id	sid	tid	token	lemma	pos
eurjchem-1774	1	1	synthesis	synthesis	NOUN
eurjchem-1774	1	2	,	,	PUNCT
eurjchem-1774	1	3	characterization	characterization	NOUN
eurjchem-1774	1	4	and	and	CCONJ
eurjchem-1774	1	5	crystal	crystal	NOUN
eurjchem-1774	1	6	structure	structure	NOUN
eurjchem-1774	1	7	of	of	ADP
eurjchem-1774	1	8	platinum(ii	platinum(ii	NOUN
eurjchem-1774	1	9	)	)	PUNCT
eurjchem-1774	1	10	complexes	complex	NOUN
eurjchem-1774	1	11	with	with	ADP
eurjchem-1774	1	12	thiourea	thiourea	NOUN
eurjchem-1774	1	13	derivative	derivative	ADJ
eurjchem-1774	1	14	ligands	ligand	NOUN
eurjchem-1774	1	15	european	european	PROPN
eurjchem-1774	1	16	journal	journal	PROPN
eurjchem-1774	1	17	of	of	ADP
eurjchem-1774	1	18	chemistry	chemistry	NOUN
eurjchem-1774	1	19	9	9	NUM
eurjchem-1774	1	20	(	(	PUNCT
eurjchem-1774	1	21	4	4	NUM
eurjchem-1774	1	22	)	)	PUNCT
eurjchem-1774	1	23	(	(	PUNCT
eurjchem-1774	1	24	2018	2018	NUM
eurjchem-1774	1	25	)	)	PUNCT
eurjchem-1774	1	26	360	360	NUM
eurjchem-1774	1	27	-	-	SYM
eurjchem-1774	1	28	368	368	NUM
eurjchem-1774	1	29	european	european	ADJ
eurjchem-1774	1	30	journal	journal	PROPN
eurjchem-1774	1	31	of	of	ADP
eurjchem-1774	1	32	chemistry	chemistry	NOUN
eurjchem-1774	1	33	view	view	NOUN
eurjchem-1774	1	34	journal	journal	PROPN
eurjchem-1774	1	35	online	online	PROPN
eurjchem-1774	1	36	view	view	NOUN
eurjchem-1774	1	37	article	article	NOUN
eurjchem-1774	1	38	online	online	ADJ
eurjchem-1774	1	39	synthesis	synthesis	NOUN
eurjchem-1774	1	40	,	,	PUNCT
eurjchem-1774	1	41	characterization	characterization	NOUN
eurjchem-1774	1	42	and	and	CCONJ
eurjchem-1774	1	43	crystal	crystal	NOUN
eurjchem-1774	1	44	structure	structure	NOUN
eurjchem-1774	1	45	of	of	ADP
eurjchem-1774	1	46	platinum(ii	platinum(ii	NOUN
eurjchem-1774	1	47	)	)	PUNCT
eurjchem-1774	1	48	complexes	complex	NOUN
eurjchem-1774	1	49	with	with	ADP
eurjchem-1774	1	50	thiourea	thiourea	NOUN
eurjchem-1774	1	51	derivative	derivative	ADJ
eurjchem-1774	1	52	ligands	ligand	NOUN
eurjchem-1774	1	53	ebru	ebru	NOUN
eurjchem-1774	1	54	keskin	keskin	PROPN
eurjchem-1774	1	55	1	1	NUM
eurjchem-1774	1	56	,	,	PUNCT
eurjchem-1774	1	57	ummuhan	ummuhan	PROPN
eurjchem-1774	1	58	solmaz	solmaz	NOUN
eurjchem-1774	1	59	2	2	NUM
eurjchem-1774	1	60	,	,	PUNCT
eurjchem-1774	1	61	gun	gun	NOUN
eurjchem-1774	1	62	binzet	binzet	NOUN
eurjchem-1774	1	63	3	3	NUM
eurjchem-1774	1	64	,	,	PUNCT
eurjchem-1774	1	65	ilkay	ilkay	PROPN
eurjchem-1774	1	66	gumus	gumus	PROPN
eurjchem-1774	1	67	2	2	NUM
eurjchem-1774	1	68	,	,	PUNCT
eurjchem-1774	1	69	*	*	PUNCT
eurjchem-1774	1	70	and	and	CCONJ
eurjchem-1774	1	71	hakan	hakan	PROPN
eurjchem-1774	1	72	arslan	arslan	PROPN
eurjchem-1774	1	73	2	2	NUM
eurjchem-1774	1	74	1	1	NUM
eurjchem-1774	1	75	advanced	advanced	ADJ
eurjchem-1774	1	76	technology	technology	NOUN
eurjchem-1774	1	77	research	research	NOUN
eurjchem-1774	1	78	and	and	CCONJ
eurjchem-1774	1	79	application	application	NOUN
eurjchem-1774	1	80	center	center	NOUN
eurjchem-1774	1	81	,	,	PUNCT
eurjchem-1774	1	82	mersin	mersin	PROPN
eurjchem-1774	1	83	university	university	PROPN
eurjchem-1774	1	84	,	,	PUNCT
eurjchem-1774	1	85	mersin	mersin	PROPN
eurjchem-1774	1	86	,	,	PUNCT
eurjchem-1774	1	87	tr-33343	tr-33343	PROPN
eurjchem-1774	1	88	,	,	PUNCT
eurjchem-1774	1	89	turkey	turkey	PROPN
eurjchem-1774	1	90	ebruuvacin@mersin.edu.tr	ebruuvacin@mersin.edu.tr	PROPN
eurjchem-1774	1	91	(	(	PUNCT
eurjchem-1774	1	92	e.k	e.k	PROPN
eurjchem-1774	1	93	.	.	PROPN
eurjchem-1774	1	94	)	)	PUNCT
eurjchem-1774	1	95	2	2	NUM
eurjchem-1774	1	96	department	department	NOUN
eurjchem-1774	1	97	of	of	ADP
eurjchem-1774	1	98	chemistry	chemistry	NOUN
eurjchem-1774	1	99	,	,	PUNCT
eurjchem-1774	1	100	faculty	faculty	NOUN
eurjchem-1774	1	101	of	of	ADP
eurjchem-1774	1	102	arts	art	NOUN
eurjchem-1774	1	103	and	and	CCONJ
eurjchem-1774	1	104	science	science	PROPN
eurjchem-1774	1	105	,	,	PUNCT
eurjchem-1774	1	106	mersin	mersin	PROPN
eurjchem-1774	1	107	university	university	PROPN
eurjchem-1774	1	108	,	,	PUNCT
eurjchem-1774	1	109	mersin	mersin	PROPN
eurjchem-1774	1	110	,	,	PUNCT
eurjchem-1774	1	111	tr-33343	tr-33343	PROPN
eurjchem-1774	1	112	,	,	PUNCT
eurjchem-1774	1	113	turkey	turkey	PROPN
eurjchem-1774	1	114	ummuhansolmaz@mersin.edu.tr	ummuhansolmaz@mersin.edu.tr	ADV
eurjchem-1774	1	115	(	(	PUNCT
eurjchem-1774	1	116	u.s	u.s	PROPN
eurjchem-1774	1	117	.	.	PROPN
eurjchem-1774	1	118	)	)	PUNCT
eurjchem-1774	1	119	,	,	PUNCT
eurjchem-1774	1	120	ilkay.gumus@mersin.edu.tr	ilkay.gumus@mersin.edu.tr	PROPN
eurjchem-1774	1	121	(	(	PUNCT
eurjchem-1774	1	122	i.g	i.g	PROPN
eurjchem-1774	1	123	.	.	PROPN
eurjchem-1774	1	124	)	)	PUNCT
eurjchem-1774	1	125	,	,	PUNCT
eurjchem-1774	1	126	hakan.arslan@mersin.edu.tr	hakan.arslan@mersin.edu.tr	PROPN
eurjchem-1774	1	127	(	(	PUNCT
eurjchem-1774	1	128	h.a	h.a	PROPN
eurjchem-1774	1	129	.	.	PROPN
eurjchem-1774	1	130	)	)	PUNCT
eurjchem-1774	2	1	3	3	NUM
eurjchem-1774	2	2	department	department	NOUN
eurjchem-1774	2	3	of	of	ADP
eurjchem-1774	2	4	chemistry	chemistry	NOUN
eurjchem-1774	2	5	,	,	PUNCT
eurjchem-1774	2	6	faculty	faculty	NOUN
eurjchem-1774	2	7	of	of	ADP
eurjchem-1774	2	8	education	education	NOUN
eurjchem-1774	2	9	,	,	PUNCT
eurjchem-1774	2	10	mersin	mersin	PROPN
eurjchem-1774	2	11	university	university	PROPN
eurjchem-1774	2	12	,	,	PUNCT
eurjchem-1774	2	13	mersin	mersin	PROPN
eurjchem-1774	2	14	,	,	PUNCT
eurjchem-1774	2	15	tr-33343	tr-33343	PROPN
eurjchem-1774	2	16	,	,	PUNCT
eurjchem-1774	2	17	turkey	turkey	PROPN
eurjchem-1774	2	18	gunbinzet@mersin.edu.tr	gunbinzet@mersin.edu.tr	PROPN
eurjchem-1774	2	19	(	(	PUNCT
eurjchem-1774	2	20	g.b	g.b	PROPN
eurjchem-1774	2	21	.	.	PUNCT
eurjchem-1774	2	22	)	)	PUNCT
eurjchem-1774	3	1	*	*	PUNCT
eurjchem-1774	3	2	corresponding	correspond	VERB
eurjchem-1774	3	3	author	author	NOUN
eurjchem-1774	3	4	at	at	ADP
eurjchem-1774	3	5	:	:	PUNCT
eurjchem-1774	3	6	department	department	NOUN
eurjchem-1774	3	7	of	of	ADP
eurjchem-1774	3	8	chemistry	chemistry	NOUN
eurjchem-1774	3	9	,	,	PUNCT
eurjchem-1774	3	10	faculty	faculty	NOUN
eurjchem-1774	3	11	of	of	ADP
eurjchem-1774	3	12	education	education	NOUN
eurjchem-1774	3	13	,	,	PUNCT
eurjchem-1774	3	14	mersin	mersin	PROPN
eurjchem-1774	3	15	university	university	PROPN
eurjchem-1774	3	16	,	,	PUNCT
eurjchem-1774	3	17	mersin	mersin	PROPN
eurjchem-1774	3	18	,	,	PUNCT
eurjchem-1774	3	19	tr-33343	tr-33343	PROPN
eurjchem-1774	3	20	,	,	PUNCT
eurjchem-1774	3	21	turkey	turkey	PROPN
eurjchem-1774	3	22	.	.	PUNCT
eurjchem-1774	4	1	tel	tel	ADP
eurjchem-1774	4	2	:	:	PUNCT
eurjchem-1774	4	3	+90.324.3610001/14559	+90.324.3610001/14559	PROPN
eurjchem-1774	4	4	fax	fax	PROPN
eurjchem-1774	4	5	:	:	PUNCT
eurjchem-1774	4	6	+90.324.3610047	+90.324.3610047	NUM
eurjchem-1774	4	7	e	e	NOUN
eurjchem-1774	4	8	-	-	NOUN
eurjchem-1774	4	9	mail	mail	NOUN
eurjchem-1774	4	10	:	:	PUNCT
eurjchem-1774	4	11	ilkay.gumus@mersin.edu.tr	ilkay.gumus@mersin.edu.tr	PROPN
eurjchem-1774	4	12	(	(	PUNCT
eurjchem-1774	4	13	i.	i.	PROPN
eurjchem-1774	4	14	gumus	gumus	PROPN
eurjchem-1774	4	15	)	)	PUNCT
eurjchem-1774	4	16	.	.	PUNCT
eurjchem-1774	5	1	10.5155	10.5155	NUM
eurjchem-1774	5	2	/	/	SYM
eurjchem-1774	5	3	eurjchem.9.4.360	eurjchem.9.4.360	NOUN
eurjchem-1774	5	4	-	-	SYM
eurjchem-1774	5	5	368.1774	368.1774	NUM
eurjchem-1774	5	6	received	receive	VERB
eurjchem-1774	5	7	:	:	PUNCT
eurjchem-1774	5	8	16	16	NUM
eurjchem-1774	5	9	july	july	PROPN
eurjchem-1774	5	10	2018	2018	NUM
eurjchem-1774	5	11	received	receive	VERB
eurjchem-1774	5	12	in	in	ADP
eurjchem-1774	5	13	revised	revise	VERB
eurjchem-1774	5	14	form	form	NOUN
eurjchem-1774	5	15	:	:	PUNCT
eurjchem-1774	5	16	12	12	NUM
eurjchem-1774	5	17	october	october	NOUN
eurjchem-1774	5	18	2018	2018	NUM
eurjchem-1774	5	19	accepted	accept	VERB
eurjchem-1774	5	20	:	:	PUNCT
eurjchem-1774	5	21	15	15	NUM
eurjchem-1774	5	22	october	october	NOUN
eurjchem-1774	5	23	2018	2018	NUM
eurjchem-1774	5	24	published	publish	VERB
eurjchem-1774	5	25	online	online	ADV
eurjchem-1774	5	26	:	:	PUNCT
eurjchem-1774	5	27	31	31	NUM
eurjchem-1774	5	28	december	december	PROPN
eurjchem-1774	5	29	2018	2018	NUM
eurjchem-1774	5	30	printed	print	VERB
eurjchem-1774	5	31	:	:	PUNCT
eurjchem-1774	5	32	31	31	NUM
eurjchem-1774	5	33	december	december	PROPN
eurjchem-1774	5	34	2018	2018	NUM
eurjchem-1774	5	35	thiourea	thiourea	NOUN
eurjchem-1774	5	36	derivatives	derivative	NOUN
eurjchem-1774	5	37	[	[	X
eurjchem-1774	5	38	n-(di	n-(di	PROPN
eurjchem-1774	5	39	-	-	PUNCT
eurjchem-1774	5	40	n	n	CCONJ
eurjchem-1774	5	41	-	-	PUNCT
eurjchem-1774	5	42	propylcarbamothioyl)-4	propylcarbamothioyl)-4	VERB
eurjchem-1774	5	43	-	-	PUNCT
eurjchem-1774	5	44	fluorobenzamide	fluorobenzamide	NOUN
eurjchem-1774	5	45	(	(	PUNCT
eurjchem-1774	5	46	hl1	hl1	PROPN
eurjchem-1774	5	47	)	)	PUNCT
eurjchem-1774	5	48	and	and	CCONJ
eurjchem-1774	5	49	n-(di	n-(di	PROPN
eurjchem-1774	5	50	-	-	PUNCT
eurjchem-1774	5	51	npropylcarbamothioyl)-4	npropylcarbamothioyl)-4	PROPN
eurjchem-1774	5	52	-	-	PUNCT
eurjchem-1774	5	53	bromobenzamide	bromobenzamide	NOUN
eurjchem-1774	5	54	(	(	PUNCT
eurjchem-1774	5	55	hl2	hl2	NOUN
eurjchem-1774	5	56	)	)	PUNCT
eurjchem-1774	5	57	]	]	PUNCT
eurjchem-1774	5	58	and	and	CCONJ
eurjchem-1774	5	59	their	their	PRON
eurjchem-1774	5	60	platinum	platinum	NOUN
eurjchem-1774	5	61	complexes	complex	NOUN
eurjchem-1774	5	62	have	have	AUX
eurjchem-1774	5	63	been	be	AUX
eurjchem-1774	5	64	successfully	successfully	ADV
eurjchem-1774	5	65	synthesized	synthesize	VERB
eurjchem-1774	5	66	and	and	CCONJ
eurjchem-1774	5	67	structurally	structurally	ADV
eurjchem-1774	5	68	characterized	characterize	VERB
eurjchem-1774	5	69	by	by	ADP
eurjchem-1774	5	70	spectroscopic	spectroscopic	NOUN
eurjchem-1774	5	71	1h	1h	NUM
eurjchem-1774	5	72	nmr	nmr	NOUN
eurjchem-1774	5	73	,	,	PUNCT
eurjchem-1774	5	74	13c	13c	NOUN
eurjchem-1774	5	75	nmr	nmr	NOUN
eurjchem-1774	5	76	,	,	PUNCT
eurjchem-1774	5	77	cosy	cosy	PROPN
eurjchem-1774	5	78	,	,	PUNCT
eurjchem-1774	5	79	hmqc	hmqc	PROPN
eurjchem-1774	5	80	,	,	PUNCT
eurjchem-1774	5	81	and	and	CCONJ
eurjchem-1774	5	82	ft	ft	PROPN
eurjchem-1774	5	83	-	-	PUNCT
eurjchem-1774	5	84	ir	ir	NOUN
eurjchem-1774	5	85	techniques	technique	NOUN
eurjchem-1774	5	86	.	.	PUNCT
eurjchem-1774	6	1	the	the	DET
eurjchem-1774	6	2	structure	structure	NOUN
eurjchem-1774	6	3	of	of	ADP
eurjchem-1774	6	4	both	both	DET
eurjchem-1774	6	5	complexes	complex	NOUN
eurjchem-1774	6	6	was	be	AUX
eurjchem-1774	6	7	also	also	ADV
eurjchem-1774	6	8	confirmed	confirm	VERB
eurjchem-1774	6	9	by	by	ADP
eurjchem-1774	6	10	single	single	ADJ
eurjchem-1774	6	11	crystal	crystal	NOUN
eurjchem-1774	6	12	x	x	PROPN
eurjchem-1774	6	13	-	-	NOUN
eurjchem-1774	6	14	ray	ray	NOUN
eurjchem-1774	6	15	diffraction	diffraction	NOUN
eurjchem-1774	6	16	studies	study	NOUN
eurjchem-1774	6	17	.	.	PUNCT
eurjchem-1774	7	1	the	the	DET
eurjchem-1774	7	2	study	study	NOUN
eurjchem-1774	7	3	of	of	ADP
eurjchem-1774	7	4	x	x	ADJ
eurjchem-1774	7	5	-	-	NOUN
eurjchem-1774	7	6	ray	ray	ADJ
eurjchem-1774	7	7	single	single	ADJ
eurjchem-1774	7	8	crystal	crystal	PROPN
eurjchem-1774	7	9	diffraction	diffraction	NOUN
eurjchem-1774	7	10	shows	show	VERB
eurjchem-1774	7	11	that	that	SCONJ
eurjchem-1774	7	12	the	the	DET
eurjchem-1774	7	13	supramolecular	supramolecular	ADJ
eurjchem-1774	7	14	aggregation	aggregation	NOUN
eurjchem-1774	7	15	of	of	ADP
eurjchem-1774	7	16	the	the	DET
eurjchem-1774	7	17	complexes	complex	NOUN
eurjchem-1774	7	18	is	be	AUX
eurjchem-1774	7	19	stabilized	stabilize	VERB
eurjchem-1774	7	20	via	via	ADP
eurjchem-1774	7	21	weak	weak	ADJ
eurjchem-1774	7	22	interactions	interaction	NOUN
eurjchem-1774	7	23	as	as	ADV
eurjchem-1774	7	24	well	well	ADV
eurjchem-1774	7	25	as	as	ADP
eurjchem-1774	7	26	stacking	stack	VERB
eurjchem-1774	7	27	interactions	interaction	NOUN
eurjchem-1774	7	28	such	such	ADJ
eurjchem-1774	7	29	as	as	ADP
eurjchem-1774	7	30	c	c	NOUN
eurjchem-1774	7	31	-	-	PUNCT
eurjchem-1774	7	32	h⋅⋅⋅π	h⋅⋅⋅π	ADJ
eurjchem-1774	7	33	and	and	CCONJ
eurjchem-1774	7	34	π⋅⋅⋅π	π⋅⋅⋅π	PRON
eurjchem-1774	7	35	.	.	PUNCT
eurjchem-1774	8	1	the	the	DET
eurjchem-1774	8	2	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	8	3	-	-	PUNCT
eurjchem-1774	8	4	s	s	PROPN
eurjchem-1774	8	5	,	,	PUNCT
eurjchem-1774	8	6	o)2	o)2	NOUN
eurjchem-1774	8	7	showed	show	VERB
eurjchem-1774	8	8	c	c	NOUN
eurjchem-1774	8	9	–	–	PUNCT
eurjchem-1774	8	10	h⋯π	h⋯π	PUNCT
eurjchem-1774	8	11	and	and	CCONJ
eurjchem-1774	8	12	π⋯π	π⋯π	PUNCT
eurjchem-1774	8	13	stacking	stack	VERB
eurjchem-1774	8	14	interactions	interaction	NOUN
eurjchem-1774	8	15	,	,	PUNCT
eurjchem-1774	8	16	whereas	whereas	SCONJ
eurjchem-1774	8	17	only	only	ADV
eurjchem-1774	8	18	c	c	X
eurjchem-1774	8	19	–	–	PUNCT
eurjchem-1774	8	20	h⋯π	h⋯π	PUNCT
eurjchem-1774	8	21	stacking	stack	VERB
eurjchem-1774	8	22	interaction	interaction	NOUN
eurjchem-1774	8	23	was	be	AUX
eurjchem-1774	8	24	observed	observe	VERB
eurjchem-1774	8	25	in	in	ADP
eurjchem-1774	8	26	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	8	27	-	-	PUNCT
eurjchem-1774	8	28	s	s	PROPN
eurjchem-1774	8	29	,	,	PUNCT
eurjchem-1774	8	30	o)2	o)2	PROPN
eurjchem-1774	8	31	]	]	PUNCT
eurjchem-1774	8	32	.	.	PUNCT
eurjchem-1774	9	1	in	in	ADP
eurjchem-1774	9	2	addition	addition	NOUN
eurjchem-1774	9	3	,	,	PUNCT
eurjchem-1774	9	4	the	the	DET
eurjchem-1774	9	5	strong	strong	ADJ
eurjchem-1774	9	6	classical	classical	ADJ
eurjchem-1774	9	7	and	and	CCONJ
eurjchem-1774	9	8	non	non	ADJ
eurjchem-1774	9	9	-	-	ADJ
eurjchem-1774	9	10	classical	classical	ADJ
eurjchem-1774	9	11	intermolecular	intermolecular	ADJ
eurjchem-1774	9	12	hydrogen	hydrogen	NOUN
eurjchem-1774	9	13	bonds	bond	NOUN
eurjchem-1774	9	14	are	be	AUX
eurjchem-1774	9	15	not	not	PART
eurjchem-1774	9	16	found	find	VERB
eurjchem-1774	9	17	in	in	ADP
eurjchem-1774	9	18	the	the	DET
eurjchem-1774	9	19	prepared	prepared	ADJ
eurjchem-1774	9	20	complexes	complex	NOUN
eurjchem-1774	9	21	.	.	PUNCT
eurjchem-1774	10	1	therefore	therefore	ADV
eurjchem-1774	10	2	,	,	PUNCT
eurjchem-1774	10	3	it	it	PRON
eurjchem-1774	10	4	can	can	AUX
eurjchem-1774	10	5	be	be	AUX
eurjchem-1774	10	6	said	say	VERB
eurjchem-1774	10	7	that	that	SCONJ
eurjchem-1774	10	8	the	the	DET
eurjchem-1774	10	9	c	c	NOUN
eurjchem-1774	10	10	–	–	PUNCT
eurjchem-1774	10	11	h⋯π	h⋯π	PUNCT
eurjchem-1774	10	12	and	and	CCONJ
eurjchem-1774	10	13	π⋯π	π⋯π	PUNCT
eurjchem-1774	10	14	stacking	stack	VERB
eurjchem-1774	10	15	interactions	interaction	NOUN
eurjchem-1774	10	16	play	play	VERB
eurjchem-1774	10	17	an	an	DET
eurjchem-1774	10	18	important	important	ADJ
eurjchem-1774	10	19	role	role	NOUN
eurjchem-1774	10	20	in	in	ADP
eurjchem-1774	10	21	the	the	DET
eurjchem-1774	10	22	formation	formation	NOUN
eurjchem-1774	10	23	of	of	ADP
eurjchem-1774	10	24	supramolecular	supramolecular	ADJ
eurjchem-1774	10	25	structures	structure	NOUN
eurjchem-1774	10	26	of	of	ADP
eurjchem-1774	10	27	the	the	DET
eurjchem-1774	10	28	complexes	complex	NOUN
eurjchem-1774	10	29	.	.	PUNCT
eurjchem-1774	11	1	thiourea	thiourea	NOUN
eurjchem-1774	11	2	synthesis	synthesis	NOUN
eurjchem-1774	11	3	platinum	platinum	NOUN
eurjchem-1774	11	4	complexes	complex	NOUN
eurjchem-1774	11	5	benzamide	benzamide	VERB
eurjchem-1774	11	6	derivative	derivative	ADJ
eurjchem-1774	11	7	supramolecular	supramolecular	ADJ
eurjchem-1774	11	8	structure	structure	NOUN
eurjchem-1774	11	9	single	single	ADJ
eurjchem-1774	11	10	crystal	crystal	NOUN
eurjchem-1774	11	11	x	x	PROPN
eurjchem-1774	11	12	-	-	NOUN
eurjchem-1774	11	13	ray	ray	NOUN
eurjchem-1774	11	14	diffraction	diffraction	NOUN
eurjchem-1774	11	15	cite	cite	VERB
eurjchem-1774	11	16	this	this	PRON
eurjchem-1774	11	17	:	:	PUNCT
eurjchem-1774	11	18	eur	eur	PROPN
eurjchem-1774	11	19	.	.	PUNCT
eurjchem-1774	12	1	j.	j.	PROPN
eurjchem-1774	12	2	chem	chem	PROPN
eurjchem-1774	12	3	.	.	PUNCT
eurjchem-1774	13	1	2018	2018	NUM
eurjchem-1774	13	2	,	,	PUNCT
eurjchem-1774	13	3	9(4	9(4	NUM
eurjchem-1774	13	4	)	)	PUNCT
eurjchem-1774	13	5	,	,	PUNCT
eurjchem-1774	13	6	360	360	NUM
eurjchem-1774	13	7	-	-	SYM
eurjchem-1774	13	8	368	368	NUM
eurjchem-1774	13	9	journal	journal	NOUN
eurjchem-1774	13	10	website	website	NOUN
eurjchem-1774	13	11	:	:	PUNCT
eurjchem-1774	13	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1774	13	13	1	1	X
eurjchem-1774	13	14	.	.	PUNCT
eurjchem-1774	13	15	introduction	introduction	NOUN
eurjchem-1774	13	16	thiourea	thiourea	NOUN
eurjchem-1774	13	17	containing	contain	VERB
eurjchem-1774	13	18	compounds	compound	NOUN
eurjchem-1774	13	19	are	be	AUX
eurjchem-1774	13	20	versatile	versatile	ADJ
eurjchem-1774	13	21	molecules	molecule	NOUN
eurjchem-1774	13	22	which	which	PRON
eurjchem-1774	13	23	are	be	AUX
eurjchem-1774	13	24	capable	capable	ADJ
eurjchem-1774	13	25	of	of	ADP
eurjchem-1774	13	26	coordinating	coordinate	VERB
eurjchem-1774	13	27	with	with	ADP
eurjchem-1774	13	28	metal	metal	NOUN
eurjchem-1774	13	29	ions	ion	NOUN
eurjchem-1774	13	30	to	to	PART
eurjchem-1774	13	31	form	form	VERB
eurjchem-1774	13	32	stable	stable	ADJ
eurjchem-1774	13	33	complexes	complex	NOUN
eurjchem-1774	13	34	.	.	PUNCT
eurjchem-1774	14	1	for	for	ADP
eurjchem-1774	14	2	example	example	NOUN
eurjchem-1774	14	3	n-(alkyl	n-(alkyl	PROPN
eurjchem-1774	14	4	/	/	SYM
eurjchem-1774	14	5	aryl)-n'-acylthiourea	aryl)-n'-acylthiourea	PROPN
eurjchem-1774	14	6	and	and	CCONJ
eurjchem-1774	14	7	n	n	CCONJ
eurjchem-1774	14	8	-	-	PUNCT
eurjchem-1774	14	9	di(alkyl	di(alkyl	PROPN
eurjchem-1774	14	10	/	/	SYM
eurjchem-1774	14	11	aryl)-n'-acylthiourea	aryl)-n'-acylthiourea	PROPN
eurjchem-1774	14	12	derivatives	derivative	NOUN
eurjchem-1774	14	13	which	which	PRON
eurjchem-1774	14	14	have	have	VERB
eurjchem-1774	14	15	oxygen	oxygen	NOUN
eurjchem-1774	14	16	,	,	PUNCT
eurjchem-1774	14	17	nitrogen	nitrogen	NOUN
eurjchem-1774	14	18	and	and	CCONJ
eurjchem-1774	14	19	sulphur	sulphur	NOUN
eurjchem-1774	14	20	donor	donor	NOUN
eurjchem-1774	14	21	atoms	atom	NOUN
eurjchem-1774	14	22	,	,	PUNCT
eurjchem-1774	14	23	exhibit	exhibit	VERB
eurjchem-1774	14	24	prevalent	prevalent	ADJ
eurjchem-1774	14	25	coordination	coordination	NOUN
eurjchem-1774	14	26	modes	mode	NOUN
eurjchem-1774	14	27	.	.	PUNCT
eurjchem-1774	15	1	organic	organic	ADJ
eurjchem-1774	15	2	ligands	ligand	NOUN
eurjchem-1774	15	3	that	that	PRON
eurjchem-1774	15	4	have	have	VERB
eurjchem-1774	15	5	thiourea	thiourea	NOUN
eurjchem-1774	15	6	moiety	moiety	NOUN
eurjchem-1774	15	7	are	be	AUX
eurjchem-1774	15	8	able	able	ADJ
eurjchem-1774	15	9	to	to	PART
eurjchem-1774	15	10	bind	bind	VERB
eurjchem-1774	15	11	metal	metal	NOUN
eurjchem-1774	15	12	ions	ion	NOUN
eurjchem-1774	15	13	in	in	ADP
eurjchem-1774	15	14	several	several	ADJ
eurjchem-1774	15	15	ways	way	NOUN
eurjchem-1774	15	16	,	,	PUNCT
eurjchem-1774	15	17	like	like	ADP
eurjchem-1774	15	18	:	:	PUNCT
eurjchem-1774	15	19	(	(	PUNCT
eurjchem-1774	15	20	i	i	NOUN
eurjchem-1774	15	21	)	)	PUNCT
eurjchem-1774	15	22	acting	act	VERB
eurjchem-1774	15	23	as	as	ADP
eurjchem-1774	15	24	monodentate	monodentate	ADJ
eurjchem-1774	15	25	ligands	ligand	NOUN
eurjchem-1774	15	26	through	through	ADP
eurjchem-1774	15	27	sulphur	sulphur	NOUN
eurjchem-1774	15	28	atom	atom	NOUN
eurjchem-1774	15	29	in	in	ADP
eurjchem-1774	15	30	mononuclear	mononuclear	ADJ
eurjchem-1774	15	31	complexes	complex	NOUN
eurjchem-1774	15	32	[	[	X
eurjchem-1774	15	33	1	1	NUM
eurjchem-1774	15	34	-	-	SYM
eurjchem-1774	15	35	4	4	NUM
eurjchem-1774	15	36	]	]	PUNCT
eurjchem-1774	15	37	(	(	PUNCT
eurjchem-1774	15	38	ii	ii	NOUN
eurjchem-1774	15	39	)	)	PUNCT
eurjchem-1774	15	40	binding	bind	VERB
eurjchem-1774	15	41	to	to	ADP
eurjchem-1774	15	42	metal	metal	NOUN
eurjchem-1774	15	43	ions	ion	NOUN
eurjchem-1774	15	44	forming	form	VERB
eurjchem-1774	15	45	s	s	NOUN
eurjchem-1774	15	46	-	-	NOUN
eurjchem-1774	15	47	bridges	bridge	NOUN
eurjchem-1774	15	48	in	in	ADP
eurjchem-1774	15	49	dinuclear	dinuclear	ADJ
eurjchem-1774	15	50	complexes	complex	NOUN
eurjchem-1774	15	51	[	[	PUNCT
eurjchem-1774	15	52	4	4	NUM
eurjchem-1774	15	53	-	-	SYM
eurjchem-1774	15	54	8	8	NUM
eurjchem-1774	15	55	]	]	PUNCT
eurjchem-1774	15	56	or	or	CCONJ
eurjchem-1774	15	57	(	(	PUNCT
eurjchem-1774	15	58	iii	iii	NOUN
eurjchem-1774	15	59	)	)	PUNCT
eurjchem-1774	15	60	chelating	chelate	VERB
eurjchem-1774	15	61	sulphur	sulphur	NOUN
eurjchem-1774	15	62	and	and	CCONJ
eurjchem-1774	15	63	nitrogen	nitrogen	NOUN
eurjchem-1774	15	64	atoms	atom	NOUN
eurjchem-1774	15	65	[	[	X
eurjchem-1774	15	66	4	4	NUM
eurjchem-1774	15	67	-	-	NUM
eurjchem-1774	15	68	6,8	6,8	NUM
eurjchem-1774	15	69	-	-	SYM
eurjchem-1774	15	70	16	16	NUM
eurjchem-1774	15	71	]	]	PUNCT
eurjchem-1774	15	72	thiourea	thiourea	NOUN
eurjchem-1774	15	73	derivatives	derivative	NOUN
eurjchem-1774	15	74	as	as	ADP
eurjchem-1774	15	75	a	a	DET
eurjchem-1774	15	76	ligand	ligand	NOUN
eurjchem-1774	15	77	have	have	VERB
eurjchem-1774	15	78	a	a	DET
eurjchem-1774	15	79	large	large	ADJ
eurjchem-1774	15	80	dipole	dipole	NOUN
eurjchem-1774	15	81	moment	moment	NOUN
eurjchem-1774	15	82	and	and	CCONJ
eurjchem-1774	15	83	these	these	DET
eurjchem-1774	15	84	ligands	ligand	NOUN
eurjchem-1774	15	85	can	can	AUX
eurjchem-1774	15	86	also	also	ADV
eurjchem-1774	15	87	form	form	VERB
eurjchem-1774	15	88	extensive	extensive	ADJ
eurjchem-1774	15	89	network	network	NOUN
eurjchem-1774	15	90	of	of	ADP
eurjchem-1774	15	91	hydrogen	hydrogen	NOUN
eurjchem-1774	15	92	bonds	bond	NOUN
eurjchem-1774	15	93	due	due	ADP
eurjchem-1774	15	94	to	to	ADP
eurjchem-1774	15	95	their	their	PRON
eurjchem-1774	15	96	unique	unique	ADJ
eurjchem-1774	15	97	structures	structure	NOUN
eurjchem-1774	15	98	.	.	PUNCT
eurjchem-1774	16	1	for	for	ADP
eurjchem-1774	16	2	example	example	NOUN
eurjchem-1774	16	3	in	in	ADP
eurjchem-1774	16	4	3	3	NUM
eurjchem-1774	16	5	-	-	PUNCT
eurjchem-1774	16	6	monosubstituted	monosubstitute	VERB
eurjchem-1774	16	7	arylthioureas	arylthiourea	NOUN
eurjchem-1774	16	8	[	[	X
eurjchem-1774	16	9	17	17	NUM
eurjchem-1774	16	10	-	-	SYM
eurjchem-1774	16	11	19	19	NUM
eurjchem-1774	16	12	]	]	PUNCT
eurjchem-1774	16	13	,	,	PUNCT
eurjchem-1774	16	14	the	the	DET
eurjchem-1774	16	15	carbonyl	carbonyl	NOUN
eurjchem-1774	16	16	group	group	NOUN
eurjchem-1774	16	17	and	and	CCONJ
eurjchem-1774	16	18	the	the	DET
eurjchem-1774	16	19	proton	proton	NOUN
eurjchem-1774	16	20	on	on	ADP
eurjchem-1774	16	21	the	the	DET
eurjchem-1774	16	22	nitrogen	nitrogen	NOUN
eurjchem-1774	16	23	attach	attach	NOUN
eurjchem-1774	16	24	in	in	ADP
eurjchem-1774	16	25	a	a	DET
eurjchem-1774	16	26	strong	strong	ADJ
eurjchem-1774	16	27	hydrogen	hydrogen	NOUN
eurjchem-1774	16	28	bond	bond	NOUN
eurjchem-1774	16	29	interaction	interaction	NOUN
eurjchem-1774	16	30	which	which	PRON
eurjchem-1774	16	31	unite	unite	VERB
eurjchem-1774	16	32	into	into	ADP
eurjchem-1774	16	33	a	a	DET
eurjchem-1774	16	34	planar	planar	ADJ
eurjchem-1774	16	35	six	six	NUM
eurjchem-1774	16	36	-	-	PUNCT
eurjchem-1774	16	37	membered	membere	VERB
eurjchem-1774	16	38	ring	ring	NOUN
eurjchem-1774	16	39	structure	structure	NOUN
eurjchem-1774	16	40	forming	form	VERB
eurjchem-1774	16	41	an	an	DET
eurjchem-1774	16	42	“	"	PUNCT
eurjchem-1774	16	43	s	s	NOUN
eurjchem-1774	16	44	”	"	PUNCT
eurjchem-1774	16	45	shaped	shaped	ADJ
eurjchem-1774	16	46	conformation	conformation	NOUN
eurjchem-1774	16	47	of	of	ADP
eurjchem-1774	16	48	the	the	DET
eurjchem-1774	16	49	c	c	PROPN
eurjchem-1774	16	50	=	=	NOUN
eurjchem-1774	16	51	o	o	NOUN
eurjchem-1774	16	52	and	and	CCONJ
eurjchem-1774	16	53	c	c	NOUN
eurjchem-1774	16	54	=	=	NOUN
eurjchem-1774	16	55	s	s	PART
eurjchem-1774	16	56	groups	group	NOUN
eurjchem-1774	16	57	[	[	X
eurjchem-1774	16	58	20,21	20,21	NUM
eurjchem-1774	16	59	]	]	PUNCT
eurjchem-1774	16	60	.	.	PUNCT
eurjchem-1774	17	1	further	far	ADV
eurjchem-1774	17	2	,	,	PUNCT
eurjchem-1774	17	3	it	it	PRON
eurjchem-1774	17	4	can	can	AUX
eurjchem-1774	17	5	also	also	ADV
eurjchem-1774	17	6	be	be	AUX
eurjchem-1774	17	7	stated	state	VERB
eurjchem-1774	17	8	that	that	SCONJ
eurjchem-1774	17	9	aminethiourea	aminethiourea	NOUN
eurjchem-1774	17	10	compounds	compound	NOUN
eurjchem-1774	17	11	might	might	AUX
eurjchem-1774	17	12	have	have	VERB
eurjchem-1774	17	13	bifunctional	bifunctional	ADJ
eurjchem-1774	17	14	properties	property	NOUN
eurjchem-1774	17	15	due	due	ADJ
eurjchem-1774	17	16	to	to	ADP
eurjchem-1774	17	17	the	the	DET
eurjchem-1774	17	18	intraand	intraand	NOUN
eurjchem-1774	17	19	inter	inter	ADJ
eurjchem-1774	17	20	-	-	ADJ
eurjchem-1774	17	21	molecular	molecular	ADJ
eurjchem-1774	17	22	interactions	interaction	NOUN
eurjchem-1774	17	23	via	via	ADP
eurjchem-1774	17	24	hydrogen	hydrogen	NOUN
eurjchem-1774	17	25	bonding	bonding	NOUN
eurjchem-1774	18	1	[	[	X
eurjchem-1774	18	2	22	22	NUM
eurjchem-1774	18	3	-	-	SYM
eurjchem-1774	18	4	25	25	NUM
eurjchem-1774	18	5	]	]	PUNCT
eurjchem-1774	18	6	.	.	PUNCT
eurjchem-1774	19	1	the	the	DET
eurjchem-1774	19	2	interplay	interplay	NOUN
eurjchem-1774	19	3	of	of	ADP
eurjchem-1774	19	4	intermolecular	intermolecular	ADJ
eurjchem-1774	19	5	and	and	CCONJ
eurjchem-1774	19	6	intramolecular	intramolecular	ADJ
eurjchem-1774	19	7	hydrogen	hydrogen	NOUN
eurjchem-1774	19	8	bonding	bonding	NOUN
eurjchem-1774	19	9	has	have	VERB
eurjchem-1774	19	10	direct	direct	ADJ
eurjchem-1774	19	11	relevance	relevance	NOUN
eurjchem-1774	19	12	on	on	ADP
eurjchem-1774	19	13	chemical	chemical	ADJ
eurjchem-1774	19	14	properties	property	NOUN
eurjchem-1774	19	15	of	of	ADP
eurjchem-1774	19	16	these	these	DET
eurjchem-1774	19	17	compounds	compound	NOUN
eurjchem-1774	19	18	,	,	PUNCT
eurjchem-1774	19	19	including	include	VERB
eurjchem-1774	19	20	their	their	PRON
eurjchem-1774	19	21	use	use	NOUN
eurjchem-1774	19	22	as	as	ADP
eurjchem-1774	19	23	ligand	ligand	NOUN
eurjchem-1774	19	24	in	in	ADP
eurjchem-1774	19	25	metal	metal	NOUN
eurjchem-1774	19	26	complexes	complex	NOUN
eurjchem-1774	19	27	[	[	X
eurjchem-1774	19	28	26	26	NUM
eurjchem-1774	19	29	]	]	PUNCT
eurjchem-1774	19	30	and	and	CCONJ
eurjchem-1774	19	31	also	also	ADV
eurjchem-1774	19	32	their	their	PRON
eurjchem-1774	19	33	conformational	conformational	ADJ
eurjchem-1774	19	34	properties	property	NOUN
eurjchem-1774	19	35	,	,	PUNCT
eurjchem-1774	19	36	which	which	PRON
eurjchem-1774	19	37	have	have	VERB
eurjchem-1774	19	38	influence	influence	NOUN
eurjchem-1774	19	39	in	in	ADP
eurjchem-1774	19	40	the	the	DET
