187	42	respectively	respectively	ADV
eurjchem-1598	187	43	.	.	PUNCT
eurjchem-1598	188	1	the	the	DET
eurjchem-1598	188	2	n23	n23	PROPN
eurjchem-1598	188	3	atom	atom	NOUN
eurjchem-1598	188	4	has	have	VERB
eurjchem-1598	188	5	negative	negative	ADJ
eurjchem-1598	188	6	atomic	atomic	ADJ
eurjchem-1598	188	7	charge	charge	NOUN
eurjchem-1598	188	8	‐0.067	‐0.067	NOUN
eurjchem-1598	188	9	,	,	PUNCT
eurjchem-1598	188	10	‐0.416	‐0.416	NOUN
eurjchem-1598	188	11	,	,	PUNCT
eurjchem-1598	188	12	‐0.428	‐0.428	NOUN
eurjchem-1598	188	13	and	and	CCONJ
eurjchem-1598	188	14	‐0.439	‐0.439	NOUN
eurjchem-1598	188	15	of	of	ADP
eurjchem-1598	188	16	ligand	ligand	NOUN
eurjchem-1598	188	17	,	,	PUNCT
eurjchem-1598	188	18	zn	zn	PROPN
eurjchem-1598	188	19	,	,	PUNCT
eurjchem-1598	188	20	cd	cd	PROPN
eurjchem-1598	188	21	and	and	CCONJ
eurjchem-1598	188	22	cu	cu	PROPN
eurjchem-1598	188	23	complexes	complex	NOUN
eurjchem-1598	188	24	,	,	PUNCT
eurjchem-1598	188	25	respectively	respectively	ADV
eurjchem-1598	188	26	.	.	PUNCT
eurjchem-1598	189	1	figure	figure	NOUN
eurjchem-1598	189	2	8	8	NUM
eurjchem-1598	189	3	.	.	PUNCT
eurjchem-1598	189	4	graphical	graphical	ADJ
eurjchem-1598	189	5	reorientations	reorientation	NOUN
eurjchem-1598	189	6	of	of	ADP
eurjchem-1598	189	7	mulliken	mulliken	NOUN
eurjchem-1598	189	8	charge	charge	NOUN
eurjchem-1598	189	9	distributions	distribution	NOUN
eurjchem-1598	189	10	of	of	ADP
eurjchem-1598	189	11	ligand	ligand	ADJ
eurjchem-1598	189	12	l	l	PROPN
eurjchem-1598	189	13	and	and	CCONJ
eurjchem-1598	189	14	lcd	lcd	PROPN
eurjchem-1598	189	15	,	,	PUNCT
eurjchem-1598	189	16	lcu	lcu	PROPN
eurjchem-1598	189	17	,	,	PUNCT
eurjchem-1598	189	18	lzn	lzn	NOUN
eurjchem-1598	189	19	complexes	complex	NOUN
eurjchem-1598	189	20	.	.	PUNCT
eurjchem-1598	190	1	3.5.3	3.5.3	NUM
eurjchem-1598	190	2	.	.	PUNCT
eurjchem-1598	190	3	total	total	ADJ
eurjchem-1598	190	4	energies	energy	NOUN
eurjchem-1598	190	5	,	,	PUNCT
eurjchem-1598	190	6	dipole	dipole	NOUN
eurjchem-1598	190	7	moments	moment	NOUN
eurjchem-1598	190	8	and	and	CCONJ
eurjchem-1598	190	9	molecular	molecular	ADJ
eurjchem-1598	190	10	orbitals	orbital	NOUN
eurjchem-1598	190	11	analysis	analysis	VERB
eurjchem-1598	190	12	the	the	DET
eurjchem-1598	190	13	homo	homo	NOUN
eurjchem-1598	190	14	energy	energy	NOUN
eurjchem-1598	190	15	represents	represent	VERB
eurjchem-1598	190	16	the	the	DET
eurjchem-1598	190	17	ability	ability	NOUN
eurjchem-1598	190	18	to	to	PART
eurjchem-1598	190	19	donate	donate	VERB
eurjchem-1598	190	20	an	an	DET
eurjchem-1598	190	21	electron	electron	NOUN
eurjchem-1598	190	22	,	,	PUNCT
eurjchem-1598	190	23	lumo	lumo	NOUN
eurjchem-1598	190	24	energy	energy	NOUN
eurjchem-1598	190	25	as	as	ADP
eurjchem-1598	190	26	an	an	DET
eurjchem-1598	190	27	electron	electron	NOUN
eurjchem-1598	190	28	acceptor	acceptor	NOUN
eurjchem-1598	190	29	represents	represent	VERB
eurjchem-1598	190	30	the	the	DET
eurjchem-1598	190	31	ability	ability	NOUN
eurjchem-1598	190	32	to	to	PART
eurjchem-1598	190	33	obtain	obtain	VERB
eurjchem-1598	190	34	an	an	DET
eurjchem-1598	190	35	electron	electron	NOUN
eurjchem-1598	190	36	[	[	X
eurjchem-1598	190	37	28	28	NUM
eurjchem-1598	190	38	]	]	PUNCT
eurjchem-1598	190	39	.	.	PUNCT
eurjchem-1598	191	1	the	the	DET
eurjchem-1598	191	2	homo‐lumo	homo‐lumo	ADJ
eurjchem-1598	191	3	energy	energy	NOUN
eurjchem-1598	191	4	calculations	calculation	NOUN
eurjchem-1598	191	5	of	of	ADP
eurjchem-1598	191	6	the	the	DET
eurjchem-1598	191	7	title	title	NOUN
eurjchem-1598	191	8	compounds	compound	NOUN
eurjchem-1598	191	9	were	be	AUX
eurjchem-1598	191	10	performed	perform	VERB
eurjchem-1598	191	11	using	use	VERB
