id	sid	tid	token	lemma	pos
eurjchem-1680	1	1	correlation	correlation	NOUN
eurjchem-1680	1	2	of	of	ADP
eurjchem-1680	1	3	the	the	DET
eurjchem-1680	1	4	rates	rate	NOUN
eurjchem-1680	1	5	of	of	ADP
eurjchem-1680	1	6	solvolysis	solvolysis	NOUN
eurjchem-1680	1	7	of	of	ADP
eurjchem-1680	1	8	α	α	NOUN
eurjchem-1680	1	9	-	-	NOUN
eurjchem-1680	1	10	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	1	11	using	use	VERB
eurjchem-1680	1	12	both	both	CCONJ
eurjchem-1680	1	13	simple	simple	ADJ
eurjchem-1680	1	14	and	and	CCONJ
eurjchem-1680	1	15	extended	extended	ADJ
eurjchem-1680	1	16	forms	form	NOUN
eurjchem-1680	1	17	of	of	ADP
eurjchem-1680	1	18	the	the	DET
eurjchem-1680	1	19	grunwald	grunwald	NOUN
eurjchem-1680	1	20	-	-	PUNCT
eurjchem-1680	1	21	winstein	winstein	NOUN
eurjchem-1680	1	22	equation	equation	NOUN
eurjchem-1680	1	23	and	and	CCONJ
eurjchem-1680	1	24	the	the	DET
eurjchem-1680	1	25	application	application	NOUN
eurjchem-1680	1	26	of	of	ADP
eurjchem-1680	1	27	correlation	correlation	NOUN
eurjchem-1680	1	28	analysis	analysis	NOUN
eurjchem-1680	1	29	to	to	ADP
eurjchem-1680	1	30	related	related	ADJ
eurjchem-1680	1	31	studies	study	NOUN
eurjchem-1680	1	32	european	european	PROPN
eurjchem-1680	1	33	journal	journal	PROPN
eurjchem-1680	1	34	of	of	ADP
eurjchem-1680	1	35	chemistry	chemistry	NOUN
eurjchem-1680	1	36	9	9	NUM
eurjchem-1680	1	37	(	(	PUNCT
eurjchem-1680	1	38	1	1	NUM
eurjchem-1680	1	39	)	)	PUNCT
eurjchem-1680	1	40	(	(	PUNCT
eurjchem-1680	1	41	2018	2018	NUM
eurjchem-1680	1	42	)	)	PUNCT
eurjchem-1680	1	43	1	1	NUM
eurjchem-1680	1	44	-	-	SYM
eurjchem-1680	1	45	6	6	NUM
eurjchem-1680	1	46	european	european	ADJ
eurjchem-1680	1	47	journal	journal	NOUN
eurjchem-1680	1	48	of	of	ADP
eurjchem-1680	1	49	chemistry	chemistry	NOUN
eurjchem-1680	1	50	view	view	NOUN
eurjchem-1680	1	51	journal	journal	PROPN
eurjchem-1680	1	52	online	online	PROPN
eurjchem-1680	1	53	view	view	NOUN
eurjchem-1680	1	54	article	article	NOUN
eurjchem-1680	1	55	online	online	ADJ
eurjchem-1680	1	56	correlation	correlation	NOUN
eurjchem-1680	1	57	of	of	ADP
eurjchem-1680	1	58	the	the	DET
eurjchem-1680	1	59	rates	rate	NOUN
eurjchem-1680	1	60	of	of	ADP
eurjchem-1680	1	61	solvolysis	solvolysis	NOUN
eurjchem-1680	1	62	of	of	ADP
eurjchem-1680	1	63	α	α	NOUN
eurjchem-1680	1	64	-	-	NOUN
eurjchem-1680	1	65	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	1	66	using	use	VERB
eurjchem-1680	1	67	both	both	CCONJ
eurjchem-1680	1	68	simple	simple	ADJ
eurjchem-1680	1	69	and	and	CCONJ
eurjchem-1680	1	70	extended	extended	ADJ
eurjchem-1680	1	71	forms	form	NOUN
eurjchem-1680	1	72	of	of	ADP
eurjchem-1680	1	73	the	the	DET
eurjchem-1680	1	74	grunwald	grunwald	NOUN
eurjchem-1680	1	75	-	-	PUNCT
eurjchem-1680	1	76	winstein	winstein	NOUN
eurjchem-1680	1	77	equation	equation	NOUN
eurjchem-1680	1	78	and	and	CCONJ
eurjchem-1680	1	79	the	the	DET
eurjchem-1680	1	80	application	application	NOUN
eurjchem-1680	1	81	of	of	ADP
eurjchem-1680	1	82	correlation	correlation	NOUN
eurjchem-1680	1	83	analysis	analysis	NOUN
eurjchem-1680	1	84	to	to	ADP
eurjchem-1680	1	85	related	related	ADJ
eurjchem-1680	1	86	studies	study	NOUN
eurjchem-1680	1	87	dennis	dennis	PROPN
eurjchem-1680	1	88	neil	neil	PROPN
eurjchem-1680	1	89	kevill	kevill	PROPN
eurjchem-1680	1	90	1	1	NUM
eurjchem-1680	1	91	,	,	PUNCT
eurjchem-1680	1	92	chang	chang	PROPN
eurjchem-1680	1	93	-	-	PUNCT
eurjchem-1680	1	94	bae	bae	PROPN
eurjchem-1680	1	95	kim	kim	PROPN
eurjchem-1680	1	96	2	2	NUM
eurjchem-1680	1	97	and	and	CCONJ
eurjchem-1680	1	98	malcolm	malcolm	PROPN
eurjchem-1680	1	99	john	john	PROPN
eurjchem-1680	1	100	d’souza	d’souza	PROPN
eurjchem-1680	1	101	3	3	NUM
eurjchem-1680	1	102	,	,	PUNCT
eurjchem-1680	1	103	*	*	PROPN
eurjchem-1680	1	104	1	1	NUM
eurjchem-1680	1	105	department	department	NOUN
eurjchem-1680	1	106	of	of	ADP
eurjchem-1680	1	107	chemistry	chemistry	NOUN
eurjchem-1680	1	108	and	and	CCONJ
eurjchem-1680	1	109	biochemistry	biochemistry	NOUN
eurjchem-1680	1	110	,	,	PUNCT
eurjchem-1680	1	111	northern	northern	ADJ
eurjchem-1680	1	112	illinois	illinois	PROPN
eurjchem-1680	1	113	university	university	PROPN
eurjchem-1680	1	114	,	,	PUNCT
eurjchem-1680	1	115	dekalb	dekalb	PROPN
eurjchem-1680	1	116	,	,	PUNCT
eurjchem-1680	1	117	illinois	illinois	PROPN
eurjchem-1680	1	118	60115	60115	NUM
eurjchem-1680	1	119	-	-	SYM
eurjchem-1680	1	120	2862	2862	NUM
eurjchem-1680	1	121	,	,	PUNCT
eurjchem-1680	1	122	usa	usa	PROPN
eurjchem-1680	1	123	dkevill@niu.edu	dkevill@niu.edu	PROPN
eurjchem-1680	1	124	(	(	PUNCT
eurjchem-1680	1	125	d.n.k	d.n.k	NOUN
eurjchem-1680	1	126	.	.	PUNCT
eurjchem-1680	1	127	)	)	PUNCT
eurjchem-1680	2	1	2	2	NUM
eurjchem-1680	2	2	department	department	NOUN
eurjchem-1680	2	3	of	of	ADP
eurjchem-1680	2	4	chemistry	chemistry	NOUN
eurjchem-1680	2	5	,	,	PUNCT
eurjchem-1680	2	6	dan	dan	PROPN
eurjchem-1680	2	7	-	-	PUNCT
eurjchem-1680	2	8	kook	kook	PROPN
eurjchem-1680	2	9	university	university	PROPN
eurjchem-1680	2	10	,	,	PUNCT
eurjchem-1680	2	11	hannam	hannam	NOUN
eurjchem-1680	2	12	-	-	PUNCT
eurjchem-1680	2	13	dong	dong	NOUN
eurjchem-1680	2	14	,	,	PUNCT
eurjchem-1680	2	15	yongsan	yongsan	NOUN
eurjchem-1680	2	16	-	-	PUNCT
eurjchem-1680	2	17	gu	gu	NOUN
eurjchem-1680	2	18	,	,	PUNCT
eurjchem-1680	2	19	seoul	seoul	PROPN
eurjchem-1680	2	20	140	140	NUM
eurjchem-1680	2	21	-	-	SYM
eurjchem-1680	2	22	714	714	NUM
eurjchem-1680	2	23	,	,	PUNCT
eurjchem-1680	2	24	korea	korea	PROPN
eurjchem-1680	2	25	cbkim36@hanmail.net	cbkim36@hanmail.net	PROPN
eurjchem-1680	2	26	(	(	PUNCT
eurjchem-1680	2	27	c.b.k	c.b.k	PROPN
eurjchem-1680	2	28	.	.	PUNCT
eurjchem-1680	2	29	)	)	PUNCT
eurjchem-1680	3	1	3	3	NUM
eurjchem-1680	3	2	department	department	NOUN
eurjchem-1680	3	3	of	of	ADP
eurjchem-1680	3	4	chemistry	chemistry	NOUN
eurjchem-1680	3	5	,	,	PUNCT
eurjchem-1680	3	6	wesley	wesley	PROPN
eurjchem-1680	3	7	college	college	PROPN
eurjchem-1680	3	8	,	,	PUNCT
eurjchem-1680	3	9	120	120	NUM
eurjchem-1680	3	10	north	north	NOUN
eurjchem-1680	3	11	state	state	PROPN
eurjchem-1680	3	12	street	street	PROPN
eurjchem-1680	3	13	,	,	PUNCT
eurjchem-1680	3	14	dover	dover	PROPN
eurjchem-1680	3	15	,	,	PUNCT
eurjchem-1680	3	16	delaware	delaware	PROPN
eurjchem-1680	3	17	19901	19901	NUM
eurjchem-1680	3	18	-	-	SYM
eurjchem-1680	3	19	3875	3875	NUM
eurjchem-1680	3	20	,	,	PUNCT
eurjchem-1680	3	21	usa	usa	PROPN
eurjchem-1680	3	22	malcolm.dsouza@wesley.edu	malcolm.dsouza@wesley.edu	PROPN
eurjchem-1680	3	23	(	(	PUNCT
eurjchem-1680	3	24	m.j.d	m.j.d	VERB
eurjchem-1680	3	25	’s	’s	ADV
eurjchem-1680	3	26	.	.	PUNCT
eurjchem-1680	3	27	)	)	PUNCT
eurjchem-1680	4	1	*	*	PUNCT
eurjchem-1680	4	2	corresponding	correspond	VERB
eurjchem-1680	4	3	author	author	NOUN
eurjchem-1680	4	4	at	at	ADP
eurjchem-1680	4	5	:	:	PUNCT
eurjchem-1680	4	6	department	department	NOUN
eurjchem-1680	4	7	of	of	ADP
eurjchem-1680	4	8	chemistry	chemistry	NOUN
eurjchem-1680	4	9	,	,	PUNCT
eurjchem-1680	4	10	wesley	wesley	PROPN
eurjchem-1680	4	11	college	college	PROPN
eurjchem-1680	4	12	,	,	PUNCT
eurjchem-1680	4	13	120	120	NUM
eurjchem-1680	4	14	north	north	NOUN
eurjchem-1680	4	15	state	state	PROPN
eurjchem-1680	4	16	street	street	PROPN
eurjchem-1680	4	17	,	,	PUNCT
eurjchem-1680	4	18	dover	dover	PROPN
eurjchem-1680	4	19	,	,	PUNCT
eurjchem-1680	4	20	delaware	delaware	PROPN
eurjchem-1680	4	21	19901	19901	NUM
eurjchem-1680	4	22	-	-	SYM
eurjchem-1680	4	23	3875	3875	NUM
eurjchem-1680	4	24	,	,	PUNCT
eurjchem-1680	4	25	usa	usa	PROPN
eurjchem-1680	4	26	.	.	PROPN
eurjchem-1680	4	27	tel	tel	PROPN
eurjchem-1680	4	28	:	:	PUNCT
eurjchem-1680	4	29	+1.302.7362528	+1.302.7362528	PROPN
eurjchem-1680	4	30	fax	fax	NOUN
eurjchem-1680	4	31	:	:	PUNCT
eurjchem-1680	4	32	+1.302.7362301	+1.302.7362301	NOUN
eurjchem-1680	4	33	e	e	NOUN
eurjchem-1680	4	34	-	-	NOUN
eurjchem-1680	4	35	mail	mail	NOUN
eurjchem-1680	4	36	:	:	PUNCT
eurjchem-1680	4	37	malcolm.dsouza@wesley.edu	malcolm.dsouza@wesley.edu	PROPN
eurjchem-1680	4	38	(	(	PUNCT
eurjchem-1680	4	39	m.j	m.j	PROPN
eurjchem-1680	4	40	.	.	PROPN
eurjchem-1680	4	41	d’souza	d’souza	PROPN
eurjchem-1680	4	42	)	)	PUNCT
eurjchem-1680	4	43	.	.	PUNCT
eurjchem-1680	5	1	10.5155	10.5155	NUM
eurjchem-1680	5	2	/	/	SYM
eurjchem-1680	5	3	eurjchem.9.1.1	eurjchem.9.1.1	NOUN
eurjchem-1680	5	4	-	-	PUNCT
eurjchem-1680	5	5	6.1680	6.1680	NUM
eurjchem-1680	5	6	received	receive	VERB
eurjchem-1680	5	7	:	:	PUNCT
eurjchem-1680	5	8	03	03	NUM
eurjchem-1680	5	9	january	january	PROPN
eurjchem-1680	5	10	2018	2018	NUM
eurjchem-1680	5	11	received	receive	VERB
eurjchem-1680	5	12	in	in	ADP
eurjchem-1680	5	13	revised	revise	VERB
eurjchem-1680	5	14	form	form	NOUN
eurjchem-1680	5	15	:	:	PUNCT
eurjchem-1680	5	16	26	26	NUM
eurjchem-1680	5	17	january	january	PROPN
eurjchem-1680	5	18	2018	2018	NUM
eurjchem-1680	5	19	accepted	accept	VERB
eurjchem-1680	5	20	:	:	PUNCT
eurjchem-1680	5	21	26	26	NUM
eurjchem-1680	5	22	january	january	PROPN
eurjchem-1680	5	23	2018	2018	NUM
eurjchem-1680	5	24	published	publish	VERB
eurjchem-1680	5	25	online	online	ADV
eurjchem-1680	5	26	:	:	PUNCT
eurjchem-1680	5	27	31	31	NUM
eurjchem-1680	5	28	march	march	PROPN
eurjchem-1680	5	29	2018	2018	NUM
eurjchem-1680	5	30	printed	print	VERB
eurjchem-1680	5	31	:	:	PUNCT
eurjchem-1680	5	32	31	31	NUM
eurjchem-1680	5	33	march	march	PROPN
eurjchem-1680	5	34	2018	2018	NUM
eurjchem-1680	5	35	a	a	DET
eurjchem-1680	5	36	grunwald	grunwald	NOUN
eurjchem-1680	5	37	-	-	PUNCT
eurjchem-1680	5	38	winstein	winstein	NOUN
eurjchem-1680	5	39	treatment	treatment	NOUN
eurjchem-1680	5	40	of	of	ADP
eurjchem-1680	5	41	the	the	DET
eurjchem-1680	5	42	specific	specific	ADJ
eurjchem-1680	5	43	rates	rate	NOUN
eurjchem-1680	5	44	of	of	ADP
eurjchem-1680	5	45	solvolysis	solvolysis	NOUN
eurjchem-1680	5	46	of	of	ADP
eurjchem-1680	5	47	α	α	NOUN
eurjchem-1680	5	48	-	-	PUNCT
eurjchem-1680	5	49	bromoisobutyro	bromoisobutyro	NOUN
eurjchem-1680	5	50	phenone	phenone	NOUN
eurjchem-1680	5	51	in	in	ADP
eurjchem-1680	5	52	100	100	NUM
eurjchem-1680	5	53	%	%	NOUN
eurjchem-1680	5	54	methanol	methanol	NOUN
eurjchem-1680	5	55	and	and	CCONJ
eurjchem-1680	5	56	in	in	ADP
eurjchem-1680	5	57	several	several	ADJ
eurjchem-1680	5	58	aqueous	aqueous	ADJ
eurjchem-1680	5	59	ethanol	ethanol	NOUN
eurjchem-1680	5	60	,	,	PUNCT
eurjchem-1680	5	61	methanol	methanol	NOUN
eurjchem-1680	5	62	,	,	PUNCT
eurjchem-1680	5	63	acetone	acetone	NOUN
eurjchem-1680	5	64	,	,	PUNCT
eurjchem-1680	5	65	2,2,2trifluoroethanol	2,2,2trifluoroethanol	NUM
eurjchem-1680	5	66	(	(	PUNCT
eurjchem-1680	5	67	tfe	tfe	NOUN
eurjchem-1680	5	68	)	)	PUNCT
eurjchem-1680	5	69	,	,	PUNCT
eurjchem-1680	5	70	and	and	CCONJ
eurjchem-1680	5	71	1,1,1,3,3,3	1,1,1,3,3,3	NUM
eurjchem-1680	5	72	-	-	PUNCT
eurjchem-1680	5	73	hexafluoro-2	hexafluoro-2	NOUN
eurjchem-1680	5	74	-	-	PUNCT
eurjchem-1680	5	75	propanol	propanol	NOUN
eurjchem-1680	5	76	(	(	PUNCT
eurjchem-1680	5	77	hfip	hfip	NOUN
eurjchem-1680	5	78	)	)	PUNCT
eurjchem-1680	5	79	mixtures	mixture	NOUN
eurjchem-1680	5	80	gives	give	VERB
eurjchem-1680	5	81	a	a	DET
eurjchem-1680	5	82	good	good	ADJ
eurjchem-1680	5	83	logarithmic	logarithmic	ADJ
eurjchem-1680	5	84	correlation	correlation	NOUN
eurjchem-1680	5	85	against	against	ADP
eurjchem-1680	5	86	a	a	DET
eurjchem-1680	5	87	linear	linear	ADJ
eurjchem-1680	5	88	combination	combination	NOUN
eurjchem-1680	5	89	of	of	ADP
eurjchem-1680	5	90	nt	not	PART
eurjchem-1680	5	91	(	(	PUNCT
eurjchem-1680	5	92	solvent	solvent	NOUN
eurjchem-1680	5	93	nucleophilicity	nucleophilicity	NOUN
eurjchem-1680	5	94	)	)	PUNCT
eurjchem-1680	5	95	and	and	CCONJ
eurjchem-1680	5	96	ybr	ybr	PROPN
eurjchem-1680	5	97	(	(	PUNCT
eurjchem-1680	5	98	solvent	solvent	NOUN
eurjchem-1680	5	99	ionizing	ionizing	NOUN
eurjchem-1680	5	100	power	power	NOUN
eurjchem-1680	5	101	)	)	PUNCT
eurjchem-1680	5	102	values	value	NOUN
eurjchem-1680	5	103	.	.	PUNCT
eurjchem-1680	6	1	the	the	DET
eurjchem-1680	6	2	l	l	NOUN
eurjchem-1680	6	3	and	and	CCONJ
eurjchem-1680	6	4	m	m	PROPN
eurjchem-1680	6	5	sensitivity	sensitivity	NOUN
eurjchem-1680	6	6	values	value	NOUN
eurjchem-1680	6	7	are	be	AUX
eurjchem-1680	6	8	compared	compare	VERB
eurjchem-1680	6	9	to	to	ADP
eurjchem-1680	6	10	those	those	PRON
eurjchem-1680	6	11	previously	previously	ADV
eurjchem-1680	6	12	reported	report	VERB
eurjchem-1680	6	13	for	for	ADP
eurjchem-1680	6	14	α	α	NOUN
eurjchem-1680	6	15	-	-	NOUN
eurjchem-1680	6	16	bromoacetophenone	bromoacetophenone	NOUN
eurjchem-1680	6	17	and	and	CCONJ
eurjchem-1680	6	18	to	to	ADP
eurjchem-1680	6	19	those	those	PRON
eurjchem-1680	6	20	obtained	obtain	VERB
eurjchem-1680	6	21	from	from	ADP
eurjchem-1680	6	22	parallel	parallel	ADJ
eurjchem-1680	6	23	treatments	treatment	NOUN
eurjchem-1680	6	24	of	of	ADP
eurjchem-1680	6	25	literature	literature	NOUN
eurjchem-1680	6	26	specific	specific	ADJ
eurjchem-1680	6	27	rate	rate	NOUN
eurjchem-1680	6	28	values	value	NOUN
eurjchem-1680	6	29	for	for	ADP
eurjchem-1680	6	30	the	the	DET
eurjchem-1680	6	31	solvolyses	solvolyse	NOUN
eurjchem-1680	6	32	of	of	ADP
eurjchem-1680	6	33	several	several	ADJ
eurjchem-1680	6	34	tertiary	tertiary	ADJ
eurjchem-1680	6	35	mesylates	mesylate	NOUN
eurjchem-1680	6	36	containing	contain	VERB
eurjchem-1680	6	37	a	a	DET
eurjchem-1680	6	38	c(=o)r	c(=o)r	NOUN
eurjchem-1680	6	39	group	group	NOUN
eurjchem-1680	6	40	attached	attach	VERB
eurjchem-1680	6	41	at	at	ADP
eurjchem-1680	6	42	the	the	DET
eurjchem-1680	6	43	α	α	NOUN
eurjchem-1680	6	44	-	-	NOUN
eurjchem-1680	6	45	carbon	carbon	NOUN
eurjchem-1680	6	46	.	.	PUNCT
eurjchem-1680	7	1	kinetic	kinetic	ADJ
eurjchem-1680	7	2	data	datum	NOUN
eurjchem-1680	7	3	obtained	obtain	VERB
eurjchem-1680	7	4	earlier	early	ADV
eurjchem-1680	7	5	by	by	ADP
eurjchem-1680	7	6	pasto	pasto	NOUN
eurjchem-1680	7	7	and	and	CCONJ
eurjchem-1680	7	8	sevenair	sevenair	VERB
eurjchem-1680	7	9	for	for	ADP
eurjchem-1680	7	10	the	the	DET
eurjchem-1680	7	11	solvolyses	solvolyse	NOUN
eurjchem-1680	7	12	of	of	ADP
eurjchem-1680	7	13	the	the	DET
eurjchem-1680	7	14	same	same	ADJ
eurjchem-1680	7	15	substrate	substrate	NOUN
eurjchem-1680	7	16	in	in	ADP
eurjchem-1680	7	17	75	75	NUM
eurjchem-1680	7	18	%	%	NOUN
eurjchem-1680	7	19	aqueous	aqueous	ADJ
eurjchem-1680	7	20	ethanol	ethanol	NOUN
eurjchem-1680	7	21	(	(	PUNCT
eurjchem-1680	7	22	by	by	ADP
eurjchem-1680	7	23	weight	weight	NOUN
eurjchem-1680	7	24	)	)	PUNCT
eurjchem-1680	7	25	in	in	ADP
eurjchem-1680	7	26	the	the	DET
eurjchem-1680	7	27	presence	presence	NOUN
eurjchem-1680	7	28	of	of	ADP
eurjchem-1680	7	29	silver	silver	ADJ
eurjchem-1680	7	30	perchlorate	perchlorate	NOUN
eurjchem-1680	7	31	and	and	CCONJ
eurjchem-1680	7	32	perchloric	perchloric	ADJ
eurjchem-1680	7	33	acid	acid	NOUN
eurjchem-1680	7	34	are	be	AUX
eurjchem-1680	7	35	analysed	analyse	VERB
eurjchem-1680	7	36	using	use	VERB
eurjchem-1680	7	37	multiple	multiple	ADJ
eurjchem-1680	7	38	regression	regression	NOUN
eurjchem-1680	7	39	analysis	analysis	NOUN
eurjchem-1680	7	40	.	.	PUNCT
eurjchem-1680	8	1	solvolysis	solvolysis	NOUN
eurjchem-1680	8	2	mechanism	mechanism	NOUN
eurjchem-1680	8	3	correlation	correlation	NOUN
eurjchem-1680	8	4	α	α	NOUN
eurjchem-1680	8	5	-	-	NOUN
eurjchem-1680	8	6	bromoisobutyrophenone	bromoisobutyrophenone	ADJ
eurjchem-1680	8	7	2	2	NUM
eurjchem-1680	8	8	-	-	PUNCT
eurjchem-1680	8	9	benzoyl-2	benzoyl-2	NUM
eurjchem-1680	8	10	-	-	PUNCT
eurjchem-1680	8	11	bromopropane	bromopropane	NOUN
eurjchem-1680	8	12	grunwald	grunwald	PROPN
eurjchem-1680	8	13	-	-	PUNCT
eurjchem-1680	8	14	winstein	winstein	NOUN
eurjchem-1680	8	15	equations	equation	NOUN
eurjchem-1680	8	16	cite	cite	VERB
eurjchem-1680	8	17	this	this	PRON
eurjchem-1680	8	18	:	:	PUNCT
eurjchem-1680	8	19	eur	eur	PROPN
eurjchem-1680	8	20	.	.	PUNCT
eurjchem-1680	9	1	j.	j.	PROPN
eurjchem-1680	9	2	chem	chem	PROPN
eurjchem-1680	9	3	.	.	PUNCT
eurjchem-1680	10	1	2018	2018	NUM
eurjchem-1680	10	2	,	,	PUNCT
eurjchem-1680	10	3	9(1	9(1	NUM
eurjchem-1680	10	4	)	)	PUNCT
eurjchem-1680	10	5	,	,	PUNCT
eurjchem-1680	10	6	1	1	NUM
eurjchem-1680	10	7	-	-	SYM
eurjchem-1680	10	8	6	6	NUM
eurjchem-1680	10	9	journal	journal	NOUN
eurjchem-1680	10	10	website	website	NOUN
eurjchem-1680	10	11	:	:	PUNCT
eurjchem-1680	10	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1680	10	13	1	1	X
eurjchem-1680	10	14	.	.	PUNCT
eurjchem-1680	10	15	introduction	introduction	NOUN
eurjchem-1680	10	16	several	several	ADJ
eurjchem-1680	10	17	years	year	NOUN
eurjchem-1680	10	18	ago	ago	ADV
eurjchem-1680	10	19	,	,	PUNCT
eurjchem-1680	10	20	we	we	PRON
eurjchem-1680	10	21	reported	report	VERB
eurjchem-1680	10	22	[	[	X
eurjchem-1680	10	23	1	1	X
eurjchem-1680	10	24	]	]	PUNCT
eurjchem-1680	10	25	on	on	ADP
eurjchem-1680	10	26	the	the	DET
eurjchem-1680	10	27	application	application	NOUN
eurjchem-1680	10	28	of	of	ADP
eurjchem-1680	10	29	the	the	DET
eurjchem-1680	10	30	grunwald	grunwald	NOUN
eurjchem-1680	10	31	-	-	PUNCT
eurjchem-1680	10	32	winstein	winstein	NOUN
eurjchem-1680	10	33	equations	equation	NOUN
eurjchem-1680	10	34	[	[	X
eurjchem-1680	10	35	2	2	NUM
eurjchem-1680	10	36	-	-	SYM
eurjchem-1680	10	37	6	6	NUM
eurjchem-1680	10	38	]	]	PUNCT
eurjchem-1680	10	39	to	to	ADP
eurjchem-1680	10	40	the	the	DET
eurjchem-1680	10	41	specific	specific	ADJ
eurjchem-1680	10	42	rates	rate	NOUN
eurjchem-1680	10	43	of	of	ADP
eurjchem-1680	10	44	solvolysis	solvolysis	NOUN
eurjchem-1680	10	45	(	(	PUNCT
eurjchem-1680	10	46	k1	k1	NOUN
eurjchem-1680	10	47	)	)	PUNCT
eurjchem-1680	10	48	of	of	ADP
eurjchem-1680	10	49	the	the	DET
eurjchem-1680	10	50	primary	primary	ADJ
eurjchem-1680	10	51	alpha	alpha	NOUN
eurjchem-1680	10	52	-	-	NOUN
eurjchem-1680	10	53	bromoketone	bromoketone	NOUN
eurjchem-1680	10	54	α	α	NOUN
eurjchem-1680	10	55	-	-	NOUN
eurjchem-1680	10	56	bromoacetophenone	bromoacetophenone	NOUN
eurjchem-1680	10	57	(	(	PUNCT
eurjchem-1680	10	58	c6h5coch2br	c6h5coch2br	PROPN
eurjchem-1680	10	59	,	,	PUNCT
eurjchem-1680	10	60	1	1	NUM
eurjchem-1680	10	61	)	)	PUNCT
eurjchem-1680	10	62	(	(	PUNCT
eurjchem-1680	10	63	scheme	scheme	NOUN
eurjchem-1680	10	64	1	1	NUM
eurjchem-1680	10	65	)	)	PUNCT
eurjchem-1680	10	66	.	.	PUNCT
eurjchem-1680	11	1	an	an	DET
eurjchem-1680	11	2	sn2	sn2	PROPN
eurjchem-1680	11	3	process	process	NOUN
eurjchem-1680	11	4	had	have	AUX
eurjchem-1680	11	5	previously	previously	ADV
eurjchem-1680	11	6	been	be	AUX
eurjchem-1680	11	7	proposed	propose	VERB
eurjchem-1680	11	8	[	[	X
eurjchem-1680	11	9	7	7	X
eurjchem-1680	11	10	]	]	PUNCT
eurjchem-1680	11	11	for	for	ADP
eurjchem-1680	11	12	this	this	DET
eurjchem-1680	11	13	process	process	NOUN
eurjchem-1680	11	14	based	base	VERB
eurjchem-1680	11	15	on	on	ADP
eurjchem-1680	11	16	a	a	DET
eurjchem-1680	11	17	study	study	NOUN
eurjchem-1680	11	18	in	in	ADP
eurjchem-1680	11	19	three	three	NUM
eurjchem-1680	11	20	aqueous	aqueous	ADJ
eurjchem-1680	11	21	ethanol	ethanol	NOUN
eurjchem-1680	11	22	solvents	solvent	NOUN
eurjchem-1680	11	23	leading	lead	VERB
eurjchem-1680	11	24	to	to	ADP
eurjchem-1680	11	25	a	a	DET
eurjchem-1680	11	26	very	very	ADV
eurjchem-1680	11	27	low	low	ADJ
eurjchem-1680	11	28	m	m	NOUN
eurjchem-1680	11	29	value	value	NOUN
eurjchem-1680	11	30	of	of	ADP
eurjchem-1680	11	31	0.20±0.01	0.20±0.01	NUM
eurjchem-1680	11	32	when	when	SCONJ
eurjchem-1680	11	33	the	the	DET
eurjchem-1680	11	34	one	one	NUM
eurjchem-1680	11	35	-	-	PUNCT
eurjchem-1680	11	36	term	term	NOUN
eurjchem-1680	11	37	(	(	PUNCT
eurjchem-1680	11	38	simple	simple	ADJ
eurjchem-1680	11	39	)	)	PUNCT
eurjchem-1680	11	40	grunwaldwinstein	grunwaldwinstein	NOUN
eurjchem-1680	11	41	equation	equation	NOUN
eurjchem-1680	11	42	[	[	X
eurjchem-1680	11	43	2,3	2,3	NUM
eurjchem-1680	11	44	]	]	PUNCT
eurjchem-1680	11	45	(	(	PUNCT
eurjchem-1680	11	46	equation	equation	NOUN
eurjchem-1680	11	47	1	1	NUM
eurjchem-1680	11	48	)	)	PUNCT
eurjchem-1680	11	49	was	be	AUX
eurjchem-1680	11	50	applied	apply	VERB
eurjchem-1680	11	51	to	to	ADP
eurjchem-1680	11	52	the	the	DET
eurjchem-1680	11	53	specific	specific	ADJ
eurjchem-1680	11	54	rates	rate	NOUN
eurjchem-1680	11	55	(	(	PUNCT
eurjchem-1680	11	56	first	first	ADJ
eurjchem-1680	11	57	-	-	PUNCT
eurjchem-1680	11	58	order	order	NOUN
eurjchem-1680	11	59	rate	rate	NOUN
eurjchem-1680	11	60	coefficients	coefficient	NOUN
eurjchem-1680	11	61	)	)	PUNCT
eurjchem-1680	11	62	at	at	ADP
eurjchem-1680	11	63	three	three	NUM
eurjchem-1680	11	64	temperatures	temperature	NOUN
eurjchem-1680	11	65	in	in	ADP
eurjchem-1680	11	66	the	the	DET
eurjchem-1680	11	67	55	55	NUM
eurjchem-1680	11	68	-	-	SYM
eurjchem-1680	11	69	80	80	NUM
eurjchem-1680	11	70	°	°	PROPN
eurjchem-1680	11	71	c	c	NOUN
eurjchem-1680	11	72	range	range	NOUN
eurjchem-1680	11	73	,	,	PUNCT
eurjchem-1680	11	74	coupled	couple	VERB
eurjchem-1680	11	75	with	with	ADP
eurjchem-1680	11	76	a	a	DET
eurjchem-1680	11	77	very	very	ADV
eurjchem-1680	11	78	low	low	ADJ
eurjchem-1680	11	79	hammett	hammett	NOUN
eurjchem-1680	11	80	ϱ	ϱ	ADP
eurjchem-1680	11	81	value	value	NOUN
eurjchem-1680	11	82	[	[	X
eurjchem-1680	11	83	7	7	NUM
eurjchem-1680	11	84	]	]	PUNCT
eurjchem-1680	11	85	of	of	ADP
eurjchem-1680	11	86	+0.35	+0.35	PROPN
eurjchem-1680	11	87	being	be	AUX
eurjchem-1680	11	88	obtained	obtain	VERB
eurjchem-1680	11	89	for	for	ADP
eurjchem-1680	11	90	solvolyses	solvolyse	NOUN
eurjchem-1680	11	91	in	in	ADP
eurjchem-1680	11	92	80	80	NUM
eurjchem-1680	11	93	%	%	NOUN
eurjchem-1680	11	94	ethanol	ethanol	NOUN
eurjchem-1680	11	95	at	at	ADP
eurjchem-1680	11	96	70	70	NUM
eurjchem-1680	11	97	°	°	NOUN
eurjchem-1680	11	98	c	c	NOUN
eurjchem-1680	11	99	of	of	ADP
eurjchem-1680	11	100	the	the	DET
eurjchem-1680	11	101	parent	parent	NOUN
eurjchem-1680	11	102	and	and	CCONJ
eurjchem-1680	11	103	five	five	NUM
eurjchem-1680	11	104	metaand	metaand	NOUN
eurjchem-1680	11	105	parasubstituted	parasubstitute	VERB
eurjchem-1680	11	106	derivatives	derivative	NOUN
eurjchem-1680	11	107	.	.	PUNCT
eurjchem-1680	12	1	log	log	NOUN
eurjchem-1680	12	2	(	(	PUNCT
eurjchem-1680	12	3	k	k	NOUN
eurjchem-1680	12	4	/	/	SYM
eurjchem-1680	12	5	ko)rx	ko)rx	NOUN
eurjchem-1680	12	6	=	=	SYM
eurjchem-1680	12	7	myx	myx	NOUN
eurjchem-1680	12	8	+	+	X
eurjchem-1680	12	9	c	c	X
eurjchem-1680	12	10	(	(	PUNCT
eurjchem-1680	12	11	1	1	NUM
eurjchem-1680	12	12	)	)	PUNCT
eurjchem-1680	12	13	in	in	ADP
eurjchem-1680	12	14	equation	equation	NOUN
eurjchem-1680	12	15	(	(	PUNCT
eurjchem-1680	12	16	1	1	NUM
eurjchem-1680	12	17	)	)	PUNCT
eurjchem-1680	12	18	,	,	PUNCT
eurjchem-1680	13	1	k	k	PROPN
eurjchem-1680	13	2	and	and	CCONJ
eurjchem-1680	13	3	ko	ko	PROPN
eurjchem-1680	13	4	represent	represent	VERB
eurjchem-1680	13	5	the	the	DET
eurjchem-1680	13	6	specific	specific	ADJ
eurjchem-1680	13	7	rates	rate	NOUN
eurjchem-1680	13	8	of	of	ADP
eurjchem-1680	13	9	solvolysis	solvolysis	NOUN
eurjchem-1680	13	10	of	of	ADP
eurjchem-1680	13	11	a	a	DET
eurjchem-1680	13	12	substrate	substrate	NOUN
eurjchem-1680	13	13	rx	rx	VERB
eurjchem-1680	13	14	in	in	ADP
eurjchem-1680	13	15	a	a	DET
eurjchem-1680	13	16	given	give	VERB
eurjchem-1680	13	17	solvent	solvent	NOUN
eurjchem-1680	13	18	and	and	CCONJ
eurjchem-1680	13	19	in	in	ADP
eurjchem-1680	13	20	the	the	DET
eurjchem-1680	13	21	standard	standard	ADJ
eurjchem-1680	13	22	solvent	solvent	NOUN
eurjchem-1680	13	23	(	(	PUNCT
eurjchem-1680	13	24	80	80	NUM
eurjchem-1680	13	25	%	%	NOUN
eurjchem-1680	13	26	ethanol	ethanol	NOUN
eurjchem-1680	13	27	)	)	PUNCT
eurjchem-1680	13	28	,	,	PUNCT
eurjchem-1680	13	29	m	m	PROPN
eurjchem-1680	13	30	is	be	AUX
eurjchem-1680	13	31	the	the	DET
eurjchem-1680	13	32	sensitivity	sensitivity	NOUN
eurjchem-1680	13	33	to	to	PART
eurjchem-1680	13	34	changes	change	NOUN
eurjchem-1680	13	35	in	in	ADP
eurjchem-1680	13	36	the	the	DET
eurjchem-1680	13	37	solvent	solvent	NOUN
eurjchem-1680	13	38	ionizing	ionizing	NOUN
eurjchem-1680	13	39	power	power	NOUN
eurjchem-1680	13	40	(	(	PUNCT
eurjchem-1680	13	41	yx	yx	NOUN
eurjchem-1680	13	42	for	for	ADP
eurjchem-1680	13	43	a	a	DET
eurjchem-1680	13	44	leaving	leave	VERB
eurjchem-1680	13	45	group	group	NOUN
eurjchem-1680	13	46	x	x	NOUN
eurjchem-1680	13	47	)	)	PUNCT
eurjchem-1680	13	48	and	and	CCONJ
eurjchem-1680	13	49	c	c	PROPN
eurjchem-1680	13	50	is	be	AUX
eurjchem-1680	13	51	a	a	DET
eurjchem-1680	13	52	constant	constant	ADJ
eurjchem-1680	13	53	(	(	PUNCT
eurjchem-1680	13	54	residual	residual	ADJ
eurjchem-1680	13	55	)	)	PUNCT
eurjchem-1680	13	56	term	term	NOUN
eurjchem-1680	13	57	.	.	PUNCT
eurjchem-1680	14	1	in	in	ADP
eurjchem-1680	14	2	our	our	PRON
eurjchem-1680	14	3	determination	determination	NOUN
eurjchem-1680	14	4	[	[	X
eurjchem-1680	14	5	1	1	NUM
eurjchem-1680	14	6	]	]	PUNCT
eurjchem-1680	14	7	,	,	PUNCT
eurjchem-1680	14	8	at	at	ADP
eurjchem-1680	14	9	62.5	62.5	NUM
eurjchem-1680	14	10	°	°	NOUN
eurjchem-1680	14	11	c	c	NOUN
eurjchem-1680	14	12	,	,	PUNCT
eurjchem-1680	14	13	of	of	ADP
eurjchem-1680	14	14	the	the	DET
eurjchem-1680	14	15	specific	specific	ADJ
eurjchem-1680	14	16	rates	rate	NOUN
eurjchem-1680	14	17	of	of	ADP
eurjchem-1680	14	18	solvolysis	solvolysis	NOUN
eurjchem-1680	14	19	of	of	ADP
eurjchem-1680	14	20	1	1	NUM
eurjchem-1680	14	21	in	in	ADP
eurjchem-1680	14	22	a	a	DET
eurjchem-1680	14	23	much	much	ADV
eurjchem-1680	14	24	wide	wide	ADJ
eurjchem-1680	14	25	range	range	NOUN
eurjchem-1680	14	26	of	of	ADP
eurjchem-1680	14	27	solvent	solvent	ADJ
eurjchem-1680	14	28	type	type	NOUN
eurjchem-1680	14	29	,	,	PUNCT
eurjchem-1680	14	30	equation	equation	NOUN
eurjchem-1680	14	31	(	(	PUNCT
eurjchem-1680	14	32	1	1	X
eurjchem-1680	14	33	)	)	PUNCT
eurjchem-1680	14	34	was	be	AUX
eurjchem-1680	14	35	inadequate	inadequate	ADJ
eurjchem-1680	14	36	and	and	CCONJ
eurjchem-1680	14	37	the	the	DET
eurjchem-1680	14	38	two	two	NUM
eurjchem-1680	14	39	-	-	PUNCT
eurjchem-1680	14	40	term	term	NOUN
eurjchem-1680	14	41	(	(	PUNCT
eurjchem-1680	14	42	extended	extended	ADJ
eurjchem-1680	14	43	)	)	PUNCT
eurjchem-1680	14	44	grunwaldwinstein	grunwaldwinstein	VERB
eurjchem-1680	14	45	equation	equation	NOUN
eurjchem-1680	14	46	[	[	X
eurjchem-1680	14	47	8,9	8,9	NUM
eurjchem-1680	14	48	]	]	PUNCT
eurjchem-1680	14	49	was	be	AUX
eurjchem-1680	14	50	required	require	VERB
eurjchem-1680	14	51	(	(	PUNCT
eurjchem-1680	14	52	equation	equation	NOUN
eurjchem-1680	14	53	2	2	NUM
eurjchem-1680	14	54	)	)	PUNCT
eurjchem-1680	14	55	,	,	PUNCT
eurjchem-1680	14	56	where	where	SCONJ
eurjchem-1680	14	57	the	the	DET
eurjchem-1680	14	58	additional	additional	ADJ
eurjchem-1680	14	59	term	term	NOUN
eurjchem-1680	14	60	involves	involve	VERB
eurjchem-1680	14	61	the	the	DET
eurjchem-1680	14	62	sensitivity	sensitivity	NOUN
eurjchem-1680	14	63	l	l	NOUN
eurjchem-1680	14	64	to	to	ADP
eurjchem-1680	14	65	changes	change	NOUN
eurjchem-1680	14	66	in	in	ADP
eurjchem-1680	14	67	solvent	solvent	ADJ
eurjchem-1680	14	68	nucleophilicity	nucleophilicity	NOUN
eurjchem-1680	14	69	(	(	PUNCT
eurjchem-1680	14	70	nt	not	PART
eurjchem-1680	14	71	)	)	PUNCT
eurjchem-1680	14	72	.	.	PUNCT
eurjchem-1680	15	1	tables	table	NOUN
eurjchem-1680	15	2	of	of	ADP
eurjchem-1680	15	3	nt	nt	ADP
eurjchem-1680	15	4	values	value	NOUN
eurjchem-1680	15	5	are	be	AUX
eurjchem-1680	15	6	available	available	ADJ
eurjchem-1680	15	7	for	for	ADP
eurjchem-1680	15	8	a	a	DET
eurjchem-1680	15	9	wider	wide	ADJ
eurjchem-1680	15	10	variety	variety	NOUN
eurjchem-1680	15	11	of	of	ADP
eurjchem-1680	15	12	pure	pure	ADJ
eurjchem-1680	15	13	and	and	CCONJ
eurjchem-1680	15	14	binary	binary	ADJ
