id	sid	tid	token	lemma	pos
eurjchem-1915	1	1	synthesis	synthesis	NOUN
eurjchem-1915	1	2	and	and	CCONJ
eurjchem-1915	1	3	characterization	characterization	NOUN
eurjchem-1915	1	4	of	of	ADP
eurjchem-1915	1	5	new	new	ADJ
eurjchem-1915	1	6	3,3`-bipyrazole-4,4`-dicarboxylic	3,3`-bipyrazole-4,4`-dicarboxylic	PROPN
eurjchem-1915	1	7	acid	acid	NOUN
eurjchem-1915	1	8	derivatives	derivative	NOUN
eurjchem-1915	1	9	and	and	CCONJ
eurjchem-1915	1	10	some	some	PRON
eurjchem-1915	1	11	of	of	ADP
eurjchem-1915	1	12	their	their	PRON
eurjchem-1915	1	13	palladium(ii	palladium(ii	NOUN
eurjchem-1915	1	14	)	)	PUNCT
eurjchem-1915	1	15	complexes	complex	NOUN
eurjchem-1915	1	16	as	as	ADP
eurjchem-1915	1	17	pre	pre	NOUN
eurjchem-1915	1	18	-	-	NOUN
eurjchem-1915	1	19	catalyst	catalyst	NOUN
eurjchem-1915	1	20	for	for	ADP
eurjchem-1915	1	21	suzuki	suzuki	NOUN
eurjchem-1915	1	22	coupling	coupling	NOUN
eurjchem-1915	1	23	reaction	reaction	NOUN
eurjchem-1915	1	24	in	in	ADP
eurjchem-1915	1	25	water	water	NOUN
eurjchem-1915	1	26	european	european	PROPN
eurjchem-1915	1	27	journal	journal	PROPN
eurjchem-1915	1	28	of	of	ADP
eurjchem-1915	1	29	chemistry	chemistry	NOUN
eurjchem-1915	1	30	10	10	NUM
eurjchem-1915	1	31	(	(	PUNCT
eurjchem-1915	1	32	4	4	NUM
eurjchem-1915	1	33	)	)	PUNCT
eurjchem-1915	1	34	(	(	PUNCT
eurjchem-1915	1	35	2019	2019	NUM
eurjchem-1915	1	36	)	)	PUNCT
eurjchem-1915	1	37	367	367	NUM
eurjchem-1915	1	38	-	-	SYM
eurjchem-1915	1	39	375	375	NUM
eurjchem-1915	1	40	european	european	ADJ
eurjchem-1915	1	41	journal	journal	NOUN
eurjchem-1915	1	42	of	of	ADP
eurjchem-1915	1	43	chemistry	chemistry	NOUN
eurjchem-1915	1	44	view	view	NOUN
eurjchem-1915	1	45	journal	journal	PROPN
eurjchem-1915	1	46	online	online	PROPN
eurjchem-1915	1	47	view	view	NOUN
eurjchem-1915	1	48	article	article	NOUN
eurjchem-1915	1	49	online	online	ADJ
eurjchem-1915	1	50	synthesis	synthesis	NOUN
eurjchem-1915	1	51	and	and	CCONJ
eurjchem-1915	1	52	characterization	characterization	NOUN
eurjchem-1915	1	53	of	of	ADP
eurjchem-1915	1	54	new	new	ADJ
eurjchem-1915	1	55	3,3`-bipyrazole-4,4`-dicarboxylic	3,3`-bipyrazole-4,4`-dicarboxylic	PROPN
eurjchem-1915	1	56	acid	acid	NOUN
eurjchem-1915	1	57	derivatives	derivative	NOUN
eurjchem-1915	1	58	and	and	CCONJ
eurjchem-1915	1	59	some	some	PRON
eurjchem-1915	1	60	of	of	ADP
eurjchem-1915	1	61	their	their	PRON
eurjchem-1915	1	62	palladium(ii	palladium(ii	NOUN
eurjchem-1915	1	63	)	)	PUNCT
eurjchem-1915	1	64	complexes	complex	NOUN
eurjchem-1915	1	65	as	as	ADP
eurjchem-1915	1	66	pre	pre	NOUN
eurjchem-1915	1	67	-	-	NOUN
eurjchem-1915	1	68	catalyst	catalyst	NOUN
eurjchem-1915	1	69	for	for	ADP
eurjchem-1915	1	70	suzuki	suzuki	NOUN
eurjchem-1915	1	71	coupling	coupling	NOUN
eurjchem-1915	1	72	reaction	reaction	NOUN
eurjchem-1915	1	73	in	in	ADP
eurjchem-1915	1	74	water	water	PROPN
eurjchem-1915	1	75	othman	othman	PROPN
eurjchem-1915	1	76	abduallah	abduallah	PROPN
eurjchem-1915	1	77	al	al	PROPN
eurjchem-1915	1	78	-	-	PUNCT
eurjchem-1915	1	79	fulaij	fulaij	PROPN
eurjchem-1915	1	80	,	,	PUNCT
eurjchem-1915	1	81	abdel	abdel	PROPN
eurjchem-1915	1	82	-	-	PUNCT
eurjchem-1915	1	83	zaher	zaher	PROPN
eurjchem-1915	1	84	abdelaziz	abdelaziz	PROPN
eurjchem-1915	1	85	elassar	elassar	PROPN
eurjchem-1915	1	86	*	*	PUNCT
eurjchem-1915	1	87	and	and	CCONJ
eurjchem-1915	1	88	kamal	kamal	PROPN
eurjchem-1915	1	89	mohamed	mohamed	PROPN
eurjchem-1915	1	90	dawood	dawood	PROPN
eurjchem-1915	1	91	chemistry	chemistry	PROPN
eurjchem-1915	1	92	department	department	PROPN
eurjchem-1915	1	93	,	,	PUNCT
eurjchem-1915	1	94	faculty	faculty	NOUN
eurjchem-1915	1	95	of	of	ADP
eurjchem-1915	1	96	science	science	NOUN
eurjchem-1915	1	97	,	,	PUNCT
eurjchem-1915	1	98	kuwait	kuwait	PROPN
eurjchem-1915	1	99	university	university	PROPN
eurjchem-1915	1	100	,	,	PUNCT
eurjchem-1915	1	101	safat-13060	safat-13060	NOUN
eurjchem-1915	1	102	,	,	PUNCT
eurjchem-1915	1	103	kuwait	kuwait	PROPN
eurjchem-1915	1	104	alfulaijothman@gmail.com	alfulaijothman@gmail.com	X
eurjchem-1915	2	1	(	(	PUNCT
eurjchem-1915	2	2	o.a.a	o.a.a	PROPN
eurjchem-1915	2	3	.	.	PUNCT
eurjchem-1915	2	4	)	)	PUNCT
eurjchem-1915	2	5	,	,	PUNCT
eurjchem-1915	3	1	aelassar@yahoo.com	aelassar@yahoo.com	X
eurjchem-1915	3	2	(	(	PUNCT
eurjchem-1915	3	3	a.a.e	a.a.e	NOUN
eurjchem-1915	3	4	.	.	PUNCT
eurjchem-1915	3	5	)	)	PUNCT
eurjchem-1915	3	6	,	,	PUNCT
eurjchem-1915	4	1	dr_dawood@yahoo.com	dr_dawood@yahoo.com	PROPN
eurjchem-1915	4	2	(	(	PUNCT
eurjchem-1915	4	3	k.m.d	k.m.d	PROPN
eurjchem-1915	4	4	.	.	PUNCT
eurjchem-1915	4	5	)	)	PUNCT
eurjchem-1915	5	1	*	*	PUNCT
eurjchem-1915	5	2	corresponding	correspond	VERB
eurjchem-1915	5	3	author	author	NOUN
eurjchem-1915	5	4	at	at	ADP
eurjchem-1915	5	5	:	:	PUNCT
eurjchem-1915	5	6	chemistry	chemistry	NOUN
eurjchem-1915	5	7	department	department	NOUN
eurjchem-1915	5	8	,	,	PUNCT
eurjchem-1915	5	9	faculty	faculty	NOUN
eurjchem-1915	5	10	of	of	ADP
eurjchem-1915	5	11	science	science	NOUN
eurjchem-1915	5	12	,	,	PUNCT
eurjchem-1915	5	13	kuwait	kuwait	PROPN
eurjchem-1915	5	14	university	university	PROPN
eurjchem-1915	5	15	,	,	PUNCT
eurjchem-1915	5	16	safat-13060	safat-13060	NOUN
eurjchem-1915	5	17	,	,	PUNCT
eurjchem-1915	5	18	kuwait	kuwait	PROPN
eurjchem-1915	5	19	.	.	PUNCT
eurjchem-1915	6	1	tel	tel	ADP
eurjchem-1915	6	2	:	:	PUNCT
eurjchem-1915	6	3	+965.24983680	+965.24983680	NOUN
eurjchem-1915	6	4	fax	fax	NOUN
eurjchem-1915	6	5	:	:	PUNCT
eurjchem-1915	6	6	+965	+965	NUM
eurjchem-1915	6	7	24816482	24816482	NUM
eurjchem-1915	6	8	e	e	NOUN
eurjchem-1915	6	9	-	-	NOUN
eurjchem-1915	6	10	mail	mail	NOUN
eurjchem-1915	6	11	:	:	PUNCT
eurjchem-1915	7	1	aelassar@yahoo.com	aelassar@yahoo.com	X
eurjchem-1915	7	2	(	(	PUNCT
eurjchem-1915	7	3	a.	a.	PROPN
eurjchem-1915	7	4	a.	a.	PROPN
eurjchem-1915	7	5	elassar	elassar	PROPN
eurjchem-1915	7	6	)	)	PUNCT
eurjchem-1915	7	7	.	.	PUNCT
eurjchem-1915	8	1	10.5155	10.5155	NUM
eurjchem-1915	8	2	/	/	SYM
eurjchem-1915	8	3	eurjchem.10.4.367	eurjchem.10.4.367	NUM
eurjchem-1915	8	4	-	-	SYM
eurjchem-1915	8	5	375.1915	375.1915	NUM
eurjchem-1915	8	6	received	receive	VERB
eurjchem-1915	8	7	:	:	PUNCT
eurjchem-1915	8	8	07	07	NUM
eurjchem-1915	8	9	july	july	PROPN
eurjchem-1915	8	10	2019	2019	NUM
eurjchem-1915	8	11	received	receive	VERB
eurjchem-1915	8	12	in	in	ADP
eurjchem-1915	8	13	revised	revise	VERB
eurjchem-1915	8	14	form	form	NOUN
eurjchem-1915	8	15	:	:	PUNCT
eurjchem-1915	8	16	20	20	NUM
eurjchem-1915	8	17	october	october	NOUN
eurjchem-1915	8	18	2019	2019	NUM
eurjchem-1915	8	19	accepted	accept	VERB
eurjchem-1915	8	20	:	:	PUNCT
eurjchem-1915	8	21	27	27	NUM
eurjchem-1915	8	22	october	october	NOUN
eurjchem-1915	8	23	2019	2019	NUM
eurjchem-1915	8	24	published	publish	VERB
eurjchem-1915	8	25	online	online	ADV
eurjchem-1915	8	26	:	:	PUNCT
eurjchem-1915	8	27	31	31	NUM
eurjchem-1915	8	28	december	december	PROPN
eurjchem-1915	8	29	2019	2019	NUM
eurjchem-1915	8	30	printed	print	VERB
eurjchem-1915	8	31	:	:	PUNCT
eurjchem-1915	8	32	31	31	NUM
eurjchem-1915	8	33	december	december	PROPN
eurjchem-1915	8	34	2019	2019	NUM
eurjchem-1915	8	35	the	the	DET
eurjchem-1915	8	36	1,3	1,3	NUM
eurjchem-1915	8	37	-	-	PUNCT
eurjchem-1915	8	38	dipolar	dipolar	ADJ
eurjchem-1915	8	39	cycloaddition	cycloaddition	NOUN
eurjchem-1915	8	40	reaction	reaction	NOUN
eurjchem-1915	8	41	of	of	ADP
eurjchem-1915	8	42	bis	bis	ADJ
eurjchem-1915	8	43	-	-	ADJ
eurjchem-1915	8	44	hydrazonyl	hydrazonyl	ADJ
eurjchem-1915	8	45	chlorides	chloride	NOUN
eurjchem-1915	8	46	with	with	ADP
eurjchem-1915	8	47	methyl	methyl	NOUN
eurjchem-1915	8	48	propiolate	propiolate	NOUN
eurjchem-1915	8	49	afforded	afford	VERB
eurjchem-1915	8	50	dimethyl	dimethyl	NOUN
eurjchem-1915	8	51	1,1′-aryl-3,3`-bipyrazole-4,4`-dicarboxylates	1,1′-aryl-3,3`-bipyrazole-4,4`-dicarboxylates	NUM
eurjchem-1915	8	52	(	(	PUNCT
eurjchem-1915	8	53	5a	5a	NUM
eurjchem-1915	8	54	,	,	PUNCT
eurjchem-1915	8	55	b	b	NOUN
eurjchem-1915	8	56	)	)	PUNCT
eurjchem-1915	8	57	.	.	PUNCT
eurjchem-1915	9	1	heating	heat	VERB
eurjchem-1915	9	2	the	the	DET
eurjchem-1915	9	3	later	later	ADJ
eurjchem-1915	9	4	compound	compound	NOUN
eurjchem-1915	9	5	5a	5a	NUM
eurjchem-1915	9	6	with	with	ADP
eurjchem-1915	9	7	a	a	DET
eurjchem-1915	9	8	mixture	mixture	NOUN
eurjchem-1915	9	9	of	of	ADP
eurjchem-1915	9	10	hcl	hcl	PROPN
eurjchem-1915	9	11	/	/	SYM
eurjchem-1915	9	12	acoh	acoh	PROPN
eurjchem-1915	9	13	gave	give	VERB
eurjchem-1915	9	14	3,3`-bipyrazole-5,5`-dicarboxylic	3,3`-bipyrazole-5,5`-dicarboxylic	NUM
eurjchem-1915	9	15	acid	acid	NOUN
eurjchem-1915	9	16	derivative	derivative	ADJ
eurjchem-1915	9	17	6	6	NUM
eurjchem-1915	9	18	.	.	PUNCT
eurjchem-1915	10	1	treatment	treatment	NOUN
eurjchem-1915	10	2	of	of	ADP
eurjchem-1915	10	3	the	the	DET
eurjchem-1915	10	4	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	10	5	chloride	chloride	NOUN
eurjchem-1915	10	6	(	(	PUNCT
eurjchem-1915	10	7	1a	1a	NUM
eurjchem-1915	10	8	)	)	PUNCT
eurjchem-1915	10	9	and	and	CCONJ
eurjchem-1915	10	10	3,3`-bipyrazole-5,5`dicarboxylic	3,3`-bipyrazole-5,5`dicarboxylic	NOUN
eurjchem-1915	10	11	acid	acid	NOUN
eurjchem-1915	10	12	(	(	PUNCT
eurjchem-1915	10	13	6	6	NUM
eurjchem-1915	10	14	)	)	PUNCT
eurjchem-1915	10	15	with	with	ADP
eurjchem-1915	10	16	palladium(ii	palladium(ii	NOUN
eurjchem-1915	10	17	)	)	PUNCT
eurjchem-1915	10	18	chloride	chloride	NOUN
eurjchem-1915	10	19	gave	give	VERB
eurjchem-1915	10	20	the	the	DET
eurjchem-1915	10	21	corresponding	corresponding	ADJ
eurjchem-1915	10	22	pd	pd	NOUN
eurjchem-1915	10	23	-	-	PUNCT
eurjchem-1915	10	24	complexes	complex	NOUN
eurjchem-1915	10	25	7	7	NUM
eurjchem-1915	10	26	and	and	CCONJ
eurjchem-1915	10	27	8	8	NUM
eurjchem-1915	10	28	,	,	PUNCT
eurjchem-1915	10	29	respectively	respectively	ADV
eurjchem-1915	10	30	.	.	PUNCT
eurjchem-1915	11	1	the	the	DET
eurjchem-1915	11	2	catalytic	catalytic	ADJ
eurjchem-1915	11	3	activity	activity	NOUN
eurjchem-1915	11	4	of	of	ADP
eurjchem-1915	11	5	the	the	DET
eurjchem-1915	11	6	prepared	prepared	ADJ
eurjchem-1915	11	7	pd	pd	NOUN
eurjchem-1915	11	8	-	-	PUNCT
eurjchem-1915	11	9	complexes	complex	NOUN
eurjchem-1915	11	10	was	be	AUX
eurjchem-1915	11	11	examined	examine	VERB
eurjchem-1915	11	12	in	in	ADP
eurjchem-1915	11	13	the	the	DET
eurjchem-1915	11	14	suzuki	suzuki	PROPN
eurjchem-1915	11	15	cross	cross	PROPN
eurjchem-1915	11	16	-	-	ADJ
eurjchem-1915	11	17	coupling	coupling	ADJ
eurjchem-1915	11	18	reaction	reaction	NOUN
eurjchem-1915	11	19	of	of	ADP
eurjchem-1915	11	20	phenylboronic	phenylboronic	ADJ
eurjchem-1915	11	21	acid	acid	NOUN
eurjchem-1915	11	22	with	with	ADP
eurjchem-1915	11	23	activated	activate	VERB
eurjchem-1915	11	24	and	and	CCONJ
eurjchem-1915	11	25	deactivated	deactivate	VERB
eurjchem-1915	11	26	aryl(hetaryl	aryl(hetaryl	PROPN
eurjchem-1915	11	27	)	)	PUNCT
eurjchem-1915	11	28	bromides	bromide	NOUN
eurjchem-1915	11	29	.	.	PUNCT
eurjchem-1915	12	1	the	the	DET
eurjchem-1915	12	2	catalyst	catalyst	NOUN
eurjchem-1915	12	3	system	system	NOUN
eurjchem-1915	12	4	provides	provide	VERB
eurjchem-1915	12	5	very	very	ADV
eurjchem-1915	12	6	good	good	ADJ
eurjchem-1915	12	7	to	to	ADP
eurjchem-1915	12	8	excellent	excellent	ADJ
eurjchem-1915	12	9	yields	yield	NOUN
eurjchem-1915	12	10	,	,	PUNCT
eurjchem-1915	12	11	85	85	NUM
eurjchem-1915	12	12	-	-	SYM
eurjchem-1915	12	13	94	94	NUM
eurjchem-1915	12	14	%	%	NOUN
eurjchem-1915	12	15	.	.	PUNCT
eurjchem-1915	13	1	the	the	DET
eurjchem-1915	13	2	structures	structure	NOUN
eurjchem-1915	13	3	of	of	ADP
eurjchem-1915	13	4	the	the	DET
eurjchem-1915	13	5	obtained	obtain	VERB
eurjchem-1915	13	6	products	product	NOUN
eurjchem-1915	13	7	were	be	AUX
eurjchem-1915	13	8	established	establish	VERB
eurjchem-1915	13	9	from	from	ADP
eurjchem-1915	13	10	their	their	PRON
eurjchem-1915	13	11	elemental	elemental	ADJ
eurjchem-1915	13	12	analysis	analysis	NOUN
eurjchem-1915	13	13	,	,	PUNCT
eurjchem-1915	13	14	spectral	spectral	ADJ
eurjchem-1915	13	15	data	data	PROPN
eurjchem-1915	13	16	,	,	PUNCT
eurjchem-1915	13	17	xps	xps	PROPN
eurjchem-1915	13	18	,	,	PUNCT
eurjchem-1915	13	19	edx	edx	PROPN
eurjchem-1915	13	20	,	,	PUNCT
eurjchem-1915	13	21	and	and	CCONJ
eurjchem-1915	13	22	single	single	ADJ
eurjchem-1915	13	23	crystal	crystal	NOUN
eurjchem-1915	13	24	x	x	PROPN
eurjchem-1915	13	25	-	-	NOUN
eurjchem-1915	13	26	ray	ray	NOUN
eurjchem-1915	13	27	crystallography	crystallography	NOUN
eurjchem-1915	13	28	.	.	PUNCT
eurjchem-1915	14	1	crystal	crystal	NOUN
eurjchem-1915	14	2	data	datum	NOUN
eurjchem-1915	14	3	for	for	ADP
eurjchem-1915	14	4	c10h7n2o2	c10h7n2o2	NOUN
eurjchem-1915	14	5	(	(	PUNCT
eurjchem-1915	14	6	6	6	NUM
eurjchem-1915	14	7	):	):	PUNCT
eurjchem-1915	14	8	triclinic	triclinic	ADJ
eurjchem-1915	14	9	,	,	PUNCT
eurjchem-1915	14	10	space	space	NOUN
eurjchem-1915	14	11	group	group	NOUN
eurjchem-1915	14	12	p-1	p-1	NOUN
eurjchem-1915	14	13	(	(	PUNCT
eurjchem-1915	14	14	no	no	INTJ
eurjchem-1915	14	15	.	.	NOUN
eurjchem-1915	14	16	2	2	NUM
eurjchem-1915	14	17	)	)	PUNCT
eurjchem-1915	14	18	,	,	PUNCT
eurjchem-1915	14	19	a	a	DET
eurjchem-1915	14	20	=	=	NOUN
eurjchem-1915	14	21	3.9956(10	3.9956(10	NUM
eurjchem-1915	14	22	)	)	PUNCT
eurjchem-1915	14	23	å	å	NOUN
eurjchem-1915	14	24	,	,	PUNCT
eurjchem-1915	14	25	b	b	X
eurjchem-1915	14	26	=	=	SYM
eurjchem-1915	14	27	9.8917(18	9.8917(18	NUM
eurjchem-1915	14	28	)	)	PUNCT
eurjchem-1915	14	29	å	å	NOUN
eurjchem-1915	14	30	,	,	PUNCT
eurjchem-1915	14	31	c	c	NOUN
eurjchem-1915	14	32	=	=	SYM
eurjchem-1915	14	33	10.810(3	10.810(3	NOUN
eurjchem-1915	14	34	)	)	PUNCT
eurjchem-1915	15	1	å	å	PROPN
eurjchem-1915	15	2	,	,	PUNCT
eurjchem-1915	15	3	α	α	NOUN
eurjchem-1915	15	4	=	=	SYM
eurjchem-1915	15	5	94.167(15	94.167(15	NUM
eurjchem-1915	15	6	)	)	PUNCT
eurjchem-1915	15	7	°	°	NOUN
eurjchem-1915	15	8	,	,	PUNCT
eurjchem-1915	15	9	β	β	X
eurjchem-1915	15	10	=	=	SYM
eurjchem-1915	15	11	94.979(19	94.979(19	NUM
eurjchem-1915	15	12	)	)	PUNCT
eurjchem-1915	15	13	°	°	PROPN
eurjchem-1915	15	14	,	,	PUNCT
eurjchem-1915	15	15	γ	γ	NOUN
eurjchem-1915	15	16	=	=	SYM
eurjchem-1915	15	17	98.953(15	98.953(15	NUM
eurjchem-1915	15	18	)	)	PUNCT
eurjchem-1915	15	19	°	°	NOUN
eurjchem-1915	15	20	,	,	PUNCT
eurjchem-1915	15	21	v	v	NOUN
eurjchem-1915	15	22	=	=	SYM
eurjchem-1915	15	23	418.83(16	418.83(16	NUM
eurjchem-1915	15	24	)	)	PUNCT
eurjchem-1915	15	25	å3	å3	PROPN
eurjchem-1915	15	26	,	,	PUNCT
eurjchem-1915	15	27	z	z	NOUN
eurjchem-1915	15	28	=	=	SYM
eurjchem-1915	15	29	2	2	NUM
eurjchem-1915	15	30	,	,	PUNCT
eurjchem-1915	15	31	t	t	NOUN
eurjchem-1915	15	32	=	=	SYM
eurjchem-1915	15	33	296.(2	296.(2	NUM
eurjchem-1915	15	34	)	)	PUNCT
eurjchem-1915	16	1	k	k	NOUN
eurjchem-1915	16	2	,	,	PUNCT
eurjchem-1915	16	3	μ(cu	μ(cu	PROPN
eurjchem-1915	16	4	kα	kα	PROPN
eurjchem-1915	16	5	)	)	PUNCT
eurjchem-1915	16	6	=	=	PUNCT
eurjchem-1915	16	7	0.887	0.887	NUM
eurjchem-1915	16	8	mm-1	mm-1	SYM
eurjchem-1915	16	9	,	,	PUNCT
eurjchem-1915	16	10	dcalc	dcalc	NOUN
eurjchem-1915	16	11	=	=	PUNCT
eurjchem-1915	16	12	1.484	1.484	NUM
eurjchem-1915	16	13	g	g	NOUN
eurjchem-1915	16	14	/	/	SYM
eurjchem-1915	16	15	cm3	cm3	NOUN
eurjchem-1915	16	16	,	,	PUNCT
eurjchem-1915	16	17	5469	5469	NUM
eurjchem-1915	16	18	reflections	reflection	NOUN
eurjchem-1915	16	19	measured	measure	VERB
eurjchem-1915	16	20	(	(	PUNCT
eurjchem-1915	16	21	11.72	11.72	NUM
eurjchem-1915	16	22	°	°	NOUN
eurjchem-1915	16	23	≤	≤	NUM
eurjchem-1915	16	24	2θ	2θ	NUM
eurjchem-1915	16	25	≤	≤	NUM
eurjchem-1915	16	26	133.24	133.24	NUM
eurjchem-1915	16	27	°	°	NOUN
eurjchem-1915	16	28	)	)	PUNCT
eurjchem-1915	16	29	,	,	PUNCT
eurjchem-1915	16	30	1420	1420	NUM
eurjchem-1915	16	31	unique	unique	ADJ
eurjchem-1915	16	32	(	(	PUNCT
eurjchem-1915	16	33	rint	rint	NOUN
eurjchem-1915	16	34	=	=	SYM
eurjchem-1915	16	35	0.0633	0.0633	NUM
eurjchem-1915	16	36	,	,	PUNCT
eurjchem-1915	16	37	rsigma	rsigma	ADJ
eurjchem-1915	16	38	=	=	PUNCT
eurjchem-1915	16	39	7.24	7.24	NUM
eurjchem-1915	16	40	%	%	NOUN
eurjchem-1915	16	41	)	)	PUNCT
eurjchem-1915	16	42	which	which	PRON
eurjchem-1915	16	43	were	be	AUX
eurjchem-1915	16	44	used	use	VERB
eurjchem-1915	16	45	in	in	ADP
eurjchem-1915	16	46	all	all	DET
eurjchem-1915	16	47	calculations	calculation	NOUN
eurjchem-1915	16	48	.	.	PUNCT
eurjchem-1915	17	1	the	the	DET
eurjchem-1915	17	2	final	final	ADJ
eurjchem-1915	17	3	r1	r1	PROPN
eurjchem-1915	17	4	was	be	AUX
eurjchem-1915	17	5	0.1055	0.1055	NUM
eurjchem-1915	17	6	(	(	PUNCT
eurjchem-1915	17	7	>	>	X
eurjchem-1915	17	8	2sigma(i	2sigma(i	NUM
eurjchem-1915	17	9	)	)	PUNCT
eurjchem-1915	17	10	)	)	PUNCT
eurjchem-1915	18	1	and	and	CCONJ
eurjchem-1915	18	2	wr2	wr2	PROPN
eurjchem-1915	18	3	was	be	AUX
eurjchem-1915	18	4	0.3620	0.3620	NUM
eurjchem-1915	18	5	(	(	PUNCT
eurjchem-1915	18	6	all	all	DET
eurjchem-1915	18	7	data	datum	NOUN
eurjchem-1915	18	8	)	)	PUNCT
eurjchem-1915	18	9	.	.	PUNCT
eurjchem-1915	19	1	bipyrazoles	bipyrazole	NOUN
eurjchem-1915	19	2	c	c	NOUN
eurjchem-1915	19	3	-	-	PUNCT
eurjchem-1915	19	4	c	c	NOUN
eurjchem-1915	19	5	coupling	couple	VERB
eurjchem-1915	19	6	heterocycles	heterocycles	ADJ
eurjchem-1915	19	7	pd	pd	NOUN
eurjchem-1915	19	8	-	-	PUNCT
eurjchem-1915	19	9	complexes	complex	NOUN
eurjchem-1915	19	10	x	x	ADJ
eurjchem-1915	19	11	-	-	NOUN
eurjchem-1915	19	12	ray	ray	ADJ
eurjchem-1915	19	13	single	single	ADJ
eurjchem-1915	19	14	crystal	crystal	PROPN
eurjchem-1915	19	15	bis	bis	ADJ
eurjchem-1915	19	16	-	-	ADJ
eurjchem-1915	19	17	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	19	18	chlorides	chloride	NOUN
eurjchem-1915	19	19	cite	cite	VERB
eurjchem-1915	19	20	this	this	PRON
eurjchem-1915	19	21	:	:	PUNCT
eurjchem-1915	19	22	eur	eur	PROPN
eurjchem-1915	19	23	.	.	PUNCT
eurjchem-1915	20	1	j.	j.	PROPN
eurjchem-1915	20	2	chem	chem	PROPN
eurjchem-1915	20	3	.	.	PUNCT
eurjchem-1915	21	1	2019	2019	NUM
eurjchem-1915	21	2	,	,	PUNCT
eurjchem-1915	21	3	10(4	10(4	NUM
eurjchem-1915	21	4	)	)	PUNCT
eurjchem-1915	21	5	,	,	PUNCT
eurjchem-1915	21	6	367	367	NUM
eurjchem-1915	21	7	-	-	SYM
eurjchem-1915	21	8	375	375	NUM
eurjchem-1915	21	9	journal	journal	NOUN
eurjchem-1915	21	10	website	website	NOUN
eurjchem-1915	21	11	:	:	PUNCT
eurjchem-1915	21	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-1915	21	13	1	1	X
eurjchem-1915	21	14	.	.	PUNCT
eurjchem-1915	22	1	introduction	introduction	NOUN
eurjchem-1915	22	2	pyrazoles	pyrazole	VERB
eurjchem-1915	22	3	,	,	PUNCT
eurjchem-1915	22	4	as	as	ADP
eurjchem-1915	22	5	a	a	DET
eurjchem-1915	22	6	class	class	NOUN
eurjchem-1915	22	7	of	of	ADP
eurjchem-1915	22	8	multi	multi	ADJ
eurjchem-1915	22	9	-	-	ADJ
eurjchem-1915	22	10	donor	donor	ADJ
eurjchem-1915	22	11	nitrogen	nitrogen	NOUN
eurjchem-1915	22	12	ligands	ligand	NOUN
eurjchem-1915	22	13	with	with	ADP
eurjchem-1915	22	14	changing	change	VERB
eurjchem-1915	22	15	coordination	coordination	NOUN
eurjchem-1915	22	16	patterns	pattern	NOUN
eurjchem-1915	22	17	,	,	PUNCT
eurjchem-1915	22	18	has	have	AUX
eurjchem-1915	22	19	played	play	VERB
eurjchem-1915	22	20	important	important	ADJ
eurjchem-1915	22	21	roles	role	NOUN
eurjchem-1915	22	22	in	in	ADP
eurjchem-1915	22	23	organometallic	organometallic	ADJ
eurjchem-1915	22	24	,	,	PUNCT
eurjchem-1915	22	25	inorganic	inorganic	ADJ
eurjchem-1915	22	26	and	and	CCONJ
eurjchem-1915	22	27	materials	material	NOUN
eurjchem-1915	22	28	chemistry	chemistry	NOUN
eurjchem-1915	22	29	and	and	CCONJ
eurjchem-1915	22	30	were	be	AUX
eurjchem-1915	22	31	also	also	ADV
eurjchem-1915	22	32	used	use	VERB
eurjchem-1915	22	33	to	to	PART
eurjchem-1915	22	34	establish	establish	VERB
eurjchem-1915	22	35	pyrazolyl	pyrazolyl	ADV
eurjchem-1915	22	36	-	-	PUNCT
eurjchem-1915	22	37	bridged	bridge	VERB
eurjchem-1915	22	38	multi	multi	ADJ
eurjchem-1915	22	39	-	-	ADJ
eurjchem-1915	22	40	metal	metal	ADJ
eurjchem-1915	22	41	and	and	CCONJ
eurjchem-1915	22	42	metal	metal	NOUN
eurjchem-1915	22	43	-	-	PUNCT
eurjchem-1915	22	44	metal	metal	NOUN
eurjchem-1915	22	45	bonding	bonding	NOUN
eurjchem-1915	22	46	coordination	coordination	NOUN
eurjchem-1915	22	47	systems	system	NOUN
eurjchem-1915	22	48	[	[	X
eurjchem-1915	22	49	1,2	1,2	NUM
eurjchem-1915	22	50	]	]	PUNCT
eurjchem-1915	22	51	.	.	PUNCT
eurjchem-1915	23	1	chemistry	chemistry	NOUN
eurjchem-1915	23	2	of	of	ADP
eurjchem-1915	23	3	the	the	DET
eurjchem-1915	23	4	coordination	coordination	NOUN
eurjchem-1915	23	5	of	of	ADP
eurjchem-1915	23	6	pyrazole	pyrazole	NOUN
eurjchem-1915	23	7	and	and	CCONJ
eurjchem-1915	23	8	its	its	PRON
eurjchem-1915	23	9	derivatives	derivative	NOUN
eurjchem-1915	23	10	have	have	AUX
eurjchem-1915	23	11	received	receive	VERB
eurjchem-1915	23	12	special	special	ADJ
eurjchem-1915	23	13	attention	attention	NOUN
eurjchem-1915	23	14	because	because	SCONJ
eurjchem-1915	23	15	of	of	ADP
eurjchem-1915	23	16	its	its	PRON
eurjchem-1915	23	17	structural	structural	ADJ
eurjchem-1915	23	18	diversity	diversity	NOUN
eurjchem-1915	23	19	,	,	PUNCT
eurjchem-1915	23	20	such	such	ADJ
eurjchem-1915	23	21	as	as	ADP
eurjchem-1915	23	22	metal	metal	NOUN
eurjchem-1915	23	23	-	-	PUNCT
eurjchem-1915	23	24	based	base	VERB
eurjchem-1915	23	25	polymers	polymer	NOUN
eurjchem-1915	23	26	,	,	PUNCT
eurjchem-1915	23	27	[	[	X
eurjchem-1915	23	28	3,4	3,4	NUM
eurjchem-1915	23	29	]	]	PUNCT
eurjchem-1915	23	30	.	.	PUNCT
eurjchem-1915	24	1	furthermore	furthermore	ADV
eurjchem-1915	24	2	,	,	PUNCT
eurjchem-1915	24	3	pyrazole	pyrazole	NOUN
eurjchem-1915	24	4	-	-	PUNCT
eurjchem-1915	24	5	based	base	VERB
eurjchem-1915	24	6	palladium(ii	palladium(ii	NOUN
eurjchem-1915	24	7	)	)	PUNCT
eurjchem-1915	24	8	complexes	complex	NOUN
eurjchem-1915	24	9	were	be	AUX
eurjchem-1915	24	10	reported	report	VERB
eurjchem-1915	24	11	as	as	ADP
eurjchem-1915	24	12	examples	example	NOUN
eurjchem-1915	24	13	for	for	ADP
eurjchem-1915	24	14	interesting	interesting	ADJ
eurjchem-1915	24	15	coordination	coordination	NOUN
eurjchem-1915	24	16	chemistry	chemistry	NOUN
eurjchem-1915	24	17	[	[	X
eurjchem-1915	24	18	5	5	NUM
eurjchem-1915	24	19	-	-	SYM
eurjchem-1915	24	20	7	7	NUM
eurjchem-1915	24	21	]	]	PUNCT
eurjchem-1915	24	22	.	.	PUNCT
eurjchem-1915	25	1	pyrazolyl	pyrazolyl	ADJ
eurjchem-1915	25	2	palladium	palladium	NOUN
eurjchem-1915	25	3	complexes	complex	NOUN
eurjchem-1915	25	4	proved	prove	VERB
eurjchem-1915	25	5	to	to	PART
eurjchem-1915	25	6	be	be	AUX
eurjchem-1915	25	7	efficient	efficient	ADJ
eurjchem-1915	25	8	catalysts	catalyst	NOUN
eurjchem-1915	25	9	for	for	ADP
eurjchem-1915	25	10	cross	cross	ADJ
eurjchem-1915	25	11	-	-	ADJ
eurjchem-1915	25	12	coupling	coupling	ADJ
eurjchem-1915	25	13	reactions	reaction	NOUN
eurjchem-1915	25	14	[	[	X
eurjchem-1915	25	15	8,9	8,9	NUM
eurjchem-1915	25	16	]	]	PUNCT
eurjchem-1915	25	17	.	.	PUNCT
eurjchem-1915	26	1	besides	besides	ADV
eurjchem-1915	26	2	,	,	PUNCT
eurjchem-1915	26	3	pyrazoline	pyrazoline	NOUN
eurjchem-1915	26	4	ligands	ligand	NOUN
eurjchem-1915	26	5	coordinated	coordinate	VERB
eurjchem-1915	26	6	to	to	PART
eurjchem-1915	26	7	palladium(ii	palladium(ii	VERB
eurjchem-1915	26	8	)	)	PUNCT
eurjchem-1915	26	9	were	be	AUX
eurjchem-1915	26	10	also	also	ADV
eurjchem-1915	26	11	assigned	assign	VERB
eurjchem-1915	26	12	as	as	ADP
eurjchem-1915	26	13	very	very	ADV
eurjchem-1915	26	14	efficient	efficient	ADJ
eurjchem-1915	26	15	dna	dna	NOUN
eurjchem-1915	26	16	intercalator	intercalator	NOUN
eurjchem-1915	26	17	and	and	CCONJ
eurjchem-1915	26	18	artificial	artificial	ADJ
eurjchem-1915	26	19	metallonuclease	metallonuclease	NOUN
eurjchem-1915	27	1	[	[	X
eurjchem-1915	27	2	10	10	NUM
eurjchem-1915	27	3	]	]	PUNCT
eurjchem-1915	27	4	.	.	PUNCT
eurjchem-1915	28	1	bipyrazoles	bipyrazole	NOUN
eurjchem-1915	28	2	were	be	AUX
eurjchem-1915	28	3	found	find	VERB
eurjchem-1915	28	4	to	to	PART
eurjchem-1915	28	5	be	be	AUX
eurjchem-1915	28	6	potential	potential	ADJ
eurjchem-1915	28	7	bioactive	bioactive	ADJ
eurjchem-1915	28	8	compounds	compound	NOUN
eurjchem-1915	29	1	[	[	X
eurjchem-1915	29	2	11	11	NUM
eurjchem-1915	29	3	]	]	PUNCT
eurjchem-1915	29	4	,	,	PUNCT
eurjchem-1915	29	5	where	where	SCONJ
eurjchem-1915	29	6	they	they	PRON
eurjchem-1915	29	7	were	be	AUX
eurjchem-1915	29	8	reported	report	VERB
eurjchem-1915	29	9	to	to	PART
eurjchem-1915	29	10	have	have	VERB
eurjchem-1915	29	11	antitumor	antitumor	PROPN
eurjchem-1915	30	1	[	[	X
eurjchem-1915	30	2	12	12	NUM
eurjchem-1915	30	3	]	]	PUNCT
eurjchem-1915	30	4	,	,	PUNCT
eurjchem-1915	30	5	anti	anti	ADJ
eurjchem-1915	30	6	-	-	ADJ
eurjchem-1915	30	7	inflammatory	inflammatory	ADJ
eurjchem-1915	30	8	[	[	X
eurjchem-1915	30	9	13	13	NUM
eurjchem-1915	30	10	]	]	PUNCT
eurjchem-1915	30	11	,	,	PUNCT
eurjchem-1915	30	12	antimicrobial	antimicrobial	ADJ
eurjchem-1915	30	13	[	[	X
eurjchem-1915	30	14	14	14	NUM
eurjchem-1915	30	15	]	]	PUNCT
eurjchem-1915	30	16	and	and	CCONJ
eurjchem-1915	30	17	cytotoxic	cytotoxic	ADJ
eurjchem-1915	30	18	[	[	X
eurjchem-1915	30	19	15	15	NUM
eurjchem-1915	30	20	]	]	ADJ
eurjchem-1915	30	21	activities	activity	NOUN
eurjchem-1915	30	22	and	and	CCONJ
eurjchem-1915	30	23	scavengers	scavenger	NOUN
eurjchem-1915	30	24	for	for	ADP
eurjchem-1915	30	25	free	free	ADJ
eurjchem-1915	30	26	radicals	radical	NOUN
eurjchem-1915	30	27	[	[	X
eurjchem-1915	30	28	16	16	NUM
eurjchem-1915	30	29	]	]	PUNCT
eurjchem-1915	30	30	.	.	PUNCT
eurjchem-1915	31	1	further	far	ADV
eurjchem-1915	31	2	,	,	PUNCT
eurjchem-1915	31	3	pyrazole	pyrazole	VERB
eurjchem-1915	31	4	scaffold	scaffold	NOUN
eurjchem-1915	31	5	is	be	AUX
eurjchem-1915	31	6	a	a	DET
eurjchem-1915	31	7	component	component	NOUN
eurjchem-1915	31	8	of	of	ADP
eurjchem-1915	31	9	some	some	DET
eurjchem-1915	31	10	commercial	commercial	ADJ
eurjchem-1915	31	11	drugs	drug	NOUN
eurjchem-1915	31	12	in	in	ADP
eurjchem-1915	31	13	the	the	DET
eurjchem-1915	31	14	market	market	NOUN
eurjchem-1915	31	15	such	such	ADJ
eurjchem-1915	31	16	as	as	ADP
eurjchem-1915	31	17	celecoxib	celecoxib	NOUN
eurjchem-1915	31	18	and	and	CCONJ
eurjchem-1915	31	19	rimonabant	rimonabant	ADJ
eurjchem-1915	31	20	[	[	X
eurjchem-1915	31	21	17,18	17,18	NUM
eurjchem-1915	31	22	]	]	X
eurjchem-1915	31	23	.	.	PUNCT
eurjchem-1915	32	1	1,3	1,3	NUM
eurjchem-1915	32	2	-	-	PUNCT
eurjchem-1915	32	3	dipolar	dipolar	ADJ
eurjchem-1915	32	4	cycloaddition	cycloaddition	NOUN
eurjchem-1915	32	5	was	be	AUX
eurjchem-1915	32	6	reported	report	VERB
eurjchem-1915	32	7	as	as	ADP
eurjchem-1915	32	8	one	one	NUM
eurjchem-1915	32	9	of	of	ADP
eurjchem-1915	32	10	the	the	DET
eurjchem-1915	32	11	most	most	ADV
eurjchem-1915	32	12	valuable	valuable	ADJ
eurjchem-1915	32	13	synthetic	synthetic	ADJ
eurjchem-1915	32	14	routes	route	NOUN
eurjchem-1915	32	15	for	for	ADP
eurjchem-1915	32	16	the	the	DET
eurjchem-1915	32	17	construction	construction	NOUN
eurjchem-1915	32	18	of	of	ADP
eurjchem-1915	32	19	pyrazole	pyrazole	NOUN
eurjchem-1915	32	20	heterocycles	heterocycle	NOUN
eurjchem-1915	32	21	[	[	X
eurjchem-1915	32	22	19,20	19,20	X
eurjchem-1915	32	23	]	]	PUNCT
eurjchem-1915	32	24	.	.	PUNCT
eurjchem-1915	33	1	in	in	ADP
eurjchem-1915	33	2	continuation	continuation	NOUN
eurjchem-1915	33	3	of	of	ADP
eurjchem-1915	33	4	our	our	PRON
eurjchem-1915	33	5	research	research	NOUN
eurjchem-1915	33	6	work	work	NOUN
eurjchem-1915	33	7	about	about	ADP
eurjchem-1915	33	8	bis	bis	ADJ
eurjchem-1915	33	9	-	-	ADJ
eurjchem-1915	33	10	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	33	11	chlorides	chloride	NOUN
eurjchem-1915	33	12	[	[	PUNCT
eurjchem-1915	33	13	21	21	NUM
eurjchem-1915	33	14	-	-	SYM
eurjchem-1915	33	15	24	24	NUM
eurjchem-1915	33	16	]	]	PUNCT
eurjchem-1915	33	17	,	,	PUNCT
eurjchem-1915	33	18	we	we	PRON
eurjchem-1915	33	19	report	report	VERB
eurjchem-1915	33	20	herein	herein	ADJ
eurjchem-1915	33	21	the	the	DET
eurjchem-1915	33	22	hitherto	hitherto	NOUN
eurjchem-1915	33	23	unreported	unreporte	VERB
eurjchem-1915	33	24	regioselective	regioselective	ADJ
eurjchem-1915	33	25	double	double	ADJ
eurjchem-1915	33	26	1,3	1,3	NUM
eurjchem-1915	33	27	-	-	PUNCT
eurjchem-1915	33	28	dipolar	dipolar	ADJ
eurjchem-1915	33	29	cycloaddition	cycloaddition	NOUN
eurjchem-1915	33	30	of	of	ADP
eurjchem-1915	33	31	the	the	DET
eurjchem-1915	33	32	bis	bis	ADJ
eurjchem-1915	33	33	-	-	ADJ
eurjchem-1915	33	34	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	33	35	chlorides	chloride	NOUN
eurjchem-1915	33	36	(	(	PUNCT
eurjchem-1915	33	37	1a	1a	NUM
eurjchem-1915	33	38	,	,	PUNCT
eurjchem-1915	33	39	b	b	NOUN
eurjchem-1915	33	40	)	)	PUNCT
eurjchem-1915	33	41	with	with	ADP
eurjchem-1915	33	42	methyl	methyl	NOUN
eurjchem-1915	33	43	propiolate	propiolate	NOUN
eurjchem-1915	33	44	followed	follow	VERB
eurjchem-1915	33	45	by	by	ADP
eurjchem-1915	33	46	acid	acid	ADJ
eurjchem-1915	33	47	hydrolysis	hydrolysis	NOUN
eurjchem-1915	33	48	of	of	ADP
eurjchem-1915	33	49	one	one	NUM
eurjchem-1915	33	50	of	of	ADP
eurjchem-1915	33	51	the	the	DET
eurjchem-1915	33	52	products	product	NOUN
eurjchem-1915	33	53	and	and	CCONJ
eurjchem-1915	33	54	its	its	PRON
eurjchem-1915	33	55	reaction	reaction	NOUN
eurjchem-1915	33	56	with	with	ADP
eurjchem-1915	33	57	palladium(ii	palladium(ii	NOUN
eurjchem-1915	33	58	)	)	PUNCT
eurjchem-1915	33	59	chloride	chloride	NOUN
eurjchem-1915	33	60	and	and	CCONJ
eurjchem-1915	33	61	with	with	ADP
eurjchem-1915	33	62	urea	urea	NOUN
eurjchem-1915	33	63	.	.	PUNCT
eurjchem-1915	34	1	the	the	DET
eurjchem-1915	34	2	regioselectivity	regioselectivity	NOUN
eurjchem-1915	34	3	of	of	ADP
eurjchem-1915	34	4	the	the	DET
eurjchem-1915	34	5	obtained	obtain	VERB
eurjchem-1915	34	6	structures	structure	NOUN
eurjchem-1915	34	7	was	be	AUX
eurjchem-1915	34	8	confirmed	confirm	VERB
eurjchem-1915	34	9	from	from	ADP
eurjchem-1915	34	10	the	the	DET
eurjchem-1915	34	11	single	single	ADJ
eurjchem-1915	34	12	crystal	crystal	NOUN
eurjchem-1915	34	13	x	x	PROPN
eurjchem-1915	34	14	-	-	NOUN
eurjchem-1915	34	15	ray	ray	NOUN
eurjchem-1915	34	16	analysis	analysis	NOUN
eurjchem-1915	34	17	.	.	PUNCT
eurjchem-1915	35	1	applications	application	NOUN
eurjchem-1915	35	2	of	of	ADP
eurjchem-1915	35	3	the	the	DET
eurjchem-1915	35	4	palladium(ii	palladium(ii	NOUN
eurjchem-1915	35	5	)	)	PUNCT
eurjchem-1915	35	6	complex	complex	NOUN
eurjchem-1915	35	7	in	in	ADP
eurjchem-1915	35	8	suzuki	suzuki	PROPN
eurjchem-1915	35	9	cross	cross	PROPN
eurjchem-1915	35	10	-	-	ADJ
eurjchem-1915	35	11	coupling	coupling	NOUN
eurjchem-1915	35	12	was	be	AUX
eurjchem-1915	35	13	also	also	ADV
eurjchem-1915	35	14	examined	examine	VERB
eurjchem-1915	35	15	.	.	PUNCT
eurjchem-1915	36	1	2	2	X
eurjchem-1915	36	2	.	.	X
eurjchem-1915	36	3	experimental	experimental	ADJ
eurjchem-1915	36	4	2.1	2.1	NUM
eurjchem-1915	36	5	.	.	PUNCT
eurjchem-1915	37	1	instrumentations	instrumentation	NOUN
eurjchem-1915	37	2	melting	melt	VERB
eurjchem-1915	37	3	points	point	NOUN
eurjchem-1915	37	4	were	be	AUX
eurjchem-1915	37	5	measured	measure	VERB
eurjchem-1915	37	6	on	on	ADP
eurjchem-1915	37	7	a	a	DET
eurjchem-1915	37	8	gallenkamp	gallenkamp	NOUN
eurjchem-1915	37	9	melting	melting	NOUN
eurjchem-1915	37	10	point	point	NOUN
eurjchem-1915	37	11	apparatus	apparatus	NOUN
eurjchem-1915	37	12	.	.	PUNCT
eurjchem-1915	38	1	ir	ir	PROPN
eurjchem-1915	38	2	spectra	spectra	PROPN
eurjchem-1915	38	3	were	be	AUX
eurjchem-1915	38	4	recorded	record	VERB
eurjchem-1915	38	5	using	use	VERB
eurjchem-1915	38	6	kbr	kbr	PROPN
eurjchem-1915	38	7	disks	disk	NOUN
eurjchem-1915	38	8	using	use	VERB
eurjchem-1915	38	9	a	a	DET
eurjchem-1915	38	10	perkin	perkin	PROPN
eurjchem-1915	38	11	-	-	PUNCT
eurjchem-1915	38	12	elmer	elmer	NOUN
eurjchem-1915	38	13	system	system	NOUN
eurjchem-1915	38	14	2000	2000	NUM
eurjchem-1915	38	15	ft	ft	NOUN
eurjchem-1915	38	16	-	-	PUNCT
eurjchem-1915	38	17	ir	ir	NOUN
eurjchem-1915	38	18	spectrophotometer	spectrophotometer	NOUN
eurjchem-1915	38	19	.	.	PUNCT
eurjchem-1915	39	1	1h	1h	NUM
eurjchem-1915	39	2	nmr	nmr	NOUN
eurjchem-1915	39	3	(	(	PUNCT
eurjchem-1915	39	4	400	400	NUM
eurjchem-1915	39	5	mhz	mhz	NOUN
eurjchem-1915	39	6	)	)	PUNCT
eurjchem-1915	39	7	and	and	CCONJ
eurjchem-1915	39	8	13c	13c	NOUN
eurjchem-1915	39	9	nmr	nmr	NOUN
eurjchem-1915	39	10	(	(	PUNCT
eurjchem-1915	39	11	100	100	NUM
eurjchem-1915	39	12	mhz	mhz	NOUN
eurjchem-1915	39	13	)	)	PUNCT
eurjchem-1915	39	14	spectra	spectra	NOUN
eurjchem-1915	39	15	were	be	AUX
eurjchem-1915	39	16	recorded	record	VERB
eurjchem-1915	39	17	at	at	ADP
eurjchem-1915	39	18	25	25	NUM
eurjchem-1915	39	19	°	°	NOUN
eurjchem-1915	39	20	c	c	NOUN
eurjchem-1915	39	21	using	use	VERB
eurjchem-1915	39	22	dmso	dmso	NOUN
eurjchem-1915	39	23	-	-	PUNCT
eurjchem-1915	39	24	d6	d6	NOUN
eurjchem-1915	39	25	as	as	ADP
eurjchem-1915	39	26	a	a	DET
eurjchem-1915	39	27	solvent	solvent	NOUN
eurjchem-1915	39	28	with	with	ADP
eurjchem-1915	39	29	tms	tms	PROPN
eurjchem-1915	39	30	as	as	ADP
eurjchem-1915	39	31	internal	internal	ADJ
eurjchem-1915	39	32	standard	standard	NOUN
eurjchem-1915	39	33	on	on	ADP
eurjchem-1915	39	34	a	a	DET
eurjchem-1915	39	35	bruker	bruker	NOUN
eurjchem-1915	39	36	dpx	dpx	NOUN
eurjchem-1915	39	37	400	400	NUM
eurjchem-1915	39	38	or	or	CCONJ
eurjchem-1915	39	39	600	600	NUM
eurjchem-1915	39	40	superconducting	superconducte	VERB
eurjchem-1915	39	41	nmr	nmr	NOUN
eurjchem-1915	39	42	spectrometer	spectrometer	NOUN
eurjchem-1915	39	43	.	.	PUNCT
eurjchem-1915	40	1	chemical	chemical	ADJ
eurjchem-1915	40	2	shifts	shift	NOUN
eurjchem-1915	40	3	are	be	AUX
eurjchem-1915	40	4	reported	report	VERB
eurjchem-1915	40	5	in	in	ADP
eurjchem-1915	40	6	ppm	ppm	NOUN
eurjchem-1915	40	7	.	.	PUNCT
eurjchem-1915	41	1	abstract	abstract	ADJ
eurjchem-1915	41	2	research	research	NOUN
eurjchem-1915	41	3	article	article	NOUN
eurjchem-1915	41	4	keywords	keyword	VERB
eurjchem-1915	41	5	european	european	PROPN
eurjchem-1915	41	6	journal	journal	PROPN
eurjchem-1915	41	7	of	of	ADP
eurjchem-1915	41	8	chemistry	chemistry	NOUN
eurjchem-1915	41	9	issn	issn	VERB
eurjchem-1915	41	10	2153	2153	NUM
eurjchem-1915	41	11	-	-	SYM
eurjchem-1915	41	12	2249	2249	NUM
eurjchem-1915	41	13	(	(	PUNCT
eurjchem-1915	41	14	print	print	NOUN
eurjchem-1915	41	15	)	)	PUNCT
eurjchem-1915	41	16	/	/	PUNCT
eurjchem-1915	41	17	issn	issn	PROPN
eurjchem-1915	41	18	2153	2153	NUM
eurjchem-1915	41	19	-	-	SYM
eurjchem-1915	41	20	2257	2257	NUM
eurjchem-1915	41	21	(	(	PUNCT
eurjchem-1915	41	22	online	online	ADJ
eurjchem-1915	41	23	)	)	PUNCT
eurjchem-1915	41	24	–	–	PUNCT
eurjchem-1915	41	25	copyright	copyright	NOUN
eurjchem-1915	41	26	©	©	PROPN
eurjchem-1915	41	27	2019	2019	NUM
eurjchem-1915	41	28	the	the	DET
eurjchem-1915	41	29	authors	author	NOUN
eurjchem-1915	41	30	–	–	PUNCT
eurjchem-1915	41	31	atlanta	atlanta	PROPN
eurjchem-1915	41	32	publishing	publishing	PROPN
eurjchem-1915	41	33	house	house	PROPN
eurjchem-1915	41	34	llc	llc	PROPN
eurjchem-1915	41	35	–	–	PUNCT
eurjchem-1915	41	36	printed	print	VERB
eurjchem-1915	41	37	in	in	ADP
eurjchem-1915	41	38	the	the	DET
eurjchem-1915	41	39	usa	usa	PROPN
eurjchem-1915	41	40	.	.	PUNCT
eurjchem-1915	42	1	this	this	DET
eurjchem-1915	42	2	work	work	NOUN
eurjchem-1915	42	3	is	be	AUX
eurjchem-1915	42	4	published	publish	VERB
eurjchem-1915	42	5	and	and	CCONJ
eurjchem-1915	42	6	licensed	license	VERB
eurjchem-1915	42	7	by	by	ADP
eurjchem-1915	42	8	atlanta	atlanta	PROPN
eurjchem-1915	42	9	publishing	publishing	PROPN
eurjchem-1915	42	10	house	house	PROPN
eurjchem-1915	42	11	llc	llc	PROPN