eurjchem-1598	191	12	dft	dft	PROPN
eurjchem-1598	191	13	/	/	SYM
eurjchem-1598	191	14	b3lyp	b3lyp	PROPN
eurjchem-1598	191	15	method	method	NOUN
eurjchem-1598	191	16	with	with	ADP
eurjchem-1598	191	17	6‐311+g(d	6‐311+g(d	NUM
eurjchem-1598	191	18	,	,	PUNCT
eurjchem-1598	191	19	p	p	NOUN
eurjchem-1598	191	20	)	)	PUNCT
eurjchem-1598	191	21	basis	basis	NOUN
eurjchem-1598	191	22	set	set	NOUN
eurjchem-1598	191	23	for	for	ADP
eurjchem-1598	191	24	the	the	DET
eurjchem-1598	191	25	ligand	ligand	NOUN
eurjchem-1598	191	26	and	and	CCONJ
eurjchem-1598	191	27	dft	dft	PROPN
eurjchem-1598	191	28	/	/	SYM
eurjchem-1598	191	29	b3lyp	b3lyp	PROPN
eurjchem-1598	191	30	methods	method	NOUN
eurjchem-1598	191	31	with	with	ADP
eurjchem-1598	191	32	lanl2dz	lanl2dz	NOUN
eurjchem-1598	191	33	basis	basis	NOUN
eurjchem-1598	191	34	sets	set	NOUN
eurjchem-1598	191	35	for	for	ADP
eurjchem-1598	191	36	its	its	PRON
eurjchem-1598	191	37	cd	cd	PROPN
eurjchem-1598	191	38	,	,	PUNCT
eurjchem-1598	191	39	cu	cu	PROPN
eurjchem-1598	191	40	and	and	CCONJ
eurjchem-1598	191	41	zn	zn	PROPN
eurjchem-1598	191	42	complexes	complex	NOUN
eurjchem-1598	191	43	.	.	PUNCT
eurjchem-1598	192	1	furthermore	furthermore	ADV
eurjchem-1598	192	2	,	,	PUNCT
eurjchem-1598	192	3	the	the	DET
eurjchem-1598	192	4	orbital	orbital	ADJ
eurjchem-1598	192	5	shapes	shape	NOUN
eurjchem-1598	192	6	(	(	PUNCT
eurjchem-1598	192	7	homo‐	homo‐	NOUN
eurjchem-1598	192	8	lumo	lumo	PROPN
eurjchem-1598	192	9	)	)	PUNCT
eurjchem-1598	192	10	and	and	CCONJ
eurjchem-1598	192	11	the	the	DET
eurjchem-1598	192	12	energy	energy	NOUN
eurjchem-1598	192	13	gap	gap	NOUN
eurjchem-1598	192	14	between	between	ADP
eurjchem-1598	192	15	the	the	DET
eurjchem-1598	192	16	homo‐lumo	homo‐lumo	NOUN
eurjchem-1598	192	17	which	which	PRON
eurjchem-1598	192	18	is	be	AUX
eurjchem-1598	192	19	a	a	DET
eurjchem-1598	192	20	critical	critical	ADJ
eurjchem-1598	192	21	parameter	parameter	NOUN
eurjchem-1598	192	22	to	to	PART
eurjchem-1598	192	23	determine	determine	VERB
eurjchem-1598	192	24	molecular	molecular	ADJ
eurjchem-1598	192	25	electrical	electrical	ADJ
eurjchem-1598	192	26	transport	transport	NOUN
eurjchem-1598	192	27	properties	property	NOUN
eurjchem-1598	192	28	[	[	X
eurjchem-1598	192	29	29	29	NUM
eurjchem-1598	192	30	]	]	PUNCT
eurjchem-1598	192	31	were	be	AUX
eurjchem-1598	192	32	plotted	plot	VERB
eurjchem-1598	192	33	in	in	ADP
eurjchem-1598	192	34	3‐dimensional	3‐dimensional	PROPN
eurjchem-1598	192	35	(	(	PUNCT
eurjchem-1598	192	36	3d	3d	NOUN
eurjchem-1598	192	37	)	)	PUNCT
eurjchem-1598	192	38	by	by	ADP
eurjchem-1598	192	39	using	use	VERB
eurjchem-1598	192	40	at	at	ADP
eurjchem-1598	192	41	b3lyp/6‐311+g(d	b3lyp/6‐311+g(d	PROPN
eurjchem-1598	192	42	,	,	PUNCT
eurjchem-1598	192	43	p	p	NOUN
eurjchem-1598	192	44	)	)	PUNCT
eurjchem-1598	192	45	and	and	CCONJ
eurjchem-1598	192	46	b3lyp/	b3lyp/	NOUN
eurjchem-1598	192	47	lanl2dz	lanl2dz	NOUN
eurjchem-1598	192	48	levels	level	NOUN
eurjchem-1598	192	49	,	,	PUNCT
eurjchem-1598	192	50	respectively	respectively	ADV
eurjchem-1598	192	51	,	,	PUNCT
eurjchem-1598	192	52	are	be	AUX
eurjchem-1598	192	53	given	give	VERB
eurjchem-1598	192	54	in	in	ADP
eurjchem-1598	192	55	figure	figure	NOUN
eurjchem-1598	192	56	9	9	NUM
eurjchem-1598	192	57	.	.	PUNCT
eurjchem-1598	193	1	the	the	DET
eurjchem-1598	193	2	values	value	NOUN
eurjchem-1598	193	3	of	of	ADP
eurjchem-1598	193	4	the	the	DET
eurjchem-1598	193	5	calculated	calculated	ADJ
eurjchem-1598	193	6	energies	energy	NOUN
eurjchem-1598	193	7	,	,	PUNCT
eurjchem-1598	193	8	dipole	dipole	NOUN
eurjchem-1598	193	9	moment	moment	NOUN
eurjchem-1598	193	10	and	and	CCONJ
