id	sid	tid	token	lemma	pos
eurjchem-2279	1	1	crystal	crystal	NOUN
eurjchem-2279	1	2	structure	structure	NOUN
eurjchem-2279	1	3	of	of	ADP
eurjchem-2279	1	4	2,4	2,4	NUM
eurjchem-2279	1	5	-	-	PUNCT
eurjchem-2279	1	6	dinitrophenyl	dinitrophenyl	ADJ
eurjchem-2279	1	7	2,4,6	2,4,6	NUM
eurjchem-2279	1	8	-	-	PUNCT
eurjchem-2279	1	9	trimethylbenzenesulfonate	trimethylbenzenesulfonate	ADJ
eurjchem-2279	1	10	european	european	ADJ
eurjchem-2279	1	11	journal	journal	NOUN
eurjchem-2279	1	12	of	of	ADP
eurjchem-2279	1	13	chemistry	chemistry	NOUN
eurjchem-2279	1	14	13	13	NUM
eurjchem-2279	1	15	(	(	PUNCT
eurjchem-2279	1	16	2	2	NUM
eurjchem-2279	1	17	)	)	PUNCT
eurjchem-2279	1	18	(	(	PUNCT
eurjchem-2279	1	19	2022	2022	NUM
eurjchem-2279	1	20	)	)	PUNCT
eurjchem-2279	1	21	145	145	NUM
eurjchem-2279	1	22	-	-	SYM
eurjchem-2279	1	23	150	150	NUM
eurjchem-2279	1	24	european	european	ADJ
eurjchem-2279	1	25	journal	journal	NOUN
eurjchem-2279	1	26	of	of	ADP
eurjchem-2279	1	27	chemistry	chemistry	NOUN
eurjchem-2279	1	28	issn	issn	VERB
eurjchem-2279	1	29	2153	2153	NUM
eurjchem-2279	1	30	-	-	SYM
eurjchem-2279	1	31	2249	2249	NUM
eurjchem-2279	1	32	(	(	PUNCT
eurjchem-2279	1	33	print	print	NOUN
eurjchem-2279	1	34	)	)	PUNCT
eurjchem-2279	1	35	/	/	PUNCT
eurjchem-2279	1	36	issn	issn	PROPN
eurjchem-2279	1	37	2153	2153	NUM
eurjchem-2279	1	38	-	-	SYM
eurjchem-2279	1	39	2257	2257	NUM
eurjchem-2279	1	40	(	(	PUNCT
eurjchem-2279	1	41	online	online	ADJ
eurjchem-2279	1	42	)	)	PUNCT
eurjchem-2279	1	43	–	–	PUNCT
eurjchem-2279	2	1	copyright	copyright	NOUN
eurjchem-2279	2	2	©	©	PROPN
eurjchem-2279	2	3	2022	2022	NUM
eurjchem-2279	2	4	the	the	DET
eurjchem-2279	2	5	authors	author	NOUN
eurjchem-2279	2	6	–	–	PUNCT
eurjchem-2279	2	7	atlanta	atlanta	PROPN
eurjchem-2279	2	8	publishing	publishing	PROPN
eurjchem-2279	2	9	house	house	PROPN
eurjchem-2279	2	10	llc	llc	PROPN
eurjchem-2279	2	11	–	–	PUNCT
eurjchem-2279	2	12	printed	print	VERB
eurjchem-2279	2	13	in	in	ADP
eurjchem-2279	2	14	the	the	DET
eurjchem-2279	2	15	usa	usa	PROPN
eurjchem-2279	2	16	.	.	PUNCT
eurjchem-2279	3	1	this	this	DET
eurjchem-2279	3	2	work	work	NOUN
eurjchem-2279	3	3	is	be	AUX
eurjchem-2279	3	4	published	publish	VERB
eurjchem-2279	3	5	and	and	CCONJ
eurjchem-2279	3	6	licensed	license	VERB
eurjchem-2279	3	7	by	by	ADP
eurjchem-2279	3	8	atlanta	atlanta	PROPN
eurjchem-2279	3	9	publishing	publishing	PROPN
eurjchem-2279	3	10	house	house	PROPN
eurjchem-2279	3	11	llc	llc	PROPN
eurjchem-2279	3	12	–	–	PUNCT
eurjchem-2279	3	13	cc	cc	PROPN
eurjchem-2279	3	14	by	by	ADP
eurjchem-2279	3	15	nc	nc	PROPN
eurjchem-2279	3	16	–	–	PUNCT
eurjchem-2279	3	17	some	some	DET
eurjchem-2279	3	18	rights	right	NOUN
eurjchem-2279	3	19	reserved	reserve	VERB
eurjchem-2279	3	20	.	.	PUNCT
eurjchem-2279	4	1	https://dx.doi.org/10.5155/eurjchem.13.2.145-150.2279	https://dx.doi.org/10.5155/eurjchem.13.2.145-150.2279	PROPN
eurjchem-2279	4	2	european	european	PROPN
eurjchem-2279	4	3	journal	journal	PROPN
eurjchem-2279	4	4	of	of	ADP
eurjchem-2279	4	5	chemistry	chemistry	NOUN
eurjchem-2279	4	6	view	view	NOUN
eurjchem-2279	4	7	journal	journal	PROPN
eurjchem-2279	4	8	online	online	PROPN
eurjchem-2279	4	9	view	view	NOUN
eurjchem-2279	4	10	article	article	NOUN
eurjchem-2279	4	11	online	online	PROPN
eurjchem-2279	4	12	crystal	crystal	PROPN
eurjchem-2279	4	13	structure	structure	NOUN
eurjchem-2279	4	14	of	of	ADP
eurjchem-2279	4	15	2,4	2,4	NUM
eurjchem-2279	4	16	-	-	PUNCT
eurjchem-2279	4	17	dinitrophenyl	dinitrophenyl	ADJ
eurjchem-2279	4	18	2,4,6	2,4,6	NUM
eurjchem-2279	4	19	-	-	PUNCT
eurjchem-2279	4	20	trimethylbenzenesulfonate	trimethylbenzenesulfonate	NOUN
eurjchem-2279	4	21	brock	brock	PROPN
eurjchem-2279	4	22	anton	anton	PROPN
eurjchem-2279	4	23	stenfors	stenfor	NOUN
eurjchem-2279	4	24	and	and	CCONJ
eurjchem-2279	4	25	felix	felix	PROPN
eurjchem-2279	4	26	nyuangem	nyuangem	PROPN
eurjchem-2279	4	27	ngassa	ngassa	PROPN
eurjchem-2279	4	28	*	*	PUNCT
eurjchem-2279	4	29	department	department	NOUN
eurjchem-2279	4	30	of	of	ADP
eurjchem-2279	4	31	chemistry	chemistry	NOUN
eurjchem-2279	4	32	,	,	PUNCT
eurjchem-2279	4	33	grand	grand	ADJ
eurjchem-2279	4	34	valley	valley	PROPN
eurjchem-2279	4	35	state	state	PROPN
eurjchem-2279	4	36	university	university	PROPN
eurjchem-2279	4	37	,	,	PUNCT
eurjchem-2279	4	38	1	1	NUM
eurjchem-2279	4	39	campus	campus	NOUN
eurjchem-2279	4	40	drive	drive	NOUN
eurjchem-2279	4	41	,	,	PUNCT
eurjchem-2279	4	42	allendale	allendale	PROPN
eurjchem-2279	4	43	,	,	PUNCT
eurjchem-2279	4	44	mi	mi	PROPN
eurjchem-2279	4	45	49401	49401	NUM
eurjchem-2279	4	46	,	,	PUNCT
eurjchem-2279	4	47	usa	usa	PROPN
eurjchem-2279	4	48	*	*	PUNCT
eurjchem-2279	4	49	corresponding	correspond	VERB
eurjchem-2279	4	50	author	author	NOUN
eurjchem-2279	4	51	at	at	ADP
eurjchem-2279	4	52	:	:	PUNCT
eurjchem-2279	4	53	department	department	NOUN
eurjchem-2279	4	54	of	of	ADP
eurjchem-2279	4	55	chemistry	chemistry	NOUN
eurjchem-2279	4	56	,	,	PUNCT
eurjchem-2279	4	57	grand	grand	ADJ
eurjchem-2279	4	58	valley	valley	PROPN
eurjchem-2279	4	59	state	state	PROPN
eurjchem-2279	4	60	university	university	PROPN
eurjchem-2279	4	61	,	,	PUNCT
eurjchem-2279	4	62	1	1	NUM
eurjchem-2279	4	63	campus	campus	NOUN
eurjchem-2279	4	64	drive	drive	NOUN
eurjchem-2279	4	65	,	,	PUNCT
eurjchem-2279	4	66	allendale	allendale	PROPN
eurjchem-2279	4	67	,	,	PUNCT
eurjchem-2279	4	68	mi	mi	PROPN
eurjchem-2279	4	69	49401	49401	NUM
eurjchem-2279	4	70	,	,	PUNCT
eurjchem-2279	4	71	usa	usa	PROPN
eurjchem-2279	4	72	.	.	PROPN
eurjchem-2279	5	1	e	e	X
eurjchem-2279	5	2	-	-	NOUN
eurjchem-2279	5	3	mail	mail	NOUN
eurjchem-2279	5	4	:	:	PUNCT
eurjchem-2279	5	5	ngassaf@gvsu.edu	ngassaf@gvsu.edu	PROPN
eurjchem-2279	5	6	(	(	PUNCT
eurjchem-2279	5	7	f.n	f.n	PROPN
eurjchem-2279	5	8	.	.	NOUN
eurjchem-2279	5	9	ngassa	ngassa	NOUN
eurjchem-2279	5	10	)	)	PUNCT
eurjchem-2279	5	11	.	.	PUNCT
eurjchem-2279	6	1	10.5155	10.5155	NUM
eurjchem-2279	6	2	/	/	SYM
eurjchem-2279	6	3	eurjchem.13.2.145	eurjchem.13.2.145	NOUN
eurjchem-2279	6	4	-	-	SYM
eurjchem-2279	6	5	150.2279	150.2279	NOUN
eurjchem-2279	6	6	received	receive	VERB
eurjchem-2279	6	7	:	:	PUNCT
eurjchem-2279	6	8	06	06	NUM
eurjchem-2279	6	9	april	april	PROPN
eurjchem-2279	6	10	2022	2022	NUM
eurjchem-2279	6	11	received	receive	VERB
eurjchem-2279	6	12	in	in	ADP
eurjchem-2279	6	13	revised	revise	VERB
eurjchem-2279	6	14	form	form	NOUN
eurjchem-2279	6	15	:	:	PUNCT
eurjchem-2279	6	16	12	12	NUM
eurjchem-2279	6	17	april	april	PROPN
eurjchem-2279	6	18	2022	2022	NUM
eurjchem-2279	6	19	accepted	accept	VERB
eurjchem-2279	6	20	:	:	PUNCT
eurjchem-2279	6	21	27	27	NUM
eurjchem-2279	6	22	april	april	PROPN
eurjchem-2279	6	23	2022	2022	NUM
eurjchem-2279	6	24	published	publish	VERB
eurjchem-2279	6	25	online	online	ADV
eurjchem-2279	6	26	:	:	PUNCT
eurjchem-2279	6	27	30	30	NUM
eurjchem-2279	6	28	june	june	PROPN
eurjchem-2279	6	29	2022	2022	NUM
eurjchem-2279	6	30	printed	print	VERB
eurjchem-2279	6	31	:	:	PUNCT
eurjchem-2279	6	32	30	30	NUM
eurjchem-2279	6	33	june	june	PROPN
eurjchem-2279	6	34	2022	2022	NUM
eurjchem-2279	6	35	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	6	36	are	be	AUX
eurjchem-2279	6	37	a	a	DET
eurjchem-2279	6	38	useful	useful	ADJ
eurjchem-2279	6	39	class	class	NOUN
eurjchem-2279	6	40	of	of	ADP
eurjchem-2279	6	41	synthetic	synthetic	ADJ
eurjchem-2279	6	42	precursors	precursor	NOUN
eurjchem-2279	6	43	,	,	PUNCT
eurjchem-2279	6	44	affording	afford	VERB
eurjchem-2279	6	45	either	either	CCONJ
eurjchem-2279	6	46	their	their	PRON
eurjchem-2279	6	47	arylamine	arylamine	NOUN
eurjchem-2279	6	48	or	or	CCONJ
eurjchem-2279	6	49	arylsulfonamide	arylsulfonamide	NOUN
eurjchem-2279	6	50	counterparts	counterpart	NOUN
eurjchem-2279	6	51	upon	upon	SCONJ
eurjchem-2279	6	52	amination	amination	NOUN
eurjchem-2279	6	53	via	via	ADP
eurjchem-2279	6	54	regioselective	regioselective	ADJ
eurjchem-2279	6	55	c	c	PROPN
eurjchem-2279	6	56	–	–	PUNCT
eurjchem-2279	6	57	o	o	NOUN
eurjchem-2279	6	58	/	/	SYM
eurjchem-2279	6	59	s	s	PROPN
eurjchem-2279	6	60	–	–	PUNCT
eurjchem-2279	6	61	o	o	NOUN
eurjchem-2279	6	62	bond	bond	NOUN
eurjchem-2279	6	63	cleavage	cleavage	NOUN
eurjchem-2279	6	64	.	.	PUNCT
eurjchem-2279	7	1	herein	herein	NOUN
eurjchem-2279	7	2	,	,	PUNCT
eurjchem-2279	7	3	the	the	DET
eurjchem-2279	7	4	synthesis	synthesis	NOUN
eurjchem-2279	7	5	of	of	ADP
eurjchem-2279	7	6	2,4	2,4	NUM
eurjchem-2279	7	7	-	-	PUNCT
eurjchem-2279	7	8	dinitrophenyl	dinitrophenyl	ADJ
eurjchem-2279	7	9	2,4,6	2,4,6	NUM
eurjchem-2279	7	10	-	-	PUNCT
eurjchem-2279	7	11	trimethylbenzenesulfonate	trimethylbenzenesulfonate	NOUN
eurjchem-2279	7	12	is	be	AUX
eurjchem-2279	7	13	described	describe	VERB
eurjchem-2279	7	14	,	,	PUNCT
eurjchem-2279	7	15	utilizing	utilize	VERB
eurjchem-2279	7	16	our	our	PRON
eurjchem-2279	7	17	previously	previously	ADV
eurjchem-2279	7	18	developed	develop	VERB
eurjchem-2279	7	19	synthetic	synthetic	ADJ
eurjchem-2279	7	20	methods	method	NOUN
eurjchem-2279	7	21	,	,	PUNCT
eurjchem-2279	7	22	and	and	CCONJ
eurjchem-2279	7	23	crystallographic	crystallographic	ADJ
eurjchem-2279	7	24	characterization	characterization	NOUN
eurjchem-2279	7	25	.	.	PUNCT
eurjchem-2279	8	1	while	while	SCONJ
eurjchem-2279	8	2	the	the	DET
eurjchem-2279	8	3	mechanism	mechanism	NOUN
eurjchem-2279	8	4	for	for	ADP
eurjchem-2279	8	5	nucleophilic	nucleophilic	ADJ
eurjchem-2279	8	6	substitution	substitution	NOUN
eurjchem-2279	8	7	at	at	ADP
eurjchem-2279	8	8	the	the	DET
eurjchem-2279	8	9	sulfonyl	sulfonyl	NOUN
eurjchem-2279	8	10	group	group	NOUN
eurjchem-2279	8	11	remains	remain	VERB
eurjchem-2279	8	12	largely	largely	ADV
eurjchem-2279	8	13	unknown	unknown	ADJ
