id	sid	tid	token	lemma	pos
eurjchem-2214	1	1	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	VERB
eurjchem-2214	1	2	as	as	ADP
eurjchem-2214	1	3	a	a	DET
eurjchem-2214	1	4	planarity	planarity	NOUN
eurjchem-2214	1	5	chuck	chuck	NOUN
eurjchem-2214	1	6	in	in	ADP
eurjchem-2214	1	7	the	the	DET
eurjchem-2214	1	8	search	search	NOUN
eurjchem-2214	1	9	for	for	ADP
eurjchem-2214	1	10	cis	cis	NOUN
eurjchem-2214	1	11	-	-	PUNCT
eurjchem-2214	1	12	platin	platin	ADJ
eurjchem-2214	1	13	analogues	analogue	NOUN
eurjchem-2214	1	14	of	of	ADP
eurjchem-2214	1	15	nickel	nickel	NOUN
eurjchem-2214	1	16	:	:	PUNCT
eurjchem-2214	1	17	spectral	spectral	ADJ
eurjchem-2214	1	18	,	,	PUNCT
eurjchem-2214	1	19	single	single	ADJ
eurjchem-2214	1	20	crystal	crystal	NOUN
eurjchem-2214	1	21	x	x	PROPN
eurjchem-2214	1	22	-	-	NOUN
eurjchem-2214	1	23	ray	ray	NOUN
eurjchem-2214	1	24	structural	structural	NOUN
eurjchem-2214	1	25	,	,	PUNCT
eurjchem-2214	1	26	bvs	bvs	PROPN
eurjchem-2214	1	27	,	,	PUNCT
eurjchem-2214	1	28	and	and	CCONJ
eurjchem-2214	1	29	csm	csm	VERB
eurjchem-2214	1	30	analysis	analysis	NOUN
eurjchem-2214	1	31	of	of	ADP
eurjchem-2214	1	32	some	some	DET
eurjchem-2214	1	33	planar	planar	ADJ
eurjchem-2214	1	34	nickel(ii	nickel(ii	ADJ
eurjchem-2214	1	35	)	)	PUNCT
eurjchem-2214	1	36	mixed	mixed	ADJ
eurjchem-2214	1	37	ligand	ligand	NOUN
eurjchem-2214	1	38	complexes	complex	NOUN
eurjchem-2214	1	39	european	european	PROPN
eurjchem-2214	1	40	journal	journal	PROPN
eurjchem-2214	1	41	of	of	ADP
eurjchem-2214	1	42	chemistry	chemistry	NOUN
eurjchem-2214	1	43	13	13	NUM
eurjchem-2214	1	44	(	(	PUNCT
eurjchem-2214	1	45	1	1	NUM
eurjchem-2214	1	46	)	)	PUNCT
eurjchem-2214	1	47	(	(	PUNCT
eurjchem-2214	1	48	2022	2022	NUM
eurjchem-2214	1	49	)	)	PUNCT
eurjchem-2214	1	50	117	117	NUM
eurjchem-2214	1	51	-	-	SYM
eurjchem-2214	1	52	125	125	NUM
eurjchem-2214	1	53	european	european	ADJ
eurjchem-2214	1	54	journal	journal	NOUN
eurjchem-2214	1	55	of	of	ADP
eurjchem-2214	1	56	chemistry	chemistry	NOUN
eurjchem-2214	1	57	issn	issn	VERB
eurjchem-2214	1	58	2153	2153	NUM
eurjchem-2214	1	59	-	-	SYM
eurjchem-2214	1	60	2249	2249	NUM
eurjchem-2214	1	61	(	(	PUNCT
eurjchem-2214	1	62	print	print	NOUN
eurjchem-2214	1	63	)	)	PUNCT
eurjchem-2214	1	64	/	/	PUNCT
eurjchem-2214	1	65	issn	issn	PROPN
eurjchem-2214	1	66	2153	2153	NUM
eurjchem-2214	1	67	-	-	SYM
eurjchem-2214	1	68	2257	2257	NUM
eurjchem-2214	1	69	(	(	PUNCT
eurjchem-2214	1	70	online	online	ADJ
eurjchem-2214	1	71	)	)	PUNCT
eurjchem-2214	1	72	–	–	PUNCT
eurjchem-2214	2	1	copyright	copyright	NOUN
eurjchem-2214	2	2	©	©	PROPN
eurjchem-2214	2	3	2022	2022	NUM
eurjchem-2214	2	4	the	the	DET
eurjchem-2214	2	5	authors	author	NOUN
eurjchem-2214	2	6	–	–	PUNCT
eurjchem-2214	2	7	atlanta	atlanta	PROPN
eurjchem-2214	2	8	publishing	publishing	PROPN
eurjchem-2214	2	9	house	house	PROPN
eurjchem-2214	2	10	llc	llc	PROPN
eurjchem-2214	2	11	–	–	PUNCT
eurjchem-2214	2	12	printed	print	VERB
eurjchem-2214	2	13	in	in	ADP
eurjchem-2214	2	14	the	the	DET
eurjchem-2214	2	15	usa	usa	PROPN
eurjchem-2214	2	16	.	.	PUNCT
eurjchem-2214	3	1	this	this	DET
eurjchem-2214	3	2	work	work	NOUN
eurjchem-2214	3	3	is	be	AUX
eurjchem-2214	3	4	published	publish	VERB
eurjchem-2214	3	5	and	and	CCONJ
eurjchem-2214	3	6	licensed	license	VERB
eurjchem-2214	3	7	by	by	ADP
eurjchem-2214	3	8	atlanta	atlanta	PROPN
eurjchem-2214	3	9	publishing	publishing	PROPN
eurjchem-2214	3	10	house	house	PROPN
eurjchem-2214	3	11	llc	llc	PROPN
eurjchem-2214	3	12	–	–	PUNCT
eurjchem-2214	3	13	cc	cc	PROPN
eurjchem-2214	3	14	by	by	ADP
eurjchem-2214	3	15	nc	nc	PROPN
eurjchem-2214	3	16	–	–	PUNCT
eurjchem-2214	3	17	some	some	DET
eurjchem-2214	3	18	rights	right	NOUN
eurjchem-2214	3	19	reserved	reserve	VERB
eurjchem-2214	3	20	.	.	PUNCT
eurjchem-2214	4	1	https://dx.doi.org/10.5155/eurjchem.13.1.117-125.2214	https://dx.doi.org/10.5155/eurjchem.13.1.117-125.2214	ADJ
eurjchem-2214	4	2	european	european	ADJ
eurjchem-2214	4	3	journal	journal	NOUN
eurjchem-2214	4	4	of	of	ADP
eurjchem-2214	4	5	chemistry	chemistry	NOUN
eurjchem-2214	4	6	view	view	NOUN
eurjchem-2214	4	7	journal	journal	PROPN
eurjchem-2214	4	8	online	online	PROPN
eurjchem-2214	4	9	view	view	NOUN
eurjchem-2214	4	10	article	article	NOUN
eurjchem-2214	4	11	online	online	NOUN
eurjchem-2214	4	12	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	PROPN
eurjchem-2214	4	13	as	as	ADP
eurjchem-2214	4	14	a	a	DET
eurjchem-2214	4	15	planarity	planarity	NOUN
eurjchem-2214	4	16	chuck	chuck	NOUN
eurjchem-2214	4	17	in	in	ADP
eurjchem-2214	4	18	the	the	DET
eurjchem-2214	4	19	search	search	NOUN
eurjchem-2214	4	20	for	for	ADP
eurjchem-2214	4	21	cis	cis	NOUN
eurjchem-2214	4	22	-	-	PUNCT
eurjchem-2214	4	23	platin	platin	ADJ
eurjchem-2214	4	24	analogues	analogue	NOUN
eurjchem-2214	4	25	of	of	ADP
eurjchem-2214	4	26	nickel	nickel	NOUN
eurjchem-2214	4	27	:	:	PUNCT
eurjchem-2214	4	28	spectral	spectral	ADJ
eurjchem-2214	4	29	,	,	PUNCT
eurjchem-2214	4	30	single	single	ADJ
eurjchem-2214	4	31	crystal	crystal	NOUN
eurjchem-2214	4	32	x	x	PROPN
eurjchem-2214	4	33	-	-	NOUN
eurjchem-2214	4	34	ray	ray	NOUN
eurjchem-2214	4	35	structural	structural	NOUN
eurjchem-2214	4	36	,	,	PUNCT
eurjchem-2214	4	37	bvs	bvs	PROPN
eurjchem-2214	4	38	,	,	PUNCT
eurjchem-2214	4	39	and	and	CCONJ
eurjchem-2214	4	40	csm	csm	VERB
eurjchem-2214	4	41	analysis	analysis	NOUN
eurjchem-2214	4	42	of	of	ADP
eurjchem-2214	4	43	some	some	DET
eurjchem-2214	4	44	planar	planar	ADJ
eurjchem-2214	4	45	nickel(ii	nickel(ii	ADJ
eurjchem-2214	4	46	)	)	PUNCT
eurjchem-2214	4	47	mixed	mixed	ADJ
eurjchem-2214	4	48	ligand	ligand	NOUN
eurjchem-2214	4	49	complexes	complex	NOUN
eurjchem-2214	4	50	kuppukkannu	kuppukkannu	NOUN
eurjchem-2214	4	51	ramalingam	ramalingam	ADJ
eurjchem-2214	4	52	1	1	NUM
eurjchem-2214	4	53	,	,	PUNCT
eurjchem-2214	4	54	*	*	PUNCT
eurjchem-2214	4	55	,	,	PUNCT
eurjchem-2214	4	56	murugesan	murugesan	PROPN
eurjchem-2214	4	57	saravanan	saravanan	PROPN
eurjchem-2214	4	58	1,2	1,2	NUM
eurjchem-2214	4	59	,	,	PUNCT
eurjchem-2214	4	60	gabriele	gabriele	PROPN
eurjchem-2214	4	61	bocelli	bocelli	PROPN
eurjchem-2214	4	62	3	3	NUM
eurjchem-2214	4	63	,	,	PUNCT
eurjchem-2214	4	64	lara	lara	PROPN
eurjchem-2214	4	65	righi	righi	PROPN
eurjchem-2214	4	66	3	3	NUM
eurjchem-2214	4	67	,	,	PUNCT
eurjchem-2214	4	68	yurii	yurii	PROPN
eurjchem-2214	4	69	chumakov	chumakov	PROPN
eurjchem-2214	4	70	4	4	NUM
eurjchem-2214	4	71	and	and	CCONJ
eurjchem-2214	4	72	andrea	andrea	PROPN
eurjchem-2214	4	73	cantoni	cantoni	PROPN
eurjchem-2214	4	74	3	3	NUM
eurjchem-2214	4	75	1	1	NUM
eurjchem-2214	4	76	department	department	NOUN
eurjchem-2214	4	77	of	of	ADP
eurjchem-2214	4	78	chemistry	chemistry	NOUN
eurjchem-2214	4	79	,	,	PUNCT
eurjchem-2214	4	80	faculty	faculty	NOUN
eurjchem-2214	4	81	of	of	ADP
eurjchem-2214	4	82	science	science	NOUN
eurjchem-2214	4	83	,	,	PUNCT
eurjchem-2214	4	84	annamalai	annamalai	PROPN
eurjchem-2214	4	85	university	university	PROPN
eurjchem-2214	4	86	,	,	PUNCT
eurjchem-2214	4	87	annamalainagar	annamalainagar	NOUN
eurjchem-2214	4	88	608002	608002	NUM
eurjchem-2214	4	89	,	,	PUNCT
eurjchem-2214	4	90	india	india	PROPN
eurjchem-2214	4	91	2	2	PROPN
eurjchem-2214	4	92	perkin	perkin	PROPN
eurjchem-2214	4	93	elmer	elmer	PROPN
eurjchem-2214	4	94	incorporation	incorporation	PROPN
eurjchem-2214	4	95	,	,	PUNCT
eurjchem-2214	4	96	kerala	kerala	PROPN
eurjchem-2214	4	97	682001	682001	NUM
eurjchem-2214	4	98	,	,	PUNCT
eurjchem-2214	4	99	india	india	PROPN
eurjchem-2214	4	100	3	3	PROPN
eurjchem-2214	4	101	department	department	NOUN
eurjchem-2214	4	102	of	of	ADP
eurjchem-2214	4	103	chemistry	chemistry	NOUN
eurjchem-2214	4	104	,	,	PUNCT
eurjchem-2214	4	105	universita	universita	PROPN
eurjchem-2214	4	106	di	di	PROPN
eurjchem-2214	4	107	parma	parma	PROPN
eurjchem-2214	4	108	,	,	PUNCT
eurjchem-2214	4	109	parco	parco	PROPN
eurjchem-2214	4	110	area	area	PROPN
eurjchem-2214	4	111	delle	delle	PROPN
eurjchem-2214	4	112	scienze-37a	scienze-37a	PROPN
eurjchem-2214	4	113	,	,	PUNCT
eurjchem-2214	4	114	i-43100	i-43100	PROPN
eurjchem-2214	4	115	,	,	PUNCT
eurjchem-2214	4	116	parma	parma	PROPN
eurjchem-2214	4	117	,	,	PUNCT
eurjchem-2214	4	118	italy	italy	PROPN
eurjchem-2214	4	119	4	4	NUM
eurjchem-2214	4	120	institute	institute	PROPN
eurjchem-2214	4	121	of	of	ADP
eurjchem-2214	4	122	applied	applied	ADJ
eurjchem-2214	4	123	physics	physics	PROPN
eurjchem-2214	4	124	,	,	PUNCT
eurjchem-2214	4	125	institute	institute	NOUN
eurjchem-2214	4	126	of	of	ADP
eurjchem-2214	4	127	applied	applied	ADJ
eurjchem-2214	4	128	physics	physic	NOUN
eurjchem-2214	4	129	,	,	PUNCT
eurjchem-2214	4	130	academiei	academiei	PROPN
eurjchem-2214	4	131	str	str	NOUN
eurjchem-2214	4	132	.	.	PUNCT
eurjchem-2214	5	1	5	5	NUM
eurjchem-2214	5	2	,	,	PUNCT
eurjchem-2214	5	3	chisinau	chisinau	PROPN
eurjchem-2214	5	4	,	,	PUNCT
eurjchem-2214	5	5	moldova	moldova	PROPN
eurjchem-2214	5	6	*	*	PUNCT
eurjchem-2214	5	7	corresponding	correspond	VERB
eurjchem-2214	5	8	author	author	NOUN
eurjchem-2214	5	9	at	at	ADP
eurjchem-2214	5	10	:	:	PUNCT
eurjchem-2214	5	11	department	department	NOUN
eurjchem-2214	5	12	of	of	ADP
eurjchem-2214	5	13	chemistry	chemistry	NOUN
eurjchem-2214	5	14	,	,	PUNCT
eurjchem-2214	5	15	faculty	faculty	NOUN
eurjchem-2214	5	16	of	of	ADP
eurjchem-2214	5	17	science	science	NOUN
eurjchem-2214	5	18	,	,	PUNCT
eurjchem-2214	5	19	annamalai	annamalai	PROPN
eurjchem-2214	5	20	university	university	PROPN
eurjchem-2214	5	21	,	,	PUNCT
eurjchem-2214	5	22	annamalainagar	annamalainagar	NOUN
eurjchem-2214	5	23	608002	608002	NUM
eurjchem-2214	5	24	,	,	PUNCT
eurjchem-2214	5	25	india	india	PROPN
eurjchem-2214	5	26	.	.	PUNCT
eurjchem-2214	6	1	e	e	X
eurjchem-2214	6	2	-	-	NOUN
eurjchem-2214	6	3	mail	mail	NOUN
eurjchem-2214	6	4	:	:	PUNCT
eurjchem-2214	7	1	krauchem@yahoo.com	krauchem@yahoo.com	X
eurjchem-2214	7	2	(	(	PUNCT
eurjchem-2214	7	3	k.	k.	PROPN
eurjchem-2214	7	4	ramalingam	ramalingam	PROPN
eurjchem-2214	7	5	)	)	PUNCT
eurjchem-2214	7	6	.	.	PUNCT
eurjchem-2214	8	1	10.5155	10.5155	NUM
eurjchem-2214	8	2	/	/	SYM
eurjchem-2214	8	3	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	8	4	-	-	SYM
eurjchem-2214	8	5	125.2214	125.2214	NUM
eurjchem-2214	8	6	received	receive	VERB
eurjchem-2214	8	7	:	:	PUNCT
eurjchem-2214	8	8	16	16	NUM
eurjchem-2214	8	9	november	november	PROPN
eurjchem-2214	8	10	2021	2021	NUM
eurjchem-2214	8	11	received	receive	VERB
eurjchem-2214	8	12	in	in	ADP
eurjchem-2214	8	13	revised	revise	VERB
eurjchem-2214	8	14	form	form	NOUN
eurjchem-2214	8	15	:	:	PUNCT
eurjchem-2214	8	16	22	22	NUM
eurjchem-2214	8	17	january	january	PROPN
eurjchem-2214	8	18	2022	2022	NUM
eurjchem-2214	8	19	accepted	accept	VERB
eurjchem-2214	8	20	:	:	PUNCT
eurjchem-2214	8	21	26	26	NUM
eurjchem-2214	8	22	january	january	PROPN
eurjchem-2214	8	23	2022	2022	NUM
eurjchem-2214	8	24	published	publish	VERB
eurjchem-2214	8	25	online	online	ADV
eurjchem-2214	8	26	:	:	PUNCT
eurjchem-2214	8	27	31	31	NUM
eurjchem-2214	8	28	march	march	NOUN
eurjchem-2214	8	29	2022	2022	NUM
eurjchem-2214	8	30	printed	print	VERB
eurjchem-2214	8	31	:	:	PUNCT
eurjchem-2214	8	32	31	31	NUM
eurjchem-2214	8	33	march	march	NOUN
eurjchem-2214	8	34	2022	2022	NUM
eurjchem-2214	9	1	[	[	X
eurjchem-2214	9	2	ni(pyrdtc)(pph3)(ncs	ni(pyrdtc)(pph3)(ncs	NOUN
eurjchem-2214	9	3	)	)	PUNCT
eurjchem-2214	9	4	]	]	PUNCT
eurjchem-2214	9	5	(	(	PUNCT
eurjchem-2214	9	6	1	1	NUM
eurjchem-2214	9	7	)	)	PUNCT
eurjchem-2214	9	8	,	,	PUNCT
eurjchem-2214	10	1	[	[	X
eurjchem-2214	10	2	ni(pyrdtc)(4	ni(pyrdtc)(4	NOUN
eurjchem-2214	10	3	-	-	PUNCT
eurjchem-2214	10	4	mp)(ncs	mp)(nc	NOUN
eurjchem-2214	10	5	)	)	PUNCT
eurjchem-2214	10	6	]	]	PUNCT
eurjchem-2214	10	7	(	(	PUNCT
eurjchem-2214	10	8	2	2	NUM
eurjchem-2214	10	9	)	)	PUNCT
eurjchem-2214	10	10	,	,	PUNCT
eurjchem-2214	11	1	[	[	X
eurjchem-2214	11	2	ni(pyrdtc)(pph3)(cn)]·h2o	ni(pyrdtc)(pph3)(cn)]·h2o	NOUN
eurjchem-2214	11	3	(	(	PUNCT
eurjchem-2214	11	4	3	3	NUM
eurjchem-2214	11	5	)	)	PUNCT
eurjchem-2214	11	6	,	,	PUNCT
eurjchem-2214	11	7	[	[	X
eurjchem-2214	11	8	ni(pyrdtc)(pph3)2]clo4	ni(pyrdtc)(pph3)2]clo4	X
eurjchem-2214	11	9	(	(	PUNCT
eurjchem-2214	11	10	4	4	NUM
eurjchem-2214	11	11	)	)	PUNCT
eurjchem-2214	11	12	,	,	PUNCT
eurjchem-2214	11	13	and	and	CCONJ
eurjchem-2214	11	14	[	[	AUX
eurjchem-2214	11	15	ni(pyrdtc)(p	ni(pyrdtc)(p	X
eurjchem-2214	11	16	�	�	PROPN
eurjchem-2214	11	17	p)]bph4·2h2o	p)]bph4·2h2o	NOUN
eurjchem-2214	11	18	(	(	PUNCT
eurjchem-2214	11	19	5	5	NUM
eurjchem-2214	11	20	)	)	PUNCT
eurjchem-2214	11	21	[	[	X
eurjchem-2214	11	22	where	where	SCONJ
eurjchem-2214	11	23	pyrdtc	pyrdtc	NOUN
eurjchem-2214	11	24	:	:	PUNCT
eurjchem-2214	11	25	pyrrolidine	pyrrolidine	ADJ
eurjchem-2214	11	26	carbodithioate	carbodithioate	PROPN
eurjchem-2214	11	27	/	/	SYM
eurjchem-2214	11	28	s	s	PROPN
eurjchem-2214	11	29	�	�	PROPN
eurjchem-2214	11	30	s	s	PART
eurjchem-2214	11	31	,	,	PUNCT
eurjchem-2214	11	32	pph3	pph3	NOUN
eurjchem-2214	11	33	:	:	PUNCT
eurjchem-2214	11	34	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2214	11	35	,	,	PUNCT
eurjchem-2214	11	36	4	4	NUM
eurjchem-2214	11	37	-	-	PUNCT
eurjchem-2214	11	38	mp	mp	NOUN
eurjchem-2214	11	39	:	:	PUNCT
eurjchem-2214	11	40	tri(4	tri(4	NOUN
eurjchem-2214	11	41	-	-	PUNCT
eurjchem-2214	11	42	methylphenyl)phosphine	methylphenyl)phosphine	PROPN
eurjchem-2214	11	43	,	,	PUNCT
eurjchem-2214	11	44	dppe	dppe	PROPN
eurjchem-2214	11	45	/	/	SYM
eurjchem-2214	11	46	p	p	X
eurjchem-2214	11	47	�	�	X
eurjchem-2214	11	48	p	p	X
eurjchem-2214	11	49	:	:	PUNCT
eurjchem-2214	11	50	1,2	1,2	NUM
eurjchem-2214	11	51	-	-	SYM
eurjchem-2214	11	52	bis(diphenylphosphino)ethane	bis(diphenylphosphino)ethane	NUM
eurjchem-2214	11	53	]	]	PUNCT
eurjchem-2214	11	54	have	have	AUX
eurjchem-2214	11	55	been	be	AUX
eurjchem-2214	11	56	prepared	prepare	VERB
eurjchem-2214	11	57	from	from	ADP
eurjchem-2214	11	58	the	the	DET
eurjchem-2214	11	59	parent	parent	NOUN
eurjchem-2214	11	60	bisdithiocarbamate	bisdithiocarbamate	NOUN
eurjchem-2214	11	61	,	,	PUNCT
eurjchem-2214	11	62	[	[	X
eurjchem-2214	11	63	ni(pyrdtc)]2	ni(pyrdtc)]2	ADV
eurjchem-2214	11	64	(	(	PUNCT
eurjchem-2214	11	65	6	6	NUM
eurjchem-2214	11	66	)	)	PUNCT
eurjchem-2214	11	67	.	.	PUNCT
eurjchem-2214	12	1	the	the	DET
eurjchem-2214	12	2	prepared	prepare	VERB
eurjchem-2214	12	3	compounds	compound	NOUN
eurjchem-2214	12	4	were	be	AUX
eurjchem-2214	12	5	characterized	characterize	VERB
eurjchem-2214	12	6	by	by	ADP
eurjchem-2214	12	7	electronic	electronic	ADJ
eurjchem-2214	12	8	,	,	PUNCT
eurjchem-2214	12	9	ir	ir	PROPN
eurjchem-2214	12	10	,	,	PUNCT
eurjchem-2214	12	11	1h	1h	NUM
eurjchem-2214	12	12	,	,	PUNCT
eurjchem-2214	12	13	13c	13c	NOUN
eurjchem-2214	12	14	,	,	PUNCT
eurjchem-2214	12	15	and	and	CCONJ
eurjchem-2214	12	16	31p	31p	NUM
eurjchem-2214	12	17	nmr	nmr	NOUN
eurjchem-2214	12	18	spectra	spectra	NOUN
eurjchem-2214	12	19	.	.	PUNCT
eurjchem-2214	13	1	in	in	ADP
eurjchem-2214	13	2	the	the	DET
eurjchem-2214	13	3	ir	ir	PROPN
eurjchem-2214	13	4	spectra	spectra	NOUN
eurjchem-2214	13	5	of	of	ADP
eurjchem-2214	13	6	the	the	DET
eurjchem-2214	13	7	compounds	compound	NOUN
eurjchem-2214	13	8	,	,	PUNCT
eurjchem-2214	13	9	thioureide	thioureide	ADJ
eurjchem-2214	13	10	bands	band	NOUN
eurjchem-2214	13	11	are	be	AUX
eurjchem-2214	13	12	observed	observe	VERB
eurjchem-2214	13	13	at	at	ADP
eurjchem-2214	13	14	higher	high	ADJ
eurjchem-2214	13	15	wavenumbers	wavenumber	NOUN
eurjchem-2214	13	16	for	for	ADP
eurjchem-2214	13	17	the	the	DET
eurjchem-2214	13	18	mixed	mixed	ADJ
eurjchem-2214	13	19	ligand	ligand	NOUN
eurjchem-2214	13	20	complexes	complex	NOUN
eurjchem-2214	13	21	1	1	NUM
eurjchem-2214	13	22	-	-	SYM
eurjchem-2214	13	23	5	5	NUM
eurjchem-2214	13	24	(	(	PUNCT
eurjchem-2214	13	25	1528	1528	NUM
eurjchem-2214	13	26	-	-	SYM
eurjchem-2214	13	27	1540	1540	NUM
eurjchem-2214	13	28	cm-1	cm-1	NOUN
eurjchem-2214	13	29	)	)	PUNCT
eurjchem-2214	13	30	than	than	ADP
eurjchem-2214	13	31	the	the	DET
eurjchem-2214	13	32	parent	parent	NOUN
eurjchem-2214	13	33	compound	compound	NOUN
eurjchem-2214	13	34	(	(	PUNCT
eurjchem-2214	13	35	1490	1490	NUM
eurjchem-2214	13	36	cm-1	cm-1	NOUN
eurjchem-2214	13	37	)	)	PUNCT
eurjchem-2214	13	38	.	.	PUNCT
eurjchem-2214	14	1	cyclic	cyclic	ADJ
eurjchem-2214	14	2	voltammetry	voltammetry	NOUN
eurjchem-2214	14	3	showed	show	VERB
eurjchem-2214	14	4	an	an	DET
eurjchem-2214	14	5	increasing	increase	VERB
eurjchem-2214	14	6	order	order	NOUN
eurjchem-2214	14	7	of	of	ADP
eurjchem-2214	14	8	reduction	reduction	NOUN
eurjchem-2214	14	9	potentials	potential	VERB
eurjchem-2214	14	10	:	:	PUNCT
eurjchem-2214	14	11	5	5	NUM
eurjchem-2214	14	12	<	<	X
eurjchem-2214	14	13	<	<	X
eurjchem-2214	14	14	1	1	NUM
eurjchem-2214	14	15	~	~	SYM
eurjchem-2214	14	16	2	2	NUM
eurjchem-2214	14	17	<	<	X
eurjchem-2214	14	18	3	3	NUM
eurjchem-2214	14	19	<	<	X
eurjchem-2214	14	20	4	4	NUM
eurjchem-2214	14	21	<	<	X
eurjchem-2214	14	22	<	<	X
eurjchem-2214	14	23	[	[	X
eurjchem-2214	14	24	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	14	25	]	]	PUNCT
eurjchem-2214	14	26	indicating	indicate	VERB
eurjchem-2214	14	27	an	an	DET
eurjchem-2214	14	28	alleviation	alleviation	NOUN
eurjchem-2214	14	29	of	of	ADP
eurjchem-2214	14	30	electron	electron	NOUN
eurjchem-2214	14	31	density	density	NOUN
eurjchem-2214	14	32	on	on	ADP
eurjchem-2214	14	33	nickel	nickel	NOUN
eurjchem-2214	14	34	in	in	ADP
eurjchem-2214	14	35	the	the	DET
eurjchem-2214	14	36	mixed	mixed	ADJ
eurjchem-2214	14	37	complexes	complex	NOUN
eurjchem-2214	14	38	compared	compare	VERB
eurjchem-2214	14	39	to	to	ADP
eurjchem-2214	14	40	the	the	DET
eurjchem-2214	14	41	parent	parent	NOUN
eurjchem-2214	14	42	compound	compound	NOUN
eurjchem-2214	14	43	.	.	PUNCT
eurjchem-2214	15	1	single	single	ADJ
eurjchem-2214	15	2	crystal	crystal	PROPN
eurjchem-2214	15	3	x	x	PROPN
eurjchem-2214	15	4	-	-	NOUN
eurjchem-2214	15	5	ray	ray	NOUN
eurjchem-2214	15	6	structure	structure	NOUN
eurjchem-2214	15	7	of	of	ADP
eurjchem-2214	15	8	the	the	DET
eurjchem-2214	15	9	complexes	complex	NOUN
eurjchem-2214	15	10	displayed	display	VERB
eurjchem-2214	15	11	planar	planar	ADJ
eurjchem-2214	15	12	geometry	geometry	NOUN
eurjchem-2214	15	13	around	around	ADP
eurjchem-2214	15	14	nickel	nickel	NOUN
eurjchem-2214	15	15	which	which	PRON
eurjchem-2214	15	16	is	be	AUX
eurjchem-2214	15	17	in	in	ADP
eurjchem-2214	15	18	keeping	keep	VERB
eurjchem-2214	15	19	with	with	ADP
eurjchem-2214	15	20	their	their	PRON
eurjchem-2214	15	21	diamagnetism	diamagnetism	NOUN
eurjchem-2214	15	22	.	.	PUNCT
eurjchem-2214	16	1	bond	bond	NOUN
eurjchem-2214	16	2	valence	valence	NOUN
eurjchem-2214	16	3	sums	sum	NOUN
eurjchem-2214	16	4	calculated	calculate	VERB
eurjchem-2214	16	5	with	with	ADP
eurjchem-2214	16	6	the	the	DET
eurjchem-2214	16	7	corrected	correct	VERB
eurjchem-2214	16	8	rij	rij	PROPN
eurjchem-2214	16	9	indicated	indicate	VERB
eurjchem-2214	16	10	the	the	DET
eurjchem-2214	16	11	divalent	divalent	ADJ
eurjchem-2214	16	12	nature	nature	NOUN
eurjchem-2214	16	13	of	of	ADP
eurjchem-2214	16	14	nickel	nickel	NOUN
eurjchem-2214	16	15	with	with	ADP
eurjchem-2214	16	16	predominant	predominant	ADJ
eurjchem-2214	16	17	covalent	covalent	ADJ
eurjchem-2214	16	18	interactions	interaction	NOUN
eurjchem-2214	16	19	.	.	PUNCT
eurjchem-2214	17	1	continuous	continuous	ADJ
eurjchem-2214	17	2	shape	shape	NOUN
eurjchem-2214	17	3	measure	measure	NOUN
eurjchem-2214	17	4	analysis	analysis	NOUN
eurjchem-2214	17	5	of	of	ADP
eurjchem-2214	17	6	the	the	DET
eurjchem-2214	17	7	mixed	mixed	ADJ
eurjchem-2214	17	8	ligand	ligand	NOUN
eurjchem-2214	17	9	chromophores	chromophore	NOUN
eurjchem-2214	17	10	stipulates	stipulate	VERB
eurjchem-2214	17	11	a	a	DET
eurjchem-2214	17	12	planar	planar	ADJ
eurjchem-2214	17	13	square	square	ADJ
eurjchem-2214	17	14	environment	environment	NOUN
eurjchem-2214	17	15	around	around	ADP
eurjchem-2214	17	16	central	central	ADJ
eurjchem-2214	17	17	nickel	nickel	NOUN
eurjchem-2214	17	18	atom	atom	NOUN
eurjchem-2214	17	19	and	and	CCONJ
eurjchem-2214	17	20	deviation	deviation	NOUN
eurjchem-2214	17	21	to	to	AUX
eurjchem-2214	17	22	tetrahedral	tetrahedral	ADJ
eurjchem-2214	17	23	or	or	CCONJ
eurjchem-2214	17	24	trigonal	trigonal	ADJ
eurjchem-2214	17	25	bipyramidal	bipyramidal	ADJ
eurjchem-2214	17	26	variants	variant	NOUN
eurjchem-2214	17	27	are	be	AUX
eurjchem-2214	17	28	absolutely	absolutely	ADV
eurjchem-2214	17	29	negated	negate	VERB
eurjchem-2214	17	30	.	.	PUNCT
eurjchem-2214	18	1	in	in	ADP
eurjchem-2214	18	2	this	this	DET
eurjchem-2214	18	3	study	study	NOUN
eurjchem-2214	18	4	,	,	PUNCT
eurjchem-2214	18	5	csm	csm	VERB
eurjchem-2214	18	6	analysis	analysis	NOUN
eurjchem-2214	18	7	of	of	ADP
eurjchem-2214	18	8	cis	cis	NOUN
eurjchem-2214	18	9	-	-	PUNCT
eurjchem-2214	18	10	platin	platin	NOUN
eurjchem-2214	18	11	,	,	PUNCT
eurjchem-2214	18	12	a	a	DET
eurjchem-2214	18	13	clinical	clinical	ADJ
eurjchem-2214	18	14	anti	anti	ADJ
eurjchem-2214	18	15	-	-	ADJ
eurjchem-2214	18	16	cancer	cancer	ADJ
eurjchem-2214	18	17	agent	agent	NOUN
eurjchem-2214	18	18	,	,	PUNCT
eurjchem-2214	18	19	showed	show	VERB
eurjchem-2214	18	20	a	a	DET
eurjchem-2214	18	21	comparable	comparable	ADJ
eurjchem-2214	18	22	shape	shape	NOUN
eurjchem-2214	18	23	measure	measure	NOUN
eurjchem-2214	18	24	as	as	ADP
eurjchem-2214	18	25	those	those	PRON
eurjchem-2214	18	26	of	of	ADP
eurjchem-2214	18	27	the	the	DET
eurjchem-2214	18	28	mixed	mixed	ADJ
eurjchem-2214	18	29	ligand	ligand	NOUN
eurjchem-2214	18	30	complexes	complex	NOUN
eurjchem-2214	18	31	1	1	NUM
eurjchem-2214	18	32	-	-	SYM
eurjchem-2214	18	33	5	5	NUM
eurjchem-2214	18	34	.	.	PUNCT
eurjchem-2214	19	1	hence	hence	ADV
eurjchem-2214	19	2	,	,	PUNCT
eurjchem-2214	19	3	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	ADJ
eurjchem-2214	19	4	acts	act	NOUN
eurjchem-2214	19	5	as	as	ADP
eurjchem-2214	19	6	a	a	DET
eurjchem-2214	19	7	‘	'	PUNCT
eurjchem-2214	19	8	chuck	chuck	NOUN
eurjchem-2214	19	9	’	'	PUNCT
eurjchem-2214	19	10	in	in	ADP
eurjchem-2214	19	11	compounds	compound	NOUN
eurjchem-2214	19	12	1	1	NUM
eurjchem-2214	19	13	-	-	SYM
eurjchem-2214	19	14	5	5	NUM
eurjchem-2214	19	15	to	to	PART
eurjchem-2214	19	16	stabilize	stabilize	VERB
eurjchem-2214	19	17	the	the	DET
eurjchem-2214	19	18	planar	planar	ADJ
eurjchem-2214	19	19	square	square	ADJ
eurjchem-2214	19	20	shape	shape	NOUN
eurjchem-2214	19	21	of	of	ADP
eurjchem-2214	19	22	the	the	DET
eurjchem-2214	19	23	nickel	nickel	NOUN
eurjchem-2214	19	24	chromophores	chromophore	NOUN
eurjchem-2214	19	25	and	and	CCONJ
eurjchem-2214	19	26	provides	provide	VERB
eurjchem-2214	19	27	a	a	DET
eurjchem-2214	19	28	suitable	suitable	ADJ
eurjchem-2214	19	29	template	template	NOUN
eurjchem-2214	19	30	to	to	PART
eurjchem-2214	19	31	synthesize	synthesize	VERB
eurjchem-2214	19	32	analogues	analogue	NOUN
eurjchem-2214	19	33	of	of	ADP
eurjchem-2214	19	34	cis	cis	NOUN
eurjchem-2214	19	35	-	-	PUNCT
eurjchem-2214	19	36	platin	platin	NOUN
eurjchem-2214	19	37	.	.	PUNCT
eurjchem-2214	20	1	planarity	planarity	NOUN
eurjchem-2214	20	2	chuck	chuck	PROPN
eurjchem-2214	20	3	triphenylphosphine	triphenylphosphine	PROPN
eurjchem-2214	20	4	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	PROPN
eurjchem-2214	20	5	bond	bond	NOUN
eurjchem-2214	20	6	valence	valence	NOUN
eurjchem-2214	20	7	sum	sum	NOUN
eurjchem-2214	20	8	analysis	analysis	NOUN
eurjchem-2214	20	9	1,2	1,2	NUM
eurjchem-2214	20	10	-	-	SYM
eurjchem-2214	20	11	bis(diphenylphosphino)ethane	bis(diphenylphosphino)ethane	NUM
eurjchem-2214	20	12	continuous	continuous	ADJ
eurjchem-2214	20	13	shape	shape	NOUN
eurjchem-2214	20	14	measure	measure	NOUN
eurjchem-2214	20	15	analysis	analysis	NOUN
eurjchem-2214	20	16	cite	cite	VERB
eurjchem-2214	20	17	this	this	PRON
eurjchem-2214	20	18	:	:	PUNCT
eurjchem-2214	20	19	eur	eur	PROPN
eurjchem-2214	20	20	.	.	PUNCT
eurjchem-2214	21	1	j.	j.	PROPN
eurjchem-2214	21	2	chem	chem	PROPN
eurjchem-2214	21	3	.	.	PUNCT
eurjchem-2214	22	1	2022	2022	NUM
eurjchem-2214	22	2	,	,	PUNCT
eurjchem-2214	22	3	13(1	13(1	NUM
eurjchem-2214	22	4	)	)	PUNCT
eurjchem-2214	22	5	,	,	PUNCT
eurjchem-2214	22	6	117	117	NUM
eurjchem-2214	22	7	-	-	SYM
eurjchem-2214	22	8	125	125	NUM
eurjchem-2214	22	9	journal	journal	NOUN
eurjchem-2214	22	10	website	website	NOUN
eurjchem-2214	22	11	:	:	PUNCT
eurjchem-2214	22	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2214	22	13	1	1	X
eurjchem-2214	22	14	.	.	PUNCT
eurjchem-2214	22	15	introduction	introduction	NOUN
eurjchem-2214	22	16	research	research	NOUN
eurjchem-2214	22	17	on	on	ADP
eurjchem-2214	22	18	metal	metal	NOUN
eurjchem-2214	22	19	-	-	PUNCT
eurjchem-2214	22	20	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2214	22	21	compounds	compound	NOUN
eurjchem-2214	22	22	has	have	AUX
eurjchem-2214	22	23	been	be	AUX
eurjchem-2214	22	24	ruling	rule	VERB
eurjchem-2214	22	25	the	the	DET
eurjchem-2214	22	26	roost	roost	NOUN
eurjchem-2214	22	27	for	for	ADP
eurjchem-2214	22	28	more	more	ADJ
eurjchem-2214	22	29	than	than	ADP
eurjchem-2214	22	30	six	six	NUM
eurjchem-2214	22	31	decades	decade	NOUN
eurjchem-2214	22	32	now	now	ADV
eurjchem-2214	22	33	because	because	SCONJ
eurjchem-2214	22	34	of	of	ADP
eurjchem-2214	22	35	the	the	DET
eurjchem-2214	22	36	remarkable	remarkable	ADJ
eurjchem-2214	22	37	structural	structural	ADJ
eurjchem-2214	22	38	assortment	assortment	NOUN
eurjchem-2214	22	39	and	and	CCONJ
eurjchem-2214	22	40	applications	application	NOUN
eurjchem-2214	22	41	in	in	ADP
eurjchem-2214	22	42	diverse	diverse	ADJ
eurjchem-2214	22	43	fields	field	NOUN
eurjchem-2214	22	44	[	[	X
eurjchem-2214	22	45	1	1	NUM
eurjchem-2214	22	46	-	-	SYM
eurjchem-2214	22	47	7	7	NUM
eurjchem-2214	22	48	]	]	PUNCT
eurjchem-2214	22	49	.	.	PUNCT
eurjchem-2214	23	1	in	in	ADP
eurjchem-2214	23	2	particular	particular	ADJ
eurjchem-2214	23	3	,	,	PUNCT
eurjchem-2214	23	4	the	the	DET
eurjchem-2214	23	5	formation	formation	NOUN
eurjchem-2214	23	6	of	of	ADP
eurjchem-2214	23	7	nano	nano	NOUN
eurjchem-2214	23	8	metal	metal	NOUN
eurjchem-2214	23	9	sulphides	sulphide	NOUN
eurjchem-2214	23	10	from	from	ADP
eurjchem-2214	23	11	single	single	ADJ
eurjchem-2214	23	12	source	source	NOUN
eurjchem-2214	23	13	precursors	precursor	NOUN
eurjchem-2214	23	14	has	have	AUX
eurjchem-2214	23	15	resulted	result	VERB
eurjchem-2214	23	16	in	in	ADP
eurjchem-2214	23	17	a	a	DET
eurjchem-2214	23	18	surge	surge	NOUN
eurjchem-2214	23	19	of	of	ADP
eurjchem-2214	23	20	publications	publication	NOUN
eurjchem-2214	23	21	[	[	X
eurjchem-2214	23	22	8	8	NUM
eurjchem-2214	23	23	-	-	SYM
eurjchem-2214	23	24	11	11	NUM
eurjchem-2214	23	25	]	]	PUNCT
eurjchem-2214	23	26	.	.	PUNCT
eurjchem-2214	24	1	group	group	NOUN
eurjchem-2214	24	2	x	x	PROPN
eurjchem-2214	24	3	dithiolates	dithiolates	PROPN
eurjchem-2214	24	4	undergo	undergo	VERB
eurjchem-2214	24	5	substitution	substitution	NOUN
eurjchem-2214	24	6	reactions	reaction	NOUN
eurjchem-2214	24	7	with	with	ADP
eurjchem-2214	24	8	soft	soft	ADJ
eurjchem-2214	24	9	phosphines	phosphine	NOUN
eurjchem-2214	24	10	and	and	CCONJ
eurjchem-2214	24	11	hard	hard	ADJ
eurjchem-2214	24	12	nitrogenous	nitrogenous	ADJ
eurjchem-2214	24	13	bases	basis	NOUN
eurjchem-2214	24	14	due	due	ADP
eurjchem-2214	24	15	to	to	ADP
eurjchem-2214	24	16	their	their	PRON
eurjchem-2214	24	17	borderline	borderline	NOUN
eurjchem-2214	24	18	nature	nature	NOUN
eurjchem-2214	24	19	.	.	PUNCT
eurjchem-2214	25	1	detailed	detailed	ADJ
eurjchem-2214	25	2	structural	structural	ADJ
eurjchem-2214	25	3	and	and	CCONJ
eurjchem-2214	25	4	spectral	spectral	ADJ
eurjchem-2214	25	5	studies	study	NOUN
eurjchem-2214	25	6	on	on	ADP
eurjchem-2214	25	7	a	a	DET
eurjchem-2214	25	8	variety	variety	NOUN
eurjchem-2214	25	9	of	of	ADP
eurjchem-2214	25	10	planar	planar	PROPN
eurjchem-2214	25	11	nis	nis	PROPN
eurjchem-2214	25	12	�	�	PROPN
eurjchem-2214	25	13	s	s	PART
eurjchem-2214	25	14	/	/	SYM
eurjchem-2214	25	15	c	c	NOUN
eurjchem-2214	25	16	/	/	SYM
eurjchem-2214	25	17	n	n	CCONJ
eurjchem-2214	25	18	/	/	SYM
eurjchem-2214	25	19	p	p	X
eurjchem-2214	25	20	�	�	PROPN
eurjchem-2214	25	21	p	p	NOUN
eurjchem-2214	25	22	chromophores	chromophore	NOUN
eurjchem-2214	25	23	have	have	AUX
eurjchem-2214	25	24	been	be	AUX
eurjchem-2214	25	25	undertaken	undertake	VERB
eurjchem-2214	25	26	from	from	ADP
eurjchem-2214	25	27	this	this	DET
eurjchem-2214	25	28	laboratory	laboratory	NOUN
eurjchem-2214	25	29	as	as	ADV
eurjchem-2214	25	30	well	well	ADV
eurjchem-2214	25	31	as	as	ADP
eurjchem-2214	25	32	by	by	ADP
eurjchem-2214	25	33	others	other	NOUN
eurjchem-2214	25	34	[	[	X
eurjchem-2214	25	35	1218	1218	NUM
eurjchem-2214	25	36	]	]	PUNCT
eurjchem-2214	25	37	.	.	PUNCT
eurjchem-2214	26	1	transition	transition	NOUN
eurjchem-2214	26	2	metal	metal	NOUN
eurjchem-2214	26	3	chalcogenides	chalcogenide	NOUN
eurjchem-2214	26	4	and	and	CCONJ
eurjchem-2214	26	5	phosphine	phosphine	NOUN
eurjchem-2214	26	6	complexes	complex	NOUN
eurjchem-2214	26	7	find	find	VERB
eurjchem-2214	26	8	use	use	NOUN
eurjchem-2214	26	9	as	as	ADP
eurjchem-2214	26	10	semiconducting	semiconducting	NOUN
eurjchem-2214	26	11	,	,	PUNCT
eurjchem-2214	26	12	optical	optical	ADJ
eurjchem-2214	26	13	magnetic	magnetic	NOUN
eurjchem-2214	26	14	,	,	PUNCT
eurjchem-2214	26	15	catalytic	catalytic	ADJ
eurjchem-2214	26	16	materials	material	NOUN
eurjchem-2214	26	17	,	,	PUNCT
eurjchem-2214	26	18	and	and	CCONJ
eurjchem-2214	26	19	as	as	ADP
eurjchem-2214	26	20	anti	anti	ADJ
eurjchem-2214	26	21	-	-	ADJ
eurjchem-2214	26	22	cancer	cancer	ADJ
eurjchem-2214	26	23	agents	agent	NOUN
eurjchem-2214	26	24	[	[	X
eurjchem-2214	26	25	19	19	NUM
eurjchem-2214	26	26	-	-	SYM
eurjchem-2214	26	27	23	23	NUM
eurjchem-2214	26	28	]	]	PUNCT
eurjchem-2214	26	29	.	.	PUNCT
eurjchem-2214	27	1	in	in	ADP
eurjchem-2214	27	2	this	this	DET
eurjchem-2214	27	3	connection	connection	NOUN
eurjchem-2214	27	4	,	,	PUNCT
eurjchem-2214	27	5	it	it	PRON
eurjchem-2214	27	6	is	be	AUX
eurjchem-2214	27	7	noteworthy	noteworthy	ADJ
eurjchem-2214	27	8	that	that	SCONJ
eurjchem-2214	27	9	five	five	NUM
eurjchem-2214	27	10	of	of	ADP
eurjchem-2214	27	11	the	the	DET
eurjchem-2214	27	12	anticancer	anticancer	NOUN
eurjchem-2214	27	13	drugs	drug	NOUN
eurjchem-2214	27	14	approved	approve	VERB
eurjchem-2214	27	15	for	for	ADP
eurjchem-2214	27	16	treating	treat	VERB
eurjchem-2214	27	17	a	a	DET
eurjchem-2214	27	18	variety	variety	NOUN
eurjchem-2214	27	19	of	of	ADP
eurjchem-2214	27	20	testicular	testicular	NOUN
eurjchem-2214	27	21	,	,	PUNCT
eurjchem-2214	27	22	ovarian	ovarian	ADJ
eurjchem-2214	27	23	,	,	PUNCT
eurjchem-2214	27	24	lung	lung	NOUN
eurjchem-2214	27	25	(	(	PUNCT
eurjchem-2214	27	26	nsclc	nsclc	NOUN
eurjchem-2214	27	27	)	)	PUNCT
eurjchem-2214	27	28	,	,	PUNCT
eurjchem-2214	27	29	head	head	NOUN
eurjchem-2214	27	30	and	and	CCONJ
eurjchem-2214	27	31	neck	neck	NOUN
eurjchem-2214	27	32	,	,	PUNCT
eurjchem-2214	27	33	bladder	bladder	NOUN
eurjchem-2214	27	34	,	,	PUNCT
eurjchem-2214	27	35	gastric	gastric	ADJ
eurjchem-2214	27	36	cancers	cancer	NOUN
eurjchem-2214	27	37	,	,	PUNCT
eurjchem-2214	27	38	and	and	CCONJ
eurjchem-2214	27	39	other	other	ADJ
eurjchem-2214	27	40	malignancies	malignancy	NOUN
eurjchem-2214	27	41	are	be	AUX
eurjchem-2214	27	42	cisplatin	cisplatin	NOUN
eurjchem-2214	27	43	,	,	PUNCT
eurjchem-2214	27	44	carboplatin	carboplatin	NOUN
eurjchem-2214	27	45	and	and	CCONJ
eurjchem-2214	27	46	oxaliplatin	oxaliplatin	NOUN
eurjchem-2214	27	47	(	(	PUNCT
eurjchem-2214	27	48	worldwide	worldwide	ADV
eurjchem-2214	27	49	)	)	PUNCT
eurjchem-2214	27	50	,	,	PUNCT
eurjchem-2214	27	51	nedaplatin	nedaplatin	NOUN
eurjchem-2214	27	52	(	(	PUNCT
eurjchem-2214	27	53	japan	japan	PROPN
eurjchem-2214	27	54	)	)	PUNCT
eurjchem-2214	27	55	and	and	CCONJ
eurjchem-2214	27	56	lobaplatin	lobaplatin	NOUN
eurjchem-2214	27	57	(	(	PUNCT
eurjchem-2214	27	58	china	china	PROPN
eurjchem-2214	27	59	)	)	PUNCT
eurjchem-2214	28	1	[	[	X
eurjchem-2214	28	2	24	24	NUM
eurjchem-2214	28	3	-	-	SYM
eurjchem-2214	28	4	28	28	NUM
eurjchem-2214	28	5	]	]	PUNCT
eurjchem-2214	28	6	.	.	PUNCT
eurjchem-2214	29	1	however	however	ADV
eurjchem-2214	29	2	,	,	PUNCT
eurjchem-2214	29	3	the	the	DET
eurjchem-2214	29	4	major	major	ADJ
eurjchem-2214	29	5	dose	dose	NOUN
eurjchem-2214	29	6	-	-	PUNCT
eurjchem-2214	29	7	limiting	limit	VERB
eurjchem-2214	29	8	toxicity	toxicity	NOUN
eurjchem-2214	29	9	of	of	ADP
eurjchem-2214	29	10	cis	cis	NOUN
eurjchem-2214	29	11	-	-	PUNCT
eurjchem-2214	29	12	platin	platin	NOUN
eurjchem-2214	29	13	is	be	AUX
eurjchem-2214	29	14	its	its	PRON
eurjchem-2214	29	15	renal	renal	ADJ
eurjchem-2214	29	16	toxicity	toxicity	NOUN
eurjchem-2214	29	17	observed	observe	VERB
eurjchem-2214	29	18	in	in	ADP
eurjchem-2214	29	19	28	28	NUM
eurjchem-2214	29	20	to	to	PART
eurjchem-2214	29	21	36	36	NUM
eurjchem-2214	29	22	%	%	NOUN
eurjchem-2214	29	23	of	of	ADP
eurjchem-2214	29	24	patients	patient	NOUN
eurjchem-2214	29	25	during	during	ADP
eurjchem-2214	29	26	chemotherapy	chemotherapy	NOUN
eurjchem-2214	29	27	[	[	X
eurjchem-2214	29	28	29	29	NUM
eurjchem-2214	29	29	]	]	PUNCT
eurjchem-2214	29	30	.	.	PUNCT
eurjchem-2214	30	1	therefore	therefore	ADV
eurjchem-2214	30	2	,	,	PUNCT
eurjchem-2214	30	3	the	the	DET
eurjchem-2214	30	4	attempts	attempt	NOUN
eurjchem-2214	30	5	have	have	AUX
eurjchem-2214	30	6	been	be	AUX
eurjchem-2214	30	7	made	make	VERB
eurjchem-2214	30	8	to	to	PART
eurjchem-2214	30	9	identify	identify	VERB
eurjchem-2214	30	10	less	less	ADV
eurjchem-2214	30	11	toxic	toxic	ADJ
eurjchem-2214	30	12	nickel(ii	nickel(ii	ADJ
eurjchem-2214	30	13	)	)	PUNCT
eurjchem-2214	30	14	analogues	analogue	NOUN
eurjchem-2214	30	15	of	of	ADP
eurjchem-2214	30	16	cis	cis	NOUN
eurjchem-2214	30	17	-	-	PUNCT
eurjchem-2214	30	18	platin	platin	NOUN
eurjchem-2214	30	19	in	in	ADP
eurjchem-2214	30	20	the	the	DET
eurjchem-2214	30	21	past	past	NOUN
eurjchem-2214	30	22	and	and	CCONJ
eurjchem-2214	30	23	a	a	DET
eurjchem-2214	30	24	salen	salen	ADJ
eurjchem-2214	30	25	complex	complex	NOUN
eurjchem-2214	30	26	of	of	ADP
eurjchem-2214	30	27	nickel	nickel	NOUN
eurjchem-2214	30	28	was	be	AUX
eurjchem-2214	30	29	screened	screen	VERB
eurjchem-2214	30	30	and	and	CCONJ
eurjchem-2214	30	31	was	be	AUX
eurjchem-2214	30	32	found	find	VERB
eurjchem-2214	30	33	to	to	PART
eurjchem-2214	30	34	be	be	AUX
eurjchem-2214	30	35	active	active	ADJ
eurjchem-2214	30	36	[	[	X
eurjchem-2214	30	37	30	30	NUM
eurjchem-2214	30	38	]	]	PUNCT
eurjchem-2214	30	39	.	.	PUNCT
eurjchem-2214	31	1	cis	cis	NOUN
eurjchem-2214	31	2	-	-	PUNCT
eurjchem-2214	31	3	platin	platin	NOUN
eurjchem-2214	31	4	activity	activity	NOUN
eurjchem-2214	31	5	is	be	AUX
eurjchem-2214	31	6	related	relate	VERB
eurjchem-2214	31	7	to	to	ADP
eurjchem-2214	31	8	its	its	PRON
eurjchem-2214	31	9	ability	ability	NOUN
eurjchem-2214	31	10	to	to	PART
eurjchem-2214	31	11	bind	bind	VERB
eurjchem-2214	31	12	to	to	ADP
eurjchem-2214	31	13	nitrogen	nitrogen	NOUN
eurjchem-2214	31	14	atom	atom	NOUN
eurjchem-2214	31	15	of	of	ADP
eurjchem-2214	31	16	dna	dna	PROPN
eurjchem-2214	31	17	after	after	SCONJ
eurjchem-2214	31	18	its	its	PRON
eurjchem-2214	31	19	in	in	ADP
eurjchem-2214	31	20	vivo	vivo	ADJ
eurjchem-2214	31	21	transformation	transformation	NOUN
eurjchem-2214	31	22	to	to	ADP
eurjchem-2214	31	23	cis-[pt(nh3)2(h2o)2]2+and	cis-[pt(nh3)2(h2o)2]2+and	NOUN
eurjchem-2214	31	24	most	most	ADV
eurjchem-2214	31	25	importantly	importantly	ADV
eurjchem-2214	31	26	,	,	PUNCT
eurjchem-2214	31	27	platinum(ii	platinum(ii	ADJ
eurjchem-2214	31	28	)	)	PUNCT
eurjchem-2214	31	29	retains	retain	VERB
eurjchem-2214	31	30	its	its	PRON
eurjchem-2214	31	31	planarity	planarity	NOUN
eurjchem-2214	31	32	all	all	ADV
eurjchem-2214	31	33	over	over	ADV
eurjchem-2214	31	34	because	because	SCONJ
eurjchem-2214	31	35	of	of	ADP
eurjchem-2214	31	36	the	the	DET
eurjchem-2214	31	37	relatively	relatively	ADV
eurjchem-2214	31	38	large	large	ADJ
eurjchem-2214	31	39	lfse	lfse	NOUN
eurjchem-2214	31	40	associated	associate	VERB
eurjchem-2214	31	41	with	with	ADP
eurjchem-2214	31	42	it	it	PRON
eurjchem-2214	31	43	compared	compare	VERB
eurjchem-2214	31	44	to	to	ADP
eurjchem-2214	31	45	nickel	nickel	NOUN
eurjchem-2214	31	46	and	and	CCONJ
eurjchem-2214	31	47	palladium	palladium	NOUN
eurjchem-2214	31	48	.	.	PUNCT
eurjchem-2214	32	1	relatively	relatively	ADV
eurjchem-2214	32	2	,	,	PUNCT
eurjchem-2214	32	3	higher	high	ADJ
eurjchem-2214	32	4	electronegativity	electronegativity	NOUN
eurjchem-2214	32	5	of	of	ADP
eurjchem-2214	32	6	ni2	ni2	PROPN
eurjchem-2214	32	7	+	+	PROPN
eurjchem-2214	32	8	(	(	PUNCT
eurjchem-2214	32	9	1.75	1.75	NUM
eurjchem-2214	32	10	)	)	PUNCT
eurjchem-2214	32	11	over	over	ADP
eurjchem-2214	32	12	pd2	pd2	NOUN
eurjchem-2214	32	13	+	+	CCONJ
eurjchem-2214	32	14	(	(	PUNCT
eurjchem-2214	32	15	1.35	1.35	NUM
eurjchem-2214	32	16	)	)	PUNCT
eurjchem-2214	32	17	and	and	CCONJ
eurjchem-2214	32	18	pt2	pt2	PROPN
eurjchem-2214	32	19	+	+	CCONJ
eurjchem-2214	32	20	(	(	PUNCT
eurjchem-2214	32	21	1.44	1.44	NUM
eurjchem-2214	32	22	)	)	PUNCT
eurjchem-2214	32	23	favors	favor	VERB
eurjchem-2214	32	24	the	the	DET
eurjchem-2214	32	25	formation	formation	NOUN
eurjchem-2214	32	26	of	of	ADP
eurjchem-2214	32	27	octahedral	octahedral	ADJ
eurjchem-2214	32	28	aqua	aqua	NOUN
eurjchem-2214	32	29	complexes	complex	NOUN
eurjchem-2214	32	30	than	than	ADP
eurjchem-2214	32	31	its	its	PRON
eurjchem-2214	32	32	congeners	congener	NOUN
eurjchem-2214	32	33	at	at	ADP
eurjchem-2214	32	34	a	a	DET
eurjchem-2214	32	35	facile	facile	ADJ
eurjchem-2214	32	36	rate	rate	NOUN
eurjchem-2214	32	37	,	,	PUNCT
eurjchem-2214	32	38	which	which	PRON
eurjchem-2214	32	39	is	be	AUX
eurjchem-2214	32	40	not	not	PART
eurjchem-2214	32	41	generally	generally	ADV
eurjchem-2214	32	42	desirable	desirable	ADJ
eurjchem-2214	32	43	for	for	ADP
eurjchem-2214	32	44	its	its	PRON
eurjchem-2214	32	45	anticancer	anticancer	NOUN
eurjchem-2214	32	46	activity	activity	NOUN
eurjchem-2214	32	47	as	as	ADP
eurjchem-2214	32	48	a	a	DET
eurjchem-2214	32	49	contrast	contrast	NOUN
eurjchem-2214	32	50	to	to	ADP
eurjchem-2214	32	51	platinum	platinum	NOUN
eurjchem-2214	32	52	and	and	CCONJ
eurjchem-2214	32	53	palladium	palladium	NOUN
eurjchem-2214	32	54	.	.	PUNCT
eurjchem-2214	33	1	therefore	therefore	ADV
eurjchem-2214	33	2	,	,	PUNCT
eurjchem-2214	33	3	the	the	DET
eurjchem-2214	33	4	use	use	NOUN
eurjchem-2214	33	5	of	of	ADP
eurjchem-2214	33	6	divalent	divalent	ADJ
eurjchem-2214	33	7	nickel	nickel	NOUN
eurjchem-2214	33	8	in	in	ADP
eurjchem-2214	33	9	the	the	DET
eurjchem-2214	33	10	place	place	NOUN
eurjchem-2214	33	11	of	of	ADP
eurjchem-2214	33	12	platinum	platinum	NOUN
eurjchem-2214	33	13	necessitates	necessitate	VERB
eurjchem-2214	33	14	the	the	DET
eurjchem-2214	33	15	stabilization	stabilization	NOUN
eurjchem-2214	33	16	of	of	ADP
eurjchem-2214	33	17	planarity	planarity	NOUN
eurjchem-2214	33	18	of	of	ADP
eurjchem-2214	33	19	coordination	coordination	NOUN
eurjchem-2214	33	20	environment	environment	NOUN
eurjchem-2214	33	21	.	.	PUNCT
eurjchem-2214	34	1	abstract	abstract	ADJ
eurjchem-2214	34	2	research	research	NOUN
eurjchem-2214	34	3	article	article	NOUN
eurjchem-2214	34	4	keywords	keyword	VERB
eurjchem-2214	34	5	https://dx.doi.org/10.5155/eurjchem.13.1.117-125.2214	https://dx.doi.org/10.5155/eurjchem.13.1.117-125.2214	PROPN
eurjchem-2214	34	6	https://www.eurjchem.com/	https://www.eurjchem.com/	ADJ
eurjchem-2214	34	7	https://dx.doi.org/10.5155/eurjchem.13.1.117-125.2214	https://dx.doi.org/10.5155/eurjchem.13.1.117-125.2214	PROPN
eurjchem-2214	34	8	mailto:krauchem@yahoo.com	mailto:krauchem@yahoo.com	PROPN
eurjchem-2214	34	9	http://www.eurjchem.com/	http://www.eurjchem.com/	PROPN
eurjchem-2214	34	10	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.13.1.117-125.2214&domain=pdf&date_stamp=2022-03-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.13.1.117-125.2214&domain=pdf&date_stamp=2022-03-31	PROPN
eurjchem-2214	34	11	118	118	NUM
eurjchem-2214	34	12	ramalingam	ramalingam	NOUN
eurjchem-2214	34	13	et	et	PROPN
eurjchem-2214	34	14	al	al	PROPN
eurjchem-2214	34	15	.	.	PUNCT
eurjchem-2214	34	16	/	/	SYM
eurjchem-2214	34	17	european	european	PROPN
eurjchem-2214	34	18	journal	journal	PROPN
eurjchem-2214	34	19	of	of	ADP
eurjchem-2214	34	20	chemistry	chemistry	NOUN
eurjchem-2214	34	21	13	13	NUM
eurjchem-2214	34	22	(	(	PUNCT
eurjchem-2214	34	23	1	1	NUM
eurjchem-2214	34	24	)	)	PUNCT
eurjchem-2214	34	25	(	(	PUNCT
eurjchem-2214	34	26	2022	2022	NUM
eurjchem-2214	34	27	)	)	PUNCT
eurjchem-2214	34	28	117	117	NUM
eurjchem-2214	34	29	-	-	SYM
eurjchem-2214	34	30	125	125	NUM
eurjchem-2214	34	31	2022	2022	NUM
eurjchem-2214	34	32	–	–	PUNCT
eurjchem-2214	34	33	european	european	ADJ
eurjchem-2214	34	34	journal	journal	NOUN
eurjchem-2214	34	35	of	of	ADP
eurjchem-2214	34	36	chemistry	chemistry	NOUN
eurjchem-2214	34	37	–	–	PUNCT
eurjchem-2214	34	38	cc	cc	NOUN
eurjchem-2214	34	39	by	by	ADP
eurjchem-2214	34	40	nc	nc	PROPN
eurjchem-2214	34	41	–	–	PUNCT
eurjchem-2214	34	42	doi	doi	NOUN
eurjchem-2214	34	43	:	:	PUNCT
eurjchem-2214	34	44	10.5155	10.5155	NUM
eurjchem-2214	34	45	/	/	SYM
eurjchem-2214	34	46	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	34	47	-	-	SYM
eurjchem-2214	34	48	125.2214	125.2214	NUM
eurjchem-2214	34	49	c4h8nh	c4h8nh	NOUN
eurjchem-2214	34	50	+	+	CCONJ
eurjchem-2214	34	51	cs2	cs2	NOUN
eurjchem-2214	34	52	→	→	SYM
eurjchem-2214	34	53	c4h8ncs2h	c4h8ncs2h	VERB
eurjchem-2214	34	54	2c4h8ncs2h	2c4h8ncs2h	NOUN
eurjchem-2214	34	55	+	+	CCONJ
eurjchem-2214	34	56	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	34	57	→	→	SYM
eurjchem-2214	34	58	[	[	X
eurjchem-2214	34	59	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	34	60	]	]	X
eurjchem-2214	34	61	+	+	NUM
eurjchem-2214	34	62	6h2o	6h2o	NOUN
eurjchem-2214	35	1	+	+	CCONJ
eurjchem-2214	36	1	2hcl	2hcl	NUM
eurjchem-2214	36	2	[	[	X
eurjchem-2214	36	3	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	36	4	]	]	X
eurjchem-2214	36	5	+	+	CCONJ
eurjchem-2214	36	6	2pph3	2pph3	NUM
eurjchem-2214	36	7	+	+	CCONJ
eurjchem-2214	36	8	2nh4ncs	2nh4ncs	NUM
eurjchem-2214	36	9	+	+	CCONJ
eurjchem-2214	36	10	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	36	11	→	→	SYM
eurjchem-2214	36	12	2[ni(pyrdtc)(pph3)(ncs	2[ni(pyrdtc)(pph3)(ncs	NUM
eurjchem-2214	36	13	)	)	PUNCT
eurjchem-2214	36	14	]	]	PUNCT
eurjchem-2214	37	1	+	+	CCONJ
eurjchem-2214	37	2	2nh4cl	2nh4cl	NUM
eurjchem-2214	37	3	+	+	NUM
eurjchem-2214	37	4	6h2o	6h2o	NOUN
eurjchem-2214	37	5	scheme	scheme	VERB
eurjchem-2214	37	6	1	1	NUM
eurjchem-2214	37	7	in	in	ADP
eurjchem-2214	37	8	our	our	PRON
eurjchem-2214	37	9	efforts	effort	NOUN
eurjchem-2214	37	10	to	to	PART
eurjchem-2214	37	11	identify	identify	VERB
eurjchem-2214	37	12	planar	planar	ADJ
eurjchem-2214	37	13	divalent	divalent	ADJ
eurjchem-2214	37	14	nickel	nickel	NOUN
eurjchem-2214	37	15	analogues	analogue	NOUN
eurjchem-2214	37	16	of	of	ADP
eurjchem-2214	37	17	cis	cis	NOUN
eurjchem-2214	37	18	-	-	PUNCT
eurjchem-2214	37	19	platin	platin	NOUN
eurjchem-2214	37	20	,	,	PUNCT
eurjchem-2214	37	21	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	NOUN
eurjchem-2214	37	22	is	be	AUX
eurjchem-2214	37	23	used	use	VERB
eurjchem-2214	37	24	as	as	ADP
eurjchem-2214	37	25	a	a	DET
eurjchem-2214	37	26	‘	'	PUNCT
eurjchem-2214	37	27	planarity	planarity	NOUN
eurjchem-2214	37	28	chuck	chuck	NOUN
eurjchem-2214	37	29	,	,	PUNCT
eurjchem-2214	37	30	which	which	PRON
eurjchem-2214	37	31	holds	hold	VERB
eurjchem-2214	37	32	the	the	DET
eurjchem-2214	37	33	work	work	NOUN
eurjchem-2214	37	34	piece	piece	NOUN
eurjchem-2214	37	35	’	'	PUNCT
eurjchem-2214	37	36	in	in	ADP
eurjchem-2214	37	37	this	this	DET
eurjchem-2214	37	38	study	study	NOUN
eurjchem-2214	37	39	.	.	PUNCT
eurjchem-2214	38	1	here	here	ADV
eurjchem-2214	38	2	in	in	ADV
eurjchem-2214	38	3	,	,	PUNCT
eurjchem-2214	38	4	we	we	PRON
eurjchem-2214	38	5	report	report	VERB
eurjchem-2214	38	6	the	the	DET
eurjchem-2214	38	7	synthesis	synthesis	NOUN
eurjchem-2214	38	8	,	,	PUNCT
eurjchem-2214	38	9	infrared	infrare	VERB
eurjchem-2214	38	10	,	,	PUNCT
eurjchem-2214	38	11	electronic	electronic	ADJ
eurjchem-2214	38	12	,	,	PUNCT
eurjchem-2214	38	13	1h	1h	NUM
eurjchem-2214	38	14	and	and	CCONJ
eurjchem-2214	38	15	13cnmr	13cnmr	ADJ
eurjchem-2214	38	16	spectral	spectral	ADJ
eurjchem-2214	38	17	,	,	PUNCT
eurjchem-2214	38	18	voltammetric	voltammetric	ADJ
eurjchem-2214	38	19	and	and	CCONJ
eurjchem-2214	38	20	single	single	ADJ
eurjchem-2214	38	21	crystal	crystal	NOUN
eurjchem-2214	38	22	x	x	PROPN
eurjchem-2214	38	23	-	-	NOUN
eurjchem-2214	38	24	ray	ray	NOUN
eurjchem-2214	38	25	structural	structural	ADJ
eurjchem-2214	38	26	studies	study	NOUN
eurjchem-2214	38	27	on	on	ADP
eurjchem-2214	38	28	bis(pyrrolidinecarbodithioato)nickel(ii)-phosphine	bis(pyrrolidinecarbodithioato)nickel(ii)-phosphine	NOUN
eurjchem-2214	38	29	/cyanide	/cyanide	ADJ
eurjchem-2214	38	30	/	/	SYM
eurjchem-2214	38	31	thiocyanate	thiocyanate	NOUN
eurjchem-2214	38	32	and	and	CCONJ
eurjchem-2214	38	33	dppe	dppe	NOUN
eurjchem-2214	38	34	complexes	complexe	VERB
eurjchem-2214	38	35	with	with	ADP
eurjchem-2214	38	36	nis	nis	PROPN
eurjchem-2214	38	37	�	�	PROPN
eurjchem-2214	38	38	spn	spn	PROPN
eurjchem-2214	38	39	,	,	PUNCT
eurjchem-2214	38	40	nis	nis	PROPN
eurjchem-2214	38	41	�	�	PROPN
eurjchem-2214	38	42	spc	spc	PROPN
eurjchem-2214	38	43	,	,	PUNCT
eurjchem-2214	38	44	nis	nis	PROPN
eurjchem-2214	38	45	�	�	PROPN
eurjchem-2214	38	46	sp2	sp2	NOUN
eurjchem-2214	38	47	and	and	CCONJ
eurjchem-2214	38	48	nis	nis	PROPN
eurjchem-2214	38	49	�	�	PROPN
eurjchem-2214	38	50	sp	sp	NOUN
eurjchem-2214	38	51	�	�	PROPN
eurjchem-2214	38	52	p	p	NOUN
eurjchem-2214	38	53	chromophores	chromophore	NOUN
eurjchem-2214	38	54	.	.	PUNCT
eurjchem-2214	39	1	the	the	DET
eurjchem-2214	39	2	structural	structural	ADJ
eurjchem-2214	39	3	information	information	NOUN
eurjchem-2214	39	4	is	be	AUX
eurjchem-2214	39	5	used	use	VERB
eurjchem-2214	39	6	in	in	ADP
eurjchem-2214	39	7	the	the	DET
eurjchem-2214	39	8	evaluation	evaluation	NOUN
eurjchem-2214	39	9	of	of	ADP
eurjchem-2214	39	10	bond	bond	NOUN
eurjchem-2214	39	11	valence	valence	NOUN
eurjchem-2214	39	12	sums	sum	NOUN
eurjchem-2214	39	13	and	and	CCONJ
eurjchem-2214	39	14	continuous	continuous	ADJ
eurjchem-2214	39	15	shape	shape	NOUN
eurjchem-2214	39	16	measure	measure	NOUN
eurjchem-2214	39	17	.	.	PUNCT
eurjchem-2214	40	1	the	the	DET
eurjchem-2214	40	2	continuous	continuous	ADJ
eurjchem-2214	40	3	shape	shape	NOUN
eurjchem-2214	40	4	measure	measure	NOUN
eurjchem-2214	40	5	data	datum	NOUN
eurjchem-2214	40	6	is	be	AUX
eurjchem-2214	40	7	used	use	VERB
eurjchem-2214	40	8	to	to	PART
eurjchem-2214	40	9	assess	assess	VERB
eurjchem-2214	40	10	the	the	DET
eurjchem-2214	40	11	ruggedness	ruggedness	NOUN
eurjchem-2214	40	12	of	of	ADP
eurjchem-2214	40	13	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	NOUN
eurjchem-2214	40	14	as	as	ADP
eurjchem-2214	40	15	a	a	DET
eurjchem-2214	40	16	‘	'	PUNCT
eurjchem-2214	40	17	planarity	planarity	NOUN
eurjchem-2214	40	18	chuck	chuck	NOUN
eurjchem-2214	40	19	’	'	PUNCT
eurjchem-2214	40	20	.	.	PUNCT
eurjchem-2214	41	1	2	2	X
eurjchem-2214	41	2	.	.	X
eurjchem-2214	41	3	experimental	experimental	ADJ
eurjchem-2214	41	4	2.1	2.1	NUM
eurjchem-2214	41	5	.	.	PUNCT
eurjchem-2214	41	6	materials	material	NOUN
eurjchem-2214	41	7	and	and	CCONJ
eurjchem-2214	41	8	physical	physical	ADJ
eurjchem-2214	41	9	measurements	measurement	NOUN
eurjchem-2214	41	10	all	all	DET
eurjchem-2214	41	11	the	the	DET
eurjchem-2214	41	12	reagents	reagent	NOUN
eurjchem-2214	41	13	and	and	CCONJ
eurjchem-2214	41	14	solvents	solvent	NOUN
eurjchem-2214	41	15	were	be	AUX
eurjchem-2214	41	16	commercially	commercially	ADV
eurjchem-2214	41	17	available	available	ADJ
eurjchem-2214	41	18	high	high	ADJ
eurjchem-2214	41	19	purity	purity	NOUN
eurjchem-2214	41	20	materials	material	NOUN
eurjchem-2214	41	21	(	(	PUNCT
eurjchem-2214	41	22	merck	merck	NOUN
eurjchem-2214	41	23	)	)	PUNCT
eurjchem-2214	41	24	used	use	VERB
eurjchem-2214	41	25	as	as	SCONJ
eurjchem-2214	41	26	supplied	supply	VERB
eurjchem-2214	41	27	without	without	ADP
eurjchem-2214	41	28	further	further	ADJ
eurjchem-2214	41	29	purification	purification	NOUN
eurjchem-2214	41	30	.	.	PUNCT
eurjchem-2214	42	1	ft	ft	PROPN
eurjchem-2214	42	2	-	-	PUNCT
eurjchem-2214	42	3	ir	ir	NOUN
eurjchem-2214	42	4	spectra	spectra	NOUN
eurjchem-2214	42	5	of	of	ADP
eurjchem-2214	42	6	the	the	DET
eurjchem-2214	42	7	complexes	complex	NOUN
eurjchem-2214	42	8	were	be	AUX
eurjchem-2214	42	9	recorded	record	VERB
eurjchem-2214	42	10	on	on	ADP
eurjchem-2214	42	11	an	an	DET
eurjchem-2214	42	12	avatar	avatar	ADJ
eurjchem-2214	42	13	nicolet	nicolet	NOUN
eurjchem-2214	42	14	ft	ft	PROPN
eurjchem-2214	42	15	-	-	PUNCT
eurjchem-2214	42	16	ir	ir	NOUN
eurjchem-2214	42	17	spectrophotometer	spectrophotometer	NOUN
eurjchem-2214	42	18	(	(	PUNCT
eurjchem-2214	42	19	400	400	NUM
eurjchem-2214	42	20	-	-	SYM
eurjchem-2214	42	21	4000	4000	NUM
eurjchem-2214	42	22	cm-1	cm-1	NOUN
eurjchem-2214	42	23	)	)	PUNCT
eurjchem-2214	42	24	as	as	ADP
eurjchem-2214	42	25	kbr	kbr	PROPN
eurjchem-2214	42	26	pellets	pellet	NOUN
eurjchem-2214	42	27	.	.	PUNCT
eurjchem-2214	43	1	electronic	electronic	ADJ
eurjchem-2214	43	2	spectra	spectra	NOUN
eurjchem-2214	43	3	of	of	ADP
eurjchem-2214	43	4	the	the	DET
eurjchem-2214	43	5	complexes	complex	NOUN
eurjchem-2214	43	6	were	be	AUX
eurjchem-2214	43	7	recorded	record	VERB
eurjchem-2214	43	8	on	on	ADP
eurjchem-2214	43	9	a	a	DET
eurjchem-2214	43	10	hitachi	hitachi	PROPN
eurjchem-2214	43	11	u-2001	u-2001	PROPN
eurjchem-2214	43	12	spectrophotometer	spectrophotometer	NOUN
eurjchem-2214	43	13	in	in	ADP
eurjchem-2214	43	14	dichloromethane	dichloromethane	NOUN
eurjchem-2214	43	15	.	.	PUNCT
eurjchem-2214	44	1	cyclic	cyclic	ADJ
eurjchem-2214	44	2	voltammograms	voltammogram	NOUN
eurjchem-2214	44	3	(	(	PUNCT
eurjchem-2214	44	4	cv	cv	PROPN
eurjchem-2214	44	5	)	)	PUNCT
eurjchem-2214	44	6	of	of	ADP
eurjchem-2214	44	7	the	the	DET
eurjchem-2214	44	8	complexes	complex	NOUN
eurjchem-2214	44	9	were	be	AUX
eurjchem-2214	44	10	carried	carry	VERB
eurjchem-2214	44	11	out	out	ADP
eurjchem-2214	44	12	with	with	ADP
eurjchem-2214	44	13	ecda-001	ecda-001	NOUN
eurjchem-2214	44	14	electrochemistry	electrochemistry	NOUN
eurjchem-2214	44	15	system	system	NOUN
eurjchem-2214	44	16	at	at	ADP
eurjchem-2214	44	17	a	a	DET
eurjchem-2214	44	18	scanning	scanning	NOUN
eurjchem-2214	44	19	rate	rate	NOUN
eurjchem-2214	44	20	of	of	ADP
eurjchem-2214	44	21	100	100	NUM
eurjchem-2214	44	22	mv	mv	PROPN
eurjchem-2214	44	23	/	/	SYM
eurjchem-2214	44	24	s.	s.	PROPN
eurjchem-2214	44	25	a	a	DET
eurjchem-2214	44	26	three	three	NUM
eurjchem-2214	44	27	-	-	PUNCT
eurjchem-2214	44	28	electrode	electrode	NOUN
eurjchem-2214	44	29	system	system	NOUN
eurjchem-2214	44	30	with	with	ADP
eurjchem-2214	44	31	ag	ag	PROPN
eurjchem-2214	44	32	/	/	SYM
