id	sid	tid	token	lemma	pos
eurjchem-1675	1	1	synthesis	synthesis	NOUN
eurjchem-1675	1	2	and	and	CCONJ
eurjchem-1675	1	3	dft	dft	NOUN
eurjchem-1675	1	4	study	study	NOUN
eurjchem-1675	1	5	of	of	ADP
eurjchem-1675	1	6	novel	novel	ADJ
eurjchem-1675	1	7	pyrazole	pyrazole	NOUN
eurjchem-1675	1	8	,	,	PUNCT
eurjchem-1675	1	9	thiophene	thiophene	NOUN
eurjchem-1675	1	10	,	,	PUNCT
eurjchem-1675	1	11	1,3	1,3	NUM
eurjchem-1675	1	12	-	-	PUNCT
eurjchem-1675	1	13	thiazole	thiazole	NOUN
eurjchem-1675	1	14	and	and	CCONJ
eurjchem-1675	1	15	1,3,4	1,3,4	NUM
eurjchem-1675	1	16	-	-	PUNCT
eurjchem-1675	1	17	thiadiazole	thiadiazole	NOUN
eurjchem-1675	1	18	derivatives	derivative	NOUN
eurjchem-1675	1	19	european	european	PROPN
eurjchem-1675	1	20	journal	journal	PROPN
eurjchem-1675	1	21	of	of	ADP
eurjchem-1675	1	22	chemistry	chemistry	NOUN
eurjchem-1675	1	23	9	9	NUM
eurjchem-1675	1	24	(	(	PUNCT
eurjchem-1675	1	25	1	1	NUM
eurjchem-1675	1	26	)	)	PUNCT
eurjchem-1675	1	27	(	(	PUNCT
eurjchem-1675	1	28	2018	2018	NUM
eurjchem-1675	1	29	)	)	PUNCT
eurjchem-1675	1	30	30	30	NUM
eurjchem-1675	1	31	-	-	SYM
eurjchem-1675	1	32	38	38	NUM
eurjchem-1675	1	33	european	european	ADJ
eurjchem-1675	1	34	journal	journal	NOUN
eurjchem-1675	1	35	of	of	ADP
eurjchem-1675	1	36	chemistry	chemistry	NOUN
eurjchem-1675	1	37	view	view	NOUN
eurjchem-1675	1	38	journal	journal	PROPN
eurjchem-1675	1	39	online	online	PROPN
eurjchem-1675	1	40	view	view	NOUN
eurjchem-1675	1	41	article	article	NOUN
eurjchem-1675	1	42	online	online	ADJ
eurjchem-1675	1	43	synthesis	synthesis	NOUN
eurjchem-1675	1	44	and	and	CCONJ
eurjchem-1675	1	45	dft	dft	NOUN
eurjchem-1675	1	46	study	study	NOUN
eurjchem-1675	1	47	of	of	ADP
eurjchem-1675	1	48	novel	novel	ADJ
eurjchem-1675	1	49	pyrazole	pyrazole	NOUN
eurjchem-1675	1	50	,	,	PUNCT
eurjchem-1675	1	51	thiophene	thiophene	NOUN
eurjchem-1675	1	52	,	,	PUNCT
eurjchem-1675	1	53	1,3	1,3	NUM
eurjchem-1675	1	54	-	-	PUNCT
eurjchem-1675	1	55	thiazole	thiazole	NOUN
eurjchem-1675	1	56	and	and	CCONJ
eurjchem-1675	1	57	1,3,4	1,3,4	NUM
eurjchem-1675	1	58	-	-	PUNCT
eurjchem-1675	1	59	thiadiazole	thiadiazole	NOUN
eurjchem-1675	1	60	derivatives	derivative	NOUN
eurjchem-1675	1	61	asmaa	asmaa	PROPN
eurjchem-1675	1	62	mahmoud	mahmoud	PROPN
eurjchem-1675	1	63	fahim	fahim	PROPN
eurjchem-1675	1	64	1	1	NUM
eurjchem-1675	1	65	,	,	PUNCT
eurjchem-1675	1	66	*	*	PUNCT
eurjchem-1675	1	67	,	,	PUNCT
eurjchem-1675	1	68	ahmad	ahmad	PROPN
eurjchem-1675	1	69	mahmoud	mahmoud	PROPN
eurjchem-1675	1	70	farag	farag	PROPN
eurjchem-1675	1	71	2	2	NUM
eurjchem-1675	1	72	,	,	PUNCT
eurjchem-1675	1	73	mohamed	mohamed	PROPN
eurjchem-1675	1	74	rabie	rabie	PROPN
eurjchem-1675	1	75	shaaban	shaaban	VERB
eurjchem-1675	1	76	2,3	2,3	NUM
eurjchem-1675	1	77	and	and	CCONJ
eurjchem-1675	1	78	eman	eman	PROPN
eurjchem-1675	1	79	ali	ali	PROPN
eurjchem-1675	1	80	ragab	ragab	PROPN
eurjchem-1675	1	81	2	2	NUM
eurjchem-1675	1	82	1	1	NUM
eurjchem-1675	1	83	department	department	NOUN
eurjchem-1675	1	84	of	of	ADP
eurjchem-1675	1	85	green	green	ADJ
eurjchem-1675	1	86	chemistry	chemistry	NOUN
eurjchem-1675	1	87	,	,	PUNCT
eurjchem-1675	1	88	national	national	ADJ
eurjchem-1675	1	89	research	research	NOUN
eurjchem-1675	1	90	center	center	NOUN
eurjchem-1675	1	91	,	,	PUNCT
eurjchem-1675	1	92	dokki	dokki	PROPN
eurjchem-1675	1	93	,	,	PUNCT
eurjchem-1675	1	94	p.o	p.o	PROPN
eurjchem-1675	1	95	.	.	PROPN
eurjchem-1675	1	96	box	box	PROPN
eurjchem-1675	1	97	.	.	PUNCT
eurjchem-1675	2	1	12622	12622	NUM
eurjchem-1675	2	2	,	,	PUNCT
eurjchem-1675	2	3	cairo	cairo	PROPN
eurjchem-1675	2	4	,	,	PUNCT
eurjchem-1675	2	5	egypt	egypt	PROPN
eurjchem-1675	2	6	asmaamahmoud8521@gmail.com	asmaamahmoud8521@gmail.com	PROPN
eurjchem-1675	3	1	(	(	PUNCT
eurjchem-1675	3	2	a.m.f	a.m.f	PROPN
eurjchem-1675	3	3	.	.	PUNCT
eurjchem-1675	3	4	)	)	PUNCT
eurjchem-1675	4	1	2	2	NUM
eurjchem-1675	4	2	chemistry	chemistry	NOUN
eurjchem-1675	4	3	department	department	NOUN
eurjchem-1675	4	4	,	,	PUNCT
eurjchem-1675	4	5	faculty	faculty	NOUN
eurjchem-1675	4	6	of	of	ADP
eurjchem-1675	4	7	science	science	NOUN
eurjchem-1675	4	8	,	,	PUNCT
eurjchem-1675	4	9	cairo	cairo	PROPN
eurjchem-1675	4	10	university	university	PROPN
eurjchem-1675	4	11	,	,	PUNCT
eurjchem-1675	4	12	giza	giza	PROPN
eurjchem-1675	4	13	,	,	PUNCT
eurjchem-1675	4	14	12613	12613	NUM
eurjchem-1675	4	15	,	,	PUNCT
eurjchem-1675	4	16	egypt	egypt	PROPN
eurjchem-1675	4	17	afarag49@gmail.com	afarag49@gmail.com	PROPN
eurjchem-1675	4	18	(	(	PUNCT
eurjchem-1675	4	19	a.m.f	a.m.f	NOUN
eurjchem-1675	4	20	.	.	PUNCT
eurjchem-1675	4	21	)	)	PUNCT
eurjchem-1675	4	22	,	,	PUNCT
eurjchem-1675	4	23	emanragab72@yahoo.com	emanragab72@yahoo.com	X
eurjchem-1675	4	24	(	(	PUNCT
eurjchem-1675	4	25	e.a.r	e.a.r	NOUN
eurjchem-1675	4	26	.	.	PUNCT
eurjchem-1675	4	27	)	)	PUNCT
eurjchem-1675	5	1	3	3	NUM
eurjchem-1675	5	2	department	department	NOUN
eurjchem-1675	5	3	of	of	ADP
eurjchem-1675	5	4	chemistry	chemistry	NOUN
eurjchem-1675	5	5	,	,	PUNCT
eurjchem-1675	5	6	faculty	faculty	NOUN
eurjchem-1675	5	7	of	of	ADP
eurjchem-1675	5	8	applied	apply	VERB
eurjchem-1675	5	9	science	science	NOUN
eurjchem-1675	5	10	,	,	PUNCT
eurjchem-1675	5	11	umm	umm	INTJ
eurjchem-1675	5	12	al	al	PROPN
eurjchem-1675	5	13	-	-	PUNCT
eurjchem-1675	5	14	qura	qura	PROPN
eurjchem-1675	5	15	university	university	PROPN
eurjchem-1675	5	16	,	,	PUNCT
eurjchem-1675	5	17	makkah	makkah	PROPN
eurjchem-1675	5	18	almukkarramah	almukkarramah	PROPN
eurjchem-1675	5	19	,	,	PUNCT
eurjchem-1675	5	20	21955	21955	NUM
eurjchem-1675	5	21	,	,	PUNCT
eurjchem-1675	5	22	kingdom	kingdom	NOUN
eurjchem-1675	5	23	of	of	ADP
eurjchem-1675	5	24	saudi	saudi	PROPN
eurjchem-1675	5	25	arabia	arabia	PROPN
eurjchem-1675	5	26	rabiemohamed@hotmail.com	rabiemohamed@hotmail.com	X
eurjchem-1675	5	27	(	(	PUNCT
eurjchem-1675	5	28	m.r.s	m.r.s	NOUN
eurjchem-1675	5	29	.	.	PUNCT
eurjchem-1675	5	30	)	)	PUNCT
eurjchem-1675	6	1	*	*	PUNCT
eurjchem-1675	6	2	corresponding	correspond	VERB
eurjchem-1675	6	3	author	author	NOUN
eurjchem-1675	6	4	at	at	ADP
eurjchem-1675	6	5	:	:	PUNCT
eurjchem-1675	6	6	department	department	NOUN
eurjchem-1675	6	7	of	of	ADP
eurjchem-1675	6	8	green	green	ADJ
eurjchem-1675	6	9	chemistry	chemistry	PROPN
eurjchem-1675	6	10	,	,	PUNCT
eurjchem-1675	6	11	national	national	ADJ
eurjchem-1675	6	12	research	research	NOUN
eurjchem-1675	6	13	center	center	NOUN
eurjchem-1675	6	14	,	,	PUNCT
eurjchem-1675	6	15	dokki	dokki	PROPN
eurjchem-1675	6	16	,	,	PUNCT
eurjchem-1675	6	17	p.o	p.o	PROPN
eurjchem-1675	6	18	.	.	PROPN
eurjchem-1675	6	19	box	box	PROPN
eurjchem-1675	6	20	.	.	PUNCT
eurjchem-1675	7	1	12622	12622	NUM
eurjchem-1675	7	2	,	,	PUNCT
eurjchem-1675	7	3	cairo	cairo	PROPN
eurjchem-1675	7	4	,	,	PUNCT
eurjchem-1675	7	5	egypt	egypt	PROPN
eurjchem-1675	7	6	.	.	PUNCT
eurjchem-1675	8	1	tel	tel	ADP
eurjchem-1675	8	2	:	:	PUNCT
eurjchem-1675	8	3	+2.002.01156161066	+2.002.01156161066	NUM
eurjchem-1675	8	4	fax	fax	NOUN
eurjchem-1675	8	5	:	:	PUNCT
eurjchem-1675	8	6	+2.002.01156161066	+2.002.01156161066	ADJ
eurjchem-1675	8	7	e	e	NOUN
eurjchem-1675	8	8	-	-	NOUN
eurjchem-1675	8	9	mail	mail	NOUN
eurjchem-1675	8	10	:	:	PUNCT
eurjchem-1675	8	11	asmaamahmoud8521@gmail.com	asmaamahmoud8521@gmail.com	X
eurjchem-1675	9	1	(	(	PUNCT
eurjchem-1675	9	2	a.m.	a.m.	NOUN
eurjchem-1675	9	3	fahim	fahim	PROPN
eurjchem-1675	9	4	)	)	PUNCT
eurjchem-1675	9	5	.	.	PUNCT
eurjchem-1675	10	1	10.5155	10.5155	NUM
eurjchem-1675	10	2	/	/	SYM
eurjchem-1675	10	3	eurjchem.9.1.30	eurjchem.9.1.30	PROPN
eurjchem-1675	10	4	-	-	SYM
eurjchem-1675	10	5	38.1675	38.1675	NUM
eurjchem-1675	10	6	received	receive	VERB
eurjchem-1675	10	7	:	:	PUNCT
eurjchem-1675	10	8	23	23	NUM
eurjchem-1675	10	9	november	november	PROPN
eurjchem-1675	10	10	2017	2017	NUM
eurjchem-1675	10	11	received	receive	VERB
eurjchem-1675	10	12	in	in	ADP
eurjchem-1675	10	13	revised	revise	VERB
eurjchem-1675	10	14	form	form	NOUN
eurjchem-1675	10	15	:	:	PUNCT
eurjchem-1675	10	16	22	22	NUM
eurjchem-1675	10	17	december	december	PROPN
eurjchem-1675	10	18	2017	2017	NUM
eurjchem-1675	10	19	accepted	accept	VERB
eurjchem-1675	10	20	:	:	PUNCT
eurjchem-1675	10	21	29	29	NUM
eurjchem-1675	10	22	december	december	PROPN
eurjchem-1675	10	23	2017	2017	NUM
eurjchem-1675	10	24	published	publish	VERB
eurjchem-1675	10	25	online	online	ADV
eurjchem-1675	10	26	:	:	PUNCT
eurjchem-1675	10	27	31	31	NUM
eurjchem-1675	10	28	march	march	PROPN
eurjchem-1675	10	29	2018	2018	NUM
eurjchem-1675	10	30	printed	print	VERB
eurjchem-1675	10	31	:	:	PUNCT
eurjchem-1675	10	32	31	31	NUM
eurjchem-1675	10	33	march	march	PROPN
eurjchem-1675	10	34	2018	2018	NUM
eurjchem-1675	10	35	regioselective	regioselective	ADJ
eurjchem-1675	10	36	facile	facile	ADJ
eurjchem-1675	10	37	synthesis	synthesis	NOUN
eurjchem-1675	10	38	of	of	ADP
eurjchem-1675	10	39	innovative	innovative	ADJ
eurjchem-1675	10	40	heterocycles	heterocycle	NOUN
eurjchem-1675	10	41	from	from	ADP
eurjchem-1675	10	42	the	the	DET
eurjchem-1675	10	43	reaction	reaction	NOUN
eurjchem-1675	10	44	of	of	ADP
eurjchem-1675	10	45	2	2	NUM
eurjchem-1675	10	46	-	-	PUNCT
eurjchem-1675	10	47	cyano	cyano	NOUN
eurjchem-1675	10	48	-	-	PUNCT
eurjchem-1675	10	49	ncyclohexylacetamide	ncyclohexylacetamide	NOUN
eurjchem-1675	10	50	(	(	PUNCT
eurjchem-1675	10	51	3	3	NUM
eurjchem-1675	10	52	)	)	PUNCT
eurjchem-1675	10	53	with	with	ADP
eurjchem-1675	10	54	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1675	10	55	chloride	chloride	PROPN
eurjchem-1675	10	56	(	(	PUNCT
eurjchem-1675	10	57	4	4	NUM
eurjchem-1675	10	58	)	)	PUNCT
eurjchem-1675	10	59	in	in	ADP
eurjchem-1675	10	60	basic	basic	ADJ
eurjchem-1675	10	61	condition	condition	NOUN
eurjchem-1675	10	62	afforded	afford	VERB
eurjchem-1675	10	63	amino	amino	NOUN
eurjchem-1675	10	64	pyrazole	pyrazole	NOUN
eurjchem-1675	10	65	derivative	derivative	ADJ
eurjchem-1675	10	66	6	6	NUM
eurjchem-1675	10	67	.	.	PUNCT
eurjchem-1675	11	1	the	the	DET
eurjchem-1675	11	2	behavior	behavior	NOUN
eurjchem-1675	11	3	of	of	ADP
eurjchem-1675	11	4	acetamide	acetamide	NOUN
eurjchem-1675	11	5	3	3	NUM
eurjchem-1675	11	6	with	with	ADP
eurjchem-1675	11	7	phenylisothiocyanate	phenylisothiocyanate	NOUN
eurjchem-1675	11	8	in	in	ADP
eurjchem-1675	11	9	dmf	dmf	PROPN
eurjchem-1675	11	10	/	/	SYM
eurjchem-1675	11	11	koh	koh	PROPN
eurjchem-1675	11	12	surveyed	survey	VERB
eurjchem-1675	11	13	by	by	ADP
eurjchem-1675	11	14	addition	addition	NOUN
eurjchem-1675	11	15	of	of	ADP
eurjchem-1675	11	16	the	the	DET
eurjchem-1675	11	17	α	α	NOUN
eurjchem-1675	11	18	-	-	ADJ
eurjchem-1675	11	19	halo	halo	NOUN
eurjchem-1675	11	20	ketones	ketone	NOUN
eurjchem-1675	11	21	to	to	PART
eurjchem-1675	11	22	yeild	yeild	VERB
eurjchem-1675	11	23	the	the	DET
eurjchem-1675	11	24	corresponding	corresponding	ADJ
eurjchem-1675	11	25	thiophene	thiophene	NOUN
eurjchem-1675	11	26	derivative	derivative	ADJ
eurjchem-1675	11	27	13a	13a	NOUN
eurjchem-1675	11	28	,	,	PUNCT
eurjchem-1675	11	29	13b	13b	NUM
eurjchem-1675	11	30	,	,	PUNCT
eurjchem-1675	11	31	16	16	NUM
eurjchem-1675	11	32	,	,	PUNCT
eurjchem-1675	11	33	18	18	NUM
eurjchem-1675	11	34	and	and	CCONJ
eurjchem-1675	11	35	1,3	1,3	NUM
eurjchem-1675	11	36	-	-	PUNCT
eurjchem-1675	11	37	thiazoles	thiazole	NOUN
eurjchem-1675	11	38	21	21	NUM
eurjchem-1675	11	39	.	.	PUNCT
eurjchem-1675	12	1	reaction	reaction	NOUN
eurjchem-1675	12	2	of	of	ADP
eurjchem-1675	12	3	intermediate	intermediate	ADJ
eurjchem-1675	12	4	potassium	potassium	NOUN
eurjchem-1675	12	5	salt	salt	NOUN
eurjchem-1675	12	6	9	9	NUM
eurjchem-1675	12	7	with	with	ADP
eurjchem-1675	12	8	hydrazonoyl	hydrazonoyl	PROPN
eurjchem-1675	12	9	chloride	chloride	PROPN
eurjchem-1675	12	10	22a	22a	NOUN
eurjchem-1675	12	11	-	-	PUNCT
eurjchem-1675	12	12	e	e	NOUN
eurjchem-1675	12	13	furnished	furnish	VERB
eurjchem-1675	12	14	the	the	DET
eurjchem-1675	12	15	corresponding	corresponding	ADJ
eurjchem-1675	12	16	1,2,4	1,2,4	NUM
eurjchem-1675	12	17	-	-	PUNCT
eurjchem-1675	12	18	thiadiazoles	thiadiazole	NOUN
eurjchem-1675	12	19	24a	24a	NOUN
eurjchem-1675	12	20	-	-	PUNCT
eurjchem-1675	12	21	e.	e.	PROPN
eurjchem-1675	12	22	density	density	PROPN
eurjchem-1675	12	23	functional	functional	ADJ
eurjchem-1675	12	24	theory	theory	NOUN
eurjchem-1675	12	25	(	(	PUNCT
eurjchem-1675	12	26	dft	dft	NOUN
eurjchem-1675	12	27	)	)	PUNCT
eurjchem-1675	12	28	calculations	calculation	NOUN
eurjchem-1675	12	29	at	at	ADP
eurjchem-1675	12	30	the	the	DET
eurjchem-1675	12	31	b3lyp	b3lyp	NOUN
eurjchem-1675	12	32	and	and	CCONJ
eurjchem-1675	12	33	hf	hf	ADP
eurjchem-1675	12	34	techniques	technique	NOUN
eurjchem-1675	12	35	combined	combine	VERB
eurjchem-1675	12	36	with	with	ADP
eurjchem-1675	12	37	631g(d	631g(d	NOUN
eurjchem-1675	12	38	)	)	PUNCT
eurjchem-1675	12	39	basis	basis	NOUN
eurjchem-1675	12	40	set	set	VERB
eurjchem-1675	12	41	to	to	PART
eurjchem-1675	12	42	investigate	investigate	VERB
eurjchem-1675	12	43	the	the	DET
eurjchem-1675	12	44	equilibrium	equilibrium	NOUN
eurjchem-1675	12	45	geometry	geometry	NOUN
eurjchem-1675	12	46	of	of	ADP
eurjchem-1675	12	47	the	the	DET
eurjchem-1675	12	48	innovative	innovative	ADJ
eurjchem-1675	12	49	compound	compound	NOUN
eurjchem-1675	12	50	pyrazoles	pyrazole	VERB
eurjchem-1675	12	51	6	6	NUM
eurjchem-1675	12	52	and	and	CCONJ
eurjchem-1675	12	53	the	the	DET
eurjchem-1675	12	54	stability	stability	NOUN
eurjchem-1675	12	55	affording	afford	VERB
eurjchem-1675	12	56	of	of	ADP
eurjchem-1675	12	57	homo	homo	NOUN
eurjchem-1675	12	58	/	/	SYM
eurjchem-1675	12	59	lumo	lumo	NOUN
eurjchem-1675	12	60	molecular	molecular	ADJ
eurjchem-1675	12	61	orbitals	orbital	NOUN
eurjchem-1675	12	62	.	.	PUNCT
eurjchem-1675	13	1	pyrazoles	pyrazole	VERB
eurjchem-1675	13	2	thiophene	thiophene	NOUN
eurjchem-1675	13	3	1,3	1,3	NUM
eurjchem-1675	13	4	-	-	PUNCT
eurjchem-1675	13	5	thiazoles	thiazole	NOUN
eurjchem-1675	13	6	dft	dft	NOUN
eurjchem-1675	13	7	calculation	calculation	NOUN
eurjchem-1675	13	8	1,3,4	1,3,4	NUM
eurjchem-1675	13	9	-	-	PUNCT
eurjchem-1675	13	10	thiadiazole	thiadiazole	NOUN
eurjchem-1675	13	11	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	13	12	cite	cite	VERB
eurjchem-1675	13	13	this	this	PRON
eurjchem-1675	13	14	:	:	PUNCT
eurjchem-1675	13	15	eur	eur	PROPN
eurjchem-1675	13	16	.	.	PUNCT
eurjchem-1675	14	1	j.	j.	PROPN
eurjchem-1675	14	2	chem	chem	PROPN
eurjchem-1675	14	3	.	.	PUNCT
eurjchem-1675	15	1	2018	2018	NUM
eurjchem-1675	15	2	,	,	PUNCT
eurjchem-1675	15	3	9(1	9(1	NUM
eurjchem-1675	15	4	)	)	PUNCT
eurjchem-1675	15	5	,	,	PUNCT
eurjchem-1675	15	6	30	30	NUM
eurjchem-1675	15	7	-	-	SYM
eurjchem-1675	15	8	38	38	NUM
eurjchem-1675	15	9	journal	journal	NOUN
eurjchem-1675	15	10	website	website	NOUN
eurjchem-1675	15	11	:	:	PUNCT
eurjchem-1675	15	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1675	15	13	1	1	X
eurjchem-1675	15	14	.	.	PUNCT
eurjchem-1675	16	1	introduction	introduction	NOUN
eurjchem-1675	16	2	cyanoacetamide	cyanoacetamide	ADJ
eurjchem-1675	16	3	derivatives	derivative	NOUN
eurjchem-1675	16	4	are	be	AUX
eurjchem-1675	16	5	polyfunctional	polyfunctional	ADJ
eurjchem-1675	16	6	and	and	CCONJ
eurjchem-1675	16	7	extremely	extremely	ADV
eurjchem-1675	16	8	sensitive	sensitive	ADJ
eurjchem-1675	16	9	,	,	PUNCT
eurjchem-1675	16	10	which	which	PRON
eurjchem-1675	16	11	grip	grip	VERB
eurjchem-1675	16	12	both	both	CCONJ
eurjchem-1675	16	13	electrophilic	electrophilic	ADJ
eurjchem-1675	16	14	and	and	CCONJ
eurjchem-1675	16	15	nucleophilic	nucleophilic	ADJ
eurjchem-1675	16	16	interiors	interior	NOUN
eurjchem-1675	16	17	.	.	PUNCT
eurjchem-1675	17	1	two	two	NUM
eurjchem-1675	17	2	of	of	ADP
eurjchem-1675	17	3	the	the	DET
eurjchem-1675	17	4	nucleophilic	nucleophilic	ADJ
eurjchem-1675	17	5	interiors	interior	NOUN
eurjchem-1675	17	6	in	in	ADP
eurjchem-1675	17	7	cyanoacetamides	cyanoacetamide	NOUN
eurjchem-1675	17	8	are	be	AUX
eurjchem-1675	17	9	limited	limit	VERB
eurjchem-1675	17	10	on	on	ADP
eurjchem-1675	17	11	the	the	DET
eurjchem-1675	17	12	nh	nh	PROPN
eurjchem-1675	17	13	and	and	CCONJ
eurjchem-1675	17	14	the	the	DET
eurjchem-1675	17	15	c-2	c-2	NOUN
eurjchem-1675	17	16	positions	position	NOUN
eurjchem-1675	17	17	with	with	ADP
eurjchem-1675	17	18	a	a	DET
eurjchem-1675	17	19	reactivity	reactivity	NOUN
eurjchem-1675	17	20	instruction	instruction	NOUN
eurjchem-1675	17	21	,	,	PUNCT
eurjchem-1675	17	22	c-2	c-2	NOUN
eurjchem-1675	17	23	>	>	X
eurjchem-1675	17	24	nh	nh	PROPN
eurjchem-1675	17	25	.	.	PROPN
eurjchem-1675	18	1	two	two	NUM
eurjchem-1675	18	2	electrophilic	electrophilic	ADJ
eurjchem-1675	18	3	positions	position	NOUN
eurjchem-1675	18	4	are	be	AUX
eurjchem-1675	18	5	attached	attach	VERB
eurjchem-1675	18	6	with	with	ADP
eurjchem-1675	18	7	the	the	DET
eurjchem-1675	18	8	c-1	c-1	NOUN
eurjchem-1675	18	9	and	and	CCONJ
eurjchem-1675	18	10	c-3	c-3	PROPN
eurjchem-1675	18	11	situations	situation	NOUN
eurjchem-1675	18	12	with	with	ADP
eurjchem-1675	18	13	reactivity	reactivity	NOUN
eurjchem-1675	18	14	order	order	NOUN
eurjchem-1675	18	15	c-3	c-3	NOUN
eurjchem-1675	18	16	>	>	X
eurjchem-1675	19	1	c-1	c-1	NOUN
eurjchem-1675	19	2	(	(	PUNCT
eurjchem-1675	19	3	figure	figure	NOUN
eurjchem-1675	19	4	1	1	NUM
eurjchem-1675	19	5	)	)	PUNCT
eurjchem-1675	20	1	[	[	X
eurjchem-1675	20	2	1	1	NUM
eurjchem-1675	20	3	-	-	SYM
eurjchem-1675	20	4	5	5	NUM
eurjchem-1675	20	5	]	]	PUNCT
eurjchem-1675	20	6	.	.	PUNCT
eurjchem-1675	21	1	cyanoacetamide	cyanoacetamide	ADJ
eurjchem-1675	21	2	active	active	ADJ
eurjchem-1675	21	3	synthons	synthon	NOUN
eurjchem-1675	21	4	are	be	AUX
eurjchem-1675	21	5	successfully	successfully	ADV
eurjchem-1675	21	6	used	use	VERB
eurjchem-1675	21	7	for	for	ADP
eurjchem-1675	21	8	the	the	DET
eurjchem-1675	21	9	creations	creation	NOUN
eurjchem-1675	21	10	of	of	ADP
eurjchem-1675	21	11	numerous	numerous	ADJ
eurjchem-1675	21	12	open	open	ADJ
eurjchem-1675	21	13	-	-	PUNCT
eurjchem-1675	21	14	chain	chain	NOUN
eurjchem-1675	21	15	groups	group	NOUN
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eurjchem-1675	21	17	poly	poly	ADJ
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eurjchem-1675	21	20	moieties	moiety	NOUN
eurjchem-1675	21	21	[	[	PUNCT
eurjchem-1675	21	22	6	6	NUM
eurjchem-1675	21	23	-	-	SYM
eurjchem-1675	21	24	8	8	NUM
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eurjchem-1675	21	26	.	.	PUNCT
eurjchem-1675	22	1	the	the	DET
eurjchem-1675	22	2	occurrence	occurrence	NOUN
eurjchem-1675	22	3	of	of	ADP
eurjchem-1675	22	4	two	two	NUM
eurjchem-1675	22	5	electron	electron	NOUN
eurjchem-1675	22	6	-	-	PUNCT
eurjchem-1675	22	7	withdrawing	withdraw	VERB
eurjchem-1675	22	8	groups	group	NOUN
eurjchem-1675	22	9	’	'	PUNCT
eurjchem-1675	22	10	outcomes	outcome	NOUN
eurjchem-1675	22	11	in	in	ADP
eurjchem-1675	22	12	the	the	DET
eurjchem-1675	22	13	extraordinary	extraordinary	ADJ
eurjchem-1675	22	14	action	action	NOUN
eurjchem-1675	22	15	of	of	ADP
eurjchem-1675	22	16	cyanoacetamides	cyanoacetamide	NOUN
eurjchem-1675	22	17	as	as	ADP
eurjchem-1675	22	18	ch	ch	NOUN
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eurjchem-1675	22	22	active	active	ADJ
eurjchem-1675	22	23	methylene	methylene	NOUN
eurjchem-1675	22	24	worth	worth	NOUN
eurjchem-1675	22	25	they	they	PRON
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eurjchem-1675	22	28	included	include	VERB
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eurjchem-1675	22	30	a	a	DET
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eurjchem-1675	22	32	of	of	ADP
eurjchem-1675	22	33	condensation	condensation	NOUN
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eurjchem-1675	22	36	reactions	reaction	NOUN
eurjchem-1675	22	37	[	[	X
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eurjchem-1675	23	11	them	they	PRON
eurjchem-1675	23	12	to	to	PART
eurjchem-1675	23	13	re	re	VERB
eurjchem-1675	23	14	-	-	VERB
eurjchem-1675	23	15	join	join	VERB
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eurjchem-1675	23	17	common	common	ADJ
eurjchem-1675	23	18	reagents	reagent	NOUN
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eurjchem-1675	23	20	form	form	VERB
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eurjchem-1675	23	43	[	[	X
eurjchem-1675	23	44	14	14	NUM
eurjchem-1675	23	45	-	-	SYM
eurjchem-1675	23	46	16	16	NUM
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eurjchem-1675	23	50	-	-	PUNCT
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eurjchem-1675	23	54	-	-	PUNCT
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eurjchem-1675	23	56	[	[	X
eurjchem-1675	23	57	17	17	NUM
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eurjchem-1675	24	1	[	[	X
eurjchem-1675	24	2	22,23	22,23	NOUN
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eurjchem-1675	24	4	.	.	PUNCT
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eurjchem-1675	25	10	for	for	ADP
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eurjchem-1675	25	22	[	[	PUNCT
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eurjchem-1675	26	9	3	3	NUM
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eurjchem-1675	29	11	–	–	PUNCT
eurjchem-1675	29	12	printed	print	VERB
eurjchem-1675	29	13	in	in	ADP
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eurjchem-1675	30	1	this	this	DET
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eurjchem-1675	30	8	atlanta	atlanta	PROPN
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eurjchem-1675	30	12	–	–	PUNCT
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eurjchem-1675	30	20	.	.	PUNCT
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eurjchem-1675	32	30	free	free	ADJ
eurjchem-1675	32	31	mw/	mw/	NOUN
eurjchem-1675	32	32	300	300	NUM
eurjchem-1675	32	33	w	w	NOUN
eurjchem-1675	32	34	/	/	SYM
eurjchem-1675	32	35	180	180	NUM
eurjchem-1675	32	36	oc	oc	NOUN
eurjchem-1675	32	37	h	h	NOUN
eurjchem-1675	33	1	n	n	NOUN
eurjchem-1675	34	1	h	h	NOUN
eurjchem-1675	35	1	cn	cn	NOUN
eurjchem-1675	35	2	o	o	PROPN
eurjchem-1675	36	1	+	+	CCONJ
eurjchem-1675	36	2	n	n	NUM
eurjchem-1675	36	3	3	3	NUM
eurjchem-1675	36	4	1	1	NUM
eurjchem-1675	36	5	2	2	NUM
eurjchem-1675	36	6	n	n	PRON
eurjchem-1675	36	7	nhh3cco	nhh3cco	NOUN
eurjchem-1675	36	8	4naoc2h5	4naoc2h5	NOUN
eurjchem-1675	36	9	/	/	SYM
eurjchem-1675	36	10	etoh	etoh	ADJ
eurjchem-1675	36	11	5	5	NUM
eurjchem-1675	36	12	ar	ar	NOUN
eurjchem-1675	36	13	=	=	NOUN
eurjchem-1675	36	14	4	4	NUM
eurjchem-1675	36	15	-	-	PUNCT
eurjchem-1675	36	16	ch3oc6h4	ch3oc6h4	ADP
eurjchem-1675	36	17	hn	hn	PROPN
eurjchem-1675	36	18	o	o	NOUN
eurjchem-1675	36	19	n	n	CCONJ
eurjchem-1675	36	20	n	n	PRON
eurjchem-1675	36	21	etooc	etooc	ADV
eurjchem-1675	36	22	nh2	nh2	PROPN
eurjchem-1675	36	23	6	6	NUM
eurjchem-1675	36	24	n	n	NOUN
eurjchem-1675	36	25	h	h	NOUN
eurjchem-1675	36	26	o	o	NOUN
eurjchem-1675	36	27	n	n	CCONJ
eurjchem-1675	36	28	nh	nh	PROPN
eurjchem-1675	36	29	cn	cn	PROPN
eurjchem-1675	36	30	7	7	NUM
eurjchem-1675	36	31	oc2h5	oc2h5	PROPN
eurjchem-1675	36	32	h	h	PROPN
eurjchem-1675	36	33	ar	ar	PROPN
eurjchem-1675	36	34	cl	cl	PROPN
eurjchem-1675	36	35	ar	ar	PROPN
eurjchem-1675	36	36	ar	ar	PROPN
eurjchem-1675	36	37	h	h	PROPN
eurjchem-1675	37	1	hn	hn	NOUN
eurjchem-1675	37	2	o	o	INTJ
eurjchem-1675	37	3	cn	cn	PROPN
eurjchem-1675	37	4	n	n	CCONJ
eurjchem-1675	37	5	n	n	CCONJ
eurjchem-1675	37	6	coch3	coch3	ADJ
eurjchem-1675	37	7	h	h	PROPN
eurjchem-1675	37	8	ar	ar	PROPN
eurjchem-1675	37	9	aromatization	aromatization	PROPN
eurjchem-1675	38	1	h	h	PROPN
eurjchem-1675	38	2	nh	nh	PROPN
eurjchem-1675	38	3	o	o	PROPN
eurjchem-1675	38	4	nc	nc	PROPN
eurjchem-1675	38	5	coch3	coch3	PROPN
eurjchem-1675	38	6	n	n	PROPN
eurjchem-1675	38	7	nh	nh	PROPN
eurjchem-1675	38	8	ar	ar	PROPN
eurjchem-1675	38	9	-h2o	-h2o	NOUN
eurjchem-1675	38	10	8	8	NUM
eurjchem-1675	38	11	scheme	scheme	NOUN
eurjchem-1675	38	12	1	1	NUM
eurjchem-1675	38	13	may	may	AUX
eurjchem-1675	38	14	possibly	possibly	ADV
eurjchem-1675	38	15	exist	exist	VERB
eurjchem-1675	38	16	applicable	applicable	ADJ
eurjchem-1675	38	17	a	a	DET
eurjchem-1675	38	18	numerous	numerous	ADJ
eurjchem-1675	38	19	techniques	technique	NOUN
eurjchem-1675	38	20	.	.	PUNCT
eurjchem-1675	39	1	the	the	DET
eurjchem-1675	39	2	greatest	great	ADJ
eurjchem-1675	39	3	versatile	versatile	ADJ
eurjchem-1675	39	4	and	and	CCONJ
eurjchem-1675	39	5	routinely	routinely	ADV
eurjchem-1675	39	6	used	use	VERB
eurjchem-1675	39	7	preparative	preparative	ADJ
eurjchem-1675	39	8	method	method	NOUN
eurjchem-1675	39	9	is	be	AUX
eurjchem-1675	39	10	the	the	DET
eurjchem-1675	39	11	acylation	acylation	NOUN
eurjchem-1675	39	12	of	of	ADP
eurjchem-1675	39	13	aromatic	aromatic	ADJ
eurjchem-1675	39	14	or	or	CCONJ
eurjchem-1675	39	15	heterocyclic	heterocyclic	ADJ
eurjchem-1675	39	16	amines	amine	NOUN
eurjchem-1675	39	17	with	with	ADP
eurjchem-1675	39	18	ethyl	ethyl	PROPN
eurjchem-1675	39	19	cyanoacetate	cyanoacetate	NOUN
eurjchem-1675	39	20	further	far	ADV
eurjchem-1675	39	21	down	down	ADP
eurjchem-1675	39	22	numerous	numerous	ADJ
eurjchem-1675	39	23	reaction	reaction	NOUN
eurjchem-1675	39	24	conditions	condition	NOUN
eurjchem-1675	39	25	[	[	X
eurjchem-1675	39	26	25	25	NUM
eurjchem-1675	39	27	]	]	PUNCT
eurjchem-1675	39	28	.	.	PUNCT
eurjchem-1675	40	1	our	our	PRON
eurjchem-1675	40	2	improvement	improvement	NOUN
eurjchem-1675	40	3	research	research	NOUN
eurjchem-1675	40	4	,	,	PUNCT
eurjchem-1675	40	5	to	to	PART
eurjchem-1675	40	6	institute	institute	VERB
eurjchem-1675	40	7	that	that	SCONJ
eurjchem-1675	40	8	the	the	DET
eurjchem-1675	40	9	hitherto	hitherto	NOUN
eurjchem-1675	40	10	unreported	unreporte	VERB
eurjchem-1675	40	11	2	2	NUM
eurjchem-1675	40	12	-	-	PUNCT
eurjchem-1675	40	13	cyano	cyano	NOUN
eurjchem-1675	40	14	-	-	PUNCT
eurjchem-1675	40	15	n	n	CCONJ
eurjchem-1675	40	16	-	-	PUNCT
eurjchem-1675	40	17	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	40	18	(	(	PUNCT
eurjchem-1675	40	19	3	3	NUM
eurjchem-1675	40	20	)	)	PUNCT
eurjchem-1675	40	21	is	be	AUX
eurjchem-1675	40	22	a	a	DET
eurjchem-1675	40	23	extremely	extremely	ADV
eurjchem-1675	40	24	versatile	versatile	ADJ
eurjchem-1675	40	25	structure	structure	NOUN
eurjchem-1675	40	26	block	block	NOUN
eurjchem-1675	40	27	for	for	ADP
eurjchem-1675	40	28	the	the	DET
eurjchem-1675	40	29	production	production	NOUN
eurjchem-1675	40	30	of	of	ADP
eurjchem-1675	40	31	an	an	DET
eurjchem-1675	40	32	extensive	extensive	ADJ
eurjchem-1675	40	33	variety	variety	NOUN
eurjchem-1675	40	34	of	of	ADP
eurjchem-1675	40	35	numerous	numerous	ADJ
eurjchem-1675	40	36	innovative	innovative	ADJ
eurjchem-1675	40	37	fused	fuse	VERB
eurjchem-1675	40	38	heterocyclic	heterocyclic	ADJ
eurjchem-1675	40	39	moieties	moiety	NOUN
eurjchem-1675	40	40	.	.	PUNCT
eurjchem-1675	41	1	we	we	PRON
eurjchem-1675	41	2	proficient	proficient	VERB
eurjchem-1675	41	3	theoretical	theoretical	ADJ
eurjchem-1675	41	4	studies	study	NOUN
eurjchem-1675	41	5	on	on	ADP
eurjchem-1675	41	6	the	the	DET
eurjchem-1675	41	7	furthermost	furthermost	ADJ
eurjchem-1675	41	8	encouraging	encouraging	ADJ
eurjchem-1675	41	9	fused	fuse	VERB
eurjchem-1675	41	10	heterocyclic	heterocyclic	ADJ
eurjchem-1675	41	11	compounds	compound	NOUN
eurjchem-1675	41	12	by	by	ADP
eurjchem-1675	41	13	exhausting	exhaust	VERB
eurjchem-1675	41	14	the	the	DET
eurjchem-1675	41	15	hf/6	hf/6	NOUN
eurjchem-1675	41	16	-	-	PUNCT
eurjchem-1675	41	17	31	31	NUM
eurjchem-1675	41	18	g	g	NOUN
eurjchem-1675	41	19	(	(	PUNCT
eurjchem-1675	41	20	d	d	NOUN
eurjchem-1675	41	21	)	)	PUNCT
eurjchem-1675	41	22	and	and	CCONJ
eurjchem-1675	41	23	dft	dft	PROPN
eurjchem-1675	41	24	(	(	PUNCT
eurjchem-1675	41	25	b3lyp/6	b3lyp/6	PROPN
eurjchem-1675	41	26	-	-	NOUN
eurjchem-1675	41	27	31g(d	31g(d	NUM
eurjchem-1675	41	28	)	)	PUNCT
eurjchem-1675	41	29	)	)	PUNCT
eurjchem-1675	41	30	techniques	technique	NOUN
eurjchem-1675	41	31	[	[	X
eurjchem-1675	41	32	26,27	26,27	NUM
eurjchem-1675	41	33	]	]	X
eurjchem-1675	41	34	highly	highly	ADV
eurjchem-1675	41	35	resourceful	resourceful	ADJ
eurjchem-1675	41	36	building	building	NOUN
eurjchem-1675	41	37	block	block	NOUN
eurjchem-1675	41	38	for	for	ADP
eurjchem-1675	41	39	the	the	DET
eurjchem-1675	41	40	synthesis	synthesis	NOUN
eurjchem-1675	41	41	of	of	ADP
eurjchem-1675	41	42	an	an	DET
eurjchem-1675	41	43	extensive	extensive	ADJ
eurjchem-1675	41	44	diversity	diversity	NOUN
eurjchem-1675	41	45	of	of	ADP
eurjchem-1675	41	46	numerous	numerous	ADJ
eurjchem-1675	41	47	innovative	innovative	ADJ
eurjchem-1675	41	48	pyridine	pyridine	NOUN
eurjchem-1675	41	49	-	-	PUNCT
eurjchem-1675	41	50	based	base	VERB
eurjchem-1675	41	51	heterocyclic	heterocyclic	ADJ
eurjchem-1675	41	52	derivatives	derivative	NOUN
eurjchem-1675	41	53	.	.	PUNCT
eurjchem-1675	42	1	we	we	PRON
eurjchem-1675	42	2	consummate	consummate	VERB
eurjchem-1675	42	3	theoretical	theoretical	ADJ
eurjchem-1675	42	4	studies	study	NOUN
eurjchem-1675	42	5	on	on	ADP
eurjchem-1675	42	6	the	the	DET
eurjchem-1675	42	7	furthermost	furthermost	ADJ
eurjchem-1675	42	8	encouraging	encouraging	ADJ
eurjchem-1675	42	9	fused	fuse	VERB
eurjchem-1675	42	10	heterocyclic	heterocyclic	ADJ
eurjchem-1675	42	11	compounds	compound	NOUN
eurjchem-1675	42	12	through	through	ADP
eurjchem-1675	42	13	exhausting	exhaust	VERB
eurjchem-1675	42	14	the	the	DET
eurjchem-1675	42	15	hf	hf	NOUN
eurjchem-1675	42	16	and	and	CCONJ
eurjchem-1675	42	17	dft	dft	PROPN
eurjchem-1675	42	18	processes	process	NOUN
eurjchem-1675	42	19	[	[	X
eurjchem-1675	42	20	28,29	28,29	X
eurjchem-1675	42	21	]	]	X
eurjchem-1675	42	22	utilizing	utilize	VERB
eurjchem-1675	42	23	gaussian	gaussian	NOUN
eurjchem-1675	42	24	09w	09w	NOUN
eurjchem-1675	43	1	[	[	X
eurjchem-1675	43	2	30	30	NUM
eurjchem-1675	43	3	]	]	PUNCT
eurjchem-1675	43	4	.	.	PUNCT
eurjchem-1675	43	5	2	2	X
eurjchem-1675	43	6	.	.	X
eurjchem-1675	43	7	experimental	experimental	ADJ
eurjchem-1675	43	8	2.1	2.1	NUM
eurjchem-1675	43	9	.	.	PUNCT
eurjchem-1675	43	10	general	general	ADJ
eurjchem-1675	43	11	gallenkamp	gallenkamp	NOUN
eurjchem-1675	43	12	melting	melting	NOUN
eurjchem-1675	43	13	point	point	NOUN
eurjchem-1675	43	14	apparatus	apparatus	NOUN
eurjchem-1675	43	15	was	be	AUX
eurjchem-1675	43	16	used	use	VERB
eurjchem-1675	43	17	for	for	ADP
eurjchem-1675	43	18	measuring	measure	VERB
eurjchem-1675	43	19	the	the	DET
eurjchem-1675	43	20	melting	melting	NOUN
eurjchem-1675	43	21	points	point	NOUN
eurjchem-1675	43	22	.	.	PUNCT
eurjchem-1675	44	1	moreover	moreover	ADV
eurjchem-1675	44	2	,	,	PUNCT
eurjchem-1675	44	3	shimadzu	shimadzu	ADJ
eurjchem-1675	44	4	ft	ft	PROPN
eurjchem-1675	44	5	-	-	PUNCT
eurjchem-1675	44	6	ir	ir	PROPN
eurjchem-1675	44	7	8101	8101	NUM
eurjchem-1675	44	8	pc	pc	NOUN
eurjchem-1675	44	9	infrared	infrare	VERB
eurjchem-1675	44	10	spectrophotometer	spectrophotometer	NOUN
eurjchem-1675	44	11	recorded	record	VERB
eurjchem-1675	44	12	the	the	DET
eurjchem-1675	44	13	ir	ir	PROPN
eurjchem-1675	44	14	spectra	spectra	PROPN
eurjchem-1675	44	15	.	.	PUNCT
eurjchem-1675	45	1	the	the	DET
eurjchem-1675	45	2	1h	1h	NUM
eurjchem-1675	45	3	nmr	nmr	NOUN
eurjchem-1675	45	4	and	and	CCONJ
eurjchem-1675	45	5	13c	13c	NOUN
eurjchem-1675	45	6	nmr	nmr	NOUN
eurjchem-1675	45	7	spectra	spectra	NOUN
eurjchem-1675	45	8	were	be	AUX
eurjchem-1675	45	9	determined	determine	VERB
eurjchem-1675	45	10	in	in	ADP
eurjchem-1675	45	11	cdcl3	cdcl3	NOUN
eurjchem-1675	45	12	or	or	CCONJ
eurjchem-1675	45	13	dmso	dmso	NOUN
eurjchem-1675	45	14	-	-	NOUN
eurjchem-1675	45	15	d6	d6	NOUN
eurjchem-1675	45	16	at	at	ADP
eurjchem-1675	45	17	300	300	NUM
eurjchem-1675	45	18	mhz	mhz	NOUN
eurjchem-1675	45	19	on	on	ADP
eurjchem-1675	45	20	a	a	DET
eurjchem-1675	45	21	varian	varian	NOUN
eurjchem-1675	45	22	mercury	mercury	NOUN
eurjchem-1675	45	23	vx	vx	ADP
eurjchem-1675	45	24	300	300	NUM
eurjchem-1675	45	25	nmr	nmr	NOUN
eurjchem-1675	45	26	spectrometer	spectrometer	NOUN
eurjchem-1675	45	27	(	(	PUNCT
eurjchem-1675	45	28	1h	1h	NUM
eurjchem-1675	45	29	at	at	ADP
eurjchem-1675	45	30	300	300	NUM
eurjchem-1675	45	31	mhz	mhz	NOUN
eurjchem-1675	45	32	,	,	PUNCT
eurjchem-1675	45	33	13c	13c	NOUN
eurjchem-1675	45	34	at	at	ADP
eurjchem-1675	45	35	75	75	NUM
eurjchem-1675	45	36	mhz	mhz	NOUN
eurjchem-1675	45	37	)	)	PUNCT
eurjchem-1675	45	38	exhausting	exhaust	VERB
eurjchem-1675	45	39	trimethyl	trimethyl	ADJ
eurjchem-1675	45	40	silane	silane	NOUN
eurjchem-1675	45	41	as	as	ADP
eurjchem-1675	45	42	an	an	DET
eurjchem-1675	45	43	internal	internal	ADJ
eurjchem-1675	45	44	typical	typical	ADJ
eurjchem-1675	45	45	.	.	PUNCT
eurjchem-1675	46	1	mass	mass	PROPN
eurjchem-1675	46	2	spectra	spectra	PROPN
eurjchem-1675	46	3	were	be	AUX
eurjchem-1675	46	4	recorded	record	VERB
eurjchem-1675	46	5	on	on	ADP
eurjchem-1675	46	6	a	a	DET
eurjchem-1675	46	7	shimadzu	shimadzu	ADJ
eurjchem-1675	46	8	gcms	gcms	NOUN
eurjchem-1675	46	9	-	-	PUNCT
eurjchem-1675	46	10	qp	qp	PROPN
eurjchem-1675	46	11	1000	1000	NUM
eurjchem-1675	46	12	ex	ex	NOUN
eurjchem-1675	46	13	mass	mass	NOUN
eurjchem-1675	46	14	spectrometer	spectrometer	NOUN
eurjchem-1675	46	15	at	at	ADP
eurjchem-1675	46	16	70	70	NUM
eurjchem-1675	46	17	ev	ev	NOUN
eurjchem-1675	46	18	.	.	PROPN
eurjchem-1675	46	19	elemental	elemental	PROPN
eurjchem-1675	46	20	analyses	analysis	NOUN
eurjchem-1675	46	21	were	be	AUX
eurjchem-1675	46	22	approved	approve	VERB
eurjchem-1675	46	23	out	out	ADP
eurjchem-1675	46	24	at	at	ADP
eurjchem-1675	46	25	the	the	DET
eurjchem-1675	46	26	microanalytical	microanalytical	ADJ
eurjchem-1675	46	27	center	center	NOUN
eurjchem-1675	46	28	of	of	ADP
eurjchem-1675	46	29	cairo	cairo	PROPN
eurjchem-1675	46	30	university	university	PROPN
eurjchem-1675	46	31	,	,	PUNCT
eurjchem-1675	46	32	giza	giza	PROPN
eurjchem-1675	46	33	,	,	PUNCT
eurjchem-1675	46	34	egypt	egypt	PROPN
eurjchem-1675	46	35	.	.	PUNCT
eurjchem-1675	47	1	microwave	microwave	NOUN
eurjchem-1675	47	2	experiments	experiment	NOUN
eurjchem-1675	47	3	were	be	AUX
eurjchem-1675	47	4	carried	carry	VERB
eurjchem-1675	47	5	out	out	ADP
eurjchem-1675	47	6	using	use	VERB
eurjchem-1675	47	7	cem	cem	NOUN
eurjchem-1675	47	8	discovertm	discovertm	NOUN
eurjchem-1675	47	9	microwave	microwave	NOUN
eurjchem-1675	47	10	apparatus	apparatus	NOUN
eurjchem-1675	47	11	.	.	PUNCT
eurjchem-1675	48	1	2.2	2.2	NUM
eurjchem-1675	48	2	.	.	PUNCT
eurjchem-1675	48	3	material	material	NOUN
eurjchem-1675	48	4	and	and	CCONJ
eurjchem-1675	48	5	reagents	reagent	NOUN
eurjchem-1675	48	6	cyclohexylamine	cyclohexylamine	NOUN
eurjchem-1675	48	7	,	,	PUNCT
eurjchem-1675	48	8	ethylcyanoacetate	ethylcyanoacetate	ADJ
eurjchem-1675	48	9	,	,	PUNCT
eurjchem-1675	48	10	phenyl	phenyl	NOUN
eurjchem-1675	48	11	isothiocya	isothiocya	ADJ
eurjchem-1675	48	12	nate	nate	PROPN
eurjchem-1675	48	13	,	,	PUNCT
eurjchem-1675	48	14	dimethylformamide	dimethylformamide	NOUN
eurjchem-1675	48	15	,	,	PUNCT
eurjchem-1675	48	16	potassium	potassium	NOUN
eurjchem-1675	48	17	hydroxide	hydroxide	NOUN
eurjchem-1675	48	18	,	,	PUNCT
eurjchem-1675	48	19	bromo-1phenylethanone	bromo-1phenylethanone	PROPN
eurjchem-1675	48	20	,	,	PUNCT
eurjchem-1675	48	21	ethyl	ethyl	PROPN
eurjchem-1675	48	22	bromoacetate	bromoacetate	NOUN
eurjchem-1675	48	23	,	,	PUNCT
eurjchem-1675	48	24	chloroacetonitrile	chloroacetonitrile	NOUN
eurjchem-1675	48	25	,	,	PUNCT
eurjchem-1675	48	26	chloroacetone	chloroacetone	NOUN
eurjchem-1675	48	27	,	,	PUNCT
eurjchem-1675	48	28	ethanol	ethanol	NOUN
eurjchem-1675	48	29	and	and	CCONJ
eurjchem-1675	48	30	triethylamine	triethylamine	NOUN
eurjchem-1675	48	31	were	be	AUX
eurjchem-1675	48	32	purchased	purchase	VERB
eurjchem-1675	48	33	from	from	ADP
eurjchem-1675	48	34	aldrich	aldrich	PROPN
eurjchem-1675	48	35	chemical	chemical	PROPN
eurjchem-1675	48	36	co.	co.	PROPN
eurjchem-1675	48	37	methanol	methanol	NOUN
eurjchem-1675	48	38	,	,	PUNCT
eurjchem-1675	48	39	petroleum	petroleum	NOUN
eurjchem-1675	48	40	ether	ether	NOUN
eurjchem-1675	48	41	,	,	PUNCT
eurjchem-1675	48	42	chloroform	chloroform	NOUN
eurjchem-1675	48	43	were	be	AUX
eurjchem-1675	48	44	purchased	purchase	VERB
eurjchem-1675	48	45	from	from	ADP
eurjchem-1675	48	46	bdh	bdh	NOUN
eurjchem-1675	48	47	reagents	reagent	NOUN
eurjchem-1675	48	48	.	.	PUNCT
eurjchem-1675	49	1	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1675	49	2	chlorides	chloride	NOUN
eurjchem-1675	49	3	(	(	PUNCT
eurjchem-1675	49	4	4	4	NUM
eurjchem-1675	49	5	)	)	PUNCT
eurjchem-1675	49	6	,	,	PUNCT
eurjchem-1675	49	7	benzylidenecyanoacetate	benzylidenecyanoacetate	NOUN
eurjchem-1675	49	8	(	(	PUNCT
eurjchem-1675	49	9	22a	22a	NOUN
eurjchem-1675	49	10	-	-	SYM
eurjchem-1675	49	11	e	e	NOUN
eurjchem-1675	49	12	)	)	PUNCT
eurjchem-1675	49	13	were	be	AUX
eurjchem-1675	49	14	synthesised	synthesise	VERB
eurjchem-1675	49	15	following	follow	VERB
eurjchem-1675	49	16	literature	literature	NOUN
eurjchem-1675	49	17	processes	process	NOUN
eurjchem-1675	49	18	[	[	X
eurjchem-1675	49	19	20,21	20,21	NUM
eurjchem-1675	49	20	]	]	PUNCT
eurjchem-1675	49	21	.	.	PUNCT
eurjchem-1675	50	1	2.3	2.3	NUM
eurjchem-1675	50	2	.	.	PUNCT
eurjchem-1675	50	3	synthesis	synthesis	NOUN
eurjchem-1675	50	4	2	2	NUM
eurjchem-1675	50	5	-	-	PUNCT
eurjchem-1675	50	6	cyano	cyano	NOUN
eurjchem-1675	50	7	-	-	PUNCT
eurjchem-1675	50	8	n	n	CCONJ
eurjchem-1675	50	9	-	-	PUNCT
eurjchem-1675	50	10	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	50	11	(	(	PUNCT
eurjchem-1675	50	12	3	3	NUM
eurjchem-1675	50	13	)	)	PUNCT
eurjchem-1675	50	14	cyclohexylamine	cyclohexylamine	NOUN
eurjchem-1675	50	15	mixture	mixture	NOUN
eurjchem-1675	50	16	(	(	PUNCT
eurjchem-1675	50	17	1	1	NUM
eurjchem-1675	50	18	)	)	PUNCT
eurjchem-1675	50	19	(	(	PUNCT
eurjchem-1675	50	20	1.5	1.5	NUM
eurjchem-1675	50	21	g	g	NOUN
eurjchem-1675	50	22	,	,	PUNCT
eurjchem-1675	50	23	10	10	NUM
eurjchem-1675	50	24	mmol	mmol	NOUN
eurjchem-1675	50	25	)	)	PUNCT
eurjchem-1675	50	26	and	and	CCONJ
eurjchem-1675	50	27	ethyl	ethyl	PROPN
eurjchem-1675	50	28	cyanoacetate	cyanoacetate	NOUN
eurjchem-1675	50	29	(	(	PUNCT
eurjchem-1675	50	30	2	2	NUM
eurjchem-1675	50	31	)	)	PUNCT
eurjchem-1675	50	32	(	(	PUNCT
eurjchem-1675	50	33	1.1	1.1	NUM
eurjchem-1675	50	34	g	g	NOUN
eurjchem-1675	50	35	,	,	PUNCT
eurjchem-1675	50	36	10	10	NUM
eurjchem-1675	50	37	mmol	mmol	NOUN
eurjchem-1675	50	38	)	)	PUNCT
eurjchem-1675	50	39	was	be	AUX
eurjchem-1675	50	40	mixed	mix	VERB
eurjchem-1675	50	41	in	in	ADP
eurjchem-1675	50	42	a	a	DET
eurjchem-1675	50	43	process	process	NOUN
eurjchem-1675	50	44	vial	vial	NOUN
eurjchem-1675	50	45	.	.	PUNCT
eurjchem-1675	51	1	the	the	DET
eurjchem-1675	51	2	vial	vial	ADJ
eurjchem-1675	51	3	capped	cap	VERB
eurjchem-1675	51	4	properly	properly	ADV
eurjchem-1675	51	5	and	and	CCONJ
eurjchem-1675	51	6	irradiated	irradiate	VERB
eurjchem-1675	51	7	with	with	ADP
eurjchem-1675	51	8	microwave	microwave	NOUN
eurjchem-1675	51	9	underneath	underneath	ADP
eurjchem-1675	51	10	pressurized	pressurized	ADJ
eurjchem-1675	51	11	environments	environment	NOUN
eurjchem-1675	51	12	(	(	PUNCT
eurjchem-1675	51	13	17.2	17.2	NUM
eurjchem-1675	51	14	bar	bar	NOUN
eurjchem-1675	51	15	,	,	PUNCT
eurjchem-1675	51	16	180	180	NUM
eurjchem-1675	51	17	°	°	NOUN
eurjchem-1675	51	18	c	c	NOUN
eurjchem-1675	51	19	)	)	PUNCT
eurjchem-1675	51	20	on	on	ADP
eurjchem-1675	51	21	behalf	behalf	NOUN
eurjchem-1675	51	22	of	of	ADP
eurjchem-1675	51	23	5	5	NUM
eurjchem-1675	51	24	min	min	NOUN
eurjchem-1675	51	25	.	.	PUNCT
eurjchem-1675	52	1	the	the	DET
eurjchem-1675	52	2	reaction	reaction	NOUN
eurjchem-1675	52	3	mixture	mixture	NOUN
eurjchem-1675	52	4	was	be	AUX
eurjchem-1675	52	5	disappeared	disappear	VERB
eurjchem-1675	52	6	in	in	ADP
eurjchem-1675	52	7	vacuo	vacuo	NOUN
eurjchem-1675	52	8	and	and	CCONJ
eurjchem-1675	52	9	residual	residual	ADJ
eurjchem-1675	52	10	solid	solid	NOUN
eurjchem-1675	52	11	was	be	AUX
eurjchem-1675	52	12	occupied	occupy	VERB
eurjchem-1675	52	13	in	in	ADP
eurjchem-1675	52	14	ether	ether	NOUN
eurjchem-1675	52	15	,	,	PUNCT
eurjchem-1675	52	16	formerly	formerly	ADV
eurjchem-1675	52	17	together	together	ADV
eurjchem-1675	52	18	through	through	ADP
eurjchem-1675	52	19	filtration	filtration	NOUN
eurjchem-1675	52	20	wash	wash	NOUN
eurjchem-1675	52	21	away	away	ADV
eurjchem-1675	52	22	,	,	PUNCT
eurjchem-1675	52	23	dried	dry	VERB
eurjchem-1675	52	24	and	and	CCONJ
eurjchem-1675	52	25	finally	finally	ADV
eurjchem-1675	52	26	crystallized	crystallize	VERB
eurjchem-1675	52	27	from	from	ADP
eurjchem-1675	52	28	ethanol	ethanol	NOUN
eurjchem-1675	52	29	:	:	PUNCT
eurjchem-1675	52	30	dmf	dmf	PROPN
eurjchem-1675	52	31	(	(	PUNCT
eurjchem-1675	52	32	2:1	2:1	NUM
eurjchem-1675	52	33	,	,	PUNCT
eurjchem-1675	52	34	v	v	NOUN
eurjchem-1675	52	35	:	:	SYM
eurjchem-1675	52	36	v	v	NOUN
eurjchem-1675	52	37	)	)	PUNCT
eurjchem-1675	52	38	to	to	PART
eurjchem-1675	52	39	give	give	VERB
eurjchem-1675	52	40	white	white	ADJ
eurjchem-1675	52	41	crystal	crystal	NOUN
eurjchem-1675	52	42	of	of	ADP
eurjchem-1675	52	43	2	2	NUM
eurjchem-1675	52	44	-	-	PUNCT