eurjchem-1774	19	41	applied	apply	VERB
eurjchem-1774	19	42	fields	field	NOUN
eurjchem-1774	19	43	[	[	X
eurjchem-1774	19	44	27	27	NUM
eurjchem-1774	19	45	]	]	PUNCT
eurjchem-1774	19	46	.	.	PUNCT
eurjchem-1774	20	1	metal	metal	NOUN
eurjchem-1774	20	2	complexes	complex	NOUN
eurjchem-1774	20	3	of	of	ADP
eurjchem-1774	20	4	these	these	DET
eurjchem-1774	20	5	compounds	compound	NOUN
eurjchem-1774	20	6	have	have	AUX
eurjchem-1774	20	7	long	long	ADV
eurjchem-1774	20	8	been	be	AUX
eurjchem-1774	20	9	known	know	VERB
eurjchem-1774	20	10	not	not	PART
eurjchem-1774	20	11	only	only	ADV
eurjchem-1774	20	12	for	for	ADP
eurjchem-1774	20	13	their	their	PRON
eurjchem-1774	20	14	wide	wide	ADJ
eurjchem-1774	20	15	range	range	NOUN
eurjchem-1774	20	16	of	of	ADP
eurjchem-1774	20	17	biological	biological	ADJ
eurjchem-1774	20	18	applications	application	NOUN
eurjchem-1774	20	19	but	but	CCONJ
eurjchem-1774	20	20	also	also	ADV
eurjchem-1774	20	21	for	for	ADP
eurjchem-1774	20	22	their	their	PRON
eurjchem-1774	20	23	role	role	NOUN
eurjchem-1774	20	24	in	in	ADP
eurjchem-1774	20	25	analytical	analytical	ADJ
eurjchem-1774	20	26	sciences	science	NOUN
eurjchem-1774	21	1	[	[	X
eurjchem-1774	21	2	28	28	NUM
eurjchem-1774	21	3	-	-	SYM
eurjchem-1774	21	4	30	30	NUM
eurjchem-1774	21	5	]	]	PUNCT
eurjchem-1774	21	6	,	,	PUNCT
eurjchem-1774	21	7	as	as	ADP
eurjchem-1774	21	8	inhibitors	inhibitor	NOUN
eurjchem-1774	21	9	in	in	ADP
eurjchem-1774	21	10	the	the	DET
eurjchem-1774	21	11	corrosion	corrosion	NOUN
eurjchem-1774	21	12	field	field	NOUN
eurjchem-1774	21	13	[	[	X
eurjchem-1774	21	14	31	31	NUM
eurjchem-1774	21	15	]	]	PUNCT
eurjchem-1774	21	16	and	and	CCONJ
eurjchem-1774	21	17	as	as	ADP
eurjchem-1774	21	18	catalysts	catalyst	NOUN
eurjchem-1774	21	19	in	in	ADP
eurjchem-1774	21	20	chemical	chemical	ADJ
eurjchem-1774	21	21	reactions	reaction	NOUN
eurjchem-1774	21	22	[	[	X
eurjchem-1774	21	23	21,32	21,32	NUM
eurjchem-1774	21	24	]	]	PUNCT
eurjchem-1774	21	25	.	.	PUNCT
eurjchem-1774	22	1	because	because	SCONJ
eurjchem-1774	22	2	of	of	ADP
eurjchem-1774	22	3	the	the	DET
eurjchem-1774	22	4	significant	significant	ADJ
eurjchem-1774	22	5	properties	property	NOUN
eurjchem-1774	22	6	that	that	PRON
eurjchem-1774	22	7	thiourea	thiourea	NOUN
eurjchem-1774	22	8	derivatives	derivative	NOUN
eurjchem-1774	22	9	have	have	VERB
eurjchem-1774	22	10	,	,	PUNCT
eurjchem-1774	22	11	their	their	PRON
eurjchem-1774	22	12	synthesis	synthesis	NOUN
eurjchem-1774	22	13	,	,	PUNCT
eurjchem-1774	22	14	structure	structure	NOUN
eurjchem-1774	22	15	,	,	PUNCT
eurjchem-1774	22	16	biological	biological	ADJ
eurjchem-1774	22	17	activity	activity	NOUN
eurjchem-1774	22	18	and	and	CCONJ
eurjchem-1774	22	19	application	application	NOUN
eurjchem-1774	22	20	to	to	ADP
eurjchem-1774	22	21	these	these	DET
eurjchem-1774	22	22	kinds	kind	NOUN
eurjchem-1774	22	23	of	of	ADP
eurjchem-1774	22	24	compounds	compound	NOUN
eurjchem-1774	22	25	have	have	AUX
eurjchem-1774	22	26	drawn	draw	VERB
eurjchem-1774	22	27	attention	attention	NOUN
eurjchem-1774	22	28	from	from	ADP
eurjchem-1774	22	29	the	the	DET
eurjchem-1774	22	30	past	past	NOUN
eurjchem-1774	22	31	to	to	ADP
eurjchem-1774	22	32	the	the	DET
eurjchem-1774	22	33	present	present	NOUN
eurjchem-1774	22	34	.	.	PUNCT
eurjchem-1774	23	1	numbers	number	NOUN
eurjchem-1774	23	2	of	of	ADP
eurjchem-1774	23	3	studies	study	NOUN
eurjchem-1774	23	4	,	,	PUNCT
eurjchem-1774	23	5	involving	involve	VERB
eurjchem-1774	23	6	structural	structural	ADJ
eurjchem-1774	23	7	ligand	ligand	NOUN
eurjchem-1774	23	8	design	design	NOUN
eurjchem-1774	23	9	and	and	CCONJ
eurjchem-1774	23	10	the	the	DET
eurjchem-1774	23	11	synthesis	synthesis	NOUN
eurjchem-1774	23	12	of	of	ADP
eurjchem-1774	23	13	complexes	complex	NOUN
eurjchem-1774	23	14	for	for	ADP
eurjchem-1774	23	15	different	different	ADJ
eurjchem-1774	23	16	purposes	purpose	NOUN
eurjchem-1774	23	17	in	in	ADP
eurjchem-1774	23	18	various	various	ADJ
eurjchem-1774	23	19	fields	field	NOUN
eurjchem-1774	23	20	,	,	PUNCT
eurjchem-1774	23	21	have	have	AUX
eurjchem-1774	23	22	increased	increase	VERB
eurjchem-1774	23	23	.	.	PUNCT
eurjchem-1774	24	1	as	as	ADP
eurjchem-1774	24	2	a	a	DET
eurjchem-1774	24	3	part	part	NOUN
eurjchem-1774	24	4	of	of	ADP
eurjchem-1774	24	5	our	our	PRON
eurjchem-1774	24	6	research	research	NOUN
eurjchem-1774	24	7	,	,	PUNCT
eurjchem-1774	24	8	we	we	PRON
eurjchem-1774	24	9	report	report	VERB
eurjchem-1774	24	10	herein	herein	VERB
eurjchem-1774	24	11	the	the	DET
eurjchem-1774	24	12	synthesis	synthesis	NOUN
eurjchem-1774	24	13	and	and	CCONJ
eurjchem-1774	24	14	characterization	characterization	NOUN
eurjchem-1774	24	15	of	of	ADP
eurjchem-1774	24	16	thiourea	thiourea	NOUN
eurjchem-1774	24	17	derivative	derivative	ADJ
eurjchem-1774	24	18	ligands	ligand	NOUN
eurjchem-1774	24	19	(	(	PUNCT
eurjchem-1774	24	20	n-(di	n-(di	PROPN
eurjchem-1774	24	21	-	-	PUNCT
eurjchem-1774	24	22	n	n	CCONJ
eurjchem-1774	24	23	-	-	PUNCT
eurjchem-1774	24	24	propylcarbamothioyl)-4	propylcarbamothioyl)-4	VERB
eurjchem-1774	24	25	-	-	PUNCT
eurjchem-1774	24	26	fluorobenzamide	fluorobenzamide	NOUN
eurjchem-1774	24	27	(	(	PUNCT
eurjchem-1774	24	28	hl1	hl1	PROPN
eurjchem-1774	24	29	)	)	PUNCT
eurjchem-1774	24	30	and	and	CCONJ
eurjchem-1774	24	31	n-(di	n-(di	PROPN
eurjchem-1774	24	32	-	-	PUNCT
eurjchem-1774	24	33	n	n	CCONJ
eurjchem-1774	24	34	-	-	PUNCT
eurjchem-1774	24	35	propyl	propyl	ADJ
eurjchem-1774	24	36	abstract	abstract	ADJ
eurjchem-1774	24	37	research	research	NOUN
eurjchem-1774	24	38	article	article	NOUN
eurjchem-1774	24	39	keywords	keyword	VERB
eurjchem-1774	24	40	european	european	PROPN
eurjchem-1774	24	41	journal	journal	PROPN
eurjchem-1774	24	42	of	of	ADP
eurjchem-1774	24	43	chemistry	chemistry	NOUN
eurjchem-1774	24	44	issn	issn	VERB
eurjchem-1774	24	45	2153	2153	NUM
eurjchem-1774	24	46	-	-	SYM
eurjchem-1774	24	47	2249	2249	NUM
eurjchem-1774	24	48	(	(	PUNCT
eurjchem-1774	24	49	print	print	NOUN
eurjchem-1774	24	50	)	)	PUNCT
eurjchem-1774	24	51	/	/	PUNCT
eurjchem-1774	24	52	issn	issn	PROPN
eurjchem-1774	24	53	2153	2153	NUM
eurjchem-1774	24	54	-	-	SYM
eurjchem-1774	24	55	2257	2257	NUM
eurjchem-1774	24	56	(	(	PUNCT
eurjchem-1774	24	57	online	online	ADJ
eurjchem-1774	24	58	)	)	PUNCT
eurjchem-1774	24	59	–	–	PUNCT
eurjchem-1774	25	1	copyright	copyright	NOUN
eurjchem-1774	25	2	©	©	PROPN
eurjchem-1774	25	3	2018	2018	NUM
eurjchem-1774	25	4	the	the	DET
eurjchem-1774	25	5	authors	author	NOUN
eurjchem-1774	25	6	–	–	PUNCT
eurjchem-1774	25	7	atlanta	atlanta	PROPN
eurjchem-1774	25	8	publishing	publishing	PROPN
eurjchem-1774	25	9	house	house	PROPN
eurjchem-1774	25	10	llc	llc	PROPN
eurjchem-1774	25	11	–	–	PUNCT
eurjchem-1774	25	12	printed	print	VERB
eurjchem-1774	25	13	in	in	ADP
eurjchem-1774	25	14	the	the	DET
eurjchem-1774	25	15	usa	usa	PROPN
eurjchem-1774	25	16	.	.	PUNCT
eurjchem-1774	26	1	this	this	DET
eurjchem-1774	26	2	work	work	NOUN
eurjchem-1774	26	3	is	be	AUX
eurjchem-1774	26	4	published	publish	VERB
eurjchem-1774	26	5	and	and	CCONJ
eurjchem-1774	26	6	licensed	license	VERB
eurjchem-1774	26	7	by	by	ADP
eurjchem-1774	26	8	atlanta	atlanta	PROPN
eurjchem-1774	26	9	publishing	publishing	PROPN
eurjchem-1774	26	10	house	house	PROPN
eurjchem-1774	26	11	llc	llc	PROPN
eurjchem-1774	26	12	–	–	PUNCT
eurjchem-1774	26	13	cc	cc	PROPN
eurjchem-1774	26	14	by	by	ADP
eurjchem-1774	26	15	nc	nc	PROPN
eurjchem-1774	26	16	–	–	PUNCT
eurjchem-1774	26	17	some	some	DET
eurjchem-1774	26	18	rights	right	NOUN
eurjchem-1774	26	19	reserved	reserve	VERB
eurjchem-1774	26	20	.	.	PUNCT
eurjchem-1774	27	1	http://dx.doi.org/10.5155/eurjchem.9.4.360-368.1774	http://dx.doi.org/10.5155/eurjchem.9.4.360-368.1774	NOUN
eurjchem-1774	27	2	http://dx.doi.org/10.5155/eurjchem.9.4.360-368.1774	http://dx.doi.org/10.5155/eurjchem.9.4.360-368.1774	NOUN
eurjchem-1774	27	3	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.4.360-368.1774&domain=pdf&date_stamp=2018-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.4.360-368.1774&domain=pdf&date_stamp=2018-12-31	NOUN
eurjchem-1774	27	4	http://www.eurjchem.com/	http://www.eurjchem.com/	VERB
eurjchem-1774	27	5	http://dx.doi.org/10.5155/eurjchem.9.4.360-368.1774	http://dx.doi.org/10.5155/eurjchem.9.4.360-368.1774	PROPN
eurjchem-1774	27	6	mailto:ebruuvacin@mersin.edu.tr	mailto:ebruuvacin@mersin.edu.tr	PROPN
eurjchem-1774	27	7	mailto:ummuhansolmaz@mersin.edu.tr	mailto:ummuhansolmaz@mersin.edu.tr	PROPN
eurjchem-1774	27	8	mailto:ilkay.gumus@mersin.edu.tr	mailto:ilkay.gumus@mersin.edu.tr	PROPN
eurjchem-1774	27	9	mailto:hakan.arslan@mersin.edu.tr	mailto:hakan.arslan@mersin.edu.tr	PROPN
eurjchem-1774	27	10	mailto:gunbinzet@mersin.edu.tr	mailto:gunbinzet@mersin.edu.tr	PROPN
eurjchem-1774	27	11	mailto:ilkay.gumus@mersin.edu.tr	mailto:ilkay.gumus@mersin.edu.tr	PROPN
eurjchem-1774	27	12	http://www.eurjchem.com/	http://www.eurjchem.com/	PROPN
eurjchem-1774	27	13	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.4.360-368.1774&domain=pdf&date_stamp=2018-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.9.4.360-368.1774&domain=pdf&date_stamp=2018-12-31	PROPN
eurjchem-1774	27	14	�	�	PROPN
eurjchem-1774	27	15	keskin	keskin	PROPN
eurjchem-1774	27	16	et	et	PROPN
eurjchem-1774	27	17	al	al	PROPN
eurjchem-1774	27	18	.	.	PUNCT
eurjchem-1774	27	19	/	/	SYM
eurjchem-1774	27	20	european	european	PROPN
eurjchem-1774	27	21	journal	journal	PROPN
eurjchem-1774	27	22	of	of	ADP
eurjchem-1774	27	23	chemistry	chemistry	NOUN
eurjchem-1774	27	24	9	9	NUM
eurjchem-1774	27	25	(	(	PUNCT
eurjchem-1774	27	26	4	4	NUM
eurjchem-1774	27	27	)	)	PUNCT
eurjchem-1774	27	28	(	(	PUNCT
eurjchem-1774	27	29	2018	2018	NUM
eurjchem-1774	27	30	)	)	PUNCT
eurjchem-1774	27	31	360	360	NUM
eurjchem-1774	27	32	-	-	SYM
eurjchem-1774	27	33	368	368	NUM
eurjchem-1774	27	34	361	361	NUM
eurjchem-1774	27	35	scheme	scheme	NOUN
eurjchem-1774	27	36	1	1	NUM
eurjchem-1774	27	37	.	.	PUNCT
eurjchem-1774	28	1	synthesis	synthesis	NOUN
eurjchem-1774	28	2	of	of	ADP
eurjchem-1774	28	3	thiourea	thiourea	NOUN
eurjchem-1774	28	4	ligands	ligand	NOUN
eurjchem-1774	28	5	.	.	PUNCT
eurjchem-1774	29	1	carbamothioyl)-4	carbamothioyl)-4	VERB
eurjchem-1774	29	2	-	-	PUNCT
eurjchem-1774	29	3	bromobenzamide	bromobenzamide	NOUN
eurjchem-1774	29	4	(	(	PUNCT
eurjchem-1774	29	5	hl2	hl2	NOUN
eurjchem-1774	29	6	)	)	PUNCT
eurjchem-1774	29	7	)	)	PUNCT
eurjchem-1774	29	8	and	and	CCONJ
eurjchem-1774	29	9	their	their	PRON
eurjchem-1774	29	10	platinum	platinum	NOUN
eurjchem-1774	29	11	complexes	complex	NOUN
eurjchem-1774	29	12	(	(	PUNCT
eurjchem-1774	29	13	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	29	14	-	-	PUNCT
eurjchem-1774	29	15	s	s	PROPN
eurjchem-1774	29	16	,	,	PUNCT
eurjchem-1774	29	17	o)2	o)2	PROPN
eurjchem-1774	29	18	]	]	PUNCT
eurjchem-1774	29	19	and	and	CCONJ
eurjchem-1774	29	20	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	29	21	-	-	PUNCT
eurjchem-1774	29	22	s	s	PROPN
eurjchem-1774	29	23	,	,	PUNCT
eurjchem-1774	29	24	o)2	o)2	NUM
eurjchem-1774	29	25	)	)	PUNCT
eurjchem-1774	29	26	.	.	PUNCT
eurjchem-1774	30	1	conformational	conformational	ADJ
eurjchem-1774	30	2	properties	property	NOUN
eurjchem-1774	30	3	of	of	ADP
eurjchem-1774	30	4	synthesized	synthesize	VERB
eurjchem-1774	30	5	complexes	complex	NOUN
eurjchem-1774	30	6	have	have	AUX
eurjchem-1774	30	7	also	also	ADV
eurjchem-1774	30	8	been	be	AUX
eurjchem-1774	30	9	investigated	investigate	VERB
eurjchem-1774	30	10	by	by	ADP
eurjchem-1774	30	11	intermolecular	intermolecular	ADJ
eurjchem-1774	30	12	contacts	contact	NOUN
eurjchem-1774	30	13	obtained	obtain	VERB
eurjchem-1774	30	14	from	from	ADP
eurjchem-1774	30	15	x	x	ADJ
eurjchem-1774	30	16	-	-	NOUN
eurjchem-1774	30	17	ray	ray	ADJ
eurjchem-1774	30	18	single	single	ADJ
eurjchem-1774	30	19	crystal	crystal	PROPN
eurjchem-1774	30	20	diffraction	diffraction	NOUN
eurjchem-1774	30	21	study	study	NOUN
eurjchem-1774	30	22	.	.	PUNCT
eurjchem-1774	31	1	2	2	X
eurjchem-1774	31	2	.	.	X
eurjchem-1774	31	3	experimental	experimental	ADJ
eurjchem-1774	31	4	2.1	2.1	NUM
eurjchem-1774	31	5	.	.	PUNCT
eurjchem-1774	32	1	instrumentation	instrumentation	NOUN
eurjchem-1774	32	2	infrared	infrared	PROPN
eurjchem-1774	32	3	measurement	measurement	PROPN
eurjchem-1774	32	4	was	be	AUX
eurjchem-1774	32	5	recorded	record	VERB
eurjchem-1774	32	6	in	in	ADP
eurjchem-1774	32	7	the	the	DET
eurjchem-1774	32	8	range	range	NOUN
eurjchem-1774	32	9	4004000	4004000	NUM
eurjchem-1774	32	10	cm−1	cm−1	NOUN
eurjchem-1774	32	11	on	on	ADP
eurjchem-1774	32	12	a	a	DET
eurjchem-1774	32	13	perkin	perkin	PROPN
eurjchem-1774	32	14	elmer	elmer	PROPN
eurjchem-1774	32	15	spectrum	spectrum	PROPN
eurjchem-1774	32	16	100	100	NUM
eurjchem-1774	32	17	series	series	PROPN
eurjchem-1774	32	18	ftir	ftir	PROPN
eurjchem-1774	32	19	/	/	SYM
eurjchem-1774	32	20	fir	fir	PROPN
eurjchem-1774	32	21	/	/	SYM
eurjchem-1774	32	22	nir	nir	ADJ
eurjchem-1774	32	23	spectrometer	spectrometer	NOUN
eurjchem-1774	32	24	frontier	frontier	NOUN
eurjchem-1774	32	25	,	,	PUNCT
eurjchem-1774	32	26	atr	atr	PROPN
eurjchem-1774	32	27	instrument	instrument	NOUN
eurjchem-1774	32	28	.	.	PUNCT
eurjchem-1774	33	1	the	the	DET
eurjchem-1774	33	2	nmr	nmr	NOUN
eurjchem-1774	33	3	spectra	spectra	NOUN
eurjchem-1774	33	4	were	be	AUX
eurjchem-1774	33	5	recorded	record	VERB
eurjchem-1774	33	6	in	in	ADP
eurjchem-1774	33	7	cdcl3	cdcl3	NOUN
eurjchem-1774	33	8	solvent	solvent	NOUN
eurjchem-1774	33	9	on	on	ADP
eurjchem-1774	33	10	bruker	bruker	PROPN
eurjchem-1774	33	11	avance	avance	PROPN
eurjchem-1774	33	12	iii	iii	PROPN
eurjchem-1774	33	13	400	400	NUM
eurjchem-1774	33	14	mhz	mhz	NOUN
eurjchem-1774	33	15	nanobay	nanobay	NOUN
eurjchem-1774	33	16	ft	ft	NOUN
eurjchem-1774	33	17	-	-	PUNCT
eurjchem-1774	33	18	nmr	nmr	NOUN
eurjchem-1774	33	19	spectrophotometer	spectrophotometer	NOUN
eurjchem-1774	33	20	using	use	VERB
eurjchem-1774	33	21	tetramethylsilane	tetramethylsilane	NOUN
eurjchem-1774	33	22	as	as	ADP
eurjchem-1774	33	23	an	an	DET
eurjchem-1774	33	24	internal	internal	ADJ
eurjchem-1774	33	25	standard	standard	NOUN
eurjchem-1774	33	26	.	.	PUNCT
eurjchem-1774	34	1	the	the	DET
eurjchem-1774	34	2	x	x	ADJ
eurjchem-1774	34	3	-	-	NOUN
eurjchem-1774	34	4	ray	ray	NOUN
eurjchem-1774	34	5	diffraction	diffraction	NOUN
eurjchem-1774	34	6	data	datum	NOUN
eurjchem-1774	34	7	were	be	AUX
eurjchem-1774	34	8	recorded	record	VERB
eurjchem-1774	34	9	on	on	ADP
eurjchem-1774	34	10	a	a	DET
eurjchem-1774	34	11	bruker	bruker	PROPN
eurjchem-1774	34	12	apex	apex	PROPN
eurjchem-1774	34	13	-	-	PUNCT
eurjchem-1774	34	14	ii	ii	PROPN
eurjchem-1774	34	15	ccd	ccd	PROPN
eurjchem-1774	34	16	diffractometer	diffractometer	NOUN
eurjchem-1774	34	17	.	.	PUNCT
eurjchem-1774	35	1	a	a	DET
eurjchem-1774	35	2	suitable	suitable	ADJ
eurjchem-1774	35	3	crystal	crystal	NOUN
eurjchem-1774	35	4	was	be	AUX
eurjchem-1774	35	5	selected	select	VERB
eurjchem-1774	35	6	and	and	CCONJ
eurjchem-1774	35	7	coated	coat	VERB
eurjchem-1774	35	8	with	with	ADP
eurjchem-1774	35	9	paratone	paratone	NOUN
eurjchem-1774	35	10	oil	oil	NOUN
eurjchem-1774	35	11	and	and	CCONJ
eurjchem-1774	35	12	mounted	mount	VERB
eurjchem-1774	35	13	on	on	ADP
eurjchem-1774	35	14	a	a	DET
eurjchem-1774	35	15	nylon	nylon	NOUN
eurjchem-1774	35	16	loop	loop	NOUN
eurjchem-1774	35	17	on	on	ADP
eurjchem-1774	35	18	a	a	DET
eurjchem-1774	35	19	bruker	bruker	PROPN
eurjchem-1774	35	20	apex	apex	PROPN
eurjchem-1774	35	21	-	-	PUNCT
eurjchem-1774	35	22	ii	ii	PROPN
eurjchem-1774	35	23	ccd	ccd	PROPN
eurjchem-1774	35	24	diffractometer	diffractometer	NOUN
eurjchem-1774	35	25	.	.	PUNCT
eurjchem-1774	36	1	the	the	DET
eurjchem-1774	36	2	crystal	crystal	NOUN
eurjchem-1774	36	3	was	be	AUX
eurjchem-1774	36	4	kept	keep	VERB
eurjchem-1774	36	5	at	at	ADP
eurjchem-1774	36	6	t	t	NOUN
eurjchem-1774	36	7	=	=	SYM
eurjchem-1774	36	8	100	100	NUM
eurjchem-1774	36	9	k	k	NOUN
eurjchem-1774	36	10	during	during	ADP
eurjchem-1774	36	11	data	data	NOUN
eurjchem-1774	36	12	collection	collection	NOUN
eurjchem-1774	36	13	.	.	PUNCT
eurjchem-1774	37	1	the	the	DET
eurjchem-1774	37	2	data	datum	NOUN
eurjchem-1774	37	3	were	be	AUX
eurjchem-1774	37	4	collected	collect	VERB
eurjchem-1774	37	5	with	with	ADP
eurjchem-1774	37	6	mokα	mokα	ADJ
eurjchem-1774	37	7	(	(	PUNCT
eurjchem-1774	37	8	λ	λ	SYM
eurjchem-1774	37	9	=	=	SYM
eurjchem-1774	37	10	0.71073	0.71073	NUM
eurjchem-1774	37	11	å	å	NOUN
eurjchem-1774	37	12	)	)	PUNCT
eurjchem-1774	37	13	radiation	radiation	NOUN
eurjchem-1774	37	14	at	at	ADP
eurjchem-1774	37	15	a	a	DET
eurjchem-1774	37	16	crystal	crystal	NOUN
eurjchem-1774	37	17	-	-	PUNCT
eurjchem-1774	37	18	to	to	ADP
eurjchem-1774	37	19	-	-	PUNCT
eurjchem-1774	37	20	detector	detector	NOUN
eurjchem-1774	37	21	distance	distance	NOUN
eurjchem-1774	37	22	of	of	ADP
eurjchem-1774	37	23	40	40	NUM
eurjchem-1774	37	24	mm	mm	NOUN
eurjchem-1774	37	25	.	.	PUNCT
eurjchem-1774	38	1	using	use	VERB
eurjchem-1774	38	2	olex2	olex2	PROPN
eurjchem-1774	39	1	[	[	X
eurjchem-1774	39	2	33	33	NUM
eurjchem-1774	39	3	]	]	PUNCT
eurjchem-1774	39	4	,	,	PUNCT
eurjchem-1774	39	5	the	the	DET
eurjchem-1774	39	6	structure	structure	NOUN
eurjchem-1774	39	7	was	be	AUX
eurjchem-1774	39	8	solved	solve	VERB
eurjchem-1774	39	9	with	with	ADP
eurjchem-1774	39	10	the	the	DET
eurjchem-1774	39	11	superflip	superflip	NOUN
eurjchem-1774	39	12	[	[	X
eurjchem-1774	39	13	34	34	NUM
eurjchem-1774	39	14	-	-	SYM
eurjchem-1774	39	15	36	36	NUM
eurjchem-1774	39	16	]	]	PUNCT
eurjchem-1774	39	17	structure	structure	NOUN
eurjchem-1774	39	18	solution	solution	NOUN
eurjchem-1774	39	19	program	program	NOUN
eurjchem-1774	39	20	,	,	PUNCT
eurjchem-1774	39	21	using	use	VERB
eurjchem-1774	39	22	the	the	DET
eurjchem-1774	39	23	charge	charge	NOUN
eurjchem-1774	39	24	flipping	flipping	NOUN
eurjchem-1774	39	25	solution	solution	NOUN
eurjchem-1774	39	26	method	method	NOUN
eurjchem-1774	39	27	and	and	CCONJ
eurjchem-1774	39	28	refined	refine	VERB
eurjchem-1774	39	29	by	by	ADP
eurjchem-1774	39	30	full	full	ADJ
eurjchem-1774	39	31	-	-	PUNCT
eurjchem-1774	39	32	matrix	matrix	NOUN
eurjchem-1774	39	33	least	least	ADJ
eurjchem-1774	39	34	-	-	PUNCT
eurjchem-1774	39	35	squares	square	NOUN
eurjchem-1774	39	36	techniques	technique	NOUN
eurjchem-1774	39	37	on	on	ADP
eurjchem-1774	39	38	f2	f2	PROPN
eurjchem-1774	39	39	using	use	VERB
eurjchem-1774	39	40	shelxl	shelxl	NOUN
eurjchem-1774	39	41	[	[	X
eurjchem-1774	39	42	37	37	NUM
eurjchem-1774	39	43	]	]	PUNCT
eurjchem-1774	39	44	with	with	ADP
eurjchem-1774	39	45	refinement	refinement	NOUN
eurjchem-1774	39	46	of	of	ADP
eurjchem-1774	39	47	f2	f2	PROPN
eurjchem-1774	39	48	against	against	ADP
eurjchem-1774	39	49	all	all	DET
eurjchem-1774	39	50	reflections	reflection	NOUN
eurjchem-1774	39	51	.	.	PUNCT
eurjchem-1774	40	1	hydrogen	hydrogen	NOUN
eurjchem-1774	40	2	atoms	atom	NOUN
eurjchem-1774	40	3	were	be	AUX
eurjchem-1774	40	4	constrained	constrain	VERB
eurjchem-1774	40	5	by	by	ADP
eurjchem-1774	40	6	difference	difference	NOUN
eurjchem-1774	40	7	maps	map	NOUN
eurjchem-1774	40	8	and	and	CCONJ
eurjchem-1774	40	9	were	be	AUX
eurjchem-1774	40	10	refined	refine	VERB
eurjchem-1774	40	11	isotropically	isotropically	ADV
eurjchem-1774	40	12	,	,	PUNCT
eurjchem-1774	40	13	and	and	CCONJ
eurjchem-1774	40	14	all	all	DET
eurjchem-1774	40	15	non	non	ADJ
eurjchem-1774	40	16	-	-	ADJ
eurjchem-1774	40	17	hydrogen	hydrogen	ADJ
eurjchem-1774	40	18	atoms	atom	NOUN
eurjchem-1774	40	19	were	be	AUX
eurjchem-1774	40	20	refined	refine	VERB
eurjchem-1774	40	21	anisotropically	anisotropically	ADV
eurjchem-1774	40	22	.	.	PUNCT
eurjchem-1774	41	1	2.2	2.2	NUM
eurjchem-1774	41	2	.	.	PUNCT
eurjchem-1774	41	3	reagents	reagent	NOUN
eurjchem-1774	41	4	potassium	potassium	NOUN
eurjchem-1774	41	5	thiocyanate	thiocyanate	NOUN
eurjchem-1774	41	6	,	,	PUNCT
eurjchem-1774	41	7	4	4	NUM
eurjchem-1774	41	8	-	-	PUNCT
eurjchem-1774	41	9	fluorobenzoyl	fluorobenzoyl	NOUN
eurjchem-1774	41	10	chloride	chloride	NOUN
eurjchem-1774	41	11	and	and	CCONJ
eurjchem-1774	41	12	4bromobenzoylchloride	4bromobenzoylchloride	NUM
eurjchem-1774	41	13	were	be	AUX
eurjchem-1774	41	14	purchased	purchase	VERB
eurjchem-1774	41	15	from	from	ADP
eurjchem-1774	41	16	merck	merck	PROPN
eurjchem-1774	41	17	and	and	CCONJ
eurjchem-1774	41	18	used	use	VERB
eurjchem-1774	41	19	as	as	SCONJ
eurjchem-1774	41	20	received	receive	VERB
eurjchem-1774	41	21	.	.	PUNCT
eurjchem-1774	42	1	all	all	DET
eurjchem-1774	42	2	other	other	ADJ
eurjchem-1774	42	3	chemicals	chemical	NOUN
eurjchem-1774	42	4	and	and	CCONJ
eurjchem-1774	42	5	solvents	solvent	NOUN
eurjchem-1774	42	6	were	be	AUX
eurjchem-1774	42	7	obtained	obtain	VERB
eurjchem-1774	42	8	from	from	ADP
eurjchem-1774	42	9	commercial	commercial	ADJ
eurjchem-1774	42	10	suppliers	supplier	NOUN
eurjchem-1774	42	11	and	and	CCONJ
eurjchem-1774	42	12	used	use	VERB
eurjchem-1774	42	13	without	without	ADP
eurjchem-1774	42	14	further	further	ADJ
eurjchem-1774	42	15	purifycation	purifycation	NOUN
eurjchem-1774	42	16	.	.	PUNCT
eurjchem-1774	43	1	2.3	2.3	NUM
eurjchem-1774	43	2	.	.	PUNCT
eurjchem-1774	43	3	synthesis	synthesis	NOUN
eurjchem-1774	43	4	and	and	CCONJ
eurjchem-1774	43	5	characterization	characterization	NOUN
eurjchem-1774	43	6	2.3.1	2.3.1	NUM
eurjchem-1774	43	7	.	.	PUNCT
eurjchem-1774	43	8	general	general	ADJ
eurjchem-1774	43	9	procedure	procedure	NOUN
eurjchem-1774	43	10	for	for	ADP
eurjchem-1774	43	11	the	the	DET
eurjchem-1774	43	12	synthesis	synthesis	NOUN
eurjchem-1774	43	13	of	of	ADP
eurjchem-1774	43	14	ligands	ligand	NOUN
eurjchem-1774	43	15	(	(	PUNCT
eurjchem-1774	43	16	hl1,2	hl1,2	NOUN
eurjchem-1774	43	17	)	)	PUNCT
eurjchem-1774	43	18	hl1,2	hl1,2	ADJ
eurjchem-1774	43	19	ligands	ligand	NOUN
eurjchem-1774	43	20	were	be	AUX
eurjchem-1774	43	21	prepared	prepare	VERB
eurjchem-1774	43	22	according	accord	VERB
eurjchem-1774	43	23	to	to	ADP
eurjchem-1774	43	24	previously	previously	ADV
eurjchem-1774	43	25	published	publish	VERB
eurjchem-1774	43	26	methods	method	NOUN
eurjchem-1774	43	27	[	[	PUNCT
eurjchem-1774	43	28	38	38	NUM
eurjchem-1774	43	29	-	-	SYM
eurjchem-1774	43	30	40	40	NUM
eurjchem-1774	43	31	]	]	PUNCT
eurjchem-1774	43	32	.	.	PUNCT
eurjchem-1774	44	1	a	a	DET
eurjchem-1774	44	2	solution	solution	NOUN
eurjchem-1774	44	3	of	of	ADP
eurjchem-1774	44	4	substituted	substitute	VERB
eurjchem-1774	44	5	benzoyl	benzoyl	NOUN
eurjchem-1774	44	6	chloride	chloride	NOUN
eurjchem-1774	44	7	(	(	PUNCT
eurjchem-1774	44	8	4	4	NUM
eurjchem-1774	44	9	-	-	PUNCT
eurjchem-1774	44	10	fluorobenzoyl	fluorobenzoyl	NOUN
eurjchem-1774	44	11	chloride	chloride	NOUN
eurjchem-1774	44	12	and	and	CCONJ
eurjchem-1774	44	13	4	4	NUM
eurjchem-1774	44	14	-	-	PUNCT
eurjchem-1774	44	15	bromobenzoyl	bromobenzoyl	VERB
eurjchem-1774	44	16	chloride	chloride	NOUN
eurjchem-1774	44	17	,	,	PUNCT
eurjchem-1774	44	18	5	5	NUM
eurjchem-1774	44	19	mmol	mmol	NOUN
eurjchem-1774	44	20	)	)	PUNCT
eurjchem-1774	44	21	in	in	ADP
eurjchem-1774	44	22	dry	dry	ADJ
eurjchem-1774	44	23	acetone	acetone	NOUN
eurjchem-1774	44	24	(	(	PUNCT
eurjchem-1774	44	25	50	50	NUM
eurjchem-1774	44	26	ml	ml	NOUN
eurjchem-1774	44	27	)	)	PUNCT
eurjchem-1774	44	28	was	be	AUX
eurjchem-1774	44	29	added	add	VERB
eurjchem-1774	44	30	dropwise	dropwise	NOUN
eurjchem-1774	44	31	to	to	ADP
eurjchem-1774	44	32	a	a	DET
eurjchem-1774	44	33	suspension	suspension	NOUN
eurjchem-1774	44	34	of	of	ADP
eurjchem-1774	44	35	potassium	potassium	NOUN
eurjchem-1774	44	36	thiocyanate	thiocyanate	NOUN
eurjchem-1774	44	37	(	(	PUNCT
eurjchem-1774	44	38	5	5	NUM
eurjchem-1774	44	39	mmol	mmol	NOUN
eurjchem-1774	44	40	,	,	PUNCT
eurjchem-1774	44	41	0.490	0.490	NUM
eurjchem-1774	44	42	g	g	NOUN
eurjchem-1774	44	43	)	)	PUNCT
eurjchem-1774	44	44	in	in	ADP
eurjchem-1774	44	45	acetone	acetone	NOUN
eurjchem-1774	44	46	(	(	PUNCT
eurjchem-1774	44	47	30	30	NUM
eurjchem-1774	44	48	ml	ml	NOUN
eurjchem-1774	44	49	)	)	PUNCT
eurjchem-1774	44	50	.	.	PUNCT
eurjchem-1774	45	1	the	the	DET
eurjchem-1774	45	2	reaction	reaction	NOUN
eurjchem-1774	45	3	mixture	mixture	NOUN
eurjchem-1774	45	4	was	be	AUX
eurjchem-1774	45	5	heated	heat	VERB
eurjchem-1774	45	6	under	under	ADP
eurjchem-1774	45	7	reflux	reflux	NOUN
eurjchem-1774	45	8	for	for	ADP
eurjchem-1774	45	9	30	30	NUM
eurjchem-1774	45	10	min	min	NOUN
eurjchem-1774	45	11	and	and	CCONJ
eurjchem-1774	45	12	then	then	ADV
eurjchem-1774	45	13	cooled	cool	VERB
eurjchem-1774	45	14	to	to	ADP
eurjchem-1774	45	15	room	room	NOUN
eurjchem-1774	45	16	temperature	temperature	NOUN
eurjchem-1774	45	17	.	.	PUNCT
eurjchem-1774	46	1	a	a	DET
eurjchem-1774	46	2	solution	solution	NOUN
eurjchem-1774	46	3	of	of	ADP
eurjchem-1774	46	4	di	di	NOUN
eurjchem-1774	46	5	-	-	PUNCT
eurjchem-1774	46	6	n	n	CCONJ
eurjchem-1774	46	7	-	-	PUNCT
eurjchem-1774	46	8	propylamine	propylamine	NOUN
eurjchem-1774	46	9	(	(	PUNCT
eurjchem-1774	46	10	5	5	NUM
eurjchem-1774	46	11	mmol	mmol	NOUN
eurjchem-1774	46	12	,	,	PUNCT
eurjchem-1774	46	13	0.54	0.54	NUM
eurjchem-1774	46	14	g	g	NOUN
eurjchem-1774	46	15	)	)	PUNCT
eurjchem-1774	46	16	was	be	AUX
eurjchem-1774	46	17	added	add	VERB
eurjchem-1774	46	18	and	and	CCONJ
eurjchem-1774	46	19	the	the	DET
eurjchem-1774	46	20	resulting	result	VERB
eurjchem-1774	46	21	mixture	mixture	NOUN
eurjchem-1774	46	22	was	be	AUX
eurjchem-1774	46	23	stirred	stir	VERB
eurjchem-1774	46	24	for	for	ADP
eurjchem-1774	46	25	2	2	NUM
eurjchem-1774	46	26	h.	h.	NOUN
eurjchem-1774	46	27	after	after	ADP
eurjchem-1774	46	28	that	that	PRON
eurjchem-1774	46	29	,	,	PUNCT
eurjchem-1774	46	30	the	the	DET
eurjchem-1774	46	31	reaction	reaction	NOUN
eurjchem-1774	46	32	mixture	mixture	NOUN
eurjchem-1774	46	33	was	be	AUX
eurjchem-1774	46	34	poured	pour	VERB
eurjchem-1774	46	35	into	into	ADP
eurjchem-1774	46	36	hydrochloric	hydrochloric	ADJ
eurjchem-1774	46	37	acid	acid	NOUN
eurjchem-1774	46	38	(	(	PUNCT
eurjchem-1774	46	39	0.1	0.1	NUM
eurjchem-1774	46	40	m	m	NOUN
eurjchem-1774	46	41	,	,	PUNCT
eurjchem-1774	46	42	300	300	NUM
eurjchem-1774	46	43	ml	ml	NOUN
eurjchem-1774	46	44	)	)	PUNCT
eurjchem-1774	46	45	,	,	PUNCT
eurjchem-1774	46	46	and	and	CCONJ
eurjchem-1774	46	47	the	the	DET
eurjchem-1774	46	48	solution	solution	NOUN
eurjchem-1774	46	49	was	be	AUX
eurjchem-1774	46	50	filtered	filter	VERB
eurjchem-1774	46	51	.	.	PUNCT
eurjchem-1774	47	1	the	the	DET