eurjchem-1680	15	15	solvents	solvent	NOUN
eurjchem-1680	15	16	[	[	X
eurjchem-1680	15	17	6,9	6,9	NUM
eurjchem-1680	15	18	]	]	PUNCT
eurjchem-1680	15	19	.	.	PUNCT
eurjchem-1680	16	1	log	log	NOUN
eurjchem-1680	16	2	(	(	PUNCT
eurjchem-1680	16	3	k	k	NOUN
eurjchem-1680	16	4	/	/	SYM
eurjchem-1680	16	5	ko)rx	ko)rx	NOUN
eurjchem-1680	16	6	=	=	SYM
eurjchem-1680	16	7	lnt	lnt	NOUN
eurjchem-1680	16	8	+	+	CCONJ
eurjchem-1680	16	9	myx	myx	NOUN
eurjchem-1680	16	10	+	+	X
eurjchem-1680	16	11	c	c	X
eurjchem-1680	16	12	(	(	PUNCT
eurjchem-1680	16	13	2	2	NUM
eurjchem-1680	16	14	)	)	PUNCT
eurjchem-1680	16	15	it	it	PRON
eurjchem-1680	16	16	is	be	AUX
eurjchem-1680	16	17	of	of	ADP
eurjchem-1680	16	18	interest	interest	NOUN
eurjchem-1680	16	19	to	to	PART
eurjchem-1680	16	20	investigate	investigate	VERB
eurjchem-1680	16	21	the	the	DET
eurjchem-1680	16	22	corresponding	corresponding	ADJ
eurjchem-1680	16	23	solvolysis	solvolysis	NOUN
eurjchem-1680	16	24	of	of	ADP
eurjchem-1680	16	25	the	the	DET
eurjchem-1680	16	26	tertiary	tertiary	ADJ
eurjchem-1680	16	27	alpha	alpha	NOUN
eurjchem-1680	16	28	-	-	PUNCT
eurjchem-1680	16	29	bromoketone	bromoketone	NOUN
eurjchem-1680	16	30	α	α	NOUN
eurjchem-1680	16	31	-	-	NOUN
eurjchem-1680	16	32	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	16	33	(	(	PUNCT
eurjchem-1680	16	34	2	2	NUM
eurjchem-1680	16	35	-	-	PUNCT
eurjchem-1680	16	36	benzoyl-2	benzoyl-2	NUM
eurjchem-1680	16	37	-	-	PUNCT
eurjchem-1680	16	38	bromopropane	bromopropane	NOUN
eurjchem-1680	16	39	,	,	PUNCT
eurjchem-1680	16	40	c6h5coc(ch3)2br	c6h5coc(ch3)2br	ADJ
eurjchem-1680	16	41	,	,	PUNCT
eurjchem-1680	16	42	2	2	NUM
eurjchem-1680	16	43	)	)	PUNCT
eurjchem-1680	16	44	(	(	PUNCT
eurjchem-1680	16	45	scheme	scheme	NOUN
eurjchem-1680	16	46	1	1	NUM
eurjchem-1680	16	47	)	)	PUNCT
eurjchem-1680	16	48	to	to	PART
eurjchem-1680	16	49	see	see	VERB
eurjchem-1680	16	50	whether	whether	SCONJ
eurjchem-1680	16	51	it	it	PRON
eurjchem-1680	16	52	follows	follow	VERB
eurjchem-1680	16	53	the	the	DET
eurjchem-1680	16	54	same	same	ADJ
eurjchem-1680	16	55	pathway	pathway	NOUN
eurjchem-1680	16	56	as	as	ADP
eurjchem-1680	16	57	1	1	NUM
eurjchem-1680	16	58	or	or	CCONJ
eurjchem-1680	16	59	whether	whether	SCONJ
eurjchem-1680	16	60	there	there	PRON
eurjchem-1680	16	61	is	be	VERB
eurjchem-1680	16	62	a	a	DET
eurjchem-1680	16	63	partial	partial	ADJ
eurjchem-1680	16	64	or	or	CCONJ
eurjchem-1680	16	65	complete	complete	ADJ
eurjchem-1680	16	66	movement	movement	NOUN
eurjchem-1680	16	67	towards	towards	ADP
eurjchem-1680	16	68	a	a	DET
eurjchem-1680	16	69	unimolecular	unimolecular	ADJ
eurjchem-1680	16	70	path	path	NOUN
eurjchem-1680	16	71	-	-	PUNCT
eurjchem-1680	16	72	way	way	NOUN
eurjchem-1680	16	73	involving	involve	VERB
eurjchem-1680	16	74	formation	formation	NOUN
eurjchem-1680	16	75	of	of	ADP
eurjchem-1680	16	76	a	a	DET
eurjchem-1680	16	77	carbocation	carbocation	NOUN
eurjchem-1680	16	78	,	,	PUNCT
eurjchem-1680	16	79	as	as	SCONJ
eurjchem-1680	16	80	has	have	VERB
eurjchem-1680	16	81	abstract	abstract	ADJ
eurjchem-1680	16	82	research	research	NOUN
eurjchem-1680	16	83	article	article	NOUN
eurjchem-1680	16	84	keywords	keyword	VERB
eurjchem-1680	16	85	european	european	PROPN
eurjchem-1680	16	86	journal	journal	PROPN
eurjchem-1680	16	87	of	of	ADP
eurjchem-1680	16	88	chemistry	chemistry	NOUN
eurjchem-1680	16	89	issn	issn	VERB
eurjchem-1680	16	90	2153	2153	NUM
eurjchem-1680	16	91	-	-	SYM
eurjchem-1680	16	92	2249	2249	NUM
eurjchem-1680	16	93	(	(	PUNCT
eurjchem-1680	16	94	print	print	NOUN
eurjchem-1680	16	95	)	)	PUNCT
eurjchem-1680	16	96	/	/	PUNCT
eurjchem-1680	16	97	issn	issn	PROPN
eurjchem-1680	16	98	2153	2153	NUM
eurjchem-1680	16	99	-	-	SYM
eurjchem-1680	16	100	2257	2257	NUM
eurjchem-1680	16	101	(	(	PUNCT
eurjchem-1680	16	102	online	online	ADJ
eurjchem-1680	16	103	)	)	PUNCT
eurjchem-1680	16	104	–	–	PUNCT
eurjchem-1680	17	1	copyright	copyright	NOUN
eurjchem-1680	17	2	©	©	PROPN
eurjchem-1680	17	3	2018	2018	NUM
eurjchem-1680	17	4	the	the	DET
eurjchem-1680	17	5	authors	author	NOUN
eurjchem-1680	17	6	–	–	PUNCT
eurjchem-1680	17	7	atlanta	atlanta	PROPN
eurjchem-1680	17	8	publishing	publishing	PROPN
eurjchem-1680	17	9	house	house	PROPN
eurjchem-1680	17	10	llc	llc	PROPN
eurjchem-1680	17	11	–	–	PUNCT
eurjchem-1680	17	12	printed	print	VERB
eurjchem-1680	17	13	in	in	ADP
eurjchem-1680	17	14	the	the	DET
eurjchem-1680	17	15	usa	usa	PROPN
eurjchem-1680	17	16	.	.	PUNCT
eurjchem-1680	18	1	this	this	DET
eurjchem-1680	18	2	work	work	NOUN
eurjchem-1680	18	3	is	be	AUX
eurjchem-1680	18	4	published	publish	VERB
eurjchem-1680	18	5	and	and	CCONJ
eurjchem-1680	18	6	licensed	license	VERB
eurjchem-1680	18	7	by	by	ADP
eurjchem-1680	18	8	atlanta	atlanta	PROPN
eurjchem-1680	18	9	publishing	publishing	PROPN
eurjchem-1680	18	10	house	house	PROPN
eurjchem-1680	18	11	llc	llc	PROPN
eurjchem-1680	18	12	–	–	PUNCT
eurjchem-1680	18	13	cc	cc	PROPN
eurjchem-1680	18	14	by	by	ADP
eurjchem-1680	18	15	nc	nc	PROPN
eurjchem-1680	18	16	–	–	PUNCT
eurjchem-1680	18	17	some	some	DET
eurjchem-1680	18	18	rights	right	NOUN
eurjchem-1680	18	19	reserved	reserve	VERB
eurjchem-1680	18	20	.	.	PUNCT
eurjchem-1680	19	1	http://dx.doi.org/10.5155/eurjchem.9.1.1-6.1680	http://dx.doi.org/10.5155/eurjchem.9.1.1-6.1680	VERB
eurjchem-1680	19	2	http://dx.doi.org/10.5155/eurjchem.9.1.1-6.1680	http://dx.doi.org/10.5155/eurjchem.9.1.1-6.1680	VERB
eurjchem-1680	19	3	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.1.1-6.1680&domain=pdf&date_stamp=2018-03-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.1.1-6.1680&domain=pdf&date_stamp=2018-03-31	NOUN
eurjchem-1680	19	4	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-1680	19	5	http://dx.doi.org/10.5155/eurjchem.9.1.1-6.1680	http://dx.doi.org/10.5155/eurjchem.9.1.1-6.1680	PROPN
eurjchem-1680	19	6	mailto:dkevill@niu.edu	mailto:dkevill@niu.edu	PROPN
eurjchem-1680	19	7	mailto:cbkim36@hanmail.net	mailto:cbkim36@hanmail.net	PROPN
eurjchem-1680	19	8	mailto:malcolm.dsouza@wesley.edu	mailto:malcolm.dsouza@wesley.edu	PROPN
eurjchem-1680	19	9	mailto:malcolm.dsouza@wesley.edu	mailto:malcolm.dsouza@wesley.edu	PROPN
eurjchem-1680	19	10	http://www.eurjchem.com/	http://www.eurjchem.com/	PROPN
eurjchem-1680	19	11	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.1.1-6.1680&domain=pdf&date_stamp=2018-03-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.1.1-6.1680&domain=pdf&date_stamp=2018-03-31	PROPN
eurjchem-1680	19	12	�	�	PROPN
eurjchem-1680	19	13	2	2	NUM
eurjchem-1680	19	14	kevill	kevill	NOUN
eurjchem-1680	19	15	et	et	PROPN
eurjchem-1680	19	16	al	al	PROPN
eurjchem-1680	19	17	.	.	PUNCT
eurjchem-1680	19	18	/	/	SYM
eurjchem-1680	19	19	european	european	PROPN
eurjchem-1680	19	20	journal	journal	PROPN
eurjchem-1680	19	21	of	of	ADP
eurjchem-1680	19	22	chemistry	chemistry	NOUN
eurjchem-1680	19	23	9	9	NUM
eurjchem-1680	19	24	(	(	PUNCT
eurjchem-1680	19	25	1	1	NUM
eurjchem-1680	19	26	)	)	PUNCT
eurjchem-1680	19	27	(	(	PUNCT
eurjchem-1680	19	28	2018	2018	NUM
eurjchem-1680	19	29	)	)	PUNCT
eurjchem-1680	19	30	1	1	NUM
eurjchem-1680	19	31	-	-	SYM
eurjchem-1680	19	32	6	6	NUM
eurjchem-1680	19	33	table	table	NOUN
eurjchem-1680	19	34	1	1	NUM
eurjchem-1680	19	35	.	.	PUNCT
eurjchem-1680	19	36	specific	specific	ADJ
eurjchem-1680	19	37	rates	rate	NOUN
eurjchem-1680	19	38	of	of	ADP
eurjchem-1680	19	39	solvolysis	solvolysis	NOUN
eurjchem-1680	19	40	(	(	PUNCT
eurjchem-1680	19	41	k2	k2	NOUN
eurjchem-1680	19	42	)	)	PUNCT
eurjchem-1680	19	43	for	for	ADP
eurjchem-1680	19	44	the	the	DET
eurjchem-1680	19	45	solvolysis	solvolysis	NOUN
eurjchem-1680	19	46	of	of	ADP
eurjchem-1680	19	47	α	α	NOUN
eurjchem-1680	19	48	-	-	NOUN
eurjchem-1680	19	49	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	19	50	(	(	PUNCT
eurjchem-1680	19	51	2	2	NUM
eurjchem-1680	19	52	)	)	PUNCT
eurjchem-1680	19	53	at	at	ADP
eurjchem-1680	19	54	62.5	62.5	NUM
eurjchem-1680	19	55	°	°	NOUN
eurjchem-1680	19	56	c	c	NOUN
eurjchem-1680	19	57	together	together	ADV
eurjchem-1680	19	58	with	with	ADP
eurjchem-1680	19	59	the	the	DET
eurjchem-1680	19	60	nt	nt	NOUN
eurjchem-1680	19	61	and	and	CCONJ
eurjchem-1680	19	62	ybr	ybr	PROPN
eurjchem-1680	19	63	values	value	NOUN
eurjchem-1680	19	64	for	for	ADP
eurjchem-1680	19	65	the	the	DET
eurjchem-1680	19	66	solvents	solvent	NOUN
eurjchem-1680	19	67	and	and	CCONJ
eurjchem-1680	19	68	the	the	DET
eurjchem-1680	19	69	ratio	ratio	NOUN
eurjchem-1680	19	70	of	of	ADP
eurjchem-1680	19	71	the	the	DET
eurjchem-1680	19	72	k2	k2	ADJ
eurjchem-1680	19	73	values	value	NOUN
eurjchem-1680	19	74	relative	relative	ADJ
eurjchem-1680	19	75	to	to	ADP
eurjchem-1680	19	76	the	the	DET
eurjchem-1680	19	77	corresponding	corresponding	ADJ
eurjchem-1680	19	78	values	value	NOUN
eurjchem-1680	19	79	for	for	ADP
eurjchem-1680	19	80	1	1	NUM
eurjchem-1680	19	81	(	(	PUNCT
eurjchem-1680	19	82	k2	k2	PROPN
eurjchem-1680	19	83	/	/	SYM
eurjchem-1680	19	84	k1	k1	NOUN
eurjchem-1680	19	85	)	)	PUNCT
eurjchem-1680	19	86	.	.	PUNCT
eurjchem-1680	20	1	solvent	solvent	PROPN
eurjchem-1680	20	2	a	a	DET
eurjchem-1680	20	3	107	107	NUM
eurjchem-1680	20	4	k2(s-1	k2(s-1	NOUN
eurjchem-1680	20	5	)	)	PUNCT
eurjchem-1680	20	6	b	b	NOUN
eurjchem-1680	20	7	nt	not	PART
eurjchem-1680	21	1	c	c	PROPN
eurjchem-1680	21	2	ybr	ybr	PROPN
eurjchem-1680	21	3	d	d	PROPN
eurjchem-1680	21	4	(	(	PUNCT
eurjchem-1680	21	5	k2	k2	PROPN
eurjchem-1680	21	6	/	/	SYM
eurjchem-1680	21	7	k1	k1	NOUN
eurjchem-1680	21	8	)	)	PUNCT
eurjchem-1680	21	9	e	e	NOUN
eurjchem-1680	21	10	90	90	NUM
eurjchem-1680	21	11	%	%	NOUN
eurjchem-1680	21	12	etoh	etoh	PROPN
eurjchem-1680	21	13	1.79±0.05	1.79±0.05	NOUN
eurjchem-1680	21	14	0.16	0.16	NUM
eurjchem-1680	21	15	-0.84	-0.84	NUM
eurjchem-1680	21	16	(	(	PUNCT
eurjchem-1680	21	17	0.038	0.038	NUM
eurjchem-1680	21	18	)	)	PUNCT
eurjchem-1680	21	19	f	f	PROPN
eurjchem-1680	21	20	80	80	NUM
eurjchem-1680	21	21	%	%	NOUN
eurjchem-1680	21	22	etoh	etoh	NOUN
eurjchem-1680	21	23	3.70±0.08	3.70±0.08	NUM
eurjchem-1680	21	24	0.00	0.00	NUM
eurjchem-1680	21	25	0.00	0.00	NUM
eurjchem-1680	21	26	0.090	0.090	NUM
eurjchem-1680	21	27	60	60	NUM
eurjchem-1680	21	28	%	%	NOUN
eurjchem-1680	21	29	etoh	etoh	NOUN
eurjchem-1680	21	30	12.1±0.6	12.1±0.6	NUM
eurjchem-1680	21	31	-0.39	-0.39	NUM
eurjchem-1680	21	32	1.26	1.26	NUM
eurjchem-1680	21	33	0.154	0.154	NUM
eurjchem-1680	21	34	40	40	NUM
eurjchem-1680	21	35	%	%	NOUN
eurjchem-1680	21	36	etoh	etoh	PROPN
eurjchem-1680	21	37	43.5±1.5	43.5±1.5	NUM
eurjchem-1680	21	38	-0.74	-0.74	VERB
eurjchem-1680	21	39	2.62	2.62	NUM
eurjchem-1680	21	40	0.316	0.316	NUM
eurjchem-1680	21	41	100	100	NUM
eurjchem-1680	21	42	%	%	NOUN
eurjchem-1680	21	43	meoh	meoh	NOUN
eurjchem-1680	21	44	2.29±0.08	2.29±0.08	NUM
eurjchem-1680	21	45	0.17	0.17	NUM
eurjchem-1680	21	46	-1.12	-1.12	NUM
eurjchem-1680	21	47	0.082	0.082	NUM
eurjchem-1680	21	48	90	90	NUM
eurjchem-1680	21	49	%	%	NOUN
eurjchem-1680	21	50	meoh	meoh	NOUN
eurjchem-1680	21	51	6.58±0.13	6.58±0.13	NUM
eurjchem-1680	21	52	-0.01	-0.01	NUM
eurjchem-1680	21	53	-0.14	-0.14	NOUN
eurjchem-1680	21	54	g	g	PROPN
eurjchem-1680	21	55	80	80	NUM
eurjchem-1680	21	56	%	%	NOUN
eurjchem-1680	21	57	meoh	meoh	NOUN
eurjchem-1680	21	58	11.7±0.4	11.7±0.4	NUM
eurjchem-1680	21	59	-0.06	-0.06	NUM
eurjchem-1680	21	60	0.70	0.70	NUM
eurjchem-1680	22	1	0.187	0.187	NUM
eurjchem-1680	22	2	60	60	NUM
eurjchem-1680	22	3	%	%	NOUN
eurjchem-1680	22	4	meoh	meoh	NOUN
eurjchem-1680	22	5	37.8±0.8	37.8±0.8	NUM
eurjchem-1680	22	6	-0.54	-0.54	NUM
eurjchem-1680	22	7	2.04	2.04	NUM
eurjchem-1680	22	8	0.332	0.332	NUM
eurjchem-1680	22	9	40	40	NUM
eurjchem-1680	22	10	%	%	NOUN
eurjchem-1680	22	11	meoh	meoh	NOUN
eurjchem-1680	22	12	106±5	106±5	NUM
eurjchem-1680	22	13	-0.87	-0.87	NUM
eurjchem-1680	22	14	3.14	3.14	NUM
eurjchem-1680	22	15	0.632	0.632	NUM
eurjchem-1680	22	16	80	80	NUM
eurjchem-1680	22	17	%	%	NOUN
eurjchem-1680	22	18	acetone	acetone	NOUN
eurjchem-1680	22	19	0.735±0.017	0.735±0.017	ADP
eurjchem-1680	22	20	-0.37	-0.37	NUM
eurjchem-1680	22	21	-0.7	-0.7	PROPN
eurjchem-1680	22	22	0.036	0.036	NUM
eurjchem-1680	22	23	60	60	NUM
eurjchem-1680	22	24	%	%	NOUN
eurjchem-1680	22	25	acetone	acetone	NOUN
eurjchem-1680	23	1	5.88±0.21	5.88±0.21	NOUN
eurjchem-1680	23	2	-0.52	-0.52	NUM
eurjchem-1680	23	3	1.03	1.03	NUM
eurjchem-1680	23	4	0.104	0.104	NUM
eurjchem-1680	23	5	80	80	NUM
eurjchem-1680	23	6	%	%	NOUN
eurjchem-1680	23	7	tfe	tfe	NOUN
eurjchem-1680	23	8	5.22±0.22	5.22±0.22	NOUN
eurjchem-1680	23	9	-2.19	-2.19	NUM
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eurjchem-1680	23	11	2.03	2.03	NUM
eurjchem-1680	23	12	60	60	NUM
eurjchem-1680	23	13	%	%	NOUN
eurjchem-1680	23	14	tfe	tfe	NOUN
eurjchem-1680	23	15	16.0±0.3	16.0±0.3	NUM
eurjchem-1680	23	16	-1.85	-1.85	NUM
eurjchem-1680	23	17	2.91	2.91	NUM
eurjchem-1680	23	18	1.55	1.55	NUM
eurjchem-1680	23	19	90	90	NUM
eurjchem-1680	23	20	%	%	NOUN
eurjchem-1680	23	21	hfip	hfip	NOUN
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eurjchem-1680	23	25	h	h	NOUN
eurjchem-1680	23	26	g	g	PROPN
eurjchem-1680	23	27	70	70	NUM
eurjchem-1680	23	28	%	%	NOUN
eurjchem-1680	23	29	hfip	hfip	PROPN
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eurjchem-1680	23	39	volume	volume	NOUN
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eurjchem-1680	23	48	tfe	tfe	NOUN
eurjchem-1680	23	49	-	-	PUNCT
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eurjchem-1680	23	52	hfip	hfip	PROPN
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eurjchem-1680	23	54	h2o	h2o	PROPN
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eurjchem-1680	23	59	a	a	DET
eurjchem-1680	23	60	weight	weight	NOUN
eurjchem-1680	23	61	-	-	PUNCT
eurjchem-1680	23	62	weight	weight	NOUN
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eurjchem-1680	24	1	b	b	X
eurjchem-1680	24	2	with	with	ADP
eurjchem-1680	24	3	associated	associated	ADJ
eurjchem-1680	24	4	standard	standard	ADJ
eurjchem-1680	24	5	deviation	deviation	NOUN
eurjchem-1680	24	6	.	.	PUNCT
eurjchem-1680	25	1	c	c	NOUN
eurjchem-1680	25	2	from	from	ADP
eurjchem-1680	25	3	ref	ref	NOUN
eurjchem-1680	25	4	.	.	PUNCT
eurjchem-1680	26	1	[	[	X
eurjchem-1680	26	2	6	6	NUM
eurjchem-1680	26	3	]	]	PUNCT
eurjchem-1680	26	4	.	.	PUNCT
eurjchem-1680	27	1	d	d	X
eurjchem-1680	27	2	unless	unless	SCONJ
eurjchem-1680	27	3	otherwise	otherwise	ADV
eurjchem-1680	27	4	stated	state	VERB
eurjchem-1680	27	5	,	,	PUNCT
eurjchem-1680	27	6	from	from	ADP
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eurjchem-1680	27	8	.	.	PUNCT
eurjchem-1680	28	1	[	[	X
eurjchem-1680	28	2	5	5	NUM
eurjchem-1680	28	3	]	]	PUNCT
eurjchem-1680	28	4	.	.	PUNCT
eurjchem-1680	29	1	e	e	X
eurjchem-1680	29	2	ratio	ratio	NOUN
eurjchem-1680	29	3	of	of	ADP
eurjchem-1680	29	4	the	the	DET
eurjchem-1680	29	5	specific	specific	ADJ
eurjchem-1680	29	6	rates	rate	NOUN
eurjchem-1680	29	7	of	of	ADP
eurjchem-1680	29	8	solvolysis	solvolysis	NOUN
eurjchem-1680	29	9	for	for	ADP
eurjchem-1680	29	10	2	2	NUM
eurjchem-1680	29	11	and	and	CCONJ
eurjchem-1680	29	12	1	1	NUM
eurjchem-1680	29	13	at	at	ADP
eurjchem-1680	29	14	62.5	62.5	NUM
eurjchem-1680	29	15	°	°	NOUN
eurjchem-1680	29	16	c	c	NOUN
eurjchem-1680	29	17	(	(	PUNCT
eurjchem-1680	29	18	k1	k1	NOUN
eurjchem-1680	29	19	values	value	NOUN
eurjchem-1680	29	20	from	from	ADP
eurjchem-1680	29	21	ref	ref	NOUN
eurjchem-1680	29	22	.	.	PUNCT
eurjchem-1680	30	1	[	[	X
eurjchem-1680	30	2	1	1	NUM
eurjchem-1680	30	3	]	]	PUNCT
eurjchem-1680	30	4	)	)	PUNCT
eurjchem-1680	30	5	.	.	PUNCT
eurjchem-1680	31	1	f	f	PROPN
eurjchem-1680	31	2	using	use	VERB
eurjchem-1680	31	3	the	the	DET
eurjchem-1680	31	4	averaged	average	VERB
eurjchem-1680	31	5	value	value	NOUN
eurjchem-1680	31	6	for	for	ADP
eurjchem-1680	31	7	k1	k1	NOUN
eurjchem-1680	31	8	(	(	PUNCT
eurjchem-1680	31	9	see	see	AUX
eurjchem-1680	31	10	footnote	footnote	VERB
eurjchem-1680	31	11	h	h	NOUN
eurjchem-1680	31	12	to	to	PART
eurjchem-1680	31	13	table	table	VERB
eurjchem-1680	31	14	1	1	NUM
eurjchem-1680	31	15	of	of	ADP
eurjchem-1680	31	16	ref	ref	NOUN
eurjchem-1680	31	17	.	.	PUNCT
eurjchem-1680	32	1	[	[	X
eurjchem-1680	32	2	1	1	NUM
eurjchem-1680	32	3	]	]	PUNCT
eurjchem-1680	32	4	)	)	PUNCT
eurjchem-1680	32	5	.	.	PUNCT
eurjchem-1680	33	1	g	g	PROPN
eurjchem-1680	33	2	the	the	DET
eurjchem-1680	33	3	k1	k1	PROPN
eurjchem-1680	33	4	value	value	NOUN
eurjchem-1680	33	5	is	be	AUX
eurjchem-1680	33	6	not	not	PART
eurjchem-1680	33	7	available	available	ADJ
eurjchem-1680	33	8	.	.	PUNCT
eurjchem-1680	34	1	h	h	NOUN
eurjchem-1680	34	2	from	from	ADP
eurjchem-1680	34	3	ref	ref	NOUN
eurjchem-1680	34	4	.	.	PUNCT
eurjchem-1680	35	1	[	[	X
eurjchem-1680	35	2	20	20	NUM
eurjchem-1680	35	3	]	]	PUNCT
eurjchem-1680	35	4	.	.	PUNCT
eurjchem-1680	36	1	mso	mso	PROPN
eurjchem-1680	36	2	o	o	PROPN
eurjchem-1680	36	3	och3	och3	ADJ
eurjchem-1680	36	4	3	3	NUM
eurjchem-1680	36	5	mso	mso	NOUN
eurjchem-1680	36	6	o	o	NOUN
eurjchem-1680	36	7	ph	ph	NOUN
eurjchem-1680	36	8	mso	mso	NOUN
eurjchem-1680	36	9	o	o	NOUN
eurjchem-1680	36	10	4	4	NUM
eurjchem-1680	36	11	5	5	NUM
eurjchem-1680	36	12	r	r	NOUN
eurjchem-1680	36	13	o	o	NOUN
eurjchem-1680	36	14	6	6	NUM
eurjchem-1680	36	15	o	o	NOUN
eurjchem-1680	36	16	br	br	NOUN
eurjchem-1680	37	1	1	1	NUM
eurjchem-1680	37	2	br	br	NOUN
eurjchem-1680	37	3	o	o	NOUN
eurjchem-1680	37	4	2	2	NUM
eurjchem-1680	37	5	oms	om	NOUN
eurjchem-1680	37	6	ph	ph	X
eurjchem-1680	37	7	o	o	NOUN
eurjchem-1680	37	8	7	7	NUM
eurjchem-1680	37	9	(	(	PUNCT
eurjchem-1680	37	10	a	a	X
eurjchem-1680	37	11	,	,	PUNCT
eurjchem-1680	37	12	r	r	NOUN
eurjchem-1680	37	13	=	=	SYM
eurjchem-1680	37	14	(	(	PUNCT
eurjchem-1680	37	15	ch3)3c	ch3)3c	PROPN
eurjchem-1680	37	16	;	;	PUNCT
eurjchem-1680	37	17	b	b	X
eurjchem-1680	37	18	,	,	PUNCT
eurjchem-1680	37	19	r	r	NOUN
eurjchem-1680	37	20	=	=	SYM
eurjchem-1680	37	21	ph	ph	NOUN
eurjchem-1680	37	22	)	)	PUNCT
eurjchem-1680	37	23	scheme	scheme	NOUN
eurjchem-1680	37	24	1	1	NUM
eurjchem-1680	37	25	been	be	AUX
eurjchem-1680	37	26	proposed	propose	VERB
eurjchem-1680	37	27	for	for	ADP
eurjchem-1680	37	28	the	the	DET
eurjchem-1680	37	29	solvolyses	solvolyse	NOUN
eurjchem-1680	37	30	of	of	ADP
eurjchem-1680	37	31	several	several	ADJ
eurjchem-1680	37	32	tertiary	tertiary	ADJ
eurjchem-1680	37	33	ketones	ketone	NOUN
eurjchem-1680	37	34	related	relate	VERB
eurjchem-1680	37	35	to	to	ADP
eurjchem-1680	37	36	2	2	NUM
eurjchem-1680	37	37	but	but	CCONJ
eurjchem-1680	37	38	with	with	ADP
eurjchem-1680	37	39	a	a	DET
eurjchem-1680	37	40	considerably	considerably	ADV
eurjchem-1680	37	41	more	more	ADV
eurjchem-1680	37	42	effective	effective	ADJ
eurjchem-1680	37	43	leaving	leave	VERB
eurjchem-1680	37	44	group	group	NOUN
eurjchem-1680	37	45	(	(	PUNCT
eurjchem-1680	37	46	nucleofuge	nucleofuge	NOUN
eurjchem-1680	37	47	)	)	PUNCT
eurjchem-1680	37	48	such	such	ADJ
eurjchem-1680	37	49	as	as	ADP
eurjchem-1680	37	50	methanesulfonate	methanesulfonate	NOUN
eurjchem-1680	37	51	(	(	PUNCT
eurjchem-1680	37	52	mesylate	mesylate	NOUN
eurjchem-1680	37	53	)	)	PUNCT
eurjchem-1680	37	54	or	or	CCONJ
eurjchem-1680	37	55	trifluoromethanesulfonate	trifluoromethanesulfonate	ADJ
eurjchem-1680	37	56	(	(	PUNCT
eurjchem-1680	37	57	triflate	triflate	NOUN
eurjchem-1680	37	58	)	)	PUNCT
eurjchem-1680	38	1	[	[	X
eurjchem-1680	38	2	10	10	NUM
eurjchem-1680	38	3	-	-	SYM
eurjchem-1680	38	4	12	12	NUM
eurjchem-1680	38	5	]	]	PUNCT
eurjchem-1680	38	6	.	.	PUNCT
eurjchem-1680	39	1	an	an	DET
eurjchem-1680	39	2	alternative	alternative	ADJ
eurjchem-1680	39	3	approach	approach	NOUN
eurjchem-1680	39	4	for	for	ADP
eurjchem-1680	39	5	generating	generate	VERB
eurjchem-1680	39	6	carbocations	carbocation	NOUN
eurjchem-1680	39	7	,	,	PUNCT
eurjchem-1680	39	8	with	with	ADP
eurjchem-1680	39	9	the	the	DET
eurjchem-1680	39	10	charge	charge	NOUN
eurjchem-1680	39	11	primarily	primarily	ADV
eurjchem-1680	39	12	at	at	ADP
eurjchem-1680	39	13	the	the	DET
eurjchem-1680	39	14	α	α	NOUN
eurjchem-1680	39	15	-	-	NOUN
eurjchem-1680	39	16	carbon	carbon	NOUN
eurjchem-1680	39	17	,	,	PUNCT
eurjchem-1680	39	18	is	be	AUX
eurjchem-1680	39	19	to	to	PART
eurjchem-1680	39	20	use	use	VERB
eurjchem-1680	39	21	tertiary	tertiary	ADJ
eurjchem-1680	39	22	α	α	NOUN
eurjchem-1680	39	23	-	-	NOUN
eurjchem-1680	39	24	haloketones	haloketone	NOUN
eurjchem-1680	39	25	in	in	ADP
eurjchem-1680	39	26	the	the	DET
eurjchem-1680	39	27	presence	presence	NOUN
eurjchem-1680	39	28	of	of	ADP
eurjchem-1680	39	29	silver	silver	NOUN
eurjchem-1680	39	30	-	-	PUNCT
eurjchem-1680	39	31	ion	ion	NOUN
eurjchem-1680	39	32	[	[	X
eurjchem-1680	39	33	13	13	NUM
eurjchem-1680	39	34	]	]	PUNCT
eurjchem-1680	39	35	,	,	PUNCT
eurjchem-1680	39	36	with	with	ADP
eurjchem-1680	39	37	the	the	DET
eurjchem-1680	39	38	complexation	complexation	NOUN
eurjchem-1680	39	39	of	of	ADP
eurjchem-1680	39	40	the	the	DET
eurjchem-1680	39	41	chlorine	chlorine	NOUN
eurjchem-1680	39	42	,	,	PUNCT
eurjchem-1680	39	43	bromine	bromine	NOUN
eurjchem-1680	39	44	or	or	CCONJ
eurjchem-1680	39	45	iodine	iodine	NOUN
eurjchem-1680	39	46	with	with	ADP
eurjchem-1680	39	47	the	the	DET
eurjchem-1680	39	48	silver	silver	NOUN
eurjchem-1680	39	49	-	-	PUNCT
eurjchem-1680	39	50	ion	ion	NOUN
eurjchem-1680	39	51	providing	provide	VERB
eurjchem-1680	39	52	an	an	DET
eurjchem-1680	39	53	alternative	alternative	ADJ
eurjchem-1680	39	54	route	route	NOUN
eurjchem-1680	39	55	to	to	ADP
eurjchem-1680	39	56	an	an	DET
eurjchem-1680	39	57	effective	effective	ADJ
eurjchem-1680	39	58	leaving	leaving	NOUN
eurjchem-1680	39	59	group	group	NOUN
eurjchem-1680	39	60	[	[	X
eurjchem-1680	39	61	14	14	NUM
eurjchem-1680	39	62	]	]	PUNCT
eurjchem-1680	39	63	.	.	PUNCT
eurjchem-1680	40	1	in	in	ADP
eurjchem-1680	40	2	an	an	DET
eurjchem-1680	40	3	earlier	early	ADJ
eurjchem-1680	40	4	study	study	NOUN
eurjchem-1680	40	5	,	,	PUNCT
eurjchem-1680	40	6	pasto	pasto	NOUN
eurjchem-1680	40	7	and	and	CCONJ
eurjchem-1680	40	8	sevenair	sevenair	VERB
eurjchem-1680	40	9	[	[	X
eurjchem-1680	40	10	15	15	NUM
eurjchem-1680	40	11	]	]	PUNCT
eurjchem-1680	40	12	found	find	VERB
eurjchem-1680	40	13	that	that	SCONJ
eurjchem-1680	40	14	the	the	DET
eurjchem-1680	40	15	solvolyses	solvolyse	NOUN
eurjchem-1680	40	16	of	of	ADP
eurjchem-1680	40	17	2	2	NUM
eurjchem-1680	40	18	proceeded	proceed	VERB
eurjchem-1680	40	19	extremely	extremely	ADV
eurjchem-1680	40	20	slowly	slowly	ADV
eurjchem-1680	40	21	in	in	ADP
eurjchem-1680	40	22	75	75	NUM
eurjchem-1680	40	23	%	%	NOUN
eurjchem-1680	40	24	aqueous	aqueous	ADJ
eurjchem-1680	40	25	ethanol	ethanol	NOUN
eurjchem-1680	40	26	(	(	PUNCT
eurjchem-1680	40	27	by	by	ADP
eurjchem-1680	40	28	weight	weight	NOUN
eurjchem-1680	40	29	)	)	PUNCT
eurjchem-1680	40	30	,	,	PUNCT
eurjchem-1680	40	31	with	with	ADP
eurjchem-1680	40	32	less	less	ADJ
eurjchem-1680	40	33	than	than	ADP
eurjchem-1680	40	34	2	2	NUM
eurjchem-1680	40	35	%	%	NOUN
eurjchem-1680	40	36	reaction	reaction	NOUN
eurjchem-1680	40	37	after	after	ADP
eurjchem-1680	40	38	13	13	NUM
eurjchem-1680	40	39	days	day	NOUN
eurjchem-1680	40	40	at	at	ADP
eurjchem-1680	40	41	25	25	NUM
eurjchem-1680	40	42	°	°	NOUN
eurjchem-1680	40	43	c	c	NOUN
eurjchem-1680	40	44	.	.	PUNCT
eurjchem-1680	41	1	we	we	PRON
eurjchem-1680	41	2	have	have	AUX
eurjchem-1680	41	3	found	find	VERB
eurjchem-1680	41	4	,	,	PUNCT
eurjchem-1680	41	5	however	however	ADV
eurjchem-1680	41	6	,	,	PUNCT
eurjchem-1680	41	7	that	that	SCONJ
eurjchem-1680	41	8	,	,	PUNCT
eurjchem-1680	41	9	with	with	ADP
eurjchem-1680	41	10	the	the	DET
eurjchem-1680	41	11	use	use	NOUN
eurjchem-1680	41	12	of	of	ADP
eurjchem-1680	41	13	sealed	seal	VERB
eurjchem-1680	41	14	ampoules	ampoule	NOUN
eurjchem-1680	41	15	,	,	PUNCT
eurjchem-1680	41	16	the	the	DET
eurjchem-1680	41	17	specific	specific	ADJ
eurjchem-1680	41	18	rates	rate	NOUN
eurjchem-1680	41	19	can	can	AUX
eurjchem-1680	41	20	be	be	AUX
eurjchem-1680	41	21	obtained	obtain	VERB
eurjchem-1680	41	22	for	for	ADP
eurjchem-1680	41	23	solvolyses	solvolyse	NOUN
eurjchem-1680	41	24	in	in	ADP
eurjchem-1680	41	25	a	a	DET
eurjchem-1680	41	26	wide	wide	ADJ
eurjchem-1680	41	27	variety	variety	NOUN
eurjchem-1680	41	28	of	of	ADP
eurjchem-1680	41	29	solvents	solvent	NOUN
eurjchem-1680	41	30	when	when	SCONJ
eurjchem-1680	41	31	the	the	DET
eurjchem-1680	41	32	temperature	temperature	NOUN
eurjchem-1680	41	33	is	be	AUX
eurjchem-1680	41	34	elevated	elevate	VERB
eurjchem-1680	41	35	to	to	ADP
eurjchem-1680	41	36	62.5	62.5	NUM
eurjchem-1680	41	37	°	°	NOUN
eurjchem-1680	41	38	c	c	NOUN
eurjchem-1680	41	39	.	.	NOUN
eurjchem-1680	42	1	2	2	X
eurjchem-1680	42	2	.	.	X
eurjchem-1680	42	3	experimental	experimental	VERB
eurjchem-1680	42	4	the	the	DET
eurjchem-1680	42	5	α	α	NOUN
eurjchem-1680	42	6	-	-	PUNCT
eurjchem-1680	42	7	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	42	8	(	(	PUNCT
eurjchem-1680	42	9	aldrich	aldrich	PROPN
eurjchem-1680	42	10	,	,	PUNCT
eurjchem-1680	42	11	98	98	NUM
eurjchem-1680	42	12	%	%	NOUN
eurjchem-1680	42	13	,	,	PUNCT
eurjchem-1680	42	14	2	2	NUM
eurjchem-1680	42	15	)	)	PUNCT
eurjchem-1680	42	16	was	be	AUX
eurjchem-1680	42	17	used	use	VERB
eurjchem-1680	42	18	as	as	SCONJ
eurjchem-1680	42	19	received	receive	VERB
eurjchem-1680	42	20	.	.	PUNCT
eurjchem-1680	43	1	the	the	DET
eurjchem-1680	43	2	purifications	purification	NOUN
eurjchem-1680	43	3	of	of	ADP
eurjchem-1680	43	4	acetone	acetone	NOUN
eurjchem-1680	43	5	[	[	X
eurjchem-1680	43	6	12	12	NUM
eurjchem-1680	43	7	]	]	PUNCT
eurjchem-1680	43	8	,	,	PUNCT
eurjchem-1680	43	9	ethanol	ethanol	NOUN
eurjchem-1680	43	10	[	[	X
eurjchem-1680	43	11	16	16	NUM
eurjchem-1680	43	12	]	]	PUNCT
eurjchem-1680	43	13	,	,	PUNCT
eurjchem-1680	43	14	methanol	methanol	NOUN
eurjchem-1680	43	15	[	[	X
eurjchem-1680	43	16	16	16	NUM
eurjchem-1680	43	17	]	]	PUNCT
eurjchem-1680	43	18	,	,	PUNCT
eurjchem-1680	43	19	2,2,2	2,2,2	NUM
eurjchem-1680	43	20	-	-	NOUN
eurjchem-1680	43	21	trifluoroethanol	trifluoroethanol	NOUN
eurjchem-1680	43	22	(	(	PUNCT
eurjchem-1680	43	23	tfe	tfe	NOUN
eurjchem-1680	43	24	)	)	PUNCT
eurjchem-1680	44	1	[	[	X
eurjchem-1680	44	2	17	17	NUM
eurjchem-1680	44	3	]	]	PUNCT
eurjchem-1680	44	4	,	,	PUNCT
eurjchem-1680	44	5	and	and	CCONJ
eurjchem-1680	44	6	1,1,1,3,3,3	1,1,1,3,3,3	NUM
eurjchem-1680	44	7	-	-	PUNCT
eurjchem-1680	44	8	hexafluoro-2	hexafluoro-2	NOUN
eurjchem-1680	44	9	-	-	PUNCT
eurjchem-1680	44	10	propanol	propanol	NOUN
eurjchem-1680	44	11	(	(	PUNCT
eurjchem-1680	44	12	hfip)[18	hfip)[18	NOUN
eurjchem-1680	44	13	]	]	PUNCT
eurjchem-1680	44	14	were	be	AUX
eurjchem-1680	44	15	as	as	ADV
eurjchem-1680	44	16	previously	previously	ADV
eurjchem-1680	44	17	described	describe	VERB
eurjchem-1680	44	18	.	.	PUNCT
eurjchem-1680	45	1	all	all	DET
eurjchem-1680	45	2	kinetic	kinetic	ADJ
eurjchem-1680	45	3	runs	run	NOUN
eurjchem-1680	45	4	were	be	AUX
eurjchem-1680	45	5	performed	perform	VERB
eurjchem-1680	45	6	with	with	ADP
eurjchem-1680	45	7	5×10	5×10	NUM
eurjchem-1680	45	8	-	-	SYM
eurjchem-1680	45	9	3	3	NUM
eurjchem-1680	45	10	m	m	NOUN
eurjchem-1680	45	11	substrate	substrate	NOUN
eurjchem-1680	45	12	in	in	ADP
eurjchem-1680	45	13	the	the	DET
eurjchem-1680	45	14	appropriate	appropriate	ADJ
eurjchem-1680	45	15	solvent	solvent	NOUN
eurjchem-1680	45	16	contained	contain	VERB
eurjchem-1680	45	17	within	within	ADP
eurjchem-1680	45	18	sealed	seal	VERB
eurjchem-1680	45	19	tubes	tube	NOUN
eurjchem-1680	45	20	at	at	ADP
eurjchem-1680	45	21	62.5	62.5	NUM
