id	sid	tid	token	lemma	pos
eurjchem-1865	1	1	synthesis	synthesis	NOUN
eurjchem-1865	1	2	and	and	CCONJ
eurjchem-1865	1	3	crystallographic	crystallographic	ADJ
eurjchem-1865	1	4	structure	structure	NOUN
eurjchem-1865	1	5	of	of	ADP
eurjchem-1865	1	6	nickel(0	nickel(0	PROPN
eurjchem-1865	1	7	)	)	PUNCT
eurjchem-1865	1	8	carbonyl	carbonyl	NOUN
eurjchem-1865	1	9	complex	complex	NOUN
eurjchem-1865	1	10	with	with	ADP
eurjchem-1865	1	11	bitianp	bitianp	NOUN
eurjchem-1865	1	12	,	,	PUNCT
eurjchem-1865	1	13	an	an	DET
eurjchem-1865	1	14	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	1	15	diphosphine	diphosphine	ADJ
eurjchem-1865	1	16	european	european	PROPN
eurjchem-1865	1	17	journal	journal	PROPN
eurjchem-1865	1	18	of	of	ADP
eurjchem-1865	1	19	chemistry	chemistry	NOUN
eurjchem-1865	1	20	10	10	NUM
eurjchem-1865	1	21	(	(	PUNCT
eurjchem-1865	1	22	2	2	NUM
eurjchem-1865	1	23	)	)	PUNCT
eurjchem-1865	1	24	(	(	PUNCT
eurjchem-1865	1	25	2019	2019	NUM
eurjchem-1865	1	26	)	)	PUNCT
eurjchem-1865	1	27	171	171	NUM
eurjchem-1865	1	28	-	-	SYM
eurjchem-1865	1	29	174	174	NUM
eurjchem-1865	1	30	european	european	ADJ
eurjchem-1865	1	31	journal	journal	PROPN
eurjchem-1865	1	32	of	of	ADP
eurjchem-1865	1	33	chemistry	chemistry	NOUN
eurjchem-1865	1	34	view	view	NOUN
eurjchem-1865	1	35	journal	journal	PROPN
eurjchem-1865	1	36	online	online	PROPN
eurjchem-1865	1	37	view	view	NOUN
eurjchem-1865	1	38	article	article	NOUN
eurjchem-1865	1	39	online	online	ADJ
eurjchem-1865	1	40	synthesis	synthesis	NOUN
eurjchem-1865	1	41	and	and	CCONJ
eurjchem-1865	1	42	crystallographic	crystallographic	ADJ
eurjchem-1865	1	43	structure	structure	NOUN
eurjchem-1865	1	44	of	of	ADP
eurjchem-1865	1	45	nickel(0	nickel(0	PROPN
eurjchem-1865	1	46	)	)	PUNCT
eurjchem-1865	1	47	carbonyl	carbonyl	NOUN
eurjchem-1865	1	48	complex	complex	NOUN
eurjchem-1865	1	49	with	with	ADP
eurjchem-1865	1	50	bitianp	bitianp	NOUN
eurjchem-1865	1	51	,	,	PUNCT
eurjchem-1865	1	52	an	an	DET
eurjchem-1865	1	53	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	1	54	diphosphine	diphosphine	PROPN
eurjchem-1865	1	55	marco	marco	PROPN
eurjchem-1865	1	56	fusè	fusè	PROPN
eurjchem-1865	1	57	1	1	NUM
eurjchem-1865	1	58	,	,	PUNCT
eurjchem-1865	1	59	giorgio	giorgio	PROPN
eurjchem-1865	1	60	facchetti	facchetti	ADJ
eurjchem-1865	1	61	2	2	NUM
eurjchem-1865	1	62	,	,	PUNCT
eurjchem-1865	1	63	isabella	isabella	NOUN
eurjchem-1865	1	64	rimoldi	rimoldi	PROPN
eurjchem-1865	1	65	2	2	NUM
eurjchem-1865	1	66	and	and	CCONJ
eurjchem-1865	1	67	carlo	carlo	PROPN
eurjchem-1865	1	68	castellano	castellano	PROPN
eurjchem-1865	1	69	3	3	NUM
eurjchem-1865	1	70	,	,	PUNCT
eurjchem-1865	1	71	*	*	PROPN
eurjchem-1865	1	72	1	1	NUM
eurjchem-1865	1	73	scuola	scuola	NOUN
eurjchem-1865	1	74	normale	normale	PROPN
eurjchem-1865	1	75	superiore	superiore	PROPN
eurjchem-1865	1	76	,	,	PUNCT
eurjchem-1865	1	77	piazza	piazza	NOUN
eurjchem-1865	1	78	dei	dei	NOUN
eurjchem-1865	1	79	cavalieri	cavalieri	PROPN
eurjchem-1865	1	80	7	7	NUM
eurjchem-1865	1	81	,	,	PUNCT
eurjchem-1865	1	82	56126	56126	NUM
eurjchem-1865	1	83	pisa	pisa	NOUN
eurjchem-1865	1	84	,	,	PUNCT
eurjchem-1865	1	85	italia	italia	PROPN
eurjchem-1865	1	86	marco.fuse@sns.it	marco.fuse@sns.it	PROPN
eurjchem-1865	1	87	(	(	PUNCT
eurjchem-1865	1	88	m.f	m.f	PROPN
eurjchem-1865	1	89	.	.	PUNCT
eurjchem-1865	1	90	)	)	PUNCT
eurjchem-1865	1	91	2	2	NUM
eurjchem-1865	1	92	dipartimento	dipartimento	VERB
eurjchem-1865	1	93	di	di	X
eurjchem-1865	1	94	scienze	scienze	PROPN
eurjchem-1865	1	95	farmaceutiche	farmaceutiche	PROPN
eurjchem-1865	1	96	,	,	PUNCT
eurjchem-1865	1	97	università	università	PROPN
eurjchem-1865	1	98	degli	degli	PROPN
eurjchem-1865	1	99	studi	studi	PROPN
eurjchem-1865	1	100	di	di	X
eurjchem-1865	1	101	milano	milano	PROPN
eurjchem-1865	1	102	,	,	PUNCT
eurjchem-1865	1	103	via	via	ADP
eurjchem-1865	1	104	golgi	golgi	PROPN
eurjchem-1865	1	105	19	19	NUM
eurjchem-1865	1	106	,	,	PUNCT
eurjchem-1865	1	107	20133	20133	NUM
eurjchem-1865	1	108	milano	milano	PROPN
eurjchem-1865	1	109	,	,	PUNCT
eurjchem-1865	1	110	italia	italia	PROPN
eurjchem-1865	1	111	giorgio.facchetti@unimi.it	giorgio.facchetti@unimi.it	PROPN
eurjchem-1865	1	112	(	(	PUNCT
eurjchem-1865	1	113	g.f	g.f	NOUN
eurjchem-1865	1	114	.	.	PROPN
eurjchem-1865	1	115	)	)	PUNCT
eurjchem-1865	1	116	,	,	PUNCT
eurjchem-1865	1	117	isabella.rimoldi@unimi.it	isabella.rimoldi@unimi.it	NOUN
eurjchem-1865	1	118	(	(	PUNCT
eurjchem-1865	1	119	i.r	i.r	PROPN
eurjchem-1865	1	120	.	.	PROPN
eurjchem-1865	1	121	)	)	PUNCT
eurjchem-1865	1	122	3	3	NUM
eurjchem-1865	1	123	dipartimento	dipartimento	VERB
eurjchem-1865	1	124	di	di	PROPN
eurjchem-1865	1	125	chimica	chimica	PROPN
eurjchem-1865	1	126	,	,	PUNCT
eurjchem-1865	1	127	università	università	PROPN
eurjchem-1865	1	128	degli	degli	PROPN
eurjchem-1865	1	129	studi	studi	PROPN
eurjchem-1865	1	130	di	di	X
eurjchem-1865	1	131	milano	milano	PROPN
eurjchem-1865	1	132	,	,	PUNCT
eurjchem-1865	1	133	via	via	ADP
eurjchem-1865	1	134	golgi	golgi	PROPN
eurjchem-1865	1	135	19	19	NUM
eurjchem-1865	1	136	,	,	PUNCT
eurjchem-1865	1	137	20133	20133	NUM
eurjchem-1865	1	138	milano	milano	PROPN
eurjchem-1865	1	139	,	,	PUNCT
eurjchem-1865	1	140	italia	italia	PROPN
eurjchem-1865	1	141	carlo.castellano@unimi.it	carlo.castellano@unimi.it	PROPN
eurjchem-1865	1	142	(	(	PUNCT
eurjchem-1865	1	143	c.c	c.c	PROPN
eurjchem-1865	1	144	.	.	PROPN
eurjchem-1865	1	145	)	)	PUNCT
eurjchem-1865	2	1	*	*	PUNCT
eurjchem-1865	2	2	corresponding	correspond	VERB
eurjchem-1865	2	3	author	author	NOUN
eurjchem-1865	2	4	at	at	ADP
eurjchem-1865	2	5	:	:	PUNCT
eurjchem-1865	2	6	dipartimento	dipartimento	VERB
eurjchem-1865	2	7	di	di	PROPN
eurjchem-1865	2	8	chimica	chimica	PROPN
eurjchem-1865	2	9	,	,	PUNCT
eurjchem-1865	2	10	università	università	PROPN
eurjchem-1865	2	11	degli	degli	PROPN
eurjchem-1865	2	12	studi	studi	PROPN
eurjchem-1865	2	13	di	di	X
eurjchem-1865	2	14	milano	milano	PROPN
eurjchem-1865	2	15	,	,	PUNCT
eurjchem-1865	2	16	via	via	ADP
eurjchem-1865	2	17	golgi	golgi	PROPN
eurjchem-1865	2	18	19	19	NUM
eurjchem-1865	2	19	,	,	PUNCT
eurjchem-1865	2	20	20133	20133	NUM
eurjchem-1865	2	21	milano	milano	PROPN
eurjchem-1865	2	22	,	,	PUNCT
eurjchem-1865	2	23	italia	italia	PROPN
eurjchem-1865	2	24	.	.	PUNCT
eurjchem-1865	3	1	tel	tel	ADP
eurjchem-1865	3	2	:	:	PUNCT
eurjchem-1865	3	3	+39.02.50314449	+39.02.50314449	NUM
eurjchem-1865	3	4	fax	fax	NOUN
eurjchem-1865	3	5	:	:	PUNCT
eurjchem-1865	3	6	+39.02.50314454	+39.02.50314454	NUM
eurjchem-1865	3	7	e	e	NOUN
eurjchem-1865	3	8	-	-	NOUN
eurjchem-1865	3	9	mail	mail	NOUN
eurjchem-1865	3	10	:	:	PUNCT
eurjchem-1865	3	11	carlo.castellano@unimi.it	carlo.castellano@unimi.it	PROPN
eurjchem-1865	3	12	(	(	PUNCT
eurjchem-1865	3	13	c.	c.	PROPN
eurjchem-1865	3	14	castellano	castellano	PROPN
eurjchem-1865	3	15	)	)	PUNCT
eurjchem-1865	3	16	.	.	PUNCT
eurjchem-1865	4	1	10.5155	10.5155	NUM
eurjchem-1865	4	2	/	/	SYM
eurjchem-1865	4	3	eurjchem.10.2.171	eurjchem.10.2.171	PRON
eurjchem-1865	4	4	-	-	PUNCT
eurjchem-1865	4	5	174.1865	174.1865	NUM
eurjchem-1865	4	6	received	receive	VERB
eurjchem-1865	4	7	:	:	PUNCT
eurjchem-1865	4	8	02	02	NUM
eurjchem-1865	4	9	april	april	PROPN
eurjchem-1865	4	10	2019	2019	NUM
eurjchem-1865	4	11	received	receive	VERB
eurjchem-1865	4	12	in	in	ADP
eurjchem-1865	4	13	revised	revise	VERB
eurjchem-1865	4	14	form	form	NOUN
eurjchem-1865	4	15	:	:	PUNCT
eurjchem-1865	4	16	18	18	NUM
eurjchem-1865	4	17	may	may	AUX
eurjchem-1865	4	18	2019	2019	NUM
eurjchem-1865	4	19	accepted	accept	VERB
eurjchem-1865	4	20	:	:	PUNCT
eurjchem-1865	4	21	19	19	NUM
eurjchem-1865	4	22	may	may	AUX
eurjchem-1865	4	23	2019	2019	NUM
eurjchem-1865	4	24	published	publish	VERB
eurjchem-1865	4	25	online	online	ADV
eurjchem-1865	4	26	:	:	PUNCT
eurjchem-1865	4	27	30	30	NUM
eurjchem-1865	4	28	june	june	PROPN
eurjchem-1865	4	29	2019	2019	NUM
eurjchem-1865	4	30	printed	print	VERB
eurjchem-1865	4	31	:	:	PUNCT
eurjchem-1865	4	32	30	30	NUM
eurjchem-1865	4	33	june	june	PROPN
eurjchem-1865	4	34	2019	2019	NUM
eurjchem-1865	4	35	the	the	DET
eurjchem-1865	4	36	reaction	reaction	NOUN
eurjchem-1865	4	37	between	between	ADP
eurjchem-1865	4	38	an	an	DET
eurjchem-1865	4	39	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	4	40	diphosphine	diphosphine	NOUN
eurjchem-1865	4	41	,	,	PUNCT
eurjchem-1865	4	42	bitianp	bitianp	NOUN
eurjchem-1865	4	43	and	and	CCONJ
eurjchem-1865	4	44	[	[	X
eurjchem-1865	4	45	ni(co)4	ni(co)4	NOUN
eurjchem-1865	4	46	]	]	PUNCT
eurjchem-1865	4	47	was	be	AUX
eurjchem-1865	4	48	achieved	achieve	VERB
eurjchem-1865	4	49	by	by	ADP
eurjchem-1865	4	50	direct	direct	ADJ
eurjchem-1865	4	51	condensation	condensation	NOUN
eurjchem-1865	4	52	in	in	ADP
eurjchem-1865	4	53	ch3cl	ch3cl	NOUN
eurjchem-1865	4	54	to	to	PART
eurjchem-1865	4	55	afford	afford	VERB
eurjchem-1865	4	56	complexes	complex	NOUN
eurjchem-1865	4	57	of	of	ADP
eurjchem-1865	4	58	general	general	ADJ
eurjchem-1865	4	59	formula	formula	NOUN
eurjchem-1865	5	1	[	[	X
eurjchem-1865	5	2	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	5	3	)	)	PUNCT
eurjchem-1865	5	4	]	]	PUNCT
eurjchem-1865	5	5	.	.	PUNCT
eurjchem-1865	6	1	this	this	DET
eurjchem-1865	6	2	compound	compound	NOUN
eurjchem-1865	6	3	was	be	AUX
eurjchem-1865	6	4	characterized	characterize	VERB
eurjchem-1865	6	5	by	by	ADP
eurjchem-1865	6	6	elemental	elemental	ADJ
eurjchem-1865	6	7	analysis	analysis	NOUN
eurjchem-1865	6	8	,	,	PUNCT
eurjchem-1865	6	9	ir	ir	NOUN
eurjchem-1865	6	10	,	,	PUNCT
eurjchem-1865	6	11	1h-	1h-	NUM
eurjchem-1865	6	12	,	,	PUNCT
eurjchem-1865	6	13	13cand	13cand	NUM
eurjchem-1865	6	14	31p	31p	ADJ
eurjchem-1865	6	15	-	-	PUNCT
eurjchem-1865	6	16	nmr	nmr	NOUN
eurjchem-1865	6	17	spectroscopies	spectroscopy	NOUN
eurjchem-1865	6	18	.	.	PUNCT
eurjchem-1865	7	1	the	the	DET
eurjchem-1865	7	2	structure	structure	NOUN
eurjchem-1865	7	3	of	of	ADP
eurjchem-1865	7	4	nickel	nickel	NOUN
eurjchem-1865	7	5	complex	complex	NOUN
eurjchem-1865	7	6	has	have	AUX
eurjchem-1865	7	7	been	be	AUX
eurjchem-1865	7	8	determined	determine	VERB
eurjchem-1865	7	9	by	by	ADP
eurjchem-1865	7	10	x	x	NOUN
eurjchem-1865	7	11	-	-	NOUN
eurjchem-1865	7	12	ray	ray	NOUN
eurjchem-1865	7	13	crystallography	crystallography	NOUN
eurjchem-1865	7	14	.	.	PUNCT
eurjchem-1865	8	1	crystal	crystal	NOUN
eurjchem-1865	8	2	data	datum	NOUN
eurjchem-1865	8	3	for	for	ADP
eurjchem-1865	8	4	c42h28nio2p2s2	c42h28nio2p2s2	NOUN
eurjchem-1865	8	5	(	(	PUNCT
eurjchem-1865	8	6	m	m	PROPN
eurjchem-1865	8	7	=	=	VERB
eurjchem-1865	8	8	749.41	749.41	NUM
eurjchem-1865	8	9	g	g	NOUN
eurjchem-1865	8	10	/	/	SYM
eurjchem-1865	8	11	mol	mol	NOUN
eurjchem-1865	8	12	):	):	PUNCT
eurjchem-1865	8	13	triclinic	triclinic	ADJ
eurjchem-1865	8	14	,	,	PUNCT
eurjchem-1865	8	15	space	space	NOUN
eurjchem-1865	8	16	group	group	NOUN
eurjchem-1865	8	17	p-1	p-1	NOUN
eurjchem-1865	8	18	(	(	PUNCT
eurjchem-1865	8	19	no	no	INTJ
eurjchem-1865	8	20	.	.	NOUN
eurjchem-1865	8	21	2	2	NUM
eurjchem-1865	8	22	)	)	PUNCT
eurjchem-1865	8	23	,	,	PUNCT
eurjchem-1865	8	24	a	a	DET
eurjchem-1865	8	25	=	=	NOUN
eurjchem-1865	8	26	10.539(2	10.539(2	NUM
eurjchem-1865	8	27	)	)	PUNCT
eurjchem-1865	8	28	å	å	PROPN
eurjchem-1865	8	29	,	,	PUNCT
eurjchem-1865	8	30	b	b	X
eurjchem-1865	8	31	=	=	SYM
eurjchem-1865	8	32	11.811(2	11.811(2	PROPN
eurjchem-1865	8	33	)	)	PUNCT
eurjchem-1865	8	34	å	å	NOUN
eurjchem-1865	8	35	,	,	PUNCT
eurjchem-1865	8	36	c	c	NOUN
eurjchem-1865	8	37	=	=	SYM
eurjchem-1865	8	38	15.994(3	15.994(3	NOUN
eurjchem-1865	8	39	)	)	PUNCT
eurjchem-1865	9	1	å	å	NOUN
eurjchem-1865	9	2	,	,	PUNCT
eurjchem-1865	9	3	α	α	NOUN
eurjchem-1865	9	4	=	=	PUNCT
eurjchem-1865	9	5	83.93(3	83.93(3	NUM
eurjchem-1865	9	6	)	)	PUNCT
eurjchem-1865	9	7	°	°	PROPN
eurjchem-1865	9	8	,	,	PUNCT
eurjchem-1865	9	9	β	β	X
eurjchem-1865	9	10	=	=	SYM
eurjchem-1865	9	11	88.18(3	88.18(3	NUM
eurjchem-1865	9	12	)	)	PUNCT
eurjchem-1865	9	13	°	°	PROPN
eurjchem-1865	9	14	,	,	PUNCT
eurjchem-1865	9	15	γ	γ	NOUN
eurjchem-1865	9	16	=	=	SYM
eurjchem-1865	9	17	65.24(3	65.24(3	NOUN
eurjchem-1865	9	18	)	)	PUNCT
eurjchem-1865	9	19	°	°	NOUN
eurjchem-1865	9	20	,	,	PUNCT
eurjchem-1865	9	21	v	v	NOUN
eurjchem-1865	9	22	=	=	SYM
eurjchem-1865	9	23	1797.6(7	1797.6(7	ADJ
eurjchem-1865	9	24	)	)	PUNCT
eurjchem-1865	9	25	å3	å3	PROPN
eurjchem-1865	9	26	,	,	PUNCT
eurjchem-1865	9	27	z	z	NOUN
eurjchem-1865	9	28	=	=	SYM
eurjchem-1865	9	29	2	2	NUM
eurjchem-1865	9	30	,	,	PUNCT
eurjchem-1865	9	31	t	t	NOUN
eurjchem-1865	9	32	=	=	SYM
eurjchem-1865	9	33	294(2	294(2	NUM
eurjchem-1865	9	34	)	)	PUNCT
eurjchem-1865	9	35	k	k	NOUN
eurjchem-1865	9	36	,	,	PUNCT
eurjchem-1865	9	37	μ(mokα	μ(mokα	NOUN
eurjchem-1865	9	38	)	)	PUNCT
eurjchem-1865	9	39	=	=	PUNCT
eurjchem-1865	9	40	0.781	0.781	NUM
eurjchem-1865	9	41	mm-1	mm-1	NOUN
eurjchem-1865	9	42	,	,	PUNCT
eurjchem-1865	9	43	dcalc	dcalc	NOUN
eurjchem-1865	9	44	=	=	PROPN
eurjchem-1865	9	45	1.385	1.385	NUM
eurjchem-1865	9	46	g	g	PROPN
eurjchem-1865	9	47	/	/	SYM
eurjchem-1865	9	48	cm3	cm3	NOUN
eurjchem-1865	9	49	,	,	PUNCT
eurjchem-1865	9	50	22744	22744	NUM
eurjchem-1865	9	51	reflections	reflection	NOUN
eurjchem-1865	9	52	measured	measure	VERB
eurjchem-1865	9	53	(	(	PUNCT
eurjchem-1865	9	54	2.56	2.56	NUM
eurjchem-1865	9	55	°	°	NOUN
eurjchem-1865	9	56	≤	≤	NUM
eurjchem-1865	9	57	2θ	2θ	NUM
eurjchem-1865	9	58	≤	≤	NOUN
eurjchem-1865	9	59	64.726	64.726	NUM
eurjchem-1865	9	60	°	°	NUM
eurjchem-1865	9	61	)	)	PUNCT
eurjchem-1865	9	62	,	,	PUNCT
eurjchem-1865	9	63	11837	11837	NUM
eurjchem-1865	9	64	unique	unique	ADJ
eurjchem-1865	9	65	(	(	PUNCT
eurjchem-1865	9	66	rint	rint	NOUN
eurjchem-1865	9	67	=	=	SYM
eurjchem-1865	9	68	0.0157	0.0157	NUM
eurjchem-1865	9	69	,	,	PUNCT
eurjchem-1865	9	70	rsigma	rsigma	ADJ
eurjchem-1865	9	71	=	=	SYM
eurjchem-1865	9	72	0.0215	0.0215	NUM
eurjchem-1865	9	73	)	)	PUNCT
eurjchem-1865	9	74	which	which	PRON
eurjchem-1865	9	75	were	be	AUX
eurjchem-1865	9	76	used	use	VERB
eurjchem-1865	9	77	in	in	ADP
eurjchem-1865	9	78	all	all	DET
eurjchem-1865	9	79	calculations	calculation	NOUN
eurjchem-1865	9	80	.	.	PUNCT
eurjchem-1865	10	1	the	the	DET
eurjchem-1865	10	2	final	final	ADJ
eurjchem-1865	10	3	r1	r1	NOUN
eurjchem-1865	10	4	was	be	AUX
eurjchem-1865	10	5	0.0360	0.0360	NUM
eurjchem-1865	10	6	(	(	PUNCT
eurjchem-1865	10	7	i	i	X
eurjchem-1865	10	8	>	>	X
eurjchem-1865	10	9	2σ(i	2σ(i	NUM
eurjchem-1865	10	10	)	)	PUNCT
eurjchem-1865	10	11	)	)	PUNCT
eurjchem-1865	11	1	and	and	CCONJ
eurjchem-1865	11	2	wr2	wr2	PROPN
eurjchem-1865	11	3	was	be	AUX
eurjchem-1865	11	4	0.1088	0.1088	NUM
eurjchem-1865	11	5	(	(	PUNCT
eurjchem-1865	11	6	all	all	DET
eurjchem-1865	11	7	data	datum	NOUN
eurjchem-1865	11	8	)	)	PUNCT
eurjchem-1865	11	9	.	.	PUNCT
eurjchem-1865	12	1	the	the	DET
eurjchem-1865	12	2	coordination	coordination	NOUN
eurjchem-1865	12	3	sphere	sphere	NOUN
eurjchem-1865	12	4	of	of	ADP
eurjchem-1865	12	5	the	the	DET
eurjchem-1865	12	6	ni	ni	PROPN
eurjchem-1865	12	7	center	center	NOUN
eurjchem-1865	12	8	is	be	AUX
eurjchem-1865	12	9	best	well	ADV
eurjchem-1865	12	10	described	describe	VERB
eurjchem-1865	12	11	as	as	ADP
eurjchem-1865	12	12	a	a	DET
eurjchem-1865	12	13	tetrahedral	tetrahedral	ADJ
eurjchem-1865	12	14	geometry	geometry	NOUN
eurjchem-1865	12	15	.	.	PUNCT
eurjchem-1865	13	1	carbonyl	carbonyl	NOUN
eurjchem-1865	13	2	sigma	sigma	VERB
eurjchem-1865	13	3	donor	donor	NOUN
eurjchem-1865	13	4	envelope	envelope	NOUN
eurjchem-1865	13	5	ring	ring	NOUN
eurjchem-1865	13	6	nickel	nickel	NOUN
eurjchem-1865	13	7	complex	complex	ADJ
eurjchem-1865	13	8	tetrahedral	tetrahedral	ADJ
eurjchem-1865	13	9	geometry	geometry	NOUN
eurjchem-1865	13	10	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	13	11	diphosphine	diphosphine	NOUN
eurjchem-1865	13	12	cite	cite	VERB
eurjchem-1865	13	13	this	this	PRON
eurjchem-1865	13	14	:	:	PUNCT
eurjchem-1865	13	15	eur	eur	PROPN
eurjchem-1865	13	16	.	.	PUNCT
eurjchem-1865	14	1	j.	j.	PROPN
eurjchem-1865	14	2	chem	chem	PROPN
eurjchem-1865	14	3	.	.	PUNCT
eurjchem-1865	15	1	2019	2019	NUM
eurjchem-1865	15	2	,	,	PUNCT
eurjchem-1865	15	3	10(2	10(2	NUM
eurjchem-1865	15	4	)	)	PUNCT
eurjchem-1865	15	5	,	,	PUNCT
eurjchem-1865	15	6	171	171	NUM
eurjchem-1865	15	7	-	-	SYM
eurjchem-1865	15	8	174	174	NUM
eurjchem-1865	15	9	journal	journal	NOUN
eurjchem-1865	15	10	website	website	NOUN
eurjchem-1865	15	11	:	:	PUNCT
eurjchem-1865	15	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1865	15	13	1	1	X
eurjchem-1865	15	14	.	.	PUNCT
eurjchem-1865	15	15	introduction	introduction	NOUN
eurjchem-1865	15	16	bidentate	bidentate	NOUN
eurjchem-1865	15	17	diphosphine	diphosphine	NOUN
eurjchem-1865	15	18	have	have	AUX
eurjchem-1865	15	19	played	play	VERB
eurjchem-1865	15	20	a	a	DET
eurjchem-1865	15	21	key	key	ADJ
eurjchem-1865	15	22	role	role	NOUN
eurjchem-1865	15	23	in	in	ADP
eurjchem-1865	15	24	several	several	ADJ
eurjchem-1865	15	25	catalytic	catalytic	ADJ
eurjchem-1865	15	26	processes	process	NOUN
eurjchem-1865	15	27	and	and	CCONJ
eurjchem-1865	15	28	have	have	AUX
eurjchem-1865	15	29	proved	prove	VERB
eurjchem-1865	15	30	to	to	PART
eurjchem-1865	15	31	be	be	AUX
eurjchem-1865	15	32	among	among	ADP
eurjchem-1865	15	33	the	the	DET
eurjchem-1865	15	34	most	most	ADV
eurjchem-1865	15	35	active	active	ADJ
eurjchem-1865	15	36	chiral	chiral	ADJ
eurjchem-1865	15	37	ligands	ligand	NOUN
eurjchem-1865	15	38	for	for	ADP
eurjchem-1865	15	39	stereoselective	stereoselective	ADJ
eurjchem-1865	15	40	applications	application	NOUN
eurjchem-1865	15	41	[	[	X