eurjchem-2214	44	33	agcl	agcl	NOUN
eurjchem-2214	44	34	as	as	ADP
eurjchem-2214	44	35	reference	reference	NOUN
eurjchem-2214	44	36	,	,	PUNCT
eurjchem-2214	44	37	platinum	platinum	NOUN
eurjchem-2214	44	38	wire	wire	NOUN
eurjchem-2214	44	39	as	as	ADP
eurjchem-2214	44	40	counter	counter	NOUN
eurjchem-2214	44	41	and	and	CCONJ
eurjchem-2214	44	42	glassy	glassy	NOUN
eurjchem-2214	44	43	carbon	carbon	NOUN
eurjchem-2214	44	44	as	as	SCONJ
eurjchem-2214	44	45	working	work	VERB
eurjchem-2214	44	46	electrode	electrode	NOUN
eurjchem-2214	44	47	was	be	AUX
eurjchem-2214	44	48	employed	employ	VERB
eurjchem-2214	44	49	.	.	PUNCT
eurjchem-2214	45	1	tetrabutylammonium	tetrabutylammonium	NOUN
eurjchem-2214	45	2	perchlorate	perchlorate	NOUN
eurjchem-2214	45	3	(	(	PUNCT
eurjchem-2214	45	4	tbap	tbap	NOUN
eurjchem-2214	45	5	)	)	PUNCT
eurjchem-2214	45	6	of	of	ADP
eurjchem-2214	45	7	0.1	0.1	NUM
eurjchem-2214	45	8	m	m	NOUN
eurjchem-2214	45	9	concentration	concentration	NOUN
eurjchem-2214	45	10	was	be	AUX
eurjchem-2214	45	11	used	use	VERB
eurjchem-2214	45	12	as	as	ADP
eurjchem-2214	45	13	supporting	support	VERB
eurjchem-2214	45	14	electrolyte	electrolyte	NOUN
eurjchem-2214	45	15	.	.	PUNCT
eurjchem-2214	46	1	1h-	1h-	NUM
eurjchem-2214	46	2	,	,	PUNCT
eurjchem-2214	46	3	13c-	13c-	NUM
eurjchem-2214	46	4	,	,	PUNCT
eurjchem-2214	46	5	and	and	CCONJ
eurjchem-2214	46	6	31p	31p	NOUN
eurjchem-2214	46	7	-	-	PUNCT
eurjchem-2214	46	8	nmr	nmr	NOUN
eurjchem-2214	46	9	spectra	spectra	NOUN
eurjchem-2214	46	10	of	of	ADP
eurjchem-2214	46	11	the	the	DET
eurjchem-2214	46	12	complexes	complex	NOUN
eurjchem-2214	46	13	were	be	AUX
eurjchem-2214	46	14	recorded	record	VERB
eurjchem-2214	46	15	on	on	ADP
eurjchem-2214	46	16	an	an	DET
eurjchem-2214	46	17	amx	amx	NOUN
eurjchem-2214	46	18	400	400	NUM
eurjchem-2214	46	19	instrument	instrument	NOUN
eurjchem-2214	46	20	with	with	ADP
eurjchem-2214	46	21	cdcl3	cdcl3	NOUN
eurjchem-2214	46	22	as	as	SCONJ
eurjchem-2214	46	23	solvent	solvent	ADJ
eurjchem-2214	46	24	and	and	CCONJ
eurjchem-2214	46	25	chemical	chemical	NOUN
eurjchem-2214	46	26	shifts	shift	NOUN
eurjchem-2214	46	27	are	be	AUX
eurjchem-2214	46	28	reported	report	VERB
eurjchem-2214	46	29	with	with	ADP
eurjchem-2214	46	30	reference	reference	NOUN
eurjchem-2214	46	31	to	to	ADP
eurjchem-2214	46	32	tms	tms	PROPN
eurjchem-2214	46	33	and	and	CCONJ
eurjchem-2214	46	34	h3po4	h3po4	NOUN
eurjchem-2214	46	35	.	.	PUNCT
eurjchem-2214	47	1	2.2	2.2	NUM
eurjchem-2214	47	2	.	.	PUNCT
eurjchem-2214	48	1	x	x	X
eurjchem-2214	48	2	-	-	NOUN
eurjchem-2214	48	3	ray	ray	NOUN
eurjchem-2214	48	4	crystallography	crystallography	NOUN
eurjchem-2214	48	5	the	the	DET
eurjchem-2214	48	6	intensity	intensity	NOUN
eurjchem-2214	48	7	data	datum	NOUN
eurjchem-2214	48	8	were	be	AUX
eurjchem-2214	48	9	collected	collect	VERB
eurjchem-2214	48	10	on	on	ADP
eurjchem-2214	48	11	a	a	DET
eurjchem-2214	48	12	bruker	bruker	PROPN
eurjchem-2214	48	13	axs	axs	PROPN
eurjchem-2214	48	14	smart	smart	ADJ
eurjchem-2214	48	15	single	single	ADJ
eurjchem-2214	48	16	crystal	crystal	NOUN
eurjchem-2214	48	17	diffractometer	diffractometer	NOUN
eurjchem-2214	48	18	with	with	ADP
eurjchem-2214	48	19	ccd	ccd	PROPN
eurjchem-2214	48	20	,	,	PUNCT
eurjchem-2214	48	21	using	use	VERB
eurjchem-2214	48	22	graphite	graphite	NOUN
eurjchem-2214	48	23	monochromated	monochromate	VERB
eurjchem-2214	48	24	mo	mo	PROPN
eurjchem-2214	48	25	-	-	ADJ
eurjchem-2214	48	26	kα	kα	PROPN
eurjchem-2214	48	27	radiation	radiation	NOUN
eurjchem-2214	48	28	(	(	PUNCT
eurjchem-2214	48	29	λ	λ	X
eurjchem-2214	48	30	=	=	SYM
eurjchem-2214	48	31	0.71073	0.71073	NUM
eurjchem-2214	48	32	å	å	NOUN
eurjchem-2214	48	33	)	)	PUNCT
eurjchem-2214	48	34	.	.	PUNCT
eurjchem-2214	49	1	absorption	absorption	NOUN
eurjchem-2214	49	2	corrections	correction	NOUN
eurjchem-2214	49	3	were	be	AUX
eurjchem-2214	49	4	performed	perform	VERB
eurjchem-2214	49	5	with	with	ADP
eurjchem-2214	49	6	sadabs	sadab	NOUN
eurjchem-2214	49	7	[	[	X
eurjchem-2214	49	8	31	31	NUM
eurjchem-2214	49	9	]	]	PUNCT
eurjchem-2214	49	10	.	.	PUNCT
eurjchem-2214	50	1	the	the	DET
eurjchem-2214	50	2	structures	structure	NOUN
eurjchem-2214	50	3	were	be	AUX
eurjchem-2214	50	4	solved	solve	VERB
eurjchem-2214	50	5	by	by	ADP
eurjchem-2214	50	6	direct	direct	ADJ
eurjchem-2214	50	7	methods	method	NOUN
eurjchem-2214	50	8	with	with	ADP
eurjchem-2214	50	9	shelxl	shelxl	NOUN
eurjchem-2214	50	10	ntv	ntv	PROPN
eurjchem-2214	50	11	5.1	5.1	NUM
eurjchem-2214	50	12	and	and	CCONJ
eurjchem-2214	50	13	refined	refine	VERB
eurjchem-2214	50	14	by	by	ADP
eurjchem-2214	50	15	shelxl	shelxl	NOUN
eurjchem-2214	50	16	and	and	CCONJ
eurjchem-2214	50	17	olex-2	olex-2	NUM
eurjchem-2214	50	18	[	[	X
eurjchem-2214	50	19	32,33	32,33	NUM
eurjchem-2214	50	20	]	]	PUNCT
eurjchem-2214	50	21	.	.	PUNCT
eurjchem-2214	51	1	all	all	DET
eurjchem-2214	51	2	the	the	DET
eurjchem-2214	51	3	non	non	ADJ
eurjchem-2214	51	4	-	-	ADJ
eurjchem-2214	51	5	hydrogen	hydrogen	ADJ
eurjchem-2214	51	6	atoms	atom	NOUN
eurjchem-2214	51	7	were	be	AUX
eurjchem-2214	51	8	refined	refine	VERB
eurjchem-2214	51	9	anisotropically	anisotropically	ADV
eurjchem-2214	51	10	and	and	CCONJ
eurjchem-2214	51	11	all	all	DET
eurjchem-2214	51	12	the	the	DET
eurjchem-2214	51	13	hydrogen	hydrogen	NOUN
eurjchem-2214	51	14	atoms	atom	NOUN
eurjchem-2214	51	15	were	be	AUX
eurjchem-2214	51	16	fixed	fix	VERB
eurjchem-2214	51	17	geometrically	geometrically	ADV
eurjchem-2214	51	18	.	.	PUNCT
eurjchem-2214	52	1	molecular	molecular	ADJ
eurjchem-2214	52	2	plots	plot	NOUN
eurjchem-2214	52	3	were	be	AUX
eurjchem-2214	52	4	drawn	draw	VERB
eurjchem-2214	52	5	with	with	ADP
eurjchem-2214	52	6	the	the	DET
eurjchem-2214	52	7	help	help	NOUN
eurjchem-2214	52	8	of	of	ADP
eurjchem-2214	52	9	ortep	ortep	NOUN
eurjchem-2214	52	10	[	[	X
eurjchem-2214	52	11	34	34	NUM
eurjchem-2214	52	12	]	]	PUNCT
eurjchem-2214	52	13	and	and	CCONJ
eurjchem-2214	52	14	mercury	mercury	NOUN
eurjchem-2214	53	1	[	[	X
eurjchem-2214	53	2	35	35	NUM
eurjchem-2214	53	3	]	]	PUNCT
eurjchem-2214	53	4	.	.	PUNCT
eurjchem-2214	54	1	repeated	repeat	VERB
eurjchem-2214	54	2	crystallization	crystallization	NOUN
eurjchem-2214	54	3	of	of	ADP
eurjchem-2214	54	4	compound	compound	NOUN
eurjchem-2214	54	5	5	5	NUM
eurjchem-2214	54	6	resulted	result	VERB
eurjchem-2214	54	7	in	in	ADP
eurjchem-2214	54	8	crystals	crystal	NOUN
eurjchem-2214	54	9	with	with	ADP
eurjchem-2214	54	10	poor	poor	ADJ
eurjchem-2214	54	11	x	x	NOUN
eurjchem-2214	54	12	-	-	NOUN
eurjchem-2214	54	13	ray	ray	NOUN
eurjchem-2214	54	14	diffracting	diffract	VERB
eurjchem-2214	54	15	ability	ability	NOUN
eurjchem-2214	54	16	and	and	CCONJ
eurjchem-2214	54	17	hence	hence	ADV
eurjchem-2214	54	18	the	the	DET
eurjchem-2214	54	19	number	number	NOUN
eurjchem-2214	54	20	of	of	ADP
eurjchem-2214	54	21	observed	observed	ADJ
eurjchem-2214	54	22	reflections	reflection	NOUN
eurjchem-2214	54	23	were	be	AUX
eurjchem-2214	54	24	very	very	ADV
eurjchem-2214	54	25	low	low	ADJ
eurjchem-2214	54	26	which	which	PRON
eurjchem-2214	54	27	resulted	result	VERB
eurjchem-2214	54	28	in	in	ADP
eurjchem-2214	54	29	higher	high	ADJ
eurjchem-2214	54	30	‘	'	PUNCT
eurjchem-2214	54	31	r	r	NOUN
eurjchem-2214	54	32	’	'	PUNCT
eurjchem-2214	54	33	(	(	PUNCT
eurjchem-2214	54	34	number	number	NOUN
eurjchem-2214	54	35	of	of	ADP
eurjchem-2214	54	36	reflections	reflection	NOUN
eurjchem-2214	54	37	collected	collect	VERB
eurjchem-2214	54	38	:	:	PUNCT
eurjchem-2214	54	39	12503	12503	NUM
eurjchem-2214	54	40	;	;	PUNCT
eurjchem-2214	54	41	number	number	NOUN
eurjchem-2214	54	42	of	of	ADP
eurjchem-2214	54	43	observed	observed	ADJ
eurjchem-2214	54	44	reflections	reflection	NOUN
eurjchem-2214	54	45	(	(	PUNCT
eurjchem-2214	54	46	>	>	X
eurjchem-2214	54	47	2σ	2σ	NUM
eurjchem-2214	54	48	):	):	PUNCT
eurjchem-2214	54	49	3984	3984	NUM
eurjchem-2214	54	50	)	)	PUNCT
eurjchem-2214	54	51	.	.	PUNCT
eurjchem-2214	55	1	2.3	2.3	NUM
eurjchem-2214	55	2	.	.	PUNCT
eurjchem-2214	56	1	preparations	preparation	NOUN
eurjchem-2214	56	2	,	,	PUNCT
eurjchem-2214	56	3	elemental	elemental	ADJ
eurjchem-2214	56	4	,	,	PUNCT
eurjchem-2214	56	5	spectral	spectral	ADJ
eurjchem-2214	56	6	and	and	CCONJ
eurjchem-2214	56	7	cyclic	cyclic	ADJ
eurjchem-2214	56	8	voltammetric	voltammetric	ADJ
eurjchem-2214	56	9	data	datum	NOUN
eurjchem-2214	56	10	pyrrolidine	pyrrolidine	NOUN
eurjchem-2214	56	11	(	(	PUNCT
eurjchem-2214	56	12	1.70	1.70	NUM
eurjchem-2214	56	13	ml	ml	NOUN
eurjchem-2214	56	14	,	,	PUNCT
eurjchem-2214	56	15	20	20	NUM
eurjchem-2214	56	16	mmol	mmol	NOUN
eurjchem-2214	56	17	)	)	PUNCT
eurjchem-2214	56	18	,	,	PUNCT
eurjchem-2214	56	19	carbondisulfide	carbondisulfide	ADP
eurjchem-2214	56	20	(	(	PUNCT
eurjchem-2214	56	21	>	>	X
eurjchem-2214	56	22	1.25	1.25	NUM
eurjchem-2214	56	23	ml	ml	PROPN
eurjchem-2214	56	24	20	20	NUM
eurjchem-2214	56	25	mmol	mmol	NOUN
eurjchem-2214	56	26	)	)	PUNCT
eurjchem-2214	56	27	in	in	ADP
eurjchem-2214	56	28	ethanol	ethanol	NOUN
eurjchem-2214	56	29	(	(	PUNCT
eurjchem-2214	56	30	20ml	20ml	NOUN
eurjchem-2214	56	31	)	)	PUNCT
eurjchem-2214	56	32	under	under	ADP
eurjchem-2214	56	33	ammonical	ammonical	ADJ
eurjchem-2214	56	34	medium	medium	NOUN
eurjchem-2214	56	35	(	(	PUNCT
eurjchem-2214	56	36	1.0	1.0	NUM
eurjchem-2214	56	37	ml	ml	NOUN
eurjchem-2214	56	38	of	of	ADP
eurjchem-2214	56	39	aqueous	aqueous	ADJ
eurjchem-2214	56	40	ammonia	ammonia	NOUN
eurjchem-2214	56	41	)	)	PUNCT
eurjchem-2214	56	42	were	be	AUX
eurjchem-2214	56	43	mixed	mix	VERB
eurjchem-2214	56	44	under	under	ADP
eurjchem-2214	56	45	ice	ice	NOUN
eurjchem-2214	56	46	cold	cold	ADJ
eurjchem-2214	56	47	condition(5	condition(5	PROPN
eurjchem-2214	56	48	°	°	ADP
eurjchem-2214	56	49	c	c	NOUN
eurjchem-2214	56	50	)	)	PUNCT
eurjchem-2214	56	51	to	to	PART
eurjchem-2214	56	52	form	form	VERB
eurjchem-2214	56	53	yellow	yellow	ADJ
eurjchem-2214	56	54	ammoniumpyrrolidinecarbodithioate	ammoniumpyrrolidinecarbodithioate	NOUN
eurjchem-2214	56	55	.	.	PUNCT
eurjchem-2214	57	1	to	to	ADP
eurjchem-2214	57	2	the	the	DET
eurjchem-2214	57	3	ammonium	ammonium	NOUN
eurjchem-2214	57	4	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	NOUN
eurjchem-2214	57	5	,	,	PUNCT
eurjchem-2214	57	6	aqueous	aqueous	ADJ
eurjchem-2214	57	7	solution	solution	NOUN
eurjchem-2214	57	8	of	of	ADP
eurjchem-2214	57	9	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	57	10	(	(	PUNCT
eurjchem-2214	57	11	0.240	0.240	NUM
eurjchem-2214	57	12	g	g	NOUN
eurjchem-2214	57	13	,	,	PUNCT
eurjchem-2214	57	14	10	10	NUM
eurjchem-2214	57	15	mmol	mmol	NOUN
eurjchem-2214	57	16	)	)	PUNCT
eurjchem-2214	57	17	was	be	AUX
eurjchem-2214	57	18	added	add	VERB
eurjchem-2214	57	19	with	with	ADP
eurjchem-2214	57	20	continuous	continuous	ADJ
eurjchem-2214	57	21	stirring	stirring	NOUN
eurjchem-2214	57	22	.	.	PUNCT
eurjchem-2214	58	1	a	a	DET
eurjchem-2214	58	2	green	green	ADJ
eurjchem-2214	58	3	precipitate	precipitate	NOUN
eurjchem-2214	58	4	of	of	ADP
eurjchem-2214	58	5	[	[	X
eurjchem-2214	58	6	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	58	7	]	]	PUNCT
eurjchem-2214	58	8	was	be	AUX
eurjchem-2214	58	9	obtained	obtain	VERB
eurjchem-2214	58	10	,	,	PUNCT
eurjchem-2214	58	11	which	which	PRON
eurjchem-2214	58	12	was	be	AUX
eurjchem-2214	58	13	washed	wash	VERB
eurjchem-2214	58	14	with	with	ADP
eurjchem-2214	58	15	alcohol	alcohol	NOUN
eurjchem-2214	58	16	and	and	CCONJ
eurjchem-2214	58	17	was	be	AUX
eurjchem-2214	58	18	then	then	ADV
eurjchem-2214	58	19	dried	dry	VERB
eurjchem-2214	58	20	in	in	ADP
eurjchem-2214	58	21	air	air	NOUN
eurjchem-2214	58	22	.	.	PUNCT
eurjchem-2214	59	1	yield	yield	NOUN
eurjchem-2214	59	2	:	:	PUNCT
eurjchem-2214	59	3	80	80	NUM
eurjchem-2214	59	4	%	%	NOUN
eurjchem-2214	59	5	,	,	PUNCT
eurjchem-2214	59	6	dec	dec	PROPN
eurjchem-2214	59	7	.	.	PROPN
eurjchem-2214	59	8	temp	temp	PROPN
eurjchem-2214	59	9	.	.	PUNCT
eurjchem-2214	60	1	:	:	PUNCT
eurjchem-2214	60	2	210	210	NUM
eurjchem-2214	60	3	°	°	SYM
eurjchem-2214	60	4	c	c	VERB
eurjchem-2214	60	5	.	.	PUNCT
eurjchem-2214	61	1	all	all	DET
eurjchem-2214	61	2	the	the	DET
eurjchem-2214	61	3	mixed	mixed	ADJ
eurjchem-2214	61	4	ligand	ligand	NOUN
eurjchem-2214	61	5	complexes	complex	NOUN
eurjchem-2214	61	6	were	be	AUX
eurjchem-2214	61	7	prepared	prepare	VERB
eurjchem-2214	61	8	from	from	ADP
eurjchem-2214	61	9	the	the	DET
eurjchem-2214	61	10	parent	parent	NOUN
eurjchem-2214	61	11	[	[	X
eurjchem-2214	61	12	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	61	13	]	]	PUNCT
eurjchem-2214	61	14	with	with	ADP
eurjchem-2214	61	15	the	the	DET
eurjchem-2214	61	16	appropriate	appropriate	ADJ
eurjchem-2214	61	17	phosphine	phosphine	NOUN
eurjchem-2214	61	18	,	,	PUNCT
eurjchem-2214	61	19	cyanide	cyanide	NOUN
eurjchem-2214	61	20	,	,	PUNCT
eurjchem-2214	61	21	and	and	CCONJ
eurjchem-2214	61	22	thiocyanate	thiocyanate	NOUN
eurjchem-2214	61	23	anions	anion	NOUN
eurjchem-2214	61	24	.	.	PUNCT
eurjchem-2214	62	1	a	a	DET
eurjchem-2214	62	2	mixture	mixture	NOUN
eurjchem-2214	62	3	of	of	ADP
eurjchem-2214	62	4	[	[	X
eurjchem-2214	62	5	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	62	6	]	]	X
eurjchem-2214	62	7	(	(	PUNCT
eurjchem-2214	62	8	0.089	0.089	NUM
eurjchem-2214	62	9	g	g	NOUN
eurjchem-2214	62	10	,	,	PUNCT
eurjchem-2214	62	11	0.25	0.25	NUM
eurjchem-2214	62	12	mmol	mmol	NOUN
eurjchem-2214	62	13	)	)	PUNCT
eurjchem-2214	62	14	,	,	PUNCT
eurjchem-2214	62	15	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2214	62	16	(	(	PUNCT
eurjchem-2214	62	17	0.131	0.131	NUM
eurjchem-2214	62	18	g	g	NOUN
eurjchem-2214	62	19	,	,	PUNCT
eurjchem-2214	62	20	0.5	0.5	NUM
eurjchem-2214	62	21	mmol	mmol	NOUN
eurjchem-2214	62	22	)	)	PUNCT
eurjchem-2214	62	23	,	,	PUNCT
eurjchem-2214	62	24	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	62	25	(	(	PUNCT
eurjchem-2214	62	26	0.059	0.059	NUM
eurjchem-2214	62	27	g	g	NOUN
eurjchem-2214	62	28	,	,	PUNCT
eurjchem-2214	62	29	0.25	0.25	NUM
eurjchem-2214	62	30	mmol	mmol	NOUN
eurjchem-2214	62	31	)	)	PUNCT
eurjchem-2214	62	32	,	,	PUNCT
eurjchem-2214	62	33	and	and	CCONJ
eurjchem-2214	62	34	ammonium	ammonium	NOUN
eurjchem-2214	62	35	thiocyanate	thiocyanate	NOUN
eurjchem-2214	62	36	(	(	PUNCT
eurjchem-2214	62	37	0.038	0.038	NUM
eurjchem-2214	62	38	g	g	NOUN
eurjchem-2214	62	39	,	,	PUNCT
eurjchem-2214	62	40	0.5	0.5	NUM
eurjchem-2214	62	41	mmol	mmol	NOUN
eurjchem-2214	62	42	)	)	PUNCT
eurjchem-2214	62	43	in	in	ADP
eurjchem-2214	62	44	acetonitrile	acetonitrile	NOUN
eurjchem-2214	62	45	and	and	CCONJ
eurjchem-2214	62	46	methanol	methanol	NOUN
eurjchem-2214	62	47	(	(	PUNCT
eurjchem-2214	62	48	2:1	2:1	NUM
eurjchem-2214	62	49	,	,	PUNCT
eurjchem-2214	62	50	50	50	NUM
eurjchem-2214	62	51	ml	ml	NOUN
eurjchem-2214	62	52	)	)	PUNCT
eurjchem-2214	62	53	was	be	AUX
eurjchem-2214	62	54	refluxed	refluxe	VERB
eurjchem-2214	62	55	for	for	ADP
eurjchem-2214	62	56	two	two	NUM
eurjchem-2214	62	57	hours	hour	NOUN
eurjchem-2214	62	58	followed	follow	VERB
eurjchem-2214	62	59	by	by	ADP
eurjchem-2214	62	60	concentration	concentration	NOUN
eurjchem-2214	62	61	to	to	PART
eurjchem-2214	62	62	ca.25	ca.25	VERB
eurjchem-2214	62	63	cm3	cm3	NOUN
eurjchem-2214	62	64	and	and	CCONJ
eurjchem-2214	62	65	then	then	ADV
eurjchem-2214	62	66	the	the	DET
eurjchem-2214	62	67	solution	solution	NOUN
eurjchem-2214	62	68	was	be	AUX
eurjchem-2214	62	69	filtered	filter	VERB
eurjchem-2214	62	70	and	and	CCONJ
eurjchem-2214	62	71	kept	keep	VERB
eurjchem-2214	62	72	for	for	ADP
eurjchem-2214	62	73	evaporation	evaporation	NOUN
eurjchem-2214	62	74	.	.	PUNCT
eurjchem-2214	63	1	after	after	ADP
eurjchem-2214	63	2	two	two	NUM
eurjchem-2214	63	3	days	day	NOUN
eurjchem-2214	63	4	,	,	PUNCT
eurjchem-2214	63	5	single	single	ADJ
eurjchem-2214	63	6	crystals	crystal	NOUN
eurjchem-2214	63	7	of	of	ADP
eurjchem-2214	63	8	compound	compound	NOUN
eurjchem-2214	63	9	suitable	suitable	ADJ
eurjchem-2214	63	10	for	for	ADP
eurjchem-2214	63	11	analysis	analysis	NOUN
eurjchem-2214	63	12	were	be	AUX
eurjchem-2214	63	13	obtained	obtain	VERB
eurjchem-2214	63	14	.	.	PUNCT
eurjchem-2214	64	1	the	the	DET
eurjchem-2214	64	2	preparative	preparative	ADJ
eurjchem-2214	64	3	procedures	procedure	NOUN
eurjchem-2214	64	4	for	for	ADP
eurjchem-2214	64	5	compounds	compound	NOUN
eurjchem-2214	64	6	2	2	NUM
eurjchem-2214	64	7	-	-	SYM
eurjchem-2214	64	8	5	5	NUM
eurjchem-2214	64	9	were	be	AUX
eurjchem-2214	64	10	identical	identical	ADJ
eurjchem-2214	64	11	to	to	ADP
eurjchem-2214	64	12	the	the	DET
eurjchem-2214	64	13	procedure	procedure	NOUN
eurjchem-2214	64	14	followed	follow	VERB
eurjchem-2214	64	15	for	for	ADP
eurjchem-2214	64	16	compound	compound	NOUN
eurjchem-2214	64	17	1	1	NUM
eurjchem-2214	64	18	.	.	PUNCT
eurjchem-2214	64	19	reactants	reactant	NOUN
eurjchem-2214	64	20	for	for	ADP
eurjchem-2214	64	21	[	[	X
eurjchem-2214	64	22	ni(pyrdtc)(4	ni(pyrdtc)(4	NOUN
eurjchem-2214	64	23	-	-	PUNCT
eurjchem-2214	64	24	mp)(ncs	mp)(nc	NOUN
eurjchem-2214	64	25	)	)	PUNCT
eurjchem-2214	64	26	]	]	PUNCT
eurjchem-2214	65	1	(	(	PUNCT
eurjchem-2214	65	2	2	2	NUM
eurjchem-2214	65	3	):	):	PUNCT
eurjchem-2214	65	4	[	[	X
eurjchem-2214	65	5	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	65	6	]	]	X
eurjchem-2214	65	7	(	(	PUNCT
eurjchem-2214	65	8	0.089	0.089	NUM
eurjchem-2214	65	9	g	g	NOUN
eurjchem-2214	65	10	,	,	PUNCT
eurjchem-2214	65	11	0.25	0.25	NUM
eurjchem-2214	65	12	mmol	mmol	NOUN
eurjchem-2214	65	13	)	)	PUNCT
eurjchem-2214	65	14	,	,	PUNCT
eurjchem-2214	65	15	tri(4	tri(4	NOUN
eurjchem-2214	65	16	-	-	PUNCT
eurjchem-2214	65	17	methylphenyl)phosphine	methylphenyl)phosphine	PROPN
eurjchem-2214	65	18	(	(	PUNCT
eurjchem-2214	65	19	0.153	0.153	NUM
eurjchem-2214	65	20	g	g	NOUN
eurjchem-2214	65	21	,	,	PUNCT
eurjchem-2214	65	22	0.5	0.5	NUM
eurjchem-2214	65	23	mmol	mmol	NOUN
eurjchem-2214	65	24	)	)	PUNCT
eurjchem-2214	65	25	,	,	PUNCT
eurjchem-2214	65	26	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	65	27	(	(	PUNCT
eurjchem-2214	65	28	0.059	0.059	NUM
eurjchem-2214	65	29	g	g	NOUN
eurjchem-2214	65	30	,	,	PUNCT
eurjchem-2214	65	31	0.25	0.25	NUM
eurjchem-2214	65	32	mmol	mmol	NOUN
eurjchem-2214	65	33	)	)	PUNCT
eurjchem-2214	65	34	and	and	CCONJ
eurjchem-2214	65	35	ammonium	ammonium	NOUN
eurjchem-2214	65	36	thiocyanate	thiocyanate	NOUN
eurjchem-2214	65	37	(	(	PUNCT
eurjchem-2214	65	38	0.038	0.038	NUM
eurjchem-2214	65	39	g	g	NOUN
eurjchem-2214	65	40	,	,	PUNCT
eurjchem-2214	65	41	0.5	0.5	NUM
eurjchem-2214	65	42	mmol	mmol	NOUN
eurjchem-2214	65	43	)	)	PUNCT
eurjchem-2214	65	44	.	.	PUNCT
eurjchem-2214	66	1	reactants	reactant	NOUN
eurjchem-2214	66	2	for	for	ADP
eurjchem-2214	66	3	[	[	X
eurjchem-2214	66	4	ni(pyrdtc	ni(pyrdtc	NOUN
eurjchem-2214	66	5	)	)	PUNCT
eurjchem-2214	66	6	(	(	PUNCT
eurjchem-2214	66	7	pph3)(cn)].h2o	pph3)(cn)].h2o	NOUN
eurjchem-2214	66	8	(	(	PUNCT
eurjchem-2214	66	9	3	3	NUM
eurjchem-2214	66	10	):	):	PUNCT
eurjchem-2214	66	11	[	[	X
eurjchem-2214	66	12	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	66	13	]	]	X
eurjchem-2214	66	14	(	(	PUNCT
eurjchem-2214	66	15	0.089	0.089	NUM
eurjchem-2214	66	16	g	g	NOUN
eurjchem-2214	66	17	,	,	PUNCT
eurjchem-2214	66	18	0.25	0.25	NUM
eurjchem-2214	66	19	mmol	mmol	NOUN
eurjchem-2214	66	20	)	)	PUNCT
eurjchem-2214	66	21	,	,	PUNCT
eurjchem-2214	66	22	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2214	66	23	(	(	PUNCT
eurjchem-2214	66	24	0.131	0.131	NUM
eurjchem-2214	66	25	g	g	NOUN
eurjchem-2214	66	26	,	,	PUNCT
eurjchem-2214	66	27	0.5	0.5	NUM
eurjchem-2214	66	28	mmol	mmol	NOUN
eurjchem-2214	66	29	)	)	PUNCT
eurjchem-2214	66	30	,	,	PUNCT
eurjchem-2214	66	31	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	66	32	(	(	PUNCT
eurjchem-2214	66	33	0.059	0.059	NUM
eurjchem-2214	66	34	g	g	NOUN
eurjchem-2214	66	35	,	,	PUNCT
eurjchem-2214	66	36	0.25	0.25	NUM
eurjchem-2214	66	37	mmol	mmol	NOUN
eurjchem-2214	66	38	)	)	PUNCT
eurjchem-2214	66	39	and	and	CCONJ
eurjchem-2214	66	40	potassium	potassium	NOUN
eurjchem-2214	66	41	cyanide	cyanide	NOUN
eurjchem-2214	66	42	(	(	PUNCT
eurjchem-2214	66	43	0.033	0.033	NUM
eurjchem-2214	66	44	g	g	NOUN
eurjchem-2214	66	45	,	,	PUNCT
eurjchem-2214	66	46	0.5	0.5	NUM
eurjchem-2214	66	47	mmol	mmol	NOUN
eurjchem-2214	66	48	)	)	PUNCT
eurjchem-2214	66	49	.	.	PUNCT
eurjchem-2214	67	1	reactants	reactant	NOUN
eurjchem-2214	67	2	for	for	ADP
eurjchem-2214	67	3	[	[	X
eurjchem-2214	67	4	ni(pyrdtc)(pph3)2	ni(pyrdtc)(pph3)2	ADJ
eurjchem-2214	67	5	]	]	X
eurjchem-2214	67	6	clo4	clo4	PROPN
eurjchem-2214	67	7	(	(	PUNCT
eurjchem-2214	67	8	4	4	NUM
eurjchem-2214	67	9	):	):	PUNCT
eurjchem-2214	67	10	[	[	X
eurjchem-2214	67	11	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	67	12	]	]	X
eurjchem-2214	67	13	(	(	PUNCT
eurjchem-2214	67	14	0.089	0.089	NUM
eurjchem-2214	67	15	g	g	NOUN
eurjchem-2214	67	16	,	,	PUNCT
eurjchem-2214	67	17	0.25	0.25	NUM
eurjchem-2214	67	18	mmol	mmol	NOUN
eurjchem-2214	67	19	)	)	PUNCT
eurjchem-2214	67	20	,	,	PUNCT
eurjchem-2214	67	21	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2214	67	22	(	(	PUNCT
eurjchem-2214	67	23	0.262	0.262	NUM
eurjchem-2214	67	24	g	g	NOUN
eurjchem-2214	67	25	,	,	PUNCT
eurjchem-2214	67	26	1.0	1.0	NUM
eurjchem-2214	67	27	mmol	mmol	NOUN
eurjchem-2214	67	28	)	)	PUNCT
eurjchem-2214	67	29	,	,	PUNCT
eurjchem-2214	67	30	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	67	31	(	(	PUNCT
eurjchem-2214	67	32	0.059	0.059	NUM
eurjchem-2214	67	33	g	g	NOUN
eurjchem-2214	67	34	,	,	PUNCT
eurjchem-2214	67	35	0.25	0.25	NUM
eurjchem-2214	67	36	mmol	mmol	NOUN
eurjchem-2214	67	37	)	)	PUNCT
eurjchem-2214	67	38	and	and	CCONJ
eurjchem-2214	67	39	nh4clo4	nh4clo4	PROPN
eurjchem-2214	67	40	(	(	PUNCT
eurjchem-2214	67	41	0.059	0.059	NUM
eurjchem-2214	67	42	g	g	NOUN
eurjchem-2214	67	43	,	,	PUNCT
eurjchem-2214	67	44	0.5	0.5	NUM
eurjchem-2214	67	45	mmol	mmol	NOUN
eurjchem-2214	67	46	)	)	PUNCT
eurjchem-2214	67	47	.	.	PUNCT
eurjchem-2214	68	1	reactants	reactant	VERB
eurjchem-2214	68	2	for	for	ADP
eurjchem-2214	68	3	[	[	X
eurjchem-2214	68	4	ni(pyrdtc)(dppe)]bph4·2h2o	ni(pyrdtc)(dppe)]bph4·2h2o	NOUN
eurjchem-2214	68	5	(	(	PUNCT
eurjchem-2214	68	6	5	5	NUM
eurjchem-2214	68	7	):	):	PUNCT
eurjchem-2214	68	8	[	[	X
eurjchem-2214	68	9	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	68	10	]	]	X
eurjchem-2214	68	11	(	(	PUNCT
eurjchem-2214	68	12	0.089	0.089	NUM
eurjchem-2214	68	13	g	g	NOUN
eurjchem-2214	68	14	,	,	PUNCT
eurjchem-2214	68	15	0.25	0.25	NUM
eurjchem-2214	68	16	mmol	mmol	NOUN
eurjchem-2214	68	17	)	)	PUNCT
eurjchem-2214	68	18	,	,	PUNCT
eurjchem-2214	68	19	1,2	1,2	NUM
eurjchem-2214	68	20	-	-	SYM
eurjchem-2214	68	21	bis(diphenylphosphino)ethane	bis(diphenylphosphino)ethane	NUM
eurjchem-2214	68	22	(	(	PUNCT
eurjchem-2214	68	23	0.199	0.199	NUM
eurjchem-2214	68	24	g	g	NOUN
eurjchem-2214	68	25	,	,	PUNCT
eurjchem-2214	68	26	0.5	0.5	NUM
eurjchem-2214	68	27	mmol	mmol	NOUN
eurjchem-2214	68	28	)	)	PUNCT
eurjchem-2214	68	29	,	,	PUNCT
eurjchem-2214	68	30	nicl2·6h2o	nicl2·6h2o	NOUN
eurjchem-2214	68	31	(	(	PUNCT
eurjchem-2214	68	32	0.059	0.059	NUM
eurjchem-2214	68	33	g	g	NOUN
eurjchem-2214	68	34	,	,	PUNCT
eurjchem-2214	68	35	0.25	0.25	NUM
eurjchem-2214	68	36	mmol	mmol	NOUN
eurjchem-2214	68	37	)	)	PUNCT
eurjchem-2214	68	38	and	and	CCONJ
eurjchem-2214	68	39	nabph4	nabph4	PROPN
eurjchem-2214	68	40	(	(	PUNCT
eurjchem-2214	68	41	0.086	0.086	NUM
eurjchem-2214	68	42	g	g	NOUN
eurjchem-2214	68	43	,	,	PUNCT
eurjchem-2214	68	44	0.15	0.15	NUM
eurjchem-2214	68	45	mmol	mmol	NOUN
eurjchem-2214	68	46	)	)	PUNCT
eurjchem-2214	68	47	.	.	PUNCT
eurjchem-2214	69	1	the	the	DET
eurjchem-2214	69	2	general	general	ADJ
eurjchem-2214	69	3	reaction	reaction	NOUN
eurjchem-2214	69	4	sequence	sequence	NOUN
eurjchem-2214	69	5	is	be	AUX
eurjchem-2214	69	6	given	give	VERB
eurjchem-2214	69	7	in	in	ADP
eurjchem-2214	69	8	scheme	scheme	NOUN
eurjchem-2214	69	9	1	1	NUM
eurjchem-2214	69	10	.	.	PUNCT
eurjchem-2214	70	1	pyrrolidinecarbodithioato(isothiocyanato)(triphenylphosph	pyrrolidinecarbodithioato(isothiocyanato)(triphenylphosph	PROPN
eurjchem-2214	70	2	ine)nickel(ii	ine)nickel(ii	PROPN
eurjchem-2214	70	3	)	)	PUNCT
eurjchem-2214	70	4	(	(	PUNCT
eurjchem-2214	70	5	1	1	NUM
eurjchem-2214	70	6	):	):	PUNCT
eurjchem-2214	70	7	color	color	NOUN
eurjchem-2214	70	8	:	:	PUNCT
eurjchem-2214	70	9	purple	purple	ADJ
eurjchem-2214	70	10	.	.	PUNCT
eurjchem-2214	71	1	yield	yield	NOUN
eurjchem-2214	71	2	:	:	PUNCT
eurjchem-2214	71	3	70	70	NUM
eurjchem-2214	71	4	%	%	NOUN
eurjchem-2214	71	5	.	.	PUNCT
eurjchem-2214	72	1	dec	dec	PROPN
eurjchem-2214	72	2	.	.	PROPN
eurjchem-2214	72	3	temp	temp	PROPN
eurjchem-2214	72	4	.	.	PUNCT
eurjchem-2214	73	1	:	:	PUNCT
eurjchem-2214	73	2	185	185	NUM
eurjchem-2214	73	3	°	°	SYM
eurjchem-2214	73	4	c	c	NOUN
eurjchem-2214	73	5	.	.	PUNCT
eurjchem-2214	74	1	ft	ft	PROPN
eurjchem-2214	74	2	-	-	PUNCT
eurjchem-2214	74	3	ir	ir	PROPN
eurjchem-2214	74	4	(	(	PUNCT
eurjchem-2214	74	5	kbr	kbr	PROPN
eurjchem-2214	74	6	,	,	PUNCT
eurjchem-2214	74	7	ν	ν	PROPN
eurjchem-2214	74	8	,	,	PUNCT
eurjchem-2214	74	9	cm-1	cm-1	NUM
eurjchem-2214	74	10	):	):	PUNCT
eurjchem-2214	74	11	1533	1533	NUM
eurjchem-2214	74	12	(	(	PUNCT
eurjchem-2214	74	13	νc	νc	NOUN
eurjchem-2214	74	14	-	-	PUNCT
eurjchem-2214	74	15	n(thioureide	n(thioureide	NOUN
eurjchem-2214	74	16	)	)	PUNCT
eurjchem-2214	74	17	)	)	PUNCT
eurjchem-2214	74	18	,	,	PUNCT
eurjchem-2214	74	19	2094	2094	NUM
eurjchem-2214	74	20	(	(	PUNCT
eurjchem-2214	74	21	nc(s)-	nc(s)-	NOUN
eurjchem-2214	74	22	)	)	PUNCT
eurjchem-2214	74	23	.	.	PUNCT
eurjchem-2214	75	1	1h	1h	NUM
eurjchem-2214	75	2	nmr	nmr	NOUN
eurjchem-2214	75	3	(	(	PUNCT
eurjchem-2214	75	4	400	400	NUM
eurjchem-2214	75	5	mhz	mhz	NOUN
eurjchem-2214	75	6	,	,	PUNCT
eurjchem-2214	75	7	cdcl3	cdcl3	PROPN
eurjchem-2214	75	8	,	,	PUNCT
eurjchem-2214	75	9	δ	δ	PROPN
eurjchem-2214	75	10	,	,	PUNCT
eurjchem-2214	75	11	ppm	ppm	NOUN
eurjchem-2214	75	12	):	):	PUNCT
eurjchem-2214	75	13	3.48	3.48	NUM
eurjchem-2214	75	14	-	-	SYM
eurjchem-2214	75	15	3.52	3.52	NUM
eurjchem-2214	75	16	(	(	PUNCT
eurjchem-2214	75	17	t	t	PROPN
eurjchem-2214	75	18	,	,	PUNCT
eurjchem-2214	75	19	4h	4h	NUM
eurjchem-2214	75	20	,	,	PUNCT
eurjchem-2214	75	21	nch2ch2	nch2ch2	PROPN
eurjchem-2214	75	22	,	,	PUNCT
eurjchem-2214	75	23	3j	3j	NOUN
eurjchem-2214	75	24	=	=	NUM
eurjchem-2214	75	25	6.7	6.7	NUM
eurjchem-2214	75	26	hz	hz	NOUN
eurjchem-2214	75	27	)	)	PUNCT
eurjchem-2214	75	28	,	,	PUNCT
eurjchem-2214	75	29	1.82	1.82	NUM
eurjchem-2214	75	30	-	-	SYM
eurjchem-2214	75	31	1.95	1.95	NUM
eurjchem-2214	75	32	(	(	PUNCT
eurjchem-2214	75	33	m	m	PROPN
eurjchem-2214	75	34	,	,	PUNCT
eurjchem-2214	75	35	4h	4h	NOUN
eurjchem-2214	75	36	,	,	PUNCT
eurjchem-2214	75	37	nch2ch2	nch2ch2	PROPN
eurjchem-2214	75	38	)	)	PUNCT
eurjchem-2214	75	39	,	,	PUNCT
eurjchem-2214	75	40	7.30	7.30	NUM
eurjchem-2214	75	41	-	-	SYM
eurjchem-2214	75	42	7.61	7.61	NUM
eurjchem-2214	75	43	(	(	PUNCT
eurjchem-2214	75	44	m	m	PROPN
eurjchem-2214	75	45	,	,	PUNCT
eurjchem-2214	75	46	15h	15h	NUM
eurjchem-2214	75	47	,	,	PUNCT
eurjchem-2214	75	48	pph3	pph3	NOUN
eurjchem-2214	75	49	)	)	PUNCT
eurjchem-2214	75	50	.	.	PUNCT
eurjchem-2214	76	1	13c	13c	NOUN
eurjchem-2214	76	2	nmr	nmr	NOUN
eurjchem-2214	76	3	(	(	PUNCT
eurjchem-2214	76	4	100	100	NUM
eurjchem-2214	76	5	mhz	mhz	NOUN
eurjchem-2214	76	6	,	,	PUNCT
eurjchem-2214	76	7	cdcl3	cdcl3	PROPN
eurjchem-2214	76	8	,	,	PUNCT
eurjchem-2214	76	9	δ	δ	PROPN
eurjchem-2214	76	10	,	,	PUNCT
eurjchem-2214	76	11	ppm	ppm	NUM
eurjchem-2214	76	12	):	):	PUNCT
eurjchem-2214	76	13	198.9	198.9	NUM
eurjchem-2214	76	14	(	(	PUNCT
eurjchem-2214	76	15	ncs2	ncs2	PROPN
eurjchem-2214	76	16	,	,	PUNCT
eurjchem-2214	76	17	thioureide	thioureide	ADV
eurjchem-2214	76	18	)	)	PUNCT
eurjchem-2214	76	19	,	,	PUNCT
eurjchem-2214	76	20	49.1	49.1	NUM
eurjchem-2214	76	21	(	(	PUNCT
eurjchem-2214	76	22	nch2	nch2	PROPN
eurjchem-2214	76	23	)	)	PUNCT
eurjchem-2214	76	24	,	,	PUNCT
eurjchem-2214	76	25	24.2	24.2	NUM
eurjchem-2214	76	26	(	(	PUNCT
eurjchem-2214	76	27	ch2	ch2	PROPN
eurjchem-2214	76	28	)	)	PUNCT
eurjchem-2214	76	29	.	.	PUNCT
eurjchem-2214	77	1	31p	31p	NUM
eurjchem-2214	77	2	nmr	nmr	NOUN
eurjchem-2214	77	3	(	(	PUNCT
eurjchem-2214	77	4	162	162	NUM
eurjchem-2214	77	5	mhz	mhz	NOUN
eurjchem-2214	77	6	,	,	PUNCT
eurjchem-2214	77	7	cdcl3	cdcl3	PROPN
eurjchem-2214	77	8	,	,	PUNCT
eurjchem-2214	77	9	δ	δ	PROPN
eurjchem-2214	77	10	,	,	PUNCT
eurjchem-2214	77	11	ppm	ppm	NUM
eurjchem-2214	77	12	):	):	PUNCT
eurjchem-2214	77	13	19.9	19.9	NUM
eurjchem-2214	77	14	(	(	PUNCT
eurjchem-2214	77	15	p	p	NOUN
eurjchem-2214	77	16	,	,	PUNCT
eurjchem-2214	77	17	pph3	pph3	NOUN
eurjchem-2214	77	18	)	)	PUNCT
eurjchem-2214	77	19	.	.	PUNCT
eurjchem-2214	78	1	anal	anal	PROPN
eurjchem-2214	78	2	.	.	PUNCT
eurjchem-2214	78	3	calcd	calcd	NOUN
eurjchem-2214	78	4	.	.	PUNCT
eurjchem-2214	79	1	for	for	ADP
eurjchem-2214	79	2	c24h23n2nips3	c24h23n2nips3	NOUN
eurjchem-2214	79	3	:	:	PUNCT
eurjchem-2214	79	4	c	c	X
eurjchem-2214	79	5	,	,	PUNCT
eurjchem-2214	79	6	54.83	54.83	NUM
eurjchem-2214	79	7	;	;	PUNCT
eurjchem-2214	79	8	h	h	NOUN
eurjchem-2214	79	9	;	;	PUNCT
eurjchem-2214	79	10	4.39	4.39	NUM
eurjchem-2214	79	11	;	;	PUNCT
eurjchem-2214	79	12	n	n	CCONJ
eurjchem-2214	79	13	,	,	PUNCT
eurjchem-2214	79	14	5.29	5.29	NUM
eurjchem-2214	79	15	.	.	PUNCT
eurjchem-2214	79	16	found	find	VERB
eurjchem-2214	79	17	:	:	PUNCT
eurjchem-2214	80	1	c	c	X
eurjchem-2214	80	2	,	,	PUNCT
eurjchem-2214	80	3	54.87	54.87	NUM
eurjchem-2214	80	4	;	;	PUNCT
eurjchem-2214	80	5	h	h	X
eurjchem-2214	80	6	,	,	PUNCT
eurjchem-2214	80	7	4.42	4.42	NUM
eurjchem-2214	80	8	;	;	PUNCT
eurjchem-2214	80	9	n	n	CCONJ
eurjchem-2214	80	10	,	,	PUNCT
eurjchem-2214	80	11	5.33	5.33	NUM
eurjchem-2214	80	12	%	%	NOUN
eurjchem-2214	80	13	.	.	PUNCT
eurjchem-2214	81	1	uv	uv	NOUN
eurjchem-2214	81	2	/	/	SYM
eurjchem-2214	81	3	vis	vis	X
eurjchem-2214	81	4	(	(	PUNCT
eurjchem-2214	81	5	ch2cl2	ch2cl2	NOUN
eurjchem-2214	81	6	,	,	PUNCT
eurjchem-2214	81	7	λmax	λmax	NOUN
eurjchem-2214	81	8	,	,	PUNCT
eurjchem-2214	81	9	nm	nm	NOUN
eurjchem-2214	81	10	,	,	PUNCT
eurjchem-2214	81	11	(	(	PUNCT
eurjchem-2214	81	12	od	od	NOUN
eurjchem-2214	81	13	)	)	PUNCT
eurjchem-2214	81	14	):	):	PUNCT
eurjchem-2214	81	15	480	480	NUM
eurjchem-2214	81	16	(	(	PUNCT
eurjchem-2214	81	17	4.45	4.45	NUM
eurjchem-2214	81	18	)	)	PUNCT
eurjchem-2214	81	19	.	.	PUNCT
eurjchem-2214	82	1	cv	cv	PROPN
eurjchem-2214	82	2	(	(	PUNCT
eurjchem-2214	82	3	mv	mv	PROPN
eurjchem-2214	82	4	):	):	PUNCT
eurjchem-2214	82	5	-1006	-1006	PROPN
eurjchem-2214	82	6	.	.	PUNCT
eurjchem-2214	82	7	pyrrolidinecarbodithioato(isothiocyanato	pyrrolidinecarbodithioato(isothiocyanato	PROPN
eurjchem-2214	82	8	)	)	PUNCT
eurjchem-2214	82	9	(	(	PUNCT
eurjchem-2214	82	10	tri(4	tri(4	NOUN
eurjchem-2214	82	11	-	-	PUNCT
eurjchem-2214	82	12	methylphen	methylphen	NOUN
eurjchem-2214	82	13	yl)phosphine)nickel(ii	yl)phosphine)nickel(ii	NUM
eurjchem-2214	82	14	)	)	PUNCT
eurjchem-2214	82	15	(	(	PUNCT
eurjchem-2214	82	16	2	2	NUM
eurjchem-2214	82	17	):	):	PUNCT
eurjchem-2214	82	18	color	color	NOUN
eurjchem-2214	82	19	:	:	PUNCT
eurjchem-2214	82	20	purple	purple	ADJ
eurjchem-2214	82	21	.	.	PUNCT
eurjchem-2214	83	1	yield	yield	NOUN
eurjchem-2214	83	2	:	:	PUNCT
eurjchem-2214	83	3	73	73	NUM
eurjchem-2214	83	4	%	%	NOUN
eurjchem-2214	83	5	.	.	PUNCT
eurjchem-2214	84	1	dec	dec	PROPN
eurjchem-2214	84	2	.	.	PROPN
eurjchem-2214	84	3	temp	temp	PROPN
eurjchem-2214	84	4	.	.	PUNCT
eurjchem-2214	85	1	:	:	PUNCT
eurjchem-2214	85	2	187	187	NUM
eurjchem-2214	85	3	°	°	SYM
eurjchem-2214	85	4	c	c	NOUN
eurjchem-2214	85	5	.	.	PUNCT
eurjchem-2214	86	1	ft	ft	PROPN
eurjchem-2214	86	2	-	-	PUNCT
eurjchem-2214	86	3	ir	ir	PROPN
eurjchem-2214	86	4	(	(	PUNCT
eurjchem-2214	86	5	kbr	kbr	PROPN
eurjchem-2214	86	6	,	,	PUNCT
eurjchem-2214	86	7	ν	ν	PROPN
eurjchem-2214	86	8	,	,	PUNCT
eurjchem-2214	86	9	cm-1	cm-1	NUM
eurjchem-2214	86	10	):	):	PUNCT
eurjchem-2214	86	11	1531	1531	NUM
eurjchem-2214	86	12	(	(	PUNCT
eurjchem-2214	86	13	νc	νc	NOUN
eurjchem-2214	86	14	-	-	PUNCT
eurjchem-2214	86	15	n(thioureide	n(thioureide	NOUN
eurjchem-2214	86	16	)	)	PUNCT
eurjchem-2214	86	17	)	)	PUNCT
eurjchem-2214	86	18	,	,	PUNCT
eurjchem-2214	86	19	2099	2099	NUM
eurjchem-2214	86	20	(	(	PUNCT
eurjchem-2214	86	21	nc(s)-	nc(s)-	NOUN
eurjchem-2214	86	22	)	)	PUNCT
eurjchem-2214	86	23	.	.	PUNCT
eurjchem-2214	87	1	1h	1h	NUM
eurjchem-2214	87	2	nmr	nmr	NOUN
eurjchem-2214	87	3	(	(	PUNCT
eurjchem-2214	87	4	400	400	NUM
eurjchem-2214	87	5	mhz	mhz	NOUN
eurjchem-2214	87	6	,	,	PUNCT
eurjchem-2214	87	7	cdcl3	cdcl3	PROPN
eurjchem-2214	87	8	,	,	PUNCT
eurjchem-2214	87	9	δ	δ	PROPN
eurjchem-2214	87	10	,	,	PUNCT
eurjchem-2214	87	11	ppm	ppm	NOUN
eurjchem-2214	87	12	):	):	PUNCT
eurjchem-2214	87	13	3.55	3.55	NUM
eurjchem-2214	87	14	-	-	SYM
eurjchem-2214	87	15	3.60	3.60	NUM
eurjchem-2214	87	16	(	(	PUNCT
eurjchem-2214	87	17	t	t	PROPN
eurjchem-2214	87	18	,	,	PUNCT
eurjchem-2214	87	19	4h	4h	NUM
eurjchem-2214	87	20	,	,	PUNCT
eurjchem-2214	87	21	nch2ch2	nch2ch2	PROPN
eurjchem-2214	87	22	,	,	PUNCT
eurjchem-2214	87	23	3j	3j	NOUN
eurjchem-2214	87	24	=	=	SYM
eurjchem-2214	87	25	6.5	6.5	NUM
eurjchem-2214	87	26	hz	hz	NOUN
eurjchem-2214	87	27	)	)	PUNCT
eurjchem-2214	87	28	,	,	PUNCT
eurjchem-2214	87	29	1.85	1.85	NUM
eurjchem-2214	87	30	-	-	SYM
eurjchem-2214	87	31	1.95	1.95	NUM
eurjchem-2214	87	32	(	(	PUNCT
eurjchem-2214	87	33	m	m	PROPN
eurjchem-2214	87	34	,	,	PUNCT
eurjchem-2214	87	35	4h	4h	NOUN
eurjchem-2214	87	36	,	,	PUNCT
eurjchem-2214	87	37	nch2ch2	nch2ch2	PROPN
eurjchem-2214	87	38	)	)	PUNCT
eurjchem-2214	87	39	,	,	PUNCT
eurjchem-2214	87	40	7.30	7.30	NUM
eurjchem-2214	87	41	-	-	SYM
eurjchem-2214	87	42	7.61	7.61	NUM
eurjchem-2214	87	43	(	(	PUNCT
eurjchem-2214	87	44	m	m	PROPN
eurjchem-2214	87	45	,	,	PUNCT
eurjchem-2214	87	46	15h	15h	NUM
eurjchem-2214	87	47	,	,	PUNCT
eurjchem-2214	87	48	pph3	pph3	NOUN
eurjchem-2214	87	49	)	)	PUNCT
eurjchem-2214	87	50	.	.	PUNCT
eurjchem-2214	88	1	13c	13c	NOUN
eurjchem-2214	88	2	nmr	nmr	NOUN
eurjchem-2214	88	3	(	(	PUNCT
eurjchem-2214	88	4	100	100	NUM
eurjchem-2214	88	5	mhz	mhz	NOUN
eurjchem-2214	88	6	,	,	PUNCT
eurjchem-2214	88	7	cdcl3	cdcl3	PROPN
eurjchem-2214	88	8	,	,	PUNCT
eurjchem-2214	88	9	δ	δ	PROPN
eurjchem-2214	88	10	,	,	PUNCT
eurjchem-2214	88	11	ppm	ppm	NUM
eurjchem-2214	88	12	):	):	PUNCT
eurjchem-2214	88	13	199.1	199.1	NUM
eurjchem-2214	88	14	(	(	PUNCT
eurjchem-2214	88	15	ncs2	ncs2	PROPN
eurjchem-2214	88	16	,	,	PUNCT
eurjchem-2214	88	17	thioureide	thioureide	ADV
eurjchem-2214	88	18	)	)	PUNCT
eurjchem-2214	88	19	,	,	PUNCT
eurjchem-2214	88	20	49.2	49.2	NUM
eurjchem-2214	88	21	(	(	PUNCT
eurjchem-2214	88	22	nch2	nch2	PROPN
eurjchem-2214	88	23	)	)	PUNCT
eurjchem-2214	88	24	,	,	PUNCT
eurjchem-2214	88	25	24.4	24.4	NUM
eurjchem-2214	88	26	(	(	PUNCT
eurjchem-2214	88	27	ch2	ch2	PROPN
eurjchem-2214	88	28	)	)	PUNCT
eurjchem-2214	88	29	.	.	PUNCT
eurjchem-2214	89	1	31p	31p	NUM
eurjchem-2214	89	2	nmr	nmr	NOUN
eurjchem-2214	89	3	(	(	PUNCT
eurjchem-2214	89	4	162	162	NUM
eurjchem-2214	89	5	mhz	mhz	NOUN
eurjchem-2214	89	6	,	,	PUNCT
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eurjchem-2214	89	8	,	,	PUNCT
eurjchem-2214	89	9	δ	δ	PROPN
eurjchem-2214	89	10	,	,	PUNCT
eurjchem-2214	89	11	ppm	ppm	NUM
eurjchem-2214	89	12	):	):	PUNCT
eurjchem-2214	89	13	15.9	15.9	NUM
eurjchem-2214	89	14	(	(	PUNCT
eurjchem-2214	89	15	p	p	NOUN
eurjchem-2214	89	16	,	,	PUNCT
eurjchem-2214	89	17	pph3	pph3	NOUN
eurjchem-2214	89	18	)	)	PUNCT
eurjchem-2214	89	19	.	.	PUNCT
eurjchem-2214	90	1	anal	anal	PROPN
eurjchem-2214	90	2	.	.	PUNCT
eurjchem-2214	90	3	calcd	calcd	NOUN
eurjchem-2214	90	4	.	.	PUNCT
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eurjchem-2214	91	3	:	:	PUNCT
eurjchem-2214	91	4	c	c	X
eurjchem-2214	91	5	,	,	PUNCT
eurjchem-2214	91	6	57.11	57.11	NUM
eurjchem-2214	91	7	;	;	PUNCT
eurjchem-2214	91	8	h	h	NOUN
eurjchem-2214	91	9	,	,	PUNCT
eurjchem-2214	91	10	5.10	5.10	NUM
eurjchem-2214	91	11	;	;	PUNCT
eurjchem-2214	91	12	n	n	CCONJ
eurjchem-2214	91	13	,	,	PUNCT
eurjchem-2214	91	14	4.90	4.90	NUM
eurjchem-2214	91	15	.	.	PUNCT
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eurjchem-2214	92	2	:	:	PUNCT
eurjchem-2214	92	3	c	c	X
eurjchem-2214	92	4	,	,	PUNCT
eurjchem-2214	92	5	57.15	57.15	NUM
eurjchem-2214	92	6	;	;	PUNCT
eurjchem-2214	92	7	h	h	NOUN
eurjchem-2214	92	8	,	,	PUNCT
eurjchem-2214	92	9	5.15	5.15	NUM
eurjchem-2214	92	10	;	;	PUNCT
eurjchem-2214	92	11	n	n	CCONJ
eurjchem-2214	92	12	,	,	PUNCT
eurjchem-2214	92	13	4.94	4.94	NUM
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eurjchem-2214	92	15	.	.	PUNCT
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eurjchem-2214	93	2	/	/	SYM
eurjchem-2214	93	3	vis	vis	X
eurjchem-2214	93	4	(	(	PUNCT
eurjchem-2214	93	5	ch2cl2	ch2cl2	NOUN
eurjchem-2214	93	6	,	,	PUNCT
eurjchem-2214	93	7	λmax	λmax	NOUN
eurjchem-2214	93	8	,	,	PUNCT
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eurjchem-2214	93	10	,	,	PUNCT
eurjchem-2214	93	11	(	(	PUNCT
eurjchem-2214	93	12	od	od	NOUN
eurjchem-2214	93	13	)	)	PUNCT
eurjchem-2214	93	14	):	):	PUNCT
eurjchem-2214	93	15	480	480	NUM
eurjchem-2214	93	16	(	(	PUNCT
eurjchem-2214	93	17	4.65	4.65	NUM
eurjchem-2214	93	18	)	)	PUNCT
eurjchem-2214	93	19	.	.	PUNCT
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eurjchem-2214	94	2	(	(	PUNCT
eurjchem-2214	94	3	mv	mv	PROPN
eurjchem-2214	94	4	):	):	PUNCT
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eurjchem-2214	94	6	.	.	PUNCT
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eurjchem-2214	94	8	)	)	PUNCT
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eurjchem-2214	94	10	(	(	PUNCT
eurjchem-2214	94	11	ii	ii	NOUN
eurjchem-2214	94	12	)	)	PUNCT
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eurjchem-2214	94	14	(	(	PUNCT
eurjchem-2214	94	15	3	3	NUM
eurjchem-2214	94	16	):	):	PUNCT
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eurjchem-2214	94	18	:	:	PUNCT
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eurjchem-2214	94	20	.	.	PUNCT
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eurjchem-2214	94	22	:	:	PUNCT
eurjchem-2214	94	23	68	68	NUM
eurjchem-2214	94	24	%	%	NOUN
eurjchem-2214	94	25	.	.	PUNCT
eurjchem-2214	95	1	dec	dec	PROPN
eurjchem-2214	95	2	.	.	PROPN
eurjchem-2214	95	3	temp	temp	PROPN
eurjchem-2214	95	4	.	.	PUNCT
eurjchem-2214	96	1	:	:	PUNCT
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eurjchem-2214	97	4	.	.	PUNCT
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eurjchem-2214	98	2	(	(	PUNCT
eurjchem-2214	98	3	kbr	kbr	PROPN
eurjchem-2214	98	4	,	,	PUNCT
eurjchem-2214	98	5	ν	ν	PROPN
eurjchem-2214	98	6	,	,	PUNCT
eurjchem-2214	98	7	cm-1	cm-1	NUM
eurjchem-2214	98	8	):	):	PUNCT
eurjchem-2214	98	9	1528	1528	NUM
eurjchem-2214	98	10	(	(	PUNCT
eurjchem-2214	98	11	νc	νc	NOUN
eurjchem-2214	98	12	-	-	PUNCT
eurjchem-2214	98	13	n(thioureide	n(thioureide	NOUN
eurjchem-2214	98	14	)	)	PUNCT
eurjchem-2214	98	15	)	)	PUNCT
eurjchem-2214	98	16	,	,	PUNCT
eurjchem-2214	98	17	2112	2112	NUM
eurjchem-2214	98	18	(	(	PUNCT
eurjchem-2214	98	19	cn-	cn-	NOUN
eurjchem-2214	98	20	)	)	PUNCT
eurjchem-2214	98	21	.	.	PUNCT
eurjchem-2214	99	1	1h	1h	NUM
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eurjchem-2214	99	3	(	(	PUNCT
eurjchem-2214	99	4	400	400	NUM
eurjchem-2214	99	5	mhz	mhz	NOUN
eurjchem-2214	99	6	,	,	PUNCT
eurjchem-2214	99	7	cdcl3	cdcl3	PROPN
eurjchem-2214	99	8	,	,	PUNCT
eurjchem-2214	99	9	δ	δ	PROPN
eurjchem-2214	99	10	,	,	PUNCT
eurjchem-2214	99	11	ppm	ppm	NUM
eurjchem-2214	99	12	):	):	PUNCT
eurjchem-2214	99	13	3.48	3.48	NUM
eurjchem-2214	99	14	-	-	SYM
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eurjchem-2214	99	16	(	(	PUNCT
eurjchem-2214	99	17	t	t	PROPN
eurjchem-2214	99	18	,	,	PUNCT
eurjchem-2214	99	19	4h	4h	NUM
eurjchem-2214	99	20	,	,	PUNCT
eurjchem-2214	99	21	nch2ch2	nch2ch2	PROPN
eurjchem-2214	99	22	,	,	PUNCT
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eurjchem-2214	99	24	=	=	NUM
eurjchem-2214	99	25	6.4	6.4	NUM
eurjchem-2214	99	26	hz	hz	NOUN
eurjchem-2214	99	27	)	)	PUNCT
eurjchem-2214	99	28	,	,	PUNCT
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eurjchem-2214	99	30	-	-	SYM
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eurjchem-2214	99	32	(	(	PUNCT
eurjchem-2214	99	33	m	m	PROPN
eurjchem-2214	99	34	,	,	PUNCT
eurjchem-2214	99	35	4h	4h	NOUN
eurjchem-2214	99	36	,	,	PUNCT
eurjchem-2214	99	37	nch2ch2	nch2ch2	PROPN
eurjchem-2214	99	38	)	)	PUNCT
eurjchem-2214	99	39	,	,	PUNCT
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eurjchem-2214	99	41	-	-	SYM
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eurjchem-2214	99	43	(	(	PUNCT
eurjchem-2214	99	44	m	m	PROPN
eurjchem-2214	99	45	,	,	PUNCT
eurjchem-2214	99	46	15h	15h	NUM
eurjchem-2214	99	47	,	,	PUNCT
eurjchem-2214	99	48	pph3	pph3	NOUN
eurjchem-2214	99	49	)	)	PUNCT
eurjchem-2214	99	50	.	.	PUNCT
eurjchem-2214	100	1	13c	13c	NOUN
eurjchem-2214	100	2	nmr	nmr	NOUN
eurjchem-2214	100	3	(	(	PUNCT
eurjchem-2214	100	4	100	100	NUM
eurjchem-2214	100	5	mhz	mhz	NOUN
eurjchem-2214	100	6	,	,	PUNCT
eurjchem-2214	100	7	cdcl3	cdcl3	PROPN
eurjchem-2214	100	8	,	,	PUNCT
eurjchem-2214	100	9	δ	δ	PROPN
eurjchem-2214	100	10	,	,	PUNCT
eurjchem-2214	100	11	ppm	ppm	NOUN
eurjchem-2214	100	12	):	):	PUNCT
eurjchem-2214	100	13	200.6	200.6	NUM
eurjchem-2214	100	14	(	(	PUNCT
eurjchem-2214	100	15	ncs2	ncs2	PROPN
eurjchem-2214	100	16	,	,	PUNCT
eurjchem-2214	100	17	thioureide	thioureide	ADV
eurjchem-2214	100	18	)	)	PUNCT
eurjchem-2214	100	19	,	,	PUNCT
eurjchem-2214	100	20	49.0	49.0	NUM
eurjchem-2214	100	21	(	(	PUNCT
eurjchem-2214	100	22	nch2	nch2	PROPN
eurjchem-2214	100	23	)	)	PUNCT
eurjchem-2214	100	24	,	,	PUNCT
eurjchem-2214	100	25	24.3	24.3	NUM
eurjchem-2214	100	26	(	(	PUNCT
eurjchem-2214	100	27	ch2	ch2	PROPN
eurjchem-2214	100	28	)	)	PUNCT
eurjchem-2214	100	29	.	.	PUNCT
eurjchem-2214	101	1	31p	31p	NUM
eurjchem-2214	101	2	nmr	nmr	NOUN
eurjchem-2214	101	3	(	(	PUNCT
eurjchem-2214	101	4	162	162	NUM
eurjchem-2214	101	5	mhz	mhz	NOUN
eurjchem-2214	101	6	,	,	PUNCT
eurjchem-2214	101	7	cdcl3	cdcl3	PROPN
eurjchem-2214	101	8	,	,	PUNCT
eurjchem-2214	101	9	δ	δ	PROPN
eurjchem-2214	101	10	,	,	PUNCT
eurjchem-2214	101	11	ppm	ppm	NUM
eurjchem-2214	101	12	):	):	PUNCT
eurjchem-2214	101	13	29.4	29.4	NUM
eurjchem-2214	101	14	(	(	PUNCT
eurjchem-2214	101	15	p	p	NOUN
eurjchem-2214	101	16	,	,	PUNCT
eurjchem-2214	101	17	pph3	pph3	NOUN
eurjchem-2214	101	18	)	)	PUNCT
eurjchem-2214	101	19	.	.	PUNCT
eurjchem-2214	102	1	anal	anal	PROPN
eurjchem-2214	102	2	.	.	PUNCT
eurjchem-2214	102	3	calcd	calcd	NOUN
eurjchem-2214	102	4	.	.	PUNCT
eurjchem-2214	103	1	for	for	ADP
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eurjchem-2214	103	3	:	:	PUNCT
eurjchem-2214	103	4	c	c	X
eurjchem-2214	103	5	,	,	PUNCT
eurjchem-2214	103	6	56.35	56.35	NUM
eurjchem-2214	103	7	;	;	PUNCT
eurjchem-2214	103	8	h	h	NOUN
eurjchem-2214	103	9	,	,	PUNCT
eurjchem-2214	103	10	4.88	4.88	NUM
eurjchem-2214	103	11	;	;	PUNCT
eurjchem-2214	103	12	n	n	CCONJ
eurjchem-2214	103	13	,	,	PUNCT
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eurjchem-2214	103	17	:	:	PUNCT
eurjchem-2214	104	1	c	c	X
eurjchem-2214	104	2	,	,	PUNCT
eurjchem-2214	104	3	56.38	56.38	NUM
eurjchem-2214	104	4	;	;	PUNCT
eurjchem-2214	104	5	h	h	NOUN
eurjchem-2214	104	6	,	,	PUNCT
eurjchem-2214	104	7	4.92	4.92	NUM
eurjchem-2214	104	8	;	;	PUNCT
eurjchem-2214	104	9	n	n	CCONJ
eurjchem-2214	104	10	,	,	PUNCT
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eurjchem-2214	104	13	.	.	PUNCT
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eurjchem-2214	105	2	/	/	SYM
eurjchem-2214	105	3	vis	vis	X
eurjchem-2214	105	4	(	(	PUNCT
eurjchem-2214	105	5	ch2cl2	ch2cl2	NOUN
eurjchem-2214	105	6	,	,	PUNCT
eurjchem-2214	105	7	λmax	λmax	NOUN
eurjchem-2214	105	8	,	,	PUNCT
eurjchem-2214	105	9	nm	nm	NOUN
eurjchem-2214	105	10	,	,	PUNCT
eurjchem-2214	105	11	(	(	PUNCT
eurjchem-2214	105	12	od	od	NOUN
eurjchem-2214	105	13	)	)	PUNCT
eurjchem-2214	105	14	):	):	PUNCT
eurjchem-2214	105	15	431	431	NUM
eurjchem-2214	105	16	(	(	PUNCT
eurjchem-2214	105	17	5.15	5.15	NUM
eurjchem-2214	105	18	)	)	PUNCT
eurjchem-2214	105	19	.	.	PUNCT
eurjchem-2214	106	1	cv	cv	PROPN
eurjchem-2214	106	2	(	(	PUNCT
eurjchem-2214	106	3	mv	mv	PROPN
eurjchem-2214	106	4	):	):	PUNCT
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eurjchem-2214	106	6	.	.	PUNCT
eurjchem-2214	106	7	pyrrolidinecarbodithioatobis(triphenylphosphine	pyrrolidinecarbodithioatobis(triphenylphosphine	PROPN
eurjchem-2214	106	8	)	)	PUNCT
eurjchem-2214	106	9	nickel(ii	nickel(ii	ADJ
eurjchem-2214	106	10	)	)	PUNCT
eurjchem-2214	106	11	perchlorate	perchlorate	NOUN
eurjchem-2214	106	12	(	(	PUNCT
eurjchem-2214	106	13	4	4	NUM
eurjchem-2214	106	14	):	):	PUNCT
eurjchem-2214	106	15	color	color	NOUN
eurjchem-2214	106	16	:	:	PUNCT
eurjchem-2214	106	17	red	red	ADJ
eurjchem-2214	106	18	.	.	PUNCT
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eurjchem-2214	106	20	:	:	PUNCT
eurjchem-2214	106	21	72	72	NUM
eurjchem-2214	106	22	%	%	NOUN
eurjchem-2214	106	23	.	.	PUNCT
eurjchem-2214	107	1	dec	dec	PROPN
eurjchem-2214	107	2	.	.	PROPN
eurjchem-2214	107	3	temp	temp	PROPN
eurjchem-2214	107	4	.	.	PUNCT
eurjchem-2214	108	1	:	:	PUNCT
eurjchem-2214	108	2	200	200	NUM
eurjchem-2214	108	3	°	°	NOUN
eurjchem-2214	108	4	c	c	X
eurjchem-2214	108	5	.	.	PUNCT
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eurjchem-2214	109	2	et	et	PROPN
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eurjchem-2214	109	4	.	.	PUNCT
eurjchem-2214	109	5	/	/	SYM
eurjchem-2214	109	6	european	european	PROPN
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eurjchem-2214	109	12	1	1	NUM
eurjchem-2214	109	13	)	)	PUNCT
eurjchem-2214	109	14	(	(	PUNCT
eurjchem-2214	109	15	2022	2022	NUM
eurjchem-2214	109	16	)	)	PUNCT
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eurjchem-2214	109	18	-	-	SYM
eurjchem-2214	109	19	125	125	NUM
eurjchem-2214	109	20	119	119	NUM
eurjchem-2214	109	21	2022	2022	NUM
eurjchem-2214	109	22	–	–	PUNCT
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eurjchem-2214	109	24	journal	journal	NOUN
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eurjchem-2214	109	27	–	–	PUNCT
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eurjchem-2214	109	31	–	–	PUNCT
eurjchem-2214	109	32	doi	doi	NOUN
eurjchem-2214	109	33	:	:	PUNCT
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eurjchem-2214	109	35	/	/	SYM
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eurjchem-2214	109	37	-	-	SYM
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eurjchem-2214	109	40	(	(	PUNCT
eurjchem-2214	109	41	kbr	kbr	PROPN
eurjchem-2214	109	42	,	,	PUNCT
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eurjchem-2214	109	44	,	,	PUNCT
eurjchem-2214	109	45	cm-1	cm-1	NUM
eurjchem-2214	109	46	):	):	PUNCT
eurjchem-2214	109	47	1540	1540	NUM
eurjchem-2214	109	48	(	(	PUNCT
eurjchem-2214	109	49	νc	νc	NOUN
eurjchem-2214	109	50	-	-	PUNCT
eurjchem-2214	109	51	n(thioureide	n(thioureide	NOUN
eurjchem-2214	109	52	)	)	PUNCT
eurjchem-2214	109	53	)	)	PUNCT
eurjchem-2214	109	54	,	,	PUNCT
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eurjchem-2214	109	56	(	(	PUNCT
eurjchem-2214	109	57	clo4-	clo4-	NOUN
eurjchem-2214	109	58	)	)	PUNCT
eurjchem-2214	109	59	.	.	PUNCT
eurjchem-2214	110	1	1h	1h	NUM
eurjchem-2214	110	2	nmr	nmr	NOUN
eurjchem-2214	110	3	(	(	PUNCT
eurjchem-2214	110	4	400	400	NUM
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eurjchem-2214	110	6	,	,	PUNCT
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eurjchem-2214	110	8	,	,	PUNCT
eurjchem-2214	110	9	δ	δ	PROPN
eurjchem-2214	110	10	,	,	PUNCT
eurjchem-2214	110	11	ppm	ppm	NOUN
eurjchem-2214	110	12	):	):	PUNCT
eurjchem-2214	110	13	3.24	3.24	NUM
eurjchem-2214	110	14	-	-	SYM
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eurjchem-2214	110	16	(	(	PUNCT
eurjchem-2214	110	17	t	t	PROPN
eurjchem-2214	110	18	,	,	PUNCT
eurjchem-2214	110	19	4h	4h	NUM
eurjchem-2214	110	20	,	,	PUNCT
eurjchem-2214	110	21	nch2ch2	nch2ch2	PROPN
eurjchem-2214	110	22	,	,	PUNCT
eurjchem-2214	110	23	3j	3j	NOUN
eurjchem-2214	110	24	=	=	SYM
eurjchem-2214	110	25	6.2	6.2	NUM
eurjchem-2214	110	26	hz	hz	NOUN
eurjchem-2214	110	27	)	)	PUNCT
eurjchem-2214	110	28	,	,	PUNCT
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eurjchem-2214	110	30	-	-	SYM
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eurjchem-2214	110	32	(	(	PUNCT
eurjchem-2214	110	33	m	m	PROPN
eurjchem-2214	110	34	,	,	PUNCT
eurjchem-2214	110	35	4h	4h	NOUN
eurjchem-2214	110	36	,	,	PUNCT
eurjchem-2214	110	37	nch2ch2	nch2ch2	PROPN
eurjchem-2214	110	38	)	)	PUNCT
eurjchem-2214	110	39	,	,	PUNCT
eurjchem-2214	110	40	7.30	7.30	NUM
eurjchem-2214	110	41	-	-	SYM
eurjchem-2214	110	42	7.62	7.62	NUM
eurjchem-2214	110	43	(	(	PUNCT
eurjchem-2214	110	44	m	m	PROPN
eurjchem-2214	110	45	,	,	PUNCT
eurjchem-2214	110	46	15h	15h	NUM
eurjchem-2214	110	47	,	,	PUNCT
eurjchem-2214	110	48	pph3	pph3	NOUN
eurjchem-2214	110	49	)	)	PUNCT
eurjchem-2214	110	50	.	.	PUNCT
eurjchem-2214	111	1	13c	13c	NOUN
eurjchem-2214	111	2	nmr	nmr	NOUN
eurjchem-2214	111	3	(	(	PUNCT
eurjchem-2214	111	4	100	100	NUM
eurjchem-2214	111	5	mhz	mhz	NOUN
eurjchem-2214	111	6	,	,	PUNCT
eurjchem-2214	111	7	cdcl3	cdcl3	PROPN
eurjchem-2214	111	8	,	,	PUNCT
eurjchem-2214	111	9	δ	δ	PROPN
eurjchem-2214	111	10	,	,	PUNCT
eurjchem-2214	111	11	ppm	ppm	NUM
eurjchem-2214	111	12	):	):	PUNCT
eurjchem-2214	111	13	195.4	195.4	NUM
eurjchem-2214	111	14	(	(	PUNCT
eurjchem-2214	111	15	ncs2	ncs2	PROPN
eurjchem-2214	111	16	,	,	PUNCT
eurjchem-2214	111	17	thioureide	thioureide	ADV
eurjchem-2214	111	18	)	)	PUNCT
eurjchem-2214	111	19	,	,	PUNCT
eurjchem-2214	111	20	49.5	49.5	NUM
eurjchem-2214	111	21	(	(	PUNCT
eurjchem-2214	111	22	nch2	nch2	PROPN
eurjchem-2214	111	23	)	)	PUNCT
eurjchem-2214	111	24	,	,	PUNCT
eurjchem-2214	111	25	24.1	24.1	NUM
eurjchem-2214	111	26	(	(	PUNCT
eurjchem-2214	111	27	ch2	ch2	PROPN
eurjchem-2214	111	28	)	)	PUNCT
eurjchem-2214	111	29	.	.	PUNCT
eurjchem-2214	112	1	31p	31p	NUM
eurjchem-2214	112	2	nmr	nmr	NOUN
eurjchem-2214	112	3	(	(	PUNCT
eurjchem-2214	112	4	162	162	NUM
eurjchem-2214	112	5	mhz	mhz	NOUN
eurjchem-2214	112	6	,	,	PUNCT
eurjchem-2214	112	7	cdcl3	cdcl3	PROPN
eurjchem-2214	112	8	,	,	PUNCT
eurjchem-2214	112	9	δ	δ	PROPN
eurjchem-2214	112	10	,	,	PUNCT
eurjchem-2214	112	11	ppm	ppm	NUM
eurjchem-2214	112	12	):	):	PUNCT
eurjchem-2214	112	13	28.7	28.7	NUM
eurjchem-2214	112	14	(	(	PUNCT
eurjchem-2214	112	15	p	p	NOUN
eurjchem-2214	112	16	,	,	PUNCT
eurjchem-2214	112	17	pph3	pph3	NOUN
eurjchem-2214	112	18	)	)	PUNCT
eurjchem-2214	112	19	.	.	PUNCT
eurjchem-2214	113	1	anal	anal	PROPN
eurjchem-2214	113	2	.	.	PUNCT
eurjchem-2214	113	3	calcd	calcd	NOUN
eurjchem-2214	113	4	.	.	PUNCT
eurjchem-2214	114	1	for	for	ADP
eurjchem-2214	114	2	c41h38clnnio4p2s2	c41h38clnnio4p2s2	NOUN
eurjchem-2214	114	3	:	:	PUNCT