eurjchem-1915	42	12	–	–	PUNCT
eurjchem-1915	42	13	cc	cc	PROPN
eurjchem-1915	42	14	by	by	ADP
eurjchem-1915	42	15	nc	nc	PROPN
eurjchem-1915	42	16	–	–	PUNCT
eurjchem-1915	42	17	some	some	DET
eurjchem-1915	42	18	rights	right	NOUN
eurjchem-1915	42	19	reserved	reserve	VERB
eurjchem-1915	42	20	.	.	PUNCT
eurjchem-1915	43	1	http://dx.doi.org/10.5155/eurjchem.10.4.367-375.1915	http://dx.doi.org/10.5155/eurjchem.10.4.367-375.1915	ADJ
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eurjchem-1915	43	3	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.4.367-375.1915&domain=pdf&date_stamp=2019-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.4.367-375.1915&domain=pdf&date_stamp=2019-12-31	NOUN
eurjchem-1915	43	4	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-1915	43	5	http://dx.doi.org/10.5155/eurjchem.10.4.367-375.1915	http://dx.doi.org/10.5155/eurjchem.10.4.367-375.1915	PROPN
eurjchem-1915	43	6	mailto:alfulaijothman@gmail.com	mailto:alfulaijothman@gmail.com	PROPN
eurjchem-1915	43	7	mailto:aelassar@yahoo.com	mailto:aelassar@yahoo.com	X
eurjchem-1915	43	8	mailto:dr_dawood@yahoo.com	mailto:dr_dawood@yahoo.com	X
eurjchem-1915	44	1	mailto:aelassar@yahoo.com	mailto:aelassar@yahoo.com	PROPN
eurjchem-1915	44	2	http://www.eurjchem.com/	http://www.eurjchem.com/	PROPN
eurjchem-1915	44	3	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.4.367-375.1915&domain=pdf&date_stamp=2019-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.10.4.367-375.1915&domain=pdf&date_stamp=2019-12-31	PROPN
eurjchem-1915	44	4	�	�	PROPN
eurjchem-1915	44	5	368	368	NUM
eurjchem-1915	44	6	al	al	PROPN
eurjchem-1915	44	7	-	-	PUNCT
eurjchem-1915	44	8	fulaij	fulaij	PROPN
eurjchem-1915	44	9	et	et	PROPN
eurjchem-1915	44	10	al	al	PROPN
eurjchem-1915	44	11	.	.	PUNCT
eurjchem-1915	44	12	/	/	SYM
eurjchem-1915	44	13	european	european	PROPN
eurjchem-1915	44	14	journal	journal	PROPN
eurjchem-1915	44	15	of	of	ADP
eurjchem-1915	44	16	chemistry	chemistry	NOUN
eurjchem-1915	44	17	10	10	NUM
eurjchem-1915	44	18	(	(	PUNCT
eurjchem-1915	44	19	4	4	NUM
eurjchem-1915	44	20	)	)	PUNCT
eurjchem-1915	44	21	(	(	PUNCT
eurjchem-1915	44	22	2019	2019	NUM
eurjchem-1915	44	23	)	)	PUNCT
eurjchem-1915	44	24	367	367	NUM
eurjchem-1915	44	25	-	-	SYM
eurjchem-1915	44	26	375	375	NUM
eurjchem-1915	44	27	scheme	scheme	NOUN
eurjchem-1915	44	28	1	1	NUM
eurjchem-1915	44	29	.	.	PUNCT
eurjchem-1915	44	30	synthesis	synthesis	NOUN
eurjchem-1915	44	31	of	of	ADP
eurjchem-1915	44	32	1,1`-diphenyl-3,3`-bipyrazole	1,1`-diphenyl-3,3`-bipyrazole	NUM
eurjchem-1915	44	33	derivatives	derivative	NOUN
eurjchem-1915	44	34	5	5	NUM
eurjchem-1915	44	35	and	and	CCONJ
eurjchem-1915	44	36	6	6	NUM
eurjchem-1915	44	37	.	.	PUNCT
eurjchem-1915	44	38	low	low	ADJ
eurjchem-1915	44	39	-	-	PUNCT
eurjchem-1915	44	40	resolution	resolution	NOUN
eurjchem-1915	44	41	electron	electron	NOUN
eurjchem-1915	44	42	impact	impact	NOUN
eurjchem-1915	44	43	mass	mass	NOUN
eurjchem-1915	44	44	spectra	spectra	NOUN
eurjchem-1915	44	45	[	[	X
eurjchem-1915	44	46	ms(ei	ms(ei	NOUN
eurjchem-1915	44	47	)	)	PUNCT
eurjchem-1915	44	48	]	]	PUNCT
eurjchem-1915	44	49	and	and	CCONJ
eurjchem-1915	44	50	high	high	ADJ
eurjchem-1915	44	51	-	-	PUNCT
eurjchem-1915	44	52	resolution	resolution	NOUN
eurjchem-1915	44	53	electron	electron	NOUN
eurjchem-1915	44	54	impact	impact	NOUN
eurjchem-1915	44	55	mass	mass	NOUN
eurjchem-1915	44	56	spectra	spectra	NOUN
eurjchem-1915	45	1	[	[	X
eurjchem-1915	45	2	hrms	hrm	NOUN
eurjchem-1915	45	3	(	(	PUNCT
eurjchem-1915	45	4	ei	ei	NOUN
eurjchem-1915	45	5	)	)	PUNCT
eurjchem-1915	45	6	]	]	PUNCT
eurjchem-1915	45	7	were	be	AUX
eurjchem-1915	45	8	performed	perform	VERB
eurjchem-1915	45	9	on	on	ADP
eurjchem-1915	45	10	high	high	ADJ
eurjchem-1915	45	11	resolution	resolution	NOUN
eurjchem-1915	45	12	gc	gc	PROPN
eurjchem-1915	45	13	-	-	PROPN
eurjchem-1915	45	14	ms	ms	PROPN
eurjchem-1915	45	15	(	(	PUNCT
eurjchem-1915	45	16	dfs	dfs	PROPN
eurjchem-1915	45	17	)	)	PUNCT
eurjchem-1915	45	18	thermo	thermo	NOUN
eurjchem-1915	45	19	spectrometers	spectrometer	NOUN
eurjchem-1915	45	20	at	at	ADP
eurjchem-1915	45	21	70.1	70.1	NUM
eurjchem-1915	45	22	ev	ev	NOUN
eurjchem-1915	45	23	using	use	VERB
eurjchem-1915	45	24	magnetic	magnetic	ADJ
eurjchem-1915	45	25	sector	sector	NOUN
eurjchem-1915	45	26	mass	mass	NOUN
eurjchem-1915	45	27	analyzer	analyzer	NOUN
eurjchem-1915	45	28	.	.	PUNCT
eurjchem-1915	46	1	the	the	DET
eurjchem-1915	46	2	crystal	crystal	NOUN
eurjchem-1915	46	3	structures	structure	NOUN
eurjchem-1915	46	4	were	be	AUX
eurjchem-1915	46	5	determined	determine	VERB
eurjchem-1915	46	6	by	by	ADP
eurjchem-1915	46	7	a	a	DET
eurjchem-1915	46	8	rigaku	rigaku	NOUN
eurjchem-1915	46	9	r	r	NOUN
eurjchem-1915	46	10	-	-	PUNCT
eurjchem-1915	46	11	axis	axis	NOUN
eurjchem-1915	46	12	rapid	rapid	ADJ
eurjchem-1915	46	13	diffractometer	diffractometer	NOUN
eurjchem-1915	46	14	and	and	CCONJ
eurjchem-1915	46	15	bruker	bruker	NOUN
eurjchem-1915	46	16	x8	x8	PROPN
eurjchem-1915	46	17	prospector	prospector	PROPN
eurjchem-1915	46	18	and	and	CCONJ
eurjchem-1915	46	19	the	the	DET
eurjchem-1915	46	20	single	single	ADJ
eurjchem-1915	46	21	crystal	crystal	NOUN
eurjchem-1915	46	22	x	x	PROPN
eurjchem-1915	46	23	-	-	NOUN
eurjchem-1915	46	24	ray	ray	NOUN
eurjchem-1915	46	25	diffraction	diffraction	NOUN
eurjchem-1915	46	26	data	datum	NOUN
eurjchem-1915	46	27	collections	collection	NOUN
eurjchem-1915	46	28	were	be	AUX
eurjchem-1915	46	29	made	make	VERB
eurjchem-1915	46	30	by	by	ADP
eurjchem-1915	46	31	using	use	VERB
eurjchem-1915	46	32	mo	mo	PROPN
eurjchem-1915	46	33	-	-	ADJ
eurjchem-1915	46	34	kα	kα	PROPN
eurjchem-1915	46	35	radiation	radiation	NOUN
eurjchem-1915	46	36	.	.	PUNCT
eurjchem-1915	47	1	the	the	DET
eurjchem-1915	47	2	data	datum	NOUN
eurjchem-1915	47	3	were	be	AUX
eurjchem-1915	47	4	collected	collect	VERB
eurjchem-1915	47	5	at	at	ADP
eurjchem-1915	47	6	room	room	NOUN
eurjchem-1915	47	7	temperature	temperature	NOUN
eurjchem-1915	47	8	.	.	PUNCT
eurjchem-1915	48	1	the	the	DET
eurjchem-1915	48	2	structure	structure	NOUN
eurjchem-1915	48	3	was	be	AUX
eurjchem-1915	48	4	solved	solve	VERB
eurjchem-1915	48	5	by	by	ADP
eurjchem-1915	48	6	direct	direct	ADJ
eurjchem-1915	48	7	methods	method	NOUN
eurjchem-1915	48	8	and	and	CCONJ
eurjchem-1915	48	9	was	be	AUX
eurjchem-1915	48	10	expanded	expand	VERB
eurjchem-1915	48	11	using	use	VERB
eurjchem-1915	48	12	fourier	fourier	NOUN
eurjchem-1915	48	13	techniques	technique	NOUN
eurjchem-1915	48	14	.	.	PUNCT
eurjchem-1915	49	1	the	the	DET
eurjchem-1915	49	2	non	non	ADJ
eurjchem-1915	49	3	-	-	ADJ
eurjchem-1915	49	4	hydrogen	hydrogen	ADJ
eurjchem-1915	49	5	atoms	atom	NOUN
eurjchem-1915	49	6	were	be	AUX
eurjchem-1915	49	7	refined	refine	VERB
eurjchem-1915	49	8	anisotropically	anisotropically	ADV
eurjchem-1915	49	9	.	.	PUNCT
eurjchem-1915	50	1	the	the	DET
eurjchem-1915	50	2	structure	structure	NOUN
eurjchem-1915	50	3	was	be	AUX
eurjchem-1915	50	4	solved	solve	VERB
eurjchem-1915	50	5	and	and	CCONJ
eurjchem-1915	50	6	refined	refined	ADJ
eurjchem-1915	50	7	using	use	VERB
eurjchem-1915	50	8	the	the	DET
eurjchem-1915	50	9	bruker	bruker	PROPN
eurjchem-1915	50	10	shelxtl	shelxtl	PROPN
eurjchem-1915	50	11	software	software	PROPN
eurjchem-1915	50	12	package	package	NOUN
eurjchem-1915	50	13	(	(	PUNCT
eurjchem-1915	50	14	structure	structure	NOUN
eurjchem-1915	50	15	solution	solution	NOUN
eurjchem-1915	50	16	program	program	NOUN
eurjchem-1915	50	17	-	-	PUNCT
eurjchem-1915	50	18	shelxs-97	shelxs-97	PROPN
eurjchem-1915	50	19	and	and	CCONJ
eurjchem-1915	50	20	refinement	refinement	NOUN
eurjchem-1915	50	21	program	program	NOUN
eurjchem-1915	50	22	-	-	PUNCT
eurjchem-1915	50	23	shelxl-97	shelxl-97	PROPN
eurjchem-1915	50	24	)	)	PUNCT
eurjchem-1915	51	1	[	[	X
eurjchem-1915	51	2	25	25	NUM
eurjchem-1915	51	3	]	]	PUNCT
eurjchem-1915	51	4	.	.	PUNCT
eurjchem-1915	52	1	data	datum	NOUN
eurjchem-1915	52	2	were	be	AUX
eurjchem-1915	52	3	corrected	correct	VERB
eurjchem-1915	52	4	for	for	ADP
eurjchem-1915	52	5	the	the	DET
eurjchem-1915	52	6	absorption	absorption	NOUN
eurjchem-1915	52	7	effects	effect	NOUN
eurjchem-1915	52	8	using	use	VERB
eurjchem-1915	52	9	the	the	DET
eurjchem-1915	52	10	multi	multi	ADJ
eurjchem-1915	52	11	-	-	ADJ
eurjchem-1915	52	12	scan	scan	ADJ
eurjchem-1915	52	13	method	method	NOUN
eurjchem-1915	52	14	(	(	PUNCT
eurjchem-1915	52	15	sadabs	sadab	NOUN
eurjchem-1915	52	16	)	)	PUNCT
eurjchem-1915	52	17	.	.	PUNCT
eurjchem-1915	53	1	scanning	scan	VERB
eurjchem-1915	53	2	electron	electron	NOUN
eurjchem-1915	53	3	microscopy	microscopy	NOUN
eurjchem-1915	53	4	(	(	PUNCT
eurjchem-1915	53	5	sem	sem	NOUN
eurjchem-1915	53	6	)	)	PUNCT
eurjchem-1915	53	7	and	and	CCONJ
eurjchem-1915	53	8	energy	energy	NOUN
eurjchem-1915	53	9	dispersive	dispersive	ADJ
eurjchem-1915	53	10	xray	xray	NOUN
eurjchem-1915	53	11	analysis	analysis	NOUN
eurjchem-1915	53	12	(	(	PUNCT
eurjchem-1915	53	13	edx	edx	PROPN
eurjchem-1915	53	14	)	)	PUNCT
eurjchem-1915	53	15	were	be	AUX
eurjchem-1915	53	16	examined	examine	VERB
eurjchem-1915	53	17	at	at	ADP
eurjchem-1915	53	18	room	room	NOUN
eurjchem-1915	53	19	temperature	temperature	NOUN
eurjchem-1915	53	20	(	(	PUNCT
eurjchem-1915	53	21	25	25	NUM
eurjchem-1915	53	22	°	°	NOUN
eurjchem-1915	53	23	c	c	NOUN
eurjchem-1915	53	24	)	)	PUNCT
eurjchem-1915	53	25	in	in	ADP
eurjchem-1915	53	26	a	a	DET
eurjchem-1915	53	27	model	model	NOUN
eurjchem-1915	53	28	jsm	jsm	PROPN
eurjchem-1915	53	29	6300	6300	NUM
eurjchem-1915	53	30	jeol	jeol	PROPN
eurjchem-1915	53	31	scanning	scan	VERB
eurjchem-1915	53	32	electron	electron	NOUN
eurjchem-1915	53	33	microscope	microscope	NOUN
eurjchem-1915	53	34	(	(	PUNCT
eurjchem-1915	53	35	akishima	akishima	PROPN
eurjchem-1915	53	36	,	,	PUNCT
eurjchem-1915	53	37	japan	japan	PROPN
eurjchem-1915	53	38	)	)	PUNCT
eurjchem-1915	53	39	at	at	ADP
eurjchem-1915	53	40	20	20	NUM
eurjchem-1915	53	41	kv	kv	NOUN
eurjchem-1915	53	42	.	.	PUNCT
eurjchem-1915	54	1	x	x	X
eurjchem-1915	54	2	-	-	PUNCT
eurjchem-1915	54	3	ray	ray	NOUN
eurjchem-1915	54	4	photoelectron	photoelectron	NOUN
eurjchem-1915	54	5	spectroscopy	spectroscopy	NOUN
eurjchem-1915	54	6	(	(	PUNCT
eurjchem-1915	54	7	xps	xps	PROPN
eurjchem-1915	54	8	)	)	PUNCT
eurjchem-1915	54	9	was	be	AUX
eurjchem-1915	54	10	conducted	conduct	VERB
eurjchem-1915	54	11	using	use	VERB
eurjchem-1915	54	12	a	a	DET
eurjchem-1915	54	13	thermo	thermo	NOUN
eurjchem-1915	54	14	scientific	scientific	ADJ
eurjchem-1915	54	15	escalab250xi	escalab250xi	PROPN
eurjchem-1915	54	16	spectrometer	spectrometer	NOUN
eurjchem-1915	54	17	.	.	PUNCT
eurjchem-1915	55	1	the	the	DET
eurjchem-1915	55	2	bis	bis	ADJ
eurjchem-1915	55	3	-	-	ADJ
eurjchem-1915	55	4	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	55	5	chlorides	chloride	NOUN
eurjchem-1915	55	6	(	(	PUNCT
eurjchem-1915	55	7	1a	1a	NUM
eurjchem-1915	55	8	,	,	PUNCT
eurjchem-1915	55	9	b	b	X
eurjchem-1915	55	10	)	)	PUNCT
eurjchem-1915	55	11	was	be	AUX
eurjchem-1915	55	12	prepared	prepare	VERB
eurjchem-1915	55	13	following	follow	VERB
eurjchem-1915	55	14	the	the	DET
eurjchem-1915	55	15	literature	literature	NOUN
eurjchem-1915	55	16	procedure	procedure	NOUN
eurjchem-1915	55	17	(	(	PUNCT
eurjchem-1915	55	18	scheme	scheme	NOUN
eurjchem-1915	55	19	1	1	NUM
eurjchem-1915	55	20	)	)	PUNCT
eurjchem-1915	56	1	[	[	X
eurjchem-1915	56	2	26	26	NUM
eurjchem-1915	56	3	]	]	PUNCT
eurjchem-1915	56	4	.	.	PUNCT
eurjchem-1915	57	1	2.2	2.2	NUM
eurjchem-1915	57	2	.	.	PUNCT
eurjchem-1915	57	3	synthesis	synthesis	NOUN
eurjchem-1915	57	4	of	of	ADP
eurjchem-1915	57	5	1,1'-diaryl-3,3'-bipyrazole	1,1'-diaryl-3,3'-bipyrazole	PROPN
eurjchem-1915	57	6	derivatives	derivative	NOUN
eurjchem-1915	57	7	(	(	PUNCT
eurjchem-1915	57	8	5a	5a	NUM
eurjchem-1915	57	9	,	,	PUNCT
eurjchem-1915	57	10	b	b	NOUN
eurjchem-1915	57	11	)	)	PUNCT
eurjchem-1915	57	12	to	to	ADP
eurjchem-1915	57	13	a	a	DET
eurjchem-1915	57	14	solution	solution	NOUN
eurjchem-1915	57	15	of	of	ADP
eurjchem-1915	57	16	the	the	DET
eurjchem-1915	57	17	appropriate	appropriate	ADJ
eurjchem-1915	57	18	bis	bis	ADJ
eurjchem-1915	57	19	-	-	ADJ
eurjchem-1915	57	20	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	57	21	chloride	chloride	PROPN
eurjchem-1915	57	22	1a	1a	NOUN
eurjchem-1915	57	23	or	or	CCONJ
eurjchem-1915	57	24	1b	1b	NUM
eurjchem-1915	57	25	(	(	PUNCT
eurjchem-1915	57	26	10	10	NUM
eurjchem-1915	57	27	mmol	mmol	NOUN
eurjchem-1915	57	28	)	)	PUNCT
eurjchem-1915	57	29	in	in	ADP
eurjchem-1915	57	30	dry	dry	ADJ
eurjchem-1915	57	31	benzene	benzene	NOUN
eurjchem-1915	57	32	(	(	PUNCT
eurjchem-1915	57	33	30	30	NUM
eurjchem-1915	57	34	ml	ml	NOUN
eurjchem-1915	57	35	)	)	PUNCT
eurjchem-1915	57	36	,	,	PUNCT
eurjchem-1915	57	37	methyl	methyl	NOUN
eurjchem-1915	57	38	propiolate	propiolate	NOUN
eurjchem-1915	57	39	3	3	NUM
eurjchem-1915	57	40	(	(	PUNCT
eurjchem-1915	57	41	20	20	NUM
eurjchem-1915	57	42	mmol	mmol	NOUN
eurjchem-1915	57	43	)	)	PUNCT
eurjchem-1915	57	44	was	be	AUX
eurjchem-1915	57	45	added	add	VERB
eurjchem-1915	57	46	,	,	PUNCT
eurjchem-1915	57	47	followed	follow	VERB
eurjchem-1915	57	48	by	by	ADP
eurjchem-1915	57	49	dropwise	dropwise	NOUN
eurjchem-1915	57	50	addition	addition	NOUN
eurjchem-1915	57	51	of	of	ADP
eurjchem-1915	57	52	triethylamine	triethylamine	NOUN
eurjchem-1915	57	53	(	(	PUNCT
eurjchem-1915	57	54	0.2	0.2	NUM
eurjchem-1915	57	55	ml	ml	NOUN
eurjchem-1915	57	56	)	)	PUNCT
eurjchem-1915	57	57	.	.	PUNCT
eurjchem-1915	58	1	the	the	DET
eurjchem-1915	58	2	reaction	reaction	NOUN
eurjchem-1915	58	3	mixture	mixture	NOUN
eurjchem-1915	58	4	was	be	AUX
eurjchem-1915	58	5	refluxed	refluxe	VERB
eurjchem-1915	58	6	for	for	ADP
eurjchem-1915	58	7	4	4	NUM
eurjchem-1915	58	8	h	h	NOUN
eurjchem-1915	58	9	then	then	ADV
eurjchem-1915	58	10	left	leave	VERB
eurjchem-1915	58	11	to	to	PART
eurjchem-1915	58	12	cool	cool	VERB
eurjchem-1915	58	13	to	to	PART
eurjchem-1915	58	14	room	room	VERB
eurjchem-1915	58	15	temperature	temperature	NOUN
eurjchem-1915	58	16	.	.	PUNCT
eurjchem-1915	59	1	the	the	DET
eurjchem-1915	59	2	solvent	solvent	NOUN
eurjchem-1915	59	3	was	be	AUX
eurjchem-1915	59	4	evaporated	evaporate	VERB
eurjchem-1915	59	5	under	under	ADP
eurjchem-1915	59	6	reduced	reduced	ADJ
eurjchem-1915	59	7	pressure	pressure	NOUN
eurjchem-1915	59	8	then	then	ADV
eurjchem-1915	59	9	the	the	DET
eurjchem-1915	59	10	residue	residue	NOUN
eurjchem-1915	59	11	was	be	AUX
eurjchem-1915	59	12	treated	treat	VERB
eurjchem-1915	59	13	with	with	ADP
eurjchem-1915	59	14	few	few	ADJ
eurjchem-1915	59	15	drops	drop	NOUN
eurjchem-1915	59	16	of	of	ADP
eurjchem-1915	59	17	methanol	methanol	NOUN
eurjchem-1915	59	18	.	.	PUNCT
eurjchem-1915	60	1	the	the	DET
eurjchem-1915	60	2	precipitated	precipitate	VERB
eurjchem-1915	60	3	product	product	NOUN
eurjchem-1915	60	4	was	be	AUX
eurjchem-1915	60	5	filtered	filter	VERB
eurjchem-1915	60	6	off	off	ADP
eurjchem-1915	60	7	,	,	PUNCT
eurjchem-1915	60	8	washed	wash	VERB
eurjchem-1915	60	9	with	with	ADP
eurjchem-1915	60	10	methanol	methanol	NOUN
eurjchem-1915	60	11	,	,	PUNCT
eurjchem-1915	60	12	dried	dry	VERB
eurjchem-1915	60	13	and	and	CCONJ
eurjchem-1915	60	14	finally	finally	ADV
eurjchem-1915	60	15	recrystallized	recrystallize	VERB
eurjchem-1915	60	16	from	from	ADP
eurjchem-1915	60	17	dmf	dmf	PROPN
eurjchem-1915	60	18	to	to	PART
eurjchem-1915	60	19	afford	afford	VERB
eurjchem-1915	60	20	the	the	DET
eurjchem-1915	60	21	corresponding	corresponding	ADJ
eurjchem-1915	60	22	3,3'bipyrazole	3,3'bipyrazole	NUM
eurjchem-1915	60	23	derivatives	derivative	NOUN
eurjchem-1915	60	24	5a	5a	NUM
eurjchem-1915	60	25	,	,	PUNCT
eurjchem-1915	60	26	b	b	PROPN
eurjchem-1915	60	27	(	(	PUNCT
eurjchem-1915	60	28	scheme	scheme	NOUN
eurjchem-1915	60	29	1	1	NUM
eurjchem-1915	60	30	)	)	PUNCT
eurjchem-1915	60	31	.	.	PUNCT
eurjchem-1915	61	1	dimethyl	dimethyl	PROPN
eurjchem-1915	61	2	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicarboxylate	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicarboxylate	NUM
eurjchem-1915	61	3	(	(	PUNCT
eurjchem-1915	61	4	5a	5a	NUM
eurjchem-1915	61	5	):	):	PUNCT
eurjchem-1915	61	6	color	color	NOUN
eurjchem-1915	61	7	:	:	PUNCT
eurjchem-1915	61	8	beige	beige	ADJ
eurjchem-1915	61	9	.	.	PUNCT
eurjchem-1915	61	10	yield	yield	NOUN
eurjchem-1915	61	11	:	:	PUNCT
eurjchem-1915	61	12	70	70	NUM
eurjchem-1915	61	13	%	%	NOUN
eurjchem-1915	61	14	.	.	PUNCT
eurjchem-1915	62	1	m.p	m.p	PROPN
eurjchem-1915	62	2	.	.	PROPN
eurjchem-1915	62	3	:	:	PUNCT
eurjchem-1915	63	1	260	260	NUM
eurjchem-1915	63	2	-	-	SYM
eurjchem-1915	63	3	262	262	NUM
eurjchem-1915	63	4	°	°	NOUN
eurjchem-1915	63	5	c	c	NOUN
eurjchem-1915	63	6	.	.	PUNCT
eurjchem-1915	64	1	ft	ft	PROPN
eurjchem-1915	64	2	-	-	PUNCT
eurjchem-1915	64	3	ir	ir	PROPN
eurjchem-1915	64	4	(	(	PUNCT
eurjchem-1915	64	5	kbr	kbr	PROPN
eurjchem-1915	64	6	,	,	PUNCT
eurjchem-1915	64	7	ν	ν	PROPN
eurjchem-1915	64	8	,	,	PUNCT
eurjchem-1915	64	9	cm−1	cm−1	NOUN
eurjchem-1915	64	10	):	):	PUNCT
eurjchem-1915	64	11	3084	3084	NUM
eurjchem-1915	64	12	(	(	PUNCT
eurjchem-1915	64	13	ch	ch	NOUN
eurjchem-1915	64	14	)	)	PUNCT
eurjchem-1915	64	15	,	,	PUNCT
eurjchem-1915	64	16	2989	2989	NUM
eurjchem-1915	64	17	(	(	PUNCT
eurjchem-1915	64	18	ch	ch	NOUN
eurjchem-1915	64	19	)	)	PUNCT
eurjchem-1915	64	20	,	,	PUNCT
eurjchem-1915	64	21	1733	1733	NUM
eurjchem-1915	64	22	(	(	PUNCT
eurjchem-1915	64	23	c	c	NOUN
eurjchem-1915	64	24	=	=	NOUN
eurjchem-1915	64	25	o	o	NOUN
eurjchem-1915	64	26	)	)	PUNCT
eurjchem-1915	64	27	.	.	PUNCT
eurjchem-1915	65	1	1h	1h	NUM
eurjchem-1915	65	2	nmr	nmr	NOUN
eurjchem-1915	65	3	(	(	PUNCT
eurjchem-1915	65	4	400	400	NUM
eurjchem-1915	65	5	mhz	mhz	NOUN
eurjchem-1915	65	6	,	,	PUNCT
eurjchem-1915	65	7	dmso	dmso	NOUN
eurjchem-1915	65	8	-	-	NOUN
eurjchem-1915	65	9	d6	d6	NOUN
eurjchem-1915	65	10	,	,	PUNCT
eurjchem-1915	65	11	δ	δ	PROPN
eurjchem-1915	65	12	,	,	PUNCT
eurjchem-1915	65	13	ppm	ppm	NUM
eurjchem-1915	65	14	):	):	PUNCT
eurjchem-1915	65	15	7.53	7.53	NUM
eurjchem-1915	65	16	(	(	PUNCT
eurjchem-1915	65	17	s	s	PROPN
eurjchem-1915	65	18	,	,	PUNCT
eurjchem-1915	65	19	2h	2h	NUM
eurjchem-1915	65	20	,	,	PUNCT
eurjchem-1915	65	21	pyrazole	pyrazole	NOUN
eurjchem-1915	65	22	-	-	PUNCT
eurjchem-1915	65	23	h	h	NOUN
eurjchem-1915	65	24	)	)	PUNCT
eurjchem-1915	65	25	,	,	PUNCT
eurjchem-1915	65	26	7.52	7.52	NUM
eurjchem-1915	65	27	-	-	SYM
eurjchem-1915	65	28	7.34	7.34	NUM
eurjchem-1915	65	29	(	(	PUNCT
eurjchem-1915	65	30	m	m	PROPN
eurjchem-1915	65	31	,	,	PUNCT
eurjchem-1915	65	32	10h	10h	NUM
eurjchem-1915	65	33	,	,	PUNCT
eurjchem-1915	65	34	ar	ar	NOUN
eurjchem-1915	65	35	-	-	NOUN
eurjchem-1915	65	36	h	h	NOUN
eurjchem-1915	65	37	)	)	PUNCT
eurjchem-1915	65	38	,	,	PUNCT
eurjchem-1915	65	39	3.45	3.45	NUM
eurjchem-1915	65	40	(	(	PUNCT
eurjchem-1915	65	41	s	s	PROPN
eurjchem-1915	65	42	,	,	PUNCT
eurjchem-1915	65	43	6h	6h	NUM
eurjchem-1915	65	44	,	,	PUNCT
eurjchem-1915	65	45	2ch3	2ch3	NUM
eurjchem-1915	65	46	)	)	PUNCT
eurjchem-1915	65	47	.	.	PUNCT
eurjchem-1915	66	1	13c	13c	NOUN
eurjchem-1915	66	2	nmr	nmr	NOUN
eurjchem-1915	66	3	(	(	PUNCT
eurjchem-1915	66	4	100	100	NUM
eurjchem-1915	66	5	mhz	mhz	NOUN
eurjchem-1915	66	6	,	,	PUNCT
eurjchem-1915	66	7	dmso	dmso	NOUN
eurjchem-1915	66	8	-	-	NOUN
eurjchem-1915	66	9	d6	d6	NOUN
eurjchem-1915	66	10	,	,	PUNCT
eurjchem-1915	66	11	δ	δ	PROPN
eurjchem-1915	66	12	,	,	PUNCT
eurjchem-1915	66	13	ppm	ppm	NOUN
eurjchem-1915	66	14	):	):	PUNCT
eurjchem-1915	66	15	160.1	160.1	NUM
eurjchem-1915	66	16	(	(	PUNCT
eurjchem-1915	66	17	2c	2c	NUM
eurjchem-1915	66	18	,	,	PUNCT
eurjchem-1915	66	19	c	c	PROPN
eurjchem-1915	66	20	=	=	SYM
eurjchem-1915	66	21	o	o	NOUN
eurjchem-1915	66	22	)	)	PUNCT
eurjchem-1915	66	23	,	,	PUNCT
eurjchem-1915	66	24	144.9	144.9	NUM
eurjchem-1915	66	25	(	(	PUNCT
eurjchem-1915	66	26	2c	2c	NOUN
eurjchem-1915	66	27	,	,	PUNCT
eurjchem-1915	66	28	pyrazole	pyrazole	NOUN
eurjchem-1915	66	29	-	-	PUNCT
eurjchem-1915	66	30	c	c	NOUN
eurjchem-1915	66	31	)	)	PUNCT
eurjchem-1915	66	32	,	,	PUNCT
eurjchem-1915	66	33	129.02	129.02	NUM
eurjchem-1915	66	34	(	(	PUNCT
eurjchem-1915	66	35	2c	2c	NOUN
eurjchem-1915	66	36	,	,	PUNCT
eurjchem-1915	66	37	pyrazole	pyrazole	NOUN
eurjchem-1915	66	38	-	-	PUNCT
eurjchem-1915	66	39	c	c	NOUN
eurjchem-1915	66	40	)	)	PUNCT
eurjchem-1915	66	41	,	,	PUNCT
eurjchem-1915	66	42	116.6	116.6	NUM
eurjchem-1915	66	43	(	(	PUNCT
eurjchem-1915	66	44	2c	2c	NOUN
eurjchem-1915	66	45	,	,	PUNCT
eurjchem-1915	66	46	pyrazole	pyrazole	NOUN
eurjchem-1915	66	47	-	-	PUNCT
eurjchem-1915	66	48	c	c	NOUN
eurjchem-1915	66	49	)	)	PUNCT
eurjchem-1915	66	50	,	,	PUNCT
eurjchem-1915	66	51	140.1	140.1	NUM
eurjchem-1915	66	52	(	(	PUNCT
eurjchem-1915	66	53	2c	2c	NUM
eurjchem-1915	66	54	,	,	PUNCT
eurjchem-1915	66	55	ar	ar	NOUN
eurjchem-1915	66	56	-	-	NOUN
eurjchem-1915	66	57	c	c	NOUN
eurjchem-1915	66	58	)	)	PUNCT
eurjchem-1915	66	59	,	,	PUNCT
eurjchem-1915	66	60	128.9	128.9	NUM
eurjchem-1915	66	61	(	(	PUNCT
eurjchem-1915	66	62	4c	4c	NOUN
eurjchem-1915	66	63	,	,	PUNCT
eurjchem-1915	66	64	ar	ar	NOUN
eurjchem-1915	66	65	-	-	NOUN
eurjchem-1915	66	66	c	c	NOUN
eurjchem-1915	66	67	)	)	PUNCT
eurjchem-1915	66	68	,	,	PUNCT
eurjchem-1915	66	69	126.0	126.0	NUM
eurjchem-1915	66	70	(	(	PUNCT
eurjchem-1915	66	71	2c	2c	NUM
eurjchem-1915	66	72	,	,	PUNCT
eurjchem-1915	66	73	ar	ar	NOUN
eurjchem-1915	66	74	-	-	NOUN
eurjchem-1915	66	75	c	c	NOUN
eurjchem-1915	66	76	)	)	PUNCT
eurjchem-1915	66	77	,	,	PUNCT
eurjchem-1915	66	78	121.1	121.1	NUM
eurjchem-1915	66	79	(	(	PUNCT
eurjchem-1915	66	80	4c	4c	NOUN
eurjchem-1915	66	81	,	,	PUNCT
eurjchem-1915	66	82	ar	ar	NOUN
eurjchem-1915	66	83	-	-	NOUN
eurjchem-1915	66	84	c	c	NOUN
eurjchem-1915	66	85	)	)	PUNCT
eurjchem-1915	66	86	,	,	PUNCT
eurjchem-1915	66	87	52.1	52.1	NUM
eurjchem-1915	66	88	(	(	PUNCT
eurjchem-1915	66	89	2c	2c	NOUN
eurjchem-1915	66	90	,	,	PUNCT
eurjchem-1915	66	91	och3	och3	ADJ
eurjchem-1915	66	92	)	)	PUNCT
eurjchem-1915	66	93	.	.	PUNCT
eurjchem-1915	67	1	hrms	hrm	NOUN
eurjchem-1915	67	2	(	(	PUNCT
eurjchem-1915	67	3	ei	ei	PROPN
eurjchem-1915	67	4	,	,	PUNCT
eurjchem-1915	67	5	m	m	PROPN
eurjchem-1915	67	6	/	/	SYM
eurjchem-1915	67	7	z	z	ADJ
eurjchem-1915	67	8	)	)	PUNCT
eurjchem-1915	67	9	calcd	calcd	NOUN
eurjchem-1915	67	10	.	.	PUNCT
eurjchem-1915	68	1	for	for	ADP
eurjchem-1915	68	2	c22h18n4o4	c22h18n4o4	NOUN
eurjchem-1915	68	3	:	:	PUNCT
eurjchem-1915	68	4	402.10	402.10	NUM
eurjchem-1915	68	5	(	(	PUNCT
eurjchem-1915	68	6	m+	m+	NUM
eurjchem-1915	68	7	)	)	PUNCT
eurjchem-1915	68	8	;	;	PUNCT
eurjchem-1915	68	9	found	find	VERB
eurjchem-1915	68	10	:	:	PUNCT
eurjchem-1915	68	11	402.13	402.13	NUM
eurjchem-1915	68	12	.	.	PUNCT
eurjchem-1915	69	1	anal	anal	ADJ
eurjchem-1915	69	2	.	.	PUNCT
eurjchem-1915	69	3	calcd	calcd	NOUN
eurjchem-1915	69	4	.	.	PUNCT
eurjchem-1915	70	1	for	for	ADP
eurjchem-1915	70	2	c22h18n4o4	c22h18n4o4	NOUN
eurjchem-1915	70	3	:	:	PUNCT
eurjchem-1915	70	4	c	c	X
eurjchem-1915	70	5	,	,	PUNCT
eurjchem-1915	70	6	65.66	65.66	NUM
eurjchem-1915	70	7	;	;	PUNCT
eurjchem-1915	70	8	h	h	NOUN
eurjchem-1915	70	9	,	,	PUNCT
eurjchem-1915	70	10	4.51	4.51	NUM
eurjchem-1915	70	11	;	;	PUNCT
eurjchem-1915	70	12	n	n	CCONJ
eurjchem-1915	70	13	,	,	PUNCT
eurjchem-1915	70	14	13.92	13.92	NUM
eurjchem-1915	70	15	.	.	PUNCT
eurjchem-1915	70	16	found	find	VERB
eurjchem-1915	70	17	:	:	PUNCT
eurjchem-1915	71	1	c	c	X
eurjchem-1915	71	2	,	,	PUNCT
eurjchem-1915	71	3	65.67	65.67	NUM
eurjchem-1915	71	4	;	;	PUNCT
eurjchem-1915	71	5	h	h	X
eurjchem-1915	71	6	,	,	PUNCT
eurjchem-1915	71	7	4.32	4.32	NUM
eurjchem-1915	71	8	;	;	PUNCT
eurjchem-1915	71	9	n	n	CCONJ
eurjchem-1915	71	10	,	,	PUNCT
eurjchem-1915	71	11	13.97	13.97	NUM
eurjchem-1915	71	12	%	%	NOUN
eurjchem-1915	71	13	.	.	PUNCT
eurjchem-1915	72	1	dimethyl	dimethyl	PROPN
eurjchem-1915	72	2	1,1'-di(4	1,1'-di(4	NUM
eurjchem-1915	72	3	-	-	PUNCT
eurjchem-1915	72	4	chlorophenyl)-3,3'-bipyrazole-4,4'-dicar	chlorophenyl)-3,3'-bipyrazole-4,4'-dicar	NOUN
eurjchem-1915	72	5	boxylate	boxylate	NOUN
eurjchem-1915	72	6	(	(	PUNCT
eurjchem-1915	72	7	5b	5b	NUM
eurjchem-1915	72	8	):	):	PUNCT
eurjchem-1915	72	9	color	color	NOUN
eurjchem-1915	72	10	:	:	PUNCT
eurjchem-1915	72	11	yellow	yellow	ADJ
eurjchem-1915	72	12	.	.	PUNCT
eurjchem-1915	72	13	yield	yield	NOUN
eurjchem-1915	72	14	:	:	PUNCT
eurjchem-1915	72	15	60	60	NUM
eurjchem-1915	72	16	%	%	NOUN
eurjchem-1915	72	17	.	.	PUNCT
eurjchem-1915	73	1	m.p	m.p	PROPN
eurjchem-1915	73	2	.	.	PROPN
eurjchem-1915	73	3	:	:	PUNCT
eurjchem-1915	74	1	232	232	NUM
eurjchem-1915	74	2	-	-	SYM
eurjchem-1915	74	3	233	233	NUM
eurjchem-1915	74	4	°	°	NOUN
eurjchem-1915	74	5	c	c	NOUN
eurjchem-1915	74	6	.	.	PUNCT
eurjchem-1915	75	1	ir	ir	PROPN
eurjchem-1915	75	2	(	(	PUNCT
eurjchem-1915	75	3	kbr	kbr	PROPN
eurjchem-1915	75	4	,	,	PUNCT
eurjchem-1915	75	5	ν	ν	PROPN
eurjchem-1915	75	6	,	,	PUNCT
eurjchem-1915	75	7	cm−1	cm−1	NOUN
eurjchem-1915	75	8	):	):	PUNCT
eurjchem-1915	75	9	3076	3076	NUM
eurjchem-1915	75	10	(	(	PUNCT
eurjchem-1915	75	11	ch	ch	NOUN
eurjchem-1915	75	12	)	)	PUNCT
eurjchem-1915	75	13	,	,	PUNCT
eurjchem-1915	75	14	2988	2988	NUM
eurjchem-1915	75	15	(	(	PUNCT
eurjchem-1915	75	16	ch	ch	NOUN
eurjchem-1915	75	17	)	)	PUNCT
eurjchem-1915	75	18	,	,	PUNCT
eurjchem-1915	75	19	1736	1736	NUM
eurjchem-1915	75	20	(	(	PUNCT
eurjchem-1915	75	21	c	c	NOUN
eurjchem-1915	75	22	=	=	NOUN
eurjchem-1915	75	23	o	o	NOUN
eurjchem-1915	75	24	)	)	PUNCT
eurjchem-1915	75	25	.	.	PUNCT
eurjchem-1915	76	1	1h	1h	NUM
eurjchem-1915	76	2	nmr	nmr	NOUN
eurjchem-1915	76	3	(	(	PUNCT
eurjchem-1915	76	4	400	400	NUM
eurjchem-1915	76	5	mhz	mhz	NOUN
eurjchem-1915	76	6	,	,	PUNCT
eurjchem-1915	76	7	dmso	dmso	NOUN
eurjchem-1915	76	8	-	-	NOUN
eurjchem-1915	76	9	d6	d6	NOUN
eurjchem-1915	76	10	,	,	PUNCT
eurjchem-1915	76	11	δ	δ	PROPN
eurjchem-1915	76	12	,	,	PUNCT
eurjchem-1915	76	13	ppm	ppm	NOUN
eurjchem-1915	76	14	):	):	PUNCT
eurjchem-1915	76	15	7.56	7.56	NUM
eurjchem-1915	76	16	(	(	PUNCT
eurjchem-1915	76	17	s	s	PROPN
eurjchem-1915	76	18	,	,	PUNCT
eurjchem-1915	76	19	2h	2h	NUM
eurjchem-1915	76	20	,	,	PUNCT
eurjchem-1915	76	21	pyrazole	pyrazole	NOUN
eurjchem-1915	76	22	-	-	PUNCT
eurjchem-1915	76	23	h	h	NOUN
eurjchem-1915	76	24	)	)	PUNCT
eurjchem-1915	76	25	,	,	PUNCT
eurjchem-1915	76	26	7.64	7.64	NUM
eurjchem-1915	76	27	,	,	PUNCT
eurjchem-1915	76	28	7.62	7.62	NUM
eurjchem-1915	76	29	(	(	PUNCT
eurjchem-1915	76	30	d	d	NOUN
eurjchem-1915	76	31	,	,	PUNCT
eurjchem-1915	76	32	2h	2h	NUM
eurjchem-1915	76	33	,	,	PUNCT
eurjchem-1915	76	34	ar	ar	NOUN
eurjchem-1915	76	35	-	-	NOUN
eurjchem-1915	76	36	h	h	PROPN
eurjchem-1915	76	37	,	,	PUNCT
eurjchem-1915	76	38	j	j	PROPN
eurjchem-1915	76	39	=	=	SYM
eurjchem-1915	76	40	8	8	NUM
eurjchem-1915	76	41	hz	hz	NOUN
eurjchem-1915	76	42	)	)	PUNCT
eurjchem-1915	76	43	;	;	PUNCT
eurjchem-1915	76	44	7.40	7.40	NUM
eurjchem-1915	76	45	,	,	PUNCT
eurjchem-1915	76	46	7.38	7.38	NUM
eurjchem-1915	76	47	(	(	PUNCT
eurjchem-1915	76	48	d	d	NOUN
eurjchem-1915	76	49	,	,	PUNCT
eurjchem-1915	76	50	2h	2h	NUM
eurjchem-1915	76	51	,	,	PUNCT
eurjchem-1915	76	52	ar	ar	NOUN
eurjchem-1915	76	53	-	-	NOUN
eurjchem-1915	76	54	h	h	PROPN
eurjchem-1915	76	55	,	,	PUNCT
eurjchem-1915	76	56	j	j	PROPN
eurjchem-1915	76	57	=	=	SYM
eurjchem-1915	76	58	8	8	NUM
eurjchem-1915	76	59	hz	hz	NOUN
eurjchem-1915	76	60	)	)	PUNCT
eurjchem-1915	76	61	,	,	PUNCT
eurjchem-1915	76	62	7.60	7.60	NUM
eurjchem-1915	76	63	,	,	PUNCT
eurjchem-1915	76	64	7.58	7.58	NUM
eurjchem-1915	76	65	(	(	PUNCT
eurjchem-1915	76	66	d	d	NOUN
eurjchem-1915	76	67	,	,	PUNCT
eurjchem-1915	76	68	2h	2h	NUM
eurjchem-1915	76	69	,	,	PUNCT
eurjchem-1915	76	70	ar	ar	NOUN
eurjchem-1915	76	71	-	-	NOUN
eurjchem-1915	76	72	h	h	PROPN
eurjchem-1915	76	73	,	,	PUNCT
eurjchem-1915	76	74	j	j	PROPN
eurjchem-1915	76	75	=	=	SYM
eurjchem-1915	76	76	8	8	NUM
eurjchem-1915	76	77	hz	hz	NOUN
eurjchem-1915	76	78	)	)	PUNCT
eurjchem-1915	76	79	,	,	PUNCT
eurjchem-1915	76	80	7.33	7.33	NUM
eurjchem-1915	76	81	(	(	PUNCT
eurjchem-1915	76	82	d	d	PROPN
eurjchem-1915	76	83	,	,	PUNCT
eurjchem-1915	76	84	2h	2h	NUM
eurjchem-1915	76	85	,	,	PUNCT
eurjchem-1915	76	86	ar	ar	NOUN
eurjchem-1915	76	87	-	-	NOUN
eurjchem-1915	76	88	h	h	PROPN
eurjchem-1915	76	89	,	,	PUNCT
eurjchem-1915	76	90	j	j	PROPN
eurjchem-1915	76	91	=	=	SYM
eurjchem-1915	76	92	8	8	NUM
eurjchem-1915	76	93	hz	hz	NOUN
eurjchem-1915	76	94	)	)	PUNCT
eurjchem-1915	76	95	,	,	PUNCT
eurjchem-1915	76	96	3.76	3.76	NUM
eurjchem-1915	76	97	(	(	PUNCT
eurjchem-1915	76	98	s	s	PROPN
eurjchem-1915	76	99	,	,	PUNCT
eurjchem-1915	76	100	6h	6h	NUM
eurjchem-1915	76	101	,	,	PUNCT
eurjchem-1915	76	102	2och3	2och3	NUM
eurjchem-1915	76	103	)	)	PUNCT
eurjchem-1915	76	104	.	.	PUNCT
eurjchem-1915	77	1	13c	13c	NOUN
eurjchem-1915	77	2	nmr	nmr	NOUN
eurjchem-1915	77	3	(	(	PUNCT
eurjchem-1915	77	4	100	100	NUM
eurjchem-1915	77	5	mhz	mhz	NOUN
eurjchem-1915	77	6	,	,	PUNCT
eurjchem-1915	77	7	dmso	dmso	NOUN
eurjchem-1915	77	8	-	-	NOUN
eurjchem-1915	77	9	d6	d6	NOUN
eurjchem-1915	77	10	,	,	PUNCT
eurjchem-1915	77	11	δ	δ	PROPN
eurjchem-1915	77	12	,	,	PUNCT
eurjchem-1915	77	13	ppm	ppm	NOUN
eurjchem-1915	77	14	):	):	PUNCT
eurjchem-1915	77	15	160.2	160.2	NUM
eurjchem-1915	77	16	(	(	PUNCT
eurjchem-1915	77	17	2c	2c	NOUN
eurjchem-1915	77	18	,	,	PUNCT
eurjchem-1915	77	19	c	c	PROPN
eurjchem-1915	77	20	=	=	SYM
eurjchem-1915	77	21	o	o	NOUN
eurjchem-1915	77	22	)	)	PUNCT
eurjchem-1915	77	23	,	,	PUNCT
eurjchem-1915	77	24	147.4	147.4	NUM
eurjchem-1915	77	25	(	(	PUNCT
eurjchem-1915	77	26	2c	2c	NOUN
eurjchem-1915	77	27	,	,	PUNCT
eurjchem-1915	77	28	pyrazole	pyrazole	NOUN
eurjchem-1915	77	29	-	-	PUNCT
eurjchem-1915	77	30	c	c	NOUN
eurjchem-1915	77	31	)	)	PUNCT
eurjchem-1915	77	32	,	,	PUNCT
eurjchem-1915	77	33	129.2	129.2	NUM
eurjchem-1915	77	34	(	(	PUNCT
eurjchem-1915	77	35	2c	2c	NUM
eurjchem-1915	77	36	,	,	PUNCT
eurjchem-1915	77	37	pyrazolec	pyrazolec	NOUN
eurjchem-1915	77	38	)	)	PUNCT
eurjchem-1915	77	39	,	,	PUNCT
eurjchem-1915	77	40	117.5	117.5	NUM
eurjchem-1915	77	41	(	(	PUNCT
eurjchem-1915	77	42	2c	2c	NOUN
eurjchem-1915	77	43	,	,	PUNCT
eurjchem-1915	77	44	pyrazole	pyrazole	NOUN
eurjchem-1915	77	45	-	-	PUNCT
eurjchem-1915	77	46	c	c	NOUN
eurjchem-1915	77	47	)	)	PUNCT
eurjchem-1915	77	48	,	,	PUNCT
eurjchem-1915	77	49	139.6	139.6	NUM
eurjchem-1915	77	50	(	(	PUNCT
eurjchem-1915	77	51	2c	2c	NUM
eurjchem-1915	77	52	,	,	PUNCT
eurjchem-1915	77	53	ar	ar	NOUN
eurjchem-1915	77	54	-	-	NOUN
eurjchem-1915	77	55	c	c	NOUN
eurjchem-1915	77	56	)	)	PUNCT
eurjchem-1915	77	57	,	,	PUNCT
eurjchem-1915	77	58	129.2	129.2	NUM
eurjchem-1915	77	59	(	(	PUNCT
eurjchem-1915	77	60	2c	2c	NUM
eurjchem-1915	77	61	,	,	PUNCT
eurjchem-1915	77	62	ar	ar	NOUN
eurjchem-1915	77	63	-	-	NOUN
eurjchem-1915	77	64	c	c	NOUN
eurjchem-1915	77	65	)	)	PUNCT
eurjchem-1915	77	66	,	,	PUNCT
eurjchem-1915	77	67	126.0	126.0	NUM
eurjchem-1915	77	68	(	(	PUNCT
eurjchem-1915	77	69	4c	4c	NOUN
eurjchem-1915	77	70	,	,	PUNCT
eurjchem-1915	77	71	ar	ar	NOUN
eurjchem-1915	77	72	-	-	NOUN
eurjchem-1915	77	73	c	c	NOUN
eurjchem-1915	77	74	)	)	PUNCT
eurjchem-1915	77	75	,	,	PUNCT
eurjchem-1915	77	76	120.9	120.9	NUM
eurjchem-1915	77	77	(	(	PUNCT
eurjchem-1915	77	78	4c	4c	NOUN
eurjchem-1915	77	79	,	,	PUNCT
eurjchem-1915	77	80	ar	ar	NOUN
eurjchem-1915	77	81	-	-	NOUN
eurjchem-1915	77	82	c	c	NOUN
eurjchem-1915	77	83	)	)	PUNCT
eurjchem-1915	77	84	,	,	PUNCT
eurjchem-1915	77	85	54.3	54.3	NUM
eurjchem-1915	77	86	(	(	PUNCT
eurjchem-1915	77	87	2c	2c	NOUN
eurjchem-1915	77	88	,	,	PUNCT
eurjchem-1915	77	89	och3	och3	ADJ
eurjchem-1915	77	90	)	)	PUNCT
eurjchem-1915	77	91	.	.	PUNCT
eurjchem-1915	78	1	hrms	hrm	NOUN
eurjchem-1915	78	2	(	(	PUNCT
eurjchem-1915	78	3	ei	ei	PROPN
eurjchem-1915	78	4	,	,	PUNCT
eurjchem-1915	78	5	m	m	PROPN
eurjchem-1915	78	6	/	/	SYM
eurjchem-1915	78	7	z	z	ADJ
eurjchem-1915	78	8	)	)	PUNCT
eurjchem-1915	78	9	calcd	calcd	NOUN
eurjchem-1915	78	10	.	.	PUNCT
eurjchem-1915	79	1	for	for	ADP
eurjchem-1915	79	2	c22h16cl2n4o4	c22h16cl2n4o4	NOUN
eurjchem-1915	79	3	:	:	PUNCT
eurjchem-1915	79	4	470.05	470.05	NUM
eurjchem-1915	79	5	(	(	PUNCT
eurjchem-1915	79	6	m+	m+	NUM
eurjchem-1915	79	7	)	)	PUNCT
eurjchem-1915	79	8	;	;	PUNCT
eurjchem-1915	79	9	found	find	VERB
eurjchem-1915	79	10	:	:	PUNCT
eurjchem-1915	79	11	470.10	470.10	NUM
eurjchem-1915	79	12	.	.	PUNCT
eurjchem-1915	80	1	anal	anal	ADJ
eurjchem-1915	80	2	.	.	PUNCT
eurjchem-1915	80	3	calcd	calcd	NOUN
eurjchem-1915	80	4	.	.	PUNCT
eurjchem-1915	81	1	for	for	ADP
eurjchem-1915	81	2	c22h16cl2n4o4	c22h16cl2n4o4	NOUN
eurjchem-1915	81	3	:	:	PUNCT
eurjchem-1915	81	4	c	c	X
eurjchem-1915	81	5	,	,	PUNCT
eurjchem-1915	81	6	56.07	56.07	NUM
eurjchem-1915	81	7	;	;	PUNCT
eurjchem-1915	81	8	h	h	NOUN
eurjchem-1915	81	9	,	,	PUNCT
eurjchem-1915	81	10	3.42	3.42	NUM
eurjchem-1915	81	11	;	;	PUNCT
eurjchem-1915	81	12	n	n	CCONJ
eurjchem-1915	81	13	,	,	PUNCT
eurjchem-1915	81	14	11.89	11.89	NUM
eurjchem-1915	81	15	.	.	PUNCT
eurjchem-1915	82	1	found	find	VERB
eurjchem-1915	82	2	:	:	PUNCT
eurjchem-1915	83	1	c	c	X
eurjchem-1915	83	2	,	,	PUNCT
eurjchem-1915	83	3	56.16	56.16	NUM
eurjchem-1915	83	4	;	;	PUNCT
eurjchem-1915	83	5	h	h	NOUN
eurjchem-1915	83	6	,	,	PUNCT
eurjchem-1915	83	7	3.34	3.34	NUM
eurjchem-1915	83	8	;	;	PUNCT
eurjchem-1915	83	9	n	n	CCONJ
eurjchem-1915	83	10	,	,	PUNCT
eurjchem-1915	83	11	11.91	11.91	NUM
eurjchem-1915	83	12	%	%	NOUN
eurjchem-1915	83	13	.	.	PUNCT
eurjchem-1915	84	1	2.3	2.3	NUM
eurjchem-1915	84	2	.	.	X
eurjchem-1915	85	1	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicarboxylic	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicarboxylic	NUM
eurjchem-1915	85	2	acid	acid	NOUN
eurjchem-1915	85	3	(	(	PUNCT
eurjchem-1915	85	4	6	6	NUM
eurjchem-1915	85	5	)	)	PUNCT
eurjchem-1915	85	6	a	a	DET
eurjchem-1915	85	7	solution	solution	NOUN
eurjchem-1915	85	8	of	of	ADP
eurjchem-1915	85	9	compound	compound	ADJ
eurjchem-1915	85	10	5a	5a	NOUN
eurjchem-1915	85	11	(	(	PUNCT
eurjchem-1915	85	12	1	1	NUM
eurjchem-1915	85	13	mmol	mmol	NOUN
eurjchem-1915	85	14	)	)	PUNCT
eurjchem-1915	85	15	in	in	ADP
eurjchem-1915	85	16	a	a	DET
eurjchem-1915	85	17	mixture	mixture	NOUN
eurjchem-1915	85	18	of	of	ADP
eurjchem-1915	85	19	glacial	glacial	ADJ
eurjchem-1915	85	20	acetic	acetic	ADJ
eurjchem-1915	85	21	acid	acid	NOUN
eurjchem-1915	85	22	(	(	PUNCT
eurjchem-1915	85	23	15	15	NUM
eurjchem-1915	85	24	ml	ml	NOUN
eurjchem-1915	85	25	)	)	PUNCT
eurjchem-1915	85	26	,	,	PUNCT
eurjchem-1915	85	27	hydrochloric	hydrochloric	ADJ
eurjchem-1915	85	28	acid	acid	NOUN
eurjchem-1915	85	29	(	(	PUNCT
eurjchem-1915	85	30	5	5	NUM
eurjchem-1915	85	31	ml	ml	NOUN
eurjchem-1915	85	32	)	)	PUNCT
eurjchem-1915	85	33	and	and	CCONJ
eurjchem-1915	85	34	water	water	NOUN
eurjchem-1915	85	35	(	(	PUNCT
eurjchem-1915	85	36	5	5	NUM
eurjchem-1915	85	37	ml	ml	NOUN
eurjchem-1915	85	38	)	)	PUNCT
eurjchem-1915	85	39	,	,	PUNCT
eurjchem-1915	85	40	was	be	AUX
eurjchem-1915	85	41	refluxed	refluxe	VERB
eurjchem-1915	85	42	for	for	ADP
eurjchem-1915	85	43	5	5	NUM
eurjchem-1915	85	44	h	h	NOUN
eurjchem-1915	85	45	during	during	ADP
eurjchem-1915	85	46	which	which	PRON
eurjchem-1915	85	47	compound	compound	NOUN
eurjchem-1915	85	48	5a	5a	NUM
eurjchem-1915	85	49	was	be	AUX
eurjchem-1915	85	50	dissolved	dissolve	VERB
eurjchem-1915	85	51	and	and	CCONJ
eurjchem-1915	85	52	a	a	DET
eurjchem-1915	85	53	solid	solid	ADJ