eurjchem-1680	45	22	°	°	NOUN
eurjchem-1680	45	23	c	c	NOUN
eurjchem-1680	45	24	,	,	PUNCT
eurjchem-1680	45	25	usually	usually	ADV
eurjchem-1680	45	26	with	with	ADP
eurjchem-1680	45	27	5	5	NUM
eurjchem-1680	45	28	ml	ml	NOUN
eurjchem-1680	45	29	aliquots	aliquot	NOUN
eurjchem-1680	45	30	,	,	PUNCT
eurjchem-1680	45	31	but	but	CCONJ
eurjchem-1680	45	32	with	with	ADP
eurjchem-1680	45	33	2	2	NUM
eurjchem-1680	45	34	ml	ml	NOUN
eurjchem-1680	45	35	aliquots	aliquot	NOUN
eurjchem-1680	45	36	for	for	ADP
eurjchem-1680	45	37	the	the	DET
eurjchem-1680	45	38	runs	run	NOUN
eurjchem-1680	45	39	in	in	ADP
eurjchem-1680	45	40	hfip	hfip	PROPN
eurjchem-1680	45	41	-	-	PUNCT
eurjchem-1680	45	42	h2o	h2o	PROPN
eurjchem-1680	45	43	mixtures	mixture	NOUN
eurjchem-1680	45	44	.	.	PUNCT
eurjchem-1680	46	1	at	at	ADP
eurjchem-1680	46	2	appropriate	appropriate	ADJ
eurjchem-1680	46	3	time	time	NOUN
eurjchem-1680	46	4	intervals	interval	NOUN
eurjchem-1680	46	5	,	,	PUNCT
eurjchem-1680	46	6	the	the	DET
eurjchem-1680	46	7	aliquots	aliquot	NOUN
eurjchem-1680	46	8	were	be	AUX
eurjchem-1680	46	9	removed	remove	VERB
eurjchem-1680	46	10	and	and	CCONJ
eurjchem-1680	46	11	quenched	quench	VERB
eurjchem-1680	46	12	by	by	ADP
eurjchem-1680	46	13	addition	addition	NOUN
eurjchem-1680	46	14	to	to	ADP
eurjchem-1680	46	15	20	20	NUM
eurjchem-1680	46	16	ml	ml	NOUN
eurjchem-1680	46	17	of	of	ADP
eurjchem-1680	46	18	acetone	acetone	NOUN
eurjchem-1680	46	19	maintained	maintain	VERB
eurjchem-1680	46	20	at	at	ADP
eurjchem-1680	46	21	solid	solid	ADJ
eurjchem-1680	46	22	co2	co2	NOUN
eurjchem-1680	46	23	-	-	PUNCT
eurjchem-1680	46	24	acetone	acetone	NOUN
eurjchem-1680	46	25	slush	slush	NOUN
eurjchem-1680	46	26	temperature	temperature	NOUN
eurjchem-1680	46	27	and	and	CCONJ
eurjchem-1680	46	28	containing	contain	VERB
eurjchem-1680	46	29	resorcinol	resorcinol	NOUN
eurjchem-1680	46	30	blue	blue	NOUN
eurjchem-1680	46	31	(	(	PUNCT
eurjchem-1680	46	32	lacmoid	lacmoid	NOUN
eurjchem-1680	46	33	)	)	PUNCT
eurjchem-1680	46	34	as	as	ADP
eurjchem-1680	46	35	indicator	indicator	NOUN
eurjchem-1680	46	36	.	.	PUNCT
eurjchem-1680	47	1	the	the	DET
eurjchem-1680	47	2	acid	acid	NOUN
eurjchem-1680	47	3	produced	produce	VERB
eurjchem-1680	47	4	was	be	AUX
eurjchem-1680	47	5	then	then	ADV
eurjchem-1680	47	6	determined	determine	VERB
eurjchem-1680	47	7	by	by	ADP
eurjchem-1680	47	8	titration	titration	NOUN
eurjchem-1680	47	9	against	against	ADP
eurjchem-1680	47	10	a	a	DET
eurjchem-1680	47	11	standardized	standardized	ADJ
eurjchem-1680	47	12	solution	solution	NOUN
eurjchem-1680	47	13	of	of	ADP
eurjchem-1680	47	14	triethylamine	triethylamine	NOUN
eurjchem-1680	47	15	in	in	ADP
eurjchem-1680	47	16	toluene	toluene	NOUN
eurjchem-1680	47	17	.	.	PUNCT
eurjchem-1680	48	1	for	for	ADP
eurjchem-1680	48	2	the	the	DET
eurjchem-1680	48	3	runs	run	NOUN
eurjchem-1680	48	4	in	in	ADP
eurjchem-1680	48	5	100	100	NUM
eurjchem-1680	48	6	%	%	NOUN
eurjchem-1680	48	7	meoh	meoh	NOUN
eurjchem-1680	48	8	,	,	PUNCT
eurjchem-1680	48	9	loss	loss	NOUN
eurjchem-1680	48	10	of	of	ADP
eurjchem-1680	48	11	hbr	hbr	PROPN
eurjchem-1680	48	12	by	by	ADP
eurjchem-1680	48	13	reaction	reaction	NOUN
eurjchem-1680	48	14	with	with	ADP
eurjchem-1680	48	15	the	the	DET
eurjchem-1680	48	16	solvent	solvent	NOUN
eurjchem-1680	48	17	,	,	PUNCT
eurjchem-1680	48	18	was	be	AUX
eurjchem-1680	48	19	prevented	prevent	VERB
eurjchem-1680	48	20	by	by	ADP
eurjchem-1680	48	21	the	the	DET
eurjchem-1680	48	22	addition	addition	NOUN
eurjchem-1680	48	23	of	of	ADP
eurjchem-1680	48	24	5.5×10	5.5×10	NUM
eurjchem-1680	48	25	-	-	SYM
eurjchem-1680	48	26	3	3	NUM
eurjchem-1680	48	27	m	m	NOUN
eurjchem-1680	48	28	lutidine	lutidine	NOUN
eurjchem-1680	48	29	(	(	PUNCT
eurjchem-1680	48	30	2,6	2,6	NUM
eurjchem-1680	48	31	-	-	NOUN
eurjchem-1680	48	32	dimethylpyridine	dimethylpyridine	NOUN
eurjchem-1680	48	33	,	,	PUNCT
eurjchem-1680	48	34	aldrich	aldrich	PROPN
eurjchem-1680	48	35	99	99	NUM
eurjchem-1680	48	36	%	%	NOUN
eurjchem-1680	48	37	)	)	PUNCT
eurjchem-1680	49	1	[	[	X
eurjchem-1680	49	2	1	1	NUM
eurjchem-1680	49	3	]	]	PUNCT
eurjchem-1680	49	4	.	.	PUNCT
eurjchem-1680	50	1	the	the	DET
eurjchem-1680	50	2	determinations	determination	NOUN
eurjchem-1680	50	3	of	of	ADP
eurjchem-1680	50	4	the	the	DET
eurjchem-1680	50	5	specific	specific	ADJ
eurjchem-1680	50	6	rates	rate	NOUN
eurjchem-1680	50	7	(	(	PUNCT
eurjchem-1680	50	8	first	first	ADJ
eurjchem-1680	50	9	-	-	PUNCT
eurjchem-1680	50	10	order	order	NOUN
eurjchem-1680	50	11	rate	rate	NOUN
eurjchem-1680	50	12	coefficients	coefficient	NOUN
eurjchem-1680	50	13	)	)	PUNCT
eurjchem-1680	50	14	for	for	ADP
eurjchem-1680	50	15	solvolysis	solvolysis	NOUN
eurjchem-1680	50	16	were	be	AUX
eurjchem-1680	50	17	as	as	ADP
eurjchem-1680	50	18	previous	previous	ADJ
eurjchem-1680	50	19	described	describe	VERB
eurjchem-1680	50	20	[	[	X
eurjchem-1680	50	21	9	9	NUM
eurjchem-1680	50	22	]	]	PUNCT
eurjchem-1680	50	23	.	.	PUNCT
eurjchem-1680	51	1	the	the	DET
eurjchem-1680	51	2	regression	regression	NOUN
eurjchem-1680	51	3	analyses	analysis	NOUN
eurjchem-1680	51	4	were	be	AUX
eurjchem-1680	51	5	carried	carry	VERB
eurjchem-1680	51	6	out	out	ADP
eurjchem-1680	51	7	using	use	VERB
eurjchem-1680	51	8	commercially	commercially	ADV
eurjchem-1680	51	9	available	available	ADJ
eurjchem-1680	51	10	statistical	statistical	ADJ
eurjchem-1680	51	11	packages	package	NOUN
eurjchem-1680	51	12	.	.	PUNCT
eurjchem-1680	52	1	3	3	X
eurjchem-1680	52	2	.	.	NOUN
eurjchem-1680	52	3	results	result	NOUN
eurjchem-1680	52	4	and	and	CCONJ
eurjchem-1680	52	5	discussion	discussion	VERB
eurjchem-1680	52	6	the	the	DET
eurjchem-1680	52	7	specific	specific	ADJ
eurjchem-1680	52	8	rates	rate	NOUN
eurjchem-1680	52	9	of	of	ADP
eurjchem-1680	52	10	solvolysis	solvolysis	NOUN
eurjchem-1680	52	11	of	of	ADP
eurjchem-1680	52	12	α	α	NOUN
eurjchem-1680	52	13	-	-	NOUN
eurjchem-1680	52	14	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	52	15	(	(	PUNCT
eurjchem-1680	52	16	2	2	NUM
eurjchem-1680	52	17	)	)	PUNCT
eurjchem-1680	52	18	in	in	ADP
eurjchem-1680	52	19	a	a	DET
eurjchem-1680	52	20	variety	variety	NOUN
eurjchem-1680	52	21	of	of	ADP
eurjchem-1680	52	22	solvents	solvent	NOUN
eurjchem-1680	52	23	at	at	ADP
eurjchem-1680	52	24	62.5	62.5	NUM
eurjchem-1680	52	25	°	°	NOUN
eurjchem-1680	52	26	c	c	NOUN
eurjchem-1680	52	27	are	be	AUX
eurjchem-1680	52	28	presented	present	VERB
eurjchem-1680	52	29	in	in	ADP
eurjchem-1680	52	30	table	table	NOUN
eurjchem-1680	52	31	1	1	NUM
eurjchem-1680	52	32	.	.	PUNCT
eurjchem-1680	53	1	all	all	PRON
eurjchem-1680	53	2	of	of	ADP
eurjchem-1680	53	3	the	the	DET
eurjchem-1680	53	4	integrated	integrate	VERB
eurjchem-1680	53	5	values	value	NOUN
eurjchem-1680	53	6	from	from	ADP
eurjchem-1680	53	7	the	the	PRON
eurjchem-1680	53	8	,	,	PUNCT
eurjchem-1680	53	9	at	at	ADP
eurjchem-1680	53	10	least	least	ADJ
eurjchem-1680	53	11	,	,	PUNCT
eurjchem-1680	53	12	duplicate	duplicate	ADJ
eurjchem-1680	53	13	runs	run	NOUN
eurjchem-1680	53	14	are	be	AUX
eurjchem-1680	53	15	averaged	average	VERB
eurjchem-1680	53	16	and	and	CCONJ
eurjchem-1680	53	17	the	the	DET
eurjchem-1680	53	18	average	average	ADJ
eurjchem-1680	53	19	values	value	NOUN
eurjchem-1680	53	20	together	together	ADV
eurjchem-1680	53	21	with	with	ADP
eurjchem-1680	53	22	the	the	DET
eurjchem-1680	53	23	standard	standard	ADJ
eurjchem-1680	53	24	deviation	deviation	NOUN
eurjchem-1680	53	25	are	be	AUX
eurjchem-1680	53	26	reported	report	VERB
eurjchem-1680	53	27	.	.	PUNCT
eurjchem-1680	54	1	also	also	ADV
eurjchem-1680	54	2	presented	present	VERB
eurjchem-1680	54	3	within	within	ADP
eurjchem-1680	54	4	the	the	DET
eurjchem-1680	54	5	table	table	NOUN
eurjchem-1680	54	6	are	be	AUX
eurjchem-1680	54	7	the	the	DET
eurjchem-1680	54	8	relevant	relevant	ADJ
eurjchem-1680	54	9	solvent	solvent	NOUN
eurjchem-1680	54	10	nucleophilicity	nucleophilicity	NOUN
eurjchem-1680	54	11	(	(	PUNCT
eurjchem-1680	54	12	nt)[6	nt)[6	NOUN
eurjchem-1680	54	13	]	]	X
eurjchem-1680	54	14	and	and	CCONJ
eurjchem-1680	54	15	ionizing	ionize	VERB
eurjchem-1680	54	16	power	power	NOUN
eurjchem-1680	54	17	(	(	PUNCT
eurjchem-1680	54	18	ybr	ybr	PROPN
eurjchem-1680	54	19	)	)	PUNCT
eurjchem-1680	55	1	[	[	X
eurjchem-1680	55	2	5,19,20	5,19,20	NUM
eurjchem-1680	55	3	]	]	PUNCT
eurjchem-1680	55	4	values	value	NOUN
eurjchem-1680	55	5	used	use	VERB
eurjchem-1680	55	6	in	in	ADP
eurjchem-1680	55	7	the	the	DET
eurjchem-1680	55	8	simple	simple	ADJ
eurjchem-1680	55	9	and	and	CCONJ
eurjchem-1680	55	10	multiple	multiple	ADJ
eurjchem-1680	55	11	regression	regression	NOUN
eurjchem-1680	55	12	analyses	analysis	NOUN
eurjchem-1680	55	13	,	,	PUNCT
eurjchem-1680	55	14	together	together	ADV
eurjchem-1680	55	15	,	,	PUNCT
eurjchem-1680	55	16	when	when	SCONJ
eurjchem-1680	55	17	both	both	DET
eurjchem-1680	55	18	specific	specific	ADJ
eurjchem-1680	55	19	rates	rate	NOUN
eurjchem-1680	55	20	are	be	AUX
eurjchem-1680	55	21	available	available	ADJ
eurjchem-1680	55	22	,	,	PUNCT
eurjchem-1680	55	23	with	with	ADP
eurjchem-1680	55	24	the	the	DET
eurjchem-1680	55	25	ratio	ratio	NOUN
eurjchem-1680	55	26	of	of	ADP
eurjchem-1680	55	27	the	the	DET
eurjchem-1680	55	28	specific	specific	ADJ
eurjchem-1680	55	29	rate	rate	NOUN
eurjchem-1680	55	30	for	for	ADP
eurjchem-1680	55	31	the	the	DET
eurjchem-1680	55	32	solvolysis	solvolysis	NOUN
eurjchem-1680	55	33	of	of	ADP
eurjchem-1680	55	34	2	2	NUM
eurjchem-1680	55	35	relative	relative	ADJ
eurjchem-1680	55	36	to	to	ADP
eurjchem-1680	55	37	that	that	PRON
eurjchem-1680	55	38	for	for	ADP
eurjchem-1680	55	39	the	the	DET
eurjchem-1680	55	40	corresponding	corresponding	ADJ
eurjchem-1680	55	41	solvolysis	solvolysis	NOUN
eurjchem-1680	55	42	of	of	ADP
eurjchem-1680	55	43	1	1	NUM
eurjchem-1680	55	44	[	[	X
eurjchem-1680	55	45	1	1	NUM
eurjchem-1680	55	46	]	]	PUNCT
eurjchem-1680	55	47	.	.	PUNCT
eurjchem-1680	56	1	these	these	DET
eurjchem-1680	56	2	ratios	ratio	NOUN
eurjchem-1680	56	3	vary	vary	VERB
eurjchem-1680	56	4	from	from	ADP
eurjchem-1680	56	5	0.038	0.038	NUM
eurjchem-1680	56	6	in	in	ADP
eurjchem-1680	56	7	90	90	NUM
eurjchem-1680	56	8	%	%	NOUN
eurjchem-1680	56	9	ethanol	ethanol	NOUN
eurjchem-1680	56	10	to	to	ADP
eurjchem-1680	56	11	4.35	4.35	NUM
eurjchem-1680	56	12	in	in	ADP
eurjchem-1680	56	13	70	70	NUM
eurjchem-1680	56	14	%	%	NOUN
eurjchem-1680	56	15	hfip	hfip	NOUN
eurjchem-1680	56	16	,	,	PUNCT
eurjchem-1680	56	17	a	a	DET
eurjchem-1680	56	18	relatively	relatively	ADV
eurjchem-1680	56	19	small	small	ADJ
eurjchem-1680	56	20	range	range	NOUN
eurjchem-1680	56	21	considering	consider	VERB
eurjchem-1680	56	22	the	the	DET
eurjchem-1680	56	23	large	large	ADJ
eurjchem-1680	56	24	varia	varia	NOUN
eurjchem-1680	56	25	2018	2018	NUM
eurjchem-1680	56	26	–	–	PUNCT
eurjchem-1680	56	27	european	european	ADJ
eurjchem-1680	56	28	journal	journal	NOUN
eurjchem-1680	56	29	of	of	ADP
eurjchem-1680	56	30	chemistry	chemistry	NOUN
eurjchem-1680	56	31	–	–	PUNCT
eurjchem-1680	56	32	cc	cc	NOUN
eurjchem-1680	56	33	by	by	ADP
eurjchem-1680	56	34	nc	nc	PROPN
eurjchem-1680	56	35	–	–	PUNCT
eurjchem-1680	56	36	doi	doi	NOUN
eurjchem-1680	56	37	:	:	PUNCT
eurjchem-1680	56	38	10.5155	10.5155	NUM
eurjchem-1680	56	39	/	/	SYM
eurjchem-1680	56	40	eurjchem.9.1.1	eurjchem.9.1.1	NOUN
eurjchem-1680	56	41	-	-	PUNCT
eurjchem-1680	56	42	6.1680	6.1680	NUM
eurjchem-1680	56	43	kevill	kevill	NOUN
eurjchem-1680	56	44	et	et	PROPN
eurjchem-1680	56	45	al	al	PROPN
eurjchem-1680	56	46	.	.	PUNCT
eurjchem-1680	56	47	/	/	SYM
eurjchem-1680	56	48	european	european	PROPN
eurjchem-1680	56	49	journal	journal	PROPN
eurjchem-1680	56	50	of	of	ADP
eurjchem-1680	56	51	chemistry	chemistry	NOUN
eurjchem-1680	56	52	9	9	NUM
eurjchem-1680	56	53	(	(	PUNCT
eurjchem-1680	56	54	1	1	NUM
eurjchem-1680	56	55	)	)	PUNCT
eurjchem-1680	56	56	(	(	PUNCT
eurjchem-1680	56	57	2018	2018	NUM
eurjchem-1680	56	58	)	)	PUNCT
eurjchem-1680	56	59	1	1	NUM
eurjchem-1680	56	60	-	-	SYM
eurjchem-1680	56	61	6	6	NUM
eurjchem-1680	56	62	3	3	NUM
eurjchem-1680	56	63	table	table	NOUN
eurjchem-1680	56	64	2	2	NUM
eurjchem-1680	56	65	.	.	PUNCT
eurjchem-1680	56	66	correlation	correlation	NOUN
eurjchem-1680	56	67	of	of	ADP
eurjchem-1680	56	68	the	the	DET
eurjchem-1680	56	69	specific	specific	ADJ
eurjchem-1680	56	70	rates	rate	NOUN
eurjchem-1680	56	71	of	of	ADP
eurjchem-1680	56	72	solvolysis	solvolysis	NOUN
eurjchem-1680	56	73	for	for	ADP
eurjchem-1680	56	74	α	α	NOUN
eurjchem-1680	56	75	-	-	NOUN
eurjchem-1680	56	76	bromoacetophenone	bromoacetophenone	NOUN
eurjchem-1680	56	77	(	(	PUNCT
eurjchem-1680	56	78	1	1	NUM
eurjchem-1680	56	79	)	)	PUNCT
eurjchem-1680	56	80	and	and	CCONJ
eurjchem-1680	56	81	α	α	X
eurjchem-1680	56	82	-	-	NOUN
eurjchem-1680	56	83	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	56	84	(	(	PUNCT
eurjchem-1680	56	85	2	2	NUM
eurjchem-1680	56	86	)	)	PUNCT
eurjchem-1680	56	87	,	,	PUNCT
eurjchem-1680	56	88	using	use	VERB
eurjchem-1680	56	89	equations	equation	NOUN
eurjchem-1680	56	90	(	(	PUNCT
eurjchem-1680	56	91	1	1	NUM
eurjchem-1680	56	92	)	)	PUNCT
eurjchem-1680	56	93	and	and	CCONJ
eurjchem-1680	56	94	(	(	PUNCT
eurjchem-1680	56	95	2	2	NUM
eurjchem-1680	56	96	)	)	PUNCT
eurjchem-1680	56	97	and	and	CCONJ
eurjchem-1680	56	98	tertiary	tertiary	ADJ
eurjchem-1680	56	99	alpha	alpha	NOUN
eurjchem-1680	56	100	-	-	PUNCT
eurjchem-1680	56	101	ketomesylates	ketomesylate	NOUN
eurjchem-1680	56	102	(	(	PUNCT
eurjchem-1680	56	103	3	3	NUM
eurjchem-1680	56	104	6	6	NUM
eurjchem-1680	56	105	)	)	PUNCT
eurjchem-1680	56	106	,	,	PUNCT
eurjchem-1680	56	107	using	use	VERB
eurjchem-1680	56	108	equations	equation	NOUN
eurjchem-1680	56	109	(	(	PUNCT
eurjchem-1680	56	110	3	3	NUM
eurjchem-1680	56	111	)	)	PUNCT
eurjchem-1680	56	112	and	and	CCONJ
eurjchem-1680	56	113	(	(	PUNCT
eurjchem-1680	56	114	4).a	4).a	X
eurjchem-1680	56	115	,	,	PUNCT
eurjchem-1680	56	116	b	b	PROPN
eurjchem-1680	56	117	compound	compound	NOUN
eurjchem-1680	56	118	n	n	NOUN
eurjchem-1680	56	119	c	c	NOUN
eurjchem-1680	56	120	l	l	NOUN
eurjchem-1680	57	1	d	d	X
eurjchem-1680	57	2	m	m	VERB
eurjchem-1680	57	3	e	e	X
eurjchem-1680	57	4	(	(	PUNCT
eurjchem-1680	57	5	c	c	NOUN
eurjchem-1680	57	6	+	+	CCONJ
eurjchem-1680	57	7	log	log	PROPN
eurjchem-1680	57	8	ko	ko	PROPN
eurjchem-1680	57	9	)	)	PUNCT
eurjchem-1680	57	10	r	r	NOUN
eurjchem-1680	57	11	f	f	PROPN
eurjchem-1680	57	12	1	1	NUM
eurjchem-1680	57	13	15	15	NUM
eurjchem-1680	57	14	1.02±0.08	1.02±0.08	NUM
eurjchem-1680	57	15	0.44±0.04	0.44±0.04	PROPN
eurjchem-1680	57	16	0.10±0.06	0.10±0.06	NOUN
eurjchem-1680	57	17	f	f	PROPN
eurjchem-1680	57	18	0.967	0.967	NUM
eurjchem-1680	57	19	85.8	85.8	NUM
eurjchem-1680	57	20	2	2	NUM
eurjchem-1680	57	21	15	15	NUM
eurjchem-1680	57	22	0.63±0.06	0.63±0.06	NOUN
eurjchem-1680	57	23	0.58±0.04	0.58±0.04	NOUN
eurjchem-1680	57	24	0.11±0.05	0.11±0.05	NOUN
eurjchem-1680	57	25	f	f	PROPN
eurjchem-1680	57	26	0.970	0.970	NUM
eurjchem-1680	57	27	92.7	92.7	NUM
eurjchem-1680	57	28	3	3	NUM
eurjchem-1680	57	29	6	6	NUM
eurjchem-1680	57	30	0.22±0.13	0.22±0.13	NUM
eurjchem-1680	57	31	-7.783	-7.783	PUNCT
eurjchem-1680	57	32	0.632	0.632	NUM
eurjchem-1680	57	33	2.7	2.7	NUM
eurjchem-1680	57	34	6	6	NUM
eurjchem-1680	57	35	0.45±0.23	0.45±0.23	NOUN
eurjchem-1680	57	36	0.64±0.24	0.64±0.24	NOUN
eurjchem-1680	57	37	-6.946	-6.946	PUNCT
eurjchem-1680	57	38	0.859	0.859	NUM
eurjchem-1680	57	39	4.3	4.3	NUM
eurjchem-1680	57	40	5	5	NUM
eurjchem-1680	57	41	g	g	ADP
eurjchem-1680	57	42	0.40±0.14	0.40±0.14	NOUN
eurjchem-1680	57	43	-8.394	-8.394	PUNCT
eurjchem-1680	57	44	0.852	0.852	NUM
eurjchem-1680	57	45	7.9	7.9	NUM
eurjchem-1680	57	46	5	5	NUM
eurjchem-1680	57	47	g	g	NOUN
eurjchem-1680	57	48	0.37±0.14	0.37±0.14	NUM
eurjchem-1680	57	49	0.71±0.14	0.71±0.14	PROPN
eurjchem-1680	57	50	-7.593	-7.593	PUNCT
eurjchem-1680	57	51	0.968	0.968	NUM
eurjchem-1680	57	52	14.9	14.9	NUM
eurjchem-1680	57	53	4	4	NUM
eurjchem-1680	57	54	5	5	NUM
eurjchem-1680	57	55	h	h	NOUN
eurjchem-1680	57	56	0.58±0.09	0.58±0.09	ADJ
eurjchem-1680	57	57	-7.395	-7.395	PUNCT
eurjchem-1680	57	58	0.966	0.966	NUM
eurjchem-1680	57	59	41.7	41.7	NUM
eurjchem-1680	57	60	5	5	NUM
eurjchem-1680	57	61	h	h	NOUN
eurjchem-1680	57	62	0.10±0.17	0.10±0.17	NOUN
eurjchem-1680	57	63	0.65±0.17	0.65±0.17	ADJ
eurjchem-1680	57	64	-7.184	-7.184	NUM
eurjchem-1680	57	65	0.971	0.971	NUM
eurjchem-1680	57	66	16.3	16.3	NUM
eurjchem-1680	57	67	5	5	NUM
eurjchem-1680	57	68	6	6	NUM
eurjchem-1680	57	69	0.62±0.05	0.62±0.05	NOUN
eurjchem-1680	57	70	-6.142	-6.142	PROPN
eurjchem-1680	57	71	0.990	0.990	NUM
eurjchem-1680	57	72	190	190	NUM
eurjchem-1680	57	73	6	6	NUM
eurjchem-1680	57	74	0.04±0.12	0.04±0.12	NUM
eurjchem-1680	57	75	0.66±0.12	0.66±0.12	NOUN
eurjchem-1680	57	76	-6.073	-6.073	NUM
eurjchem-1680	57	77	0.990	0.990	NUM
eurjchem-1680	57	78	73.6	73.6	NUM
eurjchem-1680	57	79	6	6	NUM
eurjchem-1680	57	80	5	5	NUM
eurjchem-1680	57	81	i	i	PRON
eurjchem-1680	57	82	0.96±0.02	0.96±0.02	VERB
eurjchem-1680	57	83	-5.096	-5.096	NOUN
eurjchem-1680	57	84	0.999	0.999	NUM
eurjchem-1680	57	85	2237	2237	NUM
eurjchem-1680	57	86	5i	5i	NUM
eurjchem-1680	57	87	0.03±0.04	0.03±0.04	NOUN
eurjchem-1680	57	88	0.96±0.04	0.96±0.04	NOUN
eurjchem-1680	57	89	-5.038	-5.038	PUNCT
eurjchem-1680	57	90	0.999	0.999	NUM
eurjchem-1680	57	91	941	941	NUM
eurjchem-1680	57	92	a	a	DET
eurjchem-1680	57	93	the	the	DET
eurjchem-1680	57	94	absence	absence	NOUN
eurjchem-1680	57	95	of	of	ADP
eurjchem-1680	57	96	an	an	DET
eurjchem-1680	57	97	l	l	NOUN
eurjchem-1680	57	98	value	value	NOUN
eurjchem-1680	57	99	indicates	indicate	VERB
eurjchem-1680	57	100	that	that	SCONJ
eurjchem-1680	57	101	the	the	DET
eurjchem-1680	57	102	correlation	correlation	NOUN
eurjchem-1680	57	103	is	be	AUX
eurjchem-1680	57	104	against	against	ADP
eurjchem-1680	57	105	only	only	ADV
eurjchem-1680	57	106	yx	yx	NOUN
eurjchem-1680	57	107	values	value	NOUN
eurjchem-1680	57	108	.	.	PUNCT
eurjchem-1680	58	1	b	b	X
eurjchem-1680	58	2	for	for	ADP
eurjchem-1680	58	3	compounds	compound	NOUN
eurjchem-1680	58	4	1	1	NUM
eurjchem-1680	58	5	and	and	CCONJ
eurjchem-1680	58	6	2	2	NUM
eurjchem-1680	58	7	,	,	PUNCT
eurjchem-1680	58	8	the	the	DET
eurjchem-1680	58	9	y	y	PROPN
eurjchem-1680	58	10	scale	scale	NOUN
eurjchem-1680	58	11	is	be	AUX
eurjchem-1680	58	12	the	the	DET
eurjchem-1680	58	13	ybr	ybr	PROPN
eurjchem-1680	58	14	scale	scale	NOUN
eurjchem-1680	58	15	and	and	CCONJ
eurjchem-1680	58	16	,	,	PUNCT
eurjchem-1680	58	17	for	for	ADP
eurjchem-1680	58	18	compounds	compound	NOUN
eurjchem-1680	58	19	3	3	NUM
eurjchem-1680	58	20	through	through	ADP
eurjchem-1680	58	21	6	6	NUM
eurjchem-1680	58	22	(	(	PUNCT
eurjchem-1680	58	23	specific	specific	ADJ
eurjchem-1680	58	24	rate	rate	NOUN
eurjchem-1680	58	25	rate	rate	NOUN
eurjchem-1680	58	26	data	datum	NOUN
eurjchem-1680	58	27	from	from	ADP
eurjchem-1680	58	28	ref	ref	NOUN
eurjchem-1680	58	29	.	.	PUNCT
eurjchem-1680	59	1	[	[	X
eurjchem-1680	59	2	10	10	NUM
eurjchem-1680	59	3	]	]	NUM
eurjchem-1680	59	4	)	)	PUNCT
eurjchem-1680	59	5	,	,	PUNCT
eurjchem-1680	59	6	it	it	PRON
eurjchem-1680	59	7	is	be	AUX
eurjchem-1680	59	8	the	the	DET
eurjchem-1680	59	9	yots	yot	NOUN
eurjchem-1680	59	10	scale	scale	NOUN
eurjchem-1680	59	11	.	.	PUNCT
eurjchem-1680	60	1	c	c	NOUN
eurjchem-1680	60	2	number	number	NOUN
eurjchem-1680	60	3	of	of	ADP
eurjchem-1680	60	4	solvents	solvent	NOUN
eurjchem-1680	60	5	.	.	PUNCT
eurjchem-1680	61	1	d	d	DET
eurjchem-1680	61	2	sensitivity	sensitivity	NOUN
eurjchem-1680	61	3	to	to	PART
eurjchem-1680	61	4	changes	change	NOUN
eurjchem-1680	61	5	in	in	ADP
eurjchem-1680	61	6	solvent	solvent	ADJ
eurjchem-1680	61	7	nucleophilicity	nucleophilicity	NOUN
eurjchem-1680	61	8	,	,	PUNCT
eurjchem-1680	61	9	with	with	ADP
eurjchem-1680	61	10	associated	associated	ADJ
eurjchem-1680	61	11	standard	standard	ADJ
eurjchem-1680	61	12	error	error	NOUN
eurjchem-1680	61	13	.	.	PUNCT
eurjchem-1680	62	1	e	e	NOUN
eurjchem-1680	62	2	sensitivity	sensitivity	NOUN
eurjchem-1680	62	3	to	to	ADP
eurjchem-1680	62	4	changes	change	NOUN
eurjchem-1680	62	5	in	in	ADP
eurjchem-1680	62	6	solvent	solvent	ADJ
eurjchem-1680	62	7	ionizing	ionizing	NOUN
eurjchem-1680	62	8	power	power	NOUN
eurjchem-1680	62	9	,	,	PUNCT
eurjchem-1680	62	10	with	with	ADP
eurjchem-1680	62	11	associated	associated	ADJ
eurjchem-1680	62	12	standard	standard	ADJ
eurjchem-1680	62	13	error	error	NOUN
eurjchem-1680	62	14	.	.	PUNCT
eurjchem-1680	63	1	f	f	PROPN
eurjchem-1680	63	2	since	since	SCONJ
eurjchem-1680	63	3	ko	ko	PROPN
eurjchem-1680	63	4	values	value	NOUN
eurjchem-1680	63	5	are	be	AUX
eurjchem-1680	63	6	available	available	ADJ
eurjchem-1680	63	7	,	,	PUNCT
eurjchem-1680	63	8	these	these	DET
eurjchem-1680	63	9	correlations	correlation	NOUN
eurjchem-1680	63	10	are	be	AUX
eurjchem-1680	63	11	against	against	ADP
eurjchem-1680	63	12	log(k	log(k	PROPN
eurjchem-1680	63	13	/	/	SYM
eurjchem-1680	63	14	ko	ko	PROPN
eurjchem-1680	63	15	)	)	PUNCT
eurjchem-1680	63	16	values	value	NOUN
eurjchem-1680	63	17	,	,	PUNCT
eurjchem-1680	63	18	such	such	ADJ
eurjchem-1680	63	19	that	that	SCONJ
eurjchem-1680	63	20	these	these	DET
eurjchem-1680	63	21	values	value	NOUN
eurjchem-1680	63	22	are	be	AUX
eurjchem-1680	63	23	the	the	DET
eurjchem-1680	63	24	c	c	NOUN
eurjchem-1680	63	25	values	value	NOUN
eurjchem-1680	63	26	.	.	PUNCT
eurjchem-1680	64	1	g	g	ADP
eurjchem-1680	64	2	omitting	omit	VERB
eurjchem-1680	64	3	the	the	DET
eurjchem-1680	64	4	etoh	etoh	ADJ
eurjchem-1680	64	5	values	value	NOUN
eurjchem-1680	64	6	.	.	PUNCT
eurjchem-1680	65	1	h	h	NOUN
eurjchem-1680	65	2	specific	specific	ADJ
eurjchem-1680	65	3	rate	rate	NOUN
eurjchem-1680	65	4	not	not	PART
eurjchem-1680	65	5	available	available	ADJ
eurjchem-1680	65	6	for	for	ADP
eurjchem-1680	65	7	solvolysis	solvolysis	NOUN
eurjchem-1680	65	8	in	in	ADP
eurjchem-1680	65	9	etoh	etoh	NOUN
eurjchem-1680	65	10	.	.	PUNCT
eurjchem-1680	66	1	i	i	PRON
eurjchem-1680	66	2	specific	specific	ADJ
eurjchem-1680	66	3	rate	rate	NOUN
eurjchem-1680	66	4	not	not	PART
eurjchem-1680	66	5	available	available	ADJ
eurjchem-1680	66	6	for	for	ADP
eurjchem-1680	66	7	solvolysis	solvolysis	NOUN
eurjchem-1680	66	8	in	in	ADP
eurjchem-1680	66	9	trifluoroacetic	trifluoroacetic	ADJ
eurjchem-1680	66	10	acid	acid	NOUN
eurjchem-1680	66	11	(	(	PUNCT
eurjchem-1680	66	12	tfa	tfa	NOUN
eurjchem-1680	66	13	)	)	PUNCT
eurjchem-1680	66	14	.	.	PUNCT
eurjchem-1680	67	1	figure	figure	NOUN
eurjchem-1680	67	2	1	1	NUM
eurjchem-1680	67	3	.	.	PUNCT
eurjchem-1680	68	1	plot	plot	NOUN
eurjchem-1680	68	2	of	of	ADP
eurjchem-1680	68	3	log	log	NOUN
eurjchem-1680	68	4	(	(	PUNCT
eurjchem-1680	68	5	k	k	NOUN
eurjchem-1680	68	6	/	/	SYM
eurjchem-1680	68	7	ko	ko	PROPN
eurjchem-1680	68	8	)	)	PUNCT
eurjchem-1680	68	9	for	for	ADP
eurjchem-1680	68	10	the	the	DET
eurjchem-1680	68	11	solvolyses	solvolyse	NOUN
eurjchem-1680	68	12	of	of	ADP
eurjchem-1680	68	13	α	α	NOUN
eurjchem-1680	68	14	-	-	NOUN
eurjchem-1680	68	15	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	68	16	(	(	PUNCT
eurjchem-1680	68	17	2	2	NUM
eurjchem-1680	68	18	)	)	PUNCT
eurjchem-1680	68	19	in	in	ADP
eurjchem-1680	68	20	15	15	NUM
eurjchem-1680	68	21	solvents	solvent	NOUN
eurjchem-1680	68	22	against	against	ADP
eurjchem-1680	68	23	(	(	PUNCT
eurjchem-1680	68	24	0.63	0.63	NUM
eurjchem-1680	68	25	nt	not	PART
eurjchem-1680	68	26	+	+	NUM
eurjchem-1680	68	27	0.58	0.58	NUM
eurjchem-1680	68	28	ybr	ybr	PROPN
eurjchem-1680	68	29	)	)	PUNCT
eurjchem-1680	68	30	;	;	PUNCT
eurjchem-1680	68	31	multiple	multiple	ADJ
eurjchem-1680	68	32	correlation	correlation	NOUN
eurjchem-1680	68	33	coefficient	coefficient	NOUN
eurjchem-1680	68	34	of	of	ADP
eurjchem-1680	68	35	0.970	0.970	NUM
eurjchem-1680	68	36	.	.	PUNCT
eurjchem-1680	69	1	tions	tion	NOUN
eurjchem-1680	69	2	in	in	ADP
eurjchem-1680	69	3	both	both	PRON
eurjchem-1680	69	4	nt	not	PART
eurjchem-1680	69	5	and	and	CCONJ
eurjchem-1680	69	6	ybr	ybr	PROPN
eurjchem-1680	69	7	values	value	NOUN
eurjchem-1680	69	8	.	.	PUNCT
eurjchem-1680	70	1	since	since	SCONJ
eurjchem-1680	70	2	the	the	DET
eurjchem-1680	70	3	solvolyses	solvolyse	NOUN
eurjchem-1680	70	4	of	of	ADP
eurjchem-1680	70	5	1	1	NUM
eurjchem-1680	70	6	were	be	AUX
eurjchem-1680	70	7	considered	consider	VERB
eurjchem-1680	70	8	to	to	PART
eurjchem-1680	70	9	show	show	VERB
eurjchem-1680	70	10	a	a	DET
eurjchem-1680	70	11	grunwald	grunwald	NOUN
eurjchem-1680	70	12	-	-	PUNCT
eurjchem-1680	70	13	winstein	winstein	NOUN
eurjchem-1680	70	14	equation	equation	NOUN
eurjchem-1680	70	15	behavior	behavior	NOUN
eurjchem-1680	70	16	typical	typical	ADJ
eurjchem-1680	70	17	of	of	ADP
eurjchem-1680	70	18	that	that	PRON
eurjchem-1680	70	19	to	to	PART
eurjchem-1680	70	20	be	be	AUX
eurjchem-1680	70	21	expected	expect	VERB
eurjchem-1680	70	22	for	for	ADP
eurjchem-1680	70	23	an	an	DET
eurjchem-1680	70	24	sn2	sn2	PROPN
eurjchem-1680	70	25	process	process	NOUN
eurjchem-1680	70	26	over	over	ADP
eurjchem-1680	70	27	the	the	DET
eurjchem-1680	70	28	full	full	ADJ
eurjchem-1680	70	29	range	range	NOUN
eurjchem-1680	70	30	of	of	ADP
eurjchem-1680	70	31	solvents	solvent	NOUN
eurjchem-1680	70	32	[	[	X
eurjchem-1680	70	33	1	1	NUM
eurjchem-1680	70	34	]	]	PUNCT
eurjchem-1680	70	35	,	,	PUNCT
eurjchem-1680	70	36	it	it	PRON
eurjchem-1680	70	37	is	be	AUX
eurjchem-1680	70	38	reasonable	reasonable	ADJ
eurjchem-1680	70	39	to	to	PART
eurjchem-1680	70	40	assign	assign	VERB
eurjchem-1680	70	41	the	the	DET
eurjchem-1680	70	42	variations	variation	NOUN
eurjchem-1680	70	43	in	in	ADP
eurjchem-1680	70	44	the	the	DET
eurjchem-1680	70	45	k2	k2	ADJ
eurjchem-1680	70	46	/	/	SYM
eurjchem-1680	70	47	k1	k1	NOUN
eurjchem-1680	70	48	ratio	ratio	NOUN
eurjchem-1680	70	49	to	to	ADP
eurjchem-1680	70	50	the	the	DET
eurjchem-1680	70	51	solvolyses	solvolyse	NOUN
eurjchem-1680	70	52	of	of	ADP
eurjchem-1680	70	53	the	the	DET
eurjchem-1680	70	54	tertiary	tertiary	ADJ
eurjchem-1680	70	55	alphabromoketone	alphabromoketone	NOUN
eurjchem-1680	70	56	2	2	NUM
eurjchem-1680	70	57	showing	show	VERB
eurjchem-1680	70	58	considerably	considerably	ADV
eurjchem-1680	70	59	increased	increase	VERB
eurjchem-1680	70	60	unimolecular	unimolecular	ADJ
eurjchem-1680	70	61	character	character	NOUN
eurjchem-1680	70	62	,	,	PUNCT
eurjchem-1680	70	63	which	which	PRON
eurjchem-1680	70	64	will	will	AUX
eurjchem-1680	70	65	be	be	AUX
eurjchem-1680	70	66	especially	especially	ADV
eurjchem-1680	70	67	favored	favor	VERB
eurjchem-1680	70	68	in	in	ADP
eurjchem-1680	70	69	the	the	DET
eurjchem-1680	70	70	fluoroalcohol	fluoroalcohol	NOUN
eurjchem-1680	70	71	-	-	PUNCT
eurjchem-1680	70	72	containing	contain	VERB
eurjchem-1680	70	73	solvents	solvent	NOUN
eurjchem-1680	70	74	.	.	PUNCT
eurjchem-1680	71	1	when	when	SCONJ
eurjchem-1680	71	2	the	the	DET
eurjchem-1680	71	3	extended	extended	ADJ
eurjchem-1680	71	4	grunwald	grunwald	NOUN
eurjchem-1680	71	5	-	-	PUNCT
eurjchem-1680	71	6	winstein	winstein	NOUN
eurjchem-1680	71	7	equation	equation	NOUN
eurjchem-1680	71	8	is	be	AUX
eurjchem-1680	71	9	applied	apply	VERB
eurjchem-1680	71	10	to	to	ADP
eurjchem-1680	71	11	the	the	DET
eurjchem-1680	71	12	specific	specific	ADJ
eurjchem-1680	71	13	rates	rate	NOUN
eurjchem-1680	71	14	for	for	ADP
eurjchem-1680	71	15	the	the	DET
eurjchem-1680	71	16	solvolyses	solvolyse	NOUN
eurjchem-1680	71	17	of	of	ADP
eurjchem-1680	71	18	2	2	NUM
eurjchem-1680	71	19	reported	report	VERB
eurjchem-1680	71	20	in	in	ADP