eurjchem-2279	8	14	,	,	PUNCT
eurjchem-2279	8	15	experimental	experimental	ADJ
eurjchem-2279	8	16	work	work	NOUN
eurjchem-2279	8	17	within	within	ADP
eurjchem-2279	8	18	our	our	PRON
eurjchem-2279	8	19	group	group	NOUN
eurjchem-2279	8	20	and	and	CCONJ
eurjchem-2279	8	21	in	in	ADP
eurjchem-2279	8	22	the	the	DET
eurjchem-2279	8	23	literature	literature	NOUN
eurjchem-2279	8	24	lend	lend	VERB
eurjchem-2279	8	25	credence	credence	NOUN
eurjchem-2279	8	26	to	to	ADP
eurjchem-2279	8	27	a	a	DET
eurjchem-2279	8	28	mechanism	mechanism	NOUN
eurjchem-2279	8	29	analogous	analogous	ADJ
eurjchem-2279	8	30	to	to	ADP
eurjchem-2279	8	31	its	its	PRON
eurjchem-2279	8	32	carbonyl	carbonyl	NOUN
eurjchem-2279	8	33	counterpart	counterpart	NOUN
eurjchem-2279	8	34	.	.	PUNCT
eurjchem-2279	9	1	characterization	characterization	NOUN
eurjchem-2279	9	2	of	of	ADP
eurjchem-2279	9	3	the	the	DET
eurjchem-2279	9	4	molecular	molecular	ADJ
eurjchem-2279	9	5	structure	structure	NOUN
eurjchem-2279	9	6	of	of	ADP
eurjchem-2279	9	7	the	the	DET
eurjchem-2279	9	8	title	title	NOUN
eurjchem-2279	9	9	compound	compound	NOUN
eurjchem-2279	9	10	,	,	PUNCT
eurjchem-2279	9	11	c15h14n2o7s	c15h14n2o7s	PROPN
eurjchem-2279	9	12	,	,	PUNCT
eurjchem-2279	9	13	at	at	ADP
eurjchem-2279	9	14	173	173	NUM
eurjchem-2279	9	15	k	k	NOUN
eurjchem-2279	9	16	,	,	PUNCT
eurjchem-2279	9	17	features	feature	VERB
eurjchem-2279	9	18	a	a	DET
eurjchem-2279	9	19	sulfonate	sulfonate	ADJ
eurjchem-2279	9	20	group	group	NOUN
eurjchem-2279	9	21	with	with	ADP
eurjchem-2279	9	22	s	s	PROPN
eurjchem-2279	9	23	=	=	NOUN
eurjchem-2279	9	24	o	o	NOUN
eurjchem-2279	9	25	bond	bond	NOUN
eurjchem-2279	9	26	lengths	length	NOUN
eurjchem-2279	9	27	of	of	ADP
eurjchem-2279	9	28	1.4198(19	1.4198(19	NUM
eurjchem-2279	9	29	)	)	PUNCT
eurjchem-2279	9	30	and	and	CCONJ
eurjchem-2279	9	31	1.4183(19	1.4183(19	NUM
eurjchem-2279	9	32	)	)	PUNCT
eurjchem-2279	9	33	å	å	PROPN
eurjchem-2279	9	34	and	and	CCONJ
eurjchem-2279	9	35	a	a	DET
eurjchem-2279	9	36	s	s	PROPN
eurjchem-2279	9	37	–	–	PUNCT
eurjchem-2279	9	38	o	o	NOUN
eurjchem-2279	9	39	bond	bond	NOUN
eurjchem-2279	9	40	length	length	NOUN
eurjchem-2279	9	41	of	of	ADP
eurjchem-2279	9	42	1.6387(18	1.6387(18	NUM
eurjchem-2279	9	43	)	)	PUNCT
eurjchem-2279	10	1	å	å	NOUN
eurjchem-2279	10	2	.	.	PUNCT
eurjchem-2279	11	1	viewing	view	VERB
eurjchem-2279	11	2	down	down	ADP
eurjchem-2279	11	3	the	the	DET
eurjchem-2279	11	4	s	s	PROPN
eurjchem-2279	11	5	–	–	PUNCT
eurjchem-2279	11	6	o	o	NOUN
eurjchem-2279	11	7	bond	bond	NOUN
eurjchem-2279	11	8	reveals	reveal	VERB
eurjchem-2279	11	9	gauche	gauche	NOUN
eurjchem-2279	11	10	oriented	orient	VERB
eurjchem-2279	11	11	aromatic	aromatic	ADJ
eurjchem-2279	11	12	rings	ring	NOUN
eurjchem-2279	11	13	.	.	PUNCT
eurjchem-2279	12	1	crystal	crystal	NOUN
eurjchem-2279	12	2	data	data	PROPN
eurjchem-2279	12	3	for	for	ADP
eurjchem-2279	12	4	c15h14n2o7s	c15h14n2o7s	PROPN
eurjchem-2279	12	5	:	:	PUNCT
eurjchem-2279	12	6	monoclinic	monoclinic	ADJ
eurjchem-2279	12	7	,	,	PUNCT
eurjchem-2279	12	8	space	space	NOUN
eurjchem-2279	12	9	group	group	NOUN
eurjchem-2279	12	10	p21	p21	PROPN
eurjchem-2279	12	11	/	/	SYM
eurjchem-2279	12	12	c	c	PROPN
eurjchem-2279	12	13	(	(	PUNCT
eurjchem-2279	12	14	no	no	INTJ
eurjchem-2279	12	15	.	.	NOUN
eurjchem-2279	12	16	14	14	NUM
eurjchem-2279	12	17	)	)	PUNCT
eurjchem-2279	12	18	,	,	PUNCT
eurjchem-2279	12	19	a	a	DET
eurjchem-2279	12	20	=	=	SYM
eurjchem-2279	12	21	6.8773(10	6.8773(10	NUM
eurjchem-2279	12	22	)	)	PUNCT
eurjchem-2279	12	23	å	å	PROPN
eurjchem-2279	12	24	,	,	PUNCT
eurjchem-2279	12	25	b	b	NOUN
eurjchem-2279	12	26	=	=	SYM
eurjchem-2279	12	27	8.9070(14	8.9070(14	NUM
eurjchem-2279	12	28	)	)	PUNCT
eurjchem-2279	12	29	å	å	PROPN
eurjchem-2279	12	30	,	,	PUNCT
eurjchem-2279	12	31	c	c	NOUN
eurjchem-2279	12	32	=	=	SYM
eurjchem-2279	12	33	25.557(4	25.557(4	NUM
eurjchem-2279	12	34	)	)	PUNCT
eurjchem-2279	12	35	å	å	NOUN
eurjchem-2279	12	36	,	,	PUNCT
eurjchem-2279	12	37	β	β	X
eurjchem-2279	12	38	=	=	SYM
eurjchem-2279	12	39	93.0630(18	93.0630(18	NUM
eurjchem-2279	12	40	)	)	PUNCT
eurjchem-2279	12	41	°	°	NOUN
eurjchem-2279	12	42	,	,	PUNCT
eurjchem-2279	12	43	v	v	NOUN
eurjchem-2279	12	44	=	=	SYM
eurjchem-2279	12	45	1563.3(4	1563.3(4	NOUN
eurjchem-2279	12	46	)	)	PUNCT
eurjchem-2279	12	47	å3	å3	PROPN
eurjchem-2279	12	48	,	,	PUNCT
eurjchem-2279	12	49	z	z	NOUN
eurjchem-2279	12	50	=	=	SYM
eurjchem-2279	12	51	4	4	NUM
eurjchem-2279	12	52	,	,	PUNCT
eurjchem-2279	12	53	t	t	NOUN
eurjchem-2279	12	54	=	=	SYM
eurjchem-2279	12	55	173.15	173.15	NUM
eurjchem-2279	12	56	k	k	NOUN
eurjchem-2279	12	57	,	,	PUNCT
eurjchem-2279	12	58	μ(mokα	μ(mokα	NOUN
eurjchem-2279	12	59	)	)	PUNCT
eurjchem-2279	12	60	=	=	SYM
eurjchem-2279	12	61	0.251	0.251	NUM
eurjchem-2279	12	62	mm-1	mm-1	NOUN
eurjchem-2279	12	63	,	,	PUNCT
eurjchem-2279	12	64	dcalc	dcalc	NOUN
eurjchem-2279	12	65	=	=	NOUN
eurjchem-2279	12	66	1.557	1.557	NUM
eurjchem-2279	12	67	g	g	NOUN
eurjchem-2279	12	68	/	/	SYM
eurjchem-2279	12	69	cm3	cm3	NOUN
eurjchem-2279	12	70	,	,	PUNCT
eurjchem-2279	12	71	12259	12259	NUM
eurjchem-2279	12	72	reflections	reflection	NOUN
eurjchem-2279	12	73	measured	measure	VERB
eurjchem-2279	12	74	(	(	PUNCT
eurjchem-2279	12	75	3.192	3.192	NUM
eurjchem-2279	12	76	°	°	NOUN
eurjchem-2279	12	77	≤	≤	ADJ
eurjchem-2279	12	78	2θ	2θ	NUM
eurjchem-2279	12	79	≤	≤	NUM
eurjchem-2279	12	80	50.682	50.682	NUM
eurjchem-2279	12	81	°	°	NUM
eurjchem-2279	12	82	)	)	PUNCT
eurjchem-2279	12	83	,	,	PUNCT
eurjchem-2279	12	84	2861	2861	NUM
eurjchem-2279	12	85	unique	unique	ADJ
eurjchem-2279	12	86	(	(	PUNCT
eurjchem-2279	12	87	rint	rint	NOUN
eurjchem-2279	12	88	=	=	SYM
eurjchem-2279	12	89	0.0493	0.0493	NUM
eurjchem-2279	12	90	,	,	PUNCT
eurjchem-2279	12	91	rsigma	rsigma	ADJ
eurjchem-2279	12	92	=	=	SYM
eurjchem-2279	12	93	0.0419	0.0419	NUM
eurjchem-2279	12	94	)	)	PUNCT
eurjchem-2279	12	95	which	which	PRON
eurjchem-2279	12	96	were	be	AUX
eurjchem-2279	12	97	used	use	VERB
eurjchem-2279	12	98	in	in	ADP
eurjchem-2279	12	99	all	all	DET
eurjchem-2279	12	100	calculations	calculation	NOUN
eurjchem-2279	12	101	.	.	PUNCT
eurjchem-2279	13	1	the	the	DET
eurjchem-2279	13	2	final	final	ADJ
eurjchem-2279	13	3	r1	r1	NOUN
eurjchem-2279	13	4	was	be	AUX
eurjchem-2279	13	5	0.0457	0.0457	NUM
eurjchem-2279	13	6	(	(	PUNCT
eurjchem-2279	13	7	i	i	X
eurjchem-2279	13	8	>	>	X
eurjchem-2279	13	9	2σ(i	2σ(i	NUM
eurjchem-2279	13	10	)	)	PUNCT
eurjchem-2279	13	11	)	)	PUNCT
eurjchem-2279	14	1	and	and	CCONJ
eurjchem-2279	14	2	wr2	wr2	PROPN
eurjchem-2279	14	3	was	be	AUX
eurjchem-2279	14	4	0.1306	0.1306	NUM
eurjchem-2279	14	5	(	(	PUNCT
eurjchem-2279	14	6	all	all	DET
eurjchem-2279	14	7	data	datum	NOUN
eurjchem-2279	14	8	)	)	PUNCT
eurjchem-2279	14	9	.	.	PUNCT
eurjchem-2279	15	1	crystal	crystal	NOUN
eurjchem-2279	15	2	sulfonate	sulfonate	NOUN
eurjchem-2279	15	3	sulfonylation	sulfonylation	NOUN
eurjchem-2279	15	4	crystallization	crystallization	NOUN
eurjchem-2279	15	5	x	x	NOUN
eurjchem-2279	15	6	-	-	NOUN
eurjchem-2279	15	7	ray	ray	NOUN
eurjchem-2279	15	8	diffraction	diffraction	NOUN
eurjchem-2279	15	9	synthetic	synthetic	ADJ
eurjchem-2279	15	10	methods	method	NOUN
eurjchem-2279	15	11	cite	cite	VERB
eurjchem-2279	15	12	this	this	PRON
eurjchem-2279	15	13	:	:	PUNCT
eurjchem-2279	15	14	eur	eur	PROPN
eurjchem-2279	15	15	.	.	PUNCT
eurjchem-2279	16	1	j.	j.	PROPN
eurjchem-2279	16	2	chem	chem	PROPN
eurjchem-2279	16	3	.	.	PUNCT
eurjchem-2279	17	1	2022	2022	NUM
eurjchem-2279	17	2	,	,	PUNCT
eurjchem-2279	17	3	13(2	13(2	PROPN
eurjchem-2279	17	4	)	)	PUNCT
eurjchem-2279	17	5	,	,	PUNCT
eurjchem-2279	17	6	145	145	NUM
eurjchem-2279	17	7	-	-	SYM
eurjchem-2279	17	8	150	150	NUM
eurjchem-2279	17	9	journal	journal	NOUN
eurjchem-2279	17	10	website	website	NOUN
eurjchem-2279	17	11	:	:	PUNCT
eurjchem-2279	17	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2279	17	13	1	1	X
eurjchem-2279	17	14	.	.	PUNCT
eurjchem-2279	18	1	introduction	introduction	NOUN
eurjchem-2279	18	2	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	18	3	are	be	AUX
eurjchem-2279	18	4	ubiquitous	ubiquitous	ADJ
eurjchem-2279	18	5	building	building	NOUN
eurjchem-2279	18	6	blocks	block	NOUN
eurjchem-2279	18	7	in	in	ADP
eurjchem-2279	18	8	synthetic	synthetic	ADJ
eurjchem-2279	18	9	chemistry	chemistry	NOUN
eurjchem-2279	18	10	,	,	PUNCT
eurjchem-2279	18	11	utilized	utilize	VERB
eurjchem-2279	18	12	as	as	ADP
eurjchem-2279	18	13	synthetic	synthetic	ADJ
eurjchem-2279	18	14	precursors	precursor	NOUN
eurjchem-2279	18	15	and	and	CCONJ
eurjchem-2279	18	16	protecting	protect	VERB
eurjchem-2279	18	17	groups	group	NOUN
eurjchem-2279	18	18	alike	alike	ADV
eurjchem-2279	18	19	due	due	ADP
eurjchem-2279	18	20	to	to	ADP
eurjchem-2279	18	21	the	the	DET
eurjchem-2279	18	22	stability	stability	NOUN
eurjchem-2279	18	23	of	of	ADP
eurjchem-2279	18	24	the	the	DET
eurjchem-2279	18	25	sulfonate	sulfonate	ADJ
eurjchem-2279	18	26	ester	ester	NOUN
eurjchem-2279	18	27	leaving	leave	VERB
eurjchem-2279	18	28	group	group	NOUN
eurjchem-2279	19	1	[	[	X
eurjchem-2279	19	2	1,2	1,2	NUM
eurjchem-2279	19	3	]	]	PUNCT
eurjchem-2279	19	4	.	.	PUNCT
eurjchem-2279	20	1	this	this	DET
eurjchem-2279	20	2	class	class	NOUN
eurjchem-2279	20	3	of	of	ADP
eurjchem-2279	20	4	compounds	compound	NOUN
eurjchem-2279	20	5	also	also	ADV
eurjchem-2279	20	6	exhibit	exhibit	VERB
eurjchem-2279	20	7	medicinal	medicinal	ADJ
eurjchem-2279	20	8	properties	property	NOUN
eurjchem-2279	20	9	[	[	X
eurjchem-2279	20	10	3,4	3,4	NUM
eurjchem-2279	20	11	]	]	PUNCT
eurjchem-2279	20	12	.	.	PUNCT
eurjchem-2279	21	1	while	while	SCONJ
eurjchem-2279	21	2	the	the	DET
