id sid tid token lemma pos eurjchem-1613 1 1 untitled untitled ADJ eurjchem-1613 1 2 issn issn PROPN eurjchem-1613 1 3 2 2 NUM eurjchem-1613 1 4 thermo thermo NOUN eurjchem-1613 1 5 ions ion NOUN eurjchem-1613 1 6 with with ADP eurjchem-1613 1 7 ebrahim ebrahim PROPN eurjchem-1613 1 8 g g PROPN eurjchem-1613 1 9 chemistry chemistry NOUN eurjchem-1613 1 10 depar depar NOUN eurjchem-1613 1 11 * * PUNCT eurjchem-1613 1 12 corresponding correspond VERB eurjchem-1613 1 13 tel tel PROPN eurjchem-1613 1 14 . . PUNCT eurjchem-1613 1 15 : : PUNCT eurjchem-1613 2 1 +98.056.322 +98.056.322 PROPN eurjchem-1613 2 2 article article PROPN eurjchem-1613 2 3 inf inf PROPN eurjchem-1613 2 4 doi doi PROPN eurjchem-1613 2 5 : : PUNCT eurjchem-1613 2 6     SPACE eurjchem-1613 2 7 10.5155 10.5155 NUM eurjchem-1613 2 8 / / SYM eurjchem-1613 2 9 eu eu PROPN eurjchem-1613 2 10 received receive VERB eurjchem-1613 2 11 : : PUNCT eurjchem-1613 2 12 12 12 NUM eurjchem-1613 2 13 july july NOUN eurjchem-1613 2 14 received receive VERB eurjchem-1613 2 15 in in ADP eurjchem-1613 2 16 revis revis PROPN eurjchem-1613 2 17 accepted accept VERB eurjchem-1613 2 18 : : PUNCT eurjchem-1613 2 19 07 07 NUM eurjchem-1613 2 20 oct oct PROPN eurjchem-1613 2 21 published publish VERB eurjchem-1613 2 22 online online ADV eurjchem-1613 2 23 printed print VERB eurjchem-1613 2 24 : : PUNCT eurjchem-1613 2 25 31 31 NUM eurjchem-1613 2 26 dece dece PROPN eurjchem-1613 2 27 keywords keyword VERB eurjchem-1613 2 28 kinetics kinetic NOUN eurjchem-1613 2 29 tryptophan tryptophan NOUN eurjchem-1613 2 30 stability stability NOUN eurjchem-1613 2 31 constan constan ADJ eurjchem-1613 2 32 thermodynamic thermodynamic ADJ eurjchem-1613 2 33 metal metal NOUN eurjchem-1613 2 34 ion‐compl ion‐compl NOUN eurjchem-1613 2 35 dioxane‐water dioxane‐water VERB eurjchem-1613 2 36 m m VERB eurjchem-1613 2 37 1 1 NUM eurjchem-1613 2 38 . . PUNCT eurjchem-1613 2 39 introducti introducti VERB eurjchem-1613 2 40 the the DET eurjchem-1613 2 41 seco seco PROPN eurjchem-1613 2 42 biochemical biochemical ADJ eurjchem-1613 2 43 f f NOUN eurjchem-1613 2 44 by by ADP eurjchem-1613 2 45 noncovale noncovale NOUN eurjchem-1613 2 46 and and CCONJ eurjchem-1613 2 47 with with ADP eurjchem-1613 2 48 vari vari X eurjchem-1613 2 49 between between ADP eurjchem-1613 2 50 met meet VERB eurjchem-1613 2 51 protein protein NOUN eurjchem-1613 2 52 react react NOUN eurjchem-1613 2 53 understand understand VERB eurjchem-1613 2 54 evaluation evaluation NOUN eurjchem-1613 2 55 of of ADP eurjchem-1613 2 56 for for ADP eurjchem-1613 2 57 determini determini ADJ eurjchem-1613 2 58 potentiometr potentiometr NOUN eurjchem-1613 2 59 tion tion NOUN eurjchem-1613 2 60 of of ADP eurjchem-1613 2 61 amino amino NOUN eurjchem-1613 2 62 used use VERB eurjchem-1613 2 63 as as ADP eurjchem-1613 2 64 a a DET eurjchem-1613 2 65 m m NOUN eurjchem-1613 2 66 constants constant NOUN eurjchem-1613 2 67 . . PUNCT eurjchem-1613 3 1 t t PROPN eurjchem-1613 3 2 bjerrum bjerrum NOUN eurjchem-1613 4 1 [ [ X eurjchem-1613 4 2 2 2 X eurjchem-1613 4 3 ] ] PUNCT eurjchem-1613 4 4 a a DET eurjchem-1613 4 5 been be AUX eurjchem-1613 4 6 utilized utilize VERB eurjchem-1613 4 7 solvent solvent NOUN eurjchem-1613 4 8 and and CCONJ eurjchem-1613 4 9 t t NOUN eurjchem-1613 4 10 quite quite ADJ eurjchem-1613 4 11 number number NOUN eurjchem-1613 4 12 l‐tryptop l‐tryptop PUNCT eurjchem-1613 4 13 important important ADJ eurjchem-1613 4 14 ro ro ADJ eurjchem-1613 4 15 essential essential ADJ eurjchem-1613 4 16 am am NOUN eurjchem-1613 4 17 precursor precursor NOUN eurjchem-1613 4 18 of of ADP eurjchem-1613 4 19 biomolecules biomolecule NOUN eurjchem-1613 4 20 the the DET eurjchem-1613 4 21 extent extent NOUN eurjchem-1613 4 22 of of ADP eurjchem-1613 4 23 2153‐2249 2153‐2249 PROPN eurjchem-1613 4 24 ( ( PUNCT eurjchem-1613 4 25 prin prin PROPN eurjchem-1613 4 26 dynamic dynamic PROPN eurjchem-1613 4 27 h h NOUN eurjchem-1613 4 28 tryptop tryptop NOUN eurjchem-1613 4 29 ghiamati ghiamati PROPN eurjchem-1613 4 30 * * PUNCT eurjchem-1613 4 31 an an DET eurjchem-1613 4 32 rtment rtment NOUN eurjchem-1613 4 33 , , PUNCT eurjchem-1613 4 34 university university NOUN eurjchem-1613 4 35 o o NOUN eurjchem-1613 4 36 author author NOUN eurjchem-1613 4 37 at at ADP eurjchem-1613 4 38 : : PUNCT eurjchem-1613 4 39 chemist chemist NOUN eurjchem-1613 4 40 202065 202065 NUM eurjchem-1613 4 41 . . PUNCT eurjchem-1613 5 1 fax fax NOUN eurjchem-1613 5 2 : : PUNCT eurjchem-1613 5 3 +98.05 +98.05 NOUN eurjchem-1613 5 4 formation formation NOUN eurjchem-1613 5 5 urjchem.8.4.333 urjchem.8.4.333 ADP eurjchem-1613 5 6 - - SYM eurjchem-1613 5 7 3 3 NUM eurjchem-1613 5 8 y y PROPN eurjchem-1613 5 9 2017 2017 NUM eurjchem-1613 5 10 sed sed ADJ eurjchem-1613 5 11 form form NOUN eurjchem-1613 5 12 : : PUNCT eurjchem-1613 5 13 03 03 NUM eurjchem-1613 5 14 octob octob PROPN eurjchem-1613 5 15 tober tober NOUN eurjchem-1613 5 16 2017 2017 NUM eurjchem-1613 5 17 e e NOUN eurjchem-1613 5 18 : : PUNCT eurjchem-1613 5 19 31 31 NUM eurjchem-1613 5 20 december december PROPN eurjchem-1613 5 21 20 20 NUM eurjchem-1613 5 22 ember ember VERB eurjchem-1613 5 23 2017 2017 NUM eurjchem-1613 5 24     SPACE eurjchem-1613 5 25 nt not PART eurjchem-1613 5 26 cs cs PROPN eurjchem-1613 5 27 lex lex PROPN eurjchem-1613 5 28 mixture mixture NOUN eurjchem-1613 5 29 ion ion NOUN eurjchem-1613 5 30 ondary ondary ADJ eurjchem-1613 5 31 , , PUNCT eurjchem-1613 5 32 tertiary tertiary ADJ eurjchem-1613 5 33 function function NOUN eurjchem-1613 5 34 of of ADP eurjchem-1613 5 35 pep pep NOUN eurjchem-1613 5 36 ent ent NOUN eurjchem-1613 5 37 interaction interaction NOUN eurjchem-1613 5 38 ious ious ADJ eurjchem-1613 5 39 metal metal NOUN eurjchem-1613 5 40 or or CCONJ eurjchem-1613 5 41 o o ADJ eurjchem-1613 5 42 tal tal ADJ eurjchem-1613 5 43 ions ion NOUN eurjchem-1613 5 44 and and CCONJ eurjchem-1613 5 45 a a DET eurjchem-1613 5 46 tions tion NOUN eurjchem-1613 5 47 is be AUX eurjchem-1613 5 48 an an DET eurjchem-1613 5 49 inte inte NOUN eurjchem-1613 5 50 how how SCONJ eurjchem-1613 5 51 well well ADV eurjchem-1613 5 52 the the DET eurjchem-1613 5 53 their their PRON eurjchem-1613 5 54 stability stability NOUN eurjchem-1613 5 55 c c AUX eurjchem-1613 5 56 ing e VERB eurjchem-1613 5 57 the the DET eurjchem-1613 5 58 stability stability NOUN eurjchem-1613 5 59 ry ry AUX eurjchem-1613 5 60 has have VERB eurjchem-1613 5 61 its its PRON eurjchem-1613 5 62 own own ADJ eurjchem-1613 5 63 o o NOUN eurjchem-1613 5 64 acids acid NOUN eurjchem-1613 5 65 in in ADP eurjchem-1613 5 66 the the DET eurjchem-1613 5 67 p p NOUN eurjchem-1613 5 68 method method NOUN eurjchem-1613 5 69 for for ADP eurjchem-1613 5 70 me i PRON eurjchem-1613 5 71 his his PRON eurjchem-1613 5 72 technique technique NOUN eurjchem-1613 5 73 and and CCONJ eurjchem-1613 5 74 later later ADJ eurjchem-1613 5 75 modif modif NOUN eurjchem-1613 5 76 extensively extensively ADV eurjchem-1613 5 77 by by ADP eurjchem-1613 5 78 temperature temperature NOUN eurjchem-1613 5 79 ef ef NOUN eurjchem-1613 5 80 r r NOUN eurjchem-1613 5 81 of of ADP eurjchem-1613 5 82 researchers researcher NOUN eurjchem-1613 5 83 phan phan PROPN eurjchem-1613 5 84 ( ( PUNCT eurjchem-1613 5 85 trp trp PROPN eurjchem-1613 5 86 ) ) PUNCT eurjchem-1613 5 87 is be AUX eurjchem-1613 5 88 a a DET eurjchem-1613 5 89 ole ole NOUN eurjchem-1613 5 90 in in ADP eurjchem-1613 5 91 many many ADJ eurjchem-1613 5 92 mino mino ADJ eurjchem-1613 5 93 acid acid NOUN eurjchem-1613 5 94 for for ADP eurjchem-1613 5 95 hormones hormone NOUN eurjchem-1613 5 96 , , PUNCT eurjchem-1613 5 97 neu neu PROPN eurjchem-1613 5 98 . . PUNCT eurjchem-1613 6 1 the the DET eurjchem-1613 6 2 level level NOUN eurjchem-1613 6 3 of of ADP eurjchem-1613 6 4 t t PROPN eurjchem-1613 6 5 f f PROPN eurjchem-1613 6 6 hepatic hepatic PROPN eurjchem-1613 6 7 diseas disea NOUN eurjchem-1613 6 8 eu eu PROPN eurjchem-1613 6 9 t t PROPN eurjchem-1613 6 10 ) ) PUNCT eurjchem-1613 6 11 / / SYM eurjchem-1613 6 12 issn issn PROPN eurjchem-1613 6 13 2153‐2 2153‐2 NUM eurjchem-1613 6 14 ht ht NOUN eurjchem-1613 6 15 europ europ NOUN eurjchem-1613 6 16 and and CCONJ eurjchem-1613 6 17 kinet kinet PROPN eurjchem-1613 6 18 phan phan PROPN eurjchem-1613 6 19 nd nd PROPN eurjchem-1613 6 20 zahra zahra PROPN eurjchem-1613 6 21 ab ab PROPN eurjchem-1613 6 22 of of ADP eurjchem-1613 6 23 birjand birjand NOUN eurjchem-1613 6 24 , , PUNCT eurjchem-1613 6 25 birjand birjand NOUN eurjchem-1613 6 26 , , PUNCT eurjchem-1613 6 27 try try VERB eurjchem-1613 6 28 department department PROPN eurjchem-1613 6 29 , , PUNCT eurjchem-1613 6 30 un un PROPN eurjchem-1613 6 31 56.32202065 56.32202065 NUM eurjchem-1613 6 32 . . PUNCT eurjchem-1613 7 1 e‐ma e‐ma PRON eurjchem-1613 7 2 338.1613 338.1613 NUM eurjchem-1613 7 3 ber ber NOUN eurjchem-1613 7 4 2017 2017 NUM eurjchem-1613 7 5 017 017 NUM eurjchem-1613 7 6 y y PROPN eurjchem-1613 7 7 and and CCONJ eurjchem-1613 7 8 quatern quatern ADJ eurjchem-1613 7 9 ptides ptide NOUN eurjchem-1613 7 10 and and CCONJ eurjchem-1613 7 11 prot prot VERB eurjchem-1613 7 12 n n CCONJ eurjchem-1613 7 13 among among ADP eurjchem-1613 7 14 consti consti NOUN eurjchem-1613 7 15 organic organic ADJ eurjchem-1613 7 16 cations cation NOUN eurjchem-1613 7 17 amino amino NOUN eurjchem-1613 7 18 acids acid NOUN eurjchem-1613 7 19 wh wh AUX eurjchem-1613 7 20 eresting ereste VERB eurjchem-1613 7 21 phenom phenom NOUN eurjchem-1613 7 22 ese ese NOUN eurjchem-1613 7 23 interaction interaction NOUN eurjchem-1613 7 24 constants constant NOUN eurjchem-1613 7 25 . . PUNCT eurjchem-1613 8 1 amo amo PROPN eurjchem-1613 8 2 y y PROPN eurjchem-1613 8 3 constant constant ADJ eurjchem-1613 8 4 of of ADP eurjchem-1613 8 5 m m PROPN eurjchem-1613 8 6 advantages advantage NOUN eurjchem-1613 8 7 . . PUNCT eurjchem-1613 9 1 p p PRON eurjchem-1613 9 2 presence presence NOUN eurjchem-1613 9 3 of of ADP eurjchem-1613 9 4 me i PRON eurjchem-1613 9 5 easuring easure VERB eurjchem-1613 9 6 meta meta ADJ eurjchem-1613 9 7 which which PRON eurjchem-1613 9 8 first first ADV eurjchem-1613 9 9 fied fie VERB eurjchem-1613 9 10 by by ADP eurjchem-1613 9 11 calvin calvin PROPN eurjchem-1613 9 12 a a DET eurjchem-1613 9 13 y y PROPN eurjchem-1613 9 14 numerous numerous ADJ eurjchem-1613 9 15 res re NOUN eurjchem-1613 9 16 ffect ffect NOUN eurjchem-1613 9 17 have have AUX eurjchem-1613 9 18 also also ADV eurjchem-1613 9 19 s s PART eurjchem-1613 10 1 [ [ X eurjchem-1613 10 2 19‐34 19‐34 NUM eurjchem-1613 10 3 ] ] PUNCT eurjchem-1613 10 4 . . PUNCT eurjchem-1613 11 1 an an DET eurjchem-1613 11 2 oxidizable oxidizable ADJ eurjchem-1613 11 3 a a DET eurjchem-1613 11 4 biochemical biochemical ADJ eurjchem-1613 11 5 p p NOUN eurjchem-1613 11 6 human human NOUN eurjchem-1613 11 7 and and CCONJ eurjchem-1613 11 8 urotransmitters urotransmitter NOUN eurjchem-1613 11 9 trp trp PROPN eurjchem-1613 11 10 in in ADP eurjchem-1613 11 11 plasma plasma NOUN eurjchem-1613 11 12 i i PRON eurjchem-1613 11 13 se se X eurjchem-1613 12 1 [ [ X eurjchem-1613 12 2 35 35 NUM eurjchem-1613 12 3 ] ] PUNCT eurjchem-1613 12 4 . . PUNCT eurjchem-1613 13 1 the the DET eurjchem-1613 13 2 pr pr NOUN eurjchem-1613 13 3 uropean uropean PROPN eurjchem-1613 13 4 journal journal NOUN eurjchem-1613 13 5 europe europe PROPN eurjchem-1613 13 6 2257 2257 NUM eurjchem-1613 13 7 ( ( PUNCT eurjchem-1613 13 8 online online ADJ eurjchem-1613 13 9 ) ) PUNCT eurjchem-1613 13 10   NOUN eurjchem-1613 13 11 2 2 NUM eurjchem-1613 13 12 ttp://dx.doi.org/10 ttp://dx.doi.org/10 VERB eurjchem-1613 13 13 pean pean PROPN eurjchem-1613 13 14 jo jo PROPN eurjchem-1613 13 15 journal journal PROPN eurjchem-1613 13 16 web web PROPN eurjchem-1613 13 17 tic tic PROPN eurjchem-1613 13 18 studies study NOUN eurjchem-1613 13 19 bazari bazari ADJ eurjchem-1613 13 20 971‐743‐4765 971‐743‐4765 NUM eurjchem-1613 13 21 , , PUNCT eurjchem-1613 13 22 ira ira PROPN eurjchem-1613 13 23 niversity niversity PROPN eurjchem-1613 13 24 of of ADP eurjchem-1613 13 25 birjand birjand NOUN eurjchem-1613 13 26 , , PUNCT eurjchem-1613 13 27 ail ail ADV eurjchem-1613 13 28 address address NOUN eurjchem-1613 13 29 : : PUNCT eurjchem-1613 13 30 eghiam eghiam VERB eurjchem-1613 13 31 abstract abstract ADJ eurjchem-1613 13 32 amino amino NOUN eurjchem-1613 13 33 acid acid NOUN eurjchem-1613 13 34 of of ADP eurjchem-1613 13 35 study study NOUN eurjchem-1613 13 36 its its PRON eurjchem-1613 13 37 intera intera NOUN eurjchem-1613 13 38 examine examine VERB eurjchem-1613 13 39 the the DET eurjchem-1613 13 40 th th X eurjchem-1613 13 41 these these DET eurjchem-1613 13 42 tasks task NOUN eurjchem-1613 13 43 , , PUNCT eurjchem-1613 13 44 the the PRON eurjchem-1613 13 45 and and CCONJ eurjchem-1613 13 46 pb(ii pb(ii ADJ eurjchem-1613 13 47 ) ) PUNCT eurjchem-1613 13 48 at at ADP eurjchem-1613 13 49 t t NOUN eurjchem-1613 13 50 utilizing utilize VERB eurjchem-1613 13 51 modifi modifi NOUN eurjchem-1613 13 52 water water NOUN eurjchem-1613 13 53 : : PUNCT eurjchem-1613 13 54 dioxane dioxane NOUN eurjchem-1613 13 55 complexes complex NOUN eurjchem-1613 13 56 incr incr VERB eurjchem-1613 13 57 negative negative ADJ eurjchem-1613 13 58 values value NOUN eurjchem-1613 13 59 conveying convey VERB eurjchem-1613 13 60 the the DET eurjchem-1613 13 61 contributing contribute VERB eurjchem-1613 13 62 m m NOUN eurjchem-1613 13 63 of of ADP eurjchem-1613 13 64 natural natural ADJ eurjchem-1613 13 65 loga loga NOUN eurjchem-1613 13 66 the the DET eurjchem-1613 13 67 stability stability NOUN eurjchem-1613 13 68 co co VERB eurjchem-1613 13 69 to to ADP eurjchem-1613 13 70 estimation estimation NOUN eurjchem-1613 13 71 o o PROPN eurjchem-1613 13 72 was be AUX eurjchem-1613 13 73 concluded conclude VERB eurjchem-1613 13 74 kf kf PROPN eurjchem-1613 14 1 pb(ii)‐trp pb(ii)‐trp PROPN eurjchem-1613 14 2 < < X eurjchem-1613 14 3 kf kf PROPN eurjchem-1613 14 4 ni ni PROPN eurjchem-1613 14 5 ( ( PUNCT eurjchem-1613 14 6 aforementione aforementione PROPN eurjchem-1613 14 7 ea ea PROPN eurjchem-1613 14 8 fe(iii)‐trp fe(iii)‐trp PROPN eurjchem-1613 14 9 < < X eurjchem-1613 14 10 ea ea PROPN eurjchem-1613 14 11 n n CCONJ eurjchem-1613 14 12 cite cite VERB eurjchem-1613 14 13 this this PRON eurjchem-1613 14 14 : : PUNCT eurjchem-1613 14 15 eur eur PROPN eurjchem-1613 14 16 . . PUNCT eurjchem-1613 15 1 j j PROPN eurjchem-1613 15 2 nary nary ADJ eurjchem-1613 15 3 structures structure NOUN eurjchem-1613 15 4 teins tein NOUN eurjchem-1613 15 5 are be AUX eurjchem-1613 15 6 contr contr VERB eurjchem-1613 15 7 ituent ituent NOUN eurjchem-1613 15 8 amino amino NOUN eurjchem-1613 15 9 a a PRON eurjchem-1613 16 1 [ [ X eurjchem-1613 16 2 1 1 NUM eurjchem-1613 16 3 ] ] PUNCT eurjchem-1613 16 4 . . PUNCT eurjchem-1613 17 1 the the DET eurjchem-1613 17 2 intera intera NOUN eurjchem-1613 17 3 hich hich NOUN eurjchem-1613 17 4 mimics mimic VERB eurjchem-1613 17 5 m m PROPN eurjchem-1613 17 6 menon menon PROPN eurjchem-1613 17 7 . . PUNCT eurjchem-1613 18 1 one one NUM eurjchem-1613 18 2 w w NOUN eurjchem-1613 18 3 ns ns PROPN eurjchem-1613 18 4 could could AUX eurjchem-1613 18 5 occu occu VERB eurjchem-1613 18 6 ong ong PROPN eurjchem-1613 18 7 various various ADJ eurjchem-1613 18 8 met meet VERB eurjchem-1613 18 9 metal metal NOUN eurjchem-1613 18 10 ion ion NOUN eurjchem-1613 18 11 compl compl NOUN eurjchem-1613 18 12 potentiometric potentiometric PROPN eurjchem-1613 18 13 tal tal PROPN eurjchem-1613 18 14 ions ion NOUN eurjchem-1613 18 15 is be AUX eurjchem-1613 18 16 gene gene NOUN eurjchem-1613 18 17 l l NOUN eurjchem-1613 18 18 complex complex ADJ eurjchem-1613 18 19 sta sta NOUN eurjchem-1613 18 20 was be AUX eurjchem-1613 18 21 described describe VERB eurjchem-1613 18 22 and and CCONJ eurjchem-1613 18 23 wilson wilson PROPN eurjchem-1613 19 1 [ [ X eurjchem-1613 19 2 3,4 3,4 NUM eurjchem-1613 19 3 searches search NOUN eurjchem-1613 19 4 [ [ X eurjchem-1613 19 5 5‐18 5‐18 NUM eurjchem-1613 19 6 ] ] PUNCT eurjchem-1613 19 7 been be AUX eurjchem-1613 19 8 examine examine ADJ eurjchem-1613 19 9 amino amino NOUN eurjchem-1613 19 10 acid acid NOUN eurjchem-1613 19 11 play play NOUN eurjchem-1613 19 12 processes process NOUN eurjchem-1613 19 13 . . PUNCT eurjchem-1613 20 1 it it PRON eurjchem-1613 20 2 i i PRON eurjchem-1613 20 3 herbivores herbivore VERB eurjchem-1613 20 4 as as ADP eurjchem-1613 20 5 s s PRON eurjchem-1613 20 6 and and CCONJ eurjchem-1613 20 7 other other ADJ eurjchem-1613 20 8 rele rele PROPN eurjchem-1613 20 9 is be AUX eurjchem-1613 20 10 closely closely ADV eurjchem-1613 20 11 relat relat ADJ eurjchem-1613 20 12 esent esent NOUN eurjchem-1613 20 13 study study NOUN eurjchem-1613 20 14 foc foc VERB eurjchem-1613 20 15 of of ADP eurjchem-1613 20 16 chemistry chemistry NOUN eurjchem-1613 20 17 8 8 NUM eurjchem-1613 20 18 ( ( PUNCT eurjchem-1613 20 19 ean ean NOUN eurjchem-1613 20 20 journal journal NOUN eurjchem-1613 20 21 of of ADP eurjchem-1613 20 22 ch ch PROPN eurjchem-1613 20 23 2017 2017 NUM eurjchem-1613 20 24 atlanta atlanta PROPN eurjchem-1613 20 25 pub pub NOUN eurjchem-1613 20 26 0.5155 0.5155 NUM eurjchem-1613 20 27 / / SYM eurjchem-1613 20 28 eurjchem eurjchem PROPN eurjchem-1613 20 29 ournal ournal ADJ eurjchem-1613 20 30 bpage bpage NOUN eurjchem-1613 20 31 : : PUNCT eurjchem-1613 21 1 www www PROPN eurjchem-1613 21 2 . . PROPN eurjchem-1613 21 3 s s PART eurjchem-1613 21 4 on on ADP eurjchem-1613 21 5 inter inter PRON eurjchem-1613 21 6 an an DET eurjchem-1613 21 7 , , PUNCT eurjchem-1613 21 8 birjand birjand NOUN eurjchem-1613 21 9 , , PUNCT eurjchem-1613 21 10 971‐743‐ 971‐743‐ PROPN eurjchem-1613 21 11 mat@birjand.ac.ir mat@birjand.ac.ir NOUN eurjchem-1613 21 12 ( ( PUNCT eurjchem-1613 21 13 e e NOUN eurjchem-1613 21 14 tryptophan tryptophan NOUN eurjchem-1613 21 15 ( ( PUNCT eurjchem-1613 21 16 trp trp PROPN eurjchem-1613 21 17 action action NOUN eurjchem-1613 21 18 with with ADP eurjchem-1613 21 19 som som NOUN eurjchem-1613 21 20 hermodynamic hermodynamic PROPN eurjchem-1613 21 21 e e PROPN eurjchem-1613 21 22 stability stability NOUN eurjchem-1613 21 23 consta consta PROPN eurjchem-1613 21 24 temperatures temperature NOUN eurjchem-1613 21 25 of of ADP eurjchem-1613 21 26 ied ied PROPN eurjchem-1613 21 27 bjerrum bjerrum PROPN eurjchem-1613 21 28 ’s ’s PART eurjchem-1613 21 29 m m VERB eurjchem-1613 21 30 mixture mixture NOUN eurjchem-1613 21 31 ( ( PUNCT eurjchem-1613 21 32 50:50 50:50 NUM eurjchem-1613 21 33 reased rease VERB eurjchem-1613 21 34 as as ADP eurjchem-1613 21 35 the the DET eurjchem-1613 21 36 di di NOUN eurjchem-1613 21 37 s s X eurjchem-1613 21 38 of of ADP eurjchem-1613 21 39 δg δg NOUN eurjchem-1613 21 40 ° ° NOUN eurjchem-1613 21 41 are be AUX eurjchem-1613 21 42 indi indi PROPN eurjchem-1613 21 43 complex complex ADJ eurjchem-1613 21 44 forma forma NOUN eurjchem-1613 21 45 more more ADV eurjchem-1613 21 46 to to ADP eurjchem-1613 21 47 spontane spontane VERB eurjchem-1613 21 48 rithm rithm PROPN eurjchem-1613 21 49 of of ADP eurjchem-1613 21 50 the the DET eurjchem-1613 21 51 sta sta NOUN eurjchem-1613 21 52 nstant nstant NOUN eurjchem-1613 21 53 of of ADP eurjchem-1613 21 54 the the DET eurjchem-1613 21 55 com com NOUN eurjchem-1613 21 56 of of ADP eurjchem-1613 21 57 rate rate NOUN eurjchem-1613 21 58 constant constant ADJ eurjchem-1613 21 59 that that SCONJ eurjchem-1613 21 60 the the DET eurjchem-1613 21 61 order order NOUN eurjchem-1613 21 62 o o NOUN eurjchem-1613 21 63 ( ( PUNCT eurjchem-1613 21 64 ii)‐trp ii)‐trp PROPN eurjchem-1613 21 65 < < X eurjchem-1613 21 66 kf kf X eurjchem-1613 21 67 cu(ii)‐trp cu(ii)‐trp PROPN eurjchem-1613 22 1 d d NOUN eurjchem-1613 22 2 complexes complexe VERB eurjchem-1613 22 3 in in ADP eurjchem-1613 22 4 ni(ii)‐trp ni(ii)‐trp ADV eurjchem-1613 22 5 < < X eurjchem-1613 22 6 ea ea X eurjchem-1613 22 7 co(ii)‐trp co(ii)‐trp PROPN eurjchem-1613 22 8 j. j. PROPN eurjchem-1613 22 9 chem chem PROPN eurjchem-1613 22 10 . . PUNCT eurjchem-1613 23 1 2017 2017 NUM eurjchem-1613 23 2 , , PUNCT eurjchem-1613 23 3 8 8 NUM eurjchem-1613 23 4 ( ( PUNCT eurjchem-1613 23 5 s s X eurjchem-1613 23 6 and and CCONJ eurjchem-1613 23 7 rolled roll VERB eurjchem-1613 23 8 acids acid NOUN eurjchem-1613 23 9 , , PUNCT eurjchem-1613 23 10 action action NOUN eurjchem-1613 23 11 metal‐ metal‐ NOUN eurjchem-1613 23 12 ay ay NOUN eurjchem-1613 23 13 to to ADP eurjchem-1613 23 14 ur ur PROPN eurjchem-1613 23 15 is be AUX eurjchem-1613 23 16 thods thod NOUN eurjchem-1613 23 17 lexes lexe NOUN eurjchem-1613 23 18 , , PUNCT eurjchem-1613 23 19 titra‐ titra‐ ADJ eurjchem-1613 23 20 erally erally ADV eurjchem-1613 23 21 bility bility NOUN eurjchem-1613 23 22 d d NOUN eurjchem-1613 23 23 by by ADP eurjchem-1613 23 24 4 4 NUM eurjchem-1613 23 25 ] ] PUNCT eurjchem-1613 23 26 has have AUX eurjchem-1613 23 27 . . PUNCT eurjchem-1613 24 1 the the DET eurjchem-1613 24 2 ed ed NOUN eurjchem-1613 24 3 by by ADP eurjchem-1613 24 4 ys ys PRON eurjchem-1613 24 5 an an PRON eurjchem-1613 24 6 is be AUX eurjchem-1613 24 7 an an DET eurjchem-1613 24 8 s s NOUN eurjchem-1613 24 9 the the DET eurjchem-1613 24 10 evant evant ADJ eurjchem-1613 24 11 ed ed NOUN eurjchem-1613 24 12 to to ADP eurjchem-1613 24 13 cuses cuse NOUN eurjchem-1613 24 14 on on ADP eurjchem-1613 24 15 t t PROPN eurjchem-1613 24 16 of of ADP eurjchem-1613 24 17 tr tr NOUN eurjchem-1613 24 18 pb(i pb(i X eurjchem-1613 24 19 natio natio NOUN eurjchem-1613 24 20 stab stab NOUN eurjchem-1613 24 21 δh δh NOUN eurjchem-1613 24 22 ° ° PROPN eurjchem-1613 24 23 , , PUNCT eurjchem-1613 24 24 rate rate NOUN eurjchem-1613 24 25 2 2 NUM eurjchem-1613 24 26 . . PUNCT eurjchem-1613 25 1 ex ex X eurjchem-1613 25 2 2.1 2.1 NUM eurjchem-1613 25 3 . . PUNCT eurjchem-1613 26 1 h h PROPN eurjchem-1613 26 2 reag reag PROPN eurjchem-1613 26 3 merc merc NOUN eurjchem-1613 26 4 disti disti NOUN eurjchem-1613 26 5 cont cont PROPN eurjchem-1613 26 6 1.69 1.69 NUM eurjchem-1613 26 7 was be AUX eurjchem-1613 26 8 pour pour X eurjchem-1613 26 9 statt statt NOUN eurjchem-1613 26 10 then then ADV eurjchem-1613 26 11 duri duri PROPN eurjchem-1613 26 12 ph ph PROPN eurjchem-1613 26 13 w w PROPN eurjchem-1613 26 14 incre incre PROPN eurjchem-1613 26 15 ( ( PUNCT eurjchem-1613 26 16 4 4 NUM eurjchem-1613 26 17 ) ) PUNCT eurjchem-1613 26 18 ( ( PUNCT eurjchem-1613 26 19 2017 2017 NUM eurjchem-1613 26 20 ) ) PUNCT eurjchem-1613 26 21 333‐3 333‐3 NUM eurjchem-1613 26 22 hemistry hemistry NOUN eurjchem-1613 26 23 lishing lishe VERB eurjchem-1613 26 24 house house PROPN eurjchem-1613 26 25 llc llc PROPN eurjchem-1613 26 26 m.8.4.333 m.8.4.333 NOUN eurjchem-1613 26 27 - - PUNCT eurjchem-1613 26 28 338.16 338.16 NUM eurjchem-1613 26 29 of of ADP eurjchem-1613 26 30 che che X eurjchem-1613 26 31 eurjchem.com eurjchem.com X eurjchem-1613 26 32 raction raction NOUN eurjchem-1613 26 33 of of ADP eurjchem-1613 26 34 4765 4765 NUM eurjchem-1613 26 35 , , PUNCT eurjchem-1613 26 36 iran iran PROPN eurjchem-1613 26 37 . . PUNCT eurjchem-1613 27 1 ( ( PUNCT eurjchem-1613 27 2 e. e. PROPN eurjchem-1613 27 3 ghiamati ghiamati PROPN eurjchem-1613 27 4 ) ) PUNCT eurjchem-1613 27 5 . . PUNCT eurjchem-1613 28 1 p p X eurjchem-1613 28 2 ) ) PUNCT eurjchem-1613 28 3 was be AUX eurjchem-1613 28 4 chosen choose VERB eurjchem-1613 28 5 a a DET eurjchem-1613 28 6 me me PROPN eurjchem-1613 28 7 transition transition NOUN eurjchem-1613 28 8 me i PRON eurjchem-1613 28 9 and and CCONJ eurjchem-1613 28 10 kinetic kinetic ADJ eurjchem-1613 28 11 phe phe NOUN eurjchem-1613 28 12 ants ant NOUN eurjchem-1613 28 13 of of ADP eurjchem-1613 28 14 trp trp PROPN eurjchem-1613 28 15 com com PROPN eurjchem-1613 28 16 f f PROPN eurjchem-1613 28 17 25 25 NUM eurjchem-1613 28 18 , , PUNCT eurjchem-1613 28 19 30 30 NUM eurjchem-1613 28 20 , , PUNCT eurjchem-1613 28 21 35 35 NUM eurjchem-1613 28 22 , , PUNCT