eurjchem-2214	114	4	c	c	X
eurjchem-2214	114	5	,	,	PUNCT
eurjchem-2214	114	6	59.35	59.35	NUM
eurjchem-2214	114	7	;	;	PUNCT
eurjchem-2214	114	8	h	h	NOUN
eurjchem-2214	114	9	,	,	PUNCT
eurjchem-2214	114	10	4.58	4.58	NUM
eurjchem-2214	114	11	,	,	PUNCT
eurjchem-2214	114	12	n	n	CCONJ
eurjchem-2214	114	13	,	,	PUNCT
eurjchem-2214	114	14	1.65	1.65	NUM
eurjchem-2214	114	15	.	.	PUNCT
eurjchem-2214	114	16	found	find	VERB
eurjchem-2214	114	17	:	:	PUNCT
eurjchem-2214	115	1	c	c	X
eurjchem-2214	115	2	,	,	PUNCT
eurjchem-2214	115	3	59.40	59.40	NUM
eurjchem-2214	115	4	;	;	PUNCT
eurjchem-2214	115	5	h	h	NOUN
eurjchem-2214	115	6	,	,	PUNCT
eurjchem-2214	115	7	4.62	4.62	NUM
eurjchem-2214	115	8	;	;	PUNCT
eurjchem-2214	115	9	n	n	CCONJ
eurjchem-2214	115	10	,	,	PUNCT
eurjchem-2214	115	11	1.69	1.69	NUM
eurjchem-2214	115	12	%	%	NOUN
eurjchem-2214	115	13	.	.	PUNCT
eurjchem-2214	116	1	uv	uv	NOUN
eurjchem-2214	116	2	/	/	SYM
eurjchem-2214	116	3	vis	vis	X
eurjchem-2214	116	4	(	(	PUNCT
eurjchem-2214	116	5	ch2cl2	ch2cl2	NOUN
eurjchem-2214	116	6	,	,	PUNCT
eurjchem-2214	116	7	λmax	λmax	NOUN
eurjchem-2214	116	8	,	,	PUNCT
eurjchem-2214	116	9	nm	nm	NOUN
eurjchem-2214	116	10	,	,	PUNCT
eurjchem-2214	116	11	(	(	PUNCT
eurjchem-2214	116	12	od	od	NOUN
eurjchem-2214	116	13	)	)	PUNCT
eurjchem-2214	116	14	):	):	PUNCT
eurjchem-2214	116	15	480	480	NUM
eurjchem-2214	116	16	(	(	PUNCT
eurjchem-2214	116	17	4.67	4.67	NUM
eurjchem-2214	116	18	)	)	PUNCT
eurjchem-2214	116	19	.	.	PUNCT
eurjchem-2214	117	1	cv	cv	PROPN
eurjchem-2214	117	2	(	(	PUNCT
eurjchem-2214	117	3	mv	mv	PROPN
eurjchem-2214	117	4	):	):	PUNCT
eurjchem-2214	117	5	-1440	-1440	PROPN
eurjchem-2214	117	6	.	.	PUNCT
eurjchem-2214	118	1	pyrrolidinecarbodithioato-1	pyrrolidinecarbodithioato-1	NOUN
eurjchem-2214	118	2	,	,	PUNCT
eurjchem-2214	118	3	2	2	NUM
eurjchem-2214	118	4	-	-	NUM
eurjchem-2214	118	5	bis(diphenylphosphinoetha	bis(diphenylphosphinoetha	NUM
eurjchem-2214	118	6	ne)nickel(ii	ne)nickel(ii	PROPN
eurjchem-2214	118	7	)	)	PUNCT
eurjchem-2214	118	8	tetraphenylborate	tetraphenylborate	NOUN
eurjchem-2214	118	9	(	(	PUNCT
eurjchem-2214	118	10	5	5	NUM
eurjchem-2214	118	11	):	):	PUNCT
eurjchem-2214	118	12	color	color	NOUN
eurjchem-2214	118	13	:	:	PUNCT
eurjchem-2214	119	1	red	red	ADJ
eurjchem-2214	119	2	.	.	PUNCT
eurjchem-2214	119	3	yield	yield	NOUN
eurjchem-2214	119	4	:	:	PUNCT
eurjchem-2214	119	5	71	71	NUM
eurjchem-2214	119	6	%	%	NOUN
eurjchem-2214	119	7	.	.	PUNCT
eurjchem-2214	120	1	dec	dec	PROPN
eurjchem-2214	120	2	.	.	PROPN
eurjchem-2214	120	3	temp	temp	PROPN
eurjchem-2214	120	4	.	.	PUNCT
eurjchem-2214	121	1	:	:	PUNCT
eurjchem-2214	121	2	205	205	NUM
eurjchem-2214	121	3	°	°	SYM
eurjchem-2214	121	4	c	c	NOUN
eurjchem-2214	121	5	.	.	PUNCT
eurjchem-2214	122	1	ft	ft	PROPN
eurjchem-2214	122	2	-	-	PUNCT
eurjchem-2214	122	3	ir	ir	PROPN
eurjchem-2214	122	4	(	(	PUNCT
eurjchem-2214	122	5	kbr	kbr	PROPN
eurjchem-2214	122	6	,	,	PUNCT
eurjchem-2214	122	7	ν	ν	PROPN
eurjchem-2214	122	8	,	,	PUNCT
eurjchem-2214	122	9	cm-1	cm-1	NUM
eurjchem-2214	122	10	):	):	PUNCT
eurjchem-2214	122	11	1529	1529	NUM
eurjchem-2214	122	12	(	(	PUNCT
eurjchem-2214	122	13	νc	νc	NOUN
eurjchem-2214	122	14	-	-	PUNCT
eurjchem-2214	122	15	n(thioureide	n(thioureide	NOUN
eurjchem-2214	122	16	)	)	PUNCT
eurjchem-2214	122	17	)	)	PUNCT
eurjchem-2214	122	18	,	,	PUNCT
eurjchem-2214	122	19	1434	1434	NUM
eurjchem-2214	122	20	(	(	PUNCT
eurjchem-2214	122	21	bph4-	bph4-	NUM
eurjchem-2214	122	22	)	)	PUNCT
eurjchem-2214	122	23	.	.	PUNCT
eurjchem-2214	123	1	1h	1h	NUM
eurjchem-2214	123	2	nmr	nmr	NOUN
eurjchem-2214	123	3	(	(	PUNCT
eurjchem-2214	123	4	400	400	NUM
eurjchem-2214	123	5	mhz	mhz	NOUN
eurjchem-2214	123	6	,	,	PUNCT
eurjchem-2214	123	7	cdcl3	cdcl3	PROPN
eurjchem-2214	123	8	,	,	PUNCT
eurjchem-2214	123	9	δ	δ	PROPN
eurjchem-2214	123	10	,	,	PUNCT
eurjchem-2214	123	11	ppm	ppm	NOUN
eurjchem-2214	123	12	):	):	PUNCT
eurjchem-2214	123	13	3.43	3.43	NUM
eurjchem-2214	123	14	-	-	SYM
eurjchem-2214	123	15	3.50	3.50	NUM
eurjchem-2214	123	16	(	(	PUNCT
eurjchem-2214	123	17	t	t	PROPN
eurjchem-2214	123	18	,	,	PUNCT
eurjchem-2214	123	19	4h	4h	NUM
eurjchem-2214	123	20	,	,	PUNCT
eurjchem-2214	123	21	nch2ch2	nch2ch2	PROPN
eurjchem-2214	123	22	,	,	PUNCT
eurjchem-2214	123	23	3j	3j	NOUN
eurjchem-2214	123	24	=	=	NOUN
eurjchem-2214	123	25	6.1	6.1	NUM
eurjchem-2214	123	26	hz	hz	NOUN
eurjchem-2214	123	27	)	)	PUNCT
eurjchem-2214	123	28	,	,	PUNCT
eurjchem-2214	123	29	1.52	1.52	NUM
eurjchem-2214	123	30	-	-	SYM
eurjchem-2214	123	31	1.61	1.61	NUM
eurjchem-2214	123	32	(	(	PUNCT
eurjchem-2214	123	33	m	m	PROPN
eurjchem-2214	123	34	,	,	PUNCT
eurjchem-2214	123	35	4h	4h	NOUN
eurjchem-2214	123	36	,	,	PUNCT
eurjchem-2214	123	37	nch2ch2	nch2ch2	PROPN
eurjchem-2214	123	38	)	)	PUNCT
eurjchem-2214	123	39	,	,	PUNCT
eurjchem-2214	123	40	7.32	7.32	NUM
eurjchem-2214	123	41	-	-	SYM
eurjchem-2214	123	42	7.60	7.60	NUM
eurjchem-2214	123	43	(	(	PUNCT
eurjchem-2214	123	44	m	m	PROPN
eurjchem-2214	123	45	,	,	PUNCT
eurjchem-2214	123	46	15h	15h	NUM
eurjchem-2214	123	47	,	,	PUNCT
eurjchem-2214	123	48	pph3	pph3	NOUN
eurjchem-2214	123	49	)	)	PUNCT
eurjchem-2214	123	50	.	.	PUNCT
eurjchem-2214	124	1	13c	13c	NOUN
eurjchem-2214	124	2	nmr	nmr	NOUN
eurjchem-2214	124	3	(	(	PUNCT
eurjchem-2214	124	4	100	100	NUM
eurjchem-2214	124	5	mhz	mhz	NOUN
eurjchem-2214	124	6	,	,	PUNCT
eurjchem-2214	124	7	cdcl3	cdcl3	PROPN
eurjchem-2214	124	8	,	,	PUNCT
eurjchem-2214	124	9	δ	δ	PROPN
eurjchem-2214	124	10	,	,	PUNCT
eurjchem-2214	124	11	ppm	ppm	NUM
eurjchem-2214	124	12	):	):	PUNCT
eurjchem-2214	124	13	197.4	197.4	NUM
eurjchem-2214	124	14	(	(	PUNCT
eurjchem-2214	124	15	ncs2	ncs2	PROPN
eurjchem-2214	124	16	,	,	PUNCT
eurjchem-2214	124	17	thioureide	thioureide	ADV
eurjchem-2214	124	18	)	)	PUNCT
eurjchem-2214	124	19	,	,	PUNCT
eurjchem-2214	124	20	49.7	49.7	NUM
eurjchem-2214	124	21	(	(	PUNCT
eurjchem-2214	124	22	nch2	nch2	PROPN
eurjchem-2214	124	23	)	)	PUNCT
eurjchem-2214	124	24	,	,	PUNCT
eurjchem-2214	124	25	24.2	24.2	NUM
eurjchem-2214	124	26	(	(	PUNCT
eurjchem-2214	124	27	ch2	ch2	PROPN
eurjchem-2214	124	28	)	)	PUNCT
eurjchem-2214	124	29	.	.	PUNCT
eurjchem-2214	125	1	31p	31p	NUM
eurjchem-2214	125	2	nmr	nmr	NOUN
eurjchem-2214	125	3	(	(	PUNCT
eurjchem-2214	125	4	162	162	NUM
eurjchem-2214	125	5	mhz	mhz	NOUN
eurjchem-2214	125	6	,	,	PUNCT
eurjchem-2214	125	7	cdcl3	cdcl3	PROPN
eurjchem-2214	125	8	,	,	PUNCT
eurjchem-2214	125	9	δ	δ	PROPN
eurjchem-2214	125	10	,	,	PUNCT
eurjchem-2214	125	11	ppm	ppm	NUM
eurjchem-2214	125	12	):	):	PUNCT
eurjchem-2214	125	13	61.5	61.5	NUM
eurjchem-2214	125	14	(	(	PUNCT
eurjchem-2214	125	15	p	p	X
eurjchem-2214	125	16	,	,	PUNCT
eurjchem-2214	125	17	pph3	pph3	NOUN
eurjchem-2214	125	18	)	)	PUNCT
eurjchem-2214	125	19	.	.	PUNCT
eurjchem-2214	126	1	anal	anal	PROPN
eurjchem-2214	126	2	.	.	PUNCT
eurjchem-2214	126	3	calcd	calcd	NOUN
eurjchem-2214	126	4	.	.	PUNCT
eurjchem-2214	127	1	for	for	ADP
eurjchem-2214	127	2	c55h56bnnio2p2s2	c55h56bnnio2p2s2	NOUN
eurjchem-2214	127	3	:	:	PUNCT
eurjchem-2214	127	4	c	c	X
eurjchem-2214	127	5	,	,	PUNCT
eurjchem-2214	127	6	68.86	68.86	NUM
eurjchem-2214	127	7	;	;	PUNCT
eurjchem-2214	127	8	h	h	X
eurjchem-2214	127	9	,	,	PUNCT
eurjchem-2214	127	10	5.85	5.85	NUM
eurjchem-2214	127	11	;	;	PUNCT
eurjchem-2214	127	12	n	n	CCONJ
eurjchem-2214	127	13	,	,	PUNCT
eurjchem-2214	127	14	1.44	1.44	NUM
eurjchem-2214	127	15	.	.	PUNCT
eurjchem-2214	127	16	found	find	VERB
eurjchem-2214	127	17	:	:	PUNCT
eurjchem-2214	128	1	c	c	X
eurjchem-2214	128	2	,	,	PUNCT
eurjchem-2214	128	3	68.91	68.91	NUM
eurjchem-2214	128	4	;	;	PUNCT
eurjchem-2214	129	1	h	h	NOUN
eurjchem-2214	129	2	,	,	PUNCT
eurjchem-2214	129	3	5.89	5.89	NUM
eurjchem-2214	129	4	;	;	PUNCT
eurjchem-2214	129	5	n	n	CCONJ
eurjchem-2214	129	6	,	,	PUNCT
eurjchem-2214	129	7	1.47	1.47	NUM
eurjchem-2214	129	8	%	%	NOUN
eurjchem-2214	129	9	.	.	PUNCT
eurjchem-2214	130	1	uv	uv	NOUN
eurjchem-2214	130	2	/	/	SYM
eurjchem-2214	130	3	vis	vis	X
eurjchem-2214	130	4	(	(	PUNCT
eurjchem-2214	130	5	ch2cl2	ch2cl2	NOUN
eurjchem-2214	130	6	,	,	PUNCT
eurjchem-2214	130	7	λmax	λmax	NOUN
eurjchem-2214	130	8	,	,	PUNCT
eurjchem-2214	130	9	nm	nm	NOUN
eurjchem-2214	130	10	,	,	PUNCT
eurjchem-2214	130	11	(	(	PUNCT
eurjchem-2214	130	12	od	od	NOUN
eurjchem-2214	130	13	)	)	PUNCT
eurjchem-2214	130	14	):	):	PUNCT
eurjchem-2214	130	15	440	440	NUM
eurjchem-2214	130	16	(	(	PUNCT
eurjchem-2214	130	17	4.17	4.17	NUM
eurjchem-2214	130	18	)	)	PUNCT
eurjchem-2214	130	19	.	.	PUNCT
eurjchem-2214	131	1	cv	cv	PROPN
eurjchem-2214	131	2	(	(	PUNCT
eurjchem-2214	131	3	mv	mv	PROPN
eurjchem-2214	131	4	):	):	PUNCT
eurjchem-2214	131	5	-892/	-892/	NOUN
eurjchem-2214	131	6	808	808	NUM
eurjchem-2214	131	7	.	.	NOUN
eurjchem-2214	131	8	3	3	NUM
eurjchem-2214	131	9	.	.	NOUN
eurjchem-2214	131	10	results	result	NOUN
eurjchem-2214	131	11	and	and	CCONJ
eurjchem-2214	131	12	discussion	discussion	NOUN
eurjchem-2214	131	13	3.1	3.1	NUM
eurjchem-2214	131	14	.	.	PUNCT
eurjchem-2214	132	1	infrared	infrared	PROPN
eurjchem-2214	132	2	spectra	spectra	PROPN
eurjchem-2214	132	3	ft	ft	PROPN
eurjchem-2214	132	4	-	-	PUNCT
eurjchem-2214	132	5	ir	ir	PROPN
eurjchem-2214	132	6	spectra	spectra	NOUN
eurjchem-2214	132	7	of	of	ADP
eurjchem-2214	132	8	the	the	DET
eurjchem-2214	132	9	planar	planar	ADJ
eurjchem-2214	132	10	ni(ii)-dithiocarbamate	ni(ii)-dithiocarbamate	NOUN
eurjchem-2214	132	11	complexes	complex	NOUN
eurjchem-2214	132	12	show	show	VERB
eurjchem-2214	132	13	signature	signature	NOUN
eurjchem-2214	132	14	bands	band	NOUN
eurjchem-2214	132	15	around	around	ADP
eurjchem-2214	132	16	1500	1500	NUM
eurjchem-2214	132	17	cm-1	cm-1	NOUN
eurjchem-2214	132	18	due	due	ADP
eurjchem-2214	132	19	to	to	ADP
eurjchem-2214	132	20	the	the	DET
eurjchem-2214	132	21	presence	presence	NOUN
eurjchem-2214	132	22	of	of	ADP
eurjchem-2214	132	23	thioureide	thioureide	ADJ
eurjchem-2214	132	24	group	group	NOUN
eurjchem-2214	132	25	.	.	PUNCT
eurjchem-2214	133	1	[	[	X
eurjchem-2214	133	2	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	133	3	]	]	PUNCT
eurjchem-2214	133	4	shows	show	VERB
eurjchem-2214	133	5	the	the	DET
eurjchem-2214	133	6	thioureide	thioureide	NOUN
eurjchem-2214	133	7	stretching	stretch	VERB
eurjchem-2214	133	8	band	band	NOUN
eurjchem-2214	133	9	at	at	ADP
eurjchem-2214	133	10	1510	1510	NUM
eurjchem-2214	133	11	cm-1	cm-1	NOUN
eurjchem-2214	133	12	and	and	CCONJ
eurjchem-2214	133	13	c	c	X
eurjchem-2214	133	14	-	-	PUNCT
eurjchem-2214	133	15	s	s	NOUN
eurjchem-2214	133	16	stretching	stretch	VERB
eurjchem-2214	133	17	band	band	NOUN
eurjchem-2214	133	18	at	at	ADP
eurjchem-2214	133	19	1050	1050	NUM
eurjchem-2214	133	20	cm-1	cm-1	NOUN
eurjchem-2214	133	21	.	.	PUNCT
eurjchem-2214	134	1	all	all	DET
eurjchem-2214	134	2	the	the	DET
eurjchem-2214	134	3	mixed	mixed	ADJ
eurjchem-2214	134	4	ligand	ligand	NOUN
eurjchem-2214	134	5	compounds	compound	NOUN
eurjchem-2214	134	6	reported	report	VERB
eurjchem-2214	134	7	in	in	ADP
eurjchem-2214	134	8	this	this	DET
eurjchem-2214	134	9	study	study	NOUN
eurjchem-2214	134	10	show	show	VERB
eurjchem-2214	134	11	a	a	DET
eurjchem-2214	134	12	significant	significant	ADJ
eurjchem-2214	134	13	increase	increase	NOUN
eurjchem-2214	134	14	in	in	ADP
eurjchem-2214	134	15	both	both	PRON
eurjchem-2214	134	16	thioureide	thioureide	NOUN
eurjchem-2214	134	17	and	and	CCONJ
eurjchem-2214	134	18	c	c	AUX
eurjchem-2214	134	19	-	-	PUNCT
eurjchem-2214	134	20	s	s	PRON
eurjchem-2214	134	21	stretching	stretch	VERB
eurjchem-2214	134	22	wavenumbers	wavenumber	NOUN
eurjchem-2214	134	23	(	(	PUNCT
eurjchem-2214	134	24	1532	1532	NUM
eurjchem-2214	134	25	,	,	PUNCT
eurjchem-2214	134	26	1096	1096	NUM
eurjchem-2214	134	27	(	(	PUNCT
eurjchem-2214	134	28	1	1	NUM
eurjchem-2214	134	29	)	)	PUNCT
eurjchem-2214	134	30	,	,	PUNCT
eurjchem-2214	134	31	1531	1531	NUM
eurjchem-2214	134	32	,	,	PUNCT
eurjchem-2214	134	33	1096	1096	NUM
eurjchem-2214	134	34	(	(	PUNCT
eurjchem-2214	134	35	2	2	NUM
eurjchem-2214	134	36	)	)	PUNCT
eurjchem-2214	134	37	,	,	PUNCT
eurjchem-2214	134	38	1528	1528	NUM
eurjchem-2214	134	39	,	,	PUNCT
eurjchem-2214	134	40	1095	1095	NUM
eurjchem-2214	134	41	(	(	PUNCT
eurjchem-2214	134	42	3	3	NUM
eurjchem-2214	134	43	)	)	PUNCT
eurjchem-2214	134	44	,	,	PUNCT
eurjchem-2214	134	45	1540	1540	NUM
eurjchem-2214	134	46	,	,	PUNCT
eurjchem-2214	134	47	1090	1090	NUM
eurjchem-2214	134	48	(	(	PUNCT
eurjchem-2214	134	49	4	4	NUM
eurjchem-2214	134	50	)	)	PUNCT
eurjchem-2214	134	51	,	,	PUNCT
eurjchem-2214	134	52	1529	1529	NUM
eurjchem-2214	134	53	,	,	PUNCT
eurjchem-2214	134	54	1100	1100	NUM
eurjchem-2214	134	55	(	(	PUNCT
eurjchem-2214	134	56	5	5	NUM
eurjchem-2214	134	57	)	)	PUNCT
eurjchem-2214	134	58	cm-1	cm-1	NOUN
eurjchem-2214	134	59	)	)	PUNCT
eurjchem-2214	134	60	.	.	PUNCT
eurjchem-2214	135	1	the	the	DET
eurjchem-2214	135	2	thioureide	thioureide	ADJ
eurjchem-2214	135	3	band	band	NOUN
eurjchem-2214	135	4	has	have	AUX
eurjchem-2214	135	5	been	be	AUX
eurjchem-2214	135	6	used	use	VERB
eurjchem-2214	135	7	as	as	ADP
eurjchem-2214	135	8	a	a	DET
eurjchem-2214	135	9	measure	measure	NOUN
eurjchem-2214	135	10	of	of	ADP
eurjchem-2214	135	11	the	the	DET
eurjchem-2214	135	12	contribution	contribution	NOUN
eurjchem-2214	135	13	of	of	ADP
eurjchem-2214	135	14	the	the	DET
eurjchem-2214	135	15	thioureide	thioureide	ADJ
eurjchem-2214	135	16	form	form	NOUN
eurjchem-2214	135	17	of	of	ADP
eurjchem-2214	135	18	the	the	DET
eurjchem-2214	135	19	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	135	20	ligands	ligand	NOUN
eurjchem-2214	135	21	and	and	CCONJ
eurjchem-2214	135	22	indicates	indicate	VERB
eurjchem-2214	135	23	the	the	DET
eurjchem-2214	135	24	extent	extent	NOUN
eurjchem-2214	135	25	of	of	ADP
eurjchem-2214	135	26	the	the	DET
eurjchem-2214	135	27	delocalization	delocalization	NOUN
eurjchem-2214	135	28	of	of	ADP
eurjchem-2214	135	29	electron	electron	NOUN
eurjchem-2214	135	30	density	density	NOUN
eurjchem-2214	135	31	between	between	ADP
eurjchem-2214	135	32	nitrogen	nitrogen	NOUN
eurjchem-2214	135	33	and	and	CCONJ
eurjchem-2214	135	34	carbon	carbon	NOUN
eurjchem-2214	135	35	.	.	PUNCT
eurjchem-2214	136	1	presence	presence	NOUN
eurjchem-2214	136	2	of	of	ADP
eurjchem-2214	136	3	pph3	pph3	NOUN
eurjchem-2214	136	4	around	around	ADP
eurjchem-2214	136	5	ni(ii	ni(ii	PROPN
eurjchem-2214	136	6	)	)	PUNCT
eurjchem-2214	136	7	increased	increase	VERB
eurjchem-2214	136	8	electron	electron	NOUN
eurjchem-2214	136	9	delocalization	delocalization	NOUN
eurjchem-2214	136	10	around	around	ADP
eurjchem-2214	136	11	the	the	DET
eurjchem-2214	136	12	metal	metal	NOUN
eurjchem-2214	136	13	compared	compare	VERB
eurjchem-2214	136	14	to	to	ADP
eurjchem-2214	136	15	the	the	DET
eurjchem-2214	136	16	parent	parent	NOUN
eurjchem-2214	136	17	bis	bis	ADJ
eurjchem-2214	136	18	-	-	PUNCT
eurjchem-2214	136	19	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	136	20	.	.	PUNCT
eurjchem-2214	137	1	the	the	DET
eurjchem-2214	137	2	band	band	NOUN
eurjchem-2214	137	3	observed	observe	VERB
eurjchem-2214	137	4	around	around	ADP
eurjchem-2214	137	5	1090	1090	NUM
eurjchem-2214	137	6	cm-1	cm-1	NOUN
eurjchem-2214	137	7	corresponds	correspond	NOUN
eurjchem-2214	137	8	to	to	ADP
eurjchem-2214	137	9	c	c	NOUN
eurjchem-2214	137	10	-	-	PUNCT
eurjchem-2214	137	11	s	s	PRON
eurjchem-2214	137	12	stretching	stretching	NOUN
eurjchem-2214	137	13	of	of	ADP
eurjchem-2214	137	14	the	the	DET
eurjchem-2214	137	15	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	137	16	moiety	moiety	NOUN
eurjchem-2214	137	17	.	.	PUNCT
eurjchem-2214	138	1	the	the	DET
eurjchem-2214	138	2	nc(s	nc(s	NUM
eurjchem-2214	138	3	)	)	PUNCT
eurjchem-2214	138	4	stretch	stretch	NOUN
eurjchem-2214	138	5	appears	appear	VERB
eurjchem-2214	138	6	at	at	ADP
eurjchem-2214	138	7	2094	2094	NUM
eurjchem-2214	138	8	and	and	CCONJ
eurjchem-2214	138	9	2099	2099	NUM
eurjchem-2214	138	10	cm-1	cm-1	X
eurjchem-2214	138	11	for	for	ADP
eurjchem-2214	138	12	compounds	compound	NOUN
eurjchem-2214	138	13	1	1	NUM
eurjchem-2214	138	14	and	and	CCONJ
eurjchem-2214	138	15	2	2	NUM
eurjchem-2214	138	16	,	,	PUNCT
eurjchem-2214	138	17	respectively	respectively	ADV
eurjchem-2214	138	18	.	.	PUNCT
eurjchem-2214	139	1	the	the	DET
eurjchem-2214	139	2	cyanide	cyanide	NOUN
eurjchem-2214	139	3	stretching	stretch	VERB
eurjchem-2214	139	4	band	band	NOUN
eurjchem-2214	139	5	appears	appear	VERB
eurjchem-2214	139	6	at	at	ADP
eurjchem-2214	139	7	2112	2112	NUM
eurjchem-2214	139	8	cm-1	cm-1	VERB
eurjchem-2214	139	9	for	for	ADP
eurjchem-2214	139	10	compound	compound	NOUN
eurjchem-2214	139	11	3	3	NUM
eurjchem-2214	139	12	.	.	PUNCT
eurjchem-2214	139	13	characteristic	characteristic	ADJ
eurjchem-2214	139	14	bands	band	NOUN
eurjchem-2214	139	15	due	due	ADP
eurjchem-2214	139	16	to	to	PART
eurjchem-2214	139	17	clo4and	clo4and	VERB
eurjchem-2214	139	18	bph4anions	bph4anion	NOUN
eurjchem-2214	139	19	appeared	appear	VERB
eurjchem-2214	139	20	at	at	ADP
eurjchem-2214	139	21	1100	1100	NUM
eurjchem-2214	139	22	and	and	CCONJ
eurjchem-2214	139	23	1434	1434	NUM
eurjchem-2214	139	24	cm-1	cm-1	NOUN
eurjchem-2214	139	25	respectively	respectively	ADV
eurjchem-2214	139	26	.	.	PUNCT
eurjchem-2214	140	1	the	the	DET
eurjchem-2214	140	2	c	c	NOUN
eurjchem-2214	140	3	-	-	PUNCT
eurjchem-2214	140	4	h	h	NOUN
eurjchem-2214	140	5	stretching	stretching	NOUN
eurjchem-2214	140	6	of	of	ADP
eurjchem-2214	140	7	the	the	DET
eurjchem-2214	140	8	pyrrolidine	pyrrolidine	ADJ
eurjchem-2214	140	9	ring	ring	NOUN
eurjchem-2214	140	10	in	in	ADP
eurjchem-2214	140	11	all	all	DET
eurjchem-2214	140	12	the	the	DET
eurjchem-2214	140	13	compounds	compound	NOUN
eurjchem-2214	140	14	remain	remain	VERB
eurjchem-2214	140	15	unaffected	unaffected	ADJ
eurjchem-2214	140	16	and	and	CCONJ
eurjchem-2214	140	17	is	be	AUX
eurjchem-2214	140	18	observed	observe	VERB
eurjchem-2214	140	19	~2920	~2920	PUNCT
eurjchem-2214	140	20	cm-1	cm-1	NOUN
eurjchem-2214	140	21	.	.	PUNCT
eurjchem-2214	141	1	3.2	3.2	NUM
eurjchem-2214	141	2	.	.	PUNCT
eurjchem-2214	142	1	electronic	electronic	ADJ
eurjchem-2214	142	2	spectra	spectra	ADJ
eurjchem-2214	142	3	electronic	electronic	ADJ
eurjchem-2214	142	4	spectra	spectra	NOUN
eurjchem-2214	142	5	of	of	ADP
eurjchem-2214	142	6	the	the	DET
eurjchem-2214	142	7	compounds	compound	NOUN
eurjchem-2214	142	8	were	be	AUX
eurjchem-2214	142	9	recorded	record	VERB
eurjchem-2214	142	10	in	in	ADP
eurjchem-2214	142	11	ch2cl2	ch2cl2	PROPN
eurjchem-2214	142	12	.	.	PUNCT
eurjchem-2214	142	13	electronic	electronic	ADJ
eurjchem-2214	142	14	spectrum	spectrum	NOUN
eurjchem-2214	142	15	of	of	ADP
eurjchem-2214	142	16	ammonium	ammonium	NOUN
eurjchem-2214	142	17	pyrrolidinedithiocarbamate	pyrrolidinedithiocarbamate	NOUN
eurjchem-2214	142	18	showed	show	VERB
eurjchem-2214	142	19	a	a	DET
eurjchem-2214	142	20	π	π	PROPN
eurjchem-2214	142	21	→	→	SYM
eurjchem-2214	142	22	π	π	PROPN
eurjchem-2214	142	23	*	*	PUNCT
eurjchem-2214	142	24	transition	transition	NOUN
eurjchem-2214	142	25	prominently	prominently	ADV
eurjchem-2214	142	26	at	at	ADP
eurjchem-2214	142	27	350	350	NUM
eurjchem-2214	142	28	nm	nm	NOUN
eurjchem-2214	142	29	.	.	PUNCT
eurjchem-2214	143	1	the	the	DET
eurjchem-2214	143	2	π	π	PROPN
eurjchem-2214	143	3	→	→	SYM
eurjchem-2214	143	4	π	π	PROPN
eurjchem-2214	143	5	*	*	PUNCT
eurjchem-2214	143	6	transition	transition	NOUN
eurjchem-2214	143	7	was	be	AUX
eurjchem-2214	143	8	identified	identify	VERB
eurjchem-2214	143	9	at	at	ADP
eurjchem-2214	143	10	380	380	NUM
eurjchem-2214	143	11	nm	nm	NOUN
eurjchem-2214	143	12	while	while	SCONJ
eurjchem-2214	143	13	the	the	DET
eurjchem-2214	143	14	n	n	X
eurjchem-2214	143	15	→	→	SYM
eurjchem-2214	143	16	π	π	PROPN
eurjchem-2214	143	17	*	*	PUNCT
eurjchem-2214	143	18	transition	transition	NOUN
eurjchem-2214	143	19	was	be	AUX
eurjchem-2214	143	20	observed	observe	VERB
eurjchem-2214	143	21	at	at	ADP
eurjchem-2214	143	22	320	320	NUM
eurjchem-2214	143	23	nm	nm	NOUN
eurjchem-2214	143	24	in	in	ADP
eurjchem-2214	143	25	the	the	DET
eurjchem-2214	143	26	parent	parent	NOUN
eurjchem-2214	144	1	[	[	X
eurjchem-2214	144	2	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	144	3	]	]	PUNCT
eurjchem-2214	144	4	.	.	PUNCT
eurjchem-2214	145	1	ligand	ligand	PROPN
eurjchem-2214	145	2	to	to	PART
eurjchem-2214	145	3	metal	metal	NOUN
eurjchem-2214	145	4	charge	charge	NOUN
eurjchem-2214	145	5	transfer	transfer	NOUN
eurjchem-2214	145	6	transition	transition	NOUN
eurjchem-2214	145	7	was	be	AUX
eurjchem-2214	145	8	observed	observe	VERB
eurjchem-2214	145	9	at	at	ADP
eurjchem-2214	145	10	390	390	NUM
eurjchem-2214	145	11	nm	nm	NOUN
eurjchem-2214	145	12	and	and	CCONJ
eurjchem-2214	145	13	the	the	DET
eurjchem-2214	145	14	d	d	PROPN
eurjchem-2214	145	15	-	-	PUNCT
eurjchem-2214	145	16	d	d	NOUN
eurjchem-2214	145	17	transition	transition	NOUN
eurjchem-2214	145	18	was	be	AUX
eurjchem-2214	145	19	observed	observe	VERB
eurjchem-2214	145	20	at	at	ADP
eurjchem-2214	145	21	430	430	NUM
eurjchem-2214	145	22	nm	nm	NOUN
eurjchem-2214	145	23	with	with	ADP
eurjchem-2214	145	24	relatively	relatively	ADV
eurjchem-2214	145	25	low	low	ADJ
eurjchem-2214	145	26	intensity	intensity	NOUN
eurjchem-2214	145	27	.	.	PUNCT
eurjchem-2214	146	1	in	in	ADP
eurjchem-2214	146	2	this	this	DET
eurjchem-2214	146	3	study	study	NOUN
eurjchem-2214	146	4	,	,	PUNCT
eurjchem-2214	146	5	d	d	X
eurjchem-2214	146	6	-	-	PUNCT
eurjchem-2214	146	7	d	d	ADJ
eurjchem-2214	146	8	transitions	transition	NOUN
eurjchem-2214	146	9	of	of	ADP
eurjchem-2214	146	10	the	the	DET
eurjchem-2214	146	11	various	various	ADJ
eurjchem-2214	146	12	planar	planar	ADJ
eurjchem-2214	146	13	nickel	nickel	NOUN
eurjchem-2214	146	14	-	-	PUNCT
eurjchem-2214	146	15	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	146	16	compounds	compound	NOUN
eurjchem-2214	146	17	are	be	AUX
eurjchem-2214	146	18	observed	observe	VERB
eurjchem-2214	146	19	in	in	ADP
eurjchem-2214	146	20	the	the	DET
eurjchem-2214	146	21	range	range	NOUN
eurjchem-2214	146	22	between	between	ADP
eurjchem-2214	146	23	430	430	NUM
eurjchem-2214	146	24	and	and	CCONJ
eurjchem-2214	146	25	480	480	NUM
eurjchem-2214	146	26	nm	nm	NOUN
eurjchem-2214	146	27	,	,	PUNCT
eurjchem-2214	146	28	due	due	ADP
eurjchem-2214	146	29	to	to	ADP
eurjchem-2214	146	30	dyz	dyz	PROPN
eurjchem-2214	146	31	-	-	PUNCT
eurjchem-2214	146	32	dxy	dxy	NOUN
eurjchem-2214	146	33	transitions	transition	NOUN
eurjchem-2214	146	34	[	[	X
eurjchem-2214	146	35	12	12	NUM
eurjchem-2214	146	36	]	]	PUNCT
eurjchem-2214	146	37	.	.	PUNCT
eurjchem-2214	147	1	absorption	absorption	NOUN
eurjchem-2214	147	2	bands	band	NOUN
eurjchem-2214	147	3	observed	observe	VERB
eurjchem-2214	147	4	around	around	ADP
eurjchem-2214	147	5	480	480	NUM
eurjchem-2214	147	6	nm	nm	NOUN
eurjchem-2214	147	7	in	in	ADP
eurjchem-2214	147	8	compounds	compound	NOUN
eurjchem-2214	147	9	1	1	NUM
eurjchem-2214	147	10	,	,	PUNCT
eurjchem-2214	147	11	2	2	NUM
eurjchem-2214	147	12	and	and	CCONJ
eurjchem-2214	147	13	4	4	NUM
eurjchem-2214	147	14	are	be	AUX
eurjchem-2214	147	15	attributed	attribute	VERB
eurjchem-2214	147	16	to	to	ADP
eurjchem-2214	147	17	d	d	PROPN
eurjchem-2214	147	18	-	-	PUNCT
eurjchem-2214	147	19	d	d	NOUN
eurjchem-2214	147	20	transitions	transition	NOUN
eurjchem-2214	147	21	.	.	PUNCT
eurjchem-2214	148	1	the	the	DET
eurjchem-2214	148	2	cyanide	cyanide	NOUN
eurjchem-2214	148	3	ion	ion	NOUN
eurjchem-2214	148	4	and	and	CCONJ
eurjchem-2214	148	5	chelating	chelating	NOUN
eurjchem-2214	148	6	dppe	dppe	NOUN
eurjchem-2214	148	7	force	force	VERB
eurjchem-2214	148	8	a	a	DET
eurjchem-2214	148	9	relatively	relatively	ADV
eurjchem-2214	148	10	larger	large	ADJ
eurjchem-2214	148	11	lfse	lfse	ADJ
eurjchem-2214	148	12	and	and	CCONJ
eurjchem-2214	148	13	hence	hence	ADV
eurjchem-2214	148	14	the	the	DET
eurjchem-2214	148	15	corresponding	corresponding	ADJ
eurjchem-2214	148	16	absorptions	absorption	NOUN
eurjchem-2214	148	17	were	be	AUX
eurjchem-2214	148	18	observed	observe	VERB
eurjchem-2214	148	19	at	at	ADP
eurjchem-2214	148	20	430	430	NUM
eurjchem-2214	148	21	and	and	CCONJ
eurjchem-2214	148	22	440	440	NUM
eurjchem-2214	148	23	nm	nm	NOUN
eurjchem-2214	148	24	in	in	ADP
eurjchem-2214	148	25	compounds	compound	NOUN
eurjchem-2214	148	26	3	3	NUM
eurjchem-2214	148	27	and	and	CCONJ
eurjchem-2214	148	28	5	5	NUM
eurjchem-2214	148	29	respectively	respectively	ADV
eurjchem-2214	148	30	.	.	PUNCT
eurjchem-2214	149	1	3.3	3.3	NUM
eurjchem-2214	149	2	.	.	PUNCT
eurjchem-2214	149	3	cyclic	cyclic	ADJ
eurjchem-2214	149	4	voltammetry	voltammetry	NOUN
eurjchem-2214	149	5	in	in	ADP
eurjchem-2214	149	6	all	all	DET
eurjchem-2214	149	7	complexes	complex	NOUN
eurjchem-2214	149	8	,	,	PUNCT
eurjchem-2214	149	9	ni(ii	ni(ii	PROPN
eurjchem-2214	149	10	)	)	PUNCT
eurjchem-2214	149	11	is	be	AUX
eurjchem-2214	149	12	reduced	reduce	VERB
eurjchem-2214	149	13	to	to	ADP
eurjchem-2214	149	14	ni(i	ni(i	NOUN
eurjchem-2214	149	15	)	)	PUNCT
eurjchem-2214	149	16	and	and	CCONJ
eurjchem-2214	149	17	mixed	mixed	ADJ
eurjchem-2214	149	18	ligand	ligand	NOUN
eurjchem-2214	149	19	complexes	complex	NOUN
eurjchem-2214	149	20	showed	show	VERB
eurjchem-2214	149	21	lower	low	ADJ
eurjchem-2214	149	22	reduction	reduction	NOUN
eurjchem-2214	149	23	potentials	potential	NOUN
eurjchem-2214	149	24	than	than	ADP
eurjchem-2214	149	25	the	the	DET
eurjchem-2214	149	26	parent	parent	NOUN
eurjchem-2214	149	27	,	,	PUNCT
eurjchem-2214	149	28	[	[	X
eurjchem-2214	149	29	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	149	30	]	]	X
eurjchem-2214	149	31	(	(	PUNCT
eurjchem-2214	149	32	-1789	-1789	ADV
eurjchem-2214	149	33	mv	mv	PROPN
eurjchem-2214	149	34	)	)	PUNCT
eurjchem-2214	149	35	.	.	PUNCT
eurjchem-2214	150	1	complex	complex	ADJ
eurjchem-2214	150	2	5	5	NUM
eurjchem-2214	150	3	showed	show	VERB
eurjchem-2214	150	4	relatively	relatively	ADV
eurjchem-2214	150	5	a	a	DET
eurjchem-2214	150	6	lower	low	ADJ
eurjchem-2214	150	7	reduction	reduction	NOUN
eurjchem-2214	150	8	potential	potential	NOUN
eurjchem-2214	150	9	(	(	PUNCT
eurjchem-2214	150	10	-892/-808	-892/-808	NOUN
eurjchem-2214	150	11	mv	mv	NOUN
eurjchem-2214	150	12	)	)	PUNCT
eurjchem-2214	150	13	than	than	ADP
eurjchem-2214	150	14	the	the	DET
eurjchem-2214	150	15	other	other	ADJ
eurjchem-2214	150	16	four	four	NUM
eurjchem-2214	150	17	complexes	complex	NOUN
eurjchem-2214	150	18	due	due	ADP
eurjchem-2214	150	19	to	to	ADP
eurjchem-2214	150	20	the	the	DET
eurjchem-2214	150	21	coordination	coordination	NOUN
eurjchem-2214	150	22	of	of	ADP
eurjchem-2214	150	23	chelating	chelate	VERB
eurjchem-2214	150	24	π	π	PROPN
eurjchem-2214	150	25	-	-	ADJ
eurjchem-2214	150	26	acceptor	acceptor	ADJ
eurjchem-2214	150	27	dppe	dppe	NOUN
eurjchem-2214	150	28	and	and	CCONJ
eurjchem-2214	150	29	underwent	undergo	VERB
eurjchem-2214	150	30	a	a	DET
eurjchem-2214	150	31	quasi	quasi	ADJ
eurjchem-2214	150	32	-	-	ADJ
eurjchem-2214	150	33	reversible	reversible	ADJ
eurjchem-2214	150	34	one	one	NUM
eurjchem-2214	150	35	-	-	PUNCT
eurjchem-2214	150	36	electron	electron	NOUN
eurjchem-2214	150	37	reduction	reduction	NOUN
eurjchem-2214	150	38	while	while	SCONJ
eurjchem-2214	150	39	the	the	DET
eurjchem-2214	150	40	other	other	ADJ
eurjchem-2214	150	41	complexes	complex	NOUN
eurjchem-2214	150	42	underwent	undergo	VERB
eurjchem-2214	150	43	irreversible	irreversible	ADJ
eurjchem-2214	150	44	reductions	reduction	NOUN
eurjchem-2214	150	45	.	.	PUNCT
eurjchem-2214	151	1	the	the	DET
eurjchem-2214	151	2	quasi	quasi	ADJ
eurjchem-2214	151	3	-	-	ADJ
eurjchem-2214	151	4	reversible	reversible	ADJ
eurjchem-2214	151	5	reduction	reduction	NOUN
eurjchem-2214	151	6	observed	observe	VERB
eurjchem-2214	151	7	in	in	ADP
eurjchem-2214	151	8	the	the	DET
eurjchem-2214	151	9	dppe	dppe	PROPN
eurjchem-2214	151	10	complex	complex	NOUN
eurjchem-2214	151	11	indicates	indicate	VERB
eurjchem-2214	151	12	the	the	DET
eurjchem-2214	151	13	effective	effective	ADJ
eurjchem-2214	151	14	π	π	ADJ
eurjchem-2214	151	15	-	-	ADJ
eurjchem-2214	151	16	acidic	acidic	ADJ
eurjchem-2214	151	17	cushioning	cushioning	NOUN
eurjchem-2214	151	18	provided	provide	VERB
eurjchem-2214	151	19	by	by	ADP
eurjchem-2214	151	20	the	the	DET
eurjchem-2214	151	21	ligand	ligand	NOUN
eurjchem-2214	151	22	.	.	PUNCT
eurjchem-2214	152	1	as	as	ADP
eurjchem-2214	152	2	a	a	DET
eurjchem-2214	152	3	contrast	contrast	NOUN
eurjchem-2214	152	4	,	,	PUNCT
eurjchem-2214	152	5	the	the	DET
eurjchem-2214	152	6	parent	parent	NOUN
eurjchem-2214	152	7	[	[	X
eurjchem-2214	152	8	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	152	9	]	]	X
eurjchem-2214	152	10	complex	complex	ADJ
eurjchem-2214	152	11	undergoes	undergo	VERB
eurjchem-2214	152	12	an	an	DET
eurjchem-2214	152	13	irreversible	irreversible	ADJ
eurjchem-2214	152	14	one	one	NUM
eurjchem-2214	152	15	-	-	PUNCT
eurjchem-2214	152	16	electron	electron	NOUN
eurjchem-2214	152	17	reduction	reduction	NOUN
eurjchem-2214	152	18	at	at	ADP
eurjchem-2214	152	19	-1789	-1789	PROPN
eurjchem-2214	152	20	mv	mv	PROPN
eurjchem-2214	152	21	,	,	PUNCT
eurjchem-2214	152	22	a	a	DET
eurjchem-2214	152	23	large	large	ADJ
eurjchem-2214	152	24	negative	negative	ADJ
eurjchem-2214	152	25	potential	potential	NOUN
eurjchem-2214	152	26	indicating	indicate	VERB
eurjchem-2214	152	27	the	the	DET
eurjchem-2214	152	28	reluctance	reluctance	NOUN
eurjchem-2214	152	29	of	of	ADP
eurjchem-2214	152	30	the	the	DET
eurjchem-2214	152	31	metal	metal	NOUN
eurjchem-2214	152	32	to	to	PART
eurjchem-2214	152	33	add	add	VERB
eurjchem-2214	152	34	electron	electron	NOUN
eurjchem-2214	152	35	density	density	NOUN
eurjchem-2214	152	36	to	to	ADP
eurjchem-2214	152	37	the	the	DET
eurjchem-2214	152	38	already	already	ADV
eurjchem-2214	152	39	electron	electron	NOUN
eurjchem-2214	152	40	rich	rich	ADJ
eurjchem-2214	152	41	center	center	NOUN
eurjchem-2214	152	42	[	[	X
eurjchem-2214	152	43	17	17	NUM
eurjchem-2214	152	44	]	]	PUNCT
eurjchem-2214	152	45	.	.	PUNCT
eurjchem-2214	153	1	between	between	ADP
eurjchem-2214	153	2	the	the	DET
eurjchem-2214	153	3	two	two	NUM
eurjchem-2214	153	4	limiting	limit	VERB
eurjchem-2214	153	5	values	value	NOUN
eurjchem-2214	153	6	of	of	ADP
eurjchem-2214	153	7	the	the	DET
eurjchem-2214	153	8	reduction	reduction	NOUN
eurjchem-2214	153	9	potentials	potential	NOUN
eurjchem-2214	153	10	,	,	PUNCT
eurjchem-2214	153	11	complex	complex	ADJ
eurjchem-2214	153	12	3	3	NUM
eurjchem-2214	153	13	undergoes	undergoe	NOUN
eurjchem-2214	153	14	reduction	reduction	NOUN
eurjchem-2214	153	15	at	at	ADP
eurjchem-2214	153	16	-1245	-1245	PROPN
eurjchem-2214	153	17	mv	mv	PROPN
eurjchem-2214	153	18	due	due	ADP
eurjchem-2214	153	19	to	to	ADP
eurjchem-2214	153	20	the	the	DET
eurjchem-2214	153	21	presence	presence	NOUN
eurjchem-2214	153	22	of	of	ADP
eurjchem-2214	153	23	both	both	DET
eurjchem-2214	153	24	cyanide	cyanide	NOUN
eurjchem-2214	153	25	ion	ion	NOUN
eurjchem-2214	153	26	and	and	CCONJ
eurjchem-2214	153	27	pph3	pph3	NOUN
eurjchem-2214	153	28	.	.	PUNCT
eurjchem-2214	154	1	complexes	complex	NOUN
eurjchem-2214	154	2	1	1	NUM
eurjchem-2214	154	3	and	and	CCONJ
eurjchem-2214	154	4	2	2	NUM
eurjchem-2214	154	5	showed	show	VERB
eurjchem-2214	154	6	comparable	comparable	ADJ
eurjchem-2214	154	7	reduction	reduction	NOUN
eurjchem-2214	154	8	potentials	potential	NOUN
eurjchem-2214	154	9	.	.	PUNCT
eurjchem-2214	155	1	following	follow	VERB
eurjchem-2214	155	2	is	be	AUX
eurjchem-2214	155	3	the	the	DET
eurjchem-2214	155	4	increasing	increase	VERB
eurjchem-2214	155	5	order	order	NOUN
eurjchem-2214	155	6	of	of	ADP
eurjchem-2214	155	7	reduction	reduction	NOUN
eurjchem-2214	155	8	potentials	potential	NOUN
eurjchem-2214	155	9	for	for	ADP
eurjchem-2214	155	10	the	the	DET
eurjchem-2214	155	11	complexes	complex	NOUN
eurjchem-2214	155	12	:	:	PUNCT
eurjchem-2214	155	13	5	5	NUM
eurjchem-2214	155	14	<	<	X
eurjchem-2214	155	15	<	<	X
eurjchem-2214	155	16	1	1	NUM
eurjchem-2214	155	17	~	~	SYM
eurjchem-2214	155	18	2	2	NUM
eurjchem-2214	155	19	<3	<3	PUNCT
eurjchem-2214	155	20	<	<	X
eurjchem-2214	155	21	4	4	NUM
eurjchem-2214	155	22	<	<	X
eurjchem-2214	155	23	<	<	X
eurjchem-2214	155	24	[	[	X
eurjchem-2214	155	25	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	155	26	]	]	PUNCT
eurjchem-2214	155	27	.	.	PUNCT
eurjchem-2214	156	1	3.4	3.4	NUM
eurjchem-2214	156	2	.	.	PUNCT
eurjchem-2214	157	1	nmr	nmr	PROPN
eurjchem-2214	157	2	spectra	spectra	PROPN
eurjchem-2214	157	3	pyrrolidine	pyrrolidine	PROPN
eurjchem-2214	157	4	shows	show	VERB
eurjchem-2214	157	5	two	two	NUM
eurjchem-2214	157	6	1h	1h	NUM
eurjchem-2214	157	7	nmr	nmr	NOUN
eurjchem-2214	157	8	signals	signal	NOUN
eurjchem-2214	157	9	at	at	ADP
eurjchem-2214	157	10	δ	δ	PROPN
eurjchem-2214	157	11	2.75	2.75	NUM
eurjchem-2214	157	12	and	and	CCONJ
eurjchem-2214	157	13	1.59	1.59	NUM
eurjchem-2214	157	14	ppm	ppm	NOUN
eurjchem-2214	157	15	for	for	ADP
eurjchem-2214	157	16	nch2ch2	nch2ch2	NOUN
eurjchem-2214	157	17	and	and	CCONJ
eurjchem-2214	157	18	nch2ch2	nch2ch2	NOUN
eurjchem-2214	157	19	protons	proton	NOUN
eurjchem-2214	157	20	,	,	PUNCT
eurjchem-2214	157	21	respectively	respectively	ADV
eurjchem-2214	157	22	.	.	PUNCT
eurjchem-2214	158	1	similarly	similarly	ADV
eurjchem-2214	158	2	,	,	PUNCT
eurjchem-2214	158	3	for	for	SCONJ
eurjchem-2214	158	4	the	the	DET
eurjchem-2214	158	5	ammonium	ammonium	NOUN
eurjchem-2214	158	6	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	VERB
eurjchem-2214	158	7	the	the	DET
eurjchem-2214	158	8	two	two	NUM
eurjchem-2214	158	9	signals	signal	NOUN
eurjchem-2214	158	10	were	be	AUX
eurjchem-2214	158	11	reported	report	VERB
eurjchem-2214	158	12	at	at	ADP
eurjchem-2214	158	13	δ	δ	PROPN
eurjchem-2214	158	14	3.65	3.65	NUM
eurjchem-2214	158	15	(	(	PUNCT
eurjchem-2214	158	16	n	n	CCONJ
eurjchem-2214	158	17	-	-	PUNCT
eurjchem-2214	158	18	ch2	ch2	NOUN
eurjchem-2214	158	19	)	)	PUNCT
eurjchem-2214	158	20	and	and	CCONJ
eurjchem-2214	158	21	1.84	1.84	NUM
eurjchem-2214	158	22	(	(	PUNCT
eurjchem-2214	158	23	c	c	NOUN
eurjchem-2214	158	24	-	-	PUNCT
eurjchem-2214	158	25	ch2	ch2	NOUN
eurjchem-2214	158	26	)	)	PUNCT
eurjchem-2214	158	27	ppm	ppm	NOUN
eurjchem-2214	159	1	[	[	X
eurjchem-2214	159	2	36	36	NUM
eurjchem-2214	159	3	]	]	PUNCT
eurjchem-2214	159	4	.	.	PUNCT
eurjchem-2214	160	1	on	on	ADP
eurjchem-2214	160	2	complex	complex	ADJ
eurjchem-2214	160	3	formation	formation	NOUN
eurjchem-2214	160	4	,	,	PUNCT
eurjchem-2214	160	5	the	the	DET
eurjchem-2214	160	6	protons	proton	NOUN
eurjchem-2214	160	7	adjacent	adjacent	ADJ
eurjchem-2214	160	8	to	to	ADP
eurjchem-2214	160	9	nitrogen	nitrogen	NOUN
eurjchem-2214	160	10	(	(	PUNCT
eurjchem-2214	160	11	nch2ch2	nch2ch2	NOUN
eurjchem-2214	160	12	)	)	PUNCT
eurjchem-2214	160	13	atom	atom	NOUN
eurjchem-2214	160	14	undergo	undergo	VERB
eurjchem-2214	160	15	strong	strong	ADJ
eurjchem-2214	160	16	deshielding	deshielding	NOUN
eurjchem-2214	160	17	whereas	whereas	SCONJ
eurjchem-2214	160	18	the	the	DET
eurjchem-2214	160	19	protons	proton	NOUN
eurjchem-2214	160	20	away	away	ADV
eurjchem-2214	160	21	from	from	ADP
eurjchem-2214	160	22	n	n	X
eurjchem-2214	160	23	-	-	PUNCT
eurjchem-2214	160	24	atom	atom	NOUN
eurjchem-2214	160	25	(	(	PUNCT
eurjchem-2214	160	26	nch2ch2	nch2ch2	NOUN
eurjchem-2214	160	27	)	)	PUNCT
eurjchem-2214	160	28	undergo	undergo	VERB
eurjchem-2214	160	29	weak	weak	ADJ
eurjchem-2214	160	30	deshielding	deshielding	NOUN
eurjchem-2214	160	31	.	.	PUNCT
eurjchem-2214	161	1	in	in	ADP
eurjchem-2214	161	2	complex	complex	ADJ
eurjchem-2214	161	3	1	1	NUM
eurjchem-2214	161	4	,	,	PUNCT
eurjchem-2214	161	5	nch2ch2	nch2ch2	ADJ
eurjchem-2214	161	6	protons	proton	NOUN
eurjchem-2214	161	7	undergo	undergo	VERB
eurjchem-2214	161	8	strong	strong	ADJ
eurjchem-2214	161	9	deshielding	deshielding	NOUN
eurjchem-2214	161	10	to	to	PART
eurjchem-2214	161	11	give	give	VERB
eurjchem-2214	161	12	the	the	DET
eurjchem-2214	161	13	signal	signal	NOUN
eurjchem-2214	161	14	at	at	ADP
eurjchem-2214	161	15	δ	δ	PROPN
eurjchem-2214	161	16	3.48	3.48	NUM
eurjchem-2214	161	17	-	-	SYM
eurjchem-2214	161	18	3.52	3.52	NUM
eurjchem-2214	161	19	ppm	ppm	NOUN
eurjchem-2214	161	20	and	and	CCONJ
eurjchem-2214	161	21	nch2ch2	nch2ch2	NOUN
eurjchem-2214	161	22	protons	proton	NOUN
eurjchem-2214	161	23	undergo	undergo	VERB
eurjchem-2214	161	24	weak	weak	ADJ
eurjchem-2214	161	25	deshielding	deshielding	NOUN
eurjchem-2214	161	26	at	at	ADP
eurjchem-2214	161	27	δ	δ	PROPN
eurjchem-2214	161	28	1.82	1.82	NUM
eurjchem-2214	161	29	-	-	SYM
eurjchem-2214	161	30	1.95	1.95	NUM
eurjchem-2214	161	31	ppm	ppm	NOUN
eurjchem-2214	161	32	.	.	PUNCT
eurjchem-2214	162	1	a	a	DET
eurjchem-2214	162	2	similar	similar	ADJ
eurjchem-2214	162	3	trend	trend	NOUN
eurjchem-2214	162	4	of	of	ADP
eurjchem-2214	162	5	chemical	chemical	ADJ
eurjchem-2214	162	6	shifts	shift	NOUN
eurjchem-2214	162	7	is	be	AUX
eurjchem-2214	162	8	observed	observe	VERB
eurjchem-2214	162	9	for	for	ADP
eurjchem-2214	162	10	compounds	compound	NOUN
eurjchem-2214	162	11	2	2	NUM
eurjchem-2214	162	12	to	to	PART
eurjchem-2214	162	13	5	5	NUM
eurjchem-2214	162	14	indicating	indicate	VERB
eurjchem-2214	162	15	the	the	DET
eurjchem-2214	162	16	fact	fact	NOUN
eurjchem-2214	162	17	that	that	SCONJ
eurjchem-2214	162	18	the	the	DET
eurjchem-2214	162	19	protons	proton	NOUN
eurjchem-2214	162	20	away	away	ADV
eurjchem-2214	162	21	from	from	ADP
eurjchem-2214	162	22	nitrogen	nitrogen	NOUN
eurjchem-2214	162	23	are	be	AUX
eurjchem-2214	162	24	less	less	ADV
eurjchem-2214	162	25	deshielded	deshielded	ADJ
eurjchem-2214	162	26	compared	compare	VERB
eurjchem-2214	162	27	to	to	ADP
eurjchem-2214	162	28	those	those	PRON
eurjchem-2214	162	29	which	which	PRON
eurjchem-2214	162	30	are	be	AUX
eurjchem-2214	162	31	adjacent	adjacent	ADJ
eurjchem-2214	162	32	to	to	ADP
eurjchem-2214	162	33	the	the	DET
eurjchem-2214	162	34	nitrogen	nitrogen	NOUN
eurjchem-2214	162	35	.	.	PUNCT
eurjchem-2214	163	1	the	the	DET
eurjchem-2214	163	2	chemical	chemical	ADJ
eurjchem-2214	163	3	shifts	shift	NOUN
eurjchem-2214	163	4	of	of	ADP
eurjchem-2214	163	5	the	the	DET
eurjchem-2214	163	6	carbon	carbon	NOUN
eurjchem-2214	163	7	atom	atom	NOUN
eurjchem-2214	163	8	of	of	ADP
eurjchem-2214	163	9	the	the	DET
eurjchem-2214	163	10	>	>	X
eurjchem-2214	163	11	ncs2	ncs2	ADJ
eurjchem-2214	163	12	moiety	moiety	NOUN
eurjchem-2214	163	13	are	be	AUX
eurjchem-2214	163	14	correlated	correlate	VERB
eurjchem-2214	163	15	to	to	ADP
eurjchem-2214	163	16	the	the	DET
eurjchem-2214	163	17	bonding	bonding	NOUN
eurjchem-2214	163	18	in	in	ADP
eurjchem-2214	163	19	the	the	DET
eurjchem-2214	163	20	>	>	X
eurjchem-2214	163	21	ncs2	ncs2	PROPN
eurjchem-2214	163	22	fragment	fragment	NOUN
eurjchem-2214	163	23	from	from	ADP
eurjchem-2214	163	24	the	the	DET
eurjchem-2214	163	25	13c	13c	NOUN
eurjchem-2214	163	26	nmr	nmr	NOUN
eurjchem-2214	163	27	spectra	spectra	NOUN
eurjchem-2214	163	28	of	of	ADP
eurjchem-2214	163	29	complexes	complex	NOUN
eurjchem-2214	163	30	.	.	PUNCT
eurjchem-2214	164	1	the	the	DET
eurjchem-2214	164	2	thioureide	thioureide	NOUN
eurjchem-2214	164	3	stretching	stretching	NOUN
eurjchem-2214	164	4	bands	band	NOUN
eurjchem-2214	164	5	are	be	AUX
eurjchem-2214	164	6	usually	usually	ADV
eurjchem-2214	164	7	observed	observe	VERB
eurjchem-2214	164	8	around	around	ADP
eurjchem-2214	164	9	1500	1500	NUM
eurjchem-2214	164	10	cm-1	cm-1	NOUN
eurjchem-2214	164	11	for	for	ADP
eurjchem-2214	164	12	n	n	CCONJ
eurjchem-2214	164	13	,	,	PUNCT
eurjchem-2214	164	14	n	n	CCONJ
eurjchem-2214	164	15	-	-	PUNCT
eurjchem-2214	164	16	dialkyldithio	dialkyldithio	NOUN
eurjchem-2214	164	17	carbamates	carbamate	NOUN
eurjchem-2214	164	18	.	.	PUNCT
eurjchem-2214	165	1	complex	complex	ADJ
eurjchem-2214	165	2	1	1	NUM
eurjchem-2214	165	3	shows	show	VERB
eurjchem-2214	165	4	the	the	DET
eurjchem-2214	165	5	thioureide	thioureide	ADJ
eurjchem-2214	165	6	band	band	NOUN
eurjchem-2214	165	7	at	at	ADP
eurjchem-2214	165	8	1533	1533	NUM
eurjchem-2214	165	9	cm1	cm1	NOUN
eurjchem-2214	165	10	and	and	CCONJ
eurjchem-2214	165	11	hence	hence	ADV
eurjchem-2214	165	12	a	a	DET
eurjchem-2214	165	13	low	low	ADJ
eurjchem-2214	165	14	13c	13c	NOUN
eurjchem-2214	165	15	chemical	chemical	NOUN
eurjchem-2214	165	16	shift	shift	NOUN
eurjchem-2214	165	17	was	be	AUX
eurjchem-2214	165	18	observed	observe	VERB
eurjchem-2214	165	19	at	at	ADP
eurjchem-2214	165	20	δ	δ	PROPN
eurjchem-2214	165	21	198.9	198.9	NUM
eurjchem-2214	165	22	ppm	ppm	NOUN
eurjchem-2214	165	23	.	.	PUNCT
eurjchem-2214	166	1	the	the	DET
eurjchem-2214	166	2	cyanide	cyanide	NOUN
eurjchem-2214	166	3	and	and	CCONJ
eurjchem-2214	166	4	the	the	DET
eurjchem-2214	166	5	isothiocyanate	isothiocyanate	ADJ
eurjchem-2214	166	6	carbon	carbon	NOUN
eurjchem-2214	166	7	signals	signal	NOUN
eurjchem-2214	166	8	are	be	AUX
eurjchem-2214	166	9	observed	observe	VERB
eurjchem-2214	166	10	merged	merge	VERB
eurjchem-2214	166	11	with	with	ADP
eurjchem-2214	166	12	the	the	DET
eurjchem-2214	166	13	phenyl	phenyl	NOUN
eurjchem-2214	166	14	ring	ring	NOUN
eurjchem-2214	166	15	carbons	carbon	NOUN
eurjchem-2214	166	16	in	in	ADP
eurjchem-2214	166	17	the	the	DET
eurjchem-2214	166	18	δ	δ	PROPN
eurjchem-2214	166	19	range	range	VERB
eurjchem-2214	166	20	130	130	NUM
eurjchem-2214	166	21	and	and	CCONJ
eurjchem-2214	166	22	145	145	NUM
eurjchem-2214	166	23	ppm	ppm	NOUN
eurjchem-2214	166	24	.	.	PUNCT
eurjchem-2214	167	1	the	the	DET
eurjchem-2214	167	2	n13cs2	n13cs2	PROPN
eurjchem-2214	167	3	signal	signal	NOUN
eurjchem-2214	167	4	of	of	ADP
eurjchem-2214	167	5	compound	compound	NOUN
eurjchem-2214	167	6	4	4	NUM
eurjchem-2214	167	7	appears	appear	VERB
eurjchem-2214	167	8	highly	highly	ADV
eurjchem-2214	167	9	deshielded	deshielde	VERB
eurjchem-2214	167	10	than	than	ADP
eurjchem-2214	167	11	the	the	DET
eurjchem-2214	167	12	other	other	ADJ
eurjchem-2214	167	13	due	due	ADP
eurjchem-2214	167	14	to	to	ADP
eurjchem-2214	167	15	the	the	DET
eurjchem-2214	167	16	mitigation	mitigation	NOUN
eurjchem-2214	167	17	of	of	ADP
eurjchem-2214	167	18	electron	electron	NOUN
eurjchem-2214	167	19	density	density	NOUN
eurjchem-2214	167	20	on	on	ADP
eurjchem-2214	167	21	nickel	nickel	NOUN
eurjchem-2214	167	22	by	by	ADP
eurjchem-2214	167	23	the	the	DET
eurjchem-2214	167	24	presence	presence	NOUN
eurjchem-2214	167	25	of	of	ADP
eurjchem-2214	167	26	two	two	NUM
eurjchem-2214	167	27	phosphines	phosphine	NOUN
eurjchem-2214	167	28	.	.	PUNCT
eurjchem-2214	168	1	free	free	ADJ
eurjchem-2214	168	2	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2214	168	3	31p	31p	NUM
eurjchem-2214	168	4	signal	signal	NOUN
eurjchem-2214	168	5	appears	appear	VERB
eurjchem-2214	168	6	at	at	ADP
eurjchem-2214	168	7	δ	δ	PROPN
eurjchem-2214	168	8	equivalent	equivalent	ADJ
eurjchem-2214	168	9	to	to	PART
eurjchem-2214	168	10	-5	-5	VERB
eurjchem-2214	168	11	ppm	ppm	VERB
eurjchem-2214	168	12	a	a	DET
eurjchem-2214	168	13	coordinated	coordinated	ADJ
eurjchem-2214	168	14	phosphine	phosphine	NOUN
eurjchem-2214	168	15	has	have	VERB
eurjchem-2214	168	16	a	a	DET
eurjchem-2214	168	17	signal	signal	NOUN
eurjchem-2214	168	18	at	at	ADP
eurjchem-2214	168	19	δ	δ	PROPN
eurjchem-2214	168	20	20	20	NUM
eurjchem-2214	168	21	ppm	ppm	NOUN
eurjchem-2214	168	22	,	,	PUNCT
eurjchem-2214	168	23	a	a	DET
eurjchem-2214	168	24	free	free	ADJ
eurjchem-2214	168	25	chelating	chelating	NOUN
eurjchem-2214	168	26	dppe	dppe	NOUN
eurjchem-2214	168	27	has	have	VERB
eurjchem-2214	168	28	a	a	DET
eurjchem-2214	168	29	signal	signal	NOUN
eurjchem-2214	168	30	at	at	ADP
eurjchem-2214	168	31	δ	δ	PROPN
eurjchem-2214	168	32	30	30	NUM
eurjchem-2214	168	33	ppm	ppm	NOUN
eurjchem-2214	168	34	,	,	PUNCT
eurjchem-2214	168	35	and	and	CCONJ
eurjchem-2214	168	36	a	a	DET
eurjchem-2214	168	37	coordinated	coordinate	VERB
eurjchem-2214	168	38	chelating	chelating	NOUN
eurjchem-2214	168	39	dppe	dppe	NOUN
eurjchem-2214	168	40	has	have	VERB
eurjchem-2214	168	41	a	a	DET
eurjchem-2214	168	42	signal	signal	NOUN
eurjchem-2214	168	43	at	at	ADP
eurjchem-2214	168	44	δ	δ	PROPN
eurjchem-2214	168	45	60	60	NUM
eurjchem-2214	168	46	ppm	ppm	NOUN
eurjchem-2214	168	47	[	[	X
eurjchem-2214	168	48	7	7	NUM
eurjchem-2214	168	49	-	-	SYM
eurjchem-2214	168	50	9	9	NUM
eurjchem-2214	168	51	]	]	PUNCT
eurjchem-2214	168	52	.	.	PUNCT
eurjchem-2214	169	1	31p	31p	PROPN
eurjchem-2214	169	2	signals	signal	NOUN
eurjchem-2214	169	3	are	be	AUX
eurjchem-2214	169	4	observed	observe	VERB
eurjchem-2214	169	5	at	at	ADP
eurjchem-2214	169	6	δ	δ	PROPN
eurjchem-2214	169	7	29.4	29.4	NUM
eurjchem-2214	169	8	,	,	PUNCT
eurjchem-2214	169	9	28.7	28.7	NUM
eurjchem-2214	169	10	,	,	PUNCT
eurjchem-2214	169	11	19.9	19.9	NUM
eurjchem-2214	169	12	,	,	PUNCT
eurjchem-2214	169	13	and	and	CCONJ
eurjchem-2214	169	14	15.9	15.9	NUM
eurjchem-2214	169	15	ppm	ppm	NOUN
eurjchem-2214	169	16	for	for	ADP
eurjchem-2214	169	17	nis2pc	nis2pc	PROPN
eurjchem-2214	169	18	(	(	PUNCT
eurjchem-2214	169	19	3	3	NUM
eurjchem-2214	169	20	)	)	PUNCT
eurjchem-2214	169	21	,	,	PUNCT
eurjchem-2214	169	22	nis2p2(4	nis2p2(4	PROPN
eurjchem-2214	169	23	)	)	PUNCT
eurjchem-2214	169	24	,	,	PUNCT
eurjchem-2214	169	25	nis2pn	nis2pn	NOUN
eurjchem-2214	169	26	(	(	PUNCT
eurjchem-2214	169	27	1	1	NUM
eurjchem-2214	169	28	)	)	PUNCT
eurjchem-2214	169	29	,	,	PUNCT
eurjchem-2214	169	30	and	and	CCONJ
eurjchem-2214	169	31	nis2p(4	nis2p(4	PROPN
eurjchem-2214	169	32	-	-	PROPN
eurjchem-2214	169	33	me)3n	me)3n	PROPN
eurjchem-2214	169	34	(	(	PUNCT
eurjchem-2214	169	35	2	2	NUM
eurjchem-2214	169	36	)	)	PUNCT
eurjchem-2214	169	37	chromophores	chromophore	NOUN
eurjchem-2214	169	38	,	,	PUNCT
eurjchem-2214	169	39	respectively	respectively	ADV
eurjchem-2214	169	40	,	,	PUNCT
eurjchem-2214	169	41	in	in	ADP
eurjchem-2214	169	42	the	the	DET
eurjchem-2214	169	43	given	give	VERB
eurjchem-2214	169	44	order	order	NOUN
eurjchem-2214	169	45	.	.	PUNCT
eurjchem-2214	170	1	a	a	DET
eurjchem-2214	170	2	very	very	ADV
eurjchem-2214	170	3	high	high	ADJ
eurjchem-2214	170	4	deshielding	deshielding	NOUN
eurjchem-2214	170	5	observed	observe	VERB
eurjchem-2214	170	6	in	in	ADP
eurjchem-2214	170	7	the	the	DET
eurjchem-2214	170	8	case	case	NOUN
eurjchem-2214	170	9	of	of	ADP
eurjchem-2214	170	10	nis2pc	nis2pc	PROPN
eurjchem-2214	170	11	(	(	PUNCT
eurjchem-2214	170	12	3	3	X
eurjchem-2214	170	13	)	)	PUNCT
eurjchem-2214	170	14	chromophore	chromophore	NOUN
eurjchem-2214	170	15	indicates	indicate	VERB
eurjchem-2214	170	16	a	a	DET
eurjchem-2214	170	17	relatively	relatively	ADV
eurjchem-2214	170	18	strong	strong	ADJ
eurjchem-2214	170	19	coordination	coordination	NOUN
eurjchem-2214	170	20	of	of	ADP
eurjchem-2214	170	21	phosphine	phosphine	NOUN
eurjchem-2214	170	22	to	to	ADP
eurjchem-2214	170	23	nickel	nickel	NOUN
eurjchem-2214	170	24	compared	compare	VERB
eurjchem-2214	170	25	to	to	ADP
eurjchem-2214	170	26	others	other	NOUN
eurjchem-2214	170	27	.	.	PUNCT
eurjchem-2214	171	1	however	however	ADV
eurjchem-2214	171	2	,	,	PUNCT
eurjchem-2214	171	3	the	the	DET
eurjchem-2214	171	4	shift	shift	NOUN
eurjchem-2214	171	5	observed	observe	VERB
eurjchem-2214	171	6	in	in	ADP
eurjchem-2214	171	7	nis2p2(4	nis2p2(4	NOUN
eurjchem-2214	171	8	)	)	PUNCT
eurjchem-2214	171	9	chromophore	chromophore	NOUN
eurjchem-2214	171	10	is	be	AUX
eurjchem-2214	171	11	comparable	comparable	ADJ
eurjchem-2214	171	12	to	to	ADP
eurjchem-2214	171	13	that	that	PRON
eurjchem-2214	171	14	observed	observe	VERB
eurjchem-2214	171	15	in	in	ADP
eurjchem-2214	171	16	compound	compound	NOUN
eurjchem-2214	171	17	(	(	PUNCT
eurjchem-2214	171	18	3	3	NUM
eurjchem-2214	171	19	)	)	PUNCT
eurjchem-2214	171	20	.	.	PUNCT
eurjchem-2214	172	1	the	the	DET
eurjchem-2214	172	2	chemical	chemical	ADJ
eurjchem-2214	172	3	shifts	shift	NOUN
eurjchem-2214	172	4	for	for	ADP
eurjchem-2214	172	5	the	the	DET
eurjchem-2214	172	6	nis2pn	nis2pn	NOUN
eurjchem-2214	172	7	chromophores	chromophore	NOUN
eurjchem-2214	172	8	show	show	VERB
eurjchem-2214	172	9	a	a	DET
eurjchem-2214	172	10	highly	highly	ADV
eurjchem-2214	172	11	significant	significant	ADJ
eurjchem-2214	172	12	deshielding	deshielding	NOUN
eurjchem-2214	172	13	to	to	ADP
eurjchem-2214	172	14	the	the	DET
eurjchem-2214	172	15	extent	extent	NOUN
eurjchem-2214	172	16	of	of	ADP
eurjchem-2214	172	17	δ	δ	PROPN
eurjchem-2214	172	18	~25	~25	ADJ
eurjchem-2214	172	19	ppm	ppm	NOUN
eurjchem-2214	172	20	compared	compare	VERB
eurjchem-2214	172	21	to	to	ADP
eurjchem-2214	172	22	the	the	DET
eurjchem-2214	172	23	free	free	ADJ
eurjchem-2214	172	24	ligand	ligand	NOUN
eurjchem-2214	172	25	.	.	PUNCT
eurjchem-2214	173	1	[	[	X
eurjchem-2214	173	2	ni(pyrdtc)(dppe	ni(pyrdtc)(dppe	NOUN
eurjchem-2214	173	3	)	)	PUNCT
eurjchem-2214	173	4	]	]	X
eurjchem-2214	173	5	bph4	bph4	PROPN
eurjchem-2214	173	6	(	(	PUNCT
eurjchem-2214	173	7	5	5	NUM
eurjchem-2214	173	8	)	)	PUNCT
eurjchem-2214	173	9	shows	show	VERB
eurjchem-2214	173	10	a	a	DET
eurjchem-2214	173	11	chemical	chemical	ADJ
eurjchem-2214	173	12	shift	shift	NOUN
eurjchem-2214	173	13	of	of	ADP
eurjchem-2214	173	14	δ	δ	PROPN
eurjchem-2214	173	15	61.5	61.5	NUM
eurjchem-2214	173	16	ppm	ppm	NOUN
eurjchem-2214	173	17	,	,	PUNCT
eurjchem-2214	173	18	which	which	PRON
eurjchem-2214	173	19	indicates	indicate	VERB
eurjchem-2214	173	20	a	a	DET
eurjchem-2214	173	21	significant	significant	ADJ
eurjchem-2214	173	22	chelating	chelating	NOUN
eurjchem-2214	173	23	by	by	ADP
eurjchem-2214	173	24	dppe	dppe	NOUN
eurjchem-2214	173	25	.	.	PUNCT
eurjchem-2214	174	1	3.5	3.5	NUM
eurjchem-2214	174	2	.	.	PUNCT
eurjchem-2214	175	1	single	single	ADJ
eurjchem-2214	175	2	crystal	crystal	PROPN
eurjchem-2214	175	3	x	x	PROPN
eurjchem-2214	175	4	-	-	NOUN
eurjchem-2214	175	5	ray	ray	NOUN
eurjchem-2214	175	6	structure	structure	NOUN
eurjchem-2214	175	7	analysis	analysis	NOUN
eurjchem-2214	175	8	crystal	crystal	NOUN
eurjchem-2214	175	9	data	datum	NOUN
eurjchem-2214	175	10	,	,	PUNCT
eurjchem-2214	175	11	data	data	NOUN
eurjchem-2214	175	12	collection	collection	NOUN
eurjchem-2214	175	13	,	,	PUNCT
eurjchem-2214	175	14	and	and	CCONJ
eurjchem-2214	175	15	refinement	refinement	NOUN
eurjchem-2214	175	16	parameters	parameter	NOUN
eurjchem-2214	175	17	of	of	ADP
eurjchem-2214	175	18	the	the	DET
eurjchem-2214	175	19	complexes	complex	NOUN
eurjchem-2214	175	20	are	be	AUX
eurjchem-2214	175	21	shown	show	VERB
eurjchem-2214	175	22	in	in	ADP
eurjchem-2214	175	23	table	table	NOUN
eurjchem-2214	175	24	1	1	NUM
eurjchem-2214	175	25	.	.	PUNCT
eurjchem-2214	175	26	thermal	thermal	ADJ
eurjchem-2214	175	27	ellipsoid	ellipsoid	NOUN
eurjchem-2214	175	28	plots	plot	NOUN
eurjchem-2214	175	29	of	of	ADP
eurjchem-2214	175	30	the	the	DET
eurjchem-2214	175	31	complexes	complex	NOUN
eurjchem-2214	175	32	are	be	AUX
eurjchem-2214	175	33	shown	show	VERB
eurjchem-2214	175	34	in	in	ADP
eurjchem-2214	175	35	figures	figure	NOUN
eurjchem-2214	175	36	1	1	NUM
eurjchem-2214	175	37	-	-	SYM
eurjchem-2214	175	38	4	4	NUM
eurjchem-2214	175	39	.	.	NUM
eurjchem-2214	175	40	selected	select	VERB