eurjchem-1774	47	2	solid	solid	ADJ
eurjchem-1774	47	3	product	product	NOUN
eurjchem-1774	47	4	was	be	AUX
eurjchem-1774	47	5	washed	wash	VERB
eurjchem-1774	47	6	with	with	ADP
eurjchem-1774	47	7	water	water	NOUN
eurjchem-1774	47	8	and	and	CCONJ
eurjchem-1774	47	9	purified	purify	VERB
eurjchem-1774	47	10	by	by	ADP
eurjchem-1774	47	11	recrystallization	recrystallization	NOUN
eurjchem-1774	47	12	from	from	ADP
eurjchem-1774	47	13	an	an	DET
eurjchem-1774	47	14	ethanol	ethanol	NOUN
eurjchem-1774	47	15	:	:	PUNCT
eurjchem-1774	47	16	dichloromethane	dichloromethane	NOUN
eurjchem-1774	47	17	mixture	mixture	NOUN
eurjchem-1774	47	18	(	(	PUNCT
eurjchem-1774	47	19	1:1	1:1	NUM
eurjchem-1774	47	20	,	,	PUNCT
eurjchem-1774	47	21	v	v	NOUN
eurjchem-1774	47	22	:	:	SYM
eurjchem-1774	47	23	v	v	NOUN
eurjchem-1774	47	24	)	)	PUNCT
eurjchem-1774	47	25	(	(	PUNCT
eurjchem-1774	47	26	scheme	scheme	NOUN
eurjchem-1774	47	27	1	1	NUM
eurjchem-1774	47	28	)	)	PUNCT
eurjchem-1774	47	29	.	.	PUNCT
eurjchem-1774	48	1	n-(di	n-(di	PROPN
eurjchem-1774	48	2	-	-	PUNCT
eurjchem-1774	48	3	n	n	CCONJ
eurjchem-1774	48	4	-	-	PUNCT
eurjchem-1774	48	5	propylcarbamothioyl)-4	propylcarbamothioyl)-4	VERB
eurjchem-1774	48	6	-	-	PUNCT
eurjchem-1774	48	7	fluorobenzamide	fluorobenzamide	NOUN
eurjchem-1774	48	8	(	(	PUNCT
eurjchem-1774	48	9	hl1	hl1	NOUN
eurjchem-1774	48	10	):	):	PUNCT
eurjchem-1774	48	11	colour	colour	NOUN
eurjchem-1774	48	12	:	:	PUNCT
eurjchem-1774	48	13	white	white	ADJ
eurjchem-1774	48	14	.	.	PUNCT
eurjchem-1774	49	1	yield	yield	NOUN
eurjchem-1774	49	2	:	:	PUNCT
eurjchem-1774	50	1	%	%	NOUN
eurjchem-1774	50	2	70	70	NUM
eurjchem-1774	50	3	.	.	PUNCT
eurjchem-1774	51	1	ft	ft	PROPN
eurjchem-1774	51	2	-	-	PUNCT
eurjchem-1774	51	3	ir	ir	PROPN
eurjchem-1774	51	4	(	(	PUNCT
eurjchem-1774	51	5	atr	atr	PROPN
eurjchem-1774	51	6	,	,	PUNCT
eurjchem-1774	51	7	ν	ν	NOUN
eurjchem-1774	51	8	,	,	PUNCT
eurjchem-1774	51	9	cm-1	cm-1	NUM
eurjchem-1774	51	10	):	):	PUNCT
eurjchem-1774	51	11	3271	3271	NUM
eurjchem-1774	51	12	(	(	PUNCT
eurjchem-1774	51	13	nh	nh	NOUN
eurjchem-1774	51	14	)	)	PUNCT
eurjchem-1774	51	15	,	,	PUNCT
eurjchem-1774	51	16	2968	2968	NUM
eurjchem-1774	51	17	,	,	PUNCT
eurjchem-1774	51	18	2934	2934	NUM
eurjchem-1774	51	19	,	,	PUNCT
eurjchem-1774	51	20	2877	2877	NUM
eurjchem-1774	51	21	(	(	PUNCT
eurjchem-1774	51	22	ch	ch	NOUN
eurjchem-1774	51	23	)	)	PUNCT
eurjchem-1774	51	24	,	,	PUNCT
eurjchem-1774	51	25	1643	1643	NUM
eurjchem-1774	51	26	(	(	PUNCT
eurjchem-1774	51	27	c	c	NOUN
eurjchem-1774	51	28	=	=	NOUN
eurjchem-1774	51	29	o	o	NOUN
eurjchem-1774	51	30	)	)	PUNCT
eurjchem-1774	51	31	,	,	PUNCT
eurjchem-1774	51	32	1275	1275	NUM
eurjchem-1774	51	33	(	(	PUNCT
eurjchem-1774	51	34	c	c	NOUN
eurjchem-1774	51	35	=	=	SYM
eurjchem-1774	51	36	s	s	NOUN
eurjchem-1774	51	37	)	)	PUNCT
eurjchem-1774	51	38	,	,	PUNCT
eurjchem-1774	51	39	753	753	NUM
eurjchem-1774	51	40	(	(	PUNCT
eurjchem-1774	51	41	c	c	NOUN
eurjchem-1774	51	42	-	-	SYM
eurjchem-1774	51	43	f	f	NOUN
eurjchem-1774	51	44	)	)	PUNCT
eurjchem-1774	51	45	.	.	PUNCT
eurjchem-1774	52	1	1h	1h	NUM
eurjchem-1774	52	2	nmr	nmr	NOUN
eurjchem-1774	52	3	(	(	PUNCT
eurjchem-1774	52	4	400	400	NUM
eurjchem-1774	52	5	mhz	mhz	NOUN
eurjchem-1774	52	6	,	,	PUNCT
eurjchem-1774	52	7	cdcl3	cdcl3	PROPN
eurjchem-1774	52	8	,	,	PUNCT
eurjchem-1774	52	9	δ	δ	PROPN
eurjchem-1774	52	10	,	,	PUNCT
eurjchem-1774	52	11	ppm	ppm	NUM
eurjchem-1774	52	12	):	):	PUNCT
eurjchem-1774	52	13	8.42	8.42	NUM
eurjchem-1774	52	14	(	(	PUNCT
eurjchem-1774	52	15	s	s	PROPN
eurjchem-1774	52	16	,	,	PUNCT
eurjchem-1774	52	17	1h	1h	NUM
eurjchem-1774	52	18	,	,	PUNCT
eurjchem-1774	52	19	nh	nh	PROPN
eurjchem-1774	52	20	)	)	PUNCT
eurjchem-1774	52	21	,	,	PUNCT
eurjchem-1774	52	22	7.86	7.86	NUM
eurjchem-1774	52	23	(	(	PUNCT
eurjchem-1774	52	24	d	d	NOUN
eurjchem-1774	52	25	,	,	PUNCT
eurjchem-1774	52	26	2h	2h	NUM
eurjchem-1774	52	27	,	,	PUNCT
eurjchem-1774	52	28	ar	ar	NOUN
eurjchem-1774	52	29	-	-	NOUN
eurjchem-1774	52	30	h	h	NOUN
eurjchem-1774	52	31	)	)	PUNCT
eurjchem-1774	52	32	,	,	PUNCT
eurjchem-1774	52	33	7.15	7.15	NUM
eurjchem-1774	52	34	(	(	PUNCT
eurjchem-1774	52	35	d	d	PROPN
eurjchem-1774	52	36	,	,	PUNCT
eurjchem-1774	52	37	2h	2h	NUM
eurjchem-1774	52	38	,	,	PUNCT
eurjchem-1774	52	39	ar	ar	NOUN
eurjchem-1774	52	40	-	-	NOUN
eurjchem-1774	52	41	h	h	NOUN
eurjchem-1774	52	42	)	)	PUNCT
eurjchem-1774	52	43	,	,	PUNCT
eurjchem-1774	52	44	3.92	3.92	NUM
eurjchem-1774	52	45	(	(	PUNCT
eurjchem-1774	52	46	t	t	PROPN
eurjchem-1774	52	47	,	,	PUNCT
eurjchem-1774	52	48	2h	2h	NUM
eurjchem-1774	52	49	,	,	PUNCT
eurjchem-1774	52	50	n	n	CCONJ
eurjchem-1774	52	51	-	-	PUNCT
eurjchem-1774	52	52	ch2	ch2	NOUN
eurjchem-1774	52	53	)	)	PUNCT
eurjchem-1774	52	54	,	,	PUNCT
eurjchem-1774	52	55	3.51	3.51	NUM
eurjchem-1774	52	56	(	(	PUNCT
eurjchem-1774	52	57	t	t	PROPN
eurjchem-1774	52	58	,	,	PUNCT
eurjchem-1774	52	59	2h	2h	NUM
eurjchem-1774	52	60	,	,	PUNCT
eurjchem-1774	52	61	nch2	nch2	PROPN
eurjchem-1774	52	62	)	)	PUNCT
eurjchem-1774	52	63	,	,	PUNCT
eurjchem-1774	52	64	1.83	1.83	NUM
eurjchem-1774	52	65	(	(	PUNCT
eurjchem-1774	52	66	m	m	PROPN
eurjchem-1774	52	67	,	,	PUNCT
eurjchem-1774	52	68	2h	2h	NUM
eurjchem-1774	52	69	,	,	PUNCT
eurjchem-1774	52	70	-ch2-	-ch2-	PRON
eurjchem-1774	52	71	)	)	PUNCT
eurjchem-1774	52	72	,	,	PUNCT
eurjchem-1774	52	73	1.71	1.71	NUM
eurjchem-1774	52	74	(	(	PUNCT
eurjchem-1774	52	75	m	m	PROPN
eurjchem-1774	52	76	,	,	PUNCT
eurjchem-1774	52	77	2h	2h	NUM
eurjchem-1774	52	78	,	,	PUNCT
eurjchem-1774	52	79	-ch2-	-ch2-	PRON
eurjchem-1774	52	80	)	)	PUNCT
eurjchem-1774	52	81	,	,	PUNCT
eurjchem-1774	52	82	1.02	1.02	NUM
eurjchem-1774	52	83	(	(	PUNCT
eurjchem-1774	52	84	t	t	PROPN
eurjchem-1774	52	85	,	,	PUNCT
eurjchem-1774	52	86	3h	3h	NUM
eurjchem-1774	52	87	,	,	PUNCT
eurjchem-1774	52	88	ch3	ch3	PROPN
eurjchem-1774	52	89	)	)	PUNCT
eurjchem-1774	52	90	,	,	PUNCT
eurjchem-1774	52	91	0.88	0.88	NUM
eurjchem-1774	52	92	(	(	PUNCT
eurjchem-1774	52	93	t	t	PROPN
eurjchem-1774	52	94	,	,	PUNCT
eurjchem-1774	52	95	3h	3h	NUM
eurjchem-1774	52	96	,	,	PUNCT
eurjchem-1774	52	97	ch3	ch3	PROPN
eurjchem-1774	52	98	)	)	PUNCT
eurjchem-1774	52	99	.	.	PUNCT
eurjchem-1774	53	1	13c	13c	NOUN
eurjchem-1774	53	2	nmr	nmr	NOUN
eurjchem-1774	53	3	(	(	PUNCT
eurjchem-1774	53	4	100	100	NUM
eurjchem-1774	53	5	mhz	mhz	NOUN
eurjchem-1774	53	6	,	,	PUNCT
eurjchem-1774	53	7	cdcl3	cdcl3	PROPN
eurjchem-1774	53	8	,	,	PUNCT
eurjchem-1774	53	9	δ	δ	PROPN
eurjchem-1774	53	10	,	,	PUNCT
eurjchem-1774	53	11	ppm	ppm	NOUN
eurjchem-1774	53	12	):	):	PUNCT
eurjchem-1774	53	13	180.10	180.10	NUM
eurjchem-1774	53	14	(	(	PUNCT
eurjchem-1774	53	15	c	c	NOUN
eurjchem-1774	53	16	=	=	SYM
eurjchem-1774	53	17	s	s	NOUN
eurjchem-1774	53	18	)	)	PUNCT
eurjchem-1774	53	19	,	,	PUNCT
eurjchem-1774	53	20	162.83	162.83	NUM
eurjchem-1774	53	21	(	(	PUNCT
eurjchem-1774	53	22	c	c	NOUN
eurjchem-1774	53	23	=	=	NOUN
eurjchem-1774	53	24	o	o	NOUN
eurjchem-1774	53	25	)	)	PUNCT
eurjchem-1774	53	26	,	,	PUNCT
eurjchem-1774	53	27	130.61	130.61	NUM
eurjchem-1774	53	28	(	(	PUNCT
eurjchem-1774	53	29	c	c	NOUN
eurjchem-1774	53	30	-	-	PUNCT
eurjchem-1774	53	31	ar	ar	NOUN
eurjchem-1774	53	32	)	)	PUNCT
eurjchem-1774	53	33	,	,	PUNCT
eurjchem-1774	53	34	130.52	130.52	NUM
eurjchem-1774	53	35	(	(	PUNCT
eurjchem-1774	53	36	c	c	NOUN
eurjchem-1774	53	37	-	-	PUNCT
eurjchem-1774	53	38	ar	ar	NOUN
eurjchem-1774	53	39	)	)	PUNCT
eurjchem-1774	53	40	,	,	PUNCT
eurjchem-1774	53	41	115.96	115.96	NUM
eurjchem-1774	53	42	(	(	PUNCT
eurjchem-1774	53	43	car	car	NOUN
eurjchem-1774	53	44	)	)	PUNCT
eurjchem-1774	53	45	,	,	PUNCT
eurjchem-1774	53	46	115.74	115.74	NUM
eurjchem-1774	53	47	(	(	PUNCT
eurjchem-1774	53	48	c	c	NOUN
eurjchem-1774	53	49	-	-	PUNCT
eurjchem-1774	53	50	ar	ar	NOUN
eurjchem-1774	53	51	)	)	PUNCT
eurjchem-1774	53	52	,	,	PUNCT
eurjchem-1774	53	53	54.99	54.99	NUM
eurjchem-1774	53	54	(	(	PUNCT
eurjchem-1774	53	55	c	c	NOUN
eurjchem-1774	53	56	-	-	PUNCT
eurjchem-1774	53	57	n	n	CCONJ
eurjchem-1774	53	58	)	)	PUNCT
eurjchem-1774	53	59	,	,	PUNCT
eurjchem-1774	53	60	54.89	54.89	NUM
eurjchem-1774	53	61	(	(	PUNCT
eurjchem-1774	53	62	cn	cn	PROPN
eurjchem-1774	53	63	)	)	PUNCT
eurjchem-1774	53	64	,	,	PUNCT
eurjchem-1774	53	65	21.46	21.46	NUM
eurjchem-1774	53	66	(	(	PUNCT
eurjchem-1774	53	67	ch2	ch2	PROPN
eurjchem-1774	53	68	)	)	PUNCT
eurjchem-1774	53	69	,	,	PUNCT
eurjchem-1774	53	70	19.73	19.73	NUM
eurjchem-1774	53	71	(	(	PUNCT
eurjchem-1774	53	72	ch2	ch2	PROPN
eurjchem-1774	53	73	)	)	PUNCT
eurjchem-1774	53	74	,	,	PUNCT
eurjchem-1774	53	75	11.31	11.31	NUM
eurjchem-1774	53	76	(	(	PUNCT
eurjchem-1774	53	77	ch3	ch3	PROPN
eurjchem-1774	53	78	)	)	PUNCT
eurjchem-1774	53	79	,	,	PUNCT
eurjchem-1774	53	80	11.27	11.27	NUM
eurjchem-1774	53	81	(	(	PUNCT
eurjchem-1774	53	82	ch3	ch3	PROPN
eurjchem-1774	53	83	)	)	PUNCT
eurjchem-1774	53	84	.	.	PUNCT
eurjchem-1774	54	1	n-(di	n-(di	PROPN
eurjchem-1774	54	2	-	-	PUNCT
eurjchem-1774	54	3	n	n	CCONJ
eurjchem-1774	54	4	-	-	PUNCT
eurjchem-1774	54	5	propylcarbamothioyl)-4	propylcarbamothioyl)-4	VERB
eurjchem-1774	54	6	-	-	PUNCT
eurjchem-1774	54	7	bromobenzamide	bromobenzamide	NOUN
eurjchem-1774	54	8	(	(	PUNCT
eurjchem-1774	54	9	hl2	hl2	NOUN
eurjchem-1774	54	10	):	):	PUNCT
eurjchem-1774	54	11	colour	colour	NOUN
eurjchem-1774	54	12	:	:	PUNCT
eurjchem-1774	54	13	white	white	ADJ
eurjchem-1774	54	14	.	.	PUNCT
eurjchem-1774	54	15	yield	yield	NOUN
eurjchem-1774	54	16	:	:	PUNCT
eurjchem-1774	54	17	%	%	NOUN
eurjchem-1774	54	18	88	88	NUM
eurjchem-1774	54	19	.	.	PUNCT
eurjchem-1774	55	1	ft	ft	PROPN
eurjchem-1774	55	2	-	-	PUNCT
eurjchem-1774	55	3	ir	ir	PROPN
eurjchem-1774	55	4	(	(	PUNCT
eurjchem-1774	55	5	atr	atr	PROPN
eurjchem-1774	55	6	,	,	PUNCT
eurjchem-1774	55	7	ν	ν	NOUN
eurjchem-1774	55	8	,	,	PUNCT
eurjchem-1774	55	9	cm-1	cm-1	NUM
eurjchem-1774	55	10	):	):	PUNCT
eurjchem-1774	55	11	3207	3207	NUM
eurjchem-1774	55	12	(	(	PUNCT
eurjchem-1774	55	13	nh	nh	NOUN
eurjchem-1774	55	14	)	)	PUNCT
eurjchem-1774	55	15	,	,	PUNCT
eurjchem-1774	55	16	2962	2962	NUM
eurjchem-1774	55	17	,	,	PUNCT
eurjchem-1774	55	18	2947	2947	NUM
eurjchem-1774	55	19	,	,	PUNCT
eurjchem-1774	55	20	2871	2871	NUM
eurjchem-1774	55	21	(	(	PUNCT
eurjchem-1774	55	22	ch	ch	NOUN
eurjchem-1774	55	23	)	)	PUNCT
eurjchem-1774	55	24	,	,	PUNCT
eurjchem-1774	55	25	1685	1685	NUM
eurjchem-1774	55	26	(	(	PUNCT
eurjchem-1774	55	27	c	c	NOUN
eurjchem-1774	55	28	=	=	NOUN
eurjchem-1774	55	29	o	o	NOUN
eurjchem-1774	55	30	)	)	PUNCT
eurjchem-1774	55	31	,	,	PUNCT
eurjchem-1774	55	32	1261	1261	NUM
eurjchem-1774	55	33	(	(	PUNCT
eurjchem-1774	55	34	c	c	NOUN
eurjchem-1774	55	35	=	=	SYM
eurjchem-1774	55	36	s	s	NOUN
eurjchem-1774	55	37	)	)	PUNCT
eurjchem-1774	55	38	,	,	PUNCT
eurjchem-1774	55	39	750	750	NUM
eurjchem-1774	55	40	(	(	PUNCT
eurjchem-1774	55	41	c	c	NOUN
eurjchem-1774	55	42	-	-	PUNCT
eurjchem-1774	55	43	br	br	NOUN
eurjchem-1774	55	44	)	)	PUNCT
eurjchem-1774	55	45	.	.	PUNCT
eurjchem-1774	56	1	1h	1h	NUM
eurjchem-1774	56	2	nmr	nmr	NOUN
eurjchem-1774	56	3	(	(	PUNCT
eurjchem-1774	56	4	400	400	NUM
eurjchem-1774	56	5	mhz	mhz	NOUN
eurjchem-1774	56	6	,	,	PUNCT
eurjchem-1774	56	7	cdcl3	cdcl3	PROPN
eurjchem-1774	56	8	,	,	PUNCT
eurjchem-1774	56	9	δ	δ	PROPN
eurjchem-1774	56	10	,	,	PUNCT
eurjchem-1774	56	11	ppm	ppm	NUM
eurjchem-1774	56	12	):	):	PUNCT
eurjchem-1774	56	13	8.38	8.38	NUM
eurjchem-1774	56	14	(	(	PUNCT
eurjchem-1774	56	15	s	s	PROPN
eurjchem-1774	56	16	,	,	PUNCT
eurjchem-1774	56	17	1h	1h	NUM
eurjchem-1774	56	18	,	,	PUNCT
eurjchem-1774	56	19	nh	nh	PROPN
eurjchem-1774	56	20	)	)	PUNCT
eurjchem-1774	56	21	,	,	PUNCT
eurjchem-1774	56	22	7.64	7.64	NUM
eurjchem-1774	56	23	(	(	PUNCT
eurjchem-1774	56	24	d	d	PROPN
eurjchem-1774	56	25	,	,	PUNCT
eurjchem-1774	56	26	2h	2h	NUM
eurjchem-1774	56	27	,	,	PUNCT
eurjchem-1774	56	28	ar	ar	NOUN
eurjchem-1774	56	29	-	-	NOUN
eurjchem-1774	56	30	h	h	NOUN
eurjchem-1774	56	31	)	)	PUNCT
eurjchem-1774	56	32	,	,	PUNCT
eurjchem-1774	56	33	7.62	7.62	NUM
eurjchem-1774	56	34	(	(	PUNCT
eurjchem-1774	56	35	d	d	NOUN
eurjchem-1774	56	36	,	,	PUNCT
eurjchem-1774	56	37	2h	2h	NUM
eurjchem-1774	56	38	,	,	PUNCT
eurjchem-1774	56	39	ar	ar	NOUN
eurjchem-1774	56	40	-	-	NOUN
eurjchem-1774	56	41	h	h	NOUN
eurjchem-1774	56	42	)	)	PUNCT
eurjchem-1774	56	43	,	,	PUNCT
eurjchem-1774	56	44	3.95	3.95	NUM
eurjchem-1774	56	45	(	(	PUNCT
eurjchem-1774	56	46	s	s	PROPN
eurjchem-1774	56	47	,	,	PUNCT
eurjchem-1774	56	48	2h	2h	NUM
eurjchem-1774	56	49	,	,	PUNCT
eurjchem-1774	56	50	n	n	CCONJ
eurjchem-1774	56	51	-	-	PUNCT
eurjchem-1774	56	52	ch2	ch2	NOUN
eurjchem-1774	56	53	)	)	PUNCT
eurjchem-1774	56	54	,	,	PUNCT
eurjchem-1774	56	55	3.50	3.50	NUM
eurjchem-1774	56	56	(	(	PUNCT
eurjchem-1774	56	57	s	s	PROPN
eurjchem-1774	56	58	,	,	PUNCT
eurjchem-1774	56	59	2h	2h	NUM
eurjchem-1774	56	60	,	,	PUNCT
eurjchem-1774	56	61	nch2	nch2	PROPN
eurjchem-1774	56	62	)	)	PUNCT
eurjchem-1774	56	63	,	,	PUNCT
eurjchem-1774	56	64	1.84	1.84	NUM
eurjchem-1774	56	65	(	(	PUNCT
eurjchem-1774	56	66	m	m	PROPN
eurjchem-1774	56	67	,	,	PUNCT
eurjchem-1774	56	68	2h	2h	NUM
eurjchem-1774	56	69	,	,	PUNCT
eurjchem-1774	56	70	-ch2-	-ch2-	PRON
eurjchem-1774	56	71	)	)	PUNCT
eurjchem-1774	56	72	,	,	PUNCT
eurjchem-1774	56	73	1.67	1.67	NUM
eurjchem-1774	56	74	(	(	PUNCT
eurjchem-1774	56	75	m	m	PROPN
eurjchem-1774	56	76	,	,	PUNCT
eurjchem-1774	56	77	2h	2h	NUM
eurjchem-1774	56	78	,	,	PUNCT
eurjchem-1774	56	79	-ch2-	-ch2-	PRON
eurjchem-1774	56	80	)	)	PUNCT
eurjchem-1774	56	81	,	,	PUNCT
eurjchem-1774	56	82	1.04	1.04	NUM
eurjchem-1774	56	83	(	(	PUNCT
eurjchem-1774	56	84	s	s	PROPN
eurjchem-1774	56	85	,	,	PUNCT
eurjchem-1774	56	86	3h	3h	NUM
eurjchem-1774	56	87	,	,	PUNCT
eurjchem-1774	56	88	ch3	ch3	PROPN
eurjchem-1774	56	89	)	)	PUNCT
eurjchem-1774	56	90	,	,	PUNCT
eurjchem-1774	56	91	0.91	0.91	NUM
eurjchem-1774	56	92	(	(	PUNCT
eurjchem-1774	56	93	s	s	PROPN
eurjchem-1774	56	94	,	,	PUNCT
eurjchem-1774	56	95	3h	3h	NUM
eurjchem-1774	56	96	,	,	PUNCT
eurjchem-1774	56	97	ch3	ch3	PROPN
eurjchem-1774	56	98	)	)	PUNCT
eurjchem-1774	56	99	.	.	PUNCT
eurjchem-1774	57	1	13c	13c	NOUN
eurjchem-1774	57	2	nmr	nmr	NOUN
eurjchem-1774	57	3	(	(	PUNCT
eurjchem-1774	57	4	100	100	NUM
eurjchem-1774	57	5	mhz	mhz	NOUN
eurjchem-1774	57	6	,	,	PUNCT
eurjchem-1774	57	7	cdcl3	cdcl3	PROPN
eurjchem-1774	57	8	,	,	PUNCT
eurjchem-1774	57	9	δ	δ	PROPN
eurjchem-1774	57	10	,	,	PUNCT
eurjchem-1774	57	11	ppm	ppm	NOUN
eurjchem-1774	57	12	):	):	PUNCT
eurjchem-1774	57	13	179.88	179.88	NUM
eurjchem-1774	57	14	(	(	PUNCT
eurjchem-1774	57	15	c	c	NOUN
eurjchem-1774	57	16	=	=	SYM
eurjchem-1774	57	17	s	s	NOUN
eurjchem-1774	57	18	)	)	PUNCT
eurjchem-1774	57	19	,	,	PUNCT
eurjchem-1774	57	20	162.97	162.97	NUM
eurjchem-1774	57	21	(	(	PUNCT
eurjchem-1774	57	22	c	c	NOUN
eurjchem-1774	57	23	=	=	NOUN
eurjchem-1774	57	24	o	o	NOUN
eurjchem-1774	57	25	)	)	PUNCT
eurjchem-1774	57	26	,	,	PUNCT
eurjchem-1774	57	27	132.02	132.02	NUM
eurjchem-1774	57	28	(	(	PUNCT
eurjchem-1774	57	29	c	c	NOUN
eurjchem-1774	57	30	-	-	PUNCT
eurjchem-1774	57	31	ar	ar	NOUN
eurjchem-1774	57	32	)	)	PUNCT
eurjchem-1774	57	33	,	,	PUNCT
eurjchem-1774	57	34	131.40	131.40	NUM
eurjchem-1774	57	35	(	(	PUNCT
eurjchem-1774	57	36	c	c	NOUN
eurjchem-1774	57	37	-	-	PUNCT
eurjchem-1774	57	38	ar	ar	NOUN
eurjchem-1774	57	39	)	)	PUNCT
eurjchem-1774	57	40	,	,	PUNCT
eurjchem-1774	57	41	129.55	129.55	NUM
eurjchem-1774	57	42	(	(	PUNCT
eurjchem-1774	57	43	car	car	NOUN
eurjchem-1774	57	44	)	)	PUNCT
eurjchem-1774	57	45	,	,	PUNCT
eurjchem-1774	57	46	127.78	127.78	NUM
eurjchem-1774	57	47	(	(	PUNCT
eurjchem-1774	57	48	c	c	NOUN
eurjchem-1774	57	49	-	-	PUNCT
eurjchem-1774	57	50	ar	ar	NOUN
eurjchem-1774	57	51	)	)	PUNCT
eurjchem-1774	57	52	,	,	PUNCT
eurjchem-1774	57	53	55.02	55.02	NUM
eurjchem-1774	57	54	(	(	PUNCT
eurjchem-1774	57	55	c	c	NOUN
eurjchem-1774	57	56	-	-	PUNCT
eurjchem-1774	57	57	n	n	CCONJ
eurjchem-1774	57	58	)	)	PUNCT
eurjchem-1774	57	59	,	,	PUNCT
eurjchem-1774	57	60	54.95	54.95	NUM
eurjchem-1774	57	61	(	(	PUNCT
eurjchem-1774	57	62	cn	cn	PROPN
eurjchem-1774	57	63	)	)	PUNCT
eurjchem-1774	57	64	,	,	PUNCT
eurjchem-1774	57	65	21.48	21.48	NUM
eurjchem-1774	57	66	(	(	PUNCT
eurjchem-1774	57	67	ch2	ch2	PROPN
eurjchem-1774	57	68	)	)	PUNCT
eurjchem-1774	57	69	,	,	PUNCT
eurjchem-1774	57	70	19.75	19.75	NUM
eurjchem-1774	57	71	(	(	PUNCT
eurjchem-1774	57	72	ch2	ch2	PROPN
eurjchem-1774	57	73	)	)	PUNCT
eurjchem-1774	57	74	,	,	PUNCT
eurjchem-1774	57	75	11.35	11.35	NUM
eurjchem-1774	57	76	(	(	PUNCT
eurjchem-1774	57	77	ch3	ch3	PROPN
eurjchem-1774	57	78	)	)	PUNCT
eurjchem-1774	57	79	,	,	PUNCT
eurjchem-1774	57	80	11.31	11.31	NUM
eurjchem-1774	57	81	(	(	PUNCT
eurjchem-1774	57	82	ch3	ch3	PROPN
eurjchem-1774	57	83	)	)	PUNCT
eurjchem-1774	57	84	.	.	PUNCT
eurjchem-1774	58	1	2.3.2	2.3.2	X
eurjchem-1774	58	2	.	.	PUNCT
eurjchem-1774	58	3	general	general	ADJ
eurjchem-1774	58	4	procedure	procedure	NOUN
eurjchem-1774	58	5	for	for	ADP
eurjchem-1774	58	6	the	the	DET
eurjchem-1774	58	7	synthesis	synthesis	NOUN
eurjchem-1774	58	8	of	of	ADP
eurjchem-1774	58	9	platinum	platinum	NOUN
eurjchem-1774	58	10	complexes	complexe	VERB
eurjchem-1774	58	11	a	a	DET
eurjchem-1774	58	12	solution	solution	NOUN
eurjchem-1774	58	13	of	of	ADP
eurjchem-1774	58	14	hl1,2	hl1,2	NOUN
eurjchem-1774	58	15	(	(	PUNCT
eurjchem-1774	58	16	2.0	2.0	NUM
eurjchem-1774	58	17	mmol	mmol	NOUN
eurjchem-1774	58	18	,	,	PUNCT
eurjchem-1774	58	19	hl1	hl1	PROPN
eurjchem-1774	58	20	:	:	PUNCT
eurjchem-1774	58	21	0.56	0.56	NUM
eurjchem-1774	58	22	g	g	NOUN
eurjchem-1774	58	23	;	;	PUNCT
eurjchem-1774	58	24	hl2	hl2	NOUN
eurjchem-1774	58	25	:	:	PUNCT
eurjchem-1774	58	26	0.67	0.67	NUM
eurjchem-1774	58	27	g	g	NOUN
eurjchem-1774	58	28	)	)	PUNCT
eurjchem-1774	58	29	in	in	ADP
eurjchem-1774	58	30	ethanol	ethanol	NOUN
eurjchem-1774	58	31	(	(	PUNCT
eurjchem-1774	58	32	50	50	NUM
eurjchem-1774	58	33	ml	ml	NOUN
eurjchem-1774	58	34	)	)	PUNCT
eurjchem-1774	58	35	at	at	ADP
eurjchem-1774	58	36	70	70	NUM
eurjchem-1774	58	37	○	○	PROPN
eurjchem-1774	58	38	c	c	PROPN
eurjchem-1774	58	39	was	be	AUX
eurjchem-1774	58	40	added	add	VERB
eurjchem-1774	58	41	dropwise	dropwise	NOUN
eurjchem-1774	58	42	to	to	ADP
eurjchem-1774	58	43	a	a	DET
eurjchem-1774	58	44	solution	solution	NOUN
eurjchem-1774	58	45	of	of	ADP
eurjchem-1774	58	46	potassium	potassium	NOUN
eurjchem-1774	58	47	tetrachloroplatinate(ii	tetrachloroplatinate(ii	NOUN
eurjchem-1774	58	48	)	)	PUNCT
eurjchem-1774	58	49	(	(	PUNCT
eurjchem-1774	58	50	1.0	1.0	NUM
eurjchem-1774	58	51	mmol	mmol	NOUN
eurjchem-1774	58	52	,	,	PUNCT
eurjchem-1774	58	53	0.416	0.416	NUM
eurjchem-1774	58	54	g	g	NOUN
eurjchem-1774	58	55	)	)	PUNCT
eurjchem-1774	58	56	in	in	ADP
eurjchem-1774	58	57	water	water	NOUN
eurjchem-1774	58	58	(	(	PUNCT
eurjchem-1774	58	59	50	50	NUM
eurjchem-1774	58	60	ml	ml	NOUN
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eurjchem-1774	58	62	at	at	ADP
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eurjchem-1774	58	72	30	30	NUM
eurjchem-1774	58	73	min	min	NOUN
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eurjchem-1774	58	80	.	.	PUNCT
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eurjchem-1774	59	3	–	–	PUNCT
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eurjchem-1774	59	7	,	,	PUNCT
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eurjchem-1774	59	16	:	:	PUNCT
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eurjchem-1774	59	19	2:1	2:1	NUM
eurjchem-1774	59	20	,	,	PUNCT
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eurjchem-1774	59	22	:	:	PUNCT
eurjchem-1774	59	23	v	v	NOUN
eurjchem-1774	59	24	)	)	PUNCT
eurjchem-1774	59	25	(	(	PUNCT
eurjchem-1774	59	26	scheme	scheme	NOUN
eurjchem-1774	59	27	2	2	NUM
eurjchem-1774	59	28	)	)	PUNCT
eurjchem-1774	60	1	[	[	X
eurjchem-1774	60	2	41	41	NUM
eurjchem-1774	60	3	-	-	SYM
eurjchem-1774	60	4	50	50	NUM
eurjchem-1774	60	5	]	]	PUNCT
eurjchem-1774	60	6	.	.	PUNCT
eurjchem-1774	61	1	bis[4	bis[4	X
eurjchem-1774	61	2	-	-	PUNCT
eurjchem-1774	61	3	fluoro	fluoro	NOUN
eurjchem-1774	61	4	-	-	PUNCT
eurjchem-1774	61	5	n-(di	n-(di	PROPN
eurjchem-1774	61	6	-	-	PUNCT
eurjchem-1774	61	7	n	n	CCONJ
eurjchem-1774	61	8	-	-	PUNCT
eurjchem-1774	61	9	propylcarbamothioyl)benzamido	propylcarbamothioyl)benzamido	NOUN
eurjchem-1774	61	10	-	-	PUNCT
eurjchem-1774	61	11	o	o	NOUN
eurjchem-1774	61	12	,	,	PUNCT
eurjchem-1774	61	13	s	s	X
eurjchem-1774	61	14	]	]	X
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eurjchem-1774	61	16	)	)	PUNCT
eurjchem-1774	61	17	,	,	PUNCT
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eurjchem-1774	61	19	-	-	PUNCT
eurjchem-1774	61	20	s	s	PROPN
eurjchem-1774	61	21	,	,	PUNCT
eurjchem-1774	61	22	o)2	o)2	PROPN
eurjchem-1774	61	23	]	]	NOUN
eurjchem-1774	61	24	:	:	PUNCT
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eurjchem-1774	61	26	:	:	PUNCT
eurjchem-1774	61	27	yellow	yellow	ADJ
eurjchem-1774	61	28	.	.	PUNCT
eurjchem-1774	62	1	yield	yield	NOUN
eurjchem-1774	62	2	:	:	PUNCT
eurjchem-1774	62	3	78	78	NUM
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eurjchem-1774	62	5	.	.	PUNCT
eurjchem-1774	63	1	ft	ft	PROPN
eurjchem-1774	63	2	-	-	PUNCT
eurjchem-1774	63	3	ir	ir	PROPN
eurjchem-1774	63	4	(	(	PUNCT
eurjchem-1774	63	5	atr	atr	PROPN
eurjchem-1774	63	6	,	,	PUNCT
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eurjchem-1774	63	8	,	,	PUNCT
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eurjchem-1774	63	10	):	):	PUNCT
eurjchem-1774	63	11	ν(c	ν(c	PROPN
eurjchem-1774	63	12	–	–	PUNCT
eurjchem-1774	63	13	h	h	NOUN
eurjchem-1774	63	14	)	)	PUNCT
eurjchem-1774	63	15	2962	2962	NUM
eurjchem-1774	63	16	,	,	PUNCT
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eurjchem-1774	63	18	,	,	PUNCT
eurjchem-1774	63	19	2868	2868	NUM
eurjchem-1774	63	20	(	(	PUNCT
eurjchem-1774	63	21	w	w	NOUN
eurjchem-1774	63	22	)	)	PUNCT
eurjchem-1774	63	23	,	,	PUNCT
eurjchem-1774	63	24	ν(c	ν(c	PROPN
eurjchem-1774	63	25	–	–	PUNCT
eurjchem-1774	63	26	n	n	CCONJ
eurjchem-1774	63	27	)	)	PUNCT
eurjchem-1774	63	28	1578	1578	NUM
eurjchem-1774	63	29	(	(	PUNCT
eurjchem-1774	63	30	w	w	NOUN
eurjchem-1774	63	31	)	)	PUNCT
eurjchem-1774	63	32	,	,	PUNCT
eurjchem-1774	63	33	ν(c	ν(c	PROPN
eurjchem-1774	63	34	–	–	PUNCT
eurjchem-1774	63	35	o	o	NOUN
eurjchem-1774	63	36	)	)	PUNCT
eurjchem-1774	63	37	1487	1487	NUM
eurjchem-1774	63	38	(	(	PUNCT
eurjchem-1774	63	39	vs	vs	NOUN
eurjchem-1774	63	40	)	)	PUNCT
eurjchem-1774	63	41	,	,	PUNCT
eurjchem-1774	63	42	ν(c	ν(c	PROPN
eurjchem-1774	63	43	–	–	PUNCT
eurjchem-1774	63	44	s	s	X
eurjchem-1774	63	45	)	)	PUNCT
eurjchem-1774	63	46	1088	1088	NUM
eurjchem-1774	63	47	(	(	PUNCT
eurjchem-1774	63	48	s	s	NOUN
eurjchem-1774	63	49	)	)	PUNCT
eurjchem-1774	63	50	.	.	PUNCT
eurjchem-1774	64	1	1h	1h	NUM
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eurjchem-1774	64	3	(	(	PUNCT
eurjchem-1774	64	4	400	400	NUM
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eurjchem-1774	64	6	,	,	PUNCT
eurjchem-1774	64	7	cdcl3	cdcl3	PROPN
eurjchem-1774	64	8	,	,	PUNCT
eurjchem-1774	64	9	δ	δ	PROPN
eurjchem-1774	64	10	,	,	PUNCT
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eurjchem-1774	64	12	):	):	PUNCT
eurjchem-1774	64	13	8.16	8.16	NUM
eurjchem-1774	64	14	(	(	PUNCT
eurjchem-1774	64	15	td	td	PROPN
eurjchem-1774	64	16	,	,	PUNCT
eurjchem-1774	64	17	4h	4h	NUM
eurjchem-1774	64	18	,	,	PUNCT
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eurjchem-1774	64	20	–	–	PROPN
eurjchem-1774	64	21	h	h	NOUN
eurjchem-1774	64	22	)	)	PUNCT
eurjchem-1774	64	23	,	,	PUNCT
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eurjchem-1774	64	25	(	(	PUNCT
eurjchem-1774	64	26	td	td	PROPN
eurjchem-1774	64	27	,	,	PUNCT
eurjchem-1774	64	28	4h	4h	NUM
eurjchem-1774	64	29	,	,	PUNCT
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eurjchem-1774	64	31	–	–	PROPN
eurjchem-1774	64	32	h	h	NOUN
eurjchem-1774	64	33	)	)	PUNCT
eurjchem-1774	64	34	,	,	PUNCT
eurjchem-1774	64	35	3.65	3.65	NUM
eurjchem-1774	64	36	(	(	PUNCT
eurjchem-1774	64	37	q	q	NOUN
eurjchem-1774	64	38	,	,	PUNCT
eurjchem-1774	64	39	4h	4h	NUM
eurjchem-1774	64	40	,	,	PUNCT
eurjchem-1774	64	41	n	n	CCONJ
eurjchem-1774	64	42	–	–	PUNCT
eurjchem-1774	64	43	ch2	ch2	NOUN
eurjchem-1774	64	44	)	)	PUNCT
eurjchem-1774	64	45	,	,	PUNCT
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eurjchem-1774	64	47	(	(	PUNCT
eurjchem-1774	64	48	q	q	NOUN
eurjchem-1774	64	49	,	,	PUNCT
eurjchem-1774	64	50	4h	4h	NUM
eurjchem-1774	64	51	,	,	PUNCT
eurjchem-1774	64	52	n	n	CCONJ
eurjchem-1774	64	53	–	–	PUNCT
eurjchem-1774	64	54	ch2	ch2	NOUN
eurjchem-1774	64	55	)	)	PUNCT
eurjchem-1774	64	56	,	,	PUNCT
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eurjchem-1774	64	58	(	(	PUNCT
eurjchem-1774	64	59	p	p	X
eurjchem-1774	64	60	,	,	PUNCT
eurjchem-1774	64	61	4h	4h	NUM
eurjchem-1774	64	62	,	,	PUNCT
eurjchem-1774	64	63	n	n	CCONJ
eurjchem-1774	64	64	–	–	PUNCT
eurjchem-1774	64	65	ch2	ch2	NOUN
eurjchem-1774	64	66	-	-	PUNCT
eurjchem-1774	64	67	ch2	ch2	NOUN
eurjchem-1774	64	68	)	)	PUNCT
eurjchem-1774	64	69	,	,	PUNCT
eurjchem-1774	64	70	1.63	1.63	NUM
eurjchem-1774	64	71	(	(	PUNCT
eurjchem-1774	64	72	p	p	X
eurjchem-1774	64	73	,	,	PUNCT
eurjchem-1774	64	74	4h	4h	NUM
eurjchem-1774	64	75	,	,	PUNCT
eurjchem-1774	64	76	n	n	CCONJ
eurjchem-1774	64	77	–	–	PUNCT
eurjchem-1774	64	78	ch2	ch2	NOUN
eurjchem-1774	64	79	-	-	PUNCT
eurjchem-1774	64	80	ch2	ch2	NOUN
eurjchem-1774	64	81	)	)	PUNCT
eurjchem-1774	64	82	,	,	PUNCT
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eurjchem-1774	64	84	(	(	PUNCT
eurjchem-1774	64	85	m	m	PROPN
eurjchem-1774	64	86	,	,	PUNCT
eurjchem-1774	64	87	12h	12h	NUM
eurjchem-1774	64	88	,	,	PUNCT
eurjchem-1774	64	89	ch3	ch3	PROPN
eurjchem-1774	64	90	)	)	PUNCT
eurjchem-1774	64	91	.	.	PUNCT
eurjchem-1774	65	1	13c	13c	NOUN
eurjchem-1774	65	2	nmr	nmr	NOUN
eurjchem-1774	65	3	(	(	PUNCT
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eurjchem-1774	65	6	,	,	PUNCT
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eurjchem-1774	65	8	,	,	PUNCT
eurjchem-1774	65	9	δ	δ	PROPN
eurjchem-1774	65	10	,	,	PUNCT
eurjchem-1774	65	11	ppm	ppm	NUM
eurjchem-1774	65	12	):	):	PUNCT
eurjchem-1774	65	13	167.68	167.68	NUM
eurjchem-1774	65	14	(	(	PUNCT
eurjchem-1774	65	15	c	c	X
eurjchem-1774	65	16	–	–	PUNCT
eurjchem-1774	65	17	s	s	NOUN
eurjchem-1774	65	18	)	)	PUNCT
eurjchem-1774	65	19	,	,	PUNCT