eurjchem-1598	193	11	frontier	frontier	NOUN
eurjchem-1598	193	12	molecular	molecular	ADJ
eurjchem-1598	193	13	orbital	orbital	ADJ
eurjchem-1598	193	14	energies	energy	NOUN
eurjchem-1598	193	15	of	of	ADP
eurjchem-1598	193	16	ligand	ligand	NOUN
eurjchem-1598	193	17	and	and	CCONJ
eurjchem-1598	193	18	cd	cd	PROPN
eurjchem-1598	193	19	,	,	PUNCT
eurjchem-1598	193	20	cu	cu	PROPN
eurjchem-1598	193	21	and	and	CCONJ
eurjchem-1598	193	22	zn	zn	PROPN
eurjchem-1598	193	23	complexes	complex	NOUN
eurjchem-1598	193	24	from	from	ADP
eurjchem-1598	193	25	the	the	DET
eurjchem-1598	193	26	b3lyp	b3lyp	PROPN
eurjchem-1598	193	27	and	and	CCONJ
eurjchem-1598	193	28	b3lyp	b3lyp	SYM
eurjchem-1598	193	29	/	/	SYM
eurjchem-1598	193	30	lanl2dz/6‐311+g(d	lanl2dz/6‐311+g(d	PROPN
eurjchem-1598	193	31	,	,	PUNCT
eurjchem-1598	193	32	p	p	NOUN
eurjchem-1598	193	33	)	)	PUNCT
eurjchem-1598	193	34	basis	basis	NOUN
eurjchem-1598	193	35	set	set	VERB
eurjchem-1598	193	36	calcula‐	calcula‐	NOUN
eurjchem-1598	193	37	tions	tion	NOUN
eurjchem-1598	193	38	are	be	AUX
eurjchem-1598	193	39	given	give	VERB
eurjchem-1598	193	40	in	in	ADP
eurjchem-1598	193	41	table	table	NOUN
eurjchem-1598	193	42	4	4	NUM
eurjchem-1598	193	43	.	.	PUNCT
eurjchem-1598	193	44	hadi	hadi	PROPN
eurjchem-1598	193	45	et	et	PROPN
eurjchem-1598	193	46	al	al	PROPN
eurjchem-1598	193	47	.	.	PUNCT
eurjchem-1598	193	48	/	/	SYM
eurjchem-1598	193	49	european	european	PROPN
eurjchem-1598	193	50	journal	journal	PROPN
eurjchem-1598	193	51	of	of	ADP
eurjchem-1598	193	52	chemistry	chemistry	NOUN
eurjchem-1598	193	53	8	8	NUM
eurjchem-1598	193	54	(	(	PUNCT
eurjchem-1598	193	55	3	3	NUM
eurjchem-1598	193	56	)	)	PUNCT
eurjchem-1598	193	57	(	(	PUNCT
eurjchem-1598	193	58	2017	2017	NUM
eurjchem-1598	193	59	)	)	PUNCT
eurjchem-1598	193	60	252‐257	252‐257	NOUN
eurjchem-1598	193	61	257	257	NUM
eurjchem-1598	193	62	table	table	NOUN
eurjchem-1598	193	63	3	3	NUM
eurjchem-1598	193	64	.	.	PUNCT
eurjchem-1598	194	1	the	the	DET
eurjchem-1598	194	2	mulliken	mulliken	PROPN
eurjchem-1598	194	3	atomic	atomic	ADJ
eurjchem-1598	194	4	charge	charge	NOUN
eurjchem-1598	194	5	distribution	distribution	NOUN
eurjchem-1598	194	6	of	of	ADP
eurjchem-1598	194	7	ligand	ligand	ADJ
eurjchem-1598	194	8	l	l	PROPN
eurjchem-1598	194	9	and	and	CCONJ
eurjchem-1598	194	10	lcd	lcd	PROPN
eurjchem-1598	194	11	,	,	PUNCT
eurjchem-1598	194	12	lcu	lcu	PROPN
eurjchem-1598	194	13	,	,	PUNCT
eurjchem-1598	194	14	lzn	lzn	NOUN
eurjchem-1598	194	15	complexes	complex	NOUN
eurjchem-1598	194	16	.	.	PUNCT
eurjchem-1598	195	1	atoms	atom	NOUN
eurjchem-1598	195	2	mulliken	mulliken	PROPN
eurjchem-1598	195	3	atomic	atomic	ADJ
eurjchem-1598	195	4	charges	charge	NOUN
eurjchem-1598	195	5	(	(	PUNCT
eurjchem-1598	195	6	q	q	NOUN
eurjchem-1598	195	7	/	/	SYM
eurjchem-1598	195	8	e	e	NOUN
eurjchem-1598	195	9	)	)	PUNCT
eurjchem-1598	195	10	atoms	atom	NOUN
eurjchem-1598	195	11	mulliken	mulliken	ADJ
eurjchem-1598	195	12	atomic	atomic	ADJ
eurjchem-1598	195	13	charges	charge	NOUN
eurjchem-1598	195	14	(	(	PUNCT
eurjchem-1598	195	15	q	q	NOUN
eurjchem-1598	195	16	/	/	SYM
eurjchem-1598	195	17	e	e	NOUN
eurjchem-1598	195	18	)	)	PUNCT
eurjchem-1598	195	19	l	l	NOUN
eurjchem-1598	195	20	lcd	lcd	NOUN
eurjchem-1598	195	21	lcu	lcu	PROPN
eurjchem-1598	195	22	lzn	lzn	PROPN
eurjchem-1598	195	23	l	l	PROPN
eurjchem-1598	195	24	lcd	lcd	PROPN
eurjchem-1598	195	25	lcu	lcu	PROPN
eurjchem-1598	195	26	lzn	lzn	NOUN
eurjchem-1598	195	27	1	1	NUM
eurjchem-1598	195	28	c	c	NOUN
eurjchem-1598	195	29	‐0.418	‐0.418	PROPN
eurjchem-1598	195	30	‐0.328	‐0.328	NOUN
eurjchem-1598	195	31	‐0.324	‐0.324	PROPN
eurjchem-1598	195	32	‐0.333	‐0.333	NOUN