eurjchem-1865	15	42	1	1	NUM
eurjchem-1865	15	43	-	-	SYM
eurjchem-1865	15	44	5	5	NUM
eurjchem-1865	15	45	]	]	PUNCT
eurjchem-1865	15	46	.	.	PUNCT
eurjchem-1865	16	1	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	16	2	diphosphines	diphosphine	NOUN
eurjchem-1865	16	3	[	[	X
eurjchem-1865	16	4	6	6	NUM
eurjchem-1865	16	5	-	-	SYM
eurjchem-1865	16	6	9	9	NUM
eurjchem-1865	16	7	]	]	PUNCT
eurjchem-1865	16	8	,	,	PUNCT
eurjchem-1865	16	9	in	in	ADP
eurjchem-1865	16	10	particular	particular	ADJ
eurjchem-1865	16	11	,	,	PUNCT
eurjchem-1865	16	12	represent	represent	VERB
eurjchem-1865	16	13	a	a	DET
eurjchem-1865	16	14	class	class	NOUN
eurjchem-1865	16	15	of	of	ADP
eurjchem-1865	16	16	phosphorus	phosphorus	NOUN
eurjchem-1865	16	17	ligands	ligand	NOUN
eurjchem-1865	16	18	that	that	PRON
eurjchem-1865	16	19	have	have	AUX
eurjchem-1865	16	20	been	be	AUX
eurjchem-1865	16	21	established	establish	VERB
eurjchem-1865	16	22	as	as	ADP
eurjchem-1865	16	23	being	be	AUX
eurjchem-1865	16	24	extremely	extremely	ADV
eurjchem-1865	16	25	efficient	efficient	ADJ
eurjchem-1865	16	26	in	in	ADP
eurjchem-1865	16	27	the	the	DET
eurjchem-1865	16	28	asymmetric	asymmetric	ADJ
eurjchem-1865	16	29	hydrogenation	hydrogenation	NOUN
eurjchem-1865	16	30	of	of	ADP
eurjchem-1865	16	31	a	a	DET
eurjchem-1865	16	32	wide	wide	ADJ
eurjchem-1865	16	33	range	range	NOUN
eurjchem-1865	16	34	of	of	ADP
eurjchem-1865	16	35	substrates	substrate	NOUN
eurjchem-1865	16	36	,	,	PUNCT
eurjchem-1865	16	37	particularly	particularly	ADV
eurjchem-1865	16	38	aryl	aryl	NOUN
eurjchem-1865	16	39	and	and	CCONJ
eurjchem-1865	16	40	heteroaryl	heteroaryl	NOUN
eurjchem-1865	16	41	ketones	ketone	NOUN
eurjchem-1865	16	42	[	[	PUNCT
eurjchem-1865	16	43	10	10	NUM
eurjchem-1865	16	44	-	-	SYM
eurjchem-1865	16	45	17	17	NUM
eurjchem-1865	16	46	]	]	PUNCT
eurjchem-1865	16	47	.	.	PUNCT
eurjchem-1865	17	1	whereas	whereas	SCONJ
eurjchem-1865	17	2	,	,	PUNCT
eurjchem-1865	17	3	ni(0	ni(0	PROPN
eurjchem-1865	17	4	)	)	PUNCT
eurjchem-1865	17	5	complexes	complex	NOUN
eurjchem-1865	17	6	of	of	ADP
eurjchem-1865	17	7	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	17	8	diphosphines	diphosphine	NOUN
eurjchem-1865	17	9	are	be	AUX
eurjchem-1865	17	10	known	know	VERB
eurjchem-1865	17	11	for	for	ADP
eurjchem-1865	17	12	stereo	stereo	NOUN
eurjchem-1865	17	13	-	-	PUNCT
eurjchem-1865	17	14	selectively	selectively	ADV
eurjchem-1865	17	15	catalysis	catalysis	NOUN
eurjchem-1865	17	16	of	of	ADP
eurjchem-1865	17	17	αarylation	αarylation	NOUN
eurjchem-1865	17	18	[	[	X
eurjchem-1865	17	19	18	18	NUM
eurjchem-1865	17	20	-	-	SYM
eurjchem-1865	17	21	21	21	NUM
eurjchem-1865	17	22	]	]	PUNCT
eurjchem-1865	17	23	.	.	PUNCT
eurjchem-1865	18	1	the	the	DET
eurjchem-1865	18	2	chelating	chelating	NOUN
eurjchem-1865	18	3	structure	structure	NOUN
eurjchem-1865	18	4	plays	play	VERB
eurjchem-1865	18	5	a	a	DET
eurjchem-1865	18	6	key	key	ADJ
eurjchem-1865	18	7	role	role	NOUN
eurjchem-1865	18	8	in	in	ADP
eurjchem-1865	18	9	the	the	DET
eurjchem-1865	18	10	catalytic	catalytic	ADJ
eurjchem-1865	18	11	property	property	NOUN
eurjchem-1865	18	12	of	of	ADP
eurjchem-1865	18	13	such	such	ADJ
eurjchem-1865	18	14	systems	system	NOUN
eurjchem-1865	18	15	,	,	PUNCT
eurjchem-1865	18	16	since	since	SCONJ
eurjchem-1865	18	17	it	it	PRON
eurjchem-1865	18	18	is	be	AUX
eurjchem-1865	18	19	able	able	ADJ
eurjchem-1865	18	20	to	to	PART
eurjchem-1865	18	21	impose	impose	VERB
eurjchem-1865	18	22	a	a	DET
eurjchem-1865	18	23	relatively	relatively	ADV
eurjchem-1865	18	24	rigid	rigid	ADJ
eurjchem-1865	18	25	environment	environment	NOUN
eurjchem-1865	18	26	,	,	PUNCT
eurjchem-1865	18	27	tuning	tune	VERB
eurjchem-1865	18	28	the	the	DET
eurjchem-1865	18	29	electron	electron	NOUN
eurjchem-1865	18	30	richness	richness	NOUN
eurjchem-1865	18	31	at	at	ADP
eurjchem-1865	18	32	the	the	DET
eurjchem-1865	18	33	metal	metal	NOUN
eurjchem-1865	18	34	and	and	CCONJ
eurjchem-1865	18	35	,	,	PUNCT
eurjchem-1865	18	36	in	in	ADP
eurjchem-1865	18	37	turn	turn	NOUN
eurjchem-1865	18	38	,	,	PUNCT
eurjchem-1865	18	39	the	the	DET
eurjchem-1865	18	40	reactivity	reactivity	NOUN
eurjchem-1865	18	41	of	of	ADP
eurjchem-1865	18	42	the	the	DET
eurjchem-1865	18	43	coordinated	coordinated	ADJ
eurjchem-1865	18	44	complex	complex	NOUN
eurjchem-1865	19	1	[	[	X
eurjchem-1865	19	2	22	22	NUM
eurjchem-1865	19	3	]	]	PUNCT
eurjchem-1865	19	4	.	.	PUNCT
eurjchem-1865	20	1	indeed	indeed	ADV
eurjchem-1865	20	2	,	,	PUNCT
eurjchem-1865	20	3	understanding	understand	VERB
eurjchem-1865	20	4	the	the	DET
eurjchem-1865	20	5	electronic	electronic	ADJ
eurjchem-1865	20	6	properties	property	NOUN
eurjchem-1865	20	7	of	of	ADP
eurjchem-1865	20	8	the	the	DET
eurjchem-1865	20	9	diphosphine	diphosphine	ADJ
eurjchem-1865	20	10	ligand	ligand	NOUN
eurjchem-1865	20	11	is	be	AUX
eurjchem-1865	20	12	crucial	crucial	ADJ
eurjchem-1865	20	13	to	to	PART
eurjchem-1865	20	14	design	design	VERB
eurjchem-1865	20	15	and	and	CCONJ
eurjchem-1865	20	16	develop	develop	VERB
eurjchem-1865	20	17	new	new	ADJ
eurjchem-1865	20	18	efficient	efficient	ADJ
eurjchem-1865	20	19	catalytic	catalytic	ADJ
eurjchem-1865	20	20	systems	system	NOUN
eurjchem-1865	20	21	.	.	PUNCT
eurjchem-1865	21	1	a	a	DET
eurjchem-1865	21	2	common	common	ADJ
eurjchem-1865	21	3	way	way	NOUN
eurjchem-1865	21	4	to	to	PART
eurjchem-1865	21	5	evaluate	evaluate	VERB
eurjchem-1865	21	6	experimentally	experimentally	ADV
eurjchem-1865	21	7	the	the	DET
eurjchem-1865	21	8	electron	electron	NOUN
eurjchem-1865	21	9	density	density	NOUN
eurjchem-1865	21	10	at	at	ADP
eurjchem-1865	21	11	the	the	DET
eurjchem-1865	21	12	metal	metal	NOUN
eurjchem-1865	21	13	center	center	NOUN
eurjchem-1865	21	14	is	be	AUX
eurjchem-1865	21	15	to	to	PART
eurjchem-1865	21	16	prepare	prepare	VERB
eurjchem-1865	21	17	carbonylic	carbonylic	ADJ
eurjchem-1865	21	18	complexes	complex	NOUN
eurjchem-1865	21	19	in	in	ADP
eurjchem-1865	21	20	order	order	NOUN
eurjchem-1865	21	21	to	to	PART
eurjchem-1865	21	22	measure	measure	VERB
eurjchem-1865	21	23	the	the	DET
eurjchem-1865	21	24	co	co	NOUN
eurjchem-1865	21	25	stretching	stretch	VERB
eurjchem-1865	21	26	(	(	PUNCT
eurjchem-1865	21	27	νco	νco	NOUN
eurjchem-1865	21	28	)	)	PUNCT
eurjchem-1865	21	29	.	.	PUNCT
eurjchem-1865	22	1	this	this	DET
eurjchem-1865	22	2	approach	approach	NOUN
eurjchem-1865	22	3	stemmed	stem	VERB
eurjchem-1865	22	4	from	from	ADP
eurjchem-1865	22	5	the	the	DET
eurjchem-1865	22	6	landmark	landmark	NOUN
eurjchem-1865	22	7	work	work	NOUN
eurjchem-1865	22	8	of	of	ADP
eurjchem-1865	22	9	tolman	tolman	PROPN
eurjchem-1865	22	10	on	on	ADP
eurjchem-1865	22	11	the	the	DET
eurjchem-1865	22	12	ni(0	ni(0	PROPN
eurjchem-1865	22	13	)	)	PUNCT
eurjchem-1865	22	14	monophosphine	monophosphine	NOUN
eurjchem-1865	22	15	complexes	complexe	VERB
eurjchem-1865	22	16	[	[	X
eurjchem-1865	22	17	23	23	NUM
eurjchem-1865	22	18	]	]	PUNCT
eurjchem-1865	22	19	,	,	PUNCT
eurjchem-1865	22	20	in	in	ADP
eurjchem-1865	22	21	which	which	PRON
eurjchem-1865	22	22	the	the	DET
eurjchem-1865	22	23	co	co	X
eurjchem-1865	22	24	stretching	stretch	VERB
eurjchem-1865	22	25	a1	a1	NOUN
eurjchem-1865	22	26	symmetry	symmetry	NOUN
eurjchem-1865	22	27	in	in	ADP
eurjchem-1865	22	28	the	the	DET
eurjchem-1865	22	29	corresponding	corresponding	ADJ
eurjchem-1865	22	30	ni(co)3l	ni(co)3l	ADJ
eurjchem-1865	22	31	complex	complex	NOUN
eurjchem-1865	22	32	was	be	AUX
eurjchem-1865	22	33	taken	take	VERB
eurjchem-1865	22	34	as	as	ADP
eurjchem-1865	22	35	descriptor	descriptor	NOUN
eurjchem-1865	22	36	of	of	ADP
eurjchem-1865	22	37	the	the	DET
eurjchem-1865	22	38	net	net	ADJ
eurjchem-1865	22	39	donor	donor	NOUN
eurjchem-1865	22	40	ability	ability	NOUN
eurjchem-1865	22	41	of	of	ADP
eurjchem-1865	22	42	the	the	DET
eurjchem-1865	22	43	ligand	ligand	NOUN
eurjchem-1865	22	44	(	(	PUNCT
eurjchem-1865	22	45	l	l	NOUN
eurjchem-1865	22	46	)	)	PUNCT
eurjchem-1865	22	47	.	.	PUNCT
eurjchem-1865	23	1	similarly	similarly	ADV
eurjchem-1865	23	2	this	this	DET
eurjchem-1865	23	3	parameter	parameter	NOUN
eurjchem-1865	23	4	has	have	AUX
eurjchem-1865	23	5	been	be	AUX
eurjchem-1865	23	6	also	also	ADV
eurjchem-1865	23	7	used	use	VERB
eurjchem-1865	23	8	for	for	ADP
eurjchem-1865	23	9	chelating	chelate	VERB
eurjchem-1865	23	10	systems	system	NOUN
eurjchem-1865	23	11	[	[	X
eurjchem-1865	23	12	24	24	NUM
eurjchem-1865	23	13	]	]	PUNCT
eurjchem-1865	23	14	and	and	CCONJ
eurjchem-1865	23	15	recently	recently	ADV
eurjchem-1865	23	16	studied	study	VERB
eurjchem-1865	23	17	in	in	ADP
eurjchem-1865	23	18	its	its	PRON
eurjchem-1865	23	19	nature	nature	NOUN
eurjchem-1865	23	20	from	from	ADP
eurjchem-1865	23	21	experimental	experimental	ADJ
eurjchem-1865	23	22	and	and	CCONJ
eurjchem-1865	23	23	theoretical	theoretical	ADJ
eurjchem-1865	23	24	points	point	NOUN
eurjchem-1865	23	25	of	of	ADP
eurjchem-1865	23	26	view	view	NOUN
eurjchem-1865	23	27	[	[	X
eurjchem-1865	23	28	25	25	NUM
eurjchem-1865	23	29	-	-	SYM
eurjchem-1865	23	30	27	27	NUM
eurjchem-1865	23	31	]	]	PUNCT
eurjchem-1865	23	32	.	.	PUNCT
eurjchem-1865	24	1	surprisingly	surprisingly	ADV
eurjchem-1865	24	2	,	,	PUNCT
eurjchem-1865	24	3	despite	despite	SCONJ
eurjchem-1865	24	4	the	the	DET
eurjchem-1865	24	5	systems	system	NOUN
eurjchem-1865	24	6	are	be	AUX
eurjchem-1865	24	7	of	of	ADP
eurjchem-1865	24	8	interest	interest	NOUN
eurjchem-1865	24	9	,	,	PUNCT
eurjchem-1865	24	10	only	only	ADV
eurjchem-1865	24	11	few	few	ADJ
eurjchem-1865	24	12	examples	example	NOUN
eurjchem-1865	24	13	of	of	ADP
eurjchem-1865	24	14	ni(0	ni(0	NOUN
eurjchem-1865	24	15	)	)	PUNCT
eurjchem-1865	24	16	dicarbonylic	dicarbonylic	ADJ
eurjchem-1865	24	17	complexes	complex	NOUN
eurjchem-1865	24	18	are	be	AUX
eurjchem-1865	24	19	present	present	ADJ
eurjchem-1865	24	20	in	in	ADP
eurjchem-1865	24	21	literature	literature	NOUN
eurjchem-1865	24	22	[	[	X
eurjchem-1865	24	23	28,29	28,29	X
eurjchem-1865	24	24	]	]	PUNCT
eurjchem-1865	24	25	.	.	PUNCT
eurjchem-1865	25	1	we	we	PRON
eurjchem-1865	25	2	present	present	VERB
eurjchem-1865	25	3	here	here	ADV
eurjchem-1865	25	4	the	the	DET
eurjchem-1865	25	5	crystallographic	crystallographic	ADJ
eurjchem-1865	25	6	structure	structure	NOUN
eurjchem-1865	25	7	of	of	ADP
eurjchem-1865	25	8	a	a	DET
eurjchem-1865	25	9	dicarbonyl	dicarbonyl	NOUN
eurjchem-1865	25	10	ni(0	ni(0	NOUN
eurjchem-1865	25	11	)	)	PUNCT
eurjchem-1865	25	12	complex	complex	ADJ
eurjchem-1865	25	13	bearing	bearing	NOUN
eurjchem-1865	25	14	2,2’-bis(diphenylphosphi	2,2’-bis(diphenylphosphi	ADJ
eurjchem-1865	26	1	no)-3,3’-bibenzo[b]thiophene	no)-3,3’-bibenzo[b]thiophene	PROPN
eurjchem-1865	26	2	(	(	PUNCT
eurjchem-1865	26	3	bitianp	bitianp	NOUN
eurjchem-1865	26	4	)	)	PUNCT
eurjchem-1865	26	5	,	,	PUNCT
eurjchem-1865	26	6	an	an	DET
eurjchem-1865	26	7	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	26	8	diphosphine	diphosphine	ADJ
eurjchem-1865	26	9	ligand	ligand	NOUN
eurjchem-1865	27	1	[	[	X
eurjchem-1865	27	2	30	30	NUM
eurjchem-1865	27	3	]	]	PUNCT
eurjchem-1865	27	4	(	(	PUNCT
eurjchem-1865	27	5	scheme	scheme	NOUN
eurjchem-1865	27	6	1	1	NUM
eurjchem-1865	27	7	)	)	PUNCT
eurjchem-1865	27	8	.	.	PUNCT
eurjchem-1865	28	1	2	2	X
eurjchem-1865	28	2	.	.	X
eurjchem-1865	28	3	experimental	experimental	ADJ
eurjchem-1865	28	4	all	all	DET
eurjchem-1865	28	5	manipulations	manipulation	NOUN
eurjchem-1865	28	6	involving	involve	VERB
eurjchem-1865	28	7	air	air	NOUN
eurjchem-1865	28	8	-	-	PUNCT
eurjchem-1865	28	9	sensitive	sensitive	ADJ
eurjchem-1865	28	10	materials	material	NOUN
eurjchem-1865	28	11	were	be	AUX
eurjchem-1865	28	12	performed	perform	VERB
eurjchem-1865	28	13	under	under	ADP
eurjchem-1865	28	14	nitrogen	nitrogen	NOUN
eurjchem-1865	28	15	atmosphere	atmosphere	NOUN
eurjchem-1865	28	16	using	use	VERB
eurjchem-1865	28	17	standard	standard	ADJ
eurjchem-1865	28	18	schlenk	schlenk	PROPN
eurjchem-1865	28	19	techniques	technique	NOUN
eurjchem-1865	28	20	.	.	PUNCT
eurjchem-1865	29	1	all	all	DET
eurjchem-1865	29	2	solvents	solvent	NOUN
eurjchem-1865	29	3	used	use	VERB
eurjchem-1865	29	4	were	be	AUX
eurjchem-1865	29	5	anhydrous	anhydrous	ADJ
eurjchem-1865	29	6	by	by	ADP
eurjchem-1865	29	7	fresh	fresh	ADJ
eurjchem-1865	29	8	distil	distil	PROPN
eurjchem-1865	29	9	abstract	abstract	ADJ
eurjchem-1865	29	10	research	research	NOUN
eurjchem-1865	29	11	article	article	NOUN
eurjchem-1865	29	12	keywords	keyword	VERB
eurjchem-1865	29	13	european	european	PROPN
eurjchem-1865	29	14	journal	journal	PROPN
eurjchem-1865	29	15	of	of	ADP
eurjchem-1865	29	16	chemistry	chemistry	NOUN
eurjchem-1865	29	17	issn	issn	VERB
eurjchem-1865	29	18	2153	2153	NUM
eurjchem-1865	29	19	-	-	SYM
eurjchem-1865	29	20	2249	2249	NUM
eurjchem-1865	29	21	(	(	PUNCT
eurjchem-1865	29	22	print	print	NOUN
eurjchem-1865	29	23	)	)	PUNCT
eurjchem-1865	29	24	/	/	PUNCT
eurjchem-1865	29	25	issn	issn	PROPN
eurjchem-1865	29	26	2153	2153	NUM
eurjchem-1865	29	27	-	-	SYM
eurjchem-1865	29	28	2257	2257	NUM
eurjchem-1865	29	29	(	(	PUNCT
eurjchem-1865	29	30	online	online	ADJ
eurjchem-1865	29	31	)	)	PUNCT
eurjchem-1865	29	32	–	–	PUNCT
eurjchem-1865	30	1	copyright	copyright	NOUN
eurjchem-1865	30	2	©	©	PROPN
eurjchem-1865	30	3	2019	2019	NUM
eurjchem-1865	30	4	the	the	DET
eurjchem-1865	30	5	authors	author	NOUN
eurjchem-1865	30	6	–	–	PUNCT
eurjchem-1865	30	7	atlanta	atlanta	PROPN
eurjchem-1865	30	8	publishing	publishing	PROPN
eurjchem-1865	30	9	house	house	PROPN
eurjchem-1865	30	10	llc	llc	PROPN
eurjchem-1865	30	11	–	–	PUNCT
eurjchem-1865	30	12	printed	print	VERB
eurjchem-1865	30	13	in	in	ADP
eurjchem-1865	30	14	the	the	DET
eurjchem-1865	30	15	usa	usa	PROPN
eurjchem-1865	30	16	.	.	PUNCT
eurjchem-1865	31	1	this	this	DET
eurjchem-1865	31	2	work	work	NOUN
eurjchem-1865	31	3	is	be	AUX
eurjchem-1865	31	4	published	publish	VERB
eurjchem-1865	31	5	and	and	CCONJ
eurjchem-1865	31	6	licensed	license	VERB
eurjchem-1865	31	7	by	by	ADP
eurjchem-1865	31	8	atlanta	atlanta	PROPN
eurjchem-1865	31	9	publishing	publishing	PROPN
eurjchem-1865	31	10	house	house	PROPN
eurjchem-1865	31	11	llc	llc	PROPN
eurjchem-1865	31	12	–	–	PUNCT
eurjchem-1865	31	13	cc	cc	PROPN
eurjchem-1865	31	14	by	by	ADP
eurjchem-1865	31	15	nc	nc	PROPN
eurjchem-1865	31	16	–	–	PUNCT
eurjchem-1865	31	17	some	some	DET
eurjchem-1865	31	18	rights	right	NOUN
eurjchem-1865	31	19	reserved	reserve	VERB
eurjchem-1865	31	20	.	.	PUNCT
eurjchem-1865	32	1	http://dx.doi.org/10.5155/eurjchem.10.2.171-174.1865	http://dx.doi.org/10.5155/eurjchem.10.2.171-174.1865	ADJ
eurjchem-1865	32	2	http://dx.doi.org/10.5155/eurjchem.10.2.171-174.1865	http://dx.doi.org/10.5155/eurjchem.10.2.171-174.1865	ADJ
eurjchem-1865	32	3	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.2.171-174.1865&domain=pdf&date_stamp=2019-06-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.2.171-174.1865&domain=pdf&date_stamp=2019-06-30	NOUN
eurjchem-1865	32	4	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-1865	32	5	http://dx.doi.org/10.5155/eurjchem.10.2.171-174.1865	http://dx.doi.org/10.5155/eurjchem.10.2.171-174.1865	ADJ
eurjchem-1865	32	6	mailto:marco.fuse@sns.it	mailto:marco.fuse@sns.it	AUX
eurjchem-1865	32	7	mailto:giorgio.facchetti@unimi.it	mailto:giorgio.facchetti@unimi.it	PROPN
eurjchem-1865	32	8	mailto:isabella.rimoldi@unimi.it	mailto:isabella.rimoldi@unimi.it	PROPN
eurjchem-1865	32	9	mailto:carlo.castellano@unimi.it	mailto:carlo.castellano@unimi.it	PROPN
eurjchem-1865	32	10	mailto:carlo.castellano@unimi.it	mailto:carlo.castellano@unimi.it	PROPN
eurjchem-1865	32	11	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-1865	32	12	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.2.171-174.1865&domain=pdf&date_stamp=2019-06-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.2.171-174.1865&domain=pdf&date_stamp=2019-06-30	PROPN
eurjchem-1865	32	13	�	�	PROPN
eurjchem-1865	32	14	172	172	NUM
eurjchem-1865	32	15	fusè	fusè	NOUN
eurjchem-1865	32	16	et	et	PROPN
eurjchem-1865	32	17	al	al	PROPN
eurjchem-1865	32	18	.	.	PUNCT
eurjchem-1865	32	19	/	/	SYM
eurjchem-1865	32	20	european	european	PROPN
eurjchem-1865	32	21	journal	journal	PROPN
eurjchem-1865	32	22	of	of	ADP
eurjchem-1865	32	23	chemistry	chemistry	NOUN
eurjchem-1865	32	24	10	10	NUM
eurjchem-1865	32	25	(	(	PUNCT
eurjchem-1865	32	26	2	2	NUM
eurjchem-1865	32	27	)	)	PUNCT
eurjchem-1865	32	28	(	(	PUNCT
eurjchem-1865	32	29	2019	2019	NUM
eurjchem-1865	32	30	)	)	PUNCT
eurjchem-1865	32	31	171	171	NUM
eurjchem-1865	32	32	-	-	SYM
eurjchem-1865	32	33	174	174	NUM
eurjchem-1865	32	34	ni	ni	NOUN
eurjchem-1865	32	35	oc	oc	NOUN
eurjchem-1865	32	36	oc	oc	ADP
eurjchem-1865	32	37	p	p	X
eurjchem-1865	32	38	p	p	X
eurjchem-1865	32	39	ph	ph	ADJ
eurjchem-1865	32	40	ph	ph	ADJ
eurjchem-1865	32	41	ph	ph	NOUN
eurjchem-1865	32	42	ph	ph	NOUN
eurjchem-1865	32	43	s	s	PROPN
eurjchem-1865	32	44	s	s	X
eurjchem-1865	32	45	p	p	X
eurjchem-1865	32	46	p	p	NOUN
eurjchem-1865	32	47	ph	ph	ADJ
eurjchem-1865	32	48	ph	ph	ADJ
eurjchem-1865	32	49	ph	ph	NOUN
eurjchem-1865	32	50	ph	ph	NOUN
eurjchem-1865	32	51	s	s	PART
eurjchem-1865	32	52	s	s	NOUN
eurjchem-1865	32	53	[	[	X
eurjchem-1865	32	54	ni(co)4	ni(co)4	X
eurjchem-1865	32	55	]	]	X
eurjchem-1865	32	56	ch3cl	ch3cl	X
eurjchem-1865	32	57	scheme	scheme	VERB
eurjchem-1865	32	58	1	1	NUM
eurjchem-1865	32	59	.	.	PUNCT
eurjchem-1865	32	60	synthesis	synthesis	NOUN
eurjchem-1865	32	61	of	of	ADP
eurjchem-1865	32	62	[	[	X
eurjchem-1865	32	63	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	32	64	)	)	PUNCT