eurjchem-1675	52	45	cyano	cyano	NOUN
eurjchem-1675	52	46	-	-	PUNCT
eurjchem-1675	52	47	n	n	CCONJ
eurjchem-1675	52	48	-	-	PUNCT
eurjchem-1675	52	49	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	52	50	(	(	PUNCT
eurjchem-1675	52	51	3	3	NUM
eurjchem-1675	52	52	)	)	PUNCT
eurjchem-1675	52	53	(	(	PUNCT
eurjchem-1675	52	54	scheme	scheme	NOUN
eurjchem-1675	52	55	1	1	NUM
eurjchem-1675	52	56	)	)	PUNCT
eurjchem-1675	53	1	[	[	X
eurjchem-1675	53	2	31,32	31,32	NUM
eurjchem-1675	53	3	]	]	PUNCT
eurjchem-1675	53	4	.	.	PUNCT
eurjchem-1675	54	1	color	color	NOUN
eurjchem-1675	54	2	:	:	PUNCT
eurjchem-1675	54	3	white	white	ADJ
eurjchem-1675	54	4	.	.	PUNCT
eurjchem-1675	55	1	yield	yield	NOUN
eurjchem-1675	55	2	:	:	PUNCT
eurjchem-1675	55	3	90	90	NUM
eurjchem-1675	55	4	%	%	NOUN
eurjchem-1675	55	5	.	.	PUNCT
eurjchem-1675	56	1	m.p	m.p	PROPN
eurjchem-1675	56	2	.	.	PROPN
eurjchem-1675	56	3	:	:	PUNCT
eurjchem-1675	57	1	126	126	NUM
eurjchem-1675	57	2	-	-	SYM
eurjchem-1675	57	3	128	128	NUM
eurjchem-1675	57	4	°	°	NUM
eurjchem-1675	57	5	c	c	NOUN
eurjchem-1675	57	6	.	.	PUNCT
eurjchem-1675	57	7	ft	ft	PROPN
eurjchem-1675	57	8	-	-	PUNCT
eurjchem-1675	57	9	ir	ir	PROPN
eurjchem-1675	57	10	(	(	PUNCT
eurjchem-1675	57	11	kbr	kbr	PROPN
eurjchem-1675	57	12	,	,	PUNCT
eurjchem-1675	57	13	ν	ν	PROPN
eurjchem-1675	57	14	,	,	PUNCT
eurjchem-1675	57	15	cm-1	cm-1	NUM
eurjchem-1675	57	16	):	):	PUNCT
eurjchem-1675	57	17	1662	1662	NUM
eurjchem-1675	57	18	(	(	PUNCT
eurjchem-1675	57	19	c	c	NOUN
eurjchem-1675	57	20	=	=	NOUN
eurjchem-1675	57	21	o	o	NOUN
eurjchem-1675	57	22	)	)	PUNCT
eurjchem-1675	57	23	,	,	PUNCT
eurjchem-1675	57	24	2204	2204	NUM
eurjchem-1675	57	25	(	(	PUNCT
eurjchem-1675	57	26	cn	cn	PROPN
eurjchem-1675	57	27	)	)	PUNCT
eurjchem-1675	57	28	,	,	PUNCT
eurjchem-1675	57	29	3278	3278	NUM
eurjchem-1675	57	30	(	(	PUNCT
eurjchem-1675	57	31	nh	nh	NOUN
eurjchem-1675	57	32	)	)	PUNCT
eurjchem-1675	57	33	.	.	PUNCT
eurjchem-1675	58	1	1h	1h	NUM
eurjchem-1675	58	2	nmr	nmr	NOUN
eurjchem-1675	58	3	(	(	PUNCT
eurjchem-1675	58	4	300	300	NUM
eurjchem-1675	58	5	mhz	mhz	NOUN
eurjchem-1675	58	6	,	,	PUNCT
eurjchem-1675	58	7	dmso	dmso	NOUN
eurjchem-1675	58	8	-	-	NOUN
eurjchem-1675	58	9	d6	d6	NOUN
eurjchem-1675	58	10	,	,	PUNCT
eurjchem-1675	58	11	δ	δ	PROPN
eurjchem-1675	58	12	,	,	PUNCT
eurjchem-1675	58	13	ppm	ppm	NOUN
eurjchem-1675	58	14	):	):	PUNCT
eurjchem-1675	58	15	1.40	1.40	NUM
eurjchem-1675	58	16	-	-	SYM
eurjchem-1675	58	17	1.70	1.70	NUM
eurjchem-1675	58	18	(	(	PUNCT
eurjchem-1675	58	19	m	m	PROPN
eurjchem-1675	58	20	,	,	PUNCT
eurjchem-1675	58	21	10h	10h	NUM
eurjchem-1675	58	22	,	,	PUNCT
eurjchem-1675	58	23	hc	hc	NOUN
eurjchem-1675	58	24	-	-	PUNCT
eurjchem-1675	58	25	aliphatic	aliphatic	NOUN
eurjchem-1675	58	26	)	)	PUNCT
eurjchem-1675	58	27	,	,	PUNCT
eurjchem-1675	58	28	3.30	3.30	NUM
eurjchem-1675	58	29	(	(	PUNCT
eurjchem-1675	58	30	s	s	PROPN
eurjchem-1675	58	31	,	,	PUNCT
eurjchem-1675	58	32	2h	2h	NUM
eurjchem-1675	58	33	,	,	PUNCT
eurjchem-1675	58	34	h2c	h2c	PROPN
eurjchem-1675	58	35	)	)	PUNCT
eurjchem-1675	58	36	,	,	PUNCT
eurjchem-1675	58	37	3.55	3.55	NUM
eurjchem-1675	58	38	(	(	PUNCT
eurjchem-1675	58	39	s	s	PROPN
eurjchem-1675	58	40	,	,	PUNCT
eurjchem-1675	58	41	1h	1h	NUM
eurjchem-1675	58	42	,	,	PUNCT
eurjchem-1675	58	43	hc	hc	PROPN
eurjchem-1675	58	44	)	)	PUNCT
eurjchem-1675	58	45	,	,	PUNCT
eurjchem-1675	58	46	8.08	8.08	NUM
eurjchem-1675	58	47	(	(	PUNCT
eurjchem-1675	58	48	s	s	PROPN
eurjchem-1675	58	49	,	,	PUNCT
eurjchem-1675	58	50	1h	1h	NUM
eurjchem-1675	58	51	,	,	PUNCT
eurjchem-1675	58	52	hn	hn	PROPN
eurjchem-1675	58	53	,	,	PUNCT
eurjchem-1675	58	54	d2o	d2o	NOUN
eurjchem-1675	58	55	-	-	ADJ
eurjchem-1675	58	56	exchangable	exchangable	ADJ
eurjchem-1675	58	57	)	)	PUNCT
eurjchem-1675	58	58	.	.	PUNCT
eurjchem-1675	59	1	13c	13c	NOUN
eurjchem-1675	59	2	nmr	nmr	NOUN
eurjchem-1675	59	3	(	(	PUNCT
eurjchem-1675	59	4	75	75	NUM
eurjchem-1675	59	5	mhz	mhz	NOUN
eurjchem-1675	59	6	,	,	PUNCT
eurjchem-1675	59	7	dmso	dmso	NOUN
eurjchem-1675	59	8	-	-	NOUN
eurjchem-1675	59	9	d6	d6	NOUN
eurjchem-1675	59	10	,	,	PUNCT
eurjchem-1675	59	11	δ	δ	PROPN
eurjchem-1675	59	12	,	,	PUNCT
eurjchem-1675	59	13	ppm	ppm	NUM
eurjchem-1675	59	14	):	):	PUNCT
eurjchem-1675	59	15	24.3	24.3	NUM
eurjchem-1675	59	16	(	(	PUNCT
eurjchem-1675	59	17	ch2	ch2	PROPN
eurjchem-1675	59	18	)	)	PUNCT
eurjchem-1675	59	19	,	,	PUNCT
eurjchem-1675	59	20	25.3	25.3	NUM
eurjchem-1675	59	21	(	(	PUNCT
eurjchem-1675	59	22	ch2	ch2	PROPN
eurjchem-1675	59	23	)	)	PUNCT
eurjchem-1675	59	24	,	,	PUNCT
eurjchem-1675	59	25	27.3	27.3	NUM
eurjchem-1675	59	26	(	(	PUNCT
eurjchem-1675	59	27	ch2	ch2	PROPN
eurjchem-1675	59	28	)	)	PUNCT
eurjchem-1675	59	29	,	,	PUNCT
eurjchem-1675	59	30	34.3	34.3	NUM
eurjchem-1675	59	31	(	(	PUNCT
eurjchem-1675	59	32	ch2	ch2	PROPN
eurjchem-1675	59	33	)	)	PUNCT
eurjchem-1675	59	34	,	,	PUNCT
eurjchem-1675	59	35	47.1	47.1	NUM
eurjchem-1675	59	36	(	(	PUNCT
eurjchem-1675	59	37	ch	ch	NOUN
eurjchem-1675	59	38	)	)	PUNCT
eurjchem-1675	59	39	,	,	PUNCT
eurjchem-1675	59	40	125.7(cn	125.7(cn	NUM
eurjchem-1675	59	41	)	)	PUNCT
eurjchem-1675	59	42	,	,	PUNCT
eurjchem-1675	59	43	171.2	171.2	NUM
eurjchem-1675	59	44	(	(	PUNCT
eurjchem-1675	59	45	c	c	NOUN
eurjchem-1675	59	46	=	=	NOUN
eurjchem-1675	59	47	o	o	NOUN
eurjchem-1675	59	48	)	)	PUNCT
eurjchem-1675	59	49	.	.	PUNCT
eurjchem-1675	60	1	ms	ms	NOUN
eurjchem-1675	60	2	(	(	PUNCT
eurjchem-1675	60	3	m	m	PROPN
eurjchem-1675	60	4	/	/	SYM
eurjchem-1675	60	5	z	z	NOUN
eurjchem-1675	60	6	(	(	PUNCT
eurjchem-1675	60	7	%	%	NOUN
eurjchem-1675	60	8	)	)	PUNCT
eurjchem-1675	60	9	):	):	PUNCT
eurjchem-1675	60	10	166	166	NUM
eurjchem-1675	60	11	(	(	PUNCT
eurjchem-1675	60	12	m+	m+	NUM
eurjchem-1675	60	13	,	,	PUNCT
eurjchem-1675	60	14	100.0	100.0	NUM
eurjchem-1675	60	15	)	)	PUNCT
eurjchem-1675	60	16	,	,	PUNCT
eurjchem-1675	60	17	123	123	NUM
eurjchem-1675	60	18	(	(	PUNCT
eurjchem-1675	60	19	75.3	75.3	NUM
eurjchem-1675	60	20	)	)	PUNCT
eurjchem-1675	60	21	,	,	PUNCT
eurjchem-1675	60	22	56	56	NUM
eurjchem-1675	60	23	(	(	PUNCT
eurjchem-1675	60	24	7.3	7.3	NUM
eurjchem-1675	60	25	)	)	PUNCT
eurjchem-1675	60	26	,	,	PUNCT
eurjchem-1675	60	27	82	82	NUM
eurjchem-1675	60	28	(	(	PUNCT
eurjchem-1675	60	29	86.9	86.9	NUM
eurjchem-1675	60	30	)	)	PUNCT
eurjchem-1675	60	31	.	.	PUNCT
eurjchem-1675	61	1	anal	anal	PROPN
eurjchem-1675	61	2	.	.	PUNCT
eurjchem-1675	61	3	calcd	calcd	NOUN
eurjchem-1675	61	4	.	.	PUNCT
eurjchem-1675	62	1	for	for	ADP
eurjchem-1675	62	2	c9h14n2o	c9h14n2o	NOUN
eurjchem-1675	62	3	:	:	PUNCT
eurjchem-1675	62	4	c	c	X
eurjchem-1675	62	5	,	,	PUNCT
eurjchem-1675	62	6	65.03	65.03	NUM
eurjchem-1675	62	7	;	;	PUNCT
eurjchem-1675	62	8	h	h	X
eurjchem-1675	62	9	,	,	PUNCT
eurjchem-1675	62	10	8.49	8.49	NUM
eurjchem-1675	62	11	;	;	PUNCT
eurjchem-1675	62	12	n	n	CCONJ
eurjchem-1675	62	13	,	,	PUNCT
eurjchem-1675	62	14	16.85	16.85	NUM
eurjchem-1675	62	15	.	.	PUNCT
eurjchem-1675	62	16	found	find	VERB
eurjchem-1675	62	17	:	:	PUNCT
eurjchem-1675	63	1	c	c	X
eurjchem-1675	63	2	,	,	PUNCT
eurjchem-1675	63	3	65.08	65.08	NUM
eurjchem-1675	63	4	;	;	PUNCT
eurjchem-1675	63	5	h	h	X
eurjchem-1675	63	6	,	,	PUNCT
eurjchem-1675	63	7	8.51	8.51	NUM
eurjchem-1675	63	8	;	;	PUNCT
eurjchem-1675	63	9	n	n	CCONJ
eurjchem-1675	63	10	,	,	PUNCT
eurjchem-1675	63	11	16.89	16.89	NUM
eurjchem-1675	63	12	%	%	NOUN
eurjchem-1675	63	13	.	.	PUNCT
eurjchem-1675	64	1	2.4	2.4	NUM
eurjchem-1675	64	2	.	.	PUNCT
eurjchem-1675	64	3	reactions	reaction	NOUN
eurjchem-1675	64	4	of	of	ADP
eurjchem-1675	64	5	2	2	NUM
eurjchem-1675	64	6	-	-	PUNCT
eurjchem-1675	64	7	cyano	cyano	NOUN
eurjchem-1675	64	8	-	-	PUNCT
eurjchem-1675	64	9	n	n	CCONJ
eurjchem-1675	64	10	-	-	PUNCT
eurjchem-1675	64	11	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	64	12	(	(	PUNCT
eurjchem-1675	64	13	3	3	NUM
eurjchem-1675	64	14	)	)	PUNCT
eurjchem-1675	64	15	with	with	ADP
eurjchem-1675	64	16	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1675	64	17	halides	halide	NOUN
eurjchem-1675	64	18	(	(	PUNCT
eurjchem-1675	64	19	4	4	NUM
eurjchem-1675	64	20	)	)	PUNCT
eurjchem-1675	64	21	general	general	ADJ
eurjchem-1675	64	22	procedure	procedure	NOUN
eurjchem-1675	64	23	:	:	PUNCT
eurjchem-1675	64	24	2	2	NUM
eurjchem-1675	64	25	-	-	PUNCT
eurjchem-1675	64	26	cyano	cyano	NOUN
eurjchem-1675	64	27	-	-	PUNCT
eurjchem-1675	64	28	n	n	CCONJ
eurjchem-1675	64	29	-	-	PUNCT
eurjchem-1675	64	30	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	64	31	(	(	PUNCT
eurjchem-1675	64	32	3	3	NUM
eurjchem-1675	64	33	)	)	PUNCT
eurjchem-1675	64	34	(	(	PUNCT
eurjchem-1675	64	35	0.166	0.166	NUM
eurjchem-1675	64	36	g	g	NOUN
eurjchem-1675	64	37	,	,	PUNCT
eurjchem-1675	64	38	1	1	NUM
eurjchem-1675	64	39	mmol	mmol	NOUN
eurjchem-1675	64	40	)	)	PUNCT
eurjchem-1675	64	41	was	be	AUX
eurjchem-1675	64	42	added	add	VERB
eurjchem-1675	64	43	to	to	ADP
eurjchem-1675	64	44	an	an	DET
eurjchem-1675	64	45	ethanolic	ethanolic	ADJ
eurjchem-1675	64	46	sodium	sodium	NOUN
eurjchem-1675	64	47	ethoxide	ethoxide	NOUN
eurjchem-1675	64	48	solution	solution	NOUN
eurjchem-1675	64	49	[	[	X
eurjchem-1675	64	50	prepared	prepare	VERB
eurjchem-1675	64	51	from	from	ADP
eurjchem-1675	64	52	sodium	sodium	NOUN
eurjchem-1675	64	53	metal	metal	NOUN
eurjchem-1675	64	54	(	(	PUNCT
eurjchem-1675	64	55	0.02	0.02	NUM
eurjchem-1675	64	56	g	g	NOUN
eurjchem-1675	64	57	,	,	PUNCT
eurjchem-1675	64	58	1	1	NUM
eurjchem-1675	64	59	mmol	mmol	NOUN
eurjchem-1675	64	60	)	)	PUNCT
eurjchem-1675	64	61	and	and	CCONJ
eurjchem-1675	64	62	absolute	absolute	ADJ
eurjchem-1675	64	63	ethanol	ethanol	NOUN
eurjchem-1675	64	64	(	(	PUNCT
eurjchem-1675	64	65	15	15	NUM
eurjchem-1675	64	66	ml	ml	NOUN
eurjchem-1675	64	67	)	)	PUNCT
eurjchem-1675	64	68	]	]	PUNCT
eurjchem-1675	64	69	with	with	ADP
eurjchem-1675	64	70	stirring	stirring	NOUN
eurjchem-1675	64	71	.	.	PUNCT
eurjchem-1675	65	1	after	after	ADP
eurjchem-1675	65	2	stirring	stir	VERB
eurjchem-1675	65	3	for	for	ADP
eurjchem-1675	65	4	20	20	NUM
eurjchem-1675	65	5	minutes	minute	NOUN
eurjchem-1675	65	6	,	,	PUNCT
eurjchem-1675	65	7	the	the	DET
eurjchem-1675	65	8	appropriate	appropriate	ADJ
eurjchem-1675	65	9	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1675	65	10	halides	halide	NOUN
eurjchem-1675	65	11	(	(	PUNCT
eurjchem-1675	65	12	4	4	NUM
eurjchem-1675	65	13	)	)	PUNCT
eurjchem-1675	65	14	(	(	PUNCT
eurjchem-1675	65	15	1	1	NUM
eurjchem-1675	65	16	mmol	mmol	NOUN
eurjchem-1675	65	17	)	)	PUNCT
eurjchem-1675	65	18	was	be	AUX
eurjchem-1675	65	19	added	add	VERB
eurjchem-1675	65	20	portion	portion	NOUN
eurjchem-1675	65	21	wise	wise	ADJ
eurjchem-1675	65	22	to	to	ADP
eurjchem-1675	65	23	the	the	DET
eurjchem-1675	65	24	resulting	result	VERB
eurjchem-1675	65	25	solution	solution	NOUN
eurjchem-1675	65	26	and	and	CCONJ
eurjchem-1675	65	27	the	the	DET
eurjchem-1675	65	28	reaction	reaction	NOUN
eurjchem-1675	65	29	mixture	mixture	NOUN
eurjchem-1675	65	30	was	be	AUX
eurjchem-1675	65	31	stirred	stir	VERB
eurjchem-1675	65	32	for	for	ADP
eurjchem-1675	65	33	further	further	ADJ
eurjchem-1675	65	34	12	12	NUM
eurjchem-1675	65	35	h	h	NOUN
eurjchem-1675	65	36	at	at	ADP
eurjchem-1675	65	37	room	room	NOUN
eurjchem-1675	65	38	temperature	temperature	NOUN
eurjchem-1675	65	39	.	.	PUNCT
eurjchem-1675	66	1	2018	2018	NUM
eurjchem-1675	66	2	–	–	PUNCT
eurjchem-1675	66	3	european	european	ADJ
eurjchem-1675	66	4	journal	journal	NOUN
eurjchem-1675	66	5	of	of	ADP
eurjchem-1675	66	6	chemistry	chemistry	NOUN
eurjchem-1675	66	7	–	–	PUNCT
eurjchem-1675	66	8	cc	cc	NOUN
eurjchem-1675	66	9	by	by	ADP
eurjchem-1675	66	10	nc	nc	PROPN
eurjchem-1675	66	11	–	–	PUNCT
eurjchem-1675	66	12	doi	doi	NOUN
eurjchem-1675	66	13	:	:	PUNCT
eurjchem-1675	66	14	10.5155	10.5155	NUM
eurjchem-1675	66	15	/	/	SYM
eurjchem-1675	66	16	eurjchem.9.1.30	eurjchem.9.1.30	NOUN
eurjchem-1675	66	17	-	-	SYM
eurjchem-1675	66	18	38.1675	38.1675	NUM
eurjchem-1675	66	19	32	32	NUM
eurjchem-1675	66	20	fahim	fahim	PROPN
eurjchem-1675	66	21	et	et	PROPN
eurjchem-1675	66	22	al	al	PROPN
eurjchem-1675	66	23	.	.	PUNCT
eurjchem-1675	66	24	/	/	SYM
eurjchem-1675	66	25	european	european	PROPN
eurjchem-1675	66	26	journal	journal	PROPN
eurjchem-1675	66	27	of	of	ADP
eurjchem-1675	66	28	chemistry	chemistry	NOUN
eurjchem-1675	66	29	9	9	NUM
eurjchem-1675	66	30	(	(	PUNCT
eurjchem-1675	66	31	1	1	NUM
eurjchem-1675	66	32	)	)	PUNCT
eurjchem-1675	66	33	(	(	PUNCT
eurjchem-1675	66	34	2018	2018	NUM
eurjchem-1675	66	35	)	)	PUNCT
eurjchem-1675	66	36	30	30	NUM
eurjchem-1675	66	37	-	-	SYM
eurjchem-1675	66	38	38	38	NUM
eurjchem-1675	66	39	n	n	NUM
eurjchem-1675	66	40	h	h	NOUN
eurjchem-1675	67	1	o	o	X
eurjchem-1675	67	2	koh	koh	PROPN
eurjchem-1675	67	3	phncs	phnc	VERB
eurjchem-1675	68	1	n	n	PRON
eurjchem-1675	68	2	h	h	NOUN
eurjchem-1675	69	1	o	o	NOUN
eurjchem-1675	69	2	c	c	NOUN
eurjchem-1675	70	1	n	n	PRON
eurjchem-1675	70	2	h	h	NOUN
eurjchem-1675	70	3	s	s	PROPN
eurjchem-1675	70	4	kph	kph	PROPN
eurjchem-1675	70	5	dil	dil	PROPN
eurjchem-1675	70	6	.	.	PUNCT
eurjchem-1675	71	1	hcl	hcl	PROPN
eurjchem-1675	71	2	nh	nh	PROPN
eurjchem-1675	72	1	o	o	NOUN
eurjchem-1675	72	2	c	c	NOUN
eurjchem-1675	73	1	hn	hn	INTJ
eurjchem-1675	73	2	sh	sh	INTJ
eurjchem-1675	73	3	ph	ph	PROPN
eurjchem-1675	73	4	3	3	NUM
eurjchem-1675	73	5	9	9	NUM
eurjchem-1675	73	6	10	10	NUM
eurjchem-1675	73	7	h	h	NOUN
eurjchem-1675	73	8	h	h	NOUN
eurjchem-1675	73	9	n	n	ADP
eurjchem-1675	73	10	n	n	CCONJ
eurjchem-1675	73	11	n	n	PROPN
eurjchem-1675	73	12	ar	ar	NOUN
eurjchem-1675	73	13	br	br	NOUN
eurjchem-1675	73	14	o	o	PROPN
eurjchem-1675	73	15	11a	11a	NOUN
eurjchem-1675	73	16	,	,	PUNCT
eurjchem-1675	73	17	b	b	PROPN
eurjchem-1675	73	18	nh	nh	NOUN
eurjchem-1675	74	1	o	o	PROPN
eurjchem-1675	74	2	c	c	PROPN
eurjchem-1675	74	3	nh	nh	PROPN
eurjchem-1675	74	4	s	s	PART
eurjchem-1675	74	5	ph	ph	PROPN
eurjchem-1675	74	6	o	o	PROPN
eurjchem-1675	74	7	ar	ar	PROPN
eurjchem-1675	74	8	12	12	NUM
eurjchem-1675	74	9	n	n	NUM
eurjchem-1675	74	10	h	h	NOUN
eurjchem-1675	74	11	o	o	NOUN
eurjchem-1675	74	12	13a	13a	PROPN
eurjchem-1675	74	13	,	,	PUNCT
eurjchem-1675	74	14	b	b	PROPN
eurjchem-1675	74	15	ar	ar	PROPN
eurjchem-1675	74	16	a	a	PROPN
eurjchem-1675	74	17	b	b	X
eurjchem-1675	74	18	c6h5	c6h5	PROPN
eurjchem-1675	74	19	4	4	NUM
eurjchem-1675	74	20	-	-	PUNCT
eurjchem-1675	74	21	brc6h4	brc6h4	NOUN
eurjchem-1675	74	22	etoh	etoh	PROPN
eurjchem-1675	74	23	h	h	PROPN
eurjchem-1675	75	1	h	h	NOUN
eurjchem-1675	75	2	s	s	PROPN
eurjchem-1675	75	3	phhn	phhn	PROPN
eurjchem-1675	75	4	ch2n	ch2n	PROPN
eurjchem-1675	75	5	13	13	NUM
eurjchem-1675	76	1	n	n	NOUN
eurjchem-1675	76	2	c2h5o	c2h5o	NUM
eurjchem-1675	76	3	br	br	NOUN
eurjchem-1675	77	1	o	o	NOUN
eurjchem-1675	77	2	nh	nh	INTJ
eurjchem-1675	77	3	o	o	X
eurjchem-1675	77	4	c	c	PROPN
eurjchem-1675	77	5	nh	nh	PROPN
eurjchem-1675	77	6	s	s	PART
eurjchem-1675	77	7	ph	ph	PROPN
eurjchem-1675	77	8	c2h5o	c2h5o	NUM
eurjchem-1675	77	9	cn	cn	NUM
eurjchem-1675	77	10	15	15	NUM
eurjchem-1675	77	11	o	o	NOUN
eurjchem-1675	77	12	h2o	h2o	PROPN
eurjchem-1675	77	13	16	16	NUM
eurjchem-1675	77	14	h	h	NOUN
eurjchem-1675	77	15	nh	nh	NOUN
eurjchem-1675	77	16	o	o	PROPN
eurjchem-1675	77	17	s	s	VERB
eurjchem-1675	77	18	nhph	nhph	PROPN
eurjchem-1675	77	19	cooc2h5	cooc2h5	NOUN
eurjchem-1675	77	20	h2n	h2n	PROPN
eurjchem-1675	77	21	d	d	PROPN
eurjchem-1675	77	22	,	,	PUNCT
eurjchem-1675	77	23	mw	mw	VERB
eurjchem-1675	77	24	14etoh	14etoh	PROPN
eurjchem-1675	77	25	d	d	PROPN
eurjchem-1675	77	26	,	,	PUNCT
eurjchem-1675	77	27	mw	mw	X
eurjchem-1675	77	28	h2o	h2o	PROPN
eurjchem-1675	77	29	h	h	NOUN
eurjchem-1675	77	30	h	h	NOUN
eurjchem-1675	77	31	scheme	scheme	NOUN
eurjchem-1675	77	32	2	2	NUM
eurjchem-1675	77	33	the	the	DET
eurjchem-1675	77	34	solid	solid	ADJ
eurjchem-1675	77	35	that	that	PRON
eurjchem-1675	77	36	formed	form	VERB
eurjchem-1675	77	37	was	be	AUX
eurjchem-1675	77	38	filtered	filter	VERB
eurjchem-1675	77	39	off	off	ADP
eurjchem-1675	77	40	,	,	PUNCT
eurjchem-1675	77	41	washed	wash	VERB
eurjchem-1675	77	42	with	with	ADP
eurjchem-1675	77	43	water	water	NOUN
eurjchem-1675	77	44	and	and	CCONJ
eurjchem-1675	77	45	dried	dry	VERB
eurjchem-1675	77	46	.	.	PUNCT
eurjchem-1675	78	1	recrystallization	recrystallization	NOUN
eurjchem-1675	78	2	from	from	ADP
eurjchem-1675	78	3	the	the	DET
eurjchem-1675	78	4	proper	proper	ADJ
eurjchem-1675	78	5	solvent	solvent	NOUN
eurjchem-1675	78	6	afforded	afford	VERB
eurjchem-1675	78	7	the	the	DET
eurjchem-1675	78	8	aminopyrazole	aminopyrazole	NOUN
eurjchem-1675	78	9	derivatives	derivative	NOUN
eurjchem-1675	78	10	(	(	PUNCT
eurjchem-1675	78	11	6	6	NUM
eurjchem-1675	78	12	)	)	PUNCT
eurjchem-1675	78	13	(	(	PUNCT
eurjchem-1675	78	14	scheme	scheme	NOUN
eurjchem-1675	78	15	1	1	NUM
eurjchem-1675	78	16	)	)	PUNCT
eurjchem-1675	78	17	.	.	PUNCT
eurjchem-1675	79	1	ethyl	ethyl	PROPN
eurjchem-1675	79	2	5	5	NUM
eurjchem-1675	79	3	-	-	PUNCT
eurjchem-1675	79	4	amino-4-(cyclohexylcarbamoyl)-1-(4	amino-4-(cyclohexylcarbamoyl)-1-(4	ADJ
eurjchem-1675	79	5	-	-	PUNCT
eurjchem-1675	79	6	methoxyphenyl)-1h	methoxyphenyl)-1h	NOUN
eurjchem-1675	79	7	-	-	PUNCT
eurjchem-1675	79	8	pyrazole-3	pyrazole-3	NOUN
eurjchem-1675	79	9	-	-	NOUN
eurjchem-1675	79	10	carboxylate	carboxylate	NOUN
eurjchem-1675	79	11	(	(	PUNCT
eurjchem-1675	79	12	6	6	NUM
eurjchem-1675	79	13	):	):	PUNCT
eurjchem-1675	79	14	color	color	NOUN
eurjchem-1675	79	15	:	:	PUNCT
eurjchem-1675	79	16	pale	pale	ADJ
eurjchem-1675	79	17	yellow	yellow	ADJ
eurjchem-1675	79	18	.	.	PUNCT
eurjchem-1675	80	1	yield	yield	NOUN
eurjchem-1675	80	2	:	:	PUNCT
eurjchem-1675	80	3	70	70	NUM
eurjchem-1675	80	4	%	%	NOUN
eurjchem-1675	80	5	.	.	PUNCT
eurjchem-1675	81	1	m.p	m.p	PROPN
eurjchem-1675	81	2	.	.	PROPN
eurjchem-1675	81	3	:	:	PUNCT
eurjchem-1675	82	1	>	>	PUNCT
eurjchem-1675	82	2	300	300	NUM
eurjchem-1675	82	3	°	°	SYM
eurjchem-1675	82	4	c	c	NOUN
eurjchem-1675	82	5	.	.	PUNCT
eurjchem-1675	82	6	ft	ft	PROPN
eurjchem-1675	82	7	-	-	PUNCT
eurjchem-1675	82	8	ir	ir	PROPN
eurjchem-1675	82	9	(	(	PUNCT
eurjchem-1675	82	10	kbr	kbr	PROPN
eurjchem-1675	82	11	,	,	PUNCT
eurjchem-1675	82	12	ν	ν	PROPN
eurjchem-1675	82	13	,	,	PUNCT
eurjchem-1675	82	14	cm-1	cm-1	NUM
eurjchem-1675	82	15	):	):	PUNCT
eurjchem-1675	82	16	1691	1691	NUM
eurjchem-1675	82	17	(	(	PUNCT
eurjchem-1675	82	18	c	c	NOUN
eurjchem-1675	82	19	=	=	NOUN
eurjchem-1675	82	20	o	o	NOUN
eurjchem-1675	82	21	)	)	PUNCT
eurjchem-1675	82	22	,	,	PUNCT
eurjchem-1675	82	23	3280	3280	NUM
eurjchem-1675	82	24	(	(	PUNCT
eurjchem-1675	82	25	nh2	nh2	PROPN
eurjchem-1675	82	26	)	)	PUNCT
eurjchem-1675	82	27	,	,	PUNCT
eurjchem-1675	82	28	3409	3409	NUM
eurjchem-1675	82	29	(	(	PUNCT
eurjchem-1675	82	30	nh	nh	NOUN
eurjchem-1675	82	31	)	)	PUNCT
eurjchem-1675	82	32	.	.	PUNCT
eurjchem-1675	83	1	1h	1h	NUM
eurjchem-1675	83	2	nmr	nmr	NOUN
eurjchem-1675	83	3	(	(	PUNCT
eurjchem-1675	83	4	300	300	NUM
eurjchem-1675	83	5	mhz	mhz	NOUN
eurjchem-1675	83	6	,	,	PUNCT
eurjchem-1675	83	7	dmso	dmso	NOUN
eurjchem-1675	83	8	-	-	NOUN
eurjchem-1675	83	9	d6	d6	NOUN
eurjchem-1675	83	10	,	,	PUNCT
eurjchem-1675	83	11	δ	δ	PROPN
eurjchem-1675	83	12	,	,	PUNCT
eurjchem-1675	83	13	ppm	ppm	NUM
eurjchem-1675	83	14	):	):	PUNCT
eurjchem-1675	83	15	1.391.49	1.391.49	NUM
eurjchem-1675	83	16	(	(	PUNCT
eurjchem-1675	83	17	m	m	PROPN
eurjchem-1675	83	18	,	,	PUNCT
eurjchem-1675	83	19	10h	10h	NUM
eurjchem-1675	83	20	,	,	PUNCT
eurjchem-1675	83	21	h2c	h2c	PROPN
eurjchem-1675	83	22	)	)	PUNCT
eurjchem-1675	83	23	,	,	PUNCT
eurjchem-1675	83	24	1.52	1.52	NUM
eurjchem-1675	83	25	(	(	PUNCT
eurjchem-1675	83	26	t	t	PROPN
eurjchem-1675	83	27	,	,	PUNCT
eurjchem-1675	83	28	3h	3h	NUM
eurjchem-1675	83	29	,	,	PUNCT
eurjchem-1675	83	30	h3c	h3c	PROPN
eurjchem-1675	83	31	)	)	PUNCT
eurjchem-1675	83	32	,	,	PUNCT
eurjchem-1675	83	33	3.54	3.54	NUM
eurjchem-1675	83	34	(	(	PUNCT
eurjchem-1675	83	35	s	s	PROPN
eurjchem-1675	83	36	,	,	PUNCT
eurjchem-1675	83	37	1h	1h	NUM
eurjchem-1675	83	38	,	,	PUNCT
eurjchem-1675	83	39	hc	hc	PROPN
eurjchem-1675	83	40	-	-	PUNCT
eurjchem-1675	83	41	nh	nh	NOUN
eurjchem-1675	83	42	)	)	PUNCT
eurjchem-1675	83	43	,	,	PUNCT
eurjchem-1675	83	44	3.73	3.73	NUM
eurjchem-1675	83	45	(	(	PUNCT
eurjchem-1675	83	46	s	s	PROPN
eurjchem-1675	83	47	,	,	PUNCT
eurjchem-1675	83	48	3h	3h	NUM
eurjchem-1675	83	49	,	,	PUNCT
eurjchem-1675	83	50	h3c	h3c	X
eurjchem-1675	83	51	)	)	PUNCT
eurjchem-1675	83	52	,	,	PUNCT
eurjchem-1675	83	53	4.29	4.29	NUM
eurjchem-1675	83	54	(	(	PUNCT
eurjchem-1675	83	55	q	q	NOUN
eurjchem-1675	83	56	,	,	PUNCT
eurjchem-1675	83	57	2h	2h	NUM
eurjchem-1675	83	58	,	,	PUNCT
eurjchem-1675	83	59	h2c	h2c	PROPN
eurjchem-1675	83	60	)	)	PUNCT
eurjchem-1675	83	61	,	,	PUNCT
eurjchem-1675	83	62	6.52	6.52	NUM
eurjchem-1675	83	63	(	(	PUNCT
eurjchem-1675	83	64	s	s	NOUN
eurjchem-1675	83	65	,	,	PUNCT
eurjchem-1675	83	66	2h	2h	NUM
eurjchem-1675	83	67	,	,	PUNCT
eurjchem-1675	83	68	h2n	h2n	PROPN
eurjchem-1675	83	69	d2oexchangable	d2oexchangable	ADJ
eurjchem-1675	83	70	)	)	PUNCT
eurjchem-1675	83	71	,	,	PUNCT
eurjchem-1675	83	72	6.80	6.80	NUM
eurjchem-1675	83	73	(	(	PUNCT
eurjchem-1675	83	74	s	s	NOUN
eurjchem-1675	83	75	,	,	PUNCT
eurjchem-1675	83	76	2h	2h	NUM
eurjchem-1675	83	77	,	,	PUNCT
eurjchem-1675	83	78	hc	hc	NOUN
eurjchem-1675	83	79	)	)	PUNCT
eurjchem-1675	83	80	,	,	PUNCT
eurjchem-1675	83	81	7.20	7.20	NUM
eurjchem-1675	83	82	(	(	PUNCT
eurjchem-1675	83	83	s	s	PROPN
eurjchem-1675	83	84	,	,	PUNCT
eurjchem-1675	83	85	2h	2h	NUM
eurjchem-1675	83	86	,	,	PUNCT
eurjchem-1675	83	87	hc	hc	NOUN
eurjchem-1675	83	88	)	)	PUNCT
eurjchem-1675	83	89	,	,	PUNCT
eurjchem-1675	83	90	8.05	8.05	NUM
eurjchem-1675	83	91	(	(	PUNCT
eurjchem-1675	83	92	s	s	PROPN
eurjchem-1675	83	93	,	,	PUNCT
eurjchem-1675	83	94	1h	1h	NUM
eurjchem-1675	83	95	,	,	PUNCT
eurjchem-1675	83	96	hn	hn	PROPN
eurjchem-1675	83	97	d2o	d2o	NOUN
eurjchem-1675	83	98	-	-	PUNCT
eurjchem-1675	83	99	exchangable	exchangable	ADJ
eurjchem-1675	83	100	)	)	PUNCT
eurjchem-1675	83	101	.	.	PUNCT
eurjchem-1675	84	1	13c	13c	NOUN
eurjchem-1675	84	2	nmr	nmr	NOUN
eurjchem-1675	84	3	(	(	PUNCT
eurjchem-1675	84	4	75	75	NUM
eurjchem-1675	84	5	mhz	mhz	NOUN
eurjchem-1675	84	6	,	,	PUNCT
eurjchem-1675	84	7	dmso	dmso	NOUN
eurjchem-1675	84	8	,	,	PUNCT
eurjchem-1675	84	9	δ	δ	PROPN
eurjchem-1675	84	10	,	,	PUNCT
eurjchem-1675	84	11	ppm	ppm	NUM
eurjchem-1675	84	12	):	):	PUNCT
eurjchem-1675	84	13	15.3	15.3	NUM
eurjchem-1675	84	14	(	(	PUNCT
eurjchem-1675	84	15	ch3	ch3	PROPN
eurjchem-1675	84	16	)	)	PUNCT
eurjchem-1675	84	17	,	,	PUNCT
eurjchem-1675	84	18	25.3	25.3	NUM
eurjchem-1675	84	19	(	(	PUNCT
eurjchem-1675	84	20	ch2	ch2	PROPN
eurjchem-1675	84	21	)	)	PUNCT
eurjchem-1675	84	22	,	,	PUNCT
eurjchem-1675	84	23	28.2	28.2	NUM
eurjchem-1675	84	24	(	(	PUNCT
eurjchem-1675	84	25	ch2	ch2	PROPN
eurjchem-1675	84	26	)	)	PUNCT
eurjchem-1675	84	27	,	,	PUNCT
eurjchem-1675	84	28	34.3	34.3	NUM
eurjchem-1675	84	29	(	(	PUNCT
eurjchem-1675	84	30	ch2	ch2	PROPN
eurjchem-1675	84	31	)	)	PUNCT
eurjchem-1675	84	32	,	,	PUNCT
eurjchem-1675	84	33	47.1	47.1	NUM
eurjchem-1675	84	34	(	(	PUNCT
eurjchem-1675	84	35	ch	ch	NOUN
eurjchem-1675	84	36	)	)	PUNCT
eurjchem-1675	84	37	,	,	PUNCT
eurjchem-1675	84	38	54.3	54.3	NUM
eurjchem-1675	84	39	(	(	PUNCT
eurjchem-1675	84	40	och3	och3	ADJ
eurjchem-1675	84	41	)	)	PUNCT
eurjchem-1675	84	42	,	,	PUNCT
eurjchem-1675	84	43	62.8	62.8	NUM
eurjchem-1675	84	44	(	(	PUNCT
eurjchem-1675	84	45	ch2	ch2	PROPN
eurjchem-1675	84	46	)	)	PUNCT
eurjchem-1675	84	47	,	,	PUNCT
eurjchem-1675	84	48	96.2	96.2	NUM
eurjchem-1675	84	49	(	(	PUNCT
eurjchem-1675	84	50	ch	ch	NOUN
eurjchem-1675	84	51	)	)	PUNCT
eurjchem-1675	84	52	,	,	PUNCT
eurjchem-1675	84	53	115.7	115.7	NUM
eurjchem-1675	84	54	(	(	PUNCT
eurjchem-1675	84	55	ch	ch	NOUN
eurjchem-1675	84	56	)	)	PUNCT
eurjchem-1675	84	57	,	,	PUNCT
eurjchem-1675	84	58	124.1	124.1	NUM
eurjchem-1675	84	59	(	(	PUNCT
eurjchem-1675	84	60	ch	ch	NOUN
eurjchem-1675	84	61	)	)	PUNCT
eurjchem-1675	84	62	,	,	PUNCT
eurjchem-1675	84	63	133.2	133.2	NUM
eurjchem-1675	84	64	(	(	PUNCT
eurjchem-1675	84	65	ch	ch	NOUN
eurjchem-1675	84	66	)	)	PUNCT
eurjchem-1675	84	67	,	,	PUNCT
eurjchem-1675	84	68	142.3	142.3	NUM
eurjchem-1675	84	69	(	(	PUNCT
eurjchem-1675	84	70	ch=	ch=	PROPN
eurjchem-1675	84	71	)	)	PUNCT
eurjchem-1675	84	72	,	,	PUNCT
eurjchem-1675	84	73	148.3	148.3	NUM
eurjchem-1675	84	74	(	(	PUNCT
eurjchem-1675	84	75	ch	ch	NOUN
eurjchem-1675	84	76	)	)	PUNCT
eurjchem-1675	84	77	,	,	PUNCT
eurjchem-1675	84	78	162	162	NUM
eurjchem-1675	84	79	(	(	PUNCT
eurjchem-1675	84	80	c	c	NOUN
eurjchem-1675	84	81	=	=	NOUN
eurjchem-1675	84	82	o	o	NOUN
eurjchem-1675	84	83	)	)	PUNCT
eurjchem-1675	84	84	,	,	PUNCT
eurjchem-1675	84	85	167	167	NUM
eurjchem-1675	84	86	(	(	PUNCT
eurjchem-1675	84	87	c	c	NOUN
eurjchem-1675	84	88	=	=	NOUN
eurjchem-1675	84	89	o	o	NOUN
eurjchem-1675	84	90	)	)	PUNCT
eurjchem-1675	84	91	.	.	PUNCT
eurjchem-1675	85	1	ms	ms	NOUN
eurjchem-1675	85	2	(	(	PUNCT
eurjchem-1675	85	3	ei	ei	PROPN
eurjchem-1675	85	4	,	,	PUNCT
eurjchem-1675	85	5	m	m	PROPN
eurjchem-1675	85	6	/	/	SYM
eurjchem-1675	85	7	z	z	PROPN
eurjchem-1675	85	8	(	(	PUNCT
eurjchem-1675	85	9	%	%	NOUN
eurjchem-1675	85	10	)	)	PUNCT
eurjchem-1675	85	11	):	):	PUNCT
eurjchem-1675	85	12	386	386	NUM
eurjchem-1675	85	13	(	(	PUNCT
eurjchem-1675	85	14	m+	m+	NUM
eurjchem-1675	85	15	,	,	PUNCT
eurjchem-1675	85	16	100.0	100.0	NUM
eurjchem-1675	85	17	)	)	PUNCT
eurjchem-1675	85	18	,	,	PUNCT
eurjchem-1675	85	19	370	370	NUM
eurjchem-1675	85	20	(	(	PUNCT
eurjchem-1675	85	21	21.0	21.0	NUM
eurjchem-1675	85	22	)	)	PUNCT
eurjchem-1675	85	23	,	,	PUNCT
eurjchem-1675	85	24	315	315	NUM
eurjchem-1675	85	25	(	(	PUNCT
eurjchem-1675	85	26	45.4	45.4	NUM
eurjchem-1675	85	27	)	)	PUNCT
eurjchem-1675	85	28	.	.	PUNCT
eurjchem-1675	86	1	anal	anal	PROPN
eurjchem-1675	86	2	.	.	PUNCT
eurjchem-1675	86	3	calcd	calcd	NOUN
eurjchem-1675	86	4	.	.	PUNCT
eurjchem-1675	87	1	for	for	ADP
eurjchem-1675	87	2	c20h26n4o4	c20h26n4o4	PROPN
eurjchem-1675	87	3	:	:	PUNCT
eurjchem-1675	87	4	c	c	X
eurjchem-1675	87	5	,	,	PUNCT
eurjchem-1675	87	6	62.16	62.16	NUM
eurjchem-1675	87	7	;	;	PUNCT
eurjchem-1675	87	8	h	h	NOUN
eurjchem-1675	87	9	,	,	PUNCT
eurjchem-1675	87	10	6.78	6.78	NUM
eurjchem-1675	87	11	;	;	PUNCT
eurjchem-1675	87	12	n	n	CCONJ
eurjchem-1675	87	13	,	,	PUNCT
eurjchem-1675	87	14	14.50	14.50	NUM
eurjchem-1675	87	15	.	.	PUNCT
eurjchem-1675	87	16	found	find	VERB
eurjchem-1675	87	17	:	:	PUNCT
eurjchem-1675	88	1	c	c	X
eurjchem-1675	88	2	,	,	PUNCT
eurjchem-1675	88	3	62.22	62.22	NUM
eurjchem-1675	88	4	;	;	PUNCT
eurjchem-1675	88	5	h	h	NOUN
eurjchem-1675	88	6	,	,	PUNCT
eurjchem-1675	88	7	6.82	6.82	NUM
eurjchem-1675	88	8	;	;	PUNCT
eurjchem-1675	88	9	n	n	CCONJ
eurjchem-1675	88	10	,	,	PUNCT
eurjchem-1675	88	11	14.53	14.53	NUM
eurjchem-1675	88	12	%	%	NOUN
eurjchem-1675	88	13	.	.	PUNCT
eurjchem-1675	89	1	2.5	2.5	NUM
eurjchem-1675	89	2	.	.	PUNCT
eurjchem-1675	90	1	reaction	reaction	NOUN
eurjchem-1675	90	2	of	of	ADP
eurjchem-1675	90	3	2	2	NUM
eurjchem-1675	90	4	-	-	PUNCT
eurjchem-1675	90	5	cyano	cyano	NOUN
eurjchem-1675	90	6	-	-	PUNCT
eurjchem-1675	90	7	n	n	CCONJ
eurjchem-1675	90	8	-	-	PUNCT
eurjchem-1675	90	9	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	90	10	(	(	PUNCT
eurjchem-1675	90	11	3	3	NUM
eurjchem-1675	90	12	)	)	PUNCT
eurjchem-1675	90	13	with	with	ADP
eurjchem-1675	90	14	phenyl	phenyl	NOUN
eurjchem-1675	90	15	isothiocyanate	isothiocyanate	NOUN
eurjchem-1675	90	16	general	general	ADJ
eurjchem-1675	90	17	procedure	procedure	NOUN
eurjchem-1675	90	18	:	:	PUNCT
eurjchem-1675	90	19	potassium	potassium	NOUN
eurjchem-1675	90	20	hydroxide	hydroxide	NOUN
eurjchem-1675	90	21	solution	solution	NOUN
eurjchem-1675	90	22	(	(	PUNCT
eurjchem-1675	90	23	0.11	0.11	NUM
eurjchem-1675	90	24	g	g	NOUN
eurjchem-1675	90	25	,	,	PUNCT
eurjchem-1675	90	26	2	2	NUM
eurjchem-1675	90	27	mmol	mmol	NOUN
eurjchem-1675	90	28	)	)	PUNCT
eurjchem-1675	90	29	in	in	ADP
eurjchem-1675	90	30	dimethyl	dimethyl	PROPN
eurjchem-1675	90	31	formamide	formamide	ADV
eurjchem-1675	90	32	(	(	PUNCT
eurjchem-1675	90	33	20	20	NUM
eurjchem-1675	90	34	ml	ml	NOUN
eurjchem-1675	90	35	)	)	PUNCT
eurjchem-1675	90	36	was	be	AUX
eurjchem-1675	90	37	auxiliary	auxiliary	ADJ
eurjchem-1675	90	38	to	to	ADP
eurjchem-1675	90	39	2cyano	2cyano	NUM
eurjchem-1675	90	40	-	-	PUNCT
eurjchem-1675	90	41	n	n	CCONJ
eurjchem-1675	90	42	-	-	PUNCT
eurjchem-1675	90	43	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	90	44	(	(	PUNCT
eurjchem-1675	90	45	3	3	NUM
eurjchem-1675	90	46	)	)	PUNCT
eurjchem-1675	90	47	(	(	PUNCT
eurjchem-1675	90	48	0.332	0.332	NUM
eurjchem-1675	90	49	g	g	NOUN
eurjchem-1675	90	50	,	,	PUNCT
eurjchem-1675	90	51	2	2	NUM
eurjchem-1675	90	52	mmol	mmol	NOUN
eurjchem-1675	90	53	)	)	PUNCT
eurjchem-1675	90	54	.	.	PUNCT
eurjchem-1675	91	1	afterward	afterward	ADV
eurjchem-1675	91	2	stirring	stir	VERB
eurjchem-1675	91	3	for	for	ADP
eurjchem-1675	91	4	30	30	NUM
eurjchem-1675	91	5	min	min	NOUN
eurjchem-1675	91	6	,	,	PUNCT
eurjchem-1675	91	7	phenyl	phenyl	NOUN
eurjchem-1675	91	8	-	-	PUNCT
eurjchem-1675	91	9	isothiocyanate	isothiocyanate	NOUN
eurjchem-1675	91	10	(	(	PUNCT
eurjchem-1675	91	11	0.24	0.24	NUM
eurjchem-1675	91	12	ml	ml	NOUN
eurjchem-1675	91	13	,	,	PUNCT
eurjchem-1675	91	14	2	2	NUM
eurjchem-1675	91	15	mmol	mmol	NOUN
eurjchem-1675	91	16	)	)	PUNCT
eurjchem-1675	91	17	was	be	AUX
eurjchem-1675	91	18	further	further	ADJ
eurjchem-1675	91	19	to	to	ADP
eurjchem-1675	91	20	the	the	DET
eurjchem-1675	91	21	subsequent	subsequent	ADJ
eurjchem-1675	91	22	mixture	mixture	NOUN
eurjchem-1675	91	23	and	and	CCONJ
eurjchem-1675	91	24	stirring	stirring	NOUN
eurjchem-1675	91	25	was	be	AUX
eurjchem-1675	91	26	sustained	sustain	VERB
eurjchem-1675	91	27	for	for	ADP
eurjchem-1675	91	28	6	6	NUM
eurjchem-1675	91	29	h	h	NOUN
eurjchem-1675	91	30	,	,	PUNCT
eurjchem-1675	91	31	formerly	formerly	ADV
eurjchem-1675	91	32	decant	decant	VERB
eurjchem-1675	91	33	over	over	ADP
eurjchem-1675	91	34	crushed	crushed	ADJ
eurjchem-1675	91	35	ice	ice	NOUN
eurjchem-1675	91	36	containing	contain	VERB
eurjchem-1675	91	37	hydrochloric	hydrochloric	ADJ
eurjchem-1675	91	38	acid	acid	NOUN
eurjchem-1675	91	39	.	.	PUNCT
eurjchem-1675	92	1	the	the	DET
eurjchem-1675	92	2	formed	form	VERB
eurjchem-1675	92	3	product	product	NOUN
eurjchem-1675	92	4	was	be	AUX
eurjchem-1675	92	5	filtered	filter	VERB
eurjchem-1675	92	6	off	off	ADP
eurjchem-1675	92	7	,	,	PUNCT
eurjchem-1675	92	8	washed	wash	VERB
eurjchem-1675	92	9	with	with	ADP
eurjchem-1675	92	10	water	water	NOUN
eurjchem-1675	92	11	,	,	PUNCT
eurjchem-1675	92	12	dried	dry	VERB
eurjchem-1675	92	13	and	and	CCONJ
eurjchem-1675	92	14	finally	finally	ADV
eurjchem-1675	92	15	recrystallized	recrystallize	VERB
eurjchem-1675	92	16	from	from	ADP
eurjchem-1675	92	17	the	the	DET
eurjchem-1675	92	18	proper	proper	ADJ
eurjchem-1675	92	19	solvent	solvent	NOUN
eurjchem-1675	92	20	(	(	PUNCT
eurjchem-1675	92	21	scheme	scheme	NOUN
eurjchem-1675	92	22	2	2	NUM
eurjchem-1675	92	23	)	)	PUNCT
eurjchem-1675	92	24	.	.	PUNCT
eurjchem-1675	93	1	2	2	NUM
eurjchem-1675	93	2	-	-	PUNCT
eurjchem-1675	93	3	cyano	cyano	NOUN
eurjchem-1675	93	4	-	-	PUNCT
eurjchem-1675	93	5	n	n	CCONJ
eurjchem-1675	93	6	-	-	PUNCT
eurjchem-1675	93	7	cyclohexyl-3	cyclohexyl-3	NUM
eurjchem-1675	93	8	-	-	PUNCT
eurjchem-1675	93	9	mercapto-3-(phenylamino)acrylamide	mercapto-3-(phenylamino)acrylamide	NOUN
eurjchem-1675	93	10	(	(	PUNCT
eurjchem-1675	93	11	10	10	NUM
eurjchem-1675	93	12	):	):	PUNCT
eurjchem-1675	93	13	color	color	NOUN
eurjchem-1675	93	14	:	:	PUNCT
eurjchem-1675	93	15	yellow	yellow	ADJ
eurjchem-1675	93	16	.	.	PUNCT
eurjchem-1675	94	1	yield	yield	NOUN
eurjchem-1675	94	2	:	:	PUNCT
eurjchem-1675	94	3	80	80	NUM
eurjchem-1675	94	4	%	%	NOUN
eurjchem-1675	94	5	.	.	PUNCT
eurjchem-1675	95	1	m.p	m.p	PROPN
eurjchem-1675	95	2	.	.	PROPN
eurjchem-1675	95	3	:	:	PUNCT
eurjchem-1675	96	1	152	152	NUM
eurjchem-1675	96	2	-	-	SYM
eurjchem-1675	96	3	154	154	NUM
eurjchem-1675	96	4	°	°	PROPN
eurjchem-1675	96	5	c	c	NOUN
eurjchem-1675	96	6	.	.	PUNCT
eurjchem-1675	96	7	ft	ft	PROPN
eurjchem-1675	96	8	-	-	PUNCT
eurjchem-1675	96	9	ir	ir	PROPN
eurjchem-1675	96	10	(	(	PUNCT
eurjchem-1675	96	11	kbr	kbr	PROPN
eurjchem-1675	96	12	,	,	PUNCT
eurjchem-1675	96	13	ν	ν	PROPN
eurjchem-1675	96	14	,	,	PUNCT
eurjchem-1675	96	15	cm-1	cm-1	NUM
eurjchem-1675	96	16	):	):	PUNCT
eurjchem-1675	96	17	1670	1670	NUM
eurjchem-1675	96	18	(	(	PUNCT
eurjchem-1675	96	19	c	c	NOUN
eurjchem-1675	96	20	=	=	NOUN
eurjchem-1675	96	21	o	o	NOUN
eurjchem-1675	96	22	)	)	PUNCT
eurjchem-1675	96	23	,	,	PUNCT
eurjchem-1675	96	24	2250	2250	NUM
eurjchem-1675	96	25	(	(	PUNCT
eurjchem-1675	96	26	c	c	NOUN
eurjchem-1675	96	27	=	=	SYM
eurjchem-1675	96	28	n	n	NUM
eurjchem-1675	96	29	)	)	PUNCT
eurjchem-1675	96	30	,	,	PUNCT
eurjchem-1675	96	31	3266	3266	NUM
eurjchem-1675	96	32	(	(	PUNCT
eurjchem-1675	96	33	nh	nh	NOUN
eurjchem-1675	96	34	)	)	PUNCT
eurjchem-1675	96	35	.	.	PUNCT
eurjchem-1675	96	36	1h	1h	NUM
eurjchem-1675	96	37	nmr	nmr	NOUN
eurjchem-1675	96	38	(	(	PUNCT
eurjchem-1675	96	39	300	300	NUM
eurjchem-1675	96	40	mhz	mhz	NOUN
eurjchem-1675	96	41	,	,	PUNCT
eurjchem-1675	96	42	dmso	dmso	NOUN
eurjchem-1675	96	43	-	-	NOUN
eurjchem-1675	96	44	d6	d6	NOUN
eurjchem-1675	96	45	,	,	PUNCT
eurjchem-1675	96	46	δ	δ	PROPN
eurjchem-1675	96	47	,	,	PUNCT
eurjchem-1675	96	48	ppm	ppm	NUM
eurjchem-1675	96	49	):	):	PUNCT
eurjchem-1675	96	50	1.37	1.37	NUM
eurjchem-1675	96	51	-	-	SYM
eurjchem-1675	96	52	1.52	1.52	NUM
eurjchem-1675	96	53	(	(	PUNCT
eurjchem-1675	96	54	m	m	PROPN
eurjchem-1675	96	55	,	,	PUNCT
eurjchem-1675	96	56	10h	10h	NUM
eurjchem-1675	96	57	,	,	PUNCT
eurjchem-1675	96	58	h2c	h2c	PROPN
eurjchem-1675	96	59	)	)	PUNCT
eurjchem-1675	96	60	,	,	PUNCT
eurjchem-1675	96	61	3.55	3.55	NUM
eurjchem-1675	96	62	(	(	PUNCT
eurjchem-1675	96	63	s	s	PROPN
eurjchem-1675	96	64	,	,	PUNCT
eurjchem-1675	96	65	1h	1h	NUM
eurjchem-1675	96	66	,	,	PUNCT
eurjchem-1675	96	67	hc	hc	PROPN
eurjchem-1675	96	68	-	-	PUNCT
eurjchem-1675	96	69	nh	nh	NOUN
eurjchem-1675	96	70	)	)	PUNCT
eurjchem-1675	96	71	,	,	PUNCT
eurjchem-1675	96	72	7.33	7.33	NUM
eurjchem-1675	96	73	-	-	SYM
eurjchem-1675	96	74	7.74	7.74	NUM
eurjchem-1675	96	75	(	(	PUNCT
eurjchem-1675	96	76	m	m	PROPN
eurjchem-1675	96	77	,	,	PUNCT
eurjchem-1675	96	78	5h	5h	NUM
eurjchem-1675	96	79	,	,	PUNCT
eurjchem-1675	96	80	ar	ar	NOUN
eurjchem-1675	96	81	-	-	NOUN
eurjchem-1675	96	82	h	h	NOUN
eurjchem-1675	96	83	)	)	PUNCT
eurjchem-1675	96	84	,	,	PUNCT
eurjchem-1675	96	85	7.91	7.91	NUM
eurjchem-1675	96	86	(	(	PUNCT
eurjchem-1675	96	87	s	s	PROPN
eurjchem-1675	96	88	,	,	PUNCT
eurjchem-1675	96	89	1h	1h	NUM
eurjchem-1675	96	90	,	,	PUNCT
eurjchem-1675	96	91	hc	hc	PROPN
eurjchem-1675	96	92	)	)	PUNCT
eurjchem-1675	96	93	,	,	PUNCT
eurjchem-1675	96	94	10.88	10.88	NUM
eurjchem-1675	96	95	(	(	PUNCT
eurjchem-1675	96	96	s	s	PROPN
eurjchem-1675	96	97	,	,	PUNCT
eurjchem-1675	96	98	1h	1h	NUM
eurjchem-1675	96	99	,	,	PUNCT
eurjchem-1675	96	100	hn	hn	PROPN
eurjchem-1675	96	101	d2o	d2o	NOUN
eurjchem-1675	96	102	-	-	PUNCT
eurjchem-1675	96	103	exchangable	exchangable	ADJ
eurjchem-1675	96	104	)	)	PUNCT
eurjchem-1675	96	105	,	,	PUNCT
eurjchem-1675	96	106	11.83	11.83	NUM
eurjchem-1675	96	107	(	(	PUNCT
eurjchem-1675	96	108	s	s	PROPN
eurjchem-1675	96	109	,	,	PUNCT
eurjchem-1675	96	110	1h	1h	NUM
eurjchem-1675	96	111	,	,	PUNCT
eurjchem-1675	96	112	hs	hs	X
eurjchem-1675	96	113	d2o	d2o	NOUN
eurjchem-1675	96	114	-	-	PUNCT
eurjchem-1675	96	115	exchangable	exchangable	ADJ
eurjchem-1675	96	116	)	)	PUNCT
eurjchem-1675	96	117	.	.	PUNCT
eurjchem-1675	97	1	13c	13c	NOUN
eurjchem-1675	97	2	nmr	nmr	NOUN
eurjchem-1675	97	3	(	(	PUNCT
eurjchem-1675	97	4	75	75	NUM
eurjchem-1675	97	5	mhz	mhz	NOUN
eurjchem-1675	97	6	,	,	PUNCT
eurjchem-1675	97	7	dmso	dmso	NOUN
eurjchem-1675	97	8	-	-	NOUN
eurjchem-1675	97	9	d6	d6	NOUN
eurjchem-1675	97	10	,	,	PUNCT
eurjchem-1675	97	11	δ	δ	PROPN
eurjchem-1675	97	12	,	,	PUNCT
eurjchem-1675	97	13	ppm	ppm	NUM
eurjchem-1675	97	14	):	):	PUNCT
eurjchem-1675	97	15	23.2	23.2	NUM
eurjchem-1675	97	16	(	(	PUNCT
eurjchem-1675	97	17	ch2	ch2	PROPN
eurjchem-1675	97	18	)	)	PUNCT
eurjchem-1675	97	19	,	,	PUNCT
eurjchem-1675	97	20	27.3	27.3	NUM
eurjchem-1675	97	21	(	(	PUNCT
eurjchem-1675	97	22	ch2	ch2	PROPN
eurjchem-1675	97	23	)	)	PUNCT
eurjchem-1675	97	24	,	,	PUNCT
eurjchem-1675	97	25	32.3	32.3	NUM
eurjchem-1675	97	26	(	(	PUNCT
eurjchem-1675	97	27	ch2	ch2	PROPN
eurjchem-1675	97	28	)	)	PUNCT
eurjchem-1675	97	29	,	,	PUNCT
eurjchem-1675	97	30	43.5	43.5	NUM
eurjchem-1675	97	31	(	(	PUNCT
eurjchem-1675	97	32	ch	ch	NOUN
eurjchem-1675	97	33	)	)	PUNCT
eurjchem-1675	97	34	,	,	PUNCT
eurjchem-1675	97	35	88.0	88.0	NUM
eurjchem-1675	97	36	(	(	PUNCT
eurjchem-1675	97	37	ch	ch	NOUN
eurjchem-1675	97	38	)	)	PUNCT
eurjchem-1675	97	39	,	,	PUNCT
eurjchem-1675	97	40	115.0	115.0	NUM
eurjchem-1675	97	41	(	(	PUNCT
eurjchem-1675	97	42	ch	ch	NOUN
eurjchem-1675	97	43	)	)	PUNCT
eurjchem-1675	97	44	,	,	PUNCT
eurjchem-1675	97	45	118.3	118.3	NUM
eurjchem-1675	97	46	(	(	PUNCT
eurjchem-1675	97	47	ch	ch	NOUN
eurjchem-1675	97	48	)	)	PUNCT
eurjchem-1675	97	49	,	,	PUNCT
eurjchem-1675	97	50	142.0	142.0	NUM
eurjchem-1675	97	51	(	(	PUNCT
eurjchem-1675	97	52	ch	ch	NOUN
eurjchem-1675	97	53	)	)	PUNCT
eurjchem-1675	97	54	,	,	PUNCT
eurjchem-1675	97	55	96.2	96.2	NUM
eurjchem-1675	97	56	(	(	PUNCT
eurjchem-1675	97	57	ch	ch	NOUN
eurjchem-1675	97	58	)	)	PUNCT
eurjchem-1675	97	59	,	,	PUNCT
eurjchem-1675	97	60	115.7	115.7	NUM
eurjchem-1675	97	61	(	(	PUNCT
eurjchem-1675	97	62	cn	cn	PROPN
eurjchem-1675	97	63	)	)	PUNCT
eurjchem-1675	97	64	,	,	PUNCT
eurjchem-1675	97	65	124.1	124.1	NUM
eurjchem-1675	97	66	(	(	PUNCT
eurjchem-1675	97	67	ch	ch	NOUN
eurjchem-1675	97	68	)	)	PUNCT
eurjchem-1675	97	69	,	,	PUNCT
eurjchem-1675	97	70	133.2	133.2	NUM
eurjchem-1675	97	71	(	(	PUNCT
eurjchem-1675	97	72	ch	ch	NOUN
eurjchem-1675	97	73	)	)	PUNCT
eurjchem-1675	97	74	,	,	PUNCT
eurjchem-1675	97	75	142.3	142.3	NUM
eurjchem-1675	97	76	(	(	PUNCT
eurjchem-1675	97	77	ch=	ch=	PROPN
eurjchem-1675	97	78	)	)	PUNCT
eurjchem-1675	97	79	,	,	PUNCT
eurjchem-1675	97	80	148.3	148.3	NUM
eurjchem-1675	97	81	(	(	PUNCT
eurjchem-1675	97	82	ch	ch	NOUN
eurjchem-1675	97	83	)	)	PUNCT
eurjchem-1675	97	84	,	,	PUNCT
eurjchem-1675	97	85	159.0	159.0	NUM
eurjchem-1675	97	86	(	(	PUNCT
eurjchem-1675	97	87	c	c	NOUN
eurjchem-1675	97	88	=	=	NOUN
eurjchem-1675	97	89	o	o	NOUN
eurjchem-1675	97	90	)	)	PUNCT
eurjchem-1675	97	91	.	.	PUNCT
eurjchem-1675	98	1	ms	ms	NOUN
eurjchem-1675	98	2	(	(	PUNCT
eurjchem-1675	98	3	m	m	PROPN
eurjchem-1675	98	4	/	/	SYM
eurjchem-1675	98	5	z	z	NOUN
eurjchem-1675	98	6	(	(	PUNCT
eurjchem-1675	98	7	%	%	NOUN
eurjchem-1675	98	8	)	)	PUNCT
eurjchem-1675	98	9	):	):	PUNCT
eurjchem-1675	98	10	301	301	NUM
eurjchem-1675	98	11	(	(	PUNCT
eurjchem-1675	98	12	m+	m+	NUM
eurjchem-1675	98	13	,	,	PUNCT
eurjchem-1675	98	14	100.0	100.0	NUM
eurjchem-1675	98	15	)	)	PUNCT
eurjchem-1675	98	16	,	,	PUNCT
eurjchem-1675	98	17	268	268	NUM
eurjchem-1675	98	18	(	(	PUNCT
eurjchem-1675	98	19	65.3	65.3	NUM
eurjchem-1675	98	20	)	)	PUNCT
eurjchem-1675	98	21	.	.	PUNCT
eurjchem-1675	99	1	anal	anal	PROPN
eurjchem-1675	99	2	.	.	PUNCT
eurjchem-1675	99	3	calcd	calcd	NOUN
eurjchem-1675	99	4	.	.	PUNCT
eurjchem-1675	100	1	for	for	SCONJ
eurjchem-1675	100	2	c16h19n3os	c16h19n3os	NOUN
eurjchem-1675	100	3	:	:	PUNCT
eurjchem-1675	100	4	c	c	X
eurjchem-1675	100	5	,	,	PUNCT
eurjchem-1675	100	6	63.67	63.67	NUM
eurjchem-1675	100	7	;	;	PUNCT
eurjchem-1675	100	8	h	h	NOUN
eurjchem-1675	100	9	,	,	PUNCT
eurjchem-1675	100	10	6.35	6.35	NUM
eurjchem-1675	100	11	;	;	PUNCT
eurjchem-1675	100	12	n	n	CCONJ
eurjchem-1675	100	13	,	,	PUNCT
eurjchem-1675	100	14	13.94	13.94	NUM
eurjchem-1675	100	15	.	.	PUNCT
eurjchem-1675	100	16	found	find	VERB
eurjchem-1675	100	17	:	:	PUNCT
eurjchem-1675	101	1	c	c	X
eurjchem-1675	101	2	,	,	PUNCT
eurjchem-1675	101	3	63.70	63.70	NUM
eurjchem-1675	101	4	;	;	PUNCT
eurjchem-1675	102	1	h	h	NOUN
eurjchem-1675	102	2	,	,	PUNCT
eurjchem-1675	102	3	6.40	6.40	NUM
eurjchem-1675	102	4	;	;	PUNCT
eurjchem-1675	102	5	n	n	CCONJ
eurjchem-1675	102	6	,	,	PUNCT
eurjchem-1675	102	7	13.90	13.90	NUM
eurjchem-1675	102	8	%	%	NOUN
eurjchem-1675	102	9	.	.	PUNCT
eurjchem-1675	103	1	2.6	2.6	NUM
eurjchem-1675	103	2	.	.	PUNCT
eurjchem-1675	103	3	reaction	reaction	NOUN
eurjchem-1675	103	4	of	of	ADP
eurjchem-1675	103	5	2	2	NUM
eurjchem-1675	103	6	-	-	PUNCT
eurjchem-1675	103	7	cyano	cyano	NOUN
eurjchem-1675	103	8	-	-	PUNCT
eurjchem-1675	103	9	n	n	CCONJ
eurjchem-1675	103	10	-	-	PUNCT
eurjchem-1675	103	11	cyclohexyl-3	cyclohexyl-3	NOUN
eurjchem-1675	103	12	-	-	PUNCT
eurjchem-1675	103	13	mercapto-3-(phenyl	mercapto-3-(phenyl	NOUN
eurjchem-1675	103	14	amino)acrylamide	amino)acrylamide	PROPN
eurjchem-1675	103	15	(	(	PUNCT
eurjchem-1675	103	16	10	10	NUM
eurjchem-1675	103	17	)	)	PUNCT
eurjchem-1675	103	18	with	with	ADP
eurjchem-1675	103	19	α	α	NOUN