eurjchem-2279	21	3	importance	importance	NOUN
eurjchem-2279	21	4	of	of	ADP
eurjchem-2279	21	5	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	21	6	is	be	AUX
eurjchem-2279	21	7	evident	evident	ADJ
eurjchem-2279	21	8	,	,	PUNCT
eurjchem-2279	21	9	mechanistic	mechanistic	ADJ
eurjchem-2279	21	10	details	detail	NOUN
eurjchem-2279	21	11	for	for	ADP
eurjchem-2279	21	12	nucleophilic	nucleophilic	ADJ
eurjchem-2279	21	13	substitution	substitution	NOUN
eurjchem-2279	21	14	at	at	ADP
eurjchem-2279	21	15	the	the	DET
eurjchem-2279	21	16	sulfonyl	sulfonyl	NOUN
eurjchem-2279	21	17	group	group	NOUN
eurjchem-2279	21	18	remain	remain	VERB
eurjchem-2279	21	19	unknown	unknown	ADJ
eurjchem-2279	21	20	[	[	X
eurjchem-2279	21	21	5	5	NUM
eurjchem-2279	21	22	-	-	SYM
eurjchem-2279	21	23	8	8	NUM
eurjchem-2279	21	24	]	]	PUNCT
eurjchem-2279	21	25	.	.	PUNCT
eurjchem-2279	22	1	previous	previous	ADJ
eurjchem-2279	22	2	reports	report	NOUN
eurjchem-2279	22	3	suggest	suggest	VERB
eurjchem-2279	22	4	a	a	DET
eurjchem-2279	22	5	substitution	substitution	NOUN
eurjchem-2279	22	6	mechanism	mechanism	NOUN
eurjchem-2279	22	7	somewhat	somewhat	ADV
eurjchem-2279	22	8	analogous	analogous	ADJ
eurjchem-2279	22	9	to	to	ADP
eurjchem-2279	22	10	its	its	PRON
eurjchem-2279	22	11	carbonyl	carbonyl	NOUN
eurjchem-2279	22	12	counterpart	counterpart	NOUN
eurjchem-2279	23	1	[	[	X
eurjchem-2279	23	2	9,10	9,10	NUM
eurjchem-2279	23	3	]	]	PUNCT
eurjchem-2279	23	4	.	.	PUNCT
eurjchem-2279	24	1	in	in	ADP
eurjchem-2279	24	2	our	our	PRON
eurjchem-2279	24	3	work	work	NOUN
eurjchem-2279	24	4	,	,	PUNCT
eurjchem-2279	24	5	our	our	PRON
eurjchem-2279	24	6	interests	interest	NOUN
eurjchem-2279	24	7	are	be	AUX
eurjchem-2279	24	8	focused	focus	VERB
eurjchem-2279	24	9	on	on	ADP
eurjchem-2279	24	10	the	the	DET
eurjchem-2279	24	11	nucleophilic	nucleophilic	ADJ
eurjchem-2279	24	12	aromatic	aromatic	ADJ
eurjchem-2279	24	13	substitution	substitution	NOUN
eurjchem-2279	24	14	(	(	PUNCT
eurjchem-2279	24	15	snar	snar	NOUN
eurjchem-2279	24	16	)	)	PUNCT
eurjchem-2279	24	17	reaction	reaction	NOUN
eurjchem-2279	24	18	of	of	ADP
eurjchem-2279	24	19	various	various	ADJ
eurjchem-2279	24	20	arylsulfonate	arylsulfonate	NOUN
eurjchem-2279	24	21	analogs	analog	NOUN
eurjchem-2279	24	22	.	.	PUNCT
eurjchem-2279	25	1	while	while	SCONJ
eurjchem-2279	25	2	the	the	DET
eurjchem-2279	25	3	s	s	PROPN
eurjchem-2279	25	4	–	–	PUNCT
eurjchem-2279	25	5	o	o	NOUN
eurjchem-2279	25	6	cleavage	cleavage	NOUN
eurjchem-2279	25	7	is	be	AUX
eurjchem-2279	25	8	responsible	responsible	ADJ
eurjchem-2279	25	9	for	for	ADP
eurjchem-2279	25	10	most	most	ADJ
eurjchem-2279	25	11	of	of	ADP
eurjchem-2279	25	12	the	the	DET
eurjchem-2279	25	13	uses	use	NOUN
eurjchem-2279	25	14	currently	currently	ADV
eurjchem-2279	25	15	seen	see	VERB
eurjchem-2279	25	16	in	in	ADP
eurjchem-2279	25	17	the	the	DET
eurjchem-2279	25	18	literature	literature	NOUN
eurjchem-2279	25	19	,	,	PUNCT
eurjchem-2279	25	20	a	a	DET
eurjchem-2279	25	21	competitive	competitive	ADJ
eurjchem-2279	25	22	s	s	NOUN
eurjchem-2279	25	23	–	–	PUNCT
eurjchem-2279	25	24	o	o	NOUN
eurjchem-2279	25	25	and	and	CCONJ
eurjchem-2279	25	26	c	c	NOUN
eurjchem-2279	25	27	–	–	PUNCT
eurjchem-2279	25	28	o	o	NOUN
eurjchem-2279	25	29	bond	bond	NOUN
eurjchem-2279	25	30	fission	fission	NOUN
eurjchem-2279	25	31	of	of	ADP
eurjchem-2279	25	32	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	25	33	,	,	PUNCT
eurjchem-2279	25	34	in	in	ADP
eurjchem-2279	25	35	the	the	DET
eurjchem-2279	25	36	presence	presence	NOUN
eurjchem-2279	25	37	of	of	ADP
eurjchem-2279	25	38	a	a	DET
eurjchem-2279	25	39	nucleophilic	nucleophilic	ADJ
eurjchem-2279	25	40	amine	amine	NOUN
eurjchem-2279	25	41	,	,	PUNCT
eurjchem-2279	25	42	lends	lend	VERB
eurjchem-2279	25	43	credence	credence	NOUN
eurjchem-2279	25	44	to	to	ADP
eurjchem-2279	25	45	a	a	DET
eurjchem-2279	25	46	facile	facile	ADJ
eurjchem-2279	25	47	synthesis	synthesis	NOUN
eurjchem-2279	25	48	of	of	ADP
eurjchem-2279	25	49	arylamines	arylamine	NOUN
eurjchem-2279	25	50	and	and	CCONJ
eurjchem-2279	25	51	arylsulfonamides	arylsulfonamide	NOUN
eurjchem-2279	25	52	,	,	PUNCT
eurjchem-2279	25	53	two	two	NUM
eurjchem-2279	25	54	biologically	biologically	ADV
eurjchem-2279	25	55	significant	significant	ADJ
eurjchem-2279	25	56	classes	class	NOUN
eurjchem-2279	25	57	of	of	ADP
eurjchem-2279	25	58	compounds	compound	NOUN
eurjchem-2279	25	59	[	[	X
eurjchem-2279	25	60	11	11	NUM
eurjchem-2279	25	61	]	]	PUNCT
eurjchem-2279	25	62	.	.	PUNCT
eurjchem-2279	26	1	previously	previously	ADV
eurjchem-2279	26	2	,	,	PUNCT
eurjchem-2279	26	3	our	our	PRON
eurjchem-2279	26	4	group	group	NOUN
eurjchem-2279	26	5	investigated	investigate	VERB
eurjchem-2279	26	6	the	the	DET
eurjchem-2279	26	7	structure	structure	NOUN
eurjchem-2279	26	8	of	of	ADP
eurjchem-2279	26	9	two	two	NUM
eurjchem-2279	26	10	unique	unique	ADJ
eurjchem-2279	26	11	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	26	12	[	[	X
eurjchem-2279	26	13	12,13	12,13	NUM
eurjchem-2279	26	14	]	]	PUNCT
eurjchem-2279	26	15	.	.	PUNCT
eurjchem-2279	27	1	a	a	DET
eurjchem-2279	27	2	variety	variety	NOUN
eurjchem-2279	27	3	of	of	ADP
eurjchem-2279	27	4	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	27	5	have	have	AUX
eurjchem-2279	27	6	been	be	AUX
eurjchem-2279	27	7	synthesized	synthesize	VERB
eurjchem-2279	27	8	to	to	PART
eurjchem-2279	27	9	gain	gain	VERB
eurjchem-2279	27	10	further	further	ADJ
eurjchem-2279	27	11	insight	insight	NOUN
eurjchem-2279	27	12	into	into	ADP
eurjchem-2279	27	13	the	the	DET
eurjchem-2279	27	14	regioselective	regioselective	ADJ
eurjchem-2279	27	15	factors	factor	NOUN
eurjchem-2279	27	16	responsible	responsible	ADJ
eurjchem-2279	27	17	for	for	ADP
eurjchem-2279	27	18	the	the	DET
eurjchem-2279	27	19	s	s	NOUN
eurjchem-2279	27	20	–	–	PUNCT
eurjchem-2279	27	21	o	o	NOUN
eurjchem-2279	27	22	/	/	SYM
eurjchem-2279	27	23	c	c	PROPN
eurjchem-2279	27	24	–	–	PUNCT
eurjchem-2279	27	25	o	o	NOUN
eurjchem-2279	27	26	bond	bond	NOUN
eurjchem-2279	27	27	cleavage	cleavage	NOUN
eurjchem-2279	27	28	(	(	PUNCT
eurjchem-2279	27	29	scheme	scheme	NOUN
eurjchem-2279	27	30	1	1	NUM
eurjchem-2279	27	31	)	)	PUNCT
eurjchem-2279	27	32	.	.	PUNCT
eurjchem-2279	28	1	apart	apart	ADV
eurjchem-2279	28	2	from	from	ADP
eurjchem-2279	28	3	being	be	AUX
eurjchem-2279	28	4	useful	useful	ADJ
eurjchem-2279	28	5	synthetic	synthetic	ADJ
eurjchem-2279	28	6	precursors	precursor	NOUN
eurjchem-2279	28	7	,	,	PUNCT
eurjchem-2279	28	8	their	their	PRON
eurjchem-2279	28	9	arylsulfonamide	arylsulfonamide	NOUN
eurjchem-2279	28	10	and	and	CCONJ
eurjchem-2279	28	11	arylamine	arylamine	NOUN
eurjchem-2279	28	12	counterparts	counterpart	NOUN
eurjchem-2279	28	13	are	be	AUX
eurjchem-2279	28	14	widely	widely	ADV
eurjchem-2279	28	15	used	use	VERB
eurjchem-2279	28	16	in	in	ADP
eurjchem-2279	28	17	medicinal	medicinal	ADJ
eurjchem-2279	28	18	chemistry	chemistry	NOUN
eurjchem-2279	29	1	[	[	X
eurjchem-2279	29	2	14,15	14,15	NUM
eurjchem-2279	29	3	]	]	PUNCT
eurjchem-2279	29	4	.	.	PUNCT
eurjchem-2279	30	1	a	a	DET
eurjchem-2279	30	2	regioselective	regioselective	ADJ
eurjchem-2279	30	3	synthesis	synthesis	NOUN
eurjchem-2279	30	4	of	of	ADP
eurjchem-2279	30	5	these	these	DET
eurjchem-2279	30	6	molecules	molecule	NOUN
eurjchem-2279	30	7	can	can	AUX
eurjchem-2279	30	8	be	be	AUX
eurjchem-2279	30	9	carried	carry	VERB
eurjchem-2279	30	10	out	out	ADP
eurjchem-2279	30	11	via	via	ADP
eurjchem-2279	30	12	amination	amination	NOUN
eurjchem-2279	30	13	of	of	ADP
eurjchem-2279	30	14	electrophilic	electrophilic	ADJ
eurjchem-2279	30	15	arylsulfonate	arylsulfonate	NOUN
eurjchem-2279	30	16	precursors	precursor	NOUN
eurjchem-2279	30	17	.	.	PUNCT
eurjchem-2279	31	1	we	we	PRON
eurjchem-2279	31	2	aim	aim	VERB
eurjchem-2279	31	3	to	to	PART
eurjchem-2279	31	4	investigate	investigate	VERB
eurjchem-2279	31	5	the	the	DET
eurjchem-2279	31	6	effects	effect	NOUN
eurjchem-2279	31	7	of	of	ADP
eurjchem-2279	31	8	various	various	ADJ
eurjchem-2279	31	9	sulfonate	sulfonate	ADJ
eurjchem-2279	31	10	substituents	substituent	NOUN
eurjchem-2279	31	11	and	and	CCONJ
eurjchem-2279	31	12	amines	amine	NOUN
eurjchem-2279	31	13	to	to	PART
eurjchem-2279	31	14	achieve	achieve	VERB
eurjchem-2279	31	15	high	high	ADJ
eurjchem-2279	31	16	regioselectivities	regioselectivitie	NOUN
eurjchem-2279	31	17	for	for	ADP
eurjchem-2279	31	18	a	a	DET
eurjchem-2279	31	19	favorable	favorable	ADJ
eurjchem-2279	31	20	s	s	NOUN
eurjchem-2279	31	21	–	–	PUNCT
eurjchem-2279	31	22	o	o	NOUN
eurjchem-2279	31	23	or	or	CCONJ
eurjchem-2279	31	24	c	c	NOUN
eurjchem-2279	31	25	–	–	PUNCT
eurjchem-2279	31	26	o	o	NOUN
eurjchem-2279	31	27	bond	bond	NOUN
eurjchem-2279	31	28	cleavage	cleavage	NOUN
eurjchem-2279	31	29	.	.	PUNCT
eurjchem-2279	32	1	as	as	SCONJ
eurjchem-2279	32	2	the	the	DET
eurjchem-2279	32	3	title	title	NOUN
eurjchem-2279	32	4	compound	compound	NOUN
eurjchem-2279	32	5	is	be	AUX
eurjchem-2279	32	6	of	of	ADP
eurjchem-2279	32	7	interest	interest	NOUN
eurjchem-2279	32	8	in	in	ADP
eurjchem-2279	32	9	this	this	DET
eurjchem-2279	32	10	ongoing	ongoing	ADJ
eurjchem-2279	32	11	investigation	investigation	NOUN
eurjchem-2279	32	12	,	,	PUNCT
eurjchem-2279	32	13	we	we	PRON
eurjchem-2279	32	14	report	report	VERB
eurjchem-2279	32	15	herein	herein	VERB
eurjchem-2279	32	16	the	the	DET
eurjchem-2279	32	17	synthesis	synthesis	NOUN
eurjchem-2279	32	18	and	and	CCONJ
eurjchem-2279	32	19	crystallographic	crystallographic	ADJ
eurjchem-2279	32	20	characterrization	characterrization	NOUN
eurjchem-2279	32	21	of	of	ADP
eurjchem-2279	32	22	this	this	DET
eurjchem-2279	32	23	electrophilic	electrophilic	ADJ