eurjchem-1865	32	65	]	]	PUNCT
eurjchem-1865	32	66	complex	complex	ADJ
eurjchem-1865	32	67	.	.	PUNCT
eurjchem-1865	33	1	figure	figure	NOUN
eurjchem-1865	33	2	1	1	NUM
eurjchem-1865	33	3	.	.	PUNCT
eurjchem-1865	33	4	ft	ft	PROPN
eurjchem-1865	33	5	-	-	PUNCT
eurjchem-1865	33	6	ir	ir	NOUN
eurjchem-1865	33	7	spectra	spectra	NOUN
eurjchem-1865	33	8	of	of	ADP
eurjchem-1865	33	9	[	[	X
eurjchem-1865	33	10	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	33	11	)	)	PUNCT
eurjchem-1865	33	12	]	]	PUNCT
eurjchem-1865	34	1	complex	complex	NOUN
eurjchem-1865	34	2	in	in	ADP
eurjchem-1865	34	3	chcl3	chcl3	PROPN
eurjchem-1865	34	4	in	in	ADP
eurjchem-1865	34	5	the	the	DET
eurjchem-1865	34	6	carbonyl	carbonyl	NOUN
eurjchem-1865	34	7	stretching	stretch	VERB
eurjchem-1865	34	8	region	region	NOUN
eurjchem-1865	34	9	.	.	PUNCT
eurjchem-1865	35	1	the	the	DET
eurjchem-1865	35	2	two	two	NUM
eurjchem-1865	35	3	most	most	ADV
eurjchem-1865	35	4	intense	intense	ADJ
eurjchem-1865	35	5	peaks	peak	NOUN
eurjchem-1865	35	6	at	at	ADP
eurjchem-1865	35	7	2007	2007	NUM
eurjchem-1865	35	8	and	and	CCONJ
eurjchem-1865	35	9	1947	1947	NUM
eurjchem-1865	35	10	cm-1	cm-1	X
eurjchem-1865	35	11	represent	represent	VERB
eurjchem-1865	35	12	the	the	DET
eurjchem-1865	35	13	symmetric	symmetric	ADJ
eurjchem-1865	35	14	and	and	CCONJ
eurjchem-1865	35	15	anti	anti	ADJ
eurjchem-1865	35	16	-	-	ADJ
eurjchem-1865	35	17	symmetric	symmetric	ADJ
eurjchem-1865	35	18	stretching	stretching	NOUN
eurjchem-1865	35	19	,	,	PUNCT
eurjchem-1865	35	20	respectively	respectively	ADV
eurjchem-1865	35	21	.	.	PUNCT
eurjchem-1865	36	1	lation	lation	NOUN
eurjchem-1865	36	2	under	under	ADP
eurjchem-1865	36	3	nitrogen	nitrogen	NOUN
eurjchem-1865	36	4	before	before	ADP
eurjchem-1865	36	5	use	use	NOUN
eurjchem-1865	36	6	.	.	PUNCT
eurjchem-1865	37	1	unless	unless	SCONJ
eurjchem-1865	37	2	otherwise	otherwise	ADV
eurjchem-1865	37	3	stated	state	VERB
eurjchem-1865	37	4	,	,	PUNCT
eurjchem-1865	37	5	reagents	reagent	NOUN
eurjchem-1865	37	6	were	be	AUX
eurjchem-1865	37	7	purchased	purchase	VERB
eurjchem-1865	37	8	from	from	ADP
eurjchem-1865	37	9	commercial	commercial	ADJ
eurjchem-1865	37	10	sources	source	NOUN
eurjchem-1865	37	11	and	and	CCONJ
eurjchem-1865	37	12	used	use	VERB
eurjchem-1865	37	13	without	without	ADP
eurjchem-1865	37	14	further	further	ADJ
eurjchem-1865	37	15	purification	purification	NOUN
eurjchem-1865	37	16	.	.	PUNCT
eurjchem-1865	38	1	bitianp	bitianp	PROPN
eurjchem-1865	38	2	ligand	ligand	PROPN
eurjchem-1865	39	1	[	[	X
eurjchem-1865	39	2	30	30	NUM
eurjchem-1865	39	3	]	]	PUNCT
eurjchem-1865	39	4	and	and	CCONJ
eurjchem-1865	40	1	the	the	DET
eurjchem-1865	40	2	respective	respective	ADJ
eurjchem-1865	40	3	ni(0	ni(0	PROPN
eurjchem-1865	40	4	)	)	PUNCT
eurjchem-1865	40	5	dicarbonyl	dicarbonyl	NOUN
eurjchem-1865	40	6	complex	complex	NOUN
eurjchem-1865	40	7	[	[	X
eurjchem-1865	40	8	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	40	9	)	)	PUNCT
eurjchem-1865	40	10	]	]	PUNCT
eurjchem-1865	40	11	were	be	AUX
eurjchem-1865	40	12	synthesized	synthesize	VERB
eurjchem-1865	40	13	according	accord	VERB
eurjchem-1865	40	14	to	to	ADP
eurjchem-1865	40	15	literature	literature	NOUN
eurjchem-1865	40	16	procedures	procedure	NOUN
eurjchem-1865	40	17	[	[	X
eurjchem-1865	40	18	25	25	NUM
eurjchem-1865	40	19	]	]	PUNCT
eurjchem-1865	40	20	.	.	PUNCT
eurjchem-1865	41	1	ftir	ftir	PROPN
eurjchem-1865	41	2	spectra	spectra	PROPN
eurjchem-1865	41	3	of	of	ADP
eurjchem-1865	41	4	chloroform	chloroform	NOUN
eurjchem-1865	41	5	solutions	solution	NOUN
eurjchem-1865	41	6	were	be	AUX
eurjchem-1865	41	7	recorded	record	VERB
eurjchem-1865	41	8	at	at	ADP
eurjchem-1865	41	9	room	room	NOUN
eurjchem-1865	41	10	temperature	temperature	NOUN
eurjchem-1865	41	11	by	by	ADP
eurjchem-1865	41	12	using	use	VERB
eurjchem-1865	41	13	a	a	DET
eurjchem-1865	41	14	perkin	perkin	PROPN
eurjchem-1865	41	15	elmer	elmer	PROPN
eurjchem-1865	41	16	(	(	PUNCT
eurjchem-1865	41	17	ma	ma	PROPN
eurjchem-1865	41	18	,	,	PUNCT
eurjchem-1865	41	19	usa	usa	PROPN
eurjchem-1865	41	20	)	)	PUNCT
eurjchem-1865	41	21	ftir	ftir	PROPN
eurjchem-1865	41	22	spectrometer	spectrometer	NOUN
eurjchem-1865	41	23	“	"	PUNCT
eurjchem-1865	41	24	spectrum	spectrum	VERB
eurjchem-1865	41	25	one	one	NUM
eurjchem-1865	41	26	”	"	PUNCT
eurjchem-1865	41	27	in	in	ADP
eurjchem-1865	41	28	a	a	DET
eurjchem-1865	41	29	spectral	spectral	ADJ
eurjchem-1865	41	30	region	region	NOUN
eurjchem-1865	41	31	between	between	ADP
eurjchem-1865	41	32	2200	2200	NUM
eurjchem-1865	41	33	and	and	CCONJ
eurjchem-1865	41	34	1600	1600	NUM
eurjchem-1865	41	35	cm-1	cm-1	NOUN
eurjchem-1865	41	36	and	and	CCONJ
eurjchem-1865	41	37	analyzed	analyze	VERB
eurjchem-1865	41	38	using	use	VERB
eurjchem-1865	41	39	the	the	DET
eurjchem-1865	41	40	transmittance	transmittance	NOUN
eurjchem-1865	41	41	technique	technique	NOUN
eurjchem-1865	41	42	with	with	ADP
eurjchem-1865	41	43	32	32	NUM
eurjchem-1865	41	44	scans	scan	NOUN
eurjchem-1865	41	45	per	per	ADP
eurjchem-1865	41	46	ion	ion	NOUN
eurjchem-1865	41	47	and	and	CCONJ
eurjchem-1865	41	48	4	4	NUM
eurjchem-1865	41	49	cm-1	cm-1	NOUN
eurjchem-1865	41	50	resolution	resolution	NOUN
eurjchem-1865	41	51	.	.	PUNCT
eurjchem-1865	42	1	1h	1h	NUM
eurjchem-1865	42	2	,	,	PUNCT
eurjchem-1865	42	3	13c	13c	NOUN
eurjchem-1865	42	4	,	,	PUNCT
eurjchem-1865	42	5	and	and	CCONJ
eurjchem-1865	42	6	31p	31p	NUM
eurjchem-1865	42	7	nmr	nmr	NOUN
eurjchem-1865	42	8	spectra	spectra	NOUN
eurjchem-1865	42	9	were	be	AUX
eurjchem-1865	42	10	recorded	record	VERB
eurjchem-1865	42	11	in	in	ADP
eurjchem-1865	42	12	cdcl3	cdcl3	NOUN
eurjchem-1865	42	13	on	on	ADP
eurjchem-1865	42	14	bruker	bruker	PROPN
eurjchem-1865	42	15	drx	drx	PROPN
eurjchem-1865	42	16	avance	avance	PROPN
eurjchem-1865	42	17	300	300	NUM
eurjchem-1865	42	18	mhz	mhz	NOUN
eurjchem-1865	42	19	equipped	equip	VERB
eurjchem-1865	42	20	with	with	ADP
eurjchem-1865	42	21	a	a	DET
eurjchem-1865	42	22	non	non	ADJ
eurjchem-1865	42	23	-	-	ADJ
eurjchem-1865	42	24	reverse	reverse	ADJ
eurjchem-1865	42	25	probe	probe	NOUN
eurjchem-1865	42	26	or	or	CCONJ
eurjchem-1865	42	27	bruker	bruker	PROPN
eurjchem-1865	42	28	drx	drx	PROPN
eurjchem-1865	42	29	avance	avance	PROPN
eurjchem-1865	42	30	400	400	NUM
eurjchem-1865	42	31	mhz	mhz	NOUN
eurjchem-1865	42	32	.	.	PUNCT
eurjchem-1865	43	1	chemical	chemical	ADJ
eurjchem-1865	43	2	shifts	shift	NOUN
eurjchem-1865	43	3	(	(	PUNCT
eurjchem-1865	43	4	in	in	ADP
eurjchem-1865	43	5	ppm	ppm	NOUN
eurjchem-1865	43	6	)	)	PUNCT
eurjchem-1865	43	7	were	be	AUX
eurjchem-1865	43	8	referenced	reference	VERB
eurjchem-1865	43	9	to	to	ADP
eurjchem-1865	43	10	residual	residual	ADJ
eurjchem-1865	43	11	solvent	solvent	NOUN
eurjchem-1865	43	12	proton	proton	NOUN
eurjchem-1865	43	13	/	/	SYM
eurjchem-1865	43	14	carbon	carbon	NOUN
eurjchem-1865	43	15	peak	peak	NOUN
eurjchem-1865	43	16	or	or	CCONJ
eurjchem-1865	43	17	using	use	VERB
eurjchem-1865	43	18	external	external	ADJ
eurjchem-1865	43	19	standard	standard	ADJ
eurjchem-1865	43	20	85	85	NUM
eurjchem-1865	43	21	%	%	NOUN
eurjchem-1865	43	22	h3po4	h3po4	NOUN
eurjchem-1865	43	23	for	for	ADP
eurjchem-1865	43	24	31p	31p	NOUN
eurjchem-1865	43	25	nmr	nmr	NOUN
eurjchem-1865	43	26	.	.	PUNCT
eurjchem-1865	44	1	signal	signal	PROPN
eurjchem-1865	44	2	multiplicity	multiplicity	NOUN
eurjchem-1865	44	3	was	be	AUX
eurjchem-1865	44	4	determined	determine	VERB
eurjchem-1865	44	5	as	as	ADP
eurjchem-1865	44	6	s	s	NOUN
eurjchem-1865	44	7	(	(	PUNCT
eurjchem-1865	44	8	singlet	singlet	NOUN
eurjchem-1865	44	9	)	)	PUNCT
eurjchem-1865	44	10	,	,	PUNCT
eurjchem-1865	44	11	d	d	X
eurjchem-1865	44	12	(	(	PUNCT
eurjchem-1865	44	13	doublet	doublet	PROPN
eurjchem-1865	44	14	)	)	PUNCT
eurjchem-1865	44	15	,	,	PUNCT
eurjchem-1865	44	16	t	t	PROPN
eurjchem-1865	44	17	(	(	PUNCT
eurjchem-1865	44	18	triplet	triplet	NOUN
eurjchem-1865	44	19	)	)	PUNCT
eurjchem-1865	44	20	,	,	PUNCT
eurjchem-1865	44	21	q	q	PROPN
eurjchem-1865	44	22	(	(	PUNCT
eurjchem-1865	44	23	quartet	quartet	NOUN
eurjchem-1865	44	24	)	)	PUNCT
eurjchem-1865	44	25	or	or	CCONJ
eurjchem-1865	44	26	m	m	PROPN
eurjchem-1865	44	27	(	(	PUNCT
eurjchem-1865	44	28	multiplet	multiplet	NOUN
eurjchem-1865	44	29	)	)	PUNCT
eurjchem-1865	44	30	.	.	PUNCT
eurjchem-1865	45	1	2.1	2.1	NUM
eurjchem-1865	45	2	.	.	PUNCT
eurjchem-1865	45	3	synthesis	synthesis	NOUN
eurjchem-1865	45	4	of	of	ADP
eurjchem-1865	45	5	[	[	X
eurjchem-1865	45	6	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	45	7	)	)	PUNCT
eurjchem-1865	45	8	]	]	PUNCT
eurjchem-1865	46	1	complex	complex	ADJ
eurjchem-1865	46	2	to	to	ADP
eurjchem-1865	46	3	a	a	DET
eurjchem-1865	46	4	solution	solution	NOUN
eurjchem-1865	46	5	of	of	ADP
eurjchem-1865	46	6	diphosphine	diphosphine	ADJ
eurjchem-1865	46	7	ligand	ligand	NOUN
eurjchem-1865	46	8	in	in	ADP
eurjchem-1865	46	9	cdcl3	cdcl3	NOUN
eurjchem-1865	46	10	(	(	PUNCT
eurjchem-1865	46	11	1	1	NUM
eurjchem-1865	46	12	mm	mm	NOUN
eurjchem-1865	46	13	)	)	PUNCT
eurjchem-1865	46	14	,	,	PUNCT
eurjchem-1865	46	15	1	1	NUM
eurjchem-1865	46	16	mmol	mmol	NOUN
eurjchem-1865	46	17	of	of	ADP
eurjchem-1865	46	18	[	[	X
eurjchem-1865	46	19	ni(co)4	ni(co)4	NOUN
eurjchem-1865	46	20	]	]	PUNCT
eurjchem-1865	46	21	was	be	AUX
eurjchem-1865	46	22	added	add	VERB
eurjchem-1865	46	23	and	and	CCONJ
eurjchem-1865	46	24	the	the	DET
eurjchem-1865	46	25	resulting	result	VERB
eurjchem-1865	46	26	mixture	mixture	NOUN
eurjchem-1865	46	27	kept	keep	VERB
eurjchem-1865	46	28	under	under	ADP
eurjchem-1865	46	29	stirring	stirring	NOUN
eurjchem-1865	46	30	.	.	PUNCT
eurjchem-1865	47	1	the	the	DET
eurjchem-1865	47	2	reaction	reaction	NOUN
eurjchem-1865	47	3	was	be	AUX
eurjchem-1865	47	4	then	then	ADV
eurjchem-1865	47	5	monitored	monitor	VERB
eurjchem-1865	47	6	by	by	ADP
eurjchem-1865	47	7	31p	31p	NOUN
eurjchem-1865	47	8	nmr	nmr	NOUN
eurjchem-1865	47	9	.	.	PUNCT
eurjchem-1865	48	1	[	[	X
eurjchem-1865	48	2	ni(co)4	ni(co)4	X
eurjchem-1865	48	3	]	]	PUNCT
eurjchem-1865	48	4	with	with	SCONJ
eurjchem-1865	48	5	the	the	DET
eurjchem-1865	48	6	diphosphine	diphosphine	NOUN
eurjchem-1865	48	7	quickly	quickly	ADV
eurjchem-1865	48	8	reacted	react	VERB
eurjchem-1865	48	9	and	and	CCONJ
eurjchem-1865	48	10	produced	produce	VERB
eurjchem-1865	48	11	the	the	DET
eurjchem-1865	48	12	corresponding	corresponding	ADJ
eurjchem-1865	48	13	tetrahedral	tetrahedral	ADJ
eurjchem-1865	48	14	dicarbonyl	dicarbonyl	NOUN
eurjchem-1865	48	15	diphosphine	diphosphine	PROPN
eurjchem-1865	48	16	complex	complex	NOUN
eurjchem-1865	48	17	.	.	PUNCT
eurjchem-1865	49	1	the	the	DET
eurjchem-1865	49	2	reaction	reaction	NOUN
eurjchem-1865	49	3	proceeded	proceed	VERB
eurjchem-1865	49	4	without	without	ADP
eurjchem-1865	49	5	formation	formation	NOUN
eurjchem-1865	49	6	of	of	ADP
eurjchem-1865	49	7	sideproducts	sideproduct	NOUN
eurjchem-1865	49	8	as	as	SCONJ
eurjchem-1865	49	9	stated	state	VERB
eurjchem-1865	49	10	by	by	ADP
eurjchem-1865	49	11	the	the	DET
eurjchem-1865	49	12	presence	presence	NOUN
eurjchem-1865	49	13	of	of	ADP
eurjchem-1865	49	14	a	a	DET
eurjchem-1865	49	15	single	single	ADJ
eurjchem-1865	49	16	peak	peak	NOUN
eurjchem-1865	49	17	in	in	ADP
eurjchem-1865	49	18	the	the	DET
eurjchem-1865	49	19	31p	31p	NUM
eurjchem-1865	49	20	nmr	nmr	NOUN
eurjchem-1865	49	21	spectrum	spectrum	NOUN
eurjchem-1865	49	22	[	[	X
eurjchem-1865	49	23	31	31	NUM
eurjchem-1865	49	24	]	]	PUNCT
eurjchem-1865	49	25	.	.	PUNCT
eurjchem-1865	50	1	crystals	crystal	NOUN
eurjchem-1865	50	2	suitable	suitable	ADJ
eurjchem-1865	50	3	for	for	ADP
eurjchem-1865	50	4	x	x	ADJ
eurjchem-1865	50	5	-	-	NOUN
eurjchem-1865	50	6	ray	ray	ADJ
eurjchem-1865	50	7	crystallographic	crystallographic	ADJ
eurjchem-1865	50	8	analysis	analysis	NOUN
eurjchem-1865	50	9	were	be	AUX
eurjchem-1865	50	10	obtained	obtain	VERB
eurjchem-1865	50	11	by	by	ADP
eurjchem-1865	50	12	slow	slow	ADJ
eurjchem-1865	50	13	evaporation	evaporation	NOUN
eurjchem-1865	50	14	of	of	ADP
eurjchem-1865	50	15	the	the	DET
eurjchem-1865	50	16	solvent	solvent	NOUN
eurjchem-1865	50	17	in	in	ADP
eurjchem-1865	50	18	n2	n2	ADJ
eurjchem-1865	50	19	stream	stream	NOUN
eurjchem-1865	50	20	.	.	PUNCT
eurjchem-1865	51	1	[	[	X
eurjchem-1865	51	2	ni(co)2(2	ni(co)2(2	ADJ
eurjchem-1865	51	3	,	,	PUNCT
eurjchem-1865	51	4	2'-bis(diphenylphosphanyl)-3	2'-bis(diphenylphosphanyl)-3	NUM
eurjchem-1865	51	5	,	,	PUNCT
eurjchem-1865	51	6	3'-bibenzo[b]thiophene	3'-bibenzo[b]thiophene	NUM
eurjchem-1865	51	7	)	)	PUNCT
eurjchem-1865	51	8	]	]	X
eurjchem-1865	51	9	:	:	PUNCT
eurjchem-1865	51	10	color	color	NOUN
eurjchem-1865	51	11	:	:	PUNCT
eurjchem-1865	51	12	pale	pale	ADJ
eurjchem-1865	51	13	yellow	yellow	ADJ
eurjchem-1865	51	14	.	.	PUNCT
eurjchem-1865	52	1	ft	ft	PROPN
eurjchem-1865	52	2	-	-	PUNCT
eurjchem-1865	52	3	ir	ir	NOUN
eurjchem-1865	52	4	:	:	PUNCT
eurjchem-1865	52	5	(	(	PUNCT
eurjchem-1865	52	6	chcl3	chcl3	PROPN
eurjchem-1865	52	7	,	,	PUNCT
eurjchem-1865	52	8	ν	ν	PROPN
eurjchem-1865	52	9	,	,	PUNCT
eurjchem-1865	52	10	cm-1	cm-1	NUM
eurjchem-1865	52	11	):	):	PUNCT
eurjchem-1865	52	12	2007	2007	NUM
eurjchem-1865	52	13	(	(	PUNCT
eurjchem-1865	52	14	co	co	NOUN
eurjchem-1865	52	15	)	)	PUNCT
eurjchem-1865	52	16	(	(	PUNCT
eurjchem-1865	52	17	symmetric	symmetric	ADJ
eurjchem-1865	52	18	stretching	stretching	NOUN
eurjchem-1865	52	19	)	)	PUNCT
eurjchem-1865	52	20	,	,	PUNCT
eurjchem-1865	52	21	1947	1947	NUM
eurjchem-1865	52	22	(	(	PUNCT
eurjchem-1865	52	23	co	co	NOUN
eurjchem-1865	52	24	)	)	PUNCT
eurjchem-1865	52	25	(	(	PUNCT
eurjchem-1865	52	26	asymmetric	asymmetric	ADJ
eurjchem-1865	52	27	stretching	stretching	NOUN
eurjchem-1865	52	28	)	)	PUNCT
eurjchem-1865	52	29	.	.	PUNCT
eurjchem-1865	53	1	1h	1h	NUM
eurjchem-1865	53	2	nmr	nmr	NOUN
eurjchem-1865	53	3	(	(	PUNCT
eurjchem-1865	53	4	300	300	NUM
eurjchem-1865	53	5	mhz	mhz	NOUN
eurjchem-1865	53	6	,	,	PUNCT
eurjchem-1865	53	7	cdcl3	cdcl3	PROPN
eurjchem-1865	53	8	,	,	PUNCT
eurjchem-1865	53	9	δ	δ	PROPN
eurjchem-1865	53	10	,	,	PUNCT
eurjchem-1865	53	11	ppm	ppm	NUM
eurjchem-1865	53	12	):	):	PUNCT
eurjchem-1865	53	13	6.89	6.89	NUM
eurjchem-1865	53	14	(	(	PUNCT
eurjchem-1865	53	15	m	m	PROPN
eurjchem-1865	53	16	,	,	PUNCT
eurjchem-1865	53	17	2h	2h	NUM
eurjchem-1865	53	18	,	,	PUNCT
eurjchem-1865	53	19	arh	arh	ADJ
eurjchem-1865	53	20	)	)	PUNCT
eurjchem-1865	53	21	,	,	PUNCT
eurjchem-1865	53	22	6.99	6.99	NUM
eurjchem-1865	53	23	(	(	PUNCT
eurjchem-1865	53	24	m	m	PROPN
eurjchem-1865	53	25	,	,	PUNCT
eurjchem-1865	53	26	2h	2h	NUM
eurjchem-1865	53	27	,	,	PUNCT
eurjchem-1865	53	28	arh	arh	ADJ
eurjchem-1865	53	29	)	)	PUNCT
eurjchem-1865	53	30	,	,	PUNCT
eurjchem-1865	53	31	7.13	7.13	NUM
eurjchem-1865	53	32	(	(	PUNCT
eurjchem-1865	53	33	m	m	PROPN
eurjchem-1865	53	34	,	,	PUNCT
eurjchem-1865	53	35	3h	3h	NUM
eurjchem-1865	53	36	,	,	PUNCT
eurjchem-1865	53	37	arh	arh	PROPN
eurjchem-1865	53	38	)	)	PUNCT
eurjchem-1865	53	39	,	,	PUNCT
eurjchem-1865	53	40	7.19	7.19	NUM
eurjchem-1865	53	41	(	(	PUNCT
eurjchem-1865	53	42	m	m	PROPN
eurjchem-1865	53	43	,	,	PUNCT
eurjchem-1865	53	44	2h	2h	NUM
eurjchem-1865	53	45	,	,	PUNCT
eurjchem-1865	53	46	arh	arh	ADJ
eurjchem-1865	53	47	)	)	PUNCT
eurjchem-1865	53	48	,	,	PUNCT
eurjchem-1865	53	49	7.29	7.29	NUM
eurjchem-1865	53	50	(	(	PUNCT
eurjchem-1865	53	51	m	m	PROPN
eurjchem-1865	53	52	,	,	PUNCT
eurjchem-1865	53	53	3h	3h	NUM
eurjchem-1865	53	54	,	,	PUNCT
eurjchem-1865	53	55	arh	arh	PROPN
eurjchem-1865	53	56	)	)	PUNCT
eurjchem-1865	53	57	,	,	PUNCT
eurjchem-1865	53	58	7.50	7.50	NUM
eurjchem-1865	53	59	(	(	PUNCT
eurjchem-1865	53	60	m	m	PROPN
eurjchem-1865	53	61	,	,	PUNCT
eurjchem-1865	53	62	8h	8h	NUM
eurjchem-1865	53	63	,	,	PUNCT
eurjchem-1865	53	64	arh	arh	PROPN
eurjchem-1865	53	65	)	)	PUNCT
eurjchem-1865	53	66	,	,	PUNCT
eurjchem-1865	53	67	7.66	7.66	NUM
eurjchem-1865	53	68	(	(	PUNCT
eurjchem-1865	53	69	m	m	PROPN
eurjchem-1865	53	70	,	,	PUNCT
eurjchem-1865	53	71	4h	4h	NUM
eurjchem-1865	53	72	,	,	PUNCT
eurjchem-1865	53	73	arh	arh	PROPN
eurjchem-1865	53	74	)	)	PUNCT
eurjchem-1865	53	75	,	,	PUNCT
eurjchem-1865	53	76	7.74	7.74	NUM
eurjchem-1865	53	77	(	(	PUNCT
eurjchem-1865	53	78	m	m	PROPN
eurjchem-1865	53	79	,	,	PUNCT
eurjchem-1865	53	80	2h	2h	NUM
eurjchem-1865	53	81	,	,	PUNCT
eurjchem-1865	53	82	arh	arh	ADJ
eurjchem-1865	53	83	)	)	PUNCT
eurjchem-1865	53	84	,	,	PUNCT
eurjchem-1865	53	85	7.87	7.87	NUM
eurjchem-1865	53	86	(	(	PUNCT
eurjchem-1865	53	87	m	m	PROPN
eurjchem-1865	53	88	,	,	PUNCT
eurjchem-1865	53	89	2h	2h	NUM
eurjchem-1865	53	90	,	,	PUNCT
eurjchem-1865	53	91	arh	arh	ADJ
eurjchem-1865	53	92	)	)	PUNCT
eurjchem-1865	53	93	.	.	PUNCT
eurjchem-1865	54	1	31p	31p	NUM
eurjchem-1865	54	2	nmr	nmr	NOUN
eurjchem-1865	54	3	(	(	PUNCT
eurjchem-1865	54	4	121.5	121.5	NUM
eurjchem-1865	54	5	mhz	mhz	NOUN
eurjchem-1865	54	6	,	,	PUNCT
eurjchem-1865	54	7	cdcl3	cdcl3	PROPN
eurjchem-1865	54	8	,	,	PUNCT
eurjchem-1865	54	9	δ	δ	PROPN
eurjchem-1865	54	10	,	,	PUNCT
eurjchem-1865	54	11	ppm	ppm	NUM
eurjchem-1865	54	12	):	):	PUNCT
eurjchem-1865	54	13	22.9	22.9	NUM
eurjchem-1865	54	14	(	(	PUNCT
eurjchem-1865	54	15	s	s	NOUN
eurjchem-1865	54	16	,	,	PUNCT
eurjchem-1865	54	17	2p	2p	NUM
eurjchem-1865	54	18	)	)	PUNCT
eurjchem-1865	54	19	.	.	PUNCT
eurjchem-1865	55	1	13c	13c	NOUN
eurjchem-1865	55	2	nmr	nmr	NOUN
eurjchem-1865	55	3	(	(	PUNCT
eurjchem-1865	55	4	75	75	NUM
eurjchem-1865	55	5	mhz	mhz	NOUN
eurjchem-1865	55	6	,	,	PUNCT
eurjchem-1865	55	7	cdcl3	cdcl3	PROPN
eurjchem-1865	55	8	,	,	PUNCT
eurjchem-1865	55	9	δ	δ	PROPN