eurjchem-1675	103	20	-	-	PUNCT
eurjchem-1675	103	21	haloketones	haloketone	NOUN
eurjchem-1675	103	22	thermal	thermal	ADJ
eurjchem-1675	103	23	method	method	NOUN
eurjchem-1675	103	24	:	:	PUNCT
eurjchem-1675	103	25	mixture	mixture	NOUN
eurjchem-1675	103	26	of	of	ADP
eurjchem-1675	103	27	2	2	NUM
eurjchem-1675	103	28	-	-	PUNCT
eurjchem-1675	103	29	cyano	cyano	NOUN
eurjchem-1675	103	30	-	-	PUNCT
eurjchem-1675	103	31	n	n	CCONJ
eurjchem-1675	103	32	-	-	PUNCT
eurjchem-1675	103	33	cyclohexyl-3mercapto-3-(phenylamino	cyclohexyl-3mercapto-3-(phenylamino	NOUN
eurjchem-1675	103	34	)	)	PUNCT
eurjchem-1675	103	35	acrylamide	acrylamide	NOUN
eurjchem-1675	103	36	(	(	PUNCT
eurjchem-1675	103	37	10	10	NUM
eurjchem-1675	103	38	)	)	PUNCT
eurjchem-1675	103	39	(	(	PUNCT
eurjchem-1675	103	40	0.3	0.3	NUM
eurjchem-1675	103	41	g	g	NOUN
eurjchem-1675	103	42	,	,	PUNCT
eurjchem-1675	103	43	1	1	NUM
eurjchem-1675	103	44	mmol	mmol	NOUN
eurjchem-1675	103	45	)	)	PUNCT
eurjchem-1675	103	46	2018	2018	NUM
eurjchem-1675	103	47	–	–	PUNCT
eurjchem-1675	103	48	european	european	ADJ
eurjchem-1675	103	49	journal	journal	NOUN
eurjchem-1675	103	50	of	of	ADP
eurjchem-1675	103	51	chemistry	chemistry	NOUN
eurjchem-1675	103	52	–	–	PUNCT
eurjchem-1675	103	53	cc	cc	NOUN
eurjchem-1675	103	54	by	by	ADP
eurjchem-1675	103	55	nc	nc	PROPN
eurjchem-1675	103	56	–	–	PUNCT
eurjchem-1675	103	57	doi	doi	NOUN
eurjchem-1675	103	58	:	:	PUNCT
eurjchem-1675	103	59	10.5155	10.5155	NUM
eurjchem-1675	103	60	/	/	SYM
eurjchem-1675	103	61	eurjchem.9.1.30	eurjchem.9.1.30	NOUN
eurjchem-1675	103	62	-	-	SYM
eurjchem-1675	103	63	38.1675	38.1675	NUM
eurjchem-1675	103	64	fahim	fahim	PROPN
eurjchem-1675	103	65	et	et	PROPN
eurjchem-1675	103	66	al	al	PROPN
eurjchem-1675	103	67	.	.	PUNCT
eurjchem-1675	103	68	/	/	SYM
eurjchem-1675	103	69	european	european	PROPN
eurjchem-1675	103	70	journal	journal	PROPN
eurjchem-1675	103	71	of	of	ADP
eurjchem-1675	103	72	chemistry	chemistry	NOUN
eurjchem-1675	103	73	9	9	NUM
eurjchem-1675	103	74	(	(	PUNCT
eurjchem-1675	103	75	1	1	NUM
eurjchem-1675	103	76	)	)	PUNCT
eurjchem-1675	103	77	(	(	PUNCT
eurjchem-1675	103	78	2018	2018	NUM
eurjchem-1675	103	79	)	)	PUNCT
eurjchem-1675	103	80	30	30	NUM
eurjchem-1675	103	81	-	-	SYM
eurjchem-1675	103	82	38	38	NUM
eurjchem-1675	103	83	33	33	NUM
eurjchem-1675	103	84	n	n	NUM
eurjchem-1675	104	1	h	h	NOUN
eurjchem-1675	105	1	o	o	INTJ
eurjchem-1675	105	2	cn	cn	INTJ
eurjchem-1675	105	3	h	h	NOUN
eurjchem-1675	105	4	shph	shph	VERB
eurjchem-1675	105	5	10	10	NUM
eurjchem-1675	105	6	cncl	cncl	NOUN
eurjchem-1675	105	7	n	n	DET
eurjchem-1675	105	8	h	h	NOUN
eurjchem-1675	106	1	o	o	NOUN
eurjchem-1675	106	2	s	s	VERB
eurjchem-1675	106	3	nh2	nh2	PROPN
eurjchem-1675	106	4	phhn	phhn	PROPN
eurjchem-1675	106	5	cn	cn	PROPN
eurjchem-1675	107	1	18	18	NUM
eurjchem-1675	107	2	etoh	etoh	NOUN
eurjchem-1675	107	3	h	h	NOUN
eurjchem-1675	107	4	h	h	NOUN
eurjchem-1675	108	1	d	d	NOUN
eurjchem-1675	108	2	,	,	PUNCT
eurjchem-1675	108	3	mw	mw	NOUN
eurjchem-1675	108	4	n	n	PROPN
eurjchem-1675	108	5	17	17	NUM
eurjchem-1675	108	6	d	d	PROPN
eurjchem-1675	108	7	,	,	PUNCT
eurjchem-1675	108	8	mw	mw	X
eurjchem-1675	108	9	h3c	h3c	X
eurjchem-1675	108	10	cl	cl	NOUN
eurjchem-1675	108	11	o	o	NOUN
eurjchem-1675	108	12	etoh	etoh	NOUN
eurjchem-1675	109	1	n	n	PRON
eurjchem-1675	109	2	h	h	NOUN
eurjchem-1675	110	1	o	o	X
eurjchem-1675	110	2	cn	cn	PROPN
eurjchem-1675	110	3	sch2coch3phhn	sch2coch3phhn	PROPN
eurjchem-1675	110	4	20	20	NUM
eurjchem-1675	110	5	n	n	NUM
eurjchem-1675	110	6	h	h	NOUN
eurjchem-1675	111	1	o	o	INTJ
eurjchem-1675	111	2	cn	cn	INTJ
eurjchem-1675	112	1	n	n	CCONJ
eurjchem-1675	112	2	sph	sph	PROPN
eurjchem-1675	112	3	h3c	h3c	PUNCT
eurjchem-1675	112	4	21	21	NUM
eurjchem-1675	112	5	h	h	NOUN
eurjchem-1675	112	6	h	h	NOUN
eurjchem-1675	112	7	19	19	NUM
eurjchem-1675	112	8	scheme	scheme	NOUN
eurjchem-1675	112	9	3	3	NUM
eurjchem-1675	112	10	treated	treat	VERB
eurjchem-1675	112	11	with	with	ADP
eurjchem-1675	112	12	α	α	NOUN
eurjchem-1675	112	13	-	-	PUNCT
eurjchem-1675	112	14	haloketones	haloketone	NOUN
eurjchem-1675	112	15	(	(	PUNCT
eurjchem-1675	112	16	1	1	NUM
eurjchem-1675	112	17	mmol	mmol	NOUN
eurjchem-1675	112	18	)	)	PUNCT
eurjchem-1675	112	19	with	with	ADP
eurjchem-1675	112	20	absolute	absolute	ADJ
eurjchem-1675	112	21	alcohol	alcohol	NOUN
eurjchem-1675	112	22	(	(	PUNCT
eurjchem-1675	112	23	20	20	NUM
eurjchem-1675	112	24	ml	ml	NOUN
eurjchem-1675	112	25	)	)	PUNCT
eurjchem-1675	112	26	with	with	ADP
eurjchem-1675	112	27	few	few	ADJ
eurjchem-1675	112	28	drops	drop	NOUN
eurjchem-1675	112	29	of	of	ADP
eurjchem-1675	112	30	triethylamine	triethylamine	NOUN
eurjchem-1675	112	31	as	as	ADP
eurjchem-1675	112	32	a	a	DET
eurjchem-1675	112	33	catalyst	catalyst	NOUN
eurjchem-1675	112	34	formed	form	VERB
eurjchem-1675	112	35	solid	solid	ADJ
eurjchem-1675	112	36	after	after	ADP
eurjchem-1675	112	37	reflux	reflux	NOUN
eurjchem-1675	112	38	for	for	ADP
eurjchem-1675	112	39	2h	2h	NUM
eurjchem-1675	112	40	.	.	PUNCT
eurjchem-1675	113	1	the	the	DET
eurjchem-1675	113	2	solid	solid	ADJ
eurjchem-1675	113	3	product	product	NOUN
eurjchem-1675	113	4	so	so	ADV
eurjchem-1675	113	5	formed	form	VERB
eurjchem-1675	113	6	was	be	AUX
eurjchem-1675	113	7	filtered	filter	VERB
eurjchem-1675	113	8	off	off	ADP
eurjchem-1675	113	9	,	,	PUNCT
eurjchem-1675	113	10	washed	wash	VERB
eurjchem-1675	113	11	with	with	ADP
eurjchem-1675	113	12	water	water	NOUN
eurjchem-1675	113	13	,	,	PUNCT
eurjchem-1675	113	14	dried	dry	VERB
eurjchem-1675	113	15	and	and	CCONJ
eurjchem-1675	113	16	finally	finally	ADV
eurjchem-1675	113	17	recrystallized	recrystallize	VERB
eurjchem-1675	113	18	from	from	ADP
eurjchem-1675	113	19	the	the	DET
eurjchem-1675	113	20	proper	proper	ADJ
eurjchem-1675	113	21	solvent	solvent	NOUN
eurjchem-1675	113	22	to	to	PART
eurjchem-1675	113	23	afford	afford	VERB
eurjchem-1675	113	24	compounds	compound	NOUN
eurjchem-1675	113	25	13a	13a	NOUN
eurjchem-1675	113	26	,	,	PUNCT
eurjchem-1675	113	27	13b	13b	NUM
eurjchem-1675	113	28	,	,	PUNCT
eurjchem-1675	113	29	16	16	NUM
eurjchem-1675	113	30	,	,	PUNCT
eurjchem-1675	113	31	18	18	NUM
eurjchem-1675	113	32	and	and	CCONJ
eurjchem-1675	113	33	21	21	NUM
eurjchem-1675	113	34	(	(	PUNCT
eurjchem-1675	113	35	scheme	scheme	NOUN
eurjchem-1675	113	36	2	2	NUM
eurjchem-1675	113	37	and	and	CCONJ
eurjchem-1675	113	38	3	3	NUM
eurjchem-1675	113	39	)	)	PUNCT
eurjchem-1675	113	40	.	.	PUNCT
eurjchem-1675	114	1	microwave	microwave	NOUN
eurjchem-1675	114	2	method	method	NOUN
eurjchem-1675	114	3	:	:	PUNCT
eurjchem-1675	114	4	ethanolic	ethanolic	ADJ
eurjchem-1675	114	5	mixture	mixture	NOUN
eurjchem-1675	114	6	of	of	ADP
eurjchem-1675	114	7	2	2	NUM
eurjchem-1675	114	8	-	-	PUNCT
eurjchem-1675	114	9	cyano	cyano	NOUN
eurjchem-1675	114	10	-	-	PUNCT
eurjchem-1675	114	11	n	n	CCONJ
eurjchem-1675	114	12	-	-	PUNCT
eurjchem-1675	114	13	cyclo	cyclo	NOUN
eurjchem-1675	114	14	hexyl-3	hexyl-3	NOUN
eurjchem-1675	114	15	-	-	PUNCT
eurjchem-1675	114	16	mercapto-3-(phenylamino	mercapto-3-(phenylamino	ADJ
eurjchem-1675	114	17	)	)	PUNCT
eurjchem-1675	114	18	acrylamide	acrylamide	NOUN
eurjchem-1675	114	19	(	(	PUNCT
eurjchem-1675	114	20	10	10	NUM
eurjchem-1675	114	21	)	)	PUNCT
eurjchem-1675	114	22	(	(	PUNCT
eurjchem-1675	114	23	0.3	0.3	NUM
eurjchem-1675	114	24	g	g	NOUN
eurjchem-1675	114	25	,	,	PUNCT
eurjchem-1675	114	26	1	1	NUM
eurjchem-1675	114	27	mmol	mmol	NOUN
eurjchem-1675	114	28	)	)	PUNCT
eurjchem-1675	114	29	reacts	react	VERB
eurjchem-1675	114	30	with	with	ADP
eurjchem-1675	114	31	α	α	NOUN
eurjchem-1675	114	32	-	-	PUNCT
eurjchem-1675	114	33	haloketones	haloketone	NOUN
eurjchem-1675	114	34	(	(	PUNCT
eurjchem-1675	114	35	1	1	NUM
eurjchem-1675	114	36	mmol	mmol	NOUN
eurjchem-1675	114	37	)	)	PUNCT
eurjchem-1675	114	38	with	with	ADP
eurjchem-1675	114	39	few	few	ADJ
eurjchem-1675	114	40	drops	drop	NOUN
eurjchem-1675	114	41	of	of	ADP
eurjchem-1675	114	42	triethylamine	triethylamine	NOUN
eurjchem-1675	114	43	was	be	AUX
eurjchem-1675	114	44	mixed	mix	VERB
eurjchem-1675	114	45	in	in	ADP
eurjchem-1675	114	46	a	a	DET
eurjchem-1675	114	47	process	process	NOUN
eurjchem-1675	114	48	vial	vial	NOUN
eurjchem-1675	114	49	.	.	PUNCT
eurjchem-1675	115	1	the	the	DET
eurjchem-1675	115	2	vial	vial	ADJ
eurjchem-1675	115	3	capped	cap	VERB
eurjchem-1675	115	4	properly	properly	ADV
eurjchem-1675	115	5	and	and	CCONJ
eurjchem-1675	115	6	irradiated	irradiate	VERB
eurjchem-1675	115	7	by	by	ADP
eurjchem-1675	115	8	microwaves	microwave	NOUN
eurjchem-1675	115	9	using	use	VERB
eurjchem-1675	115	10	pressurized	pressurized	ADJ
eurjchem-1675	115	11	conditions	condition	NOUN
eurjchem-1675	115	12	(	(	PUNCT
eurjchem-1675	115	13	17.2	17.2	NUM
eurjchem-1675	115	14	bar	bar	NOUN
eurjchem-1675	115	15	,	,	PUNCT
eurjchem-1675	115	16	150	150	NUM
eurjchem-1675	115	17	°	°	NOUN
eurjchem-1675	115	18	c	c	NOUN
eurjchem-1675	115	19	)	)	PUNCT
eurjchem-1675	115	20	for	for	ADP
eurjchem-1675	115	21	3	3	NUM
eurjchem-1675	115	22	min	min	NOUN
eurjchem-1675	115	23	,	,	PUNCT
eurjchem-1675	115	24	the	the	DET
eurjchem-1675	115	25	reaction	reaction	NOUN
eurjchem-1675	115	26	mixture	mixture	NOUN
eurjchem-1675	115	27	was	be	AUX
eurjchem-1675	115	28	evaporated	evaporate	VERB
eurjchem-1675	115	29	in	in	ADP
eurjchem-1675	115	30	vacuo	vacuo	NOUN
eurjchem-1675	115	31	and	and	CCONJ
eurjchem-1675	115	32	residual	residual	ADJ
eurjchem-1675	115	33	solid	solid	NOUN
eurjchem-1675	115	34	was	be	AUX
eurjchem-1675	115	35	taken	take	VERB
eurjchem-1675	115	36	in	in	ADP
eurjchem-1675	115	37	ethanol	ethanol	NOUN
eurjchem-1675	115	38	then	then	ADV
eurjchem-1675	115	39	collected	collect	VERB
eurjchem-1675	115	40	by	by	ADP
eurjchem-1675	115	41	filteration	filteration	NOUN
eurjchem-1675	115	42	,	,	PUNCT
eurjchem-1675	115	43	washed	wash	VERB
eurjchem-1675	115	44	,	,	PUNCT
eurjchem-1675	115	45	dried	dry	VERB
eurjchem-1675	115	46	and	and	CCONJ
eurjchem-1675	115	47	finally	finally	ADV
eurjchem-1675	115	48	recrystalized	recrystalize	VERB
eurjchem-1675	115	49	from	from	ADP
eurjchem-1675	115	50	the	the	DET
eurjchem-1675	115	51	proper	proper	ADJ
eurjchem-1675	115	52	solvent	solvent	NOUN
eurjchem-1675	115	53	to	to	PART
eurjchem-1675	115	54	afford	afford	VERB
eurjchem-1675	115	55	compounds	compound	NOUN
eurjchem-1675	115	56	13a	13a	NOUN
eurjchem-1675	115	57	,	,	PUNCT
eurjchem-1675	115	58	13b	13b	NUM
eurjchem-1675	115	59	,	,	PUNCT
eurjchem-1675	115	60	16	16	NUM
eurjchem-1675	115	61	,	,	PUNCT
eurjchem-1675	115	62	18	18	NUM
eurjchem-1675	115	63	and	and	CCONJ
eurjchem-1675	115	64	21	21	NUM
eurjchem-1675	115	65	.	.	X
eurjchem-1675	115	66	4	4	NUM
eurjchem-1675	115	67	-	-	PUNCT
eurjchem-1675	115	68	amino-5	amino-5	NUM
eurjchem-1675	115	69	-	-	PUNCT
eurjchem-1675	115	70	benzoyl	benzoyl	NOUN
eurjchem-1675	115	71	-	-	PUNCT
eurjchem-1675	115	72	n	n	CCONJ
eurjchem-1675	115	73	-	-	PUNCT
eurjchem-1675	115	74	cyclohexyl-2-(phenylamino)thiophe	cyclohexyl-2-(phenylamino)thiophe	NOUN
eurjchem-1675	115	75	ne-3	ne-3	NOUN
eurjchem-1675	115	76	-	-	PUNCT
eurjchem-1675	115	77	carboxamide	carboxamide	NOUN
eurjchem-1675	115	78	(	(	PUNCT
eurjchem-1675	115	79	13a	13a	NOUN
eurjchem-1675	115	80	):	):	PUNCT
eurjchem-1675	115	81	color	color	NOUN
eurjchem-1675	115	82	:	:	PUNCT
eurjchem-1675	115	83	reddish	reddish	PROPN
eurjchem-1675	115	84	brown	brown	NOUN
eurjchem-1675	115	85	.	.	PUNCT
eurjchem-1675	116	1	yield	yield	NOUN
eurjchem-1675	116	2	:	:	PUNCT
eurjchem-1675	116	3	80	80	NUM
eurjchem-1675	116	4	%	%	NOUN
eurjchem-1675	116	5	.	.	PUNCT
eurjchem-1675	117	1	m.p	m.p	PROPN
eurjchem-1675	117	2	.	.	PROPN
eurjchem-1675	117	3	:	:	PUNCT
eurjchem-1675	118	1	256	256	NUM
eurjchem-1675	118	2	-	-	SYM
eurjchem-1675	118	3	258	258	NUM
eurjchem-1675	118	4	°	°	NOUN
eurjchem-1675	118	5	c	c	NOUN
eurjchem-1675	118	6	.	.	PUNCT
eurjchem-1675	119	1	ft	ft	PROPN
eurjchem-1675	119	2	-	-	PUNCT
eurjchem-1675	119	3	ir	ir	PROPN
eurjchem-1675	119	4	(	(	PUNCT
eurjchem-1675	119	5	kbr	kbr	PROPN
eurjchem-1675	119	6	,	,	PUNCT
eurjchem-1675	119	7	ν	ν	PROPN
eurjchem-1675	119	8	,	,	PUNCT
eurjchem-1675	119	9	cm-1	cm-1	NUM
eurjchem-1675	119	10	):	):	PUNCT
eurjchem-1675	119	11	1620	1620	NUM
eurjchem-1675	119	12	(	(	PUNCT
eurjchem-1675	119	13	c	c	NOUN
eurjchem-1675	119	14	=	=	NOUN
eurjchem-1675	119	15	o	o	NOUN
eurjchem-1675	119	16	)	)	PUNCT
eurjchem-1675	119	17	,	,	PUNCT
eurjchem-1675	119	18	3297	3297	NUM
eurjchem-1675	119	19	(	(	PUNCT
eurjchem-1675	119	20	nh2	nh2	PROPN
eurjchem-1675	119	21	)	)	PUNCT
eurjchem-1675	119	22	,	,	PUNCT
eurjchem-1675	119	23	3556	3556	NUM
eurjchem-1675	119	24	(	(	PUNCT
eurjchem-1675	119	25	nh	nh	NOUN
eurjchem-1675	119	26	)	)	PUNCT
eurjchem-1675	119	27	.	.	PUNCT
eurjchem-1675	120	1	1h	1h	NUM
eurjchem-1675	120	2	nmr	nmr	NOUN
eurjchem-1675	120	3	(	(	PUNCT
eurjchem-1675	120	4	300	300	NUM
eurjchem-1675	120	5	mhz	mhz	NOUN
eurjchem-1675	120	6	,	,	PUNCT
eurjchem-1675	120	7	dmso	dmso	NOUN
eurjchem-1675	120	8	-	-	NOUN
eurjchem-1675	120	9	d6	d6	NOUN
eurjchem-1675	120	10	,	,	PUNCT
eurjchem-1675	120	11	δ	δ	PROPN
eurjchem-1675	120	12	,	,	PUNCT
eurjchem-1675	120	13	ppm	ppm	NOUN
eurjchem-1675	120	14	):	):	PUNCT
eurjchem-1675	120	15	1.40	1.40	NUM
eurjchem-1675	120	16	-	-	SYM
eurjchem-1675	120	17	1.70	1.70	NUM
eurjchem-1675	120	18	(	(	PUNCT
eurjchem-1675	120	19	m	m	PROPN
eurjchem-1675	120	20	,	,	PUNCT
eurjchem-1675	120	21	10h	10h	NUM
eurjchem-1675	120	22	,	,	PUNCT
eurjchem-1675	120	23	h2c	h2c	PROPN
eurjchem-1675	120	24	)	)	PUNCT
eurjchem-1675	120	25	,	,	PUNCT
eurjchem-1675	120	26	3.55	3.55	NUM
eurjchem-1675	120	27	(	(	PUNCT
eurjchem-1675	120	28	s	s	PROPN
eurjchem-1675	120	29	,	,	PUNCT
eurjchem-1675	120	30	1h	1h	NUM
eurjchem-1675	120	31	,	,	PUNCT
eurjchem-1675	120	32	hc	hc	PROPN
eurjchem-1675	120	33	-	-	PUNCT
eurjchem-1675	120	34	nh	nh	NOUN
eurjchem-1675	120	35	)	)	PUNCT
eurjchem-1675	120	36	,	,	PUNCT
eurjchem-1675	120	37	6.22	6.22	NUM
eurjchem-1675	120	38	(	(	PUNCT
eurjchem-1675	120	39	s	s	NOUN
eurjchem-1675	120	40	,	,	PUNCT
eurjchem-1675	120	41	2h	2h	NUM
eurjchem-1675	120	42	,	,	PUNCT
eurjchem-1675	120	43	h2n	h2n	PROPN
eurjchem-1675	120	44	d2oexchangable	d2oexchangable	ADJ
eurjchem-1675	120	45	)	)	PUNCT
eurjchem-1675	120	46	,	,	PUNCT
eurjchem-1675	120	47	6.46	6.46	NUM
eurjchem-1675	120	48	-	-	SYM
eurjchem-1675	120	49	7.01	7.01	NUM
eurjchem-1675	120	50	(	(	PUNCT
eurjchem-1675	120	51	m	m	PROPN
eurjchem-1675	120	52	,	,	PUNCT
eurjchem-1675	120	53	5h	5h	NUM
eurjchem-1675	120	54	,	,	PUNCT
eurjchem-1675	120	55	ar	ar	NOUN
eurjchem-1675	120	56	-	-	NOUN
eurjchem-1675	120	57	h	h	NOUN
eurjchem-1675	120	58	)	)	PUNCT
eurjchem-1675	120	59	,	,	PUNCT
eurjchem-1675	120	60	7.45	7.45	NUM
eurjchem-1675	120	61	(	(	PUNCT
eurjchem-1675	120	62	m	m	PROPN
eurjchem-1675	120	63	,	,	PUNCT
eurjchem-1675	120	64	3h	3h	NUM
eurjchem-1675	120	65	,	,	PUNCT
eurjchem-1675	120	66	hc	hc	PROPN
eurjchem-1675	120	67	)	)	PUNCT
eurjchem-1675	120	68	,	,	PUNCT
eurjchem-1675	120	69	7.81	7.81	NUM
eurjchem-1675	120	70	(	(	PUNCT
eurjchem-1675	120	71	d	d	PROPN
eurjchem-1675	120	72	,	,	PUNCT
eurjchem-1675	120	73	j	j	PROPN
eurjchem-1675	120	74	=	=	SYM
eurjchem-1675	120	75	2.1	2.1	NUM
eurjchem-1675	120	76	hz	hz	NOUN
eurjchem-1675	120	77	,	,	PUNCT
eurjchem-1675	120	78	2h	2h	NUM
eurjchem-1675	120	79	,	,	PUNCT
eurjchem-1675	120	80	hc	hc	NOUN
eurjchem-1675	120	81	)	)	PUNCT
eurjchem-1675	120	82	,	,	PUNCT
eurjchem-1675	120	83	8.05	8.05	NUM
eurjchem-1675	120	84	(	(	PUNCT
eurjchem-1675	120	85	s	s	PROPN
eurjchem-1675	120	86	,	,	PUNCT
eurjchem-1675	120	87	1h	1h	NUM
eurjchem-1675	120	88	,	,	PUNCT
eurjchem-1675	120	89	hn	hn	PROPN
eurjchem-1675	120	90	d2o	d2o	NOUN
eurjchem-1675	120	91	-	-	PUNCT
eurjchem-1675	120	92	exchangable	exchangable	ADJ
eurjchem-1675	120	93	)	)	PUNCT
eurjchem-1675	120	94	,	,	PUNCT
eurjchem-1675	120	95	9.51	9.51	NUM
eurjchem-1675	120	96	(	(	PUNCT
eurjchem-1675	120	97	s	s	PROPN
eurjchem-1675	120	98	,	,	PUNCT
eurjchem-1675	120	99	1h	1h	NUM
eurjchem-1675	120	100	,	,	PUNCT
eurjchem-1675	120	101	hn	hn	PROPN
eurjchem-1675	120	102	d2o	d2o	NOUN
eurjchem-1675	120	103	-	-	PUNCT
eurjchem-1675	120	104	exchangable	exchangable	ADJ
eurjchem-1675	120	105	)	)	PUNCT
eurjchem-1675	120	106	.	.	PUNCT
eurjchem-1675	121	1	13c	13c	NOUN
eurjchem-1675	121	2	nmr	nmr	NOUN
eurjchem-1675	121	3	(	(	PUNCT
eurjchem-1675	121	4	75	75	NUM
eurjchem-1675	121	5	mhz	mhz	NOUN
eurjchem-1675	121	6	,	,	PUNCT
eurjchem-1675	121	7	dmso	dmso	NOUN
eurjchem-1675	121	8	-	-	NOUN
eurjchem-1675	121	9	d6	d6	NOUN
eurjchem-1675	121	10	,	,	PUNCT
eurjchem-1675	121	11	δ	δ	PROPN
eurjchem-1675	121	12	,	,	PUNCT
eurjchem-1675	121	13	ppm	ppm	NUM
eurjchem-1675	121	14	):	):	PUNCT
eurjchem-1675	121	15	24.6	24.6	NUM
eurjchem-1675	121	16	(	(	PUNCT
eurjchem-1675	121	17	ch2	ch2	PROPN
eurjchem-1675	121	18	)	)	PUNCT
eurjchem-1675	121	19	,	,	PUNCT
eurjchem-1675	121	20	28.1	28.1	NUM
eurjchem-1675	121	21	(	(	PUNCT
eurjchem-1675	121	22	ch2	ch2	PROPN
eurjchem-1675	121	23	)	)	PUNCT
eurjchem-1675	121	24	,	,	PUNCT
eurjchem-1675	121	25	34.5	34.5	NUM
eurjchem-1675	121	26	(	(	PUNCT
eurjchem-1675	121	27	ch2	ch2	PROPN
eurjchem-1675	121	28	)	)	PUNCT
eurjchem-1675	121	29	,	,	PUNCT
eurjchem-1675	121	30	92.3	92.3	NUM
eurjchem-1675	121	31	(	(	PUNCT
eurjchem-1675	121	32	ch	ch	NOUN
eurjchem-1675	121	33	)	)	PUNCT
eurjchem-1675	121	34	,	,	PUNCT
eurjchem-1675	121	35	103.2	103.2	NUM
eurjchem-1675	121	36	(	(	PUNCT
eurjchem-1675	121	37	ch	ch	NOUN
eurjchem-1675	121	38	)	)	PUNCT
eurjchem-1675	121	39	,	,	PUNCT
eurjchem-1675	121	40	116.0	116.0	NUM
eurjchem-1675	121	41	(	(	PUNCT
eurjchem-1675	121	42	ch	ch	NOUN
eurjchem-1675	121	43	)	)	PUNCT
eurjchem-1675	121	44	,	,	PUNCT
eurjchem-1675	121	45	128.3	128.3	NUM
eurjchem-1675	121	46	(	(	PUNCT
eurjchem-1675	121	47	ch	ch	NOUN
eurjchem-1675	121	48	)	)	PUNCT
eurjchem-1675	121	49	,	,	PUNCT
eurjchem-1675	121	50	129.3	129.3	NUM
eurjchem-1675	121	51	(	(	PUNCT
eurjchem-1675	121	52	ch	ch	NOUN
eurjchem-1675	121	53	)	)	PUNCT
eurjchem-1675	121	54	,	,	PUNCT
eurjchem-1675	121	55	133.3	133.3	NUM
eurjchem-1675	121	56	(	(	PUNCT
eurjchem-1675	121	57	ch	ch	NOUN
eurjchem-1675	121	58	)	)	PUNCT
eurjchem-1675	121	59	,	,	PUNCT
eurjchem-1675	121	60	136.0	136.0	NUM
eurjchem-1675	121	61	(	(	PUNCT
eurjchem-1675	121	62	ch	ch	NOUN
eurjchem-1675	121	63	)	)	PUNCT
eurjchem-1675	121	64	,	,	PUNCT
eurjchem-1675	121	65	143.2	143.2	NUM
eurjchem-1675	121	66	(	(	PUNCT
eurjchem-1675	121	67	ch	ch	NOUN
eurjchem-1675	121	68	)	)	PUNCT
eurjchem-1675	121	69	,	,	PUNCT
eurjchem-1675	121	70	167.3	167.3	NUM
eurjchem-1675	121	71	(	(	PUNCT
eurjchem-1675	121	72	c	c	NOUN
eurjchem-1675	121	73	=	=	NOUN
eurjchem-1675	121	74	o	o	NOUN
eurjchem-1675	121	75	)	)	PUNCT
eurjchem-1675	121	76	,	,	PUNCT
eurjchem-1675	121	77	180.0	180.0	NUM
eurjchem-1675	121	78	(	(	PUNCT
eurjchem-1675	121	79	c	c	NOUN
eurjchem-1675	121	80	=	=	NOUN
eurjchem-1675	121	81	o	o	NOUN
eurjchem-1675	121	82	)	)	PUNCT
eurjchem-1675	121	83	.	.	PUNCT
eurjchem-1675	122	1	ms	ms	NOUN
eurjchem-1675	122	2	(	(	PUNCT
eurjchem-1675	122	3	m	m	PROPN
eurjchem-1675	122	4	/	/	SYM
eurjchem-1675	122	5	z	z	NOUN
eurjchem-1675	122	6	(	(	PUNCT
eurjchem-1675	122	7	%	%	NOUN
eurjchem-1675	122	8	)	)	PUNCT
eurjchem-1675	122	9	):	):	PUNCT
eurjchem-1675	122	10	419	419	NUM
eurjchem-1675	122	11	(	(	PUNCT
eurjchem-1675	122	12	m+	m+	NUM
eurjchem-1675	122	13	,	,	PUNCT
eurjchem-1675	122	14	100	100	NUM
eurjchem-1675	122	15	)	)	PUNCT
eurjchem-1675	122	16	,	,	PUNCT
eurjchem-1675	122	17	126	126	NUM
eurjchem-1675	122	18	(	(	PUNCT
eurjchem-1675	122	19	12.3	12.3	NUM
eurjchem-1675	122	20	)	)	PUNCT
eurjchem-1675	122	21	,	,	PUNCT
eurjchem-1675	122	22	321	321	NUM
eurjchem-1675	122	23	(	(	PUNCT
eurjchem-1675	122	24	33.2	33.2	NUM
eurjchem-1675	122	25	)	)	PUNCT
eurjchem-1675	122	26	.	.	PUNCT
eurjchem-1675	123	1	anal	anal	PROPN
eurjchem-1675	123	2	.	.	PUNCT
eurjchem-1675	123	3	calcd	calcd	NOUN
eurjchem-1675	123	4	.	.	PUNCT
eurjchem-1675	124	1	for	for	ADP
eurjchem-1675	124	2	c24h25n3o2s	c24h25n3o2s	NUM
eurjchem-1675	124	3	:	:	PUNCT
eurjchem-1675	124	4	c	c	X
eurjchem-1675	124	5	,	,	PUNCT
eurjchem-1675	124	6	68.71	68.71	NUM
eurjchem-1675	124	7	;	;	PUNCT
eurjchem-1675	124	8	h	h	NOUN
eurjchem-1675	124	9	,	,	PUNCT
eurjchem-1675	124	10	6.01	6.01	NUM
eurjchem-1675	124	11	;	;	PUNCT
eurjchem-1675	124	12	n	n	CCONJ
eurjchem-1675	124	13	,	,	PUNCT
eurjchem-1675	124	14	10.02	10.02	NUM
eurjchem-1675	124	15	.	.	PUNCT
eurjchem-1675	124	16	found	find	VERB
eurjchem-1675	124	17	:	:	PUNCT
eurjchem-1675	125	1	c	c	X
eurjchem-1675	125	2	,	,	PUNCT
eurjchem-1675	125	3	68.75	68.75	NUM
eurjchem-1675	125	4	;	;	PUNCT
eurjchem-1675	125	5	h	h	NOUN
eurjchem-1675	125	6	,	,	PUNCT
eurjchem-1675	125	7	6.07	6.07	NUM
eurjchem-1675	125	8	;	;	PUNCT
eurjchem-1675	125	9	n	n	CCONJ
eurjchem-1675	125	10	,	,	PUNCT
eurjchem-1675	125	11	10.07	10.07	NUM
eurjchem-1675	125	12	%	%	NOUN
eurjchem-1675	125	13	.	.	PUNCT
eurjchem-1675	126	1	4	4	NUM
eurjchem-1675	126	2	-	-	PUNCT
eurjchem-1675	126	3	amino-5-(4	amino-5-(4	NOUN
eurjchem-1675	126	4	-	-	PUNCT
eurjchem-1675	126	5	bromobenzoyl)-n	bromobenzoyl)-n	NOUN
eurjchem-1675	126	6	-	-	PUNCT
eurjchem-1675	126	7	cyclohexyl-2-(phenylamino	cyclohexyl-2-(phenylamino	NOUN
eurjchem-1675	126	8	)	)	PUNCT
eurjchem-1675	126	9	thiophene-3	thiophene-3	NUM
eurjchem-1675	126	10	-	-	PUNCT
eurjchem-1675	126	11	carboxamide	carboxamide	NOUN
eurjchem-1675	126	12	(	(	PUNCT
eurjchem-1675	126	13	13b	13b	NUM
eurjchem-1675	126	14	):	):	PUNCT
eurjchem-1675	126	15	color	color	NOUN
eurjchem-1675	126	16	:	:	PUNCT
eurjchem-1675	126	17	brown	brown	ADJ
eurjchem-1675	126	18	.	.	PUNCT
eurjchem-1675	126	19	yield	yield	NOUN
eurjchem-1675	126	20	:	:	PUNCT
eurjchem-1675	126	21	80	80	NUM
eurjchem-1675	126	22	%	%	NOUN
eurjchem-1675	126	23	.	.	PUNCT
eurjchem-1675	127	1	m.p	m.p	PROPN
eurjchem-1675	127	2	.	.	PROPN
eurjchem-1675	127	3	:	:	PUNCT
eurjchem-1675	128	1	260	260	NUM
eurjchem-1675	128	2	-	-	SYM
eurjchem-1675	128	3	262	262	NUM
eurjchem-1675	128	4	°	°	NOUN
eurjchem-1675	128	5	c	c	NOUN
eurjchem-1675	128	6	.	.	PUNCT
eurjchem-1675	129	1	ft	ft	PROPN
eurjchem-1675	129	2	-	-	PUNCT
eurjchem-1675	129	3	ir	ir	PROPN
eurjchem-1675	129	4	(	(	PUNCT
eurjchem-1675	129	5	kbr	kbr	PROPN
eurjchem-1675	129	6	,	,	PUNCT
eurjchem-1675	129	7	ν	ν	PROPN
eurjchem-1675	129	8	,	,	PUNCT
eurjchem-1675	129	9	cm-1	cm-1	NUM
eurjchem-1675	129	10	):	):	PUNCT
eurjchem-1675	129	11	1620	1620	NUM
eurjchem-1675	129	12	(	(	PUNCT
eurjchem-1675	129	13	c	c	NOUN
eurjchem-1675	129	14	=	=	NOUN
eurjchem-1675	129	15	o	o	NOUN
eurjchem-1675	129	16	)	)	PUNCT
eurjchem-1675	129	17	,	,	PUNCT
eurjchem-1675	129	18	3285	3285	NUM
eurjchem-1675	129	19	(	(	PUNCT
eurjchem-1675	129	20	nh2	nh2	PROPN
eurjchem-1675	129	21	)	)	PUNCT
eurjchem-1675	129	22	,	,	PUNCT
eurjchem-1675	129	23	3356	3356	NUM
eurjchem-1675	129	24	(	(	PUNCT
eurjchem-1675	129	25	nh	nh	NOUN
eurjchem-1675	129	26	)	)	PUNCT
eurjchem-1675	129	27	.	.	PUNCT
eurjchem-1675	130	1	1h	1h	NUM
eurjchem-1675	130	2	nmr	nmr	NOUN
eurjchem-1675	130	3	(	(	PUNCT
eurjchem-1675	130	4	300	300	NUM
eurjchem-1675	130	5	mhz	mhz	NOUN
eurjchem-1675	130	6	,	,	PUNCT
eurjchem-1675	130	7	dmso	dmso	NOUN
eurjchem-1675	130	8	-	-	NOUN
eurjchem-1675	130	9	d6	d6	NOUN
eurjchem-1675	130	10	,	,	PUNCT
eurjchem-1675	130	11	δ	δ	PROPN
eurjchem-1675	130	12	,	,	PUNCT
eurjchem-1675	130	13	ppm	ppm	NUM
eurjchem-1675	130	14	):	):	PUNCT
eurjchem-1675	130	15	1.37	1.37	NUM
eurjchem-1675	130	16	-	-	SYM
eurjchem-1675	130	17	1.52	1.52	NUM
eurjchem-1675	130	18	(	(	PUNCT
eurjchem-1675	130	19	m	m	PROPN
eurjchem-1675	130	20	,	,	PUNCT
eurjchem-1675	130	21	10h	10h	NUM
eurjchem-1675	130	22	,	,	PUNCT
eurjchem-1675	130	23	h2c	h2c	PROPN
eurjchem-1675	130	24	)	)	PUNCT
eurjchem-1675	130	25	,	,	PUNCT
eurjchem-1675	130	26	3.42	3.42	NUM
eurjchem-1675	130	27	(	(	PUNCT
eurjchem-1675	130	28	s	s	PROPN
eurjchem-1675	130	29	,	,	PUNCT
eurjchem-1675	130	30	1h	1h	NUM
eurjchem-1675	130	31	,	,	PUNCT
eurjchem-1675	130	32	hc	hc	PROPN
eurjchem-1675	130	33	-	-	PUNCT
eurjchem-1675	130	34	nh	nh	NOUN
eurjchem-1675	130	35	)	)	PUNCT
eurjchem-1675	130	36	,	,	PUNCT
eurjchem-1675	130	37	6.22	6.22	NUM
eurjchem-1675	130	38	(	(	PUNCT
eurjchem-1675	130	39	s	s	NOUN
eurjchem-1675	130	40	,	,	PUNCT
eurjchem-1675	130	41	2h	2h	NUM
eurjchem-1675	130	42	,	,	PUNCT
eurjchem-1675	130	43	h2n	h2n	PROPN
eurjchem-1675	130	44	d2oexchangable	d2oexchangable	ADJ
eurjchem-1675	130	45	)	)	PUNCT
eurjchem-1675	130	46	7.05	7.05	NUM
eurjchem-1675	130	47	-	-	SYM
eurjchem-1675	130	48	7.38	7.38	NUM
eurjchem-1675	130	49	(	(	PUNCT
eurjchem-1675	130	50	m	m	PROPN
eurjchem-1675	130	51	,	,	PUNCT
eurjchem-1675	130	52	5h	5h	NUM
eurjchem-1675	130	53	,	,	PUNCT
eurjchem-1675	130	54	ar	ar	NOUN
eurjchem-1675	130	55	-	-	NOUN
eurjchem-1675	130	56	h	h	NOUN
eurjchem-1675	130	57	)	)	PUNCT
eurjchem-1675	130	58	,	,	PUNCT
eurjchem-1675	130	59	7.52	7.52	NUM
eurjchem-1675	130	60	(	(	PUNCT
eurjchem-1675	130	61	d	d	PROPN
eurjchem-1675	130	62	,	,	PUNCT
eurjchem-1675	130	63	j	j	PROPN
eurjchem-1675	130	64	=	=	SYM
eurjchem-1675	130	65	3.2	3.2	NUM
eurjchem-1675	130	66	hz	hz	NOUN
eurjchem-1675	130	67	,	,	PUNCT
eurjchem-1675	130	68	2h	2h	NUM
eurjchem-1675	130	69	,	,	PUNCT
eurjchem-1675	130	70	hc	hc	NOUN
eurjchem-1675	130	71	)	)	PUNCT
eurjchem-1675	130	72	,	,	PUNCT
eurjchem-1675	130	73	7.68	7.68	NUM
eurjchem-1675	130	74	(	(	PUNCT
eurjchem-1675	130	75	d	d	PROPN
eurjchem-1675	130	76	,	,	PUNCT
eurjchem-1675	130	77	j	j	PROPN
eurjchem-1675	130	78	=	=	SYM
eurjchem-1675	130	79	7.6	7.6	NUM
eurjchem-1675	130	80	hz	hz	NOUN
eurjchem-1675	130	81	,	,	PUNCT
eurjchem-1675	130	82	2h	2h	NUM
eurjchem-1675	130	83	,	,	PUNCT
eurjchem-1675	130	84	hc	hc	NOUN
eurjchem-1675	130	85	)	)	PUNCT
eurjchem-1675	130	86	,	,	PUNCT
eurjchem-1675	130	87	7.912	7.912	NUM
eurjchem-1675	130	88	(	(	PUNCT
eurjchem-1675	130	89	s	s	PROPN
eurjchem-1675	130	90	,	,	PUNCT
eurjchem-1675	130	91	1h	1h	NUM
eurjchem-1675	130	92	,	,	PUNCT
eurjchem-1675	130	93	hn	hn	PROPN
eurjchem-1675	130	94	d2o	d2o	NOUN
eurjchem-1675	130	95	-	-	PUNCT
eurjchem-1675	130	96	exchangable	exchangable	ADJ
eurjchem-1675	130	97	)	)	PUNCT
eurjchem-1675	130	98	,	,	PUNCT
eurjchem-1675	130	99	9.76	9.76	NUM
eurjchem-1675	130	100	(	(	PUNCT
eurjchem-1675	130	101	s	s	PROPN
eurjchem-1675	130	102	,	,	PUNCT
eurjchem-1675	130	103	1h	1h	NUM
eurjchem-1675	130	104	,	,	PUNCT
eurjchem-1675	130	105	hn	hn	PROPN
eurjchem-1675	130	106	d2o	d2o	NOUN
eurjchem-1675	130	107	-	-	PUNCT
eurjchem-1675	130	108	exchangable	exchangable	ADJ
eurjchem-1675	130	109	)	)	PUNCT
eurjchem-1675	130	110	.	.	PUNCT
eurjchem-1675	131	1	13c	13c	NOUN
eurjchem-1675	131	2	nmr	nmr	NOUN
eurjchem-1675	131	3	(	(	PUNCT
eurjchem-1675	131	4	75	75	NUM
eurjchem-1675	131	5	mhz	mhz	NOUN
eurjchem-1675	131	6	,	,	PUNCT
eurjchem-1675	131	7	dmso	dmso	NOUN
eurjchem-1675	131	8	-	-	NOUN
eurjchem-1675	131	9	d6	d6	NOUN
eurjchem-1675	131	10	,	,	PUNCT
eurjchem-1675	131	11	δ	δ	PROPN
eurjchem-1675	131	12	,	,	PUNCT
eurjchem-1675	131	13	ppm	ppm	NUM
eurjchem-1675	131	14	):	):	PUNCT
eurjchem-1675	131	15	23.4	23.4	NUM
eurjchem-1675	131	16	(	(	PUNCT
eurjchem-1675	131	17	ch2	ch2	PROPN
eurjchem-1675	131	18	)	)	PUNCT
eurjchem-1675	131	19	,	,	PUNCT
eurjchem-1675	131	20	25.3	25.3	NUM
eurjchem-1675	131	21	(	(	PUNCT
eurjchem-1675	131	22	ch2	ch2	PROPN
eurjchem-1675	131	23	)	)	PUNCT
eurjchem-1675	131	24	,	,	PUNCT
eurjchem-1675	131	25	32.5	32.5	NUM
eurjchem-1675	131	26	(	(	PUNCT
eurjchem-1675	131	27	ch2	ch2	PROPN
eurjchem-1675	131	28	)	)	PUNCT
eurjchem-1675	131	29	,	,	PUNCT
eurjchem-1675	131	30	94.3	94.3	NUM
eurjchem-1675	131	31	(	(	PUNCT
eurjchem-1675	131	32	ch	ch	NOUN
eurjchem-1675	131	33	)	)	PUNCT
eurjchem-1675	131	34	,	,	PUNCT
eurjchem-1675	131	35	105.7	105.7	NUM
eurjchem-1675	131	36	(	(	PUNCT
eurjchem-1675	131	37	ch	ch	NOUN
eurjchem-1675	131	38	)	)	PUNCT
eurjchem-1675	131	39	,	,	PUNCT
eurjchem-1675	131	40	114.2	114.2	NUM
eurjchem-1675	131	41	(	(	PUNCT
eurjchem-1675	131	42	ch	ch	NOUN
eurjchem-1675	131	43	)	)	PUNCT
eurjchem-1675	131	44	,	,	PUNCT
eurjchem-1675	131	45	118.6	118.6	NUM
eurjchem-1675	131	46	(	(	PUNCT
eurjchem-1675	131	47	ch	ch	NOUN
eurjchem-1675	131	48	)	)	PUNCT
eurjchem-1675	131	49	,	,	PUNCT
eurjchem-1675	131	50	127.3	127.3	NUM
eurjchem-1675	131	51	(	(	PUNCT
eurjchem-1675	131	52	ch	ch	NOUN
eurjchem-1675	131	53	)	)	PUNCT
eurjchem-1675	131	54	,	,	PUNCT
eurjchem-1675	131	55	129.3	129.3	NUM
eurjchem-1675	131	56	(	(	PUNCT
eurjchem-1675	131	57	ch	ch	NOUN
eurjchem-1675	131	58	)	)	PUNCT
eurjchem-1675	131	59	,	,	PUNCT
eurjchem-1675	131	60	132.3	132.3	NUM
eurjchem-1675	131	61	(	(	PUNCT
eurjchem-1675	131	62	ch	ch	NOUN
eurjchem-1675	131	63	)	)	PUNCT
eurjchem-1675	131	64	,	,	PUNCT
eurjchem-1675	131	65	134.3	134.3	NUM
eurjchem-1675	131	66	(	(	PUNCT
eurjchem-1675	131	67	ch	ch	NOUN
eurjchem-1675	131	68	)	)	PUNCT
eurjchem-1675	131	69	,	,	PUNCT
eurjchem-1675	131	70	143.2	143.2	NUM
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eurjchem-1675	131	72	ch	ch	NOUN
eurjchem-1675	131	73	)	)	PUNCT
eurjchem-1675	131	74	,	,	PUNCT
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eurjchem-1675	131	77	c	c	NOUN
eurjchem-1675	131	78	=	=	NOUN
eurjchem-1675	131	79	o	o	NOUN
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eurjchem-1675	131	81	,	,	PUNCT
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eurjchem-1675	131	83	(	(	PUNCT
eurjchem-1675	131	84	ch=	ch=	PROPN
eurjchem-1675	131	85	)	)	PUNCT
eurjchem-1675	131	86	,	,	PUNCT
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eurjchem-1675	131	88	(	(	PUNCT
eurjchem-1675	131	89	c	c	NOUN
eurjchem-1675	131	90	=	=	NOUN
eurjchem-1675	131	91	o	o	NOUN
eurjchem-1675	131	92	)	)	PUNCT
eurjchem-1675	131	93	.	.	PUNCT
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eurjchem-1675	132	2	(	(	PUNCT
eurjchem-1675	132	3	m	m	PROPN
eurjchem-1675	132	4	/	/	SYM
eurjchem-1675	132	5	z	z	NOUN
eurjchem-1675	132	6	(	(	PUNCT
eurjchem-1675	132	7	%	%	NOUN
eurjchem-1675	132	8	)	)	PUNCT
eurjchem-1675	132	9	):	):	PUNCT
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eurjchem-1675	132	12	m+	m+	NUM
eurjchem-1675	132	13	,	,	PUNCT
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eurjchem-1675	132	16	,	,	PUNCT
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eurjchem-1675	132	18	(	(	PUNCT
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eurjchem-1675	132	20	)	)	PUNCT
eurjchem-1675	132	21	,	,	PUNCT
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eurjchem-1675	132	23	(	(	PUNCT
eurjchem-1675	132	24	41.00	41.00	NUM
eurjchem-1675	132	25	)	)	PUNCT
eurjchem-1675	132	26	.	.	PUNCT
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eurjchem-1675	133	2	.	.	PUNCT
eurjchem-1675	133	3	calcd	calcd	NOUN
eurjchem-1675	133	4	.	.	PUNCT
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eurjchem-1675	134	2	c24h24brn3o2s	c24h24brn3o2s	NOUN
eurjchem-1675	134	3	:	:	PUNCT
eurjchem-1675	134	4	c	c	X
eurjchem-1675	134	5	,	,	PUNCT
eurjchem-1675	134	6	57.83	57.83	NUM
eurjchem-1675	134	7	;	;	PUNCT
eurjchem-1675	134	8	h	h	X
eurjchem-1675	134	9	,	,	PUNCT
eurjchem-1675	134	10	4.85	4.85	NUM
eurjchem-1675	134	11	;	;	PUNCT
eurjchem-1675	134	12	n	n	CCONJ
eurjchem-1675	134	13	,	,	PUNCT
eurjchem-1675	134	14	8.43	8.43	NUM
eurjchem-1675	134	15	.	.	PUNCT
eurjchem-1675	134	16	found	find	VERB
eurjchem-1675	134	17	:	:	PUNCT
eurjchem-1675	135	1	c	c	X
eurjchem-1675	135	2	,	,	PUNCT
eurjchem-1675	135	3	57.85	57.85	NUM
eurjchem-1675	135	4	;	;	PUNCT
eurjchem-1675	135	5	h	h	NOUN
eurjchem-1675	135	6	,	,	PUNCT
eurjchem-1675	135	7	4.88	4.88	NUM
eurjchem-1675	135	8	;	;	PUNCT
eurjchem-1675	135	9	n	n	CCONJ
eurjchem-1675	135	10	,	,	PUNCT
eurjchem-1675	135	11	8.47	8.47	NUM
eurjchem-1675	135	12	%	%	NOUN
eurjchem-1675	135	13	.	.	PUNCT
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eurjchem-1675	136	2	3	3	NUM
eurjchem-1675	136	3	-	-	PUNCT
eurjchem-1675	136	4	amino-4-(cyclohexylcarbamoyl)-5-(phenylamino	amino-4-(cyclohexylcarbamoyl)-5-(phenylamino	NOUN
eurjchem-1675	136	5	)	)	PUNCT
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eurjchem-1675	136	7	-	-	PUNCT
eurjchem-1675	136	8	carboxylate	carboxylate	NOUN
eurjchem-1675	136	9	(	(	PUNCT
eurjchem-1675	136	10	16	16	NUM
eurjchem-1675	136	11	):	):	PUNCT
eurjchem-1675	136	12	color	color	NOUN
eurjchem-1675	136	13	:	:	PUNCT
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eurjchem-1675	136	16	.	.	PUNCT
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eurjchem-1675	137	2	:	:	PUNCT
eurjchem-1675	137	3	80	80	NUM
eurjchem-1675	137	4	%	%	NOUN
eurjchem-1675	137	5	.	.	PUNCT
eurjchem-1675	138	1	m.p	m.p	PROPN
eurjchem-1675	138	2	.	.	PROPN
eurjchem-1675	138	3	:	:	PUNCT
eurjchem-1675	139	1	160	160	NUM
eurjchem-1675	139	2	-	-	SYM
eurjchem-1675	139	3	162	162	NUM
eurjchem-1675	139	4	°	°	PROPN
eurjchem-1675	139	5	c	c	NOUN
eurjchem-1675	139	6	.	.	PUNCT
eurjchem-1675	139	7	ft	ft	PROPN
eurjchem-1675	139	8	-	-	PUNCT
eurjchem-1675	139	9	ir	ir	PROPN
eurjchem-1675	139	10	(	(	PUNCT
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eurjchem-1675	139	14	,	,	PUNCT
eurjchem-1675	139	15	cm-1	cm-1	NUM
eurjchem-1675	139	16	):	):	PUNCT
eurjchem-1675	139	17	1654	1654	NUM
eurjchem-1675	139	18	(	(	PUNCT
eurjchem-1675	139	19	c	c	NOUN
eurjchem-1675	139	20	=	=	NOUN
eurjchem-1675	139	21	o	o	NOUN
eurjchem-1675	139	22	)	)	PUNCT
eurjchem-1675	139	23	,	,	PUNCT
eurjchem-1675	139	24	3332	3332	NUM
eurjchem-1675	139	25	(	(	PUNCT
eurjchem-1675	139	26	nh2	nh2	PROPN
eurjchem-1675	139	27	)	)	PUNCT
eurjchem-1675	139	28	,	,	PUNCT
eurjchem-1675	139	29	3428	3428	NUM
eurjchem-1675	139	30	(	(	PUNCT
eurjchem-1675	139	31	nh	nh	NOUN
eurjchem-1675	139	32	)	)	PUNCT
eurjchem-1675	139	33	.	.	PUNCT
eurjchem-1675	140	1	1h	1h	NUM
eurjchem-1675	140	2	nmr	nmr	NOUN
eurjchem-1675	140	3	(	(	PUNCT
eurjchem-1675	140	4	300	300	NUM
eurjchem-1675	140	5	mhz	mhz	NOUN
eurjchem-1675	140	6	,	,	PUNCT
eurjchem-1675	140	7	dmso	dmso	NOUN
eurjchem-1675	140	8	-	-	NOUN
eurjchem-1675	140	9	d6	d6	NOUN
eurjchem-1675	140	10	,	,	PUNCT
eurjchem-1675	140	11	δ	δ	PROPN
eurjchem-1675	140	12	,	,	PUNCT
eurjchem-1675	140	13	ppm	ppm	NOUN
eurjchem-1675	140	14	):	):	PUNCT
eurjchem-1675	140	15	1.43	1.43	NUM
eurjchem-1675	140	16	-	-	SYM
eurjchem-1675	140	17	1.65	1.65	NUM
eurjchem-1675	140	18	(	(	PUNCT
eurjchem-1675	140	19	m	m	PROPN
eurjchem-1675	140	20	,	,	PUNCT
eurjchem-1675	140	21	10h	10h	NUM
eurjchem-1675	140	22	,	,	PUNCT
eurjchem-1675	140	23	h2c	h2c	PROPN
eurjchem-1675	140	24	)	)	PUNCT
eurjchem-1675	140	25	,	,	PUNCT
eurjchem-1675	140	26	1.79	1.79	NUM
eurjchem-1675	140	27	(	(	PUNCT
eurjchem-1675	140	28	t	t	PROPN
eurjchem-1675	140	29	,	,	PUNCT
eurjchem-1675	140	30	3h	3h	NUM
eurjchem-1675	140	31	,	,	PUNCT
eurjchem-1675	140	32	h3c	h3c	X
eurjchem-1675	140	33	)	)	PUNCT
eurjchem-1675	140	34	,	,	PUNCT
eurjchem-1675	140	35	3.53	3.53	NUM
eurjchem-1675	140	36	(	(	PUNCT
eurjchem-1675	140	37	s	s	PROPN
eurjchem-1675	140	38	,	,	PUNCT
eurjchem-1675	140	39	1h	1h	NUM
eurjchem-1675	140	40	,	,	PUNCT
eurjchem-1675	140	41	hc	hc	PROPN
eurjchem-1675	140	42	-	-	PUNCT
eurjchem-1675	140	43	nh	nh	NOUN
eurjchem-1675	140	44	)	)	PUNCT
eurjchem-1675	140	45	,	,	PUNCT
eurjchem-1675	140	46	4.183	4.183	NUM
eurjchem-1675	140	47	(	(	PUNCT
eurjchem-1675	140	48	q	q	NOUN
eurjchem-1675	140	49	,	,	PUNCT
eurjchem-1675	140	50	2h	2h	NUM
eurjchem-1675	140	51	,	,	PUNCT
eurjchem-1675	140	52	h2c	h2c	PROPN
eurjchem-1675	140	53	)	)	PUNCT
eurjchem-1675	140	54	,	,	PUNCT
eurjchem-1675	140	55	6.61	6.61	NUM
eurjchem-1675	140	56	(	(	PUNCT
eurjchem-1675	140	57	s	s	PROPN
eurjchem-1675	140	58	,	,	PUNCT
eurjchem-1675	140	59	2h	2h	NUM
eurjchem-1675	140	60	,	,	PUNCT
eurjchem-1675	140	61	h2n	h2n	NOUN
eurjchem-1675	140	62	d2o	d2o	NOUN
eurjchem-1675	140	63	-	-	NOUN
eurjchem-1675	140	64	exchangable	exchangable	ADJ
eurjchem-1675	140	65	)	)	PUNCT
eurjchem-1675	140	66	,	,	PUNCT
eurjchem-1675	140	67	7.02	7.02	NUM
eurjchem-1675	140	68	-	-	SYM
eurjchem-1675	140	69	7.21	7.21	NUM
eurjchem-1675	140	70	(	(	PUNCT
eurjchem-1675	140	71	m	m	PROPN
eurjchem-1675	140	72	,	,	PUNCT
eurjchem-1675	140	73	5h	5h	NUM
eurjchem-1675	140	74	,	,	PUNCT
eurjchem-1675	140	75	ar	ar	NOUN
eurjchem-1675	140	76	-	-	NOUN
eurjchem-1675	140	77	h	h	NOUN
eurjchem-1675	140	78	)	)	PUNCT
eurjchem-1675	140	79	,	,	PUNCT
eurjchem-1675	140	80	7.932	7.932	NUM
eurjchem-1675	140	81	(	(	PUNCT
eurjchem-1675	140	82	s	s	PROPN
eurjchem-1675	140	83	,	,	PUNCT
eurjchem-1675	140	84	1h	1h	NUM
eurjchem-1675	140	85	,	,	PUNCT
eurjchem-1675	140	86	hn	hn	PROPN
eurjchem-1675	140	87	d2o	d2o	NOUN
eurjchem-1675	140	88	-	-	PUNCT
eurjchem-1675	140	89	exchangable	exchangable	ADJ
eurjchem-1675	140	90	)	)	PUNCT
eurjchem-1675	140	91	,	,	PUNCT
eurjchem-1675	140	92	9.66	9.66	NUM
eurjchem-1675	140	93	(	(	PUNCT
eurjchem-1675	140	94	s	s	PROPN
eurjchem-1675	140	95	,	,	PUNCT
eurjchem-1675	140	96	1h	1h	NUM
eurjchem-1675	140	97	,	,	PUNCT
eurjchem-1675	140	98	hn	hn	PROPN
eurjchem-1675	140	99	,	,	PUNCT
eurjchem-1675	140	100	d2o	d2o	NOUN
eurjchem-1675	140	101	-	-	ADJ
eurjchem-1675	140	102	exchangable	exchangable	ADJ
eurjchem-1675	140	103	)	)	PUNCT
eurjchem-1675	140	104	.	.	PUNCT
eurjchem-1675	141	1	13c	13c	NOUN
eurjchem-1675	141	2	nmr	nmr	NOUN
eurjchem-1675	141	3	(	(	PUNCT
eurjchem-1675	141	4	75	75	NUM
eurjchem-1675	141	5	mhz	mhz	NOUN
eurjchem-1675	141	6	,	,	PUNCT
eurjchem-1675	141	7	dmso	dmso	NOUN
eurjchem-1675	141	8	-	-	NOUN
eurjchem-1675	141	9	d6	d6	NOUN
eurjchem-1675	141	10	,	,	PUNCT
eurjchem-1675	141	11	δ	δ	PROPN
eurjchem-1675	141	12	,	,	PUNCT
eurjchem-1675	141	13	ppm	ppm	NUM
eurjchem-1675	141	14	):	):	PUNCT
eurjchem-1675	141	15	14.3	14.3	NUM
eurjchem-1675	141	16	(	(	PUNCT
eurjchem-1675	141	17	ch3	ch3	PROPN
eurjchem-1675	141	18	)	)	PUNCT
eurjchem-1675	141	19	,	,	PUNCT
eurjchem-1675	141	20	24.3	24.3	NUM
eurjchem-1675	141	21	(	(	PUNCT
eurjchem-1675	141	22	ch2	ch2	PROPN
eurjchem-1675	141	23	)	)	PUNCT
eurjchem-1675	141	24	,	,	PUNCT
eurjchem-1675	141	25	28.3	28.3	NUM
eurjchem-1675	141	26	(	(	PUNCT
eurjchem-1675	141	27	ch2	ch2	PROPN
eurjchem-1675	141	28	)	)	PUNCT
eurjchem-1675	141	29	,	,	PUNCT
eurjchem-1675	141	30	48.3	48.3	NUM
eurjchem-1675	141	31	(	(	PUNCT
eurjchem-1675	141	32	ch	ch	NOUN
eurjchem-1675	141	33	)	)	PUNCT
eurjchem-1675	141	34	,	,	PUNCT
eurjchem-1675	141	35	60.3	60.3	NUM
eurjchem-1675	141	36	(	(	PUNCT
eurjchem-1675	141	37	ch2	ch2	PROPN
eurjchem-1675	141	38	)	)	PUNCT
eurjchem-1675	141	39	,	,	PUNCT
eurjchem-1675	141	40	103.7	103.7	NUM
eurjchem-1675	141	41	(	(	PUNCT
eurjchem-1675	141	42	ch	ch	NOUN
eurjchem-1675	141	43	)	)	PUNCT
eurjchem-1675	141	44	116.2	116.2	NUM
eurjchem-1675	141	45	(	(	PUNCT
eurjchem-1675	141	46	ch	ch	NOUN
eurjchem-1675	141	47	)	)	PUNCT
eurjchem-1675	141	48	,	,	PUNCT
eurjchem-1675	141	49	118.6	118.6	NUM
eurjchem-1675	141	50	(	(	PUNCT
eurjchem-1675	141	51	ch	ch	NOUN
eurjchem-1675	141	52	)	)	PUNCT
eurjchem-1675	141	53	,	,	PUNCT
eurjchem-1675	141	54	120.5	120.5	NUM
eurjchem-1675	141	55	(	(	PUNCT
eurjchem-1675	141	56	ch	ch	NOUN
eurjchem-1675	141	57	)	)	PUNCT
eurjchem-1675	141	58	,	,	PUNCT
eurjchem-1675	141	59	129.3	129.3	NUM
eurjchem-1675	141	60	(	(	PUNCT
eurjchem-1675	141	61	ch	ch	NOUN
eurjchem-1675	141	62	)	)	PUNCT
eurjchem-1675	141	63	,	,	PUNCT
eurjchem-1675	141	64	133.3	133.3	NUM
eurjchem-1675	141	65	(	(	PUNCT
eurjchem-1675	141	66	ch	ch	NOUN
eurjchem-1675	141	67	)	)	PUNCT
eurjchem-1675	141	68	,	,	PUNCT
eurjchem-1675	141	69	143.2	143.2	NUM
eurjchem-1675	141	70	(	(	PUNCT
eurjchem-1675	141	71	ch	ch	NOUN
eurjchem-1675	141	72	)	)	PUNCT
eurjchem-1675	141	73	,	,	PUNCT
eurjchem-1675	141	74	160	160	NUM
eurjchem-1675	141	75	(	(	PUNCT
eurjchem-1675	141	76	c	c	NOUN
eurjchem-1675	141	77	=	=	SYM
eurjchem-1675	141	78	s	s	NOUN
eurjchem-1675	141	79	)	)	PUNCT
eurjchem-1675	141	80	,	,	PUNCT
eurjchem-1675	141	81	167.2	167.2	NUM
eurjchem-1675	141	82	(	(	PUNCT
eurjchem-1675	141	83	ch=	ch=	PROPN
eurjchem-1675	141	84	)	)	PUNCT
eurjchem-1675	141	85	,	,	PUNCT
eurjchem-1675	141	86	169.2	169.2	NUM
eurjchem-1675	141	87	(	(	PUNCT
eurjchem-1675	141	88	c	c	NOUN
eurjchem-1675	141	89	=	=	NOUN
eurjchem-1675	141	90	o	o	NOUN
eurjchem-1675	141	91	)	)	PUNCT
eurjchem-1675	141	92	.	.	PUNCT
eurjchem-1675	142	1	ms	ms	NOUN
eurjchem-1675	142	2	(	(	PUNCT
eurjchem-1675	142	3	m	m	PROPN
eurjchem-1675	142	4	/	/	SYM
eurjchem-1675	142	5	z	z	NOUN
eurjchem-1675	142	6	(	(	PUNCT
eurjchem-1675	142	7	%	%	NOUN
eurjchem-1675	142	8	)	)	PUNCT
eurjchem-1675	142	9	):	):	PUNCT
eurjchem-1675	142	10	387	387	NUM
eurjchem-1675	142	11	(	(	PUNCT
eurjchem-1675	142	12	m+	m+	NUM
eurjchem-1675	142	13	,	,	PUNCT
eurjchem-1675	142	14	100.0	100.0	NUM
eurjchem-1675	142	15	)	)	PUNCT
eurjchem-1675	142	16	,	,	PUNCT
eurjchem-1675	142	17	341	341	NUM
eurjchem-1675	142	18	(	(	PUNCT
eurjchem-1675	142	19	18.3	18.3	NUM
eurjchem-1675	142	20	)	)	PUNCT
eurjchem-1675	142	21	,	,	PUNCT
eurjchem-1675	142	22	288	288	NUM
eurjchem-1675	142	23	(	(	PUNCT
eurjchem-1675	142	24	7.5	7.5	NUM
eurjchem-1675	142	25	)	)	PUNCT
eurjchem-1675	142	26	.	.	PUNCT