eurjchem-1680	71	21	table	table	NOUN
eurjchem-1680	71	22	1	1	NUM
eurjchem-1680	71	23	,	,	PUNCT
eurjchem-1680	71	24	values	value	NOUN
eurjchem-1680	71	25	are	be	AUX
eurjchem-1680	71	26	obtained	obtain	VERB
eurjchem-1680	71	27	for	for	ADP
eurjchem-1680	71	28	l	l	NOUN
eurjchem-1680	71	29	of	of	ADP
eurjchem-1680	71	30	0.63±0.06	0.63±0.06	NOUN
eurjchem-1680	71	31	and	and	CCONJ
eurjchem-1680	71	32	for	for	ADP
eurjchem-1680	71	33	m	m	PROPN
eurjchem-1680	71	34	of	of	ADP
eurjchem-1680	71	35	0.58±0.04	0.58±0.04	NOUN
eurjchem-1680	71	36	,	,	PUNCT
eurjchem-1680	71	37	with	with	ADP
eurjchem-1680	71	38	a	a	DET
eurjchem-1680	71	39	small	small	ADJ
eurjchem-1680	71	40	residual	residual	ADJ
eurjchem-1680	71	41	c	c	NOUN
eurjchem-1680	71	42	value	value	NOUN
eurjchem-1680	71	43	of	of	ADP
eurjchem-1680	71	44	0.11±0.05	0.11±0.05	NOUN
eurjchem-1680	71	45	and	and	CCONJ
eurjchem-1680	71	46	with	with	ADP
eurjchem-1680	71	47	a	a	DET
eurjchem-1680	71	48	correlation	correlation	NOUN
eurjchem-1680	71	49	coefficient	coefficient	NOUN
eurjchem-1680	71	50	of	of	ADP
eurjchem-1680	71	51	0.970	0.970	NUM
eurjchem-1680	71	52	(	(	PUNCT
eurjchem-1680	71	53	table	table	NOUN
eurjchem-1680	71	54	2	2	NUM
eurjchem-1680	71	55	)	)	PUNCT
eurjchem-1680	71	56	.	.	PUNCT
eurjchem-1680	72	1	the	the	DET
eurjchem-1680	72	2	plot	plot	NOUN
eurjchem-1680	72	3	of	of	ADP
eurjchem-1680	72	4	log	log	NOUN
eurjchem-1680	72	5	(	(	PUNCT
eurjchem-1680	72	6	k	k	NOUN
eurjchem-1680	72	7	/	/	SYM
eurjchem-1680	72	8	ko	ko	PROPN
eurjchem-1680	72	9	)	)	PUNCT
eurjchem-1680	72	10	against	against	ADP
eurjchem-1680	72	11	(	(	PUNCT
eurjchem-1680	72	12	0.63nt	0.63nt	NOUN
eurjchem-1680	72	13	+	+	CCONJ
eurjchem-1680	72	14	0.58ybr	0.58ybr	NUM
eurjchem-1680	72	15	)	)	PUNCT
eurjchem-1680	72	16	is	be	AUX
eurjchem-1680	72	17	shown	show	VERB
eurjchem-1680	72	18	in	in	ADP
eurjchem-1680	72	19	figure	figure	NOUN
eurjchem-1680	72	20	1	1	NUM
eurjchem-1680	72	21	.	.	PUNCT
eurjchem-1680	73	1	the	the	DET
eurjchem-1680	73	2	corresponding	correspond	VERB
eurjchem-1680	73	3	values	value	NOUN
eurjchem-1680	73	4	for	for	ADP
eurjchem-1680	73	5	the	the	DET
eurjchem-1680	73	6	solvolyses	solvolyse	NOUN
eurjchem-1680	73	7	of	of	ADP
eurjchem-1680	73	8	1	1	NUM
eurjchem-1680	73	9	,	,	PUNCT
eurjchem-1680	73	10	with	with	ADP
eurjchem-1680	73	11	the	the	DET
eurjchem-1680	73	12	expected	expect	VERB
eurjchem-1680	73	13	higher	high	ADJ
eurjchem-1680	73	14	l	l	NOUN
eurjchem-1680	73	15	value	value	NOUN
eurjchem-1680	73	16	and	and	CCONJ
eurjchem-1680	73	17	lower	low	ADJ
eurjchem-1680	73	18	m	m	NOUN
eurjchem-1680	73	19	value	value	NOUN
eurjchem-1680	73	20	being	be	AUX
eurjchem-1680	73	21	coupled	couple	VERB
eurjchem-1680	73	22	with	with	ADP
eurjchem-1680	73	23	a	a	DET
eurjchem-1680	73	24	correlation	correlation	NOUN
eurjchem-1680	73	25	coefficient	coefficient	NOUN
eurjchem-1680	73	26	and	and	CCONJ
eurjchem-1680	73	27	an	an	DET
eurjchem-1680	73	28	f	f	NOUN
eurjchem-1680	73	29	-	-	PUNCT
eurjchem-1680	73	30	test	test	NOUN
eurjchem-1680	73	31	value	value	NOUN
eurjchem-1680	73	32	essentially	essentially	ADV
eurjchem-1680	73	33	identified	identify	VERB
eurjchem-1680	73	34	to	to	ADP
eurjchem-1680	73	35	those	those	PRON
eurjchem-1680	73	36	presently	presently	ADV
eurjchem-1680	73	37	reported	report	VERB
eurjchem-1680	73	38	for	for	ADP
eurjchem-1680	73	39	2	2	NUM
eurjchem-1680	73	40	are	be	AUX
eurjchem-1680	73	41	also	also	ADV
eurjchem-1680	73	42	reported	report	VERB
eurjchem-1680	73	43	within	within	ADP
eurjchem-1680	73	44	table	table	NOUN
eurjchem-1680	73	45	2	2	NUM
eurjchem-1680	73	46	.	.	PUNCT
eurjchem-1680	74	1	the	the	DET
eurjchem-1680	74	2	extended	extend	VERB
eurjchem-1680	74	3	grunwald	grunwald	NOUN
eurjchem-1680	74	4	-	-	PUNCT
eurjchem-1680	74	5	winstein	winstein	NOUN
eurjchem-1680	74	6	equation	equation	NOUN
eurjchem-1680	74	7	comparison	comparison	NOUN
eurjchem-1680	74	8	of	of	ADP
eurjchem-1680	74	9	1	1	NUM
eurjchem-1680	74	10	with	with	ADP
eurjchem-1680	74	11	2	2	NUM
eurjchem-1680	74	12	suggests	suggest	VERB
eurjchem-1680	74	13	a	a	DET
eurjchem-1680	74	14	movement	movement	NOUN
eurjchem-1680	74	15	away	away	ADV
eurjchem-1680	74	16	from	from	ADP
eurjchem-1680	74	17	an	an	DET
eurjchem-1680	74	18	essentially	essentially	ADV
eurjchem-1680	74	19	pure	pure	ADJ
eurjchem-1680	74	20	sn2	sn2	PROPN
eurjchem-1680	74	21	reaction	reaction	NOUN
eurjchem-1680	74	22	for	for	ADP
eurjchem-1680	74	23	1	1	NUM
eurjchem-1680	74	24	on	on	ADP
eurjchem-1680	74	25	going	go	VERB
eurjchem-1680	74	26	to	to	ADP
eurjchem-1680	74	27	the	the	DET
eurjchem-1680	74	28	solvolyses	solvolyse	NOUN
eurjchem-1680	74	29	of	of	ADP
eurjchem-1680	74	30	2	2	NUM
eurjchem-1680	74	31	.	.	PUNCT
eurjchem-1680	75	1	however	however	ADV
eurjchem-1680	75	2	,	,	PUNCT
eurjchem-1680	75	3	the	the	DET
eurjchem-1680	75	4	l	l	NOUN
eurjchem-1680	75	5	-	-	PUNCT
eurjchem-1680	75	6	value	value	NOUN
eurjchem-1680	75	7	is	be	AUX
eurjchem-1680	75	8	somewhat	somewhat	ADV
eurjchem-1680	75	9	higher	high	ADJ
eurjchem-1680	75	10	and	and	CCONJ
eurjchem-1680	75	11	the	the	DET
eurjchem-1680	75	12	m	m	NOUN
eurjchem-1680	75	13	-	-	PUNCT
eurjchem-1680	75	14	value	value	NOUN
eurjchem-1680	75	15	somewhat	somewhat	ADV
eurjchem-1680	75	16	lower	low	ADJ
eurjchem-1680	75	17	than	than	SCONJ
eurjchem-1680	75	18	one	one	PRON
eurjchem-1680	75	19	would	would	AUX
eurjchem-1680	75	20	expect	expect	VERB
eurjchem-1680	75	21	for	for	ADP
eurjchem-1680	75	22	an	an	DET
eurjchem-1680	75	23	sn1	sn1	PROPN
eurjchem-1680	75	24	reaction	reaction	NOUN
eurjchem-1680	75	25	.	.	PUNCT
eurjchem-1680	76	1	in	in	ADP
eurjchem-1680	76	2	the	the	DET
eurjchem-1680	76	3	extreme	extreme	NOUN
eurjchem-1680	76	4	,	,	PUNCT
eurjchem-1680	76	5	the	the	DET
eurjchem-1680	76	6	behavior	behavior	NOUN
eurjchem-1680	76	7	in	in	ADP
eurjchem-1680	76	8	sn1	sn1	PROPN
eurjchem-1680	76	9	solvolyses	solvolyse	NOUN
eurjchem-1680	76	10	is	be	AUX
eurjchem-1680	76	11	illustrated	illustrate	VERB
eurjchem-1680	76	12	by	by	ADP
eurjchem-1680	76	13	studies	study	NOUN
eurjchem-1680	76	14	of	of	ADP
eurjchem-1680	76	15	the	the	DET
eurjchem-1680	76	16	solvolyses	solvolyse	NOUN
eurjchem-1680	76	17	of	of	ADP
eurjchem-1680	76	18	1	1	NUM
eurjchem-1680	76	19	-	-	PUNCT
eurjchem-1680	76	20	adamantyl	adamantyl	ADJ
eurjchem-1680	76	21	and	and	CCONJ
eurjchem-1680	76	22	2	2	NUM
eurjchem-1680	76	23	-	-	PUNCT
eurjchem-1680	76	24	adamantyl	adamantyl	ADJ
eurjchem-1680	76	25	derivatives	derivative	NOUN
eurjchem-1680	76	26	[	[	X
eurjchem-1680	76	27	5	5	NUM
eurjchem-1680	76	28	]	]	PUNCT
eurjchem-1680	76	29	,	,	PUNCT
eurjchem-1680	76	30	which	which	PRON
eurjchem-1680	76	31	show	show	VERB
eurjchem-1680	76	32	a	a	DET
eurjchem-1680	76	33	negligible	negligible	ADJ
eurjchem-1680	76	34	dependence	dependence	NOUN
eurjchem-1680	76	35	on	on	ADP
eurjchem-1680	76	36	solvent	solvent	ADJ
eurjchem-1680	76	37	nucleophilicity	nucleophilicity	NOUN
eurjchem-1680	76	38	and	and	CCONJ
eurjchem-1680	76	39	(	(	PUNCT
eurjchem-1680	76	40	by	by	ADP
eurjchem-1680	76	41	definition	definition	NOUN
eurjchem-1680	76	42	)	)	PUNCT
eurjchem-1680	76	43	an	an	DET
eurjchem-1680	76	44	m	m	NOUN
eurjchem-1680	76	45	value	value	NOUN
eurjchem-1680	76	46	of	of	ADP
eurjchem-1680	76	47	unity	unity	NOUN
eurjchem-1680	76	48	.	.	PUNCT
eurjchem-1680	77	1	a	a	DET
eurjchem-1680	77	2	typical	typical	ADJ
eurjchem-1680	77	3	solvolysis	solvolysis	NOUN
eurjchem-1680	77	4	of	of	ADP
eurjchem-1680	77	5	a	a	DET
eurjchem-1680	77	6	non	non	ADJ
eurjchem-1680	77	7	-	-	ADJ
eurjchem-1680	77	8	caged	caged	ADJ
eurjchem-1680	77	9	structure	structure	NOUN
eurjchem-1680	77	10	tertiary	tertiary	ADJ
eurjchem-1680	77	11	halide	halide	NOUN
eurjchem-1680	77	12	,	,	PUNCT
eurjchem-1680	77	13	tert	tert	NOUN
eurjchem-1680	77	14	-	-	PUNCT
eurjchem-1680	77	15	butyl	butyl	NOUN
eurjchem-1680	77	16	chloride	chloride	NOUN
eurjchem-1680	77	17	,	,	PUNCT
eurjchem-1680	77	18	does	do	AUX
eurjchem-1680	77	19	show	show	VERB
eurjchem-1680	77	20	a	a	DET
eurjchem-1680	77	21	small	small	ADJ
eurjchem-1680	77	22	dependence	dependence	NOUN
eurjchem-1680	77	23	on	on	ADP
eurjchem-1680	77	24	solvent	solvent	ADJ
eurjchem-1680	77	25	nucleophilicity	nucleophilicity	NOUN
eurjchem-1680	77	26	and	and	CCONJ
eurjchem-1680	77	27	a	a	DET
eurjchem-1680	77	28	mechanism	mechanism	NOUN
eurjchem-1680	77	29	,	,	PUNCT
eurjchem-1680	77	30	described	describe	VERB
eurjchem-1680	77	31	as	as	ADP
eurjchem-1680	77	32	sn2	sn2	PROPN
eurjchem-1680	77	33	(	(	PUNCT
eurjchem-1680	77	34	intermediate	intermediate	ADJ
eurjchem-1680	77	35	)	)	PUNCT
eurjchem-1680	77	36	,	,	PUNCT
eurjchem-1680	77	37	has	have	AUX
eurjchem-1680	77	38	been	be	AUX
eurjchem-1680	77	39	proposed	propose	VERB
eurjchem-1680	77	40	in	in	ADP
eurjchem-1680	77	41	order	order	NOUN
eurjchem-1680	77	42	to	to	PART
eurjchem-1680	77	43	explain	explain	VERB
eurjchem-1680	77	44	values	value	NOUN
eurjchem-1680	77	45	for	for	ADP
eurjchem-1680	77	46	l	l	NOUN
eurjchem-1680	77	47	of	of	ADP
eurjchem-1680	77	48	0.30	0.30	NUM
eurjchem-1680	77	49	and	and	CCONJ
eurjchem-1680	77	50	for	for	ADP
eurjchem-1680	77	51	m	m	PROPN
eurjchem-1680	77	52	of	of	ADP
eurjchem-1680	77	53	0.76	0.76	NUM
eurjchem-1680	77	54	[	[	X
eurjchem-1680	77	55	19	19	NUM
eurjchem-1680	77	56	]	]	PUNCT
eurjchem-1680	77	57	.	.	PUNCT
eurjchem-1680	78	1	the	the	DET
eurjchem-1680	78	2	mechanism	mechanism	NOUN
eurjchem-1680	78	3	is	be	AUX
eurjchem-1680	78	4	considered	consider	VERB
eurjchem-1680	78	5	to	to	PART
eurjchem-1680	78	6	be	be	AUX
eurjchem-1680	78	7	bimolecular	bimolecular	ADJ
eurjchem-1680	78	8	but	but	CCONJ
eurjchem-1680	78	9	with	with	ADP
eurjchem-1680	78	10	reduced	reduce	VERB
eurjchem-1680	78	11	bond	bond	NOUN
eurjchem-1680	78	12	formation	formation	NOUN
eurjchem-1680	78	13	and	and	CCONJ
eurjchem-1680	78	14	more	more	ADV
eurjchem-1680	78	15	extensive	extensive	ADJ
eurjchem-1680	78	16	bond	bond	NOUN
eurjchem-1680	78	17	breaking	breaking	NOUN
eurjchem-1680	78	18	than	than	ADP
eurjchem-1680	78	19	in	in	ADP
eurjchem-1680	78	20	the	the	DET
eurjchem-1680	78	21	traditional	traditional	ADJ
eurjchem-1680	78	22	sn2	sn2	PROPN
eurjchem-1680	78	23	situation	situation	NOUN
eurjchem-1680	78	24	.	.	PUNCT
eurjchem-1680	79	1	an	an	DET
eurjchem-1680	79	2	extension	extension	NOUN
eurjchem-1680	79	3	from	from	ADP
eurjchem-1680	79	4	11	11	NUM
eurjchem-1680	79	5	solvents	solvent	NOUN
eurjchem-1680	79	6	[	[	X
eurjchem-1680	79	7	19	19	NUM
eurjchem-1680	79	8	]	]	PUNCT
eurjchem-1680	79	9	to	to	ADP
eurjchem-1680	79	10	46	46	NUM
eurjchem-1680	79	11	solvents	solvent	NOUN
eurjchem-1680	79	12	and	and	CCONJ
eurjchem-1680	79	13	with	with	ADP
eurjchem-1680	79	14	use	use	NOUN
eurjchem-1680	79	15	of	of	ADP
eurjchem-1680	79	16	nt	not	PART
eurjchem-1680	79	17	and	and	CCONJ
eurjchem-1680	79	18	yc1	yc1	PRON
eurjchem-1680	79	19	values	value	NOUN
eurjchem-1680	79	20	led	lead	VERB
eurjchem-1680	79	21	[	[	X
eurjchem-1680	79	22	21	21	NUM
eurjchem-1680	79	23	]	]	PUNCT
eurjchem-1680	79	24	to	to	ADP
eurjchem-1680	79	25	very	very	ADV
eurjchem-1680	79	26	similar	similar	ADJ
eurjchem-1680	79	27	correlation	correlation	NOUN
eurjchem-1680	79	28	sensitivities	sensitivity	NOUN
eurjchem-1680	79	29	of	of	ADP
eurjchem-1680	79	30	0.38	0.38	NUM
eurjchem-1680	79	31	for	for	ADP
eurjchem-1680	79	32	l	l	NOUN
eurjchem-1680	79	33	and	and	CCONJ
eurjchem-1680	79	34	0.86	0.86	NUM
eurjchem-1680	79	35	for	for	ADP
eurjchem-1680	79	36	m.	m.	NOUN
eurjchem-1680	79	37	it	it	PRON
eurjchem-1680	79	38	has	have	AUX
eurjchem-1680	79	39	been	be	AUX
eurjchem-1680	79	40	suggested	suggest	VERB
eurjchem-1680	79	41	that	that	SCONJ
eurjchem-1680	79	42	values	value	NOUN
eurjchem-1680	79	43	for	for	ADP
eurjchem-1680	79	44	l	l	NOUN
eurjchem-1680	79	45	as	as	ADV
eurjchem-1680	79	46	large	large	ADJ
eurjchem-1680	79	47	as	as	ADP
eurjchem-1680	79	48	0.3	0.3	NUM
eurjchem-1680	79	49	can	can	AUX
eurjchem-1680	79	50	be	be	AUX
eurjchem-1680	79	51	accommodated	accommodate	VERB
eurjchem-1680	79	52	by	by	ADP
eurjchem-1680	79	53	nucleophilic	nucleophilic	ADJ
eurjchem-1680	79	54	solvation	solvation	NOUN
eurjchem-1680	79	55	of	of	ADP
eurjchem-1680	79	56	the	the	DET
eurjchem-1680	79	57	incipient	incipient	ADJ
eurjchem-1680	79	58	carbocation	carbocation	NOUN
eurjchem-1680	80	1	[	[	X
eurjchem-1680	80	2	22	22	NUM
eurjchem-1680	80	3	]	]	PUNCT
eurjchem-1680	80	4	but	but	CCONJ
eurjchem-1680	80	5	,	,	PUNCT
eurjchem-1680	80	6	thinking	think	VERB
eurjchem-1680	80	7	in	in	ADP
eurjchem-1680	80	8	terms	term	NOUN
eurjchem-1680	80	9	of	of	ADP
eurjchem-1680	80	10	the	the	DET
eurjchem-1680	80	11	detailed	detailed	ADJ
eurjchem-1680	80	12	structure	structure	NOUN
eurjchem-1680	80	13	of	of	ADP
eurjchem-1680	80	14	the	the	DET
eurjchem-1680	80	15	activated	activated	ADJ
eurjchem-1680	80	16	complex	complex	NOUN
eurjchem-1680	80	17	,	,	PUNCT
eurjchem-1680	80	18	the	the	DET
eurjchem-1680	80	19	structures	structure	NOUN
eurjchem-1680	80	20	for	for	ADP
eurjchem-1680	80	21	the	the	DET
eurjchem-1680	80	22	sn2	sn2	PROPN
eurjchem-1680	80	23	(	(	PUNCT
eurjchem-1680	80	24	intermediate	intermediate	ADJ
eurjchem-1680	80	25	)	)	PUNCT
eurjchem-1680	80	26	pathway	pathway	NOUN
eurjchem-1680	80	27	and	and	CCONJ
eurjchem-1680	80	28	for	for	ADP
eurjchem-1680	80	29	the	the	DET
eurjchem-1680	80	30	sn1	sn1	PROPN
eurjchem-1680	80	31	with	with	ADP
eurjchem-1680	80	32	a	a	DET
eurjchem-1680	80	33	moderate	moderate	ADJ
eurjchem-1680	80	34	solvation	solvation	NOUN
eurjchem-1680	80	35	of	of	ADP
eurjchem-1680	80	36	the	the	DET
eurjchem-1680	80	37	developing	develop	VERB
eurjchem-1680	80	38	carbocation	carbocation	NOUN
eurjchem-1680	80	39	can	can	AUX
eurjchem-1680	80	40	be	be	AUX
eurjchem-1680	80	41	considered	consider	VERB
eurjchem-1680	80	42	as	as	ADV
eurjchem-1680	80	43	essentially	essentially	ADV
eurjchem-1680	80	44	identical	identical	ADJ
eurjchem-1680	80	45	.	.	PUNCT
eurjchem-1680	81	1	the	the	DET
eurjchem-1680	81	2	values	value	NOUN
eurjchem-1680	81	3	for	for	ADP
eurjchem-1680	81	4	solvolysis	solvolysis	NOUN
eurjchem-1680	81	5	of	of	ADP
eurjchem-1680	81	6	2	2	NUM
eurjchem-1680	81	7	show	show	VERB
eurjchem-1680	81	8	appreciably	appreciably	ADV
eurjchem-1680	81	9	larger	large	ADJ
eurjchem-1680	81	10	l	l	NOUN
eurjchem-1680	81	11	values	value	NOUN
eurjchem-1680	81	12	and	and	CCONJ
eurjchem-1680	81	13	lower	low	ADJ
eurjchem-1680	81	14	m	m	VERB
eurjchem-1680	81	15	values	value	NOUN
eurjchem-1680	81	16	,	,	PUNCT
eurjchem-1680	81	17	suggesting	suggest	VERB
eurjchem-1680	81	18	a	a	DET
eurjchem-1680	81	19	tighter	tight	ADJ
eurjchem-1680	81	20	transition	transition	NOUN
eurjchem-1680	81	21	state	state	NOUN
eurjchem-1680	81	22	for	for	ADP
eurjchem-1680	81	23	the	the	DET
eurjchem-1680	81	24	solvolyses	solvolyse	NOUN
eurjchem-1680	81	25	of	of	ADP
eurjchem-1680	81	26	2	2	NUM
eurjchem-1680	81	27	than	than	ADP
eurjchem-1680	81	28	for	for	ADP
eurjchem-1680	81	29	t	t	NOUN
eurjchem-1680	81	30	-	-	PUNCT
eurjchem-1680	81	31	butyl	butyl	NOUN
eurjchem-1680	81	32	chloride	chloride	NOUN
eurjchem-1680	81	33	.	.	PUNCT
eurjchem-1680	82	1	also	also	ADV
eurjchem-1680	82	2	included	include	VERB
eurjchem-1680	82	3	in	in	ADP
eurjchem-1680	82	4	table	table	NOUN
eurjchem-1680	82	5	2	2	NUM
eurjchem-1680	82	6	are	be	AUX
eurjchem-1680	82	7	values	value	NOUN
eurjchem-1680	82	8	which	which	PRON
eurjchem-1680	82	9	have	have	AUX
eurjchem-1680	82	10	been	be	AUX
eurjchem-1680	82	11	calculated	calculate	VERB
eurjchem-1680	82	12	from	from	ADP
eurjchem-1680	82	13	specific	specific	ADJ
eurjchem-1680	82	14	rate	rate	NOUN
eurjchem-1680	82	15	values	value	NOUN
eurjchem-1680	82	16	reported	report	VERB
eurjchem-1680	82	17	for	for	ADP
eurjchem-1680	82	18	five	five	NUM
eurjchem-1680	82	19	or	or	CCONJ
eurjchem-1680	82	20	six	six	NUM
eurjchem-1680	82	21	pure	pure	ADJ
eurjchem-1680	82	22	solvents	solvent	NOUN
eurjchem-1680	82	23	by	by	ADP
eurjchem-1680	82	24	creary	creary	ADJ
eurjchem-1680	82	25	[	[	X
eurjchem-1680	82	26	10	10	NUM
eurjchem-1680	82	27	]	]	PUNCT
eurjchem-1680	82	28	.	.	PUNCT
eurjchem-1680	83	1	using	use	VERB
eurjchem-1680	83	2	nt	not	PART
eurjchem-1680	83	3	and	and	CCONJ
eurjchem-1680	83	4	yots	yot	NOUN
eurjchem-1680	83	5	values	value	NOUN
eurjchem-1680	83	6	,	,	PUNCT
eurjchem-1680	83	7	we	we	PRON
eurjchem-1680	83	8	have	have	AUX
eurjchem-1680	83	9	used	use	VERB
eurjchem-1680	83	10	both	both	CCONJ
eurjchem-1680	83	11	the	the	DET
eurjchem-1680	83	12	simple	simple	ADJ
eurjchem-1680	83	13	(	(	PUNCT
eurjchem-1680	83	14	equation	equation	NOUN
eurjchem-1680	83	15	1	1	NUM
eurjchem-1680	83	16	)	)	PUNCT
eurjchem-1680	83	17	and	and	CCONJ
eurjchem-1680	83	18	extended	extend	VERB
eurjchem-1680	83	19	(	(	PUNCT
eurjchem-1680	83	20	equation	equation	NOUN
eurjchem-1680	83	21	2	2	NUM
eurjchem-1680	83	22	)	)	PUNCT
eurjchem-1680	83	23	forms	form	NOUN
eurjchem-1680	83	24	of	of	ADP
eurjchem-1680	83	25	the	the	DET
eurjchem-1680	83	26	grunwald	grunwald	NOUN
eurjchem-1680	83	27	-	-	PUNCT
eurjchem-1680	83	28	winstein	winstein	NOUN
eurjchem-1680	83	29	equation	equation	NOUN
eurjchem-1680	83	30	for	for	ADP
eurjchem-1680	83	31	the	the	DET
eurjchem-1680	83	32	solvolyses	solvolyse	NOUN
eurjchem-1680	83	33	of	of	ADP
eurjchem-1680	83	34	four	four	NUM
eurjchem-1680	83	35	α	α	NOUN
eurjchem-1680	83	36	-	-	PUNCT
eurjchem-1680	83	37	ketomesylates	ketomesylate	NOUN
eurjchem-1680	83	38	,	,	PUNCT
eurjchem-1680	83	39	which	which	PRON
eurjchem-1680	83	40	are	be	AUX
eurjchem-1680	83	41	designated	designate	VERB
eurjchem-1680	83	42	as	as	ADP
eurjchem-1680	83	43	structures	structure	NOUN
eurjchem-1680	83	44	3	3	NUM
eurjchem-1680	83	45	-	-	SYM
eurjchem-1680	83	46	6	6	NUM
eurjchem-1680	83	47	,	,	PUNCT
eurjchem-1680	83	48	where	where	SCONJ
eurjchem-1680	83	49	oms	om	NOUN
eurjchem-1680	83	50	represents	represent	VERB
eurjchem-1680	83	51	the	the	DET
eurjchem-1680	83	52	mesylate	mesylate	NOUN
eurjchem-1680	83	53	group	group	NOUN
eurjchem-1680	83	54	(	(	PUNCT
eurjchem-1680	83	55	oso2ch3	oso2ch3	PROPN
eurjchem-1680	83	56	)	)	PUNCT
eurjchem-1680	83	57	.	.	PUNCT
eurjchem-1680	84	1	although	although	SCONJ
eurjchem-1680	84	2	several	several	ADJ
eurjchem-1680	84	3	yoms	yom	NOUN
eurjchem-1680	84	4	values	value	NOUN
eurjchem-1680	84	5	are	be	AUX
eurjchem-1680	84	6	available	available	ADJ
eurjchem-1680	84	7	[	[	X
eurjchem-1680	84	8	23	23	NUM
eurjchem-1680	84	9	]	]	PUNCT
eurjchem-1680	84	10	,	,	PUNCT
eurjchem-1680	84	11	we	we	PRON
eurjchem-1680	84	12	2018	2018	NUM
eurjchem-1680	84	13	–	–	PUNCT
eurjchem-1680	84	14	european	european	ADJ
eurjchem-1680	84	15	journal	journal	NOUN
eurjchem-1680	84	16	of	of	ADP
eurjchem-1680	84	17	chemistry	chemistry	NOUN
eurjchem-1680	84	18	–	–	PUNCT
eurjchem-1680	84	19	cc	cc	NOUN
eurjchem-1680	84	20	by	by	ADP
eurjchem-1680	84	21	nc	nc	PROPN
eurjchem-1680	84	22	–	–	PUNCT
eurjchem-1680	84	23	doi	doi	NOUN
eurjchem-1680	84	24	:	:	PUNCT
eurjchem-1680	84	25	10.5155	10.5155	NUM
eurjchem-1680	84	26	/	/	SYM
eurjchem-1680	84	27	eurjchem.9.1.1	eurjchem.9.1.1	NOUN
eurjchem-1680	84	28	-	-	PUNCT
eurjchem-1680	84	29	6.1680	6.1680	NUM
eurjchem-1680	84	30	4	4	NUM
eurjchem-1680	84	31	kevill	kevill	NOUN
eurjchem-1680	84	32	et	et	PROPN
eurjchem-1680	84	33	al	al	PROPN
eurjchem-1680	84	34	.	.	PUNCT
eurjchem-1680	84	35	/	/	SYM
eurjchem-1680	84	36	european	european	PROPN
eurjchem-1680	84	37	journal	journal	PROPN
eurjchem-1680	84	38	of	of	ADP
eurjchem-1680	84	39	chemistry	chemistry	NOUN
eurjchem-1680	84	40	9	9	NUM
eurjchem-1680	84	41	(	(	PUNCT
eurjchem-1680	84	42	1	1	NUM
eurjchem-1680	84	43	)	)	PUNCT
eurjchem-1680	84	44	(	(	PUNCT
eurjchem-1680	84	45	2018	2018	NUM
eurjchem-1680	84	46	)	)	PUNCT
eurjchem-1680	84	47	1	1	NUM
eurjchem-1680	84	48	-	-	SYM
eurjchem-1680	84	49	6	6	NUM
eurjchem-1680	84	50	have	have	AUX
eurjchem-1680	84	51	used	use	VERB
eurjchem-1680	84	52	the	the	DET
eurjchem-1680	84	53	yots	yot	NOUN
eurjchem-1680	84	54	values	value	NOUN
eurjchem-1680	84	55	for	for	ADP
eurjchem-1680	84	56	a	a	DET
eurjchem-1680	84	57	tosylate	tosylate	ADJ
eurjchem-1680	84	58	leaving	leave	VERB
eurjchem-1680	84	59	group	group	NOUN
eurjchem-1680	84	60	(	(	PUNCT
eurjchem-1680	84	61	-oso2c6h4	-oso2c6h4	PROPN
eurjchem-1680	84	62	-	-	PUNCT
eurjchem-1680	84	63	p	p	X
eurjchem-1680	84	64	-	-	PUNCT
eurjchem-1680	84	65	ch3	ch3	NOUN
eurjchem-1680	84	66	)	)	PUNCT
eurjchem-1680	85	1	[	[	X
eurjchem-1680	85	2	5	5	NUM
eurjchem-1680	85	3	]	]	PUNCT
eurjchem-1680	85	4	.	.	PUNCT
eurjchem-1680	86	1	it	it	PRON
eurjchem-1680	86	2	has	have	AUX
eurjchem-1680	86	3	been	be	AUX
eurjchem-1680	86	4	suggested	suggest	VERB
eurjchem-1680	86	5	[	[	X
eurjchem-1680	86	6	5	5	X
eurjchem-1680	86	7	]	]	PUNCT
eurjchem-1680	86	8	that	that	PRON
eurjchem-1680	86	9	,	,	PUNCT
eurjchem-1680	86	10	to	to	PART
eurjchem-1680	86	11	avoid	avoid	VERB
eurjchem-1680	86	12	a	a	DET
eurjchem-1680	86	13	proliferation	proliferation	NOUN
eurjchem-1680	86	14	of	of	ADP
eurjchem-1680	86	15	y	y	PROPN
eurjchem-1680	86	16	scales	scale	NOUN
eurjchem-1680	86	17	,	,	PUNCT
eurjchem-1680	86	18	the	the	DET
eurjchem-1680	86	19	solvolyses	solvolyse	NOUN
eurjchem-1680	86	20	of	of	ADP
eurjchem-1680	86	21	sulfonate	sulfonate	ADJ
eurjchem-1680	86	22	esters	ester	NOUN
eurjchem-1680	86	23	similar	similar	ADJ
eurjchem-1680	86	24	to	to	ADP
eurjchem-1680	86	25	the	the	DET
eurjchem-1680	86	26	p	p	NOUN
eurjchem-1680	86	27	-	-	PUNCT
eurjchem-1680	86	28	toluenesulfonate	toluenesulfonate	NOUN
eurjchem-1680	86	29	(	(	PUNCT
eurjchem-1680	86	30	such	such	ADJ
eurjchem-1680	86	31	as	as	ADP
eurjchem-1680	86	32	mesylate	mesylate	NOUN
eurjchem-1680	86	33	[	[	X
eurjchem-1680	86	34	24	24	NUM
eurjchem-1680	86	35	]	]	PUNCT
eurjchem-1680	86	36	)	)	PUNCT
eurjchem-1680	86	37	be	be	AUX
eurjchem-1680	86	38	correlated	correlate	VERB
eurjchem-1680	86	39	using	use	VERB
eurjchem-1680	86	40	yots	yot	NOUN
eurjchem-1680	86	41	values	value	NOUN
eurjchem-1680	86	42	.	.	PUNCT
eurjchem-1680	87	1	creary	creary	PROPN
eurjchem-1680	87	2	found	find	VERB
eurjchem-1680	87	3	that	that	SCONJ
eurjchem-1680	87	4	for	for	ADP
eurjchem-1680	87	5	solvolysis	solvolysis	NOUN
eurjchem-1680	87	6	of	of	ADP
eurjchem-1680	87	7	5	5	NUM
eurjchem-1680	87	8	in	in	ADP
eurjchem-1680	87	9	ethanol	ethanol	NOUN
eurjchem-1680	87	10	,	,	PUNCT
eurjchem-1680	87	11	acetic	acetic	ADJ
eurjchem-1680	87	12	acid	acid	NOUN
eurjchem-1680	87	13	,	,	PUNCT
eurjchem-1680	87	14	formic	formic	ADJ
eurjchem-1680	87	15	acid	acid	NOUN
eurjchem-1680	87	16	,	,	PUNCT
eurjchem-1680	87	17	tfe	tfe	NOUN
eurjchem-1680	87	18	,	,	PUNCT
eurjchem-1680	87	19	hfip	hfip	PROPN
eurjchem-1680	87	20	,	,	PUNCT
eurjchem-1680	87	21	and	and	CCONJ
eurjchem-1680	87	22	trifluoroacetic	trifluoroacetic	ADJ
eurjchem-1680	87	23	acid	acid	NOUN
eurjchem-1680	87	24	,	,	PUNCT
eurjchem-1680	87	25	the	the	DET
eurjchem-1680	87	26	major	major	ADJ
eurjchem-1680	87	27	product	product	NOUN
eurjchem-1680	87	28	(	(	PUNCT
eurjchem-1680	87	29	94	94	NUM
eurjchem-1680	87	30	-	-	SYM
eurjchem-1680	87	31	100	100	NUM
eurjchem-1680	87	32	%	%	NOUN
eurjchem-1680	87	33	)	)	PUNCT
eurjchem-1680	87	34	was	be	AUX
eurjchem-1680	87	35	the	the	DET
eurjchem-1680	87	36	alkene	alkene	NOUN
eurjchem-1680	87	37	7a	7a	NUM
eurjchem-1680	87	38	,	,	PUNCT
eurjchem-1680	87	39	with	with	ADP
eurjchem-1680	87	40	0	0	NUM
eurjchem-1680	87	41	-	-	SYM
eurjchem-1680	87	42	6	6	NUM
eurjchem-1680	87	43	%	%	NOUN
eurjchem-1680	87	44	of	of	ADP
eurjchem-1680	87	45	the	the	DET
eurjchem-1680	87	46	direct	direct	ADJ
eurjchem-1680	87	47	substitution	substitution	NOUN
eurjchem-1680	87	48	product	product	NOUN
eurjchem-1680	87	49	.	.	PUNCT
eurjchem-1680	88	1	for	for	ADP
eurjchem-1680	88	2	the	the	DET
eurjchem-1680	88	3	solvolyses	solvolyse	NOUN
eurjchem-1680	88	4	of	of	ADP
eurjchem-1680	88	5	4	4	NUM
eurjchem-1680	88	6	,	,	PUNCT
eurjchem-1680	88	7	related	relate	VERB
eurjchem-1680	88	8	to	to	ADP
eurjchem-1680	88	9	2	2	NUM
eurjchem-1680	88	10	but	but	CCONJ
eurjchem-1680	88	11	with	with	ADP
eurjchem-1680	88	12	the	the	DET
eurjchem-1680	88	13	bromine	bromine	NOUN
eurjchem-1680	88	14	atom	atom	NOUN
eurjchem-1680	88	15	replaced	replace	VERB
eurjchem-1680	88	16	by	by	ADP
eurjchem-1680	88	17	the	the	DET
eurjchem-1680	88	18	mesylate	mesylate	NOUN
eurjchem-1680	88	19	group	group	NOUN
eurjchem-1680	88	20	,	,	PUNCT
eurjchem-1680	88	21	for	for	ADP
eurjchem-1680	88	22	solvolysis	solvolysis	NOUN
eurjchem-1680	88	23	in	in	ADP
eurjchem-1680	88	24	acetic	acetic	ADJ
eurjchem-1680	88	25	acid	acid	NOUN
eurjchem-1680	88	26	,	,	PUNCT
eurjchem-1680	88	27	formic	formic	ADJ
eurjchem-1680	88	28	acid	acid	NOUN
eurjchem-1680	88	29	,	,	PUNCT
eurjchem-1680	88	30	hfip	hfip	PROPN
eurjchem-1680	88	31	,	,	PUNCT
eurjchem-1680	88	32	and	and	CCONJ
eurjchem-1680	88	33	trifluoroacetic	trifluoroacetic	ADJ
eurjchem-1680	88	34	acid	acid	NOUN
eurjchem-1680	88	35	,	,	PUNCT
eurjchem-1680	88	36	81	81	NUM
eurjchem-1680	88	37	-	-	SYM
eurjchem-1680	88	38	97	97	NUM
eurjchem-1680	88	39	%	%	NOUN
eurjchem-1680	88	40	of	of	ADP
eurjchem-1680	88	41	the	the	DET
eurjchem-1680	88	42	product	product	NOUN
eurjchem-1680	88	43	was	be	AUX
eurjchem-1680	88	44	7b	7b	NUM
eurjchem-1680	88	45	,	,	PUNCT
eurjchem-1680	88	46	with	with	ADP
eurjchem-1680	88	47	3	3	NUM
eurjchem-1680	88	48	-	-	SYM
eurjchem-1680	88	49	19	19	NUM
eurjchem-1680	88	50	%	%	NOUN
eurjchem-1680	88	51	being	be	AUX
eurjchem-1680	88	52	the	the	DET
eurjchem-1680	88	53	direct	direct	ADJ
eurjchem-1680	88	54	substitution	substitution	NOUN
eurjchem-1680	88	55	product	product	NOUN
eurjchem-1680	88	56	.	.	PUNCT
eurjchem-1680	89	1	with	with	ADP
eurjchem-1680	89	2	r	r	NOUN
eurjchem-1680	89	3	=	=	SYM
eurjchem-1680	89	4	och3(3	och3(3	ADJ
eurjchem-1680	89	5	)	)	PUNCT
eurjchem-1680	89	6	,	,	PUNCT
eurjchem-1680	89	7	94	94	NUM
eurjchem-1680	89	8	%	%	NOUN
eurjchem-1680	89	9	of	of	ADP
eurjchem-1680	89	10	the	the	DET
eurjchem-1680	89	11	product	product	NOUN
eurjchem-1680	89	12	was	be	AUX
eurjchem-1680	89	13	the	the	DET
eurjchem-1680	89	14	alkene	alkene	NOUN
eurjchem-1680	89	15	in	in	ADP
eurjchem-1680	89	16	hfip	hfip	PROPN
eurjchem-1680	89	17	as	as	ADP
eurjchem-1680	89	18	solvent	solvent	NOUN
eurjchem-1680	89	19	,	,	PUNCT
eurjchem-1680	89	20	but	but	CCONJ
eurjchem-1680	89	21	appreciable	appreciable	ADJ
eurjchem-1680	89	22	amounts	amount	NOUN
eurjchem-1680	89	23	of	of	ADP
eurjchem-1680	89	24	both	both	CCONJ
eurjchem-1680	89	25	the	the	DET
eurjchem-1680	89	26	elimination	elimination	NOUN
eurjchem-1680	89	27	and	and	CCONJ
eurjchem-1680	89	28	substitution	substitution	NOUN
eurjchem-1680	89	29	product	product	NOUN
eurjchem-1680	89	30	were	be	AUX
eurjchem-1680	89	31	found	find	VERB
eurjchem-1680	89	32	in	in	ADP
eurjchem-1680	89	33	the	the	DET
eurjchem-1680	89	34	other	other	ADJ
eurjchem-1680	89	35	solvents	solvent	NOUN
eurjchem-1680	89	36	.	.	PUNCT
eurjchem-1680	90	1	for	for	ADP
eurjchem-1680	90	2	the	the	DET
eurjchem-1680	90	3	mesylate	mesylate	NOUN
eurjchem-1680	90	4	6	6	NUM
eurjchem-1680	90	5	,	,	PUNCT
eurjchem-1680	90	6	formation	formation	NOUN
eurjchem-1680	90	7	of	of	ADP
eurjchem-1680	90	8	a	a	DET
eurjchem-1680	90	9	double	double	ADJ
eurjchem-1680	90	10	bond	bond	NOUN
eurjchem-1680	90	11	at	at	ADP
eurjchem-1680	90	12	the	the	DET
eurjchem-1680	90	13	bridgehead	bridgehead	NOUN
eurjchem-1680	90	14	would	would	AUX
eurjchem-1680	90	15	be	be	AUX
eurjchem-1680	90	16	strongly	strongly	ADV
eurjchem-1680	90	17	disfavored	disfavor	VERB