eurjchem-1865	55	10	,	,	PUNCT
eurjchem-1865	55	11	ppm	ppm	NOUN
eurjchem-1865	55	12	):	):	PUNCT
eurjchem-1865	55	13	200.10	200.10	NUM
eurjchem-1865	55	14	(	(	PUNCT
eurjchem-1865	55	15	2c	2c	NOUN
eurjchem-1865	55	16	,	,	PUNCT
eurjchem-1865	55	17	co	co	NOUN
eurjchem-1865	55	18	)	)	PUNCT
eurjchem-1865	55	19	,	,	PUNCT
eurjchem-1865	55	20	173.84	173.84	NUM
eurjchem-1865	55	21	(	(	PUNCT
eurjchem-1865	55	22	arc	arc	NOUN
eurjchem-1865	55	23	)	)	PUNCT
eurjchem-1865	55	24	,	,	PUNCT
eurjchem-1865	55	25	140.71	140.71	NUM
eurjchem-1865	55	26	(	(	PUNCT
eurjchem-1865	55	27	ar	ar	NOUN
eurjchem-1865	55	28	-	-	NOUN
eurjchem-1865	55	29	c	c	NOUN
eurjchem-1865	55	30	)	)	PUNCT
eurjchem-1865	55	31	,	,	PUNCT
eurjchem-1865	55	32	134.17	134.17	NUM
eurjchem-1865	55	33	(	(	PUNCT
eurjchem-1865	55	34	ar	ar	NOUN
eurjchem-1865	55	35	-	-	NOUN
eurjchem-1865	55	36	ch	ch	NOUN
eurjchem-1865	55	37	)	)	PUNCT
eurjchem-1865	55	38	,	,	PUNCT
eurjchem-1865	55	39	133.95	133.95	NUM
eurjchem-1865	55	40	(	(	PUNCT
eurjchem-1865	55	41	ar	ar	NOUN
eurjchem-1865	55	42	-	-	ADJ
eurjchem-1865	55	43	ch),133,0	ch),133,0	PROPN
eurjchem-1865	55	44	(	(	PUNCT
eurjchem-1865	55	45	arc	arc	NOUN
eurjchem-1865	55	46	)	)	PUNCT
eurjchem-1865	55	47	,	,	PUNCT
eurjchem-1865	55	48	132.58	132.58	NUM
eurjchem-1865	55	49	(	(	PUNCT
eurjchem-1865	55	50	ar	ar	NOUN
eurjchem-1865	55	51	-	-	NOUN
eurjchem-1865	55	52	ch	ch	NOUN
eurjchem-1865	55	53	)	)	PUNCT
eurjchem-1865	55	54	,	,	PUNCT
eurjchem-1865	55	55	130.43	130.43	NUM
eurjchem-1865	55	56	(	(	PUNCT
eurjchem-1865	55	57	ar	ar	NOUN
eurjchem-1865	55	58	-	-	NOUN
eurjchem-1865	55	59	ch	ch	NOUN
eurjchem-1865	55	60	)	)	PUNCT
eurjchem-1865	55	61	,	,	PUNCT
eurjchem-1865	55	62	129.23	129.23	NUM
eurjchem-1865	55	63	(	(	PUNCT
eurjchem-1865	55	64	ar	ar	NOUN
eurjchem-1865	55	65	-	-	NOUN
eurjchem-1865	55	66	ch	ch	NOUN
eurjchem-1865	55	67	)	)	PUNCT
eurjchem-1865	55	68	,	,	PUNCT
eurjchem-1865	55	69	128.49	128.49	NUM
eurjchem-1865	55	70	(	(	PUNCT
eurjchem-1865	55	71	ar	ar	NOUN
eurjchem-1865	55	72	-	-	NOUN
eurjchem-1865	55	73	ch	ch	NOUN
eurjchem-1865	55	74	)	)	PUNCT
eurjchem-1865	55	75	,	,	PUNCT
eurjchem-1865	55	76	127.75	127.75	NUM
eurjchem-1865	55	77	(	(	PUNCT
eurjchem-1865	55	78	ar	ar	NOUN
eurjchem-1865	55	79	-	-	NOUN
eurjchem-1865	55	80	ch	ch	NOUN
eurjchem-1865	55	81	)	)	PUNCT
eurjchem-1865	55	82	,	,	PUNCT
eurjchem-1865	55	83	124.64	124.64	NUM
eurjchem-1865	55	84	(	(	PUNCT
eurjchem-1865	55	85	ar	ar	NOUN
eurjchem-1865	55	86	-	-	NOUN
eurjchem-1865	55	87	ch	ch	NOUN
eurjchem-1865	55	88	)	)	PUNCT
eurjchem-1865	55	89	,	,	PUNCT
eurjchem-1865	55	90	124.00	124.00	NUM
eurjchem-1865	55	91	(	(	PUNCT
eurjchem-1865	55	92	ar	ar	NOUN
eurjchem-1865	55	93	-	-	NOUN
eurjchem-1865	55	94	ch	ch	NOUN
eurjchem-1865	55	95	)	)	PUNCT
eurjchem-1865	55	96	,	,	PUNCT
eurjchem-1865	55	97	123.53	123.53	NUM
eurjchem-1865	55	98	(	(	PUNCT
eurjchem-1865	55	99	ar	ar	NOUN
eurjchem-1865	55	100	-	-	NOUN
eurjchem-1865	55	101	ch	ch	NOUN
eurjchem-1865	55	102	)	)	PUNCT
eurjchem-1865	55	103	,	,	PUNCT
eurjchem-1865	55	104	121.87	121.87	NUM
eurjchem-1865	55	105	(	(	PUNCT
eurjchem-1865	55	106	ar	ar	NOUN
eurjchem-1865	55	107	-	-	NOUN
eurjchem-1865	55	108	ch	ch	NOUN
eurjchem-1865	55	109	)	)	PUNCT
eurjchem-1865	55	110	,	,	PUNCT
eurjchem-1865	55	111	99.80	99.80	NUM
eurjchem-1865	55	112	(	(	PUNCT
eurjchem-1865	55	113	ar	ar	NOUN
eurjchem-1865	55	114	-	-	NOUN
eurjchem-1865	55	115	ch	ch	NOUN
eurjchem-1865	55	116	)	)	PUNCT
eurjchem-1865	55	117	.	.	PUNCT
eurjchem-1865	56	1	2.2	2.2	NUM
eurjchem-1865	56	2	.	.	PUNCT
eurjchem-1865	57	1	crystal	crystal	NOUN
eurjchem-1865	57	2	structure	structure	NOUN
eurjchem-1865	57	3	of	of	ADP
eurjchem-1865	57	4	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	57	5	)	)	PUNCT
eurjchem-1865	57	6	c42h28o2p2s2ni	c42h28o2p2s2ni	NOUN
eurjchem-1865	57	7	,	,	PUNCT
eurjchem-1865	57	8	m	m	VERB
eurjchem-1865	57	9	=	=	NOUN
eurjchem-1865	57	10	749.41	749.41	NUM
eurjchem-1865	57	11	,	,	PUNCT
eurjchem-1865	57	12	triclinic	triclinic	ADJ
eurjchem-1865	57	13	,	,	PUNCT
eurjchem-1865	57	14	a	a	DET
eurjchem-1865	57	15	=	=	PUNCT
eurjchem-1865	57	16	10.539(2	10.539(2	NUM
eurjchem-1865	57	17	)	)	PUNCT
eurjchem-1865	58	1	å	å	PROPN
eurjchem-1865	58	2	,	,	PUNCT
eurjchem-1865	58	3	b	b	X
eurjchem-1865	58	4	=	=	SYM
eurjchem-1865	58	5	11.811(2	11.811(2	PROPN
eurjchem-1865	58	6	)	)	PUNCT
eurjchem-1865	58	7	å	å	NOUN
eurjchem-1865	58	8	,	,	PUNCT
eurjchem-1865	58	9	c	c	NOUN
eurjchem-1865	58	10	=	=	NOUN
eurjchem-1865	58	11	15.994(3	15.994(3	NOUN
eurjchem-1865	58	12	)	)	PUNCT
eurjchem-1865	59	1	å	å	NOUN
eurjchem-1865	59	2	,	,	PUNCT
eurjchem-1865	59	3	α	α	NOUN
eurjchem-1865	59	4	=	=	PUNCT
eurjchem-1865	59	5	83.93(3	83.93(3	NUM
eurjchem-1865	59	6	)	)	PUNCT
eurjchem-1865	59	7	°	°	PROPN
eurjchem-1865	59	8	,	,	PUNCT
eurjchem-1865	59	9	β	β	X
eurjchem-1865	59	10	=	=	SYM
eurjchem-1865	59	11	88.18(3	88.18(3	NUM
eurjchem-1865	59	12	)	)	PUNCT
eurjchem-1865	59	13	°	°	PROPN
eurjchem-1865	59	14	,	,	PUNCT
eurjchem-1865	59	15	γ	γ	NOUN
eurjchem-1865	59	16	=	=	SYM
eurjchem-1865	59	17	65.24(3	65.24(3	NOUN
eurjchem-1865	59	18	)	)	PUNCT
eurjchem-1865	59	19	°	°	NOUN
eurjchem-1865	59	20	,	,	PUNCT
eurjchem-1865	59	21	v	v	NOUN
eurjchem-1865	59	22	=	=	SYM
eurjchem-1865	59	23	1797.6(6	1797.6(6	NUM
eurjchem-1865	59	24	)	)	PUNCT
eurjchem-1865	59	25	å3	å3	PROPN
eurjchem-1865	59	26	,	,	PUNCT
eurjchem-1865	59	27	t	t	NOUN
eurjchem-1865	59	28	=	=	SYM
eurjchem-1865	59	29	294(2	294(2	NUM
eurjchem-1865	59	30	)	)	PUNCT
eurjchem-1865	59	31	k	k	NOUN
eurjchem-1865	59	32	,	,	PUNCT
eurjchem-1865	59	33	space	space	NOUN
eurjchem-1865	59	34	group	group	NOUN
eurjchem-1865	59	35	p-1	p-1	NOUN
eurjchem-1865	59	36	(	(	PUNCT
eurjchem-1865	59	37	no	no	INTJ
eurjchem-1865	59	38	.	.	NOUN
eurjchem-1865	59	39	2	2	NUM
eurjchem-1865	59	40	)	)	PUNCT
eurjchem-1865	59	41	,	,	PUNCT
eurjchem-1865	59	42	z	z	NOUN
eurjchem-1865	59	43	=	=	SYM
eurjchem-1865	59	44	2	2	NUM
eurjchem-1865	59	45	,	,	PUNCT
eurjchem-1865	59	46	μ	μ	NOUN
eurjchem-1865	59	47	=	=	SYM
eurjchem-1865	59	48	(	(	PUNCT
eurjchem-1865	59	49	mokα	mokα	PROPN
eurjchem-1865	59	50	)	)	PUNCT
eurjchem-1865	59	51	0.781	0.781	NUM
eurjchem-1865	59	52	mm-1	mm-1	SYM
eurjchem-1865	59	53	.	.	PROPN
eurjchem-1865	59	54	22744	22744	NUM
eurjchem-1865	59	55	reflections	reflection	NOUN
eurjchem-1865	59	56	(	(	PUNCT
eurjchem-1865	59	57	11837	11837	NUM
eurjchem-1865	59	58	unique	unique	ADJ
eurjchem-1865	59	59	;	;	PUNCT
eurjchem-1865	59	60	rint	rint	NOUN
eurjchem-1865	59	61	=	=	NOUN
eurjchem-1865	59	62	0.012	0.012	NUM
eurjchem-1865	59	63	)	)	PUNCT
eurjchem-1865	59	64	were	be	AUX
eurjchem-1865	59	65	collected	collect	VERB
eurjchem-1865	59	66	at	at	ADP
eurjchem-1865	59	67	room	room	NOUN
eurjchem-1865	59	68	temperature	temperature	NOUN
eurjchem-1865	59	69	in	in	ADP
eurjchem-1865	59	70	the	the	DET
eurjchem-1865	59	71	range	range	NOUN
eurjchem-1865	59	72	4.38	4.38	NUM
eurjchem-1865	59	73	°	°	NOUN
eurjchem-1865	59	74	<	<	X
eurjchem-1865	59	75	2θ	2θ	NUM
eurjchem-1865	59	76	<	<	X
eurjchem-1865	59	77	63.96	63.96	NUM
eurjchem-1865	59	78	°	°	NOUN
eurjchem-1865	59	79	,	,	PUNCT
eurjchem-1865	59	80	employing	employ	VERB
eurjchem-1865	59	81	a	a	DET
eurjchem-1865	59	82	0.08	0.08	NUM
eurjchem-1865	59	83	×	×	NOUN
eurjchem-1865	59	84	0.05	0.05	NUM
eurjchem-1865	59	85	×	×	NOUN
eurjchem-1865	59	86	0.02	0.02	NUM
eurjchem-1865	59	87	mm	mm	NOUN
eurjchem-1865	59	88	crystal	crystal	NOUN
eurjchem-1865	59	89	mounted	mount	VERB
eurjchem-1865	59	90	on	on	ADP
eurjchem-1865	59	91	a	a	DET
eurjchem-1865	59	92	bruker	bruker	PROPN
eurjchem-1865	59	93	apex	apex	PROPN
eurjchem-1865	59	94	ii	ii	PROPN
eurjchem-1865	59	95	ccd	ccd	PROPN
eurjchem-1865	59	96	diffractometer	diffractometer	NOUN
eurjchem-1865	59	97	and	and	CCONJ
eurjchem-1865	59	98	using	use	VERB
eurjchem-1865	59	99	graphite	graphite	NOUN
eurjchem-1865	59	100	-	-	PUNCT
eurjchem-1865	59	101	monochromatized	monochromatize	VERB
eurjchem-1865	59	102	mo	mo	PROPN
eurjchem-1865	59	103	-	-	ADJ
eurjchem-1865	59	104	kα	kα	ADJ
eurjchem-1865	59	105	radiation	radiation	NOUN
eurjchem-1865	59	106	(	(	PUNCT
eurjchem-1865	59	107	λ	λ	X
eurjchem-1865	59	108	=	=	SYM
eurjchem-1865	59	109	0.71073	0.71073	NUM
eurjchem-1865	59	110	å	å	NOUN
eurjchem-1865	59	111	)	)	PUNCT
eurjchem-1865	59	112	.	.	PUNCT
eurjchem-1865	60	1	datasets	dataset	NOUN
eurjchem-1865	60	2	were	be	AUX
eurjchem-1865	60	3	corrected	correct	VERB
eurjchem-1865	60	4	for	for	ADP
eurjchem-1865	60	5	lorentz	lorentz	PROPN
eurjchem-1865	60	6	polarization	polarization	NOUN
eurjchem-1865	60	7	effects	effect	NOUN
eurjchem-1865	60	8	and	and	CCONJ
eurjchem-1865	60	9	for	for	ADP
eurjchem-1865	60	10	absorption	absorption	NOUN
eurjchem-1865	60	11	(	(	PUNCT
eurjchem-1865	60	12	sadabs	sadab	NOUN
eurjchem-1865	60	13	)	)	PUNCT
eurjchem-1865	61	1	[	[	X
eurjchem-1865	61	2	32	32	NUM
eurjchem-1865	61	3	]	]	PUNCT
eurjchem-1865	61	4	.	.	PUNCT
eurjchem-1865	62	1	the	the	DET
eurjchem-1865	62	2	structure	structure	NOUN
eurjchem-1865	62	3	was	be	AUX
eurjchem-1865	62	4	resolved	resolve	VERB
eurjchem-1865	62	5	by	by	ADP
eurjchem-1865	62	6	direct	direct	ADJ
eurjchem-1865	62	7	methods	method	NOUN
eurjchem-1865	62	8	(	(	PUNCT
eurjchem-1865	62	9	sir-97	sir-97	PROPN
eurjchem-1865	62	10	)	)	PUNCT
eurjchem-1865	63	1	[	[	X
eurjchem-1865	63	2	33	33	NUM
eurjchem-1865	63	3	]	]	PUNCT
eurjchem-1865	63	4	and	and	CCONJ
eurjchem-1865	63	5	was	be	AUX
eurjchem-1865	63	6	completed	complete	VERB
eurjchem-1865	63	7	by	by	ADP
eurjchem-1865	63	8	iterative	iterative	ADJ
eurjchem-1865	63	9	cycles	cycle	NOUN
eurjchem-1865	63	10	of	of	ADP
eurjchem-1865	63	11	full	full	ADJ
eurjchem-1865	63	12	-	-	PUNCT
eurjchem-1865	63	13	matrix	matrix	NOUN
eurjchem-1865	63	14	least	least	ADJ
eurjchem-1865	63	15	squares	square	NOUN
eurjchem-1865	63	16	refinement	refinement	NOUN
eurjchem-1865	63	17	on	on	ADP
eurjchem-1865	63	18	fo2	fo2	NOUN
eurjchem-1865	63	19	and	and	CCONJ
eurjchem-1865	63	20	δf	δf	VERB
eurjchem-1865	63	21	synthesis	synthesis	NOUN
eurjchem-1865	63	22	using	use	VERB
eurjchem-1865	63	23	the	the	DET
eurjchem-1865	63	24	shelxl-2017	shelxl-2017	NOUN
eurjchem-1865	63	25	[	[	X
eurjchem-1865	63	26	34	34	NUM
eurjchem-1865	63	27	]	]	X
eurjchem-1865	63	28	program	program	NOUN
eurjchem-1865	63	29	(	(	PUNCT
eurjchem-1865	63	30	wingx	wingx	NOUN
eurjchem-1865	63	31	suite	suite	PROPN
eurjchem-1865	63	32	)	)	PUNCT
eurjchem-1865	64	1	[	[	X
eurjchem-1865	64	2	35	35	NUM
eurjchem-1865	64	3	]	]	PUNCT
eurjchem-1865	64	4	.	.	PUNCT
eurjchem-1865	65	1	hydrogen	hydrogen	NOUN
eurjchem-1865	65	2	atoms	atom	NOUN
eurjchem-1865	65	3	located	locate	VERB
eurjchem-1865	65	4	on	on	ADP
eurjchem-1865	65	5	the	the	DET
eurjchem-1865	65	6	δf	δf	PROPN
eurjchem-1865	65	7	maps	map	NOUN
eurjchem-1865	65	8	were	be	AUX
eurjchem-1865	65	9	allowed	allow	VERB
eurjchem-1865	65	10	to	to	PART
eurjchem-1865	65	11	ride	ride	VERB
eurjchem-1865	65	12	.	.	PUNCT
eurjchem-1865	66	1	final	final	ADJ
eurjchem-1865	66	2	r1	r1	PROPN
eurjchem-1865	66	3	[	[	X
eurjchem-1865	66	4	wr2	wr2	X
eurjchem-1865	66	5	]	]	X
eurjchem-1865	66	6	values	value	NOUN
eurjchem-1865	66	7	are	be	AUX
eurjchem-1865	66	8	0.0360	0.0360	NUM
eurjchem-1865	67	1	[	[	X
eurjchem-1865	67	2	0.1088	0.1088	NUM
eurjchem-1865	67	3	]	]	X
eurjchem-1865	67	4	on	on	ADP
eurjchem-1865	67	5	i	i	PRON
eurjchem-1865	67	6	>	>	X
eurjchem-1865	67	7	2σ(i	2σ(i	NUM
eurjchem-1865	67	8	)	)	PUNCT
eurjchem-1865	68	1	[	[	X
eurjchem-1865	68	2	all	all	DET
eurjchem-1865	68	3	data	datum	NOUN
eurjchem-1865	68	4	]	]	PUNCT
eurjchem-1865	68	5	.	.	PUNCT
eurjchem-1865	69	1	3	3	X
eurjchem-1865	69	2	.	.	NOUN
eurjchem-1865	69	3	results	result	NOUN
eurjchem-1865	69	4	and	and	CCONJ
eurjchem-1865	69	5	discussion	discussion	NOUN
eurjchem-1865	69	6	carbon	carbon	NOUN
eurjchem-1865	69	7	monoxide	monoxide	NOUN
eurjchem-1865	69	8	is	be	AUX
eurjchem-1865	69	9	one	one	NUM
eurjchem-1865	69	10	on	on	ADP
eurjchem-1865	69	11	the	the	DET
eurjchem-1865	69	12	most	most	ADV
eurjchem-1865	69	13	common	common	ADJ
eurjchem-1865	69	14	ligand	ligand	NOUN
eurjchem-1865	69	15	for	for	ADP
eurjchem-1865	69	16	transition	transition	NOUN
eurjchem-1865	69	17	metals	metal	NOUN
eurjchem-1865	69	18	;	;	PUNCT
eurjchem-1865	69	19	the	the	DET
eurjchem-1865	69	20	metal	metal	NOUN
eurjchem-1865	69	21	carbonyl	carbonyl	NOUN
eurjchem-1865	69	22	complexes	complex	NOUN
eurjchem-1865	69	23	found	find	VERB
eurjchem-1865	69	24	application	application	NOUN
eurjchem-1865	69	25	as	as	ADP
eurjchem-1865	69	26	catalyst	catalyst	NOUN
eurjchem-1865	69	27	,	,	PUNCT
eurjchem-1865	69	28	pre	pre	ADJ
eurjchem-1865	69	29	-	-	NOUN
eurjchem-1865	69	30	catalyst	catalyst	ADJ
eurjchem-1865	69	31	or	or	CCONJ
eurjchem-1865	69	32	stoichiometric	stoichiometric	ADJ
eurjchem-1865	69	33	reagent	reagent	NOUN
eurjchem-1865	69	34	in	in	ADP
eurjchem-1865	69	35	different	different	ADJ
eurjchem-1865	69	36	kind	kind	NOUN
eurjchem-1865	69	37	of	of	ADP
eurjchem-1865	69	38	reactions	reaction	NOUN
eurjchem-1865	69	39	.	.	PUNCT
eurjchem-1865	70	1	infra	infra	NOUN
eurjchem-1865	70	2	-	-	PUNCT
eurjchem-1865	70	3	red	red	ADJ
eurjchem-1865	70	4	spectroscopy	spectroscopy	NOUN
eurjchem-1865	70	5	is	be	AUX
eurjchem-1865	70	6	known	know	VERB
eurjchem-1865	70	7	to	to	PART
eurjchem-1865	70	8	be	be	AUX
eurjchem-1865	70	9	a	a	DET
eurjchem-1865	70	10	well	well	ADV
eurjchem-1865	70	11	-	-	PUNCT
eurjchem-1865	70	12	established	establish	VERB
eurjchem-1865	70	13	technique	technique	NOUN
eurjchem-1865	70	14	to	to	PART
eurjchem-1865	70	15	study	study	VERB
eurjchem-1865	70	16	carbonyl	carbonyl	NOUN
eurjchem-1865	70	17	complexes	complex	NOUN
eurjchem-1865	70	18	and	and	CCONJ
eurjchem-1865	70	19	their	their	PRON
eurjchem-1865	70	20	electronic	electronic	ADJ
eurjchem-1865	70	21	properties	property	NOUN
eurjchem-1865	70	22	.	.	PUNCT
eurjchem-1865	71	1	in	in	ADP
eurjchem-1865	71	2	mononuclear	mononuclear	ADJ
eurjchem-1865	71	3	carbonyl	carbonyl	NOUN
eurjchem-1865	71	4	complexes	complex	NOUN
eurjchem-1865	71	5	,	,	PUNCT
eurjchem-1865	71	6	the	the	DET
eurjchem-1865	71	7	co	co	NOUN
eurjchem-1865	71	8	stretching	stretch	VERB
eurjchem-1865	71	9	band	band	NOUN
eurjchem-1865	71	10	lies	lie	VERB
eurjchem-1865	71	11	in	in	ADP
eurjchem-1865	71	12	the	the	DET
eurjchem-1865	71	13	range	range	NOUN
eurjchem-1865	71	14	of	of	ADP
eurjchem-1865	71	15	21251850	21251850	NUM
eurjchem-1865	71	16	cm-1	cm-1	NOUN
eurjchem-1865	71	17	,	,	PUNCT
eurjchem-1865	71	18	a	a	DET
eurjchem-1865	71	19	region	region	NOUN
eurjchem-1865	71	20	of	of	ADP
eurjchem-1865	71	21	the	the	DET
eurjchem-1865	71	22	ir	ir	PROPN
eurjchem-1865	71	23	spectrum	spectrum	NOUN
eurjchem-1865	71	24	commonly	commonly	ADV
eurjchem-1865	71	25	devoid	devoid	ADJ
eurjchem-1865	71	26	of	of	ADP
eurjchem-1865	71	27	other	other	ADJ
eurjchem-1865	71	28	signals	signal	NOUN
eurjchem-1865	71	29	[	[	X
eurjchem-1865	71	30	36	36	NUM
eurjchem-1865	71	31	]	]	PUNCT
eurjchem-1865	71	32	.	.	PUNCT
eurjchem-1865	72	1	the	the	DET
eurjchem-1865	72	2	stretching	stretch	VERB
eurjchem-1865	72	3	frequency	frequency	NOUN
eurjchem-1865	72	4	value	value	NOUN
eurjchem-1865	72	5	originates	originate	NOUN
eurjchem-1865	72	6	from	from	ADP
eurjchem-1865	72	7	a	a	DET
eurjchem-1865	72	8	tight	tight	ADJ
eurjchem-1865	72	9	interaction	interaction	NOUN
eurjchem-1865	72	10	between	between	ADP
eurjchem-1865	72	11	the	the	DET
eurjchem-1865	72	12	metal	metal	NOUN
eurjchem-1865	72	13	orbitals	orbital	NOUN
eurjchem-1865	72	14	and	and	CCONJ
eurjchem-1865	72	15	the	the	DET
eurjchem-1865	72	16	carbonyl	carbonyl	NOUN
eurjchem-1865	72	17	ones	one	NOUN
eurjchem-1865	72	18	and	and	CCONJ
eurjchem-1865	72	19	it	it	PRON
eurjchem-1865	72	20	is	be	AUX
eurjchem-1865	72	21	highly	highly	ADV
eurjchem-1865	72	22	affected	affect	VERB
eurjchem-1865	72	23	by	by	ADP
eurjchem-1865	72	24	the	the	DET
eurjchem-1865	72	25	nature	nature	NOUN
eurjchem-1865	72	26	of	of	ADP
eurjchem-1865	72	27	metals	metal	NOUN
eurjchem-1865	72	28	and	and	CCONJ
eurjchem-1865	72	29	their	their	PRON
eurjchem-1865	72	30	substituents	substituent	NOUN
eurjchem-1865	72	31	.	.	PUNCT
eurjchem-1865	73	1	the	the	DET
eurjchem-1865	73	2	ir	ir	PROPN
eurjchem-1865	73	3	spectrum	spectrum	NOUN
eurjchem-1865	73	4	of	of	ADP
eurjchem-1865	73	5	the	the	DET
eurjchem-1865	73	6	[	[	X
eurjchem-1865	73	7	ni(co)2	ni(co)2	NOUN
eurjchem-1865	73	8	(	(	PUNCT
eurjchem-1865	73	9	bitianp	bitianp	NOUN
eurjchem-1865	73	10	)	)	PUNCT
eurjchem-1865	73	11	]	]	PUNCT
eurjchem-1865	74	1	complex	complex	NOUN
eurjchem-1865	74	2	in	in	ADP
eurjchem-1865	74	3	chcl3	chcl3	PROPN
eurjchem-1865	74	4	revealed	reveal	VERB
eurjchem-1865	74	5	the	the	DET
eurjchem-1865	74	6	two	two	NUM
eurjchem-1865	74	7	signals	signal	NOUN
eurjchem-1865	74	8	of	of	ADP
eurjchem-1865	74	9	νco	νco	NOUN
eurjchem-1865	74	10	at	at	ADP
eurjchem-1865	74	11	2007	2007	NUM
eurjchem-1865	74	12	and	and	CCONJ
eurjchem-1865	74	13	1947	1947	NUM
eurjchem-1865	74	14	cm-1	cm-1	VERB
eurjchem-1865	74	15	the	the	DET
eurjchem-1865	74	16	symmetric	symmetric	ADJ
eurjchem-1865	74	17	and	and	CCONJ
eurjchem-1865	74	18	anti	anti	ADJ
eurjchem-1865	74	19	-	-	ADJ
eurjchem-1865	74	20	symmetric	symmetric	ADJ
eurjchem-1865	74	21	,	,	PUNCT
eurjchem-1865	74	22	respectively	respectively	ADV
eurjchem-1865	74	23	(	(	PUNCT
eurjchem-1865	74	24	figure	figure	NOUN
eurjchem-1865	74	25	1	1	NUM
eurjchem-1865	74	26	)	)	PUNCT
eurjchem-1865	74	27	.	.	PUNCT
eurjchem-1865	75	1	2019	2019	NUM
eurjchem-1865	75	2	–	–	PUNCT
eurjchem-1865	75	3	european	european	ADJ