eurjchem-1675	143	1	anal	anal	PROPN
eurjchem-1675	143	2	.	.	PUNCT
eurjchem-1675	143	3	calcd	calcd	NOUN
eurjchem-1675	143	4	.	.	PUNCT
eurjchem-1675	144	1	for	for	SCONJ
eurjchem-1675	144	2	c20h25n3o3s	c20h25n3o3	NOUN
eurjchem-1675	144	3	:	:	PUNCT
eurjchem-1675	144	4	c	c	NOUN
eurjchem-1675	144	5	,	,	PUNCT
eurjchem-1675	144	6	61.99	61.99	NUM
eurjchem-1675	144	7	;	;	PUNCT
eurjchem-1675	144	8	h	h	NOUN
eurjchem-1675	144	9	,	,	PUNCT
eurjchem-1675	144	10	6.50	6.50	NUM
eurjchem-1675	144	11	;	;	PUNCT
eurjchem-1675	144	12	n	n	CCONJ
eurjchem-1675	144	13	,	,	PUNCT
eurjchem-1675	144	14	10.84	10.84	NUM
eurjchem-1675	144	15	.	.	PUNCT
eurjchem-1675	144	16	found	find	VERB
eurjchem-1675	144	17	:	:	PUNCT
eurjchem-1675	145	1	c	c	X
eurjchem-1675	145	2	,	,	PUNCT
eurjchem-1675	145	3	61.92	61.92	NUM
eurjchem-1675	145	4	;	;	PUNCT
eurjchem-1675	145	5	h,6.46	h,6.46	PROPN
eurjchem-1675	145	6	;	;	PUNCT
eurjchem-1675	145	7	n	n	CCONJ
eurjchem-1675	145	8	,	,	PUNCT
eurjchem-1675	145	9	10.80	10.80	NUM
eurjchem-1675	145	10	%	%	NOUN
eurjchem-1675	145	11	.	.	PUNCT
eurjchem-1675	146	1	4	4	NUM
eurjchem-1675	146	2	-	-	PUNCT
eurjchem-1675	146	3	amino-5	amino-5	NUM
eurjchem-1675	146	4	-	-	PUNCT
eurjchem-1675	146	5	cyano	cyano	NOUN
eurjchem-1675	146	6	-	-	PUNCT
eurjchem-1675	146	7	n	n	CCONJ
eurjchem-1675	146	8	-	-	PUNCT
eurjchem-1675	146	9	cyclohexyl-2-(phenylamino	cyclohexyl-2-(phenylamino	NOUN
eurjchem-1675	146	10	)	)	PUNCT
eurjchem-1675	146	11	thiophene3	thiophene3	NOUN
eurjchem-1675	146	12	-	-	PUNCT
eurjchem-1675	146	13	carboxamide	carboxamide	NOUN
eurjchem-1675	146	14	(	(	PUNCT
eurjchem-1675	146	15	18	18	NUM
eurjchem-1675	146	16	):	):	PUNCT
eurjchem-1675	146	17	color	color	NOUN
eurjchem-1675	146	18	:	:	PUNCT
eurjchem-1675	146	19	yellow	yellow	ADJ
eurjchem-1675	146	20	.	.	PUNCT
eurjchem-1675	147	1	yield	yield	NOUN
eurjchem-1675	147	2	:	:	PUNCT
eurjchem-1675	147	3	75	75	NUM
eurjchem-1675	147	4	%	%	NOUN
eurjchem-1675	147	5	.	.	PUNCT
eurjchem-1675	148	1	m.p	m.p	PROPN
eurjchem-1675	148	2	.	.	PROPN
eurjchem-1675	148	3	:	:	PUNCT
eurjchem-1675	149	1	158	158	NUM
eurjchem-1675	149	2	-	-	SYM
eurjchem-1675	149	3	160	160	NUM
eurjchem-1675	149	4	°	°	NOUN
eurjchem-1675	149	5	c	c	NOUN
eurjchem-1675	149	6	.	.	PUNCT
eurjchem-1675	150	1	ft	ft	PROPN
eurjchem-1675	150	2	-	-	PUNCT
eurjchem-1675	150	3	ir	ir	PROPN
eurjchem-1675	150	4	(	(	PUNCT
eurjchem-1675	150	5	kbr	kbr	PROPN
eurjchem-1675	150	6	,	,	PUNCT
eurjchem-1675	150	7	ν	ν	PROPN
eurjchem-1675	150	8	,	,	PUNCT
eurjchem-1675	150	9	cm-1	cm-1	NUM
eurjchem-1675	150	10	):	):	PUNCT
eurjchem-1675	150	11	1650	1650	NUM
eurjchem-1675	150	12	(	(	PUNCT
eurjchem-1675	150	13	c	c	NOUN
eurjchem-1675	150	14	=	=	NOUN
eurjchem-1675	150	15	o	o	NOUN
eurjchem-1675	150	16	)	)	PUNCT
eurjchem-1675	150	17	,	,	PUNCT
eurjchem-1675	150	18	2250	2250	NUM
eurjchem-1675	150	19	(	(	PUNCT
eurjchem-1675	150	20	c	c	NOUN
eurjchem-1675	150	21	=	=	SYM
eurjchem-1675	150	22	n	n	NUM
eurjchem-1675	150	23	)	)	PUNCT
eurjchem-1675	150	24	,	,	PUNCT
eurjchem-1675	150	25	3250	3250	NUM
eurjchem-1675	150	26	(	(	PUNCT
eurjchem-1675	150	27	nh2	nh2	PROPN
eurjchem-1675	150	28	)	)	PUNCT
eurjchem-1675	150	29	,	,	PUNCT
eurjchem-1675	150	30	3428	3428	NUM
eurjchem-1675	150	31	(	(	PUNCT
eurjchem-1675	150	32	nh	nh	NOUN
eurjchem-1675	150	33	)	)	PUNCT
eurjchem-1675	150	34	.	.	PUNCT
eurjchem-1675	151	1	1h	1h	NUM
eurjchem-1675	151	2	nmr	nmr	NOUN
eurjchem-1675	151	3	(	(	PUNCT
eurjchem-1675	151	4	300	300	NUM
eurjchem-1675	151	5	mhz	mhz	NOUN
eurjchem-1675	151	6	,	,	PUNCT
eurjchem-1675	151	7	dmso	dmso	NOUN
eurjchem-1675	151	8	-	-	NOUN
eurjchem-1675	151	9	d6	d6	NOUN
eurjchem-1675	151	10	,	,	PUNCT
eurjchem-1675	151	11	δ	δ	PROPN
eurjchem-1675	151	12	,	,	PUNCT
eurjchem-1675	151	13	ppm	ppm	NUM
eurjchem-1675	151	14	):	):	PUNCT
eurjchem-1675	151	15	1.35	1.35	NUM
eurjchem-1675	151	16	-	-	SYM
eurjchem-1675	151	17	1.55	1.55	NUM
eurjchem-1675	151	18	(	(	PUNCT
eurjchem-1675	151	19	m	m	PROPN
eurjchem-1675	151	20	,	,	PUNCT
eurjchem-1675	151	21	10h	10h	NUM
eurjchem-1675	151	22	,	,	PUNCT
eurjchem-1675	151	23	h2c	h2c	PROPN
eurjchem-1675	151	24	)	)	PUNCT
eurjchem-1675	151	25	,	,	PUNCT
eurjchem-1675	151	26	3.481	3.481	NUM
eurjchem-1675	151	27	(	(	PUNCT
eurjchem-1675	151	28	s	s	PROPN
eurjchem-1675	151	29	,	,	PUNCT
eurjchem-1675	151	30	1h	1h	NUM
eurjchem-1675	151	31	,	,	PUNCT
eurjchem-1675	151	32	hc	hc	PROPN
eurjchem-1675	151	33	-	-	PUNCT
eurjchem-1675	151	34	nh	nh	NOUN
eurjchem-1675	151	35	)	)	PUNCT
eurjchem-1675	151	36	,	,	PUNCT
eurjchem-1675	151	37	6.60	6.60	NUM
eurjchem-1675	151	38	(	(	PUNCT
eurjchem-1675	151	39	s	s	NOUN
eurjchem-1675	151	40	,	,	PUNCT
eurjchem-1675	151	41	2h	2h	NUM
eurjchem-1675	151	42	,	,	PUNCT
eurjchem-1675	151	43	h2n	h2n	PROPN
eurjchem-1675	151	44	d2oexchangable	d2oexchangable	ADJ
eurjchem-1675	151	45	)	)	PUNCT
eurjchem-1675	151	46	,	,	PUNCT
eurjchem-1675	151	47	7.02	7.02	NUM
eurjchem-1675	151	48	-	-	SYM
eurjchem-1675	151	49	7.21	7.21	NUM
eurjchem-1675	151	50	(	(	PUNCT
eurjchem-1675	151	51	m	m	PROPN
eurjchem-1675	151	52	,	,	PUNCT
eurjchem-1675	151	53	5h	5h	NUM
eurjchem-1675	151	54	,	,	PUNCT
eurjchem-1675	151	55	ar	ar	NOUN
eurjchem-1675	151	56	-	-	NOUN
eurjchem-1675	151	57	h	h	NOUN
eurjchem-1675	151	58	)	)	PUNCT
eurjchem-1675	151	59	,	,	PUNCT
eurjchem-1675	151	60	7.862	7.862	NUM
eurjchem-1675	151	61	(	(	PUNCT
eurjchem-1675	151	62	s	s	PROPN
eurjchem-1675	151	63	,	,	PUNCT
eurjchem-1675	151	64	1h	1h	NUM
eurjchem-1675	151	65	,	,	PUNCT
eurjchem-1675	151	66	hn	hn	PROPN
eurjchem-1675	151	67	d2oexchangable	d2oexchangable	PROPN
eurjchem-1675	151	68	)	)	PUNCT
eurjchem-1675	151	69	,	,	PUNCT
eurjchem-1675	151	70	9.60	9.60	NUM
eurjchem-1675	151	71	(	(	PUNCT
eurjchem-1675	151	72	s	s	PROPN
eurjchem-1675	151	73	,	,	PUNCT
eurjchem-1675	151	74	1h	1h	NUM
eurjchem-1675	151	75	,	,	PUNCT
eurjchem-1675	151	76	hn	hn	PROPN
eurjchem-1675	151	77	d2o	d2o	NOUN
eurjchem-1675	151	78	-	-	PUNCT
eurjchem-1675	151	79	exchangable	exchangable	ADJ
eurjchem-1675	151	80	)	)	PUNCT
eurjchem-1675	151	81	.	.	PUNCT
eurjchem-1675	152	1	13c	13c	NOUN
eurjchem-1675	152	2	nmr	nmr	NOUN
eurjchem-1675	152	3	(	(	PUNCT
eurjchem-1675	152	4	75	75	NUM
eurjchem-1675	152	5	mhz	mhz	NOUN
eurjchem-1675	152	6	,	,	PUNCT
eurjchem-1675	152	7	dmso	dmso	NOUN
eurjchem-1675	152	8	-	-	NOUN
eurjchem-1675	152	9	d6	d6	NOUN
eurjchem-1675	152	10	,	,	PUNCT
eurjchem-1675	152	11	δ	δ	PROPN
eurjchem-1675	152	12	,	,	PUNCT
eurjchem-1675	152	13	ppm	ppm	NUM
eurjchem-1675	152	14	):	):	PUNCT
eurjchem-1675	152	15	24.6	24.6	NUM
eurjchem-1675	152	16	(	(	PUNCT
eurjchem-1675	152	17	ch2	ch2	PROPN
eurjchem-1675	152	18	)	)	PUNCT
eurjchem-1675	152	19	,	,	PUNCT
eurjchem-1675	152	20	28.3	28.3	NUM
eurjchem-1675	152	21	(	(	PUNCT
eurjchem-1675	152	22	ch2	ch2	PROPN
eurjchem-1675	152	23	)	)	PUNCT
eurjchem-1675	152	24	,	,	PUNCT
eurjchem-1675	152	25	47.6	47.6	NUM
eurjchem-1675	152	26	(	(	PUNCT
eurjchem-1675	152	27	ch	ch	NOUN
eurjchem-1675	152	28	)	)	PUNCT
eurjchem-1675	152	29	,	,	PUNCT
eurjchem-1675	152	30	85.3	85.3	NUM
eurjchem-1675	152	31	(	(	PUNCT
eurjchem-1675	152	32	ch	ch	NOUN
eurjchem-1675	152	33	)	)	PUNCT
eurjchem-1675	152	34	,	,	PUNCT
eurjchem-1675	152	35	115.3	115.3	NUM
eurjchem-1675	152	36	(	(	PUNCT
eurjchem-1675	152	37	cn	cn	PROPN
eurjchem-1675	152	38	)	)	PUNCT
eurjchem-1675	152	39	,	,	PUNCT
eurjchem-1675	152	40	116.2	116.2	NUM
eurjchem-1675	152	41	(	(	PUNCT
eurjchem-1675	152	42	ch	ch	NOUN
eurjchem-1675	152	43	)	)	PUNCT
eurjchem-1675	152	44	,	,	PUNCT
eurjchem-1675	152	45	118.6	118.6	NUM
eurjchem-1675	152	46	(	(	PUNCT
eurjchem-1675	152	47	ch	ch	NOUN
eurjchem-1675	152	48	)	)	PUNCT
eurjchem-1675	152	49	,	,	PUNCT
eurjchem-1675	152	50	129.3	129.3	NUM
eurjchem-1675	152	51	(	(	PUNCT
eurjchem-1675	152	52	ch	ch	NOUN
eurjchem-1675	152	53	)	)	PUNCT
eurjchem-1675	152	54	,	,	PUNCT
eurjchem-1675	152	55	133.3	133.3	NUM
eurjchem-1675	152	56	(	(	PUNCT
eurjchem-1675	152	57	ch	ch	NOUN
eurjchem-1675	152	58	)	)	PUNCT
eurjchem-1675	152	59	,	,	PUNCT
eurjchem-1675	152	60	138.2	138.2	NUM
eurjchem-1675	152	61	(	(	PUNCT
eurjchem-1675	152	62	ch	ch	NOUN
eurjchem-1675	152	63	)	)	PUNCT
eurjchem-1675	152	64	,	,	PUNCT
eurjchem-1675	152	65	168.4	168.4	NUM
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eurjchem-1675	152	67	c	c	NOUN
eurjchem-1675	152	68	=	=	NOUN
eurjchem-1675	152	69	o	o	NOUN
eurjchem-1675	152	70	)	)	PUNCT
eurjchem-1675	152	71	.	.	PUNCT
eurjchem-1675	153	1	ms	ms	NOUN
eurjchem-1675	153	2	(	(	PUNCT
eurjchem-1675	153	3	m	m	PROPN
eurjchem-1675	153	4	/	/	SYM
eurjchem-1675	153	5	z	z	NOUN
eurjchem-1675	153	6	(	(	PUNCT
eurjchem-1675	153	7	%	%	NOUN
eurjchem-1675	153	8	)	)	PUNCT
eurjchem-1675	153	9	):	):	PUNCT
eurjchem-1675	153	10	340	340	NUM
eurjchem-1675	153	11	(	(	PUNCT
eurjchem-1675	153	12	m+	m+	NUM
eurjchem-1675	153	13	,	,	PUNCT
eurjchem-1675	153	14	100.0	100.0	NUM
eurjchem-1675	153	15	)	)	PUNCT
eurjchem-1675	153	16	,	,	PUNCT
eurjchem-1675	153	17	257	257	NUM
eurjchem-1675	153	18	(	(	PUNCT
eurjchem-1675	153	19	14.3	14.3	NUM
eurjchem-1675	153	20	)	)	PUNCT
eurjchem-1675	153	21	,	,	PUNCT
eurjchem-1675	153	22	123.2	123.2	NUM
eurjchem-1675	153	23	(	(	PUNCT
eurjchem-1675	153	24	15.3	15.3	NUM
eurjchem-1675	153	25	)	)	PUNCT
eurjchem-1675	153	26	.	.	PUNCT
eurjchem-1675	154	1	anal	anal	PROPN
eurjchem-1675	154	2	.	.	PUNCT
eurjchem-1675	154	3	calcd	calcd	NOUN
eurjchem-1675	154	4	.	.	PUNCT
eurjchem-1675	155	1	for	for	ADP
eurjchem-1675	155	2	c18h20n4os	c18h20n4os	PROPN
eurjchem-1675	155	3	:	:	PUNCT
eurjchem-1675	155	4	c	c	X
eurjchem-1675	155	5	,	,	PUNCT
eurjchem-1675	155	6	63.50	63.50	NUM
eurjchem-1675	155	7	;	;	PUNCT
eurjchem-1675	155	8	h	h	NOUN
eurjchem-1675	155	9	,	,	PUNCT
eurjchem-1675	155	10	5.92	5.92	NUM
eurjchem-1675	155	11	;	;	PUNCT
eurjchem-1675	155	12	n	n	CCONJ
eurjchem-1675	155	13	,	,	PUNCT
eurjchem-1675	155	14	16.46	16.46	NUM
eurjchem-1675	155	15	.	.	PUNCT
eurjchem-1675	156	1	found	find	VERB
eurjchem-1675	156	2	:	:	PUNCT
eurjchem-1675	157	1	c	c	X
eurjchem-1675	157	2	,	,	PUNCT
eurjchem-1675	157	3	63.54	63.54	NUM
eurjchem-1675	157	4	;	;	PUNCT
eurjchem-1675	157	5	h	h	NOUN
eurjchem-1675	157	6	,	,	PUNCT
eurjchem-1675	157	7	5.96	5.96	NUM
eurjchem-1675	157	8	;	;	PUNCT
eurjchem-1675	157	9	n	n	CCONJ
eurjchem-1675	157	10	,	,	PUNCT
eurjchem-1675	157	11	16.48	16.48	NUM
eurjchem-1675	157	12	%	%	NOUN
eurjchem-1675	157	13	.	.	PUNCT
eurjchem-1675	158	1	2	2	NUM
eurjchem-1675	158	2	-	-	PUNCT
eurjchem-1675	158	3	cyano	cyano	NOUN
eurjchem-1675	158	4	-	-	PUNCT
eurjchem-1675	158	5	n	n	CCONJ
eurjchem-1675	158	6	-	-	PUNCT
eurjchem-1675	158	7	cyclohexyl-2-(4	cyclohexyl-2-(4	VERB
eurjchem-1675	158	8	-	-	PUNCT
eurjchem-1675	158	9	methyl-3	methyl-3	NUM
eurjchem-1675	158	10	-	-	PUNCT
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eurjchem-1675	158	12	(	(	PUNCT
eurjchem-1675	158	13	21	21	NUM
eurjchem-1675	158	14	):	):	PUNCT
eurjchem-1675	159	1	color	color	NOUN
eurjchem-1675	159	2	:	:	PUNCT
eurjchem-1675	159	3	brown	brown	ADJ
eurjchem-1675	159	4	.	.	PUNCT
eurjchem-1675	159	5	yield	yield	NOUN
eurjchem-1675	159	6	:	:	PUNCT
eurjchem-1675	159	7	85	85	NUM
eurjchem-1675	159	8	%	%	NOUN
eurjchem-1675	159	9	.	.	PUNCT
eurjchem-1675	160	1	m.p	m.p	PROPN
eurjchem-1675	160	2	.	.	PROPN
eurjchem-1675	160	3	:	:	PUNCT
eurjchem-1675	160	4	210212	210212	NUM
eurjchem-1675	160	5	°	°	SYM
eurjchem-1675	160	6	c	c	NOUN
eurjchem-1675	160	7	.	.	PUNCT
eurjchem-1675	160	8	ft	ft	PROPN
eurjchem-1675	160	9	-	-	PUNCT
eurjchem-1675	160	10	ir	ir	PROPN
eurjchem-1675	160	11	(	(	PUNCT
eurjchem-1675	160	12	kbr	kbr	PROPN
eurjchem-1675	160	13	,	,	PUNCT
eurjchem-1675	160	14	ν	ν	PROPN
eurjchem-1675	160	15	,	,	PUNCT
eurjchem-1675	160	16	cm-1	cm-1	NUM
eurjchem-1675	160	17	):	):	PUNCT
eurjchem-1675	160	18	1616	1616	NUM
eurjchem-1675	160	19	(	(	PUNCT
eurjchem-1675	160	20	c	c	NOUN
eurjchem-1675	160	21	=	=	NOUN
eurjchem-1675	160	22	o	o	NOUN
eurjchem-1675	160	23	)	)	PUNCT
eurjchem-1675	160	24	,	,	PUNCT
eurjchem-1675	160	25	2163	2163	NUM
eurjchem-1675	160	26	(	(	PUNCT
eurjchem-1675	160	27	c	c	NOUN
eurjchem-1675	160	28	=	=	SYM
eurjchem-1675	160	29	n	n	NUM
eurjchem-1675	160	30	)	)	PUNCT
eurjchem-1675	160	31	,	,	PUNCT
eurjchem-1675	160	32	3419	3419	NUM
eurjchem-1675	160	33	(	(	PUNCT
eurjchem-1675	160	34	nh	nh	NOUN
eurjchem-1675	160	35	)	)	PUNCT
eurjchem-1675	160	36	.	.	PUNCT
eurjchem-1675	161	1	1h	1h	NUM
eurjchem-1675	161	2	nmr	nmr	NOUN
eurjchem-1675	161	3	(	(	PUNCT
eurjchem-1675	161	4	300	300	NUM
eurjchem-1675	161	5	mhz	mhz	NOUN
eurjchem-1675	161	6	,	,	PUNCT
eurjchem-1675	161	7	dmso	dmso	NOUN
eurjchem-1675	161	8	-	-	NOUN
eurjchem-1675	161	9	d6	d6	NOUN
eurjchem-1675	161	10	,	,	PUNCT
eurjchem-1675	161	11	δ	δ	PROPN
eurjchem-1675	161	12	,	,	PUNCT
eurjchem-1675	161	13	ppm	ppm	NUM
eurjchem-1675	161	14	):	):	PUNCT
eurjchem-1675	161	15	1.03	1.03	NUM
eurjchem-1675	161	16	-	-	SYM
eurjchem-1675	161	17	1.09	1.09	NUM
eurjchem-1675	161	18	(	(	PUNCT
eurjchem-1675	161	19	m	m	PROPN
eurjchem-1675	161	20	,	,	PUNCT
eurjchem-1675	161	21	10h	10h	NUM
eurjchem-1675	161	22	,	,	PUNCT
eurjchem-1675	161	23	h2c	h2c	PROPN
eurjchem-1675	161	24	)	)	PUNCT
eurjchem-1675	161	25	,	,	PUNCT
eurjchem-1675	161	26	2.08	2.08	NUM
eurjchem-1675	161	27	(	(	PUNCT
eurjchem-1675	161	28	s	s	PROPN
eurjchem-1675	161	29	,	,	PUNCT
eurjchem-1675	161	30	3h	3h	NUM
eurjchem-1675	161	31	,	,	PUNCT
eurjchem-1675	161	32	h3c	h3c	PROPN
eurjchem-1675	161	33	)	)	PUNCT
eurjchem-1675	161	34	,	,	PUNCT
eurjchem-1675	161	35	3.57	3.57	NUM
eurjchem-1675	161	36	(	(	PUNCT
eurjchem-1675	161	37	s	s	PROPN
eurjchem-1675	161	38	,	,	PUNCT
eurjchem-1675	161	39	1h	1h	NUM
eurjchem-1675	161	40	,	,	PUNCT
eurjchem-1675	161	41	hc	hc	PROPN
eurjchem-1675	161	42	-	-	PUNCT
eurjchem-1675	161	43	nh	nh	NOUN
eurjchem-1675	161	44	)	)	PUNCT
eurjchem-1675	161	45	,	,	PUNCT
eurjchem-1675	161	46	6.77	6.77	NUM
eurjchem-1675	161	47	(	(	PUNCT
eurjchem-1675	161	48	s	s	PROPN
eurjchem-1675	161	49	,	,	PUNCT
eurjchem-1675	161	50	1h	1h	NUM
eurjchem-1675	161	51	,	,	PUNCT
eurjchem-1675	161	52	hc=	hc=	NOUN
eurjchem-1675	161	53	)	)	PUNCT
eurjchem-1675	161	54	,	,	PUNCT
eurjchem-1675	161	55	7.41	7.41	NUM
eurjchem-1675	161	56	-	-	SYM
eurjchem-1675	161	57	7.51	7.51	NUM
eurjchem-1675	161	58	(	(	PUNCT
eurjchem-1675	161	59	m	m	PROPN
eurjchem-1675	161	60	,	,	PUNCT
eurjchem-1675	161	61	5h	5h	NUM
eurjchem-1675	161	62	,	,	PUNCT
eurjchem-1675	161	63	ar	ar	NOUN
eurjchem-1675	161	64	-	-	NOUN
eurjchem-1675	161	65	h	h	NOUN
eurjchem-1675	161	66	)	)	PUNCT
eurjchem-1675	161	67	,	,	PUNCT
eurjchem-1675	161	68	7.801	7.801	NUM
eurjchem-1675	161	69	(	(	PUNCT
eurjchem-1675	161	70	s	s	PROPN
eurjchem-1675	161	71	,	,	PUNCT
eurjchem-1675	161	72	1h	1h	NUM
eurjchem-1675	161	73	,	,	PUNCT
eurjchem-1675	161	74	hn	hn	PROPN
eurjchem-1675	161	75	d2o	d2o	NOUN
eurjchem-1675	161	76	-	-	PUNCT
eurjchem-1675	161	77	exchangable	exchangable	ADJ
eurjchem-1675	161	78	)	)	PUNCT
eurjchem-1675	161	79	.	.	PUNCT
eurjchem-1675	162	1	13c	13c	NOUN
eurjchem-1675	162	2	nmr	nmr	NOUN
eurjchem-1675	162	3	(	(	PUNCT
eurjchem-1675	162	4	75	75	NUM
eurjchem-1675	162	5	mhz	mhz	NOUN
eurjchem-1675	162	6	,	,	PUNCT
eurjchem-1675	162	7	dmso	dmso	NOUN
eurjchem-1675	162	8	-	-	NOUN
eurjchem-1675	162	9	d6	d6	NOUN
eurjchem-1675	162	10	,	,	PUNCT
eurjchem-1675	162	11	δ	δ	PROPN
eurjchem-1675	162	12	,	,	PUNCT
eurjchem-1675	162	13	ppm	ppm	NUM
eurjchem-1675	162	14	):	):	PUNCT
eurjchem-1675	162	15	16.3	16.3	NUM
eurjchem-1675	162	16	(	(	PUNCT
eurjchem-1675	162	17	ch3	ch3	PROPN
eurjchem-1675	162	18	)	)	PUNCT
eurjchem-1675	162	19	,	,	PUNCT
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eurjchem-1675	162	21	(	(	PUNCT
eurjchem-1675	162	22	ch2	ch2	PROPN
eurjchem-1675	162	23	)	)	PUNCT
eurjchem-1675	162	24	,	,	PUNCT
eurjchem-1675	162	25	28.6	28.6	NUM
eurjchem-1675	162	26	(	(	PUNCT
eurjchem-1675	162	27	ch2	ch2	PROPN
eurjchem-1675	162	28	)	)	PUNCT
eurjchem-1675	162	29	,	,	PUNCT
eurjchem-1675	162	30	47.6	47.6	NUM
eurjchem-1675	162	31	(	(	PUNCT
eurjchem-1675	162	32	ch	ch	NOUN
eurjchem-1675	162	33	)	)	PUNCT
eurjchem-1675	162	34	,	,	PUNCT
eurjchem-1675	162	35	78.3	78.3	NUM
eurjchem-1675	162	36	(	(	PUNCT
eurjchem-1675	162	37	ch	ch	NOUN
eurjchem-1675	162	38	)	)	PUNCT
eurjchem-1675	162	39	,	,	PUNCT
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eurjchem-1675	162	41	(	(	PUNCT
eurjchem-1675	162	42	ch=	ch=	PROPN
eurjchem-1675	162	43	)	)	PUNCT
eurjchem-1675	162	44	,	,	PUNCT
eurjchem-1675	162	45	142.3	142.3	NUM
eurjchem-1675	162	46	(	(	PUNCT
eurjchem-1675	162	47	ch=	ch=	PROPN
eurjchem-1675	162	48	)	)	PUNCT
eurjchem-1675	162	49	,	,	PUNCT
eurjchem-1675	162	50	160.3	160.3	NUM
eurjchem-1675	162	51	(	(	PUNCT
eurjchem-1675	162	52	c	c	NOUN
eurjchem-1675	162	53	=	=	NOUN
eurjchem-1675	162	54	o	o	NOUN
eurjchem-1675	162	55	)	)	PUNCT
eurjchem-1675	162	56	,	,	PUNCT
eurjchem-1675	162	57	168.4	168.4	NUM
eurjchem-1675	162	58	(	(	PUNCT
eurjchem-1675	162	59	ch=	ch=	PROPN
eurjchem-1675	162	60	)	)	PUNCT
eurjchem-1675	162	61	.	.	PUNCT
eurjchem-1675	163	1	ms	ms	NOUN
eurjchem-1675	163	2	(	(	PUNCT
eurjchem-1675	163	3	m	m	PROPN
eurjchem-1675	163	4	/	/	SYM
eurjchem-1675	163	5	z	z	NOUN
eurjchem-1675	163	6	(	(	PUNCT
eurjchem-1675	163	7	%	%	NOUN
eurjchem-1675	163	8	)	)	PUNCT
eurjchem-1675	163	9	):	):	PUNCT
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eurjchem-1675	163	11	(	(	PUNCT
eurjchem-1675	163	12	m+	m+	NUM
eurjchem-1675	163	13	,	,	PUNCT
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eurjchem-1675	163	15	)	)	PUNCT
eurjchem-1675	163	16	,	,	PUNCT
eurjchem-1675	163	17	284	284	NUM
eurjchem-1675	163	18	(	(	PUNCT
eurjchem-1675	163	19	14.6	14.6	NUM
eurjchem-1675	163	20	)	)	PUNCT
eurjchem-1675	163	21	.	.	PUNCT
eurjchem-1675	164	1	anal	anal	PROPN
eurjchem-1675	164	2	.	.	PUNCT
eurjchem-1675	164	3	calcd	calcd	NOUN
eurjchem-1675	164	4	.	.	PUNCT
eurjchem-1675	165	1	for	for	SCONJ
eurjchem-1675	165	2	c19h21n3os	c19h21n3os	NOUN
eurjchem-1675	165	3	:	:	PUNCT
eurjchem-1675	165	4	c	c	X
eurjchem-1675	165	5	,	,	PUNCT
eurjchem-1675	165	6	67.23	67.23	NUM
eurjchem-1675	165	7	;	;	PUNCT
eurjchem-1675	165	8	h	h	NOUN
eurjchem-1675	165	9	,	,	PUNCT
eurjchem-1675	165	10	6.24	6.24	NUM
eurjchem-1675	165	11	;	;	PUNCT
eurjchem-1675	165	12	n	n	CCONJ
eurjchem-1675	165	13	,	,	PUNCT
eurjchem-1675	165	14	12.38	12.38	NUM
eurjchem-1675	165	15	.	.	PUNCT
eurjchem-1675	165	16	found	find	VERB
eurjchem-1675	165	17	:	:	PUNCT
eurjchem-1675	166	1	c	c	X
eurjchem-1675	166	2	,	,	PUNCT
eurjchem-1675	166	3	67.19	67.19	NUM
eurjchem-1675	166	4	;	;	PUNCT
eurjchem-1675	166	5	h	h	NOUN
eurjchem-1675	166	6	,	,	PUNCT
eurjchem-1675	166	7	6.26	6.26	NUM
eurjchem-1675	166	8	;	;	PUNCT
eurjchem-1675	166	9	n	n	CCONJ
eurjchem-1675	166	10	,	,	PUNCT
eurjchem-1675	166	11	12.39	12.39	NUM
eurjchem-1675	166	12	%	%	NOUN
eurjchem-1675	166	13	.	.	PUNCT
eurjchem-1675	167	1	2.7	2.7	NUM
eurjchem-1675	167	2	.	.	PUNCT
eurjchem-1675	168	1	reaction	reaction	NOUN
eurjchem-1675	168	2	of	of	ADP
eurjchem-1675	168	3	2	2	NUM
eurjchem-1675	168	4	-	-	PUNCT
eurjchem-1675	168	5	cyano	cyano	NOUN
eurjchem-1675	168	6	-	-	PUNCT
eurjchem-1675	168	7	n	n	CCONJ
eurjchem-1675	168	8	-	-	PUNCT
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eurjchem-1675	168	10	-	-	PUNCT
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eurjchem-1675	168	12	amino)acrylamide	amino)acrylamide	PROPN
eurjchem-1675	168	13	(	(	PUNCT
eurjchem-1675	168	14	9	9	NUM
eurjchem-1675	168	15	)	)	PUNCT
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eurjchem-1675	168	18	derivatives	derivative	NOUN
eurjchem-1675	168	19	thermal	thermal	ADJ
eurjchem-1675	168	20	method	method	NOUN
eurjchem-1675	168	21	:	:	PUNCT
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eurjchem-1675	168	24	of	of	ADP
eurjchem-1675	168	25	acrylamide	acrylamide	NOUN
eurjchem-1675	168	26	(	(	PUNCT
eurjchem-1675	168	27	9	9	NUM
eurjchem-1675	168	28	)	)	PUNCT
eurjchem-1675	168	29	(	(	PUNCT
eurjchem-1675	168	30	0.3	0.3	NUM
eurjchem-1675	168	31	g	g	NOUN
eurjchem-1675	168	32	,	,	PUNCT
eurjchem-1675	168	33	1	1	NUM
eurjchem-1675	168	34	mmol	mmol	NOUN
eurjchem-1675	168	35	)	)	PUNCT
eurjchem-1675	168	36	treated	treat	VERB
eurjchem-1675	168	37	with	with	ADP
eurjchem-1675	168	38	hydrazonyl	hydrazonyl	NOUN
eurjchem-1675	168	39	chloride	chloride	NOUN
eurjchem-1675	168	40	derivatives	derivative	NOUN
eurjchem-1675	168	41	(	(	PUNCT
eurjchem-1675	168	42	22a	22a	NOUN
eurjchem-1675	168	43	2018	2018	NUM
eurjchem-1675	168	44	–	–	PUNCT
eurjchem-1675	168	45	european	european	ADJ
eurjchem-1675	168	46	journal	journal	NOUN
eurjchem-1675	168	47	of	of	ADP
eurjchem-1675	168	48	chemistry	chemistry	NOUN
eurjchem-1675	168	49	–	–	PUNCT
eurjchem-1675	168	50	cc	cc	NOUN
eurjchem-1675	168	51	by	by	ADP
eurjchem-1675	168	52	nc	nc	PROPN
eurjchem-1675	168	53	–	–	PUNCT
eurjchem-1675	168	54	doi	doi	NOUN
eurjchem-1675	168	55	:	:	PUNCT
eurjchem-1675	168	56	10.5155	10.5155	NUM
eurjchem-1675	168	57	/	/	SYM
eurjchem-1675	168	58	eurjchem.9.1.30	eurjchem.9.1.30	NOUN
eurjchem-1675	168	59	-	-	SYM
eurjchem-1675	168	60	38.1675	38.1675	NUM
eurjchem-1675	168	61	34	34	NUM
eurjchem-1675	168	62	fahim	fahim	PROPN
eurjchem-1675	168	63	et	et	PROPN
eurjchem-1675	168	64	al	al	PROPN
eurjchem-1675	168	65	.	.	PUNCT
eurjchem-1675	168	66	/	/	SYM
eurjchem-1675	168	67	european	european	PROPN
eurjchem-1675	168	68	journal	journal	PROPN
eurjchem-1675	168	69	of	of	ADP
eurjchem-1675	168	70	chemistry	chemistry	NOUN
eurjchem-1675	168	71	9	9	NUM
eurjchem-1675	168	72	(	(	PUNCT
eurjchem-1675	168	73	1	1	NUM
eurjchem-1675	168	74	)	)	PUNCT
eurjchem-1675	168	75	(	(	PUNCT
eurjchem-1675	168	76	2018	2018	NUM
eurjchem-1675	168	77	)	)	PUNCT
eurjchem-1675	168	78	30	30	NUM
eurjchem-1675	168	79	-	-	SYM
eurjchem-1675	168	80	38	38	NUM
eurjchem-1675	168	81	n	n	NUM
eurjchem-1675	168	82	h	h	NOUN
eurjchem-1675	169	1	o	o	NOUN
eurjchem-1675	169	2	n	n	CCONJ
eurjchem-1675	169	3	h	h	NOUN
eurjchem-1675	170	1	o	o	NOUN
eurjchem-1675	170	2	c	c	NOUN
eurjchem-1675	171	1	n	n	NUM
eurjchem-1675	171	2	h	h	NOUN
eurjchem-1675	172	1	koh	koh	PROPN
eurjchem-1675	172	2	s	s	PROPN
eurjchem-1675	172	3	kph	kph	PROPN
eurjchem-1675	172	4	phncs	phncs	PROPN
eurjchem-1675	172	5	n	n	PROPN
eurjchem-1675	172	6	h	h	PROPN
eurjchem-1675	172	7	nc	nc	PROPN
eurjchem-1675	172	8	ar	ar	PROPN
eurjchem-1675	172	9	cl	cl	PROPN
eurjchem-1675	173	1	o	o	PROPN
eurjchem-1675	174	1	cn	cn	INTJ
eurjchem-1675	175	1	cn	cn	INTJ
eurjchem-1675	175	2	h	h	PROPN
eurjchem-1675	175	3	s	s	PART
eurjchem-1675	175	4	ph	ph	NOUN
eurjchem-1675	175	5	nroc	nroc	NOUN
eurjchem-1675	175	6	nhar	nhar	NOUN
eurjchem-1675	175	7	r	r	PROPN
eurjchem-1675	175	8	o	o	NOUN
eurjchem-1675	175	9	n	n	ADP
eurjchem-1675	175	10	s	s	NOUN
eurjchem-1675	175	11	n	n	PRON
eurjchem-1675	175	12	ph	ph	NOUN
eurjchem-1675	176	1	n	n	NOUN
eurjchem-1675	176	2	h	h	NOUN
eurjchem-1675	177	1	o	o	INTJ
eurjchem-1675	177	2	cn	cn	INTJ
eurjchem-1675	177	3	r	r	NOUN
eurjchem-1675	177	4	nhar	nhar	NOUN
eurjchem-1675	177	5	n	n	ADP
eurjchem-1675	177	6	n	n	PROPN
eurjchem-1675	177	7	s	s	PROPN
eurjchem-1675	177	8	cor	cor	PROPN
eurjchem-1675	177	9	ar	ar	PROPN
eurjchem-1675	177	10	n	n	PROPN
eurjchem-1675	177	11	h	h	NOUN
eurjchem-1675	178	1	o	o	NOUN
eurjchem-1675	178	2	cn	cn	INTJ
eurjchem-1675	178	3	26	26	NUM
eurjchem-1675	178	4	9	9	NUM
eurjchem-1675	178	5	23	23	NUM
eurjchem-1675	178	6	h	h	NOUN
eurjchem-1675	178	7	3	3	NUM
eurjchem-1675	178	8	h	h	NOUN
eurjchem-1675	178	9	h	h	NOUN
eurjchem-1675	179	1	h	h	NOUN
eurjchem-1675	180	1	d	d	NOUN
eurjchem-1675	180	2	,	,	PUNCT
eurjchem-1675	180	3	mw	mw	PROPN
eurjchem-1675	180	4	oc2h5	oc2h5	PROPN
eurjchem-1675	180	5	4	4	PROPN
eurjchem-1675	180	6	-	-	PUNCT
eurjchem-1675	180	7	clc6h4	clc6h4	NOUN
eurjchem-1675	180	8	oc2h5	oc2h5	PROPN
eurjchem-1675	181	1	oc2h5	oc2h5	PROPN
eurjchem-1675	181	2	c6h5	c6h5	PROPN
eurjchem-1675	181	3	r	r	NOUN
eurjchem-1675	181	4	ar	ar	NOUN
eurjchem-1675	181	5	a	a	PRON
eurjchem-1675	181	6	b	b	NOUN
eurjchem-1675	181	7	c	c	NOUN
eurjchem-1675	181	8	d	d	SYM
eurjchem-1675	181	9	4	4	NUM
eurjchem-1675	181	10	-	-	PUNCT
eurjchem-1675	181	11	ch3c6h4	ch3c6h4	PROPN
eurjchem-1675	181	12	4	4	NUM
eurjchem-1675	181	13	-	-	PUNCT
eurjchem-1675	181	14	ch3oc6h4	ch3oc6h4	NOUN
eurjchem-1675	181	15	c6h5	c6h5	PROPN
eurjchem-1675	181	16	24a	24a	NOUN
eurjchem-1675	181	17	-	-	NUM
eurjchem-1675	181	18	e	e	ADP
eurjchem-1675	181	19	e	e	PROPN
eurjchem-1675	181	20	oc2h5	oc2h5	PROPN
eurjchem-1675	181	21	c6h5	c6h5	PROPN
eurjchem-1675	181	22	22a	22a	NOUN
eurjchem-1675	181	23	-	-	SYM
eurjchem-1675	181	24	e	e	NOUN
eurjchem-1675	181	25	n	n	NOUN
eurjchem-1675	181	26	n	n	NOUN
eurjchem-1675	181	27	o	o	NOUN
eurjchem-1675	181	28	s	s	NOUN
eurjchem-1675	181	29	n	n	VERB
eurjchem-1675	181	30	n	n	PRON
eurjchem-1675	181	31	h	h	NOUN
eurjchem-1675	182	1	o	o	INTJ
eurjchem-1675	182	2	cn	cn	INTJ
eurjchem-1675	182	3	r	r	NOUN
eurjchem-1675	182	4	nhar	nhar	NOUN
eurjchem-1675	182	5	25	25	NUM
eurjchem-1675	182	6	h	h	NOUN
eurjchem-1675	182	7	-h2o	-h2o	NOUN
eurjchem-1675	182	8	-phnh2	-phnh2	NUM
eurjchem-1675	182	9	-	-	PUNCT
eurjchem-1675	182	10	phnh2	phnh2	NOUN
eurjchem-1675	182	11	h	h	NOUN
eurjchem-1675	182	12	scheme	scheme	NOUN
eurjchem-1675	182	13	4	4	NUM
eurjchem-1675	182	14	e	e	NOUN
eurjchem-1675	182	15	)	)	PUNCT
eurjchem-1675	182	16	(	(	PUNCT
eurjchem-1675	182	17	1	1	NUM
eurjchem-1675	182	18	mmol	mmol	NOUN
eurjchem-1675	182	19	)	)	PUNCT
eurjchem-1675	182	20	with	with	ADP
eurjchem-1675	182	21	little	little	ADJ
eurjchem-1675	182	22	amount	amount	NOUN
eurjchem-1675	182	23	of	of	ADP
eurjchem-1675	182	24	triethylamine	triethylamine	NOUN
eurjchem-1675	182	25	as	as	ADP
eurjchem-1675	182	26	a	a	DET
eurjchem-1675	182	27	catalyst	catalyst	NOUN
eurjchem-1675	182	28	formed	form	VERB
eurjchem-1675	182	29	green	green	PROPN
eurjchem-1675	182	30	solid	solid	ADV
eurjchem-1675	182	31	afterward	afterward	ADV
eurjchem-1675	182	32	reflux	reflux	NOUN
eurjchem-1675	182	33	for	for	ADP
eurjchem-1675	182	34	6	6	NUM
eurjchem-1675	182	35	h.	h.	NOUN
eurjchem-1675	182	36	the	the	DET
eurjchem-1675	182	37	solid	solid	ADJ
eurjchem-1675	182	38	product	product	NOUN
eurjchem-1675	182	39	formed	form	VERB
eurjchem-1675	182	40	and	and	CCONJ
eurjchem-1675	182	41	filtered	filter	VERB
eurjchem-1675	182	42	off	off	ADP
eurjchem-1675	182	43	,	,	PUNCT
eurjchem-1675	182	44	washed	wash	VERB
eurjchem-1675	182	45	with	with	ADP
eurjchem-1675	182	46	water	water	NOUN
eurjchem-1675	182	47	,	,	PUNCT
eurjchem-1675	182	48	dried	dry	VERB
eurjchem-1675	182	49	and	and	CCONJ
eurjchem-1675	182	50	finally	finally	ADV
eurjchem-1675	182	51	recrystallized	recrystallize	VERB
eurjchem-1675	182	52	from	from	ADP
eurjchem-1675	182	53	the	the	DET
eurjchem-1675	182	54	proper	proper	ADJ
eurjchem-1675	182	55	solvent	solvent	NOUN
eurjchem-1675	182	56	to	to	PART
eurjchem-1675	182	57	afford	afford	VERB
eurjchem-1675	182	58	compounds	compound	NOUN
eurjchem-1675	182	59	24a	24a	NOUN
eurjchem-1675	182	60	-	-	NUM
eurjchem-1675	182	61	e	e	X
eurjchem-1675	182	62	(	(	PUNCT
eurjchem-1675	182	63	scheme	scheme	NOUN
eurjchem-1675	182	64	4	4	NUM
eurjchem-1675	182	65	)	)	PUNCT
eurjchem-1675	182	66	.	.	PUNCT
eurjchem-1675	183	1	microwave	microwave	NOUN
eurjchem-1675	183	2	method	method	NOUN
eurjchem-1675	183	3	:	:	PUNCT
eurjchem-1675	183	4	acrylamide	acrylamide	NOUN
eurjchem-1675	183	5	solution	solution	NOUN
eurjchem-1675	183	6	(	(	PUNCT
eurjchem-1675	183	7	9	9	NUM
eurjchem-1675	183	8	)	)	PUNCT
eurjchem-1675	183	9	(	(	PUNCT
eurjchem-1675	183	10	0.3	0.3	NUM
eurjchem-1675	183	11	g	g	NOUN
eurjchem-1675	183	12	,	,	PUNCT
eurjchem-1675	183	13	1	1	NUM
eurjchem-1675	183	14	mmol	mmol	NOUN
eurjchem-1675	183	15	)	)	PUNCT
eurjchem-1675	183	16	reacts	react	NOUN
eurjchem-1675	183	17	with	with	ADP
eurjchem-1675	183	18	hydrazonyl	hydrazonyl	NOUN
eurjchem-1675	183	19	derivatives	derivative	NOUN
eurjchem-1675	183	20	22a	22a	NOUN
eurjchem-1675	183	21	-	-	SYM
eurjchem-1675	183	22	e	e	X
eurjchem-1675	183	23	(	(	PUNCT
eurjchem-1675	183	24	1	1	NUM
eurjchem-1675	183	25	mmol	mmol	NOUN
eurjchem-1675	183	26	)	)	PUNCT
eurjchem-1675	183	27	with	with	ADP
eurjchem-1675	183	28	few	few	ADJ
eurjchem-1675	183	29	drops	drop	NOUN
eurjchem-1675	183	30	of	of	ADP
eurjchem-1675	183	31	triethylamine	triethylamine	NOUN
eurjchem-1675	183	32	was	be	AUX
eurjchem-1675	183	33	mixed	mix	VERB
eurjchem-1675	183	34	in	in	ADP
eurjchem-1675	183	35	a	a	DET
eurjchem-1675	183	36	process	process	NOUN
eurjchem-1675	183	37	vial	vial	NOUN
eurjchem-1675	183	38	.	.	PUNCT
eurjchem-1675	184	1	the	the	DET
eurjchem-1675	184	2	vial	vial	ADJ
eurjchem-1675	184	3	capped	cap	VERB
eurjchem-1675	184	4	properly	properly	ADV
eurjchem-1675	184	5	and	and	CCONJ
eurjchem-1675	184	6	irradiated	irradiate	VERB
eurjchem-1675	184	7	by	by	ADP
eurjchem-1675	184	8	microwaves	microwave	NOUN
eurjchem-1675	184	9	using	use	VERB
eurjchem-1675	184	10	pressurized	pressurized	ADJ
eurjchem-1675	184	11	conditions	condition	NOUN
eurjchem-1675	184	12	(	(	PUNCT
eurjchem-1675	184	13	17.2	17.2	NUM
eurjchem-1675	184	14	bar	bar	NOUN
eurjchem-1675	184	15	,	,	PUNCT
eurjchem-1675	184	16	150	150	NUM
eurjchem-1675	184	17	°	°	NOUN
eurjchem-1675	184	18	c	c	NOUN
eurjchem-1675	184	19	)	)	PUNCT
eurjchem-1675	184	20	for	for	ADP
eurjchem-1675	184	21	20	20	NUM
eurjchem-1675	184	22	min	min	NOUN
eurjchem-1675	184	23	,	,	PUNCT
eurjchem-1675	184	24	the	the	DET
eurjchem-1675	184	25	reaction	reaction	NOUN
eurjchem-1675	184	26	mixture	mixture	NOUN
eurjchem-1675	184	27	was	be	AUX
eurjchem-1675	184	28	evaporated	evaporate	VERB
eurjchem-1675	184	29	in	in	ADP
eurjchem-1675	184	30	vacuo	vacuo	NOUN
eurjchem-1675	184	31	and	and	CCONJ
eurjchem-1675	184	32	residual	residual	ADJ
eurjchem-1675	184	33	solid	solid	NOUN
eurjchem-1675	184	34	was	be	AUX
eurjchem-1675	184	35	taken	take	VERB
eurjchem-1675	184	36	in	in	ADP
eurjchem-1675	184	37	ethanol	ethanol	NOUN
eurjchem-1675	184	38	then	then	ADV
eurjchem-1675	184	39	collected	collect	VERB
eurjchem-1675	184	40	by	by	ADP
eurjchem-1675	184	41	filteration	filteration	NOUN
eurjchem-1675	184	42	,	,	PUNCT
eurjchem-1675	184	43	washed	wash	VERB
eurjchem-1675	184	44	,	,	PUNCT
eurjchem-1675	184	45	dried	dry	VERB
eurjchem-1675	184	46	and	and	CCONJ
eurjchem-1675	184	47	finally	finally	ADV
eurjchem-1675	184	48	recrystalized	recrystalize	VERB
eurjchem-1675	184	49	from	from	ADP
eurjchem-1675	184	50	the	the	DET
eurjchem-1675	184	51	proper	proper	ADJ
eurjchem-1675	184	52	solvent	solvent	NOUN
eurjchem-1675	184	53	to	to	PART
eurjchem-1675	184	54	afford	afford	VERB
eurjchem-1675	184	55	the	the	DET
eurjchem-1675	184	56	corresponding	corresponding	ADJ
eurjchem-1675	184	57	compounds	compound	NOUN
eurjchem-1675	184	58	24a	24a	NOUN
eurjchem-1675	184	59	-	-	PROPN
eurjchem-1675	184	60	e.	e.	PROPN
eurjchem-1675	184	61	ethyl-4-(4	ethyl-4-(4	PROPN
eurjchem-1675	184	62	-	-	PUNCT
eurjchem-1675	184	63	chlorophenyl)-5-(1	chlorophenyl)-5-(1	NOUN
eurjchem-1675	184	64	-	-	PUNCT
eurjchem-1675	184	65	cyano-2-(cyclohexylamino)2	cyano-2-(cyclohexylamino)2	NOUN
eurjchem-1675	184	66	-	-	PUNCT
eurjchem-1675	184	67	oxoethylidene)-4	oxoethylidene)-4	ADJ
eurjchem-1675	184	68	,	,	PUNCT
eurjchem-1675	184	69	5	5	NUM
eurjchem-1675	184	70	-	-	SYM
eurjchem-1675	184	71	dihydro-1	dihydro-1	NUM
eurjchem-1675	184	72	,	,	PUNCT
eurjchem-1675	184	73	3	3	NUM
eurjchem-1675	184	74	,	,	PUNCT
eurjchem-1675	184	75	4	4	NUM
eurjchem-1675	184	76	-	-	PUNCT
eurjchem-1675	184	77	thiadiazole-2	thiadiazole-2	NUM
eurjchem-1675	184	78	-	-	PUNCT
eurjchem-1675	184	79	carboxylate	carboxylate	NOUN
eurjchem-1675	184	80	(	(	PUNCT
eurjchem-1675	184	81	24a	24a	NOUN
eurjchem-1675	184	82	):	):	PUNCT
eurjchem-1675	184	83	color	color	NOUN
eurjchem-1675	184	84	:	:	PUNCT
eurjchem-1675	184	85	yellow	yellow	ADJ
eurjchem-1675	184	86	powder	powder	NOUN
eurjchem-1675	184	87	.	.	PUNCT
eurjchem-1675	185	1	yield	yield	NOUN
eurjchem-1675	185	2	:	:	PUNCT
eurjchem-1675	185	3	75	75	NUM
eurjchem-1675	185	4	%	%	NOUN
eurjchem-1675	185	5	.	.	PUNCT
eurjchem-1675	186	1	m.p	m.p	PROPN
eurjchem-1675	186	2	.	.	PROPN
eurjchem-1675	186	3	:	:	PUNCT
eurjchem-1675	187	1	218	218	NUM
eurjchem-1675	187	2	-	-	SYM
eurjchem-1675	187	3	220	220	NUM
eurjchem-1675	187	4	°	°	NOUN
eurjchem-1675	187	5	c	c	NOUN
eurjchem-1675	187	6	.	.	PUNCT
eurjchem-1675	188	1	ftir	ftir	PROPN
eurjchem-1675	188	2	(	(	PUNCT
eurjchem-1675	188	3	kbr	kbr	PROPN
eurjchem-1675	188	4	,	,	PUNCT
eurjchem-1675	188	5	ν	ν	PROPN
eurjchem-1675	188	6	,	,	PUNCT
eurjchem-1675	188	7	cm-1	cm-1	NUM
eurjchem-1675	188	8	):	):	PUNCT
eurjchem-1675	188	9	1620	1620	NUM
eurjchem-1675	188	10	(	(	PUNCT
eurjchem-1675	188	11	c	c	NOUN
eurjchem-1675	188	12	=	=	NOUN
eurjchem-1675	188	13	o	o	NOUN
eurjchem-1675	188	14	)	)	PUNCT
eurjchem-1675	188	15	,	,	PUNCT
eurjchem-1675	188	16	2191	2191	NUM
eurjchem-1675	188	17	(	(	PUNCT
eurjchem-1675	188	18	c	c	NOUN
eurjchem-1675	188	19	=	=	SYM
eurjchem-1675	188	20	n	n	NUM
eurjchem-1675	188	21	)	)	PUNCT
eurjchem-1675	188	22	,	,	PUNCT
eurjchem-1675	188	23	3340	3340	NUM
eurjchem-1675	188	24	(	(	PUNCT
eurjchem-1675	188	25	nh	nh	NOUN
eurjchem-1675	188	26	)	)	PUNCT
eurjchem-1675	188	27	.	.	PUNCT
eurjchem-1675	189	1	1h	1h	NUM
eurjchem-1675	189	2	nmr	nmr	NOUN
eurjchem-1675	189	3	(	(	PUNCT
eurjchem-1675	189	4	300	300	NUM
eurjchem-1675	189	5	mhz	mhz	NOUN
eurjchem-1675	189	6	,	,	PUNCT
eurjchem-1675	189	7	dmso	dmso	NOUN
eurjchem-1675	189	8	-	-	NOUN
eurjchem-1675	189	9	d6	d6	NOUN
eurjchem-1675	189	10	,	,	PUNCT
eurjchem-1675	189	11	δ	δ	PROPN
eurjchem-1675	189	12	,	,	PUNCT
eurjchem-1675	189	13	ppm	ppm	NUM
eurjchem-1675	189	14	):	):	PUNCT
eurjchem-1675	189	15	1.32	1.32	NUM
eurjchem-1675	189	16	-	-	SYM
eurjchem-1675	189	17	1.42	1.42	NUM
eurjchem-1675	189	18	(	(	PUNCT
eurjchem-1675	189	19	m	m	PROPN
eurjchem-1675	189	20	,	,	PUNCT
eurjchem-1675	189	21	10h	10h	NUM
eurjchem-1675	189	22	,	,	PUNCT
eurjchem-1675	189	23	h2c	h2c	PROPN
eurjchem-1675	189	24	)	)	PUNCT
eurjchem-1675	189	25	,	,	PUNCT
eurjchem-1675	189	26	1.823	1.823	NUM
eurjchem-1675	189	27	(	(	PUNCT
eurjchem-1675	189	28	t	t	PROPN
eurjchem-1675	189	29	,	,	PUNCT
eurjchem-1675	189	30	3h	3h	NUM
eurjchem-1675	189	31	,	,	PUNCT
eurjchem-1675	189	32	h3c	h3c	PROPN
eurjchem-1675	189	33	)	)	PUNCT
eurjchem-1675	189	34	,	,	PUNCT
eurjchem-1675	189	35	3.531	3.531	NUM
eurjchem-1675	189	36	(	(	PUNCT
eurjchem-1675	189	37	s	s	PROPN
eurjchem-1675	189	38	,	,	PUNCT
eurjchem-1675	189	39	1h	1h	NUM
eurjchem-1675	189	40	,	,	PUNCT
eurjchem-1675	189	41	hc	hc	PROPN
eurjchem-1675	189	42	-	-	PUNCT
eurjchem-1675	189	43	nh	nh	NOUN
eurjchem-1675	189	44	)	)	PUNCT
eurjchem-1675	189	45	,	,	PUNCT
eurjchem-1675	189	46	4.20	4.20	NUM
eurjchem-1675	189	47	(	(	PUNCT
eurjchem-1675	189	48	q	q	NOUN
eurjchem-1675	189	49	,	,	PUNCT
eurjchem-1675	189	50	2h	2h	NUM
eurjchem-1675	189	51	,	,	PUNCT
eurjchem-1675	189	52	h2c	h2c	PROPN
eurjchem-1675	189	53	)	)	PUNCT
eurjchem-1675	189	54	,	,	PUNCT
eurjchem-1675	189	55	6.40	6.40	NUM
eurjchem-1675	189	56	-	-	SYM
eurjchem-1675	189	57	7.21	7.21	NUM
eurjchem-1675	189	58	(	(	PUNCT
eurjchem-1675	189	59	m	m	PROPN
eurjchem-1675	189	60	,	,	PUNCT
eurjchem-1675	189	61	4h	4h	NOUN
eurjchem-1675	189	62	,	,	PUNCT
eurjchem-1675	189	63	ar	ar	NOUN
eurjchem-1675	189	64	-	-	NOUN
eurjchem-1675	189	65	h	h	NOUN
eurjchem-1675	189	66	)	)	PUNCT
eurjchem-1675	189	67	,	,	PUNCT
eurjchem-1675	189	68	7.86	7.86	NUM
eurjchem-1675	189	69	(	(	PUNCT
eurjchem-1675	189	70	s	s	PROPN
eurjchem-1675	189	71	,	,	PUNCT
eurjchem-1675	189	72	1h	1h	NUM
eurjchem-1675	189	73	,	,	PUNCT
eurjchem-1675	189	74	hn	hn	PROPN
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eurjchem-1675	189	77	exchangable	exchangable	ADJ
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eurjchem-1675	190	3	(	(	PUNCT
eurjchem-1675	190	4	75	75	NUM
eurjchem-1675	190	5	mhz	mhz	NOUN
eurjchem-1675	190	6	,	,	PUNCT
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eurjchem-1675	190	8	-	-	NOUN
eurjchem-1675	190	9	d6	d6	NOUN
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eurjchem-1675	190	14	):	):	PUNCT
eurjchem-1675	190	15	12.3	12.3	NUM
eurjchem-1675	190	16	(	(	PUNCT
eurjchem-1675	190	17	ch3	ch3	PROPN
eurjchem-1675	190	18	)	)	PUNCT
eurjchem-1675	190	19	,	,	PUNCT
eurjchem-1675	190	20	22.3	22.3	NUM
eurjchem-1675	190	21	(	(	PUNCT
eurjchem-1675	190	22	ch2	ch2	PROPN
eurjchem-1675	190	23	)	)	PUNCT
eurjchem-1675	190	24	,	,	PUNCT
eurjchem-1675	190	25	28.6	28.6	NUM
eurjchem-1675	190	26	(	(	PUNCT
eurjchem-1675	190	27	ch2	ch2	PROPN
eurjchem-1675	190	28	)	)	PUNCT
eurjchem-1675	190	29	,	,	PUNCT
eurjchem-1675	190	30	47.6	47.6	NUM
eurjchem-1675	190	31	(	(	PUNCT
eurjchem-1675	190	32	ch	ch	NOUN
eurjchem-1675	190	33	)	)	PUNCT
eurjchem-1675	190	34	,	,	PUNCT
eurjchem-1675	190	35	60.3	60.3	NUM
eurjchem-1675	190	36	(	(	PUNCT
eurjchem-1675	190	37	ch2	ch2	PROPN
eurjchem-1675	190	38	)	)	PUNCT
eurjchem-1675	190	39	,	,	PUNCT
eurjchem-1675	190	40	87.3	87.3	NUM
eurjchem-1675	190	41	(	(	PUNCT
eurjchem-1675	190	42	ch=	ch=	PROPN
eurjchem-1675	190	43	)	)	PUNCT
eurjchem-1675	190	44	,	,	PUNCT
eurjchem-1675	190	45	115.3	115.3	NUM
eurjchem-1675	190	46	(	(	PUNCT
eurjchem-1675	190	47	cn	cn	PROPN
eurjchem-1675	190	48	)	)	PUNCT
eurjchem-1675	190	49	,	,	PUNCT
eurjchem-1675	190	50	117.3	117.3	NUM
eurjchem-1675	190	51	(	(	PUNCT
eurjchem-1675	190	52	ch	ch	NOUN
eurjchem-1675	190	53	)	)	PUNCT
eurjchem-1675	190	54	,	,	PUNCT
eurjchem-1675	190	55	124.3	124.3	NUM
eurjchem-1675	190	56	(	(	PUNCT
eurjchem-1675	190	57	ch	ch	NOUN
eurjchem-1675	190	58	)	)	PUNCT
eurjchem-1675	190	59	,	,	PUNCT
eurjchem-1675	190	60	129.3	129.3	NUM
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eurjchem-1675	190	62	ch	ch	NOUN
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eurjchem-1675	190	68	)	)	PUNCT
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eurjchem-1675	190	73	=	=	SYM
eurjchem-1675	190	74	s	s	PART
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eurjchem-1675	190	76	,	,	PUNCT
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eurjchem-1675	190	79	c	c	NOUN
eurjchem-1675	190	80	=	=	NOUN
eurjchem-1675	190	81	o	o	NOUN
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eurjchem-1675	190	83	,	,	PUNCT
eurjchem-1675	190	84	162.3	162.3	NUM
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eurjchem-1675	190	86	c	c	NOUN
eurjchem-1675	190	87	=	=	NOUN
eurjchem-1675	190	88	o	o	NOUN
eurjchem-1675	190	89	)	)	PUNCT
eurjchem-1675	190	90	.	.	PUNCT
eurjchem-1675	191	1	ms	ms	NOUN
eurjchem-1675	191	2	(	(	PUNCT
eurjchem-1675	191	3	m	m	PROPN
eurjchem-1675	191	4	/	/	SYM
eurjchem-1675	191	5	z	z	NOUN
eurjchem-1675	191	6	(	(	PUNCT
eurjchem-1675	191	7	%	%	NOUN
eurjchem-1675	191	8	)	)	PUNCT
eurjchem-1675	191	9	):	):	PUNCT
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eurjchem-1675	191	12	m+	m+	NUM
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eurjchem-1675	191	16	,	,	PUNCT
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eurjchem-1675	191	18	(	(	PUNCT
eurjchem-1675	191	19	36.8	36.8	NUM
eurjchem-1675	191	20	)	)	PUNCT
eurjchem-1675	191	21	.	.	PUNCT
eurjchem-1675	192	1	anal	anal	PROPN
eurjchem-1675	192	2	.	.	PUNCT
eurjchem-1675	192	3	calcd	calcd	NOUN
eurjchem-1675	192	4	.	.	PUNCT
eurjchem-1675	193	1	for	for	ADP
eurjchem-1675	193	2	c20h21cln4o3s	c20h21cln4o3s	ADJ
eurjchem-1675	193	3	:	:	PUNCT
eurjchem-1675	193	4	c	c	X
eurjchem-1675	193	5	,	,	PUNCT
eurjchem-1675	193	6	55.49	55.49	NUM
eurjchem-1675	193	7	;	;	PUNCT
eurjchem-1675	193	8	h	h	NOUN
eurjchem-1675	193	9	,	,	PUNCT
eurjchem-1675	193	10	4.89	4.89	NUM
eurjchem-1675	193	11	;	;	PUNCT
eurjchem-1675	193	12	n	n	CCONJ
eurjchem-1675	193	13	,	,	PUNCT
eurjchem-1675	193	14	12.94	12.94	NUM
eurjchem-1675	193	15	.	.	PUNCT
eurjchem-1675	193	16	found	find	VERB
eurjchem-1675	193	17	:	:	PUNCT
eurjchem-1675	194	1	c	c	X
eurjchem-1675	194	2	,	,	PUNCT
eurjchem-1675	194	3	55.52	55.52	NUM
eurjchem-1675	194	4	;	;	PUNCT
eurjchem-1675	194	5	h	h	NOUN
eurjchem-1675	194	6	,	,	PUNCT
eurjchem-1675	194	7	4.85	4.85	NUM
eurjchem-1675	194	8	;	;	PUNCT
eurjchem-1675	194	9	n	n	CCONJ
eurjchem-1675	194	10	,	,	PUNCT
eurjchem-1675	194	11	12.90	12.90	NUM
eurjchem-1675	194	12	%	%	NOUN
eurjchem-1675	194	13	.	.	PUNCT
eurjchem-1675	195	1	ethyl-5-(1	ethyl-5-(1	PROPN
eurjchem-1675	195	2	-	-	PUNCT
eurjchem-1675	195	3	cyano-2-(cyclohexylamino)-2	cyano-2-(cyclohexylamino)-2	NOUN
eurjchem-1675	195	4	-	-	PUNCT
eurjchem-1675	195	5	oxoethylidene)-4-(ptolyl)-4	oxoethylidene)-4-(ptolyl)-4	ADJ
eurjchem-1675	195	6	,	,	PUNCT
eurjchem-1675	195	7	5	5	NUM
eurjchem-1675	195	8	-	-	PUNCT
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eurjchem-1675	195	10	-	-	PUNCT
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eurjchem-1675	195	12	-	-	PUNCT
eurjchem-1675	195	13	carboxylate	carboxylate	NOUN
eurjchem-1675	195	14	(	(	PUNCT
eurjchem-1675	195	15	24b	24b	NUM
eurjchem-1675	195	16	):	):	PUNCT
eurjchem-1675	195	17	color	color	NOUN
eurjchem-1675	195	18	:	:	PUNCT
eurjchem-1675	195	19	pale	pale	ADJ
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eurjchem-1675	195	21	.	.	PUNCT