eurjchem-1680	90	18	and	and	CCONJ
eurjchem-1680	90	19	the	the	DET
eurjchem-1680	90	20	substitution	substitution	NOUN
eurjchem-1680	90	21	product	product	NOUN
eurjchem-1680	90	22	was	be	AUX
eurjchem-1680	90	23	the	the	DET
eurjchem-1680	90	24	major	major	ADJ
eurjchem-1680	90	25	product	product	NOUN
eurjchem-1680	90	26	,	,	PUNCT
eurjchem-1680	90	27	accompanied	accompany	VERB
eurjchem-1680	90	28	by	by	ADP
eurjchem-1680	90	29	small	small	ADJ
eurjchem-1680	90	30	amounts	amount	NOUN
eurjchem-1680	90	31	of	of	ADP
eurjchem-1680	90	32	the	the	DET
eurjchem-1680	90	33	1,3elimination	1,3elimination	NUM
eurjchem-1680	90	34	product	product	NOUN
eurjchem-1680	90	35	.	.	PUNCT
eurjchem-1680	91	1	for	for	ADP
eurjchem-1680	91	2	more	more	ADJ
eurjchem-1680	91	3	details	detail	NOUN
eurjchem-1680	91	4	of	of	ADP
eurjchem-1680	91	5	the	the	DET
eurjchem-1680	91	6	product	product	NOUN
eurjchem-1680	91	7	formation	formation	NOUN
eurjchem-1680	91	8	,	,	PUNCT
eurjchem-1680	91	9	the	the	DET
eurjchem-1680	91	10	reader	reader	NOUN
eurjchem-1680	91	11	is	be	AUX
eurjchem-1680	91	12	referred	refer	VERB
eurjchem-1680	91	13	to	to	ADP
eurjchem-1680	91	14	the	the	DET
eurjchem-1680	91	15	original	original	ADJ
eurjchem-1680	91	16	report	report	NOUN
eurjchem-1680	91	17	[	[	X
eurjchem-1680	91	18	10	10	NUM
eurjchem-1680	91	19	]	]	PUNCT
eurjchem-1680	91	20	and	and	CCONJ
eurjchem-1680	91	21	to	to	ADP
eurjchem-1680	91	22	a	a	DET
eurjchem-1680	91	23	subsequent	subsequent	ADJ
eurjchem-1680	91	24	review	review	NOUN
eurjchem-1680	91	25	article	article	NOUN
eurjchem-1680	91	26	[	[	X
eurjchem-1680	91	27	11	11	NUM
eurjchem-1680	91	28	]	]	PUNCT
eurjchem-1680	91	29	.	.	PUNCT
eurjchem-1680	92	1	creary	creary	ADJ
eurjchem-1680	92	2	[	[	X
eurjchem-1680	92	3	10	10	NUM
eurjchem-1680	92	4	]	]	PUNCT
eurjchem-1680	92	5	presented	present	VERB
eurjchem-1680	92	6	plots	plot	NOUN
eurjchem-1680	92	7	of	of	ADP
eurjchem-1680	92	8	log	log	NOUN
eurjchem-1680	92	9	k	k	X
eurjchem-1680	92	10	against	against	ADP
eurjchem-1680	92	11	yots	yot	NOUN
eurjchem-1680	92	12	for	for	ADP
eurjchem-1680	92	13	compounds	compound	NOUN
eurjchem-1680	92	14	3	3	NUM
eurjchem-1680	92	15	6	6	NUM
eurjchem-1680	92	16	,	,	PUNCT
eurjchem-1680	92	17	indicating	indicate	VERB
eurjchem-1680	92	18	slopes	slope	NOUN
eurjchem-1680	92	19	of	of	ADP
eurjchem-1680	92	20	0.63	0.63	NUM
eurjchem-1680	92	21	for	for	ADP
eurjchem-1680	92	22	4	4	NUM
eurjchem-1680	92	23	,	,	PUNCT
eurjchem-1680	92	24	0.66	0.66	NUM
eurjchem-1680	92	25	for	for	ADP
eurjchem-1680	92	26	5	5	NUM
eurjchem-1680	92	27	,	,	PUNCT
eurjchem-1680	92	28	and	and	CCONJ
eurjchem-1680	92	29	1.01	1.01	NUM
eurjchem-1680	92	30	for	for	ADP
eurjchem-1680	92	31	6	6	NUM
eurjchem-1680	92	32	.	.	PUNCT
eurjchem-1680	92	33	for	for	ADP
eurjchem-1680	92	34	3	3	NUM
eurjchem-1680	92	35	,	,	PUNCT
eurjchem-1680	92	36	with	with	ADP
eurjchem-1680	92	37	the	the	DET
eurjchem-1680	92	38	electron	electron	NOUN
eurjchem-1680	92	39	withdrawing	withdraw	VERB
eurjchem-1680	92	40	methoxy	methoxy	ADJ
eurjchem-1680	92	41	group	group	NOUN
eurjchem-1680	92	42	on	on	ADP
eurjchem-1680	92	43	the	the	DET
eurjchem-1680	92	44	carbonyl	carbonyl	NOUN
eurjchem-1680	92	45	carbon	carbon	NOUN
eurjchem-1680	92	46	,	,	PUNCT
eurjchem-1680	92	47	a	a	DET
eurjchem-1680	92	48	scattered	scatter	VERB
eurjchem-1680	92	49	plot	plot	NOUN
eurjchem-1680	92	50	was	be	AUX
eurjchem-1680	92	51	observed	observe	VERB
eurjchem-1680	92	52	,	,	PUNCT
eurjchem-1680	92	53	with	with	ADP
eurjchem-1680	92	54	a	a	DET
eurjchem-1680	92	55	particularly	particularly	ADV
eurjchem-1680	92	56	large	large	ADJ
eurjchem-1680	92	57	deviation	deviation	NOUN
eurjchem-1680	92	58	for	for	ADP
eurjchem-1680	92	59	the	the	DET
eurjchem-1680	92	60	specific	specific	ADJ
eurjchem-1680	92	61	rate	rate	NOUN
eurjchem-1680	92	62	for	for	ADP
eurjchem-1680	92	63	ethanolysis	ethanolysis	NOUN
eurjchem-1680	92	64	.	.	PUNCT
eurjchem-1680	93	1	we	we	PRON
eurjchem-1680	93	2	have	have	AUX
eurjchem-1680	93	3	analyzed	analyze	VERB
eurjchem-1680	93	4	the	the	DET
eurjchem-1680	93	5	specific	specific	ADJ
eurjchem-1680	93	6	rates	rate	NOUN
eurjchem-1680	93	7	of	of	ADP
eurjchem-1680	93	8	solvolysis	solvolysis	NOUN
eurjchem-1680	93	9	of	of	ADP
eurjchem-1680	93	10	3	3	NUM
eurjchem-1680	93	11	through	through	ADP
eurjchem-1680	93	12	6	6	NUM
eurjchem-1680	93	13	by	by	ADP
eurjchem-1680	93	14	simple	simple	ADJ
eurjchem-1680	93	15	and	and	CCONJ
eurjchem-1680	93	16	multiple	multiple	ADJ
eurjchem-1680	93	17	regression	regression	NOUN
eurjchem-1680	93	18	analyses	analysis	NOUN
eurjchem-1680	93	19	.	.	PUNCT
eurjchem-1680	94	1	while	while	SCONJ
eurjchem-1680	94	2	the	the	DET
eurjchem-1680	94	3	5	5	NUM
eurjchem-1680	94	4	or	or	CCONJ
eurjchem-1680	94	5	6	6	NUM
eurjchem-1680	94	6	data	datum	NOUN
eurjchem-1680	94	7	points	point	NOUN
eurjchem-1680	94	8	available	available	ADJ
eurjchem-1680	94	9	for	for	ADP
eurjchem-1680	94	10	the	the	DET
eurjchem-1680	94	11	solvolyses	solvolyse	NOUN
eurjchem-1680	94	12	of	of	ADP
eurjchem-1680	94	13	3	3	NUM
eurjchem-1680	94	14	through	through	ADP
eurjchem-1680	94	15	6	6	NUM
eurjchem-1680	94	16	are	be	AUX
eurjchem-1680	94	17	low	low	ADJ
eurjchem-1680	94	18	for	for	ADP
eurjchem-1680	94	19	a	a	DET
eurjchem-1680	94	20	multiple	multiple	ADJ
eurjchem-1680	94	21	regression	regression	NOUN
eurjchem-1680	94	22	analysis	analysis	NOUN
eurjchem-1680	94	23	,	,	PUNCT
eurjchem-1680	94	24	a	a	DET
eurjchem-1680	94	25	review	review	NOUN
eurjchem-1680	94	26	[	[	X
eurjchem-1680	94	27	25	25	NUM
eurjchem-1680	94	28	]	]	PUNCT
eurjchem-1680	94	29	has	have	AUX
eurjchem-1680	94	30	suggested	suggest	VERB
eurjchem-1680	94	31	a	a	DET
eurjchem-1680	94	32	minimum	minimum	NOUN
eurjchem-1680	94	33	of	of	ADP
eurjchem-1680	94	34	five	five	NUM
eurjchem-1680	94	35	data	datum	NOUN
eurjchem-1680	94	36	points	point	NOUN
eurjchem-1680	94	37	for	for	ADP
eurjchem-1680	94	38	each	each	DET
eurjchem-1680	94	39	variable	variable	NOUN
eurjchem-1680	94	40	,	,	PUNCT
eurjchem-1680	94	41	they	they	PRON
eurjchem-1680	94	42	do	do	AUX
eurjchem-1680	94	43	cover	cover	VERB
eurjchem-1680	94	44	a	a	DET
eurjchem-1680	94	45	wide	wide	ADJ
eurjchem-1680	94	46	range	range	NOUN
eurjchem-1680	94	47	of	of	ADP
eurjchem-1680	94	48	solvent	solvent	ADJ
eurjchem-1680	94	49	type	type	NOUN
eurjchem-1680	94	50	and	and	CCONJ
eurjchem-1680	94	51	,	,	PUNCT
eurjchem-1680	94	52	hence	hence	ADV
eurjchem-1680	94	53	,	,	PUNCT
eurjchem-1680	94	54	they	they	PRON
eurjchem-1680	94	55	represent	represent	VERB
eurjchem-1680	94	56	a	a	DET
eurjchem-1680	94	57	favorable	favorable	ADJ
eurjchem-1680	94	58	variety	variety	NOUN
eurjchem-1680	94	59	of	of	ADP
eurjchem-1680	94	60	nt	not	PART
eurjchem-1680	94	61	and	and	CCONJ
eurjchem-1680	94	62	yots	yot	NOUN
eurjchem-1680	94	63	combinations	combination	NOUN
eurjchem-1680	94	64	.	.	PUNCT
eurjchem-1680	95	1	the	the	DET
eurjchem-1680	95	2	m	m	ADJ
eurjchem-1680	95	3	and	and	CCONJ
eurjchem-1680	95	4	the	the	DET
eurjchem-1680	95	5	l	l	NOUN
eurjchem-1680	95	6	plus	plus	CCONJ
eurjchem-1680	95	7	m	m	PROPN
eurjchem-1680	95	8	values	value	NOUN
eurjchem-1680	95	9	obtained	obtain	VERB
eurjchem-1680	95	10	are	be	AUX
eurjchem-1680	95	11	reported	report	VERB
eurjchem-1680	95	12	in	in	ADP
eurjchem-1680	95	13	table	table	NOUN
eurjchem-1680	95	14	2	2	NUM
eurjchem-1680	95	15	.	.	PUNCT
eurjchem-1680	96	1	since	since	SCONJ
eurjchem-1680	96	2	the	the	DET
eurjchem-1680	96	3	creary	creary	ADJ
eurjchem-1680	96	4	data	datum	NOUN
eurjchem-1680	96	5	for	for	ADP
eurjchem-1680	96	6	the	the	DET
eurjchem-1680	96	7	solvolysis	solvolysis	NOUN
eurjchem-1680	96	8	of	of	ADP
eurjchem-1680	96	9	3	3	NUM
eurjchem-1680	96	10	6	6	NUM
eurjchem-1680	96	11	do	do	AUX
eurjchem-1680	96	12	not	not	PART
eurjchem-1680	96	13	indicate	indicate	VERB
eurjchem-1680	96	14	a	a	DET
eurjchem-1680	96	15	value	value	NOUN
eurjchem-1680	96	16	for	for	ADP
eurjchem-1680	96	17	the	the	DET
eurjchem-1680	96	18	specific	specific	ADJ
eurjchem-1680	96	19	rate	rate	NOUN
eurjchem-1680	96	20	of	of	ADP
eurjchem-1680	96	21	solvolysis	solvolysis	NOUN
eurjchem-1680	96	22	in	in	ADP
eurjchem-1680	96	23	80	80	NUM
eurjchem-1680	96	24	%	%	NOUN
eurjchem-1680	96	25	ethanol	ethanol	NOUN
eurjchem-1680	96	26	[	[	PUNCT
eurjchem-1680	96	27	the	the	DET
eurjchem-1680	96	28	ko	ko	PROPN
eurjchem-1680	96	29	value	value	NOUN
eurjchem-1680	96	30	for	for	ADP
eurjchem-1680	96	31	insertion	insertion	NOUN
eurjchem-1680	96	32	into	into	ADP
eurjchem-1680	96	33	equations	equation	NOUN
eurjchem-1680	96	34	(	(	PUNCT
eurjchem-1680	96	35	1	1	NUM
eurjchem-1680	96	36	)	)	PUNCT
eurjchem-1680	96	37	and	and	CCONJ
eurjchem-1680	96	38	(	(	PUNCT
eurjchem-1680	96	39	2	2	NUM
eurjchem-1680	96	40	)	)	PUNCT
eurjchem-1680	96	41	]	]	PUNCT
eurjchem-1680	96	42	,	,	PUNCT
eurjchem-1680	96	43	the	the	DET
eurjchem-1680	96	44	equations	equation	NOUN
eurjchem-1680	96	45	were	be	AUX
eurjchem-1680	96	46	rearranged	rearrange	VERB
eurjchem-1680	96	47	to	to	PART
eurjchem-1680	96	48	give	give	VERB
eurjchem-1680	96	49	,	,	PUNCT
eurjchem-1680	96	50	respectively	respectively	ADV
eurjchem-1680	96	51	:	:	PUNCT
eurjchem-1680	96	52	log	log	NOUN
eurjchem-1680	96	53	k	k	NOUN
eurjchem-1680	96	54	=	=	PUNCT
eurjchem-1680	96	55	myx	myx	PROPN
eurjchem-1680	96	56	+	+	CCONJ
eurjchem-1680	96	57	(	(	PUNCT
eurjchem-1680	96	58	c+	c+	X
eurjchem-1680	96	59	log	log	NOUN
eurjchem-1680	96	60	ko	ko	PROPN
eurjchem-1680	96	61	)	)	PUNCT
eurjchem-1680	96	62	(	(	PUNCT
eurjchem-1680	96	63	3	3	X
eurjchem-1680	96	64	)	)	PUNCT
eurjchem-1680	96	65	and	and	CCONJ
eurjchem-1680	96	66	log	log	VERB
eurjchem-1680	96	67	k	k	PROPN
eurjchem-1680	96	68	=	=	PUNCT
eurjchem-1680	96	69	lnt	lnt	PROPN
eurjchem-1680	96	70	+	+	CCONJ
eurjchem-1680	96	71	myx	myx	PROPN
eurjchem-1680	96	72	+	+	X
eurjchem-1680	96	73	(	(	PUNCT
eurjchem-1680	96	74	c	c	NOUN
eurjchem-1680	96	75	+	+	CCONJ
eurjchem-1680	96	76	log	log	PROPN
eurjchem-1680	96	77	ko	ko	PROPN
eurjchem-1680	96	78	)	)	PUNCT
eurjchem-1680	96	79	(	(	PUNCT
eurjchem-1680	96	80	4	4	X
eurjchem-1680	96	81	)	)	PUNCT
eurjchem-1680	96	82	such	such	ADJ
eurjchem-1680	96	83	that	that	SCONJ
eurjchem-1680	96	84	in	in	ADP
eurjchem-1680	96	85	both	both	DET
eurjchem-1680	96	86	instances	instance	NOUN
eurjchem-1680	96	87	,	,	PUNCT
eurjchem-1680	96	88	with	with	ADP
eurjchem-1680	96	89	correlation	correlation	NOUN
eurjchem-1680	96	90	of	of	ADP
eurjchem-1680	96	91	log	log	NOUN
eurjchem-1680	96	92	k	k	NOUN
eurjchem-1680	96	93	,	,	PUNCT
eurjchem-1680	96	94	rather	rather	ADV
eurjchem-1680	96	95	than	than	ADP
eurjchem-1680	96	96	log(k	log(k	PROPN
eurjchem-1680	96	97	/	/	SYM
eurjchem-1680	96	98	ko	ko	PROPN
eurjchem-1680	96	99	)	)	PUNCT
eurjchem-1680	96	100	,	,	PUNCT
eurjchem-1680	96	101	the	the	DET
eurjchem-1680	96	102	residual	residual	ADJ
eurjchem-1680	96	103	term	term	NOUN
eurjchem-1680	96	104	is	be	AUX
eurjchem-1680	96	105	(	(	PUNCT
eurjchem-1680	96	106	c	c	NOUN
eurjchem-1680	96	107	+	+	CCONJ
eurjchem-1680	96	108	log	log	PROPN
eurjchem-1680	96	109	ko	ko	PROPN
eurjchem-1680	96	110	)	)	PUNCT
eurjchem-1680	96	111	rather	rather	ADV
eurjchem-1680	96	112	than	than	ADP
eurjchem-1680	96	113	c.	c.	NOUN
eurjchem-1680	96	114	correlating	correlate	VERB
eurjchem-1680	96	115	only	only	ADV
eurjchem-1680	96	116	against	against	ADP
eurjchem-1680	96	117	yots	yot	NOUN
eurjchem-1680	96	118	values	value	NOUN
eurjchem-1680	96	119	,	,	PUNCT
eurjchem-1680	96	120	the	the	DET
eurjchem-1680	96	121	m	m	NOUN
eurjchem-1680	96	122	values	value	NOUN
eurjchem-1680	96	123	obtained	obtain	VERB
eurjchem-1680	96	124	for	for	ADP
eurjchem-1680	96	125	4	4	NUM
eurjchem-1680	96	126	-	-	SYM
eurjchem-1680	96	127	6	6	NUM
eurjchem-1680	96	128	are	be	AUX
eurjchem-1680	96	129	similar	similar	ADJ
eurjchem-1680	96	130	to	to	ADP
eurjchem-1680	96	131	those	those	PRON
eurjchem-1680	96	132	reported	report	VERB
eurjchem-1680	96	133	by	by	ADP
eurjchem-1680	96	134	creary	creary	ADJ
eurjchem-1680	96	135	[	[	X
eurjchem-1680	96	136	10	10	NUM
eurjchem-1680	96	137	]	]	PUNCT
eurjchem-1680	96	138	but	but	CCONJ
eurjchem-1680	96	139	the	the	DET
eurjchem-1680	96	140	detailed	detailed	ADJ
eurjchem-1680	96	141	correlations	correlation	NOUN
eurjchem-1680	96	142	allow	allow	VERB
eurjchem-1680	96	143	assessment	assessment	NOUN
eurjchem-1680	96	144	in	in	ADP
eurjchem-1680	96	145	terms	term	NOUN
eurjchem-1680	96	146	of	of	ADP
eurjchem-1680	96	147	standard	standard	ADJ
eurjchem-1680	96	148	error	error	NOUN
eurjchem-1680	96	149	,	,	PUNCT
eurjchem-1680	96	150	correlation	correlation	NOUN
eurjchem-1680	96	151	coefficient	coefficient	NOUN
eurjchem-1680	96	152	and	and	CCONJ
eurjchem-1680	96	153	f	f	NOUN
eurjchem-1680	96	154	-	-	PUNCT
eurjchem-1680	96	155	test	test	NOUN
eurjchem-1680	96	156	value	value	NOUN
eurjchem-1680	96	157	.	.	PUNCT
eurjchem-1680	97	1	as	as	SCONJ
eurjchem-1680	97	2	expected	expect	VERB
eurjchem-1680	97	3	,	,	PUNCT
eurjchem-1680	97	4	solvolysis	solvolysis	NOUN
eurjchem-1680	97	5	of	of	ADP
eurjchem-1680	97	6	3	3	NUM
eurjchem-1680	97	7	gives	give	VERB
eurjchem-1680	97	8	an	an	DET
eurjchem-1680	97	9	m	m	NOUN
eurjchem-1680	97	10	-	-	NOUN
eurjchem-1680	97	11	value	value	NOUN
eurjchem-1680	97	12	with	with	ADP
eurjchem-1680	97	13	a	a	DET
eurjchem-1680	97	14	largest	large	ADJ
eurjchem-1680	97	15	standard	standard	ADJ
eurjchem-1680	97	16	error	error	NOUN
eurjchem-1680	97	17	,	,	PUNCT
eurjchem-1680	97	18	0.22±0.13	0.22±0.13	NOUN
eurjchem-1680	97	19	,	,	PUNCT
eurjchem-1680	97	20	and	and	CCONJ
eurjchem-1680	97	21	a	a	DET
eurjchem-1680	97	22	low	low	ADJ
eurjchem-1680	97	23	,	,	PUNCT
eurjchem-1680	97	24	0.632	0.632	NUM
eurjchem-1680	97	25	correlation	correlation	NOUN
eurjchem-1680	97	26	coefficient	coefficient	NOUN
eurjchem-1680	97	27	.	.	PUNCT
eurjchem-1680	98	1	the	the	DET
eurjchem-1680	98	2	twoterm	twoterm	NOUN
eurjchem-1680	98	3	correlation	correlation	NOUN
eurjchem-1680	98	4	is	be	AUX
eurjchem-1680	98	5	also	also	ADV
eurjchem-1680	98	6	poor	poor	ADJ
eurjchem-1680	98	7	(	(	PUNCT
eurjchem-1680	98	8	r	r	NOUN
eurjchem-1680	98	9	=	=	NOUN
eurjchem-1680	98	10	0.859	0.859	NUM
eurjchem-1680	98	11	)	)	PUNCT
eurjchem-1680	98	12	.	.	PUNCT
eurjchem-1680	99	1	as	as	SCONJ
eurjchem-1680	99	2	observed	observe	VERB
eurjchem-1680	99	3	by	by	ADP
eurjchem-1680	99	4	creary	creary	ADJ
eurjchem-1680	99	5	,	,	PUNCT
eurjchem-1680	99	6	the	the	DET
eurjchem-1680	99	7	one	one	NUM
eurjchem-1680	99	8	-	-	PUNCT
eurjchem-1680	99	9	term	term	NOUN
eurjchem-1680	99	10	correlation	correlation	NOUN
eurjchem-1680	99	11	is	be	AUX
eurjchem-1680	99	12	considerably	considerably	ADV
eurjchem-1680	99	13	improved	improve	VERB
eurjchem-1680	99	14	when	when	SCONJ
eurjchem-1680	99	15	the	the	DET
eurjchem-1680	99	16	data	datum	NOUN
eurjchem-1680	99	17	point	point	VERB
eurjchem-1680	99	18	for	for	SCONJ
eurjchem-1680	99	19	solvolysis	solvolysis	NOUN
eurjchem-1680	99	20	in	in	ADP
eurjchem-1680	99	21	ethanol	ethanol	NOUN
eurjchem-1680	99	22	is	be	AUX
eurjchem-1680	99	23	omitted	omit	VERB
eurjchem-1680	99	24	.	.	PUNCT
eurjchem-1680	100	1	the	the	DET
eurjchem-1680	100	2	resultant	resultant	ADJ
eurjchem-1680	100	3	five	five	NUM
eurjchem-1680	100	4	-	-	PUNCT
eurjchem-1680	100	5	point	point	NOUN
eurjchem-1680	100	6	correlation	correlation	NOUN
eurjchem-1680	100	7	against	against	ADP
eurjchem-1680	100	8	yots	yot	NOUN
eurjchem-1680	100	9	values	value	NOUN
eurjchem-1680	100	10	leads	lead	VERB
eurjchem-1680	100	11	to	to	ADP
eurjchem-1680	100	12	an	an	DET
eurjchem-1680	100	13	m	m	NOUN
eurjchem-1680	100	14	-	-	NOUN
eurjchem-1680	100	15	value	value	NOUN
eurjchem-1680	100	16	of	of	ADP
eurjchem-1680	100	17	0.40±0.14	0.40±0.14	NOUN
eurjchem-1680	100	18	and	and	CCONJ
eurjchem-1680	100	19	a	a	DET
eurjchem-1680	100	20	correlation	correlation	NOUN
eurjchem-1680	100	21	coefficient	coefficient	NOUN
eurjchem-1680	100	22	of	of	ADP
eurjchem-1680	100	23	0.852	0.852	NUM
eurjchem-1680	100	24	.	.	PUNCT
eurjchem-1680	101	1	the	the	DET
eurjchem-1680	101	2	goodness	goodness	NOUN
eurjchem-1680	101	3	-	-	PUNCT
eurjchem-1680	101	4	of	of	ADP
eurjchem-1680	101	5	-	-	PUNCT
eurjchem-1680	101	6	fit	fit	NOUN
eurjchem-1680	101	7	is	be	AUX
eurjchem-1680	101	8	further	far	ADV
eurjchem-1680	101	9	improved	improve	VERB
eurjchem-1680	101	10	by	by	ADP
eurjchem-1680	101	11	use	use	NOUN
eurjchem-1680	101	12	of	of	ADP
eurjchem-1680	101	13	the	the	DET
eurjchem-1680	101	14	two	two	NUM
eurjchem-1680	101	15	-	-	PUNCT
eurjchem-1680	101	16	term	term	NOUN
eurjchem-1680	101	17	correlation	correlation	NOUN
eurjchem-1680	101	18	with	with	ADP
eurjchem-1680	101	19	l	l	NOUN
eurjchem-1680	101	20	=	=	SYM
eurjchem-1680	101	21	0.37±0.14	0.37±0.14	PROPN
eurjchem-1680	101	22	,	,	PUNCT
eurjchem-1680	101	23	m	m	VERB
eurjchem-1680	101	24	=	=	NOUN
eurjchem-1680	101	25	0.71±0.14	0.71±0.14	PROPN
eurjchem-1680	101	26	and	and	CCONJ
eurjchem-1680	101	27	r	r	NOUN
eurjchem-1680	101	28	=	=	SYM
eurjchem-1680	101	29	0.968	0.968	NUM
eurjchem-1680	101	30	,	,	PUNCT
eurjchem-1680	101	31	with	with	ADP
eurjchem-1680	101	32	the	the	DET
eurjchem-1680	101	33	correlation	correlation	NOUN
eurjchem-1680	101	34	coefficient	coefficient	NOUN
eurjchem-1680	101	35	now	now	ADV
eurjchem-1680	101	36	being	be	AUX
eurjchem-1680	101	37	only	only	ADV
eurjchem-1680	101	38	very	very	ADV
eurjchem-1680	101	39	slightly	slightly	ADV
eurjchem-1680	101	40	lower	low	ADJ
eurjchem-1680	101	41	than	than	ADP
eurjchem-1680	101	42	those	those	PRON
eurjchem-1680	101	43	obtained	obtain	VERB
eurjchem-1680	101	44	for	for	ADP
eurjchem-1680	101	45	the	the	DET
eurjchem-1680	101	46	two	two	NUM
eurjchem-1680	101	47	-	-	PUNCT
eurjchem-1680	101	48	term	term	NOUN
eurjchem-1680	101	49	correlations	correlation	NOUN
eurjchem-1680	101	50	of	of	ADP
eurjchem-1680	101	51	the	the	DET
eurjchem-1680	101	52	solvolyses	solvolyse	NOUN
eurjchem-1680	101	53	of	of	ADP
eurjchem-1680	101	54	4	4	NUM
eurjchem-1680	101	55	through	through	ADP
eurjchem-1680	101	56	6	6	NUM
eurjchem-1680	101	57	(	(	PUNCT
eurjchem-1680	101	58	table	table	NOUN
eurjchem-1680	101	59	2	2	NUM
eurjchem-1680	101	60	)	)	PUNCT
eurjchem-1680	101	61	.	.	PUNCT
eurjchem-1680	102	1	consistent	consistent	ADJ
eurjchem-1680	102	2	with	with	ADP
eurjchem-1680	102	3	the	the	DET
eurjchem-1680	102	4	proposed	propose	VERB
eurjchem-1680	102	5	unimolecular	unimolecular	ADJ
eurjchem-1680	102	6	processes	process	NOUN
eurjchem-1680	102	7	for	for	ADP
eurjchem-1680	102	8	the	the	DET
eurjchem-1680	102	9	solvolyses	solvolyse	NOUN
eurjchem-1680	102	10	of	of	ADP
eurjchem-1680	102	11	4	4	NUM
eurjchem-1680	102	12	6	6	NUM
eurjchem-1680	102	13	,	,	PUNCT
eurjchem-1680	102	14	good	good	ADJ
eurjchem-1680	102	15	correlations	correlation	NOUN
eurjchem-1680	102	16	are	be	AUX
eurjchem-1680	102	17	obtained	obtain	VERB
eurjchem-1680	102	18	using	use	VERB
eurjchem-1680	102	19	the	the	DET
eurjchem-1680	102	20	one	one	NUM
eurjchem-1680	102	21	-	-	PUNCT
eurjchem-1680	102	22	term	term	NOUN
eurjchem-1680	102	23	grunwald	grunwald	NOUN
eurjchem-1680	102	24	-	-	PUNCT
eurjchem-1680	102	25	winstein	winstein	NOUN
eurjchem-1680	102	26	equation	equation	NOUN
eurjchem-1680	102	27	(	(	PUNCT
eurjchem-1680	102	28	r	r	NOUN
eurjchem-1680	102	29	=	=	SYM
eurjchem-1680	102	30	0.966	0.966	NUM
eurjchem-1680	102	31	to	to	ADP
eurjchem-1680	102	32	0.999	0.999	NUM
eurjchem-1680	102	33	)	)	PUNCT
eurjchem-1680	102	34	and	and	CCONJ
eurjchem-1680	102	35	the	the	DET
eurjchem-1680	102	36	two	two	NUM
eurjchem-1680	102	37	-	-	PUNCT
eurjchem-1680	102	38	term	term	NOUN
eurjchem-1680	102	39	equations	equation	NOUN
eurjchem-1680	102	40	leads	lead	VERB
eurjchem-1680	102	41	to	to	ADP
eurjchem-1680	102	42	l	l	NOUN
eurjchem-1680	102	43	values	value	NOUN
eurjchem-1680	102	44	statistically	statistically	ADV
eurjchem-1680	102	45	close	close	ADJ
eurjchem-1680	102	46	to	to	ADP
eurjchem-1680	102	47	zero	zero	NUM
eurjchem-1680	102	48	(	(	PUNCT
eurjchem-1680	102	49	0.03±0.04	0.03±0.04	NOUN
eurjchem-1680	102	50	to	to	ADP
eurjchem-1680	102	51	0.10±0.17	0.10±0.17	PROPN
eurjchem-1680	102	52	)	)	PUNCT
eurjchem-1680	102	53	and	and	CCONJ
eurjchem-1680	102	54	with	with	ADP
eurjchem-1680	102	55	essentially	essentially	ADV
eurjchem-1680	102	56	no	no	DET
eurjchem-1680	102	57	change	change	NOUN
eurjchem-1680	102	58	in	in	ADP
eurjchem-1680	102	59	the	the	DET
eurjchem-1680	102	60	r	r	NOUN
eurjchem-1680	102	61	values	value	NOUN
eurjchem-1680	102	62	(	(	PUNCT
eurjchem-1680	102	63	0.971	0.971	NUM
eurjchem-1680	102	64	to	to	ADP
eurjchem-1680	102	65	0.999	0.999	NUM
eurjchem-1680	102	66	)	)	PUNCT
eurjchem-1680	102	67	.	.	PUNCT
eurjchem-1680	103	1	the	the	DET
eurjchem-1680	103	2	analyses	analysis	NOUN
eurjchem-1680	103	3	of	of	ADP
eurjchem-1680	103	4	the	the	DET
eurjchem-1680	103	5	solvolyses	solvolyse	NOUN
eurjchem-1680	103	6	of	of	ADP
eurjchem-1680	103	7	the	the	DET
eurjchem-1680	103	8	mesylates	mesylate	NOUN
eurjchem-1680	103	9	4	4	NUM
eurjchem-1680	103	10	-	-	SYM
eurjchem-1680	103	11	6	6	NUM
eurjchem-1680	103	12	reported	report	VERB
eurjchem-1680	103	13	in	in	ADP
eurjchem-1680	103	14	table	table	NOUN
eurjchem-1680	103	15	2	2	NUM
eurjchem-1680	103	16	,	,	PUNCT
eurjchem-1680	103	17	strongly	strongly	ADV
eurjchem-1680	103	18	supports	support	VERB
eurjchem-1680	103	19	the	the	DET
eurjchem-1680	103	20	proposal	proposal	NOUN
eurjchem-1680	103	21	of	of	ADP
eurjchem-1680	103	22	essentially	essentially	ADV
eurjchem-1680	103	23	classical	classical	ADJ
eurjchem-1680	103	24	sn1	sn1	PROPN
eurjchem-1680	103	25	+	+	CCONJ
eurjchem-1680	103	26	e1	e1	NOUN
eurjchem-1680	103	27	reaction	reaction	NOUN
eurjchem-1680	103	28	schemes	scheme	NOUN
eurjchem-1680	103	29	.	.	PUNCT
eurjchem-1680	104	1	further	far	ADV
eurjchem-1680	104	2	,	,	PUNCT
eurjchem-1680	104	3	the	the	DET
eurjchem-1680	104	4	reported	report	VERB
eurjchem-1680	104	5	[	[	X
eurjchem-1680	104	6	10	10	NUM
eurjchem-1680	104	7	]	]	PUNCT
eurjchem-1680	104	8	product	product	NOUN
eurjchem-1680	104	9	studies	study	NOUN
eurjchem-1680	104	10	,	,	PUNCT
eurjchem-1680	104	11	showing	show	VERB
eurjchem-1680	104	12	the	the	DET
eurjchem-1680	104	13	principal	principal	ADJ
eurjchem-1680	104	14	product	product	NOUN
eurjchem-1680	104	15	to	to	PART
eurjchem-1680	104	16	be	be	AUX
eurjchem-1680	104	17	that	that	SCONJ
eurjchem-1680	104	18	formed	form	VERB
eurjchem-1680	104	19	by	by	ADP
eurjchem-1680	104	20	an	an	DET
eurjchem-1680	104	21	elimination	elimination	NOUN
eurjchem-1680	104	22	pathway	pathway	NOUN
eurjchem-1680	104	23	strongly	strongly	ADV
eurjchem-1680	104	24	indicates	indicate	VERB
eurjchem-1680	104	25	that	that	SCONJ
eurjchem-1680	104	26	the	the	DET
eurjchem-1680	104	27	reactions	reaction	NOUN
eurjchem-1680	104	28	are	be	AUX
eurjchem-1680	104	29	predominantly	predominantly	ADV
eurjchem-1680	104	30	completed	complete	VERB
eurjchem-1680	104	31	by	by	ADP
eurjchem-1680	104	32	proton	proton	NOUN
eurjchem-1680	104	33	abstraction	abstraction	NOUN
eurjchem-1680	104	34	rather	rather	ADV
eurjchem-1680	104	35	than	than	ADP
eurjchem-1680	104	36	by	by	ADP
eurjchem-1680	104	37	collapse	collapse	NOUN
eurjchem-1680	104	38	to	to	ADP
eurjchem-1680	104	39	a	a	DET
eurjchem-1680	104	40	substitution	substitution	NOUN
eurjchem-1680	104	41	product	product	NOUN
eurjchem-1680	104	42	.	.	PUNCT
eurjchem-1680	105	1	such	such	ADJ
eurjchem-1680	105	2	reactions	reaction	NOUN
eurjchem-1680	105	3	require	require	VERB
eurjchem-1680	105	4	the	the	DET
eurjchem-1680	105	5	terminology	terminology	NOUN
eurjchem-1680	105	6	sn2	sn2	PROPN
eurjchem-1680	105	7	(	(	PUNCT
eurjchem-1680	105	8	intermediate	intermediate	ADJ
eurjchem-1680	105	9	)	)	PUNCT
eurjchem-1680	106	1	[	[	X
eurjchem-1680	106	2	8	8	NUM
eurjchem-1680	106	3	]	]	PUNCT
eurjchem-1680	106	4	to	to	PART
eurjchem-1680	106	5	be	be	AUX
eurjchem-1680	106	6	modified	modify	VERB
eurjchem-1680	106	7	to	to	ADP
eurjchem-1680	106	8	e2	e2	PROPN
eurjchem-1680	106	9	(	(	PUNCT
eurjchem-1680	106	10	intermediate	intermediate	ADJ
eurjchem-1680	106	11	)	)	PUNCT
eurjchem-1680	106	12	when	when	SCONJ
eurjchem-1680	106	13	elimination	elimination	NOUN
eurjchem-1680	106	14	strongly	strongly	ADV
eurjchem-1680	106	15	dominates	dominate	VERB
eurjchem-1680	106	16	or	or	CCONJ
eurjchem-1680	106	17	,	,	PUNCT
eurjchem-1680	106	18	in	in	ADP
eurjchem-1680	106	19	general	general	ADJ
eurjchem-1680	106	20	,	,	PUNCT
eurjchem-1680	106	21	to	to	ADP
eurjchem-1680	106	22	[	[	X
eurjchem-1680	106	23	sn2	sn2	PROPN
eurjchem-1680	106	24	+	+	CCONJ
eurjchem-1680	106	25	e2	e2	PROPN
eurjchem-1680	106	26	]	]	PUNCT
eurjchem-1680	106	27	(	(	PUNCT
eurjchem-1680	106	28	intermediate	intermediate	ADJ
eurjchem-1680	106	29	)	)	PUNCT
eurjchem-1680	106	30	.	.	PUNCT
eurjchem-1680	107	1	one	one	NUM
eurjchem-1680	107	2	further	further	ADJ
eurjchem-1680	107	3	point	point	NOUN
eurjchem-1680	107	4	that	that	PRON
eurjchem-1680	107	5	should	should	AUX
eurjchem-1680	107	6	be	be	AUX
eurjchem-1680	107	7	addressed	address	VERB
eurjchem-1680	107	8	is	be	AUX
eurjchem-1680	107	9	the	the	DET
eurjchem-1680	107	10	question	question	NOUN
eurjchem-1680	107	11	as	as	ADP
eurjchem-1680	107	12	to	to	ADP
eurjchem-1680	107	13	why	why	SCONJ
eurjchem-1680	107	14	the	the	DET
eurjchem-1680	107	15	replacement	replacement	NOUN
eurjchem-1680	107	16	of	of	ADP
eurjchem-1680	107	17	the	the	DET
eurjchem-1680	107	18	bromine	bromine	NOUN
eurjchem-1680	107	19	in	in	ADP
eurjchem-1680	107	20	substrate	substrate	NOUN
eurjchem-1680	107	21	2	2	NUM
eurjchem-1680	107	22	by	by	ADP
eurjchem-1680	107	23	the	the	DET
eurjchem-1680	107	24	mesylate	mesylate	NOUN
eurjchem-1680	107	25	group	group	NOUN
eurjchem-1680	107	26	to	to	PART
eurjchem-1680	107	27	give	give	VERB
eurjchem-1680	107	28	substrate	substrate	NOUN
eurjchem-1680	107	29	4	4	NUM
eurjchem-1680	107	30	leads	lead	NOUN
eurjchem-1680	107	31	to	to	ADP
eurjchem-1680	107	32	very	very	ADV
eurjchem-1680	107	33	different	different	ADJ
eurjchem-1680	107	34	solvolytic	solvolytic	ADJ
eurjchem-1680	107	35	behavior	behavior	NOUN
eurjchem-1680	107	36	,	,	PUNCT
eurjchem-1680	107	37	as	as	SCONJ
eurjchem-1680	107	38	is	be	AUX
eurjchem-1680	107	39	indicated	indicate	VERB
eurjchem-1680	107	40	by	by	ADP
eurjchem-1680	107	41	the	the	DET
eurjchem-1680	107	42	entries	entry	NOUN
eurjchem-1680	107	43	in	in	ADP
eurjchem-1680	107	44	table	table	NOUN
eurjchem-1680	107	45	2	2	NUM
eurjchem-1680	107	46	,	,	PUNCT
eurjchem-1680	107	47	with	with	ADP
eurjchem-1680	107	48	the	the	DET
eurjchem-1680	107	49	l	l	NOUN
eurjchem-1680	107	50	value	value	NOUN
eurjchem-1680	107	51	falling	fall	VERB
eurjchem-1680	107	52	from	from	ADP
eurjchem-1680	107	53	0.63±0.06	0.63±0.06	PROPN
eurjchem-1680	107	54	for	for	ADP
eurjchem-1680	107	55	solvolyses	solvolyse	NOUN
eurjchem-1680	107	56	of	of	ADP
eurjchem-1680	107	57	2	2	NUM
eurjchem-1680	107	58	to	to	ADP
eurjchem-1680	107	59	0.10±0.17	0.10±0.17	NOUN
eurjchem-1680	107	60	for	for	ADP
eurjchem-1680	107	61	solvolyses	solvolyse	NOUN
eurjchem-1680	107	62	of	of	ADP
eurjchem-1680	107	63	4	4	NUM
eurjchem-1680	107	64	.	.	PUNCT
eurjchem-1680	108	1	it	it	PRON
eurjchem-1680	108	2	is	be	AUX
eurjchem-1680	108	3	well	well	ADV
eurjchem-1680	108	4	established	establish	VERB
eurjchem-1680	108	5	that	that	SCONJ
eurjchem-1680	108	6	the	the	DET
eurjchem-1680	108	7	ratio	ratio	NOUN
eurjchem-1680	108	8	of	of	ADP
eurjchem-1680	108	9	the	the	DET
eurjchem-1680	108	10	specific	specific	ADJ
eurjchem-1680	108	11	rate	rate	NOUN