eurjchem-2214	175	41	bond	bond	NOUN
eurjchem-2214	175	42	distances	distance	NOUN
eurjchem-2214	175	43	and	and	CCONJ
eurjchem-2214	175	44	angles	angle	NOUN
eurjchem-2214	175	45	are	be	AUX
eurjchem-2214	175	46	given	give	VERB
eurjchem-2214	175	47	in	in	ADP
eurjchem-2214	175	48	table	table	NOUN
eurjchem-2214	175	49	2	2	NUM
eurjchem-2214	175	50	.	.	PUNCT
eurjchem-2214	176	1	in	in	ADP
eurjchem-2214	176	2	general	general	ADJ
eurjchem-2214	176	3	,	,	PUNCT
eurjchem-2214	176	4	nickel	nickel	NOUN
eurjchem-2214	176	5	atom	atom	NOUN
eurjchem-2214	176	6	is	be	AUX
eurjchem-2214	176	7	approximately	approximately	ADV
eurjchem-2214	176	8	in	in	ADP
eurjchem-2214	176	9	a	a	DET
eurjchem-2214	176	10	square	square	ADJ
eurjchem-2214	176	11	planar	planar	ADJ
eurjchem-2214	176	12	environment	environment	NOUN
eurjchem-2214	176	13	in	in	ADP
eurjchem-2214	176	14	keeping	keep	VERB
eurjchem-2214	176	15	with	with	ADP
eurjchem-2214	176	16	the	the	DET
eurjchem-2214	176	17	observed	observe	VERB
eurjchem-2214	176	18	diamagnetism	diamagnetism	NOUN
eurjchem-2214	176	19	of	of	ADP
eurjchem-2214	176	20	the	the	DET
eurjchem-2214	176	21	complexes	complex	NOUN
eurjchem-2214	176	22	.	.	PUNCT
eurjchem-2214	177	1	perfect	perfect	ADJ
eurjchem-2214	177	2	square	square	ADJ
eurjchem-2214	177	3	planar	planar	ADJ
eurjchem-2214	177	4	geometry	geometry	NOUN
eurjchem-2214	177	5	is	be	AUX
eurjchem-2214	177	6	not	not	PART
eurjchem-2214	177	7	observed	observe	VERB
eurjchem-2214	177	8	in	in	ADP
eurjchem-2214	177	9	the	the	DET
eurjchem-2214	177	10	complexes	complex	NOUN
eurjchem-2214	177	11	because	because	SCONJ
eurjchem-2214	177	12	of	of	ADP
eurjchem-2214	177	13	small	small	ADJ
eurjchem-2214	177	14	bite	bite	NOUN
eurjchem-2214	177	15	angle	angle	NOUN
eurjchem-2214	177	16	associated	associate	VERB
eurjchem-2214	177	17	with	with	ADP
eurjchem-2214	177	18	the	the	DET
eurjchem-2214	177	19	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	ADJ
eurjchem-2214	177	20	anion	anion	NOUN
eurjchem-2214	177	21	.	.	PUNCT
eurjchem-2214	178	1	120	120	NUM
eurjchem-2214	178	2	ramalingam	ramalingam	NOUN
eurjchem-2214	178	3	et	et	PROPN
eurjchem-2214	178	4	al	al	PROPN
eurjchem-2214	178	5	.	.	PUNCT
eurjchem-2214	178	6	/	/	SYM
eurjchem-2214	178	7	european	european	PROPN
eurjchem-2214	178	8	journal	journal	PROPN
eurjchem-2214	178	9	of	of	ADP
eurjchem-2214	178	10	chemistry	chemistry	NOUN
eurjchem-2214	178	11	13	13	NUM
eurjchem-2214	178	12	(	(	PUNCT
eurjchem-2214	178	13	1	1	NUM
eurjchem-2214	178	14	)	)	PUNCT
eurjchem-2214	178	15	(	(	PUNCT
eurjchem-2214	178	16	2022	2022	NUM
eurjchem-2214	178	17	)	)	PUNCT
eurjchem-2214	178	18	117	117	NUM
eurjchem-2214	178	19	-	-	SYM
eurjchem-2214	178	20	125	125	NUM
eurjchem-2214	178	21	2022	2022	NUM
eurjchem-2214	178	22	–	–	PUNCT
eurjchem-2214	178	23	european	european	ADJ
eurjchem-2214	178	24	journal	journal	NOUN
eurjchem-2214	178	25	of	of	ADP
eurjchem-2214	178	26	chemistry	chemistry	NOUN
eurjchem-2214	178	27	–	–	PUNCT
eurjchem-2214	178	28	cc	cc	NOUN
eurjchem-2214	178	29	by	by	ADP
eurjchem-2214	178	30	nc	nc	PROPN
eurjchem-2214	178	31	–	–	PUNCT
eurjchem-2214	178	32	doi	doi	NOUN
eurjchem-2214	178	33	:	:	PUNCT
eurjchem-2214	178	34	10.5155	10.5155	NUM
eurjchem-2214	178	35	/	/	SYM
eurjchem-2214	178	36	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	178	37	-	-	SYM
eurjchem-2214	178	38	125.2214	125.2214	NUM
eurjchem-2214	178	39	table	table	NOUN
eurjchem-2214	178	40	1	1	NUM
eurjchem-2214	178	41	.	.	PUNCT
eurjchem-2214	178	42	crystal	crystal	NOUN
eurjchem-2214	178	43	data	data	PROPN
eurjchem-2214	178	44	,	,	PUNCT
eurjchem-2214	178	45	data	data	NOUN
eurjchem-2214	178	46	collection	collection	NOUN
eurjchem-2214	178	47	,	,	PUNCT
eurjchem-2214	178	48	and	and	CCONJ
eurjchem-2214	178	49	refinement	refinement	NOUN
eurjchem-2214	178	50	parameters	parameter	NOUN
eurjchem-2214	178	51	for	for	ADP
eurjchem-2214	178	52	compounds	compound	NOUN
eurjchem-2214	178	53	1	1	NUM
eurjchem-2214	178	54	-	-	SYM
eurjchem-2214	178	55	4	4	NUM
eurjchem-2214	178	56	.	.	PUNCT
eurjchem-2214	179	1	compound	compound	NOUN
eurjchem-2214	179	2	1	1	NUM
eurjchem-2214	179	3	2	2	NUM
eurjchem-2214	179	4	3	3	NUM
eurjchem-2214	179	5	4	4	NUM
eurjchem-2214	179	6	empirical	empirical	ADJ
eurjchem-2214	179	7	formula	formula	NOUN
eurjchem-2214	179	8	c24h23n2nips3	c24h23n2nips3	PROPN
eurjchem-2214	179	9	c27h29n2	c27h29n2	PROPN
eurjchem-2214	179	10	ni	ni	PROPN
eurjchem-2214	179	11	ps3	ps3	PROPN
eurjchem-2214	179	12	c24h25n2	c24h25n2	PROPN
eurjchem-2214	179	13	ni	ni	PROPN
eurjchem-2214	179	14	ops2	ops2	PROPN
eurjchem-2214	179	15	c41h38clnnio4p2s2	c41h38clnnio4p2s2	PROPN
eurjchem-2214	179	16	formula	formula	NOUN
eurjchem-2214	179	17	weight	weight	NOUN
eurjchem-2214	179	18	525.33	525.33	NUM
eurjchem-2214	179	19	567.38	567.38	NUM
eurjchem-2214	179	20	511.26	511.26	NUM
eurjchem-2214	179	21	828.92	828.92	NUM
eurjchem-2214	179	22	temperature	temperature	NOUN
eurjchem-2214	179	23	(	(	PUNCT
eurjchem-2214	179	24	k	k	NOUN
eurjchem-2214	179	25	)	)	PUNCT
eurjchem-2214	179	26	293(2	293(2	NUM
eurjchem-2214	179	27	)	)	PUNCT
eurjchem-2214	179	28	293(2	293(2	NUM
eurjchem-2214	179	29	)	)	PUNCT
eurjchem-2214	179	30	293(2	293(2	NUM
eurjchem-2214	179	31	)	)	PUNCT
eurjchem-2214	179	32	293	293	NUM
eurjchem-2214	179	33	crystal	crystal	NOUN
eurjchem-2214	179	34	system	system	NOUN
eurjchem-2214	179	35	triclinic	triclinic	ADJ
eurjchem-2214	179	36	monoclinic	monoclinic	ADJ
eurjchem-2214	179	37	triclinic	triclinic	ADJ
eurjchem-2214	179	38	orthorhombic	orthorhombic	NOUN
eurjchem-2214	179	39	space	space	NOUN
eurjchem-2214	179	40	group	group	NOUN
eurjchem-2214	179	41	p-1	p-1	NOUN
eurjchem-2214	179	42	p2111	p2111	PROPN
eurjchem-2214	179	43	p-1	p-1	PROPN
eurjchem-2214	179	44	pbca	pbca	PROPN
eurjchem-2214	179	45	a	a	PRON
eurjchem-2214	179	46	,	,	PUNCT
eurjchem-2214	179	47	(	(	PUNCT
eurjchem-2214	179	48	å	å	NOUN
eurjchem-2214	179	49	)	)	PUNCT
eurjchem-2214	179	50	7.791(2	7.791(2	NUM
eurjchem-2214	179	51	)	)	PUNCT
eurjchem-2214	179	52	10.167(2	10.167(2	PROPN
eurjchem-2214	179	53	)	)	PUNCT
eurjchem-2214	179	54	9.6420(19	9.6420(19	NUM
eurjchem-2214	179	55	)	)	PUNCT
eurjchem-2214	179	56	16.442(2	16.442(2	NOUN
eurjchem-2214	179	57	)	)	PUNCT
eurjchem-2214	179	58	b	b	NOUN
eurjchem-2214	179	59	,	,	PUNCT
eurjchem-2214	179	60	(	(	PUNCT
eurjchem-2214	179	61	å	å	NOUN
eurjchem-2214	179	62	)	)	PUNCT
eurjchem-2214	179	63	11.763(2	11.763(2	NUM
eurjchem-2214	179	64	)	)	PUNCT
eurjchem-2214	179	65	9.906(2	9.906(2	NUM
eurjchem-2214	179	66	)	)	PUNCT
eurjchem-2214	179	67	10.353(2	10.353(2	NUM
eurjchem-2214	179	68	)	)	PUNCT
eurjchem-2214	179	69	21.627(2	21.627(2	NOUN
eurjchem-2214	179	70	)	)	PUNCT
eurjchem-2214	180	1	c	c	X
eurjchem-2214	180	2	,	,	PUNCT
eurjchem-2214	180	3	(	(	PUNCT
eurjchem-2214	180	4	å	å	NOUN
eurjchem-2214	180	5	)	)	PUNCT
eurjchem-2214	180	6	14.283(2	14.283(2	NUM
eurjchem-2214	180	7	)	)	PUNCT
eurjchem-2214	180	8	28.077(2	28.077(2	NOUN
eurjchem-2214	180	9	)	)	PUNCT
eurjchem-2214	180	10	13.925(3	13.925(3	NUM
eurjchem-2214	180	11	)	)	PUNCT
eurjchem-2214	180	12	21.591(2	21.591(2	NOUN
eurjchem-2214	180	13	)	)	PUNCT
eurjchem-2214	181	1	α	α	PROPN
eurjchem-2214	181	2	(	(	PUNCT
eurjchem-2214	181	3	°	°	NOUN
eurjchem-2214	181	4	)	)	PUNCT
eurjchem-2214	181	5	96.86(2	96.86(2	NUM
eurjchem-2214	181	6	)	)	PUNCT
eurjchem-2214	181	7	90	90	NUM
eurjchem-2214	181	8	85.93(3	85.93(3	NOUN
eurjchem-2214	181	9	)	)	PUNCT
eurjchem-2214	181	10	90.00	90.00	NUM
eurjchem-2214	181	11	β	β	X
eurjchem-2214	181	12	(	(	PUNCT
eurjchem-2214	181	13	°	°	PROPN
eurjchem-2214	181	14	)	)	PUNCT
eurjchem-2214	181	15	97.70(3	97.70(3	NUM
eurjchem-2214	181	16	)	)	PUNCT
eurjchem-2214	181	17	97.88(3	97.88(3	NUM
eurjchem-2214	181	18	)	)	PUNCT
eurjchem-2214	181	19	89.14(3	89.14(3	NOUN
eurjchem-2214	181	20	)	)	PUNCT
eurjchem-2214	181	21	90.00	90.00	NUM
eurjchem-2214	181	22	γ	γ	X
eurjchem-2214	181	23	(	(	PUNCT
eurjchem-2214	181	24	°	°	PROPN
eurjchem-2214	181	25	)	)	PUNCT
eurjchem-2214	181	26	105.47(2	105.47(2	NUM
eurjchem-2214	181	27	)	)	PUNCT
eurjchem-2214	181	28	90	90	NUM
eurjchem-2214	181	29	62.63(3	62.63(3	NOUN
eurjchem-2214	181	30	)	)	PUNCT
eurjchem-2214	181	31	90.00	90.00	NUM
eurjchem-2214	181	32	volume	volume	NOUN
eurjchem-2214	181	33	(	(	PUNCT
eurjchem-2214	181	34	å3	å3	PROPN
eurjchem-2214	181	35	)	)	PUNCT
eurjchem-2214	181	36	1233.6(4	1233.6(4	NUM
eurjchem-2214	181	37	)	)	PUNCT
eurjchem-2214	181	38	2801.1(8	2801.1(8	NUM
eurjchem-2214	181	39	)	)	PUNCT
eurjchem-2214	181	40	1231.1(5	1231.1(5	NUM
eurjchem-2214	181	41	)	)	PUNCT
eurjchem-2214	181	42	7677.6(14	7677.6(14	NOUN
eurjchem-2214	181	43	)	)	PUNCT
eurjchem-2214	181	44	z	z	NOUN
eurjchem-2214	181	45	2	2	NUM
eurjchem-2214	181	46	4	4	NUM
eurjchem-2214	181	47	2	2	NUM
eurjchem-2214	181	48	8	8	NUM
eurjchem-2214	181	49	ρcalc(g	ρcalc(g	NOUN
eurjchem-2214	181	50	/	/	SYM
eurjchem-2214	181	51	cm3	cm3	NOUN
eurjchem-2214	181	52	)	)	PUNCT
eurjchem-2214	181	53	1.414	1.414	NUM
eurjchem-2214	181	54	1.345	1.345	NUM
eurjchem-2214	181	55	1.379	1.379	NUM
eurjchem-2214	181	56	1.434	1.434	NUM
eurjchem-2214	181	57	μ	μ	NOUN
eurjchem-2214	181	58	(	(	PUNCT
eurjchem-2214	181	59	mm-1	mm-1	X
eurjchem-2214	181	60	)	)	PUNCT
eurjchem-2214	181	61	1.120	1.120	NUM
eurjchem-2214	181	62	0.992	0.992	NUM
eurjchem-2214	181	63	1.041	1.041	NUM
eurjchem-2214	181	64	0.810	0.810	NUM
eurjchem-2214	181	65	f(000	f(000	NOUN
eurjchem-2214	181	66	)	)	PUNCT
eurjchem-2214	181	67	544.0	544.0	NUM
eurjchem-2214	181	68	1184.0	1184.0	NUM
eurjchem-2214	181	69	532.0	532.0	NUM
eurjchem-2214	181	70	3440.0	3440.0	NUM
eurjchem-2214	181	71	crystal	crystal	NOUN
eurjchem-2214	181	72	size	size	NOUN
eurjchem-2214	181	73	(	(	PUNCT
eurjchem-2214	181	74	mm3	mm3	PROPN
eurjchem-2214	181	75	)	)	PUNCT
eurjchem-2214	181	76	0.34	0.34	NUM
eurjchem-2214	181	77	×	×	NOUN
eurjchem-2214	181	78	0.19	0.19	NUM
eurjchem-2214	181	79	×	×	NOUN
eurjchem-2214	181	80	0.11	0.11	NUM
eurjchem-2214	181	81	0.23×	0.23×	NUM
eurjchem-2214	181	82	0.19	0.19	NUM
eurjchem-2214	181	83	×	×	NOUN
eurjchem-2214	181	84	0.16	0.16	NUM
eurjchem-2214	181	85	0.24	0.24	NUM
eurjchem-2214	181	86	×	×	NOUN
eurjchem-2214	181	87	0.21×	0.21×	NUM
eurjchem-2214	181	88	0.19	0.19	NUM
eurjchem-2214	181	89	0.29	0.29	NUM
eurjchem-2214	181	90	×	×	NOUN
eurjchem-2214	181	91	0.19	0.19	NUM
eurjchem-2214	181	92	×	×	NOUN
eurjchem-2214	181	93	0.15	0.15	NUM
eurjchem-2214	181	94	radiation	radiation	NOUN
eurjchem-2214	181	95	mokα	mokα	NOUN
eurjchem-2214	181	96	(	(	PUNCT
eurjchem-2214	181	97	λ	λ	X
eurjchem-2214	181	98	=	=	SYM
eurjchem-2214	181	99	0.71073	0.71073	NUM
eurjchem-2214	181	100	)	)	PUNCT
eurjchem-2214	181	101	mokα	mokα	NOUN
eurjchem-2214	181	102	(	(	PUNCT
eurjchem-2214	181	103	λ	λ	X
eurjchem-2214	181	104	=	=	SYM
eurjchem-2214	181	105	0.71073	0.71073	NUM
eurjchem-2214	181	106	)	)	PUNCT
eurjchem-2214	181	107	mokα	mokα	NOUN
eurjchem-2214	181	108	(	(	PUNCT
eurjchem-2214	181	109	λ	λ	X
eurjchem-2214	181	110	=	=	SYM
eurjchem-2214	181	111	0.71073	0.71073	NUM
eurjchem-2214	181	112	)	)	PUNCT
eurjchem-2214	181	113	mokα	mokα	NOUN
eurjchem-2214	181	114	(	(	PUNCT
eurjchem-2214	181	115	λ	λ	X
eurjchem-2214	181	116	=	=	SYM
eurjchem-2214	181	117	0.71073	0.71073	NUM
eurjchem-2214	181	118	)	)	PUNCT
eurjchem-2214	181	119	2θ	2θ	NUM
eurjchem-2214	181	120	range	range	VERB
eurjchem-2214	181	121	for	for	ADP
eurjchem-2214	181	122	data	data	NOUN
eurjchem-2214	181	123	collection	collection	NOUN
eurjchem-2214	181	124	(	(	PUNCT
eurjchem-2214	181	125	°	°	PROPN
eurjchem-2214	181	126	)	)	PUNCT
eurjchem-2214	181	127	3.64	3.64	NUM
eurjchem-2214	181	128	to	to	ADP
eurjchem-2214	181	129	56.476	56.476	NUM
eurjchem-2214	181	130	2.928	2.928	NUM
eurjchem-2214	181	131	to	to	ADP
eurjchem-2214	181	132	62.13	62.13	NUM
eurjchem-2214	181	133	2.932	2.932	NUM
eurjchem-2214	181	134	to	to	ADP
eurjchem-2214	181	135	60.84	60.84	NUM
eurjchem-2214	181	136	3.64	3.64	NUM
eurjchem-2214	181	137	to	to	ADP
eurjchem-2214	181	138	56.90	56.90	NUM
eurjchem-2214	181	139	index	index	NOUN
eurjchem-2214	181	140	ranges	range	VERB
eurjchem-2214	181	141	-10	-10	PUNCT
eurjchem-2214	181	142	≤	≤	NUM
eurjchem-2214	181	143	h	h	NOUN
eurjchem-2214	181	144	≤	≤	NUM
eurjchem-2214	181	145	10	10	NUM
eurjchem-2214	181	146	-15	-15	SYM
eurjchem-2214	181	147	≤	≤	NUM
eurjchem-2214	181	148	k	k	NOUN
eurjchem-2214	182	1	≤	≤	NUM
eurjchem-2214	182	2	14	14	NUM
eurjchem-2214	182	3	-18	-18	SYM
eurjchem-2214	182	4	≤	≤	NUM
eurjchem-2214	182	5	l	l	NOUN
eurjchem-2214	182	6	≤	≤	NUM
eurjchem-2214	182	7	17	17	NUM
eurjchem-2214	182	8	-13	-13	SYM
eurjchem-2214	182	9	≤	≤	NUM
eurjchem-2214	182	10	h	h	NOUN
eurjchem-2214	182	11	≤	≤	NOUN
eurjchem-2214	182	12	13	13	NUM
eurjchem-2214	182	13	-13	-13	SYM
eurjchem-2214	182	14	≤	≤	NUM
eurjchem-2214	183	1	k	k	SYM
eurjchem-2214	183	2	≤	≤	NUM
eurjchem-2214	183	3	13	13	NUM
eurjchem-2214	183	4	-35	-35	SYM
eurjchem-2214	183	5	≤	≤	NUM
eurjchem-2214	183	6	l	l	NOUN
eurjchem-2214	183	7	≤	≤	NUM
eurjchem-2214	183	8	35	35	NUM
eurjchem-2214	183	9	-13	-13	SYM
eurjchem-2214	183	10	≤	≤	NUM
eurjchem-2214	183	11	h	h	NOUN
eurjchem-2214	183	12	≤	≤	NOUN
eurjchem-2214	183	13	13	13	NUM
eurjchem-2214	183	14	-14	-14	SYM
eurjchem-2214	183	15	≤	≤	NUM
eurjchem-2214	184	1	k	k	X
eurjchem-2214	185	1	≤	≤	NUM
eurjchem-2214	185	2	14	14	NUM
eurjchem-2214	185	3	-19	-19	SYM
eurjchem-2214	185	4	≤	≤	NUM
eurjchem-2214	185	5	l	l	NOUN
eurjchem-2214	185	6	≤	≤	NUM
eurjchem-2214	185	7	19	19	NUM
eurjchem-2214	185	8	-18	-18	SYM
eurjchem-2214	185	9	≤	≤	NUM
eurjchem-2214	185	10	h	h	NOUN
eurjchem-2214	185	11	≤	≤	NUM
eurjchem-2214	185	12	21	21	NUM
eurjchem-2214	185	13	-21	-21	NOUN
eurjchem-2214	185	14	≤	≤	NUM
eurjchem-2214	185	15	k	k	PROPN
eurjchem-2214	185	16	≤	≤	NUM
eurjchem-2214	185	17	27	27	NUM
eurjchem-2214	185	18	-25	-25	SYM
eurjchem-2214	185	19	≤	≤	NUM
eurjchem-2214	185	20	l	l	NOUN
eurjchem-2214	185	21	≤	≤	NUM
eurjchem-2214	185	22	27	27	NUM
eurjchem-2214	185	23	reflections	reflection	NOUN
eurjchem-2214	185	24	collected	collect	VERB
eurjchem-2214	185	25	13527	13527	NUM
eurjchem-2214	185	26	31234	31234	NUM
eurjchem-2214	185	27	17505	17505	NUM
eurjchem-2214	185	28	45499	45499	NUM
eurjchem-2214	185	29	independent	independent	ADJ
eurjchem-2214	185	30	reflections	reflection	NOUN
eurjchem-2214	185	31	5431	5431	NUM
eurjchem-2214	186	1	[	[	X
eurjchem-2214	186	2	rint	rint	X
eurjchem-2214	186	3	=	=	SYM
eurjchem-2214	186	4	0.0200	0.0200	NUM
eurjchem-2214	186	5	,	,	PUNCT
eurjchem-2214	186	6	rsigma	rsigma	ADJ
eurjchem-2214	186	7	=	=	SYM
eurjchem-2214	186	8	0.0218	0.0218	NUM
eurjchem-2214	186	9	]	]	PUNCT
eurjchem-2214	186	10	12535	12535	NUM
eurjchem-2214	187	1	[	[	X
eurjchem-2214	187	2	rint	rint	X
eurjchem-2214	187	3	=	=	SYM
eurjchem-2214	187	4	0.0497	0.0497	NUM
eurjchem-2214	187	5	,	,	PUNCT
eurjchem-2214	187	6	rsigma	rsigma	ADJ
eurjchem-2214	187	7	=	=	SYM
eurjchem-2214	187	8	0.0522	0.0522	NUM
eurjchem-2214	187	9	]	]	PUNCT
eurjchem-2214	187	10	6676	6676	NUM
eurjchem-2214	188	1	[	[	X
eurjchem-2214	188	2	rint	rint	X
eurjchem-2214	188	3	=	=	SYM
eurjchem-2214	188	4	0.0266	0.0266	NUM
eurjchem-2214	188	5	,	,	PUNCT
eurjchem-2214	188	6	rsigma	rsigma	ADJ
eurjchem-2214	188	7	=	=	SYM
eurjchem-2214	188	8	0.0353	0.0353	NUM
eurjchem-2214	188	9	]	]	PUNCT
eurjchem-2214	188	10	8975	8975	NUM
eurjchem-2214	188	11	[	[	X
eurjchem-2214	188	12	rint	rint	X
eurjchem-2214	188	13	=	=	SYM
eurjchem-2214	188	14	0.1043	0.1043	NUM
eurjchem-2214	188	15	,	,	PUNCT
eurjchem-2214	188	16	rsigma	rsigma	ADJ
eurjchem-2214	188	17	=	=	SYM
eurjchem-2214	188	18	0.2598	0.2598	NUM
eurjchem-2214	188	19	]	]	PUNCT
eurjchem-2214	188	20	data	data	NOUN
eurjchem-2214	188	21	/	/	SYM
eurjchem-2214	188	22	restraints	restraint	NOUN
eurjchem-2214	188	23	/	/	SYM
eurjchem-2214	188	24	parameters	parameter	NOUN
eurjchem-2214	188	25	5431/0/270	5431/0/270	NUM
eurjchem-2214	188	26	12535/1/613	12535/1/613	NUM
eurjchem-2214	188	27	6676/0/288	6676/0/288	NUM
eurjchem-2214	188	28	8975/0/622	8975/0/622	NUM
eurjchem-2214	188	29	goodness	goodness	NOUN
eurjchem-2214	188	30	-	-	PUNCT
eurjchem-2214	188	31	of	of	ADP
eurjchem-2214	188	32	-	-	PUNCT
eurjchem-2214	188	33	fit	fit	NOUN
eurjchem-2214	188	34	on	on	ADP
eurjchem-2214	188	35	f2	f2	PROPN
eurjchem-2214	188	36	1.001	1.001	NUM
eurjchem-2214	188	37	1.004	1.004	NUM
eurjchem-2214	188	38	1.000	1.000	NUM
eurjchem-2214	188	39	0.997	0.997	NUM
eurjchem-2214	188	40	final	final	ADJ
eurjchem-2214	188	41	r	r	NOUN
eurjchem-2214	188	42	indexes	index	NOUN
eurjchem-2214	188	43	[	[	X
eurjchem-2214	188	44	i≥2σ	i≥2σ	X
eurjchem-2214	188	45	(	(	PUNCT
eurjchem-2214	188	46	i	i	NOUN
eurjchem-2214	188	47	)	)	PUNCT
eurjchem-2214	188	48	]	]	PUNCT
eurjchem-2214	189	1	r1	r1	PROPN
eurjchem-2214	189	2	=	=	SYM
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eurjchem-2214	189	4	,	,	PUNCT
eurjchem-2214	189	5	wr2	wr2	PROPN
eurjchem-2214	189	6	=	=	PROPN
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eurjchem-2214	189	8	r1	r1	NOUN
eurjchem-2214	189	9	=	=	PUNCT
eurjchem-2214	189	10	0.0426	0.0426	NUM
eurjchem-2214	189	11	,	,	PUNCT
eurjchem-2214	189	12	wr2	wr2	PROPN
eurjchem-2214	189	13	=	=	PROPN
eurjchem-2214	189	14	0.0968	0.0968	NUM
eurjchem-2214	189	15	r1	r1	NOUN
eurjchem-2214	189	16	=	=	PUNCT
eurjchem-2214	189	17	0.0356	0.0356	NUM
eurjchem-2214	189	18	,	,	PUNCT
eurjchem-2214	189	19	wr2	wr2	PROPN
eurjchem-2214	189	20	=	=	PROPN
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eurjchem-2214	189	22	r1	r1	NOUN
eurjchem-2214	189	23	=	=	PUNCT
eurjchem-2214	189	24	0.0471	0.0471	NUM
eurjchem-2214	189	25	,	,	PUNCT
eurjchem-2214	189	26	wr2	wr2	PROPN
eurjchem-2214	189	27	=	=	NOUN
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eurjchem-2214	189	29	final	final	ADJ
eurjchem-2214	189	30	r	r	NOUN
eurjchem-2214	189	31	indexes	index	NOUN
eurjchem-2214	189	32	[	[	X
eurjchem-2214	189	33	all	all	DET
eurjchem-2214	189	34	data	datum	NOUN
eurjchem-2214	189	35	]	]	PUNCT
eurjchem-2214	189	36	r1	r1	NOUN
eurjchem-2214	189	37	=	=	SYM
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eurjchem-2214	189	39	,	,	PUNCT
eurjchem-2214	189	40	wr2	wr2	PROPN
eurjchem-2214	189	41	=	=	PROPN
eurjchem-2214	189	42	0.1001	0.1001	NUM
eurjchem-2214	189	43	r1	r1	NOUN
eurjchem-2214	189	44	=	=	SYM
eurjchem-2214	189	45	0.0639	0.0639	PROPN
eurjchem-2214	189	46	,	,	PUNCT
eurjchem-2214	189	47	wr2	wr2	PROPN
eurjchem-2214	189	48	=	=	PROPN
eurjchem-2214	189	49	0.1044	0.1044	NUM
eurjchem-2214	189	50	r1	r1	PROPN
eurjchem-2214	189	51	=	=	SYM
eurjchem-2214	189	52	0.0641	0.0641	NUM
eurjchem-2214	189	53	,	,	PUNCT
eurjchem-2214	189	54	wr2	wr2	PROPN
eurjchem-2214	189	55	=	=	PUNCT
eurjchem-2214	189	56	0.0960	0.0960	NUM
eurjchem-2214	189	57	r1	r1	PROPN
eurjchem-2214	189	58	=	=	PUNCT
eurjchem-2214	189	59	0.1992	0.1992	NUM
eurjchem-2214	189	60	,	,	PUNCT
eurjchem-2214	189	61	wr2	wr2	PROPN
eurjchem-2214	189	62	=	=	PROPN
eurjchem-2214	189	63	0.1124	0.1124	NUM
eurjchem-2214	189	64	largest	large	ADJ
eurjchem-2214	189	65	diff	diff	NOUN
eurjchem-2214	189	66	.	.	PUNCT
eurjchem-2214	190	1	peak	peak	PROPN
eurjchem-2214	190	2	/	/	SYM
eurjchem-2214	190	3	hole	hole	NOUN
eurjchem-2214	190	4	(	(	PUNCT
eurjchem-2214	190	5	e.å-3	e.å-3	PROPN
eurjchem-2214	190	6	)	)	PUNCT
eurjchem-2214	190	7	0.67/-0.45	0.67/-0.45	NOUN
eurjchem-2214	190	8	0.56/-0.54	0.56/-0.54	NUM
eurjchem-2214	190	9	0.45/-0.31	0.45/-0.31	NOUN
eurjchem-2214	190	10	0.63/-0.39	0.63/-0.39	NOUN
eurjchem-2214	190	11	flack	flack	ADJ
eurjchem-2214	190	12	parameter	parameter	NOUN
eurjchem-2214	190	13	0.008(7	0.008(7	NOUN
eurjchem-2214	190	14	)	)	PUNCT
eurjchem-2214	190	15	figure	figure	NOUN
eurjchem-2214	190	16	1	1	NUM
eurjchem-2214	190	17	.	.	PUNCT
eurjchem-2214	191	1	ortep	ortep	NOUN
eurjchem-2214	191	2	diagram	diagram	NOUN
eurjchem-2214	191	3	of	of	ADP
eurjchem-2214	191	4	[	[	X
eurjchem-2214	191	5	ni(pyrdtc)(pph3)(ncs	ni(pyrdtc)(pph3)(nc	NOUN
eurjchem-2214	191	6	)	)	PUNCT
eurjchem-2214	191	7	]	]	PUNCT
eurjchem-2214	191	8	(	(	PUNCT
eurjchem-2214	191	9	1	1	NUM
eurjchem-2214	191	10	)	)	PUNCT
eurjchem-2214	191	11	.	.	PUNCT
eurjchem-2214	192	1	angular	angular	ADJ
eurjchem-2214	192	2	disposition	disposition	NOUN
eurjchem-2214	192	3	of	of	ADP
eurjchem-2214	192	4	the	the	DET
eurjchem-2214	192	5	planar	planar	ADJ
eurjchem-2214	192	6	chromophores	chromophore	NOUN
eurjchem-2214	192	7	is	be	AUX
eurjchem-2214	192	8	depicted	depict	VERB
eurjchem-2214	192	9	in	in	ADP
eurjchem-2214	192	10	figure	figure	NOUN
eurjchem-2214	192	11	5	5	NUM
eurjchem-2214	192	12	.	.	PUNCT
eurjchem-2214	193	1	in	in	ADP
eurjchem-2214	193	2	complex	complex	ADJ
eurjchem-2214	193	3	1	1	NUM
eurjchem-2214	193	4	,	,	PUNCT
eurjchem-2214	193	5	the	the	DET
eurjchem-2214	193	6	two	two	NUM
eurjchem-2214	193	7	ni	ni	PROPN
eurjchem-2214	193	8	-	-	PUNCT
eurjchem-2214	193	9	s	s	PART
eurjchem-2214	193	10	distances	distance	NOUN
eurjchem-2214	193	11	are	be	AUX
eurjchem-2214	193	12	unequal	unequal	ADJ
eurjchem-2214	193	13	due	due	ADP
eurjchem-2214	193	14	to	to	ADP
eurjchem-2214	193	15	the	the	DET
eurjchem-2214	193	16	difference	difference	NOUN
eurjchem-2214	193	17	in	in	ADP
eurjchem-2214	193	18	the	the	DET
eurjchem-2214	193	19	trans	tran	NOUN
eurjchem-2214	193	20	influencing	influence	VERB
eurjchem-2214	193	21	property	property	NOUN
eurjchem-2214	193	22	of	of	ADP
eurjchem-2214	193	23	the	the	DET
eurjchem-2214	193	24	ncsand	ncsand	NOUN
eurjchem-2214	193	25	pph3	pph3	NOUN
eurjchem-2214	193	26	groups	group	NOUN
eurjchem-2214	193	27	.	.	PUNCT
eurjchem-2214	194	1	the	the	DET
eurjchem-2214	194	2	pph3	pph3	NOUN
eurjchem-2214	194	3	has	have	VERB
eurjchem-2214	194	4	higher	high	ADJ
eurjchem-2214	194	5	trans	tran	NOUN
eurjchem-2214	194	6	influencing	influence	VERB
eurjchem-2214	194	7	ability	ability	NOUN
eurjchem-2214	194	8	than	than	ADP
eurjchem-2214	194	9	the	the	DET
eurjchem-2214	194	10	ncsgroup	ncsgroup	NOUN
eurjchem-2214	194	11	.	.	PUNCT
eurjchem-2214	195	1	hence	hence	ADV
eurjchem-2214	195	2	the	the	DET
eurjchem-2214	195	3	ni	ni	PROPN
eurjchem-2214	195	4	-	-	PROPN
eurjchem-2214	195	5	s(1	s(1	PROPN
eurjchem-2214	195	6	)	)	PUNCT
eurjchem-2214	195	7	bond	bond	NOUN
eurjchem-2214	195	8	which	which	PRON
eurjchem-2214	195	9	is	be	AUX
eurjchem-2214	195	10	trans	trans	PROPN
eurjchem-2214	195	11	to	to	ADP
eurjchem-2214	195	12	pph3	pph3	PROPN
eurjchem-2214	195	13	is	be	AUX
eurjchem-2214	195	14	longer	long	ADJ
eurjchem-2214	195	15	than	than	ADP
eurjchem-2214	195	16	ni	ni	PROPN
eurjchem-2214	195	17	-	-	PUNCT
eurjchem-2214	195	18	s(2	s(2	NOUN
eurjchem-2214	195	19	)	)	PUNCT
eurjchem-2214	195	20	bond	bond	NOUN
eurjchem-2214	195	21	which	which	PRON
eurjchem-2214	195	22	is	be	AUX
eurjchem-2214	195	23	trans	trans	PROPN
eurjchem-2214	195	24	to	to	ADP
eurjchem-2214	195	25	ncs	ncs	PROPN
eurjchem-2214	195	26	group	group	NOUN
eurjchem-2214	196	1	[	[	X
eurjchem-2214	196	2	ni	ni	PROPN
eurjchem-2214	196	3	-	-	PROPN
eurjchem-2214	196	4	s(1	s(1	PROPN
eurjchem-2214	196	5	):	):	PUNCT
eurjchem-2214	196	6	2.2365(11	2.2365(11	NUM
eurjchem-2214	196	7	)	)	PUNCT
eurjchem-2214	196	8	å	å	PROPN
eurjchem-2214	196	9	,	,	PUNCT
eurjchem-2214	196	10	ni	ni	NOUN
eurjchem-2214	196	11	-	-	PUNCT
eurjchem-2214	196	12	s(2	s(2	PROPN
eurjchem-2214	196	13	):	):	PUNCT
eurjchem-2214	196	14	2.1889(7	2.1889(7	NUM
eurjchem-2214	196	15	)	)	PUNCT
eurjchem-2214	197	1	å	å	X
eurjchem-2214	197	2	]	]	X
eurjchem-2214	197	3	.	.	PUNCT
eurjchem-2214	198	1	the	the	DET
eurjchem-2214	198	2	s	s	PROPN
eurjchem-2214	198	3	-	-	PUNCT
eurjchem-2214	198	4	ni	ni	PROPN
eurjchem-2214	198	5	-	-	PUNCT
eurjchem-2214	198	6	s	s	PART
eurjchem-2214	198	7	angle	angle	NOUN
eurjchem-2214	198	8	is	be	AUX
eurjchem-2214	198	9	78.45(2	78.45(2	NUM
eurjchem-2214	198	10	)	)	PUNCT
eurjchem-2214	198	11	°	°	PROPN
eurjchem-2214	198	12	,	,	PUNCT
eurjchem-2214	198	13	which	which	PRON
eurjchem-2214	198	14	is	be	AUX
eurjchem-2214	198	15	significantly	significantly	ADV
eurjchem-2214	198	16	smaller	small	ADJ
eurjchem-2214	198	17	than	than	ADP
eurjchem-2214	198	18	that	that	PRON
eurjchem-2214	198	19	observed	observe	VERB
eurjchem-2214	198	20	in	in	ADP
eurjchem-2214	198	21	the	the	DET
eurjchem-2214	198	22	parent	parent	NOUN
eurjchem-2214	198	23	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2214	198	24	(	(	PUNCT
eurjchem-2214	198	25	79.33(5	79.33(5	NUM
eurjchem-2214	198	26	)	)	PUNCT
eurjchem-2214	198	27	°	°	NUM
eurjchem-2214	198	28	)	)	PUNCT
eurjchem-2214	199	1	[	[	X
eurjchem-2214	199	2	37	37	NUM
eurjchem-2214	199	3	]	]	PUNCT
eurjchem-2214	199	4	.	.	PUNCT
eurjchem-2214	200	1	delocalization	delocalization	NOUN
eurjchem-2214	200	2	of	of	ADP
eurjchem-2214	200	3	π	π	PROPN
eurjchem-2214	200	4	-	-	NOUN
eurjchem-2214	200	5	electron	electron	NOUN
eurjchem-2214	200	6	density	density	NOUN
eurjchem-2214	200	7	over	over	ADP
eurjchem-2214	200	8	s2cn	s2cn	ADV
eurjchem-2214	201	1	moiety	moiety	NOUN
eurjchem-2214	201	2	is	be	AUX
eurjchem-2214	201	3	evident	evident	ADJ
eurjchem-2214	201	4	from	from	ADP
eurjchem-2214	201	5	the	the	DET
eurjchem-2214	201	6	shortening	shortening	NOUN
eurjchem-2214	201	7	of	of	ADP
eurjchem-2214	201	8	c	c	NOUN
eurjchem-2214	201	9	-	-	PUNCT
eurjchem-2214	201	10	s	s	NOUN
eurjchem-2214	201	11	and	and	CCONJ
eurjchem-2214	201	12	c	c	NOUN
eurjchem-2214	201	13	-	-	PUNCT
eurjchem-2214	201	14	n	n	PRON
eurjchem-2214	201	15	bonds	bond	NOUN
eurjchem-2214	201	16	and	and	CCONJ
eurjchem-2214	201	17	the	the	DET
eurjchem-2214	201	18	ncsgroup	ncsgroup	NOUN
eurjchem-2214	201	19	is	be	AUX
eurjchem-2214	201	20	slightly	slightly	ADV
eurjchem-2214	201	21	bent	bent	ADJ
eurjchem-2214	201	22	towards	towards	ADP
eurjchem-2214	201	23	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	201	24	group	group	NOUN
eurjchem-2214	201	25	.	.	PUNCT
eurjchem-2214	202	1	the	the	DET
eurjchem-2214	202	2	thioureide	thioureide	ADJ
eurjchem-2214	202	3	bond	bond	NOUN
eurjchem-2214	202	4	distance	distance	NOUN
eurjchem-2214	202	5	in	in	ADP
eurjchem-2214	202	6	compound	compound	NOUN
eurjchem-2214	202	7	1	1	NUM
eurjchem-2214	202	8	was	be	AUX
eurjchem-2214	202	9	found	find	VERB
eurjchem-2214	202	10	to	to	PART
eurjchem-2214	202	11	be	be	AUX
eurjchem-2214	202	12	1.303(3	1.303(3	NUM
eurjchem-2214	202	13	)	)	PUNCT
eurjchem-2214	202	14	å	å	NOUN
eurjchem-2214	202	15	.	.	PUNCT
eurjchem-2214	203	1	in	in	ADP
eurjchem-2214	203	2	complex	complex	ADJ
eurjchem-2214	203	3	2	2	NUM
eurjchem-2214	203	4	also	also	ADV
eurjchem-2214	203	5	,	,	PUNCT
eurjchem-2214	203	6	the	the	DET
eurjchem-2214	203	7	two	two	NUM
eurjchem-2214	203	8	ni	ni	PROPN
eurjchem-2214	203	9	-	-	PUNCT
eurjchem-2214	203	10	s	s	PART
eurjchem-2214	203	11	distances	distance	NOUN
eurjchem-2214	203	12	are	be	AUX
eurjchem-2214	203	13	unequal	unequal	ADJ
eurjchem-2214	203	14	due	due	ADP
eurjchem-2214	203	15	to	to	ADP
eurjchem-2214	203	16	the	the	DET
eurjchem-2214	203	17	difference	difference	NOUN
eurjchem-2214	203	18	in	in	ADP
eurjchem-2214	203	19	the	the	DET
eurjchem-2214	203	20	trans	trans	PROPN
eurjchem-2214	203	21	influences	influence	NOUN
eurjchem-2214	203	22	exerted	exert	VERB
eurjchem-2214	203	23	by	by	ADP
eurjchem-2214	203	24	the	the	DET
eurjchem-2214	203	25	tri(4methylphenyl)phosphine(4	tri(4methylphenyl)phosphine(4	PROPN
eurjchem-2214	203	26	-	-	PUNCT
eurjchem-2214	203	27	mp	mp	NOUN
eurjchem-2214	203	28	)	)	PUNCT
eurjchem-2214	203	29	compared	compare	VERB
eurjchem-2214	203	30	to	to	ADP
eurjchem-2214	203	31	ncs-	ncs-	X
eurjchem-2214	203	32	.	.	PUNCT
eurjchem-2214	204	1	the	the	DET
eurjchem-2214	204	2	4	4	NUM
eurjchem-2214	204	3	-	-	PUNCT
eurjchem-2214	204	4	mp	mp	NOUN
eurjchem-2214	204	5	group	group	NOUN
eurjchem-2214	204	6	exerts	exert	VERB
eurjchem-2214	204	7	higher	high	ADJ
eurjchem-2214	204	8	trans	tran	NOUN
eurjchem-2214	204	9	influence	influence	NOUN
eurjchem-2214	204	10	than	than	ADP
eurjchem-2214	204	11	ncsgroup	ncsgroup	NOUN
eurjchem-2214	204	12	and	and	CCONJ
eurjchem-2214	204	13	hence	hence	ADV
eurjchem-2214	204	14	the	the	DET
eurjchem-2214	204	15	two	two	NUM
eurjchem-2214	204	16	ni	ni	PROPN
eurjchem-2214	204	17	-	-	PUNCT
eurjchem-2214	204	18	s	s	PART
eurjchem-2214	204	19	distances	distance	NOUN
eurjchem-2214	204	20	differ	differ	VERB
eurjchem-2214	204	21	significantly	significantly	ADV
eurjchem-2214	204	22	[	[	X
eurjchem-2214	204	23	ni	ni	PROPN
eurjchem-2214	204	24	-	-	PROPN
eurjchem-2214	204	25	s(1	s(1	PROPN
eurjchem-2214	204	26	):	):	PUNCT
eurjchem-2214	204	27	2.2515(16	2.2515(16	NUM
eurjchem-2214	204	28	)	)	PUNCT
eurjchem-2214	204	29	,	,	PUNCT
eurjchem-2214	204	30	ni	ni	NOUN
eurjchem-2214	204	31	-	-	PUNCT
eurjchem-2214	204	32	s(2	s(2	PROPN
eurjchem-2214	204	33	):	):	PUNCT
eurjchem-2214	204	34	2.1756(17	2.1756(17	NUM
eurjchem-2214	204	35	)	)	PUNCT
eurjchem-2214	205	1	å	å	NOUN
eurjchem-2214	205	2	]	]	PUNCT
eurjchem-2214	205	3	as	as	SCONJ
eurjchem-2214	205	4	observed	observe	VERB
eurjchem-2214	205	5	in	in	ADP
eurjchem-2214	205	6	compound	compound	NOUN
eurjchem-2214	205	7	1	1	NUM
eurjchem-2214	205	8	.	.	PUNCT
eurjchem-2214	206	1	the	the	DET
eurjchem-2214	206	2	observed	observed	ADJ
eurjchem-2214	206	3	thioureide	thioureide	NOUN
eurjchem-2214	206	4	distance	distance	NOUN
eurjchem-2214	206	5	1.298(8	1.298(8	NUM
eurjchem-2214	206	6	)	)	PUNCT
eurjchem-2214	206	7	å	å	PROPN
eurjchem-2214	206	8	is	be	AUX
eurjchem-2214	206	9	comparable	comparable	ADJ
eurjchem-2214	206	10	to	to	ADP
eurjchem-2214	206	11	that	that	PRON
eurjchem-2214	206	12	observed	observe	VERB
eurjchem-2214	206	13	in	in	ADP
eurjchem-2214	206	14	compound	compound	NOUN
eurjchem-2214	206	15	1	1	NUM
eurjchem-2214	206	16	.	.	PUNCT
eurjchem-2214	207	1	there	there	PRON
eurjchem-2214	207	2	is	be	VERB
eurjchem-2214	207	3	an	an	DET
eurjchem-2214	207	4	increase	increase	NOUN
eurjchem-2214	207	5	in	in	ADP
eurjchem-2214	207	6	ni	ni	ADJ
eurjchem-2214	207	7	-	-	PROPN
eurjchem-2214	207	8	p	p	ADJ
eurjchem-2214	207	9	distance	distance	NOUN
eurjchem-2214	207	10	due	due	ADP
eurjchem-2214	207	11	to	to	ADP
eurjchem-2214	207	12	the	the	DET
eurjchem-2214	207	13	steric	steric	ADJ
eurjchem-2214	207	14	effect	effect	NOUN
eurjchem-2214	207	15	of	of	ADP
eurjchem-2214	207	16	the	the	DET
eurjchem-2214	207	17	4	4	NUM
eurjchem-2214	207	18	-	-	PUNCT
eurjchem-2214	207	19	methyl	methyl	NOUN
eurjchem-2214	207	20	substituent	substituent	NOUN
eurjchem-2214	207	21	.	.	PUNCT
eurjchem-2214	208	1	then	then	ADV
eurjchem-2214	208	2	-	-	PUNCT
eurjchem-2214	208	3	c	c	ADP
eurjchem-2214	208	4	-	-	PUNCT
eurjchem-2214	208	5	s	s	NOUN
eurjchem-2214	208	6	angles	angle	NOUN
eurjchem-2214	208	7	were	be	AUX
eurjchem-2214	208	8	found	find	VERB
eurjchem-2214	208	9	to	to	PART
eurjchem-2214	208	10	be	be	AUX
eurjchem-2214	208	11	comparable	comparable	ADJ
eurjchem-2214	208	12	(	(	PUNCT
eurjchem-2214	208	13	177.9(8)	177.9(8)	ADJ
eurjchem-2214	208	14	°	°	NOUN
eurjchem-2214	208	15	in	in	ADP
eurjchem-2214	208	16	compound	compound	NOUN
eurjchem-2214	208	17	2	2	NUM
eurjchem-2214	208	18	and	and	CCONJ
eurjchem-2214	208	19	178.1(7	178.1(7	NUM
eurjchem-2214	208	20	)	)	PUNCT
eurjchem-2214	208	21	°	°	NOUN
eurjchem-2214	208	22	in	in	ADP
eurjchem-2214	208	23	compound	compound	NOUN
eurjchem-2214	208	24	1	1	NUM
eurjchem-2214	208	25	)	)	PUNCT
eurjchem-2214	208	26	and	and	CCONJ
eurjchem-2214	208	27	are	be	AUX
eurjchem-2214	208	28	slightly	slightly	ADV
eurjchem-2214	208	29	non	non	ADJ
eurjchem-2214	208	30	-	-	ADJ
eurjchem-2214	208	31	linear	linear	ADJ
eurjchem-2214	208	32	.	.	PUNCT
eurjchem-2214	209	1	however	however	ADV
eurjchem-2214	209	2	,	,	PUNCT
eurjchem-2214	209	3	steric	steric	ADJ
eurjchem-2214	209	4	influence	influence	NOUN
eurjchem-2214	209	5	of	of	ADP
eurjchem-2214	209	6	4	4	NUM
eurjchem-2214	209	7	-	-	PUNCT
eurjchem-2214	209	8	methyl	methyl	NOUN
eurjchem-2214	209	9	group	group	NOUN
eurjchem-2214	209	10	in	in	ADP
eurjchem-2214	209	11	compound	compound	NOUN
eurjchem-2214	209	12	2	2	NUM
eurjchem-2214	209	13	manifests	manifest	VERB
eurjchem-2214	209	14	itself	itself	PRON
eurjchem-2214	209	15	in	in	ADP
eurjchem-2214	209	16	a	a	DET
eurjchem-2214	209	17	highly	highly	ADV
eurjchem-2214	209	18	significant	significant	ADJ
eurjchem-2214	209	19	manner	manner	NOUN
eurjchem-2214	209	20	in	in	ADP
eurjchem-2214	209	21	a	a	DET
eurjchem-2214	209	22	reduced	reduced	ADJ
eurjchem-2214	209	23	nin	nin	NOUN
eurjchem-2214	209	24	-	-	PUNCT
eurjchem-2214	209	25	c(s	c(s	ADJ
eurjchem-2214	209	26	)	)	PUNCT
eurjchem-2214	209	27	angle	angle	NOUN
eurjchem-2214	209	28	equivalent	equivalent	ADJ
eurjchem-2214	209	29	to	to	ADP
eurjchem-2214	209	30	162.4(6	162.4(6	NUM
eurjchem-2214	209	31	)	)	PUNCT
eurjchem-2214	209	32	°	°	PROPN
eurjchem-2214	209	33	compared	compare	VERB
eurjchem-2214	209	34	to	to	ADP
eurjchem-2214	209	35	175.08(19	175.08(19	NUM
eurjchem-2214	209	36	)	)	PUNCT
eurjchem-2214	209	37	°	°	NOUN
eurjchem-2214	209	38	observed	observe	VERB
eurjchem-2214	209	39	in	in	ADP
eurjchem-2214	209	40	compound	compound	NOUN
eurjchem-2214	209	41	1	1	NUM
eurjchem-2214	209	42	.	.	PUNCT
eurjchem-2214	210	1	the	the	DET
eurjchem-2214	210	2	ni	ni	PROPN
eurjchem-2214	210	3	-	-	PUNCT
eurjchem-2214	210	4	s	s	NOUN
eurjchem-2214	210	5	distances	distance	NOUN
eurjchem-2214	210	6	in	in	ADP
eurjchem-2214	210	7	compound	compound	NOUN
eurjchem-2214	210	8	2	2	NUM
eurjchem-2214	210	9	are	be	AUX
eurjchem-2214	210	10	unequal	unequal	ADJ
eurjchem-2214	210	11	as	as	SCONJ
eurjchem-2214	210	12	observed	observe	VERB
eurjchem-2214	210	13	in	in	ADP
eurjchem-2214	210	14	compound	compound	NOUN
eurjchem-2214	210	15	1	1	NUM
eurjchem-2214	210	16	and	and	CCONJ
eurjchem-2214	210	17	the	the	DET
eurjchem-2214	210	18	heterolepticity	heterolepticity	NOUN
eurjchem-2214	210	19	is	be	AUX
eurjchem-2214	210	20	magnified	magnify	VERB
eurjchem-2214	210	21	because	because	SCONJ
eurjchem-2214	210	22	of	of	ADP
eurjchem-2214	210	23	the	the	DET
eurjchem-2214	210	24	trans	trans	PROPN
eurjchem-2214	210	25	influence	influence	NOUN
eurjchem-2214	210	26	of	of	ADP
eurjchem-2214	210	27	the	the	DET
eurjchem-2214	210	28	4	4	NUM
eurjchem-2214	210	29	-	-	PUNCT
eurjchem-2214	210	30	mp	mp	NOUN
eurjchem-2214	210	31	.	.	PUNCT
eurjchem-2214	211	1	a	a	DET
eurjchem-2214	211	2	short	short	ADJ
eurjchem-2214	211	3	thioureide	thioureide	NOUN
eurjchem-2214	211	4	distance	distance	NOUN
eurjchem-2214	211	5	(	(	PUNCT
eurjchem-2214	211	6	1.298(8	1.298(8	NUM
eurjchem-2214	211	7	)	)	PUNCT
eurjchem-2214	211	8	å	å	NOUN
eurjchem-2214	211	9	)	)	PUNCT
eurjchem-2214	211	10	was	be	AUX
eurjchem-2214	211	11	observed	observe	VERB
eurjchem-2214	211	12	and	and	CCONJ
eurjchem-2214	211	13	is	be	AUX
eurjchem-2214	211	14	in	in	ADP
eurjchem-2214	211	15	line	line	NOUN
eurjchem-2214	211	16	with	with	ADP
eurjchem-2214	211	17	the	the	DET
eurjchem-2214	211	18	ir	ir	PROPN
eurjchem-2214	211	19	spectral	spectral	PROPN
eurjchem-2214	211	20	observations	observation	NOUN
eurjchem-2214	211	21	.	.	PUNCT
eurjchem-2214	212	1	in	in	ADP
eurjchem-2214	212	2	compound	compound	NOUN
eurjchem-2214	212	3	3	3	NUM
eurjchem-2214	212	4	,	,	PUNCT
eurjchem-2214	212	5	ni	ni	PROPN
eurjchem-2214	212	6	-	-	PUNCT
eurjchem-2214	212	7	s	s	PART
eurjchem-2214	212	8	distances	distance	NOUN
eurjchem-2214	212	9	are	be	AUX
eurjchem-2214	212	10	asymmetrical	asymmetrical	ADJ
eurjchem-2214	212	11	[	[	X
eurjchem-2214	212	12	ni	ni	PROPN
eurjchem-2214	212	13	-	-	PROPN
eurjchem-2214	212	14	s(1	s(1	PROPN
eurjchem-2214	212	15	):	):	PUNCT
eurjchem-2214	212	16	2.2102(7	2.2102(7	PROPN
eurjchem-2214	212	17	)	)	PUNCT
eurjchem-2214	212	18	;	;	PUNCT
eurjchem-2214	212	19	ni	ni	PROPN
eurjchem-2214	212	20	-	-	PUNCT
eurjchem-2214	212	21	s(2	s(2	PROPN
eurjchem-2214	212	22	):	):	PUNCT
eurjchem-2214	212	23	2.2186(12	2.2186(12	NUM
eurjchem-2214	212	24	)	)	PUNCT
eurjchem-2214	213	1	å	å	NOUN
eurjchem-2214	213	2	]	]	PUNCT
eurjchem-2214	213	3	and	and	CCONJ
eurjchem-2214	213	4	as	as	ADP
eurjchem-2214	213	5	the	the	DET
eurjchem-2214	213	6	cyanide	cyanide	NOUN
eurjchem-2214	213	7	ion	ion	NOUN
eurjchem-2214	213	8	which	which	PRON
eurjchem-2214	213	9	occupies	occupy	VERB
eurjchem-2214	213	10	the	the	DET
eurjchem-2214	213	11	highest	high	ADJ
eurjchem-2214	213	12	position	position	NOUN
eurjchem-2214	213	13	in	in	ADP
eurjchem-2214	213	14	spectrochemical	spectrochemical	ADJ
eurjchem-2214	213	15	series	series	NOUN
eurjchem-2214	213	16	,	,	PUNCT
eurjchem-2214	213	17	influences	influence	VERB
eurjchem-2214	213	18	a	a	DET
eurjchem-2214	213	19	strong	strong	ADJ
eurjchem-2214	213	20	trans	trans	PROPN
eurjchem-2214	213	21	effect	effect	NOUN
eurjchem-2214	213	22	.	.	PUNCT
eurjchem-2214	214	1	the	the	DET
eurjchem-2214	214	2	nic(n	nic(n	NOUN
eurjchem-2214	214	3	)	)	PUNCT
eurjchem-2214	214	4	distance	distance	NOUN
eurjchem-2214	214	5	was	be	AUX
eurjchem-2214	214	6	found	find	VERB
eurjchem-2214	214	7	to	to	PART
eurjchem-2214	214	8	be	be	AUX
eurjchem-2214	214	9	1.857(2)å	1.857(2)å	NUM
eurjchem-2214	214	10	.	.	PUNCT
eurjchem-2214	215	1	the	the	DET
eurjchem-2214	215	2	p	p	PROPN
eurjchem-2214	215	3	-	-	PUNCT
eurjchem-2214	215	4	ni	ni	PROPN
eurjchem-2214	215	5	-	-	PUNCT
eurjchem-2214	215	6	s	s	PART
eurjchem-2214	215	7	angle	angle	NOUN
eurjchem-2214	215	8	was	be	AUX
eurjchem-2214	215	9	175.95(2	175.95(2	NUM
eurjchem-2214	215	10	)	)	PUNCT
eurjchem-2214	215	11	°	°	NOUN
eurjchem-2214	215	12	,	,	PUNCT
eurjchem-2214	215	13	which	which	PRON
eurjchem-2214	215	14	indicates	indicate	VERB
eurjchem-2214	215	15	near	near	ADP
eurjchem-2214	215	16	linearity	linearity	NOUN
eurjchem-2214	215	17	.	.	PUNCT
eurjchem-2214	216	1	the	the	DET
eurjchem-2214	216	2	p	p	PROPN
eurjchem-2214	216	3	-	-	PUNCT
eurjchem-2214	216	4	ni	ni	PROPN
eurjchem-2214	216	5	-	-	PUNCT
eurjchem-2214	216	6	c	c	PROPN
eurjchem-2214	216	7	angle	angle	NOUN
eurjchem-2214	216	8	was	be	AUX
eurjchem-2214	216	9	found	find	VERB
eurjchem-2214	216	10	to	to	PART
eurjchem-2214	216	11	be	be	AUX
eurjchem-2214	216	12	91.90(7)	91.90(7)	NUM
eurjchem-2214	216	13	°	°	NUM
eurjchem-2214	216	14	.	.	PUNCT
eurjchem-2214	217	1	the	the	DET
eurjchem-2214	217	2	thioureide	thioureide	ADJ
eurjchem-2214	217	3	distance	distance	NOUN
eurjchem-2214	217	4	was	be	AUX
eurjchem-2214	217	5	observed	observe	VERB
eurjchem-2214	217	6	to	to	PART
eurjchem-2214	217	7	be	be	AUX
eurjchem-2214	217	8	,	,	PUNCT
eurjchem-2214	217	9	1.298(3	1.298(3	NUM
eurjchem-2214	217	10	)	)	PUNCT
eurjchem-2214	217	11	å	å	PROPN
eurjchem-2214	217	12	.	.	PUNCT
eurjchem-2214	217	13	ramalingam	ramalingam	NOUN
eurjchem-2214	217	14	et	et	PROPN
eurjchem-2214	217	15	al	al	PROPN
eurjchem-2214	217	16	.	.	PUNCT
eurjchem-2214	217	17	/	/	SYM
eurjchem-2214	217	18	european	european	PROPN
eurjchem-2214	217	19	journal	journal	PROPN
eurjchem-2214	217	20	of	of	ADP
eurjchem-2214	217	21	chemistry	chemistry	NOUN
eurjchem-2214	217	22	13	13	NUM
eurjchem-2214	217	23	(	(	PUNCT
eurjchem-2214	217	24	1	1	NUM
eurjchem-2214	217	25	)	)	PUNCT
eurjchem-2214	217	26	(	(	PUNCT
eurjchem-2214	217	27	2022	2022	NUM
eurjchem-2214	217	28	)	)	PUNCT
eurjchem-2214	217	29	117	117	NUM
eurjchem-2214	217	30	-	-	SYM
eurjchem-2214	217	31	125	125	NUM
eurjchem-2214	217	32	121	121	NUM
eurjchem-2214	217	33	2022	2022	NUM
eurjchem-2214	217	34	–	–	PUNCT
eurjchem-2214	217	35	european	european	ADJ
eurjchem-2214	217	36	journal	journal	NOUN
eurjchem-2214	217	37	of	of	ADP
eurjchem-2214	217	38	chemistry	chemistry	NOUN
eurjchem-2214	217	39	–	–	PUNCT
eurjchem-2214	217	40	cc	cc	NOUN
eurjchem-2214	217	41	by	by	ADP
eurjchem-2214	217	42	nc	nc	PROPN
eurjchem-2214	217	43	–	–	PUNCT
eurjchem-2214	217	44	doi	doi	NOUN
eurjchem-2214	217	45	:	:	PUNCT
eurjchem-2214	217	46	10.5155	10.5155	NUM
eurjchem-2214	217	47	/	/	SYM
eurjchem-2214	217	48	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	217	49	-	-	SYM
eurjchem-2214	217	50	125.2214	125.2214	NUM
eurjchem-2214	217	51	table	table	NOUN
eurjchem-2214	217	52	2	2	NUM
eurjchem-2214	217	53	.	.	NUM
eurjchem-2214	217	54	selected	select	VERB
eurjchem-2214	217	55	bond	bond	NOUN
eurjchem-2214	217	56	distances	distance	NOUN
eurjchem-2214	217	57	(	(	PUNCT
eurjchem-2214	217	58	å	å	NOUN
eurjchem-2214	217	59	)	)	PUNCT
eurjchem-2214	217	60	and	and	CCONJ
eurjchem-2214	217	61	angles	angle	NOUN
eurjchem-2214	217	62	(	(	PUNCT
eurjchem-2214	217	63	°	°	NUM
eurjchem-2214	217	64	)	)	PUNCT
eurjchem-2214	217	65	.	.	PUNCT
eurjchem-2214	218	1	compound	compound	VERB
eurjchem-2214	218	2	ni	ni	PROPN
eurjchem-2214	218	3	-	-	PROPN
eurjchem-2214	218	4	s(1	s(1	PROPN
eurjchem-2214	218	5	)	)	PUNCT
eurjchem-2214	218	6	,	,	PUNCT
eurjchem-2214	218	7	ni	ni	PROPN
eurjchem-2214	218	8	-	-	PUNCT
eurjchem-2214	218	9	s(2	s(2	NOUN
eurjchem-2214	218	10	)	)	PUNCT
eurjchem-2214	218	11	ni	ni	PROPN
eurjchem-2214	218	12	-	-	PROPN
eurjchem-2214	218	13	p	p	PROPN
eurjchem-2214	218	14	ni	ni	PROPN
eurjchem-2214	218	15	-	-	PUNCT
eurjchem-2214	218	16	n	n	CCONJ
eurjchem-2214	218	17	/	/	SYM
eurjchem-2214	218	18	ni	ni	PROPN
eurjchem-2214	218	19	-	-	PUNCT
eurjchem-2214	218	20	c	c	NOUN
eurjchem-2214	218	21	/	/	SYM
eurjchem-2214	218	22	ni	ni	NOUN
eurjchem-2214	218	23	-	-	PROPN
eurjchem-2214	218	24	p	p	ADJ
eurjchem-2214	218	25	c	c	NOUN
eurjchem-2214	218	26	-	-	PUNCT
eurjchem-2214	218	27	n	n	PRON
eurjchem-2214	218	28	s(1)-ni	s(1)-ni	PROPN
eurjchem-2214	218	29	-	-	PUNCT
eurjchem-2214	218	30	s(2	s(2	NOUN
eurjchem-2214	218	31	)	)	PUNCT
eurjchem-2214	218	32	p	p	PROPN
eurjchem-2214	218	33	-	-	PUNCT
eurjchem-2214	218	34	ni	ni	NOUN
eurjchem-2214	218	35	-	-	PROPN
eurjchem-2214	218	36	p	p	X
eurjchem-2214	218	37	/	/	SYM
eurjchem-2214	218	38	c	c	NOUN
eurjchem-2214	218	39	/	/	SYM
eurjchem-2214	218	40	n	n	PROPN
eurjchem-2214	218	41	1	1	NUM
eurjchem-2214	218	42	2.2365(11	2.2365(11	NUM
eurjchem-2214	218	43	)	)	PUNCT
eurjchem-2214	218	44	,	,	PUNCT
eurjchem-2214	218	45	2.1889(7	2.1889(7	NUM
eurjchem-2214	218	46	)	)	PUNCT
eurjchem-2214	218	47	2.2087(10	2.2087(10	NUM
eurjchem-2214	218	48	)	)	PUNCT
eurjchem-2214	218	49	1.862(2	1.862(2	NUM
eurjchem-2214	218	50	)	)	PUNCT
eurjchem-2214	218	51	1.303(3	1.303(3	NUM
eurjchem-2214	218	52	)	)	PUNCT
eurjchem-2214	218	53	78.45(3	78.45(3	ADJ
eurjchem-2214	218	54	)	)	PUNCT
eurjchem-2214	218	55	95.03(7	95.03(7	NOUN
eurjchem-2214	218	56	)	)	PUNCT
eurjchem-2214	218	57	2	2	NUM
eurjchem-2214	218	58	#	#	NOUN
eurjchem-2214	218	59	2.2515(16	2.2515(16	NUM
eurjchem-2214	218	60	)	)	PUNCT
eurjchem-2214	218	61	,	,	PUNCT
eurjchem-2214	218	62	2.1756(17	2.1756(17	NUM
eurjchem-2214	218	63	)	)	PUNCT
eurjchem-2214	218	64	2.2459(15	2.2459(15	NUM
eurjchem-2214	218	65	)	)	PUNCT
eurjchem-2214	218	66	1.820(5	1.820(5	NUM
eurjchem-2214	218	67	)	)	PUNCT
eurjchem-2214	218	68	1.259(7	1.259(7	NUM
eurjchem-2214	218	69	)	)	PUNCT
eurjchem-2214	218	70	77.46(6	77.46(6	NUM
eurjchem-2214	218	71	)	)	PUNCT
eurjchem-2214	218	72	90.61(16	90.61(16	NUM
eurjchem-2214	218	73	)	)	PUNCT
eurjchem-2214	218	74	3	3	NUM
eurjchem-2214	218	75	2.2186(12	2.2186(12	NUM
eurjchem-2214	218	76	)	)	PUNCT
eurjchem-2214	218	77	,	,	PUNCT
eurjchem-2214	218	78	2.2102(7	2.2102(7	NUM
eurjchem-2214	218	79	)	)	PUNCT
eurjchem-2214	218	80	2.1956(11	2.1956(11	NUM
eurjchem-2214	218	81	)	)	PUNCT
eurjchem-2214	218	82	1.857(2	1.857(2	NUM
eurjchem-2214	218	83	)	)	PUNCT
eurjchem-2214	218	84	1.298(3	1.298(3	NUM
eurjchem-2214	218	85	)	)	PUNCT
eurjchem-2214	218	86	79.01(3	79.01(3	NUM
eurjchem-2214	218	87	)	)	PUNCT
eurjchem-2214	218	88	91.90(7	91.90(7	NOUN
eurjchem-2214	218	89	)	)	PUNCT
eurjchem-2214	218	90	4	4	NUM
eurjchem-2214	218	91	2.2250(15	2.2250(15	NUM
eurjchem-2214	218	92	)	)	PUNCT
eurjchem-2214	218	93	,	,	PUNCT
eurjchem-2214	218	94	2.2002(15	2.2002(15	NUM
eurjchem-2214	218	95	)	)	PUNCT
eurjchem-2214	218	96	2.2076(15	2.2076(15	NUM
eurjchem-2214	218	97	)	)	PUNCT
eurjchem-2214	218	98	2.2268(14	2.2268(14	NUM
eurjchem-2214	218	99	)	)	PUNCT
eurjchem-2214	218	100	1.302(6	1.302(6	NUM
eurjchem-2214	218	101	)	)	PUNCT
eurjchem-2214	218	102	78.38(5	78.38(5	NOUN
eurjchem-2214	218	103	)	)	PUNCT
eurjchem-2214	218	104	99.66(5	99.66(5	NOUN
eurjchem-2214	218	105	)	)	PUNCT
eurjchem-2214	218	106	5	5	NUM
eurjchem-2214	218	107	2.228(3	2.228(3	NUM
eurjchem-2214	218	108	)	)	PUNCT
eurjchem-2214	218	109	,	,	PUNCT
eurjchem-2214	218	110	2.223(3	2.223(3	NUM
eurjchem-2214	218	111	)	)	PUNCT
eurjchem-2214	218	112	2.171(3	2.171(3	NUM
eurjchem-2214	218	113	)	)	PUNCT
eurjchem-2214	218	114	2.178(3	2.178(3	NUM
eurjchem-2214	218	115	)	)	PUNCT
eurjchem-2214	218	116	1.314(12	1.314(12	NUM
eurjchem-2214	218	117	)	)	PUNCT
eurjchem-2214	219	1	79.57(12	79.57(12	NUM
eurjchem-2214	219	2	)	)	PUNCT
eurjchem-2214	219	3	86.55(1	86.55(1	NOUN
eurjchem-2214	219	4	)	)	PUNCT
eurjchem-2214	220	1	[	[	X
eurjchem-2214	220	2	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	220	3	]	]	X
eurjchem-2214	220	4	*	*	PUNCT
eurjchem-2214	220	5	2.214(1	2.214(1	NUM
eurjchem-2214	220	6	)	)	PUNCT
eurjchem-2214	220	7	,	,	PUNCT
eurjchem-2214	220	8	2.198(1	2.198(1	NUM
eurjchem-2214	220	9	)	)	PUNCT
eurjchem-2214	220	10	1.311(4	1.311(4	NUM
eurjchem-2214	220	11	)	)	PUNCT
eurjchem-2214	220	12	79.33(5	79.33(5	NUM
eurjchem-2214	220	13	)	)	PUNCT
eurjchem-2214	220	14	*	*	VERB
eurjchem-2214	220	15	reference	reference	NOUN
eurjchem-2214	220	16	[	[	X
eurjchem-2214	220	17	37	37	NUM
eurjchem-2214	220	18	]	]	PUNCT
eurjchem-2214	220	19	.	.	PUNCT
eurjchem-2214	221	1	#	#	NOUN
eurjchem-2214	221	2	bond	bond	NOUN
eurjchem-2214	221	3	parameters	parameter	NOUN
eurjchem-2214	221	4	of	of	ADP
eurjchem-2214	221	5	one	one	NUM
eurjchem-2214	221	6	of	of	ADP
eurjchem-2214	221	7	the	the	DET
eurjchem-2214	221	8	two	two	NUM
eurjchem-2214	221	9	asymmetric	asymmetric	ADJ
eurjchem-2214	221	10	units	unit	NOUN
eurjchem-2214	221	11	(	(	PUNCT
eurjchem-2214	221	12	unprimed	unprimed	ADJ
eurjchem-2214	221	13	)	)	PUNCT
eurjchem-2214	221	14	are	be	AUX
eurjchem-2214	221	15	listed	list	VERB
eurjchem-2214	221	16	.	.	PUNCT
eurjchem-2214	222	1	figure	figure	NOUN
eurjchem-2214	222	2	2	2	NUM
eurjchem-2214	222	3	.	.	PUNCT
eurjchem-2214	222	4	ortep	ortep	NOUN
eurjchem-2214	222	5	diagram	diagram	NOUN
eurjchem-2214	222	6	of	of	ADP
eurjchem-2214	222	7	[	[	X
eurjchem-2214	222	8	ni(pyrdtc)(4	ni(pyrdtc)(4	NOUN
eurjchem-2214	222	9	-	-	PUNCT
eurjchem-2214	222	10	mp)(ncs	mp)(nc	NOUN
eurjchem-2214	222	11	)	)	PUNCT
eurjchem-2214	222	12	]	]	PUNCT
eurjchem-2214	222	13	(	(	PUNCT
eurjchem-2214	222	14	2	2	NUM
eurjchem-2214	222	15	)	)	PUNCT
eurjchem-2214	222	16	.	.	PUNCT
eurjchem-2214	223	1	figure	figure	VERB
eurjchem-2214	223	2	3	3	NUM
eurjchem-2214	223	3	.	.	PUNCT
eurjchem-2214	223	4	ortep	ortep	NOUN
eurjchem-2214	223	5	diagram	diagram	NOUN
eurjchem-2214	223	6	of	of	ADP
eurjchem-2214	223	7	[	[	X
eurjchem-2214	223	8	ni(pyrdtc)(pph3)(cn)].h2o	ni(pyrdtc)(pph3)(cn)].h2o	NOUN
eurjchem-2214	223	9	(	(	PUNCT
eurjchem-2214	223	10	3	3	NUM
eurjchem-2214	223	11	)	)	PUNCT
eurjchem-2214	223	12	.	.	PUNCT
eurjchem-2214	224	1	water	water	NOUN
eurjchem-2214	224	2	molecule	molecule	NOUN
eurjchem-2214	224	3	are	be	AUX
eurjchem-2214	224	4	not	not	PART
eurjchem-2214	224	5	included	include	VERB
eurjchem-2214	224	6	.	.	PUNCT
eurjchem-2214	225	1	in	in	ADP
eurjchem-2214	225	2	complex	complex	ADJ
eurjchem-2214	225	3	4	4	NUM
eurjchem-2214	225	4	,	,	PUNCT
eurjchem-2214	225	5	the	the	DET
eurjchem-2214	225	6	ni	ni	PROPN
eurjchem-2214	225	7	-	-	PUNCT
eurjchem-2214	225	8	s	s	PROPN
eurjchem-2214	225	9	and	and	CCONJ
eurjchem-2214	225	10	ni	ni	PROPN
eurjchem-2214	225	11	-	-	PROPN
eurjchem-2214	225	12	p	p	PROPN
eurjchem-2214	225	13	distances	distance	NOUN
eurjchem-2214	225	14	trans	tran	NOUN
eurjchem-2214	225	15	to	to	ADP
eurjchem-2214	225	16	each	each	DET
eurjchem-2214	225	17	other	other	ADJ
eurjchem-2214	225	18	show	show	VERB
eurjchem-2214	225	19	a	a	DET
eurjchem-2214	225	20	balancing	balancing	NOUN
eurjchem-2214	225	21	trend	trend	NOUN
eurjchem-2214	225	22	with	with	ADP
eurjchem-2214	225	23	longer	long	ADJ
eurjchem-2214	225	24	ni	ni	PROPN
eurjchem-2214	225	25	-	-	PUNCT
eurjchem-2214	225	26	s	s	PROPN
eurjchem-2214	225	27	bond	bond	NOUN
eurjchem-2214	225	28	trans	tran	NOUN
eurjchem-2214	225	29	to	to	ADP
eurjchem-2214	225	30	short	short	ADJ
eurjchem-2214	225	31	nip	nip	NOUN
eurjchem-2214	225	32	bond	bond	NOUN
eurjchem-2214	225	33	distance	distance	NOUN
eurjchem-2214	225	34	in	in	ADP
eurjchem-2214	225	35	the	the	DET
eurjchem-2214	225	36	molecule	molecule	NOUN
eurjchem-2214	225	37	and	and	CCONJ
eurjchem-2214	225	38	vice	vice	NOUN
eurjchem-2214	225	39	-	-	NOUN
eurjchem-2214	225	40	versa	versa	NOUN
eurjchem-2214	225	41	.	.	PUNCT
eurjchem-2214	226	1	the	the	DET
eurjchem-2214	226	2	thioureide	thioureide	ADJ
eurjchem-2214	226	3	distance	distance	NOUN
eurjchem-2214	226	4	was	be	AUX
eurjchem-2214	226	5	found	find	VERB
eurjchem-2214	226	6	to	to	PART
eurjchem-2214	226	7	be	be	AUX
eurjchem-2214	226	8	1.302(6	1.302(6	NUM
eurjchem-2214	226	9	)	)	PUNCT
eurjchem-2214	226	10	å	å	NOUN
eurjchem-2214	226	11	.	.	PUNCT
eurjchem-2214	227	1	the	the	DET
eurjchem-2214	227	2	s	s	PROPN
eurjchem-2214	227	3	-	-	PUNCT
eurjchem-2214	227	4	ni	ni	PROPN
eurjchem-2214	227	5	-	-	PUNCT
eurjchem-2214	227	6	s	s	PART
eurjchem-2214	227	7	angle	angle	NOUN
eurjchem-2214	227	8	was	be	AUX
eurjchem-2214	227	9	found	find	VERB
eurjchem-2214	227	10	to	to	PART
eurjchem-2214	227	11	be	be	AUX
eurjchem-2214	227	12	78.38(5	78.38(5	NOUN
eurjchem-2214	227	13	)	)	PUNCT
eurjchem-2214	227	14	°	°	NOUN
eurjchem-2214	228	1	and	and	CCONJ
eurjchem-2214	228	2	the	the	DET
eurjchem-2214	228	3	p	p	PROPN
eurjchem-2214	228	4	-	-	PUNCT
eurjchem-2214	228	5	ni	ni	NOUN
eurjchem-2214	228	6	-	-	ADJ
eurjchem-2214	228	7	p	p	NOUN
eurjchem-2214	228	8	angle	angle	NOUN
eurjchem-2214	228	9	was	be	AUX
eurjchem-2214	228	10	found	find	VERB
eurjchem-2214	228	11	to	to	PART
eurjchem-2214	228	12	be	be	AUX
eurjchem-2214	228	13	99.66(5)	99.66(5)	NUM
eurjchem-2214	228	14	°	°	PROPN
eurjchem-2214	228	15	.	.	PUNCT
eurjchem-2214	229	1	the	the	DET
eurjchem-2214	229	2	perchlorate	perchlorate	NOUN
eurjchem-2214	229	3	anion	anion	NOUN
eurjchem-2214	229	4	was	be	AUX
eurjchem-2214	229	5	found	find	VERB
eurjchem-2214	229	6	to	to	PART
eurjchem-2214	229	7	be	be	AUX
eurjchem-2214	229	8	distorted	distort	VERB
eurjchem-2214	229	9	from	from	ADP
eurjchem-2214	229	10	tetrahedral	tetrahedral	ADJ
eurjchem-2214	229	11	geometry	geometry	NOUN
eurjchem-2214	229	12	.	.	PUNCT
eurjchem-2214	230	1	in	in	ADP
eurjchem-2214	230	2	complex	complex	ADJ
eurjchem-2214	230	3	5	5	NUM
eurjchem-2214	230	4	,	,	PUNCT
eurjchem-2214	230	5	two	two	NUM
eurjchem-2214	230	6	water	water	NOUN
eurjchem-2214	230	7	molecules	molecule	NOUN
eurjchem-2214	230	8	cocrystallized	cocrystallize	VERB
eurjchem-2214	230	9	with	with	ADP
eurjchem-2214	230	10	the	the	DET
eurjchem-2214	230	11	molecule	molecule	NOUN
eurjchem-2214	230	12	and	and	CCONJ
eurjchem-2214	230	13	the	the	DET
eurjchem-2214	230	14	crystals	crystal	NOUN
eurjchem-2214	230	15	obtained	obtain	VERB
eurjchem-2214	230	16	were	be	AUX
eurjchem-2214	230	17	of	of	ADP
eurjchem-2214	230	18	poor	poor	ADJ
eurjchem-2214	230	19	crystallinity	crystallinity	NOUN
eurjchem-2214	230	20	.	.	PUNCT
