id	sid	tid	token	lemma	pos
eurjchem-2047	1	1	crystal	crystal	NOUN
eurjchem-2047	1	2	and	and	CCONJ
eurjchem-2047	1	3	molecular	molecular	ADJ
eurjchem-2047	1	4	structure	structure	NOUN
eurjchem-2047	1	5	of	of	ADP
eurjchem-2047	1	6	bis(n-(diethylcarbamothioyl)cyclohexane	bis(n-(diethylcarbamothioyl)cyclohexane	PROPN
eurjchem-2047	1	7	carboxamido)copper(ii	carboxamido)copper(ii	PROPN
eurjchem-2047	1	8	)	)	PUNCT
eurjchem-2047	1	9	complex	complex	ADJ
eurjchem-2047	1	10	european	european	ADJ
eurjchem-2047	1	11	journal	journal	NOUN
eurjchem-2047	1	12	of	of	ADP
eurjchem-2047	1	13	chemistry	chemistry	NOUN
eurjchem-2047	1	14	11	11	NUM
eurjchem-2047	1	15	(	(	PUNCT
eurjchem-2047	1	16	4	4	NUM
eurjchem-2047	1	17	)	)	PUNCT
eurjchem-2047	1	18	(	(	PUNCT
eurjchem-2047	1	19	2020	2020	NUM
eurjchem-2047	1	20	)	)	PUNCT
eurjchem-2047	1	21	319	319	NUM
eurjchem-2047	1	22	-	-	SYM
eurjchem-2047	1	23	323	323	NUM
eurjchem-2047	1	24	european	european	ADJ
eurjchem-2047	1	25	journal	journal	NOUN
eurjchem-2047	1	26	of	of	ADP
eurjchem-2047	1	27	chemistry	chemistry	NOUN
eurjchem-2047	1	28	issn	issn	VERB
eurjchem-2047	1	29	2153	2153	NUM
eurjchem-2047	1	30	-	-	SYM
eurjchem-2047	1	31	2249	2249	NUM
eurjchem-2047	1	32	(	(	PUNCT
eurjchem-2047	1	33	print	print	NOUN
eurjchem-2047	1	34	)	)	PUNCT
eurjchem-2047	1	35	/	/	PUNCT
eurjchem-2047	1	36	issn	issn	PROPN
eurjchem-2047	1	37	2153	2153	NUM
eurjchem-2047	1	38	-	-	SYM
eurjchem-2047	1	39	2257	2257	NUM
eurjchem-2047	1	40	(	(	PUNCT
eurjchem-2047	1	41	online	online	ADJ
eurjchem-2047	1	42	)	)	PUNCT
eurjchem-2047	1	43	–	–	PUNCT
eurjchem-2047	2	1	copyright	copyright	NOUN
eurjchem-2047	2	2	©	©	PROPN
eurjchem-2047	2	3	2020	2020	NUM
eurjchem-2047	2	4	the	the	DET
eurjchem-2047	2	5	authors	author	NOUN
eurjchem-2047	2	6	–	–	PUNCT
eurjchem-2047	2	7	atlanta	atlanta	PROPN
eurjchem-2047	2	8	publishing	publishing	PROPN
eurjchem-2047	2	9	house	house	PROPN
eurjchem-2047	2	10	llc	llc	PROPN
eurjchem-2047	2	11	–	–	PUNCT
eurjchem-2047	2	12	printed	print	VERB
eurjchem-2047	2	13	in	in	ADP
eurjchem-2047	2	14	the	the	DET
eurjchem-2047	2	15	usa	usa	PROPN
eurjchem-2047	2	16	.	.	PUNCT
eurjchem-2047	3	1	this	this	DET
eurjchem-2047	3	2	work	work	NOUN
eurjchem-2047	3	3	is	be	AUX
eurjchem-2047	3	4	published	publish	VERB
eurjchem-2047	3	5	and	and	CCONJ
eurjchem-2047	3	6	licensed	license	VERB
eurjchem-2047	3	7	by	by	ADP
eurjchem-2047	3	8	atlanta	atlanta	PROPN
eurjchem-2047	3	9	publishing	publishing	PROPN
eurjchem-2047	3	10	house	house	PROPN
eurjchem-2047	3	11	llc	llc	PROPN
eurjchem-2047	3	12	–	–	PUNCT
eurjchem-2047	3	13	cc	cc	PROPN
eurjchem-2047	3	14	by	by	ADP
eurjchem-2047	3	15	nc	nc	PROPN
eurjchem-2047	3	16	–	–	PUNCT
eurjchem-2047	3	17	some	some	DET
eurjchem-2047	3	18	rights	right	NOUN
eurjchem-2047	3	19	reserved	reserve	VERB
eurjchem-2047	3	20	.	.	PUNCT
eurjchem-2047	4	1	http://dx.doi.org/10.5155/eurjchem.11.4.319-323.2047	http://dx.doi.org/10.5155/eurjchem.11.4.319-323.2047	ADJ
eurjchem-2047	4	2	european	european	PROPN
eurjchem-2047	4	3	journal	journal	PROPN
eurjchem-2047	4	4	of	of	ADP
eurjchem-2047	4	5	chemistry	chemistry	NOUN
eurjchem-2047	4	6	view	view	NOUN
eurjchem-2047	4	7	journal	journal	PROPN
eurjchem-2047	4	8	online	online	PROPN
eurjchem-2047	4	9	view	view	NOUN
eurjchem-2047	4	10	article	article	NOUN
eurjchem-2047	4	11	online	online	PROPN
eurjchem-2047	4	12	crystal	crystal	PROPN
eurjchem-2047	4	13	and	and	CCONJ
eurjchem-2047	4	14	molecular	molecular	ADJ
eurjchem-2047	4	15	structure	structure	NOUN
eurjchem-2047	4	16	of	of	ADP
eurjchem-2047	4	17	bis(n-(diethylcarbamothioyl)cyclohexane	bis(n-(diethylcarbamothioyl)cyclohexane	PROPN
eurjchem-2047	4	18	carboxamido)copper(ii	carboxamido)copper(ii	PROPN
eurjchem-2047	4	19	)	)	PUNCT
eurjchem-2047	4	20	complex	complex	ADJ
eurjchem-2047	4	21	cemal	cemal	NOUN
eurjchem-2047	4	22	koray	koray	PROPN
eurjchem-2047	4	23	ozer	ozer	PROPN
eurjchem-2047	4	24	1	1	NUM
eurjchem-2047	4	25	,	,	PUNCT
eurjchem-2047	4	26	gun	gun	NOUN
eurjchem-2047	4	27	binzet	binzet	NOUN
eurjchem-2047	4	28	2	2	NUM
eurjchem-2047	4	29	,	,	PUNCT
eurjchem-2047	4	30	*	*	PUNCT
eurjchem-2047	4	31	and	and	CCONJ
eurjchem-2047	4	32	hakan	hakan	PROPN
eurjchem-2047	4	33	arslan	arslan	PROPN
eurjchem-2047	4	34	1	1	NUM
eurjchem-2047	4	35	1	1	NUM
eurjchem-2047	4	36	department	department	NOUN
eurjchem-2047	4	37	of	of	ADP
eurjchem-2047	4	38	chemistry	chemistry	NOUN
eurjchem-2047	4	39	,	,	PUNCT
eurjchem-2047	4	40	faculty	faculty	NOUN
eurjchem-2047	4	41	of	of	ADP
eurjchem-2047	4	42	arts	art	NOUN
eurjchem-2047	4	43	and	and	CCONJ
eurjchem-2047	4	44	science	science	PROPN
eurjchem-2047	4	45	,	,	PUNCT
eurjchem-2047	4	46	mersin	mersin	PROPN
eurjchem-2047	4	47	university	university	PROPN
eurjchem-2047	4	48	,	,	PUNCT
eurjchem-2047	4	49	mersin	mersin	PROPN
eurjchem-2047	4	50	,	,	PUNCT
eurjchem-2047	4	51	tr	tr	VERB
eurjchem-2047	4	52	33343	33343	NUM
eurjchem-2047	4	53	,	,	PUNCT
eurjchem-2047	4	54	turkey	turkey	PROPN
eurjchem-2047	4	55	c.korayozer@gmail.com	c.korayozer@gmail.com	PROPN
eurjchem-2047	5	1	(	(	PUNCT
eurjchem-2047	5	2	c.k.o	c.k.o	PROPN
eurjchem-2047	5	3	.	.	PROPN
eurjchem-2047	5	4	)	)	PUNCT
eurjchem-2047	5	5	,	,	PUNCT
eurjchem-2047	5	6	hakan.arslan@mersin.edu.tr	hakan.arslan@mersin.edu.tr	PROPN
eurjchem-2047	5	7	(	(	PUNCT
eurjchem-2047	5	8	h.a	h.a	PROPN
eurjchem-2047	5	9	.	.	PROPN
eurjchem-2047	5	10	)	)	PUNCT
eurjchem-2047	5	11	2	2	NUM
eurjchem-2047	5	12	department	department	NOUN
eurjchem-2047	5	13	of	of	ADP
eurjchem-2047	5	14	chemistry	chemistry	NOUN
eurjchem-2047	5	15	,	,	PUNCT
eurjchem-2047	5	16	faculty	faculty	NOUN
eurjchem-2047	5	17	of	of	ADP
eurjchem-2047	5	18	education	education	NOUN
eurjchem-2047	5	19	,	,	PUNCT
eurjchem-2047	5	20	mersin	mersin	PROPN
eurjchem-2047	5	21	university	university	PROPN
eurjchem-2047	5	22	,	,	PUNCT
eurjchem-2047	5	23	mersin	mersin	PROPN
eurjchem-2047	5	24	,	,	PUNCT
eurjchem-2047	5	25	tr-33343	tr-33343	PROPN
eurjchem-2047	5	26	,	,	PUNCT
eurjchem-2047	5	27	turkey	turkey	PROPN
eurjchem-2047	5	28	gunbinzet@mersin.edu.tr	gunbinzet@mersin.edu.tr	PROPN
eurjchem-2047	5	29	(	(	PUNCT
eurjchem-2047	5	30	g.b	g.b	PROPN
eurjchem-2047	5	31	.	.	PUNCT
eurjchem-2047	5	32	)	)	PUNCT
eurjchem-2047	6	1	*	*	PUNCT
eurjchem-2047	6	2	corresponding	correspond	VERB
eurjchem-2047	6	3	author	author	NOUN
eurjchem-2047	6	4	at	at	ADP
eurjchem-2047	6	5	:	:	PUNCT
eurjchem-2047	6	6	department	department	NOUN
eurjchem-2047	6	7	of	of	ADP
eurjchem-2047	6	8	chemistry	chemistry	NOUN
eurjchem-2047	6	9	,	,	PUNCT
eurjchem-2047	6	10	faculty	faculty	NOUN
eurjchem-2047	6	11	of	of	ADP
eurjchem-2047	6	12	education	education	NOUN
eurjchem-2047	6	13	,	,	PUNCT
eurjchem-2047	6	14	mersin	mersin	PROPN
eurjchem-2047	6	15	university	university	PROPN
eurjchem-2047	6	16	,	,	PUNCT
eurjchem-2047	6	17	mersin	mersin	PROPN
eurjchem-2047	6	18	,	,	PUNCT
eurjchem-2047	6	19	tr-33343	tr-33343	PROPN
eurjchem-2047	6	20	,	,	PUNCT
eurjchem-2047	6	21	turkey	turkey	NOUN
eurjchem-2047	6	22	.	.	PUNCT
eurjchem-2047	7	1	e	e	X
eurjchem-2047	7	2	-	-	NOUN
eurjchem-2047	7	3	mail	mail	NOUN
eurjchem-2047	7	4	:	:	PUNCT
eurjchem-2047	7	5	gunbinzet@mersin.edu.tr	gunbinzet@mersin.edu.tr	PROPN
eurjchem-2047	7	6	(	(	PUNCT
eurjchem-2047	7	7	g.	g.	PROPN
eurjchem-2047	7	8	binzet	binzet	PROPN
eurjchem-2047	7	9	)	)	PUNCT
eurjchem-2047	7	10	.	.	PUNCT
eurjchem-2047	8	1	10.5155	10.5155	NUM
eurjchem-2047	8	2	/	/	SYM
eurjchem-2047	8	3	eurjchem.11.4.319	eurjchem.11.4.319	PROPN
eurjchem-2047	8	4	-	-	PUNCT
eurjchem-2047	8	5	323.2047	323.2047	NUM
eurjchem-2047	8	6	received	receive	VERB
eurjchem-2047	8	7	:	:	PUNCT
eurjchem-2047	8	8	13	13	NUM
eurjchem-2047	8	9	october	october	PROPN
eurjchem-2047	8	10	2020	2020	NUM
eurjchem-2047	8	11	received	receive	VERB
eurjchem-2047	8	12	in	in	ADP
eurjchem-2047	8	13	revised	revise	VERB
eurjchem-2047	8	14	form	form	NOUN
eurjchem-2047	8	15	:	:	PUNCT
eurjchem-2047	8	16	05	05	NUM
eurjchem-2047	8	17	november	november	PROPN
eurjchem-2047	8	18	2020	2020	NUM
eurjchem-2047	8	19	accepted	accept	VERB
eurjchem-2047	8	20	:	:	PUNCT
eurjchem-2047	8	21	15	15	NUM
eurjchem-2047	8	22	november	november	PROPN
eurjchem-2047	8	23	2020	2020	NUM
eurjchem-2047	8	24	published	publish	VERB
eurjchem-2047	8	25	online	online	ADV
eurjchem-2047	8	26	:	:	PUNCT
eurjchem-2047	8	27	31	31	NUM
eurjchem-2047	8	28	december	december	PROPN
eurjchem-2047	8	29	2020	2020	NUM
eurjchem-2047	8	30	printed	print	VERB
eurjchem-2047	8	31	:	:	PUNCT
eurjchem-2047	8	32	31	31	NUM
eurjchem-2047	8	33	december	december	PROPN
eurjchem-2047	8	34	2020	2020	NUM
eurjchem-2047	8	35	herein	herein	NOUN
eurjchem-2047	8	36	,	,	PUNCT
eurjchem-2047	8	37	we	we	PRON
eurjchem-2047	8	38	describe	describe	VERB
eurjchem-2047	8	39	the	the	DET
eurjchem-2047	8	40	synthesis	synthesis	NOUN
eurjchem-2047	8	41	and	and	CCONJ
eurjchem-2047	8	42	characterization	characterization	NOUN
eurjchem-2047	8	43	of	of	ADP
eurjchem-2047	8	44	bis(n-(diethylcarbamothioyl)cyclohexane	bis(n-(diethylcarbamothioyl)cyclohexane	PROPN
eurjchem-2047	8	45	carboxamido)copper(ii	carboxamido)copper(ii	PROPN
eurjchem-2047	8	46	)	)	PUNCT
eurjchem-2047	8	47	complex	complex	ADJ
eurjchem-2047	8	48	,	,	PUNCT
eurjchem-2047	8	49	cis-[cu(l	cis-[cu(l	NUM
eurjchem-2047	8	50	-	-	PUNCT
eurjchem-2047	8	51	κ2s	κ2	NOUN
eurjchem-2047	8	52	,	,	PUNCT
eurjchem-2047	8	53	o)2	o)2	PROPN
eurjchem-2047	8	54	]	]	PUNCT
eurjchem-2047	8	55	,	,	PUNCT
eurjchem-2047	8	56	has	have	AUX
eurjchem-2047	8	57	been	be	AUX
eurjchem-2047	8	58	prepared	prepare	VERB
eurjchem-2047	8	59	by	by	ADP
eurjchem-2047	8	60	the	the	DET
eurjchem-2047	8	61	reaction	reaction	NOUN
eurjchem-2047	8	62	of	of	ADP
eurjchem-2047	8	63	n-(diethyl	n-(diethyl	PROPN
eurjchem-2047	8	64	carbamothioyl)cyclohexanecarboxamide	carbamothioyl)cyclohexanecarboxamide	PROPN
eurjchem-2047	8	65	ligand	ligand	NOUN
eurjchem-2047	8	66	with	with	ADP
eurjchem-2047	8	67	copper(ii	copper(ii	NOUN
eurjchem-2047	8	68	)	)	PUNCT
eurjchem-2047	8	69	acetate	acetate	NOUN
eurjchem-2047	8	70	.	.	PUNCT
eurjchem-2047	9	1	the	the	DET
eurjchem-2047	9	2	green	green	ADJ
eurjchem-2047	9	3	colored	colored	ADJ
eurjchem-2047	9	4	crystals	crystal	NOUN
eurjchem-2047	9	5	of	of	ADP
eurjchem-2047	9	6	the	the	DET
eurjchem-2047	9	7	complex	complex	NOUN
eurjchem-2047	9	8	were	be	AUX
eurjchem-2047	9	9	obtained	obtain	VERB
eurjchem-2047	9	10	by	by	ADP
eurjchem-2047	9	11	slow	slow	ADJ
eurjchem-2047	9	12	evaporation	evaporation	NOUN
eurjchem-2047	9	13	of	of	ADP
eurjchem-2047	9	14	their	their	PRON
eurjchem-2047	9	15	dichloromethane	dichloromethane	NOUN
eurjchem-2047	9	16	:	:	PUNCT
eurjchem-2047	9	17	ethanol	ethanol	NOUN
eurjchem-2047	9	18	solution	solution	NOUN
eurjchem-2047	9	19	(	(	PUNCT
eurjchem-2047	9	20	2:1	2:1	NUM
eurjchem-2047	9	21	,	,	PUNCT
eurjchem-2047	9	22	v	v	NOUN
eurjchem-2047	9	23	:	:	PUNCT
eurjchem-2047	9	24	v	v	NOUN
eurjchem-2047	9	25	)	)	PUNCT
eurjchem-2047	9	26	.	.	PUNCT
eurjchem-2047	10	1	the	the	DET
eurjchem-2047	10	2	crystal	crystal	NOUN
eurjchem-2047	10	3	structure	structure	NOUN
eurjchem-2047	10	4	of	of	ADP
eurjchem-2047	10	5	cis-[cu(l	cis-[cu(l	NOUN
eurjchem-2047	10	6	-	-	PUNCT
eurjchem-2047	10	7	κ2s	κ2	NOUN
eurjchem-2047	10	8	,	,	PUNCT
eurjchem-2047	10	9	o)2	o)2	PROPN
eurjchem-2047	10	10	]	]	PUNCT
eurjchem-2047	10	11	was	be	AUX
eurjchem-2047	10	12	obtained	obtain	VERB
eurjchem-2047	10	13	by	by	ADP
eurjchem-2047	10	14	single	single	ADJ
eurjchem-2047	10	15	-	-	PUNCT
eurjchem-2047	10	16	crystal	crystal	NOUN
eurjchem-2047	10	17	x	x	ADJ
eurjchem-2047	10	18	-	-	NOUN
eurjchem-2047	10	19	ray	ray	NOUN
eurjchem-2047	10	20	diffraction	diffraction	NOUN
eurjchem-2047	10	21	.	.	PUNCT
eurjchem-2047	11	1	the	the	DET
eurjchem-2047	11	2	crystal	crystal	NOUN
eurjchem-2047	11	3	structure	structure	NOUN
eurjchem-2047	11	4	reveals	reveal	VERB
eurjchem-2047	11	5	an	an	DET
eurjchem-2047	11	6	monoclinic	monoclinic	ADJ
eurjchem-2047	11	7	c2	c2	PROPN
eurjchem-2047	11	8	(	(	PUNCT
eurjchem-2047	11	9	no	no	INTJ
eurjchem-2047	11	10	.	.	NOUN
eurjchem-2047	11	11	5	5	NUM
eurjchem-2047	11	12	)	)	PUNCT
eurjchem-2047	11	13	space	space	NOUN
eurjchem-2047	11	14	group	group	NOUN
eurjchem-2047	11	15	with	with	ADP
eurjchem-2047	11	16	cell	cell	NOUN
eurjchem-2047	11	17	parameters	parameter	NOUN
eurjchem-2047	11	18	a	a	DET
eurjchem-2047	11	19	=	=	SYM
eurjchem-2047	11	20	14.848(3	14.848(3	PROPN
eurjchem-2047	11	21	)	)	PUNCT
eurjchem-2047	11	22	å	å	PROPN
eurjchem-2047	11	23	,	,	PUNCT
eurjchem-2047	11	24	b	b	X
eurjchem-2047	11	25	=	=	SYM
eurjchem-2047	11	26	10.543(2	10.543(2	PROPN
eurjchem-2047	11	27	)	)	PUNCT
eurjchem-2047	11	28	å	å	PROPN
eurjchem-2047	11	29	,	,	PUNCT
eurjchem-2047	11	30	c	c	NOUN
eurjchem-2047	11	31	=	=	SYM
eurjchem-2047	11	32	10.511(2	10.511(2	NUM
eurjchem-2047	11	33	)	)	PUNCT
eurjchem-2047	11	34	å	å	NOUN
eurjchem-2047	11	35	,	,	PUNCT
eurjchem-2047	11	36	β	β	X
eurjchem-2047	11	37	=	=	SYM
eurjchem-2047	11	38	123.84(3	123.84(3	NUM
eurjchem-2047	11	39	)	)	PUNCT
eurjchem-2047	11	40	°	°	NOUN
eurjchem-2047	11	41	,	,	PUNCT
eurjchem-2047	11	42	v	v	NOUN
eurjchem-2047	11	43	=	=	SYM
eurjchem-2047	11	44	1366.7(7	1366.7(7	NOUN
eurjchem-2047	11	45	)	)	PUNCT
eurjchem-2047	11	46	å3	å3	PROPN
eurjchem-2047	11	47	,	,	PUNCT
eurjchem-2047	11	48	z	z	NOUN
eurjchem-2047	11	49	=	=	SYM
eurjchem-2047	11	50	2	2	NUM
eurjchem-2047	11	51	,	,	PUNCT
eurjchem-2047	11	52	t	t	NOUN
eurjchem-2047	11	53	=	=	SYM
eurjchem-2047	11	54	153(2	153(2	NUM
eurjchem-2047	11	55	)	)	PUNCT
eurjchem-2047	11	56	k	k	NOUN
eurjchem-2047	11	57	,	,	PUNCT
eurjchem-2047	11	58	μ(mokα	μ(mokα	NOUN
eurjchem-2047	11	59	)	)	PUNCT
eurjchem-2047	11	60	=	=	SYM
eurjchem-2047	11	61	0.979	0.979	NUM
eurjchem-2047	11	62	mm-1	mm-1	NOUN
eurjchem-2047	11	63	,	,	PUNCT
eurjchem-2047	11	64	dcalc	dcalc	NOUN
eurjchem-2047	11	65	=	=	NOUN
eurjchem-2047	11	66	1.327	1.327	NUM
eurjchem-2047	11	67	g	g	NOUN
eurjchem-2047	11	68	/	/	SYM
eurjchem-2047	11	69	cm3	cm3	NOUN
eurjchem-2047	11	70	,	,	PUNCT
eurjchem-2047	11	71	4979	4979	NUM
eurjchem-2047	11	72	reflections	reflection	NOUN
eurjchem-2047	11	73	measured	measure	VERB
eurjchem-2047	11	74	(	(	PUNCT
eurjchem-2047	11	75	6.6	6.6	NUM
eurjchem-2047	11	76	°	°	NOUN
eurjchem-2047	11	77	≤	≤	NUM
eurjchem-2047	11	78	2θ	2θ	NUM
eurjchem-2047	11	79	≤	≤	NUM
eurjchem-2047	11	80	50.68	50.68	NUM
eurjchem-2047	11	81	°	°	NOUN
eurjchem-2047	11	82	)	)	PUNCT
eurjchem-2047	11	83	,	,	PUNCT
eurjchem-2047	11	84	2243	2243	NUM
eurjchem-2047	11	85	unique	unique	ADJ
eurjchem-2047	11	86	(	(	PUNCT
eurjchem-2047	11	87	rint	rint	NOUN
eurjchem-2047	11	88	=	=	SYM
eurjchem-2047	11	89	0.0223	0.0223	NUM
eurjchem-2047	11	90	,	,	PUNCT
eurjchem-2047	11	91	rsigma	rsigma	ADJ
eurjchem-2047	11	92	=	=	SYM
eurjchem-2047	11	93	0.0444	0.0444	NUM
eurjchem-2047	11	94	)	)	PUNCT
eurjchem-2047	11	95	which	which	PRON
eurjchem-2047	11	96	were	be	AUX
eurjchem-2047	11	97	used	use	VERB
eurjchem-2047	11	98	in	in	ADP
eurjchem-2047	11	99	all	all	DET
eurjchem-2047	11	100	calculations	calculation	NOUN
eurjchem-2047	11	101	.	.	PUNCT
eurjchem-2047	12	1	the	the	DET
eurjchem-2047	12	2	final	final	ADJ
eurjchem-2047	12	3	r1	r1	NOUN
eurjchem-2047	12	4	was	be	AUX
eurjchem-2047	12	5	0.0225	0.0225	NUM
eurjchem-2047	12	6	(	(	PUNCT
eurjchem-2047	12	7	>	>	X
eurjchem-2047	12	8	2sigma(i	2sigma(i	NUM
eurjchem-2047	12	9	)	)	PUNCT
eurjchem-2047	12	10	)	)	PUNCT
eurjchem-2047	13	1	and	and	CCONJ
eurjchem-2047	13	2	wr2	wr2	PROPN
eurjchem-2047	13	3	was	be	AUX
eurjchem-2047	13	4	0.0490	0.0490	NUM
eurjchem-2047	13	5	(	(	PUNCT
eurjchem-2047	13	6	all	all	DET
eurjchem-2047	13	7	data	datum	NOUN
eurjchem-2047	13	8	)	)	PUNCT
eurjchem-2047	13	9	.	.	PUNCT
eurjchem-2047	14	1	the	the	DET
eurjchem-2047	14	2	angular	angular	ADJ
eurjchem-2047	14	3	structural	structural	ADJ
eurjchem-2047	14	4	index	index	NOUN
eurjchem-2047	14	5	parameter	parameter	NOUN
eurjchem-2047	14	6	,	,	PUNCT
eurjchem-2047	14	7	τ4	τ4	PROPN
eurjchem-2047	14	8	,	,	PUNCT
eurjchem-2047	14	9	is	be	AUX
eurjchem-2047	14	10	equal	equal	ADJ
eurjchem-2047	14	11	to	to	ADP
eurjchem-2047	14	12	0.40	0.40	NUM
eurjchem-2047	14	13	,	,	PUNCT
eurjchem-2047	14	14	which	which	PRON
eurjchem-2047	14	15	confirms	confirm	VERB
eurjchem-2047	14	16	the	the	DET
eurjchem-2047	14	17	distorted	distorted	ADJ
eurjchem-2047	14	18	square	square	ADJ
eurjchem-2047	14	19	planar	planar	ADJ
eurjchem-2047	14	20	geometry	geometry	NOUN
eurjchem-2047	14	21	for	for	ADP
eurjchem-2047	14	22	the	the	DET
eurjchem-2047	14	23	title	title	NOUN
eurjchem-2047	14	24	compound	compound	NOUN
eurjchem-2047	14	25	.	.	PUNCT
eurjchem-2047	15	1	the	the	DET
eurjchem-2047	15	2	puckering	pucker	VERB
eurjchem-2047	15	3	parameters	parameter	NOUN
eurjchem-2047	15	4	(	(	PUNCT
eurjchem-2047	15	5	q2	q2	NOUN
eurjchem-2047	15	6	=	=	SYM
eurjchem-2047	15	7	0.015(3	0.015(3	PROPN
eurjchem-2047	15	8	)	)	PUNCT
eurjchem-2047	15	9	å	å	PROPN
eurjchem-2047	15	10	,	,	PUNCT
eurjchem-2047	15	11	q3	q3	NOUN
eurjchem-2047	15	12	=	=	PUNCT
eurjchem-2047	15	13	0.576(3	0.576(3	NUM
eurjchem-2047	15	14	)	)	PUNCT
eurjchem-2047	15	15	å	å	NOUN
eurjchem-2047	15	16	,	,	PUNCT
eurjchem-2047	15	17	qt	qt	NOUN
eurjchem-2047	15	18	=	=	SYM
eurjchem-2047	15	19	0.577(3	0.577(3	NOUN
eurjchem-2047	15	20	)	)	PUNCT
eurjchem-2047	15	21	å	å	NOUN
eurjchem-2047	15	22	,	,	PUNCT
eurjchem-2047	15	23	θ	θ	PROPN
eurjchem-2047	15	24	=	=	SYM
eurjchem-2047	15	25	1.6(3	1.6(3	NUM
eurjchem-2047	15	26	)	)	PUNCT
eurjchem-2047	15	27	°	°	PROPN
eurjchem-2047	15	28	and	and	CCONJ
eurjchem-2047	15	29	φ	φ	NUM
eurjchem-2047	15	30	=	=	SYM
eurjchem-2047	15	31	20(11	20(11	NUM
eurjchem-2047	15	32	)	)	PUNCT
eurjchem-2047	15	33	°	°	NOUN
eurjchem-2047	15	34	)	)	PUNCT
eurjchem-2047	15	35	of	of	ADP
eurjchem-2047	15	36	the	the	DET
eurjchem-2047	15	37	title	title	NOUN
eurjchem-2047	15	38	complex	complex	NOUN
eurjchem-2047	15	39	show	show	VERB
eurjchem-2047	15	40	that	that	SCONJ
eurjchem-2047	15	41	the	the	DET
eurjchem-2047	15	42	cyclohexane	cyclohexane	NOUN
eurjchem-2047	15	43	ring	ring	NOUN