eurjchem-1613 28 23 an an DET eurjchem-1613 28 24 ethod ethod NOUN eurjchem-1613 28 25 . . PUNCT eurjchem-1613 29 1 potentiom potentiom ADJ eurjchem-1613 29 2 , , PUNCT eurjchem-1613 29 3 v v NOUN eurjchem-1613 29 4 : : PUNCT eurjchem-1613 29 5 v v NOUN eurjchem-1613 29 6 ) ) PUNCT eurjchem-1613 29 7 . . PUNCT eurjchem-1613 30 1 our our PRON eurjchem-1613 30 2 findin findin VERB eurjchem-1613 30 3 ioxane ioxane NOUN eurjchem-1613 30 4 content content NOUN eurjchem-1613 30 5 w w ADP eurjchem-1613 30 6 cation cation NOUN eurjchem-1613 30 7 of of ADP eurjchem-1613 30 8 sponta sponta PROPN eurjchem-1613 30 9 ation ation PROPN eurjchem-1613 30 10 is be AUX eurjchem-1613 30 11 an an DET eurjchem-1613 30 12 endo endo NOUN eurjchem-1613 30 13 eity eity NOUN eurjchem-1613 30 14 , , PUNCT eurjchem-1613 30 15 causing cause VERB eurjchem-1613 30 16 rea rea NOUN eurjchem-1613 30 17 ability ability NOUN eurjchem-1613 30 18 constants constant VERB eurjchem-1613 30 19 mplexes mplexe NOUN eurjchem-1613 30 20 at at ADP eurjchem-1613 30 21 any any DET eurjchem-1613 30 22 t t NOUN eurjchem-1613 30 23 and and CCONJ eurjchem-1613 30 24 activation activation NOUN eurjchem-1613 30 25 e e NOUN eurjchem-1613 30 26 of of ADP eurjchem-1613 30 27 increasing increase VERB eurjchem-1613 30 28 stab stab NOUN eurjchem-1613 30 29 < < X eurjchem-1613 30 30 kf kf X eurjchem-1613 30 31 fe fe X eurjchem-1613 30 32 ( ( PUNCT eurjchem-1613 30 33 iii)‐ iii)‐ NUM eurjchem-1613 30 34 trp trp PROPN eurjchem-1613 30 35 . . PUNCT eurjchem-1613 30 36 fu fu PROPN eurjchem-1613 30 37 water‐dioxane water‐dioxane PROPN eurjchem-1613 31 1 m m VERB eurjchem-1613 32 1 p p X eurjchem-1613 32 2 < < X eurjchem-1613 32 3 ea ea X eurjchem-1613 32 4 cu(ii)‐trp cu(ii)‐trp NOUN eurjchem-1613 32 5 < < X eurjchem-1613 32 6 ea ea X eurjchem-1613 32 7 p p NOUN eurjchem-1613 32 8 ( ( PUNCT eurjchem-1613 32 9 4 4 NUM eurjchem-1613 32 10 ) ) PUNCT eurjchem-1613 32 11 , , PUNCT eurjchem-1613 32 12 333‐338 333‐338 NUM eurjchem-1613 32 13 he he PRON eurjchem-1613 32 14 i i NOUN eurjchem-1613 32 15 ) ) PUNCT eurjchem-1613 32 16 determin determin VERB eurjchem-1613 32 17 ryptophan ryptophan ADJ eurjchem-1613 32 18 with with ADP eurjchem-1613 32 19 ii ii NOUN eurjchem-1613 32 20 ) ) PUNCT eurjchem-1613 32 21 metal metal NOUN eurjchem-1613 32 22 ions ion NOUN eurjchem-1613 32 23 on on ADP eurjchem-1613 32 24 of of ADP eurjchem-1613 32 25 the the DET eurjchem-1613 32 26 natu natu PROPN eurjchem-1613 32 27 ility ility PROPN eurjchem-1613 32 28 , , PUNCT eurjchem-1613 32 29 ( ( PUNCT eurjchem-1613 32 30 iii iii X eurjchem-1613 32 31 ) ) PUNCT eurjchem-1613 32 32 evalu evalu NOUN eurjchem-1613 32 33 , , PUNCT eurjchem-1613 32 34 and and CCONJ eurjchem-1613 32 35 δs δs NOUN eurjchem-1613 32 36 ° ° PRON eurjchem-1613 33 1 and and CCONJ eurjchem-1613 33 2 f f PROPN eurjchem-1613 33 3 constant constant PROPN eurjchem-1613 33 4 , , PUNCT eurjchem-1613 33 5 k k PROPN eurjchem-1613 33 6 and and CCONJ eurjchem-1613 33 7 xperimental xperimental ADJ eurjchem-1613 33 8 materials material NOUN eurjchem-1613 33 9 and and CCONJ eurjchem-1613 33 10 highly highly ADV eurjchem-1613 33 11 pure pure ADJ eurjchem-1613 33 12 tr tr ADV eurjchem-1613 33 13 gent gent ADJ eurjchem-1613 33 14 grade grade NOUN eurjchem-1613 33 15 , , PUNCT eurjchem-1613 33 16 dio dio NOUN eurjchem-1613 33 17 ck ck PROPN eurjchem-1613 33 18 , , PUNCT eurjchem-1613 33 19 germany germany PROPN eurjchem-1613 33 20 . . PUNCT eurjchem-1613 34 1 a a DET eurjchem-1613 34 2 illed ille VERB eurjchem-1613 34 3 water water NOUN eurjchem-1613 34 4 ( ( PUNCT eurjchem-1613 34 5 dd dd VERB eurjchem-1613 34 6 taining taine VERB eurjchem-1613 34 7 5.000× 5.000× PROPN eurjchem-1613 34 8 90×10‐2 90×10‐2 NOUN eurjchem-1613 34 9 m m NOUN eurjchem-1613 34 10 hclo hclo PROPN eurjchem-1613 34 11 added add VERB eurjchem-1613 34 12 to to ADP eurjchem-1613 34 13 adj adj PROPN eurjchem-1613 34 14 red red PROPN eurjchem-1613 34 15 into into ADP eurjchem-1613 34 16 a a DET eurjchem-1613 34 17 dou dou NOUN eurjchem-1613 34 18 ted ted NOUN eurjchem-1613 34 19 to to PART eurjchem-1613 34 20 desired desire VERB eurjchem-1613 34 21 n n CCONJ eurjchem-1613 34 22 titrated titrate VERB eurjchem-1613 34 23 with with ADP eurjchem-1613 34 24 ing ing NOUN eurjchem-1613 34 25 the the DET eurjchem-1613 34 26 experim experim NOUN eurjchem-1613 34 27 was be AUX eurjchem-1613 34 28 corrected correct VERB eurjchem-1613 34 29 a a DET eurjchem-1613 34 30 ements ement NOUN eurjchem-1613 34 31 of of ADP eurjchem-1613 34 32 0.05 0.05 NUM eurjchem-1613 34 33 338 338 NUM eurjchem-1613 34 34 c c NOUN eurjchem-1613 34 35 ‐ ‐ ADP eurjchem-1613 34 36 all all DET eurjchem-1613 34 37 rights right NOUN eurjchem-1613 34 38 rese rese ADJ eurjchem-1613 34 39 13 13 NUM eurjchem-1613 34 40 emistry emistry NOUN eurjchem-1613 35 1 m m VERB eurjchem-1613 35 2 f f PROPN eurjchem-1613 35 3 some some DET eurjchem-1613 35 4 tra tra NOUN eurjchem-1613 35 5 as as ADP eurjchem-1613 35 6 a a DET eurjchem-1613 35 7 drug drug NOUN eurjchem-1613 35 8 . . PUNCT eurjchem-1613 36 1 a a DET eurjchem-1613 36 2 syst syst PROPN eurjchem-1613 36 3 etal etal NOUN eurjchem-1613 36 4 ions ion NOUN eurjchem-1613 36 5 , , PUNCT eurjchem-1613 36 6 and and CCONJ eurjchem-1613 36 7 q q PROPN eurjchem-1613 36 8 enomena enomena NOUN eurjchem-1613 36 9 on on ADP eurjchem-1613 36 10 thi thi PROPN eurjchem-1613 36 11 mplexes mplexe NOUN eurjchem-1613 36 12 with with ADP eurjchem-1613 36 13 fe fe PROPN eurjchem-1613 36 14 ( ( PUNCT eurjchem-1613 36 15 nd nd ADV eurjchem-1613 36 16 40 40 NUM eurjchem-1613 36 17 ° ° NUM eurjchem-1613 36 18 c c NOUN eurjchem-1613 36 19 were be AUX eurjchem-1613 36 20 d d X eurjchem-1613 36 21 metric metric ADJ eurjchem-1613 36 22 titrations titration NOUN eurjchem-1613 36 23 ngs ng NOUN eurjchem-1613 36 24 showed show VERB eurjchem-1613 36 25 tha tha INTJ eurjchem-1613 36 26 was be AUX eurjchem-1613 36 27 raised raise VERB eurjchem-1613 36 28 or or CCONJ eurjchem-1613 36 29 t t NOUN eurjchem-1613 36 30 aneity aneity NOUN eurjchem-1613 36 31 of of ADP eurjchem-1613 36 32 the the DET eurjchem-1613 36 33 pro pro ADJ eurjchem-1613 36 34 othermic othermic ADJ eurjchem-1613 36 35 proces proce NOUN eurjchem-1613 36 36 action action NOUN eurjchem-1613 36 37 favoring favor VERB eurjchem-1613 36 38 a a DET eurjchem-1613 36 39 versus versus ADP eurjchem-1613 36 40 1 1 NUM eurjchem-1613 36 41 / / SYM eurjchem-1613 36 42 t t NOUN eurjchem-1613 36 43 are be AUX eurjchem-1613 36 44 temperature temperature NOUN eurjchem-1613 36 45 . . PUNCT eurjchem-1613 37 1 mo mo PROPN eurjchem-1613 37 2 energy energy NOUN eurjchem-1613 37 3 for for ADP eurjchem-1613 37 4 each each DET eurjchem-1613 37 5 bility bility NOUN eurjchem-1613 37 6 of of ADP eurjchem-1613 37 7 the the DET eurjchem-1613 37 8 com com NOUN eurjchem-1613 37 9 urthermore urthermore NOUN eurjchem-1613 37 10 the the DET eurjchem-1613 37 11 a a DET eurjchem-1613 37 12 mixture mixture NOUN eurjchem-1613 37 13 obeyed obey VERB eurjchem-1613 38 1 pb(ii)‐trp pb(ii)‐trp PROPN eurjchem-1613 38 2 . . PUNCT eurjchem-1613 39 1 ation ation PROPN eurjchem-1613 39 2 of of ADP eurjchem-1613 39 3 the the DET eurjchem-1613 39 4 sta sta NOUN eurjchem-1613 39 5 h h NOUN eurjchem-1613 39 6 fe(iii fe(iii PROPN eurjchem-1613 39 7 ) ) PUNCT eurjchem-1613 39 8 , , PUNCT eurjchem-1613 39 9 co(ii co(ii VERB eurjchem-1613 39 10 in in ADP eurjchem-1613 39 11 water water NOUN eurjchem-1613 39 12 and and CCONJ eurjchem-1613 39 13 ure ure PROPN eurjchem-1613 39 14 of of ADP eurjchem-1613 39 15 solvent solvent ADJ eurjchem-1613 39 16 uation uation NOUN eurjchem-1613 39 17 of of ADP eurjchem-1613 39 18 thermo thermo NOUN eurjchem-1613 39 19 finally finally ADV eurjchem-1613 39 20 estimatio estimatio VERB eurjchem-1613 40 1 d d PRON eurjchem-1613 40 2 activation activation NOUN eurjchem-1613 40 3 ene ene NOUN eurjchem-1613 40 4 d d NOUN eurjchem-1613 40 5 procedure procedure NOUN eurjchem-1613 40 6 rp rp NOUN eurjchem-1613 40 7 , , PUNCT eurjchem-1613 40 8 nitrate nitrate NOUN eurjchem-1613 40 9 salt salt NOUN eurjchem-1613 40 10 oxane oxane NOUN eurjchem-1613 40 11 and and CCONJ eurjchem-1613 40 12 hclo hclo VERB eurjchem-1613 40 13 all all PRON eurjchem-1613 40 14 of of ADP eurjchem-1613 40 15 the the DET eurjchem-1613 40 16 solut solut NOUN eurjchem-1613 40 17 dw dw PROPN eurjchem-1613 40 18 ) ) PUNCT eurjchem-1613 40 19 . . PUNCT eurjchem-1613 41 1 a a DET eurjchem-1613 41 2 25.00 25.00 NUM eurjchem-1613 41 3 ml ml NOUN eurjchem-1613 41 4 10‐3 10‐3 NUM eurjchem-1613 41 5 m m NOUN eurjchem-1613 41 6 trp trp PROPN eurjchem-1613 41 7 , , PUNCT eurjchem-1613 41 8 3 3 NUM eurjchem-1613 41 9 o4 o4 PROPN eurjchem-1613 41 10 . . PUNCT eurjchem-1613 42 1 the the DET eurjchem-1613 42 2 sufficie sufficie ADJ eurjchem-1613 42 3 ust ust PROPN eurjchem-1613 42 4 the the DET eurjchem-1613 42 5 ionic ionic ADJ eurjchem-1613 42 6 uble uble ADJ eurjchem-1613 42 7 walled wall VERB eurjchem-1613 42 8 gla gla PROPN eurjchem-1613 42 9 temperatures temperature NOUN eurjchem-1613 42 10 an an DET eurjchem-1613 42 11 accurately accurately ADV eurjchem-1613 42 12 s s VERB eurjchem-1613 42 13 ments ment NOUN eurjchem-1613 42 14 the the DET eurjchem-1613 42 15 react react NOUN eurjchem-1613 42 16 and and CCONJ eurjchem-1613 42 17 recorded record VERB eurjchem-1613 42 18 af af INTJ eurjchem-1613 42 19 ml ml PROPN eurjchem-1613 42 20 . . PUNCT eurjchem-1613 43 1 each each DET eurjchem-1613 43 2 titrat titrat NOUN eurjchem-1613 43 3 rved rve VERB eurjchem-1613 43 4 ‐ ‐ NOUN eurjchem-1613 43 5 printed print VERB eurjchem-1613 43 6 in in ADP eurjchem-1613 43 7 y y PROPN eurjchem-1613 43 8 ansition ansition PROPN eurjchem-1613 43 9 m m PROPN eurjchem-1613 43 10 tematic tematic ADJ eurjchem-1613 43 11 approac approac NOUN eurjchem-1613 43 12 qualitatively qualitatively ADV eurjchem-1613 43 13 and and CCONJ eurjchem-1613 43 14 is be AUX eurjchem-1613 43 15 model model NOUN eurjchem-1613 43 16 drug drug NOUN eurjchem-1613 43 17 . . PUNCT eurjchem-1613 44 1 iii iii X eurjchem-1613 44 2 ) ) PUNCT eurjchem-1613 44 3 , , PUNCT eurjchem-1613 45 1 co(ii co(ii PROPN eurjchem-1613 45 2 ) ) PUNCT eurjchem-1613 45 3 , , PUNCT eurjchem-1613 45 4 ni(ii ni(ii X eurjchem-1613 45 5 determined determine VERB eurjchem-1613 45 6 pote pote NOUN eurjchem-1613 45 7 s s VERB eurjchem-1613 45 8 were be AUX eurjchem-1613 45 9 carried carry VERB eurjchem-1613 45 10 ou ou ADV eurjchem-1613 45 11 at at ADP eurjchem-1613 45 12 the the DET eurjchem-1613 45 13 stability stability NOUN eurjchem-1613 45 14 c c PROPN eurjchem-1613 45 15 emperature emperature NOUN eurjchem-1613 45 16 was be AUX eurjchem-1613 45 17 cesses cesse NOUN eurjchem-1613 45 18 . . PUNCT eurjchem-1613 46 1 δh δh NOUN eurjchem-1613 46 2 ° ° PROPN eurjchem-1613 46 3 valu valu VERB eurjchem-1613 46 4 ss ss PROPN eurjchem-1613 46 5 and and CCONJ eurjchem-1613 46 6 δs δs NOUN eurjchem-1613 46 7 ° ° PROPN eurjchem-1613 46 8 valu valu NOUN eurjchem-1613 46 9 and and CCONJ eurjchem-1613 46 10 disordering disordering NOUN eurjchem-1613 46 11 . . PUNCT eurjchem-1613 47 1 linear linear ADJ eurjchem-1613 47 2 leading lead VERB eurjchem-1613 47 3 t t PROPN eurjchem-1613 47 4 oreover oreover NOUN eurjchem-1613 47 5 , , PUNCT eurjchem-1613 47 6 kinetic kinetic ADJ eurjchem-1613 47 7 complex complex ADJ eurjchem-1613 47 8 forma forma NOUN eurjchem-1613 47 9 mplexes mplexe NOUN eurjchem-1613 47 10 is be AUX eurjchem-1613 47 11 : : PUNCT eurjchem-1613 47 12 kf kf PROPN eurjchem-1613 47 13 co(ii co(ii PROPN eurjchem-1613 47 14 ) ) PUNCT eurjchem-1613 47 15 activation activation NOUN eurjchem-1613 47 16 energy energy NOUN eurjchem-1613 47 17 the the DET eurjchem-1613 47 18 following follow VERB eurjchem-1613 47 19 tr tr NOUN eurjchem-1613 47 20 ability ability NOUN eurjchem-1613 47 21 constant constant ADJ eurjchem-1613 47 22 i i PROPN eurjchem-1613 47 23 ) ) PUNCT eurjchem-1613 47 24 , , PUNCT eurjchem-1613 47 25 ni ni PROPN eurjchem-1613 47 26 ( ( PUNCT eurjchem-1613 47 27 ii ii PROPN eurjchem-1613 47 28 ) ) PUNCT eurjchem-1613 47 29 , , PUNCT eurjchem-1613 47 30 zn(i zn(i X eurjchem-1613 47 31 dioxane dioxane NOUN eurjchem-1613 47 32 mixtu mixtu NOUN eurjchem-1613 47 33 t t NOUN eurjchem-1613 47 34 and and CCONJ eurjchem-1613 47 35 tempera tempera NOUN eurjchem-1613 47 36 odynamic odynamic ADJ eurjchem-1613 47 37 para para NOUN eurjchem-1613 47 38 on on ADP eurjchem-1613 47 39 of of ADP eurjchem-1613 47 40 kinetic kinetic ADJ eurjchem-1613 47 41 pa pa PROPN eurjchem-1613 47 42 ergy ergy PROPN eurjchem-1613 47 43 , , PUNCT eurjchem-1613 47 44 ea ea X eurjchem-1613 47 45 . . NOUN eurjchem-1613 47 46 of of ADP eurjchem-1613 47 47 the the DET eurjchem-1613 47 48 respect respect NOUN eurjchem-1613 47 49 o4 o4 PROPN eurjchem-1613 47 50 all all PRON eurjchem-1613 47 51 were be AUX eurjchem-1613 47 52 pu pu PROPN eurjchem-1613 47 53 tions tion NOUN eurjchem-1613 47 54 were be AUX eurjchem-1613 47 55 mad mad ADJ eurjchem-1613 47 56 l l NOUN eurjchem-1613 47 57 solution solution NOUN eurjchem-1613 47 58 mixt mixt ADJ eurjchem-1613 47 59 .000×10‐3 .000×10‐3 PUNCT eurjchem-1613 48 1 m m VERB eurjchem-1613 48 2 m m VERB eurjchem-1613 48 3 ent ent NOUN eurjchem-1613 48 4 amount amount NOUN eurjchem-1613 48 5 of of ADP eurjchem-1613 48 6 0 0 NUM eurjchem-1613 48 7 strength strength NOUN eurjchem-1613 48 8 . . PUNCT eurjchem-1613 49 1 the the DET eurjchem-1613 49 2 ass ass NOUN eurjchem-1613 49 3 reactor reactor NOUN eurjchem-1613 49 4 ; ; PUNCT eurjchem-1613 49 5 it it PRON eurjchem-1613 49 6 of of ADP eurjchem-1613 49 7 25 25 NUM eurjchem-1613 49 8 , , PUNCT eurjchem-1613 49 9 30 30 NUM eurjchem-1613 49 10 , , PUNCT eurjchem-1613 49 11 35 35 NUM eurjchem-1613 49 12 a a DET eurjchem-1613 49 13 standardized standardized ADJ eurjchem-1613 49 14 n n DET eurjchem-1613 49 15 tor tor NOUN eurjchem-1613 49 16 was be AUX eurjchem-1613 49 17 purged purge VERB eurjchem-1613 49 18 fter fter ADV eurjchem-1613 49 19 each each DET eurjchem-1613 49 20 additio additio PROPN eurjchem-1613 49 21 tion tion PROPN eurjchem-1613 49 22 consumed consume VERB eurjchem-1613 49 23 the the DET eurjchem-1613 49 24 usa usa PROPN eurjchem-1613 49 25 metal metal PROPN eurjchem-1613 49 26 ch ch NOUN eurjchem-1613 49 27 was be AUX eurjchem-1613 49 28 made make VERB eurjchem-1613 49 29 to to ADP eurjchem-1613 49 30 d d VERB eurjchem-1613 49 31 quantitatively quantitatively ADV eurjchem-1613 49 32 to to PART eurjchem-1613 49 33 accomplish accomplish VERB eurjchem-1613 49 34 i i PRON eurjchem-1613 49 35 ) ) PUNCT eurjchem-1613 49 36 , , PUNCT eurjchem-1613 49 37 cu(ii cu(ii PROPN eurjchem-1613 49 38 ) ) PUNCT eurjchem-1613 49 39 , , PUNCT eurjchem-1613 49 40 zn(ii zn(ii NUM eurjchem-1613 49 41 ) ) PUNCT eurjchem-1613 49 42 entiometrically entiometrically ADV eurjchem-1613 49 43 , , PUNCT eurjchem-1613 49 44 ut ut PROPN eurjchem-1613 49 45 in in ADP eurjchem-1613 49 46 water water NOUN eurjchem-1613 49 47 , , PUNCT eurjchem-1613 49 48 and and CCONJ eurjchem-1613 49 49 onstants onstant NOUN eurjchem-1613 49 50 of of ADP eurjchem-1613 49 51 the the DET eurjchem-1613 49 52 s s NOUN eurjchem-1613 49 53 elevated elevated ADJ eurjchem-1613 49 54 . . PUNCT eurjchem-1613 50 1 the the DET eurjchem-1613 50 2 ues ue NOUN eurjchem-1613 50 3 are be AUX eurjchem-1613 50 4 positive positive ADJ eurjchem-1613 50 5 , , PUNCT eurjchem-1613 50 6 es es PRON eurjchem-1613 50 7 are be AUX eurjchem-1613 50 8 positive positive ADJ eurjchem-1613 50 9 the the DET eurjchem-1613 50 10 variations variation NOUN eurjchem-1613 50 11 to to ADP eurjchem-1613 50 12 evaluation evaluation NOUN eurjchem-1613 50 13 of of ADP eurjchem-1613 50 14 study study NOUN eurjchem-1613 50 15 gave give VERB eurjchem-1613 50 16 rise rise NOUN eurjchem-1613 50 17 ation ation NOUN eurjchem-1613 50 18 process process NOUN eurjchem-1613 50 19 . . PUNCT eurjchem-1613 51 1 it it PRON eurjchem-1613 51 2 ‐trp ‐trp PROPN eurjchem-1613 51 3   X eurjchem-1613 51 4 kf kf PROPN eurjchem-1613 52 1 zn(ii)‐trp zn(ii)‐trp PROPN eurjchem-1613 52 2 < < X eurjchem-1613 52 3 y y PROPN eurjchem-1613 52 4 values value NOUN eurjchem-1613 52 5 for for ADP eurjchem-1613 52 6 the the DET eurjchem-1613 52 7 rend rend NOUN eurjchem-1613 52 8 ea ea PUNCT eurjchem-1613 52 9 zn(ii)‐trp zn(ii)‐trp PROPN eurjchem-1613 52 10 < < X eurjchem-1613 52 11 t t PROPN eurjchem-1613 52 12 of of ADP eurjchem-1613 52 13 complexes complexes PROPN eurjchem-1613 52 14 ii ii PROPN eurjchem-1613 52 15 ) ) PUNCT eurjchem-1613 52 16 , , PUNCT eurjchem-1613 52 17 cu(ii cu(ii PROPN eurjchem-1613 52 18 ) ) PUNCT eurjchem-1613 52 19 and and CCONJ eurjchem-1613 52 20 ure ure PROPN eurjchem-1613 52 21 , , PUNCT eurjchem-1613 52 22 ii ii PROPN eurjchem-1613 52 23 ) ) PUNCT eurjchem-1613 52 24 exami‐ exami‐ X eurjchem-1613 52 25 ature ature NOUN eurjchem-1613 52 26 on on ADP eurjchem-1613 52 27 their their PRON eurjchem-1613 52 28 meters meter NOUN eurjchem-1613 52 29 of of ADP eurjchem-1613 52 30 δg δg NOUN eurjchem-1613 52 31 ° ° NOUN eurjchem-1613 52 32 , , PUNCT eurjchem-1613 52 33 arameters arameter NOUN eurjchem-1613 52 34 , , PUNCT eurjchem-1613 52 35 i.e. i.e. X eurjchem-1613 52 36 , , PUNCT eurjchem-1613 52 37 tive tive NOUN eurjchem-1613 52 38 metals metal NOUN eurjchem-1613 52 39 as as SCONJ eurjchem-1613 52 40 urchased urchase VERB eurjchem-1613 52 41 from from ADP eurjchem-1613 52 42 de de ADV eurjchem-1613 52 43 by by ADP eurjchem-1613 52 44 doubled double VERB eurjchem-1613 52 45 ture ture NOUN eurjchem-1613 52 46 was be AUX eurjchem-1613 52 47 made make VERB eurjchem-1613 52 48 metal metal NOUN eurjchem-1613 52 49 ion ion NOUN eurjchem-1613 52 50 and and CCONJ eurjchem-1613 52 51 0.10 0.10 NUM eurjchem-1613 52 52 m m NOUN eurjchem-1613 52 53 nano3 nano3 ADJ eurjchem-1613 52 54 solution solution NOUN eurjchem-1613 52 55 was be AUX eurjchem-1613 52 56 was be AUX eurjchem-1613 52 57 thermos‐ thermos‐ NUM eurjchem-1613 52 58 and and CCONJ eurjchem-1613 52 59 40 40 NUM eurjchem-1613 52 60 ° ° NOUN eurjchem-1613 52 61 c c NOUN eurjchem-1613 52 62 and and CCONJ eurjchem-1613 52 63 naoh naoh NOUN eurjchem-1613 52 64 solution solution NOUN eurjchem-1613 52 65 . . PUNCT eurjchem-1613 53 1 d d NOUN eurjchem-1613 53 2 with with ADP eurjchem-1613 53 3 n2 n2 PROPN eurjchem-1613 53 4 . . PUNCT eurjchem-1613 54 1 the the DET eurjchem-1613 54 2 on on ADP eurjchem-1613 54 3 of of ADP eurjchem-1613 54 4 titrant titrant NOUN eurjchem-1613 54 5 in in ADP eurjchem-1613 54 6 6‐8 6‐8 PROPN eurjchem-1613 54 7 ml ml NOUN eurjchem-1613 54 8 of of ADP eurjchem-1613 54 9 the the DET eurjchem-1613 54 10 334 334 NUM eurjchem-1613 54 11 ghiamati ghiamati NOUN eurjchem-1613 54 12 and and CCONJ eurjchem-1613 54 13 abazari abazari ADJ eurjchem-1613 54 14 / / SYM eurjchem-1613 54 15 european european ADJ eurjchem-1613 54 16 journal journal PROPN eurjchem-1613 54 17 of of ADP eurjchem-1613 54 18 chemistry chemistry NOUN eurjchem-1613 54 19 8 8 NUM eurjchem-1613 54 20 ( ( PUNCT eurjchem-1613 54 21 4 4 NUM eurjchem-1613 54 22 ) ) PUNCT eurjchem-1613 54 23 ( ( PUNCT eurjchem-1613 54 24 2017 2017 NUM eurjchem-1613 54 25 ) ) PUNCT eurjchem-1613 54 26 333‐338 333‐338 NUM eurjchem-1613 54 27 titrant titrant NOUN eurjchem-1613 54 28 , , PUNCT eurjchem-1613 54 29 and and CCONJ eurjchem-1613 54 30 five five NUM eurjchem-1613 54 31 replicate replicate ADJ eurjchem-1613 54 32 measurements measurement NOUN eurjchem-1613 54 33 were be AUX eurjchem-1613 54 34 conducted conduct VERB eurjchem-1613 54 35 in in ADP eurjchem-1613 54 36 order order NOUN eurjchem-1613 54 37 to to PART eurjchem-1613 54 38 check check VERB eurjchem-1613 54 39 the the DET eurjchem-1613 54 40 reproducibility reproducibility NOUN eurjchem-1613 54 41 of of ADP eurjchem-1613 54 42 the the DET eurjchem-1613 54 43 data datum NOUN eurjchem-1613 54 44 . . PUNCT eurjchem-1613 55 1 the the DET eurjchem-1613 55 2 calculation calculation NOUN eurjchem-1613 55 3 of of ADP eurjchem-1613 55 4 the the DET eurjchem-1613 55 5 stability stability NOUN eurjchem-1613 55 6 constants constant NOUN eurjchem-1613 55 7 of of ADP eurjchem-1613 55 8 the the DET eurjchem-1613 55 9 complexes complex NOUN eurjchem-1613 55 10 were be AUX eurjchem-1613 55 11 performed perform VERB eurjchem-1613 55 12 using use VERB eurjchem-1613 55 13 our our PRON eurjchem-1613 55 14 developed develop VERB eurjchem-1613 55 15 computer computer NOUN eurjchem-1613 55 16 programme programme NOUN eurjchem-1613 55 17 . . PUNCT eurjchem-1613 56 1 spectrophoto‐ spectrophoto‐ PROPN eurjchem-1613 56 2 metric metric ADJ eurjchem-1613 56 3 measurements measurement NOUN eurjchem-1613 56 4 were be AUX eurjchem-1613 56 5 done do VERB eurjchem-1613 56 6 with with ADP eurjchem-1613 56 7 a a DET eurjchem-1613 56 8 uv‐vis uv‐vis ADJ eurjchem-1613 56 9 specord specord NOUN eurjchem-1613 56 10 210 210 NUM eurjchem-1613 56 11 plus plus CCONJ eurjchem-1613 56 12 with with ADP eurjchem-1613 56 13 a a DET eurjchem-1613 56 14 gdu gdu NOUN eurjchem-1613 56 15 computer computer NOUN eurjchem-1613 56 16 and and CCONJ eurjchem-1613 56 17 using use VERB eurjchem-1613 56 18 thermostated thermostat VERB eurjchem-1613 56 19 matched match VERB eurjchem-1613 56 20 10 10 NUM eurjchem-1613 56 21 mm mm PROPN eurjchem-1613 56 22 quartz quartz NOUN eurjchem-1613 56 23 cells cell NOUN eurjchem-1613 56 24 . . PUNCT eurjchem-1613 57 1 ir ir PROPN eurjchem-1613 57 2 spectra spectra PROPN eurjchem-1613 57 3 were be AUX eurjchem-1613 57 4 acquired acquire VERB eurjchem-1613 57 5 as as ADP eurjchem-1613 57 6 kbr kbr PROPN eurjchem-1613 57 7 disc disc NOUN eurjchem-1613 57 8 by by ADP eurjchem-1613 57 9 avatar avatar NOUN eurjchem-1613 57 10 , , PUNCT eurjchem-1613 57 11 usa usa PROPN eurjchem-1613 57 12 370 370 NUM eurjchem-1613 57 13 ft‐ir ft‐ir NOUN eurjchem-1613 57 14 . . PUNCT eurjchem-1613 58 1 2.2 2.2 NUM eurjchem-1613 58 2 . . PUNCT eurjchem-1613 58 3 calibration calibration NOUN eurjchem-1613 58 4 of of ADP eurjchem-1613 58 5 the the DET eurjchem-1613 58 6 glass glass NOUN eurjchem-1613 58 7 electrode electrode NOUN eurjchem-1613 58 8 all all DET eurjchem-1613 58 9 ph ph ADJ eurjchem-1613 58 10 titrations titration NOUN eurjchem-1613 58 11 were be AUX eurjchem-1613 58 12 performed perform VERB eurjchem-1613 58 13 using use VERB eurjchem-1613 58 14 a a DET eurjchem-1613 58 15 metrohm metrohm NUM eurjchem-1613 58 16 794 794 NUM eurjchem-1613 58 17 basic basic ADJ eurjchem-1613 58 18 automatic automatic ADJ eurjchem-1613 58 19 titrator titrator NOUN eurjchem-1613 58 20 ( ( PUNCT eurjchem-1613 58 21 titrino titrino PROPN eurjchem-1613 58 22 ) ) PUNCT eurjchem-1613 58 23 , , PUNCT eurjchem-1613 58 24 coupled couple VERB eurjchem-1613 58 25 with with ADP eurjchem-1613 58 26 a a DET eurjchem-1613 58 27 thermo‐ thermo‐ NOUN eurjchem-1613 58 28 stating state VERB eurjchem-1613 58 29 bath bath NOUN eurjchem-1613 58 30 hero hero NOUN eurjchem-1613 58 31 ( ( PUNCT eurjchem-1613 58 32 ±0.1 ±0.1 NOUN eurjchem-1613 58 33 ° ° NOUN eurjchem-1613 58 34 c c NOUN eurjchem-1613 58 35 ) ) PUNCT eurjchem-1613 58 36 . . PUNCT eurjchem-1613 59 1 the the DET eurjchem-1613 59 2 ph ph ADJ eurjchem-1613 59 3 meter meter NOUN eurjchem-1613 59 4 was be AUX eurjchem-1613 59 5 calibrated calibrate VERB eurjchem-1613 59 6 using use VERB eurjchem-1613 59 7 merck merck PROPN eurjchem-1613 59 8 standard standard ADJ eurjchem-1613 59 9 buffer buffer NOUN eurjchem-1613 59 10 solutions solution NOUN eurjchem-1613 59 11 with with ADP eurjchem-1613 59 12 ph ph NOUN eurjchem-1613 59 13 of of ADP eurjchem-1613 59 14 4.0 4.0 NUM eurjchem-1613 59 15 , , PUNCT eurjchem-1613 59 16 7.0 7.0 NUM eurjchem-1613 59 17 and and CCONJ eurjchem-1613 59 18 9.0 9.0 NUM eurjchem-1613 59 19 . . PUNCT eurjchem-1613 60 1 a a DET eurjchem-1613 60 2 combination combination NOUN eurjchem-1613 60 3 of of ADP eurjchem-1613 60 4 calomel calomel ADJ eurjchem-1613 60 5 and and CCONJ eurjchem-1613 60 6 glass glass NOUN