eurjchem-1915	85	54	product	product	NOUN
eurjchem-1915	85	55	was	be	AUX
eurjchem-1915	85	56	precipitated	precipitate	VERB
eurjchem-1915	85	57	.	.	PUNCT
eurjchem-1915	86	1	the	the	DET
eurjchem-1915	86	2	mixture	mixture	NOUN
eurjchem-1915	86	3	was	be	AUX
eurjchem-1915	86	4	left	leave	VERB
eurjchem-1915	86	5	to	to	PART
eurjchem-1915	86	6	cool	cool	VERB
eurjchem-1915	86	7	to	to	PART
eurjchem-1915	86	8	room	room	VERB
eurjchem-1915	86	9	temperature	temperature	NOUN
eurjchem-1915	86	10	and	and	CCONJ
eurjchem-1915	86	11	the	the	DET
eurjchem-1915	86	12	precipitate	precipitate	NOUN
eurjchem-1915	86	13	was	be	AUX
eurjchem-1915	86	14	collected	collect	VERB
eurjchem-1915	86	15	by	by	ADP
eurjchem-1915	86	16	filtration	filtration	NOUN
eurjchem-1915	86	17	and	and	CCONJ
eurjchem-1915	86	18	recrystallized	recrystallize	VERB
eurjchem-1915	86	19	from	from	ADP
eurjchem-1915	86	20	acetonitrile	acetonitrile	NOUN
eurjchem-1915	86	21	:	:	PUNCT
eurjchem-1915	86	22	methanol	methanol	NOUN
eurjchem-1915	86	23	(	(	PUNCT
eurjchem-1915	86	24	2:1	2:1	NUM
eurjchem-1915	86	25	,	,	PUNCT
eurjchem-1915	86	26	v	v	NOUN
eurjchem-1915	86	27	:	:	SYM
eurjchem-1915	86	28	v	v	NOUN
eurjchem-1915	86	29	)	)	PUNCT
eurjchem-1915	86	30	to	to	PART
eurjchem-1915	86	31	give	give	VERB
eurjchem-1915	86	32	3,3'-bipyrazole-4,4'-dicarboxylic	3,3'-bipyrazole-4,4'-dicarboxylic	NUM
eurjchem-1915	86	33	acid	acid	NOUN
eurjchem-1915	86	34	(	(	PUNCT
eurjchem-1915	86	35	6	6	NUM
eurjchem-1915	86	36	)	)	PUNCT
eurjchem-1915	86	37	as	as	ADP
eurjchem-1915	86	38	pale	pale	ADJ
eurjchem-1915	86	39	gray	gray	ADJ
eurjchem-1915	86	40	crystals	crystal	NOUN
eurjchem-1915	86	41	(	(	PUNCT
eurjchem-1915	86	42	2.32	2.32	NUM
eurjchem-1915	86	43	g	g	NOUN
eurjchem-1915	86	44	,	,	PUNCT
eurjchem-1915	86	45	62	62	NUM
eurjchem-1915	86	46	%	%	NOUN
eurjchem-1915	86	47	)	)	PUNCT
eurjchem-1915	86	48	(	(	PUNCT
eurjchem-1915	86	49	scheme	scheme	NOUN
eurjchem-1915	86	50	1	1	NUM
eurjchem-1915	86	51	)	)	PUNCT
eurjchem-1915	86	52	.	.	PUNCT
eurjchem-1915	87	1	m.p	m.p	PROPN
eurjchem-1915	87	2	.	.	PROPN
eurjchem-1915	87	3	:	:	PUNCT
eurjchem-1915	88	1	208	208	NUM
eurjchem-1915	88	2	-	-	SYM
eurjchem-1915	88	3	210	210	NUM
eurjchem-1915	88	4	°	°	NOUN
eurjchem-1915	88	5	c	c	NOUN
eurjchem-1915	88	6	.	.	PUNCT
eurjchem-1915	89	1	color	color	NOUN
eurjchem-1915	89	2	:	:	PUNCT
eurjchem-1915	89	3	pale	pale	ADJ
eurjchem-1915	89	4	grey	grey	NOUN
eurjchem-1915	89	5	.	.	PUNCT
eurjchem-1915	90	1	yield	yield	NOUN
eurjchem-1915	90	2	:	:	PUNCT
eurjchem-1915	90	3	62	62	NUM
eurjchem-1915	90	4	%	%	NOUN
eurjchem-1915	90	5	.	.	PUNCT
eurjchem-1915	91	1	ir	ir	PROPN
eurjchem-1915	91	2	(	(	PUNCT
eurjchem-1915	91	3	kbr	kbr	PROPN
eurjchem-1915	91	4	,	,	PUNCT
eurjchem-1915	91	5	ν	ν	PROPN
eurjchem-1915	91	6	,	,	PUNCT
eurjchem-1915	91	7	cm−1	cm−1	NOUN
eurjchem-1915	91	8	):	):	PUNCT
eurjchem-1915	91	9	3427	3427	NUM
eurjchem-1915	91	10	(	(	PUNCT
eurjchem-1915	91	11	oh	oh	INTJ
eurjchem-1915	91	12	,	,	PUNCT
eurjchem-1915	91	13	acid	acid	NOUN
eurjchem-1915	91	14	)	)	PUNCT
eurjchem-1915	91	15	,	,	PUNCT
eurjchem-1915	91	16	3064	3064	NUM
eurjchem-1915	91	17	(	(	PUNCT
eurjchem-1915	91	18	ch	ch	NOUN
eurjchem-1915	91	19	)	)	PUNCT
eurjchem-1915	91	20	,	,	PUNCT
eurjchem-1915	91	21	2981	2981	NUM
eurjchem-1915	91	22	(	(	PUNCT
eurjchem-1915	91	23	ch	ch	NOUN
eurjchem-1915	91	24	)	)	PUNCT
eurjchem-1915	91	25	,	,	PUNCT
eurjchem-1915	91	26	1702	1702	NUM
eurjchem-1915	91	27	(	(	PUNCT
eurjchem-1915	91	28	c	c	NOUN
eurjchem-1915	91	29	=	=	SYM
eurjchem-1915	91	30	o	o	NOUN
eurjchem-1915	91	31	,	,	PUNCT
eurjchem-1915	91	32	acid	acid	NOUN
eurjchem-1915	91	33	)	)	PUNCT
eurjchem-1915	91	34	.	.	PUNCT
eurjchem-1915	92	1	1h	1h	NUM
eurjchem-1915	92	2	nmr	nmr	NOUN
eurjchem-1915	92	3	(	(	PUNCT
eurjchem-1915	92	4	400	400	NUM
eurjchem-1915	92	5	mhz	mhz	NOUN
eurjchem-1915	92	6	,	,	PUNCT
eurjchem-1915	92	7	dmso	dmso	NOUN
eurjchem-1915	92	8	-	-	NOUN
eurjchem-1915	92	9	d6	d6	NOUN
eurjchem-1915	92	10	,	,	PUNCT
eurjchem-1915	92	11	δ	δ	PROPN
eurjchem-1915	92	12	,	,	PUNCT
eurjchem-1915	92	13	ppm	ppm	NUM
eurjchem-1915	92	14	):	):	PUNCT
eurjchem-1915	92	15	7.49	7.49	NUM
eurjchem-1915	92	16	-	-	SYM
eurjchem-1915	92	17	7.37	7.37	NUM
eurjchem-1915	92	18	(	(	PUNCT
eurjchem-1915	92	19	m	m	PROPN
eurjchem-1915	92	20	,	,	PUNCT
eurjchem-1915	92	21	10h	10h	NUM
eurjchem-1915	92	22	,	,	PUNCT
eurjchem-1915	92	23	ar	ar	NOUN
eurjchem-1915	92	24	-	-	NOUN
eurjchem-1915	92	25	h	h	NOUN
eurjchem-1915	92	26	)	)	PUNCT
eurjchem-1915	92	27	,	,	PUNCT
eurjchem-1915	92	28	7.53	7.53	NUM
eurjchem-1915	92	29	(	(	PUNCT
eurjchem-1915	92	30	s	s	PROPN
eurjchem-1915	92	31	,	,	PUNCT
eurjchem-1915	92	32	2h	2h	NUM
eurjchem-1915	92	33	,	,	PUNCT
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eurjchem-1915	92	35	-	-	PUNCT
eurjchem-1915	92	36	h	h	NOUN
eurjchem-1915	92	37	)	)	PUNCT
eurjchem-1915	92	38	,	,	PUNCT
eurjchem-1915	92	39	13.45	13.45	NUM
eurjchem-1915	92	40	(	(	PUNCT
eurjchem-1915	92	41	br	br	NOUN
eurjchem-1915	92	42	.	.	PUNCT
eurjchem-1915	92	43	s	s	PART
eurjchem-1915	92	44	,	,	PUNCT
eurjchem-1915	92	45	2h	2h	NUM
eurjchem-1915	92	46	,	,	PUNCT
eurjchem-1915	92	47	co2h	co2h	PROPN
eurjchem-1915	92	48	)	)	PUNCT
eurjchem-1915	92	49	.	.	PUNCT
eurjchem-1915	93	1	13c	13c	NOUN
eurjchem-1915	93	2	nmr	nmr	NOUN
eurjchem-1915	93	3	(	(	PUNCT
eurjchem-1915	93	4	100	100	NUM
eurjchem-1915	93	5	mhz	mhz	NOUN
eurjchem-1915	93	6	,	,	PUNCT
eurjchem-1915	93	7	dmso	dmso	NOUN
eurjchem-1915	93	8	-	-	NOUN
eurjchem-1915	93	9	d6	d6	NOUN
eurjchem-1915	93	10	,	,	PUNCT
eurjchem-1915	93	11	δ	δ	PROPN
eurjchem-1915	93	12	,	,	PUNCT
eurjchem-1915	93	13	ppm	ppm	NUM
eurjchem-1915	93	14	):	):	PUNCT
eurjchem-1915	93	15	158.2	158.2	NUM
eurjchem-1915	93	16	(	(	PUNCT
eurjchem-1915	93	17	2c	2c	NUM
eurjchem-1915	93	18	,	,	PUNCT
eurjchem-1915	93	19	c	c	PROPN
eurjchem-1915	93	20	=	=	SYM
eurjchem-1915	93	21	o	o	NOUN
eurjchem-1915	93	22	)	)	PUNCT
eurjchem-1915	93	23	,	,	PUNCT
eurjchem-1915	93	24	144.6	144.6	NUM
eurjchem-1915	93	25	(	(	PUNCT
eurjchem-1915	93	26	2c	2c	NUM
eurjchem-1915	93	27	,	,	PUNCT
eurjchem-1915	93	28	pyrazolec	pyrazolec	NOUN
eurjchem-1915	93	29	)	)	PUNCT
eurjchem-1915	93	30	,	,	PUNCT
eurjchem-1915	93	31	128.6	128.6	NUM
eurjchem-1915	93	32	(	(	PUNCT
eurjchem-1915	93	33	2c	2c	NOUN
eurjchem-1915	93	34	,	,	PUNCT
eurjchem-1915	93	35	pyrazole	pyrazole	NOUN
eurjchem-1915	93	36	-	-	PUNCT
eurjchem-1915	93	37	c	c	NOUN
eurjchem-1915	93	38	)	)	PUNCT
eurjchem-1915	93	39	,	,	PUNCT
eurjchem-1915	93	40	109.8	109.8	NUM
eurjchem-1915	93	41	(	(	PUNCT
eurjchem-1915	93	42	2c	2c	NUM
eurjchem-1915	93	43	,	,	PUNCT
eurjchem-1915	93	44	pyrazole	pyrazole	NOUN
eurjchem-1915	93	45	-	-	PUNCT
eurjchem-1915	93	46	c	c	NOUN
eurjchem-1915	93	47	)	)	PUNCT
eurjchem-1915	93	48	,	,	PUNCT
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eurjchem-1915	93	50	(	(	PUNCT
eurjchem-1915	93	51	2c	2c	NOUN
eurjchem-1915	93	52	,	,	PUNCT
eurjchem-1915	93	53	ar	ar	NOUN
eurjchem-1915	93	54	-	-	NOUN
eurjchem-1915	93	55	c	c	NOUN
eurjchem-1915	93	56	)	)	PUNCT
eurjchem-1915	93	57	,	,	PUNCT
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eurjchem-1915	93	59	(	(	PUNCT
eurjchem-1915	93	60	4c	4c	NOUN
eurjchem-1915	93	61	,	,	PUNCT
eurjchem-1915	93	62	ar	ar	NOUN
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eurjchem-1915	93	64	c	c	NOUN
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eurjchem-1915	93	66	,	,	PUNCT
eurjchem-1915	93	67	128.5	128.5	NUM
eurjchem-1915	93	68	(	(	PUNCT
eurjchem-1915	93	69	4c	4c	NOUN
eurjchem-1915	93	70	,	,	PUNCT
eurjchem-1915	93	71	ar	ar	NOUN
eurjchem-1915	93	72	-	-	NOUN
eurjchem-1915	93	73	c	c	NOUN
eurjchem-1915	93	74	)	)	PUNCT
eurjchem-1915	93	75	,	,	PUNCT
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eurjchem-1915	93	77	(	(	PUNCT
eurjchem-1915	93	78	2c	2c	NUM
eurjchem-1915	93	79	,	,	PUNCT
eurjchem-1915	93	80	ar	ar	NOUN
eurjchem-1915	93	81	-	-	NOUN
eurjchem-1915	93	82	c	c	NOUN
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eurjchem-1915	93	84	.	.	PUNCT
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eurjchem-1915	94	2	(	(	PUNCT
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eurjchem-1915	94	4	,	,	PUNCT
eurjchem-1915	94	5	m	m	PROPN
eurjchem-1915	94	6	/	/	SYM
eurjchem-1915	94	7	z	z	ADJ
eurjchem-1915	94	8	)	)	PUNCT
eurjchem-1915	94	9	calcd	calcd	NOUN
eurjchem-1915	94	10	.	.	PUNCT
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eurjchem-1915	95	2	c20h14n4o4	c20h14n4o4	NOUN
eurjchem-1915	95	3	:	:	PUNCT
eurjchem-1915	95	4	374.1015	374.1015	NUM
eurjchem-1915	95	5	(	(	PUNCT
eurjchem-1915	95	6	m+	m+	NUM
eurjchem-1915	95	7	)	)	PUNCT
eurjchem-1915	95	8	;	;	PUNCT
eurjchem-1915	95	9	found	find	VERB
eurjchem-1915	95	10	:	:	PUNCT
eurjchem-1915	95	11	374.1014	374.1014	NUM
eurjchem-1915	95	12	.	.	PUNCT
eurjchem-1915	95	13	anal	anal	ADJ
eurjchem-1915	95	14	.	.	PUNCT
eurjchem-1915	95	15	calcd	calcd	NOUN
eurjchem-1915	95	16	.	.	PUNCT
eurjchem-1915	96	1	for	for	ADP
eurjchem-1915	96	2	c20h14n4o4	c20h14n4o4	NOUN
eurjchem-1915	96	3	:	:	PUNCT
eurjchem-1915	96	4	c	c	X
eurjchem-1915	96	5	,	,	PUNCT
eurjchem-1915	96	6	64.17	64.17	NUM
eurjchem-1915	96	7	;	;	PUNCT
eurjchem-1915	96	8	h	h	NOUN
eurjchem-1915	96	9	,	,	PUNCT
eurjchem-1915	96	10	3.77	3.77	NUM
eurjchem-1915	96	11	;	;	PUNCT
eurjchem-1915	96	12	n	n	CCONJ
eurjchem-1915	96	13	,	,	PUNCT
eurjchem-1915	96	14	14.97	14.97	NUM
eurjchem-1915	96	15	.	.	PUNCT
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eurjchem-1915	96	17	:	:	PUNCT
eurjchem-1915	97	1	c	c	X
eurjchem-1915	97	2	,	,	PUNCT
eurjchem-1915	97	3	64.54	64.54	NUM
eurjchem-1915	97	4	;	;	PUNCT
eurjchem-1915	97	5	h	h	NOUN
eurjchem-1915	97	6	,	,	PUNCT
eurjchem-1915	97	7	3.73	3.73	NUM
eurjchem-1915	97	8	:	:	PUNCT
eurjchem-1915	97	9	n	n	CCONJ
eurjchem-1915	97	10	,	,	PUNCT
eurjchem-1915	97	11	14.75	14.75	NUM
eurjchem-1915	97	12	%	%	NOUN
eurjchem-1915	97	13	.	.	PUNCT
eurjchem-1915	98	1	crystal	crystal	PROPN
eurjchem-1915	98	2	data	data	PROPN
eurjchem-1915	98	3	:	:	PUNCT
eurjchem-1915	98	4	crystal	crystal	NOUN
eurjchem-1915	98	5	dimensions	dimension	NOUN
eurjchem-1915	98	6	0.060	0.060	NUM
eurjchem-1915	98	7	×	×	NOUN
eurjchem-1915	98	8	0.080	0.080	NUM
eurjchem-1915	98	9	×	×	PROPN
eurjchem-1915	98	10	0.200	0.200	NUM
eurjchem-1915	98	11	mm	mm	PROPN
eurjchem-1915	98	12	,	,	PUNCT
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eurjchem-1915	98	14	,	,	PUNCT
eurjchem-1915	98	15	a	a	DET
eurjchem-1915	98	16	=	=	NOUN
eurjchem-1915	98	17	3.9956(10	3.9956(10	NUM
eurjchem-1915	98	18	)	)	PUNCT
eurjchem-1915	98	19	å	å	NOUN
eurjchem-1915	98	20	,	,	PUNCT
eurjchem-1915	98	21	b	b	X
eurjchem-1915	98	22	=	=	SYM
eurjchem-1915	98	23	9.8917(18	9.8917(18	NUM
eurjchem-1915	98	24	)	)	PUNCT
eurjchem-1915	98	25	å	å	NOUN
eurjchem-1915	98	26	,	,	PUNCT
eurjchem-1915	98	27	c	c	NOUN
eurjchem-1915	98	28	=	=	SYM
eurjchem-1915	98	29	10.810(3	10.810(3	NOUN
eurjchem-1915	98	30	)	)	PUNCT
eurjchem-1915	98	31	å	å	NOUN
eurjchem-1915	98	32	,	,	PUNCT
eurjchem-1915	98	33	v	v	NOUN
eurjchem-1915	98	34	=	=	SYM
eurjchem-1915	98	35	418.83	418.83	NUM
eurjchem-1915	98	36	(	(	PUNCT
eurjchem-1915	98	37	16	16	NUM
eurjchem-1915	98	38	)	)	PUNCT
eurjchem-1915	98	39	å3	å3	PROPN
eurjchem-1915	98	40	,	,	PUNCT
eurjchem-1915	98	41	α	α	NOUN
eurjchem-1915	98	42	=	=	SYM
eurjchem-1915	98	43	94.167(15	94.167(15	NUM
eurjchem-1915	98	44	)	)	PUNCT
eurjchem-1915	98	45	°	°	NOUN
eurjchem-1915	98	46	,	,	PUNCT
eurjchem-1915	98	47	β	β	X
eurjchem-1915	98	48	=	=	SYM
eurjchem-1915	98	49	94.979(19	94.979(19	NUM
eurjchem-1915	98	50	)	)	PUNCT
eurjchem-1915	98	51	°	°	PROPN
eurjchem-1915	98	52	,	,	PUNCT
eurjchem-1915	98	53	γ	γ	NOUN
eurjchem-1915	98	54	=	=	SYM
eurjchem-1915	98	55	98.953(15	98.953(15	NUM
eurjchem-1915	98	56	)	)	PUNCT
eurjchem-1915	98	57	°	°	NOUN
eurjchem-1915	98	58	,	,	PUNCT
eurjchem-1915	98	59	θmax	θmax	NOUN
eurjchem-1915	98	60	66.62	66.62	NUM
eurjchem-1915	98	61	°	°	NOUN
eurjchem-1915	98	62	(	(	PUNCT
eurjchem-1915	98	63	0.84	0.84	NUM
eurjchem-1915	98	64	å	å	PROPN
eurjchem-1915	98	65	resolution	resolution	NOUN
eurjchem-1915	98	66	)	)	PUNCT
eurjchem-1915	98	67	,	,	PUNCT
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eurjchem-1915	98	71	,	,	PUNCT
eurjchem-1915	98	72	z	z	NOUN
eurjchem-1915	98	73	=	=	SYM
eurjchem-1915	98	74	2	2	NUM
eurjchem-1915	98	75	,	,	PUNCT
eurjchem-1915	98	76	dcalc	dcalc	NOUN
eurjchem-1915	98	77	=	=	PUNCT
eurjchem-1915	98	78	1.484	1.484	NUM
eurjchem-1915	98	79	g	g	NOUN
eurjchem-1915	98	80	/	/	SYM
eurjchem-1915	98	81	cm3	cm3	NOUN
eurjchem-1915	98	82	,	,	PUNCT
eurjchem-1915	98	83	f000	f000	PROPN
eurjchem-1915	98	84	=	=	SYM
eurjchem-1915	98	85	194	194	NUM
eurjchem-1915	98	86	,	,	PUNCT
eurjchem-1915	98	87	r1	r1	NOUN
eurjchem-1915	98	88	=	=	PUNCT
eurjchem-1915	98	89	10.55	10.55	NUM
eurjchem-1915	98	90	%	%	NOUN
eurjchem-1915	98	91	,	,	PUNCT
eurjchem-1915	98	92	wr2	wr2	PROPN
eurjchem-1915	98	93	=	=	PROPN
eurjchem-1915	98	94	36.20	36.20	NUM
eurjchem-1915	98	95	%	%	NOUN
eurjchem-1915	98	96	.	.	PUNCT
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eurjchem-1915	99	2	.	.	PUNCT
eurjchem-1915	99	3	synthesis	synthesis	NOUN
eurjchem-1915	99	4	of	of	ADP
eurjchem-1915	99	5	bis	bis	ADJ
eurjchem-1915	99	6	-	-	ADJ
eurjchem-1915	99	7	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	99	8	chloride	chloride	NOUN
eurjchem-1915	99	9	-	-	PUNCT
eurjchem-1915	99	10	pdcl2	pdcl2	NOUN
eurjchem-1915	99	11	complex	complex	NOUN
eurjchem-1915	99	12	(	(	PUNCT
eurjchem-1915	99	13	7	7	NUM
eurjchem-1915	99	14	)	)	PUNCT
eurjchem-1915	99	15	a	a	DET
eurjchem-1915	99	16	solution	solution	NOUN
eurjchem-1915	99	17	of	of	ADP
eurjchem-1915	99	18	compound	compound	NOUN
eurjchem-1915	99	19	1a	1a	X
eurjchem-1915	99	20	(	(	PUNCT
eurjchem-1915	99	21	0.307	0.307	NUM
eurjchem-1915	99	22	g	g	NOUN
eurjchem-1915	99	23	,	,	PUNCT
eurjchem-1915	99	24	1	1	NUM
eurjchem-1915	99	25	mmol	mmol	NOUN
eurjchem-1915	99	26	)	)	PUNCT
eurjchem-1915	99	27	in	in	ADP
eurjchem-1915	99	28	dmf	dmf	PROPN
eurjchem-1915	99	29	(	(	PUNCT
eurjchem-1915	99	30	25	25	NUM
eurjchem-1915	99	31	ml	ml	NOUN
eurjchem-1915	99	32	)	)	PUNCT
eurjchem-1915	99	33	was	be	AUX
eurjchem-1915	99	34	added	add	VERB
eurjchem-1915	99	35	to	to	ADP
eurjchem-1915	99	36	a	a	DET
eurjchem-1915	99	37	hot	hot	ADJ
eurjchem-1915	99	38	solution	solution	NOUN
eurjchem-1915	99	39	of	of	ADP
eurjchem-1915	99	40	palladium(ii	palladium(ii	NOUN
eurjchem-1915	99	41	)	)	PUNCT
eurjchem-1915	99	42	chloride	chloride	NOUN
eurjchem-1915	99	43	(	(	PUNCT
eurjchem-1915	99	44	0.177	0.177	NUM
eurjchem-1915	99	45	g	g	NOUN
eurjchem-1915	99	46	,	,	PUNCT
eurjchem-1915	99	47	1	1	NUM
eurjchem-1915	99	48	mmol	mmol	NOUN
eurjchem-1915	99	49	)	)	PUNCT
eurjchem-1915	99	50	in	in	ADP
eurjchem-1915	99	51	methanol	methanol	NOUN
eurjchem-1915	99	52	(	(	PUNCT
eurjchem-1915	99	53	30	30	NUM
eurjchem-1915	99	54	ml	ml	NOUN
eurjchem-1915	99	55	)	)	PUNCT
eurjchem-1915	99	56	.	.	PUNCT
eurjchem-1915	100	1	the	the	DET
eurjchem-1915	100	2	reaction	reaction	NOUN
eurjchem-1915	100	3	mixture	mixture	NOUN
eurjchem-1915	100	4	was	be	AUX
eurjchem-1915	100	5	refluxed	refluxe	VERB
eurjchem-1915	100	6	for	for	ADP
eurjchem-1915	100	7	3	3	NUM
eurjchem-1915	100	8	h	h	NOUN
eurjchem-1915	100	9	,	,	PUNCT
eurjchem-1915	100	10	then	then	ADV
eurjchem-1915	100	11	left	leave	VERB
eurjchem-1915	100	12	to	to	PART
eurjchem-1915	100	13	cool	cool	VERB
eurjchem-1915	100	14	to	to	PART
eurjchem-1915	100	15	room	room	VERB
eurjchem-1915	100	16	temperature	temperature	NOUN
eurjchem-1915	100	17	.	.	PUNCT
eurjchem-1915	101	1	the	the	DET
eurjchem-1915	101	2	formed	form	VERB
eurjchem-1915	101	3	solid	solid	ADJ
eurjchem-1915	101	4	product	product	NOUN
eurjchem-1915	101	5	was	be	AUX
eurjchem-1915	101	6	collected	collect	VERB
eurjchem-1915	101	7	by	by	ADP
eurjchem-1915	101	8	filtration	filtration	NOUN
eurjchem-1915	101	9	,	,	PUNCT
eurjchem-1915	101	10	washed	wash	VERB
eurjchem-1915	101	11	with	with	ADP
eurjchem-1915	101	12	dmf	dmf	PROPN
eurjchem-1915	101	13	then	then	ADV
eurjchem-1915	101	14	water	water	NOUN
eurjchem-1915	101	15	and	and	CCONJ
eurjchem-1915	101	16	ethanol	ethanol	NOUN
eurjchem-1915	101	17	to	to	PART
eurjchem-1915	101	18	give	give	VERB
eurjchem-1915	101	19	the	the	DET
eurjchem-1915	101	20	pd	pd	NOUN
eurjchem-1915	101	21	-	-	NOUN
eurjchem-1915	101	22	complex	complex	ADJ
eurjchem-1915	101	23	7	7	NUM
eurjchem-1915	101	24	as	as	ADP
eurjchem-1915	101	25	pale	pale	ADJ
eurjchem-1915	101	26	gray	gray	ADJ
eurjchem-1915	101	27	solid	solid	ADJ
eurjchem-1915	101	28	(	(	PUNCT
eurjchem-1915	101	29	0.305	0.305	NUM
eurjchem-1915	101	30	g	g	NOUN
eurjchem-1915	101	31	,	,	PUNCT
eurjchem-1915	101	32	63	63	NUM
eurjchem-1915	101	33	%	%	NOUN
eurjchem-1915	101	34	)	)	PUNCT
eurjchem-1915	101	35	(	(	PUNCT
eurjchem-1915	101	36	scheme	scheme	NOUN
eurjchem-1915	101	37	2	2	NUM
eurjchem-1915	101	38	)	)	PUNCT
eurjchem-1915	101	39	.	.	PUNCT
eurjchem-1915	102	1	color	color	NOUN
eurjchem-1915	102	2	:	:	PUNCT
eurjchem-1915	102	3	pale	pale	ADJ
eurjchem-1915	102	4	gray	gray	NOUN
eurjchem-1915	102	5	.	.	PUNCT
eurjchem-1915	103	1	yield	yield	NOUN
eurjchem-1915	103	2	:	:	PUNCT
eurjchem-1915	103	3	63	63	NUM
eurjchem-1915	103	4	%	%	NOUN
eurjchem-1915	103	5	.	.	PUNCT
eurjchem-1915	104	1	m.p	m.p	PROPN
eurjchem-1915	104	2	.	.	PROPN
eurjchem-1915	104	3	:	:	PUNCT
eurjchem-1915	105	1	280	280	NUM
eurjchem-1915	105	2	-	-	SYM
eurjchem-1915	105	3	281	281	NUM
eurjchem-1915	105	4	°	°	NOUN
eurjchem-1915	105	5	c	c	NOUN
eurjchem-1915	105	6	.	.	PUNCT
eurjchem-1915	106	1	ir	ir	PROPN
eurjchem-1915	106	2	(	(	PUNCT
eurjchem-1915	106	3	kbr	kbr	PROPN
eurjchem-1915	106	4	,	,	PUNCT
eurjchem-1915	106	5	ν	ν	PROPN
eurjchem-1915	106	6	,	,	PUNCT
eurjchem-1915	106	7	cm−1	cm−1	NOUN
eurjchem-1915	106	8	):	):	PUNCT
eurjchem-1915	106	9	3321	3321	NUM
eurjchem-1915	106	10	(	(	PUNCT
eurjchem-1915	106	11	nh	nh	NOUN
eurjchem-1915	106	12	)	)	PUNCT
eurjchem-1915	106	13	,	,	PUNCT
eurjchem-1915	106	14	3238	3238	NUM
eurjchem-1915	106	15	(	(	PUNCT
eurjchem-1915	106	16	nh	nh	NOUN
eurjchem-1915	106	17	)	)	PUNCT
eurjchem-1915	106	18	,	,	PUNCT
eurjchem-1915	106	19	3053	3053	NUM
eurjchem-1915	106	20	(	(	PUNCT
eurjchem-1915	106	21	ch	ch	NOUN
eurjchem-1915	106	22	)	)	PUNCT
eurjchem-1915	106	23	,	,	PUNCT
eurjchem-1915	106	24	1639	1639	NUM
eurjchem-1915	106	25	(	(	PUNCT
eurjchem-1915	106	26	c	c	NOUN
eurjchem-1915	106	27	=	=	SYM
eurjchem-1915	106	28	n	n	NUM
eurjchem-1915	106	29	)	)	PUNCT
eurjchem-1915	106	30	.	.	PUNCT
eurjchem-1915	107	1	2019	2019	NUM
eurjchem-1915	107	2	–	–	PUNCT
eurjchem-1915	107	3	european	european	ADJ
eurjchem-1915	107	4	journal	journal	NOUN
eurjchem-1915	107	5	of	of	ADP
eurjchem-1915	107	6	chemistry	chemistry	NOUN
eurjchem-1915	107	7	–	–	PUNCT
eurjchem-1915	107	8	cc	cc	NOUN
eurjchem-1915	107	9	by	by	ADP
eurjchem-1915	107	10	nc	nc	PROPN
eurjchem-1915	107	11	–	–	PUNCT
eurjchem-1915	107	12	doi	doi	PROPN
eurjchem-1915	107	13	:	:	PUNCT
eurjchem-1915	107	14	10.5155	10.5155	NUM
eurjchem-1915	107	15	/	/	SYM
eurjchem-1915	107	16	eurjchem.10.4.367	eurjchem.10.4.367	NUM
eurjchem-1915	107	17	-	-	SYM
eurjchem-1915	107	18	375.1915	375.1915	NUM
eurjchem-1915	107	19	al	al	PROPN
eurjchem-1915	107	20	-	-	PUNCT
eurjchem-1915	107	21	fulaij	fulaij	PROPN
eurjchem-1915	107	22	et	et	PROPN
eurjchem-1915	107	23	al	al	PROPN
eurjchem-1915	107	24	.	.	PUNCT
eurjchem-1915	107	25	/	/	SYM
eurjchem-1915	107	26	european	european	PROPN
eurjchem-1915	107	27	journal	journal	PROPN
eurjchem-1915	107	28	of	of	ADP
eurjchem-1915	107	29	chemistry	chemistry	NOUN
eurjchem-1915	107	30	10	10	NUM
eurjchem-1915	107	31	(	(	PUNCT
eurjchem-1915	107	32	4	4	NUM
eurjchem-1915	107	33	)	)	PUNCT
eurjchem-1915	107	34	(	(	PUNCT
eurjchem-1915	107	35	2019	2019	NUM
eurjchem-1915	107	36	)	)	PUNCT
eurjchem-1915	107	37	367	367	NUM
eurjchem-1915	107	38	-	-	SYM
eurjchem-1915	107	39	375	375	NUM
eurjchem-1915	107	40	369	369	NUM
eurjchem-1915	107	41	scheme	scheme	NOUN
eurjchem-1915	107	42	2	2	NUM
eurjchem-1915	107	43	.	.	PUNCT
eurjchem-1915	107	44	complexation	complexation	NOUN
eurjchem-1915	107	45	of	of	ADP
eurjchem-1915	107	46	bis	bis	ADJ
eurjchem-1915	107	47	-	-	ADJ
eurjchem-1915	107	48	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	107	49	chloride	chloride	PROPN
eurjchem-1915	107	50	1a	1a	PROPN
eurjchem-1915	107	51	and	and	CCONJ
eurjchem-1915	107	52	bipyrazole	bipyrazole	ADJ
eurjchem-1915	107	53	-	-	PUNCT
eurjchem-1915	107	54	dicarboxylic	dicarboxylic	NOUN
eurjchem-1915	107	55	acid	acid	NOUN
eurjchem-1915	107	56	6	6	NUM
eurjchem-1915	107	57	with	with	ADP
eurjchem-1915	107	58	pdcl2	pdcl2	NOUN
eurjchem-1915	107	59	.	.	PUNCT
eurjchem-1915	108	1	1h	1h	NUM
eurjchem-1915	108	2	nmr	nmr	NOUN
eurjchem-1915	108	3	(	(	PUNCT
eurjchem-1915	108	4	400	400	NUM
eurjchem-1915	108	5	mhz	mhz	NOUN
eurjchem-1915	108	6	,	,	PUNCT
eurjchem-1915	108	7	dmso	dmso	NOUN
eurjchem-1915	108	8	-	-	NOUN
eurjchem-1915	108	9	d6	d6	NOUN
eurjchem-1915	108	10	,	,	PUNCT
eurjchem-1915	108	11	δ	δ	PROPN
eurjchem-1915	108	12	,	,	PUNCT
eurjchem-1915	108	13	ppm	ppm	NUM
eurjchem-1915	108	14	):	):	PUNCT
eurjchem-1915	108	15	7.08	7.08	NUM
eurjchem-1915	108	16	-	-	SYM
eurjchem-1915	108	17	6.38	6.38	NUM
eurjchem-1915	108	18	(	(	PUNCT
eurjchem-1915	108	19	m	m	PROPN
eurjchem-1915	108	20	,	,	PUNCT
eurjchem-1915	108	21	10h	10h	NUM
eurjchem-1915	108	22	,	,	PUNCT
eurjchem-1915	108	23	ar	ar	NOUN
eurjchem-1915	108	24	-	-	NOUN
eurjchem-1915	108	25	h	h	NOUN
eurjchem-1915	108	26	)	)	PUNCT
eurjchem-1915	108	27	,	,	PUNCT
eurjchem-1915	108	28	7.96	7.96	NUM
eurjchem-1915	108	29	(	(	PUNCT
eurjchem-1915	108	30	br	br	NOUN
eurjchem-1915	108	31	.	.	PUNCT
eurjchem-1915	108	32	s	s	PART
eurjchem-1915	108	33	,	,	PUNCT
eurjchem-1915	108	34	1h	1h	NUM
eurjchem-1915	108	35	,	,	PUNCT
eurjchem-1915	108	36	nh	nh	PROPN
eurjchem-1915	108	37	)	)	PUNCT
eurjchem-1915	108	38	,	,	PUNCT
eurjchem-1915	108	39	10.66	10.66	NUM
eurjchem-1915	108	40	(	(	PUNCT
eurjchem-1915	108	41	br	br	NOUN
eurjchem-1915	108	42	.	.	PUNCT
eurjchem-1915	108	43	s	s	PART
eurjchem-1915	108	44	,	,	PUNCT
eurjchem-1915	108	45	1h	1h	NUM
eurjchem-1915	108	46	,	,	PUNCT
eurjchem-1915	108	47	nh	nh	PROPN
eurjchem-1915	108	48	)	)	PUNCT
eurjchem-1915	108	49	.	.	PUNCT
eurjchem-1915	109	1	13c	13c	NOUN
eurjchem-1915	109	2	nmr	nmr	NOUN
eurjchem-1915	109	3	(	(	PUNCT
eurjchem-1915	109	4	100	100	NUM
eurjchem-1915	109	5	mhz	mhz	NOUN
eurjchem-1915	109	6	,	,	PUNCT
eurjchem-1915	109	7	dmso	dmso	NOUN
eurjchem-1915	109	8	-	-	NOUN
eurjchem-1915	109	9	d6	d6	NOUN
eurjchem-1915	109	10	,	,	PUNCT
eurjchem-1915	109	11	δ	δ	PROPN
eurjchem-1915	109	12	,	,	PUNCT
eurjchem-1915	109	13	ppm	ppm	NOUN
eurjchem-1915	109	14	):	):	PUNCT
eurjchem-1915	109	15	156.2	156.2	NUM
eurjchem-1915	109	16	(	(	PUNCT
eurjchem-1915	109	17	2c	2c	NUM
eurjchem-1915	109	18	,	,	PUNCT
eurjchem-1915	109	19	c	c	NOUN
eurjchem-1915	109	20	=	=	SYM
eurjchem-1915	109	21	n	n	NUM
eurjchem-1915	109	22	)	)	PUNCT
eurjchem-1915	109	23	,	,	PUNCT
eurjchem-1915	109	24	144.3	144.3	NUM
eurjchem-1915	109	25	(	(	PUNCT
eurjchem-1915	109	26	2c	2c	NUM
eurjchem-1915	109	27	,	,	PUNCT
eurjchem-1915	109	28	ar	ar	NOUN
eurjchem-1915	109	29	-	-	NOUN
eurjchem-1915	109	30	c	c	NOUN
eurjchem-1915	109	31	)	)	PUNCT
eurjchem-1915	109	32	,	,	PUNCT
eurjchem-1915	109	33	130.2	130.2	NUM
eurjchem-1915	109	34	(	(	PUNCT
eurjchem-1915	109	35	4c	4c	NOUN
eurjchem-1915	109	36	,	,	PUNCT
eurjchem-1915	109	37	ar	ar	NOUN
eurjchem-1915	109	38	-	-	NOUN
eurjchem-1915	109	39	c	c	NOUN
eurjchem-1915	109	40	)	)	PUNCT
eurjchem-1915	109	41	,	,	PUNCT
eurjchem-1915	109	42	120.0	120.0	NUM
eurjchem-1915	109	43	(	(	PUNCT
eurjchem-1915	109	44	2c	2c	NUM
eurjchem-1915	109	45	,	,	PUNCT
eurjchem-1915	109	46	ar	ar	NOUN
eurjchem-1915	109	47	-	-	NOUN
eurjchem-1915	109	48	c	c	NOUN
eurjchem-1915	109	49	)	)	PUNCT
eurjchem-1915	109	50	,	,	PUNCT
eurjchem-1915	109	51	118.23	118.23	NUM
eurjchem-1915	109	52	(	(	PUNCT
eurjchem-1915	109	53	4c	4c	NOUN
eurjchem-1915	109	54	,	,	PUNCT
eurjchem-1915	109	55	ar	ar	NOUN
eurjchem-1915	109	56	-	-	NOUN
eurjchem-1915	109	57	c	c	NOUN
eurjchem-1915	109	58	)	)	PUNCT
eurjchem-1915	109	59	.	.	PUNCT
eurjchem-1915	110	1	ms	ms	NOUN
eurjchem-1915	110	2	(	(	PUNCT
eurjchem-1915	110	3	ei	ei	PROPN
eurjchem-1915	110	4	)	)	PUNCT
eurjchem-1915	110	5	,	,	PUNCT
eurjchem-1915	110	6	m	m	PROPN
eurjchem-1915	110	7	/	/	SYM
eurjchem-1915	110	8	z	z	PROPN
eurjchem-1915	110	9	(	(	PUNCT
eurjchem-1915	110	10	%	%	NOUN
eurjchem-1915	110	11	)	)	PUNCT
eurjchem-1915	110	12	):	):	PUNCT
eurjchem-1915	110	13	484.50	484.50	NUM
eurjchem-1915	110	14	(	(	PUNCT
eurjchem-1915	110	15	m+	m+	NUM
eurjchem-1915	110	16	,	,	PUNCT
eurjchem-1915	110	17	73	73	NUM
eurjchem-1915	110	18	%	%	NOUN
eurjchem-1915	110	19	)	)	PUNCT
eurjchem-1915	110	20	,	,	PUNCT
eurjchem-1915	110	21	271.0	271.0	NUM
eurjchem-1915	110	22	(	(	PUNCT
eurjchem-1915	110	23	32	32	NUM
eurjchem-1915	110	24	%	%	NOUN
eurjchem-1915	110	25	)	)	PUNCT
eurjchem-1915	110	26	,	,	PUNCT
eurjchem-1915	110	27	237.1	237.1	NUM
eurjchem-1915	110	28	(	(	PUNCT
eurjchem-1915	110	29	44	44	NUM
eurjchem-1915	110	30	%	%	NOUN
eurjchem-1915	110	31	)	)	PUNCT
eurjchem-1915	110	32	,	,	PUNCT
eurjchem-1915	110	33	214.0	214.0	NUM
eurjchem-1915	110	34	(	(	PUNCT
eurjchem-1915	110	35	63	63	NUM
eurjchem-1915	110	36	%	%	NOUN
eurjchem-1915	110	37	)	)	PUNCT
eurjchem-1915	110	38	,	,	PUNCT
eurjchem-1915	110	39	122.0	122.0	NUM
eurjchem-1915	110	40	(	(	PUNCT
eurjchem-1915	110	41	23	23	NUM
eurjchem-1915	110	42	%	%	NOUN
eurjchem-1915	110	43	)	)	PUNCT
eurjchem-1915	110	44	.	.	PUNCT
eurjchem-1915	111	1	uv	uv	NOUN
eurjchem-1915	111	2	/	/	SYM
eurjchem-1915	111	3	vis	vis	X
eurjchem-1915	111	4	(	(	PUNCT
eurjchem-1915	111	5	chcl3	chcl3	PROPN
eurjchem-1915	111	6	,	,	PUNCT
eurjchem-1915	111	7	λmax	λmax	NOUN
eurjchem-1915	111	8	,	,	PUNCT
eurjchem-1915	111	9	nm	nm	NOUN
eurjchem-1915	111	10	,	,	PUNCT
eurjchem-1915	111	11	(	(	PUNCT
eurjchem-1915	111	12	ε	ε	PROPN
eurjchem-1915	111	13	)	)	PUNCT
eurjchem-1915	111	14	):	):	PUNCT
eurjchem-1915	112	1	239.55	239.55	NUM
eurjchem-1915	112	2	,	,	PUNCT
eurjchem-1915	112	3	292.0	292.0	NUM
eurjchem-1915	112	4	,	,	PUNCT
eurjchem-1915	112	5	326.17	326.17	NUM
eurjchem-1915	112	6	.	.	PUNCT
eurjchem-1915	113	1	anal	anal	ADJ
eurjchem-1915	113	2	.	.	PUNCT
eurjchem-1915	113	3	calcd	calcd	NOUN
eurjchem-1915	113	4	.	.	PUNCT
eurjchem-1915	114	1	for	for	SCONJ
eurjchem-1915	114	2	c14h12cl4n4pd	c14h12cl4n4pd	PROPN
eurjchem-1915	114	3	:	:	PUNCT
eurjchem-1915	114	4	c	c	NOUN
eurjchem-1915	114	5	,	,	PUNCT
eurjchem-1915	114	6	34.71	34.71	NUM
eurjchem-1915	114	7	;	;	PUNCT
eurjchem-1915	114	8	h	h	NOUN
eurjchem-1915	114	9	,	,	PUNCT
eurjchem-1915	114	10	2.50	2.50	NUM
eurjchem-1915	114	11	;	;	PUNCT
eurjchem-1915	114	12	n	n	CCONJ
eurjchem-1915	114	13	,	,	PUNCT
eurjchem-1915	114	14	11.56	11.56	NUM
eurjchem-1915	114	15	.	.	PUNCT
eurjchem-1915	114	16	found	find	VERB
eurjchem-1915	114	17	:	:	PUNCT
eurjchem-1915	115	1	c	c	X
eurjchem-1915	115	2	,	,	PUNCT
eurjchem-1915	115	3	34.54	34.54	NUM
eurjchem-1915	115	4	;	;	PUNCT
eurjchem-1915	115	5	h	h	NOUN
eurjchem-1915	115	6	,	,	PUNCT
eurjchem-1915	115	7	2.73	2.73	NUM
eurjchem-1915	115	8	;	;	PUNCT
eurjchem-1915	115	9	n	n	CCONJ
eurjchem-1915	115	10	,	,	PUNCT
eurjchem-1915	115	11	11.43	11.43	NUM
eurjchem-1915	115	12	%	%	NOUN
eurjchem-1915	115	13	.	.	PUNCT
eurjchem-1915	116	1	edx	edx	PROPN
eurjchem-1915	116	2	anal	anal	PROPN
eurjchem-1915	116	3	.	.	PUNCT
eurjchem-1915	117	1	for	for	ADP
eurjchem-1915	117	2	pd	pd	PROPN
eurjchem-1915	117	3	:	:	PUNCT
eurjchem-1915	117	4	calcd	calcd	NOUN
eurjchem-1915	117	5	.	.	PUNCT
eurjchem-1915	117	6	:	:	PUNCT
eurjchem-1915	117	7	21.96	21.96	NUM
eurjchem-1915	117	8	%	%	NOUN
eurjchem-1915	117	9	,	,	PUNCT
eurjchem-1915	117	10	found	find	VERB
eurjchem-1915	117	11	21.70	21.70	NUM
eurjchem-1915	117	12	%	%	NOUN
eurjchem-1915	117	13	.	.	PUNCT
eurjchem-1915	118	1	2.5	2.5	NUM
eurjchem-1915	118	2	.	.	PUNCT
eurjchem-1915	119	1	synthesis	synthesis	NOUN
eurjchem-1915	119	2	of	of	ADP
eurjchem-1915	119	3	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicar	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicar	NUM
eurjchem-1915	119	4	boxylic	boxylic	ADJ
eurjchem-1915	119	5	acid	acid	NOUN
eurjchem-1915	119	6	-	-	PUNCT
eurjchem-1915	119	7	palladium(ii	palladium(ii	NOUN
eurjchem-1915	119	8	)	)	PUNCT
eurjchem-1915	119	9	chloride	chloride	NOUN
eurjchem-1915	119	10	complex	complex	NOUN
eurjchem-1915	119	11	(	(	PUNCT
eurjchem-1915	119	12	8)	8)	NUM
eurjchem-1915	119	13	a	a	DET
eurjchem-1915	119	14	solution	solution	NOUN
eurjchem-1915	119	15	of	of	ADP
eurjchem-1915	119	16	palladium(ii	palladium(ii	NOUN
eurjchem-1915	119	17	)	)	PUNCT
eurjchem-1915	119	18	chloride	chloride	NOUN
eurjchem-1915	119	19	(	(	PUNCT
eurjchem-1915	119	20	0.354	0.354	NUM
eurjchem-1915	119	21	g	g	NOUN
eurjchem-1915	119	22	,	,	PUNCT
eurjchem-1915	119	23	2	2	NUM
eurjchem-1915	119	24	mmol	mmol	NOUN
eurjchem-1915	119	25	)	)	PUNCT
eurjchem-1915	119	26	in	in	ADP
eurjchem-1915	119	27	methanol	methanol	NOUN
eurjchem-1915	119	28	(	(	PUNCT
eurjchem-1915	119	29	25	25	NUM
eurjchem-1915	119	30	ml	ml	NOUN
eurjchem-1915	119	31	)	)	PUNCT
eurjchem-1915	119	32	was	be	AUX
eurjchem-1915	119	33	added	add	VERB
eurjchem-1915	119	34	to	to	ADP
eurjchem-1915	119	35	a	a	DET
eurjchem-1915	119	36	solution	solution	NOUN
eurjchem-1915	119	37	of	of	ADP
eurjchem-1915	119	38	compound	compound	NOUN
eurjchem-1915	119	39	6	6	NUM
eurjchem-1915	119	40	(	(	PUNCT
eurjchem-1915	119	41	0.374	0.374	NUM
eurjchem-1915	119	42	g	g	NOUN
eurjchem-1915	119	43	,	,	PUNCT
eurjchem-1915	119	44	1	1	NUM
eurjchem-1915	119	45	mmol	mmol	NOUN
eurjchem-1915	119	46	)	)	PUNCT
eurjchem-1915	119	47	in	in	ADP
eurjchem-1915	119	48	methanol	methanol	NOUN
eurjchem-1915	119	49	(	(	PUNCT
eurjchem-1915	119	50	25	25	NUM
eurjchem-1915	119	51	ml	ml	NOUN
eurjchem-1915	119	52	)	)	PUNCT
eurjchem-1915	119	53	.	.	PUNCT
eurjchem-1915	120	1	the	the	DET
eurjchem-1915	120	2	reaction	reaction	NOUN
eurjchem-1915	120	3	mixture	mixture	NOUN
eurjchem-1915	120	4	was	be	AUX
eurjchem-1915	120	5	refluxed	refluxe	VERB
eurjchem-1915	120	6	for	for	ADP
eurjchem-1915	120	7	5h	5h	NUM
eurjchem-1915	120	8	,	,	PUNCT
eurjchem-1915	120	9	then	then	ADV
eurjchem-1915	120	10	left	leave	VERB
eurjchem-1915	120	11	to	to	PART
eurjchem-1915	120	12	cool	cool	VERB
eurjchem-1915	120	13	to	to	PART
eurjchem-1915	120	14	room	room	VERB
eurjchem-1915	120	15	temperature	temperature	NOUN
eurjchem-1915	120	16	.	.	PUNCT
eurjchem-1915	121	1	the	the	DET
eurjchem-1915	121	2	precipitated	precipitate	VERB
eurjchem-1915	121	3	solid	solid	ADJ
eurjchem-1915	121	4	product	product	NOUN
eurjchem-1915	121	5	was	be	AUX
eurjchem-1915	121	6	collected	collect	VERB
eurjchem-1915	121	7	by	by	ADP
eurjchem-1915	121	8	filtration	filtration	NOUN
eurjchem-1915	121	9	and	and	CCONJ
eurjchem-1915	121	10	recrystallized	recrystallize	VERB
eurjchem-1915	121	11	from	from	ADP
eurjchem-1915	121	12	dmf	dmf	PROPN
eurjchem-1915	121	13	/	/	SYM
eurjchem-1915	121	14	acetonitrile	acetonitrile	NOUN
eurjchem-1915	121	15	(	(	PUNCT
eurjchem-1915	121	16	1:1	1:1	NUM
eurjchem-1915	121	17	)	)	PUNCT
eurjchem-1915	121	18	to	to	PART
eurjchem-1915	121	19	yield	yield	VERB
eurjchem-1915	121	20	the	the	DET
eurjchem-1915	121	21	pdcomplex	pdcomplex	NOUN
eurjchem-1915	121	22	8	8	NUM
eurjchem-1915	121	23	as	as	ADP
eurjchem-1915	121	24	green	green	ADJ
eurjchem-1915	121	25	solid	solid	ADJ
eurjchem-1915	121	26	(	(	PUNCT
eurjchem-1915	121	27	0.67	0.67	NUM
eurjchem-1915	121	28	g	g	NOUN
eurjchem-1915	121	29	)	)	PUNCT
eurjchem-1915	121	30	(	(	PUNCT
eurjchem-1915	121	31	scheme	scheme	NOUN
eurjchem-1915	121	32	2	2	NUM
eurjchem-1915	121	33	)	)	PUNCT
eurjchem-1915	121	34	.	.	PUNCT
eurjchem-1915	122	1	color	color	NOUN
eurjchem-1915	122	2	:	:	PUNCT
eurjchem-1915	122	3	green	green	ADJ
eurjchem-1915	122	4	.	.	PUNCT
eurjchem-1915	123	1	yield	yield	NOUN
eurjchem-1915	123	2	:	:	PUNCT
eurjchem-1915	123	3	92	92	NUM
eurjchem-1915	123	4	%	%	NOUN
eurjchem-1915	123	5	.	.	PUNCT
eurjchem-1915	124	1	m.p	m.p	PROPN
eurjchem-1915	124	2	.	.	PROPN
eurjchem-1915	124	3	:	:	PUNCT
eurjchem-1915	125	1	264	264	NUM
eurjchem-1915	125	2	-	-	SYM
eurjchem-1915	125	3	266	266	NUM
eurjchem-1915	125	4	°	°	NOUN
eurjchem-1915	125	5	c	c	NOUN
eurjchem-1915	125	6	.	.	PUNCT
eurjchem-1915	126	1	ir	ir	PROPN
eurjchem-1915	126	2	(	(	PUNCT
eurjchem-1915	126	3	kbr	kbr	PROPN
eurjchem-1915	126	4	,	,	PUNCT
eurjchem-1915	126	5	ν	ν	PROPN
eurjchem-1915	126	6	,	,	PUNCT
eurjchem-1915	126	7	cm−1	cm−1	NOUN
eurjchem-1915	126	8	):	):	PUNCT
eurjchem-1915	126	9	3435	3435	NUM
eurjchem-1915	126	10	(	(	PUNCT
eurjchem-1915	126	11	oh	oh	INTJ
eurjchem-1915	126	12	)	)	PUNCT
eurjchem-1915	126	13	,	,	PUNCT
eurjchem-1915	126	14	3062	3062	NUM
eurjchem-1915	126	15	(	(	PUNCT
eurjchem-1915	126	16	ch	ch	NOUN
eurjchem-1915	126	17	)	)	PUNCT
eurjchem-1915	126	18	,	,	PUNCT
eurjchem-1915	126	19	1725	1725	NUM
eurjchem-1915	126	20	(	(	PUNCT
eurjchem-1915	126	21	c	c	NOUN
eurjchem-1915	126	22	=	=	NOUN
eurjchem-1915	126	23	o	o	NOUN
eurjchem-1915	126	24	)	)	PUNCT
eurjchem-1915	126	25	,	,	PUNCT
eurjchem-1915	126	26	1703	1703	NUM
eurjchem-1915	126	27	(	(	PUNCT
eurjchem-1915	126	28	c	c	NOUN
eurjchem-1915	126	29	=	=	NOUN
eurjchem-1915	126	30	o	o	NOUN
eurjchem-1915	126	31	)	)	PUNCT
eurjchem-1915	126	32	.	.	PUNCT
eurjchem-1915	127	1	1h	1h	NUM
eurjchem-1915	127	2	nmr	nmr	NOUN
eurjchem-1915	127	3	(	(	PUNCT
eurjchem-1915	127	4	400	400	NUM
eurjchem-1915	127	5	mhz	mhz	NOUN
eurjchem-1915	127	6	,	,	PUNCT
eurjchem-1915	127	7	dmso	dmso	NOUN
eurjchem-1915	127	8	-	-	NOUN
eurjchem-1915	127	9	d6	d6	NOUN
eurjchem-1915	127	10	,	,	PUNCT
eurjchem-1915	127	11	δ	δ	PROPN
eurjchem-1915	127	12	,	,	PUNCT
eurjchem-1915	127	13	ppm	ppm	NOUN
eurjchem-1915	127	14	):	):	PUNCT
eurjchem-1915	127	15	7.07	7.07	NUM
eurjchem-1915	127	16	(	(	PUNCT
eurjchem-1915	127	17	s	s	PROPN
eurjchem-1915	127	18	,	,	PUNCT
eurjchem-1915	127	19	2h	2h	NUM
eurjchem-1915	127	20	,	,	PUNCT
eurjchem-1915	127	21	pyrazole	pyrazole	NOUN
eurjchem-1915	127	22	-	-	PUNCT
eurjchem-1915	127	23	h	h	NOUN
eurjchem-1915	127	24	)	)	PUNCT
eurjchem-1915	127	25	,	,	PUNCT
eurjchem-1915	127	26	7.53	7.53	NUM
eurjchem-1915	127	27	-	-	SYM
eurjchem-1915	127	28	7.19	7.19	NUM
eurjchem-1915	127	29	(	(	PUNCT
eurjchem-1915	127	30	m	m	PROPN
eurjchem-1915	127	31	,	,	PUNCT
eurjchem-1915	127	32	10h	10h	NUM
eurjchem-1915	127	33	,	,	PUNCT
eurjchem-1915	127	34	ar	ar	NOUN
eurjchem-1915	127	35	-	-	NOUN
eurjchem-1915	127	36	h	h	NOUN
eurjchem-1915	127	37	)	)	PUNCT
eurjchem-1915	127	38	,	,	PUNCT
eurjchem-1915	127	39	13.48	13.48	NUM
eurjchem-1915	127	40	(	(	PUNCT
eurjchem-1915	127	41	br	br	NOUN
eurjchem-1915	127	42	.	.	PUNCT
eurjchem-1915	127	43	s	s	PART
eurjchem-1915	127	44	,	,	PUNCT
eurjchem-1915	127	45	2h	2h	NUM
eurjchem-1915	127	46	,	,	PUNCT
eurjchem-1915	127	47	co2h	co2h	PROPN
eurjchem-1915	127	48	)	)	PUNCT
eurjchem-1915	127	49	.	.	PUNCT
eurjchem-1915	128	1	13c	13c	NOUN
eurjchem-1915	128	2	nmr	nmr	NOUN
eurjchem-1915	128	3	(	(	PUNCT
eurjchem-1915	128	4	100	100	NUM
eurjchem-1915	128	5	mhz	mhz	NOUN
eurjchem-1915	128	6	,	,	PUNCT
eurjchem-1915	128	7	dmso	dmso	NOUN
eurjchem-1915	128	8	-	-	NOUN
eurjchem-1915	128	9	d6	d6	NOUN
eurjchem-1915	128	10	,	,	PUNCT
eurjchem-1915	128	11	δ	δ	PROPN
eurjchem-1915	128	12	,	,	PUNCT
eurjchem-1915	128	13	ppm	ppm	NUM
eurjchem-1915	128	14	):	):	PUNCT