eurjchem-1680	108	12	of	of	ADP
eurjchem-1680	108	13	solvolysis	solvolysis	NOUN
eurjchem-1680	108	14	in	in	ADP
eurjchem-1680	108	15	a	a	DET
eurjchem-1680	108	16	given	give	VERB
eurjchem-1680	108	17	solvent	solvent	NOUN
eurjchem-1680	108	18	for	for	ADP
eurjchem-1680	108	19	a	a	DET
eurjchem-1680	108	20	sulfonate	sulfonate	NOUN
eurjchem-1680	108	21	relative	relative	NOUN
eurjchem-1680	108	22	to	to	ADP
eurjchem-1680	108	23	that	that	PRON
eurjchem-1680	108	24	of	of	ADP
eurjchem-1680	108	25	a	a	DET
eurjchem-1680	108	26	halide	halide	NOUN
eurjchem-1680	108	27	can	can	AUX
eurjchem-1680	108	28	give	give	VERB
eurjchem-1680	108	29	useful	useful	ADJ
eurjchem-1680	108	30	information	information	NOUN
eurjchem-1680	108	31	regarding	regard	VERB
eurjchem-1680	108	32	mechanism	mechanism	NOUN
eurjchem-1680	108	33	.	.	PUNCT
eurjchem-1680	109	1	initial	initial	ADJ
eurjchem-1680	109	2	consideration	consideration	NOUN
eurjchem-1680	109	3	focused	focus	VERB
eurjchem-1680	109	4	on	on	ADP
eurjchem-1680	109	5	the	the	DET
eurjchem-1680	109	6	extent	extent	NOUN
eurjchem-1680	109	7	of	of	ADP
eurjchem-1680	109	8	charge	charge	NOUN
eurjchem-1680	109	9	development	development	NOUN
eurjchem-1680	109	10	on	on	ADP
eurjchem-1680	109	11	the	the	DET
eurjchem-1680	109	12	leaving	leave	VERB
eurjchem-1680	109	13	group	group	NOUN
eurjchem-1680	109	14	at	at	ADP
eurjchem-1680	109	15	the	the	DET
eurjchem-1680	109	16	transition	transition	NOUN
eurjchem-1680	109	17	state	state	NOUN
eurjchem-1680	110	1	[	[	X
eurjchem-1680	110	2	24,26	24,26	NUM
eurjchem-1680	110	3	-	-	SYM
eurjchem-1680	110	4	28	28	NUM
eurjchem-1680	110	5	]	]	PUNCT
eurjchem-1680	110	6	.	.	PUNCT
eurjchem-1680	111	1	however	however	ADV
eurjchem-1680	111	2	,	,	PUNCT
eurjchem-1680	111	3	it	it	PRON
eurjchem-1680	111	4	has	have	AUX
eurjchem-1680	111	5	since	since	ADV
eurjchem-1680	111	6	been	be	AUX
eurjchem-1680	111	7	proposed	propose	VERB
eurjchem-1680	111	8	that	that	SCONJ
eurjchem-1680	111	9	in	in	ADP
eurjchem-1680	111	10	relatively	relatively	ADV
eurjchem-1680	111	11	crowded	crowded	ADJ
eurjchem-1680	111	12	tertiary	tertiary	ADJ
eurjchem-1680	111	13	structures	structure	NOUN
eurjchem-1680	111	14	,	,	PUNCT
eurjchem-1680	111	15	such	such	ADJ
eurjchem-1680	111	16	as	as	ADP
eurjchem-1680	111	17	with	with	ADP
eurjchem-1680	111	18	the	the	DET
eurjchem-1680	111	19	tertiary	tertiary	ADJ
eurjchem-1680	111	20	alpha	alpha	NOUN
eurjchem-1680	111	21	-	-	PUNCT
eurjchem-1680	111	22	substituted	substitute	VERB
eurjchem-1680	111	23	ketones	ketone	NOUN
eurjchem-1680	111	24	2	2	NUM
eurjchem-1680	111	25	and	and	CCONJ
eurjchem-1680	111	26	4	4	NUM
eurjchem-1680	111	27	,	,	PUNCT
eurjchem-1680	111	28	the	the	DET
eurjchem-1680	111	29	koms	koms	PROPN
eurjchem-1680	111	30	/	/	SYM
eurjchem-1680	111	31	kbr	kbr	PROPN
eurjchem-1680	111	32	ratio	ratio	NOUN
eurjchem-1680	111	33	(	(	PUNCT
eurjchem-1680	111	34	for	for	ADP
eurjchem-1680	111	35	example	example	NOUN
eurjchem-1680	111	36	)	)	PUNCT
eurjchem-1680	111	37	can	can	AUX
eurjchem-1680	111	38	be	be	AUX
eurjchem-1680	111	39	raised	raise	VERB
eurjchem-1680	111	40	considerably	considerably	ADV
eurjchem-1680	111	41	by	by	ADP
eurjchem-1680	111	42	steric	steric	ADJ
eurjchem-1680	111	43	factors	factor	NOUN
eurjchem-1680	111	44	[	[	X
eurjchem-1680	111	45	29	29	NUM
eurjchem-1680	111	46	]	]	PUNCT
eurjchem-1680	111	47	being	be	AUX
eurjchem-1680	111	48	much	much	ADV
eurjchem-1680	111	49	greater	great	ADJ
eurjchem-1680	111	50	for	for	ADP
eurjchem-1680	111	51	the	the	DET
eurjchem-1680	111	52	bulkier	bulky	ADJ
eurjchem-1680	111	53	sulfonate	sulfonate	NOUN
eurjchem-1680	111	54	leaving	leave	VERB
eurjchem-1680	111	55	group	group	NOUN
eurjchem-1680	111	56	than	than	ADP
eurjchem-1680	111	57	for	for	ADP
eurjchem-1680	111	58	the	the	DET
eurjchem-1680	111	59	halide	halide	NOUN
eurjchem-1680	111	60	ion	ion	NOUN
eurjchem-1680	111	61	leaving	leaving	NOUN
eurjchem-1680	111	62	group	group	NOUN
eurjchem-1680	112	1	[	[	X
eurjchem-1680	112	2	30,31	30,31	NUM
eurjchem-1680	112	3	]	]	PUNCT
eurjchem-1680	112	4	especially	especially	ADV
eurjchem-1680	112	5	for	for	ADP
eurjchem-1680	112	6	unimolecular	unimolecular	ADJ
eurjchem-1680	112	7	solvolyses	solvolyse	NOUN
eurjchem-1680	112	8	via	via	ADP
eurjchem-1680	112	9	the	the	DET
eurjchem-1680	112	10	carbocation	carbocation	NOUN
eurjchem-1680	112	11	,	,	PUNCT
eurjchem-1680	112	12	when	when	SCONJ
eurjchem-1680	112	13	a	a	DET
eurjchem-1680	112	14	late	late	ADJ
eurjchem-1680	112	15	transition	transition	NOUN
eurjchem-1680	112	16	state	state	NOUN
eurjchem-1680	112	17	is	be	AUX
eurjchem-1680	112	18	involved	involve	VERB
eurjchem-1680	112	19	.	.	PUNCT
eurjchem-1680	113	1	inspection	inspection	NOUN
eurjchem-1680	113	2	of	of	ADP
eurjchem-1680	113	3	the	the	DET
eurjchem-1680	113	4	data	datum	NOUN
eurjchem-1680	113	5	in	in	ADP
eurjchem-1680	113	6	table	table	NOUN
eurjchem-1680	113	7	2	2	NUM
eurjchem-1680	113	8	shows	show	VERB
eurjchem-1680	113	9	that	that	SCONJ
eurjchem-1680	113	10	,	,	PUNCT
eurjchem-1680	113	11	with	with	ADP
eurjchem-1680	113	12	the	the	DET
eurjchem-1680	113	13	application	application	NOUN
eurjchem-1680	113	14	of	of	ADP
eurjchem-1680	113	15	equation	equation	NOUN
eurjchem-1680	113	16	(	(	PUNCT
eurjchem-1680	113	17	2	2	NUM
eurjchem-1680	113	18	)	)	PUNCT
eurjchem-1680	113	19	,	,	PUNCT
eurjchem-1680	113	20	the	the	DET
eurjchem-1680	113	21	m	m	NOUN
eurjchem-1680	113	22	-	-	PUNCT
eurjchem-1680	113	23	values	value	NOUN
eurjchem-1680	113	24	are	be	AUX
eurjchem-1680	113	25	similar	similar	ADJ
eurjchem-1680	113	26	for	for	ADP
eurjchem-1680	113	27	the	the	DET
eurjchem-1680	113	28	bromide	bromide	NOUN
eurjchem-1680	113	29	and	and	CCONJ
eurjchem-1680	113	30	the	the	DET
eurjchem-1680	113	31	mesylate	mesylate	NOUN
eurjchem-1680	113	32	.	.	PUNCT
eurjchem-1680	114	1	however	however	ADV
eurjchem-1680	114	2	,	,	PUNCT
eurjchem-1680	114	3	these	these	DET
eurjchem-1680	114	4	values	value	NOUN
eurjchem-1680	114	5	can	can	AUX
eurjchem-1680	114	6	not	not	PART
eurjchem-1680	114	7	be	be	AUX
eurjchem-1680	114	8	directly	directly	ADV
eurjchem-1680	114	9	compared	compare	VERB
eurjchem-1680	114	10	because	because	SCONJ
eurjchem-1680	114	11	one	one	NUM
eurjchem-1680	114	12	is	be	AUX
eurjchem-1680	114	13	based	base	VERB
eurjchem-1680	114	14	on	on	ADP
eurjchem-1680	114	15	the	the	DET
eurjchem-1680	114	16	ybr	ybr	PROPN
eurjchem-1680	114	17	scale	scale	NOUN
eurjchem-1680	114	18	and	and	CCONJ
eurjchem-1680	114	19	the	the	DET
eurjchem-1680	114	20	other	other	ADJ
eurjchem-1680	114	21	on	on	ADP
eurjchem-1680	114	22	the	the	DET
eurjchem-1680	114	23	yots	yot	NOUN
eurjchem-1680	114	24	scale	scale	NOUN
eurjchem-1680	114	25	,	,	PUNCT
eurjchem-1680	114	26	with	with	ADP
eurjchem-1680	114	27	the	the	DET
eurjchem-1680	114	28	variations	variation	NOUN
eurjchem-1680	114	29	in	in	ADP
eurjchem-1680	114	30	ybr	ybr	PROPN
eurjchem-1680	114	31	values	value	NOUN
eurjchem-1680	114	32	being	be	AUX
eurjchem-1680	114	33	approximately	approximately	ADV
eurjchem-1680	114	34	23	23	NUM
eurjchem-1680	114	35	%	%	NOUN
eurjchem-1680	114	36	greater	great	ADJ
eurjchem-1680	114	37	[	[	X
eurjchem-1680	114	38	5	5	NUM
eurjchem-1680	114	39	]	]	PUNCT
eurjchem-1680	114	40	.	.	PUNCT
eurjchem-1680	115	1	these	these	DET
eurjchem-1680	115	2	values	value	NOUN
eurjchem-1680	115	3	are	be	AUX
eurjchem-1680	115	4	coupled	couple	VERB
eurjchem-1680	115	5	with	with	ADP
eurjchem-1680	115	6	l	l	NOUN
eurjchem-1680	115	7	values	value	NOUN
eurjchem-1680	115	8	for	for	ADP
eurjchem-1680	115	9	the	the	DET
eurjchem-1680	115	10	solvolyses	solvolyse	NOUN
eurjchem-1680	115	11	of	of	ADP
eurjchem-1680	115	12	essentially	essentially	ADV
eurjchem-1680	115	13	zero	zero	NUM
eurjchem-1680	115	14	for	for	ADP
eurjchem-1680	115	15	4	4	NUM
eurjchem-1680	115	16	and	and	CCONJ
eurjchem-1680	115	17	of	of	ADP
eurjchem-1680	115	18	0.63±0.06	0.63±0.06	NOUN
eurjchem-1680	115	19	for	for	ADP
eurjchem-1680	115	20	2	2	NUM
eurjchem-1680	115	21	.	.	PUNCT
eurjchem-1680	116	1	this	this	PRON
eurjchem-1680	116	2	suggests	suggest	VERB
eurjchem-1680	116	3	that	that	SCONJ
eurjchem-1680	116	4	steric	steric	ADJ
eurjchem-1680	116	5	acceleration	acceleration	NOUN
eurjchem-1680	116	6	being	be	AUX
eurjchem-1680	116	7	larger	large	ADJ
eurjchem-1680	116	8	for	for	ADP
eurjchem-1680	116	9	the	the	DET
eurjchem-1680	116	10	bulkier	bulky	ADJ
eurjchem-1680	116	11	mesylate	mesylate	NOUN
eurjchem-1680	116	12	favors	favor	VERB
eurjchem-1680	116	13	this	this	DET
eurjchem-1680	116	14	substrate	substrate	NOUN
eurjchem-1680	116	15	reacting	react	VERB
eurjchem-1680	116	16	,	,	PUNCT
eurjchem-1680	116	17	as	as	SCONJ
eurjchem-1680	116	18	proposed	propose	VERB
eurjchem-1680	116	19	earlier	early	ADV
eurjchem-1680	116	20	by	by	ADP
eurjchem-1680	116	21	creary	creary	ADJ
eurjchem-1680	116	22	[	[	X
eurjchem-1680	116	23	10	10	NUM
eurjchem-1680	116	24	]	]	PUNCT
eurjchem-1680	116	25	,	,	PUNCT
eurjchem-1680	116	26	by	by	ADP
eurjchem-1680	116	27	an	an	DET
eurjchem-1680	116	28	essentially	essentially	ADV
eurjchem-1680	116	29	unimolecular	unimolecular	ADJ
eurjchem-1680	116	30	ionization	ionization	NOUN
eurjchem-1680	116	31	process	process	NOUN
eurjchem-1680	116	32	(	(	PUNCT
eurjchem-1680	116	33	e1	e1	PROPN
eurjchem-1680	116	34	plus	plus	CCONJ
eurjchem-1680	116	35	sn1	sn1	PROPN
eurjchem-1680	116	36	)	)	PUNCT
eurjchem-1680	116	37	but	but	CCONJ
eurjchem-1680	116	38	that	that	SCONJ
eurjchem-1680	116	39	this	this	DET
eurjchem-1680	116	40	pathway	pathway	NOUN
eurjchem-1680	116	41	is	be	AUX
eurjchem-1680	116	42	considerably	considerably	ADV
eurjchem-1680	116	43	less	less	ADV
eurjchem-1680	116	44	favored	favor	VERB
eurjchem-1680	116	45	for	for	ADP
eurjchem-1680	116	46	the	the	DET
eurjchem-1680	116	47	presently	presently	ADV
eurjchem-1680	116	48	reported	report	VERB
eurjchem-1680	116	49	corresponding	correspond	VERB
eurjchem-1680	116	50	bromide	bromide	NOUN
eurjchem-1680	116	51	2	2	NUM
eurjchem-1680	116	52	,	,	PUNCT
eurjchem-1680	116	53	such	such	ADJ
eurjchem-1680	116	54	that	that	SCONJ
eurjchem-1680	116	55	the	the	DET
eurjchem-1680	116	56	dominant	dominant	ADJ
eurjchem-1680	116	57	pathway	pathway	NOUN
eurjchem-1680	116	58	becomes	become	VERB
eurjchem-1680	116	59	the	the	DET
eurjchem-1680	116	60	[	[	X
eurjchem-1680	116	61	sn2	sn2	PROPN
eurjchem-1680	116	62	+	+	CCONJ
eurjchem-1680	116	63	e2](intermediate	e2](intermediate	ADJ
eurjchem-1680	116	64	)	)	PUNCT
eurjchem-1680	116	65	pathway	pathway	NOUN
eurjchem-1680	116	66	.	.	PUNCT
eurjchem-1680	117	1	supporting	support	VERB
eurjchem-1680	117	2	the	the	DET
eurjchem-1680	117	3	belief	belief	NOUN
eurjchem-1680	117	4	that	that	SCONJ
eurjchem-1680	117	5	this	this	DET
eurjchem-1680	117	6	a	a	DET
eurjchem-1680	117	7	reasonable	reasonable	ADJ
eurjchem-1680	117	8	proposal	proposal	NOUN
eurjchem-1680	117	9	to	to	PART
eurjchem-1680	117	10	explain	explain	VERB
eurjchem-1680	117	11	the	the	DET
eurjchem-1680	117	12	differences	difference	NOUN
eurjchem-1680	117	13	in	in	ADP
eurjchem-1680	117	14	behavior	behavior	NOUN
eurjchem-1680	117	15	,	,	PUNCT
eurjchem-1680	117	16	values	value	NOUN
eurjchem-1680	117	17	of	of	ADP
eurjchem-1680	117	18	the	the	DET
eurjchem-1680	117	19	koms	koms	PROPN
eurjchem-1680	117	20	/	/	SYM
eurjchem-1680	117	21	kbr	kbr	PROPN
eurjchem-1680	117	22	ratio	ratio	NOUN
eurjchem-1680	117	23	as	as	ADV
eurjchem-1680	117	24	large	large	ADJ
eurjchem-1680	117	25	as	as	ADP
eurjchem-1680	117	26	104	104	NUM
eurjchem-1680	117	27	in	in	ADP
eurjchem-1680	117	28	80	80	NUM
eurjchem-1680	117	29	%	%	NOUN
eurjchem-1680	117	30	ethanol	ethanol	NOUN
eurjchem-1680	117	31	and	and	CCONJ
eurjchem-1680	117	32	105	105	NUM
eurjchem-1680	117	33	in	in	ADP
eurjchem-1680	117	34	acetic	acetic	ADJ
eurjchem-1680	117	35	acid	acid	NOUN
eurjchem-1680	117	36	have	have	AUX
eurjchem-1680	117	37	been	be	AUX
eurjchem-1680	117	38	observed	observe	VERB
eurjchem-1680	117	39	[	[	X
eurjchem-1680	117	40	30,31	30,31	NUM
eurjchem-1680	117	41	]	]	PUNCT
eurjchem-1680	117	42	for	for	ADP
eurjchem-1680	117	43	the	the	DET
eurjchem-1680	117	44	unimolecular	unimolecular	ADJ
eurjchem-1680	117	45	solvolyses	solvolyse	NOUN
eurjchem-1680	117	46	of	of	ADP
eurjchem-1680	117	47	the	the	DET
eurjchem-1680	117	48	tertiary	tertiary	ADJ
eurjchem-1680	117	49	1	1	NUM
eurjchem-1680	117	50	-	-	PUNCT
eurjchem-1680	117	51	adamantyl	adamantyl	ADJ
eurjchem-1680	117	52	derivatives	derivative	NOUN
eurjchem-1680	117	53	at	at	ADP
eurjchem-1680	117	54	25	25	NUM
eurjchem-1680	117	55	°	°	NOUN
eurjchem-1680	117	56	c	c	NOUN
eurjchem-1680	117	57	.	.	PUNCT
eurjchem-1680	118	1	such	such	ADJ
eurjchem-1680	118	2	values	value	NOUN
eurjchem-1680	118	3	could	could	AUX
eurjchem-1680	118	4	lead	lead	VERB
eurjchem-1680	118	5	to	to	ADP
eurjchem-1680	118	6	the	the	DET
eurjchem-1680	118	7	unimolecular	unimolecular	ADJ
eurjchem-1680	118	8	pathway	pathway	NOUN
eurjchem-1680	118	9	operating	operate	VERB
eurjchem-1680	118	10	for	for	ADP
eurjchem-1680	118	11	the	the	DET
eurjchem-1680	118	12	mesylate	mesylate	NOUN
eurjchem-1680	118	13	4	4	NUM
eurjchem-1680	118	14	to	to	PART
eurjchem-1680	118	15	become	become	VERB
eurjchem-1680	118	16	so	so	ADV
eurjchem-1680	118	17	much	much	ADV
eurjchem-1680	118	18	slower	slow	ADJ
eurjchem-1680	118	19	for	for	ADP
eurjchem-1680	118	20	the	the	DET
eurjchem-1680	118	21	corresponding	corresponding	ADJ
eurjchem-1680	118	22	bromide	bromide	NOUN
eurjchem-1680	118	23	2	2	NUM
eurjchem-1680	118	24	that	that	SCONJ
eurjchem-1680	118	25	an	an	DET
eurjchem-1680	118	26	alternative	alternative	ADJ
eurjchem-1680	118	27	mechanism	mechanism	NOUN
eurjchem-1680	118	28	involving	involve	VERB
eurjchem-1680	118	29	nucleophilic	nucleophilic	ADJ
eurjchem-1680	118	30	assistance	assistance	NOUN
eurjchem-1680	118	31	from	from	ADP
eurjchem-1680	118	32	the	the	DET
eurjchem-1680	118	33	solvent	solvent	NOUN
eurjchem-1680	118	34	becomes	become	VERB
eurjchem-1680	118	35	the	the	DET
eurjchem-1680	118	36	favored	favor	VERB
eurjchem-1680	118	37	pathway	pathway	NOUN
eurjchem-1680	118	38	.	.	PUNCT
eurjchem-1680	119	1	a	a	DET
eurjchem-1680	119	2	comparison	comparison	NOUN
eurjchem-1680	119	3	of	of	ADP
eurjchem-1680	119	4	the	the	DET
eurjchem-1680	119	5	specific	specific	ADJ
eurjchem-1680	119	6	rates	rate	NOUN
eurjchem-1680	119	7	under	under	ADP
eurjchem-1680	119	8	identical	identical	ADJ
eurjchem-1680	119	9	conditions	condition	NOUN
eurjchem-1680	119	10	for	for	ADP
eurjchem-1680	119	11	compounds	compound	NOUN
eurjchem-1680	119	12	2	2	NUM
eurjchem-1680	119	13	and	and	CCONJ
eurjchem-1680	119	14	4	4	NUM
eurjchem-1680	119	15	would	would	AUX
eurjchem-1680	119	16	allow	allow	VERB
eurjchem-1680	119	17	the	the	DET
eurjchem-1680	119	18	determination	determination	NOUN
eurjchem-1680	119	19	of	of	ADP
eurjchem-1680	119	20	the	the	DET
eurjchem-1680	119	21	koms	koms	PROPN
eurjchem-1680	119	22	/	/	SYM
eurjchem-1680	119	23	kbr	kbr	PROPN
eurjchem-1680	119	24	ratio	ratio	NOUN
eurjchem-1680	119	25	[	[	X
eurjchem-1680	119	26	24	24	NUM
eurjchem-1680	119	27	]	]	PUNCT
eurjchem-1680	119	28	.	.	PUNCT
eurjchem-1680	120	1	values	value	NOUN
eurjchem-1680	120	2	close	close	ADJ
eurjchem-1680	120	3	to	to	ADP
eurjchem-1680	120	4	unity	unity	NOUN
eurjchem-1680	120	5	would	would	AUX
eurjchem-1680	120	6	indicate	indicate	VERB
eurjchem-1680	120	7	considerable	considerable	ADJ
eurjchem-1680	120	8	sn2	sn2	PROPN
eurjchem-1680	120	9	character	character	NOUN
eurjchem-1680	120	10	and	and	CCONJ
eurjchem-1680	120	11	values	value	NOUN
eurjchem-1680	120	12	considerably	considerably	ADV
eurjchem-1680	120	13	larger	large	ADJ
eurjchem-1680	120	14	than	than	ADP
eurjchem-1680	120	15	unity	unity	NOUN
eurjchem-1680	120	16	would	would	AUX
eurjchem-1680	120	17	suggest	suggest	VERB
eurjchem-1680	120	18	considerable	considerable	ADJ
eurjchem-1680	120	19	sn1	sn1	PROPN
eurjchem-1680	120	20	character	character	NOUN
eurjchem-1680	120	21	.	.	PUNCT
eurjchem-1680	121	1	using	use	VERB
eurjchem-1680	121	2	the	the	DET
eurjchem-1680	121	3	arrhenius	arrhenius	NOUN
eurjchem-1680	121	4	equation	equation	NOUN
eurjchem-1680	121	5	,	,	PUNCT
eurjchem-1680	121	6	one	one	PRON
eurjchem-1680	121	7	can	can	AUX
eurjchem-1680	121	8	calculate	calculate	VERB
eurjchem-1680	121	9	from	from	ADP
eurjchem-1680	121	10	the	the	DET
eurjchem-1680	121	11	creary	creary	ADJ
eurjchem-1680	121	12	data	datum	NOUN
eurjchem-1680	121	13	[	[	X
eurjchem-1680	121	14	10	10	NUM
eurjchem-1680	121	15	]	]	X
eurjchem-1680	121	16	a	a	DET
eurjchem-1680	121	17	specific	specific	ADJ
eurjchem-1680	121	18	rate	rate	NOUN
eurjchem-1680	121	19	for	for	ADP
eurjchem-1680	121	20	the	the	DET
eurjchem-1680	121	21	mesylate	mesylate	NOUN
eurjchem-1680	121	22	in	in	ADP
eurjchem-1680	121	23	100	100	NUM
eurjchem-1680	121	24	%	%	NOUN
eurjchem-1680	121	25	hfip	hfip	NOUN
eurjchem-1680	121	26	at	at	ADP
eurjchem-1680	121	27	62.5	62.5	NUM
eurjchem-1680	121	28	°	°	NOUN
eurjchem-1680	121	29	c	c	NOUN
eurjchem-1680	121	30	of	of	ADP
eurjchem-1680	121	31	1.87×10	1.87×10	NUM
eurjchem-1680	121	32	-	-	SYM
eurjchem-1680	121	33	4	4	NUM
eurjchem-1680	121	34	s-1	s-1	NOUN
eurjchem-1680	121	35	and	and	CCONJ
eurjchem-1680	121	36	using	use	VERB
eurjchem-1680	121	37	the	the	DET
eurjchem-1680	121	38	extended	extended	ADJ
eurjchem-1680	121	39	grunwald	grunwald	NOUN
eurjchem-1680	121	40	-	-	PUNCT
eurjchem-1680	121	41	winstein	winstein	NOUN
eurjchem-1680	121	42	equation	equation	NOUN
eurjchem-1680	121	43	,	,	PUNCT
eurjchem-1680	121	44	with	with	ADP
eurjchem-1680	121	45	extrapolated	extrapolated	ADJ
eurjchem-1680	121	46	values	value	NOUN
eurjchem-1680	121	47	for	for	ADP
eurjchem-1680	121	48	100	100	NUM
eurjchem-1680	121	49	%	%	NOUN
eurjchem-1680	121	50	hfip	hfip	NOUN
eurjchem-1680	121	51	as	as	ADP
eurjchem-1680	121	52	solvent	solvent	NOUN
eurjchem-1680	121	53	of	of	ADP
eurjchem-1680	121	54	-6.08	-6.08	NUM
eurjchem-1680	121	55	for	for	ADP
eurjchem-1680	121	56	nt	not	PART
eurjchem-1680	121	57	and	and	CCONJ
eurjchem-1680	121	58	5.20	5.20	NUM
eurjchem-1680	121	59	for	for	ADP
eurjchem-1680	121	60	ybr	ybr	PROPN
eurjchem-1680	121	61	,	,	PUNCT
eurjchem-1680	121	62	one	one	PRON
eurjchem-1680	121	63	can	can	AUX
eurjchem-1680	121	64	calculate	calculate	VERB
eurjchem-1680	121	65	for	for	ADP
eurjchem-1680	121	66	the	the	DET
eurjchem-1680	121	67	bromide	bromide	NOUN
eurjchem-1680	121	68	in	in	ADP
eurjchem-1680	121	69	100	100	NUM
eurjchem-1680	121	70	%	%	NOUN
eurjchem-1680	121	71	hfip	hfip	NOUN
eurjchem-1680	121	72	at	at	ADP
eurjchem-1680	121	73	62.5	62.5	NUM
eurjchem-1680	121	74	°	°	ADP
eurjchem-1680	121	75	c	c	NOUN
eurjchem-1680	121	76	a	a	DET
eurjchem-1680	121	77	specific	specific	ADJ
eurjchem-1680	121	78	rate	rate	NOUN
eurjchem-1680	121	79	of	of	ADP
eurjchem-1680	121	80	7.32×10	7.32×10	NOUN
eurjchem-1680	121	81	-	-	SYM
eurjchem-1680	121	82	8	8	NUM
eurjchem-1680	121	83	s1	s1	NOUN
eurjchem-1680	121	84	.	.	PUNCT
eurjchem-1680	122	1	the	the	DET
eurjchem-1680	122	2	koms	koms	PROPN
eurjchem-1680	122	3	/	/	SYM
eurjchem-1680	122	4	kbr	kbr	PROPN
eurjchem-1680	122	5	ratio	ratio	NOUN
eurjchem-1680	122	6	of	of	ADP
eurjchem-1680	122	7	2.55×103	2.55×103	NUM
eurjchem-1680	122	8	is	be	AUX
eurjchem-1680	122	9	consistent	consistent	ADJ
eurjchem-1680	122	10	with	with	ADP
eurjchem-1680	122	11	appreciable	appreciable	ADJ
eurjchem-1680	122	12	unimolecular	unimolecular	ADJ
eurjchem-1680	122	13	character	character	NOUN
eurjchem-1680	122	14	at	at	ADP
eurjchem-1680	122	15	the	the	DET
eurjchem-1680	122	16	transition	transition	NOUN
eurjchem-1680	122	17	state	state	NOUN
eurjchem-1680	122	18	for	for	ADP
eurjchem-1680	122	19	the	the	DET
eurjchem-1680	122	20	solvolysis	solvolysis	NOUN
eurjchem-1680	122	21	of	of	ADP
eurjchem-1680	122	22	the	the	DET
eurjchem-1680	122	23	mesylate	mesylate	NOUN
eurjchem-1680	122	24	.	.	PUNCT
eurjchem-1680	123	1	another	another	DET
eurjchem-1680	123	2	interesting	interesting	ADJ
eurjchem-1680	123	3	comparison	comparison	NOUN
eurjchem-1680	123	4	is	be	AUX
eurjchem-1680	123	5	of	of	ADP
eurjchem-1680	123	6	compound	compound	NOUN
eurjchem-1680	123	7	6	6	NUM
eurjchem-1680	123	8	with	with	ADP
eurjchem-1680	123	9	the	the	DET
eurjchem-1680	123	10	corresponding	correspond	VERB
eurjchem-1680	123	11	compound	compound	NOUN
eurjchem-1680	123	12	with	with	ADP
eurjchem-1680	123	13	the	the	DET
eurjchem-1680	123	14	benzoyl	benzoyl	NOUN
eurjchem-1680	123	15	group	group	NOUN
eurjchem-1680	123	16	replaced	replace	VERB
eurjchem-1680	123	17	by	by	ADP
eurjchem-1680	123	18	a	a	DET
eurjchem-1680	123	19	methyl	methyl	NOUN
eurjchem-1680	123	20	group	group	NOUN
eurjchem-1680	123	21	,	,	PUNCT
eurjchem-1680	123	22	which	which	PRON
eurjchem-1680	123	23	has	have	AUX
eurjchem-1680	123	24	been	be	AUX
eurjchem-1680	123	25	previously	previously	ADV
eurjchem-1680	123	26	studied	study	VERB
eurjchem-1680	123	27	[	[	PUNCT
eurjchem-1680	123	28	18	18	NUM
eurjchem-1680	123	29	]	]	PUNCT
eurjchem-1680	123	30	in	in	ADP
eurjchem-1680	123	31	several	several	ADJ
eurjchem-1680	123	32	solvolyses	solvolyse	NOUN
eurjchem-1680	123	33	,	,	PUNCT
eurjchem-1680	123	34	including	include	VERB
eurjchem-1680	123	35	one	one	NUM
eurjchem-1680	123	36	in	in	ADP
eurjchem-1680	123	37	97	97	NUM
eurjchem-1680	123	38	%	%	NOUN
eurjchem-1680	123	39	tfe	tfe	NOUN
eurjchem-1680	123	40	at	at	ADP
eurjchem-1680	123	41	25.2	25.2	NUM
eurjchem-1680	123	42	°	°	NOUN
eurjchem-1680	123	43	c	c	NOUN
eurjchem-1680	123	44	where	where	SCONJ
eurjchem-1680	123	45	a	a	DET
eurjchem-1680	123	46	specific	specific	ADJ
eurjchem-1680	123	47	rate	rate	NOUN
eurjchem-1680	123	48	of	of	ADP
eurjchem-1680	123	49	solvolysis	solvolysis	NOUN
eurjchem-1680	123	50	of	of	ADP
eurjchem-1680	123	51	2.31×10	2.31×10	NUM
eurjchem-1680	123	52	-	-	SYM
eurjchem-1680	123	53	2	2	NUM
eurjchem-1680	123	54	s-1	s-1	NOUN
eurjchem-1680	123	55	was	be	AUX
eurjchem-1680	123	56	obtained	obtain	VERB
eurjchem-1680	123	57	.	.	PUNCT
eurjchem-1680	124	1	this	this	DET
eurjchem-1680	124	2	2018	2018	NUM
eurjchem-1680	124	3	–	–	PUNCT
eurjchem-1680	124	4	european	european	ADJ
eurjchem-1680	124	5	journal	journal	NOUN
eurjchem-1680	124	6	of	of	ADP
eurjchem-1680	124	7	chemistry	chemistry	NOUN
eurjchem-1680	124	8	–	–	PUNCT
eurjchem-1680	124	9	cc	cc	NOUN
eurjchem-1680	124	10	by	by	ADP
eurjchem-1680	124	11	nc	nc	PROPN
eurjchem-1680	124	12	–	–	PUNCT
eurjchem-1680	124	13	doi	doi	NOUN
eurjchem-1680	124	14	:	:	PUNCT
eurjchem-1680	124	15	10.5155	10.5155	NUM
eurjchem-1680	124	16	/	/	SYM
eurjchem-1680	124	17	eurjchem.9.1.1	eurjchem.9.1.1	NOUN
eurjchem-1680	124	18	-	-	PUNCT
eurjchem-1680	124	19	6.1680	6.1680	NUM
eurjchem-1680	124	20	kevill	kevill	NOUN
eurjchem-1680	124	21	et	et	PROPN
eurjchem-1680	124	22	al	al	PROPN
eurjchem-1680	124	23	.	.	PUNCT
eurjchem-1680	124	24	/	/	SYM
eurjchem-1680	124	25	european	european	PROPN
eurjchem-1680	124	26	journal	journal	PROPN
eurjchem-1680	124	27	of	of	ADP
eurjchem-1680	124	28	chemistry	chemistry	NOUN
eurjchem-1680	124	29	9	9	NUM
eurjchem-1680	124	30	(	(	PUNCT
eurjchem-1680	124	31	1	1	NUM
eurjchem-1680	124	32	)	)	PUNCT
eurjchem-1680	124	33	(	(	PUNCT
eurjchem-1680	124	34	2018	2018	NUM
eurjchem-1680	124	35	)	)	PUNCT
eurjchem-1680	124	36	1	1	NUM
eurjchem-1680	124	37	-	-	SYM
eurjchem-1680	124	38	6	6	NUM
eurjchem-1680	124	39	5	5	NUM
eurjchem-1680	124	40	can	can	AUX
eurjchem-1680	124	41	be	be	AUX
eurjchem-1680	124	42	compared	compare	VERB
eurjchem-1680	124	43	with	with	ADP
eurjchem-1680	124	44	the	the	DET
eurjchem-1680	124	45	value	value	NOUN
eurjchem-1680	124	46	determined	determine	VERB
eurjchem-1680	124	47	[	[	X
eurjchem-1680	124	48	10	10	NUM
eurjchem-1680	124	49	]	]	PUNCT
eurjchem-1680	124	50	for	for	ADP
eurjchem-1680	124	51	6	6	NUM
eurjchem-1680	124	52	in	in	ADP
eurjchem-1680	124	53	100	100	NUM
eurjchem-1680	124	54	%	%	NOUN
eurjchem-1680	124	55	tfe	tfe	NOUN
eurjchem-1680	124	56	at	at	ADP
eurjchem-1680	124	57	25.0	25.0	NUM
eurjchem-1680	124	58	°	°	NOUN
eurjchem-1680	124	59	c	c	NOUN
eurjchem-1680	124	60	of	of	ADP
eurjchem-1680	124	61	4.33×10	4.33×10	NUM
eurjchem-1680	124	62	-	-	SYM
eurjchem-1680	124	63	4	4	NUM
eurjchem-1680	124	64	s-1	s-1	NOUN
eurjchem-1680	124	65	.	.	PUNCT
eurjchem-1680	125	1	the	the	DET
eurjchem-1680	125	2	temperatures	temperature	NOUN
eurjchem-1680	125	3	show	show	VERB
eurjchem-1680	125	4	only	only	ADV
eurjchem-1680	125	5	a	a	DET
eurjchem-1680	125	6	small	small	ADJ
eurjchem-1680	125	7	difference	difference	NOUN
eurjchem-1680	125	8	and	and	CCONJ
eurjchem-1680	125	9	the	the	DET
eurjchem-1680	125	10	yots	yot	NOUN
eurjchem-1680	125	11	values	value	NOUN
eurjchem-1680	125	12	of	of	ADP
eurjchem-1680	125	13	1.77	1.77	NUM
eurjchem-1680	125	14	for	for	ADP
eurjchem-1680	125	15	100	100	NUM
eurjchem-1680	125	16	%	%	NOUN
eurjchem-1680	125	17	tfe	tfe	NOUN
eurjchem-1680	125	18	and	and	CCONJ
eurjchem-1680	125	19	1.83	1.83	NUM
eurjchem-1680	125	20	for	for	ADP
eurjchem-1680	125	21	97	97	NUM
eurjchem-1680	125	22	%	%	NOUN
eurjchem-1680	125	23	tfe	tfe	NOUN
eurjchem-1680	125	24	[	[	X
eurjchem-1680	125	25	5	5	NUM
eurjchem-1680	125	26	]	]	PUNCT
eurjchem-1680	125	27	are	be	AUX
eurjchem-1680	125	28	also	also	ADV
eurjchem-1680	125	29	very	very	ADV
eurjchem-1680	125	30	similar	similar	ADJ
eurjchem-1680	125	31	.	.	PUNCT
eurjchem-1680	126	1	the	the	DET
eurjchem-1680	126	2	kch3	kch3	PROPN
eurjchem-1680	126	3	/	/	SYM
eurjchem-1680	126	4	kcoph	kcoph	PROPN
eurjchem-1680	126	5	ratio	ratio	NOUN
eurjchem-1680	126	6	of	of	ADP
eurjchem-1680	126	7	53	53	NUM
eurjchem-1680	126	8	is	be	AUX
eurjchem-1680	126	9	quite	quite	ADV
eurjchem-1680	126	10	low	low	ADJ
eurjchem-1680	126	11	considering	consider	VERB
eurjchem-1680	126	12	the	the	DET
eurjchem-1680	126	13	expected	expect	VERB
eurjchem-1680	126	14	strong	strong	ADJ
eurjchem-1680	126	15	electron	electron	NOUN
eurjchem-1680	126	16	-	-	PUNCT
eurjchem-1680	126	17	withdrawing	withdraw	VERB
eurjchem-1680	126	18	influence	influence	NOUN
eurjchem-1680	126	19	of	of	ADP
eurjchem-1680	126	20	a	a	DET
eurjchem-1680	126	21	benzoyl	benzoyl	NOUN
eurjchem-1680	126	22	group	group	NOUN
eurjchem-1680	126	23	.	.	PUNCT
eurjchem-1680	127	1	it	it	PRON
eurjchem-1680	127	2	is	be	AUX
eurjchem-1680	127	3	possible	possible	ADJ
eurjchem-1680	127	4	that	that	SCONJ
eurjchem-1680	127	5	the	the	DET
eurjchem-1680	127	6	larger	large	ADJ
eurjchem-1680	127	7	benzoyl	benzoyl	NOUN
eurjchem-1680	127	8	group	group	NOUN
eurjchem-1680	127	9	could	could	AUX
eurjchem-1680	127	10	lead	lead	VERB
eurjchem-1680	127	11	to	to	ADP
eurjchem-1680	127	12	an	an	DET
eurjchem-1680	127	13	appreciable	appreciable	ADJ
eurjchem-1680	127	14	steric	steric	ADJ
eurjchem-1680	127	15	acceleration	acceleration	NOUN
eurjchem-1680	127	16	of	of	ADP
eurjchem-1680	127	17	the	the	DET
eurjchem-1680	127	18	ionization	ionization	NOUN
eurjchem-1680	127	19	process	process	NOUN
eurjchem-1680	127	20	,	,	PUNCT
eurjchem-1680	127	21	counteracting	counteract	VERB
eurjchem-1680	127	22	to	to	ADP
eurjchem-1680	127	23	a	a	DET
eurjchem-1680	127	24	large	large	ADJ
eurjchem-1680	127	25	degree	degree	NOUN
eurjchem-1680	127	26	the	the	DET
eurjchem-1680	127	27	electronic	electronic	ADJ
eurjchem-1680	127	28	influences	influence	NOUN
eurjchem-1680	127	29	[	[	X
eurjchem-1680	127	30	29	29	NUM
eurjchem-1680	127	31	]	]	PUNCT
eurjchem-1680	127	32	.	.	PUNCT
eurjchem-1680	128	1	in	in	ADP
eurjchem-1680	128	2	reactions	reaction	NOUN
eurjchem-1680	128	3	requiring	require	VERB