eurjchem-1613 60 7 electrode electrode NOUN eurjchem-1613 60 8 was be AUX eurjchem-1613 60 9 used use VERB eurjchem-1613 60 10 . . PUNCT eurjchem-1613 61 1 to to PART eurjchem-1613 61 2 compensate compensate VERB eurjchem-1613 61 3 for for ADP eurjchem-1613 61 4 acid acid NOUN eurjchem-1613 61 5 error error NOUN eurjchem-1613 61 6 ( ( PUNCT eurjchem-1613 61 7 ph ph NOUN eurjchem-1613 61 8 = = SYM eurjchem-1613 61 9 2‐4 2‐4 NUM eurjchem-1613 61 10 ) ) PUNCT eurjchem-1613 61 11 of of ADP eurjchem-1613 61 12 the the DET eurjchem-1613 61 13 electrode electrode NOUN eurjchem-1613 61 14 , , PUNCT eurjchem-1613 61 15 30 30 NUM eurjchem-1613 61 16 ml ml NOUN eurjchem-1613 61 17 solution solution NOUN eurjchem-1613 61 18 containing contain VERB eurjchem-1613 61 19 kcl kcl NOUN eurjchem-1613 61 20 , , PUNCT eurjchem-1613 61 21 0.1 0.1 NUM eurjchem-1613 61 22 m m NOUN eurjchem-1613 61 23 was be AUX eurjchem-1613 61 24 titrated titrate VERB eurjchem-1613 61 25 with with ADP eurjchem-1613 61 26 standardized standardized ADJ eurjchem-1613 61 27 perchloric perchloric ADJ eurjchem-1613 61 28 acid acid NOUN eurjchem-1613 61 29 , , PUNCT eurjchem-1613 61 30 following follow VERB eurjchem-1613 61 31 a a DET eurjchem-1613 61 32 plot plot NOUN eurjchem-1613 61 33 of of ADP eurjchem-1613 61 34 calculated calculated ADJ eurjchem-1613 61 35 ph ph PROPN eurjchem-1613 61 36 versus versus ADP eurjchem-1613 61 37 read read NOUN eurjchem-1613 61 38 ph ph PROPN eurjchem-1613 61 39 , , PUNCT eurjchem-1613 61 40 and and CCONJ eurjchem-1613 61 41 producing produce VERB eurjchem-1613 61 42 the the DET eurjchem-1613 61 43 equation equation NOUN eurjchem-1613 61 44 for for ADP eurjchem-1613 61 45 ph ph ADJ eurjchem-1613 61 46 correction correction NOUN eurjchem-1613 61 47 . . PUNCT eurjchem-1613 62 1 to to PART eurjchem-1613 62 2 account account VERB eurjchem-1613 62 3 for for ADP eurjchem-1613 62 4 alkaline alkaline NOUN eurjchem-1613 62 5 error error NOUN eurjchem-1613 62 6 ( ( PUNCT eurjchem-1613 62 7 ph ph NOUN eurjchem-1613 62 8 = = NOUN eurjchem-1613 62 9 10‐12 10‐12 NUM eurjchem-1613 62 10 ) ) PUNCT eurjchem-1613 62 11 the the DET eurjchem-1613 62 12 same same ADJ eurjchem-1613 62 13 volume volume NOUN eurjchem-1613 62 14 of of ADP eurjchem-1613 62 15 kcl kcl PROPN eurjchem-1613 62 16 , , PUNCT eurjchem-1613 62 17 0.1 0.1 NUM eurjchem-1613 62 18 m m NOUN eurjchem-1613 62 19 solution solution NOUN eurjchem-1613 62 20 was be AUX eurjchem-1613 62 21 titrated titrate VERB eurjchem-1613 62 22 with with ADP eurjchem-1613 62 23 standardized standardized ADJ eurjchem-1613 62 24 sodium sodium NOUN eurjchem-1613 62 25 hydroxide hydroxide NOUN eurjchem-1613 62 26 and and CCONJ eurjchem-1613 62 27 the the DET eurjchem-1613 62 28 ph ph ADJ eurjchem-1613 62 29 correction correction NOUN eurjchem-1613 62 30 equation equation NOUN eurjchem-1613 62 31 was be AUX eurjchem-1613 62 32 acquired acquire VERB eurjchem-1613 63 1 [ [ X eurjchem-1613 63 2 36 36 NUM eurjchem-1613 63 3 ] ] PUNCT eurjchem-1613 63 4 . . PUNCT eurjchem-1613 64 1 2.3 2.3 NUM eurjchem-1613 64 2 . . PUNCT eurjchem-1613 65 1 the the DET eurjchem-1613 65 2 method method NOUN eurjchem-1613 65 3 for for ADP eurjchem-1613 65 4 determination determination NOUN eurjchem-1613 65 5 of of ADP eurjchem-1613 65 6 stability stability NOUN eurjchem-1613 65 7 constant constant VERB eurjchem-1613 65 8 the the DET eurjchem-1613 65 9 method method NOUN eurjchem-1613 65 10 for for ADP eurjchem-1613 65 11 determination determination NOUN eurjchem-1613 65 12 of of ADP eurjchem-1613 65 13 stability stability NOUN eurjchem-1613 65 14 constant constant ADJ eurjchem-1613 65 15 was be AUX eurjchem-1613 65 16 established establish VERB eurjchem-1613 65 17 by by ADP eurjchem-1613 65 18 j. j. PROPN eurjchem-1613 65 19 bjerrum bjerrum PROPN eurjchem-1613 66 1 [ [ X eurjchem-1613 66 2 2 2 NUM eurjchem-1613 66 3 ] ] PUNCT eurjchem-1613 66 4 . . PUNCT eurjchem-1613 67 1 he he PRON eurjchem-1613 67 2 measured measure VERB eurjchem-1613 67 3 the the DET eurjchem-1613 67 4 stability stability NOUN eurjchem-1613 67 5 of of ADP eurjchem-1613 67 6 metal metal NOUN eurjchem-1613 67 7 amines amine NOUN eurjchem-1613 67 8 using use VERB eurjchem-1613 67 9 the the DET eurjchem-1613 67 10 concentration concentration NOUN eurjchem-1613 67 11 of of ADP eurjchem-1613 67 12 metal metal NOUN eurjchem-1613 67 13 free free ADJ eurjchem-1613 67 14 ligand ligand NOUN eurjchem-1613 67 15 and and CCONJ eurjchem-1613 67 16 the the DET eurjchem-1613 67 17 total total ADJ eurjchem-1613 67 18 ligand ligand ADJ eurjchem-1613 67 19 concentration concentration NOUN eurjchem-1613 67 20 . . PUNCT eurjchem-1613 68 1 the the DET eurjchem-1613 68 2 key key NOUN eurjchem-1613 68 3 to to ADP eurjchem-1613 68 4 his his PRON eurjchem-1613 68 5 method method NOUN eurjchem-1613 68 6 was be AUX eurjchem-1613 68 7 the the DET eurjchem-1613 68 8 use use NOUN eurjchem-1613 68 9 of of ADP eurjchem-1613 68 10 the the DET eurjchem-1613 68 11 then then ADV eurjchem-1613 68 12 recently recently ADV eurjchem-1613 68 13 developed develop VERB eurjchem-1613 68 14 glass glass NOUN eurjchem-1613 68 15 electrode electrode NOUN eurjchem-1613 68 16 and and CCONJ eurjchem-1613 68 17 ph ph ADJ eurjchem-1613 68 18 meter meter NOUN eurjchem-1613 68 19 . . PUNCT eurjchem-1613 69 1 later later PROPN eurjchem-1613 69 2 m. m. PROPN eurjchem-1613 69 3 calvin calvin PROPN eurjchem-1613 69 4 and and CCONJ eurjchem-1613 69 5 k.w k.w PROPN eurjchem-1613 69 6 . . PROPN eurjchem-1613 69 7 wilson wilson PROPN eurjchem-1613 70 1 [ [ X eurjchem-1613 70 2 3 3 NUM eurjchem-1613 70 3 ] ] X eurjchem-1613 70 4 modified modify VERB eurjchem-1613 70 5 the the DET eurjchem-1613 70 6 method method NOUN eurjchem-1613 70 7 so so SCONJ eurjchem-1613 70 8 that that SCONJ eurjchem-1613 70 9 ph ph ADJ eurjchem-1613 70 10 measurements measurement NOUN eurjchem-1613 70 11 made make VERB eurjchem-1613 70 12 during during ADP eurjchem-1613 70 13 titration titration NOUN eurjchem-1613 70 14 of of ADP eurjchem-1613 70 15 a a DET eurjchem-1613 70 16 solution solution NOUN eurjchem-1613 70 17 containing contain VERB eurjchem-1613 70 18 chelating chelate VERB eurjchem-1613 70 19 agent agent NOUN eurjchem-1613 70 20 in in ADP eurjchem-1613 70 21 the the DET eurjchem-1613 70 22 presence presence NOUN eurjchem-1613 70 23 and and CCONJ eurjchem-1613 70 24 in in ADP eurjchem-1613 70 25 the the DET eurjchem-1613 70 26 absence absence NOUN eurjchem-1613 70 27 of of ADP eurjchem-1613 70 28 a a DET eurjchem-1613 70 29 metal metal NOUN eurjchem-1613 70 30 ion ion NOUN eurjchem-1613 70 31 , , PUNCT eurjchem-1613 70 32 with with ADP eurjchem-1613 70 33 a a DET eurjchem-1613 70 34 base base NOUN eurjchem-1613 70 35 could could AUX eurjchem-1613 70 36 be be AUX eurjchem-1613 70 37 used use VERB eurjchem-1613 70 38 to to PART eurjchem-1613 70 39 calculate calculate VERB eurjchem-1613 70 40 the the DET eurjchem-1613 70 41 amount amount NOUN eurjchem-1613 70 42 of of ADP eurjchem-1613 70 43 hydrogen hydrogen NOUN eurjchem-1613 70 44 ions ion NOUN eurjchem-1613 70 45 released release VERB eurjchem-1613 70 46 in in ADP eurjchem-1613 70 47 the the DET eurjchem-1613 70 48 reaction reaction NOUN eurjchem-1613 70 49 vessel vessel NOUN eurjchem-1613 70 50 , , PUNCT eurjchem-1613 70 51 the the DET eurjchem-1613 70 52 free free ADJ eurjchem-1613 70 53 ligand ligand NOUN eurjchem-1613 70 54 exponent exponent NOUN eurjchem-1613 70 55 , , PUNCT eurjchem-1613 70 56 the the DET eurjchem-1613 70 57 degree degree NOUN eurjchem-1613 70 58 of of ADP eurjchem-1613 70 59 formation formation NOUN eurjchem-1613 70 60 of of ADP eurjchem-1613 70 61 the the DET eurjchem-1613 70 62 system system NOUN eurjchem-1613 70 63 , , PUNCT eurjchem-1613 70 64 , , PUNCT eurjchem-1613 70 65 and and CCONJ eurjchem-1613 70 66 the the DET eurjchem-1613 70 67 stability stability NOUN eurjchem-1613 70 68 of of ADP eurjchem-1613 70 69 the the DET eurjchem-1613 70 70 metal‐ligand metal‐ligand NOUN eurjchem-1613 70 71 complex complex NOUN eurjchem-1613 70 72 . . PUNCT eurjchem-1613 71 1 if if SCONJ eurjchem-1613 71 2 we we PRON eurjchem-1613 71 3 assume assume VERB eurjchem-1613 71 4 the the DET eurjchem-1613 71 5 presence presence NOUN eurjchem-1613 71 6 of of ADP eurjchem-1613 71 7 the the DET eurjchem-1613 71 8 reacting react VERB eurjchem-1613 71 9 species specie NOUN eurjchem-1613 71 10 h2l+ h2l+ NOUN eurjchem-1613 71 11 as as ADP eurjchem-1613 71 12 protonated protonated ADJ eurjchem-1613 71 13 amino amino NOUN eurjchem-1613 71 14 acid acid NOUN eurjchem-1613 71 15 , , PUNCT eurjchem-1613 71 16 hl hl NOUN eurjchem-1613 71 17 as as ADP eurjchem-1613 71 18 the the DET eurjchem-1613 71 19 amino amino NOUN eurjchem-1613 71 20 acid acid NOUN eurjchem-1613 71 21 , , PUNCT eurjchem-1613 71 22 and and CCONJ eurjchem-1613 71 23 l‐ l‐ PRON eurjchem-1613 71 24 the the DET eurjchem-1613 71 25 anion anion NOUN eurjchem-1613 71 26 of of ADP eurjchem-1613 71 27 amino amino NOUN eurjchem-1613 71 28 acid acid NOUN eurjchem-1613 71 29 , , PUNCT eurjchem-1613 71 30 then then ADV eurjchem-1613 71 31 the the DET eurjchem-1613 71 32 following follow VERB eurjchem-1613 71 33 reactions reaction NOUN eurjchem-1613 71 34 may may AUX eurjchem-1613 71 35 occur occur VERB eurjchem-1613 71 36 in in ADP eurjchem-1613 71 37 the the DET eurjchem-1613 71 38 solution solution NOUN eurjchem-1613 71 39 . . PUNCT eurjchem-1613 72 1 h h NOUN eurjchem-1613 73 1 l l NOUN eurjchem-1613 73 2 ⇌ ⇌ PROPN eurjchem-1613 73 3 hl hl NOUN eurjchem-1613 73 4 h h NOUN eurjchem-1613 73 5 ( ( PUNCT eurjchem-1613 73 6 1 1 NUM eurjchem-1613 73 7 ) ) PUNCT eurjchem-1613 73 8 k k NOUN eurjchem-1613 73 9 ( ( PUNCT eurjchem-1613 73 10 2 2 X eurjchem-1613 73 11 ) ) PUNCT eurjchem-1613 73 12 hl hl NOUN eurjchem-1613 73 13 ⇌ ⇌ PROPN eurjchem-1613 73 14 l l PROPN eurjchem-1613 73 15 h h NOUN eurjchem-1613 73 16 ( ( PUNCT eurjchem-1613 73 17 3 3 NUM eurjchem-1613 73 18 ) ) PUNCT eurjchem-1613 73 19 k k NOUN eurjchem-1613 73 20 ( ( PUNCT eurjchem-1613 73 21 4 4 X eurjchem-1613 73 22 ) ) PUNCT eurjchem-1613 73 23 m m VERB eurjchem-1613 73 24 hl hl NOUN eurjchem-1613 73 25 ⇌ ⇌ PROPN eurjchem-1613 73 26 ml ml PROPN eurjchem-1613 73 27 h h PROPN eurjchem-1613 73 28 ( ( PUNCT eurjchem-1613 73 29 5 5 NUM eurjchem-1613 73 30 ) ) PUNCT eurjchem-1613 73 31 k k NOUN eurjchem-1613 73 32 ( ( PUNCT eurjchem-1613 73 33 6 6 NUM eurjchem-1613 73 34 ) ) PUNCT eurjchem-1613 74 1 ml ml NOUN eurjchem-1613 74 2 l l NOUN eurjchem-1613 74 3 ⇌ ⇌ PROPN eurjchem-1613 74 4 ml ml X eurjchem-1613 74 5 ( ( PUNCT eurjchem-1613 74 6 7 7 NUM eurjchem-1613 74 7 ) ) PUNCT eurjchem-1613 74 8 k k NOUN eurjchem-1613 74 9 ( ( PUNCT eurjchem-1613 74 10 8) 8) NUM eurjchem-1613 74 11 here here ADV eurjchem-1613 74 12 kf1 kf1 PROPN eurjchem-1613 74 13 and and CCONJ eurjchem-1613 74 14 kf2 kf2 PROPN eurjchem-1613 74 15 are be AUX eurjchem-1613 74 16 the the DET eurjchem-1613 74 17 first first ADJ eurjchem-1613 74 18 and and CCONJ eurjchem-1613 74 19 the the DET eurjchem-1613 74 20 second second ADJ eurjchem-1613 74 21 stability stability NOUN eurjchem-1613 74 22 constants constant NOUN eurjchem-1613 74 23 of of ADP eurjchem-1613 74 24 the the DET eurjchem-1613 74 25 complex complex NOUN eurjchem-1613 74 26 . . PUNCT eurjchem-1613 75 1 we we PRON eurjchem-1613 75 2 define define VERB eurjchem-1613 75 3 as as ADP eurjchem-1613 75 4 : : PUNCT eurjchem-1613 75 5 n n CCONJ eurjchem-1613 75 6 ( ( PUNCT eurjchem-1613 75 7 9 9 X eurjchem-1613 75 8 ) ) PUNCT eurjchem-1613 75 9 the the DET eurjchem-1613 75 10 concentration concentration NOUN eurjchem-1613 75 11 of of ADP eurjchem-1613 75 12 free free ADJ eurjchem-1613 75 13 ligand ligand NOUN eurjchem-1613 75 14 is be AUX eurjchem-1613 75 15 the the DET eurjchem-1613 75 16 sum sum NOUN eurjchem-1613 75 17 of of ADP eurjchem-1613 75 18 concent‐ concent‐ NOUN eurjchem-1613 75 19 ration ration NOUN eurjchem-1613 75 20 of of ADP eurjchem-1613 75 21 contained contain VERB eurjchem-1613 75 22 ligand ligand NOUN eurjchem-1613 75 23 species specie NOUN eurjchem-1613 75 24 at at ADP eurjchem-1613 75 25 different different ADJ eurjchem-1613 75 26 form form NOUN eurjchem-1613 75 27 , , PUNCT eurjchem-1613 75 28 i.e. i.e. X eurjchem-1613 75 29 l l NOUN eurjchem-1613 75 30 h h NOUN eurjchem-1613 75 31 l l NOUN eurjchem-1613 75 32 hl hl NOUN eurjchem-1613 75 33 l l NOUN eurjchem-1613 75 34 ( ( PUNCT eurjchem-1613 75 35 10 10 NUM eurjchem-1613 75 36 ) ) PUNCT eurjchem-1613 75 37 the the DET eurjchem-1613 75 38 bound bind VERB eurjchem-1613 75 39 ligand ligand NOUN eurjchem-1613 75 40 concentration concentration NOUN eurjchem-1613 75 41 is be AUX eurjchem-1613 75 42 then then ADV eurjchem-1613 75 43 estimated estimate VERB eurjchem-1613 75 44 as as ADP eurjchem-1613 75 45 : : PUNCT eurjchem-1613 75 46 c c NOUN eurjchem-1613 75 47 c c PROPN eurjchem-1613 75 48 c c X eurjchem-1613 75 49 ( ( PUNCT eurjchem-1613 75 50 11 11 NUM eurjchem-1613 75 51 ) ) PUNCT eurjchem-1613 75 52 after after ADP eurjchem-1613 75 53 rearrangement rearrangement NOUN eurjchem-1613 75 54 and and CCONJ eurjchem-1613 75 55 substitutions substitution NOUN eurjchem-1613 75 56 we we PRON eurjchem-1613 75 57 have have VERB eurjchem-1613 75 58 : : PUNCT eurjchem-1613 75 59 n n X eurjchem-1613 75 60 ( ( PUNCT eurjchem-1613 75 61 12 12 NUM eurjchem-1613 75 62 ) ) PUNCT eurjchem-1613 75 63 where where SCONJ eurjchem-1613 75 64 th2l+ th2l+ PROPN eurjchem-1613 75 65 is be AUX eurjchem-1613 75 66 the the DET eurjchem-1613 75 67 total total ADJ eurjchem-1613 75 68 concentration concentration NOUN eurjchem-1613 75 69 of of ADP eurjchem-1613 75 70 h2l+ h2l+ PROPN eurjchem-1613 75 71 . . PUNCT eurjchem-1613 76 1 then then ADV eurjchem-1613 76 2 : : PUNCT eurjchem-1613 76 3 n n X eurjchem-1613 76 4 ( ( PUNCT eurjchem-1613 76 5 13 13 NUM eurjchem-1613 76 6 ) ) PUNCT eurjchem-1613 76 7 we we PRON eurjchem-1613 76 8 know know VERB eurjchem-1613 76 9 that that PRON eurjchem-1613 76 10 : : PUNCT eurjchem-1613 76 11 t t PROPN eurjchem-1613 76 12 m m VERB eurjchem-1613 76 13 ml ml INTJ eurjchem-1613 76 14 ml ml PROPN eurjchem-1613 76 15 ( ( PUNCT eurjchem-1613 76 16 14 14 NUM eurjchem-1613 76 17 ) ) PUNCT eurjchem-1613 76 18 t t NOUN eurjchem-1613 76 19 hl hl NOUN eurjchem-1613 76 20 ml ml PROPN eurjchem-1613 76 21 2 2 NUM eurjchem-1613 76 22 ml ml NOUN eurjchem-1613 76 23 ( ( PUNCT eurjchem-1613 76 24 15 15 NUM eurjchem-1613 76 25 ) ) PUNCT eurjchem-1613 76 26 perchloric perchloric ADJ eurjchem-1613 76 27 acid acid NOUN eurjchem-1613 76 28 was be AUX eurjchem-1613 76 29 added add VERB eurjchem-1613 76 30 to to ADP eurjchem-1613 76 31 titrand titrand NOUN eurjchem-1613 76 32 solution solution NOUN eurjchem-1613 76 33 in in ADP eurjchem-1613 76 34 excess excess NOUN eurjchem-1613 76 35 to to PART eurjchem-1613 76 36 prevent prevent VERB eurjchem-1613 76 37 the the DET eurjchem-1613 76 38 hydrolysis hydrolysis NOUN eurjchem-1613 76 39 of of ADP eurjchem-1613 76 40 metal metal NOUN eurjchem-1613 76 41 ion ion NOUN eurjchem-1613 76 42 . . PUNCT eurjchem-1613 77 1 clo clo PROPN eurjchem-1613 77 2 t t PROPN eurjchem-1613 77 3 2 2 NUM eurjchem-1613 77 4 t t PROPN eurjchem-1613 77 5 ( ( PUNCT eurjchem-1613 77 6 16 16 NUM eurjchem-1613 77 7 ) ) PUNCT eurjchem-1613 77 8 t t PROPN eurjchem-1613 77 9 is be AUX eurjchem-1613 77 10 total total ADJ eurjchem-1613 77 11 concentration concentration NOUN eurjchem-1613 77 12 of of ADP eurjchem-1613 77 13 added add VERB eurjchem-1613 77 14 perchloric perchloric ADJ eurjchem-1613 77 15 acid acid NOUN eurjchem-1613 77 16 to to ADP eurjchem-1613 77 17 titrand titrand NOUN eurjchem-1613 77 18 . . PUNCT eurjchem-1613 78 1 ml ml ADP eurjchem-1613 78 2 2 2 NUM eurjchem-1613 78 3 ml ml NOUN eurjchem-1613 78 4 na na ADP eurjchem-1613 78 5 t t PROPN eurjchem-1613 78 6 h h NOUN eurjchem-1613 78 7 ( ( PUNCT eurjchem-1613 78 8 17 17 NUM eurjchem-1613 78 9 ) ) PUNCT eurjchem-1613 78 10 n n CCONJ eurjchem-1613 78 11 ( ( PUNCT eurjchem-1613 78 12 18 18 NUM eurjchem-1613 78 13 ) ) PUNCT eurjchem-1613 78 14 finally finally ADV eurjchem-1613 78 15 , , PUNCT eurjchem-1613 78 16 we we PRON eurjchem-1613 78 17 will will AUX eurjchem-1613 78 18 have have VERB eurjchem-1613 78 19 : : PUNCT eurjchem-1613 78 20 hl hl X eurjchem-1613 78 21 ( ( PUNCT eurjchem-1613 78 22 19 19 NUM eurjchem-1613 78 23 ) ) PUNCT eurjchem-1613 78 24 from from ADP eurjchem-1613 78 25 plot plot NOUN eurjchem-1613 78 26 of of ADP eurjchem-1613 78 27 phl phl NOUN eurjchem-1613 78 28 versus versus ADP eurjchem-1613 78 29 , , PUNCT eurjchem-1613 78 30 the the DET eurjchem-1613 78 31 stability stability NOUN eurjchem-1613 78 32 constant constant ADJ eurjchem-1613 78 33 could could AUX eurjchem-1613 78 34 be be AUX eurjchem-1613 78 35 calculated calculate VERB eurjchem-1613 78 36 . . PUNCT eurjchem-1613 79 1 k k X eurjchem-1613 79 2 ( ( PUNCT eurjchem-1613 79 3 20 20 NUM eurjchem-1613 79 4 ) ) PUNCT eurjchem-1613 79 5 k k NOUN eurjchem-1613 79 6 ( ( PUNCT eurjchem-1613 79 7 21 21 NUM eurjchem-1613 79 8 ) ) PUNCT eurjchem-1613 79 9 all all DET eurjchem-1613 79 10 our our PRON eurjchem-1613 79 11 calculations calculation NOUN eurjchem-1613 79 12 in in ADP eurjchem-1613 79 13 this this DET eurjchem-1613 79 14 work work NOUN eurjchem-1613 79 15 were be AUX eurjchem-1613 79 16 executed execute VERB eurjchem-1613 79 17 by by ADP eurjchem-1613 79 18 grcβeta grcβeta PROPN eurjchem-1613 79 19 computer‐program computer‐program PROPN eurjchem-1613 79 20 developed develop VERB eurjchem-1613 79 21 in in ADP eurjchem-1613 79 22 our our PRON eurjchem-1613 79 23 lab lab NOUN eurjchem-1613 79 24 . . PUNCT eurjchem-1613 80 1 the the DET eurjchem-1613 80 2 software software NOUN eurjchem-1613 80 3 inputs input NOUN eurjchem-1613 80 4 are be AUX eurjchem-1613 80 5 a a DET eurjchem-1613 80 6 ) ) PUNCT eurjchem-1613 80 7 initial initial ADJ eurjchem-1613 80 8 volume volume NOUN eurjchem-1613 80 9 of of ADP eurjchem-1613 80 10 solution solution NOUN eurjchem-1613 80 11 containing contain VERB eurjchem-1613 80 12 the the DET eurjchem-1613 80 13 amino amino NOUN eurjchem-1613 80 14 acid acid NOUN eurjchem-1613 80 15 , , PUNCT eurjchem-1613 80 16 metal metal NOUN eurjchem-1613 80 17 ion ion NOUN eurjchem-1613 80 18 , , PUNCT eurjchem-1613 80 19 and and CCONJ eurjchem-1613 80 20 perchloric perchloric ADJ eurjchem-1613 80 21 acid acid PROPN eurjchem-1613 80 22 , , PUNCT eurjchem-1613 80 23 b b NOUN eurjchem-1613 80 24 ) ) PUNCT eurjchem-1613 80 25 the the DET eurjchem-1613 80 26 concentration concentration NOUN eurjchem-1613 80 27 of of ADP eurjchem-1613 80 28 perchloric perchloric ADJ eurjchem-1613 80 29 acid acid NOUN eurjchem-1613 80 30 , , PUNCT eurjchem-1613 80 31 c c X eurjchem-1613 80 32 ) ) PUNCT eurjchem-1613 80 33 the the DET eurjchem-1613 80 34 concentration concentration NOUN eurjchem-1613 80 35 of of ADP eurjchem-1613 80 36 sodium sodium NOUN eurjchem-1613 80 37 hydroxide hydroxide NOUN eurjchem-1613 80 38 , , PUNCT eurjchem-1613 80 39 d d X eurjchem-1613 80 40 ) ) PUNCT eurjchem-1613 80 41 the the DET eurjchem-1613 80 42 concentration concentration NOUN eurjchem-1613 80 43 of of ADP eurjchem-1613 80 44 amino amino NOUN eurjchem-1613 80 45 acid acid NOUN eurjchem-1613 80 46 , , PUNCT eurjchem-1613 80 47 and and CCONJ eurjchem-1613 80 48 e e X eurjchem-1613 80 49 ) ) PUNCT eurjchem-1613 80 50 pka1 pka1 NOUN eurjchem-1613 80 51 and and CCONJ eurjchem-1613 80 52 pka2 pka2 NOUN eurjchem-1613 80 53 of of ADP eurjchem-1613 80 54 the the DET eurjchem-1613 80 55 amino amino NOUN eurjchem-1613 80 56 acid acid NOUN eurjchem-1613 80 57 in in ADP eurjchem-1613 80 58 the the DET eurjchem-1613 80 59 specified specified ADJ eurjchem-1613 80 60 medium medium NOUN eurjchem-1613 80 61 and and CCONJ eurjchem-1613 80 62 at at ADP eurjchem-1613 80 63 desired desire VERB eurjchem-1613 80 64 ionic ionic ADJ eurjchem-1613 80 65 strength strength NOUN eurjchem-1613 80 66 which which PRON eurjchem-1613 80 67 was be AUX eurjchem-1613 80 68 found find VERB eurjchem-1613 80 69 in in ADP eurjchem-1613 80 70 the the DET eurjchem-1613 80 71 literature literature NOUN eurjchem-1613 80 72 [ [ X eurjchem-1613 80 73 37 37 NUM eurjchem-1613 80 74 ] ] PUNCT eurjchem-1613 80 75 . . PUNCT eurjchem-1613 81 1 in in ADP eurjchem-1613 81 2 water water NOUN eurjchem-1613 81 3 : : PUNCT eurjchem-1613 81 4 dioxane dioxane NOUN eurjchem-1613 81 5 mixture mixture NOUN eurjchem-1613 81 6 ( ( PUNCT eurjchem-1613 81 7 50:50 50:50 NUM eurjchem-1613 81 8 , , PUNCT eurjchem-1613 81 9 v v NOUN eurjchem-1613 81 10 : : PUNCT eurjchem-1613 81 11 v v NOUN eurjchem-1613 81 12 ) ) PUNCT eurjchem-1613 81 13 and and CCONJ eurjchem-1613 81 14 0.1 0.1 NUM eurjchem-1613 81 15 m m NOUN eurjchem-1613 81 16 nano3 nano3 PROPN eurjchem-1613 81 17 , , PUNCT eurjchem-1613 81 18 trp trp PROPN eurjchem-1613 81 19 has have AUX eurjchem-1613 81 20 pka1 pka1 VERB eurjchem-1613 81 21 = = PROPN eurjchem-1613 81 22 3.47 3.47 NUM eurjchem-1613 81 23 and and CCONJ eurjchem-1613 81 24 pka2 pka2 NOUN eurjchem-1613 81 25 = = NUM eurjchem-1613 82 1 10.22 10.22 NUM eurjchem-1613 82 2 . . PUNCT eurjchem-1613 83 1 after after ADP eurjchem-1613 83 2 insertion insertion NOUN eurjchem-1613 83 3 of of ADP eurjchem-1613 83 4 the the DET eurjchem-1613 83 5 pertinent pertinent ADJ eurjchem-1613 83 6 values value NOUN eurjchem-1613 83 7 , , PUNCT eurjchem-1613 83 8 the the DET eurjchem-1613 83 9 software software NOUN eurjchem-1613 83 10 plots plot VERB eurjchem-1613 83 11 the the DET eurjchem-1613 83 12 corrected correct VERB eurjchem-1613 83 13 ph ph NOUN eurjchem-1613 83 14 of of ADP eurjchem-1613 83 15 the the DET eurjchem-1613 83 16 titrand titrand NOUN eurjchem-1613 83 17 solution solution NOUN eurjchem-1613 83 18 versus versus ADP eurjchem-1613 83 19 the the DET eurjchem-1613 83 20 concentration concentration NOUN eurjchem-1613 83 21 of of ADP eurjchem-1613 83 22 added add VERB eurjchem-1613 83 23 standar‐ standar‐ PROPN eurjchem-1613 83 24 dized dize VERB eurjchem-1613 83 25 naoh naoh NOUN eurjchem-1613 83 26 , , PUNCT eurjchem-1613 83 27 plus plus CCONJ eurjchem-1613 83 28 drawing draw VERB eurjchem-1613 83 29 two two NUM eurjchem-1613 83 30 curves curve NOUN eurjchem-1613 83 31 , , PUNCT eurjchem-1613 83 32 one one NUM eurjchem-1613 83 33 for for ADP eurjchem-1613 83 34 a a DET eurjchem-1613 83 35 = = SYM eurjchem-1613 83 36 0.5 0.5 NUM eurjchem-1613 83 37 and and CCONJ eurjchem-1613 83 38 the the DET eurjchem-1613 83 39 other other ADJ eurjchem-1613 83 40 for for ADP eurjchem-1613 83 41 = = PROPN eurjchem-1613 83 42 1.5 1.5 NUM eurjchem-1613 83 43 . . PUNCT eurjchem-1613 84 1 the the DET eurjchem-1613 84 2 intersections intersection NOUN eurjchem-1613 84 3 of of ADP eurjchem-1613 84 4 the the DET eurjchem-1613 84 5 potentiometric potentiometric ADJ eurjchem-1613 84 6 titration titration NOUN eurjchem-1613 84 7 curve curve NOUN eurjchem-1613 84 8 with with ADP eurjchem-1613 84 9 these these DET eurjchem-1613 84 10 two two NUM eurjchem-1613 84 11 curves curve NOUN eurjchem-1613 84 12 produce produce VERB eurjchem-1613 84 13 two two NUM eurjchem-1613 84 14 points point NOUN eurjchem-1613 84 15 ( ( PUNCT eurjchem-1613 84 16 figure figure NOUN eurjchem-1613 84 17 1 1 NUM eurjchem-1613 84 18 ) ) PUNCT eurjchem-1613 84 19 whose whose DET eurjchem-1613 84 20 corresponding corresponding ADJ eurjchem-1613 84 21 phs phs NOUN eurjchem-1613 84 22 will will AUX eurjchem-1613 84 23 be be AUX eurjchem-1613 84 24 used use VERB eurjchem-1613 84 25 to to PART eurjchem-1613 84 26 evaluate evaluate VERB eurjchem-1613 84 27 the the DET eurjchem-1613 84 28 respective respective ADJ eurjchem-1613 84 29 stability stability NOUN eurjchem-1613 84 30 constants constant NOUN eurjchem-1613 84 31 of of ADP eurjchem-1613 84 32 the the DET eurjchem-1613 84 33 metal metal NOUN eurjchem-1613 84 34 ion‐amino ion‐amino NOUN eurjchem-1613 84 35 acid acid NOUN eurjchem-1613 84 36 complexes complex NOUN