eurjchem-1915	128	15	159.7	159.7	NUM
eurjchem-1915	128	16	(	(	PUNCT
eurjchem-1915	128	17	2c	2c	NUM
eurjchem-1915	128	18	,	,	PUNCT
eurjchem-1915	128	19	c	c	PROPN
eurjchem-1915	128	20	=	=	SYM
eurjchem-1915	128	21	o	o	NOUN
eurjchem-1915	128	22	,	,	PUNCT
eurjchem-1915	128	23	co2h	co2h	PROPN
eurjchem-1915	128	24	)	)	PUNCT
eurjchem-1915	128	25	,	,	PUNCT
eurjchem-1915	128	26	158.2	158.2	NUM
eurjchem-1915	128	27	(	(	PUNCT
eurjchem-1915	128	28	2c	2c	NUM
eurjchem-1915	128	29	,	,	PUNCT
eurjchem-1915	128	30	c	c	NOUN
eurjchem-1915	128	31	=	=	SYM
eurjchem-1915	128	32	n	n	CCONJ
eurjchem-1915	128	33	,	,	PUNCT
eurjchem-1915	128	34	pyrazole	pyrazole	NOUN
eurjchem-1915	128	35	-	-	PUNCT
eurjchem-1915	128	36	c	c	NOUN
eurjchem-1915	128	37	)	)	PUNCT
eurjchem-1915	128	38	,	,	PUNCT
eurjchem-1915	128	39	144.6	144.6	NUM
eurjchem-1915	128	40	(	(	PUNCT
eurjchem-1915	128	41	2c	2c	NUM
eurjchem-1915	128	42	,	,	PUNCT
eurjchem-1915	128	43	ar	ar	NOUN
eurjchem-1915	128	44	-	-	NOUN
eurjchem-1915	128	45	c	c	NOUN
eurjchem-1915	128	46	)	)	PUNCT
eurjchem-1915	128	47	,	,	PUNCT
eurjchem-1915	128	48	140.0	140.0	NUM
eurjchem-1915	128	49	(	(	PUNCT
eurjchem-1915	128	50	4c	4c	NOUN
eurjchem-1915	128	51	,	,	PUNCT
eurjchem-1915	128	52	ar	ar	NOUN
eurjchem-1915	128	53	-	-	NOUN
eurjchem-1915	128	54	c	c	NOUN
eurjchem-1915	128	55	)	)	PUNCT
eurjchem-1915	128	56	,	,	PUNCT
eurjchem-1915	128	57	134.4	134.4	NUM
eurjchem-1915	128	58	(	(	PUNCT
eurjchem-1915	128	59	2c	2c	NOUN
eurjchem-1915	128	60	,	,	PUNCT
eurjchem-1915	128	61	pyrazole	pyrazole	NOUN
eurjchem-1915	128	62	-	-	PUNCT
eurjchem-1915	128	63	c	c	NOUN
eurjchem-1915	128	64	)	)	PUNCT
eurjchem-1915	128	65	,	,	PUNCT
eurjchem-1915	128	66	128.6	128.6	NUM
eurjchem-1915	128	67	(	(	PUNCT
eurjchem-1915	128	68	2c	2c	NUM
eurjchem-1915	128	69	,	,	PUNCT
eurjchem-1915	128	70	ar	ar	NOUN
eurjchem-1915	128	71	-	-	NOUN
eurjchem-1915	128	72	c	c	NOUN
eurjchem-1915	128	73	)	)	PUNCT
eurjchem-1915	128	74	,	,	PUNCT
eurjchem-1915	128	75	125.8	125.8	NUM
eurjchem-1915	128	76	(	(	PUNCT
eurjchem-1915	128	77	4c	4c	NOUN
eurjchem-1915	128	78	,	,	PUNCT
eurjchem-1915	128	79	ar	ar	NOUN
eurjchem-1915	128	80	-	-	NOUN
eurjchem-1915	128	81	c	c	NOUN
eurjchem-1915	128	82	)	)	PUNCT
eurjchem-1915	128	83	,	,	PUNCT
eurjchem-1915	128	84	109.8	109.8	NUM
eurjchem-1915	128	85	(	(	PUNCT
eurjchem-1915	128	86	2c	2c	NUM
eurjchem-1915	128	87	,	,	PUNCT
eurjchem-1915	128	88	pyrazole	pyrazole	NOUN
eurjchem-1915	128	89	-	-	PUNCT
eurjchem-1915	128	90	c	c	NOUN
eurjchem-1915	128	91	)	)	PUNCT
eurjchem-1915	128	92	.	.	PUNCT
eurjchem-1915	129	1	uv	uv	NOUN
eurjchem-1915	129	2	/	/	SYM
eurjchem-1915	129	3	vis	vis	X
eurjchem-1915	129	4	(	(	PUNCT
eurjchem-1915	129	5	chcl3	chcl3	PROPN
eurjchem-1915	129	6	,	,	PUNCT
eurjchem-1915	129	7	λmax	λmax	NOUN
eurjchem-1915	129	8	,	,	PUNCT
eurjchem-1915	129	9	nm	nm	NOUN
eurjchem-1915	129	10	,	,	PUNCT
eurjchem-1915	129	11	(	(	PUNCT
eurjchem-1915	129	12	ε	ε	PROPN
eurjchem-1915	129	13	)	)	PUNCT
eurjchem-1915	129	14	):	):	PUNCT
eurjchem-1915	129	15	266	266	NUM
eurjchem-1915	129	16	.	.	PUNCT
eurjchem-1915	130	1	anal	anal	ADJ
eurjchem-1915	130	2	.	.	PUNCT
eurjchem-1915	130	3	calcd	calcd	NOUN
eurjchem-1915	130	4	.	.	PUNCT
eurjchem-1915	131	1	for	for	ADP
eurjchem-1915	131	2	c20h14cl4n4o4pd2	c20h14cl4n4o4pd2	NOUN
eurjchem-1915	131	3	:	:	PUNCT
eurjchem-1915	131	4	c	c	X
eurjchem-1915	131	5	,	,	PUNCT
eurjchem-1915	131	6	32.95	32.95	NUM
eurjchem-1915	131	7	;	;	PUNCT
eurjchem-1915	131	8	h	h	NOUN
eurjchem-1915	131	9	,	,	PUNCT
eurjchem-1915	131	10	1.94	1.94	NUM
eurjchem-1915	131	11	;	;	PUNCT
eurjchem-1915	131	12	n	n	CCONJ
eurjchem-1915	131	13	,	,	PUNCT
eurjchem-1915	131	14	7.69	7.69	NUM
eurjchem-1915	131	15	.	.	PUNCT
eurjchem-1915	131	16	found	find	VERB
eurjchem-1915	131	17	:	:	PUNCT
eurjchem-1915	132	1	c	c	X
eurjchem-1915	132	2	,	,	PUNCT
eurjchem-1915	132	3	32.75	32.75	NUM
eurjchem-1915	132	4	;	;	PUNCT
eurjchem-1915	132	5	h	h	NOUN
eurjchem-1915	132	6	,	,	PUNCT
eurjchem-1915	132	7	2.03	2.03	NUM
eurjchem-1915	132	8	;	;	PUNCT
eurjchem-1915	132	9	n	n	CCONJ
eurjchem-1915	132	10	,	,	PUNCT
eurjchem-1915	132	11	6.87	6.87	NUM
eurjchem-1915	132	12	%	%	NOUN
eurjchem-1915	132	13	.	.	PUNCT
eurjchem-1915	133	1	edx	edx	PROPN
eurjchem-1915	133	2	anal	anal	PROPN
eurjchem-1915	133	3	.	.	PUNCT
eurjchem-1915	134	1	for	for	ADP
eurjchem-1915	134	2	pd	pd	PROPN
eurjchem-1915	134	3	:	:	PUNCT
eurjchem-1915	134	4	calcd	calcd	NOUN
eurjchem-1915	134	5	.	.	PUNCT
eurjchem-1915	135	1	29.20	29.20	NUM
eurjchem-1915	135	2	%	%	NOUN
eurjchem-1915	135	3	,	,	PUNCT
eurjchem-1915	135	4	found	find	VERB
eurjchem-1915	135	5	.	.	PUNCT
eurjchem-1915	136	1	29.6	29.6	NUM
eurjchem-1915	136	2	%	%	NOUN
eurjchem-1915	136	3	.	.	PUNCT
eurjchem-1915	137	1	2.6	2.6	NUM
eurjchem-1915	137	2	.	.	PUNCT
eurjchem-1915	137	3	synthesis	synthesis	NOUN
eurjchem-1915	137	4	of	of	ADP
eurjchem-1915	137	5	poly	poly	ADJ
eurjchem-1915	137	6	-	-	PUNCT
eurjchem-1915	137	7	n	n	CCONJ
eurjchem-1915	137	8	-	-	PUNCT
eurjchem-1915	137	9	bis(3,3`-bi	bis(3,3`-bi	ADJ
eurjchem-1915	137	10	-	-	PUNCT
eurjchem-1915	137	11	pyrazolylcarbonyl)urea	pyrazolylcarbonyl)urea	PROPN
eurjchem-1915	137	12	derivative	derivative	NOUN
eurjchem-1915	137	13	(	(	PUNCT
eurjchem-1915	137	14	10	10	NUM
eurjchem-1915	137	15	)	)	PUNCT
eurjchem-1915	137	16	to	to	ADP
eurjchem-1915	137	17	a	a	DET
eurjchem-1915	137	18	solution	solution	NOUN
eurjchem-1915	137	19	of	of	ADP
eurjchem-1915	137	20	compound	compound	NOUN
eurjchem-1915	137	21	6	6	NUM
eurjchem-1915	137	22	(	(	PUNCT
eurjchem-1915	137	23	0.374	0.374	NUM
eurjchem-1915	137	24	g	g	NOUN
eurjchem-1915	137	25	,	,	PUNCT
eurjchem-1915	137	26	1	1	NUM
eurjchem-1915	137	27	mmol	mmol	NOUN
eurjchem-1915	137	28	)	)	PUNCT
eurjchem-1915	137	29	in	in	ADP
eurjchem-1915	137	30	dmf	dmf	PROPN
eurjchem-1915	137	31	(	(	PUNCT
eurjchem-1915	137	32	25	25	NUM
eurjchem-1915	137	33	ml	ml	NOUN
eurjchem-1915	137	34	)	)	PUNCT
eurjchem-1915	137	35	,	,	PUNCT
eurjchem-1915	137	36	urea	urea	NOUN
eurjchem-1915	137	37	(	(	PUNCT
eurjchem-1915	137	38	0.060	0.060	NUM
eurjchem-1915	137	39	g	g	NOUN
eurjchem-1915	137	40	,	,	PUNCT
eurjchem-1915	137	41	2	2	NUM
eurjchem-1915	137	42	mmol	mmol	NOUN
eurjchem-1915	137	43	)	)	PUNCT
eurjchem-1915	137	44	were	be	AUX
eurjchem-1915	137	45	added	add	VERB
eurjchem-1915	137	46	.	.	PUNCT
eurjchem-1915	138	1	the	the	DET
eurjchem-1915	138	2	reaction	reaction	NOUN
eurjchem-1915	138	3	mixture	mixture	NOUN
eurjchem-1915	138	4	was	be	AUX
eurjchem-1915	138	5	refluxed	refluxe	VERB
eurjchem-1915	138	6	for	for	ADP
eurjchem-1915	138	7	5	5	NUM
eurjchem-1915	138	8	h	h	NOUN
eurjchem-1915	138	9	then	then	ADV
eurjchem-1915	138	10	left	leave	VERB
eurjchem-1915	138	11	to	to	PART
eurjchem-1915	138	12	cool	cool	VERB
eurjchem-1915	138	13	to	to	PART
eurjchem-1915	138	14	room	room	VERB
eurjchem-1915	138	15	temperature	temperature	NOUN
eurjchem-1915	138	16	.	.	PUNCT
eurjchem-1915	139	1	the	the	DET
eurjchem-1915	139	2	precipitated	precipitate	VERB
eurjchem-1915	139	3	product	product	NOUN
eurjchem-1915	139	4	was	be	AUX
eurjchem-1915	139	5	collected	collect	VERB
eurjchem-1915	139	6	by	by	ADP
eurjchem-1915	139	7	filtration	filtration	NOUN
eurjchem-1915	139	8	and	and	CCONJ
eurjchem-1915	139	9	recrystallized	recrystallize	VERB
eurjchem-1915	139	10	from	from	ADP
eurjchem-1915	139	11	dmf	dmf	PROPN
eurjchem-1915	139	12	/	/	SYM
eurjchem-1915	139	13	acetonitrile	acetonitrile	NOUN
eurjchem-1915	139	14	(	(	PUNCT
eurjchem-1915	139	15	1:1	1:1	NUM
eurjchem-1915	139	16	)	)	PUNCT
eurjchem-1915	139	17	to	to	PART
eurjchem-1915	139	18	give	give	VERB
eurjchem-1915	139	19	the	the	DET
eurjchem-1915	139	20	polybis(3,3`-bi	polybis(3,3`-bi	NOUN
eurjchem-1915	139	21	-	-	PUNCT
eurjchem-1915	139	22	pyrazolylcarbonyl)urea	pyrazolylcarbonyl)urea	NOUN
eurjchem-1915	139	23	derivative	derivative	ADJ
eurjchem-1915	139	24	10	10	NUM
eurjchem-1915	139	25	as	as	ADP
eurjchem-1915	139	26	yellow	yellow	ADJ
eurjchem-1915	139	27	powder	powder	NOUN
eurjchem-1915	139	28	(	(	PUNCT
eurjchem-1915	139	29	0.35	0.35	NUM
eurjchem-1915	139	30	g	g	NOUN
eurjchem-1915	139	31	)	)	PUNCT
eurjchem-1915	139	32	(	(	PUNCT
eurjchem-1915	139	33	scheme	scheme	NOUN
eurjchem-1915	139	34	3	3	NUM
eurjchem-1915	139	35	)	)	PUNCT
eurjchem-1915	139	36	.	.	PUNCT
eurjchem-1915	140	1	colour	colour	NOUN
eurjchem-1915	140	2	:	:	PUNCT
eurjchem-1915	140	3	yellow	yellow	ADJ
eurjchem-1915	140	4	powder	powder	NOUN
eurjchem-1915	140	5	.	.	PUNCT
eurjchem-1915	141	1	m.p	m.p	PROPN
eurjchem-1915	141	2	.	.	PROPN
eurjchem-1915	141	3	:	:	PUNCT
eurjchem-1915	142	1	>	>	X
eurjchem-1915	142	2	300	300	NUM
eurjchem-1915	142	3	oc	oc	NOUN
eurjchem-1915	142	4	.	.	PUNCT
eurjchem-1915	143	1	ir	ir	PROPN
eurjchem-1915	143	2	(	(	PUNCT
eurjchem-1915	143	3	kbr	kbr	PROPN
eurjchem-1915	143	4	,	,	PUNCT
eurjchem-1915	143	5	ν	ν	PROPN
eurjchem-1915	143	6	,	,	PUNCT
eurjchem-1915	143	7	cm−1	cm−1	NOUN
eurjchem-1915	143	8	):	):	PUNCT
eurjchem-1915	143	9	3208	3208	NUM
eurjchem-1915	143	10	(	(	PUNCT
eurjchem-1915	143	11	nh	nh	NOUN
eurjchem-1915	143	12	)	)	PUNCT
eurjchem-1915	143	13	,	,	PUNCT
eurjchem-1915	143	14	3122	3122	NUM
eurjchem-1915	143	15	(	(	PUNCT
eurjchem-1915	143	16	nh	nh	NOUN
eurjchem-1915	143	17	)	)	PUNCT
eurjchem-1915	143	18	,	,	PUNCT
eurjchem-1915	143	19	3069	3069	NUM
eurjchem-1915	143	20	(	(	PUNCT
eurjchem-1915	143	21	ch	ch	NOUN
eurjchem-1915	143	22	)	)	PUNCT
eurjchem-1915	143	23	,	,	PUNCT
eurjchem-1915	143	24	1726	1726	NUM
eurjchem-1915	143	25	(	(	PUNCT
eurjchem-1915	143	26	c	c	NOUN
eurjchem-1915	143	27	=	=	NOUN
eurjchem-1915	143	28	o	o	NOUN
eurjchem-1915	143	29	)	)	PUNCT
eurjchem-1915	143	30	,	,	PUNCT
eurjchem-1915	143	31	1660	1660	NUM
eurjchem-1915	143	32	(	(	PUNCT
eurjchem-1915	143	33	c	c	NOUN
eurjchem-1915	143	34	=	=	NOUN
eurjchem-1915	143	35	o	o	NOUN
eurjchem-1915	143	36	)	)	PUNCT
eurjchem-1915	143	37	.	.	PUNCT
eurjchem-1915	144	1	1h	1h	NUM
eurjchem-1915	144	2	nmr	nmr	NOUN
eurjchem-1915	144	3	(	(	PUNCT
eurjchem-1915	144	4	400	400	NUM
eurjchem-1915	144	5	mhz	mhz	NOUN
eurjchem-1915	144	6	,	,	PUNCT
eurjchem-1915	144	7	dmso	dmso	NOUN
eurjchem-1915	144	8	-	-	NOUN
eurjchem-1915	144	9	d6	d6	NOUN
eurjchem-1915	144	10	,	,	PUNCT
eurjchem-1915	144	11	δ	δ	PROPN
eurjchem-1915	144	12	,	,	PUNCT
eurjchem-1915	144	13	ppm	ppm	NUM
eurjchem-1915	144	14	):	):	PUNCT
eurjchem-1915	144	15	12.47	12.47	NUM
eurjchem-1915	144	16	(	(	PUNCT
eurjchem-1915	144	17	br	br	NOUN
eurjchem-1915	144	18	.	.	PUNCT
eurjchem-1915	144	19	s	s	PART
eurjchem-1915	144	20	,	,	PUNCT
eurjchem-1915	144	21	2h	2h	NUM
eurjchem-1915	144	22	,	,	PUNCT
eurjchem-1915	144	23	nh	nh	PROPN
eurjchem-1915	144	24	)	)	PUNCT
eurjchem-1915	144	25	,	,	PUNCT
eurjchem-1915	144	26	7.99	7.99	NUM
eurjchem-1915	144	27	-	-	SYM
eurjchem-1915	144	28	7.39	7.39	NUM
eurjchem-1915	144	29	(	(	PUNCT
eurjchem-1915	144	30	m	m	PROPN
eurjchem-1915	144	31	,	,	PUNCT
eurjchem-1915	144	32	10h	10h	NUM
eurjchem-1915	144	33	,	,	PUNCT
eurjchem-1915	144	34	ar	ar	NOUN
eurjchem-1915	144	35	-	-	NOUN
eurjchem-1915	144	36	h	h	NOUN
eurjchem-1915	144	37	)	)	PUNCT
eurjchem-1915	144	38	,	,	PUNCT
eurjchem-1915	144	39	7.59	7.59	NUM
eurjchem-1915	144	40	(	(	PUNCT
eurjchem-1915	144	41	s	s	PROPN
eurjchem-1915	144	42	,	,	PUNCT
eurjchem-1915	144	43	2h	2h	NUM
eurjchem-1915	144	44	,	,	PUNCT
eurjchem-1915	144	45	pyrazole	pyrazole	NOUN
eurjchem-1915	144	46	-	-	PUNCT
eurjchem-1915	144	47	ch	ch	NOUN
eurjchem-1915	144	48	)	)	PUNCT
eurjchem-1915	144	49	.	.	PUNCT
eurjchem-1915	145	1	13c	13c	NOUN
eurjchem-1915	145	2	nmr	nmr	NOUN
eurjchem-1915	145	3	(	(	PUNCT
eurjchem-1915	145	4	100	100	NUM
eurjchem-1915	145	5	mhz	mhz	NOUN
eurjchem-1915	145	6	,	,	PUNCT
eurjchem-1915	145	7	dmso	dmso	NOUN
eurjchem-1915	145	8	-	-	NOUN
eurjchem-1915	145	9	d6	d6	NOUN
eurjchem-1915	145	10	,	,	PUNCT
eurjchem-1915	145	11	δ	δ	PROPN
eurjchem-1915	145	12	,	,	PUNCT
eurjchem-1915	145	13	ppm	ppm	NUM
eurjchem-1915	145	14	):	):	PUNCT
eurjchem-1915	145	15	163.3	163.3	NUM
eurjchem-1915	145	16	(	(	PUNCT
eurjchem-1915	145	17	1c	1c	NOUN
eurjchem-1915	145	18	,	,	PUNCT
eurjchem-1915	145	19	c	c	NOUN
eurjchem-1915	145	20	=	=	SYM
eurjchem-1915	145	21	o	o	NOUN
eurjchem-1915	145	22	)	)	PUNCT
eurjchem-1915	145	23	,	,	PUNCT
eurjchem-1915	145	24	159.6	159.6	NUM
eurjchem-1915	145	25	(	(	PUNCT
eurjchem-1915	145	26	2c	2c	NUM
eurjchem-1915	145	27	,	,	PUNCT
eurjchem-1915	145	28	c	c	PROPN
eurjchem-1915	145	29	=	=	SYM
eurjchem-1915	145	30	o	o	NOUN
eurjchem-1915	145	31	)	)	PUNCT
eurjchem-1915	145	32	,	,	PUNCT
eurjchem-1915	145	33	146.0	146.0	NUM
eurjchem-1915	145	34	(	(	PUNCT
eurjchem-1915	145	35	2c	2c	NOUN
eurjchem-1915	145	36	,	,	PUNCT
eurjchem-1915	145	37	pyrazole	pyrazole	NOUN
eurjchem-1915	145	38	-	-	PUNCT
eurjchem-1915	145	39	c	c	NOUN
eurjchem-1915	145	40	)	)	PUNCT
eurjchem-1915	145	41	,	,	PUNCT
eurjchem-1915	145	42	138.8	138.8	NUM
eurjchem-1915	145	43	(	(	PUNCT
eurjchem-1915	145	44	2c	2c	NUM
eurjchem-1915	145	45	,	,	PUNCT
eurjchem-1915	145	46	ar	ar	NOUN
eurjchem-1915	145	47	-	-	NOUN
eurjchem-1915	145	48	c	c	NOUN
eurjchem-1915	145	49	)	)	PUNCT
eurjchem-1915	145	50	,	,	PUNCT
eurjchem-1915	145	51	131.7	131.7	NUM
eurjchem-1915	145	52	(	(	PUNCT
eurjchem-1915	145	53	4c	4c	NOUN
eurjchem-1915	145	54	,	,	PUNCT
eurjchem-1915	145	55	ar	ar	NOUN
eurjchem-1915	145	56	-	-	NOUN
eurjchem-1915	145	57	c	c	NOUN
eurjchem-1915	145	58	)	)	PUNCT
eurjchem-1915	145	59	,	,	PUNCT
eurjchem-1915	145	60	129.8	129.8	NUM
eurjchem-1915	145	61	(	(	PUNCT
eurjchem-1915	145	62	2c	2c	NOUN
eurjchem-1915	145	63	,	,	PUNCT
eurjchem-1915	145	64	pyrazole	pyrazole	NOUN
eurjchem-1915	145	65	-	-	PUNCT
eurjchem-1915	145	66	c	c	NOUN
eurjchem-1915	145	67	)	)	PUNCT
eurjchem-1915	145	68	,	,	PUNCT
eurjchem-1915	145	69	127.2	127.2	NUM
eurjchem-1915	145	70	(	(	PUNCT
eurjchem-1915	145	71	2c	2c	NUM
eurjchem-1915	145	72	,	,	PUNCT
eurjchem-1915	145	73	arc	arc	NOUN
eurjchem-1915	145	74	)	)	PUNCT
eurjchem-1915	145	75	,	,	PUNCT
eurjchem-1915	145	76	118.9	118.9	NUM
eurjchem-1915	145	77	(	(	PUNCT
eurjchem-1915	145	78	4c	4c	NOUN
eurjchem-1915	145	79	,	,	PUNCT
eurjchem-1915	145	80	ar	ar	NOUN
eurjchem-1915	145	81	-	-	NOUN
eurjchem-1915	145	82	c	c	NOUN
eurjchem-1915	145	83	)	)	PUNCT
eurjchem-1915	145	84	,	,	PUNCT
eurjchem-1915	145	85	117.1	117.1	NUM
eurjchem-1915	145	86	(	(	PUNCT
eurjchem-1915	145	87	2c	2c	NOUN
eurjchem-1915	145	88	,	,	PUNCT
eurjchem-1915	145	89	pyrazole	pyrazole	NOUN
eurjchem-1915	145	90	-	-	PUNCT
eurjchem-1915	145	91	c	c	NOUN
eurjchem-1915	145	92	)	)	PUNCT
eurjchem-1915	145	93	.	.	PUNCT
eurjchem-1915	146	1	anal	anal	PROPN
eurjchem-1915	146	2	.	.	PUNCT
eurjchem-1915	146	3	calcd	calcd	NOUN
eurjchem-1915	146	4	.	.	PUNCT
eurjchem-1915	147	1	for	for	ADP
eurjchem-1915	147	2	repeating	repeat	VERB
eurjchem-1915	147	3	unit	unit	NOUN
eurjchem-1915	147	4	c21h14n6o3	c21h14n6o3	PROPN
eurjchem-1915	147	5	:	:	PUNCT
eurjchem-1915	147	6	c	c	X
eurjchem-1915	147	7	,	,	PUNCT
eurjchem-1915	147	8	63.31	63.31	NUM
eurjchem-1915	147	9	;	;	PUNCT
eurjchem-1915	148	1	h	h	NOUN
eurjchem-1915	148	2	,	,	PUNCT
eurjchem-1915	148	3	3.54	3.54	NUM
eurjchem-1915	148	4	;	;	PUNCT
eurjchem-1915	148	5	n	n	CCONJ
eurjchem-1915	148	6	,	,	PUNCT
eurjchem-1915	148	7	21.10	21.10	NUM
eurjchem-1915	148	8	.	.	PUNCT
eurjchem-1915	148	9	found	find	VERB
eurjchem-1915	148	10	:	:	PUNCT
eurjchem-1915	149	1	c	c	X
eurjchem-1915	149	2	,	,	PUNCT
eurjchem-1915	149	3	63.51	63.51	NUM
eurjchem-1915	149	4	;	;	PUNCT
eurjchem-1915	149	5	h	h	NOUN
eurjchem-1915	149	6	,	,	PUNCT
eurjchem-1915	149	7	3.72	3.72	NUM
eurjchem-1915	149	8	;	;	PUNCT
eurjchem-1915	149	9	n	n	CCONJ
eurjchem-1915	149	10	,	,	PUNCT
eurjchem-1915	149	11	21.21	21.21	NUM
eurjchem-1915	149	12	%	%	NOUN
eurjchem-1915	149	13	.	.	PUNCT
eurjchem-1915	150	1	2.7	2.7	NUM
eurjchem-1915	150	2	.	.	PUNCT
eurjchem-1915	150	3	suzuki	suzuki	NOUN
eurjchem-1915	150	4	-	-	PUNCT
eurjchem-1915	150	5	miyaura	miyaura	NOUN
eurjchem-1915	150	6	cross	cross	NOUN
eurjchem-1915	150	7	-	-	NOUN
eurjchem-1915	150	8	coupling	coupling	NOUN
eurjchem-1915	150	9	of	of	ADP
eurjchem-1915	150	10	aryl(hetaryl	aryl(hetaryl	NOUN
eurjchem-1915	150	11	)	)	PUNCT
eurjchem-1915	150	12	bromides	bromide	NOUN
eurjchem-1915	150	13	with	with	ADP
eurjchem-1915	150	14	phenylboronic	phenylboronic	ADJ
eurjchem-1915	150	15	acid	acid	NOUN
eurjchem-1915	150	16	in	in	ADP
eurjchem-1915	150	17	water	water	NOUN
eurjchem-1915	150	18	a	a	DET
eurjchem-1915	150	19	mixture	mixture	NOUN
eurjchem-1915	150	20	of	of	ADP
eurjchem-1915	150	21	the	the	DET
eurjchem-1915	150	22	appropriate	appropriate	ADJ
eurjchem-1915	150	23	aryl(hetaryl	aryl(hetaryl	PROPN
eurjchem-1915	150	24	)	)	PUNCT
eurjchem-1915	150	25	bromides	bromide	VERB
eurjchem-1915	150	26	12	12	NUM
eurjchem-1915	150	27	-	-	SYM
eurjchem-1915	150	28	17	17	NUM
eurjchem-1915	150	29	(	(	PUNCT
eurjchem-1915	150	30	1	1	NUM
eurjchem-1915	150	31	mmol	mmol	NOUN
eurjchem-1915	150	32	)	)	PUNCT
eurjchem-1915	150	33	,	,	PUNCT
eurjchem-1915	150	34	phenylboronic	phenylboronic	ADJ
eurjchem-1915	150	35	acid	acid	NOUN
eurjchem-1915	150	36	11	11	NUM
eurjchem-1915	150	37	(	(	PUNCT
eurjchem-1915	150	38	146	146	NUM
eurjchem-1915	150	39	mg	mg	NOUN
eurjchem-1915	150	40	,	,	PUNCT
eurjchem-1915	150	41	1.2	1.2	NUM
eurjchem-1915	150	42	mmol	mmol	NOUN
eurjchem-1915	150	43	)	)	PUNCT
eurjchem-1915	150	44	,	,	PUNCT
eurjchem-1915	150	45	tetrabutylammonium	tetrabutylammonium	NOUN
eurjchem-1915	150	46	bromide	bromide	NOUN
eurjchem-1915	150	47	(	(	PUNCT
eurjchem-1915	150	48	tbab	tbab	PROPN
eurjchem-1915	150	49	)	)	PUNCT
eurjchem-1915	150	50	(	(	PUNCT
eurjchem-1915	150	51	194	194	NUM
eurjchem-1915	150	52	mg	mg	PROPN
eurjchem-1915	150	53	,	,	PUNCT
eurjchem-1915	150	54	0.6	0.6	NUM
eurjchem-1915	150	55	mmol	mmol	NOUN
eurjchem-1915	150	56	)	)	PUNCT
eurjchem-1915	150	57	,	,	PUNCT
eurjchem-1915	150	58	palladium	palladium	NOUN
eurjchem-1915	150	59	complex	complex	NOUN
eurjchem-1915	150	60	7	7	NUM
eurjchem-1915	150	61	(	(	PUNCT
eurjchem-1915	150	62	7	7	NUM
eurjchem-1915	150	63	mg	mg	NOUN
eurjchem-1915	150	64	,	,	PUNCT
eurjchem-1915	150	65	1	1	NUM
eurjchem-1915	150	66	mol%	mol%	NOUN
eurjchem-1915	150	67	)	)	PUNCT
eurjchem-1915	150	68	and	and	CCONJ
eurjchem-1915	150	69	koh	koh	PROPN
eurjchem-1915	150	70	(	(	PUNCT
eurjchem-1915	150	71	112	112	NUM
eurjchem-1915	150	72	mg	mg	PROPN
eurjchem-1915	150	73	,	,	PUNCT
eurjchem-1915	150	74	2	2	NUM
eurjchem-1915	150	75	mmol	mmol	NOUN
eurjchem-1915	150	76	)	)	PUNCT
eurjchem-1915	150	77	in	in	ADP
eurjchem-1915	150	78	distilled	distil	VERB
eurjchem-1915	150	79	water	water	NOUN
eurjchem-1915	150	80	(	(	PUNCT
eurjchem-1915	150	81	3	3	NUM
eurjchem-1915	150	82	ml	ml	NOUN
eurjchem-1915	150	83	)	)	PUNCT
eurjchem-1915	150	84	was	be	AUX
eurjchem-1915	150	85	thermally	thermally	ADV
eurjchem-1915	150	86	heated	heat	VERB
eurjchem-1915	150	87	with	with	ADP
eurjchem-1915	150	88	stirring	stir	VERB
eurjchem-1915	150	89	at	at	ADP
eurjchem-1915	150	90	100	100	NUM
eurjchem-1915	150	91	°	°	NOUN
eurjchem-1915	150	92	c	c	NOUN
eurjchem-1915	150	93	under	under	ADP
eurjchem-1915	150	94	open	open	ADJ
eurjchem-1915	150	95	air	air	NOUN
eurjchem-1915	150	96	for	for	ADP
eurjchem-1915	150	97	the	the	DET
eurjchem-1915	150	98	appropriate	appropriate	ADJ
eurjchem-1915	150	99	reaction	reaction	NOUN
eurjchem-1915	150	100	time	time	NOUN
eurjchem-1915	150	101	(	(	PUNCT
eurjchem-1915	150	102	monitored	monitor	VERB
eurjchem-1915	150	103	by	by	ADP
eurjchem-1915	150	104	tlc	tlc	PROPN
eurjchem-1915	150	105	)	)	PUNCT
eurjchem-1915	150	106	,	,	PUNCT
eurjchem-1915	150	107	as	as	SCONJ
eurjchem-1915	150	108	listed	list	VERB
eurjchem-1915	150	109	in	in	ADP
eurjchem-1915	150	110	table	table	NOUN
eurjchem-1915	150	111	4	4	NUM
eurjchem-1915	150	112	.	.	PUNCT
eurjchem-1915	151	1	after	after	SCONJ
eurjchem-1915	151	2	the	the	DET
eurjchem-1915	151	3	reaction	reaction	NOUN
eurjchem-1915	151	4	was	be	AUX
eurjchem-1915	151	5	complete	complete	ADJ
eurjchem-1915	151	6	,	,	PUNCT
eurjchem-1915	151	7	the	the	DET
eurjchem-1915	151	8	product	product	NOUN
eurjchem-1915	151	9	was	be	AUX
eurjchem-1915	151	10	extracted	extract	VERB
eurjchem-1915	151	11	with	with	ADP
eurjchem-1915	151	12	ethyl	ethyl	PROPN
eurjchem-1915	151	13	acetate	acetate	NOUN
eurjchem-1915	151	14	(	(	PUNCT
eurjchem-1915	151	15	3×20	3×20	NUM
eurjchem-1915	151	16	ml	ml	NOUN
eurjchem-1915	151	17	)	)	PUNCT
eurjchem-1915	151	18	.	.	PUNCT
eurjchem-1915	152	1	the	the	DET
eurjchem-1915	152	2	combined	combine	VERB
eurjchem-1915	152	3	organic	organic	ADJ
eurjchem-1915	152	4	extracts	extract	NOUN
eurjchem-1915	152	5	were	be	AUX
eurjchem-1915	152	6	dried	dry	VERB
eurjchem-1915	152	7	over	over	ADP
eurjchem-1915	152	8	anhydrous	anhydrous	ADJ
eurjchem-1915	152	9	mgso4	mgso4	NOUN
eurjchem-1915	152	10	then	then	ADV
eurjchem-1915	152	11	filtered	filter	VERB
eurjchem-1915	152	12	and	and	CCONJ
eurjchem-1915	152	13	the	the	DET
eurjchem-1915	152	14	solvent	solvent	NOUN
eurjchem-1915	152	15	was	be	AUX
eurjchem-1915	152	16	evaporated	evaporate	VERB
eurjchem-1915	152	17	under	under	ADP
eurjchem-1915	152	18	reduced	reduced	ADJ
eurjchem-1915	152	19	pressure	pressure	NOUN
eurjchem-1915	152	20	.	.	PUNCT
eurjchem-1915	153	1	the	the	DET
eurjchem-1915	153	2	residue	residue	NOUN
eurjchem-1915	153	3	was	be	AUX
eurjchem-1915	153	4	then	then	ADV
eurjchem-1915	153	5	subjected	subject	VERB
eurjchem-1915	153	6	to	to	ADP
eurjchem-1915	153	7	separation	separation	NOUN
eurjchem-1915	153	8	via	via	ADP
eurjchem-1915	153	9	flash	flash	NOUN
eurjchem-1915	153	10	column	column	NOUN
eurjchem-1915	153	11	chromatography	chromatography	NOUN
eurjchem-1915	153	12	with	with	ADP
eurjchem-1915	153	13	hexane	hexane	NOUN
eurjchem-1915	153	14	:	:	PUNCT
eurjchem-1915	153	15	ethyl	ethyl	PROPN
eurjchem-1915	153	16	acetate	acetate	PROPN
eurjchem-1915	153	17	(	(	PUNCT
eurjchem-1915	153	18	10:1	10:1	NUM
eurjchem-1915	153	19	,	,	PUNCT
eurjchem-1915	153	20	v	v	NOUN
eurjchem-1915	153	21	:	:	PUNCT
eurjchem-1915	153	22	v	v	NOUN
eurjchem-1915	153	23	)	)	PUNCT
eurjchem-1915	153	24	as	as	ADP
eurjchem-1915	153	25	an	an	DET
eurjchem-1915	153	26	eluent	eluent	NOUN
eurjchem-1915	153	27	to	to	PART
eurjchem-1915	153	28	give	give	VERB
eurjchem-1915	153	29	the	the	DET
eurjchem-1915	153	30	corresponding	corresponding	ADJ
eurjchem-1915	153	31	pure	pure	ADJ
eurjchem-1915	153	32	cross	cross	ADJ
eurjchem-1915	153	33	-	-	ADJ
eurjchem-1915	153	34	coupled	couple	VERB
eurjchem-1915	153	35	products	product	NOUN
eurjchem-1915	153	36	18	18	NUM
eurjchem-1915	153	37	-	-	SYM
eurjchem-1915	153	38	23	23	NUM
eurjchem-1915	153	39	.	.	PUNCT
eurjchem-1915	154	1	all	all	DET
eurjchem-1915	154	2	experiments	experiment	NOUN
eurjchem-1915	154	3	were	be	AUX
eurjchem-1915	154	4	done	do	VERB
eurjchem-1915	154	5	in	in	ADP
eurjchem-1915	154	6	triplicate	triplicate	NOUN
eurjchem-1915	154	7	.	.	PUNCT
eurjchem-1915	155	1	4	4	NUM
eurjchem-1915	155	2	-	-	NUM
eurjchem-1915	155	3	acetylbiphenyl	acetylbiphenyl	NOUN
eurjchem-1915	155	4	(	(	PUNCT
eurjchem-1915	155	5	18	18	NUM
eurjchem-1915	155	6	):	):	PUNCT
eurjchem-1915	155	7	m.p	m.p	PROPN
eurjchem-1915	155	8	.	.	PROPN
eurjchem-1915	155	9	:	:	PUNCT
eurjchem-1915	156	1	117	117	NUM
eurjchem-1915	156	2	-	-	SYM
eurjchem-1915	156	3	119	119	NUM
eurjchem-1915	156	4	°	°	PROPN
eurjchem-1915	156	5	c	c	X
eurjchem-1915	156	6	(	(	PUNCT
eurjchem-1915	156	7	lit	lit	ADJ
eurjchem-1915	156	8	.	.	PUNCT
eurjchem-1915	157	1	m.p	m.p	PROPN
eurjchem-1915	157	2	.	.	PROPN
eurjchem-1915	157	3	:	:	PUNCT
eurjchem-1915	158	1	118	118	NUM
eurjchem-1915	158	2	-	-	SYM
eurjchem-1915	158	3	120	120	NUM
eurjchem-1915	158	4	°	°	NUM
eurjchem-1915	158	5	c	c	NOUN
eurjchem-1915	158	6	[	[	X
eurjchem-1915	158	7	27	27	NUM
eurjchem-1915	158	8	]	]	NUM
eurjchem-1915	158	9	)	)	PUNCT
eurjchem-1915	158	10	.	.	PUNCT
eurjchem-1915	159	1	1,1'-biphenyl-4	1,1'-biphenyl-4	NOUN
eurjchem-1915	159	2	-	-	PUNCT
eurjchem-1915	159	3	carbonitrile	carbonitrile	NOUN
eurjchem-1915	159	4	(	(	PUNCT
eurjchem-1915	159	5	19	19	NUM
eurjchem-1915	159	6	):	):	PUNCT
eurjchem-1915	159	7	m.p	m.p	PROPN
eurjchem-1915	159	8	.	.	PROPN
eurjchem-1915	159	9	:	:	PUNCT
eurjchem-1915	159	10	85	85	NUM
eurjchem-1915	159	11	-	-	SYM
eurjchem-1915	159	12	86	86	NUM
eurjchem-1915	159	13	°	°	NUM
eurjchem-1915	159	14	c	c	X
eurjchem-1915	159	15	(	(	PUNCT
eurjchem-1915	159	16	lit	lit	ADJ
eurjchem-1915	159	17	.	.	PUNCT
eurjchem-1915	160	1	m.p	m.p	PROPN
eurjchem-1915	160	2	.	.	PROPN
eurjchem-1915	160	3	:	:	PUNCT
eurjchem-1915	161	1	86	86	NUM
eurjchem-1915	161	2	-	-	SYM
eurjchem-1915	161	3	87	87	NUM
eurjchem-1915	161	4	°	°	NUM
eurjchem-1915	161	5	c	c	NOUN
eurjchem-1915	161	6	[	[	X
eurjchem-1915	161	7	28	28	NUM
eurjchem-1915	161	8	]	]	NUM
eurjchem-1915	161	9	)	)	PUNCT
eurjchem-1915	161	10	.	.	PUNCT
eurjchem-1915	162	1	3	3	X
eurjchem-1915	162	2	-	-	PUNCT
eurjchem-1915	162	3	nitrobiphenyl	nitrobiphenyl	NOUN
eurjchem-1915	162	4	(	(	PUNCT
eurjchem-1915	162	5	20	20	NUM
eurjchem-1915	162	6	):	):	PUNCT
eurjchem-1915	162	7	m.p	m.p	PROPN
eurjchem-1915	162	8	.	.	PROPN
eurjchem-1915	162	9	:	:	PUNCT
eurjchem-1915	163	1	56	56	NUM
eurjchem-1915	163	2	-	-	SYM
eurjchem-1915	163	3	58	58	NUM
eurjchem-1915	163	4	°	°	PROPN
eurjchem-1915	163	5	c	c	X
eurjchem-1915	163	6	(	(	PUNCT
eurjchem-1915	163	7	lit	lit	ADJ
eurjchem-1915	163	8	.	.	PUNCT
eurjchem-1915	164	1	m.p	m.p	PROPN
eurjchem-1915	164	2	.	.	PROPN
eurjchem-1915	164	3	:	:	PUNCT
eurjchem-1915	165	1	57	57	NUM
eurjchem-1915	165	2	-	-	SYM
eurjchem-1915	165	3	59	59	NUM
eurjchem-1915	165	4	°	°	NUM
eurjchem-1915	165	5	c	c	NOUN
eurjchem-1915	165	6	[	[	X
eurjchem-1915	165	7	29	29	NUM
eurjchem-1915	165	8	]	]	NUM
eurjchem-1915	165	9	)	)	PUNCT
eurjchem-1915	165	10	.	.	PUNCT
eurjchem-1915	166	1	4	4	NUM
eurjchem-1915	166	2	-	-	PUNCT
eurjchem-1915	166	3	phenylphenol	phenylphenol	NOUN
eurjchem-1915	166	4	(	(	PUNCT
eurjchem-1915	166	5	21	21	NUM
eurjchem-1915	166	6	):	):	PUNCT
eurjchem-1915	166	7	m.p	m.p	PROPN
eurjchem-1915	166	8	.	.	PROPN
eurjchem-1915	166	9	:	:	PUNCT
eurjchem-1915	167	1	144	144	NUM
eurjchem-1915	167	2	-	-	SYM
eurjchem-1915	167	3	145	145	NUM
eurjchem-1915	167	4	°	°	NUM
eurjchem-1915	167	5	c	c	X
eurjchem-1915	167	6	(	(	PUNCT
eurjchem-1915	167	7	lit	lit	ADJ
eurjchem-1915	167	8	.	.	PUNCT
eurjchem-1915	168	1	m.p	m.p	PROPN
eurjchem-1915	168	2	.	.	PROPN
eurjchem-1915	168	3	:	:	PUNCT
eurjchem-1915	169	1	146	146	NUM
eurjchem-1915	169	2	-	-	SYM
eurjchem-1915	169	3	147	147	NUM
eurjchem-1915	169	4	°	°	NUM
eurjchem-1915	169	5	c	c	NOUN
eurjchem-1915	169	6	[	[	X
eurjchem-1915	169	7	29	29	NUM
eurjchem-1915	169	8	]	]	SYM
eurjchem-1915	169	9	)	)	PUNCT
eurjchem-1915	169	10	.	.	PUNCT
eurjchem-1915	170	1	n	n	X
eurjchem-1915	170	2	-	-	PUNCT
eurjchem-1915	170	3	acetyl-4	acetyl-4	NOUN
eurjchem-1915	170	4	-	-	PUNCT
eurjchem-1915	170	5	aminobiphenyl	aminobiphenyl	NOUN
eurjchem-1915	170	6	(	(	PUNCT
eurjchem-1915	170	7	22	22	NUM
eurjchem-1915	170	8	):	):	PUNCT
eurjchem-1915	170	9	m.p	m.p	PROPN
eurjchem-1915	170	10	.	.	PROPN
eurjchem-1915	170	11	:	:	PUNCT
eurjchem-1915	171	1	152	152	NUM
eurjchem-1915	171	2	-	-	SYM
eurjchem-1915	171	3	154	154	NUM
eurjchem-1915	171	4	°	°	ADP
eurjchem-1915	171	5	c	c	X
eurjchem-1915	171	6	(	(	PUNCT
eurjchem-1915	171	7	lit	lit	ADJ
eurjchem-1915	171	8	.	.	PUNCT
eurjchem-1915	172	1	m.p	m.p	PROPN
eurjchem-1915	172	2	.	.	PROPN
eurjchem-1915	172	3	:	:	PUNCT
eurjchem-1915	173	1	150	150	NUM
eurjchem-1915	173	2	-	-	SYM
eurjchem-1915	173	3	153	153	NUM
eurjchem-1915	173	4	°	°	PROPN
eurjchem-1915	173	5	c	c	NOUN
eurjchem-1915	173	6	[	[	X
eurjchem-1915	173	7	29	29	NUM
eurjchem-1915	173	8	]	]	NUM
eurjchem-1915	173	9	)	)	PUNCT
eurjchem-1915	173	10	.	.	PUNCT
eurjchem-1915	174	1	4	4	NUM
eurjchem-1915	174	2	,	,	PUNCT
eurjchem-1915	174	3	6	6	NUM
eurjchem-1915	174	4	-	-	PUNCT
eurjchem-1915	174	5	dimethyl-2	dimethyl-2	NOUN
eurjchem-1915	174	6	-	-	PUNCT
eurjchem-1915	174	7	oxo-5	oxo-5	NOUN
eurjchem-1915	174	8	-	-	PUNCT
eurjchem-1915	174	9	phenyl-1	phenyl-1	ADJ
eurjchem-1915	174	10	,	,	PUNCT
eurjchem-1915	174	11	2	2	NUM
eurjchem-1915	174	12	-	-	PUNCT
eurjchem-1915	174	13	dihydropyridine-3	dihydropyridine-3	NUM
eurjchem-1915	174	14	-	-	PUNCT
eurjchem-1915	174	15	carbo	carbo	NOUN
eurjchem-1915	174	16	nitrile	nitrile	NOUN
eurjchem-1915	174	17	(	(	PUNCT
eurjchem-1915	174	18	23	23	NUM
eurjchem-1915	174	19	):	):	PUNCT
eurjchem-1915	174	20	color	color	NOUN
eurjchem-1915	174	21	:	:	PUNCT
eurjchem-1915	174	22	brown	brown	ADJ
eurjchem-1915	174	23	crystals	crystal	NOUN
eurjchem-1915	174	24	.	.	PUNCT
eurjchem-1915	175	1	yield	yield	NOUN
eurjchem-1915	175	2	:	:	PUNCT
eurjchem-1915	175	3	88	88	NUM
eurjchem-1915	175	4	%	%	NOUN
eurjchem-1915	175	5	.	.	PUNCT
eurjchem-1915	176	1	m.p	m.p	PROPN
eurjchem-1915	176	2	.	.	PROPN
eurjchem-1915	176	3	:	:	PUNCT
eurjchem-1915	177	1	230	230	NUM
eurjchem-1915	177	2	-	-	SYM
eurjchem-1915	177	3	231	231	NUM
eurjchem-1915	177	4	°	°	NOUN
eurjchem-1915	177	5	c	c	NOUN
eurjchem-1915	177	6	.	.	PUNCT
eurjchem-1915	178	1	ir	ir	PROPN
eurjchem-1915	178	2	(	(	PUNCT
eurjchem-1915	178	3	kbr	kbr	PROPN
eurjchem-1915	178	4	,	,	PUNCT
eurjchem-1915	178	5	ν	ν	PROPN
eurjchem-1915	178	6	,	,	PUNCT
eurjchem-1915	178	7	cm−1	cm−1	NOUN
eurjchem-1915	178	8	):	):	PUNCT
eurjchem-1915	178	9	3434	3434	NUM
eurjchem-1915	178	10	(	(	PUNCT
eurjchem-1915	178	11	nh	nh	NOUN
eurjchem-1915	178	12	)	)	PUNCT
eurjchem-1915	178	13	,	,	PUNCT
eurjchem-1915	178	14	2218	2218	NUM
eurjchem-1915	178	15	(	(	PUNCT
eurjchem-1915	178	16	c≡n	c≡n	PROPN
eurjchem-1915	178	17	)	)	PUNCT
eurjchem-1915	178	18	,	,	PUNCT
eurjchem-1915	178	19	1658	1658	NUM
eurjchem-1915	178	20	(	(	PUNCT
eurjchem-1915	178	21	c	c	NOUN
eurjchem-1915	178	22	=	=	NOUN
eurjchem-1915	178	23	o	o	NOUN
eurjchem-1915	178	24	)	)	PUNCT
eurjchem-1915	178	25	.	.	PUNCT
eurjchem-1915	179	1	1h	1h	NUM
eurjchem-1915	179	2	nmr	nmr	NOUN
eurjchem-1915	179	3	(	(	PUNCT
eurjchem-1915	179	4	400	400	NUM
eurjchem-1915	179	5	mhz	mhz	NOUN
eurjchem-1915	179	6	,	,	PUNCT
eurjchem-1915	179	7	dmso	dmso	NOUN
eurjchem-1915	179	8	-	-	NOUN
eurjchem-1915	179	9	d6	d6	NOUN
eurjchem-1915	179	10	,	,	PUNCT
eurjchem-1915	179	11	δ	δ	PROPN
eurjchem-1915	179	12	,	,	PUNCT
eurjchem-1915	179	13	ppm	ppm	NUM
eurjchem-1915	179	14	):	):	PUNCT
eurjchem-1915	179	15	7.77	7.77	NUM
eurjchem-1915	179	16	-	-	SYM
eurjchem-1915	179	17	7.31	7.31	NUM
eurjchem-1915	179	18	(	(	PUNCT
eurjchem-1915	179	19	m	m	PROPN
eurjchem-1915	179	20	,	,	PUNCT
eurjchem-1915	179	21	5h	5h	NUM
eurjchem-1915	179	22	,	,	PUNCT
eurjchem-1915	179	23	ar	ar	NOUN
eurjchem-1915	179	24	-	-	NOUN
eurjchem-1915	179	25	h	h	NOUN
eurjchem-1915	179	26	)	)	PUNCT
eurjchem-1915	179	27	;	;	PUNCT
eurjchem-1915	179	28	6.15	6.15	NUM
eurjchem-1915	179	29	(	(	PUNCT
eurjchem-1915	179	30	br	br	NOUN
eurjchem-1915	179	31	.	.	PUNCT
eurjchem-1915	179	32	s	s	PART
eurjchem-1915	179	33	,	,	PUNCT
eurjchem-1915	179	34	1h	1h	NUM
eurjchem-1915	179	35	,	,	PUNCT
eurjchem-1915	179	36	nh	nh	PROPN
eurjchem-1915	179	37	,	,	PUNCT
eurjchem-1915	179	38	d2o	d2o	NOUN
eurjchem-1915	179	39	-	-	ADJ
eurjchem-1915	179	40	exchangeable	exchangeable	ADJ
eurjchem-1915	179	41	)	)	PUNCT
eurjchem-1915	179	42	,	,	PUNCT
eurjchem-1915	179	43	2.49	2.49	NUM
eurjchem-1915	179	44	(	(	PUNCT
eurjchem-1915	179	45	s	s	PROPN
eurjchem-1915	179	46	,	,	PUNCT
eurjchem-1915	179	47	3h	3h	NUM
eurjchem-1915	179	48	,	,	PUNCT
eurjchem-1915	179	49	ch3	ch3	PROPN
eurjchem-1915	179	50	)	)	PUNCT
eurjchem-1915	179	51	,	,	PUNCT
eurjchem-1915	179	52	2.21	2.21	NUM
eurjchem-1915	179	53	(	(	PUNCT
eurjchem-1915	179	54	s	s	PROPN
eurjchem-1915	179	55	,	,	PUNCT
eurjchem-1915	179	56	3h	3h	NUM
eurjchem-1915	179	57	,	,	PUNCT
eurjchem-1915	179	58	ch3	ch3	PROPN
eurjchem-1915	179	59	)	)	PUNCT
eurjchem-1915	179	60	.	.	PUNCT
eurjchem-1915	180	1	13c	13c	NOUN
eurjchem-1915	180	2	nmr	nmr	NOUN
eurjchem-1915	180	3	(	(	PUNCT
eurjchem-1915	180	4	100	100	NUM
eurjchem-1915	180	5	mhz	mhz	NOUN
eurjchem-1915	180	6	,	,	PUNCT
eurjchem-1915	180	7	dmso	dmso	NOUN
eurjchem-1915	180	8	-	-	NOUN
eurjchem-1915	180	9	d6	d6	NOUN
eurjchem-1915	180	10	,	,	PUNCT
eurjchem-1915	180	11	δ	δ	PROPN
eurjchem-1915	180	12	,	,	PUNCT
eurjchem-1915	180	13	ppm	ppm	NUM
eurjchem-1915	180	14	):	):	PUNCT
eurjchem-1915	180	15	160.93	160.93	NUM
eurjchem-1915	180	16	(	(	PUNCT
eurjchem-1915	180	17	1c	1c	NOUN
eurjchem-1915	180	18	,	,	PUNCT
eurjchem-1915	180	19	c	c	NOUN
eurjchem-1915	180	20	=	=	SYM
eurjchem-1915	180	21	o	o	NOUN
eurjchem-1915	180	22	)	)	PUNCT
eurjchem-1915	180	23	,	,	PUNCT
eurjchem-1915	180	24	158.41	158.41	NUM
eurjchem-1915	180	25	(	(	PUNCT
eurjchem-1915	180	26	1c	1c	NOUN
eurjchem-1915	180	27	,	,	PUNCT
eurjchem-1915	180	28	pyridine	pyridine	NOUN
eurjchem-1915	180	29	-	-	PUNCT
eurjchem-1915	180	30	c	c	NOUN
eurjchem-1915	180	31	)	)	PUNCT
eurjchem-1915	180	32	,	,	PUNCT
eurjchem-1915	180	33	151.37	151.37	NUM
eurjchem-1915	180	34	(	(	PUNCT
eurjchem-1915	180	35	1c	1c	NOUN
eurjchem-1915	180	36	,	,	PUNCT
eurjchem-1915	180	37	ar	ar	NOUN
eurjchem-1915	180	38	-	-	NOUN
eurjchem-1915	180	39	c	c	NOUN
eurjchem-1915	180	40	)	)	PUNCT
eurjchem-1915	180	41	,	,	PUNCT
eurjchem-1915	180	42	134.01	134.01	NUM
eurjchem-1915	180	43	(	(	PUNCT
eurjchem-1915	180	44	2c	2c	NOUN
eurjchem-1915	180	45	,	,	PUNCT
eurjchem-1915	180	46	ar	ar	NOUN
eurjchem-1915	180	47	-	-	NOUN
eurjchem-1915	180	48	c	c	NOUN
eurjchem-1915	180	49	)	)	PUNCT
eurjchem-1915	180	50	,	,	PUNCT
eurjchem-1915	180	51	129.87	129.87	NUM
eurjchem-1915	180	52	(	(	PUNCT
eurjchem-1915	180	53	2c	2c	NOUN
eurjchem-1915	180	54	,	,	PUNCT
eurjchem-1915	180	55	ar	ar	NOUN
eurjchem-1915	180	56	-	-	NOUN
eurjchem-1915	180	57	c	c	NOUN
eurjchem-1915	180	58	)	)	PUNCT
eurjchem-1915	180	59	,	,	PUNCT
eurjchem-1915	180	60	127.26	127.26	NUM
eurjchem-1915	180	61	(	(	PUNCT
eurjchem-1915	180	62	1c	1c	NOUN
eurjchem-1915	180	63	,	,	PUNCT
eurjchem-1915	180	64	ar	ar	NOUN
eurjchem-1915	180	65	-	-	NOUN
eurjchem-1915	180	66	c	c	NOUN
eurjchem-1915	180	67	)	)	PUNCT
eurjchem-1915	180	68	,	,	PUNCT
eurjchem-1915	180	69	115.90	115.90	NUM
eurjchem-1915	180	70	(	(	PUNCT
eurjchem-1915	180	71	1c	1c	NOUN
eurjchem-1915	180	72	,	,	PUNCT
eurjchem-1915	180	73	pyridine	pyridine	NOUN
eurjchem-1915	180	74	-	-	PUNCT
eurjchem-1915	180	75	c	c	NOUN
eurjchem-1915	180	76	)	)	PUNCT
eurjchem-1915	180	77	,	,	PUNCT
eurjchem-1915	180	78	107.39	107.39	NUM
eurjchem-1915	180	79	(	(	PUNCT
eurjchem-1915	180	80	1c	1c	NOUN
eurjchem-1915	180	81	,	,	PUNCT
eurjchem-1915	180	82	pyridine	pyridine	NOUN
eurjchem-1915	180	83	-	-	PUNCT
eurjchem-1915	180	84	c	c	NOUN
eurjchem-1915	180	85	)	)	PUNCT
eurjchem-1915	180	86	,	,	PUNCT
eurjchem-1915	180	87	100.45	100.45	NUM
eurjchem-1915	180	88	(	(	PUNCT
eurjchem-1915	180	89	1c	1c	NOUN
eurjchem-1915	180	90	,	,	PUNCT
eurjchem-1915	180	91	pyridine	pyridine	NOUN
eurjchem-1915	180	92	-	-	PUNCT
eurjchem-1915	180	93	c	c	NOUN
eurjchem-1915	180	94	)	)	PUNCT
eurjchem-1915	180	95	,	,	PUNCT
eurjchem-1915	180	96	99.07	99.07	NUM
eurjchem-1915	180	97	(	(	PUNCT
eurjchem-1915	180	98	1c	1c	X
eurjchem-1915	180	99	,	,	PUNCT
eurjchem-1915	180	100	cn	cn	PROPN
eurjchem-1915	180	101	)	)	PUNCT
eurjchem-1915	180	102	,	,	PUNCT
eurjchem-1915	180	103	18.85	18.85	NUM
eurjchem-1915	180	104	(	(	PUNCT
eurjchem-1915	180	105	1c	1c	NOUN
eurjchem-1915	180	106	,	,	PUNCT
eurjchem-1915	180	107	ch3	ch3	PROPN
eurjchem-1915	180	108	)	)	PUNCT
eurjchem-1915	180	109	,	,	PUNCT
eurjchem-1915	180	110	13.44	13.44	NUM
eurjchem-1915	180	111	(	(	PUNCT