eurjchem-2279	32	24	arylsulfonate	arylsulfonate	NOUN
eurjchem-2279	32	25	.	.	PUNCT
eurjchem-2279	33	1	2	2	X
eurjchem-2279	33	2	.	.	X
eurjchem-2279	33	3	experimental	experimental	ADJ
eurjchem-2279	33	4	2.1	2.1	NUM
eurjchem-2279	33	5	.	.	PUNCT
eurjchem-2279	33	6	instrumentation	instrumentation	NOUN
eurjchem-2279	33	7	and	and	CCONJ
eurjchem-2279	33	8	materials	material	NOUN
eurjchem-2279	33	9	reagents	reagent	NOUN
eurjchem-2279	33	10	were	be	AUX
eurjchem-2279	33	11	obtained	obtain	VERB
eurjchem-2279	33	12	from	from	ADP
eurjchem-2279	33	13	commercial	commercial	ADJ
eurjchem-2279	33	14	sources	source	NOUN
eurjchem-2279	33	15	and	and	CCONJ
eurjchem-2279	33	16	used	use	VERB
eurjchem-2279	33	17	without	without	ADP
eurjchem-2279	33	18	further	further	ADJ
eurjchem-2279	33	19	purification	purification	NOUN
eurjchem-2279	33	20	.	.	PUNCT
eurjchem-2279	34	1	thin	thin	ADJ
eurjchem-2279	34	2	-	-	PUNCT
eurjchem-2279	34	3	layer	layer	NOUN
eurjchem-2279	34	4	chromatography	chromatography	NOUN
eurjchem-2279	34	5	(	(	PUNCT
eurjchem-2279	34	6	tlc	tlc	NOUN
eurjchem-2279	34	7	)	)	PUNCT
eurjchem-2279	34	8	was	be	AUX
eurjchem-2279	34	9	used	use	VERB
eurjchem-2279	34	10	to	to	PART
eurjchem-2279	34	11	track	track	VERB
eurjchem-2279	34	12	reaction	reaction	NOUN
eurjchem-2279	34	13	progress	progress	NOUN
eurjchem-2279	34	14	and	and	CCONJ
eurjchem-2279	34	15	obtain	obtain	VERB
eurjchem-2279	34	16	rf	rf	NUM
eurjchem-2279	34	17	values	value	NOUN
eurjchem-2279	34	18	for	for	ADP
eurjchem-2279	34	19	the	the	DET
eurjchem-2279	34	20	reactions	reaction	NOUN
eurjchem-2279	34	21	.	.	PUNCT
eurjchem-2279	35	1	1h	1h	NUM
eurjchem-2279	35	2	nmr	nmr	PROPN
eurjchem-2279	35	3	spectra	spectra	NOUN
eurjchem-2279	35	4	(	(	PUNCT
eurjchem-2279	35	5	400	400	NUM
eurjchem-2279	35	6	mhz	mhz	NOUN
eurjchem-2279	35	7	)	)	PUNCT
eurjchem-2279	35	8	were	be	AUX
eurjchem-2279	35	9	recorded	record	VERB
eurjchem-2279	35	10	on	on	ADP
eurjchem-2279	35	11	a	a	DET
eurjchem-2279	35	12	jeol	jeol	ADJ
eurjchem-2279	35	13	ecz400	ecz400	NOUN
eurjchem-2279	35	14	spectrometer	spectrometer	NOUN
eurjchem-2279	35	15	using	use	VERB
eurjchem-2279	35	16	a	a	DET
eurjchem-2279	35	17	chloroform	chloroform	NOUN
eurjchem-2279	35	18	-	-	PUNCT
eurjchem-2279	35	19	d	d	NOUN
eurjchem-2279	35	20	solvent	solvent	NOUN
eurjchem-2279	35	21	.	.	PUNCT
eurjchem-2279	36	1	chemical	chemical	ADJ
eurjchem-2279	36	2	shifts	shift	NOUN
eurjchem-2279	36	3	are	be	AUX
eurjchem-2279	36	4	reported	report	VERB
eurjchem-2279	36	5	in	in	ADP
eurjchem-2279	36	6	parts	part	NOUN
eurjchem-2279	36	7	per	per	ADP
eurjchem-2279	36	8	million	million	NUM
eurjchem-2279	36	9	(	(	PUNCT
eurjchem-2279	36	10	ppm	ppm	PROPN
eurjchem-2279	36	11	,	,	PUNCT
eurjchem-2279	36	12	δ	δ	NOUN
eurjchem-2279	36	13	)	)	PUNCT
eurjchem-2279	36	14	relative	relative	ADJ
eurjchem-2279	36	15	to	to	ADP
eurjchem-2279	36	16	the	the	DET
eurjchem-2279	36	17	residual	residual	ADJ
eurjchem-2279	36	18	solvent	solvent	NOUN
eurjchem-2279	36	19	peak	peak	NOUN
eurjchem-2279	36	20	,	,	PUNCT
eurjchem-2279	36	21	and	and	CCONJ
eurjchem-2279	36	22	coupling	couple	VERB
eurjchem-2279	36	23	constants	constant	NOUN
eurjchem-2279	36	24	(	(	PUNCT
eurjchem-2279	36	25	j	j	NOUN
eurjchem-2279	36	26	)	)	PUNCT
eurjchem-2279	36	27	are	be	AUX
eurjchem-2279	36	28	reported	report	VERB
eurjchem-2279	36	29	in	in	ADP
eurjchem-2279	36	30	hertz	hertz	NOUN
eurjchem-2279	36	31	(	(	PUNCT
eurjchem-2279	36	32	hz	hz	PROPN
eurjchem-2279	36	33	)	)	PUNCT
eurjchem-2279	36	34	.	.	PUNCT
eurjchem-2279	37	1	results	result	NOUN
eurjchem-2279	37	2	were	be	AUX
eurjchem-2279	37	3	analyzed	analyze	VERB
eurjchem-2279	37	4	,	,	PUNCT
eurjchem-2279	37	5	and	and	CCONJ
eurjchem-2279	37	6	figures	figure	NOUN
eurjchem-2279	37	7	were	be	AUX
eurjchem-2279	37	8	created	create	VERB
eurjchem-2279	37	9	with	with	ADP
eurjchem-2279	37	10	the	the	DET
eurjchem-2279	37	11	use	use	NOUN
eurjchem-2279	37	12	of	of	ADP
eurjchem-2279	37	13	mestrenov	mestrenov	NOUN
eurjchem-2279	38	1	[	[	X
eurjchem-2279	38	2	16	16	NUM
eurjchem-2279	38	3	]	]	PUNCT
eurjchem-2279	38	4	.	.	PUNCT
eurjchem-2279	39	1	2.2	2.2	NUM
eurjchem-2279	39	2	.	.	PUNCT
eurjchem-2279	40	1	synthesis	synthesis	VERB
eurjchem-2279	40	2	the	the	DET
eurjchem-2279	40	3	title	title	NOUN
eurjchem-2279	40	4	compound	compound	NOUN
eurjchem-2279	40	5	was	be	AUX
eurjchem-2279	40	6	prepared	prepare	VERB
eurjchem-2279	40	7	via	via	ADP
eurjchem-2279	40	8	a	a	DET
eurjchem-2279	40	9	dropwise	dropwise	NOUN
eurjchem-2279	40	10	addition	addition	NOUN
eurjchem-2279	40	11	of	of	ADP
eurjchem-2279	40	12	2,4	2,4	NUM
eurjchem-2279	40	13	-	-	PUNCT
eurjchem-2279	40	14	dinitrophenol	dinitrophenol	NOUN
eurjchem-2279	40	15	(	(	PUNCT
eurjchem-2279	40	16	2.02	2.02	NUM
eurjchem-2279	40	17	g	g	NOUN
eurjchem-2279	40	18	,	,	PUNCT
eurjchem-2279	40	19	11.0	11.0	NUM
eurjchem-2279	40	20	mmol	mmol	NOUN
eurjchem-2279	40	21	)	)	PUNCT
eurjchem-2279	40	22	to	to	ADP
eurjchem-2279	40	23	a	a	DET
eurjchem-2279	40	24	stirred	stirred	ADJ
eurjchem-2279	40	25	mixture	mixture	NOUN
eurjchem-2279	40	26	of	of	ADP
eurjchem-2279	40	27	2,4,6	2,4,6	NUM
eurjchem-2279	40	28	-	-	PUNCT
eurjchem-2279	40	29	trimethylsulfonyl	trimethylsulfonyl	ADJ
eurjchem-2279	40	30	chloride	chloride	NOUN
eurjchem-2279	40	31	(	(	PUNCT
eurjchem-2279	40	32	1.00	1.00	NUM
eurjchem-2279	40	33	g	g	NOUN
eurjchem-2279	40	34	,	,	PUNCT
eurjchem-2279	40	35	4.58	4.58	NUM
eurjchem-2279	40	36	mmol	mmol	NOUN
eurjchem-2279	40	37	)	)	PUNCT
eurjchem-2279	40	38	in	in	ADP
eurjchem-2279	40	39	10	10	NUM
eurjchem-2279	40	40	ml	ml	NOUN
eurjchem-2279	40	41	of	of	ADP
eurjchem-2279	40	42	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-2279	40	43	.	.	PUNCT
eurjchem-2279	41	1	abstract	abstract	ADJ
eurjchem-2279	41	2	research	research	NOUN
eurjchem-2279	41	3	article	article	NOUN
eurjchem-2279	41	4	keywords	keyword	VERB
eurjchem-2279	41	5	https://dx.doi.org/10.5155/eurjchem.13.2.145-150.2279	https://dx.doi.org/10.5155/eurjchem.13.2.145-150.2279	ADV
eurjchem-2279	41	6	https://www.eurjchem.com/	https://www.eurjchem.com/	VERB
eurjchem-2279	41	7	https://dx.doi.org/10.5155/eurjchem.13.2.145-150.2279	https://dx.doi.org/10.5155/eurjchem.13.2.145-150.2279	PROPN
eurjchem-2279	41	8	mailto:ngassaf@gvsu.edu	mailto:ngassaf@gvsu.edu	PROPN
eurjchem-2279	41	9	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2279	41	10	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.13.2.145-150.2279&domain=pdf&date_stamp=2022-06-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.13.2.145-150.2279&domain=pdf&date_stamp=2022-06-30	PROPN
eurjchem-2279	41	11	146	146	NUM
eurjchem-2279	41	12	stenfors	stenfor	NOUN
eurjchem-2279	41	13	and	and	CCONJ
eurjchem-2279	41	14	ngassa	ngassa	NOUN
eurjchem-2279	41	15	/	/	SYM
eurjchem-2279	41	16	european	european	ADJ
eurjchem-2279	41	17	journal	journal	PROPN
eurjchem-2279	41	18	of	of	ADP
eurjchem-2279	41	19	chemistry	chemistry	NOUN
eurjchem-2279	41	20	13	13	NUM
eurjchem-2279	41	21	(	(	PUNCT
eurjchem-2279	41	22	2	2	NUM
eurjchem-2279	41	23	)	)	PUNCT
eurjchem-2279	41	24	(	(	PUNCT
eurjchem-2279	41	25	2022	2022	NUM
eurjchem-2279	41	26	)	)	PUNCT
eurjchem-2279	41	27	145	145	NUM
eurjchem-2279	41	28	-	-	SYM
eurjchem-2279	41	29	150	150	NUM
eurjchem-2279	41	30	2022	2022	NUM
eurjchem-2279	41	31	–	–	PUNCT
eurjchem-2279	41	32	european	european	ADJ
eurjchem-2279	41	33	journal	journal	NOUN
eurjchem-2279	41	34	of	of	ADP
eurjchem-2279	41	35	chemistry	chemistry	NOUN
eurjchem-2279	41	36	–	–	PUNCT
eurjchem-2279	41	37	cc	cc	NOUN
eurjchem-2279	41	38	by	by	ADP
eurjchem-2279	41	39	nc	nc	PROPN
eurjchem-2279	41	40	–	–	PUNCT
eurjchem-2279	41	41	doi	doi	NOUN
eurjchem-2279	41	42	:	:	PUNCT
eurjchem-2279	41	43	10.5155	10.5155	NUM
eurjchem-2279	41	44	/	/	SYM
eurjchem-2279	41	45	eurjchem.13.2.145	eurjchem.13.2.145	NUM
eurjchem-2279	41	46	-	-	PUNCT
eurjchem-2279	41	47	150.2279	150.2279	NUM
eurjchem-2279	41	48	table	table	NOUN
eurjchem-2279	41	49	1	1	NUM
eurjchem-2279	41	50	.	.	PUNCT
eurjchem-2279	42	1	crystal	crystal	NOUN
eurjchem-2279	42	2	data	datum	NOUN
eurjchem-2279	42	3	and	and	CCONJ
eurjchem-2279	42	4	details	detail	NOUN
eurjchem-2279	42	5	of	of	ADP
eurjchem-2279	42	6	the	the	DET
eurjchem-2279	42	7	structure	structure	NOUN
eurjchem-2279	42	8	refinement	refinement	NOUN
eurjchem-2279	42	9	for	for	ADP
eurjchem-2279	42	10	the	the	DET
eurjchem-2279	42	11	title	title	NOUN
eurjchem-2279	42	12	compound	compound	NOUN
eurjchem-2279	42	13	.	.	PUNCT
eurjchem-2279	43	1	parameters	parameter	NOUN
eurjchem-2279	43	2	empirical	empirical	ADJ
eurjchem-2279	43	3	formula	formula	NOUN
eurjchem-2279	43	4	c15h14n2o7s	c15h14n2o7s	NOUN
eurjchem-2279	43	5	formula	formula	NOUN
eurjchem-2279	43	6	weight	weight	NOUN
eurjchem-2279	43	7	366.34	366.34	NUM
eurjchem-2279	43	8	temperature	temperature	NOUN
eurjchem-2279	43	9	(	(	PUNCT
eurjchem-2279	43	10	k	k	NOUN
eurjchem-2279	43	11	)	)	PUNCT
eurjchem-2279	43	12	173.15	173.15	NUM
eurjchem-2279	43	13	crystal	crystal	NOUN
eurjchem-2279	43	14	system	system	NOUN
eurjchem-2279	43	15	monoclinic	monoclinic	ADJ
eurjchem-2279	43	16	space	space	NOUN
eurjchem-2279	43	17	group	group	NOUN
eurjchem-2279	43	18	p21	p21	PROPN
eurjchem-2279	43	19	/	/	SYM
eurjchem-2279	43	20	c	c	PROPN
eurjchem-2279	43	21	a	a	PRON
eurjchem-2279	43	22	,	,	PUNCT
eurjchem-2279	43	23	(	(	PUNCT
eurjchem-2279	43	24	å	å	NOUN
eurjchem-2279	43	25	)	)	PUNCT
eurjchem-2279	43	26	6.8773(10	6.8773(10	NUM
eurjchem-2279	43	27	)	)	PUNCT
eurjchem-2279	43	28	b	b	NOUN
eurjchem-2279	43	29	,	,	PUNCT
eurjchem-2279	43	30	(	(	PUNCT
eurjchem-2279	43	31	å	å	NOUN
eurjchem-2279	43	32	)	)	PUNCT
eurjchem-2279	43	33	8.9070(14	8.9070(14	NUM
