id sid tid token lemma pos eurjchem-221 1 1 microsoft microsoft PROPN eurjchem-221 1 2 word word NOUN eurjchem-221 1 3 european_journal_of_chemistry_1_4_2010_360_367_221 european_journal_of_chemistry_1_4_2010_360_367_221 PROPN eurjchem-221 1 4 european european ADJ eurjchem-221 1 5     SPACE eurjchem-221 1 6 journal journal NOUN eurjchem-221 1 7     SPACE eurjchem-221 1 8 of of ADP eurjchem-221 1 9     SPACE eurjchem-221 1 10 chemistry chemistry NOUN eurjchem-221 1 11     SPACE eurjchem-221 1 12 1 1 NUM eurjchem-221 1 13     SPACE eurjchem-221 1 14 ( ( PUNCT eurjchem-221 1 15 4 4 NUM eurjchem-221 1 16 ) ) PUNCT eurjchem-221 1 17     SPACE eurjchem-221 1 18 ( ( PUNCT eurjchem-221 1 19 2010 2010 NUM eurjchem-221 1 20 ) ) PUNCT eurjchem-221 1 21     SPACE eurjchem-221 1 22 360‐367 360‐367 NUM eurjchem-221 1 23         SPACE eurjchem-221 1 24 european european ADJ eurjchem-221 1 25     SPACE eurjchem-221 1 26 journal journal NOUN eurjchem-221 1 27     SPACE eurjchem-221 1 28 of of ADP eurjchem-221 1 29     SPACE eurjchem-221 1 30 chemistry chemistry NOUN eurjchem-221 1 31     SPACE eurjchem-221 1 32 issn issn VERB eurjchem-221 1 33     SPACE eurjchem-221 1 34 2153‐2249 2153‐2249 NUM eurjchem-221 1 35     SPACE eurjchem-221 1 36 ( ( PUNCT eurjchem-221 1 37 print print NOUN eurjchem-221 1 38 ) ) PUNCT eurjchem-221 1 39     SPACE eurjchem-221 1 40 / / SYM eurjchem-221 1 41     SPACE eurjchem-221 1 42 issn issn VERB eurjchem-221 1 43     SPACE eurjchem-221 1 44 2153‐2257 2153‐2257 NUM eurjchem-221 1 45     SPACE eurjchem-221 1 46 ( ( PUNCT eurjchem-221 1 47 online online ADJ eurjchem-221 1 48 ) ) PUNCT eurjchem-221 1 49     SPACE eurjchem-221 1 50   NOUN eurjchem-221 1 51     SPACE eurjchem-221 1 52 2010 2010 NUM eurjchem-221 1 53     SPACE eurjchem-221 1 54 eurjchem eurjchem NOUN eurjchem-221 1 55     SPACE eurjchem-221 1 56 doi:10.5155 doi:10.5155 NOUN eurjchem-221 1 57 / / SYM eurjchem-221 1 58 eurjchem.1.4.360‐367.221 eurjchem.1.4.360‐367.221 ADJ eurjchem-221 1 59                 SPACE eurjchem-221 1 60 european european ADJ eurjchem-221 1 61     SPACE eurjchem-221 1 62 journal journal NOUN eurjchem-221 1 63     SPACE eurjchem-221 1 64 of of ADP eurjchem-221 1 65     SPACE eurjchem-221 1 66 chemistry chemistry NOUN eurjchem-221 1 67     SPACE eurjchem-221 1 68 journal journal NOUN eurjchem-221 1 69     SPACE eurjchem-221 1 70 homepage homepage NOUN eurjchem-221 1 71 : : PUNCT eurjchem-221 1 72     SPACE eurjchem-221 1 73 www.eurjchem.com www.eurjchem.com NOUN eurjchem-221 1 74                     SPACE eurjchem-221 1 75 chiral chiral ADJ eurjchem-221 1 76     SPACE eurjchem-221 1 77 cu(ii cu(ii PROPN eurjchem-221 1 78 ) ) PUNCT eurjchem-221 1 79     SPACE eurjchem-221 1 80 salen salen PROPN eurjchem-221 1 81     SPACE eurjchem-221 1 82 complexes complex NOUN eurjchem-221 1 83     SPACE eurjchem-221 1 84 catalyzed catalyze VERB eurjchem-221 1 85     SPACE eurjchem-221 1 86 aerobic aerobic ADJ eurjchem-221 1 87     SPACE eurjchem-221 1 88 oxidative oxidative ADJ eurjchem-221 1 89     SPACE eurjchem-221 1 90 biaryl biaryl NOUN eurjchem-221 1 91     SPACE eurjchem-221 1 92 coupling‐ coupling‐ NOUN eurjchem-221 1 93 probing probe VERB eurjchem-221 1 94     SPACE eurjchem-221 1 95 the the DET eurjchem-221 1 96     SPACE eurjchem-221 1 97 reaction reaction NOUN eurjchem-221 1 98     SPACE eurjchem-221 1 99 by by ADP eurjchem-221 1 100     SPACE eurjchem-221 1 101 epr epr PROPN eurjchem-221 1 102     SPACE eurjchem-221 1 103 subbaramanian subbaramanian PROPN eurjchem-221 1 104     SPACE eurjchem-221 1 105 sabarinathan sabarinathan PROPN eurjchem-221 1 106 , , PUNCT eurjchem-221 1 107     SPACE eurjchem-221 1 108 gnanasambandam gnanasambandam PROPN eurjchem-221 1 109     SPACE eurjchem-221 1 110 vasuki vasuki NOUN eurjchem-221 1 111 * * NOUN eurjchem-221 1 112     SPACE eurjchem-221 1 113 and and CCONJ eurjchem-221 1 114     SPACE eurjchem-221 1 115 pillutla pillutla NOUN eurjchem-221 1 116     SPACE eurjchem-221 1 117 sambasiva sambasiva PROPN eurjchem-221 1 118     SPACE eurjchem-221 1 119 rao rao PROPN eurjchem-221 1 120     SPACE eurjchem-221 1 121 department department NOUN eurjchem-221 1 122     SPACE eurjchem-221 1 123 of of ADP eurjchem-221 1 124     SPACE eurjchem-221 1 125 chemistry chemistry NOUN eurjchem-221 1 126 , , PUNCT eurjchem-221 1 127     SPACE eurjchem-221 1 128 pondicherry pondicherry NOUN eurjchem-221 1 129     SPACE eurjchem-221 1 130 university university NOUN eurjchem-221 1 131 , , PUNCT eurjchem-221 1 132     SPACE eurjchem-221 1 133 pudhucherry pudhucherry VERB eurjchem-221 1 134 , , PUNCT eurjchem-221 1 135     SPACE eurjchem-221 1 136 in­605 in­605 NOUN eurjchem-221 1 137     SPACE eurjchem-221 1 138 014 014 NUM eurjchem-221 1 139 , , PUNCT eurjchem-221 1 140     SPACE eurjchem-221 1 141 india india PROPN eurjchem-221 1 142     SPACE eurjchem-221 1 143 * * PROPN eurjchem-221 1 144 corresponding correspond VERB eurjchem-221 1 145     SPACE eurjchem-221 1 146 author author NOUN eurjchem-221 1 147     SPACE eurjchem-221 1 148 at at ADP eurjchem-221 1 149 : : PUNCT eurjchem-221 1 150     SPACE eurjchem-221 1 151 department department NOUN eurjchem-221 1 152     SPACE eurjchem-221 1 153 of of ADP eurjchem-221 1 154     SPACE eurjchem-221 1 155 chemistry chemistry NOUN eurjchem-221 1 156 , , PUNCT eurjchem-221 1 157     SPACE eurjchem-221 1 158 pondicherry pondicherry NOUN eurjchem-221 1 159     SPACE eurjchem-221 1 160 university university NOUN eurjchem-221 1 161 , , PUNCT eurjchem-221 1 162     SPACE eurjchem-221 1 163 pudhucherry pudhucherry VERB eurjchem-221 1 164 , , PUNCT eurjchem-221 1 165     SPACE eurjchem-221 1 166 in­605 in­605 NOUN eurjchem-221 1 167     SPACE eurjchem-221 1 168 014 014 NUM eurjchem-221 1 169 , , PUNCT eurjchem-221 1 170     SPACE eurjchem-221 1 171 india india PROPN eurjchem-221 1 172 . . PUNCT eurjchem-221 1 173     SPACE eurjchem-221 2 1 tel tel PROPN eurjchem-221 2 2 . . PUNCT eurjchem-221 2 3 : : PUNCT eurjchem-221 2 4     SPACE eurjchem-221 2 5 +91.413.2654498 +91.413.2654498 PROPN eurjchem-221 2 6 ; ; PUNCT eurjchem-221 2 7     SPACE eurjchem-221 2 8 fax fax NOUN eurjchem-221 2 9 : : PUNCT eurjchem-221 2 10     SPACE eurjchem-221 2 11 +91.413.2655987 +91.413.2655987 NUM eurjchem-221 2 12 . . PUNCT eurjchem-221 2 13     SPACE eurjchem-221 2 14 e­mail e­mail NOUN eurjchem-221 2 15     SPACE eurjchem-221 2 16 address address NOUN eurjchem-221 2 17 : : PUNCT eurjchem-221 2 18     SPACE eurjchem-221 2 19 vasukig@gmail.com vasukig@gmail.com X eurjchem-221 2 20     SPACE eurjchem-221 2 21 ( ( PUNCT eurjchem-221 2 22 g. g. NOUN eurjchem-221 2 23     SPACE eurjchem-221 2 24 vasuki vasuki NOUN eurjchem-221 2 25 ) ) PUNCT eurjchem-221 2 26 . . PUNCT eurjchem-221 2 27                                 SPACE eurjchem-221 2 28 article article NOUN eurjchem-221 2 29     SPACE eurjchem-221 2 30 information information NOUN eurjchem-221 2 31         SPACE eurjchem-221 2 32 abstract abstract ADJ eurjchem-221 2 33 received receive VERB eurjchem-221 2 34 : : PUNCT eurjchem-221 2 35     SPACE eurjchem-221 2 36 27 27 NUM eurjchem-221 2 37     SPACE eurjchem-221 2 38 july july PROPN eurjchem-221 2 39     SPACE eurjchem-221 2 40 2010 2010 NUM eurjchem-221 2 41     SPACE eurjchem-221 2 42 received receive VERB eurjchem-221 2 43     SPACE eurjchem-221 2 44 in in ADP eurjchem-221 2 45     SPACE eurjchem-221 2 46 revised revise VERB eurjchem-221 2 47     SPACE eurjchem-221 2 48 form form NOUN eurjchem-221 2 49 : : PUNCT eurjchem-221 2 50     SPACE eurjchem-221 2 51 29 29 NUM eurjchem-221 2 52     SPACE eurjchem-221 2 53 september september PROPN eurjchem-221 2 54     SPACE eurjchem-221 2 55 2010 2010 NUM eurjchem-221 2 56     SPACE eurjchem-221 2 57 accepted accept VERB eurjchem-221 2 58 : : PUNCT eurjchem-221 2 59     SPACE eurjchem-221 2 60 30 30 NUM eurjchem-221 2 61     SPACE eurjchem-221 2 62 september september PROPN eurjchem-221 2 63     SPACE eurjchem-221 2 64 2010 2010 NUM eurjchem-221 2 65     SPACE eurjchem-221 2 66 online online NOUN eurjchem-221 2 67 : : PUNCT eurjchem-221 2 68     SPACE eurjchem-221 3 1 31 31 NUM eurjchem-221 3 2     SPACE eurjchem-221 3 3 december december PROPN eurjchem-221 3 4     SPACE eurjchem-221 3 5 2010 2010 NUM eurjchem-221 3 6     SPACE eurjchem-221 3 7 keywords keyword VERB eurjchem-221 3 8         SPACE eurjchem-221 3 9 aerobic aerobic ADJ eurjchem-221 3 10     SPACE eurjchem-221 3 11 oxidative oxidative ADJ eurjchem-221 3 12     SPACE eurjchem-221 3 13 coupling coupling NOUN eurjchem-221 3 14     SPACE eurjchem-221 3 15 of of ADP eurjchem-221 3 16     SPACE eurjchem-221 3 17 2‐naphthol 2‐naphthol NOUN eurjchem-221 3 18     SPACE eurjchem-221 3 19 to to ADP eurjchem-221 3 20     SPACE eurjchem-221 3 21 1,1'‐binaphthyl‐2,2'‐diol 1,1'‐binaphthyl‐2,2'‐diol NUM eurjchem-221 3 22     SPACE eurjchem-221 3 23 has have AUX eurjchem-221 3 24     SPACE eurjchem-221 3 25 been be AUX eurjchem-221 3 26     SPACE eurjchem-221 3 27 achieved achieve VERB eurjchem-221 3 28     SPACE eurjchem-221 3 29 using use VERB eurjchem-221 3 30     SPACE eurjchem-221 3 31 chiral chiral ADJ eurjchem-221 3 32 / / SYM eurjchem-221 3 33 achiral achiral ADJ eurjchem-221 3 34     SPACE eurjchem-221 3 35 copper copper NOUN eurjchem-221 3 36     SPACE eurjchem-221 3 37 salen salen PROPN eurjchem-221 3 38     SPACE eurjchem-221 3 39 complexes complex NOUN eurjchem-221 3 40     SPACE eurjchem-221 3 41 as as ADP eurjchem-221 3 42     SPACE eurjchem-221 3 43 catalyst catalyst NOUN eurjchem-221 3 44 . . PUNCT eurjchem-221 3 45     SPACE eurjchem-221 4 1 moderate moderate ADJ eurjchem-221 4 2     SPACE eurjchem-221 4 3 enantioselectivity enantioselectivity NOUN eurjchem-221 4 4     SPACE eurjchem-221 4 5 was be AUX eurjchem-221 4 6     SPACE eurjchem-221 4 7 obtained obtain VERB eurjchem-221 4 8     SPACE eurjchem-221 4 9 for for ADP eurjchem-221 4 10     SPACE eurjchem-221 4 11 the the DET eurjchem-221 4 12     SPACE eurjchem-221 4 13 reaction reaction NOUN eurjchem-221 4 14     SPACE eurjchem-221 4 15 of of ADP eurjchem-221 4 16     SPACE eurjchem-221 4 17 2‐napthol 2‐napthol NOUN eurjchem-221 4 18     SPACE eurjchem-221 4 19 with with ADP eurjchem-221 4 20     SPACE eurjchem-221 4 21 a a DET eurjchem-221 4 22     SPACE eurjchem-221 4 23 coordinating coordinating NOUN eurjchem-221 4 24     SPACE eurjchem-221 4 25 substituent substituent NOUN eurjchem-221 4 26     SPACE eurjchem-221 4 27 with with ADP eurjchem-221 4 28     SPACE eurjchem-221 4 29 a a DET eurjchem-221 4 30     SPACE eurjchem-221 4 31 chiral chiral ADJ eurjchem-221 4 32     SPACE eurjchem-221 4 33 salen salen ADJ eurjchem-221 4 34     SPACE eurjchem-221 4 35 complex complex NOUN eurjchem-221 4 36 . . PUNCT eurjchem-221 4 37     SPACE eurjchem-221 5 1 unsubstituted unsubstitute VERB eurjchem-221 5 2     SPACE eurjchem-221 5 3 2‐naphthol 2‐naphthol NOUN eurjchem-221 5 4     SPACE eurjchem-221 5 5 resulted result VERB eurjchem-221 5 6     SPACE eurjchem-221 5 7 in in ADP eurjchem-221 5 8     SPACE eurjchem-221 5 9 racemic racemic ADJ eurjchem-221 5 10     SPACE eurjchem-221 5 11 1,1'‐binaphthyl‐2,2'‐diol 1,1'‐binaphthyl‐2,2'‐diol NUM eurjchem-221 5 12     SPACE eurjchem-221 5 13 only only ADV eurjchem-221 5 14     SPACE eurjchem-221 5 15 with with ADP eurjchem-221 5 16     SPACE eurjchem-221 5 17 all all DET eurjchem-221 5 18     SPACE eurjchem-221 5 19 chiral chiral ADJ eurjchem-221 5 20     SPACE eurjchem-221 5 21 complexes complex NOUN eurjchem-221 5 22 . . PUNCT eurjchem-221 5 23     SPACE eurjchem-221 5 24 electron electron NOUN eurjchem-221 5 25     SPACE eurjchem-221 5 26 paramagnetic paramagnetic NOUN eurjchem-221 5 27     SPACE eurjchem-221 5 28 resonance resonance NOUN eurjchem-221 5 29     SPACE eurjchem-221 5 30 spectroscopy spectroscopy NOUN eurjchem-221 5 31     SPACE eurjchem-221 5 32 has have AUX eurjchem-221 5 33     SPACE eurjchem-221 5 34 been be AUX eurjchem-221 5 35     SPACE eurjchem-221 5 36 used use VERB eurjchem-221 5 37     SPACE eurjchem-221 5 38 to to PART eurjchem-221 5 39     SPACE eurjchem-221 5 40 understand understand VERB eurjchem-221 5 41     SPACE eurjchem-221 5 42 the the DET eurjchem-221 5 43     SPACE eurjchem-221 5 44 factors factor NOUN eurjchem-221 5 45     SPACE eurjchem-221 5 46 influencing influence VERB eurjchem-221 5 47     SPACE eurjchem-221 5 48 the the DET eurjchem-221 5 49     SPACE eurjchem-221 5 50 asymmetric asymmetric ADJ eurjchem-221 5 51     SPACE eurjchem-221 5 52 induction induction NOUN eurjchem-221 5 53 . . PUNCT eurjchem-221 5 54     SPACE eurjchem-221 5 55 biaryl biaryl NOUN eurjchem-221 5 56     SPACE eurjchem-221 5 57 coupling couple VERB eurjchem-221 5 58     SPACE eurjchem-221 5 59 chiral chiral ADJ eurjchem-221 5 60     SPACE eurjchem-221 5 61 copper copper NOUN eurjchem-221 5 62     SPACE eurjchem-221 5 63 salen salen PROPN eurjchem-221 5 64     SPACE eurjchem-221 5 65 complexes complex NOUN eurjchem-221 5 66     SPACE eurjchem-221 5 67 cross cross ADJ eurjchem-221 5 68     SPACE eurjchem-221 5 69 coupling couple VERB eurjchem-221 5 70     SPACE eurjchem-221 5 71 binol binol ADJ eurjchem-221 5 72     SPACE eurjchem-221 5 73 aerobic aerobic ADJ eurjchem-221 5 74     SPACE eurjchem-221 5 75 oxidation oxidation NOUN eurjchem-221 5 76     SPACE eurjchem-221 5 77 epr epr PROPN eurjchem-221 5 78         SPACE eurjchem-221 5 79 1 1 NUM eurjchem-221 5 80 . . PUNCT eurjchem-221 5 81     SPACE eurjchem-221 5 82 introduction introduction NOUN eurjchem-221 5 83         SPACE eurjchem-221 5 84 transition transition NOUN eurjchem-221 5 85     SPACE eurjchem-221 5 86 metal metal NOUN eurjchem-221 5 87     SPACE eurjchem-221 5 88 complexes complex NOUN eurjchem-221 5 89     SPACE eurjchem-221 5 90 with with ADP eurjchem-221 5 91     SPACE eurjchem-221 5 92 chiral chiral ADJ eurjchem-221 5 93     SPACE eurjchem-221 5 94 ligands ligand NOUN eurjchem-221 5 95     SPACE eurjchem-221 5 96 play play NOUN eurjchem-221 5 97     SPACE eurjchem-221 5 98 a a DET eurjchem-221 5 99     SPACE eurjchem-221 5 100 significant significant ADJ eurjchem-221 5 101     SPACE eurjchem-221 5 102 role role NOUN eurjchem-221 5 103     SPACE eurjchem-221 5 104 in in ADP eurjchem-221 5 105     SPACE eurjchem-221 5 106 catalyzed catalyze VERB eurjchem-221 5 107     SPACE eurjchem-221 5 108 enantioselective enantioselective ADJ eurjchem-221 5 109     SPACE eurjchem-221 5 110 reactions reaction NOUN eurjchem-221 5 111 . . PUNCT eurjchem-221 5 112     SPACE eurjchem-221 6 1 among among ADP eurjchem-221 6 2     SPACE eurjchem-221 6 3 all all PRON eurjchem-221 6 4     SPACE eurjchem-221 6 5 of of ADP eurjchem-221 6 6     SPACE eurjchem-221 6 7 the the DET eurjchem-221 6 8     SPACE eurjchem-221 6 9 ligands ligand NOUN eurjchem-221 6 10 , , PUNCT eurjchem-221 6 11     SPACE eurjchem-221 6 12 jacobson jacobson PROPN eurjchem-221 6 13     SPACE eurjchem-221 6 14 chiral chiral ADJ eurjchem-221 6 15     SPACE eurjchem-221 6 16 salen salen PROPN eurjchem-221 6 17     SPACE eurjchem-221 6 18 ligand ligand NOUN eurjchem-221 6 19     SPACE eurjchem-221 6 20 is be AUX eurjchem-221 6 21     SPACE eurjchem-221 6 22 known know VERB eurjchem-221 6 23     SPACE eurjchem-221 6 24 as as ADP eurjchem-221 6 25     SPACE eurjchem-221 6 26 the the DET eurjchem-221 6 27     SPACE eurjchem-221 6 28 previledged previledge VERB eurjchem-221 6 29     SPACE eurjchem-221 6 30 ligand ligand NOUN eurjchem-221 6 31     SPACE eurjchem-221 6 32 as as SCONJ eurjchem-221 6 33     SPACE eurjchem-221 6 34 it it PRON eurjchem-221 6 35     SPACE eurjchem-221 6 36 is be AUX eurjchem-221 6 37     SPACE eurjchem-221 6 38 capable capable ADJ eurjchem-221 6 39     SPACE eurjchem-221 6 40 of of ADP eurjchem-221 6 41     SPACE eurjchem-221 6 42 complexing complexe VERB eurjchem-221 6 43     SPACE eurjchem-221 6 44 with with ADP eurjchem-221 6 45     SPACE eurjchem-221 6 46 several several ADJ eurjchem-221 6 47     SPACE eurjchem-221 6 48 metal metal NOUN eurjchem-221 6 49     SPACE eurjchem-221 6 50 ions ion NOUN eurjchem-221 6 51     SPACE eurjchem-221 6 52 and and CCONJ eurjchem-221 6 53     SPACE eurjchem-221 6 54 stabilizes stabilize VERB eurjchem-221 6 55     SPACE eurjchem-221 6 56 them they PRON eurjchem-221 6 57     SPACE eurjchem-221 6 58 in in ADP eurjchem-221 6 59     SPACE eurjchem-221 6 60 different different ADJ eurjchem-221 6 61     SPACE eurjchem-221 6 62 oxidation oxidation NOUN eurjchem-221 6 63     SPACE eurjchem-221 6 64 states state NOUN eurjchem-221 6 65     SPACE eurjchem-221 7 1 [ [ X eurjchem-221 7 2 1‐ 1‐ NUM eurjchem-221 7 3 5 5 NUM eurjchem-221 7 4 ] ] PUNCT eurjchem-221 7 5 . . PUNCT eurjchem-221 7 6     SPACE eurjchem-221 7 7 moreover moreover ADV eurjchem-221 7 8 , , PUNCT eurjchem-221 7 9     SPACE eurjchem-221 7 10 the the DET eurjchem-221 7 11     SPACE eurjchem-221 7 12 steric steric NOUN eurjchem-221 7 13     SPACE eurjchem-221 7 14 and and CCONJ eurjchem-221 7 15     SPACE eurjchem-221 7 16 electronic electronic ADJ eurjchem-221 7 17     SPACE eurjchem-221 7 18 nature nature NOUN eurjchem-221 7 19     SPACE eurjchem-221 7 20 of of ADP eurjchem-221 7 21     SPACE eurjchem-221 7 22 the the DET eurjchem-221 7 23     SPACE eurjchem-221 7 24 complex complex NOUN eurjchem-221 7 25     SPACE eurjchem-221 7 26 can can AUX eurjchem-221 7 27     SPACE eurjchem-221 7 28 be be AUX eurjchem-221 7 29     SPACE eurjchem-221 7 30 easily easily ADV eurjchem-221 7 31     SPACE eurjchem-221 7 32 tuned tune VERB eurjchem-221 7 33 . . PUNCT eurjchem-221 7 34     SPACE eurjchem-221 8 1 they they PRON eurjchem-221 8 2     SPACE eurjchem-221 8 3 are be AUX eurjchem-221 8 4     SPACE eurjchem-221 8 5 found find VERB eurjchem-221 8 6     SPACE eurjchem-221 8 7 to to PART eurjchem-221 8 8     SPACE eurjchem-221 8 9 be be AUX eurjchem-221 8 10     SPACE eurjchem-221 8 11 efficient efficient ADJ eurjchem-221 8 12     SPACE eurjchem-221 8 13 catalysts catalyst NOUN eurjchem-221 8 14     SPACE eurjchem-221 8 15 in in ADP eurjchem-221 8 16     SPACE eurjchem-221 8 17 several several ADJ eurjchem-221 8 18     SPACE eurjchem-221 8 19 mechanistically mechanistically ADV eurjchem-221 8 20     SPACE eurjchem-221 8 21 different different ADJ eurjchem-221 8 22     SPACE eurjchem-221 8 23 asymmetric asymmetric ADJ eurjchem-221 8 24     SPACE eurjchem-221 8 25 reactions reaction NOUN eurjchem-221 8 26 . . PUNCT eurjchem-221 8 27     SPACE eurjchem-221 9 1 the the DET eurjchem-221 9 2     SPACE eurjchem-221 9 3 efficiency efficiency NOUN eurjchem-221 9 4     SPACE eurjchem-221 9 5 of of ADP eurjchem-221 9 6     SPACE eurjchem-221 9 7 these these DET eurjchem-221 9 8     SPACE eurjchem-221 9 9 asymmetric asymmetric ADJ eurjchem-221 9 10     SPACE eurjchem-221 9 11 catalysts catalyst NOUN eurjchem-221 9 12     SPACE eurjchem-221 9 13 in in ADP eurjchem-221 9 14     SPACE eurjchem-221 9 15 general general NOUN eurjchem-221 9 16     SPACE eurjchem-221 9 17 is be AUX eurjchem-221 9 18     SPACE eurjchem-221 9 19 controlled control VERB eurjchem-221 9 20     SPACE eurjchem-221 9 21 by by ADP eurjchem-221 9 22     SPACE eurjchem-221 9 23 several several ADJ eurjchem-221 9 24     SPACE eurjchem-221 9 25 molecular molecular ADJ eurjchem-221 9 26     SPACE eurjchem-221 9 27 characteristics characteristic NOUN eurjchem-221 9 28 , , PUNCT eurjchem-221 9 29     SPACE eurjchem-221 9 30 such such ADJ eurjchem-221 9 31     SPACE eurjchem-221 9 32 as as ADP eurjchem-221 9 33     SPACE eurjchem-221 9 34 symmetry symmetry NOUN eurjchem-221 9 35 , , PUNCT eurjchem-221 9 36     SPACE eurjchem-221 9 37 steric steric ADJ eurjchem-221 9 38     SPACE eurjchem-221 9 39 properties property NOUN eurjchem-221 9 40 , , PUNCT eurjchem-221 9 41     SPACE eurjchem-221 9 42 electronic electronic ADJ eurjchem-221 9 43     SPACE eurjchem-221 9 44 nature nature NOUN eurjchem-221 9 45     SPACE eurjchem-221 9 46 of of ADP eurjchem-221 9 47     SPACE eurjchem-221 9 48 the the DET eurjchem-221 9 49     SPACE eurjchem-221 9 50 metal metal NOUN eurjchem-221 9 51     SPACE eurjchem-221 9 52 ion ion NOUN eurjchem-221 9 53     SPACE eurjchem-221 9 54 and and CCONJ eurjchem-221 9 55     SPACE eurjchem-221 9 56 the the DET eurjchem-221 9 57     SPACE eurjchem-221 9 58 ligands ligand NOUN eurjchem-221 9 59 , , PUNCT eurjchem-221 9 60     SPACE eurjchem-221 9 61 as as ADV eurjchem-221 9 62     SPACE eurjchem-221 9 63 well well ADV eurjchem-221 9 64     SPACE eurjchem-221 9 65 as as ADP eurjchem-221 9 66     SPACE eurjchem-221 9 67 the the DET eurjchem-221 9 68     SPACE eurjchem-221 9 69 interaction interaction NOUN eurjchem-221 9 70     SPACE eurjchem-221 9 71 of of ADP eurjchem-221 9 72     SPACE eurjchem-221 9 73 the the DET eurjchem-221 9 74     SPACE eurjchem-221 9 75 substrate substrate NOUN eurjchem-221 9 76     SPACE eurjchem-221 9 77 with with ADP eurjchem-221 9 78     SPACE eurjchem-221 9 79 the the DET eurjchem-221 9 80     SPACE eurjchem-221 9 81 catalyst catalyst NOUN eurjchem-221 9 82 . . PUNCT eurjchem-221 9 83                               SPACE eurjchem-221 10 1 a a DET eurjchem-221 10 2     SPACE eurjchem-221 10 3 rational rational ADJ eurjchem-221 10 4     SPACE eurjchem-221 10 5 design design NOUN eurjchem-221 10 6     SPACE eurjchem-221 10 7 of of ADP eurjchem-221 10 8     SPACE eurjchem-221 10 9 a a DET eurjchem-221 10 10     SPACE eurjchem-221 10 11 chiral chiral ADJ eurjchem-221 10 12     SPACE eurjchem-221 10 13 catalyst catalyst NOUN eurjchem-221 10 14     SPACE eurjchem-221 10 15 with with ADP eurjchem-221 10 16     SPACE eurjchem-221 10 17 improved improve VERB eurjchem-221 10 18     SPACE eurjchem-221 10 19 performance performance NOUN eurjchem-221 10 20     SPACE eurjchem-221 10 21 can can AUX eurjchem-221 10 22     SPACE eurjchem-221 10 23 be be AUX eurjchem-221 10 24     SPACE eurjchem-221 10 25 achieved achieve VERB eurjchem-221 10 26     SPACE eurjchem-221 10 27 only only ADV eurjchem-221 10 28     SPACE eurjchem-221 10 29 by by ADP eurjchem-221 10 30     SPACE eurjchem-221 10 31 an an DET eurjchem-221 10 32     SPACE eurjchem-221 10 33 understanding understanding NOUN eurjchem-221 10 34     SPACE eurjchem-221 10 35 of of ADP eurjchem-221 10 36     SPACE eurjchem-221 10 37 the the DET eurjchem-221 10 38     SPACE eurjchem-221 10 39 electronic electronic ADJ eurjchem-221 10 40     SPACE eurjchem-221 10 41 and and CCONJ eurjchem-221 10 42     SPACE eurjchem-221 10 43 structural structural ADJ eurjchem-221 10 44     SPACE eurjchem-221 10 45 properties property NOUN eurjchem-221 10 46     SPACE eurjchem-221 10 47 that that PRON eurjchem-221 10 48     SPACE eurjchem-221 10 49 influence influence VERB eurjchem-221 10 50     SPACE eurjchem-221 10 51 the the DET eurjchem-221 10 52     SPACE eurjchem-221 10 53 reaction reaction NOUN eurjchem-221 10 54 . . PUNCT eurjchem-221 10 55     SPACE eurjchem-221 11 1 the the DET eurjchem-221 11 2     SPACE eurjchem-221 11 3 use use NOUN eurjchem-221 11 4     SPACE eurjchem-221 11 5 of of ADP eurjchem-221 11 6     SPACE eurjchem-221 11 7 electron electron NOUN eurjchem-221 11 8     SPACE eurjchem-221 11 9 paramagnetic paramagnetic NOUN eurjchem-221 11 10     SPACE eurjchem-221 11 11 resonance resonance NOUN eurjchem-221 11 12     SPACE eurjchem-221 11 13 spectroscopy spectroscopy NOUN eurjchem-221 11 14     SPACE eurjchem-221 11 15 ( ( PUNCT eurjchem-221 11 16 epr epr PROPN eurjchem-221 11 17 ) ) PUNCT eurjchem-221 11 18     SPACE eurjchem-221 11 19 as as ADP eurjchem-221 11 20     SPACE eurjchem-221 11 21 a a DET eurjchem-221 11 22     SPACE eurjchem-221 11 23 tool tool NOUN eurjchem-221 11 24     SPACE eurjchem-221 11 25 to to PART eurjchem-221 11 26     SPACE eurjchem-221 11 27 understand understand VERB eurjchem-221 11 28     SPACE eurjchem-221 11 29 the the DET eurjchem-221 11 30     SPACE eurjchem-221 11 31 mechanism mechanism NOUN eurjchem-221 11 32     SPACE eurjchem-221 11 33 of of ADP eurjchem-221 11 34     SPACE eurjchem-221 11 35 metal metal NOUN eurjchem-221 11 36     SPACE eurjchem-221 11 37 catalyzed catalyze VERB eurjchem-221 11 38     SPACE eurjchem-221 11 39 asymmetric asymmetric ADJ eurjchem-221 11 40     SPACE eurjchem-221 11 41 reactions reaction NOUN eurjchem-221 11 42     SPACE eurjchem-221 11 43 is be AUX eurjchem-221 11 44     SPACE eurjchem-221 11 45 an an DET eurjchem-221 11 46     SPACE eurjchem-221 11 47 emerging emerge VERB eurjchem-221 11 48     SPACE eurjchem-221 11 49 area area NOUN eurjchem-221 11 50     SPACE eurjchem-221 11 51 of of ADP eurjchem-221 11 52     SPACE eurjchem-221 11 53 research research NOUN eurjchem-221 11 54     SPACE eurjchem-221 12 1 [ [ X eurjchem-221 12 2 6‐9 6‐9 NOUN eurjchem-221 12 3 ] ] PUNCT eurjchem-221 12 4 . . PUNCT eurjchem-221 12 5     SPACE eurjchem-221 12 6 copper(ii copper(ii NOUN eurjchem-221 12 7 ) ) PUNCT eurjchem-221 12 8 , , PUNCT eurjchem-221 12 9     SPACE eurjchem-221 12 10 an an DET eurjchem-221 12 11     SPACE eurjchem-221 12 12 epr epr ADJ eurjchem-221 12 13     SPACE eurjchem-221 12 14 active active ADJ eurjchem-221 12 15     SPACE eurjchem-221 12 16 metal metal NOUN eurjchem-221 12 17     SPACE eurjchem-221 12 18 ion ion NOUN eurjchem-221 12 19 , , PUNCT eurjchem-221 12 20     SPACE eurjchem-221 12 21 has have AUX eurjchem-221 12 22     SPACE eurjchem-221 12 23 been be AUX eurjchem-221 12 24     SPACE eurjchem-221 12 25 used use VERB eurjchem-221 12 26     SPACE eurjchem-221 12 27 in in ADP eurjchem-221 12 28     SPACE eurjchem-221 12 29 several several ADJ eurjchem-221 12 30     SPACE eurjchem-221 12 31 asymmetric asymmetric ADJ eurjchem-221 12 32     SPACE eurjchem-221 12 33 oxidation oxidation NOUN eurjchem-221 12 34     SPACE eurjchem-221 12 35 reactions reaction NOUN eurjchem-221 12 36     SPACE eurjchem-221 13 1 [ [ X eurjchem-221 13 2 10‐18 10‐18 X eurjchem-221 13 3 ] ] X eurjchem-221 13 4 . . PUNCT eurjchem-221 13 5     SPACE eurjchem-221 13 6 use use NOUN eurjchem-221 13 7     SPACE eurjchem-221 13 8 of of ADP eurjchem-221 13 9     SPACE eurjchem-221 13 10 oxygen oxygen NOUN eurjchem-221 13 11     SPACE eurjchem-221 13 12 present present ADJ eurjchem-221 13 13     SPACE eurjchem-221 13 14 in in ADP eurjchem-221 13 15     SPACE eurjchem-221 13 16 air air NOUN eurjchem-221 13 17     SPACE eurjchem-221 13 18 as as ADP eurjchem-221 13 19     SPACE eurjchem-221 13 20 oxidizing oxidize VERB eurjchem-221 13 21     SPACE eurjchem-221 13 22 agent agent NOUN eurjchem-221 13 23     SPACE eurjchem-221 13 24 is be AUX eurjchem-221 13 25     SPACE eurjchem-221 13 26 gaining gain VERB eurjchem-221 13 27     SPACE eurjchem-221 13 28 attention attention NOUN eurjchem-221 13 29     SPACE eurjchem-221 13 30 by by ADP eurjchem-221 13 31     SPACE eurjchem-221 13 32 being be AUX eurjchem-221 13 33     SPACE eurjchem-221 13 34 abundant abundant ADJ eurjchem-221 13 35     SPACE eurjchem-221 13 36 and and CCONJ eurjchem-221 13 37     SPACE eurjchem-221 13 38 cost cost NOUN eurjchem-221 13 39     SPACE eurjchem-221 13 40 effective effective ADJ eurjchem-221 13 41     SPACE eurjchem-221 13 42 [ [ X eurjchem-221 13 43 19 19 NUM eurjchem-221 13 44 ] ] PUNCT eurjchem-221 13 45 . . PUNCT eurjchem-221 13 46     SPACE eurjchem-221 14 1 enantioselective enantioselective ADJ eurjchem-221 14 2     SPACE eurjchem-221 14 3 oxidative oxidative ADJ eurjchem-221 14 4     SPACE eurjchem-221 14 5 coupling coupling NOUN eurjchem-221 14 6     SPACE eurjchem-221 14 7 of of ADP eurjchem-221 14 8         SPACE eurjchem-221 14 9 2‐naphthol 2‐naphthol NOUN eurjchem-221 14 10     SPACE eurjchem-221 14 11 is be AUX eurjchem-221 14 12     SPACE eurjchem-221 14 13 an an DET eurjchem-221 14 14     SPACE eurjchem-221 14 15 important important ADJ eurjchem-221 14 16     SPACE eurjchem-221 14 17 oxidation oxidation NOUN eurjchem-221 14 18     SPACE eurjchem-221 14 19 reaction reaction NOUN eurjchem-221 14 20     SPACE eurjchem-221 14 21 in in ADP eurjchem-221 14 22     SPACE eurjchem-221 14 23 asymmetric asymmetric ADJ eurjchem-221 14 24     SPACE eurjchem-221 14 25 synthesis synthesis NOUN eurjchem-221 14 26     SPACE eurjchem-221 14 27 [ [ X eurjchem-221 14 28 20‐22 20‐22 NUM eurjchem-221 14 29 ] ] PUNCT eurjchem-221 14 30 . . PUNCT eurjchem-221 14 31     SPACE eurjchem-221 15 1 enantioselective enantioselective ADJ eurjchem-221 15 2     SPACE eurjchem-221 15 3 oxidative oxidative ADJ eurjchem-221 15 4     SPACE eurjchem-221 15 5 coupling coupling NOUN eurjchem-221 15 6     SPACE eurjchem-221 15 7 of of ADP eurjchem-221 15 8                           SPACE eurjchem-221 15 9 2‐naphthol 2‐naphthol NOUN eurjchem-221 15 10     SPACE eurjchem-221 15 11 using use VERB eurjchem-221 15 12     SPACE eurjchem-221 15 13 chiral chiral ADJ eurjchem-221 15 14     SPACE eurjchem-221 15 15 copper copper NOUN eurjchem-221 15 16     SPACE eurjchem-221 15 17 amine amine ADJ eurjchem-221 15 18     SPACE eurjchem-221 15 19 complexes complex NOUN eurjchem-221 15 20     SPACE eurjchem-221 15 21 has have AUX eurjchem-221 15 22     SPACE eurjchem-221 15 23 been be AUX eurjchem-221 15 24     SPACE eurjchem-221 15 25 attempted attempt VERB eurjchem-221 15 26     SPACE eurjchem-221 15 27 by by ADP eurjchem-221 15 28     SPACE eurjchem-221 15 29 several several ADJ eurjchem-221 15 30     SPACE eurjchem-221 15 31 research research NOUN eurjchem-221 15 32     SPACE eurjchem-221 15 33 groups group NOUN eurjchem-221 15 34     SPACE eurjchem-221 16 1 [ [ X eurjchem-221 16 2 23‐25 23‐25 X eurjchem-221 16 3 ] ] PUNCT eurjchem-221 16 4 . . PUNCT eurjchem-221 16 5     SPACE eurjchem-221 16 6 moreover moreover ADV eurjchem-221 16 7     SPACE eurjchem-221 16 8 copper copper NOUN eurjchem-221 16 9     SPACE eurjchem-221 16 10 n n CCONJ eurjchem-221 16 11 , , PUNCT eurjchem-221 16 12 n n CCONJ eurjchem-221 16 13 , , PUNCT eurjchem-221 16 14 n',n'‐tetramethylethylenediamine n',n'‐tetramethylethylenediamine NOUN eurjchem-221 16 15     SPACE eurjchem-221 16 16 ( ( PUNCT eurjchem-221 16 17 tmeda tmeda NOUN eurjchem-221 16 18 ) ) PUNCT eurjchem-221 16 19     SPACE eurjchem-221 16 20 complex complex NOUN eurjchem-221 16 21     SPACE eurjchem-221 16 22 is be AUX eurjchem-221 16 23     SPACE eurjchem-221 16 24 an an DET eurjchem-221 16 25     SPACE eurjchem-221 16 26 effective effective ADJ eurjchem-221 16 27     SPACE eurjchem-221 16 28 catalyst catalyst NOUN eurjchem-221 16 29     SPACE eurjchem-221 16 30 for for ADP eurjchem-221 16 31     SPACE eurjchem-221 16 32 1,1'‐binaphthyl‐2,2'‐diol 1,1'‐binaphthyl‐2,2'‐diol NUM eurjchem-221 16 33     SPACE eurjchem-221 16 34 ( ( PUNCT eurjchem-221 16 35 binol binol ADJ eurjchem-221 16 36 ) ) PUNCT eurjchem-221 16 37     SPACE eurjchem-221 16 38 synthesis synthesis NOUN eurjchem-221 16 39     SPACE eurjchem-221 17 1 [ [ X eurjchem-221 17 2 26 26 NUM eurjchem-221 17 3 ] ] PUNCT eurjchem-221 17 4 . . PUNCT eurjchem-221 17 5     SPACE eurjchem-221 17 6 to to ADP eurjchem-221 17 7     SPACE eurjchem-221 17 8 the the DET eurjchem-221 17 9     SPACE eurjchem-221 17 10 best good ADJ eurjchem-221 17 11     SPACE eurjchem-221 17 12 of of ADP eurjchem-221 17 13     SPACE eurjchem-221 17 14 our our PRON eurjchem-221 17 15     SPACE eurjchem-221 17 16 knowledge knowledge NOUN eurjchem-221 17 17 , , PUNCT eurjchem-221 17 18     SPACE eurjchem-221 17 19 oxidative oxidative ADJ eurjchem-221 17 20     SPACE eurjchem-221 17 21 coupling coupling NOUN eurjchem-221 17 22     SPACE eurjchem-221 17 23 of of ADP eurjchem-221 17 24     SPACE eurjchem-221 17 25 2‐naphthol 2‐naphthol NOUN eurjchem-221 17 26     SPACE eurjchem-221 17 27 to to PART eurjchem-221 17 28     SPACE eurjchem-221 17 29 binol binol VERB eurjchem-221 17 30     SPACE eurjchem-221 17 31 using use VERB eurjchem-221 17 32     SPACE eurjchem-221 17 33 chiral chiral ADJ eurjchem-221 17 34     SPACE eurjchem-221 17 35 copper copper NOUN eurjchem-221 17 36     SPACE eurjchem-221 17 37 salen salen PROPN eurjchem-221 17 38     SPACE eurjchem-221 17 39 complexes complex NOUN eurjchem-221 17 40     SPACE eurjchem-221 17 41 using use VERB eurjchem-221 17 42     SPACE eurjchem-221 17 43 oxygen oxygen NOUN eurjchem-221 17 44     SPACE eurjchem-221 17 45 present present ADJ eurjchem-221 17 46     SPACE eurjchem-221 17 47 in in ADP eurjchem-221 17 48     SPACE eurjchem-221 17 49 air air NOUN eurjchem-221 17 50     SPACE eurjchem-221 17 51 is be AUX eurjchem-221 17 52     SPACE eurjchem-221 17 53 not not PART eurjchem-221 17 54     SPACE eurjchem-221 17 55 reported report VERB eurjchem-221 17 56 . . PUNCT eurjchem-221 17 57     SPACE eurjchem-221 18 1 in in ADP eurjchem-221 18 2     SPACE eurjchem-221 18 3 this this DET eurjchem-221 18 4     SPACE eurjchem-221 18 5 article article NOUN eurjchem-221 18 6 , , PUNCT eurjchem-221 18 7     SPACE eurjchem-221 18 8 the the DET eurjchem-221 18 9     SPACE eurjchem-221 18 10 results result NOUN eurjchem-221 18 11     SPACE eurjchem-221 18 12 of of ADP eurjchem-221 18 13     SPACE eurjchem-221 18 14 aerobic aerobic ADJ eurjchem-221 18 15     SPACE eurjchem-221 18 16 oxidative oxidative ADJ eurjchem-221 18 17     SPACE eurjchem-221 18 18 coupling coupling NOUN eurjchem-221 18 19     SPACE eurjchem-221 18 20 of of ADP eurjchem-221 18 21     SPACE eurjchem-221 18 22 2‐naphthol 2‐naphthol NOUN eurjchem-221 18 23     SPACE eurjchem-221 18 24 to to PART eurjchem-221 18 25     SPACE eurjchem-221 18 26 binol binol VERB eurjchem-221 18 27     SPACE eurjchem-221 18 28 catalysed catalyse VERB eurjchem-221 18 29     SPACE eurjchem-221 18 30 by by ADP eurjchem-221 18 31     SPACE eurjchem-221 18 32 copper copper NOUN eurjchem-221 18 33     SPACE eurjchem-221 18 34 salen salen PROPN eurjchem-221 18 35     SPACE eurjchem-221 18 36 complexes complex NOUN eurjchem-221 18 37     SPACE eurjchem-221 18 38 have have AUX eurjchem-221 18 39     SPACE eurjchem-221 18 40 been be AUX eurjchem-221 18 41     SPACE eurjchem-221 18 42 reported report VERB eurjchem-221 18 43 . . PUNCT eurjchem-221 18 44     SPACE eurjchem-221 19 1 epr epr PROPN eurjchem-221 19 2     SPACE eurjchem-221 19 3 has have AUX eurjchem-221 19 4     SPACE eurjchem-221 19 5 been be AUX eurjchem-221 19 6     SPACE eurjchem-221 19 7 used use VERB eurjchem-221 19 8     SPACE eurjchem-221 19 9 as as ADP eurjchem-221 19 10     SPACE eurjchem-221 19 11 a a DET eurjchem-221 19 12     SPACE eurjchem-221 19 13 tool tool NOUN eurjchem-221 19 14     SPACE eurjchem-221 19 15 to to PART eurjchem-221 19 16     SPACE eurjchem-221 19 17 explore explore VERB eurjchem-221 19 18     SPACE eurjchem-221 19 19 the the DET eurjchem-221 19 20     SPACE eurjchem-221 19 21 catalyst catalyst NOUN eurjchem-221 19 22     SPACE eurjchem-221 19 23 structure structure NOUN eurjchem-221 19 24     SPACE eurjchem-221 19 25 and and CCONJ eurjchem-221 19 26     SPACE eurjchem-221 19 27 mechanism mechanism NOUN eurjchem-221 19 28     SPACE eurjchem-221 19 29 of of ADP eurjchem-221 19 30     SPACE eurjchem-221 19 31 the the DET eurjchem-221 19 32     SPACE eurjchem-221 19 33 reaction reaction NOUN eurjchem-221 19 34 . . PUNCT eurjchem-221 19 35         SPACE eurjchem-221 20 1 2 2 NUM eurjchem-221 20 2 . . PUNCT eurjchem-221 20 3     SPACE eurjchem-221 20 4 experimental experimental ADJ eurjchem-221 20 5         SPACE eurjchem-221 20 6 2.1 2.1 NUM eurjchem-221 20 7 . . PUNCT eurjchem-221 20 8     SPACE eurjchem-221 20 9 materials material NOUN eurjchem-221 20 10         SPACE eurjchem-221 20 11 salicylaldehyde salicylaldehyde NOUN eurjchem-221 20 12 , , PUNCT eurjchem-221 20 13     SPACE eurjchem-221 20 14 2‐naphthol 2‐naphthol NOUN eurjchem-221 20 15 , , PUNCT eurjchem-221 20 16     SPACE eurjchem-221 20 17 and and CCONJ eurjchem-221 20 18     SPACE eurjchem-221 20 19 2,4‐di‐ter‐butyl 2,4‐di‐ter‐butyl NUM eurjchem-221 20 20     SPACE eurjchem-221 20 21 phenol phenol NOUN eurjchem-221 20 22     SPACE eurjchem-221 20 23 were be AUX eurjchem-221 20 24     SPACE eurjchem-221 20 25 purchased purchase VERB eurjchem-221 20 26     SPACE eurjchem-221 20 27 from from ADP eurjchem-221 20 28     SPACE eurjchem-221 20 29 himedia himedia NOUN eurjchem-221 20 30     SPACE eurjchem-221 20 31 and and CCONJ eurjchem-221 20 32     SPACE eurjchem-221 20 33 used use VERB eurjchem-221 20 34     SPACE eurjchem-221 20 35 without without ADP eurjchem-221 20 36     SPACE eurjchem-221 20 37 further further ADJ eurjchem-221 20 38     SPACE eurjchem-221 20 39 purification purification NOUN eurjchem-221 20 40 . . PUNCT eurjchem-221 20 41     SPACE eurjchem-221 21 1 1,2‐diaminocyclohexane 1,2‐diaminocyclohexane NOUN eurjchem-221 21 2     SPACE eurjchem-221 21 3 purchased purchase VERB eurjchem-221 21 4     SPACE eurjchem-221 21 5 from from ADP eurjchem-221 21 6     SPACE eurjchem-221 21 7 merck merck NOUN eurjchem-221 21 8     SPACE eurjchem-221 21 9 was be AUX eurjchem-221 21 10     SPACE eurjchem-221 21 11 resolved resolve VERB eurjchem-221 21 12     SPACE eurjchem-221 21 13 according accord VERB eurjchem-221 21 14     SPACE eurjchem-221 21 15 to to ADP eurjchem-221 21 16     SPACE eurjchem-221 21 17 the the DET eurjchem-221 21 18     SPACE eurjchem-221 21 19 literature literature NOUN eurjchem-221 21 20     SPACE eurjchem-221 21 21 procedure procedure NOUN eurjchem-221 21 22     SPACE eurjchem-221 21 23 [ [ X eurjchem-221 21 24 27 27 NUM eurjchem-221 21 25 ] ] PUNCT eurjchem-221 21 26 . . PUNCT eurjchem-221 21 27     SPACE eurjchem-221 21 28 formylation formylation NOUN eurjchem-221 21 29     SPACE eurjchem-221 21 30 of of ADP eurjchem-221 21 31     SPACE eurjchem-221 21 32 2,4‐di‐ter‐butyl 2,4‐di‐ter‐butyl NUM eurjchem-221 21 33     SPACE eurjchem-221 21 34 phenol phenol NOUN eurjchem-221 21 35     SPACE eurjchem-221 21 36 and and CCONJ eurjchem-221 21 37     SPACE eurjchem-221 21 38 2‐naphthol 2‐naphthol NOUN eurjchem-221 21 39     SPACE eurjchem-221 21 40 was be AUX eurjchem-221 21 41     SPACE eurjchem-221 21 42 carried carry VERB eurjchem-221 21 43     SPACE eurjchem-221 21 44 out out ADP eurjchem-221 21 45     SPACE eurjchem-221 21 46 by by ADP eurjchem-221 21 47     SPACE eurjchem-221 21 48 following follow VERB eurjchem-221 21 49     SPACE eurjchem-221 21 50 the the DET eurjchem-221 21 51     SPACE eurjchem-221 21 52 reported report VERB eurjchem-221 21 53     SPACE eurjchem-221 21 54 procedure procedure NOUN eurjchem-221 21 55     SPACE eurjchem-221 22 1 [ [ X eurjchem-221 22 2 27,28 27,28 NUM eurjchem-221 22 3 ] ] X eurjchem-221 22 4 . . PUNCT eurjchem-221 22 5         SPACE eurjchem-221 22 6 2.2 2.2 NUM eurjchem-221 22 7     SPACE eurjchem-221 22 8 product product NOUN eurjchem-221 22 9     SPACE eurjchem-221 22 10 identification identification NOUN eurjchem-221 22 11         SPACE eurjchem-221 22 12 melting melting NOUN eurjchem-221 22 13     SPACE eurjchem-221 22 14 points point NOUN eurjchem-221 22 15     SPACE eurjchem-221 22 16 were be AUX eurjchem-221 22 17     SPACE eurjchem-221 22 18 determined determine VERB eurjchem-221 22 19     SPACE eurjchem-221 22 20 in in ADP eurjchem-221 22 21     SPACE eurjchem-221 22 22 open open ADJ eurjchem-221 22 23     SPACE eurjchem-221 22 24 capillary capillary ADJ eurjchem-221 22 25     SPACE eurjchem-221 22 26 tubes tube NOUN eurjchem-221 22 27     SPACE eurjchem-221 22 28 on on ADP eurjchem-221 22 29     SPACE eurjchem-221 22 30 a a DET eurjchem-221 22 31     SPACE eurjchem-221 22 32 mpa mpa NOUN eurjchem-221 22 33     SPACE eurjchem-221 22 34 120 120 NUM eurjchem-221 22 35     SPACE eurjchem-221 22 36 melting melting NOUN eurjchem-221 22 37     SPACE