eurjchem-1680	128	4	the	the	DET
eurjchem-1680	128	5	removal	removal	NOUN
eurjchem-1680	128	6	of	of	ADP
eurjchem-1680	128	7	a	a	DET
eurjchem-1680	128	8	chlorine	chlorine	NOUN
eurjchem-1680	128	9	,	,	PUNCT
eurjchem-1680	128	10	bromine	bromine	NOUN
eurjchem-1680	128	11	,	,	PUNCT
eurjchem-1680	128	12	or	or	CCONJ
eurjchem-1680	128	13	iodine	iodine	NOUN
eurjchem-1680	128	14	attached	attach	VERB
eurjchem-1680	128	15	to	to	ADP
eurjchem-1680	128	16	the	the	DET
eurjchem-1680	128	17	carbon	carbon	NOUN
eurjchem-1680	128	18	adjacent	adjacent	ADJ
eurjchem-1680	128	19	to	to	ADP
eurjchem-1680	128	20	a	a	DET
eurjchem-1680	128	21	carbonyl	carbonyl	NOUN
eurjchem-1680	128	22	carbon	carbon	NOUN
eurjchem-1680	128	23	,	,	PUNCT
eurjchem-1680	128	24	silver	silver	NOUN
eurjchem-1680	128	25	-	-	PUNCT
eurjchem-1680	128	26	ion	ion	NOUN
eurjchem-1680	128	27	is	be	AUX
eurjchem-1680	128	28	frequently	frequently	ADV
eurjchem-1680	128	29	added	add	VERB
eurjchem-1680	128	30	to	to	PART
eurjchem-1680	128	31	promote	promote	VERB
eurjchem-1680	128	32	the	the	DET
eurjchem-1680	128	33	removal	removal	NOUN
eurjchem-1680	128	34	of	of	ADP
eurjchem-1680	128	35	the	the	DET
eurjchem-1680	128	36	halide	halide	NOUN
eurjchem-1680	128	37	ion	ion	NOUN
eurjchem-1680	128	38	[	[	X
eurjchem-1680	128	39	13,15,32,33	13,15,32,33	NUM
eurjchem-1680	128	40	]	]	PUNCT
eurjchem-1680	128	41	.	.	PUNCT
eurjchem-1680	129	1	in	in	ADP
eurjchem-1680	129	2	an	an	DET
eurjchem-1680	129	3	earlier	early	ADJ
eurjchem-1680	129	4	kinetic	kinetic	ADJ
eurjchem-1680	129	5	study	study	NOUN
eurjchem-1680	129	6	of	of	ADP
eurjchem-1680	129	7	the	the	DET
eurjchem-1680	129	8	solvolysis	solvolysis	NOUN
eurjchem-1680	129	9	of	of	ADP
eurjchem-1680	129	10	2	2	NUM
eurjchem-1680	129	11	in	in	ADP
eurjchem-1680	129	12	75	75	NUM
eurjchem-1680	129	13	%	%	NOUN
eurjchem-1680	129	14	aqueous	aqueous	ADJ
eurjchem-1680	129	15	ethanol	ethanol	NOUN
eurjchem-1680	129	16	(	(	PUNCT
eurjchem-1680	129	17	by	by	ADP
eurjchem-1680	129	18	weight	weight	NOUN
eurjchem-1680	129	19	)	)	PUNCT
eurjchem-1680	129	20	,	,	PUNCT
eurjchem-1680	129	21	pasto	pasto	NOUN
eurjchem-1680	129	22	and	and	CCONJ
eurjchem-1680	129	23	sevenair	sevenair	VERB
eurjchem-1680	129	24	[	[	X
eurjchem-1680	129	25	15	15	NUM
eurjchem-1680	129	26	]	]	PUNCT
eurjchem-1680	129	27	found	find	VERB
eurjchem-1680	129	28	that	that	SCONJ
eurjchem-1680	129	29	a	a	DET
eurjchem-1680	129	30	very	very	ADV
eurjchem-1680	129	31	slow	slow	ADJ
eurjchem-1680	129	32	reaction	reaction	NOUN
eurjchem-1680	129	33	at	at	ADP
eurjchem-1680	129	34	25.0	25.0	NUM
eurjchem-1680	129	35	°	°	NOUN
eurjchem-1680	129	36	c	c	NOUN
eurjchem-1680	129	37	could	could	AUX
eurjchem-1680	129	38	be	be	AUX
eurjchem-1680	129	39	appreciably	appreciably	ADV
eurjchem-1680	129	40	accelerated	accelerate	VERB
eurjchem-1680	129	41	by	by	ADP
eurjchem-1680	129	42	the	the	DET
eurjchem-1680	129	43	addition	addition	NOUN
eurjchem-1680	129	44	of	of	ADP
eurjchem-1680	129	45	silver	silver	ADJ
eurjchem-1680	129	46	perchlorate	perchlorate	NOUN
eurjchem-1680	129	47	and	and	CCONJ
eurjchem-1680	129	48	the	the	DET
eurjchem-1680	129	49	reaction	reaction	NOUN
eurjchem-1680	129	50	could	could	AUX
eurjchem-1680	129	51	then	then	ADV
eurjchem-1680	129	52	be	be	AUX
eurjchem-1680	129	53	further	far	ADV
eurjchem-1680	129	54	accelerated	accelerate	VERB
eurjchem-1680	129	55	by	by	ADP
eurjchem-1680	129	56	the	the	DET
eurjchem-1680	129	57	addition	addition	NOUN
eurjchem-1680	129	58	of	of	ADP
eurjchem-1680	129	59	perchloric	perchloric	ADJ
eurjchem-1680	129	60	acid	acid	NOUN
eurjchem-1680	129	61	.	.	PUNCT
eurjchem-1680	130	1	the	the	DET
eurjchem-1680	130	2	rate	rate	NOUN
eurjchem-1680	130	3	could	could	AUX
eurjchem-1680	130	4	formally	formally	ADV
eurjchem-1680	130	5	be	be	AUX
eurjchem-1680	130	6	expressed	express	VERB
eurjchem-1680	130	7	in	in	ADP
eurjchem-1680	130	8	terms	term	NOUN
eurjchem-1680	130	9	of	of	ADP
eurjchem-1680	130	10	an	an	DET
eurjchem-1680	130	11	apparent	apparent	ADJ
eurjchem-1680	130	12	second	second	ADJ
eurjchem-1680	130	13	-	-	PUNCT
eurjchem-1680	130	14	order	order	NOUN
eurjchem-1680	130	15	rate	rate	NOUN
eurjchem-1680	130	16	coefficient	coefficient	NOUN
eurjchem-1680	130	17	(	(	PUNCT
eurjchem-1680	130	18	equation	equation	NOUN
eurjchem-1680	130	19	(	(	PUNCT
eurjchem-1680	130	20	5	5	NUM
eurjchem-1680	130	21	)	)	PUNCT
eurjchem-1680	130	22	)	)	PUNCT
eurjchem-1680	130	23	rate	rate	NOUN
eurjchem-1680	130	24	=	=	PUNCT
eurjchem-1680	130	25	kapp	kapp	NOUN
eurjchem-1680	131	1	[	[	X
eurjchem-1680	131	2	rbr][ag+	rbr][ag+	X
eurjchem-1680	131	3	]	]	X
eurjchem-1680	131	4	(	(	PUNCT
eurjchem-1680	131	5	5	5	X
eurjchem-1680	131	6	)	)	PUNCT
eurjchem-1680	131	7	it	it	PRON
eurjchem-1680	131	8	was	be	AUX
eurjchem-1680	131	9	proposed	propose	VERB
eurjchem-1680	131	10	that	that	SCONJ
eurjchem-1680	131	11	the	the	DET
eurjchem-1680	131	12	rate	rate	NOUN
eurjchem-1680	131	13	could	could	AUX
eurjchem-1680	131	14	best	well	ADV
eurjchem-1680	131	15	be	be	AUX
eurjchem-1680	131	16	described	describe	VERB
eurjchem-1680	131	17	by	by	ADP
eurjchem-1680	131	18	three	three	NUM
eurjchem-1680	131	19	contributions	contribution	NOUN
eurjchem-1680	131	20	to	to	ADP
eurjchem-1680	131	21	the	the	DET
eurjchem-1680	131	22	rate	rate	NOUN
eurjchem-1680	131	23	equation	equation	NOUN
eurjchem-1680	131	24	,	,	PUNCT
eurjchem-1680	131	25	with	with	ADP
eurjchem-1680	131	26	one	one	NUM
eurjchem-1680	131	27	first	first	ADJ
eurjchem-1680	131	28	-	-	PUNCT
eurjchem-1680	131	29	order	order	NOUN
eurjchem-1680	131	30	in	in	ADP
eurjchem-1680	131	31	both	both	DET
eurjchem-1680	131	32	[	[	X
eurjchem-1680	131	33	ag+	ag+	X
eurjchem-1680	131	34	]	]	PUNCT
eurjchem-1680	131	35	and	and	CCONJ
eurjchem-1680	131	36	[	[	X
eurjchem-1680	131	37	rbr	rbr	NOUN
eurjchem-1680	131	38	]	]	PUNCT
eurjchem-1680	131	39	and	and	CCONJ
eurjchem-1680	131	40	with	with	ADP
eurjchem-1680	131	41	the	the	DET
eurjchem-1680	131	42	other	other	ADJ
eurjchem-1680	131	43	two	two	NUM
eurjchem-1680	131	44	terms	term	NOUN
eurjchem-1680	131	45	also	also	ADV
eurjchem-1680	131	46	having	have	VERB
eurjchem-1680	131	47	a	a	DET
eurjchem-1680	131	48	contribution	contribution	NOUN
eurjchem-1680	131	49	from	from	ADP
eurjchem-1680	131	50	[	[	X
eurjchem-1680	131	51	h+	h+	X
eurjchem-1680	131	52	]	]	X
eurjchem-1680	131	53	or	or	CCONJ
eurjchem-1680	131	54	from	from	ADP
eurjchem-1680	131	55	a	a	DET
eurjchem-1680	131	56	second	second	ADJ
eurjchem-1680	131	57	[	[	X
eurjchem-1680	131	58	ag+	ag+	X
eurjchem-1680	131	59	]	]	X
eurjchem-1680	131	60	,	,	PUNCT
eurjchem-1680	131	61	as	as	ADP
eurjchem-1680	131	62	in	in	ADP
eurjchem-1680	131	63	equation	equation	NOUN
eurjchem-1680	131	64	(	(	PUNCT
eurjchem-1680	131	65	6	6	NUM
eurjchem-1680	131	66	)	)	PUNCT
eurjchem-1680	131	67	.	.	PUNCT
eurjchem-1680	132	1	rate	rate	NOUN
eurjchem-1680	132	2	=	=	SYM
eurjchem-1680	132	3	kπ[ag+][rbr	kπ[ag+][rbr	X
eurjchem-1680	132	4	]	]	X
eurjchem-1680	133	1	+	+	PUNCT
eurjchem-1680	133	2	kh[ag+][rbr][h+	kh[ag+][rbr][h+	X
eurjchem-1680	133	3	]	]	X
eurjchem-1680	133	4	+	+	X
eurjchem-1680	133	5	kag[ag+]2[rbr	kag[ag+]2[rbr	PROPN
eurjchem-1680	133	6	]	]	X
eurjchem-1680	133	7	(	(	PUNCT
eurjchem-1680	133	8	6	6	X
eurjchem-1680	133	9	)	)	PUNCT
eurjchem-1680	133	10	combining	combine	VERB
eurjchem-1680	133	11	equations	equation	NOUN
eurjchem-1680	133	12	(	(	PUNCT
eurjchem-1680	133	13	5	5	NUM
eurjchem-1680	133	14	)	)	PUNCT
eurjchem-1680	133	15	and	and	CCONJ
eurjchem-1680	133	16	(	(	PUNCT
eurjchem-1680	133	17	6	6	X
eurjchem-1680	133	18	)	)	PUNCT
eurjchem-1680	133	19	we	we	PRON
eurjchem-1680	133	20	arrive	arrive	VERB
eurjchem-1680	133	21	at	at	ADP
eurjchem-1680	133	22	equation	equation	NOUN
eurjchem-1680	133	23	(	(	PUNCT
eurjchem-1680	133	24	7	7	NUM
eurjchem-1680	133	25	)	)	PUNCT
eurjchem-1680	133	26	.	.	PUNCT
eurjchem-1680	134	1	kapp	kapp	PROPN
eurjchem-1680	134	2	=	=	PUNCT
eurjchem-1680	135	1	kπ	kπ	PROPN
eurjchem-1680	135	2	+	+	CCONJ
eurjchem-1680	135	3	kh[h+	kh[h+	PROPN
eurjchem-1680	135	4	]	]	PUNCT
eurjchem-1680	136	1	+	+	CCONJ
eurjchem-1680	136	2	kag[ag+	kag[ag+	X
eurjchem-1680	136	3	]	]	X
eurjchem-1680	136	4	(	(	PUNCT
eurjchem-1680	136	5	7	7	X
eurjchem-1680	136	6	)	)	PUNCT
eurjchem-1680	136	7	using	use	VERB
eurjchem-1680	136	8	graphical	graphical	ADJ
eurjchem-1680	136	9	methods	method	NOUN
eurjchem-1680	136	10	,	,	PUNCT
eurjchem-1680	136	11	the	the	DET
eurjchem-1680	136	12	authors	author	NOUN
eurjchem-1680	136	13	were	be	AUX
eurjchem-1680	136	14	able	able	ADJ
eurjchem-1680	136	15	to	to	PART
eurjchem-1680	136	16	extract	extract	VERB
eurjchem-1680	136	17	from	from	ADP
eurjchem-1680	136	18	their	their	PRON
eurjchem-1680	136	19	rate	rate	NOUN
eurjchem-1680	136	20	data	datum	NOUN
eurjchem-1680	136	21	values	value	NOUN
eurjchem-1680	136	22	for	for	ADP
eurjchem-1680	136	23	kπ	kπ	PROPN
eurjchem-1680	136	24	of	of	ADP
eurjchem-1680	136	25	0.052	0.052	NUM
eurjchem-1680	136	26	lmol-1min-1	lmol-1min-1	ADJ
eurjchem-1680	136	27	,	,	PUNCT
eurjchem-1680	136	28	for	for	ADP
eurjchem-1680	136	29	kh	kh	PROPN
eurjchem-1680	136	30	of	of	ADP
eurjchem-1680	136	31	0.062	0.062	NUM
eurjchem-1680	136	32	l2mol-2min-1	l2mol-2min-1	NOUN
eurjchem-1680	136	33	(	(	PUNCT
eurjchem-1680	136	34	units	unit	NOUN
eurjchem-1680	136	35	erroneously	erroneously	ADV
eurjchem-1680	136	36	reported	report	VERB
eurjchem-1680	136	37	[	[	X
eurjchem-1680	136	38	15	15	NUM
eurjchem-1680	136	39	]	]	PUNCT
eurjchem-1680	136	40	as	as	ADP
eurjchem-1680	136	41	lmol1min-1	lmol1min-1	NOUN
eurjchem-1680	136	42	)	)	PUNCT
eurjchem-1680	136	43	,	,	PUNCT
eurjchem-1680	136	44	and	and	CCONJ
eurjchem-1680	136	45	two	two	NUM
eurjchem-1680	136	46	different	different	ADJ
eurjchem-1680	136	47	graphical	graphical	ADJ
eurjchem-1680	136	48	methods	method	NOUN
eurjchem-1680	136	49	gave	give	VERB
eurjchem-1680	136	50	values	value	NOUN
eurjchem-1680	136	51	of	of	ADP
eurjchem-1680	136	52	1.81	1.81	NUM
eurjchem-1680	136	53	l2mol-2min-1	l2mol-2min-1	NOUN
eurjchem-1680	136	54	or	or	CCONJ
eurjchem-1680	136	55	2.24	2.24	NUM
eurjchem-1680	136	56	l2mol-2min-1	l2mol-2min-1	NOUN
eurjchem-1680	136	57	for	for	ADP
eurjchem-1680	136	58	kag	kag	PROPN
eurjchem-1680	136	59	.	.	PROPN
eurjchem-1680	137	1	with	with	ADP
eurjchem-1680	137	2	the	the	DET
eurjchem-1680	137	3	use	use	NOUN
eurjchem-1680	137	4	of	of	ADP
eurjchem-1680	137	5	statistical	statistical	ADJ
eurjchem-1680	137	6	packages	package	NOUN
eurjchem-1680	137	7	for	for	ADP
eurjchem-1680	137	8	multiple	multiple	ADJ
eurjchem-1680	137	9	regression	regression	NOUN
eurjchem-1680	137	10	analysis	analysis	NOUN
eurjchem-1680	137	11	,	,	PUNCT
eurjchem-1680	137	12	which	which	PRON
eurjchem-1680	137	13	have	have	AUX
eurjchem-1680	137	14	since	since	SCONJ
eurjchem-1680	137	15	become	become	VERB
eurjchem-1680	137	16	readily	readily	ADV
eurjchem-1680	137	17	available	available	ADJ
eurjchem-1680	137	18	,	,	PUNCT
eurjchem-1680	137	19	we	we	PRON
eurjchem-1680	137	20	have	have	AUX
eurjchem-1680	137	21	reanalyzed	reanalyze	VERB
eurjchem-1680	137	22	in	in	ADP
eurjchem-1680	137	23	terms	term	NOUN
eurjchem-1680	137	24	of	of	ADP
eurjchem-1680	137	25	equation	equation	NOUN
eurjchem-1680	137	26	(	(	PUNCT
eurjchem-1680	137	27	7	7	X
eurjchem-1680	137	28	)	)	PUNCT
eurjchem-1680	137	29	the	the	DET
eurjchem-1680	137	30	twelve	twelve	NUM
eurjchem-1680	137	31	sets	set	NOUN
eurjchem-1680	137	32	of	of	ADP
eurjchem-1680	137	33	rate	rate	NOUN
eurjchem-1680	137	34	coefficients	coefficient	NOUN
eurjchem-1680	137	35	and	and	CCONJ
eurjchem-1680	137	36	concentrations	concentration	NOUN
eurjchem-1680	137	37	to	to	PART
eurjchem-1680	137	38	arrive	arrive	VERB
eurjchem-1680	137	39	at	at	ADP
eurjchem-1680	137	40	a	a	DET
eurjchem-1680	137	41	rigorously	rigorously	ADV
eurjchem-1680	137	42	derived	derive	VERB
eurjchem-1680	137	43	set	set	NOUN
eurjchem-1680	137	44	of	of	ADP
eurjchem-1680	137	45	values	value	NOUN
eurjchem-1680	137	46	of	of	ADP
eurjchem-1680	137	47	0.037±0.010	0.037±0.010	NOUN
eurjchem-1680	137	48	lmol-1min-1	lmol-1min-1	PROPN
eurjchem-1680	137	49	for	for	ADP
eurjchem-1680	137	50	kπ	kπ	PROPN
eurjchem-1680	137	51	,	,	PUNCT
eurjchem-1680	137	52	0.073±0.016	0.073±0.016	PROPN
eurjchem-1680	137	53	l2mol-2min-1	l2mol-2min-1	PROPN
eurjchem-1680	137	54	for	for	ADP
eurjchem-1680	137	55	kh	kh	PROPN
eurjchem-1680	137	56	,	,	PUNCT
eurjchem-1680	137	57	and	and	CCONJ
eurjchem-1680	137	58	2.26±0.22	2.26±0.22	NOUN
eurjchem-1680	137	59	l2mol-2min-1	l2mol-2min-1	NOUN
eurjchem-1680	137	60	for	for	ADP
eurjchem-1680	137	61	kag	kag	PROPN
eurjchem-1680	137	62	,	,	PUNCT
eurjchem-1680	137	63	with	with	ADP
eurjchem-1680	137	64	a	a	DET
eurjchem-1680	137	65	multiple	multiple	ADJ
eurjchem-1680	137	66	correlation	correlation	NOUN
eurjchem-1680	137	67	coefficient	coefficient	NOUN
eurjchem-1680	137	68	of	of	ADP
eurjchem-1680	137	69	0.971	0.971	NUM
eurjchem-1680	137	70	.	.	PUNCT
eurjchem-1680	138	1	the	the	DET
eurjchem-1680	138	2	values	value	NOUN
eurjchem-1680	138	3	obtained	obtain	VERB
eurjchem-1680	138	4	earlier	early	ADV
eurjchem-1680	138	5	by	by	ADP
eurjchem-1680	138	6	pasto	pasto	NOUN
eurjchem-1680	138	7	and	and	CCONJ
eurjchem-1680	138	8	sevenair	sevenair	NOUN
eurjchem-1680	138	9	are	be	AUX
eurjchem-1680	138	10	in	in	ADP
eurjchem-1680	138	11	reasonable	reasonable	ADJ
eurjchem-1680	138	12	agreement	agreement	NOUN
eurjchem-1680	138	13	with	with	ADP
eurjchem-1680	138	14	the	the	DET
eurjchem-1680	138	15	presently	presently	ADV
eurjchem-1680	138	16	reported	report	VERB
eurjchem-1680	138	17	values	value	NOUN
eurjchem-1680	138	18	and	and	CCONJ
eurjchem-1680	138	19	the	the	DET
eurjchem-1680	138	20	acceptable	acceptable	ADJ
eurjchem-1680	138	21	correlation	correlation	NOUN
eurjchem-1680	138	22	coefficient	coefficient	NOUN
eurjchem-1680	138	23	indicates	indicate	VERB
eurjchem-1680	138	24	that	that	SCONJ
eurjchem-1680	138	25	the	the	DET
eurjchem-1680	138	26	combination	combination	NOUN
eurjchem-1680	138	27	of	of	ADP
eurjchem-1680	138	28	these	these	DET
eurjchem-1680	138	29	three	three	NUM
eurjchem-1680	138	30	terms	term	NOUN
eurjchem-1680	138	31	within	within	ADP
eurjchem-1680	138	32	the	the	DET
eurjchem-1680	138	33	overall	overall	ADJ
eurjchem-1680	138	34	kinetic	kinetic	ADJ
eurjchem-1680	138	35	equation	equation	NOUN
eurjchem-1680	138	36	(	(	PUNCT
eurjchem-1680	138	37	equation	equation	NOUN
eurjchem-1680	138	38	6	6	NUM
eurjchem-1680	138	39	)	)	PUNCT
eurjchem-1680	138	40	gives	give	VERB
eurjchem-1680	138	41	a	a	DET
eurjchem-1680	138	42	reasonable	reasonable	ADJ
eurjchem-1680	138	43	reproduction	reproduction	NOUN
eurjchem-1680	138	44	of	of	ADP
eurjchem-1680	138	45	the	the	DET
eurjchem-1680	138	46	experimental	experimental	ADJ
eurjchem-1680	138	47	[	[	X
eurjchem-1680	138	48	15	15	NUM
eurjchem-1680	138	49	]	]	X
eurjchem-1680	138	50	specific	specific	ADJ
eurjchem-1680	138	51	rates	rate	NOUN
eurjchem-1680	138	52	.	.	PUNCT
eurjchem-1680	139	1	4	4	X
eurjchem-1680	139	2	.	.	X
eurjchem-1680	139	3	conclusions	conclusion	NOUN
eurjchem-1680	139	4	the	the	DET
eurjchem-1680	139	5	extended	extended	ADJ
eurjchem-1680	139	6	grunwald	grunwald	NOUN
eurjchem-1680	139	7	-	-	PUNCT
eurjchem-1680	139	8	winstein	winstein	NOUN
eurjchem-1680	139	9	equation	equation	NOUN
eurjchem-1680	139	10	[	[	X
eurjchem-1680	139	11	3	3	NUM
eurjchem-1680	139	12	-	-	SYM
eurjchem-1680	139	13	6	6	NUM
eurjchem-1680	139	14	]	]	PUNCT
eurjchem-1680	139	15	,	,	PUNCT
eurjchem-1680	139	16	which	which	PRON
eurjchem-1680	139	17	has	have	AUX
eurjchem-1680	139	18	been	be	AUX
eurjchem-1680	139	19	found	find	VERB
eurjchem-1680	139	20	to	to	PART
eurjchem-1680	139	21	be	be	AUX
eurjchem-1680	139	22	very	very	ADV
eurjchem-1680	139	23	useful	useful	ADJ
eurjchem-1680	139	24	in	in	ADP
eurjchem-1680	139	25	its	its	PRON
eurjchem-1680	139	26	application	application	NOUN
eurjchem-1680	139	27	to	to	ADP
eurjchem-1680	139	28	the	the	DET
eurjchem-1680	139	29	specific	specific	ADJ
eurjchem-1680	139	30	rates	rate	NOUN
eurjchem-1680	139	31	of	of	ADP
eurjchem-1680	139	32	solvolysis	solvolysis	NOUN
eurjchem-1680	139	33	of	of	ADP
eurjchem-1680	139	34	a	a	DET
eurjchem-1680	139	35	wide	wide	ADJ
eurjchem-1680	139	36	variety	variety	NOUN
eurjchem-1680	139	37	of	of	ADP
eurjchem-1680	139	38	substrates	substrate	NOUN
eurjchem-1680	139	39	,	,	PUNCT
eurjchem-1680	139	40	such	such	ADJ
eurjchem-1680	139	41	as	as	ADP
eurjchem-1680	139	42	phosphorus	phosphorus	NOUN
eurjchem-1680	139	43	compounds	compound	NOUN
eurjchem-1680	140	1	[	[	X
eurjchem-1680	140	2	34	34	NUM
eurjchem-1680	140	3	]	]	PUNCT
eurjchem-1680	140	4	,	,	PUNCT
eurjchem-1680	140	5	silicon	silicon	NOUN
eurjchem-1680	140	6	compounds	compound	VERB
eurjchem-1680	140	7	[	[	X
eurjchem-1680	140	8	35	35	NUM
eurjchem-1680	140	9	]	]	PUNCT
eurjchem-1680	140	10	,	,	PUNCT
eurjchem-1680	140	11	acid	acid	NOUN
eurjchem-1680	140	12	chlorides	chloride	NOUN
eurjchem-1680	140	13	[	[	X
eurjchem-1680	140	14	36	36	NUM
eurjchem-1680	140	15	]	]	PUNCT
eurjchem-1680	140	16	,	,	PUNCT
eurjchem-1680	140	17	chloroformate	chloroformate	ADJ
eurjchem-1680	140	18	esters	ester	NOUN
eurjchem-1680	140	19	[	[	X
eurjchem-1680	140	20	37	37	NUM
eurjchem-1680	140	21	]	]	PUNCT
eurjchem-1680	140	22	,	,	PUNCT
eurjchem-1680	140	23	chlorothioformate	chlorothioformate	VERB
eurjchem-1680	140	24	esters	ester	NOUN
eurjchem-1680	140	25	[	[	X
eurjchem-1680	140	26	38	38	NUM
eurjchem-1680	140	27	]	]	PUNCT
eurjchem-1680	140	28	,	,	PUNCT
eurjchem-1680	140	29	and	and	CCONJ
eurjchem-1680	140	30	heterocyclic	heterocyclic	ADJ
eurjchem-1680	140	31	compounds	compound	NOUN
eurjchem-1680	140	32	[	[	X
eurjchem-1680	140	33	39	39	NUM
eurjchem-1680	140	34	]	]	PUNCT
eurjchem-1680	140	35	,	,	PUNCT
eurjchem-1680	140	36	is	be	AUX
eurjchem-1680	140	37	here	here	ADV
eurjchem-1680	140	38	applied	apply	VERB
eurjchem-1680	140	39	to	to	ADP
eurjchem-1680	140	40	the	the	DET
eurjchem-1680	140	41	solvolyses	solvolyse	NOUN
eurjchem-1680	140	42	of	of	ADP
eurjchem-1680	140	43	tertiary	tertiary	ADJ
eurjchem-1680	140	44	alpha	alpha	NOUN
eurjchem-1680	140	45	-	-	PUNCT
eurjchem-1680	140	46	substituted	substitute	VERB
eurjchem-1680	140	47	ketones	ketone	NOUN
eurjchem-1680	140	48	,	,	PUNCT
eurjchem-1680	140	49	some	some	PRON
eurjchem-1680	140	50	of	of	ADP
eurjchem-1680	140	51	which	which	PRON
eurjchem-1680	140	52	have	have	AUX
eurjchem-1680	140	53	,	,	PUNCT
eurjchem-1680	140	54	contrary	contrary	ADJ
eurjchem-1680	140	55	to	to	ADP
eurjchem-1680	140	56	earlier	early	ADJ
eurjchem-1680	140	57	opinions	opinion	NOUN
eurjchem-1680	140	58	summarized	summarize	VERB
eurjchem-1680	140	59	elsewhere	elsewhere	ADV
eurjchem-1680	140	60	[	[	X
eurjchem-1680	140	61	12	12	NUM
eurjchem-1680	140	62	]	]	PUNCT
eurjchem-1680	140	63	,	,	PUNCT
eurjchem-1680	140	64	been	be	AUX
eurjchem-1680	140	65	found	find	VERB
eurjchem-1680	140	66	to	to	PART
eurjchem-1680	140	67	be	be	AUX
eurjchem-1680	140	68	capable	capable	ADJ
eurjchem-1680	140	69	of	of	ADP
eurjchem-1680	140	70	forming	form	VERB
eurjchem-1680	140	71	carbocations	carbocation	NOUN
eurjchem-1680	140	72	with	with	ADP
eurjchem-1680	140	73	the	the	DET
eurjchem-1680	140	74	charge	charge	NOUN
eurjchem-1680	140	75	formally	formally	ADV
eurjchem-1680	140	76	adjacent	adjacent	ADJ
eurjchem-1680	140	77	to	to	ADP
eurjchem-1680	140	78	the	the	DET
eurjchem-1680	140	79	carbonyl	carbonyl	NOUN
eurjchem-1680	140	80	group	group	NOUN
eurjchem-1680	140	81	under	under	ADP
eurjchem-1680	140	82	solvolytic	solvolytic	ADJ
eurjchem-1680	140	83	conditions	condition	NOUN
eurjchem-1680	141	1	[	[	X
eurjchem-1680	141	2	10	10	NUM
eurjchem-1680	141	3	-	-	SYM
eurjchem-1680	141	4	12	12	NUM
eurjchem-1680	141	5	]	]	PUNCT
eurjchem-1680	141	6	.	.	PUNCT
eurjchem-1680	142	1	the	the	DET
eurjchem-1680	142	2	correlation	correlation	NOUN
eurjchem-1680	142	3	of	of	ADP
eurjchem-1680	142	4	the	the	DET
eurjchem-1680	142	5	specific	specific	ADJ
eurjchem-1680	142	6	rates	rate	NOUN
eurjchem-1680	142	7	of	of	ADP
eurjchem-1680	142	8	solvolysis	solvolysis	NOUN
eurjchem-1680	142	9	of	of	ADP
eurjchem-1680	142	10	the	the	DET
eurjchem-1680	142	11	tertiary	tertiary	ADJ
eurjchem-1680	142	12	α	α	NOUN
eurjchem-1680	142	13	-	-	NOUN
eurjchem-1680	142	14	bromoisobutyrophenone	bromoisobutyrophenone	NOUN
eurjchem-1680	142	15	(	(	PUNCT
eurjchem-1680	142	16	2	2	NUM
eurjchem-1680	142	17	)	)	PUNCT
eurjchem-1680	142	18	gave	give	VERB
eurjchem-1680	142	19	l	l	NOUN
eurjchem-1680	142	20	and	and	CCONJ
eurjchem-1680	142	21	m	m	NOUN
eurjchem-1680	142	22	sensitivity	sensitivity	NOUN
eurjchem-1680	142	23	values	value	NOUN
eurjchem-1680	142	24	(	(	PUNCT
eurjchem-1680	142	25	table	table	NOUN
eurjchem-1680	142	26	2	2	NUM
eurjchem-1680	142	27	)	)	PUNCT
eurjchem-1680	142	28	very	very	ADV
eurjchem-1680	142	29	different	different	ADJ
eurjchem-1680	142	30	to	to	ADP
eurjchem-1680	142	31	those	those	PRON
eurjchem-1680	142	32	previously	previously	ADV
eurjchem-1680	142	33	reported	report	VERB
eurjchem-1680	142	34	[	[	X
eurjchem-1680	142	35	1	1	X
eurjchem-1680	142	36	]	]	PUNCT
eurjchem-1680	142	37	for	for	ADP
eurjchem-1680	142	38	the	the	DET
eurjchem-1680	142	39	solvolyses	solvolyse	NOUN
eurjchem-1680	142	40	of	of	ADP
eurjchem-1680	142	41	the	the	DET
eurjchem-1680	142	42	primary	primary	ADJ
eurjchem-1680	142	43	α	α	NOUN
eurjchem-1680	142	44	-	-	NOUN
eurjchem-1680	142	45	bromoacetophone	bromoacetophone	NOUN
eurjchem-1680	142	46	(	(	PUNCT
eurjchem-1680	142	47	1	1	NUM
eurjchem-1680	142	48	)	)	PUNCT
eurjchem-1680	142	49	,	,	PUNCT
eurjchem-1680	142	50	which	which	PRON
eurjchem-1680	142	51	had	have	AUX
eurjchem-1680	142	52	given	give	VERB
eurjchem-1680	142	53	typical	typical	ADJ
eurjchem-1680	142	54	values	value	NOUN
eurjchem-1680	142	55	for	for	ADP
eurjchem-1680	142	56	solvolysis	solvolysis	NOUN
eurjchem-1680	142	57	of	of	ADP
eurjchem-1680	142	58	a	a	DET
eurjchem-1680	142	59	primary	primary	ADJ
eurjchem-1680	142	60	substrate	substrate	NOUN
eurjchem-1680	142	61	.	.	PUNCT
eurjchem-1680	143	1	the	the	DET
eurjchem-1680	143	2	values	value	NOUN
eurjchem-1680	143	3	were	be	AUX
eurjchem-1680	143	4	also	also	ADV
eurjchem-1680	143	5	very	very	ADV
eurjchem-1680	143	6	different	different	ADJ
eurjchem-1680	143	7	to	to	ADP
eurjchem-1680	143	8	those	those	PRON
eurjchem-1680	143	9	for	for	ADP
eurjchem-1680	143	10	the	the	DET
eurjchem-1680	143	11	corresponding	corresponding	ADJ
eurjchem-1680	143	12	tertiary	tertiary	ADJ
eurjchem-1680	143	13	mesylate	mesylate	NOUN
eurjchem-1680	143	14	4	4	NUM
eurjchem-1680	143	15	which	which	PRON
eurjchem-1680	143	16	gave	give	VERB
eurjchem-1680	143	17	values	value	NOUN
eurjchem-1680	143	18	indicating	indicate	VERB
eurjchem-1680	143	19	a	a	DET
eurjchem-1680	143	20	unimolecular	unimolecular	ADJ
eurjchem-1680	143	21	(	(	PUNCT
eurjchem-1680	143	22	sn1+e1	sn1+e1	PROPN
eurjchem-1680	143	23	)	)	PUNCT
eurjchem-1680	143	24	process	process	NOUN
eurjchem-1680	143	25	.	.	PUNCT
eurjchem-1680	144	1	further	far	ADV
eurjchem-1680	144	2	,	,	PUNCT
eurjchem-1680	144	3	the	the	DET
eurjchem-1680	144	4	mesylate	mesylate	NOUN
eurjchem-1680	144	5	4	4	NUM
eurjchem-1680	144	6	reacted	react	VERB
eurjchem-1680	144	7	considerably	considerably	ADV
eurjchem-1680	144	8	faster	fast	ADV
eurjchem-1680	144	9	than	than	ADP
eurjchem-1680	144	10	the	the	DET
eurjchem-1680	144	11	bromide	bromide	NOUN
eurjchem-1680	144	12	2	2	NUM
eurjchem-1680	144	13	,	,	PUNCT
eurjchem-1680	144	14	suggesting	suggest	VERB
eurjchem-1680	144	15	that	that	SCONJ
eurjchem-1680	144	16	this	this	PRON
eurjchem-1680	144	17	represents	represent	VERB
eurjchem-1680	144	18	a	a	DET
eurjchem-1680	144	19	further	further	ADJ
eurjchem-1680	144	20	example	example	NOUN
eurjchem-1680	144	21	of	of	ADP
eurjchem-1680	144	22	,	,	PUNCT
eurjchem-1680	144	23	for	for	ADP
eurjchem-1680	144	24	crowded	crowded	ADJ
eurjchem-1680	144	25	tertiary	tertiary	ADJ
eurjchem-1680	144	26	structures	structure	NOUN
eurjchem-1680	144	27	,	,	PUNCT
eurjchem-1680	144	28	the	the	DET
eurjchem-1680	144	29	relief	relief	NOUN
eurjchem-1680	144	30	of	of	ADP
eurjchem-1680	144	31	steric	steric	ADJ
eurjchem-1680	144	32	strain	strain	NOUN
eurjchem-1680	144	33	in	in	ADP
eurjchem-1680	144	34	an	an	DET
eurjchem-1680	144	35	ionization	ionization	NOUN
eurjchem-1680	144	36	process	process	NOUN
eurjchem-1680	144	37	giving	give	VERB
eurjchem-1680	144	38	enhanced	enhance	VERB
eurjchem-1680	144	39	koms	kom	NOUN
eurjchem-1680	144	40	/	/	SYM
eurjchem-1680	144	41	kbr	kbr	PROPN
eurjchem-1680	144	42	leaving	leaving	NOUN
eurjchem-1680	144	43	-	-	PUNCT
eurjchem-1680	144	44	group	group	NOUN
eurjchem-1680	144	45	effects	effect	NOUN
eurjchem-1680	144	46	[	[	X
eurjchem-1680	144	47	31,32	31,32	NUM
eurjchem-1680	144	48	]	]	X
eurjchem-1680	144	49	.	.	PUNCT
eurjchem-1680	145	1	indeed	indeed	ADV
eurjchem-1680	145	2	,	,	PUNCT
eurjchem-1680	145	3	the	the	DET
eurjchem-1680	145	4	wide	wide	ADJ
eurjchem-1680	145	5	differences	difference	NOUN
eurjchem-1680	145	6	in	in	ADP
eurjchem-1680	145	7	l	l	NOUN
eurjchem-1680	145	8	and	and	CCONJ
eurjchem-1680	145	9	m	m	PROPN
eurjchem-1680	145	10	values	value	NOUN
eurjchem-1680	145	11	suggest	suggest	VERB
eurjchem-1680	145	12	that	that	SCONJ
eurjchem-1680	145	13	for	for	ADP
eurjchem-1680	145	14	the	the	DET
eurjchem-1680	145	15	bromide	bromide	NOUN
eurjchem-1680	145	16	a	a	DET
eurjchem-1680	145	17	process	process	NOUN
eurjchem-1680	145	18	with	with	ADP
eurjchem-1680	145	19	appreciably	appreciably	ADV
eurjchem-1680	145	20	nucleophilic	nucleophilic	ADJ
eurjchem-1680	145	21	assistance	assistance	NOUN
eurjchem-1680	145	22	from	from	ADP
eurjchem-1680	145	23	the	the	DET
eurjchem-1680	145	24	solvent	solvent	NOUN
eurjchem-1680	145	25	is	be	AUX
eurjchem-1680	145	26	favored	favor	VERB
eurjchem-1680	145	27	over	over	ADP
eurjchem-1680	145	28	a	a	DET
eurjchem-1680	145	29	considerably	considerably	ADV
eurjchem-1680	145	30	slower	slow	ADJ
eurjchem-1680	145	31	unassisted	unassisted	ADJ
eurjchem-1680	145	32	ionization	ionization	NOUN
eurjchem-1680	145	33	pathway	pathway	NOUN
eurjchem-1680	145	34	.	.	PUNCT
eurjchem-1680	146	1	the	the	DET
eurjchem-1680	146	2	scheme	scheme	NOUN
eurjchem-1680	146	3	proposed	propose	VERB
eurjchem-1680	146	4	by	by	ADP
eurjchem-1680	146	5	pasto	pasto	NOUN
eurjchem-1680	146	6	and	and	CCONJ
eurjchem-1680	146	7	sevenair	sevenair	VERB
eurjchem-1680	146	8	[	[	X
eurjchem-1680	146	9	15	15	NUM
eurjchem-1680	146	10	]	]	PUNCT
eurjchem-1680	146	11	for	for	ADP
eurjchem-1680	146	12	the	the	DET
eurjchem-1680	146	13	silver	silver	NOUN
eurjchem-1680	146	14	-	-	PUNCT
eurjchem-1680	146	15	ion	ion	NOUN
eurjchem-1680	146	16	assisted	assist	VERB
eurjchem-1680	146	17	solvolysis	solvolysis	NOUN
eurjchem-1680	146	18	of	of	ADP
eurjchem-1680	146	19	2	2	NUM
eurjchem-1680	146	20	in	in	ADP
eurjchem-1680	146	21	75	75	NUM
eurjchem-1680	146	22	%	%	NOUN
eurjchem-1680	146	23	aqueous	aqueous	ADJ
eurjchem-1680	146	24	ethanol	ethanol	NOUN
eurjchem-1680	146	25	(	(	PUNCT
eurjchem-1680	146	26	by	by	ADP
eurjchem-1680	146	27	weight	weight	NOUN
eurjchem-1680	146	28	)	)	PUNCT
eurjchem-1680	146	29	involving	involve	VERB
eurjchem-1680	146	30	three	three	NUM
eurjchem-1680	146	31	terms	term	NOUN
eurjchem-1680	146	32	with	with	ADP
eurjchem-1680	146	33	just	just	ADV
eurjchem-1680	146	34	silver	silver	ADJ
eurjchem-1680	146	35	ion	ion	NOUN
eurjchem-1680	146	36	assistance	assistance	NOUN
eurjchem-1680	146	37	,	,	PUNCT