eurjchem-2047	15	44	adopts	adopt	VERB
eurjchem-2047	15	45	a	a	DET
eurjchem-2047	15	46	chair	chair	NOUN
eurjchem-2047	15	47	conformation	conformation	NOUN
eurjchem-2047	15	48	.	.	PUNCT
eurjchem-2047	16	1	the	the	DET
eurjchem-2047	16	2	two	two	NUM
eurjchem-2047	16	3	ethyl	ethyl	PROPN
eurjchem-2047	16	4	groups	group	NOUN
eurjchem-2047	16	5	of	of	ADP
eurjchem-2047	16	6	the	the	DET
eurjchem-2047	16	7	diethyl	diethyl	NOUN
eurjchem-2047	16	8	amine	amine	ADJ
eurjchem-2047	16	9	group	group	NOUN
eurjchem-2047	16	10	have	have	VERB
eurjchem-2047	16	11	anti	anti	ADJ
eurjchem-2047	16	12	-	-	NOUN
eurjchem-2047	16	13	orientation	orientation	NOUN
eurjchem-2047	16	14	with	with	ADP
eurjchem-2047	16	15	respect	respect	NOUN
eurjchem-2047	16	16	to	to	ADP
eurjchem-2047	16	17	one	one	NUM
eurjchem-2047	16	18	another	another	DET
eurjchem-2047	16	19	.	.	PUNCT
eurjchem-2047	17	1	the	the	DET
eurjchem-2047	17	2	crystal	crystal	NOUN
eurjchem-2047	17	3	packing	packing	NOUN
eurjchem-2047	17	4	shows	show	VERB
eurjchem-2047	17	5	the	the	DET
eurjchem-2047	17	6	molecules	molecule	NOUN
eurjchem-2047	17	7	stacked	stack	VERB
eurjchem-2047	17	8	in	in	ADP
eurjchem-2047	17	9	parallel	parallel	ADJ
eurjchem-2047	17	10	sheets	sheet	NOUN
eurjchem-2047	17	11	along	along	ADP
eurjchem-2047	17	12	[	[	X
eurjchem-2047	17	13	010	010	NUM
eurjchem-2047	17	14	]	]	PUNCT
eurjchem-2047	17	15	,	,	PUNCT
eurjchem-2047	17	16	accompanied	accompany	VERB
eurjchem-2047	17	17	by	by	ADP
eurjchem-2047	17	18	c3	c3	PROPN
eurjchem-2047	17	19	-	-	PROPN
eurjchem-2047	17	20	h3a···o1ⁱ	h3a···o1ⁱ	PROPN
eurjchem-2047	17	21	(	(	PUNCT
eurjchem-2047	17	22	i	i	NOUN
eurjchem-2047	17	23	-x	-x	PROPN
eurjchem-2047	17	24	,	,	PUNCT
eurjchem-2047	17	25	+	+	NOUN
eurjchem-2047	17	26	y	y	PROPN
eurjchem-2047	17	27	,	,	PUNCT
eurjchem-2047	17	28	1	1	NUM
eurjchem-2047	17	29	-	-	PUNCT
eurjchem-2047	17	30	z	z	NOUN
eurjchem-2047	17	31	)	)	PUNCT
eurjchem-2047	17	32	intermolecular	intermolecular	ADJ
eurjchem-2047	17	33	contact	contact	NOUN
eurjchem-2047	17	34	.	.	PUNCT
eurjchem-2047	18	1	thiourea	thiourea	NOUN
eurjchem-2047	18	2	copper	copper	PROPN
eurjchem-2047	18	3	complex	complex	PROPN
eurjchem-2047	18	4	crystal	crystal	NOUN
eurjchem-2047	18	5	structure	structure	NOUN
eurjchem-2047	18	6	chair	chair	NOUN
eurjchem-2047	18	7	conformation	conformation	PROPN
eurjchem-2047	18	8	single	single	ADJ
eurjchem-2047	18	9	crystal	crystal	NOUN
eurjchem-2047	18	10	x	x	PROPN
eurjchem-2047	18	11	-	-	NOUN
eurjchem-2047	18	12	ray	ray	NOUN
eurjchem-2047	18	13	diffraction	diffraction	NOUN
eurjchem-2047	18	14	distorted	distort	VERB
eurjchem-2047	18	15	square	square	ADJ
eurjchem-2047	18	16	planar	planar	ADJ
eurjchem-2047	18	17	geometry	geometry	NOUN
eurjchem-2047	18	18	cite	cite	VERB
eurjchem-2047	18	19	this	this	PRON
eurjchem-2047	18	20	:	:	PUNCT
eurjchem-2047	19	1	eur	eur	PROPN
eurjchem-2047	19	2	.	.	PUNCT
eurjchem-2047	20	1	j.	j.	PROPN
eurjchem-2047	20	2	chem	chem	PROPN
eurjchem-2047	20	3	.	.	PUNCT
eurjchem-2047	21	1	2020	2020	NUM
eurjchem-2047	21	2	,	,	PUNCT
eurjchem-2047	21	3	11(4	11(4	NUM
eurjchem-2047	21	4	)	)	PUNCT
eurjchem-2047	21	5	,	,	PUNCT
eurjchem-2047	21	6	319	319	NUM
eurjchem-2047	21	7	-	-	SYM
eurjchem-2047	21	8	323	323	NUM
eurjchem-2047	21	9	journal	journal	NOUN
eurjchem-2047	21	10	website	website	NOUN
eurjchem-2047	21	11	:	:	PUNCT
eurjchem-2047	21	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2047	21	13	1	1	X
eurjchem-2047	21	14	.	.	PUNCT
eurjchem-2047	21	15	introduction	introduction	NOUN
eurjchem-2047	21	16	thiourea	thiourea	NOUN
eurjchem-2047	21	17	derivative	derivative	ADJ
eurjchem-2047	21	18	compounds	compound	NOUN
eurjchem-2047	21	19	have	have	VERB
eurjchem-2047	21	20	a	a	DET
eurjchem-2047	21	21	long	long	ADJ
eurjchem-2047	21	22	history	history	NOUN
eurjchem-2047	21	23	as	as	ADP
eurjchem-2047	21	24	ligands	ligand	NOUN
eurjchem-2047	21	25	in	in	ADP
eurjchem-2047	21	26	coordination	coordination	NOUN
eurjchem-2047	21	27	chemistry	chemistry	NOUN
eurjchem-2047	21	28	due	due	ADP
eurjchem-2047	21	29	to	to	ADP
eurjchem-2047	21	30	their	their	PRON
eurjchem-2047	21	31	ease	ease	NOUN
eurjchem-2047	21	32	of	of	ADP
eurjchem-2047	21	33	synthesis	synthesis	NOUN
eurjchem-2047	21	34	,	,	PUNCT
eurjchem-2047	21	35	variability	variability	NOUN
eurjchem-2047	21	36	in	in	ADP
eurjchem-2047	21	37	structural	structural	ADJ
eurjchem-2047	21	38	design	design	NOUN
eurjchem-2047	21	39	,	,	PUNCT
eurjchem-2047	21	40	and	and	CCONJ
eurjchem-2047	21	41	wide	wide	ADJ
eurjchem-2047	21	42	range	range	NOUN
eurjchem-2047	21	43	of	of	ADP
eurjchem-2047	21	44	applications	application	NOUN
eurjchem-2047	21	45	.	.	PUNCT
eurjchem-2047	22	1	the	the	DET
eurjchem-2047	22	2	nitrogen	nitrogen	NOUN
eurjchem-2047	22	3	,	,	PUNCT
eurjchem-2047	22	4	oxygen	oxygen	NOUN
eurjchem-2047	22	5	,	,	PUNCT
eurjchem-2047	22	6	and	and	CCONJ
eurjchem-2047	22	7	sulfur	sulfur	NOUN
eurjchem-2047	22	8	donor	donor	NOUN
eurjchem-2047	22	9	atoms	atom	NOUN
eurjchem-2047	22	10	of	of	ADP
eurjchem-2047	22	11	thiourea	thiourea	NOUN
eurjchem-2047	22	12	derivatives	derivative	NOUN
eurjchem-2047	22	13	provide	provide	VERB
eurjchem-2047	22	14	a	a	DET
eurjchem-2047	22	15	multitude	multitude	NOUN
eurjchem-2047	22	16	of	of	ADP
eurjchem-2047	22	17	bonding	bonding	NOUN
eurjchem-2047	22	18	possibilities	possibility	NOUN
eurjchem-2047	22	19	[	[	X
eurjchem-2047	22	20	1	1	NUM
eurjchem-2047	22	21	-	-	SYM
eurjchem-2047	22	22	6	6	NUM
eurjchem-2047	22	23	]	]	PUNCT
eurjchem-2047	22	24	.	.	PUNCT
eurjchem-2047	23	1	the	the	DET
eurjchem-2047	23	2	thiourea	thiourea	NOUN
eurjchem-2047	23	3	derivatives	derivative	NOUN
eurjchem-2047	23	4	are	be	AUX
eurjchem-2047	23	5	able	able	ADJ
eurjchem-2047	23	6	to	to	PART
eurjchem-2047	23	7	coordinate	coordinate	VERB
eurjchem-2047	23	8	to	to	ADP
eurjchem-2047	23	9	a	a	DET
eurjchem-2047	23	10	range	range	NOUN
eurjchem-2047	23	11	of	of	ADP
eurjchem-2047	23	12	metal	metal	NOUN
eurjchem-2047	23	13	centers	center	NOUN
eurjchem-2047	23	14	as	as	ADP
eurjchem-2047	23	15	neutral	neutral	ADJ
eurjchem-2047	23	16	ligands	ligand	NOUN
eurjchem-2047	23	17	,	,	PUNCT
eurjchem-2047	23	18	monoanions	monoanion	NOUN
eurjchem-2047	23	19	,	,	PUNCT
eurjchem-2047	23	20	or	or	CCONJ
eurjchem-2047	23	21	dianions	dianion	NOUN
eurjchem-2047	23	22	.	.	PUNCT
eurjchem-2047	24	1	both	both	CCONJ
eurjchem-2047	24	2	the	the	DET
eurjchem-2047	24	3	ligands	ligand	NOUN
eurjchem-2047	24	4	and	and	CCONJ
eurjchem-2047	24	5	their	their	PRON
eurjchem-2047	24	6	metal	metal	NOUN
eurjchem-2047	24	7	complexes	complex	NOUN
eurjchem-2047	24	8	display	display	VERB
eurjchem-2047	24	9	a	a	DET
eurjchem-2047	24	10	wide	wide	ADJ
eurjchem-2047	24	11	range	range	NOUN
eurjchem-2047	24	12	of	of	ADP
eurjchem-2047	24	13	biological	biological	ADJ
eurjchem-2047	24	14	activity	activity	NOUN
eurjchem-2047	24	15	including	include	VERB
eurjchem-2047	24	16	antibacterial	antibacterial	ADJ
eurjchem-2047	24	17	[	[	X
eurjchem-2047	24	18	7	7	NUM
eurjchem-2047	24	19	-	-	SYM
eurjchem-2047	24	20	12	12	NUM
eurjchem-2047	24	21	]	]	PUNCT
eurjchem-2047	24	22	,	,	PUNCT
eurjchem-2047	24	23	antifungal	antifungal	PROPN
eurjchem-2047	25	1	[	[	X
eurjchem-2047	25	2	1319	1319	NUM
eurjchem-2047	25	3	]	]	PUNCT
eurjchem-2047	25	4	,	,	PUNCT
eurjchem-2047	25	5	antitumor	antitumor	PROPN
eurjchem-2047	25	6	[	[	PUNCT
eurjchem-2047	25	7	20	20	NUM
eurjchem-2047	25	8	-	-	SYM
eurjchem-2047	25	9	24	24	NUM
eurjchem-2047	25	10	]	]	PUNCT
eurjchem-2047	25	11	,	,	PUNCT
eurjchem-2047	25	12	antiviral	antiviral	NOUN
eurjchem-2047	25	13	[	[	X
eurjchem-2047	25	14	25	25	NUM
eurjchem-2047	25	15	]	]	PUNCT
eurjchem-2047	25	16	antithyroid	antithyroid	NOUN
eurjchem-2047	26	1	[	[	X
eurjchem-2047	26	2	26	26	NUM
eurjchem-2047	26	3	,	,	PUNCT
eurjchem-2047	26	4	27	27	NUM
eurjchem-2047	26	5	]	]	PUNCT
eurjchem-2047	26	6	,	,	PUNCT
eurjchem-2047	26	7	anthelmintic	anthelmintic	ADJ
eurjchem-2047	26	8	[	[	X
eurjchem-2047	26	9	28	28	NUM
eurjchem-2047	26	10	]	]	PUNCT
eurjchem-2047	26	11	,	,	PUNCT
eurjchem-2047	26	12	rodenticidal	rodenticidal	ADJ
eurjchem-2047	26	13	[	[	X
eurjchem-2047	26	14	29	29	NUM
eurjchem-2047	26	15	]	]	PUNCT
eurjchem-2047	26	16	,	,	PUNCT
eurjchem-2047	26	17	insecticidal	insecticidal	NOUN
eurjchem-2047	26	18	[	[	X
eurjchem-2047	26	19	30	30	NUM
eurjchem-2047	26	20	]	]	PUNCT
eurjchem-2047	26	21	,	,	PUNCT
eurjchem-2047	26	22	herbicidal	herbicidal	NOUN
eurjchem-2047	26	23	[	[	X
eurjchem-2047	26	24	31	31	NUM
eurjchem-2047	26	25	]	]	PUNCT
eurjchem-2047	26	26	,	,	PUNCT
eurjchem-2047	26	27	anti	anti	ADJ
eurjchem-2047	26	28	-	-	ADJ
eurjchem-2047	26	29	parasitic	parasitic	ADJ
eurjchem-2047	26	30	[	[	X
eurjchem-2047	26	31	32	32	NUM
eurjchem-2047	26	32	]	]	PUNCT
eurjchem-2047	26	33	,	,	PUNCT
eurjchem-2047	26	34	antileishmanial	antileishmanial	ADJ
eurjchem-2047	26	35	[	[	X
eurjchem-2047	26	36	24	24	NUM
eurjchem-2047	26	37	]	]	PUNCT
eurjchem-2047	26	38	,	,	PUNCT
eurjchem-2047	26	39	antioxidant	antioxidant	ADJ
eurjchem-2047	26	40	[	[	X
eurjchem-2047	26	41	33	33	NUM
eurjchem-2047	26	42	]	]	PUNCT
eurjchem-2047	26	43	and	and	CCONJ
eurjchem-2047	26	44	plant	plant	NOUN
eurjchem-2047	26	45	-	-	PUNCT
eurjchem-2047	26	46	growth	growth	NOUN
eurjchem-2047	26	47	regulator	regulator	NOUN
eurjchem-2047	26	48	[	[	X
eurjchem-2047	26	49	34	34	NUM
eurjchem-2047	26	50	]	]	PUNCT
eurjchem-2047	26	51	properties	property	NOUN
eurjchem-2047	26	52	.	.	PUNCT
eurjchem-2047	27	1	additionally	additionally	ADV
eurjchem-2047	27	2	,	,	PUNCT
eurjchem-2047	27	3	especially	especially	ADV
eurjchem-2047	27	4	benzoyl	benzoyl	ADJ
eurjchem-2047	27	5	thiourea	thiourea	NOUN
eurjchem-2047	27	6	derivatives	derivative	NOUN
eurjchem-2047	27	7	possess	possess	VERB
eurjchem-2047	27	8	wide	wide	ADJ
eurjchem-2047	27	9	applications	application	NOUN
eurjchem-2047	27	10	in	in	ADP
eurjchem-2047	27	11	several	several	ADJ
eurjchem-2047	27	12	areas	area	NOUN
eurjchem-2047	27	13	of	of	ADP
eurjchem-2047	27	14	life	life	NOUN
eurjchem-2047	27	15	sciences	science	NOUN
eurjchem-2047	27	16	as	as	ADP
eurjchem-2047	27	17	catalysts	catalyst	NOUN
eurjchem-2047	27	18	[	[	X
eurjchem-2047	27	19	35	35	NUM
eurjchem-2047	27	20	-	-	SYM
eurjchem-2047	27	21	39	39	NUM
eurjchem-2047	27	22	]	]	PUNCT
eurjchem-2047	27	23	,	,	PUNCT
eurjchem-2047	27	24	fluorescent	fluorescent	ADJ
eurjchem-2047	27	25	sensor	sensor	NOUN
eurjchem-2047	27	26	[	[	X
eurjchem-2047	27	27	40,41	40,41	NOUN
eurjchem-2047	27	28	]	]	X
eurjchem-2047	27	29	,	,	PUNCT
eurjchem-2047	27	30	anion	anion	NOUN
eurjchem-2047	27	31	selective	selective	ADJ
eurjchem-2047	27	32	sensors	sensor	NOUN
eurjchem-2047	27	33	[	[	X
eurjchem-2047	27	34	42	42	NUM
eurjchem-2047	27	35	-	-	SYM
eurjchem-2047	27	36	46	46	NUM
eurjchem-2047	27	37	]	]	PUNCT
eurjchem-2047	27	38	liquid	liquid	NOUN
eurjchem-2047	27	39	-	-	PUNCT
eurjchem-2047	27	40	liquid	liquid	NOUN
eurjchem-2047	27	41	extraction	extraction	NOUN
eurjchem-2047	27	42	[	[	X
eurjchem-2047	27	43	47,48	47,48	NOUN
eurjchem-2047	27	44	]	]	PUNCT
eurjchem-2047	27	45	,	,	PUNCT
eurjchem-2047	27	46	preconcentration	preconcentration	NOUN
eurjchem-2047	27	47	[	[	X
eurjchem-2047	27	48	49	49	NUM
eurjchem-2047	27	49	-	-	SYM
eurjchem-2047	27	50	51	51	NUM
eurjchem-2047	27	51	]	]	PUNCT
eurjchem-2047	27	52	and	and	CCONJ
eurjchem-2047	27	53	highly	highly	ADV
eurjchem-2047	27	54	efficient	efficient	ADJ
eurjchem-2047	27	55	chromatographic	chromatographic	ADJ
eurjchem-2047	27	56	separation	separation	NOUN
eurjchem-2047	27	57	[	[	X
eurjchem-2047	27	58	52,53	52,53	NOUN
eurjchem-2047	27	59	]	]	PUNCT
eurjchem-2047	27	60	.	.	PUNCT
eurjchem-2047	28	1	our	our	PRON
eurjchem-2047	28	2	research	research	NOUN
eurjchem-2047	28	3	group	group	NOUN
eurjchem-2047	28	4	is	be	AUX
eurjchem-2047	28	5	interested	interested	ADJ
eurjchem-2047	28	6	in	in	ADP
eurjchem-2047	28	7	the	the	DET
eurjchem-2047	28	8	synthesis	synthesis	NOUN
eurjchem-2047	28	9	,	,	PUNCT
eurjchem-2047	28	10	characterization	characterization	NOUN
eurjchem-2047	28	11	,	,	PUNCT
eurjchem-2047	28	12	crystal	crystal	NOUN
eurjchem-2047	28	13	structure	structure	NOUN
eurjchem-2047	28	14	,	,	PUNCT
eurjchem-2047	28	15	biological	biological	ADJ
eurjchem-2047	28	16	applications	application	NOUN
eurjchem-2047	28	17	,	,	PUNCT
eurjchem-2047	28	18	and	and	CCONJ
eurjchem-2047	28	19	coordination	coordination	NOUN
eurjchem-2047	28	20	chemistry	chemistry	NOUN
eurjchem-2047	28	21	of	of	ADP
eurjchem-2047	28	22	novel	novel	ADJ
eurjchem-2047	28	23	thiourea	thiourea	NOUN
eurjchem-2047	28	24	derivative	derivative	ADJ
eurjchem-2047	28	25	compounds	compound	NOUN
eurjchem-2047	29	1	[	[	X
eurjchem-2047	29	2	7,8,54	7,8,54	NUM
eurjchem-2047	29	3	-	-	SYM
eurjchem-2047	29	4	62	62	NUM
eurjchem-2047	29	5	]	]	PUNCT
eurjchem-2047	29	6	.	.	PUNCT
eurjchem-2047	30	1	as	as	ADP
eurjchem-2047	30	2	a	a	DET
eurjchem-2047	30	3	part	part	NOUN
eurjchem-2047	30	4	of	of	ADP
eurjchem-2047	30	5	our	our	PRON
eurjchem-2047	30	6	ongoing	ongoing	ADJ
eurjchem-2047	30	7	studies	study	NOUN
eurjchem-2047	30	8	into	into	ADP
eurjchem-2047	30	9	the	the	DET
eurjchem-2047	30	10	structure	structure	NOUN
eurjchem-2047	30	11	and	and	CCONJ
eurjchem-2047	30	12	utility	utility	NOUN
eurjchem-2047	30	13	of	of	ADP
eurjchem-2047	30	14	oxygen	oxygen	NOUN
eurjchem-2047	30	15	and	and	CCONJ
eurjchem-2047	30	16	sulfur	sulfur	NOUN
eurjchem-2047	30	17	containing	contain	VERB
eurjchem-2047	30	18	thiourea	thiourea	NOUN
eurjchem-2047	30	19	derivatives	derivative	NOUN
eurjchem-2047	30	20	,	,	PUNCT
eurjchem-2047	30	21	we	we	PRON
eurjchem-2047	30	22	report	report	VERB
eurjchem-2047	30	23	the	the	DET
eurjchem-2047	30	24	crystal	crystal	NOUN
eurjchem-2047	30	25	structure	structure	NOUN
eurjchem-2047	30	26	of	of	ADP
eurjchem-2047	30	27	bis(n-(diethylcarbamothioyl	bis(n-(diethylcarbamothioyl	PROPN
eurjchem-2047	30	28	)	)	PUNCT
eurjchem-2047	30	29	cyclohexane	cyclohexane	NOUN
eurjchem-2047	30	30	carboxamido)copper(ii	carboxamido)copper(ii	PROPN
eurjchem-2047	30	31	)	)	PUNCT
eurjchem-2047	30	32	complex	complex	NOUN
eurjchem-2047	30	33	.	.	PUNCT
eurjchem-2047	31	1	2	2	X
eurjchem-2047	31	2	.	.	X
eurjchem-2047	31	3	experimental	experimental	ADJ
eurjchem-2047	31	4	2.1	2.1	NUM
eurjchem-2047	31	5	.	.	PUNCT
eurjchem-2047	32	1	instrumentation	instrumentation	NOUN
eurjchem-2047	32	2	1h	1h	NUM
eurjchem-2047	32	3	nmr	nmr	NOUN
eurjchem-2047	32	4	spectrum	spectrum	NOUN
eurjchem-2047	32	5	of	of	ADP
eurjchem-2047	32	6	the	the	DET
eurjchem-2047	32	7	ligand	ligand	NOUN
eurjchem-2047	32	8	was	be	AUX
eurjchem-2047	32	9	recorded	record	VERB
eurjchem-2047	32	10	on	on	ADP
eurjchem-2047	32	11	a	a	DET
eurjchem-2047	32	12	bruker	bruker	NOUN
eurjchem-2047	32	13	dpx-400	dpx-400	NOUN
eurjchem-2047	32	14	spectrometer	spectrometer	NOUN
eurjchem-2047	32	15	at	at	ADP
eurjchem-2047	32	16	400	400	NUM
eurjchem-2047	32	17	mhz	mhz	NOUN
eurjchem-2047	32	18	using	use	VERB
eurjchem-2047	32	19	cdcl3	cdcl3	NOUN
eurjchem-2047	32	20	as	as	ADP
eurjchem-2047	32	21	the	the	DET
eurjchem-2047	32	22	solvent	solvent	NOUN
eurjchem-2047	32	23	,	,	PUNCT
eurjchem-2047	32	24	with	with	ADP
eurjchem-2047	32	25	tetramethylsilane	tetramethylsilane	NOUN
eurjchem-2047	32	26	as	as	ADP
eurjchem-2047	32	27	an	an	DET
eurjchem-2047	32	28	internal	internal	ADJ
eurjchem-2047	32	29	standard	standard	NOUN
eurjchem-2047	32	30	.	.	PUNCT
eurjchem-2047	33	1	room	room	NOUN
eurjchem-2047	33	2	temperature	temperature	NOUN
eurjchem-2047	33	3	attenuated	attenuate	VERB
eurjchem-2047	33	4	total	total	ADJ
eurjchem-2047	33	5	reflection	reflection	NOUN
eurjchem-2047	33	6	fourier	fourier	NOUN
eurjchem-2047	33	7	transform	transform	NOUN
eurjchem-2047	33	8	infrared	infrared	ADJ
eurjchem-2047	33	9	(	(	PUNCT
eurjchem-2047	33	10	ft	ft	NOUN
eurjchem-2047	33	11	-	-	PUNCT
eurjchem-2047	33	12	ir	ir	PROPN
eurjchem-2047	33	13	atr	atr	PROPN
eurjchem-2047	33	14	)	)	PUNCT
eurjchem-2047	33	15	spectra	spectra	NOUN
eurjchem-2047	33	16	of	of	ADP
eurjchem-2047	33	17	all	all	DET
eurjchem-2047	33	18	synthesized	synthesize	VERB
eurjchem-2047	33	19	compounds	compound	NOUN
eurjchem-2047	33	20	were	be	AUX
eurjchem-2047	33	21	recorded	record	VERB
eurjchem-2047	33	22	using	use	VERB
eurjchem-2047	33	23	a	a	DET
eurjchem-2047	33	24	varian	varian	NOUN
eurjchem-2047	33	25	fts1000	fts1000	NOUN
eurjchem-2047	33	26	ft	ft	PROPN
eurjchem-2047	33	27	-	-	PUNCT
eurjchem-2047	33	28	ir	ir	NOUN
eurjchem-2047	33	29	spectrometer	spectrometer	NOUN
eurjchem-2047	33	30	with	with	ADP
eurjchem-2047	33	31	diamond	diamond	NOUN
eurjchem-2047	33	32	/	/	SYM
eurjchem-2047	33	33	znse	znse	NOUN
eurjchem-2047	33	34	prism	prism	NOUN
eurjchem-2047	33	35	(	(	PUNCT
eurjchem-2047	33	36	4000	4000	NUM
eurjchem-2047	33	37	-	-	SYM
eurjchem-2047	33	38	525	525	NUM
eurjchem-2047	33	39	cm-1	cm-1	NOUN
eurjchem-2047	33	40	;	;	PUNCT
eurjchem-2047	33	41	number	number	NOUN
eurjchem-2047	33	42	of	of	ADP
eurjchem-2047	33	43	scans	scan	NOUN
eurjchem-2047	33	44	:	:	PUNCT
eurjchem-2047	33	45	250	250	NUM
eurjchem-2047	33	46	;	;	PUNCT
eurjchem-2047	33	47	resolution	resolution	NOUN
eurjchem-2047	33	48	:	:	PUNCT
eurjchem-2047	33	49	1	1	NUM
eurjchem-2047	33	50	cm-1	cm-1	NOUN
eurjchem-2047	33	51	)	)	PUNCT
eurjchem-2047	33	52	.	.	PUNCT
eurjchem-2047	34	1	the	the	DET
eurjchem-2047	34	2	x	x	ADJ
eurjchem-2047	34	3	-	-	NOUN
eurjchem-2047	34	4	ray	ray	NOUN
eurjchem-2047	34	5	diffraction	diffraction	NOUN
eurjchem-2047	34	6	data	datum	NOUN
eurjchem-2047	34	7	were	be	AUX
eurjchem-2047	34	8	recorded	record	VERB
eurjchem-2047	34	9	on	on	ADP
eurjchem-2047	34	10	a	a	DET
eurjchem-2047	34	11	bruker	bruker	PROPN
eurjchem-2047	34	12	apex	apex	PROPN
eurjchem-2047	34	13	-	-	PUNCT
eurjchem-2047	34	14	ii	ii	PROPN
eurjchem-2047	34	15	ccd	ccd	PROPN
eurjchem-2047	34	16	diffractometer	diffractometer	NOUN
eurjchem-2047	34	17	.	.	PUNCT
eurjchem-2047	35	1	a	a	DET
eurjchem-2047	35	2	suitable	suitable	ADJ
eurjchem-2047	35	3	crystal	crystal	NOUN
eurjchem-2047	35	4	was	be	AUX