eurjchem-221 22 38 point point NOUN eurjchem-221 22 39     SPACE eurjchem-221 22 40 apparatus apparatus NOUN eurjchem-221 22 41     SPACE eurjchem-221 22 42 and and CCONJ eurjchem-221 22 43     SPACE eurjchem-221 22 44 uncorrected uncorrecte VERB eurjchem-221 22 45 . . PUNCT eurjchem-221 22 46     SPACE eurjchem-221 22 47 the the DET eurjchem-221 22 48     SPACE eurjchem-221 22 49 1h 1h NUM eurjchem-221 22 50     SPACE eurjchem-221 22 51 nmr nmr NOUN eurjchem-221 22 52     SPACE eurjchem-221 22 53 spectra spectra NOUN eurjchem-221 22 54     SPACE eurjchem-221 22 55 were be AUX eurjchem-221 22 56     SPACE eurjchem-221 22 57 recorded record VERB eurjchem-221 22 58     SPACE eurjchem-221 22 59 on on ADP eurjchem-221 22 60     SPACE eurjchem-221 22 61 a a DET eurjchem-221 22 62     SPACE eurjchem-221 22 63 bruker bruker NOUN eurjchem-221 22 64     SPACE eurjchem-221 22 65 400 400 NUM eurjchem-221 22 66     SPACE eurjchem-221 22 67 mhz mhz NOUN eurjchem-221 22 68     SPACE eurjchem-221 22 69 spectrometer spectrometer NOUN eurjchem-221 22 70     SPACE eurjchem-221 22 71 and and CCONJ eurjchem-221 22 72     SPACE eurjchem-221 22 73 chemical chemical NOUN eurjchem-221 22 74     SPACE eurjchem-221 22 75 shift shift NOUN eurjchem-221 22 76     SPACE eurjchem-221 22 77 values value NOUN eurjchem-221 22 78     SPACE eurjchem-221 22 79 are be AUX eurjchem-221 22 80     SPACE eurjchem-221 22 81 reported report VERB eurjchem-221 22 82     SPACE eurjchem-221 22 83 in in ADP eurjchem-221 22 84     SPACE eurjchem-221 22 85 δ δ PROPN eurjchem-221 22 86     SPACE eurjchem-221 22 87 units unit NOUN eurjchem-221 22 88     SPACE eurjchem-221 22 89 ( ( PUNCT eurjchem-221 22 90 parts part NOUN eurjchem-221 22 91     SPACE eurjchem-221 22 92 per per ADP eurjchem-221 22 93     SPACE eurjchem-221 22 94 million million NUM eurjchem-221 22 95 ) ) PUNCT eurjchem-221 22 96     SPACE eurjchem-221 22 97 relative relative NOUN eurjchem-221 22 98     SPACE eurjchem-221 22 99 to to ADP eurjchem-221 22 100     SPACE eurjchem-221 22 101 me4si me4si NOUN eurjchem-221 22 102     SPACE eurjchem-221 22 103 as as ADP eurjchem-221 22 104     SPACE eurjchem-221 22 105 internal internal ADJ eurjchem-221 22 106     SPACE eurjchem-221 22 107 standard standard NOUN eurjchem-221 22 108 . . PUNCT eurjchem-221 22 109     SPACE eurjchem-221 22 110 ir ir PROPN eurjchem-221 22 111     SPACE eurjchem-221 22 112 spectra spectra NOUN eurjchem-221 22 113     SPACE eurjchem-221 22 114 were be AUX eurjchem-221 22 115     SPACE eurjchem-221 22 116 recorded record VERB eurjchem-221 22 117     SPACE eurjchem-221 22 118 on on ADP eurjchem-221 22 119     SPACE eurjchem-221 22 120 a a DET eurjchem-221 22 121     SPACE eurjchem-221 22 122 nicolet nicolet NOUN eurjchem-221 22 123     SPACE eurjchem-221 22 124 6700 6700 NUM eurjchem-221 22 125     SPACE eurjchem-221 22 126 ft‐ir ft‐ir NOUN eurjchem-221 22 127     SPACE eurjchem-221 22 128 spectrometer spectrometer NOUN eurjchem-221 22 129     SPACE eurjchem-221 22 130 in in ADP eurjchem-221 22 131     SPACE eurjchem-221 22 132 potassium potassium NOUN eurjchem-221 22 133     SPACE eurjchem-221 22 134 bromide bromide NOUN eurjchem-221 22 135     SPACE eurjchem-221 22 136 disc disc NOUN eurjchem-221 22 137     SPACE eurjchem-221 22 138 or or CCONJ eurjchem-221 22 139     SPACE eurjchem-221 22 140 neat neat ADJ eurjchem-221 22 141     SPACE eurjchem-221 22 142 thin thin ADJ eurjchem-221 22 143     SPACE eurjchem-221 22 144 film film NOUN eurjchem-221 22 145 . . PUNCT eurjchem-221 22 146     SPACE eurjchem-221 23 1 elemental elemental NOUN eurjchem-221 23 2     SPACE eurjchem-221 23 3 analyses analysis NOUN eurjchem-221 23 4     SPACE eurjchem-221 23 5 were be AUX eurjchem-221 23 6     SPACE eurjchem-221 23 7 carried carry VERB eurjchem-221 23 8     SPACE eurjchem-221 23 9 out out ADP eurjchem-221 23 10     SPACE eurjchem-221 23 11 on on ADP eurjchem-221 23 12     SPACE eurjchem-221 23 13 perkin‐elmer perkin‐elmer NOUN eurjchem-221 23 14     SPACE eurjchem-221 23 15 2400 2400 NUM eurjchem-221 23 16     SPACE eurjchem-221 23 17 series series NOUN eurjchem-221 23 18     SPACE eurjchem-221 23 19 chns chns PROPN eurjchem-221 23 20 / / SYM eurjchem-221 23 21 o o NOUN eurjchem-221 23 22     SPACE eurjchem-221 23 23 analyser analyser NOUN eurjchem-221 23 24 . . PUNCT eurjchem-221 23 25     SPACE eurjchem-221 24 1 all all DET eurjchem-221 24 2     SPACE eurjchem-221 24 3 the the DET eurjchem-221 24 4     SPACE eurjchem-221 24 5 epr epr PROPN eurjchem-221 24 6     SPACE eurjchem-221 24 7 spectra spectra NOUN eurjchem-221 24 8     SPACE eurjchem-221 24 9 were be AUX eurjchem-221 24 10     SPACE eurjchem-221 24 11 recorded record VERB eurjchem-221 24 12     SPACE eurjchem-221 24 13 on on ADP eurjchem-221 24 14     SPACE eurjchem-221 24 15 a a DET eurjchem-221 24 16     SPACE eurjchem-221 24 17 jeol jeol PROPN eurjchem-221 24 18     SPACE eurjchem-221 24 19 jes jes PROPN eurjchem-221 24 20     SPACE eurjchem-221 24 21 te100 te100 PROPN eurjchem-221 24 22     SPACE eurjchem-221 24 23 esr esr PROPN eurjchem-221 24 24     SPACE eurjchem-221 24 25 spectrometer spectrometer NOUN eurjchem-221 24 26     SPACE eurjchem-221 24 27 operating operating NOUN eurjchem-221 24 28     SPACE eurjchem-221 24 29 at at ADP eurjchem-221 24 30     SPACE eurjchem-221 24 31 x‐band x‐band NOUN eurjchem-221 24 32     SPACE eurjchem-221 24 33 frequencies frequency NOUN eurjchem-221 24 34     SPACE eurjchem-221 24 35 and and CCONJ eurjchem-221 24 36     SPACE eurjchem-221 24 37 having have VERB eurjchem-221 24 38     SPACE eurjchem-221 24 39 a a DET eurjchem-221 24 40     SPACE eurjchem-221 24 41 100 100 NUM eurjchem-221 24 42     SPACE eurjchem-221 24 43 khz khz NOUN eurjchem-221 24 44     SPACE eurjchem-221 24 45 modulation modulation NOUN eurjchem-221 24 46     SPACE eurjchem-221 24 47 to to PART eurjchem-221 24 48     SPACE eurjchem-221 24 49 obtain obtain VERB eurjchem-221 24 50     SPACE eurjchem-221 24 51 first first ADJ eurjchem-221 24 52     SPACE eurjchem-221 24 53 derivative derivative ADJ eurjchem-221 24 54     SPACE eurjchem-221 24 55 epr epr PROPN eurjchem-221 24 56     SPACE eurjchem-221 24 57 spectrum spectrum NOUN eurjchem-221 24 58 . . PUNCT eurjchem-221 24 59     SPACE eurjchem-221 24 60 epr epr PROPN eurjchem-221 24 61     SPACE eurjchem-221 24 62 spectra spectra NOUN eurjchem-221 24 63     SPACE eurjchem-221 24 64 at at ADP eurjchem-221 24 65     SPACE eurjchem-221 24 66 77 77 NUM eurjchem-221 24 67     SPACE eurjchem-221 24 68 k k NOUN eurjchem-221 24 69     SPACE eurjchem-221 24 70 were be AUX eurjchem-221 24 71     SPACE eurjchem-221 24 72 measured measure VERB eurjchem-221 24 73     SPACE eurjchem-221 24 74 by by ADP eurjchem-221 24 75     SPACE eurjchem-221 24 76 immersing immerse VERB eurjchem-221 24 77     SPACE eurjchem-221 24 78 the the DET eurjchem-221 24 79     SPACE eurjchem-221 24 80 sample sample NOUN eurjchem-221 24 81     SPACE eurjchem-221 24 82 in in ADP eurjchem-221 24 83     SPACE eurjchem-221 24 84 a a DET eurjchem-221 24 85     SPACE eurjchem-221 24 86 quartz quartz NOUN eurjchem-221 24 87     SPACE eurjchem-221 24 88 dewar dewar PROPN eurjchem-221 24 89     SPACE eurjchem-221 24 90 filled fill VERB eurjchem-221 24 91     SPACE eurjchem-221 24 92 with with ADP eurjchem-221 24 93     SPACE eurjchem-221 24 94 liquid liquid NOUN eurjchem-221 24 95     SPACE eurjchem-221 24 96 nitrogen nitrogen NOUN eurjchem-221 24 97 . . PUNCT eurjchem-221 24 98         SPACE eurjchem-221 24 99 2.3 2.3 NUM eurjchem-221 24 100     SPACE eurjchem-221 24 101 preparation preparation NOUN eurjchem-221 24 102     SPACE eurjchem-221 24 103 of of ADP eurjchem-221 24 104     SPACE eurjchem-221 24 105 ligands ligand NOUN eurjchem-221 24 106             SPACE eurjchem-221 24 107 all all DET eurjchem-221 24 108     SPACE eurjchem-221 24 109 salen salen PROPN eurjchem-221 24 110     SPACE eurjchem-221 24 111 ligands ligand NOUN eurjchem-221 24 112     SPACE eurjchem-221 24 113 were be AUX eurjchem-221 24 114     SPACE eurjchem-221 24 115 synthesized synthesize VERB eurjchem-221 24 116     SPACE eurjchem-221 24 117 according accord VERB eurjchem-221 24 118     SPACE eurjchem-221 24 119 to to ADP eurjchem-221 24 120     SPACE eurjchem-221 24 121 the the DET eurjchem-221 24 122     SPACE eurjchem-221 24 123 reported report VERB eurjchem-221 24 124     SPACE eurjchem-221 24 125 procedure procedure NOUN eurjchem-221 24 126     SPACE eurjchem-221 25 1 [ [ X eurjchem-221 25 2 29 29 NUM eurjchem-221 25 3 ] ] PUNCT eurjchem-221 25 4 . . PUNCT eurjchem-221 25 5     SPACE eurjchem-221 25 6 sabarinathan sabarinathan PROPN eurjchem-221 25 7     SPACE eurjchem-221 25 8 et et NOUN eurjchem-221 25 9     SPACE eurjchem-221 25 10 al al PROPN eurjchem-221 25 11 . . PROPN eurjchem-221 25 12     SPACE eurjchem-221 25 13 / / SYM eurjchem-221 25 14     SPACE eurjchem-221 25 15 european european ADJ eurjchem-221 25 16     SPACE eurjchem-221 25 17 journal journal NOUN eurjchem-221 25 18     SPACE eurjchem-221 25 19 of of ADP eurjchem-221 25 20     SPACE eurjchem-221 25 21 chemistry chemistry NOUN eurjchem-221 25 22     SPACE eurjchem-221 25 23 1 1 NUM eurjchem-221 25 24     SPACE eurjchem-221 25 25 ( ( PUNCT eurjchem-221 25 26 4 4 NUM eurjchem-221 25 27 ) ) PUNCT eurjchem-221 25 28     SPACE eurjchem-221 25 29 ( ( PUNCT eurjchem-221 25 30 2010 2010 NUM eurjchem-221 25 31 ) ) PUNCT eurjchem-221 25 32     SPACE eurjchem-221 25 33 360­367 360­367 NUM eurjchem-221 25 34     SPACE eurjchem-221 25 35 361 361 NUM eurjchem-221 25 36     SPACE eurjchem-221 25 37 2.4 2.4 NUM eurjchem-221 25 38 . . PUNCT eurjchem-221 25 39     SPACE eurjchem-221 25 40 preparation preparation NOUN eurjchem-221 25 41     SPACE eurjchem-221 25 42 of of ADP eurjchem-221 25 43     SPACE eurjchem-221 25 44 complexes complex NOUN eurjchem-221 25 45         SPACE eurjchem-221 25 46 2.4.1 2.4.1 NUM eurjchem-221 25 47 . . PUNCT eurjchem-221 25 48     SPACE eurjchem-221 25 49 preparation preparation NOUN eurjchem-221 25 50     SPACE eurjchem-221 25 51 of of ADP eurjchem-221 25 52     SPACE eurjchem-221 25 53 complex complex NOUN eurjchem-221 25 54     SPACE eurjchem-221 25 55 1 1 NUM eurjchem-221 25 56         SPACE eurjchem-221 25 57 to to ADP eurjchem-221 25 58     SPACE eurjchem-221 25 59 a a DET eurjchem-221 25 60     SPACE eurjchem-221 25 61 solution solution NOUN eurjchem-221 25 62     SPACE eurjchem-221 25 63 of of ADP eurjchem-221 25 64     SPACE eurjchem-221 25 65 ( ( PUNCT eurjchem-221 25 66 1r,2r)‐[n 1r,2r)‐[n NUM eurjchem-221 25 67 , , PUNCT eurjchem-221 25 68 n’­bis(2’‐hydoxybenzylidine)]‐ n’­bis(2’‐hydoxybenzylidine)]‐ PROPN eurjchem-221 25 69 1,2‐diaminocyclohexane 1,2‐diaminocyclohexane NOUN eurjchem-221 25 70     SPACE eurjchem-221 25 71 ( ( PUNCT eurjchem-221 25 72 1.32 1.32 NUM eurjchem-221 25 73     SPACE eurjchem-221 25 74 g g NOUN eurjchem-221 25 75 , , PUNCT eurjchem-221 25 76     SPACE eurjchem-221 25 77 4.1 4.1 NUM eurjchem-221 25 78     SPACE eurjchem-221 25 79 mmol mmol NOUN eurjchem-221 25 80 ) ) PUNCT eurjchem-221 25 81     SPACE eurjchem-221 25 82 in in ADP eurjchem-221 25 83     SPACE eurjchem-221 25 84 ethanol ethanol NOUN eurjchem-221 25 85 , , PUNCT eurjchem-221 25 86     SPACE eurjchem-221 25 87 cucl2.2h2o cucl2.2h2o VERB eurjchem-221 25 88     SPACE eurjchem-221 25 89 ( ( PUNCT eurjchem-221 25 90 0.69 0.69 NUM eurjchem-221 25 91     SPACE eurjchem-221 25 92 g g NOUN eurjchem-221 25 93 , , PUNCT eurjchem-221 25 94     SPACE eurjchem-221 25 95 4.1 4.1 NUM eurjchem-221 25 96     SPACE eurjchem-221 25 97 mmol mmol NOUN eurjchem-221 25 98 ) ) PUNCT eurjchem-221 25 99     SPACE eurjchem-221 25 100 in in ADP eurjchem-221 25 101     SPACE eurjchem-221 25 102 ethanol ethanol NOUN eurjchem-221 25 103     SPACE eurjchem-221 25 104 was be AUX eurjchem-221 25 105     SPACE eurjchem-221 25 106 added add VERB eurjchem-221 25 107 . . PUNCT eurjchem-221 25 108     SPACE eurjchem-221 26 1 the the DET eurjchem-221 26 2     SPACE eurjchem-221 26 3 reaction reaction NOUN eurjchem-221 26 4     SPACE eurjchem-221 26 5 mixture mixture NOUN eurjchem-221 26 6     SPACE eurjchem-221 26 7 was be AUX eurjchem-221 26 8     SPACE eurjchem-221 26 9 stirred stir VERB eurjchem-221 26 10     SPACE eurjchem-221 26 11 for for ADP eurjchem-221 26 12     SPACE eurjchem-221 26 13 3 3 NUM eurjchem-221 26 14     SPACE eurjchem-221 26 15 h h NOUN eurjchem-221 26 16     SPACE eurjchem-221 26 17 at at ADP eurjchem-221 26 18     SPACE eurjchem-221 26 19 ambient ambient ADJ eurjchem-221 26 20     SPACE eurjchem-221 26 21 temperature temperature NOUN eurjchem-221 26 22     SPACE eurjchem-221 26 23 then then ADV eurjchem-221 26 24     SPACE eurjchem-221 26 25 maintained maintain VERB eurjchem-221 26 26     SPACE eurjchem-221 26 27 at at ADP eurjchem-221 26 28     SPACE eurjchem-221 26 29 5 5 NUM eurjchem-221 26 30     SPACE eurjchem-221 26 31 οc οc NOUN eurjchem-221 26 32 . . PUNCT eurjchem-221 26 33     SPACE eurjchem-221 26 34 the the DET eurjchem-221 26 35     SPACE eurjchem-221 26 36 compound compound NOUN eurjchem-221 26 37     SPACE eurjchem-221 26 38 formed form VERB eurjchem-221 26 39     SPACE eurjchem-221 26 40 was be AUX eurjchem-221 26 41     SPACE eurjchem-221 26 42 filtered filter VERB eurjchem-221 26 43     SPACE eurjchem-221 26 44 and and CCONJ eurjchem-221 26 45     SPACE eurjchem-221 26 46 recrystallized recrystallize VERB eurjchem-221 26 47     SPACE eurjchem-221 26 48 from from ADP eurjchem-221 26 49     SPACE eurjchem-221 26 50 dichloromethane dichloromethane NOUN eurjchem-221 26 51     SPACE eurjchem-221 26 52 ( ( PUNCT eurjchem-221 26 53 30 30 NUM eurjchem-221 26 54     SPACE eurjchem-221 26 55 ml ml NOUN eurjchem-221 26 56 ) ) PUNCT eurjchem-221 26 57     SPACE eurjchem-221 26 58 in in ADP eurjchem-221 26 59     SPACE eurjchem-221 26 60 less less ADJ eurjchem-221 26 61     SPACE eurjchem-221 26 62 than than ADP eurjchem-221 26 63       SPACE eurjchem-221 26 64 5 5 NUM eurjchem-221 26 65     SPACE eurjchem-221 26 66 οc οc PROPN eurjchem-221 26 67 . . PUNCT eurjchem-221 26 68     SPACE eurjchem-221 26 69 yield yield NOUN eurjchem-221 26 70 : : PUNCT eurjchem-221 26 71     SPACE eurjchem-221 26 72 76 76 NUM eurjchem-221 26 73 % % NOUN eurjchem-221 26 74 . . PUNCT eurjchem-221 26 75     SPACE eurjchem-221 27 1 solubility solubility NOUN eurjchem-221 27 2 : : PUNCT eurjchem-221 27 3     SPACE eurjchem-221 27 4 sparingly sparingly ADV eurjchem-221 27 5     SPACE eurjchem-221 27 6 soluble soluble ADJ eurjchem-221 27 7     SPACE eurjchem-221 27 8 in in ADP eurjchem-221 27 9     SPACE eurjchem-221 27 10 chcl3 chcl3 PROPN eurjchem-221 27 11 , , PUNCT eurjchem-221 27 12     SPACE eurjchem-221 27 13 ch2cl2 ch2cl2 ADJ eurjchem-221 27 14 , , PUNCT eurjchem-221 27 15     SPACE eurjchem-221 27 16 accn accn VERB eurjchem-221 27 17 , , PUNCT eurjchem-221 27 18     SPACE eurjchem-221 27 19 acetone acetone NOUN eurjchem-221 27 20 , , PUNCT eurjchem-221 27 21     SPACE eurjchem-221 27 22 etoac etoac ADJ eurjchem-221 27 23 , , PUNCT eurjchem-221 27 24     SPACE eurjchem-221 27 25 meoh meoh NOUN eurjchem-221 27 26 , , PUNCT eurjchem-221 27 27     SPACE eurjchem-221 27 28 etoh etoh NOUN eurjchem-221 27 29     SPACE eurjchem-221 27 30 and and CCONJ eurjchem-221 27 31     SPACE eurjchem-221 27 32 soluble soluble ADJ eurjchem-221 27 33     SPACE eurjchem-221 27 34 in in ADP eurjchem-221 27 35     SPACE eurjchem-221 27 36 dmso dmso NOUN eurjchem-221 27 37 . . PUNCT eurjchem-221 27 38     SPACE eurjchem-221 28 1 m.p m.p PROPN eurjchem-221 28 2 . . PROPN eurjchem-221 28 3 : : PUNCT eurjchem-221 28 4     SPACE eurjchem-221 29 1 312 312 NUM eurjchem-221 29 2     SPACE eurjchem-221 29 3 οc οc PRON eurjchem-221 29 4     SPACE eurjchem-221 29 5 ( ( PUNCT eurjchem-221 29 6 dec dec PROPN eurjchem-221 29 7 ) ) PUNCT eurjchem-221 29 8 . . PUNCT eurjchem-221 29 9     SPACE eurjchem-221 30 1 esi esi PROPN eurjchem-221 30 2     SPACE eurjchem-221 30 3 mass mass NOUN eurjchem-221 30 4     SPACE eurjchem-221 30 5 m+ m+ NUM eurjchem-221 30 6 : : PUNCT eurjchem-221 30 7     SPACE eurjchem-221 30 8 384 384 NUM eurjchem-221 30 9 . . PUNCT eurjchem-221 30 10     SPACE eurjchem-221 30 11 ir ir PROPN eurjchem-221 30 12     SPACE eurjchem-221 30 13 ( ( PUNCT eurjchem-221 30 14 kbr kbr PROPN eurjchem-221 30 15 , , PUNCT eurjchem-221 30 16     SPACE eurjchem-221 30 17 cm‐1 cm‐1 NOUN eurjchem-221 30 18 ): ): PUNCT eurjchem-221 30 19     SPACE eurjchem-221 30 20 2932 2932 NUM eurjchem-221 30 21 , , PUNCT eurjchem-221 30 22     SPACE eurjchem-221 30 23 2858 2858 NUM eurjchem-221 30 24 , , PUNCT eurjchem-221 30 25     SPACE eurjchem-221 30 26 1630 1630 NUM eurjchem-221 30 27 , , PUNCT eurjchem-221 30 28     SPACE eurjchem-221 30 29 1603 1603 NUM eurjchem-221 30 30 , , PUNCT eurjchem-221 30 31     SPACE eurjchem-221 30 32 1545 1545 NUM eurjchem-221 30 33 , , PUNCT eurjchem-221 30 34     SPACE eurjchem-221 30 35 1393 1393 NUM eurjchem-221 30 36 , , PUNCT eurjchem-221 30 37     SPACE eurjchem-221 30 38 1345 1345 NUM eurjchem-221 30 39 , , PUNCT eurjchem-221 30 40     SPACE eurjchem-221 30 41 1305 1305 NUM eurjchem-221 30 42 , , PUNCT eurjchem-221 30 43     SPACE eurjchem-221 30 44 1282 1282 NUM eurjchem-221 30 45 , , PUNCT eurjchem-221 30 46     SPACE eurjchem-221 30 47 1199 1199 NUM eurjchem-221 30 48 , , PUNCT eurjchem-221 30 49     SPACE eurjchem-221 30 50 1152 1152 NUM eurjchem-221 30 51 , , PUNCT eurjchem-221 30 52     SPACE eurjchem-221 30 53 1026 1026 NUM eurjchem-221 30 54 , , PUNCT eurjchem-221 30 55     SPACE eurjchem-221 30 56 905 905 NUM eurjchem-221 30 57 , , PUNCT eurjchem-221 30 58     SPACE eurjchem-221 30 59 801 801 NUM eurjchem-221 30 60 , , PUNCT eurjchem-221 30 61     SPACE eurjchem-221 30 62 757 757 PROPN eurjchem-221 30 63 . . PUNCT eurjchem-221 30 64     SPACE eurjchem-221 30 65 anal anal ADJ eurjchem-221 30 66 . . PUNCT eurjchem-221 30 67     SPACE eurjchem-221 30 68 calcd calcd NOUN eurjchem-221 30 69 . . PUNCT eurjchem-221 30 70     SPACE eurjchem-221 30 71 for for ADP eurjchem-221 30 72     SPACE eurjchem-221 30 73 c20h20cun2o2 c20h20cun2o2 VERB eurjchem-221 30 74 : : PUNCT eurjchem-221 30 75     SPACE eurjchem-221 30 76 c c X eurjchem-221 30 77 , , PUNCT eurjchem-221 30 78     SPACE eurjchem-221 30 79 62.57 62.57 NUM eurjchem-221 30 80 ; ; PUNCT eurjchem-221 30 81     SPACE eurjchem-221 30 82 h h NOUN eurjchem-221 30 83 , , PUNCT eurjchem-221 30 84     SPACE eurjchem-221 30 85 5.25 5.25 NUM eurjchem-221 30 86 ; ; PUNCT eurjchem-221 30 87     SPACE eurjchem-221 30 88 n n CCONJ eurjchem-221 30 89 , , PUNCT eurjchem-221 30 90     SPACE eurjchem-221 30 91 7.30 7.30 NUM eurjchem-221 30 92 . . PUNCT eurjchem-221 30 93     SPACE eurjchem-221 30 94 found find VERB eurjchem-221 30 95     SPACE eurjchem-221 30 96 c c NOUN eurjchem-221 30 97 , , PUNCT eurjchem-221 30 98     SPACE eurjchem-221 30 99 62.95 62.95 NUM eurjchem-221 30 100 ; ; PUNCT eurjchem-221 30 101     SPACE eurjchem-221 30 102 h h NOUN eurjchem-221 30 103 , , PUNCT eurjchem-221 30 104     SPACE eurjchem-221 30 105 5.39 5.39 NUM eurjchem-221 30 106 ; ; PUNCT eurjchem-221 30 107     SPACE eurjchem-221 30 108 n n CCONJ eurjchem-221 30 109 , , PUNCT eurjchem-221 30 110     SPACE eurjchem-221 30 111 7.40 7.40 NUM eurjchem-221 30 112 . . PUNCT eurjchem-221 30 113         SPACE eurjchem-221 30 114 2.4.2 2.4.2 NUM eurjchem-221 30 115 . . PUNCT eurjchem-221 30 116     SPACE eurjchem-221 30 117 preparation preparation NOUN eurjchem-221 30 118     SPACE eurjchem-221 30 119 of of ADP eurjchem-221 30 120     SPACE eurjchem-221 30 121 complex complex ADJ eurjchem-221 30 122     SPACE eurjchem-221 30 123 2 2 NUM eurjchem-221 30 124         SPACE eurjchem-221 30 125 the the DET eurjchem-221 30 126     SPACE eurjchem-221 30 127 complex complex NOUN eurjchem-221 30 128     SPACE eurjchem-221 30 129 was be AUX eurjchem-221 30 130     SPACE eurjchem-221 30 131 synthesized synthesize VERB eurjchem-221 30 132     SPACE eurjchem-221 30 133 following follow VERB eurjchem-221 30 134     SPACE eurjchem-221 30 135 the the DET eurjchem-221 30 136     SPACE eurjchem-221 30 137 procedure procedure NOUN eurjchem-221 30 138     SPACE eurjchem-221 30 139 described describe VERB eurjchem-221 30 140     SPACE eurjchem-221 30 141 for for ADP eurjchem-221 30 142     SPACE eurjchem-221 30 143 complex complex NOUN eurjchem-221 30 144     SPACE eurjchem-221 30 145 1 1 NUM eurjchem-221 30 146     SPACE eurjchem-221 30 147 using use VERB eurjchem-221 30 148     SPACE eurjchem-221 30 149 ( ( PUNCT eurjchem-221 30 150 1r,2r)‐[n 1r,2r)‐[n NUM eurjchem-221 30 151 , , PUNCT eurjchem-221 30 152 n’­bis(2’‐hydoxy‐ n’­bis(2’‐hydoxy‐ NOUN eurjchem-221 30 153 3’,5’‐di‐t‐butyl‐benzylidine)]‐1,2‐diaminocyclohexane 3’,5’‐di‐t‐butyl‐benzylidine)]‐1,2‐diaminocyclohexane NUM eurjchem-221 30 154 , , PUNCT eurjchem-221 30 155     SPACE eurjchem-221 30 156 but but CCONJ eurjchem-221 30 157     SPACE eurjchem-221 30 158 met‐ met‐ VERB eurjchem-221 30 159 hanol hanol NOUN eurjchem-221 30 160     SPACE eurjchem-221 30 161 ( ( PUNCT eurjchem-221 30 162 30 30 NUM eurjchem-221 30 163     SPACE eurjchem-221 30 164 ml ml NOUN eurjchem-221 30 165 ) ) PUNCT eurjchem-221 30 166     SPACE eurjchem-221 30 167 was be AUX eurjchem-221 30 168     SPACE eurjchem-221 30 169 used use VERB eurjchem-221 30 170     SPACE eurjchem-221 30 171 as as ADP eurjchem-221 30 172     SPACE eurjchem-221 30 173 solvent solvent NOUN eurjchem-221 30 174 . . PUNCT eurjchem-221 30 175     SPACE eurjchem-221 30 176 yield yield NOUN eurjchem-221 30 177 : : PUNCT eurjchem-221 30 178     SPACE eurjchem-221 30 179 99 99 NUM eurjchem-221 30 180 % % NOUN eurjchem-221 30 181 . . PUNCT eurjchem-221 30 182     SPACE eurjchem-221 31 1 solubility solubility NOUN eurjchem-221 31 2 : : PUNCT eurjchem-221 31 3     SPACE eurjchem-221 31 4 sparingly sparingly ADV eurjchem-221 31 5     SPACE eurjchem-221 31 6 soluble soluble ADJ eurjchem-221 31 7     SPACE eurjchem-221 31 8 in in ADP eurjchem-221 31 9     SPACE eurjchem-221 31 10 meoh meoh NOUN eurjchem-221 31 11 , , PUNCT eurjchem-221 31 12     SPACE eurjchem-221 31 13 etoh etoh NOUN eurjchem-221 31 14     SPACE eurjchem-221 31 15 and and CCONJ eurjchem-221 31 16     SPACE eurjchem-221 31 17 soluble soluble ADJ eurjchem-221 31 18     SPACE eurjchem-221 31 19 in in ADP eurjchem-221 31 20     SPACE eurjchem-221 31 21 chcl3 chcl3 PROPN eurjchem-221 31 22 , , PUNCT eurjchem-221 31 23     SPACE eurjchem-221 31 24 ch2cl2 ch2cl2 ADJ eurjchem-221 31 25 , , PUNCT eurjchem-221 31 26     SPACE eurjchem-221 31 27 accn accn VERB eurjchem-221 31 28 , , PUNCT eurjchem-221 31 29     SPACE eurjchem-221 31 30 acetone acetone NOUN eurjchem-221 31 31 , , PUNCT eurjchem-221 31 32     SPACE eurjchem-221 31 33 etoac etoac ADJ eurjchem-221 31 34 , , PUNCT eurjchem-221 31 35     SPACE eurjchem-221 31 36 dmf dmf PROPN eurjchem-221 31 37 , , PUNCT eurjchem-221 31 38     SPACE eurjchem-221 31 39 dmso dmso NOUN eurjchem-221 31 40 , , PUNCT eurjchem-221 31 41     SPACE eurjchem-221 31 42 chlorobenzene chlorobenzene NOUN eurjchem-221 31 43 , , PUNCT eurjchem-221 31 44     SPACE eurjchem-221 31 45 toluene toluene NOUN eurjchem-221 31 46 . . PUNCT eurjchem-221 31 47     SPACE eurjchem-221 32 1 m.p m.p PROPN eurjchem-221 32 2 . . PROPN eurjchem-221 32 3 : : PUNCT eurjchem-221 32 4     SPACE eurjchem-221 33 1 265‐270 265‐270 NUM eurjchem-221 33 2     SPACE eurjchem-221 33 3 οc οc PRON eurjchem-221 33 4     SPACE eurjchem-221 33 5 ( ( PUNCT eurjchem-221 33 6 dec dec PROPN eurjchem-221 33 7 ) ) PUNCT eurjchem-221 33 8 . . PUNCT eurjchem-221 33 9     SPACE eurjchem-221 34 1 esi esi PROPN eurjchem-221 34 2     SPACE eurjchem-221 34 3 mass mass PROPN eurjchem-221 34 4     SPACE eurjchem-221 34 5 m+ m+ NUM eurjchem-221 34 6 : : PUNCT eurjchem-221 34 7     SPACE eurjchem-221 34 8 608 608 NUM eurjchem-221 34 9 . . PUNCT eurjchem-221 34 10     SPACE eurjchem-221 35 1 ir ir VERB eurjchem-221 35 2     SPACE eurjchem-221 35 3 ( ( PUNCT eurjchem-221 35 4 kbr kbr PROPN eurjchem-221 35 5 , , PUNCT eurjchem-221 35 6     SPACE eurjchem-221 35 7 cm‐1 cm‐1 NOUN eurjchem-221 35 8 ): ): PUNCT eurjchem-221 35 9     SPACE eurjchem-221 35 10 2954 2954 NUM eurjchem-221 35 11 , , PUNCT eurjchem-221 35 12     SPACE eurjchem-221 35 13 2866 2866 NUM eurjchem-221 35 14 , , PUNCT eurjchem-221 35 15     SPACE eurjchem-221 35 16 1621 1621 NUM eurjchem-221 35 17 , , PUNCT eurjchem-221 35 18     SPACE eurjchem-221 35 19 1526 1526 NUM eurjchem-221 35 20 , , PUNCT eurjchem-221 35 21     SPACE eurjchem-221 35 22 1462 1462 NUM eurjchem-221 35 23 , , PUNCT eurjchem-221 35 24     SPACE eurjchem-221 35 25 1432 1432 NUM eurjchem-221 35 26 , , PUNCT eurjchem-221 35 27     SPACE eurjchem-221 35 28 1346 1346 NUM eurjchem-221 35 29 , , PUNCT eurjchem-221 35 30     SPACE eurjchem-221 35 31 1322 1322 NUM eurjchem-221 35 32 , , PUNCT eurjchem-221 35 33     SPACE eurjchem-221 35 34 1254 1254 NUM eurjchem-221 35 35 , , PUNCT eurjchem-221 35 36     SPACE eurjchem-221 35 37 1165 1165 NUM eurjchem-221 35 38 . . PUNCT eurjchem-221 35 39     SPACE eurjchem-221 36 1 anal anal ADJ eurjchem-221 36 2 . . PUNCT eurjchem-221 36 3     SPACE eurjchem-221 36 4 calcd calcd NOUN eurjchem-221 36 5 . . PUNCT eurjchem-221 36 6     SPACE eurjchem-221 36 7 for for ADP eurjchem-221 36 8     SPACE eurjchem-221 36 9 c36h52cun2o2 c36h52cun2o2 VERB eurjchem-221 36 10 : : PUNCT eurjchem-221 36 11     SPACE eurjchem-221 36 12 c c X eurjchem-221 36 13 , , PUNCT eurjchem-221 36 14     SPACE eurjchem-221 36 15 71.07 71.07 NUM eurjchem-221 36 16 ; ; PUNCT eurjchem-221 36 17     SPACE eurjchem-221 36 18 h h NOUN eurjchem-221 36 19 , , PUNCT eurjchem-221 36 20     SPACE eurjchem-221 36 21 8.62 8.62 NUM eurjchem-221 36 22 ; ; PUNCT eurjchem-221 36 23     SPACE eurjchem-221 36 24 n n CCONJ eurjchem-221 36 25 , , PUNCT eurjchem-221 36 26     SPACE eurjchem-221 36 27 4.60 4.60 NUM eurjchem-221 36 28 . . PUNCT eurjchem-221 36 29     SPACE eurjchem-221 36 30 found find VERB eurjchem-221 36 31     SPACE eurjchem-221 36 32 c c NOUN eurjchem-221 36 33 , , PUNCT eurjchem-221 36 34     SPACE eurjchem-221 36 35 71.13 71.13 NUM eurjchem-221 36 36 ; ; PUNCT eurjchem-221 36 37     SPACE eurjchem-221 36 38 h h NOUN eurjchem-221 36 39 , , PUNCT eurjchem-221 36 40     SPACE eurjchem-221 36 41 8.57 8.57 NUM eurjchem-221 36 42 ; ; PUNCT eurjchem-221 36 43     SPACE eurjchem-221 36 44 n n CCONJ eurjchem-221 36 45 , , PUNCT eurjchem-221 36 46     SPACE eurjchem-221 36 47 4.61 4.61 NUM eurjchem-221 36 48 . . PUNCT eurjchem-221 36 49         SPACE eurjchem-221 36 50 2.4.3 2.4.3 NUM eurjchem-221 36 51 . . PUNCT eurjchem-221 36 52     SPACE eurjchem-221 36 53 preparation preparation NOUN eurjchem-221 36 54     SPACE eurjchem-221 36 55 of of ADP eurjchem-221 36 56     SPACE eurjchem-221 36 57 complex complex NOUN eurjchem-221 36 58     SPACE eurjchem-221 36 59 3 3 NUM eurjchem-221 36 60         SPACE eurjchem-221 36 61 the the DET eurjchem-221 36 62     SPACE eurjchem-221 36 63 complex complex NOUN eurjchem-221 36 64     SPACE eurjchem-221 36 65 was be AUX eurjchem-221 36 66     SPACE eurjchem-221 36 67 synthesized synthesize VERB eurjchem-221 36 68     SPACE eurjchem-221 36 69 following follow VERB eurjchem-221 36 70     SPACE eurjchem-221 36 71 the the DET eurjchem-221 36 72     SPACE eurjchem-221 36 73 procedure procedure NOUN eurjchem-221 36 74     SPACE eurjchem-221 36 75 described describe VERB eurjchem-221 36 76     SPACE eurjchem-221 36 77 for for ADP eurjchem-221 36 78     SPACE eurjchem-221 36 79 complex complex NOUN eurjchem-221 36 80     SPACE eurjchem-221 36 81 1 1 NUM eurjchem-221 36 82     SPACE eurjchem-221 36 83 using use VERB eurjchem-221 36 84     SPACE eurjchem-221 36 85 ( ( PUNCT eurjchem-221 36 86 1r,2r)‐[n 1r,2r)‐[n NUM eurjchem-221 36 87 , , PUNCT eurjchem-221 36 88 n’­bis(2’‐ n’­bis(2’‐ PUNCT eurjchem-221 37 1 hydoxynaphthylidine)]‐1,2‐diaminocyclohexane hydoxynaphthylidine)]‐1,2‐diaminocyclohexane PROPN eurjchem-221 37 2 . . PUNCT eurjchem-221 37 3     SPACE eurjchem-221 37 4 yield yield NOUN eurjchem-221 37 5 : : PUNCT eurjchem-221 37 6     SPACE eurjchem-221 37 7 99 99 NUM eurjchem-221 37 8 % % NOUN eurjchem-221 37 9 . . PUNCT eurjchem-221 37 10     SPACE eurjchem-221 38 1 solubility solubility NOUN eurjchem-221 38 2 : : PUNCT eurjchem-221 38 3     SPACE eurjchem-221 38 4 soluble soluble ADJ eurjchem-221 38 5     SPACE eurjchem-221 38 6 in in ADP eurjchem-221 38 7     SPACE eurjchem-221 38 8 chcl3 chcl3 PROPN eurjchem-221 38 9 , , PUNCT eurjchem-221 38 10     SPACE eurjchem-221 38 11 ch2cl2 ch2cl2 PROPN eurjchem-221 38 12 , , PUNCT eurjchem-221 38 13     SPACE eurjchem-221 38 14 accn accn VERB eurjchem-221 38 15 , , PUNCT eurjchem-221 38 16     SPACE eurjchem-221 38 17 acetone acetone NOUN eurjchem-221 38 18 , , PUNCT eurjchem-221 38 19     SPACE eurjchem-221 38 20 etoac etoac ADJ eurjchem-221 38 21 , , PUNCT eurjchem-221 38 22     SPACE eurjchem-221 38 23 dmf dmf PROPN eurjchem-221 38 24 , , PUNCT eurjchem-221 38 25     SPACE eurjchem-221 38 26 dmso dmso NOUN eurjchem-221 38 27 . . PUNCT eurjchem-221 38 28     SPACE eurjchem-221 39 1 m.p m.p PROPN eurjchem-221 39 2 . . PROPN eurjchem-221 39 3 : : PUNCT eurjchem-221 39 4     SPACE eurjchem-221 39 5 not not PART eurjchem-221 39 6     SPACE eurjchem-221 39 7 melted melt VERB eurjchem-221 39 8     SPACE eurjchem-221 39 9 > > SYM eurjchem-221 39 10     SPACE eurjchem-221 39 11 320 320 NUM eurjchem-221 39 12     SPACE eurjchem-221 39 13 οc οc PROPN eurjchem-221 39 14 . . PUNCT eurjchem-221 39 15     SPACE eurjchem-221 39 16 esi esi PROPN eurjchem-221 39 17     SPACE eurjchem-221 39 18 mass mass PROPN eurjchem-221 39 19     SPACE eurjchem-221 39 20 m+ m+ NUM eurjchem-221 39 21 : : PUNCT eurjchem-221 39 22     SPACE eurjchem-221 39 23 484 484 NUM eurjchem-221 39 24 . . PUNCT eurjchem-221 39 25     SPACE eurjchem-221 40 1 ir ir VERB eurjchem-221 40 2     SPACE eurjchem-221 40 3 ( ( PUNCT eurjchem-221 40 4 kbr kbr PROPN eurjchem-221 40 5 , , PUNCT eurjchem-221 40 6     SPACE eurjchem-221 40 7 cm‐ cm‐ X eurjchem-221 40 8 1 1 NUM eurjchem-221 40 9 ): ): PUNCT eurjchem-221 40 10     SPACE eurjchem-221 40 11 2932 2932 NUM eurjchem-221 40 12 , , PUNCT eurjchem-221 40 13     SPACE eurjchem-221 40 14 2360 2360 NUM eurjchem-221 40 15 , , PUNCT eurjchem-221 40 16     SPACE eurjchem-221 40 17 1615 1615 NUM eurjchem-221 40 18 , , PUNCT eurjchem-221 40 19     SPACE eurjchem-221 40 20 1538 1538 NUM eurjchem-221 40 21 , , PUNCT eurjchem-221 40 22     SPACE eurjchem-221 40 23 1508 1508 NUM eurjchem-221 40 24 , , PUNCT eurjchem-221 40 25     SPACE eurjchem-221 40 26 1397 1397 NUM eurjchem-221 40 27 , , PUNCT eurjchem-221 40 28     SPACE eurjchem-221 40 29 1345 1345 NUM eurjchem-221 40 30 , , PUNCT eurjchem-221 40 31     SPACE eurjchem-221 40 32 1310 1310 NUM eurjchem-221 40 33 , , PUNCT eurjchem-221 40 34     SPACE eurjchem-221 40 35 1183 1183 NUM eurjchem-221 40 36 , , PUNCT eurjchem-221 40 37     SPACE eurjchem-221 40 38 1091 1091 NUM eurjchem-221 40 39 , , PUNCT eurjchem-221 40 40     SPACE eurjchem-221 40 41 1037 1037 NUM eurjchem-221 40 42 , , PUNCT eurjchem-221 40 43     SPACE eurjchem-221 40 44 827 827 NUM eurjchem-221 40 45 , , PUNCT eurjchem-221 40 46     SPACE eurjchem-221 40 47 739 739 NUM eurjchem-221 40 48 . . PUNCT eurjchem-221 40 49     SPACE eurjchem-221 41 1 anal anal ADJ eurjchem-221 41 2 . . PUNCT eurjchem-221 41 3     SPACE eurjchem-221 41 4 calcd calcd NOUN eurjchem-221 41 5 . . PUNCT eurjchem-221 41 6     SPACE eurjchem-221 41 7 for for ADP eurjchem-221 41 8     SPACE eurjchem-221 41 9 c28h24cun2o2 c28h24cun2o2 VERB eurjchem-221 41 10 : : PUNCT eurjchem-221 41 11     SPACE eurjchem-221 41 12 c c X eurjchem-221 41 13 , , PUNCT eurjchem-221 41 14     SPACE eurjchem-221 41 15 69.48 69.48 NUM eurjchem-221 41 16 ; ; PUNCT eurjchem-221 41 17     SPACE eurjchem-221 41 18 h h NOUN eurjchem-221 41 19 , , PUNCT eurjchem-221 41 20     SPACE eurjchem-221 41 21 5.00 5.00 NUM eurjchem-221 41 22 ; ; PUNCT eurjchem-221 41 23     SPACE eurjchem-221 41 24 n n CCONJ eurjchem-221 41 25 , , PUNCT eurjchem-221 41 26     SPACE eurjchem-221 41 27 5.79 5.79 NUM eurjchem-221 41 28 . . PUNCT eurjchem-221 41 29     SPACE eurjchem-221 41 30 found find VERB eurjchem-221 41 31     SPACE eurjchem-221 41 32 c c NOUN eurjchem-221 41 33 , , PUNCT eurjchem-221 41 34     SPACE eurjchem-221 41 35 69.55 69.55 NUM eurjchem-221 41 36 ; ; PUNCT eurjchem-221 41 37     SPACE eurjchem-221 41 38 h h NOUN eurjchem-221 41 39 , , PUNCT eurjchem-221 41 40     SPACE eurjchem-221 41 41 4.98 4.98 NUM eurjchem-221 41 42 ; ; PUNCT eurjchem-221 41 43     SPACE eurjchem-221 41 44 n n CCONJ eurjchem-221 41 45 , , PUNCT eurjchem-221 41 46     SPACE eurjchem-221 41 47 5.74 5.74 NUM eurjchem-221 41 48 . . PUNCT eurjchem-221 41 49         SPACE eurjchem-221 42 1 2.4.4 2.4.4 NUM eurjchem-221 42 2 . . PUNCT eurjchem-221 42 3     SPACE eurjchem-221 42 4 preparation preparation NOUN eurjchem-221 42 5     SPACE eurjchem-221 42 6 of of ADP eurjchem-221 42 7     SPACE eurjchem-221 42 8 complex complex NOUN eurjchem-221 42 9     SPACE eurjchem-221 42 10 4 4 NUM eurjchem-221 42 11         SPACE eurjchem-221 42 12 to to ADP eurjchem-221 42 13     SPACE eurjchem-221 42 14 a a DET eurjchem-221 42 15     SPACE eurjchem-221 42 16 solution solution NOUN eurjchem-221 42 17     SPACE eurjchem-221 42 18 of of ADP eurjchem-221 42 19     SPACE eurjchem-221 42 20 bis(2’‐hydoxybenzylidine)]‐1,2‐diamino bis(2’‐hydoxybenzylidine)]‐1,2‐diamino NOUN eurjchem-221 42 21     SPACE eurjchem-221 42 22 benzene benzene NOUN eurjchem-221 42 23     SPACE eurjchem-221 42 24 ( ( PUNCT eurjchem-221 42 25 1.89 1.89 NUM eurjchem-221 42 26     SPACE eurjchem-221 42 27 g g NOUN eurjchem-221 42 28 , , PUNCT eurjchem-221 42 29     SPACE eurjchem-221 42 30 6 6 NUM eurjchem-221 42 31     SPACE eurjchem-221 42 32 mmol mmol NOUN eurjchem-221 42 33 ) ) PUNCT eurjchem-221 42 34     SPACE eurjchem-221 42 35 in in ADP eurjchem-221 42 36     SPACE eurjchem-221 42 37 ethanol ethanol NOUN eurjchem-221 42 38     SPACE eurjchem-221 42 39 cucl2.2h2o cucl2.2h2o NOUN eurjchem-221 42 40     SPACE eurjchem-221 42 41 ( ( PUNCT eurjchem-221 42 42 1.02 1.02 NUM eurjchem-221 42 43     SPACE eurjchem-221 42 44 g g NOUN eurjchem-221 42 45 , , PUNCT eurjchem-221 42 46     SPACE eurjchem-221 42 47 6 6 NUM eurjchem-221 42 48     SPACE eurjchem-221 42 49 mmol mmol NOUN eurjchem-221 42 50 ) ) PUNCT eurjchem-221 42 51     SPACE eurjchem-221 42 52 in in ADP eurjchem-221 42 53     SPACE eurjchem-221 42 54 ethanol ethanol NOUN eurjchem-221 42 55     SPACE eurjchem-221 42 56 was be AUX eurjchem-221 42 57     SPACE eurjchem-221 42 58 added add VERB eurjchem-221 42 59 . . PUNCT eurjchem-221 42 60     SPACE eurjchem-221 43 1 the the DET eurjchem-221 43 2     SPACE eurjchem-221 43 3 reaction reaction NOUN eurjchem-221 43 4     SPACE eurjchem-221 43 5 mixture mixture NOUN eurjchem-221 43 6     SPACE eurjchem-221 43 7 was be AUX eurjchem-221 43 8     SPACE eurjchem-221 43 9 stirred stir VERB eurjchem-221 43 10     SPACE eurjchem-221 43 11 for for ADP eurjchem-221 43 12     SPACE eurjchem-221 43 13 6 6 NUM eurjchem-221 43 14     SPACE eurjchem-221 43 15 h h NOUN eurjchem-221 43 16     SPACE eurjchem-221 43 17 at at ADP eurjchem-221 43 18     SPACE eurjchem-221 43 19 ambient ambient ADJ eurjchem-221 43 20     SPACE eurjchem-221 43 21 temperature temperature NOUN eurjchem-221 43 22     SPACE eurjchem-221 43 23 then then ADV eurjchem-221 43 24     SPACE eurjchem-221 43 25 maintained maintain VERB eurjchem-221 43 26     SPACE eurjchem-221 43 27 at at ADP eurjchem-221 43 28     SPACE eurjchem-221 43 29 5 5 NUM eurjchem-221 43 30     SPACE eurjchem-221 43 31 οc οc NOUN eurjchem-221 43 32 . . PUNCT eurjchem-221 43 33     SPACE eurjchem-221 43 34 the the DET eurjchem-221 43 35     SPACE eurjchem-221 43 36 compound compound NOUN eurjchem-221 43 37     SPACE eurjchem-221 43 38 formed form VERB eurjchem-221 43 39     SPACE eurjchem-221 43 40 was be AUX eurjchem-221 43 41     SPACE eurjchem-221 43 42 filtered filter VERB eurjchem-221 43 43     SPACE eurjchem-221 43 44 and and CCONJ eurjchem-221 43 45     SPACE eurjchem-221 43 46 washed wash VERB eurjchem-221 43 47     SPACE eurjchem-221 43 48 by by ADP eurjchem-221 43 49     SPACE eurjchem-221 43 50 dichloromethane dichloromethane NOUN eurjchem-221 43 51     SPACE eurjchem-221 43 52 ( ( PUNCT eurjchem-221 43 53 20 20 NUM eurjchem-221 43 54     SPACE eurjchem-221 43 55 ml ml NOUN eurjchem-221 43 56     SPACE eurjchem-221 43 57 x x NOUN eurjchem-221 43 58     SPACE eurjchem-221 43 59 2 2 NUM eurjchem-221 43 60 ) ) PUNCT eurjchem-221 43 61 . . PUNCT eurjchem-221 43 62     SPACE eurjchem-221 44 1 yield yield NOUN eurjchem-221 44 2 : : PUNCT eurjchem-221 44 3     SPACE eurjchem-221 44 4 57 57 NUM eurjchem-221 44 5 % % NOUN eurjchem-221 44 6 . . PUNCT eurjchem-221 44 7     SPACE eurjchem-221 45 1 solubility solubility NOUN eurjchem-221 45 2 : : PUNCT eurjchem-221 45 3     SPACE eurjchem-221 45 4 soluble soluble ADJ eurjchem-221 45 5     SPACE eurjchem-221 45 6 in in ADP eurjchem-221 45 7     SPACE eurjchem-221 45 8 chcl3 chcl3 PROPN eurjchem-221 45 9 , , PUNCT eurjchem-221 45 10     SPACE eurjchem-221 45 11 ch2cl2 ch2cl2 PROPN eurjchem-221 45 12 , , PUNCT eurjchem-221 45 13     SPACE eurjchem-221 45 14 meoh meoh NOUN eurjchem-221 45 15 , , PUNCT eurjchem-221 45 16     SPACE eurjchem-221 45 17 etoh etoh NOUN eurjchem-221 45 18 , , PUNCT eurjchem-221 45 19     SPACE eurjchem-221 45 20 etoac etoac ADJ eurjchem-221 45 21 , , PUNCT eurjchem-221 45 22     SPACE eurjchem-221 45 23 acetone acetone NOUN eurjchem-221 45 24 , , PUNCT eurjchem-221 45 25     SPACE eurjchem-221 45 26 accn accn VERB eurjchem-221 45 27 , , PUNCT eurjchem-221 45 28     SPACE eurjchem-221 45 29 dmf dmf PROPN eurjchem-221 45 30 , , PUNCT eurjchem-221 45 31     SPACE eurjchem-221 45 32 dmso dmso NOUN eurjchem-221 45 33 . . PUNCT eurjchem-221 45 34     SPACE eurjchem-221 46 1 m.p m.p PROPN eurjchem-221 46 2 . . PROPN eurjchem-221 46 3 : : PUNCT eurjchem-221 46 4     SPACE eurjchem-221 46 5 189 189 NUM eurjchem-221 46 6     SPACE eurjchem-221 46 7 οc οc PRON eurjchem-221 46 8     SPACE eurjchem-221 46 9 ( ( PUNCT eurjchem-221 46 10 dec dec PROPN eurjchem-221 46 11 ) ) PUNCT eurjchem-221 46 12 . . PUNCT eurjchem-221 46 13     SPACE eurjchem-221 47 1 esi esi PROPN eurjchem-221 47 2     SPACE eurjchem-221 47 3 mass mass PROPN eurjchem-221 47 4     SPACE eurjchem-221 47 5 m+ m+ NUM eurjchem-221 47 6 : : PUNCT eurjchem-221 47 7     SPACE eurjchem-221 47 8 378 378 NUM eurjchem-221 47 9 . . PUNCT eurjchem-221 47 10     SPACE eurjchem-221 47 11 ir ir VERB eurjchem-221 47 12     SPACE eurjchem-221 47 13 ( ( PUNCT eurjchem-221 47 14 kbr kbr PROPN eurjchem-221 47 15 , , PUNCT eurjchem-221 47 16     SPACE eurjchem-221 47 17 cm‐1):1607 cm‐1):1607 ADJ eurjchem-221 47 18 , , PUNCT eurjchem-221 47 19     SPACE eurjchem-221 47 20 1580 1580 NUM eurjchem-221 47 21 , , PUNCT eurjchem-221 47 22     SPACE eurjchem-221 47 23 1534 1534 NUM eurjchem-221 47 24 , , PUNCT eurjchem-221 47 25     SPACE eurjchem-221 47 26 1466 1466 NUM eurjchem-221 47 27 , , PUNCT eurjchem-221 47 28     SPACE eurjchem-221 47 29 1439 1439 NUM eurjchem-221 47 30 , , PUNCT eurjchem-221 47 31     SPACE eurjchem-221 47 32 1386 1386 NUM eurjchem-221 47 33 , , PUNCT eurjchem-221 47 34     SPACE eurjchem-221 47 35 1306 1306 NUM eurjchem-221 47 36 , , PUNCT eurjchem-221 47 37     