eurjchem-1680	146	38	assistance	assistance	NOUN
eurjchem-1680	146	39	from	from	ADP
eurjchem-1680	146	40	both	both	DET
eurjchem-1680	146	41	silver	silver	ADJ
eurjchem-1680	146	42	ion	ion	NOUN
eurjchem-1680	146	43	and	and	CCONJ
eurjchem-1680	146	44	a	a	DET
eurjchem-1680	146	45	proton	proton	NOUN
eurjchem-1680	146	46	,	,	PUNCT
eurjchem-1680	146	47	and	and	CCONJ
eurjchem-1680	146	48	assistance	assistance	NOUN
eurjchem-1680	146	49	by	by	ADP
eurjchem-1680	146	50	one	one	NUM
eurjchem-1680	146	51	silver	silver	NOUN
eurjchem-1680	146	52	ion	ion	NOUN
eurjchem-1680	146	53	assisted	assist	VERB
eurjchem-1680	146	54	by	by	ADP
eurjchem-1680	146	55	a	a	DET
eurjchem-1680	146	56	second	second	ADJ
eurjchem-1680	146	57	one	one	NUM
eurjchem-1680	146	58	,	,	PUNCT
eurjchem-1680	146	59	has	have	AUX
eurjchem-1680	146	60	been	be	AUX
eurjchem-1680	146	61	shown	show	VERB
eurjchem-1680	146	62	to	to	PART
eurjchem-1680	146	63	be	be	AUX
eurjchem-1680	146	64	a	a	DET
eurjchem-1680	146	65	reasonable	reasonable	ADJ
eurjchem-1680	146	66	one	one	NUM
eurjchem-1680	146	67	by	by	ADP
eurjchem-1680	146	68	the	the	DET
eurjchem-1680	146	69	application	application	NOUN
eurjchem-1680	146	70	of	of	ADP
eurjchem-1680	146	71	multiple	multiple	ADJ
eurjchem-1680	146	72	regression	regression	NOUN
eurjchem-1680	146	73	analysis	analysis	NOUN
eurjchem-1680	146	74	.	.	PUNCT
eurjchem-1680	147	1	acknowledgements	acknowledgement	NOUN
eurjchem-1680	147	2	support	support	NOUN
eurjchem-1680	147	3	is	be	AUX
eurjchem-1680	147	4	acknowledged	acknowledge	VERB
eurjchem-1680	147	5	from	from	ADP
eurjchem-1680	147	6	the	the	DET
eurjchem-1680	147	7	donors	donor	NOUN
eurjchem-1680	147	8	of	of	ADP
eurjchem-1680	147	9	the	the	DET
eurjchem-1680	147	10	american	american	PROPN
eurjchem-1680	147	11	chemical	chemical	PROPN
eurjchem-1680	147	12	society	society	PROPN
eurjchem-1680	147	13	petroleum	petroleum	PROPN
eurjchem-1680	147	14	research	research	NOUN
eurjchem-1680	147	15	fund	fund	NOUN
eurjchem-1680	147	16	(	(	PUNCT
eurjchem-1680	147	17	prf	prf	PROPN
eurjchem-1680	147	18	#	#	NOUN
eurjchem-1680	147	19	38163ac4	38163ac4	PROPN
eurjchem-1680	147	20	)	)	PUNCT
eurjchem-1680	147	21	;	;	PUNCT
eurjchem-1680	147	22	the	the	DET
eurjchem-1680	147	23	state	state	NOUN
eurjchem-1680	147	24	of	of	ADP
eurjchem-1680	147	25	delaware	delaware	PROPN
eurjchem-1680	147	26	;	;	PUNCT
eurjchem-1680	147	27	the	the	DET
eurjchem-1680	147	28	national	national	PROPN
eurjchem-1680	147	29	institute	institute	PROPN
eurjchem-1680	147	30	of	of	ADP
eurjchem-1680	147	31	general	general	PROPN
eurjchem-1680	147	32	medical	medical	PROPN
eurjchem-1680	147	33	sciences	sciences	PROPN
eurjchem-1680	147	34	(	(	PUNCT
eurjchem-1680	147	35	p20gm103446	p20gm103446	PROPN
eurjchem-1680	147	36	)	)	PUNCT
eurjchem-1680	147	37	from	from	ADP
eurjchem-1680	147	38	the	the	DET
eurjchem-1680	147	39	national	national	PROPN
eurjchem-1680	147	40	institutes	institutes	PROPN
eurjchem-1680	147	41	of	of	ADP
eurjchem-1680	147	42	health	health	PROPN
eurjchem-1680	147	43	(	(	PUNCT
eurjchem-1680	147	44	inbre	inbre	PROPN
eurjchem-1680	147	45	program	program	PROPN
eurjchem-1680	147	46	)	)	PUNCT
eurjchem-1680	147	47	;	;	PUNCT
eurjchem-1680	147	48	and	and	CCONJ
eurjchem-1680	147	49	a	a	DET
eurjchem-1680	147	50	national	national	PROPN
eurjchem-1680	147	51	science	science	PROPN
eurjchem-1680	147	52	foundation	foundation	PROPN
eurjchem-1680	147	53	(	(	PUNCT
eurjchem-1680	147	54	nsf	nsf	NOUN
eurjchem-1680	147	55	)	)	PUNCT
eurjchem-1680	147	56	epscor	epscor	NOUN
eurjchem-1680	147	57	grant	grant	VERB
eurjchem-1680	147	58	iia-1301765	iia-1301765	NOUN
eurjchem-1680	147	59	.	.	PUNCT
eurjchem-1680	148	1	disclosure	disclosure	NOUN
eurjchem-1680	148	2	statement	statement	NOUN
eurjchem-1680	148	3	conflict	conflict	NOUN
eurjchem-1680	148	4	of	of	ADP
eurjchem-1680	148	5	interests	interest	NOUN
eurjchem-1680	148	6	:	:	PUNCT
eurjchem-1680	148	7	the	the	DET
eurjchem-1680	148	8	authors	author	NOUN
eurjchem-1680	148	9	declare	declare	VERB
eurjchem-1680	148	10	that	that	SCONJ
eurjchem-1680	148	11	they	they	PRON
eurjchem-1680	148	12	have	have	VERB
eurjchem-1680	148	13	no	no	DET
eurjchem-1680	148	14	conflict	conflict	NOUN
eurjchem-1680	148	15	of	of	ADP
eurjchem-1680	148	16	interest	interest	NOUN
eurjchem-1680	148	17	.	.	PUNCT
eurjchem-1680	149	1	author	author	NOUN
eurjchem-1680	149	2	contributions	contribution	NOUN
eurjchem-1680	149	3	:	:	PUNCT
eurjchem-1680	149	4	all	all	DET
eurjchem-1680	149	5	authors	author	NOUN
eurjchem-1680	149	6	contributed	contribute	VERB
eurjchem-1680	149	7	equally	equally	ADV
eurjchem-1680	149	8	to	to	ADP
eurjchem-1680	149	9	this	this	DET
eurjchem-1680	149	10	work	work	NOUN
eurjchem-1680	149	11	.	.	PUNCT
eurjchem-1680	150	1	ethical	ethical	ADJ
eurjchem-1680	150	2	approval	approval	NOUN
eurjchem-1680	150	3	:	:	PUNCT
eurjchem-1680	151	1	all	all	DET
eurjchem-1680	151	2	ethical	ethical	ADJ
eurjchem-1680	151	3	guidelines	guideline	NOUN
eurjchem-1680	151	4	have	have	AUX
eurjchem-1680	151	5	been	be	AUX
eurjchem-1680	151	6	adhered	adhere	VERB
eurjchem-1680	151	7	.	.	PUNCT
eurjchem-1680	152	1	sample	sample	NOUN
eurjchem-1680	152	2	availability	availability	NOUN
eurjchem-1680	152	3	:	:	PUNCT
eurjchem-1680	152	4	samples	sample	NOUN
eurjchem-1680	152	5	of	of	ADP
eurjchem-1680	152	6	the	the	DET
eurjchem-1680	152	7	compounds	compound	NOUN
eurjchem-1680	152	8	are	be	AUX
eurjchem-1680	152	9	available	available	ADJ
eurjchem-1680	152	10	from	from	ADP
eurjchem-1680	152	11	the	the	DET
eurjchem-1680	152	12	author	author	NOUN
eurjchem-1680	152	13	.	.	PUNCT
eurjchem-1680	153	1	funding	fund	VERB
eurjchem-1680	153	2	american	american	PROPN
eurjchem-1680	153	3	chemical	chemical	PROPN
eurjchem-1680	153	4	society	society	PROPN
eurjchem-1680	153	5	petroleum	petroleum	PROPN
eurjchem-1680	153	6	research	research	NOUN
eurjchem-1680	153	7	fund	fund	PROPN
eurjchem-1680	153	8	http://dx.doi.org/10.13039/100006770	http://dx.doi.org/10.13039/100006770	PROPN
eurjchem-1680	153	9	national	national	PROPN
eurjchem-1680	153	10	institute	institute	PROPN
eurjchem-1680	153	11	of	of	ADP
eurjchem-1680	153	12	general	general	PROPN
eurjchem-1680	153	13	medical	medical	PROPN
eurjchem-1680	153	14	sciences	sciences	PROPN
eurjchem-1680	153	15	http://dx.doi.org/10.13039/100000057	http://dx.doi.org/10.13039/100000057	PROPN
eurjchem-1680	153	16	national	national	PROPN
eurjchem-1680	153	17	science	science	PROPN
eurjchem-1680	153	18	foundation	foundation	PROPN
eurjchem-1680	153	19	http://dx.doi.org/10.13039/501100008982	http://dx.doi.org/10.13039/501100008982	PROPN
eurjchem-1680	153	20	orcid	orcid	PROPN
eurjchem-1680	153	21	dennis	dennis	PROPN
eurjchem-1680	153	22	neil	neil	PROPN
eurjchem-1680	153	23	kevill	kevill	PROPN
eurjchem-1680	154	1	https://orcid.org/0000-0002-1921-7184	https://orcid.org/0000-0002-1921-7184	PROPN
eurjchem-1680	154	2	malcolm	malcolm	PROPN
eurjchem-1680	154	3	john	john	PROPN
eurjchem-1680	154	4	d’souza	d’souza	PROPN
eurjchem-1680	154	5	https://orcid.org/0000-0002-9368-790x	https://orcid.org/0000-0002-9368-790x	PROPN
eurjchem-1680	154	6	references	reference	NOUN
eurjchem-1680	154	7	[	[	X
eurjchem-1680	154	8	1	1	NUM
eurjchem-1680	154	9	]	]	PUNCT
eurjchem-1680	154	10	.	.	PUNCT
eurjchem-1680	155	1	kevill	kevill	PROPN
eurjchem-1680	155	2	,	,	PUNCT
eurjchem-1680	155	3	d.	d.	PROPN
eurjchem-1680	155	4	n.	n.	PROPN
eurjchem-1680	155	5	;	;	PUNCT
eurjchem-1680	155	6	kim	kim	PROPN
eurjchem-1680	155	7	,	,	PUNCT
eurjchem-1680	155	8	c.	c.	PROPN
eurjchem-1680	155	9	b.	b.	PROPN
eurjchem-1680	155	10	j.	j.	PROPN
eurjchem-1680	155	11	org	org	PROPN
eurjchem-1680	155	12	.	.	PUNCT
eurjchem-1680	155	13	chem	chem	PROPN
eurjchem-1680	155	14	.	.	PUNCT
eurjchem-1680	156	1	2005	2005	NUM
eurjchem-1680	156	2	,	,	PUNCT
eurjchem-1680	156	3	70	70	NUM
eurjchem-1680	156	4	,	,	PUNCT
eurjchem-1680	156	5	1490	1490	NUM
eurjchem-1680	156	6	-	-	SYM
eurjchem-1680	156	7	1493	1493	NUM
eurjchem-1680	156	8	.	.	PUNCT
eurjchem-1680	157	1	[	[	X
eurjchem-1680	157	2	2	2	NUM
eurjchem-1680	157	3	]	]	PUNCT
eurjchem-1680	157	4	.	.	PUNCT
eurjchem-1680	158	1	grunwald	grunwald	PROPN
eurjchem-1680	158	2	,	,	PUNCT
eurjchem-1680	158	3	e.	e.	PROPN
eurjchem-1680	158	4	;	;	PUNCT
eurjchem-1680	158	5	winstein	winstein	PROPN
eurjchem-1680	158	6	,	,	PUNCT
eurjchem-1680	158	7	s.	s.	PROPN
eurjchem-1680	158	8	j.	j.	PROPN
eurjchem-1680	158	9	am	am	PROPN
eurjchem-1680	158	10	.	.	PUNCT
eurjchem-1680	159	1	chem	chem	PROPN
eurjchem-1680	159	2	.	.	PUNCT
eurjchem-1680	160	1	soc	soc	PROPN
eurjchem-1680	160	2	.	.	PUNCT
eurjchem-1680	161	1	1948	1948	NUM
eurjchem-1680	161	2	,	,	PUNCT
eurjchem-1680	161	3	70	70	NUM
eurjchem-1680	161	4	,	,	PUNCT
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eurjchem-1680	161	6	-	-	SYM
eurjchem-1680	161	7	854	854	NUM
eurjchem-1680	161	8	.	.	PUNCT
eurjchem-1680	162	1	[	[	X
eurjchem-1680	162	2	3	3	NUM
eurjchem-1680	162	3	]	]	PUNCT
eurjchem-1680	162	4	.	.	PUNCT
eurjchem-1680	162	5	winstein	winstein	PROPN
eurjchem-1680	162	6	,	,	PUNCT
eurjchem-1680	162	7	s.	s.	PROPN
eurjchem-1680	162	8	;	;	PUNCT
eurjchem-1680	162	9	grunwald	grunwald	PROPN
eurjchem-1680	162	10	,	,	PUNCT
eurjchem-1680	162	11	e.	e.	PROPN
eurjchem-1680	162	12	;	;	PUNCT
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eurjchem-1680	162	14	,	,	PUNCT
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eurjchem-1680	162	17	j.	j.	PROPN
eurjchem-1680	162	18	am	am	PROPN
eurjchem-1680	162	19	.	.	PUNCT
eurjchem-1680	163	1	chem	chem	PROPN
eurjchem-1680	163	2	.	.	PUNCT
eurjchem-1680	164	1	soc	soc	PROPN
eurjchem-1680	164	2	.	.	PUNCT
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eurjchem-1680	165	2	,	,	PUNCT
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eurjchem-1680	165	4	,	,	PUNCT
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eurjchem-1680	165	6	-	-	SYM
eurjchem-1680	165	7	2707	2707	NUM
eurjchem-1680	165	8	.	.	PUNCT
eurjchem-1680	166	1	[	[	X
eurjchem-1680	166	2	4	4	NUM
eurjchem-1680	166	3	]	]	PUNCT
eurjchem-1680	166	4	.	.	PUNCT
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eurjchem-1680	166	6	,	,	PUNCT
eurjchem-1680	166	7	d.	d.	PROPN
eurjchem-1680	166	8	n.	n.	PROPN
eurjchem-1680	166	9	;	;	PUNCT
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eurjchem-1680	166	11	,	,	PUNCT
eurjchem-1680	166	12	m.	m.	NOUN
eurjchem-1680	166	13	j.	j.	PROPN
eurjchem-1680	166	14	j.	j.	PROPN
eurjchem-1680	166	15	chem	chem	PROPN
eurjchem-1680	166	16	.	.	PUNCT
eurjchem-1680	167	1	res	re	NOUN
eurjchem-1680	167	2	.	.	PROPN
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eurjchem-1680	167	4	,	,	PUNCT
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eurjchem-1680	167	6	-	-	SYM
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eurjchem-1680	167	8	.	.	PUNCT
eurjchem-1680	168	1	[	[	X
eurjchem-1680	168	2	5	5	NUM
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eurjchem-1680	168	4	.	.	PUNCT
eurjchem-1680	169	1	bentley	bentley	PROPN
eurjchem-1680	169	2	,	,	PUNCT
eurjchem-1680	169	3	t.	t.	PROPN
eurjchem-1680	169	4	w.	w.	PROPN
eurjchem-1680	169	5	;	;	PUNCT
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eurjchem-1680	169	7	,	,	PUNCT
eurjchem-1680	169	8	g.	g.	PROPN
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eurjchem-1680	169	10	.	.	PUNCT
eurjchem-1680	170	1	phys	phy	NOUN
eurjchem-1680	170	2	.	.	PUNCT
eurjchem-1680	171	1	org	org	PROPN
eurjchem-1680	171	2	.	.	PUNCT
eurjchem-1680	171	3	chem	chem	PROPN
eurjchem-1680	171	4	.	.	PUNCT
eurjchem-1680	172	1	1990	1990	NUM
eurjchem-1680	172	2	,	,	PUNCT
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eurjchem-1680	172	4	,	,	PUNCT
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eurjchem-1680	172	6	-	-	SYM
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eurjchem-1680	172	8	.	.	PUNCT
eurjchem-1680	173	1	[	[	X
eurjchem-1680	173	2	6	6	NUM
eurjchem-1680	173	3	]	]	PUNCT
eurjchem-1680	173	4	.	.	PUNCT
eurjchem-1680	173	5	kevill	kevill	PROPN
eurjchem-1680	173	6	,	,	PUNCT
eurjchem-1680	173	7	d.	d.	PROPN
eurjchem-1680	173	8	n.	n.	PROPN
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eurjchem-1680	173	14	-	-	PUNCT
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eurjchem-1680	173	16	relationships	relationship	NOUN
eurjchem-1680	173	17	;	;	PUNCT
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eurjchem-1680	173	19	,	,	PUNCT
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eurjchem-1680	173	23	;	;	PUNCT
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eurjchem-1680	173	26	:	:	PUNCT
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eurjchem-1680	173	28	,	,	PUNCT
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eurjchem-1680	173	32	,	,	PUNCT
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eurjchem-1680	173	34	;	;	PUNCT
eurjchem-1680	173	35	volume	volume	NOUN
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eurjchem-1680	173	40	-	-	SYM
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eurjchem-1680	173	42	.	.	PUNCT
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eurjchem-1680	186	2	.	.	PUNCT
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eurjchem-1680	218	5	;	;	PUNCT
eurjchem-1680	218	6	carter	carter	PROPN
eurjchem-1680	218	7	,	,	PUNCT
eurjchem-1680	218	8	g.	g.	PROPN
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eurjchem-1680	218	10	j.	j.	PROPN
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eurjchem-1680	218	12	.	.	PUNCT
eurjchem-1680	219	1	chem	chem	PROPN
eurjchem-1680	219	2	.	.	PUNCT
eurjchem-1680	220	1	soc	soc	PROPN
eurjchem-1680	220	2	.	.	PUNCT
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eurjchem-1680	221	2	,	,	PUNCT
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eurjchem-1680	221	4	,	,	PUNCT
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eurjchem-1680	221	6	-	-	SYM
eurjchem-1680	221	7	5747	5747	NUM
eurjchem-1680	221	8	.	.	PUNCT
eurjchem-1680	222	1	[	[	X
eurjchem-1680	222	2	20	20	NUM
eurjchem-1680	222	3	]	]	PUNCT
eurjchem-1680	222	4	.	.	PUNCT
eurjchem-1680	223	1	kevill	kevill	PROPN
eurjchem-1680	223	2	,	,	PUNCT
eurjchem-1680	223	3	d.	d.	PROPN
eurjchem-1680	223	4	n.	n.	PROPN
eurjchem-1680	223	5	;	;	PUNCT
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eurjchem-1680	223	7	,	,	PUNCT
eurjchem-1680	223	8	z.	z.	PROPN
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eurjchem-1680	223	11	.	.	PUNCT
eurjchem-1680	224	1	j.	j.	PROPN
eurjchem-1680	224	2	mol	mol	PROPN
eurjchem-1680	224	3	.	.	PUNCT
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eurjchem-1680	225	2	.	.	PUNCT
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eurjchem-1680	225	6	,	,	PUNCT
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eurjchem-1680	225	8	-	-	SYM
eurjchem-1680	225	9	455	455	NUM
eurjchem-1680	225	10	.	.	PUNCT
eurjchem-1680	226	1	[	[	X
eurjchem-1680	226	2	21	21	NUM
eurjchem-1680	226	3	]	]	PUNCT
eurjchem-1680	226	4	.	.	PUNCT
eurjchem-1680	226	5	kevill	kevill	PROPN
eurjchem-1680	226	6	,	,	PUNCT
eurjchem-1680	226	7	d.	d.	PROPN
eurjchem-1680	226	8	n.	n.	PROPN
eurjchem-1680	226	9	;	;	PUNCT
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eurjchem-1680	226	11	,	,	PUNCT
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eurjchem-1680	226	13	j.	j.	PROPN
eurjchem-1680	226	14	j.	j.	PROPN
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eurjchem-1680	226	16	.	.	PUNCT
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eurjchem-1680	227	2	.	.	PUNCT
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eurjchem-1680	227	4	,	,	PUNCT
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eurjchem-1680	227	6	,	,	PUNCT
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eurjchem-1680	227	8	-	-	SYM
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eurjchem-1680	227	10	.	.	PUNCT
eurjchem-1680	228	1	[	[	X
eurjchem-1680	228	2	22	22	NUM
eurjchem-1680	228	3	]	]	PUNCT
eurjchem-1680	228	4	.	.	PUNCT
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eurjchem-1680	229	2	,	,	PUNCT
eurjchem-1680	229	3	d.	d.	PROPN
eurjchem-1680	229	4	n.	n.	PROPN
eurjchem-1680	229	5	;	;	PUNCT
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eurjchem-1680	229	7	,	,	PUNCT
eurjchem-1680	229	8	s.	s.	PROPN
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eurjchem-1680	229	10	;	;	PUNCT
eurjchem-1680	229	11	fujimoto	fujimoto	PROPN
eurjchem-1680	229	12	,	,	PUNCT
eurjchem-1680	229	13	e.	e.	PROPN
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eurjchem-1680	229	22	j.	j.	PROPN
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eurjchem-1680	229	25	mcmanus	mcmanus	PROPN
eurjchem-1680	229	26	,	,	PUNCT
eurjchem-1680	229	27	s.	s.	PROPN
eurjchem-1680	229	28	p.	p.	PROPN
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eurjchem-1680	229	32	in	in	ADP
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eurjchem-1680	229	35	,	,	PUNCT
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eurjchem-1680	229	37	.	.	NOUN
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eurjchem-1680	229	43	,	,	PUNCT
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eurjchem-1680	229	45	,	,	PUNCT
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eurjchem-1680	229	47	,	,	PUNCT
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eurjchem-1680	229	51	.	.	PUNCT
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eurjchem-1680	230	2	-	-	SYM
eurjchem-1680	230	3	283	283	NUM
eurjchem-1680	230	4	.	.	PUNCT
eurjchem-1680	231	1	[	[	X
eurjchem-1680	231	2	23	23	NUM
eurjchem-1680	231	3	]	]	PUNCT
eurjchem-1680	231	4	.	.	PUNCT
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eurjchem-1680	232	2	,	,	PUNCT
eurjchem-1680	232	3	t.	t.	PROPN
eurjchem-1680	232	4	w.	w.	PROPN
eurjchem-1680	232	5	;	;	PUNCT
eurjchem-1680	232	6	carter	carter	PROPN
eurjchem-1680	232	7	,	,	PUNCT
eurjchem-1680	232	8	g.	g.	PROPN
eurjchem-1680	232	9	e.	e.	PROPN
eurjchem-1680	232	10	j.	j.	PROPN
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eurjchem-1680	232	12	.	.	PUNCT
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eurjchem-1680	232	14	.	.	PUNCT
eurjchem-1680	233	1	1983	1983	NUM
eurjchem-1680	233	2	,	,	PUNCT
eurjchem-1680	233	3	48	48	NUM
eurjchem-1680	233	4	,	,	PUNCT
eurjchem-1680	233	5	579	579	NUM
eurjchem-1680	233	6	-	-	SYM
eurjchem-1680	233	7	584	584	NUM
eurjchem-1680	233	8	.	.	PUNCT
eurjchem-1680	234	1	[	[	X
eurjchem-1680	234	2	24	24	NUM
eurjchem-1680	234	3	]	]	PUNCT
eurjchem-1680	234	4	.	.	PUNCT
eurjchem-1680	235	1	hoffmann	hoffmann	PROPN
eurjchem-1680	235	2	,	,	PUNCT
eurjchem-1680	235	3	h.	h.	PROPN
eurjchem-1680	235	4	m.	m.	PROPN
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eurjchem-1680	235	6	j.	j.	PROPN
eurjchem-1680	235	7	chem	chem	PROPN
eurjchem-1680	235	8	.	.	PUNCT
eurjchem-1680	236	1	soc	soc	PROPN
eurjchem-1680	236	2	.	.	PUNCT
eurjchem-1680	237	1	1965	1965	NUM
eurjchem-1680	237	2	,	,	PUNCT
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eurjchem-1680	237	4	-	-	SYM
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eurjchem-1680	237	6	.	.	PUNCT
eurjchem-1680	238	1	[	[	X
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eurjchem-1680	238	4	.	.	PUNCT
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eurjchem-1680	239	2	,	,	PUNCT
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eurjchem-1680	239	5	;	;	PUNCT
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eurjchem-1680	239	10	;	;	PUNCT
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eurjchem-1680	239	16	;	;	PUNCT
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eurjchem-1680	239	18	,	,	PUNCT
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eurjchem-1680	239	21	;	;	PUNCT
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eurjchem-1680	239	27	.	.	PUNCT
eurjchem-1680	240	1	j.	j.	PROPN
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eurjchem-1680	240	3	.	.	PUNCT
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eurjchem-1680	241	2	,	,	PUNCT
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eurjchem-1680	241	4	,	,	PUNCT
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eurjchem-1680	241	6	-	-	SYM
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eurjchem-1680	241	8	.	.	PUNCT
eurjchem-1680	242	1	[	[	X
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eurjchem-1680	242	4	.	.	PUNCT
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eurjchem-1680	243	5	;	;	PUNCT
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eurjchem-1680	243	10	;	;	PUNCT
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eurjchem-1680	243	13	h.	h.	PROPN
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eurjchem-1680	243	22	.	.	PUNCT
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eurjchem-1680	243	24	.	.	PUNCT
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eurjchem-1680	244	2	,	,	PUNCT
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eurjchem-1680	244	4	,	,	PUNCT
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eurjchem-1680	244	6	-	-	SYM
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eurjchem-1680	244	8	.	.	PUNCT
eurjchem-1680	245	1	[	[	X
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eurjchem-1680	245	4	.	.	PUNCT
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eurjchem-1680	247	11	.	.	PUNCT
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eurjchem-1680	248	2	-	-	SYM
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eurjchem-1680	251	2	-	-	SYM
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eurjchem-1680	252	4	.	.	PUNCT
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eurjchem-1680	253	20	;	;	PUNCT
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eurjchem-1680	253	27	.	.	PUNCT
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eurjchem-1680	255	2	.	.	PUNCT
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eurjchem-1680	256	2	,	,	PUNCT
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eurjchem-1680	257	4	.	.	PUNCT
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eurjchem-1680	297	16	by	by	ADP
eurjchem-1680	297	17	nc	nc	PROPN
eurjchem-1680	297	18	license	license	PROPN
eurjchem-1680	297	19	,	,	PUNCT
eurjchem-1680	297	20	which	which	PRON
eurjchem-1680	297	21	permits	permit	VERB
eurjchem-1680	297	22	unrestricted	unrestricted	ADJ
eurjchem-1680	297	23	non	non	ADJ
eurjchem-1680	297	24	-	-	ADJ
eurjchem-1680	297	25	commercial	commercial	ADJ
eurjchem-1680	297	26	use	use	NOUN
eurjchem-1680	297	27	,	,	PUNCT
eurjchem-1680	297	28	distribution	distribution	NOUN
eurjchem-1680	297	29	,	,	PUNCT
eurjchem-1680	297	30	and	and	CCONJ
eurjchem-1680	297	31	reproduction	reproduction	NOUN
eurjchem-1680	297	32	in	in	ADP
eurjchem-1680	297	33	any	any	DET
eurjchem-1680	297	34	medium	medium	NOUN
eurjchem-1680	297	35	,	,	PUNCT
eurjchem-1680	297	36	provided	provide	VERB
eurjchem-1680	297	37	the	the	DET
eurjchem-1680	297	38	original	original	ADJ
eurjchem-1680	297	39	work	work	NOUN
eurjchem-1680	297	40	is	be	AUX
eurjchem-1680	297	41	properly	properly	ADV
eurjchem-1680	297	42	cited	cite	VERB
eurjchem-1680	297	43	without	without	ADP
eurjchem-1680	297	44	any	any	DET
eurjchem-1680	297	45	further	further	ADJ
eurjchem-1680	297	46	permission	permission	NOUN
eurjchem-1680	297	47	from	from	ADP
eurjchem-1680	297	48	atlanta	atlanta	PROPN
eurjchem-1680	297	49	publishing	publishing	PROPN
eurjchem-1680	297	50	house	house	PROPN
eurjchem-1680	297	51	llc	llc	PROPN
eurjchem-1680	297	52	(	(	PUNCT
eurjchem-1680	297	53	european	european	PROPN
eurjchem-1680	297	54	journal	journal	PROPN
eurjchem-1680	297	55	of	of	ADP
eurjchem-1680	297	56	chemistry	chemistry	NOUN
eurjchem-1680	297	57	)	)	PUNCT
eurjchem-1680	297	58	.	.	PUNCT
eurjchem-1680	298	1	no	no	DET
eurjchem-1680	298	2	use	use	NOUN
eurjchem-1680	298	3	,	,	PUNCT
eurjchem-1680	298	4	distribution	distribution	NOUN
eurjchem-1680	298	5	or	or	CCONJ
eurjchem-1680	298	6	reproduction	reproduction	NOUN
eurjchem-1680	298	7	is	be	AUX
eurjchem-1680	298	8	permitted	permit	VERB
eurjchem-1680	298	9	which	which	PRON
eurjchem-1680	298	10	does	do	AUX
eurjchem-1680	298	11	not	not	PART
eurjchem-1680	298	12	comply	comply	VERB
eurjchem-1680	298	13	with	with	ADP
eurjchem-1680	298	14	these	these	DET
eurjchem-1680	298	15	terms	term	NOUN
eurjchem-1680	298	16	.	.	PUNCT
eurjchem-1680	299	1	permissions	permission	NOUN
eurjchem-1680	299	2	for	for	ADP
eurjchem-1680	299	3	commercial	commercial	ADJ
eurjchem-1680	299	4	use	use	NOUN
eurjchem-1680	299	5	of	of	ADP
eurjchem-1680	299	6	this	this	DET
eurjchem-1680	299	7	work	work	NOUN
eurjchem-1680	299	8	beyond	beyond	ADP
eurjchem-1680	299	9	the	the	DET
eurjchem-1680	299	10	scope	scope	NOUN
eurjchem-1680	299	11	of	of	ADP
eurjchem-1680	299	12	the	the	DET
eurjchem-1680	299	13	license	license	NOUN
eurjchem-1680	299	14	(	(	PUNCT
eurjchem-1680	299	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1680	299	16	)	)	PUNCT
eurjchem-1680	299	17	are	be	AUX
eurjchem-1680	299	18	administered	administer	VERB
eurjchem-1680	299	19	by	by	ADP
eurjchem-1680	299	20	atlanta	atlanta	PROPN
eurjchem-1680	299	21	publishing	publishing	PROPN
eurjchem-1680	299	22	house	house	PROPN
eurjchem-1680	299	23	llc	llc	PROPN
eurjchem-1680	299	24	(	(	PUNCT
eurjchem-1680	299	25	european	european	PROPN
eurjchem-1680	299	26	journal	journal	PROPN
eurjchem-1680	299	27	of	of	ADP
eurjchem-1680	299	28	chemistry	chemistry	NOUN
eurjchem-1680	299	29	)	)	PUNCT
eurjchem-1680	299	30	.	.	PUNCT
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eurjchem-1680	300	2	–	–	PUNCT
eurjchem-1680	300	3	european	european	ADJ
eurjchem-1680	300	4	journal	journal	NOUN
eurjchem-1680	300	5	of	of	ADP
eurjchem-1680	300	6	chemistry	chemistry	NOUN
eurjchem-1680	300	7	–	–	PUNCT
eurjchem-1680	300	8	cc	cc	NOUN
eurjchem-1680	300	9	by	by	ADP
eurjchem-1680	300	10	nc	nc	PROPN
eurjchem-1680	300	11	–	–	PUNCT
eurjchem-1680	300	12	doi	doi	NOUN
eurjchem-1680	300	13	:	:	PUNCT
eurjchem-1680	300	14	10.5155	10.5155	NUM
eurjchem-1680	300	15	/	/	SYM
eurjchem-1680	300	16	eurjchem.9.1.1	eurjchem.9.1.1	NOUN
eurjchem-1680	300	17	-	-	PUNCT
eurjchem-1680	300	18	6.1680	6.1680	NUM
eurjchem-1680	300	19	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1680	300	20	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-1680	300	21	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1680	300	22	printfield10	printfield10	NOUN
eurjchem-1680	300	23	:	:	PUNCT
eurjchem-1680	300	24	printfield11	printfield11	NOUN
eurjchem-1680	300	25	:	:	PUNCT
eurjchem-1680	300	26	printfield12	printfield12	PROPN
eurjchem-1680	300	27	:	:	PUNCT
eurjchem-1680	300	28	printfield13	printfield13	VERB
eurjchem-1680	300	29	:	:	PUNCT
eurjchem-1680	300	30	printfield14	printfield14	NOUN
eurjchem-1680	300	31	:	:	PUNCT
eurjchem-1680	300	32	printfield15	printfield15	NOUN
eurjchem-1680	300	33	:	:	PUNCT
eurjchem-1680	300	34	printfield20	printfield20	PROPN
eurjchem-1680	300	35	:	:	PUNCT
eurjchem-1680	300	36	printfield21	printfield21	ADJ
eurjchem-1680	300	37	:	:	PUNCT
eurjchem-1680	300	38	printfield22	printfield22	NOUN
eurjchem-1680	300	39	:	:	PUNCT
eurjchem-1680	300	40	printfield23	printfield23	NOUN
eurjchem-1680	300	41	:	:	PUNCT
eurjchem-1680	300	42	printfield24	printfield24	NOUN
eurjchem-1680	300	43	:	:	PUNCT
eurjchem-1680	300	44	printfield25	printfield25	NOUN
eurjchem-1680	300	45	:	:	PUNCT