eurjchem-2279	43	34	)	)	PUNCT
eurjchem-2279	43	35	c	c	NOUN
eurjchem-2279	43	36	,	,	PUNCT
eurjchem-2279	43	37	(	(	PUNCT
eurjchem-2279	43	38	å	å	NOUN
eurjchem-2279	43	39	)	)	PUNCT
eurjchem-2279	43	40	25.557(4	25.557(4	NUM
eurjchem-2279	43	41	)	)	PUNCT
eurjchem-2279	44	1	α	α	PROPN
eurjchem-2279	44	2	(	(	PUNCT
eurjchem-2279	44	3	°	°	PROPN
eurjchem-2279	44	4	)	)	PUNCT
eurjchem-2279	44	5	90	90	NUM
eurjchem-2279	44	6	β	β	X
eurjchem-2279	44	7	(	(	PUNCT
eurjchem-2279	44	8	°	°	PROPN
eurjchem-2279	44	9	)	)	PUNCT
eurjchem-2279	44	10	93.0630(18	93.0630(18	NUM
eurjchem-2279	44	11	)	)	PUNCT
eurjchem-2279	44	12	γ	γ	PROPN
eurjchem-2279	44	13	(	(	PUNCT
eurjchem-2279	44	14	°	°	PROPN
eurjchem-2279	44	15	)	)	PUNCT
eurjchem-2279	44	16	90	90	NUM
eurjchem-2279	44	17	volume	volume	NOUN
eurjchem-2279	44	18	(	(	PUNCT
eurjchem-2279	44	19	å3	å3	PROPN
eurjchem-2279	44	20	)	)	PUNCT
eurjchem-2279	44	21	1563.3(4	1563.3(4	NOUN
eurjchem-2279	44	22	)	)	PUNCT
eurjchem-2279	44	23	z	z	NOUN
eurjchem-2279	44	24	4	4	NUM
eurjchem-2279	44	25	ρcalc	ρcalc	NOUN
eurjchem-2279	44	26	(	(	PUNCT
eurjchem-2279	44	27	g	g	NOUN
eurjchem-2279	44	28	/	/	SYM
eurjchem-2279	44	29	cm3	cm3	NOUN
eurjchem-2279	44	30	)	)	PUNCT
eurjchem-2279	44	31	1.557	1.557	NUM
eurjchem-2279	44	32	μ	μ	NOUN
eurjchem-2279	44	33	(	(	PUNCT
eurjchem-2279	44	34	mm-1	mm-1	NOUN
eurjchem-2279	44	35	)	)	PUNCT
eurjchem-2279	44	36	0.251	0.251	NUM
eurjchem-2279	44	37	f(000	f(000	PROPN
eurjchem-2279	44	38	)	)	PUNCT
eurjchem-2279	44	39	760.0	760.0	NUM
eurjchem-2279	44	40	crystal	crystal	NOUN
eurjchem-2279	44	41	size	size	NOUN
eurjchem-2279	44	42	(	(	PUNCT
eurjchem-2279	44	43	mm3	mm3	PROPN
eurjchem-2279	44	44	)	)	PUNCT
eurjchem-2279	44	45	0.216	0.216	NUM
eurjchem-2279	44	46	×	×	NOUN
eurjchem-2279	44	47	0.138	0.138	NUM
eurjchem-2279	44	48	×	×	NOUN
eurjchem-2279	44	49	0.117	0.117	NUM
eurjchem-2279	44	50	radiation	radiation	NOUN
eurjchem-2279	44	51	mokα	mokα	NOUN
eurjchem-2279	44	52	(	(	PUNCT
eurjchem-2279	44	53	λ	λ	X
eurjchem-2279	44	54	=	=	SYM
eurjchem-2279	44	55	0.71073	0.71073	NUM
eurjchem-2279	44	56	)	)	PUNCT
eurjchem-2279	44	57	2θ	2θ	NUM
eurjchem-2279	44	58	range	range	VERB
eurjchem-2279	44	59	for	for	ADP
eurjchem-2279	44	60	data	data	NOUN
eurjchem-2279	44	61	collection	collection	NOUN
eurjchem-2279	44	62	(	(	PUNCT
eurjchem-2279	44	63	°	°	PROPN
eurjchem-2279	44	64	)	)	PUNCT
eurjchem-2279	44	65	3.192	3.192	NUM
eurjchem-2279	44	66	to	to	ADP
eurjchem-2279	44	67	50.682	50.682	NUM
eurjchem-2279	44	68	index	index	NOUN
eurjchem-2279	44	69	ranges	range	VERB
eurjchem-2279	44	70	-8	-8	ADJ
eurjchem-2279	44	71	≤	≤	NUM
eurjchem-2279	44	72	h	h	NOUN
eurjchem-2279	44	73	≤	≤	NOUN
eurjchem-2279	44	74	8	8	NUM
eurjchem-2279	44	75	,	,	PUNCT
eurjchem-2279	44	76	-10	-10	PUNCT
eurjchem-2279	44	77	≤	≤	NUM
eurjchem-2279	45	1	k	k	X
eurjchem-2279	45	2	≤	≤	NUM
eurjchem-2279	45	3	10	10	NUM
eurjchem-2279	45	4	,	,	PUNCT
eurjchem-2279	45	5	-30	-30	SYM
eurjchem-2279	45	6	≤	≤	NUM
eurjchem-2279	45	7	l	l	NOUN
eurjchem-2279	45	8	≤	≤	NUM
eurjchem-2279	45	9	30	30	NUM
eurjchem-2279	45	10	reflections	reflection	NOUN
eurjchem-2279	45	11	collected	collect	VERB
eurjchem-2279	45	12	12259	12259	NUM
eurjchem-2279	45	13	independent	independent	ADJ
eurjchem-2279	45	14	reflections	reflection	NOUN
eurjchem-2279	45	15	2861	2861	NUM
eurjchem-2279	46	1	[	[	X
eurjchem-2279	46	2	rint	rint	X
eurjchem-2279	46	3	=	=	SYM
eurjchem-2279	46	4	0.0493	0.0493	NUM
eurjchem-2279	46	5	,	,	PUNCT
eurjchem-2279	46	6	rsigma	rsigma	ADJ
eurjchem-2279	46	7	=	=	SYM
eurjchem-2279	46	8	0.0419	0.0419	NUM
eurjchem-2279	46	9	]	]	X
eurjchem-2279	46	10	data	data	NOUN
eurjchem-2279	46	11	/	/	SYM
eurjchem-2279	46	12	restraints	restraint	NOUN
eurjchem-2279	46	13	/	/	SYM
eurjchem-2279	46	14	parameters	parameter	NOUN
eurjchem-2279	46	15	2861/0/229	2861/0/229	NUM
eurjchem-2279	46	16	goodness	goodness	NOUN
eurjchem-2279	46	17	-	-	PUNCT
eurjchem-2279	46	18	of	of	ADP
eurjchem-2279	46	19	-	-	PUNCT
eurjchem-2279	46	20	fit	fit	NOUN
eurjchem-2279	46	21	on	on	ADP
eurjchem-2279	46	22	f2	f2	PROPN
eurjchem-2279	46	23	1.050	1.050	NUM
eurjchem-2279	46	24	final	final	ADJ
eurjchem-2279	46	25	r	r	NOUN
eurjchem-2279	46	26	indexes	index	NOUN
eurjchem-2279	46	27	[	[	X
eurjchem-2279	46	28	i≥2σ	i≥2σ	X
eurjchem-2279	46	29	(	(	PUNCT
eurjchem-2279	46	30	i	i	NOUN
eurjchem-2279	46	31	)	)	PUNCT
eurjchem-2279	46	32	]	]	PUNCT
eurjchem-2279	46	33	r1	r1	PROPN
eurjchem-2279	46	34	=	=	PUNCT
eurjchem-2279	46	35	0.0457	0.0457	NUM
eurjchem-2279	46	36	,	,	PUNCT
eurjchem-2279	46	37	wr2	wr2	PROPN
eurjchem-2279	46	38	=	=	NOUN
eurjchem-2279	46	39	0.1146	0.1146	NUM
eurjchem-2279	46	40	final	final	ADJ
eurjchem-2279	46	41	r	r	NOUN
eurjchem-2279	46	42	indexes	index	NOUN
eurjchem-2279	46	43	[	[	X
eurjchem-2279	46	44	all	all	DET
eurjchem-2279	46	45	data	datum	NOUN
eurjchem-2279	46	46	]	]	PUNCT
eurjchem-2279	46	47	r1	r1	NOUN
eurjchem-2279	46	48	=	=	PUNCT
eurjchem-2279	46	49	0.0659	0.0659	NUM
eurjchem-2279	46	50	,	,	PUNCT
eurjchem-2279	46	51	wr2	wr2	PROPN
eurjchem-2279	46	52	=	=	PROPN
eurjchem-2279	46	53	0.1306	0.1306	NUM
eurjchem-2279	47	1	largest	large	ADJ
eurjchem-2279	47	2	diff	diff	NOUN
eurjchem-2279	47	3	.	.	PUNCT
eurjchem-2279	47	4	peak	peak	PROPN
eurjchem-2279	47	5	/	/	SYM
eurjchem-2279	47	6	hole	hole	NOUN
eurjchem-2279	47	7	(	(	PUNCT
eurjchem-2279	47	8	e.å-3	e.å-3	PROPN
eurjchem-2279	47	9	)	)	PUNCT
eurjchem-2279	47	10	0.34/-0.38	0.34/-0.38	X
eurjchem-2279	47	11	s	s	PART
eurjchem-2279	47	12	r1	r1	NOUN
eurjchem-2279	48	1	o	o	NOUN
eurjchem-2279	48	2	o	o	X
eurjchem-2279	48	3	o	o	X
eurjchem-2279	48	4	r3	r3	PROPN
eurjchem-2279	48	5	h	h	NOUN
eurjchem-2279	48	6	n	n	PRON
eurjchem-2279	48	7	r4	r4	PROPN
eurjchem-2279	48	8	s	s	PART
eurjchem-2279	48	9	r1	r1	NOUN
eurjchem-2279	48	10	o	o	NOUN
eurjchem-2279	48	11	o	o	X
eurjchem-2279	48	12	n	n	CCONJ
eurjchem-2279	48	13	r3	r3	PROPN
eurjchem-2279	48	14	r4	r4	NOUN
eurjchem-2279	48	15	+	+	CCONJ
eurjchem-2279	48	16	competing	compete	VERB
eurjchem-2279	48	17	regioselectivity	regioselectivity	NOUN
eurjchem-2279	48	18	r2	r2	PROPN
eurjchem-2279	48	19	n	n	ADP
eurjchem-2279	48	20	r4	r4	PROPN
eurjchem-2279	48	21	r3	r3	PROPN
eurjchem-2279	48	22	(	(	PUNCT
eurjchem-2279	48	23	ii	ii	NOUN
eurjchem-2279	48	24	)	)	PUNCT
eurjchem-2279	48	25	(	(	PUNCT
eurjchem-2279	48	26	iii)(i	iii)(i	NOUN
eurjchem-2279	48	27	)	)	PUNCT
eurjchem-2279	48	28	s	s	NOUN
eurjchem-2279	48	29	-	-	PUNCT
eurjchem-2279	48	30	o	o	NOUN
eurjchem-2279	48	31	/	/	SYM
eurjchem-2279	48	32	c	c	NOUN
eurjchem-2279	48	33	-	-	PUNCT
eurjchem-2279	48	34	o	o	NOUN
eurjchem-2279	48	35	cleavage	cleavage	NOUN
eurjchem-2279	48	36	r2	r2	PROPN
eurjchem-2279	48	37	scheme	scheme	NOUN
eurjchem-2279	48	38	1	1	NUM
eurjchem-2279	48	39	.	.	PUNCT
eurjchem-2279	48	40	general	general	ADJ
eurjchem-2279	48	41	reaction	reaction	NOUN
eurjchem-2279	48	42	for	for	ADP
eurjchem-2279	48	43	the	the	DET
eurjchem-2279	48	44	regioselective	regioselective	ADJ
eurjchem-2279	48	45	s	s	NOUN
eurjchem-2279	48	46	–	–	PUNCT
eurjchem-2279	48	47	o	o	NOUN
eurjchem-2279	48	48	/	/	SYM
eurjchem-2279	48	49	c	c	PROPN
eurjchem-2279	48	50	–	–	PUNCT
eurjchem-2279	48	51	o	o	NOUN
eurjchem-2279	48	52	bond	bond	NOUN
eurjchem-2279	48	53	cleavage	cleavage	NOUN
eurjchem-2279	48	54	of	of	ADP
eurjchem-2279	48	55	arylsulfonate	arylsulfonate	NOUN
eurjchem-2279	48	56	(	(	PUNCT
eurjchem-2279	48	57	i	i	NOUN
eurjchem-2279	48	58	)	)	PUNCT
eurjchem-2279	48	59	in	in	ADP
eurjchem-2279	48	60	the	the	DET
eurjchem-2279	48	61	presence	presence	NOUN
eurjchem-2279	48	62	of	of	ADP
eurjchem-2279	48	63	nucleophilic	nucleophilic	ADJ
eurjchem-2279	48	64	amine	amine	NOUN
eurjchem-2279	48	65	to	to	PART
eurjchem-2279	48	66	afford	afford	VERB
eurjchem-2279	48	67	the	the	DET
eurjchem-2279	48	68	corresponding	corresponding	ADJ
eurjchem-2279	48	69	arylsulfonamide	arylsulfonamide	NOUN
eurjchem-2279	48	70	(	(	PUNCT
eurjchem-2279	48	71	ii	ii	NOUN
eurjchem-2279	48	72	)	)	PUNCT
eurjchem-2279	48	73	and	and	CCONJ
eurjchem-2279	48	74	arylamine	arylamine	NOUN
eurjchem-2279	48	75	(	(	PUNCT
eurjchem-2279	48	76	iii	iii	NOUN
eurjchem-2279	48	77	)	)	PUNCT
eurjchem-2279	48	78	.	.	PUNCT
eurjchem-2279	49	1	following	follow	VERB
eurjchem-2279	49	2	another	another	DET
eurjchem-2279	49	3	dropwise	dropwise	NOUN
eurjchem-2279	49	4	addition	addition	NOUN
eurjchem-2279	49	5	of	of	ADP
eurjchem-2279	49	6	aqueous	aqueous	ADJ
eurjchem-2279	49	7	potassium	potassium	NOUN
eurjchem-2279	49	8	carbonate	carbonate	NOUN
eurjchem-2279	49	9	(	(	PUNCT
eurjchem-2279	49	10	10	10	NUM
eurjchem-2279	49	11	ml	ml	NOUN
eurjchem-2279	49	12	,	,	PUNCT
eurjchem-2279	49	13	0.915	0.915	NUM
eurjchem-2279	49	14	m	m	NOUN
eurjchem-2279	49	15	)	)	PUNCT
eurjchem-2279	49	16	,	,	PUNCT
eurjchem-2279	49	17	the	the	DET
eurjchem-2279	49	18	mixture	mixture	NOUN
eurjchem-2279	49	19	was	be	AUX
eurjchem-2279	49	20	left	leave	VERB
eurjchem-2279	49	21	to	to	PART
eurjchem-2279	49	22	stir	stir	VERB
eurjchem-2279	49	23	for	for	ADP
eurjchem-2279	49	24	24	24	NUM
eurjchem-2279	49	25	h	h	NOUN
eurjchem-2279	49	26	at	at	ADP
eurjchem-2279	49	27	room	room	NOUN
eurjchem-2279	49	28	temperature	temperature	NOUN
eurjchem-2279	49	29	.	.	PUNCT
eurjchem-2279	50	1	after	after	ADP
eurjchem-2279	50	2	dilution	dilution	NOUN
eurjchem-2279	50	3	with	with	ADP
eurjchem-2279	50	4	15	15	NUM
eurjchem-2279	50	5	ml	ml	NOUN
eurjchem-2279	50	6	of	of	ADP
eurjchem-2279	50	7	dichloromethane	dichloromethane	NOUN
eurjchem-2279	50	8	,	,	PUNCT
eurjchem-2279	50	9	the	the	DET
eurjchem-2279	50	10	reaction	reaction	NOUN
eurjchem-2279	50	11	mixture	mixture	NOUN
eurjchem-2279	50	12	was	be	AUX
eurjchem-2279	50	13	washed	wash	VERB