eurjchem-2047	35	5	selected	select	VERB
eurjchem-2047	35	6	and	and	CCONJ
eurjchem-2047	35	7	coated	coat	VERB
eurjchem-2047	35	8	with	with	ADP
eurjchem-2047	35	9	paratone	paratone	NOUN
eurjchem-2047	35	10	oil	oil	NOUN
eurjchem-2047	35	11	and	and	CCONJ
eurjchem-2047	35	12	mounted	mount	VERB
eurjchem-2047	35	13	on	on	ADP
eurjchem-2047	35	14	a	a	DET
eurjchem-2047	35	15	nylon	nylon	NOUN
eurjchem-2047	35	16	loop	loop	NOUN
eurjchem-2047	35	17	on	on	ADP
eurjchem-2047	35	18	a	a	DET
eurjchem-2047	35	19	bruker	bruker	PROPN
eurjchem-2047	35	20	apex	apex	PROPN
eurjchem-2047	35	21	-	-	PUNCT
eurjchem-2047	35	22	ii	ii	PROPN
eurjchem-2047	35	23	ccd	ccd	PROPN
eurjchem-2047	35	24	diffractometer	diffractometer	NOUN
eurjchem-2047	35	25	.	.	PUNCT
eurjchem-2047	36	1	the	the	DET
eurjchem-2047	36	2	crystal	crystal	NOUN
eurjchem-2047	36	3	was	be	AUX
eurjchem-2047	36	4	kept	keep	VERB
eurjchem-2047	36	5	at	at	ADP
eurjchem-2047	36	6	t	t	NOUN
eurjchem-2047	36	7	=	=	SYM
eurjchem-2047	36	8	153(2	153(2	NUM
eurjchem-2047	36	9	)	)	PUNCT
eurjchem-2047	36	10	k	k	NOUN
eurjchem-2047	36	11	during	during	ADP
eurjchem-2047	36	12	data	data	NOUN
eurjchem-2047	36	13	collection	collection	NOUN
eurjchem-2047	36	14	.	.	PUNCT
eurjchem-2047	37	1	the	the	DET
eurjchem-2047	37	2	data	datum	NOUN
eurjchem-2047	37	3	were	be	AUX
eurjchem-2047	37	4	collected	collect	VERB
eurjchem-2047	37	5	with	with	ADP
eurjchem-2047	37	6	mokα	mokα	ADJ
eurjchem-2047	37	7	(	(	PUNCT
eurjchem-2047	37	8	λ	λ	SYM
eurjchem-2047	37	9	=	=	SYM
eurjchem-2047	37	10	0.71073	0.71073	NUM
eurjchem-2047	37	11	å	å	NOUN
eurjchem-2047	37	12	)	)	PUNCT
eurjchem-2047	37	13	radiation	radiation	NOUN
eurjchem-2047	37	14	at	at	ADP
eurjchem-2047	37	15	a	a	DET
eurjchem-2047	37	16	crystal	crystal	NOUN
eurjchem-2047	37	17	-	-	PUNCT
eurjchem-2047	37	18	todetector	todetector	NOUN
eurjchem-2047	37	19	distance	distance	NOUN
eurjchem-2047	37	20	of	of	ADP
eurjchem-2047	37	21	40	40	NUM
eurjchem-2047	37	22	mm	mm	NOUN
eurjchem-2047	37	23	.	.	PUNCT
eurjchem-2047	38	1	abstract	abstract	ADJ
eurjchem-2047	38	2	research	research	NOUN
eurjchem-2047	38	3	article	article	NOUN
eurjchem-2047	38	4	keywords	keyword	VERB
eurjchem-2047	38	5	http://dx.doi.org/10.5155/eurjchem.11.4.319-323.2047	http://dx.doi.org/10.5155/eurjchem.11.4.319-323.2047	PROPN
eurjchem-2047	38	6	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2047	38	7	http://dx.doi.org/10.5155/eurjchem.11.4.319-323.2047	http://dx.doi.org/10.5155/eurjchem.11.4.319-323.2047	PROPN
eurjchem-2047	38	8	mailto:c.korayozer@gmail.com	mailto:c.korayozer@gmail.com	X
eurjchem-2047	39	1	mailto:hakan.arslan@mersin.edu.tr	mailto:hakan.arslan@mersin.edu.tr	PROPN
eurjchem-2047	39	2	mailto:gunbinzet@mersin.edu.tr	mailto:gunbinzet@mersin.edu.tr	ADV
eurjchem-2047	39	3	mailto:gunbinzet@mersin.edu.tr	mailto:gunbinzet@mersin.edu.tr	PROPN
eurjchem-2047	39	4	http://www.eurjchem.com/	http://www.eurjchem.com/	PROPN
eurjchem-2047	39	5	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.11.4.319-323.2047&domain=pdf&date_stamp=2020-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.11.4.319-323.2047&domain=pdf&date_stamp=2020-12-31	PROPN
eurjchem-2047	39	6	320	320	NUM
eurjchem-2047	39	7	ozer	ozer	NOUN
eurjchem-2047	39	8	et	et	PROPN
eurjchem-2047	39	9	al	al	PROPN
eurjchem-2047	39	10	.	.	PUNCT
eurjchem-2047	39	11	/	/	SYM
eurjchem-2047	39	12	european	european	PROPN
eurjchem-2047	39	13	journal	journal	PROPN
eurjchem-2047	39	14	of	of	ADP
eurjchem-2047	39	15	chemistry	chemistry	NOUN
eurjchem-2047	39	16	11	11	NUM
eurjchem-2047	39	17	(	(	PUNCT
eurjchem-2047	39	18	4	4	NUM
eurjchem-2047	39	19	)	)	PUNCT
eurjchem-2047	39	20	(	(	PUNCT
eurjchem-2047	39	21	2020	2020	NUM
eurjchem-2047	39	22	)	)	PUNCT
eurjchem-2047	39	23	319	319	NUM
eurjchem-2047	39	24	-	-	SYM
eurjchem-2047	39	25	323	323	NUM
eurjchem-2047	39	26	2020	2020	NUM
eurjchem-2047	39	27	–	–	PUNCT
eurjchem-2047	39	28	european	european	ADJ
eurjchem-2047	39	29	journal	journal	NOUN
eurjchem-2047	39	30	of	of	ADP
eurjchem-2047	39	31	chemistry	chemistry	NOUN
eurjchem-2047	39	32	–	–	PUNCT
eurjchem-2047	39	33	cc	cc	NOUN
eurjchem-2047	39	34	by	by	ADP
eurjchem-2047	39	35	nc	nc	PROPN
eurjchem-2047	39	36	–	–	PUNCT
eurjchem-2047	39	37	doi	doi	NOUN
eurjchem-2047	39	38	:	:	PUNCT
eurjchem-2047	39	39	10.5155	10.5155	NUM
eurjchem-2047	39	40	/	/	SYM
eurjchem-2047	39	41	eurjchem.11.4.319	eurjchem.11.4.319	ADJ
eurjchem-2047	39	42	-	-	PUNCT
eurjchem-2047	39	43	323.2047	323.2047	NUM
eurjchem-2047	39	44	scheme	scheme	NOUN
eurjchem-2047	39	45	1	1	NUM
eurjchem-2047	39	46	.	.	PUNCT
eurjchem-2047	39	47	synthesis	synthesis	NOUN
eurjchem-2047	39	48	of	of	ADP
eurjchem-2047	39	49	ligand	ligand	NOUN
eurjchem-2047	39	50	and	and	CCONJ
eurjchem-2047	39	51	its	its	PRON
eurjchem-2047	39	52	copper	copper	NOUN
eurjchem-2047	39	53	complex	complex	NOUN
eurjchem-2047	39	54	.	.	PUNCT
eurjchem-2047	40	1	using	use	VERB
eurjchem-2047	40	2	olex2	olex2	PROPN
eurjchem-2047	41	1	[	[	X
eurjchem-2047	41	2	63	63	NUM
eurjchem-2047	41	3	]	]	PUNCT
eurjchem-2047	41	4	,	,	PUNCT
eurjchem-2047	41	5	the	the	DET
eurjchem-2047	41	6	structure	structure	NOUN
eurjchem-2047	41	7	was	be	AUX
eurjchem-2047	41	8	solved	solve	VERB
eurjchem-2047	41	9	with	with	ADP
eurjchem-2047	41	10	the	the	DET
eurjchem-2047	41	11	superflip	superflip	NOUN
eurjchem-2047	41	12	[	[	X
eurjchem-2047	41	13	64	64	NUM
eurjchem-2047	41	14	]	]	PUNCT
eurjchem-2047	41	15	structure	structure	NOUN
eurjchem-2047	41	16	solution	solution	NOUN
eurjchem-2047	41	17	program	program	NOUN
eurjchem-2047	41	18	,	,	PUNCT
eurjchem-2047	41	19	using	use	VERB
eurjchem-2047	41	20	the	the	DET
eurjchem-2047	41	21	charge	charge	NOUN
eurjchem-2047	41	22	flipping	flipping	NOUN
eurjchem-2047	41	23	solution	solution	NOUN
eurjchem-2047	41	24	method	method	NOUN
eurjchem-2047	41	25	and	and	CCONJ
eurjchem-2047	41	26	refined	refine	VERB
eurjchem-2047	41	27	by	by	ADP
eurjchem-2047	41	28	full	full	ADJ
eurjchem-2047	41	29	-	-	PUNCT
eurjchem-2047	41	30	matrix	matrix	NOUN
eurjchem-2047	41	31	leastsquares	leastsquare	NOUN
eurjchem-2047	41	32	technique	technique	NOUN
eurjchem-2047	41	33	on	on	ADP
eurjchem-2047	41	34	f2	f2	PROPN
eurjchem-2047	41	35	using	use	VERB
eurjchem-2047	41	36	shelxl	shelxl	NOUN
eurjchem-2047	41	37	[	[	X
eurjchem-2047	41	38	65	65	NUM
eurjchem-2047	41	39	]	]	PUNCT
eurjchem-2047	41	40	with	with	ADP
eurjchem-2047	41	41	a	a	DET
eurjchem-2047	41	42	refinement	refinement	NOUN
eurjchem-2047	41	43	of	of	ADP
eurjchem-2047	41	44	f2	f2	PROPN
eurjchem-2047	41	45	against	against	ADP
eurjchem-2047	41	46	all	all	DET
eurjchem-2047	41	47	reflections	reflection	NOUN
eurjchem-2047	41	48	.	.	PUNCT
eurjchem-2047	42	1	hydrogen	hydrogen	NOUN
eurjchem-2047	42	2	atoms	atom	NOUN
eurjchem-2047	42	3	were	be	AUX
eurjchem-2047	42	4	constrained	constrain	VERB
eurjchem-2047	42	5	by	by	ADP
eurjchem-2047	42	6	difference	difference	NOUN
eurjchem-2047	42	7	maps	map	NOUN
eurjchem-2047	42	8	and	and	CCONJ
eurjchem-2047	42	9	were	be	AUX
eurjchem-2047	42	10	refined	refine	VERB
eurjchem-2047	42	11	isotropically	isotropically	ADV
eurjchem-2047	42	12	,	,	PUNCT
eurjchem-2047	42	13	and	and	CCONJ
eurjchem-2047	42	14	all	all	DET
eurjchem-2047	42	15	nonhydrogen	nonhydrogen	NOUN
eurjchem-2047	42	16	atoms	atom	NOUN
eurjchem-2047	42	17	were	be	AUX
eurjchem-2047	42	18	refined	refine	VERB
eurjchem-2047	42	19	anisotropically	anisotropically	ADV
eurjchem-2047	42	20	.	.	PUNCT
eurjchem-2047	43	1	all	all	DET
eurjchem-2047	43	2	geometrical	geometrical	ADJ
eurjchem-2047	43	3	data	datum	NOUN
eurjchem-2047	43	4	were	be	AUX
eurjchem-2047	43	5	calculated	calculate	VERB
eurjchem-2047	43	6	using	use	VERB
eurjchem-2047	43	7	platon	platon	NOUN
eurjchem-2047	43	8	[	[	X
eurjchem-2047	43	9	66	66	NUM
eurjchem-2047	43	10	]	]	PUNCT
eurjchem-2047	43	11	.	.	PUNCT
eurjchem-2047	44	1	molecular	molecular	ADJ
eurjchem-2047	44	2	structure	structure	NOUN
eurjchem-2047	44	3	and	and	CCONJ
eurjchem-2047	44	4	packing	packing	NOUN
eurjchem-2047	44	5	diagrams	diagram	NOUN
eurjchem-2047	44	6	were	be	AUX
eurjchem-2047	44	7	generated	generate	VERB
eurjchem-2047	44	8	using	use	VERB
eurjchem-2047	44	9	olex2	olex2	PROPN
eurjchem-2047	44	10	and	and	CCONJ
eurjchem-2047	44	11	mercury	mercury	NOUN
eurjchem-2047	44	12	,	,	PUNCT
eurjchem-2047	44	13	respectively	respectively	ADV
eurjchem-2047	44	14	[	[	X
eurjchem-2047	44	15	63,67	63,67	NOUN
eurjchem-2047	44	16	]	]	X
eurjchem-2047	44	17	.	.	PUNCT
eurjchem-2047	45	1	2.2	2.2	NUM
eurjchem-2047	45	2	.	.	PUNCT
eurjchem-2047	45	3	reagents	reagent	NOUN
eurjchem-2047	45	4	all	all	DET
eurjchem-2047	45	5	chemicals	chemical	NOUN
eurjchem-2047	45	6	used	use	VERB
eurjchem-2047	45	7	for	for	ADP
eurjchem-2047	45	8	the	the	DET
eurjchem-2047	45	9	preparation	preparation	NOUN
eurjchem-2047	45	10	of	of	ADP
eurjchem-2047	45	11	the	the	DET
eurjchem-2047	45	12	compounds	compound	NOUN
eurjchem-2047	45	13	were	be	AUX
eurjchem-2047	45	14	of	of	ADP
eurjchem-2047	45	15	reagent	reagent	ADJ
eurjchem-2047	45	16	grade	grade	NOUN
eurjchem-2047	45	17	quality	quality	NOUN
eurjchem-2047	45	18	.	.	PUNCT
eurjchem-2047	46	1	acetone	acetone	NOUN
eurjchem-2047	46	2	was	be	AUX
eurjchem-2047	46	3	distilled	distil	VERB
eurjchem-2047	46	4	before	before	ADP
eurjchem-2047	46	5	use	use	NOUN
eurjchem-2047	46	6	.	.	PUNCT
eurjchem-2047	47	1	potassium	potassium	NOUN
eurjchem-2047	47	2	thiocyanate	thiocyanate	NOUN
eurjchem-2047	47	3	and	and	CCONJ
eurjchem-2047	47	4	cyclohexanecarbonyl	cyclohexanecarbonyl	ADJ
eurjchem-2047	47	5	chloride	chloride	PROPN
eurjchem-2047	47	6	were	be	AUX
eurjchem-2047	47	7	purchased	purchase	VERB
eurjchem-2047	47	8	from	from	ADP
eurjchem-2047	47	9	merck	merck	PROPN
eurjchem-2047	47	10	and	and	CCONJ
eurjchem-2047	47	11	used	use	VERB
eurjchem-2047	47	12	as	as	SCONJ
eurjchem-2047	47	13	received	receive	VERB
eurjchem-2047	47	14	.	.	PUNCT
eurjchem-2047	48	1	all	all	DET
eurjchem-2047	48	2	other	other	ADJ
eurjchem-2047	48	3	chemicals	chemical	NOUN
eurjchem-2047	48	4	and	and	CCONJ
eurjchem-2047	48	5	solvents	solvent	NOUN
eurjchem-2047	48	6	were	be	AUX
eurjchem-2047	48	7	obtained	obtain	VERB
eurjchem-2047	48	8	from	from	ADP
eurjchem-2047	48	9	commercial	commercial	ADJ
eurjchem-2047	48	10	suppliers	supplier	NOUN
eurjchem-2047	48	11	and	and	CCONJ
eurjchem-2047	48	12	used	use	VERB
eurjchem-2047	48	13	without	without	ADP
eurjchem-2047	48	14	further	further	ADJ
eurjchem-2047	48	15	purification	purification	NOUN
eurjchem-2047	48	16	.	.	PUNCT
eurjchem-2047	49	1	2.3	2.3	NUM
eurjchem-2047	49	2	.	.	PUNCT
eurjchem-2047	50	1	synthesis	synthesis	NOUN
eurjchem-2047	50	2	2.3.1	2.3.1	NUM
eurjchem-2047	50	3	.	.	PUNCT
eurjchem-2047	50	4	synthesis	synthesis	NOUN
eurjchem-2047	50	5	of	of	ADP
eurjchem-2047	50	6	n-(diethylcarbamothioyl)cyclohexane	n-(diethylcarbamothioyl)cyclohexane	NOUN
eurjchem-2047	50	7	carboxamide	carboxamide	NOUN
eurjchem-2047	50	8	,	,	PUNCT
eurjchem-2047	50	9	hl	hl	NOUN
eurjchem-2047	50	10	n-(diethylcarbamothioyl)cyclohexanecarboxamide	n-(diethylcarbamothioyl)cyclohexanecarboxamide	ADV
eurjchem-2047	50	11	(	(	PUNCT
eurjchem-2047	50	12	hl	hl	NOUN
eurjchem-2047	50	13	)	)	PUNCT
eurjchem-2047	50	14	was	be	AUX
eurjchem-2047	50	15	prepared	prepare	VERB
eurjchem-2047	50	16	according	accord	VERB
eurjchem-2047	50	17	to	to	ADP
eurjchem-2047	50	18	previously	previously	ADV
eurjchem-2047	50	19	published	publish	VERB
eurjchem-2047	50	20	methods	method	NOUN
eurjchem-2047	50	21	[	[	X
eurjchem-2047	50	22	5462,68	5462,68	NUM
eurjchem-2047	50	23	]	]	PUNCT
eurjchem-2047	50	24	.	.	PUNCT
eurjchem-2047	51	1	a	a	DET
eurjchem-2047	51	2	solution	solution	NOUN
eurjchem-2047	51	3	of	of	ADP
eurjchem-2047	51	4	cyclohexanecarbonyl	cyclohexanecarbonyl	ADJ
eurjchem-2047	51	5	chloride	chloride	NOUN
eurjchem-2047	51	6	(	(	PUNCT
eurjchem-2047	51	7	5.00	5.00	NUM
eurjchem-2047	51	8	mmoles	mmole	NOUN
eurjchem-2047	51	9	,	,	PUNCT
eurjchem-2047	51	10	0.683	0.683	NUM
eurjchem-2047	51	11	ml	ml	NOUN
eurjchem-2047	51	12	)	)	PUNCT
eurjchem-2047	51	13	in	in	ADP
eurjchem-2047	51	14	acetone	acetone	NOUN
eurjchem-2047	51	15	(	(	PUNCT
eurjchem-2047	51	16	30	30	NUM
eurjchem-2047	51	17	ml	ml	NOUN
eurjchem-2047	51	18	)	)	PUNCT
eurjchem-2047	51	19	was	be	AUX
eurjchem-2047	51	20	added	add	VERB
eurjchem-2047	51	21	dropwise	dropwise	NOUN
eurjchem-2047	51	22	to	to	ADP
eurjchem-2047	51	23	a	a	DET
eurjchem-2047	51	24	suspension	suspension	NOUN
eurjchem-2047	51	25	of	of	ADP
eurjchem-2047	51	26	potassium	potassium	NOUN
eurjchem-2047	51	27	thiocyanate	thiocyanate	NOUN
eurjchem-2047	51	28	(	(	PUNCT
eurjchem-2047	51	29	5.00	5.00	NUM
eurjchem-2047	51	30	mmoles	mmole	NOUN
eurjchem-2047	51	31	,	,	PUNCT
eurjchem-2047	51	32	0.4908	0.4908	NUM
eurjchem-2047	51	33	g	g	NOUN
eurjchem-2047	51	34	)	)	PUNCT
eurjchem-2047	51	35	in	in	ADP
eurjchem-2047	51	36	acetone	acetone	NOUN
eurjchem-2047	51	37	(	(	PUNCT
eurjchem-2047	51	38	30	30	NUM
eurjchem-2047	51	39	ml	ml	NOUN
eurjchem-2047	51	40	)	)	PUNCT
eurjchem-2047	51	41	.	.	PUNCT
eurjchem-2047	52	1	the	the	DET
eurjchem-2047	52	2	reaction	reaction	NOUN
eurjchem-2047	52	3	mixture	mixture	NOUN
eurjchem-2047	52	4	was	be	AUX
eurjchem-2047	52	5	heated	heat	VERB
eurjchem-2047	52	6	(	(	PUNCT
eurjchem-2047	52	7	50	50	NUM
eurjchem-2047	52	8	°	°	NOUN
eurjchem-2047	52	9	c	c	NOUN
eurjchem-2047	52	10	)	)	PUNCT
eurjchem-2047	52	11	under	under	ADP
eurjchem-2047	52	12	reflux	reflux	NOUN
eurjchem-2047	52	13	for	for	ADP
eurjchem-2047	52	14	30	30	NUM
eurjchem-2047	52	15	min	min	NOUN
eurjchem-2047	52	16	and	and	CCONJ
eurjchem-2047	52	17	then	then	ADV
eurjchem-2047	52	18	cooled	cool	VERB
eurjchem-2047	52	19	to	to	ADP
eurjchem-2047	52	20	room	room	NOUN
eurjchem-2047	52	21	temperature	temperature	NOUN
eurjchem-2047	52	22	.	.	PUNCT
eurjchem-2047	53	1	a	a	DET
eurjchem-2047	53	2	solution	solution	NOUN
eurjchem-2047	53	3	of	of	ADP
eurjchem-2047	53	4	diethyl	diethyl	NOUN
eurjchem-2047	53	5	amine	amine	NOUN
eurjchem-2047	53	6	(	(	PUNCT
eurjchem-2047	53	7	5.00	5.00	NUM
eurjchem-2047	53	8	mmoles	mmole	NOUN
eurjchem-2047	53	9	,	,	PUNCT
eurjchem-2047	53	10	0.520	0.520	NUM
eurjchem-2047	53	11	ml	ml	NOUN
eurjchem-2047	53	12	)	)	PUNCT
eurjchem-2047	53	13	in	in	ADP
eurjchem-2047	53	14	acetone	acetone	NOUN
eurjchem-2047	53	15	(	(	PUNCT
eurjchem-2047	53	16	30	30	NUM
eurjchem-2047	53	17	ml	ml	NOUN
eurjchem-2047	53	18	)	)	PUNCT
eurjchem-2047	53	19	was	be	AUX
eurjchem-2047	53	20	added	add	VERB
eurjchem-2047	53	21	and	and	CCONJ
eurjchem-2047	53	22	the	the	DET
eurjchem-2047	53	23	resulting	result	VERB
eurjchem-2047	53	24	mixture	mixture	NOUN
eurjchem-2047	53	25	was	be	AUX
eurjchem-2047	53	26	stirred	stir	VERB
eurjchem-2047	53	27	for	for	ADP
eurjchem-2047	53	28	2	2	NUM
eurjchem-2047	53	29	h.	h.	PROPN
eurjchem-2047	53	30	hydrochloric	hydrochloric	PROPN
eurjchem-2047	53	31	acid	acid	PROPN
eurjchem-2047	53	32	(	(	PUNCT
eurjchem-2047	53	33	0.1	0.1	NUM
eurjchem-2047	53	34	n	n	CCONJ
eurjchem-2047	53	35	,	,	PUNCT
eurjchem-2047	53	36	100	100	NUM
eurjchem-2047	53	37	ml	ml	NOUN
eurjchem-2047	53	38	)	)	PUNCT
eurjchem-2047	53	39	was	be	AUX
eurjchem-2047	53	40	added	add	VERB
eurjchem-2047	53	41	and	and	CCONJ
eurjchem-2047	53	42	the	the	DET
eurjchem-2047	53	43	solution	solution	NOUN
eurjchem-2047	53	44	filtered	filter	VERB
eurjchem-2047	53	45	.	.	PUNCT
eurjchem-2047	54	1	the	the	DET
eurjchem-2047	54	2	solid	solid	ADJ
eurjchem-2047	54	3	product	product	NOUN
eurjchem-2047	54	4	was	be	AUX
eurjchem-2047	54	5	washed	wash	VERB
eurjchem-2047	54	6	with	with	ADP
eurjchem-2047	54	7	water	water	NOUN
eurjchem-2047	54	8	and	and	CCONJ
eurjchem-2047	54	9	purified	purify	VERB
eurjchem-2047	54	10	by	by	ADP
eurjchem-2047	54	11	recrystallization	recrystallization	NOUN
eurjchem-2047	54	12	from	from	ADP
eurjchem-2047	54	13	an	an	DET
eurjchem-2047	54	14	ethanol	ethanol	NOUN
eurjchem-2047	54	15	:	:	PUNCT
eurjchem-2047	54	16	dichloromethane	dichloromethane	NOUN
eurjchem-2047	54	17	mixture	mixture	NOUN
eurjchem-2047	54	18	(	(	PUNCT
eurjchem-2047	54	19	1:2	1:2	NUM
eurjchem-2047	54	20	,	,	PUNCT
eurjchem-2047	54	21	v	v	NOUN
eurjchem-2047	54	22	:	:	SYM
eurjchem-2047	54	23	v	v	NOUN
eurjchem-2047	54	24	)	)	PUNCT
eurjchem-2047	54	25	(	(	PUNCT
eurjchem-2047	54	26	scheme	scheme	NOUN
eurjchem-2047	54	27	1	1	NUM
eurjchem-2047	54	28	)	)	PUNCT
eurjchem-2047	54	29	.	.	PUNCT
eurjchem-2047	55	1	yield	yield	NOUN
eurjchem-2047	55	2	:	:	PUNCT
eurjchem-2047	55	3	76	76	NUM
eurjchem-2047	55	4	%	%	NOUN
eurjchem-2047	55	5	(	(	PUNCT
eurjchem-2047	55	6	0.9211	0.9211	NUM
eurjchem-2047	55	7	g	g	NOUN
eurjchem-2047	55	8	)	)	PUNCT
eurjchem-2047	55	9	.	.	PUNCT
eurjchem-2047	56	1	1h	1h	NUM
eurjchem-2047	56	2	nmr	nmr	NOUN
eurjchem-2047	56	3	(	(	PUNCT
eurjchem-2047	56	4	400	400	NUM
eurjchem-2047	56	5	mhz	mhz	NOUN
eurjchem-2047	56	6	,	,	PUNCT
eurjchem-2047	56	7	cdcl3	cdcl3	PROPN
eurjchem-2047	56	8	,	,	PUNCT
eurjchem-2047	56	9	δ	δ	PROPN
eurjchem-2047	56	10	,	,	PUNCT
eurjchem-2047	56	11	ppm	ppm	NUM
eurjchem-2047	56	12	):	):	PUNCT
eurjchem-2047	56	13	8.00	8.00	NUM
eurjchem-2047	56	14	(	(	PUNCT
eurjchem-2047	56	15	s	s	PROPN
eurjchem-2047	56	16	,	,	PUNCT
eurjchem-2047	56	17	1h	1h	NUM
eurjchem-2047	56	18	,	,	PUNCT
eurjchem-2047	56	19	nh	nh	PROPN
eurjchem-2047	56	20	)	)	PUNCT
eurjchem-2047	56	21	,	,	PUNCT
eurjchem-2047	56	22	3.93	3.93	NUM
eurjchem-2047	56	23	(	(	PUNCT
eurjchem-2047	56	24	t	t	PROPN
eurjchem-2047	56	25	,	,	PUNCT
eurjchem-2047	56	26	2h	2h	NUM
eurjchem-2047	56	27	,	,	PUNCT
eurjchem-2047	56	28	nch2	nch2	PROPN
eurjchem-2047	56	29	)	)	PUNCT
eurjchem-2047	56	30	,	,	PUNCT
eurjchem-2047	56	31	3.43	3.43	NUM
eurjchem-2047	56	32	(	(	PUNCT
eurjchem-2047	56	33	t	t	PROPN
eurjchem-2047	56	34	,	,	PUNCT
eurjchem-2047	56	35	2h	2h	NUM
eurjchem-2047	56	36	,	,	PUNCT
eurjchem-2047	56	37	nch2	nch2	PROPN
eurjchem-2047	56	38	)	)	PUNCT
eurjchem-2047	56	39	,	,	PUNCT
eurjchem-2047	56	40	2.24	2.24	NUM
eurjchem-2047	56	41	(	(	PUNCT
eurjchem-2047	56	42	tt	tt	PROPN
eurjchem-2047	56	43	,	,	PUNCT