eurjchem-1613 84 37 . . PUNCT eurjchem-1613 85 1 table table NOUN eurjchem-1613 85 2 1 1 NUM eurjchem-1613 85 3 . . PUNCT eurjchem-1613 86 1 compa compa PROPN eurjchem-1613 86 2 log log PROPN eurjchem-1613 86 3 kf kf PROPN eurjchem-1613 86 4 log log PROPN eurjchem-1613 86 5 kf1 kf1 PROPN eurjchem-1613 86 6 log log PROPN eurjchem-1613 86 7 kf2 kf2 PROPN eurjchem-1613 86 8 additiona additiona PROPN eurjchem-1613 86 9 second second ADJ eurjchem-1613 86 10 deriv deriv PROPN eurjchem-1613 86 11 points point NOUN eurjchem-1613 86 12 . . PUNCT eurjchem-1613 87 1 thermod thermod PROPN eurjchem-1613 87 2 δs δs PROPN eurjchem-1613 87 3 ° ° PROPN eurjchem-1613 87 4 values value NOUN eurjchem-1613 87 5 . . PUNCT eurjchem-1613 88 1 t t PROPN eurjchem-1613 88 2 calculated calculate VERB eurjchem-1613 88 3 fro fro NOUN eurjchem-1613 88 4 ∆ ∆ PROPN eurjchem-1613 88 5 ° ° PROPN eurjchem-1613 89 1 rt rt PROPN eurjchem-1613 89 2 ln ln ADV eurjchem-1613 89 3 the the DET eurjchem-1613 89 4 plot plot NOUN eurjchem-1613 89 5 slop slop NOUN eurjchem-1613 89 6 equals equal VERB eurjchem-1613 89 7 to to PART eurjchem-1613 89 8 slope slope VERB eurjchem-1613 89 9 ∆ ∆ PROPN eurjchem-1613 89 10 . . PUNCT eurjchem-1613 90 1 using use VERB eurjchem-1613 90 2 the the PRON eurjchem-1613 90 3 for for ADP eurjchem-1613 90 4 calculatin calculatin NOUN eurjchem-1613 90 5 ∆ ∆ PROPN eurjchem-1613 90 6 ° ° NOUN eurjchem-1613 91 1 ∆ ∆ PROPN eurjchem-1613 91 2 ° ° NOUN eurjchem-1613 91 3 regarding regard VERB eurjchem-1613 91 4 depends depend VERB eurjchem-1613 91 5 on on ADP eurjchem-1613 91 6 th th NOUN eurjchem-1613 91 7 reaction reaction NOUN eurjchem-1613 91 8 of of ADP eurjchem-1613 91 9 : : PUNCT eurjchem-1613 91 10 aa aa PROPN eurjchem-1613 91 11 + + CCONJ eurjchem-1613 91 12 bb bb INTJ eurjchem-1613 91 13 → → SYM eurjchem-1613 91 14 pro pro X eurjchem-1613 91 15 the the DET eurjchem-1613 91 16 rate rate NOUN eurjchem-1613 91 17 l l NOUN eurjchem-1613 91 18 rate rate NOUN eurjchem-1613 91 19 = = PROPN eurjchem-1613 91 20 k×[a]n k×[a]n NOUN eurjchem-1613 91 21 where where SCONJ eurjchem-1613 91 22 n n NUM eurjchem-1613 91 23 and and CCONJ eurjchem-1613 91 24 depend depend VERB eurjchem-1613 91 25 on on ADP eurjchem-1613 91 26 th th NUM eurjchem-1613 91 27 reaction reaction NOUN eurjchem-1613 91 28 , , PUNCT eurjchem-1613 91 29 the the DET eurjchem-1613 91 30 i i PROPN eurjchem-1613 91 31 regarding regard VERB eurjchem-1613 91 32 initial initial ADJ eurjchem-1613 91 33 concen concen PROPN eurjchem-1613 91 34 t t PROPN eurjchem-1613 91 35 a a X eurjchem-1613 91 36 by by ADP eurjchem-1613 91 37 taking take VERB eurjchem-1613 91 38 we we PRON eurjchem-1613 91 39 have have VERB eurjchem-1613 91 40 : : PUNCT eurjchem-1613 91 41 log log VERB eurjchem-1613 91 42 t t PROPN eurjchem-1613 91 43 log log VERB eurjchem-1613 91 44 the the DET eurjchem-1613 91 45 outpu outpu NOUN eurjchem-1613 91 46 slope slope NOUN eurjchem-1613 91 47 of of ADP eurjchem-1613 91 48 ( ( PUNCT eurjchem-1613 91 49 1‐n 1‐n NUM eurjchem-1613 91 50 amino amino NOUN eurjchem-1613 91 51 acid acid NOUN eurjchem-1613 91 52 is be AUX eurjchem-1613 91 53 of of ADP eurjchem-1613 91 54 the the DET eurjchem-1613 91 55 reacti reacti NOUN eurjchem-1613 91 56 concentration concentration NOUN eurjchem-1613 91 57 the the DET eurjchem-1613 91 58 obtained obtain VERB eurjchem-1613 91 59 concentration concentration NOUN eurjchem-1613 91 60 correspondin correspondin VERB eurjchem-1613 91 61 half half NOUN eurjchem-1613 91 62 of of ADP eurjchem-1613 91 63 this this PRON eurjchem-1613 91 64 c c NOUN eurjchem-1613 91 65 recorded record VERB eurjchem-1613 91 66 . . PUNCT eurjchem-1613 92 1 th th X eurjchem-1613 92 2 time time NOUN eurjchem-1613 92 3 required require VERB eurjchem-1613 92 4 half half NOUN eurjchem-1613 92 5 . . PUNCT eurjchem-1613 93 1 by by ADP eurjchem-1613 93 2 findi findi NOUN eurjchem-1613 93 3 repeated repeat VERB eurjchem-1613 93 4 unt unt NOUN eurjchem-1613 93 5 versus versus ADP eurjchem-1613 93 6 log log PROPN eurjchem-1613 93 7 t1/2 t1/2 NOUN eurjchem-1613 93 8 using use VERB eurjchem-1613 93 9 exp exp NOUN eurjchem-1613 93 10 by by ADP eurjchem-1613 93 11 substituti substituti NOUN eurjchem-1613 93 12 g g PROPN eurjchem-1613 93 13 rison rison PROPN eurjchem-1613 93 14 between between ADP eurjchem-1613 93 15 our our PRON eurjchem-1613 93 16 co co X eurjchem-1613 93 17 ( ( PUNCT eurjchem-1613 93 18 ii)‐trp ii)‐trp PROPN eurjchem-1613 93 19 4.41 4.41 NUM eurjchem-1613 93 20 ( ( PUNCT eurjchem-1613 93 21 3.86 3.86 NUM eurjchem-1613 93 22 ) ) PUNCT eurjchem-1613 93 23 7.98 7.98 NUM eurjchem-1613 93 24 ( ( PUNCT eurjchem-1613 93 25 ‐ ‐ NOUN eurjchem-1613 93 26 ) ) PUNCT eurjchem-1613 93 27 ally ally NOUN eurjchem-1613 93 28 the the DET eurjchem-1613 93 29 softwa softwa PROPN eurjchem-1613 93 30 vative vative ADJ eurjchem-1613 93 31 of of ADP eurjchem-1613 93 32 d‐ph d‐ph PROPN eurjchem-1613 93 33 ynamic ynamic ADJ eurjchem-1613 93 34 study study NOUN eurjchem-1613 93 35 i i PRON eurjchem-1613 93 36 the the DET eurjchem-1613 93 37 gibb gibb PROPN eurjchem-1613 93 38 ’s ’s PART eurjchem-1613 93 39 fre fre NOUN eurjchem-1613 93 40 om om ADP eurjchem-1613 93 41 the the DET eurjchem-1613 93 42 equation equation NOUN eurjchem-1613 93 43 n n PROPN eurjchem-1613 93 44 of of ADP eurjchem-1613 93 45 log log NOUN eurjchem-1613 93 46 kf kf PROPN eurjchem-1613 93 47 versu versu PROPN eurjchem-1613 93 48 o o NOUN eurjchem-1613 93 49 : : PUNCT eurjchem-1613 93 50 ° ° ADP eurjchem-1613 93 51 e e X eurjchem-1613 93 52 equation equation NOUN eurjchem-1613 93 53 ( ( PUNCT eurjchem-1613 93 54 23 23 NUM eurjchem-1613 93 55 ) ) PUNCT eurjchem-1613 93 56 , , PUNCT eurjchem-1613 93 57 ng ng PROPN eurjchem-1613 93 58 δs δs PROPN eurjchem-1613 93 59 ° ° NOUN eurjchem-1613 93 60 we we PRON eurjchem-1613 93 61 have have VERB eurjchem-1613 93 62 : : PUNCT eurjchem-1613 93 63 t∆ t∆ PROPN eurjchem-1613 93 64 ° ° NOUN eurjchem-1613 93 65 g g PROPN eurjchem-1613 93 66 kinetics kinetic NOUN eurjchem-1613 93 67 stud stud NOUN eurjchem-1613 93 68 he he PRON eurjchem-1613 93 69 concentratio concentratio NOUN eurjchem-1613 93 70 oduct oduct NOUN eurjchem-1613 93 71 law law NOUN eurjchem-1613 93 72 could could AUX eurjchem-1613 93 73 be be AUX eurjchem-1613 93 74 de de ADP eurjchem-1613 93 75 n×[b]m n×[b]m NOUN eurjchem-1613 93 76 m m NOUN eurjchem-1613 93 77 are be AUX eurjchem-1613 93 78 the the DET eurjchem-1613 93 79 orde orde PROPN eurjchem-1613 93 80 he he PRON eurjchem-1613 93 81 detailed detail VERB eurjchem-1613 93 82 rea rea NOUN eurjchem-1613 93 83 integrated integrate VERB eurjchem-1613 93 84 rate rate NOUN eurjchem-1613 93 85 n n NOUN eurjchem-1613 93 86 1 1 NUM eurjchem-1613 93 87 k k NOUN eurjchem-1613 93 88 g g PROPN eurjchem-1613 93 89 half‐life half‐life PROPN eurjchem-1613 93 90 defin defin NOUN eurjchem-1613 93 91 ntration ntration NOUN eurjchem-1613 93 92 we we PRON eurjchem-1613 93 93 hav hav VERB eurjchem-1613 93 94 a a DET eurjchem-1613 93 95 g g PROPN eurjchem-1613 93 96 logarithm logarithm NOUN eurjchem-1613 93 97 from from ADP eurjchem-1613 93 98 1 1 NUM eurjchem-1613 93 99 n n PRON eurjchem-1613 93 100 ut ut NOUN eurjchem-1613 93 101 of of ADP eurjchem-1613 93 102 plotting plot VERB eurjchem-1613 93 103 lo lo PROPN eurjchem-1613 93 104 n n CCONJ eurjchem-1613 93 105 ) ) PUNCT eurjchem-1613 93 106 and and CCONJ eurjchem-1613 93 107 intercep intercep NOUN eurjchem-1613 93 108 allowed allow VERB eurjchem-1613 93 109 to to PART eurjchem-1613 93 110 rea rea VERB eurjchem-1613 93 111 on on ADP eurjchem-1613 93 112 is be AUX eurjchem-1613 93 113 measure measure NOUN eurjchem-1613 93 114 n n ADP eurjchem-1613 93 115 of of ADP eurjchem-1613 93 116 one one NUM eurjchem-1613 93 117 compo compo NOUN eurjchem-1613 93 118 curve curve NOUN eurjchem-1613 93 119 an an DET eurjchem-1613 93 120 arbitr arbitr NOUN eurjchem-1613 93 121 n n CCONJ eurjchem-1613 93 122 is be AUX eurjchem-1613 93 123 regarded regard VERB eurjchem-1613 93 124 ng ng PROPN eurjchem-1613 93 125 time time NOUN eurjchem-1613 93 126 is be AUX eurjchem-1613 93 127 initial initial ADJ eurjchem-1613 93 128 oncentration oncentration NOUN eurjchem-1613 93 129 is be AUX eurjchem-1613 93 130 e e NOUN eurjchem-1613 93 131 discrepancy discrepancy NOUN eurjchem-1613 93 132 d d PROPN eurjchem-1613 93 133 to to PART eurjchem-1613 93 134 reduce reduce VERB eurjchem-1613 93 135 the the DET eurjchem-1613 93 136 ing ing ADJ eurjchem-1613 93 137 other other ADJ eurjchem-1613 93 138 point point NOUN eurjchem-1613 93 139 til til ADV eurjchem-1613 93 140 enough enough ADJ eurjchem-1613 93 141 data datum NOUN eurjchem-1613 93 142 2 2 NUM eurjchem-1613 93 143 . . PUNCT eurjchem-1613 93 144 perimental perimental PROPN eurjchem-1613 93 145 data data PROPN eurjchem-1613 93 146 ng ng PROPN eurjchem-1613 93 147 n n PROPN eurjchem-1613 93 148 in in ADP eurjchem-1613 93 149 the the DET eurjchem-1613 93 150 eq eq NOUN eurjchem-1613 93 151 hiamati hiamati PROPN eurjchem-1613 93 152 and and CCONJ eurjchem-1613 93 153 aba aba PROPN eurjchem-1613 93 154 r r NOUN eurjchem-1613 93 155 obtained obtain VERB eurjchem-1613 93 156 logarith logarith PROPN eurjchem-1613 93 157 ni ni PROPN eurjchem-1613 93 158 ( ( PUNCT eurjchem-1613 93 159 ii)‐t ii)‐t NOUN eurjchem-1613 93 160 5.81 5.81 NUM eurjchem-1613 93 161 ( ( PUNCT eurjchem-1613 93 162 5.7 5.7 NUM eurjchem-1613 93 163 9.98 9.98 NUM eurjchem-1613 93 164 ( ( PUNCT eurjchem-1613 93 165 10 10 NUM eurjchem-1613 93 166 re re NOUN eurjchem-1613 93 167 is be AUX eurjchem-1613 93 168 capable capable ADJ eurjchem-1613 93 169 o o NOUN eurjchem-1613 93 170 versus versus ADP eurjchem-1613 93 171 d‐vnaoh d‐vnaoh PROPN eurjchem-1613 93 172 involved involved ADJ eurjchem-1613 93 173 evalu evalu NOUN eurjchem-1613 93 174 ee ee ADP eurjchem-1613 93 175 energy energy NOUN eurjchem-1613 93 176 chan chan PROPN eurjchem-1613 93 177 n n ADV eurjchem-1613 93 178 below below ADV eurjchem-1613 93 179 : : PUNCT eurjchem-1613 93 180 us we PRON eurjchem-1613 93 181 1 1 NUM eurjchem-1613 93 182 / / SYM eurjchem-1613 93 183 t t PROPN eurjchem-1613 93 184 produce produce NOUN eurjchem-1613 93 185 , , PUNCT eurjchem-1613 93 186 enthalpy enthalpy NOUN eurjchem-1613 93 187 chan chan PROPN eurjchem-1613 93 188 dy dy PROPN eurjchem-1613 93 189 , , PUNCT eurjchem-1613 93 190 the the DET eurjchem-1613 93 191 rate rate NOUN eurjchem-1613 93 192 of of ADP eurjchem-1613 93 193 ons on NOUN eurjchem-1613 93 194 of of ADP eurjchem-1613 93 195 the the DET eurjchem-1613 93 196 react react NOUN eurjchem-1613 93 197 escribed escribe VERB eurjchem-1613 93 198 as as ADP eurjchem-1613 93 199 : : PUNCT eurjchem-1613 93 200 rs rs X eurjchem-1613 93 201 of of ADP eurjchem-1613 93 202 the the DET eurjchem-1613 93 203 reacta reacta ADJ eurjchem-1613 93 204 ction ction PROPN eurjchem-1613 93 205 mechanis mechanis PROPN eurjchem-1613 93 206 equation equation NOUN eurjchem-1613 93 207 could could AUX eurjchem-1613 93 208 t t PROPN eurjchem-1613 93 209 nition nition NOUN eurjchem-1613 93 210 , , PUNCT eurjchem-1613 93 211 i.e. i.e. X eurjchem-1613 93 212 , , PUNCT eurjchem-1613 93 213 as as ADP eurjchem-1613 93 214 [ [ X eurjchem-1613 93 215 a a X eurjchem-1613 93 216 e e NOUN eurjchem-1613 93 217 : : PUNCT eurjchem-1613 93 218 m m VERB eurjchem-1613 93 219 both both DET eurjchem-1613 93 220 sides side NOUN eurjchem-1613 93 221 o o INTJ eurjchem-1613 93 222 log log VERB eurjchem-1613 93 223 a a DET eurjchem-1613 93 224 og og PROPN eurjchem-1613 93 225 t1/2 t1/2 PROPN eurjchem-1613 93 226 versus versus ADP eurjchem-1613 93 227 lo lo PROPN eurjchem-1613 93 228 pt pt PROPN eurjchem-1613 93 229 of of ADP eurjchem-1613 93 230 log log PROPN eurjchem-1613 93 231 act act PROPN eurjchem-1613 93 232 with with ADP eurjchem-1613 93 233 metal metal NOUN eurjchem-1613 94 1 i i PRON eurjchem-1613 94 2 ed ed VERB eurjchem-1613 94 3 at at ADP eurjchem-1613 94 4 different different ADJ eurjchem-1613 94 5 onent onent NOUN eurjchem-1613 94 6 is be AUX eurjchem-1613 94 7 drawn draw VERB eurjchem-1613 94 8 rary rary ADJ eurjchem-1613 94 9 point point NOUN eurjchem-1613 94 10 could could AUX eurjchem-1613 94 11 as as ADP eurjchem-1613 94 12 initial initial ADJ eurjchem-1613 94 13 con con PROPN eurjchem-1613 94 14 l l PROPN eurjchem-1613 94 15 time time NOUN eurjchem-1613 94 16 . . PUNCT eurjchem-1613 95 1 then then ADV eurjchem-1613 95 2 the the DET eurjchem-1613 95 3 s s NOUN eurjchem-1613 95 4 chosen choose VERB eurjchem-1613 95 5 and and CCONJ eurjchem-1613 95 6 i i PRON eurjchem-1613 95 7 between between ADP eurjchem-1613 95 8 these these DET eurjchem-1613 95 9 concentration concentration NOUN eurjchem-1613 95 10 o o NOUN eurjchem-1613 95 11 ts ts ADV eurjchem-1613 95 12 on on ADP eurjchem-1613 95 13 the the DET eurjchem-1613 95 14 cure cure NOUN eurjchem-1613 95 15 a a PRON eurjchem-1613 95 16 to to PART eurjchem-1613 95 17 be be AUX eurjchem-1613 95 18 produ produ NOUN eurjchem-1613 95 19 a a DET eurjchem-1613 95 20 the the DET eurjchem-1613 95 21 value value NOUN eurjchem-1613 95 22 of of ADP eurjchem-1613 95 23 n n DET eurjchem-1613 95 24 quation quation NOUN eurjchem-1613 95 25 ( ( PUNCT eurjchem-1613 95 26 28 28 NUM eurjchem-1613 95 27 ) ) PUNCT eurjchem-1613 95 28 , , PUNCT eurjchem-1613 95 29 th th X eurjchem-1613 95 30 azari azari PROPN eurjchem-1613 95 31 / / SYM eurjchem-1613 95 32 european european PROPN eurjchem-1613 95 33 hm hm INTJ eurjchem-1613 95 34 stability stability PROPN eurjchem-1613 95 35 constan constan PROPN eurjchem-1613 95 36 trp trp PROPN eurjchem-1613 95 37 76 76 NUM eurjchem-1613 95 38 ) ) PUNCT eurjchem-1613 95 39 .20 .20 NUM eurjchem-1613 95 40 ) ) PUNCT eurjchem-1613 95 41 of of ADP eurjchem-1613 95 42 plotting plot VERB eurjchem-1613 95 43 first first ADJ eurjchem-1613 95 44 h h NOUN eurjchem-1613 95 45 to to PART eurjchem-1613 95 46 clarify clarify VERB eurjchem-1613 95 47 the the DET eurjchem-1613 95 48 ating ate VERB eurjchem-1613 95 49 δg δg NOUN eurjchem-1613 95 50 ° ° NOUN eurjchem-1613 95 51 , , PUNCT eurjchem-1613 95 52 δh δh ADP eurjchem-1613 95 53 ° ° NOUN eurjchem-1613 95 54 nge nge NOUN eurjchem-1613 95 55 , , PUNCT eurjchem-1613 95 56 δg δg NOUN eurjchem-1613 95 57 ° ° NOUN eurjchem-1613 95 58 , , PUNCT eurjchem-1613 95 59 coul coul PROPN eurjchem-1613 95 60 es es PROPN eurjchem-1613 95 61 straight straight ADJ eurjchem-1613 95 62 line line NOUN eurjchem-1613 95 63 ges ge NOUN eurjchem-1613 95 64 were be AUX eurjchem-1613 95 65 comp comp NOUN eurjchem-1613 95 66 a a DET eurjchem-1613 95 67 chemical chemical PROPN eurjchem-1613 95 68 rea rea PROPN eurjchem-1613 95 69 ting ting PROPN eurjchem-1613 95 70 species species PROPN eurjchem-1613 95 71 . . PUNCT eurjchem-1613 96 1 fo fo ADP eurjchem-1613 96 2 ants ant NOUN eurjchem-1613 96 3 and and CCONJ eurjchem-1613 96 4 their their PRON eurjchem-1613 96 5 v v NOUN eurjchem-1613 96 6 sm sm PROPN eurjchem-1613 96 7 . . PROPN eurjchem-1613 97 1 for for ADP eurjchem-1613 97 2 the the DET eurjchem-1613 97 3 n n NOUN eurjchem-1613 97 4 o o NOUN eurjchem-1613 97 5 d d AUX eurjchem-1613 97 6 be be VERB eurjchem-1613 97 7 represente represente PROPN eurjchem-1613 97 8 a a X eurjchem-1613 97 9 ] ] PUNCT eurjchem-1613 97 10 reaches reach VERB eurjchem-1613 97 11 to to ADP eurjchem-1613 97 12 h h PROPN eurjchem-1613 97 13 f f PROPN eurjchem-1613 97 14 the the DET eurjchem-1613 97 15 equation equation NOUN eurjchem-1613 97 16 g g PROPN eurjchem-1613 97 17 [ [ X eurjchem-1613 97 18 a a X eurjchem-1613 97 19 ] ] X eurjchem-1613 97 20 is be AUX eurjchem-1613 97 21 a a DET eurjchem-1613 97 22 linear linear NOUN eurjchem-1613 97 23 . . PUNCT eurjchem-1613 98 1 in in ADP eurjchem-1613 98 2 practice practice NOUN eurjchem-1613 98 3 on on ADP eurjchem-1613 98 4 and and CCONJ eurjchem-1613 98 5 the the DET eurjchem-1613 98 6 prog prog PROPN eurjchem-1613 98 7 times times PROPN eurjchem-1613 98 8 . . PUNCT eurjchem-1613 99 1 the the DET eurjchem-1613 99 2 pl pl PROPN eurjchem-1613 99 3 against against ADP eurjchem-1613 99 4 the the DET eurjchem-1613 99 5 tim tim PROPN eurjchem-1613 99 6 d d NOUN eurjchem-1613 99 7 be be AUX eurjchem-1613 99 8 selected select VERB eurjchem-1613 99 9 an an DET eurjchem-1613 99 10 ncentration ncentration NOUN eurjchem-1613 99 11 an an DET eurjchem-1613 99 12 e e NOUN eurjchem-1613 99 13 point point NOUN eurjchem-1613 99 14 equivale equivale NOUN eurjchem-1613 99 15 ts ts ADP eurjchem-1613 99 16 pertinent pertinent NOUN eurjchem-1613 99 17 tim tim PROPN eurjchem-1613 99 18 e e PROPN eurjchem-1613 99 19 two two NUM eurjchem-1613 99 20 values value NOUN eurjchem-1613 99 21 i i PRON eurjchem-1613 99 22 of of ADP eurjchem-1613 99 23 the the DET eurjchem-1613 99 24 compone compone NOUN eurjchem-1613 99 25 e e NOUN eurjchem-1613 99 26 this this DET eurjchem-1613 99 27 task task NOUN eurjchem-1613 99 28 coul coul PROPN eurjchem-1613 99 29 ced ce VERB eurjchem-1613 99 30 to to PART eurjchem-1613 99 31 plot plot VERB eurjchem-1613 99 32 log log NOUN eurjchem-1613 99 33 could could AUX eurjchem-1613 99 34 be be AUX eurjchem-1613 99 35 calcul calcul PROPN eurjchem-1613 99 36 he he PRON eurjchem-1613 99 37 rate rate VERB eurjchem-1613 99 38 consta consta PROPN eurjchem-1613 99 39 n n PROPN eurjchem-1613 99 40 journal journal PROPN eurjchem-1613 99 41 of of ADP eurjchem-1613 99 42 chem chem NOUN eurjchem-1613 99 43 nts nt NOUN eurjchem-1613 99 44 of of ADP eurjchem-1613 99 45 trp trp PROPN eurjchem-1613 99 46 complex complex PROPN eurjchem-1613 99 47 fe(iii)‐trp fe(iii)‐trp PROPN eurjchem-1613 99 48 8.79 8.79 NUM eurjchem-1613 99 49 ( ( PUNCT eurjchem-1613 99 50 9.00 9.00 NUM eurjchem-1613 99 51 ) ) PUNCT eurjchem-1613 99 52 17.21 17.21 NUM eurjchem-1613 99 53 ( ( PUNCT eurjchem-1613 99 54 ‐ ‐ NOUN eurjchem-1613 99 55 ) ) PUNCT eurjchem-1613 99 56 t t NOUN eurjchem-1613 99 57 and and CCONJ eurjchem-1613 99 58 e e PROPN eurjchem-1613 99 59 end end NOUN eurjchem-1613 99 60 , , PUNCT eurjchem-1613 99 61 and and CCONJ eurjchem-1613 99 62 ld ld PROPN eurjchem-1613 99 63 be be AUX eurjchem-1613 99 64 ( ( PUNCT eurjchem-1613 99 65 22 22 NUM eurjchem-1613 99 66 ) ) PUNCT eurjchem-1613 99 67 with with ADP eurjchem-1613 99 68 ( ( PUNCT eurjchem-1613 99 69 23 23 NUM eurjchem-1613 99 70 ) ) PUNCT eurjchem-1613 99 71 puted put VERB eurjchem-1613 99 72 . . PUNCT eurjchem-1613 100 1 ( ( PUNCT eurjchem-1613 100 2 24 24 NUM eurjchem-1613 100 3 ) ) PUNCT eurjchem-1613 100 4 action action NOUN eurjchem-1613 100 5 or or CCONJ eurjchem-1613 100 6 the the DET eurjchem-1613 100 7 ( ( PUNCT eurjchem-1613 100 8 25 25 NUM eurjchem-1613 100 9 ) ) PUNCT eurjchem-1613 100 10 ( ( PUNCT eurjchem-1613 100 11 26 26 NUM eurjchem-1613 100 12 ) ) PUNCT eurjchem-1613 100 13 alues alue VERB eurjchem-1613 100 14 order order NOUN eurjchem-1613 100 15 ed ed NOUN eurjchem-1613 100 16 as as ADP eurjchem-1613 100 17 : : PUNCT eurjchem-1613 100 18 ( ( PUNCT eurjchem-1613 100 19 27 27 NUM eurjchem-1613 100 20 ) ) PUNCT eurjchem-1613 100 21 alf alf NOUN eurjchem-1613 100 22 of of ADP eurjchem-1613 100 23 ( ( PUNCT eurjchem-1613 100 24 28 28 NUM eurjchem-1613 100 25 ) ) PUNCT eurjchem-1613 100 26 ( ( PUNCT eurjchem-1613 100 27 28 28 NUM eurjchem-1613 100 28 ) ) PUNCT eurjchem-1613 100 29 , , PUNCT eurjchem-1613 100 30 ( ( PUNCT eurjchem-1613 100 31 29 29 X eurjchem-1613 100 32 ) ) PUNCT eurjchem-1613 100 33 r r NOUN eurjchem-1613 100 34 with with ADP eurjchem-1613 100 35 e e NOUN eurjchem-1613 100 36 , , PUNCT eurjchem-1613 100 37 the the DET eurjchem-1613 100 38 gress gress ADJ eurjchem-1613 100 39 lot lot NOUN eurjchem-1613 100 40 of of ADP eurjchem-1613 100 41 me i PRON eurjchem-1613 100 42 . . PUNCT eurjchem-1613 101 1 on on ADP eurjchem-1613 101 2 nd nd PRON eurjchem-1613 101 3 its its PRON eurjchem-1613 101 4 d d NOUN eurjchem-1613 101 5 its its PRON eurjchem-1613 101 6 ent ent NOUN eurjchem-1613 101 7 to to ADP eurjchem-1613 101 8 me i PRON eurjchem-1613 101 9 is be AUX eurjchem-1613 101 10 s s PRON eurjchem-1613 101 11 the the DET eurjchem-1613 101 12 ent ent NOUN eurjchem-1613 101 13 to to ADP eurjchem-1613 101 14 ld ld PROPN eurjchem-1613 101 15 be be AUX eurjchem-1613 101 16 g g PROPN eurjchem-1613 101 17 [ [ X eurjchem-1613 101 18 a a X eurjchem-1613 101 19 ] ] X eurjchem-1613 101 20 lated late VERB eurjchem-1613 101 21 . . PUNCT eurjchem-1613 102 1 nt not PART eurjchem-1613 102 2 , , PUNCT eurjchem-1613 102 3 k k PROPN eurjchem-1613 102 4 , , PUNCT eurjchem-1613 102 5 coul coul PROPN eurjchem-1613 102 6 and and CCONJ eurjchem-1613 102 7 equa equa PROPN eurjchem-1613 102 8 k k PROPN eurjchem-1613 102 9 whe whe PROPN eurjchem-1613 102 10 8.31 8.31 NUM eurjchem-1613 102 11 the the DET eurjchem-1613 102 12 e e PROPN eurjchem-1613 102 13 ln ln PROPN eurjchem-1613 102 14 k k PROPN eurjchem-1613 102 15 a a DET eurjchem-1613 102 16 slop slop NOUN eurjchem-1613 102 17 3 3 NUM eurjchem-1613 102 18 . . PUNCT eurjchem-1613 102 19 re re PROPN eurjchem-1613 102 20 f f PROPN eurjchem-1613 102 21 ( ( PUNCT eurjchem-1613 102 22 ii)‐ ii)‐ NUM eurjchem-1613 102 23 been be AUX eurjchem-1613 102 24 betw betw NOUN eurjchem-1613 102 25 ion‐t ion‐t VERB eurjchem-1613 102 26 they they PRON eurjchem-1613 102 27 tabl tabl VERB eurjchem-1613 102 28 resp resp PROPN eurjchem-1613 102 29 temp temp NOUN eurjchem-1613 102 30 figur figur PROPN eurjchem-1613 102 31 stand stand VERB eurjchem-1613 102 32 t t PROPN eurjchem-1613 102 33 kf kf PROPN eurjchem-1613 103 1 co co PROPN eurjchem-1613 103 2 ( ( PUNCT eurjchem-1613 103 3 mistry mistry PROPN eurjchem-1613 103 4 8 8 NUM eurjchem-1613 103 5 ( ( PUNCT eurjchem-1613 103 6 4 4 NUM eurjchem-1613 103 7 ) ) PUNCT eurjchem-1613 103 8 ( ( PUNCT eurjchem-1613 103 9 2017 2017 NUM eurjchem-1613 103 10 xes xe NOUN eurjchem-1613 103 11 in in ADP eurjchem-1613 103 12 water water NOUN eurjchem-1613 103 13 at at ADP eurjchem-1613 103 14 25 25 NUM eurjchem-1613 103 15 ° ° NOUN eurjchem-1613 103 16 zn zn PROPN eurjchem-1613 103 17 ( ( PUNCT eurjchem-1613 103 18 i i PROPN eurjchem-1613 103 19 4.85 4.85 NUM eurjchem-1613 103 20 8.75 8.75 NUM eurjchem-1613 103 21 ld ld PROPN eurjchem-1613 103 22 be be AUX eurjchem-1613 103 23 estimated estimate VERB eurjchem-1613 103 24 activation activation NOUN eurjchem-1613 103 25 en en ADP eurjchem-1613 103 26 ation ation PROPN eurjchem-1613 103 27 : : PUNCT eurjchem-1613 103 28 ae ae PROPN eurjchem-1613 103 29 ere ere PROPN eurjchem-1613 103 30 ea ea PROPN eurjchem-1613 103 31 is be AUX eurjchem-1613 103 32 the the DET eurjchem-1613 103 33 act act NOUN eurjchem-1613 103 34 145.j 145.j PROPN eurjchem-1613 103 35 / / SYM eurjchem-1613 103 36 k.mol k.mol PROPN eurjchem-1613 103 37 . . PUNCT eurjchem-1613 104 1 ta ta ADP eurjchem-1613 104 2 equation equation NOUN eurjchem-1613 104 3 ( ( PUNCT eurjchem-1613 104 4 30 30 NUM eurjchem-1613 104 5 ) ) PUNCT eurjchem-1613 104 6 , , PUNCT eurjchem-1613 104 7 y y PROPN eurjchem-1613 104 8 k k PROPN eurjchem-1613 104 9 a a DET eurjchem-1613 104 10 plot plot NOUN eurjchem-1613 104 11 of of ADP eurjchem-1613 104 12 ln(k ln(k NOUN eurjchem-1613 104 13 ) ) PUNCT eurjchem-1613 104 14 v v ADP eurjchem-1613 104 15 e e PROPN eurjchem-1613 104 16 of of ADP eurjchem-1613 104 17 ‐ea ‐ea PROPN eurjchem-1613 105 1 /r /r X eurjchem-1613 105 2 , , PUNCT eurjchem-1613 105 3 or or CCONJ eurjchem-1613 105 4 e e NOUN eurjchem-1613 105 5 esults esult NOUN eurjchem-1613 105 6 and and CCONJ eurjchem-1613 105 7 disc disc NOUN eurjchem-1613 105 8 figure figure NOUN eurjchem-1613 105 9 1 1 NUM eurjchem-1613 105 10 illustr illustr PROPN eurjchem-1613 105 11 trp trp PROPN eurjchem-1613 105 12 complex complex NOUN eurjchem-1613 105 13 in in ADP eurjchem-1613 105 14 n n CCONJ eurjchem-1613 105 15 shown show VERB eurjchem-1613 105 16 on on ADP eurjchem-1613 105 17 f f PROPN eurjchem-1613 105 18 ween ween PROPN eurjchem-1613 105 19 the the DET eurjchem-1613 105 20 stabil stabil PROPN eurjchem-1613 105 21 trp trp PROPN eurjchem-1613 105 22 complexes