eurjchem-2214	231	1	however	however	ADV
eurjchem-2214	231	2	,	,	PUNCT
eurjchem-2214	231	3	the	the	DET
eurjchem-2214	231	4	ni	ni	PROPN
eurjchem-2214	231	5	-	-	PUNCT
eurjchem-2214	231	6	s	s	PROPN
eurjchem-2214	231	7	,	,	PUNCT
eurjchem-2214	231	8	ni	ni	PROPN
eurjchem-2214	231	9	-	-	PROPN
eurjchem-2214	231	10	p	p	X
eurjchem-2214	231	11	,	,	PUNCT
eurjchem-2214	231	12	and	and	CCONJ
eurjchem-2214	231	13	c	c	X
eurjchem-2214	231	14	-	-	PUNCT
eurjchem-2214	231	15	n	n	NOUN
eurjchem-2214	231	16	distances	distance	NOUN
eurjchem-2214	231	17	from	from	ADP
eurjchem-2214	231	18	the	the	DET
eurjchem-2214	231	19	structure	structure	NOUN
eurjchem-2214	231	20	solution	solution	NOUN
eurjchem-2214	231	21	are	be	AUX
eurjchem-2214	231	22	considered	consider	VERB
eurjchem-2214	231	23	for	for	ADP
eurjchem-2214	231	24	the	the	DET
eurjchem-2214	231	25	sake	sake	NOUN
eurjchem-2214	231	26	of	of	ADP
eurjchem-2214	231	27	comparison	comparison	NOUN
eurjchem-2214	231	28	with	with	ADP
eurjchem-2214	231	29	the	the	DET
eurjchem-2214	231	30	other	other	ADJ
eurjchem-2214	231	31	four	four	NUM
eurjchem-2214	231	32	compounds	compound	NOUN
eurjchem-2214	231	33	.	.	PUNCT
eurjchem-2214	232	1	the	the	DET
eurjchem-2214	232	2	ni	ni	PROPN
eurjchem-2214	232	3	-	-	PUNCT
eurjchem-2214	232	4	s	s	NOUN
eurjchem-2214	232	5	bond	bond	NOUN
eurjchem-2214	232	6	distances	distance	NOUN
eurjchem-2214	232	7	are	be	AUX
eurjchem-2214	232	8	almost	almost	ADV
eurjchem-2214	232	9	similar	similar	ADJ
eurjchem-2214	232	10	[	[	X
eurjchem-2214	232	11	ni	ni	NOUN
eurjchem-2214	232	12	-	-	PUNCT
eurjchem-2214	232	13	s	s	NOUN
eurjchem-2214	232	14	:	:	PUNCT
eurjchem-2214	232	15	2.228(3)-2.223(3	2.228(3)-2.223(3	NUM
eurjchem-2214	232	16	)	)	PUNCT
eurjchem-2214	232	17	å	å	NOUN
eurjchem-2214	232	18	]	]	PUNCT
eurjchem-2214	232	19	and	and	CCONJ
eurjchem-2214	232	20	the	the	DET
eurjchem-2214	232	21	s	s	PROPN
eurjchem-2214	232	22	-	-	PUNCT
eurjchem-2214	232	23	ni	ni	PROPN
eurjchem-2214	232	24	-	-	PUNCT
eurjchem-2214	232	25	s	s	PART
eurjchem-2214	232	26	bite	bite	NOUN
eurjchem-2214	232	27	angle	angle	NOUN
eurjchem-2214	232	28	of	of	ADP
eurjchem-2214	232	29	the	the	DET
eurjchem-2214	232	30	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2214	232	31	was	be	AUX
eurjchem-2214	232	32	found	find	VERB
eurjchem-2214	232	33	to	to	PART
eurjchem-2214	232	34	be	be	AUX
eurjchem-2214	232	35	79.57(12)	79.57(12)	NOUN
eurjchem-2214	232	36	°	°	NUM
eurjchem-2214	232	37	.	.	PUNCT
eurjchem-2214	233	1	short	short	PROPN
eurjchem-2214	233	2	ni	ni	PROPN
eurjchem-2214	233	3	-	-	PROPN
eurjchem-2214	233	4	p	p	ADJ
eurjchem-2214	233	5	bond	bond	NOUN
eurjchem-2214	233	6	distances	distance	NOUN
eurjchem-2214	233	7	observed	observe	VERB
eurjchem-2214	233	8	in	in	ADP
eurjchem-2214	233	9	the	the	DET
eurjchem-2214	233	10	dppe	dppe	NOUN
eurjchem-2214	233	11	compared	compare	VERB
eurjchem-2214	233	12	to	to	ADP
eurjchem-2214	233	13	those	those	PRON
eurjchem-2214	233	14	of	of	ADP
eurjchem-2214	233	15	its	its	PRON
eurjchem-2214	233	16	pph3	pph3	NOUN
eurjchem-2214	233	17	analogue	analogue	NOUN
eurjchem-2214	233	18	is	be	AUX
eurjchem-2214	233	19	due	due	ADJ
eurjchem-2214	233	20	to	to	ADP
eurjchem-2214	233	21	the	the	DET
eurjchem-2214	233	22	chelating	chelate	VERB
eurjchem-2214	233	23	nature	nature	NOUN
eurjchem-2214	233	24	of	of	ADP
eurjchem-2214	233	25	the	the	DET
eurjchem-2214	233	26	dppe	dppe	PROPN
eurjchem-2214	233	27	ligand	ligand	AUX
eurjchem-2214	233	28	.	.	PUNCT
eurjchem-2214	234	1	the	the	DET
eurjchem-2214	234	2	thioureide	thioureide	ADJ
eurjchem-2214	234	3	bond	bond	NOUN
eurjchem-2214	234	4	distance	distance	NOUN
eurjchem-2214	234	5	is	be	AUX
eurjchem-2214	234	6	1.314(12	1.314(12	NUM
eurjchem-2214	234	7	)	)	PUNCT
eurjchem-2214	235	1	å	å	NOUN
eurjchem-2214	235	2	.	.	PUNCT
eurjchem-2214	236	1	the	the	DET
eurjchem-2214	236	2	two	two	NUM
eurjchem-2214	236	3	ni	ni	PROPN
eurjchem-2214	236	4	-	-	PUNCT
eurjchem-2214	236	5	s	s	PART
eurjchem-2214	236	6	distances	distance	NOUN
eurjchem-2214	236	7	are	be	AUX
eurjchem-2214	236	8	longer	long	ADJ
eurjchem-2214	236	9	than	than	ADP
eurjchem-2214	236	10	the	the	DET
eurjchem-2214	236	11	distances	distance	NOUN
eurjchem-2214	236	12	observed	observe	VERB
eurjchem-2214	236	13	in	in	ADP
eurjchem-2214	236	14	other	other	ADJ
eurjchem-2214	236	15	similar	similar	ADJ
eurjchem-2214	236	16	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2214	236	17	.	.	PUNCT
eurjchem-2214	237	1	the	the	DET
eurjchem-2214	237	2	two	two	NUM
eurjchem-2214	237	3	ni	ni	PROPN
eurjchem-2214	237	4	-	-	PUNCT
eurjchem-2214	237	5	p	p	ADJ
eurjchem-2214	237	6	distances	distance	NOUN
eurjchem-2214	237	7	[	[	X
eurjchem-2214	237	8	2.171(3	2.171(3	NUM
eurjchem-2214	237	9	)	)	PUNCT
eurjchem-2214	237	10	and	and	CCONJ
eurjchem-2214	237	11	2.178(3	2.178(3	NUM
eurjchem-2214	237	12	)	)	PUNCT
eurjchem-2214	237	13	å	å	NOUN
eurjchem-2214	237	14	]	]	X
eurjchem-2214	237	15	are	be	AUX
eurjchem-2214	237	16	relatively	relatively	ADV
eurjchem-2214	237	17	very	very	ADV
eurjchem-2214	237	18	short	short	ADJ
eurjchem-2214	237	19	and	and	CCONJ
eurjchem-2214	237	20	are	be	AUX
eurjchem-2214	237	21	almost	almost	ADV
eurjchem-2214	237	22	equal	equal	ADJ
eurjchem-2214	237	23	considering	consider	VERB
eurjchem-2214	237	24	the	the	DET
eurjchem-2214	237	25	respective	respective	ADJ
eurjchem-2214	237	26	esd	esd	NOUN
eurjchem-2214	237	27	’s	’s	PART
eurjchem-2214	237	28	.	.	PUNCT
eurjchem-2214	238	1	the	the	DET
eurjchem-2214	238	2	p	p	PROPN
eurjchem-2214	238	3	-	-	PUNCT
eurjchem-2214	238	4	ni	ni	NOUN
eurjchem-2214	238	5	-	-	ADJ
eurjchem-2214	238	6	p	p	NOUN
eurjchem-2214	238	7	angle	angle	NOUN
eurjchem-2214	238	8	is	be	AUX
eurjchem-2214	238	9	lower	low	ADJ
eurjchem-2214	238	10	than	than	ADP
eurjchem-2214	238	11	that	that	PRON
eurjchem-2214	238	12	observed	observe	VERB
eurjchem-2214	238	13	in	in	ADP
eurjchem-2214	238	14	complex	complex	ADJ
eurjchem-2214	238	15	4	4	NUM
eurjchem-2214	238	16	because	because	SCONJ
eurjchem-2214	238	17	of	of	ADP
eurjchem-2214	238	18	the	the	DET
eurjchem-2214	238	19	chelating	chelate	VERB
eurjchem-2214	238	20	nature	nature	NOUN
eurjchem-2214	238	21	of	of	ADP
eurjchem-2214	238	22	dppe	dppe	PROPN
eurjchem-2214	238	23	.	.	PUNCT
eurjchem-2214	239	1	from	from	ADP
eurjchem-2214	239	2	tables	table	NOUN
eurjchem-2214	239	3	2	2	NUM
eurjchem-2214	239	4	and	and	CCONJ
eurjchem-2214	239	5	3	3	NUM
eurjchem-2214	239	6	,	,	PUNCT
eurjchem-2214	239	7	maximum	maximum	ADJ
eurjchem-2214	239	8	deviation	deviation	NOUN
eurjchem-2214	239	9	of	of	ADP
eurjchem-2214	239	10	nickel	nickel	NOUN
eurjchem-2214	239	11	atom	atom	NOUN
eurjchem-2214	239	12	from	from	ADP
eurjchem-2214	239	13	the	the	DET
eurjchem-2214	239	14	planar	planar	ADJ
eurjchem-2214	239	15	square	square	ADJ
eurjchem-2214	239	16	chromophores	chromophore	NOUN
eurjchem-2214	239	17	is	be	AUX
eurjchem-2214	239	18	observed	observe	VERB
eurjchem-2214	239	19	in	in	ADP
eurjchem-2214	239	20	compound	compound	NOUN
eurjchem-2214	239	21	1	1	NUM
eurjchem-2214	239	22	.	.	PUNCT
eurjchem-2214	240	1	ni	ni	PROPN
eurjchem-2214	240	2	-	-	PUNCT
eurjchem-2214	240	3	s	s	PROPN
eurjchem-2214	240	4	bond	bond	NOUN
eurjchem-2214	240	5	distances	distance	NOUN
eurjchem-2214	240	6	in	in	ADP
eurjchem-2214	240	7	the	the	DET
eurjchem-2214	240	8	complexes	complex	NOUN
eurjchem-2214	240	9	1	1	NUM
eurjchem-2214	240	10	-	-	SYM
eurjchem-2214	240	11	4	4	NUM
eurjchem-2214	240	12	are	be	AUX
eurjchem-2214	240	13	affected	affect	VERB
eurjchem-2214	240	14	to	to	ADP
eurjchem-2214	240	15	a	a	DET
eurjchem-2214	240	16	larger	large	ADJ
eurjchem-2214	240	17	extent	extent	NOUN
eurjchem-2214	240	18	by	by	ADP
eurjchem-2214	240	19	trans	tran	NOUN
eurjchem-2214	240	20	influence	influence	NOUN
eurjchem-2214	240	21	and	and	CCONJ
eurjchem-2214	240	22	the	the	DET
eurjchem-2214	240	23	steric	steric	ADJ
eurjchem-2214	240	24	effect	effect	NOUN
eurjchem-2214	240	25	of	of	ADP
eurjchem-2214	240	26	the	the	DET
eurjchem-2214	240	27	substituted	substitute	VERB
eurjchem-2214	240	28	phosphines	phosphine	NOUN
eurjchem-2214	240	29	in	in	ADP
eurjchem-2214	240	30	the	the	DET
eurjchem-2214	240	31	coordination	coordination	NOUN
eurjchem-2214	240	32	environment	environment	NOUN
eurjchem-2214	240	33	.	.	PUNCT
eurjchem-2214	241	1	it	it	PRON
eurjchem-2214	241	2	is	be	AUX
eurjchem-2214	241	3	noteworthy	noteworthy	ADJ
eurjchem-2214	241	4	that	that	SCONJ
eurjchem-2214	241	5	the	the	DET
eurjchem-2214	241	6	s	s	PROPN
eurjchem-2214	241	7	-	-	PUNCT
eurjchem-2214	241	8	ni	ni	PROPN
eurjchem-2214	241	9	-	-	PUNCT
eurjchem-2214	241	10	s	s	NOUN
eurjchem-2214	241	11	angles	angle	NOUN
eurjchem-2214	241	12	of	of	ADP
eurjchem-2214	241	13	all	all	PRON
eurjchem-2214	241	14	are	be	AUX
eurjchem-2214	241	15	close	close	ADJ
eurjchem-2214	241	16	to	to	ADP
eurjchem-2214	241	17	that	that	PRON
eurjchem-2214	241	18	observed	observe	VERB
eurjchem-2214	241	19	in	in	ADP
eurjchem-2214	241	20	the	the	DET
eurjchem-2214	241	21	parent	parent	NOUN
eurjchem-2214	241	22	bisdithiocarbamate	bisdithiocarbamate	NOUN
eurjchem-2214	241	23	(	(	PUNCT
eurjchem-2214	241	24	79.33(5	79.33(5	NUM
eurjchem-2214	241	25	)	)	PUNCT
eurjchem-2214	241	26	°	°	NOUN
eurjchem-2214	242	1	[	[	X
eurjchem-2214	242	2	37	37	NUM
eurjchem-2214	242	3	]	]	NUM
eurjchem-2214	242	4	)	)	PUNCT
eurjchem-2214	242	5	.	.	PUNCT
eurjchem-2214	243	1	compounds	compound	VERB
eurjchem-2214	243	2	1	1	NUM
eurjchem-2214	243	3	-	-	SYM
eurjchem-2214	243	4	4	4	NUM
eurjchem-2214	243	5	contain	contain	NOUN
eurjchem-2214	243	6	monodentate	monodentate	NOUN
eurjchem-2214	243	7	phosphines	phosphine	NOUN
eurjchem-2214	243	8	,	,	PUNCT
eurjchem-2214	243	9	thiocyanate	thiocyanate	NOUN
eurjchem-2214	243	10	or	or	CCONJ
eurjchem-2214	243	11	cyanide	cyanide	NOUN
eurjchem-2214	243	12	besides	besides	SCONJ
eurjchem-2214	243	13	the	the	DET
eurjchem-2214	243	14	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	ADJ
eurjchem-2214	243	15	anion	anion	NOUN
eurjchem-2214	243	16	.	.	PUNCT
eurjchem-2214	244	1	structurally	structurally	ADV
eurjchem-2214	244	2	,	,	PUNCT
eurjchem-2214	244	3	a	a	DET
eurjchem-2214	244	4	clear	clear	ADJ
eurjchem-2214	244	5	heterolepticity	heterolepticity	NOUN
eurjchem-2214	244	6	in	in	ADP
eurjchem-2214	244	7	bonding	bonding	NOUN
eurjchem-2214	244	8	is	be	AUX
eurjchem-2214	244	9	observed	observe	VERB
eurjchem-2214	244	10	in	in	ADP
eurjchem-2214	244	11	ms	ms	PROPN
eurjchem-2214	244	12	distances	distance	NOUN
eurjchem-2214	244	13	(	(	PUNCT
eurjchem-2214	244	14	mean	mean	NOUN
eurjchem-2214	244	15	:	:	PUNCT
eurjchem-2214	244	16	short	short	ADJ
eurjchem-2214	244	17	m	m	PROPN
eurjchem-2214	244	18	-	-	PUNCT
eurjchem-2214	244	19	s	s	PART
eurjchem-2214	244	20	distance	distance	NOUN
eurjchem-2214	244	21	:	:	PUNCT
eurjchem-2214	244	22	2.1937(11	2.1937(11	NUM
eurjchem-2214	244	23	)	)	PUNCT
eurjchem-2214	244	24	;	;	PUNCT
eurjchem-2214	244	25	long	long	ADJ
eurjchem-2214	244	26	distance	distance	NOUN
eurjchem-2214	244	27	:	:	PUNCT
eurjchem-2214	244	28	2.2329(13	2.2329(13	NUM
eurjchem-2214	244	29	)	)	PUNCT
eurjchem-2214	244	30	å	å	NOUN
eurjchem-2214	244	31	)	)	PUNCT
eurjchem-2214	244	32	.	.	PUNCT
eurjchem-2214	245	1	mean	mean	VERB
eurjchem-2214	245	2	ni	ni	PROPN
eurjchem-2214	245	3	-	-	PROPN
eurjchem-2214	245	4	p	p	ADJ
eurjchem-2214	245	5	distance	distance	NOUN
eurjchem-2214	245	6	in	in	ADP
eurjchem-2214	245	7	the	the	DET
eurjchem-2214	245	8	reported	report	VERB
eurjchem-2214	245	9	compounds	compound	NOUN
eurjchem-2214	245	10	is	be	AUX
eurjchem-2214	245	11	2.2144(13	2.2144(13	NUM
eurjchem-2214	245	12	)	)	PUNCT
eurjchem-2214	246	1	å	å	NOUN
eurjchem-2214	246	2	.	.	PUNCT
eurjchem-2214	247	1	interestingly	interestingly	ADV
eurjchem-2214	247	2	,	,	PUNCT
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eurjchem-2214	247	4	mean	mean	ADJ
eurjchem-2214	247	5	s	s	NOUN
eurjchem-2214	247	6	-	-	PUNCT
eurjchem-2214	247	7	ni	ni	PROPN
eurjchem-2214	247	8	-	-	PUNCT
eurjchem-2214	247	9	s	s	PART
eurjchem-2214	247	10	angle	angle	NOUN
eurjchem-2214	247	11	observed	observe	VERB
eurjchem-2214	247	12	in	in	ADP
eurjchem-2214	247	13	compounds	compound	NOUN
eurjchem-2214	247	14	1	1	NUM
eurjchem-2214	247	15	-	-	SYM
eurjchem-2214	247	16	6	6	NUM
eurjchem-2214	247	17	is	be	AUX
eurjchem-2214	247	18	78.70(7	78.70(7	NUM
eurjchem-2214	247	19	)	)	PUNCT
eurjchem-2214	247	20	°	°	NOUN
eurjchem-2214	247	21	,	,	PUNCT
eurjchem-2214	247	22	which	which	PRON
eurjchem-2214	247	23	is	be	AUX
eurjchem-2214	247	24	signifycantly	signifycantly	ADV
eurjchem-2214	247	25	less	less	ADJ
eurjchem-2214	247	26	than	than	ADP
eurjchem-2214	247	27	the	the	DET
eurjchem-2214	247	28	ideal	ideal	ADJ
eurjchem-2214	247	29	right	right	ADJ
eurjchem-2214	247	30	angle	angle	NOUN
eurjchem-2214	247	31	.	.	PUNCT
eurjchem-2214	248	1	trans-[nicl2(pph3)2	trans-[nicl2(pph3)2	PROPN
eurjchem-2214	248	2	]	]	X
eurjchem-2214	248	3	·	·	PUNCT
eurjchem-2214	249	1	2ch2cl2	2ch2cl2	NUM
eurjchem-2214	249	2	[	[	X
eurjchem-2214	249	3	38	38	NUM
eurjchem-2214	249	4	]	]	PUNCT
eurjchem-2214	249	5	shows	show	VERB
eurjchem-2214	249	6	an	an	DET
eurjchem-2214	249	7	ni	ni	PROPN
eurjchem-2214	249	8	-	-	PROPN
eurjchem-2214	249	9	p	p	ADJ
eurjchem-2214	249	10	distance	distance	NOUN
eurjchem-2214	249	11	of	of	ADP
eurjchem-2214	249	12	2.2439(5	2.2439(5	NOUN
eurjchem-2214	249	13	)	)	PUNCT
eurjchem-2214	249	14	å	å	PROPN
eurjchem-2214	249	15	and	and	CCONJ
eurjchem-2214	249	16	its	its	PRON
eurjchem-2214	249	17	tetrahedral	tetrahedral	ADJ
eurjchem-2214	249	18	analogue	analogue	NOUN
eurjchem-2214	249	19	[	[	X
eurjchem-2214	249	20	nicl2(pph3)2	nicl2(pph3)2	NOUN
eurjchem-2214	249	21	]	]	X
eurjchem-2214	250	1	[	[	X
eurjchem-2214	250	2	39	39	NUM
eurjchem-2214	250	3	]	]	PUNCT
eurjchem-2214	250	4	shows	show	VERB
eurjchem-2214	250	5	a	a	DET
eurjchem-2214	250	6	relatively	relatively	ADV
eurjchem-2214	250	7	longer	long	ADJ
eurjchem-2214	250	8	ni	ni	ADJ
eurjchem-2214	250	9	-	-	PROPN
eurjchem-2214	250	10	p	p	ADJ
eurjchem-2214	250	11	distance	distance	NOUN
eurjchem-2214	250	12	of	of	ADP
eurjchem-2214	250	13	2.3180(2	2.3180(2	NUM
eurjchem-2214	250	14	)	)	PUNCT
eurjchem-2214	251	1	å	å	NOUN
eurjchem-2214	251	2	.	.	NOUN
eurjchem-2214	251	3	122	122	NUM
eurjchem-2214	251	4	ramalingam	ramalingam	NOUN
eurjchem-2214	251	5	et	et	PROPN
eurjchem-2214	251	6	al	al	PROPN
eurjchem-2214	251	7	.	.	PUNCT
eurjchem-2214	251	8	/	/	SYM
eurjchem-2214	251	9	european	european	PROPN
eurjchem-2214	251	10	journal	journal	PROPN
eurjchem-2214	251	11	of	of	ADP
eurjchem-2214	251	12	chemistry	chemistry	NOUN
eurjchem-2214	251	13	13	13	NUM
eurjchem-2214	251	14	(	(	PUNCT
eurjchem-2214	251	15	1	1	NUM
eurjchem-2214	251	16	)	)	PUNCT
eurjchem-2214	251	17	(	(	PUNCT
eurjchem-2214	251	18	2022	2022	NUM
eurjchem-2214	251	19	)	)	PUNCT
eurjchem-2214	251	20	117	117	NUM
eurjchem-2214	251	21	-	-	SYM
eurjchem-2214	251	22	125	125	NUM
eurjchem-2214	251	23	2022	2022	NUM
eurjchem-2214	251	24	–	–	PUNCT
eurjchem-2214	251	25	european	european	ADJ
eurjchem-2214	251	26	journal	journal	NOUN
eurjchem-2214	251	27	of	of	ADP
eurjchem-2214	251	28	chemistry	chemistry	NOUN
eurjchem-2214	251	29	–	–	PUNCT
eurjchem-2214	251	30	cc	cc	NOUN
eurjchem-2214	251	31	by	by	ADP
eurjchem-2214	251	32	nc	nc	PROPN
eurjchem-2214	251	33	–	–	PUNCT
eurjchem-2214	251	34	doi	doi	NOUN
eurjchem-2214	251	35	:	:	PUNCT
eurjchem-2214	251	36	10.5155	10.5155	NUM
eurjchem-2214	251	37	/	/	SYM
eurjchem-2214	251	38	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	251	39	-	-	SYM
eurjchem-2214	251	40	125.2214	125.2214	NUM
eurjchem-2214	251	41	table	table	NOUN
eurjchem-2214	251	42	3	3	NUM
eurjchem-2214	251	43	.	.	PUNCT
eurjchem-2214	251	44	bond	bond	NOUN
eurjchem-2214	251	45	valence	valence	NOUN
eurjchem-2214	251	46	sum	sum	NOUN
eurjchem-2214	251	47	of	of	ADP
eurjchem-2214	251	48	nickel	nickel	NOUN
eurjchem-2214	251	49	atom	atom	NOUN
eurjchem-2214	251	50	and	and	CCONJ
eurjchem-2214	251	51	its	its	PRON
eurjchem-2214	251	52	deviation	deviation	NOUN
eurjchem-2214	251	53	from	from	ADP
eurjchem-2214	251	54	the	the	DET
eurjchem-2214	251	55	planes	plane	NOUN
eurjchem-2214	251	56	.	.	PUNCT
eurjchem-2214	252	1	compound	compound	PROPN
eurjchem-2214	252	2	vij	vij	PROPN
eurjchem-2214	252	3	*	*	PUNCT
eurjchem-2214	252	4	maximum	maximum	ADJ
eurjchem-2214	252	5	deviation	deviation	NOUN
eurjchem-2214	252	6	(	(	PUNCT
eurjchem-2214	252	7	å	å	NOUN
eurjchem-2214	252	8	)	)	PUNCT
eurjchem-2214	252	9	of	of	ADP
eurjchem-2214	252	10	atoms	atom	NOUN
eurjchem-2214	252	11	from	from	ADP
eurjchem-2214	252	12	s	s	PROPN
eurjchem-2214	252	13	�	�	PROPN
eurjchem-2214	252	14	spn	spn	PROPN
eurjchem-2214	252	15	/	/	SYM
eurjchem-2214	252	16	s	s	PROPN
eurjchem-2214	252	17	�	�	PROPN
eurjchem-2214	252	18	spc	spc	PROPN
eurjchem-2214	252	19	/	/	SYM
eurjchem-2214	252	20	s	s	PROPN
eurjchem-2214	252	21	�	�	ADP
eurjchem-2214	252	22	spp/	spp/	PROPN
eurjchem-2214	252	23	s	s	PROPN
eurjchem-2214	252	24	�	�	PROPN
eurjchem-2214	252	25	sp	sp	NOUN
eurjchem-2214	252	26	�	�	NOUN
eurjchem-2214	252	27	p/	p/	NOUN
eurjchem-2214	252	28	s	s	PART
eurjchem-2214	252	29	�	�	PROPN
eurjchem-2214	252	30	ss	ss	NOUN
eurjchem-2214	252	31	�	�	PROPN
eurjchem-2214	252	32	s	s	PART
eurjchem-2214	252	33	planes	plane	NOUN
eurjchem-2214	252	34	maximum	maximum	ADJ
eurjchem-2214	252	35	deviation	deviation	NOUN
eurjchem-2214	252	36	(	(	PUNCT
eurjchem-2214	252	37	å	å	NOUN
eurjchem-2214	252	38	)	)	PUNCT
eurjchem-2214	252	39	of	of	ADP
eurjchem-2214	252	40	nickel	nickel	NOUN
eurjchem-2214	252	41	from	from	ADP
eurjchem-2214	252	42	s	s	PROPN
eurjchem-2214	252	43	�	�	PROPN
eurjchem-2214	252	44	spn	spn	PROPN
eurjchem-2214	252	45	/	/	SYM
eurjchem-2214	252	46	s	s	PROPN
eurjchem-2214	252	47	�	�	PROPN
eurjchem-2214	252	48	spc	spc	PROPN
eurjchem-2214	252	49	/	/	SYM
eurjchem-2214	252	50	s	s	PROPN
eurjchem-2214	252	51	�	�	ADP
eurjchem-2214	252	52	spp/	spp/	PROPN
eurjchem-2214	252	53	s	s	PROPN
eurjchem-2214	252	54	�	�	PROPN
eurjchem-2214	252	55	sp	sp	NOUN
eurjchem-2214	252	56	�	�	NOUN
eurjchem-2214	252	57	p/	p/	NOUN
eurjchem-2214	252	58	s	s	PART
eurjchem-2214	252	59	�	�	PROPN
eurjchem-2214	252	60	ss	ss	NOUN
eurjchem-2214	252	61	�	�	PROPN
eurjchem-2214	252	62	s	s	PART
eurjchem-2214	252	63	planes	plane	NOUN
eurjchem-2214	252	64	[	[	X
eurjchem-2214	252	65	ni(pyrdtc)(pph3)(ncs	ni(pyrdtc)(pph3)(ncs	NOUN
eurjchem-2214	252	66	)	)	PUNCT
eurjchem-2214	252	67	]	]	PUNCT
eurjchem-2214	252	68	(	(	PUNCT
eurjchem-2214	252	69	1	1	X
eurjchem-2214	252	70	)	)	PUNCT
eurjchem-2214	252	71	2.040	2.040	NUM
eurjchem-2214	252	72	0.0751	0.0751	NUM
eurjchem-2214	252	73	0.0682	0.0682	NUM
eurjchem-2214	252	74	[	[	X
eurjchem-2214	252	75	ni(pyrdtc)(4	ni(pyrdtc)(4	NOUN
eurjchem-2214	252	76	-	-	PUNCT
eurjchem-2214	252	77	mp)(ncs	mp)(nc	NOUN
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eurjchem-2214	252	80	(	(	PUNCT
eurjchem-2214	252	81	2	2	X
eurjchem-2214	252	82	)	)	PUNCT
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eurjchem-2214	253	1	[	[	X
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eurjchem-2214	253	3	(	(	PUNCT
eurjchem-2214	253	4	3	3	NUM
eurjchem-2214	253	5	)	)	PUNCT
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eurjchem-2214	253	9	[	[	PUNCT
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eurjchem-2214	253	12	4	4	NUM
eurjchem-2214	253	13	)	)	PUNCT
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eurjchem-2214	253	17	[	[	X
eurjchem-2214	253	18	ni(pyrdtc)(dppe)]·bph4(5	ni(pyrdtc)(dppe)]·bph4(5	X
eurjchem-2214	253	19	)	)	PUNCT
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eurjchem-2214	253	23	[	[	PUNCT
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eurjchem-2214	253	25	(	(	PUNCT
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eurjchem-2214	253	27	)	)	PUNCT
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eurjchem-2214	253	44	[	[	X
eurjchem-2214	253	45	44	44	NUM
eurjchem-2214	253	46	-	-	SYM
eurjchem-2214	253	47	46	46	NUM
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eurjchem-2214	253	49	.	.	PUNCT
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eurjchem-2214	254	4	-	-	PROPN
eurjchem-2214	254	5	c	c	PROPN
eurjchem-2214	254	6	(	(	PUNCT
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eurjchem-2214	254	14	(	(	PUNCT
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eurjchem-2214	254	24	experimental	experimental	ADJ
eurjchem-2214	254	25	bond	bond	NOUN
eurjchem-2214	254	26	distances	distance	NOUN
eurjchem-2214	254	27	for	for	ADP
eurjchem-2214	254	28	twenty	twenty	NUM
eurjchem-2214	254	29	complexes	complex	NOUN
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eurjchem-2214	254	35	central	central	ADJ
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eurjchem-2214	255	1	‡	‡	PUNCT
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eurjchem-2214	256	2	parameters	parameter	NOUN
eurjchem-2214	256	3	are	be	AUX
eurjchem-2214	256	4	from	from	ADP
eurjchem-2214	256	5	reference	reference	NOUN
eurjchem-2214	256	6	[	[	X
eurjchem-2214	256	7	37	37	NUM
eurjchem-2214	256	8	]	]	PUNCT
eurjchem-2214	256	9	.	.	PUNCT
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eurjchem-2214	258	4	[	[	X
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eurjchem-2214	258	6	(	(	PUNCT
eurjchem-2214	258	7	4	4	NUM
eurjchem-2214	258	8	)	)	PUNCT
eurjchem-2214	258	9	.	.	PUNCT
eurjchem-2214	259	1	the	the	DET
eurjchem-2214	259	2	perchlorate	perchlorate	NOUN
eurjchem-2214	259	3	anion	anion	NOUN
eurjchem-2214	259	4	is	be	AUX
eurjchem-2214	259	5	not	not	PART
eurjchem-2214	259	6	included	include	VERB
eurjchem-2214	259	7	.	.	PUNCT
eurjchem-2214	260	1	ni	ni	ADJ
eurjchem-2214	260	2	-	-	PUNCT
eurjchem-2214	260	3	cl	cl	NOUN
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eurjchem-2214	260	5	in	in	ADP
eurjchem-2214	260	6	the	the	DET
eurjchem-2214	260	7	tetrahedral	tetrahedral	ADJ
eurjchem-2214	260	8	compounds	compound	NOUN
eurjchem-2214	260	9	are	be	AUX
eurjchem-2214	260	10	longer	long	ADJ
eurjchem-2214	260	11	than	than	ADP
eurjchem-2214	260	12	that	that	PRON
eurjchem-2214	260	13	observed	observe	VERB
eurjchem-2214	260	14	in	in	ADP
eurjchem-2214	260	15	the	the	DET
eurjchem-2214	260	16	planar	planar	ADJ
eurjchem-2214	260	17	form	form	NOUN
eurjchem-2214	260	18	(	(	PUNCT
eurjchem-2214	260	19	tetrahedral	tetrahedral	ADJ
eurjchem-2214	260	20	:	:	PUNCT
eurjchem-2214	260	21	2.2075(4	2.2075(4	NOUN
eurjchem-2214	260	22	)	)	PUNCT
eurjchem-2214	260	23	å	å	NOUN
eurjchem-2214	260	24	;	;	PUNCT
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eurjchem-2214	260	26	square	square	NOUN
eurjchem-2214	260	27	:	:	PUNCT
eurjchem-2214	260	28	2.1672(5	2.1672(5	NUM
eurjchem-2214	260	29	)	)	PUNCT
eurjchem-2214	260	30	å	å	NOUN
eurjchem-2214	260	31	)	)	PUNCT
eurjchem-2214	260	32	.	.	PUNCT
eurjchem-2214	261	1	p	p	X
eurjchem-2214	261	2	-	-	PUNCT
eurjchem-2214	261	3	ni	ni	ADJ
eurjchem-2214	261	4	-	-	PUNCT
eurjchem-2214	261	5	cl	cl	NOUN
eurjchem-2214	261	6	angle	angle	NOUN
eurjchem-2214	261	7	in	in	ADP
eurjchem-2214	261	8	the	the	DET
eurjchem-2214	261	9	planar	planar	PROPN
eurjchem-2214	261	10	square	square	ADJ
eurjchem-2214	261	11	trans-[nicl2(pph3)2]·2ch2cl2	trans-[nicl2(pph3)2]·2ch2cl2	NOUN
eurjchem-2214	261	12	is	be	AUX
eurjchem-2214	261	13	93.03(2)	93.03(2)	NOUN
eurjchem-2214	261	14	°	°	NUM
eurjchem-2214	261	15	.	.	PUNCT
eurjchem-2214	262	1	its	its	PRON
eurjchem-2214	262	2	noteworthy	noteworthy	ADJ
eurjchem-2214	262	3	,	,	PUNCT
eurjchem-2214	262	4	that	that	SCONJ
eurjchem-2214	262	5	the	the	DET
eurjchem-2214	262	6	ni	ni	PROPN
eurjchem-2214	262	7	-	-	PUNCT
eurjchem-2214	262	8	p	p	ADJ
eurjchem-2214	262	9	distances	distance	NOUN
eurjchem-2214	262	10	recorded	record	VERB
eurjchem-2214	262	11	in	in	ADP
eurjchem-2214	262	12	the	the	DET
eurjchem-2214	262	13	present	present	ADJ
eurjchem-2214	262	14	study	study	NOUN
eurjchem-2214	262	15	are	be	AUX
eurjchem-2214	262	16	longer	long	ADJ
eurjchem-2214	262	17	than	than	ADP
eurjchem-2214	262	18	the	the	DET
eurjchem-2214	262	19	distance	distance	NOUN
eurjchem-2214	262	20	reported	report	VERB
eurjchem-2214	262	21	for	for	ADP
eurjchem-2214	262	22	trans-[nicl2(pph3)2	trans-[nicl2(pph3)2	NOUN
eurjchem-2214	262	23	]	]	PUNCT
eurjchem-2214	262	24	·	·	PUNCT
eurjchem-2214	262	25	2ch2cl2	2ch2cl2	NUM
eurjchem-2214	262	26	.	.	PUNCT
eurjchem-2214	262	27	comparison	comparison	NOUN
eurjchem-2214	262	28	of	of	ADP
eurjchem-2214	262	29	ni	ni	PROPN
eurjchem-2214	262	30	-	-	PUNCT
eurjchem-2214	262	31	s	s	NOUN
eurjchem-2214	262	32	bond	bond	NOUN
eurjchem-2214	262	33	distances	distance	NOUN
eurjchem-2214	262	34	of	of	ADP
eurjchem-2214	262	35	trans[ni(sc6h5)2(pme3)2	trans[ni(sc6h5)2(pme3)2	NOUN
eurjchem-2214	262	36	]	]	X
eurjchem-2214	262	37	(	(	PUNCT
eurjchem-2214	262	38	9	9	NUM
eurjchem-2214	262	39	)	)	PUNCT
eurjchem-2214	262	40	,	,	PUNCT
eurjchem-2214	262	41	trans-[ni(sc6h4(o	trans-[ni(sc6h4(o	PROPN
eurjchem-2214	262	42	-	-	PUNCT
eurjchem-2214	262	43	me))2(pme3)2	me))2(pme3)2	NOUN
eurjchem-2214	262	44	]	]	X
eurjchem-2214	262	45	(	(	PUNCT
eurjchem-2214	262	46	10	10	NUM
eurjchem-2214	262	47	)	)	PUNCT
eurjchem-2214	262	48	and	and	CCONJ
eurjchem-2214	262	49	[	[	X
eurjchem-2214	262	50	ni(scoc6h5)2(pph3)2	ni(scoc6h5)2(pph3)2	PROPN
eurjchem-2214	262	51	]	]	X
eurjchem-2214	262	52	(	(	PUNCT
eurjchem-2214	262	53	11	11	NUM
eurjchem-2214	262	54	)	)	PUNCT
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eurjchem-2214	262	57	distances	distance	NOUN
eurjchem-2214	262	58	observed	observe	VERB
eurjchem-2214	262	59	in	in	ADP
eurjchem-2214	262	60	compounds	compound	NOUN
eurjchem-2214	262	61	1	1	NUM
eurjchem-2214	262	62	-	-	SYM
eurjchem-2214	262	63	6	6	NUM
eurjchem-2214	262	64	show	show	NOUN
eurjchem-2214	262	65	that	that	SCONJ
eurjchem-2214	262	66	they	they	PRON
eurjchem-2214	262	67	are	be	AUX
eurjchem-2214	262	68	between	between	ADP
eurjchem-2214	262	69	the	the	DET
eurjchem-2214	262	70	heteroleptic	heteroleptic	ADJ
eurjchem-2214	262	71	bond	bond	NOUN
eurjchem-2214	262	72	distances	distance	NOUN
eurjchem-2214	262	73	[	[	X
eurjchem-2214	262	74	ni	ni	NOUN
eurjchem-2214	262	75	-	-	PUNCT
eurjchem-2214	262	76	s	s	NOUN
eurjchem-2214	262	77	:	:	PUNCT
eurjchem-2214	262	78	2.2138(5	2.2138(5	NUM
eurjchem-2214	262	79	)	)	PUNCT
eurjchem-2214	262	80	å	å	PROPN
eurjchem-2214	262	81	(	(	PUNCT
eurjchem-2214	262	82	9	9	NUM
eurjchem-2214	262	83	)	)	PUNCT
eurjchem-2214	262	84	,	,	PUNCT
eurjchem-2214	262	85	2.2116(7	2.2116(7	NUM
eurjchem-2214	262	86	)	)	PUNCT
eurjchem-2214	262	87	å	å	NOUN
eurjchem-2214	262	88	(	(	PUNCT
eurjchem-2214	262	89	10	10	NUM
eurjchem-2214	262	90	)	)	PUNCT
eurjchem-2214	262	91	,	,	PUNCT
eurjchem-2214	262	92	2.231(5	2.231(5	NUM
eurjchem-2214	262	93	)	)	PUNCT
eurjchem-2214	262	94	å	å	PROPN
eurjchem-2214	262	95	(	(	PUNCT
eurjchem-2214	262	96	11	11	NUM
eurjchem-2214	262	97	)	)	PUNCT
eurjchem-2214	262	98	]	]	PUNCT
eurjchem-2214	263	1	[	[	X
eurjchem-2214	263	2	40,41	40,41	NOUN
eurjchem-2214	263	3	]	]	X
eurjchem-2214	263	4	.	.	PUNCT
eurjchem-2214	264	1	but	but	CCONJ
eurjchem-2214	264	2	the	the	DET
eurjchem-2214	264	3	ni	ni	PROPN
eurjchem-2214	264	4	-	-	PROPN
eurjchem-2214	264	5	p	p	ADJ
eurjchem-2214	264	6	distances	distance	NOUN
eurjchem-2214	264	7	are	be	AUX
eurjchem-2214	264	8	comparable	comparable	ADJ
eurjchem-2214	264	9	to	to	ADP
eurjchem-2214	264	10	the	the	DET
eurjchem-2214	264	11	distances	distance	NOUN
eurjchem-2214	264	12	reported	report	VERB
eurjchem-2214	264	13	in	in	ADP
eurjchem-2214	264	14	the	the	DET
eurjchem-2214	264	15	present	present	ADJ
eurjchem-2214	264	16	study	study	NOUN
eurjchem-2214	264	17	[	[	X
eurjchem-2214	264	18	ni	ni	NOUN
eurjchem-2214	264	19	-	-	ADJ
eurjchem-2214	264	20	p	p	X
eurjchem-2214	264	21	:	:	PUNCT
eurjchem-2214	264	22	2.2199(7	2.2199(7	NUM
eurjchem-2214	264	23	)	)	PUNCT
eurjchem-2214	264	24	å	å	NOUN
eurjchem-2214	264	25	(	(	PUNCT
eurjchem-2214	264	26	9	9	NUM
eurjchem-2214	264	27	)	)	PUNCT
eurjchem-2214	264	28	,	,	PUNCT
eurjchem-2214	264	29	2.2141(8	2.2141(8	NUM
eurjchem-2214	264	30	)	)	PUNCT
eurjchem-2214	264	31	å	å	PROPN
eurjchem-2214	264	32	(	(	PUNCT
eurjchem-2214	264	33	10	10	NUM
eurjchem-2214	264	34	)	)	PUNCT
eurjchem-2214	264	35	,	,	PUNCT
eurjchem-2214	264	36	2.156(5	2.156(5	NUM
eurjchem-2214	264	37	)	)	PUNCT
eurjchem-2214	264	38	å	å	PROPN
eurjchem-2214	264	39	(	(	PUNCT
eurjchem-2214	264	40	11	11	NUM
eurjchem-2214	264	41	)	)	PUNCT
eurjchem-2214	264	42	]	]	PUNCT
eurjchem-2214	264	43	.	.	PUNCT
eurjchem-2214	265	1	the	the	DET
eurjchem-2214	265	2	corresponding	corresponding	PROPN
eurjchem-2214	265	3	s	s	PROPN
eurjchem-2214	265	4	-	-	PUNCT
eurjchem-2214	265	5	ni	ni	NOUN
eurjchem-2214	265	6	-	-	PROPN
eurjchem-2214	265	7	p	p	ADJ
eurjchem-2214	265	8	and	and	CCONJ
eurjchem-2214	265	9	s	s	PROPN
eurjchem-2214	265	10	-	-	PUNCT
eurjchem-2214	265	11	ni	ni	PROPN
eurjchem-2214	265	12	-	-	PUNCT
eurjchem-2214	265	13	s	s	NOUN
eurjchem-2214	265	14	bond	bond	NOUN
eurjchem-2214	265	15	angles	angle	NOUN
eurjchem-2214	265	16	in	in	ADP
eurjchem-2214	265	17	compounds	compound	NOUN
eurjchem-2214	265	18	9	9	NUM
eurjchem-2214	265	19	-	-	SYM
eurjchem-2214	265	20	11	11	NUM
eurjchem-2214	265	21	clearly	clearly	ADV
eurjchem-2214	265	22	indicate	indicate	VERB
eurjchem-2214	265	23	that	that	SCONJ
eurjchem-2214	265	24	the	the	DET
eurjchem-2214	265	25	planar	planar	ADJ
eurjchem-2214	265	26	square	square	ADJ
eurjchem-2214	265	27	geometry	geometry	NOUN
eurjchem-2214	265	28	in	in	ADP
eurjchem-2214	265	29	compounds	compound	NOUN
eurjchem-2214	265	30	1	1	NUM
eurjchem-2214	265	31	-	-	SYM
eurjchem-2214	265	32	6	6	NUM
eurjchem-2214	265	33	is	be	AUX
eurjchem-2214	265	34	skewed	skewed	ADJ
eurjchem-2214	265	35	because	because	SCONJ
eurjchem-2214	265	36	of	of	ADP
eurjchem-2214	265	37	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	ADJ
eurjchem-2214	265	38	anion	anion	NOUN
eurjchem-2214	265	39	[	[	X
eurjchem-2214	265	40	s	s	NOUN
eurjchem-2214	265	41	-	-	PUNCT
eurjchem-2214	265	42	ni	ni	NOUN
eurjchem-2214	265	43	-	-	ADJ
eurjchem-2214	265	44	p	p	ADJ
eurjchem-2214	265	45	:	:	PUNCT
eurjchem-2214	265	46	93.23(2	93.23(2	NUM
eurjchem-2214	265	47	)	)	PUNCT
eurjchem-2214	265	48	°	°	NOUN
eurjchem-2214	265	49	(	(	PUNCT
eurjchem-2214	265	50	9	9	NUM
eurjchem-2214	265	51	)	)	PUNCT
eurjchem-2214	265	52	,	,	PUNCT
eurjchem-2214	265	53	93.49(3	93.49(3	NOUN
eurjchem-2214	265	54	)	)	PUNCT
eurjchem-2214	265	55	°	°	NOUN
eurjchem-2214	265	56	(	(	PUNCT
eurjchem-2214	265	57	10	10	NUM
eurjchem-2214	265	58	)	)	PUNCT
eurjchem-2214	265	59	,	,	PUNCT
eurjchem-2214	265	60	s	s	PROPN
eurjchem-2214	265	61	-	-	PUNCT
eurjchem-2214	265	62	ni	ni	NOUN
eurjchem-2214	265	63	-	-	PUNCT
eurjchem-2214	265	64	s	s	NOUN
eurjchem-2214	265	65	:	:	PUNCT
eurjchem-2214	265	66	95.0(3	95.0(3	NUM
eurjchem-2214	265	67	)	)	PUNCT
eurjchem-2214	265	68	°	°	NOUN
eurjchem-2214	266	1	(	(	PUNCT
eurjchem-2214	266	2	11	11	NUM
eurjchem-2214	266	3	)	)	PUNCT
eurjchem-2214	266	4	]	]	PUNCT
eurjchem-2214	266	5	.	.	PUNCT
eurjchem-2214	267	1	bond	bond	NOUN
eurjchem-2214	267	2	parameters	parameter	NOUN
eurjchem-2214	267	3	of	of	ADP
eurjchem-2214	267	4	cis	cis	NOUN
eurjchem-2214	267	5	-	-	PUNCT
eurjchem-2214	267	6	platin	platin	NOUN
eurjchem-2214	267	7	(	(	PUNCT
eurjchem-2214	267	8	12	12	NUM
eurjchem-2214	267	9	)	)	PUNCT
eurjchem-2214	267	10	reported	report	VERB
eurjchem-2214	267	11	in	in	ADP
eurjchem-2214	267	12	the	the	DET
eurjchem-2214	267	13	literature	literature	NOUN
eurjchem-2214	267	14	[	[	X
eurjchem-2214	267	15	pt	pt	INTJ
eurjchem-2214	267	16	-	-	PUNCT
eurjchem-2214	267	17	cl	cl	NOUN
eurjchem-2214	267	18	:	:	PUNCT
eurjchem-2214	267	19	2.33(1	2.33(1	NUM
eurjchem-2214	267	20	)	)	PUNCT
eurjchem-2214	267	21	å	å	PROPN
eurjchem-2214	267	22	,	,	PUNCT
eurjchem-2214	267	23	pt	pt	NOUN
eurjchem-2214	267	24	-	-	PUNCT
eurjchem-2214	267	25	n	n	CCONJ
eurjchem-2214	267	26	:	:	PUNCT
eurjchem-2214	267	27	2.01(4	2.01(4	NUM
eurjchem-2214	267	28	)	)	PUNCT
eurjchem-2214	267	29	å	å	NOUN
eurjchem-2214	267	30	,	,	PUNCT
eurjchem-2214	267	31	cl	cl	NOUN
eurjchem-2214	267	32	-	-	PUNCT
eurjchem-2214	267	33	pt	pt	NOUN
eurjchem-2214	267	34	-	-	PUNCT
eurjchem-2214	267	35	n	n	CCONJ
eurjchem-2214	267	36	:	:	PUNCT
eurjchem-2214	267	37	90.9(4	90.9(4	NOUN
eurjchem-2214	267	38	)	)	PUNCT
eurjchem-2214	267	39	°	°	PROPN
eurjchem-2214	267	40	]	]	PUNCT
eurjchem-2214	267	41	show	show	VERB
eurjchem-2214	267	42	that	that	SCONJ
eurjchem-2214	267	43	bond	bond	NOUN
eurjchem-2214	267	44	angles	angle	NOUN
eurjchem-2214	267	45	are	be	AUX
eurjchem-2214	267	46	close	close	ADJ
eurjchem-2214	267	47	to	to	ADP
eurjchem-2214	267	48	90	90	NUM
eurjchem-2214	267	49	°	°	NOUN
eurjchem-2214	268	1	[	[	X
eurjchem-2214	268	2	42	42	NUM
eurjchem-2214	268	3	]	]	PUNCT
eurjchem-2214	268	4	.	.	PUNCT
eurjchem-2214	269	1	however	however	ADV
eurjchem-2214	269	2	,	,	PUNCT
eurjchem-2214	269	3	mean	mean	VERB
eurjchem-2214	269	4	p	p	PROPN
eurjchem-2214	269	5	-	-	PUNCT
eurjchem-2214	269	6	ni	ni	NOUN
eurjchem-2214	269	7	-	-	PROPN
eurjchem-2214	269	8	p	p	X
eurjchem-2214	269	9	/	/	SYM
eurjchem-2214	269	10	c	c	NOUN
eurjchem-2214	269	11	/	/	SYM
eurjchem-2214	269	12	n	n	NOUN
eurjchem-2214	269	13	angles	angle	NOUN
eurjchem-2214	269	14	for	for	ADP
eurjchem-2214	269	15	compounds	compound	NOUN
eurjchem-2214	269	16	1	1	NUM
eurjchem-2214	269	17	-	-	SYM
eurjchem-2214	269	18	5	5	NUM
eurjchem-2214	269	19	is	be	AUX
eurjchem-2214	269	20	92.35(7	92.35(7	NUM
eurjchem-2214	269	21	)	)	PUNCT
eurjchem-2214	269	22	°	°	NOUN
eurjchem-2214	269	23	and	and	CCONJ
eurjchem-2214	269	24	the	the	DET
eurjchem-2214	269	25	variation	variation	NOUN
eurjchem-2214	269	26	in	in	ADP
eurjchem-2214	269	27	the	the	DET
eurjchem-2214	269	28	angle	angle	NOUN
eurjchem-2214	269	29	depends	depend	VERB
eurjchem-2214	269	30	on	on	ADP
eurjchem-2214	269	31	the	the	DET
eurjchem-2214	269	32	bulkiness	bulkiness	NOUN
eurjchem-2214	269	33	of	of	ADP
eurjchem-2214	269	34	the	the	DET
eurjchem-2214	269	35	substituent	substituent	NOUN
eurjchem-2214	269	36	.	.	PUNCT
eurjchem-2214	270	1	the	the	DET
eurjchem-2214	270	2	compounds	compound	NOUN
eurjchem-2214	270	3	investigated	investigate	VERB
eurjchem-2214	270	4	in	in	ADP
eurjchem-2214	270	5	the	the	DET
eurjchem-2214	270	6	present	present	ADJ
eurjchem-2214	270	7	study	study	NOUN
eurjchem-2214	270	8	contain	contain	VERB
eurjchem-2214	270	9	nickel	nickel	NOUN
eurjchem-2214	270	10	as	as	ADP
eurjchem-2214	270	11	the	the	DET
eurjchem-2214	270	12	central	central	ADJ
eurjchem-2214	270	13	atom	atom	NOUN
eurjchem-2214	270	14	which	which	PRON
eurjchem-2214	270	15	is	be	AUX
eurjchem-2214	270	16	of	of	ADP
eurjchem-2214	270	17	lower	low	ADJ
eurjchem-2214	270	18	renal	renal	ADJ
eurjchem-2214	270	19	toxicity	toxicity	NOUN
eurjchem-2214	270	20	than	than	ADP
eurjchem-2214	270	21	platinum	platinum	NOUN
eurjchem-2214	270	22	.	.	PUNCT
eurjchem-2214	271	1	the	the	DET
eurjchem-2214	271	2	chelating	chelate	VERB
eurjchem-2214	271	3	nature	nature	NOUN
eurjchem-2214	271	4	of	of	ADP
eurjchem-2214	271	5	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	ADJ
eurjchem-2214	271	6	anion	anion	NOUN
eurjchem-2214	271	7	adds	add	VERB
eurjchem-2214	271	8	extra	extra	ADJ
eurjchem-2214	271	9	stability	stability	NOUN
eurjchem-2214	271	10	to	to	ADP
eurjchem-2214	271	11	the	the	DET
eurjchem-2214	271	12	planar	planar	ADJ
eurjchem-2214	271	13	square	square	ADJ
eurjchem-2214	271	14	geometry	geometry	NOUN
eurjchem-2214	271	15	and	and	CCONJ
eurjchem-2214	271	16	nickel(ii	nickel(ii	NOUN
eurjchem-2214	271	17	)	)	PUNCT
eurjchem-2214	271	18	shows	show	VERB
eurjchem-2214	271	19	reluctance	reluctance	NOUN
eurjchem-2214	271	20	to	to	PART
eurjchem-2214	271	21	add	add	VERB
eurjchem-2214	271	22	axial	axial	ADJ
eurjchem-2214	271	23	ligands	ligand	NOUN
eurjchem-2214	271	24	similar	similar	ADJ
eurjchem-2214	271	25	to	to	ADP
eurjchem-2214	271	26	divalent	divalent	ADJ
eurjchem-2214	271	27	platinum	platinum	NOUN
eurjchem-2214	271	28	.	.	PUNCT
eurjchem-2214	272	1	3.6	3.6	NUM
eurjchem-2214	272	2	.	.	PUNCT
eurjchem-2214	273	1	bond	bond	NOUN
eurjchem-2214	273	2	valence	valence	NOUN
eurjchem-2214	273	3	sum	sum	NOUN
eurjchem-2214	273	4	analysis	analysis	NOUN
eurjchem-2214	273	5	the	the	DET
eurjchem-2214	273	6	bond	bond	NOUN
eurjchem-2214	273	7	valence	valence	NOUN
eurjchem-2214	273	8	sum	sum	NOUN
eurjchem-2214	273	9	(	(	PUNCT
eurjchem-2214	273	10	bvs	bvs	NOUN
eurjchem-2214	273	11	)	)	PUNCT
eurjchem-2214	273	12	model	model	NOUN
eurjchem-2214	273	13	can	can	AUX
eurjchem-2214	273	14	be	be	AUX
eurjchem-2214	273	15	used	use	VERB
eurjchem-2214	273	16	to	to	PART
eurjchem-2214	273	17	determine	determine	VERB
eurjchem-2214	273	18	the	the	DET
eurjchem-2214	273	19	compatibility	compatibility	NOUN
eurjchem-2214	273	20	between	between	ADP
eurjchem-2214	273	21	a	a	DET
eurjchem-2214	273	22	given	give	VERB
eurjchem-2214	273	23	coordination	coordination	NOUN
eurjchem-2214	273	24	model	model	NOUN
eurjchem-2214	273	25	and	and	CCONJ
eurjchem-2214	273	26	a	a	DET
eurjchem-2214	273	27	particular	particular	ADJ
eurjchem-2214	273	28	oxidation	oxidation	NOUN
eurjchem-2214	273	29	state	state	NOUN
eurjchem-2214	273	30	and	and	CCONJ
eurjchem-2214	273	31	conversely	conversely	ADV
eurjchem-2214	273	32	,	,	PUNCT
eurjchem-2214	273	33	the	the	DET
eurjchem-2214	273	34	method	method	NOUN
eurjchem-2214	273	35	is	be	AUX
eurjchem-2214	273	36	used	use	VERB
eurjchem-2214	273	37	to	to	PART
eurjchem-2214	273	38	check	check	VERB
eurjchem-2214	273	39	correctness	correctness	NOUN
eurjchem-2214	273	40	of	of	ADP
eurjchem-2214	273	41	the	the	DET
eurjchem-2214	273	42	determined	determined	ADJ
eurjchem-2214	273	43	structure	structure	NOUN
eurjchem-2214	273	44	.	.	PUNCT
eurjchem-2214	274	1	application	application	NOUN
eurjchem-2214	274	2	of	of	ADP
eurjchem-2214	274	3	bvs	bvs	PROPN
eurjchem-2214	274	4	model	model	NOUN
eurjchem-2214	274	5	[	[	X
eurjchem-2214	274	6	43	43	NUM
eurjchem-2214	274	7	]	]	PUNCT
eurjchem-2214	274	8	,	,	PUNCT
eurjchem-2214	274	9	to	to	PART
eurjchem-2214	274	10	divalent	divalent	VERB
eurjchem-2214	274	11	nickel	nickel	NOUN
eurjchem-2214	274	12	coordination	coordination	NOUN
eurjchem-2214	274	13	complexes	complex	NOUN
eurjchem-2214	274	14	always	always	ADV
eurjchem-2214	274	15	resulted	result	VERB
eurjchem-2214	274	16	in	in	ADP
eurjchem-2214	274	17	a	a	DET
eurjchem-2214	274	18	higher	high	ADJ
eurjchem-2214	274	19	valence	valence	NOUN
eurjchem-2214	274	20	and	and	CCONJ
eurjchem-2214	274	21	for	for	ADP
eurjchem-2214	274	22	many	many	ADJ
eurjchem-2214	274	23	of	of	ADP
eurjchem-2214	274	24	the	the	DET
eurjchem-2214	274	25	dithiocarbamato	dithiocarbamato	NOUN
eurjchem-2214	274	26	complexes	complex	NOUN
eurjchem-2214	274	27	of	of	ADP
eurjchem-2214	274	28	divalent	divalent	ADJ
eurjchem-2214	274	29	nickel	nickel	NOUN
eurjchem-2214	274	30	,	,	PUNCT
eurjchem-2214	274	31	the	the	DET
eurjchem-2214	274	32	bond	bond	NOUN
eurjchem-2214	274	33	valence	valence	NOUN
eurjchem-2214	274	34	sums	sum	NOUN
eurjchem-2214	274	35	exceeded	exceed	VERB
eurjchem-2214	274	36	2.8	2.8	NUM
eurjchem-2214	274	37	.	.	PUNCT
eurjchem-2214	275	1	the	the	DET
eurjchem-2214	275	2	increased	increase	VERB
eurjchem-2214	275	3	vi	vi	NOUN
eurjchem-2214	275	4	obtained	obtain	VERB
eurjchem-2214	275	5	for	for	ADP
eurjchem-2214	275	6	ni2	ni2	PROPN
eurjchem-2214	275	7	+	+	PROPN
eurjchem-2214	275	8	is	be	AUX
eurjchem-2214	275	9	due	due	ADJ
eurjchem-2214	275	10	to	to	ADP
eurjchem-2214	275	11	the	the	DET
eurjchem-2214	275	12	use	use	NOUN
eurjchem-2214	275	13	of	of	ADP
eurjchem-2214	275	14	rij	rij	ADJ
eurjchem-2214	275	15	values	value	NOUN
eurjchem-2214	275	16	obtained	obtain	VERB
eurjchem-2214	275	17	from	from	ADP
eurjchem-2214	275	18	the	the	DET
eurjchem-2214	275	19	crystallographic	crystallographic	ADJ
eurjchem-2214	275	20	bond	bond	NOUN
eurjchem-2214	275	21	distances	distance	NOUN
eurjchem-2214	275	22	of	of	ADP
eurjchem-2214	275	23	homoleptic	homoleptic	ADJ
eurjchem-2214	275	24	extended	extended	ADJ
eurjchem-2214	275	25	solids	solid	NOUN
eurjchem-2214	275	26	,	,	PUNCT
eurjchem-2214	275	27	which	which	PRON
eurjchem-2214	275	28	have	have	VERB
eurjchem-2214	275	29	predominantly	predominantly	ADV
eurjchem-2214	275	30	ionic	ionic	ADJ
eurjchem-2214	275	31	character	character	NOUN
eurjchem-2214	275	32	and	and	CCONJ
eurjchem-2214	275	33	in	in	ADP
eurjchem-2214	275	34	the	the	DET
eurjchem-2214	275	35	present	present	ADJ
eurjchem-2214	275	36	study	study	NOUN
eurjchem-2214	275	37	,	,	PUNCT
eurjchem-2214	275	38	rij	rij	ADJ
eurjchem-2214	275	39	distances	distance	NOUN
eurjchem-2214	275	40	have	have	AUX
eurjchem-2214	275	41	been	be	AUX
eurjchem-2214	275	42	redetermined	redetermine	VERB
eurjchem-2214	275	43	for	for	ADP
eurjchem-2214	275	44	some	some	DET
eurjchem-2214	275	45	model	model	NOUN
eurjchem-2214	275	46	complexes	complex	NOUN
eurjchem-2214	275	47	of	of	ADP
eurjchem-2214	275	48	transition	transition	NOUN
eurjchem-2214	275	49	metals	metal	NOUN
eurjchem-2214	275	50	with	with	ADP
eurjchem-2214	275	51	partial	partial	ADJ
eurjchem-2214	275	52	covalence	covalence	NOUN
eurjchem-2214	275	53	[	[	X
eurjchem-2214	275	54	44,45	44,45	X
eurjchem-2214	275	55	]	]	X
eurjchem-2214	275	56	.	.	PUNCT
eurjchem-2214	276	1	the	the	DET
eurjchem-2214	276	2	bvs	bvs	PROPN
eurjchem-2214	276	3	computed	compute	VERB
eurjchem-2214	276	4	for	for	ADP
eurjchem-2214	276	5	the	the	DET
eurjchem-2214	276	6	complexes	complex	NOUN
eurjchem-2214	276	7	with	with	ADP
eurjchem-2214	276	8	the	the	DET
eurjchem-2214	276	9	revised	revise	VERB
eurjchem-2214	276	10	rij	rij	NOUN
eurjchem-2214	276	11	[	[	X
eurjchem-2214	276	12	46	46	NUM
eurjchem-2214	276	13	]	]	PUNCT
eurjchem-2214	276	14	are	be	AUX
eurjchem-2214	276	15	shown	show	VERB
eurjchem-2214	276	16	in	in	ADP
eurjchem-2214	276	17	table	table	NOUN
eurjchem-2214	276	18	3	3	NUM
eurjchem-2214	276	19	and	and	CCONJ
eurjchem-2214	276	20	the	the	DET
eurjchem-2214	276	21	formal	formal	ADJ
eurjchem-2214	276	22	oxidation	oxidation	NOUN
eurjchem-2214	276	23	state	state	NOUN
eurjchem-2214	276	24	for	for	ADP
eurjchem-2214	276	25	the	the	DET
eurjchem-2214	276	26	complexes	complex	NOUN
eurjchem-2214	276	27	1	1	NUM
eurjchem-2214	276	28	-	-	SYM
eurjchem-2214	276	29	5	5	NUM
eurjchem-2214	276	30	are	be	AUX
eurjchem-2214	276	31	~2.0	~2.0	PUNCT
eurjchem-2214	276	32	confirming	confirm	VERB
eurjchem-2214	276	33	the	the	DET
eurjchem-2214	276	34	correctness	correctness	NOUN
eurjchem-2214	276	35	of	of	ADP
eurjchem-2214	276	36	the	the	DET
eurjchem-2214	276	37	determined	determined	ADJ
eurjchem-2214	276	38	crystal	crystal	NOUN
eurjchem-2214	276	39	structures	structure	NOUN
eurjchem-2214	276	40	and	and	CCONJ
eurjchem-2214	276	41	the	the	DET
eurjchem-2214	276	42	formal	formal	ADJ
eurjchem-2214	276	43	oxidation	oxidation	NOUN
eurjchem-2214	276	44	state	state	NOUN
eurjchem-2214	276	45	of	of	ADP
eurjchem-2214	276	46	the	the	DET
eurjchem-2214	276	47	central	central	ADJ
eurjchem-2214	276	48	nickel	nickel	NOUN
eurjchem-2214	276	49	atom	atom	NOUN
eurjchem-2214	276	50	.	.	PUNCT
eurjchem-2214	277	1	3.7	3.7	NUM
eurjchem-2214	277	2	.	.	PUNCT
eurjchem-2214	278	1	continuous	continuous	ADJ
eurjchem-2214	278	2	shape	shape	NOUN
eurjchem-2214	278	3	measure	measure	NOUN
eurjchem-2214	278	4	analysis	analysis	NOUN
eurjchem-2214	278	5	of	of	ADP
eurjchem-2214	278	6	the	the	DET
eurjchem-2214	278	7	chromophores	chromophore	NOUN
eurjchem-2214	278	8	continuous	continuous	ADJ
eurjchem-2214	278	9	shape	shape	NOUN
eurjchem-2214	278	10	measure	measure	NOUN
eurjchem-2214	278	11	(	(	PUNCT
eurjchem-2214	278	12	csm	csm	NOUN
eurjchem-2214	278	13	)	)	PUNCT
eurjchem-2214	278	14	details	detail	NOUN
eurjchem-2214	278	15	the	the	DET
eurjchem-2214	278	16	extent	extent	NOUN
eurjchem-2214	278	17	of	of	ADP
eurjchem-2214	278	18	distortion	distortion	NOUN
eurjchem-2214	278	19	of	of	ADP
eurjchem-2214	278	20	a	a	DET
eurjchem-2214	278	21	polyhedron	polyhedron	NOUN
eurjchem-2214	278	22	from	from	ADP
eurjchem-2214	278	23	the	the	DET
eurjchem-2214	278	24	ideal	ideal	ADJ
eurjchem-2214	278	25	symmetry	symmetry	NOUN
eurjchem-2214	278	26	or	or	CCONJ
eurjchem-2214	278	27	from	from	ADP
eurjchem-2214	278	28	reference	reference	NOUN
eurjchem-2214	278	29	symmetry	symmetry	NOUN
eurjchem-2214	279	1	[	[	X
eurjchem-2214	279	2	47	47	NUM
eurjchem-2214	279	3	-	-	SYM
eurjchem-2214	279	4	49	49	NUM
eurjchem-2214	279	5	]	]	PUNCT
eurjchem-2214	279	6	.	.	PUNCT
eurjchem-2214	280	1	descriptions	description	NOUN
eurjchem-2214	280	2	of	of	ADP
eurjchem-2214	280	3	geometries	geometry	NOUN
eurjchem-2214	280	4	such	such	ADJ
eurjchem-2214	280	5	as	as	ADP
eurjchem-2214	280	6	‘	'	PUNCT
eurjchem-2214	280	7	slightly	slightly	ADV
eurjchem-2214	280	8	distorted	distort	VERB
eurjchem-2214	280	9	’	'	PUNCT
eurjchem-2214	280	10	or	or	CCONJ
eurjchem-2214	280	11	‘	'	PUNCT
eurjchem-2214	280	12	severely	severely	ADV
eurjchem-2214	280	13	distorted	distort	VERB
eurjchem-2214	280	14	’	'	PUNCT
eurjchem-2214	280	15	with	with	ADP
eurjchem-2214	280	16	reference	reference	NOUN
eurjchem-2214	280	17	to	to	ADP
eurjchem-2214	280	18	a	a	DET
eurjchem-2214	280	19	polyhedron	polyhedron	NOUN
eurjchem-2214	280	20	is	be	AUX
eurjchem-2214	280	21	highly	highly	ADV
eurjchem-2214	280	22	qualitative	qualitative	ADJ
eurjchem-2214	280	23	in	in	ADP
eurjchem-2214	280	24	nature	nature	NOUN
eurjchem-2214	280	25	.	.	PUNCT
eurjchem-2214	281	1	degree	degree	NOUN
eurjchem-2214	281	2	of	of	ADP
eurjchem-2214	281	3	distortion	distortion	NOUN
eurjchem-2214	281	4	of	of	ADP
eurjchem-2214	281	5	a	a	DET
eurjchem-2214	281	6	particular	particular	ADJ
eurjchem-2214	281	7	molecular	molecular	ADJ
eurjchem-2214	281	8	structure	structure	NOUN
eurjchem-2214	281	9	from	from	ADP
eurjchem-2214	281	10	an	an	DET
eurjchem-2214	281	11	ideal	ideal	ADJ
eurjchem-2214	281	12	polyhedron	polyhedron	NOUN
eurjchem-2214	281	13	can	can	AUX
eurjchem-2214	281	14	be	be	AUX
eurjchem-2214	281	15	assessed	assess	VERB
eurjchem-2214	281	16	by	by	ADP
eurjchem-2214	281	17	symmetry	symmetry	NOUN
eurjchem-2214	281	18	measures	measure	NOUN
eurjchem-2214	281	19	.	.	PUNCT
eurjchem-2214	282	1	table	table	NOUN
eurjchem-2214	282	2	4	4	NUM
eurjchem-2214	282	3	depicts	depict	VERB
eurjchem-2214	282	4	the	the	DET
eurjchem-2214	282	5	continuous	continuous	ADJ
eurjchem-2214	282	6	shape	shape	NOUN
eurjchem-2214	282	7	measures	measure	NOUN
eurjchem-2214	282	8	of	of	ADP
eurjchem-2214	282	9	the	the	DET
eurjchem-2214	282	10	chromophores	chromophore	NOUN
eurjchem-2214	282	11	evaluated	evaluate	VERB
eurjchem-2214	282	12	from	from	ADP
eurjchem-2214	282	13	the	the	DET
eurjchem-2214	282	14	structural	structural	ADJ
eurjchem-2214	282	15	parameters	parameter	NOUN
eurjchem-2214	282	16	of	of	ADP
eurjchem-2214	282	17	the	the	DET
eurjchem-2214	282	18	compounds	compound	NOUN
eurjchem-2214	282	19	1	1	NUM
eurjchem-2214	282	20	-	-	SYM
eurjchem-2214	282	21	6	6	NUM
eurjchem-2214	282	22	along	along	ADP
eurjchem-2214	282	23	with	with	ADP
eurjchem-2214	282	24	five	five	NUM
eurjchem-2214	282	25	more	more	ADJ
eurjchem-2214	282	26	complexes	complex	NOUN
eurjchem-2214	282	27	which	which	PRON
eurjchem-2214	282	28	contain	contain	VERB
eurjchem-2214	282	29	similar	similar	ADJ
eurjchem-2214	282	30	chromophores	chromophore	NOUN
eurjchem-2214	282	31	7	7	NUM
eurjchem-2214	282	32	-	-	SYM
eurjchem-2214	282	33	11	11	NUM
eurjchem-2214	282	34	from	from	ADP
eurjchem-2214	282	35	the	the	DET
eurjchem-2214	282	36	published	publish	VERB
eurjchem-2214	282	37	crystal	crystal	NOUN
eurjchem-2214	282	38	structures	structure	NOUN
eurjchem-2214	282	39	for	for	ADP
eurjchem-2214	282	40	comparison	comparison	NOUN
eurjchem-2214	282	41	(	(	PUNCT
eurjchem-2214	282	42	figure	figure	NOUN
eurjchem-2214	282	43	5	5	NUM
eurjchem-2214	282	44	)	)	PUNCT
eurjchem-2214	282	45	.	.	PUNCT
eurjchem-2214	283	1	the	the	DET
eurjchem-2214	283	2	csm	csm	NOUN
eurjchem-2214	283	3	values	value	NOUN
eurjchem-2214	283	4	vary	vary	VERB
eurjchem-2214	283	5	from	from	ADP
eurjchem-2214	283	6	0	0	NUM
eurjchem-2214	283	7	to	to	ADP
eurjchem-2214	283	8	100	100	NUM
eurjchem-2214	283	9	,	,	PUNCT
eurjchem-2214	283	10	higher	high	ADJ
eurjchem-2214	283	11	the	the	DET
eurjchem-2214	283	12	value	value	NOUN
eurjchem-2214	283	13	,	,	PUNCT
eurjchem-2214	283	14	larger	large	ADJ
eurjchem-2214	283	15	is	be	AUX
eurjchem-2214	283	16	the	the	DET
eurjchem-2214	283	17	deviation	deviation	NOUN
eurjchem-2214	283	18	of	of	ADP
eurjchem-2214	283	19	a	a	DET
eurjchem-2214	283	20	structure	structure	NOUN
eurjchem-2214	283	21	from	from	ADP
eurjchem-2214	283	22	the	the	DET
eurjchem-2214	283	23	assigned	assign	VERB
eurjchem-2214	283	24	shape	shape	NOUN
eurjchem-2214	283	25	.	.	PUNCT
eurjchem-2214	284	1	all	all	DET
eurjchem-2214	284	2	the	the	DET
eurjchem-2214	284	3	chromophores	chromophore	NOUN
eurjchem-2214	284	4	of	of	ADP
eurjchem-2214	284	5	compounds	compound	NOUN
eurjchem-2214	284	6	1	1	NUM
eurjchem-2214	284	7	-	-	SYM
eurjchem-2214	284	8	6	6	NUM
eurjchem-2214	284	9	showed	show	VERB
eurjchem-2214	284	10	csm	csm	NOUN
eurjchem-2214	284	11	≤	≤	NUM
eurjchem-2214	284	12	0.7196	0.7196	NUM
eurjchem-2214	284	13	(	(	PUNCT
eurjchem-2214	284	14	planar	planar	ADJ
eurjchem-2214	284	15	square	square	NOUN
eurjchem-2214	284	16	)	)	PUNCT
eurjchem-2214	284	17	confirming	confirm	VERB
eurjchem-2214	284	18	their	their	PRON
eurjchem-2214	284	19	planar	planar	ADJ
eurjchem-2214	284	20	square	square	ADJ
eurjchem-2214	284	21	geometry	geometry	NOUN
eurjchem-2214	284	22	.	.	PUNCT
eurjchem-2214	285	1	as	as	ADP
eurjchem-2214	285	2	a	a	DET
eurjchem-2214	285	3	contrast	contrast	NOUN
eurjchem-2214	285	4	,	,	PUNCT
eurjchem-2214	285	5	the	the	DET
eurjchem-2214	285	6	assessed	assessed	ADJ
eurjchem-2214	285	7	values	value	NOUN
eurjchem-2214	285	8	for	for	ADP
eurjchem-2214	285	9	tetrahedral	tetrahedral	ADJ
eurjchem-2214	285	10	configuration	configuration	NOUN
eurjchem-2214	285	11	of	of	ADP
eurjchem-2214	285	12	the	the	DET
eurjchem-2214	285	13	chromophores	chromophore	NOUN
eurjchem-2214	285	14	are	be	AUX
eurjchem-2214	285	15	relatively	relatively	ADV
eurjchem-2214	285	16	large	large	ADJ
eurjchem-2214	285	17	(	(	PUNCT
eurjchem-2214	285	18	csm	csm	NOUN
eurjchem-2214	285	19	=	=	PUNCT
eurjchem-2214	285	20	30.5372	30.5372	NUM
eurjchem-2214	285	21	33.7831	33.7831	NUM
eurjchem-2214	285	22	)	)	PUNCT
eurjchem-2214	285	23	,	,	PUNCT
eurjchem-2214	285	24	confirming	confirm	VERB
eurjchem-2214	285	25	the	the	DET
eurjchem-2214	285	26	planar	planar	ADJ
eurjchem-2214	285	27	square	square	ADJ
eurjchem-2214	285	28	geometry	geometry	NOUN
eurjchem-2214	285	29	of	of	ADP
eurjchem-2214	285	30	the	the	DET
eurjchem-2214	285	31	chromophores	chromophore	NOUN
eurjchem-2214	285	32	.	.	PUNCT
eurjchem-2214	286	1	ramalingam	ramalingam	NOUN
eurjchem-2214	286	2	et	et	PROPN
eurjchem-2214	286	3	al	al	PROPN
eurjchem-2214	286	4	.	.	PUNCT
eurjchem-2214	286	5	/	/	SYM
eurjchem-2214	286	6	european	european	PROPN
eurjchem-2214	286	7	journal	journal	PROPN