eurjchem-2047	56	44	1h	1h	NUM
eurjchem-2047	56	45	,	,	PUNCT
eurjchem-2047	56	46	ch	ch	NOUN
eurjchem-2047	56	47	,	,	PUNCT
eurjchem-2047	56	48	ch	ch	NOUN
eurjchem-2047	56	49	)	)	PUNCT
eurjchem-2047	56	50	,	,	PUNCT
eurjchem-2047	56	51	1.89	1.89	NUM
eurjchem-2047	56	52	(	(	PUNCT
eurjchem-2047	56	53	d	d	PROPN
eurjchem-2047	56	54	,	,	PUNCT
eurjchem-2047	56	55	1h	1h	NUM
eurjchem-2047	56	56	,	,	PUNCT
eurjchem-2047	56	57	ch	ch	NOUN
eurjchem-2047	56	58	,	,	PUNCT
eurjchem-2047	56	59	ch	ch	NOUN
eurjchem-2047	56	60	)	)	PUNCT
eurjchem-2047	56	61	,	,	PUNCT
eurjchem-2047	56	62	1.84	1.84	NUM
eurjchem-2047	56	63	(	(	PUNCT
eurjchem-2047	56	64	d	d	PROPN
eurjchem-2047	56	65	,	,	PUNCT
eurjchem-2047	56	66	1h	1h	NUM
eurjchem-2047	56	67	,	,	PUNCT
eurjchem-2047	56	68	ch	ch	NOUN
eurjchem-2047	56	69	,	,	PUNCT
eurjchem-2047	56	70	ch	ch	NOUN
eurjchem-2047	56	71	)	)	PUNCT
eurjchem-2047	56	72	,	,	PUNCT
eurjchem-2047	56	73	1.78	1.78	NUM
eurjchem-2047	56	74	(	(	PUNCT
eurjchem-2047	56	75	m	m	PROPN
eurjchem-2047	56	76	,	,	PUNCT
eurjchem-2047	56	77	1h	1h	NUM
eurjchem-2047	56	78	,	,	PUNCT
eurjchem-2047	56	79	ch	ch	NOUN
eurjchem-2047	56	80	,	,	PUNCT
eurjchem-2047	56	81	ch	ch	NOUN
eurjchem-2047	56	82	)	)	PUNCT
eurjchem-2047	56	83	,	,	PUNCT
eurjchem-2047	56	84	1.74	1.74	NUM
eurjchem-2047	56	85	(	(	PUNCT
eurjchem-2047	56	86	m	m	PROPN
eurjchem-2047	56	87	,	,	PUNCT
eurjchem-2047	56	88	1h	1h	NUM
eurjchem-2047	56	89	,	,	PUNCT
eurjchem-2047	56	90	ch	ch	NOUN
eurjchem-2047	56	91	,	,	PUNCT
eurjchem-2047	56	92	ch	ch	NOUN
eurjchem-2047	56	93	)	)	PUNCT
eurjchem-2047	56	94	,	,	PUNCT
eurjchem-2047	56	95	1.67	1.67	NUM
eurjchem-2047	56	96	(	(	PUNCT
eurjchem-2047	56	97	m	m	PROPN
eurjchem-2047	56	98	,	,	PUNCT
eurjchem-2047	56	99	1h	1h	NUM
eurjchem-2047	56	100	,	,	PUNCT
eurjchem-2047	56	101	ch	ch	NOUN
eurjchem-2047	56	102	,	,	PUNCT
eurjchem-2047	56	103	ch	ch	NOUN
eurjchem-2047	56	104	)	)	PUNCT
eurjchem-2047	56	105	,	,	PUNCT
eurjchem-2047	56	106	1.64	1.64	NUM
eurjchem-2047	56	107	(	(	PUNCT
eurjchem-2047	56	108	m	m	PROPN
eurjchem-2047	56	109	,	,	PUNCT
eurjchem-2047	56	110	1h	1h	NUM
eurjchem-2047	56	111	,	,	PUNCT
eurjchem-2047	56	112	ch	ch	NOUN
eurjchem-2047	56	113	,	,	PUNCT
eurjchem-2047	56	114	ch	ch	NOUN
eurjchem-2047	56	115	)	)	PUNCT
eurjchem-2047	56	116	,	,	PUNCT
eurjchem-2047	56	117	1.41	1.41	NUM
eurjchem-2047	56	118	(	(	PUNCT
eurjchem-2047	56	119	m	m	PROPN
eurjchem-2047	56	120	,	,	PUNCT
eurjchem-2047	56	121	4h	4h	NUM
eurjchem-2047	56	122	,	,	PUNCT
eurjchem-2047	56	123	ch	ch	NOUN
eurjchem-2047	56	124	,	,	PUNCT
eurjchem-2047	56	125	ch	ch	NOUN
eurjchem-2047	56	126	)	)	PUNCT
eurjchem-2047	56	127	,	,	PUNCT
eurjchem-2047	56	128	1.32	1.32	NUM
eurjchem-2047	56	129	(	(	PUNCT
eurjchem-2047	56	130	t	t	PROPN
eurjchem-2047	56	131	,	,	PUNCT
eurjchem-2047	56	132	3h	3h	NUM
eurjchem-2047	56	133	,	,	PUNCT
eurjchem-2047	56	134	ch3	ch3	PROPN
eurjchem-2047	56	135	)	)	PUNCT
eurjchem-2047	56	136	,	,	PUNCT
eurjchem-2047	56	137	1.23	1.23	NUM
eurjchem-2047	56	138	(	(	PUNCT
eurjchem-2047	56	139	t	t	PROPN
eurjchem-2047	56	140	,	,	PUNCT
eurjchem-2047	56	141	3h	3h	NUM
eurjchem-2047	56	142	,	,	PUNCT
eurjchem-2047	56	143	ch3	ch3	PROPN
eurjchem-2047	56	144	)	)	PUNCT
eurjchem-2047	56	145	.	.	PUNCT
eurjchem-2047	57	1	ft	ft	PROPN
eurjchem-2047	57	2	-	-	PUNCT
eurjchem-2047	57	3	ir	ir	PROPN
eurjchem-2047	57	4	(	(	PUNCT
eurjchem-2047	57	5	cm-1	cm-1	PROPN
eurjchem-2047	57	6	):	):	PUNCT
eurjchem-2047	57	7	3240	3240	NUM
eurjchem-2047	57	8	ν(nh	ν(nh	NOUN
eurjchem-2047	57	9	)	)	PUNCT
eurjchem-2047	57	10	,	,	PUNCT
eurjchem-2047	57	11	2976	2976	NUM
eurjchem-2047	57	12	,	,	PUNCT
eurjchem-2047	57	13	2926	2926	NUM
eurjchem-2047	57	14	,	,	PUNCT
eurjchem-2047	57	15	2853	2853	NUM
eurjchem-2047	57	16	ν(ch	ν(ch	NOUN
eurjchem-2047	57	17	)	)	PUNCT
eurjchem-2047	57	18	,	,	PUNCT
eurjchem-2047	57	19	1661	1661	NUM
eurjchem-2047	57	20	ν(c	ν(c	NOUN
eurjchem-2047	57	21	=	=	SYM
eurjchem-2047	57	22	o	o	NOUN
eurjchem-2047	57	23	)	)	PUNCT
eurjchem-2047	57	24	,	,	PUNCT
eurjchem-2047	57	25	1312	1312	NUM
eurjchem-2047	57	26	ν(c	ν(c	PROPN
eurjchem-2047	57	27	=	=	SYM
eurjchem-2047	57	28	s	s	PART
eurjchem-2047	57	29	)	)	PUNCT
eurjchem-2047	58	1	[	[	X
eurjchem-2047	58	2	62	62	NUM
eurjchem-2047	58	3	]	]	PUNCT
eurjchem-2047	58	4	.	.	PUNCT
eurjchem-2047	59	1	2.3.2	2.3.2	NUM
eurjchem-2047	59	2	.	.	X
eurjchem-2047	59	3	synthesis	synthesis	NOUN
eurjchem-2047	59	4	of	of	ADP
eurjchem-2047	59	5	copper	copper	NOUN
eurjchem-2047	59	6	complex	complex	NOUN
eurjchem-2047	59	7	,	,	PUNCT
eurjchem-2047	59	8	cu(l	cu(l	NOUN
eurjchem-2047	59	9	-	-	PUNCT
eurjchem-2047	59	10	κ2s	κ2	NOUN
eurjchem-2047	59	11	,	,	PUNCT
eurjchem-2047	59	12	o)2	o)2	ADJ
eurjchem-2047	59	13	paramagnetic	paramagnetic	ADJ
eurjchem-2047	59	14	copper	copper	NOUN
eurjchem-2047	59	15	complex	complex	NOUN
eurjchem-2047	59	16	was	be	AUX
eurjchem-2047	59	17	prepared	prepare	VERB
eurjchem-2047	59	18	according	accord	VERB
eurjchem-2047	59	19	to	to	ADP
eurjchem-2047	59	20	the	the	DET
eurjchem-2047	59	21	method	method	NOUN
eurjchem-2047	59	22	described	describe	VERB
eurjchem-2047	59	23	in	in	ADP
eurjchem-2047	59	24	the	the	DET
eurjchem-2047	59	25	literature	literature	NOUN
eurjchem-2047	59	26	[	[	X
eurjchem-2047	59	27	62	62	NUM
eurjchem-2047	59	28	]	]	PUNCT
eurjchem-2047	59	29	.	.	PUNCT
eurjchem-2047	60	1	a	a	DET
eurjchem-2047	60	2	solution	solution	NOUN
eurjchem-2047	60	3	of	of	ADP
eurjchem-2047	60	4	copper(ii	copper(ii	PROPN
eurjchem-2047	60	5	)	)	PUNCT
eurjchem-2047	60	6	acetate	acetate	NOUN
eurjchem-2047	60	7	(	(	PUNCT
eurjchem-2047	60	8	10.0	10.0	NUM
eurjchem-2047	60	9	mmoles	mmole	NOUN
eurjchem-2047	60	10	,	,	PUNCT
eurjchem-2047	60	11	1.8163	1.8163	NUM
eurjchem-2047	60	12	g	g	NOUN
eurjchem-2047	60	13	)	)	PUNCT
eurjchem-2047	60	14	in	in	ADP
eurjchem-2047	60	15	ethanol	ethanol	NOUN
eurjchem-2047	60	16	(	(	PUNCT
eurjchem-2047	60	17	30	30	NUM
eurjchem-2047	60	18	ml	ml	NOUN
eurjchem-2047	60	19	)	)	PUNCT
eurjchem-2047	60	20	was	be	AUX
eurjchem-2047	60	21	added	add	VERB
eurjchem-2047	60	22	dropwise	dropwise	NOUN
eurjchem-2047	60	23	to	to	ADP
eurjchem-2047	60	24	a	a	DET
eurjchem-2047	60	25	solution	solution	NOUN
eurjchem-2047	60	26	of	of	ADP
eurjchem-2047	60	27	n-(diethylcarbamothioyl	n-(diethylcarbamothioyl	NUM
eurjchem-2047	60	28	)	)	PUNCT
eurjchem-2047	60	29	cyclohexanecarboxamide	cyclohexanecarboxamide	NOUN
eurjchem-2047	60	30	(	(	PUNCT
eurjchem-2047	60	31	22.0	22.0	NUM
eurjchem-2047	60	32	mmoles	mmole	NOUN
eurjchem-2047	60	33	,	,	PUNCT
eurjchem-2047	60	34	5.3324	5.3324	NUM
eurjchem-2047	60	35	g	g	NOUN
eurjchem-2047	60	36	)	)	PUNCT
eurjchem-2047	60	37	in	in	ADP
eurjchem-2047	60	38	a	a	DET
eurjchem-2047	60	39	1:2	1:2	NUM
eurjchem-2047	60	40	ratio	ratio	NOUN
eurjchem-2047	60	41	with	with	ADP
eurjchem-2047	60	42	a	a	DET
eurjchem-2047	60	43	small	small	ADJ
eurjchem-2047	60	44	excess	excess	NOUN
eurjchem-2047	60	45	of	of	ADP
eurjchem-2047	60	46	n-(diethylcarbamothioyl)cyclohexane	n-(diethylcarbamothioyl)cyclohexane	NOUN
eurjchem-2047	60	47	carboxamide	carboxamide	NOUN
eurjchem-2047	60	48	in	in	ADP
eurjchem-2047	60	49	ethanol	ethanol	NOUN
eurjchem-2047	60	50	(	(	PUNCT
eurjchem-2047	60	51	30	30	NUM
eurjchem-2047	60	52	ml	ml	NOUN
eurjchem-2047	60	53	)	)	PUNCT
eurjchem-2047	60	54	at	at	ADP
eurjchem-2047	60	55	room	room	NOUN
eurjchem-2047	60	56	temperature	temperature	NOUN
eurjchem-2047	60	57	and	and	CCONJ
eurjchem-2047	60	58	the	the	DET
eurjchem-2047	60	59	resulting	result	VERB
eurjchem-2047	60	60	mixture	mixture	NOUN
eurjchem-2047	60	61	was	be	AUX
eurjchem-2047	60	62	stirred	stir	VERB
eurjchem-2047	60	63	for	for	ADP
eurjchem-2047	60	64	30	30	NUM
eurjchem-2047	60	65	min	min	NOUN
eurjchem-2047	60	66	.	.	PUNCT
eurjchem-2047	61	1	the	the	DET
eurjchem-2047	61	2	solid	solid	ADJ
eurjchem-2047	61	3	complex	complex	NOUN
eurjchem-2047	61	4	was	be	AUX
eurjchem-2047	61	5	filtered	filter	VERB
eurjchem-2047	61	6	and	and	CCONJ
eurjchem-2047	61	7	re	re	VERB
eurjchem-2047	61	8	-	-	VERB
eurjchem-2047	61	9	crystallized	crystallized	ADJ
eurjchem-2047	61	10	from	from	ADP
eurjchem-2047	61	11	ethanol	ethanol	NOUN
eurjchem-2047	61	12	:	:	PUNCT
eurjchem-2047	61	13	dichloromethane	dichloromethane	NOUN
eurjchem-2047	61	14	mixture	mixture	NOUN
eurjchem-2047	61	15	(	(	PUNCT
eurjchem-2047	61	16	1:2	1:2	NUM
eurjchem-2047	61	17	,	,	PUNCT
eurjchem-2047	61	18	v	v	NOUN
eurjchem-2047	61	19	:	:	SYM
eurjchem-2047	61	20	v	v	NOUN
eurjchem-2047	61	21	)	)	PUNCT
eurjchem-2047	61	22	(	(	PUNCT
eurjchem-2047	61	23	scheme	scheme	NOUN
eurjchem-2047	61	24	1	1	NUM
eurjchem-2047	61	25	)	)	PUNCT
eurjchem-2047	61	26	.	.	PUNCT
eurjchem-2047	62	1	bis(n-(diethylcarbamothioyl	bis(n-(diethylcarbamothioyl	PROPN
eurjchem-2047	62	2	)	)	PUNCT
eurjchem-2047	62	3	cyclohexanecarboxamido)copper(ii	cyclohexanecarboxamido)copper(ii	NOUN
eurjchem-2047	62	4	)	)	PUNCT
eurjchem-2047	63	1	[	[	X
eurjchem-2047	63	2	cu(l	cu(l	NOUN
eurjchem-2047	63	3	-	-	PUNCT
eurjchem-2047	63	4	κ2s	κ2	NOUN
eurjchem-2047	63	5	,	,	PUNCT
eurjchem-2047	63	6	o)2	o)2	NOUN
eurjchem-2047	63	7	]	]	NOUN
eurjchem-2047	63	8	:	:	PUNCT
eurjchem-2047	63	9	color	color	NOUN
eurjchem-2047	63	10	:	:	PUNCT
eurjchem-2047	63	11	green	green	ADJ
eurjchem-2047	63	12	.	.	PUNCT
eurjchem-2047	64	1	m.p	m.p	PROPN
eurjchem-2047	64	2	.	.	PROPN
eurjchem-2047	64	3	:	:	PUNCT
eurjchem-2047	65	1	71	71	NUM
eurjchem-2047	65	2	-	-	SYM
eurjchem-2047	65	3	73	73	NUM
eurjchem-2047	65	4	°	°	NUM
eurjchem-2047	65	5	c	c	NOUN
eurjchem-2047	65	6	.	.	PUNCT
eurjchem-2047	65	7	yield	yield	NOUN
eurjchem-2047	65	8	:	:	PUNCT
eurjchem-2047	65	9	81	81	NUM
eurjchem-2047	65	10	%	%	NOUN
eurjchem-2047	65	11	(	(	PUNCT
eurjchem-2047	65	12	4.4161	4.4161	NUM
eurjchem-2047	65	13	g	g	NOUN
eurjchem-2047	65	14	)	)	PUNCT
eurjchem-2047	65	15	.	.	PUNCT
eurjchem-2047	66	1	ft	ft	PROPN
eurjchem-2047	66	2	-	-	PUNCT
eurjchem-2047	66	3	ir	ir	PROPN
eurjchem-2047	66	4	(	(	PUNCT
eurjchem-2047	66	5	atr	atr	PROPN
eurjchem-2047	66	6	,	,	PUNCT
eurjchem-2047	66	7	cm-1	cm-1	PROPN
eurjchem-2047	66	8	):	):	PUNCT
eurjchem-2047	66	9	2972	2972	NUM
eurjchem-2047	66	10	,	,	PUNCT
eurjchem-2047	66	11	2924	2924	NUM
eurjchem-2047	66	12	,	,	PUNCT
eurjchem-2047	66	13	2854	2854	NUM
eurjchem-2047	66	14	ν(ch	ν(ch	NOUN
eurjchem-2047	66	15	)	)	PUNCT
eurjchem-2047	66	16	,	,	PUNCT
eurjchem-2047	66	17	1522	1522	NUM
eurjchem-2047	66	18	ν(cn	ν(cn	NOUN
eurjchem-2047	66	19	)	)	PUNCT
eurjchem-2047	66	20	,	,	PUNCT
eurjchem-2047	66	21	1489	1489	NUM
eurjchem-2047	66	22	ν(co	ν(co	NOUN
eurjchem-2047	66	23	)	)	PUNCT
eurjchem-2047	67	1	[	[	X
eurjchem-2047	67	2	62	62	NUM
eurjchem-2047	67	3	]	]	PUNCT
eurjchem-2047	67	4	.	.	PUNCT
eurjchem-2047	68	1	3	3	X
eurjchem-2047	68	2	.	.	NOUN
eurjchem-2047	68	3	results	result	NOUN
eurjchem-2047	68	4	and	and	CCONJ
eurjchem-2047	68	5	discussion	discussion	VERB
eurjchem-2047	68	6	the	the	DET
eurjchem-2047	68	7	block	block	NOUN
eurjchem-2047	68	8	-	-	PUNCT
eurjchem-2047	68	9	shaped	shape	VERB
eurjchem-2047	68	10	green	green	ADJ
eurjchem-2047	68	11	colored	colored	ADJ
eurjchem-2047	68	12	crystals	crystal	NOUN
eurjchem-2047	68	13	of	of	ADP
eurjchem-2047	68	14	the	the	DET
eurjchem-2047	68	15	copper	copper	NOUN
eurjchem-2047	68	16	complex	complex	NOUN
eurjchem-2047	68	17	was	be	AUX
eurjchem-2047	68	18	obtained	obtain	VERB
eurjchem-2047	68	19	by	by	ADP
eurjchem-2047	68	20	slow	slow	ADJ
eurjchem-2047	68	21	evaporation	evaporation	NOUN
eurjchem-2047	68	22	of	of	ADP
eurjchem-2047	68	23	their	their	PRON
eurjchem-2047	68	24	dichloromethane	dichloromethane	NOUN
eurjchem-2047	68	25	:	:	PUNCT
eurjchem-2047	68	26	ethanol	ethanol	NOUN
eurjchem-2047	68	27	solution	solution	NOUN
eurjchem-2047	68	28	(	(	PUNCT
eurjchem-2047	68	29	2:1	2:1	NUM
eurjchem-2047	68	30	,	,	PUNCT
eurjchem-2047	68	31	v	v	NOUN
eurjchem-2047	68	32	:	:	PUNCT
eurjchem-2047	68	33	v	v	NOUN
eurjchem-2047	68	34	)	)	PUNCT
eurjchem-2047	68	35	.	.	PUNCT
eurjchem-2047	69	1	the	the	DET
eurjchem-2047	69	2	molecular	molecular	ADJ
eurjchem-2047	69	3	structure	structure	NOUN
eurjchem-2047	69	4	of	of	ADP
eurjchem-2047	69	5	the	the	DET
eurjchem-2047	69	6	copper	copper	NOUN
eurjchem-2047	69	7	complex	complex	NOUN
eurjchem-2047	69	8	was	be	AUX
eurjchem-2047	69	9	determined	determine	VERB
eurjchem-2047	69	10	by	by	ADP
eurjchem-2047	69	11	single	single	ADJ
eurjchem-2047	69	12	crystal	crystal	NOUN
eurjchem-2047	69	13	x	x	PROPN
eurjchem-2047	69	14	-	-	NOUN
eurjchem-2047	69	15	ray	ray	NOUN
eurjchem-2047	69	16	diffraction	diffraction	NOUN
eurjchem-2047	69	17	.	.	PUNCT
eurjchem-2047	70	1	the	the	DET
eurjchem-2047	70	2	copper	copper	NOUN
eurjchem-2047	70	3	complex	complex	NOUN
eurjchem-2047	70	4	crystallized	crystallize	VERB
eurjchem-2047	70	5	in	in	ADP
eurjchem-2047	70	6	the	the	DET
eurjchem-2047	70	7	monoclinic	monoclinic	ADJ
eurjchem-2047	70	8	space	space	NOUN
eurjchem-2047	70	9	group	group	NOUN
eurjchem-2047	70	10	c2	c2	PROPN
eurjchem-2047	70	11	(	(	PUNCT
eurjchem-2047	70	12	no	no	INTJ
eurjchem-2047	70	13	.	.	NOUN
eurjchem-2047	70	14	5	5	NUM
eurjchem-2047	70	15	)	)	PUNCT
eurjchem-2047	70	16	and	and	CCONJ
eurjchem-2047	70	17	the	the	DET
eurjchem-2047	70	18	crystal	crystal	NOUN
eurjchem-2047	70	19	and	and	CCONJ
eurjchem-2047	70	20	structure	structure	NOUN
eurjchem-2047	70	21	refinement	refinement	NOUN
eurjchem-2047	70	22	data	datum	NOUN
eurjchem-2047	70	23	are	be	AUX
eurjchem-2047	70	24	given	give	VERB
eurjchem-2047	70	25	in	in	ADP
eurjchem-2047	70	26	table	table	NOUN
eurjchem-2047	70	27	1	1	NUM
eurjchem-2047	70	28	.	.	NUM
eurjchem-2047	70	29	selected	select	VERB
eurjchem-2047	70	30	bond	bond	NOUN
eurjchem-2047	70	31	lengths	length	NOUN
eurjchem-2047	70	32	and	and	CCONJ
eurjchem-2047	70	33	angles	angle	NOUN
eurjchem-2047	70	34	are	be	AUX
eurjchem-2047	70	35	given	give	VERB
eurjchem-2047	70	36	in	in	ADP
eurjchem-2047	70	37	table	table	NOUN
eurjchem-2047	70	38	2	2	NUM
eurjchem-2047	70	39	.	.	PUNCT
eurjchem-2047	71	1	the	the	DET
eurjchem-2047	71	2	molecular	molecular	ADJ
eurjchem-2047	71	3	structure	structure	NOUN
eurjchem-2047	71	4	of	of	ADP
eurjchem-2047	71	5	the	the	DET
eurjchem-2047	71	6	complex	complex	NOUN
eurjchem-2047	71	7	with	with	ADP
eurjchem-2047	71	8	the	the	DET
eurjchem-2047	71	9	atomic	atomic	ADJ
eurjchem-2047	71	10	numbering	numbering	NOUN
eurjchem-2047	71	11	scheme	scheme	NOUN
eurjchem-2047	71	12	is	be	AUX
eurjchem-2047	71	13	shown	show	VERB
eurjchem-2047	71	14	in	in	ADP
eurjchem-2047	71	15	figure	figure	NOUN
eurjchem-2047	71	16	1	1	NUM
eurjchem-2047	71	17	.	.	PUNCT
eurjchem-2047	72	1	the	the	DET
eurjchem-2047	72	2	reaction	reaction	NOUN
eurjchem-2047	72	3	between	between	ADP
eurjchem-2047	72	4	n-(diethylcarbamothioyl)cyclohexane	n-(diethylcarbamothioyl)cyclohexane	NOUN
eurjchem-2047	72	5	carboxamide	carboxamide	NOUN
eurjchem-2047	72	6	ligands	ligand	NOUN
eurjchem-2047	72	7	and	and	CCONJ
eurjchem-2047	72	8	copper(ii	copper(ii	NOUN
eurjchem-2047	72	9	)	)	PUNCT
eurjchem-2047	72	10	ion	ion	NOUN
eurjchem-2047	72	11	produces	produce	VERB
eurjchem-2047	72	12	a	a	DET
eurjchem-2047	72	13	metal	metal	NOUN
eurjchem-2047	72	14	complex	complex	NOUN
eurjchem-2047	72	15	with	with	ADP
eurjchem-2047	72	16	the	the	DET
eurjchem-2047	72	17	expected	expect	VERB
eurjchem-2047	72	18	metal	metal	NOUN
eurjchem-2047	72	19	:	:	PUNCT
eurjchem-2047	72	20	ligand	ligand	NOUN
eurjchem-2047	72	21	ratio	ratio	NOUN
eurjchem-2047	72	22	of	of	ADP
eurjchem-2047	72	23	1:2	1:2	NUM
eurjchem-2047	72	24	.	.	PUNCT
eurjchem-2047	73	1	the	the	DET
eurjchem-2047	73	2	chelating	chelate	VERB
eurjchem-2047	73	3	two	two	NUM
eurjchem-2047	73	4	thiourea	thiourea	NOUN
eurjchem-2047	73	5	ligands	ligand	NOUN
eurjchem-2047	73	6	are	be	AUX
eurjchem-2047	73	7	coordinated	coordinate	VERB
eurjchem-2047	73	8	with	with	ADP
eurjchem-2047	73	9	a	a	DET
eurjchem-2047	73	10	copper(ii	copper(ii	NOUN
eurjchem-2047	73	11	)	)	PUNCT
eurjchem-2047	73	12	ion	ion	NOUN
eurjchem-2047	73	13	in	in	ADP
eurjchem-2047	73	14	a	a	DET
eurjchem-2047	73	15	bidentate	bidentate	ADJ
eurjchem-2047	73	16	mode	mode	NOUN
eurjchem-2047	73	17	,	,	PUNCT
eurjchem-2047	73	18	forming	form	VERB
eurjchem-2047	73	19	two	two	NUM
eurjchem-2047	73	20	six	six	NUM
eurjchem-2047	73	21	-	-	PUNCT
eurjchem-2047	73	22	membered	membere	VERB
eurjchem-2047	73	23	chelate	chelate	NOUN
eurjchem-2047	73	24	rings	ring	NOUN
eurjchem-2047	73	25	(	(	PUNCT
eurjchem-2047	73	26	cu1	cu1	NOUN
eurjchem-2047	73	27	-	-	PUNCT
eurjchem-2047	73	28	s1	s1	NOUN
eurjchem-2047	73	29	-	-	PUNCT
eurjchem-2047	73	30	c5	c5	PROPN
eurjchem-2047	73	31	-	-	PUNCT
eurjchem-2047	73	32	n1	n1	NOUN
eurjchem-2047	73	33	-	-	PUNCT
eurjchem-2047	73	34	c6	c6	NOUN
eurjchem-2047	73	35	-	-	PUNCT
eurjchem-2047	73	36	o1	o1	NOUN
eurjchem-2047	73	37	)	)	PUNCT
eurjchem-2047	73	38	.	.	PUNCT
eurjchem-2047	74	1	the	the	DET
eurjchem-2047	74	2	six	six	NUM
eurjchem-2047	74	3	-	-	PUNCT
eurjchem-2047	74	4	membered	membere	VERB
eurjchem-2047	74	5	rings	ring	NOUN
eurjchem-2047	74	6	are	be	AUX
eurjchem-2047	74	7	formed	form	VERB
eurjchem-2047	74	8	via	via	ADP
eurjchem-2047	74	9	oxygen	oxygen	NOUN
eurjchem-2047	74	10	and	and	CCONJ
eurjchem-2047	74	11	sulphur	sulphur	NOUN
eurjchem-2047	74	12	atoms	atom	NOUN
eurjchem-2047	74	13	,	,	PUNCT
eurjchem-2047	74	14	and	and	CCONJ
eurjchem-2047	74	15	the	the	DET
eurjchem-2047	74	16	dihedral	dihedral	ADJ
eurjchem-2047	74	17	angle	angle	NOUN
eurjchem-2047	74	18	between	between	ADP
eurjchem-2047	74	19	these	these	DET
eurjchem-2047	74	20	chelate	chelate	NOUN
eurjchem-2047	74	21	rings	ring	NOUN
eurjchem-2047	74	22	in	in	ADP
eurjchem-2047	74	23	the	the	DET
eurjchem-2047	74	24	copper	copper	NOUN
eurjchem-2047	74	25	complex	complex	NOUN
eurjchem-2047	74	26	is	be	AUX
eurjchem-2047	74	27	44.96	44.96	NUM
eurjchem-2047	74	28	°	°	NOUN
eurjchem-2047	74	29	(	(	PUNCT
eurjchem-2047	74	30	figure	figure	NOUN
eurjchem-2047	74	31	2	2	NUM
eurjchem-2047	74	32	)	)	PUNCT
eurjchem-2047	74	33	.	.	PUNCT
eurjchem-2047	75	1	the	the	DET