eurjchem-1865	75	4	journal	journal	NOUN
eurjchem-1865	75	5	of	of	ADP
eurjchem-1865	75	6	chemistry	chemistry	NOUN
eurjchem-1865	75	7	–	–	PUNCT
eurjchem-1865	75	8	cc	cc	NOUN
eurjchem-1865	75	9	by	by	ADP
eurjchem-1865	75	10	nc	nc	PROPN
eurjchem-1865	75	11	–	–	PUNCT
eurjchem-1865	75	12	doi	doi	NOUN
eurjchem-1865	75	13	:	:	PUNCT
eurjchem-1865	75	14	10.5155	10.5155	NUM
eurjchem-1865	75	15	/	/	SYM
eurjchem-1865	75	16	eurjchem.10.2.171	eurjchem.10.2.171	PRON
eurjchem-1865	75	17	-	-	PUNCT
eurjchem-1865	75	18	174.1865	174.1865	NUM
eurjchem-1865	75	19	fusè	fusè	NOUN
eurjchem-1865	75	20	et	et	PROPN
eurjchem-1865	75	21	al	al	PROPN
eurjchem-1865	75	22	.	.	PUNCT
eurjchem-1865	75	23	/	/	SYM
eurjchem-1865	75	24	european	european	PROPN
eurjchem-1865	75	25	journal	journal	PROPN
eurjchem-1865	75	26	of	of	ADP
eurjchem-1865	75	27	chemistry	chemistry	NOUN
eurjchem-1865	75	28	10	10	NUM
eurjchem-1865	75	29	(	(	PUNCT
eurjchem-1865	75	30	2	2	NUM
eurjchem-1865	75	31	)	)	PUNCT
eurjchem-1865	75	32	(	(	PUNCT
eurjchem-1865	75	33	2019	2019	NUM
eurjchem-1865	75	34	)	)	PUNCT
eurjchem-1865	75	35	171	171	NUM
eurjchem-1865	75	36	-	-	SYM
eurjchem-1865	75	37	174	174	NUM
eurjchem-1865	75	38	173	173	NUM
eurjchem-1865	75	39	figure	figure	NOUN
eurjchem-1865	75	40	2	2	NUM
eurjchem-1865	75	41	.	.	PUNCT
eurjchem-1865	76	1	ortep	ortep	NOUN
eurjchem-1865	77	1	[	[	X
eurjchem-1865	77	2	35	35	NUM
eurjchem-1865	77	3	]	]	X
eurjchem-1865	77	4	drawing	drawing	NOUN
eurjchem-1865	77	5	of	of	ADP
eurjchem-1865	77	6	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	77	7	)	)	PUNCT
eurjchem-1865	77	8	with	with	ADP
eurjchem-1865	77	9	the	the	DET
eurjchem-1865	77	10	arbitrary	arbitrary	ADJ
eurjchem-1865	77	11	atom	atom	NOUN
eurjchem-1865	77	12	numbering	numbering	NOUN
eurjchem-1865	77	13	(	(	PUNCT
eurjchem-1865	77	14	ellipsoids	ellipsoid	NOUN
eurjchem-1865	77	15	are	be	AUX
eurjchem-1865	77	16	at	at	ADP
eurjchem-1865	77	17	40	40	NUM
eurjchem-1865	77	18	%	%	NOUN
eurjchem-1865	77	19	probability	probability	NOUN
eurjchem-1865	77	20	)	)	PUNCT
eurjchem-1865	77	21	.	.	PUNCT
eurjchem-1865	78	1	selected	select	VERB
eurjchem-1865	78	2	interatomic	interatomic	ADJ
eurjchem-1865	78	3	distances	distance	NOUN
eurjchem-1865	78	4	(	(	PUNCT
eurjchem-1865	78	5	å	å	NOUN
eurjchem-1865	78	6	)	)	PUNCT
eurjchem-1865	78	7	and	and	CCONJ
eurjchem-1865	78	8	bond	bond	NOUN
eurjchem-1865	78	9	angles	angle	NOUN
eurjchem-1865	78	10	are	be	AUX
eurjchem-1865	78	11	(	(	PUNCT
eurjchem-1865	78	12	°	°	PROPN
eurjchem-1865	78	13	):	):	PUNCT
eurjchem-1865	78	14	ni	ni	PROPN
eurjchem-1865	78	15	-	-	PROPN
eurjchem-1865	78	16	p1	p1	PROPN
eurjchem-1865	78	17	2.216(9	2.216(9	NUM
eurjchem-1865	78	18	)	)	PUNCT
eurjchem-1865	78	19	,	,	PUNCT
eurjchem-1865	78	20	ni	ni	PROPN
eurjchem-1865	78	21	-	-	PUNCT
eurjchem-1865	78	22	p2	p2	PROPN
eurjchem-1865	78	23	2.196(8	2.196(8	NOUN
eurjchem-1865	78	24	)	)	PUNCT
eurjchem-1865	78	25	,	,	PUNCT
eurjchem-1865	78	26	p1	p1	PROPN
eurjchem-1865	78	27	-	-	PUNCT
eurjchem-1865	78	28	c3	c3	PROPN
eurjchem-1865	78	29	1.826(2	1.826(2	NUM
eurjchem-1865	78	30	)	)	PUNCT
eurjchem-1865	78	31	,	,	PUNCT
eurjchem-1865	78	32	c3	c3	PROPN
eurjchem-1865	78	33	-	-	NOUN
eurjchem-1865	78	34	c4	c4	PROPN
eurjchem-1865	78	35	1.365(2	1.365(2	NUM
eurjchem-1865	78	36	)	)	PUNCT
eurjchem-1865	78	37	,	,	PUNCT
eurjchem-1865	78	38	c4	c4	NOUN
eurjchem-1865	78	39	-	-	PUNCT
eurjchem-1865	78	40	c12	c12	NOUN
eurjchem-1865	78	41	1.480(3	1.480(3	NUM
eurjchem-1865	78	42	)	)	PUNCT
eurjchem-1865	78	43	,	,	PUNCT
eurjchem-1865	78	44	c11	c11	NOUN
eurjchem-1865	78	45	-	-	PUNCT
eurjchem-1865	78	46	c12	c12	NOUN
eurjchem-1865	78	47	1.367(2	1.367(2	NUM
eurjchem-1865	78	48	)	)	PUNCT
eurjchem-1865	78	49	,	,	PUNCT
eurjchem-1865	78	50	p2	p2	NOUN
eurjchem-1865	78	51	-	-	PUNCT
eurjchem-1865	78	52	c11	c11	NOUN
eurjchem-1865	78	53	1.818(2	1.818(2	NUM
eurjchem-1865	78	54	)	)	PUNCT
eurjchem-1865	78	55	,	,	PUNCT
eurjchem-1865	78	56	c3	c3	PROPN
eurjchem-1865	78	57	-	-	PUNCT
eurjchem-1865	78	58	s1	s1	PROPN
eurjchem-1865	78	59	1.744(2	1.744(2	NUM
eurjchem-1865	78	60	)	)	PUNCT
eurjchem-1865	78	61	,	,	PUNCT
eurjchem-1865	78	62	c11	c11	NOUN
eurjchem-1865	78	63	-	-	PUNCT
eurjchem-1865	78	64	s2	s2	NOUN
eurjchem-1865	78	65	1.739(2	1.739(2	NUM
eurjchem-1865	78	66	)	)	PUNCT
eurjchem-1865	78	67	;	;	PUNCT
eurjchem-1865	78	68	c1	c1	PROPN
eurjchem-1865	78	69	-	-	PUNCT
eurjchem-1865	78	70	ni	ni	PROPN
eurjchem-1865	78	71	-	-	PROPN
eurjchem-1865	78	72	c2	c2	PROPN
eurjchem-1865	78	73	114.72(2	114.72(2	NUM
eurjchem-1865	78	74	)	)	PUNCT
eurjchem-1865	78	75	,	,	PUNCT
eurjchem-1865	78	76	p1	p1	PROPN
eurjchem-1865	78	77	-	-	PUNCT
eurjchem-1865	78	78	ni	ni	NOUN
eurjchem-1865	78	79	-	-	PUNCT
eurjchem-1865	78	80	p2	p2	NOUN
eurjchem-1865	78	81	100.86(1	100.86(1	NUM
eurjchem-1865	78	82	)	)	PUNCT
eurjchem-1865	78	83	,	,	PUNCT
eurjchem-1865	78	84	p1	p1	PROPN
eurjchem-1865	78	85	-	-	PUNCT
eurjchem-1865	78	86	ni	ni	PROPN
eurjchem-1865	78	87	-	-	PROPN
eurjchem-1865	78	88	c2	c2	PROPN
eurjchem-1865	78	89	114.26(3	114.26(3	NUM
eurjchem-1865	78	90	)	)	PUNCT
eurjchem-1865	78	91	,	,	PUNCT
eurjchem-1865	78	92	p2	p2	PROPN
eurjchem-1865	78	93	-	-	PUNCT
eurjchem-1865	78	94	ni	ni	NOUN
eurjchem-1865	78	95	-	-	PROPN
eurjchem-1865	78	96	c2	c2	PROPN
eurjchem-1865	78	97	112.87(1	112.87(1	NUM
eurjchem-1865	78	98	)	)	PUNCT
eurjchem-1865	78	99	,	,	PUNCT
eurjchem-1865	78	100	c11	c11	NOUN
eurjchem-1865	78	101	-	-	PUNCT
eurjchem-1865	78	102	p2	p2	NOUN
eurjchem-1865	78	103	-	-	PUNCT
eurjchem-1865	78	104	ni	ni	NOUN
eurjchem-1865	78	105	106.46(1	106.46(1	NUM
eurjchem-1865	78	106	)	)	PUNCT
eurjchem-1865	78	107	,	,	PUNCT
eurjchem-1865	78	108	c3	c3	PROPN
eurjchem-1865	78	109	-	-	PUNCT
eurjchem-1865	78	110	p1	p1	PROPN
eurjchem-1865	78	111	-	-	PROPN
eurjchem-1865	78	112	ni	ni	NOUN
eurjchem-1865	78	113	116.26(3	116.26(3	NUM
eurjchem-1865	78	114	)	)	PUNCT
eurjchem-1865	78	115	(	(	PUNCT
eurjchem-1865	78	116	color	color	NOUN
eurjchem-1865	78	117	online	online	NOUN
eurjchem-1865	78	118	)	)	PUNCT
eurjchem-1865	78	119	.	.	PUNCT
eurjchem-1865	79	1	the	the	DET
eurjchem-1865	79	2	result	result	NOUN
eurjchem-1865	79	3	agreed	agree	VERB
eurjchem-1865	79	4	with	with	ADP
eurjchem-1865	79	5	the	the	DET
eurjchem-1865	79	6	one	one	NOUN
eurjchem-1865	79	7	already	already	ADV
eurjchem-1865	79	8	reported	report	VERB
eurjchem-1865	79	9	for	for	ADP
eurjchem-1865	79	10	this	this	DET
eurjchem-1865	79	11	compound	compound	NOUN
eurjchem-1865	79	12	[	[	X
eurjchem-1865	79	13	26	26	NUM
eurjchem-1865	79	14	]	]	PUNCT
eurjchem-1865	79	15	and	and	CCONJ
eurjchem-1865	79	16	it	it	PRON
eurjchem-1865	79	17	is	be	AUX
eurjchem-1865	79	18	consistent	consistent	ADJ
eurjchem-1865	79	19	with	with	ADP
eurjchem-1865	79	20	solely	solely	ADV
eurjchem-1865	79	21	formation	formation	NOUN
eurjchem-1865	79	22	of	of	ADP
eurjchem-1865	79	23	the	the	DET
eurjchem-1865	79	24	complex	complex	NOUN
eurjchem-1865	79	25	with	with	ADP
eurjchem-1865	79	26	a	a	DET
eurjchem-1865	79	27	tetrahedral	tetrahedral	ADJ
eurjchem-1865	79	28	geometry	geometry	NOUN
eurjchem-1865	79	29	of	of	ADP
eurjchem-1865	79	30	coordination	coordination	NOUN
eurjchem-1865	79	31	.	.	PUNCT
eurjchem-1865	80	1	the	the	DET
eurjchem-1865	80	2	σ	σ	PROPN
eurjchem-1865	80	3	donor	donor	NOUN
eurjchem-1865	80	4	property	property	NOUN
eurjchem-1865	80	5	of	of	ADP
eurjchem-1865	80	6	the	the	DET
eurjchem-1865	80	7	diphosphine	diphosphine	NOUN
eurjchem-1865	80	8	is	be	AUX
eurjchem-1865	80	9	at	at	ADP
eurjchem-1865	80	10	the	the	DET
eurjchem-1865	80	11	origin	origin	NOUN
eurjchem-1865	80	12	of	of	ADP
eurjchem-1865	80	13	the	the	DET
eurjchem-1865	80	14	red	red	ADJ
eurjchem-1865	80	15	shift	shift	NOUN
eurjchem-1865	80	16	of	of	ADP
eurjchem-1865	80	17	the	the	DET
eurjchem-1865	80	18	νco	νco	NOUN
eurjchem-1865	80	19	,	,	PUNCT
eurjchem-1865	80	20	in	in	ADP
eurjchem-1865	80	21	fact	fact	NOUN
eurjchem-1865	80	22	,	,	PUNCT
eurjchem-1865	80	23	in	in	ADP
eurjchem-1865	80	24	carbonyl	carbonyl	NOUN
eurjchem-1865	80	25	ni(0	ni(0	PROPN
eurjchem-1865	80	26	)	)	PUNCT
eurjchem-1865	80	27	complexes	complexe	VERB
eurjchem-1865	80	28	the	the	DET
eurjchem-1865	80	29	tetrahedral	tetrahedral	ADJ
eurjchem-1865	80	30	geometry	geometry	NOUN
eurjchem-1865	80	31	is	be	AUX
eurjchem-1865	80	32	expected	expect	VERB
eurjchem-1865	80	33	to	to	PART
eurjchem-1865	80	34	drive	drive	VERB
eurjchem-1865	80	35	the	the	DET
eurjchem-1865	80	36	charge	charge	NOUN
eurjchem-1865	80	37	flow	flow	NOUN
eurjchem-1865	80	38	from	from	ADP
eurjchem-1865	80	39	the	the	DET
eurjchem-1865	80	40	phosphorus	phosphorus	NOUN
eurjchem-1865	80	41	lone	lone	ADJ
eurjchem-1865	80	42	pairs	pair	NOUN
eurjchem-1865	80	43	to	to	ADP
eurjchem-1865	80	44	the	the	DET
eurjchem-1865	80	45	π	π	PROPN
eurjchem-1865	80	46	*	*	NOUN
eurjchem-1865	80	47	orbitals	orbital	NOUN
eurjchem-1865	80	48	[	[	X
eurjchem-1865	80	49	26	26	NUM
eurjchem-1865	80	50	]	]	PUNCT
eurjchem-1865	80	51	.	.	PUNCT
eurjchem-1865	81	1	the	the	DET
eurjchem-1865	81	2	asymmetric	asymmetric	ADJ
eurjchem-1865	81	3	unit	unit	NOUN
eurjchem-1865	81	4	consists	consist	VERB
eurjchem-1865	81	5	of	of	ADP
eurjchem-1865	81	6	a	a	DET
eurjchem-1865	81	7	dicarbonyl	dicarbonyl	NOUN
eurjchem-1865	81	8	ni(0	ni(0	NOUN
eurjchem-1865	81	9	)	)	PUNCT
eurjchem-1865	81	10	complex	complex	NOUN
eurjchem-1865	81	11	where	where	SCONJ
eurjchem-1865	81	12	the	the	DET
eurjchem-1865	81	13	nickel	nickel	NOUN
eurjchem-1865	81	14	atom	atom	NOUN
eurjchem-1865	81	15	results	result	NOUN
eurjchem-1865	81	16	to	to	PART
eurjchem-1865	81	17	be	be	AUX
eurjchem-1865	81	18	tetracoordinated	tetracoordinate	VERB
eurjchem-1865	81	19	by	by	ADP
eurjchem-1865	81	20	two	two	NUM
eurjchem-1865	81	21	carbonyls	carbonyls	NOUN
eurjchem-1865	81	22	and	and	CCONJ
eurjchem-1865	81	23	two	two	NUM
eurjchem-1865	81	24	diphenylphosphines	diphenylphosphine	NOUN
eurjchem-1865	81	25	.	.	PUNCT
eurjchem-1865	82	1	each	each	PRON
eurjchem-1865	82	2	of	of	ADP
eurjchem-1865	82	3	the	the	DET
eurjchem-1865	82	4	two	two	NUM
eurjchem-1865	82	5	diphenylphosphines	diphenylphosphine	NOUN
eurjchem-1865	82	6	is	be	AUX
eurjchem-1865	82	7	in	in	ADP
eurjchem-1865	82	8	turn	turn	NOUN
eurjchem-1865	82	9	linked	link	VERB
eurjchem-1865	82	10	to	to	ADP
eurjchem-1865	82	11	the	the	DET
eurjchem-1865	82	12	corresponding	corresponding	ADJ
eurjchem-1865	82	13	bibenzo[b]thiophene	bibenzo[b]thiophene	PROPN
eurjchem-1865	82	14	.	.	PUNCT
eurjchem-1865	83	1	selected	select	VERB
eurjchem-1865	83	2	interatomic	interatomic	ADJ
eurjchem-1865	83	3	distances	distance	NOUN
eurjchem-1865	83	4	and	and	CCONJ
eurjchem-1865	83	5	bond	bond	NOUN
eurjchem-1865	83	6	angles	angle	NOUN
eurjchem-1865	83	7	are	be	AUX
eurjchem-1865	83	8	reported	report	VERB
eurjchem-1865	83	9	in	in	ADP
eurjchem-1865	83	10	the	the	DET
eurjchem-1865	83	11	caption	caption	NOUN
eurjchem-1865	83	12	of	of	ADP
eurjchem-1865	83	13	figure	figure	NOUN
eurjchem-1865	83	14	2	2	NUM
eurjchem-1865	84	1	[	[	X
eurjchem-1865	84	2	37	37	NUM
eurjchem-1865	84	3	]	]	PUNCT
eurjchem-1865	84	4	.	.	PUNCT
eurjchem-1865	85	1	the	the	DET
eurjchem-1865	85	2	coordination	coordination	NOUN
eurjchem-1865	85	3	sphere	sphere	NOUN
eurjchem-1865	85	4	of	of	ADP
eurjchem-1865	85	5	the	the	DET
eurjchem-1865	85	6	ni	ni	PROPN
eurjchem-1865	85	7	center	center	NOUN
eurjchem-1865	85	8	is	be	AUX
eurjchem-1865	85	9	best	well	ADV
eurjchem-1865	85	10	described	describe	VERB
eurjchem-1865	85	11	as	as	ADP
eurjchem-1865	85	12	tetrahedral	tetrahedral	ADJ
eurjchem-1865	85	13	.	.	PUNCT
eurjchem-1865	86	1	in	in	ADP
eurjchem-1865	86	2	fact	fact	NOUN
eurjchem-1865	86	3	,	,	PUNCT
eurjchem-1865	86	4	the	the	DET
eurjchem-1865	86	5	okuniewski	okuniewski	ADJ
eurjchem-1865	86	6	parameter	parameter	NOUN
eurjchem-1865	86	7	[	[	X
eurjchem-1865	86	8	38	38	NUM
eurjchem-1865	86	9	]	]	SYM
eurjchem-1865	86	10	'	'	PUNCT
eurjchem-1865	86	11	4	4	NUM
eurjchem-1865	86	12	180	180	NUM
eurjchem-1865	86	13	360	360	NUM
eurjchem-1865	86	14	180	180	NUM
eurjchem-1865	86	15	β	β	X
eurjchem-1865	86	16	α	α	X
eurjchem-1865	86	17	βτ	βτ	NOUN
eurjchem-1865	86	18	α	α	NOUN
eurjchem-1865	86	19	θ	θ	NOUN
eurjchem-1865	86	20	−	−	PROPN
eurjchem-1865	86	21	°	°	NUM
eurjchem-1865	86	22	−	−	NOUN
eurjchem-1865	86	23	=	=	SYM
eurjchem-1865	86	24	+	+	NUM
eurjchem-1865	86	25	°	°	PROPN
eurjchem-1865	86	26	−	−	NOUN
eurjchem-1865	86	27	°	°	NOUN
eurjchem-1865	86	28	−	−	NOUN
eurjchem-1865	86	29	,	,	PUNCT
eurjchem-1865	86	30	where	where	SCONJ
eurjchem-1865	86	31	β	β	X
eurjchem-1865	86	32	>	>	X
eurjchem-1865	86	33	α	α	PROPN
eurjchem-1865	86	34	are	be	AUX
eurjchem-1865	86	35	the	the	DET
eurjchem-1865	86	36	two	two	NUM
eurjchem-1865	86	37	largest	large	ADJ
eurjchem-1865	86	38	angles	angle	NOUN
eurjchem-1865	86	39	around	around	ADP
eurjchem-1865	86	40	the	the	DET
eurjchem-1865	86	41	metal	metal	NOUN
eurjchem-1865	86	42	coordination	coordination	NOUN
eurjchem-1865	86	43	center	center	NOUN
eurjchem-1865	86	44	and	and	CCONJ
eurjchem-1865	86	45	θ	θ	PROPN
eurjchem-1865	86	46	is	be	AUX
eurjchem-1865	86	47	the	the	DET
eurjchem-1865	86	48	tetrahedral	tetrahedral	ADJ
eurjchem-1865	86	49	angle	angle	NOUN
eurjchem-1865	86	50	(	(	PUNCT
eurjchem-1865	86	51	109.5	109.5	NUM
eurjchem-1865	86	52	°	°	NUM
eurjchem-1865	86	53	)	)	PUNCT
eurjchem-1865	86	54	,	,	PUNCT
eurjchem-1865	86	55	is	be	AUX
eurjchem-1865	86	56	a	a	DET
eurjchem-1865	86	57	structural	structural	ADJ
eurjchem-1865	86	58	index	index	NOUN
eurjchem-1865	86	59	to	to	PART
eurjchem-1865	86	60	distinguish	distinguish	VERB
eurjchem-1865	86	61	whether	whether	SCONJ
eurjchem-1865	86	62	the	the	DET
eurjchem-1865	86	63	geometry	geometry	NOUN
eurjchem-1865	86	64	of	of	ADP
eurjchem-1865	86	65	the	the	DET
eurjchem-1865	86	66	coordination	coordination	NOUN
eurjchem-1865	86	67	center	center	NOUN
eurjchem-1865	86	68	is	be	AUX
eurjchem-1865	86	69	square	square	ADJ
eurjchem-1865	86	70	planar	planar	ADJ
eurjchem-1865	86	71	(	(	PUNCT
eurjchem-1865	86	72	τ	τ	X
eurjchem-1865	86	73	=	=	SYM
eurjchem-1865	86	74	0	0	NUM
eurjchem-1865	86	75	)	)	PUNCT
eurjchem-1865	86	76	or	or	CCONJ
eurjchem-1865	86	77	tetrahedral	tetrahedral	ADJ
eurjchem-1865	86	78	(	(	PUNCT
eurjchem-1865	86	79	τ	τ	X
eurjchem-1865	86	80	=	=	SYM
eurjchem-1865	86	81	1	1	NUM
eurjchem-1865	86	82	)	)	PUNCT
eurjchem-1865	86	83	.	.	PUNCT
eurjchem-1865	87	1	in	in	ADP
eurjchem-1865	87	2	the	the	DET
eurjchem-1865	87	3	present	present	ADJ
eurjchem-1865	87	4	case	case	NOUN
eurjchem-1865	87	5	,	,	PUNCT
eurjchem-1865	87	6	β	β	X
eurjchem-1865	87	7	is	be	AUX
eurjchem-1865	87	8	114.26	114.26	NUM
eurjchem-1865	87	9	°	°	NOUN
eurjchem-1865	87	10	and	and	CCONJ
eurjchem-1865	87	11	α	α	DET
eurjchem-1865	87	12	112.87	112.87	NUM
eurjchem-1865	87	13	°	°	NOUN
eurjchem-1865	87	14	determining	determine	VERB
eurjchem-1865	87	15	a	a	DET
eurjchem-1865	87	16	value	value	NOUN
eurjchem-1865	87	17	of	of	ADP
eurjchem-1865	87	18	τ4	τ4	NOUN
eurjchem-1865	87	19	`	`	PUNCT
eurjchem-1865	87	20	=	=	PUNCT
eurjchem-1865	87	21	0.9353	0.9353	NUM
eurjchem-1865	87	22	indicative	indicative	ADJ
eurjchem-1865	87	23	of	of	ADP
eurjchem-1865	87	24	an	an	DET
eurjchem-1865	87	25	almost	almost	ADV
eurjchem-1865	87	26	tetrahedral	tetrahedral	ADJ
eurjchem-1865	87	27	environment	environment	NOUN
eurjchem-1865	87	28	of	of	ADP
eurjchem-1865	87	29	the	the	DET
eurjchem-1865	87	30	nickel	nickel	NOUN
eurjchem-1865	87	31	atom	atom	NOUN
eurjchem-1865	87	32	.	.	PUNCT
eurjchem-1865	88	1	moreover	moreover	ADV
eurjchem-1865	88	2	,	,	PUNCT
eurjchem-1865	88	3	the	the	DET
eurjchem-1865	88	4	ni	ni	ADJ
eurjchem-1865	88	5	-	-	PUNCT
eurjchem-1865	88	6	p2	p2	PROPN
eurjchem-1865	88	7	ring	ring	NOUN
eurjchem-1865	88	8	displays	display	VERB
eurjchem-1865	88	9	an	an	DET
eurjchem-1865	88	10	envelope	envelope	NOUN
eurjchem-1865	88	11	conformation	conformation	NOUN
eurjchem-1865	88	12	with	with	ADP
eurjchem-1865	88	13	a	a	DET
eurjchem-1865	88	14	deviation	deviation	NOUN
eurjchem-1865	88	15	of	of	ADP
eurjchem-1865	88	16	the	the	DET
eurjchem-1865	88	17	p2	p2	PROPN
eurjchem-1865	88	18	atom	atom	NOUN
eurjchem-1865	88	19	from	from	ADP
eurjchem-1865	88	20	the	the	DET
eurjchem-1865	88	21	mean	mean	ADJ
eurjchem-1865	88	22	plane	plane	NOUN
eurjchem-1865	88	23	defined	define	VERB
eurjchem-1865	88	24	by	by	ADP
eurjchem-1865	88	25	c11	c11	NOUN
eurjchem-1865	88	26	,	,	PUNCT
eurjchem-1865	88	27	c12	c12	PROPN
eurjchem-1865	88	28	,	,	PUNCT
eurjchem-1865	88	29	c4	c4	NOUN
eurjchem-1865	88	30	,	,	PUNCT
eurjchem-1865	88	31	c3	c3	PROPN
eurjchem-1865	88	32	,	,	PUNCT
eurjchem-1865	88	33	p1	p1	PROPN
eurjchem-1865	88	34	and	and	CCONJ
eurjchem-1865	88	35	ni	ni	PROPN
eurjchem-1865	88	36	of	of	ADP
eurjchem-1865	88	37	-0.733	-0.733	PROPN
eurjchem-1865	88	38	å	å	PROPN
eurjchem-1865	88	39	and	and	CCONJ
eurjchem-1865	88	40	the	the	DET
eurjchem-1865	88	41	following	follow	VERB
eurjchem-1865	88	42	torsion	torsion	NOUN
eurjchem-1865	88	43	angles	angle	NOUN
eurjchem-1865	88	44	:	:	PUNCT
eurjchem-1865	88	45	c3	c3	PROPN
eurjchem-1865	88	46	-	-	PUNCT
eurjchem-1865	88	47	p1	p1	PROPN
eurjchem-1865	88	48	-	-	PUNCT
eurjchem-1865	88	49	ni	ni	NOUN
eurjchem-1865	88	50	-	-	NOUN
eurjchem-1865	88	51	p2	p2	PROPN
eurjchem-1865	88	52	7.5	7.5	NUM
eurjchem-1865	88	53	°	°	NUM
eurjchem-1865	88	54	and	and	CCONJ
eurjchem-1865	88	55	c11	c11	NOUN
eurjchem-1865	88	56	-	-	PUNCT
eurjchem-1865	88	57	p2	p2	NOUN
eurjchem-1865	88	58	-	-	PUNCT
eurjchem-1865	88	59	nip1	nip1	PROPN
eurjchem-1865	88	60	55.4	55.4	NUM
eurjchem-1865	88	61	°	°	PROPN
eurjchem-1865	88	62	.	.	PUNCT
