id	sid	tid	token	lemma	pos
eurjchem-2037	1	1	imino	imino	NOUN
eurjchem-2037	1	2	-	-	PUNCT
eurjchem-2037	1	3	pyridyl	pyridyl	NOUN
eurjchem-2037	1	4	and	and	CCONJ
eurjchem-2037	1	5	pph3	pph3	PROPN
eurjchem-2037	1	6	mixed	mixed	ADJ
eurjchem-2037	1	7	ligand	ligand	NOUN
eurjchem-2037	1	8	complexes	complex	NOUN
eurjchem-2037	1	9	of	of	ADP
eurjchem-2037	1	10	cu(i)x	cu(i)x	PROPN
eurjchem-2037	1	11	(	(	PUNCT
eurjchem-2037	1	12	x	x	NOUN
eurjchem-2037	1	13	:	:	PUNCT
eurjchem-2037	1	14	i	i	PROPN
eurjchem-2037	1	15	,	,	PUNCT
eurjchem-2037	1	16	br	br	PROPN
eurjchem-2037	1	17	,	,	PUNCT
eurjchem-2037	1	18	and	and	CCONJ
eurjchem-2037	1	19	cl	cl	NOUN
eurjchem-2037	1	20	):	):	PUNCT
eurjchem-2037	1	21	synthesis	synthesis	NOUN
eurjchem-2037	1	22	,	,	PUNCT
eurjchem-2037	1	23	structure	structure	NOUN
eurjchem-2037	1	24	,	,	PUNCT
eurjchem-2037	1	25	dft	dft	PROPN
eurjchem-2037	1	26	and	and	CCONJ
eurjchem-2037	1	27	hirshfeld	hirshfeld	PROPN
eurjchem-2037	1	28	surface	surface	PROPN
eurjchem-2037	1	29	studies	studies	PROPN
eurjchem-2037	1	30	european	european	PROPN
eurjchem-2037	1	31	journal	journal	PROPN
eurjchem-2037	1	32	of	of	ADP
eurjchem-2037	1	33	chemistry	chemistry	NOUN
eurjchem-2037	1	34	11	11	NUM
eurjchem-2037	1	35	(	(	PUNCT
eurjchem-2037	1	36	4	4	NUM
eurjchem-2037	1	37	)	)	PUNCT
eurjchem-2037	1	38	(	(	PUNCT
eurjchem-2037	1	39	2020	2020	NUM
eurjchem-2037	1	40	)	)	PUNCT
eurjchem-2037	1	41	334	334	NUM
eurjchem-2037	1	42	-	-	SYM
eurjchem-2037	1	43	341	341	NUM
eurjchem-2037	1	44	european	european	ADJ
eurjchem-2037	1	45	journal	journal	NOUN
eurjchem-2037	1	46	of	of	ADP
eurjchem-2037	1	47	chemistry	chemistry	NOUN
eurjchem-2037	1	48	issn	issn	VERB
eurjchem-2037	1	49	2153	2153	NUM
eurjchem-2037	1	50	-	-	SYM
eurjchem-2037	1	51	2249	2249	NUM
eurjchem-2037	1	52	(	(	PUNCT
eurjchem-2037	1	53	print	print	NOUN
eurjchem-2037	1	54	)	)	PUNCT
eurjchem-2037	1	55	/	/	PUNCT
eurjchem-2037	1	56	issn	issn	PROPN
eurjchem-2037	1	57	2153	2153	NUM
eurjchem-2037	1	58	-	-	SYM
eurjchem-2037	1	59	2257	2257	NUM
eurjchem-2037	1	60	(	(	PUNCT
eurjchem-2037	1	61	online	online	ADJ
eurjchem-2037	1	62	)	)	PUNCT
eurjchem-2037	1	63	–	–	PUNCT
eurjchem-2037	2	1	copyright	copyright	NOUN
eurjchem-2037	2	2	©	©	PROPN
eurjchem-2037	2	3	2020	2020	NUM
eurjchem-2037	2	4	the	the	DET
eurjchem-2037	2	5	authors	author	NOUN
eurjchem-2037	2	6	–	–	PUNCT
eurjchem-2037	2	7	atlanta	atlanta	PROPN
eurjchem-2037	2	8	publishing	publishing	PROPN
eurjchem-2037	2	9	house	house	PROPN
eurjchem-2037	2	10	llc	llc	PROPN
eurjchem-2037	2	11	–	–	PUNCT
eurjchem-2037	2	12	printed	print	VERB
eurjchem-2037	2	13	in	in	ADP
eurjchem-2037	2	14	the	the	DET
eurjchem-2037	2	15	usa	usa	PROPN
eurjchem-2037	2	16	.	.	PUNCT
eurjchem-2037	3	1	this	this	DET
eurjchem-2037	3	2	work	work	NOUN
eurjchem-2037	3	3	is	be	AUX
eurjchem-2037	3	4	published	publish	VERB
eurjchem-2037	3	5	and	and	CCONJ
eurjchem-2037	3	6	licensed	license	VERB
eurjchem-2037	3	7	by	by	ADP
eurjchem-2037	3	8	atlanta	atlanta	PROPN
eurjchem-2037	3	9	publishing	publishing	PROPN
eurjchem-2037	3	10	house	house	PROPN
eurjchem-2037	3	11	llc	llc	PROPN
eurjchem-2037	3	12	–	–	PUNCT
eurjchem-2037	3	13	cc	cc	PROPN
eurjchem-2037	3	14	by	by	ADP
eurjchem-2037	3	15	nc	nc	PROPN
eurjchem-2037	3	16	–	–	PUNCT
eurjchem-2037	3	17	some	some	DET
eurjchem-2037	3	18	rights	right	NOUN
eurjchem-2037	3	19	reserved	reserve	VERB
eurjchem-2037	3	20	.	.	PUNCT
eurjchem-2037	4	1	http://dx.doi.org/10.5155/eurjchem.11.4.334-341.2037	http://dx.doi.org/10.5155/eurjchem.11.4.334-341.2037	PROPN
eurjchem-2037	4	2	european	european	PROPN
eurjchem-2037	4	3	journal	journal	PROPN
eurjchem-2037	4	4	of	of	ADP
eurjchem-2037	4	5	chemistry	chemistry	NOUN
eurjchem-2037	4	6	view	view	NOUN
eurjchem-2037	4	7	journal	journal	PROPN
eurjchem-2037	4	8	online	online	PROPN
eurjchem-2037	4	9	view	view	NOUN
eurjchem-2037	4	10	article	article	NOUN
eurjchem-2037	4	11	online	online	PROPN
eurjchem-2037	4	12	imino	imino	PROPN
eurjchem-2037	4	13	-	-	PUNCT
eurjchem-2037	4	14	pyridyl	pyridyl	NOUN
eurjchem-2037	4	15	and	and	CCONJ
eurjchem-2037	4	16	pph3	pph3	PROPN
eurjchem-2037	4	17	mixed	mixed	ADJ
eurjchem-2037	4	18	ligand	ligand	NOUN
eurjchem-2037	4	19	complexes	complex	NOUN
eurjchem-2037	4	20	of	of	ADP
eurjchem-2037	4	21	cu(i)x	cu(i)x	PROPN
eurjchem-2037	4	22	(	(	PUNCT
eurjchem-2037	4	23	x	x	NOUN
eurjchem-2037	4	24	:	:	PUNCT
eurjchem-2037	4	25	i	i	PROPN
eurjchem-2037	4	26	,	,	PUNCT
eurjchem-2037	4	27	br	br	PROPN
eurjchem-2037	4	28	,	,	PUNCT
eurjchem-2037	4	29	and	and	CCONJ
eurjchem-2037	4	30	cl	cl	NOUN
eurjchem-2037	4	31	):	):	PUNCT
eurjchem-2037	4	32	synthesis	synthesis	NOUN
eurjchem-2037	4	33	,	,	PUNCT
eurjchem-2037	4	34	structure	structure	NOUN
eurjchem-2037	4	35	,	,	PUNCT
eurjchem-2037	4	36	dft	dft	PROPN
eurjchem-2037	4	37	and	and	CCONJ
eurjchem-2037	4	38	hirshfeld	hirshfeld	PROPN
eurjchem-2037	4	39	surface	surface	PROPN
eurjchem-2037	4	40	studies	studies	PROPN
eurjchem-2037	4	41	jahangir	jahangir	PROPN
eurjchem-2037	4	42	mondal	mondal	PROPN
eurjchem-2037	4	43	,	,	PUNCT
eurjchem-2037	4	44	amit	amit	PROPN
eurjchem-2037	4	45	kumar	kumar	PROPN
eurjchem-2037	4	46	manna	manna	PROPN
eurjchem-2037	4	47	and	and	CCONJ
eurjchem-2037	4	48	goutam	goutam	VERB
eurjchem-2037	4	49	kumar	kumar	PROPN
eurjchem-2037	4	50	patra	patra	PROPN
eurjchem-2037	4	51	*	*	PROPN
eurjchem-2037	4	52	department	department	PROPN
eurjchem-2037	4	53	of	of	ADP
eurjchem-2037	4	54	chemistry	chemistry	NOUN
eurjchem-2037	4	55	,	,	PUNCT
eurjchem-2037	4	56	guru	guru	NOUN
eurjchem-2037	4	57	ghasidas	ghasidas	PROPN
eurjchem-2037	4	58	vishwavidyalaya	vishwavidyalaya	PROPN
eurjchem-2037	4	59	,	,	PUNCT
eurjchem-2037	4	60	bilaspur	bilaspur	PROPN
eurjchem-2037	4	61	,	,	PUNCT
eurjchem-2037	4	62	chhattisgarh	chhattisgarh	NOUN
eurjchem-2037	4	63	,	,	PUNCT
eurjchem-2037	4	64	495009	495009	NUM
eurjchem-2037	4	65	,	,	PUNCT
eurjchem-2037	4	66	india	india	PROPN
eurjchem-2037	4	67	mailtobapi88@gmail.com	mailtobapi88@gmail.com	PROPN
eurjchem-2037	4	68	(	(	PUNCT
eurjchem-2037	4	69	j.m	j.m	PROPN
eurjchem-2037	4	70	.	.	PROPN
eurjchem-2037	4	71	)	)	PUNCT
eurjchem-2037	4	72	,	,	PUNCT
eurjchem-2037	4	73	amitmanna51@gmail.com	amitmanna51@gmail.com	X
eurjchem-2037	4	74	(	(	PUNCT
eurjchem-2037	4	75	a.k.m	a.k.m	PROPN
eurjchem-2037	4	76	.	.	PUNCT
eurjchem-2037	4	77	)	)	PUNCT
eurjchem-2037	4	78	,	,	PUNCT
eurjchem-2037	4	79	goutam.patra@ggu.ac.in	goutam.patra@ggu.ac.in	NOUN
eurjchem-2037	4	80	(	(	PUNCT
eurjchem-2037	4	81	g.k.p	g.k.p	NOUN
eurjchem-2037	4	82	.	.	PUNCT
eurjchem-2037	4	83	)	)	PUNCT
eurjchem-2037	5	1	*	*	PUNCT
eurjchem-2037	5	2	corresponding	correspond	VERB
eurjchem-2037	5	3	author	author	NOUN
eurjchem-2037	5	4	at	at	ADP
eurjchem-2037	5	5	:	:	PUNCT
eurjchem-2037	5	6	department	department	NOUN
eurjchem-2037	5	7	of	of	ADP
eurjchem-2037	5	8	chemistry	chemistry	NOUN
eurjchem-2037	5	9	,	,	PUNCT
eurjchem-2037	5	10	guru	guru	NOUN
eurjchem-2037	5	11	ghasidas	ghasidas	PROPN
eurjchem-2037	5	12	vishwavidyalaya	vishwavidyalaya	PROPN
eurjchem-2037	5	13	,	,	PUNCT
eurjchem-2037	5	14	bilaspur	bilaspur	PROPN
eurjchem-2037	5	15	,	,	PUNCT
eurjchem-2037	5	16	chhattisgarh	chhattisgarh	NOUN
eurjchem-2037	5	17	,	,	PUNCT
eurjchem-2037	5	18	495009	495009	NUM
eurjchem-2037	5	19	,	,	PUNCT
eurjchem-2037	5	20	india	india	PROPN
eurjchem-2037	5	21	.	.	PUNCT
eurjchem-2037	6	1	e	e	X
eurjchem-2037	6	2	-	-	NOUN
eurjchem-2037	6	3	mail	mail	NOUN
eurjchem-2037	6	4	:	:	PUNCT
eurjchem-2037	6	5	goutam.patra@ggu.ac.in	goutam.patra@ggu.ac.in	NOUN
eurjchem-2037	6	6	(	(	PUNCT
eurjchem-2037	6	7	g.k	g.k	PROPN
eurjchem-2037	6	8	.	.	PROPN
eurjchem-2037	6	9	patra	patra	PROPN
eurjchem-2037	6	10	)	)	PUNCT
eurjchem-2037	6	11	.	.	PUNCT
eurjchem-2037	7	1	10.5155	10.5155	NUM
eurjchem-2037	7	2	/	/	SYM
eurjchem-2037	7	3	eurjchem.11.4.334	eurjchem.11.4.334	NOUN
eurjchem-2037	7	4	-	-	SYM
eurjchem-2037	7	5	341.2037	341.2037	NUM
eurjchem-2037	7	6	received	receive	VERB
eurjchem-2037	7	7	:	:	PUNCT
eurjchem-2037	7	8	30	30	NUM
eurjchem-2037	7	9	august	august	PROPN
eurjchem-2037	7	10	2020	2020	NUM
eurjchem-2037	7	11	received	receive	VERB
eurjchem-2037	7	12	in	in	ADP
eurjchem-2037	7	13	revised	revise	VERB
eurjchem-2037	7	14	form	form	NOUN
eurjchem-2037	7	15	:	:	PUNCT
eurjchem-2037	7	16	10	10	NUM
eurjchem-2037	7	17	october	october	NOUN
eurjchem-2037	7	18	2020	2020	NUM
eurjchem-2037	7	19	accepted	accept	VERB
eurjchem-2037	7	20	:	:	PUNCT
eurjchem-2037	7	21	20	20	NUM
eurjchem-2037	7	22	october	october	NOUN
eurjchem-2037	7	23	2020	2020	NUM
eurjchem-2037	7	24	published	publish	VERB
eurjchem-2037	7	25	online	online	ADV
eurjchem-2037	7	26	:	:	PUNCT
eurjchem-2037	7	27	31	31	NUM
eurjchem-2037	7	28	december	december	PROPN
eurjchem-2037	7	29	2020	2020	NUM
eurjchem-2037	7	30	printed	print	VERB
eurjchem-2037	7	31	:	:	PUNCT
eurjchem-2037	7	32	31	31	NUM
eurjchem-2037	7	33	december	december	PROPN
eurjchem-2037	7	34	2020	2020	NUM
eurjchem-2037	7	35	three	three	NUM
eurjchem-2037	7	36	new	new	ADJ
eurjchem-2037	7	37	halide	halide	NOUN
eurjchem-2037	7	38	bridged	bridge	VERB
eurjchem-2037	7	39	copper(i)complexes	copper(i)complexe	NOUN
eurjchem-2037	8	1	[	[	X
eurjchem-2037	8	2	cu2(µ-l)(µ-x)2)(pph3)2]n	cu2(µ-l)(µ-x)2)(pph3)2]n	PROPN
eurjchem-2037	8	3	{	{	PUNCT
eurjchem-2037	8	4	x	x	NOUN
eurjchem-2037	8	5	:	:	PUNCT
eurjchem-2037	8	6	i	i	PRON
eurjchem-2037	8	7	(	(	PUNCT
eurjchem-2037	8	8	1	1	NUM
eurjchem-2037	8	9	)	)	PUNCT
eurjchem-2037	8	10	,	,	PUNCT
eurjchem-2037	8	11	br	br	PROPN
eurjchem-2037	8	12	(	(	PUNCT
eurjchem-2037	8	13	2	2	NUM
eurjchem-2037	8	14	)	)	PUNCT
eurjchem-2037	8	15	and	and	CCONJ
eurjchem-2037	8	16	cl	cl	INTJ
eurjchem-2037	8	17	(	(	PUNCT
eurjchem-2037	8	18	3	3	NUM
eurjchem-2037	8	19	)	)	PUNCT
eurjchem-2037	8	20	}	}	PUNCT
eurjchem-2037	8	21	have	have	AUX
eurjchem-2037	8	22	been	be	AUX
eurjchem-2037	8	23	synthesized	synthesize	VERB
eurjchem-2037	8	24	by	by	ADP
eurjchem-2037	8	25	the	the	DET
eurjchem-2037	8	26	reaction	reaction	NOUN
eurjchem-2037	8	27	of	of	ADP
eurjchem-2037	8	28	cu(i)x	cu(i)x	PROPN
eurjchem-2037	8	29	(	(	PUNCT
eurjchem-2037	8	30	x	x	NOUN
eurjchem-2037	8	31	:	:	PUNCT
eurjchem-2037	8	32	i	i	PRON
eurjchem-2037	8	33	,	,	PUNCT
eurjchem-2037	8	34	br	br	PROPN
eurjchem-2037	8	35	and	and	CCONJ
eurjchem-2037	8	36	cl	cl	NOUN
eurjchem-2037	8	37	)	)	PUNCT
eurjchem-2037	8	38	with	with	ADP
eurjchem-2037	8	39	pph3	pph3	NOUN
eurjchem-2037	8	40	and	and	CCONJ
eurjchem-2037	8	41	the	the	DET
eurjchem-2037	8	42	polydentate	polydentate	ADJ
eurjchem-2037	8	43	imino	imino	NOUN
eurjchem-2037	8	44	-	-	PUNCT
eurjchem-2037	8	45	pyridyl	pyridyl	ADJ
eurjchem-2037	8	46	ligand	ligand	PROPN
eurjchem-2037	8	47	l.	l.	PROPN
eurjchem-2037	8	48	interestingly	interestingly	ADV
eurjchem-2037	8	49	,	,	PUNCT
eurjchem-2037	8	50	copper(i	copper(i	NOUN
eurjchem-2037	8	51	)	)	PUNCT
eurjchem-2037	8	52	forms	form	VERB
eurjchem-2037	8	53	coordination	coordination	NOUN
eurjchem-2037	8	54	polymers	polymer	NOUN
eurjchem-2037	8	55	with	with	ADP
eurjchem-2037	8	56	the	the	DET
eurjchem-2037	8	57	ligand	ligand	ADJ
eurjchem-2037	8	58	l	l	NOUN
eurjchem-2037	8	59	and	and	CCONJ
eurjchem-2037	8	60	the	the	DET
eurjchem-2037	8	61	co	co	ADJ
eurjchem-2037	8	62	-	-	ADJ
eurjchem-2037	8	63	ligand	ligand	ADJ
eurjchem-2037	8	64	pph3	pph3	NOUN
eurjchem-2037	8	65	.	.	PUNCT
eurjchem-2037	9	1	these	these	PRON
eurjchem-2037	9	2	complexes	complexe	VERB
eurjchem-2037	9	3	1	1	NUM
eurjchem-2037	9	4	,	,	PUNCT
eurjchem-2037	9	5	2	2	NUM
eurjchem-2037	9	6	and	and	CCONJ
eurjchem-2037	9	7	3	3	NUM
eurjchem-2037	9	8	have	have	AUX
eurjchem-2037	9	9	been	be	AUX
eurjchem-2037	9	10	characterized	characterize	VERB
eurjchem-2037	9	11	by	by	ADP
eurjchem-2037	9	12	elemental	elemental	ADJ
eurjchem-2037	9	13	analysis	analysis	NOUN
eurjchem-2037	9	14	,	,	PUNCT
eurjchem-2037	9	15	ir	ir	INTJ
eurjchem-2037	9	16	,	,	PUNCT
eurjchem-2037	9	17	uv	uv	NOUN
eurjchem-2037	9	18	-	-	PUNCT
eurjchem-2037	9	19	vis	vis	X
eurjchem-2037	9	20	,	,	PUNCT
eurjchem-2037	9	21	and	and	CCONJ
eurjchem-2037	9	22	nmr	nmr	NOUN
eurjchem-2037	9	23	spectroscopy	spectroscopy	NOUN
eurjchem-2037	9	24	.	.	PUNCT
eurjchem-2037	10	1	the	the	DET
eurjchem-2037	10	2	crystal	crystal	NOUN
eurjchem-2037	10	3	structure	structure	NOUN
eurjchem-2037	10	4	of	of	ADP
eurjchem-2037	10	5	the	the	DET
eurjchem-2037	10	6	complex	complex	ADJ
eurjchem-2037	10	7	2	2	NUM
eurjchem-2037	10	8	has	have	AUX
eurjchem-2037	10	9	been	be	AUX
eurjchem-2037	10	10	determined	determine	VERB
eurjchem-2037	10	11	by	by	ADP
eurjchem-2037	10	12	single	single	ADJ
eurjchem-2037	10	13	-	-	PUNCT
eurjchem-2037	10	14	crystal	crystal	NOUN
eurjchem-2037	10	15	x	x	ADJ
eurjchem-2037	10	16	-	-	NOUN
eurjchem-2037	10	17	ray	ray	NOUN
eurjchem-2037	10	18	analysis	analysis	NOUN
eurjchem-2037	10	19	.	.	PUNCT
eurjchem-2037	11	1	crystal	crystal	NOUN
eurjchem-2037	11	2	data	datum	NOUN
eurjchem-2037	11	3	for	for	ADP
eurjchem-2037	11	4	complex	complex	ADJ
eurjchem-2037	11	5	2	2	NUM
eurjchem-2037	11	6	:	:	PUNCT
eurjchem-2037	11	7	triclinic	triclinic	ADJ
eurjchem-2037	11	8	,	,	PUNCT
eurjchem-2037	11	9	space	space	NOUN
eurjchem-2037	11	10	group	group	NOUN
eurjchem-2037	11	11	p-1	p-1	NOUN
eurjchem-2037	11	12	(	(	PUNCT
eurjchem-2037	11	13	no	no	INTJ
eurjchem-2037	11	14	.	.	NOUN
eurjchem-2037	11	15	2	2	NUM
eurjchem-2037	11	16	)	)	PUNCT
eurjchem-2037	11	17	,	,	PUNCT
eurjchem-2037	11	18	a	a	DET
eurjchem-2037	11	19	=	=	NOUN
eurjchem-2037	11	20	9.471(10	9.471(10	NUM
eurjchem-2037	11	21	)	)	PUNCT
eurjchem-2037	12	1	å	å	NOUN
eurjchem-2037	12	2	,	,	PUNCT
eurjchem-2037	12	3	b	b	X
eurjchem-2037	12	4	=	=	SYM
eurjchem-2037	12	5	11.043(11	11.043(11	NUM
eurjchem-2037	12	6	)	)	PUNCT
eurjchem-2037	12	7	å	å	NOUN
eurjchem-2037	12	8	,	,	PUNCT
eurjchem-2037	12	9	c	c	NOUN
eurjchem-2037	12	10	=	=	SYM
eurjchem-2037	12	11	13.215(18	13.215(18	NUM
eurjchem-2037	12	12	)	)	PUNCT
eurjchem-2037	12	13	å	å	NOUN
eurjchem-2037	12	14	,	,	PUNCT
eurjchem-2037	12	15	α	α	PROPN
eurjchem-2037	12	16	=	=	SYM
eurjchem-2037	12	17	65.853(18	65.853(18	NUM
eurjchem-2037	12	18	)	)	PUNCT
eurjchem-2037	12	19	°	°	PROPN
eurjchem-2037	12	20	,	,	PUNCT
eurjchem-2037	12	21	β	β	X
eurjchem-2037	12	22	=	=	SYM
eurjchem-2037	12	23	69.94(2	69.94(2	NUM
eurjchem-2037	12	24	)	)	PUNCT
eurjchem-2037	12	25	°	°	PROPN
eurjchem-2037	12	26	,	,	PUNCT
eurjchem-2037	12	27	γ	γ	NOUN
eurjchem-2037	12	28	=	=	SYM
eurjchem-2037	12	29	67.350(14	67.350(14	NUM
eurjchem-2037	12	30	)	)	PUNCT
eurjchem-2037	12	31	°	°	NOUN
eurjchem-2037	12	32	,	,	PUNCT
eurjchem-2037	12	33	v	v	NOUN
eurjchem-2037	12	34	=	=	SYM
eurjchem-2037	12	35	1135(2	1135(2	NUM
eurjchem-2037	12	36	)	)	PUNCT
eurjchem-2037	12	37	å3	å3	PROPN
eurjchem-2037	12	38	,	,	PUNCT
eurjchem-2037	12	39	z	z	NOUN
eurjchem-2037	12	40	=	=	SYM
eurjchem-2037	12	41	2	2	NUM
eurjchem-2037	12	42	,	,	PUNCT
eurjchem-2037	12	43	t	t	NOUN
eurjchem-2037	12	44	=	=	PUNCT
eurjchem-2037	12	45	296.15	296.15	NUM
eurjchem-2037	12	46	k	k	NOUN
eurjchem-2037	12	47	,	,	PUNCT
eurjchem-2037	12	48	μ(mokα	μ(mokα	NOUN
eurjchem-2037	12	49	)	)	PUNCT
eurjchem-2037	12	50	=	=	SYM
eurjchem-2037	12	51	2.806	2.806	NUM
eurjchem-2037	12	52	mm-1	mm-1	NOUN
eurjchem-2037	12	53	,	,	PUNCT
eurjchem-2037	12	54	dcalc	dcalc	NOUN
eurjchem-2037	12	55	=	=	NOUN
eurjchem-2037	12	56	1.535	1.535	NUM
eurjchem-2037	12	57	g	g	NOUN
eurjchem-2037	12	58	/	/	SYM
eurjchem-2037	12	59	cm3	cm3	NOUN
eurjchem-2037	12	60	,	,	PUNCT
eurjchem-2037	12	61	4059	4059	NUM
eurjchem-2037	12	62	reflections	reflection	NOUN
eurjchem-2037	12	63	measured	measure	VERB
eurjchem-2037	12	64	(	(	PUNCT
eurjchem-2037	12	65	3.462	3.462	NUM
eurjchem-2037	12	66	°	°	NOUN
eurjchem-2037	12	67	≤	≤	ADJ
eurjchem-2037	12	68	2θ	2θ	NUM
eurjchem-2037	12	69	≤	≤	NUM
eurjchem-2037	12	70	44.818	44.818	NUM
eurjchem-2037	12	71	°	°	NOUN
eurjchem-2037	12	72	)	)	PUNCT
eurjchem-2037	12	73	,	,	PUNCT
eurjchem-2037	12	74	2639	2639	NUM
eurjchem-2037	12	75	unique	unique	ADJ
eurjchem-2037	12	76	(	(	PUNCT
eurjchem-2037	12	77	rint	rint	NOUN
eurjchem-2037	12	78	=	=	SYM
eurjchem-2037	12	79	0.0637	0.0637	NUM
eurjchem-2037	12	80	,	,	PUNCT
eurjchem-2037	12	81	rsigma	rsigma	ADJ
eurjchem-2037	12	82	=	=	SYM
eurjchem-2037	12	83	0.1621	0.1621	NUM
eurjchem-2037	12	84	)	)	PUNCT
eurjchem-2037	12	85	which	which	PRON
eurjchem-2037	12	86	were	be	AUX
eurjchem-2037	12	87	used	use	VERB
eurjchem-2037	12	88	in	in	ADP
eurjchem-2037	12	89	all	all	DET
eurjchem-2037	12	90	calculations	calculation	NOUN
eurjchem-2037	12	91	.	.	PUNCT
eurjchem-2037	13	1	the	the	DET
eurjchem-2037	13	2	final	final	ADJ
eurjchem-2037	13	3	r1	r1	PROPN
eurjchem-2037	13	4	was	be	AUX
eurjchem-2037	13	5	0.0700	0.0700	NUM
eurjchem-2037	13	6	(	(	PUNCT
eurjchem-2037	13	7	i	i	X
eurjchem-2037	13	8	>	>	X
eurjchem-2037	13	9	2σ(i	2σ(i	NUM
eurjchem-2037	13	10	)	)	PUNCT
eurjchem-2037	13	11	)	)	PUNCT
eurjchem-2037	14	1	and	and	CCONJ
eurjchem-2037	14	2	wr2	wr2	PROPN
eurjchem-2037	14	3	was	be	AUX
eurjchem-2037	14	4	0.2207	0.2207	NUM
eurjchem-2037	14	5	(	(	PUNCT
eurjchem-2037	14	6	all	all	DET
eurjchem-2037	14	7	data	datum	NOUN
eurjchem-2037	14	8	)	)	PUNCT
eurjchem-2037	14	9	.	.	PUNCT
eurjchem-2037	15	1	hirshfeld	hirshfeld	PROPN
eurjchem-2037	15	2	surface	surface	NOUN
eurjchem-2037	15	3	analysis	analysis	NOUN
eurjchem-2037	15	4	of	of	ADP
eurjchem-2037	15	5	the	the	DET
eurjchem-2037	15	6	complex	complex	ADJ
eurjchem-2037	15	7	2	2	NUM
eurjchem-2037	15	8	showed	show	VERB
eurjchem-2037	15	9	h···h	h···h	PROPN
eurjchem-2037	15	10	,	,	PUNCT
eurjchem-2037	15	11	n···h	n···h	PROPN
eurjchem-2037	15	12	and	and	CCONJ
eurjchem-2037	15	13	br···h	br···h	PROPN
eurjchem-2037	15	14	interactions	interaction	NOUN
eurjchem-2037	15	15	of	of	ADP
eurjchem-2037	15	16	55.9	55.9	NUM
eurjchem-2037	15	17	,	,	PUNCT
eurjchem-2037	15	18	14.4	14.4	NUM
eurjchem-2037	15	19	and	and	CCONJ
eurjchem-2037	15	20	4.1	4.1	NUM
eurjchem-2037	15	21	%	%	NOUN
eurjchem-2037	15	22	,	,	PUNCT
eurjchem-2037	15	23	respectively	respectively	ADV
eurjchem-2037	15	24	.	.	PUNCT
eurjchem-2037	16	1	mep	mep	PROPN
eurjchem-2037	16	2	of	of	ADP
eurjchem-2037	16	3	ligand	ligand	PROPN
eurjchem-2037	16	4	l	l	PROPN
eurjchem-2037	16	5	reflects	reflect	VERB
eurjchem-2037	16	6	the	the	DET
eurjchem-2037	16	7	whole	whole	ADJ
eurjchem-2037	16	8	molecule	molecule	NOUN
eurjchem-2037	16	9	is	be	AUX
eurjchem-2037	16	10	reddish	reddish	ADJ
eurjchem-2037	16	11	yellow	yellow	ADJ
eurjchem-2037	16	12	in	in	ADP
eurjchem-2037	16	13	color	color	NOUN
eurjchem-2037	16	14	because	because	SCONJ
eurjchem-2037	16	15	of	of	ADP
eurjchem-2037	16	16	equally	equally	ADV
eurjchem-2037	16	17	distributed	distribute	VERB
eurjchem-2037	16	18	electron	electron	NOUN
eurjchem-2037	16	19	density	density	NOUN
eurjchem-2037	16	20	over	over	ADP
eurjchem-2037	16	21	the	the	DET
eurjchem-2037	16	22	molecule	molecule	NOUN
eurjchem-2037	16	23	.	.	PUNCT
eurjchem-2037	17	1	for	for	ADP
eurjchem-2037	17	2	this	this	DET
eurjchem-2037	17	3	reason	reason	NOUN
eurjchem-2037	17	4	,	,	PUNCT
eurjchem-2037	17	5	the	the	DET
eurjchem-2037	17	6	ligand	ligand	NOUN
eurjchem-2037	17	7	is	be	AUX
eurjchem-2037	17	8	supramolecularly	supramolecularly	ADV
eurjchem-2037	17	9	arranged	arrange	VERB
eurjchem-2037	17	10	via	via	ADP
eurjchem-2037	17	11	-{cui2-µ-x2	-{cui2-µ-x2	PUNCT
eurjchem-2037	17	12	}	}	PUNCT
eurjchem-2037	17	13	rhomboid	rhomboid	NOUN
eurjchem-2037	17	14	core	core	NOUN
eurjchem-2037	17	15	in	in	ADP
eurjchem-2037	17	16	the	the	DET
eurjchem-2037	17	17	complex	complex	ADJ
eurjchem-2037	17	18	2	2	NUM
eurjchem-2037	17	19	.	.	PUNCT
eurjchem-2037	18	1	the	the	DET
eurjchem-2037	18	2	ligand	ligand	PROPN
eurjchem-2037	18	3	l	l	NOUN
eurjchem-2037	18	4	is	be	AUX
eurjchem-2037	18	5	non	non	ADJ
eurjchem-2037	18	6	-	-	ADJ
eurjchem-2037	18	7	emissive	emissive	ADJ
eurjchem-2037	18	8	at	at	ADP
eurjchem-2037	18	9	room	room	NOUN
eurjchem-2037	18	10	temperature	temperature	NOUN
eurjchem-2037	18	11	in	in	ADP
eurjchem-2037	18	12	dichloromethane	dichloromethane	NOUN
eurjchem-2037	18	13	,	,	PUNCT
eurjchem-2037	18	14	whereas	whereas	SCONJ
eurjchem-2037	18	15	the	the	DET
eurjchem-2037	18	16	complexes	complex	NOUN
eurjchem-2037	18	17	1	1	NUM
eurjchem-2037	18	18	,	,	PUNCT
eurjchem-2037	18	19	2	2	NUM
eurjchem-2037	18	20	and	and	CCONJ
eurjchem-2037	18	21	3	3	NUM
eurjchem-2037	18	22	are	be	AUX
eurjchem-2037	18	23	photoluminescent	photoluminescent	NOUN
eurjchem-2037	18	24	.	.	PUNCT
eurjchem-2037	19	1	dft	dft	PROPN
eurjchem-2037	19	2	and	and	CCONJ
eurjchem-2037	19	3	hirshfeld	hirshfeld	PROPN
eurjchem-2037	19	4	surface	surface	PROPN
eurjchem-2037	19	5	studies	study	NOUN
eurjchem-2037	19	6	have	have	AUX
eurjchem-2037	19	7	also	also	ADV
eurjchem-2037	19	8	been	be	AUX
eurjchem-2037	19	9	performed	perform	VERB
eurjchem-2037	19	10	for	for	ADP
eurjchem-2037	19	11	complex	complex	ADJ
eurjchem-2037	19	12	2	2	NUM
eurjchem-2037	19	13	.	.	PUNCT
eurjchem-2037	19	14	dft	dft	PROPN
eurjchem-2037	19	15	imino	imino	PROPN
eurjchem-2037	19	16	-	-	PUNCT
eurjchem-2037	19	17	pyridyl	pyridyl	ADJ
eurjchem-2037	19	18	ligand	ligand	NOUN
eurjchem-2037	19	19	x	x	PROPN
eurjchem-2037	19	20	-	-	NOUN
eurjchem-2037	19	21	ray	ray	NOUN
eurjchem-2037	19	22	crystal	crystal	NOUN
eurjchem-2037	19	23	structure	structure	NOUN
eurjchem-2037	19	24	hirshfeld	hirshfeld	PROPN
eurjchem-2037	19	25	surface	surface	PROPN
eurjchem-2037	19	26	studies	study	NOUN
eurjchem-2037	19	27	bridged	bridge	VERB
eurjchem-2037	19	28	copper(i	copper(i	NOUN
eurjchem-2037	19	29	)	)	PUNCT
eurjchem-2037	19	30	complexes	complexe	VERB
eurjchem-2037	19	31	copper(i	copper(i	NOUN
eurjchem-2037	19	32	)	)	PUNCT
eurjchem-2037	19	33	coordination	coordination	NOUN
eurjchem-2037	19	34	polymer	polymer	NOUN
eurjchem-2037	19	35	cite	cite	VERB
eurjchem-2037	19	36	this	this	PRON
eurjchem-2037	19	37	:	:	PUNCT
eurjchem-2037	20	1	eur	eur	PROPN
eurjchem-2037	20	2	.	.	PUNCT
eurjchem-2037	21	1	j.	j.	PROPN
eurjchem-2037	21	2	chem	chem	PROPN
eurjchem-2037	21	3	.	.	PUNCT
eurjchem-2037	22	1	2020	2020	NUM
eurjchem-2037	22	2	,	,	PUNCT
eurjchem-2037	22	3	11(4	11(4	NUM
eurjchem-2037	22	4	)	)	PUNCT
eurjchem-2037	22	5	,	,	PUNCT
eurjchem-2037	22	6	334	334	NUM
eurjchem-2037	22	7	-	-	SYM
eurjchem-2037	22	8	341	341	NUM
eurjchem-2037	22	9	journal	journal	NOUN
eurjchem-2037	22	10	website	website	NOUN
eurjchem-2037	22	11	:	:	PUNCT
eurjchem-2037	22	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2037	22	13	1	1	X
eurjchem-2037	22	14	.	.	PUNCT
eurjchem-2037	22	15	introduction	introduction	NOUN
eurjchem-2037	22	16	in	in	ADP
eurjchem-2037	22	17	recent	recent	ADJ
eurjchem-2037	22	18	years	year	NOUN
eurjchem-2037	22	19	,	,	PUNCT
eurjchem-2037	22	20	crystal	crystal	NOUN
eurjchem-2037	22	21	engineering	engineering	NOUN
eurjchem-2037	22	22	has	have	AUX
eurjchem-2037	22	23	recognized	recognize	VERB
eurjchem-2037	22	24	the	the	DET
eurjchem-2037	22	25	intermolecular	intermolecular	ADJ
eurjchem-2037	22	26	covalent	covalent	NOUN
eurjchem-2037	22	27	and	and	CCONJ
eurjchem-2037	22	28	non	non	ADJ
eurjchem-2037	22	29	-	-	ADJ
eurjchem-2037	22	30	covalent	covalent	ADJ
eurjchem-2037	22	31	interactions	interaction	NOUN
eurjchem-2037	22	32	in	in	ADP
eurjchem-2037	22	33	terms	term	NOUN
eurjchem-2037	22	34	of	of	ADP
eurjchem-2037	22	35	self	self	NOUN
eurjchem-2037	22	36	-	-	PUNCT
eurjchem-2037	22	37	assembly	assembly	NOUN
eurjchem-2037	22	38	towards	towards	ADP
eurjchem-2037	22	39	the	the	DET
eurjchem-2037	22	40	design	design	NOUN
eurjchem-2037	22	41	of	of	ADP
eurjchem-2037	22	42	novel	novel	ADJ
eurjchem-2037	22	43	functional	functional	ADJ
eurjchem-2037	22	44	materials	material	NOUN
eurjchem-2037	22	45	[	[	X
eurjchem-2037	22	46	1	1	NUM
eurjchem-2037	22	47	-	-	SYM
eurjchem-2037	22	48	6	6	NUM
eurjchem-2037	22	49	]	]	PUNCT
eurjchem-2037	22	50	.	.	PUNCT
eurjchem-2037	23	1	studies	study	NOUN
eurjchem-2037	23	2	of	of	ADP
eurjchem-2037	23	3	copper(i	copper(i	NOUN
eurjchem-2037	23	4	)	)	PUNCT
eurjchem-2037	23	5	complexes	complex	NOUN
eurjchem-2037	23	6	with	with	ADP
eurjchem-2037	23	7	mixed	mixed	ADJ
eurjchem-2037	23	8	ligand	ligand	NOUN
eurjchem-2037	23	9	systems	system	NOUN
eurjchem-2037	23	10	containing	contain	VERB
eurjchem-2037	23	11	triphenyl	triphenyl	NOUN
eurjchem-2037	23	12	phosphine	phosphine	NOUN
eurjchem-2037	23	13	and	and	CCONJ
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eurjchem-2037	23	15	having	have	VERB
eurjchem-2037	23	16	s	s	NOUN
eurjchem-2037	23	17	and	and	CCONJ
eurjchem-2037	23	18	n	n	PRON
eurjchem-2037	23	19	donors	donor	NOUN
eurjchem-2037	23	20	have	have	AUX
eurjchem-2037	23	21	been	be	AUX
eurjchem-2037	23	22	increasing	increase	VERB
eurjchem-2037	23	23	because	because	SCONJ
eurjchem-2037	23	24	of	of	ADP
eurjchem-2037	23	25	the	the	DET
eurjchem-2037	23	26	flexibility	flexibility	NOUN
eurjchem-2037	23	27	of	of	ADP
eurjchem-2037	23	28	these	these	DET
eurjchem-2037	23	29	ligands	ligand	NOUN
eurjchem-2037	23	30	and	and	CCONJ
eurjchem-2037	23	31	the	the	DET
eurjchem-2037	23	32	different	different	ADJ
eurjchem-2037	23	33	steric	steric	ADJ
eurjchem-2037	23	34	characteristics	characteristic	NOUN
eurjchem-2037	23	35	of	of	ADP
eurjchem-2037	23	36	the	the	DET
eurjchem-2037	23	37	phosphine	phosphine	NOUN
eurjchem-2037	23	38	ligands	ligand	NOUN
eurjchem-2037	23	39	,	,	PUNCT
eurjchem-2037	23	40	which	which	PRON
eurjchem-2037	23	41	can	can	AUX
eurjchem-2037	23	42	modify	modify	VERB
eurjchem-2037	23	43	the	the	DET
eurjchem-2037	23	44	compound	compound	NOUN
eurjchem-2037	23	45	geometry	geometry	NOUN
eurjchem-2037	23	46	[	[	X
eurjchem-2037	23	47	7,8	7,8	NUM
eurjchem-2037	23	48	]	]	PUNCT