eurjchem-2047	75	2	bond	bond	NOUN
eurjchem-2047	75	3	angles	angle	VERB
eurjchem-2047	75	4	around	around	ADP
eurjchem-2047	75	5	the	the	DET
eurjchem-2047	75	6	copper	copper	NOUN
eurjchem-2047	75	7	ion	ion	NOUN
eurjchem-2047	75	8	are	be	AUX
eurjchem-2047	75	9	s1	s1	NOUN
eurjchem-2047	75	10	-	-	PUNCT
eurjchem-2047	75	11	cu1	cu1	NOUN
eurjchem-2047	75	12	-	-	PUNCT
eurjchem-2047	75	13	o1	o1	NOUN
eurjchem-2047	75	14	=	=	SYM
eurjchem-2047	75	15	95.97(5	95.97(5	NOUN
eurjchem-2047	75	16	)	)	PUNCT
eurjchem-2047	75	17	°	°	NOUN
eurjchem-2047	75	18	and	and	CCONJ
eurjchem-2047	75	19	s1i	s1i	PROPN
eurjchem-2047	75	20	-	-	PUNCT
eurjchem-2047	75	21	cu1	cu1	NOUN
eurjchem-2047	75	22	-	-	PUNCT
eurjchem-2047	75	23	s1	s1	NOUN
eurjchem-2047	75	24	=	=	SYM
eurjchem-2047	75	25	92.94(4	92.94(4	NOUN
eurjchem-2047	75	26	)	)	PUNCT
eurjchem-2047	75	27	°	°	NOUN
eurjchem-2047	76	1	(	(	PUNCT
eurjchem-2047	76	2	i	i	PRON
eurjchem-2047	76	3	-x	-x	PROPN
eurjchem-2047	76	4	,	,	PUNCT
eurjchem-2047	76	5	+	+	NOUN
eurjchem-2047	76	6	y	y	PROPN
eurjchem-2047	76	7	,	,	PUNCT
eurjchem-2047	76	8	1	1	NUM
eurjchem-2047	76	9	-	-	SYM
eurjchem-2047	76	10	z	z	NOUN
eurjchem-2047	76	11	)	)	PUNCT
eurjchem-2047	76	12	for	for	ADP
eurjchem-2047	76	13	cis-[cul2	cis-[cul2	PROPN
eurjchem-2047	76	14	]	]	PUNCT
eurjchem-2047	76	15	,	,	PUNCT
eurjchem-2047	76	16	so	so	CCONJ
eurjchem-2047	76	17	the	the	DET
eurjchem-2047	76	18	bite	bite	NOUN
eurjchem-2047	76	19	angles	angle	NOUN
eurjchem-2047	76	20	of	of	ADP
eurjchem-2047	76	21	the	the	DET
eurjchem-2047	76	22	complex	complex	ADJ
eurjchem-2047	76	23	deviate	deviate	NOUN
eurjchem-2047	76	24	slightly	slightly	ADV
eurjchem-2047	76	25	from	from	ADP
eurjchem-2047	76	26	the	the	DET
eurjchem-2047	76	27	ideal	ideal	ADJ
eurjchem-2047	76	28	angle	angle	NOUN
eurjchem-2047	76	29	(	(	PUNCT
eurjchem-2047	76	30	90	90	NUM
eurjchem-2047	76	31	°	°	NUM
eurjchem-2047	76	32	)	)	PUNCT
eurjchem-2047	77	1	[	[	X
eurjchem-2047	77	2	69	69	NUM
eurjchem-2047	77	3	]	]	PUNCT
eurjchem-2047	77	4	.	.	PUNCT
eurjchem-2047	78	1	the	the	DET
eurjchem-2047	78	2	copper	copper	NOUN
eurjchem-2047	78	3	center	center	NOUN
eurjchem-2047	78	4	,	,	PUNCT
eurjchem-2047	78	5	surrounded	surround	VERB
eurjchem-2047	78	6	by	by	ADP
eurjchem-2047	78	7	oxygen	oxygen	NOUN
eurjchem-2047	78	8	and	and	CCONJ
eurjchem-2047	78	9	sulphur	sulphur	NOUN
eurjchem-2047	78	10	atoms	atom	NOUN
eurjchem-2047	78	11	in	in	ADP
eurjchem-2047	78	12	the	the	DET
eurjchem-2047	78	13	complex	complex	ADJ
eurjchem-2047	78	14	form	form	NOUN
eurjchem-2047	78	15	,	,	PUNCT
eurjchem-2047	78	16	has	have	VERB
eurjchem-2047	78	17	a	a	DET
eurjchem-2047	78	18	distorted	distort	VERB
eurjchem-2047	78	19	square	square	ADJ
eurjchem-2047	78	20	planar	planar	ADJ
eurjchem-2047	78	21	geometry	geometry	NOUN
eurjchem-2047	78	22	as	as	SCONJ
eurjchem-2047	78	23	shown	show	VERB
eurjchem-2047	78	24	in	in	ADP
eurjchem-2047	78	25	figure	figure	NOUN
eurjchem-2047	78	26	1	1	NUM
eurjchem-2047	78	27	.	.	PUNCT
eurjchem-2047	79	1	the	the	DET
eurjchem-2047	79	2	sum	sum	NOUN
eurjchem-2047	79	3	of	of	ADP
eurjchem-2047	79	4	the	the	DET
eurjchem-2047	79	5	equatorial	equatorial	NOUN
eurjchem-2047	79	6	angles	angle	VERB
eurjchem-2047	79	7	s1	s1	NOUN
eurjchem-2047	79	8	-	-	PUNCT
eurjchem-2047	79	9	cu1	cu1	NOUN
eurjchem-2047	79	10	-	-	PUNCT
eurjchem-2047	79	11	o1	o1	NOUN
eurjchem-2047	79	12	,	,	PUNCT
eurjchem-2047	79	13	s1	s1	NOUN
eurjchem-2047	79	14	-	-	PUNCT
eurjchem-2047	79	15	cu1	cu1	NOUN
eurjchem-2047	79	16	-	-	PUNCT
eurjchem-2047	79	17	s1i	s1i	PROPN
eurjchem-2047	79	18	,	,	PUNCT
eurjchem-2047	79	19	o1	o1	NOUN
eurjchem-2047	79	20	-	-	PUNCT
eurjchem-2047	79	21	cu1o1i	cu1o1i	NOUN
eurjchem-2047	79	22	,	,	PUNCT
eurjchem-2047	79	23	and	and	CCONJ
eurjchem-2047	79	24	o1i	o1i	NUM
eurjchem-2047	79	25	-	-	PUNCT
eurjchem-2047	79	26	cu1	cu1	NOUN
eurjchem-2047	79	27	-	-	PUNCT
eurjchem-2047	79	28	s1i	s1i	PROPN
eurjchem-2047	79	29	(	(	PUNCT
eurjchem-2047	79	30	i	i	NOUN
eurjchem-2047	79	31	-x	-x	PROPN
eurjchem-2047	79	32	,	,	PUNCT
eurjchem-2047	79	33	+	+	NOUN
eurjchem-2047	79	34	y	y	PROPN
eurjchem-2047	79	35	,	,	PUNCT
eurjchem-2047	79	36	1	1	NUM
eurjchem-2047	79	37	-	-	SYM
eurjchem-2047	79	38	z	z	NOUN
eurjchem-2047	79	39	)	)	PUNCT
eurjchem-2047	79	40	are	be	AUX
eurjchem-2047	79	41	373.20	373.20	NUM
eurjchem-2047	79	42	°	°	NOUN
eurjchem-2047	79	43	,	,	PUNCT
eurjchem-2047	79	44	which	which	PRON
eurjchem-2047	79	45	is	be	AUX
eurjchem-2047	79	46	consistent	consistent	ADJ
eurjchem-2047	79	47	with	with	ADP
eurjchem-2047	79	48	distorted	distorted	ADJ
eurjchem-2047	79	49	square	square	ADJ
eurjchem-2047	79	50	planar	planar	ADJ
eurjchem-2047	79	51	geometry	geometry	NOUN
eurjchem-2047	79	52	.	.	PUNCT
eurjchem-2047	80	1	in	in	ADP
eurjchem-2047	80	2	addition	addition	NOUN
eurjchem-2047	80	3	,	,	PUNCT
eurjchem-2047	80	4	it	it	PRON
eurjchem-2047	80	5	is	be	AUX
eurjchem-2047	80	6	clear	clear	ADJ
eurjchem-2047	80	7	that	that	SCONJ
eurjchem-2047	80	8	the	the	DET
eurjchem-2047	80	9	τ4	τ4	PROPN
eurjchem-2047	80	10	parameter	parameter	NOUN
eurjchem-2047	80	11	is	be	AUX
eurjchem-2047	80	12	essential	essential	ADJ
eurjchem-2047	80	13	for	for	ADP
eurjchem-2047	80	14	four	four	NUM
eurjchem-2047	80	15	-	-	PUNCT
eurjchem-2047	80	16	coordinate	coordinate	NOUN
eurjchem-2047	80	17	transition	transition	NOUN
eurjchem-2047	80	18	metal	metal	NOUN
eurjchem-2047	80	19	complexes	complex	NOUN
eurjchem-2047	80	20	since	since	SCONJ
eurjchem-2047	80	21	square	square	ADJ
eurjchem-2047	80	22	planar	planar	ADJ
eurjchem-2047	80	23	and	and	CCONJ
eurjchem-2047	80	24	tetrahedral	tetrahedral	ADJ
eurjchem-2047	80	25	geometries	geometry	NOUN
eurjchem-2047	80	26	are	be	AUX
eurjchem-2047	80	27	the	the	DET
eurjchem-2047	80	28	extremes	extreme	NOUN
eurjchem-2047	81	1	[	[	X
eurjchem-2047	81	2	70	70	NUM
eurjchem-2047	81	3	]	]	PUNCT
eurjchem-2047	81	4	.	.	PUNCT
eurjchem-2047	82	1	the	the	DET
eurjchem-2047	82	2	angular	angular	ADJ
eurjchem-2047	82	3	structural	structural	ADJ
eurjchem-2047	82	4	index	index	NOUN
eurjchem-2047	82	5	parameter	parameter	NOUN
eurjchem-2047	82	6	,	,	PUNCT
eurjchem-2047	82	7	τ4	τ4	PROPN
eurjchem-2047	82	8	=	=	PUNCT
eurjchem-2047	82	9	(	(	PUNCT
eurjchem-2047	82	10	360-(β+α))/141	360-(β+α))/141	NUM
eurjchem-2047	82	11	,	,	PUNCT
eurjchem-2047	82	12	evaluated	evaluate	VERB
eurjchem-2047	82	13	from	from	ADP
eurjchem-2047	82	14	the	the	DET
eurjchem-2047	82	15	two	two	NUM
eurjchem-2047	82	16	largest	large	ADJ
eurjchem-2047	82	17	angles	angle	NOUN
eurjchem-2047	82	18	in	in	ADP
eurjchem-2047	82	19	the	the	DET
eurjchem-2047	82	20	four	four	NUM
eurjchem-2047	82	21	-	-	PUNCT
eurjchem-2047	82	22	coordinated	coordinate	VERB
eurjchem-2047	82	23	geometry	geometry	NOUN
eurjchem-2047	82	24	,	,	PUNCT
eurjchem-2047	82	25	which	which	PRON
eurjchem-2047	82	26	has	have	VERB
eurjchem-2047	82	27	ideal	ideal	ADJ
eurjchem-2047	82	28	values	value	NOUN
eurjchem-2047	82	29	of	of	ADP
eurjchem-2047	82	30	1	1	NUM
eurjchem-2047	82	31	for	for	ADP
eurjchem-2047	82	32	a	a	DET
eurjchem-2047	82	33	perfect	perfect	ADJ
eurjchem-2047	82	34	tetrahedral	tetrahedral	ADJ
eurjchem-2047	82	35	geometry	geometry	NOUN
eurjchem-2047	82	36	and	and	CCONJ
eurjchem-2047	82	37	0	0	NUM
eurjchem-2047	82	38	for	for	ADP
eurjchem-2047	82	39	a	a	DET
eurjchem-2047	82	40	perfect	perfect	ADJ
eurjchem-2047	82	41	square	square	ADJ
eurjchem-2047	82	42	planar	planar	ADJ
eurjchem-2047	82	43	geometry	geometry	NOUN
eurjchem-2047	82	44	,	,	PUNCT
eurjchem-2047	82	45	is	be	AUX
eurjchem-2047	82	46	equal	equal	ADJ
eurjchem-2047	82	47	to	to	ADP
eurjchem-2047	82	48	0.40	0.40	NUM
eurjchem-2047	82	49	,	,	PUNCT
eurjchem-2047	82	50	which	which	PRON
eurjchem-2047	82	51	confirms	confirm	VERB
eurjchem-2047	82	52	the	the	DET
eurjchem-2047	82	53	distorted	distorted	ADJ
eurjchem-2047	82	54	square	square	ADJ
eurjchem-2047	82	55	planar	planar	ADJ
eurjchem-2047	82	56	geometry	geometry	NOUN
eurjchem-2047	82	57	for	for	ADP
eurjchem-2047	82	58	the	the	DET
eurjchem-2047	82	59	title	title	NOUN
eurjchem-2047	82	60	compound	compound	NOUN
eurjchem-2047	82	61	.	.	PUNCT
eurjchem-2047	83	1	the	the	DET
eurjchem-2047	83	2	distance	distance	NOUN
eurjchem-2047	83	3	of	of	ADP
eurjchem-2047	83	4	copper	copper	NOUN
eurjchem-2047	83	5	atom	atom	NOUN
eurjchem-2047	83	6	from	from	ADP
eurjchem-2047	83	7	the	the	DET
eurjchem-2047	83	8	best	good	ADJ
eurjchem-2047	83	9	plane	plane	NOUN
eurjchem-2047	83	10	through	through	ADP
eurjchem-2047	83	11	the	the	DET
eurjchem-2047	83	12	coordination	coordination	NOUN
eurjchem-2047	83	13	sphere	sphere	NOUN
eurjchem-2047	83	14	is	be	AUX
eurjchem-2047	83	15	0.000	0.000	NUM
eurjchem-2047	83	16	å	å	NOUN
eurjchem-2047	83	17	.	.	PUNCT
eurjchem-2047	84	1	the	the	DET
eurjchem-2047	84	2	deviations	deviation	NOUN
eurjchem-2047	84	3	from	from	ADP
eurjchem-2047	84	4	the	the	DET
eurjchem-2047	84	5	best	good	ADJ
eurjchem-2047	84	6	plane	plane	NOUN
eurjchem-2047	84	7	(	(	PUNCT
eurjchem-2047	84	8	o1	o1	NOUN
eurjchem-2047	84	9	/	/	SYM
eurjchem-2047	84	10	s1	s1	PROPN
eurjchem-2047	84	11	/	/	SYM
eurjchem-2047	84	12	cu	cu	PROPN
eurjchem-2047	84	13	/	/	SYM
eurjchem-2047	84	14	s1i	s1i	PROPN
eurjchem-2047	84	15	/	/	SYM
eurjchem-2047	84	16	oi	oi	PROPN
eurjchem-2047	84	17	;	;	PUNCT
eurjchem-2047	84	18	i	i	PRON
eurjchem-2047	84	19	-x	-x	PROPN
eurjchem-2047	84	20	,	,	PUNCT
eurjchem-2047	84	21	+	+	NOUN
eurjchem-2047	84	22	y	y	PROPN
eurjchem-2047	84	23	,	,	PUNCT
eurjchem-2047	84	24	1	1	NUM
eurjchem-2047	84	25	-	-	SYM
eurjchem-2047	84	26	z	z	NOUN
eurjchem-2047	84	27	)	)	PUNCT
eurjchem-2047	84	28	are	be	AUX
eurjchem-2047	84	29	0.548(2	0.548(2	NOUN
eurjchem-2047	84	30	)	)	PUNCT
eurjchem-2047	84	31	and	and	CCONJ
eurjchem-2047	84	32	0.428(2	0.428(2	NUM
eurjchem-2047	84	33	)	)	PUNCT
eurjchem-2047	84	34	å	å	PROPN
eurjchem-2047	84	35	for	for	ADP
eurjchem-2047	84	36	o1	o1	NOUN
eurjchem-2047	84	37	and	and	CCONJ
eurjchem-2047	84	38	s1	s1	NOUN
eurjchem-2047	84	39	atoms	atom	NOUN
eurjchem-2047	84	40	,	,	PUNCT
eurjchem-2047	84	41	respectively	respectively	ADV
eurjchem-2047	84	42	.	.	PUNCT
eurjchem-2047	85	1	ozer	ozer	NOUN
eurjchem-2047	85	2	et	et	PROPN
eurjchem-2047	85	3	al	al	PROPN
eurjchem-2047	85	4	.	.	PUNCT
eurjchem-2047	85	5	/	/	SYM
eurjchem-2047	85	6	european	european	PROPN
eurjchem-2047	85	7	journal	journal	PROPN
eurjchem-2047	85	8	of	of	ADP
eurjchem-2047	85	9	chemistry	chemistry	NOUN
eurjchem-2047	85	10	11	11	NUM
eurjchem-2047	85	11	(	(	PUNCT
eurjchem-2047	85	12	4	4	NUM
eurjchem-2047	85	13	)	)	PUNCT
eurjchem-2047	85	14	(	(	PUNCT
eurjchem-2047	85	15	2020	2020	NUM
eurjchem-2047	85	16	)	)	PUNCT
eurjchem-2047	85	17	319	319	NUM
eurjchem-2047	85	18	-	-	SYM
eurjchem-2047	85	19	323	323	NUM
eurjchem-2047	85	20	321	321	NUM
eurjchem-2047	85	21	2020	2020	NUM
eurjchem-2047	85	22	–	–	PUNCT
eurjchem-2047	85	23	european	european	ADJ
eurjchem-2047	85	24	journal	journal	NOUN
eurjchem-2047	85	25	of	of	ADP
eurjchem-2047	85	26	chemistry	chemistry	NOUN
eurjchem-2047	85	27	–	–	PUNCT
eurjchem-2047	85	28	cc	cc	NOUN
eurjchem-2047	85	29	by	by	ADP
eurjchem-2047	85	30	nc	nc	PROPN
eurjchem-2047	85	31	–	–	PUNCT
eurjchem-2047	85	32	doi	doi	NOUN
eurjchem-2047	85	33	:	:	PUNCT
eurjchem-2047	85	34	10.5155	10.5155	NUM
eurjchem-2047	85	35	/	/	SYM
eurjchem-2047	85	36	eurjchem.11.4.319	eurjchem.11.4.319	ADJ
eurjchem-2047	85	37	-	-	PUNCT
eurjchem-2047	85	38	323.2047	323.2047	NUM
eurjchem-2047	85	39	table	table	NOUN
eurjchem-2047	85	40	1	1	NUM
eurjchem-2047	85	41	.	.	PUNCT
eurjchem-2047	85	42	crystal	crystal	NOUN
eurjchem-2047	85	43	data	datum	NOUN
eurjchem-2047	85	44	and	and	CCONJ
eurjchem-2047	85	45	structure	structure	NOUN
eurjchem-2047	85	46	refinement	refinement	NOUN
eurjchem-2047	85	47	for	for	ADP
eurjchem-2047	85	48	[	[	NOUN
eurjchem-2047	85	49	cu(l	cu(l	NOUN
eurjchem-2047	85	50	-	-	PUNCT
eurjchem-2047	85	51	κ2s	κ2	NOUN
eurjchem-2047	85	52	,	,	PUNCT
eurjchem-2047	85	53	o)2	o)2	PROPN
eurjchem-2047	85	54	]	]	PUNCT
eurjchem-2047	85	55	.	.	PUNCT
eurjchem-2047	86	1	empirical	empirical	ADJ
eurjchem-2047	86	2	formula	formula	NOUN
eurjchem-2047	86	3	c24h42cun4o2s2	c24h42cun4o2s2	NOUN
eurjchem-2047	86	4	formula	formula	NOUN
eurjchem-2047	86	5	weight	weight	NOUN
eurjchem-2047	86	6	546.28	546.28	NUM
eurjchem-2047	86	7	temperature	temperature	NOUN
eurjchem-2047	86	8	(	(	PUNCT
eurjchem-2047	86	9	k	k	NOUN
eurjchem-2047	86	10	)	)	PUNCT
eurjchem-2047	86	11	153(2	153(2	NUM
eurjchem-2047	86	12	)	)	PUNCT
eurjchem-2047	86	13	crystal	crystal	NOUN
eurjchem-2047	86	14	system	system	NOUN
eurjchem-2047	86	15	monoclinic	monoclinic	ADJ
eurjchem-2047	86	16	space	space	NOUN
eurjchem-2047	86	17	group	group	NOUN
eurjchem-2047	86	18	c2	c2	PROPN
eurjchem-2047	86	19	a	a	DET
eurjchem-2047	86	20	(	(	PUNCT
eurjchem-2047	86	21	å	å	NOUN
eurjchem-2047	86	22	)	)	PUNCT
eurjchem-2047	86	23	14.848(3	14.848(3	PROPN
eurjchem-2047	86	24	)	)	PUNCT
eurjchem-2047	86	25	b	b	PROPN
eurjchem-2047	86	26	(	(	PUNCT
eurjchem-2047	86	27	å	å	NOUN
eurjchem-2047	86	28	)	)	PUNCT
eurjchem-2047	86	29	10.543(2	10.543(2	NUM
eurjchem-2047	86	30	)	)	PUNCT
eurjchem-2047	87	1	c	c	NOUN
eurjchem-2047	87	2	(	(	PUNCT
eurjchem-2047	87	3	å	å	NOUN
eurjchem-2047	87	4	)	)	PUNCT
eurjchem-2047	87	5	10.511(2	10.511(2	NUM
eurjchem-2047	87	6	)	)	PUNCT
eurjchem-2047	87	7	β	β	PROPN
eurjchem-2047	87	8	(	(	PUNCT
eurjchem-2047	87	9	°	°	PROPN
eurjchem-2047	87	10	)	)	PUNCT
eurjchem-2047	87	11	123.84(3	123.84(3	NUM
eurjchem-2047	87	12	)	)	PUNCT
eurjchem-2047	87	13	volume	volume	NOUN
eurjchem-2047	87	14	(	(	PUNCT
eurjchem-2047	87	15	å3	å3	PROPN
eurjchem-2047	87	16	)	)	PUNCT
eurjchem-2047	87	17	1366.7(7	1366.7(7	NOUN
eurjchem-2047	87	18	)	)	PUNCT
eurjchem-2047	87	19	z	z	NOUN
eurjchem-2047	87	20	2	2	NUM
eurjchem-2047	87	21	ρcalc	ρcalc	NOUN
eurjchem-2047	87	22	(	(	PUNCT
eurjchem-2047	87	23	g	g	NOUN
eurjchem-2047	87	24	/	/	SYM
eurjchem-2047	87	25	cm3	cm3	NOUN
eurjchem-2047	87	26	)	)	PUNCT
eurjchem-2047	87	27	1.327	1.327	NUM
eurjchem-2047	87	28	μ	μ	NOUN
eurjchem-2047	87	29	(	(	PUNCT
eurjchem-2047	87	30	mm-1	mm-1	NOUN
eurjchem-2047	87	31	)	)	PUNCT
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eurjchem-2047	87	33	f(000	f(000	NOUN
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eurjchem-2047	87	38	(	(	PUNCT
eurjchem-2047	87	39	mm3	mm3	NOUN
eurjchem-2047	87	40	)	)	PUNCT
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eurjchem-2047	87	43	0.22	0.22	NUM
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eurjchem-2047	87	48	(	(	PUNCT
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eurjchem-2047	87	50	=	=	SYM
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eurjchem-2047	87	52	å	å	NOUN
eurjchem-2047	87	53	)	)	PUNCT
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eurjchem-2047	87	59	(	(	PUNCT
eurjchem-2047	87	60	°	°	PROPN
eurjchem-2047	87	61	)	)	PUNCT
eurjchem-2047	87	62	6.6	6.6	NUM
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eurjchem-2047	87	64	50.68	50.68	NUM
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eurjchem-2047	87	66	ranges	range	VERB
eurjchem-2047	87	67	-17	-17	PUNCT
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eurjchem-2047	87	69	h	h	NOUN
eurjchem-2047	87	70	≤	≤	NOUN
eurjchem-2047	87	71	17	17	NUM
eurjchem-2047	87	72	,	,	PUNCT
eurjchem-2047	87	73	-12	-12	PROPN
eurjchem-2047	87	74	≤	≤	NUM
eurjchem-2047	87	75	k	k	X
eurjchem-2047	87	76	≤	≤	NUM
eurjchem-2047	87	77	10	10	NUM
eurjchem-2047	87	78	,	,	PUNCT
eurjchem-2047	87	79	-12	-12	PROPN
eurjchem-2047	87	80	≤	≤	NUM
eurjchem-2047	87	81	l	l	NOUN
eurjchem-2047	87	82	≤	≤	NUM
eurjchem-2047	87	83	12	12	NUM
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eurjchem-2047	87	85	collected	collect	VERB
eurjchem-2047	87	86	4979	4979	NUM
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eurjchem-2047	87	88	reflections	reflection	NOUN
eurjchem-2047	87	89	2243	2243	NUM
eurjchem-2047	88	1	[	[	X
eurjchem-2047	88	2	rint	rint	X
eurjchem-2047	88	3	=	=	SYM
eurjchem-2047	88	4	0.0223	0.0223	NUM
eurjchem-2047	88	5	,	,	PUNCT
eurjchem-2047	88	6	rsigma	rsigma	ADJ
eurjchem-2047	88	7	=	=	PUNCT
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eurjchem-2047	88	9	]	]	PUNCT
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eurjchem-2047	88	13	/	/	SYM
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eurjchem-2047	88	15	2243/1/153	2243/1/153	NUM
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eurjchem-2047	88	17	-	-	PUNCT
eurjchem-2047	88	18	of	of	ADP
eurjchem-2047	88	19	-	-	PUNCT
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eurjchem-2047	88	21	on	on	ADP
eurjchem-2047	88	22	f2	f2	PROPN
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eurjchem-2047	88	26	indexes	index	NOUN
eurjchem-2047	88	27	[	[	X
eurjchem-2047	88	28	i≥2σ	i≥2σ	X
eurjchem-2047	88	29	(	(	PUNCT
eurjchem-2047	88	30	i	i	NOUN
eurjchem-2047	88	31	)	)	PUNCT
eurjchem-2047	88	32	]	]	PUNCT
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eurjchem-2047	89	2	=	=	SYM
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eurjchem-2047	89	4	,	,	PUNCT
eurjchem-2047	89	5	wr2	wr2	PROPN
eurjchem-2047	89	6	=	=	PROPN
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eurjchem-2047	89	9	r	r	NOUN
eurjchem-2047	89	10	indexes	index	NOUN
eurjchem-2047	89	11	[	[	X
eurjchem-2047	89	12	all	all	DET
eurjchem-2047	89	13	data	datum	NOUN
eurjchem-2047	89	14	]	]	PUNCT
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eurjchem-2047	89	16	=	=	PUNCT
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eurjchem-2047	89	23	diff	diff	NOUN
eurjchem-2047	89	24	.	.	PUNCT
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eurjchem-2047	90	3	(	(	PUNCT
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eurjchem-2047	90	5	)	)	PUNCT
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eurjchem-2047	90	10	)	)	PUNCT
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eurjchem-2047	90	12	2	2	NUM
eurjchem-2047	90	13	.	.	PUNCT
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eurjchem-2047	91	2	lengths	length	NOUN