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eurjchem-1675	195	23	:	:	PUNCT
eurjchem-1675	195	24	70	70	NUM
eurjchem-1675	195	25	%	%	NOUN
eurjchem-1675	195	26	.	.	PUNCT
eurjchem-1675	196	1	m.p	m.p	PROPN
eurjchem-1675	196	2	.	.	PROPN
eurjchem-1675	196	3	:	:	PUNCT
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eurjchem-1675	197	2	-	-	SYM
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eurjchem-1675	197	7	ft	ft	PROPN
eurjchem-1675	197	8	-	-	PUNCT
eurjchem-1675	197	9	ir	ir	PROPN
eurjchem-1675	197	10	(	(	PUNCT
eurjchem-1675	197	11	kbr	kbr	PROPN
eurjchem-1675	197	12	,	,	PUNCT
eurjchem-1675	197	13	ν	ν	PROPN
eurjchem-1675	197	14	,	,	PUNCT
eurjchem-1675	197	15	cm-1	cm-1	NUM
eurjchem-1675	197	16	):	):	PUNCT
eurjchem-1675	197	17	1619	1619	NUM
eurjchem-1675	197	18	(	(	PUNCT
eurjchem-1675	197	19	c	c	NOUN
eurjchem-1675	197	20	=	=	NOUN
eurjchem-1675	197	21	o	o	NOUN
eurjchem-1675	197	22	)	)	PUNCT
eurjchem-1675	197	23	,	,	PUNCT
eurjchem-1675	197	24	2190	2190	NUM
eurjchem-1675	197	25	(	(	PUNCT
eurjchem-1675	197	26	c	c	NOUN
eurjchem-1675	197	27	=	=	SYM
eurjchem-1675	197	28	n	n	NUM
eurjchem-1675	197	29	)	)	PUNCT
eurjchem-1675	197	30	,	,	PUNCT
eurjchem-1675	197	31	3342	3342	NUM
eurjchem-1675	197	32	(	(	PUNCT
eurjchem-1675	197	33	nh	nh	NOUN
eurjchem-1675	197	34	)	)	PUNCT
eurjchem-1675	197	35	.	.	PUNCT
eurjchem-1675	198	1	1h	1h	NUM
eurjchem-1675	198	2	nmr	nmr	NOUN
eurjchem-1675	198	3	(	(	PUNCT
eurjchem-1675	198	4	300	300	NUM
eurjchem-1675	198	5	mhz	mhz	NOUN
eurjchem-1675	198	6	,	,	PUNCT
eurjchem-1675	198	7	dmso	dmso	NOUN
eurjchem-1675	198	8	-	-	NOUN
eurjchem-1675	198	9	d6	d6	NOUN
eurjchem-1675	198	10	,	,	PUNCT
eurjchem-1675	198	11	δ	δ	PROPN
eurjchem-1675	198	12	,	,	PUNCT
eurjchem-1675	198	13	ppm	ppm	NUM
eurjchem-1675	198	14	):	):	PUNCT
eurjchem-1675	198	15	1.33	1.33	NUM
eurjchem-1675	198	16	-	-	SYM
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eurjchem-1675	198	18	(	(	PUNCT
eurjchem-1675	198	19	m	m	PROPN
eurjchem-1675	198	20	,	,	PUNCT
eurjchem-1675	198	21	10h	10h	NUM
eurjchem-1675	198	22	,	,	PUNCT
eurjchem-1675	198	23	h2c	h2c	PROPN
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eurjchem-1675	198	25	,	,	PUNCT
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eurjchem-1675	198	27	(	(	PUNCT
eurjchem-1675	198	28	t	t	PROPN
eurjchem-1675	198	29	,	,	PUNCT
eurjchem-1675	198	30	3h	3h	NUM
eurjchem-1675	198	31	,	,	PUNCT
eurjchem-1675	198	32	h3c	h3c	PROPN
eurjchem-1675	198	33	)	)	PUNCT
eurjchem-1675	198	34	,	,	PUNCT
eurjchem-1675	198	35	2.35	2.35	NUM
eurjchem-1675	198	36	(	(	PUNCT
eurjchem-1675	198	37	s	s	PROPN
eurjchem-1675	198	38	,	,	PUNCT
eurjchem-1675	198	39	3h	3h	NUM
eurjchem-1675	198	40	,	,	PUNCT
eurjchem-1675	198	41	h3c	h3c	PROPN
eurjchem-1675	198	42	)	)	PUNCT
eurjchem-1675	198	43	,	,	PUNCT
eurjchem-1675	198	44	3.66	3.66	NUM
eurjchem-1675	198	45	(	(	PUNCT
eurjchem-1675	198	46	s	s	PROPN
eurjchem-1675	198	47	,	,	PUNCT
eurjchem-1675	198	48	1h	1h	NUM
eurjchem-1675	198	49	,	,	PUNCT
eurjchem-1675	198	50	hc	hc	PROPN
eurjchem-1675	198	51	-	-	PUNCT
eurjchem-1675	198	52	nh	nh	NOUN
eurjchem-1675	198	53	)	)	PUNCT
eurjchem-1675	198	54	,	,	PUNCT
eurjchem-1675	198	55	4.20	4.20	NUM
eurjchem-1675	198	56	(	(	PUNCT
eurjchem-1675	198	57	q	q	NOUN
eurjchem-1675	198	58	,	,	PUNCT
eurjchem-1675	198	59	2h	2h	NUM
eurjchem-1675	198	60	,	,	PUNCT
eurjchem-1675	198	61	h2c	h2c	PROPN
eurjchem-1675	198	62	)	)	PUNCT
eurjchem-1675	198	63	,	,	PUNCT
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eurjchem-1675	198	65	(	(	PUNCT
eurjchem-1675	198	66	d	d	PROPN
eurjchem-1675	198	67	,	,	PUNCT
eurjchem-1675	198	68	2h	2h	NUM
eurjchem-1675	198	69	,	,	PUNCT
eurjchem-1675	198	70	j	j	PROPN
eurjchem-1675	198	71	=	=	PROPN
eurjchem-1675	198	72	1.2	1.2	NUM
eurjchem-1675	198	73	hz	hz	NOUN
eurjchem-1675	198	74	,	,	PUNCT
eurjchem-1675	198	75	ar	ar	NOUN
eurjchem-1675	198	76	-	-	NOUN
eurjchem-1675	198	77	h	h	NOUN
eurjchem-1675	198	78	)	)	PUNCT
eurjchem-1675	198	79	,	,	PUNCT
eurjchem-1675	198	80	6.81	6.81	NUM
eurjchem-1675	198	81	(	(	PUNCT
eurjchem-1675	198	82	d	d	PROPN
eurjchem-1675	198	83	,	,	PUNCT
eurjchem-1675	198	84	2h	2h	NUM
eurjchem-1675	198	85	,	,	PUNCT
eurjchem-1675	198	86	j	j	PROPN
eurjchem-1675	198	87	=	=	PROPN
eurjchem-1675	198	88	1.2	1.2	NUM
eurjchem-1675	198	89	hz	hz	NOUN
eurjchem-1675	198	90	,	,	PUNCT
eurjchem-1675	198	91	ar	ar	NOUN
eurjchem-1675	198	92	-	-	NOUN
eurjchem-1675	198	93	h	h	NOUN
eurjchem-1675	198	94	)	)	PUNCT
eurjchem-1675	198	95	,	,	PUNCT
eurjchem-1675	198	96	7.89	7.89	NUM
eurjchem-1675	198	97	(	(	PUNCT
eurjchem-1675	198	98	s	s	PROPN
eurjchem-1675	198	99	,	,	PUNCT
eurjchem-1675	198	100	1h	1h	NUM
eurjchem-1675	198	101	,	,	PUNCT
eurjchem-1675	198	102	hn	hn	PROPN
eurjchem-1675	198	103	d2o	d2o	NOUN
eurjchem-1675	198	104	-	-	PUNCT
eurjchem-1675	198	105	exchangable	exchangable	ADJ
eurjchem-1675	198	106	)	)	PUNCT
eurjchem-1675	198	107	.	.	PUNCT
eurjchem-1675	199	1	13c	13c	NOUN
eurjchem-1675	199	2	nmr	nmr	NOUN
eurjchem-1675	199	3	(	(	PUNCT
eurjchem-1675	199	4	75	75	NUM
eurjchem-1675	199	5	mhz	mhz	NOUN
eurjchem-1675	199	6	,	,	PUNCT
eurjchem-1675	199	7	dmso	dmso	NOUN
eurjchem-1675	199	8	-	-	NOUN
eurjchem-1675	199	9	d6	d6	NOUN
eurjchem-1675	199	10	,	,	PUNCT
eurjchem-1675	199	11	δ	δ	PROPN
eurjchem-1675	199	12	,	,	PUNCT
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eurjchem-1675	199	14	):	):	PUNCT
eurjchem-1675	199	15	13.6	13.6	NUM
eurjchem-1675	199	16	(	(	PUNCT
eurjchem-1675	199	17	ch3	ch3	PROPN
eurjchem-1675	199	18	)	)	PUNCT
eurjchem-1675	199	19	,	,	PUNCT
eurjchem-1675	199	20	22.3	22.3	NUM
eurjchem-1675	199	21	(	(	PUNCT
eurjchem-1675	199	22	ch3	ch3	PROPN
eurjchem-1675	199	23	)	)	PUNCT
eurjchem-1675	199	24	,	,	PUNCT
eurjchem-1675	199	25	23.3	23.3	NUM
eurjchem-1675	199	26	(	(	PUNCT
eurjchem-1675	199	27	ch2	ch2	PROPN
eurjchem-1675	199	28	)	)	PUNCT
eurjchem-1675	199	29	,	,	PUNCT
eurjchem-1675	199	30	28.6	28.6	NUM
eurjchem-1675	199	31	(	(	PUNCT
eurjchem-1675	199	32	ch2	ch2	PROPN
eurjchem-1675	199	33	)	)	PUNCT
eurjchem-1675	199	34	,	,	PUNCT
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eurjchem-1675	199	36	(	(	PUNCT
eurjchem-1675	199	37	ch	ch	NOUN
eurjchem-1675	199	38	)	)	PUNCT
eurjchem-1675	199	39	,	,	PUNCT
eurjchem-1675	199	40	60.3	60.3	NUM
eurjchem-1675	199	41	(	(	PUNCT
eurjchem-1675	199	42	ch2	ch2	PROPN
eurjchem-1675	199	43	)	)	PUNCT
eurjchem-1675	199	44	,	,	PUNCT
eurjchem-1675	199	45	88.4	88.4	NUM
eurjchem-1675	199	46	(	(	PUNCT
eurjchem-1675	199	47	ch=	ch=	PROPN
eurjchem-1675	199	48	)	)	PUNCT
eurjchem-1675	199	49	,	,	PUNCT
eurjchem-1675	199	50	115.3	115.3	NUM
eurjchem-1675	199	51	(	(	PUNCT
eurjchem-1675	199	52	cn	cn	PROPN
eurjchem-1675	199	53	)	)	PUNCT
eurjchem-1675	199	54	,	,	PUNCT
eurjchem-1675	199	55	128.3	128.3	NUM
eurjchem-1675	199	56	(	(	PUNCT
eurjchem-1675	199	57	ch	ch	NOUN
eurjchem-1675	199	58	)	)	PUNCT
eurjchem-1675	199	59	,	,	PUNCT
eurjchem-1675	199	60	129.3	129.3	NUM
eurjchem-1675	199	61	(	(	PUNCT
eurjchem-1675	199	62	ch	ch	NOUN
eurjchem-1675	199	63	)	)	PUNCT
eurjchem-1675	199	64	,	,	PUNCT
eurjchem-1675	199	65	143.6	143.6	NUM
eurjchem-1675	199	66	(	(	PUNCT
eurjchem-1675	199	67	ch	ch	NOUN
eurjchem-1675	199	68	)	)	PUNCT
eurjchem-1675	199	69	,	,	PUNCT
eurjchem-1675	199	70	154.0	154.0	NUM
eurjchem-1675	199	71	(	(	PUNCT
eurjchem-1675	199	72	ch	ch	NOUN
eurjchem-1675	199	73	=	=	SYM
eurjchem-1675	199	74	s	s	PART
eurjchem-1675	199	75	)	)	PUNCT
eurjchem-1675	199	76	,	,	PUNCT
eurjchem-1675	199	77	159.5	159.5	NUM
eurjchem-1675	199	78	(	(	PUNCT
eurjchem-1675	199	79	c	c	NOUN
eurjchem-1675	199	80	=	=	NOUN
eurjchem-1675	199	81	o	o	NOUN
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eurjchem-1675	199	83	,	,	PUNCT
eurjchem-1675	199	84	161.6	161.6	NUM
eurjchem-1675	199	85	(	(	PUNCT
eurjchem-1675	199	86	c	c	NOUN
eurjchem-1675	199	87	=	=	NOUN
eurjchem-1675	199	88	o	o	NOUN
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eurjchem-1675	199	90	.	.	PUNCT
eurjchem-1675	200	1	ms	ms	NOUN
eurjchem-1675	200	2	(	(	PUNCT
eurjchem-1675	200	3	m	m	PROPN
eurjchem-1675	200	4	/	/	SYM
eurjchem-1675	200	5	z	z	NOUN
eurjchem-1675	200	6	(	(	PUNCT
eurjchem-1675	200	7	%	%	NOUN
eurjchem-1675	200	8	)	)	PUNCT
eurjchem-1675	200	9	):	):	PUNCT
eurjchem-1675	200	10	412	412	NUM
eurjchem-1675	200	11	(	(	PUNCT
eurjchem-1675	200	12	m+	m+	NUM
eurjchem-1675	200	13	,	,	PUNCT
eurjchem-1675	200	14	100.0	100.0	NUM
eurjchem-1675	200	15	)	)	PUNCT
eurjchem-1675	200	16	,	,	PUNCT
eurjchem-1675	200	17	384	384	NUM
eurjchem-1675	200	18	(	(	PUNCT
eurjchem-1675	200	19	75	75	NUM
eurjchem-1675	200	20	)	)	PUNCT
eurjchem-1675	200	21	.	.	PUNCT
eurjchem-1675	201	1	anal	anal	PROPN
eurjchem-1675	201	2	.	.	PUNCT
eurjchem-1675	201	3	calcd	calcd	NOUN
eurjchem-1675	201	4	.	.	PUNCT
eurjchem-1675	202	1	for	for	ADP
eurjchem-1675	202	2	c21h24n4o3s	c21h24n4o3s	NUM
eurjchem-1675	202	3	:	:	SYM
eurjchem-1675	202	4	c	c	X
eurjchem-1675	202	5	,	,	PUNCT
eurjchem-1675	202	6	61.15	61.15	NUM
eurjchem-1675	202	7	;	;	PUNCT
eurjchem-1675	202	8	h	h	NOUN
eurjchem-1675	202	9	,	,	PUNCT
eurjchem-1675	202	10	5.86	5.86	NUM
eurjchem-1675	202	11	;	;	PUNCT
eurjchem-1675	202	12	n	n	CCONJ
eurjchem-1675	202	13	,	,	PUNCT
eurjchem-1675	202	14	13.58	13.58	NUM
eurjchem-1675	202	15	.	.	PUNCT
eurjchem-1675	202	16	found	find	VERB
eurjchem-1675	202	17	:	:	PUNCT
eurjchem-1675	203	1	c	c	X
eurjchem-1675	203	2	,	,	PUNCT
eurjchem-1675	203	3	61.17	61.17	NUM
eurjchem-1675	203	4	;	;	PUNCT
eurjchem-1675	203	5	h	h	NOUN
eurjchem-1675	203	6	,	,	PUNCT
eurjchem-1675	203	7	5.89	5.89	NUM
eurjchem-1675	203	8	;	;	PUNCT
eurjchem-1675	203	9	n	n	CCONJ
eurjchem-1675	203	10	,	,	PUNCT
eurjchem-1675	203	11	13.63	13.63	NUM
eurjchem-1675	203	12	%	%	NOUN
eurjchem-1675	203	13	.	.	PUNCT
eurjchem-1675	204	1	ethyl-5-(1	ethyl-5-(1	NOUN
eurjchem-1675	204	2	-	-	PUNCT
eurjchem-1675	204	3	cyano-2-(cyclohexylamino)-2	cyano-2-(cyclohexylamino)-2	NOUN
eurjchem-1675	204	4	-	-	PUNCT
eurjchem-1675	204	5	oxoethylidene)-4(4	oxoethylidene)-4(4	NOUN
eurjchem-1675	204	6	-	-	PUNCT
eurjchem-1675	204	7	methoxyphenyl)-4,5	methoxyphenyl)-4,5	NOUN
eurjchem-1675	204	8	-	-	PUNCT
eurjchem-1675	204	9	dihydro-1	dihydro-1	NOUN
eurjchem-1675	204	10	,	,	PUNCT
eurjchem-1675	204	11	3	3	NUM
eurjchem-1675	204	12	,	,	PUNCT
eurjchem-1675	204	13	4	4	NUM
eurjchem-1675	204	14	-	-	PUNCT
eurjchem-1675	204	15	thiadiazole-2	thiadiazole-2	NUM
eurjchem-1675	204	16	-	-	PUNCT
eurjchem-1675	204	17	carboxylate	carboxylate	NOUN
eurjchem-1675	204	18	(	(	PUNCT
eurjchem-1675	204	19	24c	24c	NOUN
eurjchem-1675	204	20	):	):	PUNCT
eurjchem-1675	204	21	color	color	NOUN
eurjchem-1675	204	22	:	:	PUNCT
eurjchem-1675	204	23	yellow	yellow	ADJ
eurjchem-1675	204	24	.	.	PUNCT
eurjchem-1675	205	1	yield	yield	NOUN
eurjchem-1675	205	2	:	:	PUNCT
eurjchem-1675	205	3	70	70	NUM
eurjchem-1675	205	4	%	%	NOUN
eurjchem-1675	205	5	.	.	PUNCT
eurjchem-1675	206	1	m.p	m.p	PROPN
eurjchem-1675	206	2	.	.	PROPN
eurjchem-1675	206	3	:	:	PUNCT
eurjchem-1675	207	1	170	170	NUM
eurjchem-1675	207	2	-	-	SYM
eurjchem-1675	207	3	172	172	NUM
eurjchem-1675	207	4	°	°	SYM
eurjchem-1675	207	5	c	c	NOUN
eurjchem-1675	207	6	.	.	PUNCT
eurjchem-1675	208	1	ft	ft	PROPN
eurjchem-1675	208	2	-	-	PUNCT
eurjchem-1675	208	3	ir	ir	PROPN
eurjchem-1675	208	4	(	(	PUNCT
eurjchem-1675	208	5	kbr	kbr	PROPN
eurjchem-1675	208	6	,	,	PUNCT
eurjchem-1675	208	7	ν	ν	PROPN
eurjchem-1675	208	8	,	,	PUNCT
eurjchem-1675	208	9	cm-1	cm-1	NUM
eurjchem-1675	208	10	):	):	PUNCT
eurjchem-1675	208	11	1623	1623	NUM
eurjchem-1675	208	12	(	(	PUNCT
eurjchem-1675	208	13	c	c	NOUN
eurjchem-1675	208	14	=	=	NOUN
eurjchem-1675	208	15	o	o	NOUN
eurjchem-1675	208	16	)	)	PUNCT
eurjchem-1675	208	17	,	,	PUNCT
eurjchem-1675	208	18	2186	2186	NUM
eurjchem-1675	208	19	(	(	PUNCT
eurjchem-1675	208	20	c	c	NOUN
eurjchem-1675	208	21	=	=	SYM
eurjchem-1675	208	22	n	n	NUM
eurjchem-1675	208	23	)	)	PUNCT
eurjchem-1675	208	24	,	,	PUNCT
eurjchem-1675	208	25	3345	3345	NUM
eurjchem-1675	208	26	(	(	PUNCT
eurjchem-1675	208	27	nh	nh	NOUN
eurjchem-1675	208	28	)	)	PUNCT
eurjchem-1675	208	29	.	.	PUNCT
eurjchem-1675	209	1	1h	1h	NUM
eurjchem-1675	209	2	nmr	nmr	NOUN
eurjchem-1675	209	3	(	(	PUNCT
eurjchem-1675	209	4	300	300	NUM
eurjchem-1675	209	5	mhz	mhz	NOUN
eurjchem-1675	209	6	,	,	PUNCT
eurjchem-1675	209	7	dmso	dmso	NOUN
eurjchem-1675	209	8	-	-	NOUN
eurjchem-1675	209	9	d6	d6	NOUN
eurjchem-1675	209	10	,	,	PUNCT
eurjchem-1675	209	11	δ	δ	PROPN
eurjchem-1675	209	12	,	,	PUNCT
eurjchem-1675	209	13	ppm	ppm	NOUN
eurjchem-1675	209	14	):	):	PUNCT
eurjchem-1675	209	15	1.29	1.29	NUM
eurjchem-1675	209	16	-	-	SYM
eurjchem-1675	209	17	1.42	1.42	NUM
eurjchem-1675	209	18	(	(	PUNCT
eurjchem-1675	209	19	m	m	PROPN
eurjchem-1675	209	20	,	,	PUNCT
eurjchem-1675	209	21	10h	10h	NUM
eurjchem-1675	209	22	,	,	PUNCT
eurjchem-1675	209	23	h2c	h2c	PROPN
eurjchem-1675	209	24	)	)	PUNCT
eurjchem-1675	209	25	,	,	PUNCT
eurjchem-1675	209	26	1.78	1.78	NUM
eurjchem-1675	209	27	(	(	PUNCT
eurjchem-1675	209	28	t	t	PROPN
eurjchem-1675	209	29	,	,	PUNCT
eurjchem-1675	209	30	3h	3h	NUM
eurjchem-1675	209	31	,	,	PUNCT
eurjchem-1675	209	32	h3c	h3c	PROPN
eurjchem-1675	209	33	)	)	PUNCT
eurjchem-1675	209	34	,	,	PUNCT
eurjchem-1675	209	35	3.523	3.523	NUM
eurjchem-1675	209	36	(	(	PUNCT
eurjchem-1675	209	37	s	s	PROPN
eurjchem-1675	209	38	,	,	PUNCT
eurjchem-1675	209	39	1h	1h	NUM
eurjchem-1675	209	40	,	,	PUNCT
eurjchem-1675	209	41	hc	hc	PROPN
eurjchem-1675	209	42	-	-	PUNCT
eurjchem-1675	209	43	nh	nh	NOUN
eurjchem-1675	209	44	)	)	PUNCT
eurjchem-1675	209	45	,	,	PUNCT
eurjchem-1675	209	46	3.64	3.64	NUM
eurjchem-1675	209	47	(	(	PUNCT
eurjchem-1675	209	48	s	s	PROPN
eurjchem-1675	209	49	,	,	PUNCT
eurjchem-1675	209	50	3h	3h	NUM
eurjchem-1675	209	51	,	,	PUNCT
eurjchem-1675	209	52	h3c	h3c	PROPN
eurjchem-1675	209	53	)	)	PUNCT
eurjchem-1675	209	54	,	,	PUNCT
eurjchem-1675	209	55	4.20	4.20	NUM
eurjchem-1675	209	56	(	(	PUNCT
eurjchem-1675	209	57	q	q	NOUN
eurjchem-1675	209	58	,	,	PUNCT
eurjchem-1675	209	59	2h	2h	NUM
eurjchem-1675	209	60	,	,	PUNCT
eurjchem-1675	209	61	h2c	h2c	PROPN
eurjchem-1675	209	62	)	)	PUNCT
eurjchem-1675	209	63	,	,	PUNCT
eurjchem-1675	209	64	6.34	6.34	NUM
eurjchem-1675	209	65	-	-	SYM
eurjchem-1675	209	66	6.63	6.63	NUM
eurjchem-1675	209	67	(	(	PUNCT
eurjchem-1675	209	68	m	m	PROPN
eurjchem-1675	209	69	,	,	PUNCT
eurjchem-1675	209	70	4h	4h	NOUN
eurjchem-1675	209	71	,	,	PUNCT
eurjchem-1675	209	72	ar	ar	NOUN
eurjchem-1675	209	73	-	-	NOUN
eurjchem-1675	209	74	h	h	NOUN
eurjchem-1675	209	75	)	)	PUNCT
eurjchem-1675	209	76	,	,	PUNCT
eurjchem-1675	209	77	7.832	7.832	NUM
eurjchem-1675	209	78	(	(	PUNCT
eurjchem-1675	209	79	s	s	PROPN
eurjchem-1675	209	80	,	,	PUNCT
eurjchem-1675	209	81	1h	1h	NUM
eurjchem-1675	209	82	,	,	PUNCT
eurjchem-1675	209	83	hn	hn	PROPN
eurjchem-1675	209	84	d2o	d2o	NOUN
eurjchem-1675	209	85	-	-	PUNCT
eurjchem-1675	209	86	exchangable	exchangable	ADJ
eurjchem-1675	209	87	)	)	PUNCT
eurjchem-1675	209	88	.	.	PUNCT
eurjchem-1675	210	1	13c	13c	NOUN
eurjchem-1675	210	2	nmr	nmr	NOUN
eurjchem-1675	210	3	(	(	PUNCT
eurjchem-1675	210	4	75	75	NUM
eurjchem-1675	210	5	mhz	mhz	NOUN
eurjchem-1675	210	6	,	,	PUNCT
eurjchem-1675	210	7	dmso	dmso	NOUN
eurjchem-1675	210	8	-	-	NOUN
eurjchem-1675	210	9	d6	d6	NOUN
eurjchem-1675	210	10	,	,	PUNCT
eurjchem-1675	210	11	δ	δ	PROPN
eurjchem-1675	210	12	,	,	PUNCT
eurjchem-1675	210	13	ppm	ppm	NUM
eurjchem-1675	210	14	):	):	PUNCT
eurjchem-1675	210	15	13.8	13.8	NUM
eurjchem-1675	210	16	(	(	PUNCT
eurjchem-1675	210	17	ch3	ch3	PROPN
eurjchem-1675	210	18	)	)	PUNCT
eurjchem-1675	210	19	,	,	PUNCT
eurjchem-1675	210	20	23.3	23.3	NUM
eurjchem-1675	210	21	(	(	PUNCT
eurjchem-1675	210	22	ch3	ch3	PROPN
eurjchem-1675	210	23	)	)	PUNCT
eurjchem-1675	210	24	,	,	PUNCT
eurjchem-1675	210	25	28.6	28.6	NUM
eurjchem-1675	210	26	(	(	PUNCT
eurjchem-1675	210	27	ch2	ch2	PROPN
eurjchem-1675	210	28	)	)	PUNCT
eurjchem-1675	210	29	,	,	PUNCT
eurjchem-1675	210	30	47.6	47.6	NUM
eurjchem-1675	210	31	(	(	PUNCT
eurjchem-1675	210	32	ch	ch	NOUN
eurjchem-1675	210	33	)	)	PUNCT
eurjchem-1675	210	34	,	,	PUNCT
eurjchem-1675	210	35	60.7	60.7	NUM
eurjchem-1675	210	36	(	(	PUNCT
eurjchem-1675	210	37	ch2	ch2	PROPN
eurjchem-1675	210	38	)	)	PUNCT
eurjchem-1675	210	39	,	,	PUNCT
eurjchem-1675	210	40	113.2	113.2	NUM
eurjchem-1675	210	41	(	(	PUNCT
eurjchem-1675	210	42	ch	ch	NOUN
eurjchem-1675	210	43	)	)	PUNCT
eurjchem-1675	210	44	,	,	PUNCT
eurjchem-1675	210	45	115.3	115.3	NUM
eurjchem-1675	210	46	(	(	PUNCT
eurjchem-1675	210	47	cn	cn	PROPN
eurjchem-1675	210	48	)	)	PUNCT
eurjchem-1675	210	49	,	,	PUNCT
eurjchem-1675	210	50	119.3	119.3	NUM
eurjchem-1675	210	51	(	(	PUNCT
eurjchem-1675	210	52	ch	ch	NOUN
eurjchem-1675	210	53	)	)	PUNCT
eurjchem-1675	210	54	,	,	PUNCT
eurjchem-1675	210	55	129.3	129.3	NUM
eurjchem-1675	210	56	(	(	PUNCT
eurjchem-1675	210	57	ch	ch	NOUN
eurjchem-1675	210	58	)	)	PUNCT
eurjchem-1675	210	59	,	,	PUNCT
eurjchem-1675	210	60	139.3	139.3	NUM
eurjchem-1675	210	61	(	(	PUNCT
eurjchem-1675	210	62	ch	ch	NOUN
eurjchem-1675	210	63	)	)	PUNCT
eurjchem-1675	210	64	,	,	PUNCT
eurjchem-1675	210	65	154.0	154.0	NUM
eurjchem-1675	210	66	(	(	PUNCT
eurjchem-1675	210	67	ch	ch	NOUN
eurjchem-1675	210	68	=	=	SYM
eurjchem-1675	210	69	s	s	PART
eurjchem-1675	210	70	)	)	PUNCT
eurjchem-1675	210	71	,	,	PUNCT
eurjchem-1675	210	72	160.2	160.2	NUM
eurjchem-1675	210	73	(	(	PUNCT
eurjchem-1675	210	74	c	c	NOUN
eurjchem-1675	210	75	=	=	NOUN
eurjchem-1675	210	76	o	o	NOUN
eurjchem-1675	210	77	)	)	PUNCT
eurjchem-1675	210	78	.	.	PUNCT
eurjchem-1675	211	1	ms	ms	NOUN
eurjchem-1675	211	2	(	(	PUNCT
eurjchem-1675	211	3	m	m	PROPN
eurjchem-1675	211	4	/	/	SYM
eurjchem-1675	211	5	z	z	NOUN
eurjchem-1675	211	6	(	(	PUNCT
eurjchem-1675	211	7	%	%	NOUN
eurjchem-1675	211	8	)	)	PUNCT
eurjchem-1675	211	9	):	):	PUNCT
eurjchem-1675	211	10	428	428	NUM
eurjchem-1675	211	11	(	(	PUNCT
eurjchem-1675	211	12	m+	m+	NUM
eurjchem-1675	211	13	,	,	PUNCT
eurjchem-1675	211	14	100.0	100.0	NUM
eurjchem-1675	211	15	)	)	PUNCT
eurjchem-1675	211	16	.	.	PUNCT
eurjchem-1675	212	1	anal	anal	PROPN
eurjchem-1675	212	2	.	.	PUNCT
eurjchem-1675	212	3	calcd	calcd	NOUN
eurjchem-1675	212	4	.	.	PUNCT
eurjchem-1675	213	1	for	for	ADP
eurjchem-1675	213	2	c21h24n4o4s	c21h24n4o4s	NUM
eurjchem-1675	213	3	:	:	PUNCT
eurjchem-1675	213	4	c	c	NOUN
eurjchem-1675	213	5	,	,	PUNCT
eurjchem-1675	213	6	58.86	58.86	NUM
eurjchem-1675	213	7	;	;	PUNCT
eurjchem-1675	213	8	h	h	NOUN
eurjchem-1675	213	9	,	,	PUNCT
eurjchem-1675	213	10	5.65	5.65	NUM
eurjchem-1675	213	11	;	;	PUNCT
eurjchem-1675	213	12	n	n	CCONJ
eurjchem-1675	213	13	,	,	PUNCT
eurjchem-1675	213	14	13.07	13.07	NUM
eurjchem-1675	213	15	.	.	PUNCT
eurjchem-1675	213	16	found	find	VERB
eurjchem-1675	213	17	:	:	PUNCT
eurjchem-1675	214	1	c	c	X
eurjchem-1675	214	2	,	,	PUNCT
eurjchem-1675	214	3	58.91	58.91	NUM
eurjchem-1675	214	4	;	;	PUNCT
eurjchem-1675	214	5	h	h	NOUN
eurjchem-1675	214	6	,	,	PUNCT
eurjchem-1675	214	7	5.62	5.62	NUM
eurjchem-1675	214	8	;	;	PUNCT
eurjchem-1675	214	9	n	n	CCONJ
eurjchem-1675	214	10	,	,	PUNCT
eurjchem-1675	214	11	13.11	13.11	NUM
eurjchem-1675	214	12	%	%	NOUN
eurjchem-1675	214	13	.	.	PUNCT
eurjchem-1675	215	1	ethyl-5-(1	ethyl-5-(1	PROPN
eurjchem-1675	215	2	-	-	PUNCT
eurjchem-1675	215	3	cyano-2-(cyclohexylamino)-2	cyano-2-(cyclohexylamino)-2	NOUN
eurjchem-1675	215	4	-	-	PUNCT
eurjchem-1675	215	5	oxoethylidene)-4phenyl-4	oxoethylidene)-4phenyl-4	PROPN
eurjchem-1675	215	6	,	,	PUNCT
eurjchem-1675	215	7	5	5	NUM
eurjchem-1675	215	8	-	-	SYM
eurjchem-1675	215	9	dihydro-1	dihydro-1	NUM
eurjchem-1675	215	10	,	,	PUNCT
eurjchem-1675	215	11	3	3	NUM
eurjchem-1675	215	12	,	,	PUNCT
eurjchem-1675	215	13	4	4	NUM
eurjchem-1675	215	14	-	-	PUNCT
eurjchem-1675	215	15	thiadiazole-2	thiadiazole-2	NUM
eurjchem-1675	215	16	-	-	PUNCT
eurjchem-1675	215	17	carboxylate	carboxylate	NOUN
eurjchem-1675	215	18	(	(	PUNCT
eurjchem-1675	215	19	24d	24d	NUM
eurjchem-1675	215	20	):	):	PUNCT
eurjchem-1675	215	21	color	color	NOUN
eurjchem-1675	215	22	:	:	PUNCT
eurjchem-1675	215	23	pale	pale	ADJ
eurjchem-1675	215	24	yellow	yellow	ADJ
eurjchem-1675	215	25	.	.	PUNCT
eurjchem-1675	215	26	yield	yield	NOUN
eurjchem-1675	215	27	:	:	PUNCT
eurjchem-1675	215	28	75	75	NUM
eurjchem-1675	215	29	%	%	NOUN
eurjchem-1675	215	30	.	.	PUNCT
eurjchem-1675	216	1	m.p	m.p	PROPN
eurjchem-1675	216	2	.	.	PROPN
eurjchem-1675	216	3	:	:	PUNCT
eurjchem-1675	217	1	204	204	NUM
eurjchem-1675	217	2	-	-	SYM
eurjchem-1675	217	3	206	206	NUM
eurjchem-1675	217	4	°	°	SYM
eurjchem-1675	217	5	c	c	NOUN
eurjchem-1675	217	6	.	.	PUNCT
eurjchem-1675	218	1	ft	ft	PROPN
eurjchem-1675	218	2	-	-	PUNCT
eurjchem-1675	218	3	ir	ir	PROPN
eurjchem-1675	218	4	(	(	PUNCT
eurjchem-1675	218	5	kbr	kbr	PROPN
eurjchem-1675	218	6	,	,	PUNCT
eurjchem-1675	218	7	ν	ν	PROPN
eurjchem-1675	218	8	,	,	PUNCT
eurjchem-1675	218	9	cm-1	cm-1	NUM
eurjchem-1675	218	10	):	):	PUNCT
eurjchem-1675	218	11	1681	1681	NUM
eurjchem-1675	218	12	(	(	PUNCT
eurjchem-1675	218	13	c	c	NOUN
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eurjchem-1675	218	15	o	o	NOUN
eurjchem-1675	218	16	)	)	PUNCT
eurjchem-1675	218	17	,	,	PUNCT
eurjchem-1675	218	18	2169	2169	NUM
eurjchem-1675	218	19	(	(	PUNCT
eurjchem-1675	218	20	c	c	NOUN
eurjchem-1675	218	21	=	=	SYM
eurjchem-1675	218	22	n	n	NUM
eurjchem-1675	218	23	)	)	PUNCT
eurjchem-1675	218	24	,	,	PUNCT
eurjchem-1675	218	25	3243	3243	NUM
eurjchem-1675	218	26	(	(	PUNCT
eurjchem-1675	218	27	nh	nh	NOUN
eurjchem-1675	218	28	)	)	PUNCT
eurjchem-1675	218	29	.	.	PUNCT
eurjchem-1675	219	1	1h	1h	NUM
eurjchem-1675	219	2	nmr	nmr	NOUN
eurjchem-1675	219	3	(	(	PUNCT
eurjchem-1675	219	4	300	300	NUM
eurjchem-1675	219	5	mhz	mhz	NOUN
eurjchem-1675	219	6	,	,	PUNCT
eurjchem-1675	219	7	dmso	dmso	NOUN
eurjchem-1675	219	8	-	-	NOUN
eurjchem-1675	219	9	d6	d6	NOUN
eurjchem-1675	219	10	,	,	PUNCT
eurjchem-1675	219	11	δ	δ	PROPN
eurjchem-1675	219	12	,	,	PUNCT
eurjchem-1675	219	13	ppm	ppm	NUM
eurjchem-1675	219	14	):	):	PUNCT
eurjchem-1675	219	15	1.30	1.30	NUM
eurjchem-1675	219	16	-	-	SYM
eurjchem-1675	219	17	1.40	1.40	NUM
eurjchem-1675	219	18	(	(	PUNCT
eurjchem-1675	219	19	m	m	PROPN
eurjchem-1675	219	20	,	,	PUNCT
eurjchem-1675	219	21	10h	10h	NUM
eurjchem-1675	219	22	,	,	PUNCT
eurjchem-1675	219	23	h2c	h2c	PROPN
eurjchem-1675	219	24	)	)	PUNCT
eurjchem-1675	219	25	,	,	PUNCT
eurjchem-1675	219	26	1.79	1.79	NUM
eurjchem-1675	219	27	(	(	PUNCT
eurjchem-1675	219	28	t	t	PROPN
eurjchem-1675	219	29	,	,	PUNCT
eurjchem-1675	219	30	3h	3h	NUM
eurjchem-1675	219	31	,	,	PUNCT
eurjchem-1675	219	32	h3c	h3c	PROPN
eurjchem-1675	219	33	)	)	PUNCT
eurjchem-1675	219	34	,	,	PUNCT
eurjchem-1675	219	35	3.72	3.72	NUM
eurjchem-1675	219	36	(	(	PUNCT
eurjchem-1675	219	37	s	s	PROPN
eurjchem-1675	219	38	,	,	PUNCT
eurjchem-1675	219	39	1h	1h	NUM
eurjchem-1675	219	40	,	,	PUNCT
eurjchem-1675	219	41	hc	hc	PROPN
eurjchem-1675	219	42	-	-	PUNCT
eurjchem-1675	219	43	nh	nh	NOUN
eurjchem-1675	219	44	)	)	PUNCT
eurjchem-1675	219	45	,	,	PUNCT
eurjchem-1675	219	46	4.20	4.20	NUM
eurjchem-1675	219	47	(	(	PUNCT
eurjchem-1675	219	48	q	q	NOUN
eurjchem-1675	219	49	,	,	PUNCT
eurjchem-1675	219	50	2h	2h	NUM
eurjchem-1675	219	51	,	,	PUNCT
eurjchem-1675	219	52	h2c	h2c	PROPN
eurjchem-1675	219	53	)	)	PUNCT
eurjchem-1675	219	54	,	,	PUNCT
eurjchem-1675	219	55	6.50	6.50	NUM
eurjchem-1675	219	56	-	-	SYM
eurjchem-1675	219	57	7.06	7.06	NUM
eurjchem-1675	219	58	(	(	PUNCT
eurjchem-1675	219	59	m	m	PROPN
eurjchem-1675	219	60	,	,	PUNCT
eurjchem-1675	219	61	5h	5h	NUM
eurjchem-1675	219	62	,	,	PUNCT
eurjchem-1675	219	63	ar	ar	NOUN
eurjchem-1675	219	64	-	-	NOUN
eurjchem-1675	219	65	h	h	NOUN
eurjchem-1675	219	66	)	)	PUNCT
eurjchem-1675	219	67	,	,	PUNCT
eurjchem-1675	219	68	8.001	8.001	NUM
eurjchem-1675	219	69	(	(	PUNCT
eurjchem-1675	219	70	s	s	PROPN
eurjchem-1675	219	71	,	,	PUNCT
eurjchem-1675	219	72	1h	1h	NUM
eurjchem-1675	219	73	,	,	PUNCT
eurjchem-1675	219	74	hn	hn	PROPN
eurjchem-1675	219	75	d2o	d2o	NOUN
eurjchem-1675	219	76	-	-	PUNCT
eurjchem-1675	219	77	exchangable	exchangable	ADJ
eurjchem-1675	219	78	)	)	PUNCT
eurjchem-1675	219	79	.	.	PUNCT
eurjchem-1675	220	1	13c	13c	NOUN
eurjchem-1675	220	2	nmr	nmr	NOUN
eurjchem-1675	220	3	(	(	PUNCT
eurjchem-1675	220	4	75	75	NUM
eurjchem-1675	220	5	mhz	mhz	NOUN
eurjchem-1675	220	6	,	,	PUNCT
eurjchem-1675	220	7	dmsod6	dmsod6	PROPN
eurjchem-1675	220	8	,	,	PUNCT
eurjchem-1675	220	9	δ	δ	PROPN
eurjchem-1675	220	10	,	,	PUNCT
eurjchem-1675	220	11	ppm	ppm	NUM
eurjchem-1675	220	12	):	):	PUNCT
eurjchem-1675	220	13	13.8	13.8	NUM
eurjchem-1675	220	14	(	(	PUNCT
eurjchem-1675	220	15	ch3	ch3	PROPN
eurjchem-1675	220	16	)	)	PUNCT
eurjchem-1675	220	17	,	,	PUNCT
eurjchem-1675	220	18	23.3	23.3	NUM
eurjchem-1675	220	19	(	(	PUNCT
eurjchem-1675	220	20	ch3	ch3	PROPN
eurjchem-1675	220	21	)	)	PUNCT
eurjchem-1675	220	22	,	,	PUNCT
eurjchem-1675	220	23	28.6	28.6	NUM
eurjchem-1675	220	24	(	(	PUNCT
eurjchem-1675	220	25	ch2	ch2	PROPN
eurjchem-1675	220	26	)	)	PUNCT
eurjchem-1675	220	27	,	,	PUNCT
eurjchem-1675	220	28	47.6	47.6	NUM
eurjchem-1675	220	29	(	(	PUNCT
eurjchem-1675	220	30	ch	ch	NOUN
eurjchem-1675	220	31	)	)	PUNCT
eurjchem-1675	220	32	,	,	PUNCT
eurjchem-1675	220	33	60.7	60.7	NUM
eurjchem-1675	220	34	(	(	PUNCT
eurjchem-1675	220	35	ch2	ch2	PROPN
eurjchem-1675	220	36	)	)	PUNCT
eurjchem-1675	220	37	,	,	PUNCT
eurjchem-1675	220	38	113.2	113.2	NUM
eurjchem-1675	220	39	(	(	PUNCT
eurjchem-1675	220	40	ch	ch	NOUN
eurjchem-1675	220	41	)	)	PUNCT
eurjchem-1675	220	42	,	,	PUNCT
eurjchem-1675	220	43	115.3	115.3	NUM
eurjchem-1675	220	44	(	(	PUNCT
eurjchem-1675	220	45	cn	cn	PROPN
eurjchem-1675	220	46	)	)	PUNCT
eurjchem-1675	220	47	,	,	PUNCT
eurjchem-1675	220	48	119.3	119.3	NUM
eurjchem-1675	220	49	(	(	PUNCT
eurjchem-1675	220	50	ch	ch	NOUN
eurjchem-1675	220	51	)	)	PUNCT
eurjchem-1675	220	52	,	,	PUNCT
eurjchem-1675	220	53	129.3	129.3	NUM
eurjchem-1675	220	54	(	(	PUNCT
eurjchem-1675	220	55	ch	ch	NOUN
eurjchem-1675	220	56	)	)	PUNCT
eurjchem-1675	220	57	,	,	PUNCT
eurjchem-1675	220	58	139.3	139.3	NUM
eurjchem-1675	220	59	(	(	PUNCT
eurjchem-1675	220	60	ch	ch	NOUN
eurjchem-1675	220	61	)	)	PUNCT
eurjchem-1675	220	62	,	,	PUNCT
eurjchem-1675	220	63	154.0	154.0	NUM
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eurjchem-1675	220	65	ch	ch	NOUN
eurjchem-1675	220	66	=	=	SYM
eurjchem-1675	220	67	s	s	PART
eurjchem-1675	220	68	)	)	PUNCT
eurjchem-1675	220	69	,	,	PUNCT
eurjchem-1675	220	70	160.2	160.2	NUM
eurjchem-1675	220	71	(	(	PUNCT
eurjchem-1675	220	72	c	c	NOUN
eurjchem-1675	220	73	=	=	NOUN
eurjchem-1675	220	74	o	o	NOUN
eurjchem-1675	220	75	)	)	PUNCT
eurjchem-1675	220	76	.	.	PUNCT
eurjchem-1675	221	1	ms	ms	NOUN
eurjchem-1675	221	2	(	(	PUNCT
eurjchem-1675	221	3	m	m	PROPN
eurjchem-1675	221	4	/	/	SYM
eurjchem-1675	221	5	z	z	NOUN
eurjchem-1675	221	6	(	(	PUNCT
eurjchem-1675	221	7	%	%	NOUN
eurjchem-1675	221	8	)	)	PUNCT
eurjchem-1675	221	9	):	):	PUNCT
eurjchem-1675	221	10	398	398	NUM
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eurjchem-1675	221	12	m+	m+	NUM
eurjchem-1675	221	13	,	,	PUNCT
eurjchem-1675	221	14	100.0	100.0	NUM
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eurjchem-1675	221	16	,	,	PUNCT
eurjchem-1675	221	17	370	370	NUM
eurjchem-1675	221	18	(	(	PUNCT
eurjchem-1675	221	19	80	80	NUM
eurjchem-1675	221	20	%	%	NOUN
eurjchem-1675	221	21	)	)	PUNCT
eurjchem-1675	221	22	.	.	PUNCT
eurjchem-1675	222	1	anal	anal	PROPN
eurjchem-1675	222	2	.	.	PUNCT
eurjchem-1675	222	3	calcd	calcd	NOUN
eurjchem-1675	222	4	.	.	PUNCT
eurjchem-1675	223	1	for	for	ADP
eurjchem-1675	223	2	c20h22n4o3s	c20h22n4o3s	NUM
eurjchem-1675	223	3	:	:	PUNCT
eurjchem-1675	223	4	c	c	X
eurjchem-1675	223	5	,	,	PUNCT
eurjchem-1675	223	6	60.28	60.28	NUM
eurjchem-1675	223	7	;	;	PUNCT
eurjchem-1675	223	8	h	h	NOUN
eurjchem-1675	223	9	,	,	PUNCT
eurjchem-1675	223	10	5.57	5.57	NUM
eurjchem-1675	223	11	;	;	PUNCT
eurjchem-1675	223	12	n	n	CCONJ
eurjchem-1675	223	13	,	,	PUNCT
eurjchem-1675	223	14	14.06	14.06	NUM
eurjchem-1675	223	15	.	.	PUNCT
eurjchem-1675	223	16	found	find	VERB
eurjchem-1675	223	17	:	:	PUNCT
eurjchem-1675	224	1	c	c	X
eurjchem-1675	224	2	,	,	PUNCT
eurjchem-1675	224	3	60.30	60.30	NUM
eurjchem-1675	224	4	;	;	PUNCT
eurjchem-1675	224	5	h	h	NOUN
eurjchem-1675	224	6	,	,	PUNCT
eurjchem-1675	224	7	5.58	5.58	NUM
eurjchem-1675	224	8	;	;	PUNCT
eurjchem-1675	224	9	n	n	CCONJ
eurjchem-1675	224	10	,	,	PUNCT
eurjchem-1675	224	11	14.09	14.09	NUM
eurjchem-1675	224	12	%	%	NOUN
eurjchem-1675	224	13	.	.	PUNCT
eurjchem-1675	225	1	2-(5	2-(5	NOUN
eurjchem-1675	225	2	-	-	PUNCT
eurjchem-1675	225	3	benzoyl-3	benzoyl-3	NUM
eurjchem-1675	225	4	-	-	PUNCT
eurjchem-1675	225	5	phenyl-1	phenyl-1	NOUN
eurjchem-1675	225	6	,	,	PUNCT
eurjchem-1675	225	7	3	3	NUM
eurjchem-1675	225	8	,	,	PUNCT
eurjchem-1675	225	9	4	4	NUM
eurjchem-1675	225	10	-	-	PUNCT
eurjchem-1675	225	11	thiadiazol-2(3h)-ylidene)-2cyano	thiadiazol-2(3h)-ylidene)-2cyano	NUM
eurjchem-1675	225	12	-	-	PUNCT
eurjchem-1675	225	13	n	n	CCONJ
eurjchem-1675	225	14	-	-	PUNCT
eurjchem-1675	225	15	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	225	16	(	(	PUNCT
eurjchem-1675	225	17	24e	24e	NUM
eurjchem-1675	225	18	):	):	PUNCT
eurjchem-1675	225	19	color	color	NOUN
eurjchem-1675	225	20	:	:	PUNCT
eurjchem-1675	225	21	brown	brown	ADJ
eurjchem-1675	225	22	.	.	PUNCT
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eurjchem-1675	225	24	:	:	PUNCT
eurjchem-1675	225	25	75	75	NUM
eurjchem-1675	225	26	%	%	NOUN
eurjchem-1675	225	27	.	.	PUNCT
eurjchem-1675	226	1	2018	2018	NUM
eurjchem-1675	226	2	–	–	PUNCT
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eurjchem-1675	226	7	–	–	PUNCT
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eurjchem-1675	226	10	nc	nc	PROPN
eurjchem-1675	226	11	–	–	PUNCT
eurjchem-1675	226	12	doi	doi	NOUN
eurjchem-1675	226	13	:	:	PUNCT
eurjchem-1675	226	14	10.5155	10.5155	NUM
eurjchem-1675	226	15	/	/	SYM
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eurjchem-1675	226	17	-	-	SYM
eurjchem-1675	226	18	38.1675	38.1675	NUM
eurjchem-1675	226	19	fahim	fahim	PROPN
eurjchem-1675	226	20	et	et	PROPN
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eurjchem-1675	226	22	.	.	PUNCT
eurjchem-1675	226	23	/	/	SYM
eurjchem-1675	226	24	european	european	PROPN
eurjchem-1675	226	25	journal	journal	PROPN
eurjchem-1675	226	26	of	of	ADP
eurjchem-1675	226	27	chemistry	chemistry	NOUN
eurjchem-1675	226	28	9	9	NUM
eurjchem-1675	226	29	(	(	PUNCT
eurjchem-1675	226	30	1	1	NUM
eurjchem-1675	226	31	)	)	PUNCT
eurjchem-1675	226	32	(	(	PUNCT
eurjchem-1675	226	33	2018	2018	NUM
eurjchem-1675	226	34	)	)	PUNCT
eurjchem-1675	226	35	30	30	NUM
eurjchem-1675	226	36	-	-	SYM
eurjchem-1675	226	37	38	38	NUM
eurjchem-1675	226	38	35	35	NUM
eurjchem-1675	226	39	m.p	m.p	NOUN
eurjchem-1675	226	40	.	.	PROPN
eurjchem-1675	226	41	:	:	PUNCT
eurjchem-1675	226	42	174	174	NUM
eurjchem-1675	226	43	-	-	SYM
eurjchem-1675	226	44	176	176	NUM
eurjchem-1675	226	45	°	°	PROPN
eurjchem-1675	226	46	c	c	NOUN
eurjchem-1675	226	47	.	.	PUNCT
eurjchem-1675	227	1	ft	ft	PROPN
eurjchem-1675	227	2	-	-	PUNCT
eurjchem-1675	227	3	ir	ir	PROPN
eurjchem-1675	227	4	(	(	PUNCT
eurjchem-1675	227	5	kbr	kbr	PROPN
eurjchem-1675	227	6	,	,	PUNCT
eurjchem-1675	227	7	ν	ν	PROPN
eurjchem-1675	227	8	,	,	PUNCT
eurjchem-1675	227	9	cm-1	cm-1	NUM
eurjchem-1675	227	10	):	):	PUNCT
eurjchem-1675	227	11	1646	1646	NUM
eurjchem-1675	227	12	(	(	PUNCT
eurjchem-1675	227	13	c	c	NOUN
eurjchem-1675	227	14	=	=	NOUN
eurjchem-1675	227	15	o	o	NOUN
eurjchem-1675	227	16	)	)	PUNCT
eurjchem-1675	227	17	,	,	PUNCT
eurjchem-1675	227	18	2171	2171	NUM
eurjchem-1675	227	19	(	(	PUNCT
eurjchem-1675	227	20	c	c	NOUN
eurjchem-1675	227	21	=	=	SYM
eurjchem-1675	227	22	n	n	NUM
eurjchem-1675	227	23	)	)	PUNCT
eurjchem-1675	227	24	,	,	PUNCT
eurjchem-1675	227	25	3262	3262	NUM
eurjchem-1675	227	26	(	(	PUNCT
eurjchem-1675	227	27	nh	nh	NOUN
eurjchem-1675	227	28	)	)	PUNCT
eurjchem-1675	227	29	.	.	PUNCT
eurjchem-1675	228	1	1h	1h	NUM
eurjchem-1675	228	2	nmr	nmr	NOUN
eurjchem-1675	228	3	(	(	PUNCT
eurjchem-1675	228	4	300	300	NUM
eurjchem-1675	228	5	mhz	mhz	NOUN
eurjchem-1675	228	6	,	,	PUNCT
eurjchem-1675	228	7	dmso	dmso	NOUN
eurjchem-1675	228	8	-	-	NOUN
eurjchem-1675	228	9	d6	d6	NOUN
eurjchem-1675	228	10	,	,	PUNCT
eurjchem-1675	228	11	δ	δ	PROPN
eurjchem-1675	228	12	,	,	PUNCT
eurjchem-1675	228	13	ppm	ppm	NUM
eurjchem-1675	228	14	):	):	PUNCT
eurjchem-1675	228	15	1.291.38	1.291.38	NUM
eurjchem-1675	228	16	(	(	PUNCT
eurjchem-1675	228	17	m	m	PROPN
eurjchem-1675	228	18	,	,	PUNCT
eurjchem-1675	228	19	10h	10h	NUM
eurjchem-1675	228	20	,	,	PUNCT
eurjchem-1675	228	21	h2c	h2c	PROPN
eurjchem-1675	228	22	)	)	PUNCT
eurjchem-1675	228	23	,	,	PUNCT
eurjchem-1675	228	24	3.58	3.58	NUM
eurjchem-1675	228	25	(	(	PUNCT
eurjchem-1675	228	26	s	s	PROPN
eurjchem-1675	228	27	,	,	PUNCT
eurjchem-1675	228	28	1h	1h	NUM
eurjchem-1675	228	29	,	,	PUNCT
eurjchem-1675	228	30	hc	hc	PROPN
eurjchem-1675	228	31	-	-	PUNCT
eurjchem-1675	228	32	nh	nh	NOUN
eurjchem-1675	228	33	)	)	PUNCT
eurjchem-1675	228	34	,	,	PUNCT
eurjchem-1675	228	35	6.50	6.50	NUM
eurjchem-1675	228	36	-	-	SYM
eurjchem-1675	228	37	7.07	7.07	NUM
eurjchem-1675	228	38	(	(	PUNCT
eurjchem-1675	228	39	m	m	PROPN
eurjchem-1675	228	40	,	,	PUNCT
eurjchem-1675	228	41	5h	5h	NUM
eurjchem-1675	228	42	,	,	PUNCT
eurjchem-1675	228	43	arh	arh	PROPN
eurjchem-1675	228	44	)	)	PUNCT
eurjchem-1675	228	45	,	,	PUNCT
eurjchem-1675	228	46	7.45	7.45	NUM
eurjchem-1675	228	47	(	(	PUNCT
eurjchem-1675	228	48	m	m	PROPN
eurjchem-1675	228	49	,	,	PUNCT
eurjchem-1675	228	50	3h	3h	NUM
eurjchem-1675	228	51	,	,	PUNCT
eurjchem-1675	228	52	ar	ar	NOUN
eurjchem-1675	228	53	-	-	NOUN
eurjchem-1675	228	54	h	h	NOUN
eurjchem-1675	228	55	)	)	PUNCT
eurjchem-1675	228	56	,	,	PUNCT
eurjchem-1675	228	57	7.81	7.81	NUM
eurjchem-1675	228	58	(	(	PUNCT
eurjchem-1675	228	59	d	d	PROPN
eurjchem-1675	228	60	,	,	PUNCT
eurjchem-1675	228	61	2h	2h	NUM
eurjchem-1675	228	62	,	,	PUNCT
eurjchem-1675	228	63	j	j	PROPN
eurjchem-1675	228	64	=	=	SYM
eurjchem-1675	228	65	3.1	3.1	NUM
eurjchem-1675	228	66	hz	hz	NOUN
eurjchem-1675	228	67	,	,	PUNCT
eurjchem-1675	228	68	ar	ar	NOUN
eurjchem-1675	228	69	-	-	NOUN
eurjchem-1675	228	70	h	h	NOUN
eurjchem-1675	228	71	)	)	PUNCT
eurjchem-1675	228	72	,	,	PUNCT
eurjchem-1675	228	73	7.936	7.936	NUM
eurjchem-1675	228	74	(	(	PUNCT
eurjchem-1675	228	75	s	s	PROPN
eurjchem-1675	228	76	,	,	PUNCT
eurjchem-1675	228	77	1h	1h	NUM
eurjchem-1675	228	78	,	,	PUNCT
eurjchem-1675	228	79	hn	hn	PROPN
eurjchem-1675	228	80	d2o	d2o	NOUN
eurjchem-1675	228	81	-	-	PUNCT
eurjchem-1675	228	82	exchangable	exchangable	ADJ
eurjchem-1675	228	83	)	)	PUNCT
eurjchem-1675	228	84	.	.	PUNCT
eurjchem-1675	229	1	13c	13c	NOUN
eurjchem-1675	229	2	nmr	nmr	NOUN
eurjchem-1675	229	3	(	(	PUNCT
eurjchem-1675	229	4	75	75	NUM
eurjchem-1675	229	5	mhz	mhz	NOUN
eurjchem-1675	229	6	,	,	PUNCT
eurjchem-1675	229	7	dmso	dmso	NOUN
eurjchem-1675	229	8	-	-	NOUN
eurjchem-1675	229	9	d6	d6	NOUN
eurjchem-1675	229	10	,	,	PUNCT
eurjchem-1675	229	11	δ	δ	PROPN
eurjchem-1675	229	12	,	,	PUNCT
eurjchem-1675	229	13	ppm	ppm	NUM
eurjchem-1675	229	14	):	):	PUNCT
eurjchem-1675	229	15	23.3	23.3	NUM
eurjchem-1675	229	16	(	(	PUNCT
eurjchem-1675	229	17	ch3	ch3	PROPN
eurjchem-1675	229	18	)	)	PUNCT
eurjchem-1675	229	19	,	,	PUNCT
eurjchem-1675	229	20	28.6	28.6	NUM
eurjchem-1675	229	21	(	(	PUNCT
eurjchem-1675	229	22	ch2	ch2	PROPN
eurjchem-1675	229	23	)	)	PUNCT
eurjchem-1675	229	24	,	,	PUNCT
eurjchem-1675	229	25	47.6	47.6	NUM
eurjchem-1675	229	26	(	(	PUNCT
eurjchem-1675	229	27	ch	ch	NOUN
eurjchem-1675	229	28	)	)	PUNCT
eurjchem-1675	229	29	,	,	PUNCT
eurjchem-1675	229	30	60.7	60.7	NUM
eurjchem-1675	229	31	(	(	PUNCT
eurjchem-1675	229	32	ch2	ch2	PROPN
eurjchem-1675	229	33	)	)	PUNCT
eurjchem-1675	229	34	,	,	PUNCT
eurjchem-1675	229	35	113.2	113.2	NUM
eurjchem-1675	229	36	(	(	PUNCT
eurjchem-1675	229	37	ch	ch	NOUN
eurjchem-1675	229	38	)	)	PUNCT
eurjchem-1675	229	39	,	,	PUNCT
eurjchem-1675	229	40	115.3	115.3	NUM
eurjchem-1675	229	41	(	(	PUNCT
eurjchem-1675	229	42	cn	cn	PROPN
eurjchem-1675	229	43	)	)	PUNCT
eurjchem-1675	229	44	,	,	PUNCT
eurjchem-1675	229	45	116.3	116.3	NUM
eurjchem-1675	229	46	(	(	PUNCT
eurjchem-1675	229	47	ch	ch	NOUN
eurjchem-1675	229	48	)	)	PUNCT
eurjchem-1675	229	49	,	,	PUNCT
eurjchem-1675	229	50	119.3	119.3	NUM
eurjchem-1675	229	51	(	(	PUNCT
eurjchem-1675	229	52	ch	ch	NOUN
eurjchem-1675	229	53	)	)	PUNCT
eurjchem-1675	229	54	,	,	PUNCT
eurjchem-1675	229	55	129.3	129.3	NUM
eurjchem-1675	229	56	(	(	PUNCT
eurjchem-1675	229	57	ch	ch	NOUN
eurjchem-1675	229	58	)	)	PUNCT
eurjchem-1675	229	59	,	,	PUNCT
eurjchem-1675	229	60	134.3	134.3	NUM
eurjchem-1675	229	61	(	(	PUNCT
eurjchem-1675	229	62	ch	ch	NOUN
eurjchem-1675	229	63	)	)	PUNCT
eurjchem-1675	229	64	,	,	PUNCT
eurjchem-1675	229	65	146.0	146.0	NUM
eurjchem-1675	229	66	(	(	PUNCT
eurjchem-1675	229	67	ch	ch	NOUN
eurjchem-1675	229	68	)	)	PUNCT
eurjchem-1675	229	69	,	,	PUNCT
eurjchem-1675	229	70	154.0	154.0	NUM
eurjchem-1675	229	71	(	(	PUNCT
eurjchem-1675	229	72	ch	ch	NOUN
eurjchem-1675	229	73	=	=	SYM
eurjchem-1675	229	74	s	s	PART
eurjchem-1675	229	75	)	)	PUNCT
eurjchem-1675	229	76	,	,	PUNCT
eurjchem-1675	229	77	160.2	160.2	NUM
eurjchem-1675	229	78	(	(	PUNCT
eurjchem-1675	229	79	c	c	NOUN
eurjchem-1675	229	80	=	=	NOUN
eurjchem-1675	229	81	o	o	NOUN
eurjchem-1675	229	82	)	)	PUNCT
eurjchem-1675	229	83	,	,	PUNCT
eurjchem-1675	229	84	183.0	183.0	NUM
eurjchem-1675	229	85	(	(	PUNCT
eurjchem-1675	229	86	c	c	NOUN
eurjchem-1675	229	87	=	=	NOUN
eurjchem-1675	229	88	o	o	NOUN
eurjchem-1675	229	89	)	)	PUNCT
eurjchem-1675	229	90	.	.	PUNCT
eurjchem-1675	230	1	ms	ms	NOUN
eurjchem-1675	230	2	(	(	PUNCT
eurjchem-1675	230	3	m	m	PROPN
eurjchem-1675	230	4	/	/	SYM
eurjchem-1675	230	5	z	z	NOUN
eurjchem-1675	230	6	(	(	PUNCT
eurjchem-1675	230	7	%	%	NOUN
eurjchem-1675	230	8	)	)	PUNCT
eurjchem-1675	230	9	):	):	PUNCT
eurjchem-1675	230	10	430	430	NUM
eurjchem-1675	230	11	(	(	PUNCT
eurjchem-1675	230	12	m+	m+	NUM
eurjchem-1675	230	13	,	,	PUNCT
eurjchem-1675	230	14	100.0	100.0	NUM
eurjchem-1675	230	15	)	)	PUNCT
eurjchem-1675	230	16	.	.	PUNCT
eurjchem-1675	231	1	anal	anal	PROPN
eurjchem-1675	231	2	.	.	PUNCT
eurjchem-1675	231	3	calcd	calcd	NOUN
eurjchem-1675	231	4	.	.	PUNCT
eurjchem-1675	232	1	for	for	ADP
eurjchem-1675	232	2	c24h22n4o3s	c24h22n4o3s	NUM
eurjchem-1675	232	3	:	:	PUNCT
eurjchem-1675	232	4	c	c	X
eurjchem-1675	232	5	,	,	PUNCT
eurjchem-1675	232	6	66.96	66.96	NUM
eurjchem-1675	232	7	;	;	PUNCT
eurjchem-1675	232	8	h	h	NOUN
eurjchem-1675	232	9	,	,	PUNCT
eurjchem-1675	232	10	5.15	5.15	NUM
eurjchem-1675	232	11	;	;	PUNCT
eurjchem-1675	232	12	n	n	CCONJ
eurjchem-1675	232	13	,	,	PUNCT
eurjchem-1675	232	14	13.01	13.01	NUM
eurjchem-1675	232	15	.	.	PUNCT
eurjchem-1675	232	16	found	find	VERB
eurjchem-1675	232	17	:	:	PUNCT
eurjchem-1675	233	1	c	c	X
eurjchem-1675	233	2	,	,	PUNCT
eurjchem-1675	233	3	66.98	66.98	NUM
eurjchem-1675	233	4	;	;	PUNCT
eurjchem-1675	233	5	h	h	NOUN
eurjchem-1675	233	6	,	,	PUNCT
eurjchem-1675	233	7	5.17	5.17	NUM
eurjchem-1675	233	8	;	;	PUNCT
eurjchem-1675	233	9	n	n	CCONJ
eurjchem-1675	233	10	,	,	PUNCT
eurjchem-1675	233	11	13.06	13.06	NUM
eurjchem-1675	233	12	%	%	NOUN
eurjchem-1675	233	13	.	.	PUNCT
eurjchem-1675	234	1	3	3	X
eurjchem-1675	234	2	.	.	NOUN
eurjchem-1675	234	3	results	result	NOUN
eurjchem-1675	234	4	and	and	CCONJ
eurjchem-1675	234	5	discussion	discussion	NOUN
eurjchem-1675	234	6	3.1	3.1	NUM
eurjchem-1675	234	7	.	.	PUNCT
eurjchem-1675	235	1	chemistry	chemistry	NOUN
eurjchem-1675	235	2	the	the	DET
eurjchem-1675	235	3	reaction	reaction	NOUN
eurjchem-1675	235	4	between	between	ADP
eurjchem-1675	235	5	cyclohexylamine	cyclohexylamine	NOUN
eurjchem-1675	235	6	(	(	PUNCT
eurjchem-1675	235	7	1	1	NUM
eurjchem-1675	235	8	)	)	PUNCT
eurjchem-1675	235	9	and	and	CCONJ
eurjchem-1675	235	10	ethyl	ethyl	PROPN
eurjchem-1675	235	11	cyanoacetate	cyanoacetate	NOUN
eurjchem-1675	235	12	(	(	PUNCT
eurjchem-1675	235	13	2	2	NUM
eurjchem-1675	235	14	)	)	PUNCT
eurjchem-1675	235	15	without	without	ADP
eurjchem-1675	235	16	solvent	solvent	NOUN
eurjchem-1675	235	17	under	under	ADP
eurjchem-1675	235	18	microwave	microwave	NOUN
eurjchem-1675	235	19	irradiation	irradiation	NOUN
eurjchem-1675	235	20	afforded	afford	VERB
eurjchem-1675	235	21	the	the	DET
eurjchem-1675	235	22	corresponding	correspond	VERB
eurjchem-1675	235	23	2	2	NUM
eurjchem-1675	235	24	-	-	PUNCT
eurjchem-1675	235	25	cyano	cyano	NOUN
eurjchem-1675	235	26	-	-	PUNCT
eurjchem-1675	235	27	n	n	CCONJ
eurjchem-1675	235	28	-	-	PUNCT
eurjchem-1675	235	29	cyclohexyacetamide	cyclohexyacetamide	NOUN
eurjchem-1675	235	30	(	(	PUNCT
eurjchem-1675	235	31	3	3	NUM
eurjchem-1675	235	32	)	)	PUNCT
eurjchem-1675	235	33	in	in	ADP
eurjchem-1675	235	34	excellent	excellent	ADJ
eurjchem-1675	235	35	yield	yield	NOUN
eurjchem-1675	235	36	as	as	SCONJ
eurjchem-1675	235	37	displayed	display	VERB
eurjchem-1675	235	38	in	in	ADP