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eurjchem-1774	65	21	(	(	PUNCT
eurjchem-1774	65	22	c	c	NOUN
eurjchem-1774	65	23	–	–	PUNCT
eurjchem-1774	65	24	o	o	NOUN
eurjchem-1774	65	25	)	)	PUNCT
eurjchem-1774	65	26	,	,	PUNCT
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eurjchem-1774	65	30	–	–	PUNCT
eurjchem-1774	65	31	ar	ar	NOUN
eurjchem-1774	65	32	)	)	PUNCT
eurjchem-1774	65	33	,	,	PUNCT
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eurjchem-1774	65	35	(	(	PUNCT
eurjchem-1774	65	36	c	c	NOUN
eurjchem-1774	65	37	–	–	PUNCT
eurjchem-1774	65	38	ar	ar	NOUN
eurjchem-1774	65	39	)	)	PUNCT
eurjchem-1774	65	40	,	,	PUNCT
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eurjchem-1774	65	42	(	(	PUNCT
eurjchem-1774	65	43	c	c	NOUN
eurjchem-1774	65	44	–	–	PUNCT
eurjchem-1774	65	45	ar	ar	NOUN
eurjchem-1774	65	46	)	)	PUNCT
eurjchem-1774	65	47	,	,	PUNCT
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eurjchem-1774	65	49	(	(	PUNCT
eurjchem-1774	65	50	c	c	NOUN
eurjchem-1774	65	51	–	–	PUNCT
eurjchem-1774	65	52	ar	ar	NOUN
eurjchem-1774	65	53	)	)	PUNCT
eurjchem-1774	65	54	,	,	PUNCT
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eurjchem-1774	65	56	(	(	PUNCT
eurjchem-1774	65	57	c	c	NOUN
eurjchem-1774	65	58	–	–	PUNCT
eurjchem-1774	65	59	ar	ar	NOUN
eurjchem-1774	65	60	)	)	PUNCT
eurjchem-1774	65	61	,	,	PUNCT
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eurjchem-1774	65	63	(	(	PUNCT
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eurjchem-1774	65	65	–	–	PUNCT
eurjchem-1774	65	66	ar	ar	NOUN
eurjchem-1774	65	67	)	)	PUNCT
eurjchem-1774	65	68	54.54	54.54	NUM
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eurjchem-1774	65	70	c	c	NOUN
eurjchem-1774	65	71	–	–	PUNCT
eurjchem-1774	65	72	n	n	NUM
eurjchem-1774	65	73	)	)	PUNCT
eurjchem-1774	65	74	,	,	PUNCT
eurjchem-1774	65	75	53.75	53.75	NUM
eurjchem-1774	65	76	(	(	PUNCT
eurjchem-1774	65	77	c	c	NOUN
eurjchem-1774	65	78	–	–	PUNCT
eurjchem-1774	65	79	n	n	NUM
eurjchem-1774	65	80	)	)	PUNCT
eurjchem-1774	65	81	,	,	PUNCT
eurjchem-1774	65	82	21.27	21.27	NUM
eurjchem-1774	65	83	(	(	PUNCT
eurjchem-1774	65	84	ch2	ch2	PROPN
eurjchem-1774	65	85	)	)	PUNCT
eurjchem-1774	65	86	,	,	PUNCT
eurjchem-1774	65	87	20.53	20.53	NUM
eurjchem-1774	65	88	(	(	PUNCT
eurjchem-1774	65	89	ch2	ch2	PROPN
eurjchem-1774	65	90	)	)	PUNCT
eurjchem-1774	65	91	,	,	PUNCT
eurjchem-1774	65	92	11.40	11.40	NUM
eurjchem-1774	65	93	(	(	PUNCT
eurjchem-1774	65	94	ch3	ch3	PROPN
eurjchem-1774	65	95	)	)	PUNCT
eurjchem-1774	65	96	.	.	PUNCT
eurjchem-1774	66	1	bis[4	bis[4	X
eurjchem-1774	66	2	-	-	PUNCT
eurjchem-1774	66	3	bromo	bromo	NOUN
eurjchem-1774	66	4	-	-	PUNCT
eurjchem-1774	66	5	n-(di	n-(di	PROPN
eurjchem-1774	66	6	-	-	PUNCT
eurjchem-1774	66	7	n	n	CCONJ
eurjchem-1774	66	8	-	-	PUNCT
eurjchem-1774	66	9	propylcarbamothioyl)benzamido	propylcarbamothioyl)benzamido	NOUN
eurjchem-1774	66	10	-	-	PUNCT
eurjchem-1774	66	11	o	o	NOUN
eurjchem-1774	66	12	,	,	PUNCT
eurjchem-1774	66	13	s	s	X
eurjchem-1774	66	14	]	]	X
eurjchem-1774	66	15	platinum(ii	platinum(ii	NOUN
eurjchem-1774	66	16	)	)	PUNCT
eurjchem-1774	66	17	,	,	PUNCT
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eurjchem-1774	66	19	-	-	PUNCT
eurjchem-1774	66	20	s	s	PROPN
eurjchem-1774	66	21	,	,	PUNCT
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eurjchem-1774	66	24	:	:	PUNCT
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eurjchem-1774	66	26	:	:	PUNCT
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eurjchem-1774	67	2	.	.	PUNCT
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eurjchem-1774	67	4	:	:	PUNCT
eurjchem-1774	67	5	72	72	NUM
eurjchem-1774	67	6	%	%	NOUN
eurjchem-1774	67	7	.	.	PUNCT
eurjchem-1774	68	1	ft	ft	PROPN
eurjchem-1774	68	2	-	-	PUNCT
eurjchem-1774	68	3	ir	ir	PROPN
eurjchem-1774	68	4	(	(	PUNCT
eurjchem-1774	68	5	atr	atr	PROPN
eurjchem-1774	68	6	,	,	PUNCT
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eurjchem-1774	68	8	,	,	PUNCT
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eurjchem-1774	68	10	):	):	PUNCT
eurjchem-1774	68	11	ν(c	ν(c	PROPN
eurjchem-1774	68	12	–	–	PUNCT
eurjchem-1774	68	13	h	h	NOUN
eurjchem-1774	68	14	)	)	PUNCT
eurjchem-1774	68	15	2972	2972	NUM
eurjchem-1774	68	16	,	,	PUNCT
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eurjchem-1774	68	18	,	,	PUNCT
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eurjchem-1774	68	20	(	(	PUNCT
eurjchem-1774	68	21	w	w	NOUN
eurjchem-1774	68	22	)	)	PUNCT
eurjchem-1774	68	23	,	,	PUNCT
eurjchem-1774	68	24	ν(c	ν(c	PROPN
eurjchem-1774	68	25	–	–	PUNCT
eurjchem-1774	68	26	n	n	CCONJ
eurjchem-1774	68	27	)	)	PUNCT
eurjchem-1774	68	28	1565	1565	NUM
eurjchem-1774	68	29	(	(	PUNCT
eurjchem-1774	68	30	w	w	NOUN
eurjchem-1774	68	31	)	)	PUNCT
eurjchem-1774	68	32	,	,	PUNCT
eurjchem-1774	68	33	ν(c	ν(c	PROPN
eurjchem-1774	68	34	–	–	PUNCT
eurjchem-1774	68	35	o	o	NOUN
eurjchem-1774	68	36	)	)	PUNCT
eurjchem-1774	68	37	1492	1492	NUM
eurjchem-1774	68	38	(	(	PUNCT
eurjchem-1774	68	39	vs	vs	NOUN
eurjchem-1774	68	40	)	)	PUNCT
eurjchem-1774	68	41	,	,	PUNCT
eurjchem-1774	68	42	ν(c	ν(c	PROPN
eurjchem-1774	68	43	–	–	PUNCT
eurjchem-1774	68	44	s	s	X
eurjchem-1774	68	45	)	)	PUNCT
eurjchem-1774	68	46	1090	1090	NUM
eurjchem-1774	68	47	(	(	PUNCT
eurjchem-1774	68	48	s	s	NOUN
eurjchem-1774	68	49	)	)	PUNCT
eurjchem-1774	68	50	.	.	PUNCT
eurjchem-1774	69	1	1h	1h	NUM
eurjchem-1774	69	2	nmr	nmr	NOUN
eurjchem-1774	69	3	(	(	PUNCT
eurjchem-1774	69	4	400	400	NUM
eurjchem-1774	69	5	mhz	mhz	NOUN
eurjchem-1774	69	6	,	,	PUNCT
eurjchem-1774	69	7	cdcl3	cdcl3	PROPN
eurjchem-1774	69	8	,	,	PUNCT
eurjchem-1774	69	9	δ	δ	PROPN
eurjchem-1774	69	10	,	,	PUNCT
eurjchem-1774	69	11	ppm	ppm	NOUN
eurjchem-1774	69	12	):	):	PUNCT
eurjchem-1774	69	13	8.10	8.10	NUM
eurjchem-1774	69	14	(	(	PUNCT
eurjchem-1774	69	15	td	td	PROPN
eurjchem-1774	69	16	,	,	PUNCT
eurjchem-1774	69	17	4h	4h	NUM
eurjchem-1774	69	18	,	,	PUNCT
eurjchem-1774	69	19	ar	ar	PROPN
eurjchem-1774	69	20	–	–	PROPN
eurjchem-1774	69	21	h	h	NOUN
eurjchem-1774	69	22	)	)	PUNCT
eurjchem-1774	69	23	,	,	PUNCT
eurjchem-1774	69	24	7.57	7.57	NUM
eurjchem-1774	69	25	(	(	PUNCT
eurjchem-1774	69	26	td	td	PROPN
eurjchem-1774	69	27	,	,	PUNCT
eurjchem-1774	69	28	4h	4h	NUM
eurjchem-1774	69	29	,	,	PUNCT
eurjchem-1774	69	30	ar	ar	PROPN
eurjchem-1774	69	31	–	–	PROPN
eurjchem-1774	69	32	h	h	NOUN
eurjchem-1774	69	33	)	)	PUNCT
eurjchem-1774	69	34	,	,	PUNCT
eurjchem-1774	69	35	3.75	3.75	NUM
eurjchem-1774	69	36	(	(	PUNCT
eurjchem-1774	69	37	q	q	NOUN
eurjchem-1774	69	38	,	,	PUNCT
eurjchem-1774	69	39	4h	4h	NUM
eurjchem-1774	69	40	,	,	PUNCT
eurjchem-1774	69	41	n	n	CCONJ
eurjchem-1774	69	42	–	–	PUNCT
eurjchem-1774	69	43	ch2	ch2	NOUN
eurjchem-1774	69	44	)	)	PUNCT
eurjchem-1774	69	45	,	,	PUNCT
eurjchem-1774	69	46	3.67	3.67	NUM
eurjchem-1774	69	47	(	(	PUNCT
eurjchem-1774	69	48	q	q	NOUN
eurjchem-1774	69	49	,	,	PUNCT
eurjchem-1774	69	50	4h	4h	NUM
eurjchem-1774	69	51	,	,	PUNCT
eurjchem-1774	69	52	n	n	CCONJ
eurjchem-1774	69	53	–	–	PUNCT
eurjchem-1774	69	54	ch2	ch2	NOUN
eurjchem-1774	69	55	)	)	PUNCT
eurjchem-1774	69	56	,	,	PUNCT
eurjchem-1774	69	57	1.85	1.85	NUM
eurjchem-1774	69	58	(	(	PUNCT
eurjchem-1774	69	59	p	p	X
eurjchem-1774	69	60	,	,	PUNCT
eurjchem-1774	69	61	4h	4h	NUM
eurjchem-1774	69	62	,	,	PUNCT
eurjchem-1774	69	63	n	n	CCONJ
eurjchem-1774	69	64	–	–	PUNCT
eurjchem-1774	69	65	ch2	ch2	NOUN
eurjchem-1774	69	66	-	-	PUNCT
eurjchem-1774	69	67	ch2	ch2	NOUN
eurjchem-1774	69	68	)	)	PUNCT
eurjchem-1774	69	69	,	,	PUNCT
eurjchem-1774	69	70	1.76	1.76	NUM
eurjchem-1774	69	71	(	(	PUNCT
eurjchem-1774	69	72	p	p	X
eurjchem-1774	69	73	,	,	PUNCT
eurjchem-1774	69	74	4h	4h	NUM
eurjchem-1774	69	75	,	,	PUNCT
eurjchem-1774	69	76	n	n	CCONJ
eurjchem-1774	69	77	–	–	PUNCT
eurjchem-1774	69	78	ch2	ch2	NOUN
eurjchem-1774	69	79	-	-	PUNCT
eurjchem-1774	69	80	ch2	ch2	NOUN
eurjchem-1774	69	81	)	)	PUNCT
eurjchem-1774	69	82	,	,	PUNCT
eurjchem-1774	69	83	0.99	0.99	NUM
eurjchem-1774	69	84	(	(	PUNCT
eurjchem-1774	69	85	m	m	PROPN
eurjchem-1774	69	86	,	,	PUNCT
eurjchem-1774	69	87	12h	12h	NUM
eurjchem-1774	69	88	,	,	PUNCT
eurjchem-1774	69	89	ch3	ch3	PROPN
eurjchem-1774	69	90	)	)	PUNCT
eurjchem-1774	69	91	.	.	PUNCT
eurjchem-1774	70	1	13c	13c	NOUN
eurjchem-1774	70	2	nmr	nmr	NOUN
eurjchem-1774	70	3	(	(	PUNCT
eurjchem-1774	70	4	100	100	NUM
eurjchem-1774	70	5	mhz	mhz	NOUN
eurjchem-1774	70	6	,	,	PUNCT
eurjchem-1774	70	7	cdcl3	cdcl3	PROPN
eurjchem-1774	70	8	,	,	PUNCT
eurjchem-1774	70	9	δ	δ	PROPN
eurjchem-1774	70	10	,	,	PUNCT
eurjchem-1774	70	11	ppm	ppm	NOUN
eurjchem-1774	70	12	):	):	PUNCT
eurjchem-1774	70	13	167.74	167.74	NUM
eurjchem-1774	70	14	(	(	PUNCT
eurjchem-1774	70	15	c	c	NOUN
eurjchem-1774	70	16	–	–	PUNCT
eurjchem-1774	70	17	s	s	NOUN
eurjchem-1774	70	18	)	)	PUNCT
eurjchem-1774	70	19	,	,	PUNCT
eurjchem-1774	70	20	167.47	167.47	NUM
eurjchem-1774	70	21	(	(	PUNCT
eurjchem-1774	70	22	c	c	NOUN
eurjchem-1774	70	23	–	–	PUNCT
eurjchem-1774	70	24	o	o	NOUN
eurjchem-1774	70	25	)	)	PUNCT
eurjchem-1774	70	26	,	,	PUNCT
eurjchem-1774	70	27	136.64	136.64	NUM
eurjchem-1774	70	28	(	(	PUNCT
eurjchem-1774	70	29	c	c	NOUN
eurjchem-1774	70	30	–	–	PUNCT
eurjchem-1774	70	31	ar	ar	NOUN
eurjchem-1774	70	32	)	)	PUNCT
eurjchem-1774	70	33	,	,	PUNCT
eurjchem-1774	70	34	131.36	131.36	NUM
eurjchem-1774	70	35	(	(	PUNCT
eurjchem-1774	70	36	c	c	X
eurjchem-1774	70	37	–	–	PUNCT
eurjchem-1774	70	38	ar	ar	NOUN
eurjchem-1774	70	39	)	)	PUNCT
eurjchem-1774	70	40	,	,	PUNCT
eurjchem-1774	70	41	131.13	131.13	NUM
eurjchem-1774	70	42	(	(	PUNCT
eurjchem-1774	70	43	c	c	NOUN
eurjchem-1774	70	44	–	–	PUNCT
eurjchem-1774	70	45	ar	ar	NOUN
eurjchem-1774	70	46	)	)	PUNCT
eurjchem-1774	70	47	,	,	PUNCT
eurjchem-1774	70	48	130.85	130.85	NUM
eurjchem-1774	70	49	(	(	PUNCT
eurjchem-1774	70	50	c	c	NOUN
eurjchem-1774	70	51	–	–	PUNCT
eurjchem-1774	70	52	ar	ar	NOUN
eurjchem-1774	70	53	)	)	PUNCT
eurjchem-1774	70	54	,	,	PUNCT
eurjchem-1774	70	55	126.27	126.27	NUM
eurjchem-1774	70	56	(	(	PUNCT
eurjchem-1774	70	57	c	c	NOUN
eurjchem-1774	70	58	–	–	PUNCT
eurjchem-1774	70	59	ar	ar	NOUN
eurjchem-1774	70	60	)	)	PUNCT
eurjchem-1774	70	61	,	,	PUNCT
eurjchem-1774	70	62	54.60	54.60	NUM
eurjchem-1774	70	63	(	(	PUNCT
eurjchem-1774	70	64	c	c	NOUN
eurjchem-1774	70	65	–	–	PUNCT
eurjchem-1774	70	66	n	n	NUM
eurjchem-1774	70	67	)	)	PUNCT
eurjchem-1774	70	68	,	,	PUNCT
eurjchem-1774	70	69	53.51	53.51	NUM
eurjchem-1774	70	70	(	(	PUNCT
eurjchem-1774	70	71	c	c	NOUN
eurjchem-1774	70	72	–	–	PUNCT
eurjchem-1774	70	73	n	n	NUM
eurjchem-1774	70	74	)	)	PUNCT
eurjchem-1774	70	75	,	,	PUNCT
eurjchem-1774	70	76	20.49	20.49	NUM
eurjchem-1774	70	77	(	(	PUNCT
eurjchem-1774	70	78	ch2	ch2	PROPN
eurjchem-1774	70	79	)	)	PUNCT
eurjchem-1774	70	80	,	,	PUNCT
eurjchem-1774	70	81	20.53	20.53	NUM
eurjchem-1774	70	82	(	(	PUNCT
eurjchem-1774	70	83	ch2	ch2	PROPN
eurjchem-1774	70	84	)	)	PUNCT
eurjchem-1774	70	85	,	,	PUNCT
eurjchem-1774	70	86	11.40	11.40	NUM
eurjchem-1774	70	87	(	(	PUNCT
eurjchem-1774	70	88	ch3	ch3	PROPN
eurjchem-1774	70	89	)	)	PUNCT
eurjchem-1774	70	90	.	.	PUNCT
eurjchem-1774	71	1	3	3	X
eurjchem-1774	71	2	.	.	NOUN
eurjchem-1774	71	3	results	result	NOUN
eurjchem-1774	71	4	and	and	CCONJ
eurjchem-1774	71	5	discussion	discussion	NOUN
eurjchem-1774	71	6	3.1	3.1	NUM
eurjchem-1774	71	7	.	.	PUNCT
eurjchem-1774	72	1	nmr	nmr	NOUN
eurjchem-1774	72	2	and	and	CCONJ
eurjchem-1774	72	3	ft	ft	PROPN
eurjchem-1774	72	4	-	-	PUNCT
eurjchem-1774	72	5	ir	ir	NOUN
eurjchem-1774	72	6	spectral	spectral	ADJ
eurjchem-1774	72	7	analysis	analysis	NOUN
eurjchem-1774	72	8	the	the	DET
eurjchem-1774	72	9	synthesized	synthesize	VERB
eurjchem-1774	72	10	compounds	compound	NOUN
eurjchem-1774	72	11	have	have	AUX
eurjchem-1774	72	12	been	be	AUX
eurjchem-1774	72	13	characterized	characterize	VERB
eurjchem-1774	72	14	by	by	ADP
eurjchem-1774	72	15	spectroscopic	spectroscopic	NOUN
eurjchem-1774	72	16	1h	1h	NUM
eurjchem-1774	72	17	nmr	nmr	NOUN
eurjchem-1774	72	18	,	,	PUNCT
eurjchem-1774	72	19	13c	13c	NOUN
eurjchem-1774	72	20	nmr	nmr	NOUN
eurjchem-1774	72	21	,	,	PUNCT
eurjchem-1774	72	22	cosy	cosy	PROPN
eurjchem-1774	72	23	,	,	PUNCT
eurjchem-1774	72	24	hmqc	hmqc	PROPN
eurjchem-1774	72	25	and	and	CCONJ
eurjchem-1774	72	26	ft	ft	PROPN
eurjchem-1774	72	27	-	-	PUNCT
eurjchem-1774	72	28	ir	ir	NOUN
eurjchem-1774	72	29	techniques	technique	NOUN
eurjchem-1774	72	30	.	.	PUNCT
eurjchem-1774	73	1	the	the	DET
eurjchem-1774	73	2	nmr	nmr	NOUN
eurjchem-1774	73	3	spectra	spectra	NOUN
eurjchem-1774	73	4	of	of	ADP
eurjchem-1774	73	5	the	the	DET
eurjchem-1774	73	6	ligands	ligand	NOUN
eurjchem-1774	73	7	and	and	CCONJ
eurjchem-1774	73	8	their	their	PRON
eurjchem-1774	73	9	platinum	platinum	NOUN
eurjchem-1774	73	10	complexes	complex	NOUN
eurjchem-1774	73	11	were	be	AUX
eurjchem-1774	73	12	recorded	record	VERB
eurjchem-1774	73	13	in	in	ADP
eurjchem-1774	73	14	cdcl3	cdcl3	PROPN
eurjchem-1774	73	15	.	.	PUNCT
eurjchem-1774	74	1	2018	2018	NUM
eurjchem-1774	74	2	–	–	PUNCT
eurjchem-1774	74	3	european	european	ADJ
eurjchem-1774	74	4	journal	journal	NOUN
eurjchem-1774	74	5	of	of	ADP
eurjchem-1774	74	6	chemistry	chemistry	NOUN
eurjchem-1774	74	7	–	–	PUNCT
eurjchem-1774	74	8	cc	cc	NOUN
eurjchem-1774	74	9	by	by	ADP
eurjchem-1774	74	10	nc	nc	PROPN
eurjchem-1774	74	11	–	–	PUNCT
eurjchem-1774	74	12	doi	doi	PROPN
eurjchem-1774	74	13	:	:	PUNCT
eurjchem-1774	74	14	10.5155	10.5155	NUM
eurjchem-1774	74	15	/	/	SYM
eurjchem-1774	74	16	eurjchem.9.4.360	eurjchem.9.4.360	NOUN
eurjchem-1774	74	17	-	-	SYM
eurjchem-1774	74	18	368.1774	368.1774	NUM
eurjchem-1774	74	19	362	362	NUM
eurjchem-1774	74	20	keskin	keskin	NOUN
eurjchem-1774	74	21	et	et	PROPN
eurjchem-1774	74	22	al	al	PROPN
eurjchem-1774	74	23	.	.	PUNCT
eurjchem-1774	74	24	/	/	SYM
eurjchem-1774	74	25	european	european	PROPN
eurjchem-1774	74	26	journal	journal	PROPN
eurjchem-1774	74	27	of	of	ADP
eurjchem-1774	74	28	chemistry	chemistry	NOUN
eurjchem-1774	74	29	9	9	NUM
eurjchem-1774	74	30	(	(	PUNCT
eurjchem-1774	74	31	4	4	NUM
eurjchem-1774	74	32	)	)	PUNCT
eurjchem-1774	74	33	(	(	PUNCT
eurjchem-1774	74	34	2018	2018	NUM
eurjchem-1774	74	35	)	)	PUNCT
eurjchem-1774	74	36	360	360	NUM
eurjchem-1774	74	37	-	-	SYM
eurjchem-1774	74	38	368	368	NUM
eurjchem-1774	74	39	scheme	scheme	NOUN
eurjchem-1774	74	40	2	2	NUM
eurjchem-1774	74	41	.	.	PUNCT
eurjchem-1774	74	42	synthesis	synthesis	NOUN
eurjchem-1774	74	43	of	of	ADP
eurjchem-1774	74	44	thiourea	thiourea	NOUN
eurjchem-1774	74	45	complexes	complex	NOUN
eurjchem-1774	74	46	.	.	PUNCT
eurjchem-1774	75	1	figure	figure	NOUN
eurjchem-1774	75	2	1	1	NUM
eurjchem-1774	75	3	.	.	PUNCT
eurjchem-1774	75	4	cosy	cosy	PROPN
eurjchem-1774	75	5	nmr	nmr	NOUN
eurjchem-1774	75	6	spectrum	spectrum	NOUN
eurjchem-1774	75	7	of	of	ADP
eurjchem-1774	75	8	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	75	9	-	-	PUNCT
eurjchem-1774	75	10	s	s	PROPN
eurjchem-1774	75	11	,	,	PUNCT
eurjchem-1774	75	12	o)2	o)2	NOUN
eurjchem-1774	75	13	]	]	PUNCT
eurjchem-1774	75	14	complex	complex	NOUN
eurjchem-1774	75	15	.	.	PUNCT
eurjchem-1774	76	1	the	the	DET
eurjchem-1774	76	2	nmr	nmr	NOUN
eurjchem-1774	76	3	data	datum	NOUN
eurjchem-1774	76	4	of	of	ADP
eurjchem-1774	76	5	the	the	DET
eurjchem-1774	76	6	compounds	compound	NOUN
eurjchem-1774	76	7	are	be	AUX
eurjchem-1774	76	8	given	give	VERB
eurjchem-1774	76	9	in	in	ADP
eurjchem-1774	76	10	the	the	DET
eurjchem-1774	76	11	experimental	experimental	ADJ
eurjchem-1774	76	12	section	section	NOUN
eurjchem-1774	76	13	and	and	CCONJ
eurjchem-1774	76	14	are	be	AUX
eurjchem-1774	76	15	consistent	consistent	ADJ
eurjchem-1774	76	16	with	with	ADP
eurjchem-1774	76	17	the	the	DET
eurjchem-1774	76	18	structural	structural	ADJ
eurjchem-1774	76	19	results	result	NOUN
eurjchem-1774	76	20	.	.	PUNCT
eurjchem-1774	77	1	in	in	ADP
eurjchem-1774	77	2	the	the	DET
eurjchem-1774	77	3	1h	1h	NUM
eurjchem-1774	77	4	nmr	nmr	NOUN
eurjchem-1774	77	5	of	of	ADP
eurjchem-1774	77	6	the	the	DET
eurjchem-1774	77	7	ligands	ligand	NOUN
eurjchem-1774	77	8	(	(	PUNCT
eurjchem-1774	77	9	hl1,2	hl1,2	ADJ
eurjchem-1774	77	10	)	)	PUNCT
eurjchem-1774	77	11	characteristic	characteristic	ADJ
eurjchem-1774	77	12	nh	nh	PROPN
eurjchem-1774	77	13	proton	proton	NOUN
eurjchem-1774	77	14	signals	signal	NOUN
eurjchem-1774	77	15	were	be	AUX
eurjchem-1774	77	16	observed	observe	VERB
eurjchem-1774	77	17	at	at	ADP
eurjchem-1774	77	18	δ	δ	PROPN
eurjchem-1774	77	19	8.42	8.42	NUM
eurjchem-1774	77	20	and	and	CCONJ
eurjchem-1774	77	21	8.38	8.38	NUM
eurjchem-1774	77	22	ppm	ppm	NOUN
eurjchem-1774	77	23	,	,	PUNCT
eurjchem-1774	77	24	respectively	respectively	ADV
eurjchem-1774	77	25	,	,	PUNCT
eurjchem-1774	77	26	as	as	ADP
eurjchem-1774	77	27	a	a	DET
eurjchem-1774	77	28	singlet	singlet	NOUN
eurjchem-1774	77	29	.	.	PUNCT
eurjchem-1774	78	1	after	after	ADP
eurjchem-1774	78	2	the	the	DET
eurjchem-1774	78	3	complexation	complexation	NOUN
eurjchem-1774	78	4	,	,	PUNCT
eurjchem-1774	78	5	the	the	DET
eurjchem-1774	78	6	signals	signal	NOUN
eurjchem-1774	78	7	that	that	PRON
eurjchem-1774	78	8	belong	belong	VERB
eurjchem-1774	78	9	to	to	ADP
eurjchem-1774	78	10	nh	nh	PROPN
eurjchem-1774	78	11	group	group	NOUN
eurjchem-1774	78	12	were	be	AUX
eurjchem-1774	78	13	not	not	PART
eurjchem-1774	78	14	observed	observe	VERB
eurjchem-1774	78	15	due	due	ADP
eurjchem-1774	78	16	to	to	ADP
eurjchem-1774	78	17	the	the	DET
eurjchem-1774	78	18	deprotonation	deprotonation	NOUN
eurjchem-1774	78	19	.	.	PUNCT
eurjchem-1774	79	1	the	the	DET
eurjchem-1774	79	2	ligands	ligand	NOUN
eurjchem-1774	79	3	have	have	AUX
eurjchem-1774	79	4	shown	show	VERB
eurjchem-1774	79	5	bidentate	bidentate	NOUN
eurjchem-1774	79	6	coordination	coordination	NOUN
eurjchem-1774	79	7	via	via	ADP
eurjchem-1774	79	8	the	the	DET
eurjchem-1774	79	9	sulfur	sulfur	NOUN
eurjchem-1774	79	10	and	and	CCONJ
eurjchem-1774	79	11	oxygen	oxygen	NOUN
eurjchem-1774	79	12	atoms	atom	NOUN
eurjchem-1774	79	13	to	to	PART
eurjchem-1774	79	14	platinum	platinum	VERB
eurjchem-1774	79	15	metal	metal	NOUN
eurjchem-1774	79	16	atom	atom	NOUN
eurjchem-1774	79	17	.	.	PUNCT
eurjchem-1774	80	1	slight	slight	ADJ
eurjchem-1774	80	2	diffrences	diffrence	NOUN
eurjchem-1774	80	3	were	be	AUX
eurjchem-1774	80	4	observed	observe	VERB
eurjchem-1774	80	5	in	in	ADP
eurjchem-1774	80	6	the	the	DET
eurjchem-1774	80	7	1h	1h	NUM
eurjchem-1774	80	8	nmr	nmr	NOUN
eurjchem-1774	80	9	spectra	spectra	NOUN
eurjchem-1774	80	10	of	of	ADP
eurjchem-1774	80	11	the	the	DET
eurjchem-1774	80	12	complexes	complex	NOUN
eurjchem-1774	80	13	related	relate	VERB
eurjchem-1774	80	14	to	to	ADP
eurjchem-1774	80	15	attached	attach	VERB
eurjchem-1774	80	16	subtituent	subtituent	NOUN
eurjchem-1774	80	17	groups	group	NOUN
eurjchem-1774	80	18	(	(	PUNCT
eurjchem-1774	80	19	f	f	PROPN
eurjchem-1774	80	20	or	or	CCONJ
eurjchem-1774	80	21	br	br	NOUN
eurjchem-1774	80	22	)	)	PUNCT
eurjchem-1774	80	23	,	,	PUNCT
eurjchem-1774	80	24	altering	alter	VERB
eurjchem-1774	80	25	the	the	DET
eurjchem-1774	80	26	electronic	electronic	ADJ
eurjchem-1774	80	27	structure	structure	NOUN
eurjchem-1774	80	28	of	of	ADP
eurjchem-1774	80	29	the	the	DET
eurjchem-1774	80	30	ligand	ligand	NOUN
eurjchem-1774	80	31	.	.	PUNCT
eurjchem-1774	81	1	the	the	DET
eurjchem-1774	81	2	signals	signal	NOUN
eurjchem-1774	81	3	for	for	ADP
eurjchem-1774	81	4	the	the	DET
eurjchem-1774	81	5	aromatic	aromatic	ADJ
eurjchem-1774	81	6	protons	proton	NOUN
eurjchem-1774	81	7	were	be	AUX
eurjchem-1774	81	8	observed	observe	VERB
eurjchem-1774	81	9	in	in	ADP
eurjchem-1774	81	10	the	the	DET
eurjchem-1774	81	11	range	range	NOUN
eurjchem-1774	81	12	of	of	ADP
eurjchem-1774	81	13	δ	δ	PROPN
eurjchem-1774	81	14	7.15	7.15	NUM
eurjchem-1774	81	15	-	-	SYM
eurjchem-1774	81	16	7.86	7.86	NUM
eurjchem-1774	81	17	ppm	ppm	NOUN
eurjchem-1774	81	18	for	for	ADP
eurjchem-1774	81	19	each	each	DET
eurjchem-1774	81	20	ligand	ligand	NOUN
eurjchem-1774	81	21	,	,	PUNCT
eurjchem-1774	81	22	with	with	ADP
eurjchem-1774	81	23	small	small	ADJ
eurjchem-1774	81	24	differences	difference	NOUN
eurjchem-1774	81	25	in	in	ADP
eurjchem-1774	81	26	their	their	PRON
eurjchem-1774	81	27	environments	environment	NOUN
eurjchem-1774	81	28	.	.	PUNCT
eurjchem-1774	82	1	after	after	ADP
eurjchem-1774	82	2	the	the	DET
eurjchem-1774	82	3	metalation	metalation	NOUN
eurjchem-1774	82	4	,	,	PUNCT
eurjchem-1774	82	5	diffrently	diffrently	ADV
eurjchem-1774	82	6	from	from	ADP
eurjchem-1774	82	7	the	the	DET
eurjchem-1774	82	8	free	free	ADJ
eurjchem-1774	82	9	ligand	ligand	NOUN
eurjchem-1774	82	10	,	,	PUNCT
eurjchem-1774	82	11	the	the	DET
eurjchem-1774	82	12	aromatic	aromatic	ADJ
eurjchem-1774	82	13	proton	proton	NOUN
eurjchem-1774	82	14	resonance	resonance	NOUN
eurjchem-1774	82	15	values	value	NOUN
eurjchem-1774	82	16	shifted	shift	VERB
eurjchem-1774	82	17	to	to	ADP
eurjchem-1774	82	18	downfield	downfield	NOUN
eurjchem-1774	82	19	,	,	PUNCT
eurjchem-1774	82	20	between	between	ADP
eurjchem-1774	82	21	the	the	DET
eurjchem-1774	82	22	range	range	NOUN
eurjchem-1774	82	23	of	of	ADP
eurjchem-1774	82	24	δ	δ	PROPN
eurjchem-1774	82	25	~7	~7	NOUN
eurjchem-1774	82	26	-	-	PUNCT
eurjchem-1774	82	27	8	8	NUM
eurjchem-1774	82	28	ppm	ppm	NOUN
eurjchem-1774	82	29	.	.	PUNCT
eurjchem-1774	83	1	the	the	DET
eurjchem-1774	83	2	resonance	resonance	NOUN
eurjchem-1774	83	3	values	value	NOUN
eurjchem-1774	83	4	,	,	PUNCT
eurjchem-1774	83	5	obtained	obtain	VERB
eurjchem-1774	83	6	from	from	ADP
eurjchem-1774	83	7	the	the	DET
eurjchem-1774	83	8	1h	1h	NUM
eurjchem-1774	83	9	nmr	nmr	NOUN
eurjchem-1774	83	10	spectra	spectra	NOUN
eurjchem-1774	83	11	of	of	ADP
eurjchem-1774	83	12	the	the	DET
eurjchem-1774	83	13	complexes	complex	NOUN
eurjchem-1774	83	14	,	,	PUNCT
eurjchem-1774	83	15	were	be	AUX
eurjchem-1774	83	16	almost	almost	ADV
eurjchem-1774	83	17	similar	similar	ADJ
eurjchem-1774	83	18	.	.	PUNCT
eurjchem-1774	84	1	the	the	DET
eurjchem-1774	84	2	most	most	ADV
eurjchem-1774	84	3	observed	observed	ADJ
eurjchem-1774	84	4	distinct	distinct	ADJ
eurjchem-1774	84	5	shift	shift	NOUN
eurjchem-1774	84	6	values	value	NOUN
eurjchem-1774	84	7	were	be	AUX
eurjchem-1774	84	8	aliphatic	aliphatic	ADJ
eurjchem-1774	84	9	protons	proton	NOUN
eurjchem-1774	84	10	in	in	ADP
eurjchem-1774	84	11	cis[pt(l2	cis[pt(l2	PROPN
eurjchem-1774	84	12	-	-	PUNCT
eurjchem-1774	84	13	s	s	PROPN
eurjchem-1774	84	14	,	,	PUNCT
eurjchem-1774	84	15	o)2	o)2	NOUN
eurjchem-1774	84	16	]	]	PUNCT
eurjchem-1774	84	17	comp	comp	NOUN
eurjchem-1774	84	18	-	-	PUNCT
eurjchem-1774	84	19	lexes	lexe	NOUN
eurjchem-1774	84	20	.	.	PUNCT
eurjchem-1774	85	1	compared	compare	VERB
eurjchem-1774	85	2	to	to	ADP
eurjchem-1774	85	3	free	free	ADJ
eurjchem-1774	85	4	ligands	ligand	NOUN
eurjchem-1774	85	5	,	,	PUNCT
eurjchem-1774	85	6	the	the	DET
eurjchem-1774	85	7	resonance	resonance	NOUN
eurjchem-1774	85	8	values	value	NOUN
eurjchem-1774	85	9	that	that	PRON
eurjchem-1774	85	10	were	be	AUX
eurjchem-1774	85	11	obtained	obtain	VERB
eurjchem-1774	85	12	for	for	ADP
eurjchem-1774	85	13	the	the	DET
eurjchem-1774	85	14	aliphatic	aliphatic	ADJ
eurjchem-1774	85	15	protons	proton	NOUN
eurjchem-1774	85	16	shifted	shift	VERB
eurjchem-1774	85	17	to	to	PART
eurjchem-1774	85	18	upfield	upfield	VERB
eurjchem-1774	85	19	,	,	PUNCT
eurjchem-1774	85	20	only	only	ADV
eurjchem-1774	85	21	the	the	DET
eurjchem-1774	85	22	observed	observed	ADJ
eurjchem-1774	85	23	signals	signal	NOUN
eurjchem-1774	85	24	,	,	PUNCT
eurjchem-1774	85	25	which	which	PRON
eurjchem-1774	85	26	belong	belong	VERB
eurjchem-1774	85	27	to	to	ADP
eurjchem-1774	85	28	the	the	DET
eurjchem-1774	85	29	methyl	methyl	NOUN
eurjchem-1774	85	30	group	group	NOUN
eurjchem-1774	85	31	shifted	shift	VERB
eurjchem-1774	85	32	to	to	ADP
eurjchem-1774	85	33	downfield	downfield	VERB
eurjchem-1774	85	34	region	region	NOUN
eurjchem-1774	85	35	in	in	ADP
eurjchem-1774	85	36	cis-[pt(l1s	cis-[pt(l1s	ADJ
eurjchem-1774	85	37	,	,	PUNCT
eurjchem-1774	85	38	o)2	o)2	PROPN
eurjchem-1774	85	39	]	]	PUNCT
eurjchem-1774	85	40	and	and	CCONJ
eurjchem-1774	85	41	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	85	42	-	-	PUNCT
eurjchem-1774	85	43	s	s	PROPN
eurjchem-1774	85	44	,	,	PUNCT
eurjchem-1774	85	45	o)2	o)2	NOUN
eurjchem-1774	85	46	]	]	PUNCT
eurjchem-1774	85	47	complexes	complex	NOUN
eurjchem-1774	85	48	.	.	PUNCT
eurjchem-1774	86	1	in	in	ADP
eurjchem-1774	86	2	13c	13c	NUM
eurjchem-1774	86	3	nmr	nmr	NOUN
eurjchem-1774	86	4	spectrum	spectrum	NOUN
eurjchem-1774	86	5	of	of	ADP
eurjchem-1774	86	6	free	free	ADJ
eurjchem-1774	86	7	ligands	ligand	NOUN
eurjchem-1774	86	8	,	,	PUNCT
eurjchem-1774	86	9	thiocarbonyl	thiocarbonyl	NOUN
eurjchem-1774	86	10	(	(	PUNCT
eurjchem-1774	86	11	c	c	NOUN
eurjchem-1774	86	12	=	=	SYM
eurjchem-1774	86	13	s	s	NOUN
eurjchem-1774	86	14	)	)	PUNCT
eurjchem-1774	86	15	and	and	CCONJ
eurjchem-1774	86	16	carbonyl	carbonyl	NOUN
eurjchem-1774	86	17	(	(	PUNCT
eurjchem-1774	86	18	c	c	NOUN
eurjchem-1774	86	19	=	=	NOUN
eurjchem-1774	86	20	o	o	NOUN
eurjchem-1774	86	21	)	)	PUNCT
eurjchem-1774	86	22	carbons	carbon	NOUN
eurjchem-1774	86	23	appeared	appear	VERB
eurjchem-1774	86	24	at	at	ADP
eurjchem-1774	86	25	δ	δ	PROPN
eurjchem-1774	86	26	180	180	NUM
eurjchem-1774	86	27	-	-	SYM
eurjchem-1774	86	28	162	162	NUM
eurjchem-1774	86	29	ppm	ppm	NOUN
eurjchem-1774	86	30	range	range	NOUN
eurjchem-1774	86	31	.	.	PUNCT
eurjchem-1774	87	1	it	it	PRON
eurjchem-1774	87	2	has	have	AUX
eurjchem-1774	87	3	been	be	AUX
eurjchem-1774	87	4	observed	observe	VERB
eurjchem-1774	87	5	from	from	ADP
eurjchem-1774	87	6	the	the	DET
eurjchem-1774	87	7	13c	13c	NOUN
eurjchem-1774	87	8	nmr	nmr	NOUN
eurjchem-1774	87	9	spectra	spectra	NOUN
eurjchem-1774	87	10	of	of	ADP
eurjchem-1774	87	11	the	the	DET
eurjchem-1774	87	12	complexes	complex	NOUN
eurjchem-1774	87	13	,	,	PUNCT
eurjchem-1774	87	14	that	that	SCONJ
eurjchem-1774	87	15	the	the	DET
eurjchem-1774	87	16	c	c	PROPN
eurjchem-1774	87	17	–	–	PUNCT
eurjchem-1774	87	18	s	s	NOUN
eurjchem-1774	87	19	carbon	carbon	NOUN
eurjchem-1774	87	20	resonance	resonance	NOUN
eurjchem-1774	87	21	values	value	NOUN
eurjchem-1774	87	22	shifted	shift	VERB
eurjchem-1774	87	23	to	to	PART
eurjchem-1774	87	24	upfield	upfield	VERB
eurjchem-1774	87	25	while	while	SCONJ
eurjchem-1774	87	26	the	the	DET
eurjchem-1774	87	27	resonance	resonance	NOUN
eurjchem-1774	87	28	values	value	NOUN
eurjchem-1774	87	29	of	of	ADP