eurjchem-2047	91	3	and	and	CCONJ
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eurjchem-2047	91	6	[	[	X
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eurjchem-2047	91	10	,	,	PUNCT
eurjchem-2047	91	11	o)2	o)2	PROPN
eurjchem-2047	91	12	]	]	PUNCT
eurjchem-2047	91	13	.	.	PUNCT
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eurjchem-2047	92	2	distance	distance	NOUN
eurjchem-2047	92	3	(	(	PUNCT
eurjchem-2047	92	4	å	å	NOUN
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eurjchem-2047	92	8	(	(	PUNCT
eurjchem-2047	92	9	å	å	NOUN
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eurjchem-2047	92	23	s1	s1	NOUN
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eurjchem-2047	92	25	)	)	PUNCT
eurjchem-2047	92	26	c1	c1	PROPN
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eurjchem-2047	92	28	c2	c2	PROPN
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eurjchem-2047	92	33	o1	o1	NOUN
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eurjchem-2047	92	53	c5	c5	PROPN
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eurjchem-2047	92	58	c8	c8	PROPN
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eurjchem-2047	92	63	c6	c6	PROPN
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eurjchem-2047	92	67	-	-	PUNCT
eurjchem-2047	92	68	c12	c12	PROPN
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eurjchem-2047	92	71	n1	n1	PROPN
eurjchem-2047	92	72	-	-	PUNCT
eurjchem-2047	92	73	c5	c5	PROPN
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eurjchem-2047	92	75	)	)	PUNCT
eurjchem-2047	92	76	c8	c8	NOUN
eurjchem-2047	92	77	-	-	PUNCT
eurjchem-2047	92	78	c9	c9	NOUN
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eurjchem-2047	92	81	n1	n1	PROPN
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eurjchem-2047	92	83	c6	c6	PROPN
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eurjchem-2047	92	85	)	)	PUNCT
eurjchem-2047	92	86	c9	c9	NOUN
eurjchem-2047	92	87	-	-	PUNCT
eurjchem-2047	92	88	c10	c10	PROPN
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eurjchem-2047	92	90	)	)	PUNCT
eurjchem-2047	92	91	n2	n2	ADJ
eurjchem-2047	92	92	-	-	PUNCT
eurjchem-2047	92	93	c1	c1	PROPN
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eurjchem-2047	92	95	)	)	PUNCT
eurjchem-2047	92	96	c10	c10	VERB
eurjchem-2047	92	97	-	-	PUNCT
eurjchem-2047	92	98	c11	c11	NOUN
eurjchem-2047	92	99	1.517(4	1.517(4	NUM
eurjchem-2047	92	100	)	)	PUNCT
eurjchem-2047	92	101	n2	n2	ADJ
eurjchem-2047	92	102	-	-	PUNCT
eurjchem-2047	92	103	c3	c3	NOUN
eurjchem-2047	92	104	1.464(3	1.464(3	NUM
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eurjchem-2047	92	108	c12	c12	NOUN
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eurjchem-2047	92	113	(	(	PUNCT
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eurjchem-2047	92	119	°	°	NOUN
eurjchem-2047	92	120	)	)	PUNCT
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eurjchem-2047	92	122	-	-	PUNCT
eurjchem-2047	92	123	cu1	cu1	NOUN
eurjchem-2047	92	124	-	-	PUNCT
eurjchem-2047	92	125	s1	s1	NOUN
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eurjchem-2047	92	130	c5	c5	PROPN
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eurjchem-2047	92	132	s1	s1	PROPN
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eurjchem-2047	92	134	)	)	PUNCT
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eurjchem-2047	92	136	-	-	PUNCT
eurjchem-2047	92	137	cu1	cu1	NOUN
eurjchem-2047	92	138	-	-	PUNCT
eurjchem-2047	92	139	s11	s11	NOUN
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eurjchem-2047	92	143	-	-	PUNCT
eurjchem-2047	92	144	c5	c5	PROPN
eurjchem-2047	92	145	-	-	PUNCT
eurjchem-2047	92	146	s1	s1	PROPN
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eurjchem-2047	92	148	)	)	PUNCT
eurjchem-2047	92	149	o11	o11	NOUN
eurjchem-2047	92	150	-	-	PUNCT
eurjchem-2047	92	151	cu1	cu1	NOUN
eurjchem-2047	92	152	-	-	PUNCT
eurjchem-2047	92	153	s1	s1	NOUN
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eurjchem-2047	92	155	)	)	PUNCT
eurjchem-2047	92	156	n2	n2	ADJ
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eurjchem-2047	92	158	c5	c5	PROPN
eurjchem-2047	92	159	-	-	PUNCT
eurjchem-2047	92	160	n1	n1	NOUN
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eurjchem-2047	92	162	)	)	PUNCT
eurjchem-2047	92	163	o1	o1	NOUN
eurjchem-2047	92	164	-	-	PUNCT
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eurjchem-2047	92	166	-	-	PUNCT
eurjchem-2047	92	167	s1	s1	NOUN
eurjchem-2047	92	168	95.97(5	95.97(5	PROPN
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eurjchem-2047	92	172	c6	c6	PROPN
eurjchem-2047	92	173	-	-	PUNCT
eurjchem-2047	92	174	n1	n1	NOUN
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eurjchem-2047	92	176	)	)	PUNCT
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eurjchem-2047	92	179	cu1	cu1	NOUN
eurjchem-2047	92	180	-	-	PUNCT
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eurjchem-2047	92	188	c7	c7	PROPN
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eurjchem-2047	92	197	)	)	PUNCT
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eurjchem-2047	92	202	c7	c7	PROPN
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eurjchem-2047	92	216	c8	c8	PROPN
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eurjchem-2047	92	237	c5	c5	PROPN
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eurjchem-2047	92	249	n2	n2	ADJ
eurjchem-2047	92	250	-	-	PUNCT
eurjchem-2047	92	251	c1	c1	NOUN
eurjchem-2047	92	252	115.54(17	115.54(17	VERB
eurjchem-2047	92	253	)	)	PUNCT
eurjchem-2047	92	254	c9	c9	NOUN
eurjchem-2047	92	255	-	-	PUNCT
eurjchem-2047	92	256	c8	c8	PROPN
eurjchem-2047	92	257	-	-	PUNCT
eurjchem-2047	92	258	c7	c7	PROPN
eurjchem-2047	92	259	111.11(19	111.11(19	PROPN
eurjchem-2047	92	260	)	)	PUNCT
eurjchem-2047	92	261	c5	c5	PROPN
eurjchem-2047	92	262	-	-	PUNCT
eurjchem-2047	92	263	n2	n2	NOUN
eurjchem-2047	92	264	-	-	PUNCT
eurjchem-2047	92	265	c1	c1	NOUN
eurjchem-2047	92	266	120.86(19	120.86(19	NOUN
eurjchem-2047	92	267	)	)	PUNCT
eurjchem-2047	92	268	c8	c8	NOUN
eurjchem-2047	92	269	-	-	PUNCT
eurjchem-2047	92	270	c9	c9	NOUN
eurjchem-2047	92	271	-	-	PUNCT
eurjchem-2047	92	272	c10	c10	PROPN
eurjchem-2047	92	273	110.84(19	110.84(19	PROPN
eurjchem-2047	92	274	)	)	PUNCT
eurjchem-2047	92	275	c5	c5	PROPN
eurjchem-2047	92	276	-	-	PUNCT
eurjchem-2047	92	277	n2	n2	NOUN
eurjchem-2047	92	278	-	-	PUNCT
eurjchem-2047	92	279	c3	c3	NOUN
eurjchem-2047	92	280	123.59(19	123.59(19	NUM
eurjchem-2047	92	281	)	)	PUNCT
eurjchem-2047	92	282	c11	c11	NOUN
eurjchem-2047	92	283	-	-	PUNCT
eurjchem-2047	92	284	c10	c10	VERB
eurjchem-2047	92	285	-	-	PUNCT
eurjchem-2047	92	286	c9	c9	NOUN
eurjchem-2047	92	287	111.1(2	111.1(2	NUM
eurjchem-2047	92	288	)	)	PUNCT
eurjchem-2047	92	289	n2	n2	ADJ
eurjchem-2047	92	290	-	-	PUNCT
eurjchem-2047	92	291	c1	c1	NOUN
eurjchem-2047	92	292	-	-	PUNCT
eurjchem-2047	92	293	c2	c2	PROPN
eurjchem-2047	92	294	111.62(19	111.62(19	NUM
eurjchem-2047	92	295	)	)	PUNCT
eurjchem-2047	92	296	c10	c10	VERB
eurjchem-2047	92	297	-	-	PUNCT
eurjchem-2047	92	298	c11	c11	NOUN
eurjchem-2047	92	299	-	-	PUNCT
eurjchem-2047	92	300	c12	c12	NOUN
eurjchem-2047	92	301	111.5(2	111.5(2	NUM
eurjchem-2047	92	302	)	)	PUNCT
eurjchem-2047	92	303	n2	n2	ADJ
eurjchem-2047	92	304	-	-	PUNCT
eurjchem-2047	92	305	c3	c3	NOUN
eurjchem-2047	92	306	-	-	PUNCT
eurjchem-2047	92	307	c4	c4	ADJ
eurjchem-2047	92	308	112.4(2	112.4(2	NUM
eurjchem-2047	92	309	)	)	PUNCT
eurjchem-2047	92	310	c11	c11	NOUN
eurjchem-2047	92	311	-	-	PUNCT
eurjchem-2047	92	312	c12	c12	NOUN
eurjchem-2047	92	313	-	-	PUNCT
eurjchem-2047	92	314	c7	c7	PROPN
eurjchem-2047	92	315	111.12(19	111.12(19	NUM
eurjchem-2047	92	316	)	)	PUNCT
eurjchem-2047	92	317	1	1	NUM
eurjchem-2047	92	318	symmetry	symmetry	NOUN
eurjchem-2047	92	319	code	code	NOUN
eurjchem-2047	92	320	:	:	PUNCT
eurjchem-2047	92	321	-x	-x	PROPN
eurjchem-2047	92	322	,	,	PUNCT
eurjchem-2047	92	323	+	+	NOUN
eurjchem-2047	92	324	y	y	PROPN
eurjchem-2047	92	325	,	,	PUNCT
eurjchem-2047	92	326	1	1	NUM
eurjchem-2047	92	327	-	-	PUNCT
eurjchem-2047	92	328	z.	z.	PROPN
eurjchem-2047	92	329	figure	figure	NOUN
eurjchem-2047	92	330	1	1	NUM
eurjchem-2047	92	331	.	.	PUNCT
eurjchem-2047	93	1	the	the	DET
eurjchem-2047	93	2	molecular	molecular	ADJ
eurjchem-2047	93	3	structure	structure	NOUN
eurjchem-2047	93	4	of	of	ADP
eurjchem-2047	93	5	bis(n-(diethylcarbamothioyl)cyclohexane	bis(n-(diethylcarbamothioyl)cyclohexane	PROPN
eurjchem-2047	93	6	carboxamido)copper(ii	carboxamido)copper(ii	PROPN
eurjchem-2047	93	7	)	)	PUNCT
eurjchem-2047	93	8	complex	complex	NOUN
eurjchem-2047	93	9	with	with	ADP
eurjchem-2047	93	10	atom	atom	NOUN
eurjchem-2047	93	11	labeling	labeling	NOUN
eurjchem-2047	93	12	scheme	scheme	NOUN
eurjchem-2047	93	13	.	.	PUNCT
eurjchem-2047	94	1	displacements	displacement	NOUN
eurjchem-2047	94	2	of	of	ADP
eurjchem-2047	94	3	ellipsoids	ellipsoid	NOUN
eurjchem-2047	94	4	are	be	AUX
eurjchem-2047	94	5	shown	show	VERB
eurjchem-2047	94	6	at	at	ADP
eurjchem-2047	94	7	the	the	DET
eurjchem-2047	94	8	50	50	NUM
eurjchem-2047	94	9	%	%	NOUN
eurjchem-2047	94	10	probability	probability	NOUN
eurjchem-2047	94	11	level	level	NOUN
eurjchem-2047	94	12	,	,	PUNCT
eurjchem-2047	94	13	i	i	PRON
eurjchem-2047	94	14	-x	-x	PROPN
eurjchem-2047	94	15	,	,	PUNCT
eurjchem-2047	94	16	+	+	NOUN
eurjchem-2047	94	17	y	y	PROPN
eurjchem-2047	94	18	,	,	PUNCT
eurjchem-2047	94	19	1	1	NUM
eurjchem-2047	94	20	-	-	PUNCT
eurjchem-2047	94	21	z.	z.	PROPN
eurjchem-2047	94	22	322	322	NUM
eurjchem-2047	94	23	ozer	ozer	NOUN
eurjchem-2047	94	24	et	et	PROPN
eurjchem-2047	94	25	al	al	PROPN
eurjchem-2047	94	26	.	.	PUNCT
eurjchem-2047	94	27	/	/	SYM
eurjchem-2047	94	28	european	european	PROPN
eurjchem-2047	94	29	journal	journal	PROPN
eurjchem-2047	94	30	of	of	ADP
eurjchem-2047	94	31	chemistry	chemistry	NOUN
eurjchem-2047	94	32	11	11	NUM
eurjchem-2047	94	33	(	(	PUNCT
eurjchem-2047	94	34	4	4	NUM
eurjchem-2047	94	35	)	)	PUNCT
eurjchem-2047	94	36	(	(	PUNCT
eurjchem-2047	94	37	2020	2020	NUM
eurjchem-2047	94	38	)	)	PUNCT
eurjchem-2047	94	39	319	319	NUM
eurjchem-2047	94	40	-	-	SYM
eurjchem-2047	94	41	323	323	NUM
eurjchem-2047	94	42	2020	2020	NUM
eurjchem-2047	94	43	–	–	PUNCT
eurjchem-2047	94	44	european	european	ADJ
eurjchem-2047	94	45	journal	journal	NOUN
eurjchem-2047	94	46	of	of	ADP
eurjchem-2047	94	47	chemistry	chemistry	NOUN
eurjchem-2047	94	48	–	–	PUNCT
eurjchem-2047	94	49	cc	cc	NOUN
eurjchem-2047	94	50	by	by	ADP
eurjchem-2047	94	51	nc	nc	PROPN
eurjchem-2047	94	52	–	–	PUNCT
eurjchem-2047	94	53	doi	doi	NOUN
eurjchem-2047	94	54	:	:	PUNCT
eurjchem-2047	94	55	10.5155	10.5155	NUM
eurjchem-2047	94	56	/	/	SYM
eurjchem-2047	95	1	eurjchem.11.4.319	eurjchem.11.4.319	ADJ
eurjchem-2047	95	2	-	-	PUNCT
eurjchem-2047	95	3	323.2047	323.2047	NUM
eurjchem-2047	95	4	figure	figure	NOUN
eurjchem-2047	95	5	2	2	NUM
eurjchem-2047	95	6	.	.	NOUN
eurjchem-2047	95	7	packing	pack	VERB
eurjchem-2047	95	8	diagram	diagram	NOUN
eurjchem-2047	95	9	for	for	ADP
eurjchem-2047	95	10	bis(n-(diethylcarbamothioyl)cyclohexane	bis(n-(diethylcarbamothioyl)cyclohexane	PROPN
eurjchem-2047	95	11	carboxamido)copper(ii	carboxamido)copper(ii	PROPN
eurjchem-2047	95	12	)	)	PUNCT
eurjchem-2047	95	13	complex	complex	NOUN
eurjchem-2047	95	14	,	,	PUNCT
eurjchem-2047	95	15	viewed	view	VERB
eurjchem-2047	95	16	along	along	ADP
eurjchem-2047	95	17	[	[	X
eurjchem-2047	95	18	010	010	NUM
eurjchem-2047	95	19	]	]	PUNCT
eurjchem-2047	95	20	.	.	PUNCT
eurjchem-2047	96	1	intermolecular	intermolecular	ADJ
eurjchem-2047	96	2	c	c	X
eurjchem-2047	96	3	-	-	PUNCT
eurjchem-2047	96	4	h···o	h···o	PROPN
eurjchem-2047	96	5	contact	contact	NOUN
eurjchem-2047	96	6	is	be	AUX
eurjchem-2047	96	7	indicated	indicate	VERB
eurjchem-2047	96	8	by	by	ADP
eurjchem-2047	96	9	dashed	dash	VERB
eurjchem-2047	96	10	lines	line	NOUN
eurjchem-2047	96	11	.	.	PUNCT
eurjchem-2047	97	1	the	the	DET
eurjchem-2047	97	2	chelate	chelate	NOUN
eurjchem-2047	97	3	ring	ring	NOUN
eurjchem-2047	97	4	systems	system	NOUN
eurjchem-2047	97	5	,	,	PUNCT
eurjchem-2047	97	6	cu1	cu1	PROPN
eurjchem-2047	97	7	–	–	PUNCT
eurjchem-2047	97	8	o1	o1	NOUN
eurjchem-2047	97	9	–	–	PUNCT
eurjchem-2047	97	10	c6	c6	PROPN
eurjchem-2047	97	11	–	–	PUNCT
eurjchem-2047	97	12	n1	n1	NOUN
eurjchem-2047	97	13	–	–	PUNCT
eurjchem-2047	97	14	c5	c5	PROPN
eurjchem-2047	97	15	–	–	PUNCT
eurjchem-2047	97	16	s1	s1	NOUN
eurjchem-2047	97	17	,	,	PUNCT
eurjchem-2047	97	18	are	be	AUX
eurjchem-2047	97	19	nearly	nearly	ADV
eurjchem-2047	97	20	planar	planar	ADJ
eurjchem-2047	97	21	as	as	ADV
eurjchem-2047	97	22	well	well	ADV
eurjchem-2047	97	23	with	with	ADP
eurjchem-2047	97	24	the	the	DET
eurjchem-2047	97	25	largest	large	ADJ
eurjchem-2047	97	26	deviations	deviation	NOUN
eurjchem-2047	97	27	from	from	ADP
eurjchem-2047	97	28	the	the	DET
eurjchem-2047	97	29	best	good	ADJ
eurjchem-2047	97	30	plane	plane	NOUN
eurjchem-2047	97	31	being	be	AUX
eurjchem-2047	97	32	0.175(2	0.175(2	NUM
eurjchem-2047	97	33	)	)	PUNCT
eurjchem-2047	97	34	å	å	PROPN
eurjchem-2047	97	35	for	for	ADP
eurjchem-2047	97	36	c5	c5	PROPN
eurjchem-2047	97	37	atom	atom	PROPN
eurjchem-2047	97	38	.	.	PUNCT
eurjchem-2047	98	1	the	the	DET
eurjchem-2047	98	2	c6	c6	PROPN
eurjchem-2047	98	3	-	-	PUNCT
eurjchem-2047	98	4	o1	o1	PROPN
eurjchem-2047	98	5	and	and	CCONJ
eurjchem-2047	98	6	c5	c5	PROPN
eurjchem-2047	98	7	-	-	PUNCT
eurjchem-2047	98	8	s1	s1	PROPN
eurjchem-2047	98	9	bond	bond	NOUN
eurjchem-2047	98	10	lengths	length	NOUN
eurjchem-2047	98	11	are	be	AUX
eurjchem-2047	98	12	1.276(2	1.276(2	NUM
eurjchem-2047	98	13	)	)	PUNCT
eurjchem-2047	98	14	and	and	CCONJ
eurjchem-2047	98	15	1.739(2	1.739(2	NUM
eurjchem-2047	98	16	)	)	PUNCT
eurjchem-2047	98	17	å	å	PROPN
eurjchem-2047	98	18	for	for	ADP
eurjchem-2047	98	19	copper(ii	copper(ii	NOUN
eurjchem-2047	98	20	)	)	PUNCT
eurjchem-2047	98	21	complex	complex	NOUN
eurjchem-2047	98	22	which	which	PRON
eurjchem-2047	98	23	are	be	AUX
eurjchem-2047	98	24	slightly	slightly	ADV
eurjchem-2047	98	25	longer	long	ADJ
eurjchem-2047	98	26	than	than	ADP
eurjchem-2047	98	27	the	the	DET
eurjchem-2047	98	28	corresponding	correspond	VERB
eurjchem-2047	98	29	distance	distance	NOUN
eurjchem-2047	98	30	found	find	VERB
eurjchem-2047	98	31	in	in	ADP
eurjchem-2047	98	32	free	free	ADJ
eurjchem-2047	98	33	ligand	ligand	NOUN
eurjchem-2047	98	34	(	(	PUNCT
eurjchem-2047	98	35	c	c	NOUN
eurjchem-2047	98	36	=	=	SYM
eurjchem-2047	98	37	o	o	NOUN
eurjchem-2047	98	38	,	,	PUNCT
eurjchem-2047	98	39	1.228(3	1.228(3	NUM
eurjchem-2047	98	40	)	)	PUNCT
eurjchem-2047	98	41	and	and	CCONJ
eurjchem-2047	98	42	c	c	X
eurjchem-2047	98	43	=	=	SYM
eurjchem-2047	98	44	s	s	NOUN
eurjchem-2047	98	45	,	,	PUNCT
eurjchem-2047	98	46	1.664(2	1.664(2	NUM
eurjchem-2047	98	47	)	)	PUNCT
eurjchem-2047	98	48	å	å	NOUN
eurjchem-2047	98	49	)	)	PUNCT
eurjchem-2047	99	1	[	[	X
eurjchem-2047	99	2	62	62	NUM
eurjchem-2047	99	3	]	]	PUNCT
eurjchem-2047	99	4	.	.	PUNCT
eurjchem-2047	100	1	this	this	PRON
eurjchem-2047	100	2	indicates	indicate	VERB
eurjchem-2047	100	3	the	the	DET
eurjchem-2047	100	4	existence	existence	NOUN
eurjchem-2047	100	5	of	of	ADP
eurjchem-2047	100	6	electron	electron	NOUN
eurjchem-2047	100	7	delocalization	delocalization	NOUN
eurjchem-2047	100	8	over	over	ADP
eurjchem-2047	100	9	the	the	DET
eurjchem-2047	100	10	six	six	NUM
eurjchem-2047	100	11	-	-	PUNCT
eurjchem-2047	100	12	member	member	NOUN
eurjchem-2047	100	13	chelate	chelate	NOUN
eurjchem-2047	100	14	rings	ring	NOUN
eurjchem-2047	100	15	(	(	PUNCT
eurjchem-2047	100	16	cu1	cu1	NOUN
eurjchem-2047	100	17	-	-	PUNCT
eurjchem-2047	100	18	s1	s1	NOUN
eurjchem-2047	100	19	-	-	PUNCT
eurjchem-2047	100	20	c5	c5	PROPN
eurjchem-2047	100	21	-	-	PUNCT
eurjchem-2047	100	22	n1	n1	NOUN
eurjchem-2047	100	23	-	-	PUNCT
eurjchem-2047	100	24	c6	c6	NOUN
eurjchem-2047	100	25	-	-	PUNCT
eurjchem-2047	100	26	o1	o1	NOUN
eurjchem-2047	100	27	and	and	CCONJ
eurjchem-2047	100	28	cu1	cu1	NOUN
eurjchem-2047	100	29	-	-	PUNCT
eurjchem-2047	100	30	s1i	s1i	PROPN
eurjchem-2047	100	31	-c5i	-c5i	PUNCT
eurjchem-2047	100	32	-n1i	-n1i	INTJ
eurjchem-2047	100	33	-c6i	-c6i	INTJ
eurjchem-2047	101	1	-o1i	-o1i	ADV
eurjchem-2047	101	2	;	;	PUNCT
eurjchem-2047	101	3	i	i	PRON
eurjchem-2047	101	4	-x	-x	PROPN
eurjchem-2047	101	5	,	,	PUNCT
eurjchem-2047	101	6	+	+	NOUN
eurjchem-2047	101	7	y	y	PROPN
eurjchem-2047	101	8	,	,	PUNCT
eurjchem-2047	101	9	1z	1z	NOUN
eurjchem-2047	101	10	)	)	PUNCT
eurjchem-2047	101	11	due	due	ADP
eurjchem-2047	101	12	to	to	ADP
eurjchem-2047	101	13	the	the	DET
eurjchem-2047	101	14	coordination	coordination	NOUN
eurjchem-2047	101	15	of	of	ADP
eurjchem-2047	101	16	the	the	DET
eurjchem-2047	101	17	oxygen	oxygen	NOUN
eurjchem-2047	101	18	and	and	CCONJ
eurjchem-2047	101	19	sulfur	sulfur	NOUN
eurjchem-2047	101	20	atoms	atom	NOUN
eurjchem-2047	101	21	with	with	ADP
eurjchem-2047	101	22	the	the	DET
eurjchem-2047	101	23	copper(ii	copper(ii	NOUN
eurjchem-2047	101	24	)	)	PUNCT
eurjchem-2047	101	25	ion	ion	NOUN
eurjchem-2047	101	26	.	.	PUNCT
eurjchem-2047	102	1	this	this	DET
eurjchem-2047	102	2	result	result	NOUN
eurjchem-2047	102	3	was	be	AUX
eurjchem-2047	102	4	also	also	ADV
eurjchem-2047	102	5	confirmed	confirm	VERB
eurjchem-2047	102	6	by	by	ADP
eurjchem-2047	102	7	the	the	DET
eurjchem-2047	102	8	short	short	ADJ
eurjchem-2047	102	9	c	c	PROPN
eurjchem-2047	102	10	-	-	PUNCT
eurjchem-2047	102	11	n	n	PRON
eurjchem-2047	102	12	bond	bond	NOUN
eurjchem-2047	102	13	distance	distance	NOUN
eurjchem-2047	102	14	(	(	PUNCT
eurjchem-2047	102	15	n1	n1	NOUN
eurjchem-2047	102	16	-	-	PUNCT
eurjchem-2047	102	17	c5	c5	PROPN
eurjchem-2047	102	18	,	,	PUNCT
eurjchem-2047	102	19	1.345(3	1.345(3	NUM
eurjchem-2047	102	20	)	)	PUNCT
eurjchem-2047	102	21	and	and	CCONJ
eurjchem-2047	102	22	n1	n1	NOUN
eurjchem-2047	102	23	-	-	PUNCT
eurjchem-2047	102	24	c6	c6	PROPN
eurjchem-2047	102	25	,	,	PUNCT
eurjchem-2047	102	26	1.322(3	1.322(3	NUM