eurjchem-2037	23	49	.	.	PUNCT
eurjchem-2037	24	1	copper(i	copper(i	NOUN
eurjchem-2037	24	2	)	)	PUNCT
eurjchem-2037	24	3	halides	halide	NOUN
eurjchem-2037	24	4	have	have	AUX
eurjchem-2037	24	5	been	be	AUX
eurjchem-2037	24	6	used	use	VERB
eurjchem-2037	24	7	as	as	ADP
eurjchem-2037	24	8	the	the	DET
eurjchem-2037	24	9	inorganic	inorganic	ADJ
eurjchem-2037	24	10	component	component	NOUN
eurjchem-2037	24	11	in	in	ADP
eurjchem-2037	24	12	the	the	DET
eurjchem-2037	24	13	building	building	NOUN
eurjchem-2037	24	14	of	of	ADP
eurjchem-2037	24	15	novel	novel	ADJ
eurjchem-2037	24	16	coordination	coordination	NOUN
eurjchem-2037	24	17	polymers	polymer	NOUN
eurjchem-2037	24	18	with	with	ADP
eurjchem-2037	24	19	diverse	diverse	ADJ
eurjchem-2037	24	20	structural	structural	ADJ
eurjchem-2037	24	21	motifs	motif	NOUN
eurjchem-2037	24	22	such	such	ADJ
eurjchem-2037	24	23	as	as	ADP
eurjchem-2037	24	24	rhomboid	rhomboid	ADJ
eurjchem-2037	24	25	fragment	fragment	NOUN
eurjchem-2037	24	26	,	,	PUNCT
eurjchem-2037	24	27	cubane	cubane	NOUN
eurjchem-2037	24	28	-	-	PUNCT
eurjchem-2037	24	29	like	like	ADJ
eurjchem-2037	24	30	or	or	CCONJ
eurjchem-2037	24	31	chair	chair	NOUN
eurjchem-2037	24	32	-	-	PUNCT
eurjchem-2037	24	33	like	like	ADJ
eurjchem-2037	24	34	fragment	fragment	NOUN
eurjchem-2037	24	35	,	,	PUNCT
eurjchem-2037	24	36	one	one	NUM
eurjchem-2037	24	37	-	-	PUNCT
eurjchem-2037	24	38	dimensional	dimensional	ADJ
eurjchem-2037	24	39	ladder	ladder	NOUN
eurjchem-2037	24	40	strand	strand	NOUN
eurjchem-2037	24	41	or	or	CCONJ
eurjchem-2037	24	42	zig	zig	VERB
eurjchem-2037	24	43	-	-	PUNCT
eurjchem-2037	24	44	zag	zag	NOUN
eurjchem-2037	24	45	chain	chain	NOUN
eurjchem-2037	24	46	[	[	X
eurjchem-2037	24	47	9	9	NUM
eurjchem-2037	24	48	]	]	PUNCT
eurjchem-2037	24	49	.	.	PUNCT
eurjchem-2037	25	1	cu(i)-complexes	cu(i)-complexe	NOUN
eurjchem-2037	25	2	are	be	AUX
eurjchem-2037	25	3	well	well	ADV
eurjchem-2037	25	4	known	known	ADJ
eurjchem-2037	25	5	for	for	ADP
eurjchem-2037	25	6	their	their	PRON
eurjchem-2037	25	7	enriched	enrich	VERB
eurjchem-2037	25	8	photoluminescence	photoluminescence	NOUN
eurjchem-2037	25	9	properties	property	NOUN
eurjchem-2037	25	10	and	and	CCONJ
eurjchem-2037	25	11	their	their	PRON
eurjchem-2037	25	12	potential	potential	ADJ
eurjchem-2037	25	13	applications	application	NOUN
eurjchem-2037	25	14	in	in	ADP
eurjchem-2037	25	15	solar	solar	ADJ
eurjchem-2037	25	16	energy	energy	NOUN
eurjchem-2037	25	17	conversion	conversion	NOUN
eurjchem-2037	25	18	,	,	PUNCT
eurjchem-2037	25	19	lightemitting	lightemitte	VERB
eurjchem-2037	25	20	devices	device	NOUN
eurjchem-2037	25	21	,	,	PUNCT
eurjchem-2037	25	22	luminescence	luminescence	NOUN
eurjchem-2037	25	23	-	-	PUNCT
eurjchem-2037	25	24	based	base	VERB
eurjchem-2037	25	25	sensors	sensor	NOUN
eurjchem-2037	25	26	,	,	PUNCT
eurjchem-2037	25	27	and	and	CCONJ
eurjchem-2037	25	28	probes	probe	NOUN
eurjchem-2037	25	29	of	of	ADP
eurjchem-2037	25	30	biological	biological	ADJ
eurjchem-2037	25	31	systems	system	NOUN
eurjchem-2037	25	32	[	[	X
eurjchem-2037	25	33	10	10	NUM
eurjchem-2037	25	34	-	-	SYM
eurjchem-2037	25	35	15	15	NUM
eurjchem-2037	25	36	]	]	PUNCT
eurjchem-2037	25	37	.	.	PUNCT
eurjchem-2037	26	1	numerous	numerous	ADJ
eurjchem-2037	26	2	cu(i)-complexes	cu(i)-complexe	NOUN
eurjchem-2037	26	3	such	such	ADJ
eurjchem-2037	26	4	as	as	ADP
eurjchem-2037	26	5	discrete	discrete	ADJ
eurjchem-2037	26	6	monomers	monomer	NOUN
eurjchem-2037	26	7	,	,	PUNCT
eurjchem-2037	26	8	dimeric	dimeric	ADJ
eurjchem-2037	26	9	clusters	cluster	NOUN
eurjchem-2037	26	10	and	and	CCONJ
eurjchem-2037	26	11	1d	1d	NUM
eurjchem-2037	26	12	coordination	coordination	NOUN
eurjchem-2037	26	13	chains	chain	NOUN
eurjchem-2037	26	14	have	have	AUX
eurjchem-2037	26	15	been	be	AUX
eurjchem-2037	26	16	reported	report	VERB
eurjchem-2037	26	17	by	by	ADP
eurjchem-2037	26	18	several	several	ADJ
eurjchem-2037	26	19	researchers	researcher	NOUN
eurjchem-2037	26	20	[	[	X
eurjchem-2037	26	21	16	16	NUM
eurjchem-2037	26	22	-	-	SYM
eurjchem-2037	26	23	18	18	NUM
eurjchem-2037	26	24	]	]	PUNCT
eurjchem-2037	26	25	.	.	PUNCT
eurjchem-2037	27	1	most	most	ADJ
eurjchem-2037	27	2	of	of	ADP
eurjchem-2037	27	3	the	the	DET
eurjchem-2037	27	4	complexes	complex	NOUN
eurjchem-2037	27	5	contain	contain	VERB
eurjchem-2037	27	6	halide	halide	NOUN
eurjchem-2037	27	7	as	as	ADP
eurjchem-2037	27	8	the	the	DET
eurjchem-2037	27	9	counter	counter	NOUN
eurjchem-2037	27	10	anion	anion	NOUN
eurjchem-2037	27	11	in	in	ADP
eurjchem-2037	27	12	combination	combination	NOUN
eurjchem-2037	27	13	with	with	ADP
eurjchem-2037	27	14	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2037	27	15	and	and	CCONJ
eurjchem-2037	27	16	n	n	CCONJ
eurjchem-2037	27	17	-	-	PUNCT
eurjchem-2037	27	18	heterocyclic	heterocyclic	ADJ
eurjchem-2037	27	19	molecules	molecule	NOUN
eurjchem-2037	27	20	as	as	ADP
eurjchem-2037	27	21	the	the	DET
eurjchem-2037	27	22	ligand	ligand	NOUN
eurjchem-2037	27	23	.	.	PUNCT
eurjchem-2037	28	1	the	the	DET
eurjchem-2037	28	2	electronic	electronic	ADJ
eurjchem-2037	28	3	and	and	CCONJ
eurjchem-2037	28	4	structural	structural	ADJ
eurjchem-2037	28	5	characteristics	characteristic	NOUN
eurjchem-2037	28	6	of	of	ADP
eurjchem-2037	28	7	the	the	DET
eurjchem-2037	28	8	nheterocyclic	nheterocyclic	ADJ
eurjchem-2037	28	9	ligands	ligand	NOUN
eurjchem-2037	28	10	play	play	VERB
eurjchem-2037	28	11	an	an	DET
eurjchem-2037	28	12	important	important	ADJ
eurjchem-2037	28	13	role	role	NOUN
eurjchem-2037	28	14	in	in	ADP
eurjchem-2037	28	15	determining	determine	VERB
eurjchem-2037	28	16	the	the	DET
eurjchem-2037	28	17	structure	structure	NOUN
eurjchem-2037	28	18	of	of	ADP
eurjchem-2037	28	19	the	the	DET
eurjchem-2037	28	20	polynuclear	polynuclear	NOUN
eurjchem-2037	28	21	complexes	complex	NOUN
eurjchem-2037	28	22	and	and	CCONJ
eurjchem-2037	28	23	consequently	consequently	ADV
eurjchem-2037	28	24	their	their	PRON
eurjchem-2037	28	25	photophysical	photophysical	ADJ
eurjchem-2037	28	26	properties	property	NOUN
eurjchem-2037	28	27	[	[	X
eurjchem-2037	28	28	19	19	NUM
eurjchem-2037	28	29	-	-	SYM
eurjchem-2037	28	30	21	21	NUM
eurjchem-2037	28	31	]	]	PUNCT
eurjchem-2037	28	32	.	.	PUNCT
eurjchem-2037	29	1	in	in	ADP
eurjchem-2037	29	2	addition	addition	NOUN
eurjchem-2037	29	3	,	,	PUNCT
eurjchem-2037	29	4	the	the	DET
eurjchem-2037	29	5	ancillary	ancillary	ADJ
eurjchem-2037	29	6	ligands	ligand	NOUN
eurjchem-2037	29	7	such	such	ADJ
eurjchem-2037	29	8	as	as	ADP
eurjchem-2037	29	9	halide	halide	NOUN
eurjchem-2037	29	10	and	and	CCONJ
eurjchem-2037	29	11	phosphine	phosphine	NOUN
eurjchem-2037	29	12	also	also	ADV
eurjchem-2037	29	13	have	have	VERB
eurjchem-2037	29	14	great	great	ADJ
eurjchem-2037	29	15	effects	effect	NOUN
eurjchem-2037	29	16	on	on	ADP
eurjchem-2037	29	17	the	the	DET
eurjchem-2037	29	18	emissive	emissive	ADJ
eurjchem-2037	29	19	properties	property	NOUN
eurjchem-2037	29	20	of	of	ADP
eurjchem-2037	29	21	the	the	DET
eurjchem-2037	29	22	cu(i)-complexes	cu(i)-complexe	NOUN
eurjchem-2037	29	23	[	[	X
eurjchem-2037	29	24	22	22	NUM
eurjchem-2037	29	25	-	-	SYM
eurjchem-2037	29	26	25	25	NUM
eurjchem-2037	29	27	]	]	PUNCT
eurjchem-2037	29	28	.	.	PUNCT
eurjchem-2037	30	1	analysis	analysis	NOUN
eurjchem-2037	30	2	of	of	ADP
eurjchem-2037	30	3	the	the	DET
eurjchem-2037	30	4	self	self	NOUN
eurjchem-2037	30	5	-	-	PUNCT
eurjchem-2037	30	6	assembly	assembly	NOUN
eurjchem-2037	30	7	for	for	ADP
eurjchem-2037	30	8	various	various	ADJ
eurjchem-2037	30	9	intermolecular	intermolecular	ADJ
eurjchem-2037	30	10	interactions	interaction	NOUN
eurjchem-2037	30	11	like	like	ADP
eurjchem-2037	30	12	hydrogen	hydrogen	NOUN
eurjchem-2037	30	13	bonding	bonding	NOUN
eurjchem-2037	30	14	or	or	CCONJ
eurjchem-2037	30	15	π	π	PROPN
eurjchem-2037	30	16	-	-	PROPN
eurjchem-2037	30	17	π	π	ADJ
eurjchem-2037	30	18	stacking	stacking	NOUN
eurjchem-2037	30	19	is	be	AUX
eurjchem-2037	30	20	important	important	ADJ
eurjchem-2037	30	21	to	to	PART
eurjchem-2037	30	22	understand	understand	VERB
eurjchem-2037	30	23	how	how	SCONJ
eurjchem-2037	30	24	molecules	molecule	NOUN
eurjchem-2037	30	25	interact	interact	VERB
eurjchem-2037	30	26	with	with	ADP
eurjchem-2037	30	27	their	their	PRON
eurjchem-2037	30	28	direct	direct	ADJ
eurjchem-2037	30	29	environment	environment	NOUN
eurjchem-2037	30	30	and	and	CCONJ
eurjchem-2037	30	31	focus	focus	VERB
eurjchem-2037	30	32	on	on	ADP
eurjchem-2037	30	33	insight	insight	NOUN
eurjchem-2037	30	34	into	into	ADP
eurjchem-2037	30	35	crystal	crystal	NOUN
eurjchem-2037	30	36	packing	packing	NOUN
eurjchem-2037	30	37	behavior	behavior	NOUN
eurjchem-2037	30	38	.	.	PUNCT
eurjchem-2037	31	1	hirshfeld	hirshfeld	PROPN
eurjchem-2037	31	2	surface	surface	NOUN
eurjchem-2037	31	3	-	-	PUNCT
eurjchem-2037	31	4	based	base	VERB
eurjchem-2037	31	5	tools	tool	NOUN
eurjchem-2037	31	6	appear	appear	VERB
eurjchem-2037	31	7	as	as	ADP
eurjchem-2037	31	8	a	a	DET
eurjchem-2037	31	9	novel	novel	ADJ
eurjchem-2037	31	10	approach	approach	NOUN
eurjchem-2037	31	11	to	to	ADP
eurjchem-2037	31	12	this	this	DET
eurjchem-2037	31	13	end	end	NOUN
eurjchem-2037	31	14	[	[	X
eurjchem-2037	31	15	26	26	NUM
eurjchem-2037	31	16	-	-	SYM
eurjchem-2037	31	17	31	31	NUM
eurjchem-2037	31	18	]	]	PUNCT
eurjchem-2037	31	19	.	.	PUNCT
eurjchem-2037	32	1	the	the	DET
eurjchem-2037	32	2	central	central	ADJ
eurjchem-2037	32	3	element	element	NOUN
eurjchem-2037	32	4	in	in	ADP
eurjchem-2037	32	5	this	this	DET
eurjchem-2037	32	6	method	method	NOUN
eurjchem-2037	32	7	is	be	AUX
eurjchem-2037	32	8	the	the	DET
eurjchem-2037	32	9	derivation	derivation	NOUN
eurjchem-2037	32	10	of	of	ADP
eurjchem-2037	32	11	the	the	DET
eurjchem-2037	32	12	hirshfeld	hirshfeld	PROPN
eurjchem-2037	32	13	surface	surface	NOUN
eurjchem-2037	32	14	and	and	CCONJ
eurjchem-2037	32	15	immediately	immediately	ADV
eurjchem-2037	32	16	interpretable	interpretable	ADJ
eurjchem-2037	32	17	visualization	visualization	NOUN
eurjchem-2037	32	18	of	of	ADP
eurjchem-2037	32	19	a	a	DET
eurjchem-2037	32	20	molecule	molecule	NOUN
eurjchem-2037	32	21	within	within	ADP
eurjchem-2037	32	22	its	its	PRON
eurjchem-2037	32	23	environment	environment	NOUN
eurjchem-2037	32	24	,	,	PUNCT
eurjchem-2037	32	25	and	and	CCONJ
eurjchem-2037	32	26	the	the	DET
eurjchem-2037	32	27	decomposition	decomposition	NOUN
eurjchem-2037	32	28	of	of	ADP
eurjchem-2037	32	29	this	this	DET
eurjchem-2037	32	30	surface	surface	NOUN
eurjchem-2037	32	31	to	to	PART
eurjchem-2037	32	32	provide	provide	VERB
eurjchem-2037	32	33	a	a	DET
eurjchem-2037	32	34	directly	directly	ADV
eurjchem-2037	32	35	accessible	accessible	ADJ
eurjchem-2037	32	36	2d	2d	NUM
eurjchem-2037	32	37	map	map	NOUN
eurjchem-2037	32	38	[	[	X
eurjchem-2037	32	39	32	32	NUM
eurjchem-2037	32	40	]	]	PUNCT
eurjchem-2037	32	41	as	as	ADP
eurjchem-2037	32	42	“	"	PUNCT
eurjchem-2037	32	43	molecular	molecular	ADJ
eurjchem-2037	32	44	fingerprint	fingerprint	NOUN
eurjchem-2037	32	45	”	"	PUNCT
eurjchem-2037	32	46	.	.	PUNCT
eurjchem-2037	33	1	in	in	ADP
eurjchem-2037	33	2	continuation	continuation	NOUN
eurjchem-2037	33	3	of	of	ADP
eurjchem-2037	33	4	our	our	PRON
eurjchem-2037	33	5	studies	study	NOUN
eurjchem-2037	33	6	on	on	ADP
eurjchem-2037	33	7	the	the	DET
eurjchem-2037	33	8	cu(i	cu(i	NOUN
eurjchem-2037	33	9	)	)	PUNCT
eurjchem-2037	33	10	coordination	coordination	NOUN
eurjchem-2037	33	11	polymers	polymer	NOUN
eurjchem-2037	33	12	of	of	ADP
eurjchem-2037	33	13	imino	imino	NOUN
eurjchem-2037	33	14	-	-	PUNCT
eurjchem-2037	33	15	pyridyl	pyridyl	ADJ
eurjchem-2037	33	16	ligands	ligand	NOUN
eurjchem-2037	33	17	,	,	PUNCT
eurjchem-2037	33	18	we	we	PRON
eurjchem-2037	33	19	have	have	AUX
eurjchem-2037	33	20	reported	report	VERB
eurjchem-2037	33	21	here	here	ADV
eurjchem-2037	33	22	the	the	DET
eurjchem-2037	33	23	synthesis	synthesis	NOUN
eurjchem-2037	33	24	,	,	PUNCT
eurjchem-2037	33	25	structure	structure	NOUN
eurjchem-2037	33	26	,	,	PUNCT
eurjchem-2037	33	27	spectroscopic	spectroscopic	NOUN
eurjchem-2037	33	28	,	,	PUNCT
eurjchem-2037	33	29	photophysical	photophysical	ADJ
eurjchem-2037	33	30	,	,	PUNCT
eurjchem-2037	33	31	and	and	CCONJ
eurjchem-2037	33	32	theoretical	theoretical	ADJ
eurjchem-2037	33	33	studies	study	NOUN
eurjchem-2037	33	34	of	of	ADP
eurjchem-2037	33	35	halide	halide	NOUN
eurjchem-2037	33	36	-	-	PUNCT
eurjchem-2037	33	37	based	base	VERB
eurjchem-2037	33	38	cu(i	cu(i	NOUN
eurjchem-2037	33	39	)	)	PUNCT
eurjchem-2037	33	40	complexes	complex	NOUN
eurjchem-2037	33	41	1	1	NUM
eurjchem-2037	33	42	,	,	PUNCT
eurjchem-2037	33	43	2	2	NUM
eurjchem-2037	33	44	and	and	CCONJ
eurjchem-2037	33	45	3	3	NUM
eurjchem-2037	33	46	of	of	ADP
eurjchem-2037	33	47	a	a	DET
eurjchem-2037	33	48	polydentate	polydentate	ADJ
eurjchem-2037	33	49	imino	imino	NOUN
eurjchem-2037	33	50	-	-	PUNCT
eurjchem-2037	33	51	pyridyl	pyridyl	ADJ
eurjchem-2037	33	52	ligand	ligand	NOUN
eurjchem-2037	33	53	(	(	PUNCT
eurjchem-2037	33	54	l	l	NOUN
eurjchem-2037	33	55	)	)	PUNCT
eurjchem-2037	33	56	(	(	PUNCT
eurjchem-2037	33	57	scheme	scheme	NOUN
eurjchem-2037	33	58	1	1	NUM
eurjchem-2037	33	59	)	)	PUNCT
eurjchem-2037	33	60	.	.	PUNCT
eurjchem-2037	34	1	abstract	abstract	ADJ
eurjchem-2037	34	2	research	research	NOUN
eurjchem-2037	34	3	article	article	NOUN
eurjchem-2037	34	4	keywords	keyword	VERB
eurjchem-2037	34	5	http://dx.doi.org/10.5155/eurjchem.11.4.334-341.2037	http://dx.doi.org/10.5155/eurjchem.11.4.334-341.2037	NOUN
eurjchem-2037	34	6	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2037	34	7	http://dx.doi.org/10.5155/eurjchem.11.4.334-341.2037	http://dx.doi.org/10.5155/eurjchem.11.4.334-341.2037	NOUN
eurjchem-2037	34	8	mailto:mailtobapi88@gmail.com	mailto:mailtobapi88@gmail.com	X
eurjchem-2037	34	9	mailto:amitmanna51@gmail.com	mailto:amitmanna51@gmail.com	PROPN
eurjchem-2037	34	10	mailto:goutam.patra@ggu.ac.in	mailto:goutam.patra@ggu.ac.in	PROPN
eurjchem-2037	34	11	mailto:goutam.patra@ggu.ac.in	mailto:goutam.patra@ggu.ac.in	PROPN
eurjchem-2037	34	12	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2037	34	13	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.11.4.334-341.2037&domain=pdf&date_stamp=2020-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.11.4.334-341.2037&domain=pdf&date_stamp=2020-12-31	NOUN
eurjchem-2037	34	14	mondal	mondal	PROPN
eurjchem-2037	34	15	et	et	PROPN
eurjchem-2037	34	16	al	al	PROPN
eurjchem-2037	34	17	.	.	PUNCT
eurjchem-2037	34	18	/	/	SYM
eurjchem-2037	34	19	european	european	PROPN
eurjchem-2037	34	20	journal	journal	PROPN
eurjchem-2037	34	21	of	of	ADP
eurjchem-2037	34	22	chemistry	chemistry	NOUN
eurjchem-2037	34	23	11	11	NUM
eurjchem-2037	34	24	(	(	PUNCT
eurjchem-2037	34	25	4	4	NUM
eurjchem-2037	34	26	)	)	PUNCT
eurjchem-2037	34	27	(	(	PUNCT
eurjchem-2037	34	28	2020	2020	NUM
eurjchem-2037	34	29	)	)	PUNCT
eurjchem-2037	34	30	334	334	NUM
eurjchem-2037	34	31	-	-	SYM
eurjchem-2037	34	32	341	341	NUM
eurjchem-2037	34	33	335	335	NUM
eurjchem-2037	34	34	2020	2020	NUM
eurjchem-2037	34	35	–	–	PUNCT
eurjchem-2037	34	36	european	european	ADJ
eurjchem-2037	34	37	journal	journal	NOUN
eurjchem-2037	34	38	of	of	ADP
eurjchem-2037	34	39	chemistry	chemistry	NOUN
eurjchem-2037	34	40	–	–	PUNCT
eurjchem-2037	34	41	cc	cc	NOUN
eurjchem-2037	34	42	by	by	ADP
eurjchem-2037	34	43	nc	nc	PROPN
eurjchem-2037	34	44	–	–	PUNCT
eurjchem-2037	34	45	doi	doi	NOUN
eurjchem-2037	34	46	:	:	PUNCT
eurjchem-2037	34	47	10.5155	10.5155	NUM
eurjchem-2037	34	48	/	/	SYM
eurjchem-2037	34	49	eurjchem.11.4.334	eurjchem.11.4.334	NOUN
eurjchem-2037	34	50	-	-	SYM
eurjchem-2037	34	51	341.2037	341.2037	NUM
eurjchem-2037	34	52	n	n	CCONJ
eurjchem-2037	34	53	n	n	CCONJ
eurjchem-2037	34	54	nn	nn	PROPN
eurjchem-2037	34	55	l	l	NOUN
eurjchem-2037	34	56	scheme	scheme	NOUN
eurjchem-2037	34	57	1	1	NUM
eurjchem-2037	34	58	.	.	X
eurjchem-2037	34	59	ligand	ligand	PROPN
eurjchem-2037	34	60	(	(	PUNCT
eurjchem-2037	34	61	l	l	NOUN
eurjchem-2037	34	62	)	)	PUNCT
eurjchem-2037	34	63	system	system	NOUN
eurjchem-2037	34	64	used	use	VERB
eurjchem-2037	34	65	in	in	ADP
eurjchem-2037	34	66	this	this	DET
eurjchem-2037	34	67	study	study	NOUN
eurjchem-2037	34	68	.	.	PUNCT
eurjchem-2037	35	1	2	2	NUM
eurjchem-2037	35	2	cux	cux	NOUN
eurjchem-2037	35	3	+	+	CCONJ
eurjchem-2037	35	4	2	2	NUM
eurjchem-2037	35	5	pph3	pph3	NOUN
eurjchem-2037	35	6	cu	cu	PROPN
eurjchem-2037	35	7	cu	cu	PROPN
eurjchem-2037	35	8	x	x	PUNCT
eurjchem-2037	35	9	x	x	X
eurjchem-2037	35	10	pph3ph3p	pph3ph3p	X
eurjchem-2037	35	11	nn	nn	X
eurjchem-2037	35	12	n	n	CCONJ
eurjchem-2037	35	13	ncu	ncu	PROPN
eurjchem-2037	35	14	cu	cu	PROPN
eurjchem-2037	35	15	x	x	PUNCT
eurjchem-2037	35	16	x	x	SYM
eurjchem-2037	35	17	pph3	pph3	NOUN
eurjchem-2037	35	18	ph3p	ph3p	PROPN
eurjchem-2037	35	19	(	(	PUNCT
eurjchem-2037	35	20	x	x	NOUN
eurjchem-2037	35	21	:	:	PUNCT
eurjchem-2037	35	22	i	i	PRON
eurjchem-2037	35	23	,	,	PUNCT
eurjchem-2037	35	24	br	br	PROPN
eurjchem-2037	35	25	,	,	PUNCT
eurjchem-2037	35	26	cl	cl	NOUN
eurjchem-2037	35	27	)	)	PUNCT
eurjchem-2037	35	28	ch2cl2	ch2cl2	NOUN
eurjchem-2037	35	29	rt	rt	PROPN
eurjchem-2037	35	30	(	(	PUNCT
eurjchem-2037	35	31	1	1	NUM
eurjchem-2037	35	32	)	)	PUNCT
eurjchem-2037	35	33	x	x	NOUN
eurjchem-2037	35	34	:	:	PUNCT
eurjchem-2037	35	35	i	i	PRON
eurjchem-2037	35	36	(	(	PUNCT
eurjchem-2037	35	37	2	2	NUM
eurjchem-2037	35	38	)	)	PUNCT
eurjchem-2037	35	39	x	x	NOUN
eurjchem-2037	35	40	:	:	PUNCT
eurjchem-2037	35	41	br	br	PROPN
eurjchem-2037	35	42	(	(	PUNCT
eurjchem-2037	35	43	3	3	NUM
eurjchem-2037	35	44	)	)	PUNCT
eurjchem-2037	35	45	x	x	NOUN
eurjchem-2037	35	46	:	:	PUNCT
eurjchem-2037	35	47	cl	cl	NOUN
eurjchem-2037	35	48	nn	nn	PROPN
eurjchem-2037	35	49	n	n	CCONJ
eurjchem-2037	35	50	n	n	CCONJ
eurjchem-2037	35	51	nn	nn	PROPN
eurjchem-2037	35	52	n	n	CCONJ
eurjchem-2037	35	53	n	n	PROPN
eurjchem-2037	35	54	(	(	PUNCT
eurjchem-2037	35	55	l	l	NOUN
eurjchem-2037	35	56	)	)	PUNCT
eurjchem-2037	35	57	2:2:1	2:2:1	NUM
eurjchem-2037	35	58	scheme	scheme	NOUN
eurjchem-2037	35	59	2	2	NUM
eurjchem-2037	35	60	.	.	PUNCT
eurjchem-2037	35	61	synthetic	synthetic	ADJ
eurjchem-2037	35	62	route	route	NOUN
eurjchem-2037	35	63	of	of	ADP
eurjchem-2037	35	64	the	the	DET
eurjchem-2037	35	65	complexes	complex	NOUN
eurjchem-2037	35	66	1	1	NUM
eurjchem-2037	35	67	,	,	PUNCT
eurjchem-2037	35	68	2	2	NUM
eurjchem-2037	35	69	and	and	CCONJ
eurjchem-2037	35	70	3	3	NUM
eurjchem-2037	35	71	.	.	NOUN
eurjchem-2037	35	72	2	2	NUM
eurjchem-2037	35	73	.	.	X
eurjchem-2037	35	74	experimental	experimental	ADJ
eurjchem-2037	35	75	2.1	2.1	NUM
eurjchem-2037	35	76	.	.	PUNCT
eurjchem-2037	36	1	materials	material	NOUN
eurjchem-2037	36	2	and	and	CCONJ
eurjchem-2037	36	3	physical	physical	ADJ
eurjchem-2037	36	4	measurements	measurement	NOUN
eurjchem-2037	36	5	all	all	DET
eurjchem-2037	36	6	chemicals	chemical	NOUN
eurjchem-2037	36	7	used	use	VERB
eurjchem-2037	36	8	in	in	ADP
eurjchem-2037	36	9	this	this	DET
eurjchem-2037	36	10	study	study	NOUN
eurjchem-2037	36	11	were	be	AUX
eurjchem-2037	36	12	purchased	purchase	VERB
eurjchem-2037	36	13	from	from	ADP
eurjchem-2037	36	14	aldrich	aldrich	PROPN
eurjchem-2037	36	15	chemical	chemical	PROPN
eurjchem-2037	36	16	company	company	NOUN
eurjchem-2037	36	17	,	,	PUNCT
eurjchem-2037	36	18	usa	usa	PROPN
eurjchem-2037	36	19	and	and	CCONJ
eurjchem-2037	36	20	acros	acros	PROPN
eurjchem-2037	36	21	chemical	chemical	PROPN
eurjchem-2037	36	22	company	company	PROPN
eurjchem-2037	36	23	,	,	PUNCT
eurjchem-2037	36	24	usa	usa	PROPN
eurjchem-2037	36	25	,	,	PUNCT
eurjchem-2037	36	26	and	and	CCONJ
eurjchem-2037	36	27	used	use	VERB
eurjchem-2037	36	28	without	without	ADP
eurjchem-2037	36	29	further	further	ADJ
eurjchem-2037	36	30	purification	purification	NOUN
eurjchem-2037	36	31	unless	unless	SCONJ
eurjchem-2037	36	32	otherwise	otherwise	ADV
eurjchem-2037	36	33	mentioned	mention	VERB
eurjchem-2037	36	34	.	.	PUNCT
eurjchem-2037	37	1	the	the	DET
eurjchem-2037	37	2	melting	melting	NOUN
eurjchem-2037	37	3	point	point	NOUN
eurjchem-2037	37	4	was	be	AUX
eurjchem-2037	37	5	determined	determine	VERB
eurjchem-2037	37	6	by	by	ADP
eurjchem-2037	37	7	an	an	DET
eurjchem-2037	37	8	electrothermal	electrothermal	ADJ
eurjchem-2037	37	9	ia9000	ia9000	PROPN
eurjchem-2037	37	10	series	series	NOUN
eurjchem-2037	37	11	digital	digital	ADJ
eurjchem-2037	37	12	melting	melting	NOUN
eurjchem-2037	37	13	point	point	NOUN
eurjchem-2037	37	14	apparatus	apparatus	NOUN
eurjchem-2037	37	15	and	and	CCONJ
eurjchem-2037	37	16	is	be	AUX
eurjchem-2037	37	17	uncorrected	uncorrecte	VERB
eurjchem-2037	37	18	.	.	PUNCT
eurjchem-2037	38	1	microanalyses	microanalysis	NOUN
eurjchem-2037	38	2	were	be	AUX
eurjchem-2037	38	3	carried	carry	VERB
eurjchem-2037	38	4	out	out	ADP
eurjchem-2037	38	5	using	use	VERB
eurjchem-2037	38	6	a	a	DET
eurjchem-2037	38	7	perkinelmer	perkinelmer	ADJ
eurjchem-2037	38	8	2400ii	2400ii	ADJ
eurjchem-2037	38	9	elemental	elemental	ADJ
eurjchem-2037	38	10	analyzer	analyzer	NOUN
eurjchem-2037	38	11	.	.	PUNCT
eurjchem-2037	39	1	infra	infra	NOUN
eurjchem-2037	39	2	-	-	PUNCT
eurjchem-2037	39	3	red	red	ADJ
eurjchem-2037	39	4	(	(	PUNCT
eurjchem-2037	39	5	ir	ir	NOUN
eurjchem-2037	39	6	)	)	PUNCT
eurjchem-2037	39	7	spectra	spectra	NOUN
eurjchem-2037	39	8	and	and	CCONJ
eurjchem-2037	39	9	solution	solution	NOUN
eurjchem-2037	39	10	electronic	electronic	ADJ
eurjchem-2037	39	11	spectra	spectra	NOUN
eurjchem-2037	39	12	were	be	AUX
eurjchem-2037	39	13	recorded	record	VERB
eurjchem-2037	39	14	on	on	ADP
eurjchem-2037	39	15	nicolet	nicolet	PROPN
eurjchem-2037	39	16	magna	magna	PROPN
eurjchem-2037	39	17	ir	ir	PROPN
eurjchem-2037	39	18	(	(	PUNCT
eurjchem-2037	39	19	series	series	PROPN
eurjchem-2037	39	20	ii	ii	PROPN
eurjchem-2037	39	21	)	)	PUNCT
eurjchem-2037	39	22	and	and	CCONJ
eurjchem-2037	39	23	shimadzu	shimadzu	ADJ
eurjchem-2037	39	24	uv-160a	uv-160a	NOUN
eurjchem-2037	39	25	spectrophotometers	spectrophotometer	NOUN
eurjchem-2037	39	26	,	,	PUNCT
eurjchem-2037	39	27	respectively	respectively	ADV
eurjchem-2037	39	28	.	.	PUNCT
eurjchem-2037	40	1	1h	1h	NUM
eurjchem-2037	40	2	nmr	nmr	NOUN
eurjchem-2037	40	3	and	and	CCONJ
eurjchem-2037	40	4	13c	13c	NOUN
eurjchem-2037	40	5	nmr	nmr	NOUN
eurjchem-2037	40	6	and	and	CCONJ
eurjchem-2037	40	7	electro	electro	ADJ
eurjchem-2037	40	8	-	-	PUNCT
eurjchem-2037	40	9	spray	spray	NOUN
eurjchem-2037	40	10	ionization	ionization	NOUN
eurjchem-2037	40	11	mass	mass	NOUN
eurjchem-2037	40	12	(	(	PUNCT
eurjchem-2037	40	13	esi	esi	PROPN
eurjchem-2037	40	14	-	-	ADJ
eurjchem-2037	40	15	ms	ms	ADJ
eurjchem-2037	40	16	)	)	PUNCT
eurjchem-2037	40	17	measurements	measurement	NOUN
eurjchem-2037	40	18	were	be	AUX
eurjchem-2037	40	19	made	make	VERB
eurjchem-2037	40	20	using	use	VERB
eurjchem-2037	40	21	a	a	DET
eurjchem-2037	40	22	bruker	bruker	NOUN
eurjchem-2037	40	23	advance	advance	NOUN
eurjchem-2037	40	24	400	400	NUM
eurjchem-2037	40	25	mhz	mhz	NOUN
eurjchem-2037	40	26	and	and	CCONJ
eurjchem-2037	40	27	finnigan	finnigan	ADJ
eurjchem-2037	40	28	lcq	lcq	PROPN
eurjchem-2037	40	29	decaxp	decaxp	PROPN
eurjchem-2037	40	30	max	max	PROPN
eurjchem-2037	40	31	mass	mass	PROPN
eurjchem-2037	40	32	spectrometer	spectrometer	NOUN
eurjchem-2037	40	33	,	,	PUNCT
eurjchem-2037	40	34	respectively	respectively	ADV
eurjchem-2037	40	35	.	.	PUNCT
eurjchem-2037	41	1	x	x	X
eurjchem-2037	41	2	-	-	NOUN
eurjchem-2037	41	3	ray	ray	NOUN
eurjchem-2037	41	4	powder	powder	NOUN
eurjchem-2037	41	5	patterns	pattern	NOUN
eurjchem-2037	41	6	are	be	AUX
eurjchem-2037	41	7	collected	collect	VERB
eurjchem-2037	41	8	on	on	ADP
eurjchem-2037	41	9	a	a	DET
eurjchem-2037	41	10	philips	philips	PROPN
eurjchem-2037	41	11	pw-1710	pw-1710	ADJ
eurjchem-2037	41	12	automated	automate	VERB
eurjchem-2037	41	13	diffractometer	diffractometer	NOUN
eurjchem-2037	41	14	.	.	PUNCT
eurjchem-2037	42	1	fluorescence	fluorescence	PROPN
eurjchem-2037	42	2	spectra	spectra	PROPN
eurjchem-2037	42	3	were	be	AUX
eurjchem-2037	42	4	recorded	record	VERB
eurjchem-2037	42	5	on	on	ADP
eurjchem-2037	42	6	a	a	DET
eurjchem-2037	42	7	perkin	perkin	PROPN
eurjchem-2037	42	8	elmer	elmer	NOUN
eurjchem-2037	42	9	ls55	ls55	PROPN
eurjchem-2037	42	10	luminescence	luminescence	NOUN
eurjchem-2037	42	11	spectrometer	spectrometer	NOUN
eurjchem-2037	42	12	.	.	PUNCT
eurjchem-2037	43	1	2.2	2.2	NUM
eurjchem-2037	43	2	.	.	PUNCT
eurjchem-2037	43	3	synthesis	synthesis	NOUN
eurjchem-2037	43	4	of	of	ADP
eurjchem-2037	43	5	the	the	DET
eurjchem-2037	43	6	imino	imino	NOUN
eurjchem-2037	43	7	-	-	PUNCT
eurjchem-2037	43	8	pyridyl	pyridyl	ADJ
eurjchem-2037	43	9	ligand	ligand	NOUN
eurjchem-2037	43	10	(	(	PUNCT
eurjchem-2037	43	11	l	l	NOUN
eurjchem-2037	43	12	)	)	PUNCT
eurjchem-2037	43	13	the	the	DET
eurjchem-2037	43	14	imino	imino	NOUN
eurjchem-2037	43	15	-	-	PUNCT
eurjchem-2037	43	16	pyridyl	pyridyl	ADJ
eurjchem-2037	43	17	ligand	ligand	NOUN
eurjchem-2037	43	18	(	(	PUNCT
eurjchem-2037	43	19	l	l	NOUN
eurjchem-2037	43	20	)	)	PUNCT
eurjchem-2037	43	21	has	have	AUX
eurjchem-2037	43	22	been	be	AUX
eurjchem-2037	43	23	prepared	prepare	VERB
eurjchem-2037	43	24	by	by	ADP
eurjchem-2037	43	25	following	follow	VERB
eurjchem-2037	43	26	a	a	DET
eurjchem-2037	43	27	reported	report	VERB
eurjchem-2037	43	28	procedure	procedure	NOUN
eurjchem-2037	43	29	[	[	X
eurjchem-2037	43	30	33	33	NUM
eurjchem-2037	43	31	]	]	PUNCT
eurjchem-2037	43	32	.	.	PUNCT
eurjchem-2037	44	1	1	1	NUM
eurjchem-2037	44	2	ml	ml	NOUN
eurjchem-2037	44	3	(	(	PUNCT
eurjchem-2037	44	4	15	15	NUM
eurjchem-2037	44	5	mmol	mmol	NOUN
eurjchem-2037	44	6	)	)	PUNCT