complexe VERB eurjchem-1613 105 23 y y PROPN eurjchem-1613 105 24 are be AUX eurjchem-1613 105 25 in in ADP eurjchem-1613 105 26 a a DET eurjchem-1613 105 27 good good ADJ eurjchem-1613 105 28 le le ADP eurjchem-1613 105 29 2 2 NUM eurjchem-1613 105 30 demonstr demonstr NOUN eurjchem-1613 105 31 pective pective ADJ eurjchem-1613 105 32 complex complex ADJ eurjchem-1613 105 33 peratures perature NOUN eurjchem-1613 105 34 of of ADP eurjchem-1613 105 35 25 25 NUM eurjchem-1613 105 36 re re NOUN eurjchem-1613 105 37 1 1 NUM eurjchem-1613 105 38 . . PUNCT eurjchem-1613 106 1 a a DET eurjchem-1613 106 2 plot plot NOUN eurjchem-1613 106 3 of of ADP eurjchem-1613 106 4 dardized dardize VERB eurjchem-1613 106 5 naoh naoh NOUN eurjchem-1613 106 6 solu solu PROPN eurjchem-1613 106 7 f f PROPN eurjchem-1613 106 8 the the DET eurjchem-1613 106 9 order order NOUN eurjchem-1613 106 10 of of ADP eurjchem-1613 106 11 inc inc PROPN eurjchem-1613 106 12 ( ( PUNCT eurjchem-1613 106 13 ii)‐trp ii)‐trp PROPN eurjchem-1613 106 14   PUNCT eurjchem-1613 106 15 kf kf PROPN eurjchem-1613 107 1 zn(ii)‐trp zn(ii)‐trp PROPN eurjchem-1613 107 2 … … PUNCT eurjchem-1613 107 3 kf kf INTJ eurjchem-1613 107 4 cu(ii)‐trp cu(ii)‐trp INTJ eurjchem-1613 107 5 < < X eurjchem-1613 108 1 kf kf PROPN eurjchem-1613 108 2 7 7 NUM eurjchem-1613 108 3 ) ) PUNCT eurjchem-1613 108 4 333‐338 333‐338 NUM eurjchem-1613 108 5 ° ° ADP eurjchem-1613 108 6 c c PROPN eurjchem-1613 108 7 with with ADP eurjchem-1613 108 8 literature literature NOUN eurjchem-1613 108 9 ( ( PUNCT eurjchem-1613 108 10 ii)‐trp ii)‐trp PROPN eurjchem-1613 108 11 ( ( PUNCT eurjchem-1613 108 12 5.01 5.01 NUM eurjchem-1613 108 13 ) ) PUNCT eurjchem-1613 108 14 ( ( PUNCT eurjchem-1613 108 15 8.20 8.20 NUM eurjchem-1613 108 16 ) ) PUNCT eurjchem-1613 108 17 d. d. NOUN eurjchem-1613 108 18 the the DET eurjchem-1613 108 19 relation relation NOUN eurjchem-1613 108 20 nergy nergy PROPN eurjchem-1613 108 21 has have VERB eurjchem-1613 108 22 bee bee PROPN eurjchem-1613 108 23 tivation tivation NOUN eurjchem-1613 108 24 energy energy NOUN eurjchem-1613 108 25 aking ake VERB eurjchem-1613 108 26 the the DET eurjchem-1613 108 27 natur natur PROPN eurjchem-1613 108 28 yields yield NOUN eurjchem-1613 108 29 : : PUNCT eurjchem-1613 108 30 ln ln ADV eurjchem-1613 108 31 a a DET eurjchem-1613 108 32 versus versus ADP eurjchem-1613 108 33 1 1 NUM eurjchem-1613 108 34 / / SYM eurjchem-1613 108 35 t t NOUN eurjchem-1613 108 36 pro pro X eurjchem-1613 108 37 ea ea X eurjchem-1613 108 38 = = PUNCT eurjchem-1613 108 39 ‐r ‐r X eurjchem-1613 108 40 ( ( PUNCT eurjchem-1613 108 41 slope slope NOUN eurjchem-1613 108 42 ) ) PUNCT eurjchem-1613 108 43 a a DET eurjchem-1613 108 44 cussion cussion NOUN eurjchem-1613 108 45 rates rate VERB eurjchem-1613 108 46 a a DET eurjchem-1613 108 47 potentio potentio NOUN eurjchem-1613 108 48 n n DET eurjchem-1613 108 49 water water NOUN eurjchem-1613 108 50 at at ADP eurjchem-1613 108 51 25 25 NUM eurjchem-1613 108 52 figure figure NOUN eurjchem-1613 108 53 2 2 NUM eurjchem-1613 108 54 . . PUNCT eurjchem-1613 108 55 tabl tabl ADJ eurjchem-1613 108 56 lity lity NOUN eurjchem-1613 108 57 constant constant ADJ eurjchem-1613 108 58 va va NOUN eurjchem-1613 108 59 in in ADP eurjchem-1613 108 60 water water NOUN eurjchem-1613 108 61 at at ADP eurjchem-1613 108 62 25 25 NUM eurjchem-1613 108 63 agreement agreement NOUN eurjchem-1613 108 64 with with ADP eurjchem-1613 108 65 rates rate NOUN eurjchem-1613 108 66 the the DET eurjchem-1613 108 67 stabi stabi NOUN eurjchem-1613 108 68 xes xes PROPN eurjchem-1613 108 69 in in ADP eurjchem-1613 108 70 water‐dio water‐dio PROPN eurjchem-1613 108 71 5‐40 5‐40 NUM eurjchem-1613 108 72 ° ° NOUN eurjchem-1613 108 73 c c NOUN eurjchem-1613 108 74 . . PUNCT eurjchem-1613 109 1 corrected correct VERB eurjchem-1613 109 2 ph ph PROPN eurjchem-1613 109 3 ve ve NOUN eurjchem-1613 109 4 ution ution NOUN eurjchem-1613 109 5 for for ADP eurjchem-1613 109 6 zn(ii)‐tr zn(ii)‐tr NOUN eurjchem-1613 109 7 n n NOUN eurjchem-1613 110 1 h h NOUN eurjchem-1613 110 2 h h NOUN eurjchem-1613 111 1 o o NOUN eurjchem-1613 111 2 figure figure NOUN eurjchem-1613 111 3 2 2 NUM eurjchem-1613 111 4 . . PUNCT eurjchem-1613 112 1 the the DET eurjchem-1613 112 2 stru stru NOUN eurjchem-1613 112 3 creasing crease VERB eurjchem-1613 112 4 stabili stabili NOUN eurjchem-1613 112 5 p p X eurjchem-1613 112 6 < < X eurjchem-1613 112 7 kf kf X eurjchem-1613 113 1 pb(ii)‐trp pb(ii)‐trp VERB eurjchem-1613 113 2 < < X eurjchem-1613 113 3 k k PROPN eurjchem-1613 113 4 fe fe X eurjchem-1613 113 5 ( ( PUNCT eurjchem-1613 113 6 iii)‐ iii)‐ NUM eurjchem-1613 113 7 trp trp PROPN eurjchem-1613 113 8 ( ( PUNCT eurjchem-1613 113 9 in in ADP eurjchem-1613 113 10 parenthesis parenthesis NOUN eurjchem-1613 113 11 ) ) PUNCT eurjchem-1613 113 12 re re VERB eurjchem-1613 113 13 cu cu PROPN eurjchem-1613 113 14 ( ( PUNCT eurjchem-1613 113 15 ii)‐trp ii)‐trp PROPN eurjchem-1613 113 16 8.37 8.37 NUM eurjchem-1613 113 17 ( ( PUNCT eurjchem-1613 113 18 7.80 7.80 NUM eurjchem-1613 113 19 ) ) PUNCT eurjchem-1613 113 20 15.83 15.83 NUM eurjchem-1613 113 21 ( ( PUNCT eurjchem-1613 113 22 15.90 15.90 NUM eurjchem-1613 113 23 ) ) PUNCT eurjchem-1613 113 24 n n NOUN eurjchem-1613 113 25 between between ADP eurjchem-1613 113 26 the the DET eurjchem-1613 113 27 n n ADV eurjchem-1613 113 28 shown show VERB eurjchem-1613 113 29 by by ADP eurjchem-1613 113 30 y y PROPN eurjchem-1613 113 31 in in ADP eurjchem-1613 113 32 j j PROPN eurjchem-1613 113 33 / / SYM eurjchem-1613 113 34 mol mol PROPN eurjchem-1613 113 35 , , PUNCT eurjchem-1613 113 36 r r NOUN eurjchem-1613 113 37 ha ha INTJ eurjchem-1613 113 38 ral ral ADJ eurjchem-1613 113 39 logarithm logarithm PROPN eurjchem-1613 113 40 o o PROPN eurjchem-1613 113 41 duces duce VERB eurjchem-1613 113 42 a a DET eurjchem-1613 113 43 straigh straigh NOUN eurjchem-1613 113 44 nd nd NOUN eurjchem-1613 113 45 r r NOUN eurjchem-1613 113 46 = = SYM eurjchem-1613 114 1 8.3145 8.3145 NUM eurjchem-1613 114 2 j j PROPN eurjchem-1613 114 3 ometric ometric ADJ eurjchem-1613 114 4 titration titration NOUN eurjchem-1613 114 5 ° ° PROPN eurjchem-1613 114 6 c c PROPN eurjchem-1613 114 7 . . PUNCT eurjchem-1613 115 1 the the DET eurjchem-1613 115 2 structu structu PROPN eurjchem-1613 115 3 le le X eurjchem-1613 115 4 1 1 NUM eurjchem-1613 115 5 exhibits exhibit NOUN eurjchem-1613 115 6 alues alue NOUN eurjchem-1613 115 7 of of ADP eurjchem-1613 115 8 the the DET eurjchem-1613 115 9 pe pe PROPN eurjchem-1613 115 10 5 5 NUM eurjchem-1613 115 11 ° ° NOUN eurjchem-1613 115 12 c c NOUN eurjchem-1613 115 13 . . PUNCT eurjchem-1613 116 1 the the DET eurjchem-1613 116 2 results result NOUN eurjchem-1613 116 3 h h VERB eurjchem-1613 116 4 the the DET eurjchem-1613 116 5 works work NOUN eurjchem-1613 116 6 in in ADP eurjchem-1613 116 7 ility ility NOUN eurjchem-1613 116 8 constant constant ADJ eurjchem-1613 116 9 oxane oxane NOUN eurjchem-1613 116 10 mixture mixture NOUN eurjchem-1613 116 11 rsus rsus NOUN eurjchem-1613 116 12 the the DET eurjchem-1613 116 13 concent concent PROPN eurjchem-1613 116 14 rp rp NOUN eurjchem-1613 116 15 in in ADP eurjchem-1613 116 16 water water NOUN eurjchem-1613 116 17 at at ADP eurjchem-1613 116 18 25 25 NUM eurjchem-1613 116 19 ° ° NOUN eurjchem-1613 116 20 c c NOUN eurjchem-1613 116 21 n n NUM eurjchem-1613 116 22 h h NOUN eurjchem-1613 117 1 o o NOUN eurjchem-1613 117 2 h h NOUN eurjchem-1613 117 3 o o NOUN eurjchem-1613 117 4 ucture ucture NOUN eurjchem-1613 117 5 of of ADP eurjchem-1613 117 6 trp trp PROPN eurjchem-1613 117 7 . . PUNCT eurjchem-1613 118 1 ity ity PROPN eurjchem-1613 118 2 is be AUX eurjchem-1613 118 3 as as SCONJ eurjchem-1613 118 4 follows follow VERB eurjchem-1613 118 5 kf kf PROPN eurjchem-1613 118 6 ni(ii)‐trp ni(ii)‐trp INTJ eurjchem-1613 118 7 < < X eurjchem-1613 118 8 … … PUNCT eurjchem-1613 118 9 335 335 NUM eurjchem-1613 118 10 eference eference NOUN eurjchem-1613 118 11 [ [ X eurjchem-1613 118 12 14 14 NUM eurjchem-1613 118 13 ] ] PUNCT eurjchem-1613 118 14 . . PUNCT eurjchem-1613 118 15 ) ) PUNCT eurjchem-1613 119 1 rate rate NOUN eurjchem-1613 119 2 constant constant ADJ eurjchem-1613 119 3 the the DET eurjchem-1613 119 4 following follow VERB eurjchem-1613 119 5 ( ( PUNCT eurjchem-1613 119 6 30 30 NUM eurjchem-1613 119 7 ) ) PUNCT eurjchem-1613 119 8 as as ADP eurjchem-1613 119 9 the the DET eurjchem-1613 119 10 value value NOUN eurjchem-1613 119 11 of of ADP eurjchem-1613 119 12 f f PROPN eurjchem-1613 119 13 each each DET eurjchem-1613 119 14 side side NOUN eurjchem-1613 119 15 of of ADP eurjchem-1613 119 16 ( ( PUNCT eurjchem-1613 119 17 31 31 NUM eurjchem-1613 119 18 ) ) PUNCT eurjchem-1613 119 19 ht ht NOUN eurjchem-1613 119 20 line line NOUN eurjchem-1613 119 21 with with ADP eurjchem-1613 119 22 the the DET eurjchem-1613 119 23 j j PROPN eurjchem-1613 119 24 / / SYM eurjchem-1613 119 25 k.mol k.mol PROPN eurjchem-1613 119 26 . . PUNCT eurjchem-1613 120 1 n n PRON eurjchem-1613 120 2 curve curve VERB eurjchem-1613 120 3 for for ADP eurjchem-1613 120 4 zn zn PROPN eurjchem-1613 120 5 ure ure PROPN eurjchem-1613 120 6 of of ADP eurjchem-1613 120 7 trp trp PROPN eurjchem-1613 120 8 has have VERB eurjchem-1613 120 9 a a DET eurjchem-1613 120 10 comparison comparison NOUN eurjchem-1613 120 11 ertinent ertinent NOUN eurjchem-1613 120 12 metal metal NOUN eurjchem-1613 120 13 s s NOUN eurjchem-1613 120 14 indicate indicate VERB eurjchem-1613 120 15 that that SCONJ eurjchem-1613 120 16 the the DET eurjchem-1613 120 17 literature literature NOUN eurjchem-1613 120 18 . . PUNCT eurjchem-1613 121 1 values value NOUN eurjchem-1613 121 2 of of ADP eurjchem-1613 121 3 the the DET eurjchem-1613 121 4 ( ( PUNCT eurjchem-1613 121 5 50:50 50:50 NUM eurjchem-1613 121 6 , , PUNCT eurjchem-1613 121 7 v v NOUN eurjchem-1613 121 8 : : PUNCT eurjchem-1613 121 9 v v NOUN eurjchem-1613 121 10 ) ) PUNCT eurjchem-1613 121 11 at at ADP eurjchem-1613 121 12 tration tration NOUN eurjchem-1613 121 13 of of ADP eurjchem-1613 121 14 added add VERB eurjchem-1613 121 15 c. c. NOUN eurjchem-1613 121 16 : : PUNCT eurjchem-1613 121 17 ( ( PUNCT eurjchem-1613 121 18 32 32 NUM eurjchem-1613 121 19 ) ) SYM eurjchem-1613 121 20 336 336 NUM eurjchem-1613 121 21 table table NOUN eurjchem-1613 121 22 2 2 NUM eurjchem-1613 121 23 . . PUNCT eurjchem-1613 121 24 logarit logarit PROPN eurjchem-1613 121 25 complex complex ADJ eurjchem-1613 121 26 fe(iii)‐trp fe(iii)‐trp PROPN eurjchem-1613 121 27 co(ii)‐trp co(ii)‐trp NOUN eurjchem-1613 122 1 ni(ii)‐trp ni(ii)‐trp INTJ eurjchem-1613 122 2 cu(ii)‐trp cu(ii)‐trp INTJ eurjchem-1613 123 1 zn(ii)‐trp zn(ii)‐trp INTJ eurjchem-1613 123 2 pb(ii)‐trp pb(ii)‐trp PROPN eurjchem-1613 123 3 table table NOUN eurjchem-1613 123 4 3 3 NUM eurjchem-1613 123 5 . . PUNCT eurjchem-1613 124 1 ‐δg ‐δg NOUN eurjchem-1613 124 2 ° ° ADP eurjchem-1613 124 3 1 1 NUM eurjchem-1613 124 4 v v NOUN eurjchem-1613 124 5 complex complex ADJ eurjchem-1613 124 6 fe(iii)‐trp fe(iii)‐trp NOUN eurjchem-1613 124 7 co(ii)‐trp co(ii)‐trp NOUN eurjchem-1613 125 1 ni(ii)‐trp ni(ii)‐trp INTJ eurjchem-1613 125 2 cu(ii)‐trp cu(ii)‐trp INTJ eurjchem-1613 126 1 zn(ii)‐trp zn(ii)‐trp INTJ eurjchem-1613 126 2 pb(ii)‐trp pb(ii)‐trp PROPN eurjchem-1613 126 3 table table NOUN eurjchem-1613 126 4 4 4 NUM eurjchem-1613 126 5 . . PUNCT eurjchem-1613 126 6 δs δs NOUN eurjchem-1613 126 7 ° ° ADP eurjchem-1613 126 8 1 1 NUM eurjchem-1613 126 9 an an DET eurjchem-1613 126 10 complex complex ADJ eurjchem-1613 126 11 fe(iii)‐trp fe(iii)‐trp NOUN eurjchem-1613 126 12 co(ii)‐trp co(ii)‐trp NOUN eurjchem-1613 127 1 ni(ii)‐trp ni(ii)‐trp INTJ eurjchem-1613 127 2 cu(ii)‐trp cu(ii)‐trp INTJ eurjchem-1613 128 1 zn(ii)‐trp zn(ii)‐trp PROPN eurjchem-1613 128 2 pb(ii)‐trp pb(ii)‐trp VERB eurjchem-1613 128 3 it it PRON eurjchem-1613 128 4 was be AUX eurjchem-1613 128 5 fou fou PROPN eurjchem-1613 128 6 first first ADJ eurjchem-1613 128 7 formatio formatio ADJ eurjchem-1613 128 8 process process NOUN eurjchem-1613 128 9 ( ( PUNCT eurjchem-1613 128 10 i.e. i.e. X eurjchem-1613 128 11 a a PRON eurjchem-1613 128 12 and and CCONJ eurjchem-1613 128 13 l‐ l‐ NUM eurjchem-1613 128 14 ) ) PUNCT eurjchem-1613 128 15 . . PUNCT eurjchem-1613 129 1 her she PRON eurjchem-1613 129 2 between between ADP eurjchem-1613 129 3 ligan ligan NOUN eurjchem-1613 129 4 the the DET eurjchem-1613 129 5 stepwise stepwise NOUN eurjchem-1613 129 6 illustrates illustrate VERB eurjchem-1613 129 7 tha tha NOUN eurjchem-1613 129 8 which which PRON eurjchem-1613 129 9 is be AUX eurjchem-1613 129 10 the the DET eurjchem-1613 129 11 regarding regard VERB eurjchem-1613 129 12 m m NOUN eurjchem-1613 129 13 tryptophan tryptophan NOUN eurjchem-1613 129 14 , , PUNCT eurjchem-1613 129 15 d d X eurjchem-1613 129 16 the the DET eurjchem-1613 129 17 side side NOUN eurjchem-1613 129 18 chai chai NOUN eurjchem-1613 129 19 center center NOUN eurjchem-1613 129 20 to to ADP eurjchem-1613 129 21 me i PRON eurjchem-1613 129 22 formula formula NOUN eurjchem-1613 129 23 for for ADP eurjchem-1613 129 24 m m NOUN eurjchem-1613 129 25 figure figure NOUN eurjchem-1613 129 26 3 3 NUM eurjchem-1613 129 27 . . PUNCT eurjchem-1613 130 1 the the DET eurjchem-1613 130 2 m m NOUN eurjchem-1613 130 3 possible possible ADJ eurjchem-1613 130 4 configu configu NOUN eurjchem-1613 130 5 unpublished unpublished ADJ eurjchem-1613 130 6 res re NOUN eurjchem-1613 130 7 the the DET eurjchem-1613 130 8 varia varia NOUN eurjchem-1613 130 9 complex complex NOUN eurjchem-1613 130 10 of of ADP eurjchem-1613 130 11 p p NOUN eurjchem-1613 130 12 that that SCONJ eurjchem-1613 130 13 the the DET eurjchem-1613 130 14 stab stab NOUN eurjchem-1613 130 15 evaluated evaluate VERB eurjchem-1613 130 16 at at ADP eurjchem-1613 130 17 a a DET eurjchem-1613 130 18 table table NOUN eurjchem-1613 130 19 3 3 NUM eurjchem-1613 130 20 s s PART eurjchem-1613 130 21 the the DET eurjchem-1613 130 22 solvent solvent NOUN eurjchem-1613 130 23 m m VERB eurjchem-1613 130 24 these these DET eurjchem-1613 130 25 compl compl NOUN eurjchem-1613 130 26 values value NOUN eurjchem-1613 130 27 were be AUX eurjchem-1613 130 28 order order NOUN eurjchem-1613 130 29 of of ADP eurjchem-1613 130 30 incre incre VERB eurjchem-1613 130 31 thm thm PROPN eurjchem-1613 130 32 of of ADP eurjchem-1613 130 33 the the DET eurjchem-1613 130 34 first first ADJ eurjchem-1613 130 35 and and CCONJ eurjchem-1613 130 36 values value NOUN eurjchem-1613 130 37 for for ADP eurjchem-1613 130 38 the the DET eurjchem-1613 130 39 corre corre PROPN eurjchem-1613 130 40 nd nd NOUN eurjchem-1613 130 41 δh δh NOUN eurjchem-1613 130 42 ° ° ADP eurjchem-1613 130 43 1 1 NUM eurjchem-1613 130 44 values value NOUN eurjchem-1613 130 45 for for ADP eurjchem-1613 130 46 t t PROPN eurjchem-1613 130 47 und und VERB eurjchem-1613 130 48 that that PRON eurjchem-1613 130 49 in in ADP eurjchem-1613 130 50 gen gen PROPN eurjchem-1613 130 51 on on ADP eurjchem-1613 130 52 complex complex ADJ eurjchem-1613 130 53 pr pr NOUN eurjchem-1613 130 54 attraction attraction NOUN eurjchem-1613 130 55 betw betw NOUN eurjchem-1613 130 56 re re PRON eurjchem-1613 130 57 electrostatic electrostatic PROPN eurjchem-1613 130 58 nds nds PROPN eurjchem-1613 130 59 are be AUX eurjchem-1613 130 60 not not PART eurjchem-1613 130 61 i i PRON eurjchem-1613 130 62 m m VERB eurjchem-1613 130 63 formation formation NOUN eurjchem-1613 130 64 cons con NOUN eurjchem-1613 130 65 at at ADP eurjchem-1613 130 66 the the DET eurjchem-1613 130 67 most most ADV eurjchem-1613 130 68 stab stab NOUN eurjchem-1613 130 69 e e NOUN eurjchem-1613 130 70 outcome outcome NOUN eurjchem-1613 130 71 of of ADP eurjchem-1613 130 72 q q NOUN eurjchem-1613 130 73 metal metal NOUN eurjchem-1613 130 74 ion‐trp ion‐trp NOUN eurjchem-1613 130 75 does do AUX eurjchem-1613 130 76 not not PART eurjchem-1613 130 77 contain contain VERB eurjchem-1613 130 78 in in ADP eurjchem-1613 130 79 does do AUX eurjchem-1613 130 80 not not PART eurjchem-1613 130 81 po po VERB eurjchem-1613 130 82 etal etal ADJ eurjchem-1613 130 83 ions ion NOUN eurjchem-1613 130 84 . . PUNCT eurjchem-1613 131 1 acco acco PROPN eurjchem-1613 131 2 m(try)2(h2o)2 m(try)2(h2o)2 PROPN eurjchem-1613 131 3 c c PROPN eurjchem-1613 131 4 most most ADV eurjchem-1613 131 5 stable stable ADJ eurjchem-1613 131 6 config config NOUN eurjchem-1613 131 7 urations uration NOUN eurjchem-1613 131 8 according accord VERB eurjchem-1613 131 9 sults sult NOUN eurjchem-1613 131 10 ) ) PUNCT eurjchem-1613 131 11 . . PUNCT eurjchem-1613 132 1 ation ation PROPN eurjchem-1613 132 2 of of ADP eurjchem-1613 132 3 natura natura PROPN eurjchem-1613 132 4 pb(ii)‐trp pb(ii)‐trp PROPN eurjchem-1613 132 5 has have VERB eurjchem-1613 132 6 b b DET eurjchem-1613 132 7 bility bility NOUN eurjchem-1613 132 8 constant constant ADJ eurjchem-1613 132 9 any any DET eurjchem-1613 132 10 temperatur temperatur NOUN eurjchem-1613 132 11 how how SCONJ eurjchem-1613 132 12 s s AUX eurjchem-1613 132 13 δg1 δg1 PROPN eurjchem-1613 132 14 ° ° PROPN eurjchem-1613 132 15 valu valu VERB eurjchem-1613 132 16 mixture mixture NOUN eurjchem-1613 132 17 . . PUNCT eurjchem-1613 133 1 the the DET eurjchem-1613 133 2 n n NUM eurjchem-1613 133 3 exation exation NOUN eurjchem-1613 133 4 proces proce NOUN eurjchem-1613 133 5 increased increase VERB eurjchem-1613 133 6 by by ADP eurjchem-1613 133 7 easing ease VERB eurjchem-1613 133 8 δg1 δg1 NOUN eurjchem-1613 133 9 ° ° PROPN eurjchem-1613 133 10 is be AUX eurjchem-1613 133 11 as as ADV eurjchem-1613 133 12 ghiama ghiama NOUN eurjchem-1613 134 1 d d NOUN eurjchem-1613 134 2 second second ADJ eurjchem-1613 134 3 stability stability NOUN eurjchem-1613 134 4 c c PROPN eurjchem-1613 134 5 kf1 kf1 PROPN eurjchem-1613 134 6 & & CCONJ eurjchem-1613 134 7 kf2 kf2 PROPN eurjchem-1613 135 1 kf1 kf1 PROPN eurjchem-1613 135 2 kf2 kf2 PROPN eurjchem-1613 136 1 kf1 kf1 PROPN eurjchem-1613 136 2 kf2 kf2 PROPN eurjchem-1613 137 1 kf1 kf1 PROPN eurjchem-1613 137 2 kf2 kf2 PROPN eurjchem-1613 138 1 kf1 kf1 PROPN eurjchem-1613 138 2 kf2 kf2 PROPN eurjchem-1613 139 1 kf1 kf1 PROPN eurjchem-1613 139 2 kf2 kf2 PROPN eurjchem-1613 140 1 kf1 kf1 PROPN eurjchem-1613 140 2 kf2 kf2 PROPN eurjchem-1613 140 3 esponding esponding PROPN eurjchem-1613 140 4 trp trp PROPN eurjchem-1613 140 5 com com NOUN eurjchem-1613 140 6 ‐δg ‐δg NOUN eurjchem-1613 140 7 ° ° ADP eurjchem-1613 140 8 1 1 NUM eurjchem-1613 140 9 ( ( PUNCT eurjchem-1613 140 10 kj kj PROPN eurjchem-1613 140 11 / / SYM eurjchem-1613 140 12 mol mol PROPN eurjchem-1613 140 13 ) ) PUNCT eurjchem-1613 140 14 25 25 NUM eurjchem-1613 140 15 ° ° PROPN eurjchem-1613 140 16 c c NOUN eurjchem-1613 140 17 6.48 6.48 NUM eurjchem-1613 140 18 5.21 5.21 NUM eurjchem-1613 140 19 5.69 5.69 NUM eurjchem-1613 140 20 6.30 6.30 NUM eurjchem-1613 140 21 5.21 5.21 NUM eurjchem-1613 140 22 5.61 5.61 NUM eurjchem-1613 140 23 the the DET eurjchem-1613 140 24 related relate VERB eurjchem-1613 140 25 trp trp PROPN eurjchem-1613 140 26 com com NOUN eurjchem-1613 140 27 δs δs NOUN eurjchem-1613 140 28 ° ° ADP eurjchem-1613 140 29 1 1 NUM eurjchem-1613 140 30 ( ( PUNCT eurjchem-1613 140 31 j j PROPN eurjchem-1613 140 32 / / SYM eurjchem-1613 140 33 mol mol PROPN eurjchem-1613 140 34 ) ) PUNCT eurjchem-1613 140 35 25 25 NUM eurjchem-1613 140 36 ° ° PROPN eurjchem-1613 140 37 c c ADP eurjchem-1613 140 38 33.15 33.15 NUM eurjchem-1613 140 39 47.55 47.55 NUM eurjchem-1613 140 40 27.92 27.92 NUM eurjchem-1613 140 41 30.65 30.65 NUM eurjchem-1613 140 42 45.59 45.59 NUM eurjchem-1613 140 43 29.51 29.51 NUM eurjchem-1613 140 44 neral neral PROPN eurjchem-1613 140 45 kf2 kf2 PROPN eurjchem-1613 140 46 > > X eurjchem-1613 141 1 kf1 kf1 PROPN eurjchem-1613 141 2 . . PUNCT eurjchem-1613 142 1 t t PROPN eurjchem-1613 142 2 rocess rocess PROPN eurjchem-1613 142 3 is be AUX eurjchem-1613 142 4 weake weake NOUN eurjchem-1613 142 5 ween ween PROPN eurjchem-1613 142 6 m2 m2 PROPN eurjchem-1613 142 7 + + PROPN eurjchem-1613 142 8 and and CCONJ eurjchem-1613 142 9 l‐ l‐ PROPN eurjchem-1613 142 10 c c PROPN eurjchem-1613 142 11 repulsion repulsion NOUN eurjchem-1613 142 12 an an DET eurjchem-1613 142 13 portant portant ADJ eurjchem-1613 142 14 factors factor NOUN eurjchem-1613 142 15 stant stant NOUN eurjchem-1613 142 16 value value NOUN eurjchem-1613 142 17 of of ADP eurjchem-1613 142 18 th th X eurjchem-1613 142 19 ble ble PROPN eurjchem-1613 142 20 configuratio configuratio NOUN eurjchem-1613 142 21 quantum quantum NOUN eurjchem-1613 142 22 mech mech NOUN eurjchem-1613 142 23 complexation complexation NOUN eurjchem-1613 142 24 , , PUNCT eurjchem-1613 142 25 n n CCONJ eurjchem-1613 142 26 any any DET eurjchem-1613 142 27 readily readily ADV eurjchem-1613 142 28 io io X eurjchem-1613 142 29 ossess ossess NOUN eurjchem-1613 142 30 any any DET eurjchem-1613 142 31 cle cle NOUN eurjchem-1613 142 32 ordingly ordingly ADV eurjchem-1613 142 33 , , PUNCT eurjchem-1613 142 34 the the DET eurjchem-1613 142 35 su su PROPN eurjchem-1613 142 36 complex complex NOUN eurjchem-1613 142 37 is be AUX eurjchem-1613 142 38 show show VERB eurjchem-1613 142 39 uration uration NOUN eurjchem-1613 142 40 of of ADP eurjchem-1613 142 41 trp trp PROPN eurjchem-1613 142 42 in in ADP eurjchem-1613 142 43 g g PROPN eurjchem-1613 142 44 to to ADP eurjchem-1613 142 45 quantum quantum PROPN eurjchem-1613 142 46 mech mech NOUN eurjchem-1613 142 47 al al PROPN eurjchem-1613 142 48 logarithm logarithm PROPN eurjchem-1613 142 49 of of SCONJ eurjchem-1613 142 50 been be AUX eurjchem-1613 142 51 shown show VERB eurjchem-1613 142 52 in in ADP eurjchem-1613 142 53 for for ADP eurjchem-1613 142 54 all all DET eurjchem-1613 142 55 the the DET eurjchem-1613 142 56 c c NOUN eurjchem-1613 142 57 re re NOUN eurjchem-1613 142 58 . . PUNCT eurjchem-1613 143 1 ues ues PROPN eurjchem-1613 143 2 for for ADP eurjchem-1613 143 3 the the DET eurjchem-1613 143 4 resp resp NOUN eurjchem-1613 143 5 negative negative ADJ eurjchem-1613 143 6 δg1 δg1 PROPN eurjchem-1613 143 7 ° ° ADP eurjchem-1613 143 8 v v NOUN eurjchem-1613 143 9 sses sse NOUN eurjchem-1613 143 10 are be AUX eurjchem-1613 143 11 spon spon ADV eurjchem-1613 143 12 enhancing enhance VERB eurjchem-1613 143 13 the the DET eurjchem-1613 143 14 s s NOUN eurjchem-1613 143 15 follows follow VERB eurjchem-1613 143 16 : : PUNCT eurjchem-1613 143 17 ati ati NOUN eurjchem-1613 143 18 and and CCONJ eurjchem-1613 143 19 abazari abazari ADJ eurjchem-1613 143 20 / / SYM eurjchem-1613 143 21 constants constant NOUN eurjchem-1613 143 22 of of ADP eurjchem-1613 143 23 the the DET eurjchem-1613 143 24 res re NOUN eurjchem-1613 143 25 t t PROPN eurjchem-1613 143 26 ( ( PUNCT eurjchem-1613 143 27 ° ° ADP eurjchem-1613 143 28 c c NOUN eurjchem-1613 143 29 ) ) PUNCT eurjchem-1613 143 30 25 25 NUM eurjchem-1613 143 31 9.86 9.86 NUM eurjchem-1613 143 32 19.02 19.02 NUM eurjchem-1613 143 33 6.12 6.12 NUM eurjchem-1613 143 34 10.99 10.99 NUM eurjchem-1613 143 35 7.34 7.34 NUM eurjchem-1613 143 36 13.46 13.46 NUM eurjchem-1613 143 37 9.33 9.33 NUM eurjchem-1613 143 38 17.31 17.31 NUM eurjchem-1613 143 39 6.15 6.15 NUM eurjchem-1613 143 40 10.98 10.98 NUM eurjchem-1613 143 41 7.20 7.20 NUM eurjchem-1613 143 42 12.92 12.92 NUM eurjchem-1613 143 43 mplexes mplexe NOUN eurjchem-1613 143 44 in in ADP eurjchem-1613 143 45 water water NOUN eurjchem-1613 143 46 : : PUNCT eurjchem-1613 143 47 di di NOUN eurjchem-1613 143 48 30 30 NUM eurjchem-1613 143 49 ° ° NUM eurjchem-1613 143 50 c c NOUN eurjchem-1613 143 51 6.63 6.63 NUM eurjchem-1613 143 52 5.44 5.44 NUM eurjchem-1613 143 53 5.84 5.84 NUM eurjchem-1613 143 54 6.41 6.41 NUM eurjchem-1613 143 55 5.44 5.44 NUM eurjchem-1613 143 56 5.78 5.78 NUM eurjchem-1613 143 57 mplexes mplexe NOUN eurjchem-1613 143 58 in in ADP eurjchem-1613 143 59 water water NOUN eurjchem-1613 143 60 : : PUNCT eurjchem-1613 144 