eurjchem-1675	235	39	scheme	scheme	NOUN
eurjchem-1675	235	40	1	1	NUM
eurjchem-1675	235	41	.	.	PUNCT
eurjchem-1675	236	1	the	the	DET
eurjchem-1675	236	2	ir	ir	PROPN
eurjchem-1675	236	3	spectrum	spectrum	NOUN
eurjchem-1675	236	4	of	of	ADP
eurjchem-1675	236	5	the	the	DET
eurjchem-1675	236	6	reaction	reaction	NOUN
eurjchem-1675	236	7	product	product	NOUN
eurjchem-1675	236	8	indicated	indicate	VERB
eurjchem-1675	236	9	three	three	NUM
eurjchem-1675	236	10	absorption	absorption	NOUN
eurjchem-1675	236	11	bands	band	NOUN
eurjchem-1675	236	12	at	at	ADP
eurjchem-1675	236	13	3278	3278	NUM
eurjchem-1675	236	14	(	(	PUNCT
eurjchem-1675	236	15	nh	nh	NOUN
eurjchem-1675	236	16	)	)	PUNCT
eurjchem-1675	236	17	,	,	PUNCT
eurjchem-1675	236	18	2204	2204	NUM
eurjchem-1675	236	19	(	(	PUNCT
eurjchem-1675	236	20	c≡n	c≡n	PROPN
eurjchem-1675	236	21	)	)	PUNCT
eurjchem-1675	236	22	,	,	PUNCT
eurjchem-1675	236	23	1662	1662	NUM
eurjchem-1675	236	24	cm-1	cm-1	X
eurjchem-1675	236	25	(	(	PUNCT
eurjchem-1675	236	26	c	c	NOUN
eurjchem-1675	236	27	=	=	NOUN
eurjchem-1675	236	28	o	o	NOUN
eurjchem-1675	236	29	)	)	PUNCT
eurjchem-1675	236	30	.	.	PUNCT
eurjchem-1675	237	1	the	the	DET
eurjchem-1675	237	2	mass	mass	PROPN
eurjchem-1675	237	3	spectrum	spectrum	PROPN
eurjchem-1675	237	4	exhibited	exhibit	VERB
eurjchem-1675	237	5	a	a	DET
eurjchem-1675	237	6	peak	peak	NOUN
eurjchem-1675	237	7	at	at	ADP
eurjchem-1675	237	8	m	m	PROPN
eurjchem-1675	237	9	/	/	SYM
eurjchem-1675	237	10	z	z	PROPN
eurjchem-1675	237	11	166	166	NUM
eurjchem-1675	237	12	attributable	attributable	ADJ
eurjchem-1675	237	13	to	to	ADP
eurjchem-1675	237	14	the	the	DET
eurjchem-1675	237	15	molecular	molecular	ADJ
eurjchem-1675	237	16	ion	ion	NOUN
eurjchem-1675	237	17	of	of	ADP
eurjchem-1675	237	18	the	the	DET
eurjchem-1675	237	19	acetamide	acetamide	NOUN
eurjchem-1675	237	20	3	3	NUM
eurjchem-1675	237	21	.	.	PUNCT
eurjchem-1675	238	1	the	the	DET
eurjchem-1675	238	2	assignment	assignment	NOUN
eurjchem-1675	238	3	is	be	AUX
eurjchem-1675	238	4	moreover	moreover	ADV
eurjchem-1675	238	5	assembled	assemble	VERB
eurjchem-1675	238	6	on	on	ADP
eurjchem-1675	238	7	the	the	DET
eurjchem-1675	238	8	incidence	incidence	NOUN
eurjchem-1675	238	9	of	of	ADP
eurjchem-1675	238	10	signals	signal	NOUN
eurjchem-1675	238	11	(	(	PUNCT
eurjchem-1675	238	12	δ	δ	PROPN
eurjchem-1675	238	13	1.40	1.40	NUM
eurjchem-1675	238	14	-	-	SYM
eurjchem-1675	238	15	1.70	1.70	NUM
eurjchem-1675	238	16	cyclohexyl	cyclohexyl	NOUN
eurjchem-1675	238	17	,	,	PUNCT
eurjchem-1675	238	18	δ	δ	PROPN
eurjchem-1675	238	19	3.30	3.30	NUM
eurjchem-1675	238	20	ch2	ch2	NOUN
eurjchem-1675	238	21	,	,	PUNCT
eurjchem-1675	238	22	and	and	CCONJ
eurjchem-1675	238	23	δ	δ	PROPN
eurjchem-1675	238	24	8.08	8.08	NUM
eurjchem-1675	238	25	ppm	ppm	PROPN
eurjchem-1675	238	26	nh	nh	PROPN
eurjchem-1675	238	27	)	)	PUNCT
eurjchem-1675	238	28	in	in	ADP
eurjchem-1675	238	29	1h	1h	NUM
eurjchem-1675	238	30	nmr	nmr	NOUN
eurjchem-1675	238	31	spectrum	spectrum	NOUN
eurjchem-1675	238	32	of	of	ADP
eurjchem-1675	238	33	the	the	DET
eurjchem-1675	238	34	reaction	reaction	NOUN
eurjchem-1675	238	35	product	product	NOUN
eurjchem-1675	238	36	and	and	CCONJ
eurjchem-1675	238	37	its	its	PRON
eurjchem-1675	238	38	13c	13c	NOUN
eurjchem-1675	238	39	nmr	nmr	NOUN
eurjchem-1675	238	40	exhibited	exhibit	VERB
eurjchem-1675	238	41	signals	signal	NOUN
eurjchem-1675	238	42	at	at	ADP
eurjchem-1675	238	43	active	active	ADJ
eurjchem-1675	238	44	methylene	methylene	NOUN
eurjchem-1675	238	45	group	group	NOUN
eurjchem-1675	238	46	at	at	ADP
eurjchem-1675	238	47	δ	δ	PROPN
eurjchem-1675	238	48	27.3	27.3	NUM
eurjchem-1675	238	49	ppm	ppm	NOUN
eurjchem-1675	238	50	and	and	CCONJ
eurjchem-1675	238	51	carbonyl	carbonyl	NOUN
eurjchem-1675	238	52	group	group	NOUN
eurjchem-1675	238	53	at	at	ADP
eurjchem-1675	238	54	δ	δ	PROPN
eurjchem-1675	238	55	171.2	171.2	NUM
eurjchem-1675	238	56	ppm	ppm	NOUN
eurjchem-1675	238	57	.	.	PUNCT
eurjchem-1675	239	1	performance	performance	NOUN
eurjchem-1675	239	2	of	of	ADP
eurjchem-1675	239	3	2	2	NUM
eurjchem-1675	239	4	-	-	PUNCT
eurjchem-1675	239	5	cyano	cyano	NOUN
eurjchem-1675	239	6	-	-	PUNCT
eurjchem-1675	239	7	n	n	CCONJ
eurjchem-1675	239	8	-	-	PUNCT
eurjchem-1675	239	9	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	239	10	(	(	PUNCT
eurjchem-1675	239	11	3	3	NUM
eurjchem-1675	239	12	)	)	PUNCT
eurjchem-1675	239	13	with	with	ADP
eurjchem-1675	239	14	the	the	DET
eurjchem-1675	239	15	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1675	239	16	chloride	chloride	NOUN
eurjchem-1675	239	17	4	4	NUM
eurjchem-1675	239	18	in	in	ADP
eurjchem-1675	239	19	ethanolic	ethanolic	ADJ
eurjchem-1675	239	20	sodium	sodium	NOUN
eurjchem-1675	239	21	ethoxide	ethoxide	NOUN
eurjchem-1675	239	22	solution	solution	NOUN
eurjchem-1675	240	1	,	,	PUNCT
eurjchem-1675	240	2	it	it	PRON
eurjchem-1675	240	3	provides	provide	VERB
eurjchem-1675	240	4	a	a	DET
eurjchem-1675	240	5	single	single	ADJ
eurjchem-1675	240	6	product	product	NOUN
eurjchem-1675	240	7	for	for	ADP
eurjchem-1675	240	8	which	which	PRON
eurjchem-1675	240	9	the	the	DET
eurjchem-1675	240	10	two	two	NUM
eurjchem-1675	240	11	possible	possible	ADJ
eurjchem-1675	240	12	structures	structure	NOUN
eurjchem-1675	240	13	6	6	NUM
eurjchem-1675	240	14	and	and	CCONJ
eurjchem-1675	240	15	8	8	NUM
eurjchem-1675	240	16	can	can	AUX
eurjchem-1675	240	17	be	be	AUX
eurjchem-1675	240	18	deliberated	deliberate	VERB
eurjchem-1675	240	19	(	(	PUNCT
eurjchem-1675	240	20	scheme	scheme	NOUN
eurjchem-1675	240	21	1	1	NUM
eurjchem-1675	240	22	)	)	PUNCT
eurjchem-1675	240	23	.	.	PUNCT
eurjchem-1675	241	1	nevertheless	nevertheless	ADV
eurjchem-1675	241	2	,	,	PUNCT
eurjchem-1675	241	3	elemental	elemental	ADJ
eurjchem-1675	241	4	analysis	analysis	NOUN
eurjchem-1675	241	5	and	and	CCONJ
eurjchem-1675	241	6	spectral	spectral	ADJ
eurjchem-1675	241	7	data	datum	NOUN
eurjchem-1675	241	8	were	be	AUX
eurjchem-1675	241	9	in	in	ADP
eurjchem-1675	241	10	complete	complete	ADJ
eurjchem-1675	241	11	agreement	agreement	NOUN
eurjchem-1675	241	12	with	with	ADP
eurjchem-1675	241	13	the	the	DET
eurjchem-1675	241	14	aminopyrazole	aminopyrazole	NOUN
eurjchem-1675	241	15	structure	structure	NOUN
eurjchem-1675	241	16	6	6	NUM
eurjchem-1675	241	17	.	.	PUNCT
eurjchem-1675	242	1	for	for	ADP
eurjchem-1675	242	2	instance	instance	NOUN
eurjchem-1675	242	3	,	,	PUNCT
eurjchem-1675	242	4	the	the	DET
eurjchem-1675	242	5	ir	ir	PROPN
eurjchem-1675	242	6	spectrum	spectrum	NOUN
eurjchem-1675	242	7	of	of	ADP
eurjchem-1675	242	8	the	the	DET
eurjchem-1675	242	9	aminopyrazole	aminopyrazole	NOUN
eurjchem-1675	242	10	6	6	NUM
eurjchem-1675	242	11	displayed	display	VERB
eurjchem-1675	242	12	absorption	absorption	NOUN
eurjchem-1675	242	13	bands	band	NOUN
eurjchem-1675	242	14	at	at	ADP
eurjchem-1675	242	15	and	and	CCONJ
eurjchem-1675	242	16	3280	3280	NUM
eurjchem-1675	242	17	cm-1	cm-1	VERB
eurjchem-1675	242	18	owing	owe	VERB
eurjchem-1675	242	19	to	to	ADP
eurjchem-1675	242	20	amino	amino	NOUN
eurjchem-1675	242	21	group	group	NOUN
eurjchem-1675	242	22	and	and	CCONJ
eurjchem-1675	242	23	exposed	expose	VERB
eurjchem-1675	242	24	bands	band	NOUN
eurjchem-1675	242	25	1691	1691	NUM
eurjchem-1675	242	26	and	and	CCONJ
eurjchem-1675	242	27	3409	3409	NUM
eurjchem-1675	242	28	cm-1	cm-1	X
eurjchem-1675	242	29	due	due	ADP
eurjchem-1675	242	30	to	to	ADP
eurjchem-1675	242	31	amide	amide	NOUN
eurjchem-1675	242	32	-	-	PUNCT
eurjchem-1675	242	33	nh	nh	PROPN
eurjchem-1675	242	34	and	and	CCONJ
eurjchem-1675	242	35	a	a	DET
eurjchem-1675	242	36	carbonyl	carbonyl	NOUN
eurjchem-1675	242	37	group	group	NOUN
eurjchem-1675	242	38	,	,	PUNCT
eurjchem-1675	242	39	respectively	respectively	ADV
eurjchem-1675	242	40	.	.	PUNCT
eurjchem-1675	243	1	additionally	additionally	ADV
eurjchem-1675	243	2	,	,	PUNCT
eurjchem-1675	243	3	its	its	PRON
eurjchem-1675	243	4	1h	1h	NUM
eurjchem-1675	243	5	nmr	nmr	NOUN
eurjchem-1675	243	6	spectrum	spectrum	NOUN
eurjchem-1675	243	7	exposed	expose	VERB
eurjchem-1675	243	8	a	a	DET
eurjchem-1675	243	9	signal	signal	NOUN
eurjchem-1675	243	10	at	at	ADP
eurjchem-1675	243	11	δ	δ	PROPN
eurjchem-1675	243	12	6.52	6.52	NUM
eurjchem-1675	243	13	and	and	CCONJ
eurjchem-1675	243	14	8.05	8.05	NUM
eurjchem-1675	243	15	ppm	ppm	NOUN
eurjchem-1675	243	16	conforming	conforming	NOUN
eurjchem-1675	243	17	to	to	ADP
eurjchem-1675	243	18	nh	nh	PROPN
eurjchem-1675	243	19	and	and	CCONJ
eurjchem-1675	243	20	nh2	nh2	PROPN
eurjchem-1675	243	21	protons	proton	NOUN
eurjchem-1675	243	22	,	,	PUNCT
eurjchem-1675	243	23	respectively	respectively	ADV
eurjchem-1675	243	24	in	in	ADP
eurjchem-1675	243	25	adding	add	VERB
eurjchem-1675	243	26	to	to	ADP
eurjchem-1675	243	27	an	an	DET
eurjchem-1675	243	28	aliphatic	aliphatic	ADJ
eurjchem-1675	243	29	multiple	multiple	NOUN
eurjchem-1675	243	30	at	at	ADP
eurjchem-1675	243	31	δ	δ	PROPN
eurjchem-1675	243	32	1.39	1.39	NUM
eurjchem-1675	243	33	-	-	SYM
eurjchem-1675	243	34	1.49	1.49	NUM
eurjchem-1675	243	35	ppm	ppm	NOUN
eurjchem-1675	243	36	.	.	PUNCT
eurjchem-1675	244	1	consequently	consequently	ADV
eurjchem-1675	244	2	,	,	PUNCT
eurjchem-1675	244	3	the	the	DET
eurjchem-1675	244	4	synthesis	synthesis	NOUN
eurjchem-1675	244	5	of	of	ADP
eurjchem-1675	244	6	some	some	DET
eurjchem-1675	244	7	cyclohexyl	cyclohexyl	NOUN
eurjchem-1675	244	8	-	-	PUNCT
eurjchem-1675	244	9	based	base	VERB
eurjchem-1675	244	10	1,3,4	1,3,4	NUM
eurjchem-1675	244	11	-	-	PUNCT
eurjchem-1675	244	12	thiadiazole	thiadiazole	NOUN
eurjchem-1675	244	13	derivatives	derivative	NOUN
eurjchem-1675	244	14	is	be	AUX
eurjchem-1675	244	15	tried	try	VERB
eurjchem-1675	244	16	.	.	PUNCT
eurjchem-1675	245	1	subsequently	subsequently	ADV
eurjchem-1675	245	2	,	,	PUNCT
eurjchem-1675	245	3	handling	handle	VERB
eurjchem-1675	245	4	2cyano	2cyano	NUM
eurjchem-1675	245	5	-	-	PUNCT
eurjchem-1675	245	6	n	n	CCONJ
eurjchem-1675	245	7	-	-	PUNCT
eurjchem-1675	245	8	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	245	9	(	(	PUNCT
eurjchem-1675	245	10	3	3	NUM
eurjchem-1675	245	11	)	)	PUNCT
eurjchem-1675	245	12	with	with	ADP
eurjchem-1675	245	13	phenyl	phenyl	NOUN
eurjchem-1675	245	14	isothiocyanate	isothiocyanate	NOUN
eurjchem-1675	245	15	in	in	ADP
eurjchem-1675	245	16	dimethyl	dimethyl	PROPN
eurjchem-1675	245	17	formamide	formamide	ADV
eurjchem-1675	245	18	,	,	PUNCT
eurjchem-1675	245	19	in	in	ADP
eurjchem-1675	245	20	presence	presence	NOUN
eurjchem-1675	245	21	of	of	ADP
eurjchem-1675	245	22	potassium	potassium	NOUN
eurjchem-1675	245	23	hydroxide	hydroxide	NOUN
eurjchem-1675	245	24	,	,	PUNCT
eurjchem-1675	245	25	at	at	ADP
eurjchem-1675	245	26	room	room	NOUN
eurjchem-1675	245	27	temperature	temperature	NOUN
eurjchem-1675	245	28	provided	provide	VERB
eurjchem-1675	245	29	the	the	DET
eurjchem-1675	245	30	non	non	ADJ
eurjchem-1675	245	31	-	-	ADJ
eurjchem-1675	245	32	isolable	isolable	ADJ
eurjchem-1675	245	33	intermediate	intermediate	ADJ
eurjchem-1675	245	34	potssium	potssium	NOUN
eurjchem-1675	245	35	salt	salt	NOUN
eurjchem-1675	245	36	9	9	NUM
eurjchem-1675	245	37	which	which	PRON
eurjchem-1675	245	38	was	be	AUX
eurjchem-1675	245	39	distorted	distort	VERB
eurjchem-1675	245	40	into	into	ADP
eurjchem-1675	245	41	the	the	DET
eurjchem-1675	245	42	consistent	consistent	ADJ
eurjchem-1675	245	43	2cyano	2cyano	NUM
eurjchem-1675	245	44	-	-	PUNCT
eurjchem-1675	245	45	n	n	CCONJ
eurjchem-1675	245	46	-	-	PUNCT
eurjchem-1675	245	47	cyclohexyl-3	cyclohexyl-3	NUM
eurjchem-1675	245	48	-	-	PUNCT
eurjchem-1675	245	49	mercapto-3-(phenylamino)acrylamide	mercapto-3-(phenylamino)acrylamide	NOUN
eurjchem-1675	245	50	(	(	PUNCT
eurjchem-1675	245	51	10	10	NUM
eurjchem-1675	245	52	)	)	PUNCT
eurjchem-1675	245	53	upon	upon	SCONJ
eurjchem-1675	245	54	handling	handle	VERB
eurjchem-1675	245	55	with	with	ADP
eurjchem-1675	245	56	dilute	dilute	NOUN
eurjchem-1675	245	57	hydrochloric	hydrochloric	ADJ
eurjchem-1675	245	58	acid	acid	NOUN
eurjchem-1675	245	59	as	as	SCONJ
eurjchem-1675	245	60	displayed	display	VERB
eurjchem-1675	245	61	in	in	ADP
eurjchem-1675	245	62	scheme	scheme	NOUN
eurjchem-1675	245	63	2	2	NUM
eurjchem-1675	245	64	.	.	PUNCT
eurjchem-1675	246	1	the	the	DET
eurjchem-1675	246	2	association	association	NOUN
eurjchem-1675	246	3	of	of	ADP
eurjchem-1675	246	4	the	the	DET
eurjchem-1675	246	5	latter	latter	ADJ
eurjchem-1675	246	6	product	product	NOUN
eurjchem-1675	246	7	was	be	AUX
eurjchem-1675	246	8	recognized	recognize	VERB
eurjchem-1675	246	9	on	on	ADP
eurjchem-1675	246	10	the	the	DET
eurjchem-1675	246	11	foundation	foundation	NOUN
eurjchem-1675	246	12	of	of	ADP
eurjchem-1675	246	13	its	its	PRON
eurjchem-1675	246	14	elemental	elemental	ADJ
eurjchem-1675	246	15	analysis	analysis	NOUN
eurjchem-1675	246	16	and	and	CCONJ
eurjchem-1675	246	17	spectral	spectral	ADJ
eurjchem-1675	246	18	analysis	analysis	NOUN
eurjchem-1675	246	19	.	.	PUNCT
eurjchem-1675	247	1	for	for	ADP
eurjchem-1675	247	2	instance	instance	NOUN
eurjchem-1675	247	3	,	,	PUNCT
eurjchem-1675	247	4	its	its	PRON
eurjchem-1675	247	5	ir	ir	PROPN
eurjchem-1675	247	6	spectrum	spectrum	NOUN
eurjchem-1675	247	7	exposed	expose	VERB
eurjchem-1675	247	8	a	a	DET
eurjchem-1675	247	9	characteristic	characteristic	ADJ
eurjchem-1675	247	10	band	band	NOUN
eurjchem-1675	247	11	at	at	ADP
eurjchem-1675	247	12	3266	3266	NUM
eurjchem-1675	247	13	cm-1	cm-1	VERB
eurjchem-1675	247	14	owing	owe	VERB
eurjchem-1675	247	15	to	to	ADP
eurjchem-1675	247	16	nh	nh	PROPN
eurjchem-1675	247	17	group	group	NOUN
eurjchem-1675	247	18	and	and	CCONJ
eurjchem-1675	247	19	two	two	NUM
eurjchem-1675	247	20	strong	strong	ADJ
eurjchem-1675	247	21	absorption	absorption	NOUN
eurjchem-1675	247	22	bands	band	NOUN
eurjchem-1675	247	23	at	at	ADP
eurjchem-1675	247	24	1670	1670	NUM
eurjchem-1675	247	25	and	and	CCONJ
eurjchem-1675	247	26	2250	2250	NUM
eurjchem-1675	247	27	cm-1	cm-1	X
eurjchem-1675	247	28	to	to	ADP
eurjchem-1675	247	29	c	c	NOUN
eurjchem-1675	247	30	=	=	NOUN
eurjchem-1675	247	31	o	o	NOUN
eurjchem-1675	247	32	and	and	CCONJ
eurjchem-1675	247	33	cyano	cyano	NOUN
eurjchem-1675	247	34	group	group	NOUN
eurjchem-1675	247	35	,	,	PUNCT
eurjchem-1675	247	36	respectively	respectively	ADV
eurjchem-1675	247	37	.	.	PUNCT
eurjchem-1675	248	1	its	its	PRON
eurjchem-1675	248	2	1h	1h	NUM
eurjchem-1675	248	3	nmr	nmr	NOUN
eurjchem-1675	248	4	exposed	expose	VERB
eurjchem-1675	248	5	signals	signal	NOUN
eurjchem-1675	248	6	at	at	ADP
eurjchem-1675	248	7	δ	δ	PROPN
eurjchem-1675	248	8	1.37	1.37	NUM
eurjchem-1675	248	9	-	-	SYM
eurjchem-1675	248	10	1.52	1.52	NUM
eurjchem-1675	248	11	ppm	ppm	NOUN
eurjchem-1675	248	12	aliphatic	aliphatic	ADJ
eurjchem-1675	248	13	multiplet	multiplet	NOUN
eurjchem-1675	248	14	corresponding	correspond	VERB
eurjchem-1675	248	15	to	to	ADP
eurjchem-1675	248	16	cyclohexyl	cyclohexyl	PROPN
eurjchem-1675	248	17	protons	proton	NOUN
eurjchem-1675	248	18	,	,	PUNCT
eurjchem-1675	248	19	at	at	ADP
eurjchem-1675	248	20	δ	δ	PROPN
eurjchem-1675	248	21	10.88	10.88	NUM
eurjchem-1675	248	22	and	and	CCONJ
eurjchem-1675	248	23	11.83	11.83	NUM
eurjchem-1675	248	24	ppm	ppm	NOUN
eurjchem-1675	248	25	due	due	ADP
eurjchem-1675	248	26	to	to	ADP
eurjchem-1675	248	27	nh	nh	PROPN
eurjchem-1675	248	28	and	and	CCONJ
eurjchem-1675	248	29	sh	sh	PROPN
eurjchem-1675	248	30	protons	proton	NOUN
eurjchem-1675	248	31	,	,	PUNCT
eurjchem-1675	248	32	respecttively	respecttively	ADV
eurjchem-1675	248	33	.	.	PUNCT
eurjchem-1675	249	1	additionally	additionally	ADV
eurjchem-1675	249	2	,	,	PUNCT
eurjchem-1675	249	3	its	its	PRON
eurjchem-1675	249	4	mass	mass	NOUN
eurjchem-1675	249	5	spectrum	spectrum	NOUN
eurjchem-1675	249	6	exposed	expose	VERB
eurjchem-1675	249	7	a	a	DET
eurjchem-1675	249	8	peak	peak	NOUN
eurjchem-1675	249	9	at	at	ADP
eurjchem-1675	249	10	m	m	PROPN
eurjchem-1675	249	11	/	/	SYM
eurjchem-1675	249	12	z	z	PROPN
eurjchem-1675	249	13	301	301	NUM
eurjchem-1675	249	14	corresponding	correspond	VERB
eurjchem-1675	249	15	to	to	ADP
eurjchem-1675	249	16	its	its	PRON
eurjchem-1675	249	17	molecular	molecular	ADJ
eurjchem-1675	249	18	ion	ion	NOUN
eurjchem-1675	249	19	.	.	PUNCT
eurjchem-1675	250	1	an	an	DET
eurjchem-1675	250	2	acceptable	acceptable	ADJ
eurjchem-1675	250	3	mechanism	mechanism	NOUN
eurjchem-1675	250	4	for	for	ADP
eurjchem-1675	250	5	the	the	DET
eurjchem-1675	250	6	synthesis	synthesis	NOUN
eurjchem-1675	250	7	of	of	ADP
eurjchem-1675	250	8	compound	compound	NOUN
eurjchem-1675	250	9	10	10	NUM
eurjchem-1675	250	10	is	be	AUX
eurjchem-1675	250	11	given	give	VERB
eurjchem-1675	250	12	in	in	ADP
eurjchem-1675	250	13	scheme	scheme	NOUN
eurjchem-1675	250	14	2	2	NUM
eurjchem-1675	250	15	.	.	PUNCT
eurjchem-1675	250	16	underneath	underneath	ADP
eurjchem-1675	250	17	microwave	microwave	NOUN
eurjchem-1675	250	18	irradiation	irradiation	NOUN
eurjchem-1675	250	19	,	,	PUNCT
eurjchem-1675	250	20	compound	compound	NOUN
eurjchem-1675	250	21	10	10	NUM
eurjchem-1675	250	22	responds	respond	NOUN
eurjchem-1675	250	23	with	with	ADP
eurjchem-1675	250	24	bromo-1	bromo-1	NOUN
eurjchem-1675	250	25	-	-	PUNCT
eurjchem-1675	250	26	phenylethanone	phenylethanone	NOUN
eurjchem-1675	250	27	derivatives	derivative	NOUN
eurjchem-1675	250	28	11a	11a	NOUN
eurjchem-1675	250	29	,	,	PUNCT
eurjchem-1675	250	30	b	b	NOUN
eurjchem-1675	250	31	in	in	ADP
eurjchem-1675	250	32	refluxing	refluxing	NOUN
eurjchem-1675	250	33	ethanol	ethanol	NOUN
eurjchem-1675	250	34	and	and	CCONJ
eurjchem-1675	250	35	in	in	ADP
eurjchem-1675	250	36	the	the	DET
eurjchem-1675	250	37	occurrence	occurrence	NOUN
eurjchem-1675	250	38	of	of	ADP
eurjchem-1675	250	39	catalytic	catalytic	ADJ
eurjchem-1675	250	40	amount	amount	NOUN
eurjchem-1675	250	41	of	of	ADP
eurjchem-1675	250	42	triethylamine	triethylamine	NOUN
eurjchem-1675	250	43	,	,	PUNCT
eurjchem-1675	250	44	to	to	PART
eurjchem-1675	250	45	give	give	VERB
eurjchem-1675	250	46	the	the	DET
eurjchem-1675	250	47	corresponding	correspond	VERB
eurjchem-1675	250	48	thiophene	thiophene	NOUN
eurjchem-1675	250	49	derivatives	derivative	NOUN
eurjchem-1675	250	50	13a	13a	NOUN
eurjchem-1675	250	51	and	and	CCONJ
eurjchem-1675	250	52	13b	13b	NOUN
eurjchem-1675	250	53	(	(	PUNCT
eurjchem-1675	250	54	scheme	scheme	NOUN
eurjchem-1675	250	55	2	2	NUM
eurjchem-1675	250	56	)	)	PUNCT
eurjchem-1675	250	57	.	.	PUNCT
eurjchem-1675	251	1	the	the	DET
eurjchem-1675	251	2	1h	1h	NUM
eurjchem-1675	251	3	nmr	nmr	NOUN
eurjchem-1675	251	4	spectrum	spectrum	NOUN
eurjchem-1675	251	5	of	of	ADP
eurjchem-1675	251	6	compound	compound	NOUN
eurjchem-1675	251	7	13a	13a	NOUN
eurjchem-1675	251	8	exposed	expose	VERB
eurjchem-1675	251	9	a	a	DET
eurjchem-1675	251	10	broad	broad	NOUN
eurjchem-1675	251	11	at	at	ADP
eurjchem-1675	251	12	δ	δ	PROPN
eurjchem-1675	251	13	9.51	9.51	NUM
eurjchem-1675	251	14	ppm	ppm	NOUN
eurjchem-1675	251	15	d2o	d2o	NOUN
eurjchem-1675	251	16	-	-	ADJ
eurjchem-1675	251	17	exchangeable	exchangeable	ADJ
eurjchem-1675	251	18	signal	signal	NOUN
eurjchem-1675	251	19	owing	owe	VERB
eurjchem-1675	251	20	to	to	PART
eurjchem-1675	251	21	amide	amide	VERB
eurjchem-1675	251	22	nh	nh	PROPN
eurjchem-1675	251	23	proton	proton	NOUN
eurjchem-1675	251	24	,	,	PUNCT
eurjchem-1675	251	25	furthermore	furthermore	ADV
eurjchem-1675	251	26	,	,	PUNCT
eurjchem-1675	251	27	multiple	multiple	ADJ
eurjchem-1675	251	28	at	at	ADP
eurjchem-1675	251	29	δ	δ	PROPN
eurjchem-1675	251	30	6.46	6.46	NUM
eurjchem-1675	251	31	-	-	SYM
eurjchem-1675	251	32	7.01	7.01	NUM
eurjchem-1675	251	33	ppm	ppm	NOUN
eurjchem-1675	251	34	due	due	ADJ
eurjchem-1675	251	35	to	to	ADP
eurjchem-1675	251	36	aromatic	aromatic	ADJ
eurjchem-1675	251	37	protons	proton	NOUN
eurjchem-1675	251	38	.	.	PUNCT
eurjchem-1675	252	1	its	its	PRON
eurjchem-1675	252	2	mass	mass	NOUN
eurjchem-1675	252	3	spectrum	spectrum	NOUN
eurjchem-1675	252	4	demonstrated	demonstrate	VERB
eurjchem-1675	252	5	a	a	DET
eurjchem-1675	252	6	molecular	molecular	ADJ
eurjchem-1675	252	7	ion	ion	NOUN
eurjchem-1675	252	8	peak	peak	NOUN
eurjchem-1675	252	9	at	at	ADP
eurjchem-1675	252	10	m	m	PROPN
eurjchem-1675	252	11	/	/	SYM
eurjchem-1675	252	12	z	z	PROPN
eurjchem-1675	252	13	419	419	NUM
eurjchem-1675	252	14	.	.	PUNCT
eurjchem-1675	253	1	the	the	DET
eurjchem-1675	253	2	1h	1h	NUM
eurjchem-1675	253	3	nmr	nmr	NOUN
eurjchem-1675	253	4	spectrum	spectrum	NOUN
eurjchem-1675	253	5	of	of	ADP
eurjchem-1675	253	6	compound	compound	NOUN
eurjchem-1675	253	7	13b	13b	X
eurjchem-1675	253	8	exposed	expose	VERB
eurjchem-1675	253	9	a	a	DET
eurjchem-1675	253	10	broad	broad	ADJ
eurjchem-1675	253	11	signal	signal	NOUN
eurjchem-1675	253	12	at	at	ADP
eurjchem-1675	253	13	δ	δ	PROPN
eurjchem-1675	253	14	9.76	9.76	NUM
eurjchem-1675	253	15	ppm	ppm	NOUN
eurjchem-1675	253	16	(	(	PUNCT
eurjchem-1675	253	17	d2oexchangable	d2oexchangable	PROPN
eurjchem-1675	253	18	)	)	PUNCT
eurjchem-1675	253	19	due	due	ADP
eurjchem-1675	253	20	to	to	PART
eurjchem-1675	253	21	amide	amide	VERB
eurjchem-1675	253	22	nh	nh	PROPN
eurjchem-1675	253	23	proton	proton	NOUN
eurjchem-1675	253	24	,	,	PUNCT
eurjchem-1675	253	25	in	in	ADP
eurjchem-1675	253	26	totaling	total	VERB
eurjchem-1675	253	27	to	to	ADP
eurjchem-1675	253	28	a	a	DET
eurjchem-1675	253	29	multiplet	multiplet	NOUN
eurjchem-1675	253	30	signal	signal	NOUN
eurjchem-1675	253	31	at	at	ADP
eurjchem-1675	253	32	δ	δ	PROPN
eurjchem-1675	253	33	7.05	7.05	NUM
eurjchem-1675	253	34	-	-	SYM
eurjchem-1675	253	35	7.38	7.38	NUM
eurjchem-1675	253	36	ppm	ppm	NOUN
eurjchem-1675	253	37	due	due	ADJ
eurjchem-1675	253	38	to	to	ADP
eurjchem-1675	253	39	aromatic	aromatic	ADJ
eurjchem-1675	253	40	protons	proton	NOUN
eurjchem-1675	253	41	.	.	PUNCT
eurjchem-1675	254	1	its	its	PRON
eurjchem-1675	254	2	mass	mass	NOUN
eurjchem-1675	254	3	spectrum	spectrum	NOUN
eurjchem-1675	254	4	demonstrated	demonstrate	VERB
eurjchem-1675	254	5	a	a	DET
eurjchem-1675	254	6	molecular	molecular	ADJ
eurjchem-1675	254	7	ion	ion	NOUN
eurjchem-1675	254	8	peak	peak	NOUN
eurjchem-1675	254	9	at	at	ADP
eurjchem-1675	254	10	m	m	PROPN
eurjchem-1675	254	11	/	/	SYM
eurjchem-1675	254	12	z	z	PROPN
eurjchem-1675	254	13	497	497	NUM
eurjchem-1675	254	14	.	.	PUNCT
eurjchem-1675	255	1	correspondingly	correspondingly	ADV
eurjchem-1675	255	2	,	,	PUNCT
eurjchem-1675	255	3	compound	compound	NOUN
eurjchem-1675	255	4	10	10	NUM
eurjchem-1675	255	5	responds	respond	NOUN
eurjchem-1675	255	6	with	with	ADP
eurjchem-1675	255	7	ethyl	ethyl	PROPN
eurjchem-1675	255	8	bromoacetate	bromoacetate	NOUN
eurjchem-1675	255	9	(	(	PUNCT
eurjchem-1675	255	10	14	14	NUM
eurjchem-1675	255	11	)	)	PUNCT
eurjchem-1675	255	12	underneath	underneath	ADP
eurjchem-1675	255	13	forced	force	VERB
eurjchem-1675	255	14	microwave	microwave	NOUN
eurjchem-1675	255	15	irradiation	irradiation	NOUN
eurjchem-1675	255	16	to	to	PART
eurjchem-1675	255	17	give	give	VERB
eurjchem-1675	255	18	a	a	DET
eurjchem-1675	255	19	single	single	ADJ
eurjchem-1675	255	20	product	product	NOUN
eurjchem-1675	255	21	identified	identify	VERB
eurjchem-1675	255	22	as	as	ADP
eurjchem-1675	255	23	ethyl	ethyl	PROPN
eurjchem-1675	255	24	4-(cyclohexylcarbamoyl)-3	4-(cyclohexylcarbamoyl)-3	PROPN
eurjchem-1675	255	25	-	-	PUNCT
eurjchem-1675	255	26	amino-5-(phenylamino)thiophene-2	amino-5-(phenylamino)thiophene-2	PROPN
eurjchem-1675	255	27	-	-	NOUN
eurjchem-1675	255	28	carboxylate	carboxylate	NOUN
eurjchem-1675	255	29	(	(	PUNCT
eurjchem-1675	255	30	16	16	NUM
eurjchem-1675	255	31	)	)	PUNCT
eurjchem-1675	255	32	(	(	PUNCT
eurjchem-1675	255	33	scheme	scheme	NOUN
eurjchem-1675	255	34	2	2	NUM
eurjchem-1675	255	35	)	)	PUNCT
eurjchem-1675	255	36	.	.	PUNCT
eurjchem-1675	256	1	the	the	DET
eurjchem-1675	256	2	previous	previous	ADJ
eurjchem-1675	256	3	product	product	NOUN
eurjchem-1675	256	4	was	be	AUX
eurjchem-1675	256	5	apportioned	apportion	VERB
eurjchem-1675	256	6	on	on	ADP
eurjchem-1675	256	7	the	the	DET
eurjchem-1675	256	8	basis	basis	NOUN
eurjchem-1675	256	9	of	of	ADP
eurjchem-1675	256	10	its	its	PRON
eurjchem-1675	256	11	elemental	elemental	ADJ
eurjchem-1675	256	12	analysis	analysis	NOUN
eurjchem-1675	256	13	and	and	CCONJ
eurjchem-1675	256	14	spectral	spectral	ADJ
eurjchem-1675	256	15	data	datum	NOUN
eurjchem-1675	256	16	.	.	PUNCT
eurjchem-1675	257	1	such	such	ADJ
eurjchem-1675	257	2	as	as	SCONJ
eurjchem-1675	257	3	,	,	PUNCT
eurjchem-1675	257	4	its	its	PRON
eurjchem-1675	257	5	1h	1h	NUM
eurjchem-1675	257	6	nmr	nmr	NOUN
eurjchem-1675	257	7	spectrum	spectrum	NOUN
eurjchem-1675	257	8	revealed	reveal	VERB
eurjchem-1675	257	9	signal	signal	NOUN
eurjchem-1675	257	10	at	at	ADP
eurjchem-1675	257	11	δ	δ	PROPN
eurjchem-1675	257	12	1.43	1.43	NUM
eurjchem-1675	257	13	-	-	SYM
eurjchem-1675	257	14	1.65	1.65	NUM
eurjchem-1675	257	15	ppmdue	ppmdue	ADJ
eurjchem-1675	257	16	to	to	ADP
eurjchem-1675	257	17	methyl	methyl	NOUN
eurjchem-1675	257	18	protons	proton	NOUN
eurjchem-1675	257	19	,	,	PUNCT
eurjchem-1675	257	20	δ	δ	PROPN
eurjchem-1675	257	21	4.183	4.183	NUM
eurjchem-1675	257	22	ppm	ppm	ADJ
eurjchem-1675	257	23	due	due	ADJ
eurjchem-1675	257	24	methylene	methylene	NOUN
eurjchem-1675	257	25	protons	proton	NOUN
eurjchem-1675	257	26	,	,	PUNCT
eurjchem-1675	257	27	in	in	ADP
eurjchem-1675	257	28	addition	addition	NOUN
eurjchem-1675	257	29	to	to	ADP
eurjchem-1675	257	30	a	a	DET
eurjchem-1675	257	31	d2o	d2o	NOUN
eurjchem-1675	257	32	-	-	ADJ
eurjchem-1675	257	33	exchangable	exchangable	ADJ
eurjchem-1675	257	34	signal	signal	NOUN
eurjchem-1675	257	35	at	at	ADP
eurjchem-1675	257	36	δ	δ	PROPN
eurjchem-1675	257	37	6.61	6.61	NUM
eurjchem-1675	257	38	ppm	ppm	NOUN
eurjchem-1675	257	39	owing	owe	VERB
eurjchem-1675	257	40	to	to	ADP
eurjchem-1675	257	41	nh2	nh2	PROPN
eurjchem-1675	257	42	protons	proton	NOUN
eurjchem-1675	257	43	,	,	PUNCT
eurjchem-1675	257	44	a	a	DET
eurjchem-1675	257	45	broad	broad	ADJ
eurjchem-1675	257	46	signal	signal	NOUN
eurjchem-1675	257	47	at	at	ADP
eurjchem-1675	257	48	δ	δ	PROPN
eurjchem-1675	257	49	9.66	9.66	NUM
eurjchem-1675	257	50	ppm	ppm	NOUN
eurjchem-1675	257	51	(	(	PUNCT
eurjchem-1675	257	52	d2o	d2o	NOUN
eurjchem-1675	257	53	-	-	ADJ
eurjchem-1675	257	54	exchangable	exchangable	ADJ
eurjchem-1675	257	55	)	)	PUNCT
eurjchem-1675	257	56	due	due	ADP
eurjchem-1675	257	57	to	to	ADP
eurjchem-1675	257	58	nh	nh	NOUN
eurjchem-1675	257	59	protons	proton	NOUN
eurjchem-1675	257	60	and	and	CCONJ
eurjchem-1675	257	61	a	a	DET
eurjchem-1675	257	62	multiplet	multiplet	NOUN
eurjchem-1675	257	63	at	at	ADP
eurjchem-1675	257	64	δ	δ	PROPN
eurjchem-1675	257	65	7.02	7.02	NUM
eurjchem-1675	257	66	-	-	SYM
eurjchem-1675	257	67	7.21	7.21	NUM
eurjchem-1675	257	68	ppm	ppm	NOUN
eurjchem-1675	257	69	owing	owe	VERB
eurjchem-1675	257	70	to	to	ADP
eurjchem-1675	257	71	aromatic	aromatic	ADJ
eurjchem-1675	257	72	protons	proton	NOUN
eurjchem-1675	257	73	,	,	PUNCT
eurjchem-1675	257	74	respectively	respectively	ADV
eurjchem-1675	257	75	,	,	PUNCT
eurjchem-1675	257	76	additionally	additionally	ADV
eurjchem-1675	257	77	,	,	PUNCT
eurjchem-1675	257	78	its	its	PRON
eurjchem-1675	257	79	mass	mass	NOUN
eurjchem-1675	257	80	spectrum	spectrum	NOUN
eurjchem-1675	257	81	revealed	reveal	VERB
eurjchem-1675	257	82	a	a	DET
eurjchem-1675	257	83	peak	peak	NOUN
eurjchem-1675	257	84	at	at	ADP
eurjchem-1675	257	85	m	m	PROPN
eurjchem-1675	257	86	/	/	SYM
eurjchem-1675	257	87	z	z	PROPN
eurjchem-1675	257	88	387	387	NUM
eurjchem-1675	257	89	corresponding	correspond	VERB
eurjchem-1675	257	90	to	to	ADP
eurjchem-1675	257	91	its	its	PRON
eurjchem-1675	257	92	molecular	molecular	ADJ
eurjchem-1675	257	93	ion	ion	NOUN
eurjchem-1675	257	94	.	.	PUNCT
eurjchem-1675	258	1	in	in	ADP
eurjchem-1675	258	2	a	a	DET
eurjchem-1675	258	3	comparable	comparable	ADJ
eurjchem-1675	258	4	technique	technique	NOUN
eurjchem-1675	258	5	,	,	PUNCT
eurjchem-1675	258	6	compound	compound	NOUN
eurjchem-1675	258	7	10	10	NUM
eurjchem-1675	258	8	responds	respond	NOUN
eurjchem-1675	258	9	with	with	ADP
eurjchem-1675	258	10	chloroacetonitrile	chloroacetonitrile	NOUN
eurjchem-1675	258	11	(	(	PUNCT
eurjchem-1675	258	12	17	17	NUM
eurjchem-1675	258	13	)	)	PUNCT
eurjchem-1675	258	14	to	to	PART
eurjchem-1675	258	15	donate	donate	VERB
eurjchem-1675	258	16	the	the	DET
eurjchem-1675	258	17	corresponding	correspond	VERB
eurjchem-1675	258	18	4	4	NUM
eurjchem-1675	258	19	-	-	PUNCT
eurjchem-1675	258	20	amino5	amino5	NOUN
eurjchem-1675	258	21	-	-	PUNCT
eurjchem-1675	258	22	cyano	cyano	NOUN
eurjchem-1675	258	23	-	-	PUNCT
eurjchem-1675	258	24	n	n	CCONJ
eurjchem-1675	258	25	-	-	PUNCT
eurjchem-1675	258	26	cyclohexyl-2-(phenylamino)thiophene-3carboxamide	cyclohexyl-2-(phenylamino)thiophene-3carboxamide	NOUN
eurjchem-1675	258	27	(	(	PUNCT
eurjchem-1675	258	28	18	18	NUM
eurjchem-1675	258	29	)	)	PUNCT
eurjchem-1675	258	30	(	(	PUNCT
eurjchem-1675	258	31	scheme	scheme	NOUN
eurjchem-1675	258	32	3	3	NUM
eurjchem-1675	258	33	)	)	PUNCT
eurjchem-1675	258	34	.	.	PUNCT
eurjchem-1675	259	1	the	the	DET
eurjchem-1675	259	2	ir	ir	PROPN
eurjchem-1675	259	3	spectrum	spectrum	NOUN
eurjchem-1675	259	4	of	of	ADP
eurjchem-1675	259	5	the	the	DET
eurjchem-1675	259	6	latter	latter	ADJ
eurjchem-1675	259	7	product	product	NOUN
eurjchem-1675	259	8	presented	present	VERB
eurjchem-1675	259	9	strong	strong	ADJ
eurjchem-1675	259	10	carbonyl	carbonyl	NOUN
eurjchem-1675	259	11	absorption	absorption	NOUN
eurjchem-1675	259	12	band	band	NOUN
eurjchem-1675	259	13	at	at	ADP
eurjchem-1675	259	14	1650	1650	NUM
eurjchem-1675	259	15	cm-1	cm-1	NOUN
eurjchem-1675	259	16	,	,	PUNCT
eurjchem-1675	259	17	nitrile	nitrile	ADJ
eurjchem-1675	259	18	band	band	NOUN
eurjchem-1675	259	19	at	at	ADP
eurjchem-1675	259	20	2250	2250	NUM
eurjchem-1675	259	21	cm-1	cm-1	NOUN
eurjchem-1675	259	22	and	and	CCONJ
eurjchem-1675	259	23	nh	nh	PROPN
eurjchem-1675	259	24	and	and	CCONJ
eurjchem-1675	259	25	nh2	nh2	PROPN
eurjchem-1675	259	26	band	band	NOUN
eurjchem-1675	259	27	at	at	ADP
eurjchem-1675	259	28	3428	3428	NUM
eurjchem-1675	259	29	and	and	CCONJ
eurjchem-1675	259	30	3250	3250	NUM
eurjchem-1675	259	31	cm-1	cm-1	NOUN
eurjchem-1675	259	32	,	,	PUNCT
eurjchem-1675	259	33	respectively	respectively	ADV
eurjchem-1675	259	34	.	.	PUNCT
eurjchem-1675	260	1	the	the	DET
eurjchem-1675	260	2	1h	1h	NUM
eurjchem-1675	260	3	nmr	nmr	NOUN
eurjchem-1675	260	4	spectrum	spectrum	NOUN
eurjchem-1675	260	5	of	of	ADP
eurjchem-1675	260	6	the	the	DET
eurjchem-1675	260	7	equivalent	equivalent	ADJ
eurjchem-1675	260	8	invention	invention	NOUN
eurjchem-1675	260	9	revealed	reveal	VERB
eurjchem-1675	260	10	a	a	DET
eurjchem-1675	260	11	single	single	ADJ
eurjchem-1675	260	12	signal	signal	NOUN
eurjchem-1675	260	13	exchangeable	exchangeable	ADJ
eurjchem-1675	260	14	δ	δ	PROPN
eurjchem-1675	260	15	6.60	6.60	NUM
eurjchem-1675	260	16	ppm	ppm	NOUN
eurjchem-1675	260	17	owing	owe	VERB
eurjchem-1675	260	18	to	to	ADP
eurjchem-1675	260	19	amino	amino	NOUN
eurjchem-1675	260	20	protons	proton	NOUN
eurjchem-1675	260	21	,	,	PUNCT
eurjchem-1675	260	22	a	a	DET
eurjchem-1675	260	23	broad	broad	ADJ
eurjchem-1675	260	24	d2o	d2o	NOUN
eurjchem-1675	260	25	-	-	ADJ
eurjchem-1675	260	26	exchangable	exchangable	ADJ
eurjchem-1675	260	27	signal	signal	NOUN
eurjchem-1675	260	28	at	at	ADP
eurjchem-1675	260	29	δ	δ	PROPN
eurjchem-1675	260	30	9.60	9.60	NUM
eurjchem-1675	260	31	ppm	ppm	NOUN
eurjchem-1675	260	32	due	due	ADP
eurjchem-1675	260	33	to	to	ADP
eurjchem-1675	260	34	nh	nh	PROPN
eurjchem-1675	260	35	proton	proton	NOUN
eurjchem-1675	260	36	and	and	CCONJ
eurjchem-1675	260	37	a	a	DET
eurjchem-1675	260	38	multiplet	multiplet	NOUN
eurjchem-1675	260	39	signal	signal	NOUN
eurjchem-1675	260	40	at	at	ADP
eurjchem-1675	260	41	δ	δ	PROPN
eurjchem-1675	260	42	7.02	7.02	NUM
eurjchem-1675	260	43	-	-	SYM
eurjchem-1675	260	44	7.21	7.21	NUM
eurjchem-1675	260	45	ppm	ppm	NOUN
eurjchem-1675	260	46	due	due	ADJ
eurjchem-1675	260	47	aromatic	aromatic	ADJ
eurjchem-1675	260	48	protons	proton	NOUN
eurjchem-1675	260	49	.	.	PUNCT
eurjchem-1675	261	1	its	its	PRON
eurjchem-1675	261	2	mass	mass	NOUN
eurjchem-1675	261	3	spectrum	spectrum	NOUN
eurjchem-1675	261	4	exposed	expose	VERB
eurjchem-1675	261	5	a	a	DET
eurjchem-1675	261	6	peak	peak	NOUN
eurjchem-1675	261	7	at	at	ADP
eurjchem-1675	261	8	m	m	PROPN
eurjchem-1675	261	9	/	/	SYM
eurjchem-1675	261	10	z	z	NOUN
eurjchem-1675	261	11	340	340	NUM
eurjchem-1675	261	12	corresponding	correspond	VERB
eurjchem-1675	261	13	to	to	ADP
eurjchem-1675	261	14	its	its	PRON
eurjchem-1675	261	15	molecular	molecular	ADJ
eurjchem-1675	261	16	ion	ion	NOUN
eurjchem-1675	261	17	.	.	PUNCT
eurjchem-1675	262	1	as	as	ADV
eurjchem-1675	262	2	soon	soon	ADV
eurjchem-1675	262	3	as	as	ADP
eurjchem-1675	262	4	2	2	NUM
eurjchem-1675	262	5	-	-	PUNCT
eurjchem-1675	262	6	cyano	cyano	NOUN
eurjchem-1675	262	7	-	-	PUNCT
eurjchem-1675	262	8	n	n	CCONJ
eurjchem-1675	262	9	-	-	PUNCT
eurjchem-1675	262	10	cyclohexyl-3	cyclohexyl-3	NOUN
eurjchem-1675	262	11	-	-	PUNCT
eurjchem-1675	262	12	mercapto-3-(phenylamino	mercapto-3-(phenylamino	NOUN
eurjchem-1675	262	13	)	)	PUNCT
eurjchem-1675	262	14	acrylamide	acrylamide	NOUN
eurjchem-1675	262	15	(	(	PUNCT
eurjchem-1675	262	16	10	10	NUM
eurjchem-1675	262	17	)	)	PUNCT
eurjchem-1675	262	18	was	be	AUX
eurjchem-1675	262	19	preserved	preserve	VERB
eurjchem-1675	262	20	with	with	ADP
eurjchem-1675	262	21	chloroacetone	chloroacetone	PROPN
eurjchem-1675	262	22	(	(	PUNCT
eurjchem-1675	262	23	19	19	NUM
eurjchem-1675	262	24	)	)	PUNCT
eurjchem-1675	262	25	,	,	PUNCT
eurjchem-1675	262	26	it	it	PRON
eurjchem-1675	262	27	gave	give	VERB
eurjchem-1675	262	28	2	2	NUM
eurjchem-1675	262	29	-	-	PUNCT
eurjchem-1675	262	30	cyano	cyano	NOUN
eurjchem-1675	262	31	-	-	PUNCT
eurjchem-1675	262	32	n	n	CCONJ
eurjchem-1675	262	33	-	-	PUNCT
eurjchem-1675	262	34	cyclohexyl-2-(4	cyclohexyl-2-(4	VERB
eurjchem-1675	262	35	-	-	PUNCT
eurjchem-1675	262	36	methyl-3	methyl-3	NUM
eurjchem-1675	262	37	-	-	PUNCT
eurjchem-1675	262	38	phenylthiazol-2(3h)-ylidene)acetamide	phenylthiazol-2(3h)-ylidene)acetamide	NOUN
eurjchem-1675	262	39	(	(	PUNCT
eurjchem-1675	262	40	21	21	NUM
eurjchem-1675	262	41	)	)	PUNCT
eurjchem-1675	262	42	(	(	PUNCT
eurjchem-1675	262	43	scheme	scheme	NOUN
eurjchem-1675	262	44	3	3	NUM
eurjchem-1675	262	45	)	)	PUNCT
eurjchem-1675	262	46	.	.	PUNCT
eurjchem-1675	263	1	the	the	DET
eurjchem-1675	263	2	mass	mass	PROPN
eurjchem-1675	263	3	spectrum	spectrum	NOUN
eurjchem-1675	263	4	of	of	ADP
eurjchem-1675	263	5	the	the	DET
eurjchem-1675	263	6	previous	previous	ADJ
eurjchem-1675	263	7	product	product	NOUN
eurjchem-1675	263	8	revealed	reveal	VERB
eurjchem-1675	263	9	a	a	DET
eurjchem-1675	263	10	peak	peak	NOUN
eurjchem-1675	263	11	at	at	ADP
eurjchem-1675	263	12	m	m	PROPN
eurjchem-1675	263	13	/	/	SYM
eurjchem-1675	263	14	z	z	NOUN
eurjchem-1675	263	15	339	339	NUM
eurjchem-1675	263	16	consistent	consistent	ADJ
eurjchem-1675	263	17	to	to	ADP
eurjchem-1675	263	18	its	its	PRON
eurjchem-1675	263	19	molecular	molecular	ADJ
eurjchem-1675	263	20	ion	ion	NOUN
eurjchem-1675	263	21	.	.	PUNCT
eurjchem-1675	264	1	its	its	PRON
eurjchem-1675	264	2	ir	ir	PROPN
eurjchem-1675	264	3	spectrum	spectrum	NOUN
eurjchem-1675	264	4	demonstrated	demonstrate	VERB
eurjchem-1675	264	5	absorption	absorption	NOUN
eurjchem-1675	264	6	bands	band	NOUN
eurjchem-1675	264	7	at	at	ADP
eurjchem-1675	264	8	3419	3419	NUM
eurjchem-1675	264	9	,	,	PUNCT
eurjchem-1675	264	10	2163	2163	NUM
eurjchem-1675	264	11	and	and	CCONJ
eurjchem-1675	264	12	1616	1616	NUM
eurjchem-1675	264	13	cm-1	cm-1	VERB
eurjchem-1675	264	14	owing	owe	VERB
eurjchem-1675	264	15	to	to	ADP
eurjchem-1675	264	16	nh	nh	PROPN
eurjchem-1675	264	17	,	,	PUNCT
eurjchem-1675	264	18	nitrile	nitrile	ADJ
eurjchem-1675	264	19	and	and	CCONJ
eurjchem-1675	264	20	carbonyl	carbonyl	NOUN
eurjchem-1675	264	21	group	group	NOUN
eurjchem-1675	264	22	,	,	PUNCT
eurjchem-1675	264	23	respectively	respectively	ADV
eurjchem-1675	264	24	.	.	PUNCT
eurjchem-1675	265	1	the	the	DET
eurjchem-1675	265	2	1h	1h	NUM
eurjchem-1675	265	3	nmr	nmr	NOUN
eurjchem-1675	265	4	spectrum	spectrum	NOUN
eurjchem-1675	265	5	of	of	ADP
eurjchem-1675	265	6	the	the	DET
eurjchem-1675	265	7	matching	match	VERB
eurjchem-1675	265	8	products	product	NOUN
eurjchem-1675	265	9	exposed	expose	VERB
eurjchem-1675	265	10	a	a	DET
eurjchem-1675	265	11	singlet	singlet	ADJ
eurjchem-1675	265	12	signal	signal	NOUN
eurjchem-1675	265	13	at	at	ADP
eurjchem-1675	265	14	δ	δ	PROPN
eurjchem-1675	265	15	1.031.09	1.031.09	NUM
eurjchem-1675	265	16	ppm	ppm	NOUN
eurjchem-1675	265	17	owing	owe	VERB
eurjchem-1675	265	18	to	to	ADP
eurjchem-1675	265	19	aliphatic	aliphatic	ADJ
eurjchem-1675	265	20	protons	proton	NOUN
eurjchem-1675	265	21	δ	δ	PROPN
eurjchem-1675	265	22	2.08	2.08	NUM
eurjchem-1675	265	23	ppm	ppm	NOUN
eurjchem-1675	265	24	due	due	ADP
eurjchem-1675	265	25	to	to	ADP
eurjchem-1675	265	26	methyl	methyl	NOUN
eurjchem-1675	265	27	protons	proton	NOUN
eurjchem-1675	265	28	,	,	PUNCT
eurjchem-1675	265	29	additionally	additionally	ADV
eurjchem-1675	265	30	to	to	ADP
eurjchem-1675	265	31	broad	broad	ADJ
eurjchem-1675	265	32	band	band	NOUN
eurjchem-1675	265	33	d2o	d2o	NOUN
eurjchem-1675	265	34	-	-	NOUN
eurjchem-1675	265	35	exchangable	exchangable	ADJ
eurjchem-1675	265	36	at	at	ADP
eurjchem-1675	265	37	δ	δ	PROPN
eurjchem-1675	265	38	7.801	7.801	NUM
eurjchem-1675	265	39	ppm	ppm	NOUN
eurjchem-1675	265	40	due	due	ADP
eurjchem-1675	265	41	to	to	ADP
eurjchem-1675	265	42	nh	nh	NOUN
eurjchem-1675	265	43	protons	proton	NOUN
eurjchem-1675	265	44	and	and	CCONJ
eurjchem-1675	265	45	a	a	DET
eurjchem-1675	265	46	multiplet	multiplet	NOUN
eurjchem-1675	265	47	at	at	ADP
eurjchem-1675	265	48	δ	δ	PROPN
eurjchem-1675	265	49	7.41	7.41	NUM
eurjchem-1675	265	50	-	-	SYM
eurjchem-1675	265	51	7.51	7.51	NUM
eurjchem-1675	265	52	ppm	ppm	NOUN
eurjchem-1675	265	53	owing	owe	VERB
eurjchem-1675	265	54	aromatic	aromatic	ADJ
eurjchem-1675	265	55	protons	proton	NOUN
eurjchem-1675	265	56	.	.	PUNCT
eurjchem-1675	266	1	in	in	ADP
eurjchem-1675	266	2	a	a	DET
eurjchem-1675	266	3	comparable	comparable	ADJ
eurjchem-1675	266	4	way	way	NOUN
eurjchem-1675	266	5	,	,	PUNCT
eurjchem-1675	266	6	reaction	reaction	NOUN
eurjchem-1675	266	7	of	of	ADP
eurjchem-1675	266	8	the	the	DET
eurjchem-1675	266	9	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1675	266	10	chloride	chloride	PROPN
eurjchem-1675	266	11	22a	22a	NOUN
eurjchem-1675	266	12	-	-	PUNCT
eurjchem-1675	266	13	e	e	NOUN
eurjchem-1675	266	14	with	with	ADP
eurjchem-1675	266	15	the	the	DET
eurjchem-1675	266	16	intermediate	intermediate	ADJ
eurjchem-1675	266	17	potassium	potassium	NOUN
eurjchem-1675	266	18	salt	salt	NOUN
eurjchem-1675	266	19	9	9	NUM
eurjchem-1675	266	20	further	far	ADV
eurjchem-1675	266	21	down	down	ADP
eurjchem-1675	266	22	the	the	DET
eurjchem-1675	266	23	equivalent	equivalent	ADJ
eurjchem-1675	266	24	reaction	reaction	NOUN
eurjchem-1675	266	25	condition	condition	NOUN
eurjchem-1675	266	26	furnished	furnish	VERB
eurjchem-1675	266	27	the	the	DET
eurjchem-1675	266	28	afforded	afford	VERB
eurjchem-1675	266	29	only	only	ADV
eurjchem-1675	266	30	one	one	NUM
eurjchem-1675	266	31	isolable	isolable	ADJ
eurjchem-1675	266	32	product	product	NOUN
eurjchem-1675	266	33	(	(	PUNCT
eurjchem-1675	266	34	as	as	SCONJ
eurjchem-1675	266	35	detected	detect	VERB
eurjchem-1675	266	36	by	by	ADP
eurjchem-1675	266	37	thin	thin	ADJ
eurjchem-1675	266	38	layer	layer	NOUN
eurjchem-1675	266	39	chromotogrpahy	chromotogrpahy	NOUN
eurjchem-1675	266	40	)	)	PUNCT
eurjchem-1675	266	41	1,3,4	1,3,4	NUM
eurjchem-1675	266	42	-	-	PUNCT
eurjchem-1675	266	43	thiadiazole	thiadiazole	NOUN
eurjchem-1675	266	44	derivatives	derivative	NOUN
eurjchem-1675	266	45	(	(	PUNCT
eurjchem-1675	266	46	24a	24a	NOUN
eurjchem-1675	266	47	-	-	SYM
eurjchem-1675	266	48	e	e	NOUN
eurjchem-1675	266	49	)	)	PUNCT
eurjchem-1675	266	50	and	and	CCONJ
eurjchem-1675	266	51	the	the	DET
eurjchem-1675	266	52	further	further	ADJ
eurjchem-1675	266	53	structures	structure	NOUN
eurjchem-1675	266	54	25	25	NUM
eurjchem-1675	266	55	and	and	CCONJ
eurjchem-1675	266	56	26	26	NUM
eurjchem-1675	266	57	were	be	AUX
eurjchem-1675	266	58	excluded	exclude	VERB
eurjchem-1675	266	59	based	base	VERB
eurjchem-1675	266	60	on	on	ADP
eurjchem-1675	266	61	the	the	DET
eurjchem-1675	266	62	elemental	elemental	ADJ
eurjchem-1675	266	63	and	and	CCONJ
eurjchem-1675	266	64	spectroscopic	spectroscopic	ADJ
eurjchem-1675	266	65	data	datum	NOUN
eurjchem-1675	266	66	of	of	ADP
eurjchem-1675	266	67	the	the	DET
eurjchem-1675	266	68	reaction	reaction	NOUN
eurjchem-1675	266	69	product	product	NOUN
eurjchem-1675	266	70	(	(	PUNCT
eurjchem-1675	266	71	scheme	scheme	NOUN
eurjchem-1675	266	72	4	4	NUM
eurjchem-1675	266	73	)	)	PUNCT
eurjchem-1675	266	74	.	.	PUNCT
eurjchem-1675	267	1	the	the	DET
eurjchem-1675	267	2	ir	ir	PROPN
eurjchem-1675	267	3	of	of	ADP
eurjchem-1675	267	4	compound	compound	NOUN