eurjchem-2037	44	7	of	of	ADP
eurjchem-2037	44	8	distilled	distil	VERB
eurjchem-2037	44	9	ethylenediamine	ethylenediamine	NOUN
eurjchem-2037	44	10	and	and	CCONJ
eurjchem-2037	44	11	2.86	2.86	NUM
eurjchem-2037	44	12	(	(	PUNCT
eurjchem-2037	44	13	30	30	NUM
eurjchem-2037	44	14	mmol	mmol	NOUN
eurjchem-2037	44	15	)	)	PUNCT
eurjchem-2037	44	16	of	of	ADP
eurjchem-2037	44	17	freshly	freshly	ADV
eurjchem-2037	44	18	distilled	distil	VERB
eurjchem-2037	44	19	4	4	NUM
eurjchem-2037	44	20	-	-	PUNCT
eurjchem-2037	44	21	pyridinecarboxaldehyde	pyridinecarboxaldehyde	NOUN
eurjchem-2037	44	22	were	be	AUX
eurjchem-2037	44	23	refluxed	refluxe	VERB
eurjchem-2037	44	24	in	in	ADP
eurjchem-2037	44	25	50	50	NUM
eurjchem-2037	44	26	ml	ml	NOUN
eurjchem-2037	44	27	of	of	ADP
eurjchem-2037	44	28	anhydrous	anhydrous	ADJ
eurjchem-2037	44	29	methanol	methanol	NOUN
eurjchem-2037	44	30	for	for	ADP
eurjchem-2037	44	31	6	6	NUM
eurjchem-2037	44	32	h.	h.	NOUN
eurjchem-2037	44	33	on	on	ADP
eurjchem-2037	44	34	evaporating	evaporate	VERB
eurjchem-2037	44	35	the	the	DET
eurjchem-2037	44	36	solvent	solvent	NOUN
eurjchem-2037	44	37	,	,	PUNCT
eurjchem-2037	44	38	a	a	DET
eurjchem-2037	44	39	slightly	slightly	ADV
eurjchem-2037	44	40	yellow	yellow	ADJ
eurjchem-2037	44	41	semi	semi	ADJ
eurjchem-2037	44	42	-	-	ADJ
eurjchem-2037	44	43	solid	solid	ADJ
eurjchem-2037	44	44	was	be	AUX
eurjchem-2037	44	45	obtained	obtain	VERB
eurjchem-2037	44	46	which	which	PRON
eurjchem-2037	44	47	on	on	ADP
eurjchem-2037	44	48	recrystallization	recrystallization	NOUN
eurjchem-2037	44	49	from	from	ADP
eurjchem-2037	44	50	n	n	CCONJ
eurjchem-2037	44	51	-	-	PUNCT
eurjchem-2037	44	52	hexane	hexane	NOUN
eurjchem-2037	44	53	gave	give	VERB
eurjchem-2037	44	54	colourless	colourless	ADJ
eurjchem-2037	44	55	needles	needle	NOUN
eurjchem-2037	44	56	suitable	suitable	ADJ
eurjchem-2037	44	57	for	for	ADP
eurjchem-2037	44	58	x	x	NOUN
eurjchem-2037	44	59	-	-	NOUN
eurjchem-2037	44	60	ray	ray	NOUN
eurjchem-2037	44	61	analysis	analysis	NOUN
eurjchem-2037	44	62	.	.	PUNCT
eurjchem-2037	45	1	(	(	PUNCT
eurjchem-2037	45	2	1e	1e	NUM
eurjchem-2037	45	3	,	,	PUNCT
eurjchem-2037	45	4	1'e)-n	1'e)-n	NUM
eurjchem-2037	45	5	,	,	PUNCT
eurjchem-2037	45	6	n'-(ethane-1	n'-(ethane-1	NOUN
eurjchem-2037	45	7	,	,	PUNCT
eurjchem-2037	45	8	2	2	NUM
eurjchem-2037	45	9	-	-	PUNCT
eurjchem-2037	45	10	diyl	diyl	NOUN
eurjchem-2037	45	11	)	)	PUNCT
eurjchem-2037	45	12	bis(1-(pyridin-4	bis(1-(pyridin-4	NOUN
eurjchem-2037	45	13	-	-	PUNCT
eurjchem-2037	45	14	yl)methan	yl)methan	ADV
eurjchem-2037	45	15	imine	imine	NOUN
eurjchem-2037	45	16	)	)	PUNCT
eurjchem-2037	45	17	(	(	PUNCT
eurjchem-2037	45	18	l	l	NOUN
eurjchem-2037	45	19	):	):	PUNCT
eurjchem-2037	45	20	color	color	NOUN
eurjchem-2037	45	21	:	:	PUNCT
eurjchem-2037	45	22	colorless	colorless	ADJ
eurjchem-2037	45	23	.	.	PUNCT
eurjchem-2037	45	24	yield	yield	NOUN
eurjchem-2037	45	25	:	:	PUNCT
eurjchem-2037	45	26	61	61	NUM
eurjchem-2037	45	27	%	%	NOUN
eurjchem-2037	45	28	.	.	PUNCT
eurjchem-2037	46	1	m.p	m.p	PROPN
eurjchem-2037	46	2	.	.	PROPN
eurjchem-2037	46	3	:	:	PUNCT
eurjchem-2037	47	1	125	125	NUM
eurjchem-2037	47	2	-	-	SYM
eurjchem-2037	47	3	128	128	NUM
eurjchem-2037	47	4	°	°	NOUN
eurjchem-2037	47	5	c	c	NOUN
eurjchem-2037	47	6	.	.	PUNCT
eurjchem-2037	48	1	ft	ft	PROPN
eurjchem-2037	48	2	-	-	PUNCT
eurjchem-2037	48	3	ir	ir	PROPN
eurjchem-2037	48	4	(	(	PUNCT
eurjchem-2037	48	5	kbr	kbr	PROPN
eurjchem-2037	48	6	,	,	PUNCT
eurjchem-2037	48	7	ν	ν	PROPN
eurjchem-2037	48	8	,	,	PUNCT
eurjchem-2037	48	9	cm-1	cm-1	NUM
eurjchem-2037	48	10	):	):	PUNCT
eurjchem-2037	48	11	1648	1648	NUM
eurjchem-2037	48	12	(	(	PUNCT
eurjchem-2037	48	13	c	c	NOUN
eurjchem-2037	48	14	=	=	SYM
eurjchem-2037	48	15	n	n	NUM
eurjchem-2037	48	16	)	)	PUNCT
eurjchem-2037	48	17	.	.	PUNCT
eurjchem-2037	49	1	1h	1h	NUM
eurjchem-2037	49	2	nmr	nmr	NOUN
eurjchem-2037	49	3	(	(	PUNCT
eurjchem-2037	49	4	400	400	NUM
eurjchem-2037	49	5	mhz	mhz	NOUN
eurjchem-2037	49	6	,	,	PUNCT
eurjchem-2037	49	7	cdcl3	cdcl3	PROPN
eurjchem-2037	49	8	,	,	PUNCT
eurjchem-2037	49	9	δ	δ	PROPN
eurjchem-2037	49	10	,	,	PUNCT
eurjchem-2037	49	11	ppm):8.66	ppm):8.66	PROPN
eurjchem-2037	49	12	(	(	PUNCT
eurjchem-2037	49	13	d	d	NOUN
eurjchem-2037	49	14	,	,	PUNCT
eurjchem-2037	49	15	j	j	PROPN
eurjchem-2037	49	16	=	=	SYM
eurjchem-2037	49	17	4	4	NUM
eurjchem-2037	49	18	hz	hz	NOUN
eurjchem-2037	49	19	,	,	PUNCT
eurjchem-2037	49	20	4h	4h	NOUN
eurjchem-2037	49	21	,	,	PUNCT
eurjchem-2037	49	22	ar	ar	NOUN
eurjchem-2037	49	23	-	-	NOUN
eurjchem-2037	49	24	h	h	NOUN
eurjchem-2037	49	25	)	)	PUNCT
eurjchem-2037	49	26	,	,	PUNCT
eurjchem-2037	49	27	8.25	8.25	NUM
eurjchem-2037	49	28	(	(	PUNCT
eurjchem-2037	49	29	s	s	PROPN
eurjchem-2037	49	30	,	,	PUNCT
eurjchem-2037	49	31	2h	2h	NUM
eurjchem-2037	49	32	,	,	PUNCT
eurjchem-2037	49	33	ch	ch	NOUN
eurjchem-2037	49	34	)	)	PUNCT
eurjchem-2037	49	35	,	,	PUNCT
eurjchem-2037	49	36	7.53	7.53	NUM
eurjchem-2037	49	37	(	(	PUNCT
eurjchem-2037	49	38	d	d	NOUN
eurjchem-2037	49	39	,	,	PUNCT
eurjchem-2037	49	40	j=	j=	ADP
eurjchem-2037	49	41	4	4	NUM
eurjchem-2037	49	42	hz	hz	VERB
eurjchem-2037	49	43	,	,	PUNCT
eurjchem-2037	49	44	4h	4h	NOUN
eurjchem-2037	49	45	,	,	PUNCT
eurjchem-2037	49	46	ar	ar	NOUN
eurjchem-2037	49	47	-	-	NOUN
eurjchem-2037	49	48	h	h	NOUN
eurjchem-2037	49	49	)	)	PUNCT
eurjchem-2037	49	50	,	,	PUNCT
eurjchem-2037	49	51	4.03	4.03	NUM
eurjchem-2037	49	52	(	(	PUNCT
eurjchem-2037	49	53	s	s	PROPN
eurjchem-2037	49	54	,	,	PUNCT
eurjchem-2037	49	55	4h	4h	NOUN
eurjchem-2037	49	56	,	,	PUNCT
eurjchem-2037	49	57	ch2	ch2	PROPN
eurjchem-2037	49	58	)	)	PUNCT
eurjchem-2037	49	59	.	.	PUNCT
eurjchem-2037	50	1	13c	13c	NOUN
eurjchem-2037	50	2	nmr	nmr	NOUN
eurjchem-2037	50	3	(	(	PUNCT
eurjchem-2037	50	4	200	200	NUM
eurjchem-2037	50	5	mhz	mhz	NOUN
eurjchem-2037	50	6	,	,	PUNCT
eurjchem-2037	50	7	cdcl3	cdcl3	PROPN
eurjchem-2037	50	8	,	,	PUNCT
eurjchem-2037	50	9	δ	δ	PROPN
eurjchem-2037	50	10	,	,	PUNCT
eurjchem-2037	50	11	ppm	ppm	NUM
eurjchem-2037	50	12	):	):	PUNCT
eurjchem-2037	50	13	160.84	160.84	NUM
eurjchem-2037	50	14	,	,	PUNCT
eurjchem-2037	50	15	150.42	150.42	NUM
eurjchem-2037	50	16	,	,	PUNCT
eurjchem-2037	50	17	142.63	142.63	NUM
eurjchem-2037	50	18	,	,	PUNCT
eurjchem-2037	50	19	121.83	121.83	NUM
eurjchem-2037	50	20	,	,	PUNCT
eurjchem-2037	50	21	61.27	61.27	NUM
eurjchem-2037	50	22	.	.	PUNCT
eurjchem-2037	51	1	anal	anal	ADJ
eurjchem-2037	51	2	.	.	PUNCT
eurjchem-2037	51	3	calcd	calcd	NOUN
eurjchem-2037	51	4	.	.	PUNCT
eurjchem-2037	52	1	for	for	ADP
eurjchem-2037	52	2	c14h14n4	c14h14n4	PROPN
eurjchem-2037	52	3	:	:	PUNCT
eurjchem-2037	52	4	c	c	X
eurjchem-2037	52	5	,	,	PUNCT
eurjchem-2037	52	6	70.57	70.57	NUM
eurjchem-2037	52	7	;	;	PUNCT
eurjchem-2037	52	8	h	h	NOUN
eurjchem-2037	52	9	,	,	PUNCT
eurjchem-2037	52	10	5.92	5.92	NUM
eurjchem-2037	52	11	;	;	PUNCT
eurjchem-2037	52	12	n	n	CCONJ
eurjchem-2037	52	13	,	,	PUNCT
eurjchem-2037	52	14	23.51	23.51	NUM
eurjchem-2037	52	15	.	.	PUNCT
eurjchem-2037	52	16	found	find	VERB
eurjchem-2037	52	17	:	:	PUNCT
eurjchem-2037	53	1	c	c	X
eurjchem-2037	53	2	,	,	PUNCT
eurjchem-2037	53	3	70.43	70.43	NUM
eurjchem-2037	53	4	;	;	PUNCT
eurjchem-2037	53	5	h	h	NOUN
eurjchem-2037	53	6	,	,	PUNCT
eurjchem-2037	53	7	5.92	5.92	NUM
eurjchem-2037	53	8	;	;	PUNCT
eurjchem-2037	53	9	n	n	CCONJ
eurjchem-2037	53	10	,	,	PUNCT
eurjchem-2037	53	11	23.62	23.62	NUM
eurjchem-2037	53	12	%	%	NOUN
eurjchem-2037	53	13	.	.	PUNCT
eurjchem-2037	54	1	uv	uv	NOUN
eurjchem-2037	54	2	/	/	SYM
eurjchem-2037	54	3	vis	vis	X
eurjchem-2037	54	4	(	(	PUNCT
eurjchem-2037	54	5	ch3oh	ch3oh	ADV
eurjchem-2037	54	6	,	,	PUNCT
eurjchem-2037	54	7	λmax	λmax	NOUN
eurjchem-2037	54	8	,	,	PUNCT
eurjchem-2037	54	9	nm	nm	NOUN
eurjchem-2037	54	10	,	,	PUNCT
eurjchem-2037	54	11	(	(	PUNCT
eurjchem-2037	54	12	ε	ε	PROPN
eurjchem-2037	54	13	)	)	PUNCT
eurjchem-2037	54	14	):	):	PUNCT
eurjchem-2037	54	15	236	236	NUM
eurjchem-2037	54	16	(	(	PUNCT
eurjchem-2037	54	17	27.30	27.30	NUM
eurjchem-2037	54	18	)	)	PUNCT
eurjchem-2037	54	19	.	.	PUNCT
eurjchem-2037	55	1	2.3	2.3	NUM
eurjchem-2037	55	2	.	.	PUNCT
eurjchem-2037	55	3	synthesis	synthesis	NOUN
eurjchem-2037	55	4	of	of	ADP
eurjchem-2037	55	5	[	[	X
eurjchem-2037	55	6	cu2(µ-l)(µ-i)2(pph3)2]n	cu2(µ-l)(µ-i)2(pph3)2]n	NOUN
eurjchem-2037	55	7	(	(	PUNCT
eurjchem-2037	55	8	1	1	NUM
eurjchem-2037	55	9	)	)	PUNCT
eurjchem-2037	55	10	to	to	ADP
eurjchem-2037	55	11	a	a	DET
eurjchem-2037	55	12	solution	solution	NOUN
eurjchem-2037	55	13	of	of	ADP
eurjchem-2037	55	14	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2037	55	15	(	(	PUNCT
eurjchem-2037	55	16	0.262	0.262	NUM
eurjchem-2037	55	17	g	g	NOUN
eurjchem-2037	55	18	,	,	PUNCT
eurjchem-2037	55	19	1	1	NUM
eurjchem-2037	55	20	mmol	mmol	NOUN
eurjchem-2037	55	21	)	)	PUNCT
eurjchem-2037	55	22	in	in	ADP
eurjchem-2037	55	23	ch2cl2	ch2cl2	PUNCT
eurjchem-2037	55	24	(	(	PUNCT
eurjchem-2037	55	25	60	60	NUM
eurjchem-2037	55	26	ml	ml	NOUN
eurjchem-2037	55	27	)	)	PUNCT
eurjchem-2037	55	28	,	,	PUNCT
eurjchem-2037	55	29	solid	solid	ADJ
eurjchem-2037	55	30	cuprous	cuprous	ADJ
eurjchem-2037	55	31	iodide	iodide	NOUN
eurjchem-2037	55	32	(	(	PUNCT
eurjchem-2037	55	33	0.19	0.19	NUM
eurjchem-2037	55	34	g	g	NOUN
eurjchem-2037	55	35	,	,	PUNCT
eurjchem-2037	55	36	1	1	NUM
eurjchem-2037	55	37	mmol	mmol	NOUN
eurjchem-2037	55	38	)	)	PUNCT
eurjchem-2037	55	39	was	be	AUX
eurjchem-2037	55	40	added	add	VERB
eurjchem-2037	55	41	.	.	PUNCT
eurjchem-2037	56	1	the	the	DET
eurjchem-2037	56	2	reaction	reaction	NOUN
eurjchem-2037	56	3	mixture	mixture	NOUN
eurjchem-2037	56	4	was	be	AUX
eurjchem-2037	56	5	stirred	stir	VERB
eurjchem-2037	56	6	for	for	SCONJ
eurjchem-2037	56	7	1	1	NUM
eurjchem-2037	56	8	h	h	NOUN
eurjchem-2037	56	9	to	to	PART
eurjchem-2037	56	10	get	get	VERB
eurjchem-2037	56	11	a	a	DET
eurjchem-2037	56	12	clear	clear	ADJ
eurjchem-2037	56	13	colorless	colorless	ADJ
eurjchem-2037	56	14	solution	solution	NOUN
eurjchem-2037	56	15	.	.	PUNCT
eurjchem-2037	57	1	the	the	DET
eurjchem-2037	57	2	30	30	NUM
eurjchem-2037	57	3	ml	ml	NOUN
eurjchem-2037	57	4	ch2cl2	ch2cl2	NOUN
eurjchem-2037	57	5	solution	solution	NOUN
eurjchem-2037	57	6	of	of	ADP
eurjchem-2037	57	7	the	the	DET
eurjchem-2037	57	8	ligand	ligand	NOUN
eurjchem-2037	57	9	,	,	PUNCT
eurjchem-2037	57	10	l	l	X
eurjchem-2037	57	11	(	(	PUNCT
eurjchem-2037	57	12	0.119	0.119	NUM
eurjchem-2037	57	13	g	g	NOUN
eurjchem-2037	57	14	,	,	PUNCT
eurjchem-2037	57	15	0.5	0.5	NUM
eurjchem-2037	57	16	mmol	mmol	NOUN
eurjchem-2037	57	17	)	)	PUNCT
eurjchem-2037	57	18	was	be	AUX
eurjchem-2037	57	19	added	add	VERB
eurjchem-2037	57	20	with	with	ADP
eurjchem-2037	57	21	constant	constant	ADJ
eurjchem-2037	57	22	stirring	stirring	NOUN
eurjchem-2037	57	23	for	for	ADP
eurjchem-2037	57	24	another	another	DET
eurjchem-2037	57	25	1h	1h	NUM
eurjchem-2037	57	26	at	at	ADP
eurjchem-2037	57	27	room	room	NOUN
eurjchem-2037	57	28	temperature	temperature	NOUN
eurjchem-2037	57	29	to	to	PART
eurjchem-2037	57	30	give	give	VERB
eurjchem-2037	57	31	a	a	DET
eurjchem-2037	57	32	clear	clear	ADJ
eurjchem-2037	57	33	reddish	reddish	ADJ
eurjchem-2037	57	34	solution	solution	NOUN
eurjchem-2037	57	35	.	.	PUNCT
eurjchem-2037	58	1	the	the	DET
eurjchem-2037	58	2	solution	solution	NOUN
eurjchem-2037	58	3	was	be	AUX
eurjchem-2037	58	4	evaporated	evaporate	VERB
eurjchem-2037	58	5	to	to	PART
eurjchem-2037	58	6	dryness	dryness	VERB
eurjchem-2037	58	7	to	to	PART
eurjchem-2037	58	8	obtain	obtain	VERB
eurjchem-2037	58	9	a	a	DET
eurjchem-2037	58	10	reddish	reddish	ADJ
eurjchem-2037	58	11	-	-	PUNCT
eurjchem-2037	58	12	yellow	yellow	NOUN
eurjchem-2037	58	13	solid	solid	NOUN
eurjchem-2037	58	14	.	.	PUNCT
eurjchem-2037	59	1	it	it	PRON
eurjchem-2037	59	2	was	be	AUX
eurjchem-2037	59	3	washed	wash	VERB
eurjchem-2037	59	4	with	with	ADP
eurjchem-2037	59	5	5	5	NUM
eurjchem-2037	59	6	ml	ml	NOUN
eurjchem-2037	59	7	of	of	ADP
eurjchem-2037	59	8	ch2cl2	ch2cl2	X
eurjchem-2037	59	9	(	(	PUNCT
eurjchem-2037	59	10	scheme	scheme	NOUN
eurjchem-2037	59	11	2	2	NUM
eurjchem-2037	59	12	)	)	PUNCT
eurjchem-2037	59	13	.	.	PUNCT
eurjchem-2037	60	1	[	[	X
eurjchem-2037	60	2	cu2(µ-(1e	cu2(µ-(1e	PROPN
eurjchem-2037	60	3	,	,	PUNCT
eurjchem-2037	60	4	1'e)-n	1'e)-n	NUM
eurjchem-2037	60	5	,	,	PUNCT
eurjchem-2037	60	6	n'-(ethane-1	n'-(ethane-1	NOUN
eurjchem-2037	60	7	,	,	PUNCT
eurjchem-2037	60	8	2	2	NUM
eurjchem-2037	60	9	-	-	PUNCT
eurjchem-2037	60	10	diyl)bis(1-(pyridin-4	diyl)bis(1-(pyridin-4	NOUN
eurjchem-2037	60	11	-	-	PUNCT
eurjchem-2037	60	12	yl)met	yl)met	PRON
eurjchem-2037	60	13	hanimine))(µ-i)2	hanimine))(µ-i)2	NOUN
eurjchem-2037	60	14	(	(	PUNCT
eurjchem-2037	60	15	pph3)2]n	pph3)2]n	X
eurjchem-2037	60	16	(	(	PUNCT
eurjchem-2037	60	17	1	1	NUM
eurjchem-2037	60	18	):	):	PUNCT
eurjchem-2037	60	19	color	color	NOUN
eurjchem-2037	60	20	:	:	PUNCT
eurjchem-2037	60	21	reddish	reddish	ADJ
eurjchem-2037	60	22	yellow	yellow	NOUN
eurjchem-2037	60	23	.	.	PUNCT
eurjchem-2037	60	24	yield	yield	NOUN
eurjchem-2037	60	25	:	:	PUNCT
eurjchem-2037	60	26	85	85	NUM
eurjchem-2037	60	27	%	%	NOUN
eurjchem-2037	60	28	.	.	PUNCT
eurjchem-2037	61	1	m.p	m.p	PROPN
eurjchem-2037	61	2	.	.	PROPN
eurjchem-2037	61	3	:	:	PUNCT
eurjchem-2037	62	1	>	>	PUNCT
eurjchem-2037	62	2	200	200	NUM
eurjchem-2037	62	3	°	°	NOUN
eurjchem-2037	62	4	c	c	NOUN
eurjchem-2037	62	5	.	.	PUNCT
eurjchem-2037	62	6	ft	ft	PROPN
eurjchem-2037	62	7	-	-	PUNCT
eurjchem-2037	62	8	ir	ir	PROPN
eurjchem-2037	62	9	(	(	PUNCT
eurjchem-2037	62	10	kbr	kbr	PROPN
eurjchem-2037	62	11	,	,	PUNCT
eurjchem-2037	62	12	ν	ν	PROPN
eurjchem-2037	62	13	,	,	PUNCT
eurjchem-2037	62	14	cm-1	cm-1	NUM
eurjchem-2037	62	15	):	):	PUNCT
eurjchem-2037	62	16	1610	1610	NUM
eurjchem-2037	62	17	(	(	PUNCT
eurjchem-2037	62	18	c	c	NOUN
eurjchem-2037	62	19	=	=	SYM
eurjchem-2037	62	20	n	n	NUM
eurjchem-2037	62	21	)	)	PUNCT
eurjchem-2037	62	22	.	.	PUNCT
eurjchem-2037	63	1	anal	anal	PROPN
eurjchem-2037	63	2	.	.	PUNCT
eurjchem-2037	63	3	calcd	calcd	NOUN
eurjchem-2037	63	4	.	.	PUNCT
eurjchem-2037	64	1	for	for	ADP
eurjchem-2037	64	2	c50h44cu2i2n4p2	c50h44cu2i2n4p2	PROPN
eurjchem-2037	64	3	:	:	PUNCT
eurjchem-2037	64	4	c	c	X
eurjchem-2037	64	5	,	,	PUNCT
eurjchem-2037	64	6	52.51	52.51	NUM
eurjchem-2037	64	7	;	;	PUNCT
eurjchem-2037	64	8	h	h	NOUN
eurjchem-2037	64	9	,	,	PUNCT
eurjchem-2037	64	10	3.88	3.88	NUM
eurjchem-2037	64	11	;	;	PUNCT
eurjchem-2037	64	12	n	n	CCONJ
eurjchem-2037	64	13	,	,	PUNCT
eurjchem-2037	64	14	4.90	4.90	NUM
eurjchem-2037	64	15	.	.	PUNCT
eurjchem-2037	64	16	found	find	VERB
eurjchem-2037	64	17	:	:	PUNCT
eurjchem-2037	65	1	c	c	X
eurjchem-2037	65	2	,	,	PUNCT
eurjchem-2037	65	3	52.63	52.63	NUM
eurjchem-2037	65	4	;	;	PUNCT
eurjchem-2037	65	5	h	h	X
eurjchem-2037	65	6	,	,	PUNCT
eurjchem-2037	65	7	4.13	4.13	NUM
eurjchem-2037	65	8	;	;	PUNCT
eurjchem-2037	65	9	n	n	CCONJ
eurjchem-2037	65	10	,	,	PUNCT
eurjchem-2037	65	11	4.71	4.71	NUM
eurjchem-2037	65	12	%	%	NOUN
eurjchem-2037	65	13	.	.	PUNCT
eurjchem-2037	66	1	uv	uv	NOUN
eurjchem-2037	66	2	/	/	SYM
eurjchem-2037	66	3	vis	vis	X
eurjchem-2037	66	4	(	(	PUNCT
eurjchem-2037	66	5	ch3oh	ch3oh	ADV
eurjchem-2037	66	6	,	,	PUNCT
eurjchem-2037	66	7	λmax	λmax	NOUN
eurjchem-2037	66	8	,	,	PUNCT
eurjchem-2037	66	9	nm	nm	NOUN
eurjchem-2037	66	10	,	,	PUNCT
eurjchem-2037	66	11	(	(	PUNCT
eurjchem-2037	66	12	ε	ε	PROPN
eurjchem-2037	66	13	)	)	PUNCT
eurjchem-2037	66	14	):	):	PUNCT
eurjchem-2037	66	15	370	370	NUM
eurjchem-2037	66	16	(	(	PUNCT
eurjchem-2037	66	17	2.33	2.33	NUM
eurjchem-2037	66	18	)	)	PUNCT
eurjchem-2037	66	19	.	.	PUNCT
eurjchem-2037	67	1	2.4	2.4	NUM
eurjchem-2037	67	2	.	.	PUNCT
eurjchem-2037	67	3	synthesis	synthesis	NOUN
eurjchem-2037	67	4	of	of	ADP
eurjchem-2037	67	5	[	[	X
eurjchem-2037	67	6	cu2(µ-l)(µ-br)2(pph3)2]n	cu2(µ-l)(µ-br)2(pph3)2]n	NOUN
eurjchem-2037	67	7	(	(	PUNCT
eurjchem-2037	67	8	2	2	NUM
eurjchem-2037	67	9	)	)	PUNCT
eurjchem-2037	67	10	to	to	ADP
eurjchem-2037	67	11	a	a	DET
eurjchem-2037	67	12	solution	solution	NOUN
eurjchem-2037	67	13	of	of	ADP
eurjchem-2037	67	14	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2037	67	15	(	(	PUNCT
eurjchem-2037	67	16	0.262	0.262	NUM
eurjchem-2037	67	17	g	g	NOUN
eurjchem-2037	67	18	,	,	PUNCT
eurjchem-2037	67	19	1	1	NUM
eurjchem-2037	67	20	mmol	mmol	NOUN
eurjchem-2037	67	21	)	)	PUNCT
eurjchem-2037	67	22	in	in	ADP
eurjchem-2037	67	23	ch2cl2	ch2cl2	PUNCT
eurjchem-2037	67	24	(	(	PUNCT
eurjchem-2037	67	25	60	60	NUM
eurjchem-2037	67	26	ml	ml	NOUN
eurjchem-2037	67	27	)	)	PUNCT
eurjchem-2037	67	28	,	,	PUNCT
eurjchem-2037	67	29	solid	solid	ADJ
eurjchem-2037	67	30	cuprous	cuprous	ADJ
eurjchem-2037	67	31	bromide	bromide	NOUN
eurjchem-2037	67	32	(	(	PUNCT
eurjchem-2037	67	33	0.144	0.144	NUM
eurjchem-2037	67	34	g	g	NOUN
eurjchem-2037	67	35	,	,	PUNCT
eurjchem-2037	67	36	1	1	NUM
eurjchem-2037	67	37	mmol	mmol	NOUN
eurjchem-2037	67	38	)	)	PUNCT
eurjchem-2037	67	39	was	be	AUX
eurjchem-2037	67	40	added	add	VERB
eurjchem-2037	67	41	.	.	PUNCT
eurjchem-2037	68	1	the	the	DET
eurjchem-2037	68	2	reaction	reaction	NOUN
eurjchem-2037	68	3	mixture	mixture	NOUN
eurjchem-2037	68	4	was	be	AUX
eurjchem-2037	68	5	stirred	stir	VERB
eurjchem-2037	68	6	for	for	SCONJ
eurjchem-2037	68	7	1	1	NUM
eurjchem-2037	68	8	h	h	NOUN
eurjchem-2037	68	9	to	to	PART
eurjchem-2037	68	10	get	get	VERB
eurjchem-2037	68	11	a	a	DET
eurjchem-2037	68	12	clear	clear	ADJ
eurjchem-2037	68	13	orange	orange	NOUN
eurjchem-2037	68	14	solution	solution	NOUN
eurjchem-2037	68	15	.	.	PUNCT
eurjchem-2037	69	1	the	the	DET
eurjchem-2037	69	2	30	30	NUM
eurjchem-2037	69	3	ml	ml	NOUN
eurjchem-2037	69	4	ch2cl2	ch2cl2	NOUN
eurjchem-2037	69	5	solution	solution	NOUN
eurjchem-2037	69	6	of	of	ADP
eurjchem-2037	69	7	the	the	DET
eurjchem-2037	69	8	ligand	ligand	NOUN
eurjchem-2037	69	9	,	,	PUNCT
eurjchem-2037	69	10	l	l	X
eurjchem-2037	69	11	(	(	PUNCT
eurjchem-2037	69	12	0.119	0.119	NUM
eurjchem-2037	69	13	g	g	NOUN
eurjchem-2037	69	14	,	,	PUNCT
eurjchem-2037	69	15	0.5	0.5	NUM
eurjchem-2037	69	16	mmol	mmol	NOUN
eurjchem-2037	69	17	)	)	PUNCT
eurjchem-2037	69	18	was	be	AUX
eurjchem-2037	69	19	added	add	VERB
eurjchem-2037	69	20	with	with	ADP
eurjchem-2037	69	21	constant	constant	ADJ
eurjchem-2037	69	22	stirring	stirring	NOUN
eurjchem-2037	69	23	for	for	ADP
eurjchem-2037	69	24	another	another	DET
eurjchem-2037	69	25	1h	1h	NUM
eurjchem-2037	69	26	at	at	ADP
eurjchem-2037	69	27	room	room	NOUN
eurjchem-2037	69	28	temperature	temperature	NOUN
eurjchem-2037	69	29	to	to	PART
eurjchem-2037	69	30	give	give	VERB
eurjchem-2037	69	31	a	a	DET
eurjchem-2037	69	32	clear	clear	ADJ
eurjchem-2037	69	33	orange	orange	NOUN
eurjchem-2037	69	34	solution	solution	NOUN
eurjchem-2037	69	35	.	.	PUNCT
eurjchem-2037	70	1	the	the	DET
eurjchem-2037	70	2	solution	solution	NOUN
eurjchem-2037	70	3	was	be	AUX
eurjchem-2037	70	4	evaporated	evaporate	VERB
eurjchem-2037	70	5	to	to	PART
eurjchem-2037	70	6	dryness	dryness	VERB
eurjchem-2037	70	7	to	to	PART
eurjchem-2037	70	8	obtain	obtain	VERB
eurjchem-2037	70	9	orange	orange	PROPN
eurjchem-2037	70	10	solid	solid	ADJ
eurjchem-2037	70	11	.	.	PUNCT
eurjchem-2037	71	1	it	it	PRON
eurjchem-2037	71	2	was	be	AUX
eurjchem-2037	71	3	washed	wash	VERB
eurjchem-2037	71	4	with	with	ADP
eurjchem-2037	71	5	5	5	NUM
eurjchem-2037	71	6	ml	ml	NOUN
eurjchem-2037	71	7	of	of	ADP
eurjchem-2037	71	8	ch2cl2	ch2cl2	NOUN
eurjchem-2037	71	9	.	.	PUNCT
eurjchem-2037	72	1	bright	bright	ADJ
eurjchem-2037	72	2	red	red	ADJ
eurjchem-2037	72	3	single	single	ADJ
eurjchem-2037	72	4	crystals	crystal	NOUN
eurjchem-2037	72	5	of	of	ADP
eurjchem-2037	72	6	the	the	DET
eurjchem-2037	72	7	complex	complex	ADJ
eurjchem-2037	72	8	,	,	PUNCT
eurjchem-2037	72	9	suitable	suitable	ADJ
eurjchem-2037	72	10	for	for	ADP
eurjchem-2037	72	11	x	x	NOUN
eurjchem-2037	72	12	-	-	NOUN
eurjchem-2037	72	13	ray	ray	NOUN
eurjchem-2037	72	14	analysis	analysis	NOUN
eurjchem-2037	72	15	were	be	AUX
eurjchem-2037	72	16	obtained	obtain	VERB
eurjchem-2037	72	17	by	by	ADP
eurjchem-2037	72	18	direct	direct	ADJ
eurjchem-2037	72	19	diffusion	diffusion	NOUN
eurjchem-2037	72	20	of	of	ADP
eurjchem-2037	72	21	hexane	hexane	NOUN
eurjchem-2037	72	22	to	to	ADP
eurjchem-2037	72	23	the	the	DET
eurjchem-2037	72	24	ch2cl2	ch2cl2	NOUN
eurjchem-2037	72	25	solution	solution	NOUN
eurjchem-2037	72	26	of	of	ADP
eurjchem-2037	72	27	the	the	DET
eurjchem-2037	72	28	yellow	yellow	ADJ
eurjchem-2037	72	29	solid	solid	ADJ
eurjchem-2037	72	30	(	(	PUNCT
eurjchem-2037	72	31	scheme	scheme	NOUN
eurjchem-2037	72	32	2	2	NUM
eurjchem-2037	72	33	)	)	PUNCT
eurjchem-2037	72	34	.	.	PUNCT
eurjchem-2037	73	1	[	[	X
eurjchem-2037	73	2	cu2(µ-(1e	cu2(µ-(1e	PROPN
eurjchem-2037	73	3	,	,	PUNCT
eurjchem-2037	73	4	1'e)-n	1'e)-n	NUM
eurjchem-2037	73	5	,	,	PUNCT
eurjchem-2037	73	6	n'-(ethane-1	n'-(ethane-1	NOUN
eurjchem-2037	73	7	,	,	PUNCT
eurjchem-2037	73	8	2	2	NUM
eurjchem-2037	73	9	-	-	PUNCT
eurjchem-2037	73	10	diyl)bis(1-(pyridin-4	diyl)bis(1-(pyridin-4	NOUN
eurjchem-2037	73	11	-	-	PUNCT
eurjchem-2037	73	12	yl)met	yl)met	PRON
eurjchem-2037	73	13	hanimine))(µ-br)2(pph3)2]n	hanimine))(µ-br)2(pph3)2]n	PROPN
eurjchem-2037	73	14	(	(	PUNCT
eurjchem-2037	73	15	2	2	NUM
eurjchem-2037	73	16	):	):	PUNCT
eurjchem-2037	73	17	color	color	NOUN
eurjchem-2037	73	18	:	:	PUNCT
eurjchem-2037	73	19	bright	bright	ADJ
eurjchem-2037	73	20	red	red	ADJ
eurjchem-2037	73	21	.	.	PUNCT
eurjchem-2037	74	1	yield	yield	NOUN
eurjchem-2037	74	2	:	:	PUNCT
eurjchem-2037	74	3	89	89	NUM
eurjchem-2037	74	4	%	%	NOUN
eurjchem-2037	74	5	.	.	PUNCT
eurjchem-2037	75	1	m.p	m.p	PROPN
eurjchem-2037	75	2	.	.	PROPN
eurjchem-2037	75	3	:	:	PUNCT
eurjchem-2037	76	1	>	>	PUNCT
eurjchem-2037	76	2	200	200	NUM
eurjchem-2037	76	3	°	°	NOUN
eurjchem-2037	76	4	c	c	NOUN
eurjchem-2037	76	5	.	.	PUNCT
eurjchem-2037	76	6	ft	ft	PROPN
eurjchem-2037	76	7	-	-	PUNCT
eurjchem-2037	76	8	ir	ir	PROPN
eurjchem-2037	76	9	(	(	PUNCT
eurjchem-2037	76	10	kbr	kbr	PROPN
eurjchem-2037	76	11	,	,	PUNCT
eurjchem-2037	76	12	ν	ν	PROPN
eurjchem-2037	76	13	,	,	PUNCT
eurjchem-2037	76	14	cm-1	cm-1	NUM
eurjchem-2037	76	15	):	):	PUNCT
eurjchem-2037	76	16	1607	1607	NUM
eurjchem-2037	76	17	(	(	PUNCT
eurjchem-2037	76	18	c	c	NOUN
eurjchem-2037	76	19	=	=	SYM
eurjchem-2037	76	20	n	n	NUM
eurjchem-2037	76	21	)	)	PUNCT
eurjchem-2037	76	22	.	.	PUNCT
eurjchem-2037	77	1	anal	anal	PROPN
eurjchem-2037	77	2	.	.	PUNCT
eurjchem-2037	77	3	calcd	calcd	NOUN
eurjchem-2037	77	4	.	.	PUNCT
eurjchem-2037	78	1	for	for	ADP
eurjchem-2037	78	2	336	336	NUM
eurjchem-2037	78	3	mondal	mondal	PROPN
eurjchem-2037	78	4	et	et	PROPN
eurjchem-2037	78	5	al	al	PROPN
eurjchem-2037	78	6	.	.	PUNCT
eurjchem-2037	78	7	/	/	SYM
eurjchem-2037	78	8	european	european	PROPN
eurjchem-2037	78	9	journal	journal	PROPN
eurjchem-2037	78	10	of	of	ADP
eurjchem-2037	78	11	chemistry	chemistry	NOUN
eurjchem-2037	78	12	11	11	NUM
eurjchem-2037	78	13	(	(	PUNCT
eurjchem-2037	78	14	4	4	NUM
eurjchem-2037	78	15	)	)	PUNCT
eurjchem-2037	78	16	(	(	PUNCT
eurjchem-2037	78	17	2020	2020	NUM
eurjchem-2037	78	18	)	)	PUNCT
eurjchem-2037	78	19	334	334	NUM
eurjchem-2037	78	20	-	-	SYM
eurjchem-2037	78	21	341	341	NUM
eurjchem-2037	78	22	2020	2020	NUM
eurjchem-2037	78	23	–	–	PUNCT
eurjchem-2037	78	24	european	european	ADJ
eurjchem-2037	78	25	journal	journal	NOUN
eurjchem-2037	78	26	of	of	ADP
eurjchem-2037	78	27	chemistry	chemistry	NOUN
eurjchem-2037	78	28	–	–	PUNCT
eurjchem-2037	78	29	cc	cc	NOUN
eurjchem-2037	78	30	by	by	ADP
eurjchem-2037	78	31	nc	nc	PROPN
eurjchem-2037	78	32	–	–	PUNCT
eurjchem-2037	78	33	doi	doi	NOUN
eurjchem-2037	78	34	:	:	PUNCT
eurjchem-2037	78	35	10.5155	10.5155	NUM
eurjchem-2037	78	36	/	/	SYM
eurjchem-2037	78	37	eurjchem.11.4.334	eurjchem.11.4.334	NOUN
eurjchem-2037	78	38	-	-	SYM
eurjchem-2037	78	39	341.2037	341.2037	NUM
eurjchem-2037	78	40	c50h44cu2br2n4p2	c50h44cu2br2n4p2	NOUN
eurjchem-2037	78	41	:	:	PUNCT
eurjchem-2037	78	42	c	c	X
eurjchem-2037	78	43	,	,	PUNCT
eurjchem-2037	78	44	57.21	57.21	NUM
eurjchem-2037	78	45	;	;	PUNCT
eurjchem-2037	78	46	h	h	NOUN
eurjchem-2037	78	47	,	,	PUNCT
eurjchem-2037	78	48	4.22	4.22	NUM
eurjchem-2037	78	49	;	;	PUNCT
eurjchem-2037	78	50	n	n	CCONJ
eurjchem-2037	78	51	,	,	PUNCT
eurjchem-2037	78	52	5.34	5.34	NUM
eurjchem-2037	78	53	.	.	PUNCT
eurjchem-2037	78	54	found	find	VERB
eurjchem-2037	78	55	:	:	PUNCT
eurjchem-2037	79	1	c	c	X
eurjchem-2037	79	2	,	,	PUNCT
eurjchem-2037	79	3	56.98	56.98	NUM
eurjchem-2037	79	4	;	;	PUNCT
eurjchem-2037	79	5	h	h	NOUN
eurjchem-2037	79	6	,	,	PUNCT
eurjchem-2037	79	7	4.33	4.33	NUM
eurjchem-2037	79	8	;	;	PUNCT
eurjchem-2037	79	9	n	n	CCONJ
eurjchem-2037	79	10	,	,	PUNCT
eurjchem-2037	79	11	5.27	5.27	NUM
eurjchem-2037	79	12	%	%	NOUN
eurjchem-2037	79	13	.	.	PUNCT
eurjchem-2037	80	1	uv	uv	NOUN
eurjchem-2037	80	2	/	/	SYM
eurjchem-2037	80	3	vis	vis	X
eurjchem-2037	80	4	(	(	PUNCT
eurjchem-2037	80	5	ch3oh	ch3oh	ADV
eurjchem-2037	80	6	,	,	PUNCT
eurjchem-2037	80	7	λmax	λmax	NOUN
eurjchem-2037	80	8	,	,	PUNCT
eurjchem-2037	80	9	nm	nm	NOUN
eurjchem-2037	80	10	,	,	PUNCT
eurjchem-2037	80	11	(	(	PUNCT
eurjchem-2037	80	12	ε	ε	PROPN
eurjchem-2037	80	13	)	)	PUNCT
eurjchem-2037	80	14	):	):	PUNCT
eurjchem-2037	80	15	366	366	NUM
eurjchem-2037	80	16	(	(	PUNCT
eurjchem-2037	80	17	2.32	2.32	NUM
eurjchem-2037	80	18	)	)	PUNCT
eurjchem-2037	80	19	.	.	PUNCT
eurjchem-2037	81	1	2.5	2.5	NUM
eurjchem-2037	81	2	.	.	PUNCT
eurjchem-2037	81	3	synthesis	synthesis	NOUN
eurjchem-2037	81	4	of	of	ADP
eurjchem-2037	81	5	[	[	X
eurjchem-2037	81	6	cu2(µ-l)(µ-cl)2(pph3)2]n	cu2(µ-l)(µ-cl)2(pph3)2]n	X
eurjchem-2037	81	7	(	(	PUNCT