eurjchem-1598	195	33	22	22	NUM
eurjchem-1598	195	34	h	h	NOUN
eurjchem-1598	195	35	0.104	0.104	NUM
eurjchem-1598	195	36	0.232	0.232	NUM
eurjchem-1598	195	37	0.233	0.233	NUM
eurjchem-1598	195	38	0.232	0.232	NUM
eurjchem-1598	195	39	2	2	NUM
eurjchem-1598	195	40	c	c	NOUN
eurjchem-1598	195	41	‐0.676	‐0.676	NOUN
eurjchem-1598	195	42	‐0.026	‐0.026	PROPN
eurjchem-1598	195	43	‐0.020	‐0.020	NOUN
eurjchem-1598	195	44	0.023	0.023	NUM
eurjchem-1598	195	45	23	23	NUM
eurjchem-1598	195	46	n	n	DET
eurjchem-1598	195	47	‐0.067	‐0.067	NOUN
eurjchem-1598	195	48	‐0.428	‐0.428	NOUN
eurjchem-1598	195	49	‐0.439	‐0.439	NOUN
eurjchem-1598	195	50	‐0.416	‐0.416	ADP
eurjchem-1598	195	51	3	3	NUM
eurjchem-1598	195	52	c	c	NOUN
eurjchem-1598	195	53	0.872	0.872	NUM
eurjchem-1598	195	54	0.197	0.197	NUM
eurjchem-1598	195	55	0.203	0.203	NUM
eurjchem-1598	195	56	0.224	0.224	NUM
eurjchem-1598	195	57	24	24	NUM
eurjchem-1598	195	58	h	h	NOUN
eurjchem-1598	195	59	0.266	0.266	NUM
eurjchem-1598	195	60	0.333	0.333	NUM
eurjchem-1598	195	61	0.326	0.326	NUM
eurjchem-1598	195	62	0.334	0.334	NUM
eurjchem-1598	195	63	4	4	NUM
eurjchem-1598	195	64	c	c	NOUN
eurjchem-1598	195	65	‐0.794	‐0.794	NOUN
eurjchem-1598	195	66	‐0.406	‐0.406	VERB
eurjchem-1598	195	67	‐0.339	‐0.339	PROPN
eurjchem-1598	195	68	‐0.411	‐0.411	NOUN
eurjchem-1598	195	69	25	25	NUM
eurjchem-1598	195	70	n	n	NUM
eurjchem-1598	195	71	‐0.146	‐0.146	PROPN
eurjchem-1598	195	72	‐0.393	‐0.393	NOUN
eurjchem-1598	195	73	‐0.393	‐0.393	NOUN
eurjchem-1598	195	74	‐0.481	‐0.481	NOUN
eurjchem-1598	195	75	5	5	NUM
eurjchem-1598	195	76	c	c	NOUN
eurjchem-1598	195	77	‐0.305	‐0.305	NOUN
eurjchem-1598	195	78	‐0.231	‐0.231	PROPN
eurjchem-1598	195	79	‐0.258	‐0.258	NOUN
eurjchem-1598	195	80	‐0.233	‐0.233	NOUN
eurjchem-1598	195	81	26	26	NUM
eurjchem-1598	195	82	c	c	NOUN
eurjchem-1598	195	83	‐0.189	‐0.189	NOUN
eurjchem-1598	195	84	0.238	0.238	NUM
eurjchem-1598	195	85	0.236	0.236	NUM
eurjchem-1598	195	86	0.250	0.250	NUM
eurjchem-1598	195	87	6	6	NUM
eurjchem-1598	195	88	c	c	NOUN
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eurjchem-1598	196	54	c	c	ADP
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eurjchem-1598	198	21	c	c	NOUN
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eurjchem-1598	207	2	.	.	PUNCT
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eurjchem-1598	208	2	.	.	PUNCT
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eurjchem-1598	209	2	,	,	PUNCT
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eurjchem-1598	209	4	)	)	PUNCT
eurjchem-1598	209	5	,	,	PUNCT
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eurjchem-1598	209	7	.	.	PUNCT
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eurjchem-1598	210	3	]	]	PUNCT
eurjchem-1598	210	4	.	.	PUNCT
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eurjchem-1598	211	2	,	,	PUNCT
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eurjchem-1598	211	4	;	;	PUNCT
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eurjchem-1598	211	6	,	,	PUNCT
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eurjchem-1598	214	2	,	,	PUNCT
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eurjchem-1598	214	4	)	)	PUNCT
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eurjchem-1598	214	8	.	.	PUNCT
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eurjchem-1598	215	3	]	]	PUNCT
eurjchem-1598	215	4	.	.	PUNCT
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eurjchem-1598	215	6	,	,	PUNCT
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eurjchem-1598	215	9	;	;	PUNCT
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eurjchem-1598	217	2	.	.	PROPN