eurjchem-2047	102	27	)	)	PUNCT
eurjchem-2047	102	28	å	å	NOUN
eurjchem-2047	102	29	)	)	PUNCT
eurjchem-2047	102	30	which	which	PRON
eurjchem-2047	102	31	are	be	AUX
eurjchem-2047	102	32	shorter	short	ADJ
eurjchem-2047	102	33	than	than	ADP
eurjchem-2047	102	34	the	the	DET
eurjchem-2047	102	35	average	average	NOUN
eurjchem-2047	102	36	for	for	ADP
eurjchem-2047	102	37	c	c	NOUN
eurjchem-2047	102	38	-	-	PUNCT
eurjchem-2047	102	39	n	n	CCONJ
eurjchem-2047	102	40	single	single	ADJ
eurjchem-2047	102	41	bond	bond	NOUN
eurjchem-2047	102	42	distance	distance	NOUN
eurjchem-2047	102	43	(	(	PUNCT
eurjchem-2047	102	44	1.48	1.48	NUM
eurjchem-2047	102	45	å	å	NOUN
eurjchem-2047	102	46	)	)	PUNCT
eurjchem-2047	103	1	[	[	X
eurjchem-2047	103	2	71,72	71,72	NUM
eurjchem-2047	103	3	]	]	X
eurjchem-2047	103	4	.	.	PUNCT
eurjchem-2047	104	1	the	the	DET
eurjchem-2047	104	2	molecular	molecular	ADJ
eurjchem-2047	104	3	structure	structure	NOUN
eurjchem-2047	104	4	is	be	AUX
eurjchem-2047	104	5	very	very	ADV
eurjchem-2047	104	6	close	close	ADJ
eurjchem-2047	104	7	to	to	ADP
eurjchem-2047	104	8	the	the	DET
eurjchem-2047	104	9	related	relate	VERB
eurjchem-2047	104	10	bis(n-(di	bis(n-(di	PROPN
eurjchem-2047	104	11	-	-	PUNCT
eurjchem-2047	104	12	n	n	CCONJ
eurjchem-2047	104	13	-	-	PUNCT
eurjchem-2047	104	14	propylcarbamothioyl)cyclohexanecarbox	propylcarbamothioyl)cyclohexanecarbox	NOUN
eurjchem-2047	104	15	amido	amido	NOUN
eurjchem-2047	104	16	)	)	PUNCT
eurjchem-2047	104	17	copper(ii	copper(ii	NOUN
eurjchem-2047	104	18	)	)	PUNCT
eurjchem-2047	104	19	complex	complex	NOUN
eurjchem-2047	104	20	,	,	PUNCT
eurjchem-2047	104	21	[	[	X
eurjchem-2047	104	22	71	71	NUM
eurjchem-2047	104	23	]	]	PUNCT
eurjchem-2047	104	24	and	and	CCONJ
eurjchem-2047	104	25	shows	show	VERB
eurjchem-2047	104	26	similar	similar	ADJ
eurjchem-2047	104	27	short	short	ADJ
eurjchem-2047	104	28	metals	metal	NOUN
eurjchem-2047	104	29	,	,	PUNCT
eurjchem-2047	104	30	metal	metal	NOUN
eurjchem-2047	104	31	-	-	PUNCT
eurjchem-2047	104	32	o	o	NOUN
eurjchem-2047	104	33	,	,	PUNCT
eurjchem-2047	104	34	c	c	NOUN
eurjchem-2047	104	35	-	-	PUNCT
eurjchem-2047	104	36	o	o	NOUN
eurjchem-2047	104	37	,	,	PUNCT
eurjchem-2047	104	38	c	c	NOUN
eurjchem-2047	104	39	-	-	PUNCT
eurjchem-2047	104	40	n	n	NOUN
eurjchem-2047	104	41	and	and	CCONJ
eurjchem-2047	104	42	c	c	NOUN
eurjchem-2047	104	43	-	-	PUNCT
eurjchem-2047	104	44	s	s	NOUN
eurjchem-2047	104	45	bonds	bond	NOUN
eurjchem-2047	104	46	indicating	indicate	VERB
eurjchem-2047	104	47	the	the	DET
eurjchem-2047	104	48	known	known	ADJ
eurjchem-2047	104	49	πbonding	πbonde	VERB
eurjchem-2047	104	50	character	character	NOUN
eurjchem-2047	104	51	in	in	ADP
eurjchem-2047	104	52	the	the	DET
eurjchem-2047	104	53	chelate	chelate	NOUN
eurjchem-2047	104	54	rings	ring	NOUN
eurjchem-2047	104	55	.	.	PUNCT
eurjchem-2047	105	1	all	all	DET
eurjchem-2047	105	2	other	other	ADJ
eurjchem-2047	105	3	bond	bond	NOUN
eurjchem-2047	105	4	lengths	length	NOUN
eurjchem-2047	105	5	are	be	AUX
eurjchem-2047	105	6	within	within	ADP
eurjchem-2047	105	7	normal	normal	ADJ
eurjchem-2047	105	8	ranges	range	NOUN
eurjchem-2047	105	9	(	(	PUNCT
eurjchem-2047	105	10	table	table	NOUN
eurjchem-2047	105	11	2	2	NUM
eurjchem-2047	105	12	)	)	PUNCT
eurjchem-2047	106	1	[	[	X
eurjchem-2047	106	2	72	72	NUM
eurjchem-2047	106	3	]	]	PUNCT
eurjchem-2047	106	4	.	.	PUNCT
eurjchem-2047	107	1	the	the	DET
eurjchem-2047	107	2	cyclohexane	cyclohexane	NOUN
eurjchem-2047	107	3	ring	ring	NOUN
eurjchem-2047	107	4	in	in	ADP
eurjchem-2047	107	5	the	the	DET
eurjchem-2047	107	6	title	title	NOUN
eurjchem-2047	107	7	complex	complex	NOUN
eurjchem-2047	107	8	exhibits	exhibit	VERB
eurjchem-2047	107	9	a	a	DET
eurjchem-2047	107	10	puckered	pucker	VERB
eurjchem-2047	107	11	conformation	conformation	NOUN
eurjchem-2047	107	12	with	with	ADP
eurjchem-2047	107	13	puckering	pucker	VERB
eurjchem-2047	107	14	parameters	parameter	NOUN
eurjchem-2047	107	15	q2	q2	NOUN
eurjchem-2047	107	16	=	=	SYM
eurjchem-2047	107	17	0.015(3	0.015(3	PROPN
eurjchem-2047	107	18	)	)	PUNCT
eurjchem-2047	107	19	å	å	PROPN
eurjchem-2047	107	20	,	,	PUNCT
eurjchem-2047	107	21	q3	q3	NOUN
eurjchem-2047	107	22	=	=	PUNCT
eurjchem-2047	107	23	0.576(3	0.576(3	NUM
eurjchem-2047	107	24	)	)	PUNCT
eurjchem-2047	107	25	å	å	NOUN
eurjchem-2047	107	26	,	,	PUNCT
eurjchem-2047	107	27	qt	qt	NOUN
eurjchem-2047	107	28	=	=	SYM
eurjchem-2047	107	29	0.577(3	0.577(3	NOUN
eurjchem-2047	107	30	)	)	PUNCT
eurjchem-2047	108	1	å	å	NOUN
eurjchem-2047	108	2	,	,	PUNCT
eurjchem-2047	108	3	θ	θ	PROPN
eurjchem-2047	108	4	=	=	SYM
eurjchem-2047	108	5	1.6(3	1.6(3	NUM
eurjchem-2047	108	6	)	)	PUNCT
eurjchem-2047	109	1	°	°	PROPN
eurjchem-2047	109	2	and	and	CCONJ
eurjchem-2047	109	3	φ	φ	NUM
eurjchem-2047	109	4	=	=	PROPN
eurjchem-2047	109	5	20(11)	20(11)	NUM
eurjchem-2047	109	6	°	°	NUM
eurjchem-2047	109	7	.	.	PUNCT
eurjchem-2047	110	1	these	these	DET
eurjchem-2047	110	2	puckering	pucker	VERB
eurjchem-2047	110	3	parameters	parameter	NOUN
eurjchem-2047	110	4	show	show	VERB
eurjchem-2047	110	5	that	that	SCONJ
eurjchem-2047	110	6	the	the	DET
eurjchem-2047	110	7	cyclohexane	cyclohexane	NOUN
eurjchem-2047	110	8	ring	ring	NOUN
eurjchem-2047	110	9	adopts	adopt	VERB
eurjchem-2047	110	10	a	a	DET
eurjchem-2047	110	11	chair	chair	NOUN
eurjchem-2047	110	12	conformation	conformation	NOUN
eurjchem-2047	111	1	[	[	X
eurjchem-2047	111	2	73	73	NUM
eurjchem-2047	111	3	]	]	PUNCT
eurjchem-2047	111	4	.	.	PUNCT
eurjchem-2047	112	1	the	the	DET
eurjchem-2047	112	2	torsion	torsion	NOUN
eurjchem-2047	112	3	angles	angle	NOUN
eurjchem-2047	112	4	of	of	ADP
eurjchem-2047	112	5	the	the	DET
eurjchem-2047	112	6	diethyl	diethyl	NOUN
eurjchem-2047	112	7	amine	amine	ADJ
eurjchem-2047	112	8	group	group	NOUN
eurjchem-2047	112	9	are	be	AUX
eurjchem-2047	112	10	c5	c5	PROPN
eurjchem-2047	112	11	-	-	PUNCT
eurjchem-2047	112	12	n2c3	n2c3	NOUN
eurjchem-2047	112	13	-	-	PUNCT
eurjchem-2047	112	14	c4	c4	NOUN
eurjchem-2047	112	15	=	=	SYM
eurjchem-2047	112	16	-90.1(3	-90.1(3	NOUN
eurjchem-2047	112	17	)	)	PUNCT
eurjchem-2047	112	18	°	°	NOUN
eurjchem-2047	112	19	and	and	CCONJ
eurjchem-2047	112	20	c5	c5	PROPN
eurjchem-2047	112	21	-	-	PUNCT
eurjchem-2047	112	22	n2	n2	NOUN
eurjchem-2047	112	23	-	-	PUNCT
eurjchem-2047	112	24	c1	c1	NOUN
eurjchem-2047	112	25	-	-	PUNCT
eurjchem-2047	112	26	c2	c2	PROPN
eurjchem-2047	112	27	=	=	PUNCT
eurjchem-2047	112	28	-88.2(3)	-88.2(3)	PROPN
eurjchem-2047	112	29	°	°	PROPN
eurjchem-2047	112	30	.	.	PUNCT
eurjchem-2047	113	1	according	accord	VERB
eurjchem-2047	113	2	to	to	ADP
eurjchem-2047	113	3	these	these	DET
eurjchem-2047	113	4	torsion	torsion	NOUN
eurjchem-2047	113	5	angles	angle	NOUN
eurjchem-2047	113	6	,	,	PUNCT
eurjchem-2047	113	7	the	the	DET
eurjchem-2047	113	8	ethyl	ethyl	PROPN
eurjchem-2047	113	9	substituents	substituent	NOUN
eurjchem-2047	113	10	(	(	PUNCT
eurjchem-2047	113	11	c5	c5	PROPN
eurjchem-2047	113	12	-	-	PUNCT
eurjchem-2047	113	13	n2	n2	PROPN
eurjchem-2047	113	14	-	-	PUNCT
eurjchem-2047	113	15	c3	c3	NOUN
eurjchem-2047	113	16	-	-	PUNCT
eurjchem-2047	113	17	c4	c4	PROPN
eurjchem-2047	113	18	and	and	CCONJ
eurjchem-2047	113	19	c5	c5	PROPN
eurjchem-2047	113	20	-	-	PUNCT
eurjchem-2047	113	21	n2	n2	NOUN
eurjchem-2047	113	22	-	-	PUNCT
eurjchem-2047	113	23	c1	c1	NOUN
eurjchem-2047	113	24	-	-	PUNCT
eurjchem-2047	113	25	c2	c2	PROPN
eurjchem-2047	113	26	)	)	PUNCT
eurjchem-2047	113	27	are	be	AUX
eurjchem-2047	113	28	in	in	ADP
eurjchem-2047	113	29	(	(	PUNCT
eurjchem-2047	113	30	-	-	PUNCT
eurjchem-2047	113	31	)	)	PUNCT
eurjchem-2047	113	32	anticlinal	anticlinal	NOUN
eurjchem-2047	113	33	(	(	PUNCT
eurjchem-2047	113	34	-ac	-ac	NOUN
eurjchem-2047	113	35	)	)	PUNCT
eurjchem-2047	113	36	and	and	CCONJ
eurjchem-2047	113	37	(	(	PUNCT
eurjchem-2047	113	38	-	-	PUNCT
eurjchem-2047	113	39	)	)	PUNCT
eurjchem-2047	113	40	synclinal	synclinal	ADJ
eurjchem-2047	113	41	(	(	PUNCT
eurjchem-2047	113	42	-sc	-sc	PRON
eurjchem-2047	113	43	)	)	PUNCT
eurjchem-2047	113	44	orientation	orientation	NOUN
eurjchem-2047	113	45	,	,	PUNCT
eurjchem-2047	113	46	respectively	respectively	ADV
eurjchem-2047	113	47	[	[	X
eurjchem-2047	113	48	74	74	NUM
eurjchem-2047	113	49	]	]	PUNCT
eurjchem-2047	113	50	.	.	PUNCT
eurjchem-2047	114	1	in	in	ADP
eurjchem-2047	114	2	addition	addition	NOUN
eurjchem-2047	114	3	,	,	PUNCT
eurjchem-2047	114	4	the	the	DET
eurjchem-2047	114	5	two	two	NUM
eurjchem-2047	114	6	ethyl	ethyl	NOUN
eurjchem-2047	114	7	groups	group	NOUN
eurjchem-2047	114	8	of	of	ADP
eurjchem-2047	114	9	the	the	DET
eurjchem-2047	114	10	diethyl	diethyl	NOUN
eurjchem-2047	114	11	amine	amine	ADJ
eurjchem-2047	114	12	group	group	NOUN
eurjchem-2047	114	13	are	be	AUX
eurjchem-2047	114	14	anti	anti	ADJ
eurjchem-2047	114	15	-	-	NOUN
eurjchem-2047	114	16	orientation	orientation	NOUN
eurjchem-2047	114	17	with	with	ADP
eurjchem-2047	114	18	respect	respect	NOUN
eurjchem-2047	114	19	to	to	ADP
eurjchem-2047	114	20	one	one	NUM
eurjchem-2047	114	21	another	another	DET
eurjchem-2047	114	22	.	.	PUNCT
eurjchem-2047	115	1	the	the	DET
eurjchem-2047	115	2	crystal	crystal	NOUN
eurjchem-2047	115	3	packing	packing	NOUN
eurjchem-2047	115	4	shows	show	VERB
eurjchem-2047	115	5	the	the	DET
eurjchem-2047	115	6	molecules	molecule	NOUN
eurjchem-2047	115	7	stacked	stack	VERB
eurjchem-2047	115	8	in	in	ADP
eurjchem-2047	115	9	parallel	parallel	ADJ
eurjchem-2047	115	10	sheets	sheet	NOUN
eurjchem-2047	115	11	along	along	ADP
eurjchem-2047	115	12	[	[	X
eurjchem-2047	115	13	010	010	NUM
eurjchem-2047	115	14	]	]	X
eurjchem-2047	115	15	(	(	PUNCT
eurjchem-2047	115	16	figure	figure	NOUN
eurjchem-2047	115	17	2	2	NUM
eurjchem-2047	115	18	)	)	PUNCT
eurjchem-2047	115	19	,	,	PUNCT
eurjchem-2047	115	20	accompanied	accompany	VERB
eurjchem-2047	115	21	by	by	ADP
eurjchem-2047	115	22	the	the	DET
eurjchem-2047	115	23	following	follow	VERB
eurjchem-2047	115	24	intermolecular	intermolecular	ADJ
eurjchem-2047	115	25	contact	contact	NOUN
eurjchem-2047	115	26	:	:	PUNCT
eurjchem-2047	115	27	c3	c3	PROPN
eurjchem-2047	115	28	-	-	PUNCT
eurjchem-2047	115	29	h3a···o1ⁱ	h3a···o1ⁱ	PROPN
eurjchem-2047	115	30	,	,	PUNCT
eurjchem-2047	115	31	with	with	ADP
eurjchem-2047	115	32	c	c	NOUN
eurjchem-2047	115	33	-	-	NOUN
eurjchem-2047	115	34	h	h	NOUN
eurjchem-2047	115	35	=	=	NOUN
eurjchem-2047	115	36	0.96	0.96	NUM
eurjchem-2047	115	37	å	å	NOUN
eurjchem-2047	115	38	,	,	PUNCT
eurjchem-2047	115	39	h···o	h···o	PROPN
eurjchem-2047	115	40	2.70	2.70	NUM
eurjchem-2047	115	41	å	å	NOUN
eurjchem-2047	115	42	,	,	PUNCT
eurjchem-2047	115	43	and	and	CCONJ
eurjchem-2047	115	44	c	c	X
eurjchem-2047	115	45	-	-	PUNCT
eurjchem-2047	115	46	h···o	h···o	PROPN
eurjchem-2047	115	47	134	134	NUM
eurjchem-2047	115	48	°	°	NUM
eurjchem-2047	115	49	;	;	PUNCT
eurjchem-2047	115	50	symmetry	symmetry	NOUN
eurjchem-2047	115	51	code	code	NOUN
eurjchem-2047	115	52	i	i	PRON
eurjchem-2047	115	53	-x	-x	PROPN
eurjchem-2047	115	54	,	,	PUNCT
eurjchem-2047	115	55	+	+	NOUN
eurjchem-2047	115	56	y	y	PROPN
eurjchem-2047	115	57	,	,	PUNCT
eurjchem-2047	115	58	1	1	NUM
eurjchem-2047	115	59	-	-	PUNCT
eurjchem-2047	115	60	z.	z.	NOUN
eurjchem-2047	115	61	possible	possible	ADJ
eurjchem-2047	115	62	intramolecular	intramolecular	ADJ
eurjchem-2047	115	63	interactions	interaction	NOUN
eurjchem-2047	115	64	are	be	AUX
eurjchem-2047	115	65	c1	c1	NOUN
eurjchem-2047	115	66	-	-	PUNCT
eurjchem-2047	115	67	h1b···n1	h1b···n1	PROPN
eurjchem-2047	115	68	,	,	PUNCT
eurjchem-2047	115	69	with	with	ADP
eurjchem-2047	115	70	c	c	NOUN
eurjchem-2047	115	71	-	-	NOUN
eurjchem-2047	115	72	h	h	NOUN
eurjchem-2047	115	73	=	=	NOUN
eurjchem-2047	115	74	0.96	0.96	NUM
eurjchem-2047	115	75	å	å	NOUN
eurjchem-2047	115	76	,	,	PUNCT
eurjchem-2047	115	77	h···o	h···o	PROPN
eurjchem-2047	115	78	2.33	2.33	NUM
eurjchem-2047	115	79	å	å	NOUN
eurjchem-2047	115	80	,	,	PUNCT
eurjchem-2047	115	81	and	and	CCONJ
eurjchem-2047	115	82	c	c	X
eurjchem-2047	115	83	-	-	PUNCT
eurjchem-2047	115	84	h···o	h···o	PROPN
eurjchem-2047	115	85	100	100	NUM
eurjchem-2047	115	86	°	°	NOUN
eurjchem-2047	115	87	and	and	CCONJ
eurjchem-2047	115	88	c3	c3	PROPN
eurjchem-2047	115	89	-	-	PUNCT
eurjchem-2047	115	90	h3b···s1	h3b···s1	PROPN
eurjchem-2047	115	91	,	,	PUNCT
eurjchem-2047	115	92	with	with	ADP
eurjchem-2047	115	93	c	c	NOUN
eurjchem-2047	115	94	-	-	NOUN
eurjchem-2047	115	95	h	h	NOUN
eurjchem-2047	115	96	=	=	NOUN
eurjchem-2047	115	97	0.96	0.96	NUM
eurjchem-2047	115	98	å	å	NOUN
eurjchem-2047	115	99	,	,	PUNCT
eurjchem-2047	115	100	h···s	h···s	PROPN
eurjchem-2047	115	101	2.57	2.57	NUM
eurjchem-2047	115	102	å	å	NOUN
eurjchem-2047	115	103	,	,	PUNCT
eurjchem-2047	115	104	and	and	CCONJ
eurjchem-2047	115	105	c	c	X
eurjchem-2047	115	106	-	-	PUNCT
eurjchem-2047	115	107	h···o	h···o	PROPN
eurjchem-2047	115	108	106	106	NUM
eurjchem-2047	115	109	°	°	NOUN
eurjchem-2047	115	110	.	.	NOUN
eurjchem-2047	116	1	4	4	NUM
eurjchem-2047	116	2	.	.	X
eurjchem-2047	116	3	conclusion	conclusion	VERB
eurjchem-2047	116	4	a	a	DET
eurjchem-2047	116	5	copper(ii	copper(ii	NOUN
eurjchem-2047	116	6	)	)	PUNCT
eurjchem-2047	116	7	complex	complex	NOUN
eurjchem-2047	116	8	,	,	PUNCT
eurjchem-2047	116	9	having	have	VERB
eurjchem-2047	116	10	the	the	DET
eurjchem-2047	116	11	general	general	ADJ
eurjchem-2047	116	12	formula	formula	NOUN
eurjchem-2047	116	13	cis-[cu(lκ2s	cis-[cu(lκ2	NOUN
eurjchem-2047	116	14	,	,	PUNCT
eurjchem-2047	116	15	o)2	o)2	PROPN
eurjchem-2047	116	16	]	]	PUNCT
eurjchem-2047	116	17	,	,	PUNCT
eurjchem-2047	116	18	has	have	AUX
eurjchem-2047	116	19	been	be	AUX
eurjchem-2047	116	20	prepared	prepare	VERB
eurjchem-2047	116	21	with	with	ADP
eurjchem-2047	116	22	n-(diethylcarbamothioyl	n-(diethylcarbamothioyl	PRON
eurjchem-2047	116	23	)	)	PUNCT
eurjchem-2047	116	24	cyclohexanecarboxamide	cyclohexanecarboxamide	VERB
eurjchem-2047	116	25	ligand	ligand	NOUN
eurjchem-2047	116	26	and	and	CCONJ
eurjchem-2047	116	27	copper(ii	copper(ii	PROPN
eurjchem-2047	116	28	)	)	PUNCT
eurjchem-2047	116	29	acetate	acetate	NOUN
eurjchem-2047	116	30	,	,	PUNCT
eurjchem-2047	116	31	and	and	CCONJ
eurjchem-2047	116	32	characterized	characterize	VERB
eurjchem-2047	116	33	by	by	ADP
eurjchem-2047	116	34	a	a	DET
eurjchem-2047	116	35	single	single	ADJ
eurjchem-2047	116	36	crystal	crystal	NOUN
eurjchem-2047	116	37	x	x	PROPN
eurjchem-2047	116	38	-	-	NOUN
eurjchem-2047	116	39	ray	ray	NOUN
eurjchem-2047	116	40	diffraction	diffraction	NOUN
eurjchem-2047	116	41	study	study	NOUN
eurjchem-2047	116	42	,	,	PUNCT
eurjchem-2047	116	43	where	where	SCONJ
eurjchem-2047	116	44	the	the	DET
eurjchem-2047	116	45	ligands	ligand	NOUN
eurjchem-2047	116	46	coordinate	coordinate	VERB
eurjchem-2047	116	47	to	to	ADP
eurjchem-2047	116	48	copper(ii	copper(ii	VERB
eurjchem-2047	116	49	)	)	PUNCT
eurjchem-2047	116	50	ion	ion	NOUN
eurjchem-2047	116	51	in	in	ADP
eurjchem-2047	116	52	a	a	DET
eurjchem-2047	116	53	cis	cis	NOUN
eurjchem-2047	116	54	conformation	conformation	NOUN
eurjchem-2047	116	55	.	.	PUNCT
eurjchem-2047	117	1	the	the	DET
eurjchem-2047	117	2	obtained	obtain	VERB
eurjchem-2047	117	3	copper	copper	NOUN
eurjchem-2047	117	4	complex	complex	NOUN
eurjchem-2047	117	5	,	,	PUNCT
eurjchem-2047	117	6	cis-[cu(l	cis-[cu(l	NOUN
eurjchem-2047	117	7	-	-	PUNCT
eurjchem-2047	117	8	κ2s	κ2	NOUN
eurjchem-2047	117	9	,	,	PUNCT
eurjchem-2047	117	10	o)2	o)2	PROPN
eurjchem-2047	117	11	]	]	PUNCT
eurjchem-2047	117	12	,	,	PUNCT
eurjchem-2047	117	13	crystallized	crystallize	VERB
eurjchem-2047	117	14	in	in	ADP
eurjchem-2047	117	15	the	the	DET
eurjchem-2047	117	16	monoclinic	monoclinic	ADJ
eurjchem-2047	117	17	space	space	NOUN
eurjchem-2047	117	18	group	group	NOUN
eurjchem-2047	117	19	c2	c2	PROPN
eurjchem-2047	117	20	.	.	PUNCT
eurjchem-2047	118	1	the	the	DET
eurjchem-2047	118	2	copper	copper	NOUN
eurjchem-2047	118	3	center	center	NOUN
eurjchem-2047	118	4	has	have	VERB
eurjchem-2047	118	5	a	a	DET
eurjchem-2047	118	6	slightly	slightly	ADV
eurjchem-2047	118	7	distorted	distort	VERB
eurjchem-2047	118	8	square	square	ADJ
eurjchem-2047	118	9	planar	planar	ADJ
eurjchem-2047	118	10	geometry	geometry	NOUN
eurjchem-2047	118	11	and	and	CCONJ
eurjchem-2047	118	12	the	the	DET
eurjchem-2047	118	13	puckering	pucker	VERB
eurjchem-2047	118	14	parameters	parameter	NOUN
eurjchem-2047	118	15	of	of	ADP
eurjchem-2047	118	16	the	the	DET
eurjchem-2047	118	17	title	title	NOUN
eurjchem-2047	118	18	complex	complex	NOUN
eurjchem-2047	118	19	show	show	VERB
eurjchem-2047	118	20	that	that	SCONJ
eurjchem-2047	118	21	the	the	DET
eurjchem-2047	118	22	cyclohexane	cyclohexane	NOUN
eurjchem-2047	118	23	ring	ring	NOUN
eurjchem-2047	118	24	adopts	adopt	VERB
eurjchem-2047	118	25	a	a	DET
eurjchem-2047	118	26	chair	chair	NOUN
eurjchem-2047	118	27	conformation	conformation	NOUN
eurjchem-2047	118	28	.	.	PUNCT
eurjchem-2047	119	1	the	the	DET
eurjchem-2047	119	2	crystal	crystal	NOUN
eurjchem-2047	119	3	packing	packing	NOUN
eurjchem-2047	119	4	shows	show	VERB
eurjchem-2047	119	5	the	the	DET
eurjchem-2047	119	6	molecules	molecule	NOUN
eurjchem-2047	119	7	stacked	stack	VERB
eurjchem-2047	119	8	in	in	ADP
eurjchem-2047	119	9	parallel	parallel	ADJ
eurjchem-2047	119	10	sheets	sheet	NOUN
eurjchem-2047	119	11	along	along	ADP
eurjchem-2047	119	12	[	[	X
eurjchem-2047	119	13	010	010	NUM
eurjchem-2047	119	14	]	]	PUNCT
eurjchem-2047	119	15	,	,	PUNCT
eurjchem-2047	119	16	accompanied	accompany	VERB
eurjchem-2047	119	17	by	by	ADP
eurjchem-2047	119	18	c3	c3	PROPN
eurjchem-2047	119	19	-	-	PROPN
eurjchem-2047	119	20	h3a···o1ⁱ	h3a···o1ⁱ	PROPN
eurjchem-2047	119	21	(	(	PUNCT
eurjchem-2047	119	22	i	i	NOUN
eurjchem-2047	119	23	-x	-x	PROPN
eurjchem-2047	119	24	,	,	PUNCT
eurjchem-2047	119	25	+	+	NOUN
eurjchem-2047	119	26	y	y	PROPN
eurjchem-2047	119	27	,	,	PUNCT
eurjchem-2047	119	28	1	1	NUM
eurjchem-2047	119	29	-	-	PUNCT
eurjchem-2047	119	30	z	z	NOUN
eurjchem-2047	119	31	)	)	PUNCT
eurjchem-2047	119	32	intermolecular	intermolecular	ADJ