eurjchem-1675	267	5	24a	24a	NOUN
eurjchem-1675	267	6	displayed	display	VERB
eurjchem-1675	267	7	absorption	absorption	NOUN
eurjchem-1675	267	8	band	band	NOUN
eurjchem-1675	267	9	at	at	ADP
eurjchem-1675	267	10	3340	3340	NUM
eurjchem-1675	267	11	cm-1	cm-1	NOUN
eurjchem-1675	267	12	due	due	ADP
eurjchem-1675	267	13	to	to	ADP
eurjchem-1675	267	14	nh	nh	PROPN
eurjchem-1675	267	15	band	band	NOUN
eurjchem-1675	267	16	,	,	PUNCT
eurjchem-1675	267	17	2190	2190	NUM
eurjchem-1675	267	18	cm-1	cm-1	VERB
eurjchem-1675	267	19	due	due	ADP
eurjchem-1675	267	20	to	to	ADP
eurjchem-1675	267	21	nitrile	nitrile	ADJ
eurjchem-1675	267	22	band	band	NOUN
eurjchem-1675	267	23	and	and	CCONJ
eurjchem-1675	267	24	strong	strong	ADJ
eurjchem-1675	267	25	carbonyl	carbonyl	NOUN
eurjchem-1675	267	26	band	band	NOUN
eurjchem-1675	267	27	at	at	ADP
eurjchem-1675	267	28	1619	1619	NUM
eurjchem-1675	267	29	cm-1	cm-1	NOUN
eurjchem-1675	267	30	,	,	PUNCT
eurjchem-1675	267	31	also	also	ADV
eurjchem-1675	267	32	its	its	PRON
eurjchem-1675	267	33	1h	1h	NUM
eurjchem-1675	267	34	nmr	nmr	NOUN
eurjchem-1675	267	35	spectrum	spectrum	NOUN
eurjchem-1675	267	36	revealed	reveal	VERB
eurjchem-1675	267	37	a	a	DET
eurjchem-1675	267	38	signal	signal	NOUN
eurjchem-1675	267	39	at	at	ADP
eurjchem-1675	267	40	δ	δ	PROPN
eurjchem-1675	267	41	1.79	1.79	NUM
eurjchem-1675	267	42	ppm	ppm	NOUN
eurjchem-1675	267	43	owing	owe	VERB
eurjchem-1675	267	44	to	to	ADP
eurjchem-1675	267	45	ch3	ch3	PROPN
eurjchem-1675	267	46	protons	proton	NOUN
eurjchem-1675	267	47	,	,	PUNCT
eurjchem-1675	267	48	δ	δ	PROPN
eurjchem-1675	267	49	4.20	4.20	NUM
eurjchem-1675	267	50	ppm	ppm	NOUN
eurjchem-1675	267	51	due	due	ADP
eurjchem-1675	267	52	to	to	ADP
eurjchem-1675	267	53	ch2	ch2	NOUN
eurjchem-1675	267	54	protons	proton	NOUN
eurjchem-1675	267	55	,	,	PUNCT
eurjchem-1675	267	56	in	in	ADP
eurjchem-1675	267	57	addition	addition	NOUN
eurjchem-1675	267	58	to	to	ADP
eurjchem-1675	267	59	multiplet	multiplet	NOUN
eurjchem-1675	267	60	singles	single	NOUN
eurjchem-1675	267	61	at	at	ADP
eurjchem-1675	267	62	δ	δ	PROPN
eurjchem-1675	267	63	6.40	6.40	NUM
eurjchem-1675	267	64	-	-	SYM
eurjchem-1675	267	65	7.21	7.21	NUM
eurjchem-1675	267	66	ppm	ppm	NOUN
eurjchem-1675	267	67	ppm	ppm	NOUN
eurjchem-1675	267	68	owing	owe	VERB
eurjchem-1675	267	69	to	to	ADP
eurjchem-1675	267	70	aromatic	aromatic	ADJ
eurjchem-1675	267	71	protons	proton	NOUN
eurjchem-1675	267	72	.	.	PUNCT
eurjchem-1675	268	1	its	its	PRON
eurjchem-1675	268	2	mass	mass	NOUN
eurjchem-1675	268	3	spectrum	spectrum	NOUN
eurjchem-1675	268	4	revealed	reveal	VERB
eurjchem-1675	268	5	a	a	DET
eurjchem-1675	268	6	peak	peak	NOUN
eurjchem-1675	268	7	at	at	ADP
eurjchem-1675	268	8	m	m	PROPN
eurjchem-1675	268	9	/	/	SYM
eurjchem-1675	268	10	z	z	PROPN
eurjchem-1675	268	11	432	432	NUM
eurjchem-1675	268	12	corresponding	correspond	VERB
eurjchem-1675	268	13	to	to	ADP
eurjchem-1675	268	14	its	its	PRON
eurjchem-1675	268	15	molecular	molecular	ADJ
eurjchem-1675	268	16	ion	ion	NOUN
eurjchem-1675	268	17	.	.	PUNCT
eurjchem-1675	269	1	the	the	DET
eurjchem-1675	269	2	extra	extra	ADJ
eurjchem-1675	269	3	probable	probable	ADJ
eurjchem-1675	269	4	structure	structure	NOUN
eurjchem-1675	269	5	24a	24a	NOUN
eurjchem-1675	269	6	was	be	AUX
eurjchem-1675	269	7	excluded	exclude	VERB
eurjchem-1675	269	8	on	on	ADP
eurjchem-1675	269	9	the	the	DET
eurjchem-1675	269	10	basis	basis	NOUN
eurjchem-1675	269	11	of	of	ADP
eurjchem-1675	269	12	both	both	CCONJ
eurjchem-1675	269	13	analytical	analytical	ADJ
eurjchem-1675	269	14	and	and	CCONJ
eurjchem-1675	269	15	spectral	spectral	ADJ
eurjchem-1675	269	16	data	datum	NOUN
eurjchem-1675	269	17	.	.	PUNCT
eurjchem-1675	270	1	3.2	3.2	NUM
eurjchem-1675	270	2	.	.	X
eurjchem-1675	271	1	molecular	molecular	ADJ
eurjchem-1675	271	2	orbital	orbital	ADJ
eurjchem-1675	271	3	calculations	calculation	NOUN
eurjchem-1675	271	4	optimization	optimization	NOUN
eurjchem-1675	271	5	geometry	geometry	NOUN
eurjchem-1675	271	6	of	of	ADP
eurjchem-1675	271	7	compounds	compound	NOUN
eurjchem-1675	271	8	6	6	NUM
eurjchem-1675	271	9	and	and	CCONJ
eurjchem-1675	271	10	8	8	NUM
eurjchem-1675	271	11	advanced	advanced	ADJ
eurjchem-1675	271	12	at	at	ADP
eurjchem-1675	271	13	dft	dft	PROPN
eurjchem-1675	271	14	(	(	PUNCT
eurjchem-1675	271	15	b3lyp	b3lyp	NUM
eurjchem-1675	271	16	)	)	PUNCT
eurjchem-1675	271	17	and	and	CCONJ
eurjchem-1675	271	18	hf	hf	ADP
eurjchem-1675	271	19	hypothesis	hypothesis	NOUN
eurjchem-1675	271	20	utilizing	utilize	VERB
eurjchem-1675	271	21	the	the	DET
eurjchem-1675	271	22	gaussian	gaussian	NOUN
eurjchem-1675	271	23	09w	09w	NOUN
eurjchem-1675	271	24	program	program	NOUN
eurjchem-1675	272	1	[	[	X
eurjchem-1675	272	2	30	30	NUM
eurjchem-1675	272	3	]	]	PUNCT
eurjchem-1675	272	4	,	,	PUNCT
eurjchem-1675	273	1	which	which	PRON
eurjchem-1675	273	2	describe	describe	VERB
eurjchem-1675	273	3	construction	construction	NOUN
eurjchem-1675	273	4	of	of	ADP
eurjchem-1675	273	5	pyrazole	pyrazole	NOUN
eurjchem-1675	273	6	ethyl	ethyl	PROPN
eurjchem-1675	273	7	4(cyclohexylcarbamoyl)-5	4(cyclohexylcarbamoyl)-5	NUM
eurjchem-1675	273	8	-	-	PUNCT
eurjchem-1675	273	9	amino-1-(4	amino-1-(4	NOUN
eurjchem-1675	273	10	-	-	PUNCT
eurjchem-1675	273	11	methoxyphenyl)-1hpyrazole-3	methoxyphenyl)-1hpyrazole-3	PROPN
eurjchem-1675	273	12	-	-	PUNCT
eurjchem-1675	273	13	carboxylate	carboxylate	NOUN
eurjchem-1675	273	14	(	(	PUNCT
eurjchem-1675	273	15	6	6	NUM
eurjchem-1675	273	16	)	)	PUNCT
eurjchem-1675	273	17	instead	instead	ADV
eurjchem-1675	273	18	of	of	ADP
eurjchem-1675	273	19	compound	compound	NOUN
eurjchem-1675	273	20	4	4	NUM
eurjchem-1675	273	21	-	-	PUNCT
eurjchem-1675	273	22	cyano	cyano	NOUN
eurjchem-1675	273	23	-	-	PUNCT
eurjchem-1675	273	24	ncyclohexyl-3	ncyclohexyl-3	NOUN
eurjchem-1675	273	25	-	-	PUNCT
eurjchem-1675	273	26	ethoxy-2	ethoxy-2	PROPN
eurjchem-1675	273	27	,	,	PUNCT
eurjchem-1675	273	28	3	3	NUM
eurjchem-1675	273	29	-	-	PUNCT
eurjchem-1675	273	30	dihydro-1-(4	dihydro-1-(4	VERB
eurjchem-1675	273	31	-	-	PUNCT
eurjchem-1675	273	32	methoxyphenyl)-1hpyrazole-5	methoxyphenyl)-1hpyrazole-5	NOUN
eurjchem-1675	273	33	-	-	PUNCT
eurjchem-1675	273	34	carboxamide	carboxamide	NOUN
eurjchem-1675	273	35	(	(	PUNCT
eurjchem-1675	273	36	8)	8)	NUM
eurjchem-1675	273	37	.	.	PUNCT
eurjchem-1675	273	38	correspondingly	correspondingly	ADV
eurjchem-1675	273	39	theoretical	theoretical	ADJ
eurjchem-1675	273	40	calculation	calculation	NOUN
eurjchem-1675	273	41	exhausting	exhaust	VERB
eurjchem-1675	273	42	dft	dft	NOUN
eurjchem-1675	273	43	calculation	calculation	NOUN
eurjchem-1675	273	44	at	at	ADP
eurjchem-1675	273	45	the	the	DET
eurjchem-1675	273	46	b3lyp	b3lyp	NOUN
eurjchem-1675	273	47	level	level	NOUN
eurjchem-1675	273	48	of	of	ADP
eurjchem-1675	273	49	theory	theory	NOUN
eurjchem-1675	273	50	and	and	CCONJ
eurjchem-1675	273	51	6	6	NUM
eurjchem-1675	273	52	-	-	SYM
eurjchem-1675	273	53	31	31	NUM
eurjchem-1675	273	54	g	g	NOUN
eurjchem-1675	273	55	(	(	PUNCT
eurjchem-1675	273	56	d	d	NOUN
eurjchem-1675	273	57	)	)	PUNCT
eurjchem-1675	273	58	as	as	ADP
eurjchem-1675	273	59	a	a	DET
eurjchem-1675	273	60	basis	basis	NOUN
eurjchem-1675	273	61	set	set	NOUN
eurjchem-1675	273	62	as	as	SCONJ
eurjchem-1675	273	63	displayed	display	VERB
eurjchem-1675	273	64	in	in	ADP
eurjchem-1675	273	65	table	table	NOUN
eurjchem-1675	273	66	1	1	NUM
eurjchem-1675	273	67	.	.	SYM
eurjchem-1675	273	68	2018	2018	NUM
eurjchem-1675	273	69	–	–	PUNCT
eurjchem-1675	273	70	european	european	ADJ
eurjchem-1675	273	71	journal	journal	NOUN
eurjchem-1675	273	72	of	of	ADP
eurjchem-1675	273	73	chemistry	chemistry	NOUN
eurjchem-1675	273	74	–	–	PUNCT
eurjchem-1675	273	75	cc	cc	NOUN
eurjchem-1675	273	76	by	by	ADP
eurjchem-1675	273	77	nc	nc	PROPN
eurjchem-1675	273	78	–	–	PUNCT
eurjchem-1675	273	79	doi	doi	NOUN
eurjchem-1675	273	80	:	:	PUNCT
eurjchem-1675	273	81	10.5155	10.5155	NUM
eurjchem-1675	273	82	/	/	SYM
eurjchem-1675	273	83	eurjchem.9.1.30	eurjchem.9.1.30	NOUN
eurjchem-1675	273	84	-	-	SYM
eurjchem-1675	273	85	38.1675	38.1675	NUM
eurjchem-1675	273	86	36	36	NUM
eurjchem-1675	273	87	fahim	fahim	PROPN
eurjchem-1675	273	88	et	et	PROPN
eurjchem-1675	273	89	al	al	PROPN
eurjchem-1675	273	90	.	.	PUNCT
eurjchem-1675	273	91	/	/	SYM
eurjchem-1675	273	92	european	european	PROPN
eurjchem-1675	273	93	journal	journal	PROPN
eurjchem-1675	273	94	of	of	ADP
eurjchem-1675	273	95	chemistry	chemistry	NOUN
eurjchem-1675	273	96	9	9	NUM
eurjchem-1675	273	97	(	(	PUNCT
eurjchem-1675	273	98	1	1	NUM
eurjchem-1675	273	99	)	)	PUNCT
eurjchem-1675	273	100	(	(	PUNCT
eurjchem-1675	273	101	2018	2018	NUM
eurjchem-1675	273	102	)	)	PUNCT
eurjchem-1675	273	103	30	30	NUM
eurjchem-1675	273	104	-	-	SYM
eurjchem-1675	273	105	38	38	NUM
eurjchem-1675	273	106	table	table	NOUN
eurjchem-1675	273	107	1	1	NUM
eurjchem-1675	273	108	.	.	PUNCT
eurjchem-1675	273	109	energetics	energetic	NOUN
eurjchem-1675	273	110	of	of	ADP
eurjchem-1675	273	111	the	the	DET
eurjchem-1675	273	112	ground	ground	NOUN
eurjchem-1675	273	113	state	state	NOUN
eurjchem-1675	273	114	of	of	ADP
eurjchem-1675	273	115	compound	compound	NOUN
eurjchem-1675	273	116	6	6	NUM
eurjchem-1675	273	117	and	and	CCONJ
eurjchem-1675	273	118	8	8	NUM
eurjchem-1675	273	119	exhausting	exhausting	ADJ
eurjchem-1675	273	120	dft	dft	PROPN
eurjchem-1675	273	121	(	(	PUNCT
eurjchem-1675	273	122	b3lyp/6	b3lyp/6	PROPN
eurjchem-1675	273	123	-	-	NOUN
eurjchem-1675	273	124	31g(d	31g(d	NUM
eurjchem-1675	273	125	)	)	PUNCT
eurjchem-1675	273	126	)	)	PUNCT
eurjchem-1675	274	1	.	.	PUNCT
eurjchem-1675	275	1	parameters	parameter	NOUN
eurjchem-1675	275	2	compound	compound	VERB
eurjchem-1675	275	3	6	6	NUM
eurjchem-1675	275	4	compound	compound	NOUN
eurjchem-1675	275	5	8	8	NUM
eurjchem-1675	275	6	et	et	NOUN
eurjchem-1675	275	7	(	(	PUNCT
eurjchem-1675	275	8	au	au	PROPN
eurjchem-1675	275	9	)	)	PUNCT
eurjchem-1675	275	10	-1222.667	-1222.667	PUNCT
eurjchem-1675	275	11	-1221.1528	-1221.1528	PUNCT
eurjchem-1675	275	12	ehomo	ehomo	NOUN
eurjchem-1675	275	13	(	(	PUNCT
eurjchem-1675	275	14	au	au	PROPN
eurjchem-1675	275	15	)	)	PUNCT
eurjchem-1675	275	16	-0.21765	-0.21765	NOUN
eurjchem-1675	275	17	-0.20163	-0.20163	PROPN
eurjchem-1675	275	18	elomo	elomo	PROPN
eurjchem-1675	275	19	(	(	PUNCT
eurjchem-1675	275	20	au	au	PROPN
eurjchem-1675	275	21	)	)	PUNCT
eurjchem-1675	275	22	-0.12886	-0.12886	NOUN
eurjchem-1675	275	23	-0.17188	-0.17188	NOUN
eurjchem-1675	276	1	eg	eg	NOUN
eurjchem-1675	276	2	=	=	SYM
eurjchem-1675	276	3	elomo	elomo	ADJ
eurjchem-1675	276	4	ehomo	ehomo	NOUN
eurjchem-1675	276	5	(	(	PUNCT
eurjchem-1675	276	6	ev	ev	INTJ
eurjchem-1675	276	7	)	)	PUNCT
eurjchem-1675	276	8	2.4161001	2.4161001	NUM
eurjchem-1675	276	9	0.80953	0.80953	NUM
eurjchem-1675	276	10	µ	µ	X
eurjchem-1675	276	11	(	(	PUNCT
eurjchem-1675	276	12	d	d	NOUN
eurjchem-1675	276	13	)	)	PUNCT
eurjchem-1675	276	14	5.6949	5.6949	NUM
eurjchem-1675	276	15	6.5415	6.5415	NUM
eurjchem-1675	276	16	net	net	ADJ
eurjchem-1675	276	17	charges	charge	NOUN
eurjchem-1675	276	18	(	(	PUNCT
eurjchem-1675	276	19	au	au	ADJ
eurjchem-1675	276	20	)	)	PUNCT
eurjchem-1675	276	21	n30	n30	PROPN
eurjchem-1675	276	22	-0.250	-0.250	PROPN
eurjchem-1675	276	23	n37	n37	NOUN
eurjchem-1675	276	24	-0.400	-0.400	ADP
eurjchem-1675	276	25	n29	n29	NOUN
eurjchem-1675	276	26	-0.629	-0.629	X
eurjchem-1675	276	27	n27	n27	PROPN
eurjchem-1675	276	28	-0.323	-0.323	PUNCT
eurjchem-1675	276	29	n26	n26	PROPN
eurjchem-1675	276	30	-0.726	-0.726	PROPN
eurjchem-1675	276	31	c22	c22	PROPN
eurjchem-1675	276	32	-0.037	-0.037	PUNCT
eurjchem-1675	276	33	o47	o47	PROPN
eurjchem-1675	276	34	-0.518	-0.518	PROPN
eurjchem-1675	276	35	c23	c23	PROPN
eurjchem-1675	276	36	0.033	0.033	NUM
eurjchem-1675	276	37	c31	c31	PROPN
eurjchem-1675	276	38	0.292	0.292	NUM
eurjchem-1675	276	39	c28	c28	PROPN
eurjchem-1675	276	40	0.527	0.527	NUM
eurjchem-1675	276	41	c23	c23	PROPN
eurjchem-1675	276	42	0.635	0.635	NUM
eurjchem-1675	276	43	n18	n18	PROPN
eurjchem-1675	276	44	-0.635	-0.635	PROPN
eurjchem-1675	276	45	c22	c22	PROPN
eurjchem-1675	276	46	0.334	0.334	NUM
eurjchem-1675	276	47	o29	o29	PROPN
eurjchem-1675	276	48	-0.496	-0.496	PUNCT
eurjchem-1675	276	49	c24	c24	NOUN
eurjchem-1675	276	50	0.201	0.201	NUM
eurjchem-1675	276	51	c25	c25	PROPN
eurjchem-1675	276	52	0.103	0.103	NUM
eurjchem-1675	276	53	n18	n18	PROPN
eurjchem-1675	276	54	-0.636	-0.636	X
eurjchem-1675	276	55	n26	n26	PROPN
eurjchem-1675	276	56	-0.246	-0.246	NOUN
eurjchem-1675	276	57	table	table	NOUN
eurjchem-1675	276	58	2	2	NUM
eurjchem-1675	276	59	.	.	PUNCT
eurjchem-1675	276	60	structural	structural	ADJ
eurjchem-1675	276	61	parameters	parameter	NOUN
eurjchem-1675	276	62	of	of	ADP
eurjchem-1675	276	63	compound	compound	NOUN
eurjchem-1675	276	64	6	6	NUM
eurjchem-1675	276	65	calculated	calculate	VERB
eurjchem-1675	276	66	using	use	VERB
eurjchem-1675	276	67	the	the	DET
eurjchem-1675	276	68	b3lyp	b3lyp	NUM
eurjchem-1675	276	69	level	level	NOUN
eurjchem-1675	276	70	and	and	CCONJ
eurjchem-1675	276	71	hf	hf	NOUN
eurjchem-1675	276	72	.	.	PUNCT
eurjchem-1675	277	1	parameters	parameter	NOUN
eurjchem-1675	277	2	bond	bond	NOUN
eurjchem-1675	277	3	length	length	NOUN
eurjchem-1675	277	4	(	(	PUNCT
eurjchem-1675	277	5	å	å	NOUN
eurjchem-1675	277	6	)	)	PUNCT
eurjchem-1675	277	7	parameters	parameter	NOUN
eurjchem-1675	277	8	bond	bond	NOUN
eurjchem-1675	277	9	angles	angle	NOUN
eurjchem-1675	277	10	(	(	PUNCT
eurjchem-1675	277	11	°	°	PRON
eurjchem-1675	277	12	)	)	PUNCT
eurjchem-1675	277	13	calculated	calculate	VERB
eurjchem-1675	277	14	,	,	PUNCT
eurjchem-1675	277	15	hf/6	hf/6	NOUN
eurjchem-1675	277	16	-	-	PUNCT
eurjchem-1675	277	17	31g(d	31g(d	NOUN
eurjchem-1675	277	18	)	)	PUNCT
eurjchem-1675	277	19	experimental	experimental	ADJ
eurjchem-1675	277	20	calculated	calculate	VERB
eurjchem-1675	277	21	,	,	PUNCT
eurjchem-1675	277	22	dft/	dft/	PROPN
eurjchem-1675	277	23	b3lyp	b3lyp	SYM
eurjchem-1675	277	24	experimental	experimental	PROPN
eurjchem-1675	277	25	n30	n30	PROPN
eurjchem-1675	277	26	-	-	PUNCT
eurjchem-1675	277	27	n29	n29	NOUN
eurjchem-1675	277	28	1.4029	1.4029	NUM
eurjchem-1675	277	29	1.43019	1.43019	NUM
eurjchem-1675	277	30	h19	h19	PROPN
eurjchem-1675	277	31	-	-	PUNCT
eurjchem-1675	277	32	n18	n18	NOUN
eurjchem-1675	277	33	-	-	PUNCT
eurjchem-1675	277	34	c20	c20	NOUN
eurjchem-1675	277	35	113.0933	113.0933	NUM
eurjchem-1675	277	36	113.00599	113.00599	NUM
eurjchem-1675	277	37	n29	n29	NOUN
eurjchem-1675	277	38	-	-	PUNCT
eurjchem-1675	277	39	c23	c23	NOUN
eurjchem-1675	277	40	1.3487	1.3487	NUM
eurjchem-1675	277	41	1.29388	1.29388	NUM
eurjchem-1675	277	42	n18	n18	PROPN
eurjchem-1675	277	43	-	-	PUNCT
eurjchem-1675	277	44	c20	c20	NOUN
eurjchem-1675	277	45	-	-	PUNCT
eurjchem-1675	277	46	o21	o21	NOUN
eurjchem-1675	277	47	121.2687	121.2687	NUM
eurjchem-1675	277	48	121.51027	121.51027	NUM
eurjchem-1675	277	49	c23	c23	PROPN
eurjchem-1675	277	50	-	-	PUNCT
eurjchem-1675	277	51	c22	c22	NOUN
eurjchem-1675	277	52	1.5088	1.5088	NUM
eurjchem-1675	277	53	1.51345	1.51345	NUM
eurjchem-1675	277	54	o21	o21	NOUN
eurjchem-1675	277	55	-	-	PUNCT
eurjchem-1675	277	56	c20	c20	NOUN
eurjchem-1675	277	57	-	-	PUNCT
eurjchem-1675	277	58	c22	c22	NOUN
eurjchem-1675	277	59	119.1665	119.1665	NUM
eurjchem-1675	277	60	117.56467	117.56467	PROPN
eurjchem-1675	277	61	c22	c22	NOUN
eurjchem-1675	277	62	-	-	PUNCT
eurjchem-1675	277	63	c24	c24	PROPN
eurjchem-1675	277	64	1.5356	1.5356	NUM
eurjchem-1675	277	65	1.52672	1.52672	NUM
eurjchem-1675	277	66	n30	n30	PROPN
eurjchem-1675	277	67	-	-	PUNCT
eurjchem-1675	277	68	n29	n29	NOUN
eurjchem-1675	277	69	-	-	PUNCT
eurjchem-1675	277	70	c23	c23	NOUN
eurjchem-1675	277	71	113.67825	113.67825	NUM
eurjchem-1675	277	72	111.92764	111.92764	NUM
eurjchem-1675	277	73	n30	n30	PROPN
eurjchem-1675	277	74	-	-	PUNCT
eurjchem-1675	277	75	c24	c24	NOUN
eurjchem-1675	277	76	1.35967	1.35967	NUM
eurjchem-1675	277	77	1.36381	1.36381	NUM
eurjchem-1675	277	78	n29	n29	NOUN
eurjchem-1675	277	79	-	-	PUNCT
eurjchem-1675	277	80	c23	c23	NOUN
eurjchem-1675	277	81	-	-	PUNCT
eurjchem-1675	277	82	c22	c22	NOUN
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eurjchem-1675	277	84	111.4882	111.4882	NUM
eurjchem-1675	277	85	c24	c24	NOUN
eurjchem-1675	277	86	-	-	PUNCT
eurjchem-1675	277	87	c46	c46	NOUN
eurjchem-1675	277	88	1.42722	1.42722	NUM
eurjchem-1675	277	89	1.39801	1.39801	NUM
eurjchem-1675	277	90	n29	n29	NOUN
eurjchem-1675	277	91	-	-	PUNCT
eurjchem-1675	277	92	c23	c23	NOUN
eurjchem-1675	277	93	-	-	PUNCT
eurjchem-1675	277	94	n26	n26	NOUN
eurjchem-1675	277	95	125.66977	125.66977	NUM
eurjchem-1675	277	96	126.01034	126.01034	NUM
eurjchem-1675	277	97	c46	c46	NOUN
eurjchem-1675	277	98	-	-	PUNCT
eurjchem-1675	277	99	o47	o47	NOUN
eurjchem-1675	277	100	1.27715	1.27715	NUM
eurjchem-1675	277	101	1.26361	1.26361	NUM
eurjchem-1675	277	102	c22	c22	NOUN
eurjchem-1675	277	103	-	-	PUNCT
eurjchem-1675	277	104	c23	c23	NOUN
eurjchem-1675	277	105	-	-	PUNCT
eurjchem-1675	277	106	n26	n26	NOUN
eurjchem-1675	277	107	125.17205	125.17205	NUM
eurjchem-1675	277	108	124.42526	124.42526	NUM
eurjchem-1675	277	109	c23	c23	PROPN
eurjchem-1675	277	110	-	-	PUNCT
eurjchem-1675	277	111	n26	n26	PROPN
eurjchem-1675	277	112	1.36255	1.36255	NUM
eurjchem-1675	277	113	1.33060	1.33060	NUM
eurjchem-1675	277	114	c31	c31	NOUN
eurjchem-1675	277	115	-	-	PUNCT
eurjchem-1675	277	116	n29	n29	NOUN
eurjchem-1675	277	117	-	-	PUNCT
eurjchem-1675	277	118	n30	n30	NOUN
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eurjchem-1675	277	120	117	117	NUM
eurjchem-1675	277	121	..	..	SYM
eurjchem-1675	277	122	5291	5291	NUM
eurjchem-1675	277	123	c20	c20	PROPN
eurjchem-1675	277	124	-	-	PUNCT
eurjchem-1675	277	125	n18	n18	PROPN
eurjchem-1675	277	126	1.35801	1.35801	NUM
eurjchem-1675	277	127	1.33727	1.33727	NUM
eurjchem-1675	277	128	c31	c31	NOUN
eurjchem-1675	277	129	-	-	PUNCT
eurjchem-1675	277	130	n29	n29	NOUN
eurjchem-1675	277	131	-	-	PUNCT
eurjchem-1675	277	132	c23	c23	PROPN
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eurjchem-1675	277	134	127.8572	127.8572	NUM
eurjchem-1675	277	135	c20	c20	NOUN
eurjchem-1675	277	136	-	-	PUNCT
eurjchem-1675	277	137	o21	o21	NOUN
eurjchem-1675	277	138	1.26007	1.26007	NUM
eurjchem-1675	277	139	1.24062	1.24062	NUM
eurjchem-1675	277	140	h27	h27	NOUN
eurjchem-1675	277	141	-	-	PUNCT
eurjchem-1675	277	142	n26	n26	NOUN
eurjchem-1675	277	143	-	-	PUNCT
eurjchem-1675	277	144	h28	h28	NOUN
eurjchem-1675	277	145	32.12128	32.12128	NUM
eurjchem-1675	277	146	116.73781	116.73781	NUM
eurjchem-1675	277	147	n29	n29	NOUN
eurjchem-1675	277	148	-	-	PUNCT
eurjchem-1675	277	149	c31	c31	NOUN
eurjchem-1675	277	150	1.42657	1.42657	NUM
eurjchem-1675	277	151	1.42545	1.42545	NUM
eurjchem-1675	277	152	n30	n30	PROPN
eurjchem-1675	277	153	-	-	PUNCT
eurjchem-1675	277	154	c24	c24	NOUN
eurjchem-1675	277	155	-	-	PUNCT
eurjchem-1675	277	156	c46	c46	NOUN
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eurjchem-1675	278	2	123.57956	123.57956	NUM
eurjchem-1675	278	3	o41	o41	NOUN
eurjchem-1675	278	4	-	-	PUNCT
eurjchem-1675	278	5	c42	c42	NOUN
eurjchem-1675	278	6	1.45374	1.45374	NUM
eurjchem-1675	278	7	1.42878	1.42878	NUM
eurjchem-1675	278	8	o47	o47	NUM
eurjchem-1675	278	9	-	-	PUNCT
eurjchem-1675	278	10	c46	c46	NOUN
eurjchem-1675	278	11	-	-	PUNCT
eurjchem-1675	278	12	c24	c24	NOUN
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eurjchem-1675	278	14	121.10727	121.10727	NUM
eurjchem-1675	278	15	hf	hf	PROPN
eurjchem-1675	278	16	dft	dft	PROPN
eurjchem-1675	278	17	figure	figure	NOUN
eurjchem-1675	278	18	2	2	NUM
eurjchem-1675	278	19	.	.	PUNCT
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eurjchem-1675	278	21	geometry	geometry	NOUN
eurjchem-1675	278	22	,	,	PUNCT
eurjchem-1675	278	23	numbering	numbering	NOUN
eurjchem-1675	278	24	system	system	NOUN
eurjchem-1675	278	25	and	and	CCONJ
eurjchem-1675	278	26	atomic	atomic	ADJ
eurjchem-1675	278	27	orbital	orbital	NOUN
eurjchem-1675	278	28	of	of	ADP
eurjchem-1675	278	29	the	the	DET
eurjchem-1675	278	30	frontier	frontier	NOUN
eurjchem-1675	278	31	molecular	molecular	ADJ
eurjchem-1675	278	32	orbital	orbital	NOUN
eurjchem-1675	278	33	of	of	ADP
eurjchem-1675	278	34	compound	compound	NOUN
eurjchem-1675	278	35	6	6	NUM
eurjchem-1675	278	36	utilizing	utilize	VERB
eurjchem-1675	278	37	hf	hf	PROPN
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eurjchem-1675	278	39	dft	dft	PROPN
eurjchem-1675	278	40	(	(	PUNCT
eurjchem-1675	278	41	b3lyp/6	b3lyp/6	PROPN
eurjchem-1675	278	42	-	-	NOUN
eurjchem-1675	278	43	31g(d	31g(d	NUM
eurjchem-1675	278	44	)	)	PUNCT
eurjchem-1675	278	45	.	.	PUNCT
eurjchem-1675	279	1	the	the	DET
eurjchem-1675	279	2	two	two	NUM
eurjchem-1675	279	3	p	p	ADJ
eurjchem-1675	279	4	-	-	PUNCT
eurjchem-1675	279	5	isoelectronic	isoelectronic	ADJ
eurjchem-1675	279	6	structures	structure	NOUN
eurjchem-1675	279	7	6	6	NUM
eurjchem-1675	279	8	and	and	CCONJ
eurjchem-1675	279	9	8	8	NUM
eurjchem-1675	279	10	are	be	AUX
eurjchem-1675	279	11	dissimilar	dissimilar	ADJ
eurjchem-1675	279	12	in	in	ADP
eurjchem-1675	279	13	order	order	NOUN
eurjchem-1675	279	14	of	of	ADP
eurjchem-1675	279	15	stability	stability	NOUN
eurjchem-1675	279	16	,	,	PUNCT
eurjchem-1675	279	17	despite	despite	SCONJ
eurjchem-1675	279	18	the	the	DET
eurjchem-1675	279	19	fact	fact	NOUN
eurjchem-1675	279	20	1h	1h	NUM
eurjchem-1675	279	21	-	-	PUNCT
eurjchem-1675	279	22	pyrazole	pyrazole	NOUN
eurjchem-1675	279	23	6	6	NUM
eurjchem-1675	279	24	appears	appear	VERB
eurjchem-1675	279	25	an	an	DET
eurjchem-1675	279	26	additional	additional	ADJ
eurjchem-1675	279	27	stable	stable	ADJ
eurjchem-1675	279	28	than	than	ADP
eurjchem-1675	279	29	pyrazole	pyrazole	NOUN
eurjchem-1675	279	30	8	8	NUM
eurjchem-1675	279	31	by	by	ADP
eurjchem-1675	279	32	1.5142	1.5142	NUM
eurjchem-1675	279	33	ev	ev	X
eurjchem-1675	279	34	(	(	PUNCT
eurjchem-1675	279	35	≈	≈	PROPN
eurjchem-1675	279	36	950.175	950.175	PROPN
eurjchem-1675	279	37	kcal	kcal	NOUN
eurjchem-1675	279	38	)	)	PUNCT
eurjchem-1675	279	39	.	.	PUNCT
eurjchem-1675	280	1	beginning	begin	VERB
eurjchem-1675	280	2	the	the	DET
eurjchem-1675	280	3	calculations	calculation	NOUN
eurjchem-1675	280	4	of	of	ADP
eurjchem-1675	280	5	the	the	DET
eurjchem-1675	280	6	energy	energy	NOUN
eurjchem-1675	280	7	gap	gap	NOUN
eurjchem-1675	280	8	,	,	PUNCT
eurjchem-1675	280	9	eg	eg	NOUN
eurjchem-1675	280	10	,	,	PUNCT
eurjchem-1675	280	11	which	which	PRON
eurjchem-1675	280	12	calculate	calculate	VERB
eurjchem-1675	280	13	the	the	DET
eurjchem-1675	280	14	chemical	chemical	NOUN
eurjchem-1675	280	15	activity	activity	NOUN
eurjchem-1675	280	16	,	,	PUNCT
eurjchem-1675	280	17	pyrazole	pyrazole	NOUN
eurjchem-1675	280	18	6	6	NUM
eurjchem-1675	280	19	was	be	AUX
eurjchem-1675	280	20	established	establish	VERB
eurjchem-1675	280	21	to	to	PART
eurjchem-1675	280	22	be	be	AUX
eurjchem-1675	280	23	extra	extra	ADJ
eurjchem-1675	280	24	reactive	reactive	ADJ
eurjchem-1675	280	25	than	than	ADP
eurjchem-1675	280	26	amino	amino	ADJ
eurjchem-1675	280	27	pyrazole	pyrazole	NOUN
eurjchem-1675	280	28	8	8	NUM
eurjchem-1675	280	29	by	by	ADP
eurjchem-1675	280	30	37.048	37.048	NUM
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eurjchem-1675	280	32	.	.	PUNCT
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eurjchem-1675	281	2	,	,	PUNCT
eurjchem-1675	281	3	the	the	DET
eurjchem-1675	281	4	polarity	polarity	NOUN
eurjchem-1675	281	5	or	or	CCONJ
eurjchem-1675	281	6	charge	charge	NOUN
eurjchem-1675	281	7	separation	separation	NOUN
eurjchem-1675	281	8	over	over	ADP
eurjchem-1675	281	9	the	the	DET
eurjchem-1675	281	10	molecule	molecule	NOUN
eurjchem-1675	281	11	,	,	PUNCT
eurjchem-1675	281	12	which	which	PRON
eurjchem-1675	281	13	is	be	AUX
eurjchem-1675	281	14	measured	measure	VERB
eurjchem-1675	281	15	through	through	ADP
eurjchem-1675	281	16	the	the	DET
eurjchem-1675	281	17	dipole	dipole	NOUN
eurjchem-1675	281	18	moment	moment	NOUN
eurjchem-1675	281	19	µ	µ	NUM
eurjchem-1675	281	20	,	,	PUNCT
eurjchem-1675	281	21	exhibited	exhibit	VERB
eurjchem-1675	281	22	that	that	SCONJ
eurjchem-1675	281	23	µ	µ	NOUN
eurjchem-1675	281	24	of	of	ADP
eurjchem-1675	281	25	pyrazole	pyrazole	NOUN
eurjchem-1675	281	26	6	6	NUM
eurjchem-1675	281	27	<	<	X
eurjchem-1675	281	28	µ	µ	X
eurjchem-1675	281	29	of	of	ADP
eurjchem-1675	281	30	pyrazole	pyrazole	NOUN
eurjchem-1675	281	31	8	8	NUM
eurjchem-1675	281	32	by	by	ADP
eurjchem-1675	281	33	0.8466	0.8466	NUM
eurjchem-1675	281	34	debye	debye	ADJ
eurjchem-1675	281	35	as	as	SCONJ
eurjchem-1675	281	36	displayed	display	VERB
eurjchem-1675	281	37	in	in	ADP
eurjchem-1675	281	38	figure	figure	NOUN
eurjchem-1675	281	39	2	2	NUM
eurjchem-1675	281	40	.	.	NOUN
eurjchem-1675	281	41	3.2.1	3.2.1	NUM
eurjchem-1675	281	42	.	.	PUNCT
eurjchem-1675	281	43	geometry	geometry	NOUN
eurjchem-1675	281	44	optimization	optimization	NOUN
eurjchem-1675	281	45	of	of	ADP
eurjchem-1675	281	46	the	the	DET
eurjchem-1675	281	47	compound	compound	NOUN
eurjchem-1675	281	48	6	6	NUM
eurjchem-1675	281	49	complete	complete	ADJ
eurjchem-1675	281	50	geometry	geometry	NOUN
eurjchem-1675	281	51	optimization	optimization	NOUN
eurjchem-1675	281	52	of	of	ADP
eurjchem-1675	281	53	compound	compound	NOUN
eurjchem-1675	281	54	6	6	NUM
eurjchem-1675	281	55	was	be	AUX
eurjchem-1675	281	56	accomplished	accomplish	VERB
eurjchem-1675	281	57	at	at	ADP
eurjchem-1675	281	58	dft	dft	PROPN
eurjchem-1675	281	59	(	(	PUNCT
eurjchem-1675	281	60	b3lyp/6	b3lyp/6	PROPN
eurjchem-1675	281	61	-	-	NOUN
eurjchem-1675	281	62	31g(d	31g(d	NUM
eurjchem-1675	281	63	)	)	PUNCT
eurjchem-1675	281	64	)	)	PUNCT
eurjchem-1675	281	65	and	and	CCONJ
eurjchem-1675	281	66	hf/6	hf/6	NOUN
eurjchem-1675	281	67	-	-	PUNCT
eurjchem-1675	281	68	31g(d	31g(d	NOUN
eurjchem-1675	281	69	)	)	PUNCT
eurjchem-1675	281	70	level	level	NOUN
eurjchem-1675	281	71	of	of	ADP
eurjchem-1675	281	72	theory	theory	NOUN
eurjchem-1675	281	73	.	.	PUNCT
eurjchem-1675	282	1	lowest	low	ADJ
eurjchem-1675	282	2	potential	potential	ADJ
eurjchem-1675	282	3	energy	energy	NOUN
eurjchem-1675	282	4	surfaces	surface	NOUN
eurjchem-1675	282	5	for	for	ADP
eurjchem-1675	282	6	the	the	DET
eurjchem-1675	282	7	optimized	optimize	VERB
eurjchem-1675	282	8	structure	structure	NOUN
eurjchem-1675	282	9	was	be	AUX
eurjchem-1675	282	10	checked	check	VERB
eurjchem-1675	282	11	as	as	ADP
eurjchem-1675	282	12	on	on	ADP
eurjchem-1675	282	13	the	the	PRON
eurjchem-1675	282	14	by	by	ADP
eurjchem-1675	282	15	frequency	frequency	NOUN
eurjchem-1675	282	16	calculations	calculation	NOUN
eurjchem-1675	282	17	.	.	PUNCT
eurjchem-1675	283	1	an	an	DET
eurjchem-1675	283	2	opinion	opinion	NOUN
eurjchem-1675	283	3	of	of	ADP
eurjchem-1675	283	4	the	the	DET
eurjchem-1675	283	5	optimized	optimize	VERB
eurjchem-1675	283	6	structure	structure	NOUN
eurjchem-1675	283	7	and	and	CCONJ
eurjchem-1675	283	8	its	its	PRON
eurjchem-1675	283	9	atoms	atom	NOUN
eurjchem-1675	283	10	numbering	numbering	NOUN
eurjchem-1675	283	11	are	be	AUX
eurjchem-1675	283	12	displayed	display	VERB
eurjchem-1675	283	13	in	in	ADP
eurjchem-1675	283	14	figure	figure	NOUN
eurjchem-1675	283	15	2	2	NUM
eurjchem-1675	283	16	.	.	PUNCT
eurjchem-1675	284	1	the	the	DET
eurjchem-1675	284	2	bond	bond	NOUN
eurjchem-1675	284	3	distances	distance	NOUN
eurjchem-1675	284	4	and	and	CCONJ
eurjchem-1675	284	5	angles	angle	NOUN
eurjchem-1675	284	6	designated	designate	VERB
eurjchem-1675	284	7	are	be	AUX
eurjchem-1675	284	8	scheduled	schedule	VERB
eurjchem-1675	284	9	in	in	ADP
eurjchem-1675	284	10	table	table	NOUN
eurjchem-1675	284	11	2	2	NUM
eurjchem-1675	284	12	.	.	PUNCT
eurjchem-1675	285	1	the	the	DET
eurjchem-1675	285	2	optimized	optimize	VERB
eurjchem-1675	285	3	geometry	geometry	NOUN
eurjchem-1675	285	4	is	be	AUX
eurjchem-1675	285	5	associated	associate	VERB
eurjchem-1675	285	6	with	with	ADP
eurjchem-1675	285	7	the	the	DET
eurjchem-1675	285	8	crystallographic	crystallographic	ADJ
eurjchem-1675	285	9	data	datum	NOUN
eurjchem-1675	285	10	of	of	ADP
eurjchem-1675	285	11	n	n	CCONJ
eurjchem-1675	285	12	-	-	PUNCT
eurjchem-1675	285	13	aryl	aryl	NOUN
eurjchem-1675	285	14	pyrazoles	pyrazole	NOUN
eurjchem-1675	286	1	[	[	X
eurjchem-1675	286	2	25	25	NUM
eurjchem-1675	286	3	-	-	SYM
eurjchem-1675	286	4	28	28	NUM
eurjchem-1675	286	5	]	]	PUNCT
eurjchem-1675	286	6	.	.	PUNCT
eurjchem-1675	287	1	the	the	DET
eurjchem-1675	287	2	overall	overall	ADJ
eurjchem-1675	287	3	energy	energy	NOUN
eurjchem-1675	287	4	minimum	minimum	NOUN
eurjchem-1675	287	5	of	of	ADP
eurjchem-1675	287	6	3	3	NUM
eurjchem-1675	287	7	-	-	PUNCT
eurjchem-1675	287	8	amino	amino	NOUN
eurjchem-1675	287	9	-	-	PUNCT
eurjchem-1675	287	10	ncyclohexyl-5	ncyclohexyl-5	NOUN
eurjchem-1675	287	11	-	-	PUNCT
eurjchem-1675	287	12	ethoxy-2	ethoxy-2	PROPN
eurjchem-1675	287	13	,	,	PUNCT
eurjchem-1675	287	14	3	3	NUM
eurjchem-1675	287	15	-	-	PUNCT
eurjchem-1675	287	16	dihydro-2-(4	dihydro-2-(4	ADJ
eurjchem-1675	287	17	-	-	PUNCT
eurjchem-1675	287	18	methoxyphenyl)-1hpyrazole-4	methoxyphenyl)-1hpyrazole-4	NOUN
eurjchem-1675	287	19	-	-	PUNCT
eurjchem-1675	287	20	carboxamide	carboxamide	NOUN
eurjchem-1675	287	21	(	(	PUNCT
eurjchem-1675	287	22	6	6	NUM
eurjchem-1675	287	23	)	)	PUNCT
eurjchem-1675	287	24	is	be	AUX
eurjchem-1675	287	25	-1222.6679	-1222.6679	PRON
eurjchem-1675	287	26	hartree	hartree	ADJ
eurjchem-1675	287	27	(	(	PUNCT
eurjchem-1675	287	28	-3.2×105	-3.2×105	PROPN
eurjchem-1675	287	29	kcal	kcal	PROPN
eurjchem-1675	287	30	/	/	SYM
eurjchem-1675	287	31	mol	mol	NOUN
eurjchem-1675	287	32	)	)	PUNCT
eurjchem-1675	287	33	with	with	ADP
eurjchem-1675	287	34	dipole	dipole	NOUN
eurjchem-1675	287	35	moment	moment	NOUN
eurjchem-1675	287	36	=	=	SYM
eurjchem-1675	287	37	5.6949	5.6949	NUM
eurjchem-1675	287	38	debye	debye	NOUN
eurjchem-1675	287	39	and	and	CCONJ
eurjchem-1675	287	40	-1214.8860	-1214.8860	X
eurjchem-1675	287	41	hartree	hartree	ADJ
eurjchem-1675	287	42	(	(	PUNCT
eurjchem-1675	287	43	-3.1×105	-3.1×105	PROPN
eurjchem-1675	287	44	kcal	kcal	ADJ
eurjchem-1675	287	45	/	/	SYM
eurjchem-1675	287	46	mol	mol	NOUN
eurjchem-1675	287	47	)	)	PUNCT
eurjchem-1675	287	48	with	with	ADP
eurjchem-1675	287	49	dipole	dipole	NOUN
eurjchem-1675	287	50	moment	moment	NOUN
eurjchem-1675	287	51	=	=	NOUN
eurjchem-1675	288	1	6.3747	6.3747	NUM
eurjchem-1675	288	2	debye	debye	ADV
eurjchem-1675	288	3	as	as	SCONJ
eurjchem-1675	288	4	measured	measure	VERB
eurjchem-1675	288	5	through	through	ADP
eurjchem-1675	288	6	dft	dft	PROPN
eurjchem-1675	288	7	/	/	SYM
eurjchem-1675	288	8	b3lyp	b3lyp	PROPN
eurjchem-1675	288	9	and	and	CCONJ
eurjchem-1675	288	10	hf	hf	NOUN
eurjchem-1675	288	11	,	,	PUNCT
eurjchem-1675	288	12	respectively	respectively	ADV
eurjchem-1675	288	13	.	.	PUNCT
eurjchem-1675	289	1	the	the	DET
eurjchem-1675	289	2	optimization	optimization	NOUN
eurjchem-1675	289	3	studies	study	NOUN
eurjchem-1675	289	4	that	that	SCONJ
eurjchem-1675	289	5	the	the	DET
eurjchem-1675	289	6	molecule	molecule	NOUN
eurjchem-1675	289	7	be	be	AUX
eurjchem-1675	289	8	appropriate	appropriate	ADJ
eurjchem-1675	289	9	to	to	ADP
eurjchem-1675	289	10	c1	c1	PROPN
eurjchem-1675	289	11	symmetry	symmetry	PROPN
eurjchem-1675	289	12	point	point	NOUN
eurjchem-1675	289	13	group	group	NOUN
eurjchem-1675	289	14	.	.	PUNCT
eurjchem-1675	290	1	it	it	PRON
eurjchem-1675	290	2	is	be	AUX
eurjchem-1675	290	3	well	well	ADV
eurjchem-1675	290	4	known	know	VERB
eurjchem-1675	290	5	that	that	SCONJ
eurjchem-1675	290	6	bond	bond	NOUN
eurjchem-1675	290	7	lengths	length	NOUN
eurjchem-1675	290	8	and	and	CCONJ
eurjchem-1675	290	9	angles	angle	NOUN
eurjchem-1675	290	10	assumed	assume	VERB
eurjchem-1675	290	11	at	at	ADP
eurjchem-1675	290	12	dft	dft	PROPN
eurjchem-1675	290	13	/	/	SYM
eurjchem-1675	290	14	b3lyp/6	b3lyp/6	PROPN
eurjchem-1675	290	15	-	-	PUNCT
eurjchem-1675	290	16	31	31	NUM
eurjchem-1675	290	17	g	g	NOUN
eurjchem-1675	290	18	level	level	NOUN
eurjchem-1675	290	19	of	of	ADP
eurjchem-1675	290	20	theory	theory	NOUN
eurjchem-1675	290	21	are	be	AUX
eurjchem-1675	290	22	regularly	regularly	ADV
eurjchem-1675	290	23	more	more	ADV
eurjchem-1675	290	24	exact	exact	ADJ
eurjchem-1675	290	25	than	than	ADP
eurjchem-1675	290	26	hf	hf	ADP
eurjchem-1675	290	27	owing	owe	VERB
eurjchem-1675	290	28	to	to	ADP
eurjchem-1675	290	29	the	the	DET
eurjchem-1675	290	30	inclusion	inclusion	NOUN
eurjchem-1675	290	31	of	of	ADP
eurjchem-1675	290	32	electron	electron	NOUN
eurjchem-1675	290	33	correlation	correlation	NOUN
eurjchem-1675	290	34	.	.	PUNCT
eurjchem-1675	291	1	on	on	ADP
eurjchem-1675	291	2	the	the	DET
eurjchem-1675	291	3	contrary	contrary	NOUN
eurjchem-1675	291	4	,	,	PUNCT
eurjchem-1675	291	5	in	in	ADP
eurjchem-1675	291	6	the	the	DET
eurjchem-1675	291	7	present	present	ADJ
eurjchem-1675	291	8	study	study	NOUN
eurjchem-1675	291	9	,	,	PUNCT
eurjchem-1675	291	10	it	it	PRON
eurjchem-1675	291	11	was	be	AUX
eurjchem-1675	291	12	found	find	VERB
eurjchem-1675	291	13	that	that	SCONJ
eurjchem-1675	291	14	dft(b3lyp/6	dft(b3lyp/6	NOUN
eurjchem-1675	291	15	-	-	PUNCT
eurjchem-1675	291	16	31g(d	31g(d	NOUN
eurjchem-1675	291	17	)	)	PUNCT
eurjchem-1675	291	18	technique	technique	NOUN
eurjchem-1675	291	19	associates	associate	NOUN
eurjchem-1675	291	20	well	well	ADV
eurjchem-1675	291	21	for	for	ADP
eurjchem-1675	291	22	the	the	DET
eurjchem-1675	291	23	molecular	molecular	ADJ
eurjchem-1675	291	24	parameters	parameter	NOUN
eurjchem-1675	291	25	comparing	compare	VERB
eurjchem-1675	291	26	with	with	ADP
eurjchem-1675	291	27	hf	hf	ADJ
eurjchem-1675	291	28	procedure	procedure	NOUN
eurjchem-1675	291	29	(	(	PUNCT
eurjchem-1675	291	30	table	table	NOUN
eurjchem-1675	291	31	2	2	NUM
eurjchem-1675	291	32	)	)	PUNCT
eurjchem-1675	291	33	.	.	PUNCT
eurjchem-1675	292	1	improved	improve	VERB
eurjchem-1675	292	2	promise	promise	NOUN
eurjchem-1675	292	3	between	between	ADP
eurjchem-1675	292	4	the	the	DET
eurjchem-1675	292	5	calculated	calculated	ADJ
eurjchem-1675	292	6	bond	bond	NOUN
eurjchem-1675	292	7	lengths	length	NOUN
eurjchem-1675	292	8	of	of	ADP
eurjchem-1675	292	9	compound	compound	NOUN
eurjchem-1675	292	10	6	6	NUM
eurjchem-1675	292	11	and	and	CCONJ
eurjchem-1675	292	12	the	the	DET
eurjchem-1675	292	13	experimental	experimental	ADJ
eurjchem-1675	292	14	data	datum	NOUN
eurjchem-1675	292	15	of	of	ADP
eurjchem-1675	292	16	naryl	naryl	PROPN
eurjchem-1675	292	17	pyrazoles	pyrazole	NOUN
eurjchem-1675	292	18	is	be	AUX
eurjchem-1675	292	19	found	find	VERB
eurjchem-1675	292	20	,	,	PUNCT
eurjchem-1675	292	21	subsequently	subsequently	ADV
eurjchem-1675	292	22	the	the	DET
eurjchem-1675	292	23	largest	large	ADJ
eurjchem-1675	292	24	difference	difference	NOUN
eurjchem-1675	292	25	is	be	AUX
eurjchem-1675	292	26	originate	originate	ADJ
eurjchem-1675	292	27	to	to	PART
eurjchem-1675	292	28	be	be	AUX
eurjchem-1675	292	29	00978	00978	NUM
eurjchem-1675	292	30	å	å	PROPN
eurjchem-1675	292	31	and	and	CCONJ
eurjchem-1675	292	32	0.01354	0.01354	NUM
eurjchem-1675	292	33	å	å	PROPN
eurjchem-1675	292	34	as	as	SCONJ
eurjchem-1675	292	35	designed	design	VERB
eurjchem-1675	292	36	at	at	ADP
eurjchem-1675	292	37	dft	dft	PROPN
eurjchem-1675	292	38	/	/	SYM
eurjchem-1675	292	39	b3lyp(d	b3lyp(d	PROPN
eurjchem-1675	292	40	)	)	PUNCT
eurjchem-1675	292	41	and	and	CCONJ
eurjchem-1675	292	42	hf	hf	NOUN
eurjchem-1675	292	43	,	,	PUNCT
eurjchem-1675	292	44	respectively	respectively	ADV
eurjchem-1675	292	45	.	.	PUNCT
eurjchem-1675	293	1	additionally	additionally	ADV
eurjchem-1675	293	2	,	,	PUNCT
eurjchem-1675	293	3	the	the	DET
eurjchem-1675	293	4	bond	bond	NOUN
eurjchem-1675	293	5	angles	angle	VERB
eurjchem-1675	293	6	difference	difference	NOUN
eurjchem-1675	293	7	0.584	0.584	NUM
eurjchem-1675	293	8	-	-	SYM
eurjchem-1675	293	9	4.012	4.012	NUM
eurjchem-1675	293	10	for	for	ADP
eurjchem-1675	293	11	hf	hf	NOUN
eurjchem-1675	293	12	and	and	CCONJ
eurjchem-1675	293	13	0.43944	0.43944	NUM
eurjchem-1675	293	14	-	-	SYM
eurjchem-1675	293	15	14.52214	14.52214	NUM
eurjchem-1675	293	16	as	as	SCONJ
eurjchem-1675	293	17	displayed	display	VERB
eurjchem-1675	293	18	in	in	ADP
eurjchem-1675	293	19	table	table	NOUN
eurjchem-1675	293	20	2	2	NUM
eurjchem-1675	293	21	.	.	PUNCT
eurjchem-1675	293	22	3.2.2	3.2.2	NUM
eurjchem-1675	293	23	.	.	PUNCT
eurjchem-1675	293	24	frontier	frontier	NOUN
eurjchem-1675	293	25	molecular	molecular	ADJ
eurjchem-1675	293	26	orbitals	orbital	NOUN
eurjchem-1675	293	27	of	of	ADP
eurjchem-1675	293	28	compound	compound	NOUN
eurjchem-1675	293	29	6	6	NUM
eurjchem-1675	293	30	frontier	frontier	NOUN
eurjchem-1675	293	31	molecular	molecular	ADJ
eurjchem-1675	293	32	orbital	orbital	ADJ
eurjchem-1675	293	33	(	(	PUNCT
eurjchem-1675	293	34	fmo	fmo	NOUN
eurjchem-1675	293	35	)	)	PUNCT
eurjchem-1675	293	36	is	be	AUX
eurjchem-1675	293	37	a	a	DET
eurjchem-1675	293	38	influential	influential	ADJ
eurjchem-1675	293	39	guiding	guide	VERB
eurjchem-1675	293	40	approach	approach	NOUN
eurjchem-1675	293	41	in	in	ADP
eurjchem-1675	293	42	the	the	DET
eurjchem-1675	293	43	electrical	electrical	ADJ
eurjchem-1675	293	44	and	and	CCONJ
eurjchem-1675	293	45	optical	optical	ADJ
eurjchem-1675	293	46	properties	property	NOUN
eurjchem-1675	293	47	,	,	PUNCT
eurjchem-1675	293	48	in	in	ADP
eurjchem-1675	293	49	addition	addition	NOUN
eurjchem-1675	293	50	to	to	ADP
eurjchem-1675	293	51	uv	uv	NOUN
eurjchem-1675	293	52	-	-	PUNCT
eurjchem-1675	293	53	vis	vis	X
eurjchem-1675	293	54	spectra	spectra	ADJ
eurjchem-1675	293	55	and	and	CCONJ
eurjchem-1675	293	56	chemical	chemical	NOUN
eurjchem-1675	293	57	reactions	reaction	NOUN
eurjchem-1675	293	58	.	.	PUNCT
eurjchem-1675	294	1	the	the	DET
eurjchem-1675	294	2	homo	homo	NOUN
eurjchem-1675	294	3	and	and	CCONJ
eurjchem-1675	294	4	lumo	lumo	NOUN
eurjchem-1675	294	5	are	be	AUX
eurjchem-1675	294	6	actual	actual	ADJ
eurjchem-1675	294	7	important	important	ADJ
eurjchem-1675	294	8	parameters	parameter	NOUN
eurjchem-1675	294	9	used	use	VERB
eurjchem-1675	294	10	in	in	ADP
eurjchem-1675	294	11	quantum	quantum	ADJ
eurjchem-1675	294	12	chemistry	chemistry	NOUN
eurjchem-1675	294	13	.	.	PUNCT
eurjchem-1675	295	1	2018	2018	NUM
eurjchem-1675	295	2	–	–	PUNCT
eurjchem-1675	295	3	european	european	ADJ
eurjchem-1675	295	4	journal	journal	NOUN
eurjchem-1675	295	5	of	of	ADP
eurjchem-1675	295	6	chemistry	chemistry	NOUN
eurjchem-1675	295	7	–	–	PUNCT
eurjchem-1675	295	8	cc	cc	NOUN
eurjchem-1675	295	9	by	by	ADP
eurjchem-1675	295	10	nc	nc	PROPN
eurjchem-1675	295	11	–	–	PUNCT
eurjchem-1675	295	12	doi	doi	NOUN
eurjchem-1675	295	13	:	:	PUNCT
eurjchem-1675	295	14	10.5155	10.5155	NUM
eurjchem-1675	295	15	/	/	SYM
eurjchem-1675	295	16	eurjchem.9.1.30	eurjchem.9.1.30	NOUN
eurjchem-1675	295	17	-	-	SYM
eurjchem-1675	295	18	38.1675	38.1675	NUM
eurjchem-1675	295	19	fahim	fahim	PROPN
eurjchem-1675	295	20	et	et	PROPN
eurjchem-1675	295	21	al	al	PROPN
eurjchem-1675	295	22	.	.	PUNCT
eurjchem-1675	295	23	/	/	SYM
eurjchem-1675	295	24	european	european	PROPN
eurjchem-1675	295	25	journal	journal	PROPN
eurjchem-1675	295	26	of	of	ADP
eurjchem-1675	295	27	chemistry	chemistry	NOUN
eurjchem-1675	295	28	9	9	NUM
eurjchem-1675	295	29	(	(	PUNCT
eurjchem-1675	295	30	1	1	NUM
eurjchem-1675	295	31	)	)	PUNCT
eurjchem-1675	295	32	(	(	PUNCT
eurjchem-1675	295	33	2018	2018	NUM
eurjchem-1675	295	34	)	)	PUNCT
eurjchem-1675	295	35	30	30	NUM
eurjchem-1675	295	36	-	-	SYM
eurjchem-1675	295	37	38	38	NUM
eurjchem-1675	295	38	37	37	NUM
eurjchem-1675	295	39	lumo	lumo	NOUN
eurjchem-1675	295	40	=	=	NOUN
eurjchem-1675	295	41	-6.3300	-6.3300	NOUN
eurjchem-1675	295	42	ev	ev	INTJ
eurjchem-1675	295	43	lumo	lumo	NOUN
eurjchem-1675	295	44	=	=	PUNCT
eurjchem-1675	295	45	-3.5064	-3.5064	NOUN
eurjchem-1675	295	46	ev	ev	X
eurjchem-1675	296	1	⇧	⇧	PROPN
eurjchem-1675	296	2	δe	δe	NOUN
eurjchem-1675	296	3	=	=	SYM
eurjchem-1675	296	4	2.5323	2.5323	NUM
eurjchem-1675	296	5	ev	ev	X
eurjchem-1675	296	6	⇧	⇧	PROPN
eurjchem-1675	296	7	δe	δe	NOUN
eurjchem-1675	296	8	=	=	SYM
eurjchem-1675	296	9	2.4161	2.4161	NUM
eurjchem-1675	296	10	ev	ev	ADP
eurjchem-1675	296	11	homo	homo	NOUN
eurjchem-1675	296	12	=	=	SYM
eurjchem-1675	296	13	-8.8623	-8.8623	NOUN
eurjchem-1675	296	14	ev	ev	INTJ
eurjchem-1675	296	15	homo	homo	NOUN
eurjchem-1675	296	16	=	=	SYM
eurjchem-1675	296	17	-5.9225	-5.9225	PROPN
eurjchem-1675	297	1	ev	ev	PROPN
eurjchem-1675	297	2	hf	hf	PROPN
eurjchem-1675	297	3	dft	dft	PROPN
eurjchem-1675	297	4	figure	figure	NOUN
eurjchem-1675	297	5	3	3	X
eurjchem-1675	297	6	.	.	PUNCT
eurjchem-1675	297	7	gap	gap	NOUN
eurjchem-1675	297	8	energy	energy	NOUN
eurjchem-1675	297	9	(	(	PUNCT
eurjchem-1675	297	10	homo	homo	NOUN
eurjchem-1675	297	11	-	-	PUNCT
eurjchem-1675	297	12	lumo	lumo	NOUN
eurjchem-1675	297	13	)	)	PUNCT
eurjchem-1675	297	14	(	(	PUNCT
eurjchem-1675	297	15	ev	ev	X
eurjchem-1675	297	16	)	)	PUNCT
eurjchem-1675	297	17	are	be	AUX
eurjchem-1675	297	18	calculated	calculate	VERB