SPACE eurjchem-221 47 38 1191 1191 NUM eurjchem-221 47 39 , , PUNCT eurjchem-221 47 40     SPACE eurjchem-221 47 41 1153 1153 NUM eurjchem-221 47 42 , , PUNCT eurjchem-221 47 43     SPACE eurjchem-221 47 44 1131 1131 NUM eurjchem-221 47 45 , , PUNCT eurjchem-221 47 46     SPACE eurjchem-221 47 47 1036 1036 NUM eurjchem-221 47 48 , , PUNCT eurjchem-221 47 49     SPACE eurjchem-221 47 50 977 977 NUM eurjchem-221 47 51 , , PUNCT eurjchem-221 47 52     SPACE eurjchem-221 47 53 924,750 924,750 NUM eurjchem-221 47 54 . . PUNCT eurjchem-221 47 55     SPACE eurjchem-221 48 1 anal anal ADJ eurjchem-221 48 2 . . PUNCT eurjchem-221 48 3     SPACE eurjchem-221 48 4 calcd calcd NOUN eurjchem-221 48 5 . . PUNCT eurjchem-221 48 6     SPACE eurjchem-221 48 7 for for ADP eurjchem-221 48 8     SPACE eurjchem-221 48 9 c20h14cun2o2 c20h14cun2o2 ADV eurjchem-221 48 10 : : PUNCT eurjchem-221 48 11     SPACE eurjchem-221 48 12 c c X eurjchem-221 48 13 , , PUNCT eurjchem-221 48 14     SPACE eurjchem-221 48 15 63.57 63.57 NUM eurjchem-221 48 16 ; ; PUNCT eurjchem-221 48 17     SPACE eurjchem-221 48 18 h h NOUN eurjchem-221 48 19 , , PUNCT eurjchem-221 48 20     SPACE eurjchem-221 48 21 3.73 3.73 NUM eurjchem-221 48 22 ; ; PUNCT eurjchem-221 48 23     SPACE eurjchem-221 48 24 n n CCONJ eurjchem-221 48 25 , , PUNCT eurjchem-221 48 26     SPACE eurjchem-221 48 27 7.41 7.41 NUM eurjchem-221 48 28 . . PUNCT eurjchem-221 48 29     SPACE eurjchem-221 48 30 found find VERB eurjchem-221 48 31     SPACE eurjchem-221 48 32 c c NOUN eurjchem-221 48 33 , , PUNCT eurjchem-221 48 34     SPACE eurjchem-221 48 35 63.66 63.66 NUM eurjchem-221 48 36 ; ; PUNCT eurjchem-221 48 37     SPACE eurjchem-221 48 38 h h NOUN eurjchem-221 48 39 , , PUNCT eurjchem-221 48 40     SPACE eurjchem-221 48 41 3.70 3.70 NUM eurjchem-221 48 42 ; ; PUNCT eurjchem-221 48 43     SPACE eurjchem-221 48 44 n n CCONJ eurjchem-221 48 45 , , PUNCT eurjchem-221 48 46     SPACE eurjchem-221 48 47 7.49 7.49 NUM eurjchem-221 48 48 . . PUNCT eurjchem-221 48 49         SPACE eurjchem-221 48 50 2.4.5 2.4.5 NUM eurjchem-221 48 51 . . PUNCT eurjchem-221 48 52     SPACE eurjchem-221 48 53 preparation preparation NOUN eurjchem-221 48 54     SPACE eurjchem-221 48 55 of of ADP eurjchem-221 48 56     SPACE eurjchem-221 48 57 complex complex NOUN eurjchem-221 48 58     SPACE eurjchem-221 48 59 5 5 NUM eurjchem-221 48 60         SPACE eurjchem-221 48 61 this this PRON eurjchem-221 48 62     SPACE eurjchem-221 48 63 was be AUX eurjchem-221 48 64     SPACE eurjchem-221 48 65 synthesized synthesize VERB eurjchem-221 48 66     SPACE eurjchem-221 48 67 as as SCONJ eurjchem-221 48 68     SPACE eurjchem-221 48 69 described describe VERB eurjchem-221 48 70     SPACE eurjchem-221 48 71 for for ADP eurjchem-221 48 72     SPACE eurjchem-221 48 73 complex complex NOUN eurjchem-221 48 74     SPACE eurjchem-221 48 75 4 4 NUM eurjchem-221 48 76     SPACE eurjchem-221 48 77 using use VERB eurjchem-221 48 78     SPACE eurjchem-221 48 79 bis(2’‐hydoxy‐3’,5’‐di‐t‐butyl‐benzylidine)]‐1,2‐diamino bis(2’‐hydoxy‐3’,5’‐di‐t‐butyl‐benzylidine)]‐1,2‐diamino PROPN eurjchem-221 48 80     SPACE eurjchem-221 48 81 benzene benzene NOUN eurjchem-221 48 82 . . PUNCT eurjchem-221 48 83     SPACE eurjchem-221 48 84 yield yield NOUN eurjchem-221 48 85 : : PUNCT eurjchem-221 48 86     SPACE eurjchem-221 48 87 73 73 NUM eurjchem-221 48 88 % % NOUN eurjchem-221 48 89 . . PUNCT eurjchem-221 48 90     SPACE eurjchem-221 49 1 solubility solubility NOUN eurjchem-221 49 2 : : PUNCT eurjchem-221 49 3     SPACE eurjchem-221 49 4 chcl3 chcl3 PROPN eurjchem-221 49 5 , , PUNCT eurjchem-221 49 6     SPACE eurjchem-221 49 7 ch2cl2 ch2cl2 ADJ eurjchem-221 49 8 , , PUNCT eurjchem-221 49 9     SPACE eurjchem-221 49 10 etoh etoh NOUN eurjchem-221 49 11 , , PUNCT eurjchem-221 49 12     SPACE eurjchem-221 49 13 meoh meoh NOUN eurjchem-221 49 14 , , PUNCT eurjchem-221 49 15     SPACE eurjchem-221 49 16 chlorobenzene chlorobenzene NOUN eurjchem-221 49 17 , , PUNCT eurjchem-221 49 18     SPACE eurjchem-221 49 19 toluene toluene NOUN eurjchem-221 49 20 . . PUNCT eurjchem-221 49 21     SPACE eurjchem-221 50 1 m.p m.p PROPN eurjchem-221 50 2 . . PROPN eurjchem-221 50 3 : : PUNCT eurjchem-221 50 4     SPACE eurjchem-221 50 5 272‐280 272‐280 NOUN eurjchem-221 50 6     SPACE eurjchem-221 50 7 οc οc PRON eurjchem-221 50 8     SPACE eurjchem-221 50 9 ( ( PUNCT eurjchem-221 50 10 dec dec PROPN eurjchem-221 50 11 ) ) PUNCT eurjchem-221 50 12 . . PUNCT eurjchem-221 50 13     SPACE eurjchem-221 51 1 esi esi PROPN eurjchem-221 51 2     SPACE eurjchem-221 51 3 mass mass NOUN eurjchem-221 51 4     SPACE eurjchem-221 51 5 m+ m+ NUM eurjchem-221 51 6 : : PUNCT eurjchem-221 51 7     SPACE eurjchem-221 51 8 602 602 NUM eurjchem-221 51 9 . . PUNCT eurjchem-221 51 10     SPACE eurjchem-221 52 1 ir ir VERB eurjchem-221 52 2     SPACE eurjchem-221 52 3 ( ( PUNCT eurjchem-221 52 4 kbr kbr PROPN eurjchem-221 52 5 , , PUNCT eurjchem-221 52 6     SPACE eurjchem-221 52 7 cm‐1 cm‐1 NOUN eurjchem-221 52 8 ): ): PUNCT eurjchem-221 52 9     SPACE eurjchem-221 52 10 2954 2954 NUM eurjchem-221 52 11 , , PUNCT eurjchem-221 52 12     SPACE eurjchem-221 52 13 1699 1699 NUM eurjchem-221 52 14 , , PUNCT eurjchem-221 52 15     SPACE eurjchem-221 52 16 1649 1649 NUM eurjchem-221 52 17 , , PUNCT eurjchem-221 52 18     SPACE eurjchem-221 52 19 1604 1604 NUM eurjchem-221 52 20 , , PUNCT eurjchem-221 52 21     SPACE eurjchem-221 52 22 1577 1577 NUM eurjchem-221 52 23 , , PUNCT eurjchem-221 52 24     SPACE eurjchem-221 52 25 1522 1522 NUM eurjchem-221 52 26 , , PUNCT eurjchem-221 52 27     SPACE eurjchem-221 52 28 1461 1461 NUM eurjchem-221 52 29 , , PUNCT eurjchem-221 52 30     SPACE eurjchem-221 52 31 1430 1430 NUM eurjchem-221 52 32 , , PUNCT eurjchem-221 52 33     SPACE eurjchem-221 52 34 1362 1362 NUM eurjchem-221 52 35 , , PUNCT eurjchem-221 52 36     SPACE eurjchem-221 52 37 1256 1256 NUM eurjchem-221 52 38 , , PUNCT eurjchem-221 52 39     SPACE eurjchem-221 52 40 1198 1198 NUM eurjchem-221 52 41 , , PUNCT eurjchem-221 52 42     SPACE eurjchem-221 52 43 744 744 NUM eurjchem-221 52 44 . . PUNCT eurjchem-221 52 45     SPACE eurjchem-221 52 46 anal anal ADJ eurjchem-221 52 47 . . PUNCT eurjchem-221 52 48     SPACE eurjchem-221 52 49 calcd calcd NOUN eurjchem-221 52 50 . . PUNCT eurjchem-221 52 51     SPACE eurjchem-221 52 52 for for ADP eurjchem-221 52 53     SPACE eurjchem-221 52 54 c36h46cun2o2 c36h46cun2o2 NOUN eurjchem-221 52 55 : : PUNCT eurjchem-221 52 56     SPACE eurjchem-221 52 57 c c X eurjchem-221 52 58 , , PUNCT eurjchem-221 52 59     SPACE eurjchem-221 52 60 71.79 71.79 NUM eurjchem-221 52 61 ; ; PUNCT eurjchem-221 52 62     SPACE eurjchem-221 52 63 h h NOUN eurjchem-221 52 64 , , PUNCT eurjchem-221 52 65     SPACE eurjchem-221 52 66 7.70 7.70 NUM eurjchem-221 52 67 ; ; PUNCT eurjchem-221 52 68     SPACE eurjchem-221 52 69 n n CCONJ eurjchem-221 52 70 , , PUNCT eurjchem-221 52 71     SPACE eurjchem-221 52 72 4.65 4.65 NUM eurjchem-221 52 73 . . PUNCT eurjchem-221 52 74     SPACE eurjchem-221 52 75 found find VERB eurjchem-221 52 76     SPACE eurjchem-221 52 77 c c NOUN eurjchem-221 52 78 , , PUNCT eurjchem-221 52 79     SPACE eurjchem-221 52 80 71.84 71.84 NUM eurjchem-221 52 81 ; ; PUNCT eurjchem-221 52 82     SPACE eurjchem-221 52 83 h h NOUN eurjchem-221 52 84 , , PUNCT eurjchem-221 52 85     SPACE eurjchem-221 52 86 7.77 7.77 NUM eurjchem-221 52 87 ; ; PUNCT eurjchem-221 52 88     SPACE eurjchem-221 52 89 n n CCONJ eurjchem-221 52 90 , , PUNCT eurjchem-221 52 91     SPACE eurjchem-221 52 92 4.63 4.63 NUM eurjchem-221 52 93 . . PUNCT eurjchem-221 52 94         SPACE eurjchem-221 53 1 2.4.6 2.4.6 NUM eurjchem-221 53 2 . . PUNCT eurjchem-221 53 3     SPACE eurjchem-221 53 4 preparation preparation NOUN eurjchem-221 53 5     SPACE eurjchem-221 53 6 of of ADP eurjchem-221 53 7     SPACE eurjchem-221 53 8 complex complex NOUN eurjchem-221 53 9     SPACE eurjchem-221 53 10 6 6 NUM eurjchem-221 53 11         SPACE eurjchem-221 53 12 this this PRON eurjchem-221 53 13     SPACE eurjchem-221 53 14 was be AUX eurjchem-221 53 15     SPACE eurjchem-221 53 16 synthesized synthesize VERB eurjchem-221 53 17     SPACE eurjchem-221 53 18 as as SCONJ eurjchem-221 53 19     SPACE eurjchem-221 53 20 described describe VERB eurjchem-221 53 21     SPACE eurjchem-221 53 22 for for ADP eurjchem-221 53 23     SPACE eurjchem-221 53 24 complex complex NOUN eurjchem-221 53 25     SPACE eurjchem-221 53 26 4 4 NUM eurjchem-221 53 27     SPACE eurjchem-221 53 28 using use VERB eurjchem-221 53 29     SPACE eurjchem-221 53 30 bis(2’‐hydoxy‐naphthylidine)]‐1,2‐diaminobenzene bis(2’‐hydoxy‐naphthylidine)]‐1,2‐diaminobenzene NOUN eurjchem-221 53 31 . . PUNCT eurjchem-221 53 32     SPACE eurjchem-221 53 33 yield yield NOUN eurjchem-221 53 34 : : PUNCT eurjchem-221 53 35     SPACE eurjchem-221 53 36 68 68 NUM eurjchem-221 53 37     SPACE eurjchem-221 53 38 % % NOUN eurjchem-221 53 39 . . PUNCT eurjchem-221 53 40     SPACE eurjchem-221 53 41 solubility solubility NOUN eurjchem-221 53 42 : : PUNCT eurjchem-221 53 43     SPACE eurjchem-221 53 44 sparingly sparingly ADV eurjchem-221 53 45     SPACE eurjchem-221 53 46 soluble soluble ADJ eurjchem-221 53 47     SPACE eurjchem-221 53 48 in in ADP eurjchem-221 53 49     SPACE eurjchem-221 53 50 ch2cl2 ch2cl2 NOUN eurjchem-221 53 51 , , PUNCT eurjchem-221 53 52     SPACE eurjchem-221 53 53 chcl3 chcl3 PROPN eurjchem-221 53 54 , , PUNCT eurjchem-221 53 55     SPACE eurjchem-221 53 56 dmso dmso NOUN eurjchem-221 53 57 , , PUNCT eurjchem-221 53 58     SPACE eurjchem-221 53 59 dmf dmf PROPN eurjchem-221 53 60 , , PUNCT eurjchem-221 53 61     SPACE eurjchem-221 53 62 and and CCONJ eurjchem-221 53 63     SPACE eurjchem-221 53 64 very very ADV eurjchem-221 53 65     SPACE eurjchem-221 53 66 less less ADJ eurjchem-221 53 67     SPACE eurjchem-221 53 68 soluble soluble ADJ eurjchem-221 53 69     SPACE eurjchem-221 53 70 in in ADP eurjchem-221 53 71     SPACE eurjchem-221 53 72 etoac etoac ADJ eurjchem-221 53 73 , , PUNCT eurjchem-221 53 74     SPACE eurjchem-221 53 75 accn accn PROPN eurjchem-221 53 76 . . PUNCT eurjchem-221 53 77     SPACE eurjchem-221 54 1 m.p m.p PROPN eurjchem-221 54 2 . . PROPN eurjchem-221 54 3 : : PUNCT eurjchem-221 54 4     SPACE eurjchem-221 54 5 not not PART eurjchem-221 54 6     SPACE eurjchem-221 54 7 melted melt VERB eurjchem-221 54 8     SPACE eurjchem-221 54 9 > > SYM eurjchem-221 54 10     SPACE eurjchem-221 54 11 320 320 NUM eurjchem-221 54 12     SPACE eurjchem-221 54 13 οc οc PROPN eurjchem-221 54 14 . . PUNCT eurjchem-221 54 15     SPACE eurjchem-221 54 16 esi esi PROPN eurjchem-221 54 17     SPACE eurjchem-221 54 18 mass mass PROPN eurjchem-221 54 19     SPACE eurjchem-221 54 20 m+ m+ NUM eurjchem-221 54 21 : : PUNCT eurjchem-221 54 22     SPACE eurjchem-221 54 23 478 478 NUM eurjchem-221 54 24 . . PUNCT eurjchem-221 54 25     SPACE eurjchem-221 55 1 ir ir VERB eurjchem-221 55 2     SPACE eurjchem-221 55 3 ( ( PUNCT eurjchem-221 55 4 kbr kbr PROPN eurjchem-221 55 5 , , PUNCT eurjchem-221 55 6     SPACE eurjchem-221 55 7 cm‐1 cm‐1 NOUN eurjchem-221 55 8 ): ): PUNCT eurjchem-221 55 9     SPACE eurjchem-221 55 10 1607 1607 NUM eurjchem-221 55 11 , , PUNCT eurjchem-221 55 12     SPACE eurjchem-221 55 13 1574 1574 NUM eurjchem-221 55 14 , , PUNCT eurjchem-221 55 15     SPACE eurjchem-221 55 16 1533 1533 NUM eurjchem-221 55 17 , , PUNCT eurjchem-221 55 18     SPACE eurjchem-221 55 19 1457 1457 NUM eurjchem-221 55 20 , , PUNCT eurjchem-221 55 21     SPACE eurjchem-221 55 22 1398 1398 NUM eurjchem-221 55 23 , , PUNCT eurjchem-221 55 24     SPACE eurjchem-221 55 25 1364 1364 NUM eurjchem-221 55 26 , , PUNCT eurjchem-221 55 27     SPACE eurjchem-221 55 28 1282 1282 NUM eurjchem-221 55 29 , , PUNCT eurjchem-221 55 30     SPACE eurjchem-221 55 31 1190 1190 NUM eurjchem-221 55 32 , , PUNCT eurjchem-221 55 33     SPACE eurjchem-221 55 34 1095 1095 NUM eurjchem-221 55 35 , , PUNCT eurjchem-221 55 36     SPACE eurjchem-221 55 37 828 828 NUM eurjchem-221 55 38 , , PUNCT eurjchem-221 55 39     SPACE eurjchem-221 55 40 737 737 NUM eurjchem-221 55 41 . . PUNCT eurjchem-221 55 42     SPACE eurjchem-221 55 43 anal anal ADJ eurjchem-221 55 44 . . PUNCT eurjchem-221 55 45     SPACE eurjchem-221 55 46 calcd calcd NOUN eurjchem-221 55 47 . . PUNCT eurjchem-221 55 48     SPACE eurjchem-221 55 49 for for ADP eurjchem-221 55 50     SPACE eurjchem-221 55 51 c28h18cun2o2 c28h18cun2o2 NOUN eurjchem-221 55 52 : : PUNCT eurjchem-221 55 53     SPACE eurjchem-221 55 54 c c X eurjchem-221 55 55 , , PUNCT eurjchem-221 55 56     SPACE eurjchem-221 55 57 70.36 70.36 NUM eurjchem-221 55 58 ; ; PUNCT eurjchem-221 55 59     SPACE eurjchem-221 55 60 h h NOUN eurjchem-221 55 61 , , PUNCT eurjchem-221 55 62     SPACE eurjchem-221 55 63 3.80 3.80 NUM eurjchem-221 55 64 ; ; PUNCT eurjchem-221 55 65     SPACE eurjchem-221 55 66 n n CCONJ eurjchem-221 55 67 , , PUNCT eurjchem-221 55 68     SPACE eurjchem-221 55 69 5.86 5.86 NUM eurjchem-221 55 70 . . PUNCT eurjchem-221 55 71     SPACE eurjchem-221 55 72 found find VERB eurjchem-221 55 73     SPACE eurjchem-221 55 74 c c NOUN eurjchem-221 55 75 , , PUNCT eurjchem-221 55 76     SPACE eurjchem-221 55 77 70.34 70.34 NUM eurjchem-221 55 78 ; ; PUNCT eurjchem-221 55 79     SPACE eurjchem-221 55 80 h h NOUN eurjchem-221 55 81 , , PUNCT eurjchem-221 55 82     SPACE eurjchem-221 55 83 3.77 3.77 NUM eurjchem-221 55 84 ; ; PUNCT eurjchem-221 55 85     SPACE eurjchem-221 55 86 n n CCONJ eurjchem-221 55 87 , , PUNCT eurjchem-221 55 88     SPACE eurjchem-221 55 89 5.81 5.81 NUM eurjchem-221 55 90 . . PUNCT eurjchem-221 55 91         SPACE eurjchem-221 55 92 2.5 2.5 NUM eurjchem-221 55 93 . . PUNCT eurjchem-221 55 94     SPACE eurjchem-221 55 95 experimental experimental ADJ eurjchem-221 55 96     SPACE eurjchem-221 55 97 procedure procedure NOUN eurjchem-221 55 98     SPACE eurjchem-221 55 99 for for ADP eurjchem-221 55 100     SPACE eurjchem-221 55 101 oxidative oxidative ADJ eurjchem-221 55 102     SPACE eurjchem-221 55 103 coupling coupling NOUN eurjchem-221 55 104     SPACE eurjchem-221 55 105 of of ADP eurjchem-221 55 106                             SPACE eurjchem-221 55 107 2­naphthol 2­naphthol NUM eurjchem-221 55 108     SPACE eurjchem-221 55 109 to to PART eurjchem-221 55 110     SPACE eurjchem-221 55 111 binol binol VERB eurjchem-221 55 112         SPACE eurjchem-221 55 113 to to ADP eurjchem-221 55 114     SPACE eurjchem-221 55 115 a a DET eurjchem-221 55 116     SPACE eurjchem-221 55 117 stirred stir VERB eurjchem-221 55 118     SPACE eurjchem-221 55 119 solution solution NOUN eurjchem-221 55 120     SPACE eurjchem-221 55 121 of of ADP eurjchem-221 55 122     SPACE eurjchem-221 55 123 2‐naphthol 2‐naphthol NOUN eurjchem-221 55 124     SPACE eurjchem-221 55 125 ( ( PUNCT eurjchem-221 55 126 0.432 0.432 NOUN eurjchem-221 55 127     SPACE eurjchem-221 55 128 g g NOUN eurjchem-221 55 129 , , PUNCT eurjchem-221 55 130     SPACE eurjchem-221 55 131 3 3 NUM eurjchem-221 55 132     SPACE eurjchem-221 55 133 mmol mmol NOUN eurjchem-221 55 134 ) ) PUNCT eurjchem-221 55 135     SPACE eurjchem-221 55 136 in in ADP eurjchem-221 55 137     SPACE eurjchem-221 55 138 chlorobenzene chlorobenzene NOUN eurjchem-221 55 139     SPACE eurjchem-221 55 140 ( ( PUNCT eurjchem-221 55 141 15 15 NUM eurjchem-221 55 142     SPACE eurjchem-221 55 143 ml ml NOUN eurjchem-221 55 144 ) ) PUNCT eurjchem-221 55 145     SPACE eurjchem-221 55 146 was be AUX eurjchem-221 55 147     SPACE eurjchem-221 55 148 added add VERB eurjchem-221 55 149     SPACE eurjchem-221 55 150 chiral chiral ADJ eurjchem-221 55 151     SPACE eurjchem-221 55 152 copper copper NOUN eurjchem-221 55 153     SPACE eurjchem-221 55 154 ( ( PUNCT eurjchem-221 55 155 ii ii NOUN eurjchem-221 55 156 ) ) PUNCT eurjchem-221 55 157     SPACE eurjchem-221 55 158 schiff‐base schiff‐base NOUN eurjchem-221 55 159     SPACE eurjchem-221 55 160 complex complex NOUN eurjchem-221 55 161     SPACE eurjchem-221 55 162 2 2 NUM eurjchem-221 55 163     SPACE eurjchem-221 55 164 ( ( PUNCT eurjchem-221 55 165 0.036 0.036 NUM eurjchem-221 55 166 g g NOUN eurjchem-221 55 167 , , PUNCT eurjchem-221 55 168     SPACE eurjchem-221 55 169 0.06 0.06 NUM eurjchem-221 55 170     SPACE eurjchem-221 55 171 mmol mmol NOUN eurjchem-221 55 172 , , PUNCT eurjchem-221 55 173     SPACE eurjchem-221 55 174 2 2 NUM eurjchem-221 55 175     SPACE eurjchem-221 55 176 mol mol NOUN eurjchem-221 55 177     SPACE eurjchem-221 55 178 % % NOUN eurjchem-221 55 179 ) ) PUNCT eurjchem-221 55 180     SPACE eurjchem-221 55 181 and and CCONJ eurjchem-221 55 182     SPACE eurjchem-221 55 183 the the DET eurjchem-221 55 184     SPACE eurjchem-221 55 185 reaction reaction NOUN eurjchem-221 55 186     SPACE eurjchem-221 55 187 mixture mixture NOUN eurjchem-221 55 188     SPACE eurjchem-221 55 189 was be AUX eurjchem-221 55 190     SPACE eurjchem-221 55 191 refluxed refluxe VERB eurjchem-221 55 192     SPACE eurjchem-221 55 193 for for ADP eurjchem-221 55 194     SPACE eurjchem-221 55 195 48 48 NUM eurjchem-221 55 196     SPACE eurjchem-221 55 197 h h NOUN eurjchem-221 55 198     SPACE eurjchem-221 55 199 under under ADP eurjchem-221 55 200     SPACE eurjchem-221 55 201 aerobic aerobic ADJ eurjchem-221 55 202     SPACE eurjchem-221 55 203 atmosphere atmosphere NOUN eurjchem-221 55 204 . . PUNCT eurjchem-221 55 205     SPACE eurjchem-221 55 206 reaction reaction NOUN eurjchem-221 55 207     SPACE eurjchem-221 55 208 mixture mixture NOUN eurjchem-221 55 209     SPACE eurjchem-221 55 210 was be AUX eurjchem-221 55 211     SPACE eurjchem-221 55 212 stirred stir VERB eurjchem-221 55 213     SPACE eurjchem-221 55 214 by by ADP eurjchem-221 55 215     SPACE eurjchem-221 55 216 magnetic magnetic ADJ eurjchem-221 55 217     SPACE eurjchem-221 55 218 stirrer stirrer NOUN eurjchem-221 55 219     SPACE eurjchem-221 55 220 at at ADP eurjchem-221 55 221     SPACE eurjchem-221 55 222 600 600 NUM eurjchem-221 55 223     SPACE eurjchem-221 55 224 rpm rpm NOUN eurjchem-221 55 225 . . PUNCT eurjchem-221 55 226     SPACE eurjchem-221 55 227 after after ADP eurjchem-221 55 228     SPACE eurjchem-221 55 229 completion completion NOUN eurjchem-221 55 230     SPACE eurjchem-221 55 231 of of ADP eurjchem-221 55 232     SPACE eurjchem-221 55 233 the the DET eurjchem-221 55 234     SPACE eurjchem-221 55 235 reaction reaction NOUN eurjchem-221 55 236 , , PUNCT eurjchem-221 55 237     SPACE eurjchem-221 55 238 solvent solvent NOUN eurjchem-221 55 239     SPACE eurjchem-221 55 240 was be AUX eurjchem-221 55 241     SPACE eurjchem-221 55 242 evaporated evaporate VERB eurjchem-221 55 243     SPACE eurjchem-221 55 244 under under ADP eurjchem-221 55 245     SPACE eurjchem-221 55 246 reduced reduce VERB eurjchem-221 55 247     SPACE eurjchem-221 55 248 pressure pressure NOUN eurjchem-221 55 249 . . PUNCT eurjchem-221 55 250     SPACE eurjchem-221 56 1 the the DET eurjchem-221 56 2     SPACE eurjchem-221 56 3 residue residue NOUN eurjchem-221 56 4     SPACE eurjchem-221 56 5 thus thus ADV eurjchem-221 56 6     SPACE eurjchem-221 56 7 obtained obtain VERB eurjchem-221 56 8     SPACE eurjchem-221 56 9 was be AUX eurjchem-221 56 10     SPACE eurjchem-221 56 11 purified purify VERB eurjchem-221 56 12     SPACE eurjchem-221 56 13 by by ADP eurjchem-221 56 14     SPACE eurjchem-221 56 15 column column NOUN eurjchem-221 56 16     SPACE eurjchem-221 56 17 chromatography chromatography NOUN eurjchem-221 56 18     SPACE eurjchem-221 56 19 on on ADP eurjchem-221 56 20     SPACE eurjchem-221 56 21 silicagel silicagel NOUN eurjchem-221 56 22     SPACE eurjchem-221 56 23 ( ( PUNCT eurjchem-221 56 24 100‐200 100‐200 NOUN eurjchem-221 56 25     SPACE eurjchem-221 56 26 mesh mesh NOUN eurjchem-221 56 27 ) ) PUNCT eurjchem-221 56 28     SPACE eurjchem-221 56 29 using use VERB eurjchem-221 56 30     SPACE eurjchem-221 56 31 ethylacetate ethylacetate ADJ eurjchem-221 56 32 / / SYM eurjchem-221 56 33 hexane hexane NOUN eurjchem-221 56 34     SPACE eurjchem-221 56 35 ( ( PUNCT eurjchem-221 56 36 1:4 1:4 NUM eurjchem-221 56 37 ) ) PUNCT eurjchem-221 56 38     SPACE eurjchem-221 56 39 as as ADP eurjchem-221 56 40     SPACE eurjchem-221 56 41 eluent eluent NOUN eurjchem-221 56 42 . . PUNCT eurjchem-221 56 43     SPACE eurjchem-221 57 1 evaporation evaporation NOUN eurjchem-221 57 2     SPACE eurjchem-221 57 3 of of ADP eurjchem-221 57 4     SPACE eurjchem-221 57 5 solvent solvent NOUN eurjchem-221 57 6     SPACE eurjchem-221 57 7 yielded yield VERB eurjchem-221 57 8     SPACE eurjchem-221 57 9 1,1'‐binaphthyl‐2,2'‐diol 1,1'‐binaphthyl‐2,2'‐diol NUM eurjchem-221 57 10 ( ( PUNCT eurjchem-221 57 11 0.322 0.322 NUM eurjchem-221 57 12     SPACE eurjchem-221 57 13 g g NOUN eurjchem-221 57 14 ) ) PUNCT eurjchem-221 57 15 . . PUNCT eurjchem-221 57 16     SPACE eurjchem-221 58 1 oxidative oxidative ADJ eurjchem-221 58 2     SPACE eurjchem-221 58 3 coupling coupling NOUN eurjchem-221 58 4     SPACE eurjchem-221 58 5 with with ADP eurjchem-221 58 6     SPACE eurjchem-221 58 7 ( ( PUNCT eurjchem-221 58 8 b b NOUN eurjchem-221 58 9 ) ) PUNCT eurjchem-221 58 10     SPACE eurjchem-221 58 11 and and CCONJ eurjchem-221 58 12     SPACE eurjchem-221 58 13 cross cross ADJ eurjchem-221 58 14     SPACE eurjchem-221 58 15 coupling couple VERB eurjchem-221 58 16     SPACE eurjchem-221 58 17 reactions reaction NOUN eurjchem-221 58 18     SPACE eurjchem-221 58 19 were be AUX eurjchem-221 58 20     SPACE eurjchem-221 58 21 performed perform VERB eurjchem-221 58 22     SPACE eurjchem-221 58 23 under under ADP eurjchem-221 58 24     SPACE eurjchem-221 58 25 similar similar ADJ eurjchem-221 58 26     SPACE eurjchem-221 58 27 condition condition NOUN eurjchem-221 58 28 . . PUNCT eurjchem-221 58 29         SPACE eurjchem-221 59 1 2.6 2.6 NUM eurjchem-221 59 2 . . PUNCT eurjchem-221 59 3     SPACE eurjchem-221 59 4 experimental experimental ADJ eurjchem-221 59 5     SPACE eurjchem-221 59 6 procedure procedure NOUN eurjchem-221 59 7     SPACE eurjchem-221 59 8 for for ADP eurjchem-221 59 9     SPACE eurjchem-221 59 10 epr epr PROPN eurjchem-221 59 11     SPACE eurjchem-221 59 12 monitoring monitoring NOUN eurjchem-221 59 13     SPACE eurjchem-221 59 14 of of ADP eurjchem-221 59 15     SPACE eurjchem-221 59 16 the the DET eurjchem-221 59 17     SPACE eurjchem-221 59 18 aerobic aerobic ADJ eurjchem-221 59 19     SPACE eurjchem-221 59 20 oxidative oxidative ADJ eurjchem-221 59 21     SPACE eurjchem-221 59 22 coupling coupling NOUN eurjchem-221 59 23     SPACE eurjchem-221 59 24 reaction reaction NOUN eurjchem-221 59 25         SPACE eurjchem-221 59 26 the the DET eurjchem-221 59 27     SPACE eurjchem-221 59 28 reaction reaction NOUN eurjchem-221 59 29     SPACE eurjchem-221 59 30 was be AUX eurjchem-221 59 31     SPACE eurjchem-221 59 32 conducted conduct VERB eurjchem-221 59 33     SPACE eurjchem-221 59 34 as as SCONJ eurjchem-221 59 35     SPACE eurjchem-221 59 36 mentioned mention VERB eurjchem-221 59 37     SPACE eurjchem-221 59 38 above above ADV eurjchem-221 59 39 . . PUNCT eurjchem-221 59 40     SPACE eurjchem-221 59 41 a a DET eurjchem-221 59 42     SPACE eurjchem-221 59 43 small small ADJ eurjchem-221 59 44     SPACE eurjchem-221 59 45 portion portion NOUN eurjchem-221 59 46     SPACE eurjchem-221 59 47 of of ADP eurjchem-221 59 48     SPACE eurjchem-221 59 49 reaction reaction NOUN eurjchem-221 59 50     SPACE eurjchem-221 59 51 mixture mixture NOUN eurjchem-221 59 52     SPACE eurjchem-221 59 53 was be AUX eurjchem-221 59 54     SPACE eurjchem-221 59 55 collected collect VERB eurjchem-221 59 56     SPACE eurjchem-221 59 57 from from ADP eurjchem-221 59 58     SPACE eurjchem-221 59 59 the the DET eurjchem-221 59 60     SPACE eurjchem-221 59 61 reaction reaction NOUN eurjchem-221 59 62     SPACE eurjchem-221 59 63 mixture mixture NOUN eurjchem-221 59 64     SPACE eurjchem-221 59 65 and and CCONJ eurjchem-221 59 66     SPACE eurjchem-221 59 67 transferred transfer VERB eurjchem-221 59 68     SPACE eurjchem-221 59 69 to to ADP eurjchem-221 59 70     SPACE eurjchem-221 59 71 aqueous aqueous ADJ eurjchem-221 59 72     SPACE eurjchem-221 59 73 cell cell NOUN eurjchem-221 59 74     SPACE eurjchem-221 59 75 and and CCONJ eurjchem-221 59 76     SPACE eurjchem-221 59 77 epr epr PROPN eurjchem-221 59 78     SPACE eurjchem-221 59 79 spectrum spectrum NOUN eurjchem-221 59 80     SPACE eurjchem-221 59 81 was be AUX eurjchem-221 59 82     SPACE eurjchem-221 59 83 recorded record VERB eurjchem-221 59 84 . . PUNCT eurjchem-221 59 85     SPACE eurjchem-221 60 1 after after ADP eurjchem-221 60 2     SPACE eurjchem-221 60 3 the the DET eurjchem-221 60 4     SPACE eurjchem-221 60 5 measurement measurement NOUN eurjchem-221 60 6     SPACE eurjchem-221 60 7 this this DET eurjchem-221 60 8     SPACE eurjchem-221 60 9 solution solution NOUN eurjchem-221 60 10     SPACE eurjchem-221 60 11 was be AUX eurjchem-221 60 12     SPACE eurjchem-221 60 13 transferred transfer VERB eurjchem-221 60 14     SPACE eurjchem-221 60 15 to to ADP eurjchem-221 60 16     SPACE eurjchem-221 60 17 the the DET eurjchem-221 60 18     SPACE eurjchem-221 60 19 reaction reaction NOUN eurjchem-221 60 20     SPACE eurjchem-221 60 21 vessel vessel NOUN eurjchem-221 60 22 . . PUNCT eurjchem-221 60 23     SPACE eurjchem-221 61 1 thus thus ADV eurjchem-221 61 2     SPACE eurjchem-221 61 3 the the DET eurjchem-221 61 4     SPACE eurjchem-221 61 5 reaction reaction NOUN eurjchem-221 61 6     SPACE eurjchem-221 61 7 was be AUX eurjchem-221 61 8     SPACE eurjchem-221 61 9 monitored monitor VERB eurjchem-221 61 10     SPACE eurjchem-221 61 11 for for ADP eurjchem-221 61 12     SPACE eurjchem-221 61 13 two two NUM eurjchem-221 61 14     SPACE eurjchem-221 61 15 days day NOUN eurjchem-221 61 16     SPACE eurjchem-221 61 17 at at ADP eurjchem-221 61 18     SPACE eurjchem-221 61 19 regular regular ADJ eurjchem-221 61 20     SPACE eurjchem-221 61 21 intervals interval NOUN eurjchem-221 61 22 . . PUNCT eurjchem-221 61 23         SPACE eurjchem-221 62 1 2.7 2.7 NUM eurjchem-221 62 2 . . PUNCT eurjchem-221 62 3     SPACE eurjchem-221 62 4 identification identification NOUN eurjchem-221 62 5     SPACE eurjchem-221 62 6 of of ADP eurjchem-221 62 7     SPACE eurjchem-221 62 8 products product NOUN eurjchem-221 62 9             SPACE eurjchem-221 62 10 1,1'‐binaphthyl‐2,2'‐diol 1,1'‐binaphthyl‐2,2'‐diol NUM eurjchem-221 62 11 ( ( PUNCT eurjchem-221 62 12 c c NOUN eurjchem-221 62 13 ): ): PUNCT eurjchem-221 62 14     SPACE eurjchem-221 62 15 m.p m.p PROPN eurjchem-221 62 16 . . PROPN eurjchem-221 62 17 : : PUNCT eurjchem-221 62 18     SPACE eurjchem-221 62 19 212‐214 212‐214 NUM eurjchem-221 62 20     SPACE eurjchem-221 63 1 οc οc PROPN eurjchem-221 63 2 . . PUNCT eurjchem-221 63 3     SPACE eurjchem-221 63 4 1h 1h NUM eurjchem-221 63 5     SPACE eurjchem-221 63 6 nmr nmr NOUN eurjchem-221 63 7     SPACE eurjchem-221 63 8 ( ( PUNCT eurjchem-221 63 9 cdcl3 cdcl3 PROPN eurjchem-221 63 10 , , PUNCT eurjchem-221 63 11     SPACE eurjchem-221 63 12 δ δ PROPN eurjchem-221 63 13 , , PUNCT eurjchem-221 63 14     SPACE eurjchem-221 63 15 ppm ppm ADJ eurjchem-221 63 16 ): ): PUNCT eurjchem-221 63 17     SPACE eurjchem-221 63 18 7.14‐7.16 7.14‐7.16 NUM eurjchem-221 63 19     SPACE eurjchem-221 63 20 ( ( PUNCT eurjchem-221 63 21 m m PROPN eurjchem-221 63 22 , , PUNCT eurjchem-221 63 23     SPACE eurjchem-221 63 24 2h 2h NUM eurjchem-221 63 25 ) ) PUNCT eurjchem-221 63 26 , , PUNCT eurjchem-221 63 27     SPACE eurjchem-221 63 28 7.26‐7.32 7.26‐7.32 NUM eurjchem-221 63 29     SPACE eurjchem-221 63 30 ( ( PUNCT eurjchem-221 63 31 m m PROPN eurjchem-221 63 32 , , PUNCT eurjchem-221 63 33     SPACE eurjchem-221 63 34 2h 2h NUM eurjchem-221 63 35 ) ) PUNCT eurjchem-221 63 36 , , PUNCT eurjchem-221 63 37     SPACE eurjchem-221 63 38 7.35‐7.39 7.35‐7.39 NOUN eurjchem-221 63 39     SPACE eurjchem-221 63 40 ( ( PUNCT eurjchem-221 63 41 m m PROPN eurjchem-221 63 42 , , PUNCT eurjchem-221 63 43     SPACE eurjchem-221 63 44 4h 4h NOUN eurjchem-221 63 45 ) ) PUNCT eurjchem-221 63 46 , , PUNCT eurjchem-221 63 47     SPACE eurjchem-221 63 48 7.88‐7.90 7.88‐7.90 NUM eurjchem-221 63 49     SPACE eurjchem-221 63 50 ( ( PUNCT eurjchem-221 63 51 m m PROPN eurjchem-221 63 52 , , PUNCT eurjchem-221 63 53     SPACE eurjchem-221 63 54 2h 2h NUM eurjchem-221 63 55 ) ) PUNCT eurjchem-221 63 56 , , PUNCT eurjchem-221 63 57     SPACE eurjchem-221 63 58 7.95‐7.98 7.95‐7.98 NUM eurjchem-221 63 59     SPACE eurjchem-221 63 60 ( ( PUNCT eurjchem-221 63 61 m m PROPN eurjchem-221 63 62 , , PUNCT eurjchem-221 63 63     SPACE eurjchem-221 63 64 2h 2h NUM eurjchem-221 63 65 ) ) PUNCT eurjchem-221 63 66     SPACE eurjchem-221 64 1 4.00‐4.70 4.00‐4.70 NUM eurjchem-221 64 2     SPACE eurjchem-221 64 3 ( ( PUNCT eurjchem-221 64 4 broad broad ADJ eurjchem-221 64 5     SPACE eurjchem-221 64 6 s s PROPN eurjchem-221 64 7 , , PUNCT eurjchem-221 64 8     SPACE eurjchem-221 64 9 2h 2h NUM eurjchem-221 64 10 ) ) PUNCT eurjchem-221 64 11 . . PUNCT eurjchem-221 64 12     SPACE eurjchem-221 64 13 13c 13c NOUN eurjchem-221 64 14     SPACE eurjchem-221 64 15 nmr nmr NOUN eurjchem-221 64 16     SPACE eurjchem-221 64 17 ( ( PUNCT eurjchem-221 64 18 cdcl3 cdcl3 PROPN eurjchem-221 64 19 , , PUNCT eurjchem-221 64 20     SPACE eurjchem-221 64 21 δ δ PROPN eurjchem-221 64 22 , , PUNCT eurjchem-221 64 23     SPACE eurjchem-221 64 24 ppm ppm ADJ eurjchem-221 64 25 ): ): PUNCT eurjchem-221 64 26     SPACE eurjchem-221 64 27 110.8 110.8 NUM eurjchem-221 64 28 , , PUNCT eurjchem-221 64 29     SPACE eurjchem-221 64 30 117.7 117.7 NUM eurjchem-221 64 31 , , PUNCT eurjchem-221 64 32     SPACE eurjchem-221 64 33 124.0 124.0 NUM eurjchem-221 64 34 , , PUNCT eurjchem-221 64 35     SPACE eurjchem-221 64 36 124.2 124.2 NUM eurjchem-221 64 37 , , PUNCT eurjchem-221 64 38     SPACE eurjchem-221 64 39 127.4 127.4 NUM eurjchem-221 64 40 , , PUNCT eurjchem-221 64 41     SPACE eurjchem-221 64 42 128.3 128.3 NUM eurjchem-221 64 43 , , PUNCT eurjchem-221 64 44     SPACE eurjchem-221 64 45 129.4 129.4 NUM eurjchem-221 64 46 , , PUNCT eurjchem-221 64 47     SPACE eurjchem-221 64 48 131.3 131.3 NUM eurjchem-221 64 49 , , PUNCT eurjchem-221 64 50     SPACE eurjchem-221 64 51 133.4 133.4 NUM eurjchem-221 64 52 , , PUNCT eurjchem-221 64 53     SPACE eurjchem-221 64 54 152.7 152.7 NUM eurjchem-221 64 55 . . PUNCT eurjchem-221 64 56     SPACE eurjchem-221 64 57 ir ir PROPN eurjchem-221 64 58     SPACE eurjchem-221 64 59 ( ( PUNCT eurjchem-221 64 60 kbr kbr PROPN eurjchem-221 64 61 , , PUNCT eurjchem-221 64 62     SPACE eurjchem-221 64 63 cm‐1 cm‐1 NOUN eurjchem-221 64 64 ): ): PUNCT eurjchem-221 64 65     SPACE eurjchem-221 64 66 3486 3486 NUM eurjchem-221 64 67 , , PUNCT eurjchem-221 64 68     SPACE eurjchem-221 64 69 3065 3065 NUM eurjchem-221 64 70 , , PUNCT eurjchem-221 64 71     SPACE eurjchem-221 64 72 2965 2965 NUM eurjchem-221 64 73 , , PUNCT eurjchem-221 64 74     SPACE eurjchem-221 64 75 2890 2890 NUM eurjchem-221 64 76 , , PUNCT eurjchem-221 64 77     SPACE eurjchem-221 64 78 1689 1689 NUM eurjchem-221 64 79 , , PUNCT eurjchem-221 64 80     SPACE eurjchem-221 64 81 1632,1540,1466,1262 1632,1540,1466,1262 NUM eurjchem-221 64 82 . . PUNCT eurjchem-221 64 83     SPACE eurjchem-221 64 84 dimethyl dimethyl NOUN eurjchem-221 64 85     SPACE eurjchem-221 64 86 2,2'‐dihydroxy‐1,1'‐binaphthyl‐3,3'‐dicarboxylate 2,2'‐dihydroxy‐1,1'‐binaphthyl‐3,3'‐dicarboxylate PROPN eurjchem-221 64 87     SPACE eurjchem-221 64 88 ( ( PUNCT eurjchem-221 64 89 d d NOUN eurjchem-221 64 90 ): ): NOUN eurjchem-221 64 91     SPACE eurjchem-221 64 92 m.p m.p PROPN eurjchem-221 64 93 . . PROPN eurjchem-221 64 94 : : PUNCT eurjchem-221 64 95     SPACE eurjchem-221 64 96 270‐272 270‐272 NOUN eurjchem-221 64 97     SPACE eurjchem-221 64 98 οc οc PROPN eurjchem-221 64 99 . . PROPN eurjchem-221 64 100     SPACE eurjchem-221 64 101 1h 1h NUM eurjchem-221 64 102     SPACE eurjchem-221 64 103 nmr nmr NOUN eurjchem-221 64 104     SPACE eurjchem-221 64 105 ( ( PUNCT eurjchem-221 64 106 cdcl3 cdcl3 PROPN eurjchem-221 64 107 , , PUNCT eurjchem-221 64 108     SPACE eurjchem-221 64 109 δ δ PROPN eurjchem-221 64 110 , , PUNCT eurjchem-221 64 111     SPACE eurjchem-221 64 112 ppm ppm ADJ eurjchem-221 64 113 ): ): PUNCT eurjchem-221 64 114     SPACE eurjchem-221 64 115 4.05 4.05 NUM eurjchem-221 64 116     SPACE eurjchem-221 64 117 ( ( PUNCT eurjchem-221 64 118 s s PROPN eurjchem-221 64 119 , , PUNCT eurjchem-221 64 120     SPACE eurjchem-221 64 121 6h 6h NOUN eurjchem-221 64 122 ) ) PUNCT eurjchem-221 64 123 , , PUNCT eurjchem-221 64 124     SPACE eurjchem-221 64 125 7.14‐7.16 7.14‐7.16 NUM eurjchem-221 64 126     SPACE eurjchem-221 64 127 ( ( PUNCT eurjchem-221 64 128 m m PROPN eurjchem-221 64 129 , , PUNCT eurjchem-221 64 130     SPACE eurjchem-221 64 131 2h 2h NUM eurjchem-221 64 132 ) ) PUNCT eurjchem-221 64 133 , , PUNCT eurjchem-221 64 134     SPACE eurjchem-221 64 135 7.32‐7.36 7.32‐7.36 NOUN eurjchem-221 64 136     SPACE eurjchem-221 64 137 ( ( PUNCT eurjchem-221 64 138 m m PROPN eurjchem-221 64 139 , , PUNCT eurjchem-221 64 140     SPACE eurjchem-221 64 141 4h 4h NOUN eurjchem-221 64 142 ) ) PUNCT eurjchem-221 64 143 , , PUNCT eurjchem-221 64 144     SPACE eurjchem-221 64 145 7.90‐7.93 7.90‐7.93 NOUN eurjchem-221 64 146     SPACE eurjchem-221 64 147 ( ( PUNCT eurjchem-221 64 148 m m PROPN eurjchem-221 64 149 , , PUNCT eurjchem-221 64 150     SPACE eurjchem-221 64 151 2h 2h NUM eurjchem-221 64 152 ) ) PUNCT eurjchem-221 64 153 , , PUNCT eurjchem-221 64 154     SPACE eurjchem-221 64 155 8.68 8.68 NUM eurjchem-221 64 156     SPACE eurjchem-221 64 157 ( ( PUNCT eurjchem-221 64 158 m m PROPN eurjchem-221 64 159 , , PUNCT eurjchem-221 64 160     SPACE eurjchem-221 64 161 2h 2h NUM eurjchem-221 64 162 ) ) PUNCT eurjchem-221 64 163 , , PUNCT eurjchem-221 64 164     SPACE eurjchem-221 64 165 10.70 10.70 NUM eurjchem-221 64 166     SPACE eurjchem-221 64 167 ( ( PUNCT eurjchem-221 64 168 m m NOUN eurjchem-221 64 169     SPACE eurjchem-221 64 170 2h 2h NUM eurjchem-221 64 171 ) ) PUNCT eurjchem-221 64 172 . . PUNCT eurjchem-221 64 173     SPACE eurjchem-221 64 174 13c 13c NOUN eurjchem-221 64 175     SPACE eurjchem-221 64 176 nmr nmr NOUN eurjchem-221 64 177     SPACE eurjchem-221 64 178 ( ( PUNCT eurjchem-221 64 179 cdcl3 cdcl3 PROPN eurjchem-221 64 180 , , PUNCT eurjchem-221 64 181     SPACE eurjchem-221 64 182 δ δ PROPN eurjchem-221 64 183 , , PUNCT eurjchem-221 64 184     SPACE eurjchem-221 64 185 ppm ppm NOUN eurjchem-221 64 186 ): ): PUNCT eurjchem-221 64 187     SPACE eurjchem-221 64 188 52.7 52.7 NUM eurjchem-221 64 189 , , PUNCT eurjchem-221 64 190     SPACE eurjchem-221 64 191 114.1 114.1 NUM eurjchem-221 64 192 , , PUNCT eurjchem-221 64 193     SPACE eurjchem-221 64 194 116.9 116.9 NUM eurjchem-221 64 195 , , PUNCT eurjchem-221 64 196     SPACE eurjchem-221 64 197 123.9 123.9 NUM eurjchem-221 64 198 , , PUNCT eurjchem-221 64 199     SPACE eurjchem-221 64 200 124.7 124.7 NUM eurjchem-221 64 201 , , PUNCT eurjchem-221 64 202     SPACE eurjchem-221 64 203 127.2 127.2 NUM eurjchem-221 64 204 , , PUNCT eurjchem-221 64 205     SPACE eurjchem-221 64 206 129.4 129.4 NUM eurjchem-221 64 207 , , PUNCT eurjchem-221 64 208     SPACE eurjchem-221 64 209 129.7 129.7 NUM eurjchem-221 64 210 , , PUNCT eurjchem-221 64 211     SPACE eurjchem-221 64 212 132.8 132.8 NUM eurjchem-221 64 213 , , PUNCT eurjchem-221 64 214     SPACE eurjchem-221 64 215 137.2 137.2 NUM eurjchem-221 64 216 , , PUNCT eurjchem-221 64 217     SPACE eurjchem-221 64 218 154.0 154.0 NUM eurjchem-221 64 219 , , PUNCT eurjchem-221 64 220     SPACE eurjchem-221 64 221 170.5 170.5 NUM eurjchem-221 64 222 . . PUNCT eurjchem-221 64 223     SPACE eurjchem-221 64 224 ir ir PROPN eurjchem-221 64 225     SPACE eurjchem-221 64 226 ( ( PUNCT eurjchem-221 64 227 kbr kbr PROPN eurjchem-221 64 228 , , PUNCT eurjchem-221 64 229     SPACE eurjchem-221 64 230 cm‐1 cm‐1 NOUN eurjchem-221 64 231 ): ): PUNCT eurjchem-221 64 232     SPACE eurjchem-221 64 233 3178 3178 NUM eurjchem-221 64 234 , , PUNCT eurjchem-221 64 235     SPACE eurjchem-221 64 236 2971 2971 NUM eurjchem-221 64 237 , , PUNCT eurjchem-221 64 238     SPACE eurjchem-221 64 239 2915 2915 NUM eurjchem-221 64 240 , , PUNCT eurjchem-221 64 241     SPACE eurjchem-221 64 242 2846 2846 NUM eurjchem-221 64 243 , , PUNCT eurjchem-221 64 244     SPACE eurjchem-221 64 245 1725 1725 NUM eurjchem-221 64 246 , , PUNCT eurjchem-221 64 247     SPACE eurjchem-221 64 248 1686 1686 NUM eurjchem-221 64 249 , , PUNCT eurjchem-221 64 250     SPACE eurjchem-221 64 251 1626 1626 NUM eurjchem-221 64 252 , , PUNCT eurjchem-221 64 253     SPACE eurjchem-221 64 254 1506 1506 NUM eurjchem-221 64 255 , , PUNCT eurjchem-221 64 256     SPACE eurjchem-221 64 257 1439 1439 NUM eurjchem-221 64 258 , , PUNCT eurjchem-221 64 259     SPACE eurjchem-221 64 260 1325 1325 NUM eurjchem-221 64 261 , , PUNCT eurjchem-221 64 262     SPACE eurjchem-221 64 263 1285 1285 NUM eurjchem-221 64 264 , , PUNCT eurjchem-221 64 265     SPACE eurjchem-221 64 266 1152 1152 NUM eurjchem-221 64 267 , , PUNCT eurjchem-221 64 268     SPACE eurjchem-221 64 269 799 799 NUM eurjchem-221 64 270 . . PUNCT eurjchem-221 64 271     SPACE eurjchem-221 64 272 methyl methyl NOUN eurjchem-221 64 273     SPACE eurjchem-221 64 274 2,2'‐dihydroxy‐1,1'‐binaphthyl‐3‐carboxylate 2,2'‐dihydroxy‐1,1'‐binaphthyl‐3‐carboxylate NOUN eurjchem-221 64 275     SPACE eurjchem-221 64 276 ( ( PUNCT eurjchem-221 64 277 e e NOUN eurjchem-221 64 278 ): ): NOUN eurjchem-221 64 279     SPACE eurjchem-221 64 280 m.p m.p PROPN eurjchem-221 64 281 . . PROPN eurjchem-221 64 282 : : PUNCT eurjchem-221 64 283     SPACE eurjchem-221 64 284 178‐180 178‐180 NOUN eurjchem-221 64 285     SPACE eurjchem-221 64 286 οc οc PROPN eurjchem-221 64 287 . . PROPN eurjchem-221 64 288     SPACE eurjchem-221 64 289 1h 1h NUM eurjchem-221 64 290     SPACE eurjchem-221 64 291 nmr nmr NOUN eurjchem-221 64 292     SPACE eurjchem-221 64 293 ( ( PUNCT eurjchem-221 64 294 cdcl3 cdcl3 PROPN eurjchem-221 64 295 , , PUNCT eurjchem-221 64 296     SPACE eurjchem-221 64 297 δ δ PROPN eurjchem-221 64 298 , , PUNCT eurjchem-221 64 299     SPACE eurjchem-221 64 300 ppm ppm ADJ eurjchem-221 64 301 ): ): PUNCT eurjchem-221 64 302     SPACE eurjchem-221 64 303 4.08 4.08 NUM eurjchem-221 64 304     SPACE eurjchem-221 64 305 ( ( PUNCT eurjchem-221 64 306 s s PROPN eurjchem-221 64 307 , , PUNCT eurjchem-221 64 308     SPACE eurjchem-221 64 309 3h 3h NUM eurjchem-221 64 310 ) ) PUNCT eurjchem-221 64 311 , , PUNCT eurjchem-221 64 312     SPACE eurjchem-221 64 313 7.06‐ 7.06‐ NUM eurjchem-221 64 314 7.08 7.08 NUM eurjchem-221 64 315     SPACE eurjchem-221 64 316 ( ( PUNCT eurjchem-221 64 317 m m PROPN eurjchem-221 64 318 , , PUNCT eurjchem-221 64 319     SPACE eurjchem-221 64 320 1h 1h NUM eurjchem-221 64 321 ) ) PUNCT eurjchem-221 64 322 , , PUNCT eurjchem-221 64 323     SPACE eurjchem-221 64 324 7.16‐7.20 7.16‐7.20 NUM eurjchem-221 64 325     SPACE eurjchem-221 64 326 ( ( PUNCT eurjchem-221 64 327 m m PROPN eurjchem-221 64 328 , , PUNCT eurjchem-221 64 329     SPACE eurjchem-221 64 330 1h 1h NUM eurjchem-221 64 331 ) ) PUNCT eurjchem-221 64 332 , , PUNCT eurjchem-221 64 333     SPACE eurjchem-221 64 334 7.22‐7.24 7.22‐7.24 NUM eurjchem-221 64 335     SPACE