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eurjchem-1598	217	4	,	,	PUNCT
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eurjchem-1598	218	3	]	]	PUNCT
eurjchem-1598	218	4	.	.	PUNCT
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eurjchem-1598	219	4	;	;	PUNCT
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eurjchem-1598	219	6	,	,	PUNCT
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eurjchem-1598	219	8	;	;	PUNCT
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eurjchem-1598	220	1	j.	j.	PROPN
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eurjchem-1598	220	3	.	.	PUNCT
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eurjchem-1598	220	7	,	,	PUNCT
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eurjchem-1598	220	9	)	)	PUNCT
eurjchem-1598	220	10	,	,	PUNCT
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eurjchem-1598	220	12	127	127	NUM
eurjchem-1598	220	13	.	.	PUNCT
eurjchem-1598	221	1	[	[	X
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eurjchem-1598	221	3	]	]	PUNCT
eurjchem-1598	221	4	.	.	PUNCT
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eurjchem-1598	221	6	,	,	PUNCT
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eurjchem-1598	221	9	;	;	PUNCT
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eurjchem-1598	221	11	,	,	PUNCT
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eurjchem-1598	221	13	;	;	PUNCT
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eurjchem-1598	221	15	,	,	PUNCT
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eurjchem-1598	221	22	.	.	PUNCT
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eurjchem-1598	222	4	.	.	PUNCT
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eurjchem-1598	223	4	,	,	PUNCT
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eurjchem-1598	223	6	)	)	PUNCT
eurjchem-1598	223	7	,	,	PUNCT
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eurjchem-1598	223	9	.	.	PUNCT
eurjchem-1598	224	1	[	[	X
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eurjchem-1598	224	3	]	]	PUNCT
eurjchem-1598	224	4	.	.	PUNCT
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eurjchem-1598	225	2	,	,	PUNCT
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eurjchem-1598	225	5	;	;	PUNCT
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eurjchem-1598	225	14	s.	s.	PROPN
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eurjchem-1598	225	17	.	.	PUNCT
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eurjchem-1598	226	2	.	.	PUNCT
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eurjchem-1598	226	4	,	,	PUNCT
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eurjchem-1598	226	6	,	,	PUNCT
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eurjchem-1598	226	8	.	.	PUNCT
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eurjchem-1598	227	3	]	]	PUNCT
eurjchem-1598	227	4	.	.	PUNCT
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eurjchem-1598	228	2	,	,	PUNCT
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eurjchem-1598	228	4	;	;	PUNCT
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eurjchem-1598	228	6	,	,	PUNCT
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eurjchem-1598	228	8	;	;	PUNCT
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eurjchem-1598	228	10	,	,	PUNCT
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eurjchem-1598	228	12	;	;	PUNCT
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eurjchem-1598	228	14	,	,	PUNCT
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eurjchem-1598	228	20	;	;	PUNCT
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eurjchem-1598	228	22	,	,	PUNCT