eurjchem-2279	50	14	with	with	ADP
eurjchem-2279	50	15	water	water	NOUN
eurjchem-2279	50	16	(	(	PUNCT
eurjchem-2279	50	17	3×10	3×10	NUM
eurjchem-2279	50	18	ml	ml	NOUN
eurjchem-2279	50	19	)	)	PUNCT
eurjchem-2279	50	20	and	and	CCONJ
eurjchem-2279	50	21	the	the	DET
eurjchem-2279	50	22	aqueous	aqueous	ADJ
eurjchem-2279	50	23	layers	layer	NOUN
eurjchem-2279	50	24	back	back	ADV
eurjchem-2279	50	25	extracted	extract	VERB
eurjchem-2279	50	26	with	with	ADP
eurjchem-2279	50	27	10	10	NUM
eurjchem-2279	50	28	ml	ml	NOUN
eurjchem-2279	50	29	of	of	ADP
eurjchem-2279	50	30	dichloromethane	dichloromethane	NOUN
eurjchem-2279	50	31	.	.	PUNCT
eurjchem-2279	51	1	the	the	DET
eurjchem-2279	51	2	organic	organic	ADJ
eurjchem-2279	51	3	layers	layer	NOUN
eurjchem-2279	51	4	were	be	AUX
eurjchem-2279	51	5	combined	combine	VERB
eurjchem-2279	51	6	,	,	PUNCT
eurjchem-2279	51	7	washed	wash	VERB
eurjchem-2279	51	8	with	with	ADP
eurjchem-2279	51	9	10	10	NUM
eurjchem-2279	51	10	ml	ml	NOUN
eurjchem-2279	51	11	of	of	ADP
eurjchem-2279	51	12	brine	brine	NOUN
eurjchem-2279	51	13	,	,	PUNCT
eurjchem-2279	51	14	dried	dry	VERB
eurjchem-2279	51	15	over	over	ADP
eurjchem-2279	51	16	anhydrous	anhydrous	ADJ
eurjchem-2279	51	17	sodium	sodium	NOUN
eurjchem-2279	51	18	sulfate	sulfate	NOUN
eurjchem-2279	51	19	,	,	PUNCT
eurjchem-2279	51	20	and	and	CCONJ
eurjchem-2279	51	21	evaporated	evaporate	VERB
eurjchem-2279	51	22	to	to	PART
eurjchem-2279	51	23	yield	yield	VERB
eurjchem-2279	51	24	a	a	DET
eurjchem-2279	51	25	crude	crude	NOUN
eurjchem-2279	51	26	,	,	PUNCT
eurjchem-2279	51	27	yellow	yellow	ADJ
eurjchem-2279	51	28	residue	residue	NOUN
eurjchem-2279	51	29	.	.	PUNCT
eurjchem-2279	52	1	recrystallization	recrystallization	NOUN
eurjchem-2279	52	2	in	in	ADP
eurjchem-2279	52	3	5	5	NUM
eurjchem-2279	52	4	ml	ml	NOUN
eurjchem-2279	52	5	of	of	ADP
eurjchem-2279	52	6	dichloromethane	dichloromethane	NOUN
eurjchem-2279	52	7	yielded	yield	VERB
eurjchem-2279	52	8	the	the	DET
eurjchem-2279	52	9	product	product	NOUN
eurjchem-2279	52	10	as	as	ADP
eurjchem-2279	52	11	large	large	ADJ
eurjchem-2279	52	12	,	,	PUNCT
eurjchem-2279	52	13	paleyellow	paleyellow	NOUN
eurjchem-2279	52	14	crystals	crystal	NOUN
eurjchem-2279	52	15	.	.	PUNCT
eurjchem-2279	53	1	2,4	2,4	NUM
eurjchem-2279	53	2	-	-	PUNCT
eurjchem-2279	53	3	dinitrophenyl	dinitrophenyl	ADJ
eurjchem-2279	53	4	2,4,6	2,4,6	NUM
eurjchem-2279	53	5	-	-	PUNCT
eurjchem-2279	53	6	trimethylbenzenesulfonate	trimethylbenzenesulfonate	NOUN
eurjchem-2279	53	7	:	:	PUNCT
eurjchem-2279	53	8	color	color	NOUN
eurjchem-2279	53	9	:	:	PUNCT
eurjchem-2279	53	10	pale	pale	ADJ
eurjchem-2279	53	11	-	-	PUNCT
eurjchem-2279	53	12	yellow	yellow	ADJ
eurjchem-2279	53	13	.	.	PUNCT
eurjchem-2279	54	1	yield	yield	NOUN
eurjchem-2279	54	2	:	:	PUNCT
eurjchem-2279	54	3	88	88	NUM
eurjchem-2279	54	4	%	%	NOUN
eurjchem-2279	54	5	.	.	PUNCT
eurjchem-2279	55	1	m.p	m.p	PROPN
eurjchem-2279	55	2	.	.	PROPN
eurjchem-2279	55	3	:	:	PUNCT
eurjchem-2279	56	1	128	128	NUM
eurjchem-2279	56	2	-	-	SYM
eurjchem-2279	56	3	132	132	NUM
eurjchem-2279	56	4	°	°	NOUN
eurjchem-2279	56	5	c	c	NOUN
eurjchem-2279	56	6	.	.	PUNCT
eurjchem-2279	57	1	rf	rf	VERB
eurjchem-2279	57	2	:	:	PUNCT
eurjchem-2279	57	3	0.86	0.86	NUM
eurjchem-2279	57	4	(	(	PUNCT
eurjchem-2279	57	5	ch2cl2	ch2cl2	NOUN
eurjchem-2279	57	6	)	)	PUNCT
eurjchem-2279	57	7	.	.	PUNCT
eurjchem-2279	58	1	1h	1h	NUM
eurjchem-2279	58	2	nmr	nmr	NOUN
eurjchem-2279	58	3	(	(	PUNCT
eurjchem-2279	58	4	400	400	NUM
eurjchem-2279	58	5	mhz	mhz	NOUN
eurjchem-2279	58	6	,	,	PUNCT
eurjchem-2279	58	7	cdcl3	cdcl3	NOUN
eurjchem-2279	58	8	,	,	PUNCT
eurjchem-2279	58	9	δ	δ	PROPN
eurjchem-2279	58	10	ppm	ppm	NOUN
eurjchem-2279	58	11	):	):	PUNCT
eurjchem-2279	58	12	8.75	8.75	NUM
eurjchem-2279	58	13	(	(	PUNCT
eurjchem-2279	58	14	d	d	PROPN
eurjchem-2279	58	15	,	,	PUNCT
eurjchem-2279	58	16	1h	1h	NUM
eurjchem-2279	58	17	,	,	PUNCT
eurjchem-2279	58	18	j	j	PROPN
eurjchem-2279	58	19	=	=	SYM
eurjchem-2279	58	20	2.8	2.8	NUM
eurjchem-2279	58	21	hz	hz	NOUN
eurjchem-2279	58	22	,	,	PUNCT
eurjchem-2279	58	23	ar	ar	NOUN
eurjchem-2279	58	24	-	-	NOUN
eurjchem-2279	58	25	h	h	NOUN
eurjchem-2279	58	26	)	)	PUNCT
eurjchem-2279	58	27	,	,	PUNCT
eurjchem-2279	58	28	8.44	8.44	NUM
eurjchem-2279	58	29	(	(	PUNCT
eurjchem-2279	58	30	dd	dd	PROPN
eurjchem-2279	58	31	,	,	PUNCT
eurjchem-2279	58	32	1h	1h	NUM
eurjchem-2279	58	33	,	,	PUNCT
eurjchem-2279	58	34	j	j	PROPN
eurjchem-2279	58	35	=	=	SYM
eurjchem-2279	58	36	9.0	9.0	NUM
eurjchem-2279	58	37	,	,	PUNCT
eurjchem-2279	58	38	2.8	2.8	NUM
eurjchem-2279	58	39	hz	hz	NOUN
eurjchem-2279	58	40	,	,	PUNCT
eurjchem-2279	58	41	ar	ar	NOUN
eurjchem-2279	58	42	-	-	NOUN
eurjchem-2279	58	43	h	h	NOUN
eurjchem-2279	58	44	)	)	PUNCT
eurjchem-2279	58	45	,	,	PUNCT
eurjchem-2279	58	46	7.58	7.58	NUM
eurjchem-2279	58	47	(	(	PUNCT
eurjchem-2279	58	48	d	d	PROPN
eurjchem-2279	58	49	,	,	PUNCT
eurjchem-2279	58	50	1h	1h	NUM
eurjchem-2279	58	51	,	,	PUNCT
eurjchem-2279	58	52	j	j	PROPN
eurjchem-2279	58	53	=	=	SYM
eurjchem-2279	58	54	9.0	9.0	NUM
eurjchem-2279	58	55	hz	hz	NOUN
eurjchem-2279	58	56	,	,	PUNCT
eurjchem-2279	58	57	ar	ar	NOUN
eurjchem-2279	58	58	-	-	NOUN
eurjchem-2279	58	59	h	h	NOUN
eurjchem-2279	58	60	)	)	PUNCT
eurjchem-2279	58	61	,	,	PUNCT
eurjchem-2279	58	62	7.03	7.03	NUM
eurjchem-2279	58	63	(	(	PUNCT
eurjchem-2279	58	64	2h	2h	NUM
eurjchem-2279	58	65	,	,	PUNCT
eurjchem-2279	58	66	s	s	X
eurjchem-2279	58	67	,	,	PUNCT
eurjchem-2279	58	68	ar	ar	NOUN
eurjchem-2279	58	69	-	-	NOUN
eurjchem-2279	58	70	h	h	NOUN
eurjchem-2279	58	71	)	)	PUNCT
eurjchem-2279	58	72	,	,	PUNCT
eurjchem-2279	58	73	2.57	2.57	NUM
eurjchem-2279	58	74	(	(	PUNCT
eurjchem-2279	58	75	6h	6h	NUM
eurjchem-2279	58	76	,	,	PUNCT
eurjchem-2279	58	77	s	s	X
eurjchem-2279	58	78	,	,	PUNCT
eurjchem-2279	58	79	bn	bn	NOUN
eurjchem-2279	58	80	-	-	PUNCT
eurjchem-2279	58	81	h	h	NOUN
eurjchem-2279	58	82	)	)	PUNCT
eurjchem-2279	58	83	,	,	PUNCT
eurjchem-2279	58	84	2.35	2.35	NUM
eurjchem-2279	58	85	(	(	PUNCT
eurjchem-2279	58	86	3h	3h	NUM
eurjchem-2279	58	87	,	,	PUNCT
eurjchem-2279	58	88	s	s	X
eurjchem-2279	58	89	,	,	PUNCT
eurjchem-2279	58	90	bn	bn	NOUN
eurjchem-2279	58	91	-	-	PUNCT
eurjchem-2279	58	92	h	h	NOUN
eurjchem-2279	58	93	)	)	PUNCT
eurjchem-2279	58	94	.	.	PUNCT
eurjchem-2279	59	1	13c	13c	NOUN
eurjchem-2279	59	2	nmr	nmr	NOUN
eurjchem-2279	59	3	(	(	PUNCT
eurjchem-2279	59	4	100	100	NUM
eurjchem-2279	59	5	mhz	mhz	NOUN
eurjchem-2279	59	6	,	,	PUNCT
eurjchem-2279	59	7	cdcl3	cdcl3	PROPN
eurjchem-2279	59	8	,	,	PUNCT
eurjchem-2279	59	9	δ	δ	PROPN
eurjchem-2279	59	10	ppm	ppm	VERB
eurjchem-2279	59	11	):	):	PUNCT
eurjchem-2279	59	12	146.12	146.12	NUM
eurjchem-2279	59	13	,	,	PUNCT
eurjchem-2279	59	14	145.70	145.70	NUM
eurjchem-2279	59	15	,	,	PUNCT
eurjchem-2279	59	16	145.16	145.16	NUM
eurjchem-2279	59	17	,	,	PUNCT
eurjchem-2279	59	18	142.95	142.95	NUM
eurjchem-2279	59	19	,	,	PUNCT
eurjchem-2279	59	20	140.84	140.84	NUM
eurjchem-2279	59	21	,	,	PUNCT
eurjchem-2279	59	22	132.39	132.39	NUM
eurjchem-2279	59	23	,	,	PUNCT
eurjchem-2279	59	24	129.55	129.55	NUM
eurjchem-2279	59	25	,	,	PUNCT
eurjchem-2279	59	26	128.57	128.57	NUM
eurjchem-2279	59	27	,	,	PUNCT
eurjchem-2279	59	28	126.21	126.21	NUM
eurjchem-2279	59	29	,	,	PUNCT
eurjchem-2279	59	30	121.62	121.62	NUM
eurjchem-2279	59	31	,	,	PUNCT
eurjchem-2279	59	32	22.87	22.87	NUM
eurjchem-2279	59	33	,	,	PUNCT
eurjchem-2279	59	34	21.34	21.34	NUM
eurjchem-2279	59	35	.	.	PUNCT
eurjchem-2279	60	1	2.3	2.3	NUM
eurjchem-2279	60	2	.	.	PUNCT
eurjchem-2279	61	1	crystallographic	crystallographic	ADJ
eurjchem-2279	61	2	characterization	characterization	NOUN
eurjchem-2279	61	3	x	x	NOUN
eurjchem-2279	61	4	-	-	NOUN
eurjchem-2279	61	5	ray	ray	NOUN
eurjchem-2279	61	6	diffraction	diffraction	NOUN
eurjchem-2279	61	7	was	be	AUX
eurjchem-2279	61	8	carried	carry	VERB
eurjchem-2279	61	9	out	out	ADP
eurjchem-2279	61	10	on	on	ADP
eurjchem-2279	61	11	a	a	DET
eurjchem-2279	61	12	bruker	bruker	NOUN
eurjchem-2279	61	13	apexii	apexii	NOUN
eurjchem-2279	61	14	ccd	ccd	PROPN
eurjchem-2279	61	15	diffractometer	diffractometer	NOUN
eurjchem-2279	61	16	with	with	ADP
eurjchem-2279	61	17	mo	mo	PROPN
eurjchem-2279	61	18	kα	kα	PROPN
eurjchem-2279	61	19	radiation	radiation	NOUN
eurjchem-2279	61	20	.	.	PUNCT
eurjchem-2279	62	1	the	the	DET
eurjchem-2279	62	2	software	software	NOUN
eurjchem-2279	62	3	used	use	VERB
eurjchem-2279	62	4	for	for	ADP
eurjchem-2279	62	5	data	datum	NOUN
eurjchem-2279	62	6	collection	collection	NOUN
eurjchem-2279	62	7	is	be	AUX
eurjchem-2279	62	8	as	as	SCONJ
eurjchem-2279	62	9	follows	follow	VERB
eurjchem-2279	62	10	:	:	PUNCT
eurjchem-2279	62	11	data	data	NOUN
eurjchem-2279	62	12	collection	collection	NOUN
eurjchem-2279	62	13	,	,	PUNCT
eurjchem-2279	62	14	apex2	apex2	PUNCT
eurjchem-2279	63	1	[	[	X
eurjchem-2279	63	2	17	17	NUM
eurjchem-2279	63	3	]	]	X
eurjchem-2279	63	4	;	;	PUNCT
eurjchem-2279	63	5	cell	cell	NOUN
eurjchem-2279	63	6	refinement	refinement	NOUN
eurjchem-2279	63	7	and	and	CCONJ
eurjchem-2279	63	8	data	datum	NOUN
eurjchem-2279	63	9	reduction	reduction	NOUN
eurjchem-2279	63	10	,	,	PUNCT
eurjchem-2279	63	11	saint	saint	PROPN
eurjchem-2279	64	1	[	[	X
eurjchem-2279	64	2	18	18	NUM
eurjchem-2279	64	3	]	]	X
eurjchem-2279	64	4	;	;	PUNCT
eurjchem-2279	64	5	program	program	NOUN
eurjchem-2279	64	6	used	use	VERB
eurjchem-2279	64	7	to	to	PART
eurjchem-2279	64	8	refine	refine	VERB
eurjchem-2279	64	9	the	the	DET
eurjchem-2279	64	10	structure	structure	NOUN
eurjchem-2279	64	11	,	,	PUNCT
eurjchem-2279	64	12	shelxl	shelxl	VERB
eurjchem-2279	64	13	[	[	X
eurjchem-2279	64	14	19	19	NUM
eurjchem-2279	64	15	]	]	PUNCT