eurjchem-1675	297	19	for	for	ADP
eurjchem-1675	297	20	compound	compound	NOUN
eurjchem-1675	297	21	6	6	NUM
eurjchem-1675	297	22	using	use	VERB
eurjchem-1675	297	23	hf	hf	PROPN
eurjchem-1675	297	24	and	and	CCONJ
eurjchem-1675	297	25	dft	dft	PROPN
eurjchem-1675	297	26	.	.	PROPN
eurjchem-1675	297	27	constructed	construct	VERB
eurjchem-1675	297	28	on	on	ADP
eurjchem-1675	297	29	their	their	PRON
eurjchem-1675	297	30	characteristics	characteristic	NOUN
eurjchem-1675	297	31	,	,	PUNCT
eurjchem-1675	297	32	it	it	PRON
eurjchem-1675	297	33	can	can	AUX
eurjchem-1675	297	34	be	be	AUX
eurjchem-1675	297	35	indicated	indicate	VERB
eurjchem-1675	297	36	how	how	SCONJ
eurjchem-1675	297	37	a	a	DET
eurjchem-1675	297	38	molecule	molecule	NOUN
eurjchem-1675	297	39	would	would	AUX
eurjchem-1675	297	40	interact	interact	VERB
eurjchem-1675	297	41	with	with	ADP
eurjchem-1675	297	42	other	other	ADJ
eurjchem-1675	297	43	molecules	molecule	NOUN
eurjchem-1675	297	44	.	.	PUNCT
eurjchem-1675	298	1	the	the	DET
eurjchem-1675	298	2	homo	homo	NOUN
eurjchem-1675	298	3	orbitals	orbital	NOUN
eurjchem-1675	298	4	can	can	AUX
eurjchem-1675	298	5	be	be	AUX
eurjchem-1675	298	6	considered	consider	VERB
eurjchem-1675	298	7	as	as	ADP
eurjchem-1675	298	8	an	an	DET
eurjchem-1675	298	9	electron	electron	NOUN
eurjchem-1675	298	10	donor	donor	NOUN
eurjchem-1675	298	11	group	group	NOUN
eurjchem-1675	298	12	,	,	PUNCT
eurjchem-1675	298	13	while	while	SCONJ
eurjchem-1675	298	14	the	the	DET
eurjchem-1675	298	15	lumo	lumo	NOUN
eurjchem-1675	298	16	orbitals	orbital	NOUN
eurjchem-1675	298	17	as	as	ADP
eurjchem-1675	298	18	free	free	ADJ
eurjchem-1675	298	19	sites	site	NOUN
eurjchem-1675	298	20	capable	capable	ADJ
eurjchem-1675	298	21	to	to	PART
eurjchem-1675	298	22	accept	accept	VERB
eurjchem-1675	298	23	them	they	PRON
eurjchem-1675	298	24	.	.	PUNCT
eurjchem-1675	299	1	due	due	ADP
eurjchem-1675	299	2	to	to	ADP
eurjchem-1675	299	3	the	the	DET
eurjchem-1675	299	4	interaction	interaction	NOUN
eurjchem-1675	299	5	between	between	ADP
eurjchem-1675	299	6	these	these	DET
eurjchem-1675	299	7	orbitals	orbital	NOUN
eurjchem-1675	299	8	,	,	PUNCT
eurjchem-1675	299	9	π	π	PROPN
eurjchem-1675	299	10	-	-	PUNCT
eurjchem-1675	299	11	π	π	PROPN
eurjchem-1675	299	12	*	*	NOUN
eurjchem-1675	299	13	transition	transition	NOUN
eurjchem-1675	299	14	,	,	PUNCT
eurjchem-1675	299	15	with	with	ADP
eurjchem-1675	299	16	respect	respect	NOUN
eurjchem-1675	299	17	to	to	ADP
eurjchem-1675	299	18	the	the	DET
eurjchem-1675	299	19	molecular	molecular	ADJ
eurjchem-1675	299	20	orbital	orbital	ADJ
eurjchem-1675	299	21	theory	theory	NOUN
eurjchem-1675	299	22	[	[	X
eurjchem-1675	299	23	33,34	33,34	NOUN
eurjchem-1675	299	24	]	]	X
eurjchem-1675	299	25	.	.	PUNCT
eurjchem-1675	300	1	energy	energy	NOUN
eurjchem-1675	300	2	of	of	ADP
eurjchem-1675	300	3	the	the	DET
eurjchem-1675	300	4	homo	homo	NOUN
eurjchem-1675	300	5	orbitals	orbital	NOUN
eurjchem-1675	300	6	can	can	AUX
eurjchem-1675	300	7	be	be	AUX
eurjchem-1675	300	8	directly	directly	ADV
eurjchem-1675	300	9	linked	link	VERB
eurjchem-1675	300	10	to	to	ADP
eurjchem-1675	300	11	the	the	DET
eurjchem-1675	300	12	ionization	ionization	NOUN
eurjchem-1675	300	13	potential	potential	NOUN
eurjchem-1675	300	14	,	,	PUNCT
eurjchem-1675	300	15	whereas	whereas	SCONJ
eurjchem-1675	300	16	the	the	DET
eurjchem-1675	300	17	lumo	lumo	ADJ
eurjchem-1675	300	18	orbital	orbital	ADJ
eurjchem-1675	300	19	energy	energy	NOUN
eurjchem-1675	300	20	can	can	AUX
eurjchem-1675	300	21	be	be	AUX
eurjchem-1675	300	22	associated	associate	VERB
eurjchem-1675	300	23	with	with	ADP
eurjchem-1675	300	24	the	the	DET
eurjchem-1675	300	25	electron	electron	NOUN
eurjchem-1675	300	26	affinity	affinity	NOUN
eurjchem-1675	300	27	.	.	PUNCT
eurjchem-1675	301	1	the	the	DET
eurjchem-1675	301	2	difference	difference	NOUN
eurjchem-1675	301	3	between	between	ADP
eurjchem-1675	301	4	the	the	DET
eurjchem-1675	301	5	orbital	orbital	ADJ
eurjchem-1675	301	6	energies	energy	NOUN
eurjchem-1675	301	7	of	of	ADP
eurjchem-1675	301	8	homo	homo	NOUN
eurjchem-1675	301	9	and	and	CCONJ
eurjchem-1675	301	10	lumo	lumo	NOUN
eurjchem-1675	301	11	is	be	AUX
eurjchem-1675	301	12	referred	refer	VERB
eurjchem-1675	301	13	to	to	ADP
eurjchem-1675	301	14	as	as	ADP
eurjchem-1675	301	15	energy	energy	NOUN
eurjchem-1675	301	16	gap	gap	NOUN
eurjchem-1675	301	17	,	,	PUNCT
eurjchem-1675	301	18	which	which	PRON
eurjchem-1675	301	19	is	be	AUX
eurjchem-1675	301	20	an	an	DET
eurjchem-1675	301	21	important	important	ADJ
eurjchem-1675	301	22	parameter	parameter	NOUN
eurjchem-1675	301	23	that	that	PRON
eurjchem-1675	301	24	can	can	AUX
eurjchem-1675	301	25	determine	determine	VERB
eurjchem-1675	301	26	the	the	DET
eurjchem-1675	301	27	reactivity	reactivity	NOUN
eurjchem-1675	301	28	or	or	CCONJ
eurjchem-1675	301	29	stability	stability	NOUN
eurjchem-1675	301	30	of	of	ADP
eurjchem-1675	301	31	molecules	molecule	NOUN
eurjchem-1675	301	32	.	.	PUNCT
eurjchem-1675	302	1	the	the	DET
eurjchem-1675	302	2	energy	energy	NOUN
eurjchem-1675	302	3	gap	gap	NOUN
eurjchem-1675	302	4	between	between	ADP
eurjchem-1675	302	5	homos	homos	PROPN
eurjchem-1675	302	6	and	and	CCONJ
eurjchem-1675	302	7	lumos	lumos	PROPN
eurjchem-1675	302	8	associated	associate	VERB
eurjchem-1675	302	9	to	to	ADP
eurjchem-1675	302	10	the	the	DET
eurjchem-1675	302	11	biological	biological	ADJ
eurjchem-1675	302	12	activity	activity	NOUN
eurjchem-1675	302	13	of	of	ADP
eurjchem-1675	302	14	the	the	DET
eurjchem-1675	302	15	molecule	molecule	NOUN
eurjchem-1675	302	16	[	[	X
eurjchem-1675	302	17	35	35	NUM
eurjchem-1675	302	18	]	]	PUNCT
eurjchem-1675	302	19	.	.	PUNCT
eurjchem-1675	303	1	moreover	moreover	ADV
eurjchem-1675	303	2	,	,	PUNCT
eurjchem-1675	303	3	it	it	PRON
eurjchem-1675	303	4	helps	help	VERB
eurjchem-1675	303	5	in	in	ADP
eurjchem-1675	303	6	characterizing	characterize	VERB
eurjchem-1675	303	7	the	the	DET
eurjchem-1675	303	8	chemical	chemical	NOUN
eurjchem-1675	303	9	reactivity	reactivity	NOUN
eurjchem-1675	303	10	and	and	CCONJ
eurjchem-1675	303	11	kinetic	kinetic	ADJ
eurjchem-1675	303	12	stability	stability	NOUN
eurjchem-1675	303	13	of	of	ADP
eurjchem-1675	303	14	the	the	DET
eurjchem-1675	303	15	molecule	molecule	NOUN
eurjchem-1675	303	16	.	.	PUNCT
eurjchem-1675	304	1	a	a	DET
eurjchem-1675	304	2	large	large	ADJ
eurjchem-1675	304	3	energy	energy	NOUN
eurjchem-1675	304	4	gap	gap	NOUN
eurjchem-1675	304	5	between	between	ADP
eurjchem-1675	304	6	homo	homo	NOUN
eurjchem-1675	304	7	-	-	PUNCT
eurjchem-1675	304	8	lumo	lumo	NOUN
eurjchem-1675	304	9	represents	represent	VERB
eurjchem-1675	304	10	the	the	DET
eurjchem-1675	304	11	high	high	ADJ
eurjchem-1675	304	12	kinetic	kinetic	ADJ
eurjchem-1675	304	13	stability	stability	NOUN
eurjchem-1675	304	14	[	[	X
eurjchem-1675	304	15	36	36	NUM
eurjchem-1675	304	16	]	]	PUNCT
eurjchem-1675	304	17	.	.	PUNCT
eurjchem-1675	305	1	figure	figure	VERB
eurjchem-1675	305	2	3	3	NUM
eurjchem-1675	305	3	indications	indication	NOUN
eurjchem-1675	305	4	that	that	SCONJ
eurjchem-1675	305	5	the	the	DET
eurjchem-1675	305	6	distributions	distribution	NOUN
eurjchem-1675	305	7	and	and	CCONJ
eurjchem-1675	305	8	energy	energy	NOUN
eurjchem-1675	305	9	levels	level	NOUN
eurjchem-1675	305	10	of	of	ADP
eurjchem-1675	305	11	the	the	DET
eurjchem-1675	305	12	optimized	optimize	VERB
eurjchem-1675	305	13	compound	compound	NOUN
eurjchem-1675	305	14	6	6	NUM
eurjchem-1675	305	15	exhausting	exhausting	ADJ
eurjchem-1675	305	16	dft	dft	NOUN
eurjchem-1675	305	17	(	(	PUNCT
eurjchem-1675	305	18	b3lyp/6	b3lyp/6	PROPN
eurjchem-1675	305	19	-	-	PROPN
eurjchem-1675	305	20	31	31	NUM
eurjchem-1675	305	21	g	g	NOUN
eurjchem-1675	305	22	(	(	PUNCT
eurjchem-1675	305	23	d	d	NOUN
eurjchem-1675	305	24	)	)	PUNCT
eurjchem-1675	305	25	)	)	PUNCT
eurjchem-1675	305	26	and	and	CCONJ
eurjchem-1675	305	27	hf/6	hf/6	NOUN
eurjchem-1675	305	28	-	-	PUNCT
eurjchem-1675	305	29	31g(d	31g(d	NUM
eurjchem-1675	305	30	)	)	PUNCT
eurjchem-1675	305	31	possesses	possess	VERB
eurjchem-1675	305	32	a	a	DET
eurjchem-1675	305	33	dipole	dipole	NOUN
eurjchem-1675	305	34	moment	moment	NOUN
eurjchem-1675	305	35	(	(	PUNCT
eurjchem-1675	305	36	5.6949	5.6949	NUM
eurjchem-1675	305	37	d	d	NOUN
eurjchem-1675	305	38	)	)	PUNCT
eurjchem-1675	305	39	and	and	CCONJ
eurjchem-1675	305	40	(	(	PUNCT
eurjchem-1675	305	41	6.3747	6.3747	NUM
eurjchem-1675	305	42	d	d	NOUN
eurjchem-1675	305	43	)	)	PUNCT
eurjchem-1675	305	44	,	,	PUNCT
eurjchem-1675	305	45	respectively	respectively	ADV
eurjchem-1675	305	46	,	,	PUNCT
eurjchem-1675	305	47	and	and	CCONJ
eurjchem-1675	305	48	homo	homo	NOUN
eurjchem-1675	305	49	and	and	CCONJ
eurjchem-1675	305	50	lumo	lumo	NOUN
eurjchem-1675	305	51	energy	energy	NOUN
eurjchem-1675	305	52	gap	gap	NOUN
eurjchem-1675	305	53	of	of	ADP
eurjchem-1675	305	54	2.4161	2.4161	NUM
eurjchem-1675	305	55	ev	ev	NOUN
eurjchem-1675	305	56	and	and	CCONJ
eurjchem-1675	305	57	2.5323	2.5323	NUM
eurjchem-1675	305	58	ev	ev	X
eurjchem-1675	305	59	which	which	PRON
eurjchem-1675	305	60	designates	designate	VERB
eurjchem-1675	305	61	its	its	PRON
eurjchem-1675	305	62	extraordinary	extraordinary	ADJ
eurjchem-1675	305	63	reactivity	reactivity	NOUN
eurjchem-1675	305	64	to	to	PART
eurjchem-1675	305	65	cooperate	cooperate	VERB
eurjchem-1675	305	66	with	with	ADP
eurjchem-1675	305	67	the	the	DET
eurjchem-1675	305	68	surrounding	surround	VERB
eurjchem-1675	305	69	media	medium	NOUN
eurjchem-1675	305	70	,	,	PUNCT
eurjchem-1675	305	71	and	and	CCONJ
eurjchem-1675	305	72	worthy	worthy	ADJ
eurjchem-1675	305	73	permanence	permanence	NOUN
eurjchem-1675	305	74	for	for	ADP
eurjchem-1675	305	75	this	this	DET
eurjchem-1675	305	76	compound	compound	NOUN
eurjchem-1675	305	77	.	.	PUNCT
eurjchem-1675	306	1	4	4	X
eurjchem-1675	306	2	.	.	X
eurjchem-1675	306	3	conclusion	conclusion	NOUN
eurjchem-1675	306	4	herein	herein	NOUN
eurjchem-1675	306	5	,	,	PUNCT
eurjchem-1675	306	6	we	we	PRON
eurjchem-1675	306	7	report	report	VERB
eurjchem-1675	306	8	the	the	DET
eurjchem-1675	306	9	synthesis	synthesis	NOUN
eurjchem-1675	306	10	of	of	ADP
eurjchem-1675	306	11	a	a	DET
eurjchem-1675	306	12	variety	variety	NOUN
eurjchem-1675	306	13	of	of	ADP
eurjchem-1675	306	14	fused	fuse	VERB
eurjchem-1675	306	15	heterocyclic	heterocyclic	ADJ
eurjchem-1675	306	16	systems	system	NOUN
eurjchem-1675	306	17	,	,	PUNCT
eurjchem-1675	306	18	consolidating	consolidate	VERB
eurjchem-1675	306	19	cyclohexyl	cyclohexyl	PROPN
eurjchem-1675	306	20	moiety	moiety	NOUN
eurjchem-1675	306	21	via	via	ADP
eurjchem-1675	306	22	the	the	DET
eurjchem-1675	306	23	reaction	reaction	NOUN
eurjchem-1675	306	24	of	of	ADP
eurjchem-1675	306	25	2	2	NUM
eurjchem-1675	306	26	-	-	PUNCT
eurjchem-1675	306	27	cyano	cyano	NOUN
eurjchem-1675	306	28	-	-	PUNCT
eurjchem-1675	306	29	n	n	CCONJ
eurjchem-1675	306	30	-	-	PUNCT
eurjchem-1675	306	31	cyclohexylacetamide	cyclohexylacetamide	NOUN
eurjchem-1675	306	32	with	with	ADP
eurjchem-1675	306	33	phenyl	phenyl	NOUN
eurjchem-1675	306	34	isothiocyanate	isothiocyanate	NOUN
eurjchem-1675	306	35	to	to	PART
eurjchem-1675	306	36	afford	afford	VERB
eurjchem-1675	306	37	the	the	DET
eurjchem-1675	306	38	corresponding	corresponding	ADJ
eurjchem-1675	306	39	fused	fuse	VERB
eurjchem-1675	306	40	heterocycles	heterocycle	NOUN
eurjchem-1675	306	41	utilizing	utilize	VERB
eurjchem-1675	306	42	conventional	conventional	ADJ
eurjchem-1675	306	43	procedures	procedure	NOUN
eurjchem-1675	306	44	and	and	CCONJ
eurjchem-1675	306	45	microwave	microwave	NOUN
eurjchem-1675	306	46	irradiation	irradiation	NOUN
eurjchem-1675	306	47	techniques	technique	NOUN
eurjchem-1675	306	48	.	.	PUNCT
eurjchem-1675	307	1	optimized	optimize	VERB
eurjchem-1675	307	2	molecular	molecular	ADJ
eurjchem-1675	307	3	structure	structure	NOUN
eurjchem-1675	307	4	,	,	PUNCT
eurjchem-1675	307	5	bond	bond	NOUN
eurjchem-1675	307	6	distance	distance	NOUN
eurjchem-1675	307	7	,	,	PUNCT
eurjchem-1675	307	8	bond	bond	NOUN
eurjchem-1675	307	9	angles	angle	NOUN
eurjchem-1675	307	10	and	and	CCONJ
eurjchem-1675	307	11	difference	difference	NOUN
eurjchem-1675	307	12	of	of	ADP
eurjchem-1675	307	13	energy	energy	NOUN
eurjchem-1675	307	14	(	(	PUNCT
eurjchem-1675	307	15	homo	homo	NOUN
eurjchem-1675	307	16	-	-	PUNCT
eurjchem-1675	307	17	lumo	lumo	NOUN
eurjchem-1675	307	18	)	)	PUNCT
eurjchem-1675	307	19	have	have	AUX
eurjchem-1675	307	20	been	be	AUX
eurjchem-1675	307	21	investigated	investigate	VERB
eurjchem-1675	307	22	by	by	ADP
eurjchem-1675	307	23	dft	dft	PROPN
eurjchem-1675	307	24	/	/	SYM
eurjchem-1675	307	25	b3lyp	b3lyp	PROPN
eurjchem-1675	307	26	and	and	CCONJ
eurjchem-1675	307	27	hf	hf	NOUN
eurjchem-1675	307	28	approaches	approach	NOUN
eurjchem-1675	307	29	combined	combine	VERB
eurjchem-1675	307	30	with	with	ADP
eurjchem-1675	307	31	6	6	NUM
eurjchem-1675	307	32	-	-	SYM
eurjchem-1675	307	33	31g(d	31g(d	NUM
eurjchem-1675	307	34	)	)	PUNCT
eurjchem-1675	307	35	basis	basis	NOUN
eurjchem-1675	307	36	set	set	NOUN
eurjchem-1675	307	37	.	.	PUNCT
eurjchem-1675	308	1	comprehensive	comprehensive	ADJ
eurjchem-1675	308	2	theoretical	theoretical	ADJ
eurjchem-1675	308	3	and	and	CCONJ
eurjchem-1675	308	4	experimental	experimental	ADJ
eurjchem-1675	308	5	structural	structural	ADJ
eurjchem-1675	308	6	studies	study	NOUN
eurjchem-1675	308	7	pyrazole	pyrazole	NOUN
eurjchem-1675	308	8	ethyl	ethyl	PROPN
eurjchem-1675	308	9	4-(cyclo	4-(cyclo	VERB
eurjchem-1675	308	10	hexylcarbamoyl)-5	hexylcarbamoyl)-5	PROPN
eurjchem-1675	308	11	-	-	PUNCT
eurjchem-1675	308	12	amino-1-(4	amino-1-(4	NOUN
eurjchem-1675	308	13	-	-	PUNCT
eurjchem-1675	308	14	methoxyphenyl)-1h	methoxyphenyl)-1h	NOUN
eurjchem-1675	308	15	-	-	PUNCT
eurjchem-1675	308	16	pyrazole3	pyrazole3	NOUN
eurjchem-1675	308	17	-	-	PUNCT
eurjchem-1675	308	18	carboxylate	carboxylate	NOUN
eurjchem-1675	308	19	have	have	AUX
eurjchem-1675	308	20	been	be	AUX
eurjchem-1675	308	21	carried	carry	VERB
eurjchem-1675	308	22	out	out	ADP
eurjchem-1675	308	23	by	by	ADP
eurjchem-1675	308	24	elemental	elemental	ADJ
eurjchem-1675	308	25	analysis	analysis	NOUN
eurjchem-1675	308	26	,	,	PUNCT
eurjchem-1675	308	27	ftir	ftir	PROPN
eurjchem-1675	308	28	,	,	PUNCT
eurjchem-1675	308	29	1h	1h	NUM
eurjchem-1675	308	30	nmr	nmr	NOUN
eurjchem-1675	308	31	,	,	PUNCT
eurjchem-1675	308	32	and	and	CCONJ
eurjchem-1675	308	33	mass	mass	NOUN
eurjchem-1675	308	34	spectroscopy	spectroscopy	NOUN
eurjchem-1675	308	35	.	.	PUNCT
eurjchem-1675	309	1	acknowledgement	acknowledgement	NOUN
eurjchem-1675	309	2	the	the	DET
eurjchem-1675	309	3	author	author	NOUN
eurjchem-1675	309	4	acknowledges	acknowledge	VERB
eurjchem-1675	309	5	the	the	DET
eurjchem-1675	309	6	support	support	NOUN
eurjchem-1675	309	7	of	of	ADP
eurjchem-1675	309	8	this	this	DET
eurjchem-1675	309	9	research	research	NOUN
eurjchem-1675	309	10	to	to	ADP
eurjchem-1675	309	11	the	the	DET
eurjchem-1675	309	12	green	green	ADJ
eurjchem-1675	309	13	chemistry	chemistry	PROPN
eurjchem-1675	309	14	department	department	PROPN
eurjchem-1675	309	15	in	in	ADP
eurjchem-1675	309	16	national	national	PROPN
eurjchem-1675	309	17	research	research	PROPN
eurjchem-1675	309	18	centre	centre	PROPN
eurjchem-1675	309	19	egypt	egypt	PROPN
eurjchem-1675	309	20	and	and	CCONJ
eurjchem-1675	309	21	department	department	PROPN
eurjchem-1675	309	22	of	of	ADP
eurjchem-1675	309	23	chemistry	chemistry	NOUN
eurjchem-1675	309	24	,	,	PUNCT
eurjchem-1675	309	25	cairo	cairo	PROPN
eurjchem-1675	309	26	university	university	PROPN
eurjchem-1675	309	27	.	.	PUNCT
eurjchem-1675	310	1	disclosure	disclosure	NOUN
eurjchem-1675	310	2	statement	statement	NOUN
eurjchem-1675	310	3	conflict	conflict	NOUN
eurjchem-1675	310	4	of	of	ADP
eurjchem-1675	310	5	interests	interest	NOUN
eurjchem-1675	310	6	:	:	PUNCT
eurjchem-1675	310	7	the	the	DET
eurjchem-1675	310	8	authors	author	NOUN
eurjchem-1675	310	9	declare	declare	VERB
eurjchem-1675	310	10	that	that	SCONJ
eurjchem-1675	310	11	they	they	PRON
eurjchem-1675	310	12	have	have	VERB
eurjchem-1675	310	13	no	no	DET
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eurjchem-1675	311	11	.	.	PUNCT
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eurjchem-1675	312	3	:	:	PUNCT
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eurjchem-1675	313	2	ethical	ethical	ADJ
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eurjchem-1675	314	13	.	.	PUNCT
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eurjchem-1675	315	17	1	1	NUM
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eurjchem-1675	316	5	;	;	PUNCT
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eurjchem-1675	316	7	,	,	PUNCT
eurjchem-1675	316	8	y.	y.	PROPN
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eurjchem-1675	316	10	;	;	PUNCT
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eurjchem-1675	316	12	,	,	PUNCT
eurjchem-1675	316	13	m.	m.	NOUN
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eurjchem-1675	317	1	[	[	X
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eurjchem-1675	317	3	]	]	PUNCT
eurjchem-1675	317	4	.	.	PUNCT
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eurjchem-1675	318	5	;	;	PUNCT
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eurjchem-1675	320	4	,	,	PUNCT
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eurjchem-1675	320	8	.	.	PUNCT
eurjchem-1675	321	1	[	[	X
eurjchem-1675	321	2	3	3	NUM
eurjchem-1675	321	3	]	]	PUNCT
eurjchem-1675	321	4	.	.	PUNCT
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eurjchem-1675	322	2	.	.	PUNCT
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eurjchem-1675	324	4	.	.	PUNCT
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eurjchem-1675	325	5	;	;	PUNCT
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eurjchem-1675	327	6	-	-	SYM
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eurjchem-1675	328	4	.	.	PUNCT
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eurjchem-1675	331	2	,	,	PUNCT
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eurjchem-1675	336	9	;	;	PUNCT
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eurjchem-1675	337	1	j.	j.	PROPN
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eurjchem-1675	339	4	.	.	PUNCT
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eurjchem-1675	371	7	,	,	PUNCT
eurjchem-1675	371	8	d.	d.	PROPN
eurjchem-1675	371	9	;	;	PUNCT
eurjchem-1675	371	10	joe	joe	PROPN
eurjchem-1675	371	11	,	,	PUNCT
eurjchem-1675	371	12	i.	i.	PROPN
eurjchem-1675	371	13	h.	h.	PROPN
eurjchem-1675	371	14	;	;	PUNCT
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eurjchem-1675	371	17	s.	s.	PROPN
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eurjchem-1675	371	24	.	.	PUNCT
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eurjchem-1675	372	4	,	,	PUNCT
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eurjchem-1675	372	6	,	,	PUNCT
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eurjchem-1675	373	1	[	[	X
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eurjchem-1675	373	3	]	]	PUNCT
eurjchem-1675	373	4	.	.	PUNCT
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eurjchem-1675	374	3	n.	n.	PROPN
eurjchem-1675	374	4	f.	f.	PROPN
eurjchem-1675	374	5	;	;	PUNCT
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eurjchem-1675	374	7	,	,	PUNCT
eurjchem-1675	374	8	a.	a.	PROPN
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eurjchem-1675	374	10	heterocycl	heterocycl	PROPN
eurjchem-1675	374	11	.	.	PUNCT
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eurjchem-1675	375	2	,	,	PUNCT
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eurjchem-1675	375	4	,	,	PUNCT
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eurjchem-1675	375	6	-	-	SYM
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eurjchem-1675	375	8	.	.	PUNCT
eurjchem-1675	376	1	[	[	X
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eurjchem-1675	376	3	]	]	PUNCT
eurjchem-1675	376	4	.	.	PUNCT
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eurjchem-1675	378	2	.	.	PUNCT
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eurjchem-1675	378	4	,	,	PUNCT
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eurjchem-1675	378	6	,	,	PUNCT
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eurjchem-1675	378	8	-	-	SYM
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eurjchem-1675	379	1	[	[	X
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eurjchem-1675	379	4	.	.	PUNCT
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eurjchem-1675	380	1	j.	j.	PROPN
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eurjchem-1675	381	2	,	,	PUNCT
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eurjchem-1675	381	6	-	-	SYM
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eurjchem-1675	381	8	.	.	PUNCT
eurjchem-1675	382	1	[	[	X
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eurjchem-1675	382	3	]	]	PUNCT
eurjchem-1675	382	4	.	.	PUNCT
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eurjchem-1675	383	2	,	,	PUNCT
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eurjchem-1675	383	5	;	;	PUNCT
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eurjchem-1675	383	7	,	,	PUNCT
eurjchem-1675	383	8	r.	r.	PROPN
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eurjchem-1675	383	14	,	,	PUNCT
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eurjchem-1675	383	16	,	,	PUNCT
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eurjchem-1675	383	18	-	-	SYM
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eurjchem-1675	383	20	.	.	PUNCT
eurjchem-1675	384	1	[	[	X
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eurjchem-1675	384	3	]	]	PUNCT
eurjchem-1675	384	4	.	.	PUNCT
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eurjchem-1675	386	4	.	.	PUNCT
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eurjchem-1675	387	5	;	;	PUNCT
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eurjchem-1675	387	7	,	,	PUNCT
eurjchem-1675	387	8	c.	c.	PROPN
eurjchem-1675	387	9	;	;	PUNCT
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eurjchem-1675	387	19	.	.	PUNCT
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eurjchem-1675	389	4	.	.	PUNCT
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eurjchem-1675	390	18	.	.	PUNCT
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eurjchem-1675	391	2	.	.	PUNCT
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eurjchem-1675	392	2	.	.	PUNCT
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eurjchem-1675	393	2	,	,	PUNCT
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eurjchem-1675	393	6	.	.	PUNCT
eurjchem-1675	394	1	[	[	X
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eurjchem-1675	394	3	]	]	PUNCT
eurjchem-1675	394	4	.	.	PUNCT
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eurjchem-1675	395	7	.	.	PUNCT
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eurjchem-1675	396	2	.	.	PUNCT
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eurjchem-1675	397	2	,	,	PUNCT
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eurjchem-1675	397	6	-	-	SYM
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eurjchem-1675	398	1	[	[	X
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eurjchem-1675	398	4	.	.	PUNCT
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eurjchem-1675	399	4	;	;	PUNCT
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eurjchem-1675	399	6	,	,	PUNCT
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eurjchem-1675	399	8	;	;	PUNCT
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eurjchem-1675	399	10	,	,	PUNCT
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eurjchem-1675	400	2	.	.	PUNCT
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eurjchem-1675	401	2	.	.	PUNCT
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eurjchem-1675	402	2	,	,	PUNCT
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eurjchem-1675	402	4	,	,	PUNCT
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eurjchem-1675	402	6	-	-	SYM
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eurjchem-1675	402	8	.	.	PUNCT
eurjchem-1675	403	1	[	[	X
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eurjchem-1675	403	3	]	]	PUNCT
eurjchem-1675	403	4	.	.	PUNCT
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eurjchem-1675	405	3	]	]	PUNCT
eurjchem-1675	405	4	.	.	PUNCT
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eurjchem-1675	407	2	.	.	PUNCT
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eurjchem-1675	408	7	-	-	SYM
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eurjchem-1675	408	9	.	.	PUNCT
eurjchem-1675	409	1	[	[	X
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eurjchem-1675	409	4	.	.	PUNCT
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eurjchem-1675	411	2	.	.	PUNCT
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eurjchem-1675	412	6	-	-	SYM
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eurjchem-1675	412	8	.	.	PUNCT
eurjchem-1675	413	1	[	[	X
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eurjchem-1675	413	3	]	]	PUNCT
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eurjchem-1675	413	9	;	;	PUNCT
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eurjchem-1675	413	19	;	;	PUNCT
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eurjchem-1675	413	42	;	;	PUNCT
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eurjchem-1675	413	66	h.	h.	PROPN
eurjchem-1675	413	67	p.	p.	PROPN
eurjchem-1675	413	68	;	;	PUNCT
eurjchem-1675	413	69	izmaylov	izmaylov	ADV
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eurjchem-1675	413	71	a.	a.	PROPN
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eurjchem-1675	413	73	;	;	PUNCT
eurjchem-1675	413	74	bloino	bloino	PROPN
eurjchem-1675	413	75	,	,	PUNCT
eurjchem-1675	413	76	j.	j.	PROPN
eurjchem-1675	413	77	;	;	PUNCT
eurjchem-1675	413	78	zheng	zheng	PROPN
eurjchem-1675	413	79	,	,	PUNCT
eurjchem-1675	413	80	g.	g.	PROPN
eurjchem-1675	413	81	;	;	PUNCT
eurjchem-1675	413	82	sonnenberg	sonnenberg	PROPN
eurjchem-1675	413	83	,	,	PUNCT
eurjchem-1675	413	84	j.	j.	PROPN
eurjchem-1675	413	85	l.	l.	PROPN
eurjchem-1675	413	86	;	;	PUNCT
eurjchem-1675	413	87	hada	hada	PROPN
eurjchem-1675	413	88	,	,	PUNCT
eurjchem-1675	413	89	m.	m.	NOUN
eurjchem-1675	413	90	;	;	PUNCT
eurjchem-1675	413	91	ehara	ehara	PROPN
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eurjchem-1675	413	93	m.	m.	NOUN
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eurjchem-1675	413	95	toyota	toyota	PROPN
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eurjchem-1675	413	97	k.	k.	PROPN
eurjchem-1675	413	98	;	;	PUNCT
eurjchem-1675	413	99	fukuda	fukuda	PROPN
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eurjchem-1675	413	101	r.	r.	PROPN
eurjchem-1675	413	102	;	;	PUNCT
eurjchem-1675	413	103	hasegawa	hasegawa	PROPN
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eurjchem-1675	413	107	ishida	ishida	PROPN
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eurjchem-1675	413	117	y.	y.	PROPN
eurjchem-1675	413	118	;	;	PUNCT
eurjchem-1675	413	119	kitao	kitao	PROPN
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eurjchem-1675	413	121	o.	o.	PROPN
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eurjchem-1675	413	125	h.	h.	PROPN
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eurjchem-1675	413	130	;	;	PUNCT
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eurjchem-1675	413	135	;	;	PUNCT
eurjchem-1675	413	136	peralta	peralta	PROPN
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eurjchem-1675	413	138	j.	j.	PROPN
eurjchem-1675	413	139	e.	e.	PROPN
eurjchem-1675	413	140	;	;	PUNCT
eurjchem-1675	413	141	ogliaro	ogliaro	PROPN
eurjchem-1675	413	142	,	,	PUNCT
eurjchem-1675	413	143	f.	f.	PROPN
eurjchem-1675	413	144	;	;	PUNCT
eurjchem-1675	413	145	bearpark	bearpark	PROPN
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eurjchem-1675	413	147	m.	m.	NOUN
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eurjchem-1675	413	149	heyd	heyd	PROPN
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eurjchem-1675	413	151	j.	j.	PROPN
eurjchem-1675	413	152	j.	j.	PROPN
eurjchem-1675	413	153	;	;	PUNCT
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eurjchem-1675	413	155	,	,	PUNCT
eurjchem-1675	413	156	e.	e.	PROPN
eurjchem-1675	413	157	;	;	PUNCT
eurjchem-1675	413	158	kudin	kudin	PROPN
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eurjchem-1675	413	160	k.	k.	PROPN
eurjchem-1675	413	161	n.	n.	PROPN
eurjchem-1675	413	162	;	;	PUNCT
eurjchem-1675	413	163	staroverov	staroverov	X
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eurjchem-1675	413	165	v.	v.	ADP
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eurjchem-1675	413	167	;	;	PUNCT
eurjchem-1675	413	168	kobayashi	kobayashi	PROPN
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eurjchem-1675	413	170	r.	r.	PROPN
eurjchem-1675	413	171	;	;	PUNCT
eurjchem-1675	413	172	normand	normand	PROPN
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eurjchem-1675	413	174	j.	j.	PROPN
eurjchem-1675	413	175	;	;	PUNCT
eurjchem-1675	413	176	raghavachari	raghavachari	PROPN
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eurjchem-1675	413	178	k.	k.	PROPN
eurjchem-1675	413	179	;	;	PUNCT
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eurjchem-1675	413	186	j.	j.	PROPN
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eurjchem-1675	413	188	;	;	PUNCT
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eurjchem-1675	413	191	s.	s.	PROPN
eurjchem-1675	413	192	s.	s.	PROPN
eurjchem-1675	413	193	;	;	PUNCT
eurjchem-1675	413	194	tomasi	tomasi	PROPN
eurjchem-1675	413	195	,	,	PUNCT
eurjchem-1675	413	196	j.	j.	PROPN
eurjchem-1675	413	197	;	;	PUNCT
eurjchem-1675	413	198	cossi	cossi	PROPN
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eurjchem-1675	413	208	j.	j.	PROPN
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eurjchem-1675	413	213	m.	m.	NOUN
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eurjchem-1675	413	219	;	;	PUNCT
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eurjchem-1675	413	224	;	;	PUNCT
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eurjchem-1675	413	227	v.	v.	PROPN
eurjchem-1675	413	228	;	;	PUNCT
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eurjchem-1675	413	231	c.	c.	PROPN
eurjchem-1675	413	232	;	;	PUNCT
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eurjchem-1675	413	243	r.	r.	PROPN
eurjchem-1675	413	244	e.	e.	PROPN
eurjchem-1675	413	245	;	;	PUNCT
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eurjchem-1675	413	247	,	,	PUNCT
eurjchem-1675	413	248	o.	o.	PROPN
eurjchem-1675	413	249	;	;	PUNCT
eurjchem-1675	413	250	austin	austin	PROPN
eurjchem-1675	413	251	,	,	PUNCT
eurjchem-1675	413	252	a.	a.	PROPN
eurjchem-1675	413	253	j.	j.	PROPN
eurjchem-1675	413	254	;	;	PUNCT
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eurjchem-1675	413	265	j.	j.	PROPN
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eurjchem-1675	413	267	;	;	PUNCT
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eurjchem-1675	413	284	g.	g.	PROPN
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eurjchem-1675	428	1	acta	acta	PROPN
eurjchem-1675	428	2	a	a	DET
eurjchem-1675	428	3	2010	2010	NUM
eurjchem-1675	428	4	,	,	PUNCT
eurjchem-1675	428	5	75(4	75(4	NOUN
eurjchem-1675	428	6	)	)	PUNCT
eurjchem-1675	428	7	,	,	PUNCT
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eurjchem-1675	430	3	s.	s.	PROPN
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eurjchem-1675	430	7	k.	k.	PROPN
eurjchem-1675	430	8	k.	k.	PROPN
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eurjchem-1675	430	12	l.	l.	PROPN
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eurjchem-1675	430	18	j.	j.	PROPN
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eurjchem-1675	430	20	.	.	PUNCT
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eurjchem-1675	431	2	.	.	PROPN
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eurjchem-1675	431	4	,	,	PUNCT
eurjchem-1675	431	5	76(4	76(4	NUM
eurjchem-1675	431	6	)	)	PUNCT
eurjchem-1675	431	7	,	,	PUNCT
eurjchem-1675	431	8	287	287	NUM
eurjchem-1675	431	9	-	-	SYM
eurjchem-1675	431	10	298	298	NUM
eurjchem-1675	431	11	.	.	PUNCT
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eurjchem-1675	432	2	©	©	PROPN
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eurjchem-1675	432	4	by	by	ADP
eurjchem-1675	432	5	authors	author	NOUN
eurjchem-1675	432	6	.	.	PUNCT
eurjchem-1675	433	1	this	this	DET
eurjchem-1675	433	2	work	work	NOUN
eurjchem-1675	433	3	is	be	AUX
eurjchem-1675	433	4	published	publish	VERB
eurjchem-1675	433	5	and	and	CCONJ
eurjchem-1675	433	6	licensed	license	VERB
eurjchem-1675	433	7	by	by	ADP
eurjchem-1675	433	8	atlanta	atlanta	PROPN
eurjchem-1675	433	9	publishing	publishing	PROPN
eurjchem-1675	433	10	house	house	PROPN
eurjchem-1675	433	11	llc	llc	PROPN
eurjchem-1675	433	12	,	,	PUNCT
eurjchem-1675	433	13	atlanta	atlanta	PROPN
eurjchem-1675	433	14	,	,	PUNCT
eurjchem-1675	433	15	ga	ga	PROPN
eurjchem-1675	433	16	,	,	PUNCT
eurjchem-1675	433	17	usa	usa	PROPN
eurjchem-1675	433	18	.	.	PUNCT
eurjchem-1675	434	1	the	the	DET
eurjchem-1675	434	2	full	full	ADJ
eurjchem-1675	434	3	terms	term	NOUN
eurjchem-1675	434	4	of	of	ADP
eurjchem-1675	434	5	this	this	DET
eurjchem-1675	434	6	license	license	NOUN
eurjchem-1675	434	7	are	be	AUX
eurjchem-1675	434	8	available	available	ADJ
eurjchem-1675	434	9	at	at	ADP
eurjchem-1675	434	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1675	434	11	and	and	CCONJ
eurjchem-1675	434	12	incorporate	incorporate	VERB
eurjchem-1675	434	13	the	the	DET
eurjchem-1675	434	14	creative	creative	ADJ
eurjchem-1675	434	15	commons	common	NOUN
eurjchem-1675	434	16	attribution	attribution	NOUN
eurjchem-1675	434	17	-	-	PUNCT
eurjchem-1675	434	18	non	non	ADJ
eurjchem-1675	434	19	commercial	commercial	NOUN
eurjchem-1675	434	20	(	(	PUNCT
eurjchem-1675	434	21	cc	cc	NOUN
eurjchem-1675	434	22	by	by	ADP
eurjchem-1675	434	23	nc	nc	PROPN
eurjchem-1675	434	24	)	)	PUNCT
eurjchem-1675	434	25	(	(	PUNCT
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eurjchem-1675	434	27	,	,	PUNCT
eurjchem-1675	434	28	v4.0	v4.0	NOUN
eurjchem-1675	434	29	)	)	PUNCT
eurjchem-1675	434	30	license	license	NOUN
eurjchem-1675	434	31	(	(	PUNCT
eurjchem-1675	434	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-1675	434	33	)	)	PUNCT
eurjchem-1675	434	34	.	.	PUNCT
eurjchem-1675	435	1	by	by	ADP
eurjchem-1675	435	2	accessing	access	VERB
eurjchem-1675	435	3	the	the	DET
eurjchem-1675	435	4	work	work	NOUN
eurjchem-1675	435	5	,	,	PUNCT
eurjchem-1675	435	6	you	you	PRON
eurjchem-1675	435	7	hereby	hereby	ADV
eurjchem-1675	435	8	accept	accept	VERB
eurjchem-1675	435	9	the	the	DET
eurjchem-1675	435	10	terms	term	NOUN
eurjchem-1675	435	11	.	.	PUNCT
eurjchem-1675	436	1	this	this	PRON
eurjchem-1675	436	2	is	be	AUX
eurjchem-1675	436	3	an	an	DET
eurjchem-1675	436	4	open	open	ADJ
eurjchem-1675	436	5	access	access	NOUN
eurjchem-1675	436	6	article	article	NOUN
eurjchem-1675	436	7	distributed	distribute	VERB
eurjchem-1675	436	8	under	under	ADP
eurjchem-1675	436	9	the	the	DET
eurjchem-1675	436	10	terms	term	NOUN
eurjchem-1675	436	11	and	and	CCONJ
eurjchem-1675	436	12	conditions	condition	NOUN
eurjchem-1675	436	13	of	of	ADP
eurjchem-1675	436	14	the	the	DET
eurjchem-1675	436	15	cc	cc	PROPN
eurjchem-1675	436	16	by	by	ADP
eurjchem-1675	436	17	nc	nc	PROPN
eurjchem-1675	436	18	license	license	PROPN
eurjchem-1675	436	19	,	,	PUNCT
eurjchem-1675	436	20	which	which	PRON
eurjchem-1675	436	21	permits	permit	VERB
eurjchem-1675	436	22	unrestricted	unrestricted	ADJ
eurjchem-1675	436	23	non	non	ADJ
eurjchem-1675	436	24	-	-	ADJ
eurjchem-1675	436	25	commercial	commercial	ADJ
eurjchem-1675	436	26	use	use	NOUN
eurjchem-1675	436	27	,	,	PUNCT
eurjchem-1675	436	28	distribution	distribution	NOUN
eurjchem-1675	436	29	,	,	PUNCT
eurjchem-1675	436	30	and	and	CCONJ
eurjchem-1675	436	31	reproduction	reproduction	NOUN
eurjchem-1675	436	32	in	in	ADP
eurjchem-1675	436	33	any	any	DET
eurjchem-1675	436	34	medium	medium	NOUN
eurjchem-1675	436	35	,	,	PUNCT
eurjchem-1675	436	36	provided	provide	VERB
eurjchem-1675	436	37	the	the	DET
eurjchem-1675	436	38	original	original	ADJ
eurjchem-1675	436	39	work	work	NOUN
eurjchem-1675	436	40	is	be	AUX
eurjchem-1675	436	41	properly	properly	ADV
eurjchem-1675	436	42	cited	cite	VERB
eurjchem-1675	436	43	without	without	ADP
eurjchem-1675	436	44	any	any	DET
eurjchem-1675	436	45	further	further	ADJ
eurjchem-1675	436	46	permission	permission	NOUN
eurjchem-1675	436	47	from	from	ADP
eurjchem-1675	436	48	atlanta	atlanta	PROPN
eurjchem-1675	436	49	publishing	publishing	PROPN
eurjchem-1675	436	50	house	house	PROPN
eurjchem-1675	436	51	llc	llc	PROPN
eurjchem-1675	436	52	(	(	PUNCT
eurjchem-1675	436	53	european	european	PROPN
eurjchem-1675	436	54	journal	journal	PROPN
eurjchem-1675	436	55	of	of	ADP
eurjchem-1675	436	56	chemistry	chemistry	NOUN
eurjchem-1675	436	57	)	)	PUNCT
eurjchem-1675	436	58	.	.	PUNCT
eurjchem-1675	437	1	no	no	DET
eurjchem-1675	437	2	use	use	NOUN
eurjchem-1675	437	3	,	,	PUNCT
eurjchem-1675	437	4	distribution	distribution	NOUN
eurjchem-1675	437	5	or	or	CCONJ
eurjchem-1675	437	6	reproduction	reproduction	NOUN
eurjchem-1675	437	7	is	be	AUX
eurjchem-1675	437	8	permitted	permit	VERB
eurjchem-1675	437	9	which	which	PRON
eurjchem-1675	437	10	does	do	AUX
eurjchem-1675	437	11	not	not	PART
eurjchem-1675	437	12	comply	comply	VERB
eurjchem-1675	437	13	with	with	ADP
eurjchem-1675	437	14	these	these	DET
eurjchem-1675	437	15	terms	term	NOUN
eurjchem-1675	437	16	.	.	PUNCT
eurjchem-1675	438	1	permissions	permission	NOUN
eurjchem-1675	438	2	for	for	ADP
eurjchem-1675	438	3	commercial	commercial	ADJ
eurjchem-1675	438	4	use	use	NOUN
eurjchem-1675	438	5	of	of	ADP
eurjchem-1675	438	6	this	this	DET
eurjchem-1675	438	7	work	work	NOUN
eurjchem-1675	438	8	beyond	beyond	ADP
eurjchem-1675	438	9	the	the	DET
eurjchem-1675	438	10	scope	scope	NOUN
eurjchem-1675	438	11	of	of	ADP
eurjchem-1675	438	12	the	the	DET
eurjchem-1675	438	13	license	license	NOUN
eurjchem-1675	438	14	(	(	PUNCT
eurjchem-1675	438	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1675	438	16	)	)	PUNCT
eurjchem-1675	438	17	are	be	AUX
eurjchem-1675	438	18	administered	administer	VERB
eurjchem-1675	438	19	by	by	ADP
eurjchem-1675	438	20	atlanta	atlanta	PROPN
eurjchem-1675	438	21	publishing	publishing	PROPN
eurjchem-1675	438	22	house	house	PROPN
eurjchem-1675	438	23	llc	llc	PROPN
eurjchem-1675	438	24	(	(	PUNCT
eurjchem-1675	438	25	european	european	PROPN
eurjchem-1675	438	26	journal	journal	PROPN
eurjchem-1675	438	27	of	of	ADP
eurjchem-1675	438	28	chemistry	chemistry	NOUN
eurjchem-1675	438	29	)	)	PUNCT
eurjchem-1675	438	30	.	.	PUNCT
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eurjchem-1675	439	2	–	–	PUNCT
eurjchem-1675	439	3	european	european	ADJ
eurjchem-1675	439	4	journal	journal	NOUN
eurjchem-1675	439	5	of	of	ADP
eurjchem-1675	439	6	chemistry	chemistry	NOUN
eurjchem-1675	439	7	–	–	PUNCT
eurjchem-1675	439	8	cc	cc	NOUN
eurjchem-1675	439	9	by	by	ADP
eurjchem-1675	439	10	nc	nc	PROPN
eurjchem-1675	439	11	–	–	PUNCT
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eurjchem-1675	439	17	-	-	PUNCT
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eurjchem-1675	439	20	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-1675	439	21	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
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eurjchem-1675	439	23	:	:	PUNCT
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eurjchem-1675	439	25	:	:	PUNCT
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eurjchem-1675	439	27	:	:	PUNCT
eurjchem-1675	439	28	printfield13	printfield13	VERB
eurjchem-1675	439	29	:	:	PUNCT
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eurjchem-1675	439	35	:	:	PUNCT
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eurjchem-1675	439	39	:	:	PUNCT
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eurjchem-1675	439	41	:	:	PUNCT
eurjchem-1675	439	42	printfield21	printfield21	ADJ
eurjchem-1675	439	43	:	:	PUNCT
eurjchem-1675	439	44	printfield22	printfield22	NOUN
eurjchem-1675	439	45	:	:	PUNCT
eurjchem-1675	439	46	printfield23	printfield23	NOUN
eurjchem-1675	439	47	:	:	PUNCT
eurjchem-1675	439	48	printfield24	printfield24	NOUN
eurjchem-1675	439	49	:	:	PUNCT
eurjchem-1675	439	50	printfield25	printfield25	NOUN
eurjchem-1675	439	51	:	:	PUNCT
eurjchem-1675	439	52	printfield26	printfield26	ADJ
eurjchem-1675	439	53	:	:	PUNCT
eurjchem-1675	439	54	printfield27	printfield27	NOUN
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eurjchem-1675	439	56	printfield28	printfield28	NOUN
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