eurjchem-1774	87	30	the	the	DET
eurjchem-1774	87	31	c	c	PROPN
eurjchem-1774	87	32	–	–	PUNCT
eurjchem-1774	87	33	o	o	NOUN
eurjchem-1774	87	34	appeared	appear	VERB
eurjchem-1774	87	35	at	at	ADP
eurjchem-1774	87	36	the	the	DET
eurjchem-1774	87	37	downfield	downfield	NOUN
eurjchem-1774	87	38	region	region	NOUN
eurjchem-1774	87	39	for	for	ADP
eurjchem-1774	87	40	both	both	DET
eurjchem-1774	87	41	complexes	complex	NOUN
eurjchem-1774	87	42	as	as	ADP
eurjchem-1774	87	43	a	a	DET
eurjchem-1774	87	44	result	result	NOUN
eurjchem-1774	87	45	of	of	ADP
eurjchem-1774	87	46	the	the	DET
eurjchem-1774	87	47	complexation	complexation	NOUN
eurjchem-1774	87	48	process	process	NOUN
eurjchem-1774	87	49	.	.	PUNCT
eurjchem-1774	88	1	the	the	DET
eurjchem-1774	88	2	two	two	NUM
eurjchem-1774	88	3	-	-	PUNCT
eurjchem-1774	88	4	dimensional	dimensional	ADJ
eurjchem-1774	88	5	nuclear	nuclear	ADJ
eurjchem-1774	88	6	magnetic	magnetic	ADJ
eurjchem-1774	88	7	resonance	resonance	NOUN
eurjchem-1774	88	8	spectra	spectra	NOUN
eurjchem-1774	88	9	is	be	AUX
eurjchem-1774	88	10	used	use	VERB
eurjchem-1774	88	11	for	for	ADP
eurjchem-1774	88	12	resolving	resolve	VERB
eurjchem-1774	88	13	the	the	DET
eurjchem-1774	88	14	interactions	interaction	NOUN
eurjchem-1774	88	15	between	between	ADP
eurjchem-1774	88	16	carbon	carbon	NOUN
eurjchem-1774	88	17	and	and	CCONJ
eurjchem-1774	88	18	hydrogen	hydrogen	NOUN
eurjchem-1774	88	19	atoms	atom	NOUN
eurjchem-1774	88	20	,	,	PUNCT
eurjchem-1774	88	21	or	or	CCONJ
eurjchem-1774	88	22	neighboring	neighboring	NOUN
eurjchem-1774	88	23	protons	proton	NOUN
eurjchem-1774	88	24	.	.	PUNCT
eurjchem-1774	89	1	these	these	DET
eurjchem-1774	89	2	spectral	spectral	ADJ
eurjchem-1774	89	3	analysis	analysis	NOUN
eurjchem-1774	89	4	are	be	AUX
eurjchem-1774	89	5	based	base	VERB
eurjchem-1774	89	6	on	on	ADP
eurjchem-1774	89	7	effective	effective	ADJ
eurjchem-1774	89	8	magnetic	magnetic	ADJ
eurjchem-1774	89	9	fields	field	NOUN
eurjchem-1774	89	10	,	,	PUNCT
eurjchem-1774	89	11	interactions	interaction	NOUN
eurjchem-1774	89	12	of	of	ADP
eurjchem-1774	89	13	the	the	DET
eurjchem-1774	89	14	nuclear	nuclear	ADJ
eurjchem-1774	89	15	spin	spin	NOUN
eurjchem-1774	89	16	with	with	ADP
eurjchem-1774	89	17	adjacent	adjacent	ADJ
eurjchem-1774	89	18	atoms	atom	NOUN
eurjchem-1774	89	19	and	and	CCONJ
eurjchem-1774	89	20	the	the	DET
eurjchem-1774	89	21	number	number	NOUN
eurjchem-1774	89	22	of	of	ADP
eurjchem-1774	89	23	equivalent	equivalent	ADJ
eurjchem-1774	89	24	protons	proton	NOUN
eurjchem-1774	89	25	.	.	PUNCT
eurjchem-1774	90	1	to	to	PART
eurjchem-1774	90	2	elucidate	elucidate	VERB
eurjchem-1774	90	3	the	the	DET
eurjchem-1774	90	4	structures	structure	NOUN
eurjchem-1774	90	5	of	of	ADP
eurjchem-1774	90	6	compounds	compound	NOUN
eurjchem-1774	90	7	,	,	PUNCT
eurjchem-1774	90	8	2d	2d	NUM
eurjchem-1774	90	9	nmr	nmr	NOUN
eurjchem-1774	90	10	experiments	experiment	NOUN
eurjchem-1774	90	11	(	(	PUNCT
eurjchem-1774	90	12	hmqc	hmqc	PROPN
eurjchem-1774	90	13	and	and	CCONJ
eurjchem-1774	90	14	cosy	cosy	PROPN
eurjchem-1774	90	15	)	)	PUNCT
eurjchem-1774	90	16	were	be	AUX
eurjchem-1774	90	17	carried	carry	VERB
eurjchem-1774	90	18	out	out	ADP
eurjchem-1774	90	19	.	.	PUNCT
eurjchem-1774	91	1	according	accord	VERB
eurjchem-1774	91	2	to	to	ADP
eurjchem-1774	91	3	the	the	DET
eurjchem-1774	91	4	cosy	cosy	ADJ
eurjchem-1774	91	5	spectrum	spectrum	NOUN
eurjchem-1774	91	6	of	of	ADP
eurjchem-1774	91	7	the	the	DET
eurjchem-1774	91	8	platinum	platinum	NOUN
eurjchem-1774	91	9	complexes	complex	NOUN
eurjchem-1774	91	10	,	,	PUNCT
eurjchem-1774	91	11	for	for	ADP
eurjchem-1774	91	12	the	the	DET
eurjchem-1774	91	13	benzamide	benzamide	NOUN
eurjchem-1774	91	14	moiety	moiety	NOUN
eurjchem-1774	91	15	,	,	PUNCT
eurjchem-1774	91	16	correlations	correlation	NOUN
eurjchem-1774	91	17	between	between	ADP
eurjchem-1774	91	18	aromatic	aromatic	ADJ
eurjchem-1774	91	19	protons	proton	NOUN
eurjchem-1774	91	20	were	be	AUX
eurjchem-1774	91	21	observed	observe	VERB
eurjchem-1774	91	22	at	at	ADP
eurjchem-1774	91	23	δ	δ	PROPN
eurjchem-1774	91	24	8.16	8.16	NUM
eurjchem-1774	91	25	;	;	PUNCT
eurjchem-1774	91	26	7.00	7.00	NUM
eurjchem-1774	91	27	and	and	CCONJ
eurjchem-1774	91	28	8.15	8.15	NUM
eurjchem-1774	91	29	;	;	PUNCT
eurjchem-1774	91	30	6.99	6.99	NUM
eurjchem-1774	91	31	ppm	ppm	NOUN
eurjchem-1774	91	32	for	for	ADP
eurjchem-1774	91	33	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	91	34	-	-	PUNCT
eurjchem-1774	91	35	s	s	PROPN
eurjchem-1774	91	36	,	,	PUNCT
eurjchem-1774	91	37	o)2	o)2	PROPN
eurjchem-1774	91	38	]	]	PUNCT
eurjchem-1774	91	39	and	and	CCONJ
eurjchem-1774	91	40	δ	δ	PROPN
eurjchem-1774	91	41	8.12;7.58	8.12;7.58	NUM
eurjchem-1774	91	42	and	and	CCONJ
eurjchem-1774	91	43	8.10	8.10	NUM
eurjchem-1774	91	44	;	;	PUNCT
eurjchem-1774	91	45	7.57	7.57	NUM
eurjchem-1774	91	46	ppm	ppm	NOUN
eurjchem-1774	91	47	for	for	ADP
eurjchem-1774	91	48	cis[pt(l2	cis[pt(l2	PROPN
eurjchem-1774	91	49	-	-	PUNCT
eurjchem-1774	91	50	s	s	PROPN
eurjchem-1774	91	51	,	,	PUNCT
eurjchem-1774	91	52	o)2	o)2	NOUN
eurjchem-1774	91	53	]	]	PUNCT
eurjchem-1774	91	54	complexes	complex	NOUN
eurjchem-1774	91	55	,	,	PUNCT
eurjchem-1774	91	56	respectively	respectively	ADV
eurjchem-1774	91	57	.	.	PUNCT
eurjchem-1774	92	1	in	in	ADP
eurjchem-1774	92	2	addition	addition	NOUN
eurjchem-1774	92	3	,	,	PUNCT
eurjchem-1774	92	4	the	the	DET
eurjchem-1774	92	5	cosy	cosy	NOUN
eurjchem-1774	92	6	spectrum	spectrum	NOUN
eurjchem-1774	92	7	of	of	ADP
eurjchem-1774	92	8	the	the	DET
eurjchem-1774	92	9	complexes	complex	NOUN
eurjchem-1774	92	10	revealed	reveal	VERB
eurjchem-1774	92	11	the	the	DET
eurjchem-1774	92	12	ch2	ch2	PROPN
eurjchem-1774	92	13	-	-	PUNCT
eurjchem-1774	92	14	ch2	ch2	PROPN
eurjchem-1774	92	15	and	and	CCONJ
eurjchem-1774	92	16	ch2	ch2	PROPN
eurjchem-1774	92	17	-	-	PUNCT
eurjchem-1774	92	18	ch3	ch3	PROPN
eurjchem-1774	92	19	interactions	interaction	NOUN
eurjchem-1774	92	20	between	between	ADP
eurjchem-1774	92	21	aliphatic	aliphatic	ADJ
eurjchem-1774	92	22	neighboring	neighboring	NOUN
eurjchem-1774	92	23	protons	proton	NOUN
eurjchem-1774	92	24	(	(	PUNCT
eurjchem-1774	92	25	figures	figure	NOUN
eurjchem-1774	92	26	1	1	NUM
eurjchem-1774	92	27	and	and	CCONJ
eurjchem-1774	92	28	2	2	NUM
eurjchem-1774	92	29	)	)	PUNCT
eurjchem-1774	92	30	.	.	PUNCT
eurjchem-1774	93	1	ch2	ch2	PROPN
eurjchem-1774	93	2	-	-	PUNCT
eurjchem-1774	93	3	ch2	ch2	NOUN
eurjchem-1774	93	4	interactions	interaction	NOUN
eurjchem-1774	93	5	were	be	AUX
eurjchem-1774	93	6	detected	detect	VERB
eurjchem-1774	93	7	between	between	ADP
eurjchem-1774	93	8	the	the	DET
eurjchem-1774	93	9	peaks	peak	NOUN
eurjchem-1774	93	10	,	,	PUNCT
eurjchem-1774	93	11	appearing	appear	VERB
eurjchem-1774	93	12	as	as	ADP
eurjchem-1774	93	13	a	a	DET
eurjchem-1774	93	14	quartet	quartet	NOUN
eurjchem-1774	93	15	close	close	ADJ
eurjchem-1774	93	16	to	to	ADP
eurjchem-1774	93	17	the	the	DET
eurjchem-1774	93	18	electronegative	electronegative	ADJ
eurjchem-1774	93	19	n	n	CCONJ
eurjchem-1774	93	20	atom	atom	NOUN
eurjchem-1774	93	21	and	and	CCONJ
eurjchem-1774	93	22	as	as	ADP
eurjchem-1774	93	23	a	a	DET
eurjchem-1774	93	24	pentet	pentet	NOUN
eurjchem-1774	93	25	,	,	PUNCT
eurjchem-1774	93	26	for	for	ADP
eurjchem-1774	93	27	both	both	DET
eurjchem-1774	93	28	complexes	complex	NOUN
eurjchem-1774	93	29	.	.	PUNCT
eurjchem-1774	94	1	also	also	ADV
eurjchem-1774	94	2	,	,	PUNCT
eurjchem-1774	94	3	the	the	DET
eurjchem-1774	94	4	correlations	correlation	NOUN
eurjchem-1774	94	5	of	of	ADP
eurjchem-1774	94	6	ch2ch3	ch2ch3	ADJ
eurjchem-1774	94	7	protons	proton	NOUN
eurjchem-1774	94	8	were	be	AUX
eurjchem-1774	94	9	observed	observe	VERB
eurjchem-1774	94	10	between	between	ADP
eurjchem-1774	94	11	the	the	DET
eurjchem-1774	94	12	peaks	peak	NOUN
eurjchem-1774	94	13	at	at	ADP
eurjchem-1774	94	14	δ	δ	PROPN
eurjchem-1774	94	15	1.65	1.65	NUM
eurjchem-1774	94	16	(	(	PUNCT
eurjchem-1774	94	17	ch2	ch2	PROPN
eurjchem-1774	94	18	)	)	PUNCT
eurjchem-1774	94	19	with	with	ADP
eurjchem-1774	94	20	0.86	0.86	NUM
eurjchem-1774	94	21	(	(	PUNCT
eurjchem-1774	94	22	ch3	ch3	PROPN
eurjchem-1774	94	23	)	)	PUNCT
eurjchem-1774	94	24	and	and	CCONJ
eurjchem-1774	94	25	1.67	1.67	NUM
eurjchem-1774	94	26	(	(	PUNCT
eurjchem-1774	94	27	ch2	ch2	PROPN
eurjchem-1774	94	28	)	)	PUNCT
eurjchem-1774	94	29	with	with	ADP
eurjchem-1774	94	30	0.85	0.85	NUM
eurjchem-1774	94	31	(	(	PUNCT
eurjchem-1774	94	32	ch3	ch3	PROPN
eurjchem-1774	94	33	)	)	PUNCT
eurjchem-1774	94	34	ppm	ppm	NOUN
eurjchem-1774	94	35	for	for	ADP
eurjchem-1774	94	36	cis[pt(l1	cis[pt(l1	PROPN
eurjchem-1774	94	37	-	-	PUNCT
eurjchem-1774	94	38	s	s	PROPN
eurjchem-1774	94	39	,	,	PUNCT
eurjchem-1774	94	40	o)2	o)2	NOUN
eurjchem-1774	94	41	]	]	PUNCT
eurjchem-1774	94	42	complex	complex	NOUN
eurjchem-1774	94	43	and	and	CCONJ
eurjchem-1774	94	44	between	between	ADP
eurjchem-1774	94	45	the	the	DET
eurjchem-1774	94	46	peaks	peak	NOUN
eurjchem-1774	94	47	at	at	ADP
eurjchem-1774	94	48	δ	δ	PROPN
eurjchem-1774	94	49	1.77	1.77	NUM
eurjchem-1774	94	50	(	(	PUNCT
eurjchem-1774	94	51	ch2	ch2	PROPN
eurjchem-1774	94	52	)	)	PUNCT
eurjchem-1774	94	53	with	with	ADP
eurjchem-1774	94	54	0.97	0.97	NUM
eurjchem-1774	94	55	(	(	PUNCT
eurjchem-1774	94	56	ch3	ch3	PROPN
eurjchem-1774	94	57	)	)	PUNCT
eurjchem-1774	94	58	and	and	CCONJ
eurjchem-1774	94	59	1.83	1.83	NUM
eurjchem-1774	94	60	(	(	PUNCT
eurjchem-1774	94	61	ch2	ch2	PROPN
eurjchem-1774	94	62	)	)	PUNCT
eurjchem-1774	94	63	with	with	ADP
eurjchem-1774	94	64	0.99	0.99	NUM
eurjchem-1774	94	65	(	(	PUNCT
eurjchem-1774	94	66	ch3	ch3	PROPN
eurjchem-1774	94	67	)	)	PUNCT
eurjchem-1774	94	68	ppm	ppm	NOUN
eurjchem-1774	94	69	for	for	ADP
eurjchem-1774	94	70	cis[pt(l2	cis[pt(l2	PROPN
eurjchem-1774	94	71	-	-	PUNCT
eurjchem-1774	94	72	s	s	PROPN
eurjchem-1774	94	73	,	,	PUNCT
eurjchem-1774	94	74	o)2	o)2	NOUN
eurjchem-1774	94	75	]	]	PUNCT
eurjchem-1774	94	76	complex	complex	NOUN
eurjchem-1774	94	77	(	(	PUNCT
eurjchem-1774	94	78	figures	figure	NOUN
eurjchem-1774	94	79	1	1	NUM
eurjchem-1774	94	80	and	and	CCONJ
eurjchem-1774	94	81	2	2	NUM
eurjchem-1774	94	82	)	)	PUNCT
eurjchem-1774	94	83	.	.	PUNCT
eurjchem-1774	95	1	the	the	DET
eurjchem-1774	95	2	hmqc	hmqc	PROPN
eurjchem-1774	95	3	shows	show	VERB
eurjchem-1774	95	4	the	the	DET
eurjchem-1774	95	5	interactions	interaction	NOUN
eurjchem-1774	95	6	between	between	ADP
eurjchem-1774	95	7	the	the	DET
eurjchem-1774	95	8	protons	proton	NOUN
eurjchem-1774	95	9	and	and	CCONJ
eurjchem-1774	95	10	their	their	PRON
eurjchem-1774	95	11	attached	attached	ADJ
eurjchem-1774	95	12	heteronuclei	heteronuclei	NOUN
eurjchem-1774	95	13	through	through	ADP
eurjchem-1774	95	14	the	the	DET
eurjchem-1774	95	15	heteronuclear	heteronuclear	NOUN
eurjchem-1774	95	16	coupling	coupling	NOUN
eurjchem-1774	95	17	.	.	PUNCT
eurjchem-1774	96	1	in	in	ADP
eurjchem-1774	96	2	the	the	DET
eurjchem-1774	96	3	hmqc	hmqc	PROPN
eurjchem-1774	96	4	spectrum	spectrum	NOUN
eurjchem-1774	96	5	of	of	ADP
eurjchem-1774	96	6	the	the	DET
eurjchem-1774	96	7	complexes	complex	NOUN
eurjchem-1774	96	8	,	,	PUNCT
eurjchem-1774	96	9	it	it	PRON
eurjchem-1774	96	10	is	be	AUX
eurjchem-1774	96	11	evident	evident	ADJ
eurjchem-1774	96	12	that	that	SCONJ
eurjchem-1774	96	13	the	the	DET
eurjchem-1774	96	14	peaks	peak	NOUN
eurjchem-1774	96	15	which	which	PRON
eurjchem-1774	96	16	were	be	AUX
eurjchem-1774	96	17	observed	observe	VERB
eurjchem-1774	96	18	in	in	ADP
eurjchem-1774	96	19	the	the	DET
eurjchem-1774	96	20	13c	13c	NOUN
eurjchem-1774	96	21	nmr	nmr	NOUN
eurjchem-1774	96	22	spectra	spectra	NOUN
eurjchem-1774	96	23	(	(	PUNCT
eurjchem-1774	96	24	δ	δ	PROPN
eurjchem-1774	96	25	167.68	167.68	NUM
eurjchem-1774	96	26	(	(	PUNCT
eurjchem-1774	96	27	c	c	X
eurjchem-1774	96	28	–	–	PUNCT
eurjchem-1774	96	29	s	s	X
eurjchem-1774	96	30	)	)	PUNCT
eurjchem-1774	96	31	and	and	CCONJ
eurjchem-1774	96	32	167.40	167.40	NUM
eurjchem-1774	96	33	(	(	PUNCT
eurjchem-1774	96	34	c	c	NOUN
eurjchem-1774	96	35	–	–	PUNCT
eurjchem-1774	96	36	o	o	NOUN
eurjchem-1774	96	37	)	)	PUNCT
eurjchem-1774	96	38	ppm	ppm	NOUN
eurjchem-1774	96	39	for	for	ADP
eurjchem-1774	96	40	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	96	41	-	-	PUNCT
eurjchem-1774	96	42	s	s	PROPN
eurjchem-1774	96	43	,	,	PUNCT
eurjchem-1774	96	44	o)2	o)2	PROPN
eurjchem-1774	96	45	]	]	PUNCT
eurjchem-1774	96	46	,	,	PUNCT
eurjchem-1774	96	47	167.74	167.74	NUM
eurjchem-1774	96	48	(	(	PUNCT
eurjchem-1774	96	49	c	c	NOUN
eurjchem-1774	96	50	–	–	PUNCT
eurjchem-1774	96	51	s	s	NOUN
eurjchem-1774	96	52	)	)	PUNCT
eurjchem-1774	96	53	and	and	CCONJ
eurjchem-1774	96	54	167.47(c	167.47(c	NUM
eurjchem-1774	96	55	–	–	PUNCT
eurjchem-1774	96	56	o	o	NOUN
eurjchem-1774	96	57	)	)	PUNCT
eurjchem-1774	96	58	ppm	ppm	NOUN
eurjchem-1774	96	59	for	for	ADP
eurjchem-1774	96	60	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	96	61	-	-	PUNCT
eurjchem-1774	96	62	s	s	PROPN
eurjchem-1774	96	63	,	,	PUNCT
eurjchem-1774	96	64	o)2	o)2	PROPN
eurjchem-1774	96	65	]	]	PUNCT
eurjchem-1774	96	66	)	)	PUNCT
eurjchem-1774	96	67	did	do	AUX
eurjchem-1774	96	68	not	not	PART
eurjchem-1774	96	69	appear	appear	VERB
eurjchem-1774	96	70	because	because	SCONJ
eurjchem-1774	96	71	of	of	ADP
eurjchem-1774	96	72	being	be	AUX
eurjchem-1774	96	73	non	non	ADJ
eurjchem-1774	96	74	-	-	ADJ
eurjchem-1774	96	75	protonated	protonated	ADJ
eurjchem-1774	96	76	carbons	carbon	NOUN
eurjchem-1774	96	77	.	.	PUNCT
eurjchem-1774	97	1	the	the	DET
eurjchem-1774	97	2	aromatic	aromatic	ADJ
eurjchem-1774	97	3	and	and	CCONJ
eurjchem-1774	97	4	aliphatic	aliphatic	ADJ
eurjchem-1774	97	5	carbons	carbon	NOUN
eurjchem-1774	97	6	that	that	PRON
eurjchem-1774	97	7	have	have	AUX
eurjchem-1774	97	8	coupled	couple	VERB
eurjchem-1774	97	9	with	with	ADP
eurjchem-1774	97	10	protons	proton	NOUN
eurjchem-1774	97	11	appeared	appear	VERB
eurjchem-1774	97	12	to	to	PART
eurjchem-1774	97	13	be	be	AUX
eurjchem-1774	97	14	compatible	compatible	ADJ
eurjchem-1774	97	15	with	with	ADP
eurjchem-1774	97	16	the	the	DET
eurjchem-1774	97	17	peaks	peak	NOUN
eurjchem-1774	97	18	in	in	ADP
eurjchem-1774	97	19	the	the	DET
eurjchem-1774	97	20	hmqc	hmqc	PROPN
eurjchem-1774	97	21	spectra	spectra	PROPN
eurjchem-1774	97	22	.	.	PUNCT
eurjchem-1774	98	1	besides	besides	SCONJ
eurjchem-1774	98	2	,	,	PUNCT
eurjchem-1774	98	3	the	the	DET
eurjchem-1774	98	4	interactions	interaction	NOUN
eurjchem-1774	98	5	between	between	ADP
eurjchem-1774	98	6	carbon	carbon	NOUN
eurjchem-1774	98	7	and	and	CCONJ
eurjchem-1774	98	8	proton	proton	NOUN
eurjchem-1774	98	9	atoms	atom	NOUN
eurjchem-1774	98	10	,	,	PUNCT
eurjchem-1774	98	11	which	which	PRON
eurjchem-1774	98	12	have	have	AUX
eurjchem-1774	98	13	attached	attach	VERB
eurjchem-1774	98	14	to	to	ADP
eurjchem-1774	98	15	electronegative	electronegative	ADJ
eurjchem-1774	98	16	n	n	X
eurjchem-1774	98	17	atom	atom	NOUN
eurjchem-1774	98	18	,	,	PUNCT
eurjchem-1774	98	19	were	be	AUX
eurjchem-1774	98	20	detected	detect	VERB
eurjchem-1774	98	21	at	at	ADP
eurjchem-1774	98	22	δ	δ	PROPN
eurjchem-1774	98	23	3.60	3.60	NUM
eurjchem-1774	98	24	with	with	ADP
eurjchem-1774	98	25	54.01	54.01	NUM
eurjchem-1774	98	26	and	and	CCONJ
eurjchem-1774	98	27	3.65	3.65	NUM
eurjchem-1774	98	28	with	with	ADP
eurjchem-1774	98	29	53.73	53.73	NUM
eurjchem-1774	98	30	ppm	ppm	NOUN
eurjchem-1774	98	31	for	for	ADP
eurjchem-1774	98	32	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	98	33	-	-	PUNCT
eurjchem-1774	98	34	s	s	PROPN
eurjchem-1774	98	35	,	,	PUNCT
eurjchem-1774	98	36	o)2	o)2	NOUN
eurjchem-1774	98	37	]	]	PUNCT
eurjchem-1774	98	38	complex	complex	NOUN
eurjchem-1774	98	39	and	and	CCONJ
eurjchem-1774	98	40	δ	δ	PROPN
eurjchem-1774	98	41	3.71	3.71	NUM
eurjchem-1774	98	42	with	with	ADP
eurjchem-1774	98	43	54.54	54.54	NUM
eurjchem-1774	98	44	ppm	ppm	NOUN
eurjchem-1774	98	45	,	,	PUNCT
eurjchem-1774	98	46	for	for	ADP
eurjchem-1774	98	47	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	98	48	-	-	PUNCT
eurjchem-1774	98	49	s	s	PROPN
eurjchem-1774	98	50	,	,	PUNCT
eurjchem-1774	98	51	o)2	o)2	NOUN
eurjchem-1774	98	52	]	]	PUNCT
eurjchem-1774	98	53	)	)	PUNCT
eurjchem-1774	98	54	complex	complex	ADJ
eurjchem-1774	98	55	,	,	PUNCT
eurjchem-1774	98	56	respectively	respectively	ADV
eurjchem-1774	98	57	(	(	PUNCT
eurjchem-1774	98	58	figures	figure	NOUN
eurjchem-1774	98	59	3	3	NUM
eurjchem-1774	98	60	and	and	CCONJ
eurjchem-1774	98	61	4	4	NUM
eurjchem-1774	98	62	)	)	PUNCT
eurjchem-1774	99	1	[	[	X
eurjchem-1774	99	2	51,52	51,52	NUM
eurjchem-1774	99	3	]	]	PUNCT
eurjchem-1774	99	4	.	.	PUNCT
eurjchem-1774	100	1	the	the	DET
eurjchem-1774	100	2	infrared	infrared	ADJ
eurjchem-1774	100	3	spectra	spectra	NOUN
eurjchem-1774	100	4	of	of	ADP
eurjchem-1774	100	5	ligands	ligand	NOUN
eurjchem-1774	100	6	with	with	ADP
eurjchem-1774	100	7	their	their	PRON
eurjchem-1774	100	8	metal	metal	NOUN
eurjchem-1774	100	9	complexes	complex	NOUN
eurjchem-1774	100	10	have	have	AUX
eurjchem-1774	100	11	been	be	AUX
eurjchem-1774	100	12	studied	study	VERB
eurjchem-1774	100	13	in	in	ADP
eurjchem-1774	100	14	order	order	NOUN
eurjchem-1774	100	15	to	to	PART
eurjchem-1774	100	16	characterize	characterize	VERB
eurjchem-1774	100	17	their	their	PRON
eurjchem-1774	100	18	structures	structure	NOUN
eurjchem-1774	100	19	and	and	CCONJ
eurjchem-1774	100	20	to	to	PART
eurjchem-1774	100	21	confirm	confirm	VERB
eurjchem-1774	100	22	the	the	DET
eurjchem-1774	100	23	presence	presence	NOUN
eurjchem-1774	100	24	of	of	ADP
eurjchem-1774	100	25	characteristic	characteristic	ADJ
eurjchem-1774	100	26	groups	group	NOUN
eurjchem-1774	100	27	.	.	PUNCT
eurjchem-1774	101	1	the	the	DET
eurjchem-1774	101	2	ir	ir	PROPN
eurjchem-1774	101	3	spectra	spectra	NOUN
eurjchem-1774	101	4	of	of	ADP
eurjchem-1774	101	5	free	free	ADJ
eurjchem-1774	101	6	ligands	ligand	NOUN
eurjchem-1774	101	7	and	and	CCONJ
eurjchem-1774	101	8	metal	metal	NOUN
eurjchem-1774	101	9	chelates	chelate	NOUN
eurjchem-1774	101	10	were	be	AUX
eurjchem-1774	101	11	carried	carry	VERB
eurjchem-1774	101	12	out	out	ADP
eurjchem-1774	101	13	in	in	ADP
eurjchem-1774	101	14	the	the	DET
eurjchem-1774	101	15	4000	4000	NUM
eurjchem-1774	101	16	-	-	SYM
eurjchem-1774	101	17	400	400	NUM
eurjchem-1774	101	18	cm–1	cm–1	NUM
eurjchem-1774	101	19	range	range	NOUN
eurjchem-1774	101	20	.	.	PUNCT
eurjchem-1774	102	1	in	in	ADP
eurjchem-1774	102	2	the	the	DET
eurjchem-1774	102	3	ir	ir	PROPN
eurjchem-1774	102	4	spectrum	spectrum	NOUN
eurjchem-1774	102	5	of	of	ADP
eurjchem-1774	102	6	the	the	DET
eurjchem-1774	102	7	ligands	ligand	NOUN
eurjchem-1774	102	8	the	the	DET
eurjchem-1774	102	9	vibration	vibration	NOUN
eurjchem-1774	102	10	band	band	NOUN
eurjchem-1774	102	11	was	be	AUX
eurjchem-1774	102	12	observed	observe	VERB
eurjchem-1774	102	13	nearly	nearly	ADV
eurjchem-1774	102	14	at	at	ADP
eurjchem-1774	102	15	~3200	~3200	NUM
eurjchem-1774	102	16	cm−1	cm−1	NOUN
eurjchem-1774	102	17	assigned	assign	VERB
eurjchem-1774	102	18	to	to	ADP
eurjchem-1774	102	19	ν(nh	ν(nh	NOUN
eurjchem-1774	102	20	)	)	PUNCT
eurjchem-1774	102	21	stretching	stretch	VERB
eurjchem-1774	102	22	vibration	vibration	NOUN
eurjchem-1774	102	23	.	.	PUNCT
eurjchem-1774	103	1	2018	2018	NUM
eurjchem-1774	103	2	–	–	PUNCT
eurjchem-1774	103	3	european	european	ADJ
eurjchem-1774	103	4	journal	journal	NOUN
eurjchem-1774	103	5	of	of	ADP
eurjchem-1774	103	6	chemistry	chemistry	NOUN
eurjchem-1774	103	7	–	–	PUNCT
eurjchem-1774	103	8	cc	cc	NOUN
eurjchem-1774	103	9	by	by	ADP
eurjchem-1774	103	10	nc	nc	PROPN
eurjchem-1774	103	11	–	–	PUNCT
eurjchem-1774	103	12	doi	doi	PROPN
eurjchem-1774	103	13	:	:	PUNCT
eurjchem-1774	103	14	10.5155	10.5155	NUM
eurjchem-1774	103	15	/	/	SYM
eurjchem-1774	103	16	eurjchem.9.4.360	eurjchem.9.4.360	NOUN
eurjchem-1774	103	17	-	-	SYM
eurjchem-1774	103	18	368.1774	368.1774	NUM
eurjchem-1774	103	19	keskin	keskin	PROPN
eurjchem-1774	103	20	et	et	PROPN
eurjchem-1774	103	21	al	al	PROPN
eurjchem-1774	103	22	.	.	PUNCT
eurjchem-1774	103	23	/	/	SYM
eurjchem-1774	103	24	european	european	PROPN
eurjchem-1774	103	25	journal	journal	PROPN
eurjchem-1774	103	26	of	of	ADP
eurjchem-1774	103	27	chemistry	chemistry	NOUN
eurjchem-1774	103	28	9	9	NUM
eurjchem-1774	103	29	(	(	PUNCT
eurjchem-1774	103	30	4	4	NUM
eurjchem-1774	103	31	)	)	PUNCT
eurjchem-1774	103	32	(	(	PUNCT
eurjchem-1774	103	33	2018	2018	NUM
eurjchem-1774	103	34	)	)	PUNCT
eurjchem-1774	103	35	360	360	NUM
eurjchem-1774	103	36	-	-	SYM
eurjchem-1774	103	37	368	368	NUM
eurjchem-1774	103	38	363	363	NUM
eurjchem-1774	103	39	figure	figure	NOUN
eurjchem-1774	103	40	2	2	NUM
eurjchem-1774	103	41	.	.	PUNCT
eurjchem-1774	103	42	cosy	cosy	PROPN
eurjchem-1774	103	43	nmr	nmr	NOUN
eurjchem-1774	103	44	spectrum	spectrum	NOUN
eurjchem-1774	103	45	of	of	ADP
eurjchem-1774	103	46	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	103	47	-	-	PUNCT
eurjchem-1774	103	48	s	s	PROPN
eurjchem-1774	103	49	,	,	PUNCT
eurjchem-1774	103	50	o)2	o)2	NOUN
eurjchem-1774	103	51	]	]	PUNCT
eurjchem-1774	103	52	complex	complex	ADJ
eurjchem-1774	103	53	.	.	PUNCT
eurjchem-1774	104	1	figure	figure	NOUN
eurjchem-1774	104	2	3	3	NUM
eurjchem-1774	104	3	.	.	X
eurjchem-1774	104	4	hmqc	hmqc	PROPN
eurjchem-1774	104	5	nmr	nmr	PROPN
eurjchem-1774	104	6	spectrum	spectrum	NOUN
eurjchem-1774	104	7	of	of	ADP
eurjchem-1774	104	8	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	104	9	-	-	PUNCT
eurjchem-1774	104	10	s	s	PROPN
eurjchem-1774	104	11	,	,	PUNCT
eurjchem-1774	104	12	o)2	o)2	NOUN
eurjchem-1774	104	13	]	]	PUNCT
eurjchem-1774	104	14	complex	complex	ADJ
eurjchem-1774	104	15	.	.	PUNCT
eurjchem-1774	105	1	figure	figure	NOUN
eurjchem-1774	105	2	4	4	NUM
eurjchem-1774	105	3	.	.	PUNCT
eurjchem-1774	106	1	hmqc	hmqc	PROPN
eurjchem-1774	106	2	nmr	nmr	PROPN
eurjchem-1774	106	3	spectrum	spectrum	NOUN
eurjchem-1774	106	4	of	of	ADP
eurjchem-1774	106	5	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	106	6	-	-	PUNCT
eurjchem-1774	106	7	s	s	PROPN
eurjchem-1774	106	8	,	,	PUNCT
eurjchem-1774	106	9	o)2	o)2	NOUN
eurjchem-1774	106	10	]	]	PUNCT
eurjchem-1774	106	11	complex	complex	NOUN
eurjchem-1774	106	12	.	.	PUNCT
eurjchem-1774	107	1	this	this	DET
eurjchem-1774	107	2	band	band	NOUN
eurjchem-1774	107	3	disappears	disappear	VERB
eurjchem-1774	107	4	upon	upon	SCONJ
eurjchem-1774	107	5	metal	metal	NOUN
eurjchem-1774	107	6	complex	complex	ADJ
eurjchem-1774	107	7	formation	formation	NOUN
eurjchem-1774	107	8	.	.	PUNCT
eurjchem-1774	108	1	the	the	DET
eurjchem-1774	108	2	vibration	vibration	NOUN
eurjchem-1774	108	3	band	band	NOUN
eurjchem-1774	108	4	observed	observe	VERB
eurjchem-1774	108	5	at	at	ADP
eurjchem-1774	108	6	1643	1643	NUM
eurjchem-1774	108	7	and	and	CCONJ
eurjchem-1774	108	8	1685	1685	NUM
eurjchem-1774	108	9	cm−1	cm−1	NOUN
eurjchem-1774	108	10	are	be	AUX
eurjchem-1774	108	11	assigned	assign	VERB
eurjchem-1774	108	12	to	to	ADP
eurjchem-1774	108	13	carbonyl	carbonyl	NOUN
eurjchem-1774	108	14	ν(c	ν(c	NOUN
eurjchem-1774	108	15	=	=	SYM
eurjchem-1774	108	16	o	o	NOUN
eurjchem-1774	108	17	)	)	PUNCT
eurjchem-1774	108	18	for	for	ADP
eurjchem-1774	108	19	hl1	hl1	PROPN
eurjchem-1774	108	20	and	and	CCONJ
eurjchem-1774	108	21	hl2	hl2	NOUN
eurjchem-1774	108	22	,	,	PUNCT
eurjchem-1774	108	23	respectively	respectively	ADV
eurjchem-1774	108	24	.	.	PUNCT
eurjchem-1774	109	1	the	the	DET
eurjchem-1774	109	2	vibration	vibration	NOUN
eurjchem-1774	109	3	bands	band	NOUN
eurjchem-1774	109	4	for	for	ADP
eurjchem-1774	109	5	hl1	hl1	PROPN
eurjchem-1774	109	6	and	and	CCONJ
eurjchem-1774	109	7	hl2	hl2	NOUN
eurjchem-1774	109	8	ligands	ligand	NOUN
eurjchem-1774	109	9	,	,	PUNCT
eurjchem-1774	109	10	which	which	PRON
eurjchem-1774	109	11	belong	belong	VERB
eurjchem-1774	109	12	to	to	ADP
eurjchem-1774	109	13	ν(c	ν(c	PROPN
eurjchem-1774	109	14	=	=	SYM
eurjchem-1774	109	15	s	s	PART
eurjchem-1774	109	16	)	)	PUNCT
eurjchem-1774	109	17	group	group	NOUN
eurjchem-1774	109	18	,	,	PUNCT
eurjchem-1774	109	19	appeared	appear	VERB
eurjchem-1774	109	20	at	at	ADP
eurjchem-1774	109	21	1275	1275	NUM
eurjchem-1774	109	22	and	and	CCONJ
eurjchem-1774	109	23	1261	1261	NUM
eurjchem-1774	109	24	cm−1	cm−1	NOUN
eurjchem-1774	109	25	,	,	PUNCT
eurjchem-1774	109	26	respectively	respectively	ADV
eurjchem-1774	109	27	.	.	PUNCT
eurjchem-1774	110	1	after	after	ADP
eurjchem-1774	110	2	the	the	DET
eurjchem-1774	110	3	complexation	complexation	NOUN
eurjchem-1774	110	4	,	,	PUNCT
eurjchem-1774	110	5	carbonyl	carbonyl	NOUN
eurjchem-1774	110	6	ν(c	ν(c	NOUN
eurjchem-1774	110	7	=	=	SYM
eurjchem-1774	110	8	o	o	NOUN
eurjchem-1774	110	9	)	)	PUNCT
eurjchem-1774	110	10	and	and	CCONJ
eurjchem-1774	110	11	thiocarbonyl	thiocarbonyl	VERB
eurjchem-1774	110	12	ν(c	ν(c	PROPN
eurjchem-1774	110	13	=	=	SYM
eurjchem-1774	110	14	s	s	PART
eurjchem-1774	110	15	)	)	PUNCT
eurjchem-1774	110	16	vibration	vibration	NOUN
eurjchem-1774	110	17	bands	band	NOUN
eurjchem-1774	110	18	shifted	shift	VERB
eurjchem-1774	110	19	to	to	ADP
eurjchem-1774	110	20	lower	low	ADJ
eurjchem-1774	110	21	values	value	NOUN
eurjchem-1774	110	22	as	as	ADP
eurjchem-1774	110	23	a	a	DET
eurjchem-1774	110	24	result	result	NOUN
eurjchem-1774	110	25	of	of	ADP
eurjchem-1774	110	26	the	the	DET
eurjchem-1774	110	27	coordination	coordination	NOUN
eurjchem-1774	110	28	via	via	ADP
eurjchem-1774	110	29	sulfur	sulfur	NOUN
eurjchem-1774	110	30	and	and	CCONJ
eurjchem-1774	110	31	oxygen	oxygen	NOUN
eurjchem-1774	110	32	atoms	atom	NOUN
eurjchem-1774	110	33	to	to	ADP
eurjchem-1774	110	34	platinum	platinum	NOUN
eurjchem-1774	110	35	ions	ion	NOUN
eurjchem-1774	110	36	[	[	X
eurjchem-1774	110	37	53	53	NUM
eurjchem-1774	110	38	-	-	SYM
eurjchem-1774	110	39	55	55	NUM
eurjchem-1774	110	40	]	]	PUNCT
eurjchem-1774	110	41	.	.	PUNCT
eurjchem-1774	111	1	3.2	3.2	NUM
eurjchem-1774	111	2	.	.	PUNCT
eurjchem-1774	112	1	crystal	crystal	NOUN
eurjchem-1774	112	2	structure	structure	NOUN
eurjchem-1774	112	3	analysis	analysis	NOUN
eurjchem-1774	112	4	the	the	DET
eurjchem-1774	112	5	molecular	molecular	ADJ
eurjchem-1774	112	6	structure	structure	NOUN
eurjchem-1774	112	7	of	of	ADP
eurjchem-1774	112	8	the	the	DET
eurjchem-1774	112	9	obtained	obtain	VERB
eurjchem-1774	112	10	complexes	complex	NOUN
eurjchem-1774	112	11	was	be	AUX
eurjchem-1774	112	12	determined	determine	VERB
eurjchem-1774	112	13	with	with	ADP
eurjchem-1774	112	14	single	single	ADJ