eurjchem-2037	81	8	3	3	NUM
eurjchem-2037	81	9	)	)	PUNCT
eurjchem-2037	81	10	to	to	ADP
eurjchem-2037	81	11	a	a	DET
eurjchem-2037	81	12	solution	solution	NOUN
eurjchem-2037	81	13	of	of	ADP
eurjchem-2037	81	14	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2037	81	15	(	(	PUNCT
eurjchem-2037	81	16	0.131	0.131	NUM
eurjchem-2037	81	17	g	g	NOUN
eurjchem-2037	81	18	,	,	PUNCT
eurjchem-2037	81	19	0.5	0.5	NUM
eurjchem-2037	81	20	mmol	mmol	NOUN
eurjchem-2037	81	21	)	)	PUNCT
eurjchem-2037	81	22	in	in	ADP
eurjchem-2037	81	23	ch2cl2	ch2cl2	X
eurjchem-2037	81	24	(	(	PUNCT
eurjchem-2037	81	25	30	30	NUM
eurjchem-2037	81	26	ml	ml	NOUN
eurjchem-2037	81	27	)	)	PUNCT
eurjchem-2037	81	28	,	,	PUNCT
eurjchem-2037	81	29	solid	solid	ADJ
eurjchem-2037	81	30	cuprous	cuprous	ADJ
eurjchem-2037	81	31	chloride	chloride	NOUN
eurjchem-2037	81	32	(	(	PUNCT
eurjchem-2037	81	33	0.049	0.049	NUM
eurjchem-2037	81	34	g	g	NOUN
eurjchem-2037	81	35	,	,	PUNCT
eurjchem-2037	81	36	0.5	0.5	NUM
eurjchem-2037	81	37	mmol	mmol	NOUN
eurjchem-2037	81	38	)	)	PUNCT
eurjchem-2037	81	39	was	be	AUX
eurjchem-2037	81	40	added	add	VERB
eurjchem-2037	81	41	.	.	PUNCT
eurjchem-2037	82	1	the	the	DET
eurjchem-2037	82	2	reaction	reaction	NOUN
eurjchem-2037	82	3	mixture	mixture	NOUN
eurjchem-2037	82	4	was	be	AUX
eurjchem-2037	82	5	stirred	stir	VERB
eurjchem-2037	82	6	for	for	SCONJ
eurjchem-2037	82	7	1	1	NUM
eurjchem-2037	82	8	h	h	NOUN
eurjchem-2037	82	9	to	to	PART
eurjchem-2037	82	10	get	get	VERB
eurjchem-2037	82	11	a	a	DET
eurjchem-2037	82	12	clear	clear	ADJ
eurjchem-2037	82	13	reddish	reddish	ADJ
eurjchem-2037	82	14	solution	solution	NOUN
eurjchem-2037	82	15	.	.	PUNCT
eurjchem-2037	83	1	the	the	DET
eurjchem-2037	83	2	20	20	NUM
eurjchem-2037	83	3	ml	ml	NOUN
eurjchem-2037	83	4	ch2cl2	ch2cl2	NOUN
eurjchem-2037	83	5	solution	solution	NOUN
eurjchem-2037	83	6	of	of	ADP
eurjchem-2037	83	7	the	the	DET
eurjchem-2037	83	8	ligand	ligand	NOUN
eurjchem-2037	83	9	,	,	PUNCT
eurjchem-2037	83	10	l	l	PROPN
eurjchem-2037	83	11	(	(	PUNCT
eurjchem-2037	83	12	0.60	0.60	NUM
eurjchem-2037	83	13	g	g	NOUN
eurjchem-2037	83	14	,	,	PUNCT
eurjchem-2037	83	15	0.25	0.25	NUM
eurjchem-2037	83	16	mmol	mmol	NOUN
eurjchem-2037	83	17	)	)	PUNCT
eurjchem-2037	83	18	was	be	AUX
eurjchem-2037	83	19	added	add	VERB
eurjchem-2037	83	20	with	with	ADP
eurjchem-2037	83	21	constant	constant	ADJ
eurjchem-2037	83	22	stirring	stirring	NOUN
eurjchem-2037	83	23	for	for	ADP
eurjchem-2037	83	24	another	another	DET
eurjchem-2037	83	25	1h	1h	NUM
eurjchem-2037	83	26	at	at	ADP
eurjchem-2037	83	27	room	room	NOUN
eurjchem-2037	83	28	temperature	temperature	NOUN
eurjchem-2037	83	29	to	to	PART
eurjchem-2037	83	30	give	give	VERB
eurjchem-2037	83	31	a	a	DET
eurjchem-2037	83	32	clear	clear	ADJ
eurjchem-2037	83	33	red	red	ADJ
eurjchem-2037	83	34	solution	solution	NOUN
eurjchem-2037	83	35	.	.	PUNCT
eurjchem-2037	84	1	the	the	DET
eurjchem-2037	84	2	solution	solution	NOUN
eurjchem-2037	84	3	was	be	AUX
eurjchem-2037	84	4	evaporated	evaporate	VERB
eurjchem-2037	84	5	to	to	PART
eurjchem-2037	84	6	dryness	dryness	VERB
eurjchem-2037	84	7	to	to	PART
eurjchem-2037	84	8	obtain	obtain	VERB
eurjchem-2037	84	9	a	a	DET
eurjchem-2037	84	10	reddish	reddish	ADJ
eurjchem-2037	84	11	-	-	PUNCT
eurjchem-2037	84	12	yellow	yellow	NOUN
eurjchem-2037	84	13	solid	solid	NOUN
eurjchem-2037	84	14	.	.	PUNCT
eurjchem-2037	85	1	it	it	PRON
eurjchem-2037	85	2	was	be	AUX
eurjchem-2037	85	3	washed	wash	VERB
eurjchem-2037	85	4	with	with	ADP
eurjchem-2037	85	5	5	5	NUM
eurjchem-2037	85	6	ml	ml	NOUN
eurjchem-2037	85	7	of	of	ADP
eurjchem-2037	85	8	ch2cl2	ch2cl2	X
eurjchem-2037	85	9	(	(	PUNCT
eurjchem-2037	85	10	scheme	scheme	NOUN
eurjchem-2037	85	11	2	2	NUM
eurjchem-2037	85	12	)	)	PUNCT
eurjchem-2037	85	13	.	.	PUNCT
eurjchem-2037	86	1	[	[	X
eurjchem-2037	86	2	cu2(µ-(1e,1'e)-n	cu2(µ-(1e,1'e)-n	ADJ
eurjchem-2037	86	3	,	,	PUNCT
eurjchem-2037	86	4	n'-(ethane-1,2	n'-(ethane-1,2	NUM
eurjchem-2037	86	5	-	-	PUNCT
eurjchem-2037	86	6	diyl)bis(1-(pyridin-4	diyl)bis(1-(pyridin-4	PROPN
eurjchem-2037	86	7	-	-	PUNCT
eurjchem-2037	86	8	yl)met	yl)met	PRON
eurjchem-2037	86	9	hanimine))(µ-cl)2(pph3)2]n	hanimine))(µ-cl)2(pph3)2]n	PRON
eurjchem-2037	86	10	(	(	PUNCT
eurjchem-2037	86	11	3	3	NUM
eurjchem-2037	86	12	):	):	PUNCT
eurjchem-2037	86	13	color	color	NOUN
eurjchem-2037	86	14	:	:	PUNCT
eurjchem-2037	86	15	reddish	reddish	ADJ
eurjchem-2037	86	16	yellow	yellow	NOUN
eurjchem-2037	86	17	.	.	PUNCT
eurjchem-2037	87	1	yield	yield	NOUN
eurjchem-2037	87	2	:	:	PUNCT
eurjchem-2037	87	3	80	80	NUM
eurjchem-2037	87	4	%	%	NOUN
eurjchem-2037	87	5	.	.	PUNCT
eurjchem-2037	88	1	m.p	m.p	PROPN
eurjchem-2037	88	2	.	.	PROPN
eurjchem-2037	88	3	:	:	PUNCT
eurjchem-2037	89	1	>	>	PUNCT
eurjchem-2037	89	2	200	200	NUM
eurjchem-2037	89	3	°	°	NOUN
eurjchem-2037	89	4	c	c	NOUN
eurjchem-2037	89	5	.	.	PUNCT
eurjchem-2037	89	6	ft	ft	PROPN
eurjchem-2037	89	7	-	-	PUNCT
eurjchem-2037	89	8	ir	ir	PROPN
eurjchem-2037	89	9	(	(	PUNCT
eurjchem-2037	89	10	kbr	kbr	PROPN
eurjchem-2037	89	11	,	,	PUNCT
eurjchem-2037	89	12	ν	ν	PROPN
eurjchem-2037	89	13	,	,	PUNCT
eurjchem-2037	89	14	cm-1	cm-1	NUM
eurjchem-2037	89	15	):	):	PUNCT
eurjchem-2037	89	16	1619	1619	NUM
eurjchem-2037	89	17	(	(	PUNCT
eurjchem-2037	89	18	c	c	NOUN
eurjchem-2037	89	19	=	=	SYM
eurjchem-2037	89	20	n	n	NUM
eurjchem-2037	89	21	)	)	PUNCT
eurjchem-2037	89	22	.	.	PUNCT
eurjchem-2037	90	1	anal	anal	PROPN
eurjchem-2037	90	2	.	.	PUNCT
eurjchem-2037	90	3	calcd	calcd	NOUN
eurjchem-2037	90	4	.	.	PUNCT
eurjchem-2037	91	1	for	for	ADP
eurjchem-2037	91	2	c50h44cu2cl2n4p2	c50h44cu2cl2n4p2	NOUN
eurjchem-2037	91	3	:	:	PUNCT
eurjchem-2037	91	4	c	c	X
eurjchem-2037	91	5	,	,	PUNCT
eurjchem-2037	91	6	62.50	62.50	NUM
eurjchem-2037	91	7	;	;	PUNCT
eurjchem-2037	91	8	h	h	NOUN
eurjchem-2037	91	9	,	,	PUNCT
eurjchem-2037	91	10	4.62	4.62	NUM
eurjchem-2037	91	11	;	;	PUNCT
eurjchem-2037	91	12	n	n	CCONJ
eurjchem-2037	91	13	,	,	PUNCT
eurjchem-2037	91	14	5.83	5.83	NUM
eurjchem-2037	91	15	.	.	PUNCT
eurjchem-2037	91	16	found	find	VERB
eurjchem-2037	91	17	:	:	PUNCT
eurjchem-2037	92	1	c	c	X
eurjchem-2037	92	2	,	,	PUNCT
eurjchem-2037	92	3	62.48	62.48	NUM
eurjchem-2037	92	4	;	;	PUNCT
eurjchem-2037	93	1	h	h	NOUN
eurjchem-2037	93	2	,	,	PUNCT
eurjchem-2037	93	3	4.73	4.73	NUM
eurjchem-2037	93	4	;	;	PUNCT
eurjchem-2037	93	5	n	n	CCONJ
eurjchem-2037	93	6	,	,	PUNCT
eurjchem-2037	93	7	5.74	5.74	NUM
eurjchem-2037	93	8	%	%	NOUN
eurjchem-2037	93	9	.	.	PUNCT
eurjchem-2037	94	1	uv	uv	NOUN
eurjchem-2037	94	2	/	/	SYM
eurjchem-2037	94	3	vis	vis	X
eurjchem-2037	94	4	(	(	PUNCT
eurjchem-2037	94	5	ch3oh	ch3oh	ADV
eurjchem-2037	94	6	,	,	PUNCT
eurjchem-2037	94	7	λmax	λmax	NOUN
eurjchem-2037	94	8	,	,	PUNCT
eurjchem-2037	94	9	nm	nm	NOUN
eurjchem-2037	94	10	,	,	PUNCT
eurjchem-2037	94	11	(	(	PUNCT
eurjchem-2037	94	12	ε	ε	PROPN
eurjchem-2037	94	13	)	)	PUNCT
eurjchem-2037	94	14	):	):	PUNCT
eurjchem-2037	94	15	360	360	NUM
eurjchem-2037	94	16	(	(	PUNCT
eurjchem-2037	94	17	2.32	2.32	NUM
eurjchem-2037	94	18	)	)	PUNCT
eurjchem-2037	94	19	.	.	PUNCT
eurjchem-2037	95	1	2.6	2.6	NUM
eurjchem-2037	95	2	.	.	PUNCT
eurjchem-2037	96	1	x	x	X
eurjchem-2037	96	2	-	-	AUX
eurjchem-2037	96	3	ray	ray	NOUN
eurjchem-2037	96	4	crystallography	crystallography	NOUN
eurjchem-2037	96	5	x	x	NOUN
eurjchem-2037	96	6	-	-	NOUN
eurjchem-2037	96	7	ray	ray	ADJ
eurjchem-2037	96	8	single	single	ADJ
eurjchem-2037	96	9	-	-	PUNCT
eurjchem-2037	96	10	crystal	crystal	NOUN
eurjchem-2037	96	11	data	datum	NOUN
eurjchem-2037	96	12	are	be	AUX
eurjchem-2037	96	13	collected	collect	VERB
eurjchem-2037	96	14	using	use	VERB
eurjchem-2037	96	15	mokα	mokα	ADJ
eurjchem-2037	96	16	(	(	PUNCT
eurjchem-2037	96	17	λ	λ	SYM
eurjchem-2037	96	18	=	=	SYM
eurjchem-2037	96	19	0.7107	0.7107	NUM
eurjchem-2037	96	20	å	å	NOUN
eurjchem-2037	96	21	)	)	PUNCT
eurjchem-2037	96	22	radiation	radiation	NOUN
eurjchem-2037	96	23	on	on	ADP
eurjchem-2037	96	24	a	a	DET
eurjchem-2037	96	25	bruker	bruker	PROPN
eurjchem-2037	96	26	apex	apex	PROPN
eurjchem-2037	96	27	ii	ii	PROPN
eurjchem-2037	96	28	diffractometer	diffractometer	PROPN
eurjchem-2037	96	29	equipped	equip	VERB
eurjchem-2037	96	30	with	with	ADP
eurjchem-2037	96	31	ccd	ccd	PROPN
eurjchem-2037	96	32	area	area	NOUN
eurjchem-2037	96	33	detector	detector	NOUN
eurjchem-2037	96	34	.	.	PUNCT
eurjchem-2037	97	1	data	datum	NOUN
eurjchem-2037	97	2	collection	collection	PROPN
eurjchem-2037	97	3	,	,	PUNCT
eurjchem-2037	97	4	data	datum	NOUN
eurjchem-2037	97	5	reduction	reduction	NOUN
eurjchem-2037	97	6	,	,	PUNCT
eurjchem-2037	97	7	structure	structure	NOUN
eurjchem-2037	97	8	solution	solution	NOUN
eurjchem-2037	97	9	/	/	SYM
eurjchem-2037	97	10	refinement	refinement	NOUN
eurjchem-2037	97	11	are	be	AUX
eurjchem-2037	97	12	carried	carry	VERB
eurjchem-2037	97	13	out	out	ADP
eurjchem-2037	97	14	using	use	VERB
eurjchem-2037	97	15	the	the	DET
eurjchem-2037	97	16	software	software	NOUN
eurjchem-2037	97	17	package	package	NOUN
eurjchem-2037	97	18	of	of	ADP
eurjchem-2037	97	19	smart	smart	ADJ
eurjchem-2037	97	20	apex	apex	NOUN
eurjchem-2037	98	1	[	[	X
eurjchem-2037	98	2	34	34	NUM
eurjchem-2037	98	3	]	]	PUNCT
eurjchem-2037	98	4	.	.	PUNCT
eurjchem-2037	99	1	the	the	DET
eurjchem-2037	99	2	structures	structure	NOUN
eurjchem-2037	99	3	are	be	AUX
eurjchem-2037	99	4	solved	solve	VERB
eurjchem-2037	99	5	by	by	ADP
eurjchem-2037	99	6	direct	direct	ADJ
eurjchem-2037	99	7	methods	method	NOUN
eurjchem-2037	99	8	(	(	PUNCT
eurjchem-2037	99	9	shelxs-97	shelxs-97	PROPN
eurjchem-2037	99	10	)	)	PUNCT
eurjchem-2037	99	11	and	and	CCONJ
eurjchem-2037	99	12	standard	standard	ADJ
eurjchem-2037	99	13	fourier	fourier	NOUN
eurjchem-2037	99	14	techniques	technique	NOUN
eurjchem-2037	99	15	,	,	PUNCT
eurjchem-2037	99	16	and	and	CCONJ
eurjchem-2037	99	17	refined	refine	VERB
eurjchem-2037	99	18	on	on	ADP
eurjchem-2037	99	19	f2	f2	PROPN
eurjchem-2037	99	20	using	use	VERB
eurjchem-2037	99	21	full	full	ADJ
eurjchem-2037	99	22	-	-	PUNCT
eurjchem-2037	99	23	matrix	matrix	NOUN
eurjchem-2037	99	24	least	least	ADJ
eurjchem-2037	99	25	-	-	PUNCT
eurjchem-2037	99	26	squares	square	NOUN
eurjchem-2037	99	27	procedures	procedure	NOUN
eurjchem-2037	99	28	(	(	PUNCT
eurjchem-2037	99	29	shelxl-97	shelxl-97	NOUN
eurjchem-2037	99	30	)	)	PUNCT
eurjchem-2037	99	31	using	use	VERB
eurjchem-2037	99	32	the	the	DET
eurjchem-2037	99	33	shelx-97	shelx-97	PROPN
eurjchem-2037	99	34	package	package	NOUN
eurjchem-2037	99	35	[	[	X
eurjchem-2037	99	36	35	35	NUM
eurjchem-2037	99	37	]	]	PUNCT
eurjchem-2037	99	38	incorporated	incorporate	VERB
eurjchem-2037	99	39	in	in	ADP
eurjchem-2037	99	40	wingx	wingx	NOUN
eurjchem-2037	99	41	[	[	X
eurjchem-2037	99	42	36	36	NUM
eurjchem-2037	99	43	]	]	PUNCT
eurjchem-2037	99	44	.	.	PUNCT
eurjchem-2037	100	1	generally	generally	ADV
eurjchem-2037	100	2	,	,	PUNCT
eurjchem-2037	100	3	non	non	ADJ
eurjchem-2037	100	4	-	-	ADJ
eurjchem-2037	100	5	hydrogen	hydrogen	ADJ
eurjchem-2037	100	6	atoms	atom	NOUN
eurjchem-2037	100	7	are	be	AUX
eurjchem-2037	100	8	considered	consider	VERB
eurjchem-2037	100	9	anisotropically	anisotropically	ADV
eurjchem-2037	100	10	.	.	PUNCT
eurjchem-2037	101	1	whenever	whenever	SCONJ
eurjchem-2037	101	2	possible	possible	ADJ
eurjchem-2037	101	3	,	,	PUNCT
eurjchem-2037	101	4	the	the	DET
eurjchem-2037	101	5	hydrogen	hydrogen	NOUN
eurjchem-2037	101	6	atoms	atom	NOUN
eurjchem-2037	101	7	are	be	AUX
eurjchem-2037	101	8	located	locate	VERB
eurjchem-2037	101	9	on	on	ADP
eurjchem-2037	101	10	a	a	DET
eurjchem-2037	101	11	difference	difference	NOUN
eurjchem-2037	101	12	fourier	fourier	NOUN
eurjchem-2037	101	13	map	map	NOUN
eurjchem-2037	101	14	and	and	CCONJ
eurjchem-2037	101	15	refined	refine	VERB
eurjchem-2037	101	16	.	.	PUNCT
eurjchem-2037	102	1	in	in	ADP
eurjchem-2037	102	2	other	other	ADJ
eurjchem-2037	102	3	cases	case	NOUN
eurjchem-2037	102	4	,	,	PUNCT
eurjchem-2037	102	5	the	the	DET
eurjchem-2037	102	6	hydrogen	hydrogen	NOUN
eurjchem-2037	102	7	atoms	atom	NOUN
eurjchem-2037	102	8	are	be	AUX
eurjchem-2037	102	9	geometrically	geometrically	ADV
eurjchem-2037	102	10	fixed	fix	VERB
eurjchem-2037	102	11	.	.	PUNCT
eurjchem-2037	103	1	2.7	2.7	NUM
eurjchem-2037	103	2	.	.	PUNCT
eurjchem-2037	104	1	theoretical	theoretical	ADJ
eurjchem-2037	104	2	calculations	calculation	NOUN
eurjchem-2037	104	3	gaussian	gaussian	NOUN
eurjchem-2037	104	4	09	09	NUM
eurjchem-2037	104	5	program	program	NOUN
eurjchem-2037	104	6	[	[	X
eurjchem-2037	104	7	37	37	NUM
eurjchem-2037	104	8	]	]	PUNCT
eurjchem-2037	104	9	has	have	AUX
eurjchem-2037	104	10	been	be	AUX
eurjchem-2037	104	11	used	use	VERB
eurjchem-2037	104	12	for	for	ADP
eurjchem-2037	104	13	the	the	DET
eurjchem-2037	104	14	quantum	quantum	ADJ
eurjchem-2037	104	15	chemical	chemical	NOUN
eurjchem-2037	104	16	calculations	calculation	NOUN
eurjchem-2037	104	17	.	.	PUNCT
eurjchem-2037	105	1	the	the	DET
eurjchem-2037	105	2	possible	possible	ADJ
eurjchem-2037	105	3	ground	ground	NOUN
eurjchem-2037	105	4	state	state	NOUN
eurjchem-2037	105	5	structures	structure	NOUN
eurjchem-2037	105	6	have	have	AUX
eurjchem-2037	105	7	been	be	AUX
eurjchem-2037	105	8	optimized	optimize	VERB
eurjchem-2037	105	9	with	with	ADP
eurjchem-2037	105	10	density	density	NOUN
eurjchem-2037	105	11	functional	functional	ADJ
eurjchem-2037	105	12	theory	theory	NOUN
eurjchem-2037	105	13	(	(	PUNCT
eurjchem-2037	105	14	dft	dft	PROPN
eurjchem-2037	105	15	)	)	PUNCT
eurjchem-2037	105	16	at	at	ADP
eurjchem-2037	105	17	b3lyp/6	b3lyp/6	PROPN
eurjchem-2037	105	18	-	-	PROPN
eurjchem-2037	105	19	311g**and	311g**and	NUM
eurjchem-2037	105	20	b3lyp	b3lyp	NOUN
eurjchem-2037	105	21	/	/	SYM
eurjchem-2037	105	22	lanl2dz	lanl2dz	PROPN
eurjchem-2037	105	23	.	.	PUNCT
eurjchem-2037	105	24	gaussview	gaussview	NOUN
eurjchem-2037	105	25	5	5	NUM
eurjchem-2037	105	26	program	program	NOUN
eurjchem-2037	106	1	[	[	X
eurjchem-2037	106	2	38	38	NUM
eurjchem-2037	106	3	]	]	PUNCT
eurjchem-2037	106	4	was	be	AUX
eurjchem-2037	106	5	used	use	VERB
eurjchem-2037	106	6	for	for	ADP
eurjchem-2037	106	7	the	the	DET
eurjchem-2037	106	8	visualization	visualization	NOUN
eurjchem-2037	106	9	of	of	ADP
eurjchem-2037	106	10	the	the	DET
eurjchem-2037	106	11	studied	study	VERB
eurjchem-2037	106	12	systems	system	NOUN
eurjchem-2037	106	13	.	.	PUNCT
eurjchem-2037	107	1	2.8	2.8	NUM
eurjchem-2037	107	2	.	.	PUNCT
eurjchem-2037	108	1	hirshfeld	hirshfeld	PROPN
eurjchem-2037	108	2	surfaces	surface	NOUN
eurjchem-2037	108	3	calculations	calculation	NOUN
eurjchem-2037	108	4	for	for	ADP
eurjchem-2037	108	5	obtaining	obtain	VERB
eurjchem-2037	108	6	additional	additional	ADJ
eurjchem-2037	108	7	insight	insight	NOUN
eurjchem-2037	108	8	into	into	ADP
eurjchem-2037	108	9	the	the	DET
eurjchem-2037	108	10	intermolecular	intermolecular	ADJ
eurjchem-2037	108	11	interaction	interaction	NOUN
eurjchem-2037	108	12	of	of	ADP
eurjchem-2037	108	13	molecular	molecular	ADJ
eurjchem-2037	108	14	crystals	crystal	NOUN
eurjchem-2037	108	15	,	,	PUNCT
eurjchem-2037	108	16	hirshfeld	hirshfeld	PROPN
eurjchem-2037	108	17	surface	surface	NOUN
eurjchem-2037	108	18	analysis	analysis	NOUN
eurjchem-2037	108	19	helps	help	VERB
eurjchem-2037	108	20	as	as	ADP
eurjchem-2037	108	21	a	a	DET
eurjchem-2037	108	22	powerful	powerful	ADJ
eurjchem-2037	108	23	set	set	NOUN
eurjchem-2037	108	24	-	-	PUNCT
eurjchem-2037	108	25	up	up	NOUN
eurjchem-2037	108	26	.	.	PUNCT
eurjchem-2037	109	1	the	the	DET
eurjchem-2037	109	2	size	size	NOUN
eurjchem-2037	109	3	and	and	CCONJ
eurjchem-2037	109	4	shape	shape	NOUN
eurjchem-2037	109	5	of	of	ADP
eurjchem-2037	109	6	hirshfeld	hirshfeld	PROPN
eurjchem-2037	109	7	surface	surface	NOUN
eurjchem-2037	109	8	allow	allow	VERB
eurjchem-2037	109	9	the	the	DET
eurjchem-2037	109	10	qualitative	qualitative	ADJ
eurjchem-2037	109	11	and	and	CCONJ
eurjchem-2037	109	12	quantitative	quantitative	ADJ
eurjchem-2037	109	13	study	study	NOUN
eurjchem-2037	109	14	and	and	CCONJ
eurjchem-2037	109	15	imagining	imagining	NOUN
eurjchem-2037	109	16	of	of	ADP
eurjchem-2037	109	17	intermolecular	intermolecular	ADJ
eurjchem-2037	109	18	close	close	ADJ
eurjchem-2037	109	19	contacts	contact	NOUN
eurjchem-2037	109	20	in	in	ADP
eurjchem-2037	109	21	molecular	molecular	ADJ
eurjchem-2037	109	22	crystals	crystal	NOUN
eurjchem-2037	109	23	[	[	X
eurjchem-2037	109	24	39	39	NUM
eurjchem-2037	109	25	]	]	PUNCT
eurjchem-2037	109	26	.	.	PUNCT
eurjchem-2037	110	1	the	the	DET
eurjchem-2037	110	2	hirshfeld	hirshfeld	PROPN
eurjchem-2037	110	3	surface	surface	NOUN
eurjchem-2037	110	4	enclosing	enclose	VERB
eurjchem-2037	110	5	a	a	DET
eurjchem-2037	110	6	molecule	molecule	NOUN
eurjchem-2037	110	7	is	be	AUX
eurjchem-2037	110	8	defined	define	VERB
eurjchem-2037	110	9	by	by	ADP
eurjchem-2037	110	10	a	a	DET
eurjchem-2037	110	11	set	set	NOUN
eurjchem-2037	110	12	of	of	ADP
eurjchem-2037	110	13	points	point	NOUN
eurjchem-2037	110	14	in	in	ADP
eurjchem-2037	110	15	3d	3d	NUM
eurjchem-2037	110	16	space	space	NOUN
eurjchem-2037	110	17	where	where	SCONJ
eurjchem-2037	110	18	the	the	DET
eurjchem-2037	110	19	contribution	contribution	NOUN
eurjchem-2037	110	20	to	to	ADP
eurjchem-2037	110	21	the	the	DET
eurjchem-2037	110	22	electron	electron	NOUN
eurjchem-2037	110	23	density	density	NOUN
eurjchem-2037	110	24	from	from	ADP
eurjchem-2037	110	25	the	the	DET
eurjchem-2037	110	26	molecule	molecule	NOUN
eurjchem-2037	110	27	of	of	ADP
eurjchem-2037	110	28	interest	interest	NOUN
eurjchem-2037	110	29	is	be	AUX
eurjchem-2037	110	30	equal	equal	ADJ
eurjchem-2037	110	31	to	to	ADP
eurjchem-2037	110	32	the	the	DET
eurjchem-2037	110	33	contribution	contribution	NOUN
eurjchem-2037	110	34	from	from	ADP
eurjchem-2037	110	35	all	all	DET
eurjchem-2037	110	36	other	other	ADJ
eurjchem-2037	110	37	molecules	molecule	NOUN
eurjchem-2037	110	38	.	.	PUNCT
eurjchem-2037	111	1	molecular	molecular	ADJ
eurjchem-2037	111	2	hirshfeld	hirshfeld	ADJ
eurjchem-2037	111	3	surfaces	surface	NOUN
eurjchem-2037	111	4	are	be	AUX
eurjchem-2037	111	5	built	build	VERB
eurjchem-2037	111	6	based	base	VERB
eurjchem-2037	111	7	on	on	ADP
eurjchem-2037	111	8	electron	electron	NOUN
eurjchem-2037	111	9	distribution	distribution	NOUN
eurjchem-2037	111	10	calculated	calculate	VERB
eurjchem-2037	111	11	as	as	ADP
eurjchem-2037	111	12	the	the	DET
eurjchem-2037	111	13	sum	sum	NOUN
eurjchem-2037	111	14	of	of	ADP
eurjchem-2037	111	15	spherical	spherical	ADJ
eurjchem-2037	111	16	atom	atom	NOUN
eurjchem-2037	111	17	electron	electron	NOUN
eurjchem-2037	111	18	densities	density	NOUN
eurjchem-2037	111	19	[	[	X
eurjchem-2037	111	20	27,40	27,40	NUM
eurjchem-2037	111	21	]	]	X
eurjchem-2037	111	22	.	.	PUNCT
eurjchem-2037	112	1	thus	thus	ADV
eurjchem-2037	112	2	,	,	PUNCT
eurjchem-2037	112	3	an	an	DET
eurjchem-2037	112	4	iso	iso	NOUN
eurjchem-2037	112	5	-	-	PUNCT
eurjchem-2037	112	6	surface	surface	NOUN
eurjchem-2037	112	7	is	be	AUX
eurjchem-2037	112	8	obtained	obtain	VERB
eurjchem-2037	112	9	,	,	PUNCT
eurjchem-2037	112	10	and	and	CCONJ
eurjchem-2037	112	11	for	for	ADP
eurjchem-2037	112	12	each	each	DET
eurjchem-2037	112	13	point	point	NOUN
eurjchem-2037	112	14	of	of	ADP
eurjchem-2037	112	15	the	the	DET
eurjchem-2037	112	16	iso	iso	NOUN
eurjchem-2037	112	17	-	-	PUNCT
eurjchem-2037	112	18	surface	surface	NOUN
eurjchem-2037	112	19	,	,	PUNCT
eurjchem-2037	112	20	two	two	NUM
eurjchem-2037	112	21	distances	distance	NOUN
eurjchem-2037	112	22	can	can	AUX
eurjchem-2037	112	23	be	be	AUX
eurjchem-2037	112	24	defined	define	VERB
eurjchem-2037	112	25	:	:	PUNCT
eurjchem-2037	112	26	de	de	X
eurjchem-2037	112	27	,	,	PUNCT
eurjchem-2037	112	28	the	the	DET
eurjchem-2037	112	29	distance	distance	NOUN
eurjchem-2037	112	30	from	from	ADP
eurjchem-2037	112	31	the	the	DET
eurjchem-2037	112	32	point	point	NOUN
eurjchem-2037	112	33	to	to	ADP
eurjchem-2037	112	34	the	the	DET
eurjchem-2037	112	35	nearest	near	ADJ
eurjchem-2037	112	36	atom	atom	NOUN
eurjchem-2037	112	37	outside	outside	ADP
eurjchem-2037	112	38	to	to	ADP
eurjchem-2037	112	39	the	the	DET
eurjchem-2037	112	40	surface	surface	NOUN
eurjchem-2037	112	41	,	,	PUNCT
eurjchem-2037	112	42	and	and	CCONJ
eurjchem-2037	112	43	di	di	NOUN
eurjchem-2037	112	44	,	,	PUNCT
eurjchem-2037	112	45	the	the	DET
eurjchem-2037	112	46	distance	distance	NOUN
eurjchem-2037	112	47	to	to	ADP
eurjchem-2037	112	48	the	the	DET
eurjchem-2037	112	49	nearest	near	ADJ
eurjchem-2037	112	50	atom	atom	NOUN
eurjchem-2037	112	51	inside	inside	ADP
eurjchem-2037	112	52	to	to	ADP
eurjchem-2037	112	53	the	the	DET
eurjchem-2037	112	54	surface	surface	NOUN
eurjchem-2037	112	55	.	.	PUNCT
eurjchem-2037	113	1	furthermore	furthermore	ADV
eurjchem-2037	113	2	,	,	PUNCT
eurjchem-2037	113	3	the	the	DET
eurjchem-2037	113	4	identification	identification	NOUN
eurjchem-2037	113	5	of	of	ADP
eurjchem-2037	113	6	the	the	DET
eurjchem-2037	113	7	regions	region	NOUN
eurjchem-2037	113	8	of	of	ADP
eurjchem-2037	113	9	particular	particular	ADJ
eurjchem-2037	113	10	importance	importance	NOUN
eurjchem-2037	113	11	to	to	ADP
eurjchem-2037	113	12	intermolecular	intermolecular	ADJ
eurjchem-2037	113	13	interactions	interaction	NOUN
eurjchem-2037	113	14	is	be	AUX
eurjchem-2037	113	15	achieved	achieve	VERB
eurjchem-2037	113	16	by	by	ADP
eurjchem-2037	113	17	mapping	mapping	NOUN
eurjchem-2037	113	18	normalized	normalize	VERB
eurjchem-2037	113	19	contact	contact	NOUN
eurjchem-2037	113	20	distance	distance	NOUN
eurjchem-2037	113	21	(	(	PUNCT
eurjchem-2037	113	22	dnorm	dnorm	NOUN
eurjchem-2037	113	23	)	)	PUNCT
eurjchem-2037	113	24	,	,	PUNCT
eurjchem-2037	113	25	expressed	express	VERB
eurjchem-2037	113	26	as	as	ADP
eurjchem-2037	113	27	:	:	PUNCT
eurjchem-2037	113	28	dnorm	dnorm	NOUN
eurjchem-2037	113	29	=	=	SYM
eurjchem-2037	113	30	(	(	PUNCT
eurjchem-2037	113	31	di	di	NOUN
eurjchem-2037	113	32	-	-	PUNCT
eurjchem-2037	113	33	rivdw)/rivdw+(de	rivdw)/rivdw+(de	ADJ
eurjchem-2037	113	34	-	-	PUNCT
eurjchem-2037	113	35	revdw)/	revdw)/	NOUN
eurjchem-2037	113	36	revdw	revdw	NOUN
eurjchem-2037	113	37	;	;	PUNCT
eurjchem-2037	113	38	where	where	SCONJ
eurjchem-2037	113	39	rivdw	rivdw	NOUN
eurjchem-2037	113	40	and	and	CCONJ
eurjchem-2037	113	41	revdw	revdw	NOUN
eurjchem-2037	113	42	are	be	AUX
eurjchem-2037	113	43	the	the	DET
eurjchem-2037	113	44	van	van	PROPN
eurjchem-2037	113	45	der	der	NOUN
eurjchem-2037	113	46	waals	waal	NOUN
eurjchem-2037	113	47	radii	radius	NOUN
eurjchem-2037	113	48	of	of	ADP
eurjchem-2037	113	49	the	the	DET
eurjchem-2037	113	50	atoms	atom	NOUN
eurjchem-2037	113	51	[	[	X
eurjchem-2037	113	52	26	26	NUM
eurjchem-2037	113	53	]	]	PUNCT
eurjchem-2037	113	54	.	.	PUNCT
eurjchem-2037	114	1	the	the	DET
eurjchem-2037	114	2	value	value	NOUN
eurjchem-2037	114	3	of	of	ADP
eurjchem-2037	114	4	dnorm	dnorm	NOUN
eurjchem-2037	114	5	is	be	AUX
eurjchem-2037	114	6	negative	negative	ADJ
eurjchem-2037	114	7	or	or	CCONJ
eurjchem-2037	114	8	positive	positive	ADJ
eurjchem-2037	114	9	when	when	SCONJ
eurjchem-2037	114	10	intermolecular	intermolecular	ADJ
eurjchem-2037	114	11	contacts	contact	NOUN
eurjchem-2037	114	12	are	be	AUX
eurjchem-2037	114	13	shorter	short	ADJ
eurjchem-2037	114	14	or	or	CCONJ
eurjchem-2037	114	15	longer	long	ADJ
eurjchem-2037	114	16	than	than	ADP
eurjchem-2037	114	17	rvdw	rvdw	NOUN
eurjchem-2037	114	18	,	,	PUNCT
eurjchem-2037	114	19	respectively	respectively	ADV
eurjchem-2037	114	20	.	.	PUNCT
eurjchem-2037	115	1	the	the	DET
eurjchem-2037	115	2	graphical	graphical	ADJ
eurjchem-2037	115	3	plots	plot	NOUN
eurjchem-2037	115	4	of	of	ADP
eurjchem-2037	115	5	the	the	DET
eurjchem-2037	115	6	molecular	molecular	ADJ
eurjchem-2037	115	7	hirshfeld	hirshfeld	NOUN
eurjchem-2037	115	8	surfaces	surface	NOUN
eurjchem-2037	115	9	mapped	map	VERB
eurjchem-2037	115	10	with	with	ADP
eurjchem-2037	115	11	dnorm	dnorm	NOUN
eurjchem-2037	115	12	employ	employ	VERB
eurjchem-2037	115	13	the	the	DET
eurjchem-2037	115	14	red	red	ADJ
eurjchem-2037	115	15	-	-	PUNCT
eurjchem-2037	115	16	white	white	ADJ
eurjchem-2037	115	17	-	-	PUNCT
eurjchem-2037	115	18	blue	blue	ADJ
eurjchem-2037	115	19	color	color	NOUN
eurjchem-2037	115	20	scheme	scheme	NOUN
eurjchem-2037	115	21	,	,	PUNCT
eurjchem-2037	115	22	where	where	SCONJ
eurjchem-2037	115	23	red	red	ADJ
eurjchem-2037	115	24	color	color	NOUN
eurjchem-2037	115	25	indicates	indicate	VERB
eurjchem-2037	115	26	the	the	DET
eurjchem-2037	115	27	shorter	short	ADJ
eurjchem-2037	115	28	intermolecular	intermolecular	ADJ
eurjchem-2037	115	29	contacts	contact	NOUN
eurjchem-2037	115	30	,	,	PUNCT
eurjchem-2037	115	31	white	white	ADJ
eurjchem-2037	115	32	color	color	NOUN
eurjchem-2037	115	33	shows	show	VERB
eurjchem-2037	115	34	the	the	DET
eurjchem-2037	115	35	contacts	contact	NOUN
eurjchem-2037	115	36	around	around	ADP
eurjchem-2037	115	37	the	the	DET
eurjchem-2037	115	38	rvdw	rvdw	NOUN
eurjchem-2037	115	39	separation	separation	NOUN
eurjchem-2037	115	40	,	,	PUNCT
eurjchem-2037	115	41	and	and	CCONJ
eurjchem-2037	115	42	blue	blue	ADJ
eurjchem-2037	115	43	color	color	NOUN
eurjchem-2037	115	44	is	be	AUX
eurjchem-2037	115	45	used	use	VERB
eurjchem-2037	115	46	to	to	PART
eurjchem-2037	115	47	point	point	VERB
eurjchem-2037	115	48	out	out	ADP
eurjchem-2037	115	49	the	the	DET
eurjchem-2037	115	50	longer	long	ADJ
eurjchem-2037	115	51	contact	contact	NOUN
eurjchem-2037	115	52	distances	distance	NOUN
eurjchem-2037	115	53	.	.	PUNCT
eurjchem-2037	116	1	due	due	ADP
eurjchem-2037	116	2	to	to	ADP
eurjchem-2037	116	3	the	the	DET
eurjchem-2037	116	4	symmetry	symmetry	NOUN