eurjchem-2214	286	8	of	of	ADP
eurjchem-2214	286	9	chemistry	chemistry	NOUN
eurjchem-2214	286	10	13	13	NUM
eurjchem-2214	286	11	(	(	PUNCT
eurjchem-2214	286	12	1	1	NUM
eurjchem-2214	286	13	)	)	PUNCT
eurjchem-2214	286	14	(	(	PUNCT
eurjchem-2214	286	15	2022	2022	NUM
eurjchem-2214	286	16	)	)	PUNCT
eurjchem-2214	286	17	117	117	NUM
eurjchem-2214	286	18	-	-	SYM
eurjchem-2214	286	19	125	125	NUM
eurjchem-2214	286	20	123	123	NUM
eurjchem-2214	286	21	2022	2022	NUM
eurjchem-2214	286	22	–	–	PUNCT
eurjchem-2214	286	23	european	european	ADJ
eurjchem-2214	286	24	journal	journal	NOUN
eurjchem-2214	286	25	of	of	ADP
eurjchem-2214	286	26	chemistry	chemistry	NOUN
eurjchem-2214	286	27	–	–	PUNCT
eurjchem-2214	286	28	cc	cc	NOUN
eurjchem-2214	286	29	by	by	ADP
eurjchem-2214	286	30	nc	nc	PROPN
eurjchem-2214	286	31	–	–	PUNCT
eurjchem-2214	286	32	doi	doi	NOUN
eurjchem-2214	286	33	:	:	PUNCT
eurjchem-2214	286	34	10.5155	10.5155	NUM
eurjchem-2214	286	35	/	/	SYM
eurjchem-2214	286	36	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	286	37	-	-	SYM
eurjchem-2214	286	38	125.2214	125.2214	NUM
eurjchem-2214	286	39	table	table	NOUN
eurjchem-2214	286	40	4	4	NUM
eurjchem-2214	286	41	.	.	PUNCT
eurjchem-2214	286	42	continuous	continuous	ADJ
eurjchem-2214	286	43	shape	shape	NOUN
eurjchem-2214	286	44	measure	measure	NOUN
eurjchem-2214	286	45	parameters	parameter	NOUN
eurjchem-2214	286	46	for	for	ADP
eurjchem-2214	286	47	the	the	DET
eurjchem-2214	286	48	chromophores	chromophore	NOUN
eurjchem-2214	286	49	.	.	PUNCT
eurjchem-2214	287	1	compound	compound	PROPN
eurjchem-2214	287	2	planar	planar	PROPN
eurjchem-2214	287	3	square	square	ADJ
eurjchem-2214	287	4	tetrahedral	tetrahedral	ADJ
eurjchem-2214	287	5	tbp‡	tbp‡	ADJ
eurjchem-2214	287	6	(	(	PUNCT
eurjchem-2214	287	7	uebd	uebd	ADJ
eurjchem-2214	287	8	)	)	PUNCT
eurjchem-2214	287	9	tbp‡	tbp‡	NOUN
eurjchem-2214	287	10	(	(	PUNCT
eurjchem-2214	287	11	ebd	ebd	PROPN
eurjchem-2214	287	12	)	)	PUNCT
eurjchem-2214	288	1	[	[	X
eurjchem-2214	288	2	ni(pyrdtc)(pph3)(ncs	ni(pyrdtc)(pph3)(nc	NOUN
eurjchem-2214	288	3	)	)	PUNCT
eurjchem-2214	288	4	]	]	PUNCT
eurjchem-2214	288	5	(	(	PUNCT
eurjchem-2214	288	6	1	1	X
eurjchem-2214	288	7	)	)	PUNCT
eurjchem-2214	288	8	0.6680	0.6680	NUM
eurjchem-2214	288	9	30.5372	30.5372	NUM
eurjchem-2214	288	10	24.4955	24.4955	NUM
eurjchem-2214	288	11	28.7562	28.7562	NUM
eurjchem-2214	289	1	[	[	X
eurjchem-2214	289	2	ni(pyrdtc)(4	ni(pyrdtc)(4	NOUN
eurjchem-2214	289	3	-	-	PUNCT
eurjchem-2214	289	4	mp)(ncs	mp)(nc	NOUN
eurjchem-2214	289	5	)	)	PUNCT
eurjchem-2214	289	6	]	]	PUNCT
eurjchem-2214	289	7	(	(	PUNCT
eurjchem-2214	289	8	2	2	X
eurjchem-2214	289	9	)	)	PUNCT
eurjchem-2214	289	10	0.5831	0.5831	NUM
eurjchem-2214	289	11	32.1472	32.1472	NUM
eurjchem-2214	289	12	23.8335	23.8335	NUM
eurjchem-2214	289	13	29.7520	29.7520	NUM
eurjchem-2214	290	1	[	[	X
eurjchem-2214	290	2	ni(pyrdtc)(pph3)(cn)]·h2o	ni(pyrdtc)(pph3)(cn)]·h2o	NOUN
eurjchem-2214	290	3	(	(	PUNCT
eurjchem-2214	290	4	3	3	NUM
eurjchem-2214	290	5	)	)	PUNCT
eurjchem-2214	290	6	0.7196	0.7196	NUM
eurjchem-2214	290	7	32.8854	32.8854	NUM
eurjchem-2214	290	8	23.3066	23.3066	NUM
eurjchem-2214	290	9	28.8087	28.8087	NUM
eurjchem-2214	290	10	[	[	X
eurjchem-2214	290	11	ni(pyrdtc)(pph3)2]·clo4	ni(pyrdtc)(pph3)2]·clo4	ADJ
eurjchem-2214	290	12	(	(	PUNCT
eurjchem-2214	290	13	4	4	NUM
eurjchem-2214	290	14	)	)	PUNCT
eurjchem-2214	290	15	0.6414	0.6414	NUM
eurjchem-2214	290	16	30.5100	30.5100	NUM
eurjchem-2214	290	17	24.6447	24.6447	NUM
eurjchem-2214	290	18	29.0546	29.0546	NUM
eurjchem-2214	290	19	[	[	PUNCT
eurjchem-2214	290	20	ni(pyrdtc)(dppe)]·bph4	ni(pyrdtc)(dppe)]·bph4	ADJ
eurjchem-2214	290	21	(	(	PUNCT
eurjchem-2214	290	22	5	5	X
eurjchem-2214	290	23	)	)	PUNCT
eurjchem-2214	290	24	0.6631	0.6631	NUM
eurjchem-2214	290	25	29.4175	29.4175	NUM
eurjchem-2214	290	26	23.5953	23.5953	NUM
eurjchem-2214	290	27	27.9039	27.9039	NUM
eurjchem-2214	290	28	[	[	X
eurjchem-2214	290	29	ni(pyrdtc)2	ni(pyrdtc)2	X
eurjchem-2214	290	30	]	]	X
eurjchem-2214	290	31	(	(	PUNCT
eurjchem-2214	290	32	6	6	NUM
eurjchem-2214	290	33	)	)	PUNCT
eurjchem-2214	290	34	0.6759	0.6759	NUM
eurjchem-2214	290	35	33.7831	33.7831	NUM
eurjchem-2214	290	36	25.9948	25.9948	NUM
eurjchem-2214	290	37	30.7708	30.7708	NUM
eurjchem-2214	290	38	planar	planar	ADJ
eurjchem-2214	290	39	trans-[nicl2(pph3)2]·2ch2cl2a(7	trans-[nicl2(pph3)2]·2ch2cl2a(7	PROPN
eurjchem-2214	290	40	)	)	PUNCT
eurjchem-2214	290	41	0.1003	0.1003	NUM
eurjchem-2214	290	42	33.4002	33.4002	NUM
eurjchem-2214	290	43	25.1710	25.1710	NUM
eurjchem-2214	290	44	30.2536	30.2536	NUM
eurjchem-2214	290	45	tetrahedral	tetrahedral	ADJ
eurjchem-2214	290	46	[	[	X
eurjchem-2214	290	47	nicl2(pph3)2	nicl2(pph3)2	NOUN
eurjchem-2214	290	48	]	]	SYM
eurjchem-2214	290	49	b	b	X
eurjchem-2214	290	50	(	(	PUNCT
eurjchem-2214	290	51	8)	8)	NUM
eurjchem-2214	290	52	25.4633	25.4633	NUM
eurjchem-2214	290	53	0.8986	0.8986	NUM
eurjchem-2214	290	54	26.6717	26.6717	NUM
eurjchem-2214	290	55	25.4612	25.4612	NUM
eurjchem-2214	290	56	trans-[ni(sc6h5)2(pme3)2	trans-[ni(sc6h5)2(pme3)2	X
eurjchem-2214	290	57	]	]	X
eurjchem-2214	290	58	c	c	X
eurjchem-2214	290	59	(	(	PUNCT
eurjchem-2214	290	60	9	9	NUM
eurjchem-2214	290	61	)	)	PUNCT
eurjchem-2214	290	62	0.0800	0.0800	NUM
eurjchem-2214	290	63	33.3867	33.3867	NUM
eurjchem-2214	290	64	25.7202	25.7202	NUM
eurjchem-2214	290	65	30.3933	30.3933	NUM
eurjchem-2214	290	66	trans-[ni(sc6h4(o	trans-[ni(sc6h4(o	NUM
eurjchem-2214	290	67	-	-	PUNCT
eurjchem-2214	290	68	me))2(pme3)2	me))2(pme3)2	NOUN
eurjchem-2214	290	69	]	]	X
eurjchem-2214	290	70	c	c	NOUN
eurjchem-2214	290	71	(	(	PUNCT
eurjchem-2214	290	72	10	10	NUM
eurjchem-2214	290	73	)	)	PUNCT
eurjchem-2214	290	74	0.0930	0.0930	NUM
eurjchem-2214	290	75	33.3953	33.3953	NUM
eurjchem-2214	290	76	25.7641	25.7641	NUM
eurjchem-2214	290	77	30.4152	30.4152	NUM
eurjchem-2214	291	1	[	[	X
eurjchem-2214	291	2	ni(sco	ni(sco	PROPN
eurjchem-2214	291	3	c6h5)2(pph3)2	c6h5)2(pph3)2	NOUN
eurjchem-2214	291	4	]	]	X
eurjchem-2214	291	5	d	d	X
eurjchem-2214	291	6	(	(	PUNCT
eurjchem-2214	291	7	11	11	NUM
eurjchem-2214	291	8	)	)	PUNCT
eurjchem-2214	291	9	0.3850	0.3850	NUM
eurjchem-2214	291	10	29.0065	29.0065	NUM
eurjchem-2214	291	11	23.9688	23.9688	NUM
eurjchem-2214	291	12	28.3971	28.3971	NUM
eurjchem-2214	291	13	cis-[pt(nh3)2cl2	cis-[pt(nh3)2cl2	NOUN
eurjchem-2214	291	14	]	]	X
eurjchem-2214	291	15	e	e	X
eurjchem-2214	291	16	(	(	PUNCT
eurjchem-2214	291	17	12	12	NUM
eurjchem-2214	291	18	)	)	PUNCT
eurjchem-2214	291	19	0.5428	0.5428	NUM
eurjchem-2214	291	20	33.1362	33.1362	NUM
eurjchem-2214	291	21	25.4844	25.4844	NUM
eurjchem-2214	291	22	30.3570	30.3570	NUM
eurjchem-2214	291	23	‡	‡	NOUN
eurjchem-2214	291	24	tbp	tbp	NOUN
eurjchem-2214	291	25	:	:	PUNCT
eurjchem-2214	291	26	triangular	triangular	ADJ
eurjchem-2214	291	27	bi	bi	NOUN
eurjchem-2214	291	28	-	-	ADJ
eurjchem-2214	291	29	pyramid	pyramid	ADJ
eurjchem-2214	291	30	total	total	ADJ
eurjchem-2214	291	31	number	number	NOUN
eurjchem-2214	291	32	of	of	ADP
eurjchem-2214	291	33	atoms	atom	NOUN
eurjchem-2214	291	34	:	:	PUNCT
eurjchem-2214	291	35	5	5	NUM
eurjchem-2214	291	36	(	(	PUNCT
eurjchem-2214	291	37	no	no	DET
eurjchem-2214	291	38	central	central	ADJ
eurjchem-2214	291	39	atom	atom	NOUN
eurjchem-2214	291	40	)	)	PUNCT
eurjchem-2214	291	41	uebd	uebd	ADJ
eurjchem-2214	291	42	:	:	PUNCT
eurjchem-2214	291	43	unequal	unequal	ADJ
eurjchem-2214	291	44	bond	bond	NOUN
eurjchem-2214	291	45	distances	distance	NOUN
eurjchem-2214	291	46	;	;	PUNCT
eurjchem-2214	291	47	ebd	ebd	ADJ
eurjchem-2214	291	48	:	:	PUNCT
eurjchem-2214	291	49	equal	equal	ADJ
eurjchem-2214	291	50	bond	bond	NOUN
eurjchem-2214	291	51	distances	distance	NOUN
eurjchem-2214	291	52	.	.	PUNCT
eurjchem-2214	292	1	a	a	DET
eurjchem-2214	292	2	planar	planar	ADJ
eurjchem-2214	292	3	square	square	NOUN
eurjchem-2214	292	4	(	(	PUNCT
eurjchem-2214	292	5	with	with	ADP
eurjchem-2214	292	6	central	central	ADJ
eurjchem-2214	292	7	atom	atom	NOUN
eurjchem-2214	292	8	)	)	PUNCT
eurjchem-2214	292	9	5	5	NUM
eurjchem-2214	292	10	atoms	atom	NOUN
eurjchem-2214	292	11	[	[	X
eurjchem-2214	292	12	38	38	NUM
eurjchem-2214	292	13	]	]	PUNCT
eurjchem-2214	292	14	.	.	PUNCT
eurjchem-2214	293	1	b	b	X
eurjchem-2214	293	2	tetrahedron	tetrahedron	NOUN
eurjchem-2214	293	3	(	(	PUNCT
eurjchem-2214	293	4	with	with	ADP
eurjchem-2214	293	5	central	central	ADJ
eurjchem-2214	293	6	atom	atom	NOUN
eurjchem-2214	293	7	)	)	PUNCT
eurjchem-2214	293	8	5	5	NUM
eurjchem-2214	293	9	atoms	atom	NOUN
eurjchem-2214	293	10	[	[	X
eurjchem-2214	293	11	39	39	NUM
eurjchem-2214	293	12	]	]	PUNCT
eurjchem-2214	293	13	.	.	PUNCT
eurjchem-2214	294	1	c	c	PROPN
eurjchem-2214	294	2	reference	reference	NOUN
eurjchem-2214	294	3	[	[	X
eurjchem-2214	294	4	40	40	NUM
eurjchem-2214	294	5	]	]	PUNCT
eurjchem-2214	294	6	.	.	PUNCT
eurjchem-2214	295	1	d	d	X
eurjchem-2214	295	2	reference	reference	NOUN
eurjchem-2214	295	3	[	[	X
eurjchem-2214	295	4	41	41	NUM
eurjchem-2214	295	5	]	]	PUNCT
eurjchem-2214	295	6	.	.	PUNCT
eurjchem-2214	296	1	e	e	PROPN
eurjchem-2214	296	2	reference	reference	NOUN
eurjchem-2214	296	3	[	[	X
eurjchem-2214	296	4	42	42	NUM
eurjchem-2214	296	5	]	]	PUNCT
eurjchem-2214	296	6	.	.	PUNCT
eurjchem-2214	297	1	figure	figure	NOUN
eurjchem-2214	297	2	5	5	NUM
eurjchem-2214	297	3	.	.	PUNCT
eurjchem-2214	297	4	comparison	comparison	NOUN
eurjchem-2214	297	5	of	of	ADP
eurjchem-2214	297	6	csm	csm	NOUN
eurjchem-2214	297	7	and	and	CCONJ
eurjchem-2214	297	8	angular	angular	ADJ
eurjchem-2214	297	9	dispositions	disposition	NOUN
eurjchem-2214	297	10	.	.	PUNCT
eurjchem-2214	298	1	a	a	DET
eurjchem-2214	298	2	comparison	comparison	NOUN
eurjchem-2214	298	3	with	with	ADP
eurjchem-2214	298	4	planar	planar	ADJ
eurjchem-2214	298	5	square	square	ADJ
eurjchem-2214	298	6	trans-[nicl2	trans-[nicl2	X
eurjchem-2214	298	7	(	(	PUNCT
eurjchem-2214	298	8	pph3)2	pph3)2	PROPN
eurjchem-2214	298	9	]	]	X
eurjchem-2214	298	10	·	·	PUNCT
eurjchem-2214	298	11	2ch2cl2	2ch2cl2	NUM
eurjchem-2214	298	12	(	(	PUNCT
eurjchem-2214	298	13	7	7	NUM
eurjchem-2214	298	14	)	)	PUNCT
eurjchem-2214	298	15	and	and	CCONJ
eurjchem-2214	298	16	its	its	PRON
eurjchem-2214	298	17	tetrahedral	tetrahedral	ADJ
eurjchem-2214	298	18	analogue	analogue	NOUN
eurjchem-2214	298	19	exemplifies	exemplify	VERB
eurjchem-2214	298	20	the	the	DET
eurjchem-2214	298	21	utility	utility	NOUN
eurjchem-2214	298	22	of	of	ADP
eurjchem-2214	298	23	csm	csm	NOUN
eurjchem-2214	298	24	[	[	X
eurjchem-2214	298	25	45,46	45,46	NOUN
eurjchem-2214	298	26	]	]	PUNCT
eurjchem-2214	298	27	.	.	PUNCT
eurjchem-2214	299	1	for	for	ADP
eurjchem-2214	299	2	compound	compound	NOUN
eurjchem-2214	299	3	7	7	NUM
eurjchem-2214	299	4	,	,	PUNCT
eurjchem-2214	299	5	csm	csm	NOUN
eurjchem-2214	299	6	(	(	PUNCT
eurjchem-2214	299	7	planar	planar	ADJ
eurjchem-2214	299	8	square	square	NOUN
eurjchem-2214	299	9	)	)	PUNCT
eurjchem-2214	299	10	=	=	SYM
eurjchem-2214	299	11	0.1003	0.1003	NUM
eurjchem-2214	299	12	,	,	PUNCT
eurjchem-2214	299	13	csm	csm	NOUN
eurjchem-2214	299	14	(	(	PUNCT
eurjchem-2214	299	15	tetrahedral	tetrahedral	ADJ
eurjchem-2214	299	16	)	)	PUNCT
eurjchem-2214	299	17	=	=	SYM
eurjchem-2214	299	18	33.4002	33.4002	NUM
eurjchem-2214	299	19	,	,	PUNCT
eurjchem-2214	299	20	on	on	ADP
eurjchem-2214	299	21	the	the	DET
eurjchem-2214	299	22	contrary	contrary	NOUN
eurjchem-2214	299	23	,	,	PUNCT
eurjchem-2214	299	24	for	for	ADP
eurjchem-2214	299	25	its	its	PRON
eurjchem-2214	299	26	tetrahedral	tetrahedral	ADJ
eurjchem-2214	299	27	analogue	analogue	NOUN
eurjchem-2214	299	28	(	(	PUNCT
eurjchem-2214	299	29	8)	8)	NUM
eurjchem-2214	299	30	,	,	PUNCT
eurjchem-2214	299	31	csm	csm	NOUN
eurjchem-2214	299	32	(	(	PUNCT
eurjchem-2214	299	33	planar	planar	ADJ
eurjchem-2214	299	34	square	square	NOUN
eurjchem-2214	299	35	)	)	PUNCT
eurjchem-2214	299	36	=	=	SYM
eurjchem-2214	299	37	25.4633	25.4633	NUM
eurjchem-2214	299	38	,	,	PUNCT
eurjchem-2214	299	39	csm	csm	NOUN
eurjchem-2214	299	40	(	(	PUNCT
eurjchem-2214	299	41	tetrahedral	tetrahedral	ADJ
eurjchem-2214	299	42	)	)	PUNCT
eurjchem-2214	299	43	=	=	SYM
eurjchem-2214	299	44	0.8986	0.8986	NUM
eurjchem-2214	299	45	.	.	PUNCT
eurjchem-2214	300	1	csms	csm	NOUN
eurjchem-2214	300	2	associated	associate	VERB
eurjchem-2214	300	3	with	with	ADP
eurjchem-2214	300	4	complexes	complex	NOUN
eurjchem-2214	300	5	9	9	NUM
eurjchem-2214	300	6	-	-	SYM
eurjchem-2214	300	7	11	11	NUM
eurjchem-2214	300	8	clearly	clearly	ADV
eurjchem-2214	300	9	demonstrate	demonstrate	VERB
eurjchem-2214	300	10	the	the	DET
eurjchem-2214	300	11	planar	planar	ADJ
eurjchem-2214	300	12	square	square	ADJ
eurjchem-2214	300	13	structures	structure	NOUN
eurjchem-2214	300	14	associated	associate	VERB
eurjchem-2214	300	15	with	with	ADP
eurjchem-2214	300	16	them	they	PRON
eurjchem-2214	300	17	.	.	PUNCT
eurjchem-2214	301	1	compounds	compound	VERB
eurjchem-2214	301	2	9	9	NUM
eurjchem-2214	301	3	and	and	CCONJ
eurjchem-2214	301	4	10	10	NUM
eurjchem-2214	301	5	stabilize	stabilize	NOUN
eurjchem-2214	301	6	as	as	ADP
eurjchem-2214	301	7	trans	trans	NOUN
eurjchem-2214	301	8	isomers	isomer	NOUN
eurjchem-2214	301	9	for	for	ADP
eurjchem-2214	301	10	steric	steric	ADJ
eurjchem-2214	301	11	reasons	reason	NOUN
eurjchem-2214	301	12	and	and	CCONJ
eurjchem-2214	301	13	are	be	AUX
eurjchem-2214	301	14	vulnerable	vulnerable	ADJ
eurjchem-2214	301	15	to	to	ADP
eurjchem-2214	301	16	aquation	aquation	NOUN
eurjchem-2214	301	17	leading	lead	VERB
eurjchem-2214	301	18	to	to	ADP
eurjchem-2214	301	19	octahedral	octahedral	ADJ
eurjchem-2214	301	20	geometry	geometry	NOUN
eurjchem-2214	301	21	and	and	CCONJ
eurjchem-2214	301	22	lose	lose	VERB
eurjchem-2214	301	23	the	the	DET
eurjchem-2214	301	24	mandatory	mandatory	ADJ
eurjchem-2214	301	25	planar	planar	ADJ
eurjchem-2214	301	26	geometry	geometry	NOUN
eurjchem-2214	301	27	.	.	PUNCT
eurjchem-2214	302	1	interestingly	interestingly	ADV
eurjchem-2214	302	2	,	,	PUNCT
eurjchem-2214	302	3	compound	compound	NOUN
eurjchem-2214	302	4	11	11	NUM
eurjchem-2214	302	5	,	,	PUNCT
eurjchem-2214	302	6	stabilizes	stabilize	VERB
eurjchem-2214	302	7	in	in	ADP
eurjchem-2214	302	8	cis	cis	NOUN
eurjchem-2214	302	9	form	form	NOUN
eurjchem-2214	302	10	but	but	CCONJ
eurjchem-2214	302	11	yet	yet	ADV
eurjchem-2214	302	12	again	again	ADV
eurjchem-2214	302	13	is	be	AUX
eurjchem-2214	302	14	amenable	amenable	ADJ
eurjchem-2214	302	15	to	to	ADP
eurjchem-2214	302	16	aquation	aquation	NOUN
eurjchem-2214	302	17	.	.	PUNCT
eurjchem-2214	303	1	the	the	DET
eurjchem-2214	303	2	susceptibility	susceptibility	NOUN
eurjchem-2214	303	3	of	of	ADP
eurjchem-2214	303	4	compounds	compound	NOUN
eurjchem-2214	303	5	9	9	NUM
eurjchem-2214	303	6	-	-	SYM
eurjchem-2214	303	7	11	11	NUM
eurjchem-2214	303	8	to	to	ADP
eurjchem-2214	303	9	aquation	aquation	NOUN
eurjchem-2214	303	10	is	be	AUX
eurjchem-2214	303	11	because	because	SCONJ
eurjchem-2214	303	12	of	of	ADP
eurjchem-2214	303	13	the	the	DET
eurjchem-2214	303	14	low	low	ADJ
eurjchem-2214	303	15	lfse	lfse	NOUN
eurjchem-2214	303	16	associated	associate	VERB
eurjchem-2214	303	17	with	with	ADP
eurjchem-2214	303	18	monodentate	monodentate	ADJ
eurjchem-2214	303	19	thiolato	thiolato	NOUN
eurjchem-2214	303	20	donors	donor	NOUN
eurjchem-2214	303	21	whereas	whereas	SCONJ
eurjchem-2214	303	22	the	the	DET
eurjchem-2214	303	23	“	"	PUNCT
eurjchem-2214	303	24	chuck	chuck	NOUN
eurjchem-2214	303	25	”	"	PUNCT
eurjchem-2214	303	26	,	,	PUNCT
eurjchem-2214	303	27	pyrrolididine	pyrrolididine	NOUN
eurjchem-2214	303	28	carbodithioate	carbodithioate	ADJ
eurjchem-2214	303	29	anion	anion	NOUN
eurjchem-2214	303	30	stabilizes	stabilize	VERB
eurjchem-2214	303	31	the	the	DET
eurjchem-2214	303	32	planar	planar	ADJ
eurjchem-2214	303	33	shape	shape	NOUN
eurjchem-2214	303	34	.	.	PUNCT
eurjchem-2214	304	1	single	single	ADJ
eurjchem-2214	304	2	crystal	crystal	PROPN
eurjchem-2214	304	3	x	x	PROPN
eurjchem-2214	304	4	-	-	NOUN
eurjchem-2214	304	5	ray	ray	NOUN
eurjchem-2214	304	6	structure	structure	NOUN
eurjchem-2214	304	7	of	of	ADP
eurjchem-2214	304	8	cis	cis	NOUN
eurjchem-2214	304	9	-	-	PUNCT
eurjchem-2214	304	10	platin	platin	NOUN
eurjchem-2214	304	11	showed	show	VERB
eurjchem-2214	304	12	a	a	DET
eurjchem-2214	304	13	planar	planar	ADJ
eurjchem-2214	304	14	square	square	ADJ
eurjchem-2214	304	15	structure	structure	NOUN
eurjchem-2214	304	16	around	around	ADP
eurjchem-2214	304	17	platinum(ii	platinum(ii	NOUN
eurjchem-2214	304	18	)	)	PUNCT
eurjchem-2214	304	19	(	(	PUNCT
eurjchem-2214	304	20	12	12	NUM
eurjchem-2214	304	21	)	)	PUNCT
eurjchem-2214	305	1	[	[	X
eurjchem-2214	305	2	42	42	NUM
eurjchem-2214	305	3	]	]	PUNCT
eurjchem-2214	305	4	.	.	PUNCT
eurjchem-2214	306	1	csm	csm	NOUN
eurjchem-2214	306	2	for	for	ADP
eurjchem-2214	306	3	planar	planar	ADJ
eurjchem-2214	306	4	square	square	ADJ
eurjchem-2214	306	5	shape	shape	NOUN
eurjchem-2214	306	6	of	of	ADP
eurjchem-2214	306	7	the	the	DET
eurjchem-2214	306	8	complex	complex	ADJ
eurjchem-2214	306	9	12	12	NUM
eurjchem-2214	306	10	is	be	AUX
eurjchem-2214	306	11	evaluated	evaluate	VERB
eurjchem-2214	306	12	to	to	PART
eurjchem-2214	306	13	be	be	AUX
eurjchem-2214	306	14	0.5428	0.5428	NUM
eurjchem-2214	306	15	and	and	CCONJ
eurjchem-2214	306	16	for	for	ADP
eurjchem-2214	306	17	tetrahedral	tetrahedral	ADJ
eurjchem-2214	306	18	geometry	geometry	NOUN
eurjchem-2214	306	19	it	it	PRON
eurjchem-2214	306	20	was	be	AUX
eurjchem-2214	306	21	found	find	VERB
eurjchem-2214	306	22	to	to	PART
eurjchem-2214	306	23	be	be	AUX
eurjchem-2214	306	24	33.1362	33.1362	NUM
eurjchem-2214	306	25	.	.	PUNCT
eurjchem-2214	307	1	the	the	DET
eurjchem-2214	307	2	csm	csm	NOUN
eurjchem-2214	307	3	values	value	NOUN
eurjchem-2214	307	4	are	be	AUX
eurjchem-2214	307	5	of	of	ADP
eurjchem-2214	307	6	the	the	DET
eurjchem-2214	307	7	same	same	ADJ
eurjchem-2214	307	8	order	order	NOUN
eurjchem-2214	307	9	as	as	SCONJ
eurjchem-2214	307	10	observed	observe	VERB
eurjchem-2214	307	11	for	for	ADP
eurjchem-2214	307	12	the	the	DET
eurjchem-2214	307	13	complexes	complex	NOUN
eurjchem-2214	307	14	1	1	NUM
eurjchem-2214	307	15	-	-	SYM
eurjchem-2214	307	16	5	5	NUM
eurjchem-2214	307	17	.	.	PUNCT
eurjchem-2214	307	18	two	two	NUM
eurjchem-2214	307	19	other	other	ADJ
eurjchem-2214	307	20	possible	possible	ADJ
eurjchem-2214	307	21	shapes	shape	NOUN
eurjchem-2214	307	22	viz	viz	PROPN
eurjchem-2214	307	23	.	.	PROPN
eurjchem-2214	307	24	,	,	PUNCT
eurjchem-2214	307	25	trigonal	trigonal	PROPN
eurjchem-2214	307	26	bipyramidal	bipyramidal	NOUN
eurjchem-2214	307	27	(	(	PUNCT
eurjchem-2214	307	28	uebd	uebd	ADJ
eurjchem-2214	307	29	)	)	PUNCT
eurjchem-2214	307	30	(	(	PUNCT
eurjchem-2214	307	31	containing	contain	VERB
eurjchem-2214	307	32	five	five	NUM
eurjchem-2214	307	33	atoms	atom	NOUN
eurjchem-2214	307	34	,	,	PUNCT
eurjchem-2214	307	35	no	no	DET
eurjchem-2214	307	36	central	central	ADJ
eurjchem-2214	307	37	atom	atom	NOUN
eurjchem-2214	307	38	and	and	CCONJ
eurjchem-2214	307	39	unequal	unequal	ADJ
eurjchem-2214	307	40	bond	bond	NOUN
eurjchem-2214	307	41	distances	distance	NOUN
eurjchem-2214	307	42	)	)	PUNCT
eurjchem-2214	307	43	and	and	CCONJ
eurjchem-2214	307	44	trigonal	trigonal	ADJ
eurjchem-2214	307	45	bipyramidal	bipyramidal	NOUN
eurjchem-2214	307	46	(	(	PUNCT
eurjchem-2214	307	47	ebd	ebd	PROPN
eurjchem-2214	307	48	)	)	PUNCT
eurjchem-2214	307	49	(	(	PUNCT
eurjchem-2214	307	50	containing	contain	VERB
eurjchem-2214	307	51	five	five	NUM
eurjchem-2214	307	52	atoms	atom	NOUN
eurjchem-2214	307	53	,	,	PUNCT
eurjchem-2214	307	54	no	no	DET
eurjchem-2214	307	55	central	central	ADJ
eurjchem-2214	307	56	atom	atom	NOUN
eurjchem-2214	307	57	and	and	CCONJ
eurjchem-2214	307	58	equal	equal	ADJ
eurjchem-2214	307	59	bond	bond	NOUN
eurjchem-2214	307	60	distances	distance	NOUN
eurjchem-2214	307	61	)	)	PUNCT
eurjchem-2214	307	62	have	have	AUX
eurjchem-2214	307	63	been	be	AUX
eurjchem-2214	307	64	evaluated	evaluate	VERB
eurjchem-2214	307	65	for	for	ADP
eurjchem-2214	307	66	all	all	DET
eurjchem-2214	307	67	the	the	DET
eurjchem-2214	307	68	compounds	compound	NOUN
eurjchem-2214	307	69	1	1	NUM
eurjchem-2214	307	70	-	-	SYM
eurjchem-2214	307	71	12	12	NUM
eurjchem-2214	307	72	and	and	CCONJ
eurjchem-2214	307	73	are	be	AUX
eurjchem-2214	307	74	listed	list	VERB
eurjchem-2214	307	75	in	in	ADP
eurjchem-2214	307	76	table	table	NOUN
eurjchem-2214	307	77	4	4	NUM
eurjchem-2214	307	78	.	.	PUNCT
eurjchem-2214	308	1	the	the	DET
eurjchem-2214	308	2	csm	csm	NOUN
eurjchem-2214	308	3	values	value	NOUN
eurjchem-2214	308	4	for	for	ADP
eurjchem-2214	308	5	the	the	DET
eurjchem-2214	308	6	trigonal	trigonal	ADJ
eurjchem-2214	308	7	bipyramidal	bipyramidal	ADJ
eurjchem-2214	308	8	variants	variant	NOUN
eurjchem-2214	308	9	lie	lie	VERB
eurjchem-2214	308	10	between	between	ADP
eurjchem-2214	308	11	23.3066	23.3066	NUM
eurjchem-2214	308	12	and	and	CCONJ
eurjchem-2214	308	13	30.7708	30.7708	NUM
eurjchem-2214	308	14	,	,	PUNCT
eurjchem-2214	308	15	clearly	clearly	ADV
eurjchem-2214	308	16	ruling	rule	VERB
eurjchem-2214	308	17	out	out	ADP
eurjchem-2214	308	18	the	the	DET
eurjchem-2214	308	19	possibility	possibility	NOUN
eurjchem-2214	308	20	of	of	ADP
eurjchem-2214	308	21	the	the	DET
eurjchem-2214	308	22	compounds	compound	NOUN
eurjchem-2214	308	23	assuming	assume	VERB
eurjchem-2214	308	24	tbp	tbp	NOUN
eurjchem-2214	308	25	geometry	geometry	NOUN
eurjchem-2214	308	26	.	.	PUNCT
eurjchem-2214	309	1	the	the	DET
eurjchem-2214	309	2	csm	csm	NOUN
eurjchem-2214	309	3	analysis	analysis	NOUN
eurjchem-2214	309	4	of	of	ADP
eurjchem-2214	309	5	compounds	compound	NOUN
eurjchem-2214	309	6	1	1	NUM
eurjchem-2214	309	7	-	-	SYM
eurjchem-2214	309	8	12	12	NUM
eurjchem-2214	309	9	reveals	reveal	VERB
eurjchem-2214	309	10	that	that	SCONJ
eurjchem-2214	309	11	compounds	compound	VERB
eurjchem-2214	309	12	1	1	NUM
eurjchem-2214	309	13	-	-	SYM
eurjchem-2214	309	14	5	5	NUM
eurjchem-2214	309	15	are	be	AUX
eurjchem-2214	309	16	stabilized	stabilize	VERB
eurjchem-2214	309	17	in	in	ADP
eurjchem-2214	309	18	planar	planar	ADJ
eurjchem-2214	309	19	square	square	ADJ
eurjchem-2214	309	20	geometry	geometry	NOUN
eurjchem-2214	309	21	,	,	PUNCT
eurjchem-2214	309	22	which	which	PRON
eurjchem-2214	309	23	is	be	AUX
eurjchem-2214	309	24	ideal	ideal	ADJ
eurjchem-2214	309	25	for	for	ADP
eurjchem-2214	309	26	anti	anti	ADJ
eurjchem-2214	309	27	-	-	ADJ
eurjchem-2214	309	28	cancer	cancer	ADJ
eurjchem-2214	309	29	activity	activity	NOUN
eurjchem-2214	309	30	,	,	PUNCT
eurjchem-2214	309	31	and	and	CCONJ
eurjchem-2214	309	32	have	have	VERB
eurjchem-2214	309	33	shape	shape	NOUN
eurjchem-2214	309	34	measure	measure	NOUN
eurjchem-2214	309	35	values	value	NOUN
eurjchem-2214	309	36	comparable	comparable	ADJ
eurjchem-2214	309	37	to	to	ADP
eurjchem-2214	309	38	cis	cis	NOUN
eurjchem-2214	309	39	-	-	PUNCT
eurjchem-2214	309	40	platin	platin	NOUN
eurjchem-2214	309	41	.	.	PUNCT
eurjchem-2214	310	1	4	4	X
eurjchem-2214	310	2	.	.	X
eurjchem-2214	310	3	conclusions	conclusion	NOUN
eurjchem-2214	310	4	thioureide	thioureide	VERB
eurjchem-2214	310	5	stretching	stretch	VERB
eurjchem-2214	310	6	bands	band	NOUN
eurjchem-2214	310	7	observed	observe	VERB
eurjchem-2214	310	8	for	for	ADP
eurjchem-2214	310	9	the	the	DET
eurjchem-2214	310	10	compounds	compound	NOUN
eurjchem-2214	310	11	1	1	NUM
eurjchem-2214	310	12	-	-	SYM
eurjchem-2214	310	13	5	5	NUM
eurjchem-2214	310	14	are	be	AUX
eurjchem-2214	310	15	in	in	ADP
eurjchem-2214	310	16	the	the	DET
eurjchem-2214	310	17	range	range	NOUN
eurjchem-2214	310	18	between	between	ADP
eurjchem-2214	310	19	1528	1528	NUM
eurjchem-2214	310	20	and1540	and1540	NOUN
eurjchem-2214	310	21	cm-1	cm-1	PROPN
eurjchem-2214	310	22	and	and	CCONJ
eurjchem-2214	310	23	are	be	AUX
eurjchem-2214	310	24	larger	large	ADJ
eurjchem-2214	310	25	than	than	ADP
eurjchem-2214	310	26	that	that	PRON
eurjchem-2214	310	27	observed	observe	VERB
eurjchem-2214	310	28	for	for	ADP
eurjchem-2214	310	29	the	the	DET
eurjchem-2214	310	30	parent	parent	NOUN
eurjchem-2214	310	31	bis	bis	ADJ
eurjchem-2214	310	32	-	-	PUNCT
eurjchem-2214	310	33	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	310	34	viz	viz	PROPN
eurjchem-2214	310	35	.	.	PROPN
eurjchem-2214	310	36	,	,	PUNCT
eurjchem-2214	310	37	1490	1490	NUM
eurjchem-2214	310	38	cm-1	cm-1	NOUN
eurjchem-2214	310	39	.	.	PUNCT
eurjchem-2214	311	1	the	the	DET
eurjchem-2214	311	2	observed	observe	VERB
eurjchem-2214	311	3	increase	increase	NOUN
eurjchem-2214	311	4	in	in	ADP
eurjchem-2214	311	5	νc	νc	NOUN
eurjchem-2214	311	6	-	-	PUNCT
eurjchem-2214	311	7	n	n	NOUN
eurjchem-2214	311	8	is	be	AUX
eurjchem-2214	311	9	because	because	SCONJ
eurjchem-2214	311	10	of	of	ADP
eurjchem-2214	311	11	the	the	DET
eurjchem-2214	311	12	π	π	ADJ
eurjchem-2214	311	13	-	-	ADJ
eurjchem-2214	311	14	acidic	acidic	ADJ
eurjchem-2214	311	15	character	character	NOUN
eurjchem-2214	311	16	of	of	ADP
eurjchem-2214	311	17	the	the	DET
eurjchem-2214	311	18	phosphines	phosphine	NOUN
eurjchem-2214	311	19	enabling	enable	VERB
eurjchem-2214	311	20	a	a	DET
eurjchem-2214	311	21	higher	high	ADJ
eurjchem-2214	311	22	delocalization	delocalization	NOUN
eurjchem-2214	311	23	of	of	ADP
eurjchem-2214	311	24	electron	electron	NOUN
eurjchem-2214	311	25	density.1h	density.1h	PROPN
eurjchem-2214	311	26	nmr	nmr	NOUN
eurjchem-2214	311	27	of	of	ADP
eurjchem-2214	311	28	the	the	DET
eurjchem-2214	311	29	complexes	complex	NOUN
eurjchem-2214	311	30	show	show	VERB
eurjchem-2214	311	31	a	a	DET
eurjchem-2214	311	32	larger	large	ADJ
eurjchem-2214	311	33	deshielding	deshielding	NOUN
eurjchem-2214	311	34	of	of	ADP
eurjchem-2214	311	35	the	the	DET
eurjchem-2214	311	36	protons	proton	NOUN
eurjchem-2214	311	37	adjacent	adjacent	ADJ
eurjchem-2214	311	38	to	to	ADP
eurjchem-2214	311	39	nitrogen	nitrogen	NOUN
eurjchem-2214	311	40	atom	atom	NOUN
eurjchem-2214	311	41	compared	compare	VERB
eurjchem-2214	311	42	to	to	ADP
eurjchem-2214	311	43	the	the	DET
eurjchem-2214	311	44	ones	one	NOUN
eurjchem-2214	311	45	away	away	ADV
eurjchem-2214	311	46	from	from	ADP
eurjchem-2214	311	47	it	it	PRON
eurjchem-2214	311	48	.	.	PUNCT
eurjchem-2214	312	1	13c	13c	NOUN
eurjchem-2214	312	2	nmr	nmr	NOUN
eurjchem-2214	312	3	chemical	chemical	ADJ
eurjchem-2214	312	4	shifts	shift	NOUN
eurjchem-2214	312	5	of	of	ADP
eurjchem-2214	312	6	the	the	DET
eurjchem-2214	312	7	thioureide	thioureide	ADJ
eurjchem-2214	312	8	carbon	carbon	NOUN
eurjchem-2214	312	9	atoms	atom	NOUN
eurjchem-2214	312	10	appear	appear	VERB
eurjchem-2214	312	11	in	in	ADP
eurjchem-2214	312	12	the	the	DET
eurjchem-2214	312	13	range	range	NOUN
eurjchem-2214	312	14	δ	δ	PROPN
eurjchem-2214	312	15	195.4	195.4	NUM
eurjchem-2214	312	16	-	-	SYM
eurjchem-2214	312	17	200.6	200.6	NUM
eurjchem-2214	312	18	ppm	ppm	NOUN
eurjchem-2214	312	19	and	and	CCONJ
eurjchem-2214	312	20	correlate	correlate	VERB
eurjchem-2214	312	21	well	well	ADV
eurjchem-2214	312	22	with	with	ADP
eurjchem-2214	312	23	relatively	relatively	ADV
eurjchem-2214	312	24	higher	high	ADJ
eurjchem-2214	312	25	ir	ir	NOUN
eurjchem-2214	312	26	stretching	stretch	VERB
eurjchem-2214	312	27	bands	band	NOUN
eurjchem-2214	312	28	.	.	PUNCT
eurjchem-2214	313	1	31p	31p	NOUN
eurjchem-2214	313	2	nmr	nmr	NOUN
eurjchem-2214	313	3	chemical	chemical	ADJ
eurjchem-2214	313	4	shifts	shift	NOUN
eurjchem-2214	313	5	of	of	ADP
eurjchem-2214	313	6	the	the	DET
eurjchem-2214	313	7	mixed	mixed	ADJ
eurjchem-2214	313	8	ligand	ligand	NOUN
eurjchem-2214	313	9	complexes	complex	NOUN
eurjchem-2214	313	10	showed	show	VERB
eurjchem-2214	313	11	large	large	ADJ
eurjchem-2214	313	12	deshielding	deshielding	NOUN
eurjchem-2214	313	13	with	with	ADP
eurjchem-2214	313	14	reference	reference	NOUN
eurjchem-2214	313	15	to	to	ADP
eurjchem-2214	313	16	free	free	ADJ
eurjchem-2214	313	17	phosphines	phosphine	NOUN
eurjchem-2214	313	18	signifying	signify	VERB
eurjchem-2214	313	19	strong	strong	ADJ
eurjchem-2214	313	20	complexation	complexation	NOUN
eurjchem-2214	313	21	.	.	PUNCT
eurjchem-2214	314	1	in	in	ADP
eurjchem-2214	314	2	cyclic	cyclic	ADJ
eurjchem-2214	314	3	voltammetric	voltammetric	ADJ
eurjchem-2214	314	4	analysis	analysis	NOUN
eurjchem-2214	314	5	,	,	PUNCT
eurjchem-2214	314	6	reduction	reduction	NOUN
eurjchem-2214	314	7	potentials	potential	NOUN
eurjchem-2214	314	8	of	of	ADP
eurjchem-2214	314	9	the	the	DET
eurjchem-2214	314	10	mixed	mixed	ADJ
eurjchem-2214	314	11	ligand	ligand	NOUN
eurjchem-2214	314	12	complexes	complex	NOUN
eurjchem-2214	314	13	are	be	AUX
eurjchem-2214	314	14	much	much	ADV
eurjchem-2214	314	15	lower	low	ADJ
eurjchem-2214	314	16	than	than	SCONJ
eurjchem-2214	314	17	their	their	PRON
eurjchem-2214	314	18	parent	parent	NOUN
eurjchem-2214	314	19	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2214	314	20	because	because	SCONJ
eurjchem-2214	314	21	of	of	ADP
eurjchem-2214	314	22	the	the	DET
eurjchem-2214	314	23	π	π	ADJ
eurjchem-2214	314	24	-	-	ADJ
eurjchem-2214	314	25	acidic	acidic	ADJ
eurjchem-2214	314	26	phosphines	phosphine	NOUN
eurjchem-2214	314	27	.	.	PUNCT
eurjchem-2214	315	1	in	in	ADP
eurjchem-2214	315	2	the	the	DET
eurjchem-2214	315	3	case	case	NOUN
eurjchem-2214	315	4	of	of	ADP
eurjchem-2214	315	5	mixed	mixed	ADJ
eurjchem-2214	315	6	divalent	divalent	NOUN
eurjchem-2214	315	7	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2214	315	8	complexes	complex	NOUN
eurjchem-2214	315	9	investigated	investigate	VERB
eurjchem-2214	315	10	in	in	ADP
eurjchem-2214	315	11	the	the	DET
eurjchem-2214	315	12	present	present	ADJ
eurjchem-2214	315	13	study	study	NOUN
eurjchem-2214	315	14	,	,	PUNCT
eurjchem-2214	315	15	ni	ni	PROPN
eurjchem-2214	315	16	-	-	PUNCT
eurjchem-2214	315	17	s	s	PROPN
eurjchem-2214	315	18	,	,	PUNCT
eurjchem-2214	315	19	ni	ni	PROPN
eurjchem-2214	315	20	-	-	PROPN
eurjchem-2214	315	21	p	p	PROPN
eurjchem-2214	315	22	,	,	PUNCT
eurjchem-2214	315	23	ni	ni	NOUN
eurjchem-2214	315	24	-	-	PUNCT
eurjchem-2214	315	25	n	n	CCONJ
eurjchem-2214	315	26	,	,	PUNCT
eurjchem-2214	315	27	and	and	CCONJ
eurjchem-2214	315	28	ni	ni	PROPN
eurjchem-2214	315	29	-	-	PROPN
eurjchem-2214	315	30	c	c	PROPN
eurjchem-2214	315	31	bond	bond	NOUN
eurjchem-2214	315	32	distances	distance	NOUN
eurjchem-2214	315	33	and	and	CCONJ
eurjchem-2214	315	34	n	n	CCONJ
eurjchem-2214	315	35	-	-	PUNCT
eurjchem-2214	315	36	ni	ni	NOUN
eurjchem-2214	315	37	-	-	PUNCT
eurjchem-2214	315	38	p	p	PROPN
eurjchem-2214	315	39	,	,	PUNCT
eurjchem-2214	315	40	n	n	CCONJ
eurjchem-2214	315	41	-	-	PUNCT
eurjchem-2214	315	42	ni	ni	ADJ
eurjchem-2214	315	43	-	-	PROPN
eurjchem-2214	315	44	p(4	p(4	PROPN
eurjchem-2214	315	45	-	-	PUNCT
eurjchem-2214	315	46	mp	mp	NOUN
eurjchem-2214	315	47	)	)	PUNCT
eurjchem-2214	315	48	,	,	PUNCT
eurjchem-2214	315	49	(	(	PUNCT
eurjchem-2214	315	50	n)c	n)c	ADJ
eurjchem-2214	315	51	-	-	PUNCT
eurjchem-2214	315	52	ni	ni	NOUN
eurjchem-2214	315	53	-	-	PUNCT
eurjchem-2214	315	54	p	p	NOUN
eurjchem-2214	315	55	,	,	PUNCT
eurjchem-2214	315	56	and	and	CCONJ
eurjchem-2214	315	57	p	p	X
eurjchem-2214	315	58	-	-	PUNCT
eurjchem-2214	315	59	ni	ni	NOUN
eurjchem-2214	315	60	-	-	ADJ
eurjchem-2214	315	61	p	p	ADJ
eurjchem-2214	315	62	bond	bond	NOUN
eurjchem-2214	315	63	angles	angle	NOUN
eurjchem-2214	315	64	varied	varied	ADJ
eurjchem-2214	315	65	according	accord	VERB
eurjchem-2214	315	66	to	to	ADP
eurjchem-2214	315	67	the	the	DET
eurjchem-2214	315	68	steric	steric	ADJ
eurjchem-2214	315	69	and	and	CCONJ
eurjchem-2214	315	70	electronic	electronic	ADJ
eurjchem-2214	315	71	effects	effect	NOUN
eurjchem-2214	315	72	of	of	ADP
eurjchem-2214	315	73	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-2214	315	74	/	/	SYM
eurjchem-2214	315	75	tri(4	tri(4	NOUN
eurjchem-2214	315	76	-	-	PUNCT
eurjchem-2214	315	77	methylphenyl	methylphenyl	NOUN
eurjchem-2214	315	78	)	)	PUNCT
eurjchem-2214	315	79	phosphine	phosphine	NOUN
eurjchem-2214	315	80	/	/	SYM
eurjchem-2214	315	81	cn-/dppe	cn-/dppe	PROPN
eurjchem-2214	315	82	.	.	PUNCT
eurjchem-2214	316	1	in	in	ADP
eurjchem-2214	316	2	particular	particular	ADJ
eurjchem-2214	316	3	,	,	PUNCT
eurjchem-2214	316	4	the	the	DET
eurjchem-2214	316	5	ni	ni	PROPN
eurjchem-2214	316	6	-	-	PUNCT
eurjchem-2214	316	7	s	s	PART
eurjchem-2214	316	8	distances	distance	NOUN
eurjchem-2214	316	9	vary	vary	VERB
eurjchem-2214	316	10	in	in	ADP
eurjchem-2214	316	11	accordance	accordance	NOUN
eurjchem-2214	316	12	with	with	ADP
eurjchem-2214	316	13	the	the	DET
eurjchem-2214	316	14	variation	variation	NOUN
eurjchem-2214	316	15	of	of	ADP
eurjchem-2214	316	16	trans	trans	PROPN
eurjchem-2214	316	17	influences	influence	NOUN
eurjchem-2214	316	18	of	of	ADP
eurjchem-2214	316	19	phosphine	phosphine	NOUN
eurjchem-2214	316	20	,	,	PUNCT
eurjchem-2214	316	21	cyanide	cyanide	NOUN
eurjchem-2214	316	22	or	or	CCONJ
eurjchem-2214	316	23	isothiocyanate	isothiocyanate	NOUN
eurjchem-2214	316	24	leading	lead	VERB
eurjchem-2214	316	25	to	to	ADP
eurjchem-2214	316	26	heterobidentate	heterobidentate	NOUN
eurjchem-2214	316	27	binding	binding	NOUN
eurjchem-2214	316	28	of	of	ADP
eurjchem-2214	316	29	the	the	DET
eurjchem-2214	316	30	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2214	316	31	.	.	PUNCT
eurjchem-2214	317	1	heterolepticity	heterolepticity	NOUN
eurjchem-2214	317	2	in	in	ADP
eurjchem-2214	317	3	ni	ni	PROPN
eurjchem-2214	317	4	-	-	PUNCT
eurjchem-2214	317	5	s	s	NOUN
eurjchem-2214	317	6	bond	bond	NOUN
eurjchem-2214	317	7	distances	distance	NOUN
eurjchem-2214	317	8	is	be	AUX
eurjchem-2214	317	9	the	the	DET
eurjchem-2214	317	10	largest	large	ADJ
eurjchem-2214	317	11	for	for	ADP
eurjchem-2214	317	12	[	[	PUNCT
eurjchem-2214	317	13	ni	ni	PROPN
eurjchem-2214	317	14	(	(	PUNCT
eurjchem-2214	317	15	pyrdtc)(4	pyrdtc)(4	PROPN
eurjchem-2214	317	16	-	-	PUNCT
eurjchem-2214	317	17	mp)(ncs	mp)(nc	NOUN
eurjchem-2214	317	18	)	)	PUNCT
eurjchem-2214	317	19	]	]	PUNCT
eurjchem-2214	318	1	(	(	PUNCT
eurjchem-2214	318	2	2	2	X
eurjchem-2214	318	3	)	)	PUNCT
eurjchem-2214	318	4	owing	owe	VERB
eurjchem-2214	318	5	to	to	ADP
eurjchem-2214	318	6	the	the	DET
eurjchem-2214	318	7	steric	steric	ADJ
eurjchem-2214	318	8	influence	influence	NOUN
eurjchem-2214	318	9	of	of	ADP
eurjchem-2214	318	10	4	4	NUM
eurjchem-2214	318	11	-	-	PUNCT
eurjchem-2214	318	12	mp	mp	NOUN
eurjchem-2214	318	13	.	.	PUNCT
eurjchem-2214	319	1	the	the	DET
eurjchem-2214	319	2	dppe	dppe	PROPN
eurjchem-2214	319	3	complex	complex	NOUN
eurjchem-2214	319	4	shows	show	VERB
eurjchem-2214	319	5	the	the	DET
eurjchem-2214	319	6	least	least	ADJ
eurjchem-2214	319	7	p	p	NOUN
eurjchem-2214	319	8	-	-	PUNCT
eurjchem-2214	319	9	ni	ni	NOUN
eurjchem-2214	319	10	-	-	ADJ
eurjchem-2214	319	11	p	p	NOUN
eurjchem-2214	319	12	angle	angle	NOUN
eurjchem-2214	319	13	due	due	ADJ
eurjchem-2214	319	14	its	its	PRON
eurjchem-2214	319	15	chelating	chelating	NOUN
eurjchem-2214	319	16	nature	nature	NOUN
eurjchem-2214	319	17	.	.	PUNCT
eurjchem-2214	320	1	all	all	DET
eurjchem-2214	320	2	compounds	compound	NOUN
eurjchem-2214	320	3	showed	show	VERB
eurjchem-2214	320	4	comparable	comparable	ADJ
eurjchem-2214	320	5	thioureide	thioureide	ADJ
eurjchem-2214	320	6	distances	distance	NOUN
eurjchem-2214	320	7	to	to	ADP
eurjchem-2214	320	8	the	the	DET
eurjchem-2214	320	9	parent	parent	NOUN
eurjchem-2214	320	10	[	[	X
eurjchem-2214	320	11	ni(pyrdtc)2	ni(pyrdtc)2	SYM
eurjchem-2214	320	12	]	]	PUNCT
eurjchem-2214	320	13	.	.	PUNCT
eurjchem-2214	321	1	bond	bond	NOUN
eurjchem-2214	321	2	valence	valence	NOUN
eurjchem-2214	321	3	sums	sum	NOUN
eurjchem-2214	321	4	revealed	reveal	VERB
eurjchem-2214	321	5	that	that	SCONJ
eurjchem-2214	321	6	the	the	DET
eurjchem-2214	321	7	nickel	nickel	NOUN
eurjchem-2214	321	8	is	be	AUX
eurjchem-2214	321	9	divalent	divalent	ADJ
eurjchem-2214	321	10	and	and	CCONJ
eurjchem-2214	321	11	the	the	DET
eurjchem-2214	321	12	bonding	bonding	NOUN
eurjchem-2214	321	13	interactions	interaction	NOUN
eurjchem-2214	321	14	are	be	AUX
eurjchem-2214	321	15	primarily	primarily	ADV
eurjchem-2214	321	16	covalent	covalent	ADJ
eurjchem-2214	321	17	.	.	PUNCT
eurjchem-2214	322	1	continuous	continuous	ADJ
eurjchem-2214	322	2	shape	shape	NOUN
eurjchem-2214	322	3	124	124	NUM
eurjchem-2214	322	4	ramalingam	ramalingam	NOUN
eurjchem-2214	322	5	et	et	PROPN
eurjchem-2214	322	6	al	al	PROPN
eurjchem-2214	322	7	.	.	PUNCT
eurjchem-2214	322	8	/	/	SYM
eurjchem-2214	322	9	european	european	PROPN
eurjchem-2214	322	10	journal	journal	PROPN
eurjchem-2214	322	11	of	of	ADP
eurjchem-2214	322	12	chemistry	chemistry	NOUN
eurjchem-2214	322	13	13	13	NUM
eurjchem-2214	322	14	(	(	PUNCT
eurjchem-2214	322	15	1	1	NUM
eurjchem-2214	322	16	)	)	PUNCT
eurjchem-2214	322	17	(	(	PUNCT
eurjchem-2214	322	18	2022	2022	NUM
eurjchem-2214	322	19	)	)	PUNCT
eurjchem-2214	322	20	117	117	NUM
eurjchem-2214	322	21	-	-	SYM
eurjchem-2214	322	22	125	125	NUM
eurjchem-2214	322	23	2022	2022	NUM
eurjchem-2214	322	24	–	–	PUNCT
eurjchem-2214	322	25	european	european	ADJ
eurjchem-2214	322	26	journal	journal	NOUN
eurjchem-2214	322	27	of	of	ADP
eurjchem-2214	322	28	chemistry	chemistry	NOUN
eurjchem-2214	322	29	–	–	PUNCT
eurjchem-2214	322	30	cc	cc	NOUN
eurjchem-2214	322	31	by	by	ADP
eurjchem-2214	322	32	nc	nc	PROPN
eurjchem-2214	322	33	–	–	PUNCT
eurjchem-2214	322	34	doi	doi	NOUN
eurjchem-2214	322	35	:	:	PUNCT
eurjchem-2214	322	36	10.5155	10.5155	NUM
eurjchem-2214	322	37	/	/	SYM
eurjchem-2214	322	38	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	322	39	-	-	SYM
eurjchem-2214	322	40	125.2214	125.2214	NUM
eurjchem-2214	322	41	measure	measure	NOUN
eurjchem-2214	322	42	analysis	analysis	NOUN
eurjchem-2214	322	43	of	of	ADP
eurjchem-2214	322	44	the	the	DET
eurjchem-2214	322	45	mixed	mixed	ADJ
eurjchem-2214	322	46	ligand	ligand	NOUN
eurjchem-2214	322	47	chromophores	chromophore	NOUN
eurjchem-2214	322	48	clearly	clearly	ADV
eurjchem-2214	322	49	specifies	specify	VERB
eurjchem-2214	322	50	a	a	DET
eurjchem-2214	322	51	planar	planar	ADJ
eurjchem-2214	322	52	square	square	ADJ
eurjchem-2214	322	53	environment	environment	NOUN
eurjchem-2214	322	54	around	around	ADP
eurjchem-2214	322	55	central	central	ADJ
eurjchem-2214	322	56	nickel	nickel	NOUN
eurjchem-2214	322	57	atom	atom	NOUN
eurjchem-2214	322	58	and	and	CCONJ
eurjchem-2214	322	59	deviation	deviation	NOUN
eurjchem-2214	322	60	to	to	ADP
eurjchem-2214	322	61	tetrahedral	tetrahedral	ADJ
eurjchem-2214	322	62	or	or	CCONJ
eurjchem-2214	322	63	trigonal	trigonal	ADJ
eurjchem-2214	322	64	bipyramidal	bipyramidal	ADJ
eurjchem-2214	322	65	variants	variant	NOUN
eurjchem-2214	322	66	without	without	ADP
eurjchem-2214	322	67	central	central	ADJ
eurjchem-2214	322	68	atoms	atom	NOUN
eurjchem-2214	322	69	is	be	AUX
eurjchem-2214	322	70	completely	completely	ADV
eurjchem-2214	322	71	negated	negate	VERB
eurjchem-2214	322	72	.	.	PUNCT
eurjchem-2214	323	1	in	in	ADP
eurjchem-2214	323	2	this	this	DET
eurjchem-2214	323	3	study	study	NOUN
eurjchem-2214	323	4	,	,	PUNCT
eurjchem-2214	323	5	clinically	clinically	ADV
eurjchem-2214	323	6	validated	validate	VERB
eurjchem-2214	323	7	cis	cis	NOUN
eurjchem-2214	323	8	-	-	PUNCT
eurjchem-2214	323	9	platin	platin	NOUN
eurjchem-2214	323	10	was	be	AUX
eurjchem-2214	323	11	subjected	subject	VERB
eurjchem-2214	323	12	to	to	PART
eurjchem-2214	323	13	csm	csm	VERB
eurjchem-2214	323	14	analysis	analysis	NOUN
eurjchem-2214	323	15	and	and	CCONJ
eurjchem-2214	323	16	was	be	AUX
eurjchem-2214	323	17	found	find	VERB
eurjchem-2214	323	18	to	to	PART
eurjchem-2214	323	19	have	have	VERB
eurjchem-2214	323	20	a	a	DET
eurjchem-2214	323	21	csm	csm	NOUN
eurjchem-2214	323	22	comparable	comparable	ADJ
eurjchem-2214	323	23	to	to	ADP
eurjchem-2214	323	24	mixed	mixed	ADJ
eurjchem-2214	323	25	ligand	ligand	NOUN
eurjchem-2214	323	26	complexes	complex	NOUN
eurjchem-2214	323	27	1	1	NUM
eurjchem-2214	323	28	-	-	SYM
eurjchem-2214	323	29	5	5	NUM
eurjchem-2214	323	30	.	.	PUNCT
eurjchem-2214	324	1	as	as	ADP
eurjchem-2214	324	2	a	a	DET
eurjchem-2214	324	3	distinction	distinction	NOUN
eurjchem-2214	324	4	,	,	PUNCT
eurjchem-2214	324	5	unlike	unlike	ADP
eurjchem-2214	324	6	monodentate	monodentate	NOUN
eurjchem-2214	324	7	thiolates	thiolate	NOUN
eurjchem-2214	324	8	,	,	PUNCT
eurjchem-2214	324	9	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	ADJ
eurjchem-2214	324	10	acts	act	NOUN
eurjchem-2214	324	11	as	as	ADP
eurjchem-2214	324	12	a	a	DET
eurjchem-2214	324	13	“	"	PUNCT
eurjchem-2214	324	14	planarity	planarity	NOUN
eurjchem-2214	324	15	chuck	chuck	NOUN
eurjchem-2214	324	16	,	,	PUNCT
eurjchem-2214	324	17	which	which	PRON
eurjchem-2214	324	18	holds	hold	VERB
eurjchem-2214	324	19	the	the	DET
eurjchem-2214	324	20	work	work	NOUN
eurjchem-2214	324	21	piece	piece	NOUN
eurjchem-2214	324	22	”	"	PUNCT
eurjchem-2214	324	23	to	to	PART
eurjchem-2214	324	24	stabilize	stabilize	VERB
eurjchem-2214	324	25	the	the	DET
eurjchem-2214	324	26	planar	planar	ADJ
eurjchem-2214	324	27	square	square	ADJ
eurjchem-2214	324	28	shape	shape	NOUN
eurjchem-2214	324	29	of	of	ADP
eurjchem-2214	324	30	the	the	DET
eurjchem-2214	324	31	nickel	nickel	NOUN
eurjchem-2214	324	32	chromophores	chromophore	NOUN
eurjchem-2214	324	33	and	and	CCONJ
eurjchem-2214	324	34	provides	provide	VERB
eurjchem-2214	324	35	the	the	DET
eurjchem-2214	324	36	setting	setting	NOUN
eurjchem-2214	324	37	for	for	ADP
eurjchem-2214	324	38	the	the	DET
eurjchem-2214	324	39	steps	step	NOUN
eurjchem-2214	324	40	to	to	PART
eurjchem-2214	324	41	mimic	mimic	VERB
eurjchem-2214	324	42	cis	cis	NOUN
eurjchem-2214	324	43	-	-	PUNCT
eurjchem-2214	324	44	platin	platin	NOUN
eurjchem-2214	324	45	coordination	coordination	NOUN
eurjchem-2214	324	46	environment	environment	NOUN
eurjchem-2214	324	47	.	.	PUNCT
eurjchem-2214	325	1	therefore	therefore	ADV
eurjchem-2214	325	2	,	,	PUNCT
eurjchem-2214	325	3	pyrrolidinecarbodithioate	pyrrolidinecarbodithioate	VERB
eurjchem-2214	325	4	as	as	ADP
eurjchem-2214	325	5	a	a	DET
eurjchem-2214	325	6	“	"	PUNCT
eurjchem-2214	325	7	molecular	molecular	ADJ
eurjchem-2214	325	8	chuck	chuck	NOUN
eurjchem-2214	325	9	”	"	PUNCT
eurjchem-2214	325	10	in	in	ADP
eurjchem-2214	325	11	compounds	compound	NOUN
eurjchem-2214	325	12	1	1	NUM
eurjchem-2214	325	13	-	-	SYM
eurjchem-2214	325	14	5	5	NUM
eurjchem-2214	325	15	to	to	PART
eurjchem-2214	325	16	stabilize	stabilize	VERB
eurjchem-2214	325	17	the	the	DET
eurjchem-2214	325	18	planar	planar	ADJ
eurjchem-2214	325	19	geometry	geometry	NOUN
eurjchem-2214	325	20	of	of	ADP
eurjchem-2214	325	21	the	the	DET
eurjchem-2214	325	22	nickel	nickel	NOUN
eurjchem-2214	325	23	chromophores	chromophore	NOUN
eurjchem-2214	325	24	and	and	CCONJ
eurjchem-2214	325	25	afford	afford	VERB
eurjchem-2214	325	26	a	a	DET
eurjchem-2214	325	27	suitable	suitable	ADJ
eurjchem-2214	325	28	template	template	NOUN
eurjchem-2214	325	29	for	for	ADP
eurjchem-2214	325	30	the	the	DET
eurjchem-2214	325	31	synthesis	synthesis	NOUN
eurjchem-2214	325	32	of	of	ADP
eurjchem-2214	325	33	less	less	ADV
eurjchem-2214	325	34	toxic	toxic	ADJ
eurjchem-2214	325	35	divalent	divalent	NOUN
eurjchem-2214	325	36	nickel	nickel	NOUN
eurjchem-2214	325	37	analogues	analogue	NOUN
eurjchem-2214	325	38	of	of	ADP
eurjchem-2214	325	39	cis	cis	NOUN
eurjchem-2214	325	40	-	-	PUNCT
eurjchem-2214	325	41	platin	platin	NOUN
eurjchem-2214	325	42	.	.	PUNCT
eurjchem-2214	326	1	supporting	support	VERB
eurjchem-2214	326	2	information	information	NOUN
eurjchem-2214	326	3	ccdc-182725	ccdc-182725	ADJ
eurjchem-2214	326	4	(	(	PUNCT
eurjchem-2214	326	5	1	1	NUM
eurjchem-2214	326	6	)	)	PUNCT
eurjchem-2214	326	7	,	,	PUNCT
eurjchem-2214	326	8	218293	218293	NUM
eurjchem-2214	326	9	(	(	PUNCT
eurjchem-2214	326	10	2	2	NUM
eurjchem-2214	326	11	)	)	PUNCT
eurjchem-2214	326	12	,	,	PUNCT
eurjchem-2214	326	13	209868	209868	NUM
eurjchem-2214	326	14	(	(	PUNCT
eurjchem-2214	326	15	3	3	NUM
eurjchem-2214	326	16	)	)	PUNCT
eurjchem-2214	326	17	,	,	PUNCT
eurjchem-2214	326	18	and	and	CCONJ
eurjchem-2214	326	19	182726	182726	NUM
eurjchem-2214	326	20	(	(	PUNCT
eurjchem-2214	326	21	4	4	X
eurjchem-2214	326	22	)	)	PUNCT
eurjchem-2214	326	23	contain	contain	VERB
eurjchem-2214	326	24	the	the	DET
eurjchem-2214	326	25	supplementary	supplementary	ADJ
eurjchem-2214	326	26	crystallographic	crystallographic	ADJ
eurjchem-2214	326	27	data	datum	NOUN
eurjchem-2214	326	28	for	for	ADP
eurjchem-2214	326	29	this	this	DET
eurjchem-2214	326	30	paper	paper	NOUN
eurjchem-2214	326	31	.	.	PUNCT
eurjchem-2214	327	1	these	these	DET
eurjchem-2214	327	2	data	datum	NOUN
eurjchem-2214	327	3	can	can	AUX
eurjchem-2214	327	4	be	be	AUX
eurjchem-2214	327	5	obtained	obtain	VERB
eurjchem-2214	327	6	free	free	ADJ
eurjchem-2214	327	7	of	of	ADP
eurjchem-2214	327	8	charge	charge	NOUN
eurjchem-2214	327	9	via	via	ADP
eurjchem-2214	327	10	www.ccdc.cam.ac.uk/data_request/cif	www.ccdc.cam.ac.uk/data_request/cif	NOUN
eurjchem-2214	327	11	,	,	PUNCT
eurjchem-2214	327	12	or	or	CCONJ
eurjchem-2214	327	13	by	by	ADP
eurjchem-2214	327	14	emailing	email	VERB
eurjchem-2214	327	15	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-2214	327	16	,	,	PUNCT
eurjchem-2214	327	17	or	or	CCONJ
eurjchem-2214	327	18	by	by	ADP
eurjchem-2214	327	19	contacting	contact	VERB
eurjchem-2214	327	20	the	the	DET
eurjchem-2214	327	21	cambridge	cambridge	PROPN
eurjchem-2214	327	22	crystallographic	crystallographic	PROPN
eurjchem-2214	327	23	data	data	PROPN
eurjchem-2214	327	24	centre	centre	NOUN
eurjchem-2214	327	25	,	,	PUNCT
eurjchem-2214	327	26	12	12	NUM
eurjchem-2214	327	27	union	union	NOUN
eurjchem-2214	327	28	road	road	NOUN
eurjchem-2214	327	29	,	,	PUNCT
eurjchem-2214	327	30	cambridge	cambridge	PROPN
eurjchem-2214	327	31	cb2	cb2	PROPN
eurjchem-2214	327	32	1ez	1ez	PROPN
eurjchem-2214	327	33	,	,	PUNCT
eurjchem-2214	327	34	uk	uk	PROPN
eurjchem-2214	327	35	;	;	PUNCT
eurjchem-2214	327	36	fax	fax	NOUN
eurjchem-2214	327	37	:	:	PUNCT
eurjchem-2214	327	38	+44(0)1223	+44(0)1223	PROPN
eurjchem-2214	327	39	-	-	PUNCT
eurjchem-2214	327	40	336033	336033	NUM
eurjchem-2214	327	41	.	.	PUNCT
eurjchem-2214	328	1	disclosure	disclosure	NOUN
eurjchem-2214	328	2	statement	statement	NOUN
eurjchem-2214	328	3	conflict	conflict	NOUN
eurjchem-2214	328	4	of	of	ADP
eurjchem-2214	328	5	interests	interest	NOUN
eurjchem-2214	328	6	:	:	PUNCT
eurjchem-2214	328	7	the	the	DET
eurjchem-2214	328	8	authors	author	NOUN
eurjchem-2214	328	9	declare	declare	VERB
eurjchem-2214	328	10	that	that	SCONJ
eurjchem-2214	328	11	they	they	PRON
eurjchem-2214	328	12	have	have	VERB
eurjchem-2214	328	13	no	no	DET
eurjchem-2214	328	14	conflict	conflict	NOUN
eurjchem-2214	328	15	of	of	ADP
eurjchem-2214	328	16	interest	interest	NOUN
eurjchem-2214	328	17	.	.	PUNCT
eurjchem-2214	329	1	ethical	ethical	ADJ
eurjchem-2214	329	2	approval	approval	NOUN
eurjchem-2214	329	3	:	:	PUNCT
eurjchem-2214	330	1	all	all	DET
eurjchem-2214	330	2	ethical	ethical	ADJ
eurjchem-2214	330	3	guidelines	guideline	NOUN
eurjchem-2214	330	4	have	have	AUX
eurjchem-2214	330	5	been	be	AUX
eurjchem-2214	330	6	adhered	adhere	VERB
eurjchem-2214	330	7	.	.	PUNCT
eurjchem-2214	331	1	sample	sample	NOUN
eurjchem-2214	331	2	availability	availability	NOUN
eurjchem-2214	331	3	:	:	PUNCT
eurjchem-2214	331	4	samples	sample	NOUN
eurjchem-2214	331	5	of	of	ADP
eurjchem-2214	331	6	the	the	DET
eurjchem-2214	331	7	compounds	compound	NOUN
eurjchem-2214	331	8	are	be	AUX
eurjchem-2214	331	9	available	available	ADJ
eurjchem-2214	331	10	from	from	ADP
eurjchem-2214	331	11	the	the	DET
eurjchem-2214	331	12	author	author	NOUN
eurjchem-2214	331	13	.	.	PUNCT
eurjchem-2214	332	1	credit	credit	NOUN
eurjchem-2214	332	2	authorship	authorship	NOUN
eurjchem-2214	332	3	contribution	contribution	NOUN
eurjchem-2214	332	4	statement	statement	NOUN
eurjchem-2214	332	5	conceptualization	conceptualization	NOUN
eurjchem-2214	332	6	:	:	PUNCT
eurjchem-2214	332	7	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	8	ramalingam	ramalingam	NOUN
eurjchem-2214	332	9	;	;	PUNCT
eurjchem-2214	332	10	methodology	methodology	PROPN
eurjchem-2214	332	11	:	:	PUNCT
eurjchem-2214	332	12	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	13	ramalingam	ramalingam	PROPN
eurjchem-2214	332	14	;	;	PUNCT
eurjchem-2214	332	15	software	software	NOUN
eurjchem-2214	332	16	:	:	PUNCT
eurjchem-2214	332	17	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	18	ramalingam	ramalingam	NOUN
eurjchem-2214	332	19	;	;	PUNCT
eurjchem-2214	332	20	validation	validation	NOUN
eurjchem-2214	332	21	:	:	PUNCT
eurjchem-2214	332	22	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	23	ramalingam	ramalingam	NOUN
eurjchem-2214	332	24	;	;	PUNCT
eurjchem-2214	332	25	formal	formal	ADJ
eurjchem-2214	332	26	analysis	analysis	NOUN
eurjchem-2214	332	27	:	:	PUNCT
eurjchem-2214	332	28	murugesan	murugesan	PROPN
eurjchem-2214	332	29	saravanan	saravanan	PROPN
eurjchem-2214	332	30	;	;	PUNCT
eurjchem-2214	332	31	investigation	investigation	NOUN
eurjchem-2214	332	32	:	:	PUNCT
eurjchem-2214	332	33	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	34	ramalingam	ramalingam	PROPN
eurjchem-2214	332	35	,	,	PUNCT
eurjchem-2214	332	36	gabriele	gabriele	PROPN
eurjchem-2214	332	37	bocelli	bocelli	PROPN
eurjchem-2214	332	38	,	,	PUNCT
eurjchem-2214	332	39	murugesan	murugesan	PROPN
eurjchem-2214	332	40	saravanan	saravanan	PROPN
eurjchem-2214	332	41	,	,	PUNCT
eurjchem-2214	332	42	lara	lara	PROPN
eurjchem-2214	332	43	righi	righi	PROPN
eurjchem-2214	332	44	,	,	PUNCT
eurjchem-2214	332	45	yuriichumakov	yuriichumakov	PROPN
eurjchem-2214	332	46	,	,	PUNCT
eurjchem-2214	332	47	andrea	andrea	PROPN
eurjchem-2214	332	48	cantoni	cantoni	PROPN
eurjchem-2214	332	49	;	;	PUNCT
eurjchem-2214	332	50	resources	resource	NOUN
eurjchem-2214	332	51	:	:	PUNCT
eurjchem-2214	332	52	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	53	ramalingam	ramalingam	PROPN
eurjchem-2214	332	54	,	,	PUNCT
eurjchem-2214	332	55	gabriele	gabriele	PROPN
eurjchem-2214	332	56	bocelli	bocelli	PROPN
eurjchem-2214	332	57	;	;	PUNCT
eurjchem-2214	332	58	data	datum	NOUN
eurjchem-2214	332	59	curation	curation	NOUN
eurjchem-2214	332	60	:	:	PUNCT
eurjchem-2214	332	61	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	62	ramalingam	ramalingam	PROPN
eurjchem-2214	332	63	,	,	PUNCT
eurjchem-2214	332	64	murugesan	murugesan	PROPN
eurjchem-2214	332	65	saravanan	saravanan	PROPN
eurjchem-2214	332	66	;	;	PUNCT
eurjchem-2214	332	67	writing	write	VERB
eurjchem-2214	332	68	original	original	ADJ
eurjchem-2214	332	69	draft	draft	NOUN
eurjchem-2214	332	70	:	:	PUNCT
eurjchem-2214	332	71	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	72	ramalingam	ramalingam	NOUN
eurjchem-2214	332	73	;	;	PUNCT
eurjchem-2214	332	74	writing	write	VERB
eurjchem-2214	332	75	review	review	NOUN
eurjchem-2214	332	76	and	and	CCONJ
eurjchem-2214	332	77	editing	editing	NOUN
eurjchem-2214	332	78	:	:	PUNCT
eurjchem-2214	332	79	murugesan	murugesan	PROPN