eurjchem-2279	64	16	;	;	PUNCT
eurjchem-2279	64	17	program	program	NOUN
eurjchem-2279	64	18	used	use	VERB
eurjchem-2279	64	19	to	to	PART
eurjchem-2279	64	20	solve	solve	VERB
eurjchem-2279	64	21	the	the	DET
eurjchem-2279	64	22	structure	structure	NOUN
eurjchem-2279	64	23	,	,	PUNCT
eurjchem-2279	64	24	shelxs	shelx	VERB
eurjchem-2279	65	1	[	[	PUNCT
eurjchem-2279	65	2	20	20	NUM
eurjchem-2279	65	3	]	]	PUNCT
eurjchem-2279	65	4	;	;	PUNCT
eurjchem-2279	65	5	molecular	molecular	ADJ
eurjchem-2279	65	6	graphics	graphic	NOUN
eurjchem-2279	65	7	and	and	CCONJ
eurjchem-2279	65	8	publication	publication	NOUN
eurjchem-2279	65	9	material	material	NOUN
eurjchem-2279	65	10	,	,	PUNCT
eurjchem-2279	65	11	olex2	olex2	PROPN
eurjchem-2279	66	1	[	[	X
eurjchem-2279	66	2	21,22	21,22	X
eurjchem-2279	66	3	]	]	X
eurjchem-2279	66	4	;	;	PUNCT
eurjchem-2279	66	5	program	program	NOUN
eurjchem-2279	66	6	used	use	VERB
eurjchem-2279	66	7	to	to	PART
eurjchem-2279	66	8	generate	generate	VERB
eurjchem-2279	66	9	figures	figure	NOUN
eurjchem-2279	66	10	,	,	PUNCT
eurjchem-2279	66	11	mercury	mercury	NOUN
eurjchem-2279	67	1	[	[	X
eurjchem-2279	67	2	23	23	NUM
eurjchem-2279	67	3	-	-	SYM
eurjchem-2279	67	4	27	27	NUM
eurjchem-2279	67	5	]	]	PUNCT
eurjchem-2279	67	6	;	;	PUNCT
eurjchem-2279	67	7	absorbance	absorbance	NOUN
eurjchem-2279	67	8	correction	correction	NOUN
eurjchem-2279	67	9	,	,	PUNCT
eurjchem-2279	67	10	sadabs	sadab	VERB
eurjchem-2279	68	1	[	[	X
eurjchem-2279	68	2	28	28	NUM
eurjchem-2279	68	3	]	]	PUNCT
eurjchem-2279	68	4	.	.	PUNCT
eurjchem-2279	69	1	3	3	X
eurjchem-2279	69	2	.	.	NOUN
eurjchem-2279	69	3	results	result	NOUN
eurjchem-2279	69	4	and	and	CCONJ
eurjchem-2279	69	5	discussion	discussion	NOUN
eurjchem-2279	69	6	3.1	3.1	NUM
eurjchem-2279	69	7	.	.	PUNCT
eurjchem-2279	69	8	crystallographic	crystallographic	ADJ
eurjchem-2279	69	9	characterization	characterization	NOUN
eurjchem-2279	69	10	crystal	crystal	NOUN
eurjchem-2279	69	11	data	datum	NOUN
eurjchem-2279	69	12	,	,	PUNCT
eurjchem-2279	69	13	data	datum	NOUN
eurjchem-2279	69	14	collection	collection	NOUN
eurjchem-2279	69	15	and	and	CCONJ
eurjchem-2279	69	16	structure	structure	NOUN
eurjchem-2279	69	17	refinement	refinement	NOUN
eurjchem-2279	69	18	details	detail	NOUN
eurjchem-2279	69	19	are	be	AUX
eurjchem-2279	69	20	summarized	summarize	VERB
eurjchem-2279	69	21	in	in	ADP
eurjchem-2279	69	22	table	table	NOUN
eurjchem-2279	69	23	1	1	NUM
eurjchem-2279	69	24	.	.	PUNCT
eurjchem-2279	70	1	a	a	DET
eurjchem-2279	70	2	list	list	NOUN
eurjchem-2279	70	3	of	of	ADP
eurjchem-2279	70	4	bond	bond	NOUN
eurjchem-2279	70	5	distances	distance	NOUN
eurjchem-2279	70	6	and	and	CCONJ
eurjchem-2279	70	7	angles	angle	NOUN
eurjchem-2279	70	8	is	be	AUX
eurjchem-2279	70	9	given	give	VERB
eurjchem-2279	70	10	in	in	ADP
eurjchem-2279	70	11	table	table	NOUN
eurjchem-2279	70	12	2	2	NUM
eurjchem-2279	70	13	.	.	PUNCT
eurjchem-2279	71	1	for	for	ADP
eurjchem-2279	71	2	this	this	DET
eurjchem-2279	71	3	structure	structure	NOUN
eurjchem-2279	71	4	,	,	PUNCT
eurjchem-2279	71	5	hydrogen	hydrogen	NOUN
eurjchem-2279	71	6	atoms	atom	NOUN
eurjchem-2279	71	7	bonded	bond	VERB
eurjchem-2279	71	8	to	to	PART
eurjchem-2279	71	9	carbon	carbon	NOUN
eurjchem-2279	71	10	atoms	atom	NOUN
eurjchem-2279	71	11	were	be	AUX
eurjchem-2279	71	12	placed	place	VERB
eurjchem-2279	71	13	in	in	ADP
eurjchem-2279	71	14	calculated	calculate	VERB
eurjchem-2279	71	15	positions	position	NOUN
eurjchem-2279	71	16	and	and	CCONJ
eurjchem-2279	71	17	refined	refine	VERB
eurjchem-2279	71	18	as	as	ADP
eurjchem-2279	71	19	riding	ride	VERB
eurjchem-2279	71	20	:	:	PUNCT
eurjchem-2279	72	1	c	c	X
eurjchem-2279	72	2	–	–	PUNCT
eurjchem-2279	72	3	h	h	NOUN
eurjchem-2279	72	4	=	=	PUNCT
eurjchem-2279	72	5	0.95–1.00	0.95–1.00	PUNCT
eurjchem-2279	73	1	å	å	NOUN
eurjchem-2279	73	2	with	with	ADP
eurjchem-2279	73	3	uiso(h	uiso(h	PROPN
eurjchem-2279	73	4	)	)	PUNCT
eurjchem-2279	73	5	=	=	SYM
eurjchem-2279	73	6	1.2ueq(c	1.2ueq(c	NUM
eurjchem-2279	73	7	)	)	PUNCT
eurjchem-2279	73	8	for	for	ADP
eurjchem-2279	73	9	methine	methine	ADJ
eurjchem-2279	73	10	groups	group	NOUN
eurjchem-2279	73	11	and	and	CCONJ
eurjchem-2279	73	12	aromatic	aromatic	ADJ
eurjchem-2279	73	13	hydrogen	hydrogen	NOUN
eurjchem-2279	73	14	atoms	atom	NOUN
eurjchem-2279	73	15	,	,	PUNCT
eurjchem-2279	73	16	and	and	CCONJ
eurjchem-2279	73	17	uiso(h	uiso(h	PROPN
eurjchem-2279	73	18	)	)	PUNCT
eurjchem-2279	73	19	=	=	SYM
eurjchem-2279	73	20	1.5ueq(c	1.5ueq(c	X
eurjchem-2279	73	21	)	)	PUNCT
eurjchem-2279	73	22	for	for	ADP
eurjchem-2279	73	23	methyl	methyl	NOUN
eurjchem-2279	73	24	groups	group	NOUN
eurjchem-2279	73	25	.	.	PUNCT
eurjchem-2279	74	1	the	the	DET
eurjchem-2279	74	2	molecular	molecular	ADJ
eurjchem-2279	74	3	structure	structure	NOUN
eurjchem-2279	74	4	of	of	ADP
eurjchem-2279	74	5	the	the	DET
eurjchem-2279	74	6	title	title	NOUN
eurjchem-2279	74	7	compound	compound	NOUN
eurjchem-2279	74	8	is	be	AUX
eurjchem-2279	74	9	shown	show	VERB
eurjchem-2279	74	10	in	in	ADP
eurjchem-2279	74	11	figure	figure	NOUN
eurjchem-2279	74	12	1	1	NUM
eurjchem-2279	74	13	.	.	PUNCT
eurjchem-2279	74	14	characterization	characterization	NOUN
eurjchem-2279	74	15	reveals	reveal	VERB
eurjchem-2279	74	16	a	a	DET
eurjchem-2279	74	17	monoclinic	monoclinic	ADJ
eurjchem-2279	74	18	system	system	NOUN
eurjchem-2279	74	19	(	(	PUNCT
eurjchem-2279	74	20	p21	p21	NOUN
eurjchem-2279	74	21	/	/	SYM
eurjchem-2279	74	22	c	c	NOUN
eurjchem-2279	74	23	space	space	NOUN
eurjchem-2279	74	24	group	group	NOUN
eurjchem-2279	74	25	)	)	PUNCT
eurjchem-2279	74	26	.	.	PUNCT
eurjchem-2279	75	1	the	the	DET
eurjchem-2279	75	2	two	two	NUM
eurjchem-2279	75	3	aryl	aryl	NOUN
eurjchem-2279	75	4	rings	ring	NOUN
eurjchem-2279	75	5	of	of	ADP
eurjchem-2279	75	6	the	the	DET
eurjchem-2279	75	7	title	title	NOUN
eurjchem-2279	75	8	compound	compound	NOUN
eurjchem-2279	75	9	are	be	AUX
eurjchem-2279	75	10	oriented	orient	VERB
eurjchem-2279	75	11	gauche	gauche	NOUN
eurjchem-2279	75	12	to	to	ADP
eurjchem-2279	75	13	one	one	NUM
eurjchem-2279	75	14	another	another	DET
eurjchem-2279	75	15	with	with	ADP
eurjchem-2279	75	16	a	a	DET
eurjchem-2279	75	17	c7	c7	PROPN
eurjchem-2279	75	18	–	–	PUNCT
eurjchem-2279	75	19	s1	s1	PROPN
eurjchem-2279	75	20	–	–	PUNCT
eurjchem-2279	75	21	o1	o1	NOUN
eurjchem-2279	75	22	–	–	PUNCT
eurjchem-2279	75	23	c1	c1	NOUN
eurjchem-2279	75	24	torsion	torsion	NOUN
eurjchem-2279	75	25	angle	angle	NOUN
eurjchem-2279	75	26	of	of	ADP
eurjchem-2279	75	27	73.8(2	73.8(2	PROPN
eurjchem-2279	75	28	)	)	PUNCT
eurjchem-2279	75	29	°	°	PROPN
eurjchem-2279	75	30	.	.	PUNCT
eurjchem-2279	76	1	the	the	DET
eurjchem-2279	76	2	o2	o2	PROPN
eurjchem-2279	76	3	=	=	PROPN
eurjchem-2279	76	4	s1	s1	PROPN
eurjchem-2279	76	5	=	=	SYM
eurjchem-2279	76	6	o3	o3	PROPN
eurjchem-2279	76	7	and	and	CCONJ
eurjchem-2279	76	8	c7	c7	PROPN
eurjchem-2279	76	9	–	–	PUNCT
eurjchem-2279	76	10	s1	s1	PROPN
eurjchem-2279	76	11	–	–	PUNCT
eurjchem-2279	76	12	o1	o1	NOUN
eurjchem-2279	76	13	bond	bond	NOUN
eurjchem-2279	76	14	angles	angle	NOUN
eurjchem-2279	76	15	of	of	ADP
eurjchem-2279	76	16	119.19(12	119.19(12	NUM
eurjchem-2279	76	17	)	)	PUNCT
eurjchem-2279	76	18	and	and	CCONJ
eurjchem-2279	76	19	102.13(11	102.13(11	NUM
eurjchem-2279	76	20	)	)	PUNCT
eurjchem-2279	76	21	°	°	NOUN
eurjchem-2279	76	22	,	,	PUNCT
eurjchem-2279	76	23	respectively	respectively	ADV
eurjchem-2279	76	24	,	,	PUNCT
eurjchem-2279	76	25	are	be	AUX
eurjchem-2279	76	26	typical	typical	ADJ
eurjchem-2279	76	27	for	for	ADP
eurjchem-2279	76	28	phenyl	phenyl	NOUN
eurjchem-2279	76	29	arene	arene	NOUN
eurjchem-2279	76	30	sulfonates	sulfonate	NOUN
eurjchem-2279	76	31	with	with	ADP
eurjchem-2279	76	32	a	a	DET
eurjchem-2279	76	33	gauche	gauche	ADJ
eurjchem-2279	76	34	conformation	conformation	NOUN
eurjchem-2279	76	35	around	around	ADP
eurjchem-2279	76	36	the	the	DET
eurjchem-2279	76	37	ester	ester	NOUN
eurjchem-2279	76	38	s	s	PROPN
eurjchem-2279	76	39	–	–	PUNCT
eurjchem-2279	76	40	o	o	NOUN
eurjchem-2279	76	41	bond	bond	NOUN
eurjchem-2279	76	42	.	.	PUNCT
eurjchem-2279	77	1	steric	steric	ADJ
eurjchem-2279	77	2	hindrance	hindrance	NOUN
eurjchem-2279	77	3	between	between	ADP
eurjchem-2279	77	4	ortho	ortho	PROPN
eurjchem-2279	77	5	substituents	substituent	NOUN
eurjchem-2279	77	6	of	of	ADP
eurjchem-2279	77	7	the	the	DET
eurjchem-2279	77	8	benzene	benzene	NOUN
eurjchem-2279	77	9	ring	ring	NOUN
eurjchem-2279	77	10	results	result	NOUN
eurjchem-2279	77	11	in	in	ADP
eurjchem-2279	77	12	a	a	DET
eurjchem-2279	77	13	40.8(3	40.8(3	PROPN
eurjchem-2279	77	14	)	)	PUNCT
eurjchem-2279	77	15	°	°	PROPN
eurjchem-2279	77	16	perturbation	perturbation	NOUN
eurjchem-2279	77	17	of	of	ADP
eurjchem-2279	77	18	the	the	DET
eurjchem-2279	77	19	nitro	nitro	NOUN
eurjchem-2279	77	20	group	group	NOUN
eurjchem-2279	77	21	relative	relative	ADJ
eurjchem-2279	77	22	to	to	ADP
eurjchem-2279	77	23	the	the	DET
eurjchem-2279	77	24	benzene	benzene	NOUN
eurjchem-2279	77	25	best	good	ADJ
eurjchem-2279	77	26	plane	plane	NOUN
eurjchem-2279	77	27	,	,	PUNCT
eurjchem-2279	77	28	allowing	allow	VERB
eurjchem-2279	77	29	the	the	DET
eurjchem-2279	77	30	shortest	short	ADJ
eurjchem-2279	77	31	contact	contact	NOUN
eurjchem-2279	77	32	of	of	ADP
eurjchem-2279	77	33	2.760(3	2.760(3	NUM
eurjchem-2279	77	34	)	)	PUNCT
eurjchem-2279	77	35	å	å	NOUN
eurjchem-2279	77	36	between	between	ADP
eurjchem-2279	77	37	the	the	DET
eurjchem-2279	77	38	oxygen	oxygen	NOUN
eurjchem-2279	77	39	atoms	atom	NOUN
eurjchem-2279	77	40	of	of	ADP
eurjchem-2279	77	41	these	these	DET
eurjchem-2279	77	42	groups	group	NOUN
eurjchem-2279	77	43	to	to	PART
eurjchem-2279	77	44	be	be	AUX