eurjchem-2037	116	5	between	between	ADP
eurjchem-2037	116	6	de	de	X
eurjchem-2037	116	7	and	and	CCONJ
eurjchem-2037	116	8	di	di	NOUN
eurjchem-2037	116	9	in	in	ADP
eurjchem-2037	116	10	the	the	DET
eurjchem-2037	116	11	expression	expression	NOUN
eurjchem-2037	116	12	for	for	ADP
eurjchem-2037	116	13	dnorm	dnorm	NOUN
eurjchem-2037	116	14	,	,	PUNCT
eurjchem-2037	116	15	where	where	SCONJ
eurjchem-2037	116	16	two	two	NUM
eurjchem-2037	116	17	hirshfeld	hirshfeld	NOUN
eurjchem-2037	116	18	surfaces	surface	NOUN
eurjchem-2037	116	19	touch	touch	VERB
eurjchem-2037	116	20	,	,	PUNCT
eurjchem-2037	116	21	both	both	PRON
eurjchem-2037	116	22	will	will	AUX
eurjchem-2037	116	23	display	display	VERB
eurjchem-2037	116	24	a	a	DET
eurjchem-2037	116	25	red	red	ADJ
eurjchem-2037	116	26	spot	spot	NOUN
eurjchem-2037	116	27	identical	identical	ADJ
eurjchem-2037	116	28	in	in	ADP
eurjchem-2037	116	29	color	color	NOUN
eurjchem-2037	116	30	intensity	intensity	NOUN
eurjchem-2037	116	31	as	as	ADV
eurjchem-2037	116	32	well	well	ADV
eurjchem-2037	116	33	as	as	ADP
eurjchem-2037	116	34	size	size	NOUN
eurjchem-2037	116	35	and	and	CCONJ
eurjchem-2037	116	36	shape	shape	NOUN
eurjchem-2037	116	37	[	[	X
eurjchem-2037	116	38	41	41	NUM
eurjchem-2037	116	39	]	]	PUNCT
eurjchem-2037	116	40	.	.	PUNCT
eurjchem-2037	117	1	the	the	DET
eurjchem-2037	117	2	mixture	mixture	NOUN
eurjchem-2037	117	3	of	of	ADP
eurjchem-2037	117	4	de	de	X
eurjchem-2037	117	5	and	and	CCONJ
eurjchem-2037	117	6	di	di	NOUN
eurjchem-2037	117	7	in	in	ADP
eurjchem-2037	117	8	the	the	DET
eurjchem-2037	117	9	form	form	NOUN
eurjchem-2037	117	10	of	of	ADP
eurjchem-2037	117	11	a	a	DET
eurjchem-2037	117	12	2d	2d	NUM
eurjchem-2037	117	13	fingerprint	fingerprint	NOUN
eurjchem-2037	117	14	plot	plot	NOUN
eurjchem-2037	117	15	provides	provide	VERB
eurjchem-2037	117	16	a	a	DET
eurjchem-2037	117	17	summary	summary	NOUN
eurjchem-2037	117	18	of	of	ADP
eurjchem-2037	117	19	intermolecular	intermolecular	ADJ
eurjchem-2037	117	20	contacts	contact	NOUN
eurjchem-2037	117	21	in	in	ADP
eurjchem-2037	117	22	the	the	DET
eurjchem-2037	117	23	crystal	crystal	NOUN
eurjchem-2037	117	24	and	and	CCONJ
eurjchem-2037	117	25	are	be	AUX
eurjchem-2037	117	26	in	in	ADP
eurjchem-2037	117	27	complement	complement	NOUN
eurjchem-2037	117	28	to	to	ADP
eurjchem-2037	117	29	the	the	DET
eurjchem-2037	117	30	hirshfeld	hirshfeld	ADJ
eurjchem-2037	117	31	surfaces	surface	NOUN
eurjchem-2037	117	32	[	[	X
eurjchem-2037	117	33	26	26	NUM
eurjchem-2037	117	34	]	]	PUNCT
eurjchem-2037	117	35	.	.	PUNCT
eurjchem-2037	118	1	the	the	DET
eurjchem-2037	118	2	information	information	NOUN
eurjchem-2037	118	3	about	about	ADP
eurjchem-2037	118	4	the	the	DET
eurjchem-2037	118	5	intermolecular	intermolecular	ADJ
eurjchem-2037	118	6	interactions	interaction	NOUN
eurjchem-2037	118	7	in	in	ADP
eurjchem-2037	118	8	the	the	DET
eurjchem-2037	118	9	immediate	immediate	ADJ
eurjchem-2037	118	10	environment	environment	NOUN
eurjchem-2037	118	11	of	of	ADP
eurjchem-2037	118	12	each	each	DET
eurjchem-2037	118	13	molecule	molecule	NOUN
eurjchem-2037	118	14	in	in	ADP
eurjchem-2037	118	15	the	the	DET
eurjchem-2037	118	16	asymmetric	asymmetric	ADJ
eurjchem-2037	118	17	unit	unit	NOUN
eurjchem-2037	118	18	is	be	AUX
eurjchem-2037	118	19	achieved	achieve	VERB
eurjchem-2037	118	20	by	by	ADP
eurjchem-2037	118	21	such	such	ADJ
eurjchem-2037	118	22	plots	plot	NOUN
eurjchem-2037	118	23	.	.	PUNCT
eurjchem-2037	119	1	in	in	ADP
eurjchem-2037	119	2	addition	addition	NOUN
eurjchem-2037	119	3	,	,	PUNCT
eurjchem-2037	119	4	the	the	DET
eurjchem-2037	119	5	close	close	ADJ
eurjchem-2037	119	6	contacts	contact	NOUN
eurjchem-2037	119	7	between	between	ADP
eurjchem-2037	119	8	particular	particular	ADJ
eurjchem-2037	119	9	atom	atom	NOUN
eurjchem-2037	119	10	types	type	NOUN
eurjchem-2037	119	11	can	can	AUX
eurjchem-2037	119	12	be	be	AUX
eurjchem-2037	119	13	highlighted	highlight	VERB
eurjchem-2037	119	14	in	in	ADP
eurjchem-2037	119	15	so	so	ADV
eurjchem-2037	119	16	-	-	PUNCT
eurjchem-2037	119	17	called	call	VERB
eurjchem-2037	119	18	resolved	resolved	ADJ
eurjchem-2037	119	19	fingerprint	fingerprint	NOUN
eurjchem-2037	119	20	plots	plot	NOUN
eurjchem-2037	119	21	[	[	X
eurjchem-2037	119	22	28	28	NUM
eurjchem-2037	119	23	]	]	PUNCT
eurjchem-2037	119	24	,	,	PUNCT
eurjchem-2037	119	25	which	which	PRON
eurjchem-2037	119	26	allow	allow	VERB
eurjchem-2037	119	27	the	the	DET
eurjchem-2037	119	28	facile	facile	ADJ
eurjchem-2037	119	29	assignment	assignment	NOUN
eurjchem-2037	119	30	of	of	ADP
eurjchem-2037	119	31	an	an	DET
eurjchem-2037	119	32	intermolecular	intermolecular	ADJ
eurjchem-2037	119	33	contact	contact	NOUN
eurjchem-2037	119	34	to	to	ADP
eurjchem-2037	119	35	a	a	DET
eurjchem-2037	119	36	certain	certain	ADJ
eurjchem-2037	119	37	type	type	NOUN
eurjchem-2037	119	38	of	of	ADP
eurjchem-2037	119	39	interaction	interaction	NOUN
eurjchem-2037	119	40	and	and	CCONJ
eurjchem-2037	119	41	quantitatively	quantitatively	ADV
eurjchem-2037	119	42	summarize	summarize	VERB
eurjchem-2037	119	43	the	the	DET
eurjchem-2037	119	44	nature	nature	NOUN
eurjchem-2037	119	45	and	and	CCONJ
eurjchem-2037	119	46	type	type	NOUN
eurjchem-2037	119	47	of	of	ADP
eurjchem-2037	119	48	intermolecular	intermolecular	ADJ
eurjchem-2037	119	49	contacts	contact	NOUN
eurjchem-2037	119	50	.	.	PUNCT
eurjchem-2037	120	1	two	two	NUM
eurjchem-2037	120	2	additional	additional	ADJ
eurjchem-2037	120	3	colored	colored	ADJ
eurjchem-2037	120	4	properties	property	NOUN
eurjchem-2037	120	5	(	(	PUNCT
eurjchem-2037	120	6	shape	shape	NOUN
eurjchem-2037	120	7	index	index	NOUN
eurjchem-2037	120	8	and	and	CCONJ
eurjchem-2037	120	9	curvedness	curvedness	NOUN
eurjchem-2037	120	10	)	)	PUNCT
eurjchem-2037	120	11	based	base	VERB
eurjchem-2037	120	12	on	on	ADP
eurjchem-2037	120	13	the	the	DET
eurjchem-2037	120	14	local	local	ADJ
eurjchem-2037	120	15	curvature	curvature	NOUN
eurjchem-2037	120	16	of	of	ADP
eurjchem-2037	120	17	the	the	DET
eurjchem-2037	120	18	surface	surface	NOUN
eurjchem-2037	120	19	can	can	AUX
eurjchem-2037	120	20	also	also	ADV
eurjchem-2037	120	21	be	be	AUX
eurjchem-2037	120	22	specified	specify	VERB
eurjchem-2037	120	23	[	[	PUNCT
eurjchem-2037	120	24	42	42	NUM
eurjchem-2037	120	25	]	]	PUNCT
eurjchem-2037	120	26	.	.	PUNCT
eurjchem-2037	121	1	the	the	DET
eurjchem-2037	121	2	hirshfeld	hirshfeld	PROPN
eurjchem-2037	121	3	surfaces	surface	NOUN
eurjchem-2037	121	4	are	be	AUX
eurjchem-2037	121	5	mapped	map	VERB
eurjchem-2037	121	6	with	with	ADP
eurjchem-2037	121	7	dnorm	dnorm	NOUN
eurjchem-2037	121	8	,	,	PUNCT
eurjchem-2037	121	9	shape	shape	NOUN
eurjchem-2037	121	10	-	-	PUNCT
eurjchem-2037	121	11	index	index	NOUN
eurjchem-2037	121	12	,	,	PUNCT
eurjchem-2037	121	13	curvedness	curvedness	ADJ
eurjchem-2037	121	14	and	and	CCONJ
eurjchem-2037	121	15	2d	2d	NUM
eurjchem-2037	121	16	fingerprint	fingerprint	NOUN
eurjchem-2037	121	17	plots	plot	NOUN
eurjchem-2037	121	18	(	(	PUNCT
eurjchem-2037	121	19	full	full	ADJ
eurjchem-2037	121	20	and	and	CCONJ
eurjchem-2037	121	21	resolved	resolve	VERB
eurjchem-2037	121	22	)	)	PUNCT
eurjchem-2037	121	23	reported	report	VERB
eurjchem-2037	121	24	in	in	ADP
eurjchem-2037	121	25	this	this	DET
eurjchem-2037	121	26	manuscript	manuscript	NOUN
eurjchem-2037	121	27	were	be	AUX
eurjchem-2037	121	28	generated	generate	VERB
eurjchem-2037	121	29	using	use	VERB
eurjchem-2037	121	30	crystal	crystal	NOUN
eurjchem-2037	121	31	-	-	PUNCT
eurjchem-2037	121	32	explorer	explorer	NOUN
eurjchem-2037	121	33	3.1	3.1	NUM
eurjchem-2037	122	1	[	[	X
eurjchem-2037	122	2	43	43	NUM
eurjchem-2037	122	3	]	]	PUNCT
eurjchem-2037	122	4	.	.	PUNCT
eurjchem-2037	123	1	2.9	2.9	NUM
eurjchem-2037	123	2	.	.	PUNCT
eurjchem-2037	124	1	molecular	molecular	ADJ
eurjchem-2037	124	2	electrostatic	electrostatic	ADJ
eurjchem-2037	124	3	potential	potential	NOUN
eurjchem-2037	124	4	(	(	PUNCT
eurjchem-2037	124	5	mep	mep	PROPN
eurjchem-2037	124	6	)	)	PUNCT
eurjchem-2037	124	7	the	the	DET
eurjchem-2037	124	8	molecular	molecular	ADJ
eurjchem-2037	124	9	electrostatic	electrostatic	ADJ
eurjchem-2037	124	10	potential	potential	NOUN
eurjchem-2037	124	11	at	at	ADP
eurjchem-2037	124	12	a	a	DET
eurjchem-2037	124	13	given	give	VERB
eurjchem-2037	124	14	point	point	NOUN
eurjchem-2037	124	15	around	around	ADP
eurjchem-2037	124	16	a	a	DET
eurjchem-2037	124	17	molecule	molecule	NOUN
eurjchem-2037	124	18	can	can	AUX
eurjchem-2037	124	19	be	be	AUX
eurjchem-2037	124	20	defined	define	VERB
eurjchem-2037	124	21	in	in	ADP
eurjchem-2037	124	22	terms	term	NOUN
eurjchem-2037	124	23	of	of	ADP
eurjchem-2037	124	24	total	total	ADJ
eurjchem-2037	124	25	charge	charge	NOUN
eurjchem-2037	124	26	distribution	distribution	NOUN
eurjchem-2037	124	27	of	of	ADP
eurjchem-2037	124	28	the	the	DET
eurjchem-2037	124	29	molecule	molecule	NOUN
eurjchem-2037	124	30	and	and	CCONJ
eurjchem-2037	124	31	relates	relate	VERB
eurjchem-2037	124	32	with	with	ADP
eurjchem-2037	124	33	dipole	dipole	NOUN
eurjchem-2037	124	34	moments	moment	NOUN
eurjchem-2037	124	35	.	.	PUNCT
eurjchem-2037	125	1	it	it	PRON
eurjchem-2037	125	2	supplies	supply	VERB
eurjchem-2037	125	3	a	a	DET
eurjchem-2037	125	4	method	method	NOUN
eurjchem-2037	125	5	to	to	PART
eurjchem-2037	125	6	understand	understand	VERB
eurjchem-2037	125	7	the	the	DET
eurjchem-2037	125	8	electron	electron	NOUN
eurjchem-2037	125	9	density	density	NOUN
eurjchem-2037	125	10	which	which	PRON
eurjchem-2037	125	11	is	be	AUX
eurjchem-2037	125	12	useful	useful	ADJ
eurjchem-2037	125	13	for	for	ADP
eurjchem-2037	125	14	determining	determine	VERB
eurjchem-2037	125	15	the	the	DET
eurjchem-2037	125	16	electrophilic	electrophilic	ADJ
eurjchem-2037	125	17	reactivity	reactivity	NOUN
eurjchem-2037	125	18	and	and	CCONJ
eurjchem-2037	125	19	nucleophilic	nucleophilic	ADJ
eurjchem-2037	125	20	reactivity	reactivity	NOUN
eurjchem-2037	125	21	along	along	ADP
eurjchem-2037	125	22	with	with	ADP
eurjchem-2037	125	23	hydrogen	hydrogen	NOUN
eurjchem-2037	125	24	-	-	PUNCT
eurjchem-2037	125	25	bonding	bonding	NOUN
eurjchem-2037	125	26	interactions	interaction	NOUN
eurjchem-2037	125	27	[	[	X
eurjchem-2037	125	28	44,45	44,45	NOUN
eurjchem-2037	125	29	]	]	X
eurjchem-2037	125	30	.	.	PUNCT
eurjchem-2037	126	1	3	3	X
eurjchem-2037	126	2	.	.	NOUN
eurjchem-2037	126	3	results	result	NOUN
eurjchem-2037	126	4	and	and	CCONJ
eurjchem-2037	126	5	discussion	discussion	NOUN
eurjchem-2037	126	6	3.1	3.1	NUM
eurjchem-2037	126	7	.	.	PUNCT
eurjchem-2037	127	1	syntheses	synthesis	NOUN
eurjchem-2037	127	2	of	of	ADP
eurjchem-2037	127	3	the	the	DET
eurjchem-2037	127	4	complexes	complex	NOUN
eurjchem-2037	127	5	1	1	NUM
eurjchem-2037	127	6	,	,	PUNCT
eurjchem-2037	127	7	2	2	NUM
eurjchem-2037	127	8	and	and	CCONJ
eurjchem-2037	127	9	3	3	NUM
eurjchem-2037	127	10	imino	imino	NOUN
eurjchem-2037	127	11	-	-	PUNCT
eurjchem-2037	127	12	pyridyl	pyridyl	NOUN
eurjchem-2037	127	13	ligand	ligand	PROPN
eurjchem-2037	127	14	l	l	PROPN
eurjchem-2037	127	15	is	be	AUX
eurjchem-2037	127	16	a	a	DET
eurjchem-2037	127	17	1	1	NUM
eurjchem-2037	127	18	+	+	SYM
eurjchem-2037	127	19	2	2	NUM
eurjchem-2037	127	20	condensate	condensate	NOUN
eurjchem-2037	127	21	of	of	ADP
eurjchem-2037	127	22	ethylene	ethylene	NOUN
eurjchem-2037	127	23	diamine	diamine	NOUN
eurjchem-2037	127	24	and	and	CCONJ
eurjchem-2037	127	25	4	4	NUM
eurjchem-2037	127	26	-	-	NUM
eurjchem-2037	127	27	pyridinecarboxaldehyde	pyridinecarboxaldehyde	NOUN
eurjchem-2037	127	28	.	.	PUNCT
eurjchem-2037	128	1	the	the	DET
eurjchem-2037	128	2	cu(i	cu(i	NOUN
eurjchem-2037	128	3	)	)	PUNCT
eurjchem-2037	128	4	complexes	complex	NOUN
eurjchem-2037	128	5	1	1	NUM
eurjchem-2037	128	6	,	,	PUNCT
eurjchem-2037	128	7	2	2	NUM
eurjchem-2037	128	8	and	and	CCONJ
eurjchem-2037	128	9	3	3	NUM
eurjchem-2037	128	10	have	have	AUX
eurjchem-2037	128	11	been	be	AUX
eurjchem-2037	128	12	synthesized	synthesize	VERB
eurjchem-2037	128	13	in	in	ADP
eurjchem-2037	128	14	good	good	ADJ
eurjchem-2037	128	15	yields	yield	NOUN
eurjchem-2037	128	16	by	by	ADP
eurjchem-2037	128	17	reacting	react	VERB
eurjchem-2037	128	18	l	l	NOUN
eurjchem-2037	128	19	with	with	ADP
eurjchem-2037	128	20	cu(i)x	cu(i)x	PROPN
eurjchem-2037	128	21	(	(	PUNCT
eurjchem-2037	128	22	x	x	NOUN
eurjchem-2037	128	23	:	:	PUNCT
eurjchem-2037	128	24	i	i	PRON
eurjchem-2037	128	25	,	,	PUNCT
eurjchem-2037	128	26	br	br	PROPN
eurjchem-2037	128	27	and	and	CCONJ
eurjchem-2037	128	28	cl	cl	NOUN
eurjchem-2037	128	29	)	)	PUNCT
eurjchem-2037	128	30	and	and	CCONJ
eurjchem-2037	128	31	pph3	pph3	NOUN
eurjchem-2037	128	32	in	in	ADP
eurjchem-2037	128	33	1:2:2	1:2:2	NUM
eurjchem-2037	128	34	proportion	proportion	NOUN
eurjchem-2037	128	35	in	in	ADP
eurjchem-2037	128	36	dichloromethane	dichloromethane	NOUN
eurjchem-2037	128	37	solvent	solvent	NOUN
eurjchem-2037	128	38	at	at	ADP
eurjchem-2037	128	39	room	room	NOUN
eurjchem-2037	128	40	temperature	temperature	NOUN
eurjchem-2037	128	41	.	.	PUNCT
eurjchem-2037	129	1	the	the	DET
eurjchem-2037	129	2	syntheses	synthesis	NOUN
eurjchem-2037	129	3	of	of	ADP
eurjchem-2037	129	4	the	the	DET
eurjchem-2037	129	5	complexes	complex	NOUN
eurjchem-2037	129	6	1	1	NUM
eurjchem-2037	129	7	,	,	PUNCT
eurjchem-2037	129	8	2	2	NUM
eurjchem-2037	129	9	and	and	CCONJ
eurjchem-2037	129	10	3	3	NUM
eurjchem-2037	129	11	are	be	AUX
eurjchem-2037	129	12	summarized	summarize	VERB
eurjchem-2037	129	13	in	in	ADP
eurjchem-2037	129	14	scheme	scheme	NOUN
eurjchem-2037	129	15	2	2	NUM
eurjchem-2037	129	16	.	.	PUNCT
eurjchem-2037	130	1	these	these	DET
eurjchem-2037	130	2	complexes	complex	NOUN
eurjchem-2037	130	3	are	be	AUX
eurjchem-2037	130	4	stable	stable	ADJ
eurjchem-2037	130	5	in	in	ADP
eurjchem-2037	130	6	the	the	DET
eurjchem-2037	130	7	solid	solid	ADJ
eurjchem-2037	130	8	state	state	NOUN
eurjchem-2037	130	9	for	for	ADP
eurjchem-2037	130	10	about	about	ADV
eurjchem-2037	130	11	2	2	NUM
eurjchem-2037	130	12	-	-	SYM
eurjchem-2037	130	13	3	3	NUM
eurjchem-2037	130	14	weeks	week	NOUN
eurjchem-2037	130	15	in	in	ADP
eurjchem-2037	130	16	air	air	NOUN
eurjchem-2037	130	17	.	.	PUNCT
eurjchem-2037	131	1	3.2	3.2	NUM
eurjchem-2037	131	2	.	.	PUNCT
eurjchem-2037	132	1	structural	structural	ADJ
eurjchem-2037	132	2	description	description	NOUN
eurjchem-2037	132	3	of	of	ADP
eurjchem-2037	132	4	the	the	DET
eurjchem-2037	132	5	complex	complex	ADJ
eurjchem-2037	132	6	2	2	NUM
eurjchem-2037	132	7	single	single	ADJ
eurjchem-2037	132	8	crystal	crystal	NOUN
eurjchem-2037	132	9	xrd	xrd	NOUN
eurjchem-2037	132	10	analysis	analysis	NOUN
eurjchem-2037	132	11	unveils	unveil	VERB
eurjchem-2037	132	12	that	that	SCONJ
eurjchem-2037	132	13	complex	complex	ADJ
eurjchem-2037	132	14	2	2	NUM
eurjchem-2037	132	15	is	be	AUX
eurjchem-2037	132	16	crystallized	crystallize	VERB
eurjchem-2037	132	17	in	in	ADP
eurjchem-2037	132	18	a	a	DET
eurjchem-2037	132	19	triclinic	triclinic	ADJ
eurjchem-2037	132	20	p-1space	p-1space	NOUN
eurjchem-2037	132	21	group	group	NOUN
eurjchem-2037	132	22	and	and	CCONJ
eurjchem-2037	132	23	it	it	PRON
eurjchem-2037	132	24	is	be	AUX
eurjchem-2037	132	25	a	a	DET
eurjchem-2037	132	26	1	1	NUM
eurjchem-2037	132	27	-	-	PUNCT
eurjchem-2037	132	28	d	d	NOUN
eurjchem-2037	132	29	coordination	coordination	NOUN
eurjchem-2037	132	30	polymer	polymer	NOUN
eurjchem-2037	132	31	.	.	PUNCT
eurjchem-2037	133	1	the	the	DET
eurjchem-2037	133	2	molecular	molecular	ADJ
eurjchem-2037	133	3	diagram	diagram	NOUN
eurjchem-2037	133	4	of	of	ADP
eurjchem-2037	133	5	the	the	DET
eurjchem-2037	133	6	complex	complex	NOUN
eurjchem-2037	133	7	is	be	AUX
eurjchem-2037	133	8	shown	show	VERB
eurjchem-2037	133	9	in	in	ADP
eurjchem-2037	133	10	figure	figure	NOUN
eurjchem-2037	133	11	1	1	NUM
eurjchem-2037	133	12	.	.	PUNCT
eurjchem-2037	134	1	the	the	DET
eurjchem-2037	134	2	crystallographic	crystallographic	ADJ
eurjchem-2037	134	3	details	detail	NOUN
eurjchem-2037	134	4	of	of	ADP
eurjchem-2037	134	5	complex	complex	ADJ
eurjchem-2037	134	6	2	2	NUM
eurjchem-2037	134	7	have	have	AUX
eurjchem-2037	134	8	been	be	AUX
eurjchem-2037	134	9	summarized	summarize	VERB
eurjchem-2037	134	10	in	in	ADP
eurjchem-2037	134	11	table	table	NOUN
eurjchem-2037	134	12	1	1	NUM
eurjchem-2037	134	13	,	,	PUNCT
eurjchem-2037	134	14	bond	bond	NOUN
eurjchem-2037	134	15	lengths	length	NOUN
eurjchem-2037	134	16	and	and	CCONJ
eurjchem-2037	134	17	angles	angle	NOUN
eurjchem-2037	134	18	of	of	ADP
eurjchem-2037	134	19	complex	complex	ADJ
eurjchem-2037	134	20	2	2	NUM
eurjchem-2037	134	21	have	have	AUX
eurjchem-2037	134	22	been	be	AUX
eurjchem-2037	134	23	listed	list	VERB
eurjchem-2037	134	24	in	in	ADP
eurjchem-2037	134	25	table	table	NOUN
eurjchem-2037	134	26	2	2	NUM
eurjchem-2037	134	27	and	and	CCONJ
eurjchem-2037	134	28	3	3	NUM
eurjchem-2037	134	29	,	,	PUNCT
eurjchem-2037	134	30	respectively	respectively	ADV
eurjchem-2037	134	31	.	.	PUNCT
eurjchem-2037	135	1	compound	compound	NOUN
eurjchem-2037	135	2	2	2	NUM
eurjchem-2037	135	3	consists	consist	VERB
eurjchem-2037	135	4	of	of	ADP
eurjchem-2037	135	5	two	two	NUM
eurjchem-2037	135	6	independent	independent	ADJ
eurjchem-2037	135	7	cu(i	cu(i	NOUN
eurjchem-2037	135	8	)	)	PUNCT
eurjchem-2037	135	9	ions	ion	NOUN
eurjchem-2037	135	10	,	,	PUNCT
eurjchem-2037	135	11	two	two	NUM
eurjchem-2037	135	12	bromide	bromide	NOUN
eurjchem-2037	135	13	anions	anion	NOUN
eurjchem-2037	135	14	,	,	PUNCT
eurjchem-2037	135	15	and	and	CCONJ
eurjchem-2037	135	16	two	two	NUM
eurjchem-2037	135	17	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2037	135	18	units	unit	NOUN
eurjchem-2037	135	19	with	with	ADP
eurjchem-2037	135	20	one	one	NUM
eurjchem-2037	135	21	imino	imino	NOUN
eurjchem-2037	135	22	-	-	PUNCT
eurjchem-2037	135	23	pyridyl	pyridyl	NOUN
eurjchem-2037	135	24	ligand	ligand	PROPN
eurjchem-2037	135	25	l.	l.	PROPN
eurjchem-2037	135	26	each	each	DET
eurjchem-2037	135	27	cu(i	cu(i	NOUN
eurjchem-2037	135	28	)	)	PUNCT
eurjchem-2037	135	29	cation	cation	NOUN
eurjchem-2037	135	30	shows	show	VERB
eurjchem-2037	135	31	four	four	NUM
eurjchem-2037	135	32	coordinated	coordinate	VERB
eurjchem-2037	135	33	distorted	distort	VERB
eurjchem-2037	135	34	tetrahedral	tetrahedral	ADJ
eurjchem-2037	135	35	geometry	geometry	NOUN
eurjchem-2037	135	36	.	.	PUNCT
eurjchem-2037	136	1	the	the	DET
eurjchem-2037	136	2	three	three	NUM
eurjchem-2037	136	3	phosphorus	phosphorus	NOUN
eurjchem-2037	136	4	-	-	PUNCT
eurjchem-2037	136	5	bound	bind	VERB
eurjchem-2037	136	6	benzene	benzene	NOUN
eurjchem-2037	136	7	rings	ring	NOUN
eurjchem-2037	136	8	make	make	VERB
eurjchem-2037	136	9	dihedral	dihedral	ADJ
eurjchem-2037	136	10	angles	angle	NOUN
eurjchem-2037	136	11	of	of	ADP
eurjchem-2037	136	12	59.5(2	59.5(2	NUM
eurjchem-2037	136	13	)	)	PUNCT
eurjchem-2037	136	14	,	,	PUNCT
eurjchem-2037	136	15	70.3(2	70.3(2	NUM
eurjchem-2037	136	16	)	)	PUNCT
eurjchem-2037	136	17	,	,	PUNCT
eurjchem-2037	136	18	and	and	CCONJ
eurjchem-2037	136	19	85.5(2	85.5(2	NUM
eurjchem-2037	136	20	)	)	PUNCT
eurjchem-2037	136	21	°	°	PROPN
eurjchem-2037	136	22	with	with	ADP
eurjchem-2037	136	23	each	each	DET
eurjchem-2037	136	24	other	other	ADJ
eurjchem-2037	136	25	.	.	PUNCT
eurjchem-2037	137	1	the	the	DET
eurjchem-2037	137	2	cu	cu	PROPN
eurjchem-2037	137	3	atom	atom	NOUN
eurjchem-2037	137	4	displays	display	VERB
eurjchem-2037	137	5	tetra	tetra	NOUN
eurjchem-2037	137	6	-	-	PUNCT
eurjchem-2037	137	7	coordination	coordination	NOUN
eurjchem-2037	137	8	,	,	PUNCT
eurjchem-2037	137	9	excluding	exclude	VERB
eurjchem-2037	137	10	the	the	DET
eurjchem-2037	137	11	central	central	ADJ
eurjchem-2037	137	12	cu···cu	cu···cu	NOUN
eurjchem-2037	137	13	contact	contact	NOUN
eurjchem-2037	137	14	of	of	ADP
eurjchem-2037	137	15	2.989	2.989	NUM
eurjchem-2037	137	16	å	å	NOUN
eurjchem-2037	137	17	,	,	PUNCT
eurjchem-2037	137	18	and	and	CCONJ
eurjchem-2037	137	19	is	be	AUX
eurjchem-2037	137	20	coordinated	coordinate	VERB
eurjchem-2037	137	21	by	by	ADP
eurjchem-2037	137	22	one	one	NUM
eurjchem-2037	137	23	phosphorus	phosphorus	NOUN
eurjchem-2037	137	24	atom	atom	NOUN
eurjchem-2037	137	25	(	(	PUNCT
eurjchem-2037	137	26	cu	cu	NOUN
eurjchem-2037	137	27	-	-	PROPN
eurjchem-2037	137	28	p	p	X
eurjchem-2037	137	29	=	=	ADJ
eurjchem-2037	137	30	2.207(5	2.207(5	NUM
eurjchem-2037	137	31	)	)	PUNCT
eurjchem-2037	137	32	å	å	NOUN
eurjchem-2037	137	33	)	)	PUNCT
eurjchem-2037	137	34	,	,	PUNCT
eurjchem-2037	137	35	one	one	NUM
eurjchem-2037	137	36	nitrogen	nitrogen	NOUN
eurjchem-2037	137	37	atom	atom	NOUN
eurjchem-2037	137	38	(	(	PUNCT
eurjchem-2037	137	39	cu	cu	PROPN
eurjchem-2037	137	40	-	-	PUNCT
eurjchem-2037	137	41	n	n	NOUN
eurjchem-2037	137	42	=	=	SYM
eurjchem-2037	137	43	2.041(12	2.041(12	NUM
eurjchem-2037	137	44	)	)	PUNCT
eurjchem-2037	137	45	å	å	NOUN
eurjchem-2037	137	46	)	)	PUNCT
eurjchem-2037	137	47	and	and	CCONJ
eurjchem-2037	137	48	two	two	NUM
eurjchem-2037	137	49	bromine	bromine	NOUN
eurjchem-2037	137	50	atoms	atom	NOUN
eurjchem-2037	137	51	(	(	PUNCT
eurjchem-2037	137	52	cu	cu	NOUN
eurjchem-2037	137	53	-	-	PUNCT
eurjchem-2037	137	54	br	br	PROPN
eurjchem-2037	137	55	=	=	SYM
eurjchem-2037	137	56	2.495(3	2.495(3	NUM
eurjchem-2037	137	57	)	)	PUNCT
eurjchem-2037	137	58	and	and	CCONJ
eurjchem-2037	137	59	2.514(3	2.514(3	NUM
eurjchem-2037	137	60	)	)	PUNCT
eurjchem-2037	137	61	å	å	NOUN
eurjchem-2037	137	62	)	)	PUNCT
eurjchem-2037	137	63	in	in	ADP
eurjchem-2037	137	64	a	a	DET
eurjchem-2037	137	65	distorted	distorted	ADJ
eurjchem-2037	137	66	tetrahedral	tetrahedral	ADJ
eurjchem-2037	137	67	geometry	geometry	NOUN
eurjchem-2037	137	68	.	.	PUNCT
eurjchem-2037	138	1	the	the	DET
eurjchem-2037	138	2	angles	angle	NOUN
eurjchem-2037	138	3	around	around	ADP
eurjchem-2037	138	4	cu	cu	PROPN
eurjchem-2037	138	5	atom	atom	NOUN
eurjchem-2037	138	6	are	be	AUX
eurjchem-2037	138	7	104.1(4	104.1(4	NUM
eurjchem-2037	138	8	)	)	PUNCT
eurjchem-2037	138	9	°	°	NOUN
eurjchem-2037	138	10	(	(	PUNCT
eurjchem-2037	138	11	br1	br1	PROPN
eurjchem-2037	138	12	-	-	PUNCT
eurjchem-2037	138	13	cu2	cu2	NOUN
eurjchem-2037	138	14	-	-	PUNCT
eurjchem-2037	138	15	n1	n1	NOUN
eurjchem-2037	138	16	)	)	PUNCT
eurjchem-2037	138	17	,	,	PUNCT
eurjchem-2037	138	18	102.5(3	102.5(3	PROPN
eurjchem-2037	138	19	)	)	PUNCT
eurjchem-2037	138	20	°	°	NOUN
eurjchem-2037	138	21	(	(	PUNCT
eurjchem-2037	138	22	br1i	br1i	NOUN
eurjchem-2037	138	23	-	-	ADJ
eurjchem-2037	138	24	cu2	cu2	NOUN
eurjchem-2037	138	25	-	-	PUNCT
eurjchem-2037	138	26	n1	n1	NOUN
eurjchem-2037	138	27	)	)	PUNCT
eurjchem-2037	138	28	,	,	PUNCT
eurjchem-2037	138	29	109.53(15	109.53(15	NUM
eurjchem-2037	138	30	)	)	PUNCT
eurjchem-2037	138	31	°	°	NOUN
eurjchem-2037	138	32	(	(	PUNCT
eurjchem-2037	138	33	p1	p1	NOUN
eurjchem-2037	138	34	-	-	PUNCT
eurjchem-2037	138	35	cu2	cu2	NOUN
eurjchem-2037	138	36	-	-	PUNCT
eurjchem-2037	138	37	br1	br1	NOUN
eurjchem-2037	138	38	)	)	PUNCT
eurjchem-2037	138	39	,	,	PUNCT
eurjchem-2037	138	40	110.78(14	110.78(14	NOUN
eurjchem-2037	138	41	)	)	PUNCT
eurjchem-2037	138	42	(	(	PUNCT
eurjchem-2037	138	43	p1	p1	NOUN
eurjchem-2037	138	44	-	-	PUNCT
eurjchem-2037	138	45	cu2	cu2	NOUN
eurjchem-2037	138	46	-	-	PUNCT
eurjchem-2037	138	47	br1i	br1i	NOUN
eurjchem-2037	138	48	)	)	PUNCT
eurjchem-2037	138	49	,	,	PUNCT
eurjchem-2037	138	50	122.0(4	122.0(4	NUM
eurjchem-2037	138	51	)	)	PUNCT
eurjchem-2037	138	52	°	°	NOUN
eurjchem-2037	138	53	(	(	PUNCT
eurjchem-2037	138	54	p1	p1	NOUN
eurjchem-2037	138	55	-	-	PUNCT
eurjchem-2037	138	56	cu2n1	cu2n1	PROPN
eurjchem-2037	138	57	)	)	PUNCT
eurjchem-2037	138	58	and	and	CCONJ
eurjchem-2037	138	59	(	(	PUNCT
eurjchem-2037	138	60	symmetry	symmetry	NOUN
eurjchem-2037	138	61	code	code	NOUN
eurjchem-2037	138	62	:	:	PUNCT
eurjchem-2037	138	63	i	i	PRON
eurjchem-2037	138	64	1	1	NUM
eurjchem-2037	138	65	-	-	SYM
eurjchem-2037	138	66	x	x	NOUN
eurjchem-2037	138	67	,	,	PUNCT
eurjchem-2037	138	68	1	1	NUM
eurjchem-2037	138	69	-	-	SYM
eurjchem-2037	138	70	y	y	PROPN
eurjchem-2037	138	71	,	,	PUNCT
eurjchem-2037	138	72	-z	-z	X
eurjchem-2037	138	73	)	)	PUNCT
eurjchem-2037	138	74	.	.	PUNCT
eurjchem-2037	139	1	in	in	ADP
eurjchem-2037	139	2	the	the	DET
eurjchem-2037	139	3	crystal	crystal	NOUN
eurjchem-2037	139	4	packing	packing	NOUN
eurjchem-2037	139	5	,	,	PUNCT
eurjchem-2037	139	6	there	there	PRON
eurjchem-2037	139	7	is	be	VERB
eurjchem-2037	139	8	no	no	DET
eurjchem-2037	139	9	intramolecular	intramolecular	ADJ
eurjchem-2037	139	10	hydrogen	hydrogen	NOUN
eurjchem-2037	139	11	bonding	bonding	NOUN
eurjchem-2037	139	12	.	.	PUNCT
eurjchem-2037	140	1	there	there	PRON
eurjchem-2037	140	2	exists	exist	VERB
eurjchem-2037	140	3	π	π	PROPN
eurjchem-2037	140	4	-	-	PUNCT
eurjchem-2037	140	5	π	π	ADJ
eurjchem-2037	140	6	stacking	stacking	NOUN
eurjchem-2037	140	7	(	(	PUNCT
eurjchem-2037	140	8	distance	distance	NOUN
eurjchem-2037	140	9	3.457	3.457	NUM
eurjchem-2037	140	10	å	å	NOUN
eurjchem-2037	140	11	)	)	PUNCT
eurjchem-2037	140	12	.	.	PUNCT
eurjchem-2037	141	1	polymeric	polymeric	ADJ
eurjchem-2037	141	2	view	view	NOUN
eurjchem-2037	141	3	of	of	ADP
eurjchem-2037	141	4	[	[	X
eurjchem-2037	141	5	cu2(µ-l)(µbr)2(pph3)2]n	cu2(µ-l)(µbr)2(pph3)2]n	X
eurjchem-2037	141	6	(	(	PUNCT
eurjchem-2037	141	7	2	2	X
eurjchem-2037	141	8	)	)	PUNCT
eurjchem-2037	141	9	has	have	AUX
eurjchem-2037	141	10	been	be	AUX
eurjchem-2037	141	11	shown	show	VERB
eurjchem-2037	141	12	in	in	ADP
eurjchem-2037	141	13	figure	figure	NOUN
eurjchem-2037	141	14	2	2	NUM
eurjchem-2037	141	15	.	.	PUNCT
eurjchem-2037	141	16	mondal	mondal	PROPN
eurjchem-2037	141	17	et	et	PROPN