eurjchem-1865	89	1	the	the	DET
eurjchem-1865	89	2	molecules	molecule	NOUN
eurjchem-1865	89	3	of	of	ADP
eurjchem-1865	89	4	the	the	DET
eurjchem-1865	89	5	complex	complex	NOUN
eurjchem-1865	89	6	are	be	AUX
eurjchem-1865	89	7	packed	pack	VERB
eurjchem-1865	89	8	with	with	ADP
eurjchem-1865	89	9	no	no	DET
eurjchem-1865	89	10	interactions	interaction	NOUN
eurjchem-1865	89	11	shorter	short	ADJ
eurjchem-1865	89	12	than	than	ADP
eurjchem-1865	89	13	the	the	DET
eurjchem-1865	89	14	sum	sum	NOUN
eurjchem-1865	89	15	of	of	ADP
eurjchem-1865	89	16	the	the	DET
eurjchem-1865	89	17	van	van	PROPN
eurjchem-1865	89	18	der	der	NOUN
eurjchem-1865	89	19	waals	waal	NOUN
eurjchem-1865	89	20	radii	radii	VERB
eurjchem-1865	89	21	.	.	PUNCT
eurjchem-1865	90	1	therefore	therefore	ADV
eurjchem-1865	90	2	,	,	PUNCT
eurjchem-1865	90	3	no	no	DET
eurjchem-1865	90	4	significant	significant	ADJ
eurjchem-1865	90	5	intra	intra	ADJ
eurjchem-1865	90	6	or	or	CCONJ
eurjchem-1865	90	7	intermolecular	intermolecular	ADJ
eurjchem-1865	90	8	hydrogen	hydrogen	NOUN
eurjchem-1865	90	9	bond	bond	NOUN
eurjchem-1865	90	10	deserves	deserve	VERB
eurjchem-1865	90	11	to	to	PART
eurjchem-1865	90	12	be	be	AUX
eurjchem-1865	90	13	reported	report	VERB
eurjchem-1865	90	14	.	.	PUNCT
eurjchem-1865	91	1	however	however	ADV
eurjchem-1865	91	2	,	,	PUNCT
eurjchem-1865	91	3	the	the	DET
eurjchem-1865	91	4	crystal	crystal	NOUN
eurjchem-1865	91	5	structure	structure	NOUN
eurjchem-1865	91	6	indicates	indicate	VERB
eurjchem-1865	91	7	that	that	SCONJ
eurjchem-1865	91	8	the	the	DET
eurjchem-1865	91	9	molecules	molecule	NOUN
eurjchem-1865	91	10	in	in	ADP
eurjchem-1865	91	11	the	the	DET
eurjchem-1865	91	12	crystals	crystal	NOUN
eurjchem-1865	91	13	are	be	AUX
eurjchem-1865	91	14	associated	associate	VERB
eurjchem-1865	91	15	by	by	ADP
eurjchem-1865	91	16	intermolecular	intermolecular	ADJ
eurjchem-1865	91	17	weak	weak	ADJ
eurjchem-1865	91	18	c	c	NOUN
eurjchem-1865	91	19	-	-	PUNCT
eurjchem-1865	91	20	h	h	NOUN
eurjchem-1865	91	21	…	…	NOUN
eurjchem-1865	91	22	o	o	NOUN
eurjchem-1865	91	23	interactions	interaction	NOUN
eurjchem-1865	91	24	,	,	PUNCT
eurjchem-1865	91	25	among	among	ADP
eurjchem-1865	91	26	which	which	PRON
eurjchem-1865	91	27	the	the	DET
eurjchem-1865	91	28	most	most	ADV
eurjchem-1865	91	29	relevant	relevant	ADJ
eurjchem-1865	91	30	one	one	NOUN
eurjchem-1865	91	31	is	be	AUX
eurjchem-1865	91	32	c125	c125	PROPN
eurjchem-1865	91	33	-	-	PUNCT
eurjchem-1865	91	34	h125	h125	PROPN
eurjchem-1865	91	35	…	…	SYM
eurjchem-1865	91	36	o2	o2	PROPN
eurjchem-1865	91	37	3.323(1	3.323(1	NUM
eurjchem-1865	91	38	)	)	PUNCT
eurjchem-1865	91	39	å	å	PROPN
eurjchem-1865	91	40	,	,	PUNCT
eurjchem-1865	91	41	129.29(4)	129.29(4)	NUM
eurjchem-1865	91	42	°	°	PROPN
eurjchem-1865	91	43	.	.	NOUN
eurjchem-1865	91	44	4	4	NUM
eurjchem-1865	91	45	.	.	X
eurjchem-1865	91	46	conclusion	conclusion	VERB
eurjchem-1865	91	47	the	the	DET
eurjchem-1865	91	48	tetrahedral	tetrahedral	ADJ
eurjchem-1865	91	49	environment	environment	NOUN
eurjchem-1865	91	50	instead	instead	ADV
eurjchem-1865	91	51	of	of	ADP
eurjchem-1865	91	52	planar	planar	ADJ
eurjchem-1865	91	53	geometry	geometry	NOUN
eurjchem-1865	91	54	is	be	AUX
eurjchem-1865	91	55	supported	support	VERB
eurjchem-1865	91	56	for	for	ADP
eurjchem-1865	91	57	ni(0	ni(0	PROPN
eurjchem-1865	91	58	)	)	PUNCT
eurjchem-1865	91	59	complex	complex	NOUN
eurjchem-1865	91	60	,	,	PUNCT
eurjchem-1865	91	61	bearing	bear	VERB
eurjchem-1865	91	62	two	two	NUM
eurjchem-1865	91	63	carbonyl	carbonyl	NOUN
eurjchem-1865	91	64	group	group	NOUN
eurjchem-1865	91	65	and	and	CCONJ
eurjchem-1865	91	66	atropoisomeric	atropoisomeric	ADJ
eurjchem-1865	91	67	diphosphine	diphosphine	NOUN
eurjchem-1865	91	68	,	,	PUNCT
eurjchem-1865	91	69	as	as	SCONJ
eurjchem-1865	91	70	demonstrated	demonstrate	VERB
eurjchem-1865	91	71	by	by	ADP
eurjchem-1865	91	72	the	the	DET
eurjchem-1865	91	73	single	single	ADJ
eurjchem-1865	91	74	crystal	crystal	NOUN
eurjchem-1865	91	75	x	x	PROPN
eurjchem-1865	91	76	-	-	NOUN
eurjchem-1865	91	77	ray	ray	NOUN
eurjchem-1865	91	78	diffraction	diffraction	NOUN
eurjchem-1865	91	79	structure	structure	NOUN
eurjchem-1865	91	80	.	.	PUNCT
eurjchem-1865	92	1	in	in	ADP
eurjchem-1865	92	2	the	the	DET
eurjchem-1865	92	3	complex	complex	ADJ
eurjchem-1865	92	4	both	both	DET
eurjchem-1865	92	5	carbonyl	carbonyl	NOUN
eurjchem-1865	92	6	compounds	compound	NOUN
eurjchem-1865	92	7	act	act	VERB
eurjchem-1865	92	8	as	as	ADP
eurjchem-1865	92	9	probe	probe	NOUN
eurjchem-1865	92	10	of	of	ADP
eurjchem-1865	92	11	tolman	tolman	PROPN
eurjchem-1865	92	12	approach	approach	NOUN
eurjchem-1865	92	13	at	at	ADP
eurjchem-1865	92	14	the	the	DET
eurjchem-1865	92	15	metal	metal	NOUN
eurjchem-1865	92	16	center	center	NOUN
eurjchem-1865	92	17	as	as	SCONJ
eurjchem-1865	92	18	evinced	evince	VERB
eurjchem-1865	92	19	by	by	ADP
eurjchem-1865	92	20	ir	ir	PROPN
eurjchem-1865	92	21	spectra	spectra	PROPN
eurjchem-1865	92	22	.	.	PUNCT
eurjchem-1865	93	1	this	this	DET
eurjchem-1865	93	2	interesting	interesting	ADJ
eurjchem-1865	93	3	result	result	NOUN
eurjchem-1865	93	4	increases	increase	VERB
eurjchem-1865	93	5	the	the	DET
eurjchem-1865	93	6	poor	poor	ADJ
eurjchem-1865	93	7	database	database	NOUN
eurjchem-1865	93	8	of	of	ADP
eurjchem-1865	93	9	crystallographic	crystallographic	ADJ
eurjchem-1865	93	10	structures	structure	NOUN
eurjchem-1865	93	11	of	of	ADP
eurjchem-1865	93	12	nickel	nickel	NOUN
eurjchem-1865	93	13	dicarbonyl	dicarbonyl	NOUN
eurjchem-1865	93	14	diphosphine	diphosphine	ADJ
eurjchem-1865	93	15	complexes	complex	NOUN
eurjchem-1865	93	16	and	and	CCONJ
eurjchem-1865	93	17	paves	pave	VERB
eurjchem-1865	93	18	the	the	DET
eurjchem-1865	93	19	base	base	NOUN
eurjchem-1865	93	20	for	for	ADP
eurjchem-1865	93	21	further	further	ADJ
eurjchem-1865	93	22	investigations	investigation	NOUN
eurjchem-1865	93	23	in	in	ADP
eurjchem-1865	93	24	the	the	DET
eurjchem-1865	93	25	structure	structure	NOUN
eurjchem-1865	93	26	determination	determination	NOUN
eurjchem-1865	93	27	of	of	ADP
eurjchem-1865	93	28	carbonyl	carbonyl	NOUN
eurjchem-1865	93	29	complexes	complex	NOUN
eurjchem-1865	93	30	of	of	ADP
eurjchem-1865	93	31	different	different	ADJ
eurjchem-1865	93	32	transition	transition	NOUN
eurjchem-1865	93	33	metal	metal	NOUN
eurjchem-1865	93	34	centers	center	NOUN
eurjchem-1865	93	35	.	.	PUNCT
eurjchem-1865	94	1	supporting	support	VERB
eurjchem-1865	94	2	information	information	NOUN
eurjchem-1865	94	3	ccdc-1536712	ccdc-1536712	NOUN
eurjchem-1865	94	4	contains	contain	VERB
eurjchem-1865	94	5	the	the	DET
eurjchem-1865	94	6	supplementary	supplementary	ADJ
eurjchem-1865	94	7	crystallographic	crystallographic	ADJ
eurjchem-1865	94	8	data	datum	NOUN
eurjchem-1865	94	9	for	for	ADP
eurjchem-1865	94	10	this	this	DET
eurjchem-1865	94	11	paper	paper	NOUN
eurjchem-1865	94	12	.	.	PUNCT
eurjchem-1865	95	1	these	these	DET
eurjchem-1865	95	2	data	datum	NOUN
eurjchem-1865	95	3	can	can	AUX
eurjchem-1865	95	4	be	be	AUX
eurjchem-1865	95	5	obtained	obtain	VERB
eurjchem-1865	95	6	free	free	ADJ
eurjchem-1865	95	7	of	of	ADP
eurjchem-1865	95	8	charge	charge	NOUN
eurjchem-1865	95	9	via	via	ADP
eurjchem-1865	95	10	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	PROPN
eurjchem-1865	95	11	,	,	PUNCT
eurjchem-1865	95	12	or	or	CCONJ
eurjchem-1865	95	13	by	by	ADP
eurjchem-1865	95	14	emailing	email	VERB
eurjchem-1865	95	15	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-1865	95	16	,	,	PUNCT
eurjchem-1865	95	17	or	or	CCONJ
eurjchem-1865	95	18	by	by	ADP
eurjchem-1865	95	19	contacting	contact	VERB
eurjchem-1865	95	20	the	the	DET
eurjchem-1865	95	21	cambridge	cambridge	PROPN
eurjchem-1865	95	22	crystallographic	crystallographic	PROPN
eurjchem-1865	95	23	data	data	PROPN
eurjchem-1865	95	24	centre	centre	NOUN
eurjchem-1865	95	25	,	,	PUNCT
eurjchem-1865	95	26	12	12	NUM
eurjchem-1865	95	27	union	union	NOUN
eurjchem-1865	95	28	road	road	NOUN
eurjchem-1865	95	29	,	,	PUNCT
eurjchem-1865	95	30	cambridge	cambridge	PROPN
eurjchem-1865	95	31	cb2	cb2	PROPN
eurjchem-1865	95	32	1ez	1ez	PROPN
eurjchem-1865	95	33	,	,	PUNCT
eurjchem-1865	95	34	uk	uk	PROPN
eurjchem-1865	95	35	;	;	PUNCT
eurjchem-1865	95	36	fax	fax	NOUN
eurjchem-1865	95	37	:	:	PUNCT
eurjchem-1865	95	38	+44(0)1223	+44(0)1223	PROPN
eurjchem-1865	95	39	-	-	PUNCT
eurjchem-1865	95	40	336033	336033	NUM
eurjchem-1865	95	41	.	.	PUNCT
eurjchem-1865	96	1	electronic	electronic	ADJ
eurjchem-1865	96	2	supplementary	supplementary	ADJ
eurjchem-1865	96	3	information	information	NOUN
eurjchem-1865	96	4	(	(	PUNCT
eurjchem-1865	96	5	esi	esi	NOUN
eurjchem-1865	96	6	)	)	PUNCT
eurjchem-1865	96	7	available	available	ADJ
eurjchem-1865	96	8	:	:	PUNCT
eurjchem-1865	96	9	tables	table	NOUN
eurjchem-1865	96	10	on	on	ADP
eurjchem-1865	96	11	crystallographic	crystallographic	ADJ
eurjchem-1865	96	12	data	datum	NOUN
eurjchem-1865	96	13	and	and	CCONJ
eurjchem-1865	96	14	structure	structure	NOUN
eurjchem-1865	96	15	refinement	refinement	NOUN
eurjchem-1865	96	16	and	and	CCONJ
eurjchem-1865	96	17	crystal	crystal	NOUN
eurjchem-1865	96	18	data	datum	NOUN
eurjchem-1865	96	19	in	in	ADP
eurjchem-1865	96	20	cif	cif	PROPN
eurjchem-1865	96	21	format	format	NOUN
eurjchem-1865	96	22	.	.	PUNCT
eurjchem-1865	97	1	disclosure	disclosure	NOUN
eurjchem-1865	97	2	statement	statement	NOUN
eurjchem-1865	97	3	conflict	conflict	NOUN
eurjchem-1865	97	4	of	of	ADP
eurjchem-1865	97	5	interests	interest	NOUN
eurjchem-1865	97	6	:	:	PUNCT
eurjchem-1865	97	7	the	the	DET
eurjchem-1865	97	8	authors	author	NOUN
eurjchem-1865	97	9	declare	declare	VERB
eurjchem-1865	97	10	that	that	SCONJ
eurjchem-1865	97	11	they	they	PRON
eurjchem-1865	97	12	have	have	VERB
eurjchem-1865	97	13	no	no	DET
eurjchem-1865	97	14	conflict	conflict	NOUN
eurjchem-1865	97	15	of	of	ADP
eurjchem-1865	97	16	interest	interest	NOUN
eurjchem-1865	97	17	.	.	PUNCT
eurjchem-1865	98	1	author	author	NOUN
eurjchem-1865	98	2	contributions	contribution	NOUN
eurjchem-1865	98	3	:	:	PUNCT
eurjchem-1865	98	4	the	the	DET
eurjchem-1865	98	5	manuscript	manuscript	NOUN
eurjchem-1865	98	6	was	be	AUX
eurjchem-1865	98	7	written	write	VERB
eurjchem-1865	98	8	through	through	ADP
eurjchem-1865	98	9	contributions	contribution	NOUN
eurjchem-1865	98	10	of	of	ADP
eurjchem-1865	98	11	all	all	DET
eurjchem-1865	98	12	authors	author	NOUN
eurjchem-1865	98	13	.	.	PUNCT
eurjchem-1865	99	1	all	all	DET
eurjchem-1865	99	2	authors	author	NOUN
eurjchem-1865	99	3	have	have	AUX
eurjchem-1865	99	4	given	give	VERB
eurjchem-1865	99	5	approval	approval	NOUN
eurjchem-1865	99	6	to	to	ADP
eurjchem-1865	99	7	the	the	DET
eurjchem-1865	99	8	final	final	ADJ
eurjchem-1865	99	9	version	version	NOUN
eurjchem-1865	99	10	of	of	ADP
eurjchem-1865	99	11	the	the	DET
eurjchem-1865	99	12	manuscript	manuscript	NOUN
eurjchem-1865	99	13	.	.	PUNCT
eurjchem-1865	100	1	these	these	DET
eurjchem-1865	100	2	authors	author	NOUN
eurjchem-1865	100	3	contributed	contribute	VERB
eurjchem-1865	100	4	equally	equally	ADV
eurjchem-1865	100	5	.	.	PUNCT
eurjchem-1865	101	1	ethical	ethical	ADJ
eurjchem-1865	101	2	approval	approval	NOUN
eurjchem-1865	101	3	:	:	PUNCT
eurjchem-1865	102	1	all	all	DET
eurjchem-1865	102	2	ethical	ethical	ADJ
eurjchem-1865	102	3	guidelines	guideline	NOUN
eurjchem-1865	102	4	have	have	AUX
eurjchem-1865	102	5	been	be	AUX
eurjchem-1865	102	6	adhered	adhere	VERB
eurjchem-1865	102	7	.	.	PUNCT
eurjchem-1865	103	1	sample	sample	NOUN
eurjchem-1865	103	2	availability	availability	NOUN
eurjchem-1865	103	3	:	:	PUNCT
eurjchem-1865	103	4	samples	sample	NOUN
eurjchem-1865	103	5	of	of	ADP
eurjchem-1865	103	6	the	the	DET
eurjchem-1865	103	7	compounds	compound	NOUN
eurjchem-1865	103	8	are	be	AUX
eurjchem-1865	103	9	available	available	ADJ
eurjchem-1865	103	10	from	from	ADP
eurjchem-1865	103	11	the	the	DET
eurjchem-1865	103	12	author	author	NOUN
eurjchem-1865	103	13	.	.	PUNCT
eurjchem-1865	104	1	orcid	orcid	PROPN
eurjchem-1865	104	2	marco	marco	PROPN
eurjchem-1865	104	3	fusè	fusè	PROPN
eurjchem-1865	104	4	http://orcid.org/0000-0003-0130-5175	http://orcid.org/0000-0003-0130-5175	PROPN
eurjchem-1865	104	5	giorgio	giorgio	PROPN
eurjchem-1865	104	6	facchetti	facchetti	PROPN
eurjchem-1865	104	7	http://orcid.org/0000-0002-1260-1335	http://orcid.org/0000-0002-1260-1335	PROPN
eurjchem-1865	104	8	isabella	isabella	PROPN
eurjchem-1865	104	9	rimoldi	rimoldi	PROPN
eurjchem-1865	104	10	http://orcid.org/0000-0002-6210-0264	http://orcid.org/0000-0002-6210-0264	PROPN
eurjchem-1865	104	11	carlo	carlo	PROPN
eurjchem-1865	104	12	castellano	castellano	PROPN
eurjchem-1865	104	13	http://orcid.org/0000-0002-7497-0670	http://orcid.org/0000-0002-7497-0670	PROPN
eurjchem-1865	104	14	references	reference	NOUN
eurjchem-1865	104	15	[	[	X
eurjchem-1865	104	16	1	1	NUM
eurjchem-1865	104	17	]	]	PUNCT
eurjchem-1865	104	18	.	.	PUNCT
eurjchem-1865	105	1	blaser	blaser	PROPN
eurjchem-1865	105	2	,	,	PUNCT
eurjchem-1865	105	3	h.	h.	PROPN
eurjchem-1865	105	4	u.	u.	PROPN
eurjchem-1865	105	5	;	;	PUNCT
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eurjchem-1865	105	7	,	,	PUNCT
eurjchem-1865	105	8	e.	e.	PROPN
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eurjchem-1865	105	14	.	.	PUNCT
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eurjchem-1865	106	6	&	&	CCONJ
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eurjchem-1865	106	10	.	.	PUNCT
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eurjchem-1865	107	2	2	2	NUM
eurjchem-1865	107	3	]	]	PUNCT
eurjchem-1865	107	4	.	.	PUNCT
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eurjchem-1865	108	2	,	,	PUNCT
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eurjchem-1865	108	5	;	;	PUNCT
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eurjchem-1865	108	10	;	;	PUNCT
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eurjchem-1865	108	13	w.	w.	PROPN
eurjchem-1865	108	14	y.	y.	PROPN
eurjchem-1865	108	15	;	;	PUNCT
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eurjchem-1865	110	2	.	.	PROPN
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eurjchem-1865	110	4	,	,	PUNCT
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eurjchem-1865	110	6	,	,	PUNCT
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eurjchem-1865	110	8	-	-	SYM
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eurjchem-1865	111	2	3	3	NUM
eurjchem-1865	111	3	]	]	PUNCT
eurjchem-1865	111	4	.	.	PUNCT
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eurjchem-1865	112	2	,	,	PUNCT
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eurjchem-1865	112	4	;	;	PUNCT
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eurjchem-1865	112	6	,	,	PUNCT
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eurjchem-1865	113	2	.	.	PUNCT
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eurjchem-1865	114	2	.	.	PUNCT
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eurjchem-1865	115	2	,	,	PUNCT
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eurjchem-1865	115	6	-	-	SYM
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eurjchem-1865	116	3	]	]	PUNCT
eurjchem-1865	116	4	.	.	PUNCT
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eurjchem-1865	116	6	,	,	PUNCT
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eurjchem-1865	116	9	;	;	PUNCT
eurjchem-1865	116	10	de	de	PROPN
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eurjchem-1865	116	13	a.	a.	PROPN
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eurjchem-1865	116	15	;	;	PUNCT
eurjchem-1865	116	16	de	de	PROPN
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eurjchem-1865	116	18	,	,	PUNCT
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eurjchem-1865	117	1	[	[	X
eurjchem-1865	117	2	5	5	NUM
eurjchem-1865	117	3	]	]	PUNCT
eurjchem-1865	117	4	.	.	PUNCT
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eurjchem-1865	118	2	,	,	PUNCT
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eurjchem-1865	118	5	;	;	PUNCT
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eurjchem-1865	118	7	,	,	PUNCT
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eurjchem-1865	118	9	;	;	PUNCT
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eurjchem-1865	118	11	,	,	PUNCT
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eurjchem-1865	118	13	;	;	PUNCT
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eurjchem-1865	118	21	;	;	PUNCT
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eurjchem-1865	118	26	.	.	PUNCT
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eurjchem-1865	119	2	.	.	PUNCT
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eurjchem-1865	120	2	,	,	PUNCT
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eurjchem-1865	120	4	,	,	PUNCT
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eurjchem-1865	120	6	-	-	SYM
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eurjchem-1865	120	8	.	.	PUNCT
eurjchem-1865	121	1	[	[	X
eurjchem-1865	121	2	6	6	NUM
eurjchem-1865	121	3	]	]	PUNCT
eurjchem-1865	121	4	.	.	PUNCT
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eurjchem-1865	122	10	;	;	PUNCT
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eurjchem-1865	122	15	;	;	PUNCT
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eurjchem-1865	123	2	,	,	PUNCT
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eurjchem-1865	124	2	.	.	PUNCT
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eurjchem-1865	125	2	.	.	PUNCT