eurjchem-221 64 336 ( ( PUNCT eurjchem-221 64 337 m m PROPN eurjchem-221 64 338 , , PUNCT eurjchem-221 64 339     SPACE eurjchem-221 64 340 1h 1h NUM eurjchem-221 64 341 ) ) PUNCT eurjchem-221 64 342 , , PUNCT eurjchem-221 64 343     SPACE eurjchem-221 64 344 7.30‐7.40 7.30‐7.40 NOUN eurjchem-221 64 345     SPACE eurjchem-221 64 346 ( ( PUNCT eurjchem-221 64 347 m m PROPN eurjchem-221 64 348 , , PUNCT eurjchem-221 64 349     SPACE eurjchem-221 64 350 4h 4h NOUN eurjchem-221 64 351 ) ) PUNCT eurjchem-221 64 352 , , PUNCT eurjchem-221 64 353     SPACE eurjchem-221 64 354 7.86‐7.95 7.86‐7.95 NOUN eurjchem-221 64 355     SPACE eurjchem-221 64 356 ( ( PUNCT eurjchem-221 64 357 m m PROPN eurjchem-221 64 358 , , PUNCT eurjchem-221 64 359     SPACE eurjchem-221 64 360 4h 4h NOUN eurjchem-221 64 361 ) ) PUNCT eurjchem-221 64 362 , , PUNCT eurjchem-221 64 363     SPACE eurjchem-221 64 364 8.74 8.74 NUM eurjchem-221 64 365     SPACE eurjchem-221 64 366 ( ( PUNCT eurjchem-221 64 367 m m PROPN eurjchem-221 64 368 , , PUNCT eurjchem-221 64 369     SPACE eurjchem-221 64 370 1h 1h NUM eurjchem-221 64 371 ) ) PUNCT eurjchem-221 64 372 , , PUNCT eurjchem-221 64 373     SPACE eurjchem-221 64 374 10.85 10.85 NUM eurjchem-221 64 375     SPACE eurjchem-221 64 376 ( ( PUNCT eurjchem-221 64 377 m m PROPN eurjchem-221 64 378 , , PUNCT eurjchem-221 64 379     SPACE eurjchem-221 64 380 1h 1h NUM eurjchem-221 64 381 ) ) PUNCT eurjchem-221 64 382 . . PUNCT eurjchem-221 64 383     SPACE eurjchem-221 64 384 13c 13c NOUN eurjchem-221 64 385     SPACE eurjchem-221 64 386 nmr nmr NOUN eurjchem-221 64 387     SPACE eurjchem-221 64 388 ( ( PUNCT eurjchem-221 64 389 cdcl3 cdcl3 PROPN eurjchem-221 64 390 , , PUNCT eurjchem-221 64 391     SPACE eurjchem-221 64 392 δ δ PROPN eurjchem-221 64 393 , , PUNCT eurjchem-221 64 394     SPACE eurjchem-221 64 395 ppm ppm ADJ eurjchem-221 64 396 ): ): PUNCT eurjchem-221 64 397     SPACE eurjchem-221 64 398 52.9 52.9 NUM eurjchem-221 64 399 , , PUNCT eurjchem-221 64 400     SPACE eurjchem-221 64 401 114.0 114.0 NUM eurjchem-221 64 402 , , PUNCT eurjchem-221 64 403     SPACE eurjchem-221 64 404 114.3 114.3 NUM eurjchem-221 64 405 , , PUNCT eurjchem-221 64 406     SPACE eurjchem-221 64 407 114.5 114.5 NUM eurjchem-221 64 408 , , PUNCT eurjchem-221 64 409     SPACE eurjchem-221 64 410 117.6 117.6 NUM eurjchem-221 64 411 , , PUNCT eurjchem-221 64 412     SPACE eurjchem-221 64 413 123.4 123.4 NUM eurjchem-221 64 414 , , PUNCT eurjchem-221 64 415     SPACE eurjchem-221 64 416 124.5 124.5 NUM eurjchem-221 64 417 , , PUNCT eurjchem-221 64 418     SPACE eurjchem-221 64 419 124.6 124.6 NUM eurjchem-221 64 420 , , PUNCT eurjchem-221 64 421     SPACE eurjchem-221 64 422 124.7 124.7 NUM eurjchem-221 64 423 , , PUNCT eurjchem-221 64 424     SPACE eurjchem-221 64 425 126.6 126.6 NUM eurjchem-221 64 426 , , PUNCT eurjchem-221 64 427     SPACE eurjchem-221 64 428 127.3 127.3 NUM eurjchem-221 64 429 , , PUNCT eurjchem-221 64 430     SPACE eurjchem-221 64 431 128.3 128.3 NUM eurjchem-221 64 432 , , PUNCT eurjchem-221 64 433     SPACE eurjchem-221 64 434 129.3 129.3 NUM eurjchem-221 64 435 , , PUNCT eurjchem-221 64 436     SPACE eurjchem-221 64 437 129.8 129.8 NUM eurjchem-221 64 438 , , PUNCT eurjchem-221 64 439     SPACE eurjchem-221 64 440 130.1 130.1 NUM eurjchem-221 64 441 , , PUNCT eurjchem-221 64 442     SPACE eurjchem-221 64 443 130.2 130.2 NUM eurjchem-221 64 444 , , PUNCT eurjchem-221 64 445     SPACE eurjchem-221 64 446 133.4 133.4 NUM eurjchem-221 64 447 , , PUNCT eurjchem-221 64 448     SPACE eurjchem-221 64 449 133.9 133.9 NUM eurjchem-221 64 450 , , PUNCT eurjchem-221 64 451     SPACE eurjchem-221 64 452 137.4 137.4 NUM eurjchem-221 64 453 , , PUNCT eurjchem-221 64 454     SPACE eurjchem-221 64 455 151.4 151.4 NUM eurjchem-221 64 456 , , PUNCT eurjchem-221 64 457     SPACE eurjchem-221 64 458 154.9 154.9 NUM eurjchem-221 64 459 , , PUNCT eurjchem-221 64 460     SPACE eurjchem-221 64 461 170.3 170.3 NUM eurjchem-221 64 462 . . PUNCT eurjchem-221 64 463     SPACE eurjchem-221 65 1 ir ir PROPN eurjchem-221 65 2     SPACE eurjchem-221 65 3 ( ( PUNCT eurjchem-221 65 4 kbr kbr PROPN eurjchem-221 65 5 , , PUNCT eurjchem-221 65 6     SPACE eurjchem-221 65 7 cm‐1 cm‐1 NOUN eurjchem-221 65 8 ): ): PUNCT eurjchem-221 65 9     SPACE eurjchem-221 65 10 3497 3497 NUM eurjchem-221 65 11 , , PUNCT eurjchem-221 65 12     SPACE eurjchem-221 65 13 2978 2978 NUM eurjchem-221 65 14 , , PUNCT eurjchem-221 65 15     SPACE eurjchem-221 65 16 2890 2890 NUM eurjchem-221 65 17 , , PUNCT eurjchem-221 65 18     SPACE eurjchem-221 65 19 1738 1738 NUM eurjchem-221 65 20 , , PUNCT eurjchem-221 65 21     SPACE eurjchem-221 65 22 1694 1694 NUM eurjchem-221 65 23 , , PUNCT eurjchem-221 65 24     SPACE eurjchem-221 65 25 1500 1500 NUM eurjchem-221 65 26 , , PUNCT eurjchem-221 65 27     SPACE eurjchem-221 65 28 1431 1431 NUM eurjchem-221 65 29 , , PUNCT eurjchem-221 65 30     SPACE eurjchem-221 65 31 1319 1319 NUM eurjchem-221 65 32 , , PUNCT eurjchem-221 65 33     SPACE eurjchem-221 65 34 1275 1275 NUM eurjchem-221 65 35 , , PUNCT eurjchem-221 65 36     SPACE eurjchem-221 65 37 1211 1211 NUM eurjchem-221 65 38 , , PUNCT eurjchem-221 65 39     SPACE eurjchem-221 65 40 1150 1150 NUM eurjchem-221 65 41 , , PUNCT eurjchem-221 65 42     SPACE eurjchem-221 65 43 999 999 NUM eurjchem-221 65 44 , , PUNCT eurjchem-221 65 45     SPACE eurjchem-221 65 46 786 786 NUM eurjchem-221 65 47 . . PUNCT eurjchem-221 65 48                     SPACE eurjchem-221 65 49 362 362 NUM eurjchem-221 65 50     SPACE eurjchem-221 65 51 sabarinathan sabarinathan PROPN eurjchem-221 65 52     SPACE eurjchem-221 65 53 et et NOUN eurjchem-221 65 54     SPACE eurjchem-221 65 55 al al PROPN eurjchem-221 65 56 . . PROPN eurjchem-221 65 57     SPACE eurjchem-221 65 58 / / SYM eurjchem-221 65 59     SPACE eurjchem-221 65 60 european european ADJ eurjchem-221 65 61     SPACE eurjchem-221 65 62 journal journal NOUN eurjchem-221 65 63     SPACE eurjchem-221 65 64 of of ADP eurjchem-221 65 65     SPACE eurjchem-221 65 66 chemistry chemistry NOUN eurjchem-221 65 67     SPACE eurjchem-221 65 68 1 1 NUM eurjchem-221 65 69     SPACE eurjchem-221 65 70 ( ( PUNCT eurjchem-221 65 71 4 4 NUM eurjchem-221 65 72 ) ) PUNCT eurjchem-221 65 73     SPACE eurjchem-221 65 74 ( ( PUNCT eurjchem-221 65 75 2010 2010 NUM eurjchem-221 65 76 ) ) PUNCT eurjchem-221 65 77     SPACE eurjchem-221 65 78 360­367 360­367 NUM eurjchem-221 65 79         SPACE eurjchem-221 65 80 figure figure NOUN eurjchem-221 65 81     SPACE eurjchem-221 65 82 1 1 NUM eurjchem-221 65 83 . . PUNCT eurjchem-221 65 84 copper copper NOUN eurjchem-221 65 85     SPACE eurjchem-221 65 86 salen salen PROPN eurjchem-221 65 87     SPACE eurjchem-221 65 88 complexes complex NOUN eurjchem-221 65 89 . . PUNCT eurjchem-221 65 90             SPACE eurjchem-221 66 1 3 3 NUM eurjchem-221 66 2 . . PUNCT eurjchem-221 66 3     SPACE eurjchem-221 66 4 results result VERB eurjchem-221 66 5     SPACE eurjchem-221 66 6 and and CCONJ eurjchem-221 66 7     SPACE eurjchem-221 66 8 discussion discussion NOUN eurjchem-221 66 9           SPACE eurjchem-221 66 10 3.1 3.1 NUM eurjchem-221 66 11 . . PUNCT eurjchem-221 66 12     SPACE eurjchem-221 66 13 epr epr PROPN eurjchem-221 66 14     SPACE eurjchem-221 66 15 characterization characterization NOUN eurjchem-221 66 16     SPACE eurjchem-221 66 17 of of ADP eurjchem-221 66 18     SPACE eurjchem-221 66 19 complexes complex NOUN eurjchem-221 66 20         SPACE eurjchem-221 66 21 three three NUM eurjchem-221 66 22     SPACE eurjchem-221 66 23 chiral chiral ADJ eurjchem-221 66 24     SPACE eurjchem-221 66 25 salen salen PROPN eurjchem-221 66 26     SPACE eurjchem-221 66 27 ligands ligand NOUN eurjchem-221 66 28     SPACE eurjchem-221 66 29 and and CCONJ eurjchem-221 66 30     SPACE eurjchem-221 66 31 three three NUM eurjchem-221 66 32     SPACE eurjchem-221 66 33 achiral achiral ADJ eurjchem-221 66 34     SPACE eurjchem-221 66 35 salen salen PROPN eurjchem-221 66 36     SPACE eurjchem-221 66 37 ligands ligand NOUN eurjchem-221 66 38     SPACE eurjchem-221 66 39 prepared prepare VERB eurjchem-221 66 40     SPACE eurjchem-221 66 41 using use VERB eurjchem-221 66 42     SPACE eurjchem-221 66 43 1r,2r‐cyclohexanediamine 1r,2r‐cyclohexanediamine NOUN eurjchem-221 66 44     SPACE eurjchem-221 66 45 and and CCONJ eurjchem-221 66 46     SPACE eurjchem-221 66 47 1,2‐diamino 1,2‐diamino NOUN eurjchem-221 66 48     SPACE eurjchem-221 66 49 benzene benzene NOUN eurjchem-221 66 50     SPACE eurjchem-221 66 51 respectively respectively ADV eurjchem-221 66 52     SPACE eurjchem-221 66 53 were be AUX eurjchem-221 66 54     SPACE eurjchem-221 66 55 complexed complexe VERB eurjchem-221 66 56     SPACE eurjchem-221 66 57 with with ADP eurjchem-221 66 58     SPACE eurjchem-221 66 59 cu(ii cu(ii PROPN eurjchem-221 66 60 ) ) PUNCT eurjchem-221 66 61     SPACE eurjchem-221 66 62 chloride chloride NOUN eurjchem-221 66 63     SPACE eurjchem-221 66 64 ( ( PUNCT eurjchem-221 66 65 figure figure NOUN eurjchem-221 66 66     SPACE eurjchem-221 66 67 1 1 NUM eurjchem-221 66 68 ) ) PUNCT eurjchem-221 66 69 . . PUNCT eurjchem-221 66 70     SPACE eurjchem-221 67 1 complexes complex NOUN eurjchem-221 67 2     SPACE eurjchem-221 67 3 1­6 1­6 NUM eurjchem-221 67 4     SPACE eurjchem-221 67 5 were be AUX eurjchem-221 67 6     SPACE eurjchem-221 67 7 characterized characterize VERB eurjchem-221 67 8     SPACE eurjchem-221 67 9 by by ADP eurjchem-221 67 10     SPACE eurjchem-221 67 11 epr epr PROPN eurjchem-221 67 12 . . PUNCT eurjchem-221 67 13     SPACE eurjchem-221 68 1 the the DET eurjchem-221 68 2     SPACE eurjchem-221 68 3 epr epr PROPN eurjchem-221 68 4     SPACE eurjchem-221 68 5 data datum NOUN eurjchem-221 68 6     SPACE eurjchem-221 68 7 are be AUX eurjchem-221 68 8     SPACE eurjchem-221 68 9 presented present VERB eurjchem-221 68 10     SPACE eurjchem-221 68 11 in in ADP eurjchem-221 68 12     SPACE eurjchem-221 68 13 table table NOUN eurjchem-221 68 14     SPACE eurjchem-221 68 15 1 1 NUM eurjchem-221 68 16 . . PUNCT eurjchem-221 68 17     SPACE eurjchem-221 68 18 epr epr PROPN eurjchem-221 68 19     SPACE eurjchem-221 68 20 parameters parameter NOUN eurjchem-221 68 21     SPACE eurjchem-221 68 22 indicate indicate VERB eurjchem-221 68 23     SPACE eurjchem-221 68 24 unique unique ADJ eurjchem-221 68 25     SPACE eurjchem-221 68 26 electronic electronic ADJ eurjchem-221 68 27     SPACE eurjchem-221 68 28 and and CCONJ eurjchem-221 68 29     SPACE eurjchem-221 68 30 geometric geometric ADJ eurjchem-221 68 31     SPACE eurjchem-221 68 32 arrangement arrangement NOUN eurjchem-221 68 33     SPACE eurjchem-221 68 34 around around ADP eurjchem-221 68 35     SPACE eurjchem-221 68 36 each each DET eurjchem-221 68 37     SPACE eurjchem-221 68 38 complex complex NOUN eurjchem-221 68 39     SPACE eurjchem-221 68 40 ( ( PUNCT eurjchem-221 68 41 figure figure NOUN eurjchem-221 68 42     SPACE eurjchem-221 68 43 2 2 NUM eurjchem-221 68 44 ) ) PUNCT eurjchem-221 68 45 . . PUNCT eurjchem-221 68 46     SPACE eurjchem-221 69 1 complexes complex NOUN eurjchem-221 69 2     SPACE eurjchem-221 69 3 1 1 NUM eurjchem-221 69 4 , , PUNCT eurjchem-221 69 5     SPACE eurjchem-221 69 6 3 3 NUM eurjchem-221 69 7 , , PUNCT eurjchem-221 69 8     SPACE eurjchem-221 69 9 4 4 NUM eurjchem-221 69 10     SPACE eurjchem-221 69 11 and and CCONJ eurjchem-221 69 12     SPACE eurjchem-221 69 13 6 6 NUM eurjchem-221 69 14     SPACE eurjchem-221 69 15 show show NOUN eurjchem-221 69 16     SPACE eurjchem-221 69 17 rhombic rhombic ADJ eurjchem-221 69 18     SPACE eurjchem-221 69 19 symmetry symmetry NOUN eurjchem-221 69 20 , , PUNCT eurjchem-221 69 21     SPACE eurjchem-221 69 22 while while SCONJ eurjchem-221 69 23     SPACE eurjchem-221 69 24 2 2 NUM eurjchem-221 69 25     SPACE eurjchem-221 69 26 and and CCONJ eurjchem-221 69 27     SPACE eurjchem-221 69 28 5 5 NUM eurjchem-221 69 29     SPACE eurjchem-221 69 30 show show NOUN eurjchem-221 69 31     SPACE eurjchem-221 69 32 axial axial ADJ eurjchem-221 69 33     SPACE eurjchem-221 69 34 symmetry symmetry NOUN eurjchem-221 69 35 . . PUNCT eurjchem-221 69 36     SPACE eurjchem-221 70 1 while while SCONJ eurjchem-221 70 2     SPACE eurjchem-221 70 3 the the DET eurjchem-221 70 4     SPACE eurjchem-221 70 5 powder powder NOUN eurjchem-221 70 6     SPACE eurjchem-221 70 7 epr epr PROPN eurjchem-221 70 8     SPACE eurjchem-221 70 9 spectrum spectrum NOUN eurjchem-221 70 10     SPACE eurjchem-221 70 11 of of ADP eurjchem-221 70 12     SPACE eurjchem-221 70 13 1 1 NUM eurjchem-221 70 14     SPACE eurjchem-221 70 15 shows show NOUN eurjchem-221 70 16     SPACE eurjchem-221 70 17 gll gll NOUN eurjchem-221 70 18     SPACE eurjchem-221 70 19 and and CCONJ eurjchem-221 70 20     SPACE eurjchem-221 70 21 g g NOUN eurjchem-221 70 22     SPACE eurjchem-221 70 23 values value NOUN eurjchem-221 70 24 , , PUNCT eurjchem-221 70 25     SPACE eurjchem-221 70 26 analogous analogous ADJ eurjchem-221 70 27     SPACE eurjchem-221 70 28 complex complex NOUN eurjchem-221 70 29     SPACE eurjchem-221 70 30 4 4 NUM eurjchem-221 70 31     SPACE eurjchem-221 70 32 show show NOUN eurjchem-221 70 33     SPACE eurjchem-221 70 34 isotropic isotropic NOUN eurjchem-221 70 35     SPACE eurjchem-221 70 36 value value NOUN eurjchem-221 70 37     SPACE eurjchem-221 70 38 only only ADV eurjchem-221 70 39 . . PUNCT eurjchem-221 70 40     SPACE eurjchem-221 71 1 complex complex NOUN eurjchem-221 71 2     SPACE eurjchem-221 71 3 1 1 NUM eurjchem-221 71 4     SPACE eurjchem-221 71 5 also also ADV eurjchem-221 71 6     SPACE eurjchem-221 71 7 shows show VERB eurjchem-221 71 8     SPACE eurjchem-221 71 9 super super ADJ eurjchem-221 71 10     SPACE eurjchem-221 71 11 hyperfine hyperfine ADJ eurjchem-221 71 12     SPACE eurjchem-221 71 13 splitting splitting NOUN eurjchem-221 71 14     SPACE eurjchem-221 71 15 due due ADJ eurjchem-221 71 16     SPACE eurjchem-221 71 17 to to ADP eurjchem-221 71 18     SPACE eurjchem-221 71 19 the the DET eurjchem-221 71 20     SPACE eurjchem-221 71 21 interaction interaction NOUN eurjchem-221 71 22     SPACE eurjchem-221 71 23 of of ADP eurjchem-221 71 24     SPACE eurjchem-221 71 25 two two NUM eurjchem-221 71 26     SPACE eurjchem-221 71 27 magnetically magnetically ADV eurjchem-221 71 28     SPACE eurjchem-221 71 29 inequivalent inequivalent NOUN eurjchem-221 71 30     SPACE eurjchem-221 71 31 nitrogens nitrogen NOUN eurjchem-221 71 32     SPACE eurjchem-221 71 33 with with ADP eurjchem-221 71 34     SPACE eurjchem-221 71 35 copper copper NOUN eurjchem-221 71 36     SPACE eurjchem-221 71 37 whereas whereas ADV eurjchem-221 71 38     SPACE eurjchem-221 71 39 complex complex NOUN eurjchem-221 71 40     SPACE eurjchem-221 71 41 4 4 NUM eurjchem-221 71 42     SPACE eurjchem-221 71 43 does do AUX eurjchem-221 71 44     SPACE eurjchem-221 71 45 not not PART eurjchem-221 71 46     SPACE eurjchem-221 71 47 shows show VERB eurjchem-221 71 48     SPACE eurjchem-221 71 49 such such ADJ eurjchem-221 71 50     SPACE eurjchem-221 71 51 super super ADJ eurjchem-221 71 52     SPACE eurjchem-221 71 53 hyperfine hyperfine ADJ eurjchem-221 71 54     SPACE eurjchem-221 71 55 splitting splitting NOUN eurjchem-221 71 56 . . PUNCT eurjchem-221 71 57     SPACE eurjchem-221 72 1 both both DET eurjchem-221 72 2     SPACE eurjchem-221 72 3 powder powder NOUN eurjchem-221 72 4     SPACE eurjchem-221 72 5 and and CCONJ eurjchem-221 72 6     SPACE eurjchem-221 72 7 solution solution NOUN eurjchem-221 72 8     SPACE eurjchem-221 72 9 epr epr PROPN eurjchem-221 72 10     SPACE eurjchem-221 72 11 of of ADP eurjchem-221 72 12     SPACE eurjchem-221 72 13 complex complex NOUN eurjchem-221 72 14     SPACE eurjchem-221 72 15 5 5 NUM eurjchem-221 72 16     SPACE eurjchem-221 72 17 at at ADP eurjchem-221 72 18     SPACE eurjchem-221 72 19 room room NOUN eurjchem-221 72 20     SPACE eurjchem-221 72 21 temperature temperature NOUN eurjchem-221 72 22     SPACE eurjchem-221 72 23 and and CCONJ eurjchem-221 72 24     SPACE eurjchem-221 72 25 at at ADP eurjchem-221 72 26     SPACE eurjchem-221 72 27 lnt lnt NOUN eurjchem-221 72 28     SPACE eurjchem-221 72 29 show show NOUN eurjchem-221 72 30     SPACE eurjchem-221 72 31 two two NUM eurjchem-221 72 32     SPACE eurjchem-221 72 33 sets set NOUN eurjchem-221 72 34     SPACE eurjchem-221 72 35 of of ADP eurjchem-221 72 36     SPACE eurjchem-221 72 37 gll gll NOUN eurjchem-221 72 38     SPACE eurjchem-221 72 39 and and CCONJ eurjchem-221 72 40     SPACE eurjchem-221 72 41 g g NOUN eurjchem-221 72 42     SPACE eurjchem-221 72 43 values value NOUN eurjchem-221 72 44     SPACE eurjchem-221 72 45 indicating indicate VERB eurjchem-221 72 46     SPACE eurjchem-221 72 47 the the DET eurjchem-221 72 48     SPACE eurjchem-221 72 49 presence presence NOUN eurjchem-221 72 50     SPACE eurjchem-221 72 51 of of ADP eurjchem-221 72 52     SPACE eurjchem-221 72 53 two two NUM eurjchem-221 72 54     SPACE eurjchem-221 72 55 copper copper NOUN eurjchem-221 72 56     SPACE eurjchem-221 72 57 species specie NOUN eurjchem-221 72 58 . . PUNCT eurjchem-221 72 59     SPACE eurjchem-221 73 1 the the DET eurjchem-221 73 2     SPACE eurjchem-221 73 3 powder powder NOUN eurjchem-221 73 4     SPACE eurjchem-221 73 5 epr epr PROPN eurjchem-221 73 6     SPACE eurjchem-221 73 7 of of ADP eurjchem-221 73 8     SPACE eurjchem-221 73 9 2 2 NUM eurjchem-221 73 10     SPACE eurjchem-221 73 11 shows show VERB eurjchem-221 73 12     SPACE eurjchem-221 73 13 one one NUM eurjchem-221 73 14     SPACE eurjchem-221 73 15 gll gll NOUN eurjchem-221 73 16     SPACE eurjchem-221 73 17 and and CCONJ eurjchem-221 73 18     SPACE eurjchem-221 73 19 g g NOUN eurjchem-221 73 20     SPACE eurjchem-221 73 21 values value NOUN eurjchem-221 73 22 , , PUNCT eurjchem-221 73 23     SPACE eurjchem-221 73 24 but but CCONJ eurjchem-221 73 25     SPACE eurjchem-221 73 26 epr epr PROPN eurjchem-221 73 27     SPACE eurjchem-221 73 28 of of ADP eurjchem-221 73 29     SPACE eurjchem-221 73 30 solution solution NOUN eurjchem-221 73 31     SPACE eurjchem-221 73 32 at at ADP eurjchem-221 73 33     SPACE eurjchem-221 73 34 lnt lnt NOUN eurjchem-221 73 35     SPACE eurjchem-221 73 36 gives give VERB eurjchem-221 73 37     SPACE eurjchem-221 73 38 two two NUM eurjchem-221 73 39     SPACE eurjchem-221 73 40 sets set NOUN eurjchem-221 73 41     SPACE eurjchem-221 73 42 of of ADP eurjchem-221 73 43     SPACE eurjchem-221 73 44 gll gll NOUN eurjchem-221 73 45     SPACE eurjchem-221 73 46 and and CCONJ eurjchem-221 73 47     SPACE eurjchem-221 73 48 g g NOUN eurjchem-221 73 49     SPACE eurjchem-221 73 50 values value NOUN eurjchem-221 73 51     SPACE eurjchem-221 73 52 similar similar ADJ eurjchem-221 73 53     SPACE eurjchem-221 73 54 to to ADP eurjchem-221 73 55     SPACE eurjchem-221 73 56 5 5 NUM eurjchem-221 73 57 . . PUNCT eurjchem-221 73 58     SPACE eurjchem-221 73 59 these these DET eurjchem-221 73 60     SPACE eurjchem-221 73 61 complexes complex NOUN eurjchem-221 73 62     SPACE eurjchem-221 73 63 may may AUX eurjchem-221 73 64     SPACE eurjchem-221 73 65 adopt adopt VERB eurjchem-221 73 66     SPACE eurjchem-221 73 67 different different ADJ eurjchem-221 73 68     SPACE eurjchem-221 73 69 conformations conformation NOUN eurjchem-221 73 70     SPACE eurjchem-221 73 71 due due ADJ eurjchem-221 73 72     SPACE eurjchem-221 73 73 to to ADP eurjchem-221 73 74     SPACE eurjchem-221 73 75 the the DET eurjchem-221 73 76     SPACE eurjchem-221 73 77 presence presence NOUN eurjchem-221 73 78     SPACE eurjchem-221 73 79 of of ADP eurjchem-221 73 80     SPACE eurjchem-221 73 81 bulky bulky ADJ eurjchem-221 73 82     SPACE eurjchem-221 73 83 tertiary tertiary ADJ eurjchem-221 73 84     SPACE eurjchem-221 73 85 butyl butyl NOUN eurjchem-221 73 86     SPACE eurjchem-221 73 87 groups group NOUN eurjchem-221 73 88 . . PUNCT eurjchem-221 73 89     SPACE eurjchem-221 74 1 complex complex ADJ eurjchem-221 74 2     SPACE eurjchem-221 74 3 3 3 NUM eurjchem-221 74 4     SPACE eurjchem-221 74 5 and and CCONJ eurjchem-221 74 6     SPACE eurjchem-221 74 7 6 6 NUM eurjchem-221 74 8     SPACE eurjchem-221 74 9 show show NOUN eurjchem-221 74 10     SPACE eurjchem-221 74 11 giso giso NOUN eurjchem-221 74 12     SPACE eurjchem-221 74 13 only only ADV eurjchem-221 74 14     SPACE eurjchem-221 74 15 at at ADP eurjchem-221 74 16     SPACE eurjchem-221 74 17 rt rt NOUN eurjchem-221 74 18     SPACE eurjchem-221 74 19 but but CCONJ eurjchem-221 74 20     SPACE eurjchem-221 74 21 solution solution NOUN eurjchem-221 74 22     SPACE eurjchem-221 74 23 sample sample NOUN eurjchem-221 74 24     SPACE eurjchem-221 74 25 at at ADP eurjchem-221 74 26     SPACE eurjchem-221 74 27 lnt lnt NOUN eurjchem-221 74 28     SPACE eurjchem-221 74 29 shows show VERB eurjchem-221 74 30     SPACE eurjchem-221 74 31 three three NUM eurjchem-221 74 32     SPACE eurjchem-221 74 33 g g NOUN eurjchem-221 74 34     SPACE eurjchem-221 74 35 values value NOUN eurjchem-221 74 36     SPACE eurjchem-221 74 37 for for ADP eurjchem-221 74 38     SPACE eurjchem-221 74 39 both both DET eurjchem-221 74 40     SPACE eurjchem-221 74 41 complexes complex NOUN eurjchem-221 74 42     SPACE eurjchem-221 74 43 confirming confirm VERB eurjchem-221 74 44     SPACE eurjchem-221 74 45 the the DET eurjchem-221 74 46     SPACE eurjchem-221 74 47 rhombic rhombic ADJ eurjchem-221 74 48     SPACE eurjchem-221 74 49 symmetry symmetry NOUN eurjchem-221 74 50 . . PUNCT eurjchem-221 74 51     SPACE eurjchem-221 74 52 in in ADP eurjchem-221 74 53     SPACE eurjchem-221 74 54 general general ADJ eurjchem-221 74 55     SPACE eurjchem-221 74 56 chiral chiral ADJ eurjchem-221 74 57     SPACE eurjchem-221 74 58 salen salen PROPN eurjchem-221 74 59     SPACE eurjchem-221 74 60 complexes complex NOUN eurjchem-221 74 61     SPACE eurjchem-221 74 62 1­3 1­3 PRON eurjchem-221 74 63     SPACE eurjchem-221 74 64 are be AUX eurjchem-221 74 65     SPACE eurjchem-221 74 66 more more ADV eurjchem-221 74 67     SPACE eurjchem-221 74 68 distorted distort VERB eurjchem-221 74 69     SPACE eurjchem-221 74 70 than than ADP eurjchem-221 74 71     SPACE eurjchem-221 74 72 their their PRON eurjchem-221 74 73     SPACE eurjchem-221 74 74 achiral achiral ADJ eurjchem-221 74 75     SPACE eurjchem-221 74 76 analogues analogue NOUN eurjchem-221 74 77     SPACE eurjchem-221 74 78 4­6 4­6 NUM eurjchem-221 74 79 . . PUNCT eurjchem-221 74 80     SPACE eurjchem-221 75 1 the the DET eurjchem-221 75 2     SPACE eurjchem-221 75 3 observed observe VERB eurjchem-221 75 4     SPACE eurjchem-221 75 5 distortion distortion NOUN eurjchem-221 75 6     SPACE eurjchem-221 75 7 can can AUX eurjchem-221 75 8     SPACE eurjchem-221 75 9 be be AUX eurjchem-221 75 10     SPACE eurjchem-221 75 11 attributed attribute VERB eurjchem-221 75 12     SPACE eurjchem-221 75 13 to to ADP eurjchem-221 75 14     SPACE eurjchem-221 75 15 the the DET eurjchem-221 75 16     SPACE eurjchem-221 75 17 trans tran NOUN eurjchem-221 75 18     SPACE eurjchem-221 75 19 orientation orientation NOUN eurjchem-221 75 20     SPACE eurjchem-221 75 21 of of ADP eurjchem-221 75 22     SPACE eurjchem-221 75 23 the the DET eurjchem-221 75 24     SPACE eurjchem-221 75 25 amino amino NOUN eurjchem-221 75 26     SPACE eurjchem-221 75 27 groups group NOUN eurjchem-221 75 28     SPACE eurjchem-221 75 29 in in ADP eurjchem-221 75 30     SPACE eurjchem-221 75 31 cyclohexanediamine cyclohexanediamine NOUN eurjchem-221 75 32 . . PUNCT eurjchem-221 75 33         SPACE eurjchem-221 76 1 3.2 3.2 NUM eurjchem-221 76 2 . . PUNCT eurjchem-221 76 3     SPACE eurjchem-221 76 4 catalytic catalytic ADJ eurjchem-221 76 5     SPACE eurjchem-221 76 6 performance performance NOUN eurjchem-221 76 7     SPACE eurjchem-221 76 8 of of ADP eurjchem-221 76 9     SPACE eurjchem-221 76 10 complexes complex NOUN eurjchem-221 76 11         SPACE eurjchem-221 76 12 all all DET eurjchem-221 76 13     SPACE eurjchem-221 76 14 complexes complex NOUN eurjchem-221 76 15     SPACE eurjchem-221 76 16 were be AUX eurjchem-221 76 17     SPACE eurjchem-221 76 18 tested test VERB eurjchem-221 76 19     SPACE eurjchem-221 76 20 for for ADP eurjchem-221 76 21     SPACE eurjchem-221 76 22 their their PRON eurjchem-221 76 23     SPACE eurjchem-221 76 24 efficacy efficacy NOUN eurjchem-221 76 25     SPACE eurjchem-221 76 26 for for ADP eurjchem-221 76 27     SPACE eurjchem-221 76 28 aerobic aerobic ADJ eurjchem-221 76 29     SPACE eurjchem-221 76 30 oxidative oxidative ADJ eurjchem-221 76 31     SPACE eurjchem-221 76 32 coupling coupling NOUN eurjchem-221 76 33     SPACE eurjchem-221 76 34 of of ADP eurjchem-221 76 35     SPACE eurjchem-221 76 36 2‐naphthol 2‐naphthol NUM eurjchem-221 76 37     SPACE eurjchem-221 76 38 derivatives derivative NOUN eurjchem-221 76 39     SPACE eurjchem-221 76 40 ( ( PUNCT eurjchem-221 76 41 scheme scheme NOUN eurjchem-221 76 42     SPACE eurjchem-221 76 43 1‐3 1‐3 NOUN eurjchem-221 76 44 ) ) PUNCT eurjchem-221 76 45 . . PUNCT eurjchem-221 76 46     SPACE eurjchem-221 77 1 to to PART eurjchem-221 77 2     SPACE eurjchem-221 77 3 optimize optimize VERB eurjchem-221 77 4     SPACE eurjchem-221 77 5 the the DET eurjchem-221 77 6     SPACE eurjchem-221 77 7 reaction reaction NOUN eurjchem-221 77 8     SPACE eurjchem-221 77 9 condition condition NOUN eurjchem-221 77 10 , , PUNCT eurjchem-221 77 11     SPACE eurjchem-221 77 12 oxidative oxidative ADJ eurjchem-221 77 13     SPACE eurjchem-221 77 14 coupling coupling NOUN eurjchem-221 77 15     SPACE eurjchem-221 77 16 of of ADP eurjchem-221 77 17                                     SPACE eurjchem-221 77 18 2‐naphthol 2‐naphthol NOUN eurjchem-221 77 19     SPACE eurjchem-221 77 20 with with ADP eurjchem-221 77 21     SPACE eurjchem-221 77 22 complex complex NOUN eurjchem-221 77 23     SPACE eurjchem-221 77 24 2 2 NUM eurjchem-221 77 25     SPACE eurjchem-221 77 26 was be AUX eurjchem-221 77 27     SPACE eurjchem-221 77 28 performed perform VERB eurjchem-221 77 29     SPACE eurjchem-221 77 30 in in ADP eurjchem-221 77 31     SPACE eurjchem-221 77 32 different different ADJ eurjchem-221 77 33     SPACE eurjchem-221 77 34 polar polar NOUN eurjchem-221 77 35     SPACE eurjchem-221 77 36 as as ADV eurjchem-221 77 37     SPACE eurjchem-221 77 38 well well ADV eurjchem-221 77 39     SPACE eurjchem-221 77 40 as as ADP eurjchem-221 77 41     SPACE eurjchem-221 77 42 non‐polar non‐polar NOUN eurjchem-221 77 43     SPACE eurjchem-221 77 44 organic organic ADJ eurjchem-221 77 45     SPACE eurjchem-221 77 46 solvents solvent NOUN eurjchem-221 77 47     SPACE eurjchem-221 77 48 like like ADP eurjchem-221 77 49     SPACE eurjchem-221 77 50 dichloromethane dichloromethane NOUN eurjchem-221 77 51 , , PUNCT eurjchem-221 77 52     SPACE eurjchem-221 77 53 dichloroethane dichloroethane ADJ eurjchem-221 77 54 , , PUNCT eurjchem-221 77 55     SPACE eurjchem-221 77 56 methanol methanol NOUN eurjchem-221 77 57 , , PUNCT eurjchem-221 77 58     SPACE eurjchem-221 77 59 ethanol ethanol NOUN eurjchem-221 77 60 , , PUNCT eurjchem-221 77 61     SPACE eurjchem-221 77 62 acetone acetone NOUN eurjchem-221 77 63 , , PUNCT eurjchem-221 77 64     SPACE eurjchem-221 77 65 tetrahydrofuron tetrahydrofuron NOUN eurjchem-221 77 66 , , PUNCT eurjchem-221 77 67     SPACE eurjchem-221 77 68 carbontetrachloride carbontetrachloride NOUN eurjchem-221 77 69 , , PUNCT eurjchem-221 77 70     SPACE eurjchem-221 77 71 chloroform chloroform NOUN eurjchem-221 77 72 , , PUNCT eurjchem-221 77 73     SPACE eurjchem-221 77 74 ethylacetate ethylacetate VERB eurjchem-221 77 75 , , PUNCT eurjchem-221 77 76     SPACE eurjchem-221 77 77 acetonitrile acetonitrile NOUN eurjchem-221 77 78 , , PUNCT eurjchem-221 77 79     SPACE eurjchem-221 77 80 xylene xylene NOUN eurjchem-221 77 81 , , PUNCT eurjchem-221 77 82     SPACE eurjchem-221 77 83 tolune tolune NOUN eurjchem-221 77 84     SPACE eurjchem-221 77 85 and and CCONJ eurjchem-221 77 86     SPACE eurjchem-221 77 87 chlorobenzene chlorobenzene NOUN eurjchem-221 77 88     SPACE eurjchem-221 77 89 at at ADP eurjchem-221 77 90     SPACE eurjchem-221 77 91 room room NOUN eurjchem-221 77 92     SPACE eurjchem-221 77 93 temperature temperature NOUN eurjchem-221 77 94     SPACE eurjchem-221 77 95 and and CCONJ eurjchem-221 77 96     SPACE eurjchem-221 77 97 under under ADV eurjchem-221 77 98     SPACE eurjchem-221 77 99 reflux reflux NOUN eurjchem-221 77 100     SPACE eurjchem-221 77 101 condition condition NOUN eurjchem-221 77 102 . . PUNCT eurjchem-221 77 103     SPACE eurjchem-221 78 1 reaction reaction NOUN eurjchem-221 78 2     SPACE eurjchem-221 78 3 in in ADP eurjchem-221 78 4     SPACE eurjchem-221 78 5 chlorobenzene chlorobenzene NOUN eurjchem-221 78 6     SPACE eurjchem-221 78 7 under under ADP eurjchem-221 78 8     SPACE eurjchem-221 78 9 refluxing refluxing NOUN eurjchem-221 78 10     SPACE eurjchem-221 78 11 condition condition NOUN eurjchem-221 78 12     SPACE eurjchem-221 78 13 resulted result VERB eurjchem-221 78 14     SPACE eurjchem-221 78 15 in in ADP eurjchem-221 78 16     SPACE eurjchem-221 78 17 the the DET eurjchem-221 78 18     SPACE eurjchem-221 78 19 optimum optimum ADJ eurjchem-221 78 20     SPACE eurjchem-221 78 21 condition condition NOUN eurjchem-221 78 22     SPACE eurjchem-221 78 23 for for ADP eurjchem-221 78 24     SPACE eurjchem-221 78 25 the the DET eurjchem-221 78 26     SPACE eurjchem-221 78 27 formation formation NOUN eurjchem-221 78 28     SPACE eurjchem-221 78 29 of of ADP eurjchem-221 78 30     SPACE eurjchem-221 78 31 the the DET eurjchem-221 78 32     SPACE eurjchem-221 78 33 desired desire VERB eurjchem-221 78 34     SPACE eurjchem-221 78 35 product product NOUN eurjchem-221 78 36     SPACE eurjchem-221 78 37 binol binol ADJ eurjchem-221 78 38 . . PUNCT eurjchem-221 78 39     SPACE eurjchem-221 78 40 in in ADP eurjchem-221 78 41     SPACE eurjchem-221 78 42 other other ADJ eurjchem-221 78 43     SPACE eurjchem-221 78 44 solvents solvent NOUN eurjchem-221 78 45     SPACE eurjchem-221 78 46 either either DET eurjchem-221 78 47     SPACE eurjchem-221 78 48 reaction reaction NOUN eurjchem-221 78 49     SPACE eurjchem-221 78 50 did do AUX eurjchem-221 78 51     SPACE eurjchem-221 78 52 not not PART eurjchem-221 78 53     SPACE eurjchem-221 78 54 yield yield VERB eurjchem-221 78 55     SPACE eurjchem-221 78 56 binol binol NOUN eurjchem-221 78 57     SPACE eurjchem-221 78 58 or or CCONJ eurjchem-221 78 59     SPACE eurjchem-221 78 60 the the DET eurjchem-221 78 61     SPACE eurjchem-221 78 62 yield yield NOUN eurjchem-221 78 63     SPACE eurjchem-221 78 64 of of ADP eurjchem-221 78 65     SPACE eurjchem-221 78 66 the the DET eurjchem-221 78 67     SPACE eurjchem-221 78 68 product product NOUN eurjchem-221 78 69     SPACE eurjchem-221 78 70 was be AUX eurjchem-221 78 71     SPACE eurjchem-221 78 72 very very ADV eurjchem-221 78 73     SPACE eurjchem-221 78 74 low low ADJ eurjchem-221 78 75 . . PUNCT eurjchem-221 78 76     SPACE eurjchem-221 78 77 the the DET eurjchem-221 78 78     SPACE eurjchem-221 78 79 reaction reaction NOUN eurjchem-221 78 80     SPACE eurjchem-221 78 81 progress progress NOUN eurjchem-221 78 82     SPACE eurjchem-221 78 83 was be AUX eurjchem-221 78 84     SPACE eurjchem-221 78 85 monitored monitor VERB eurjchem-221 78 86     SPACE eurjchem-221 78 87 by by ADP eurjchem-221 78 88     SPACE eurjchem-221 78 89 tlc tlc NOUN eurjchem-221 78 90     SPACE eurjchem-221 78 91 ( ( PUNCT eurjchem-221 78 92 sio2 sio2 PROPN eurjchem-221 78 93 ) ) PUNCT eurjchem-221 78 94 . . PUNCT eurjchem-221 78 95     SPACE eurjchem-221 78 96 reaction reaction NOUN eurjchem-221 78 97     SPACE eurjchem-221 78 98 time time NOUN eurjchem-221 78 99     SPACE eurjchem-221 78 100 was be AUX eurjchem-221 78 101     SPACE eurjchem-221 78 102 optimised optimise VERB eurjchem-221 78 103     SPACE eurjchem-221 78 104 to to PART eurjchem-221 78 105     SPACE eurjchem-221 78 106 be be AUX eurjchem-221 78 107     SPACE eurjchem-221 78 108 48 48 NUM eurjchem-221 78 109     SPACE eurjchem-221 78 110 h h NOUN eurjchem-221 78 111     SPACE eurjchem-221 78 112 to to PART eurjchem-221 78 113     SPACE eurjchem-221 78 114 obtain obtain VERB eurjchem-221 78 115     SPACE eurjchem-221 78 116 maximum maximum ADJ eurjchem-221 78 117     SPACE eurjchem-221 78 118 yield yield NOUN eurjchem-221 78 119     SPACE eurjchem-221 78 120 of of ADP eurjchem-221 78 121     SPACE eurjchem-221 78 122 the the DET eurjchem-221 78 123     SPACE eurjchem-221 78 124 desired desire VERB eurjchem-221 78 125     SPACE eurjchem-221 78 126 product product NOUN eurjchem-221 78 127     SPACE eurjchem-221 78 128 binol binol ADJ eurjchem-221 78 129 . . PUNCT eurjchem-221 78 130     SPACE eurjchem-221 79 1 continuing continue VERB eurjchem-221 79 2     SPACE eurjchem-221 79 3 the the DET eurjchem-221 79 4     SPACE eurjchem-221 79 5 reaction reaction NOUN eurjchem-221 79 6     SPACE eurjchem-221 79 7 beyond beyond ADP eurjchem-221 79 8     SPACE eurjchem-221 79 9 48 48 NUM eurjchem-221 79 10     SPACE eurjchem-221 79 11 h h NOUN eurjchem-221 79 12     SPACE eurjchem-221 79 13 resulted result VERB eurjchem-221 79 14     SPACE eurjchem-221 79 15 in in ADP eurjchem-221 79 16     SPACE eurjchem-221 79 17 lowering lower VERB eurjchem-221 79 18     SPACE eurjchem-221 79 19 the the DET eurjchem-221 79 20     SPACE eurjchem-221 79 21 yield yield NOUN eurjchem-221 79 22     SPACE eurjchem-221 79 23 of of ADP eurjchem-221 79 24     SPACE eurjchem-221 79 25 binol binol ADJ eurjchem-221 79 26 , , PUNCT eurjchem-221 79 27     SPACE eurjchem-221 79 28 probably probably ADV eurjchem-221 79 29     SPACE eurjchem-221 79 30 due due ADJ eurjchem-221 79 31     SPACE eurjchem-221 79 32 to to PART eurjchem-221 79 33     SPACE eurjchem-221 79 34 binol binol VERB eurjchem-221 79 35     SPACE eurjchem-221 79 36 undergoing undergo VERB eurjchem-221 79 37     SPACE eurjchem-221 79 38 oxidation oxidation NOUN eurjchem-221 79 39 . . PUNCT eurjchem-221 79 40     SPACE eurjchem-221 80 1 lowering lower VERB eurjchem-221 80 2     SPACE eurjchem-221 80 3 the the DET eurjchem-221 80 4     SPACE eurjchem-221 80 5 amount amount NOUN eurjchem-221 80 6     SPACE eurjchem-221 80 7 of of ADP eurjchem-221 80 8     SPACE eurjchem-221 80 9 catalyst catalyst NOUN eurjchem-221 80 10     SPACE eurjchem-221 80 11 resulted result VERB eurjchem-221 80 12     SPACE eurjchem-221 80 13 in in ADP eurjchem-221 80 14     SPACE eurjchem-221 80 15 lowering lower VERB eurjchem-221 80 16     SPACE eurjchem-221 80 17 the the DET eurjchem-221 80 18     SPACE eurjchem-221 80 19 conversion conversion NOUN eurjchem-221 80 20     SPACE eurjchem-221 80 21 of of ADP eurjchem-221 80 22                       SPACE eurjchem-221 80 23 2‐naphthol 2‐naphthol NOUN eurjchem-221 80 24 . . PUNCT eurjchem-221 80 25     SPACE eurjchem-221 80 26 the the DET eurjchem-221 80 27     SPACE eurjchem-221 80 28 effect effect NOUN eurjchem-221 80 29     SPACE eurjchem-221 80 30 of of ADP eurjchem-221 80 31     SPACE eurjchem-221 80 32 the the DET eurjchem-221 80 33     SPACE eurjchem-221 80 34 amount amount NOUN eurjchem-221 80 35     SPACE eurjchem-221 80 36 of of ADP eurjchem-221 80 37     SPACE eurjchem-221 80 38 catalyst catalyst NOUN eurjchem-221 80 39     SPACE eurjchem-221 80 40 used use VERB eurjchem-221 80 41     SPACE eurjchem-221 80 42 on on ADP eurjchem-221 80 43     SPACE eurjchem-221 80 44 the the DET eurjchem-221 80 45     SPACE eurjchem-221 80 46 reaction reaction NOUN eurjchem-221 80 47     SPACE eurjchem-221 80 48 is be AUX eurjchem-221 80 49     SPACE eurjchem-221 80 50 presented present VERB eurjchem-221 80 51     SPACE eurjchem-221 80 52 in in ADP eurjchem-221 80 53     SPACE eurjchem-221 80 54 table table NOUN eurjchem-221 80 55     SPACE eurjchem-221 80 56 2 2 NUM eurjchem-221 80 57 . . PUNCT eurjchem-221 80 58     SPACE eurjchem-221 80 59 increasing increase VERB eurjchem-221 80 60     SPACE eurjchem-221 80 61 the the DET eurjchem-221 80 62     SPACE eurjchem-221 80 63 amount amount NOUN eurjchem-221 80 64     SPACE eurjchem-221 80 65 of of ADP eurjchem-221 80 66     SPACE eurjchem-221 80 67 catalyst catalyst NOUN eurjchem-221 80 68     SPACE eurjchem-221 80 69 decreased decrease VERB eurjchem-221 80 70     SPACE eurjchem-221 80 71 the the DET eurjchem-221 80 72     SPACE eurjchem-221 80 73 yield yield NOUN eurjchem-221 80 74     SPACE eurjchem-221 80 75 of of ADP eurjchem-221 80 76     SPACE eurjchem-221 80 77 the the DET eurjchem-221 80 78     SPACE eurjchem-221 80 79 desired desire VERB eurjchem-221 80 80     SPACE eurjchem-221 80 81 product product NOUN eurjchem-221 80 82     SPACE eurjchem-221 80 83 ( ( PUNCT eurjchem-221 80 84 c c NOUN eurjchem-221 80 85 ) ) PUNCT eurjchem-221 80 86     SPACE eurjchem-221 80 87 with with ADP eurjchem-221 80 88     SPACE eurjchem-221 80 89 more more ADJ eurjchem-221 80 90     SPACE eurjchem-221 80 91 byproducts byproduct NOUN eurjchem-221 80 92 . . PUNCT eurjchem-221 80 93     SPACE eurjchem-221 80 94 therefore therefore ADV eurjchem-221 80 95 , , PUNCT eurjchem-221 80 96     SPACE eurjchem-221 80 97 the the DET eurjchem-221 80 98     SPACE eurjchem-221 80 99 reaction reaction NOUN eurjchem-221 80 100     SPACE eurjchem-221 80 101 was be AUX eurjchem-221 80 102     SPACE eurjchem-221 80 103 performed perform VERB eurjchem-221 80 104     SPACE eurjchem-221 80 105 with with ADP eurjchem-221 80 106     SPACE eurjchem-221 80 107 2 2 NUM eurjchem-221 80 108     SPACE eurjchem-221 80 109 mol% mol% NOUN eurjchem-221 80 110     SPACE eurjchem-221 80 111 of of ADP eurjchem-221 80 112     SPACE eurjchem-221 80 113 the the DET eurjchem-221 80 114     SPACE eurjchem-221 80 115 catalyst catalyst NOUN eurjchem-221 80 116     SPACE eurjchem-221 80 117 4­6 4­6 NUM eurjchem-221 80 118 . . PUNCT eurjchem-221 80 119     SPACE eurjchem-221 80 120 among among ADP eurjchem-221 80 121     SPACE eurjchem-221 80 122 all all PRON eurjchem-221 80 123     SPACE eurjchem-221 80 124 the the DET eurjchem-221 80 125     SPACE eurjchem-221 80 126 complexes complex NOUN eurjchem-221 80 127 , , PUNCT eurjchem-221 80 128     SPACE eurjchem-221 80 129 2 2 NUM eurjchem-221 80 130     SPACE eurjchem-221 80 131 showed show VERB eurjchem-221 80 132     SPACE eurjchem-221 80 133 good good ADJ eurjchem-221 80 134     SPACE eurjchem-221 80 135 conversion conversion NOUN eurjchem-221 80 136     SPACE eurjchem-221 80 137 of of ADP eurjchem-221 80 138     SPACE eurjchem-221 80 139 the the DET eurjchem-221 80 140     SPACE eurjchem-221 80 141 reactant reactant NOUN eurjchem-221 80 142     SPACE eurjchem-221 80 143 ( ( PUNCT eurjchem-221 80 144 a a NOUN eurjchem-221 80 145 ) ) PUNCT eurjchem-221 80 146     SPACE eurjchem-221 80 147 to to ADP eurjchem-221 80 148     SPACE eurjchem-221 80 149 ( ( PUNCT eurjchem-221 80 150 c c NOUN eurjchem-221 80 151 ) ) PUNCT eurjchem-221 80 152 . . PUNCT eurjchem-221 80 153     SPACE eurjchem-221 81 1 catalyst catalyst NOUN eurjchem-221 81 2     SPACE eurjchem-221 81 3 3 3 NUM eurjchem-221 81 4     SPACE eurjchem-221 81 5 was be AUX eurjchem-221 81 6     SPACE eurjchem-221 81 7 less less ADJ eurjchem-221 81 8     SPACE eurjchem-221 81 9 effective effective ADJ eurjchem-221 81 10     SPACE eurjchem-221 81 11 in in ADP eurjchem-221 81 12     SPACE eurjchem-221 81 13 converting convert VERB