eurjchem-2037	141	18	al	al	PROPN
eurjchem-2037	141	19	.	.	PUNCT
eurjchem-2037	141	20	/	/	SYM
eurjchem-2037	141	21	european	european	PROPN
eurjchem-2037	141	22	journal	journal	PROPN
eurjchem-2037	141	23	of	of	ADP
eurjchem-2037	141	24	chemistry	chemistry	NOUN
eurjchem-2037	141	25	11	11	NUM
eurjchem-2037	141	26	(	(	PUNCT
eurjchem-2037	141	27	4	4	NUM
eurjchem-2037	141	28	)	)	PUNCT
eurjchem-2037	141	29	(	(	PUNCT
eurjchem-2037	141	30	2020	2020	NUM
eurjchem-2037	141	31	)	)	PUNCT
eurjchem-2037	141	32	334	334	NUM
eurjchem-2037	141	33	-	-	SYM
eurjchem-2037	141	34	341	341	NUM
eurjchem-2037	141	35	337	337	NUM
eurjchem-2037	141	36	2020	2020	NUM
eurjchem-2037	141	37	–	–	PUNCT
eurjchem-2037	141	38	european	european	ADJ
eurjchem-2037	141	39	journal	journal	NOUN
eurjchem-2037	141	40	of	of	ADP
eurjchem-2037	141	41	chemistry	chemistry	NOUN
eurjchem-2037	141	42	–	–	PUNCT
eurjchem-2037	141	43	cc	cc	NOUN
eurjchem-2037	141	44	by	by	ADP
eurjchem-2037	141	45	nc	nc	PROPN
eurjchem-2037	141	46	–	–	PUNCT
eurjchem-2037	141	47	doi	doi	NOUN
eurjchem-2037	141	48	:	:	PUNCT
eurjchem-2037	141	49	10.5155	10.5155	NUM
eurjchem-2037	141	50	/	/	SYM
eurjchem-2037	141	51	eurjchem.11.4.334	eurjchem.11.4.334	NUM
eurjchem-2037	141	52	-	-	PUNCT
eurjchem-2037	141	53	341.2037	341.2037	NUM
eurjchem-2037	141	54	table	table	NOUN
eurjchem-2037	141	55	1	1	NUM
eurjchem-2037	141	56	.	.	PUNCT
eurjchem-2037	141	57	crystallographic	crystallographic	ADJ
eurjchem-2037	141	58	data	datum	NOUN
eurjchem-2037	141	59	and	and	CCONJ
eurjchem-2037	141	60	refinement	refinement	NOUN
eurjchem-2037	141	61	parameters	parameter	NOUN
eurjchem-2037	141	62	for	for	ADP
eurjchem-2037	141	63	complex	complex	ADJ
eurjchem-2037	141	64	2	2	NUM
eurjchem-2037	141	65	.	.	X
eurjchem-2037	141	66	compound	compound	NOUN
eurjchem-2037	142	1	[	[	X
eurjchem-2037	142	2	cu2(µ-l)(µ-br)2(pph3)2]n	cu2(µ-l)(µ-br)2(pph3)2]n	NOUN
eurjchem-2037	142	3	empirical	empirical	ADJ
eurjchem-2037	142	4	formula	formula	NOUN
eurjchem-2037	142	5	c25h22brcun2p	c25h22brcun2p	NOUN
eurjchem-2037	142	6	formula	formula	NOUN
eurjchem-2037	142	7	weight	weight	NOUN
eurjchem-2037	142	8	524.86	524.86	NUM
eurjchem-2037	142	9	temperature	temperature	NOUN
eurjchem-2037	142	10	(	(	PUNCT
eurjchem-2037	142	11	k	k	NOUN
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eurjchem-2037	142	13	296.15	296.15	NUM
eurjchem-2037	142	14	crystal	crystal	NOUN
eurjchem-2037	142	15	system	system	NOUN
eurjchem-2037	142	16	triclinic	triclinic	ADJ
eurjchem-2037	142	17	space	space	NOUN
eurjchem-2037	142	18	group	group	NOUN
eurjchem-2037	142	19	p-1	p-1	NOUN
eurjchem-2037	142	20	a	a	DET
eurjchem-2037	142	21	(	(	PUNCT
eurjchem-2037	142	22	å	å	NOUN
eurjchem-2037	142	23	)	)	PUNCT
eurjchem-2037	142	24	9.471(10	9.471(10	NUM
eurjchem-2037	142	25	)	)	PUNCT
eurjchem-2037	142	26	b	b	NOUN
eurjchem-2037	142	27	(	(	PUNCT
eurjchem-2037	142	28	å	å	NOUN
eurjchem-2037	142	29	)	)	PUNCT
eurjchem-2037	142	30	11.043(11	11.043(11	NUM
eurjchem-2037	142	31	)	)	PUNCT
eurjchem-2037	142	32	c	c	NOUN
eurjchem-2037	142	33	(	(	PUNCT
eurjchem-2037	142	34	å	å	NOUN
eurjchem-2037	142	35	)	)	PUNCT
eurjchem-2037	142	36	13.215(18	13.215(18	NUM
eurjchem-2037	142	37	)	)	PUNCT
eurjchem-2037	143	1	α	α	PROPN
eurjchem-2037	143	2	(	(	PUNCT
eurjchem-2037	143	3	°	°	PROPN
eurjchem-2037	143	4	)	)	PUNCT
eurjchem-2037	143	5	65.853(18	65.853(18	NOUN
eurjchem-2037	143	6	)	)	PUNCT
eurjchem-2037	143	7	β	β	X
eurjchem-2037	143	8	(	(	PUNCT
eurjchem-2037	143	9	°	°	PROPN
eurjchem-2037	143	10	)	)	PUNCT
eurjchem-2037	143	11	69.94(2	69.94(2	NOUN
eurjchem-2037	143	12	)	)	PUNCT
eurjchem-2037	143	13	γ	γ	PROPN
eurjchem-2037	143	14	(	(	PUNCT
eurjchem-2037	143	15	°	°	ADJ
eurjchem-2037	143	16	)	)	PUNCT
eurjchem-2037	143	17	67.350(14	67.350(14	NOUN
eurjchem-2037	143	18	)	)	PUNCT
eurjchem-2037	143	19	volume	volume	NOUN
eurjchem-2037	143	20	(	(	PUNCT
eurjchem-2037	143	21	å3	å3	PROPN
eurjchem-2037	143	22	)	)	PUNCT
eurjchem-2037	143	23	1135(2	1135(2	NUM
eurjchem-2037	143	24	)	)	PUNCT
eurjchem-2037	143	25	z	z	NOUN
eurjchem-2037	143	26	2	2	NUM
eurjchem-2037	143	27	ρcalc	ρcalc	NOUN
eurjchem-2037	143	28	(	(	PUNCT
eurjchem-2037	143	29	g	g	NOUN
eurjchem-2037	143	30	/	/	SYM
eurjchem-2037	143	31	cm3	cm3	NOUN
eurjchem-2037	143	32	)	)	PUNCT
eurjchem-2037	143	33	1.535	1.535	NUM
eurjchem-2037	143	34	μ	μ	NOUN
eurjchem-2037	143	35	(	(	PUNCT
eurjchem-2037	143	36	mm-1	mm-1	NOUN
eurjchem-2037	143	37	)	)	PUNCT
eurjchem-2037	143	38	2.806	2.806	NUM
eurjchem-2037	143	39	f(000	f(000	NOUN
eurjchem-2037	143	40	)	)	PUNCT
eurjchem-2037	143	41	530.0	530.0	NUM
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eurjchem-2037	143	43	size	size	NOUN
eurjchem-2037	143	44	(	(	PUNCT
eurjchem-2037	143	45	mm3	mm3	PROPN
eurjchem-2037	143	46	)	)	PUNCT
eurjchem-2037	143	47	0.24	0.24	NUM
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eurjchem-2037	143	49	0.22	0.22	NUM
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eurjchem-2037	143	54	(	(	PUNCT
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eurjchem-2037	143	56	=	=	SYM
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eurjchem-2037	143	58	)	)	PUNCT
eurjchem-2037	143	59	2θ	2θ	NUM
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eurjchem-2037	143	61	for	for	ADP
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eurjchem-2037	143	64	(	(	PUNCT
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eurjchem-2037	143	66	)	)	PUNCT
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eurjchem-2037	143	74	h	h	NOUN
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eurjchem-2037	143	76	9	9	NUM
eurjchem-2037	143	77	,	,	PUNCT
eurjchem-2037	143	78	-10	-10	PUNCT
eurjchem-2037	143	79	≤	≤	NUM
eurjchem-2037	144	1	k	k	X
eurjchem-2037	144	2	≤	≤	NUM
eurjchem-2037	144	3	11	11	NUM
eurjchem-2037	144	4	,	,	PUNCT
eurjchem-2037	144	5	-14	-14	PUNCT
eurjchem-2037	144	6	≤	≤	NUM
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eurjchem-2037	144	8	≤	≤	NUM
eurjchem-2037	144	9	14	14	NUM
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eurjchem-2037	144	12	4059	4059	NUM
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eurjchem-2037	145	1	[	[	X
eurjchem-2037	145	2	rint	rint	X
eurjchem-2037	145	3	=	=	SYM
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eurjchem-2037	145	5	,	,	PUNCT
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eurjchem-2037	145	7	=	=	SYM
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eurjchem-2037	145	9	]	]	X
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eurjchem-2037	145	19	-	-	PUNCT
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eurjchem-2037	145	27	[	[	X
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eurjchem-2037	145	29	(	(	PUNCT
eurjchem-2037	145	30	i	i	NOUN
eurjchem-2037	145	31	)	)	PUNCT
eurjchem-2037	145	32	]	]	PUNCT
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eurjchem-2037	146	29	(	(	PUNCT
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eurjchem-2037	148	6	(	(	PUNCT
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eurjchem-2037	148	8	)	)	PUNCT
eurjchem-2037	148	9	.	.	PUNCT
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eurjchem-2037	149	3	are	be	AUX
eurjchem-2037	149	4	drawn	draw	VERB
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eurjchem-2037	150	7	[	[	X
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eurjchem-2037	150	9	(	(	PUNCT
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eurjchem-2037	151	7	.	.	PUNCT
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eurjchem-2037	152	6	/	/	SYM
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eurjchem-2037	152	17	)	)	PUNCT
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eurjchem-2037	152	22	–	–	PUNCT
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eurjchem-2037	152	26	chemistry	chemistry	NOUN
eurjchem-2037	152	27	–	–	PUNCT
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eurjchem-2037	153	3	(	(	PUNCT
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eurjchem-2037	153	5	)	)	PUNCT
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eurjchem-2037	153	9	.	.	PUNCT
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eurjchem-2037	153	13	(	(	PUNCT
eurjchem-2037	153	14	å	å	NOUN
eurjchem-2037	153	15	)	)	PUNCT
eurjchem-2037	153	16	atom	atom	NOUN
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eurjchem-2037	153	18	length	length	NOUN
eurjchem-2037	153	19	(	(	PUNCT
eurjchem-2037	153	20	å	å	NOUN
eurjchem-2037	153	21	)	)	PUNCT
eurjchem-2037	153	22	br1	br1	PROPN
eurjchem-2037	153	23	cu2	cu2	PROPN
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eurjchem-2037	153	25	)	)	PUNCT
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eurjchem-2037	153	29	)	)	PUNCT
eurjchem-2037	153	30	br1	br1	PROPN
eurjchem-2037	154	1	cu21	cu21	PROPN
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eurjchem-2037	154	3	)	)	PUNCT
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eurjchem-2037	154	5	c10	c10	VERB
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eurjchem-2037	154	7	)	)	PUNCT
eurjchem-2037	154	8	cu2	cu2	NOUN
eurjchem-2037	155	1	br11	br11	PROPN
eurjchem-2037	155	2	2.514(3	2.514(3	NUM
eurjchem-2037	155	3	)	)	PUNCT
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eurjchem-2037	155	7	)	)	PUNCT
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eurjchem-2037	156	15	)	)	PUNCT
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eurjchem-2037	156	23	)	)	PUNCT
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eurjchem-2037	156	25	c6	c6	PROPN
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eurjchem-2037	156	27	)	)	PUNCT
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eurjchem-2037	156	35	)	)	PUNCT
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eurjchem-2037	156	41	c18	c18	NOUN
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eurjchem-2037	156	43	)	)	PUNCT
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eurjchem-2037	156	45	c16	c16	PROPN
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eurjchem-2037	156	47	)	)	PUNCT
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eurjchem-2037	156	51	)	)	PUNCT
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eurjchem-2037	156	55	)	)	PUNCT
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eurjchem-2037	156	63	)	)	PUNCT
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eurjchem-2037	161	3	c6	c6	PROPN
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eurjchem-2037	161	43	p1	p1	PROPN
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eurjchem-2037	161	53	p1	p1	PROPN
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eurjchem-2037	161	97	p1	p1	PROPN
eurjchem-2037	161	98	c6	c6	PROPN
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eurjchem-2037	161	112	c16	c16	PROPN
eurjchem-2037	161	113	c17	c17	PROPN
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eurjchem-2037	161	117	p1	p1	PROPN
eurjchem-2037	161	118	cu2	cu2	NOUN
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eurjchem-2037	161	122	c20	c20	PROPN
eurjchem-2037	161	123	c19	c19	PROPN
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eurjchem-2037	163	3	c1	c1	PROPN
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eurjchem-2037	163	13	cu2	cu2	PROPN
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eurjchem-2037	163	17	c18	c18	PROPN
eurjchem-2037	163	18	p1	p1	PROPN
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eurjchem-2037	163	21	n1	n1	PROPN
eurjchem-2037	163	22	c5	c5	PROPN
eurjchem-2037	163	23	c4	c4	PROPN
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eurjchem-2037	164	3	c1	c1	PROPN
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eurjchem-2037	164	28	c23	c23	PROPN
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eurjchem-2037	164	75	,	,	PUNCT
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eurjchem-2037	164	77	,	,	PUNCT
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eurjchem-2037	164	79	.	.	PROPN
eurjchem-2037	164	80	figure	figure	NOUN
eurjchem-2037	164	81	3	3	NUM
eurjchem-2037	164	82	.	.	PUNCT
eurjchem-2037	165	1	π	π	PROPN
eurjchem-2037	165	2	-	-	PUNCT
eurjchem-2037	165	3	π	π	ADJ
eurjchem-2037	165	4	stacking	stacking	NOUN
eurjchem-2037	165	5	in	in	ADP
eurjchem-2037	165	6	complex	complex	ADJ
eurjchem-2037	165	7	2	2	NUM
eurjchem-2037	165	8	.	.	PUNCT
eurjchem-2037	166	1	the	the	DET
eurjchem-2037	166	2	1	1	NUM
eurjchem-2037	166	3	-	-	PUNCT
eurjchem-2037	166	4	d	d	NOUN
eurjchem-2037	166	5	coordination	coordination	NOUN
eurjchem-2037	166	6	chains	chain	NOUN
eurjchem-2037	166	7	are	be	AUX
eurjchem-2037	166	8	connected	connect	VERB
eurjchem-2037	166	9	by	by	ADP
eurjchem-2037	166	10	supra	supra	PROPN
eurjchem-2037	166	11	molecular	molecular	ADJ
eurjchem-2037	166	12	π···π	π···π	NOUN
eurjchem-2037	166	13	interactions	interaction	NOUN
eurjchem-2037	166	14	to	to	PART
eurjchem-2037	166	15	form	form	VERB
eurjchem-2037	166	16	a	a	DET
eurjchem-2037	166	17	3d	3d	ADJ
eurjchem-2037	166	18	supramolecular	supramolecular	ADJ
eurjchem-2037	166	19	structure	structure	NOUN
eurjchem-2037	166	20	(	(	PUNCT
eurjchem-2037	166	21	figure	figure	NOUN
eurjchem-2037	166	22	3	3	NUM
eurjchem-2037	166	23	)	)	PUNCT
eurjchem-2037	166	24	.	.	PUNCT
eurjchem-2037	167	1	3.3	3.3	NUM
eurjchem-2037	167	2	.	.	PUNCT
eurjchem-2037	168	1	theoretical	theoretical	ADJ
eurjchem-2037	168	2	investigations	investigation	NOUN
eurjchem-2037	168	3	b3lyp	b3lyp	SYM
eurjchem-2037	168	4	correlation	correlation	NOUN
eurjchem-2037	168	5	function	function	NOUN
eurjchem-2037	168	6	by	by	ADP
eurjchem-2037	168	7	the	the	DET
eurjchem-2037	168	8	gaussian	gaussian	ADJ
eurjchem-2037	168	9	09	09	NUM
eurjchem-2037	168	10	package	package	NOUN
eurjchem-2037	168	11	using	use	VERB
eurjchem-2037	168	12	a	a	DET
eurjchem-2037	168	13	dft	dft	NOUN
eurjchem-2037	168	14	method	method	NOUN
eurjchem-2037	168	15	has	have	AUX
eurjchem-2037	168	16	been	be	AUX
eurjchem-2037	168	17	performed	perform	VERB
eurjchem-2037	168	18	to	to	PART
eurjchem-2037	168	19	further	far	ADV
eurjchem-2037	168	20	understand	understand	VERB
eurjchem-2037	168	21	the	the	DET
eurjchem-2037	168	22	electronic	electronic	ADJ
eurjchem-2037	168	23	structure	structure	NOUN
eurjchem-2037	168	24	of	of	ADP
eurjchem-2037	168	25	the	the	DET
eurjchem-2037	168	26	ligand	ligand	NOUN
eurjchem-2037	168	27	l.	l.	PROPN
eurjchem-2037	168	28	the	the	DET
eurjchem-2037	168	29	optimized	optimize	VERB
eurjchem-2037	168	30	structure	structure	NOUN
eurjchem-2037	168	31	of	of	ADP
eurjchem-2037	168	32	ligand	ligand	PROPN
eurjchem-2037	168	33	l	l	PROPN
eurjchem-2037	168	34	has	have	AUX
eurjchem-2037	168	35	been	be	AUX
eurjchem-2037	168	36	displayed	display	VERB
eurjchem-2037	168	37	in	in	ADP
eurjchem-2037	168	38	figure	figure	NOUN
eurjchem-2037	168	39	4(a	4(a	NUM
eurjchem-2037	168	40	)	)	PUNCT
eurjchem-2037	168	41	.	.	PUNCT
eurjchem-2037	169	1	the	the	DET
eurjchem-2037	169	2	energies	energy	NOUN
eurjchem-2037	169	3	of	of	ADP
eurjchem-2037	169	4	some	some	DET
eurjchem-2037	169	5	selected	select	VERB
eurjchem-2037	169	6	molecular	molecular	ADJ
eurjchem-2037	169	7	orbits	orbit	NOUN
eurjchem-2037	169	8	for	for	ADP
eurjchem-2037	169	9	l	l	NOUN
eurjchem-2037	169	10	are	be	AUX
eurjchem-2037	169	11	shown	show	VERB
eurjchem-2037	169	12	in	in	ADP
eurjchem-2037	169	13	figure	figure	NOUN
eurjchem-2037	169	14	4(b	4(b	NUM
eurjchem-2037	169	15	)	)	PUNCT
eurjchem-2037	169	16	.	.	PUNCT
eurjchem-2037	170	1	the	the	DET
eurjchem-2037	170	2	energy	energy	NOUN
eurjchem-2037	170	3	gaps	gap	NOUN
eurjchem-2037	170	4	between	between	ADP
eurjchem-2037	170	5	homo	homo	NOUN
eurjchem-2037	170	6	-	-	PUNCT
eurjchem-2037	170	7	lumo	lumo	NOUN
eurjchem-2037	170	8	,	,	PUNCT
eurjchem-2037	170	9	(	(	PUNCT
eurjchem-2037	170	10	homo-1)-(lumo+1	homo-1)-(lumo+1	PROPN
eurjchem-2037	170	11	)	)	PUNCT
eurjchem-2037	170	12	,	,	PUNCT
eurjchem-2037	170	13	(	(	PUNCT
eurjchem-2037	170	14	homo-2)-(lumo+2	homo-2)-(lumo+2	X
eurjchem-2037	170	15	)	)	PUNCT
eurjchem-2037	170	16	are	be	AUX
eurjchem-2037	170	17	8.2027	8.2027	NUM
eurjchem-2037	170	18	,	,	PUNCT
eurjchem-2037	170	19	8.3160	8.3160	NUM
eurjchem-2037	170	20	and	and	CCONJ
eurjchem-2037	170	21	9.1338	9.1338	NUM
eurjchem-2037	170	22	ev	ev	NOUN
eurjchem-2037	170	23	for	for	ADP
eurjchem-2037	170	24	the	the	DET
eurjchem-2037	170	25	ligand	ligand	ADJ
eurjchem-2037	170	26	molecule	molecule	NOUN
eurjchem-2037	170	27	.	.	PUNCT
eurjchem-2037	171	1	the	the	DET
eurjchem-2037	171	2	homo	homo	NOUN
eurjchem-2037	171	3	-	-	PUNCT
eurjchem-2037	171	4	lumo	lumo	NOUN
eurjchem-2037	171	5	energy	energy	NOUN
eurjchem-2037	171	6	gap	gap	NOUN
eurjchem-2037	171	7	between	between	ADP
eurjchem-2037	171	8	the	the	DET
eurjchem-2037	171	9	highest	high	ADJ
eurjchem-2037	171	10	occupied	occupy	VERB
eurjchem-2037	171	11	molecular	molecular	ADJ
eurjchem-2037	171	12	orbital	orbital	NOUN
eurjchem-2037	171	13	and	and	CCONJ
eurjchem-2037	171	14	the	the	DET
eurjchem-2037	171	15	lowest	low	ADJ
eurjchem-2037	171	16	unoccupied	unoccupied	ADJ
eurjchem-2037	171	17	molecular	molecular	ADJ
eurjchem-2037	171	18	orbital	orbital	NOUN
eurjchem-2037	171	19	for	for	ADP
eurjchem-2037	171	20	ligand	ligand	NOUN
eurjchem-2037	171	21	l	l	NOUN
eurjchem-2037	171	22	is	be	AUX
eurjchem-2037	171	23	5.30	5.30	NUM
eurjchem-2037	171	24	ev	ev	NOUN
eurjchem-2037	171	25	.	.	PUNCT
eurjchem-2037	172	1	mondal	mondal	PROPN
eurjchem-2037	172	2	et	et	PROPN
eurjchem-2037	172	3	al	al	PROPN
eurjchem-2037	172	4	.	.	PUNCT
eurjchem-2037	172	5	/	/	SYM
eurjchem-2037	172	6	european	european	PROPN
eurjchem-2037	172	7	journal	journal	PROPN
eurjchem-2037	172	8	of	of	ADP
eurjchem-2037	172	9	chemistry	chemistry	NOUN
eurjchem-2037	172	10	11	11	NUM
eurjchem-2037	172	11	(	(	PUNCT
eurjchem-2037	172	12	4	4	NUM
eurjchem-2037	172	13	)	)	PUNCT
eurjchem-2037	172	14	(	(	PUNCT
eurjchem-2037	172	15	2020	2020	NUM
eurjchem-2037	172	16	)	)	PUNCT
eurjchem-2037	172	17	334	334	NUM
eurjchem-2037	172	18	-	-	SYM
eurjchem-2037	172	19	341	341	NUM
eurjchem-2037	172	20	339	339	NUM
eurjchem-2037	172	21	2020	2020	NUM
eurjchem-2037	172	22	–	–	PUNCT
eurjchem-2037	172	23	european	european	ADJ
eurjchem-2037	172	24	journal	journal	NOUN
eurjchem-2037	172	25	of	of	ADP
eurjchem-2037	172	26	chemistry	chemistry	NOUN
eurjchem-2037	172	27	–	–	PUNCT
eurjchem-2037	172	28	cc	cc	NOUN
eurjchem-2037	172	29	by	by	ADP
eurjchem-2037	172	30	nc	nc	PROPN
eurjchem-2037	172	31	–	–	PUNCT
eurjchem-2037	172	32	doi	doi	NOUN
eurjchem-2037	172	33	:	:	PUNCT
eurjchem-2037	172	34	10.5155	10.5155	NUM
eurjchem-2037	172	35	/	/	SYM
eurjchem-2037	172	36	eurjchem.11.4.334	eurjchem.11.4.334	NOUN
eurjchem-2037	172	37	-	-	SYM
eurjchem-2037	172	38	341.2037	341.2037	NUM
eurjchem-2037	172	39	(	(	PUNCT
eurjchem-2037	172	40	a	a	NOUN
eurjchem-2037	172	41	)	)	PUNCT
eurjchem-2037	172	42	(	(	PUNCT
eurjchem-2037	172	43	b	b	X
eurjchem-2037	172	44	)	)	PUNCT
eurjchem-2037	172	45	lumo	lumo	NOUN
eurjchem-2037	172	46	(	(	PUNCT
eurjchem-2037	172	47	e	e	NOUN
eurjchem-2037	172	48	=	=	SYM
eurjchem-2037	172	49	-1.599	-1.599	PUNCT
eurjchem-2037	172	50	ev	ev	ADJ
eurjchem-2037	172	51	)	)	PUNCT
eurjchem-2037	172	52	homo	homo	NOUN
eurjchem-2037	172	53	(	(	PUNCT
eurjchem-2037	172	54	e	e	NOUN
eurjchem-2037	172	55	=	=	PRON
eurjchem-2037	172	56	-6.800	-6.800	PROPN
eurjchem-2037	172	57	ev	ev	INTJ
eurjchem-2037	172	58	)	)	PUNCT
eurjchem-2037	172	59	figure	figure	NOUN
eurjchem-2037	172	60	4	4	NUM
eurjchem-2037	172	61	.	.	PUNCT
eurjchem-2037	173	1	(	(	PUNCT
eurjchem-2037	173	2	a	a	X
eurjchem-2037	173	3	)	)	PUNCT
eurjchem-2037	173	4	optimized	optimize	VERB
eurjchem-2037	173	5	molecular	molecular	ADJ
eurjchem-2037	173	6	structure	structure	NOUN
eurjchem-2037	173	7	of	of	ADP
eurjchem-2037	173	8	the	the	DET
eurjchem-2037	173	9	ligand	ligand	PROPN
eurjchem-2037	173	10	l	l	NOUN
eurjchem-2037	173	11	;	;	PUNCT
eurjchem-2037	173	12	(	(	PUNCT
eurjchem-2037	173	13	b	b	X
eurjchem-2037	173	14	)	)	PUNCT
eurjchem-2037	173	15	surface	surface	NOUN
eurjchem-2037	173	16	plots	plot	NOUN
eurjchem-2037	173	17	of	of	ADP
eurjchem-2037	173	18	homo	homo	NOUN
eurjchem-2037	173	19	and	and	CCONJ
eurjchem-2037	173	20	lumo	lumo	NOUN
eurjchem-2037	173	21	of	of	ADP
eurjchem-2037	173	22	the	the	DET
eurjchem-2037	173	23	ligand	ligand	NOUN
eurjchem-2037	173	24	l.	l.	PROPN
eurjchem-2037	173	25	(	(	PUNCT
eurjchem-2037	173	26	a	a	NOUN
eurjchem-2037	173	27	)	)	PUNCT
eurjchem-2037	173	28	(	(	PUNCT
eurjchem-2037	173	29	b	b	X
eurjchem-2037	173	30	)	)	PUNCT
eurjchem-2037	173	31	(	(	PUNCT
eurjchem-2037	173	32	c	c	X
eurjchem-2037	173	33	)	)	PUNCT
eurjchem-2037	173	34	figure	figure	NOUN
eurjchem-2037	173	35	5	5	NUM
eurjchem-2037	173	36	.	.	PUNCT
eurjchem-2037	174	1	hirshfeld	hirshfeld	PROPN
eurjchem-2037	174	2	surfaces	surface	NOUN
eurjchem-2037	174	3	of	of	ADP
eurjchem-2037	174	4	complex	complex	ADJ
eurjchem-2037	174	5	2	2	NUM
eurjchem-2037	174	6	.	.	PUNCT
eurjchem-2037	175	1	(	(	PUNCT
eurjchem-2037	175	2	a	a	X
eurjchem-2037	175	3	)	)	PUNCT
eurjchem-2037	175	4	3d	3d	NUM
eurjchem-2037	175	5	dnorm	dnorm	NOUN
eurjchem-2037	175	6	surface	surface	NOUN
eurjchem-2037	175	7	,	,	PUNCT
eurjchem-2037	175	8	(	(	PUNCT
eurjchem-2037	175	9	b	b	X
eurjchem-2037	175	10	)	)	PUNCT
eurjchem-2037	175	11	surface	surface	NOUN
eurjchem-2037	175	12	index	index	NOUN
eurjchem-2037	175	13	,	,	PUNCT
eurjchem-2037	175	14	(	(	PUNCT
eurjchem-2037	175	15	c	c	X
eurjchem-2037	175	16	)	)	PUNCT
eurjchem-2037	175	17	curvedness	curvedness	ADJ
eurjchem-2037	175	18	.	.	PUNCT
eurjchem-2037	176	1	(	(	PUNCT
eurjchem-2037	176	2	a	a	X
eurjchem-2037	176	3	)	)	PUNCT
eurjchem-2037	176	4	(	(	PUNCT
eurjchem-2037	176	5	b	b	X
eurjchem-2037	176	6	)	)	PUNCT
eurjchem-2037	176	7	(	(	PUNCT
eurjchem-2037	176	8	c	c	X
eurjchem-2037	176	9	)	)	PUNCT
eurjchem-2037	176	10	(	(	PUNCT
eurjchem-2037	176	11	d	d	X
eurjchem-2037	176	12	)	)	PUNCT
eurjchem-2037	176	13	figure	figure	NOUN
eurjchem-2037	176	14	6	6	NUM
eurjchem-2037	176	15	.	.	PUNCT
eurjchem-2037	176	16	2d	2d	NOUN
eurjchem-2037	176	17	fingerprint	fingerprint	NOUN
eurjchem-2037	176	18	plots	plot	NOUN
eurjchem-2037	176	19	of	of	ADP
eurjchem-2037	176	20	complex	complex	ADJ
eurjchem-2037	176	21	2	2	NUM
eurjchem-2037	176	22	.	.	PUNCT
eurjchem-2037	177	1	(	(	PUNCT
eurjchem-2037	177	2	a	a	X
eurjchem-2037	177	3	)	)	PUNCT
eurjchem-2037	177	4	standard	standard	NOUN
eurjchem-2037	177	5	full	full	ADJ
eurjchem-2037	177	6	and	and	CCONJ
eurjchem-2037	177	7	(	(	PUNCT
eurjchem-2037	177	8	b	b	NOUN
eurjchem-2037	177	9	)	)	PUNCT
eurjchem-2037	177	10	resolved	resolve	VERB
eurjchem-2037	177	11	into	into	ADP
eurjchem-2037	177	12	h···h	h···h	PROPN
eurjchem-2037	177	13	and	and	CCONJ
eurjchem-2037	177	14	(	(	PUNCT
eurjchem-2037	177	15	c	c	NOUN
eurjchem-2037	177	16	)	)	PUNCT
eurjchem-2037	177	17	resolved	resolve	VERB
eurjchem-2037	177	18	into	into	ADP
eurjchem-2037	177	19	n···h	n···h	PROPN
eurjchem-2037	177	20	(	(	PUNCT
eurjchem-2037	177	21	d	d	NOUN
eurjchem-2037	177	22	)	)	PUNCT
eurjchem-2037	177	23	br···h	br···h	NOUN
eurjchem-2037	177	24	contacts	contact	NOUN
eurjchem-2037	177	25	,	,	PUNCT
eurjchem-2037	177	26	showing	show	VERB
eurjchem-2037	177	27	the	the	DET
eurjchem-2037	177	28	percentages	percentage	NOUN
eurjchem-2037	177	29	of	of	ADP
eurjchem-2037	177	30	contacts	contact	NOUN
eurjchem-2037	177	31	contributing	contribute	VERB
eurjchem-2037	177	32	to	to	ADP
eurjchem-2037	177	33	the	the	DET
eurjchem-2037	177	34	total	total	ADJ
eurjchem-2037	177	35	hirshfeld	hirshfeld	PROPN
eurjchem-2037	177	36	surface	surface	PROPN
eurjchem-2037	177	37	area	area	NOUN
eurjchem-2037	177	38	of	of	ADP
eurjchem-2037	177	39	the	the	DET
eurjchem-2037	177	40	molecule	molecule	NOUN
eurjchem-2037	177	41	.	.	PUNCT
eurjchem-2037	178	1	this	this	DET
eurjchem-2037	178	2	value	value	NOUN
eurjchem-2037	178	3	is	be	AUX
eurjchem-2037	178	4	a	a	DET
eurjchem-2037	178	5	useful	useful	ADJ
eurjchem-2037	178	6	quantity	quantity	NOUN
eurjchem-2037	178	7	for	for	ADP
eurjchem-2037	178	8	examining	examine	VERB
eurjchem-2037	178	9	the	the	DET
eurjchem-2037	178	10	kinetic	kinetic	ADJ
eurjchem-2037	178	11	stability	stability	NOUN
eurjchem-2037	178	12	.	.	PUNCT
eurjchem-2037	179	1	a	a	DET
eurjchem-2037	179	2	large	large	ADJ
eurjchem-2037	179	3	energy	energy	NOUN
eurjchem-2037	179	4	gap	gap	NOUN
eurjchem-2037	179	5	corresponds	correspond	VERB
eurjchem-2037	179	6	to	to	ADP
eurjchem-2037	179	7	a	a	DET
eurjchem-2037	179	8	high	high	ADJ
eurjchem-2037	179	9	energy	energy	NOUN
eurjchem-2037	179	10	required	require	VERB
eurjchem-2037	179	11	for	for	ADP
eurjchem-2037	179	12	electron	electron	NOUN
eurjchem-2037	179	13	excitation	excitation	NOUN
eurjchem-2037	179	14	.	.	PUNCT
eurjchem-2037	180	1	3.4	3.4	NUM
eurjchem-2037	180	2	.	.	X
eurjchem-2037	180	3	molecular	molecular	ADJ
eurjchem-2037	180	4	hirshfeld	hirshfeld	NOUN
eurjchem-2037	180	5	surfaces	surface	VERB
eurjchem-2037	180	6	the	the	DET
eurjchem-2037	180	7	hirshfeld	hirshfeld	PROPN
eurjchem-2037	180	8	surface	surface	NOUN
eurjchem-2037	180	9	is	be	AUX
eurjchem-2037	180	10	a	a	DET
eurjchem-2037	180	11	suitable	suitable	ADJ
eurjchem-2037	180	12	tool	tool	NOUN
eurjchem-2037	180	13	for	for	ADP
eurjchem-2037	180	14	describing	describe	VERB
eurjchem-2037	180	15	the	the	DET
eurjchem-2037	180	16	surface	surface	NOUN
eurjchem-2037	180	17	characteristics	characteristic	NOUN
eurjchem-2037	180	18	of	of	ADP
eurjchem-2037	180	19	molecules	molecule	NOUN
eurjchem-2037	180	20	.	.	PUNCT
eurjchem-2037	181	1	the	the	DET
eurjchem-2037	181	2	molecular	molecular	ADJ