eurjchem-2047	119	33	contact	contact	NOUN
eurjchem-2047	119	34	.	.	PUNCT
eurjchem-2047	120	1	acknowledgements	acknowledgement	NOUN
eurjchem-2047	120	2	a	a	DET
eurjchem-2047	120	3	part	part	NOUN
eurjchem-2047	120	4	of	of	ADP
eurjchem-2047	120	5	this	this	DET
eurjchem-2047	120	6	work	work	NOUN
eurjchem-2047	120	7	was	be	AUX
eurjchem-2047	120	8	supported	support	VERB
eurjchem-2047	120	9	by	by	ADP
eurjchem-2047	120	10	the	the	DET
eurjchem-2047	120	11	mersin	mersin	PROPN
eurjchem-2047	120	12	university	university	PROPN
eurjchem-2047	120	13	research	research	NOUN
eurjchem-2047	120	14	fund	fund	NOUN
eurjchem-2047	121	1	[	[	X
eurjchem-2047	121	2	project	project	NOUN
eurjchem-2047	121	3	no	no	PRON
eurjchem-2047	121	4	:	:	PUNCT
eurjchem-2047	121	5	bap	bap	ADJ
eurjchem-2047	121	6	-	-	PUNCT
eurjchem-2047	121	7	sbetb	sbetb	NOUN
eurjchem-2047	121	8	(	(	PUNCT
eurjchem-2047	121	9	ckö	ckö	NOUN
eurjchem-2047	121	10	)	)	PUNCT
eurjchem-2047	121	11	2007	2007	NUM
eurjchem-2047	121	12	-	-	SYM
eurjchem-2047	121	13	1	1	NUM
eurjchem-2047	121	14	]	]	PUNCT
eurjchem-2047	121	15	.	.	PUNCT
eurjchem-2047	122	1	supporting	support	VERB
eurjchem-2047	122	2	information	information	NOUN
eurjchem-2047	122	3	ccdc-2039559	ccdc-2039559	NOUN
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eurjchem-2047	122	5	the	the	DET
eurjchem-2047	122	6	supplementary	supplementary	ADJ
eurjchem-2047	122	7	crystallographic	crystallographic	ADJ
eurjchem-2047	122	8	data	datum	NOUN
eurjchem-2047	122	9	for	for	ADP
eurjchem-2047	122	10	this	this	DET
eurjchem-2047	122	11	paper	paper	NOUN
eurjchem-2047	122	12	.	.	PUNCT
eurjchem-2047	123	1	these	these	DET
eurjchem-2047	123	2	data	datum	NOUN
eurjchem-2047	123	3	can	can	AUX
eurjchem-2047	123	4	be	be	AUX
eurjchem-2047	123	5	obtained	obtain	VERB
eurjchem-2047	123	6	free	free	ADJ
eurjchem-2047	123	7	of	of	ADP
eurjchem-2047	123	8	charge	charge	NOUN
eurjchem-2047	123	9	via	via	ADP
eurjchem-2047	123	10	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	PROPN
eurjchem-2047	123	11	,	,	PUNCT
eurjchem-2047	123	12	or	or	CCONJ
eurjchem-2047	123	13	by	by	ADP
eurjchem-2047	123	14	emailing	email	VERB
eurjchem-2047	123	15	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-2047	123	16	,	,	PUNCT
eurjchem-2047	123	17	or	or	CCONJ
eurjchem-2047	123	18	by	by	ADP
eurjchem-2047	123	19	contacting	contact	VERB
eurjchem-2047	123	20	the	the	DET
eurjchem-2047	123	21	cambridge	cambridge	PROPN
eurjchem-2047	123	22	crystallographic	crystallographic	PROPN
eurjchem-2047	123	23	data	data	PROPN
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eurjchem-2047	123	25	,	,	PUNCT
eurjchem-2047	123	26	12	12	NUM
eurjchem-2047	123	27	union	union	NOUN
eurjchem-2047	123	28	road	road	NOUN
eurjchem-2047	123	29	,	,	PUNCT
eurjchem-2047	123	30	cambridge	cambridge	PROPN
eurjchem-2047	123	31	cb2	cb2	PROPN
eurjchem-2047	123	32	1ez	1ez	PROPN
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eurjchem-2047	123	34	uk	uk	PROPN
eurjchem-2047	123	35	;	;	PUNCT
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eurjchem-2047	123	37	:	:	PUNCT
eurjchem-2047	123	38	+44(0)1223	+44(0)1223	PROPN
eurjchem-2047	123	39	-	-	PUNCT
eurjchem-2047	123	40	336033	336033	NUM
eurjchem-2047	123	41	.	.	PUNCT
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eurjchem-2047	124	2	statement	statement	NOUN
eurjchem-2047	124	3	conflict	conflict	NOUN
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eurjchem-2047	124	5	interest	interest	NOUN
eurjchem-2047	124	6	:	:	PUNCT
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eurjchem-2047	124	8	authors	author	NOUN
eurjchem-2047	124	9	declare	declare	VERB
eurjchem-2047	124	10	that	that	SCONJ
eurjchem-2047	124	11	they	they	PRON
eurjchem-2047	124	12	have	have	VERB
eurjchem-2047	124	13	no	no	DET
eurjchem-2047	124	14	conflict	conflict	NOUN
eurjchem-2047	124	15	of	of	ADP
eurjchem-2047	124	16	interest	interest	NOUN
eurjchem-2047	124	17	.	.	PUNCT
eurjchem-2047	125	1	author	author	NOUN
eurjchem-2047	125	2	contributions	contribution	NOUN
eurjchem-2047	125	3	:	:	PUNCT
eurjchem-2047	125	4	all	all	DET
eurjchem-2047	125	5	authors	author	NOUN
eurjchem-2047	125	6	contributed	contribute	VERB
eurjchem-2047	125	7	equally	equally	ADV
eurjchem-2047	125	8	to	to	ADP
eurjchem-2047	125	9	this	this	DET
eurjchem-2047	125	10	work	work	NOUN
eurjchem-2047	125	11	.	.	PUNCT
eurjchem-2047	126	1	ethical	ethical	ADJ
eurjchem-2047	126	2	approval	approval	NOUN
eurjchem-2047	126	3	:	:	PUNCT
eurjchem-2047	127	1	all	all	DET
eurjchem-2047	127	2	ethical	ethical	ADJ
eurjchem-2047	127	3	guidelines	guideline	NOUN
eurjchem-2047	127	4	have	have	AUX
eurjchem-2047	127	5	been	be	AUX
eurjchem-2047	127	6	adhered	adhere	VERB
eurjchem-2047	127	7	.	.	PUNCT
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eurjchem-2047	128	2	availability	availability	NOUN
eurjchem-2047	128	3	:	:	PUNCT
eurjchem-2047	128	4	samples	sample	NOUN
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eurjchem-2047	128	6	the	the	DET
eurjchem-2047	128	7	compounds	compound	NOUN
eurjchem-2047	128	8	are	be	AUX
eurjchem-2047	128	9	available	available	ADJ
eurjchem-2047	128	10	from	from	ADP
eurjchem-2047	128	11	the	the	DET
eurjchem-2047	128	12	author	author	NOUN
eurjchem-2047	128	13	.	.	PUNCT
eurjchem-2047	129	1	funding	funding	PROPN
eurjchem-2047	129	2	mersin	mersin	PROPN
eurjchem-2047	129	3	üniversitesi	üniversitesi	PROPN
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eurjchem-2047	129	8	ozer	ozer	PROPN
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eurjchem-2047	129	14	arslan	arslan	PROPN
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eurjchem-2047	129	20	http://orcid.org/0000-0002-9601-9528	http://orcid.org/0000-0002-9601-9528	PROPN
eurjchem-2047	129	21	http://orcid.org/0000-0003-0046-9442	http://orcid.org/0000-0003-0046-9442	PROPN
eurjchem-2047	129	22	ozer	ozer	PROPN
eurjchem-2047	129	23	et	et	PROPN
eurjchem-2047	129	24	al	al	PROPN
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eurjchem-2047	129	26	/	/	SYM
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eurjchem-2047	129	31	11	11	NUM
eurjchem-2047	129	32	(	(	PUNCT
eurjchem-2047	129	33	4	4	NUM
eurjchem-2047	129	34	)	)	PUNCT
eurjchem-2047	129	35	(	(	PUNCT
eurjchem-2047	129	36	2020	2020	NUM
eurjchem-2047	129	37	)	)	PUNCT
eurjchem-2047	129	38	319	319	NUM
eurjchem-2047	129	39	-	-	SYM
eurjchem-2047	129	40	323	323	NUM
eurjchem-2047	129	41	323	323	NUM
eurjchem-2047	129	42	2020	2020	NUM
eurjchem-2047	129	43	–	–	PUNCT
eurjchem-2047	129	44	european	european	ADJ
eurjchem-2047	129	45	journal	journal	NOUN
eurjchem-2047	129	46	of	of	ADP
eurjchem-2047	129	47	chemistry	chemistry	NOUN
eurjchem-2047	129	48	–	–	PUNCT
eurjchem-2047	129	49	cc	cc	NOUN
eurjchem-2047	129	50	by	by	ADP
eurjchem-2047	129	51	nc	nc	PROPN
eurjchem-2047	129	52	–	–	PUNCT
eurjchem-2047	129	53	doi	doi	NOUN
eurjchem-2047	129	54	:	:	PUNCT
eurjchem-2047	129	55	10.5155	10.5155	NUM
eurjchem-2047	129	56	/	/	SYM
eurjchem-2047	129	57	eurjchem.11.4.319	eurjchem.11.4.319	ADJ
eurjchem-2047	129	58	-	-	PUNCT
eurjchem-2047	129	59	323.2047	323.2047	NUM
eurjchem-2047	129	60	references	reference	NOUN
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eurjchem-2047	129	62	1	1	NUM
eurjchem-2047	129	63	]	]	PUNCT
eurjchem-2047	129	64	.	.	PUNCT
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eurjchem-2047	130	2	,	,	PUNCT
eurjchem-2047	130	3	l.	l.	PROPN
eurjchem-2047	130	4	;	;	PUNCT
eurjchem-2047	130	5	hoyer	hoyer	PROPN
eurjchem-2047	130	6	,	,	PUNCT
eurjchem-2047	130	7	e.	e.	PROPN
eurjchem-2047	130	8	;	;	PUNCT
eurjchem-2047	130	9	liebscher	liebscher	PROPN
eurjchem-2047	130	10	,	,	PUNCT
eurjchem-2047	130	11	j.	j.	PROPN
eurjchem-2047	130	12	;	;	PUNCT
eurjchem-2047	130	13	hartmann	hartmann	PROPN
eurjchem-2047	130	14	,	,	PUNCT
eurjchem-2047	130	15	h.	h.	PROPN
eurjchem-2047	130	16	z.	z.	PROPN
eurjchem-2047	130	17	chem	chem	PROPN
eurjchem-2047	130	18	.	.	PUNCT
eurjchem-2047	131	1	2010	2010	NUM
eurjchem-2047	131	2	,	,	PUNCT
eurjchem-2047	131	3	21(3	21(3	NUM
eurjchem-2047	131	4	)	)	PUNCT
eurjchem-2047	131	5	,	,	PUNCT
eurjchem-2047	131	6	81	81	NUM
eurjchem-2047	131	7	-	-	SYM
eurjchem-2047	131	8	91	91	NUM
eurjchem-2047	131	9	.	.	PUNCT
eurjchem-2047	132	1	[	[	X
eurjchem-2047	132	2	2	2	NUM
eurjchem-2047	132	3	]	]	PUNCT
eurjchem-2047	132	4	.	.	PUNCT
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eurjchem-2047	133	2	,	,	PUNCT
eurjchem-2047	133	3	s.	s.	PROPN
eurjchem-2047	133	4	;	;	PUNCT
eurjchem-2047	133	5	koch	koch	PROPN
eurjchem-2047	133	6	,	,	PUNCT
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eurjchem-2047	133	8	r.	r.	PROPN
eurjchem-2047	133	9	j.	j.	PROPN
eurjchem-2047	133	10	chem	chem	PROPN
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eurjchem-2047	134	1	soc	soc	PROPN
eurjchem-2047	134	2	.	.	PROPN
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eurjchem-2047	135	2	,	,	PUNCT
eurjchem-2047	135	3	13	13	NUM
eurjchem-2047	135	4	,	,	PUNCT
eurjchem-2047	135	5	2071	2071	NUM
eurjchem-2047	135	6	-	-	SYM
eurjchem-2047	135	7	2072	2072	NUM
eurjchem-2047	135	8	.	.	PUNCT
eurjchem-2047	136	1	[	[	X
eurjchem-2047	136	2	3	3	NUM
eurjchem-2047	136	3	]	]	PUNCT
eurjchem-2047	136	4	.	.	PUNCT
eurjchem-2047	137	1	koch	koch	PROPN
eurjchem-2047	137	2	,	,	PUNCT
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eurjchem-2047	137	5	;	;	PUNCT
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eurjchem-2047	137	7	,	,	PUNCT
eurjchem-2047	137	8	y.	y.	PROPN
eurjchem-2047	137	9	;	;	PUNCT
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eurjchem-2047	137	11	,	,	PUNCT
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eurjchem-2047	138	8	,	,	PUNCT
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eurjchem-2047	138	10	,	,	PUNCT
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eurjchem-2047	138	12	-	-	SYM
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eurjchem-2047	138	14	.	.	PUNCT
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eurjchem-2047	139	4	.	.	PUNCT
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eurjchem-2047	140	5	;	;	PUNCT
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eurjchem-2047	140	30	.	.	PUNCT
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eurjchem-2047	141	2	.	.	PUNCT
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eurjchem-2047	142	2	,	,	PUNCT
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eurjchem-2047	142	5	,	,	PUNCT
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eurjchem-2047	146	2	,	,	PUNCT
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eurjchem-2047	146	4	,	,	PUNCT
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eurjchem-2047	151	3	]	]	PUNCT
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eurjchem-2047	152	2	,	,	PUNCT
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eurjchem-2047	153	2	,	,	PUNCT
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eurjchem-2047	153	5	,	,	PUNCT
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eurjchem-2047	153	7	.	.	PUNCT
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eurjchem-2047	154	3	]	]	PUNCT
eurjchem-2047	154	4	.	.	PUNCT
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eurjchem-2047	155	2	.	.	PUNCT
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eurjchem-2047	156	2	,	,	PUNCT
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eurjchem-2047	156	7	-	-	SYM
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eurjchem-2047	171	2	,	,	PUNCT
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eurjchem-2047	212	7	-	-	SYM
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eurjchem-2047	213	3	]	]	PUNCT
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eurjchem-2047	215	9	-	-	SYM
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eurjchem-2047	339	4	,	,	PUNCT
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eurjchem-2047	339	6	-	-	SYM
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eurjchem-2047	365	4	)	)	PUNCT
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eurjchem-2047	365	7	.	.	PUNCT
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eurjchem-2047	366	3	]	]	PUNCT
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eurjchem-2047	371	2	,	,	PUNCT
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eurjchem-2047	371	4	)	)	PUNCT
eurjchem-2047	371	5	,	,	PUNCT
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eurjchem-2047	371	7	-	-	SYM
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eurjchem-2047	372	3	]	]	PUNCT
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eurjchem-2047	373	7	,	,	PUNCT
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eurjchem-2047	375	3	,	,	PUNCT
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eurjchem-2047	375	5	,	,	PUNCT
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eurjchem-2047	376	4	.	.	PUNCT
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eurjchem-2047	377	11	.	.	PUNCT
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eurjchem-2047	378	2	.	.	PUNCT
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eurjchem-2047	379	2	.	.	PUNCT
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eurjchem-2047	380	2	,	,	PUNCT
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eurjchem-2047	381	4	.	.	PUNCT
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eurjchem-2047	382	2	,	,	PUNCT
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eurjchem-2047	382	5	;	;	PUNCT
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eurjchem-2047	385	5	,	,	PUNCT
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eurjchem-2047	385	7	.	.	PUNCT
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eurjchem-2047	387	18	.	.	PUNCT
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eurjchem-2047	388	7	are	be	AUX
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eurjchem-2047	388	9	at	at	ADP
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eurjchem-2047	388	31	(	(	PUNCT
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eurjchem-2047	389	4	work	work	NOUN
eurjchem-2047	389	5	,	,	PUNCT
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eurjchem-2047	389	9	the	the	DET
eurjchem-2047	389	10	terms	term	NOUN
eurjchem-2047	389	11	.	.	PUNCT
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eurjchem-2047	390	23	non	non	ADJ
eurjchem-2047	390	24	-	-	ADJ
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eurjchem-2047	390	32	in	in	ADP
eurjchem-2047	390	33	any	any	DET
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eurjchem-2047	390	37	the	the	DET
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eurjchem-2047	390	42	cited	cite	VERB
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eurjchem-2047	390	52	(	(	PUNCT
eurjchem-2047	390	53	european	european	PROPN
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eurjchem-2047	390	57	)	)	PUNCT
eurjchem-2047	390	58	.	.	PUNCT
eurjchem-2047	391	1	no	no	DET
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eurjchem-2047	391	14	these	these	DET
eurjchem-2047	391	15	terms	term	NOUN
eurjchem-2047	391	16	.	.	PUNCT
eurjchem-2047	392	1	permissions	permission	NOUN
eurjchem-2047	392	2	for	for	ADP
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eurjchem-2047	392	4	use	use	NOUN
eurjchem-2047	392	5	of	of	ADP
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eurjchem-2047	392	7	work	work	NOUN
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eurjchem-2047	392	12	the	the	DET
eurjchem-2047	392	13	license	license	NOUN
eurjchem-2047	392	14	(	(	PUNCT
eurjchem-2047	392	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
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eurjchem-2047	392	24	(	(	PUNCT
eurjchem-2047	392	25	european	european	PROPN
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eurjchem-2047	392	29	)	)	PUNCT
eurjchem-2047	392	30	.	.	PUNCT
eurjchem-2047	393	1	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
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eurjchem-2047	393	5	.	.	PUNCT
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eurjchem-2047	393	11	.	.	PUNCT
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eurjchem-2047	395	11	.	.	PUNCT
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eurjchem-2047	396	7	-	-	PUNCT
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eurjchem-2047	396	9	,	,	PUNCT
eurjchem-2047	396	10	o)2	o)2	NOUN
eurjchem-2047	396	11	3	3	NUM
eurjchem-2047	396	12	.	.	NOUN
eurjchem-2047	396	13	results	result	NOUN
eurjchem-2047	396	14	and	and	CCONJ
eurjchem-2047	396	15	discussion	discussion	NOUN
eurjchem-2047	396	16	4	4	NUM
eurjchem-2047	396	17	.	.	PUNCT
eurjchem-2047	397	1	conclusion	conclusion	NOUN
eurjchem-2047	397	2	acknowledgements	acknowledgement	NOUN
eurjchem-2047	397	3	supporting	support	VERB
eurjchem-2047	397	4	information	information	NOUN
eurjchem-2047	397	5	disclosure	disclosure	NOUN
eurjchem-2047	397	6	statement	statement	NOUN
eurjchem-2047	397	7	funding	fund	VERB
eurjchem-2047	397	8	orcid	orcid	PROPN
eurjchem-2047	397	9	references	reference	NOUN
eurjchem-2047	397	10	printfield10	printfield10	NOUN
eurjchem-2047	397	11	:	:	PUNCT
eurjchem-2047	397	12	printfield11	printfield11	NOUN
eurjchem-2047	397	13	:	:	PUNCT
eurjchem-2047	397	14	printfield12	printfield12	PROPN
eurjchem-2047	397	15	:	:	PUNCT
eurjchem-2047	397	16	printfield13	printfield13	VERB
eurjchem-2047	397	17	:	:	PUNCT
eurjchem-2047	397	18	printfield14	printfield14	NOUN
eurjchem-2047	397	19	:	:	PUNCT
eurjchem-2047	397	20	printfield20	printfield20	PROPN
eurjchem-2047	397	21	:	:	PUNCT
eurjchem-2047	398	1	printfield21	printfield21	ADJ
eurjchem-2047	398	2	:	:	PUNCT
eurjchem-2047	398	3	printfield22	printfield22	NOUN
eurjchem-2047	398	4	:	:	PUNCT
eurjchem-2047	398	5	printfield23	printfield23	NOUN
eurjchem-2047	398	6	:	:	PUNCT
eurjchem-2047	398	7	printfield24	printfield24	NOUN
eurjchem-2047	398	8	:	:	PUNCT