eurjchem-2214	332	80	saravanan	saravanan	PROPN
eurjchem-2214	332	81	;	;	PUNCT
eurjchem-2214	332	82	visualization	visualization	NOUN
eurjchem-2214	332	83	:	:	PUNCT
eurjchem-2214	332	84	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	85	ramalingam	ramalingam	PROPN
eurjchem-2214	332	86	,	,	PUNCT
eurjchem-2214	332	87	murugesan	murugesan	PROPN
eurjchem-2214	332	88	saravanan	saravanan	PROPN
eurjchem-2214	332	89	;	;	PUNCT
eurjchem-2214	332	90	supervision	supervision	NOUN
eurjchem-2214	332	91	:	:	PUNCT
eurjchem-2214	332	92	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	93	ramalingam	ramalingam	PROPN
eurjchem-2214	332	94	;	;	PUNCT
eurjchem-2214	332	95	project	project	NOUN
eurjchem-2214	332	96	administration	administration	NOUN
eurjchem-2214	332	97	:	:	PUNCT
eurjchem-2214	332	98	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	332	99	ramalingam	ramalingam	PROPN
eurjchem-2214	332	100	.	.	PUNCT
eurjchem-2214	333	1	orcid	orcid	NOUN
eurjchem-2214	333	2	and	and	CCONJ
eurjchem-2214	333	3	email	email	NOUN
eurjchem-2214	333	4	kuppukkannu	kuppukkannu	PROPN
eurjchem-2214	333	5	ramalingam	ramalingam	NOUN
eurjchem-2214	334	1	krauchem@yahoo.com	krauchem@yahoo.com	PROPN
eurjchem-2214	334	2	https://orcid.org/0000-0001-8689-8007	https://orcid.org/0000-0001-8689-8007	PROPN
eurjchem-2214	334	3	murugesan	murugesan	PROPN
eurjchem-2214	334	4	saravanan	saravanan	PROPN
eurjchem-2214	334	5	sarchem@yahoo.com	sarchem@yahoo.com	PUNCT
eurjchem-2214	335	1	https://orcid.org/0000-0003-4740-307x	https://orcid.org/0000-0003-4740-307x	NOUN
eurjchem-2214	335	2	gabriele	gabriele	PROPN
eurjchem-2214	335	3	bocelli	bocelli	PROPN
eurjchem-2214	335	4	bocelli@unipr.it	bocelli@unipr.it	PROPN
eurjchem-2214	335	5	https://orcid.org/0000-0003-3196-8885	https://orcid.org/0000-0003-3196-8885	PROPN
eurjchem-2214	335	6	lara	lara	PROPN
eurjchem-2214	335	7	righi	righi	PROPN
eurjchem-2214	335	8	lara.righi@unipr.it	lara.righi@unipr.it	VERB
eurjchem-2214	335	9	https://orcid.org/0000-0001-9372-5438	https://orcid.org/0000-0001-9372-5438	NOUN
eurjchem-2214	335	10	yurii	yurii	PROPN
eurjchem-2214	335	11	chumakov	chumakov	PROPN
eurjchem-2214	335	12	chumakov@phys.asm.md	chumakov@phys.asm.md	PROPN
eurjchem-2214	335	13	https://orcid.org/0000-0003-2582-2871	https://orcid.org/0000-0003-2582-2871	PROPN
eurjchem-2214	335	14	andrea	andrea	PROPN
eurjchem-2214	335	15	cantoni	cantoni	PROPN
eurjchem-2214	335	16	provolo@pop.unipr.it	provolo@pop.unipr.it	PROPN
eurjchem-2214	336	1	https://orcid.org/0000-0001-7224-3253	https://orcid.org/0000-0001-7224-3253	ADJ
eurjchem-2214	336	2	references	reference	NOUN
eurjchem-2214	336	3	[	[	X
eurjchem-2214	336	4	1	1	NUM
eurjchem-2214	336	5	]	]	PUNCT
eurjchem-2214	336	6	.	.	PUNCT
eurjchem-2214	337	1	angeloski	angeloski	PROPN
eurjchem-2214	337	2	,	,	PUNCT
eurjchem-2214	337	3	a.	a.	NOUN
eurjchem-2214	337	4	;	;	PUNCT
eurjchem-2214	337	5	cortie	cortie	NOUN
eurjchem-2214	337	6	,	,	PUNCT
eurjchem-2214	337	7	m.	m.	PROPN
eurjchem-2214	337	8	b.	b.	PROPN
eurjchem-2214	337	9	;	;	PUNCT
eurjchem-2214	337	10	scott	scott	PROPN
eurjchem-2214	337	11	,	,	PUNCT
eurjchem-2214	337	12	j.	j.	PROPN
eurjchem-2214	337	13	a.	a.	PROPN
eurjchem-2214	337	14	;	;	PUNCT
eurjchem-2214	337	15	bordin	bordin	NOUN
eurjchem-2214	337	16	,	,	PUNCT
eurjchem-2214	337	17	d.	d.	PROPN
eurjchem-2214	337	18	m.	m.	PROPN
eurjchem-2214	337	19	;	;	PUNCT
eurjchem-2214	337	20	mcdonagh	mcdonagh	PROPN
eurjchem-2214	337	21	,	,	PUNCT
eurjchem-2214	337	22	a.	a.	NOUN
eurjchem-2214	337	23	m.	m.	NOUN
eurjchem-2214	337	24	conversion	conversion	NOUN
eurjchem-2214	337	25	of	of	ADP
eurjchem-2214	337	26	single	single	ADJ
eurjchem-2214	337	27	crystals	crystal	NOUN
eurjchem-2214	337	28	of	of	ADP
eurjchem-2214	337	29	a	a	DET
eurjchem-2214	337	30	nickel(ii	nickel(ii	NOUN
eurjchem-2214	337	31	)	)	PUNCT
eurjchem-2214	337	32	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	337	33	complex	complex	NOUN
eurjchem-2214	337	34	to	to	ADP
eurjchem-2214	337	35	nickel	nickel	NOUN
eurjchem-2214	337	36	sulfide	sulfide	NOUN
eurjchem-2214	337	37	crystals	crystal	NOUN
eurjchem-2214	337	38	.	.	PUNCT
eurjchem-2214	338	1	inorganica	inorganica	PROPN
eurjchem-2214	338	2	chim	chim	PROPN
eurjchem-2214	338	3	.	.	PUNCT
eurjchem-2214	339	1	acta	acta	PROPN
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eurjchem-2214	339	3	,	,	PUNCT
eurjchem-2214	339	4	487	487	NUM
eurjchem-2214	339	5	,	,	PUNCT
eurjchem-2214	339	6	228–233	228–233	NUM
eurjchem-2214	339	7	.	.	PUNCT
eurjchem-2214	340	1	[	[	X
eurjchem-2214	340	2	2	2	NUM
eurjchem-2214	340	3	]	]	PUNCT
eurjchem-2214	340	4	.	.	PUNCT
eurjchem-2214	340	5	yan	yan	PROPN
eurjchem-2214	340	6	,	,	PUNCT
eurjchem-2214	340	7	y.	y.	PROPN
eurjchem-2214	340	8	;	;	PUNCT
eurjchem-2214	340	9	krishnakumar	krishnakumar	PROPN
eurjchem-2214	340	10	,	,	PUNCT
eurjchem-2214	340	11	s.	s.	PROPN
eurjchem-2214	340	12	;	;	PUNCT
eurjchem-2214	340	13	yu	yu	PROPN
eurjchem-2214	340	14	,	,	PUNCT
eurjchem-2214	340	15	h.	h.	PROPN
eurjchem-2214	340	16	;	;	PUNCT
eurjchem-2214	340	17	ramishetti	ramishetti	PROPN
eurjchem-2214	340	18	,	,	PUNCT
eurjchem-2214	340	19	s.	s.	PROPN
eurjchem-2214	340	20	;	;	PUNCT
eurjchem-2214	340	21	deng	deng	PROPN
eurjchem-2214	340	22	,	,	PUNCT
eurjchem-2214	340	23	l.-w	l.-w	PROPN
eurjchem-2214	340	24	.	.	PUNCT
eurjchem-2214	340	25	;	;	PUNCT
eurjchem-2214	340	26	wang	wang	PROPN
eurjchem-2214	340	27	,	,	PUNCT
eurjchem-2214	340	28	s.	s.	PROPN
eurjchem-2214	340	29	;	;	PUNCT
eurjchem-2214	340	30	huang	huang	PROPN
eurjchem-2214	340	31	,	,	PUNCT
eurjchem-2214	340	32	l.	l.	PROPN
eurjchem-2214	340	33	;	;	PUNCT
eurjchem-2214	340	34	huang	huang	PROPN
eurjchem-2214	340	35	,	,	PUNCT
eurjchem-2214	340	36	d.	d.	PROPN
eurjchem-2214	340	37	nickel(ii	nickel(ii	PROPN
eurjchem-2214	340	38	)	)	PUNCT
eurjchem-2214	340	39	dithiocarbamate	dithiocarbamate	VERB
eurjchem-2214	340	40	complexes	complex	NOUN
eurjchem-2214	340	41	containing	contain	VERB
eurjchem-2214	340	42	sulforhodamine	sulforhodamine	NOUN
eurjchem-2214	340	43	b	b	NOUN
eurjchem-2214	340	44	as	as	ADP
eurjchem-2214	340	45	fluorescent	fluorescent	ADJ
eurjchem-2214	340	46	probes	probe	NOUN
eurjchem-2214	340	47	for	for	ADP
eurjchem-2214	340	48	selective	selective	ADJ
eurjchem-2214	340	49	detection	detection	NOUN
eurjchem-2214	340	50	of	of	ADP
eurjchem-2214	340	51	nitrogen	nitrogen	NOUN
eurjchem-2214	340	52	dioxide	dioxide	NOUN
eurjchem-2214	340	53	.	.	PUNCT
eurjchem-2214	341	1	j.	j.	PROPN
eurjchem-2214	341	2	am	am	PROPN
eurjchem-2214	341	3	.	.	PUNCT
eurjchem-2214	342	1	chem	chem	NOUN
eurjchem-2214	342	2	.	.	PUNCT
eurjchem-2214	343	1	soc	soc	PROPN
eurjchem-2214	343	2	.	.	PUNCT
eurjchem-2214	344	1	2013	2013	NUM
eurjchem-2214	344	2	,	,	PUNCT
eurjchem-2214	344	3	135	135	NUM
eurjchem-2214	344	4	,	,	PUNCT
eurjchem-2214	344	5	5312–5315	5312–5315	NUM
eurjchem-2214	344	6	.	.	PUNCT
eurjchem-2214	345	1	[	[	X
eurjchem-2214	345	2	3	3	NUM
eurjchem-2214	345	3	]	]	PUNCT
eurjchem-2214	345	4	.	.	PUNCT
eurjchem-2214	346	1	roffey	roffey	PROPN
eurjchem-2214	346	2	,	,	PUNCT
eurjchem-2214	346	3	a.	a.	NOUN
eurjchem-2214	346	4	;	;	PUNCT
eurjchem-2214	346	5	hollingsworth	hollingsworth	NOUN
eurjchem-2214	346	6	,	,	PUNCT
eurjchem-2214	346	7	n.	n.	NOUN
eurjchem-2214	346	8	;	;	PUNCT
eurjchem-2214	346	9	hogarth	hogarth	NOUN
eurjchem-2214	346	10	,	,	PUNCT
eurjchem-2214	346	11	g.	g.	PROPN
eurjchem-2214	346	12	synthesis	synthesis	NOUN
eurjchem-2214	346	13	of	of	ADP
eurjchem-2214	346	14	ternary	ternary	ADJ
eurjchem-2214	346	15	sulfide	sulfide	NOUN
eurjchem-2214	346	16	nanomaterials	nanomaterial	NOUN
eurjchem-2214	346	17	using	use	VERB
eurjchem-2214	346	18	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	346	19	complexes	complex	NOUN
eurjchem-2214	346	20	as	as	ADP
eurjchem-2214	346	21	single	single	ADJ
eurjchem-2214	346	22	source	source	NOUN
eurjchem-2214	346	23	precursors	precursor	NOUN
eurjchem-2214	346	24	.	.	PUNCT
eurjchem-2214	347	1	nanoscale	nanoscale	PROPN
eurjchem-2214	347	2	adv	adv	PROPN
eurjchem-2214	347	3	.	.	PROPN
eurjchem-2214	347	4	2019	2019	NUM
eurjchem-2214	347	5	,	,	PUNCT
eurjchem-2214	347	6	1	1	NUM
eurjchem-2214	347	7	,	,	PUNCT
eurjchem-2214	347	8	3056–3066	3056–3066	NUM
eurjchem-2214	347	9	.	.	PUNCT
eurjchem-2214	348	1	[	[	X
eurjchem-2214	348	2	4	4	NUM
eurjchem-2214	348	3	]	]	PUNCT
eurjchem-2214	348	4	.	.	PUNCT
eurjchem-2214	349	1	al	al	PROPN
eurjchem-2214	349	2	-	-	PUNCT
eurjchem-2214	349	3	jibori	jibori	PROPN
eurjchem-2214	349	4	,	,	PUNCT
eurjchem-2214	349	5	s.	s.	PROPN
eurjchem-2214	349	6	a.	a.	PROPN
eurjchem-2214	349	7	;	;	PUNCT
eurjchem-2214	349	8	al	al	PROPN
eurjchem-2214	349	9	-	-	PUNCT
eurjchem-2214	349	10	janabi	janabi	NOUN
eurjchem-2214	349	11	,	,	PUNCT
eurjchem-2214	349	12	a.	a.	PROPN
eurjchem-2214	349	13	s.	s.	PROPN
eurjchem-2214	349	14	m.	m.	PROPN
eurjchem-2214	349	15	;	;	PUNCT
eurjchem-2214	349	16	al	al	PROPN
eurjchem-2214	349	17	-	-	PUNCT
eurjchem-2214	349	18	sahan	sahan	PROPN
eurjchem-2214	349	19	,	,	PUNCT
eurjchem-2214	349	20	s.	s.	PROPN
eurjchem-2214	349	21	w.	w.	PROPN
eurjchem-2214	349	22	m.	m.	PROPN
eurjchem-2214	349	23	;	;	PUNCT
eurjchem-2214	349	24	wagner	wagner	PROPN
eurjchem-2214	349	25	,	,	PUNCT
eurjchem-2214	349	26	c.	c.	PROPN
eurjchem-2214	349	27	pd	pd	PROPN
eurjchem-2214	349	28	(	(	PUNCT
eurjchem-2214	349	29	ii	ii	PROPN
eurjchem-2214	349	30	)	)	PUNCT
eurjchem-2214	349	31	pyrrolidine	pyrrolidine	ADJ
eurjchem-2214	349	32	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	349	33	complexes	complex	NOUN
eurjchem-2214	349	34	:	:	PUNCT
eurjchem-2214	349	35	synthesis	synthesis	NOUN
eurjchem-2214	349	36	,	,	PUNCT
eurjchem-2214	349	37	spectroscopic	spectroscopic	ADJ
eurjchem-2214	349	38	studies	study	NOUN
eurjchem-2214	349	39	and	and	CCONJ
eurjchem-2214	349	40	molecular	molecular	ADJ
eurjchem-2214	349	41	structure	structure	NOUN
eurjchem-2214	349	42	of	of	ADP
eurjchem-2214	349	43	[	[	X
eurjchem-2214	349	44	pd(pydt)(ppy	pd(pydt)(ppy	PROPN
eurjchem-2214	349	45	)	)	PUNCT
eurjchem-2214	349	46	]	]	PUNCT
eurjchem-2214	349	47	.	.	PUNCT
eurjchem-2214	350	1	j.	j.	PROPN
eurjchem-2214	350	2	mol	mol	PROPN
eurjchem-2214	350	3	.	.	PROPN
eurjchem-2214	350	4	struct	struct	NOUN
eurjchem-2214	350	5	.	.	PUNCT
eurjchem-2214	350	6	2021	2021	NUM
eurjchem-2214	350	7	,	,	PUNCT
eurjchem-2214	350	8	1227	1227	NUM
eurjchem-2214	350	9	,	,	PUNCT
eurjchem-2214	350	10	129524	129524	NUM
eurjchem-2214	350	11	.	.	PUNCT
eurjchem-2214	351	1	[	[	X
eurjchem-2214	351	2	5	5	NUM
eurjchem-2214	351	3	]	]	PUNCT
eurjchem-2214	351	4	.	.	PUNCT
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eurjchem-2214	352	2	,	,	PUNCT
eurjchem-2214	352	3	y.	y.	PROPN
eurjchem-2214	352	4	;	;	PUNCT
eurjchem-2214	352	5	xing	xing	PROPN
eurjchem-2214	352	6	,	,	PUNCT
eurjchem-2214	352	7	z.	z.	PROPN
eurjchem-2214	352	8	;	;	PUNCT
eurjchem-2214	352	9	zhang	zhang	PROPN
eurjchem-2214	352	10	,	,	PUNCT
eurjchem-2214	352	11	x.	x.	PROPN
eurjchem-2214	352	12	;	;	PUNCT
eurjchem-2214	352	13	liang	liang	PROPN
eurjchem-2214	352	14	,	,	PUNCT
eurjchem-2214	352	15	g.	g.	PROPN
eurjchem-2214	352	16	inorganic	inorganic	PROPN
eurjchem-2214	352	17	anion	anion	NOUN
eurjchem-2214	352	18	-	-	PUNCT
eurjchem-2214	352	19	dependent	dependent	ADJ
eurjchem-2214	352	20	assembly	assembly	NOUN
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eurjchem-2214	352	22	zero-	zero-	PROPN
eurjchem-2214	352	23	,	,	PUNCT
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eurjchem-2214	352	25	,	,	PUNCT
eurjchem-2214	352	26	twoand	twoand	CCONJ
eurjchem-2214	352	27	three	three	NUM
eurjchem-2214	352	28	-	-	PUNCT
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eurjchem-2214	352	31	)	)	PUNCT
eurjchem-2214	352	32	complexes	complex	NOUN
eurjchem-2214	352	33	under	under	ADP
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eurjchem-2214	352	35	guidance	guidance	NOUN
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eurjchem-2214	352	37	the	the	DET
eurjchem-2214	352	38	hsab	hsab	NOUN
eurjchem-2214	352	39	theory	theory	NOUN
eurjchem-2214	352	40	:	:	PUNCT
eurjchem-2214	352	41	synthesis	synthesis	NOUN
eurjchem-2214	352	42	,	,	PUNCT
eurjchem-2214	352	43	structure	structure	NOUN
eurjchem-2214	352	44	,	,	PUNCT
eurjchem-2214	352	45	and	and	CCONJ
eurjchem-2214	352	46	magnetic	magnetic	ADJ
eurjchem-2214	352	47	property	property	NOUN
eurjchem-2214	352	48	.	.	PUNCT
eurjchem-2214	353	1	j.	j.	PROPN
eurjchem-2214	353	2	solid	solid	PROPN
eurjchem-2214	353	3	state	state	PROPN
eurjchem-2214	353	4	chem	chem	NOUN
eurjchem-2214	353	5	.	.	PUNCT
eurjchem-2214	354	1	2017	2017	NUM
eurjchem-2214	354	2	,	,	PUNCT
eurjchem-2214	354	3	246	246	NUM
eurjchem-2214	354	4	,	,	PUNCT
eurjchem-2214	354	5	48	48	NUM
eurjchem-2214	354	6	–	–	SYM
eurjchem-2214	354	7	56	56	NUM
eurjchem-2214	354	8	.	.	PUNCT
eurjchem-2214	355	1	[	[	X
eurjchem-2214	355	2	6	6	NUM
eurjchem-2214	355	3	]	]	PUNCT
eurjchem-2214	355	4	.	.	PUNCT
eurjchem-2214	356	1	hogarth	hogarth	PROPN
eurjchem-2214	356	2	,	,	PUNCT
eurjchem-2214	356	3	g.	g.	PROPN
eurjchem-2214	356	4	metal	metal	NOUN
eurjchem-2214	356	5	-	-	PUNCT
eurjchem-2214	356	6	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	356	7	complexes	complex	NOUN
eurjchem-2214	356	8	:	:	PUNCT
eurjchem-2214	356	9	chemistry	chemistry	NOUN
eurjchem-2214	356	10	and	and	CCONJ
eurjchem-2214	356	11	biological	biological	ADJ
eurjchem-2214	356	12	activity	activity	NOUN
eurjchem-2214	356	13	.	.	PUNCT
eurjchem-2214	357	1	mini	mini	PROPN
eurjchem-2214	357	2	rev	rev	PROPN
eurjchem-2214	357	3	.	.	PROPN
eurjchem-2214	357	4	med	med	PROPN
eurjchem-2214	357	5	.	.	PROPN
eurjchem-2214	357	6	chem	chem	PROPN
eurjchem-2214	357	7	.	.	PUNCT
eurjchem-2214	358	1	2012	2012	NUM
eurjchem-2214	358	2	,	,	PUNCT
eurjchem-2214	358	3	12	12	NUM
eurjchem-2214	358	4	,	,	PUNCT
eurjchem-2214	358	5	1202–1215	1202–1215	NUM
eurjchem-2214	358	6	.	.	PUNCT
eurjchem-2214	359	1	[	[	X
eurjchem-2214	359	2	7	7	NUM
eurjchem-2214	359	3	]	]	PUNCT
eurjchem-2214	359	4	.	.	PUNCT
eurjchem-2214	359	5	ramalingam	ramalingam	PROPN
eurjchem-2214	359	6	,	,	PUNCT
eurjchem-2214	359	7	k.	k.	PROPN
eurjchem-2214	359	8	;	;	PUNCT
eurjchem-2214	359	9	srinivasan	srinivasan	NOUN
eurjchem-2214	359	10	,	,	PUNCT
eurjchem-2214	359	11	s.	s.	PROPN
eurjchem-2214	359	12	;	;	PUNCT
eurjchem-2214	359	13	rizzoli	rizzoli	NOUN
eurjchem-2214	359	14	,	,	PUNCT
eurjchem-2214	359	15	c.	c.	PROPN
eurjchem-2214	359	16	solvothermal	solvothermal	ADJ
eurjchem-2214	359	17	preparation	preparation	NOUN
eurjchem-2214	359	18	of	of	ADP
eurjchem-2214	359	19	nano	nano	NOUN
eurjchem-2214	359	20	cobalt	cobalt	NOUN
eurjchem-2214	359	21	sulfide	sulfide	NOUN
eurjchem-2214	359	22	from	from	ADP
eurjchem-2214	359	23	tris	tris	NOUN
eurjchem-2214	359	24	(	(	PUNCT
eurjchem-2214	359	25	cyclohexylpiperazinedithiocarbamato	cyclohexylpiperazinedithiocarbamato	PROPN
eurjchem-2214	359	26	)	)	PUNCT
eurjchem-2214	359	27	cobalt(iii	cobalt(iii	PROPN
eurjchem-2214	359	28	)	)	PUNCT
eurjchem-2214	359	29	and	and	CCONJ
eurjchem-2214	359	30	characterization	characterization	NOUN
eurjchem-2214	359	31	,	,	PUNCT
eurjchem-2214	359	32	single	single	ADJ
eurjchem-2214	359	33	crystal	crystal	NOUN
eurjchem-2214	359	34	x	x	PROPN
eurjchem-2214	359	35	-	-	NOUN
eurjchem-2214	359	36	ray	ray	NOUN
eurjchem-2214	359	37	crystal	crystal	NOUN
eurjchem-2214	359	38	structure	structure	NOUN
eurjchem-2214	359	39	of	of	ADP
eurjchem-2214	359	40	the	the	DET
eurjchem-2214	359	41	precursor	precursor	NOUN
eurjchem-2214	359	42	.	.	PUNCT
eurjchem-2214	360	1	j.	j.	PROPN
eurjchem-2214	360	2	coord	coord	PROPN
eurjchem-2214	360	3	.	.	PUNCT
eurjchem-2214	361	1	chem	chem	PROPN
eurjchem-2214	361	2	.	.	PUNCT
eurjchem-2214	362	1	2021	2021	NUM
eurjchem-2214	362	2	,	,	PUNCT
eurjchem-2214	362	3	73	73	NUM
eurjchem-2214	362	4	,	,	PUNCT
eurjchem-2214	362	5	3487–3499	3487–3499	NUM
eurjchem-2214	362	6	.	.	PUNCT
eurjchem-2214	363	1	[	[	X
eurjchem-2214	363	2	8	8	NUM
eurjchem-2214	363	3	]	]	PUNCT
eurjchem-2214	363	4	.	.	PUNCT
eurjchem-2214	364	1	ramalingam	ramalingam	PROPN
eurjchem-2214	364	2	,	,	PUNCT
eurjchem-2214	364	3	k.	k.	PROPN
eurjchem-2214	364	4	;	;	PUNCT
eurjchem-2214	364	5	srinivasan	srinivasan	NOUN
eurjchem-2214	364	6	,	,	PUNCT
eurjchem-2214	364	7	s.	s.	PROPN
eurjchem-2214	364	8	synthesis	synthesis	PROPN
eurjchem-2214	364	9	,	,	PUNCT
eurjchem-2214	364	10	spectral	spectral	ADJ
eurjchem-2214	364	11	,	,	PUNCT
eurjchem-2214	364	12	single	single	ADJ
eurjchem-2214	364	13	crystal	crystal	NOUN
eurjchem-2214	364	14	x	x	PROPN
eurjchem-2214	364	15	-	-	NOUN
eurjchem-2214	364	16	ray	ray	NOUN
eurjchem-2214	364	17	structural	structural	NOUN
eurjchem-2214	364	18	,	,	PUNCT
eurjchem-2214	364	19	cshm	cshm	NOUN
eurjchem-2214	364	20	and	and	CCONJ
eurjchem-2214	364	21	bvs	bvs	NOUN
eurjchem-2214	364	22	characterization	characterization	NOUN
eurjchem-2214	364	23	of	of	ADP
eurjchem-2214	364	24	iron(iii	iron(iii	NOUN
eurjchem-2214	364	25	)	)	PUNCT
eurjchem-2214	364	26	cyclohexyl	cyclohexyl	PROPN
eurjchem-2214	364	27	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2214	364	28	and	and	CCONJ
eurjchem-2214	364	29	their	their	PRON
eurjchem-2214	364	30	solvothermal	solvothermal	ADJ
eurjchem-2214	364	31	decomposition	decomposition	NOUN
eurjchem-2214	364	32	to	to	PART
eurjchem-2214	364	33	nano	nano	VERB
eurjchem-2214	364	34	iron(ii	iron(ii	NOUN
eurjchem-2214	364	35	)	)	PUNCT
eurjchem-2214	364	36	sulphide	sulphide	NOUN
eurjchem-2214	364	37	.	.	PUNCT
eurjchem-2214	365	1	j.	j.	PROPN
eurjchem-2214	365	2	mol	mol	PROPN
eurjchem-2214	365	3	.	.	PROPN
eurjchem-2214	365	4	struct	struct	NOUN
eurjchem-2214	365	5	.	.	PUNCT
eurjchem-2214	366	1	2015	2015	NUM
eurjchem-2214	366	2	,	,	PUNCT
eurjchem-2214	366	3	1100	1100	NUM
eurjchem-2214	366	4	,	,	PUNCT
eurjchem-2214	366	5	290–298	290–298	NUM
eurjchem-2214	366	6	.	.	PUNCT
eurjchem-2214	367	1	[	[	X
eurjchem-2214	367	2	9	9	NUM
eurjchem-2214	367	3	]	]	PUNCT
eurjchem-2214	367	4	.	.	PUNCT
eurjchem-2214	368	1	manohar	manohar	PROPN
eurjchem-2214	368	2	,	,	PUNCT
eurjchem-2214	368	3	a.	a.	NOUN
eurjchem-2214	368	4	;	;	PUNCT
eurjchem-2214	368	5	ramalingam	ramalingam	NOUN
eurjchem-2214	368	6	,	,	PUNCT
eurjchem-2214	368	7	k.	k.	PROPN
eurjchem-2214	368	8	;	;	PUNCT
eurjchem-2214	368	9	thiruneelakandan	thiruneelakandan	PROPN
eurjchem-2214	368	10	,	,	PUNCT
eurjchem-2214	368	11	r.	r.	PROPN
eurjchem-2214	368	12	;	;	PUNCT
eurjchem-2214	368	13	bocelli	bocelli	PROPN
eurjchem-2214	368	14	,	,	PUNCT
eurjchem-2214	368	15	g.	g.	PROPN
eurjchem-2214	368	16	;	;	PUNCT
eurjchem-2214	368	17	righi	righi	PROPN
eurjchem-2214	368	18	,	,	PUNCT
eurjchem-2214	368	19	l.	l.	PROPN
eurjchem-2214	368	20	steric	steric	ADJ
eurjchem-2214	368	21	and	and	CCONJ
eurjchem-2214	368	22	electronic	electronic	ADJ
eurjchem-2214	368	23	effects	effect	NOUN
eurjchem-2214	368	24	of	of	ADP
eurjchem-2214	368	25	chelating	chelating	NOUN
eurjchem-2214	368	26	phosphines	phosphine	NOUN
eurjchem-2214	368	27	:	:	PUNCT
eurjchem-2214	368	28	synthesis	synthesis	NOUN
eurjchem-2214	368	29	,	,	PUNCT
eurjchem-2214	368	30	spectral	spectral	ADJ
eurjchem-2214	368	31	,	,	PUNCT
eurjchem-2214	368	32	and	and	CCONJ
eurjchem-2214	368	33	single	single	ADJ
eurjchem-2214	368	34	crystal	crystal	NOUN
eurjchem-2214	368	35	x	x	PROPN
eurjchem-2214	368	36	-	-	NOUN
eurjchem-2214	368	37	ray	ray	NOUN
eurjchem-2214	368	38	structural	structural	ADJ
eurjchem-2214	368	39	studies	study	NOUN
eurjchem-2214	368	40	on	on	ADP
eurjchem-2214	368	41	[	[	PUNCT
eurjchem-2214	368	42	1,3	1,3	NUM
eurjchem-2214	368	43	-	-	PUNCT
eurjchem-2214	368	44	bis(di	bis(di	NOUN
eurjchem-2214	368	45	phenylphosphino	phenylphosphino	NOUN
eurjchem-2214	368	46	-	-	PUNCT
eurjchem-2214	368	47	k	k	NOUN
eurjchem-2214	368	48	,	,	PUNCT
eurjchem-2214	368	49	p	p	NOUN
eurjchem-2214	368	50	,	,	PUNCT
eurjchem-2214	368	51	p′)propane](diisopropyldithiocarbamato	p′)propane](diisopropyldithiocarbamato	PROPN
eurjchem-2214	368	52	)	)	PUNCT
eurjchem-2214	368	53	nickel	nickel	NOUN
eurjchem-2214	368	54	(	(	PUNCT
eurjchem-2214	368	55	ii	ii	NOUN
eurjchem-2214	368	56	)	)	PUNCT
eurjchem-2214	368	57	perchlorate	perchlorate	NOUN
eurjchem-2214	368	58	and	and	CCONJ
eurjchem-2214	368	59	[	[	X
eurjchem-2214	368	60	1,3	1,3	NUM
eurjchem-2214	368	61	-	-	PUNCT
eurjchem-2214	368	62	bis(diphenylphosphino	bis(diphenylphosphino	NOUN
eurjchem-2214	368	63	-	-	PUNCT
eurjchem-2214	368	64	k	k	NOUN
eurjchem-2214	368	65	,	,	PUNCT
eurjchem-2214	368	66	p	p	X
eurjchem-2214	368	67	,	,	PUNCT
eurjchem-2214	368	68	p′)propane](pi	p′)propane](pi	NOUN
eurjchem-2214	368	69	peridinecarbodithioato)nickel(ii	peridinecarbodithioato)nickel(ii	ADJ
eurjchem-2214	368	70	)	)	PUNCT
eurjchem-2214	368	71	perchlorate	perchlorate	NOUN
eurjchem-2214	368	72	.	.	PUNCT
eurjchem-2214	369	1	z.	z.	PROPN
eurjchem-2214	369	2	anorg	anorg	PROPN
eurjchem-2214	369	3	.	.	PUNCT
eurjchem-2214	370	1	allg	allg	PROPN
eurjchem-2214	370	2	.	.	PUNCT
eurjchem-2214	371	1	chem	chem	NOUN
eurjchem-2214	371	2	.	.	PUNCT
eurjchem-2214	372	1	2001	2001	NUM
eurjchem-2214	372	2	,	,	PUNCT
eurjchem-2214	372	3	627	627	NUM
eurjchem-2214	372	4	,	,	PUNCT
eurjchem-2214	372	5	1103–1108	1103–1108	NUM
eurjchem-2214	372	6	.	.	PUNCT
eurjchem-2214	373	1	[	[	X
eurjchem-2214	373	2	10	10	NUM
eurjchem-2214	373	3	]	]	PUNCT
eurjchem-2214	373	4	.	.	PUNCT
eurjchem-2214	374	1	arshad	arshad	ADJ
eurjchem-2214	374	2	,	,	PUNCT
eurjchem-2214	374	3	m.	m.	NOUN
eurjchem-2214	374	4	;	;	PUNCT
eurjchem-2214	374	5	wang	wang	PROPN
eurjchem-2214	374	6	,	,	PUNCT
eurjchem-2214	374	7	z.	z.	PROPN
eurjchem-2214	374	8	;	;	PUNCT
eurjchem-2214	374	9	nasir	nasir	PROPN
eurjchem-2214	374	10	,	,	PUNCT
eurjchem-2214	374	11	j.	j.	PROPN
eurjchem-2214	374	12	a.	a.	PROPN
eurjchem-2214	374	13	;	;	PUNCT
eurjchem-2214	374	14	amador	amador	PROPN
eurjchem-2214	374	15	,	,	PUNCT
eurjchem-2214	374	16	e.	e.	PROPN
eurjchem-2214	374	17	;	;	PUNCT
eurjchem-2214	374	18	jin	jin	NOUN
eurjchem-2214	374	19	,	,	PUNCT
eurjchem-2214	374	20	m.	m.	NOUN
eurjchem-2214	374	21	;	;	PUNCT
eurjchem-2214	374	22	li	li	PROPN
eurjchem-2214	374	23	,	,	PUNCT
eurjchem-2214	374	24	h.	h.	PROPN
eurjchem-2214	374	25	;	;	PUNCT
eurjchem-2214	374	26	chen	chen	PROPN
eurjchem-2214	374	27	,	,	PUNCT
eurjchem-2214	374	28	z.	z.	PROPN
eurjchem-2214	374	29	;	;	PUNCT
eurjchem-2214	374	30	rehman	rehman	PROPN
eurjchem-2214	374	31	,	,	PUNCT
eurjchem-2214	374	32	z.	z.	PROPN
eurjchem-2214	374	33	u.	u.	PROPN
eurjchem-2214	374	34	;	;	PUNCT
eurjchem-2214	374	35	chen	chen	PROPN
eurjchem-2214	374	36	,	,	PUNCT
eurjchem-2214	374	37	w.	w.	PROPN
eurjchem-2214	374	38	single	single	ADJ
eurjchem-2214	374	39	source	source	NOUN
eurjchem-2214	374	40	precursor	precursor	NOUN
eurjchem-2214	374	41	synthesized	synthesize	VERB
eurjchem-2214	374	42	cus	cus	ADJ
eurjchem-2214	374	43	nanoparticles	nanoparticle	NOUN
eurjchem-2214	374	44	for	for	ADP
eurjchem-2214	374	45	nir	nir	ADJ
eurjchem-2214	374	46	phototherapy	phototherapy	NOUN
eurjchem-2214	374	47	of	of	ADP
eurjchem-2214	374	48	cancer	cancer	NOUN
eurjchem-2214	374	49	and	and	CCONJ
eurjchem-2214	374	50	photodegradation	photodegradation	NOUN
eurjchem-2214	374	51	of	of	ADP
eurjchem-2214	374	52	organic	organic	ADJ
eurjchem-2214	374	53	carcinogen	carcinogen	NOUN
eurjchem-2214	374	54	.	.	PUNCT
eurjchem-2214	375	1	j.	j.	PROPN
eurjchem-2214	375	2	photochem	photochem	PROPN
eurjchem-2214	375	3	.	.	PUNCT
eurjchem-2214	376	1	photobiol	photobiol	PROPN
eurjchem-2214	376	2	.	.	PUNCT
eurjchem-2214	377	1	b	b	NOUN
eurjchem-2214	377	2	2021	2021	NUM
eurjchem-2214	377	3	,	,	PUNCT
eurjchem-2214	377	4	214	214	NUM
eurjchem-2214	377	5	,	,	PUNCT
eurjchem-2214	377	6	112084	112084	NUM
eurjchem-2214	377	7	.	.	PUNCT
eurjchem-2214	378	1	[	[	X
eurjchem-2214	378	2	11	11	NUM
eurjchem-2214	378	3	]	]	PUNCT
eurjchem-2214	378	4	.	.	PUNCT
eurjchem-2214	379	1	roffey	roffey	PROPN
eurjchem-2214	379	2	,	,	PUNCT
eurjchem-2214	379	3	a.	a.	NOUN
eurjchem-2214	379	4	;	;	PUNCT
eurjchem-2214	379	5	hollingsworth	hollingsworth	NOUN
eurjchem-2214	379	6	,	,	PUNCT
eurjchem-2214	379	7	n.	n.	PROPN
eurjchem-2214	379	8	;	;	PUNCT
eurjchem-2214	379	9	islam	islam	PROPN
eurjchem-2214	379	10	,	,	PUNCT
eurjchem-2214	379	11	h.-u	h.-u	PROPN
eurjchem-2214	379	12	.	.	PUNCT
eurjchem-2214	379	13	;	;	PUNCT
eurjchem-2214	380	1	mercy	mercy	NOUN
eurjchem-2214	380	2	,	,	PUNCT
eurjchem-2214	380	3	m.	m.	NOUN
eurjchem-2214	380	4	;	;	PUNCT
eurjchem-2214	380	5	sankar	sankar	NOUN
eurjchem-2214	380	6	,	,	PUNCT
eurjchem-2214	380	7	g.	g.	PROPN
eurjchem-2214	380	8	;	;	PUNCT
eurjchem-2214	380	9	catlow	catlow	NOUN
eurjchem-2214	380	10	,	,	PUNCT
eurjchem-2214	380	11	c.	c.	PROPN
eurjchem-2214	380	12	r.	r.	PROPN
eurjchem-2214	380	13	a.	a.	PROPN
eurjchem-2214	380	14	;	;	PUNCT
eurjchem-2214	380	15	hogarth	hogarth	NOUN
eurjchem-2214	380	16	,	,	PUNCT
eurjchem-2214	380	17	g.	g.	PROPN
eurjchem-2214	380	18	;	;	PUNCT
eurjchem-2214	380	19	de	de	X
eurjchem-2214	380	20	leeuw	leeuw	PROPN
eurjchem-2214	380	21	,	,	PUNCT
eurjchem-2214	380	22	n.	n.	PROPN
eurjchem-2214	380	23	h.	h.	PROPN
eurjchem-2214	380	24	phase	phase	PROPN
eurjchem-2214	380	25	control	control	NOUN
eurjchem-2214	380	26	during	during	ADP
eurjchem-2214	380	27	the	the	DET
eurjchem-2214	380	28	synthesis	synthesis	NOUN
eurjchem-2214	380	29	of	of	ADP
eurjchem-2214	380	30	nickel	nickel	NOUN
eurjchem-2214	380	31	sulfide	sulfide	NOUN
eurjchem-2214	380	32	nanoparticles	nanoparticle	NOUN
eurjchem-2214	380	33	from	from	ADP
eurjchem-2214	380	34	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2214	380	35	precursors	precursor	NOUN
eurjchem-2214	380	36	.	.	PUNCT
eurjchem-2214	381	1	nanoscale	nanoscale	PROPN
eurjchem-2214	381	2	2016	2016	NUM
eurjchem-2214	381	3	,	,	PUNCT
eurjchem-2214	381	4	8	8	NUM
eurjchem-2214	381	5	,	,	PUNCT
eurjchem-2214	381	6	11067–11075	11067–11075	NUM
eurjchem-2214	381	7	.	.	PUNCT
eurjchem-2214	382	1	[	[	X
eurjchem-2214	382	2	12	12	NUM
eurjchem-2214	382	3	]	]	PUNCT
eurjchem-2214	382	4	.	.	PUNCT
eurjchem-2214	383	1	ramalingam	ramalingam	PROPN
eurjchem-2214	383	2	,	,	PUNCT
eurjchem-2214	383	3	k.	k.	PROPN
eurjchem-2214	383	4	;	;	PUNCT
eurjchem-2214	383	5	srinivasan	srinivasan	NOUN
eurjchem-2214	383	6	,	,	PUNCT
eurjchem-2214	383	7	s.	s.	PROPN
eurjchem-2214	383	8	;	;	PUNCT
eurjchem-2214	383	9	ethirajavalli	ethirajavalli	PROPN
eurjchem-2214	383	10	,	,	PUNCT
eurjchem-2214	383	11	r.	r.	PROPN
eurjchem-2214	383	12	;	;	PUNCT
eurjchem-2214	383	13	rizzoli	rizzoli	NOUN
eurjchem-2214	383	14	,	,	PUNCT
eurjchem-2214	383	15	c.	c.	NOUN
eurjchem-2214	383	16	quantification	quantification	NOUN
eurjchem-2214	383	17	of	of	ADP
eurjchem-2214	383	18	distortions	distortion	NOUN
eurjchem-2214	383	19	associated	associate	VERB
eurjchem-2214	383	20	with	with	ADP
eurjchem-2214	383	21	planar	planar	ADJ
eurjchem-2214	383	22	nis4	nis4	NOUN
eurjchem-2214	383	23	,	,	PUNCT
eurjchem-2214	383	24	nis2np	nis2np	NOUN
eurjchem-2214	383	25	and	and	CCONJ
eurjchem-2214	383	26	nis2p2	nis2p2	ADJ
eurjchem-2214	383	27	chromophores	chromophore	NOUN
eurjchem-2214	383	28	:	:	PUNCT
eurjchem-2214	383	29	synthesis	synthesis	NOUN
eurjchem-2214	383	30	,	,	PUNCT
eurjchem-2214	383	31	structural	structural	ADJ
eurjchem-2214	383	32	and	and	CCONJ
eurjchem-2214	383	33	csm	csm	VERB
eurjchem-2214	383	34	analysis	analysis	NOUN
eurjchem-2214	383	35	.	.	PUNCT
eurjchem-2214	384	1	polyhedron	polyhedron	NOUN
eurjchem-2214	384	2	2016	2016	NUM
eurjchem-2214	384	3	,	,	PUNCT
eurjchem-2214	384	4	104	104	NUM
eurjchem-2214	384	5	,	,	PUNCT
eurjchem-2214	384	6	138–144	138–144	NUM
eurjchem-2214	384	7	.	.	PUNCT
eurjchem-2214	385	1	[	[	X
eurjchem-2214	385	2	13	13	NUM
eurjchem-2214	385	3	]	]	PUNCT
eurjchem-2214	385	4	.	.	PUNCT
eurjchem-2214	386	1	srinivasan	srinivasan	NOUN
eurjchem-2214	386	2	,	,	PUNCT
eurjchem-2214	386	3	s.	s.	PROPN
eurjchem-2214	386	4	;	;	PUNCT
eurjchem-2214	386	5	ramalingam	ramalingam	NOUN
eurjchem-2214	386	6	,	,	PUNCT
eurjchem-2214	386	7	k.	k.	PROPN
eurjchem-2214	386	8	;	;	PUNCT
eurjchem-2214	386	9	rizzoli	rizzoli	NOUN
eurjchem-2214	386	10	,	,	PUNCT
eurjchem-2214	386	11	c.	c.	PROPN
eurjchem-2214	386	12	trans	trans	PROPN
eurjchem-2214	386	13	influence	influence	PROPN
eurjchem-2214	386	14	and	and	CCONJ
eurjchem-2214	386	15	steric	steric	ADJ
eurjchem-2214	386	16	effect	effect	NOUN
eurjchem-2214	386	17	on	on	ADP
eurjchem-2214	386	18	the	the	DET
eurjchem-2214	386	19	distortions	distortion	NOUN
eurjchem-2214	386	20	in	in	ADP
eurjchem-2214	386	21	planar	planar	ADJ
eurjchem-2214	386	22	nis4	nis4	PROPN
eurjchem-2214	386	23	,	,	PUNCT
eurjchem-2214	386	24	nis2pn	nis2pn	PROPN
eurjchem-2214	386	25	,	,	PUNCT
eurjchem-2214	386	26	and	and	CCONJ
eurjchem-2214	386	27	nis2p2	nis2p2	ADJ
eurjchem-2214	386	28	chromophores	chromophore	NOUN
eurjchem-2214	386	29	.	.	PUNCT
eurjchem-2214	387	1	z.	z.	PROPN
eurjchem-2214	387	2	anorg	anorg	PROPN
eurjchem-2214	387	3	.	.	PUNCT
eurjchem-2214	388	1	allg	allg	PROPN
eurjchem-2214	388	2	.	.	PUNCT
eurjchem-2214	389	1	chem	chem	NOUN
eurjchem-2214	389	2	.	.	PUNCT
eurjchem-2214	390	1	2012	2012	NUM
eurjchem-2214	390	2	,	,	PUNCT
eurjchem-2214	390	3	638	638	NUM
eurjchem-2214	390	4	,	,	PUNCT
eurjchem-2214	390	5	1356–1361	1356–1361	NOUN
eurjchem-2214	390	6	.	.	PUNCT
eurjchem-2214	391	1	[	[	X
eurjchem-2214	391	2	14	14	NUM
eurjchem-2214	391	3	]	]	PUNCT
eurjchem-2214	391	4	.	.	PUNCT
eurjchem-2214	392	1	srinivasan	srinivasan	NOUN
eurjchem-2214	392	2	,	,	PUNCT
eurjchem-2214	392	3	s.	s.	PROPN
eurjchem-2214	392	4	;	;	PUNCT
eurjchem-2214	392	5	ramalingam	ramalingam	NOUN
eurjchem-2214	392	6	,	,	PUNCT
eurjchem-2214	392	7	k.	k.	PROPN
eurjchem-2214	392	8	;	;	PUNCT
eurjchem-2214	392	9	rizzoli	rizzoli	NOUN
eurjchem-2214	392	10	,	,	PUNCT
eurjchem-2214	392	11	c.	c.	NOUN
eurjchem-2214	392	12	synthesis	synthesis	NOUN
eurjchem-2214	392	13	,	,	PUNCT
eurjchem-2214	392	14	nmr	nmr	NOUN
eurjchem-2214	392	15	and	and	CCONJ
eurjchem-2214	392	16	single	single	ADJ
eurjchem-2214	392	17	crystal	crystal	NOUN
eurjchem-2214	392	18	x	x	PROPN
eurjchem-2214	392	19	-	-	NOUN
eurjchem-2214	392	20	ray	ray	NOUN
eurjchem-2214	392	21	structural	structural	ADJ
eurjchem-2214	392	22	studies	study	NOUN
eurjchem-2214	392	23	on	on	ADP
eurjchem-2214	392	24	planar	planar	ADJ
eurjchem-2214	392	25	nis4	nis4	NOUN
eurjchem-2214	392	26	and	and	CCONJ
eurjchem-2214	392	27	nis2pn	nis2pn	NOUN
eurjchem-2214	392	28	chromophores	chromophore	NOUN
eurjchem-2214	392	29	:	:	PUNCT
eurjchem-2214	392	30	steric	steric	ADJ
eurjchem-2214	392	31	and	and	CCONJ
eurjchem-2214	392	32	electronic	electronic	ADJ
eurjchem-2214	392	33	effects	effect	NOUN
eurjchem-2214	392	34	.	.	PUNCT
eurjchem-2214	393	1	polyhedron	polyhedron	NOUN
eurjchem-2214	393	2	2012	2012	NUM
eurjchem-2214	393	3	,	,	PUNCT
eurjchem-2214	393	4	33	33	NUM
eurjchem-2214	393	5	,	,	PUNCT
eurjchem-2214	393	6	60–66	60–66	NOUN
eurjchem-2214	393	7	.	.	PUNCT
eurjchem-2214	394	1	[	[	X
eurjchem-2214	394	2	15	15	NUM
eurjchem-2214	394	3	]	]	PUNCT
eurjchem-2214	394	4	.	.	PUNCT
eurjchem-2214	395	1	bhaskaran	bhaskaran	PROPN
eurjchem-2214	395	2	,	,	PUNCT
eurjchem-2214	395	3	r.	r.	PROPN
eurjchem-2214	395	4	;	;	PUNCT
eurjchem-2214	395	5	ramalingam	ramalingam	NOUN
eurjchem-2214	395	6	,	,	PUNCT
eurjchem-2214	395	7	k.	k.	PROPN
eurjchem-2214	395	8	;	;	PUNCT
eurjchem-2214	395	9	bocelli	bocelli	PROPN
eurjchem-2214	395	10	,	,	PUNCT
eurjchem-2214	395	11	g.	g.	PROPN
eurjchem-2214	395	12	;	;	PUNCT
eurjchem-2214	395	13	cantoni	cantoni	PROPN
eurjchem-2214	395	14	,	,	PUNCT
eurjchem-2214	395	15	a.	a.	NOUN
eurjchem-2214	395	16	;	;	PUNCT
eurjchem-2214	395	17	rizzoli	rizzoli	NOUN
eurjchem-2214	395	18	,	,	PUNCT
eurjchem-2214	395	19	c.	c.	PROPN
eurjchem-2214	395	20	steric	steric	ADJ
eurjchem-2214	395	21	and	and	CCONJ
eurjchem-2214	395	22	electronic	electronic	ADJ
eurjchem-2214	395	23	effects	effect	NOUN
eurjchem-2214	395	24	of	of	ADP
eurjchem-2214	395	25	n	n	PRON
eurjchem-2214	395	26	-coordinated	-coordinated	PROPN
eurjchem-2214	395	27	nc	nc	PROPN
eurjchem-2214	395	28	−	−	PROPN
eurjchem-2214	395	29	and	and	CCONJ
eurjchem-2214	395	30	ncs−	ncs−	PROPN
eurjchem-2214	395	31	on	on	ADP
eurjchem-2214	395	32	nis2pn	nis2pn	PROPN
eurjchem-2214	395	33	:	:	PUNCT
eurjchem-2214	395	34	synthesis	synthesis	NOUN
eurjchem-2214	395	35	,	,	PUNCT
eurjchem-2214	395	36	spectral	spectral	ADJ
eurjchem-2214	395	37	and	and	CCONJ
eurjchem-2214	395	38	single	single	ADJ
eurjchem-2214	395	39	crystal	crystal	NOUN
eurjchem-2214	395	40	x	x	PROPN
eurjchem-2214	395	41	-	-	NOUN
eurjchem-2214	395	42	ray	ray	NOUN
eurjchem-2214	395	43	structural	structural	ADJ
eurjchem-2214	395	44	studies	study	NOUN
eurjchem-2214	395	45	on	on	ADP
eurjchem-2214	395	46	n	n	CCONJ
eurjchem-2214	395	47	,	,	PUNCT
eurjchem-2214	395	48	n	n	CCONJ
eurjchem-2214	395	49	′-din	′-din	VERB
eurjchem-2214	395	50	-butyldithiocarbamate	-butyldithiocarbamate	ADJ
eurjchem-2214	395	51	complexes	complex	NOUN
eurjchem-2214	395	52	of	of	ADP
eurjchem-2214	395	53	nickel(ii	nickel(ii	NOUN
eurjchem-2214	395	54	)	)	PUNCT
eurjchem-2214	395	55	with	with	ADP
eurjchem-2214	395	56	phosphorus	phosphorus	NOUN
eurjchem-2214	395	57	and	and	CCONJ
eurjchem-2214	395	58	nitrogen	nitrogen	NOUN
eurjchem-2214	395	59	donor	donor	NOUN
eurjchem-2214	395	60	ligands	ligand	NOUN
eurjchem-2214	395	61	.	.	PUNCT
eurjchem-2214	396	1	j.	j.	PROPN
eurjchem-2214	396	2	coord	coord	PROPN
eurjchem-2214	396	3	.	.	PUNCT
eurjchem-2214	397	1	chem	chem	PROPN
eurjchem-2214	397	2	.	.	PUNCT
eurjchem-2214	398	1	2008	2008	NUM
eurjchem-2214	398	2	,	,	PUNCT
eurjchem-2214	398	3	61	61	NUM
eurjchem-2214	398	4	,	,	PUNCT
eurjchem-2214	398	5	1710–1719	1710–1719	NUM
eurjchem-2214	398	6	.	.	PUNCT
eurjchem-2214	399	1	[	[	X
eurjchem-2214	399	2	16	16	NUM
eurjchem-2214	399	3	]	]	PUNCT
eurjchem-2214	399	4	.	.	PUNCT
eurjchem-2214	400	1	arul	arul	PROPN
eurjchem-2214	400	2	prakasam	prakasam	PROPN
eurjchem-2214	400	3	,	,	PUNCT
eurjchem-2214	400	4	b.	b.	PROPN
eurjchem-2214	400	5	;	;	PUNCT
eurjchem-2214	400	6	ramalingam	ramalingam	NOUN
eurjchem-2214	400	7	,	,	PUNCT
eurjchem-2214	400	8	k.	k.	PROPN
eurjchem-2214	400	9	;	;	PUNCT
eurjchem-2214	400	10	bocelli	bocelli	PROPN
eurjchem-2214	400	11	,	,	PUNCT
eurjchem-2214	400	12	g.	g.	PROPN
eurjchem-2214	400	13	;	;	PUNCT
eurjchem-2214	400	14	cantoni	cantoni	PROPN
eurjchem-2214	400	15	,	,	PUNCT
eurjchem-2214	400	16	a.	a.	NOUN
eurjchem-2214	400	17	steric	steric	ADJ
eurjchem-2214	400	18	and	and	CCONJ
eurjchem-2214	400	19	electronic	electronic	ADJ
eurjchem-2214	400	20	effects	effect	NOUN
eurjchem-2214	400	21	of	of	ADP
eurjchem-2214	400	22	substituents	substituent	NOUN
eurjchem-2214	400	23	on	on	ADP
eurjchem-2214	400	24	planar	planar	ADJ
eurjchem-2214	400	25	nickel(ii	nickel(ii	ADJ
eurjchem-2214	400	26	)	)	PUNCT
eurjchem-2214	400	27	complexes	complex	NOUN
eurjchem-2214	400	28	:	:	PUNCT
eurjchem-2214	400	29	synthesis	synthesis	NOUN
eurjchem-2214	400	30	,	,	PUNCT
eurjchem-2214	400	31	nmr	nmr	NOUN
eurjchem-2214	400	32	spectral	spectral	ADJ
eurjchem-2214	400	33	and	and	CCONJ
eurjchem-2214	400	34	single	single	ADJ
eurjchem-2214	400	35	crystal	crystal	NOUN
eurjchem-2214	400	36	x	x	PROPN
eurjchem-2214	400	37	-	-	NOUN
eurjchem-2214	400	38	ray	ray	NOUN
eurjchem-2214	400	39	structural	structural	ADJ
eurjchem-2214	400	40	studies	study	NOUN
eurjchem-2214	400	41	on	on	ADP
eurjchem-2214	400	42	nickel(ii	nickel(ii	ADJ
eurjchem-2214	400	43	)	)	PUNCT
eurjchem-2214	400	44	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2214	400	45	with	with	ADP
eurjchem-2214	400	46	nis2pn	nis2pn	PROPN
eurjchem-2214	400	47	,	,	PUNCT
eurjchem-2214	400	48	nis2pc	nis2pc	PROPN
eurjchem-2214	400	49	,	,	PUNCT
eurjchem-2214	400	50	and	and	CCONJ
eurjchem-2214	400	51	nis2p2	nis2p2	ADJ
eurjchem-2214	400	52	chromophores	chromophore	NOUN
eurjchem-2214	400	53	.	.	PUNCT
eurjchem-2214	401	1	bull	bull	NOUN
eurjchem-2214	401	2	.	.	PUNCT
eurjchem-2214	402	1	chem	chem	PROPN
eurjchem-2214	402	2	.	.	PUNCT
eurjchem-2214	403	1	soc	soc	PROPN
eurjchem-2214	403	2	.	.	PUNCT
eurjchem-2214	404	1	jpn	jpn	PROPN
eurjchem-2214	404	2	.	.	PROPN
eurjchem-2214	405	1	2006	2006	NUM
eurjchem-2214	405	2	,	,	PUNCT
eurjchem-2214	405	3	79	79	NUM
eurjchem-2214	405	4	,	,	PUNCT
eurjchem-2214	405	5	113–117	113–117	NUM
eurjchem-2214	405	6	.	.	PUNCT
eurjchem-2214	406	1	[	[	X
eurjchem-2214	406	2	17	17	NUM
eurjchem-2214	406	3	]	]	PUNCT
eurjchem-2214	406	4	.	.	PUNCT
eurjchem-2214	407	1	thiruneelakandan	thiruneelakandan	PROPN
eurjchem-2214	407	2	,	,	PUNCT
eurjchem-2214	407	3	r.	r.	PROPN
eurjchem-2214	407	4	;	;	PUNCT
eurjchem-2214	407	5	ramalingam	ramalingam	NOUN
eurjchem-2214	407	6	,	,	PUNCT
eurjchem-2214	407	7	k.	k.	PROPN
eurjchem-2214	407	8	;	;	PUNCT
eurjchem-2214	407	9	bocelli	bocelli	PROPN
eurjchem-2214	407	10	,	,	PUNCT
eurjchem-2214	407	11	g.	g.	PROPN
eurjchem-2214	407	12	;	;	PUNCT
eurjchem-2214	407	13	righi	righi	PROPN
eurjchem-2214	407	14	,	,	PUNCT
eurjchem-2214	407	15	l.	l.	PROPN
eurjchem-2214	407	16	synthesis	synthesis	PROPN
eurjchem-2214	407	17	,	,	PUNCT
eurjchem-2214	407	18	spectral	spectral	ADJ
eurjchem-2214	407	19	,	,	PUNCT
eurjchem-2214	407	20	cyclic	cyclic	ADJ
eurjchem-2214	407	21	voltammetric	voltammetric	ADJ
eurjchem-2214	407	22	studies	study	NOUN
eurjchem-2214	407	23	,	,	PUNCT
eurjchem-2214	407	24	and	and	CCONJ
eurjchem-2214	407	25	single	single	ADJ
eurjchem-2214	407	26	crystal	crystal	NOUN
eurjchem-2214	407	27	x	x	PROPN
eurjchem-2214	407	28	-	-	NOUN
eurjchem-2214	407	29	ray	ray	NOUN
eurjchem-2214	407	30	structure	structure	NOUN
eurjchem-2214	407	31	determination	determination	NOUN
eurjchem-2214	407	32	of	of	ADP
eurjchem-2214	407	33	the	the	DET
eurjchem-2214	407	34	planar	planar	ADJ
eurjchem-2214	407	35	nis2p2	nis2p2	NOUN
eurjchem-2214	407	36	,	,	PUNCT
eurjchem-2214	407	37	nis2pn	nis2pn	NOUN
eurjchem-2214	407	38	,	,	PUNCT
eurjchem-2214	407	39	and	and	CCONJ
eurjchem-2214	407	40	nis2pc	nis2pc	ADP
eurjchem-2214	407	41	chromophores	chromophore	NOUN
eurjchem-2214	407	42	.	.	PUNCT
eurjchem-2214	408	1	z.	z.	PROPN
eurjchem-2214	408	2	anorg	anorg	PROPN
eurjchem-2214	408	3	.	.	PUNCT
eurjchem-2214	409	1	allg	allg	PROPN
eurjchem-2214	409	2	.	.	PUNCT
eurjchem-2214	410	1	chem	chem	NOUN
eurjchem-2214	410	2	.	.	PUNCT
eurjchem-2214	411	1	2005	2005	NUM
eurjchem-2214	411	2	,	,	PUNCT
eurjchem-2214	411	3	631	631	NUM
eurjchem-2214	411	4	,	,	PUNCT
eurjchem-2214	411	5	187–193	187–193	NUM
eurjchem-2214	411	6	.	.	PUNCT
eurjchem-2214	412	1	[	[	X
eurjchem-2214	412	2	18	18	NUM
eurjchem-2214	412	3	]	]	PUNCT
eurjchem-2214	412	4	.	.	PUNCT
eurjchem-2214	413	1	ramalingam	ramalingam	PROPN
eurjchem-2214	413	2	,	,	PUNCT
eurjchem-2214	413	3	k.	k.	PROPN
eurjchem-2214	413	4	;	;	PUNCT
eurjchem-2214	413	5	thiruneelakandan	thiruneelakandan	PROPN
eurjchem-2214	413	6	,	,	PUNCT
eurjchem-2214	413	7	r.	r.	PROPN
eurjchem-2214	413	8	;	;	PUNCT
eurjchem-2214	413	9	bocelli	bocelli	PROPN
eurjchem-2214	413	10	,	,	PUNCT
eurjchem-2214	413	11	g.	g.	PROPN
eurjchem-2214	413	12	;	;	PUNCT
eurjchem-2214	413	13	righi	righi	PROPN
eurjchem-2214	413	14	,	,	PUNCT
eurjchem-2214	413	15	l.	l.	PROPN
eurjchem-2214	413	16	trans	trans	PROPN
eurjchem-2214	413	17	influence	influence	PROPN
eurjchem-2214	413	18	of	of	ADP
eurjchem-2214	413	19	triphenylphosphines	triphenylphosphine	NOUN
eurjchem-2214	413	20	and	and	CCONJ
eurjchem-2214	413	21	pseudohalogens	pseudohalogen	NOUN
eurjchem-2214	413	22	on	on	ADP
eurjchem-2214	413	23	ni	ni	PROPN
eurjchem-2214	413	24	-	-	PUNCT
eurjchem-2214	413	25	s	s	PART
eurjchem-2214	413	26	bonds	bond	NOUN
eurjchem-2214	413	27	:	:	PUNCT
eurjchem-2214	413	28	synthesis	synthesis	NOUN
eurjchem-2214	413	29	,	,	PUNCT
eurjchem-2214	413	30	spectral	spectral	ADJ
eurjchem-2214	413	31	and	and	CCONJ
eurjchem-2214	413	32	single	single	ADJ
eurjchem-2214	413	33	crystal	crystal	NOUN
eurjchem-2214	413	34	x	x	PROPN
eurjchem-2214	413	35	-	-	NOUN
eurjchem-2214	413	36	ray	ray	NOUN
eurjchem-2214	413	37	structural	structural	ADJ
eurjchem-2214	413	38	studies	study	NOUN
eurjchem-2214	413	39	on	on	ADP
eurjchem-2214	413	40	nis2pn	nis2pn	PROPN
eurjchem-2214	413	41	and	and	CCONJ
eurjchem-2214	413	42	nis2pc	nis2pc	PROPN
eurjchem-2214	413	43	chromophores	chromophore	NOUN
eurjchem-2214	413	44	.	.	PUNCT
eurjchem-2214	414	1	open	open	ADJ
eurjchem-2214	414	2	chem	chem	NOUN
eurjchem-2214	414	3	.	.	PUNCT
eurjchem-2214	415	1	2012	2012	NUM
eurjchem-2214	415	2	,	,	PUNCT
eurjchem-2214	415	3	10	10	NUM
eurjchem-2214	415	4	,	,	PUNCT
eurjchem-2214	415	5	1199–1207	1199–1207	NUM
eurjchem-2214	415	6	.	.	PUNCT
eurjchem-2214	416	1	[	[	X
eurjchem-2214	416	2	19	19	NUM
eurjchem-2214	416	3	]	]	PUNCT
eurjchem-2214	416	4	.	.	PUNCT
eurjchem-2214	417	1	bobinihi	bobinihi	PROPN
eurjchem-2214	417	2	,	,	PUNCT
eurjchem-2214	417	3	f.	f.	PROPN
eurjchem-2214	417	4	f.	f.	PROPN
eurjchem-2214	417	5	;	;	PUNCT
eurjchem-2214	417	6	onwudiwe	onwudiwe	NOUN
eurjchem-2214	417	7	,	,	PUNCT
eurjchem-2214	417	8	d.	d.	PROPN
eurjchem-2214	417	9	c.	c.	PROPN
eurjchem-2214	417	10	;	;	PUNCT
eurjchem-2214	417	11	ekennia	ekennia	NOUN
eurjchem-2214	417	12	,	,	PUNCT
eurjchem-2214	417	13	a.	a.	NOUN
eurjchem-2214	417	14	c.	c.	PROPN
eurjchem-2214	417	15	;	;	PUNCT
eurjchem-2214	417	16	okpareke	okpareke	ADJ
eurjchem-2214	417	17	,	,	PUNCT
eurjchem-2214	417	18	o.	o.	PROPN
eurjchem-2214	417	19	c.	c.	PROPN
eurjchem-2214	417	20	;	;	PUNCT
eurjchem-2214	417	21	arderne	arderne	PROPN
eurjchem-2214	417	22	,	,	PUNCT
eurjchem-2214	417	23	c.	c.	PROPN
eurjchem-2214	417	24	;	;	PUNCT
eurjchem-2214	417	25	lane	lane	PROPN
eurjchem-2214	417	26	,	,	PUNCT
eurjchem-2214	417	27	j.	j.	PROPN
eurjchem-2214	417	28	r.	r.	PROPN
eurjchem-2214	417	29	group	group	PROPN
eurjchem-2214	417	30	10	10	NUM
eurjchem-2214	417	31	metal	metal	NOUN
eurjchem-2214	417	32	complexes	complex	NOUN
eurjchem-2214	417	33	of	of	ADP
eurjchem-2214	417	34	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2214	417	35	derived	derive	VERB
eurjchem-2214	417	36	from	from	ADP
eurjchem-2214	417	37	primary	primary	ADJ
eurjchem-2214	417	38	anilines	aniline	NOUN
eurjchem-2214	417	39	:	:	PUNCT
eurjchem-2214	417	40	synthesis	synthesis	NOUN
eurjchem-2214	417	41	,	,	PUNCT
eurjchem-2214	417	42	characterization	characterization	NOUN
eurjchem-2214	417	43	,	,	PUNCT
eurjchem-2214	417	44	computational	computational	ADJ
eurjchem-2214	417	45	and	and	CCONJ
eurjchem-2214	417	46	antimicrobial	antimicrobial	ADJ
eurjchem-2214	417	47	studies	study	NOUN
eurjchem-2214	417	48	.	.	PUNCT
eurjchem-2214	418	1	polyhedron	polyhedron	NOUN
eurjchem-2214	418	2	2019	2019	NUM
eurjchem-2214	418	3	,	,	PUNCT
eurjchem-2214	418	4	158	158	NUM
eurjchem-2214	418	5	,	,	PUNCT
eurjchem-2214	418	6	296–310	296–310	NUM
eurjchem-2214	418	7	.	.	PUNCT
eurjchem-2214	419	1	[	[	X
eurjchem-2214	419	2	20	20	NUM
eurjchem-2214	419	3	]	]	PUNCT
eurjchem-2214	419	4	.	.	PUNCT
eurjchem-2214	420	1	han	han	PROPN
eurjchem-2214	420	2	,	,	PUNCT
eurjchem-2214	420	3	j.	j.	PROPN
eurjchem-2214	420	4	;	;	PUNCT
eurjchem-2214	420	5	zhang	zhang	PROPN
eurjchem-2214	420	6	,	,	PUNCT
eurjchem-2214	420	7	w.	w.	PROPN
eurjchem-2214	420	8	;	;	PUNCT
eurjchem-2214	420	9	zhou	zhou	PROPN
eurjchem-2214	420	10	,	,	PUNCT
eurjchem-2214	420	11	t.	t.	PROPN
eurjchem-2214	420	12	;	;	PUNCT
eurjchem-2214	420	13	wang	wang	PROPN
eurjchem-2214	420	14	,	,	PUNCT
eurjchem-2214	420	15	x.	x.	PROPN
eurjchem-2214	420	16	;	;	PUNCT
eurjchem-2214	420	17	xu	xu	PROPN
eurjchem-2214	420	18	,	,	PUNCT
eurjchem-2214	420	19	r.	r.	PROPN
eurjchem-2214	420	20	nickel	nickel	NOUN
eurjchem-2214	420	21	-	-	PUNCT
eurjchem-2214	420	22	complexes	complex	NOUN
eurjchem-2214	420	23	with	with	ADP
eurjchem-2214	420	24	a	a	DET
eurjchem-2214	420	25	mixed	mixed	ADJ
eurjchem-2214	420	26	-	-	PUNCT
eurjchem-2214	420	27	donor	donor	NOUN
eurjchem-2214	420	28	ligand	ligand	NOUN
eurjchem-2214	420	29	for	for	ADP
eurjchem-2214	420	30	photocatalytic	photocatalytic	ADJ
eurjchem-2214	420	31	hydrogen	hydrogen	NOUN
eurjchem-2214	420	32	evolution	evolution	NOUN
eurjchem-2214	420	33	from	from	ADP
eurjchem-2214	420	34	aqueous	aqueous	ADJ
eurjchem-2214	420	35	solutions	solution	NOUN
eurjchem-2214	420	36	under	under	ADP
eurjchem-2214	420	37	visible	visible	ADJ
eurjchem-2214	420	38	light	light	NOUN
eurjchem-2214	420	39	.	.	PUNCT
eurjchem-2214	421	1	rsc	rsc	PROPN
eurjchem-2214	421	2	adv	adv	PROPN
eurjchem-2214	421	3	.	.	PROPN
eurjchem-2214	421	4	2012	2012	NUM
eurjchem-2214	421	5	,	,	PUNCT
eurjchem-2214	421	6	2	2	NUM
eurjchem-2214	421	7	,	,	PUNCT
eurjchem-2214	421	8	8293–8296	8293–8296	NUM
eurjchem-2214	421	9	.	.	PUNCT
eurjchem-2214	422	1	[	[	X
eurjchem-2214	422	2	21	21	NUM
eurjchem-2214	422	3	]	]	PUNCT
eurjchem-2214	422	4	.	.	PUNCT
eurjchem-2214	423	1	gao	gao	PROPN
eurjchem-2214	423	2	,	,	PUNCT
eurjchem-2214	423	3	m.-r	m.-r	PROPN
eurjchem-2214	423	4	.	.	PUNCT
eurjchem-2214	423	5	;	;	PUNCT
eurjchem-2214	423	6	xu	xu	PROPN
eurjchem-2214	423	7	,	,	PUNCT
eurjchem-2214	423	8	y.-f	y.-f	PROPN
eurjchem-2214	423	9	.	.	PUNCT
eurjchem-2214	423	10	;	;	PUNCT
eurjchem-2214	423	11	jiang	jiang	PROPN
eurjchem-2214	423	12	,	,	PUNCT
eurjchem-2214	423	13	j.	j.	PROPN
eurjchem-2214	423	14	;	;	PUNCT
eurjchem-2214	423	15	yu	yu	PROPN
eurjchem-2214	423	16	,	,	PUNCT
eurjchem-2214	423	17	s.-h	s.-h	NOUN
eurjchem-2214	423	18	.	.	PUNCT
eurjchem-2214	424	1	nanostructured	nanostructure	VERB
eurjchem-2214	424	2	metal	metal	NOUN
eurjchem-2214	424	3	chalcogenides	chalcogenide	NOUN
eurjchem-2214	424	4	:	:	PUNCT
eurjchem-2214	424	5	synthesis	synthesis	NOUN
eurjchem-2214	424	6	,	,	PUNCT
eurjchem-2214	424	7	modification	modification	NOUN
eurjchem-2214	424	8	,	,	PUNCT
eurjchem-2214	424	9	and	and	CCONJ
eurjchem-2214	424	10	applications	application	NOUN
eurjchem-2214	424	11	in	in	ADP
eurjchem-2214	424	12	energy	energy	NOUN
eurjchem-2214	424	13	conversion	conversion	NOUN
eurjchem-2214	424	14	and	and	CCONJ
eurjchem-2214	424	15	storage	storage	NOUN
eurjchem-2214	424	16	devices	device	NOUN
eurjchem-2214	424	17	.	.	PUNCT
eurjchem-2214	425	1	chem	chem	NOUN
eurjchem-2214	425	2	.	.	PUNCT
eurjchem-2214	426	1	soc	soc	PROPN
eurjchem-2214	426	2	.	.	PUNCT
eurjchem-2214	427	1	rev	rev	PROPN
eurjchem-2214	427	2	.	.	PROPN
eurjchem-2214	427	3	2013	2013	NUM
eurjchem-2214	427	4	,	,	PUNCT
eurjchem-2214	427	5	42	42	NUM
eurjchem-2214	427	6	,	,	PUNCT
eurjchem-2214	427	7	2986–3017	2986–3017	NUM
eurjchem-2214	427	8	.	.	PUNCT
eurjchem-2214	428	1	[	[	X
eurjchem-2214	428	2	22	22	NUM
eurjchem-2214	428	3	]	]	PUNCT
eurjchem-2214	428	4	.	.	PUNCT
eurjchem-2214	429	1	kershaw	kershaw	PROPN
eurjchem-2214	429	2	,	,	PUNCT
eurjchem-2214	429	3	s.	s.	PROPN
eurjchem-2214	429	4	v.	v.	PROPN
eurjchem-2214	429	5	;	;	PUNCT
eurjchem-2214	429	6	susha	susha	PROPN
eurjchem-2214	429	7	,	,	PUNCT
eurjchem-2214	429	8	a.	a.	NOUN
eurjchem-2214	429	9	s.	s.	PROPN
eurjchem-2214	429	10	;	;	PUNCT
eurjchem-2214	429	11	rogach	rogach	NOUN
eurjchem-2214	429	12	,	,	PUNCT
eurjchem-2214	429	13	a.	a.	PROPN
eurjchem-2214	429	14	l.	l.	PROPN
eurjchem-2214	429	15	narrow	narrow	PROPN
eurjchem-2214	429	16	bandgap	bandgap	PROPN
eurjchem-2214	429	17	colloidal	colloidal	NOUN
eurjchem-2214	429	18	metal	metal	NOUN
eurjchem-2214	429	19	chalcogenide	chalcogenide	NOUN
eurjchem-2214	429	20	quantum	quantum	ADJ
eurjchem-2214	429	21	dots	dot	NOUN
eurjchem-2214	429	22	:	:	PUNCT
eurjchem-2214	429	23	synthetic	synthetic	ADJ
eurjchem-2214	429	24	methods	method	NOUN
eurjchem-2214	429	25	,	,	PUNCT
eurjchem-2214	429	26	heterostructures	heterostructure	NOUN
eurjchem-2214	429	27	,	,	PUNCT
eurjchem-2214	429	28	assemblies	assembly	NOUN
eurjchem-2214	429	29	,	,	PUNCT
eurjchem-2214	429	30	electronic	electronic	ADJ
eurjchem-2214	429	31	and	and	CCONJ
eurjchem-2214	429	32	infrared	infrared	ADJ
eurjchem-2214	429	33	optical	optical	ADJ
eurjchem-2214	429	34	properties	property	NOUN
eurjchem-2214	429	35	.	.	PUNCT
eurjchem-2214	430	1	chem	chem	NOUN
eurjchem-2214	430	2	.	.	PUNCT
eurjchem-2214	431	1	soc	soc	PROPN
eurjchem-2214	431	2	.	.	PUNCT
eurjchem-2214	432	1	rev	rev	PROPN
eurjchem-2214	432	2	.	.	PROPN
eurjchem-2214	432	3	2013	2013	NUM
eurjchem-2214	432	4	,	,	PUNCT
eurjchem-2214	432	5	42	42	NUM
eurjchem-2214	432	6	,	,	PUNCT
eurjchem-2214	432	7	3033–3087	3033–3087	NUM
eurjchem-2214	432	8	.	.	PUNCT
eurjchem-2214	433	1	[	[	X
eurjchem-2214	433	2	23	23	NUM
eurjchem-2214	433	3	]	]	PUNCT
eurjchem-2214	433	4	.	.	PUNCT
eurjchem-2214	434	1	abu	abu	PROPN
eurjchem-2214	434	2	-	-	PUNCT
eurjchem-2214	434	3	surrah	surrah	PROPN
eurjchem-2214	434	4	,	,	PUNCT
eurjchem-2214	434	5	a.	a.	PROPN
eurjchem-2214	434	6	s.	s.	PROPN
eurjchem-2214	434	7	;	;	PUNCT
eurjchem-2214	434	8	kettunen	kettunen	PROPN
eurjchem-2214	434	9	,	,	PUNCT
eurjchem-2214	434	10	m.	m.	NOUN
eurjchem-2214	434	11	platinum	platinum	NOUN
eurjchem-2214	434	12	group	group	NOUN
eurjchem-2214	434	13	antitumor	antitumor	PROPN
eurjchem-2214	434	14	chemistry	chemistry	NOUN
eurjchem-2214	434	15	:	:	PUNCT
eurjchem-2214	434	16	design	design	NOUN
eurjchem-2214	434	17	and	and	CCONJ
eurjchem-2214	434	18	development	development	NOUN
eurjchem-2214	434	19	of	of	ADP
eurjchem-2214	434	20	new	new	ADJ
eurjchem-2214	434	21	anticancer	anticancer	NOUN
eurjchem-2214	434	22	drugs	drug	NOUN
eurjchem-2214	434	23	complementary	complementary	ADJ
eurjchem-2214	434	24	to	to	ADP
eurjchem-2214	434	25	cisplatin	cisplatin	NOUN
eurjchem-2214	434	26	.	.	PUNCT
eurjchem-2214	435	1	curr	curr	AUX
eurjchem-2214	435	2	.	.	PUNCT
eurjchem-2214	435	3	med	med	PROPN
eurjchem-2214	435	4	.	.	PROPN
eurjchem-2214	435	5	chem	chem	PROPN
eurjchem-2214	435	6	.	.	PUNCT
eurjchem-2214	436	1	2006	2006	NUM
eurjchem-2214	436	2	,	,	PUNCT
eurjchem-2214	436	3	13	13	NUM
eurjchem-2214	436	4	,	,	PUNCT
eurjchem-2214	436	5	1337–1357	1337–1357	NUM
eurjchem-2214	436	6	.	.	PUNCT
eurjchem-2214	437	1	[	[	X
eurjchem-2214	437	2	24	24	NUM
eurjchem-2214	437	3	]	]	PUNCT
eurjchem-2214	437	4	.	.	PUNCT
eurjchem-2214	438	1	weiss	weiss	PROPN
eurjchem-2214	438	2	,	,	PUNCT
eurjchem-2214	438	3	r.	r.	PROPN
eurjchem-2214	438	4	b.	b.	PROPN
eurjchem-2214	438	5	;	;	PUNCT
eurjchem-2214	438	6	christian	christian	PROPN
eurjchem-2214	438	7	,	,	PUNCT
eurjchem-2214	438	8	m.	m.	NOUN
eurjchem-2214	438	9	c.	c.	PROPN
eurjchem-2214	438	10	new	new	ADJ
eurjchem-2214	438	11	cisplatin	cisplatin	NOUN
eurjchem-2214	438	12	analogues	analogue	NOUN
eurjchem-2214	438	13	in	in	ADP
eurjchem-2214	438	14	development	development	NOUN
eurjchem-2214	438	15	.	.	PUNCT
eurjchem-2214	439	1	a	a	DET
eurjchem-2214	439	2	review	review	NOUN
eurjchem-2214	439	3	:	:	PUNCT
eurjchem-2214	439	4	a	a	DET
eurjchem-2214	439	5	review	review	NOUN
eurjchem-2214	439	6	.	.	PUNCT
eurjchem-2214	440	1	drugs	drug	NOUN
eurjchem-2214	440	2	1993	1993	NUM
eurjchem-2214	440	3	,	,	PUNCT
eurjchem-2214	440	4	46	46	NUM
eurjchem-2214	440	5	,	,	PUNCT
eurjchem-2214	440	6	360–377	360–377	NUM
eurjchem-2214	440	7	.	.	PUNCT
eurjchem-2214	441	1	http://www.ccdc.cam.ac.uk/data_request/cif	http://www.ccdc.cam.ac.uk/data_request/cif	PRON
eurjchem-2214	441	2	mailto:data_request@ccdc.cam.ac.uk	mailto:data_request@ccdc.cam.ac.uk	NOUN