eurjchem-1774	112	15	crystal	crystal	NOUN
eurjchem-1774	112	16	x	x	PROPN
eurjchem-1774	112	17	-	-	NOUN
eurjchem-1774	112	18	ray	ray	NOUN
eurjchem-1774	112	19	diffraction	diffraction	NOUN
eurjchem-1774	112	20	.	.	PUNCT
eurjchem-1774	113	1	block	block	NOUN
eurjchem-1774	113	2	shaped	shape	VERB
eurjchem-1774	113	3	yellow	yellow	ADJ
eurjchem-1774	113	4	coloured	coloured	ADJ
eurjchem-1774	113	5	crystal	crystal	NOUN
eurjchem-1774	113	6	of	of	ADP
eurjchem-1774	113	7	the	the	DET
eurjchem-1774	113	8	complexes	complex	NOUN
eurjchem-1774	113	9	was	be	AUX
eurjchem-1774	113	10	obtained	obtain	VERB
eurjchem-1774	113	11	by	by	ADP
eurjchem-1774	113	12	slow	slow	ADJ
eurjchem-1774	113	13	evaporation	evaporation	NOUN
eurjchem-1774	113	14	of	of	ADP
eurjchem-1774	113	15	their	their	PRON
eurjchem-1774	113	16	ethanol	ethanol	NOUN
eurjchem-1774	113	17	:	:	PUNCT
eurjchem-1774	113	18	dichloromethane	dichloromethane	NOUN
eurjchem-1774	113	19	solution	solution	NOUN
eurjchem-1774	113	20	(	(	PUNCT
eurjchem-1774	113	21	2:1	2:1	NUM
eurjchem-1774	113	22	,	,	PUNCT
eurjchem-1774	113	23	v	v	NOUN
eurjchem-1774	113	24	:	:	PUNCT
eurjchem-1774	113	25	v	v	NOUN
eurjchem-1774	113	26	)	)	PUNCT
eurjchem-1774	113	27	.	.	PUNCT
eurjchem-1774	114	1	the	the	DET
eurjchem-1774	114	2	complexes	complex	NOUN
eurjchem-1774	114	3	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	114	4	-	-	PUNCT
eurjchem-1774	114	5	s	s	PROPN
eurjchem-1774	114	6	,	,	PUNCT
eurjchem-1774	114	7	o)2	o)2	PROPN
eurjchem-1774	114	8	]	]	PUNCT
eurjchem-1774	114	9	and	and	CCONJ
eurjchem-1774	114	10	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	114	11	-	-	PUNCT
eurjchem-1774	114	12	s	s	PROPN
eurjchem-1774	114	13	,	,	PUNCT
eurjchem-1774	114	14	o)2	o)2	PROPN
eurjchem-1774	114	15	]	]	PUNCT
eurjchem-1774	114	16	crystallized	crystallize	VERB
eurjchem-1774	114	17	in	in	ADP
eurjchem-1774	114	18	orthorombic	orthorombic	ADJ
eurjchem-1774	114	19	space	space	NOUN
eurjchem-1774	114	20	group	group	NOUN
eurjchem-1774	114	21	fdd2	fdd2	NOUN
eurjchem-1774	114	22	and	and	CCONJ
eurjchem-1774	114	23	triclinic	triclinic	ADJ
eurjchem-1774	114	24	space	space	NOUN
eurjchem-1774	114	25	group	group	NOUN
eurjchem-1774	114	26	p1	p1	PROPN
eurjchem-1774	114	27	,	,	PUNCT
eurjchem-1774	114	28	respectively	respectively	ADV
eurjchem-1774	114	29	.	.	PUNCT
eurjchem-1774	115	1	the	the	DET
eurjchem-1774	115	2	crystal	crystal	NOUN
eurjchem-1774	115	3	and	and	CCONJ
eurjchem-1774	115	4	structure	structure	NOUN
eurjchem-1774	115	5	refinement	refinement	NOUN
eurjchem-1774	115	6	data	datum	NOUN
eurjchem-1774	115	7	are	be	AUX
eurjchem-1774	115	8	given	give	VERB
eurjchem-1774	115	9	in	in	ADP
eurjchem-1774	115	10	table	table	NOUN
eurjchem-1774	115	11	1	1	NUM
eurjchem-1774	115	12	.	.	PUNCT
eurjchem-1774	116	1	the	the	DET
eurjchem-1774	116	2	asymmetric	asymmetric	ADJ
eurjchem-1774	116	3	unit	unit	NOUN
eurjchem-1774	116	4	of	of	ADP
eurjchem-1774	116	5	the	the	DET
eurjchem-1774	116	6	cis[pt(l1	cis[pt(l1	PROPN
eurjchem-1774	116	7	-	-	PUNCT
eurjchem-1774	116	8	s	s	PROPN
eurjchem-1774	116	9	,	,	PUNCT
eurjchem-1774	116	10	o)2	o)2	PROPN
eurjchem-1774	116	11	]	]	PUNCT
eurjchem-1774	116	12	consists	consist	VERB
eurjchem-1774	116	13	of	of	ADP
eurjchem-1774	116	14	half	half	ADJ
eurjchem-1774	116	15	unique	unique	ADJ
eurjchem-1774	116	16	molecules	molecule	NOUN
eurjchem-1774	116	17	,	,	PUNCT
eurjchem-1774	116	18	while	while	SCONJ
eurjchem-1774	116	19	four	four	NUM
eurjchem-1774	116	20	crystallographically	crystallographically	ADV
eurjchem-1774	116	21	independent	independent	ADJ
eurjchem-1774	116	22	molecules	molecule	NOUN
eurjchem-1774	116	23	are	be	AUX
eurjchem-1774	116	24	observed	observe	VERB
eurjchem-1774	116	25	in	in	ADP
eurjchem-1774	116	26	the	the	DET
eurjchem-1774	116	27	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	116	28	-	-	PUNCT
eurjchem-1774	116	29	s	s	PROPN
eurjchem-1774	116	30	,	,	PUNCT
eurjchem-1774	116	31	o)2	o)2	PROPN
eurjchem-1774	116	32	]	]	PUNCT
eurjchem-1774	116	33	(	(	PUNCT
eurjchem-1774	116	34	figures	figure	NOUN
eurjchem-1774	116	35	5	5	NUM
eurjchem-1774	116	36	and	and	CCONJ
eurjchem-1774	116	37	6	6	NUM
eurjchem-1774	116	38	)	)	PUNCT
eurjchem-1774	116	39	.	.	PUNCT
eurjchem-1774	117	1	calculating	calculate	VERB
eurjchem-1774	117	2	the	the	DET
eurjchem-1774	117	3	root	root	NOUN
eurjchem-1774	117	4	mean	mean	NOUN
eurjchem-1774	117	5	square	square	ADJ
eurjchem-1774	117	6	deviations	deviation	NOUN
eurjchem-1774	117	7	between	between	ADP
eurjchem-1774	117	8	the	the	DET
eurjchem-1774	117	9	x	x	NOUN
eurjchem-1774	117	10	-	-	NOUN
eurjchem-1774	117	11	ray	ray	NOUN
eurjchem-1774	117	12	geometries	geometry	NOUN
eurjchem-1774	117	13	of	of	ADP
eurjchem-1774	117	14	the	the	DET
eurjchem-1774	117	15	four	four	NUM
eurjchem-1774	117	16	independent	independent	ADJ
eurjchem-1774	117	17	molecules	molecule	NOUN
eurjchem-1774	117	18	of	of	ADP
eurjchem-1774	117	19	the	the	DET
eurjchem-1774	117	20	cis[pt(l2	cis[pt(l2	PROPN
eurjchem-1774	117	21	-	-	PUNCT
eurjchem-1774	117	22	s	s	PROPN
eurjchem-1774	117	23	,	,	PUNCT
eurjchem-1774	117	24	o)2	o)2	PROPN
eurjchem-1774	117	25	]	]	PUNCT
eurjchem-1774	117	26	we	we	PRON
eurjchem-1774	117	27	can	can	AUX
eurjchem-1774	117	28	see	see	VERB
eurjchem-1774	117	29	that	that	SCONJ
eurjchem-1774	117	30	all	all	DET
eurjchem-1774	117	31	molecules	molecule	NOUN
eurjchem-1774	117	32	are	be	AUX
eurjchem-1774	117	33	slightly	slightly	ADV
eurjchem-1774	117	34	differ	differ	ADJ
eurjchem-1774	117	35	(	(	PUNCT
eurjchem-1774	117	36	propyl	propyl	ADJ
eurjchem-1774	117	37	regions	region	NOUN
eurjchem-1774	117	38	)	)	PUNCT
eurjchem-1774	117	39	from	from	ADP
eurjchem-1774	117	40	the	the	DET
eurjchem-1774	117	41	equilibrium	equilibrium	NOUN
eurjchem-1774	117	42	geometry	geometry	NOUN
eurjchem-1774	117	43	(	(	PUNCT
eurjchem-1774	117	44	rmsd(a	rmsd(a	NOUN
eurjchem-1774	117	45	-	-	PUNCT
eurjchem-1774	117	46	c	c	NOUN
eurjchem-1774	117	47	)	)	PUNCT
eurjchem-1774	117	48	=	=	PUNCT
eurjchem-1774	117	49	0.692	0.692	NUM
eurjchem-1774	117	50	å	å	NOUN
eurjchem-1774	117	51	with	with	ADP
eurjchem-1774	117	52	inversion	inversion	NOUN
eurjchem-1774	117	53	,	,	PUNCT
eurjchem-1774	117	54	rmsd(a	rmsd(a	NOUN
eurjchem-1774	117	55	-	-	PUNCT
eurjchem-1774	117	56	c	c	NOUN
eurjchem-1774	117	57	)	)	PUNCT
eurjchem-1774	117	58	=	=	PUNCT
eurjchem-1774	117	59	0.992	0.992	NUM
eurjchem-1774	117	60	å	å	NOUN
eurjchem-1774	117	61	without	without	ADP
eurjchem-1774	117	62	inversion	inversion	NOUN
eurjchem-1774	117	63	,	,	PUNCT
eurjchem-1774	117	64	rmsd(a	rmsd(a	PROPN
eurjchem-1774	117	65	-	-	PUNCT
eurjchem-1774	117	66	b	b	NOUN
eurjchem-1774	117	67	)	)	PUNCT
eurjchem-1774	117	68	=	=	PUNCT
eurjchem-1774	118	1	1.113	1.113	NUM
eurjchem-1774	118	2	å	å	NOUN
eurjchem-1774	118	3	with	with	ADP
eurjchem-1774	118	4	inversion	inversion	NOUN
eurjchem-1774	118	5	,	,	PUNCT
eurjchem-1774	118	6	rmsd(a	rmsd(a	PROPN
eurjchem-1774	118	7	-	-	PUNCT
eurjchem-1774	118	8	b	b	NOUN
eurjchem-1774	118	9	)	)	PUNCT
eurjchem-1774	118	10	=	=	NUM
eurjchem-1774	118	11	0.716	0.716	NUM
eurjchem-1774	118	12	å	å	NOUN
eurjchem-1774	118	13	without	without	ADP
eurjchem-1774	118	14	inversion	inversion	NOUN
eurjchem-1774	118	15	,	,	PUNCT
eurjchem-1774	118	16	rmsd(a	rmsd(a	NOUN
eurjchem-1774	118	17	-	-	PUNCT
eurjchem-1774	118	18	d	d	NOUN
eurjchem-1774	118	19	)	)	PUNCT
eurjchem-1774	118	20	=	=	SYM
eurjchem-1774	118	21	0.084	0.084	NUM
eurjchem-1774	118	22	å	å	NOUN
eurjchem-1774	118	23	with	with	ADP
eurjchem-1774	118	24	inversion	inversion	NOUN
eurjchem-1774	118	25	,	,	PUNCT
eurjchem-1774	118	26	rmsd(ad	rmsd(ad	NOUN
eurjchem-1774	118	27	)	)	PUNCT
eurjchem-1774	118	28	=	=	NOUN
eurjchem-1774	118	29	1.299	1.299	NUM
eurjchem-1774	118	30	å	å	NOUN
eurjchem-1774	118	31	without	without	ADP
eurjchem-1774	118	32	inversion	inversion	NOUN
eurjchem-1774	118	33	)	)	PUNCT
eurjchem-1774	118	34	.	.	PUNCT
eurjchem-1774	119	1	2018	2018	NUM
eurjchem-1774	119	2	–	–	PUNCT
eurjchem-1774	119	3	european	european	ADJ
eurjchem-1774	119	4	journal	journal	NOUN
eurjchem-1774	119	5	of	of	ADP
eurjchem-1774	119	6	chemistry	chemistry	NOUN
eurjchem-1774	119	7	–	–	PUNCT
eurjchem-1774	119	8	cc	cc	NOUN
eurjchem-1774	119	9	by	by	ADP
eurjchem-1774	119	10	nc	nc	PROPN
eurjchem-1774	119	11	–	–	PUNCT
eurjchem-1774	119	12	doi	doi	PROPN
eurjchem-1774	119	13	:	:	PUNCT
eurjchem-1774	119	14	10.5155	10.5155	NUM
eurjchem-1774	119	15	/	/	SYM
eurjchem-1774	119	16	eurjchem.9.4.360	eurjchem.9.4.360	NOUN
eurjchem-1774	119	17	-	-	SYM
eurjchem-1774	119	18	368.1774	368.1774	NUM
eurjchem-1774	119	19	364	364	NUM
eurjchem-1774	119	20	keskin	keskin	NOUN
eurjchem-1774	119	21	et	et	PROPN
eurjchem-1774	119	22	al	al	PROPN
eurjchem-1774	119	23	.	.	PUNCT
eurjchem-1774	119	24	/	/	SYM
eurjchem-1774	119	25	european	european	PROPN
eurjchem-1774	119	26	journal	journal	PROPN
eurjchem-1774	119	27	of	of	ADP
eurjchem-1774	119	28	chemistry	chemistry	NOUN
eurjchem-1774	119	29	9	9	NUM
eurjchem-1774	119	30	(	(	PUNCT
eurjchem-1774	119	31	4	4	NUM
eurjchem-1774	119	32	)	)	PUNCT
eurjchem-1774	119	33	(	(	PUNCT
eurjchem-1774	119	34	2018	2018	NUM
eurjchem-1774	119	35	)	)	PUNCT
eurjchem-1774	119	36	360	360	NUM
eurjchem-1774	119	37	-	-	SYM
eurjchem-1774	119	38	368	368	NUM
eurjchem-1774	119	39	table	table	NOUN
eurjchem-1774	119	40	1	1	NUM
eurjchem-1774	119	41	.	.	PUNCT
eurjchem-1774	120	1	crystal	crystal	NOUN
eurjchem-1774	120	2	data	datum	NOUN
eurjchem-1774	120	3	and	and	CCONJ
eurjchem-1774	120	4	details	detail	NOUN
eurjchem-1774	120	5	of	of	ADP
eurjchem-1774	120	6	the	the	DET
eurjchem-1774	120	7	structure	structure	NOUN
eurjchem-1774	120	8	refinement	refinement	NOUN
eurjchem-1774	120	9	for	for	ADP
eurjchem-1774	120	10	complexes	complex	NOUN
eurjchem-1774	120	11	.	.	PUNCT
eurjchem-1774	121	1	compound	compound	PROPN
eurjchem-1774	121	2	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	121	3	-	-	PUNCT
eurjchem-1774	121	4	s	s	PROPN
eurjchem-1774	121	5	,	,	PUNCT
eurjchem-1774	121	6	o)2	o)2	PROPN
eurjchem-1774	121	7	]	]	PUNCT
eurjchem-1774	121	8	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	121	9	-	-	PUNCT
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eurjchem-1774	121	11	,	,	PUNCT
eurjchem-1774	121	12	o)2	o)2	NOUN
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eurjchem-1774	121	23	(	(	PUNCT
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eurjchem-1774	121	42	)	)	PUNCT
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eurjchem-1774	121	44	)	)	PUNCT
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eurjchem-1774	121	46	,	,	PUNCT
eurjchem-1774	121	47	(	(	PUNCT
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eurjchem-1774	121	49	)	)	PUNCT
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eurjchem-1774	121	51	)	)	PUNCT
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eurjchem-1774	121	53	)	)	PUNCT
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eurjchem-1774	121	55	,	,	PUNCT
eurjchem-1774	121	56	(	(	PUNCT
eurjchem-1774	121	57	å	å	NOUN
eurjchem-1774	121	58	)	)	PUNCT
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eurjchem-1774	121	62	)	)	PUNCT
eurjchem-1774	122	1	α	α	X
eurjchem-1774	122	2	,	,	PUNCT
eurjchem-1774	122	3	(	(	PUNCT
eurjchem-1774	122	4	ᵒ	ᵒ	X
eurjchem-1774	122	5	)	)	PUNCT
eurjchem-1774	122	6	90	90	NUM
eurjchem-1774	122	7	80.253(2	80.253(2	NUM
eurjchem-1774	122	8	)	)	PUNCT
eurjchem-1774	122	9	β	β	X
eurjchem-1774	122	10	,	,	PUNCT
eurjchem-1774	122	11	(	(	PUNCT
eurjchem-1774	122	12	ᵒ	ᵒ	X
eurjchem-1774	122	13	)	)	PUNCT
eurjchem-1774	122	14	90	90	NUM
eurjchem-1774	122	15	85.604(2	85.604(2	NUM
eurjchem-1774	122	16	)	)	PUNCT
eurjchem-1774	123	1	γ	γ	X
eurjchem-1774	123	2	,	,	PUNCT
eurjchem-1774	123	3	(	(	PUNCT
eurjchem-1774	123	4	ᵒ	ᵒ	X
eurjchem-1774	123	5	)	)	PUNCT
eurjchem-1774	123	6	90	90	NUM
eurjchem-1774	123	7	63.8880(10	63.8880(10	NUM
eurjchem-1774	123	8	)	)	PUNCT
eurjchem-1774	123	9	volume	volume	NOUN
eurjchem-1774	123	10	(	(	PUNCT
eurjchem-1774	123	11	å3	å3	PROPN
eurjchem-1774	123	12	)	)	PUNCT
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eurjchem-1774	123	14	)	)	PUNCT
eurjchem-1774	123	15	6206.7(4	6206.7(4	NOUN
eurjchem-1774	123	16	)	)	PUNCT
eurjchem-1774	123	17	z	z	NOUN
eurjchem-1774	123	18	8	8	NUM
eurjchem-1774	123	19	8	8	NUM
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eurjchem-1774	123	21	(	(	PUNCT
eurjchem-1774	123	22	g	g	NOUN
eurjchem-1774	123	23	/	/	SYM
eurjchem-1774	123	24	cm3	cm3	NOUN
eurjchem-1774	123	25	)	)	PUNCT
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eurjchem-1774	123	28	μ	μ	NOUN
eurjchem-1774	123	29	(	(	PUNCT
eurjchem-1774	123	30	mm-1	mm-1	NOUN
eurjchem-1774	123	31	)	)	PUNCT
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eurjchem-1774	123	34	f(000	f(000	NOUN
eurjchem-1774	123	35	)	)	PUNCT
eurjchem-1774	123	36	3008.0	3008.0	NUM
eurjchem-1774	123	37	3424.0	3424.0	NUM
eurjchem-1774	123	38	crystal	crystal	NOUN
eurjchem-1774	123	39	size	size	NOUN
eurjchem-1774	123	40	(	(	PUNCT
eurjchem-1774	123	41	mm3	mm3	PROPN
eurjchem-1774	123	42	)	)	PUNCT
eurjchem-1774	123	43	0.21	0.21	NUM
eurjchem-1774	123	44	×	×	NOUN
eurjchem-1774	123	45	0.21	0.21	NUM
eurjchem-1774	123	46	×	×	NOUN
eurjchem-1774	123	47	0.12	0.12	NUM
eurjchem-1774	123	48	0.18	0.18	NUM
eurjchem-1774	123	49	×	×	NOUN
eurjchem-1774	123	50	0.17	0.17	NUM
eurjchem-1774	123	51	×	×	NOUN
eurjchem-1774	123	52	0.12	0.12	NUM
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eurjchem-1774	123	54	mokα	mokα	NOUN
eurjchem-1774	123	55	(	(	PUNCT
eurjchem-1774	123	56	λ	λ	X
eurjchem-1774	123	57	=	=	SYM
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eurjchem-1774	123	59	)	)	PUNCT
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eurjchem-1774	123	61	(	(	PUNCT
eurjchem-1774	123	62	λ	λ	X
eurjchem-1774	123	63	=	=	NOUN
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eurjchem-1774	123	65	)	)	PUNCT
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eurjchem-1774	123	68	for	for	ADP
eurjchem-1774	123	69	data	data	NOUN
eurjchem-1774	123	70	collection	collection	NOUN
eurjchem-1774	123	71	(	(	PUNCT
eurjchem-1774	123	72	°	°	ADP
eurjchem-1774	123	73	)	)	PUNCT
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eurjchem-1774	123	75	to	to	ADP
eurjchem-1774	123	76	53.434	53.434	NUM
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eurjchem-1774	123	78	to	to	ADP
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eurjchem-1774	123	80	index	index	NOUN
eurjchem-1774	123	81	ranges	range	VERB
eurjchem-1774	123	82	-33	-33	PROPN
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eurjchem-1774	123	84	h	h	NOUN
eurjchem-1774	123	85	≤	≤	NUM
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eurjchem-1774	123	87	,	,	PUNCT
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eurjchem-1774	123	89	≤	≤	NUM
eurjchem-1774	124	1	k	k	X
eurjchem-1774	124	2	≤	≤	NUM
eurjchem-1774	124	3	15	15	NUM
eurjchem-1774	124	4	,	,	PUNCT
eurjchem-1774	124	5	-23	-23	PUNCT
eurjchem-1774	124	6	≤	≤	NUM
eurjchem-1774	124	7	l	l	NOUN
eurjchem-1774	124	8	≤	≤	NUM
eurjchem-1774	124	9	23	23	NUM
eurjchem-1774	124	10	-19	-19	SYM
eurjchem-1774	124	11	≤	≤	NUM
eurjchem-1774	124	12	h	h	NOUN
eurjchem-1774	124	13	≤	≤	NUM
eurjchem-1774	124	14	19	19	NUM
eurjchem-1774	124	15	,	,	PUNCT
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eurjchem-1774	124	17	≤	≤	NUM
eurjchem-1774	124	18	k	k	X
eurjchem-1774	124	19	≤	≤	NUM
eurjchem-1774	124	20	21	21	NUM
eurjchem-1774	124	21	,	,	PUNCT
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eurjchem-1774	124	23	≤	≤	NUM
eurjchem-1774	124	24	l	l	NOUN
eurjchem-1774	124	25	≤	≤	NUM
eurjchem-1774	124	26	31	31	NUM
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eurjchem-1774	124	29	45369	45369	NUM
eurjchem-1774	124	30	257871	257871	NUM
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eurjchem-1774	124	32	reflections	reflection	NOUN
eurjchem-1774	124	33	3256	3256	NUM
eurjchem-1774	124	34	[	[	X
eurjchem-1774	124	35	rint	rint	X
eurjchem-1774	124	36	=	=	SYM
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eurjchem-1774	124	38	,	,	PUNCT
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eurjchem-1774	125	1	=	=	SYM
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eurjchem-1774	125	3	]	]	PUNCT
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eurjchem-1774	126	1	[	[	X
eurjchem-1774	126	2	rint	rint	X
eurjchem-1774	126	3	=	=	SYM
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eurjchem-1774	126	5	,	,	PUNCT
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eurjchem-1774	126	7	=	=	SYM
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eurjchem-1774	126	9	]	]	PUNCT
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eurjchem-1774	126	11	/	/	SYM
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eurjchem-1774	126	13	/	/	SYM
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eurjchem-1774	126	17	goodness	goodness	NOUN
eurjchem-1774	126	18	-	-	PUNCT
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eurjchem-1774	126	20	-	-	PUNCT
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eurjchem-1774	126	27	r	r	NOUN
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eurjchem-1774	126	29	[	[	X
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eurjchem-1774	126	31	(	(	PUNCT
eurjchem-1774	126	32	i	i	NOUN
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eurjchem-1774	127	1	r1	r1	NOUN
eurjchem-1774	127	2	=	=	PUNCT
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eurjchem-1774	127	4	,	,	PUNCT
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eurjchem-1774	127	9	=	=	SYM
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eurjchem-1774	127	18	[	[	X
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eurjchem-1774	127	23	=	=	SYM
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eurjchem-1774	127	25	,	,	PUNCT
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eurjchem-1774	127	30	=	=	SYM
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eurjchem-1774	128	13	(	(	PUNCT
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eurjchem-1774	128	16	(	(	PUNCT
eurjchem-1774	128	17	b	b	X
eurjchem-1774	128	18	)	)	PUNCT
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eurjchem-1774	128	21	.	.	PUNCT
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eurjchem-1774	129	3	)	)	PUNCT
eurjchem-1774	129	4	the	the	DET
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eurjchem-1774	129	6	unit	unit	NOUN
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eurjchem-1774	129	9	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	129	10	-	-	PUNCT
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eurjchem-1774	129	12	,	,	PUNCT
eurjchem-1774	129	13	o)2	o)2	PROPN
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eurjchem-1774	129	16	(	(	PUNCT
eurjchem-1774	129	17	b	b	NOUN
eurjchem-1774	129	18	)	)	PUNCT
eurjchem-1774	129	19	molecular	molecular	ADJ
eurjchem-1774	129	20	structure	structure	NOUN
eurjchem-1774	129	21	of	of	ADP
eurjchem-1774	129	22	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	129	23	-	-	PUNCT
eurjchem-1774	129	24	s	s	PROPN
eurjchem-1774	129	25	,	,	PUNCT
eurjchem-1774	129	26	o)2	o)2	PROPN
eurjchem-1774	129	27	]	]	PUNCT
eurjchem-1774	129	28	.	.	PUNCT
eurjchem-1774	130	1	figure	figure	NOUN
eurjchem-1774	130	2	7a	7a	NOUN
eurjchem-1774	130	3	shows	show	VERB
eurjchem-1774	130	4	the	the	DET
eurjchem-1774	130	5	overlay	overlay	NOUN
eurjchem-1774	130	6	diagram	diagram	NOUN
eurjchem-1774	130	7	of	of	ADP
eurjchem-1774	130	8	four	four	NUM
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eurjchem-1774	130	10	molecules	molecule	NOUN
eurjchem-1774	130	11	in	in	ADP
eurjchem-1774	130	12	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	130	13	-	-	PUNCT
eurjchem-1774	130	14	s	s	PROPN
eurjchem-1774	130	15	,	,	PUNCT
eurjchem-1774	130	16	o)2	o)2	PROPN
eurjchem-1774	130	17	]	]	PUNCT
eurjchem-1774	130	18	.	.	PUNCT
eurjchem-1774	131	1	the	the	DET
eurjchem-1774	131	2	overlay	overlay	NOUN
eurjchem-1774	131	3	diagram	diagram	NOUN
eurjchem-1774	131	4	illustrates	illustrate	VERB
eurjchem-1774	131	5	that	that	SCONJ
eurjchem-1774	131	6	the	the	DET
eurjchem-1774	131	7	conformation	conformation	NOUN
eurjchem-1774	131	8	of	of	ADP
eurjchem-1774	131	9	the	the	DET
eurjchem-1774	131	10	molecule	molecule	NOUN
eurjchem-1774	131	11	a	a	PRON
eurjchem-1774	131	12	is	be	AUX
eurjchem-1774	131	13	more	more	ADV
eurjchem-1774	131	14	similar	similar	ADJ
eurjchem-1774	131	15	to	to	ADP
eurjchem-1774	131	16	the	the	DET
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eurjchem-1774	131	18	d	d	NOUN
eurjchem-1774	131	19	,	,	PUNCT
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eurjchem-1774	131	22	conformation	conformation	NOUN
eurjchem-1774	131	23	of	of	ADP
eurjchem-1774	131	24	the	the	DET
eurjchem-1774	131	25	molecule	molecule	NOUN
eurjchem-1774	131	26	b	b	PROPN
eurjchem-1774	131	27	is	be	AUX
eurjchem-1774	131	28	more	more	ADV
eurjchem-1774	131	29	similar	similar	ADJ
eurjchem-1774	131	30	to	to	ADP
eurjchem-1774	131	31	the	the	DET
eurjchem-1774	131	32	molecule	molecule	NOUN
eurjchem-1774	131	33	c.	c.	NOUN
eurjchem-1774	131	34	the	the	DET
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eurjchem-1774	131	37	of	of	ADP
eurjchem-1774	131	38	cis-[pt(l2s	cis-[pt(l2s	NOUN
eurjchem-1774	131	39	,	,	PUNCT
eurjchem-1774	131	40	o)2	o)2	PROPN
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eurjchem-1774	131	42	is	be	AUX
eurjchem-1774	131	43	shown	show	VERB
eurjchem-1774	131	44	in	in	ADP
eurjchem-1774	131	45	figures	figure	NOUN
eurjchem-1774	131	46	7b	7b	NUM
eurjchem-1774	131	47	.	.	PUNCT
eurjchem-1774	132	1	in	in	ADP
eurjchem-1774	132	2	the	the	DET
eurjchem-1774	132	3	crystal	crystal	NOUN
eurjchem-1774	132	4	packing	packing	NOUN
eurjchem-1774	132	5	of	of	ADP
eurjchem-1774	132	6	cis[pt(l2	cis[pt(l2	PROPN
eurjchem-1774	132	7	-	-	PUNCT
eurjchem-1774	132	8	s	s	PROPN
eurjchem-1774	132	9	,	,	PUNCT
eurjchem-1774	132	10	o)2	o)2	PROPN
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eurjchem-1774	132	12	,	,	PUNCT
eurjchem-1774	132	13	molecules	molecule	NOUN
eurjchem-1774	132	14	a	a	PRON
eurjchem-1774	132	15	,	,	PUNCT
eurjchem-1774	132	16	b	b	NOUN
eurjchem-1774	132	17	,	,	PUNCT
eurjchem-1774	132	18	c	c	PROPN
eurjchem-1774	132	19	and	and	CCONJ
eurjchem-1774	132	20	d	d	PROPN
eurjchem-1774	132	21	are	be	AUX
eurjchem-1774	132	22	represented	represent	VERB
eurjchem-1774	132	23	in	in	ADP
eurjchem-1774	132	24	green	green	ADJ
eurjchem-1774	132	25	,	,	PUNCT
eurjchem-1774	132	26	red	red	ADJ
eurjchem-1774	132	27	,	,	PUNCT
eurjchem-1774	132	28	pink	pink	ADJ
eurjchem-1774	132	29	and	and	CCONJ
eurjchem-1774	132	30	blue	blue	ADJ
eurjchem-1774	132	31	,	,	PUNCT
eurjchem-1774	132	32	respectively	respectively	ADV
eurjchem-1774	132	33	,	,	PUNCT
eurjchem-1774	132	34	forming	form	VERB
eurjchem-1774	132	35	an	an	DET
eurjchem-1774	132	36	inverted	inverted	ADJ
eurjchem-1774	132	37	head	head	NOUN
eurjchem-1774	132	38	-	-	PUNCT
eurjchem-1774	132	39	totail	totail	NOUN
eurjchem-1774	132	40	arrangement	arrangement	NOUN
eurjchem-1774	132	41	without	without	ADP
eurjchem-1774	132	42	any	any	DET
eurjchem-1774	132	43	significant	significant	ADJ
eurjchem-1774	132	44	hydrogen	hydrogen	NOUN
eurjchem-1774	132	45	bond	bond	NOUN
eurjchem-1774	132	46	interactions	interaction	NOUN
eurjchem-1774	132	47	.	.	PUNCT
eurjchem-1774	133	1	in	in	ADP
eurjchem-1774	133	2	both	both	DET
eurjchem-1774	133	3	complexes	complex	NOUN
eurjchem-1774	133	4	,	,	PUNCT
eurjchem-1774	133	5	the	the	DET
eurjchem-1774	133	6	reactions	reaction	NOUN
eurjchem-1774	133	7	between	between	ADP
eurjchem-1774	133	8	ligands	ligand	NOUN
eurjchem-1774	133	9	and	and	CCONJ
eurjchem-1774	133	10	pt(ii	pt(ii	PROPN
eurjchem-1774	133	11	)	)	PUNCT
eurjchem-1774	133	12	produces	produce	VERB
eurjchem-1774	133	13	metal	metal	NOUN
eurjchem-1774	133	14	-	-	PUNCT
eurjchem-1774	133	15	complexes	complex	NOUN
eurjchem-1774	133	16	with	with	ADP
eurjchem-1774	133	17	the	the	DET
eurjchem-1774	133	18	expected	expect	VERB
eurjchem-1774	133	19	ligandmetal	ligandmetal	ADJ
eurjchem-1774	133	20	ratio	ratio	NOUN
eurjchem-1774	133	21	of	of	ADP
eurjchem-1774	133	22	2:1	2:1	NUM
eurjchem-1774	133	23	in	in	ADP
eurjchem-1774	133	24	a	a	DET
eurjchem-1774	133	25	square	square	ADJ
eurjchem-1774	133	26	-	-	PUNCT
eurjchem-1774	133	27	planar	planar	ADJ
eurjchem-1774	133	28	geometry	geometry	NOUN
eurjchem-1774	133	29	.	.	PUNCT
eurjchem-1774	134	1	the	the	DET
eurjchem-1774	134	2	chelating	chelating	NOUN
eurjchem-1774	134	3	two	two	NUM
eurjchem-1774	134	4	benzamide	benzamide	NOUN
eurjchem-1774	134	5	ligands	ligand	NOUN
eurjchem-1774	134	6	are	be	AUX
eurjchem-1774	134	7	coordinated	coordinate	VERB
eurjchem-1774	134	8	with	with	ADP
eurjchem-1774	134	9	pt	pt	NOUN
eurjchem-1774	134	10	ion	ion	NOUN
eurjchem-1774	134	11	in	in	ADP
eurjchem-1774	134	12	a	a	DET
eurjchem-1774	134	13	monoanionic	monoanionic	ADJ
eurjchem-1774	134	14	bidentate	bidentate	NOUN
eurjchem-1774	134	15	mode	mode	NOUN
eurjchem-1774	134	16	,	,	PUNCT
eurjchem-1774	134	17	forming	form	VERB
eurjchem-1774	134	18	two	two	NUM
eurjchem-1774	134	19	six	six	NUM
eurjchem-1774	134	20	membered	membere	VERB
eurjchem-1774	134	21	chelate	chelate	NOUN
eurjchem-1774	134	22	rings	ring	NOUN
eurjchem-1774	134	23	(	(	PUNCT
eurjchem-1774	134	24	pt	pt	NOUN
eurjchem-1774	134	25	-	-	PUNCT
eurjchem-1774	134	26	scnco	scnco	NOUN
eurjchem-1774	134	27	)	)	PUNCT
eurjchem-1774	134	28	.	.	PUNCT
eurjchem-1774	135	1	the	the	DET
eurjchem-1774	135	2	six	six	NUM
eurjchem-1774	135	3	membered	membere	VERB
eurjchem-1774	135	4	rings	ring	NOUN
eurjchem-1774	135	5	are	be	AUX
eurjchem-1774	135	6	formed	form	VERB
eurjchem-1774	135	7	via	via	ADP
eurjchem-1774	135	8	oxygen	oxygen	NOUN
eurjchem-1774	135	9	and	and	CCONJ
eurjchem-1774	135	10	sulphur	sulphur	NOUN
eurjchem-1774	135	11	atoms	atom	NOUN
eurjchem-1774	135	12	,	,	PUNCT
eurjchem-1774	135	13	and	and	CCONJ
eurjchem-1774	135	14	dihedral	dihedral	ADJ
eurjchem-1774	135	15	angles	angle	NOUN
eurjchem-1774	135	16	between	between	ADP
eurjchem-1774	135	17	these	these	DET
eurjchem-1774	135	18	rings	ring	NOUN
eurjchem-1774	135	19	in	in	ADP
eurjchem-1774	135	20	the	the	DET
eurjchem-1774	135	21	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	135	22	-	-	PUNCT