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eurjchem-1865	126	2	.	.	PROPN
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eurjchem-1865	127	2	,	,	PUNCT
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eurjchem-1865	127	4	,	,	PUNCT
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eurjchem-1865	127	6	-	-	SYM
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eurjchem-1865	127	8	.	.	PUNCT
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eurjchem-1865	128	2	–	–	PUNCT
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eurjchem-1865	128	7	–	–	PUNCT
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eurjchem-1865	128	17	-	-	PUNCT
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eurjchem-1865	129	8	/	/	SYM
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eurjchem-1865	129	14	(	(	PUNCT
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eurjchem-1865	129	17	(	(	PUNCT
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eurjchem-1865	129	19	)	)	PUNCT
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eurjchem-1865	129	21	-	-	SYM
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eurjchem-1865	130	2	7	7	NUM
eurjchem-1865	130	3	]	]	PUNCT
eurjchem-1865	130	4	.	.	PUNCT
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eurjchem-1865	131	2	,	,	PUNCT
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eurjchem-1865	131	4	;	;	PUNCT
eurjchem-1865	131	5	takaya	takaya	PROPN
eurjchem-1865	131	6	,	,	PUNCT
eurjchem-1865	131	7	h.	h.	PROPN
eurjchem-1865	131	8	;	;	PUNCT
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eurjchem-1865	131	12	;	;	PUNCT
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eurjchem-1865	131	14	,	,	PUNCT
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eurjchem-1865	131	20	,	,	PUNCT
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eurjchem-1865	131	22	-	-	SYM
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eurjchem-1865	131	24	.	.	PUNCT
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eurjchem-1865	132	2	8	8	NUM
eurjchem-1865	132	3	]	]	PUNCT
eurjchem-1865	132	4	.	.	PUNCT
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eurjchem-1865	132	6	,	,	PUNCT
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eurjchem-1865	132	8	;	;	PUNCT
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eurjchem-1865	132	10	,	,	PUNCT
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eurjchem-1865	132	14	,	,	PUNCT
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eurjchem-1865	132	16	;	;	PUNCT
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eurjchem-1865	132	20	;	;	PUNCT
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eurjchem-1865	132	22	,	,	PUNCT
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eurjchem-1865	132	25	:	:	PUNCT
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eurjchem-1865	133	4	.	.	PUNCT
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eurjchem-1865	134	4	;	;	PUNCT
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eurjchem-1865	134	6	,	,	PUNCT
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eurjchem-1865	134	8	;	;	PUNCT
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eurjchem-1865	134	12	;	;	PUNCT
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eurjchem-1865	134	17	:	:	PUNCT
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eurjchem-1865	134	25	-	-	SYM
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eurjchem-1865	134	27	.	.	PUNCT
eurjchem-1865	135	1	[	[	X
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eurjchem-1865	135	4	.	.	PUNCT
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eurjchem-1865	136	4	;	;	PUNCT
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eurjchem-1865	140	14	,	,	PUNCT
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eurjchem-1865	140	16	;	;	PUNCT
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eurjchem-1865	140	32	t.	t.	PROPN
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eurjchem-1865	141	2	.	.	PUNCT
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eurjchem-1865	142	2	.	.	PUNCT
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eurjchem-1865	143	2	.	.	PROPN
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eurjchem-1865	144	2	,	,	PUNCT
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eurjchem-1865	144	4	,	,	PUNCT
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eurjchem-1865	144	6	-	-	SYM
eurjchem-1865	144	7	1707	1707	NUM
eurjchem-1865	144	8	.	.	PUNCT
eurjchem-1865	145	1	[	[	X
eurjchem-1865	145	2	12	12	NUM
eurjchem-1865	145	3	]	]	PUNCT
eurjchem-1865	145	4	.	.	PUNCT
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eurjchem-1865	146	2	,	,	PUNCT
eurjchem-1865	146	3	g.	g.	PROPN
eurjchem-1865	146	4	;	;	PUNCT
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eurjchem-1865	146	6	,	,	PUNCT
eurjchem-1865	146	7	h.	h.	PROPN
eurjchem-1865	146	8	;	;	PUNCT
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eurjchem-1865	146	16	;	;	PUNCT
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eurjchem-1865	146	18	,	,	PUNCT
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eurjchem-1865	146	20	;	;	PUNCT
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eurjchem-1865	146	22	,	,	PUNCT
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eurjchem-1865	146	24	;	;	PUNCT
eurjchem-1865	146	25	schmuck	schmuck	PROPN
eurjchem-1865	146	26	,	,	PUNCT
eurjchem-1865	146	27	c.	c.	PROPN
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eurjchem-1865	146	29	.	.	PUNCT
eurjchem-1865	147	1	j.	j.	PROPN
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eurjchem-1865	147	3	.	.	PUNCT
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eurjchem-1865	147	5	.	.	PUNCT
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eurjchem-1865	148	2	,	,	PUNCT
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eurjchem-1865	148	4	,	,	PUNCT
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eurjchem-1865	148	6	-	-	SYM
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eurjchem-1865	148	8	.	.	PUNCT
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eurjchem-1865	150	2	,	,	PUNCT
eurjchem-1865	150	3	l.	l.	PROPN
eurjchem-1865	150	4	;	;	PUNCT
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eurjchem-1865	150	6	,	,	PUNCT
eurjchem-1865	150	7	f.	f.	PROPN
eurjchem-1865	150	8	y.	y.	PROPN
eurjchem-1865	150	9	;	;	PUNCT
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eurjchem-1865	150	11	,	,	PUNCT
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eurjchem-1865	150	13	;	;	PUNCT
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eurjchem-1865	150	17	h.	h.	PROPN
eurjchem-1865	150	18	;	;	PUNCT
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eurjchem-1865	150	20	,	,	PUNCT
eurjchem-1865	150	21	s.	s.	PROPN
eurjchem-1865	150	22	;	;	PUNCT
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eurjchem-1865	150	24	,	,	PUNCT
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eurjchem-1865	150	26	.	.	PUNCT
eurjchem-1865	150	27	;	;	PUNCT
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eurjchem-1865	150	32	;	;	PUNCT
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eurjchem-1865	150	34	,	,	PUNCT
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eurjchem-1865	150	36	;	;	PUNCT
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eurjchem-1865	150	38	,	,	PUNCT
eurjchem-1865	150	39	z.	z.	PROPN
eurjchem-1865	150	40	;	;	PUNCT
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eurjchem-1865	151	2	.	.	PUNCT
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eurjchem-1865	152	2	.	.	PUNCT
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eurjchem-1865	153	2	,	,	PUNCT
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eurjchem-1865	153	4	,	,	PUNCT
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eurjchem-1865	154	2	14	14	NUM
eurjchem-1865	154	3	]	]	PUNCT
eurjchem-1865	154	4	.	.	PUNCT
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eurjchem-1865	155	2	,	,	PUNCT
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eurjchem-1865	155	4	;	;	PUNCT
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eurjchem-1865	155	6	,	,	PUNCT
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eurjchem-1865	155	8	;	;	PUNCT
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eurjchem-1865	155	10	,	,	PUNCT
eurjchem-1865	155	11	g.	g.	PROPN
eurjchem-1865	155	12	;	;	PUNCT
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eurjchem-1865	155	14	,	,	PUNCT
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eurjchem-1865	155	16	;	;	PUNCT
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eurjchem-1865	155	18	,	,	PUNCT
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eurjchem-1865	155	20	;	;	PUNCT
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eurjchem-1865	155	22	,	,	PUNCT
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eurjchem-1865	155	29	,	,	PUNCT
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eurjchem-1865	155	31	,	,	PUNCT
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eurjchem-1865	155	33	-	-	SYM
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eurjchem-1865	155	35	.	.	PUNCT
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eurjchem-1865	156	3	]	]	PUNCT
eurjchem-1865	156	4	.	.	PUNCT
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eurjchem-1865	157	2	,	,	PUNCT
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eurjchem-1865	157	8	;	;	PUNCT
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eurjchem-1865	157	12	;	;	PUNCT
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eurjchem-1865	157	14	,	,	PUNCT
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eurjchem-1865	158	7	-	-	SYM
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eurjchem-1865	160	2	,	,	PUNCT
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eurjchem-1865	160	20	;	;	PUNCT
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eurjchem-1865	160	25	.	.	PUNCT
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eurjchem-1865	161	2	.	.	PUNCT
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eurjchem-1865	161	4	.	.	PUNCT
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eurjchem-1865	162	6	-	-	SYM
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eurjchem-1865	169	4	.	.	PUNCT
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eurjchem-1865	170	4	;	;	PUNCT
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eurjchem-1865	170	13	;	;	PUNCT
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eurjchem-1865	174	10	,	,	PUNCT
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eurjchem-1865	174	12	;	;	PUNCT
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eurjchem-1865	174	14	,	,	PUNCT
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eurjchem-1865	176	2	,	,	PUNCT
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eurjchem-1865	176	4	,	,	PUNCT
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eurjchem-1865	177	3	]	]	PUNCT
eurjchem-1865	177	4	.	.	PUNCT
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eurjchem-1865	177	6	,	,	PUNCT
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eurjchem-1865	177	8	;	;	PUNCT
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eurjchem-1865	177	10	,	,	PUNCT
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eurjchem-1865	177	14	,	,	PUNCT
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eurjchem-1865	177	22	,	,	PUNCT
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eurjchem-1865	177	25	.	.	PUNCT
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eurjchem-1865	178	3	.	.	PUNCT
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eurjchem-1865	180	2	,	,	PUNCT
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eurjchem-1865	180	4	,	,	PUNCT
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eurjchem-1865	180	6	-	-	SYM
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eurjchem-1865	180	8	.	.	PUNCT
eurjchem-1865	181	1	[	[	X
eurjchem-1865	181	2	23	23	NUM
eurjchem-1865	181	3	]	]	PUNCT
eurjchem-1865	181	4	.	.	PUNCT
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eurjchem-1865	182	2	,	,	PUNCT
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eurjchem-1865	184	2	.	.	PUNCT
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eurjchem-1865	185	2	,	,	PUNCT
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eurjchem-1865	185	4	,	,	PUNCT
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eurjchem-1865	185	6	-	-	SYM
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eurjchem-1865	185	8	.	.	PUNCT
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eurjchem-1865	186	3	]	]	PUNCT
eurjchem-1865	186	4	.	.	PUNCT
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eurjchem-1865	186	6	,	,	PUNCT
eurjchem-1865	186	7	b.	b.	PROPN
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eurjchem-1865	186	9	;	;	PUNCT
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eurjchem-1865	186	16	.	.	PUNCT
eurjchem-1865	187	1	chem	chem	PROPN
eurjchem-1865	187	2	.	.	PUNCT
eurjchem-1865	188	1	soc	soc	PROPN
eurjchem-1865	188	2	.	.	PUNCT
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eurjchem-1865	189	2	,	,	PUNCT
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eurjchem-1865	189	4	,	,	PUNCT
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eurjchem-1865	189	6	-	-	SYM
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eurjchem-1865	189	8	.	.	PUNCT
eurjchem-1865	190	1	[	[	X
eurjchem-1865	190	2	25	25	NUM
eurjchem-1865	190	3	]	]	PUNCT
eurjchem-1865	190	4	.	.	PUNCT
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eurjchem-1865	191	2	,	,	PUNCT
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eurjchem-1865	191	4	;	;	PUNCT
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eurjchem-1865	191	6	,	,	PUNCT
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eurjchem-1865	191	8	;	;	PUNCT
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eurjchem-1865	191	10	,	,	PUNCT
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eurjchem-1865	191	12	;	;	PUNCT
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eurjchem-1865	191	14	,	,	PUNCT
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eurjchem-1865	191	16	;	;	PUNCT
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eurjchem-1865	191	21	.	.	PUNCT
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eurjchem-1865	192	2	.	.	PUNCT
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eurjchem-1865	193	2	.	.	PUNCT
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eurjchem-1865	194	2	.	.	PUNCT
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eurjchem-1865	195	2	,	,	PUNCT
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eurjchem-1865	195	4	,	,	PUNCT
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eurjchem-1865	195	6	-	-	SYM
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eurjchem-1865	196	2	,	,	PUNCT
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eurjchem-1865	196	4	;	;	PUNCT
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eurjchem-1865	196	8	;	;	PUNCT
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eurjchem-1865	196	14	,	,	PUNCT
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eurjchem-1865	196	16	;	;	PUNCT
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eurjchem-1865	196	18	,	,	PUNCT
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eurjchem-1865	196	20	;	;	PUNCT
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eurjchem-1865	196	22	,	,	PUNCT
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eurjchem-1865	196	24	;	;	PUNCT
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eurjchem-1865	197	3	]	]	PUNCT
eurjchem-1865	197	4	.	.	PUNCT
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eurjchem-1865	198	2	,	,	PUNCT
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eurjchem-1865	198	4	;	;	PUNCT
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eurjchem-1865	198	6	,	,	PUNCT
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eurjchem-1865	198	8	;	;	PUNCT
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eurjchem-1865	198	12	;	;	PUNCT
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eurjchem-1865	198	18	,	,	PUNCT
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eurjchem-1865	199	2	.	.	PUNCT
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eurjchem-1865	200	2	,	,	PUNCT
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eurjchem-1865	200	4	,	,	PUNCT
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eurjchem-1865	200	6	-	-	SYM
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eurjchem-1865	200	8	.	.	PUNCT
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eurjchem-1865	201	4	.	.	PUNCT
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eurjchem-1865	202	5	;	;	PUNCT
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eurjchem-1865	202	7	,	,	PUNCT
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eurjchem-1865	202	9	;	;	PUNCT
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eurjchem-1865	203	2	,	,	PUNCT
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eurjchem-1865	203	4	,	,	PUNCT
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eurjchem-1865	203	6	-	-	SYM
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eurjchem-1865	204	4	.	.	PUNCT
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eurjchem-1865	205	2	,	,	PUNCT
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eurjchem-1865	205	5	;	;	PUNCT