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eurjchem-1598	228	24	;	;	PUNCT
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eurjchem-1598	229	3	.	.	PROPN
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eurjchem-1598	229	5	.	.	PUNCT
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eurjchem-1598	230	2	,	,	PUNCT
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eurjchem-1598	230	5	,	,	PUNCT
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eurjchem-1598	231	4	.	.	PUNCT
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eurjchem-1598	232	5	;	;	PUNCT
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eurjchem-1598	232	17	.	.	PUNCT
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eurjchem-1598	233	2	.	.	PUNCT
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eurjchem-1598	234	2	.	.	PUNCT
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eurjchem-1598	235	2	,	,	PUNCT
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eurjchem-1598	235	7	.	.	PUNCT
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eurjchem-1598	236	3	]	]	PUNCT
eurjchem-1598	236	4	.	.	PUNCT
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eurjchem-1598	236	9	;	;	PUNCT
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eurjchem-1598	236	161	k.	k.	PROPN
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eurjchem-1598	236	163	;	;	PUNCT
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eurjchem-1598	236	168	;	;	PUNCT
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eurjchem-1598	236	179	k.	k.	PROPN
eurjchem-1598	236	180	;	;	PUNCT
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eurjchem-1598	236	184	;	;	PUNCT
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eurjchem-1598	236	194	;	;	PUNCT
eurjchem-1598	236	195	tomasi	tomasi	PROPN
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eurjchem-1598	236	197	j.	j.	PROPN
eurjchem-1598	236	198	;	;	PUNCT
eurjchem-1598	236	199	cossi	cossi	PROPN
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eurjchem-1598	236	202	;	;	PUNCT
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eurjchem-1598	236	206	;	;	PUNCT
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eurjchem-1598	236	215	;	;	PUNCT
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eurjchem-1598	236	218	j.	j.	PROPN
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eurjchem-1598	236	220	;	;	PUNCT
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eurjchem-1598	236	223	j.	j.	PROPN
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eurjchem-1598	236	225	;	;	PUNCT
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eurjchem-1598	236	229	;	;	PUNCT
eurjchem-1598	236	230	adamo	adamo	PROPN
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eurjchem-1598	236	232	c.	c.	PROPN
eurjchem-1598	236	233	;	;	PUNCT
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eurjchem-1598	236	235	,	,	PUNCT
eurjchem-1598	236	236	j.	j.	PROPN
eurjchem-1598	236	237	;	;	PUNCT
eurjchem-1598	236	238	gomperts	gomperts	PROPN
eurjchem-1598	236	239	,	,	PUNCT
eurjchem-1598	236	240	r.	r.	PROPN
eurjchem-1598	236	241	;	;	PUNCT
eurjchem-1598	236	242	stratmann	stratmann	PROPN
eurjchem-1598	236	243	,	,	PUNCT
eurjchem-1598	236	244	r.	r.	PROPN
eurjchem-1598	236	245	e.	e.	PROPN
eurjchem-1598	236	246	;	;	PUNCT
eurjchem-1598	236	247	yazyev	yazyev	PROPN
eurjchem-1598	236	248	,	,	PUNCT
eurjchem-1598	236	249	o.	o.	PROPN
eurjchem-1598	236	250	;	;	PUNCT
eurjchem-1598	236	251	austin	austin	PROPN
eurjchem-1598	236	252	,	,	PUNCT
eurjchem-1598	236	253	a.	a.	PROPN
eurjchem-1598	236	254	j.	j.	PROPN
eurjchem-1598	236	255	;	;	PUNCT