1 d d NOUN eurjchem-1613 144 2 30 30 NUM eurjchem-1613 144 3 ° ° SYM eurjchem-1613 144 4 c c NOUN eurjchem-1613 144 5 33.07 33.07 NUM eurjchem-1613 144 6 47.51 47.51 NUM eurjchem-1613 144 7 27.95 27.95 NUM eurjchem-1613 144 8 30.51 30.51 NUM eurjchem-1613 144 9 44.87 44.87 NUM eurjchem-1613 144 10 29.65 29.65 NUM eurjchem-1613 144 11 this this PRON eurjchem-1613 144 12 means mean VERB eurjchem-1613 144 13 tha tha INTJ eurjchem-1613 145 1 er er INTJ eurjchem-1613 145 2 than than SCONJ eurjchem-1613 145 3 the the DET eurjchem-1613 145 4 se se PROPN eurjchem-1613 145 5 is be AUX eurjchem-1613 145 6 weaker weak ADJ eurjchem-1613 145 7 than than ADP eurjchem-1613 145 8 nd nd ADV eurjchem-1613 145 9 steric steric ADJ eurjchem-1613 145 10 hindr hindr NOUN eurjchem-1613 145 11 s s PROPN eurjchem-1613 145 12 for for ADP eurjchem-1613 145 13 the the DET eurjchem-1613 145 14 increa increa NOUN eurjchem-1613 145 15 he he PRON eurjchem-1613 145 16 complex complex PROPN eurjchem-1613 145 17 . . PUNCT eurjchem-1613 146 1 fig fig NOUN eurjchem-1613 146 2 on on ADP eurjchem-1613 146 3 of of ADP eurjchem-1613 146 4 trp trp PROPN eurjchem-1613 146 5 , , PUNCT eurjchem-1613 146 6 in in ADP eurjchem-1613 146 7 sol sol PROPN eurjchem-1613 146 8 hanical hanical ADJ eurjchem-1613 146 9 calculat calculat NOUN eurjchem-1613 146 10 indolyl indolyl NOUN eurjchem-1613 146 11 grou grou ADJ eurjchem-1613 146 12 onizable onizable ADJ eurjchem-1613 146 13 proton proton NOUN eurjchem-1613 146 14 early early ADV eurjchem-1613 146 15 defined define VERB eurjchem-1613 146 16 d d PROPN eurjchem-1613 146 17 uggested uggested ADJ eurjchem-1613 146 18 struc struc NOUN eurjchem-1613 146 19 we we PRON eurjchem-1613 146 20 d d PROPN eurjchem-1613 146 21 in in ADP eurjchem-1613 146 22 figure figure NOUN eurjchem-1613 146 23 4 4 NUM eurjchem-1613 146 24 . . PUNCT eurjchem-1613 146 25 liquid liquid ADJ eurjchem-1613 146 26 phase phase NOUN eurjchem-1613 146 27 , , PUNCT eurjchem-1613 146 28 amo amo PROPN eurjchem-1613 146 29 hanical hanical ADJ eurjchem-1613 146 30 calculation calculation NOUN eurjchem-1613 146 31 f f PROPN eurjchem-1613 146 32 kf1 kf1 NOUN eurjchem-1613 146 33 versus versus ADP eurjchem-1613 146 34 1 1 NUM eurjchem-1613 146 35 / / SYM eurjchem-1613 146 36 t t NOUN eurjchem-1613 146 37 n n PRON eurjchem-1613 146 38 figure figure VERB eurjchem-1613 146 39 5 5 NUM eurjchem-1613 146 40 , , PUNCT eurjchem-1613 146 41 mea mea NOUN eurjchem-1613 146 42 omplexes omplexe NOUN eurjchem-1613 146 43 coul coul PROPN eurjchem-1613 146 44 pective pective ADJ eurjchem-1613 146 45 complex complex ADJ eurjchem-1613 146 46 values value NOUN eurjchem-1613 146 47 indicate indicate VERB eurjchem-1613 146 48 ntaneous ntaneous ADJ eurjchem-1613 146 49 , , PUNCT eurjchem-1613 146 50 and and CCONJ eurjchem-1613 146 51 e e ADP eurjchem-1613 146 52 temperature temperature NOUN eurjchem-1613 146 53 . . PUNCT eurjchem-1613 147 1 / / SYM eurjchem-1613 147 2 european european PROPN eurjchem-1613 147 3 journ journ PROPN eurjchem-1613 147 4 spective spective ADJ eurjchem-1613 147 5 trp trp PROPN eurjchem-1613 147 6 comp comp PROPN eurjchem-1613 147 7 ioxane ioxane NOUN eurjchem-1613 147 8 mixture mixture NOUN eurjchem-1613 147 9 ( ( PUNCT eurjchem-1613 147 10 50 50 NUM eurjchem-1613 147 11 dioxane dioxane NOUN eurjchem-1613 147 12 mixture mixture NOUN eurjchem-1613 147 13 ( ( PUNCT eurjchem-1613 147 14 5 5 NUM eurjchem-1613 147 15 at at ADP eurjchem-1613 147 16 the the DET eurjchem-1613 147 17 econd econd NOUN eurjchem-1613 147 18 n n PRON eurjchem-1613 147 19 ml+ ml+ NOUN eurjchem-1613 147 20 rance rance NOUN eurjchem-1613 147 21 ase ase NOUN eurjchem-1613 147 22 in in ADP eurjchem-1613 147 23 ure ure PROPN eurjchem-1613 147 24 3 3 NUM eurjchem-1613 147 25 ution ution NOUN eurjchem-1613 147 26 tions tion NOUN eurjchem-1613 147 27 . . PUNCT eurjchem-1613 148 1 up up ADP eurjchem-1613 148 2 of of ADP eurjchem-1613 148 3 n n CCONJ eurjchem-1613 148 4 , , PUNCT eurjchem-1613 148 5 and and CCONJ eurjchem-1613 148 6 donor donor NOUN eurjchem-1613 148 7 ctural ctural NOUN eurjchem-1613 148 8 . . PUNCT eurjchem-1613 149 1 ong ong INTJ eurjchem-1613 150 1 22 22 NUM eurjchem-1613 150 2 ns ns INTJ eurjchem-1613 150 3 ( ( PUNCT eurjchem-1613 150 4 our our PRON eurjchem-1613 150 5 t t PROPN eurjchem-1613 150 6 for for ADP eurjchem-1613 150 7 aning aning PROPN eurjchem-1613 150 8 ld ld PROPN eurjchem-1613 150 9 be be AUX eurjchem-1613 150 10 xes xes PROPN eurjchem-1613 150 11 in in ADP eurjchem-1613 150 12 e e PROPN eurjchem-1613 150 13 that that DET eurjchem-1613 150 14 δg1 δg1 NOUN eurjchem-1613 150 15 ° ° PROPN eurjchem-1613 150 16 . . PUNCT eurjchem-1613 151 1 the the DET eurjchem-1613 151 2 δg1 δg1 PROPN eurjchem-1613 151 3 ° ° PROPN eurjchem-1613 151 4 figur figur PROPN eurjchem-1613 151 5 water water PROPN eurjchem-1613 151 6 t t PROPN eurjchem-1613 151 7 valu valu PROPN eurjchem-1613 151 8 chan chan PROPN eurjchem-1613 151 9 com com PROPN eurjchem-1613 151 10 incre incre PROPN eurjchem-1613 151 11 al al PROPN eurjchem-1613 151 12 of of ADP eurjchem-1613 151 13 chemistry chemistry NOUN eurjchem-1613 151 14 8 8 NUM eurjchem-1613 151 15 plexes plexe NOUN eurjchem-1613 151 16 in in ADP eurjchem-1613 151 17 water water NOUN eurjchem-1613 151 18 : : PUNCT eurjchem-1613 151 19 dio dio NOUN eurjchem-1613 152 1 30 30 NUM eurjchem-1613 152 2 9.99 9.99 NUM eurjchem-1613 152 3 19.25 19.25 NUM eurjchem-1613 152 4 6.50 6.50 NUM eurjchem-1613 152 5 11.55 11.55 NUM eurjchem-1613 152 6 7.51 7.51 NUM eurjchem-1613 152 7 13.73 13.73 NUM eurjchem-1613 152 8 9.35 9.35 NUM eurjchem-1613 152 9 17.73 17.73 NUM eurjchem-1613 152 10 6.35 6.35 NUM eurjchem-1613 152 11 11.24 11.24 NUM eurjchem-1613 152 12 7.32 7.32 NUM eurjchem-1613 152 13 13.39 13.39 NUM eurjchem-1613 152 14 0:50 0:50 NUM eurjchem-1613 152 15 , , PUNCT eurjchem-1613 152 16 v v NOUN eurjchem-1613 152 17 : : PUNCT eurjchem-1613 152 18 v v NOUN eurjchem-1613 152 19 ) ) PUNCT eurjchem-1613 152 20 . . PUNCT eurjchem-1613 153 1 35 35 NUM eurjchem-1613 153 2 ° ° NUM eurjchem-1613 153 3 c c PROPN eurjchem-1613 153 4 6.81 6.81 NUM eurjchem-1613 153 5 5.60 5.60 NUM eurjchem-1613 153 6 5.96 5.96 NUM eurjchem-1613 153 7 6.59 6.59 NUM eurjchem-1613 153 8 5.60 5.60 NUM eurjchem-1613 153 9 5.92 5.92 NUM eurjchem-1613 153 10 50:50 50:50 NUM eurjchem-1613 153 11 , , PUNCT eurjchem-1613 153 12 v v ADP eurjchem-1613 153 13 : : PUNCT eurjchem-1613 153 14 v v NOUN eurjchem-1613 153 15 ) ) PUNCT eurjchem-1613 153 16 . . PUNCT eurjchem-1613 154 1 35 35 NUM eurjchem-1613 154 2 ° ° NUM eurjchem-1613 154 3 c c ADP eurjchem-1613 154 4 33.13 33.13 NUM eurjchem-1613 154 5 47.26 47.26 NUM eurjchem-1613 154 6 27.88 27.88 NUM eurjchem-1613 154 7 30.60 30.60 NUM eurjchem-1613 154 8 44.73 44.73 NUM eurjchem-1613 154 9 29.65 29.65 NUM eurjchem-1613 154 10 ° ° NOUN eurjchem-1613 155 1 zn zn PROPN eurjchem-1613 155 2 ( ( PUNCT eurjchem-1613 155 3 ii)‐trp ii)‐trp PROPN eurjchem-1613 155 4   PUNCT eurjchem-1613 155 5 δg1 δg1 PROPN eurjchem-1613 155 6 ° ° NOUN eurjchem-1613 155 7 … … PUNCT eurjchem-1613 155 8 δg1 δg1 NOUN eurjchem-1613 155 9 ° ° NOUN eurjchem-1613 155 10 ni(ii)‐trp ni(ii)‐trp VERB eurjchem-1613 155 11 < < X eurjchem-1613 156 1 hn hn PRON eurjchem-1613 156 2 figure figure NOUN eurjchem-1613 156 3 4 4 NUM eurjchem-1613 156 4 . . PUNCT eurjchem-1613 157 1 the the DET eurjchem-1613 157 2 p p X eurjchem-1613 157 3 re re ADP eurjchem-1613 157 4 5 5 NUM eurjchem-1613 157 5 . . PUNCT eurjchem-1613 158 1 a a DET eurjchem-1613 158 2 plot plot NOUN eurjchem-1613 158 3 of of ADP eurjchem-1613 158 4 lo lo PROPN eurjchem-1613 158 5 r r NOUN eurjchem-1613 158 6 : : PUNCT eurjchem-1613 158 7 dioxane dioxane NOUN eurjchem-1613 158 8 mixture mixture NOUN eurjchem-1613 158 9 . . PUNCT eurjchem-1613 159 1 the the DET eurjchem-1613 159 2 data datum NOUN eurjchem-1613 159 3 in in ADP eurjchem-1613 159 4 tab tab NOUN eurjchem-1613 159 5 ues ue NOUN eurjchem-1613 159 6 , , PUNCT eurjchem-1613 159 7 for for ADP eurjchem-1613 159 8 those those PRON eurjchem-1613 159 9 c c PROPN eurjchem-1613 159 10 nge nge NOUN eurjchem-1613 159 11 enforces enforce VERB eurjchem-1613 159 12 th th X eurjchem-1613 159 13 mpletion mpletion NOUN eurjchem-1613 159 14 of of ADP eurjchem-1613 159 15 the the DET eurjchem-1613 159 16 eased eased ADJ eurjchem-1613 159 17 . . PUNCT eurjchem-1613 160 1 8 8 NUM eurjchem-1613 160 2 ( ( PUNCT eurjchem-1613 160 3 4 4 NUM eurjchem-1613 160 4 ) ) PUNCT eurjchem-1613 160 5 ( ( PUNCT eurjchem-1613 160 6 2017 2017 NUM eurjchem-1613 160 7 ) ) PUNCT eurjchem-1613 160 8 333 333 NUM eurjchem-1613 160 9 xane xane NOUN eurjchem-1613 160 10 mixture mixture NOUN eurjchem-1613 160 11 ( ( PUNCT eurjchem-1613 160 12 50 50 NUM eurjchem-1613 160 13 : : SYM eurjchem-1613 160 14 35 35 NUM eurjchem-1613 160 15 10.24 10.24 NUM eurjchem-1613 160 16 19.91 19.91 NUM eurjchem-1613 160 17 6.58 6.58 NUM eurjchem-1613 160 18 12.04 12.04 NUM eurjchem-1613 160 19 7.60 7.60 NUM eurjchem-1613 160 20 13.80 13.80 NUM eurjchem-1613 160 21 9.43 9.43 NUM eurjchem-1613 160 22 18.26 18.26 NUM eurjchem-1613 160 23 6.57 6.57 NUM eurjchem-1613 160 24 11.67 11.67 NUM eurjchem-1613 160 25 7.55 7.55 NUM eurjchem-1613 160 26 13.53 13.53 NUM eurjchem-1613 160 27 40 40 NUM eurjchem-1613 160 28 ° ° ADP eurjchem-1613 160 29 c c NOUN eurjchem-1613 160 30 6.96 6.96 NUM eurjchem-1613 160 31 5.96 5.96 NUM eurjchem-1613 160 32 6.12 6.12 NUM eurjchem-1613 160 33 6.75 6.75 NUM eurjchem-1613 160 34 5.96 5.96 NUM eurjchem-1613 160 35 6.06 6.06 NUM eurjchem-1613 160 36 40 40 NUM eurjchem-1613 160 37 ° ° ADP eurjchem-1613 160 38 c c ADP eurjchem-1613 160 39 33.08 33.08 NUM eurjchem-1613 160 40 47.65 47.65 NUM eurjchem-1613 160 41 27.95 27.95 NUM eurjchem-1613 160 42 30.62 30.62 NUM eurjchem-1613 160 43 45.14 45.14 NUM eurjchem-1613 160 44 29.51 29.51 NUM eurjchem-1613 160 45 co co X eurjchem-1613 160 46 ( ( PUNCT eurjchem-1613 160 47 ii)‐trp ii)‐trp PROPN eurjchem-1613 160 48 < < X eurjchem-1613 160 49 δg1 δg1 PROPN eurjchem-1613 160 50 ° ° NOUN eurjchem-1613 161 1 p p X eurjchem-1613 161 2 < < X eurjchem-1613 161 3 δg1 δg1 PROPN eurjchem-1613 161 4 ° ° PROPN eurjchem-1613 161 5 cu(ii)‐trp cu(ii)‐trp X eurjchem-1613 161 6 < < X eurjchem-1613 162 1 δ δ PROPN eurjchem-1613 162 2 nh2 nh2 PROPN eurjchem-1613 162 3 ho ho PROPN eurjchem-1613 163 1 o o PROPN eurjchem-1613 163 2 m m NOUN eurjchem-1613 163 3 h h NOUN eurjchem-1613 163 4 h h PROPN eurjchem-1613 163 5 proposed propose VERB eurjchem-1613 163 6 structure structure NOUN eurjchem-1613 163 7 og og PROPN eurjchem-1613 163 8 kf1 kf1 PROPN eurjchem-1613 163 9 vs. vs. ADP eurjchem-1613 163 10 1 1 NUM eurjchem-1613 163 11 / / SYM eurjchem-1613 163 12 t t PROPN eurjchem-1613 163 13 for for ADP eurjchem-1613 163 14 . . PUNCT eurjchem-1613 164 1 ble ble ADJ eurjchem-1613 164 2 4 4 NUM eurjchem-1613 164 3 shows show VERB eurjchem-1613 164 4 tha tha NOUN eurjchem-1613 164 5 complexes complex NOUN eurjchem-1613 164 6 at at ADP eurjchem-1613 164 7 2 2 NUM eurjchem-1613 164 8 e e NOUN eurjchem-1613 164 9 spontaneity spontaneity NOUN eurjchem-1613 164 10 o o NOUN eurjchem-1613 164 11 e e NOUN eurjchem-1613 164 12 reaction reaction NOUN eurjchem-1613 164 13 bec bec PROPN eurjchem-1613 164 14 ‐338 ‐338 PROPN eurjchem-1613 164 15 50 50 NUM eurjchem-1613 164 16 , , PUNCT eurjchem-1613 164 17 v v NOUN eurjchem-1613 164 18 : : PUNCT eurjchem-1613 164 19 v v NOUN eurjchem-1613 164 20 ) ) PUNCT eurjchem-1613 164 21 . . PUNCT eurjchem-1613 165 1 40 40 NUM eurjchem-1613 165 2 10.35 10.35 NUM eurjchem-1613 165 3 20.23 20.23 NUM eurjchem-1613 165 4 7.26 7.26 NUM eurjchem-1613 165 5 13.44 13.44 NUM eurjchem-1613 165 6 7.72 7.72 NUM eurjchem-1613 165 7 14.24 14.24 NUM eurjchem-1613 165 8 9.72 9.72 NUM eurjchem-1613 165 9 18.43 18.43 NUM eurjchem-1613 165 10 7.16 7.16 NUM eurjchem-1613 165 11 13.13 13.13 NUM eurjchem-1613 165 12 7.62 7.62 NUM eurjchem-1613 165 13 13.79 13.79 NUM eurjchem-1613 165 14 δh δh NOUN eurjchem-1613 165 15 ° ° NOUN eurjchem-1613 165 16 1 1 NUM eurjchem-1613 165 17 3.40 3.40 NUM eurjchem-1613 165 18 9.52 9.52 NUM eurjchem-1613 165 19 2.63 2.63 NUM eurjchem-1613 165 20 3.07 3.07 NUM eurjchem-1613 165 21 8.22 8.22 NUM eurjchem-1613 165 22 3.18 3.18 NUM eurjchem-1613 165 23 b b NOUN eurjchem-1613 165 24 ( ( PUNCT eurjchem-1613 165 25 ii)‐trp ii)‐trp PROPN eurjchem-1613 165 26 < < X eurjchem-1613 165 27 … … PUNCT eurjchem-1613 165 28 δg1 δg1 PROPN eurjchem-1613 165 29 ° ° SYM eurjchem-1613 165 30 fe fe X eurjchem-1613 165 31 ( ( PUNCT eurjchem-1613 165 32 iii)‐ iii)‐ VERB eurjchem-1613 165 33 trp trp PROPN eurjchem-1613 165 34 nh2 nh2 PROPN eurjchem-1613 165 35 oho oho PROPN eurjchem-1613 165 36 mn+ mn+ NOUN eurjchem-1613 165 37 h2o h2o VERB eurjchem-1613 165 38 h2o h2o PROPN eurjchem-1613 165 39 e e PROPN eurjchem-1613 165 40 of of ADP eurjchem-1613 165 41 metal metal NOUN eurjchem-1613 165 42 ion‐trp ion‐trp PROPN eurjchem-1613 165 43 pb(ii)‐trp pb(ii)‐trp VERB eurjchem-1613 165 44 comple comple ADJ eurjchem-1613 165 45 at at ADP eurjchem-1613 165 46 all all DET eurjchem-1613 165 47 δs1 δs1 NOUN eurjchem-1613 165 48 ° ° PART eurjchem-1613 165 49 posse posse NOUN eurjchem-1613 165 50 25‐40 25‐40 NOUN eurjchem-1613 165 51 ° ° ADP eurjchem-1613 165 52 c c VERB eurjchem-1613 165 53 . . PUNCT eurjchem-1613 166 1 here here ADV eurjchem-1613 166 2 of of ADP eurjchem-1613 166 3 the the DET eurjchem-1613 166 4 reaction reaction NOUN eurjchem-1613 166 5 a a DET eurjchem-1613 166 6 cause cause NOUN eurjchem-1613 166 7 disorder disorder NOUN eurjchem-1613 166 8 5 5 NUM eurjchem-1613 166 9 3 3 NUM eurjchem-1613 166 10 4 4 NUM eurjchem-1613 166 11 4 4 NUM eurjchem-1613 166 12 3 3 NUM eurjchem-1613 166 13 3 3 NUM eurjchem-1613 166 14 9 9 NUM eurjchem-1613 166 15 ( ( PUNCT eurjchem-1613 166 16 kj kj PROPN eurjchem-1613 166 17 / / SYM eurjchem-1613 166 18 mol mol PROPN eurjchem-1613 166 19 ) ) PUNCT eurjchem-1613 166 20 ( ( PUNCT eurjchem-1613 166 21 33 33 NUM eurjchem-1613 166 22 ) ) PUNCT eurjchem-1613 166 23 nh nh PROPN eurjchem-1613 166 24 complex complex NOUN eurjchem-1613 166 25 . . PUNCT eurjchem-1613 167 1 ex ex X eurjchem-1613 167 2 in in ADP eurjchem-1613 167 3 50:50 50:50 NUM eurjchem-1613 167 4 ( ( PUNCT eurjchem-1613 167 5 v v NOUN eurjchem-1613 167 6 : : PUNCT eurjchem-1613 167 7 v v NOUN eurjchem-1613 167 8 ) ) PUNCT eurjchem-1613 167 9 essing esse VERB eurjchem-1613 167 10 positive positive ADJ eurjchem-1613 167 11 e e NOUN eurjchem-1613 167 12 the the DET eurjchem-1613 167 13 entropy entropy NOUN eurjchem-1613 167 14 and and CCONJ eurjchem-1613 167 15 favors favor VERB eurjchem-1613 167 16 the the DET eurjchem-1613 167 17 ing ing NOUN eurjchem-1613 167 18 has have AUX eurjchem-1613 167 19 been be AUX eurjchem-1613 167 20 ghiamati ghiamati ADJ eurjchem-1613 167 21 and and CCONJ eurjchem-1613 167 22 abazari abazari ADJ eurjchem-1613 167 23 / / SYM eurjchem-1613 167 24 european european ADJ eurjchem-1613 167 25 journal journal PROPN eurjchem-1613 167 26 of of ADP eurjchem-1613 167 27 chemistry chemistry NOUN eurjchem-1613 167 28 8 8 NUM eurjchem-1613 167 29 ( ( PUNCT eurjchem-1613 167 30 4 4 NUM eurjchem-1613 167 31 ) ) PUNCT eurjchem-1613 167 32 ( ( PUNCT eurjchem-1613 167 33 2017 2017 NUM eurjchem-1613 167 34 ) ) PUNCT eurjchem-1613 167 35 333‐338 333‐338 NUM eurjchem-1613 167 36 337 337 NUM eurjchem-1613 167 37 table table NOUN eurjchem-1613 167 38 5 5 NUM eurjchem-1613 167 39 . . PUNCT eurjchem-1613 167 40 activation activation NOUN eurjchem-1613 167 41 energy energy NOUN eurjchem-1613 167 42 ( ( PUNCT eurjchem-1613 167 43 ea ea NOUN eurjchem-1613 167 44 ) ) PUNCT eurjchem-1613 167 45 and and CCONJ eurjchem-1613 167 46 the the DET eurjchem-1613 167 47 rate rate NOUN eurjchem-1613 167 48 constant constant ADJ eurjchem-1613 167 49 ( ( PUNCT eurjchem-1613 167 50 k k NOUN eurjchem-1613 167 51 ) ) PUNCT eurjchem-1613 167 52 values value NOUN eurjchem-1613 167 53 for for ADP eurjchem-1613 167 54 the the DET eurjchem-1613 167 55 pertinent pertinent ADJ eurjchem-1613 167 56 trp trp PROPN eurjchem-1613 167 57 complexes complex NOUN eurjchem-1613 167 58 in in ADP eurjchem-1613 167 59 water water NOUN eurjchem-1613 167 60 : : PUNCT eurjchem-1613 167 61 dioxane dioxane NOUN eurjchem-1613 167 62 mixture mixture NOUN eurjchem-1613 167 63 ( ( PUNCT eurjchem-1613 167 64 50:50 50:50 NUM eurjchem-1613 167 65 , , PUNCT eurjchem-1613 167 66 v v NOUN eurjchem-1613 167 67 : : PUNCT eurjchem-1613 167 68 v v NOUN eurjchem-1613 167 69 ) ) PUNCT eurjchem-1613 167 70 . . PUNCT eurjchem-1613 168 1 complex complex ADJ eurjchem-1613 168 2 ea ea PROPN eurjchem-1613 168 3 ( ( PUNCT eurjchem-1613 168 4 j j PROPN eurjchem-1613 168 5 / / SYM eurjchem-1613 168 6 mol mol PROPN eurjchem-1613 168 7 ) ) PUNCT eurjchem-1613 168 8 k k NOUN eurjchem-1613 168 9 ( ( PUNCT eurjchem-1613 168 10 1 1 NUM eurjchem-1613 168 11 / / SYM eurjchem-1613 168 12 s s NOUN eurjchem-1613 168 13 ) ) PUNCT eurjchem-1613 168 14 25 25 NUM eurjchem-1613 168 15 ° ° NUM eurjchem-1613 168 16 c c NOUN eurjchem-1613 168 17 30 30 NUM eurjchem-1613 168 18 ° ° SYM eurjchem-1613 168 19 c c NOUN eurjchem-1613 168 20 35 35 NUM eurjchem-1613 168 21 ° ° SYM eurjchem-1613 168 22 c c PROPN eurjchem-1613 168 23 40 40 NUM eurjchem-1613 168 24 ° ° NOUN eurjchem-1613 168 25 c c NOUN eurjchem-1613 168 26 fe(iii)‐trp fe(iii)‐trp NOUN eurjchem-1613 168 27 9.56×104 9.56×104 NOUN eurjchem-1613 168 28 2.84×10‐7 2.84×10‐7 NUM eurjchem-1613 168 29 5.12×10‐7 5.12×10‐7 NUM eurjchem-1613 168 30 9.15×10‐7 9.15×10‐7 NUM eurjchem-1613 168 31 1.83×10‐6 1.83×10‐6 NUM eurjchem-1613 168 32 co(ii)‐trp co(ii)‐trp NOUN eurjchem-1613 168 33 1.09×105 1.09×105 ADJ eurjchem-1613 168 34 1.76×10‐7 1.76×10‐7 NUM eurjchem-1613 168 35 3.18×10‐7 3.18×10‐7 NUM eurjchem-1613 168 36 7.05×10‐7 7.05×10‐7 NUM eurjchem-1613 168 37 1.41×10‐6 1.41×10‐6 NUM eurjchem-1613 168 38 ni(ii)‐trp ni(ii)‐trp NOUN eurjchem-1613 168 39 1.08×105 1.08×105 NUM eurjchem-1613 168 40 2.20×10‐7 2.20×10‐7 NUM eurjchem-1613 168 41 4.24×10‐7 4.24×10‐7 NUM eurjchem-1613 168 42 8.36×10‐7 8.36×10‐7 NUM eurjchem-1613 168 43 1.79×10‐6 1.79×10‐6 NUM eurjchem-1613 168 44 cu(ii)‐trp cu(ii)‐trp NOUN eurjchem-1613 168 45 1.13×105 1.13×105 NUM eurjchem-1613 168 46 2.41×10‐7 2.41×10‐7 NUM eurjchem-1613 168 47 4.93×10‐7 4.93×10‐7 NUM eurjchem-1613 168 48 9.75×10‐7 9.75×10‐7 NOUN eurjchem-1613 168 49 2.18×10‐6 2.18×10‐6 NUM eurjchem-1613 168 50 zn(ii)‐trp zn(ii)‐trp NOUN eurjchem-1613 168 51 9.52×104 9.52×104 VERB eurjchem-1613 168 52 1.82×10‐7 1.82×10‐7 NUM eurjchem-1613 168 53 3.40×10‐7 3.40×10‐7 NUM eurjchem-1613 168 54 6.93×10‐7 6.93×10‐7 NOUN eurjchem-1613 168 55 1.11×10‐6 1.11×10‐6 NUM eurjchem-1613 168 56 pb(ii)‐trp pb(ii)‐trp VERB eurjchem-1613 168 57 1.29×105 1.29×105 NUM eurjchem-1613 168 58 2.00×10‐7 2.00×10‐7 NUM eurjchem-1613 168 59 3.70×10‐7 3.70×10‐7 NUM eurjchem-1613 168 60 8.11×10‐7 8.11×10‐7 NUM eurjchem-1613 168 61 2.50×10‐6 2.50×10‐6 NUM eurjchem-1613 168 62 δh1 δh1 NOUN eurjchem-1613 168 63 ° ° ADJ eurjchem-1613 168 64 values value NOUN eurjchem-1613 168 65 are be AUX eurjchem-1613 168 66 positive positive ADJ eurjchem-1613 168 67 and and CCONJ eurjchem-1613 168 68 independent independent ADJ eurjchem-1613 168 69 of of ADP eurjchem-1613 168 70 temperature temperature NOUN eurjchem-1613 168 71 , , PUNCT eurjchem-1613 168 72 also also ADV eurjchem-1613 168 73 the the DET eurjchem-1613 168 74 temperature temperature NOUN eurjchem-1613 168 75 increase increase NOUN eurjchem-1613 168 76 affects affect VERB eurjchem-1613 168 77 the the DET eurjchem-1613 168 78 complexation complexation NOUN eurjchem-1613 168 79 . . PUNCT eurjchem-1613 169 1 because because SCONJ eurjchem-1613 169 2 m+2 m+2 NOUN eurjchem-1613 169 3 ions ion NOUN eurjchem-1613 169 4 exert exert VERB eurjchem-1613 169 5 solvation solvation NOUN eurjchem-1613 169 6 effect effect NOUN eurjchem-1613 169 7 and and CCONJ eurjchem-1613 169 8 l‐ l‐ PROPN eurjchem-1613 169 9 and and CCONJ eurjchem-1613 169 10 m+2 m+2 NOUN eurjchem-1613 169 11 ions ion NOUN eurjchem-1613 169 12 with with ADP eurjchem-1613 169 13 opposite opposite ADJ eurjchem-1613 169 14 charge charge NOUN eurjchem-1613 169 15 could could AUX eurjchem-1613 169 16 break break VERB eurjchem-1613 169 17 , , PUNCT eurjchem-1613 169 18 causing cause VERB eurjchem-1613 169 19 h h NOUN eurjchem-1613 169 20 ° ° NOUN eurjchem-1613 169 21 and and CCONJ eurjchem-1613 169 22 s s NOUN eurjchem-1613 169 23 ° ° NOUN eurjchem-1613 169 24 to to PART eurjchem-1613 169 25 become become VERB eurjchem-1613 169 26 positive positive ADJ eurjchem-1613 169 27 . . PUNCT eurjchem-1613 170 1 although although SCONJ eurjchem-1613 170 2 the the DET eurjchem-1613 170 3 process process NOUN eurjchem-1613 170 4 of of ADP eurjchem-1613 170 5 trp trp PROPN eurjchem-1613 170 6 complex complex ADJ eurjchem-1613 170 7 formation formation NOUN eurjchem-1613 170 8 with with ADP eurjchem-1613 170 9 a a DET eurjchem-1613 170 10 metal metal NOUN eurjchem-1613 170 11 ion ion NOUN eurjchem-1613 170 12 has have VERB eurjchem-1613 170 13 an an DET eurjchem-1613 170 14 endothermic endothermic ADJ eurjchem-1613 170 15 nature nature NOUN eurjchem-1613 170 16 as as ADP eurjchem-1613 170 17 a a DET eurjchem-1613 170 18 result result NOUN eurjchem-1613 170 19 of of ADP eurjchem-1613 170 20 the the DET eurjchem-1613 170 21 positive positive ADJ eurjchem-1613 170 22 δh δh NOUN eurjchem-1613 170 23 ° ° PROPN eurjchem-1613 170 24 value value NOUN eurjchem-1613 170 25 , , PUNCT eurjchem-1613 170 26 it it PRON eurjchem-1613 170 27 could could AUX eurjchem-1613 170 28 be be AUX eurjchem-1613 170 29 concluded conclude VERB eurjchem-1613 170 30 that that SCONJ eurjchem-1613 170 31 the the DET eurjchem-1613 170 32 second second ADJ eurjchem-1613 170 33 formation formation NOUN eurjchem-1613 170 34 step step NOUN eurjchem-1613 170 35 of of ADP eurjchem-1613 170 36 complex complex NOUN eurjchem-1613 170 37 is be AUX eurjchem-1613 170 38 highly highly ADV eurjchem-1613 170 39 spontaneous spontaneous ADJ eurjchem-1613 170 40 compared compare VERB eurjchem-1613 170 41 to to ADP eurjchem-1613 170 42 the the DET eurjchem-1613 170 43 first first ADJ eurjchem-1613 170 44 formation formation NOUN eurjchem-1613 170 45 step step NOUN eurjchem-1613 170 46 . . PUNCT eurjchem-1613 171 1 positive positive ADJ eurjchem-1613 171 2 h h NOUN eurjchem-1613 171 3 ° ° NOUN eurjchem-1613 171 4 and and CCONJ eurjchem-1613 171 5 s s NOUN eurjchem-1613 171 6 ° ° PROPN eurjchem-1613 171 7 means mean VERB eurjchem-1613 171 8 that that SCONJ eurjchem-1613 171 9 the the DET eurjchem-1613 171 10 reactions reaction NOUN eurjchem-1613 171 11 become become VERB eurjchem-1613 171 12 spontaneous spontaneous ADJ eurjchem-1613 171 13 at at ADP eurjchem-1613 171 14 higher high ADJ eurjchem-1613 171 15 temperatures temperature NOUN eurjchem-1613 171 16 . . PUNCT eurjchem-1613 172 1 regarding regard VERB eurjchem-1613 172 2 using use VERB eurjchem-1613 172 3 dioxane dioxane NOUN eurjchem-1613 172 4 as as ADP eurjchem-1613 172 5 a a DET eurjchem-1613 172 6 co‐solvent co‐solvent ADJ eurjchem-1613 172 7 , , PUNCT eurjchem-1613 172 8 1,4‐dioxane‐ 1,4‐dioxane‐ ADJ eurjchem-1613 172 9 water water NOUN eurjchem-1613 172 10 mixture mixture NOUN eurjchem-1613 172 11 is be AUX eurjchem-1613 172 12 a a DET eurjchem-1613 172 13 well‐defined well‐defined ADJ eurjchem-1613 172 14 solvent solvent NOUN eurjchem-1613 172 15 . . PUNCT eurjchem-1613 173 1 changes change NOUN eurjchem-1613 173 2 in in ADP eurjchem-1613 173 3 stability stability NOUN eurjchem-1613 173 4 constants constant NOUN eurjchem-1613 173 5 upon upon SCONJ eurjchem-1613 173 6 addition addition NOUN eurjchem-1613 173 7 of of ADP eurjchem-1613 173 8 1,4‐dioxane 1,4‐dioxane NUM eurjchem-1613 173 9 to to ADP eurjchem-1613 173 10 aqueous aqueous ADJ eurjchem-1613 173 11 solution solution NOUN eurjchem-1613 173 12 is be AUX eurjchem-1613 173 13 due due ADJ eurjchem-1613 173 14 to to PART