eurjchem-1915	180	112	1c	1c	NOUN
eurjchem-1915	180	113	,	,	PUNCT
eurjchem-1915	180	114	ch3	ch3	PROPN
eurjchem-1915	180	115	)	)	PUNCT
eurjchem-1915	180	116	.	.	PUNCT
eurjchem-1915	181	1	2019	2019	NUM
eurjchem-1915	181	2	–	–	PUNCT
eurjchem-1915	181	3	european	european	ADJ
eurjchem-1915	181	4	journal	journal	NOUN
eurjchem-1915	181	5	of	of	ADP
eurjchem-1915	181	6	chemistry	chemistry	NOUN
eurjchem-1915	181	7	–	–	PUNCT
eurjchem-1915	181	8	cc	cc	NOUN
eurjchem-1915	181	9	by	by	ADP
eurjchem-1915	181	10	nc	nc	PROPN
eurjchem-1915	181	11	–	–	PUNCT
eurjchem-1915	181	12	doi	doi	PROPN
eurjchem-1915	181	13	:	:	PUNCT
eurjchem-1915	181	14	10.5155	10.5155	NUM
eurjchem-1915	181	15	/	/	SYM
eurjchem-1915	181	16	eurjchem.10.4.367	eurjchem.10.4.367	NOUN
eurjchem-1915	181	17	-	-	SYM
eurjchem-1915	181	18	375.1915	375.1915	NUM
eurjchem-1915	181	19	370	370	NUM
eurjchem-1915	181	20	al	al	PROPN
eurjchem-1915	181	21	-	-	PUNCT
eurjchem-1915	181	22	fulaij	fulaij	PROPN
eurjchem-1915	181	23	et	et	PROPN
eurjchem-1915	181	24	al	al	PROPN
eurjchem-1915	181	25	.	.	PUNCT
eurjchem-1915	181	26	/	/	SYM
eurjchem-1915	181	27	european	european	PROPN
eurjchem-1915	181	28	journal	journal	PROPN
eurjchem-1915	181	29	of	of	ADP
eurjchem-1915	181	30	chemistry	chemistry	NOUN
eurjchem-1915	181	31	10	10	NUM
eurjchem-1915	181	32	(	(	PUNCT
eurjchem-1915	181	33	4	4	NUM
eurjchem-1915	181	34	)	)	PUNCT
eurjchem-1915	181	35	(	(	PUNCT
eurjchem-1915	181	36	2019	2019	NUM
eurjchem-1915	181	37	)	)	PUNCT
eurjchem-1915	181	38	367	367	NUM
eurjchem-1915	181	39	-	-	SYM
eurjchem-1915	181	40	375	375	NUM
eurjchem-1915	181	41	scheme	scheme	NOUN
eurjchem-1915	181	42	3	3	NUM
eurjchem-1915	181	43	.	.	PUNCT
eurjchem-1915	181	44	synthesis	synthesis	NOUN
eurjchem-1915	181	45	of	of	ADP
eurjchem-1915	181	46	poly	poly	ADJ
eurjchem-1915	181	47	-	-	PUNCT
eurjchem-1915	181	48	bis(3,3`-bi	bis(3,3`-bi	NOUN
eurjchem-1915	181	49	-	-	PUNCT
eurjchem-1915	181	50	pyrazolylcarbonyl)urea	pyrazolylcarbonyl)urea	PROPN
eurjchem-1915	181	51	derivative	derivative	ADJ
eurjchem-1915	181	52	10	10	NUM
eurjchem-1915	181	53	.	.	PUNCT
eurjchem-1915	182	1	figure	figure	NOUN
eurjchem-1915	182	2	1	1	NUM
eurjchem-1915	182	3	.	.	PUNCT
eurjchem-1915	183	1	ortep	ortep	NOUN
eurjchem-1915	183	2	plot	plot	NOUN
eurjchem-1915	183	3	of	of	ADP
eurjchem-1915	183	4	the	the	DET
eurjchem-1915	183	5	x	x	ADJ
eurjchem-1915	183	6	-	-	NOUN
eurjchem-1915	183	7	ray	ray	NOUN
eurjchem-1915	183	8	crystallographic	crystallographic	ADJ
eurjchem-1915	183	9	data	datum	NOUN
eurjchem-1915	183	10	of	of	ADP
eurjchem-1915	183	11	compound	compound	NOUN
eurjchem-1915	183	12	6	6	NUM
eurjchem-1915	183	13	.	.	PUNCT
eurjchem-1915	184	1	hrms	hrm	NOUN
eurjchem-1915	184	2	(	(	PUNCT
eurjchem-1915	184	3	ei	ei	INTJ
eurjchem-1915	184	4	,	,	PUNCT
eurjchem-1915	184	5	m	m	PROPN
eurjchem-1915	184	6	/	/	SYM
eurjchem-1915	184	7	z	z	ADJ
eurjchem-1915	184	8	)	)	PUNCT
eurjchem-1915	184	9	calcd	calcd	NOUN
eurjchem-1915	184	10	.	.	PUNCT
eurjchem-1915	185	1	for	for	ADP
eurjchem-1915	185	2	c14h12n2o	c14h12n2o	NOUN
eurjchem-1915	185	3	(	(	PUNCT
eurjchem-1915	185	4	m+	m+	NUM
eurjchem-1915	185	5	):	):	PUNCT
eurjchem-1915	185	6	224.09496	224.09496	NUM
eurjchem-1915	185	7	;	;	PUNCT
eurjchem-1915	185	8	found	find	VERB
eurjchem-1915	185	9	:	:	PUNCT
eurjchem-1915	186	1	224.09487	224.09487	X
eurjchem-1915	186	2	.	.	PROPN
eurjchem-1915	186	3	anal	anal	ADJ
eurjchem-1915	186	4	.	.	PUNCT
eurjchem-1915	186	5	calcd	calcd	NOUN
eurjchem-1915	186	6	.	.	PUNCT
eurjchem-1915	187	1	for	for	ADP
eurjchem-1915	187	2	c14h12n2o	c14h12n2o	NOUN
eurjchem-1915	187	3	:	:	PUNCT
eurjchem-1915	187	4	c	c	X
eurjchem-1915	187	5	,	,	PUNCT
eurjchem-1915	187	6	74.98	74.98	NUM
eurjchem-1915	187	7	;	;	PUNCT
eurjchem-1915	187	8	h	h	NOUN
eurjchem-1915	187	9	,	,	PUNCT
eurjchem-1915	187	10	5.39	5.39	NUM
eurjchem-1915	187	11	;	;	PUNCT
eurjchem-1915	187	12	n	n	CCONJ
eurjchem-1915	187	13	,	,	PUNCT
eurjchem-1915	187	14	12.49	12.49	NUM
eurjchem-1915	187	15	.	.	PUNCT
eurjchem-1915	188	1	found	find	VERB
eurjchem-1915	188	2	:	:	PUNCT
eurjchem-1915	189	1	c	c	X
eurjchem-1915	189	2	,	,	PUNCT
eurjchem-1915	189	3	75.01	75.01	NUM
eurjchem-1915	189	4	;	;	PUNCT
eurjchem-1915	189	5	h	h	NOUN
eurjchem-1915	189	6	,	,	PUNCT
eurjchem-1915	189	7	5.33	5.33	NUM
eurjchem-1915	189	8	;	;	PUNCT
eurjchem-1915	189	9	n	n	CCONJ
eurjchem-1915	189	10	,	,	PUNCT
eurjchem-1915	189	11	12.63	12.63	NUM
eurjchem-1915	189	12	%	%	NOUN
eurjchem-1915	189	13	.	.	PUNCT
eurjchem-1915	190	1	3	3	X
eurjchem-1915	190	2	.	.	NOUN
eurjchem-1915	190	3	results	result	NOUN
eurjchem-1915	190	4	and	and	CCONJ
eurjchem-1915	190	5	discussion	discussion	NOUN
eurjchem-1915	190	6	3.1	3.1	NUM
eurjchem-1915	190	7	.	.	PUNCT
eurjchem-1915	191	1	synthesis	synthesis	NOUN
eurjchem-1915	191	2	of	of	ADP
eurjchem-1915	191	3	the	the	DET
eurjchem-1915	191	4	bipyrazole	bipyrazole	ADJ
eurjchem-1915	191	5	-	-	PUNCT
eurjchem-1915	191	6	dicarboxylic	dicarboxylic	NOUN
eurjchem-1915	191	7	acid	acid	NOUN
eurjchem-1915	191	8	derivatives	derivative	NOUN
eurjchem-1915	191	9	(	(	PUNCT
eurjchem-1915	191	10	5	5	NUM
eurjchem-1915	191	11	and	and	CCONJ
eurjchem-1915	191	12	6	6	NUM
eurjchem-1915	191	13	)	)	PUNCT
eurjchem-1915	191	14	the	the	DET
eurjchem-1915	191	15	bis	bis	ADJ
eurjchem-1915	191	16	-	-	ADJ
eurjchem-1915	191	17	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	191	18	chlorides	chloride	NOUN
eurjchem-1915	191	19	1a	1a	NOUN
eurjchem-1915	191	20	,	,	PUNCT
eurjchem-1915	191	21	b	b	PROPN
eurjchem-1915	191	22	were	be	AUX
eurjchem-1915	191	23	prepared	prepare	VERB
eurjchem-1915	191	24	following	follow	VERB
eurjchem-1915	191	25	our	our	PRON
eurjchem-1915	191	26	previously	previously	ADV
eurjchem-1915	191	27	reported	report	VERB
eurjchem-1915	191	28	procedure	procedure	NOUN
eurjchem-1915	191	29	[	[	X
eurjchem-1915	191	30	26	26	NUM
eurjchem-1915	191	31	]	]	PUNCT
eurjchem-1915	191	32	.	.	PUNCT
eurjchem-1915	192	1	then	then	ADV
eurjchem-1915	192	2	,	,	PUNCT
eurjchem-1915	192	3	the	the	DET
eurjchem-1915	192	4	reaction	reaction	NOUN
eurjchem-1915	192	5	of	of	ADP
eurjchem-1915	192	6	bis	bis	ADJ
eurjchem-1915	192	7	-	-	ADJ
eurjchem-1915	192	8	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	192	9	chloride	chloride	PROPN
eurjchem-1915	192	10	1a	1a	PROPN
eurjchem-1915	192	11	with	with	ADP
eurjchem-1915	192	12	methyl	methyl	NOUN
eurjchem-1915	192	13	propiolate	propiolate	NOUN
eurjchem-1915	192	14	3	3	NUM
eurjchem-1915	192	15	,	,	PUNCT
eurjchem-1915	192	16	in	in	ADP
eurjchem-1915	192	17	1:2	1:2	NUM
eurjchem-1915	192	18	molar	molar	ADJ
eurjchem-1915	192	19	ratio	ratio	NOUN
eurjchem-1915	192	20	,	,	PUNCT
eurjchem-1915	192	21	was	be	AUX
eurjchem-1915	192	22	conducted	conduct	VERB
eurjchem-1915	192	23	in	in	ADP
eurjchem-1915	192	24	benzene	benzene	NOUN
eurjchem-1915	192	25	at	at	ADP
eurjchem-1915	192	26	reflux	reflux	NOUN
eurjchem-1915	192	27	temperature	temperature	NOUN
eurjchem-1915	192	28	in	in	ADP
eurjchem-1915	192	29	the	the	DET
eurjchem-1915	192	30	presence	presence	NOUN
eurjchem-1915	192	31	of	of	ADP
eurjchem-1915	192	32	triethylamine	triethylamine	NOUN
eurjchem-1915	192	33	to	to	PART
eurjchem-1915	192	34	afford	afford	VERB
eurjchem-1915	192	35	only	only	ADV
eurjchem-1915	192	36	one	one	NUM
eurjchem-1915	192	37	product	product	NOUN
eurjchem-1915	192	38	as	as	SCONJ
eurjchem-1915	192	39	checked	check	VERB
eurjchem-1915	192	40	by	by	ADP
eurjchem-1915	192	41	tlc	tlc	PROPN
eurjchem-1915	192	42	.	.	PUNCT
eurjchem-1915	193	1	the	the	DET
eurjchem-1915	193	2	obtained	obtain	VERB
eurjchem-1915	193	3	pure	pure	ADJ
eurjchem-1915	193	4	product	product	NOUN
eurjchem-1915	193	5	was	be	AUX
eurjchem-1915	193	6	correctly	correctly	ADV
eurjchem-1915	193	7	analyzed	analyze	VERB
eurjchem-1915	193	8	for	for	ADP
eurjchem-1915	193	9	c22h18n4o4	c22h18n4o4	PROPN
eurjchem-1915	193	10	based	base	VERB
eurjchem-1915	193	11	on	on	ADP
eurjchem-1915	193	12	its	its	PRON
eurjchem-1915	193	13	mass	mass	NOUN
eurjchem-1915	193	14	spectrum	spectrum	NOUN
eurjchem-1915	193	15	and	and	CCONJ
eurjchem-1915	193	16	elemental	elemental	ADJ
eurjchem-1915	193	17	analyses	analysis	NOUN
eurjchem-1915	193	18	.	.	PUNCT
eurjchem-1915	194	1	structure	structure	NOUN
eurjchem-1915	194	2	of	of	ADP
eurjchem-1915	194	3	the	the	DET
eurjchem-1915	194	4	obtained	obtain	VERB
eurjchem-1915	194	5	reaction	reaction	NOUN
eurjchem-1915	194	6	product	product	NOUN
eurjchem-1915	194	7	can	can	AUX
eurjchem-1915	194	8	be	be	AUX
eurjchem-1915	194	9	either	either	DET
eurjchem-1915	194	10	dimethyl	dimethyl	PROPN
eurjchem-1915	194	11	1,1′-diphenyl-3,3`bipyrazole-5,5`-dicarboxylate	1,1′-diphenyl-3,3`bipyrazole-5,5`-dicarboxylate	PROPN
eurjchem-1915	194	12	(	(	PUNCT
eurjchem-1915	194	13	4a	4a	NUM
eurjchem-1915	194	14	)	)	PUNCT
eurjchem-1915	194	15	or	or	CCONJ
eurjchem-1915	194	16	its	its	PRON
eurjchem-1915	194	17	regioisomer	regioisomer	PROPN
eurjchem-1915	194	18	dimethyl	dimethyl	PROPN
eurjchem-1915	194	19	1,1′-diphenyl-3,3`-bipyrazole-4,4`-dicarboxylate	1,1′-diphenyl-3,3`-bipyrazole-4,4`-dicarboxylate	PROPN
eurjchem-1915	194	20	(	(	PUNCT
eurjchem-1915	194	21	5a	5a	NUM
eurjchem-1915	194	22	)	)	PUNCT
eurjchem-1915	194	23	(	(	PUNCT
eurjchem-1915	194	24	scheme	scheme	NOUN
eurjchem-1915	194	25	1	1	NUM
eurjchem-1915	194	26	)	)	PUNCT
eurjchem-1915	194	27	.	.	PUNCT
eurjchem-1915	195	1	spectroscopic	spectroscopic	ADJ
eurjchem-1915	195	2	analyses	analysis	NOUN
eurjchem-1915	195	3	were	be	AUX
eurjchem-1915	195	4	fully	fully	ADV
eurjchem-1915	195	5	compatible	compatible	ADJ
eurjchem-1915	195	6	with	with	ADP
eurjchem-1915	195	7	structure	structure	NOUN
eurjchem-1915	195	8	5a	5a	NUM
eurjchem-1915	195	9	.	.	PUNCT
eurjchem-1915	196	1	for	for	ADP
eurjchem-1915	196	2	example	example	NOUN
eurjchem-1915	196	3	,	,	PUNCT
eurjchem-1915	196	4	the	the	DET
eurjchem-1915	196	5	isolated	isolated	ADJ
eurjchem-1915	196	6	product	product	NOUN
eurjchem-1915	196	7	revealed	reveal	VERB
eurjchem-1915	196	8	a	a	DET
eurjchem-1915	196	9	singlet	singlet	ADJ
eurjchem-1915	196	10	signal	signal	NOUN
eurjchem-1915	196	11	at	at	ADP
eurjchem-1915	196	12	δh	δh	ADP
eurjchem-1915	196	13	7.54	7.54	NUM
eurjchem-1915	196	14	ppm	ppm	NOUN
eurjchem-1915	196	15	in	in	ADP
eurjchem-1915	196	16	its	its	PRON
eurjchem-1915	196	17	1h	1h	NUM
eurjchem-1915	196	18	nmr	nmr	NOUN
eurjchem-1915	196	19	spectrum	spectrum	NOUN
eurjchem-1915	196	20	due	due	ADP
eurjchem-1915	196	21	to	to	ADP
eurjchem-1915	196	22	the	the	DET
eurjchem-1915	196	23	pyrazole-5	pyrazole-5	NUM
eurjchem-1915	196	24	-	-	PUNCT
eurjchem-1915	196	25	ch	ch	NOUN
eurjchem-1915	196	26	proton	proton	NOUN
eurjchem-1915	196	27	(	(	PUNCT
eurjchem-1915	196	28	structure	structure	NOUN
eurjchem-1915	196	29	5a	5a	NUM
eurjchem-1915	196	30	)	)	PUNCT
eurjchem-1915	196	31	and	and	CCONJ
eurjchem-1915	196	32	not	not	PART
eurjchem-1915	196	33	the	the	DET
eurjchem-1915	196	34	pyrazole-4ch	pyrazole-4ch	NOUN
eurjchem-1915	196	35	proton	proton	NOUN
eurjchem-1915	196	36	(	(	PUNCT
eurjchem-1915	196	37	structure	structure	NOUN
eurjchem-1915	196	38	4a	4a	NOUN
eurjchem-1915	196	39	)	)	PUNCT
eurjchem-1915	196	40	(	(	PUNCT
eurjchem-1915	196	41	where	where	SCONJ
eurjchem-1915	196	42	pyrazole-4	pyrazole-4	NOUN
eurjchem-1915	196	43	-	-	PUNCT
eurjchem-1915	196	44	ch	ch	NOUN
eurjchem-1915	196	45	proton	proton	NOUN
eurjchem-1915	196	46	appears	appear	VERB
eurjchem-1915	196	47	at	at	ADP
eurjchem-1915	196	48	a	a	DET
eurjchem-1915	196	49	lower	low	ADJ
eurjchem-1915	196	50	chemical	chemical	NOUN
eurjchem-1915	196	51	shift	shift	NOUN
eurjchem-1915	196	52	)	)	PUNCT
eurjchem-1915	197	1	[	[	X
eurjchem-1915	197	2	24	24	NUM
eurjchem-1915	197	3	]	]	PUNCT
eurjchem-1915	197	4	.	.	PUNCT
eurjchem-1915	198	1	moreover	moreover	ADV
eurjchem-1915	198	2	,	,	PUNCT
eurjchem-1915	198	3	13c	13c	NOUN
eurjchem-1915	198	4	nmr	nmr	NOUN
eurjchem-1915	198	5	spectrum	spectrum	NOUN
eurjchem-1915	198	6	exhibited	exhibit	VERB
eurjchem-1915	198	7	a	a	DET
eurjchem-1915	198	8	peak	peak	NOUN
eurjchem-1915	198	9	at	at	ADP
eurjchem-1915	198	10	δc	δc	ADP
eurjchem-1915	198	11	168.1	168.1	NUM
eurjchem-1915	198	12	(	(	PUNCT
eurjchem-1915	198	13	c	c	NOUN
eurjchem-1915	198	14	=	=	NOUN
eurjchem-1915	198	15	o	o	NOUN
eurjchem-1915	198	16	)	)	PUNCT
eurjchem-1915	198	17	,	,	PUNCT
eurjchem-1915	198	18	144.9	144.9	NUM
eurjchem-1915	198	19	,	,	PUNCT
eurjchem-1915	198	20	128.8	128.8	NUM
eurjchem-1915	198	21	,	,	PUNCT
eurjchem-1915	198	22	116.6	116.6	NUM
eurjchem-1915	198	23	(	(	PUNCT
eurjchem-1915	198	24	pyrazole	pyrazole	NOUN
eurjchem-1915	198	25	-	-	PUNCT
eurjchem-1915	198	26	carbons	carbon	NOUN
eurjchem-1915	198	27	)	)	PUNCT
eurjchem-1915	198	28	,	,	PUNCT
eurjchem-1915	198	29	138.8	138.8	NUM
eurjchem-1915	198	30	,	,	PUNCT
eurjchem-1915	198	31	130.3	130.3	NUM
eurjchem-1915	198	32	,	,	PUNCT
eurjchem-1915	198	33	124.9	124.9	NUM
eurjchem-1915	198	34	,	,	PUNCT
eurjchem-1915	198	35	121.2	121.2	NUM
eurjchem-1915	198	36	(	(	PUNCT
eurjchem-1915	198	37	aromatic	aromatic	NOUN
eurjchem-1915	198	38	-	-	PUNCT
eurjchem-1915	198	39	carbons	carbon	NOUN
eurjchem-1915	198	40	)	)	PUNCT
eurjchem-1915	198	41	,	,	PUNCT
eurjchem-1915	198	42	50.4	50.4	NUM
eurjchem-1915	198	43	ppm	ppm	NOUN
eurjchem-1915	198	44	(	(	PUNCT
eurjchem-1915	198	45	ch3	ch3	PROPN
eurjchem-1915	198	46	)	)	PUNCT
eurjchem-1915	198	47	.	.	PUNCT
eurjchem-1915	199	1	in	in	ADP
eurjchem-1915	199	2	a	a	DET
eurjchem-1915	199	3	similar	similar	ADJ
eurjchem-1915	199	4	manner	manner	NOUN
eurjchem-1915	199	5	,	,	PUNCT
eurjchem-1915	199	6	reaction	reaction	NOUN
eurjchem-1915	199	7	of	of	ADP
eurjchem-1915	199	8	bis	bis	ADJ
eurjchem-1915	199	9	-	-	ADJ
eurjchem-1915	199	10	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	199	11	chloride	chloride	NOUN
eurjchem-1915	199	12	(	(	PUNCT
eurjchem-1915	199	13	1b	1b	NUM
eurjchem-1915	199	14	)	)	PUNCT
eurjchem-1915	199	15	with	with	ADP
eurjchem-1915	199	16	methyl	methyl	NOUN
eurjchem-1915	199	17	propiolate	propiolate	NOUN
eurjchem-1915	199	18	3	3	NUM
eurjchem-1915	199	19	under	under	ADP
eurjchem-1915	199	20	similar	similar	ADJ
eurjchem-1915	199	21	reaction	reaction	NOUN
eurjchem-1915	199	22	condition	condition	NOUN
eurjchem-1915	199	23	yielded	yield	VERB
eurjchem-1915	199	24	dimethyl	dimethyl	PROPN
eurjchem-1915	199	25	1,1′-di(4	1,1′-di(4	NUM
eurjchem-1915	199	26	-	-	PUNCT
eurjchem-1915	199	27	chlorophenyl)-3,3`-bipyrazole-5,5`-dicarboxylate	chlorophenyl)-3,3`-bipyrazole-5,5`-dicarboxylate	NOUN
eurjchem-1915	199	28	(	(	PUNCT
eurjchem-1915	199	29	5b	5b	NUM
eurjchem-1915	199	30	)	)	PUNCT
eurjchem-1915	199	31	(	(	PUNCT
eurjchem-1915	199	32	scheme	scheme	NOUN
eurjchem-1915	199	33	1	1	NUM
eurjchem-1915	199	34	)	)	PUNCT
eurjchem-1915	199	35	.	.	PUNCT
eurjchem-1915	200	1	structure	structure	NOUN
eurjchem-1915	200	2	of	of	ADP
eurjchem-1915	200	3	compound	compound	NOUN
eurjchem-1915	200	4	5b	5b	NUM
eurjchem-1915	200	5	was	be	AUX
eurjchem-1915	200	6	confirmed	confirm	VERB
eurjchem-1915	200	7	from	from	ADP
eurjchem-1915	200	8	its	its	PRON
eurjchem-1915	200	9	elemental	elemental	ADJ
eurjchem-1915	200	10	and	and	CCONJ
eurjchem-1915	200	11	spectral	spectral	ADJ
eurjchem-1915	200	12	analyses	analysis	NOUN
eurjchem-1915	200	13	.	.	PUNCT
eurjchem-1915	201	1	heating	heating	NOUN
eurjchem-1915	201	2	of	of	ADP
eurjchem-1915	201	3	dimethyl	dimethyl	NOUN
eurjchem-1915	201	4	1,1′-diphenyl-3,3`-bipyrazole-4,4`dicarboxylate	1,1′-diphenyl-3,3`-bipyrazole-4,4`dicarboxylate	PROPN
eurjchem-1915	201	5	(	(	PUNCT
eurjchem-1915	201	6	5a	5a	NUM
eurjchem-1915	201	7	)	)	PUNCT
eurjchem-1915	201	8	with	with	ADP
eurjchem-1915	201	9	a	a	DET
eurjchem-1915	201	10	mixture	mixture	NOUN
eurjchem-1915	201	11	of	of	ADP
eurjchem-1915	201	12	hydrochloric	hydrochloric	ADJ
eurjchem-1915	201	13	acid	acid	NOUN
eurjchem-1915	201	14	:	:	PUNCT
eurjchem-1915	201	15	acetic	acetic	ADJ
eurjchem-1915	201	16	acid	acid	NOUN
eurjchem-1915	201	17	(	(	PUNCT
eurjchem-1915	201	18	1:3	1:3	NUM
eurjchem-1915	201	19	,	,	PUNCT
eurjchem-1915	201	20	v	v	NOUN
eurjchem-1915	201	21	:	:	SYM
eurjchem-1915	201	22	v	v	NOUN
eurjchem-1915	201	23	)	)	PUNCT
eurjchem-1915	201	24	led	lead	VERB
eurjchem-1915	201	25	to	to	ADP
eurjchem-1915	201	26	the	the	DET
eurjchem-1915	201	27	formation	formation	NOUN
eurjchem-1915	201	28	of	of	ADP
eurjchem-1915	201	29	a	a	DET
eurjchem-1915	201	30	product	product	NOUN
eurjchem-1915	201	31	that	that	PRON
eurjchem-1915	201	32	was	be	AUX
eurjchem-1915	201	33	determined	determine	VERB
eurjchem-1915	201	34	as	as	ADP
eurjchem-1915	201	35	3,3`-bipyrazole-5,5`-dicarboxylic	3,3`-bipyrazole-5,5`-dicarboxylic	NUM
eurjchem-1915	201	36	acid	acid	NOUN
eurjchem-1915	201	37	(	(	PUNCT
eurjchem-1915	201	38	6	6	NUM
eurjchem-1915	201	39	)	)	PUNCT
eurjchem-1915	201	40	.	.	PUNCT
eurjchem-1915	202	1	the	the	DET
eurjchem-1915	202	2	structure	structure	NOUN
eurjchem-1915	202	3	of	of	ADP
eurjchem-1915	202	4	the	the	DET
eurjchem-1915	202	5	product	product	NOUN
eurjchem-1915	202	6	6	6	NUM
eurjchem-1915	202	7	was	be	AUX
eurjchem-1915	202	8	confirmed	confirm	VERB
eurjchem-1915	202	9	from	from	ADP
eurjchem-1915	202	10	all	all	DET
eurjchem-1915	202	11	possible	possible	ADJ
eurjchem-1915	202	12	spectral	spectral	ADJ
eurjchem-1915	202	13	analyses	analysis	NOUN
eurjchem-1915	202	14	(	(	PUNCT
eurjchem-1915	202	15	ir	ir	PROPN
eurjchem-1915	202	16	,	,	PUNCT
eurjchem-1915	202	17	ms	ms	PROPN
eurjchem-1915	202	18	,	,	PUNCT
eurjchem-1915	202	19	1hand	1hand	NUM
eurjchem-1915	202	20	13c	13c	NOUN
eurjchem-1915	202	21	-	-	NOUN
eurjchem-1915	202	22	nmr	nmr	NOUN
eurjchem-1915	202	23	)	)	PUNCT
eurjchem-1915	202	24	as	as	ADV
eurjchem-1915	202	25	well	well	ADV
eurjchem-1915	202	26	as	as	ADP
eurjchem-1915	202	27	its	its	PRON
eurjchem-1915	202	28	single	single	ADJ
eurjchem-1915	202	29	crystal	crystal	NOUN
eurjchem-1915	202	30	x	x	PROPN
eurjchem-1915	202	31	-	-	NOUN
eurjchem-1915	202	32	ray	ray	NOUN
eurjchem-1915	202	33	analysis	analysis	NOUN
eurjchem-1915	202	34	as	as	SCONJ
eurjchem-1915	202	35	depicted	depict	VERB
eurjchem-1915	202	36	in	in	ADP
eurjchem-1915	202	37	figure	figure	NOUN
eurjchem-1915	202	38	1	1	NUM
eurjchem-1915	202	39	and	and	CCONJ
eurjchem-1915	202	40	tables	table	NOUN
eurjchem-1915	202	41	1	1	NUM
eurjchem-1915	202	42	-	-	SYM
eurjchem-1915	202	43	3	3	NUM
eurjchem-1915	202	44	(	(	PUNCT
eurjchem-1915	202	45	ccdc	ccdc	PROPN
eurjchem-1915	202	46	1548525	1548525	NUM
eurjchem-1915	202	47	)	)	PUNCT
eurjchem-1915	202	48	.	.	PUNCT
eurjchem-1915	203	1	3.2	3.2	NUM
eurjchem-1915	203	2	.	.	PUNCT
eurjchem-1915	203	3	synthesis	synthesis	NOUN
eurjchem-1915	203	4	of	of	ADP
eurjchem-1915	203	5	the	the	DET
eurjchem-1915	203	6	palladium(ii	palladium(ii	NOUN
eurjchem-1915	203	7	)	)	PUNCT
eurjchem-1915	203	8	complexes	complex	NOUN
eurjchem-1915	203	9	(	(	PUNCT
eurjchem-1915	203	10	7	7	NUM
eurjchem-1915	203	11	and	and	CCONJ
eurjchem-1915	203	12	8)	8)	NUM
eurjchem-1915	203	13	the	the	DET
eurjchem-1915	203	14	complexation	complexation	NOUN
eurjchem-1915	203	15	behaviour	behaviour	NOUN
eurjchem-1915	203	16	of	of	ADP
eurjchem-1915	203	17	the	the	DET
eurjchem-1915	203	18	bis	bis	ADJ
eurjchem-1915	203	19	-	-	ADJ
eurjchem-1915	203	20	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	203	21	chloride	chloride	PROPN
eurjchem-1915	203	22	1a	1a	NOUN
eurjchem-1915	203	23	as	as	ADP
eurjchem-1915	203	24	a	a	DET
eurjchem-1915	203	25	ligand	ligand	NOUN
eurjchem-1915	203	26	(	(	PUNCT
eurjchem-1915	203	27	l	l	NOUN
eurjchem-1915	203	28	)	)	PUNCT
eurjchem-1915	203	29	towards	towards	ADP
eurjchem-1915	203	30	pdcl2	pdcl2	NOUN
eurjchem-1915	203	31	was	be	AUX
eurjchem-1915	203	32	investigated	investigate	VERB
eurjchem-1915	203	33	.	.	PUNCT
eurjchem-1915	204	1	thus	thus	ADV
eurjchem-1915	204	2	,	,	PUNCT
eurjchem-1915	204	3	the	the	DET
eurjchem-1915	204	4	addition	addition	NOUN
eurjchem-1915	204	5	of	of	ADP
eurjchem-1915	204	6	a	a	DET
eurjchem-1915	204	7	hot	hot	ADJ
eurjchem-1915	204	8	solution	solution	NOUN
eurjchem-1915	204	9	of	of	ADP
eurjchem-1915	204	10	compound	compound	NOUN
eurjchem-1915	204	11	1a	1a	PROPN
eurjchem-1915	204	12	in	in	ADP
eurjchem-1915	204	13	dmf	dmf	PROPN
eurjchem-1915	204	14	to	to	ADP
eurjchem-1915	204	15	the	the	DET
eurjchem-1915	204	16	pdcl2	pdcl2	NOUN
eurjchem-1915	204	17	solution	solution	NOUN
eurjchem-1915	204	18	in	in	ADP
eurjchem-1915	204	19	methanol	methanol	NOUN
eurjchem-1915	204	20	at	at	ADP
eurjchem-1915	204	21	adjusted	adjust	VERB
eurjchem-1915	204	22	ph	ph	NOUN
eurjchem-1915	204	23	=	=	SYM
eurjchem-1915	204	24	5.76	5.76	NUM
eurjchem-1915	204	25	led	lead	VERB
eurjchem-1915	204	26	to	to	ADP
eurjchem-1915	204	27	the	the	DET
eurjchem-1915	204	28	formation	formation	NOUN
eurjchem-1915	204	29	of	of	ADP
eurjchem-1915	204	30	complex	complex	ADJ
eurjchem-1915	204	31	7	7	NUM
eurjchem-1915	204	32	of	of	ADP
eurjchem-1915	204	33	type	type	NOUN
eurjchem-1915	204	34	lpdcl2	lpdcl2	NOUN
eurjchem-1915	204	35	(	(	PUNCT
eurjchem-1915	204	36	scheme	scheme	NOUN
eurjchem-1915	204	37	2	2	NUM
eurjchem-1915	204	38	)	)	PUNCT
eurjchem-1915	204	39	.	.	PUNCT
eurjchem-1915	205	1	structure	structure	NOUN
eurjchem-1915	205	2	of	of	ADP
eurjchem-1915	205	3	the	the	DET
eurjchem-1915	205	4	complex	complex	ADJ
eurjchem-1915	205	5	7	7	NUM
eurjchem-1915	205	6	was	be	AUX
eurjchem-1915	205	7	established	establish	VERB
eurjchem-1915	205	8	based	base	VERB
eurjchem-1915	205	9	on	on	ADP
eurjchem-1915	205	10	its	its	PRON
eurjchem-1915	205	11	elemental	elemental	ADJ
eurjchem-1915	205	12	analyses	analysis	NOUN
eurjchem-1915	205	13	and	and	CCONJ
eurjchem-1915	205	14	spectral	spectral	ADJ
eurjchem-1915	205	15	data	datum	NOUN
eurjchem-1915	205	16	.	.	PUNCT
eurjchem-1915	206	1	besides	besides	SCONJ
eurjchem-1915	206	2	,	,	PUNCT
eurjchem-1915	206	3	the	the	DET
eurjchem-1915	206	4	experi	experi	NOUN
eurjchem-1915	206	5	-	-	PUNCT
eurjchem-1915	206	6	mental	mental	ADJ
eurjchem-1915	206	7	uv	uv	NOUN
eurjchem-1915	206	8	-	-	PUNCT
eurjchem-1915	206	9	visible	visible	ADJ
eurjchem-1915	206	10	absorption	absorption	NOUN
eurjchem-1915	206	11	spectrum	spectrum	NOUN
eurjchem-1915	206	12	of	of	ADP
eurjchem-1915	206	13	the	the	DET
eurjchem-1915	206	14	ligand	ligand	NOUN
eurjchem-1915	206	15	1a	1a	PROPN
eurjchem-1915	206	16	exhibited	exhibit	VERB
eurjchem-1915	206	17	two	two	NUM
eurjchem-1915	206	18	bands	band	NOUN
eurjchem-1915	206	19	centred	centre	VERB
eurjchem-1915	206	20	at	at	ADP
eurjchem-1915	206	21	267.72	267.72	NUM
eurjchem-1915	206	22	and	and	CCONJ
eurjchem-1915	206	23	283.00	283.00	NUM
eurjchem-1915	206	24	nm	nm	NOUN
eurjchem-1915	206	25	,	,	PUNCT
eurjchem-1915	206	26	while	while	SCONJ
eurjchem-1915	206	27	that	that	PRON
eurjchem-1915	206	28	of	of	ADP
eurjchem-1915	206	29	the	the	DET
eurjchem-1915	206	30	pd	pd	NOUN
eurjchem-1915	206	31	-	-	PUNCT
eurjchem-1915	206	32	complex	complex	ADJ
eurjchem-1915	206	33	7	7	NUM
eurjchem-1915	206	34	exhibited	exhibit	VERB
eurjchem-1915	206	35	three	three	NUM
eurjchem-1915	206	36	peaks	peak	NOUN
eurjchem-1915	206	37	in	in	ADP
eurjchem-1915	206	38	the	the	DET
eurjchem-1915	206	39	ultraviolet	ultraviolet	NOUN
eurjchem-1915	206	40	region	region	NOUN
eurjchem-1915	206	41	at	at	ADP
eurjchem-1915	206	42	239.55	239.55	NUM
eurjchem-1915	206	43	,	,	PUNCT
eurjchem-1915	206	44	292.00	292.00	NUM
eurjchem-1915	206	45	and	and	CCONJ
eurjchem-1915	206	46	326.17	326.17	NUM
eurjchem-1915	206	47	nm	nm	NOUN
eurjchem-1915	206	48	.	.	PROPN
eurjchem-1915	206	49	2019	2019	NUM
eurjchem-1915	206	50	–	–	PUNCT
eurjchem-1915	206	51	european	european	ADJ
eurjchem-1915	206	52	journal	journal	NOUN
eurjchem-1915	206	53	of	of	ADP
eurjchem-1915	206	54	chemistry	chemistry	NOUN
eurjchem-1915	206	55	–	–	PUNCT
eurjchem-1915	206	56	cc	cc	NOUN
eurjchem-1915	206	57	by	by	ADP
eurjchem-1915	206	58	nc	nc	PROPN
eurjchem-1915	206	59	–	–	PUNCT
eurjchem-1915	206	60	doi	doi	PROPN
eurjchem-1915	206	61	:	:	PUNCT
eurjchem-1915	206	62	10.5155	10.5155	NUM
eurjchem-1915	206	63	/	/	SYM
eurjchem-1915	206	64	eurjchem.10.4.367	eurjchem.10.4.367	NUM
eurjchem-1915	206	65	-	-	SYM
eurjchem-1915	206	66	375.1915	375.1915	NUM
eurjchem-1915	206	67	al	al	PROPN
eurjchem-1915	206	68	-	-	PUNCT
eurjchem-1915	206	69	fulaij	fulaij	PROPN
eurjchem-1915	206	70	et	et	PROPN
eurjchem-1915	206	71	al	al	PROPN
eurjchem-1915	206	72	.	.	PUNCT
eurjchem-1915	206	73	/	/	SYM
eurjchem-1915	206	74	european	european	PROPN
eurjchem-1915	206	75	journal	journal	PROPN
eurjchem-1915	206	76	of	of	ADP
eurjchem-1915	206	77	chemistry	chemistry	NOUN
eurjchem-1915	206	78	10	10	NUM
eurjchem-1915	206	79	(	(	PUNCT
eurjchem-1915	206	80	4	4	NUM
eurjchem-1915	206	81	)	)	PUNCT
eurjchem-1915	206	82	(	(	PUNCT
eurjchem-1915	206	83	2019	2019	NUM
eurjchem-1915	206	84	)	)	PUNCT
eurjchem-1915	206	85	367	367	NUM
eurjchem-1915	206	86	-	-	SYM
eurjchem-1915	206	87	375	375	NUM
eurjchem-1915	206	88	371	371	NUM
eurjchem-1915	206	89	table	table	NOUN
eurjchem-1915	206	90	1	1	NUM
eurjchem-1915	206	91	.	.	PUNCT
eurjchem-1915	206	92	crystal	crystal	NOUN
eurjchem-1915	206	93	data	datum	NOUN
eurjchem-1915	206	94	and	and	CCONJ
eurjchem-1915	206	95	details	detail	NOUN
eurjchem-1915	206	96	of	of	ADP
eurjchem-1915	206	97	the	the	DET
eurjchem-1915	206	98	structure	structure	NOUN
eurjchem-1915	206	99	refinement	refinement	NOUN
eurjchem-1915	206	100	for	for	ADP
eurjchem-1915	206	101	compound	compound	NOUN
eurjchem-1915	206	102	6	6	NUM
eurjchem-1915	206	103	.	.	PUNCT
eurjchem-1915	206	104	empirical	empirical	ADJ
eurjchem-1915	206	105	formula	formula	NOUN
eurjchem-1915	206	106	c10h7n2o2	c10h7n2o2	NOUN
eurjchem-1915	206	107	formula	formula	NOUN
eurjchem-1915	206	108	weight	weight	NOUN
eurjchem-1915	206	109	187.18	187.18	NUM
eurjchem-1915	206	110	temperature	temperature	NOUN
eurjchem-1915	206	111	(	(	PUNCT
eurjchem-1915	206	112	k	k	NOUN
eurjchem-1915	206	113	)	)	PUNCT
eurjchem-1915	206	114	296.(2	296.(2	NUM
eurjchem-1915	206	115	)	)	PUNCT
eurjchem-1915	206	116	crystal	crystal	NOUN
eurjchem-1915	206	117	system	system	NOUN
eurjchem-1915	206	118	triclinic	triclinic	ADJ
eurjchem-1915	206	119	space	space	NOUN
eurjchem-1915	206	120	group	group	NOUN
eurjchem-1915	206	121	p-1	p-1	NOUN
eurjchem-1915	206	122	a	a	DET
eurjchem-1915	206	123	(	(	PUNCT
eurjchem-1915	206	124	å	å	PROPN
eurjchem-1915	206	125	)	)	PUNCT
eurjchem-1915	206	126	3.9956(10	3.9956(10	NUM
eurjchem-1915	206	127	)	)	PUNCT
eurjchem-1915	206	128	b	b	NOUN
eurjchem-1915	206	129	(	(	PUNCT
eurjchem-1915	206	130	å	å	NOUN
eurjchem-1915	206	131	)	)	PUNCT
eurjchem-1915	206	132	9.8917(18	9.8917(18	NUM
eurjchem-1915	206	133	)	)	PUNCT
eurjchem-1915	206	134	c	c	NOUN
eurjchem-1915	206	135	(	(	PUNCT
eurjchem-1915	206	136	å	å	NOUN
eurjchem-1915	206	137	)	)	PUNCT
eurjchem-1915	206	138	10.810(3	10.810(3	NOUN
eurjchem-1915	206	139	)	)	PUNCT
eurjchem-1915	206	140	α	α	PROPN
eurjchem-1915	206	141	(	(	PUNCT
eurjchem-1915	206	142	°	°	PROPN
eurjchem-1915	206	143	)	)	PUNCT
eurjchem-1915	206	144	94.167(15	94.167(15	NUM
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eurjchem-1915	206	146	β	β	X
eurjchem-1915	206	147	(	(	PUNCT
eurjchem-1915	206	148	°	°	PROPN
eurjchem-1915	206	149	)	)	PUNCT
eurjchem-1915	206	150	94.979(19	94.979(19	NUM
eurjchem-1915	206	151	)	)	PUNCT
eurjchem-1915	206	152	γ	γ	PROPN
eurjchem-1915	206	153	(	(	PUNCT
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eurjchem-1915	206	157	)	)	PUNCT
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eurjchem-1915	206	160	å3	å3	PROPN
eurjchem-1915	206	161	)	)	PUNCT
eurjchem-1915	206	162	418.83(16	418.83(16	NUM
eurjchem-1915	206	163	)	)	PUNCT
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eurjchem-1915	206	165	2	2	NUM
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eurjchem-1915	206	167	(	(	PUNCT
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eurjchem-1915	206	173	μ	μ	NOUN
eurjchem-1915	206	174	(	(	PUNCT
eurjchem-1915	206	175	mm-1	mm-1	NOUN
eurjchem-1915	206	176	)	)	PUNCT
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eurjchem-1915	206	179	)	)	PUNCT
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eurjchem-1915	206	183	(	(	PUNCT
eurjchem-1915	206	184	mm3	mm3	PROPN
eurjchem-1915	206	185	)	)	PUNCT
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eurjchem-1915	206	189	×	×	NOUN
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eurjchem-1915	206	197	=	=	X
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eurjchem-1915	206	199	å	å	NOUN
eurjchem-1915	206	200	)	)	PUNCT
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eurjchem-1915	206	203	for	for	ADP
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eurjchem-1915	206	205	collection	collection	NOUN
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eurjchem-1915	206	208	)	)	PUNCT
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eurjchem-1915	206	212	index	index	NOUN
eurjchem-1915	206	213	ranges	range	VERB
eurjchem-1915	206	214	-4	-4	PUNCT
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eurjchem-1915	206	216	h	h	NOUN
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eurjchem-1915	206	219	,	,	PUNCT
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eurjchem-1915	206	223	≤	≤	NUM
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eurjchem-1915	206	225	,	,	PUNCT
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eurjchem-1915	206	229	≤	≤	NUM
eurjchem-1915	206	230	12	12	NUM
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eurjchem-1915	206	236	1420	1420	NUM
eurjchem-1915	206	237	[	[	X
eurjchem-1915	206	238	rint	rint	NOUN
eurjchem-1915	206	239	=	=	SYM
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eurjchem-1915	206	249	-	-	PUNCT
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eurjchem-1915	206	251	-	-	PUNCT
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eurjchem-1915	206	253	on	on	ADP
eurjchem-1915	206	254	f2	f2	PROPN
eurjchem-1915	206	255	1.422	1.422	NUM
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eurjchem-1915	206	257	r	r	NOUN
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eurjchem-1915	206	259	[	[	X
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eurjchem-1915	206	263	)	)	PUNCT
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eurjchem-1915	206	266	=	=	SYM
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eurjchem-1915	206	275	[	[	X
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eurjchem-1915	206	277	data	datum	NOUN
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eurjchem-1915	206	280	=	=	SYM
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eurjchem-1915	206	293	e	e	NOUN
eurjchem-1915	206	294	å-3	å-3	NUM
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eurjchem-1915	206	331	-	-	PUNCT
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eurjchem-1915	206	341	2008	2008	NUM
eurjchem-1915	206	342	)	)	PUNCT
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eurjchem-1915	206	348	(	(	PUNCT
eurjchem-1915	206	349	å	å	NOUN
eurjchem-1915	206	350	)	)	PUNCT
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eurjchem-1915	206	357	atom	atom	NOUN
eurjchem-1915	206	358	bond	bond	NOUN
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eurjchem-1915	206	360	atom	atom	NOUN
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eurjchem-1915	206	374	)	)	PUNCT
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eurjchem-1915	206	382	c10	c10	VERB
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eurjchem-1915	206	384	)	)	PUNCT
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eurjchem-1915	206	387	h7	h7	PROPN
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eurjchem-1915	206	389	)	)	PUNCT
eurjchem-1915	206	390	n2	n2	ADJ
eurjchem-1915	206	391	-	-	PUNCT
eurjchem-1915	206	392	n1	n1	NOUN
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eurjchem-1915	206	394	)	)	PUNCT
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eurjchem-1915	206	396	-	-	PUNCT
eurjchem-1915	206	397	c4	c4	NOUN
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eurjchem-1915	206	402	c10	c10	PROPN
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eurjchem-1915	206	405	c1	c1	PROPN
eurjchem-1915	206	406	-	-	PUNCT
eurjchem-1915	206	407	c2	c2	PROPN
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eurjchem-1915	206	410	n1	n1	PROPN
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eurjchem-1915	206	412	c8	c8	PROPN
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eurjchem-1915	206	417	c3	c3	PROPN
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eurjchem-1915	206	420	c1	c1	PROPN
eurjchem-1915	206	421	-	-	PUNCT
eurjchem-1915	206	422	c6	c6	PROPN
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eurjchem-1915	206	425	c3	c3	PROPN
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eurjchem-1915	206	427	c4	c4	PROPN
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eurjchem-1915	206	430	c5	c5	PROPN
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eurjchem-1915	206	432	c9	c9	PROPN
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eurjchem-1915	206	437	c7	c7	PROPN
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eurjchem-1915	206	442	c7	c7	PROPN
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eurjchem-1915	206	446	1	1	NUM
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eurjchem-1915	206	461	(	(	PUNCT
eurjchem-1915	206	462	°	°	NOUN
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eurjchem-1915	206	472	atom	atom	NOUN
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eurjchem-1915	206	479	atom	atom	NOUN
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eurjchem-1915	206	482	c5	c5	PROPN
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eurjchem-1915	206	498	n1	n1	NOUN
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eurjchem-1915	206	532	-	-	PUNCT
eurjchem-1915	206	533	c3	c3	NOUN
eurjchem-1915	206	534	-	-	PROPN
eurjchem-1915	206	535	c2	c2	PROPN
eurjchem-1915	206	536	118.2(5	118.2(5	NUM
eurjchem-1915	206	537	)	)	PUNCT
eurjchem-1915	206	538	c7	c7	PROPN
eurjchem-1915	206	539	-	-	PUNCT
eurjchem-1915	206	540	c4	c4	NOUN
eurjchem-1915	206	541	-	-	PUNCT
eurjchem-1915	206	542	c3	c3	PROPN
eurjchem-1915	206	543	121.4(5	121.4(5	NUM
eurjchem-1915	206	544	)	)	PUNCT
eurjchem-1915	206	545	c7	c7	PROPN
eurjchem-1915	206	546	-	-	PUNCT
eurjchem-1915	206	547	c4	c4	NOUN
eurjchem-1915	206	548	-	-	PUNCT
eurjchem-1915	206	549	n1	n1	NOUN
eurjchem-1915	206	550	119.6(4	119.6(4	NOUN
eurjchem-1915	206	551	)	)	PUNCT
eurjchem-1915	206	552	c3	c3	NOUN
eurjchem-1915	206	553	-	-	PUNCT
eurjchem-1915	206	554	c4	c4	NOUN
eurjchem-1915	206	555	-	-	PUNCT
eurjchem-1915	206	556	n1	n1	NOUN
eurjchem-1915	206	557	119.0(5	119.0(5	NOUN
eurjchem-1915	206	558	)	)	PUNCT
eurjchem-1915	206	559	n2	n2	ADJ
eurjchem-1915	206	560	-	-	PUNCT
eurjchem-1915	206	561	c5	c5	PROPN
eurjchem-1915	206	562	-	-	PUNCT
eurjchem-1915	206	563	c9	c9	NOUN
eurjchem-1915	206	564	110.5(4	110.5(4	PROPN
eurjchem-1915	206	565	)	)	PUNCT
eurjchem-1915	206	566	n2	n2	ADJ
eurjchem-1915	206	567	-	-	PUNCT
eurjchem-1915	206	568	c5	c5	PROPN
eurjchem-1915	206	569	-	-	PUNCT
eurjchem-1915	206	570	c5#1	c5#1	PROPN
eurjchem-1915	206	571	117.3(5	117.3(5	NUM
eurjchem-1915	206	572	)	)	PUNCT
eurjchem-1915	206	573	c9	c9	NOUN
eurjchem-1915	206	574	-	-	PUNCT
eurjchem-1915	206	575	c5	c5	PROPN
eurjchem-1915	206	576	-	-	PUNCT
eurjchem-1915	206	577	c5#1	c5#1	PROPN