eurjchem-221 81 14     SPACE eurjchem-221 81 15 ( ( PUNCT eurjchem-221 81 16 a a NOUN eurjchem-221 81 17 ) ) PUNCT eurjchem-221 81 18     SPACE eurjchem-221 81 19 to to ADP eurjchem-221 81 20     SPACE eurjchem-221 81 21 ( ( PUNCT eurjchem-221 81 22 c c NOUN eurjchem-221 81 23 ) ) PUNCT eurjchem-221 81 24 . . PUNCT eurjchem-221 81 25     SPACE eurjchem-221 82 1 a a DET eurjchem-221 82 2     SPACE eurjchem-221 82 3 blank blank ADJ eurjchem-221 82 4     SPACE eurjchem-221 82 5 experiment experiment NOUN eurjchem-221 82 6     SPACE eurjchem-221 82 7 carried carry VERB eurjchem-221 82 8     SPACE eurjchem-221 82 9 out out ADP eurjchem-221 82 10     SPACE eurjchem-221 82 11 without without ADP eurjchem-221 82 12     SPACE eurjchem-221 82 13 the the DET eurjchem-221 82 14     SPACE eurjchem-221 82 15 catalyst catalyst NOUN eurjchem-221 82 16     SPACE eurjchem-221 82 17 under under ADP eurjchem-221 82 18     SPACE eurjchem-221 82 19 identical identical ADJ eurjchem-221 82 20     SPACE eurjchem-221 82 21 experimental experimental ADJ eurjchem-221 82 22     SPACE eurjchem-221 82 23 conditions condition NOUN eurjchem-221 82 24     SPACE eurjchem-221 82 25 did do AUX eurjchem-221 82 26     SPACE eurjchem-221 82 27 not not PART eurjchem-221 82 28     SPACE eurjchem-221 82 29 produce produce VERB eurjchem-221 82 30     SPACE eurjchem-221 82 31 binol binol ADJ eurjchem-221 82 32     SPACE eurjchem-221 82 33 indicating indicate VERB eurjchem-221 82 34     SPACE eurjchem-221 82 35 the the DET eurjchem-221 82 36     SPACE eurjchem-221 82 37 participation participation NOUN eurjchem-221 82 38     SPACE eurjchem-221 82 39 of of ADP eurjchem-221 82 40     SPACE eurjchem-221 82 41 the the DET eurjchem-221 82 42     SPACE eurjchem-221 82 43 copper copper NOUN eurjchem-221 82 44     SPACE eurjchem-221 82 45 complex complex NOUN eurjchem-221 82 46     SPACE eurjchem-221 82 47 in in ADP eurjchem-221 82 48     SPACE eurjchem-221 82 49 the the DET eurjchem-221 82 50     SPACE eurjchem-221 82 51 reaction reaction NOUN eurjchem-221 82 52     SPACE eurjchem-221 82 53 path path NOUN eurjchem-221 82 54 . . PUNCT eurjchem-221 82 55     SPACE eurjchem-221 83 1 the the DET eurjchem-221 83 2     SPACE eurjchem-221 83 3 use use NOUN eurjchem-221 83 4     SPACE eurjchem-221 83 5 of of ADP eurjchem-221 83 6     SPACE eurjchem-221 83 7 stoichiometric stoichiometric NOUN eurjchem-221 83 8     SPACE eurjchem-221 83 9 amount amount NOUN eurjchem-221 83 10     SPACE eurjchem-221 83 11 of of ADP eurjchem-221 83 12     SPACE eurjchem-221 83 13 complex complex NOUN eurjchem-221 83 14     SPACE eurjchem-221 83 15 2 2 NUM eurjchem-221 83 16     SPACE eurjchem-221 83 17 as as ADP eurjchem-221 83 18     SPACE eurjchem-221 83 19 oxidizing oxidize VERB eurjchem-221 83 20     SPACE eurjchem-221 83 21 agent agent NOUN eurjchem-221 83 22     SPACE eurjchem-221 83 23 under under ADP eurjchem-221 83 24     SPACE eurjchem-221 83 25 nitrogen nitrogen NOUN eurjchem-221 83 26     SPACE eurjchem-221 83 27 atmosphere atmosphere NOUN eurjchem-221 83 28     SPACE eurjchem-221 83 29 did do AUX eurjchem-221 83 30     SPACE eurjchem-221 83 31 not not PART eurjchem-221 83 32     SPACE eurjchem-221 83 33 yield yield VERB eurjchem-221 83 34     SPACE eurjchem-221 83 35 the the DET eurjchem-221 83 36     SPACE eurjchem-221 83 37 product product NOUN eurjchem-221 83 38     SPACE eurjchem-221 83 39 indicating indicate VERB eurjchem-221 83 40     SPACE eurjchem-221 83 41 that that SCONJ eurjchem-221 83 42     SPACE eurjchem-221 83 43 oxygen oxygen NOUN eurjchem-221 83 44     SPACE eurjchem-221 83 45 is be AUX eurjchem-221 83 46     SPACE eurjchem-221 83 47 essential essential ADJ eurjchem-221 83 48     SPACE eurjchem-221 83 49 for for ADP eurjchem-221 83 50     SPACE eurjchem-221 83 51 the the DET eurjchem-221 83 52     SPACE eurjchem-221 83 53 reaction reaction NOUN eurjchem-221 83 54 . . PUNCT eurjchem-221 83 55     SPACE eurjchem-221 84 1 all all DET eurjchem-221 84 2     SPACE eurjchem-221 84 3 reactions reaction NOUN eurjchem-221 84 4     SPACE eurjchem-221 84 5 were be AUX eurjchem-221 84 6     SPACE eurjchem-221 84 7 continued continue VERB eurjchem-221 84 8     SPACE eurjchem-221 84 9 for for ADP eurjchem-221 84 10     SPACE eurjchem-221 84 11 two two NUM eurjchem-221 84 12     SPACE eurjchem-221 84 13 days day NOUN eurjchem-221 84 14     SPACE eurjchem-221 84 15 and and CCONJ eurjchem-221 84 16     SPACE eurjchem-221 84 17 the the DET eurjchem-221 84 18     SPACE eurjchem-221 84 19 desired desire VERB eurjchem-221 84 20     SPACE eurjchem-221 84 21 product product NOUN eurjchem-221 84 22     SPACE eurjchem-221 84 23 was be AUX eurjchem-221 84 24     SPACE eurjchem-221 84 25 isolated isolate VERB eurjchem-221 84 26     SPACE eurjchem-221 84 27 by by ADP eurjchem-221 84 28     SPACE eurjchem-221 84 29 column column NOUN eurjchem-221 84 30     SPACE eurjchem-221 84 31 chromatography chromatography NOUN eurjchem-221 84 32 . . PUNCT eurjchem-221 84 33     SPACE eurjchem-221 85 1 the the DET eurjchem-221 85 2     SPACE eurjchem-221 85 3 efficacy efficacy NOUN eurjchem-221 85 4     SPACE eurjchem-221 85 5 of of ADP eurjchem-221 85 6     SPACE eurjchem-221 85 7 the the DET eurjchem-221 85 8     SPACE eurjchem-221 85 9 catalyst catalyst NOUN eurjchem-221 85 10     SPACE eurjchem-221 85 11 1­3 1­3 NUM eurjchem-221 85 12     SPACE eurjchem-221 85 13 was be AUX eurjchem-221 85 14     SPACE eurjchem-221 85 15 also also ADV eurjchem-221 85 16     SPACE eurjchem-221 85 17 tested test VERB eurjchem-221 85 18     SPACE eurjchem-221 85 19 for for ADP eurjchem-221 85 20     SPACE eurjchem-221 85 21 reaction reaction NOUN eurjchem-221 85 22     SPACE eurjchem-221 85 23 with with ADP eurjchem-221 85 24     SPACE eurjchem-221 85 25 ( ( PUNCT eurjchem-221 85 26 b b NOUN eurjchem-221 85 27 ) ) PUNCT eurjchem-221 85 28     SPACE eurjchem-221 85 29 and and CCONJ eurjchem-221 85 30     SPACE eurjchem-221 85 31 in in ADP eurjchem-221 85 32     SPACE eurjchem-221 85 33 cross cross ADJ eurjchem-221 85 34     SPACE eurjchem-221 85 35 coupling coupling NOUN eurjchem-221 85 36     SPACE eurjchem-221 85 37 reaction reaction NOUN eurjchem-221 85 38     SPACE eurjchem-221 85 39 between between ADP eurjchem-221 85 40     SPACE eurjchem-221 85 41 a a PRON eurjchem-221 85 42     SPACE eurjchem-221 85 43 and and CCONJ eurjchem-221 85 44     SPACE eurjchem-221 85 45 b b NOUN eurjchem-221 85 46     SPACE eurjchem-221 85 47 ( ( PUNCT eurjchem-221 85 48 table table NOUN eurjchem-221 85 49     SPACE eurjchem-221 85 50 3 3 NUM eurjchem-221 85 51     SPACE eurjchem-221 85 52 and and CCONJ eurjchem-221 85 53     SPACE eurjchem-221 85 54 4 4 NUM eurjchem-221 85 55 ) ) PUNCT eurjchem-221 85 56 . . PUNCT eurjchem-221 85 57                   SPACE eurjchem-221 86 1 figure figure NOUN eurjchem-221 86 2     SPACE eurjchem-221 86 3 2 2 NUM eurjchem-221 86 4 . . PUNCT eurjchem-221 86 5 solution solution NOUN eurjchem-221 86 6     SPACE eurjchem-221 86 7 epr epr PROPN eurjchem-221 86 8     SPACE eurjchem-221 86 9 spectra spectra NOUN eurjchem-221 86 10     SPACE eurjchem-221 86 11 of of ADP eurjchem-221 86 12     SPACE eurjchem-221 86 13 chiral chiral ADJ eurjchem-221 86 14     SPACE eurjchem-221 86 15 complexes complex NOUN eurjchem-221 86 16     SPACE eurjchem-221 86 17 in in ADP eurjchem-221 86 18     SPACE eurjchem-221 86 19 lnt lnt NOUN eurjchem-221 86 20 . . PUNCT eurjchem-221 86 21         SPACE eurjchem-221 86 22 sabarinathan sabarinathan PROPN eurjchem-221 86 23     SPACE eurjchem-221 86 24 et et PROPN eurjchem-221 86 25     SPACE eurjchem-221 86 26 al al PROPN eurjchem-221 86 27 . . PROPN eurjchem-221 86 28     SPACE eurjchem-221 86 29 / / SYM eurjchem-221 86 30     SPACE eurjchem-221 86 31 european european ADJ eurjchem-221 86 32     SPACE eurjchem-221 86 33 journal journal NOUN eurjchem-221 86 34     SPACE eurjchem-221 86 35 of of ADP eurjchem-221 86 36     SPACE eurjchem-221 86 37 chemistry chemistry NOUN eurjchem-221 86 38     SPACE eurjchem-221 86 39 1 1 NUM eurjchem-221 86 40     SPACE eurjchem-221 86 41 ( ( PUNCT eurjchem-221 86 42 4 4 NUM eurjchem-221 86 43 ) ) PUNCT eurjchem-221 86 44     SPACE eurjchem-221 86 45 ( ( PUNCT eurjchem-221 86 46 2010 2010 NUM eurjchem-221 86 47 ) ) PUNCT eurjchem-221 86 48     SPACE eurjchem-221 87 1 360­367 360­367 NUM eurjchem-221 87 2     SPACE eurjchem-221 87 3 363 363 NUM eurjchem-221 87 4     SPACE eurjchem-221 87 5 table table NOUN eurjchem-221 87 6     SPACE eurjchem-221 87 7 1 1 NUM eurjchem-221 87 8 . . PUNCT eurjchem-221 87 9     SPACE eurjchem-221 87 10 epr epr PROPN eurjchem-221 87 11     SPACE eurjchem-221 87 12 spectral spectral ADJ eurjchem-221 87 13     SPACE eurjchem-221 87 14 data datum NOUN eurjchem-221 87 15     SPACE eurjchem-221 87 16 for for ADP eurjchem-221 87 17     SPACE eurjchem-221 87 18 the the DET eurjchem-221 87 19     SPACE eurjchem-221 87 20 salen salen PROPN eurjchem-221 87 21     SPACE eurjchem-221 87 22 copper copper NOUN eurjchem-221 87 23     SPACE eurjchem-221 87 24 complexes complex NOUN eurjchem-221 87 25 . . PUNCT eurjchem-221 87 26     SPACE eurjchem-221 87 27 entry entry NOUN eurjchem-221 87 28     SPACE eurjchem-221 87 29 complex complex NOUN eurjchem-221 87 30     SPACE eurjchem-221 87 31 recorded recorded ADJ eurjchem-221 87 32     SPACE eurjchem-221 87 33 condition condition NOUN eurjchem-221 87 34     SPACE eurjchem-221 87 35 gll gll NOUN eurjchem-221 87 36     SPACE eurjchem-221 87 37 g g PROPN eurjchem-221 87 38     SPACE eurjchem-221 87 39 all all DET eurjchem-221 87 40     SPACE eurjchem-221 87 41 mt mt PROPN eurjchem-221 87 42     SPACE eurjchem-221 87 43 a a PROPN eurjchem-221 87 44     SPACE eurjchem-221 87 45 mt mt PROPN eurjchem-221 87 46     SPACE eurjchem-221 87 47 1 1 NUM eurjchem-221 87 48     SPACE eurjchem-221 87 49 1 1 NUM eurjchem-221 87 50     SPACE eurjchem-221 87 51 rt rt NOUN eurjchem-221 87 52     SPACE eurjchem-221 87 53 powder powder NOUN eurjchem-221 87 54 2.13 2.13 NUM eurjchem-221 87 55 2.06 2.06 NUM eurjchem-221 87 56 ‐ ‐ NOUN eurjchem-221 87 57     SPACE eurjchem-221 87 58 ‐ ‐ NOUN eurjchem-221 87 59     SPACE eurjchem-221 87 60 solution solution NOUN eurjchem-221 87 61 2.10 2.10 NUM eurjchem-221 87 62 * * SYM eurjchem-221 87 63 ‐ ‐ ADV eurjchem-221 87 64 8.94 8.94 NUM eurjchem-221 87 65 * * SYM eurjchem-221 87 66     SPACE eurjchem-221 87 67 ‐ ‐ NOUN eurjchem-221 87 68     SPACE eurjchem-221 87 69 lnt lnt NOUN eurjchem-221 87 70         SPACE eurjchem-221 87 71 powder powder NOUN eurjchem-221 87 72 2.16 2.16 NUM eurjchem-221 87 73 2.06 2.06 NUM eurjchem-221 87 74 ‐ ‐ NOUN eurjchem-221 87 75     SPACE eurjchem-221 87 76 ‐ ‐ NOUN eurjchem-221 87 77     SPACE eurjchem-221 87 78 solution solution NOUN eurjchem-221 87 79 g1 g1 NOUN eurjchem-221 87 80 = = PROPN eurjchem-221 87 81 2.40 2.40 NUM eurjchem-221 87 82 g3 g3 NOUN eurjchem-221 87 83     SPACE eurjchem-221 87 84 = = NOUN eurjchem-221 87 85 1.95 1.95 NUM eurjchem-221 87 86     SPACE eurjchem-221 87 87 g2 g2 PROPN eurjchem-221 87 88 2.08 2.08 NUM eurjchem-221 87 89 a1=12.65 a1=12.65 NUM eurjchem-221 87 90     SPACE eurjchem-221 87 91 a3=10.75 a3=10.75 NOUN eurjchem-221 87 92     SPACE eurjchem-221 87 93 a2=2.95 a2=2.95 ADV eurjchem-221 87 94 2 2 NUM eurjchem-221 87 95     SPACE eurjchem-221 87 96 2 2 NUM eurjchem-221 87 97     SPACE eurjchem-221 87 98 rt rt NOUN eurjchem-221 87 99     SPACE eurjchem-221 87 100 powder powder NOUN eurjchem-221 87 101 2.18 2.18 NUM eurjchem-221 87 102 2.06 2.06 NUM eurjchem-221 87 103 ‐ ‐ NOUN eurjchem-221 87 104     SPACE eurjchem-221 87 105 ‐ ‐ NOUN eurjchem-221 87 106     SPACE eurjchem-221 87 107 solution solution NOUN eurjchem-221 87 108 2.09 2.09 NUM eurjchem-221 87 109 * * PUNCT eurjchem-221 87 110 ‐ ‐ ADP eurjchem-221 87 111 8.66 8.66 NUM eurjchem-221 87 112 * * SYM eurjchem-221 87 113     SPACE eurjchem-221 87 114 ‐ ‐ NOUN eurjchem-221 87 115     SPACE eurjchem-221 87 116 lnt lnt NOUN eurjchem-221 87 117         SPACE eurjchem-221 87 118 powder powder NOUN eurjchem-221 87 119 2.18 2.18 NUM eurjchem-221 87 120 2.05 2.05 NUM eurjchem-221 87 121 ‐ ‐ NOUN eurjchem-221 87 122     SPACE eurjchem-221 87 123 ‐ ‐ NOUN eurjchem-221 87 124     SPACE eurjchem-221 87 125 center center NOUN eurjchem-221 87 126     SPACE eurjchem-221 87 127 1b 1b NOUN eurjchem-221 87 128 2.26 2.26 NUM eurjchem-221 87 129 2.09 2.09 NUM eurjchem-221 87 130 24.43 24.43 NUM eurjchem-221 87 131     SPACE eurjchem-221 87 132 4.14 4.14 NUM eurjchem-221 87 133 center center NOUN eurjchem-221 87 134     SPACE eurjchem-221 87 135 2b 2b NUM eurjchem-221 87 136 2.20 2.20 NUM eurjchem-221 87 137 2.00 2.00 NUM eurjchem-221 87 138 19.88 19.88 NUM eurjchem-221 87 139     SPACE eurjchem-221 87 140 2.28 2.28 NUM eurjchem-221 87 141 3 3 NUM eurjchem-221 87 142     SPACE eurjchem-221 87 143 3 3 NUM eurjchem-221 87 144     SPACE eurjchem-221 87 145 rt rt NOUN eurjchem-221 87 146     SPACE eurjchem-221 87 147 powder powder NOUN eurjchem-221 87 148 2.07 2.07 NUM eurjchem-221 87 149 * * NUM eurjchem-221 87 150 ‐ ‐ NOUN eurjchem-221 87 151 ‐ ‐ NOUN eurjchem-221 87 152     SPACE eurjchem-221 87 153 ‐ ‐ NOUN eurjchem-221 87 154     SPACE eurjchem-221 87 155 solution solution NOUN eurjchem-221 87 156 2.10 2.10 NUM eurjchem-221 87 157 * * PUNCT eurjchem-221 87 158 ‐ ‐ VERB eurjchem-221 87 159 8.93 8.93 NUM eurjchem-221 87 160 * * SYM eurjchem-221 87 161     SPACE eurjchem-221 87 162 ‐ ‐ NOUN eurjchem-221 87 163     SPACE eurjchem-221 87 164 lnt lnt NOUN eurjchem-221 87 165     SPACE eurjchem-221 87 166 powder powder NOUN eurjchem-221 87 167 2.08 2.08 NUM eurjchem-221 87 168 * * NUM eurjchem-221 87 169 ‐ ‐ NOUN eurjchem-221 87 170 ‐ ‐ NOUN eurjchem-221 87 171     SPACE eurjchem-221 87 172 ‐ ‐ NOUN eurjchem-221 87 173     SPACE eurjchem-221 87 174 solution solution NOUN eurjchem-221 87 175 g1 g1 NOUN eurjchem-221 87 176 = = PROPN eurjchem-221 87 177 2.40 2.40 NUM eurjchem-221 87 178 g3 g3 NOUN eurjchem-221 87 179     SPACE eurjchem-221 87 180 = = NOUN eurjchem-221 87 181 1.95 1.95 NUM eurjchem-221 87 182     SPACE eurjchem-221 87 183 g2= g2= NOUN eurjchem-221 87 184     SPACE eurjchem-221 87 185 2.06 2.06 NUM eurjchem-221 87 186 a1=11.95 a1=11.95 ADP eurjchem-221 87 187     SPACE eurjchem-221 87 188 a3=10.06 a3=10.06 NOUN eurjchem-221 87 189     SPACE eurjchem-221 87 190 a2=2.94 a2=2.94 NUM eurjchem-221 87 191 4 4 NUM eurjchem-221 87 192     SPACE eurjchem-221 87 193 4 4 NUM eurjchem-221 87 194     SPACE eurjchem-221 87 195 rt rt NOUN eurjchem-221 87 196     SPACE eurjchem-221 87 197 powder powder NOUN eurjchem-221 87 198 2.09 2.09 NUM eurjchem-221 87 199 * * NOUN eurjchem-221 87 200 ‐ ‐ NOUN eurjchem-221 87 201 ‐ ‐ NOUN eurjchem-221 87 202     SPACE eurjchem-221 87 203 ‐ ‐ NOUN eurjchem-221 87 204     SPACE eurjchem-221 87 205 solution solution NOUN eurjchem-221 87 206 2.10 2.10 NUM eurjchem-221 87 207 * * NOUN eurjchem-221 87 208 ‐ ‐ VERB eurjchem-221 87 209 10.46 10.46 NUM eurjchem-221 87 210 * * SYM eurjchem-221 87 211     SPACE eurjchem-221 87 212 ‐ ‐ NOUN eurjchem-221 87 213     SPACE eurjchem-221 87 214 lnt lnt NOUN eurjchem-221 87 215     SPACE eurjchem-221 87 216 powder powder NOUN eurjchem-221 87 217 2.41 2.41 NUM eurjchem-221 87 218 2.09 2.09 NUM eurjchem-221 87 219 11.91 11.91 NUM eurjchem-221 87 220     SPACE eurjchem-221 87 221 ‐ ‐ NOUN eurjchem-221 87 222     SPACE eurjchem-221 87 223 solution solution NOUN eurjchem-221 87 224 g1 g1 NOUN eurjchem-221 87 225 = = PROPN eurjchem-221 87 226 2.41 2.41 NUM eurjchem-221 87 227 g3 g3 NOUN eurjchem-221 87 228     SPACE eurjchem-221 87 229 = = NOUN eurjchem-221 87 230 1.95 1.95 NUM eurjchem-221 87 231     SPACE eurjchem-221 87 232 g2 g2 PROPN eurjchem-221 87 233 2.08 2.08 NUM eurjchem-221 87 234 a1=12.33 a1=12.33 NOUN eurjchem-221 87 235     SPACE eurjchem-221 87 236 a2=10.66 a2=10.66 NOUN eurjchem-221 87 237     SPACE eurjchem-221 87 238 a2=3.34 a2=3.34 NOUN eurjchem-221 87 239 5 5 NUM eurjchem-221 87 240     SPACE eurjchem-221 87 241 5 5 NUM eurjchem-221 87 242     SPACE eurjchem-221 87 243 rt rt PROPN eurjchem-221 87 244 center center NOUN eurjchem-221 87 245     SPACE eurjchem-221 87 246 1a 1a PROPN eurjchem-221 87 247 2.29 2.29 NUM eurjchem-221 87 248 2.09 2.09 NUM eurjchem-221 87 249 17.89 17.89 NUM eurjchem-221 87 250     SPACE eurjchem-221 87 251 2.77 2.77 NUM eurjchem-221 87 252 center center NOUN eurjchem-221 87 253     SPACE eurjchem-221 87 254 2a 2a NUM eurjchem-221 87 255 2.22 2.22 NUM eurjchem-221 87 256 2.01 2.01 NUM eurjchem-221 87 257 17.25 17.25 NUM eurjchem-221 87 258     SPACE eurjchem-221 87 259 2.77 2.77 NUM eurjchem-221 87 260 solution solution NOUN eurjchem-221 87 261 2.08 2.08 NUM eurjchem-221 87 262 * * PUNCT eurjchem-221 87 263 ‐ ‐ VERB eurjchem-221 87 264 8.41 8.41 NUM eurjchem-221 87 265 * * PUNCT eurjchem-221 87 266     SPACE eurjchem-221 87 267 ‐ ‐ NOUN eurjchem-221 87 268     SPACE eurjchem-221 87 269 lnt lnt NOUN eurjchem-221 87 270     SPACE eurjchem-221 87 271 center center NOUN eurjchem-221 87 272     SPACE eurjchem-221 87 273 1a 1a PROPN eurjchem-221 87 274 2.27 2.27 NUM eurjchem-221 87 275 2.07 2.07 NUM eurjchem-221 87 276 17.03 17.03 NUM eurjchem-221 87 277     SPACE eurjchem-221 87 278 3.36 3.36 NUM eurjchem-221 87 279 center center NOUN eurjchem-221 87 280     SPACE eurjchem-221 87 281 2a 2a NUM eurjchem-221 87 282 2.22 2.22 NUM eurjchem-221 87 283 2.01 2.01 NUM eurjchem-221 87 284 16.61 16.61 NUM eurjchem-221 87 285     SPACE eurjchem-221 87 286 3.58 3.58 NUM eurjchem-221 87 287 center center NOUN eurjchem-221 87 288     SPACE eurjchem-221 87 289 1b 1b NUM eurjchem-221 87 290 2.28 2.28 NUM eurjchem-221 87 291 2.07 2.07 NUM eurjchem-221 87 292 22.01 22.01 NUM eurjchem-221 87 293     SPACE eurjchem-221 87 294 3.81 3.81 NUM eurjchem-221 87 295 center center NOUN eurjchem-221 87 296     SPACE eurjchem-221 87 297 2b 2b NOUN eurjchem-221 87 298 2.21 2.21 NUM eurjchem-221 87 299 1.99 1.99 NUM eurjchem-221 87 300 19.68 19.68 NUM eurjchem-221 87 301     SPACE eurjchem-221 87 302 1.27 1.27 NUM eurjchem-221 87 303 6 6 NUM eurjchem-221 87 304     SPACE eurjchem-221 87 305 6 6 NUM eurjchem-221 87 306     SPACE eurjchem-221 87 307 rt rt PROPN eurjchem-221 87 308     SPACE eurjchem-221 87 309 powder powder NOUN eurjchem-221 87 310 2.07 2.07 NUM eurjchem-221 87 311 ‐ ‐ NOUN eurjchem-221 87 312 ‐ ‐ NOUN eurjchem-221 87 313     SPACE eurjchem-221 87 314 ‐ ‐ NOUN eurjchem-221 87 315     SPACE eurjchem-221 87 316 solution solution NOUN eurjchem-221 87 317 2.10 2.10 NUM eurjchem-221 87 318 * * PUNCT eurjchem-221 87 319 ‐ ‐ VERB eurjchem-221 87 320 8.93 8.93 NUM eurjchem-221 87 321 * * SYM eurjchem-221 87 322     SPACE eurjchem-221 87 323 ‐ ‐ NOUN eurjchem-221 87 324     SPACE eurjchem-221 87 325 lnt lnt NOUN eurjchem-221 87 326     SPACE eurjchem-221 87 327 powder powder NOUN eurjchem-221 87 328 2.08 2.08 NUM eurjchem-221 87 329 * * NUM eurjchem-221 87 330 ‐ ‐ NOUN eurjchem-221 87 331 ‐ ‐ NOUN eurjchem-221 87 332     SPACE eurjchem-221 87 333 ‐ ‐ NOUN eurjchem-221 87 334     SPACE eurjchem-221 87 335 solution solution NOUN eurjchem-221 87 336 g1 g1 NOUN eurjchem-221 87 337 = = PROPN eurjchem-221 87 338 2.40 2.40 NUM eurjchem-221 87 339 g3 g3 NOUN eurjchem-221 87 340     SPACE eurjchem-221 87 341 = = NOUN eurjchem-221 87 342 1.95 1.95 NUM eurjchem-221 87 343     SPACE eurjchem-221 87 344 g2= g2= NOUN eurjchem-221 87 345     SPACE eurjchem-221 87 346 2.08 2.08 NUM eurjchem-221 87 347 a1=12.45 a1=12.45 NOUN eurjchem-221 87 348     SPACE eurjchem-221 87 349 a3=10.44 a3=10.44 NOUN eurjchem-221 87 350     SPACE eurjchem-221 87 351 a2=2.95 a2=2.95 X eurjchem-221 87 352 * * PUNCT eurjchem-221 87 353     SPACE eurjchem-221 87 354 represents represent VERB eurjchem-221 87 355     SPACE eurjchem-221 87 356 iso iso NOUN eurjchem-221 87 357     SPACE eurjchem-221 87 358 of of ADP eurjchem-221 87 359     SPACE eurjchem-221 87 360 the the DET eurjchem-221 87 361     SPACE eurjchem-221 87 362 parameter parameter NOUN eurjchem-221 87 363 . . PUNCT eurjchem-221 87 364     SPACE eurjchem-221 88 1 a a DET eurjchem-221 88 2     SPACE eurjchem-221 88 3 corresponds correspond NOUN eurjchem-221 88 4     SPACE eurjchem-221 88 5 to to PART eurjchem-221 88 6     SPACE eurjchem-221 88 7 powder powder NOUN eurjchem-221 88 8     SPACE eurjchem-221 88 9 spectrum spectrum NOUN eurjchem-221 88 10 . . PUNCT eurjchem-221 88 11     SPACE eurjchem-221 89 1 b b X eurjchem-221 89 2     SPACE eurjchem-221 89 3 corresponds correspond NOUN eurjchem-221 89 4     SPACE eurjchem-221 89 5 to to PART eurjchem-221 89 6     SPACE eurjchem-221 89 7 lnt lnt NOUN eurjchem-221 89 8     SPACE eurjchem-221 89 9 spectrum spectrum NOUN eurjchem-221 89 10     SPACE eurjchem-221 89 11 of of ADP eurjchem-221 89 12     SPACE eurjchem-221 89 13 solution solution NOUN eurjchem-221 89 14 . . PUNCT eurjchem-221 89 15               SPACE eurjchem-221 89 16 scheme scheme NOUN eurjchem-221 89 17     SPACE eurjchem-221 89 18 1 1 NUM eurjchem-221 89 19               SPACE eurjchem-221 89 20 scheme scheme NOUN eurjchem-221 89 21     SPACE eurjchem-221 89 22 2 2 NUM eurjchem-221 89 23             SPACE eurjchem-221 89 24 scheme scheme NOUN eurjchem-221 89 25     SPACE eurjchem-221 89 26 3 3 NUM eurjchem-221 89 27         SPACE eurjchem-221 89 28 364 364 NUM eurjchem-221 89 29     SPACE eurjchem-221 89 30 sabarinathan sabarinathan PROPN eurjchem-221 89 31     SPACE eurjchem-221 89 32 et et NOUN eurjchem-221 89 33     SPACE eurjchem-221 89 34 al al PROPN eurjchem-221 89 35 . . PROPN eurjchem-221 89 36     SPACE eurjchem-221 89 37 / / SYM eurjchem-221 89 38     SPACE eurjchem-221 89 39 european european ADJ eurjchem-221 89 40     SPACE eurjchem-221 89 41 journal journal NOUN eurjchem-221 89 42     SPACE eurjchem-221 89 43 of of ADP eurjchem-221 89 44     SPACE eurjchem-221 89 45 chemistry chemistry NOUN eurjchem-221 89 46     SPACE eurjchem-221 89 47 1 1 NUM eurjchem-221 89 48     SPACE eurjchem-221 89 49 ( ( PUNCT eurjchem-221 89 50 4 4 NUM eurjchem-221 89 51 ) ) PUNCT eurjchem-221 89 52     SPACE eurjchem-221 89 53 ( ( PUNCT eurjchem-221 89 54 2010 2010 NUM eurjchem-221 89 55 ) ) PUNCT eurjchem-221 89 56     SPACE eurjchem-221 89 57 360­367 360­367 NUM eurjchem-221 89 58         SPACE eurjchem-221 89 59 table table NOUN eurjchem-221 89 60     SPACE eurjchem-221 89 61 2 2 NUM eurjchem-221 89 62 . . PUNCT eurjchem-221 89 63     SPACE eurjchem-221 89 64 aerobic aerobic ADJ eurjchem-221 89 65     SPACE eurjchem-221 89 66 oxidation oxidation NOUN eurjchem-221 89 67     SPACE eurjchem-221 89 68 of of ADP eurjchem-221 89 69     SPACE eurjchem-221 89 70 2‐naphthol 2‐naphthol NOUN eurjchem-221 89 71     SPACE eurjchem-221 89 72 a a DET eurjchem-221 89 73     SPACE eurjchem-221 89 74 with with ADP eurjchem-221 89 75     SPACE eurjchem-221 89 76 catalysts catalyst NOUN eurjchem-221 89 77     SPACE eurjchem-221 89 78 1­6 1­6 NUM eurjchem-221 89 79 . . PUNCT eurjchem-221 89 80     SPACE eurjchem-221 89 81 entry entry NOUN eurjchem-221 89 82     SPACE eurjchem-221 89 83 catalyst catalyst NOUN eurjchem-221 89 84     SPACE eurjchem-221 89 85 amount amount NOUN eurjchem-221 89 86     SPACE eurjchem-221 89 87 of of ADP eurjchem-221 89 88     SPACE eurjchem-221 89 89 catalyst catalyst NOUN eurjchem-221 89 90     SPACE eurjchem-221 89 91 ( ( PUNCT eurjchem-221 89 92 mol mol NOUN eurjchem-221 89 93     SPACE eurjchem-221 89 94 % % NOUN eurjchem-221 89 95 ) ) PUNCT eurjchem-221 89 96     SPACE eurjchem-221 89 97 reaction reaction NOUN eurjchem-221 89 98     SPACE eurjchem-221 89 99 time time NOUN eurjchem-221 89 100     SPACE eurjchem-221 89 101 ( ( PUNCT eurjchem-221 89 102 hr hr NOUN eurjchem-221 89 103 ) ) PUNCT eurjchem-221 89 104     SPACE eurjchem-221 89 105 conversionb conversionb NOUN eurjchem-221 89 106     SPACE eurjchem-221 89 107 ( ( PUNCT eurjchem-221 89 108 % % NOUN eurjchem-221 89 109 ) ) PUNCT eurjchem-221 89 110     SPACE eurjchem-221 89 111 yieldc yieldc PROPN eurjchem-221 89 112     SPACE eurjchem-221 89 113 ( ( PUNCT eurjchem-221 89 114 % % NOUN eurjchem-221 89 115 ) ) PUNCT eurjchem-221 89 116     SPACE eurjchem-221 89 117 1 1 NUM eurjchem-221 89 118     SPACE eurjchem-221 89 119 1 1 NUM eurjchem-221 89 120     SPACE eurjchem-221 89 121 2 2 NUM eurjchem-221 89 122     SPACE eurjchem-221 89 123 48 48 NUM eurjchem-221 89 124 89 89 NUM eurjchem-221 89 125     SPACE eurjchem-221 89 126 34 34 NUM eurjchem-221 89 127 2 2 NUM eurjchem-221 89 128     SPACE eurjchem-221 89 129 2 2 NUM eurjchem-221 89 130     SPACE eurjchem-221 89 131 2 2 NUM eurjchem-221 89 132     SPACE eurjchem-221 89 133 48 48 NUM eurjchem-221 89 134 70 70 NUM eurjchem-221 89 135     SPACE eurjchem-221 89 136 75 75 NUM eurjchem-221 89 137 3 3 NUM eurjchem-221 89 138     SPACE eurjchem-221 89 139 3 3 NUM eurjchem-221 89 140     SPACE eurjchem-221 89 141 2 2 NUM eurjchem-221 89 142     SPACE eurjchem-221 89 143 48 48 NUM eurjchem-221 89 144 100 100 NUM eurjchem-221 89 145     SPACE eurjchem-221 89 146 38 38 NUM eurjchem-221 89 147 4 4 NUM eurjchem-221 89 148     SPACE eurjchem-221 89 149 1 1 NUM eurjchem-221 89 150     SPACE eurjchem-221 89 151 5 5 NUM eurjchem-221 89 152     SPACE eurjchem-221 89 153 48 48 NUM eurjchem-221 89 154 100 100 NUM eurjchem-221 89 155     SPACE eurjchem-221 89 156 27 27 NUM eurjchem-221 89 157 5 5 NUM eurjchem-221 89 158     SPACE eurjchem-221 89 159 2 2 NUM eurjchem-221 89 160     SPACE eurjchem-221 89 161 5 5 NUM eurjchem-221 89 162     SPACE eurjchem-221 89 163 40 40 NUM eurjchem-221 89 164 100 100 NUM eurjchem-221 89 165     SPACE eurjchem-221 89 166 57 57 NUM eurjchem-221 89 167 6 6 NUM eurjchem-221 89 168     SPACE eurjchem-221 89 169 3 3 NUM eurjchem-221 89 170     SPACE eurjchem-221 89 171 5 5 NUM eurjchem-221 89 172     SPACE eurjchem-221 89 173 48 48 NUM eurjchem-221 89 174 100 100 NUM eurjchem-221 89 175     SPACE eurjchem-221 89 176 23 23 NUM eurjchem-221 89 177 7 7 NUM eurjchem-221 89 178     SPACE eurjchem-221 89 179 1 1 NUM eurjchem-221 89 180     SPACE eurjchem-221 89 181 10 10 NUM eurjchem-221 89 182     SPACE eurjchem-221 89 183 20 20 NUM eurjchem-221 89 184 100 100 NUM eurjchem-221 89 185     SPACE eurjchem-221 89 186 0 0 NUM eurjchem-221 89 187 8 8 NUM eurjchem-221 89 188     SPACE eurjchem-221 89 189 2 2 NUM eurjchem-221 89 190     SPACE eurjchem-221 89 191 10 10 NUM eurjchem-221 89 192     SPACE eurjchem-221 89 193 48 48 NUM eurjchem-221 89 194 100 100 NUM eurjchem-221 89 195     SPACE eurjchem-221 89 196 0 0 NUM eurjchem-221 89 197 9 9 NUM eurjchem-221 89 198     SPACE eurjchem-221 89 199 3 3 NUM eurjchem-221 89 200     SPACE eurjchem-221 89 201 10 10 NUM eurjchem-221 89 202     SPACE eurjchem-221 89 203 48 48 NUM eurjchem-221 89 204 100 100 NUM eurjchem-221 89 205     SPACE eurjchem-221 89 206 0 0 NUM eurjchem-221 89 207 10 10 NUM eurjchem-221 89 208     SPACE eurjchem-221 89 209 4 4 NUM eurjchem-221 89 210     SPACE eurjchem-221 89 211 2 2 NUM eurjchem-221 89 212     SPACE eurjchem-221 89 213 48 48 NUM eurjchem-221 89 214 52 52 NUM eurjchem-221 89 215     SPACE eurjchem-221 89 216 35 35 NUM eurjchem-221 89 217 11 11 NUM eurjchem-221 89 218     SPACE eurjchem-221 89 219 5 5 NUM eurjchem-221 89 220     SPACE eurjchem-221 89 221 2 2 NUM eurjchem-221 89 222     SPACE eurjchem-221 89 223 48 48 NUM eurjchem-221 89 224 50 50 NUM eurjchem-221 89 225     SPACE eurjchem-221 89 226 30 30 NUM eurjchem-221 89 227 12 12 NUM eurjchem-221 89 228     SPACE eurjchem-221 89 229 6 6 NUM eurjchem-221 89 230     SPACE eurjchem-221 89 231 2 2 NUM eurjchem-221 89 232     SPACE eurjchem-221 89 233 48 48 NUM eurjchem-221 89 234 53 53 NUM eurjchem-221 89 235     SPACE eurjchem-221 89 236 38 38 NUM eurjchem-221 89 237 a a DET eurjchem-221 89 238     SPACE eurjchem-221 89 239 2‐naphthol 2‐naphthol NUM eurjchem-221 89 240     SPACE eurjchem-221 89 241 ( ( PUNCT eurjchem-221 89 242 3 3 NUM eurjchem-221 89 243     SPACE eurjchem-221 89 244 mmol mmol NOUN eurjchem-221 89 245 ) ) PUNCT eurjchem-221 89 246 , , PUNCT eurjchem-221 89 247     SPACE eurjchem-221 89 248 copper copper NOUN eurjchem-221 89 249     SPACE eurjchem-221 89 250 ( ( PUNCT eurjchem-221 89 251 ii ii NOUN eurjchem-221 89 252 ) ) PUNCT eurjchem-221 89 253     SPACE eurjchem-221 89 254 salen salen PROPN eurjchem-221 89 255     SPACE eurjchem-221 89 256 complexes complex NOUN eurjchem-221 89 257     SPACE eurjchem-221 89 258 ( ( PUNCT eurjchem-221 89 259 2‐10 2‐10 NUM eurjchem-221 89 260     SPACE eurjchem-221 89 261 mol mol NOUN eurjchem-221 89 262     SPACE eurjchem-221 89 263 % % NOUN eurjchem-221 89 264 ) ) PUNCT eurjchem-221 89 265     SPACE eurjchem-221 89 266 in in ADP eurjchem-221 89 267     SPACE eurjchem-221 89 268 chlorobenzene chlorobenzene NOUN eurjchem-221 89 269     SPACE eurjchem-221 89 270 ( ( PUNCT eurjchem-221 89 271 15 15 NUM eurjchem-221 89 272     SPACE eurjchem-221 89 273 ml ml NOUN eurjchem-221 89 274 ) ) PUNCT eurjchem-221 89 275     SPACE eurjchem-221 89 276 at at ADP eurjchem-221 89 277     SPACE eurjchem-221 89 278 reflux reflux NOUN eurjchem-221 89 279     SPACE eurjchem-221 89 280 temperature temperature NOUN eurjchem-221 89 281     SPACE eurjchem-221 89 282 under under ADP eurjchem-221 89 283     SPACE eurjchem-221 89 284 aerobic aerobic ADJ eurjchem-221 89 285     SPACE eurjchem-221 89 286 atmosphere atmosphere NOUN eurjchem-221 89 287 . . PUNCT eurjchem-221 89 288     SPACE eurjchem-221 90 1 b b X eurjchem-221 90 2     SPACE eurjchem-221 90 3 conversion conversion NOUN eurjchem-221 90 4     SPACE eurjchem-221 90 5 refers refer VERB eurjchem-221 90 6     SPACE eurjchem-221 90 7 to to PART eurjchem-221 90 8     SPACE eurjchem-221 90 9 fraction fraction NOUN eurjchem-221 90 10     SPACE eurjchem-221 90 11 of of ADP eurjchem-221 90 12     SPACE eurjchem-221 90 13 starting start VERB eurjchem-221 90 14     SPACE eurjchem-221 90 15 material material NOUN eurjchem-221 90 16     SPACE eurjchem-221 90 17 consumed consume VERB eurjchem-221 90 18     SPACE eurjchem-221 90 19 in in ADP eurjchem-221 90 20     SPACE eurjchem-221 90 21 the the DET eurjchem-221 90 22     SPACE eurjchem-221 90 23 reaction reaction NOUN eurjchem-221 90 24 . . PUNCT eurjchem-221 90 25     SPACE eurjchem-221 91 1 c c NOUN eurjchem-221 91 2     SPACE eurjchem-221 91 3 yield yield NOUN eurjchem-221 91 4     SPACE eurjchem-221 91 5 refers refer VERB eurjchem-221 91 6     SPACE eurjchem-221 91 7 to to PART eurjchem-221 91 8     SPACE eurjchem-221 91 9 fraction fraction NOUN eurjchem-221 91 10     SPACE eurjchem-221 91 11 of of ADP eurjchem-221 91 12     SPACE eurjchem-221 91 13 desired desire VERB eurjchem-221 91 14     SPACE eurjchem-221 91 15 product product NOUN eurjchem-221 91 16     SPACE eurjchem-221 91 17 with with ADP eurjchem-221 91 18     SPACE eurjchem-221 91 19 respect respect NOUN eurjchem-221 91 20     SPACE eurjchem-221 91 21 to to ADP eurjchem-221 91 22     SPACE eurjchem-221 91 23 conversion conversion NOUN eurjchem-221 91 24 . . PUNCT eurjchem-221 91 25         SPACE eurjchem-221 92 1 table table NOUN eurjchem-221 92 2     SPACE eurjchem-221 92 3 3 3 NUM eurjchem-221 92 4     SPACE eurjchem-221 92 5 aerobic aerobic ADJ eurjchem-221 92 6     SPACE eurjchem-221 92 7 oxidative oxidative ADJ eurjchem-221 92 8     SPACE eurjchem-221 92 9 coupling coupling NOUN eurjchem-221 92 10     SPACE eurjchem-221 92 11 of of ADP eurjchem-221 92 12     SPACE eurjchem-221 92 13 methyl‐2‐hydroxy‐3‐naphthoate methyl‐2‐hydroxy‐3‐naphthoate VERB eurjchem-221 92 14     SPACE eurjchem-221 92 15 and and CCONJ eurjchem-221 92 16     SPACE eurjchem-221 92 17 2‐naphthol 2‐naphthol NOUN eurjchem-221 92 18     SPACE eurjchem-221 92 19 using use VERB eurjchem-221 92 20     SPACE eurjchem-221 92 21 2 2 NUM eurjchem-221 92 22     SPACE eurjchem-221 92 23 mol% mol% NOUN eurjchem-221 92 24     SPACE eurjchem-221 92 25 chiral chiral ADJ eurjchem-221 92 26     SPACE eurjchem-221 92 27 salen salen PROPN eurjchem-221 92 28     SPACE eurjchem-221 92 29 catalyst catalyst NOUN eurjchem-221 92 30       SPACE eurjchem-221 92 31 entry entry NOUN eurjchem-221 92 32     SPACE eurjchem-221 92 33 catalyst catalyst NOUN eurjchem-221 92 34     SPACE eurjchem-221 92 35 reaction reaction NOUN eurjchem-221 92 36     SPACE eurjchem-221 92 37 time(hr time(hr NOUN eurjchem-221 92 38 ) ) PUNCT eurjchem-221 92 39     SPACE eurjchem-221 92 40 conversiona conversiona NOUN eurjchem-221 92 41     SPACE eurjchem-221 92 42 ( ( PUNCT eurjchem-221 92 43 % % NOUN eurjchem-221 92 44 ) ) PUNCT eurjchem-221 92 45     SPACE eurjchem-221 92 46 selectivityb selectivityb NOUN eurjchem-221 92 47     SPACE eurjchem-221 92 48 ( ( PUNCT eurjchem-221 92 49 c c X eurjchem-221 92 50 : : PUNCT eurjchem-221 92 51 d d ADJ eurjchem-221 92 52 : : PUNCT eurjchem-221 92 53 e e NOUN eurjchem-221 92 54 ) ) PUNCT eurjchem-221 92 55     SPACE eurjchem-221 92 56 yieldc yieldc PROPN eurjchem-221 92 57     SPACE eurjchem-221 92 58 ( ( PUNCT eurjchem-221 92 59 % % NOUN eurjchem-221 92 60 ) ) PUNCT eurjchem-221 92 61     SPACE eurjchem-221 92 62 1 1 NUM eurjchem-221 92 63     SPACE eurjchem-221 92 64 1 1 NUM eurjchem-221 92 65     SPACE eurjchem-221 92 66 90 90 NUM eurjchem-221 92 67     SPACE eurjchem-221 92 68 61 61 NUM eurjchem-221 92 69 0 0 NUM eurjchem-221 92 70 : : PUNCT eurjchem-221 92 71     SPACE eurjchem-221 92 72 0 0 NOUN eurjchem-221 92 73     SPACE eurjchem-221 92 74 : : PUNCT eurjchem-221 92 75     SPACE eurjchem-221 92 76 100 100 NUM eurjchem-221 92 77     SPACE eurjchem-221 92 78 40 40 NUM eurjchem-221 92 79 2 2 NUM eurjchem-221 92 80     SPACE eurjchem-221 92 81 2 2 NUM eurjchem-221 92 82     SPACE eurjchem-221 92 83 50 50 NUM eurjchem-221 92 84     SPACE eurjchem-221 92 85 51 51 NUM eurjchem-221 92 86 0 0 NUM eurjchem-221 92 87     SPACE eurjchem-221 92 88 : : PUNCT eurjchem-221 92 89     SPACE eurjchem-221 92 90 5.23 5.23 NUM eurjchem-221 92 91 : : PUNCT eurjchem-221 92 92     SPACE eurjchem-221 92 93 94.77 94.77 NUM eurjchem-221 92 94     SPACE eurjchem-221 92 95 89 89 NUM eurjchem-221 92 96 3 3 NUM eurjchem-221 92 97     SPACE eurjchem-221 92 98 3 3 NUM eurjchem-221 92 99     SPACE eurjchem-221 92 100 71 71 NUM eurjchem-221 92 101     SPACE eurjchem-221 92 102 44 44 NUM eurjchem-221 92 103 0 0 NUM eurjchem-221 92 104     SPACE eurjchem-221 92 105 : : PUNCT eurjchem-221 92 106     SPACE eurjchem-221 92 107 19.98 19.98 NUM eurjchem-221 92 108 : : PUNCT eurjchem-221 92 109     SPACE eurjchem-221 92 110 80.02 80.02 NUM eurjchem-221 92 111     SPACE eurjchem-221 92 112 80 80 NUM eurjchem-221 92 113 a a DET eurjchem-221 92 114     SPACE eurjchem-221 92 115 conversion conversion NOUN eurjchem-221 92 116     SPACE eurjchem-221 92 117 refers refer VERB eurjchem-221 92 118     SPACE eurjchem-221 92 119 to to PART eurjchem-221 92 120     SPACE eurjchem-221 92 121 fraction fraction NOUN eurjchem-221 92 122     SPACE eurjchem-221 92 123 of of ADP eurjchem-221 92 124     SPACE eurjchem-221 92 125 starting start VERB eurjchem-221 92 126     SPACE eurjchem-221 92 127 material material NOUN eurjchem-221 92 128     SPACE eurjchem-221 92 129 consumed consume VERB eurjchem-221 92 130     SPACE eurjchem-221 92 131 in in ADP eurjchem-221 92 132     SPACE eurjchem-221 92 133 the the DET eurjchem-221 92 134     SPACE eurjchem-221 92 135 reaction reaction NOUN eurjchem-221 92 136 . . PUNCT eurjchem-221 92 137     SPACE eurjchem-221 93 1 b b X eurjchem-221 93 2     SPACE eurjchem-221 93 3 determined determine VERB eurjchem-221 93 4     SPACE eurjchem-221 93 5 from from ADP eurjchem-221 93 6     SPACE eurjchem-221 93 7 isolated isolate VERB eurjchem-221 93 8     SPACE eurjchem-221 93 9 yields yield NOUN eurjchem-221 93 10 . . PUNCT eurjchem-221 93 11     SPACE eurjchem-221 94 1 c c NOUN eurjchem-221 94 2     SPACE eurjchem-221 94 3 yield yield NOUN eurjchem-221 94 4     SPACE eurjchem-221 94 5 refers refer VERB eurjchem-221 94 6     SPACE eurjchem-221 94 7 to to PART eurjchem-221 94 8     SPACE eurjchem-221 94 9 fraction fraction NOUN eurjchem-221 94 10     SPACE eurjchem-221 94 11 of of ADP eurjchem-221 94 12     SPACE eurjchem-221 94 13 cross cross VERB eurjchem-221 94 14     SPACE eurjchem-221 94 15 coupled couple VERB eurjchem-221 94 16     SPACE eurjchem-221 94 17 product product NOUN eurjchem-221 94 18     SPACE eurjchem-221 94 19 with with ADP eurjchem-221 94 20     SPACE eurjchem-221 94 21 respect respect NOUN eurjchem-221 94 22     SPACE eurjchem-221 94 23 to to ADP eurjchem-221 94 24     SPACE eurjchem-221 94 25 conversion conversion NOUN eurjchem-221 94 26 . . PUNCT eurjchem-221 94 27         SPACE eurjchem-221 95 1 table table NOUN eurjchem-221 95 2     SPACE eurjchem-221 95 3 4 4 NUM eurjchem-221 95 4 . . PUNCT eurjchem-221 95 5     SPACE eurjchem-221 95 6 aerobic aerobic ADJ eurjchem-221 95 7     SPACE eurjchem-221 95 8 oxidative oxidative ADJ eurjchem-221 95 9     SPACE eurjchem-221 95 10 coupling coupling NOUN eurjchem-221 95 11     SPACE eurjchem-221 95 12 of of ADP eurjchem-221 95 13     SPACE eurjchem-221 95 14 methyl‐2‐hydroxy‐3‐naphthoate methyl‐2‐hydroxy‐3‐naphthoate AUX eurjchem-221 95 15     SPACE eurjchem-221 95 16 using use VERB eurjchem-221 95 17     SPACE eurjchem-221 95 18 2 2 NUM eurjchem-221 95 19     SPACE eurjchem-221 95 20 mol% mol% NOUN eurjchem-221 95 21     SPACE eurjchem-221 95 22 chiral chiral ADJ eurjchem-221 95 23     SPACE eurjchem-221 95 24 salen salen PROPN eurjchem-221 95 25     SPACE eurjchem-221 95 26 catalyst catalyst NOUN eurjchem-221 95 27 . . PUNCT eurjchem-221 95 28     SPACE eurjchem-221 95 29 entry entry NOUN eurjchem-221 95 30     SPACE eurjchem-221 95 31 catalyst catalyst NOUN eurjchem-221 95 32       SPACE eurjchem-221 95 33 reaction reaction NOUN eurjchem-221 95 34     SPACE eurjchem-221 95 35 time time NOUN eurjchem-221 95 36     SPACE eurjchem-221 95 37 ( ( PUNCT eurjchem-221 95 38 hr hr NOUN eurjchem-221 95 39 ) ) PUNCT eurjchem-221 95 40     SPACE eurjchem-221 95 41 conversiona conversiona NOUN eurjchem-221 95 42     SPACE eurjchem-221 95 43 ( ( PUNCT eurjchem-221 95 44 % % NOUN eurjchem-221 95 45 ) ) PUNCT eurjchem-221 95 46     SPACE eurjchem-221 95 47 yieldb yieldb NOUN eurjchem-221 95 48     SPACE eurjchem-221 95 49 ( ( PUNCT eurjchem-221 95 50 % % NOUN eurjchem-221 95 51 ) ) PUNCT eurjchem-221 95 52     SPACE eurjchem-221 96 1 r r NOUN eurjchem-221 96 2 : : PUNCT eurjchem-221 96 3 s s NOUN eurjchem-221 96 4     SPACE eurjchem-221 96 5 c c PROPN eurjchem-221 96 6 ( ( PUNCT eurjchem-221 96 7 % % NOUN eurjchem-221 96 8 ) ) PUNCT eurjchem-221 96 9 1 1 NUM eurjchem-221 96 10     SPACE eurjchem-221 96 11 1 1 NUM eurjchem-221 96 12     SPACE eurjchem-221 96 13 48 48 NUM eurjchem-221 96 14     SPACE eurjchem-221 96 15 80 80 NUM eurjchem-221 96 16 55 55 NUM eurjchem-221 96 17     SPACE eurjchem-221 96 18 31:69 31:69 NUM eurjchem-221 96 19 2 2 NUM eurjchem-221 96 20     SPACE eurjchem-221 96 21 2 2 NUM eurjchem-221 96 22     SPACE eurjchem-221 96 23 48 48 NUM eurjchem-221 96 24     SPACE eurjchem-221 96 25 25 25 NUM eurjchem-221 96 26 100 100 NUM eurjchem-221 96 27     SPACE eurjchem-221 96 28 50:50 50:50 NUM eurjchem-221 96 29 3 3 NUM eurjchem-221 96 30     SPACE eurjchem-221 96 31 3 3 NUM eurjchem-221 96 32     SPACE eurjchem-221 96 33 48 48 NUM eurjchem-221 96 34     SPACE eurjchem-221 96 35 58 58 NUM eurjchem-221 96 36 42 42 NUM eurjchem-221 96 37     SPACE eurjchem-221 96 38 50:50 50:50 NUM eurjchem-221 96 39 a a DET eurjchem-221 96 40     SPACE eurjchem-221 96 41 conversion conversion NOUN eurjchem-221 96 42     