eurjchem-1774	135	23	s	s	PROPN
eurjchem-1774	135	24	,	,	PUNCT
eurjchem-1774	135	25	o)2	o)2	PROPN
eurjchem-1774	135	26	]	]	PUNCT
eurjchem-1774	135	27	and	and	CCONJ
eurjchem-1774	135	28	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	135	29	-	-	PUNCT
eurjchem-1774	135	30	s	s	PROPN
eurjchem-1774	135	31	,	,	PUNCT
eurjchem-1774	135	32	o)2	o)2	PROPN
eurjchem-1774	135	33	]	]	PUNCT
eurjchem-1774	135	34	are	be	AUX
eurjchem-1774	135	35	6.89	6.89	NUM
eurjchem-1774	135	36	and	and	CCONJ
eurjchem-1774	135	37	20.37	20.37	NUM
eurjchem-1774	135	38	°	°	NOUN
eurjchem-1774	135	39	,	,	PUNCT
eurjchem-1774	135	40	respectively	respectively	ADV
eurjchem-1774	135	41	.	.	PUNCT
eurjchem-1774	136	1	the	the	DET
eurjchem-1774	136	2	bond	bond	NOUN
eurjchem-1774	136	3	angles	angle	VERB
eurjchem-1774	136	4	around	around	ADP
eurjchem-1774	136	5	the	the	DET
eurjchem-1774	136	6	platinum	platinum	NOUN
eurjchem-1774	136	7	ion	ion	NOUN
eurjchem-1774	136	8	are	be	AUX
eurjchem-1774	136	9	s1	s1	NOUN
eurjchem-1774	136	10	–	–	PUNCT
eurjchem-1774	136	11	pt1	pt1	PROPN
eurjchem-1774	136	12	–	–	PUNCT
eurjchem-1774	136	13	o1	o1	NOUN
eurjchem-1774	136	14	=	=	SYM
eurjchem-1774	136	15	94.99(17	94.99(17	NUM
eurjchem-1774	136	16	)	)	PUNCT
eurjchem-1774	136	17	°	°	PROPN
eurjchem-1774	136	18	for	for	ADP
eurjchem-1774	136	19	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	136	20	-	-	PUNCT
eurjchem-1774	136	21	s	s	PROPN
eurjchem-1774	136	22	,	,	PUNCT
eurjchem-1774	136	23	o)2	o)2	PROPN
eurjchem-1774	136	24	]	]	PUNCT
eurjchem-1774	136	25	and	and	CCONJ
eurjchem-1774	136	26	s1	s1	PROPN
eurjchem-1774	136	27	–	–	PUNCT
eurjchem-1774	136	28	pt1	pt1	PROPN
eurjchem-1774	136	29	–	–	PUNCT
eurjchem-1774	136	30	o1	o1	NOUN
eurjchem-1774	136	31	=	=	SYM
eurjchem-1774	136	32	94.91(9	94.91(9	NOUN
eurjchem-1774	136	33	)	)	PUNCT
eurjchem-1774	136	34	and	and	CCONJ
eurjchem-1774	136	35	s2	s2	PROPN
eurjchem-1774	136	36	–	–	PUNCT
eurjchem-1774	136	37	pt1	pt1	PROPN
eurjchem-1774	136	38	–	–	PUNCT
eurjchem-1774	136	39	o2	o2	ADJ
eurjchem-1774	136	40	=	=	SYM
eurjchem-1774	136	41	93.89(10	93.89(10	NUM
eurjchem-1774	136	42	)	)	PUNCT
eurjchem-1774	136	43	°	°	PROPN
eurjchem-1774	136	44	for	for	ADP
eurjchem-1774	136	45	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	136	46	-	-	PUNCT
eurjchem-1774	136	47	s	s	PROPN
eurjchem-1774	136	48	,	,	PUNCT
eurjchem-1774	136	49	o)2	o)2	PROPN
eurjchem-1774	136	50	]	]	PUNCT
eurjchem-1774	136	51	(	(	PUNCT
eurjchem-1774	136	52	table	table	NOUN
eurjchem-1774	136	53	3	3	NUM
eurjchem-1774	136	54	)	)	PUNCT
eurjchem-1774	136	55	.	.	PUNCT
eurjchem-1774	137	1	the	the	DET
eurjchem-1774	137	2	platinum	platinum	NOUN
eurjchem-1774	137	3	center	center	NOUN
eurjchem-1774	137	4	,	,	PUNCT
eurjchem-1774	137	5	surrounded	surround	VERB
eurjchem-1774	137	6	by	by	ADP
eurjchem-1774	137	7	oxygen	oxygen	NOUN
eurjchem-1774	137	8	and	and	CCONJ
eurjchem-1774	137	9	sulphur	sulphur	NOUN
eurjchem-1774	137	10	atoms	atom	NOUN
eurjchem-1774	137	11	in	in	ADP
eurjchem-1774	137	12	complexes	complex	NOUN
eurjchem-1774	137	13	,	,	PUNCT
eurjchem-1774	137	14	is	be	AUX
eurjchem-1774	137	15	caused	cause	VERB
eurjchem-1774	137	16	by	by	ADP
eurjchem-1774	137	17	a	a	DET
eurjchem-1774	137	18	slightly	slightly	ADV
eurjchem-1774	137	19	distorted	distorted	ADJ
eurjchem-1774	137	20	square	square	ADJ
eurjchem-1774	137	21	planar	planar	ADJ
eurjchem-1774	137	22	geometry	geometry	NOUN
eurjchem-1774	137	23	as	as	SCONJ
eurjchem-1774	137	24	shown	show	VERB
eurjchem-1774	137	25	in	in	ADP
eurjchem-1774	137	26	figure	figure	NOUN
eurjchem-1774	137	27	3	3	NUM
eurjchem-1774	137	28	.	.	PUNCT
eurjchem-1774	138	1	the	the	DET
eurjchem-1774	138	2	bite	bite	NOUN
eurjchem-1774	138	3	angles	angle	NOUN
eurjchem-1774	138	4	of	of	ADP
eurjchem-1774	138	5	the	the	DET
eurjchem-1774	138	6	complexes	complex	NOUN
eurjchem-1774	138	7	deviate	deviate	VERB
eurjchem-1774	138	8	slightly	slightly	ADV
eurjchem-1774	138	9	from	from	ADP
eurjchem-1774	138	10	the	the	DET
eurjchem-1774	138	11	ideal	ideal	ADJ
eurjchem-1774	138	12	angle	angle	NOUN
eurjchem-1774	138	13	(	(	PUNCT
eurjchem-1774	138	14	90	90	NUM
eurjchem-1774	138	15	°	°	NUM
eurjchem-1774	138	16	)	)	PUNCT
eurjchem-1774	138	17	.	.	PUNCT
eurjchem-1774	139	1	the	the	DET
eurjchem-1774	139	2	value	value	NOUN
eurjchem-1774	139	3	of	of	ADP
eurjchem-1774	139	4	the	the	DET
eurjchem-1774	139	5	smallest	small	ADJ
eurjchem-1774	139	6	and	and	CCONJ
eurjchem-1774	139	7	largest	large	ADJ
eurjchem-1774	139	8	bite	bite	NOUN
eurjchem-1774	139	9	angles	angle	NOUN
eurjchem-1774	139	10	are	be	AUX
eurjchem-1774	139	11	93.89(10	93.89(10	NUM
eurjchem-1774	139	12	)	)	PUNCT
eurjchem-1774	139	13	and	and	CCONJ
eurjchem-1774	139	14	94.99(17	94.99(17	NUM
eurjchem-1774	139	15	)	)	PUNCT
eurjchem-1774	139	16	°	°	NOUN
eurjchem-1774	139	17	,	,	PUNCT
eurjchem-1774	139	18	respectively	respectively	ADV
eurjchem-1774	139	19	.	.	PUNCT
eurjchem-1774	140	1	the	the	DET
eurjchem-1774	140	2	sum	sum	NOUN
eurjchem-1774	140	3	of	of	ADP
eurjchem-1774	140	4	the	the	DET
eurjchem-1774	140	5	equatorial	equatorial	NOUN
eurjchem-1774	140	6	angles	angle	VERB
eurjchem-1774	140	7	s1	s1	NOUN
eurjchem-1774	140	8	-	-	PUNCT
eurjchem-1774	140	9	pt1	pt1	NOUN
eurjchem-1774	140	10	-	-	PUNCT
eurjchem-1774	140	11	o1	o1	NOUN
eurjchem-1774	140	12	,	,	PUNCT
eurjchem-1774	140	13	s2pt1	s2pt1	ADJ
eurjchem-1774	140	14	-	-	PUNCT
eurjchem-1774	140	15	o2	o2	ADJ
eurjchem-1774	140	16	,	,	PUNCT
eurjchem-1774	140	17	s1	s1	NOUN
eurjchem-1774	140	18	-	-	PUNCT
eurjchem-1774	140	19	pt1	pt1	NOUN
eurjchem-1774	140	20	-	-	NOUN
eurjchem-1774	140	21	s2	s2	NOUN
eurjchem-1774	140	22	and	and	CCONJ
eurjchem-1774	140	23	o1	o1	NOUN
eurjchem-1774	140	24	-	-	PUNCT
eurjchem-1774	140	25	pt1	pt1	NOUN
eurjchem-1774	140	26	-	-	PUNCT
eurjchem-1774	140	27	o2	o2	PROPN
eurjchem-1774	140	28	are	be	AUX
eurjchem-1774	140	29	360.01	360.01	NUM
eurjchem-1774	140	30	°	°	NUM
eurjchem-1774	140	31	and	and	CCONJ
eurjchem-1774	140	32	equal	equal	ADJ
eurjchem-1774	140	33	to	to	ADP
eurjchem-1774	140	34	the	the	DET
eurjchem-1774	140	35	ideal	ideal	ADJ
eurjchem-1774	140	36	value	value	NOUN
eurjchem-1774	140	37	of	of	ADP
eurjchem-1774	140	38	360.00	360.00	NUM
eurjchem-1774	140	39	°	°	NOUN
eurjchem-1774	140	40	,	,	PUNCT
eurjchem-1774	140	41	which	which	PRON
eurjchem-1774	140	42	is	be	AUX
eurjchem-1774	140	43	consistent	consistent	ADJ
eurjchem-1774	140	44	with	with	ADP
eurjchem-1774	140	45	square	square	ADJ
eurjchem-1774	140	46	planar	planar	ADJ
eurjchem-1774	140	47	geometry	geometry	NOUN
eurjchem-1774	140	48	.	.	PUNCT
eurjchem-1774	141	1	other	other	ADJ
eurjchem-1774	141	2	values	value	NOUN
eurjchem-1774	141	3	of	of	ADP
eurjchem-1774	141	4	bond	bond	NOUN
eurjchem-1774	141	5	angles	angle	NOUN
eurjchem-1774	141	6	are	be	AUX
eurjchem-1774	141	7	given	give	VERB
eurjchem-1774	141	8	in	in	ADP
eurjchem-1774	141	9	table	table	NOUN
eurjchem-1774	141	10	3	3	NUM
eurjchem-1774	141	11	.	.	PUNCT
eurjchem-1774	142	1	in	in	ADP
eurjchem-1774	142	2	the	the	DET
eurjchem-1774	142	3	both	both	DET
eurjchem-1774	142	4	complexes	complex	NOUN
eurjchem-1774	142	5	,	,	PUNCT
eurjchem-1774	142	6	the	the	DET
eurjchem-1774	142	7	c(o	c(o	NOUN
eurjchem-1774	142	8	)	)	PUNCT
eurjchem-1774	142	9	and	and	CCONJ
eurjchem-1774	142	10	c(s	c(	NOUN
eurjchem-1774	142	11	)	)	PUNCT
eurjchem-1774	142	12	bond	bond	NOUN
eurjchem-1774	142	13	lenghts	lenght	NOUN
eurjchem-1774	142	14	are	be	AUX
eurjchem-1774	142	15	1.292(9	1.292(9	NUM
eurjchem-1774	142	16	)	)	PUNCT
eurjchem-1774	142	17	and	and	CCONJ
eurjchem-1774	142	18	1.721(8	1.721(8	NUM
eurjchem-1774	142	19	)	)	PUNCT
eurjchem-1774	142	20	å	å	PROPN
eurjchem-1774	142	21	for	for	ADP
eurjchem-1774	142	22	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	142	23	-	-	PUNCT
eurjchem-1774	142	24	s	s	PROPN
eurjchem-1774	142	25	,	,	PUNCT
eurjchem-1774	142	26	o)2	o)2	PROPN
eurjchem-1774	142	27	]	]	PUNCT
eurjchem-1774	142	28	and	and	CCONJ
eurjchem-1774	142	29	1.277(5	1.277(5	NUM
eurjchem-1774	142	30	)	)	PUNCT
eurjchem-1774	142	31	and	and	CCONJ
eurjchem-1774	142	32	1.736(4	1.736(4	NUM
eurjchem-1774	142	33	)	)	PUNCT
eurjchem-1774	142	34	å	å	PROPN
eurjchem-1774	142	35	for	for	ADP
eurjchem-1774	142	36	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	142	37	-	-	PUNCT
eurjchem-1774	142	38	s	s	PROPN
eurjchem-1774	142	39	,	,	PUNCT
eurjchem-1774	142	40	o)2	o)2	PROPN
eurjchem-1774	142	41	]	]	PUNCT
eurjchem-1774	142	42	,	,	PUNCT
eurjchem-1774	142	43	which	which	PRON
eurjchem-1774	142	44	are	be	AUX
eurjchem-1774	142	45	slightly	slightly	ADV
eurjchem-1774	142	46	longer	long	ADJ
eurjchem-1774	142	47	than	than	ADP
eurjchem-1774	142	48	the	the	DET
eurjchem-1774	142	49	corresponding	correspond	VERB
eurjchem-1774	142	50	distance	distance	NOUN
eurjchem-1774	142	51	found	find	VERB
eurjchem-1774	142	52	in	in	ADP
eurjchem-1774	142	53	similar	similar	ADJ
eurjchem-1774	142	54	free	free	ADJ
eurjchem-1774	142	55	ligands	ligand	NOUN
eurjchem-1774	142	56	[	[	X
eurjchem-1774	142	57	47	47	NUM
eurjchem-1774	142	58	]	]	PUNCT
eurjchem-1774	142	59	.	.	PUNCT
eurjchem-1774	143	1	2018	2018	NUM
eurjchem-1774	143	2	–	–	PUNCT
eurjchem-1774	143	3	european	european	ADJ
eurjchem-1774	143	4	journal	journal	NOUN
eurjchem-1774	143	5	of	of	ADP
eurjchem-1774	143	6	chemistry	chemistry	NOUN
eurjchem-1774	143	7	–	–	PUNCT
eurjchem-1774	143	8	cc	cc	NOUN
eurjchem-1774	143	9	by	by	ADP
eurjchem-1774	143	10	nc	nc	PROPN
eurjchem-1774	143	11	–	–	PUNCT
eurjchem-1774	143	12	doi	doi	PROPN
eurjchem-1774	143	13	:	:	PUNCT
eurjchem-1774	143	14	10.5155	10.5155	NUM
eurjchem-1774	143	15	/	/	SYM
eurjchem-1774	143	16	eurjchem.9.4.360	eurjchem.9.4.360	NOUN
eurjchem-1774	143	17	-	-	SYM
eurjchem-1774	143	18	368.1774	368.1774	NUM
eurjchem-1774	143	19	keskin	keskin	PROPN
eurjchem-1774	143	20	et	et	PROPN
eurjchem-1774	143	21	al	al	PROPN
eurjchem-1774	143	22	.	.	PUNCT
eurjchem-1774	143	23	/	/	SYM
eurjchem-1774	143	24	european	european	PROPN
eurjchem-1774	143	25	journal	journal	PROPN
eurjchem-1774	143	26	of	of	ADP
eurjchem-1774	143	27	chemistry	chemistry	NOUN
eurjchem-1774	143	28	9	9	NUM
eurjchem-1774	143	29	(	(	PUNCT
eurjchem-1774	143	30	4	4	NUM
eurjchem-1774	143	31	)	)	PUNCT
eurjchem-1774	143	32	(	(	PUNCT
eurjchem-1774	143	33	2018	2018	NUM
eurjchem-1774	143	34	)	)	PUNCT
eurjchem-1774	143	35	360	360	NUM
eurjchem-1774	143	36	-	-	SYM
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eurjchem-1774	163	14	,	,	PUNCT
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eurjchem-1774	163	23	)	)	PUNCT
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eurjchem-1774	163	42	-	-	PROPN
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eurjchem-1774	164	6	interactions	interaction	NOUN
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eurjchem-1774	164	14	a	a	DET
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eurjchem-1774	164	16	-	-	PUNCT
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eurjchem-1774	164	20	3.902(5	3.902(5	NOUN
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eurjchem-1774	164	25	)	)	PUNCT
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eurjchem-1774	164	27	)	)	PUNCT
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eurjchem-1774	164	30	symmetry	symmetry	PROPN
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eurjchem-1774	164	34	-	-	PUNCT
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eurjchem-1774	164	52	,	,	PUNCT
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eurjchem-1774	164	68	nc	nc	PROPN
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eurjchem-1774	164	75	-	-	SYM
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eurjchem-1774	164	82	/	/	SYM
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eurjchem-1774	164	87	9	9	NUM
eurjchem-1774	164	88	(	(	PUNCT
eurjchem-1774	164	89	4	4	NUM
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eurjchem-1774	164	91	(	(	PUNCT
eurjchem-1774	164	92	2018	2018	NUM
eurjchem-1774	164	93	)	)	PUNCT
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eurjchem-1774	164	95	-	-	SYM
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eurjchem-1774	165	1	(	(	PUNCT
eurjchem-1774	165	2	a	a	X
eurjchem-1774	165	3	)	)	PUNCT
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eurjchem-1774	165	8	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	165	9	-	-	PUNCT
eurjchem-1774	165	10	s	s	PROPN
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eurjchem-1774	165	14	,	,	PUNCT
eurjchem-1774	165	15	(	(	PUNCT
eurjchem-1774	165	16	b	b	NOUN
eurjchem-1774	165	17	)	)	PUNCT
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eurjchem-1774	165	22	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	165	23	-	-	PUNCT
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eurjchem-1774	165	31	equivalence	equivalence	NOUN
eurjchem-1774	165	32	(	(	PUNCT
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eurjchem-1774	165	34	molecule	molecule	PROPN
eurjchem-1774	165	35	a	a	PRON
eurjchem-1774	165	36	,	,	PUNCT
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eurjchem-1774	165	38	molecule	molecule	NOUN
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eurjchem-1774	165	47	d	d	NOUN
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eurjchem-1774	166	7	cis-[pt(l1	cis-[pt(l1	PROPN
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eurjchem-1774	166	17	h⋯π	h⋯π	PUNCT
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eurjchem-1774	166	19	interactions	interaction	NOUN
eurjchem-1774	166	20	.	.	PUNCT
eurjchem-1774	167	1	figure	figure	NOUN
eurjchem-1774	167	2	9	9	NUM
eurjchem-1774	167	3	.	.	PUNCT
eurjchem-1774	167	4	supramolecular	supramolecular	ADJ
eurjchem-1774	167	5	structure	structure	NOUN
eurjchem-1774	167	6	in	in	ADP
eurjchem-1774	167	7	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	167	8	-	-	PUNCT
eurjchem-1774	167	9	s	s	PROPN
eurjchem-1774	167	10	,	,	PUNCT
eurjchem-1774	167	11	o)2	o)2	PROPN
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eurjchem-1774	167	14	via	via	ADP
eurjchem-1774	167	15	π⋯π	π⋯π	PRON
eurjchem-1774	167	16	stacking	stack	VERB
eurjchem-1774	167	17	interactions	interaction	NOUN
eurjchem-1774	167	18	.	.	PUNCT
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eurjchem-1774	168	3	3.902(5	3.902(5	PROPN
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eurjchem-1774	168	5	å	å	PROPN
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eurjchem-1774	168	7	symmetry	symmetry	PROPN
eurjchem-1774	168	8	code	code	PROPN
eurjchem-1774	168	9	:	:	PUNCT
eurjchem-1774	168	10	3/4	3/4	NUM
eurjchem-1774	168	11	-	-	PUNCT
eurjchem-1774	168	12	x	x	NOUN
eurjchem-1774	168	13	,	,	PUNCT
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eurjchem-1774	168	22	å	å	PROPN
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eurjchem-1774	168	24	symmetry	symmetry	PROPN
eurjchem-1774	168	25	code	code	PROPN
eurjchem-1774	168	26	:	:	PUNCT
eurjchem-1774	168	27	1/4+x	1/4+x	NUM
eurjchem-1774	168	28	,	,	PUNCT
eurjchem-1774	168	29	1/4	1/4	NUM
eurjchem-1774	168	30	-	-	PUNCT
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eurjchem-1774	168	32	,	,	PUNCT
eurjchem-1774	168	33	1/4+z	1/4+z	NUM
eurjchem-1774	168	34	)	)	PUNCT
eurjchem-1774	168	35	(	(	PUNCT
eurjchem-1774	168	36	figure	figure	NOUN
eurjchem-1774	168	37	9	9	NUM
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eurjchem-1774	168	39	.	.	PUNCT
eurjchem-1774	169	1	these	these	DET
eurjchem-1774	169	2	two	two	NUM
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eurjchem-1774	169	4	stacking	stacking	NOUN
eurjchem-1774	169	5	interactions	interaction	NOUN
eurjchem-1774	169	6	in	in	ADP
eurjchem-1774	169	7	the	the	DET
eurjchem-1774	169	8	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	169	9	-	-	PUNCT
eurjchem-1774	169	10	s	s	PROPN
eurjchem-1774	169	11	,	,	PUNCT
eurjchem-1774	169	12	o)2	o)2	PROPN
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eurjchem-1774	169	16	the	the	DET
eurjchem-1774	169	17	stability	stability	NOUN
eurjchem-1774	169	18	of	of	ADP
eurjchem-1774	169	19	its	its	PRON
eurjchem-1774	169	20	three	three	NUM
eurjchem-1774	169	21	dimensional	dimensional	ADJ
eurjchem-1774	169	22	supramolecular	supramolecular	ADJ
eurjchem-1774	169	23	structure	structure	NOUN
eurjchem-1774	169	24	.	.	PUNCT
eurjchem-1774	170	1	the	the	DET
eurjchem-1774	170	2	supramolecular	supramolecular	ADJ
eurjchem-1774	170	3	structure	structure	NOUN
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eurjchem-1774	170	5	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	170	6	-	-	PUNCT
eurjchem-1774	170	7	s	s	PROPN
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eurjchem-1774	170	15	formation	formation	NOUN
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eurjchem-1774	170	17	a	a	DET
eurjchem-1774	170	18	series	series	NOUN
eurjchem-1774	170	19	c	c	PROPN
eurjchem-1774	170	20	-	-	PUNCT
eurjchem-1774	170	21	h∙∙∙π	h∙∙∙π	NOUN
eurjchem-1774	170	22	stacking	stacking	NOUN
eurjchem-1774	170	23	interactions	interaction	NOUN
eurjchem-1774	170	24	,	,	PUNCT
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eurjchem-1774	170	26	contribute	contribute	VERB
eurjchem-1774	170	27	to	to	ADP
eurjchem-1774	170	28	the	the	DET
eurjchem-1774	170	29	stability	stability	NOUN
eurjchem-1774	170	30	of	of	ADP
eurjchem-1774	170	31	the	the	DET
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eurjchem-1774	170	36	asymmetric	asymmetric	ADJ
eurjchem-1774	170	37	unit	unit	NOUN
eurjchem-1774	170	38	of	of	ADP
eurjchem-1774	170	39	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	170	40	-	-	PUNCT
eurjchem-1774	170	41	s	s	PROPN
eurjchem-1774	170	42	,	,	PUNCT
eurjchem-1774	170	43	o)2	o)2	PROPN
eurjchem-1774	170	44	]	]	PUNCT
eurjchem-1774	170	45	.	.	PUNCT
eurjchem-1774	171	1	the	the	DET
eurjchem-1774	171	2	four	four	NUM
eurjchem-1774	171	3	independent	independent	ADJ
eurjchem-1774	171	4	molecules	molecule	NOUN
eurjchem-1774	171	5	in	in	ADP
eurjchem-1774	171	6	the	the	DET
eurjchem-1774	171	7	asymmetric	asymmetric	ADJ
eurjchem-1774	171	8	unit	unit	NOUN
eurjchem-1774	171	9	of	of	ADP
eurjchem-1774	171	10	cis-[pt(l2s	cis-[pt(l2s	NOUN
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eurjchem-1774	172	2	interactions	interaction	NOUN
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eurjchem-1774	172	5	the	the	DET
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eurjchem-1774	172	10	moiety	moiety	NOUN
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eurjchem-1774	173	8	cis-[pt(l2	cis-[pt(l2	PROPN
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eurjchem-1774	173	11	,	,	PUNCT
eurjchem-1774	173	12	o)2	o)2	PROPN
eurjchem-1774	173	13	]	]	PUNCT
eurjchem-1774	173	14	are	be	AUX
eurjchem-1774	173	15	again	again	ADV
eurjchem-1774	173	16	held	hold	VERB
eurjchem-1774	173	17	together	together	ADV
eurjchem-1774	173	18	by	by	ADP
eurjchem-1774	173	19	strong	strong	ADJ
eurjchem-1774	173	20	c	c	PROPN
eurjchem-1774	173	21	-	-	PUNCT
eurjchem-1774	173	22	h···π	h···π	NOUN
eurjchem-1774	173	23	stacking	stack	VERB
eurjchem-1774	173	24	interactions	interaction	NOUN
eurjchem-1774	173	25	.	.	PUNCT
eurjchem-1774	174	1	however	however	ADV
eurjchem-1774	174	2	,	,	PUNCT
eurjchem-1774	174	3	these	these	DET
eurjchem-1774	174	4	interactions	interaction	NOUN
eurjchem-1774	174	5	occur	occur	VERB
eurjchem-1774	174	6	between	between	ADP
eurjchem-1774	174	7	the	the	DET
eurjchem-1774	174	8	hydrogen	hydrogen	NOUN
eurjchem-1774	174	9	atoms	atom	NOUN
eurjchem-1774	174	10	of	of	ADP
eurjchem-1774	174	11	dipropyl	dipropyl	ADJ
eurjchem-1774	174	12	moiety	moiety	NOUN
eurjchem-1774	174	13	and	and	CCONJ
eurjchem-1774	174	14	the	the	DET
eurjchem-1774	174	15	hydrogen	hydrogen	NOUN
eurjchem-1774	174	16	atoms	atom	NOUN
eurjchem-1774	174	17	,	,	PUNCT
eurjchem-1774	174	18	which	which	PRON
eurjchem-1774	174	19	are	be	AUX
eurjchem-1774	174	20	different	different	ADJ
eurjchem-1774	174	21	from	from	ADP
eurjchem-1774	174	22	the	the	DET
eurjchem-1774	174	23	others	other	NOUN
eurjchem-1774	174	24	(	(	PUNCT
eurjchem-1774	174	25	c11	c11	NOUN
eurjchem-1774	174	26	-	-	PUNCT
eurjchem-1774	174	27	h11b⋅⋅⋅π	h11b⋅⋅⋅π	NOUN
eurjchem-1774	174	28	2.92	2.92	NUM
eurjchem-1774	174	29	å	å	NOUN
eurjchem-1774	174	30	,	,	PUNCT
eurjchem-1774	174	31	∠156	∠156	NOUN
eurjchem-1774	174	32	°	°	PROPN
eurjchem-1774	174	33	with	with	ADP
eurjchem-1774	174	34	symmetry	symmetry	PROPN
eurjchem-1774	174	35	code	code	PROPN
eurjchem-1774	174	36	:	:	PUNCT
eurjchem-1774	174	37	x	x	X
eurjchem-1774	174	38	,	,	PUNCT
eurjchem-1774	174	39	y	y	PROPN
eurjchem-1774	174	40	,	,	PUNCT
eurjchem-1774	174	41	z	z	PROPN
eurjchem-1774	174	42	;	;	PUNCT
eurjchem-1774	174	43	c11c	c11c	X
eurjchem-1774	174	44	-	-	PUNCT
eurjchem-1774	174	45	h11e⋅⋅⋅π	h11e⋅⋅⋅π	ADV
eurjchem-1774	174	46	2.89	2.89	NUM
eurjchem-1774	174	47	å	å	NOUN
eurjchem-1774	174	48	,	,	PUNCT
eurjchem-1774	174	49	∠156	∠156	NOUN
eurjchem-1774	174	50	°	°	PROPN
eurjchem-1774	174	51	with	with	ADP
eurjchem-1774	174	52	symmetry	symmetry	PROPN
eurjchem-1774	174	53	code	code	PROPN
eurjchem-1774	174	54	:	:	PUNCT
eurjchem-1774	174	55	x	x	X
eurjchem-1774	174	56	,	,	PUNCT
eurjchem-1774	174	57	1+y	1+y	NUM
eurjchem-1774	174	58	,	,	PUNCT
eurjchem-1774	174	59	z	z	NOUN
eurjchem-1774	174	60	;	;	PUNCT
eurjchem-1774	174	61	c11a	c11a	ADV
eurjchem-1774	174	62	-	-	PUNCT
eurjchem-1774	174	63	h11h⋅⋅⋅π	h11h⋅⋅⋅π	VERB
eurjchem-1774	174	64	2.92	2.92	NUM
eurjchem-1774	174	65	å	å	NOUN
eurjchem-1774	174	66	,	,	PUNCT
eurjchem-1774	174	67	∠164	∠164	NOUN
eurjchem-1774	174	68	°	°	PROPN
eurjchem-1774	174	69	with	with	ADP
eurjchem-1774	174	70	symmetry	symmetry	NOUN
eurjchem-1774	174	71	code	code	PROPN
eurjchem-1774	174	72	:	:	PUNCT
eurjchem-1774	174	73	x	x	X
eurjchem-1774	174	74	,	,	PUNCT
eurjchem-1774	174	75	-1+y	-1+y	INTJ
eurjchem-1774	174	76	,	,	PUNCT
eurjchem-1774	174	77	z	z	NOUN
eurjchem-1774	174	78	;	;	PUNCT
eurjchem-1774	174	79	c11b	c11b	NOUN
eurjchem-1774	174	80	-	-	PUNCT
eurjchem-1774	174	81	h11k⋅⋅⋅π	h11k⋅⋅⋅π	SYM
eurjchem-1774	174	82	2.95	2.95	NUM
eurjchem-1774	174	83	å	å	NOUN
eurjchem-1774	174	84	,	,	PUNCT
eurjchem-1774	174	85	∠162	∠162	ADV
eurjchem-1774	174	86	°	°	PROPN
eurjchem-1774	174	87	with	with	ADP
eurjchem-1774	174	88	symmetry	symmetry	NOUN
eurjchem-1774	174	89	code	code	PROPN
eurjchem-1774	174	90	:	:	PUNCT
eurjchem-1774	174	91	x	x	X
eurjchem-1774	174	92	,	,	PUNCT
eurjchem-1774	174	93	y	y	PROPN
eurjchem-1774	174	94	,	,	PUNCT
eurjchem-1774	174	95	z	z	NOUN
eurjchem-1774	174	96	)	)	PUNCT
eurjchem-1774	174	97	.	.	PUNCT
eurjchem-1774	175	1	2018	2018	NUM
eurjchem-1774	175	2	–	–	PUNCT
eurjchem-1774	175	3	european	european	ADJ
eurjchem-1774	175	4	journal	journal	NOUN
eurjchem-1774	175	5	of	of	ADP
eurjchem-1774	175	6	chemistry	chemistry	NOUN
eurjchem-1774	175	7	–	–	PUNCT
eurjchem-1774	175	8	cc	cc	NOUN
eurjchem-1774	175	9	by	by	ADP
eurjchem-1774	175	10	nc	nc	PROPN
eurjchem-1774	175	11	–	–	PUNCT
eurjchem-1774	175	12	doi	doi	PROPN
eurjchem-1774	175	13	:	:	PUNCT
eurjchem-1774	175	14	10.5155	10.5155	NUM
eurjchem-1774	175	15	/	/	SYM
eurjchem-1774	175	16	eurjchem.9.4.360	eurjchem.9.4.360	NOUN
eurjchem-1774	175	17	-	-	SYM
eurjchem-1774	175	18	368.1774	368.1774	NUM
eurjchem-1774	175	19	keskin	keskin	PROPN
eurjchem-1774	175	20	et	et	PROPN
eurjchem-1774	175	21	al	al	PROPN
eurjchem-1774	175	22	.	.	PUNCT
eurjchem-1774	175	23	/	/	SYM
eurjchem-1774	175	24	european	european	PROPN
eurjchem-1774	175	25	journal	journal	PROPN
eurjchem-1774	175	26	of	of	ADP
eurjchem-1774	175	27	chemistry	chemistry	NOUN
eurjchem-1774	175	28	9	9	NUM
eurjchem-1774	175	29	(	(	PUNCT
eurjchem-1774	175	30	4	4	NUM
eurjchem-1774	175	31	)	)	PUNCT
eurjchem-1774	175	32	(	(	PUNCT
eurjchem-1774	175	33	2018	2018	NUM
eurjchem-1774	175	34	)	)	PUNCT
eurjchem-1774	175	35	360	360	NUM
eurjchem-1774	175	36	-	-	SYM
eurjchem-1774	175	37	368	368	NUM
eurjchem-1774	175	38	367	367	NUM
eurjchem-1774	175	39	(	(	PUNCT
eurjchem-1774	175	40	a	a	NOUN
eurjchem-1774	175	41	)	)	PUNCT
eurjchem-1774	175	42	(	(	PUNCT
eurjchem-1774	175	43	b	b	X
eurjchem-1774	175	44	)	)	PUNCT
eurjchem-1774	175	45	figure	figure	NOUN
eurjchem-1774	175	46	10	10	NUM
eurjchem-1774	175	47	.	.	PUNCT
eurjchem-1774	176	1	(	(	PUNCT
eurjchem-1774	176	2	a	a	X
eurjchem-1774	176	3	)	)	PUNCT
eurjchem-1774	176	4	c	c	AUX
eurjchem-1774	176	5	-	-	PUNCT
eurjchem-1774	176	6	h⋯π	h⋯π	PUNCT
eurjchem-1774	176	7	stacking	stacking	NOUN
eurjchem-1774	176	8	interactions	interaction	NOUN
eurjchem-1774	176	9	in	in	ADP
eurjchem-1774	176	10	asymmetric	asymmetric	ADJ
eurjchem-1774	176	11	unit	unit	NOUN
eurjchem-1774	176	12	of	of	ADP
eurjchem-1774	176	13	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	176	14	-	-	PUNCT
eurjchem-1774	176	15	s	s	PROPN
eurjchem-1774	176	16	,	,	PUNCT
eurjchem-1774	176	17	o)2	o)2	PROPN
eurjchem-1774	176	18	]	]	PUNCT
eurjchem-1774	176	19	,	,	PUNCT
eurjchem-1774	176	20	(	(	PUNCT
eurjchem-1774	176	21	b	b	X
eurjchem-1774	176	22	)	)	PUNCT
eurjchem-1774	176	23	strong	strong	ADJ
eurjchem-1774	176	24	c	c	NOUN
eurjchem-1774	176	25	-	-	PUNCT
eurjchem-1774	176	26	h⋯π	h⋯π	PUNCT
eurjchem-1774	176	27	stacking	stacking	NOUN
eurjchem-1774	176	28	interactions	interaction	NOUN
eurjchem-1774	176	29	in	in	ADP
eurjchem-1774	176	30	crystal	crystal	NOUN
eurjchem-1774	176	31	lattice	lattice	NOUN
eurjchem-1774	176	32	of	of	ADP
eurjchem-1774	176	33	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	176	34	-	-	PUNCT
eurjchem-1774	176	35	s	s	PROPN
eurjchem-1774	176	36	,	,	PUNCT
eurjchem-1774	176	37	o)2	o)2	PROPN
eurjchem-1774	176	38	]	]	PUNCT
eurjchem-1774	176	39	.	.	PUNCT
eurjchem-1774	177	1	the	the	DET
eurjchem-1774	177	2	c	c	PROPN
eurjchem-1774	177	3	–	–	PUNCT
eurjchem-1774	177	4	h···π	h···π	PROPN
eurjchem-1774	177	5	lengths	length	NOUN
eurjchem-1774	177	6	in	in	ADP
eurjchem-1774	177	7	the	the	DET
eurjchem-1774	177	8	crystal	crystal	NOUN
eurjchem-1774	177	9	lattice	lattice	NOUN
eurjchem-1774	177	10	are	be	AUX
eurjchem-1774	177	11	about	about	ADV
eurjchem-1774	177	12	2.90	2.90	NUM
eurjchem-1774	177	13	å	å	NOUN
eurjchem-1774	177	14	,	,	PUNCT
eurjchem-1774	177	15	and	and	CCONJ
eurjchem-1774	177	16	are	be	AUX
eurjchem-1774	177	17	very	very	ADV
eurjchem-1774	177	18	close	close	ADJ
eurjchem-1774	177	19	the	the	DET
eurjchem-1774	177	20	optimal	optimal	ADJ
eurjchem-1774	177	21	values	value	NOUN