eurjchem-1915	206	578	132.2(6	132.2(6	NOUN
eurjchem-1915	206	579	)	)	PUNCT
eurjchem-1915	206	580	c1	c1	PROPN
eurjchem-1915	206	581	-	-	PUNCT
eurjchem-1915	206	582	c6	c6	PROPN
eurjchem-1915	206	583	-	-	PUNCT
eurjchem-1915	206	584	c7	c7	PROPN
eurjchem-1915	206	585	120.4(5	120.4(5	NUM
eurjchem-1915	206	586	)	)	PUNCT
eurjchem-1915	206	587	c4	c4	NOUN
eurjchem-1915	206	588	-	-	PUNCT
eurjchem-1915	206	589	c7	c7	PROPN
eurjchem-1915	206	590	-	-	PUNCT
eurjchem-1915	206	591	c6	c6	PROPN
eurjchem-1915	206	592	118.7(5	118.7(5	NUM
eurjchem-1915	206	593	)	)	PUNCT
eurjchem-1915	206	594	n1	n1	PROPN
eurjchem-1915	206	595	-	-	PUNCT
eurjchem-1915	206	596	c8	c8	NOUN
eurjchem-1915	206	597	-	-	PUNCT
eurjchem-1915	206	598	c9	c9	NOUN
eurjchem-1915	206	599	108.5(4	108.5(4	NUM
eurjchem-1915	206	600	)	)	PUNCT
eurjchem-1915	206	601	c8	c8	NOUN
eurjchem-1915	206	602	-	-	PUNCT
eurjchem-1915	206	603	c9	c9	NOUN
eurjchem-1915	206	604	-	-	PUNCT
eurjchem-1915	206	605	c5	c5	PROPN
eurjchem-1915	206	606	103.9(4	103.9(4	NUM
eurjchem-1915	206	607	)	)	PUNCT
eurjchem-1915	206	608	c8	c8	NOUN
eurjchem-1915	206	609	-	-	PUNCT
eurjchem-1915	206	610	c9	c9	NOUN
eurjchem-1915	206	611	-	-	PUNCT
eurjchem-1915	206	612	c10	c10	VERB
eurjchem-1915	206	613	120.7(4	120.7(4	PROPN
eurjchem-1915	206	614	)	)	PUNCT
eurjchem-1915	206	615	c5	c5	PROPN
eurjchem-1915	206	616	-	-	PUNCT
eurjchem-1915	206	617	c9	c9	NOUN
eurjchem-1915	206	618	-	-	PUNCT
eurjchem-1915	206	619	c10	c10	PROPN
eurjchem-1915	206	620	135.3(4	135.3(4	NOUN
eurjchem-1915	206	621	)	)	PUNCT
eurjchem-1915	206	622	o2	o2	PROPN
eurjchem-1915	206	623	-	-	PUNCT
eurjchem-1915	206	624	c10	c10	VERB
eurjchem-1915	206	625	-	-	PUNCT
eurjchem-1915	206	626	o3	o3	PROPN
eurjchem-1915	206	627	119.6(5	119.6(5	PROPN
eurjchem-1915	206	628	)	)	PUNCT
eurjchem-1915	206	629	o2	o2	PROPN
eurjchem-1915	206	630	-	-	PUNCT
eurjchem-1915	206	631	c10	c10	VERB
eurjchem-1915	206	632	-	-	PUNCT
eurjchem-1915	206	633	c9	c9	NOUN
eurjchem-1915	206	634	121.2(5	121.2(5	NOUN
eurjchem-1915	206	635	)	)	PUNCT
eurjchem-1915	206	636	#	#	SYM
eurjchem-1915	206	637	1	1	NUM
eurjchem-1915	206	638	symmetry	symmetry	NOUN
eurjchem-1915	206	639	code	code	NOUN
eurjchem-1915	206	640	:	:	PUNCT
eurjchem-1915	206	641	-x+1	-x+1	ADJ
eurjchem-1915	206	642	,	,	PUNCT
eurjchem-1915	206	643	-y+1	-y+1	PROPN
eurjchem-1915	206	644	,	,	PUNCT
eurjchem-1915	206	645	-z+1	-z+1	PROPN
eurjchem-1915	206	646	.	.	PUNCT
eurjchem-1915	207	1	on	on	ADP
eurjchem-1915	207	2	the	the	DET
eurjchem-1915	207	3	other	other	ADJ
eurjchem-1915	207	4	hand	hand	NOUN
eurjchem-1915	207	5	,	,	PUNCT
eurjchem-1915	207	6	all	all	DET
eurjchem-1915	207	7	trials	trial	NOUN
eurjchem-1915	207	8	to	to	PART
eurjchem-1915	207	9	chelate	chelate	VERB
eurjchem-1915	207	10	the	the	DET
eurjchem-1915	207	11	bipyrazoledicarboxylate	bipyrazoledicarboxylate	ADJ
eurjchem-1915	207	12	ester	ester	NOUN
eurjchem-1915	207	13	derivative	derivative	ADJ
eurjchem-1915	207	14	5a	5a	NUM
eurjchem-1915	207	15	with	with	ADP
eurjchem-1915	207	16	pdcl2	pdcl2	NOUN
eurjchem-1915	207	17	were	be	AUX
eurjchem-1915	207	18	failed	fail	VERB
eurjchem-1915	207	19	.	.	PUNCT
eurjchem-1915	208	1	this	this	PRON
eurjchem-1915	208	2	may	may	AUX
eurjchem-1915	208	3	be	be	AUX
eurjchem-1915	208	4	interpreted	interpret	VERB
eurjchem-1915	208	5	in	in	ADP
eurjchem-1915	208	6	terms	term	NOUN
eurjchem-1915	208	7	of	of	ADP
eurjchem-1915	208	8	the	the	DET
eurjchem-1915	208	9	non	non	NOUN
eurjchem-1915	208	10	-	-	NOUN
eurjchem-1915	208	11	planarity	planarity	NOUN
eurjchem-1915	208	12	of	of	ADP
eurjchem-1915	208	13	the	the	DET
eurjchem-1915	208	14	bipyrazole	bipyrazole	ADJ
eurjchem-1915	208	15	ester	ester	NOUN
eurjchem-1915	208	16	derivative	derivative	NOUN
eurjchem-1915	208	17	5	5	NUM
eurjchem-1915	208	18	due	due	ADP
eurjchem-1915	208	19	to	to	ADP
eurjchem-1915	208	20	the	the	DET
eurjchem-1915	208	21	high	high	ADJ
eurjchem-1915	208	22	steric	steric	ADJ
eurjchem-1915	208	23	hindrance	hindrance	NOUN
eurjchem-1915	208	24	of	of	ADP
eurjchem-1915	208	25	the	the	DET
eurjchem-1915	208	26	ester	ester	NOUN
eurjchem-1915	208	27	groups	group	NOUN
eurjchem-1915	208	28	and	and	CCONJ
eurjchem-1915	208	29	consequently	consequently	ADV
eurjchem-1915	208	30	,	,	PUNCT
eurjchem-1915	208	31	the	the	DET
eurjchem-1915	208	32	nitrogen	nitrogen	NOUN
eurjchem-1915	208	33	-	-	PUNCT
eurjchem-1915	208	34	dentates	dentate	NOUN
eurjchem-1915	208	35	are	be	AUX
eurjchem-1915	208	36	not	not	PART
eurjchem-1915	208	37	in	in	ADP
eurjchem-1915	208	38	the	the	DET
eurjchem-1915	208	39	appropriate	appropriate	ADJ
eurjchem-1915	208	40	positions	position	NOUN
eurjchem-1915	208	41	to	to	PART
eurjchem-1915	208	42	interact	interact	VERB
eurjchem-1915	208	43	with	with	ADP
eurjchem-1915	208	44	palladium	palladium	NOUN
eurjchem-1915	208	45	ions	ion	NOUN
eurjchem-1915	208	46	.	.	PUNCT
eurjchem-1915	209	1	however	however	ADV
eurjchem-1915	209	2	,	,	PUNCT
eurjchem-1915	209	3	treatment	treatment	NOUN
eurjchem-1915	209	4	of	of	ADP
eurjchem-1915	209	5	the	the	DET
eurjchem-1915	209	6	bipyrazole	bipyrazole	ADJ
eurjchem-1915	209	7	-	-	PUNCT
eurjchem-1915	209	8	dicarboxylic	dicarboxylic	NOUN
eurjchem-1915	209	9	acid	acid	NOUN
eurjchem-1915	209	10	derivative	derivative	NOUN
eurjchem-1915	209	11	6	6	NUM
eurjchem-1915	209	12	with	with	ADP
eurjchem-1915	209	13	pdcl2	pdcl2	NOUN
eurjchem-1915	209	14	in	in	ADP
eurjchem-1915	209	15	dmf	dmf	PROPN
eurjchem-1915	209	16	resulted	result	VERB
eurjchem-1915	209	17	in	in	ADP
eurjchem-1915	209	18	the	the	DET
eurjchem-1915	209	19	formation	formation	NOUN
eurjchem-1915	209	20	of	of	ADP
eurjchem-1915	209	21	the	the	DET
eurjchem-1915	209	22	bipyrazole	bipyrazole	NOUN
eurjchem-1915	209	23	-	-	PUNCT
eurjchem-1915	209	24	palladium(ii	palladium(ii	NOUN
eurjchem-1915	209	25	)	)	PUNCT
eurjchem-1915	209	26	complex	complex	ADJ
eurjchem-1915	209	27	structure	structure	NOUN
eurjchem-1915	209	28	8	8	NUM
eurjchem-1915	209	29	(	(	PUNCT
eurjchem-1915	209	30	scheme	scheme	NOUN
eurjchem-1915	209	31	2	2	NUM
eurjchem-1915	209	32	)	)	PUNCT
eurjchem-1915	209	33	.	.	PUNCT
eurjchem-1915	210	1	3.3	3.3	NUM
eurjchem-1915	210	2	.	.	PUNCT
eurjchem-1915	210	3	xps	xps	PROPN
eurjchem-1915	210	4	and	and	CCONJ
eurjchem-1915	210	5	edx	edx	PROPN
eurjchem-1915	210	6	measurements	measurement	NOUN
eurjchem-1915	210	7	of	of	ADP
eurjchem-1915	210	8	palladium(ii	palladium(ii	NOUN
eurjchem-1915	210	9	)	)	PUNCT
eurjchem-1915	210	10	complexes	complexe	VERB
eurjchem-1915	210	11	all	all	DET
eurjchem-1915	210	12	attempts	attempt	NOUN
eurjchem-1915	210	13	to	to	PART
eurjchem-1915	210	14	get	get	VERB
eurjchem-1915	210	15	a	a	DET
eurjchem-1915	210	16	single	single	ADJ
eurjchem-1915	210	17	crystal	crystal	NOUN
eurjchem-1915	210	18	of	of	ADP
eurjchem-1915	210	19	the	the	DET
eurjchem-1915	210	20	obtained	obtain	VERB
eurjchem-1915	210	21	complex	complex	NOUN
eurjchem-1915	210	22	7	7	NUM
eurjchem-1915	210	23	and	and	CCONJ
eurjchem-1915	210	24	8	8	NUM
eurjchem-1915	210	25	were	be	AUX
eurjchem-1915	210	26	not	not	PART
eurjchem-1915	210	27	successful	successful	ADJ
eurjchem-1915	210	28	.	.	PUNCT
eurjchem-1915	211	1	therefore	therefore	ADV
eurjchem-1915	211	2	,	,	PUNCT
eurjchem-1915	211	3	x	x	X
eurjchem-1915	211	4	-	-	NOUN
eurjchem-1915	211	5	ray	ray	NOUN
eurjchem-1915	211	6	photoelectron	photoelectron	NOUN
eurjchem-1915	211	7	spectroscopy	spectroscopy	NOUN
eurjchem-1915	211	8	(	(	PUNCT
eurjchem-1915	211	9	xps	xps	PROPN
eurjchem-1915	211	10	)	)	PUNCT
eurjchem-1915	211	11	technique	technique	NOUN
eurjchem-1915	211	12	was	be	AUX
eurjchem-1915	211	13	used	use	VERB
eurjchem-1915	211	14	to	to	PART
eurjchem-1915	211	15	elucidate	elucidate	VERB
eurjchem-1915	211	16	the	the	DET
eurjchem-1915	211	17	chemical	chemical	ADJ
eurjchem-1915	211	18	composition	composition	NOUN
eurjchem-1915	211	19	of	of	ADP
eurjchem-1915	211	20	the	the	DET
eurjchem-1915	211	21	palladium	palladium	NOUN
eurjchem-1915	211	22	complex	complex	NOUN
eurjchem-1915	211	23	8	8	NUM
eurjchem-1915	211	24	.	.	PUNCT
eurjchem-1915	212	1	the	the	DET
eurjchem-1915	212	2	xps	xps	PROPN
eurjchem-1915	212	3	analysis	analysis	NOUN
eurjchem-1915	212	4	(	(	PUNCT
eurjchem-1915	212	5	figure	figure	NOUN
eurjchem-1915	212	6	2	2	NUM
eurjchem-1915	212	7	)	)	PUNCT
eurjchem-1915	212	8	confirmed	confirm	VERB
eurjchem-1915	212	9	the	the	DET
eurjchem-1915	212	10	presence	presence	NOUN
eurjchem-1915	212	11	of	of	ADP
eurjchem-1915	212	12	palladium	palladium	NOUN
eurjchem-1915	212	13	,	,	PUNCT
eurjchem-1915	212	14	carbon	carbon	NOUN
eurjchem-1915	212	15	,	,	PUNCT
eurjchem-1915	212	16	nitrogen	nitrogen	NOUN
eurjchem-1915	212	17	and	and	CCONJ
eurjchem-1915	212	18	oxygen	oxygen	NOUN
eurjchem-1915	212	19	elements	element	NOUN
eurjchem-1915	212	20	in	in	ADP
eurjchem-1915	212	21	the	the	DET
eurjchem-1915	212	22	complex	complex	ADJ
eurjchem-1915	212	23	8	8	NUM
eurjchem-1915	212	24	.	.	PUNCT
eurjchem-1915	213	1	in	in	ADP
eurjchem-1915	213	2	the	the	DET
eurjchem-1915	213	3	xps	xps	PROPN
eurjchem-1915	213	4	valence	valence	NOUN
eurjchem-1915	213	5	band	band	NOUN
eurjchem-1915	213	6	spectra	spectra	NOUN
eurjchem-1915	213	7	for	for	ADP
eurjchem-1915	213	8	the	the	DET
eurjchem-1915	213	9	pd	pd	PROPN
eurjchem-1915	213	10	,	,	PUNCT
eurjchem-1915	213	11	two	two	NUM
eurjchem-1915	213	12	pairs	pair	NOUN
eurjchem-1915	213	13	pd	pd	PROPN
eurjchem-1915	213	14	3d	3d	NUM
eurjchem-1915	213	15	peaks	peak	NOUN
eurjchem-1915	213	16	were	be	AUX
eurjchem-1915	213	17	observed	observe	VERB
eurjchem-1915	213	18	(	(	PUNCT
eurjchem-1915	213	19	figure	figure	NOUN
eurjchem-1915	213	20	2a	2a	NUM
eurjchem-1915	213	21	)	)	PUNCT
eurjchem-1915	213	22	.	.	PUNCT
eurjchem-1915	214	1	the	the	DET
eurjchem-1915	214	2	binding	bind	VERB
eurjchem-1915	214	3	energy	energy	NOUN
eurjchem-1915	214	4	values	value	NOUN
eurjchem-1915	214	5	of	of	ADP
eurjchem-1915	214	6	338.1	338.1	NUM
eurjchem-1915	214	7	,	,	PUNCT
eurjchem-1915	214	8	343.3	343.3	NUM
eurjchem-1915	214	9	and	and	CCONJ
eurjchem-1915	214	10	345.1	345.1	NUM
eurjchem-1915	214	11	ev	ev	NOUN
eurjchem-1915	214	12	were	be	AUX
eurjchem-1915	214	13	assigned	assign	VERB
eurjchem-1915	214	14	to	to	PART
eurjchem-1915	214	15	incarcerate	incarcerate	VERB
eurjchem-1915	214	16	pd	pd	PROPN
eurjchem-1915	214	17	(	(	PUNCT
eurjchem-1915	214	18	ii	ii	PROPN
eurjchem-1915	214	19	)	)	PUNCT
eurjchem-1915	215	1	[	[	X
eurjchem-1915	215	2	30,31	30,31	NUM
eurjchem-1915	215	3	]	]	PUNCT
eurjchem-1915	215	4	.	.	PUNCT
eurjchem-1915	216	1	the	the	DET
eurjchem-1915	216	2	peak	peak	NOUN
eurjchem-1915	216	3	at	at	ADP
eurjchem-1915	216	4	339.86	339.86	NUM
eurjchem-1915	216	5	was	be	AUX
eurjchem-1915	216	6	assigned	assign	VERB
eurjchem-1915	216	7	to	to	ADP
eurjchem-1915	216	8	pd	pd	PROPN
eurjchem-1915	216	9	-	-	PROPN
eurjchem-1915	216	10	o	o	PROPN
eurjchem-1915	216	11	bond	bond	NOUN
eurjchem-1915	216	12	.	.	PUNCT
eurjchem-1915	217	1	n1s	n1s	PROPN
eurjchem-1915	217	2	high	high	ADJ
eurjchem-1915	217	3	-	-	PUNCT
eurjchem-1915	217	4	resolution	resolution	NOUN
eurjchem-1915	217	5	spectra	spectra	NOUN
eurjchem-1915	217	6	(	(	PUNCT
eurjchem-1915	217	7	figure	figure	NOUN
eurjchem-1915	217	8	2b	2b	NOUN
eurjchem-1915	217	9	)	)	PUNCT
eurjchem-1915	217	10	showed	show	VERB
eurjchem-1915	217	11	two	two	NUM
eurjchem-1915	217	12	peaks	peak	NOUN
eurjchem-1915	217	13	,	,	PUNCT
eurjchem-1915	217	14	the	the	DET
eurjchem-1915	217	15	first	first	ADJ
eurjchem-1915	217	16	peak	peak	NOUN
eurjchem-1915	217	17	falling	fall	VERB
eurjchem-1915	217	18	at	at	ADP
eurjchem-1915	217	19	binding	bind	VERB
eurjchem-1915	217	20	energy	energy	NOUN
eurjchem-1915	217	21	399.9	399.9	NUM
eurjchem-1915	217	22	ev	ev	PROPN
eurjchem-1915	217	23	was	be	AUX
eurjchem-1915	217	24	assigned	assign	VERB
eurjchem-1915	217	25	to	to	ADP
eurjchem-1915	217	26	pd	pd	ADJ
eurjchem-1915	217	27	-	-	PUNCT
eurjchem-1915	217	28	n	n	PRON
eurjchem-1915	217	29	bond	bond	NOUN
eurjchem-1915	217	30	[	[	X
eurjchem-1915	217	31	32,33	32,33	NUM
eurjchem-1915	217	32	]	]	PUNCT
eurjchem-1915	217	33	and	and	CCONJ
eurjchem-1915	217	34	the	the	DET
eurjchem-1915	217	35	second	second	ADJ
eurjchem-1915	217	36	one	one	NOUN
eurjchem-1915	217	37	,	,	PUNCT
eurjchem-1915	217	38	falling	fall	VERB
eurjchem-1915	217	39	at	at	ADP
eurjchem-1915	217	40	binding	bind	VERB
eurjchem-1915	217	41	energy	energy	NOUN
eurjchem-1915	217	42	406.7	406.7	NUM
eurjchem-1915	217	43	ev	ev	ADP
eurjchem-1915	217	44	attributed	attribute	VERB
eurjchem-1915	217	45	to	to	ADP
eurjchem-1915	217	46	oxidized	oxidize	VERB
eurjchem-1915	217	47	n.	n.	NOUN
eurjchem-1915	217	48	o1s	o1s	PROPN
eurjchem-1915	217	49	peak	peak	NOUN
eurjchem-1915	217	50	(	(	PUNCT
eurjchem-1915	217	51	figure	figure	NOUN
eurjchem-1915	217	52	2c	2c	NUM
eurjchem-1915	217	53	)	)	PUNCT
eurjchem-1915	217	54	at	at	ADP
eurjchem-1915	217	55	binding	bind	VERB
eurjchem-1915	217	56	energy	energy	NOUN
eurjchem-1915	217	57	531.46	531.46	NUM
eurjchem-1915	217	58	ev	ev	PRON
eurjchem-1915	217	59	assigned	assign	VERB
eurjchem-1915	217	60	to	to	PART
eurjchem-1915	217	61	c−o	c−o	VERB
eurjchem-1915	217	62	and	and	CCONJ
eurjchem-1915	217	63	o	o	ADJ
eurjchem-1915	217	64	-	-	ADJ
eurjchem-1915	217	65	h	h	ADJ
eurjchem-1915	217	66	bond	bond	NOUN
eurjchem-1915	217	67	.	.	PUNCT
eurjchem-1915	218	1	c1s	c1s	ADJ
eurjchem-1915	218	2	high	high	ADJ
eurjchem-1915	218	3	-	-	PUNCT
eurjchem-1915	218	4	resolution	resolution	NOUN
eurjchem-1915	218	5	spectra	spectra	NOUN
eurjchem-1915	218	6	for	for	ADP
eurjchem-1915	218	7	pd	pd	NOUN
eurjchem-1915	218	8	-	-	PUNCT
eurjchem-1915	218	9	complex	complex	NOUN
eurjchem-1915	218	10	are	be	AUX
eurjchem-1915	218	11	reported	report	VERB
eurjchem-1915	218	12	in	in	ADP
eurjchem-1915	218	13	figure	figure	NOUN
eurjchem-1915	218	14	2d	2d	NOUN
eurjchem-1915	218	15	.	.	PUNCT
eurjchem-1915	219	1	they	they	PRON
eurjchem-1915	219	2	were	be	AUX
eurjchem-1915	219	3	assigned	assign	VERB
eurjchem-1915	219	4	to	to	ADP
eurjchem-1915	219	5	c	c	X
eurjchem-1915	219	6	–	–	PUNCT
eurjchem-1915	219	7	c	c	NOUN
eurjchem-1915	219	8	,	,	PUNCT
eurjchem-1915	219	9	and	and	CCONJ
eurjchem-1915	219	10	c	c	X
eurjchem-1915	219	11	=	=	SYM
eurjchem-1915	219	12	c	c	X
eurjchem-1915	219	13	(	(	PUNCT
eurjchem-1915	219	14	284.5	284.5	NUM
eurjchem-1915	219	15	ev	ev	NOUN
eurjchem-1915	219	16	)	)	PUNCT
eurjchem-1915	219	17	,	,	PUNCT
eurjchem-1915	219	18	c	c	X
eurjchem-1915	219	19	–	–	PUNCT
eurjchem-1915	219	20	o	o	X
eurjchem-1915	219	21	(	(	PUNCT
eurjchem-1915	219	22	285.82	285.82	NUM
eurjchem-1915	219	23	ev	ev	NUM
eurjchem-1915	219	24	)	)	PUNCT
eurjchem-1915	219	25	and	and	CCONJ
eurjchem-1915	219	26	c	c	NOUN
eurjchem-1915	219	27	=	=	NOUN
eurjchem-1915	219	28	o	o	X
eurjchem-1915	219	29	and	and	CCONJ
eurjchem-1915	219	30	may	may	AUX
eurjchem-1915	219	31	be	be	AUX
eurjchem-1915	219	32	for	for	ADP
eurjchem-1915	219	33	c	c	NOUN
eurjchem-1915	219	34	-	-	PUNCT
eurjchem-1915	219	35	o	o	NOUN
eurjchem-1915	219	36	-	-	NOUN
eurjchem-1915	219	37	m	m	PROPN
eurjchem-1915	219	38	(	(	PUNCT
eurjchem-1915	219	39	m	m	NOUN
eurjchem-1915	219	40	metal	metal	NOUN
eurjchem-1915	219	41	ion	ion	NOUN
eurjchem-1915	219	42	)	)	PUNCT
eurjchem-1915	219	43	at	at	ADP
eurjchem-1915	219	44	binding	bind	VERB
eurjchem-1915	219	45	energy	energy	NOUN
eurjchem-1915	219	46	287.4	287.4	NUM
eurjchem-1915	219	47	ev	ev	NOUN
eurjchem-1915	219	48	)	)	PUNCT
eurjchem-1915	219	49	groups	group	NOUN
eurjchem-1915	219	50	.	.	PUNCT
eurjchem-1915	220	1	moreover	moreover	ADV
eurjchem-1915	220	2	,	,	PUNCT
eurjchem-1915	220	3	the	the	DET
eurjchem-1915	220	4	binding	bind	VERB
eurjchem-1915	220	5	energies	energy	NOUN
eurjchem-1915	220	6	198.23	198.23	NUM
eurjchem-1915	220	7	and	and	CCONJ
eurjchem-1915	220	8	199.82	199.82	NUM
eurjchem-1915	220	9	ev	ev	NUM
eurjchem-1915	220	10	were	be	AUX
eurjchem-1915	220	11	assigned	assign	VERB
eurjchem-1915	220	12	for	for	ADP
eurjchem-1915	220	13	cl	cl	NOUN
eurjchem-1915	220	14	2p	2p	NOUN
eurjchem-1915	220	15	,	,	PUNCT
eurjchem-1915	220	16	3/2	3/2	NUM
eurjchem-1915	220	17	and	and	CCONJ
eurjchem-1915	220	18	cl	cl	NOUN
eurjchem-1915	220	19	2p	2p	NUM
eurjchem-1915	220	20	,	,	PUNCT
eurjchem-1915	220	21	1/2	1/2	NUM
eurjchem-1915	220	22	.	.	NOUN
eurjchem-1915	221	1	2019	2019	NUM
eurjchem-1915	221	2	–	–	PUNCT
eurjchem-1915	221	3	european	european	ADJ
eurjchem-1915	221	4	journal	journal	NOUN
eurjchem-1915	221	5	of	of	ADP
eurjchem-1915	221	6	chemistry	chemistry	NOUN
eurjchem-1915	221	7	–	–	PUNCT
eurjchem-1915	221	8	cc	cc	NOUN
eurjchem-1915	221	9	by	by	ADP
eurjchem-1915	221	10	nc	nc	PROPN
eurjchem-1915	221	11	–	–	PUNCT
eurjchem-1915	221	12	doi	doi	PROPN
eurjchem-1915	221	13	:	:	PUNCT
eurjchem-1915	221	14	10.5155	10.5155	NUM
eurjchem-1915	221	15	/	/	SYM
eurjchem-1915	221	16	eurjchem.10.4.367	eurjchem.10.4.367	NOUN
eurjchem-1915	221	17	-	-	SYM
eurjchem-1915	221	18	375.1915	375.1915	NUM
eurjchem-1915	221	19	372	372	NUM
eurjchem-1915	221	20	al	al	PROPN
eurjchem-1915	221	21	-	-	PUNCT
eurjchem-1915	221	22	fulaij	fulaij	PROPN
eurjchem-1915	221	23	et	et	PROPN
eurjchem-1915	221	24	al	al	PROPN
eurjchem-1915	221	25	.	.	PUNCT
eurjchem-1915	221	26	/	/	SYM
eurjchem-1915	221	27	european	european	PROPN
eurjchem-1915	221	28	journal	journal	PROPN
eurjchem-1915	221	29	of	of	ADP
eurjchem-1915	221	30	chemistry	chemistry	NOUN
eurjchem-1915	221	31	10	10	NUM
eurjchem-1915	221	32	(	(	PUNCT
eurjchem-1915	221	33	4	4	NUM
eurjchem-1915	221	34	)	)	PUNCT
eurjchem-1915	221	35	(	(	PUNCT
eurjchem-1915	221	36	2019	2019	NUM
eurjchem-1915	221	37	)	)	PUNCT
eurjchem-1915	221	38	367	367	NUM
eurjchem-1915	221	39	-	-	SYM
eurjchem-1915	221	40	375	375	NUM
eurjchem-1915	221	41	figure	figure	NOUN
eurjchem-1915	221	42	2	2	NUM
eurjchem-1915	221	43	.	.	PUNCT
eurjchem-1915	221	44	xps	xps	PROPN
eurjchem-1915	221	45	of	of	ADP
eurjchem-1915	221	46	pd	pd	PROPN
eurjchem-1915	221	47	-	-	PUNCT
eurjchem-1915	221	48	complex	complex	ADJ
eurjchem-1915	221	49	8	8	NUM
eurjchem-1915	221	50	,	,	PUNCT
eurjchem-1915	221	51	binding	bind	VERB
eurjchem-1915	221	52	energy	energy	NOUN
eurjchem-1915	221	53	of	of	ADP
eurjchem-1915	221	54	c	c	PROPN
eurjchem-1915	221	55	,	,	PUNCT
eurjchem-1915	221	56	n	n	CCONJ
eurjchem-1915	221	57	,	,	PUNCT
eurjchem-1915	221	58	o	o	PROPN
eurjchem-1915	221	59	and	and	CCONJ
eurjchem-1915	221	60	pd	pd	PROPN
eurjchem-1915	221	61	.	.	PROPN
eurjchem-1915	221	62	n	n	PROPN
eurjchem-1915	221	63	n	n	CCONJ
eurjchem-1915	221	64	nn	nn	INTJ
eurjchem-1915	221	65	ph	ph	ADJ
eurjchem-1915	221	66	ph	ph	PROPN
eurjchem-1915	221	67	c	c	PROPN
eurjchem-1915	221	68	c	c	PROPN
eurjchem-1915	221	69	pd	pd	X
eurjchem-1915	221	70	cl	cl	NOUN
eurjchem-1915	222	1	cl	cl	NOUN
eurjchem-1915	223	1	o	o	NOUN
eurjchem-1915	223	2	o	o	X
eurjchem-1915	223	3	o	o	X
eurjchem-1915	223	4	o	o	X
eurjchem-1915	223	5	pd	pd	X
eurjchem-1915	223	6	cl	cl	NOUN
eurjchem-1915	223	7	cl	cl	NOUN
eurjchem-1915	223	8	n	n	CCONJ
eurjchem-1915	223	9	n	n	CCONJ
eurjchem-1915	223	10	nn	nn	INTJ
eurjchem-1915	223	11	ph	ph	ADJ
eurjchem-1915	223	12	ph	ph	PROPN
eurjchem-1915	223	13	c	c	PROPN
eurjchem-1915	223	14	c	c	PROPN
eurjchem-1915	223	15	pd	pd	X
eurjchem-1915	223	16	cl	cl	NOUN
eurjchem-1915	224	1	cl	cl	NOUN
eurjchem-1915	225	1	o	o	NOUN
eurjchem-1915	225	2	o	o	X
eurjchem-1915	225	3	o	o	X
eurjchem-1915	225	4	o	o	X
eurjchem-1915	225	5	pd	pd	X
eurjchem-1915	225	6	cl	cl	NOUN
eurjchem-1915	225	7	cl	cl	NOUN
eurjchem-1915	226	1	h	h	NOUN
eurjchem-1915	226	2	h	h	NOUN
eurjchem-1915	226	3	n	n	CCONJ
eurjchem-1915	226	4	n	n	CCONJ
eurjchem-1915	226	5	nn	nn	INTJ
eurjchem-1915	226	6	ph	ph	ADJ
eurjchem-1915	226	7	ph	ph	PROPN
eurjchem-1915	226	8	c	c	PROPN
eurjchem-1915	226	9	c	c	PROPN
eurjchem-1915	226	10	pd	pd	X
eurjchem-1915	226	11	cl	cl	NOUN
eurjchem-1915	226	12	cl	cl	NOUN
eurjchem-1915	227	1	o	o	NOUN
eurjchem-1915	228	1	o	o	X
eurjchem-1915	228	2	o	o	X
eurjchem-1915	228	3	o	o	X
eurjchem-1915	228	4	pd	pd	X
eurjchem-1915	228	5	cl	cl	NOUN
eurjchem-1915	228	6	cl	cl	NOUN
eurjchem-1915	228	7	h	h	NOUN
eurjchem-1915	228	8	hh	hh	INTJ
eurjchem-1915	228	9	h	h	NOUN
eurjchem-1915	228	10	figure	figure	NOUN
eurjchem-1915	228	11	3	3	NUM
eurjchem-1915	228	12	.	.	PUNCT
eurjchem-1915	229	1	h	h	NOUN
eurjchem-1915	229	2	-	-	PUNCT
eurjchem-1915	229	3	bonding	bonding	NOUN
eurjchem-1915	229	4	between	between	ADP
eurjchem-1915	229	5	compound	compound	NOUN
eurjchem-1915	229	6	8	8	NUM
eurjchem-1915	229	7	forms	form	NOUN
eurjchem-1915	229	8	consecutive	consecutive	ADJ
eurjchem-1915	229	9	layers	layer	NOUN
eurjchem-1915	229	10	.	.	PUNCT
eurjchem-1915	230	1	furthermore	furthermore	ADV
eurjchem-1915	230	2	,	,	PUNCT
eurjchem-1915	230	3	the	the	DET
eurjchem-1915	230	4	ir	ir	PROPN
eurjchem-1915	230	5	spectrum	spectrum	NOUN
eurjchem-1915	230	6	of	of	ADP
eurjchem-1915	230	7	compound	compound	NOUN
eurjchem-1915	230	8	8	8	NUM
eurjchem-1915	230	9	showed	show	VERB
eurjchem-1915	230	10	a	a	DET
eurjchem-1915	230	11	shift	shift	NOUN
eurjchem-1915	230	12	in	in	ADP
eurjchem-1915	230	13	the	the	DET
eurjchem-1915	230	14	carbonyl	carbonyl	NOUN
eurjchem-1915	230	15	absorption	absorption	NOUN
eurjchem-1915	230	16	,	,	PUNCT
eurjchem-1915	230	17	∆νc	∆νc	PROPN
eurjchem-1915	230	18	=	=	SYM
eurjchem-1915	230	19	o	o	X
eurjchem-1915	230	20	=	=	SYM
eurjchem-1915	230	21	23	23	NUM
eurjchem-1915	230	22	cm-1	cm-1	NOUN
eurjchem-1915	230	23	,	,	PUNCT
eurjchem-1915	230	24	and	and	CCONJ
eurjchem-1915	230	25	hydroxyl	hydroxyl	NOUN
eurjchem-1915	230	26	absorption	absorption	NOUN
eurjchem-1915	230	27	,	,	PUNCT
eurjchem-1915	230	28	∆νoh	∆νoh	NOUN
eurjchem-1915	230	29	=	=	SYM
eurjchem-1915	230	30	10	10	NUM
eurjchem-1915	230	31	cm-1	cm-1	VERB
eurjchem-1915	230	32	when	when	SCONJ
eurjchem-1915	230	33	compared	compare	VERB
eurjchem-1915	230	34	with	with	ADP
eurjchem-1915	230	35	the	the	DET
eurjchem-1915	230	36	ir	ir	PROPN
eurjchem-1915	230	37	of	of	ADP
eurjchem-1915	230	38	compound	compound	NOUN
eurjchem-1915	230	39	6	6	NUM
eurjchem-1915	230	40	,	,	PUNCT
eurjchem-1915	230	41	this	this	DET
eurjchem-1915	230	42	result	result	NOUN
eurjchem-1915	230	43	is	be	AUX
eurjchem-1915	230	44	attributed	attribute	VERB
eurjchem-1915	230	45	to	to	ADP
eurjchem-1915	230	46	the	the	DET
eurjchem-1915	230	47	hydrogen	hydrogen	NOUN
eurjchem-1915	230	48	bonding	bonding	NOUN
eurjchem-1915	230	49	between	between	ADP
eurjchem-1915	230	50	the	the	DET
eurjchem-1915	230	51	carboxylic	carboxylic	ADJ
eurjchem-1915	230	52	groups	group	NOUN
eurjchem-1915	230	53	(	(	PUNCT
eurjchem-1915	230	54	figure	figure	NOUN
eurjchem-1915	230	55	3	3	NUM
eurjchem-1915	230	56	)	)	PUNCT
eurjchem-1915	230	57	.	.	PUNCT
eurjchem-1915	231	1	moreover	moreover	ADV
eurjchem-1915	231	2	,	,	PUNCT
eurjchem-1915	231	3	the	the	DET
eurjchem-1915	231	4	microanalyses	microanalysis	NOUN
eurjchem-1915	231	5	of	of	ADP
eurjchem-1915	231	6	palladium	palladium	NOUN
eurjchem-1915	231	7	in	in	ADP
eurjchem-1915	231	8	compounds	compound	NOUN
eurjchem-1915	231	9	7	7	NUM
eurjchem-1915	231	10	and	and	CCONJ
eurjchem-1915	231	11	8	8	NUM
eurjchem-1915	231	12	were	be	AUX
eurjchem-1915	231	13	determined	determine	VERB
eurjchem-1915	231	14	from	from	ADP
eurjchem-1915	231	15	the	the	DET
eurjchem-1915	231	16	energy	energy	NOUN
eurjchem-1915	231	17	dispersive	dispersive	NOUN
eurjchem-1915	231	18	x	x	NOUN
eurjchem-1915	231	19	-	-	NOUN
eurjchem-1915	231	20	ray	ray	NOUN
eurjchem-1915	231	21	analysis	analysis	NOUN
eurjchem-1915	231	22	(	(	PUNCT
eurjchem-1915	231	23	edx	edx	PROPN
eurjchem-1915	231	24	)	)	PUNCT
eurjchem-1915	231	25	,	,	PUNCT
eurjchem-1915	231	26	which	which	PRON
eurjchem-1915	231	27	is	be	AUX
eurjchem-1915	231	28	a	a	DET
eurjchem-1915	231	29	technique	technique	NOUN
eurjchem-1915	231	30	of	of	ADP
eurjchem-1915	231	31	elemental	elemental	ADJ
eurjchem-1915	231	32	analysis	analysis	NOUN
eurjchem-1915	231	33	associated	associate	VERB
eurjchem-1915	231	34	to	to	PART
eurjchem-1915	231	35	electron	electron	NOUN
eurjchem-1915	231	36	microscopy	microscopy	NOUN
eurjchem-1915	231	37	based	base	VERB
eurjchem-1915	231	38	on	on	ADP
eurjchem-1915	231	39	the	the	DET
eurjchem-1915	231	40	generation	generation	NOUN
eurjchem-1915	231	41	of	of	ADP
eurjchem-1915	231	42	characteristic	characteristic	ADJ
eurjchem-1915	231	43	x	x	NOUN
eurjchem-1915	231	44	-	-	NOUN
eurjchem-1915	231	45	rays	ray	NOUN
eurjchem-1915	231	46	that	that	PRON
eurjchem-1915	231	47	reveals	reveal	VERB
eurjchem-1915	231	48	the	the	DET
eurjchem-1915	231	49	presence	presence	NOUN
eurjchem-1915	231	50	of	of	ADP
eurjchem-1915	231	51	elements	element	NOUN
eurjchem-1915	231	52	present	present	ADJ
eurjchem-1915	231	53	in	in	ADP
eurjchem-1915	231	54	the	the	DET
eurjchem-1915	231	55	samples	sample	NOUN
eurjchem-1915	231	56	.	.	PUNCT
eurjchem-1915	232	1	the	the	DET
eurjchem-1915	232	2	edx	edx	PROPN
eurjchem-1915	232	3	analyses	analysis	NOUN
eurjchem-1915	232	4	of	of	ADP
eurjchem-1915	232	5	compounds	compound	NOUN
eurjchem-1915	232	6	7	7	NUM
eurjchem-1915	232	7	and	and	CCONJ
eurjchem-1915	232	8	8	8	NUM
eurjchem-1915	232	9	exhibited	exhibit	VERB
eurjchem-1915	232	10	the	the	DET
eurjchem-1915	232	11	presence	presence	NOUN
eurjchem-1915	232	12	of	of	ADP
eurjchem-1915	232	13	pd	pd	PROPN
eurjchem-1915	232	14	in	in	ADP
eurjchem-1915	232	15	21.7	21.7	NUM
eurjchem-1915	232	16	and	and	CCONJ
eurjchem-1915	232	17	29.6	29.6	NUM
eurjchem-1915	232	18	%	%	NOUN
eurjchem-1915	232	19	that	that	PRON
eurjchem-1915	232	20	were	be	AUX
eurjchem-1915	232	21	very	very	ADV
eurjchem-1915	232	22	closer	close	ADJ
eurjchem-1915	232	23	to	to	ADP
eurjchem-1915	232	24	the	the	DET
eurjchem-1915	232	25	calculated	calculated	ADJ
eurjchem-1915	232	26	values	value	NOUN
eurjchem-1915	232	27	21.96	21.96	NUM
eurjchem-1915	232	28	and	and	CCONJ
eurjchem-1915	232	29	29.2	29.2	NUM
eurjchem-1915	232	30	%	%	NOUN
eurjchem-1915	232	31	,	,	PUNCT
eurjchem-1915	232	32	respecttively	respecttively	ADV
eurjchem-1915	232	33	,	,	PUNCT
eurjchem-1915	232	34	as	as	SCONJ
eurjchem-1915	232	35	depicted	depict	VERB
eurjchem-1915	232	36	in	in	ADP
eurjchem-1915	232	37	figure	figure	NOUN
eurjchem-1915	232	38	4	4	NUM
eurjchem-1915	232	39	.	.	X
eurjchem-1915	232	40	3.4	3.4	NUM
eurjchem-1915	232	41	.	.	PUNCT
eurjchem-1915	232	42	structure	structure	NOUN
eurjchem-1915	232	43	morphology	morphology	NOUN
eurjchem-1915	232	44	in	in	ADP
eurjchem-1915	232	45	general	general	ADJ
eurjchem-1915	232	46	,	,	PUNCT
eurjchem-1915	232	47	the	the	DET
eurjchem-1915	232	48	change	change	NOUN
eurjchem-1915	232	49	in	in	ADP
eurjchem-1915	232	50	the	the	DET
eurjchem-1915	232	51	surface	surface	NOUN
eurjchem-1915	232	52	morphology	morphology	NOUN
eurjchem-1915	232	53	is	be	AUX
eurjchem-1915	232	54	attributed	attribute	VERB
eurjchem-1915	232	55	to	to	ADP
eurjchem-1915	232	56	the	the	DET
eurjchem-1915	232	57	introduction	introduction	NOUN
eurjchem-1915	232	58	of	of	ADP
eurjchem-1915	232	59	metal	metal	NOUN
eurjchem-1915	232	60	ions	ion	NOUN
eurjchem-1915	232	61	into	into	ADP
eurjchem-1915	232	62	the	the	DET
eurjchem-1915	232	63	matrix	matrix	NOUN
eurjchem-1915	232	64	.	.	PUNCT
eurjchem-1915	233	1	the	the	DET
eurjchem-1915	233	2	mode	mode	NOUN
eurjchem-1915	233	3	of	of	ADP
eurjchem-1915	233	4	chelation	chelation	NOUN
eurjchem-1915	233	5	of	of	ADP
eurjchem-1915	233	6	the	the	DET
eurjchem-1915	233	7	palladium	palladium	NOUN
eurjchem-1915	233	8	ions	ion	NOUN
eurjchem-1915	233	9	within	within	ADP
eurjchem-1915	233	10	the	the	DET
eurjchem-1915	233	11	consecutive	consecutive	ADJ
eurjchem-1915	233	12	layers	layer	NOUN
eurjchem-1915	233	13	of	of	ADP
eurjchem-1915	233	14	the	the	DET
eurjchem-1915	233	15	bis	bis	ADJ
eurjchem-1915	233	16	-	-	ADJ
eurjchem-1915	233	17	pyrazole	pyrazole	ADJ
eurjchem-1915	233	18	-	-	PUNCT
eurjchem-1915	233	19	carboxylic	carboxylic	NOUN
eurjchem-1915	233	20	acid	acid	NOUN
eurjchem-1915	233	21	6	6	NUM
eurjchem-1915	233	22	was	be	AUX
eurjchem-1915	233	23	examined	examine	VERB
eurjchem-1915	233	24	by	by	ADP
eurjchem-1915	233	25	measuring	measure	VERB
eurjchem-1915	233	26	the	the	DET
eurjchem-1915	233	27	sem	sem	NOUN
eurjchem-1915	233	28	of	of	ADP
eurjchem-1915	233	29	the	the	DET
eurjchem-1915	233	30	pd	pd	NOUN
eurjchem-1915	233	31	-	-	PUNCT
eurjchem-1915	233	32	complex	complex	ADJ
eurjchem-1915	233	33	8	8	NUM
eurjchem-1915	233	34	as	as	SCONJ
eurjchem-1915	233	35	outlined	outline	VERB
eurjchem-1915	233	36	in	in	ADP
eurjchem-1915	233	37	figure	figure	NOUN
eurjchem-1915	233	38	5	5	NUM
eurjchem-1915	233	39	.	.	PUNCT
eurjchem-1915	234	1	the	the	DET
eurjchem-1915	234	2	results	result	NOUN
eurjchem-1915	234	3	of	of	ADP
eurjchem-1915	234	4	the	the	DET
eurjchem-1915	234	5	sem	sem	NOUN
eurjchem-1915	234	6	provided	provide	VERB
eurjchem-1915	234	7	consecutive	consecutive	ADJ
eurjchem-1915	234	8	layers	layer	NOUN
eurjchem-1915	234	9	which	which	PRON
eurjchem-1915	234	10	is	be	AUX
eurjchem-1915	234	11	consistent	consistent	ADJ
eurjchem-1915	234	12	with	with	ADP
eurjchem-1915	234	13	pdcl2	pdcl2	NOUN
eurjchem-1915	234	14	-	-	PUNCT
eurjchem-1915	234	15	bipyrazolepdcl2	bipyrazolepdcl2	NOUN
eurjchem-1915	234	16	layers	layer	NOUN
eurjchem-1915	234	17	.	.	PUNCT
eurjchem-1915	235	1	the	the	DET
eurjchem-1915	235	2	morphology	morphology	NOUN
eurjchem-1915	235	3	of	of	ADP
eurjchem-1915	235	4	the	the	DET
eurjchem-1915	235	5	metal	metal	NOUN
eurjchem-1915	235	6	complex	complex	NOUN
eurjchem-1915	235	7	8	8	NUM
eurjchem-1915	235	8	is	be	AUX
eurjchem-1915	235	9	shown	show	VERB
eurjchem-1915	235	10	in	in	ADP
eurjchem-1915	235	11	figure	figure	NOUN
eurjchem-1915	235	12	5	5	NUM
eurjchem-1915	235	13	,	,	PUNCT
eurjchem-1915	235	14	with	with	ADP
eurjchem-1915	235	15	10000	10000	NUM
eurjchem-1915	235	16	and	and	CCONJ
eurjchem-1915	235	17	40000	40000	NUM
eurjchem-1915	235	18	magnifications	magnification	NOUN
eurjchem-1915	235	19	.	.	PUNCT
eurjchem-1915	236	1	heating	heating	NOUN
eurjchem-1915	236	2	of	of	ADP
eurjchem-1915	236	3	3,3`-bipyrazole-5,5`-dicarboxylic	3,3`-bipyrazole-5,5`-dicarboxylic	NUM
eurjchem-1915	236	4	acid	acid	NOUN
eurjchem-1915	236	5	6	6	NUM
eurjchem-1915	236	6	with	with	ADP
eurjchem-1915	236	7	double	double	ADJ
eurjchem-1915	236	8	equivalents	equivalent	NOUN
eurjchem-1915	236	9	of	of	ADP
eurjchem-1915	236	10	urea	urea	NOUN
eurjchem-1915	236	11	led	lead	VERB
eurjchem-1915	236	12	to	to	ADP
eurjchem-1915	236	13	the	the	DET
eurjchem-1915	236	14	formation	formation	NOUN
eurjchem-1915	236	15	of	of	ADP
eurjchem-1915	236	16	the	the	DET
eurjchem-1915	236	17	polybis(3,3`-bi	polybis(3,3`-bi	NOUN
eurjchem-1915	236	18	-	-	PUNCT
eurjchem-1915	236	19	pyrazolylcarbonyl)urea	pyrazolylcarbonyl)urea	NOUN
eurjchem-1915	236	20	derivative	derivative	ADJ
eurjchem-1915	236	21	10	10	NUM
eurjchem-1915	236	22	(	(	PUNCT
eurjchem-1915	236	23	scheme	scheme	NOUN
eurjchem-1915	236	24	3	3	NUM
eurjchem-1915	236	25	)	)	PUNCT
eurjchem-1915	236	26	.	.	PUNCT
eurjchem-1915	237	1	the	the	DET
eurjchem-1915	237	2	structure	structure	NOUN
eurjchem-1915	237	3	of	of	ADP
eurjchem-1915	237	4	the	the	DET
eurjchem-1915	237	5	product	product	NOUN
eurjchem-1915	237	6	10	10	NUM
eurjchem-1915	237	7	was	be	AUX
eurjchem-1915	237	8	formed	form	VERB
eurjchem-1915	237	9	through	through	ADP
eurjchem-1915	237	10	the	the	DET
eurjchem-1915	237	11	intermediate	intermediate	ADJ
eurjchem-1915	237	12	9	9	NUM
eurjchem-1915	237	13	via	via	ADP
eurjchem-1915	237	14	loss	loss	NOUN
eurjchem-1915	237	15	of	of	ADP
eurjchem-1915	237	16	ammonia	ammonia	ADJ
eurjchem-1915	237	17	molecules	molecule	NOUN
eurjchem-1915	237	18	in	in	ADP
eurjchem-1915	237	19	a	a	DET
eurjchem-1915	237	20	step	step	NOUN
eurjchem-1915	237	21	-	-	PUNCT
eurjchem-1915	237	22	type	type	NOUN
eurjchem-1915	237	23	polymerization	polymerization	NOUN
eurjchem-1915	237	24	reaction	reaction	NOUN
eurjchem-1915	237	25	.	.	PUNCT
eurjchem-1915	238	1	comparing	compare	VERB
eurjchem-1915	238	2	with	with	ADP
eurjchem-1915	238	3	its	its	PRON
eurjchem-1915	238	4	carboxylic	carboxylic	ADJ
eurjchem-1915	238	5	acid	acid	NOUN
eurjchem-1915	238	6	precursor	precursor	NOUN
eurjchem-1915	238	7	6	6	NUM
eurjchem-1915	238	8	,	,	PUNCT
eurjchem-1915	238	9	the	the	DET
eurjchem-1915	238	10	ir	ir	PROPN
eurjchem-1915	238	11	spectrum	spectrum	NOUN
eurjchem-1915	238	12	of	of	ADP
eurjchem-1915	238	13	the	the	DET
eurjchem-1915	238	14	polyamide	polyamide	NOUN
eurjchem-1915	238	15	10	10	NUM
eurjchem-1915	238	16	showed	show	VERB
eurjchem-1915	238	17	new	new	ADJ
eurjchem-1915	238	18	broad	broad	ADJ
eurjchem-1915	238	19	bands	band	NOUN
eurjchem-1915	238	20	for	for	ADP
eurjchem-1915	238	21	the	the	DET
eurjchem-1915	238	22	nh	nh	PROPN
eurjchem-1915	238	23	groups	group	NOUN
eurjchem-1915	238	24	at	at	ADP
eurjchem-1915	238	25	3208	3208	NUM
eurjchem-1915	238	26	and	and	CCONJ
eurjchem-1915	238	27	3122	3122	NUM
eurjchem-1915	238	28	cm-1	cm-1	VERB
eurjchem-1915	238	29	in	in	ADP
eurjchem-1915	238	30	addition	addition	NOUN
eurjchem-1915	238	31	to	to	ADP
eurjchem-1915	238	32	,	,	PUNCT
eurjchem-1915	238	33	two	two	NUM
eurjchem-1915	238	34	carbonyl	carbonyl	NOUN
eurjchem-1915	238	35	absorptions	absorption	NOUN
eurjchem-1915	238	36	at	at	ADP
eurjchem-1915	238	37	1726	1726	NUM
eurjchem-1915	238	38	and	and	CCONJ
eurjchem-1915	238	39	1660	1660	NUM
eurjchem-1915	238	40	cm-1	cm-1	NOUN
eurjchem-1915	238	41	.	.	PUNCT
eurjchem-1915	239	1	moreover	moreover	ADV
eurjchem-1915	239	2	,	,	PUNCT
eurjchem-1915	239	3	the	the	DET
eurjchem-1915	239	4	structure	structure	NOUN
eurjchem-1915	239	5	of	of	ADP
eurjchem-1915	239	6	the	the	DET
eurjchem-1915	239	7	polyamide	polyamide	NOUN
eurjchem-1915	239	8	10	10	NUM
eurjchem-1915	239	9	was	be	AUX
eurjchem-1915	239	10	investigated	investigate	VERB
eurjchem-1915	239	11	using	use	VERB
eurjchem-1915	239	12	sem	sem	ADJ
eurjchem-1915	239	13	analysis	analysis	NOUN
eurjchem-1915	239	14	.	.	PUNCT
eurjchem-1915	240	1	the	the	DET
eurjchem-1915	240	2	results	result	NOUN
eurjchem-1915	240	3	of	of	ADP
eurjchem-1915	240	4	sem	sem	NOUN
eurjchem-1915	240	5	provided	provide	VERB
eurjchem-1915	240	6	consecutive	consecutive	ADJ
eurjchem-1915	240	7	layers	layer	NOUN
eurjchem-1915	240	8	which	which	PRON
eurjchem-1915	240	9	is	be	AUX
eurjchem-1915	240	10	consistent	consistent	ADJ
eurjchem-1915	240	11	with	with	ADP
eurjchem-1915	240	12	the	the	DET
eurjchem-1915	240	13	postulated	postulate	VERB
eurjchem-1915	240	14	structure	structure	NOUN
eurjchem-1915	240	15	10	10	NUM
eurjchem-1915	240	16	.	.	PUNCT
eurjchem-1915	241	1	the	the	DET
eurjchem-1915	241	2	morphological	morphological	ADJ
eurjchem-1915	241	3	structure	structure	NOUN
eurjchem-1915	241	4	of	of	ADP
eurjchem-1915	241	5	the	the	DET
eurjchem-1915	241	6	polymeric	polymeric	ADJ
eurjchem-1915	241	7	product	product	NOUN
eurjchem-1915	241	8	10	10	NUM
eurjchem-1915	241	9	is	be	AUX
eurjchem-1915	241	10	shown	show	VERB
eurjchem-1915	241	11	in	in	ADP
eurjchem-1915	241	12	figure	figure	NOUN
eurjchem-1915	241	13	6	6	NUM
eurjchem-1915	241	14	,	,	PUNCT
eurjchem-1915	241	15	with	with	ADP
eurjchem-1915	241	16	10000	10000	NUM
eurjchem-1915	241	17	and	and	CCONJ
eurjchem-1915	241	18	40000	40000	NUM
eurjchem-1915	241	19	magnifications	magnification	NOUN
eurjchem-1915	241	20	.	.	PUNCT
eurjchem-1915	242	1	it	it	PRON
eurjchem-1915	242	2	was	be	AUX
eurjchem-1915	242	3	observed	observe	VERB
eurjchem-1915	242	4	that	that	SCONJ
eurjchem-1915	242	5	the	the	DET
eurjchem-1915	242	6	bipyrazole	bipyrazole	NOUN