SPACE eurjchem-221 96 43 refers refer VERB eurjchem-221 96 44     SPACE eurjchem-221 96 45 to to PART eurjchem-221 96 46     SPACE eurjchem-221 96 47 fraction fraction NOUN eurjchem-221 96 48     SPACE eurjchem-221 96 49 of of ADP eurjchem-221 96 50     SPACE eurjchem-221 96 51 starting start VERB eurjchem-221 96 52     SPACE eurjchem-221 96 53 material material NOUN eurjchem-221 96 54     SPACE eurjchem-221 96 55 consumed consume VERB eurjchem-221 96 56     SPACE eurjchem-221 96 57 in in ADP eurjchem-221 96 58     SPACE eurjchem-221 96 59 the the DET eurjchem-221 96 60     SPACE eurjchem-221 96 61 reaction reaction NOUN eurjchem-221 96 62 . . PUNCT eurjchem-221 96 63     SPACE eurjchem-221 97 1 b b X eurjchem-221 97 2     SPACE eurjchem-221 97 3 yield yield NOUN eurjchem-221 97 4     SPACE eurjchem-221 97 5 refers refer VERB eurjchem-221 97 6     SPACE eurjchem-221 97 7 to to PART eurjchem-221 97 8     SPACE eurjchem-221 97 9 fraction fraction NOUN eurjchem-221 97 10     SPACE eurjchem-221 97 11 of of ADP eurjchem-221 97 12     SPACE eurjchem-221 97 13 desired desire VERB eurjchem-221 97 14     SPACE eurjchem-221 97 15 product product NOUN eurjchem-221 97 16     SPACE eurjchem-221 97 17 with with ADP eurjchem-221 97 18     SPACE eurjchem-221 97 19 respect respect NOUN eurjchem-221 97 20     SPACE eurjchem-221 97 21 to to ADP eurjchem-221 97 22     SPACE eurjchem-221 97 23 conversion conversion NOUN eurjchem-221 97 24 . . PUNCT eurjchem-221 97 25     SPACE eurjchem-221 98 1 c c X eurjchem-221 98 2     SPACE eurjchem-221 98 3 determined determine VERB eurjchem-221 98 4     SPACE eurjchem-221 98 5 by by ADP eurjchem-221 98 6     SPACE eurjchem-221 98 7 hplc hplc NOUN eurjchem-221 98 8     SPACE eurjchem-221 98 9 using use VERB eurjchem-221 98 10     SPACE eurjchem-221 98 11 daicel daicel NOUN eurjchem-221 98 12     SPACE eurjchem-221 98 13 chiralpak chiralpak NOUN eurjchem-221 98 14     SPACE eurjchem-221 98 15 ad‐h ad‐h PROPN eurjchem-221 98 16 . . PUNCT eurjchem-221 98 17             SPACE eurjchem-221 98 18 catalyst catalyst NOUN eurjchem-221 98 19     SPACE eurjchem-221 98 20 1 1 NUM eurjchem-221 98 21     SPACE eurjchem-221 98 22 was be AUX eurjchem-221 98 23     SPACE eurjchem-221 98 24 more more ADJ eurjchem-221 98 25     SPACE eurjchem-221 98 26 efficient efficient ADJ eurjchem-221 98 27     SPACE eurjchem-221 98 28 in in ADP eurjchem-221 98 29     SPACE eurjchem-221 98 30 oxidative oxidative ADJ eurjchem-221 98 31     SPACE eurjchem-221 98 32 coupling coupling NOUN eurjchem-221 98 33     SPACE eurjchem-221 98 34 of of ADP eurjchem-221 98 35     SPACE eurjchem-221 98 36 ( ( PUNCT eurjchem-221 98 37 b b NOUN eurjchem-221 98 38 ) ) PUNCT eurjchem-221 98 39 . . PUNCT eurjchem-221 98 40     SPACE eurjchem-221 99 1 cross cross ADJ eurjchem-221 99 2     SPACE eurjchem-221 99 3 coupling couple VERB eurjchem-221 99 4     SPACE eurjchem-221 99 5 reaction reaction NOUN eurjchem-221 99 6     SPACE eurjchem-221 99 7 between between ADP eurjchem-221 99 8     SPACE eurjchem-221 99 9 ( ( PUNCT eurjchem-221 99 10 a a NOUN eurjchem-221 99 11 ) ) PUNCT eurjchem-221 99 12     SPACE eurjchem-221 99 13 and and CCONJ eurjchem-221 99 14     SPACE eurjchem-221 99 15 ( ( PUNCT eurjchem-221 99 16 b b NOUN eurjchem-221 99 17 ) ) PUNCT eurjchem-221 99 18     SPACE eurjchem-221 99 19 under under ADP eurjchem-221 99 20     SPACE eurjchem-221 99 21 similar similar ADJ eurjchem-221 99 22     SPACE eurjchem-221 99 23 conditions condition NOUN eurjchem-221 99 24     SPACE eurjchem-221 99 25 resulted result VERB eurjchem-221 99 26     SPACE eurjchem-221 99 27 in in ADP eurjchem-221 99 28     SPACE eurjchem-221 99 29 cross cross VERB eurjchem-221 99 30     SPACE eurjchem-221 99 31 coupled couple VERB eurjchem-221 99 32     SPACE eurjchem-221 99 33 product product NOUN eurjchem-221 99 34     SPACE eurjchem-221 99 35 as as ADP eurjchem-221 99 36     SPACE eurjchem-221 99 37 the the DET eurjchem-221 99 38     SPACE eurjchem-221 99 39 major major ADJ eurjchem-221 99 40     SPACE eurjchem-221 99 41 product product NOUN eurjchem-221 99 42     SPACE eurjchem-221 99 43 while while SCONJ eurjchem-221 99 44     SPACE eurjchem-221 99 45 substrate substrate NOUN eurjchem-221 99 46     SPACE eurjchem-221 99 47 ( ( PUNCT eurjchem-221 99 48 a a X eurjchem-221 99 49 ) ) PUNCT eurjchem-221 99 50     SPACE eurjchem-221 99 51 disappeared disappear VERB eurjchem-221 99 52     SPACE eurjchem-221 99 53 completely completely ADV eurjchem-221 99 54     SPACE eurjchem-221 99 55 from from ADP eurjchem-221 99 56     SPACE eurjchem-221 99 57 the the DET eurjchem-221 99 58     SPACE eurjchem-221 99 59 reaction reaction NOUN eurjchem-221 99 60     SPACE eurjchem-221 99 61 mixture mixture NOUN eurjchem-221 99 62     SPACE eurjchem-221 99 63 forming form VERB eurjchem-221 99 64     SPACE eurjchem-221 99 65 ( ( PUNCT eurjchem-221 99 66 e e NOUN eurjchem-221 99 67 ) ) PUNCT eurjchem-221 99 68     SPACE eurjchem-221 99 69 and and CCONJ eurjchem-221 99 70     SPACE eurjchem-221 99 71 byproducts byproduct NOUN eurjchem-221 99 72 , , PUNCT eurjchem-221 99 73     SPACE eurjchem-221 99 74 reactant reactant NOUN eurjchem-221 99 75     SPACE eurjchem-221 99 76 ( ( PUNCT eurjchem-221 99 77 b b NOUN eurjchem-221 99 78 ) ) PUNCT eurjchem-221 99 79     SPACE eurjchem-221 99 80 could could AUX eurjchem-221 99 81     SPACE eurjchem-221 99 82 be be AUX eurjchem-221 99 83     SPACE eurjchem-221 99 84 isolated isolate VERB eurjchem-221 99 85     SPACE eurjchem-221 99 86 from from ADP eurjchem-221 99 87     SPACE eurjchem-221 99 88 the the DET eurjchem-221 99 89     SPACE eurjchem-221 99 90 reaction reaction NOUN eurjchem-221 99 91     SPACE eurjchem-221 99 92 mixture mixture NOUN eurjchem-221 99 93 . . PUNCT eurjchem-221 99 94     SPACE eurjchem-221 99 95 homo homo NOUN eurjchem-221 99 96     SPACE eurjchem-221 99 97 coupled couple VERB eurjchem-221 99 98     SPACE eurjchem-221 99 99 product product NOUN eurjchem-221 99 100     SPACE eurjchem-221 99 101 ( ( PUNCT eurjchem-221 99 102 c c NOUN eurjchem-221 99 103 ) ) PUNCT eurjchem-221 99 104     SPACE eurjchem-221 99 105 was be AUX eurjchem-221 99 106     SPACE eurjchem-221 99 107 not not PART eurjchem-221 99 108     SPACE eurjchem-221 99 109 formed form VERB eurjchem-221 99 110     SPACE eurjchem-221 99 111 in in ADP eurjchem-221 99 112     SPACE eurjchem-221 99 113 this this DET eurjchem-221 99 114     SPACE eurjchem-221 99 115 reaction reaction NOUN eurjchem-221 99 116     SPACE eurjchem-221 99 117 and and CCONJ eurjchem-221 99 118     SPACE eurjchem-221 99 119 the the DET eurjchem-221 99 120     SPACE eurjchem-221 99 121 yield yield NOUN eurjchem-221 99 122     SPACE eurjchem-221 99 123 of of ADP eurjchem-221 99 124     SPACE eurjchem-221 99 125 another another DET eurjchem-221 99 126     SPACE eurjchem-221 99 127 homo homo NOUN eurjchem-221 99 128     SPACE eurjchem-221 99 129 coupled couple VERB eurjchem-221 99 130     SPACE eurjchem-221 99 131 product product NOUN eurjchem-221 99 132     SPACE eurjchem-221 99 133 ( ( PUNCT eurjchem-221 99 134 d d NOUN eurjchem-221 99 135 ) ) PUNCT eurjchem-221 99 136     SPACE eurjchem-221 99 137 and and CCONJ eurjchem-221 99 138     SPACE eurjchem-221 99 139 the the DET eurjchem-221 99 140     SPACE eurjchem-221 99 141 cross cross NOUN eurjchem-221 99 142     SPACE eurjchem-221 99 143 coupled couple VERB eurjchem-221 99 144     SPACE eurjchem-221 99 145 product product NOUN eurjchem-221 99 146     SPACE eurjchem-221 99 147 ( ( PUNCT eurjchem-221 99 148 e e NOUN eurjchem-221 99 149 ) ) PUNCT eurjchem-221 99 150     SPACE eurjchem-221 99 151 are be AUX eurjchem-221 99 152     SPACE eurjchem-221 99 153 presented present VERB eurjchem-221 99 154     SPACE eurjchem-221 99 155 in in ADP eurjchem-221 99 156     SPACE eurjchem-221 99 157 table table NOUN eurjchem-221 99 158     SPACE eurjchem-221 99 159 3 3 NUM eurjchem-221 99 160 . . PUNCT eurjchem-221 99 161     SPACE eurjchem-221 99 162 this this PRON eurjchem-221 99 163     SPACE eurjchem-221 99 164 observed observe VERB eurjchem-221 99 165     SPACE eurjchem-221 99 166 selectivity selectivity NOUN eurjchem-221 99 167     SPACE eurjchem-221 99 168 in in ADP eurjchem-221 99 169     SPACE eurjchem-221 99 170 product product NOUN eurjchem-221 99 171     SPACE eurjchem-221 99 172 formation formation NOUN eurjchem-221 99 173     SPACE eurjchem-221 99 174 may may AUX eurjchem-221 99 175     SPACE eurjchem-221 99 176 be be AUX eurjchem-221 99 177     SPACE eurjchem-221 99 178 ascribed ascribe VERB eurjchem-221 99 179     SPACE eurjchem-221 99 180 to to ADP eurjchem-221 99 181     SPACE eurjchem-221 99 182 the the DET eurjchem-221 99 183     SPACE eurjchem-221 99 184 electronic electronic ADJ eurjchem-221 99 185     SPACE eurjchem-221 99 186 nature nature NOUN eurjchem-221 99 187     SPACE eurjchem-221 99 188 of of ADP eurjchem-221 99 189     SPACE eurjchem-221 99 190 the the DET eurjchem-221 99 191     SPACE eurjchem-221 99 192 radical radical NOUN eurjchem-221 99 193     SPACE eurjchem-221 99 194 formed form VERB eurjchem-221 99 195 . . PUNCT eurjchem-221 99 196     SPACE eurjchem-221 99 197 substrate substrate NOUN eurjchem-221 99 198     SPACE eurjchem-221 99 199 ( ( PUNCT eurjchem-221 99 200 b b NOUN eurjchem-221 99 201 ) ) PUNCT eurjchem-221 99 202     SPACE eurjchem-221 99 203 with with ADP eurjchem-221 99 204     SPACE eurjchem-221 99 205 an an DET eurjchem-221 99 206     SPACE eurjchem-221 99 207 electron electron NOUN eurjchem-221 99 208     SPACE eurjchem-221 99 209 withdrawing withdrawing NOUN eurjchem-221 99 210     SPACE eurjchem-221 99 211 group group NOUN eurjchem-221 99 212     SPACE eurjchem-221 99 213 might might AUX eurjchem-221 99 214     SPACE eurjchem-221 99 215 act act VERB eurjchem-221 99 216     SPACE eurjchem-221 99 217 as as ADP eurjchem-221 99 218     SPACE eurjchem-221 99 219 an an DET eurjchem-221 99 220     SPACE eurjchem-221 99 221 acceptor acceptor NOUN eurjchem-221 99 222 , , PUNCT eurjchem-221 99 223     SPACE eurjchem-221 99 224 and and CCONJ eurjchem-221 99 225     SPACE eurjchem-221 99 226 substrate substrate NOUN eurjchem-221 99 227     SPACE eurjchem-221 99 228 ( ( PUNCT eurjchem-221 99 229 a a X eurjchem-221 99 230 ) ) PUNCT eurjchem-221 99 231     SPACE eurjchem-221 99 232 might might AUX eurjchem-221 99 233     SPACE eurjchem-221 99 234 participate participate VERB eurjchem-221 99 235     SPACE eurjchem-221 99 236 in in ADP eurjchem-221 99 237     SPACE eurjchem-221 99 238 one one NUM eurjchem-221 99 239     SPACE eurjchem-221 99 240 electron electron NOUN eurjchem-221 99 241     SPACE eurjchem-221 99 242 red‐ox red‐ox PROPN eurjchem-221 99 243     SPACE eurjchem-221 99 244 reaction reaction NOUN eurjchem-221 99 245     SPACE eurjchem-221 99 246 with with ADP eurjchem-221 99 247     SPACE eurjchem-221 99 248 copper copper NOUN eurjchem-221 99 249     SPACE eurjchem-221 99 250 ( ( PUNCT eurjchem-221 99 251 ii ii NOUN eurjchem-221 99 252 ) ) PUNCT eurjchem-221 99 253     SPACE eurjchem-221 99 254 complex complex NOUN eurjchem-221 99 255     SPACE eurjchem-221 99 256 generating generating NOUN eurjchem-221 99 257     SPACE eurjchem-221 99 258 a a DET eurjchem-221 99 259     SPACE eurjchem-221 99 260 radical radical ADJ eurjchem-221 99 261     SPACE eurjchem-221 99 262 intermediate intermediate ADJ eurjchem-221 99 263     SPACE eurjchem-221 99 264 which which PRON eurjchem-221 99 265     SPACE eurjchem-221 99 266 preferentially preferentially ADV eurjchem-221 99 267     SPACE eurjchem-221 99 268 couples couple NOUN eurjchem-221 99 269     SPACE eurjchem-221 99 270 with with ADP eurjchem-221 99 271     SPACE eurjchem-221 99 272 substrate substrate NOUN eurjchem-221 99 273     SPACE eurjchem-221 99 274 ( ( PUNCT eurjchem-221 99 275 b b NOUN eurjchem-221 99 276 ) ) PUNCT eurjchem-221 99 277 . . PUNCT eurjchem-221 99 278           SPACE eurjchem-221 99 279 3.3 3.3 NUM eurjchem-221 99 280 . . PUNCT eurjchem-221 99 281     SPACE eurjchem-221 99 282 epr epr PROPN eurjchem-221 99 283     SPACE eurjchem-221 99 284 monitoring monitoring NOUN eurjchem-221 99 285     SPACE eurjchem-221 99 286 of of ADP eurjchem-221 99 287     SPACE eurjchem-221 99 288 reaction reaction NOUN eurjchem-221 99 289           SPACE eurjchem-221 99 290 the the DET eurjchem-221 99 291     SPACE eurjchem-221 99 292 reaction reaction NOUN eurjchem-221 99 293     SPACE eurjchem-221 99 294 performed perform VERB eurjchem-221 99 295     SPACE eurjchem-221 99 296 using use VERB eurjchem-221 99 297     SPACE eurjchem-221 99 298 catalyst catalyst NOUN eurjchem-221 99 299     SPACE eurjchem-221 99 300 1 1 NUM eurjchem-221 99 301     SPACE eurjchem-221 99 302 was be AUX eurjchem-221 99 303     SPACE eurjchem-221 99 304 monitored monitor VERB eurjchem-221 99 305     SPACE eurjchem-221 99 306 by by ADP eurjchem-221 99 307     SPACE eurjchem-221 99 308 epr epr PROPN eurjchem-221 99 309     SPACE eurjchem-221 99 310 and and CCONJ eurjchem-221 99 311     SPACE eurjchem-221 99 312 tlc tlc NOUN eurjchem-221 99 313 . . PUNCT eurjchem-221 99 314     SPACE eurjchem-221 100 1 there there PRON eurjchem-221 100 2     SPACE eurjchem-221 100 3 is be AUX eurjchem-221 100 4     SPACE eurjchem-221 100 5 no no DET eurjchem-221 100 6     SPACE eurjchem-221 100 7 apparent apparent ADJ eurjchem-221 100 8     SPACE eurjchem-221 100 9 difference difference NOUN eurjchem-221 100 10     SPACE eurjchem-221 100 11 in in ADP eurjchem-221 100 12     SPACE eurjchem-221 100 13 epr epr PROPN eurjchem-221 100 14     SPACE eurjchem-221 100 15 spectra spectra NOUN eurjchem-221 100 16     SPACE eurjchem-221 100 17 of of ADP eurjchem-221 100 18     SPACE eurjchem-221 100 19 the the DET eurjchem-221 100 20     SPACE eurjchem-221 100 21 complex complex NOUN eurjchem-221 100 22     SPACE eurjchem-221 100 23 and and CCONJ eurjchem-221 100 24     SPACE eurjchem-221 100 25 of of ADP eurjchem-221 100 26     SPACE eurjchem-221 100 27 the the DET eurjchem-221 100 28     SPACE eurjchem-221 100 29 reaction reaction NOUN eurjchem-221 100 30     SPACE eurjchem-221 100 31 mixture mixture NOUN eurjchem-221 100 32     SPACE eurjchem-221 100 33 till till SCONJ eurjchem-221 100 34     SPACE eurjchem-221 100 35 the the DET eurjchem-221 100 36     SPACE eurjchem-221 100 37 formation formation NOUN eurjchem-221 100 38     SPACE eurjchem-221 100 39 of of ADP eurjchem-221 100 40     SPACE eurjchem-221 100 41 binol binol NOUN eurjchem-221 100 42     SPACE eurjchem-221 100 43 was be AUX eurjchem-221 100 44     SPACE eurjchem-221 100 45 noticed notice VERB eurjchem-221 100 46     SPACE eurjchem-221 100 47 on on ADP eurjchem-221 100 48     SPACE eurjchem-221 100 49 tlc tlc NOUN eurjchem-221 100 50 . . PUNCT eurjchem-221 100 51     SPACE eurjchem-221 100 52 however however ADV eurjchem-221 100 53     SPACE eurjchem-221 100 54 different different ADJ eurjchem-221 100 55     SPACE eurjchem-221 100 56 epr epr PROPN eurjchem-221 100 57     SPACE eurjchem-221 100 58 patterns pattern NOUN eurjchem-221 100 59     SPACE eurjchem-221 100 60 are be AUX eurjchem-221 100 61     SPACE eurjchem-221 100 62 seen see VERB eurjchem-221 100 63     SPACE eurjchem-221 100 64 as as SCONJ eurjchem-221 100 65     SPACE eurjchem-221 100 66 the the DET eurjchem-221 100 67     SPACE eurjchem-221 100 68 reaction reaction NOUN eurjchem-221 100 69     SPACE eurjchem-221 100 70 was be AUX eurjchem-221 100 71     SPACE eurjchem-221 100 72 in in ADP eurjchem-221 100 73     SPACE eurjchem-221 100 74 progress progress NOUN eurjchem-221 100 75     SPACE eurjchem-221 100 76 and and CCONJ eurjchem-221 100 77     SPACE eurjchem-221 100 78 concentration concentration NOUN eurjchem-221 100 79     SPACE eurjchem-221 100 80 of of ADP eurjchem-221 100 81     SPACE eurjchem-221 100 82 binol binol NOUN eurjchem-221 100 83     SPACE eurjchem-221 100 84 in in ADP eurjchem-221 100 85     SPACE eurjchem-221 100 86 the the DET eurjchem-221 100 87     SPACE eurjchem-221 100 88 reaction reaction NOUN eurjchem-221 100 89     SPACE eurjchem-221 100 90 mixture mixture NOUN eurjchem-221 100 91     SPACE eurjchem-221 100 92 increased increase VERB eurjchem-221 100 93 . . PUNCT eurjchem-221 100 94     SPACE eurjchem-221 101 1 though though SCONJ eurjchem-221 101 2     SPACE eurjchem-221 101 3 the the DET eurjchem-221 101 4     SPACE eurjchem-221 101 5 reaction reaction NOUN eurjchem-221 101 6     SPACE eurjchem-221 101 7 is be AUX eurjchem-221 101 8     SPACE eurjchem-221 101 9 suggested suggest VERB eurjchem-221 101 10     SPACE eurjchem-221 101 11 to to PART eurjchem-221 101 12     SPACE eurjchem-221 101 13 proceed proceed VERB eurjchem-221 101 14     SPACE eurjchem-221 101 15 through through ADP eurjchem-221 101 16     SPACE eurjchem-221 101 17 a a DET eurjchem-221 101 18     SPACE eurjchem-221 101 19 radial radial ADJ eurjchem-221 101 20     SPACE eurjchem-221 101 21 mechanism mechanism NOUN eurjchem-221 101 22 , , PUNCT eurjchem-221 101 23     SPACE eurjchem-221 101 24 a a DET eurjchem-221 101 25     SPACE eurjchem-221 101 26 free free ADJ eurjchem-221 101 27     SPACE eurjchem-221 101 28 radical radical ADJ eurjchem-221 101 29     SPACE eurjchem-221 101 30 signal signal NOUN eurjchem-221 101 31     SPACE eurjchem-221 101 32 was be AUX eurjchem-221 101 33     SPACE eurjchem-221 101 34 not not PART eurjchem-221 101 35     SPACE eurjchem-221 101 36 seen see VERB eurjchem-221 101 37     SPACE eurjchem-221 101 38 in in ADP eurjchem-221 101 39     SPACE eurjchem-221 101 40 the the DET eurjchem-221 101 41     SPACE eurjchem-221 101 42 epr epr PROPN eurjchem-221 101 43     SPACE eurjchem-221 101 44 spectrum spectrum NOUN eurjchem-221 101 45     SPACE eurjchem-221 101 46 till till AUX eurjchem-221 101 47     SPACE eurjchem-221 101 48 binol binol VERB eurjchem-221 101 49     SPACE eurjchem-221 101 50 ( ( PUNCT eurjchem-221 101 51 c c NOUN eurjchem-221 101 52 ) ) PUNCT eurjchem-221 101 53     SPACE eurjchem-221 101 54 was be AUX eurjchem-221 101 55     SPACE eurjchem-221 101 56 noted note VERB eurjchem-221 101 57     SPACE eurjchem-221 101 58 on on ADP eurjchem-221 101 59     SPACE eurjchem-221 101 60 tlc tlc NOUN eurjchem-221 101 61 . . PUNCT eurjchem-221 101 62     SPACE eurjchem-221 102 1 moreover moreover ADV eurjchem-221 102 2 , , PUNCT eurjchem-221 102 3     SPACE eurjchem-221 102 4 epr epr ADJ eurjchem-221 102 5     SPACE eurjchem-221 102 6 pattern pattern NOUN eurjchem-221 102 7     SPACE eurjchem-221 102 8 of of ADP eurjchem-221 102 9     SPACE eurjchem-221 102 10 the the DET eurjchem-221 102 11     SPACE eurjchem-221 102 12 complex complex NOUN eurjchem-221 102 13     SPACE eurjchem-221 102 14 also also ADV eurjchem-221 102 15     SPACE eurjchem-221 102 16 did do AUX eurjchem-221 102 17     SPACE eurjchem-221 102 18 not not PART eurjchem-221 102 19     SPACE eurjchem-221 102 20 show show VERB eurjchem-221 102 21     SPACE eurjchem-221 102 22 any any DET eurjchem-221 102 23     SPACE eurjchem-221 102 24 change change NOUN eurjchem-221 102 25     SPACE eurjchem-221 102 26 till till SCONJ eurjchem-221 102 27     SPACE eurjchem-221 102 28 the the DET eurjchem-221 102 29     SPACE eurjchem-221 102 30 formation formation NOUN eurjchem-221 102 31     SPACE eurjchem-221 102 32 of of ADP eurjchem-221 102 33     SPACE eurjchem-221 102 34 binol binol VERB eurjchem-221 102 35     SPACE eurjchem-221 102 36 was be AUX eurjchem-221 102 37     SPACE eurjchem-221 102 38 noted note VERB eurjchem-221 102 39     SPACE eurjchem-221 102 40 on on ADP eurjchem-221 102 41     SPACE eurjchem-221 102 42 tlc tlc NOUN eurjchem-221 102 43 . . PUNCT eurjchem-221 102 44     SPACE eurjchem-221 102 45 the the DET eurjchem-221 102 46     SPACE eurjchem-221 102 47 radical radical NOUN eurjchem-221 102 48     SPACE eurjchem-221 102 49 may may AUX eurjchem-221 102 50     SPACE eurjchem-221 102 51 be be AUX eurjchem-221 102 52     SPACE eurjchem-221 102 53 short short ADJ eurjchem-221 102 54     SPACE eurjchem-221 102 55 lived live VERB eurjchem-221 102 56     SPACE eurjchem-221 102 57 and and CCONJ eurjchem-221 102 58     SPACE eurjchem-221 102 59 undergo undergo VERB eurjchem-221 102 60     SPACE eurjchem-221 102 61 dimerization dimerization NOUN eurjchem-221 102 62     SPACE eurjchem-221 102 63 before before ADP eurjchem-221 102 64     SPACE eurjchem-221 102 65 being be AUX eurjchem-221 102 66     SPACE eurjchem-221 102 67 detected detect VERB eurjchem-221 102 68     SPACE eurjchem-221 102 69 by by ADP eurjchem-221 102 70     SPACE eurjchem-221 102 71 epr epr PROPN eurjchem-221 102 72 . . PUNCT eurjchem-221 102 73     SPACE eurjchem-221 102 74 however however ADV eurjchem-221 102 75 , , PUNCT eurjchem-221 102 76     SPACE eurjchem-221 102 77 variations variation NOUN eurjchem-221 102 78     SPACE eurjchem-221 102 79 in in ADP eurjchem-221 102 80     SPACE eurjchem-221 102 81 the the DET eurjchem-221 102 82     SPACE eurjchem-221 102 83 intensity intensity NOUN eurjchem-221 102 84     SPACE eurjchem-221 102 85 of of ADP eurjchem-221 102 86     SPACE eurjchem-221 102 87 the the DET eurjchem-221 102 88     SPACE eurjchem-221 102 89 copper copper NOUN eurjchem-221 102 90     SPACE eurjchem-221 102 91 lines line NOUN eurjchem-221 102 92     SPACE eurjchem-221 102 93 were be AUX eurjchem-221 102 94     SPACE eurjchem-221 102 95 observed observe VERB eurjchem-221 102 96     SPACE eurjchem-221 102 97 which which PRON eurjchem-221 102 98     SPACE eurjchem-221 102 99 is be AUX eurjchem-221 102 100     SPACE eurjchem-221 102 101 attributable attributable ADJ eurjchem-221 102 102     SPACE eurjchem-221 102 103 to to ADP eurjchem-221 102 104     SPACE eurjchem-221 102 105 the the DET eurjchem-221 102 106     SPACE eurjchem-221 102 107 red‐ox red‐ox NOUN eurjchem-221 102 108     SPACE eurjchem-221 102 109 cycle cycle NOUN eurjchem-221 102 110     SPACE eurjchem-221 102 111 of of ADP eurjchem-221 102 112     SPACE eurjchem-221 102 113 the the DET eurjchem-221 102 114     SPACE eurjchem-221 102 115 reaction reaction NOUN eurjchem-221 102 116 . . PUNCT eurjchem-221 102 117     SPACE eurjchem-221 103 1 formation formation NOUN eurjchem-221 103 2     SPACE eurjchem-221 103 3 of of ADP eurjchem-221 103 4     SPACE eurjchem-221 103 5 a a DET eurjchem-221 103 6     SPACE eurjchem-221 103 7 new new ADJ eurjchem-221 103 8     SPACE eurjchem-221 103 9 copper copper NOUN eurjchem-221 103 10     SPACE eurjchem-221 103 11 species specie NOUN eurjchem-221 103 12     SPACE eurjchem-221 103 13 and and CCONJ eurjchem-221 103 14     SPACE eurjchem-221 103 15 a a DET eurjchem-221 103 16     SPACE eurjchem-221 103 17 radical radical ADJ eurjchem-221 103 18     SPACE eurjchem-221 103 19 signal signal NOUN eurjchem-221 103 20     SPACE eurjchem-221 103 21 was be AUX eurjchem-221 103 22     SPACE eurjchem-221 103 23 observed observe VERB eurjchem-221 103 24     SPACE eurjchem-221 103 25 ( ( PUNCT eurjchem-221 103 26 figure figure NOUN eurjchem-221 103 27     SPACE eurjchem-221 103 28 3 3 NUM eurjchem-221 103 29 , , PUNCT eurjchem-221 103 30     SPACE eurjchem-221 103 31 3 3 NUM eurjchem-221 103 32 g g NOUN eurjchem-221 103 33 ) ) PUNCT eurjchem-221 103 34     SPACE eurjchem-221 103 35 as as SCONJ eurjchem-221 103 36     SPACE eurjchem-221 103 37 the the DET eurjchem-221 103 38     SPACE eurjchem-221 103 39 reaction reaction NOUN eurjchem-221 103 40     SPACE eurjchem-221 103 41 time time NOUN eurjchem-221 103 42     SPACE eurjchem-221 103 43 increased increase VERB eurjchem-221 103 44 . . PUNCT eurjchem-221 103 45     SPACE eurjchem-221 104 1 the the DET eurjchem-221 104 2     SPACE eurjchem-221 104 3 free free ADJ eurjchem-221 104 4     SPACE eurjchem-221 104 5 radical radical ADJ eurjchem-221 104 6     SPACE eurjchem-221 104 7 signal signal NOUN eurjchem-221 104 8     SPACE eurjchem-221 104 9 persisted persist VERB eurjchem-221 104 10     SPACE eurjchem-221 104 11 till till SCONJ eurjchem-221 104 12     SPACE eurjchem-221 104 13 the the DET eurjchem-221 104 14     SPACE eurjchem-221 104 15 completion completion NOUN eurjchem-221 104 16     SPACE eurjchem-221 104 17 of of ADP eurjchem-221 104 18     SPACE eurjchem-221 104 19 the the DET eurjchem-221 104 20     SPACE eurjchem-221 104 21 reaction reaction NOUN eurjchem-221 104 22     SPACE eurjchem-221 104 23 and and CCONJ eurjchem-221 104 24     SPACE eurjchem-221 104 25 increased increase VERB eurjchem-221 104 26     SPACE eurjchem-221 104 27 in in ADP eurjchem-221 104 28     SPACE eurjchem-221 104 29 intensity intensity NOUN eurjchem-221 104 30     SPACE eurjchem-221 104 31 ( ( PUNCT eurjchem-221 104 32 figure figure NOUN eurjchem-221 104 33     SPACE eurjchem-221 104 34 3 3 NUM eurjchem-221 104 35 , , PUNCT eurjchem-221 104 36     SPACE eurjchem-221 104 37 3g‐3k 3g‐3k NOUN eurjchem-221 104 38 ) ) PUNCT eurjchem-221 104 39 . . PUNCT eurjchem-221 104 40     SPACE eurjchem-221 105 1 the the DET eurjchem-221 105 2     SPACE eurjchem-221 105 3 radical radical ADJ eurjchem-221 105 4     SPACE eurjchem-221 105 5 signal signal NOUN eurjchem-221 105 6     SPACE eurjchem-221 105 7 might might AUX eurjchem-221 105 8     SPACE eurjchem-221 105 9 arise arise VERB eurjchem-221 105 10     SPACE eurjchem-221 105 11 from from ADP eurjchem-221 105 12     SPACE eurjchem-221 105 13 binol binol NOUN eurjchem-221 105 14     SPACE eurjchem-221 105 15 and and CCONJ eurjchem-221 105 16     SPACE eurjchem-221 105 17 the the DET eurjchem-221 105 18     SPACE eurjchem-221 105 19 new new ADJ eurjchem-221 105 20     SPACE eurjchem-221 105 21 copper copper NOUN eurjchem-221 105 22     SPACE eurjchem-221 105 23 species specie NOUN eurjchem-221 105 24     SPACE eurjchem-221 105 25 seen see VERB eurjchem-221 105 26     SPACE eurjchem-221 105 27 in in ADP eurjchem-221 105 28     SPACE eurjchem-221 105 29 the the DET eurjchem-221 105 30     SPACE eurjchem-221 105 31 epr epr PROPN eurjchem-221 105 32     SPACE eurjchem-221 105 33 might might AUX eurjchem-221 105 34     SPACE eurjchem-221 105 35 be be AUX eurjchem-221 105 36     SPACE eurjchem-221 105 37 due due ADJ eurjchem-221 105 38     SPACE eurjchem-221 105 39 to to ADP eurjchem-221 105 40     SPACE eurjchem-221 105 41 the the DET eurjchem-221 105 42     SPACE eurjchem-221 105 43 interaction interaction NOUN eurjchem-221 105 44     SPACE eurjchem-221 105 45 of of ADP eurjchem-221 105 46     SPACE eurjchem-221 105 47 binol binol NOUN eurjchem-221 105 48     SPACE eurjchem-221 105 49 with with ADP eurjchem-221 105 50     SPACE eurjchem-221 105 51 the the DET eurjchem-221 105 52     SPACE eurjchem-221 105 53 catalyst catalyst NOUN eurjchem-221 105 54 . . PUNCT eurjchem-221 105 55     SPACE eurjchem-221 106 1 the the DET eurjchem-221 106 2     SPACE eurjchem-221 106 3 observed observe VERB eurjchem-221 106 4     SPACE eurjchem-221 106 5 decrease decrease NOUN eurjchem-221 106 6     SPACE eurjchem-221 106 7 in in ADP eurjchem-221 106 8     SPACE eurjchem-221 106 9 the the DET eurjchem-221 106 10     SPACE eurjchem-221 106 11 yield yield NOUN eurjchem-221 106 12     SPACE eurjchem-221 106 13 of of ADP eurjchem-221 106 14     SPACE eurjchem-221 106 15 ( ( PUNCT eurjchem-221 106 16 c c NOUN eurjchem-221 106 17 ) ) PUNCT eurjchem-221 106 18     SPACE eurjchem-221 106 19 with with ADP eurjchem-221 106 20     SPACE eurjchem-221 106 21 concomitant concomitant ADJ eurjchem-221 106 22     SPACE eurjchem-221 106 23 increase increase NOUN eurjchem-221 106 24     SPACE eurjchem-221 106 25 in in ADP eurjchem-221 106 26     SPACE eurjchem-221 106 27 other other ADJ eurjchem-221 106 28     SPACE eurjchem-221 106 29 by‐products by‐product NOUN eurjchem-221 106 30     SPACE eurjchem-221 106 31 when when SCONJ eurjchem-221 106 32     SPACE eurjchem-221 106 33 the the DET eurjchem-221 106 34     SPACE eurjchem-221 106 35 amount amount NOUN eurjchem-221 106 36     SPACE eurjchem-221 106 37 of of ADP eurjchem-221 106 38     SPACE eurjchem-221 106 39 the the DET eurjchem-221 106 40     SPACE eurjchem-221 106 41 catalyst catalyst NOUN eurjchem-221 106 42     SPACE eurjchem-221 106 43 is be AUX eurjchem-221 106 44     SPACE eurjchem-221 106 45 increased increase VERB eurjchem-221 106 46     SPACE eurjchem-221 106 47 can can AUX eurjchem-221 106 48     SPACE eurjchem-221 106 49 be be AUX eurjchem-221 106 50     SPACE eurjchem-221 106 51 attributed attribute VERB eurjchem-221 106 52     SPACE eurjchem-221 106 53 to to ADP eurjchem-221 106 54     SPACE eurjchem-221 106 55 an an DET eurjchem-221 106 56     SPACE eurjchem-221 106 57 increase increase NOUN eurjchem-221 106 58     SPACE eurjchem-221 106 59 in in ADP eurjchem-221 106 60     SPACE eurjchem-221 106 61 the the DET eurjchem-221 106 62     SPACE eurjchem-221 106 63 rate rate NOUN eurjchem-221 106 64     SPACE eurjchem-221 106 65 of of ADP eurjchem-221 106 66     SPACE eurjchem-221 106 67 the the DET eurjchem-221 106 68     SPACE eurjchem-221 106 69 reaction reaction NOUN eurjchem-221 106 70     SPACE eurjchem-221 106 71 with with ADP eurjchem-221 106 72     SPACE eurjchem-221 106 73 increasing increase VERB eurjchem-221 106 74     SPACE eurjchem-221 106 75 the the DET eurjchem-221 106 76     SPACE eurjchem-221 106 77 amount amount NOUN eurjchem-221 106 78     SPACE eurjchem-221 106 79 of of ADP eurjchem-221 106 80     SPACE eurjchem-221 106 81 the the DET eurjchem-221 106 82     SPACE eurjchem-221 106 83 catalyst catalyst NOUN eurjchem-221 106 84     SPACE eurjchem-221 106 85 resulting result VERB eurjchem-221 106 86     SPACE eurjchem-221 106 87 in in ADP eurjchem-221 106 88     SPACE eurjchem-221 106 89 ( ( PUNCT eurjchem-221 106 90 c c NOUN eurjchem-221 106 91 ) ) PUNCT eurjchem-221 106 92     SPACE eurjchem-221 106 93 and and CCONJ eurjchem-221 106 94     SPACE eurjchem-221 106 95 its its PRON eurjchem-221 106 96     SPACE eurjchem-221 106 97 reaction reaction NOUN eurjchem-221 106 98     SPACE eurjchem-221 106 99 with with ADP eurjchem-221 106 100     SPACE eurjchem-221 106 101 the the DET eurjchem-221 106 102     SPACE eurjchem-221 106 103 catalyst catalyst NOUN eurjchem-221 106 104 . . PUNCT eurjchem-221 106 105     SPACE eurjchem-221 107 1 monitoring monitor VERB eurjchem-221 107 2     SPACE eurjchem-221 107 3 the the DET eurjchem-221 107 4     SPACE eurjchem-221 107 5 reaction reaction NOUN eurjchem-221 107 6     SPACE eurjchem-221 107 7 of of ADP eurjchem-221 107 8     SPACE eurjchem-221 107 9 ( ( PUNCT eurjchem-221 107 10 a a X eurjchem-221 107 11 ) ) PUNCT eurjchem-221 107 12     SPACE eurjchem-221 107 13 using use VERB eurjchem-221 107 14     SPACE eurjchem-221 107 15 catalyst catalyst NOUN eurjchem-221 107 16     SPACE eurjchem-221 107 17 2 2 NUM eurjchem-221 107 18     SPACE eurjchem-221 107 19 also also ADV eurjchem-221 107 20     SPACE eurjchem-221 107 21 showed show VERB eurjchem-221 107 22     SPACE eurjchem-221 107 23 a a DET eurjchem-221 107 24     SPACE eurjchem-221 107 25 similar similar ADJ eurjchem-221 107 26     SPACE eurjchem-221 107 27 trend trend NOUN eurjchem-221 107 28     SPACE eurjchem-221 107 29 in in ADP eurjchem-221 107 30     SPACE eurjchem-221 107 31 the the DET eurjchem-221 107 32     SPACE eurjchem-221 107 33 epr epr PROPN eurjchem-221 107 34     SPACE eurjchem-221 107 35 lines line NOUN eurjchem-221 107 36     SPACE eurjchem-221 107 37 of of ADP eurjchem-221 107 38     SPACE eurjchem-221 107 39 copper copper NOUN eurjchem-221 107 40     SPACE eurjchem-221 107 41 as as ADV eurjchem-221 107 42     SPACE eurjchem-221 107 43 long long ADV eurjchem-221 107 44     SPACE eurjchem-221 107 45 as as ADP eurjchem-221 107 46     SPACE eurjchem-221 107 47 the the DET eurjchem-221 107 48     SPACE eurjchem-221 107 49 reaction reaction NOUN eurjchem-221 107 50     SPACE eurjchem-221 107 51 continued continue VERB eurjchem-221 107 52 . . PUNCT eurjchem-221 107 53     SPACE eurjchem-221 108 1 although although SCONJ eurjchem-221 108 2     SPACE eurjchem-221 108 3 epr epr ADJ eurjchem-221 108 4     SPACE eurjchem-221 108 5 resonances resonance NOUN eurjchem-221 108 6     SPACE eurjchem-221 108 7 corresponding correspond VERB eurjchem-221 108 8     SPACE eurjchem-221 108 9 to to ADP eurjchem-221 108 10     SPACE eurjchem-221 108 11 a a DET eurjchem-221 108 12     SPACE eurjchem-221 108 13 radical radical NOUN eurjchem-221 108 14     SPACE eurjchem-221 108 15 appeared appear VERB eurjchem-221 108 16     SPACE eurjchem-221 108 17 as as SCONJ eurjchem-221 108 18     SPACE eurjchem-221 108 19 observed observe VERB eurjchem-221 108 20     SPACE eurjchem-221 108 21 in in ADP eurjchem-221 108 22     SPACE eurjchem-221 108 23 the the DET eurjchem-221 108 24     SPACE eurjchem-221 108 25 reaction reaction NOUN eurjchem-221 108 26     SPACE eurjchem-221 108 27 with with ADP eurjchem-221 108 28     SPACE eurjchem-221 108 29 catalyst catalyst NOUN eurjchem-221 108 30     SPACE eurjchem-221 108 31 1 1 NUM eurjchem-221 108 32 , , PUNCT eurjchem-221 108 33     SPACE eurjchem-221 108 34 the the DET eurjchem-221 108 35     SPACE eurjchem-221 108 36 increasing increase VERB eurjchem-221 108 37     SPACE eurjchem-221 108 38 intensity intensity NOUN eurjchem-221 108 39     SPACE eurjchem-221 108 40 of of ADP eurjchem-221 108 41     SPACE eurjchem-221 108 42 the the DET eurjchem-221 108 43     SPACE eurjchem-221 108 44 radical radical ADJ eurjchem-221 108 45     SPACE eurjchem-221 108 46 signal signal NOUN eurjchem-221 108 47     SPACE eurjchem-221 108 48 did do AUX eurjchem-221 108 49     SPACE eurjchem-221 108 50 not not PART eurjchem-221 108 51     SPACE eurjchem-221 108 52 affect affect VERB eurjchem-221 108 53     SPACE eurjchem-221 108 54 the the DET eurjchem-221 108 55     SPACE eurjchem-221 108 56 pattern pattern NOUN eurjchem-221 108 57     SPACE eurjchem-221 108 58 of of ADP eurjchem-221 108 59     SPACE eurjchem-221 108 60 the the DET eurjchem-221 108 61     SPACE eurjchem-221 108 62 copper copper NOUN eurjchem-221 108 63     SPACE eurjchem-221 108 64 lines line NOUN eurjchem-221 108 65     SPACE eurjchem-221 108 66 ( ( PUNCT eurjchem-221 108 67 figure figure NOUN eurjchem-221 108 68     SPACE eurjchem-221 108 69 4 4 NUM eurjchem-221 108 70 , , PUNCT eurjchem-221 108 71     SPACE eurjchem-221 108 72 4i‐4j 4i‐4j NUM eurjchem-221 108 73 ) ) PUNCT eurjchem-221 108 74     SPACE eurjchem-221 108 75 ascribable ascribable NOUN eurjchem-221 108 76     SPACE eurjchem-221 108 77 to to ADP eurjchem-221 108 78     SPACE eurjchem-221 108 79 the the DET eurjchem-221 108 80     SPACE eurjchem-221 108 81 steric steric ADJ eurjchem-221 108 82     SPACE eurjchem-221 108 83 crowding crowd VERB eurjchem-221 108 84     SPACE eurjchem-221 108 85 around around ADP eurjchem-221 108 86     SPACE eurjchem-221 108 87 copper copper NOUN eurjchem-221 108 88     SPACE eurjchem-221 108 89 preventing prevent VERB eurjchem-221 108 90     SPACE eurjchem-221 108 91 the the DET eurjchem-221 108 92     SPACE eurjchem-221 108 93 binding binding NOUN eurjchem-221 108 94     SPACE eurjchem-221 108 95 of of ADP eurjchem-221 108 96     SPACE eurjchem-221 108 97 binol binol NOUN eurjchem-221 108 98     SPACE eurjchem-221 108 99 to to PART eurjchem-221 108 100     SPACE eurjchem-221 108 101 metal metal NOUN eurjchem-221 108 102     SPACE eurjchem-221 108 103 ion ion NOUN eurjchem-221 108 104 . . PUNCT eurjchem-221 108 105           SPACE eurjchem-221 109 1 3.4 3.4 NUM eurjchem-221 109 2 . . PUNCT eurjchem-221 109 3     SPACE eurjchem-221 109 4 stereoselectivity stereoselectivity NOUN eurjchem-221 109 5     SPACE eurjchem-221 109 6 of of ADP eurjchem-221 109 7     SPACE eurjchem-221 109 8 biaryl biaryl NOUN eurjchem-221 109 9     SPACE eurjchem-221 109 10 coupling coupling NOUN eurjchem-221 109 11         SPACE eurjchem-221 109 12 oxidative oxidative ADJ eurjchem-221 109 13     SPACE eurjchem-221 109 14 coupling coupling NOUN eurjchem-221 109 15     SPACE eurjchem-221 109 16 of of ADP eurjchem-221 109 17     SPACE eurjchem-221 109 18 ( ( PUNCT eurjchem-221 109 19 a a NOUN eurjchem-221 109 20 ) ) PUNCT eurjchem-221 109 21     SPACE eurjchem-221 109 22 with with ADP eurjchem-221 109 23     SPACE eurjchem-221 109 24 chiral chiral ADJ eurjchem-221 109 25     SPACE eurjchem-221 109 26 catalysts catalyst NOUN eurjchem-221 109 27     SPACE eurjchem-221 109 28 1­3 1­3 PRON eurjchem-221 109 29     SPACE eurjchem-221 109 30 resulted result VERB eurjchem-221 109 31     SPACE eurjchem-221 109 32 in in ADP eurjchem-221 109 33     SPACE eurjchem-221 109 34 the the DET eurjchem-221 109 35     SPACE eurjchem-221 109 36 formation formation NOUN eurjchem-221 109 37     SPACE eurjchem-221 109 38 of of ADP eurjchem-221 109 39     SPACE eurjchem-221 109 40 racemic racemic ADJ eurjchem-221 109 41     SPACE eurjchem-221 109 42 binol binol NOUN eurjchem-221 109 43     SPACE eurjchem-221 109 44 only only ADV eurjchem-221 109 45 . . PUNCT eurjchem-221 109 46     SPACE eurjchem-221 110 1 however however ADV eurjchem-221 110 2 , , PUNCT eurjchem-221 110 3     SPACE eurjchem-221 110 4 oxidative oxidative ADJ eurjchem-221 110 5     SPACE eurjchem-221 110 6 coupling coupling NOUN eurjchem-221 110 7     SPACE eurjchem-221 110 8 of of ADP eurjchem-221 110 9     SPACE eurjchem-221 110 10 ( ( PUNCT eurjchem-221 110 11 b b NOUN eurjchem-221 110 12 ) ) PUNCT eurjchem-221 110 13     SPACE eurjchem-221 110 14 under under ADP eurjchem-221 110 15     SPACE eurjchem-221 110 16 similar similar ADJ eurjchem-221 110 17     SPACE eurjchem-221 110 18 conditions condition NOUN eurjchem-221 110 19     SPACE eurjchem-221 110 20 resulted result VERB eurjchem-221 110 21     SPACE eurjchem-221 110 22 in in ADP eurjchem-221 110 23     SPACE eurjchem-221 110 24 38 38 NUM eurjchem-221 110 25 % % NOUN eurjchem-221 110 26     SPACE eurjchem-221 110 27 ee ee AUX eurjchem-221 110 28     SPACE eurjchem-221 110 29 ( ( PUNCT eurjchem-221 110 30 figure figure NOUN eurjchem-221 110 31     SPACE eurjchem-221 110 32 6 6 NUM eurjchem-221 110 33 ) ) PUNCT eurjchem-221 110 34     SPACE eurjchem-221 110 35 in in ADP eurjchem-221 110 36     SPACE eurjchem-221 110 37 the the DET eurjchem-221 110 38     SPACE eurjchem-221 110 39 reaction reaction NOUN eurjchem-221 110 40     SPACE eurjchem-221 110 41 with with ADP eurjchem-221 110 42     SPACE eurjchem-221 110 43 catalyst catalyst NOUN eurjchem-221 110 44     SPACE eurjchem-221 110 45 1 1 NUM eurjchem-221 110 46     SPACE eurjchem-221 110 47 ( ( PUNCT eurjchem-221 110 48 table table NOUN eurjchem-221 110 49     SPACE eurjchem-221 110 50 4 4 NUM eurjchem-221 110 51 ) ) PUNCT eurjchem-221 110 52 . . PUNCT eurjchem-221 110 53     SPACE eurjchem-221 111 1 but but CCONJ eurjchem-221 111 2     SPACE eurjchem-221 111 3 the the DET eurjchem-221 111 4     SPACE eurjchem-221 111 5 reaction reaction NOUN eurjchem-221 111 6     SPACE eurjchem-221 111 7 of of ADP eurjchem-221 111 8     SPACE eurjchem-221 111 9 ( ( PUNCT eurjchem-221 111 10 b b NOUN eurjchem-221 111 11 ) ) PUNCT eurjchem-221 111 12     SPACE eurjchem-221 111 13 with with ADP eurjchem-221 111 14     SPACE eurjchem-221 111 15 catalysts catalyst NOUN eurjchem-221 111 16     SPACE eurjchem-221 111 17 2 2 NUM eurjchem-221 111 18     SPACE eurjchem-221 111 19 and and CCONJ eurjchem-221 111 20     SPACE eurjchem-221 111 21 3 3 NUM eurjchem-221 111 22     SPACE eurjchem-221 111 23 resulted result VERB eurjchem-221 111 24     SPACE eurjchem-221 111 25 in in ADP eurjchem-221 111 26     SPACE eurjchem-221 111 27 racemic racemic ADJ eurjchem-221 111 28     SPACE eurjchem-221 111 29 products product NOUN eurjchem-221 