eurjchem-2214	441	3	mailto:krauchem@yahoo.com	mailto:krauchem@yahoo.com	NOUN
eurjchem-2214	442	1	https://orcid.org/0000-0001-8689-8007	https://orcid.org/0000-0001-8689-8007	INTJ
eurjchem-2214	442	2	mailto:sarchem@yahoo.com	mailto:sarchem@yahoo.com	X
eurjchem-2214	442	3	https://orcid.org/0000-0003-4740-307x	https://orcid.org/0000-0003-4740-307x	NUM
eurjchem-2214	442	4	mailto:bocelli@unipr.it	mailto:bocelli@unipr.it	PROPN
eurjchem-2214	442	5	https://orcid.org/0000-0003-3196-8885	https://orcid.org/0000-0003-3196-8885	NOUN
eurjchem-2214	442	6	mailto:lara.righi@unipr.it	mailto:lara.righi@unipr.it	ADJ
eurjchem-2214	442	7	https://orcid.org/0000-0001-9372-5438	https://orcid.org/0000-0001-9372-5438	NOUN
eurjchem-2214	442	8	mailto:chumakov@phys.asm.md	mailto:chumakov@phys.asm.md	NOUN
eurjchem-2214	442	9	https://orcid.org/0000-0003-2582-2871	https://orcid.org/0000-0003-2582-2871	PROPN
eurjchem-2214	442	10	mailto:provolo@pop.unipr.it	mailto:provolo@pop.unipr.it	NOUN
eurjchem-2214	442	11	https://orcid.org/0000-0001-7224-3253	https://orcid.org/0000-0001-7224-3253	INTJ
eurjchem-2214	442	12	ramalingam	ramalingam	NOUN
eurjchem-2214	442	13	et	et	PROPN
eurjchem-2214	442	14	al	al	PROPN
eurjchem-2214	442	15	.	.	PUNCT
eurjchem-2214	442	16	/	/	SYM
eurjchem-2214	442	17	european	european	PROPN
eurjchem-2214	442	18	journal	journal	PROPN
eurjchem-2214	442	19	of	of	ADP
eurjchem-2214	442	20	chemistry	chemistry	NOUN
eurjchem-2214	442	21	13	13	NUM
eurjchem-2214	442	22	(	(	PUNCT
eurjchem-2214	442	23	1	1	NUM
eurjchem-2214	442	24	)	)	PUNCT
eurjchem-2214	442	25	(	(	PUNCT
eurjchem-2214	442	26	2022	2022	NUM
eurjchem-2214	442	27	)	)	PUNCT
eurjchem-2214	442	28	117	117	NUM
eurjchem-2214	442	29	-	-	SYM
eurjchem-2214	442	30	125	125	NUM
eurjchem-2214	442	31	125	125	NUM
eurjchem-2214	442	32	2022	2022	NUM
eurjchem-2214	442	33	–	–	PUNCT
eurjchem-2214	442	34	european	european	ADJ
eurjchem-2214	442	35	journal	journal	NOUN
eurjchem-2214	442	36	of	of	ADP
eurjchem-2214	442	37	chemistry	chemistry	NOUN
eurjchem-2214	442	38	–	–	PUNCT
eurjchem-2214	442	39	cc	cc	NOUN
eurjchem-2214	442	40	by	by	ADP
eurjchem-2214	442	41	nc	nc	PROPN
eurjchem-2214	442	42	–	–	PUNCT
eurjchem-2214	442	43	doi	doi	NOUN
eurjchem-2214	442	44	:	:	PUNCT
eurjchem-2214	442	45	10.5155	10.5155	NUM
eurjchem-2214	442	46	/	/	SYM
eurjchem-2214	442	47	eurjchem.13.1.117	eurjchem.13.1.117	VERB
eurjchem-2214	442	48	-	-	SYM
eurjchem-2214	442	49	125.2214	125.2214	NUM
eurjchem-2214	442	50	[	[	X
eurjchem-2214	442	51	25	25	NUM
eurjchem-2214	442	52	]	]	PUNCT
eurjchem-2214	442	53	.	.	PUNCT
eurjchem-2214	443	1	lebwohl	lebwohl	PROPN
eurjchem-2214	443	2	,	,	PUNCT
eurjchem-2214	443	3	d.	d.	PROPN
eurjchem-2214	443	4	;	;	PUNCT
eurjchem-2214	443	5	canetta	canetta	PROPN
eurjchem-2214	443	6	,	,	PUNCT
eurjchem-2214	443	7	r.	r.	PROPN
eurjchem-2214	443	8	clinical	clinical	PROPN
eurjchem-2214	443	9	development	development	NOUN
eurjchem-2214	443	10	of	of	ADP
eurjchem-2214	443	11	platinum	platinum	NOUN
eurjchem-2214	443	12	complexes	complex	NOUN
eurjchem-2214	443	13	in	in	ADP
eurjchem-2214	443	14	cancer	cancer	NOUN
eurjchem-2214	443	15	therapy	therapy	NOUN
eurjchem-2214	443	16	:	:	PUNCT
eurjchem-2214	443	17	an	an	DET
eurjchem-2214	443	18	historical	historical	ADJ
eurjchem-2214	443	19	perspective	perspective	NOUN
eurjchem-2214	443	20	and	and	CCONJ
eurjchem-2214	443	21	an	an	DET
eurjchem-2214	443	22	update	update	NOUN
eurjchem-2214	443	23	.	.	PUNCT
eurjchem-2214	444	1	eur	eur	PROPN
eurjchem-2214	444	2	.	.	PUNCT
eurjchem-2214	445	1	j.	j.	PROPN
eurjchem-2214	445	2	cancer	cancer	PROPN
eurjchem-2214	445	3	1998	1998	NUM
eurjchem-2214	445	4	,	,	PUNCT
eurjchem-2214	445	5	34	34	NUM
eurjchem-2214	445	6	,	,	PUNCT
eurjchem-2214	445	7	1522–1534	1522–1534	NUM
eurjchem-2214	445	8	.	.	PUNCT
eurjchem-2214	446	1	[	[	X
eurjchem-2214	446	2	26	26	NUM
eurjchem-2214	446	3	]	]	PUNCT
eurjchem-2214	446	4	.	.	PUNCT
eurjchem-2214	447	1	wong	wong	PROPN
eurjchem-2214	447	2	,	,	PUNCT
eurjchem-2214	447	3	e.	e.	PROPN
eurjchem-2214	447	4	;	;	PUNCT
eurjchem-2214	447	5	giandomenico	giandomenico	PROPN
eurjchem-2214	447	6	,	,	PUNCT
eurjchem-2214	447	7	c.	c.	PROPN
eurjchem-2214	447	8	m.	m.	PROPN
eurjchem-2214	447	9	current	current	ADJ
eurjchem-2214	447	10	status	status	NOUN
eurjchem-2214	447	11	of	of	ADP
eurjchem-2214	447	12	platinum	platinum	NOUN
eurjchem-2214	447	13	-	-	PUNCT
eurjchem-2214	447	14	based	base	VERB
eurjchem-2214	447	15	antitumor	antitumor	PROPN
eurjchem-2214	447	16	drugs	drug	NOUN
eurjchem-2214	447	17	.	.	PUNCT
eurjchem-2214	448	1	chem	chem	PROPN
eurjchem-2214	448	2	.	.	PUNCT
eurjchem-2214	449	1	rev	rev	PROPN
eurjchem-2214	449	2	.	.	PROPN
eurjchem-2214	449	3	1999	1999	NUM
eurjchem-2214	449	4	,	,	PUNCT
eurjchem-2214	449	5	99	99	NUM
eurjchem-2214	449	6	,	,	PUNCT
eurjchem-2214	449	7	2451–2466	2451–2466	NUM
eurjchem-2214	449	8	.	.	PUNCT
eurjchem-2214	450	1	[	[	X
eurjchem-2214	450	2	27	27	NUM
eurjchem-2214	450	3	]	]	PUNCT
eurjchem-2214	450	4	.	.	PUNCT
eurjchem-2214	451	1	amable	amable	ADJ
eurjchem-2214	451	2	,	,	PUNCT
eurjchem-2214	451	3	l.	l.	PROPN
eurjchem-2214	451	4	cisplatin	cisplatin	PROPN
eurjchem-2214	451	5	resistance	resistance	NOUN
eurjchem-2214	451	6	and	and	CCONJ
eurjchem-2214	451	7	opportunities	opportunity	NOUN
eurjchem-2214	451	8	for	for	ADP
eurjchem-2214	451	9	precision	precision	NOUN
eurjchem-2214	451	10	medicine	medicine	NOUN
eurjchem-2214	451	11	.	.	PUNCT
eurjchem-2214	452	1	pharmacol	pharmacol	NOUN
eurjchem-2214	452	2	.	.	PUNCT
eurjchem-2214	453	1	res	re	NOUN
eurjchem-2214	453	2	.	.	PROPN
eurjchem-2214	453	3	2016	2016	NUM
eurjchem-2214	453	4	,	,	PUNCT
eurjchem-2214	453	5	106	106	NUM
eurjchem-2214	453	6	,	,	PUNCT
eurjchem-2214	453	7	27–36	27–36	NUM
eurjchem-2214	453	8	.	.	PUNCT
eurjchem-2214	454	1	[	[	X
eurjchem-2214	454	2	28	28	NUM
eurjchem-2214	454	3	]	]	PUNCT
eurjchem-2214	454	4	.	.	PUNCT
eurjchem-2214	455	1	reedijk	reedijk	PROPN
eurjchem-2214	455	2	,	,	PUNCT
eurjchem-2214	455	3	j.	j.	PROPN
eurjchem-2214	455	4	improved	improve	VERB
eurjchem-2214	455	5	understanding	understanding	NOUN
eurjchem-2214	455	6	in	in	ADP
eurjchem-2214	455	7	platiniumantitumour	platiniumantitumour	ADJ
eurjchem-2214	455	8	chemistry	chemistry	NOUN
eurjchem-2214	455	9	.	.	PUNCT
eurjchem-2214	456	1	chem	chem	PROPN
eurjchem-2214	456	2	.	.	PUNCT
eurjchem-2214	457	1	commun	commun	PROPN
eurjchem-2214	457	2	.	.	PUNCT
eurjchem-2214	458	1	(	(	PUNCT
eurjchem-2214	458	2	camb	camb	PROPN
eurjchem-2214	458	3	.	.	PUNCT
eurjchem-2214	458	4	)	)	PUNCT
eurjchem-2214	458	5	1996	1996	NUM
eurjchem-2214	458	6	,	,	PUNCT
eurjchem-2214	458	7	7	7	NUM
eurjchem-2214	458	8	,	,	PUNCT
eurjchem-2214	458	9	801–806	801–806	NUM
eurjchem-2214	458	10	.	.	PUNCT
eurjchem-2214	459	1	[	[	X
eurjchem-2214	459	2	29	29	NUM
eurjchem-2214	459	3	]	]	PUNCT
eurjchem-2214	459	4	.	.	PUNCT
eurjchem-2214	460	1	miller	miller	PROPN
eurjchem-2214	460	2	,	,	PUNCT
eurjchem-2214	460	3	r.	r.	PROPN
eurjchem-2214	460	4	p.	p.	PROPN
eurjchem-2214	460	5	;	;	PUNCT
eurjchem-2214	460	6	tadagavadi	tadagavadi	PROPN
eurjchem-2214	460	7	,	,	PUNCT
eurjchem-2214	460	8	r.	r.	PROPN
eurjchem-2214	460	9	k.	k.	PROPN
eurjchem-2214	460	10	;	;	PUNCT
eurjchem-2214	460	11	ramesh	ramesh	PROPN
eurjchem-2214	460	12	,	,	PUNCT
eurjchem-2214	460	13	g.	g.	PROPN
eurjchem-2214	460	14	;	;	PUNCT
eurjchem-2214	460	15	reeves	reeves	PROPN
eurjchem-2214	460	16	,	,	PUNCT
eurjchem-2214	460	17	w.	w.	PROPN
eurjchem-2214	460	18	b.	b.	PROPN
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eurjchem-2214	460	20	of	of	ADP
eurjchem-2214	460	21	cisplatin	cisplatin	NOUN
eurjchem-2214	460	22	nephrotoxicity	nephrotoxicity	NOUN
eurjchem-2214	460	23	.	.	PUNCT
eurjchem-2214	461	1	toxins	toxin	NOUN
eurjchem-2214	461	2	(	(	PUNCT
eurjchem-2214	461	3	basel	basel	PROPN
eurjchem-2214	461	4	)	)	PUNCT
eurjchem-2214	461	5	2010	2010	NUM
eurjchem-2214	461	6	,	,	PUNCT
eurjchem-2214	461	7	2	2	NUM
eurjchem-2214	461	8	,	,	PUNCT
eurjchem-2214	461	9	2490–2518	2490–2518	NUM
eurjchem-2214	461	10	.	.	PUNCT
eurjchem-2214	462	1	[	[	X
eurjchem-2214	462	2	30	30	NUM
eurjchem-2214	462	3	]	]	PUNCT
eurjchem-2214	462	4	.	.	PUNCT
eurjchem-2214	463	1	milbeo	milbeo	NOUN
eurjchem-2214	463	2	,	,	PUNCT
eurjchem-2214	463	3	p.	p.	NOUN
eurjchem-2214	463	4	;	;	PUNCT
eurjchem-2214	463	5	quintin	quintin	PROPN
eurjchem-2214	463	6	,	,	PUNCT
eurjchem-2214	463	7	f.	f.	PROPN
eurjchem-2214	463	8	;	;	PUNCT
eurjchem-2214	463	9	moulat	moulat	PROPN
eurjchem-2214	463	10	,	,	PUNCT
eurjchem-2214	463	11	l.	l.	PROPN
eurjchem-2214	463	12	;	;	PUNCT
eurjchem-2214	463	13	didierjean	didierjean	PROPN
eurjchem-2214	463	14	,	,	PUNCT
eurjchem-2214	463	15	c.	c.	PROPN
eurjchem-2214	463	16	;	;	PUNCT
eurjchem-2214	463	17	martinez	martinez	PROPN
eurjchem-2214	463	18	,	,	PUNCT
eurjchem-2214	463	19	j.	j.	PROPN
eurjchem-2214	463	20	;	;	PUNCT
eurjchem-2214	463	21	bantreil	bantreil	PROPN
eurjchem-2214	463	22	,	,	PUNCT
eurjchem-2214	463	23	x.	x.	NOUN
eurjchem-2214	463	24	;	;	PUNCT
eurjchem-2214	463	25	calmès	calmès	NOUN
eurjchem-2214	463	26	,	,	PUNCT
eurjchem-2214	463	27	m.	m.	NOUN
eurjchem-2214	463	28	;	;	PUNCT
eurjchem-2214	463	29	lamaty	lamaty	PROPN
eurjchem-2214	463	30	,	,	PUNCT
eurjchem-2214	463	31	f.	f.	PROPN
eurjchem-2214	463	32	synthesis	synthesis	PROPN
eurjchem-2214	463	33	,	,	PUNCT
eurjchem-2214	463	34	characterisation	characterisation	NOUN
eurjchem-2214	463	35	and	and	CCONJ
eurjchem-2214	463	36	cytotoxic	cytotoxic	ADJ
eurjchem-2214	463	37	activity	activity	NOUN
eurjchem-2214	463	38	evaluation	evaluation	NOUN
eurjchem-2214	463	39	of	of	ADP
eurjchem-2214	463	40	new	new	ADJ
eurjchem-2214	463	41	metal	metal	NOUN
eurjchem-2214	463	42	-	-	PUNCT
eurjchem-2214	463	43	salen	salen	NOUN
eurjchem-2214	463	44	complexes	complex	NOUN
eurjchem-2214	463	45	based	base	VERB
eurjchem-2214	463	46	on	on	ADP
eurjchem-2214	463	47	the	the	DET
eurjchem-2214	463	48	1,2bicyclo[2.2.2]octane	1,2bicyclo[2.2.2]octane	PROPN
eurjchem-2214	463	49	bridge	bridge	NOUN
eurjchem-2214	463	50	.	.	PUNCT
eurjchem-2214	464	1	tetrahedron	tetrahedron	PROPN
eurjchem-2214	464	2	lett	lett	PROPN
eurjchem-2214	464	3	.	.	PROPN
eurjchem-2214	464	4	2021	2021	NUM
eurjchem-2214	464	5	,	,	PUNCT
eurjchem-2214	464	6	63	63	NUM
eurjchem-2214	464	7	,	,	PUNCT
eurjchem-2214	464	8	152706	152706	NUM
eurjchem-2214	464	9	.	.	PUNCT
eurjchem-2214	465	1	[	[	X
eurjchem-2214	465	2	31	31	NUM
eurjchem-2214	465	3	]	]	PUNCT
eurjchem-2214	465	4	.	.	PUNCT
eurjchem-2214	466	1	bruker	bruker	PROPN
eurjchem-2214	466	2	(	(	PUNCT
eurjchem-2214	466	3	2009	2009	NUM
eurjchem-2214	466	4	)	)	PUNCT
eurjchem-2214	466	5	.	.	PUNCT
eurjchem-2214	467	1	sadabs	sadab	NOUN
eurjchem-2214	467	2	.	.	PUNCT
eurjchem-2214	468	1	bruker	bruker	PROPN
eurjchem-2214	468	2	axs	axs	PROPN
eurjchem-2214	468	3	inc	inc	PROPN
eurjchem-2214	468	4	.	.	PROPN
eurjchem-2214	468	5	,	,	PUNCT
eurjchem-2214	468	6	madison	madison	PROPN
eurjchem-2214	468	7	,	,	PUNCT
eurjchem-2214	468	8	wisconsin	wisconsin	PROPN
eurjchem-2214	468	9	,	,	PUNCT
eurjchem-2214	468	10	usa	usa	PROPN
eurjchem-2214	468	11	.	.	PUNCT
eurjchem-2214	469	1	[	[	X
eurjchem-2214	469	2	32	32	NUM
eurjchem-2214	469	3	]	]	PUNCT
eurjchem-2214	469	4	.	.	PUNCT
eurjchem-2214	470	1	bruker	bruker	PROPN
eurjchem-2214	470	2	axs	axs	PROPN
eurjchem-2214	470	3	,	,	PUNCT
eurjchem-2214	470	4	inc.6300	inc.6300	NUM
eurjchem-2214	470	5	,	,	PUNCT
eurjchem-2214	470	6	enterprise	enterprise	NOUN
eurjchem-2214	470	7	lane	lane	NOUN
eurjchem-2214	470	8	,	,	PUNCT
eurjchem-2214	470	9	madison	madison	PROPN
eurjchem-2214	470	10	,	,	PUNCT
eurjchem-2214	470	11	wi	wi	PROPN
eurjchem-2214	470	12	.	.	PROPN
eurjchem-2214	470	13	5179	5179	NUM
eurjchem-2214	470	14	-	-	SYM
eurjchem-2214	470	15	1173	1173	NUM
eurjchem-2214	470	16	.	.	PUNCT
eurjchem-2214	471	1	usa	usa	PROPN
eurjchem-2214	471	2	.	.	PUNCT
eurjchem-2214	472	1	[	[	X
eurjchem-2214	472	2	33	33	NUM
eurjchem-2214	472	3	]	]	PUNCT
eurjchem-2214	472	4	.	.	PUNCT
eurjchem-2214	473	1	dolomanov	dolomanov	PROPN
eurjchem-2214	473	2	,	,	PUNCT
eurjchem-2214	473	3	o.	o.	PROPN
eurjchem-2214	473	4	v.	v.	PROPN
eurjchem-2214	473	5	;	;	PUNCT
eurjchem-2214	473	6	bourhis	bourhis	NOUN
eurjchem-2214	473	7	,	,	PUNCT
eurjchem-2214	473	8	l.	l.	PROPN
eurjchem-2214	473	9	j.	j.	PROPN
eurjchem-2214	473	10	;	;	PUNCT
eurjchem-2214	473	11	gildea	gildea	PROPN
eurjchem-2214	473	12	,	,	PUNCT
eurjchem-2214	473	13	r.	r.	PROPN
eurjchem-2214	473	14	j.	j.	PROPN
eurjchem-2214	473	15	;	;	PUNCT
eurjchem-2214	473	16	howard	howard	PROPN
eurjchem-2214	473	17	,	,	PUNCT
eurjchem-2214	473	18	j.	j.	PROPN
eurjchem-2214	473	19	a.	a.	PROPN
eurjchem-2214	473	20	k.	k.	PROPN
eurjchem-2214	473	21	;	;	PUNCT
eurjchem-2214	473	22	puschmann	puschmann	PROPN
eurjchem-2214	473	23	,	,	PUNCT
eurjchem-2214	473	24	h.	h.	PROPN
eurjchem-2214	473	25	olex2	olex2	PROPN
eurjchem-2214	473	26	:	:	PUNCT
eurjchem-2214	473	27	a	a	DET
eurjchem-2214	473	28	complete	complete	ADJ
eurjchem-2214	473	29	structure	structure	NOUN
eurjchem-2214	473	30	solution	solution	NOUN
eurjchem-2214	473	31	,	,	PUNCT
eurjchem-2214	473	32	refinement	refinement	NOUN
eurjchem-2214	473	33	and	and	CCONJ
eurjchem-2214	473	34	analysis	analysis	NOUN
eurjchem-2214	473	35	program	program	NOUN
eurjchem-2214	473	36	.	.	PUNCT
eurjchem-2214	474	1	j.	j.	PROPN
eurjchem-2214	474	2	appl	appl	PROPN
eurjchem-2214	474	3	.	.	PROPN
eurjchem-2214	474	4	crystallogr	crystallogr	PROPN
eurjchem-2214	474	5	.	.	PUNCT
eurjchem-2214	475	1	2009	2009	NUM
eurjchem-2214	475	2	,	,	PUNCT
eurjchem-2214	475	3	42	42	NUM
eurjchem-2214	475	4	,	,	PUNCT
eurjchem-2214	475	5	339–341	339–341	NUM
eurjchem-2214	475	6	.	.	PUNCT
eurjchem-2214	476	1	[	[	X
eurjchem-2214	476	2	34	34	NUM
eurjchem-2214	476	3	]	]	PUNCT
eurjchem-2214	476	4	.	.	PUNCT
eurjchem-2214	476	5	faruggia	faruggia	PROPN
eurjchem-2214	476	6	,	,	PUNCT
eurjchem-2214	476	7	l.	l.	PROPN
eurjchem-2214	476	8	j.	j.	PROPN
eurjchem-2214	476	9	ortep-3	ortep-3	PROPN
eurjchem-2214	476	10	for	for	ADP
eurjchem-2214	476	11	windows	window	NOUN
eurjchem-2214	476	12	,	,	PUNCT
eurjchem-2214	476	13	university	university	NOUN
eurjchem-2214	476	14	of	of	ADP
eurjchem-2214	476	15	glassgow	glassgow	PROPN
eurjchem-2214	476	16	,	,	PUNCT
eurjchem-2214	476	17	scotland	scotland	PROPN
eurjchem-2214	476	18	,	,	PUNCT
eurjchem-2214	476	19	u	u	PROPN
eurjchem-2214	476	20	k	k	PROPN
eurjchem-2214	476	21	,	,	PUNCT
eurjchem-2214	476	22	1999	1999	NUM
eurjchem-2214	476	23	.	.	PUNCT
eurjchem-2214	477	1	[	[	X
eurjchem-2214	477	2	35	35	NUM
eurjchem-2214	477	3	]	]	SYM
eurjchem-2214	477	4	.	.	PUNCT
eurjchem-2214	477	5	macrae	macrae	PROPN
eurjchem-2214	477	6	,	,	PUNCT
eurjchem-2214	477	7	c.	c.	PROPN
eurjchem-2214	477	8	f.	f.	PROPN
eurjchem-2214	477	9	;	;	PUNCT
eurjchem-2214	477	10	sovago	sovago	PROPN
eurjchem-2214	477	11	,	,	PUNCT
eurjchem-2214	477	12	i.	i.	NOUN
eurjchem-2214	477	13	;	;	PUNCT
eurjchem-2214	477	14	cottrell	cottrell	PROPN
eurjchem-2214	477	15	,	,	PUNCT
eurjchem-2214	477	16	s.	s.	PROPN
eurjchem-2214	477	17	j.	j.	PROPN
eurjchem-2214	477	18	;	;	PUNCT
eurjchem-2214	477	19	galek	galek	PROPN
eurjchem-2214	477	20	,	,	PUNCT
eurjchem-2214	477	21	p.	p.	PROPN
eurjchem-2214	477	22	t.	t.	PROPN
eurjchem-2214	477	23	a.	a.	PROPN
eurjchem-2214	477	24	;	;	PUNCT
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eurjchem-2214	477	26	,	,	PUNCT
eurjchem-2214	477	27	p.	p.	NOUN
eurjchem-2214	477	28	;	;	PUNCT
eurjchem-2214	477	29	pidcock	pidcock	PROPN
eurjchem-2214	477	30	,	,	PUNCT
eurjchem-2214	477	31	e.	e.	PROPN
eurjchem-2214	477	32	;	;	PUNCT
eurjchem-2214	477	33	platings	plating	NOUN
eurjchem-2214	477	34	,	,	PUNCT
eurjchem-2214	477	35	m.	m.	NOUN
eurjchem-2214	477	36	;	;	PUNCT
eurjchem-2214	477	37	shields	shield	NOUN
eurjchem-2214	477	38	,	,	PUNCT
eurjchem-2214	477	39	g.	g.	PROPN
eurjchem-2214	477	40	p.	p.	PROPN
eurjchem-2214	477	41	;	;	PUNCT
eurjchem-2214	477	42	stevens	stevens	PROPN
eurjchem-2214	477	43	,	,	PUNCT
eurjchem-2214	477	44	j.	j.	PROPN
eurjchem-2214	477	45	s.	s.	PROPN
eurjchem-2214	477	46	;	;	PUNCT
eurjchem-2214	477	47	towler	towler	NOUN
eurjchem-2214	477	48	,	,	PUNCT
eurjchem-2214	477	49	m.	m.	NOUN
eurjchem-2214	477	50	;	;	PUNCT
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eurjchem-2214	477	52	,	,	PUNCT
eurjchem-2214	477	53	p.	p.	NOUN
eurjchem-2214	477	54	a.	a.	NOUN
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eurjchem-2214	477	56	4.0	4.0	NUM
eurjchem-2214	477	57	:	:	PUNCT
eurjchem-2214	477	58	from	from	ADP
eurjchem-2214	477	59	visualization	visualization	NOUN
eurjchem-2214	477	60	to	to	ADP
eurjchem-2214	477	61	analysis	analysis	NOUN
eurjchem-2214	477	62	,	,	PUNCT
eurjchem-2214	477	63	design	design	NOUN
eurjchem-2214	477	64	and	and	CCONJ
eurjchem-2214	477	65	prediction	prediction	NOUN
eurjchem-2214	477	66	.	.	PUNCT
eurjchem-2214	478	1	j.	j.	PROPN
eurjchem-2214	478	2	appl	appl	PROPN
eurjchem-2214	478	3	.	.	PROPN
eurjchem-2214	478	4	crystallogr	crystallogr	PROPN
eurjchem-2214	478	5	.	.	PUNCT
eurjchem-2214	479	1	2020	2020	NUM
eurjchem-2214	479	2	,	,	PUNCT
eurjchem-2214	479	3	53	53	NUM
eurjchem-2214	479	4	,	,	PUNCT
eurjchem-2214	479	5	226–235	226–235	NUM
eurjchem-2214	479	6	.	.	PUNCT
eurjchem-2214	480	1	[	[	X
eurjchem-2214	480	2	36	36	NUM
eurjchem-2214	480	3	]	]	PUNCT
eurjchem-2214	480	4	.	.	PUNCT
eurjchem-2214	480	5	sharma	sharma	PROPN
eurjchem-2214	480	6	,	,	PUNCT
eurjchem-2214	480	7	m.	m.	NOUN
eurjchem-2214	480	8	;	;	PUNCT
eurjchem-2214	480	9	kumar	kumar	PROPN
eurjchem-2214	480	10	,	,	PUNCT
eurjchem-2214	480	11	l.	l.	PROPN
eurjchem-2214	480	12	;	;	PUNCT
eurjchem-2214	480	13	jain	jain	PROPN
eurjchem-2214	480	14	,	,	PUNCT
eurjchem-2214	480	15	a.	a.	NOUN
eurjchem-2214	480	16	;	;	PUNCT
eurjchem-2214	480	17	verma	verma	PROPN
eurjchem-2214	480	18	,	,	PUNCT
eurjchem-2214	480	19	v.	v.	PROPN
eurjchem-2214	480	20	;	;	PUNCT
eurjchem-2214	480	21	sharma	sharma	PROPN
eurjchem-2214	480	22	,	,	PUNCT
eurjchem-2214	480	23	v.	v.	PROPN
eurjchem-2214	480	24	;	;	PUNCT
eurjchem-2214	480	25	kushwaha	kushwaha	PROPN
eurjchem-2214	480	26	,	,	PUNCT
eurjchem-2214	480	27	b.	b.	PROPN
eurjchem-2214	480	28	;	;	PUNCT
eurjchem-2214	480	29	lal	lal	PROPN
eurjchem-2214	480	30	,	,	PUNCT
eurjchem-2214	480	31	n.	n.	PROPN
eurjchem-2214	480	32	;	;	PUNCT
eurjchem-2214	480	33	kumar	kumar	PROPN
eurjchem-2214	480	34	,	,	PUNCT
eurjchem-2214	480	35	l.	l.	PROPN
eurjchem-2214	480	36	;	;	PUNCT
eurjchem-2214	480	37	rawat	rawat	PROPN
eurjchem-2214	480	38	,	,	PUNCT
eurjchem-2214	480	39	t.	t.	PROPN
eurjchem-2214	480	40	;	;	PUNCT
eurjchem-2214	480	41	dwivedi	dwivedi	PROPN
eurjchem-2214	480	42	,	,	PUNCT
eurjchem-2214	480	43	a.	a.	PROPN
eurjchem-2214	480	44	k.	k.	PROPN
eurjchem-2214	480	45	;	;	PUNCT
eurjchem-2214	480	46	maikhuri	maikhuri	PROPN
eurjchem-2214	480	47	,	,	PUNCT
eurjchem-2214	480	48	j.	j.	PROPN
eurjchem-2214	480	49	p.	p.	PROPN
eurjchem-2214	480	50	;	;	PUNCT
eurjchem-2214	480	51	sharma	sharma	PROPN
eurjchem-2214	480	52	,	,	PUNCT
eurjchem-2214	480	53	v.	v.	PROPN
eurjchem-2214	480	54	l.	l.	PROPN
eurjchem-2214	480	55	;	;	PUNCT
eurjchem-2214	480	56	gupta	gupta	PROPN
eurjchem-2214	480	57	,	,	PUNCT
eurjchem-2214	480	58	g.	g.	PROPN
eurjchem-2214	480	59	designed	design	VERB
eurjchem-2214	480	60	chemical	chemical	NOUN
eurjchem-2214	480	61	intervention	intervention	NOUN
eurjchem-2214	480	62	with	with	ADP
eurjchem-2214	480	63	thiols	thiol	NOUN
eurjchem-2214	480	64	for	for	ADP
eurjchem-2214	480	65	prophylactic	prophylactic	ADJ
eurjchem-2214	480	66	contraception	contraception	NOUN
eurjchem-2214	480	67	.	.	PUNCT
eurjchem-2214	481	1	plos	plos	PROPN
eurjchem-2214	481	2	one	one	NUM
eurjchem-2214	481	3	2013	2013	NUM
eurjchem-2214	481	4	,	,	PUNCT
eurjchem-2214	481	5	8	8	NUM
eurjchem-2214	481	6	,	,	PUNCT
eurjchem-2214	481	7	e67365	e67365	PROPN
eurjchem-2214	481	8	.	.	PUNCT
eurjchem-2214	482	1	[	[	X
eurjchem-2214	482	2	37	37	NUM
eurjchem-2214	482	3	]	]	PUNCT
eurjchem-2214	482	4	.	.	PUNCT
eurjchem-2214	483	1	engelhardt	engelhardt	PROPN
eurjchem-2214	483	2	,	,	PUNCT
eurjchem-2214	483	3	l.	l.	PROPN
eurjchem-2214	483	4	m.	m.	PROPN
eurjchem-2214	483	5	;	;	PUNCT
eurjchem-2214	483	6	patrick	patrick	PROPN
eurjchem-2214	483	7	,	,	PUNCT
eurjchem-2214	483	8	j.	j.	PROPN
eurjchem-2214	483	9	m.	m.	PROPN
eurjchem-2214	483	10	;	;	PUNCT
eurjchem-2214	483	11	white	white	ADJ
eurjchem-2214	483	12	,	,	PUNCT
eurjchem-2214	483	13	a.	a.	PROPN
eurjchem-2214	483	14	h.	h.	PROPN
eurjchem-2214	483	15	crystal	crystal	PROPN
eurjchem-2214	483	16	structures	structure	NOUN
eurjchem-2214	483	17	of	of	ADP
eurjchem-2214	483	18	bis(pyrrolidinedithiocarbamato)-nickel(ii	bis(pyrrolidinedithiocarbamato)-nickel(ii	PROPN
eurjchem-2214	483	19	)	)	PUNCT
eurjchem-2214	483	20	and	and	CCONJ
eurjchem-2214	483	21	-copper(ii	-copper(ii	PROPN
eurjchem-2214	483	22	)	)	PUNCT
eurjchem-2214	483	23	(	(	PUNCT
eurjchem-2214	483	24	redeterminations	redetermination	NOUN
eurjchem-2214	483	25	)	)	PUNCT
eurjchem-2214	483	26	.	.	PUNCT
eurjchem-2214	484	1	aust	aust	PROPN
eurjchem-2214	484	2	.	.	PUNCT
eurjchem-2214	485	1	j.	j.	PROPN
eurjchem-2214	485	2	chem	chem	PROPN
eurjchem-2214	485	3	.	.	PUNCT
eurjchem-2214	486	1	1985	1985	NUM
eurjchem-2214	486	2	,	,	PUNCT
eurjchem-2214	486	3	38	38	NUM
eurjchem-2214	486	4	,	,	PUNCT
eurjchem-2214	486	5	1413–1416	1413–1416	NUM
eurjchem-2214	486	6	.	.	PUNCT
eurjchem-2214	487	1	[	[	X
eurjchem-2214	487	2	38	38	NUM
eurjchem-2214	487	3	]	]	PUNCT
eurjchem-2214	487	4	.	.	PUNCT
eurjchem-2214	488	1	batsanov	batsanov	NOUN
eurjchem-2214	488	2	,	,	PUNCT
eurjchem-2214	488	3	a.	a.	PROPN
eurjchem-2214	488	4	s.	s.	PROPN
eurjchem-2214	488	5	;	;	PUNCT
eurjchem-2214	488	6	howard	howard	PROPN
eurjchem-2214	488	7	,	,	PUNCT
eurjchem-2214	488	8	j.	j.	PROPN
eurjchem-2214	488	9	a.	a.	PROPN
eurjchem-2214	488	10	k.	k.	PROPN
eurjchem-2214	489	1	trans	trans	PROPN
eurjchem-2214	489	2	-	-	PROPN
eurjchem-2214	489	3	dichlorobis(triphenyl	dichlorobis(triphenyl	ADJ
eurjchem-2214	489	4	phosphine)nickel(ii	phosphine)nickel(ii	NOUN
eurjchem-2214	489	5	)	)	PUNCT
eurjchem-2214	489	6	bis(dichloromethane	bis(dichloromethane	NOUN
eurjchem-2214	489	7	)	)	PUNCT
eurjchem-2214	489	8	solvate	solvate	NOUN
eurjchem-2214	489	9	:	:	PUNCT
eurjchem-2214	489	10	redetermination	redetermination	NOUN
eurjchem-2214	489	11	at	at	ADP
eurjchem-2214	489	12	120	120	NUM
eurjchem-2214	489	13	k.	k.	PROPN
eurjchem-2214	489	14	acta	acta	PROPN
eurjchem-2214	489	15	crystallogr	crystallogr	PROPN
eurjchem-2214	489	16	.	.	PUNCT
eurjchem-2214	490	1	sect	sect	NOUN
eurjchem-2214	490	2	.	.	PUNCT
eurjchem-2214	491	1	e	e	NOUN
eurjchem-2214	491	2	struct	struct	NOUN
eurjchem-2214	491	3	.	.	PUNCT
eurjchem-2214	492	1	rep	rep	PROPN
eurjchem-2214	492	2	.	.	PROPN
eurjchem-2214	492	3	online	online	PROPN
eurjchem-2214	492	4	2001	2001	NUM
eurjchem-2214	492	5	,	,	PUNCT
eurjchem-2214	492	6	57	57	NUM
eurjchem-2214	492	7	,	,	PUNCT
eurjchem-2214	492	8	m308	m308	PROPN
eurjchem-2214	492	9	–	–	PUNCT
eurjchem-2214	492	10	m309	m309	PROPN
eurjchem-2214	492	11	.	.	PUNCT
eurjchem-2214	493	1	[	[	X
eurjchem-2214	493	2	39	39	NUM
eurjchem-2214	493	3	]	]	PUNCT
eurjchem-2214	493	4	.	.	PUNCT
eurjchem-2214	494	1	brammer	brammer	PROPN
eurjchem-2214	494	2	,	,	PUNCT
eurjchem-2214	494	3	l.	l.	PROPN
eurjchem-2214	494	4	;	;	PUNCT
eurjchem-2214	494	5	stevens	stevens	PROPN
eurjchem-2214	494	6	,	,	PUNCT
eurjchem-2214	494	7	e.	e.	PROPN
eurjchem-2214	494	8	d.	d.	PROPN
eurjchem-2214	494	9	structure	structure	NOUN
eurjchem-2214	494	10	of	of	ADP
eurjchem-2214	494	11	dichlorobis(triphenyl	dichlorobis(triphenyl	PROPN
eurjchem-2214	494	12	phosphine)nickel(ii	phosphine)nickel(ii	PROPN
eurjchem-2214	494	13	)	)	PUNCT
eurjchem-2214	494	14	.	.	PUNCT
eurjchem-2214	495	1	acta	acta	PROPN
eurjchem-2214	495	2	crystallogr	crystallogr	PROPN
eurjchem-2214	495	3	.	.	PUNCT
eurjchem-2214	496	1	c	c	PROPN
eurjchem-2214	496	2	1989	1989	NUM
eurjchem-2214	496	3	,	,	PUNCT
eurjchem-2214	496	4	45	45	NUM
eurjchem-2214	496	5	,	,	PUNCT
eurjchem-2214	496	6	400–403	400–403	NUM
eurjchem-2214	496	7	.	.	PUNCT
eurjchem-2214	497	1	[	[	X
eurjchem-2214	497	2	40	40	NUM
eurjchem-2214	497	3	]	]	PUNCT
eurjchem-2214	497	4	.	.	PUNCT
eurjchem-2214	498	1	cao	cao	PROPN
eurjchem-2214	498	2	,	,	PUNCT
eurjchem-2214	498	3	r.	r.	PROPN
eurjchem-2214	498	4	;	;	PUNCT
eurjchem-2214	498	5	li	li	PROPN
eurjchem-2214	498	6	,	,	PUNCT
eurjchem-2214	498	7	x.	x.	PROPN
eurjchem-2214	498	8	;	;	PUNCT
eurjchem-2214	498	9	sun	sun	PROPN
eurjchem-2214	498	10	,	,	PUNCT
eurjchem-2214	498	11	h.	h.	NOUN
eurjchem-2214	498	12	synthesis	synthesis	NOUN
eurjchem-2214	498	13	and	and	CCONJ
eurjchem-2214	498	14	properties	property	NOUN
eurjchem-2214	498	15	of	of	ADP
eurjchem-2214	498	16	nickel(ii	nickel(ii	NOUN
eurjchem-2214	498	17	)	)	PUNCT
eurjchem-2214	498	18	complexes	complex	NOUN
eurjchem-2214	498	19	containing	contain	VERB
eurjchem-2214	498	20	trimethylphosphine	trimethylphosphine	NOUN
eurjchem-2214	498	21	and	and	CCONJ
eurjchem-2214	498	22	thiophenolato	thiophenolato	NOUN
eurjchem-2214	498	23	-	-	PUNCT
eurjchem-2214	498	24	ligands	ligand	NOUN
eurjchem-2214	498	25	.	.	PUNCT
eurjchem-2214	499	1	z.	z.	PROPN
eurjchem-2214	499	2	anorg	anorg	PROPN
eurjchem-2214	499	3	.	.	PUNCT
eurjchem-2214	500	1	allg	allg	PROPN
eurjchem-2214	500	2	.	.	PUNCT
eurjchem-2214	501	1	chem	chem	NOUN
eurjchem-2214	501	2	.	.	PUNCT
eurjchem-2214	502	1	2007	2007	NUM
eurjchem-2214	502	2	,	,	PUNCT
eurjchem-2214	502	3	633	633	NUM
eurjchem-2214	502	4	,	,	PUNCT
eurjchem-2214	502	5	2305–2309	2305–2309	NUM
eurjchem-2214	502	6	.	.	PUNCT
eurjchem-2214	503	1	[	[	X
eurjchem-2214	503	2	41	41	NUM
eurjchem-2214	503	3	]	]	PUNCT
eurjchem-2214	503	4	.	.	PUNCT
eurjchem-2214	504	1	ramalingam	ramalingam	PROPN
eurjchem-2214	504	2	,	,	PUNCT
eurjchem-2214	504	3	k.	k.	PROPN
eurjchem-2214	504	4	;	;	PUNCT
eurjchem-2214	504	5	aravamudan	aravamudan	PROPN
eurjchem-2214	504	6	,	,	PUNCT
eurjchem-2214	504	7	g.	g.	PROPN
eurjchem-2214	504	8	;	;	PUNCT
eurjchem-2214	504	9	seshasayee	seshasayee	PROPN
eurjchem-2214	504	10	,	,	PUNCT
eurjchem-2214	504	11	m.	m.	NOUN
eurjchem-2214	504	12	;	;	PUNCT
eurjchem-2214	504	13	verghese	verghese	PROPN
eurjchem-2214	504	14	,	,	PUNCT
eurjchem-2214	504	15	b.	b.	PROPN
eurjchem-2214	504	16	structure	structure	NOUN
eurjchem-2214	504	17	of	of	ADP
eurjchem-2214	504	18	bis(monothiobenzoato	bis(monothiobenzoato	NOUN
eurjchem-2214	504	19	-	-	PUNCT
eurjchem-2214	504	20	s)[ethylenebis(diphenylphos	s)[ethylenebis(diphenylphos	ADJ
eurjchem-2214	504	21	phino	phino	NOUN
eurjchem-2214	504	22	)	)	PUNCT
eurjchem-2214	504	23	]	]	PUNCT
eurjchem-2214	505	1	nickel(ii	nickel(ii	NOUN
eurjchem-2214	505	2	)	)	PUNCT
eurjchem-2214	505	3	.	.	PUNCT
eurjchem-2214	506	1	acta	acta	PROPN
eurjchem-2214	506	2	crystallogr	crystallogr	PROPN
eurjchem-2214	506	3	.	.	PUNCT
eurjchem-2214	507	1	c	c	NOUN
eurjchem-2214	507	2	1987	1987	NUM
eurjchem-2214	507	3	,	,	PUNCT
eurjchem-2214	507	4	43	43	NUM
eurjchem-2214	507	5	,	,	PUNCT
eurjchem-2214	507	6	471–473	471–473	NUM
eurjchem-2214	507	7	.	.	PUNCT
eurjchem-2214	508	1	[	[	X
eurjchem-2214	508	2	42	42	NUM
eurjchem-2214	508	3	]	]	PUNCT
eurjchem-2214	508	4	.	.	PUNCT
eurjchem-2214	508	5	milburn	milburn	PROPN
eurjchem-2214	508	6	,	,	PUNCT
eurjchem-2214	508	7	g.	g.	PROPN
eurjchem-2214	508	8	h.	h.	PROPN
eurjchem-2214	508	9	w.	w.	PROPN
eurjchem-2214	508	10	;	;	PUNCT
eurjchem-2214	508	11	truter	truter	ADV
eurjchem-2214	508	12	,	,	PUNCT
eurjchem-2214	508	13	m.	m.	PROPN
eurjchem-2214	508	14	r.	r.	PROPN
eurjchem-2214	509	1	the	the	DET
eurjchem-2214	509	2	crystal	crystal	NOUN
eurjchem-2214	509	3	structures	structure	NOUN
eurjchem-2214	509	4	of	of	ADP
eurjchem-2214	509	5	cisand	cisand	NOUN
eurjchem-2214	509	6	transdichlorodiammineplatinum(ii	transdichlorodiammineplatinum(ii	NOUN
eurjchem-2214	509	7	)	)	PUNCT
eurjchem-2214	509	8	.	.	PUNCT
eurjchem-2214	510	1	j.	j.	PROPN
eurjchem-2214	510	2	chem	chem	PROPN
eurjchem-2214	510	3	.	.	PUNCT
eurjchem-2214	511	1	soc	soc	PROPN
eurjchem-2214	511	2	.	.	PUNCT
eurjchem-2214	512	1	1966	1966	NUM
eurjchem-2214	512	2	,	,	PUNCT
eurjchem-2214	512	3	1609–1616	1609–1616	NUM
eurjchem-2214	512	4	.	.	PUNCT
eurjchem-2214	513	1	[	[	X
eurjchem-2214	513	2	43	43	NUM
eurjchem-2214	513	3	]	]	PUNCT
eurjchem-2214	513	4	.	.	PUNCT
eurjchem-2214	514	1	brown	brown	PROPN
eurjchem-2214	514	2	,	,	PUNCT
eurjchem-2214	514	3	i.	i.	PROPN
eurjchem-2214	514	4	d.	d.	PROPN
eurjchem-2214	515	1	the	the	DET
eurjchem-2214	515	2	bond	bond	NOUN
eurjchem-2214	515	3	valence	valence	NOUN
eurjchem-2214	515	4	model	model	NOUN
eurjchem-2214	515	5	as	as	ADP
eurjchem-2214	515	6	a	a	DET
eurjchem-2214	515	7	tool	tool	NOUN
eurjchem-2214	515	8	for	for	ADP
eurjchem-2214	515	9	teaching	teach	VERB
eurjchem-2214	515	10	inorganic	inorganic	ADJ
eurjchem-2214	515	11	chemistry	chemistry	NOUN
eurjchem-2214	515	12	:	:	PUNCT
eurjchem-2214	515	13	the	the	DET
eurjchem-2214	515	14	ionic	ionic	ADJ
eurjchem-2214	515	15	model	model	NOUN
eurjchem-2214	515	16	revisited	revisit	VERB
eurjchem-2214	515	17	.	.	PUNCT
eurjchem-2214	516	1	j.	j.	PROPN
eurjchem-2214	516	2	chem	chem	PROPN
eurjchem-2214	516	3	.	.	PUNCT
eurjchem-2214	517	1	educ	educ	PROPN
eurjchem-2214	517	2	.	.	PUNCT
eurjchem-2214	518	1	2000	2000	NUM
eurjchem-2214	518	2	,	,	PUNCT
eurjchem-2214	518	3	77	77	NUM
eurjchem-2214	518	4	,	,	PUNCT
eurjchem-2214	518	5	1070	1070	NUM
eurjchem-2214	518	6	.	.	PUNCT
eurjchem-2214	519	1	[	[	X
eurjchem-2214	519	2	44	44	NUM
eurjchem-2214	519	3	]	]	PUNCT
eurjchem-2214	519	4	.	.	PUNCT
eurjchem-2214	520	1	brese	brese	PROPN
eurjchem-2214	520	2	,	,	PUNCT
eurjchem-2214	520	3	n.	n.	PROPN
eurjchem-2214	520	4	e.	e.	PROPN
eurjchem-2214	520	5	;	;	PUNCT
eurjchem-2214	520	6	o’keeffe	o’keeffe	PROPN
eurjchem-2214	520	7	,	,	PUNCT
eurjchem-2214	520	8	m.	m.	NOUN
eurjchem-2214	520	9	bond	bond	NOUN
eurjchem-2214	520	10	-	-	PUNCT
eurjchem-2214	520	11	valence	valence	NOUN
eurjchem-2214	520	12	parameters	parameter	NOUN
eurjchem-2214	520	13	for	for	ADP
eurjchem-2214	520	14	solids	solid	NOUN
eurjchem-2214	520	15	.	.	PUNCT
eurjchem-2214	521	1	acta	acta	PROPN
eurjchem-2214	521	2	crystallogr	crystallogr	PROPN
eurjchem-2214	521	3	.	.	PUNCT
eurjchem-2214	522	1	b	b	NOUN
eurjchem-2214	522	2	1991	1991	NUM
eurjchem-2214	522	3	,	,	PUNCT
eurjchem-2214	522	4	47	47	NUM
eurjchem-2214	522	5	,	,	PUNCT
eurjchem-2214	522	6	192–197	192–197	NUM
eurjchem-2214	522	7	.	.	PUNCT
eurjchem-2214	523	1	[	[	X
eurjchem-2214	523	2	45	45	NUM
eurjchem-2214	523	3	]	]	PUNCT
eurjchem-2214	523	4	.	.	PUNCT
eurjchem-2214	524	1	o’keefe	o’keefe	NOUN
eurjchem-2214	524	2	,	,	PUNCT
eurjchem-2214	524	3	m.	m.	NOUN
eurjchem-2214	524	4	;	;	PUNCT
eurjchem-2214	524	5	brese	brese	PROPN
eurjchem-2214	524	6	,	,	PUNCT
eurjchem-2214	524	7	n.	n.	PROPN
eurjchem-2214	524	8	e.	e.	PROPN
eurjchem-2214	524	9	atom	atom	PROPN
eurjchem-2214	524	10	sizes	size	NOUN
eurjchem-2214	524	11	and	and	CCONJ
eurjchem-2214	524	12	bond	bond	NOUN
eurjchem-2214	524	13	lengths	length	NOUN
eurjchem-2214	524	14	in	in	ADP
eurjchem-2214	524	15	molecules	molecule	NOUN
eurjchem-2214	524	16	and	and	CCONJ
eurjchem-2214	524	17	crystals	crystal	NOUN
eurjchem-2214	524	18	.	.	PUNCT
eurjchem-2214	525	1	j.	j.	PROPN
eurjchem-2214	525	2	am	am	PROPN
eurjchem-2214	525	3	.	.	PUNCT
eurjchem-2214	526	1	chem	chem	NOUN
eurjchem-2214	526	2	.	.	PUNCT
eurjchem-2214	527	1	soc	soc	PROPN
eurjchem-2214	527	2	.	.	PUNCT
eurjchem-2214	528	1	1991	1991	NUM
eurjchem-2214	528	2	,	,	PUNCT
eurjchem-2214	528	3	113	113	NUM
eurjchem-2214	528	4	,	,	PUNCT
eurjchem-2214	528	5	3226–3229	3226–3229	NUM
eurjchem-2214	528	6	.	.	PUNCT
eurjchem-2214	529	1	[	[	X
eurjchem-2214	529	2	46	46	NUM
eurjchem-2214	529	3	]	]	PUNCT
eurjchem-2214	529	4	.	.	PUNCT
eurjchem-2214	530	1	liu	liu	PROPN
eurjchem-2214	530	2	,	,	PUNCT
eurjchem-2214	530	3	w.	w.	PROPN
eurjchem-2214	530	4	;	;	PUNCT
eurjchem-2214	530	5	thorp	thorp	PROPN
eurjchem-2214	530	6	,	,	PUNCT
eurjchem-2214	530	7	h.	h.	PROPN
eurjchem-2214	530	8	h.	h.	PROPN
eurjchem-2214	530	9	bond	bond	NOUN
eurjchem-2214	530	10	valence	valence	NOUN
eurjchem-2214	530	11	sum	sum	NOUN
eurjchem-2214	530	12	analysis	analysis	NOUN
eurjchem-2214	530	13	of	of	ADP
eurjchem-2214	530	14	metal	metal	NOUN
eurjchem-2214	530	15	-	-	PUNCT
eurjchem-2214	530	16	ligand	ligand	NOUN
eurjchem-2214	530	17	bond	bond	NOUN
eurjchem-2214	530	18	lengths	length	NOUN
eurjchem-2214	530	19	in	in	ADP
eurjchem-2214	530	20	metalloenzymes	metalloenzyme	NOUN
eurjchem-2214	530	21	and	and	CCONJ
eurjchem-2214	530	22	model	model	NOUN
eurjchem-2214	530	23	complexes	complex	NOUN
eurjchem-2214	530	24	.	.	PUNCT
eurjchem-2214	531	1	2	2	X
eurjchem-2214	531	2	.	.	NUM
eurjchem-2214	531	3	refined	refined	ADJ
eurjchem-2214	531	4	distances	distance	NOUN
eurjchem-2214	531	5	and	and	CCONJ
eurjchem-2214	531	6	other	other	ADJ
eurjchem-2214	531	7	enzymes	enzyme	NOUN
eurjchem-2214	531	8	.	.	PUNCT
eurjchem-2214	532	1	inorg	inorg	PROPN
eurjchem-2214	532	2	.	.	PUNCT
eurjchem-2214	533	1	chem	chem	PROPN
eurjchem-2214	533	2	.	.	PUNCT
eurjchem-2214	534	1	1993	1993	NUM
eurjchem-2214	534	2	,	,	PUNCT
eurjchem-2214	534	3	32	32	NUM
eurjchem-2214	534	4	,	,	PUNCT
eurjchem-2214	534	5	4102–4105	4102–4105	NUM
eurjchem-2214	534	6	.	.	PUNCT
eurjchem-2214	535	1	[	[	X
eurjchem-2214	535	2	47	47	NUM
eurjchem-2214	535	3	]	]	PUNCT
eurjchem-2214	535	4	.	.	PUNCT
eurjchem-2214	536	1	ok	ok	PROPN
eurjchem-2214	536	2	,	,	PUNCT
eurjchem-2214	536	3	k.	k.	PROPN
eurjchem-2214	536	4	m.	m.	PROPN
eurjchem-2214	536	5	;	;	PUNCT
eurjchem-2214	536	6	halasyamani	halasyamani	PROPN
eurjchem-2214	536	7	,	,	PUNCT
eurjchem-2214	536	8	p.	p.	PROPN
eurjchem-2214	536	9	s.	s.	PROPN
eurjchem-2214	536	10	;	;	PUNCT
eurjchem-2214	537	1	casanova	casanova	X
eurjchem-2214	537	2	,	,	PUNCT
eurjchem-2214	537	3	d.	d.	PROPN
eurjchem-2214	537	4	;	;	PUNCT
eurjchem-2214	537	5	llunell	llunell	PROPN
eurjchem-2214	537	6	,	,	PUNCT
eurjchem-2214	537	7	m.	m.	NOUN
eurjchem-2214	537	8	;	;	PUNCT
eurjchem-2214	537	9	alemany	alemany	NOUN
eurjchem-2214	537	10	,	,	PUNCT
eurjchem-2214	537	11	p.	p.	NOUN
eurjchem-2214	537	12	;	;	PUNCT
eurjchem-2214	537	13	alvarez	alvarez	PROPN
eurjchem-2214	537	14	,	,	PUNCT
eurjchem-2214	537	15	s.	s.	PROPN
eurjchem-2214	537	16	distortions	distortion	NOUN
eurjchem-2214	537	17	in	in	ADP
eurjchem-2214	537	18	octahedrally	octahedrally	ADV
eurjchem-2214	537	19	coordinated	coordinate	VERB
eurjchem-2214	537	20	d0	d0	NOUN
eurjchem-2214	537	21	transition	transition	NOUN
eurjchem-2214	537	22	metal	metal	NOUN
eurjchem-2214	537	23	oxides	oxide	NOUN
eurjchem-2214	537	24	:	:	PUNCT
eurjchem-2214	537	25	a	a	DET
eurjchem-2214	537	26	continuous	continuous	ADJ
eurjchem-2214	537	27	symmetry	symmetry	NOUN
eurjchem-2214	537	28	measures	measure	NOUN
eurjchem-2214	537	29	approach	approach	NOUN
eurjchem-2214	537	30	.	.	PUNCT
eurjchem-2214	538	1	chem	chem	NOUN
eurjchem-2214	538	2	.	.	PUNCT
eurjchem-2214	539	1	mater	mater	NOUN
eurjchem-2214	539	2	.	.	PUNCT
eurjchem-2214	540	1	2006	2006	NUM
eurjchem-2214	540	2	,	,	PUNCT
eurjchem-2214	540	3	18	18	NUM
eurjchem-2214	540	4	,	,	PUNCT
eurjchem-2214	540	5	3176–3183	3176–3183	NUM
eurjchem-2214	540	6	.	.	PUNCT
eurjchem-2214	541	1	[	[	X
eurjchem-2214	541	2	48	48	NUM
eurjchem-2214	541	3	]	]	PUNCT
eurjchem-2214	541	4	.	.	PUNCT
eurjchem-2214	542	1	alvarez	alvarez	PROPN
eurjchem-2214	542	2	,	,	PUNCT
eurjchem-2214	542	3	s.	s.	PROPN
eurjchem-2214	542	4	;	;	PUNCT
eurjchem-2214	542	5	avnir	avnir	PROPN
eurjchem-2214	542	6	,	,	PUNCT
eurjchem-2214	542	7	d.	d.	PROPN
eurjchem-2214	542	8	;	;	PUNCT
eurjchem-2214	542	9	llunell	llunell	PROPN
eurjchem-2214	542	10	,	,	PUNCT
eurjchem-2214	542	11	m.	m.	NOUN
eurjchem-2214	542	12	;	;	PUNCT
eurjchem-2214	542	13	pinsky	pinsky	NOUN
eurjchem-2214	542	14	,	,	PUNCT
eurjchem-2214	542	15	m.	m.	NOUN
eurjchem-2214	542	16	continuous	continuous	ADJ
eurjchem-2214	542	17	symmetry	symmetry	NOUN
eurjchem-2214	542	18	maps	map	NOUN
eurjchem-2214	542	19	and	and	CCONJ
eurjchem-2214	542	20	shape	shape	VERB
eurjchem-2214	542	21	classification	classification	NOUN
eurjchem-2214	542	22	.	.	PUNCT
eurjchem-2214	543	1	the	the	DET
eurjchem-2214	543	2	case	case	NOUN
eurjchem-2214	543	3	of	of	ADP
eurjchem-2214	543	4	six	six	NUM
eurjchem-2214	543	5	-	-	PUNCT
eurjchem-2214	543	6	coordinated	coordinate	VERB
eurjchem-2214	543	7	metal	metal	NOUN
eurjchem-2214	543	8	compounds	compound	VERB
eurjchem-2214	543	9	electronic	electronic	ADJ
eurjchem-2214	543	10	supplementary	supplementary	ADJ
eurjchem-2214	543	11	information	information	NOUN
eurjchem-2214	543	12	(	(	PUNCT
eurjchem-2214	543	13	esi	esi	NOUN
eurjchem-2214	543	14	)	)	PUNCT
eurjchem-2214	543	15	available	available	ADJ
eurjchem-2214	543	16	:	:	PUNCT
eurjchem-2214	543	17	tables	table	NOUN
eurjchem-2214	543	18	of	of	ADP
eurjchem-2214	543	19	csd	csd	NOUN
eurjchem-2214	543	20	refcodes	refcode	NOUN
eurjchem-2214	543	21	,	,	PUNCT
eurjchem-2214	543	22	structural	structural	ADJ
eurjchem-2214	543	23	parameters	parameter	NOUN
eurjchem-2214	543	24	and	and	CCONJ
eurjchem-2214	543	25	symmetry	symmetry	NOUN
eurjchem-2214	543	26	measures	measure	NOUN
eurjchem-2214	543	27	for	for	ADP
eurjchem-2214	543	28	the	the	DET
eurjchem-2214	543	29	studied	study	VERB
eurjchem-2214	543	30	compounds	compound	NOUN
eurjchem-2214	543	31	.	.	PUNCT
eurjchem-2214	544	1	see	see	VERB
eurjchem-2214	544	2	http://www.rsc.org/suppdata/	http://www.rsc.org/suppdata/	PROPN
eurjchem-2214	544	3	nj	nj	PROPN
eurjchem-2214	544	4	/	/	SYM
eurjchem-2214	544	5	b2	b2	PROPN
eurjchem-2214	544	6	/	/	SYM
eurjchem-2214	544	7	b202096n/.	b202096n/.	X
eurjchem-2214	544	8	new	new	ADJ
eurjchem-2214	544	9	j.	j.	PROPN
eurjchem-2214	544	10	chem	chem	PROPN
eurjchem-2214	544	11	.	.	PUNCT
eurjchem-2214	545	1	2002	2002	NUM
eurjchem-2214	545	2	,	,	PUNCT
eurjchem-2214	545	3	26	26	NUM
eurjchem-2214	545	4	,	,	PUNCT
eurjchem-2214	545	5	996–1009	996–1009	NUM
eurjchem-2214	545	6	.	.	PUNCT
eurjchem-2214	546	1	[	[	X
eurjchem-2214	546	2	49	49	NUM
eurjchem-2214	546	3	]	]	PUNCT
eurjchem-2214	546	4	.	.	PUNCT
eurjchem-2214	547	1	zabrodsky	zabrodsky	PROPN
eurjchem-2214	547	2	,	,	PUNCT
eurjchem-2214	547	3	h.	h.	PROPN
eurjchem-2214	547	4	;	;	PUNCT
eurjchem-2214	547	5	peleg	peleg	PROPN
eurjchem-2214	547	6	,	,	PUNCT
eurjchem-2214	547	7	s.	s.	PROPN
eurjchem-2214	547	8	;	;	PUNCT
eurjchem-2214	547	9	avnir	avnir	PROPN
eurjchem-2214	547	10	,	,	PUNCT
eurjchem-2214	547	11	d.	d.	PROPN
eurjchem-2214	547	12	continuous	continuous	ADJ
eurjchem-2214	547	13	symmetry	symmetry	NOUN
eurjchem-2214	547	14	measures	measure	NOUN
eurjchem-2214	547	15	.	.	PUNCT
eurjchem-2214	548	1	j.	j.	PROPN
eurjchem-2214	548	2	am	am	PROPN
eurjchem-2214	548	3	.	.	PUNCT
eurjchem-2214	549	1	chem	chem	NOUN
eurjchem-2214	549	2	.	.	PUNCT
eurjchem-2214	550	1	soc	soc	PROPN
eurjchem-2214	550	2	.	.	PUNCT
eurjchem-2214	551	1	1992	1992	NUM
eurjchem-2214	551	2	,	,	PUNCT
eurjchem-2214	551	3	114	114	NUM
eurjchem-2214	551	4	,	,	PUNCT
eurjchem-2214	551	5	7843–7851	7843–7851	NOUN
eurjchem-2214	551	6	.	.	PUNCT
eurjchem-2214	552	1	copyright	copyright	NOUN
eurjchem-2214	552	2	©	©	ADP
eurjchem-2214	552	3	2022	2022	NUM
eurjchem-2214	552	4	by	by	ADP
eurjchem-2214	552	5	authors	author	NOUN
eurjchem-2214	552	6	.	.	PUNCT
eurjchem-2214	553	1	this	this	DET
eurjchem-2214	553	2	work	work	NOUN
eurjchem-2214	553	3	is	be	AUX
eurjchem-2214	553	4	published	publish	VERB
eurjchem-2214	553	5	and	and	CCONJ
eurjchem-2214	553	6	licensed	license	VERB
eurjchem-2214	553	7	by	by	ADP
eurjchem-2214	553	8	atlanta	atlanta	PROPN
eurjchem-2214	553	9	publishing	publishing	PROPN
eurjchem-2214	553	10	house	house	PROPN
eurjchem-2214	553	11	llc	llc	PROPN
eurjchem-2214	553	12	,	,	PUNCT
eurjchem-2214	553	13	atlanta	atlanta	PROPN
eurjchem-2214	553	14	,	,	PUNCT
eurjchem-2214	553	15	ga	ga	PROPN
eurjchem-2214	553	16	,	,	PUNCT
eurjchem-2214	553	17	usa	usa	PROPN
eurjchem-2214	553	18	.	.	PUNCT
eurjchem-2214	554	1	the	the	DET
eurjchem-2214	554	2	full	full	ADJ
eurjchem-2214	554	3	terms	term	NOUN
eurjchem-2214	554	4	of	of	ADP
eurjchem-2214	554	5	this	this	DET
eurjchem-2214	554	6	license	license	NOUN
eurjchem-2214	554	7	are	be	AUX
eurjchem-2214	554	8	available	available	ADJ
eurjchem-2214	554	9	at	at	ADP
eurjchem-2214	554	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2214	554	11	and	and	CCONJ
eurjchem-2214	554	12	incorporate	incorporate	VERB
eurjchem-2214	554	13	the	the	DET
eurjchem-2214	554	14	creative	creative	ADJ
eurjchem-2214	554	15	commons	common	NOUN
eurjchem-2214	554	16	attribution	attribution	NOUN
eurjchem-2214	554	17	-	-	PUNCT
eurjchem-2214	554	18	non	non	ADJ
eurjchem-2214	554	19	commercial	commercial	NOUN
eurjchem-2214	554	20	(	(	PUNCT
eurjchem-2214	554	21	cc	cc	NOUN
eurjchem-2214	554	22	by	by	ADP
eurjchem-2214	554	23	nc	nc	PROPN
eurjchem-2214	554	24	)	)	PUNCT
eurjchem-2214	554	25	(	(	PUNCT
eurjchem-2214	554	26	international	international	ADJ
eurjchem-2214	554	27	,	,	PUNCT
eurjchem-2214	554	28	v4.0	v4.0	NOUN
eurjchem-2214	554	29	)	)	PUNCT
eurjchem-2214	554	30	license	license	NOUN
eurjchem-2214	554	31	(	(	PUNCT
eurjchem-2214	554	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2214	554	33	)	)	PUNCT
eurjchem-2214	554	34	.	.	PUNCT
eurjchem-2214	555	1	by	by	ADP
eurjchem-2214	555	2	accessing	access	VERB
eurjchem-2214	555	3	the	the	DET
eurjchem-2214	555	4	work	work	NOUN
eurjchem-2214	555	5	,	,	PUNCT
eurjchem-2214	555	6	you	you	PRON
eurjchem-2214	555	7	hereby	hereby	ADV
eurjchem-2214	555	8	accept	accept	VERB
eurjchem-2214	555	9	the	the	DET
eurjchem-2214	555	10	terms	term	NOUN
eurjchem-2214	555	11	.	.	PUNCT
eurjchem-2214	556	1	this	this	PRON
eurjchem-2214	556	2	is	be	AUX
eurjchem-2214	556	3	an	an	DET
eurjchem-2214	556	4	open	open	ADJ
eurjchem-2214	556	5	access	access	NOUN
eurjchem-2214	556	6	article	article	NOUN
eurjchem-2214	556	7	distributed	distribute	VERB
eurjchem-2214	556	8	under	under	ADP
eurjchem-2214	556	9	the	the	DET
eurjchem-2214	556	10	terms	term	NOUN
eurjchem-2214	556	11	and	and	CCONJ
eurjchem-2214	556	12	conditions	condition	NOUN
eurjchem-2214	556	13	of	of	ADP
eurjchem-2214	556	14	the	the	DET
eurjchem-2214	556	15	cc	cc	PROPN
eurjchem-2214	556	16	by	by	ADP
eurjchem-2214	556	17	nc	nc	PROPN
eurjchem-2214	556	18	license	license	PROPN
eurjchem-2214	556	19	,	,	PUNCT
eurjchem-2214	556	20	which	which	PRON
eurjchem-2214	556	21	permits	permit	VERB
eurjchem-2214	556	22	unrestricted	unrestricted	ADJ
eurjchem-2214	556	23	non	non	ADJ
eurjchem-2214	556	24	-	-	ADJ
eurjchem-2214	556	25	commercial	commercial	ADJ
eurjchem-2214	556	26	use	use	NOUN
eurjchem-2214	556	27	,	,	PUNCT
eurjchem-2214	556	28	distribution	distribution	NOUN
eurjchem-2214	556	29	,	,	PUNCT
eurjchem-2214	556	30	and	and	CCONJ
eurjchem-2214	556	31	reproduction	reproduction	NOUN
eurjchem-2214	556	32	in	in	ADP
eurjchem-2214	556	33	any	any	DET
eurjchem-2214	556	34	medium	medium	NOUN
eurjchem-2214	556	35	,	,	PUNCT
eurjchem-2214	556	36	provided	provide	VERB
eurjchem-2214	556	37	the	the	DET
eurjchem-2214	556	38	original	original	ADJ
eurjchem-2214	556	39	work	work	NOUN
eurjchem-2214	556	40	is	be	AUX
eurjchem-2214	556	41	properly	properly	ADV
eurjchem-2214	556	42	cited	cite	VERB
eurjchem-2214	556	43	without	without	ADP
eurjchem-2214	556	44	any	any	DET
eurjchem-2214	556	45	further	further	ADJ
eurjchem-2214	556	46	permission	permission	NOUN
eurjchem-2214	556	47	from	from	ADP
eurjchem-2214	556	48	atlanta	atlanta	PROPN
eurjchem-2214	556	49	publishing	publishing	PROPN
eurjchem-2214	556	50	house	house	PROPN
eurjchem-2214	556	51	llc	llc	PROPN
eurjchem-2214	556	52	(	(	PUNCT
eurjchem-2214	556	53	european	european	PROPN
eurjchem-2214	556	54	journal	journal	PROPN
eurjchem-2214	556	55	of	of	ADP
eurjchem-2214	556	56	chemistry	chemistry	NOUN
eurjchem-2214	556	57	)	)	PUNCT
eurjchem-2214	556	58	.	.	PUNCT
eurjchem-2214	557	1	no	no	DET
eurjchem-2214	557	2	use	use	NOUN
eurjchem-2214	557	3	,	,	PUNCT
eurjchem-2214	557	4	distribution	distribution	NOUN
eurjchem-2214	557	5	or	or	CCONJ
eurjchem-2214	557	6	reproduction	reproduction	NOUN
eurjchem-2214	557	7	is	be	AUX
eurjchem-2214	557	8	permitted	permit	VERB
eurjchem-2214	557	9	which	which	PRON
eurjchem-2214	557	10	does	do	AUX
eurjchem-2214	557	11	not	not	PART
eurjchem-2214	557	12	comply	comply	VERB
eurjchem-2214	557	13	with	with	ADP
eurjchem-2214	557	14	these	these	DET
eurjchem-2214	557	15	terms	term	NOUN
eurjchem-2214	557	16	.	.	PUNCT
eurjchem-2214	558	1	permissions	permission	NOUN
eurjchem-2214	558	2	for	for	ADP
eurjchem-2214	558	3	commercial	commercial	ADJ
eurjchem-2214	558	4	use	use	NOUN
eurjchem-2214	558	5	of	of	ADP
eurjchem-2214	558	6	this	this	DET
eurjchem-2214	558	7	work	work	NOUN
eurjchem-2214	558	8	beyond	beyond	ADP
eurjchem-2214	558	9	the	the	DET
eurjchem-2214	558	10	scope	scope	NOUN
eurjchem-2214	558	11	of	of	ADP
eurjchem-2214	558	12	the	the	DET
eurjchem-2214	558	13	license	license	NOUN
eurjchem-2214	558	14	(	(	PUNCT
eurjchem-2214	558	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2214	558	16	)	)	PUNCT
eurjchem-2214	558	17	are	be	AUX
eurjchem-2214	558	18	administered	administer	VERB
eurjchem-2214	558	19	by	by	ADP
eurjchem-2214	558	20	atlanta	atlanta	PROPN
eurjchem-2214	558	21	publishing	publishing	PROPN
eurjchem-2214	558	22	house	house	PROPN
eurjchem-2214	558	23	llc	llc	PROPN
eurjchem-2214	558	24	(	(	PUNCT
eurjchem-2214	558	25	european	european	PROPN
eurjchem-2214	558	26	journal	journal	PROPN
eurjchem-2214	558	27	of	of	ADP
eurjchem-2214	558	28	chemistry	chemistry	NOUN
eurjchem-2214	558	29	)	)	PUNCT
eurjchem-2214	558	30	.	.	PUNCT
eurjchem-2214	559	1	http://www.rsc.org/suppdata/%20nj/b2/b202096n/	http://www.rsc.org/suppdata/%20nj/b2/b202096n/	ADJ
eurjchem-2214	559	2	http://www.rsc.org/suppdata/%20nj/b2/b202096n/	http://www.rsc.org/suppdata/%20nj/b2/b202096n/	ADJ
eurjchem-2214	559	3	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2214	559	4	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2214	559	5	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2214	559	6	1	1	NUM
eurjchem-2214	559	7	.	.	PUNCT
eurjchem-2214	559	8	introduction	introduction	NOUN
eurjchem-2214	559	9	2	2	NUM
eurjchem-2214	559	10	.	.	PUNCT
eurjchem-2214	559	11	experimental	experimental	ADJ
eurjchem-2214	559	12	2.1	2.1	NUM
eurjchem-2214	559	13	.	.	PUNCT
eurjchem-2214	560	1	materials	material	NOUN
eurjchem-2214	560	2	and	and	CCONJ
eurjchem-2214	560	3	physical	physical	ADJ
eurjchem-2214	560	4	measurements	measurement	NOUN
eurjchem-2214	560	5	2.2	2.2	NUM
eurjchem-2214	560	6	.	.	PUNCT
eurjchem-2214	561	1	x	x	X
eurjchem-2214	561	2	-	-	PUNCT
eurjchem-2214	561	3	ray	ray	NOUN
eurjchem-2214	561	4	crystallography	crystallography	NOUN
eurjchem-2214	561	5	2.3	2.3	NUM
eurjchem-2214	561	6	.	.	PUNCT
eurjchem-2214	562	1	preparations	preparation	NOUN
eurjchem-2214	562	2	,	,	PUNCT
eurjchem-2214	562	3	elemental	elemental	ADJ
eurjchem-2214	562	4	,	,	PUNCT
eurjchem-2214	562	5	spectral	spectral	ADJ
eurjchem-2214	562	6	and	and	CCONJ
eurjchem-2214	562	7	cyclic	cyclic	ADJ
eurjchem-2214	562	8	voltammetric	voltammetric	ADJ
eurjchem-2214	562	9	data	datum	NOUN
eurjchem-2214	562	10	3	3	NUM
eurjchem-2214	562	11	.	.	NOUN
eurjchem-2214	562	12	results	result	NOUN
eurjchem-2214	562	13	and	and	CCONJ
eurjchem-2214	562	14	discussion	discussion	NOUN
eurjchem-2214	562	15	3.1	3.1	NUM
eurjchem-2214	562	16	.	.	PUNCT
eurjchem-2214	563	1	infrared	infrare	VERB
eurjchem-2214	563	2	spectra	spectra	PROPN
eurjchem-2214	563	3	3.2	3.2	NUM
eurjchem-2214	563	4	.	.	PUNCT
eurjchem-2214	564	1	electronic	electronic	ADJ
eurjchem-2214	564	2	spectra	spectra	NOUN
eurjchem-2214	564	3	3.3	3.3	NUM
eurjchem-2214	564	4	.	.	PUNCT
eurjchem-2214	565	1	cyclic	cyclic	ADJ
eurjchem-2214	565	2	voltammetry	voltammetry	NOUN
eurjchem-2214	565	3	3.4	3.4	NUM
eurjchem-2214	565	4	.	.	PUNCT
eurjchem-2214	566	1	nmr	nmr	NOUN
eurjchem-2214	566	2	spectra	spectra	NOUN
eurjchem-2214	566	3	3.5	3.5	NUM
eurjchem-2214	566	4	.	.	PUNCT
eurjchem-2214	567	1	single	single	ADJ
eurjchem-2214	567	2	crystal	crystal	PROPN
eurjchem-2214	567	3	x	x	PROPN
eurjchem-2214	567	4	-	-	NOUN
eurjchem-2214	567	5	ray	ray	NOUN
eurjchem-2214	567	6	structure	structure	NOUN
eurjchem-2214	567	7	analysis	analysis	NOUN
eurjchem-2214	567	8	3.6	3.6	NUM
eurjchem-2214	567	9	.	.	PUNCT
eurjchem-2214	568	1	bond	bond	NOUN
eurjchem-2214	568	2	valence	valence	NOUN
eurjchem-2214	568	3	sum	sum	NOUN
eurjchem-2214	568	4	analysis	analysis	NOUN
eurjchem-2214	568	5	3.7	3.7	NUM
eurjchem-2214	568	6	.	.	PUNCT
eurjchem-2214	569	1	continuous	continuous	ADJ
eurjchem-2214	569	2	shape	shape	NOUN
eurjchem-2214	569	3	measure	measure	NOUN
eurjchem-2214	569	4	analysis	analysis	NOUN
eurjchem-2214	569	5	of	of	ADP
eurjchem-2214	569	6	the	the	DET
eurjchem-2214	569	7	chromophores	chromophore	NOUN
eurjchem-2214	569	8	4	4	NUM
eurjchem-2214	569	9	.	.	PUNCT
eurjchem-2214	570	1	conclusions	conclusion	NOUN
eurjchem-2214	570	2	supporting	support	VERB
eurjchem-2214	570	3	information	information	NOUN
eurjchem-2214	570	4	disclosure	disclosure	NOUN
eurjchem-2214	570	5	statement	statement	NOUN
eurjchem-2214	570	6	credit	credit	NOUN
eurjchem-2214	570	7	authorship	authorship	NOUN
eurjchem-2214	570	8	contribution	contribution	NOUN
eurjchem-2214	570	9	statement	statement	NOUN
eurjchem-2214	570	10	orcid	orcid	NOUN
eurjchem-2214	570	11	and	and	CCONJ
eurjchem-2214	570	12	email	email	NOUN
eurjchem-2214	570	13	references	reference	NOUN
eurjchem-2214	570	14	printfield10	printfield10	PROPN
eurjchem-2214	570	15	:	:	PUNCT
eurjchem-2214	570	16	printfield11	printfield11	NOUN
eurjchem-2214	570	17	:	:	PUNCT
eurjchem-2214	570	18	printfield12	printfield12	PROPN
eurjchem-2214	570	19	:	:	PUNCT
eurjchem-2214	570	20	printfield13	printfield13	VERB
eurjchem-2214	570	21	:	:	PUNCT
eurjchem-2214	570	22	printfield14	printfield14	NOUN
eurjchem-2214	570	23	:	:	PUNCT
eurjchem-2214	570	24	printfield15	printfield15	NOUN
eurjchem-2214	570	25	:	:	PUNCT
eurjchem-2214	570	26	printfield16	printfield16	ADJ
eurjchem-2214	570	27	:	:	PUNCT
eurjchem-2214	570	28	printfield17	printfield17	NOUN
eurjchem-2214	570	29	:	:	PUNCT
eurjchem-2214	570	30	printfield18	printfield18	NOUN
eurjchem-2214	570	31	:	:	PUNCT
eurjchem-2214	570	32	printfield20	printfield20	PROPN
eurjchem-2214	570	33	:	:	PUNCT
eurjchem-2214	570	34	printfield21	printfield21	ADJ
eurjchem-2214	570	35	:	:	PUNCT
eurjchem-2214	570	36	printfield22	printfield22	NOUN
eurjchem-2214	570	37	:	:	PUNCT
eurjchem-2214	570	38	printfield23	printfield23	NOUN
eurjchem-2214	570	39	:	:	PUNCT
eurjchem-2214	570	40	printfield24	printfield24	NOUN
eurjchem-2214	570	41	:	:	PUNCT
eurjchem-2214	570	42	printfield25	printfield25	NOUN
eurjchem-2214	570	43	:	:	PUNCT
eurjchem-2214	570	44	printfield26	printfield26	ADJ
eurjchem-2214	570	45	:	:	PUNCT
eurjchem-2214	570	46	printfield27	printfield27	NOUN
eurjchem-2214	570	47	:	:	PUNCT
eurjchem-2214	570	48	printfield28	printfield28	NOUN
eurjchem-2214	570	49	:	:	PUNCT