eurjchem-1915	242	7	-	-	PUNCT
eurjchem-1915	242	8	based	base	VERB
eurjchem-1915	242	9	polyamide	polyamide	NOUN
eurjchem-1915	242	10	10	10	NUM
eurjchem-1915	242	11	has	have	VERB
eurjchem-1915	242	12	a	a	DET
eurjchem-1915	242	13	high	high	ADJ
eurjchem-1915	242	14	degree	degree	NOUN
eurjchem-1915	242	15	of	of	ADP
eurjchem-1915	242	16	crystallinity	crystallinity	NOUN
eurjchem-1915	242	17	.	.	PUNCT
eurjchem-1915	243	1	2019	2019	NUM
eurjchem-1915	243	2	–	–	PUNCT
eurjchem-1915	243	3	european	european	ADJ
eurjchem-1915	243	4	journal	journal	NOUN
eurjchem-1915	243	5	of	of	ADP
eurjchem-1915	243	6	chemistry	chemistry	NOUN
eurjchem-1915	243	7	–	–	PUNCT
eurjchem-1915	243	8	cc	cc	NOUN
eurjchem-1915	243	9	by	by	ADP
eurjchem-1915	243	10	nc	nc	PROPN
eurjchem-1915	243	11	–	–	PUNCT
eurjchem-1915	243	12	doi	doi	PROPN
eurjchem-1915	243	13	:	:	PUNCT
eurjchem-1915	243	14	10.5155	10.5155	NUM
eurjchem-1915	243	15	/	/	SYM
eurjchem-1915	243	16	eurjchem.10.4.367	eurjchem.10.4.367	NUM
eurjchem-1915	243	17	-	-	SYM
eurjchem-1915	243	18	375.1915	375.1915	NUM
eurjchem-1915	243	19	al	al	PROPN
eurjchem-1915	243	20	-	-	PUNCT
eurjchem-1915	243	21	fulaij	fulaij	PROPN
eurjchem-1915	243	22	et	et	PROPN
eurjchem-1915	243	23	al	al	PROPN
eurjchem-1915	243	24	.	.	PUNCT
eurjchem-1915	243	25	/	/	SYM
eurjchem-1915	243	26	european	european	PROPN
eurjchem-1915	243	27	journal	journal	PROPN
eurjchem-1915	243	28	of	of	ADP
eurjchem-1915	243	29	chemistry	chemistry	NOUN
eurjchem-1915	243	30	10	10	NUM
eurjchem-1915	243	31	(	(	PUNCT
eurjchem-1915	243	32	4	4	NUM
eurjchem-1915	243	33	)	)	PUNCT
eurjchem-1915	243	34	(	(	PUNCT
eurjchem-1915	243	35	2019	2019	NUM
eurjchem-1915	243	36	)	)	PUNCT
eurjchem-1915	243	37	367	367	NUM
eurjchem-1915	243	38	-	-	SYM
eurjchem-1915	243	39	375	375	NUM
eurjchem-1915	243	40	373	373	NUM
eurjchem-1915	243	41	figure	figure	NOUN
eurjchem-1915	243	42	4	4	NUM
eurjchem-1915	243	43	.	.	PUNCT
eurjchem-1915	244	1	edx	edx	NOUN
eurjchem-1915	244	2	of	of	ADP
eurjchem-1915	244	3	compounds	compound	NOUN
eurjchem-1915	244	4	7	7	NUM
eurjchem-1915	244	5	and	and	CCONJ
eurjchem-1915	244	6	8	8	NUM
eurjchem-1915	244	7	(	(	PUNCT
eurjchem-1915	244	8	spectrum	spectrum	NOUN
eurjchem-1915	244	9	9	9	NUM
eurjchem-1915	244	10	represent	represent	VERB
eurjchem-1915	244	11	compound	compound	NOUN
eurjchem-1915	244	12	7	7	NUM
eurjchem-1915	244	13	and	and	CCONJ
eurjchem-1915	244	14	spectrum	spectrum	NOUN
eurjchem-1915	244	15	15	15	NUM
eurjchem-1915	244	16	represent	represent	VERB
eurjchem-1915	244	17	compound	compound	NOUN
eurjchem-1915	244	18	8)	8)	NUM
eurjchem-1915	244	19	.	.	PUNCT
eurjchem-1915	244	20	figure	figure	NOUN
eurjchem-1915	244	21	5	5	NUM
eurjchem-1915	244	22	.	.	PUNCT
eurjchem-1915	244	23	sem	sem	PROPN
eurjchem-1915	244	24	micrograph	micrograph	NOUN
eurjchem-1915	244	25	of	of	ADP
eurjchem-1915	244	26	palladium	palladium	NOUN
eurjchem-1915	244	27	complex	complex	ADJ
eurjchem-1915	244	28	8	8	NUM
eurjchem-1915	244	29	.	.	PUNCT
eurjchem-1915	244	30	figure	figure	NOUN
eurjchem-1915	244	31	6	6	NUM
eurjchem-1915	244	32	.	.	PUNCT
eurjchem-1915	244	33	sem	sem	NOUN
eurjchem-1915	244	34	micrograph	micrograph	NOUN
eurjchem-1915	244	35	of	of	ADP
eurjchem-1915	244	36	the	the	DET
eurjchem-1915	244	37	polyamide	polyamide	NOUN
eurjchem-1915	244	38	product	product	NOUN
eurjchem-1915	244	39	10	10	NUM
eurjchem-1915	244	40	.	.	PUNCT
eurjchem-1915	244	41	3.5	3.5	NUM
eurjchem-1915	244	42	.	.	PUNCT
eurjchem-1915	245	1	catalytic	catalytic	ADJ
eurjchem-1915	245	2	activity	activity	NOUN
eurjchem-1915	245	3	of	of	ADP
eurjchem-1915	245	4	pd	pd	NOUN
eurjchem-1915	245	5	-	-	NOUN
eurjchem-1915	245	6	complex	complex	NOUN
eurjchem-1915	245	7	in	in	ADP
eurjchem-1915	245	8	suzuki	suzuki	PROPN
eurjchem-1915	245	9	crosscoupling	crosscoupling	NOUN
eurjchem-1915	245	10	reactions	reaction	NOUN
eurjchem-1915	245	11	the	the	DET
eurjchem-1915	245	12	palladium	palladium	NOUN
eurjchem-1915	245	13	catalyzed	catalyze	VERB
eurjchem-1915	245	14	suzuki	suzuki	NOUN
eurjchem-1915	245	15	-	-	PUNCT
eurjchem-1915	245	16	miyaura	miyaura	NOUN
eurjchem-1915	245	17	cross	cross	ADJ
eurjchem-1915	245	18	-	-	ADJ
eurjchem-1915	245	19	coupling	coupling	ADJ
eurjchem-1915	245	20	reaction	reaction	NOUN
eurjchem-1915	245	21	represents	represent	VERB
eurjchem-1915	245	22	one	one	NUM
eurjchem-1915	245	23	of	of	ADP
eurjchem-1915	245	24	the	the	DET
eurjchem-1915	245	25	most	most	ADV
eurjchem-1915	245	26	widely	widely	ADV
eurjchem-1915	245	27	and	and	CCONJ
eurjchem-1915	245	28	eco	eco	NOUN
eurjchem-1915	245	29	-	-	PUNCT
eurjchem-1915	245	30	friendly	friendly	ADJ
eurjchem-1915	245	31	method	method	NOUN
eurjchem-1915	245	32	for	for	ADP
eurjchem-1915	245	33	the	the	DET
eurjchem-1915	245	34	construction	construction	NOUN
eurjchem-1915	245	35	of	of	ADP
eurjchem-1915	245	36	carbon	carbon	NOUN
eurjchem-1915	245	37	-	-	PUNCT
eurjchem-1915	245	38	carbon	carbon	NOUN
eurjchem-1915	245	39	bonds	bond	NOUN
eurjchem-1915	245	40	in	in	ADP
eurjchem-1915	245	41	organic	organic	ADJ
eurjchem-1915	245	42	molecules	molecule	NOUN
eurjchem-1915	245	43	[	[	X
eurjchem-1915	245	44	34	34	NUM
eurjchem-1915	245	45	-	-	SYM
eurjchem-1915	245	46	36	36	NUM
eurjchem-1915	245	47	]	]	PUNCT
eurjchem-1915	245	48	.	.	PUNCT
eurjchem-1915	246	1	one	one	NUM
eurjchem-1915	246	2	of	of	ADP
eurjchem-1915	246	3	our	our	PRON
eurjchem-1915	246	4	goals	goal	NOUN
eurjchem-1915	246	5	in	in	ADP
eurjchem-1915	246	6	this	this	DET
eurjchem-1915	246	7	work	work	NOUN
eurjchem-1915	246	8	is	be	AUX
eurjchem-1915	246	9	to	to	PART
eurjchem-1915	246	10	study	study	VERB
eurjchem-1915	246	11	the	the	DET
eurjchem-1915	246	12	catalytic	catalytic	ADJ
eurjchem-1915	246	13	activity	activity	NOUN
eurjchem-1915	246	14	of	of	ADP
eurjchem-1915	246	15	the	the	DET
eurjchem-1915	246	16	prepared	prepared	ADJ
eurjchem-1915	246	17	pd	pd	NOUN
eurjchem-1915	246	18	-	-	PUNCT
eurjchem-1915	246	19	complexes	complex	NOUN
eurjchem-1915	246	20	in	in	ADP
eurjchem-1915	246	21	suzuki	suzuki	PROPN
eurjchem-1915	246	22	cross	cross	PROPN
eurjchem-1915	246	23	-	-	ADJ
eurjchem-1915	246	24	coupling	coupling	ADJ
eurjchem-1915	246	25	reaction	reaction	NOUN
eurjchem-1915	246	26	.	.	PUNCT
eurjchem-1915	247	1	thus	thus	ADV
eurjchem-1915	247	2	,	,	PUNCT
eurjchem-1915	247	3	the	the	DET
eurjchem-1915	247	4	catalytic	catalytic	ADJ
eurjchem-1915	247	5	activity	activity	NOUN
eurjchem-1915	247	6	of	of	ADP
eurjchem-1915	247	7	the	the	DET
eurjchem-1915	247	8	pd(ii	pd(ii	ADJ
eurjchem-1915	247	9	)	)	PUNCT
eurjchem-1915	247	10	complex	complex	ADJ
eurjchem-1915	247	11	8	8	NUM
eurjchem-1915	247	12	in	in	ADP
eurjchem-1915	247	13	the	the	DET
eurjchem-1915	247	14	cross	cross	ADJ
eurjchem-1915	247	15	-	-	ADJ
eurjchem-1915	247	16	coupling	coupling	ADJ
eurjchem-1915	247	17	reaction	reaction	NOUN
eurjchem-1915	247	18	between	between	ADP
eurjchem-1915	247	19	phenylboronic	phenylboronic	ADJ
eurjchem-1915	247	20	acid	acid	NOUN
eurjchem-1915	247	21	(	(	PUNCT
eurjchem-1915	247	22	11	11	NUM
eurjchem-1915	247	23	)	)	PUNCT
eurjchem-1915	247	24	and	and	CCONJ
eurjchem-1915	247	25	4	4	NUM
eurjchem-1915	247	26	-	-	NUM
eurjchem-1915	247	27	bromoacetophenone	bromoacetophenone	NOUN
eurjchem-1915	247	28	(	(	PUNCT
eurjchem-1915	247	29	12	12	NUM
eurjchem-1915	247	30	)	)	PUNCT
eurjchem-1915	247	31	was	be	AUX
eurjchem-1915	247	32	examined	examine	VERB
eurjchem-1915	247	33	and	and	CCONJ
eurjchem-1915	247	34	the	the	DET
eurjchem-1915	247	35	results	result	NOUN
eurjchem-1915	247	36	are	be	AUX
eurjchem-1915	247	37	shown	show	VERB
eurjchem-1915	247	38	in	in	ADP
eurjchem-1915	247	39	table	table	NOUN
eurjchem-1915	247	40	4	4	NUM
eurjchem-1915	247	41	.	.	PUNCT
eurjchem-1915	248	1	the	the	DET
eurjchem-1915	248	2	reaction	reaction	NOUN
eurjchem-1915	248	3	was	be	AUX
eurjchem-1915	248	4	conducted	conduct	VERB
eurjchem-1915	248	5	in	in	ADP
eurjchem-1915	248	6	water	water	NOUN
eurjchem-1915	248	7	(	(	PUNCT
eurjchem-1915	248	8	3	3	NUM
eurjchem-1915	248	9	ml	ml	NOUN
eurjchem-1915	248	10	)	)	PUNCT
eurjchem-1915	248	11	at	at	ADP
eurjchem-1915	248	12	100	100	NUM
eurjchem-1915	248	13	°	°	ADP
eurjchem-1915	248	14	c	c	NOUN
eurjchem-1915	248	15	using	use	VERB
eurjchem-1915	248	16	1	1	NUM
eurjchem-1915	248	17	mol%	mol%	NOUN
eurjchem-1915	248	18	of	of	ADP
eurjchem-1915	248	19	the	the	DET
eurjchem-1915	248	20	pd(ii	pd(ii	ADJ
eurjchem-1915	248	21	)	)	PUNCT
eurjchem-1915	248	22	complex	complex	ADJ
eurjchem-1915	248	23	8	8	NUM
eurjchem-1915	248	24	with	with	ADP
eurjchem-1915	248	25	1	1	NUM
eurjchem-1915	248	26	mmol	mmol	NOUN
eurjchem-1915	248	27	4	4	NUM
eurjchem-1915	248	28	-	-	NUM
eurjchem-1915	248	29	bromoacetophenone	bromoacetophenone	NOUN
eurjchem-1915	248	30	(	(	PUNCT
eurjchem-1915	248	31	12	12	NUM
eurjchem-1915	248	32	)	)	PUNCT
eurjchem-1915	248	33	,	,	PUNCT
eurjchem-1915	248	34	1.2	1.2	NUM
eurjchem-1915	248	35	mmol	mmol	NOUN
eurjchem-1915	248	36	phenylboronic	phenylboronic	ADJ
eurjchem-1915	248	37	acid	acid	NOUN
eurjchem-1915	248	38	(	(	PUNCT
eurjchem-1915	248	39	11	11	NUM
eurjchem-1915	248	40	)	)	PUNCT
eurjchem-1915	248	41	,	,	PUNCT
eurjchem-1915	248	42	0.6	0.6	NUM
eurjchem-1915	248	43	mmol	mmol	NOUN
eurjchem-1915	248	44	tbab	tbab	NOUN
eurjchem-1915	248	45	and	and	CCONJ
eurjchem-1915	248	46	2	2	NUM
eurjchem-1915	248	47	mmoles	mmole	NOUN
eurjchem-1915	248	48	of	of	ADP
eurjchem-1915	248	49	potassium	potassium	NOUN
eurjchem-1915	248	50	hydroxide	hydroxide	NOUN
eurjchem-1915	248	51	.	.	PUNCT
eurjchem-1915	249	1	tlc	tlc	NOUN
eurjchem-1915	249	2	of	of	ADP
eurjchem-1915	249	3	the	the	DET
eurjchem-1915	249	4	reaction	reaction	NOUN
eurjchem-1915	249	5	mixture	mixture	NOUN
eurjchem-1915	249	6	showed	show	VERB
eurjchem-1915	249	7	that	that	SCONJ
eurjchem-1915	249	8	4	4	NUM
eurjchem-1915	249	9	-	-	NUM
eurjchem-1915	249	10	bromoacetophenone	bromoacetophenone	NOUN
eurjchem-1915	249	11	(	(	PUNCT
eurjchem-1915	249	12	12	12	NUM
eurjchem-1915	249	13	)	)	PUNCT
eurjchem-1915	249	14	was	be	AUX
eurjchem-1915	249	15	completely	completely	ADV
eurjchem-1915	249	16	consumed	consume	VERB
eurjchem-1915	249	17	after	after	SCONJ
eurjchem-1915	249	18	45	45	NUM
eurjchem-1915	249	19	min	min	NOUN
eurjchem-1915	249	20	of	of	ADP
eurjchem-1915	249	21	heating	heating	NOUN
eurjchem-1915	249	22	and	and	CCONJ
eurjchem-1915	249	23	the	the	DET
eurjchem-1915	249	24	product	product	NOUN
eurjchem-1915	249	25	4	4	NUM
eurjchem-1915	249	26	-	-	NOUN
eurjchem-1915	249	27	acetylbiphenyl	acetylbiphenyl	NOUN
eurjchem-1915	249	28	(	(	PUNCT
eurjchem-1915	249	29	18	18	NUM
eurjchem-1915	249	30	)	)	PUNCT
eurjchem-1915	249	31	was	be	AUX
eurjchem-1915	249	32	isolated	isolate	VERB
eurjchem-1915	249	33	in	in	ADP
eurjchem-1915	249	34	90	90	NUM
eurjchem-1915	249	35	%	%	NOUN
eurjchem-1915	249	36	yield	yield	NOUN
eurjchem-1915	249	37	.	.	PUNCT
eurjchem-1915	250	1	next	next	ADV
eurjchem-1915	250	2	,	,	PUNCT
eurjchem-1915	250	3	the	the	DET
eurjchem-1915	250	4	utility	utility	NOUN
eurjchem-1915	250	5	of	of	ADP
eurjchem-1915	250	6	pd	pd	NOUN
eurjchem-1915	250	7	-	-	PUNCT
eurjchem-1915	250	8	complex	complex	ADJ
eurjchem-1915	250	9	8	8	NUM
eurjchem-1915	250	10	in	in	ADP
eurjchem-1915	250	11	suzuki	suzuki	NOUN
eurjchem-1915	250	12	-	-	PUNCT
eurjchem-1915	250	13	miyaura	miyaura	NOUN
eurjchem-1915	250	14	cross	cross	ADJ
eurjchem-1915	250	15	-	-	ADJ
eurjchem-1915	250	16	coupling	coupling	ADJ
eurjchem-1915	250	17	reactions	reaction	NOUN
eurjchem-1915	250	18	of	of	ADP
eurjchem-1915	250	19	further	further	ADJ
eurjchem-1915	250	20	aryl	aryl	NOUN
eurjchem-1915	250	21	and	and	CCONJ
eurjchem-1915	250	22	heteroaryl	heteroaryl	NOUN
eurjchem-1915	250	23	bromides	bromide	NOUN
eurjchem-1915	250	24	under	under	ADP
eurjchem-1915	250	25	the	the	DET
eurjchem-1915	250	26	above	above	ADJ
eurjchem-1915	250	27	condition	condition	NOUN
eurjchem-1915	250	28	was	be	AUX
eurjchem-1915	250	29	also	also	ADV
eurjchem-1915	250	30	conducted	conduct	VERB
eurjchem-1915	250	31	.	.	PUNCT
eurjchem-1915	251	1	thus	thus	ADV
eurjchem-1915	251	2	,	,	PUNCT
eurjchem-1915	251	3	suzuki	suzuki	PROPN
eurjchem-1915	251	4	coupling	coupling	NOUN
eurjchem-1915	251	5	of	of	ADP
eurjchem-1915	251	6	the	the	DET
eurjchem-1915	251	7	activated	activate	VERB
eurjchem-1915	251	8	aryl	aryl	NOUN
eurjchem-1915	251	9	bromides	bromide	NOUN
eurjchem-1915	251	10	13	13	NUM
eurjchem-1915	251	11	,	,	PUNCT
eurjchem-1915	251	12	14	14	NUM
eurjchem-1915	251	13	,	,	PUNCT
eurjchem-1915	251	14	15	15	NUM
eurjchem-1915	251	15	and	and	CCONJ
eurjchem-1915	251	16	16	16	NUM
eurjchem-1915	251	17	with	with	ADP
eurjchem-1915	251	18	phenylboronic	phenylboronic	ADJ
eurjchem-1915	251	19	acid	acid	NOUN
eurjchem-1915	251	20	11	11	NUM
eurjchem-1915	251	21	resulted	result	VERB
eurjchem-1915	251	22	in	in	ADP
eurjchem-1915	251	23	the	the	DET
eurjchem-1915	251	24	formation	formation	NOUN
eurjchem-1915	251	25	of	of	ADP
eurjchem-1915	251	26	the	the	DET
eurjchem-1915	251	27	corresponding	corresponding	ADJ
eurjchem-1915	251	28	cross	cross	NOUN
eurjchem-1915	251	29	-	-	ADJ
eurjchem-1915	251	30	coupled	couple	VERB
eurjchem-1915	251	31	products	product	NOUN
eurjchem-1915	251	32	19	19	NUM
eurjchem-1915	251	33	,	,	PUNCT
eurjchem-1915	251	34	20	20	NUM
eurjchem-1915	251	35	,	,	PUNCT
eurjchem-1915	251	36	21	21	NUM
eurjchem-1915	251	37	and	and	CCONJ
eurjchem-1915	251	38	22	22	NUM
eurjchem-1915	251	39	,	,	PUNCT
eurjchem-1915	251	40	respectively	respectively	ADV
eurjchem-1915	251	41	in	in	ADP
eurjchem-1915	251	42	excellent	excellent	ADJ
eurjchem-1915	251	43	isolated	isolated	ADJ
eurjchem-1915	251	44	yields	yield	NOUN
eurjchem-1915	251	45	as	as	SCONJ
eurjchem-1915	251	46	shown	show	VERB
eurjchem-1915	251	47	in	in	ADP
eurjchem-1915	251	48	table	table	NOUN
eurjchem-1915	251	49	4	4	NUM
eurjchem-1915	251	50	.	.	PUNCT
eurjchem-1915	252	1	cross	cross	NOUN
eurjchem-1915	252	2	-	-	ADJ
eurjchem-1915	252	3	coupling	coupling	NOUN
eurjchem-1915	252	4	of	of	ADP
eurjchem-1915	252	5	the	the	DET
eurjchem-1915	252	6	5	5	NUM
eurjchem-1915	252	7	-	-	PUNCT
eurjchem-1915	252	8	bromo	bromo	NOUN
eurjchem-1915	252	9	pyridine-3	pyridine-3	NUM
eurjchem-1915	252	10	-	-	ADJ
eurjchem-1915	252	11	carbonitrile	carbonitrile	ADJ
eurjchem-1915	252	12	derivative	derivative	ADJ
eurjchem-1915	252	13	17	17	NUM
eurjchem-1915	253	1	[	[	X
eurjchem-1915	253	2	37	37	NUM
eurjchem-1915	253	3	]	]	PUNCT
eurjchem-1915	253	4	with	with	ADP
eurjchem-1915	253	5	phenylboronic	phenylboronic	ADJ
eurjchem-1915	253	6	acid	acid	NOUN
eurjchem-1915	253	7	11	11	NUM
eurjchem-1915	253	8	in	in	ADP
eurjchem-1915	253	9	water	water	NOUN
eurjchem-1915	253	10	using	use	VERB
eurjchem-1915	253	11	pd	pd	NOUN
eurjchem-1915	253	12	-	-	PUNCT
eurjchem-1915	253	13	complex	complex	ADJ
eurjchem-1915	253	14	8	8	NUM
eurjchem-1915	253	15	(	(	PUNCT
eurjchem-1915	253	16	1	1	NUM
eurjchem-1915	253	17	mol%	mol%	NOUN
eurjchem-1915	253	18	)	)	PUNCT
eurjchem-1915	253	19	afforded	afford	VERB
eurjchem-1915	253	20	the	the	DET
eurjchem-1915	253	21	5phenylpyridine-3	5phenylpyridine-3	NUM
eurjchem-1915	253	22	-	-	PUNCT
eurjchem-1915	253	23	carbonitrile	carbonitrile	NOUN
eurjchem-1915	253	24	derivative	derivative	ADJ
eurjchem-1915	253	25	23	23	NUM
eurjchem-1915	253	26	,	,	PUNCT
eurjchem-1915	253	27	to	to	ADP
eurjchem-1915	253	28	the	the	DET
eurjchem-1915	253	29	best	good	ADJ
eurjchem-1915	253	30	of	of	ADP
eurjchem-1915	253	31	our	our	PRON
eurjchem-1915	253	32	knowledge	knowledge	NOUN
eurjchem-1915	253	33	,	,	PUNCT
eurjchem-1915	253	34	this	this	PRON
eurjchem-1915	253	35	is	be	AUX
eurjchem-1915	253	36	the	the	DET
eurjchem-1915	253	37	first	first	ADJ
eurjchem-1915	253	38	preparing	prepare	VERB
eurjchem-1915	253	39	by	by	ADP
eurjchem-1915	253	40	suzuki	suzuki	NOUN
eurjchem-1915	253	41	-	-	PUNCT
eurjchem-1915	253	42	miyaura	miyaura	NOUN
eurjchem-1915	253	43	crosscoupling	crosscoupling	NOUN
eurjchem-1915	253	44	reaction	reaction	NOUN
eurjchem-1915	253	45	,	,	PUNCT
eurjchem-1915	253	46	(	(	PUNCT
eurjchem-1915	253	47	run	run	VERB
eurjchem-1915	253	48	6	6	NUM
eurjchem-1915	253	49	,	,	PUNCT
eurjchem-1915	253	50	table	table	NOUN
eurjchem-1915	253	51	4	4	NUM
eurjchem-1915	253	52	)	)	PUNCT
eurjchem-1915	253	53	.	.	PUNCT
eurjchem-1915	254	1	the	the	DET
eurjchem-1915	254	2	identities	identity	NOUN
eurjchem-1915	254	3	of	of	ADP
eurjchem-1915	254	4	the	the	DET
eurjchem-1915	254	5	crosscoupled	crosscouple	VERB
eurjchem-1915	254	6	products	product	NOUN
eurjchem-1915	254	7	were	be	AUX
eurjchem-1915	254	8	confirmed	confirm	VERB
eurjchem-1915	254	9	by	by	ADP
eurjchem-1915	254	10	hrms	hrm	NOUN
eurjchem-1915	254	11	,	,	PUNCT
eurjchem-1915	254	12	1h	1h	NUM
eurjchem-1915	254	13	and	and	CCONJ
eurjchem-1915	254	14	13c	13c	NOUN
eurjchem-1915	254	15	nmr	nmr	NOUN
eurjchem-1915	254	16	spectra	spectra	NOUN
eurjchem-1915	254	17	.	.	PUNCT
eurjchem-1915	255	1	in	in	ADP
eurjchem-1915	255	2	similar	similar	ADJ
eurjchem-1915	255	3	manner	manner	NOUN
eurjchem-1915	255	4	,	,	PUNCT
eurjchem-1915	255	5	the	the	DET
eurjchem-1915	255	6	catalytic	catalytic	ADJ
eurjchem-1915	255	7	activity	activity	NOUN
eurjchem-1915	255	8	of	of	ADP
eurjchem-1915	255	9	pd	pd	NOUN
eurjchem-1915	255	10	-	-	PUNCT
eurjchem-1915	255	11	complex	complex	ADJ
eurjchem-1915	255	12	7	7	NUM
eurjchem-1915	255	13	was	be	AUX
eurjchem-1915	255	14	investigated	investigate	VERB
eurjchem-1915	255	15	(	(	PUNCT
eurjchem-1915	255	16	table	table	NOUN
eurjchem-1915	255	17	5	5	NUM
eurjchem-1915	255	18	)	)	PUNCT
eurjchem-1915	255	19	.	.	PUNCT
eurjchem-1915	256	1	thus	thus	ADV
eurjchem-1915	256	2	,	,	PUNCT
eurjchem-1915	256	3	suzuki	suzuki	PROPN
eurjchem-1915	256	4	coupling	coupling	NOUN
eurjchem-1915	256	5	of	of	ADP
eurjchem-1915	256	6	the	the	DET
eurjchem-1915	256	7	activated	activate	VERB
eurjchem-1915	256	8	aryl	aryl	NOUN
eurjchem-1915	256	9	bromides	bromide	NOUN
eurjchem-1915	256	10	12	12	NUM
eurjchem-1915	256	11	-	-	SYM
eurjchem-1915	256	12	16	16	NUM
eurjchem-1915	256	13	with	with	ADP
eurjchem-1915	256	14	phenylboronic	phenylboronic	ADJ
eurjchem-1915	256	15	acid	acid	NOUN
eurjchem-1915	256	16	11	11	NUM
eurjchem-1915	256	17	resulted	result	VERB
eurjchem-1915	256	18	in	in	ADP
eurjchem-1915	256	19	the	the	DET
eurjchem-1915	256	20	formation	formation	NOUN
eurjchem-1915	256	21	of	of	ADP
eurjchem-1915	256	22	the	the	DET
eurjchem-1915	256	23	corresponding	corresponding	ADJ
eurjchem-1915	256	24	cross	cross	ADJ
eurjchem-1915	256	25	-	-	ADJ
eurjchem-1915	256	26	coupled	couple	VERB
eurjchem-1915	256	27	products	product	NOUN
eurjchem-1915	256	28	1822	1822	NUM
eurjchem-1915	256	29	in	in	ADP
eurjchem-1915	256	30	excellent	excellent	ADJ
eurjchem-1915	256	31	isolated	isolated	ADJ
eurjchem-1915	256	32	yields	yield	NOUN
eurjchem-1915	256	33	as	as	SCONJ
eurjchem-1915	256	34	shown	show	VERB
eurjchem-1915	256	35	in	in	ADP
eurjchem-1915	256	36	table	table	NOUN
eurjchem-1915	256	37	5	5	NUM
eurjchem-1915	256	38	.	.	NOUN
eurjchem-1915	256	39	2019	2019	NUM
eurjchem-1915	256	40	–	–	PUNCT
eurjchem-1915	256	41	european	european	ADJ
eurjchem-1915	256	42	journal	journal	NOUN
eurjchem-1915	256	43	of	of	ADP
eurjchem-1915	256	44	chemistry	chemistry	NOUN
eurjchem-1915	256	45	–	–	PUNCT
eurjchem-1915	256	46	cc	cc	NOUN
eurjchem-1915	256	47	by	by	ADP
eurjchem-1915	256	48	nc	nc	PROPN
eurjchem-1915	256	49	–	–	PUNCT
eurjchem-1915	256	50	doi	doi	PROPN
eurjchem-1915	256	51	:	:	PUNCT
eurjchem-1915	256	52	10.5155	10.5155	NUM
eurjchem-1915	256	53	/	/	SYM
eurjchem-1915	256	54	eurjchem.10.4.367	eurjchem.10.4.367	NOUN
eurjchem-1915	256	55	-	-	SYM
eurjchem-1915	256	56	375.1915	375.1915	NUM
eurjchem-1915	256	57	374	374	NUM
eurjchem-1915	256	58	al	al	PROPN
eurjchem-1915	256	59	-	-	PUNCT
eurjchem-1915	256	60	fulaij	fulaij	PROPN
eurjchem-1915	256	61	et	et	PROPN
eurjchem-1915	256	62	al	al	PROPN
eurjchem-1915	256	63	.	.	PUNCT
eurjchem-1915	256	64	/	/	SYM
eurjchem-1915	256	65	european	european	PROPN
eurjchem-1915	256	66	journal	journal	PROPN
eurjchem-1915	256	67	of	of	ADP
eurjchem-1915	256	68	chemistry	chemistry	NOUN
eurjchem-1915	256	69	10	10	NUM
eurjchem-1915	256	70	(	(	PUNCT
eurjchem-1915	256	71	4	4	NUM
eurjchem-1915	256	72	)	)	PUNCT
eurjchem-1915	256	73	(	(	PUNCT
eurjchem-1915	256	74	2019	2019	NUM
eurjchem-1915	256	75	)	)	PUNCT
eurjchem-1915	256	76	367	367	NUM
eurjchem-1915	256	77	-	-	SYM
eurjchem-1915	256	78	375	375	NUM
eurjchem-1915	256	79	table	table	NOUN
eurjchem-1915	256	80	4	4	NUM
eurjchem-1915	256	81	.	.	PUNCT
eurjchem-1915	256	82	suzuki	suzuki	PROPN
eurjchem-1915	256	83	coupling	coupling	NOUN
eurjchem-1915	256	84	of	of	ADP
eurjchem-1915	256	85	aryl	aryl	NOUN
eurjchem-1915	256	86	bromides	bromide	NOUN
eurjchem-1915	256	87	with	with	ADP
eurjchem-1915	256	88	phenylboronic	phenylboronic	ADJ
eurjchem-1915	256	89	acid	acid	NOUN
eurjchem-1915	256	90	in	in	ADP
eurjchem-1915	256	91	water	water	NOUN
eurjchem-1915	256	92	.	.	PUNCT
eurjchem-1915	257	1	1	1	NUM
eurjchem-1915	257	2	mol%	mol%	PROPN
eurjchem-1915	257	3	cat	cat	NOUN
eurjchem-1915	257	4	.	.	PUNCT
eurjchem-1915	257	5	8	8	NUM
eurjchem-1915	257	6	or	or	CCONJ
eurjchem-1915	257	7	7	7	NUM
eurjchem-1915	257	8	,	,	PUNCT
eurjchem-1915	257	9	h2o	h2o	PROPN
eurjchem-1915	257	10	tbab	tbab	PROPN
eurjchem-1915	257	11	,	,	PUNCT
eurjchem-1915	257	12	koh	koh	PROPN
eurjchem-1915	257	13	,	,	PUNCT
eurjchem-1915	257	14	100	100	NUM
eurjchem-1915	257	15	oc	oc	PART
eurjchem-1915	257	16	11	11	NUM
eurjchem-1915	257	17	18	18	NUM
eurjchem-1915	257	18	-	-	SYM
eurjchem-1915	257	19	23	23	NUM
eurjchem-1915	257	20	ar(het)-br	ar(het)-br	NUM
eurjchem-1915	257	21	12	12	NUM
eurjchem-1915	257	22	-	-	SYM
eurjchem-1915	257	23	17	17	NUM
eurjchem-1915	257	24	b(oh)2	b(oh)2	NOUN
eurjchem-1915	257	25	+	+	CCONJ
eurjchem-1915	257	26	ar(het	ar(het	ADJ
eurjchem-1915	257	27	)	)	PUNCT
eurjchem-1915	257	28	run	run	NOUN
eurjchem-1915	257	29	ar	ar	PROPN
eurjchem-1915	257	30	(	(	PUNCT
eurjchem-1915	257	31	het)-br	het)-br	ADV
eurjchem-1915	257	32	product	product	NOUN
eurjchem-1915	257	33	time	time	NOUN
eurjchem-1915	257	34	(	(	PUNCT
eurjchem-1915	257	35	min	min	NOUN
eurjchem-1915	257	36	)	)	PUNCT
eurjchem-1915	257	37	yield	yield	NOUN
eurjchem-1915	257	38	%	%	NOUN
eurjchem-1915	257	39	a	a	DET
eurjchem-1915	257	40	1	1	NUM
eurjchem-1915	257	41	br	br	NOUN
eurjchem-1915	257	42	o	o	NOUN
eurjchem-1915	257	43	12	12	NUM
eurjchem-1915	257	44	o	o	NOUN
eurjchem-1915	257	45	18	18	NUM
eurjchem-1915	257	46	45	45	NUM
eurjchem-1915	257	47	90	90	NUM
eurjchem-1915	257	48	2	2	NUM
eurjchem-1915	257	49	nc	nc	PROPN
eurjchem-1915	257	50	br	br	PROPN
eurjchem-1915	257	51	13	13	NUM
eurjchem-1915	257	52	nc	nc	PROPN
eurjchem-1915	257	53	19	19	NUM
eurjchem-1915	257	54	45	45	NUM
eurjchem-1915	257	55	91	91	NUM
eurjchem-1915	257	56	3	3	NUM
eurjchem-1915	257	57	bro2n	bro2n	NOUN
eurjchem-1915	257	58	14	14	NUM
eurjchem-1915	257	59	o2n	o2n	NOUN
eurjchem-1915	257	60	20	20	NUM
eurjchem-1915	257	61	45	45	NUM
eurjchem-1915	257	62	92	92	NUM
eurjchem-1915	257	63	4	4	NUM
eurjchem-1915	257	64	ho	ho	NOUN
eurjchem-1915	257	65	br	br	ADP
eurjchem-1915	257	66	15	15	NUM
eurjchem-1915	258	1	oh	oh	NUM
eurjchem-1915	258	2	21	21	NUM
eurjchem-1915	258	3	60	60	NUM
eurjchem-1915	258	4	91	91	NUM
eurjchem-1915	258	5	5	5	NUM
eurjchem-1915	258	6	h3cochn	h3cochn	NUM
eurjchem-1915	258	7	br	br	NOUN
eurjchem-1915	258	8	16	16	NUM
eurjchem-1915	258	9	h3cochn	h3cochn	NUM
eurjchem-1915	258	10	22	22	NUM
eurjchem-1915	258	11	60	60	NUM
eurjchem-1915	258	12	85	85	NUM
eurjchem-1915	258	13	6	6	NUM
eurjchem-1915	258	14	n	n	NUM
eurjchem-1915	258	15	h	h	NOUN
eurjchem-1915	258	16	cn	cn	INTJ
eurjchem-1915	258	17	me	i	PRON
eurjchem-1915	258	18	me	i	PRON
eurjchem-1915	258	19	o	o	INTJ
eurjchem-1915	258	20	br	br	NOUN
eurjchem-1915	258	21	17	17	NUM
eurjchem-1915	259	1	n	n	DET
eurjchem-1915	259	2	h	h	NOUN
eurjchem-1915	259	3	cn	cn	INTJ
eurjchem-1915	259	4	me	i	PRON
eurjchem-1915	259	5	me	i	PRON
eurjchem-1915	259	6	o	o	NOUN
eurjchem-1915	259	7	23	23	NUM
eurjchem-1915	259	8	45	45	NUM
eurjchem-1915	259	9	88	88	NUM
eurjchem-1915	259	10	a	a	DET
eurjchem-1915	259	11	reaction	reaction	NOUN
eurjchem-1915	259	12	conditions	condition	NOUN
eurjchem-1915	259	13	:	:	PUNCT
eurjchem-1915	259	14	bromide	bromide	NOUN
eurjchem-1915	259	15	/	/	SYM
eurjchem-1915	259	16	boronic	boronic	ADJ
eurjchem-1915	259	17	acid	acid	NOUN
eurjchem-1915	259	18	/	/	SYM
eurjchem-1915	259	19	koh	koh	PROPN
eurjchem-1915	259	20	/	/	SYM
eurjchem-1915	259	21	tbab	tbab	PROPN
eurjchem-1915	259	22	/	/	SYM
eurjchem-1915	259	23	water	water	NOUN
eurjchem-1915	259	24	:	:	PUNCT
eurjchem-1915	259	25	1.0/1.2/2.0/0.6/3.0	1.0/1.2/2.0/0.6/3.0	NUM
eurjchem-1915	259	26	ml	ml	NOUN
eurjchem-1915	259	27	at	at	ADP
eurjchem-1915	259	28	100	100	NUM
eurjchem-1915	259	29	°	°	NOUN
eurjchem-1915	259	30	c	c	NOUN
eurjchem-1915	259	31	temperature	temperature	NOUN
eurjchem-1915	259	32	.	.	PUNCT
eurjchem-1915	260	1	all	all	DET
eurjchem-1915	260	2	values	value	NOUN
eurjchem-1915	260	3	refer	refer	VERB
eurjchem-1915	260	4	to	to	ADP
eurjchem-1915	260	5	the	the	DET
eurjchem-1915	260	6	isolated	isolate	VERB
eurjchem-1915	260	7	yields	yield	NOUN
eurjchem-1915	260	8	.	.	PUNCT
eurjchem-1915	261	1	table	table	NOUN
eurjchem-1915	261	2	5	5	NUM
eurjchem-1915	261	3	.	.	PUNCT
eurjchem-1915	261	4	suzuki	suzuki	PROPN
eurjchem-1915	261	5	coupling	coupling	NOUN
eurjchem-1915	261	6	of	of	ADP
eurjchem-1915	261	7	aryl	aryl	NOUN
eurjchem-1915	261	8	bromides	bromide	NOUN
eurjchem-1915	261	9	with	with	ADP
eurjchem-1915	261	10	phenylboronic	phenylboronic	ADJ
eurjchem-1915	261	11	acid	acid	NOUN
eurjchem-1915	261	12	in	in	ADP
eurjchem-1915	261	13	water	water	NOUN
eurjchem-1915	261	14	using	use	VERB
eurjchem-1915	261	15	pd	pd	NOUN
eurjchem-1915	261	16	-	-	NOUN
eurjchem-1915	261	17	complex	complex	ADJ
eurjchem-1915	261	18	7	7	NUM
eurjchem-1915	261	19	as	as	ADP
eurjchem-1915	261	20	a	a	DET
eurjchem-1915	261	21	catalyst	catalyst	NOUN
eurjchem-1915	261	22	.	.	PUNCT
eurjchem-1915	262	1	run	run	VERB
eurjchem-1915	262	2	ar	ar	PROPN
eurjchem-1915	262	3	(	(	PUNCT
eurjchem-1915	262	4	het)-br	het)-br	ADV
eurjchem-1915	262	5	product	product	NOUN
eurjchem-1915	262	6	time	time	NOUN
eurjchem-1915	262	7	(	(	PUNCT
eurjchem-1915	262	8	min	min	NOUN
eurjchem-1915	262	9	)	)	PUNCT
eurjchem-1915	262	10	yield	yield	NOUN
eurjchem-1915	262	11	(	(	PUNCT
eurjchem-1915	262	12	%	%	NOUN
eurjchem-1915	262	13	)	)	PUNCT
eurjchem-1915	262	14	1	1	NUM
eurjchem-1915	262	15	12	12	NUM
eurjchem-1915	262	16	18	18	NUM
eurjchem-1915	262	17	45	45	NUM
eurjchem-1915	262	18	91	91	NUM
eurjchem-1915	262	19	2	2	NUM
eurjchem-1915	262	20	13	13	NUM
eurjchem-1915	262	21	19	19	NUM
eurjchem-1915	262	22	45	45	NUM
eurjchem-1915	262	23	90	90	NUM
eurjchem-1915	262	24	3	3	NUM
eurjchem-1915	262	25	14	14	NUM
eurjchem-1915	262	26	20	20	NUM
eurjchem-1915	262	27	45	45	NUM
eurjchem-1915	262	28	94	94	NUM
eurjchem-1915	262	29	4	4	NUM
eurjchem-1915	262	30	15	15	NUM
eurjchem-1915	262	31	21	21	NUM
eurjchem-1915	262	32	60	60	NUM
eurjchem-1915	262	33	90	90	NUM
eurjchem-1915	262	34	5	5	NUM
eurjchem-1915	262	35	16	16	NUM
eurjchem-1915	262	36	22	22	NUM
eurjchem-1915	262	37	60	60	NUM
eurjchem-1915	262	38	85	85	NUM
eurjchem-1915	262	39	6	6	NUM
eurjchem-1915	262	40	17	17	NUM
eurjchem-1915	262	41	23	23	NUM
eurjchem-1915	262	42	45	45	NUM
eurjchem-1915	262	43	91	91	NUM
eurjchem-1915	262	44	table	table	NOUN
eurjchem-1915	262	45	6	6	NUM
eurjchem-1915	262	46	.	.	PUNCT
eurjchem-1915	263	1	the	the	DET
eurjchem-1915	263	2	comparison	comparison	NOUN
eurjchem-1915	263	3	of	of	ADP
eurjchem-1915	263	4	the	the	DET
eurjchem-1915	263	5	data	datum	NOUN
eurjchem-1915	263	6	obtained	obtain	VERB
eurjchem-1915	263	7	by	by	ADP
eurjchem-1915	263	8	pd	pd	NOUN
eurjchem-1915	263	9	-	-	PUNCT
eurjchem-1915	263	10	complex	complex	ADJ
eurjchem-1915	263	11	7	7	NUM
eurjchem-1915	263	12	and	and	CCONJ
eurjchem-1915	263	13	8	8	NUM
eurjchem-1915	263	14	with	with	ADP
eurjchem-1915	263	15	that	that	PRON
eurjchem-1915	263	16	reported	report	VERB
eurjchem-1915	263	17	in	in	ADP
eurjchem-1915	263	18	literature	literature	NOUN
eurjchem-1915	263	19	.	.	PUNCT
eurjchem-1915	264	1	compound	compound	NOUN
eurjchem-1915	264	2	time	time	NOUN
eurjchem-1915	264	3	(	(	PUNCT
eurjchem-1915	264	4	min	min	NOUN
eurjchem-1915	264	5	)	)	PUNCT
eurjchem-1915	264	6	yield	yield	NOUN
eurjchem-1915	264	7	(	(	PUNCT
eurjchem-1915	264	8	%	%	INTJ
eurjchem-1915	264	9	)	)	PUNCT
eurjchem-1915	264	10	comment	comment	NOUN
eurjchem-1915	264	11	or	or	CCONJ
eurjchem-1915	264	12	reference	reference	NOUN
eurjchem-1915	264	13	18	18	NUM
eurjchem-1915	264	14	1140	1140	NUM
eurjchem-1915	264	15	96	96	NUM
eurjchem-1915	264	16	reference	reference	NOUN
eurjchem-1915	264	17	28	28	NUM
eurjchem-1915	264	18	45	45	NUM
eurjchem-1915	264	19	90	90	NUM
eurjchem-1915	264	20	catalyst	catalyst	NOUN
eurjchem-1915	264	21	used	use	VERB
eurjchem-1915	264	22	:	:	PUNCT
eurjchem-1915	264	23	compound	compound	VERB
eurjchem-1915	264	24	8	8	NUM
eurjchem-1915	264	25	40	40	NUM
eurjchem-1915	264	26	91	91	NUM
eurjchem-1915	264	27	catalyst	catalyst	NOUN
eurjchem-1915	264	28	used	use	VERB
eurjchem-1915	264	29	:	:	PUNCT
eurjchem-1915	264	30	compound	compound	VERB
eurjchem-1915	264	31	7	7	NUM
eurjchem-1915	264	32	19	19	NUM
eurjchem-1915	264	33	120	120	NUM
eurjchem-1915	264	34	88	88	NUM
eurjchem-1915	264	35	reference	reference	NOUN
eurjchem-1915	264	36	28	28	NUM
eurjchem-1915	264	37	45	45	NUM
eurjchem-1915	264	38	91	91	NUM
eurjchem-1915	264	39	catalyst	catalyst	NOUN
eurjchem-1915	264	40	used	use	VERB
eurjchem-1915	264	41	:	:	PUNCT
eurjchem-1915	264	42	compound	compound	VERB
eurjchem-1915	264	43	8	8	NUM
eurjchem-1915	264	44	30	30	NUM
eurjchem-1915	264	45	90	90	NUM
eurjchem-1915	264	46	catalyst	catalyst	NOUN
eurjchem-1915	264	47	used	use	VERB
eurjchem-1915	264	48	:	:	PUNCT
eurjchem-1915	264	49	compound	compound	VERB
eurjchem-1915	264	50	7	7	NUM
eurjchem-1915	264	51	20	20	NUM
eurjchem-1915	264	52	120	120	NUM
eurjchem-1915	264	53	92	92	NUM
eurjchem-1915	264	54	reference	reference	NOUN
eurjchem-1915	264	55	29	29	NUM
eurjchem-1915	264	56	45	45	NUM
eurjchem-1915	264	57	92	92	NUM
eurjchem-1915	264	58	catalyst	catalyst	NOUN
eurjchem-1915	264	59	used	use	VERB
eurjchem-1915	264	60	:	:	PUNCT
eurjchem-1915	264	61	compound	compound	VERB
eurjchem-1915	264	62	8	8	NUM
eurjchem-1915	264	63	45	45	NUM
eurjchem-1915	264	64	94	94	NUM
eurjchem-1915	264	65	catalyst	catalyst	NOUN
eurjchem-1915	264	66	used	use	VERB
eurjchem-1915	264	67	:	:	PUNCT
eurjchem-1915	264	68	compound	compound	VERB
eurjchem-1915	264	69	7	7	NUM
eurjchem-1915	264	70	21	21	NUM
eurjchem-1915	264	71	720	720	NUM
eurjchem-1915	264	72	90	90	NUM
eurjchem-1915	264	73	reference	reference	NOUN
eurjchem-1915	264	74	29	29	NUM
eurjchem-1915	264	75	91	91	NUM
eurjchem-1915	264	76	catalyst	catalyst	NOUN
eurjchem-1915	264	77	used	use	VERB
eurjchem-1915	264	78	:	:	PUNCT
eurjchem-1915	264	79	compound	compound	VERB
eurjchem-1915	264	80	8	8	NUM
eurjchem-1915	264	81	90	90	NUM
eurjchem-1915	264	82	catalyst	catalyst	NOUN
eurjchem-1915	264	83	used	use	VERB
eurjchem-1915	264	84	:	:	PUNCT
eurjchem-1915	264	85	compound	compound	VERB
eurjchem-1915	264	86	7	7	NUM
eurjchem-1915	264	87	22	22	NUM
eurjchem-1915	264	88	660	660	NUM
eurjchem-1915	264	89	88	88	NUM
eurjchem-1915	264	90	reference	reference	NOUN
eurjchem-1915	264	91	29	29	NUM
eurjchem-1915	264	92	60	60	NUM
eurjchem-1915	264	93	85	85	NUM
eurjchem-1915	264	94	catalyst	catalyst	NOUN
eurjchem-1915	264	95	used	use	VERB
eurjchem-1915	264	96	:	:	PUNCT
eurjchem-1915	264	97	compound	compound	VERB
eurjchem-1915	264	98	8	8	NUM
eurjchem-1915	264	99	60	60	NUM
eurjchem-1915	264	100	85	85	NUM
eurjchem-1915	264	101	catalyst	catalyst	NOUN
eurjchem-1915	264	102	used	use	VERB
eurjchem-1915	264	103	:	:	PUNCT
eurjchem-1915	264	104	compound	compound	VERB
eurjchem-1915	264	105	7	7	NUM
eurjchem-1915	264	106	23	23	NUM
eurjchem-1915	264	107	to	to	ADP
eurjchem-1915	264	108	the	the	DET
eurjchem-1915	264	109	best	good	ADJ
eurjchem-1915	264	110	of	of	ADP
eurjchem-1915	264	111	our	our	PRON
eurjchem-1915	264	112	knowledge	knowledge	NOUN
eurjchem-1915	264	113	,	,	PUNCT
eurjchem-1915	264	114	this	this	PRON
eurjchem-1915	264	115	is	be	AUX
eurjchem-1915	264	116	the	the	DET
eurjchem-1915	264	117	first	first	ADJ
eurjchem-1915	264	118	reporting	reporting	NOUN
eurjchem-1915	264	119	for	for	ADP
eurjchem-1915	264	120	compound	compound	NOUN
eurjchem-1915	264	121	23	23	NUM
eurjchem-1915	264	122	for	for	ADP
eurjchem-1915	264	123	suzuki	suzuki	NOUN
eurjchem-1915	264	124	coupling	coupling	NOUN
eurjchem-1915	264	125	reaction	reaction	NOUN
eurjchem-1915	264	126	45	45	NUM
eurjchem-1915	264	127	88	88	NUM
eurjchem-1915	264	128	catalyst	catalyst	NOUN
eurjchem-1915	264	129	used	use	VERB
eurjchem-1915	264	130	:	:	PUNCT
eurjchem-1915	264	131	compound	compound	VERB
eurjchem-1915	264	132	8	8	NUM
eurjchem-1915	264	133	45	45	NUM
eurjchem-1915	264	134	91	91	NUM
eurjchem-1915	264	135	catalyst	catalyst	NOUN
eurjchem-1915	264	136	used	use	VERB
eurjchem-1915	264	137	:	:	PUNCT
eurjchem-1915	264	138	compound	compound	VERB
eurjchem-1915	264	139	7	7	NUM
eurjchem-1915	264	140	cross	cross	NOUN
eurjchem-1915	264	141	-	-	ADJ
eurjchem-1915	264	142	coupling	coupling	NOUN
eurjchem-1915	264	143	of	of	ADP
eurjchem-1915	264	144	the	the	DET
eurjchem-1915	264	145	5	5	NUM
eurjchem-1915	264	146	-	-	PUNCT
eurjchem-1915	264	147	bromopyridine-3	bromopyridine-3	NUM
eurjchem-1915	264	148	-	-	PUNCT
eurjchem-1915	264	149	carbonitrile	carbonitrile	NOUN
eurjchem-1915	264	150	derivative	derivative	NOUN
eurjchem-1915	264	151	17	17	NUM
eurjchem-1915	264	152	[	[	X
eurjchem-1915	264	153	37	37	NUM
eurjchem-1915	264	154	]	]	PUNCT
eurjchem-1915	264	155	with	with	ADP
eurjchem-1915	264	156	phenylboronic	phenylboronic	ADJ
eurjchem-1915	264	157	acid	acid	NOUN
eurjchem-1915	264	158	11	11	NUM
eurjchem-1915	264	159	in	in	ADP
eurjchem-1915	264	160	water	water	NOUN
eurjchem-1915	264	161	using	use	VERB
eurjchem-1915	264	162	pd	pd	NOUN
eurjchem-1915	264	163	-	-	PUNCT
eurjchem-1915	264	164	complex	complex	ADJ
eurjchem-1915	264	165	7	7	NUM
eurjchem-1915	264	166	(	(	PUNCT
eurjchem-1915	264	167	1	1	NUM
eurjchem-1915	264	168	mol%	mol%	NOUN
eurjchem-1915	264	169	)	)	PUNCT
eurjchem-1915	264	170	afforded	afford	VERB
eurjchem-1915	264	171	the	the	DET
eurjchem-1915	264	172	5	5	NUM
eurjchem-1915	264	173	-	-	PUNCT
eurjchem-1915	264	174	phenylpyridine-3carbonitrile	phenylpyridine-3carbonitrile	NOUN
eurjchem-1915	264	175	derivative	derivative	NOUN
eurjchem-1915	264	176	23	23	NUM
eurjchem-1915	264	177	(	(	PUNCT
eurjchem-1915	264	178	run	run	VERB
eurjchem-1915	264	179	6	6	NUM
eurjchem-1915	264	180	,	,	PUNCT
eurjchem-1915	264	181	table	table	NOUN
eurjchem-1915	264	182	5	5	NUM
eurjchem-1915	264	183	)	)	PUNCT
eurjchem-1915	264	184	.	.	PUNCT
eurjchem-1915	265	1	the	the	DET
eurjchem-1915	265	2	identities	identity	NOUN
eurjchem-1915	265	3	of	of	ADP
eurjchem-1915	265	4	the	the	DET
eurjchem-1915	265	5	cross	cross	ADJ
eurjchem-1915	265	6	-	-	ADJ
eurjchem-1915	265	7	coupled	couple	VERB
eurjchem-1915	265	8	products	product	NOUN
eurjchem-1915	265	9	were	be	AUX
eurjchem-1915	265	10	confirmed	confirm	VERB
eurjchem-1915	265	11	by	by	ADP
eurjchem-1915	265	12	hrms	hrm	NOUN
eurjchem-1915	265	13	,	,	PUNCT
eurjchem-1915	265	14	1h	1h	NUM
eurjchem-1915	265	15	and	and	CCONJ
eurjchem-1915	265	16	13c	13c	NOUN