eurjchem-1598	236	256	cammi	cammi	PROPN
eurjchem-1598	236	257	,	,	PUNCT
eurjchem-1598	236	258	r.	r.	PROPN
eurjchem-1598	236	259	;	;	PUNCT
eurjchem-1598	236	260	pomelli	pomelli	PROPN
eurjchem-1598	236	261	,	,	PUNCT
eurjchem-1598	236	262	c.	c.	NOUN
eurjchem-1598	236	263	;	;	PUNCT
eurjchem-1598	236	264	ochterski	ochterski	PROPN
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eurjchem-1598	236	266	j.	j.	PROPN
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eurjchem-1598	236	268	;	;	PUNCT
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eurjchem-1598	236	271	r.	r.	PROPN
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eurjchem-1598	236	273	;	;	PUNCT
eurjchem-1598	236	274	morokuma	morokuma	PROPN
eurjchem-1598	236	275	,	,	PUNCT
eurjchem-1598	236	276	k.	k.	PROPN
eurjchem-1598	236	277	;	;	PUNCT
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eurjchem-1598	236	279	,	,	PUNCT
eurjchem-1598	236	280	v.	v.	PROPN
eurjchem-1598	236	281	g.	g.	PROPN
eurjchem-1598	236	282	;	;	PUNCT
eurjchem-1598	236	283	voth	voth	PROPN
eurjchem-1598	236	284	,	,	PUNCT
eurjchem-1598	236	285	g.	g.	PROPN
eurjchem-1598	236	286	a.	a.	PROPN
eurjchem-1598	236	287	;	;	PUNCT
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eurjchem-1598	236	289	,	,	PUNCT
eurjchem-1598	236	290	p.	p.	PROPN
eurjchem-1598	236	291	;	;	PUNCT
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eurjchem-1598	236	293	,	,	PUNCT
eurjchem-1598	236	294	j.	j.	PROPN
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eurjchem-1598	236	296	;	;	PUNCT
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eurjchem-1598	236	298	,	,	PUNCT
eurjchem-1598	236	299	s.	s.	PROPN
eurjchem-1598	236	300	;	;	PUNCT
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eurjchem-1598	236	303	a.	a.	PROPN
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eurjchem-1598	236	305	;	;	PUNCT
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eurjchem-1598	236	307	,	,	PUNCT
eurjchem-1598	236	308	o.	o.	PROPN
eurjchem-1598	236	309	;	;	PUNCT
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eurjchem-1598	236	314	;	;	PUNCT
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eurjchem-1598	236	317	j.	j.	PROPN
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eurjchem-1598	236	319	;	;	PUNCT
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eurjchem-1598	236	322	j.	j.	PROPN
eurjchem-1598	236	323	;	;	PUNCT
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eurjchem-1598	236	326	d.	d.	PROPN
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eurjchem-1598	237	1	[	[	X
eurjchem-1598	237	2	10	10	NUM
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eurjchem-1598	237	4	.	.	PUNCT
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eurjchem-1598	239	2	.	.	PUNCT
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eurjchem-1598	240	2	,	,	PUNCT
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eurjchem-1598	240	4	,	,	PUNCT
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eurjchem-1598	240	6	.	.	PUNCT
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eurjchem-1598	241	3	]	]	PUNCT
eurjchem-1598	241	4	.	.	PUNCT
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eurjchem-1598	242	4	;	;	PUNCT
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eurjchem-1598	242	8	;	;	PUNCT
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eurjchem-1598	244	3	,	,	PUNCT
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eurjchem-1598	244	5	,	,	PUNCT
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eurjchem-1598	244	7	.	.	PUNCT
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eurjchem-1598	252	4	.	.	PUNCT