eurjchem-1774	177	22	(	(	PUNCT
eurjchem-1774	177	23	from	from	ADP
eurjchem-1774	177	24	2.8	2.8	NUM
eurjchem-1774	177	25	to	to	PART
eurjchem-1774	177	26	3.2	3.2	NUM
eurjchem-1774	177	27	å	å	NOUN
eurjchem-1774	177	28	)	)	PUNCT
eurjchem-1774	177	29	for	for	ADP
eurjchem-1774	177	30	the	the	DET
eurjchem-1774	177	31	strongest	strong	ADJ
eurjchem-1774	177	32	ch···π	ch···π	PROPN
eurjchem-1774	177	33	interactions	interaction	NOUN
eurjchem-1774	177	34	[	[	X
eurjchem-1774	177	35	57	57	NUM
eurjchem-1774	177	36	-	-	SYM
eurjchem-1774	177	37	59	59	NUM
eurjchem-1774	177	38	]	]	PUNCT
eurjchem-1774	177	39	.	.	PUNCT
eurjchem-1774	178	1	4	4	X
eurjchem-1774	178	2	.	.	X
eurjchem-1774	178	3	conclusion	conclusion	NOUN
eurjchem-1774	178	4	two	two	NUM
eurjchem-1774	178	5	platinum(ii	platinum(ii	NOUN
eurjchem-1774	178	6	)	)	PUNCT
eurjchem-1774	178	7	compounds	compound	NOUN
eurjchem-1774	178	8	,	,	PUNCT
eurjchem-1774	178	9	having	have	VERB
eurjchem-1774	178	10	the	the	DET
eurjchem-1774	178	11	general	general	ADJ
eurjchem-1774	178	12	formula	formula	NOUN
eurjchem-1774	178	13	,	,	PUNCT
eurjchem-1774	178	14	cis-[pt(l1,2	cis-[pt(l1,2	NOUN
eurjchem-1774	178	15	-	-	PUNCT
eurjchem-1774	178	16	s	s	PROPN
eurjchem-1774	178	17	,	,	PUNCT
eurjchem-1774	178	18	o)2	o)2	NOUN
eurjchem-1774	178	19	]	]	PUNCT
eurjchem-1774	178	20	with	with	ADP
eurjchem-1774	178	21	ligands	ligand	NOUN
eurjchem-1774	178	22	n-(di	n-(di	PROPN
eurjchem-1774	178	23	-	-	PUNCT
eurjchem-1774	178	24	n	n	CCONJ
eurjchem-1774	178	25	-	-	PUNCT
eurjchem-1774	178	26	propylcarbamothioyl)4	propylcarbamothioyl)4	NOUN
eurjchem-1774	178	27	-	-	PUNCT
eurjchem-1774	178	28	fluoro	fluoro	NOUN
eurjchem-1774	178	29	benzamide	benzamide	NOUN
eurjchem-1774	178	30	and	and	CCONJ
eurjchem-1774	178	31	n-(di	n-(di	PROPN
eurjchem-1774	178	32	-	-	PUNCT
eurjchem-1774	178	33	n	n	CCONJ
eurjchem-1774	178	34	-	-	PUNCT
eurjchem-1774	178	35	propylcarbamothioyl)-4bromo	propylcarbamothioyl)-4bromo	NOUN
eurjchem-1774	178	36	benzamide	benzamide	NOUN
eurjchem-1774	178	37	,	,	PUNCT
eurjchem-1774	178	38	have	have	AUX
eurjchem-1774	178	39	been	be	AUX
eurjchem-1774	178	40	prepared	prepare	VERB
eurjchem-1774	178	41	and	and	CCONJ
eurjchem-1774	178	42	characterized	characterize	VERB
eurjchem-1774	178	43	,	,	PUNCT
eurjchem-1774	178	44	where	where	SCONJ
eurjchem-1774	178	45	two	two	NUM
eurjchem-1774	178	46	monobasic	monobasic	NOUN
eurjchem-1774	178	47	o	o	NOUN
eurjchem-1774	178	48	,	,	PUNCT
eurjchem-1774	178	49	s	s	PART
eurjchem-1774	178	50	donor	donor	NOUN
eurjchem-1774	178	51	ligands	ligand	NOUN
eurjchem-1774	178	52	coordinate	coordinate	VERB
eurjchem-1774	178	53	to	to	PART
eurjchem-1774	178	54	platinum	platinum	NOUN
eurjchem-1774	178	55	in	in	ADP
eurjchem-1774	178	56	a	a	DET
eurjchem-1774	178	57	cis	cis	NOUN
eurjchem-1774	178	58	-	-	PUNCT
eurjchem-1774	178	59	o2s2	o2s2	NOUN
eurjchem-1774	178	60	conformation	conformation	NOUN
eurjchem-1774	178	61	.	.	PUNCT
eurjchem-1774	179	1	the	the	DET
eurjchem-1774	179	2	obtained	obtain	VERB
eurjchem-1774	179	3	complexes	complex	NOUN
eurjchem-1774	179	4	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	179	5	-	-	PUNCT
eurjchem-1774	179	6	s	s	PROPN
eurjchem-1774	179	7	,	,	PUNCT
eurjchem-1774	179	8	o)2	o)2	PROPN
eurjchem-1774	179	9	]	]	PUNCT
eurjchem-1774	179	10	and	and	CCONJ
eurjchem-1774	179	11	cis-[pt(l2	cis-[pt(l2	PROPN
eurjchem-1774	179	12	-	-	PUNCT
eurjchem-1774	179	13	s	s	PROPN
eurjchem-1774	179	14	,	,	PUNCT
eurjchem-1774	179	15	o)2	o)2	PROPN
eurjchem-1774	179	16	]	]	PUNCT
eurjchem-1774	179	17	crystallized	crystallize	VERB
eurjchem-1774	179	18	in	in	ADP
eurjchem-1774	179	19	an	an	DET
eurjchem-1774	179	20	orthorombic	orthorombic	ADJ
eurjchem-1774	179	21	space	space	NOUN
eurjchem-1774	179	22	group	group	NOUN
eurjchem-1774	179	23	fdd2	fdd2	NOUN
eurjchem-1774	179	24	with	with	ADP
eurjchem-1774	179	25	half	half	ADJ
eurjchem-1774	179	26	molecules	molecule	NOUN
eurjchem-1774	179	27	per	per	ADP
eurjchem-1774	179	28	unit	unit	NOUN
eurjchem-1774	179	29	cell	cell	NOUN
eurjchem-1774	179	30	and	and	CCONJ
eurjchem-1774	179	31	in	in	ADP
eurjchem-1774	179	32	a	a	DET
eurjchem-1774	179	33	triclinic	triclinic	ADJ
eurjchem-1774	179	34	space	space	NOUN
eurjchem-1774	179	35	group	group	NOUN
eurjchem-1774	179	36	p1	p1	NOUN
eurjchem-1774	179	37	with	with	ADP
eurjchem-1774	179	38	four	four	NUM
eurjchem-1774	179	39	molecules	molecule	NOUN
eurjchem-1774	179	40	per	per	ADP
eurjchem-1774	179	41	unit	unit	NOUN
eurjchem-1774	179	42	cell	cell	NOUN
eurjchem-1774	179	43	,	,	PUNCT
eurjchem-1774	179	44	respectively	respectively	ADV
eurjchem-1774	179	45	.	.	PUNCT
eurjchem-1774	180	1	the	the	DET
eurjchem-1774	180	2	supramolecular	supramolecular	ADJ
eurjchem-1774	180	3	structure	structure	NOUN
eurjchem-1774	180	4	of	of	ADP
eurjchem-1774	180	5	studied	study	VERB
eurjchem-1774	180	6	compounds	compound	NOUN
eurjchem-1774	180	7	were	be	AUX
eurjchem-1774	180	8	further	far	ADV
eurjchem-1774	180	9	examined	examine	VERB
eurjchem-1774	180	10	by	by	ADP
eurjchem-1774	180	11	non	non	ADJ
eurjchem-1774	180	12	-	-	ADJ
eurjchem-1774	180	13	covalent	covalent	ADJ
eurjchem-1774	180	14	interacttion	interacttion	NOUN
eurjchem-1774	180	15	studies	study	NOUN
eurjchem-1774	180	16	.	.	PUNCT
eurjchem-1774	181	1	the	the	DET
eurjchem-1774	181	2	results	result	NOUN
eurjchem-1774	181	3	of	of	ADP
eurjchem-1774	181	4	non	non	ADJ
eurjchem-1774	181	5	-	-	ADJ
eurjchem-1774	181	6	covalent	covalent	ADJ
eurjchem-1774	181	7	interaction	interaction	NOUN
eurjchem-1774	181	8	studies	study	NOUN
eurjchem-1774	181	9	revealed	reveal	VERB
eurjchem-1774	181	10	that	that	SCONJ
eurjchem-1774	181	11	both	both	DET
eurjchem-1774	181	12	complexes	complex	NOUN
eurjchem-1774	181	13	lack	lack	VERB
eurjchem-1774	181	14	strong	strong	ADJ
eurjchem-1774	181	15	hydrogen	hydrogen	NOUN
eurjchem-1774	181	16	bonds	bond	NOUN
eurjchem-1774	181	17	between	between	ADP
eurjchem-1774	181	18	classical	classical	ADJ
eurjchem-1774	181	19	and	and	CCONJ
eurjchem-1774	181	20	non	non	ADJ
eurjchem-1774	181	21	-	-	ADJ
eurjchem-1774	181	22	classical	classical	ADJ
eurjchem-1774	181	23	molecules	molecule	NOUN
eurjchem-1774	181	24	.	.	PUNCT
eurjchem-1774	182	1	however	however	ADV
eurjchem-1774	182	2	,	,	PUNCT
eurjchem-1774	182	3	the	the	DET
eurjchem-1774	182	4	supramolecular	supramolecular	ADJ
eurjchem-1774	182	5	aggregation	aggregation	NOUN
eurjchem-1774	182	6	of	of	ADP
eurjchem-1774	182	7	the	the	DET
eurjchem-1774	182	8	complexes	complex	NOUN
eurjchem-1774	182	9	is	be	AUX
eurjchem-1774	182	10	stabilized	stabilize	VERB
eurjchem-1774	182	11	by	by	ADP
eurjchem-1774	182	12	van	van	PROPN
eurjchem-1774	182	13	der	der	NOUN
eurjchem-1774	182	14	waals	waal	NOUN
eurjchem-1774	182	15	forces	force	NOUN
eurjchem-1774	182	16	as	as	ADV
eurjchem-1774	182	17	well	well	ADV
eurjchem-1774	182	18	as	as	ADP
eurjchem-1774	182	19	stacking	stack	VERB
eurjchem-1774	182	20	interactions	interaction	NOUN
eurjchem-1774	182	21	such	such	ADJ
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eurjchem-1774	182	25	π⋅⋅⋅π	π⋅⋅⋅π	PROPN
eurjchem-1774	182	26	.	.	PUNCT
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eurjchem-1774	183	3	work	work	NOUN
eurjchem-1774	183	4	was	be	AUX
eurjchem-1774	183	5	supported	support	VERB
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eurjchem-1774	183	7	the	the	DET
eurjchem-1774	183	8	mersin	mersin	PROPN
eurjchem-1774	183	9	university	university	PROPN
eurjchem-1774	183	10	research	research	NOUN
eurjchem-1774	183	11	fund	fund	NOUN
eurjchem-1774	184	1	[	[	X
eurjchem-1774	184	2	project	project	NOUN
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eurjchem-1774	184	6	-	-	PUNCT
eurjchem-1774	184	7	ap4	ap4	PROPN
eurjchem-1774	184	8	-	-	PUNCT
eurjchem-1774	184	9	1426	1426	NUM
eurjchem-1774	184	10	]	]	PUNCT
eurjchem-1774	184	11	.	.	PUNCT
eurjchem-1774	185	1	this	this	DET
eurjchem-1774	185	2	academic	academic	ADJ
eurjchem-1774	185	3	work	work	NOUN
eurjchem-1774	185	4	was	be	AUX
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eurjchem-1774	185	8	by	by	ADP
eurjchem-1774	185	9	the	the	DET
eurjchem-1774	185	10	mersin	mersin	PROPN
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eurjchem-1774	185	19	.	.	PUNCT
eurjchem-1774	186	1	supporting	support	VERB
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eurjchem-1774	186	4	and	and	CCONJ
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eurjchem-1774	186	7	the	the	DET
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eurjchem-1774	186	13	cis-[pt(l1	cis-[pt(l1	PROPN
eurjchem-1774	186	14	-	-	PUNCT
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eurjchem-1774	186	20	cis[pt(l2	cis[pt(l2	PROPN
eurjchem-1774	186	21	-	-	PUNCT
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eurjchem-1774	186	24	o)2	o)2	PROPN
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eurjchem-1774	186	28	.	.	PUNCT
eurjchem-1774	187	1	these	these	DET
eurjchem-1774	187	2	data	datum	NOUN
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eurjchem-1774	187	5	obtained	obtain	VERB
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eurjchem-1774	187	14	emailing	email	VERB
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eurjchem-1774	187	17	or	or	CCONJ
eurjchem-1774	187	18	by	by	ADP
eurjchem-1774	187	19	contacting	contact	VERB
eurjchem-1774	187	20	the	the	DET
eurjchem-1774	187	21	cambridge	cambridge	PROPN
eurjchem-1774	187	22	crystallographic	crystallographic	PROPN
eurjchem-1774	187	23	data	data	PROPN
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eurjchem-1774	187	25	,	,	PUNCT
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eurjchem-1774	187	28	road	road	NOUN
eurjchem-1774	187	29	,	,	PUNCT
eurjchem-1774	187	30	cambridge	cambridge	PROPN
eurjchem-1774	187	31	cb2	cb2	PROPN
eurjchem-1774	187	32	1ez	1ez	PROPN
eurjchem-1774	187	33	,	,	PUNCT
eurjchem-1774	187	34	uk	uk	PROPN
eurjchem-1774	187	35	;	;	PUNCT
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eurjchem-1774	187	37	:	:	PUNCT
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eurjchem-1774	187	39	-	-	PUNCT
eurjchem-1774	187	40	336033	336033	NUM
eurjchem-1774	187	41	.	.	PUNCT
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eurjchem-1774	188	17	.	.	PUNCT
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eurjchem-1774	189	11	.	.	PUNCT
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eurjchem-1774	190	3	:	:	PUNCT
eurjchem-1774	191	1	all	all	DET
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eurjchem-1774	192	3	:	:	PUNCT
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eurjchem-1774	194	16	1	1	NUM
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eurjchem-1774	195	7	-	-	PUNCT
eurjchem-1774	195	8	ud	ud	PROPN
eurjchem-1774	195	9	-	-	PUNCT
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eurjchem-1774	195	11	,	,	PUNCT
eurjchem-1774	195	12	a.	a.	NOUN
eurjchem-1774	195	13	;	;	PUNCT
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eurjchem-1774	195	15	,	,	PUNCT
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eurjchem-1774	195	17	;	;	PUNCT
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eurjchem-1774	195	20	m.	m.	NOUN
eurjchem-1774	195	21	;	;	PUNCT
eurjchem-1774	195	22	de	de	X
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eurjchem-1774	195	24	,	,	PUNCT
eurjchem-1774	195	25	d.	d.	PROPN
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eurjchem-1774	197	2	,	,	PUNCT
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eurjchem-1774	197	6	-	-	SYM
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eurjchem-1774	198	4	.	.	PUNCT
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eurjchem-1774	199	12	k.	k.	PROPN
eurjchem-1774	199	13	;	;	PUNCT
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eurjchem-1774	199	21	;	;	PUNCT
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eurjchem-1774	199	25	;	;	PUNCT
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eurjchem-1774	238	2	-	-	PUNCT
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eurjchem-1774	272	8	;	;	PUNCT
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eurjchem-1774	274	3	]	]	PUNCT
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eurjchem-1774	279	2	,	,	PUNCT
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eurjchem-1774	279	4	;	;	PUNCT
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eurjchem-1774	284	3	,	,	PUNCT
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eurjchem-1774	284	5	,	,	PUNCT
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eurjchem-1774	285	3	]	]	PUNCT
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eurjchem-1774	286	5	;	;	PUNCT
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eurjchem-1774	302	2	.	.	PUNCT
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eurjchem-1774	303	2	,	,	PUNCT
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eurjchem-1774	303	6	-	-	SYM
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eurjchem-1774	304	4	.	.	PUNCT
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eurjchem-1774	308	8	;	;	PUNCT
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eurjchem-1774	357	8	;	;	PUNCT
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eurjchem-1774	359	3	]	]	PUNCT
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eurjchem-1774	363	2	,	,	PUNCT
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eurjchem-1774	371	5	,	,	PUNCT
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eurjchem-1774	372	4	.	.	PUNCT
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eurjchem-1774	373	4	.	.	PUNCT
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eurjchem-1774	375	4	;	;	PUNCT
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eurjchem-1774	387	13	keskin	keskin	PROPN
eurjchem-1774	387	14	,	,	PUNCT
eurjchem-1774	387	15	e.	e.	PROPN
eurjchem-1774	387	16	;	;	PUNCT
eurjchem-1774	387	17	arslan	arslan	PROPN
eurjchem-1774	387	18	,	,	PUNCT
eurjchem-1774	387	19	b.	b.	PROPN
eurjchem-1774	387	20	;	;	PUNCT
eurjchem-1774	387	21	arslan	arslan	PROPN
eurjchem-1774	387	22	,	,	PUNCT
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eurjchem-1774	387	24	j.	j.	PROPN
eurjchem-1774	387	25	mol	mol	PROPN
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eurjchem-1774	387	28	.	.	PUNCT
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eurjchem-1774	388	2	,	,	PUNCT
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eurjchem-1774	388	4	,	,	PUNCT
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eurjchem-1774	388	6	-	-	SYM
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eurjchem-1774	388	8	.	.	PUNCT
eurjchem-1774	389	1	[	[	X
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eurjchem-1774	389	4	.	.	PUNCT
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eurjchem-1774	390	4	;	;	PUNCT
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eurjchem-1774	390	10	,	,	PUNCT
eurjchem-1774	390	11	s.	s.	PROPN
eurjchem-1774	390	12	;	;	PUNCT
eurjchem-1774	390	13	arslan	arslan	PROPN
eurjchem-1774	390	14	,	,	PUNCT
eurjchem-1774	390	15	h.	h.	PROPN
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eurjchem-1774	390	17	.	.	PUNCT
eurjchem-1774	391	1	j.	j.	PROPN
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eurjchem-1774	391	3	.	.	PUNCT
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eurjchem-1774	392	2	,	,	PUNCT
eurjchem-1774	392	3	8(4	8(4	NUM
eurjchem-1774	392	4	)	)	PUNCT
eurjchem-1774	392	5	,	,	PUNCT
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eurjchem-1774	392	7	-	-	SYM
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eurjchem-1774	392	9	.	.	PUNCT
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eurjchem-1774	393	2	©	©	PROPN
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eurjchem-1774	393	6	.	.	PUNCT
eurjchem-1774	394	1	this	this	DET
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eurjchem-1774	394	10	house	house	PROPN
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eurjchem-1774	394	12	,	,	PUNCT
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eurjchem-1774	394	14	,	,	PUNCT
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eurjchem-1774	394	16	,	,	PUNCT
eurjchem-1774	394	17	usa	usa	PROPN
eurjchem-1774	394	18	.	.	PUNCT
eurjchem-1774	395	1	the	the	DET
eurjchem-1774	395	2	full	full	ADJ
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eurjchem-1774	395	4	of	of	ADP
eurjchem-1774	395	5	this	this	DET
eurjchem-1774	395	6	license	license	NOUN
eurjchem-1774	395	7	are	be	AUX
eurjchem-1774	395	8	available	available	ADJ
eurjchem-1774	395	9	at	at	ADP
eurjchem-1774	395	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1774	395	11	and	and	CCONJ
eurjchem-1774	395	12	incorporate	incorporate	VERB
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eurjchem-1774	395	14	creative	creative	ADJ
eurjchem-1774	395	15	commons	common	NOUN
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eurjchem-1774	395	17	-	-	PUNCT
eurjchem-1774	395	18	non	non	ADJ
eurjchem-1774	395	19	commercial	commercial	NOUN
eurjchem-1774	395	20	(	(	PUNCT
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eurjchem-1774	395	22	by	by	ADP
eurjchem-1774	395	23	nc	nc	PROPN
eurjchem-1774	395	24	)	)	PUNCT
eurjchem-1774	395	25	(	(	PUNCT
eurjchem-1774	395	26	international	international	ADJ
eurjchem-1774	395	27	,	,	PUNCT
eurjchem-1774	395	28	v4.0	v4.0	NOUN
eurjchem-1774	395	29	)	)	PUNCT
eurjchem-1774	395	30	license	license	NOUN
eurjchem-1774	395	31	(	(	PUNCT
eurjchem-1774	395	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-1774	395	33	)	)	PUNCT
eurjchem-1774	395	34	.	.	PUNCT
eurjchem-1774	396	1	by	by	ADP
eurjchem-1774	396	2	accessing	access	VERB
eurjchem-1774	396	3	the	the	DET
eurjchem-1774	396	4	work	work	NOUN
eurjchem-1774	396	5	,	,	PUNCT
eurjchem-1774	396	6	you	you	PRON
eurjchem-1774	396	7	hereby	hereby	ADV
eurjchem-1774	396	8	accept	accept	VERB
eurjchem-1774	396	9	the	the	DET
eurjchem-1774	396	10	terms	term	NOUN
eurjchem-1774	396	11	.	.	PUNCT
eurjchem-1774	397	1	this	this	PRON
eurjchem-1774	397	2	is	be	AUX
eurjchem-1774	397	3	an	an	DET
eurjchem-1774	397	4	open	open	ADJ
eurjchem-1774	397	5	access	access	NOUN
eurjchem-1774	397	6	article	article	NOUN
eurjchem-1774	397	7	distributed	distribute	VERB
eurjchem-1774	397	8	under	under	ADP
eurjchem-1774	397	9	the	the	DET
eurjchem-1774	397	10	terms	term	NOUN
eurjchem-1774	397	11	and	and	CCONJ
eurjchem-1774	397	12	conditions	condition	NOUN
eurjchem-1774	397	13	of	of	ADP
eurjchem-1774	397	14	the	the	DET
eurjchem-1774	397	15	cc	cc	PROPN
eurjchem-1774	397	16	by	by	ADP
eurjchem-1774	397	17	nc	nc	PROPN
eurjchem-1774	397	18	license	license	PROPN
eurjchem-1774	397	19	,	,	PUNCT
eurjchem-1774	397	20	which	which	PRON
eurjchem-1774	397	21	permits	permit	VERB
eurjchem-1774	397	22	unrestricted	unrestricted	ADJ
eurjchem-1774	397	23	non	non	ADJ
eurjchem-1774	397	24	-	-	ADJ
eurjchem-1774	397	25	commercial	commercial	ADJ
eurjchem-1774	397	26	use	use	NOUN
eurjchem-1774	397	27	,	,	PUNCT
eurjchem-1774	397	28	distribution	distribution	NOUN
eurjchem-1774	397	29	,	,	PUNCT
eurjchem-1774	397	30	and	and	CCONJ
eurjchem-1774	397	31	reproduction	reproduction	NOUN
eurjchem-1774	397	32	in	in	ADP
eurjchem-1774	397	33	any	any	DET
eurjchem-1774	397	34	medium	medium	NOUN
eurjchem-1774	397	35	,	,	PUNCT
eurjchem-1774	397	36	provided	provide	VERB
eurjchem-1774	397	37	the	the	DET
eurjchem-1774	397	38	original	original	ADJ
eurjchem-1774	397	39	work	work	NOUN
eurjchem-1774	397	40	is	be	AUX
eurjchem-1774	397	41	properly	properly	ADV
eurjchem-1774	397	42	cited	cite	VERB
eurjchem-1774	397	43	without	without	ADP
eurjchem-1774	397	44	any	any	DET
eurjchem-1774	397	45	further	further	ADJ
eurjchem-1774	397	46	permission	permission	NOUN
eurjchem-1774	397	47	from	from	ADP
eurjchem-1774	397	48	atlanta	atlanta	PROPN
eurjchem-1774	397	49	publishing	publishing	PROPN
eurjchem-1774	397	50	house	house	PROPN
eurjchem-1774	397	51	llc	llc	PROPN
eurjchem-1774	397	52	(	(	PUNCT
eurjchem-1774	397	53	european	european	PROPN
eurjchem-1774	397	54	journal	journal	PROPN
eurjchem-1774	397	55	of	of	ADP
eurjchem-1774	397	56	chemistry	chemistry	NOUN
eurjchem-1774	397	57	)	)	PUNCT
eurjchem-1774	397	58	.	.	PUNCT
eurjchem-1774	398	1	no	no	DET
eurjchem-1774	398	2	use	use	NOUN
eurjchem-1774	398	3	,	,	PUNCT
eurjchem-1774	398	4	distribution	distribution	NOUN
eurjchem-1774	398	5	or	or	CCONJ
eurjchem-1774	398	6	reproduction	reproduction	NOUN
eurjchem-1774	398	7	is	be	AUX
eurjchem-1774	398	8	permitted	permit	VERB
eurjchem-1774	398	9	which	which	PRON
eurjchem-1774	398	10	does	do	AUX
eurjchem-1774	398	11	not	not	PART
eurjchem-1774	398	12	comply	comply	VERB
eurjchem-1774	398	13	with	with	ADP
eurjchem-1774	398	14	these	these	DET
eurjchem-1774	398	15	terms	term	NOUN
eurjchem-1774	398	16	.	.	PUNCT
eurjchem-1774	399	1	permissions	permission	NOUN
eurjchem-1774	399	2	for	for	ADP
eurjchem-1774	399	3	commercial	commercial	ADJ
eurjchem-1774	399	4	use	use	NOUN
eurjchem-1774	399	5	of	of	ADP
eurjchem-1774	399	6	this	this	DET
eurjchem-1774	399	7	work	work	NOUN
eurjchem-1774	399	8	beyond	beyond	ADP
eurjchem-1774	399	9	the	the	DET
eurjchem-1774	399	10	scope	scope	NOUN
eurjchem-1774	399	11	of	of	ADP
eurjchem-1774	399	12	the	the	DET
eurjchem-1774	399	13	license	license	NOUN
eurjchem-1774	399	14	(	(	PUNCT
eurjchem-1774	399	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1774	399	16	)	)	PUNCT
eurjchem-1774	399	17	are	be	AUX
eurjchem-1774	399	18	administered	administer	VERB
eurjchem-1774	399	19	by	by	ADP
eurjchem-1774	399	20	atlanta	atlanta	PROPN
eurjchem-1774	399	21	publishing	publishing	PROPN
eurjchem-1774	399	22	house	house	PROPN
eurjchem-1774	399	23	llc	llc	PROPN
eurjchem-1774	399	24	(	(	PUNCT
eurjchem-1774	399	25	european	european	PROPN
eurjchem-1774	399	26	journal	journal	PROPN
eurjchem-1774	399	27	of	of	ADP
eurjchem-1774	399	28	chemistry	chemistry	NOUN
eurjchem-1774	399	29	)	)	PUNCT
eurjchem-1774	399	30	.	.	PUNCT
eurjchem-1774	400	1	2018	2018	NUM
eurjchem-1774	400	2	–	–	PUNCT
eurjchem-1774	400	3	european	european	ADJ
eurjchem-1774	400	4	journal	journal	NOUN
eurjchem-1774	400	5	of	of	ADP
eurjchem-1774	400	6	chemistry	chemistry	NOUN
eurjchem-1774	400	7	–	–	PUNCT
eurjchem-1774	400	8	cc	cc	NOUN
eurjchem-1774	400	9	by	by	ADP
eurjchem-1774	400	10	nc	nc	PROPN
eurjchem-1774	400	11	–	–	PUNCT
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eurjchem-1774	400	17	-	-	PUNCT
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eurjchem-1774	400	20	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-1774	400	21	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1774	400	22	1	1	NUM
eurjchem-1774	400	23	.	.	PUNCT
eurjchem-1774	400	24	introduction	introduction	NOUN
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eurjchem-1774	400	26	.	.	PUNCT
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eurjchem-1774	400	28	2.1	2.1	NUM
eurjchem-1774	400	29	.	.	PUNCT
eurjchem-1774	401	1	instrumentation	instrumentation	NOUN
eurjchem-1774	401	2	2.2	2.2	NUM
eurjchem-1774	401	3	.	.	PUNCT
eurjchem-1774	401	4	reagents	reagent	NOUN
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eurjchem-1774	401	6	.	.	PUNCT
eurjchem-1774	402	1	synthesis	synthesis	NOUN
eurjchem-1774	402	2	and	and	CCONJ
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eurjchem-1774	402	4	2.3.1	2.3.1	NUM
eurjchem-1774	402	5	.	.	PUNCT
eurjchem-1774	402	6	general	general	ADJ
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eurjchem-1774	402	8	for	for	ADP
eurjchem-1774	402	9	the	the	DET
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eurjchem-1774	402	13	(	(	PUNCT
eurjchem-1774	402	14	hl1,2	hl1,2	ADJ
eurjchem-1774	402	15	)	)	PUNCT
eurjchem-1774	402	16	2.3.2	2.3.2	NUM
eurjchem-1774	402	17	.	.	PUNCT
eurjchem-1774	402	18	general	general	ADJ
eurjchem-1774	402	19	procedure	procedure	NOUN
eurjchem-1774	402	20	for	for	ADP
eurjchem-1774	402	21	the	the	DET
eurjchem-1774	402	22	synthesis	synthesis	NOUN
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eurjchem-1774	402	24	platinum	platinum	NOUN
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eurjchem-1774	402	26	3	3	NUM
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eurjchem-1774	402	29	and	and	CCONJ
eurjchem-1774	402	30	discussion	discussion	NOUN
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eurjchem-1774	402	32	.	.	PUNCT
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eurjchem-1774	403	2	and	and	CCONJ
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eurjchem-1774	403	4	-	-	PUNCT
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eurjchem-1774	403	9	.	.	PUNCT
eurjchem-1774	404	1	crystal	crystal	NOUN
eurjchem-1774	404	2	structure	structure	NOUN
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eurjchem-1774	404	5	.	.	PUNCT
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eurjchem-1774	405	11	:	:	PUNCT
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eurjchem-1774	405	13	:	:	PUNCT
eurjchem-1774	405	14	printfield12	printfield12	PROPN
eurjchem-1774	405	15	:	:	PUNCT
eurjchem-1774	405	16	printfield13	printfield13	VERB
eurjchem-1774	405	17	:	:	PUNCT
eurjchem-1774	405	18	printfield14	printfield14	NOUN
eurjchem-1774	405	19	:	:	PUNCT
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eurjchem-1774	405	21	:	:	PUNCT
eurjchem-1774	405	22	printfield16	printfield16	ADJ
eurjchem-1774	405	23	:	:	PUNCT
eurjchem-1774	405	24	printfield17	printfield17	NOUN
eurjchem-1774	405	25	:	:	PUNCT
eurjchem-1774	405	26	printfield18	printfield18	NOUN
eurjchem-1774	405	27	:	:	PUNCT
eurjchem-1774	405	28	printfield20	printfield20	PROPN
eurjchem-1774	405	29	:	:	PUNCT
eurjchem-1774	406	1	printfield21	printfield21	ADJ
eurjchem-1774	406	2	:	:	PUNCT
eurjchem-1774	406	3	printfield22	printfield22	NOUN
eurjchem-1774	406	4	:	:	PUNCT
eurjchem-1774	406	5	printfield23	printfield23	NOUN
eurjchem-1774	406	6	:	:	PUNCT
eurjchem-1774	406	7	printfield24	printfield24	NOUN
eurjchem-1774	406	8	:	:	PUNCT
eurjchem-1774	406	9	printfield25	printfield25	NOUN
eurjchem-1774	406	10	:	:	PUNCT
eurjchem-1774	406	11	printfield26	printfield26	ADJ
eurjchem-1774	406	12	:	:	PUNCT
eurjchem-1774	406	13	printfield27	printfield27	NOUN
eurjchem-1774	406	14	:	:	PUNCT
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eurjchem-1774	406	16	:	:	PUNCT