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eurjchem-1865	205	10	;	;	PUNCT
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eurjchem-1865	205	15	;	;	PUNCT
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eurjchem-1865	206	4	.	.	PUNCT
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eurjchem-1865	207	2	.	.	PUNCT
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eurjchem-1865	211	2	,	,	PUNCT
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eurjchem-1865	213	8	;	;	PUNCT
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eurjchem-1865	214	4	;	;	PUNCT
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eurjchem-1865	214	8	;	;	PUNCT
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eurjchem-1865	214	31	.	.	PUNCT
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eurjchem-1865	218	3	-	-	PUNCT
eurjchem-1865	218	4	detector	detector	NOUN
eurjchem-1865	218	5	absorption	absorption	NOUN
eurjchem-1865	218	6	correction	correction	NOUN
eurjchem-1865	218	7	program	program	NOUN
eurjchem-1865	218	8	,	,	PUNCT
eurjchem-1865	218	9	b.	b.	PROPN
eurjchem-1865	218	10	a.	a.	PROPN
eurjchem-1865	218	11	i.	i.	PROPN
eurjchem-1865	218	12	m.	m.	PROPN
eurjchem-1865	218	13	,	,	PUNCT
eurjchem-1865	218	14	wi	wi	PROPN
eurjchem-1865	218	15	,	,	PUNCT
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eurjchem-1865	218	17	2000	2000	NUM
eurjchem-1865	218	18	.	.	PUNCT
eurjchem-1865	219	1	[	[	X
eurjchem-1865	219	2	33	33	NUM
eurjchem-1865	219	3	]	]	PUNCT
eurjchem-1865	219	4	.	.	PUNCT
eurjchem-1865	220	1	altomare	altomare	PROPN
eurjchem-1865	220	2	,	,	PUNCT
eurjchem-1865	220	3	a.	a.	NOUN
eurjchem-1865	220	4	;	;	PUNCT
eurjchem-1865	220	5	burla	burla	PROPN
eurjchem-1865	220	6	,	,	PUNCT
eurjchem-1865	220	7	m.	m.	PROPN
eurjchem-1865	220	8	c.	c.	PROPN
eurjchem-1865	220	9	;	;	PUNCT
eurjchem-1865	220	10	camalli	camalli	PROPN
eurjchem-1865	220	11	,	,	PUNCT
eurjchem-1865	220	12	m.	m.	NOUN
eurjchem-1865	220	13	;	;	PUNCT
eurjchem-1865	220	14	cascarano	cascarano	PROPN
eurjchem-1865	220	15	,	,	PUNCT
eurjchem-1865	220	16	g.	g.	PROPN
eurjchem-1865	220	17	l.	l.	PROPN
eurjchem-1865	220	18	;	;	PUNCT
eurjchem-1865	220	19	giacovazzo	giacovazzo	PROPN
eurjchem-1865	220	20	,	,	PUNCT
eurjchem-1865	220	21	c.	c.	NOUN
eurjchem-1865	220	22	;	;	PUNCT
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eurjchem-1865	220	24	,	,	PUNCT
eurjchem-1865	220	25	a.	a.	NOUN
eurjchem-1865	220	26	;	;	PUNCT
eurjchem-1865	220	27	moliterni	moliterni	PROPN
eurjchem-1865	220	28	,	,	PUNCT
eurjchem-1865	220	29	a.	a.	PROPN
eurjchem-1865	220	30	g.	g.	PROPN
eurjchem-1865	220	31	g.	g.	PROPN
eurjchem-1865	220	32	;	;	PUNCT
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eurjchem-1865	220	34	,	,	PUNCT
eurjchem-1865	220	35	g.	g.	PROPN
eurjchem-1865	220	36	;	;	PUNCT
eurjchem-1865	220	37	spagna	spagna	PROPN
eurjchem-1865	220	38	,	,	PUNCT
eurjchem-1865	220	39	r.	r.	PROPN
eurjchem-1865	220	40	j.	j.	PROPN
eurjchem-1865	220	41	appl	appl	PROPN
eurjchem-1865	220	42	.	.	PROPN
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eurjchem-1865	220	44	.	.	PUNCT
eurjchem-1865	221	1	1999	1999	NUM
eurjchem-1865	221	2	,	,	PUNCT
eurjchem-1865	221	3	32	32	NUM
eurjchem-1865	221	4	,	,	PUNCT
eurjchem-1865	221	5	115	115	NUM
eurjchem-1865	221	6	-	-	SYM
eurjchem-1865	221	7	119	119	NUM
eurjchem-1865	221	8	.	.	PUNCT
eurjchem-1865	222	1	[	[	X
eurjchem-1865	222	2	34	34	NUM
eurjchem-1865	222	3	]	]	PUNCT
eurjchem-1865	222	4	.	.	PUNCT
eurjchem-1865	222	5	sheldrick	sheldrick	NOUN
eurjchem-1865	222	6	,	,	PUNCT
eurjchem-1865	222	7	g.	g.	PROPN
eurjchem-1865	222	8	m.	m.	PROPN
eurjchem-1865	222	9	acta	acta	PROPN
eurjchem-1865	222	10	cryst	cryst	PROPN
eurjchem-1865	222	11	.	.	PUNCT
eurjchem-1865	223	1	c	c	NOUN
eurjchem-1865	223	2	2015	2015	NUM
eurjchem-1865	223	3	,	,	PUNCT
eurjchem-1865	223	4	71	71	NUM
eurjchem-1865	223	5	,	,	PUNCT
eurjchem-1865	223	6	3	3	NUM
eurjchem-1865	223	7	-	-	SYM
eurjchem-1865	223	8	8	8	NUM
eurjchem-1865	223	9	.	.	PUNCT
eurjchem-1865	224	1	[	[	X
eurjchem-1865	224	2	35	35	NUM
eurjchem-1865	224	3	]	]	PUNCT
eurjchem-1865	224	4	.	.	PUNCT
eurjchem-1865	225	1	farrugia	farrugia	PROPN
eurjchem-1865	225	2	,	,	PUNCT
eurjchem-1865	225	3	l.	l.	PROPN
eurjchem-1865	225	4	j.	j.	PROPN
eurjchem-1865	225	5	j.	j.	PROPN
eurjchem-1865	225	6	appl	appl	PROPN
eurjchem-1865	225	7	.	.	PROPN
eurjchem-1865	226	1	crystallogr	crystallogr	PROPN
eurjchem-1865	226	2	.	.	PUNCT
eurjchem-1865	227	1	1999	1999	NUM
eurjchem-1865	227	2	,	,	PUNCT
eurjchem-1865	227	3	32	32	NUM
eurjchem-1865	227	4	,	,	PUNCT
eurjchem-1865	227	5	837	837	NUM
eurjchem-1865	227	6	-	-	SYM
eurjchem-1865	227	7	838	838	NUM
eurjchem-1865	227	8	.	.	PUNCT
eurjchem-1865	228	1	[	[	X
eurjchem-1865	228	2	36	36	NUM
eurjchem-1865	228	3	]	]	PUNCT
eurjchem-1865	228	4	.	.	PUNCT
eurjchem-1865	229	1	manceron	manceron	PROPN
eurjchem-1865	229	2	,	,	PUNCT
eurjchem-1865	229	3	l.	l.	PROPN
eurjchem-1865	229	4	;	;	PUNCT
eurjchem-1865	229	5	alikhani	alikhani	PROPN
eurjchem-1865	229	6	,	,	PUNCT
eurjchem-1865	229	7	m.	m.	PROPN
eurjchem-1865	229	8	e.	e.	PROPN
eurjchem-1865	229	9	chem	chem	PROPN
eurjchem-1865	229	10	.	.	PUNCT
eurjchem-1865	230	1	phys	phy	NOUN
eurjchem-1865	230	2	.	.	PUNCT
eurjchem-1865	231	1	1999	1999	NUM
eurjchem-1865	231	2	,	,	PUNCT
eurjchem-1865	231	3	244	244	NUM
eurjchem-1865	231	4	,	,	PUNCT
eurjchem-1865	231	5	215	215	NUM
eurjchem-1865	231	6	-	-	SYM
eurjchem-1865	231	7	226	226	NUM
eurjchem-1865	231	8	.	.	PUNCT
eurjchem-1865	232	1	[	[	X
eurjchem-1865	232	2	37	37	NUM
eurjchem-1865	232	3	]	]	SYM
eurjchem-1865	232	4	.	.	PUNCT
eurjchem-1865	233	1	colombo	colombo	PROPN
eurjchem-1865	233	2	,	,	PUNCT
eurjchem-1865	233	3	a.	a.	NOUN
eurjchem-1865	233	4	;	;	PUNCT
eurjchem-1865	233	5	dragonetti	dragonetti	PROPN
eurjchem-1865	233	6	,	,	PUNCT
eurjchem-1865	233	7	c.	c.	PROPN
eurjchem-1865	233	8	;	;	PUNCT
eurjchem-1865	233	9	magni	magni	PROPN
eurjchem-1865	233	10	,	,	PUNCT
eurjchem-1865	233	11	m.	m.	NOUN
eurjchem-1865	233	12	;	;	PUNCT
eurjchem-1865	233	13	roberto	roberto	PROPN
eurjchem-1865	233	14	,	,	PUNCT
eurjchem-1865	233	15	d.	d.	PROPN
eurjchem-1865	233	16	;	;	PUNCT
eurjchem-1865	233	17	demartin	demartin	PROPN
eurjchem-1865	233	18	,	,	PUNCT
eurjchem-1865	233	19	f.	f.	PROPN
eurjchem-1865	233	20	;	;	PUNCT
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eurjchem-1865	233	22	,	,	PUNCT
eurjchem-1865	233	23	s.	s.	PROPN
eurjchem-1865	233	24	;	;	PUNCT
eurjchem-1865	233	25	bignozzi	bignozzi	NOUN
eurjchem-1865	233	26	,	,	PUNCT
eurjchem-1865	233	27	c.	c.	PROPN
eurjchem-1865	233	28	a.	a.	PROPN
eurjchem-1865	233	29	acs	acs	PROPN
eurjchem-1865	233	30	appl	appl	PROPN
eurjchem-1865	233	31	.	.	PUNCT
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eurjchem-1865	234	2	.	.	PUNCT
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eurjchem-1865	235	2	2014	2014	NUM
eurjchem-1865	235	3	,	,	PUNCT
eurjchem-1865	235	4	6	6	NUM
eurjchem-1865	235	5	,	,	PUNCT
eurjchem-1865	235	6	13945	13945	NUM
eurjchem-1865	235	7	-	-	SYM
eurjchem-1865	235	8	13955	13955	NUM
eurjchem-1865	235	9	.	.	PUNCT
eurjchem-1865	236	1	[	[	X
eurjchem-1865	236	2	38	38	NUM
eurjchem-1865	236	3	]	]	PUNCT
eurjchem-1865	236	4	.	.	PUNCT
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eurjchem-1865	237	2	,	,	PUNCT
eurjchem-1865	237	3	a.	a.	NOUN
eurjchem-1865	237	4	;	;	PUNCT
eurjchem-1865	237	5	rosiak	rosiak	PROPN
eurjchem-1865	237	6	,	,	PUNCT
eurjchem-1865	237	7	d.	d.	PROPN
eurjchem-1865	237	8	;	;	PUNCT
eurjchem-1865	237	9	chojnacki	chojnacki	PROPN
eurjchem-1865	237	10	,	,	PUNCT
eurjchem-1865	237	11	j.	j.	PROPN
eurjchem-1865	237	12	;	;	PUNCT
eurjchem-1865	237	13	becker	becker	PROPN
eurjchem-1865	237	14	,	,	PUNCT
eurjchem-1865	237	15	b.	b.	PROPN
eurjchem-1865	237	16	polyhedron	polyhedron	PROPN
eurjchem-1865	237	17	2015	2015	NUM
eurjchem-1865	237	18	,	,	PUNCT
eurjchem-1865	237	19	90	90	NUM
eurjchem-1865	237	20	,	,	PUNCT
eurjchem-1865	237	21	47	47	NUM
eurjchem-1865	237	22	-	-	SYM
eurjchem-1865	237	23	57	57	NUM
eurjchem-1865	237	24	.	.	PUNCT
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eurjchem-1865	238	2	©	©	PROPN
eurjchem-1865	238	3	2019	2019	NUM
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eurjchem-1865	238	5	authors	author	NOUN
eurjchem-1865	238	6	.	.	PUNCT
eurjchem-1865	239	1	this	this	DET
eurjchem-1865	239	2	work	work	NOUN
eurjchem-1865	239	3	is	be	AUX
eurjchem-1865	239	4	published	publish	VERB
eurjchem-1865	239	5	and	and	CCONJ
eurjchem-1865	239	6	licensed	license	VERB
eurjchem-1865	239	7	by	by	ADP
eurjchem-1865	239	8	atlanta	atlanta	PROPN
eurjchem-1865	239	9	publishing	publishing	PROPN
eurjchem-1865	239	10	house	house	PROPN
eurjchem-1865	239	11	llc	llc	PROPN
eurjchem-1865	239	12	,	,	PUNCT
eurjchem-1865	239	13	atlanta	atlanta	PROPN
eurjchem-1865	239	14	,	,	PUNCT
eurjchem-1865	239	15	ga	ga	PROPN
eurjchem-1865	239	16	,	,	PUNCT
eurjchem-1865	239	17	usa	usa	PROPN
eurjchem-1865	239	18	.	.	PUNCT
eurjchem-1865	240	1	the	the	DET
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eurjchem-1865	240	7	are	be	AUX
eurjchem-1865	240	8	available	available	ADJ
eurjchem-1865	240	9	at	at	ADP
eurjchem-1865	240	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1865	240	11	and	and	CCONJ
eurjchem-1865	240	12	incorporate	incorporate	VERB
eurjchem-1865	240	13	the	the	DET
eurjchem-1865	240	14	creative	creative	ADJ
eurjchem-1865	240	15	commons	common	NOUN
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eurjchem-1865	240	17	-	-	PUNCT
eurjchem-1865	240	18	non	non	ADJ
eurjchem-1865	240	19	commercial	commercial	NOUN
eurjchem-1865	240	20	(	(	PUNCT
eurjchem-1865	240	21	cc	cc	NOUN
eurjchem-1865	240	22	by	by	ADP
eurjchem-1865	240	23	nc	nc	PROPN
eurjchem-1865	240	24	)	)	PUNCT
eurjchem-1865	240	25	(	(	PUNCT
eurjchem-1865	240	26	international	international	ADJ
eurjchem-1865	240	27	,	,	PUNCT
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eurjchem-1865	240	29	)	)	PUNCT
eurjchem-1865	240	30	license	license	NOUN
eurjchem-1865	240	31	(	(	PUNCT
eurjchem-1865	240	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-1865	240	33	)	)	PUNCT
eurjchem-1865	240	34	.	.	PUNCT
eurjchem-1865	241	1	by	by	ADP
eurjchem-1865	241	2	accessing	access	VERB
eurjchem-1865	241	3	the	the	DET
eurjchem-1865	241	4	work	work	NOUN
eurjchem-1865	241	5	,	,	PUNCT
eurjchem-1865	241	6	you	you	PRON
eurjchem-1865	241	7	hereby	hereby	ADV
eurjchem-1865	241	8	accept	accept	VERB
eurjchem-1865	241	9	the	the	DET
eurjchem-1865	241	10	terms	term	NOUN
eurjchem-1865	241	11	.	.	PUNCT
eurjchem-1865	242	1	this	this	PRON
eurjchem-1865	242	2	is	be	AUX
eurjchem-1865	242	3	an	an	DET
eurjchem-1865	242	4	open	open	ADJ
eurjchem-1865	242	5	access	access	NOUN
eurjchem-1865	242	6	article	article	NOUN
eurjchem-1865	242	7	distributed	distribute	VERB
eurjchem-1865	242	8	under	under	ADP
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eurjchem-1865	242	10	terms	term	NOUN
eurjchem-1865	242	11	and	and	CCONJ
eurjchem-1865	242	12	conditions	condition	NOUN
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eurjchem-1865	242	14	the	the	DET
eurjchem-1865	242	15	cc	cc	PROPN
eurjchem-1865	242	16	by	by	ADP
eurjchem-1865	242	17	nc	nc	PROPN
eurjchem-1865	242	18	license	license	PROPN
eurjchem-1865	242	19	,	,	PUNCT
eurjchem-1865	242	20	which	which	PRON
eurjchem-1865	242	21	permits	permit	VERB
eurjchem-1865	242	22	unrestricted	unrestricted	ADJ
eurjchem-1865	242	23	non	non	ADJ
eurjchem-1865	242	24	-	-	ADJ
eurjchem-1865	242	25	commercial	commercial	ADJ
eurjchem-1865	242	26	use	use	NOUN
eurjchem-1865	242	27	,	,	PUNCT
eurjchem-1865	242	28	distribution	distribution	NOUN
eurjchem-1865	242	29	,	,	PUNCT
eurjchem-1865	242	30	and	and	CCONJ
eurjchem-1865	242	31	reproduction	reproduction	NOUN
eurjchem-1865	242	32	in	in	ADP
eurjchem-1865	242	33	any	any	DET
eurjchem-1865	242	34	medium	medium	NOUN
eurjchem-1865	242	35	,	,	PUNCT
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eurjchem-1865	242	37	the	the	DET
eurjchem-1865	242	38	original	original	ADJ
eurjchem-1865	242	39	work	work	NOUN
eurjchem-1865	242	40	is	be	AUX
eurjchem-1865	242	41	properly	properly	ADV
eurjchem-1865	242	42	cited	cite	VERB
eurjchem-1865	242	43	without	without	ADP
eurjchem-1865	242	44	any	any	DET
eurjchem-1865	242	45	further	further	ADJ
eurjchem-1865	242	46	permission	permission	NOUN
eurjchem-1865	242	47	from	from	ADP
eurjchem-1865	242	48	atlanta	atlanta	PROPN
eurjchem-1865	242	49	publishing	publishing	PROPN
eurjchem-1865	242	50	house	house	PROPN
eurjchem-1865	242	51	llc	llc	PROPN
eurjchem-1865	242	52	(	(	PUNCT
eurjchem-1865	242	53	european	european	PROPN
eurjchem-1865	242	54	journal	journal	PROPN
eurjchem-1865	242	55	of	of	ADP
eurjchem-1865	242	56	chemistry	chemistry	NOUN
eurjchem-1865	242	57	)	)	PUNCT
eurjchem-1865	242	58	.	.	PUNCT
eurjchem-1865	243	1	no	no	DET
eurjchem-1865	243	2	use	use	NOUN
eurjchem-1865	243	3	,	,	PUNCT
eurjchem-1865	243	4	distribution	distribution	NOUN
eurjchem-1865	243	5	or	or	CCONJ
eurjchem-1865	243	6	reproduction	reproduction	NOUN
eurjchem-1865	243	7	is	be	AUX
eurjchem-1865	243	8	permitted	permit	VERB
eurjchem-1865	243	9	which	which	PRON
eurjchem-1865	243	10	does	do	AUX
eurjchem-1865	243	11	not	not	PART
eurjchem-1865	243	12	comply	comply	VERB
eurjchem-1865	243	13	with	with	ADP
eurjchem-1865	243	14	these	these	DET
eurjchem-1865	243	15	terms	term	NOUN
eurjchem-1865	243	16	.	.	PUNCT
eurjchem-1865	244	1	permissions	permission	NOUN
eurjchem-1865	244	2	for	for	ADP
eurjchem-1865	244	3	commercial	commercial	ADJ
eurjchem-1865	244	4	use	use	NOUN
eurjchem-1865	244	5	of	of	ADP
eurjchem-1865	244	6	this	this	DET
eurjchem-1865	244	7	work	work	NOUN
eurjchem-1865	244	8	beyond	beyond	ADP
eurjchem-1865	244	9	the	the	DET
eurjchem-1865	244	10	scope	scope	NOUN
eurjchem-1865	244	11	of	of	ADP
eurjchem-1865	244	12	the	the	DET
eurjchem-1865	244	13	license	license	NOUN
eurjchem-1865	244	14	(	(	PUNCT
eurjchem-1865	244	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1865	244	16	)	)	PUNCT
eurjchem-1865	244	17	are	be	AUX
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eurjchem-1865	244	19	by	by	ADP
eurjchem-1865	244	20	atlanta	atlanta	PROPN
eurjchem-1865	244	21	publishing	publishing	PROPN
eurjchem-1865	244	22	house	house	PROPN
eurjchem-1865	244	23	llc	llc	PROPN
eurjchem-1865	244	24	(	(	PUNCT
eurjchem-1865	244	25	european	european	PROPN
eurjchem-1865	244	26	journal	journal	PROPN
eurjchem-1865	244	27	of	of	ADP
eurjchem-1865	244	28	chemistry	chemistry	NOUN
eurjchem-1865	244	29	)	)	PUNCT
eurjchem-1865	244	30	.	.	PUNCT
eurjchem-1865	245	1	2019	2019	NUM
eurjchem-1865	245	2	–	–	PUNCT
eurjchem-1865	245	3	european	european	ADJ
eurjchem-1865	245	4	journal	journal	NOUN
eurjchem-1865	245	5	of	of	ADP
eurjchem-1865	245	6	chemistry	chemistry	NOUN
eurjchem-1865	245	7	–	–	PUNCT
eurjchem-1865	245	8	cc	cc	NOUN
eurjchem-1865	245	9	by	by	ADP
eurjchem-1865	245	10	nc	nc	PROPN
eurjchem-1865	245	11	–	–	PUNCT
eurjchem-1865	245	12	doi	doi	NOUN
eurjchem-1865	245	13	:	:	PUNCT
eurjchem-1865	245	14	10.5155	10.5155	NUM
eurjchem-1865	245	15	/	/	SYM
eurjchem-1865	245	16	eurjchem.10.2.171	eurjchem.10.2.171	DET
eurjchem-1865	245	17	-	-	PUNCT
eurjchem-1865	245	18	174.1865	174.1865	NUM
eurjchem-1865	245	19	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	PROPN
eurjchem-1865	245	20	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-1865	245	21	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-1865	245	22	1	1	NUM
eurjchem-1865	245	23	.	.	PUNCT
eurjchem-1865	245	24	introduction	introduction	NOUN
eurjchem-1865	245	25	2	2	NUM
eurjchem-1865	245	26	.	.	PUNCT
eurjchem-1865	245	27	experimental	experimental	ADJ
eurjchem-1865	245	28	2.1	2.1	NUM
eurjchem-1865	245	29	.	.	PUNCT
eurjchem-1865	246	1	synthesis	synthesis	NOUN
eurjchem-1865	246	2	of	of	ADP
eurjchem-1865	246	3	[	[	X
eurjchem-1865	246	4	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	246	5	)	)	PUNCT
eurjchem-1865	246	6	]	]	PUNCT
eurjchem-1865	246	7	complex	complex	ADJ
eurjchem-1865	246	8	2.2	2.2	NUM
eurjchem-1865	246	9	.	.	PUNCT
eurjchem-1865	247	1	crystal	crystal	NOUN
eurjchem-1865	247	2	structure	structure	NOUN
eurjchem-1865	247	3	of	of	ADP
eurjchem-1865	247	4	ni(co)2(bitianp	ni(co)2(bitianp	PROPN
eurjchem-1865	247	5	)	)	PUNCT
eurjchem-1865	247	6	3	3	NUM
eurjchem-1865	247	7	.	.	NOUN
eurjchem-1865	247	8	results	result	NOUN
eurjchem-1865	247	9	and	and	CCONJ
eurjchem-1865	247	10	discussion	discussion	NOUN
eurjchem-1865	247	11	4	4	NUM
eurjchem-1865	247	12	.	.	PUNCT
eurjchem-1865	248	1	conclusion	conclusion	NOUN
eurjchem-1865	248	2	supporting	support	VERB
eurjchem-1865	248	3	information	information	NOUN
eurjchem-1865	248	4	disclosure	disclosure	NOUN
eurjchem-1865	248	5	statement	statement	NOUN
eurjchem-1865	248	6	orcid	orcid	PROPN
eurjchem-1865	248	7	references	reference	NOUN
eurjchem-1865	248	8	printfield10	printfield10	NOUN
eurjchem-1865	248	9	:	:	PUNCT
eurjchem-1865	248	10	printfield11	printfield11	NOUN
eurjchem-1865	248	11	:	:	PUNCT
eurjchem-1865	248	12	printfield12	printfield12	PROPN
eurjchem-1865	248	13	:	:	PUNCT
eurjchem-1865	248	14	printfield13	printfield13	NOUN
eurjchem-1865	248	15	:	:	PUNCT
eurjchem-1865	248	16	printfield20	printfield20	PROPN
eurjchem-1865	248	17	:	:	PUNCT
eurjchem-1865	248	18	printfield21	printfield21	ADJ
eurjchem-1865	248	19	:	:	PUNCT
eurjchem-1865	248	20	printfield22	printfield22	NOUN
eurjchem-1865	248	21	:	:	PUNCT
eurjchem-1865	248	22	printfield23	printfield23	NOUN
eurjchem-1865	248	23	:	:	PUNCT