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eurjchem-1598	254	20	.	.	PUNCT
eurjchem-1598	255	1	j.	j.	PROPN
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eurjchem-1598	255	3	.	.	PUNCT
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eurjchem-1598	256	2	,	,	PUNCT
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eurjchem-1598	257	4	.	.	PUNCT
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eurjchem-1598	262	3	]	]	PUNCT
eurjchem-1598	262	4	.	.	PUNCT
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eurjchem-1598	262	21	,	,	PUNCT
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eurjchem-1598	262	23	m.	m.	PROPN
eurjchem-1598	262	24	j.	j.	PROPN
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eurjchem-1598	263	2	.	.	PUNCT
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eurjchem-1598	265	3	]	]	PUNCT
eurjchem-1598	265	4	.	.	PUNCT
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eurjchem-1598	266	2	,	,	PUNCT
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eurjchem-1598	266	4	;	;	PUNCT
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eurjchem-1598	266	6	,	,	PUNCT
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eurjchem-1598	266	8	k.	k.	PROPN
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eurjchem-1598	272	2	,	,	PUNCT
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eurjchem-1598	274	4	.	.	PUNCT
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eurjchem-1598	275	2	,	,	PUNCT
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eurjchem-1598	275	5	;	;	PUNCT
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eurjchem-1598	275	7	,	,	PUNCT
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eurjchem-1598	275	10	;	;	PUNCT
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eurjchem-1598	275	20	.	.	PUNCT
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eurjchem-1598	276	7	.	.	PUNCT
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eurjchem-1598	277	2	.	.	PUNCT
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eurjchem-1598	278	2	,	,	PUNCT
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eurjchem-1598	279	4	.	.	PUNCT
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eurjchem-1598	280	8	.	.	PUNCT
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eurjchem-1598	281	2	,	,	PUNCT
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eurjchem-1598	282	4	.	.	PUNCT
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eurjchem-1598	283	2	,	,	PUNCT
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eurjchem-1598	283	5	;	;	PUNCT
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eurjchem-1598	284	4	.	.	PUNCT
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eurjchem-1598	285	2	,	,	PUNCT
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eurjchem-1598	285	4	;	;	PUNCT
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eurjchem-1598	285	6	,	,	PUNCT
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eurjchem-1598	288	6	,	,	PUNCT
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eurjchem-1598	290	4	.	.	PUNCT
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eurjchem-1598	291	25	.	.	PUNCT
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eurjchem-1598	292	7	.	.	PUNCT
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eurjchem-1598	294	2	,	,	PUNCT
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eurjchem-1598	294	6	.	.	PUNCT
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eurjchem-1598	296	10	;	;	PUNCT
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eurjchem-1598	305	4	.	.	PUNCT
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