eurjchem-2037	181	3	hirshfeld	hirshfeld	NOUN
eurjchem-2037	181	4	surfaces	surface	NOUN
eurjchem-2037	181	5	of	of	ADP
eurjchem-2037	181	6	complex	complex	ADJ
eurjchem-2037	181	7	2	2	NUM
eurjchem-2037	181	8	was	be	AUX
eurjchem-2037	181	9	generated	generate	VERB
eurjchem-2037	181	10	using	use	VERB
eurjchem-2037	181	11	a	a	DET
eurjchem-2037	181	12	standard	standard	ADJ
eurjchem-2037	181	13	(	(	PUNCT
eurjchem-2037	181	14	high	high	ADJ
eurjchem-2037	181	15	)	)	PUNCT
eurjchem-2037	181	16	surface	surface	NOUN
eurjchem-2037	181	17	resolution	resolution	NOUN
eurjchem-2037	181	18	with	with	ADP
eurjchem-2037	181	19	the	the	DET
eurjchem-2037	181	20	3d	3d	NUM
eurjchem-2037	181	21	dnorm	dnorm	NOUN
eurjchem-2037	181	22	surfaces	surface	NOUN
eurjchem-2037	181	23	mapped	map	VERB
eurjchem-2037	181	24	over	over	ADP
eurjchem-2037	181	25	a	a	DET
eurjchem-2037	181	26	fixed	fix	VERB
eurjchem-2037	181	27	color	color	NOUN
eurjchem-2037	181	28	scale	scale	NOUN
eurjchem-2037	181	29	of	of	ADP
eurjchem-2037	181	30	-0.22	-0.22	NOUN
eurjchem-2037	181	31	(	(	PUNCT
eurjchem-2037	181	32	red	red	PROPN
eurjchem-2037	181	33	)	)	PUNCT
eurjchem-2037	181	34	to	to	ADP
eurjchem-2037	181	35	1.4	1.4	NUM
eurjchem-2037	181	36	å	å	NOUN
eurjchem-2037	181	37	(	(	PUNCT
eurjchem-2037	181	38	blue	blue	NOUN
eurjchem-2037	181	39	)	)	PUNCT
eurjchem-2037	181	40	.	.	PUNCT
eurjchem-2037	182	1	the	the	DET
eurjchem-2037	182	2	shape	shape	NOUN
eurjchem-2037	182	3	index	index	NOUN
eurjchem-2037	182	4	mapped	map	VERB
eurjchem-2037	182	5	in	in	ADP
eurjchem-2037	182	6	the	the	DET
eurjchem-2037	182	7	color	color	NOUN
eurjchem-2037	182	8	range	range	NOUN
eurjchem-2037	182	9	of	of	ADP
eurjchem-2037	182	10	-0.99	-0.99	NOUN
eurjchem-2037	182	11	to	to	ADP
eurjchem-2037	182	12	1.0	1.0	NUM
eurjchem-2037	182	13	,	,	PUNCT
eurjchem-2037	182	14	and	and	CCONJ
eurjchem-2037	182	15	curvedness	curvedness	ADJ
eurjchem-2037	182	16	was	be	AUX
eurjchem-2037	182	17	in	in	ADP
eurjchem-2037	182	18	the	the	DET
eurjchem-2037	182	19	range	range	NOUN
eurjchem-2037	182	20	of	of	ADP
eurjchem-2037	182	21	-4.0	-4.0	PROPN
eurjchem-2037	182	22	to	to	ADP
eurjchem-2037	182	23	0.4	0.4	NUM
eurjchem-2037	182	24	.	.	PUNCT
eurjchem-2037	183	1	the	the	DET
eurjchem-2037	183	2	surfaces	surface	NOUN
eurjchem-2037	183	3	were	be	AUX
eurjchem-2037	183	4	shown	show	VERB
eurjchem-2037	183	5	to	to	PART
eurjchem-2037	183	6	be	be	AUX
eurjchem-2037	183	7	transparent	transparent	ADJ
eurjchem-2037	183	8	to	to	PART
eurjchem-2037	183	9	allow	allow	VERB
eurjchem-2037	183	10	visualization	visualization	NOUN
eurjchem-2037	183	11	of	of	ADP
eurjchem-2037	183	12	the	the	DET
eurjchem-2037	183	13	molecular	molecular	ADJ
eurjchem-2037	183	14	moiety	moiety	NOUN
eurjchem-2037	183	15	in	in	ADP
eurjchem-2037	183	16	a	a	DET
eurjchem-2037	183	17	similar	similar	ADJ
eurjchem-2037	183	18	orientation	orientation	NOUN
eurjchem-2037	183	19	for	for	ADP
eurjchem-2037	183	20	all	all	PRON
eurjchem-2037	183	21	of	of	ADP
eurjchem-2037	183	22	the	the	DET
eurjchem-2037	183	23	structures	structure	NOUN
eurjchem-2037	183	24	around	around	ADP
eurjchem-2037	183	25	which	which	PRON
eurjchem-2037	183	26	they	they	PRON
eurjchem-2037	183	27	were	be	AUX
eurjchem-2037	183	28	calculated	calculate	VERB
eurjchem-2037	183	29	.	.	PUNCT
eurjchem-2037	184	1	the	the	DET
eurjchem-2037	184	2	molecular	molecular	ADJ
eurjchem-2037	184	3	hirshfeld	hirshfeld	NOUN
eurjchem-2037	184	4	surface	surface	NOUN
eurjchem-2037	184	5	(	(	PUNCT
eurjchem-2037	184	6	dnorm	dnorm	NOUN
eurjchem-2037	184	7	,	,	PUNCT
eurjchem-2037	184	8	shape	shape	NOUN
eurjchem-2037	184	9	index	index	NOUN
eurjchem-2037	184	10	,	,	PUNCT
eurjchem-2037	184	11	and	and	CCONJ
eurjchem-2037	184	12	curvedness	curvedness	ADJ
eurjchem-2037	184	13	)	)	PUNCT
eurjchem-2037	184	14	of	of	ADP
eurjchem-2037	184	15	complex	complex	ADJ
eurjchem-2037	184	16	2	2	NUM
eurjchem-2037	184	17	is	be	AUX
eurjchem-2037	184	18	shown	show	VERB
eurjchem-2037	184	19	in	in	ADP
eurjchem-2037	184	20	figure	figure	NOUN
eurjchem-2037	184	21	5	5	NUM
eurjchem-2037	184	22	.	.	PUNCT
eurjchem-2037	185	1	the	the	DET
eurjchem-2037	185	2	hirshfeld	hirshfeld	PROPN
eurjchem-2037	185	3	surface	surface	NOUN
eurjchem-2037	185	4	analysis	analysis	NOUN
eurjchem-2037	185	5	of	of	ADP
eurjchem-2037	185	6	the	the	DET
eurjchem-2037	185	7	complex	complex	ADJ
eurjchem-2037	185	8	2	2	NUM
eurjchem-2037	185	9	showed	show	VERB
eurjchem-2037	185	10	h···h	h···h	PROPN
eurjchem-2037	185	11	,	,	PUNCT
eurjchem-2037	185	12	n···h	n···h	PROPN
eurjchem-2037	185	13	,	,	PUNCT
eurjchem-2037	185	14	and	and	CCONJ
eurjchem-2037	185	15	br···h	br···h	NOUN
eurjchem-2037	185	16	interactions	interaction	NOUN
eurjchem-2037	185	17	of	of	ADP
eurjchem-2037	185	18	55.9	55.9	NUM
eurjchem-2037	185	19	,	,	PUNCT
eurjchem-2037	185	20	14.4	14.4	NUM
eurjchem-2037	185	21	,	,	PUNCT
eurjchem-2037	185	22	and	and	CCONJ
eurjchem-2037	185	23	4.1	4.1	NUM
eurjchem-2037	185	24	%	%	NOUN
eurjchem-2037	185	25	respectively	respectively	ADV
eurjchem-2037	185	26	,	,	PUNCT
eurjchem-2037	185	27	which	which	PRON
eurjchem-2037	185	28	revealed	reveal	VERB
eurjchem-2037	185	29	that	that	SCONJ
eurjchem-2037	185	30	the	the	DET
eurjchem-2037	185	31	main	main	ADJ
eurjchem-2037	185	32	intermolecular	intermolecular	ADJ
eurjchem-2037	185	33	interactions	interaction	NOUN
eurjchem-2037	185	34	were	be	AUX
eurjchem-2037	185	35	h···h	h···h	PROPN
eurjchem-2037	185	36	intermolecular	intermolecular	ADJ
eurjchem-2037	185	37	interactions	interaction	NOUN
eurjchem-2037	185	38	.	.	PUNCT
eurjchem-2037	186	1	the	the	DET
eurjchem-2037	186	2	n···h	n···h	PROPN
eurjchem-2037	186	3	and	and	CCONJ
eurjchem-2037	186	4	br···h	br···h	PROPN
eurjchem-2037	186	5	interactions	interaction	NOUN
eurjchem-2037	186	6	were	be	AUX
eurjchem-2037	186	7	represented	represent	VERB
eurjchem-2037	186	8	by	by	ADP
eurjchem-2037	186	9	a	a	DET
eurjchem-2037	186	10	small	small	ADJ
eurjchem-2037	186	11	area	area	NOUN
eurjchem-2037	186	12	in	in	ADP
eurjchem-2037	186	13	the	the	DET
eurjchem-2037	186	14	left	left	ADJ
eurjchem-2037	186	15	side	side	NOUN
eurjchem-2037	186	16	,	,	PUNCT
eurjchem-2037	186	17	whereas	whereas	SCONJ
eurjchem-2037	186	18	the	the	DET
eurjchem-2037	186	19	h···h	h···h	PROPN
eurjchem-2037	186	20	interactions	interaction	NOUN
eurjchem-2037	186	21	were	be	AUX
eurjchem-2037	186	22	represented	represent	VERB
eurjchem-2037	186	23	by	by	ADP
eurjchem-2037	186	24	the	the	DET
eurjchem-2037	186	25	largest	large	ADJ
eurjchem-2037	186	26	region	region	NOUN
eurjchem-2037	186	27	in	in	ADP
eurjchem-2037	186	28	the	the	DET
eurjchem-2037	186	29	fingerprint	fingerprint	NOUN
eurjchem-2037	186	30	plot	plot	NOUN
eurjchem-2037	186	31	(	(	PUNCT
eurjchem-2037	186	32	figure	figure	NOUN
eurjchem-2037	186	33	6	6	NUM
eurjchem-2037	186	34	)	)	PUNCT
eurjchem-2037	186	35	and	and	CCONJ
eurjchem-2037	186	36	thus	thus	ADV
eurjchem-2037	186	37	had	have	VERB
eurjchem-2037	186	38	the	the	DET
eurjchem-2037	186	39	most	most	ADV
eurjchem-2037	186	40	significant	significant	ADJ
eurjchem-2037	186	41	contribution	contribution	NOUN
eurjchem-2037	186	42	to	to	ADP
eurjchem-2037	186	43	the	the	DET
eurjchem-2037	186	44	total	total	ADJ
eurjchem-2037	186	45	hirshfeld	hirshfeld	NOUN
eurjchem-2037	186	46	surfaces	surface	NOUN
eurjchem-2037	186	47	(	(	PUNCT
eurjchem-2037	186	48	55.9	55.9	NUM
eurjchem-2037	186	49	%	%	NOUN
eurjchem-2037	186	50	)	)	PUNCT
eurjchem-2037	186	51	.	.	PUNCT
eurjchem-2037	187	1	340	340	NUM
eurjchem-2037	187	2	mondal	mondal	PROPN
eurjchem-2037	187	3	et	et	PROPN
eurjchem-2037	187	4	al	al	PROPN
eurjchem-2037	187	5	.	.	PUNCT
eurjchem-2037	187	6	/	/	SYM
eurjchem-2037	187	7	european	european	PROPN
eurjchem-2037	187	8	journal	journal	PROPN
eurjchem-2037	187	9	of	of	ADP
eurjchem-2037	187	10	chemistry	chemistry	NOUN
eurjchem-2037	187	11	11	11	NUM
eurjchem-2037	187	12	(	(	PUNCT
eurjchem-2037	187	13	4	4	NUM
eurjchem-2037	187	14	)	)	PUNCT
eurjchem-2037	187	15	(	(	PUNCT
eurjchem-2037	187	16	2020	2020	NUM
eurjchem-2037	187	17	)	)	PUNCT
eurjchem-2037	187	18	334	334	NUM
eurjchem-2037	187	19	-	-	SYM
eurjchem-2037	187	20	341	341	NUM
eurjchem-2037	187	21	2020	2020	NUM
eurjchem-2037	187	22	–	–	PUNCT
eurjchem-2037	187	23	european	european	ADJ
eurjchem-2037	187	24	journal	journal	NOUN
eurjchem-2037	187	25	of	of	ADP
eurjchem-2037	187	26	chemistry	chemistry	NOUN
eurjchem-2037	187	27	–	–	PUNCT
eurjchem-2037	187	28	cc	cc	NOUN
eurjchem-2037	187	29	by	by	ADP
eurjchem-2037	187	30	nc	nc	PROPN
eurjchem-2037	187	31	–	–	PUNCT
eurjchem-2037	187	32	doi	doi	NOUN
eurjchem-2037	187	33	:	:	PUNCT
eurjchem-2037	187	34	10.5155	10.5155	NUM
eurjchem-2037	187	35	/	/	SYM
eurjchem-2037	187	36	eurjchem.11.4.334	eurjchem.11.4.334	NOUN
eurjchem-2037	187	37	-	-	SYM
eurjchem-2037	187	38	341.2037	341.2037	NUM
eurjchem-2037	187	39	l	l	NOUN
eurjchem-2037	187	40	1	1	NUM
eurjchem-2037	187	41	2	2	NUM
eurjchem-2037	187	42	3	3	NUM
eurjchem-2037	187	43	figure	figure	NOUN
eurjchem-2037	187	44	7	7	NUM
eurjchem-2037	187	45	.	.	PUNCT
eurjchem-2037	187	46	molecular	molecular	ADJ
eurjchem-2037	187	47	electrostatic	electrostatic	ADJ
eurjchem-2037	187	48	potential	potential	NOUN
eurjchem-2037	187	49	(	(	PUNCT
eurjchem-2037	187	50	mep	mep	PROPN
eurjchem-2037	187	51	)	)	PUNCT
eurjchem-2037	187	52	of	of	ADP
eurjchem-2037	187	53	ligand	ligand	NOUN
eurjchem-2037	187	54	(	(	PUNCT
eurjchem-2037	187	55	a	a	NOUN
eurjchem-2037	187	56	)	)	PUNCT
eurjchem-2037	187	57	l	l	NOUN
eurjchem-2037	187	58	;	;	PUNCT
eurjchem-2037	187	59	(	(	PUNCT
eurjchem-2037	187	60	b	b	X
eurjchem-2037	187	61	)	)	PUNCT
eurjchem-2037	187	62	1	1	NUM
eurjchem-2037	187	63	,	,	PUNCT
eurjchem-2037	187	64	2	2	NUM
eurjchem-2037	187	65	and	and	CCONJ
eurjchem-2037	187	66	3	3	NUM
eurjchem-2037	187	67	.	.	X
eurjchem-2037	187	68	figure	figure	NOUN
eurjchem-2037	187	69	8	8	NUM
eurjchem-2037	187	70	.	.	PUNCT
eurjchem-2037	188	1	emission	emission	NOUN
eurjchem-2037	188	2	spectra	spectra	NOUN
eurjchem-2037	188	3	of	of	ADP
eurjchem-2037	188	4	complexes	complex	NOUN
eurjchem-2037	188	5	1	1	NUM
eurjchem-2037	188	6	,	,	PUNCT
eurjchem-2037	188	7	2	2	NUM
eurjchem-2037	188	8	and	and	CCONJ
eurjchem-2037	188	9	3	3	NUM
eurjchem-2037	188	10	in	in	ADP
eurjchem-2037	188	11	ch2cl2	ch2cl2	PUNCT
eurjchem-2037	188	12	at	at	ADP
eurjchem-2037	188	13	room	room	NOUN
eurjchem-2037	188	14	temperature	temperature	NOUN
eurjchem-2037	188	15	,	,	PUNCT
eurjchem-2037	188	16	on	on	ADP
eurjchem-2037	188	17	excitation	excitation	NOUN
eurjchem-2037	188	18	at	at	ADP
eurjchem-2037	188	19	380	380	NUM
eurjchem-2037	188	20	nm	nm	NOUN
eurjchem-2037	188	21	.	.	PUNCT
eurjchem-2037	189	1	3.5	3.5	NUM
eurjchem-2037	189	2	.	.	PUNCT
eurjchem-2037	190	1	molecular	molecular	ADJ
eurjchem-2037	190	2	electrostatic	electrostatic	ADJ
eurjchem-2037	190	3	potential	potential	NOUN
eurjchem-2037	190	4	(	(	PUNCT
eurjchem-2037	190	5	mep	mep	PROPN
eurjchem-2037	190	6	)	)	PUNCT
eurjchem-2037	190	7	the	the	DET
eurjchem-2037	190	8	potential	potential	ADJ
eurjchem-2037	190	9	increases	increase	NOUN
eurjchem-2037	190	10	in	in	ADP
eurjchem-2037	190	11	the	the	DET
eurjchem-2037	190	12	order	order	NOUN
eurjchem-2037	190	13	red	red	NOUN
eurjchem-2037	190	14	<	<	X
eurjchem-2037	190	15	yellow	yellow	NOUN
eurjchem-2037	190	16	<	<	X
eurjchem-2037	190	17	green	green	ADJ
eurjchem-2037	190	18	<	<	X
eurjchem-2037	190	19	blue	blue	ADJ
eurjchem-2037	190	20	<	<	X
eurjchem-2037	190	21	pink	pink	ADJ
eurjchem-2037	190	22	<	<	X
eurjchem-2037	190	23	white	white	PROPN
eurjchem-2037	190	24	.	.	PUNCT
eurjchem-2037	191	1	red	red	ADJ
eurjchem-2037	191	2	and	and	CCONJ
eurjchem-2037	191	3	yellow	yellow	NOUN
eurjchem-2037	191	4	represents	represent	VERB
eurjchem-2037	191	5	the	the	DET
eurjchem-2037	191	6	regions	region	NOUN
eurjchem-2037	191	7	of	of	ADP
eurjchem-2037	191	8	most	most	ADJ
eurjchem-2037	191	9	negative	negative	ADJ
eurjchem-2037	191	10	electrostatic	electrostatic	ADJ
eurjchem-2037	191	11	potential	potential	NOUN
eurjchem-2037	191	12	which	which	PRON
eurjchem-2037	191	13	is	be	AUX
eurjchem-2037	191	14	related	relate	VERB
eurjchem-2037	191	15	to	to	ADP
eurjchem-2037	191	16	electrophilic	electrophilic	ADJ
eurjchem-2037	191	17	reactivity	reactivity	NOUN
eurjchem-2037	191	18	,	,	PUNCT
eurjchem-2037	191	19	white	white	ADJ
eurjchem-2037	191	20	represents	represent	VERB
eurjchem-2037	191	21	the	the	DET
eurjchem-2037	191	22	regions	region	NOUN
eurjchem-2037	191	23	of	of	ADP
eurjchem-2037	191	24	most	most	ADV
eurjchem-2037	191	25	positive	positive	ADJ
eurjchem-2037	191	26	electrostatic	electrostatic	ADJ
eurjchem-2037	191	27	potential	potential	NOUN
eurjchem-2037	191	28	which	which	PRON
eurjchem-2037	191	29	is	be	AUX
eurjchem-2037	191	30	related	relate	VERB
eurjchem-2037	191	31	to	to	ADP
eurjchem-2037	191	32	nucleophilic	nucleophilic	ADJ
eurjchem-2037	191	33	reactivity	reactivity	NOUN
eurjchem-2037	191	34	and	and	CCONJ
eurjchem-2037	191	35	blue	blue	NOUN
eurjchem-2037	191	36	represents	represent	VERB
eurjchem-2037	191	37	the	the	DET
eurjchem-2037	191	38	region	region	NOUN
eurjchem-2037	191	39	of	of	ADP
eurjchem-2037	191	40	zero	zero	NUM
eurjchem-2037	191	41	potential	potential	NOUN
eurjchem-2037	191	42	.	.	PUNCT
eurjchem-2037	192	1	the	the	DET
eurjchem-2037	192	2	molecular	molecular	ADJ
eurjchem-2037	192	3	electrostatic	electrostatic	ADJ
eurjchem-2037	192	4	potential	potential	NOUN
eurjchem-2037	192	5	(	(	PUNCT
eurjchem-2037	192	6	mep	mep	PROPN
eurjchem-2037	192	7	)	)	PUNCT
eurjchem-2037	192	8	of	of	ADP
eurjchem-2037	192	9	ligand	ligand	ADJ
eurjchem-2037	192	10	l	l	NOUN
eurjchem-2037	192	11	is	be	AUX
eurjchem-2037	192	12	shown	show	VERB
eurjchem-2037	192	13	in	in	ADP
eurjchem-2037	192	14	figure	figure	NOUN
eurjchem-2037	192	15	7(a	7(a	NUM
eurjchem-2037	192	16	)	)	PUNCT
eurjchem-2037	192	17	,	,	PUNCT
eurjchem-2037	192	18	the	the	DET
eurjchem-2037	192	19	whole	whole	ADJ
eurjchem-2037	192	20	molecule	molecule	NOUN
eurjchem-2037	192	21	is	be	AUX
eurjchem-2037	192	22	reddish	reddish	ADJ
eurjchem-2037	192	23	yellow	yellow	ADJ
eurjchem-2037	192	24	in	in	ADP
eurjchem-2037	192	25	color	color	NOUN
eurjchem-2037	192	26	because	because	SCONJ
eurjchem-2037	192	27	of	of	ADP
eurjchem-2037	192	28	equally	equally	ADV
eurjchem-2037	192	29	distributed	distribute	VERB
eurjchem-2037	192	30	electron	electron	NOUN
eurjchem-2037	192	31	density	density	NOUN
eurjchem-2037	192	32	over	over	ADP
eurjchem-2037	192	33	the	the	DET
eurjchem-2037	192	34	molecule	molecule	NOUN
eurjchem-2037	192	35	.	.	PUNCT
eurjchem-2037	193	1	for	for	ADP
eurjchem-2037	193	2	this	this	DET
eurjchem-2037	193	3	reason	reason	NOUN
eurjchem-2037	193	4	,	,	PUNCT
eurjchem-2037	193	5	the	the	DET
eurjchem-2037	193	6	ligand	ligand	NOUN
eurjchem-2037	193	7	is	be	AUX
eurjchem-2037	193	8	supramolecularly	supramolecularly	ADV
eurjchem-2037	193	9	arranged	arrange	VERB
eurjchem-2037	193	10	via	via	ADP
eurjchem-2037	193	11	-{cui2-µ-x2	-{cui2-µ-x2	PUNCT
eurjchem-2037	193	12	}	}	PUNCT
eurjchem-2037	193	13	rhomboid	rhomboid	NOUN
eurjchem-2037	193	14	core	core	NOUN
eurjchem-2037	193	15	in	in	ADP
eurjchem-2037	193	16	the	the	DET
eurjchem-2037	193	17	complexes	complex	NOUN
eurjchem-2037	193	18	1,2	1,2	NUM
eurjchem-2037	193	19	,	,	PUNCT
eurjchem-2037	193	20	and	and	CCONJ
eurjchem-2037	193	21	3(figure	3(figure	NUM
eurjchem-2037	193	22	7(b	7(b	NUM
eurjchem-2037	193	23	)	)	PUNCT
eurjchem-2037	193	24	)	)	PUNCT
eurjchem-2037	193	25	.	.	PUNCT
eurjchem-2037	194	1	3.6	3.6	NUM
eurjchem-2037	194	2	.	.	PUNCT
eurjchem-2037	195	1	photophysical	photophysical	ADJ
eurjchem-2037	195	2	studies	study	NOUN
eurjchem-2037	195	3	fluorescent	fluorescent	NOUN
eurjchem-2037	195	4	behaviours	behaviour	NOUN
eurjchem-2037	195	5	of	of	ADP
eurjchem-2037	195	6	compounds	compound	NOUN
eurjchem-2037	195	7	were	be	AUX
eurjchem-2037	195	8	recorded	record	VERB
eurjchem-2037	195	9	in	in	ADP
eurjchem-2037	195	10	5.0×10	5.0×10	NUM
eurjchem-2037	195	11	-	-	SYM
eurjchem-2037	195	12	5	5	NUM
eurjchem-2037	195	13	mol	mol	ADP
eurjchem-2037	195	14	/	/	SYM
eurjchem-2037	195	15	l	l	NOUN
eurjchem-2037	195	16	ch2cl2	ch2cl2	NOUN
eurjchem-2037	195	17	solution	solution	NOUN
eurjchem-2037	195	18	at	at	ADP
eurjchem-2037	195	19	ambient	ambient	ADJ
eurjchem-2037	195	20	temperature	temperature	NOUN
eurjchem-2037	195	21	(	(	PUNCT
eurjchem-2037	195	22	figure	figure	NOUN
eurjchem-2037	195	23	8)	8)	NUM
eurjchem-2037	195	24	.	.	PUNCT
eurjchem-2037	195	25	complexes	complex	NOUN
eurjchem-2037	195	26	1	1	NUM
eurjchem-2037	195	27	,	,	PUNCT
eurjchem-2037	195	28	2	2	NUM
eurjchem-2037	195	29	,	,	PUNCT
eurjchem-2037	195	30	and	and	CCONJ
eurjchem-2037	195	31	3	3	NUM
eurjchem-2037	195	32	have	have	VERB
eurjchem-2037	195	33	characteristics	characteristic	NOUN
eurjchem-2037	195	34	with	with	ADP
eurjchem-2037	195	35	the	the	DET
eurjchem-2037	195	36	maximum	maximum	ADJ
eurjchem-2037	195	37	emission	emission	NOUN
eurjchem-2037	195	38	at	at	ADP
eurjchem-2037	195	39	450	450	NUM
eurjchem-2037	195	40	,	,	PUNCT
eurjchem-2037	195	41	437	437	NUM
eurjchem-2037	195	42	,	,	PUNCT
eurjchem-2037	195	43	and	and	CCONJ
eurjchem-2037	195	44	447	447	NUM
eurjchem-2037	195	45	nm	nm	NOUN
eurjchem-2037	195	46	,	,	PUNCT
eurjchem-2037	195	47	respectively	respectively	ADV
eurjchem-2037	195	48	,	,	PUNCT
eurjchem-2037	195	49	upon	upon	SCONJ
eurjchem-2037	195	50	excitation	excitation	NOUN
eurjchem-2037	195	51	at	at	ADP
eurjchem-2037	195	52	380	380	NUM
eurjchem-2037	195	53	nm	nm	NOUN
eurjchem-2037	195	54	,	,	PUNCT
eurjchem-2037	195	55	whereas	whereas	SCONJ
eurjchem-2037	195	56	the	the	DET
eurjchem-2037	195	57	ligand	ligand	NOUN
eurjchem-2037	195	58	l	l	NOUN
eurjchem-2037	195	59	is	be	AUX
eurjchem-2037	195	60	non	non	ADJ
eurjchem-2037	195	61	-	-	ADJ
eurjchem-2037	195	62	emissive	emissive	ADJ
eurjchem-2037	195	63	.	.	PUNCT
eurjchem-2037	196	1	no	no	DET
eurjchem-2037	196	2	emission	emission	NOUN
eurjchem-2037	196	3	originating	originate	VERB
eurjchem-2037	196	4	from	from	ADP
eurjchem-2037	196	5	metal	metal	NOUN
eurjchem-2037	196	6	-	-	PUNCT
eurjchem-2037	196	7	centered	center	VERB
eurjchem-2037	196	8	excited	excited	ADJ
eurjchem-2037	196	9	states	state	NOUN
eurjchem-2037	196	10	,	,	PUNCT
eurjchem-2037	196	11	since	since	SCONJ
eurjchem-2037	196	12	they	they	PRON
eurjchem-2037	196	13	are	be	AUX
eurjchem-2037	196	14	difficult	difficult	ADJ
eurjchem-2037	196	15	to	to	PART
eurjchem-2037	196	16	oxidize	oxidize	VERB
eurjchem-2037	196	17	or	or	CCONJ
eurjchem-2037	196	18	reduce	reduce	VERB
eurjchem-2037	196	19	due	due	ADJ
eurjchem-2037	196	20	to	to	ADP
eurjchem-2037	196	21	cu	cu	PROPN
eurjchem-2037	196	22	(	(	PUNCT
eurjchem-2037	196	23	i	i	NOUN
eurjchem-2037	196	24	)	)	PUNCT
eurjchem-2037	196	25	complexes	complex	NOUN
eurjchem-2037	196	26	has	have	VERB
eurjchem-2037	196	27	3d10	3d10	NUM
eurjchem-2037	196	28	electron	electron	NOUN
eurjchem-2037	196	29	configuration	configuration	NOUN
eurjchem-2037	196	30	.	.	PUNCT
eurjchem-2037	197	1	therefore	therefore	ADV
eurjchem-2037	197	2	,	,	PUNCT
eurjchem-2037	197	3	the	the	DET
eurjchem-2037	197	4	emission	emission	NOUN
eurjchem-2037	197	5	occurred	occur	VERB
eurjchem-2037	197	6	in	in	ADP
eurjchem-2037	197	7	the	the	DET
eurjchem-2037	197	8	complex	complex	NOUN
eurjchem-2037	197	9	is	be	AUX
eurjchem-2037	197	10	attributable	attributable	ADJ
eurjchem-2037	197	11	to	to	ADP
eurjchem-2037	197	12	intra	intra	ADJ
eurjchem-2037	197	13	-	-	ADJ
eurjchem-2037	197	14	ligand	ligand	ADJ
eurjchem-2037	197	15	π	π	PROPN
eurjchem-2037	197	16	-	-	PUNCT
eurjchem-2037	197	17	π	π	PROPN
eurjchem-2037	197	18	*	*	ADJ
eurjchem-2037	197	19	electronic	electronic	ADJ
eurjchem-2037	197	20	transitions	transition	NOUN
eurjchem-2037	197	21	.	.	PUNCT
eurjchem-2037	198	1	the	the	DET
eurjchem-2037	198	2	ligand	ligand	NOUN
eurjchem-2037	198	3	does	do	AUX
eurjchem-2037	198	4	not	not	PART
eurjchem-2037	198	5	show	show	VERB
eurjchem-2037	198	6	photoluminescence	photoluminescence	NOUN
eurjchem-2037	198	7	because	because	SCONJ
eurjchem-2037	198	8	photoinduced	photoinduce	VERB
eurjchem-2037	198	9	intramolecular	intramolecular	ADJ
eurjchem-2037	198	10	electron	electron	NOUN
eurjchem-2037	198	11	transfer	transfer	NOUN
eurjchem-2037	198	12	(	(	PUNCT
eurjchem-2037	198	13	pet	pet	NOUN
eurjchem-2037	198	14	)	)	PUNCT
eurjchem-2037	198	15	is	be	AUX
eurjchem-2037	198	16	prevailing	prevail	VERB
eurjchem-2037	198	17	in	in	ADP
eurjchem-2037	198	18	it	it	PRON
eurjchem-2037	198	19	.	.	PUNCT
eurjchem-2037	199	1	as	as	ADV
eurjchem-2037	199	2	soon	soon	ADV
eurjchem-2037	199	3	as	as	SCONJ
eurjchem-2037	199	4	cu(i	cu(i	NOUN
eurjchem-2037	199	5	)	)	PUNCT
eurjchem-2037	199	6	forms	form	VERB
eurjchem-2037	199	7	a	a	DET
eurjchem-2037	199	8	complex	complex	NOUN
eurjchem-2037	199	9	with	with	ADP
eurjchem-2037	199	10	the	the	DET
eurjchem-2037	199	11	ligand	ligand	NOUN
eurjchem-2037	199	12	and	and	CCONJ
eurjchem-2037	199	13	triphenyl	triphenyl	VERB
eurjchem-2037	199	14	phosphine	phosphine	NOUN
eurjchem-2037	199	15	,	,	PUNCT
eurjchem-2037	199	16	immediately	immediately	ADV
eurjchem-2037	199	17	pet	pet	ADJ
eurjchem-2037	199	18	is	be	AUX
eurjchem-2037	199	19	blocked	block	VERB
eurjchem-2037	199	20	and	and	CCONJ
eurjchem-2037	199	21	the	the	DET
eurjchem-2037	199	22	cu(i	cu(i	NOUN
eurjchem-2037	199	23	)	)	PUNCT
eurjchem-2037	199	24	complexes	complex	NOUN
eurjchem-2037	199	25	become	become	VERB
eurjchem-2037	199	26	photoluminescent	photoluminescent	NOUN
eurjchem-2037	199	27	.	.	PUNCT
eurjchem-2037	200	1	4	4	X
eurjchem-2037	200	2	.	.	X
eurjchem-2037	200	3	conclusion	conclusion	NOUN
eurjchem-2037	200	4	herein	herein	NOUN
eurjchem-2037	200	5	,	,	PUNCT
eurjchem-2037	200	6	three	three	NUM
eurjchem-2037	200	7	new	new	ADJ
eurjchem-2037	200	8	halide	halide	NOUN
eurjchem-2037	200	9	bridged	bridge	VERB
eurjchem-2037	200	10	copper(i	copper(i	NOUN
eurjchem-2037	200	11	)	)	PUNCT
eurjchem-2037	200	12	complexes	complex	NOUN
eurjchem-2037	201	1	[	[	X
eurjchem-2037	201	2	cu2(µ-l)(µ-x)2)(pph3)2]n	cu2(µ-l)(µ-x)2)(pph3)2]n	PROPN
eurjchem-2037	201	3	{	{	PUNCT
eurjchem-2037	201	4	x	x	NOUN
eurjchem-2037	201	5	:	:	PUNCT
eurjchem-2037	201	6	i	i	PRON
eurjchem-2037	201	7	(	(	PUNCT
eurjchem-2037	201	8	1	1	NUM
eurjchem-2037	201	9	)	)	PUNCT
eurjchem-2037	201	10	,	,	PUNCT
eurjchem-2037	201	11	br	br	PROPN
eurjchem-2037	201	12	(	(	PUNCT
eurjchem-2037	201	13	2	2	NUM
eurjchem-2037	201	14	)	)	PUNCT
eurjchem-2037	201	15	and	and	CCONJ
eurjchem-2037	201	16	cl	cl	INTJ
eurjchem-2037	201	17	(	(	PUNCT
eurjchem-2037	201	18	3	3	NUM
eurjchem-2037	201	19	)	)	PUNCT
eurjchem-2037	201	20	}	}	PUNCT
eurjchem-2037	201	21	have	have	AUX
eurjchem-2037	201	22	been	be	AUX
eurjchem-2037	201	23	reported	report	VERB
eurjchem-2037	201	24	,	,	PUNCT
eurjchem-2037	201	25	which	which	PRON
eurjchem-2037	201	26	were	be	AUX
eurjchem-2037	201	27	synthesized	synthesize	VERB
eurjchem-2037	201	28	by	by	ADP
eurjchem-2037	201	29	reactions	reaction	NOUN
eurjchem-2037	201	30	of	of	ADP
eurjchem-2037	201	31	cu(i)x	cu(i)x	PROPN
eurjchem-2037	201	32	(	(	PUNCT
eurjchem-2037	201	33	x	x	NOUN
eurjchem-2037	201	34	:	:	PUNCT
eurjchem-2037	201	35	i	i	PRON
eurjchem-2037	201	36	,	,	PUNCT
eurjchem-2037	201	37	br	br	PROPN
eurjchem-2037	201	38	and	and	CCONJ
eurjchem-2037	201	39	cl	cl	NOUN
eurjchem-2037	201	40	)	)	PUNCT
eurjchem-2037	201	41	with	with	ADP
eurjchem-2037	201	42	pph3	pph3	NOUN
eurjchem-2037	201	43	and	and	CCONJ
eurjchem-2037	201	44	the	the	DET
eurjchem-2037	201	45	polydentate	polydentate	ADJ
eurjchem-2037	201	46	imino	imino	NOUN
eurjchem-2037	201	47	-	-	PUNCT
eurjchem-2037	201	48	pyridyl	pyridyl	NOUN
eurjchem-2037	201	49	ligand	ligand	PROPN
eurjchem-2037	201	50	l.	l.	PROPN
eurjchem-2037	201	51	the	the	DET
eurjchem-2037	201	52	crystal	crystal	NOUN
eurjchem-2037	201	53	structure	structure	NOUN
eurjchem-2037	201	54	of	of	ADP
eurjchem-2037	201	55	the	the	DET
eurjchem-2037	201	56	complex	complex	ADJ
eurjchem-2037	201	57	2	2	NUM
eurjchem-2037	201	58	has	have	AUX
eurjchem-2037	201	59	been	be	AUX
eurjchem-2037	201	60	determined	determine	VERB
eurjchem-2037	201	61	by	by	ADP
eurjchem-2037	201	62	single	single	ADJ
eurjchem-2037	201	63	-	-	PUNCT
eurjchem-2037	201	64	crystal	crystal	NOUN
eurjchem-2037	201	65	x	x	ADJ
eurjchem-2037	201	66	-	-	NOUN
eurjchem-2037	201	67	ray	ray	NOUN
eurjchem-2037	201	68	analysis	analysis	NOUN
eurjchem-2037	201	69	and	and	CCONJ
eurjchem-2037	201	70	it	it	PRON
eurjchem-2037	201	71	is	be	AUX
eurjchem-2037	201	72	1	1	NUM
eurjchem-2037	201	73	-	-	PUNCT
eurjchem-2037	201	74	d	d	NOUN
eurjchem-2037	201	75	co	co	NOUN
eurjchem-2037	201	76	-	-	NOUN
eurjchem-2037	201	77	ordination	ordination	ADJ
eurjchem-2037	201	78	polymer	polymer	NOUN
eurjchem-2037	201	79	.	.	PUNCT
eurjchem-2037	202	1	from	from	ADP
eurjchem-2037	202	2	dft	dft	PROPN
eurjchem-2037	202	3	studies	study	NOUN
eurjchem-2037	202	4	of	of	ADP
eurjchem-2037	202	5	l	l	NOUN
eurjchem-2037	202	6	,	,	PUNCT
eurjchem-2037	202	7	it	it	PRON
eurjchem-2037	202	8	is	be	AUX
eurjchem-2037	202	9	found	find	VERB
eurjchem-2037	202	10	that	that	SCONJ
eurjchem-2037	202	11	energy	energy	NOUN
eurjchem-2037	202	12	gap	gap	NOUN
eurjchem-2037	202	13	between	between	ADP
eurjchem-2037	202	14	the	the	DET
eurjchem-2037	202	15	highest	high	ADJ
eurjchem-2037	202	16	occupied	occupy	VERB
eurjchem-2037	202	17	molecular	molecular	ADJ
eurjchem-2037	202	18	orbital	orbital	NOUN
eurjchem-2037	202	19	and	and	CCONJ
eurjchem-2037	202	20	the	the	DET
eurjchem-2037	202	21	lowest	low	ADJ
eurjchem-2037	202	22	unoccupied	unoccupied	ADJ
eurjchem-2037	202	23	molecular	molecular	ADJ