111 30 . . PUNCT eurjchem-221 111 31     SPACE eurjchem-221 112 1 a a DET eurjchem-221 112 2     SPACE eurjchem-221 112 3 cross cross ADJ eurjchem-221 112 4     SPACE eurjchem-221 112 5 coupling couple VERB eurjchem-221 112 6     SPACE eurjchem-221 112 7 reaction reaction NOUN eurjchem-221 112 8     SPACE eurjchem-221 112 9 with with ADP eurjchem-221 112 10     SPACE eurjchem-221 112 11 catalysts catalyst NOUN eurjchem-221 112 12     SPACE eurjchem-221 112 13 1­3 1­3 NOUN eurjchem-221 112 14     SPACE eurjchem-221 112 15 also also ADV eurjchem-221 112 16     SPACE eurjchem-221 112 17 resulted result VERB eurjchem-221 112 18     SPACE eurjchem-221 112 19 in in ADP eurjchem-221 112 20     SPACE eurjchem-221 112 21 racemic racemic ADJ eurjchem-221 112 22     SPACE eurjchem-221 112 23 products product NOUN eurjchem-221 112 24     SPACE eurjchem-221 112 25 only only ADV eurjchem-221 112 26 . . PUNCT eurjchem-221 112 27     SPACE eurjchem-221 113 1 these these DET eurjchem-221 113 2     SPACE eurjchem-221 113 3 observations observation NOUN eurjchem-221 113 4     SPACE eurjchem-221 113 5 suggest suggest VERB eurjchem-221 113 6     SPACE eurjchem-221 113 7 that that SCONJ eurjchem-221 113 8     SPACE eurjchem-221 113 9 the the DET eurjchem-221 113 10     SPACE eurjchem-221 113 11 presence presence NOUN eurjchem-221 113 12     SPACE eurjchem-221 113 13 of of ADP eurjchem-221 113 14     SPACE eurjchem-221 113 15 chelating chelating NOUN eurjchem-221 113 16     SPACE eurjchem-221 113 17 substituents substituent NOUN eurjchem-221 113 18     SPACE eurjchem-221 113 19 and and CCONJ eurjchem-221 113 20     SPACE eurjchem-221 113 21 less less ADJ eurjchem-221 113 22     SPACE eurjchem-221 113 23 hindered hinder VERB eurjchem-221 113 24     SPACE eurjchem-221 113 25 catalysts catalyst NOUN eurjchem-221 113 26     SPACE eurjchem-221 113 27 enables enable VERB eurjchem-221 113 28     SPACE eurjchem-221 113 29 the the DET eurjchem-221 113 30     SPACE eurjchem-221 113 31 substrate substrate NOUN eurjchem-221 113 32     SPACE eurjchem-221 113 33 to to PART eurjchem-221 113 34     SPACE eurjchem-221 113 35 remain remain VERB eurjchem-221 113 36     SPACE eurjchem-221 113 37 bound bind VERB eurjchem-221 113 38     SPACE eurjchem-221 113 39 to to ADP eurjchem-221 113 40     SPACE eurjchem-221 113 41 chiral chiral ADJ eurjchem-221 113 42     SPACE eurjchem-221 113 43 catalyst catalyst NOUN eurjchem-221 113 44     SPACE eurjchem-221 113 45 till till SCONJ eurjchem-221 113 46     SPACE eurjchem-221 113 47 the the DET eurjchem-221 113 48     SPACE eurjchem-221 113 49 coupling coupling NOUN eurjchem-221 113 50     SPACE eurjchem-221 113 51 reaction reaction NOUN eurjchem-221 113 52     SPACE eurjchem-221 113 53 is be AUX eurjchem-221 113 54     SPACE eurjchem-221 113 55 completed complete VERB eurjchem-221 113 56     SPACE eurjchem-221 113 57 ( ( PUNCT eurjchem-221 113 58 scheme scheme NOUN eurjchem-221 113 59     SPACE eurjchem-221 113 60 4 4 NUM eurjchem-221 113 61 ) ) PUNCT eurjchem-221 113 62 . . PUNCT eurjchem-221 113 63     SPACE eurjchem-221 114 1 similar similar ADJ eurjchem-221 114 2     SPACE eurjchem-221 114 3 observation observation NOUN eurjchem-221 114 4     SPACE eurjchem-221 114 5 has have AUX eurjchem-221 114 6     SPACE eurjchem-221 114 7 been be AUX eurjchem-221 114 8     SPACE eurjchem-221 114 9 reported report VERB eurjchem-221 114 10     SPACE eurjchem-221 114 11 in in ADP eurjchem-221 114 12     SPACE eurjchem-221 114 13 chiral chiral ADJ eurjchem-221 114 14     SPACE eurjchem-221 114 15 amine amine NOUN eurjchem-221 114 16     SPACE eurjchem-221 114 17 – – PUNCT eurjchem-221 114 18     SPACE eurjchem-221 114 19 copper copper NOUN eurjchem-221 114 20     SPACE eurjchem-221 114 21 complex complex NOUN eurjchem-221 114 22     SPACE eurjchem-221 114 23 catalyzed catalyze VERB eurjchem-221 114 24     SPACE eurjchem-221 114 25 reactions reaction NOUN eurjchem-221 114 26     SPACE eurjchem-221 114 27 [ [ X eurjchem-221 114 28 24 24 NUM eurjchem-221 114 29 ] ] PUNCT eurjchem-221 114 30 . . PUNCT eurjchem-221 114 31       SPACE eurjchem-221 114 32 epr epr PROPN eurjchem-221 114 33     SPACE eurjchem-221 114 34 monitoring monitoring NOUN eurjchem-221 114 35     SPACE eurjchem-221 114 36 of of ADP eurjchem-221 114 37     SPACE eurjchem-221 114 38 the the DET eurjchem-221 114 39     SPACE eurjchem-221 114 40 reaction reaction NOUN eurjchem-221 114 41     SPACE eurjchem-221 114 42 does do AUX eurjchem-221 114 43     SPACE eurjchem-221 114 44 not not PART eurjchem-221 114 45     SPACE eurjchem-221 114 46 show show VERB eurjchem-221 114 47     SPACE eurjchem-221 114 48 any any DET eurjchem-221 114 49     SPACE eurjchem-221 114 50 change change NOUN eurjchem-221 114 51     SPACE eurjchem-221 114 52 in in ADP eurjchem-221 114 53     SPACE eurjchem-221 114 54 the the DET eurjchem-221 114 55     SPACE eurjchem-221 114 56 pattern pattern NOUN eurjchem-221 114 57     SPACE eurjchem-221 114 58 of of ADP eurjchem-221 114 59     SPACE eurjchem-221 114 60 the the DET eurjchem-221 114 61     SPACE eurjchem-221 114 62 epr epr PROPN eurjchem-221 114 63     SPACE eurjchem-221 114 64 lines line NOUN eurjchem-221 114 65     SPACE eurjchem-221 114 66 as as ADV eurjchem-221 114 67     SPACE eurjchem-221 114 68 long long ADJ eurjchem-221 114 69     SPACE eurjchem-221 114 70 as as SCONJ eurjchem-221 114 71     SPACE eurjchem-221 114 72 the the DET eurjchem-221 114 73     SPACE eurjchem-221 114 74 reaction reaction NOUN eurjchem-221 114 75     SPACE eurjchem-221 114 76 occurred occur VERB eurjchem-221 114 77     SPACE eurjchem-221 114 78 ( ( PUNCT eurjchem-221 114 79 figure figure NOUN eurjchem-221 114 80     SPACE eurjchem-221 114 81 5 5 NUM eurjchem-221 114 82 ) ) PUNCT eurjchem-221 114 83 . . PUNCT eurjchem-221 114 84     SPACE eurjchem-221 115 1 contrary contrary NOUN eurjchem-221 115 2     SPACE eurjchem-221 115 3 to to ADP eurjchem-221 115 4     SPACE eurjchem-221 115 5 the the DET eurjchem-221 115 6     SPACE eurjchem-221 115 7 reaction reaction NOUN eurjchem-221 115 8     SPACE eurjchem-221 115 9 of of ADP eurjchem-221 115 10     SPACE eurjchem-221 115 11 ( ( PUNCT eurjchem-221 115 12 a a NOUN eurjchem-221 115 13 ) ) PUNCT eurjchem-221 115 14     SPACE eurjchem-221 115 15 with with ADP eurjchem-221 115 16     SPACE eurjchem-221 115 17 catalyst catalyst NOUN eurjchem-221 115 18     SPACE eurjchem-221 115 19 1 1 NUM eurjchem-221 115 20 , , PUNCT eurjchem-221 115 21     SPACE eurjchem-221 115 22 a a DET eurjchem-221 115 23     SPACE eurjchem-221 115 24 free free ADJ eurjchem-221 115 25     SPACE eurjchem-221 115 26 radical radical ADJ eurjchem-221 115 27     SPACE eurjchem-221 115 28 signal signal NOUN eurjchem-221 115 29     SPACE eurjchem-221 115 30 and and CCONJ eurjchem-221 115 31     SPACE eurjchem-221 115 32 new new ADJ eurjchem-221 115 33     SPACE eurjchem-221 115 34 copper copper NOUN eurjchem-221 115 35     SPACE eurjchem-221 115 36 specie specie NOUN eurjchem-221 115 37     SPACE eurjchem-221 115 38 did do AUX eurjchem-221 115 39     SPACE eurjchem-221 115 40 not not PART eurjchem-221 115 41     SPACE eurjchem-221 115 42 appear appear VERB eurjchem-221 115 43     SPACE eurjchem-221 115 44 as as SCONJ eurjchem-221 115 45     SPACE eurjchem-221 115 46 the the DET eurjchem-221 115 47     SPACE eurjchem-221 115 48 reaction reaction NOUN eurjchem-221 115 49     SPACE eurjchem-221 115 50 was be AUX eurjchem-221 115 51     SPACE eurjchem-221 115 52 in in ADP eurjchem-221 115 53     SPACE eurjchem-221 115 54 progress progress NOUN eurjchem-221 115 55     SPACE eurjchem-221 115 56 indicating indicate VERB eurjchem-221 115 57     SPACE eurjchem-221 115 58 that that SCONJ eurjchem-221 115 59     SPACE eurjchem-221 115 60 the the DET eurjchem-221 115 61     SPACE eurjchem-221 115 62 product product NOUN eurjchem-221 115 63     SPACE eurjchem-221 115 64 does do AUX eurjchem-221 115 65     SPACE eurjchem-221 115 66 not not PART eurjchem-221 115 67     SPACE eurjchem-221 115 68 react react VERB eurjchem-221 115 69     SPACE eurjchem-221 115 70 with with ADP eurjchem-221 115 71     SPACE eurjchem-221 115 72 the the DET eurjchem-221 115 73     SPACE eurjchem-221 115 74 catalyst catalyst NOUN eurjchem-221 115 75 . . PUNCT eurjchem-221 115 76           SPACE eurjchem-221 116 1 sabarinathan sabarinathan PROPN eurjchem-221 116 2     SPACE eurjchem-221 116 3 et et NOUN eurjchem-221 116 4     SPACE eurjchem-221 116 5 al al PROPN eurjchem-221 116 6 . . PROPN eurjchem-221 116 7     SPACE eurjchem-221 116 8 / / SYM eurjchem-221 116 9     SPACE eurjchem-221 116 10 european european ADJ eurjchem-221 116 11     SPACE eurjchem-221 116 12 journal journal NOUN eurjchem-221 116 13     SPACE eurjchem-221 116 14 of of ADP eurjchem-221 116 15     SPACE eurjchem-221 116 16 chemistry chemistry NOUN eurjchem-221 116 17     SPACE eurjchem-221 116 18 1 1 NUM eurjchem-221 116 19     SPACE eurjchem-221 116 20 ( ( PUNCT eurjchem-221 116 21 4 4 NUM eurjchem-221 116 22 ) ) PUNCT eurjchem-221 116 23     SPACE eurjchem-221 116 24 ( ( PUNCT eurjchem-221 116 25 2010 2010 NUM eurjchem-221 116 26 ) ) PUNCT eurjchem-221 116 27     SPACE eurjchem-221 117 1 360­367 360­367 NUM eurjchem-221 117 2     SPACE eurjchem-221 117 3 365 365 NUM eurjchem-221 117 4             SPACE eurjchem-221 117 5 figure figure NOUN eurjchem-221 117 6     SPACE eurjchem-221 117 7 3 3 NUM eurjchem-221 117 8 . . PUNCT eurjchem-221 117 9 epr epr PROPN eurjchem-221 117 10     SPACE eurjchem-221 117 11 monitoring monitoring NOUN eurjchem-221 117 12     SPACE eurjchem-221 117 13 of of ADP eurjchem-221 117 14     SPACE eurjchem-221 117 15 complex complex NOUN eurjchem-221 117 16     SPACE eurjchem-221 117 17 1 1 NUM eurjchem-221 117 18     SPACE eurjchem-221 117 19 with with ADP eurjchem-221 117 20     SPACE eurjchem-221 117 21 ( ( PUNCT eurjchem-221 117 22 a a NOUN eurjchem-221 117 23 ) ) PUNCT eurjchem-221 117 24 . . PUNCT eurjchem-221 117 25     SPACE eurjchem-221 117 26 ( ( PUNCT eurjchem-221 117 27 3a 3a NUM eurjchem-221 117 28 ) ) PUNCT eurjchem-221 117 29     SPACE eurjchem-221 117 30 complex complex NOUN eurjchem-221 117 31     SPACE eurjchem-221 117 32 in in ADP eurjchem-221 117 33     SPACE eurjchem-221 117 34 chlorobenzene chlorobenzene NOUN eurjchem-221 117 35 ; ; PUNCT eurjchem-221 117 36     SPACE eurjchem-221 117 37 ( ( PUNCT eurjchem-221 117 38 3b 3b NUM eurjchem-221 117 39 ) ) PUNCT eurjchem-221 117 40     SPACE eurjchem-221 117 41 after after ADP eurjchem-221 117 42     SPACE eurjchem-221 117 43 addition addition NOUN eurjchem-221 117 44     SPACE eurjchem-221 117 45 of of ADP eurjchem-221 117 46     SPACE eurjchem-221 117 47 2‐naphthol 2‐naphthol NOUN eurjchem-221 117 48 ; ; PUNCT eurjchem-221 117 49     SPACE eurjchem-221 117 50 ( ( PUNCT eurjchem-221 117 51 3c 3c NUM eurjchem-221 117 52 ) ) PUNCT eurjchem-221 117 53     SPACE eurjchem-221 117 54 30 30 NUM eurjchem-221 117 55     SPACE eurjchem-221 117 56 min min NOUN eurjchem-221 117 57 ; ; PUNCT eurjchem-221 117 58     SPACE eurjchem-221 117 59 ( ( PUNCT eurjchem-221 117 60 3d 3d NUM eurjchem-221 117 61 ) ) PUNCT eurjchem-221 117 62     SPACE eurjchem-221 117 63 2.30 2.30 NUM eurjchem-221 117 64     SPACE eurjchem-221 117 65 hr hr NOUN eurjchem-221 117 66 ; ; PUNCT eurjchem-221 117 67     SPACE eurjchem-221 117 68 ( ( PUNCT eurjchem-221 117 69 3e 3e NOUN eurjchem-221 117 70 ) ) PUNCT eurjchem-221 117 71     SPACE eurjchem-221 117 72 3.30 3.30 NUM eurjchem-221 117 73     SPACE eurjchem-221 117 74 hr hr NOUN eurjchem-221 117 75 ; ; PUNCT eurjchem-221 117 76     SPACE eurjchem-221 117 77 ( ( PUNCT eurjchem-221 117 78 3e 3e NOUN eurjchem-221 117 79 ) ) PUNCT eurjchem-221 117 80     SPACE eurjchem-221 117 81 4.30 4.30 NUM eurjchem-221 117 82     SPACE eurjchem-221 117 83 hr hr NOUN eurjchem-221 117 84 ; ; PUNCT eurjchem-221 117 85     SPACE eurjchem-221 117 86 ( ( PUNCT eurjchem-221 117 87 3f 3f PROPN eurjchem-221 117 88 ) ) PUNCT eurjchem-221 117 89     SPACE eurjchem-221 117 90 5.30 5.30 NUM eurjchem-221 117 91     SPACE eurjchem-221 117 92 hr hr NOUN eurjchem-221 117 93 ; ; PUNCT eurjchem-221 117 94     SPACE eurjchem-221 117 95 ( ( PUNCT eurjchem-221 117 96 3 3 NUM eurjchem-221 117 97 g g NOUN eurjchem-221 117 98 ) ) PUNCT eurjchem-221 117 99     SPACE eurjchem-221 117 100 6.15 6.15 NUM eurjchem-221 117 101     SPACE eurjchem-221 117 102 hr hr NOUN eurjchem-221 117 103 ; ; PUNCT eurjchem-221 117 104     SPACE eurjchem-221 117 105 ( ( PUNCT eurjchem-221 117 106 3h 3h NUM eurjchem-221 117 107 ) ) PUNCT eurjchem-221 117 108     SPACE eurjchem-221 117 109 6.45 6.45 NUM eurjchem-221 117 110     SPACE eurjchem-221 117 111 hr hr NOUN eurjchem-221 117 112 ; ; PUNCT eurjchem-221 117 113     SPACE eurjchem-221 117 114 ( ( PUNCT eurjchem-221 117 115 3i 3i NUM eurjchem-221 117 116 ) ) PUNCT eurjchem-221 117 117     SPACE eurjchem-221 117 118 7.30 7.30 NUM eurjchem-221 117 119     SPACE eurjchem-221 117 120 hr hr NOUN eurjchem-221 117 121 ; ; PUNCT eurjchem-221 117 122     SPACE eurjchem-221 117 123 ( ( PUNCT eurjchem-221 117 124 3j 3j NUM eurjchem-221 117 125 ) ) PUNCT eurjchem-221 117 126     SPACE eurjchem-221 117 127 10.00 10.00 NUM eurjchem-221 117 128     SPACE eurjchem-221 117 129 hr hr NOUN eurjchem-221 117 130 ; ; PUNCT eurjchem-221 117 131     SPACE eurjchem-221 117 132 ( ( PUNCT eurjchem-221 117 133 3k 3k NUM eurjchem-221 117 134 ) ) PUNCT eurjchem-221 117 135     SPACE eurjchem-221 117 136 4 4 NUM eurjchem-221 117 137     SPACE eurjchem-221 117 138 days day NOUN eurjchem-221 117 139 . . PUNCT eurjchem-221 117 140         SPACE eurjchem-221 117 141 figure figure NOUN eurjchem-221 117 142     SPACE eurjchem-221 117 143 4 4 NUM eurjchem-221 117 144 . . PUNCT eurjchem-221 118 1 epr epr PROPN eurjchem-221 118 2     SPACE eurjchem-221 118 3 monitoring monitoring NOUN eurjchem-221 118 4     SPACE eurjchem-221 118 5 of of ADP eurjchem-221 118 6     SPACE eurjchem-221 118 7 complex complex NOUN eurjchem-221 118 8     SPACE eurjchem-221 118 9 2 2 NUM eurjchem-221 118 10     SPACE eurjchem-221 118 11 with with ADP eurjchem-221 118 12     SPACE eurjchem-221 118 13 ( ( PUNCT eurjchem-221 118 14 a a NOUN eurjchem-221 118 15 ) ) PUNCT eurjchem-221 118 16 . . PUNCT eurjchem-221 118 17     SPACE eurjchem-221 118 18 ( ( PUNCT eurjchem-221 118 19 4a 4a NUM eurjchem-221 118 20 ) ) PUNCT eurjchem-221 118 21     SPACE eurjchem-221 118 22 complex complex NOUN eurjchem-221 118 23     SPACE eurjchem-221 118 24 in in ADP eurjchem-221 118 25     SPACE eurjchem-221 118 26 chlorobenzene chlorobenzene NOUN eurjchem-221 118 27 ; ; PUNCT eurjchem-221 118 28     SPACE eurjchem-221 118 29 ( ( PUNCT eurjchem-221 118 30 4b 4b PROPN eurjchem-221 118 31 ) ) PUNCT eurjchem-221 118 32     SPACE eurjchem-221 118 33 after after ADP eurjchem-221 118 34     SPACE eurjchem-221 118 35 addition addition NOUN eurjchem-221 118 36     SPACE eurjchem-221 118 37 of of ADP eurjchem-221 118 38     SPACE eurjchem-221 118 39 2‐naphthol 2‐naphthol NOUN eurjchem-221 118 40 ; ; PUNCT eurjchem-221 118 41     SPACE eurjchem-221 118 42 ( ( PUNCT eurjchem-221 118 43 4c 4c NOUN eurjchem-221 118 44 ) ) PUNCT eurjchem-221 118 45     SPACE eurjchem-221 118 46 2.30 2.30 NUM eurjchem-221 118 47     SPACE eurjchem-221 118 48 hr hr NOUN eurjchem-221 118 49 ; ; PUNCT eurjchem-221 118 50     SPACE eurjchem-221 118 51 ( ( PUNCT eurjchem-221 118 52 4d 4d NUM eurjchem-221 118 53 ) ) PUNCT eurjchem-221 118 54     SPACE eurjchem-221 118 55 5.30 5.30 NUM eurjchem-221 118 56     SPACE eurjchem-221 118 57 hr hr NOUN eurjchem-221 118 58 ; ; PUNCT eurjchem-221 118 59     SPACE eurjchem-221 118 60 ( ( PUNCT eurjchem-221 118 61 4e 4e NOUN eurjchem-221 118 62 ) ) PUNCT eurjchem-221 118 63     SPACE eurjchem-221 118 64 25 25 NUM eurjchem-221 118 65     SPACE eurjchem-221 118 66 hr hr NOUN eurjchem-221 118 67 ; ; PUNCT eurjchem-221 118 68     SPACE eurjchem-221 118 69 ( ( PUNCT eurjchem-221 118 70 4f 4f NUM eurjchem-221 118 71 ) ) PUNCT eurjchem-221 118 72     SPACE eurjchem-221 118 73 26.30 26.30 NUM eurjchem-221 118 74     SPACE eurjchem-221 118 75 hr hr NOUN eurjchem-221 118 76 ; ; PUNCT eurjchem-221 118 77     SPACE eurjchem-221 118 78 ( ( PUNCT eurjchem-221 118 79 4 4 NUM eurjchem-221 118 80 g g NOUN eurjchem-221 118 81 ) ) PUNCT eurjchem-221 118 82     SPACE eurjchem-221 118 83 28 28 NUM eurjchem-221 118 84     SPACE eurjchem-221 118 85 hr hr NOUN eurjchem-221 118 86 ; ; PUNCT eurjchem-221 118 87     SPACE eurjchem-221 118 88 ( ( PUNCT eurjchem-221 118 89 4h 4h NUM eurjchem-221 118 90 ) ) PUNCT eurjchem-221 118 91     SPACE eurjchem-221 118 92 34 34 NUM eurjchem-221 118 93     SPACE eurjchem-221 118 94 hr hr NOUN eurjchem-221 118 95 ; ; PUNCT eurjchem-221 118 96     SPACE eurjchem-221 118 97 ( ( PUNCT eurjchem-221 118 98 4i 4i NUM eurjchem-221 118 99 ) ) PUNCT eurjchem-221 118 100     SPACE eurjchem-221 118 101 35 35 NUM eurjchem-221 118 102     SPACE eurjchem-221 118 103 hr hr NOUN eurjchem-221 118 104 ; ; PUNCT eurjchem-221 118 105     SPACE eurjchem-221 118 106 ( ( PUNCT eurjchem-221 118 107 4j 4j NOUN eurjchem-221 118 108 ) ) PUNCT eurjchem-221 118 109     SPACE eurjchem-221 118 110 37.30 37.30 NUM eurjchem-221 118 111     SPACE eurjchem-221 118 112 hr hr NOUN eurjchem-221 118 113 . . PUNCT eurjchem-221 118 114         SPACE eurjchem-221 118 115 figure figure NOUN eurjchem-221 118 116     SPACE eurjchem-221 118 117 5 5 NUM eurjchem-221 118 118 . . PUNCT eurjchem-221 118 119     SPACE eurjchem-221 118 120 epr epr PROPN eurjchem-221 118 121     SPACE eurjchem-221 118 122 monitoring monitoring NOUN eurjchem-221 118 123     SPACE eurjchem-221 118 124 of of ADP eurjchem-221 118 125     SPACE eurjchem-221 118 126 complex complex NOUN eurjchem-221 118 127     SPACE eurjchem-221 118 128 1 1 NUM eurjchem-221 118 129     SPACE eurjchem-221 118 130 with with ADP eurjchem-221 118 131     SPACE eurjchem-221 118 132 ( ( PUNCT eurjchem-221 118 133 b b NOUN eurjchem-221 118 134 ) ) PUNCT eurjchem-221 118 135 . . PUNCT eurjchem-221 118 136     SPACE eurjchem-221 119 1 ( ( PUNCT eurjchem-221 119 2 5a 5a NUM eurjchem-221 119 3 ) ) PUNCT eurjchem-221 119 4     SPACE eurjchem-221 119 5 complex complex NOUN eurjchem-221 119 6     SPACE eurjchem-221 119 7 in in ADP eurjchem-221 119 8     SPACE eurjchem-221 119 9 chlorobenzene chlorobenzene NOUN eurjchem-221 119 10 ; ; PUNCT eurjchem-221 119 11     SPACE eurjchem-221 119 12 ( ( PUNCT eurjchem-221 119 13 5b 5b NUM eurjchem-221 119 14 ) ) PUNCT eurjchem-221 119 15     SPACE eurjchem-221 119 16 after after ADP eurjchem-221 119 17     SPACE eurjchem-221 119 18 addition addition NOUN eurjchem-221 119 19     SPACE eurjchem-221 119 20 of of ADP eurjchem-221 119 21     SPACE eurjchem-221 119 22 2‐naphthol 2‐naphthol NOUN eurjchem-221 119 23 ; ; PUNCT eurjchem-221 119 24     SPACE eurjchem-221 119 25 ( ( PUNCT eurjchem-221 119 26 5c 5c NUM eurjchem-221 119 27 ) ) PUNCT eurjchem-221 119 28     SPACE eurjchem-221 119 29 1.00 1.00 NUM eurjchem-221 119 30     SPACE eurjchem-221 119 31 hr hr NOUN eurjchem-221 119 32 ; ; PUNCT eurjchem-221 119 33     SPACE eurjchem-221 119 34 ( ( PUNCT eurjchem-221 119 35 5d 5d NUM eurjchem-221 119 36 ) ) PUNCT eurjchem-221 119 37     SPACE eurjchem-221 119 38 2.00 2.00 NUM eurjchem-221 119 39     SPACE eurjchem-221 119 40 hr hr NOUN eurjchem-221 119 41 ; ; PUNCT eurjchem-221 119 42     SPACE eurjchem-221 119 43 ( ( PUNCT eurjchem-221 119 44 5e 5e NUM eurjchem-221 119 45 ) ) PUNCT eurjchem-221 119 46     SPACE eurjchem-221 119 47 4.00 4.00 NUM eurjchem-221 119 48     SPACE eurjchem-221 119 49 hr hr NOUN eurjchem-221 119 50 ; ; PUNCT eurjchem-221 119 51     SPACE eurjchem-221 119 52 ( ( PUNCT eurjchem-221 119 53 5f 5f NOUN eurjchem-221 119 54 ) ) PUNCT eurjchem-221 119 55     SPACE eurjchem-221 119 56 7.00 7.00 NUM eurjchem-221 119 57     SPACE eurjchem-221 119 58 hr hr NOUN eurjchem-221 119 59 ; ; PUNCT eurjchem-221 119 60     SPACE eurjchem-221 119 61 ( ( PUNCT eurjchem-221 119 62 5 5 NUM eurjchem-221 119 63 g g NOUN eurjchem-221 119 64 ) ) PUNCT eurjchem-221 119 65     SPACE eurjchem-221 119 66 9.00 9.00 NUM eurjchem-221 119 67     SPACE eurjchem-221 119 68 hr hr NOUN eurjchem-221 119 69 ; ; PUNCT eurjchem-221 119 70     SPACE eurjchem-221 119 71 ( ( PUNCT eurjchem-221 119 72 5h 5h NUM eurjchem-221 119 73 ) ) PUNCT eurjchem-221 119 74     SPACE eurjchem-221 119 75 10.00 10.00 NUM eurjchem-221 119 76     SPACE eurjchem-221 119 77 hr hr NOUN eurjchem-221 119 78 ; ; PUNCT eurjchem-221 119 79     SPACE eurjchem-221 119 80 ( ( PUNCT eurjchem-221 119 81 5i 5i NUM eurjchem-221 119 82 ) ) PUNCT eurjchem-221 119 83     SPACE eurjchem-221 119 84 15 15 NUM eurjchem-221 119 85     SPACE eurjchem-221 119 86 hr hr NOUN eurjchem-221 119 87 ; ; PUNCT eurjchem-221 119 88     SPACE eurjchem-221 119 89 ( ( PUNCT eurjchem-221 119 90 5j 5j NUM eurjchem-221 119 91 ) ) PUNCT eurjchem-221 119 92     SPACE eurjchem-221 119 93 21.00 21.00 NUM eurjchem-221 119 94     SPACE eurjchem-221 119 95 hr hr NOUN eurjchem-221 119 96 ; ; PUNCT eurjchem-221 119 97     SPACE eurjchem-221 119 98 ( ( PUNCT eurjchem-221 119 99 5k 5k NUM eurjchem-221 119 100 ) ) PUNCT eurjchem-221 119 101     SPACE eurjchem-221 119 102 30.00 30.00 NUM eurjchem-221 119 103     SPACE eurjchem-221 119 104 hr hr NOUN eurjchem-221 119 105 ; ; PUNCT eurjchem-221 119 106     SPACE eurjchem-221 119 107 ( ( PUNCT eurjchem-221 119 108 5l 5l NUM eurjchem-221 119 109 ) ) PUNCT eurjchem-221 119 110     SPACE eurjchem-221 119 111 48.00 48.00 NUM eurjchem-221 119 112     SPACE eurjchem-221 119 113 hr hr NOUN eurjchem-221 119 114 . . PUNCT eurjchem-221 119 115     SPACE eurjchem-221 120 1 366 366 NUM eurjchem-221 120 2     SPACE eurjchem-221 120 3 sabarinathan sabarinathan PROPN eurjchem-221 120 4     SPACE eurjchem-221 120 5 et et NOUN eurjchem-221 120 6     SPACE eurjchem-221 120 7 al al PROPN eurjchem-221 120 8 . . PROPN eurjchem-221 120 9     SPACE eurjchem-221 120 10 / / SYM eurjchem-221 120 11     SPACE eurjchem-221 120 12 european european ADJ eurjchem-221 120 13     SPACE eurjchem-221 120 14 journal journal NOUN eurjchem-221 120 15     SPACE eurjchem-221 120 16 of of ADP eurjchem-221 120 17     SPACE eurjchem-221 120 18 chemistry chemistry NOUN eurjchem-221 120 19     SPACE eurjchem-221 120 20 1 1 NUM eurjchem-221 120 21     SPACE eurjchem-221 120 22 ( ( PUNCT eurjchem-221 120 23 4 4 NUM eurjchem-221 120 24 ) ) PUNCT eurjchem-221 120 25     SPACE eurjchem-221 120 26 ( ( PUNCT eurjchem-221 120 27 2010 2010 NUM eurjchem-221 120 28 ) ) PUNCT eurjchem-221 120 29     SPACE eurjchem-221 120 30 360­367 360­367 NUM eurjchem-221 120 31             SPACE eurjchem-221 120 32 figure figure NOUN eurjchem-221 120 33     SPACE eurjchem-221 120 34 6 6 NUM eurjchem-221 120 35 . . PUNCT eurjchem-221 120 36     SPACE eurjchem-221 120 37 chiral chiral ADJ eurjchem-221 120 38     SPACE eurjchem-221 120 39 hplc hplc NOUN eurjchem-221 120 40     SPACE eurjchem-221 120 41 of of ADP eurjchem-221 120 42     SPACE eurjchem-221 120 43 dimethyl dimethyl NOUN eurjchem-221 120 44     SPACE eurjchem-221 120 45 2,2'‐dihydroxy‐1,1'‐binaphthyl‐3,3'‐dicarboxylate 2,2'‐dihydroxy‐1,1'‐binaphthyl‐3,3'‐dicarboxylate PROPN eurjchem-221 120 46 ( ( PUNCT eurjchem-221 120 47 d d NOUN eurjchem-221 120 48 ) ) PUNCT eurjchem-221 120 49     SPACE eurjchem-221 120 50 from from ADP eurjchem-221 120 51     SPACE eurjchem-221 120 52 the the DET eurjchem-221 120 53     SPACE eurjchem-221 120 54 coupling coupling NOUN eurjchem-221 120 55     SPACE eurjchem-221 120 56 of of ADP eurjchem-221 120 57     SPACE eurjchem-221 120 58 ( ( PUNCT eurjchem-221 120 59 b b NOUN eurjchem-221 120 60 ) ) PUNCT eurjchem-221 120 61     SPACE eurjchem-221 120 62 catalyzed catalyze VERB eurjchem-221 120 63     SPACE eurjchem-221 120 64 by by ADP eurjchem-221 120 65     SPACE eurjchem-221 120 66 complex complex NOUN eurjchem-221 120 67     SPACE eurjchem-221 120 68 1 1 NUM eurjchem-221 120 69 . . PUNCT eurjchem-221 120 70         SPACE eurjchem-221 120 71 cu(i cu(i NOUN eurjchem-221 120 72 ) ) PUNCT eurjchem-221 120 73 o o NOUN eurjchem-221 121 1 o o NOUN eurjchem-221 121 2 n n CCONJ eurjchem-221 121 3 no no DET eurjchem-221 121 4 omeo omeo ADJ eurjchem-221 121 5 cu(i cu(i NOUN eurjchem-221 121 6 ) ) PUNCT eurjchem-221 122 1 o o NOUN eurjchem-221 122 2 o o NOUN eurjchem-221 122 3 n n CCONJ eurjchem-221 122 4 no no DET eurjchem-221 122 5 omeo omeo ADJ eurjchem-221 122 6 h h NOUN eurjchem-221 122 7 cu(i cu(i NOUN eurjchem-221 122 8 ) ) PUNCT eurjchem-221 123 1 o o NOUN eurjchem-221 123 2 o o NOUN eurjchem-221 123 3 n n CCONJ eurjchem-221 123 4 n n NOUN eurjchem-221 123 5 o o NOUN eurjchem-221 123 6 o o X eurjchem-221 124 1 ome ome INTJ eurjchem-221 124 2 h h NOUN eurjchem-221 125 1 oh oh INTJ eurjchem-221 126 1 oh oh INTJ eurjchem-221 126 2 o o INTJ eurjchem-221 127 1 ome ome INTJ eurjchem-221 127 2 o o INTJ eurjchem-221 127 3 ome ome NOUN eurjchem-221 127 4 n n CCONJ eurjchem-221 127 5 n n NOUN eurjchem-221 127 6 o o NOUN eurjchem-221 127 7 o o X eurjchem-221 127 8 cu(ii cu(ii PROPN eurjchem-221 127 9 ) ) PUNCT eurjchem-221 128 1 oh oh INTJ eurjchem-221 128 2 o o INTJ eurjchem-221 129 1 ome ome INTJ eurjchem-221 129 2 2 2 NUM eurjchem-221 129 3 2h 2h NUM eurjchem-221 129 4 1/2 1/2 NUM eurjchem-221 129 5 o2 o2 ADJ eurjchem-221 129 6 2 2 NUM eurjchem-221 129 7 2 2 NUM eurjchem-221 129 8 h2o h2o NOUN eurjchem-221 129 9         SPACE eurjchem-221 129 10 scheme scheme NOUN eurjchem-221 129 11     SPACE eurjchem-221 129 12 4 4 NUM eurjchem-221 129 13         SPACE eurjchem-221 129 14 the the DET eurjchem-221 129 15     SPACE eurjchem-221 129 16 observed observe VERB eurjchem-221 129 17     SPACE eurjchem-221 129 18 enationselectivity enationselectivity NOUN eurjchem-221 129 19     SPACE eurjchem-221 129 20 supports support VERB eurjchem-221 129 21     SPACE eurjchem-221 129 22 that that SCONJ eurjchem-221 129 23     SPACE eurjchem-221 129 24 the the DET eurjchem-221 129 25     SPACE eurjchem-221 129 26 reaction reaction NOUN eurjchem-221 129 27     SPACE eurjchem-221 129 28 involves involve VERB eurjchem-221 129 29     SPACE eurjchem-221 129 30 the the DET eurjchem-221 129 31     SPACE eurjchem-221 129 32 participation participation NOUN eurjchem-221 129 33     SPACE eurjchem-221 129 34 of of ADP eurjchem-221 129 35     SPACE eurjchem-221 129 36 the the DET eurjchem-221 129 37     SPACE eurjchem-221 129 38 catalyst catalyst NOUN eurjchem-221 129 39 , , PUNCT eurjchem-221 129 40     SPACE eurjchem-221 129 41 but but CCONJ eurjchem-221 129 42     SPACE eurjchem-221 129 43 binding bind VERB eurjchem-221 129 44     SPACE eurjchem-221 129 45 of of ADP eurjchem-221 129 46     SPACE eurjchem-221 129 47 the the DET eurjchem-221 129 48     SPACE eurjchem-221 129 49 substrate substrate NOUN eurjchem-221 129 50     SPACE eurjchem-221 129 51 with with ADP eurjchem-221 129 52     SPACE eurjchem-221 129 53 the the DET eurjchem-221 129 54     SPACE eurjchem-221 129 55 complex complex NOUN eurjchem-221 129 56     SPACE eurjchem-221 129 57 is be AUX eurjchem-221 129 58     SPACE eurjchem-221 129 59 not not PART eurjchem-221 129 60     SPACE eurjchem-221 129 61 detectable detectable ADJ eurjchem-221 129 62     SPACE eurjchem-221 129 63 by by ADP eurjchem-221 129 64     SPACE eurjchem-221 129 65 epr epr PROPN eurjchem-221 129 66 . . PUNCT eurjchem-221 129 67     SPACE eurjchem-221 129 68 lack lack NOUN eurjchem-221 129 69     SPACE eurjchem-221 129 70 of of ADP eurjchem-221 129 71     SPACE eurjchem-221 129 72 stereoselectivity stereoselectivity NOUN eurjchem-221 129 73     SPACE eurjchem-221 129 74 of of ADP eurjchem-221 129 75     SPACE eurjchem-221 129 76 the the DET eurjchem-221 129 77     SPACE eurjchem-221 129 78 reaction reaction NOUN eurjchem-221 129 79     SPACE eurjchem-221 129 80 of of ADP eurjchem-221 129 81     SPACE eurjchem-221 129 82 ( ( PUNCT eurjchem-221 129 83 b b NOUN eurjchem-221 129 84 ) ) PUNCT eurjchem-221 129 85     SPACE eurjchem-221 129 86 with with ADP eurjchem-221 129 87     SPACE eurjchem-221 129 88 catalysts catalyst NOUN eurjchem-221 129 89     SPACE eurjchem-221 129 90 2 2 NUM eurjchem-221 129 91     SPACE eurjchem-221 129 92 and and CCONJ eurjchem-221 129 93     SPACE eurjchem-221 129 94 3 3 NUM eurjchem-221 129 95     SPACE eurjchem-221 129 96 can can AUX eurjchem-221 129 97     SPACE eurjchem-221 129 98 be be AUX eurjchem-221 129 99     SPACE eurjchem-221 129 100 attributed attribute VERB eurjchem-221 129 101     SPACE eurjchem-221 129 102 to to ADP eurjchem-221 129 103     SPACE eurjchem-221 129 104 the the DET eurjchem-221 129 105     SPACE eurjchem-221 129 106 steric steric ADJ eurjchem-221 129 107     SPACE eurjchem-221 129 108 crowding crowd VERB eurjchem-221 129 109     SPACE eurjchem-221 129 110 around around ADP eurjchem-221 129 111     SPACE eurjchem-221 129 112 the the DET eurjchem-221 129 113     SPACE eurjchem-221 129 114 metal metal NOUN eurjchem-221 129 115     SPACE eurjchem-221 129 116 center center NOUN eurjchem-221 129 117     SPACE eurjchem-221 129 118 preventing prevent VERB eurjchem-221 129 119     SPACE eurjchem-221 129 120 the the DET eurjchem-221 129 121     SPACE eurjchem-221 129 122 chelation chelation NOUN eurjchem-221 129 123     SPACE eurjchem-221 129 124 of of ADP eurjchem-221 129 125     SPACE eurjchem-221 129 126 the the DET eurjchem-221 129 127     SPACE eurjchem-221 129 128 substrate substrate NOUN eurjchem-221 129 129     SPACE eurjchem-221 129 130 with with ADP eurjchem-221 129 131     SPACE eurjchem-221 129 132 the the DET eurjchem-221 129 133     SPACE eurjchem-221 129 134 complex complex NOUN eurjchem-221 129 135 . . PUNCT eurjchem-221 129 136         SPACE eurjchem-221 130 1 4 4 NUM eurjchem-221 130 2 . . PUNCT eurjchem-221 130 3     SPACE eurjchem-221 130 4 conclusion conclusion NOUN eurjchem-221 130 5         SPACE eurjchem-221 130 6 cu(ii cu(ii PROPN eurjchem-221 130 7 ) ) PUNCT eurjchem-221 130 8     SPACE eurjchem-221 130 9 salen salen PROPN eurjchem-221 130 10     SPACE eurjchem-221 130 11 complexes complex NOUN eurjchem-221 130 12     SPACE eurjchem-221 130 13 can can AUX eurjchem-221 130 14     SPACE eurjchem-221 130 15 be be AUX eurjchem-221 130 16     SPACE eurjchem-221 130 17 used use VERB eurjchem-221 130 18     SPACE eurjchem-221 130 19 as as ADP eurjchem-221 130 20     SPACE eurjchem-221 130 21 catalysts catalyst NOUN eurjchem-221 130 22     SPACE eurjchem-221 130 23 to to PART eurjchem-221 130 24     SPACE eurjchem-221 130 25 bring bring VERB eurjchem-221 130 26     SPACE eurjchem-221 130 27 out out ADP eurjchem-221 130 28     SPACE eurjchem-221 130 29 oxidative oxidative ADJ eurjchem-221 130 30     SPACE eurjchem-221 130 31 coupling coupling NOUN eurjchem-221 130 32     SPACE eurjchem-221 130 33 of of ADP eurjchem-221 130 34     SPACE eurjchem-221 130 35 2‐naphthol 2‐naphthol NOUN eurjchem-221 130 36     SPACE eurjchem-221 130 37 derivatives derivative NOUN eurjchem-221 130 38 . . PUNCT eurjchem-221 130 39     SPACE eurjchem-221 131 1 the the DET eurjchem-221 131 2     SPACE eurjchem-221 131 3 catalytic catalytic ADJ eurjchem-221 131 4     SPACE eurjchem-221 131 5 efficiency efficiency NOUN eurjchem-221 131 6     SPACE eurjchem-221 131 7 depends depend VERB eurjchem-221 131 8     SPACE eurjchem-221 131 9 on on ADP eurjchem-221 131 10     SPACE eurjchem-221 131 11 the the DET eurjchem-221 131 12     SPACE eurjchem-221 131 13 extent extent NOUN eurjchem-221 131 14     SPACE eurjchem-221 131 15 of of ADP eurjchem-221 131 16     SPACE eurjchem-221 131 17 the the DET eurjchem-221 131 18     SPACE eurjchem-221 131 19 distortion distortion NOUN eurjchem-221 131 20     SPACE eurjchem-221 131 21 around around ADP eurjchem-221 131 22     SPACE eurjchem-221 131 23 cu(ii cu(ii PROPN eurjchem-221 131 24 ) ) PUNCT eurjchem-221 131 25 . . PUNCT eurjchem-221 131 26     SPACE eurjchem-221 132 1 the the DET eurjchem-221 132 2     SPACE eurjchem-221 132 3 stereoselectivity stereoselectivity NOUN eurjchem-221 132 4     SPACE eurjchem-221 132 5 of of ADP eurjchem-221 132 6     SPACE eurjchem-221 132 7 the the DET eurjchem-221 132 8     SPACE eurjchem-221 132 9 reaction reaction NOUN eurjchem-221 132 10     SPACE eurjchem-221 132 11 is be AUX eurjchem-221 132 12     SPACE eurjchem-221 132 13 influenced influence VERB eurjchem-221 132 14     SPACE eurjchem-221 132 15 by by ADP eurjchem-221 132 16     SPACE eurjchem-221 132 17 the the DET eurjchem-221 132 18     SPACE eurjchem-221 132 19 nature nature NOUN eurjchem-221 132 20     SPACE eurjchem-221 132 21 of of ADP eurjchem-221 132 22     SPACE eurjchem-221 132 23 substituent substituent NOUN eurjchem-221 132 24     SPACE eurjchem-221 132 25 on on ADP eurjchem-221 132 26     SPACE eurjchem-221 132 27 the the DET eurjchem-221 132 28     SPACE eurjchem-221 132 29 substrate substrate NOUN eurjchem-221 132 30     SPACE eurjchem-221 132 31 as as ADV eurjchem-221 132 32     SPACE eurjchem-221 132 33 well well ADV eurjchem-221 132 34     SPACE eurjchem-221 132 35 as as ADP eurjchem-221 132 36     SPACE eurjchem-221 132 37 the the DET eurjchem-221 132 38     SPACE eurjchem-221 132 39 steric steric ADJ eurjchem-221 132 40     SPACE eurjchem-221 132 41 crowding crowd VERB eurjchem-221 132 42     SPACE eurjchem-221 132 43 around around ADP eurjchem-221 132 44     SPACE eurjchem-221 132 45 the the DET eurjchem-221 132 46     SPACE eurjchem-221 132 47 metal metal NOUN eurjchem-221 132 48     SPACE eurjchem-221 132 49 center center NOUN eurjchem-221 132 50 . . PUNCT eurjchem-221 132 51     SPACE eurjchem-221 132 52 biaryl biaryl NOUN eurjchem-221 132 53     SPACE eurjchem-221 132 54 coupling coupling NOUN eurjchem-221 132 55     SPACE eurjchem-221 132 56 favors favor VERB eurjchem-221 132 57     SPACE eurjchem-221 132 58 the the DET eurjchem-221 132 59     SPACE eurjchem-221 132 60 formation formation NOUN eurjchem-221 132 61     SPACE eurjchem-221 132 62 of of ADP eurjchem-221 132 63     SPACE eurjchem-221 132 64 cross cross VERB eurjchem-221 132 65     SPACE eurjchem-221 132 66 coupled couple VERB eurjchem-221 132 67     SPACE eurjchem-221 132 68 product product NOUN eurjchem-221 132 69 . . PUNCT eurjchem-221 132 70               SPACE eurjchem-221 133 1 acknowledgement acknowledgement NOUN eurjchem-221 133 2         SPACE eurjchem-221 133 3 g.v g.v PROPN eurjchem-221 133 4 . . PROPN eurjchem-221 133 5     SPACE eurjchem-221 133 6 thanks thank NOUN eurjchem-221 133 7     SPACE eurjchem-221 133 8 the the DET eurjchem-221 133 9     SPACE eurjchem-221 133 10 university university NOUN eurjchem-221 133 11     SPACE eurjchem-221 133 12 grants grant NOUN eurjchem-221 133 13     SPACE eurjchem-221 133 14 commission commission NOUN eurjchem-221 133 15     SPACE eurjchem-221 133 16 ( ( PUNCT eurjchem-221 133 17 ugc ugc PROPN eurjchem-221 133 18 ) ) PUNCT eurjchem-221 133 19     SPACE eurjchem-221 134 1 f. f. PROPN eurjchem-221 134 2     SPACE eurjchem-221 134 3 no no INTJ eurjchem-221 134 4 . . PUNCT eurjchem-221 134 5     SPACE eurjchem-221 135 1 32‐238/2006(sr 32‐238/2006(sr NUM eurjchem-221 135 2 ) ) PUNCT eurjchem-221 135 3 ) ) PUNCT eurjchem-221 135 4     SPACE eurjchem-221 135 5 & & CCONJ eurjchem-221 135 6     SPACE eurjchem-221 135 7 department department NOUN eurjchem-221 135 8     SPACE eurjchem-221 135 9 of of ADP eurjchem-221 135 10     SPACE eurjchem-221 135 11 science science NOUN eurjchem-221 135 12     SPACE eurjchem-221 135 13 and and CCONJ eurjchem-221 135 14     SPACE eurjchem-221 135 15 technology technology NOUN eurjchem-221 135 16     SPACE eurjchem-221 135 17 ( ( PUNCT eurjchem-221 135 18 dst dst PROPN eurjchem-221 135 19 ) ) PUNCT eurjchem-221 135 20 , , PUNCT eurjchem-221 135 21     SPACE eurjchem-221 135 22 government government NOUN eurjchem-221 135 23     SPACE eurjchem-221 135 24 of of ADP eurjchem-221 135 25     SPACE eurjchem-221 135 26 india india PROPN eurjchem-221 135 27 , , PUNCT eurjchem-221 135 28     SPACE eurjchem-221 135 29 new new ADJ eurjchem-221 135 30     SPACE eurjchem-221 135 31 delhi delhi PROPN eurjchem-221 135 32     SPACE eurjchem-221 135 33 for for ADP eurjchem-221 135 34     SPACE eurjchem-221 135 35 financial financial ADJ eurjchem-221 135 36     SPACE eurjchem-221 135 37 support support NOUN eurjchem-221 135 38 . . PUNCT eurjchem-221 135 39         SPACE eurjchem-221 136 1 references reference NOUN eurjchem-221 136 2         SPACE eurjchem-221 136 3 [ [ X eurjchem-221 136 4 1 1 NUM eurjchem-221 136 5 ] ] PUNCT eurjchem-221 136 6 . . PUNCT eurjchem-221 137 1 venkataramanan venkataramanan PROPN eurjchem-221 137 2 , , PUNCT eurjchem-221 137 3     SPACE eurjchem-221 137 4 n. n. PROPN eurjchem-221 137 5     SPACE eurjchem-221 137 6 s. s. PROPN eurjchem-221 137 7 ; ; PUNCT eurjchem-221 137 8     SPACE eurjchem-221 137 9 kuppuraj kuppuraj NOUN eurjchem-221 137 10 , , PUNCT eurjchem-221 137 11     SPACE eurjchem-221 137 12 g. g. NOUN eurjchem-221 137 13 ; ; PUNCT eurjchem-221 137 14     SPACE eurjchem-221 137 15 rajagopal rajagopal NOUN eurjchem-221 137 16 , , PUNCT eurjchem-221 137 17     SPACE eurjchem-221 137 18 s. s. PROPN eurjchem-221 137 19     SPACE eurjchem-221 137 20 coord coord NOUN eurjchem-221 137 21 . . PUNCT eurjchem-221 137 22     SPACE eurjchem-221 137 23 chem chem NOUN eurjchem-221 137 24 . . PUNCT eurjchem-221 137 25     SPACE eurjchem-221 137 26 rev rev VERB eurjchem-221 137 27 . . PROPN eurjchem-221 137 28     SPACE eurjchem-221 137 29 2005 2005 NUM eurjchem-221 137 30 , , PUNCT eurjchem-221 137 31     SPACE eurjchem-221 137 32 249 249 NUM eurjchem-221 137 33 , , PUNCT eurjchem-221 137 34     SPACE eurjchem-221 137 35 1249‐1268 1249‐1268 NUM eurjchem-221 137 36 . . PUNCT eurjchem-221 137 37     SPACE eurjchem-221 138 1 [ [ X eurjchem-221 138 2 2 2 NUM eurjchem-221 138 3 ] ] PUNCT eurjchem-221 138 4 . . PUNCT eurjchem-221 139 1 baleizão baleizão PROPN eurjchem-221 139 2 , , PUNCT eurjchem-221 139 3     SPACE eurjchem-221 139 4 c c NOUN eurjchem-221 139 5 ; ; PUNCT eurjchem-221 139 6     SPACE eurjchem-221 139 7 garcia garcia PROPN eurjchem-221 139 8 , , PUNCT eurjchem-221 139 9     SPACE eurjchem-221 139 10 h. h. NOUN eurjchem-221 139 11     SPACE eurjchem-221 139 12 chem chem NOUN eurjchem-221 139 13 . . PUNCT eurjchem-221 139 14     SPACE eurjchem-221 139 15 rev rev VERB eurjchem-221 139 16 . . PUNCT eurjchem-221 139 17     SPACE eurjchem-221 139 18 2006 2006 NUM eurjchem-221 139 19 , , PUNCT eurjchem-221 139 20     SPACE eurjchem-221 139 21 106 106 NUM eurjchem-221 139 22 , , PUNCT eurjchem-221 139 23     SPACE eurjchem-221 139 24 3987‐4043 3987‐4043 NUM eurjchem-221 139 25 . . PUNCT eurjchem-221 139 26     SPACE eurjchem-221 140 1 [ [ X eurjchem-221 140 2 3 3 NUM eurjchem-221 140 3 ] ] PUNCT eurjchem-221 140 4 . . PUNCT eurjchem-221 141 1 achard achard NOUN eurjchem-221 141 2 , , PUNCT eurjchem-221 141 3     SPACE eurjchem-221 141 4 t. t. PROPN eurjchem-221 141 5     SPACE eurjchem-221 141 6 r. r. PROPN eurjchem-221 141 7     SPACE eurjchem-221 141 8 j. j. PROPN eurjchem-221 141 9 ; ; PUNCT eurjchem-221 141 10     SPACE eurjchem-221 141 11 clutterbuck clutterbuck NOUN eurjchem-221 141 12 , , PUNCT eurjchem-221 141 13     SPACE eurjchem-221 141 14 l. l. PROPN eurjchem-221 141 15     SPACE eurjchem-221 141 16 a. a. NOUN eurjchem-221 141 17 ; ; PUNCT eurjchem-221 141 18     SPACE eurjchem-221 141 19 north north NOUN eurjchem-221 141 20 , , PUNCT eurjchem-221 141 21     SPACE eurjchem-221 141 22 m. m. NOUN eurjchem-221 141 