eurjchem-1613 173 15 increase increase VERB eurjchem-1613 173 16 in in ADP eurjchem-1613 173 17 ion‐ion ion‐ion NOUN eurjchem-1613 173 18 interactions interaction NOUN eurjchem-1613 173 19 resulting result VERB eurjchem-1613 173 20 from from ADP eurjchem-1613 173 21 both both CCONJ eurjchem-1613 173 22 the the DET eurjchem-1613 173 23 decreasing decrease VERB eurjchem-1613 173 24 dielectric dielectric ADJ eurjchem-1613 173 25 constant constant ADJ eurjchem-1613 173 26 and and CCONJ eurjchem-1613 173 27 the the DET eurjchem-1613 173 28 change change NOUN eurjchem-1613 173 29 in in ADP eurjchem-1613 173 30 solvent‐ion solvent‐ion NOUN eurjchem-1613 173 31 and and CCONJ eurjchem-1613 173 32 solvent‐solvent solvent‐solvent NOUN eurjchem-1613 173 33 interactions interaction NOUN eurjchem-1613 173 34 . . PUNCT eurjchem-1613 174 1 as as ADP eurjchem-1613 174 2 the the DET eurjchem-1613 174 3 dielectric dielectric ADJ eurjchem-1613 174 4 constant constant ADJ eurjchem-1613 174 5 decreases decrease NOUN eurjchem-1613 174 6 , , PUNCT eurjchem-1613 174 7 the the DET eurjchem-1613 174 8 ion ion NOUN eurjchem-1613 174 9 interaction interaction NOUN eurjchem-1613 174 10 involving involve VERB eurjchem-1613 174 11 the the DET eurjchem-1613 174 12 proton proton NOUN eurjchem-1613 174 13 and and CCONJ eurjchem-1613 174 14 anionic anionic ADJ eurjchem-1613 174 15 oxygen oxygen NOUN eurjchem-1613 174 16 on on ADP eurjchem-1613 174 17 the the DET eurjchem-1613 174 18 amino amino NOUN eurjchem-1613 174 19 acid acid NOUN eurjchem-1613 174 20 decreases decrease VERB eurjchem-1613 174 21 to to ADP eurjchem-1613 174 22 a a DET eurjchem-1613 174 23 greater great ADJ eurjchem-1613 174 24 extent extent NOUN eurjchem-1613 174 25 than than ADP eurjchem-1613 174 26 the the DET eurjchem-1613 174 27 ion ion NOUN eurjchem-1613 174 28 dipole dipole NOUN eurjchem-1613 174 29 interaction interaction NOUN eurjchem-1613 174 30 between between ADP eurjchem-1613 174 31 the the DET eurjchem-1613 174 32 proton proton NOUN eurjchem-1613 174 33 and and CCONJ eurjchem-1613 174 34 the the DET eurjchem-1613 174 35 solvent solvent ADJ eurjchem-1613 174 36 molecules molecule NOUN eurjchem-1613 174 37 . . PUNCT eurjchem-1613 175 1 co‐solvent co‐solvent ADJ eurjchem-1613 175 2 influences influence VERB eurjchem-1613 175 3 the the DET eurjchem-1613 175 4 protonation‐deproto‐ protonation‐deproto‐ PROPN eurjchem-1613 175 5 nation nation NOUN eurjchem-1613 175 6 equilibria equilibrium NOUN eurjchem-1613 175 7 in in ADP eurjchem-1613 175 8 solution solution NOUN eurjchem-1613 175 9 by by ADP eurjchem-1613 175 10 changing change VERB eurjchem-1613 175 11 the the DET eurjchem-1613 175 12 dielectric dielectric ADJ eurjchem-1613 175 13 constant constant ADJ eurjchem-1613 175 14 of of ADP eurjchem-1613 175 15 the the DET eurjchem-1613 175 16 medium medium NOUN eurjchem-1613 175 17 , , PUNCT eurjchem-1613 175 18 which which PRON eurjchem-1613 175 19 varies vary VERB eurjchem-1613 175 20 the the DET eurjchem-1613 175 21 relative relative ADJ eurjchem-1613 175 22 contri‐ contri‐ PROPN eurjchem-1613 175 23 butions bution NOUN eurjchem-1613 175 24 of of ADP eurjchem-1613 175 25 electrostatic electrostatic ADJ eurjchem-1613 175 26 and and CCONJ eurjchem-1613 175 27 non‐electrostatic non‐electrostatic ADJ eurjchem-1613 175 28 interacttions interacttion NOUN eurjchem-1613 175 29 . . PUNCT eurjchem-1613 176 1 our our PRON eurjchem-1613 176 2 outcomes outcome NOUN eurjchem-1613 176 3 demonstrate demonstrate VERB eurjchem-1613 176 4 that that SCONJ eurjchem-1613 176 5 cu(ii cu(ii PROPN eurjchem-1613 176 6 ) ) PUNCT eurjchem-1613 176 7 complexes complex NOUN eurjchem-1613 176 8 are be AUX eurjchem-1613 176 9 more more ADV eurjchem-1613 176 10 stable stable ADJ eurjchem-1613 176 11 than than ADP eurjchem-1613 176 12 the the DET eurjchem-1613 176 13 other other ADJ eurjchem-1613 176 14 metal metal NOUN eurjchem-1613 176 15 ion ion NOUN eurjchem-1613 176 16 complexes complex NOUN eurjchem-1613 176 17 as as ADP eurjchem-1613 176 18 a a DET eurjchem-1613 176 19 result result NOUN eurjchem-1613 176 20 of of ADP eurjchem-1613 176 21 the the DET eurjchem-1613 176 22 larger large ADJ eurjchem-1613 176 23 ratio ratio NOUN eurjchem-1613 176 24 of of ADP eurjchem-1613 176 25 valance valance NOUN eurjchem-1613 176 26 / / SYM eurjchem-1613 176 27 radius radius NOUN eurjchem-1613 176 28 and and CCONJ eurjchem-1613 176 29 the the DET eurjchem-1613 176 30 jahn‐teller jahn‐teller NOUN eurjchem-1613 176 31 effect effect NOUN eurjchem-1613 176 32 . . PUNCT eurjchem-1613 177 1 figure figure NOUN eurjchem-1613 177 2 6 6 NUM eurjchem-1613 177 3 shows show VERB eurjchem-1613 177 4 a a DET eurjchem-1613 177 5 potential potential ADJ eurjchem-1613 177 6 energy energy NOUN eurjchem-1613 177 7 diagram diagram NOUN eurjchem-1613 177 8 for for ADP eurjchem-1613 177 9 an an DET eurjchem-1613 177 10 endothermic endothermic ADJ eurjchem-1613 177 11 reaction reaction NOUN eurjchem-1613 177 12 . . PUNCT eurjchem-1613 178 1 the the DET eurjchem-1613 178 2 energy energy NOUN eurjchem-1613 178 3 difference difference NOUN eurjchem-1613 178 4 between between ADP eurjchem-1613 178 5 the the DET eurjchem-1613 178 6 reactants reactant NOUN eurjchem-1613 178 7 and and CCONJ eurjchem-1613 178 8 complex complex ADJ eurjchem-1613 178 9 transition transition NOUN eurjchem-1613 178 10 state state NOUN eurjchem-1613 178 11 is be AUX eurjchem-1613 178 12 called call VERB eurjchem-1613 178 13 activation activation NOUN eurjchem-1613 178 14 energy energy NOUN eurjchem-1613 178 15 . . PUNCT eurjchem-1613 179 1 higher high ADJ eurjchem-1613 179 2 activation activation NOUN eurjchem-1613 179 3 energy energy NOUN eurjchem-1613 179 4 translates translate VERB eurjchem-1613 179 5 lower low ADJ eurjchem-1613 179 6 rate rate NOUN eurjchem-1613 179 7 of of ADP eurjchem-1613 179 8 as as ADP eurjchem-1613 179 9 reaction reaction NOUN eurjchem-1613 179 10 and and CCONJ eurjchem-1613 179 11 more more ADJ eurjchem-1613 179 12 dissimilarities dissimilarity NOUN eurjchem-1613 179 13 between between ADP eurjchem-1613 179 14 the the DET eurjchem-1613 179 15 reactants reactant NOUN eurjchem-1613 179 16 and and CCONJ eurjchem-1613 179 17 the the DET eurjchem-1613 179 18 transition transition NOUN eurjchem-1613 179 19 states state NOUN eurjchem-1613 179 20 . . PUNCT eurjchem-1613 180 1 more more ADJ eurjchem-1613 180 2 discrepancy discrepancy NOUN eurjchem-1613 180 3 between between ADP eurjchem-1613 180 4 bonds bond NOUN eurjchem-1613 180 5 in in ADP eurjchem-1613 180 6 the the DET eurjchem-1613 180 7 two two NUM eurjchem-1613 180 8 states state NOUN eurjchem-1613 180 9 leads lead VERB eurjchem-1613 180 10 to to ADP eurjchem-1613 180 11 higher high ADJ eurjchem-1613 180 12 activation activation NOUN eurjchem-1613 180 13 energy energy NOUN eurjchem-1613 180 14 . . PUNCT eurjchem-1613 181 1 table table NOUN eurjchem-1613 181 2 5 5 NUM eurjchem-1613 181 3 shows show VERB eurjchem-1613 181 4 the the DET eurjchem-1613 181 5 rate rate NOUN eurjchem-1613 181 6 constant constant ADJ eurjchem-1613 181 7 and and CCONJ eurjchem-1613 181 8 activation activation NOUN eurjchem-1613 181 9 energy energy NOUN eurjchem-1613 181 10 values value NOUN eurjchem-1613 181 11 for for ADP eurjchem-1613 181 12 the the DET eurjchem-1613 181 13 aforementioned aforementioned ADJ eurjchem-1613 181 14 complexes complex NOUN eurjchem-1613 181 15 in in ADP eurjchem-1613 181 16 water‐dioxane water‐dioxane PROPN eurjchem-1613 181 17 mixture mixture NOUN eurjchem-1613 181 18 . . PUNCT eurjchem-1613 182 1 the the DET eurjchem-1613 182 2 following follow VERB eurjchem-1613 182 3 trend trend NOUN eurjchem-1613 182 4 was be AUX eurjchem-1613 182 5 acquired acquire VERB eurjchem-1613 182 6 . . PUNCT eurjchem-1613 183 1 ea ea X eurjchem-1613 184 1 zn(ii)‐trp zn(ii)‐trp NOUN eurjchem-1613 184 2 < < X eurjchem-1613 184 3 ea ea X eurjchem-1613 185 1 fe(iii)‐trp fe(iii)‐trp PROPN eurjchem-1613 185 2 < < X eurjchem-1613 185 3 ea ea X eurjchem-1613 186 1 ni(ii)‐trp ni(ii)‐trp VERB eurjchem-1613 186 2 < < X eurjchem-1613 186 3 ea ea X eurjchem-1613 187 1 co(ii)‐trp co(ii)‐trp NOUN eurjchem-1613 187 2 < < X eurjchem-1613 187 3 … … PUNCT eurjchem-1613 187 4 … … PUNCT eurjchem-1613 187 5 ea ea X eurjchem-1613 188 1 cu(ii)‐trp cu(ii)‐trp NOUN eurjchem-1613 188 2 < < X eurjchem-1613 189 1 ea ea X eurjchem-1613 190 1 pb(ii)‐trp pb(ii)‐trp INTJ eurjchem-1613 190 2 ( ( PUNCT eurjchem-1613 190 3 34 34 NUM eurjchem-1613 190 4 ) ) PUNCT eurjchem-1613 190 5 figure figure NOUN eurjchem-1613 190 6 6 6 NUM eurjchem-1613 190 7 . . PUNCT eurjchem-1613 190 8 potential potential ADJ eurjchem-1613 190 9 energy energy NOUN eurjchem-1613 190 10 diagram diagram NOUN eurjchem-1613 190 11 for for ADP eurjchem-1613 190 12 an an DET eurjchem-1613 190 13 endothermic endothermic ADJ eurjchem-1613 190 14 reaction reaction NOUN eurjchem-1613 190 15 . . PUNCT eurjchem-1613 191 1 4 4 X eurjchem-1613 191 2 . . X eurjchem-1613 191 3 conclusions conclusion NOUN eurjchem-1613 191 4 in in ADP eurjchem-1613 191 5 this this DET eurjchem-1613 191 6 study study NOUN eurjchem-1613 191 7 , , PUNCT eurjchem-1613 191 8 a a DET eurjchem-1613 191 9 systematic systematic ADJ eurjchem-1613 191 10 approach approach NOUN eurjchem-1613 191 11 was be AUX eurjchem-1613 191 12 made make VERB eurjchem-1613 191 13 to to PART eurjchem-1613 191 14 examine examine VERB eurjchem-1613 191 15 the the DET eurjchem-1613 191 16 interaction interaction NOUN eurjchem-1613 191 17 of of ADP eurjchem-1613 191 18 some some DET eurjchem-1613 191 19 transition transition NOUN eurjchem-1613 191 20 metals metal NOUN eurjchem-1613 191 21 ions ion NOUN eurjchem-1613 191 22 with with ADP eurjchem-1613 191 23 tryptophan tryptophan NOUN eurjchem-1613 191 24 in in ADP eurjchem-1613 191 25 water water NOUN eurjchem-1613 191 26 and and CCONJ eurjchem-1613 191 27 water water NOUN eurjchem-1613 191 28 : : PUNCT eurjchem-1613 191 29 dioxane dioxane NOUN eurjchem-1613 191 30 mixture mixture NOUN eurjchem-1613 191 31 ( ( PUNCT eurjchem-1613 191 32 50:50 50:50 NUM eurjchem-1613 191 33 , , PUNCT eurjchem-1613 191 34 v v NOUN eurjchem-1613 191 35 : : PUNCT eurjchem-1613 191 36 v v NOUN eurjchem-1613 191 37 ) ) PUNCT eurjchem-1613 191 38 at at ADP eurjchem-1613 191 39 various various ADJ eurjchem-1613 191 40 temperatures temperature NOUN eurjchem-1613 191 41 . . PUNCT eurjchem-1613 192 1 as as SCONJ eurjchem-1613 192 2 was be AUX eurjchem-1613 192 3 expected expect VERB eurjchem-1613 192 4 , , PUNCT eurjchem-1613 192 5 cobalt cobalt NOUN eurjchem-1613 192 6 and and CCONJ eurjchem-1613 192 7 zinc zinc NOUN eurjchem-1613 192 8 complexes complex NOUN eurjchem-1613 192 9 had have VERB eurjchem-1613 192 10 the the DET eurjchem-1613 192 11 lowest low ADJ eurjchem-1613 192 12 stability stability NOUN eurjchem-1613 192 13 and and CCONJ eurjchem-1613 192 14 copper copper NOUN eurjchem-1613 192 15 and and CCONJ eurjchem-1613 192 16 iron iron VERB eurjchem-1613 192 17 the the DET eurjchem-1613 192 18 highest high ADJ eurjchem-1613 192 19 . . PUNCT eurjchem-1613 193 1 our our PRON eurjchem-1613 193 2 results result NOUN eurjchem-1613 193 3 show show VERB eurjchem-1613 193 4 that that SCONJ eurjchem-1613 193 5 as as SCONJ eurjchem-1613 193 6 the the DET eurjchem-1613 193 7 temperature temperature NOUN eurjchem-1613 193 8 rises rise VERB eurjchem-1613 193 9 , , PUNCT eurjchem-1613 193 10 or or CCONJ eurjchem-1613 193 11 on on ADP eurjchem-1613 193 12 addition addition NOUN eurjchem-1613 193 13 of of ADP eurjchem-1613 193 14 dioxane dioxane NOUN eurjchem-1613 193 15 to to ADP eurjchem-1613 193 16 water water NOUN eurjchem-1613 193 17 , , PUNCT eurjchem-1613 193 18 the the DET eurjchem-1613 193 19 stability stability NOUN eurjchem-1613 193 20 constant constant ADJ eurjchem-1613 193 21 increases increase NOUN eurjchem-1613 193 22 , , PUNCT eurjchem-1613 193 23 the the DET eurjchem-1613 193 24 gibbs gibbs PROPN eurjchem-1613 193 25 free free ADJ eurjchem-1613 193 26 energy energy NOUN eurjchem-1613 193 27 change change NOUN eurjchem-1613 193 28 is be AUX eurjchem-1613 193 29 negative negative ADJ eurjchem-1613 193 30 correlating correlate VERB eurjchem-1613 193 31 to to ADP eurjchem-1613 193 32 the the DET eurjchem-1613 193 33 spontaneity spontaneity NOUN eurjchem-1613 193 34 of of ADP eurjchem-1613 193 35 the the DET eurjchem-1613 193 36 complex complex ADJ eurjchem-1613 193 37 formation formation NOUN eurjchem-1613 193 38 . . PUNCT eurjchem-1613 194 1 δh δh NOUN eurjchem-1613 194 2 ° ° NUM eurjchem-1613 194 3 and and CCONJ eurjchem-1613 194 4 δs δs NOUN eurjchem-1613 194 5 ° ° ADJ eurjchem-1613 194 6 values value NOUN eurjchem-1613 194 7 were be AUX eurjchem-1613 194 8 positive positive ADJ eurjchem-1613 194 9 the the DET eurjchem-1613 194 10 variations variation NOUN eurjchem-1613 194 11 in in ADP eurjchem-1613 194 12 logarithm logarithm NOUN eurjchem-1613 194 13 of of ADP eurjchem-1613 194 14 stability stability NOUN eurjchem-1613 194 15 constants constant NOUN eurjchem-1613 194 16 versus versus ADP eurjchem-1613 194 17 1 1 NUM eurjchem-1613 194 18 / / SYM eurjchem-1613 194 19 t t PROPN eurjchem-1613 194 20 is be AUX eurjchem-1613 194 21 linear linear PROPN eurjchem-1613 194 22 evidencing evidence VERB eurjchem-1613 194 23 that that SCONJ eurjchem-1613 194 24 δh δh NOUN eurjchem-1613 194 25 ° ° NOUN eurjchem-1613 194 26 s s PART eurjchem-1613 194 27 are be AUX eurjchem-1613 194 28 independent independent ADJ eurjchem-1613 194 29 of of ADP eurjchem-1613 194 30 temperature temperature NOUN eurjchem-1613 194 31 in in ADP eurjchem-1613 194 32 temperature temperature NOUN eurjchem-1613 194 33 range range NOUN eurjchem-1613 194 34 of of ADP eurjchem-1613 194 35 the the DET eurjchem-1613 194 36 study study NOUN eurjchem-1613 194 37 , , PUNCT eurjchem-1613 194 38 and and CCONJ eurjchem-1613 194 39 increase increase VERB eurjchem-1613 194 40 in in ADP eurjchem-1613 194 41 entropy entropy NOUN eurjchem-1613 194 42 enforces enforce VERB eurjchem-1613 194 43 the the DET eurjchem-1613 194 44 formation formation NOUN eurjchem-1613 194 45 of of ADP eurjchem-1613 194 46 these these DET eurjchem-1613 194 47 complexes complex NOUN eurjchem-1613 194 48 . . PUNCT eurjchem-1613 195 1 regarding regard VERB eurjchem-1613 195 2 kinetic kinetic ADJ eurjchem-1613 195 3 studies study NOUN eurjchem-1613 195 4 , , PUNCT eurjchem-1613 195 5 the the DET eurjchem-1613 195 6 obtained obtain VERB eurjchem-1613 195 7 rate rate NOUN eurjchem-1613 195 8 constants constant NOUN eurjchem-1613 195 9 were be AUX eurjchem-1613 195 10 low low ADJ eurjchem-1613 195 11 , , PUNCT eurjchem-1613 195 12 and and CCONJ eurjchem-1613 195 13 evaluated evaluated ADJ eurjchem-1613 195 14 activation activation NOUN eurjchem-1613 195 15 energy energy NOUN eurjchem-1613 195 16 for for ADP eurjchem-1613 195 17 formation formation NOUN eurjchem-1613 195 18 of of ADP eurjchem-1613 195 19 each each DET eurjchem-1613 195 20 complex complex NOUN eurjchem-1613 195 21 were be AUX eurjchem-1613 195 22 reasonable reasonable ADJ eurjchem-1613 195 23 . . PUNCT eurjchem-1613 196 1 acknowledgement acknowledgement NOUN eurjchem-1613 196 2 we we PRON eurjchem-1613 196 3 are be AUX eurjchem-1613 196 4 grateful grateful ADJ eurjchem-1613 196 5 to to PART eurjchem-1613 196 6 research research VERB eurjchem-1613 196 7 council council PROPN eurjchem-1613 196 8 of of ADP eurjchem-1613 196 9 the the DET eurjchem-1613 196 10 university university NOUN eurjchem-1613 196 11 of of ADP eurjchem-1613 196 12 birjand birjand NOUN eurjchem-1613 196 13 for for ADP eurjchem-1613 196 14 financially financially ADV eurjchem-1613 196 15 supporting support VERB eurjchem-1613 196 16 this this DET eurjchem-1613 196 17 project project NOUN eurjchem-1613 196 18 . . PUNCT eurjchem-1613 197 1 references reference NOUN eurjchem-1613 197 2 [ [ X eurjchem-1613 197 3 1 1 NUM eurjchem-1613 197 4 ] ] PUNCT eurjchem-1613 197 5 . . PUNCT eurjchem-1613 198 1 ruan ruan PROPN eurjchem-1613 198 2 , , PUNCT eurjchem-1613 198 3 c. c. PROPN eurjchem-1613 198 4 ; ; PUNCT eurjchem-1613 198 5 rodgers rodger NOUN eurjchem-1613 198 6 , , PUNCT eurjchem-1613 198 7 m. m. NOUN eurjchem-1613 198 8 t. t. PROPN eurjchem-1613 198 9 j. j. PROPN eurjchem-1613 198 10 am am PROPN eurjchem-1613 198 11 . . PUNCT eurjchem-1613 199 1 chem chem NOUN eurjchem-1613 199 2 . . PUNCT eurjchem-1613 200 1 soc soc PROPN eurjchem-1613 200 2 . . PUNCT eurjchem-1613 201 1 2004 2004 NUM eurjchem-1613 201 2 , , PUNCT eurjchem-1613 201 3 126 126 NUM eurjchem-1613 201 4 , , PUNCT eurjchem-1613 201 5 14600‐14610 14600‐14610 NUM eurjchem-1613 201 6 . . PUNCT eurjchem-1613 202 1 [ [ X eurjchem-1613 202 2 2 2 NUM eurjchem-1613 202 3 ] ] PUNCT eurjchem-1613 202 4 . . PUNCT eurjchem-1613 202 5 bjerrum bjerrum NOUN eurjchem-1613 202 6 , , PUNCT eurjchem-1613 202 7 j. j. PROPN eurjchem-1613 202 8 metal‐ammine metal‐ammine PROPN eurjchem-1613 202 9 formation formation NOUN eurjchem-1613 202 10 in in ADP eurjchem-1613 202 11 aqueous aqueous ADJ eurjchem-1613 202 12 solution solution NOUN eurjchem-1613 202 13 , , PUNCT eurjchem-1613 202 14 j. j. PROPN eurjchem-1613 202 15 p. p. PROPN eurjchem-1613 202 16 haase haase PROPN eurjchem-1613 202 17 and and CCONJ eurjchem-1613 202 18 son son NOUN eurjchem-1613 202 19 , , PUNCT eurjchem-1613 202 20 copenhagen copenhagen PROPN eurjchem-1613 202 21 , , PUNCT eurjchem-1613 202 22 1941 1941 NUM eurjchem-1613 202 23 . . PUNCT eurjchem-1613 203 1 [ [ X eurjchem-1613 203 2 3 3 NUM eurjchem-1613 203 3 ] ] PUNCT eurjchem-1613 203 4 . . PUNCT eurjchem-1613 203 5 calvin calvin PROPN eurjchem-1613 203 6 , , PUNCT eurjchem-1613 203 7 m. m. NOUN eurjchem-1613 203 8 ; ; PUNCT eurjchem-1613 203 9 wilson wilson PROPN eurjchem-1613 203 10 , , PUNCT eurjchem-1613 203 11 k. k. PROPN eurjchem-1613 203 12 w. w. PROPN eurjchem-1613 203 13 j. j. PROPN eurjchem-1613 203 14 am am PROPN eurjchem-1613 203 15 . . PUNCT eurjchem-1613 204 1 chem chem PROPN eurjchem-1613 204 2 . . PUNCT eurjchem-1613 205 1 soc soc PROPN eurjchem-1613 205 2 . . PUNCT eurjchem-1613 206 1 1945 1945 NUM eurjchem-1613 206 2 , , PUNCT eurjchem-1613 206 3 67 67 NUM eurjchem-1613 206 4 , , PUNCT eurjchem-1613 206 5 2003‐2007 2003‐2007 NUM eurjchem-1613 206 6 . . PUNCT eurjchem-1613 207 1 [ [ X eurjchem-1613 207 2 4 4 NUM eurjchem-1613 207 3 ] ] PUNCT eurjchem-1613 207 4 . . PUNCT eurjchem-1613 208 1 irving irving PROPN eurjchem-1613 208 2 , , PUNCT eurjchem-1613 208 3 h. h. PROPN eurjchem-1613 208 4 m. m. NOUN eurjchem-1613 208 5 ; ; PUNCT eurjchem-1613 208 6 rossotti rossotti ADJ eurjchem-1613 208 7 , , PUNCT eurjchem-1613 208 8 h. h. PROPN eurjchem-1613 208 9 s. s. PROPN eurjchem-1613 208 10 j. j. PROPN eurjchem-1613 208 11 chem chem PROPN eurjchem-1613 208 12 . . PUNCT eurjchem-1613 209 1 soc soc PROPN eurjchem-1613 209 2 . . PUNCT eurjchem-1613 210 1 1954 1954 NUM eurjchem-1613 210 2 , , PUNCT eurjchem-1613 210 3 2904‐2910 2904‐2910 NUM eurjchem-1613 210 4 . . PUNCT eurjchem-1613 211 1 [ [ X eurjchem-1613 211 2 5 5 NUM eurjchem-1613 211 3 ] ] PUNCT eurjchem-1613 211 4 . . PUNCT eurjchem-1613 212 1 perkins perkins PROPN eurjchem-1613 212 2 , , PUNCT eurjchem-1613 212 3 d. d. PROPN eurjchem-1613 212 4 j. j. PROPN eurjchem-1613 212 5 biochem biochem PROPN eurjchem-1613 212 6 . . PUNCT eurjchem-1613 213 1 j. j. PROPN eurjchem-1613 213 2 1953 1953 NUM eurjchem-1613 213 3 , , PUNCT eurjchem-1613 213 4 55 55 NUM eurjchem-1613 213 5 , , PUNCT eurjchem-1613 213 6 649‐652 649‐652 NUM eurjchem-1613 213 7 . . PUNCT eurjchem-1613 214 1 [ [ X eurjchem-1613 214 2 6 6 NUM eurjchem-1613 214 3 ] ] PUNCT eurjchem-1613 214 4 . . PUNCT eurjchem-1613 215 1 rosenberg rosenberg PROPN eurjchem-1613 215 2 , , PUNCT eurjchem-1613 215 3 b. b. PROPN eurjchem-1613 215 4 ; ; PUNCT eurjchem-1613 215 5 sigel sigel PROPN eurjchem-1613 215 6 , , PUNCT eurjchem-1613 215 7 h. h. PROPN eurjchem-1613 215 8 ; ; PUNCT eurjchem-1613 215 9 marcel marcel PROPN eurjchem-1613 215 10 , , PUNCT eurjchem-1613 215 11 d. d. PROPN eurjchem-1613 215 12 ; ; PUNCT eurjchem-1613 215 13 marzilli marzilli PROPN eurjchem-1613 215 14 , , PUNCT eurjchem-1613 215 15 l. l. PROPN eurjchem-1613 215 16 g. g. PROPN eurjchem-1613 215 17 ( ( PUNCT eurjchem-1613 215 18 ed ed NOUN eurjchem-1613 215 19 . . PUNCT eurjchem-1613 215 20 ) ) PUNCT eurjchem-1613 216 1 metal metal NOUN eurjchem-1613 216 2 ions ion NOUN eurjchem-1613 216 3 in in ADP eurjchem-1613 216 4 biological biological ADJ eurjchem-1613 216 5 systems system NOUN eurjchem-1613 216 6 . . PUNCT eurjchem-1613 217 1 wiley‐interscience wiley‐interscience ADV eurjchem-1613 217 2 , , PUNCT eurjchem-1613 217 3 new new PROPN eurjchem-1613 217 4 york york PROPN eurjchem-1613 217 5 , , PUNCT eurjchem-1613 217 6 1980 1980 NUM eurjchem-1613 217 7 . . PUNCT eurjchem-1613 218 1 [ [ X eurjchem-1613 218 2 7 7 NUM eurjchem-1613 218 3 ] ] PUNCT eurjchem-1613 218 4 . . PUNCT eurjchem-1613 218 5 beck beck PROPN eurjchem-1613 218 6 , , PUNCT eurjchem-1613 218 7 m. m. NOUN eurjchem-1613 218 8 t. t. PROPN eurjchem-1613 218 9 ; ; PUNCT eurjchem-1613 218 10 nagypal nagypal PROPN eurjchem-1613 218 11 , , PUNCT eurjchem-1613 218 12 i. i. NOUN eurjchem-1613 218 13 , , PUNCT eurjchem-1613 218 14 chemistry chemistry NOUN eurjchem-1613 218 15 of of ADP eurjchem-1613 218 16 complex complex ADJ eurjchem-1613 218 17 equilibria equilibrium NOUN eurjchem-1613 218 18 . . PUNCT eurjchem-1613 219 1 chapter chapter NOUN eurjchem-1613 219 2 1 1 NUM eurjchem-1613 219 3 , , PUNCT eurjchem-1613 219 4 ellis ellis PROPN eurjchem-1613 219 5 horwood horwood PROPN eurjchem-1613 219 6 , , PUNCT eurjchem-1613 219 7 new new PROPN eurjchem-1613 219 8 york york PROPN eurjchem-1613 219 9 , , PUNCT eurjchem-1613 219 10 1990 1990 NUM eurjchem-1613 219 11 . . PUNCT eurjchem-1613 220 1 [ [ X eurjchem-1613 220 2 8 8 NUM eurjchem-1613 220 3 ] ] PUNCT eurjchem-1613 220 4 . . PUNCT eurjchem-1613 221 1 smith smith PROPN eurjchem-1613 221 2 , , PUNCT eurjchem-1613 221 3 r. r. PROPN eurjchem-1613 221 4 m. m. PROPN eurjchem-1613 221 5 ; ; PUNCT eurjchem-1613 221 6 motekaitis motekaitis PROPN eurjchem-1613 221 7 , , PUNCT eurjchem-1613 221 8 r. r. PROPN eurjchem-1613 221 9 j. j. PROPN eurjchem-1613 221 10 ; ; PUNCT eurjchem-1613 221 11 martell martell PROPN eurjchem-1613 221 12 , , PUNCT eurjchem-1613 221 13 a. a. PROPN eurjchem-1613 221 14 e. e. PROPN eurjchem-1613 221 15 inorg inorg PROPN eurjchem-1613 221 16 . . PUNCT eurjchem-1613 222 1 chim chim PROPN eurjchem-1613 222 2 . . PUNCT eurjchem-1613 223 1 acta acta PROPN eurjchem-1613 223 2 1985 1985 NUM eurjchem-1613 223 3 , , PUNCT eurjchem-1613 223 4 103 103 NUM eurjchem-1613 223 5 , , PUNCT eurjchem-1613 223 6 73‐82 73‐82 NOUN eurjchem-1613 223 7 . . PUNCT eurjchem-1613 224 1 [ [ X eurjchem-1613 224 2 9 9 NUM eurjchem-1613 224 3 ] ] PUNCT eurjchem-1613 224 4 . . PUNCT eurjchem-1613 225 1 sovago sovago PROPN eurjchem-1613 225 2 , , PUNCT eurjchem-1613 225 3 i. i. NOUN eurjchem-1613 225 4 ; ; PUNCT eurjchem-1613 225 5 kiss kiss PROPN eurjchem-1613 225 6 , , PUNCT eurjchem-1613 225 7 t. t. PROPN eurjchem-1613 225 8 ; ; PUNCT eurjchem-1613 225 9 gergely gergely ADV eurjchem-1613 225 10 , , PUNCT eurjchem-1613 225 11 a. a. NOUN eurjchem-1613 225 12 pure pure PROPN eurjchem-1613 225 13 appl appl PROPN eurjchem-1613 225 14 . . PUNCT eurjchem-1613 226 1 chem chem PROPN eurjchem-1613 226 2 . . PUNCT eurjchem-1613 227 1 1993 1993 NUM eurjchem-1613 227 2 , , PUNCT eurjchem-1613 227 3 65 65 NUM eurjchem-1613 227 4 , , PUNCT eurjchem-1613 227 5 1029‐1080 1029‐1080 NUM eurjchem-1613 227 6 . . PUNCT eurjchem-1613 228 1 [ [ X eurjchem-1613 228 2 10 10 NUM eurjchem-1613 228 3 ] ] PUNCT eurjchem-1613 228 4 . . PUNCT eurjchem-1613 228 5 shoukry shoukry PROPN eurjchem-1613 228 6 , , PUNCT eurjchem-1613 228 7 m. m. NOUN eurjchem-1613 228 8 m. m. NOUN eurjchem-1613 228 9 ; ; PUNCT eurjchem-1613 228 10 shehata shehata NOUN eurjchem-1613 228 11 , , PUNCT