eurjchem-1915	265	17	nmr	nmr	NOUN
eurjchem-1915	265	18	spectra	spectra	NOUN
eurjchem-1915	265	19	.	.	PUNCT
eurjchem-1915	266	1	the	the	DET
eurjchem-1915	266	2	yield	yield	NOUN
eurjchem-1915	266	3	in	in	ADP
eurjchem-1915	266	4	case	case	NOUN
eurjchem-1915	266	5	of	of	ADP
eurjchem-1915	266	6	compound	compound	NOUN
eurjchem-1915	266	7	18	18	NUM
eurjchem-1915	266	8	,	,	PUNCT
eurjchem-1915	266	9	20	20	NUM
eurjchem-1915	266	10	and	and	CCONJ
eurjchem-1915	266	11	23	23	NUM
eurjchem-1915	266	12	showed	show	VERB
eurjchem-1915	266	13	an	an	DET
eurjchem-1915	266	14	improvement	improvement	NOUN
eurjchem-1915	266	15	from	from	ADP
eurjchem-1915	266	16	1	1	NUM
eurjchem-1915	266	17	to	to	PART
eurjchem-1915	266	18	3	3	NUM
eurjchem-1915	266	19	%	%	NOUN
eurjchem-1915	266	20	as	as	ADP
eurjchem-1915	266	21	compared	compare	VERB
eurjchem-1915	266	22	by	by	ADP
eurjchem-1915	266	23	pdcomplex	pdcomplex	NOUN
eurjchem-1915	266	24	8	8	NUM
eurjchem-1915	266	25	.	.	PUNCT
eurjchem-1915	266	26	comparison	comparison	NOUN
eurjchem-1915	266	27	between	between	ADP
eurjchem-1915	266	28	literature	literature	NOUN
eurjchem-1915	266	29	data	datum	NOUN
eurjchem-1915	266	30	and	and	CCONJ
eurjchem-1915	266	31	data	datum	NOUN
eurjchem-1915	266	32	obtained	obtain	VERB
eurjchem-1915	266	33	upon	upon	SCONJ
eurjchem-1915	266	34	using	use	VERB
eurjchem-1915	266	35	catalytic	catalytic	ADJ
eurjchem-1915	266	36	compounds	compound	NOUN
eurjchem-1915	266	37	7	7	NUM
eurjchem-1915	266	38	and	and	CCONJ
eurjchem-1915	266	39	8	8	NUM
eurjchem-1915	266	40	showed	show	VERB
eurjchem-1915	266	41	an	an	DET
eurjchem-1915	266	42	observed	observed	ADJ
eurjchem-1915	266	43	2019	2019	NUM
eurjchem-1915	266	44	–	–	PUNCT
eurjchem-1915	266	45	european	european	ADJ
eurjchem-1915	266	46	journal	journal	NOUN
eurjchem-1915	266	47	of	of	ADP
eurjchem-1915	266	48	chemistry	chemistry	NOUN
eurjchem-1915	266	49	–	–	PUNCT
eurjchem-1915	266	50	cc	cc	NOUN
eurjchem-1915	266	51	by	by	ADP
eurjchem-1915	266	52	nc	nc	PROPN
eurjchem-1915	266	53	–	–	PUNCT
eurjchem-1915	266	54	doi	doi	PROPN
eurjchem-1915	266	55	:	:	PUNCT
eurjchem-1915	266	56	10.5155	10.5155	NUM
eurjchem-1915	266	57	/	/	SYM
eurjchem-1915	266	58	eurjchem.10.4.367	eurjchem.10.4.367	NUM
eurjchem-1915	266	59	-	-	SYM
eurjchem-1915	266	60	375.1915	375.1915	NUM
eurjchem-1915	266	61	al	al	PROPN
eurjchem-1915	266	62	-	-	PUNCT
eurjchem-1915	266	63	fulaij	fulaij	PROPN
eurjchem-1915	266	64	et	et	PROPN
eurjchem-1915	266	65	al	al	PROPN
eurjchem-1915	266	66	.	.	PUNCT
eurjchem-1915	266	67	/	/	SYM
eurjchem-1915	266	68	european	european	PROPN
eurjchem-1915	266	69	journal	journal	PROPN
eurjchem-1915	266	70	of	of	ADP
eurjchem-1915	266	71	chemistry	chemistry	NOUN
eurjchem-1915	266	72	10	10	NUM
eurjchem-1915	266	73	(	(	PUNCT
eurjchem-1915	266	74	4	4	NUM
eurjchem-1915	266	75	)	)	PUNCT
eurjchem-1915	266	76	(	(	PUNCT
eurjchem-1915	266	77	2019	2019	NUM
eurjchem-1915	266	78	)	)	PUNCT
eurjchem-1915	266	79	367	367	NUM
eurjchem-1915	266	80	-	-	SYM
eurjchem-1915	266	81	375	375	NUM
eurjchem-1915	266	82	375	375	NUM
eurjchem-1915	266	83	improvement	improvement	NOUN
eurjchem-1915	266	84	in	in	ADP
eurjchem-1915	266	85	the	the	DET
eurjchem-1915	266	86	time	time	NOUN
eurjchem-1915	266	87	of	of	ADP
eurjchem-1915	266	88	the	the	DET
eurjchem-1915	266	89	reactions	reaction	NOUN
eurjchem-1915	266	90	in	in	ADP
eurjchem-1915	266	91	addition	addition	NOUN
eurjchem-1915	266	92	to	to	ADP
eurjchem-1915	266	93	the	the	DET
eurjchem-1915	266	94	yield	yield	NOUN
eurjchem-1915	266	95	%	%	NOUN
eurjchem-1915	266	96	(	(	PUNCT
eurjchem-1915	266	97	cf	cf	NOUN
eurjchem-1915	266	98	.	.	PUNCT
eurjchem-1915	266	99	table	table	NOUN
eurjchem-1915	266	100	6	6	NUM
eurjchem-1915	266	101	)	)	PUNCT
eurjchem-1915	266	102	.	.	PUNCT
eurjchem-1915	267	1	4	4	X
eurjchem-1915	267	2	.	.	X
eurjchem-1915	267	3	conclusions	conclusion	NOUN
eurjchem-1915	267	4	the	the	DET
eurjchem-1915	267	5	current	current	ADJ
eurjchem-1915	267	6	work	work	NOUN
eurjchem-1915	267	7	described	describe	VERB
eurjchem-1915	267	8	an	an	DET
eurjchem-1915	267	9	efficient	efficient	ADJ
eurjchem-1915	267	10	one	one	NUM
eurjchem-1915	267	11	-	-	PUNCT
eurjchem-1915	267	12	pot	pot	NOUN
eurjchem-1915	267	13	regionselective	regionselective	NOUN
eurjchem-1915	267	14	double	double	ADJ
eurjchem-1915	267	15	1,3	1,3	NUM
eurjchem-1915	267	16	-	-	PUNCT
eurjchem-1915	267	17	dipolar	dipolar	ADJ
eurjchem-1915	267	18	cycloaddition	cycloaddition	NOUN
eurjchem-1915	267	19	of	of	ADP
eurjchem-1915	267	20	bis	bis	ADJ
eurjchem-1915	267	21	-	-	ADJ
eurjchem-1915	267	22	hydrazonoyl	hydrazonoyl	ADJ
eurjchem-1915	267	23	chlorides	chloride	NOUN
eurjchem-1915	267	24	with	with	ADP
eurjchem-1915	267	25	two	two	NUM
eurjchem-1915	267	26	equivalents	equivalent	NOUN
eurjchem-1915	267	27	of	of	ADP
eurjchem-1915	267	28	the	the	DET
eurjchem-1915	267	29	electron	electron	NOUN
eurjchem-1915	267	30	deficient	deficient	ADJ
eurjchem-1915	267	31	alkyne	alkyne	NOUN
eurjchem-1915	267	32	;	;	PUNCT
eurjchem-1915	267	33	methyl	methyl	NOUN
eurjchem-1915	267	34	propiolate	propiolate	NOUN
eurjchem-1915	267	35	to	to	PART
eurjchem-1915	267	36	give	give	VERB
eurjchem-1915	267	37	the	the	DET
eurjchem-1915	267	38	corresponding	corresponding	ADJ
eurjchem-1915	267	39	bipyrazole	bipyrazole	ADJ
eurjchem-1915	267	40	esters	ester	NOUN
eurjchem-1915	267	41	which	which	PRON
eurjchem-1915	267	42	underwent	undergo	VERB
eurjchem-1915	267	43	acid	acid	NOUN
eurjchem-1915	267	44	hydrolysis	hydrolysis	NOUN
eurjchem-1915	267	45	to	to	PART
eurjchem-1915	267	46	give	give	VERB
eurjchem-1915	267	47	the	the	DET
eurjchem-1915	267	48	bipyrazole	bipyrazole	ADJ
eurjchem-1915	267	49	dicarboxylic	dicarboxylic	ADJ
eurjchem-1915	267	50	acid	acid	NOUN
eurjchem-1915	267	51	.	.	PUNCT
eurjchem-1915	268	1	palladium(ii)-complexes	palladium(ii)-complexe	NOUN
eurjchem-1915	268	2	of	of	ADP
eurjchem-1915	268	3	the	the	DET
eurjchem-1915	268	4	bishydrazonoyl	bishydrazonoyl	NOUN
eurjchem-1915	268	5	chloride	chloride	NOUN
eurjchem-1915	268	6	and	and	CCONJ
eurjchem-1915	268	7	bipyrazole	bipyrazole	ADJ
eurjchem-1915	268	8	dicarboxylic	dicarboxylic	ADJ
eurjchem-1915	268	9	acid	acid	NOUN
eurjchem-1915	268	10	were	be	AUX
eurjchem-1915	268	11	synthesized	synthesize	VERB
eurjchem-1915	268	12	and	and	CCONJ
eurjchem-1915	268	13	both	both	PRON
eurjchem-1915	268	14	of	of	ADP
eurjchem-1915	268	15	them	they	PRON
eurjchem-1915	268	16	was	be	AUX
eurjchem-1915	268	17	found	find	VERB
eurjchem-1915	268	18	to	to	PART
eurjchem-1915	268	19	be	be	AUX
eurjchem-1915	268	20	an	an	DET
eurjchem-1915	268	21	efficient	efficient	ADJ
eurjchem-1915	268	22	catalyst	catalyst	NOUN
eurjchem-1915	268	23	for	for	ADP
eurjchem-1915	268	24	suzuki	suzuki	PROPN
eurjchem-1915	268	25	cross	cross	ADJ
eurjchem-1915	268	26	-	-	ADJ
eurjchem-1915	268	27	coupling	coupling	ADJ
eurjchem-1915	268	28	reaction	reaction	NOUN
eurjchem-1915	268	29	.	.	PUNCT
eurjchem-1915	269	1	acknowledgments	acknowledgment	NOUN
eurjchem-1915	269	2	the	the	DET
eurjchem-1915	269	3	authors	author	NOUN
eurjchem-1915	269	4	kindly	kindly	ADV
eurjchem-1915	269	5	acknowledge	acknowledge	VERB
eurjchem-1915	269	6	the	the	DET
eurjchem-1915	269	7	financial	financial	ADJ
eurjchem-1915	269	8	support	support	NOUN
eurjchem-1915	269	9	of	of	ADP
eurjchem-1915	269	10	this	this	DET
eurjchem-1915	269	11	project	project	NOUN
eurjchem-1915	269	12	by	by	ADP
eurjchem-1915	269	13	kuwait	kuwait	PROPN
eurjchem-1915	269	14	university	university	PROPN
eurjchem-1915	269	15	,	,	PUNCT
eurjchem-1915	269	16	research	research	NOUN
eurjchem-1915	269	17	administration	administration	NOUN
eurjchem-1915	269	18	through	through	ADP
eurjchem-1915	269	19	research	research	NOUN
eurjchem-1915	269	20	project	project	NOUN
eurjchem-1915	269	21	grant	grant	VERB
eurjchem-1915	269	22	sc	sc	PROPN
eurjchem-1915	269	23	13/15	13/15	NUM
eurjchem-1915	269	24	.	.	PUNCT
eurjchem-1915	270	1	the	the	DET
eurjchem-1915	270	2	analytical	analytical	ADJ
eurjchem-1915	270	3	services	service	NOUN
eurjchem-1915	270	4	provided	provide	VERB
eurjchem-1915	270	5	by	by	ADP
eurjchem-1915	270	6	the	the	DET
eurjchem-1915	270	7	analab	analab	NOUN
eurjchem-1915	270	8	and	and	CCONJ
eurjchem-1915	270	9	saf	saf	PROPN
eurjchem-1915	270	10	in	in	ADP
eurjchem-1915	270	11	the	the	DET
eurjchem-1915	270	12	faculty	faculty	NOUN
eurjchem-1915	270	13	of	of	ADP
eurjchem-1915	270	14	science	science	NOUN
eurjchem-1915	270	15	through	through	ADP
eurjchem-1915	270	16	the	the	DET
eurjchem-1915	270	17	grant	grant	NOUN
eurjchem-1915	270	18	no	no	INTJ
eurjchem-1915	270	19	.	.	PUNCT
eurjchem-1915	271	1	gs-01/01	gs-01/01	PROPN
eurjchem-1915	271	2	,	,	PUNCT
eurjchem-1915	271	3	gs	gs	NOUN
eurjchem-1915	271	4	01/05	01/05	NUM
eurjchem-1915	271	5	and	and	CCONJ
eurjchem-1915	271	6	gs	gs	INTJ
eurjchem-1915	271	7	03/08	03/08	PRON
eurjchem-1915	271	8	are	be	AUX
eurjchem-1915	271	9	also	also	ADV
eurjchem-1915	271	10	gratefully	gratefully	ADV
eurjchem-1915	271	11	acknowledged	acknowledge	VERB
eurjchem-1915	271	12	.	.	PUNCT
eurjchem-1915	272	1	supporting	support	VERB
eurjchem-1915	272	2	information	information	NOUN
eurjchem-1915	272	3	ccdc-1548525	ccdc-1548525	NOUN
eurjchem-1915	272	4	contains	contain	VERB
eurjchem-1915	272	5	the	the	DET
eurjchem-1915	272	6	supplementary	supplementary	ADJ
eurjchem-1915	272	7	crystallographic	crystallographic	ADJ
eurjchem-1915	272	8	data	datum	NOUN
eurjchem-1915	272	9	for	for	ADP
eurjchem-1915	272	10	this	this	DET
eurjchem-1915	272	11	paper	paper	NOUN
eurjchem-1915	272	12	.	.	PUNCT
eurjchem-1915	273	1	these	these	DET
eurjchem-1915	273	2	data	datum	NOUN
eurjchem-1915	273	3	can	can	AUX
eurjchem-1915	273	4	be	be	AUX
eurjchem-1915	273	5	obtained	obtain	VERB
eurjchem-1915	273	6	free	free	ADJ
eurjchem-1915	273	7	of	of	ADP
eurjchem-1915	273	8	charge	charge	NOUN
eurjchem-1915	273	9	via	via	ADP
eurjchem-1915	273	10	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	PROPN
eurjchem-1915	273	11	,	,	PUNCT
eurjchem-1915	273	12	or	or	CCONJ
eurjchem-1915	273	13	by	by	ADP
eurjchem-1915	273	14	e	e	NOUN
eurjchem-1915	273	15	-	-	ADJ
eurjchem-1915	273	16	mailing	mailing	ADJ
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eurjchem-1915	273	18	,	,	PUNCT
eurjchem-1915	273	19	or	or	CCONJ
eurjchem-1915	273	20	by	by	ADP
eurjchem-1915	273	21	contacting	contact	VERB
eurjchem-1915	273	22	the	the	DET
eurjchem-1915	273	23	cambridge	cambridge	PROPN
eurjchem-1915	273	24	crystallographic	crystallographic	PROPN
eurjchem-1915	273	25	data	data	PROPN
eurjchem-1915	273	26	centre	centre	NOUN
eurjchem-1915	273	27	,	,	PUNCT
eurjchem-1915	273	28	12	12	NUM
eurjchem-1915	273	29	union	union	NOUN
eurjchem-1915	273	30	road	road	NOUN
eurjchem-1915	273	31	,	,	PUNCT
eurjchem-1915	273	32	cambridge	cambridge	PROPN
eurjchem-1915	273	33	cb2	cb2	PROPN
eurjchem-1915	273	34	1ez	1ez	PROPN
eurjchem-1915	273	35	,	,	PUNCT
eurjchem-1915	273	36	uk	uk	PROPN
eurjchem-1915	273	37	;	;	PUNCT
eurjchem-1915	273	38	fax	fax	NOUN
eurjchem-1915	273	39	:	:	PUNCT
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eurjchem-1915	273	41	-	-	PUNCT
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eurjchem-1915	273	43	.	.	PUNCT
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eurjchem-1915	274	2	statement	statement	NOUN
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eurjchem-1915	274	6	:	:	PUNCT
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eurjchem-1915	274	12	have	have	VERB
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eurjchem-1915	274	14	conflict	conflict	NOUN
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eurjchem-1915	274	17	.	.	PUNCT
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eurjchem-1915	275	3	:	:	PUNCT
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eurjchem-1915	275	5	authors	author	NOUN
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eurjchem-1915	275	8	to	to	ADP
eurjchem-1915	275	9	this	this	DET
eurjchem-1915	275	10	work	work	NOUN
eurjchem-1915	275	11	.	.	PUNCT
eurjchem-1915	276	1	funding	fund	VERB
eurjchem-1915	276	2	this	this	DET
eurjchem-1915	276	3	research	research	NOUN
eurjchem-1915	276	4	work	work	NOUN
eurjchem-1915	276	5	is	be	AUX
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eurjchem-1915	276	10	,	,	PUNCT
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eurjchem-1915	276	12	project	project	NOUN
eurjchem-1915	276	13	grant	grant	NOUN
eurjchem-1915	276	14	sc-13/15	sc-13/15	NOUN
eurjchem-1915	276	15	.	.	PUNCT
eurjchem-1915	277	1	orcid	orcid	PROPN
eurjchem-1915	277	2	othman	othman	PROPN
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eurjchem-1915	277	4	al	al	PROPN
eurjchem-1915	277	5	-	-	PUNCT
eurjchem-1915	277	6	fulaij	fulaij	PROPN
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eurjchem-1915	277	9	-	-	PUNCT
eurjchem-1915	277	10	zaher	zaher	PROPN
eurjchem-1915	277	11	abdelaziz	abdelaziz	PROPN
eurjchem-1915	277	12	elassar	elassar	PROPN
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eurjchem-1915	277	14	kamal	kamal	PROPN
eurjchem-1915	277	15	mohamed	mohamed	PROPN
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eurjchem-1915	277	18	references	reference	NOUN
eurjchem-1915	277	19	[	[	X
eurjchem-1915	277	20	1	1	NUM
eurjchem-1915	277	21	]	]	PUNCT
eurjchem-1915	277	22	.	.	PUNCT
eurjchem-1915	278	1	ballhausen	ballhausen	PROPN
eurjchem-1915	278	2	,	,	PUNCT
eurjchem-1915	278	3	c.	c.	PROPN
eurjchem-1915	278	4	j.	j.	PROPN
eurjchem-1915	278	5	introduction	introduction	NOUN
eurjchem-1915	278	6	to	to	PART
eurjchem-1915	278	7	ligand	ligand	ADJ
eurjchem-1915	278	8	field	field	NOUN
eurjchem-1915	278	9	theory	theory	NOUN
eurjchem-1915	278	10	,	,	PUNCT
eurjchem-1915	278	11	mcgraw	mcgraw	PROPN
eurjchem-1915	278	12	hill	hill	PROPN
eurjchem-1915	278	13	,	,	PUNCT
eurjchem-1915	278	14	new	new	PROPN
eurjchem-1915	278	15	york	york	PROPN
eurjchem-1915	278	16	,	,	PUNCT
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eurjchem-1915	279	4	.	.	PUNCT
eurjchem-1915	280	1	atwood	atwood	PROPN
eurjchem-1915	280	2	,	,	PUNCT
eurjchem-1915	280	3	j.	j.	PROPN
eurjchem-1915	280	4	d.	d.	PROPN
eurjchem-1915	280	5	;	;	PUNCT
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eurjchem-1915	280	7	,	,	PUNCT
eurjchem-1915	280	8	m.	m.	PROPN
eurjchem-1915	280	9	j.	j.	PROPN
eurjchem-1915	280	10	;	;	PUNCT
eurjchem-1915	280	11	sonnenberger	sonnenberger	NOUN
eurjchem-1915	280	12	,	,	PUNCT
eurjchem-1915	280	13	d.	d.	PROPN
eurjchem-1915	280	14	c.	c.	PROPN
eurjchem-1915	280	15	acc	acc	PROPN
eurjchem-1915	280	16	.	.	PROPN
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eurjchem-1915	280	18	.	.	PUNCT
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eurjchem-1915	281	2	.	.	PUNCT
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eurjchem-1915	282	1	[	[	X
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eurjchem-1915	282	4	.	.	PUNCT
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eurjchem-1915	283	5	;	;	PUNCT
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eurjchem-1915	283	8	c.	c.	PROPN
eurjchem-1915	283	9	;	;	PUNCT
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eurjchem-1915	283	12	c.	c.	PROPN
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eurjchem-1915	283	14	acc	acc	PROPN
eurjchem-1915	283	15	.	.	PROPN
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eurjchem-1915	283	17	.	.	PUNCT
eurjchem-1915	284	1	res	re	NOUN
eurjchem-1915	284	2	.	.	PROPN
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eurjchem-1915	285	4	,	,	PUNCT
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eurjchem-1915	285	6	-	-	SYM
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eurjchem-1915	285	8	.	.	PUNCT
eurjchem-1915	286	1	[	[	X
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eurjchem-1915	286	4	.	.	PUNCT
eurjchem-1915	287	1	chifotides	chifotide	NOUN
eurjchem-1915	287	2	,	,	PUNCT
eurjchem-1915	287	3	h.	h.	PROPN
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eurjchem-1915	287	6	,	,	PUNCT
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eurjchem-1915	300	4	;	;	PUNCT
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eurjchem-1915	324	1	[	[	X
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eurjchem-1915	324	3	]	]	PUNCT
eurjchem-1915	324	4	.	.	PUNCT
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eurjchem-1915	325	2	,	,	PUNCT
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eurjchem-1915	325	4	;	;	PUNCT
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eurjchem-1915	325	13	obara	obara	PROPN
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eurjchem-1915	328	25	;	;	PUNCT
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eurjchem-1915	328	39	;	;	PUNCT
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eurjchem-1915	328	49	;	;	PUNCT
eurjchem-1915	328	50	rogers	rogers	PROPN
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eurjchem-1915	328	52	r.	r.	PROPN
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eurjchem-1915	328	64	;	;	PUNCT
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eurjchem-1915	328	67	g.	g.	PROPN
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eurjchem-1915	328	69	;	;	PUNCT
eurjchem-1915	328	70	burton	burton	PROPN
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eurjchem-1915	328	74	;	;	PUNCT
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eurjchem-1915	328	76	,	,	PUNCT
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eurjchem-1915	328	78	n.	n.	PROPN
eurjchem-1915	328	79	;	;	PUNCT
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eurjchem-1915	328	94	;	;	PUNCT
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eurjchem-1915	328	97	k.	k.	PROPN
eurjchem-1915	328	98	;	;	PUNCT
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eurjchem-1915	328	101	a.	a.	PROPN
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eurjchem-1915	328	103	;	;	PUNCT
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eurjchem-1915	328	106	y.	y.	PROPN
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eurjchem-1915	328	109	isakson	isakson	PROPN
eurjchem-1915	328	110	,	,	PUNCT
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eurjchem-1915	328	112	c.	c.	PROPN
eurjchem-1915	328	113	j.	j.	PROPN
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eurjchem-1915	328	115	.	.	PROPN
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eurjchem-1915	328	117	.	.	PUNCT
eurjchem-1915	329	1	1997	1997	NUM
eurjchem-1915	329	2	,	,	PUNCT
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eurjchem-1915	329	4	,	,	PUNCT
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eurjchem-1915	329	6	-	-	SYM
eurjchem-1915	329	7	1365	1365	NUM
eurjchem-1915	329	8	.	.	PUNCT
eurjchem-1915	330	1	[	[	X
eurjchem-1915	330	2	18	18	NUM
eurjchem-1915	330	3	]	]	PUNCT
eurjchem-1915	330	4	.	.	PUNCT
eurjchem-1915	331	1	deng	deng	PROPN
eurjchem-1915	331	2	,	,	PUNCT
eurjchem-1915	331	3	x.	x.	PROPN
eurjchem-1915	331	4	;	;	PUNCT
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eurjchem-1915	331	8	s.	s.	PROPN
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eurjchem-1915	331	10	.	.	PUNCT
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eurjchem-1915	332	2	.	.	PROPN
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eurjchem-1915	332	4	,	,	PUNCT
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eurjchem-1915	332	6	,	,	PUNCT
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eurjchem-1915	332	8	-	-	SYM
eurjchem-1915	332	9	1310	1310	NUM
eurjchem-1915	332	10	.	.	PUNCT
eurjchem-1915	333	1	[	[	X
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eurjchem-1915	333	3	]	]	PUNCT
eurjchem-1915	333	4	.	.	PUNCT
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eurjchem-1915	334	2	,	,	PUNCT
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eurjchem-1915	334	4	;	;	PUNCT
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eurjchem-1915	335	3	]	]	PUNCT
eurjchem-1915	335	4	.	.	PUNCT
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eurjchem-1915	341	6	-	-	SYM
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eurjchem-1915	341	8	.	.	PUNCT
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eurjchem-1915	342	4	.	.	PUNCT
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eurjchem-1915	343	4	;	;	PUNCT
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eurjchem-1915	345	3	]	]	PUNCT
eurjchem-1915	345	4	.	.	PUNCT
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eurjchem-1915	347	4	.	.	PUNCT
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eurjchem-1915	348	5	;	;	PUNCT
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eurjchem-1915	352	1	a	a	DET
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eurjchem-1915	352	3	,	,	PUNCT
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eurjchem-1915	352	5	,	,	PUNCT
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eurjchem-1915	353	1	[	[	X
eurjchem-1915	353	2	26	26	NUM
eurjchem-1915	353	3	]	]	PUNCT
eurjchem-1915	353	4	.	.	PUNCT
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eurjchem-1915	356	2	27	27	NUM
eurjchem-1915	356	3	]	]	PUNCT
eurjchem-1915	356	4	.	.	PUNCT
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eurjchem-1915	357	2	,	,	PUNCT
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eurjchem-1915	357	4	,	,	PUNCT
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eurjchem-1915	357	6	-	-	SYM
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eurjchem-1915	357	8	.	.	PUNCT
eurjchem-1915	358	1	[	[	X
eurjchem-1915	358	2	28	28	NUM
eurjchem-1915	358	3	]	]	PUNCT
eurjchem-1915	358	4	.	.	PUNCT
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eurjchem-1915	359	22	.	.	PUNCT
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eurjchem-1915	361	2	.	.	PUNCT
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eurjchem-1915	362	2	,	,	PUNCT
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eurjchem-1915	362	4	,	,	PUNCT
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eurjchem-1915	362	6	-	-	SYM
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eurjchem-1915	362	8	.	.	PUNCT
eurjchem-1915	363	1	[	[	X
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eurjchem-1915	363	3	]	]	PUNCT
eurjchem-1915	363	4	.	.	PUNCT
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eurjchem-1915	364	2	,	,	PUNCT
eurjchem-1915	364	3	x.	x.	PROPN
eurjchem-1915	364	4	;	;	PUNCT
eurjchem-1915	364	5	yan	yan	PROPN
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eurjchem-1915	364	17	l.	l.	PROPN
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eurjchem-1915	364	19	;	;	PUNCT
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eurjchem-1915	364	23	;	;	PUNCT
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eurjchem-1915	364	26	w.	w.	PROPN
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eurjchem-1915	364	28	;	;	PUNCT
eurjchem-1915	364	29	li	li	PROPN
eurjchem-1915	364	30	,	,	PUNCT
eurjchem-1915	364	31	y.	y.	PROPN
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eurjchem-1915	364	39	.	.	PUNCT
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eurjchem-1915	365	2	.	.	PUNCT
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eurjchem-1915	366	2	,	,	PUNCT
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eurjchem-1915	366	5	495497	495497	NUM
eurjchem-1915	366	6	.	.	PUNCT
eurjchem-1915	367	1	[	[	X
eurjchem-1915	367	2	30	30	NUM
eurjchem-1915	367	3	]	]	PUNCT
eurjchem-1915	367	4	.	.	PUNCT
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eurjchem-1915	371	1	[	[	X
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eurjchem-1915	371	3	]	]	PUNCT
eurjchem-1915	371	4	.	.	PUNCT
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eurjchem-1915	372	4	;	;	PUNCT
eurjchem-1915	372	5	xue	xue	PROPN
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eurjchem-1915	372	8	;	;	PUNCT
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eurjchem-1915	372	40	-	-	SYM
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eurjchem-1915	372	42	.	.	PUNCT
eurjchem-1915	373	1	[	[	X
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eurjchem-1915	373	3	]	]	PUNCT
eurjchem-1915	373	4	.	.	PUNCT
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eurjchem-1915	373	8	;	;	PUNCT
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eurjchem-1915	373	27	.	.	PUNCT
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eurjchem-1915	375	8	.	.	PUNCT
eurjchem-1915	376	1	[	[	X
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eurjchem-1915	376	3	]	]	PUNCT
eurjchem-1915	376	4	.	.	PUNCT
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eurjchem-1915	377	5	;	;	PUNCT
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eurjchem-1915	377	22	;	;	PUNCT
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eurjchem-1915	381	4	.	.	PUNCT
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eurjchem-1915	391	20	(	(	PUNCT
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eurjchem-1915	391	31	(	(	PUNCT
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eurjchem-1915	392	1	by	by	ADP
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eurjchem-1915	392	4	work	work	NOUN
eurjchem-1915	392	5	,	,	PUNCT
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eurjchem-1915	392	9	the	the	DET
eurjchem-1915	392	10	terms	term	NOUN
eurjchem-1915	392	11	.	.	PUNCT
eurjchem-1915	393	1	this	this	PRON
eurjchem-1915	393	2	is	be	AUX
eurjchem-1915	393	3	an	an	DET
eurjchem-1915	393	4	open	open	ADJ
eurjchem-1915	393	5	access	access	NOUN
eurjchem-1915	393	6	article	article	NOUN
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eurjchem-1915	393	10	terms	term	NOUN
eurjchem-1915	393	11	and	and	CCONJ
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eurjchem-1915	393	15	cc	cc	PROPN
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eurjchem-1915	393	17	nc	nc	PROPN
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eurjchem-1915	393	19	,	,	PUNCT
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eurjchem-1915	393	22	unrestricted	unrestricted	ADJ
eurjchem-1915	393	23	non	non	ADJ
eurjchem-1915	393	24	-	-	ADJ
eurjchem-1915	393	25	commercial	commercial	ADJ
eurjchem-1915	393	26	use	use	NOUN
eurjchem-1915	393	27	,	,	PUNCT
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eurjchem-1915	393	29	,	,	PUNCT
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eurjchem-1915	393	31	reproduction	reproduction	NOUN
eurjchem-1915	393	32	in	in	ADP
eurjchem-1915	393	33	any	any	DET
eurjchem-1915	393	34	medium	medium	NOUN
eurjchem-1915	393	35	,	,	PUNCT
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eurjchem-1915	393	37	the	the	DET
eurjchem-1915	393	38	original	original	ADJ
eurjchem-1915	393	39	work	work	NOUN
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eurjchem-1915	393	41	properly	properly	ADV
eurjchem-1915	393	42	cited	cite	VERB
eurjchem-1915	393	43	without	without	ADP
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eurjchem-1915	393	45	further	further	ADJ
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eurjchem-1915	393	47	from	from	ADP
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eurjchem-1915	393	49	publishing	publishing	PROPN
eurjchem-1915	393	50	house	house	PROPN
eurjchem-1915	393	51	llc	llc	PROPN
eurjchem-1915	393	52	(	(	PUNCT
eurjchem-1915	393	53	european	european	PROPN
eurjchem-1915	393	54	journal	journal	PROPN
eurjchem-1915	393	55	of	of	ADP
eurjchem-1915	393	56	chemistry	chemistry	NOUN
eurjchem-1915	393	57	)	)	PUNCT
eurjchem-1915	393	58	.	.	PUNCT
eurjchem-1915	394	1	no	no	DET
eurjchem-1915	394	2	use	use	NOUN
eurjchem-1915	394	3	,	,	PUNCT
eurjchem-1915	394	4	distribution	distribution	NOUN
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eurjchem-1915	394	6	reproduction	reproduction	NOUN
eurjchem-1915	394	7	is	be	AUX
eurjchem-1915	394	8	permitted	permit	VERB
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eurjchem-1915	394	10	does	do	AUX
eurjchem-1915	394	11	not	not	PART
eurjchem-1915	394	12	comply	comply	VERB
eurjchem-1915	394	13	with	with	ADP
eurjchem-1915	394	14	these	these	DET
eurjchem-1915	394	15	terms	term	NOUN
eurjchem-1915	394	16	.	.	PUNCT
eurjchem-1915	395	1	permissions	permission	NOUN
eurjchem-1915	395	2	for	for	ADP
eurjchem-1915	395	3	commercial	commercial	ADJ
eurjchem-1915	395	4	use	use	NOUN
eurjchem-1915	395	5	of	of	ADP
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eurjchem-1915	395	7	work	work	NOUN
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eurjchem-1915	395	21	publishing	publishing	PROPN
eurjchem-1915	395	22	house	house	PROPN
eurjchem-1915	395	23	llc	llc	PROPN
eurjchem-1915	395	24	(	(	PUNCT
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eurjchem-1915	396	3	european	european	ADJ
eurjchem-1915	396	4	journal	journal	NOUN
eurjchem-1915	396	5	of	of	ADP
eurjchem-1915	396	6	chemistry	chemistry	NOUN
eurjchem-1915	396	7	–	–	PUNCT
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eurjchem-1915	396	10	nc	nc	PROPN
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eurjchem-1915	400	1	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicarboxylic	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicarboxylic	NUM
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eurjchem-1915	400	3	(	(	PUNCT
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eurjchem-1915	400	5	)	)	PUNCT
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eurjchem-1915	400	7	.	.	PUNCT
eurjchem-1915	401	1	synthesis	synthesis	NOUN
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eurjchem-1915	401	7	-	-	PUNCT
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eurjchem-1915	401	10	(	(	PUNCT
eurjchem-1915	401	11	7	7	NUM
eurjchem-1915	401	12	)	)	PUNCT
eurjchem-1915	401	13	2.5	2.5	NUM
eurjchem-1915	401	14	.	.	PUNCT
eurjchem-1915	402	1	synthesis	synthesis	NOUN
eurjchem-1915	402	2	of	of	ADP
eurjchem-1915	402	3	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicar	1,1'-diphenyl-3,3'-bipyrazole-4,4'-dicar	NUM
eurjchem-1915	402	4	boxylic	boxylic	ADJ
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eurjchem-1915	402	8	)	)	PUNCT
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eurjchem-1915	402	10	complex	complex	NOUN
eurjchem-1915	402	11	(	(	PUNCT
eurjchem-1915	402	12	8)	8)	NUM
eurjchem-1915	402	13	2.6	2.6	NUM
eurjchem-1915	402	14	.	.	PUNCT
eurjchem-1915	403	1	synthesis	synthesis	NOUN
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eurjchem-1915	403	4	-	-	PUNCT
eurjchem-1915	403	5	n	n	CCONJ
eurjchem-1915	403	6	-	-	PUNCT
eurjchem-1915	403	7	bis(3,3`-bi	bis(3,3`-bi	ADJ
eurjchem-1915	403	8	-	-	PUNCT
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eurjchem-1915	403	10	derivative	derivative	NOUN
eurjchem-1915	403	11	(	(	PUNCT
eurjchem-1915	403	12	10	10	NUM
eurjchem-1915	403	13	)	)	PUNCT
eurjchem-1915	403	14	2.7	2.7	NUM
eurjchem-1915	403	15	.	.	PUNCT
eurjchem-1915	404	1	suzuki	suzuki	NOUN
eurjchem-1915	404	2	-	-	PUNCT
eurjchem-1915	404	3	miyaura	miyaura	NOUN
eurjchem-1915	404	4	cross	cross	NOUN
eurjchem-1915	405	1	-	-	NOUN
eurjchem-1915	406	1	coupling	coupling	NOUN
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eurjchem-1915	406	3	aryl(hetaryl	aryl(hetaryl	NOUN
eurjchem-1915	406	4	)	)	PUNCT
eurjchem-1915	406	5	bromides	bromide	NOUN
eurjchem-1915	406	6	with	with	ADP
eurjchem-1915	406	7	phenylboronic	phenylboronic	ADJ
eurjchem-1915	406	8	acid	acid	NOUN
eurjchem-1915	406	9	in	in	ADP
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eurjchem-1915	406	16	3.1	3.1	NUM
eurjchem-1915	406	17	.	.	PUNCT
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eurjchem-1915	407	5	-	-	PUNCT
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eurjchem-1915	407	9	(	(	PUNCT
eurjchem-1915	407	10	5	5	NUM
eurjchem-1915	407	11	and	and	CCONJ
eurjchem-1915	407	12	6	6	NUM
eurjchem-1915	407	13	)	)	PUNCT
eurjchem-1915	407	14	3.2	3.2	NUM
eurjchem-1915	407	15	.	.	PUNCT
eurjchem-1915	408	1	synthesis	synthesis	NOUN
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eurjchem-1915	408	4	palladium(ii	palladium(ii	NOUN
eurjchem-1915	408	5	)	)	PUNCT
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eurjchem-1915	408	7	(	(	PUNCT
eurjchem-1915	408	8	7	7	NUM
eurjchem-1915	408	9	and	and	CCONJ
eurjchem-1915	408	10	8)	8)	NUM
eurjchem-1915	408	11	3.3	3.3	NUM
eurjchem-1915	408	12	.	.	PUNCT
eurjchem-1915	409	1	xps	xps	PROPN
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eurjchem-1915	409	3	edx	edx	PROPN
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eurjchem-1915	409	7	)	)	PUNCT
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eurjchem-1915	409	10	.	.	PUNCT
eurjchem-1915	410	1	structure	structure	NOUN
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eurjchem-1915	410	3	3.5	3.5	NUM
eurjchem-1915	410	4	.	.	PUNCT
eurjchem-1915	411	1	catalytic	catalytic	ADJ
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eurjchem-1915	411	3	of	of	ADP
eurjchem-1915	411	4	pd	pd	NOUN
eurjchem-1915	411	5	-	-	NOUN
eurjchem-1915	411	6	complex	complex	NOUN
eurjchem-1915	411	7	in	in	ADP
eurjchem-1915	411	8	suzuki	suzuki	PROPN
eurjchem-1915	411	9	cross	cross	PROPN
eurjchem-1915	411	10	-	-	ADJ
eurjchem-1915	411	11	coupling	coupling	ADJ
eurjchem-1915	411	12	reactions	reaction	NOUN
eurjchem-1915	411	13	4	4	NUM
eurjchem-1915	411	14	.	.	PUNCT
eurjchem-1915	412	1	conclusions	conclusion	NOUN
eurjchem-1915	412	2	acknowledgments	acknowledgment	NOUN
eurjchem-1915	412	3	supporting	support	VERB
eurjchem-1915	412	4	information	information	NOUN
eurjchem-1915	412	5	disclosure	disclosure	NOUN
eurjchem-1915	412	6	statement	statement	NOUN
eurjchem-1915	412	7	funding	fund	VERB
eurjchem-1915	412	8	orcid	orcid	PROPN
eurjchem-1915	412	9	references	reference	NOUN
eurjchem-1915	412	10	printfield10	printfield10	NOUN
eurjchem-1915	412	11	:	:	PUNCT
eurjchem-1915	412	12	printfield11	printfield11	NOUN
eurjchem-1915	412	13	:	:	PUNCT
eurjchem-1915	412	14	printfield12	printfield12	PROPN
eurjchem-1915	412	15	:	:	PUNCT
eurjchem-1915	412	16	printfield13	printfield13	VERB
eurjchem-1915	412	17	:	:	PUNCT
eurjchem-1915	412	18	printfield14	printfield14	NOUN
eurjchem-1915	412	19	:	:	PUNCT
eurjchem-1915	412	20	printfield15	printfield15	NOUN
eurjchem-1915	412	21	:	:	PUNCT
eurjchem-1915	412	22	printfield16	printfield16	ADJ
eurjchem-1915	412	23	:	:	PUNCT
eurjchem-1915	412	24	printfield17	printfield17	NOUN
eurjchem-1915	412	25	:	:	PUNCT
eurjchem-1915	412	26	printfield18	printfield18	NOUN
eurjchem-1915	412	27	:	:	PUNCT
eurjchem-1915	412	28	printfield20	printfield20	PROPN
eurjchem-1915	412	29	:	:	PUNCT
eurjchem-1915	413	1	printfield21	printfield21	ADJ
eurjchem-1915	413	2	:	:	PUNCT
eurjchem-1915	413	3	printfield22	printfield22	NOUN
eurjchem-1915	413	4	:	:	PUNCT
eurjchem-1915	413	5	printfield23	printfield23	NOUN
eurjchem-1915	413	6	:	:	PUNCT
eurjchem-1915	413	7	printfield24	printfield24	NOUN
eurjchem-1915	413	8	:	:	PUNCT
eurjchem-1915	413	9	printfield25	printfield25	NOUN
eurjchem-1915	413	10	:	:	PUNCT
eurjchem-1915	413	11	printfield26	printfield26	ADJ
eurjchem-1915	413	12	:	:	PUNCT
eurjchem-1915	413	13	printfield27	printfield27	NOUN
eurjchem-1915	413	14	:	:	PUNCT
eurjchem-1915	413	15	printfield28	printfield28	NOUN
eurjchem-1915	413	16	:	:	PUNCT