23     SPACE eurjchem-221 141 24 synlett synlett NOUN eurjchem-221 141 25     SPACE eurjchem-221 141 26 2005 2005 NUM eurjchem-221 141 27 , , PUNCT eurjchem-221 141 28     SPACE eurjchem-221 141 29 12 12 NUM eurjchem-221 141 30 , , PUNCT eurjchem-221 141 31     SPACE eurjchem-221 141 32 1828‐ 1828‐ NUM eurjchem-221 141 33 1847 1847 NUM eurjchem-221 141 34 . . PUNCT eurjchem-221 141 35     SPACE eurjchem-221 142 1 [ [ X eurjchem-221 142 2 4 4 NUM eurjchem-221 142 3 ] ] PUNCT eurjchem-221 142 4 . . PUNCT eurjchem-221 143 1 gupta gupta PROPN eurjchem-221 143 2 , , PUNCT eurjchem-221 143 3     SPACE eurjchem-221 143 4 k. k. PROPN eurjchem-221 143 5     SPACE eurjchem-221 143 6 c. c. PROPN eurjchem-221 143 7 ; ; PUNCT eurjchem-221 143 8     SPACE eurjchem-221 143 9 sutar sutar NOUN eurjchem-221 143 10     SPACE eurjchem-221 143 11 a.k a.k PROPN eurjchem-221 143 12 . . PROPN eurjchem-221 143 13     SPACE eurjchem-221 143 14 coord coord NOUN eurjchem-221 143 15 . . PUNCT eurjchem-221 143 16     SPACE eurjchem-221 143 17 chem chem NOUN eurjchem-221 143 18 . . PUNCT eurjchem-221 143 19     SPACE eurjchem-221 143 20 rev rev VERB eurjchem-221 143 21 . . PUNCT eurjchem-221 143 22     SPACE eurjchem-221 143 23 2008 2008 NUM eurjchem-221 143 24 , , PUNCT eurjchem-221 143 25     SPACE eurjchem-221 143 26 252 252 NUM eurjchem-221 143 27 , , PUNCT eurjchem-221 143 28     SPACE eurjchem-221 143 29 1420‐1450 1420‐1450 NUM eurjchem-221 143 30 . . PUNCT eurjchem-221 143 31     SPACE eurjchem-221 144 1 [ [ X eurjchem-221 144 2 5 5 NUM eurjchem-221 144 3 ] ] PUNCT eurjchem-221 144 4 . . PUNCT eurjchem-221 145 1 cozzi cozzi PROPN eurjchem-221 145 2 , , PUNCT eurjchem-221 145 3     SPACE eurjchem-221 145 4 p.g p.g PROPN eurjchem-221 145 5 . . PROPN eurjchem-221 145 6     SPACE eurjchem-221 145 7 chem chem NOUN eurjchem-221 145 8 . . PUNCT eurjchem-221 145 9     SPACE eurjchem-221 145 10 soc soc PROPN eurjchem-221 145 11 . . PUNCT eurjchem-221 145 12     SPACE eurjchem-221 145 13 rev rev VERB eurjchem-221 145 14 . . PUNCT eurjchem-221 145 15     SPACE eurjchem-221 145 16 2004 2004 NUM eurjchem-221 145 17 , , PUNCT eurjchem-221 145 18     SPACE eurjchem-221 145 19 33 33 NUM eurjchem-221 145 20 , , PUNCT eurjchem-221 145 21     SPACE eurjchem-221 145 22 410‐421 410‐421 NOUN eurjchem-221 145 23 . . PUNCT eurjchem-221 145 24     SPACE eurjchem-221 146 1 [ [ X eurjchem-221 146 2 6 6 NUM eurjchem-221 146 3 ] ] PUNCT eurjchem-221 146 4 . . PUNCT eurjchem-221 147 1 traa traa PROPN eurjchem-221 147 2 , , PUNCT eurjchem-221 147 3     SPACE eurjchem-221 147 4 y y PROPN eurjchem-221 147 5 ; ; PUNCT eurjchem-221 147 6     SPACE eurjchem-221 147 7 murphy murphy NOUN eurjchem-221 147 8 , , PUNCT eurjchem-221 147 9     SPACE eurjchem-221 147 10 d. d. PROPN eurjchem-221 147 11     SPACE eurjchem-221 147 12 m. m. NOUN eurjchem-221 147 13 ; ; PUNCT eurjchem-221 147 14     SPACE eurjchem-221 147 15 farley farley PROPN eurjchem-221 147 16 , , PUNCT eurjchem-221 147 17     SPACE eurjchem-221 147 18 r. r. PROPN eurjchem-221 147 19     SPACE eurjchem-221 147 20 d. d. PROPN eurjchem-221 147 21 ; ; PUNCT eurjchem-221 147 22     SPACE eurjchem-221 147 23 hutchings hutching NOUN eurjchem-221 147 24 , , PUNCT eurjchem-221 147 25     SPACE eurjchem-221 147 26 g. g. PROPN eurjchem-221 147 27     SPACE eurjchem-221 147 28 j. j. PROPN eurjchem-221 147 29     SPACE eurjchem-221 147 30 phys phy NOUN eurjchem-221 147 31 . . PUNCT eurjchem-221 147 32     SPACE eurjchem-221 147 33 chem chem NOUN eurjchem-221 147 34 . . PUNCT eurjchem-221 147 35     SPACE eurjchem-221 147 36 chem chem NOUN eurjchem-221 147 37 . . PUNCT eurjchem-221 147 38     SPACE eurjchem-221 148 1 phys phy NOUN eurjchem-221 148 2 . . PUNCT eurjchem-221 148 3     SPACE eurjchem-221 148 4 2001 2001 NUM eurjchem-221 148 5 , , PUNCT eurjchem-221 148 6     SPACE eurjchem-221 148 7 3 3 NUM eurjchem-221 148 8 , , PUNCT eurjchem-221 148 9     SPACE eurjchem-221 148 10 1073‐1080 1073‐1080 NUM eurjchem-221 148 11 . . PUNCT eurjchem-221 148 12     SPACE eurjchem-221 149 1 [ [ X eurjchem-221 149 2 7 7 NUM eurjchem-221 149 3 ] ] PUNCT eurjchem-221 149 4 . . PUNCT eurjchem-221 150 1 bolm bolm ADJ eurjchem-221 150 2 , , PUNCT eurjchem-221 150 3     SPACE eurjchem-221 150 4 c c NOUN eurjchem-221 150 5 ; ; PUNCT eurjchem-221 150 6     SPACE eurjchem-221 150 7 martin martin PROPN eurjchem-221 150 8 , , PUNCT eurjchem-221 150 9     SPACE eurjchem-221 150 10 m. m. NOUN eurjchem-221 150 11 ; ; PUNCT eurjchem-221 150 12     SPACE eurjchem-221 150 13 gescheidt gescheidt PROPN eurjchem-221 150 14 , , PUNCT eurjchem-221 150 15     SPACE eurjchem-221 150 16 g. g. NOUN eurjchem-221 150 17 ; ; PUNCT eurjchem-221 150 18     SPACE eurjchem-221 150 19 palivan palivan VERB eurjchem-221 150 20 , , PUNCT eurjchem-221 150 21     SPACE eurjchem-221 150 22 c. c. NOUN eurjchem-221 150 23 ; ; PUNCT eurjchem-221 150 24     SPACE eurjchem-221 150 25 neshchadin neshchadin PROPN eurjchem-221 150 26 , , PUNCT eurjchem-221 150 27     SPACE eurjchem-221 150 28 d. d. PROPN eurjchem-221 150 29 ; ; PUNCT eurjchem-221 150 30     SPACE eurjchem-221 150 31 bertagnolli bertagnolli NOUN eurjchem-221 150 32 , , PUNCT eurjchem-221 150 33     SPACE eurjchem-221 150 34 h. h. PROPN eurjchem-221 150 35 ; ; PUNCT eurjchem-221 150 36     SPACE eurjchem-221 150 37 feth feth ADJ eurjchem-221 150 38 , , PUNCT eurjchem-221 150 39     SPACE eurjchem-221 150 40 m. m. NOUN eurjchem-221 150 41 ; ; PUNCT eurjchem-221 150 42     SPACE eurjchem-221 150 43 schweiger schweiger NOUN eurjchem-221 150 44 , , PUNCT eurjchem-221 150 45     SPACE eurjchem-221 150 46 a. a. NOUN eurjchem-221 150 47 ; ; PUNCT eurjchem-221 150 48     SPACE eurjchem-221 150 49 mitrikas mitrikas NOUN eurjchem-221 150 50 , , PUNCT eurjchem-221 150 51     SPACE eurjchem-221 150 52 g. g. NOUN eurjchem-221 150 53 ; ; PUNCT eurjchem-221 150 54     SPACE eurjchem-221 150 55 harmer harmer PROPN eurjchem-221 150 56     SPACE eurjchem-221 150 57 j. j. PROPN eurjchem-221 150 58     SPACE eurjchem-221 150 59 j j PROPN eurjchem-221 150 60     SPACE eurjchem-221 150 61 am be AUX eurjchem-221 150 62 . . PUNCT eurjchem-221 150 63     SPACE eurjchem-221 150 64 chem chem NOUN eurjchem-221 150 65 . . PUNCT eurjchem-221 150 66     SPACE eurjchem-221 150 67 soc soc PROPN eurjchem-221 150 68 . . PUNCT eurjchem-221 150 69     SPACE eurjchem-221 150 70 2003 2003 NUM eurjchem-221 150 71 , , PUNCT eurjchem-221 150 72     SPACE eurjchem-221 150 73 125 125 NUM eurjchem-221 150 74 , , PUNCT eurjchem-221 150 75     SPACE eurjchem-221 150 76 6222‐6227 6222‐6227 PROPN eurjchem-221 150 77 . . PUNCT eurjchem-221 150 78     SPACE eurjchem-221 151 1 sabarinathan sabarinathan PROPN eurjchem-221 151 2     SPACE eurjchem-221 151 3 et et NOUN eurjchem-221 151 4     SPACE eurjchem-221 151 5 al al PROPN eurjchem-221 151 6 . . PROPN eurjchem-221 151 7     SPACE eurjchem-221 151 8 / / SYM eurjchem-221 151 9     SPACE eurjchem-221 151 10 european european ADJ eurjchem-221 151 11     SPACE eurjchem-221 151 12 journal journal NOUN eurjchem-221 151 13     SPACE eurjchem-221 151 14 of of ADP eurjchem-221 151 15     SPACE eurjchem-221 151 16 chemistry chemistry NOUN eurjchem-221 151 17     SPACE eurjchem-221 151 18 1 1 NUM eurjchem-221 151 19     SPACE eurjchem-221 151 20 ( ( PUNCT eurjchem-221 151 21 4 4 NUM eurjchem-221 151 22 ) ) PUNCT eurjchem-221 151 23     SPACE eurjchem-221 151 24 ( ( PUNCT eurjchem-221 151 25 2010 2010 NUM eurjchem-221 151 26 ) ) PUNCT eurjchem-221 151 27     SPACE eurjchem-221 152 1 360­367 360­367 NUM eurjchem-221 152 2     SPACE eurjchem-221 152 3 367 367 NUM eurjchem-221 152 4     SPACE eurjchem-221 152 5 [ [ X eurjchem-221 152 6 8 8 NUM eurjchem-221 152 7 ] ] PUNCT eurjchem-221 152 8 . . PUNCT eurjchem-221 153 1 bolm bolm ADJ eurjchem-221 153 2 , , PUNCT eurjchem-221 153 3     SPACE eurjchem-221 153 4 c. c. NOUN eurjchem-221 153 5 ; ; PUNCT eurjchem-221 153 6     SPACE eurjchem-221 153 7 martin martin PROPN eurjchem-221 153 8 , , PUNCT eurjchem-221 153 9     SPACE eurjchem-221 153 10 m. m. NOUN eurjchem-221 153 11 ; ; PUNCT eurjchem-221 153 12     SPACE eurjchem-221 153 13 gescheidt gescheidt PROPN eurjchem-221 153 14 , , PUNCT eurjchem-221 153 15     SPACE eurjchem-221 153 16 g. g. NOUN eurjchem-221 153 17 ; ; PUNCT eurjchem-221 153 18     SPACE eurjchem-221 153 19 palivan palivan NOUN eurjchem-221 153 20 , , PUNCT eurjchem-221 153 21     SPACE eurjchem-221 153 22 c. c. NOUN eurjchem-221 153 23 ; ; PUNCT eurjchem-221 153 24     SPACE eurjchem-221 153 25 stanoeva stanoeva PROPN eurjchem-221 153 26 , , PUNCT eurjchem-221 153 27     SPACE eurjchem-221 153 28 t. t. PROPN eurjchem-221 153 29 ; ; PUNCT eurjchem-221 153 30     SPACE eurjchem-221 153 31 chem chem NOUN eurjchem-221 153 32 , , PUNCT eurjchem-221 153 33     SPACE eurjchem-221 153 34 d. d. PROPN eurjchem-221 153 35 ; ; PUNCT eurjchem-221 153 36     SPACE eurjchem-221 153 37 bertagnolli bertagnolli NOUN eurjchem-221 153 38 , , PUNCT eurjchem-221 153 39     SPACE eurjchem-221 153 40 h. h. PROPN eurjchem-221 153 41 ; ; PUNCT eurjchem-221 153 42     SPACE eurjchem-221 153 43 feth feth ADJ eurjchem-221 153 44 , , PUNCT eurjchem-221 153 45     SPACE eurjchem-221 153 46 m. m. NOUN eurjchem-221 153 47 ; ; PUNCT eurjchem-221 153 48     SPACE eurjchem-221 153 49 schweiger schweiger NOUN eurjchem-221 153 50 , , PUNCT eurjchem-221 153 51     SPACE eurjchem-221 153 52 a. a. NOUN eurjchem-221 153 53 ; ; PUNCT eurjchem-221 153 54     SPACE eurjchem-221 153 55 mitrikas mitrikas NOUN eurjchem-221 153 56 , , PUNCT eurjchem-221 153 57     SPACE eurjchem-221 153 58 g. g. NOUN eurjchem-221 153 59 ; ; PUNCT eurjchem-221 153 60     SPACE eurjchem-221 153 61 harmer harmer PROPN eurjchem-221 153 62     SPACE eurjchem-221 153 63 j. j. PROPN eurjchem-221 153 64     SPACE eurjchem-221 153 65 chem chem NOUN eurjchem-221 153 66 . . PUNCT eurjchem-221 153 67     SPACE eurjchem-221 154 1 eur eur PROPN eurjchem-221 154 2     SPACE eurjchem-221 154 3 j. j. PROPN eurjchem-221 154 4     SPACE eurjchem-221 154 5 2006 2006 NUM eurjchem-221 154 6 , , PUNCT eurjchem-221 154 7     SPACE eurjchem-221 154 8 13 13 NUM eurjchem-221 154 9 , , PUNCT eurjchem-221 154 10     SPACE eurjchem-221 154 11 1842‐1850 1842‐1850 NOUN eurjchem-221 154 12 . . PUNCT eurjchem-221 154 13     SPACE eurjchem-221 155 1 [ [ X eurjchem-221 155 2 9 9 NUM eurjchem-221 155 3 ] ] PUNCT eurjchem-221 155 4 . . PUNCT eurjchem-221 156 1 doorslaera doorslaera NOUN eurjchem-221 156 2 , , PUNCT eurjchem-221 156 3     SPACE eurjchem-221 156 4 s. s. PROPN eurjchem-221 156 5     SPACE eurjchem-221 156 6 v. v. PROPN eurjchem-221 156 7 ; ; PUNCT eurjchem-221 156 8     SPACE eurjchem-221 156 9 caretti caretti ADJ eurjchem-221 156 10 , , PUNCT eurjchem-221 156 11     SPACE eurjchem-221 156 12 i. i. NOUN eurjchem-221 156 13 ; ; PUNCT eurjchem-221 156 14     SPACE eurjchem-221 156 15 fallis fallis PROPN eurjchem-221 156 16 , , PUNCT eurjchem-221 156 17     SPACE eurjchem-221 156 18 i. i. NOUN eurjchem-221 156 19     SPACE eurjchem-221 156 20 a. a. NOUN eurjchem-221 156 21 ; ; PUNCT eurjchem-221 156 22     SPACE eurjchem-221 156 23 murphy murphy NOUN eurjchem-221 156 24 , , PUNCT eurjchem-221 156 25     SPACE eurjchem-221 156 26 d. d. PROPN eurjchem-221 156 27     SPACE eurjchem-221 156 28 m. m. NOUN eurjchem-221 156 29     SPACE eurjchem-221 156 30 coord coord NOUN eurjchem-221 156 31 . . PUNCT eurjchem-221 156 32     SPACE eurjchem-221 156 33 chem chem NOUN eurjchem-221 156 34 . . PUNCT eurjchem-221 156 35     SPACE eurjchem-221 156 36 rev rev VERB eurjchem-221 156 37 . . PUNCT eurjchem-221 156 38     SPACE eurjchem-221 156 39 2009 2009 NUM eurjchem-221 156 40 , , PUNCT eurjchem-221 156 41     SPACE eurjchem-221 156 42 253 253 NUM eurjchem-221 156 43 , , PUNCT eurjchem-221 156 44     SPACE eurjchem-221 156 45 2116‐2130 2116‐2130 NOUN eurjchem-221 156 46 . . PUNCT eurjchem-221 156 47     SPACE eurjchem-221 157 1 [ [ X eurjchem-221 157 2 10 10 NUM eurjchem-221 157 3 ] ] PUNCT eurjchem-221 157 4 . . PUNCT eurjchem-221 158 1 zhu zhu PROPN eurjchem-221 158 2 , , PUNCT eurjchem-221 158 3     SPACE eurjchem-221 158 4 h. h. PROPN eurjchem-221 158 5     SPACE eurjchem-221 158 6 b. b. PROPN eurjchem-221 158 7 ; ; PUNCT eurjchem-221 158 8     SPACE eurjchem-221 158 9 dai dai PROPN eurjchem-221 158 10 , , PUNCT eurjchem-221 158 11     SPACE eurjchem-221 158 12 z. z. PROPN eurjchem-221 158 13     SPACE eurjchem-221 158 14 y. y. PROPN eurjchem-221 158 15 ; ; PUNCT eurjchem-221 158 16     SPACE eurjchem-221 158 17 huang huang PROPN eurjchem-221 158 18 , , PUNCT eurjchem-221 158 19     SPACE eurjchem-221 158 20 w. w. PROPN eurjchem-221 158 21 ; ; PUNCT eurjchem-221 158 22     SPACE eurjchem-221 158 23 cui cui NOUN eurjchem-221 158 24 , , PUNCT eurjchem-221 158 25     SPACE eurjchem-221 158 26 k. k. PROPN eurjchem-221 158 27 ; ; PUNCT eurjchem-221 158 28     SPACE eurjchem-221 158 29 gou gou PROPN eurjchem-221 158 30 , , PUNCT eurjchem-221 158 31     SPACE eurjchem-221 158 32 s. s. PROPN eurjchem-221 158 33     SPACE eurjchem-221 158 34 h. h. PROPN eurjchem-221 158 35 ; ; PUNCT eurjchem-221 158 36     SPACE eurjchem-221 158 37 zhu zhu PROPN eurjchem-221 158 38 , , PUNCT eurjchem-221 158 39     SPACE eurjchem-221 158 40 c. c. PROPN eurjchem-221 158 41     SPACE eurjchem-221 158 42 j. j. PROPN eurjchem-221 158 43     SPACE eurjchem-221 158 44 polyhedron polyhedron NOUN eurjchem-221 158 45     SPACE eurjchem-221 158 46 2004 2004 NUM eurjchem-221 158 47 , , PUNCT eurjchem-221 158 48     SPACE eurjchem-221 158 49 23 23 NUM eurjchem-221 158 50 , , PUNCT eurjchem-221 158 51     SPACE eurjchem-221 158 52 1131‐1137 1131‐1137 NUM eurjchem-221 158 53 . . PUNCT eurjchem-221 158 54     SPACE eurjchem-221 159 1 [ [ X eurjchem-221 159 2 11 11 NUM eurjchem-221 159 3 ] ] PUNCT eurjchem-221 159 4 . . PUNCT eurjchem-221 160 1 liu liu PROPN eurjchem-221 160 2 , , PUNCT eurjchem-221 160 3     SPACE eurjchem-221 160 4 b. b. PROPN eurjchem-221 160 5 ; ; PUNCT eurjchem-221 160 6     SPACE eurjchem-221 160 7 zhu zhu PROPN eurjchem-221 160 8 , , PUNCT eurjchem-221 160 9     SPACE eurjchem-221 160 10 s.f s.f PROPN eurjchem-221 160 11 . . PROPN eurjchem-221 160 12 ; ; PUNCT eurjchem-221 160 13     SPACE eurjchem-221 160 14 wang wang PROPN eurjchem-221 160 15 , , PUNCT eurjchem-221 160 16     SPACE eurjchem-221 160 17 l. l. PROPN eurjchem-221 160 18     SPACE eurjchem-221 160 19 x. x. PROPN eurjchem-221 160 20 ; ; PUNCT eurjchem-221 160 21     SPACE eurjchem-221 160 22 zhou zhou PROPN eurjchem-221 160 23 , , PUNCT eurjchem-221 160 24     SPACE eurjchem-221 160 25 q. q. PROPN eurjchem-221 160 26     SPACE eurjchem-221 160 27 l. l. PROPN eurjchem-221 160 28     SPACE eurjchem-221 160 29 tetrahedron tetrahedron NOUN eurjchem-221 160 30 : : PUNCT eurjchem-221 160 31     SPACE eurjchem-221 160 32 asymmetry asymmetry NOUN eurjchem-221 160 33     SPACE eurjchem-221 160 34 2006 2006 NUM eurjchem-221 160 35 , , PUNCT eurjchem-221 160 36     SPACE eurjchem-221 160 37 17 17 NUM eurjchem-221 160 38 , , PUNCT eurjchem-221 160 39     SPACE eurjchem-221 160 40 634‐641 634‐641 PROPN eurjchem-221 160 41 . . PUNCT eurjchem-221 160 42     SPACE eurjchem-221 161 1 [ [ X eurjchem-221 161 2 12 12 NUM eurjchem-221 161 3 ] ] PUNCT eurjchem-221 161 4 . . PUNCT eurjchem-221 162 1 minato minato PROPN eurjchem-221 162 2 , , PUNCT eurjchem-221 162 3     SPACE eurjchem-221 162 4 d. d. PROPN eurjchem-221 162 5 ; ; PUNCT eurjchem-221 162 6     SPACE eurjchem-221 162 7 arimoto arimoto NOUN eurjchem-221 162 8 , , PUNCT eurjchem-221 162 9     SPACE eurjchem-221 162 10 h. h. NOUN eurjchem-221 162 11 ; ; PUNCT eurjchem-221 162 12     SPACE eurjchem-221 162 13 nagasue nagasue NOUN eurjchem-221 162 14 , , PUNCT eurjchem-221 162 15     SPACE eurjchem-221 162 16 y. y. NOUN eurjchem-221 162 17 ; ; PUNCT eurjchem-221 162 18     SPACE eurjchem-221 162 19 demizu demizu PROPN eurjchem-221 162 20 , , PUNCT eurjchem-221 162 21     SPACE eurjchem-221 162 22 y. y. NOUN eurjchem-221 162 23 ; ; PUNCT eurjchem-221 162 24     SPACE eurjchem-221 162 25 onomura onomura ADJ eurjchem-221 162 26     SPACE eurjchem-221 162 27 o. o. PROPN eurjchem-221 162 28     SPACE eurjchem-221 162 29 tetrahedron tetrahedron NOUN eurjchem-221 162 30     SPACE eurjchem-221 162 31 2008 2008 NUM eurjchem-221 162 32 , , PUNCT eurjchem-221 162 33     SPACE eurjchem-221 162 34 64 64 NUM eurjchem-221 162 35 , , PUNCT eurjchem-221 162 36     SPACE eurjchem-221 162 37 6675‐6683 6675‐6683 PROPN eurjchem-221 162 38 . . PUNCT eurjchem-221 162 39     SPACE eurjchem-221 163 1 [ [ X eurjchem-221 163 2 13 13 NUM eurjchem-221 163 3 ] ] PUNCT eurjchem-221 163 4 . . PUNCT eurjchem-221 164 1 bolm bolm ADJ eurjchem-221 164 2 , , PUNCT eurjchem-221 164 3     SPACE eurjchem-221 164 4 c. c. NOUN eurjchem-221 164 5 ; ; PUNCT eurjchem-221 164 6     SPACE eurjchem-221 164 7 schlingloff schlingloff NOUN eurjchem-221 164 8 , , PUNCT eurjchem-221 164 9     SPACE eurjchem-221 164 10 g. g. NOUN eurjchem-221 164 11 ; ; PUNCT eurjchem-221 164 12     SPACE eurjchem-221 164 13 bienewald bienewald NOUN eurjchem-221 164 14 , , PUNCT eurjchem-221 164 15     SPACE eurjchem-221 164 16 f. f. PROPN eurjchem-221 164 17     SPACE eurjchem-221 164 18 j. j. PROPN eurjchem-221 164 19     SPACE eurjchem-221 164 20 mol mol PROPN eurjchem-221 164 21 . . PUNCT eurjchem-221 164 22     SPACE eurjchem-221 165 1 catal catal NOUN eurjchem-221 165 2 . . PUNCT eurjchem-221 165 3     SPACE eurjchem-221 165 4 1997 1997 NUM eurjchem-221 165 5 , , PUNCT eurjchem-221 165 6     SPACE eurjchem-221 165 7 117 117 NUM eurjchem-221 165 8 , , PUNCT eurjchem-221 165 9     SPACE eurjchem-221 165 10 347‐ 347‐ NUM eurjchem-221 165 11 350 350 NUM eurjchem-221 165 12 . . PUNCT eurjchem-221 165 13     SPACE eurjchem-221 166 1 [ [ X eurjchem-221 166 2 14 14 NUM eurjchem-221 166 3 ] ] PUNCT eurjchem-221 166 4 . . PUNCT eurjchem-221 167 1 hoang hoang PROPN eurjchem-221 167 2 , , PUNCT eurjchem-221 167 3     SPACE eurjchem-221 167 4 v. v. ADP eurjchem-221 167 5     SPACE eurjchem-221 167 6 d. d. PROPN eurjchem-221 167 7     SPACE eurjchem-221 167 8 m. m. NOUN eurjchem-221 167 9 ; ; PUNCT eurjchem-221 167 10     SPACE eurjchem-221 167 11 reddy reddy NOUN eurjchem-221 167 12 , , PUNCT eurjchem-221 167 13     SPACE eurjchem-221 167 14 p. p. NOUN eurjchem-221 167 15     SPACE eurjchem-221 167 16 a. a. NOUN eurjchem-221 167 17     SPACE eurjchem-221 167 18 n. n. PROPN eurjchem-221 167 19 ; ; PUNCT eurjchem-221 167 20     SPACE eurjchem-221 167 21 kim kim PROPN eurjchem-221 167 22 , , PUNCT eurjchem-221 167 23     SPACE eurjchem-221 167 24 t. t. PROPN eurjchem-221 167 25     SPACE eurjchem-221 167 26 j. j. PROPN eurjchem-221 167 27     SPACE eurjchem-221 167 28 organometallics organometallic NOUN eurjchem-221 167 29     SPACE eurjchem-221 167 30 2008 2008 NUM eurjchem-221 167 31 , , PUNCT eurjchem-221 167 32     SPACE eurjchem-221 167 33 27 27 NUM eurjchem-221 167 34 , , PUNCT eurjchem-221 167 35     SPACE eurjchem-221 167 36 1026‐ 1026‐ NUM eurjchem-221 167 37     SPACE eurjchem-221 167 38 1027 1027 NUM eurjchem-221 167 39 . . PUNCT eurjchem-221 167 40     SPACE eurjchem-221 168 1 [ [ X eurjchem-221 168 2 15 15 NUM eurjchem-221 168 3 ] ] PUNCT eurjchem-221 168 4 . . PUNCT eurjchem-221 169 1 ginotra ginotra PROPN eurjchem-221 169 2 , , PUNCT eurjchem-221 169 3     SPACE eurjchem-221 169 4 s. s. PROPN eurjchem-221 169 5     SPACE eurjchem-221 169 6 k. k. PROPN eurjchem-221 169 7 ; ; PUNCT eurjchem-221 169 8     SPACE eurjchem-221 169 9 singh singh NOUN eurjchem-221 169 10 , , PUNCT eurjchem-221 169 11     SPACE eurjchem-221 169 12 v. v. ADP eurjchem-221 169 13     SPACE eurjchem-221 169 14 k. k. PROPN eurjchem-221 169 15     SPACE eurjchem-221 169 16 org org PROPN eurjchem-221 169 17 . . PUNCT eurjchem-221 169 18     SPACE eurjchem-221 169 19 biomol biomol PROPN eurjchem-221 169 20 . . PUNCT eurjchem-221 169 21     SPACE eurjchem-221 169 22 chem chem NOUN eurjchem-221 169 23 . . PUNCT eurjchem-221 169 24     SPACE eurjchem-221 169 25 2006 2006 NUM eurjchem-221 169 26 , , PUNCT eurjchem-221 169 27     SPACE eurjchem-221 169 28 4 4 NUM eurjchem-221 169 29 , , PUNCT eurjchem-221 169 30     SPACE eurjchem-221 169 31 4370‐4374 4370‐4374 NOUN eurjchem-221 169 32 . . PUNCT eurjchem-221 169 33     SPACE eurjchem-221 170 1 [ [ X eurjchem-221 170 2 16 16 NUM eurjchem-221 170 3 ] ] PUNCT eurjchem-221 170 4 . . PUNCT eurjchem-221 171 1 mimmi mimmi PROPN eurjchem-221 171 2 , , PUNCT eurjchem-221 171 3     SPACE eurjchem-221 171 4 m. m. NOUN eurjchem-221 171 5     SPACE eurjchem-221 171 6 c. c. PROPN eurjchem-221 171 7 ; ; PUNCT eurjchem-221 171 8     SPACE eurjchem-221 171 9 gullotti gullotti VERB eurjchem-221 171 10 , , PUNCT eurjchem-221 171 11     SPACE eurjchem-221 171 12 m. m. NOUN eurjchem-221 171 13 ; ; PUNCT eurjchem-221 171 14     SPACE eurjchem-221 171 15 santagostini santagostini NOUN eurjchem-221 171 16 , , PUNCT eurjchem-221 171 17     SPACE eurjchem-221 171 18 l. l. PROPN eurjchem-221 171 19 ; ; PUNCT eurjchem-221 171 20     SPACE eurjchem-221 171 21 battaini battaini NOUN eurjchem-221 171 22 , , PUNCT eurjchem-221 171 23     SPACE eurjchem-221 171 24 g. g. NOUN eurjchem-221 171 25 ; ; PUNCT eurjchem-221 171 26     SPACE eurjchem-221 171 27 monzani monzani NOUN eurjchem-221 171 28 , , PUNCT eurjchem-221 171 29     SPACE eurjchem-221 171 30 e. e. PROPN eurjchem-221 171 31 ; ; PUNCT eurjchem-221 171 32     SPACE eurjchem-221 171 33 pagliarin pagliarin NOUN eurjchem-221 171 34 , , PUNCT eurjchem-221 171 35     SPACE eurjchem-221 171 36 r. r. PROPN eurjchem-221 171 37 ; ; PUNCT eurjchem-221 171 38     SPACE eurjchem-221 171 39 zoppellarod zoppellarod NOUN eurjchem-221 171 40 , , PUNCT eurjchem-221 171 41     SPACE eurjchem-221 171 42 g. g. NOUN eurjchem-221 171 43 ; ; PUNCT eurjchem-221 171 44     SPACE eurjchem-221 171 45 casella casella NOUN eurjchem-221 171 46 , , PUNCT eurjchem-221 171 47     SPACE eurjchem-221 171 48 l. l. PROPN eurjchem-221 171 49     SPACE eurjchem-221 171 50 dalton dalton PROPN eurjchem-221 171 51     SPACE eurjchem-221 171 52 trans trans PROPN eurjchem-221 171 53     SPACE eurjchem-221 171 54 2004 2004 NUM eurjchem-221 171 55 , , PUNCT eurjchem-221 171 56     SPACE eurjchem-221 171 57 2192‐ 2192‐ NUM eurjchem-221 171 58 2201 2201 NUM eurjchem-221 171 59 . . PUNCT eurjchem-221 171 60     SPACE eurjchem-221 172 1 [ [ X eurjchem-221 172 2 17 17 NUM eurjchem-221 172 3 ] ] PUNCT eurjchem-221 172 4 . . PUNCT eurjchem-221 173 1 ginotra ginotra PROPN eurjchem-221 173 2 , , PUNCT eurjchem-221 173 3     SPACE eurjchem-221 173 4 s. s. PROPN eurjchem-221 173 5     SPACE eurjchem-221 173 6 k. k. PROPN eurjchem-221 173 7 ; ; PUNCT eurjchem-221 173 8     SPACE eurjchem-221 173 9 singh singh NOUN eurjchem-221 173 10 , , PUNCT eurjchem-221 173 11     SPACE eurjchem-221 173 12 v. v. ADP eurjchem-221 173 13     SPACE eurjchem-221 173 14 k. k. PROPN eurjchem-221 173 15     SPACE eurjchem-221 173 16 tetrahedron tetrahedron NOUN eurjchem-221 173 17     SPACE eurjchem-221 173 18 2006 2006 NUM eurjchem-221 173 19 , , PUNCT eurjchem-221 173 20     SPACE eurjchem-221 173 21 62 62 NUM eurjchem-221 173 22 , , PUNCT eurjchem-221 173 23     SPACE eurjchem-221 173 24 3573‐3581 3573‐3581 PROPN eurjchem-221 173 25 . . PUNCT eurjchem-221 173 26     SPACE eurjchem-221 174 1 [ [ X eurjchem-221 174 2 18 18 NUM eurjchem-221 174 3 ] ] PUNCT eurjchem-221 174 4 . . PUNCT eurjchem-221 175 1 alamsetti alamsetti PROPN eurjchem-221 175 2 , , PUNCT eurjchem-221 175 3     SPACE eurjchem-221 175 4 s. s. PROPN eurjchem-221 175 5     SPACE eurjchem-221 175 6 k. k. PROPN eurjchem-221 175 7 ; ; PUNCT eurjchem-221 175 8     SPACE eurjchem-221 175 9 mannam mannam NOUN eurjchem-221 175 10 , , PUNCT eurjchem-221 175 11     SPACE eurjchem-221 175 12 s. s. PROPN eurjchem-221 175 13 ; ; PUNCT eurjchem-221 175 14     SPACE eurjchem-221 175 15 mutupandi mutupandi NOUN eurjchem-221 175 16 , , PUNCT eurjchem-221 175 17     SPACE eurjchem-221 175 18 p. p. NOUN eurjchem-221 175 19 ; ; PUNCT eurjchem-221 175 20     SPACE eurjchem-221 175 21 sekar sekar PROPN eurjchem-221 175 22 , , PUNCT eurjchem-221 175 23     SPACE eurjchem-221 175 24 g. g. NOUN eurjchem-221 175 25     SPACE eurjchem-221 175 26 chem chem NOUN eurjchem-221 175 27 . . PUNCT eurjchem-221 175 28     SPACE eurjchem-221 175 29 eur eur PROPN eurjchem-221 175 30 . . PUNCT eurjchem-221 175 31     SPACE eurjchem-221 176 1 j. j. PROPN eurjchem-221 176 2     SPACE eurjchem-221 176 3 2008 2008 NUM eurjchem-221 176 4 , , PUNCT eurjchem-221 176 5     SPACE eurjchem-221 176 6 15 15 NUM eurjchem-221 176 7 , , PUNCT eurjchem-221 176 8     SPACE eurjchem-221 176 9 1086‐1090 1086‐1090 NUM eurjchem-221 176 10 . . PUNCT eurjchem-221 176 11     SPACE eurjchem-221 177 1 [ [ X eurjchem-221 177 2 19 19 NUM eurjchem-221 177 3 ] ] PUNCT eurjchem-221 177 4 . . PUNCT eurjchem-221 178 1 punniyamurthy punniyamurthy ADJ eurjchem-221 178 2 , , PUNCT eurjchem-221 178 3     SPACE eurjchem-221 178 4 t. t. PROPN eurjchem-221 178 5 ; ; PUNCT eurjchem-221 178 6     SPACE eurjchem-221 178 7 velusamy velusamy NOUN eurjchem-221 178 8 , , PUNCT eurjchem-221 178 9     SPACE eurjchem-221 178 10 s. s. PROPN eurjchem-221 178 11 ; ; PUNCT eurjchem-221 178 12     SPACE eurjchem-221 178 13 iqbal iqbal PROPN eurjchem-221 178 14 , , PUNCT eurjchem-221 178 15     SPACE eurjchem-221 178 16 j. j. PROPN eurjchem-221 178 17     SPACE eurjchem-221 178 18 chem chem NOUN eurjchem-221 178 19 . . PUNCT eurjchem-221 178 20     SPACE eurjchem-221 178 21 rev rev VERB eurjchem-221 178 22 . . PUNCT eurjchem-221 178 23     SPACE eurjchem-221 178 24 2005 2005 NUM eurjchem-221 178 25 , , PUNCT eurjchem-221 178 26     SPACE eurjchem-221 178 27 105 105 NUM eurjchem-221 178 28 , , PUNCT eurjchem-221 178 29     SPACE eurjchem-221 178 30 2329‐ 2329‐ NUM eurjchem-221 178 31 2363 2363 NUM eurjchem-221 178 32 . . PUNCT eurjchem-221 178 33     SPACE eurjchem-221 179 1 [ [ X eurjchem-221 179 2 20 20 NUM eurjchem-221 179 3 ] ] PUNCT eurjchem-221 179 4 . . PUNCT eurjchem-221 180 1 pu pu PROPN eurjchem-221 180 2 , , PUNCT eurjchem-221 180 3     SPACE eurjchem-221 180 4 l. l. PROPN eurjchem-221 180 5     SPACE eurjchem-221 180 6 chem chem NOUN eurjchem-221 180 7 . . PUNCT eurjchem-221 180 8     SPACE eurjchem-221 180 9 rev rev VERB eurjchem-221 180 10 . . PUNCT eurjchem-221 180 11     SPACE eurjchem-221 180 12 1998 1998 NUM eurjchem-221 180 13 , , PUNCT eurjchem-221 180 14     SPACE eurjchem-221 180 15 98 98 NUM eurjchem-221 180 16 , , PUNCT eurjchem-221 180 17     SPACE eurjchem-221 180 18 2405‐2494 2405‐2494 NUM eurjchem-221 180 19 . . PUNCT eurjchem-221 180 20     SPACE eurjchem-221 181 1 [ [ X eurjchem-221 181 2 21 21 NUM eurjchem-221 181 3 ] ] PUNCT eurjchem-221 181 4 . . PUNCT eurjchem-221 182 1 chen chen PROPN eurjchem-221 182 2 , , PUNCT eurjchem-221 182 3     SPACE eurjchem-221 182 4 y. y. NOUN eurjchem-221 182 5 ; ; PUNCT eurjchem-221 182 6     SPACE eurjchem-221 182 7 yekta yekta NOUN eurjchem-221 182 8 , , PUNCT eurjchem-221 182 9     SPACE eurjchem-221 182 10 s. s. PROPN eurjchem-221 182 11 ; ; PUNCT eurjchem-221 182 12     SPACE eurjchem-221 182 13 yudin yudin VERB eurjchem-221 182 14 , , PUNCT eurjchem-221 182 15     SPACE eurjchem-221 182 16 a. a. NOUN eurjchem-221 182 17     SPACE eurjchem-221 182 18 k. k. PROPN eurjchem-221 182 19     SPACE eurjchem-221 182 20 chem chem NOUN eurjchem-221 182 21 . . PUNCT eurjchem-221 182 22     SPACE eurjchem-221 182 23 rev rev VERB eurjchem-221 182 24 . . PUNCT eurjchem-221 182 25     SPACE eurjchem-221 182 26 2003 2003 NUM eurjchem-221 182 27 , , PUNCT eurjchem-221 182 28     SPACE eurjchem-221 182 29 103 103 NUM eurjchem-221 182 30 , , PUNCT eurjchem-221 182 31     SPACE eurjchem-221 182 32 3155‐3211 3155‐3211 NUM eurjchem-221 182 33 . . PUNCT eurjchem-221 182 34     SPACE eurjchem-221 183 1 [ [ X eurjchem-221 183 2 22 22 NUM eurjchem-221 183 3 ] ] PUNCT eurjchem-221 183 4 . . PUNCT eurjchem-221 184 1 brunel brunel PROPN eurjchem-221 184 2 , , PUNCT eurjchem-221 184 3     SPACE eurjchem-221 184 4 j. j. PROPN eurjchem-221 184 5     SPACE eurjchem-221 184 6 m. m. NOUN eurjchem-221 184 7     SPACE eurjchem-221 184 8 chem chem NOUN eurjchem-221 184 9 . . PUNCT eurjchem-221 184 10     SPACE eurjchem-221 184 11 rev rev VERB eurjchem-221 184 12     SPACE eurjchem-221 184 13 2005 2005 NUM eurjchem-221 184 14 , , PUNCT eurjchem-221 184 15     SPACE eurjchem-221 184 16 105 105 NUM eurjchem-221 184 17 , , PUNCT eurjchem-221 184 18     SPACE eurjchem-221 184 19 857‐897 857‐897 NUM eurjchem-221 184 20 . . PUNCT eurjchem-221 184 21     SPACE eurjchem-221 185 1 [ [ X eurjchem-221 185 2 23 23 NUM eurjchem-221 185 3 ] ] PUNCT eurjchem-221 185 4 . . PUNCT eurjchem-221 186 1 smrčina smrčina PROPN eurjchem-221 186 2 , , PUNCT eurjchem-221 186 3     SPACE eurjchem-221 186 4 m. m. NOUN eurjchem-221 186 5 ; ; PUNCT eurjchem-221 186 6     SPACE eurjchem-221 186 7 poláková poláková NOUN eurjchem-221 186 8 , , PUNCT eurjchem-221 186 9     SPACE eurjchem-221 186 10 j. j. PROPN eurjchem-221 186 11 ; ; PUNCT eurjchem-221 186 12     SPACE eurjchem-221 186 13 vyskočil vyskočil NOUN eurjchem-221 186 14 , , PUNCT eurjchem-221 186 15     SPACE eurjchem-221 186 16 s. s. PROPN eurjchem-221 186 17 ; ; PUNCT eurjchem-221 186 18     SPACE eurjchem-221 186 19 kočovský kočovský NOUN eurjchem-221 186 20 , , PUNCT eurjchem-221 186 21     SPACE eurjchem-221 187 1 p. p. NOUN eurjchem-221 187 2     SPACE eurjchem-221 187 3 j. j. PROPN eurjchem-221 187 4     SPACE eurjchem-221 187 5 org org PROPN eurjchem-221 187 6 . . PUNCT eurjchem-221 187 7     SPACE eurjchem-221 187 8 chem chem NOUN eurjchem-221 187 9 . . PUNCT eurjchem-221 187 10     SPACE eurjchem-221 187 11 1993 1993 NUM eurjchem-221 187 12 , , PUNCT eurjchem-221 187 13     SPACE eurjchem-221 187 14 58 58 NUM eurjchem-221 187 15 , , PUNCT eurjchem-221 187 16     SPACE eurjchem-221 187 17 4534‐4538 4534‐4538 NOUN eurjchem-221 187 18 . . PUNCT eurjchem-221 187 19     SPACE eurjchem-221 188 1 [ [ X eurjchem-221 188 2 24 24 NUM eurjchem-221 188 3 ] ] PUNCT eurjchem-221 188 4 . . PUNCT eurjchem-221 189 1 nakajima nakajima PROPN eurjchem-221 189 2 , , PUNCT eurjchem-221 189 3     SPACE eurjchem-221 189 4 m. m. NOUN eurjchem-221 189 5 ; ; PUNCT eurjchem-221 189 6     SPACE eurjchem-221 189 7 miyoshi miyoshi PROPN eurjchem-221 189 8 , , PUNCT eurjchem-221 189 9     SPACE eurjchem-221 189 10 i. i. NOUN eurjchem-221 189 11 ; ; PUNCT eurjchem-221 189 12     SPACE eurjchem-221 189 13 kanayama kanayama NOUN eurjchem-221 189 14 , , PUNCT eurjchem-221 189 15     SPACE eurjchem-221 189 16 k. k. NOUN eurjchem-221 189 17 ; ; PUNCT eurjchem-221 189 18     SPACE eurjchem-221 189 19 hashimoto hashimoto NOUN eurjchem-221 189 20 , , PUNCT eurjchem-221 189 21     SPACE eurjchem-221 189 22 s. s. PROPN eurjchem-221 189 23     SPACE eurjchem-221 189 24 i. i. PROPN eurjchem-221 189 25 ; ; PUNCT eurjchem-221 189 26     SPACE eurjchem-221 189 27 noji noji NOUN eurjchem-221 189 28 , , PUNCT eurjchem-221 189 29     SPACE eurjchem-221 189 30 m. m. NOUN eurjchem-221 189 31 ; ; PUNCT eurjchem-221 189 32     SPACE eurjchem-221 189 33 koga koga PROPN eurjchem-221 189 34 , , PUNCT eurjchem-221 189 35     SPACE eurjchem-221 189 36 k. k. PROPN eurjchem-221 189 37     SPACE eurjchem-221 189 38 j. j. PROPN eurjchem-221 189 39     SPACE eurjchem-221 189 40 org org PROPN eurjchem-221 189 41 . . PUNCT eurjchem-221 189 42     SPACE eurjchem-221 189 43 chem chem NOUN eurjchem-221 189 44 . . PUNCT eurjchem-221 189 45     SPACE eurjchem-221 189 46 1999 1999 NUM eurjchem-221 189 47 , , PUNCT eurjchem-221 189 48     SPACE eurjchem-221 189 49 64 64 NUM eurjchem-221 189 50 , , PUNCT eurjchem-221 189 51     SPACE eurjchem-221 189 52 2264‐2271 2264‐2271 NUM eurjchem-221 189 53 . . PUNCT eurjchem-221 189 54     SPACE eurjchem-221 190 1 [ [ X eurjchem-221 190 2 25 25 NUM eurjchem-221 190 3 ] ] PUNCT eurjchem-221 190 4 . . PUNCT eurjchem-221 191 1 li li PROPN eurjchem-221 191 2 , , PUNCT eurjchem-221 191 3     SPACE eurjchem-221 191 4 x. x. NOUN eurjchem-221 191 5 ; ; PUNCT eurjchem-221 191 6     SPACE eurjchem-221 191 7 hewgley hewgley PROPN eurjchem-221 191 8 , , PUNCT eurjchem-221 191 9     SPACE eurjchem-221 191 10 j. j. PROPN eurjchem-221 191 11     SPACE eurjchem-221 191 12 b. b. PROPN eurjchem-221 191 13 ; ; PUNCT eurjchem-221 191 14     SPACE eurjchem-221 191 15 mulrooney mulrooney NOUN eurjchem-221 191 16 , , PUNCT eurjchem-221 191 17     SPACE eurjchem-221 191 18 c. c. PROPN eurjchem-221 191 19     SPACE eurjchem-221 191 20 a. a. NOUN eurjchem-221 191 21 ; ; PUNCT eurjchem-221 191 22     SPACE eurjchem-221 191 23 yang yang PROPN eurjchem-221 191 24 , , PUNCT eurjchem-221 191 25     SPACE eurjchem-221 191 26 j. j. PROPN eurjchem-221 191 27 ; ; PUNCT eurjchem-221 191 28     SPACE eurjchem-221 191 29 kozlowski kozlowski PROPN eurjchem-221 191 30 , , PUNCT eurjchem-221 191 31     SPACE eurjchem-221 191 32 m. m. NOUN eurjchem-221 191 33     SPACE eurjchem-221 191 34 c. c. PROPN eurjchem-221 191 35     SPACE eurjchem-221 191 36 j. j. PROPN eurjchem-221 191 37     SPACE eurjchem-221 191 38 org org PROPN eurjchem-221 191 39 . . PUNCT eurjchem-221 191 40     SPACE eurjchem-221 191 41 chem chem NOUN eurjchem-221 191 42 . . PUNCT eurjchem-221 191 43     SPACE eurjchem-221 191 44 2003 2003 NUM eurjchem-221 191 45 , , PUNCT eurjchem-221 191 46     SPACE eurjchem-221 191 47 68 68 NUM eurjchem-221 191 48 , , PUNCT eurjchem-221 191 49     SPACE eurjchem-221 191 50 5500‐5511 5500‐5511 NUM eurjchem-221 191 51 . . PUNCT eurjchem-221 191 52     SPACE eurjchem-221 192 1 [ [ X eurjchem-221 192 2 26 26 NUM eurjchem-221 192 3 ] ] PUNCT eurjchem-221 192 4 . . PUNCT eurjchem-221 193 1 noji noji PROPN eurjchem-221 193 2 , , PUNCT eurjchem-221 193 3     SPACE eurjchem-221 193 4 m. m. NOUN eurjchem-221 193 5 ; ; PUNCT eurjchem-221 193 6     SPACE eurjchem-221 193 7 nakajima nakajima PROPN eurjchem-221 193 8 , , PUNCT eurjchem-221 193 9     SPACE eurjchem-221 193 10 m. m. NOUN eurjchem-221 193 11 ; ; PUNCT eurjchem-221 193 12     SPACE eurjchem-221 193 13 koga koga PROPN eurjchem-221 193 14 , , PUNCT eurjchem-221 193 15     SPACE eurjchem-221 193 16 k. k. PROPN eurjchem-221 193 17     SPACE eurjchem-221 193 18 tetrahedron tetrahedron NOUN eurjchem-221 193 19     SPACE eurjchem-221 193 20 letter letter NOUN eurjchem-221 193 21     SPACE eurjchem-221 193 22 1994 1994 NUM eurjchem-221 193 23 , , PUNCT eurjchem-221 193 24     SPACE eurjchem-221 193 25 35 35 NUM eurjchem-221 193 26 , , PUNCT eurjchem-221 193 27     SPACE eurjchem-221 193 28 7983‐ 7983‐ NUM eurjchem-221 193 29 7984 7984 NUM eurjchem-221 193 30 . . PUNCT eurjchem-221 193 31     SPACE eurjchem-221 194 1 [ [ X eurjchem-221 194 2 27 27 NUM eurjchem-221 194 3 ] ] PUNCT eurjchem-221 194 4 . . PUNCT eurjchem-221 195 1 larrow larrow PROPN eurjchem-221 195 2 , , PUNCT eurjchem-221 195 3     SPACE eurjchem-221 195 4 j. j. PROPN eurjchem-221 195 5     SPACE eurjchem-221 195 6 f. f. PROPN eurjchem-221 195 7 ; ; PUNCT eurjchem-221 195 8     SPACE eurjchem-221 195 9 jacobsen jacobsen PROPN eurjchem-221 195 10 , , PUNCT eurjchem-221 195 11     SPACE eurjchem-221 195 12 e. e. PROPN eurjchem-221 195 13     SPACE eurjchem-221 195 14 n. n. PROPN eurjchem-221 195 15     SPACE eurjchem-221 195 16 j. j. PROPN eurjchem-221 195 17     SPACE eurjchem-221 195 18 org org PROPN eurjchem-221 195 19 . . PUNCT eurjchem-221 195 20     SPACE eurjchem-221 195 21 chem chem NOUN eurjchem-221 195 22 . . PUNCT eurjchem-221 195 23     SPACE eurjchem-221 196 1 1994 1994 NUM eurjchem-221 196 2 , , PUNCT eurjchem-221 196 3     SPACE eurjchem-221 196 4 59 59 NUM eurjchem-221 196 5 , , PUNCT eurjchem-221 196 6     SPACE eurjchem-221 196 7 1939‐1942 1939‐1942 NUM eurjchem-221 196 8 . . PUNCT eurjchem-221 196 9     SPACE eurjchem-221 197 1 [ [ X eurjchem-221 197 2 28 28 NUM eurjchem-221 197 3 ] ] PUNCT eurjchem-221 197 4 . . PUNCT eurjchem-221 197 5 kalechits kalechit NOUN eurjchem-221 197 6 , , PUNCT eurjchem-221 197 7     SPACE eurjchem-221 197 8 g. g. PROPN eurjchem-221 197 9     SPACE eurjchem-221 197 10 v. v. PROPN eurjchem-221 197 11 ; ; PUNCT eurjchem-221 197 12     SPACE eurjchem-221 197 13 osinovskii osinovskii ADJ eurjchem-221 197 14 , , PUNCT eurjchem-221 197 15     SPACE eurjchem-221 197 16 a. a. NOUN eurjchem-221 197 17     SPACE eurjchem-221 197 18 g. g. PROPN eurjchem-221 197 19 ; ; PUNCT eurjchem-221 197 20     SPACE eurjchem-221 197 21 matveenko matveenko PROPN eurjchem-221 197 22 , , PUNCT eurjchem-221 197 23     SPACE eurjchem-221 197 24 y. y. NOUN eurjchem-221 197 25     SPACE eurjchem-221 197 26 v. v. PROPN eurjchem-221 197 27 ; ; PUNCT eurjchem-221 197 28     SPACE eurjchem-221 197 29 ol’khovik ol’khovik ADV eurjchem-221 197 30 , , PUNCT eurjchem-221 197 31     SPACE eurjchem-221 197 32 v. v. PROPN eurjchem-221 197 33     SPACE eurjchem-221 197 34 k. k. PROPN eurjchem-221 197 35     SPACE eurjchem-221 197 36 russ russ PROPN eurjchem-221 197 37 . . PUNCT eurjchem-221 197 38     SPACE eurjchem-221 197 39 j. j. PROPN eurjchem-221 197 40     SPACE eurjchem-221 197 41 appl appl PROPN eurjchem-221 197 42 . . PUNCT eurjchem-221 197 43     SPACE eurjchem-221 197 44 chem chem NOUN eurjchem-221 197 45 . . PUNCT eurjchem-221 197 46     SPACE eurjchem-221 197 47 2002 2002 NUM eurjchem-221 197 48 , , PUNCT eurjchem-221 197 49     SPACE eurjchem-221 197 50 75 75 NUM eurjchem-221 197 51 , , PUNCT eurjchem-221 197 52     SPACE eurjchem-221 197 53 962‐964 962‐964 NUM eurjchem-221 197 54 . . PUNCT eurjchem-221 197 55     SPACE eurjchem-221 198 1 [ [ X eurjchem-221 198 2 29 29 NUM eurjchem-221 198 3 ] ] PUNCT eurjchem-221 198 4 . . PUNCT eurjchem-221 199 1 kureshy kureshy ADJ eurjchem-221 199 2 , , PUNCT eurjchem-221 199 3     SPACE eurjchem-221 199 4 r. r. PROPN eurjchem-221 199 5     SPACE eurjchem-221 199 6 i. i. PROPN eurjchem-221 199 7 ; ; PUNCT eurjchem-221 199 8     SPACE eurjchem-221 199 9 khan khan PROPN eurjchem-221 199 10 , , PUNCT eurjchem-221 199 11     SPACE eurjchem-221 199 12 n. n. PROPN eurjchem-221 199 13     SPACE eurjchem-221 199 14 h. h. PROPN eurjchem-221 199 15 ; ; PUNCT eurjchem-221 199 16     SPACE eurjchem-221 199 17 abdi abdi PROPN eurjchem-221 199 18 , , PUNCT eurjchem-221 199 19     SPACE eurjchem-221 199 20 s. s. PROPN eurjchem-221 199 21     SPACE eurjchem-221 199 22 h. h. PROPN eurjchem-221 199 23     SPACE eurjchem-221 199 24 r. r. PROPN eurjchem-221 199 25 ; ; PUNCT eurjchem-221 199 26     SPACE eurjchem-221 199 27 patel patel NOUN eurjchem-221 199 28 , , PUNCT eurjchem-221 199 29     SPACE eurjchem-221 199 30 s. s. PROPN eurjchem-221 199 31     SPACE eurjchem-221 199 32 t. t. PROPN eurjchem-221 199 33 ; ; PUNCT eurjchem-221 199 34     SPACE eurjchem-221 199 35 jasra jasra ADJ eurjchem-221 199 36 , , PUNCT eurjchem-221 199 37     SPACE eurjchem-221 199 38 r. r. PROPN eurjchem-221 199 39     SPACE eurjchem-221 199 40 v. v. PROPN eurjchem-221 199 41     SPACE eurjchem-221 199 42 tetrahedron tetrahedron NOUN eurjchem-221 199 43 : : PUNCT eurjchem-221 199 44     SPACE eurjchem-221 199 45 asymmetry asymmetry NOUN eurjchem-221 199 46     SPACE eurjchem-221 199 47 2001 2001 NUM eurjchem-221 199 48 , , PUNCT eurjchem-221 199 49     SPACE eurjchem-221 199 50 12 12 NUM eurjchem-221 199 51 , , PUNCT eurjchem-221 199 52     SPACE eurjchem-221 199 53 433‐437 433‐437 NUM eurjchem-221 199 54 . . PUNCT eurjchem-221 199 55       SPACE