eurjchem-1613 228 12 m. m. NOUN eurjchem-1613 228 13 r. r. PROPN eurjchem-1613 228 14 ; ; PUNCT eurjchem-1613 228 15 mohamed mohamed PROPN eurjchem-1613 228 16 , , PUNCT eurjchem-1613 228 17 m. m. NOUN eurjchem-1613 228 18 m. m. PROPN eurjchem-1613 228 19 a. a. PROPN eurjchem-1613 228 20 mikrochim mikrochim PROPN eurjchem-1613 228 21 . . PUNCT eurjchem-1613 229 1 acta acta PROPN eurjchem-1613 229 2 1998 1998 NUM eurjchem-1613 229 3 , , PUNCT eurjchem-1613 229 4 129 129 NUM eurjchem-1613 229 5 , , PUNCT eurjchem-1613 229 6 107‐113 107‐113 NUM eurjchem-1613 229 7 . . PUNCT eurjchem-1613 230 1 [ [ X eurjchem-1613 230 2 11 11 NUM eurjchem-1613 230 3 ] ] PUNCT eurjchem-1613 230 4 . . PUNCT eurjchem-1613 231 1 martell martell PROPN eurjchem-1613 231 2 , , PUNCT eurjchem-1613 231 3 a. a. PROPN eurjchem-1613 231 4 e. e. PROPN eurjchem-1613 231 5 ; ; PUNCT eurjchem-1613 231 6 huncock huncock PROPN eurjchem-1613 231 7 , , PUNCT eurjchem-1613 231 8 r. r. PROPN eurjchem-1613 231 9 d. d. PROPN eurjchem-1613 231 10 metal metal PROPN eurjchem-1613 231 11 complexes complex NOUN eurjchem-1613 231 12 in in ADP eurjchem-1613 231 13 aqueous aqueous ADJ eurjchem-1613 231 14 solutions solution NOUN eurjchem-1613 231 15 . . PUNCT eurjchem-1613 232 1 plenum plenum PROPN eurjchem-1613 232 2 press press PROPN eurjchem-1613 232 3 , , PUNCT eurjchem-1613 232 4 1996 1996 NUM eurjchem-1613 232 5 . . PUNCT eurjchem-1613 233 1 [ [ X eurjchem-1613 233 2 12 12 NUM eurjchem-1613 233 3 ] ] PUNCT eurjchem-1613 233 4 . . PUNCT eurjchem-1613 234 1 martell martell PROPN eurjchem-1613 234 2 , , PUNCT eurjchem-1613 234 3 a. a. PROPN eurjchem-1613 234 4 e. e. PROPN eurjchem-1613 234 5 ; ; PUNCT eurjchem-1613 234 6 motekaitis motekaitis PROPN eurjchem-1613 234 7 , , PUNCT eurjchem-1613 234 8 r. r. PROPN eurjchem-1613 234 9 j. j. PROPN eurjchem-1613 234 10 the the DET eurjchem-1613 234 11 determination determination NOUN eurjchem-1613 234 12 and and CCONJ eurjchem-1613 234 13 use use NOUN eurjchem-1613 234 14 of of ADP eurjchem-1613 234 15 stability stability NOUN eurjchem-1613 234 16 constants constant NOUN eurjchem-1613 234 17 . . PUNCT eurjchem-1613 235 1 wiley‐vch wiley‐vch PROPN eurjchem-1613 235 2 , , PUNCT eurjchem-1613 235 3 1992 1992 NUM eurjchem-1613 235 4 . . PUNCT eurjchem-1613 236 1 [ [ X eurjchem-1613 236 2 13 13 NUM eurjchem-1613 236 3 ] ] SYM eurjchem-1613 236 4 . . PUNCT eurjchem-1613 237 1 silva silva PROPN eurjchem-1613 237 2 , , PUNCT eurjchem-1613 237 3 a. a. NOUN eurjchem-1613 237 4 m. m. NOUN eurjchem-1613 237 5 ; ; PUNCT eurjchem-1613 237 6 merce merce PROPN eurjchem-1613 237 7 , , PUNCT eurjchem-1613 237 8 a. a. PROPN eurjchem-1613 237 9 l. l. PROPN eurjchem-1613 237 10 r. r. PROPN eurjchem-1613 237 11 ; ; PUNCT eurjchem-1613 237 12 mangrich mangrich PROPN eurjchem-1613 237 13 , , PUNCT eurjchem-1613 237 14 a. a. PROPN eurjchem-1613 237 15 s. s. PROPN eurjchem-1613 237 16 ; ; PUNCT eurjchem-1613 237 17 souto souto PROPN eurjchem-1613 237 18 , , PUNCT eurjchem-1613 237 19 c. c. PROPN eurjchem-1613 237 20 a. a. PROPN eurjchem-1613 237 21 t. t. PROPN eurjchem-1613 237 22 ; ; PUNCT eurjchem-1613 237 23 felcman felcman NOUN eurjchem-1613 237 24 , , PUNCT eurjchem-1613 237 25 j. j. PROPN eurjchem-1613 237 26 polyhedron polyhedron PROPN eurjchem-1613 237 27 2006 2006 NUM eurjchem-1613 237 28 , , PUNCT eurjchem-1613 237 29 25 25 NUM eurjchem-1613 237 30 , , PUNCT eurjchem-1613 237 31 1319‐1326 1319‐1326 NUM eurjchem-1613 237 32 . . PUNCT eurjchem-1613 238 1 [ [ X eurjchem-1613 238 2 14 14 NUM eurjchem-1613 238 3 ] ] PUNCT eurjchem-1613 238 4 . . PUNCT eurjchem-1613 239 1 pettit pettit PROPN eurjchem-1613 239 2 , , PUNCT eurjchem-1613 239 3 l. l. PROPN eurjchem-1613 239 4 d. d. PROPN eurjchem-1613 239 5 pure pure PROPN eurjchem-1613 239 6 appl appl PROPN eurjchem-1613 239 7 . . PUNCT eurjchem-1613 239 8 chem chem PROPN eurjchem-1613 239 9 . . PUNCT eurjchem-1613 239 10 1984 1984 NUM eurjchem-1613 239 11 , , PUNCT eurjchem-1613 239 12 56 56 NUM eurjchem-1613 239 13 , , PUNCT eurjchem-1613 239 14 247‐292 247‐292 NUM eurjchem-1613 239 15 . . PUNCT eurjchem-1613 240 1 [ [ X eurjchem-1613 240 2 15 15 NUM eurjchem-1613 240 3 ] ] SYM eurjchem-1613 240 4 . . PUNCT eurjchem-1613 240 5 taha taha PROPN eurjchem-1613 240 6 , , PUNCT eurjchem-1613 240 7 m. m. NOUN eurjchem-1613 240 8 ; ; PUNCT eurjchem-1613 240 9 khalil khalil PROPN eurjchem-1613 240 10 , , PUNCT eurjchem-1613 240 11 m. m. NOUN eurjchem-1613 240 12 m. m. NOUN eurjchem-1613 240 13 chem chem PROPN eurjchem-1613 240 14 . . PUNCT eurjchem-1613 241 1 eng eng PROPN eurjchem-1613 241 2 . . PROPN eurjchem-1613 241 3 data data PROPN eurjchem-1613 241 4 2005 2005 NUM eurjchem-1613 241 5 , , PUNCT eurjchem-1613 241 6 50 50 NUM eurjchem-1613 241 7 , , PUNCT eurjchem-1613 241 8 157‐163 157‐163 NUM eurjchem-1613 241 9 . . PUNCT eurjchem-1613 242 1 [ [ X eurjchem-1613 242 2 16 16 NUM eurjchem-1613 242 3 ] ] PUNCT eurjchem-1613 242 4 . . PUNCT eurjchem-1613 243 1 demirelli demirelli PROPN eurjchem-1613 243 2 , , PUNCT eurjchem-1613 243 3 h. h. PROPN eurjchem-1613 243 4 ; ; PUNCT eurjchem-1613 243 5 koseoglu koseoglu PROPN eurjchem-1613 243 6 , , PUNCT eurjchem-1613 243 7 f. f. PROPN eurjchem-1613 243 8 j. j. PROPN eurjchem-1613 243 9 solution solution PROPN eurjchem-1613 243 10 chem chem PROPN eurjchem-1613 243 11 . . PUNCT eurjchem-1613 244 1 2005 2005 NUM eurjchem-1613 244 2 , , PUNCT eurjchem-1613 244 3 34 34 NUM eurjchem-1613 244 4 , , PUNCT eurjchem-1613 244 5 561‐577 561‐577 NUM eurjchem-1613 244 6 . . PUNCT eurjchem-1613 245 1 [ [ X eurjchem-1613 245 2 17 17 NUM eurjchem-1613 245 3 ] ] PUNCT eurjchem-1613 245 4 . . PUNCT eurjchem-1613 246 1 podsiadly podsiadly ADV eurjchem-1613 246 2 , , PUNCT eurjchem-1613 246 3 h. h. PROPN eurjchem-1613 246 4 ; ; PUNCT eurjchem-1613 246 5 karwecka karwecka PROPN eurjchem-1613 246 6 , , PUNCT eurjchem-1613 246 7 z. z. PROPN eurjchem-1613 246 8 polyhedron polyhedron PROPN eurjchem-1613 246 9 2009 2009 NUM eurjchem-1613 246 10 , , PUNCT eurjchem-1613 246 11 28 28 NUM eurjchem-1613 246 12 , , PUNCT eurjchem-1613 246 13 1568‐1572 1568‐1572 NUM eurjchem-1613 246 14 . . PUNCT eurjchem-1613 247 1 [ [ X eurjchem-1613 247 2 18 18 NUM eurjchem-1613 247 3 ] ] PUNCT eurjchem-1613 247 4 . . PUNCT eurjchem-1613 248 1 sajadi sajadi PROPN eurjchem-1613 248 2 , , PUNCT eurjchem-1613 248 3 s. s. PROPN eurjchem-1613 248 4 a. a. PROPN eurjchem-1613 248 5 a. a. PROPN eurjchem-1613 248 6 natural natural PROPN eurjchem-1613 248 7 sci sci PROPN eurjchem-1613 248 8 . . PROPN eurjchem-1613 248 9 2010 2010 NUM eurjchem-1613 248 10 , , PUNCT eurjchem-1613 248 11 2 2 NUM eurjchem-1613 248 12 , , PUNCT eurjchem-1613 248 13 85‐90 85‐90 NUM eurjchem-1613 248 14 . . PUNCT eurjchem-1613 249 1 [ [ X eurjchem-1613 249 2 19 19 NUM eurjchem-1613 249 3 ] ] PUNCT eurjchem-1613 249 4 . . PUNCT eurjchem-1613 250 1 rani rani PROPN eurjchem-1613 250 2 , , PUNCT eurjchem-1613 250 3 r. r. PROPN eurjchem-1613 250 4 s. s. PROPN eurjchem-1613 250 5 ; ; PUNCT eurjchem-1613 250 6 rao rao PROPN eurjchem-1613 250 7 , , PUNCT eurjchem-1613 250 8 g. g. PROPN eurjchem-1613 250 9 n. n. PROPN eurjchem-1613 250 10 bull bull PROPN eurjchem-1613 250 11 . . PUNCT eurjchem-1613 251 1 chem chem PROPN eurjchem-1613 251 2 . . PUNCT eurjchem-1613 252 1 soc soc PROPN eurjchem-1613 252 2 . . PUNCT eurjchem-1613 253 1 ethiop ethiop PROPN eurjchem-1613 253 2 . . PUNCT eurjchem-1613 254 1 2013 2013 NUM eurjchem-1613 254 2 , , PUNCT eurjchem-1613 254 3 27 27 NUM eurjchem-1613 254 4 , , PUNCT eurjchem-1613 254 5 367‐376 367‐376 PROPN eurjchem-1613 254 6 . . PUNCT eurjchem-1613 255 1 [ [ X eurjchem-1613 255 2 20 20 NUM eurjchem-1613 255 3 ] ] PUNCT eurjchem-1613 255 4 . . PUNCT eurjchem-1613 255 5 turkel turkel PROPN eurjchem-1613 255 6 , , PUNCT eurjchem-1613 255 7 n. n. PROPN eurjchem-1613 255 8 bioinorg bioinorg PROPN eurjchem-1613 255 9 . . PROPN eurjchem-1613 255 10 chem chem PROPN eurjchem-1613 255 11 . . PUNCT eurjchem-1613 256 1 appl appl PROPN eurjchem-1613 256 2 . . PROPN eurjchem-1613 257 1 2015 2015 NUM eurjchem-1613 257 2 , , PUNCT eurjchem-1613 257 3 article article NOUN eurjchem-1613 257 4 i i PROPN eurjchem-1613 257 5 d d PROPN eurjchem-1613 257 6 374782 374782 NUM eurjchem-1613 257 7 , , PUNCT eurjchem-1613 257 8 1‐9 1‐9 NUM eurjchem-1613 257 9 . . PUNCT eurjchem-1613 258 1 [ [ X eurjchem-1613 258 2 21 21 NUM eurjchem-1613 258 3 ] ] PUNCT eurjchem-1613 258 4 . . PUNCT eurjchem-1613 259 1 mohamed mohamed PROPN eurjchem-1613 259 2 , , PUNCT eurjchem-1613 259 3 a. a. NOUN eurjchem-1613 259 4 a. a. PROPN eurjchem-1613 259 5 ; ; PUNCT eurjchem-1613 259 6 bakr bakr PROPN eurjchem-1613 259 7 , , PUNCT eurjchem-1613 259 8 m. m. PROPN eurjchem-1613 259 9 f. f. PROPN eurjchem-1613 259 10 ; ; PUNCT eurjchem-1613 259 11 abd abd PROPN eurjchem-1613 259 12 el‐fattah el‐fattah PROPN eurjchem-1613 259 13 , , PUNCT eurjchem-1613 259 14 k. k. PROPN eurjchem-1613 259 15 a. a. PROPN eurjchem-1613 259 16 thermochim thermochim PROPN eurjchem-1613 259 17 . . PUNCT eurjchem-1613 260 1 acta acta PROPN eurjchem-1613 260 2 1990 1990 NUM eurjchem-1613 260 3 , , PUNCT eurjchem-1613 260 4 405 405 NUM eurjchem-1613 260 5 , , PUNCT eurjchem-1613 260 6 235‐253 235‐253 NUM eurjchem-1613 260 7 . . PUNCT eurjchem-1613 261 1 [ [ X eurjchem-1613 261 2 22 22 NUM eurjchem-1613 261 3 ] ] PUNCT eurjchem-1613 261 4 . . PUNCT eurjchem-1613 262 1 masoud masoud PROPN eurjchem-1613 262 2 , , PUNCT eurjchem-1613 262 3 m. m. NOUN eurjchem-1613 262 4 s. s. PROPN eurjchem-1613 262 5 ; ; PUNCT eurjchem-1613 262 6 abdel‐nabby abdel‐nabby PROPN eurjchem-1613 262 7 , , PUNCT eurjchem-1613 262 8 b. b. PROPN eurjchem-1613 262 9 a. a. PROPN eurjchem-1613 262 10 thermochim thermochim PROPN eurjchem-1613 262 11 . . PUNCT eurjchem-1613 263 1 acta acta PROPN eurjchem-1613 263 2 1988 1988 NUM eurjchem-1613 263 3 , , PUNCT eurjchem-1613 263 4 128 128 NUM eurjchem-1613 263 5 , , PUNCT eurjchem-1613 263 6 75‐ 75‐ NUM eurjchem-1613 263 7 80 80 NUM eurjchem-1613 263 8 . . PUNCT eurjchem-1613 264 1 [ [ X eurjchem-1613 264 2 23 23 NUM eurjchem-1613 264 3 ] ] PUNCT eurjchem-1613 264 4 . . PUNCT eurjchem-1613 265 1 casale casale PROPN eurjchem-1613 265 2 , , PUNCT eurjchem-1613 265 3 a. a. NOUN eurjchem-1613 265 4 ; ; PUNCT eurjchem-1613 265 5 de de X eurjchem-1613 265 6 robertis robertis PROPN eurjchem-1613 265 7 , , PUNCT eurjchem-1613 265 8 a. a. NOUN eurjchem-1613 265 9 ; ; PUNCT eurjchem-1613 265 10 de de X eurjchem-1613 265 11 stefano stefano PROPN eurjchem-1613 265 12 , , PUNCT eurjchem-1613 265 13 c. c. PROPN eurjchem-1613 265 14 ; ; PUNCT eurjchem-1613 265 15 gianguzza gianguzza PROPN eurjchem-1613 265 16 , , PUNCT eurjchem-1613 265 17 a. a. NOUN eurjchem-1613 265 18 ; ; PUNCT eurjchem-1613 265 19 patane patane NOUN eurjchem-1613 265 20 , , PUNCT eurjchem-1613 265 21 g. g. PROPN eurjchem-1613 265 22 ; ; PUNCT eurjchem-1613 265 23 riango riango PROPN eurjchem-1613 265 24 , , PUNCT eurjchem-1613 265 25 c. c. PROPN eurjchem-1613 265 26 thermochim thermochim PROPN eurjchem-1613 265 27 . . PUNCT eurjchem-1613 266 1 acta acta PROPN eurjchem-1613 266 2 1995 1995 NUM eurjchem-1613 266 3 , , PUNCT eurjchem-1613 266 4 255 255 NUM eurjchem-1613 266 5 , , PUNCT eurjchem-1613 266 6 109‐141 109‐141 NUM eurjchem-1613 266 7 . . PUNCT eurjchem-1613 267 1 [ [ X eurjchem-1613 267 2 24 24 NUM eurjchem-1613 267 3 ] ] PUNCT eurjchem-1613 267 4 . . PUNCT eurjchem-1613 268 1 fazary fazary ADJ eurjchem-1613 268 2 , , PUNCT eurjchem-1613 268 3 a. a. PROPN eurjchem-1613 268 4 e. e. PROPN eurjchem-1613 268 5 ; ; PUNCT eurjchem-1613 268 6 mohamed mohamed PROPN eurjchem-1613 268 7 , , PUNCT eurjchem-1613 268 8 a. a. PROPN eurjchem-1613 268 9 f. f. PROPN eurjchem-1613 268 10 ; ; PUNCT eurjchem-1613 268 11 lebedeva lebedeva PROPN eurjchem-1613 268 12 , , PUNCT eurjchem-1613 268 13 n. n. PROPN eurjchem-1613 268 14 s. s. PROPN eurjchem-1613 268 15 j. j. PROPN eurjchem-1613 268 16 chem chem PROPN eurjchem-1613 268 17 . . PUNCT eurjchem-1613 269 1 thermodyn thermodyn NOUN eurjchem-1613 269 2 . . PUNCT eurjchem-1613 270 1 2006 2006 NUM eurjchem-1613 270 2 , , PUNCT eurjchem-1613 270 3 38 38 NUM eurjchem-1613 270 4 , , PUNCT eurjchem-1613 270 5 1467‐1473 1467‐1473 NUM eurjchem-1613 270 6 . . PUNCT eurjchem-1613 271 1 [ [ X eurjchem-1613 271 2 25 25 NUM eurjchem-1613 271 3 ] ] PUNCT eurjchem-1613 271 4 . . PUNCT eurjchem-1613 272 1 ghiamati ghiamati PROPN eurjchem-1613 272 2 , , PUNCT eurjchem-1613 272 3 e. e. PROPN eurjchem-1613 272 4 ; ; PUNCT eurjchem-1613 272 5 oliaei oliaei ADJ eurjchem-1613 272 6 , , PUNCT eurjchem-1613 272 7 s. s. PROPN eurjchem-1613 272 8 soj soj PROPN eurjchem-1613 272 9 biochem biochem PROPN eurjchem-1613 272 10 . . PUNCT eurjchem-1613 273 1 2017 2017 NUM eurjchem-1613 273 2 , , PUNCT eurjchem-1613 273 3 3 3 NUM eurjchem-1613 273 4 , , PUNCT eurjchem-1613 273 5 6‐12 6‐12 NUM eurjchem-1613 273 6 . . PUNCT eurjchem-1613 274 1 [ [ X eurjchem-1613 274 2 26 26 NUM eurjchem-1613 274 3 ] ] PUNCT eurjchem-1613 274 4 . . PUNCT eurjchem-1613 275 1 ghiamati ghiamati PROPN eurjchem-1613 275 2 , , PUNCT eurjchem-1613 275 3 e. e. PROPN eurjchem-1613 275 4 ; ; PUNCT eurjchem-1613 275 5 jalaeian jalaeian PROPN eurjchem-1613 275 6 , , PUNCT eurjchem-1613 275 7 e. e. PROPN eurjchem-1613 275 8 asian asian PROPN eurjchem-1613 275 9 j. j. PROPN eurjchem-1613 275 10 phys phys PROPN eurjchem-1613 275 11 . . PUNCT eurjchem-1613 276 1 chem chem PROPN eurjchem-1613 276 2 . . PUNCT eurjchem-1613 277 1 sci sci PROPN eurjchem-1613 277 2 . . PROPN eurjchem-1613 277 3 2017 2017 NUM eurjchem-1613 277 4 , , PUNCT eurjchem-1613 277 5 2 2 NUM eurjchem-1613 277 6 , , PUNCT eurjchem-1613 277 7 1‐10 1‐10 NUM eurjchem-1613 277 8 . . PUNCT eurjchem-1613 278 1 [ [ X eurjchem-1613 278 2 27 27 NUM eurjchem-1613 278 3 ] ] PUNCT eurjchem-1613 278 4 . . PUNCT eurjchem-1613 279 1 ghiamati ghiamati PROPN eurjchem-1613 279 2 , , PUNCT eurjchem-1613 279 3 e. e. PROPN eurjchem-1613 279 4 ; ; PUNCT eurjchem-1613 279 5 baniasadi baniasadi NOUN eurjchem-1613 279 6 , , PUNCT eurjchem-1613 279 7 m. m. NOUN eurjchem-1613 279 8 ; ; PUNCT eurjchem-1613 279 9 farrokhi farrokhi PROPN eurjchem-1613 279 10 , , PUNCT eurjchem-1613 279 11 a. a. NOUN eurjchem-1613 279 12 chem chem NOUN eurjchem-1613 279 13 . . PUNCT eurjchem-1613 280 1 sci sci PROPN eurjchem-1613 280 2 . . PUNCT eurjchem-1613 280 3 int int PROPN eurjchem-1613 280 4 . . PUNCT eurjchem-1613 281 1 j. j. PROPN eurjchem-1613 281 2 2017 2017 NUM eurjchem-1613 281 3 , , PUNCT eurjchem-1613 281 4 19 19 NUM eurjchem-1613 281 5 , , PUNCT eurjchem-1613 281 6 1‐ 1‐ NUM eurjchem-1613 281 7 15 15 NUM eurjchem-1613 281 8 . . PUNCT eurjchem-1613 282 1 [ [ X eurjchem-1613 282 2 28 28 NUM eurjchem-1613 282 3 ] ] PUNCT eurjchem-1613 282 4 . . PUNCT eurjchem-1613 283 1 ghiamati ghiamati PROPN eurjchem-1613 283 2 , , PUNCT eurjchem-1613 283 3 e. e. PROPN eurjchem-1613 283 4 ; ; PUNCT eurjchem-1613 283 5 lashkari lashkari PROPN eurjchem-1613 283 6 , , PUNCT eurjchem-1613 283 7 m. m. NOUN eurjchem-1613 283 8 ; ; PUNCT eurjchem-1613 283 9 hasheminia hasheminia NOUN eurjchem-1613 283 10 , , PUNCT eurjchem-1613 283 11 m. m. NOUN eurjchem-1613 283 12 asian asian PROPN eurjchem-1613 283 13 j. j. PROPN eurjchem-1613 283 14 chem chem PROPN eurjchem-1613 283 15 . . PUNCT eurjchem-1613 284 1 2013 2013 NUM eurjchem-1613 284 2 , , PUNCT eurjchem-1613 284 3 25 25 NUM eurjchem-1613 284 4 , , PUNCT eurjchem-1613 284 5 1361‐1365 1361‐1365 NUM eurjchem-1613 284 6 . . PUNCT eurjchem-1613 285 1 [ [ X eurjchem-1613 285 2 29 29 NUM eurjchem-1613 285 3 ] ] PUNCT eurjchem-1613 285 4 . . PUNCT eurjchem-1613 286 1 chaudhari chaudhari PROPN eurjchem-1613 286 2 , , PUNCT eurjchem-1613 286 3 u. u. PROPN eurjchem-1613 286 4 e. e. PROPN eurjchem-1613 286 5 orient orient PROPN eurjchem-1613 286 6 . . PUNCT eurjchem-1613 287 1 j. j. PROPN eurjchem-1613 287 2 chem chem PROPN eurjchem-1613 287 3 . . PUNCT eurjchem-1613 288 1 2011 2011 NUM eurjchem-1613 288 2 , , PUNCT eurjchem-1613 288 3 27 27 NUM eurjchem-1613 288 4 , , PUNCT eurjchem-1613 288 5 297‐300 297‐300 NUM eurjchem-1613 288 6 . . PUNCT eurjchem-1613 289 1 [ [ X eurjchem-1613 289 2 30 30 NUM eurjchem-1613 289 3 ] ] PUNCT eurjchem-1613 289 4 . . PUNCT eurjchem-1613 290 1 chaudhari chaudhari PROPN eurjchem-1613 290 2 , , PUNCT eurjchem-1613 290 3 u. u. PROPN eurjchem-1613 290 4 e. e. PROPN eurjchem-1613 290 5 int int PROPN eurjchem-1613 290 6 . . PUNCT eurjchem-1613 291 1 j. j. PROPN eurjchem-1613 291 2 chem chem PROPN eurjchem-1613 291 3 . . PUNCT eurjchem-1613 292 1 sci sci PROPN eurjchem-1613 292 2 . . PROPN eurjchem-1613 292 3 2009 2009 NUM eurjchem-1613 292 4 , , PUNCT eurjchem-1613 292 5 7 7 NUM eurjchem-1613 292 6 , , PUNCT eurjchem-1613 292 7 1746‐1750 1746‐1750 NUM eurjchem-1613 292 8 . . PUNCT eurjchem-1613 293 1 [ [ X eurjchem-1613 293 2 31 31 NUM eurjchem-1613 293 3 ] ] PUNCT eurjchem-1613 293 4 . . PUNCT eurjchem-1613 294 1 rathore rathore PROPN eurjchem-1613 294 2 , , PUNCT eurjchem-1613 294 3 m. m. NOUN eurjchem-1613 294 4 m. m. NOUN eurjchem-1613 294 5 ; ; PUNCT eurjchem-1613 294 6 parhate parhate ADJ eurjchem-1613 294 7 , , PUNCT eurjchem-1613 294 8 v. v. PROPN eurjchem-1613 294 9 v. v. ADP eurjchem-1613 294 10 ; ; PUNCT eurjchem-1613 294 11 rajput rajput PROPN eurjchem-1613 294 12 , , PUNCT eurjchem-1613 294 13 p. p. PROPN eurjchem-1613 294 14 r. r. PROPN eurjchem-1613 294 15 res res PROPN eurjchem-1613 294 16 . . PUNCT eurjchem-1613 295 1 j. j. PROPN eurjchem-1613 295 2 chem chem PROPN eurjchem-1613 295 3 . . PUNCT eurjchem-1613 296 1 sci sci PROPN eurjchem-1613 296 2 . . PROPN eurjchem-1613 296 3 2013 2013 NUM eurjchem-1613 296 4 , , PUNCT eurjchem-1613 296 5 3 3 NUM eurjchem-1613 296 6 , , PUNCT eurjchem-1613 296 7 77‐79 77‐79 ADJ eurjchem-1613 296 8 . . PUNCT eurjchem-1613 297 1 [ [ X eurjchem-1613 297 2 32 32 NUM eurjchem-1613 297 3 ] ] PUNCT eurjchem-1613 297 4 . . PUNCT eurjchem-1613 298 1 mohamed mohamed PROPN eurjchem-1613 298 2 , , PUNCT eurjchem-1613 298 3 a. a. NOUN eurjchem-1613 298 4 a. a. PROPN eurjchem-1613 298 5 ; ; PUNCT eurjchem-1613 298 6 el‐dossoki el‐dossoki PROPN eurjchem-1613 298 7 , , PUNCT eurjchem-1613 298 8 f. f. PROPN eurjchem-1613 298 9 i. i. PROPN eurjchem-1613 298 10 ; ; PUNCT eurjchem-1613 298 11 gumaa gumaa VERB eurjchem-1613 298 12 , , PUNCT eurjchem-1613 298 13 h. h. PROPN eurjchem-1613 298 14 a. a. PROPN eurjchem-1613 298 15 j. j. PROPN eurjchem-1613 298 16 chem chem PROPN eurjchem-1613 298 17 . . PUNCT eurjchem-1613 299 1 eng eng PROPN eurjchem-1613 299 2 . . PROPN eurjchem-1613 299 3 data data PROPN eurjchem-1613 299 4 2010 2010 NUM eurjchem-1613 299 5 , , PUNCT eurjchem-1613 299 6 55 55 NUM eurjchem-1613 299 7 , , PUNCT eurjchem-1613 299 8 673‐678 673‐678 NUM eurjchem-1613 299 9 . . PUNCT eurjchem-1613 300 1 338 338 NUM eurjchem-1613 300 2 ghiamati ghiamati NOUN eurjchem-1613 300 3 and and CCONJ eurjchem-1613 300 4 abazari abazari ADJ eurjchem-1613 300 5 / / SYM eurjchem-1613 300 6 european european ADJ eurjchem-1613 300 7 journal journal PROPN eurjchem-1613 300 8 of of ADP eurjchem-1613 300 9 chemistry chemistry NOUN eurjchem-1613 300 10 8 8 NUM eurjchem-1613 300 11 ( ( PUNCT eurjchem-1613 300 12 4 4 NUM eurjchem-1613 300 13 ) ) PUNCT eurjchem-1613 300 14 ( ( PUNCT eurjchem-1613 300 15 2017 2017 NUM eurjchem-1613 300 16 ) ) PUNCT eurjchem-1613 300 17 333‐338 333‐338 PROPN eurjchem-1613 301 1 [ [ X eurjchem-1613 301 2 33 33 NUM eurjchem-1613 301 3 ] ] PUNCT eurjchem-1613 301 4 . . PUNCT eurjchem-1613 302 1 sahadev sahadev PROPN eurjchem-1613 302 2 ; ; PUNCT eurjchem-1613 302 3 sharma sharma PROPN eurjchem-1613 302 4 , , PUNCT eurjchem-1613 302 5 r. r. PROPN eurjchem-1613 302 6 k. k. PROPN eurjchem-1613 302 7 ; ; PUNCT eurjchem-1613 302 8 sindhwani sindhwani PROPN eurjchem-1613 302 9 , , PUNCT eurjchem-1613 302 10 s. s. PROPN eurjchem-1613 302 11 k. k. PROPN eurjchem-1613 302 12 ; ; PUNCT eurjchem-1613 303 1 monatsh monatsh ADJ eurjchem-1613 303 2 . . PUNCT eurjchem-1613 304 1 fur fur NOUN eurjchem-1613 304 2 chemie chemie NOUN eurjchem-1613 304 3 chem chem NOUN eurjchem-1613 304 4 . . PUNCT eurjchem-1613 305 1 monthly monthly ADJ eurjchem-1613 305 2 1992 1992 NUM eurjchem-1613 305 3 , , PUNCT eurjchem-1613 305 4 123 123 NUM eurjchem-1613 305 5 , , PUNCT eurjchem-1613 305 6 1099‐1105 1099‐1105 NUM eurjchem-1613 305 7 . . PUNCT eurjchem-1613 306 1 [ [ X eurjchem-1613 306 2 34 34 NUM eurjchem-1613 306 3 ] ] PUNCT eurjchem-1613 306 4 . . PUNCT eurjchem-1613 307 1 dogan dogan PROPN eurjchem-1613 307 2 , , PUNCT eurjchem-1613 307 3 a. a. PROPN eurjchem-1613 307 4 ; ; PUNCT eurjchem-1613 307 5 aslan aslan PROPN eurjchem-1613 307 6 , , PUNCT eurjchem-1613 307 7 n. n. PROPN eurjchem-1613 307 8 ; ; PUNCT eurjchem-1613 307 9 canel canel PROPN eurjchem-1613 307 10 , , PUNCT eurjchem-1613 307 11 e. e. PROPN eurjchem-1613 307 12 ; ; PUNCT eurjchem-1613 307 13 kilic kilic PROPN eurjchem-1613 307 14 , , PUNCT eurjchem-1613 307 15 e. e. PROPN eurjchem-1613 307 16 j. j. PROPN eurjchem-1613 307 17 solution solution PROPN eurjchem-1613 307 18 chem chem PROPN eurjchem-1613 307 19 . . PUNCT eurjchem-1613 308 1 2010 2010 NUM eurjchem-1613 308 2 , , PUNCT eurjchem-1613 308 3 39 39 NUM eurjchem-1613 308 4 , , PUNCT eurjchem-1613 308 5 1589‐1596 1589‐1596 NUM eurjchem-1613 308 6 . . PUNCT eurjchem-1613 309 1 [ [ X eurjchem-1613 309 2 35 35 NUM eurjchem-1613 309 3 ] ] SYM eurjchem-1613 309 4 . . PUNCT eurjchem-1613 309 5 tang tang PROPN eurjchem-1613 309 6 , , PUNCT eurjchem-1613 309 7 x. x. PROPN eurjchem-1613 309 8 ; ; PUNCT eurjchem-1613 310 1 liu liu PROPN eurjchem-1613 310 2 , , PUNCT eurjchem-1613 310 3 y. y. PROPN eurjchem-1613 310 4 ; ; PUNCT eurjchem-1613 310 5 hou hou PROPN eurjchem-1613 310 6 , , PUNCT eurjchem-1613 310 7 h. h. PROPN eurjchem-1613 310 8 ; ; PUNCT eurjchem-1613 310 9 you you PRON eurjchem-1613 310 10 , , PUNCT eurjchem-1613 310 11 t. t. PROPN eurjchem-1613 310 12 talanta talanta PROPN eurjchem-1613 310 13 2010 2010 NUM eurjchem-1613 310 14 , , PUNCT eurjchem-1613 310 15 80 80 NUM eurjchem-1613 310 16 , , PUNCT eurjchem-1613 310 17 2182‐2186 2182‐2186 NUM eurjchem-1613 310 18 . . PUNCT eurjchem-1613 311 1 [ [ X eurjchem-1613 311 2 36 36 NUM eurjchem-1613 311 3 ] ] PUNCT eurjchem-1613 311 4 . . PUNCT eurjchem-1613 311 5 chalmers chalmers PROPN eurjchem-1613 311 6 , , PUNCT eurjchem-1613 311 7 r. r. PROPN eurjchem-1613 311 8 a. a. NOUN eurjchem-1613 311 9 chemistry chemistry PROPN eurjchem-1613 311 10 of of ADP eurjchem-1613 311 11 complex complex ADJ eurjchem-1613 311 12 equilibria equilibrium NOUN eurjchem-1613 311 13 : : PUNCT eurjchem-1613 311 14 van van PROPN eurjchem-1613 311 15 nostrand nostrand PROPN eurjchem-1613 311 16 reinhold reinhold PROPN eurjchem-1613 311 17 company company PROPN eurjchem-1613 311 18 , , PUNCT eurjchem-1613 311 19 london london PROPN eurjchem-1613 311 20 , , PUNCT eurjchem-1613 311 21 uk uk PROPN eurjchem-1613 311 22 , , PUNCT eurjchem-1613 311 23 1970 1970 NUM eurjchem-1613 311 24 . . PUNCT eurjchem-1613 312 1 [ [ X eurjchem-1613 312 2 37 37 NUM eurjchem-1613 312 3 ] ] PUNCT eurjchem-1613 312 4 . . PUNCT eurjchem-1613 313 1 azab azab ADV eurjchem-1613 313 2 , , PUNCT eurjchem-1613 313 3 h. h. PROPN eurjchem-1613 313 4 a. a. PROPN eurjchem-1613 313 5 ; ; PUNCT eurjchem-1613 313 6 el‐nady el‐nady ADJ eurjchem-1613 313 7 , , PUNCT eurjchem-1613 313 8 a. a. NOUN eurjchem-1613 313 9 m. m. NOUN eurjchem-1613 313 10 ; ; PUNCT eurjchem-1613 313 11 el‐shatoury el‐shatoury NOUN eurjchem-1613 313 12 , , PUNCT eurjchem-1613 313 13 s. s. PROPN eurjchem-1613 313 14 a. a. PROPN eurjchem-1613 313 15 ; ; PUNCT eurjchem-1613 314 1 hassan hassan PROPN eurjchem-1613 314 2 , , PUNCT eurjchem-1613 314 3 a. a. PROPN eurjchem-1613 314 4 talanta talanta PROPN eurjchem-1613 314 5 1994 1994 NUM eurjchem-1613 314 6 , , PUNCT eurjchem-1613 314 7 41 41 NUM eurjchem-1613 314 8 , , PUNCT eurjchem-1613 314 9 1255‐1259 1255‐1259 NUM eurjchem-1613 314 10 . . PUNCT