eurjchem-2037	202	24	orbital	orbital	NOUN
eurjchem-2037	202	25	for	for	ADP
eurjchem-2037	202	26	ligand	ligand	NOUN
eurjchem-2037	202	27	l	l	NOUN
eurjchem-2037	202	28	is	be	AUX
eurjchem-2037	202	29	5.30	5.30	NUM
eurjchem-2037	202	30	ev	ev	NOUN
eurjchem-2037	202	31	.	.	PUNCT
eurjchem-2037	203	1	the	the	DET
eurjchem-2037	203	2	hirshfeld	hirshfeld	PROPN
eurjchem-2037	203	3	surface	surface	NOUN
eurjchem-2037	203	4	analysis	analysis	NOUN
eurjchem-2037	203	5	of	of	ADP
eurjchem-2037	203	6	the	the	DET
eurjchem-2037	203	7	complex	complex	ADJ
eurjchem-2037	203	8	2	2	NUM
eurjchem-2037	203	9	showed	show	VERB
eurjchem-2037	203	10	h···h	h···h	PROPN
eurjchem-2037	203	11	,	,	PUNCT
eurjchem-2037	203	12	n···h	n···h	PROPN
eurjchem-2037	203	13	and	and	CCONJ
eurjchem-2037	203	14	br···h	br···h	PROPN
eurjchem-2037	203	15	interactions	interaction	NOUN
eurjchem-2037	203	16	of	of	ADP
eurjchem-2037	203	17	55.9	55.9	NUM
eurjchem-2037	203	18	,	,	PUNCT
eurjchem-2037	203	19	14.4	14.4	NUM
eurjchem-2037	203	20	and	and	CCONJ
eurjchem-2037	203	21	4.1	4.1	NUM
eurjchem-2037	203	22	%	%	NOUN
eurjchem-2037	203	23	,	,	PUNCT
eurjchem-2037	203	24	respectively	respectively	ADV
eurjchem-2037	203	25	.	.	PUNCT
eurjchem-2037	204	1	mep	mep	PROPN
eurjchem-2037	204	2	of	of	ADP
eurjchem-2037	204	3	ligand	ligand	PROPN
eurjchem-2037	204	4	l	l	PROPN
eurjchem-2037	204	5	reflects	reflect	VERB
eurjchem-2037	204	6	the	the	DET
eurjchem-2037	204	7	whole	whole	ADJ
eurjchem-2037	204	8	molecule	molecule	NOUN
eurjchem-2037	204	9	is	be	AUX
eurjchem-2037	204	10	reddish	reddish	ADJ
eurjchem-2037	204	11	yellow	yellow	ADJ
eurjchem-2037	204	12	in	in	ADP
eurjchem-2037	204	13	color	color	NOUN
eurjchem-2037	204	14	because	because	SCONJ
eurjchem-2037	204	15	of	of	ADP
eurjchem-2037	204	16	equally	equally	ADV
eurjchem-2037	204	17	distributed	distribute	VERB
eurjchem-2037	204	18	electron	electron	NOUN
eurjchem-2037	204	19	density	density	NOUN
eurjchem-2037	204	20	over	over	ADP
eurjchem-2037	204	21	the	the	DET
eurjchem-2037	204	22	molecule	molecule	NOUN
eurjchem-2037	204	23	.	.	PUNCT
eurjchem-2037	205	1	for	for	ADP
eurjchem-2037	205	2	this	this	DET
eurjchem-2037	205	3	reason	reason	NOUN
eurjchem-2037	205	4	,	,	PUNCT
eurjchem-2037	205	5	the	the	DET
eurjchem-2037	205	6	ligand	ligand	NOUN
eurjchem-2037	205	7	is	be	AUX
eurjchem-2037	205	8	supramolecularly	supramolecularly	ADV
eurjchem-2037	205	9	arranged	arrange	VERB
eurjchem-2037	205	10	via	via	ADP
eurjchem-2037	205	11	-{cui2-µ-x2	-{cui2-µ-x2	PUNCT
eurjchem-2037	205	12	}	}	PUNCT
eurjchem-2037	205	13	rhomboid	rhomboid	NOUN
eurjchem-2037	205	14	core	core	NOUN
eurjchem-2037	205	15	in	in	ADP
eurjchem-2037	205	16	the	the	DET
eurjchem-2037	205	17	complex	complex	ADJ
eurjchem-2037	205	18	2	2	NUM
eurjchem-2037	205	19	.	.	PUNCT
eurjchem-2037	206	1	the	the	DET
eurjchem-2037	206	2	ligand	ligand	PROPN
eurjchem-2037	206	3	l	l	NOUN
eurjchem-2037	206	4	is	be	AUX
eurjchem-2037	206	5	non	non	ADJ
eurjchem-2037	206	6	-	-	ADJ
eurjchem-2037	206	7	emissive	emissive	ADJ
eurjchem-2037	206	8	at	at	ADP
eurjchem-2037	206	9	room	room	NOUN
eurjchem-2037	206	10	temperature	temperature	NOUN
eurjchem-2037	206	11	in	in	ADP
eurjchem-2037	206	12	dichloromethane	dichloromethane	NOUN
eurjchem-2037	206	13	,	,	PUNCT
eurjchem-2037	206	14	whereas	whereas	SCONJ
eurjchem-2037	206	15	the	the	DET
eurjchem-2037	206	16	complexes	complex	NOUN
eurjchem-2037	206	17	1	1	NUM
eurjchem-2037	206	18	,	,	PUNCT
eurjchem-2037	206	19	2	2	NUM
eurjchem-2037	206	20	and	and	CCONJ
eurjchem-2037	206	21	3	3	NUM
eurjchem-2037	206	22	are	be	AUX
eurjchem-2037	206	23	photoluminescent	photoluminescent	ADJ
eurjchem-2037	206	24	.	.	PUNCT
eurjchem-2037	207	1	the	the	DET
eurjchem-2037	207	2	emission	emission	NOUN
eurjchem-2037	207	3	in	in	ADP
eurjchem-2037	207	4	the	the	DET
eurjchem-2037	207	5	complexes	complex	NOUN
eurjchem-2037	207	6	1	1	NUM
eurjchem-2037	207	7	,	,	PUNCT
eurjchem-2037	207	8	2	2	NUM
eurjchem-2037	207	9	and	and	CCONJ
eurjchem-2037	207	10	3	3	NUM
eurjchem-2037	207	11	is	be	AUX
eurjchem-2037	207	12	attributable	attributable	ADJ
eurjchem-2037	207	13	to	to	ADP
eurjchem-2037	207	14	intra	intra	ADJ
eurjchem-2037	207	15	-	-	ADJ
eurjchem-2037	207	16	ligand	ligand	ADJ
eurjchem-2037	207	17	π	π	PROPN
eurjchem-2037	207	18	-	-	PUNCT
eurjchem-2037	207	19	π	π	PROPN
eurjchem-2037	207	20	*	*	ADJ
eurjchem-2037	207	21	electronic	electronic	ADJ
eurjchem-2037	207	22	transitions	transition	NOUN
eurjchem-2037	207	23	.	.	PUNCT
eurjchem-2037	208	1	mondal	mondal	PROPN
eurjchem-2037	208	2	et	et	PROPN
eurjchem-2037	208	3	al	al	PROPN
eurjchem-2037	208	4	.	.	PUNCT
eurjchem-2037	208	5	/	/	SYM
eurjchem-2037	208	6	european	european	PROPN
eurjchem-2037	208	7	journal	journal	PROPN
eurjchem-2037	208	8	of	of	ADP
eurjchem-2037	208	9	chemistry	chemistry	NOUN
eurjchem-2037	208	10	11	11	NUM
eurjchem-2037	208	11	(	(	PUNCT
eurjchem-2037	208	12	4	4	NUM
eurjchem-2037	208	13	)	)	PUNCT
eurjchem-2037	208	14	(	(	PUNCT
eurjchem-2037	208	15	2020	2020	NUM
eurjchem-2037	208	16	)	)	PUNCT
eurjchem-2037	208	17	334	334	NUM
eurjchem-2037	208	18	-	-	SYM
eurjchem-2037	208	19	341	341	NUM
eurjchem-2037	208	20	341	341	NUM
eurjchem-2037	208	21	2020	2020	NUM
eurjchem-2037	208	22	–	–	PUNCT
eurjchem-2037	208	23	european	european	ADJ
eurjchem-2037	208	24	journal	journal	NOUN
eurjchem-2037	208	25	of	of	ADP
eurjchem-2037	208	26	chemistry	chemistry	NOUN
eurjchem-2037	208	27	–	–	PUNCT
eurjchem-2037	208	28	cc	cc	NOUN
eurjchem-2037	208	29	by	by	ADP
eurjchem-2037	208	30	nc	nc	PROPN
eurjchem-2037	208	31	–	–	PUNCT
eurjchem-2037	208	32	doi	doi	NOUN
eurjchem-2037	208	33	:	:	PUNCT
eurjchem-2037	208	34	10.5155	10.5155	NUM
eurjchem-2037	208	35	/	/	SYM
eurjchem-2037	208	36	eurjchem.11.4.334	eurjchem.11.4.334	NOUN
eurjchem-2037	208	37	-	-	SYM
eurjchem-2037	208	38	341.2037	341.2037	NUM
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eurjchem-2037	208	42	patra	patra	PROPN
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eurjchem-2037	208	46	thank	thank	VERB
eurjchem-2037	208	47	the	the	DET
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eurjchem-2037	208	50	science	science	NOUN
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eurjchem-2037	208	53	,	,	PUNCT
eurjchem-2037	208	54	government	government	NOUN
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eurjchem-2037	208	56	india	india	PROPN
eurjchem-2037	208	57	,	,	PUNCT
eurjchem-2037	208	58	new	new	ADJ
eurjchem-2037	208	59	delhi	delhi	PROPN
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eurjchem-2037	208	61	financial	financial	ADJ
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eurjchem-2037	208	65	nos	nos	PROPN
eurjchem-2037	208	66	.	.	PROPN
eurjchem-2037	208	67	sr	sr	PROPN
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eurjchem-2037	208	69	fst	fst	PROPN
eurjchem-2037	208	70	/	/	SYM
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eurjchem-2037	208	72	and	and	CCONJ
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eurjchem-2037	208	75	.	.	PUNCT
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eurjchem-2037	209	2	information	information	NOUN
eurjchem-2037	209	3	ccdc-1027695	ccdc-1027695	NOUN
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eurjchem-2037	209	5	the	the	DET
eurjchem-2037	209	6	supplementary	supplementary	ADJ
eurjchem-2037	209	7	crystallographic	crystallographic	ADJ
eurjchem-2037	209	8	data	datum	NOUN
eurjchem-2037	209	9	for	for	ADP
eurjchem-2037	209	10	this	this	DET
eurjchem-2037	209	11	paper	paper	NOUN
eurjchem-2037	209	12	.	.	PUNCT
eurjchem-2037	210	1	these	these	DET
eurjchem-2037	210	2	data	datum	NOUN
eurjchem-2037	210	3	can	can	AUX
eurjchem-2037	210	4	be	be	AUX
eurjchem-2037	210	5	obtained	obtain	VERB
eurjchem-2037	210	6	free	free	ADJ
eurjchem-2037	210	7	of	of	ADP
eurjchem-2037	210	8	charge	charge	NOUN
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eurjchem-2037	210	12	by	by	ADP
eurjchem-2037	210	13	emailing	email	VERB
eurjchem-2037	210	14	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-2037	210	15	,	,	PUNCT
eurjchem-2037	210	16	or	or	CCONJ
eurjchem-2037	210	17	by	by	ADP
eurjchem-2037	210	18	contacting	contact	VERB
eurjchem-2037	210	19	the	the	DET
eurjchem-2037	210	20	cambridge	cambridge	PROPN
eurjchem-2037	210	21	crystallographic	crystallographic	PROPN
eurjchem-2037	210	22	data	data	PROPN
eurjchem-2037	210	23	centre	centre	NOUN
eurjchem-2037	210	24	,	,	PUNCT
eurjchem-2037	210	25	12	12	NUM
eurjchem-2037	210	26	union	union	NOUN
eurjchem-2037	210	27	road	road	NOUN
eurjchem-2037	210	28	,	,	PUNCT
eurjchem-2037	210	29	cambridge	cambridge	PROPN
eurjchem-2037	210	30	cb2	cb2	PROPN
eurjchem-2037	210	31	1ez	1ez	PROPN
eurjchem-2037	210	32	,	,	PUNCT
eurjchem-2037	210	33	uk	uk	PROPN
eurjchem-2037	210	34	;	;	PUNCT
eurjchem-2037	210	35	fax	fax	NOUN
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eurjchem-2037	210	37	+44(0)1223	+44(0)1223	PROPN
eurjchem-2037	210	38	-	-	PUNCT
eurjchem-2037	210	39	336033	336033	NUM
eurjchem-2037	210	40	.	.	PUNCT
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eurjchem-2037	211	2	statement	statement	NOUN
eurjchem-2037	211	3	conflict	conflict	NOUN
eurjchem-2037	211	4	of	of	ADP
eurjchem-2037	211	5	interest	interest	NOUN
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eurjchem-2037	211	7	the	the	DET
eurjchem-2037	211	8	authors	author	NOUN
eurjchem-2037	211	9	declare	declare	VERB
eurjchem-2037	211	10	that	that	SCONJ
eurjchem-2037	211	11	they	they	PRON
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eurjchem-2037	211	14	conflict	conflict	NOUN
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eurjchem-2037	211	16	interest	interest	NOUN
eurjchem-2037	211	17	.	.	PUNCT
eurjchem-2037	212	1	author	author	NOUN
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eurjchem-2037	212	3	:	:	PUNCT
eurjchem-2037	212	4	all	all	DET
eurjchem-2037	212	5	authors	author	NOUN
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eurjchem-2037	212	9	this	this	DET
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eurjchem-2037	212	11	.	.	PUNCT
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eurjchem-2037	213	2	approval	approval	NOUN
eurjchem-2037	213	3	:	:	PUNCT
eurjchem-2037	214	1	all	all	DET
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eurjchem-2037	214	3	guidelines	guideline	NOUN
eurjchem-2037	214	4	have	have	AUX
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eurjchem-2037	215	6	the	the	DET
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eurjchem-2037	215	9	available	available	ADJ
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eurjchem-2037	215	11	the	the	DET
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eurjchem-2037	215	13	.	.	PUNCT
eurjchem-2037	216	1	orcid	orcid	PROPN
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eurjchem-2037	216	5	amit	amit	PROPN
eurjchem-2037	216	6	kumar	kumar	PROPN
eurjchem-2037	216	7	manna	manna	PROPN
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eurjchem-2037	216	10	kumar	kumar	PROPN
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eurjchem-2037	217	3	g.	g.	PROPN
eurjchem-2037	217	4	r.	r.	PROPN
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eurjchem-2037	235	2	,	,	PUNCT
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eurjchem-2037	335	207	p.	p.	PROPN
eurjchem-2037	335	208	y.	y.	PROPN
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eurjchem-2037	335	212	k.	k.	PROPN
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eurjchem-2037	335	214	voth	voth	PROPN
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eurjchem-2037	335	218	salvador	salvador	PROPN
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eurjchem-2037	335	220	a.	a.	NOUN
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eurjchem-2037	335	239	a.	a.	PROPN
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eurjchem-2037	335	253	d.	d.	PROPN
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eurjchem-2037	335	267	j.	j.	PROPN
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eurjchem-2037	335	274	;	;	PUNCT
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eurjchem-2037	335	277	q.	q.	PROPN
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eurjchem-2037	335	290	j.	j.	PROPN
eurjchem-2037	335	291	;	;	PUNCT
eurjchem-2037	335	292	ste	ste	PROPN
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eurjchem-2037	335	296	b.	b.	PROPN
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eurjchem-2037	336	4	;	;	PUNCT
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eurjchem-2037	336	8	;	;	PUNCT
eurjchem-2037	336	9	piskorz	piskorz	PROPN
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eurjchem-2037	364	12	,	,	PUNCT
eurjchem-2037	364	13	atlanta	atlanta	PROPN
eurjchem-2037	364	14	,	,	PUNCT
eurjchem-2037	364	15	ga	ga	PROPN
eurjchem-2037	364	16	,	,	PUNCT
eurjchem-2037	364	17	usa	usa	PROPN
eurjchem-2037	364	18	.	.	PUNCT
eurjchem-2037	365	1	the	the	DET
eurjchem-2037	365	2	full	full	ADJ
eurjchem-2037	365	3	terms	term	NOUN
eurjchem-2037	365	4	of	of	ADP
eurjchem-2037	365	5	this	this	DET
eurjchem-2037	365	6	license	license	NOUN
eurjchem-2037	365	7	are	be	AUX
eurjchem-2037	365	8	available	available	ADJ
eurjchem-2037	365	9	at	at	ADP
eurjchem-2037	365	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2037	365	11	and	and	CCONJ
eurjchem-2037	365	12	incorporate	incorporate	VERB
eurjchem-2037	365	13	the	the	DET
eurjchem-2037	365	14	creative	creative	ADJ
eurjchem-2037	365	15	commons	common	NOUN
eurjchem-2037	365	16	attribution	attribution	NOUN
eurjchem-2037	365	17	-	-	PUNCT
eurjchem-2037	365	18	non	non	ADJ
eurjchem-2037	365	19	commercial	commercial	NOUN
eurjchem-2037	365	20	(	(	PUNCT
eurjchem-2037	365	21	cc	cc	NOUN
eurjchem-2037	365	22	by	by	ADP
eurjchem-2037	365	23	nc	nc	PROPN
eurjchem-2037	365	24	)	)	PUNCT
eurjchem-2037	365	25	(	(	PUNCT
eurjchem-2037	365	26	international	international	ADJ
eurjchem-2037	365	27	,	,	PUNCT
eurjchem-2037	365	28	v4.0	v4.0	NOUN
eurjchem-2037	365	29	)	)	PUNCT
eurjchem-2037	365	30	license	license	NOUN
eurjchem-2037	365	31	(	(	PUNCT
eurjchem-2037	365	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2037	365	33	)	)	PUNCT
eurjchem-2037	365	34	.	.	PUNCT
eurjchem-2037	366	1	by	by	ADP
eurjchem-2037	366	2	accessing	access	VERB
eurjchem-2037	366	3	the	the	DET
eurjchem-2037	366	4	work	work	NOUN
eurjchem-2037	366	5	,	,	PUNCT
eurjchem-2037	366	6	you	you	PRON
eurjchem-2037	366	7	hereby	hereby	ADV
eurjchem-2037	366	8	accept	accept	VERB
eurjchem-2037	366	9	the	the	DET
eurjchem-2037	366	10	terms	term	NOUN
eurjchem-2037	366	11	.	.	PUNCT
eurjchem-2037	367	1	this	this	PRON
eurjchem-2037	367	2	is	be	AUX
eurjchem-2037	367	3	an	an	DET
eurjchem-2037	367	4	open	open	ADJ
eurjchem-2037	367	5	access	access	NOUN
eurjchem-2037	367	6	article	article	NOUN
eurjchem-2037	367	7	distributed	distribute	VERB
eurjchem-2037	367	8	under	under	ADP
eurjchem-2037	367	9	the	the	DET
eurjchem-2037	367	10	terms	term	NOUN
eurjchem-2037	367	11	and	and	CCONJ
eurjchem-2037	367	12	conditions	condition	NOUN
eurjchem-2037	367	13	of	of	ADP
eurjchem-2037	367	14	the	the	DET
eurjchem-2037	367	15	cc	cc	PROPN
eurjchem-2037	367	16	by	by	ADP
eurjchem-2037	367	17	nc	nc	PROPN
eurjchem-2037	367	18	license	license	PROPN
eurjchem-2037	367	19	,	,	PUNCT
eurjchem-2037	367	20	which	which	PRON
eurjchem-2037	367	21	permits	permit	VERB
eurjchem-2037	367	22	unrestricted	unrestricted	ADJ
eurjchem-2037	367	23	non	non	ADJ
eurjchem-2037	367	24	-	-	ADJ
eurjchem-2037	367	25	commercial	commercial	ADJ
eurjchem-2037	367	26	use	use	NOUN
eurjchem-2037	367	27	,	,	PUNCT
eurjchem-2037	367	28	distribution	distribution	NOUN
eurjchem-2037	367	29	,	,	PUNCT
eurjchem-2037	367	30	and	and	CCONJ
eurjchem-2037	367	31	reproduction	reproduction	NOUN
eurjchem-2037	367	32	in	in	ADP
eurjchem-2037	367	33	any	any	DET
eurjchem-2037	367	34	medium	medium	NOUN
eurjchem-2037	367	35	,	,	PUNCT
eurjchem-2037	367	36	provided	provide	VERB
eurjchem-2037	367	37	the	the	DET
eurjchem-2037	367	38	original	original	ADJ
eurjchem-2037	367	39	work	work	NOUN
eurjchem-2037	367	40	is	be	AUX
eurjchem-2037	367	41	properly	properly	ADV
eurjchem-2037	367	42	cited	cite	VERB
eurjchem-2037	367	43	without	without	ADP
eurjchem-2037	367	44	any	any	DET
eurjchem-2037	367	45	further	further	ADJ
eurjchem-2037	367	46	permission	permission	NOUN
eurjchem-2037	367	47	from	from	ADP
eurjchem-2037	367	48	atlanta	atlanta	PROPN
eurjchem-2037	367	49	publishing	publishing	PROPN
eurjchem-2037	367	50	house	house	PROPN
eurjchem-2037	367	51	llc	llc	PROPN
eurjchem-2037	367	52	(	(	PUNCT
eurjchem-2037	367	53	european	european	PROPN
eurjchem-2037	367	54	journal	journal	PROPN
eurjchem-2037	367	55	of	of	ADP
eurjchem-2037	367	56	chemistry	chemistry	NOUN
eurjchem-2037	367	57	)	)	PUNCT
eurjchem-2037	367	58	.	.	PUNCT
eurjchem-2037	368	1	no	no	DET
eurjchem-2037	368	2	use	use	NOUN
eurjchem-2037	368	3	,	,	PUNCT
eurjchem-2037	368	4	distribution	distribution	NOUN
eurjchem-2037	368	5	or	or	CCONJ
eurjchem-2037	368	6	reproduction	reproduction	NOUN
eurjchem-2037	368	7	is	be	AUX
eurjchem-2037	368	8	permitted	permit	VERB
eurjchem-2037	368	9	which	which	PRON
eurjchem-2037	368	10	does	do	AUX
eurjchem-2037	368	11	not	not	PART
eurjchem-2037	368	12	comply	comply	VERB
eurjchem-2037	368	13	with	with	ADP
eurjchem-2037	368	14	these	these	DET
eurjchem-2037	368	15	terms	term	NOUN
eurjchem-2037	368	16	.	.	PUNCT
eurjchem-2037	369	1	permissions	permission	NOUN
eurjchem-2037	369	2	for	for	ADP
eurjchem-2037	369	3	commercial	commercial	ADJ
eurjchem-2037	369	4	use	use	NOUN
eurjchem-2037	369	5	of	of	ADP
eurjchem-2037	369	6	this	this	DET
eurjchem-2037	369	7	work	work	NOUN
eurjchem-2037	369	8	beyond	beyond	ADP
eurjchem-2037	369	9	the	the	DET
eurjchem-2037	369	10	scope	scope	NOUN
eurjchem-2037	369	11	of	of	ADP
eurjchem-2037	369	12	the	the	DET
eurjchem-2037	369	13	license	license	NOUN
eurjchem-2037	369	14	(	(	PUNCT
eurjchem-2037	369	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2037	369	16	)	)	PUNCT
eurjchem-2037	369	17	are	be	AUX
eurjchem-2037	369	18	administered	administer	VERB
eurjchem-2037	369	19	by	by	ADP
eurjchem-2037	369	20	atlanta	atlanta	PROPN
eurjchem-2037	369	21	publishing	publishing	PROPN
eurjchem-2037	369	22	house	house	PROPN
eurjchem-2037	369	23	llc	llc	PROPN
eurjchem-2037	369	24	(	(	PUNCT
eurjchem-2037	369	25	european	european	PROPN
eurjchem-2037	369	26	journal	journal	PROPN
eurjchem-2037	369	27	of	of	ADP
eurjchem-2037	369	28	chemistry	chemistry	NOUN
eurjchem-2037	369	29	)	)	PUNCT
eurjchem-2037	369	30	.	.	PUNCT
eurjchem-2037	370	1	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	PROPN
eurjchem-2037	370	2	mailto:data_request@ccdc.cam.ac.uk	mailto:data_request@ccdc.cam.ac.uk	NOUN
eurjchem-2037	370	3	http://orcid.org/0000-0001-9867-5193	http://orcid.org/0000-0001-9867-5193	ADP
eurjchem-2037	370	4	http://orcid.org/0000-0002-9605-2168	http://orcid.org/0000-0002-9605-2168	VERB
eurjchem-2037	370	5	http://orcid.org/0000-0003-3151-0284	http://orcid.org/0000-0003-3151-0284	NOUN
eurjchem-2037	370	6	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	PROPN
eurjchem-2037	370	7	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2037	370	8	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2037	370	9	1	1	NUM
eurjchem-2037	370	10	.	.	PUNCT
eurjchem-2037	370	11	introduction	introduction	NOUN
eurjchem-2037	370	12	2	2	NUM
eurjchem-2037	370	13	.	.	PUNCT
eurjchem-2037	370	14	experimental	experimental	ADJ
eurjchem-2037	370	15	2.1	2.1	NUM
eurjchem-2037	370	16	.	.	PUNCT
eurjchem-2037	371	1	materials	material	NOUN
eurjchem-2037	371	2	and	and	CCONJ
eurjchem-2037	371	3	physical	physical	ADJ
eurjchem-2037	371	4	measurements	measurement	NOUN
eurjchem-2037	371	5	2.2	2.2	NUM
eurjchem-2037	371	6	.	.	PUNCT
eurjchem-2037	371	7	synthesis	synthesis	NOUN
eurjchem-2037	371	8	of	of	ADP
eurjchem-2037	371	9	the	the	DET
eurjchem-2037	371	10	imino	imino	NOUN
eurjchem-2037	371	11	-	-	PUNCT
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eurjchem-2037	371	13	ligand	ligand	NOUN
eurjchem-2037	371	14	(	(	PUNCT
eurjchem-2037	371	15	l	l	NOUN
eurjchem-2037	371	16	)	)	PUNCT
eurjchem-2037	371	17	2.3	2.3	NUM
eurjchem-2037	371	18	.	.	PUNCT
eurjchem-2037	372	1	synthesis	synthesis	NOUN
eurjchem-2037	372	2	of	of	ADP
eurjchem-2037	372	3	[	[	X
eurjchem-2037	372	4	cu2(µ-l)(µ-i)2(pph3)2]n	cu2(µ-l)(µ-i)2(pph3)2]n	NOUN
eurjchem-2037	372	5	(	(	PUNCT
eurjchem-2037	372	6	1	1	NUM
eurjchem-2037	372	7	)	)	PUNCT
eurjchem-2037	372	8	2.4	2.4	NUM
eurjchem-2037	372	9	.	.	PUNCT
eurjchem-2037	373	1	synthesis	synthesis	NOUN
eurjchem-2037	373	2	of	of	ADP
eurjchem-2037	373	3	[	[	X
eurjchem-2037	373	4	cu2(µ-l)(µ-br)2(pph3)2]n	cu2(µ-l)(µ-br)2(pph3)2]n	NOUN
eurjchem-2037	373	5	(	(	PUNCT
eurjchem-2037	373	6	2	2	NUM
eurjchem-2037	373	7	)	)	PUNCT
eurjchem-2037	373	8	2.5	2.5	NUM
eurjchem-2037	373	9	.	.	PUNCT
eurjchem-2037	374	1	synthesis	synthesis	NOUN
eurjchem-2037	374	2	of	of	ADP
eurjchem-2037	374	3	[	[	X
eurjchem-2037	374	4	cu2(µ-l)(µ-cl)2(pph3)2]n	cu2(µ-l)(µ-cl)2(pph3)2]n	X
eurjchem-2037	374	5	(	(	PUNCT
eurjchem-2037	374	6	3	3	NUM
eurjchem-2037	374	7	)	)	PUNCT
eurjchem-2037	374	8	2.6	2.6	NUM
eurjchem-2037	374	9	.	.	PUNCT
eurjchem-2037	375	1	x	x	X
eurjchem-2037	375	2	-	-	PUNCT
eurjchem-2037	375	3	ray	ray	NOUN
eurjchem-2037	375	4	crystallography	crystallography	NOUN
eurjchem-2037	375	5	2.7	2.7	NUM
eurjchem-2037	375	6	.	.	PUNCT
eurjchem-2037	376	1	theoretical	theoretical	ADJ
eurjchem-2037	376	2	calculations	calculation	NOUN
eurjchem-2037	376	3	2.8	2.8	NUM
eurjchem-2037	376	4	.	.	PUNCT
eurjchem-2037	377	1	hirshfeld	hirshfeld	PROPN
eurjchem-2037	377	2	surfaces	surfaces	PROPN
eurjchem-2037	377	3	calculations	calculation	VERB
eurjchem-2037	377	4	2.9	2.9	NUM
eurjchem-2037	377	5	.	.	PUNCT
eurjchem-2037	378	1	molecular	molecular	ADJ
eurjchem-2037	378	2	electrostatic	electrostatic	ADJ
eurjchem-2037	378	3	potential	potential	NOUN
eurjchem-2037	378	4	(	(	PUNCT
eurjchem-2037	378	5	mep	mep	PROPN
eurjchem-2037	378	6	)	)	PUNCT
eurjchem-2037	378	7	3	3	NUM
eurjchem-2037	378	8	.	.	NOUN
eurjchem-2037	378	9	results	result	NOUN
eurjchem-2037	378	10	and	and	CCONJ
eurjchem-2037	378	11	discussion	discussion	NOUN
eurjchem-2037	378	12	3.1	3.1	NUM
eurjchem-2037	378	13	.	.	PUNCT
eurjchem-2037	379	1	syntheses	synthesis	NOUN
eurjchem-2037	379	2	of	of	ADP
eurjchem-2037	379	3	the	the	DET
eurjchem-2037	379	4	complexes	complex	NOUN
eurjchem-2037	379	5	1	1	NUM
eurjchem-2037	379	6	,	,	PUNCT
eurjchem-2037	379	7	2	2	NUM
eurjchem-2037	379	8	and	and	CCONJ
eurjchem-2037	379	9	3	3	NUM
eurjchem-2037	379	10	3.2	3.2	NUM
eurjchem-2037	379	11	.	.	PUNCT
eurjchem-2037	380	1	structural	structural	ADJ
eurjchem-2037	380	2	description	description	NOUN
eurjchem-2037	380	3	of	of	ADP
eurjchem-2037	380	4	the	the	DET
eurjchem-2037	380	5	complex	complex	ADJ
eurjchem-2037	380	6	2	2	NUM
eurjchem-2037	380	7	3.3	3.3	NUM
eurjchem-2037	380	8	.	.	PUNCT
eurjchem-2037	381	1	theoretical	theoretical	ADJ
eurjchem-2037	381	2	investigations	investigation	NOUN
eurjchem-2037	381	3	3.4	3.4	NUM
eurjchem-2037	381	4	.	.	PUNCT
eurjchem-2037	382	1	molecular	molecular	ADJ
eurjchem-2037	382	2	hirshfeld	hirshfeld	NOUN
eurjchem-2037	382	3	surfaces	surface	NOUN
eurjchem-2037	382	4	3.5	3.5	NUM
eurjchem-2037	382	5	.	.	PUNCT
eurjchem-2037	383	1	molecular	molecular	ADJ
eurjchem-2037	383	2	electrostatic	electrostatic	ADJ
eurjchem-2037	383	3	potential	potential	NOUN
eurjchem-2037	383	4	(	(	PUNCT
eurjchem-2037	383	5	mep	mep	PROPN
eurjchem-2037	383	6	)	)	PUNCT
eurjchem-2037	383	7	3.6	3.6	NUM
eurjchem-2037	383	8	.	.	PUNCT
eurjchem-2037	384	1	photophysical	photophysical	ADJ
eurjchem-2037	384	2	studies	study	NOUN
eurjchem-2037	384	3	4	4	NUM
eurjchem-2037	384	4	.	.	PUNCT
eurjchem-2037	385	1	conclusion	conclusion	NOUN
eurjchem-2037	385	2	acknowledgements	acknowledgement	NOUN
eurjchem-2037	385	3	supporting	support	VERB
eurjchem-2037	385	4	information	information	NOUN
eurjchem-2037	385	5	disclosure	disclosure	NOUN
eurjchem-2037	385	6	statement	statement	NOUN
eurjchem-2037	385	7	orcid	orcid	PROPN
eurjchem-2037	385	8	references	reference	NOUN
eurjchem-2037	385	9	printfield10	printfield10	NOUN
eurjchem-2037	385	10	:	:	PUNCT
eurjchem-2037	385	11	printfield11	printfield11	NOUN
eurjchem-2037	385	12	:	:	PUNCT
eurjchem-2037	385	13	printfield12	printfield12	PROPN
eurjchem-2037	385	14	:	:	PUNCT
eurjchem-2037	385	15	printfield13	printfield13	VERB
eurjchem-2037	385	16	:	:	PUNCT
eurjchem-2037	385	17	printfield14	printfield14	NOUN
eurjchem-2037	385	18	:	:	PUNCT
eurjchem-2037	385	19	printfield15	printfield15	NOUN
eurjchem-2037	385	20	:	:	PUNCT
eurjchem-2037	385	21	printfield16	printfield16	ADJ
eurjchem-2037	385	22	:	:	PUNCT
eurjchem-2037	385	23	printfield17	printfield17	NOUN
eurjchem-2037	385	24	:	:	PUNCT
eurjchem-2037	385	25	printfield20	printfield20	PROPN
eurjchem-2037	385	26	:	:	PUNCT
eurjchem-2037	386	1	printfield21	printfield21	ADJ
eurjchem-2037	386	2	:	:	PUNCT
eurjchem-2037	386	3	printfield22	printfield22	NOUN
eurjchem-2037	386	4	:	:	PUNCT
eurjchem-2037	386	5	printfield23	printfield23	NOUN
eurjchem-2037	386	6	:	:	PUNCT
eurjchem-2037	386	7	printfield24	printfield24	NOUN
eurjchem-2037	386	8	:	:	PUNCT
eurjchem-2037	386	9	printfield25	printfield25	NOUN
eurjchem-2037	386	10	:	:	PUNCT
eurjchem-2037	386	11	printfield26	printfield26	ADJ
eurjchem-2037	386	12	:	:	PUNCT
eurjchem-2037	386	13	printfield27	printfield27	NOUN
eurjchem-2037	386	14	:	:	PUNCT