eurjchem-2279	77	45	close	close	ADJ
eurjchem-2279	77	46	to	to	ADP
eurjchem-2279	77	47	the	the	DET
eurjchem-2279	77	48	sum	sum	NOUN
eurjchem-2279	77	49	of	of	ADP
eurjchem-2279	77	50	the	the	DET
eurjchem-2279	77	51	van	van	PROPN
eurjchem-2279	77	52	der	der	NOUN
eurjchem-2279	77	53	waals	waal	NOUN
eurjchem-2279	77	54	radii	radii	VERB
eurjchem-2279	77	55	.	.	PUNCT
eurjchem-2279	78	1	an	an	DET
eurjchem-2279	78	2	intermolecular	intermolecular	ADJ
eurjchem-2279	78	3	s	s	NOUN
eurjchem-2279	78	4	=	=	NOUN
eurjchem-2279	78	5	o⋯n	o⋯n	ADJ
eurjchem-2279	78	6	interaction	interaction	NOUN
eurjchem-2279	78	7	between	between	ADP
eurjchem-2279	78	8	the	the	DET
eurjchem-2279	78	9	sulfonyl	sulfonyl	NOUN
eurjchem-2279	78	10	and	and	CCONJ
eurjchem-2279	78	11	nitro	nitro	NOUN
eurjchem-2279	78	12	groups	group	NOUN
eurjchem-2279	78	13	is	be	AUX
eurjchem-2279	78	14	responsible	responsible	ADJ
eurjchem-2279	78	15	for	for	ADP
eurjchem-2279	78	16	the	the	DET
eurjchem-2279	78	17	formation	formation	NOUN
eurjchem-2279	78	18	of	of	ADP
eurjchem-2279	78	19	centrosymmetric	centrosymmetric	NOUN
eurjchem-2279	78	20	dimers	dimer	NOUN
eurjchem-2279	78	21	,	,	PUNCT
eurjchem-2279	78	22	with	with	ADP
eurjchem-2279	78	23	an	an	DET
eurjchem-2279	78	24	o2⋯n2	o2⋯n2	ADJ
eurjchem-2279	78	25	distance	distance	NOUN
eurjchem-2279	78	26	of	of	ADP
eurjchem-2279	78	27	3.077(3	3.077(3	NUM
eurjchem-2279	78	28	)	)	PUNCT
eurjchem-2279	78	29	å	å	NOUN
eurjchem-2279	78	30	.	.	PUNCT
eurjchem-2279	79	1	another	another	DET
eurjchem-2279	79	2	centrosymmetric	centrosymmetric	NOUN
eurjchem-2279	79	3	dimer	dimer	NOUN
eurjchem-2279	79	4	is	be	AUX
eurjchem-2279	79	5	formed	form	VERB
eurjchem-2279	79	6	via	via	ADP
eurjchem-2279	79	7	intermolecular	intermolecular	ADJ
eurjchem-2279	79	8	π	π	PROPN
eurjchem-2279	79	9	–	–	PUNCT
eurjchem-2279	79	10	π	π	NOUN
eurjchem-2279	79	11	stacking	stack	VERB
eurjchem-2279	79	12	interactions	interaction	NOUN
eurjchem-2279	79	13	between	between	ADP
eurjchem-2279	79	14	the	the	DET
eurjchem-2279	79	15	relatively	relatively	ADV
eurjchem-2279	79	16	electron	electron	NOUN
eurjchem-2279	79	17	-	-	PUNCT
eurjchem-2279	79	18	rich	rich	ADJ
eurjchem-2279	79	19	phenyl	phenyl	NOUN
eurjchem-2279	79	20	rings	ring	NOUN
eurjchem-2279	79	21	(	(	PUNCT
eurjchem-2279	79	22	figure	figure	NOUN
eurjchem-2279	79	23	2a	2a	NUM
eurjchem-2279	79	24	)	)	PUNCT
eurjchem-2279	79	25	,	,	PUNCT
eurjchem-2279	79	26	with	with	ADP
eurjchem-2279	79	27	a	a	DET
eurjchem-2279	79	28	plane	plane	NOUN
eurjchem-2279	79	29	-	-	PUNCT
eurjchem-2279	79	30	plane	plane	NOUN
eurjchem-2279	79	31	distance	distance	NOUN
eurjchem-2279	79	32	of	of	ADP
eurjchem-2279	79	33	3.723(3	3.723(3	NUM
eurjchem-2279	79	34	)	)	PUNCT
eurjchem-2279	79	35	å	å	NOUN
eurjchem-2279	79	36	.	.	PUNCT
eurjchem-2279	80	1	these	these	DET
eurjchem-2279	80	2	dimers	dimer	NOUN
eurjchem-2279	80	3	are	be	AUX
eurjchem-2279	80	4	organized	organize	VERB
eurjchem-2279	80	5	into	into	ADP
eurjchem-2279	80	6	columns	column	NOUN
eurjchem-2279	80	7	,	,	PUNCT
eurjchem-2279	80	8	which	which	PRON
eurjchem-2279	80	9	are	be	AUX
eurjchem-2279	80	10	then	then	ADV
eurjchem-2279	80	11	assembled	assemble	VERB
eurjchem-2279	80	12	into	into	ADP
eurjchem-2279	80	13	layers	layer	NOUN
eurjchem-2279	80	14	through	through	ADP
eurjchem-2279	80	15	nonclassical	nonclassical	ADJ
eurjchem-2279	80	16	c	c	PROPN
eurjchem-2279	80	17	–	–	PUNCT
eurjchem-2279	80	18	h⋯o	h⋯o	VERB
eurjchem-2279	80	19	interactions	interaction	NOUN
eurjchem-2279	80	20	between	between	ADP
eurjchem-2279	80	21	phenyl	phenyl	NOUN
eurjchem-2279	80	22	hydrogen	hydrogen	NOUN
eurjchem-2279	80	23	atoms	atom	NOUN
eurjchem-2279	80	24	and	and	CCONJ
eurjchem-2279	80	25	sulfonyl/	sulfonyl/	ADJ
eurjchem-2279	80	26	nitro	nitro	NOUN
eurjchem-2279	80	27	group	group	NOUN
eurjchem-2279	80	28	oxygen	oxygen	NOUN
eurjchem-2279	80	29	atoms	atom	NOUN
eurjchem-2279	80	30	(	(	PUNCT
eurjchem-2279	80	31	figure	figure	NOUN
eurjchem-2279	80	32	2b	2b	NOUN
eurjchem-2279	80	33	;	;	PUNCT
eurjchem-2279	80	34	figure	figure	NOUN
eurjchem-2279	80	35	3	3	NUM
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eurjchem-2279	82	14	2022	2022	NUM
eurjchem-2279	82	15	)	)	PUNCT
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eurjchem-2279	82	17	-	-	SYM
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eurjchem-2279	82	20	2022	2022	NUM
eurjchem-2279	82	21	–	–	PUNCT
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eurjchem-2279	82	26	–	–	PUNCT
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eurjchem-2279	83	18	c3	c3	PROPN
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eurjchem-2279	83	20	)	)	PUNCT
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eurjchem-2279	83	22	o2	o2	PROPN
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eurjchem-2279	83	24	)	)	PUNCT
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eurjchem-2279	83	26	c4	c4	PROPN
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eurjchem-2279	83	28	)	)	PUNCT
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eurjchem-2279	83	32	)	)	PUNCT
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eurjchem-2279	83	44	)	)	PUNCT
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eurjchem-2279	83	46	c1	c1	NOUN
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eurjchem-2279	83	48	)	)	PUNCT
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eurjchem-2279	84	3	c3	c3	PROPN
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eurjchem-2279	84	5	)	)	PUNCT
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eurjchem-2279	84	8	o1	o1	PROPN
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eurjchem-2279	84	12	c5	c5	PROPN
eurjchem-2279	84	13	c6	c6	PROPN
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eurjchem-2279	84	15	)	)	PUNCT
eurjchem-2279	84	16	o3	o3	PROPN
eurjchem-2279	84	17	s1	s1	PROPN
eurjchem-2279	84	18	o2	o2	PROPN
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eurjchem-2279	84	20	)	)	PUNCT
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eurjchem-2279	84	22	c6	c6	PROPN
eurjchem-2279	84	23	c1	c1	PROPN
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eurjchem-2279	84	25	)	)	PUNCT
eurjchem-2279	84	26	o3	o3	PROPN
eurjchem-2279	84	27	s1	s1	PROPN
eurjchem-2279	84	28	c7	c7	PROPN
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eurjchem-2279	84	30	)	)	PUNCT
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eurjchem-2279	84	32	c7	c7	PROPN
eurjchem-2279	84	33	s1	s1	PROPN
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eurjchem-2279	84	38	s1	s1	PROPN
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eurjchem-2279	84	42	c7	c7	PROPN
eurjchem-2279	84	43	s1	s1	PROPN
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eurjchem-2279	84	45	)	)	PUNCT
eurjchem-2279	84	46	o4	o4	PROPN
eurjchem-2279	84	47	n1	n1	PROPN
eurjchem-2279	84	48	c2	c2	PROPN
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eurjchem-2279	84	50	)	)	PUNCT
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eurjchem-2279	84	52	c7	c7	PROPN
eurjchem-2279	84	53	c8	c8	PROPN
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eurjchem-2279	85	8	c2	c2	PROPN
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eurjchem-2279	85	13	c7	c7	PROPN
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eurjchem-2279	85	38	c4	c4	PROPN
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eurjchem-2279	85	48	c2	c2	PROPN
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eurjchem-2279	85	58	o1	o1	PROPN
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eurjchem-2279	86	7	c2	c2	PROPN
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eurjchem-2279	88	1	c3	c3	PROPN
eurjchem-2279	88	2	c2	c2	PROPN
eurjchem-2279	88	3	n1	n1	PROPN
eurjchem-2279	88	4	117.3(2	117.3(2	NUM
eurjchem-2279	88	5	)	)	PUNCT
eurjchem-2279	88	6	c11	c11	NOUN
eurjchem-2279	88	7	c12	c12	PROPN
eurjchem-2279	88	8	c7	c7	PROPN
eurjchem-2279	88	9	116.8(2	116.8(2	NUM
eurjchem-2279	88	10	)	)	PUNCT
eurjchem-2279	89	1	c3	c3	PROPN
eurjchem-2279	89	2	c2	c2	PROPN
eurjchem-2279	89	3	c1	c1	PROPN
eurjchem-2279	89	4	121.3(2	121.3(2	NUM
eurjchem-2279	89	5	)	)	PUNCT
eurjchem-2279	89	6	c11	c11	NOUN
eurjchem-2279	89	7	c12	c12	PROPN
eurjchem-2279	89	8	c14	c14	PROPN
eurjchem-2279	89	9	117.0(2	117.0(2	NUM
eurjchem-2279	89	10	)	)	PUNCT
eurjchem-2279	89	11	c2	c2	PROPN
eurjchem-2279	89	12	c3	c3	PROPN
eurjchem-2279	89	13	c4	c4	PROPN
eurjchem-2279	89	14	117.9(2	117.9(2	PROPN
eurjchem-2279	89	15	)	)	PUNCT
eurjchem-2279	89	16	figure	figure	NOUN
eurjchem-2279	89	17	1	1	NUM
eurjchem-2279	89	18	.	.	PUNCT
eurjchem-2279	89	19	molecular	molecular	ADJ
eurjchem-2279	89	20	structure	structure	NOUN
eurjchem-2279	89	21	of	of	ADP
eurjchem-2279	89	22	the	the	DET
eurjchem-2279	89	23	title	title	NOUN
eurjchem-2279	89	24	compound	compound	NOUN
eurjchem-2279	89	25	.	.	PUNCT
eurjchem-2279	90	1	(	(	PUNCT
eurjchem-2279	90	2	a	a	X
eurjchem-2279	90	3	)	)	PUNCT
eurjchem-2279	90	4	(	(	PUNCT
eurjchem-2279	90	5	b	b	X
eurjchem-2279	90	6	)	)	PUNCT
eurjchem-2279	90	7	figure	figure	NOUN
eurjchem-2279	90	8	2	2	NUM
eurjchem-2279	90	9	.	.	PUNCT
eurjchem-2279	91	1	(	(	PUNCT
eurjchem-2279	91	2	a	a	X
eurjchem-2279	91	3	)	)	PUNCT
eurjchem-2279	91	4	centrosymmetric	centrosymmetric	NOUN
eurjchem-2279	91	5	dimers	dimer	NOUN
eurjchem-2279	91	6	of	of	ADP
eurjchem-2279	91	7	the	the	DET
eurjchem-2279	91	8	title	title	NOUN
eurjchem-2279	91	9	compound	compound	NOUN
eurjchem-2279	91	10	formed	form	VERB
eurjchem-2279	91	11	via	via	ADP
eurjchem-2279	91	12	intermolecular	intermolecular	ADJ
eurjchem-2279	91	13	π	π	PROPN
eurjchem-2279	91	14	–	–	PUNCT
eurjchem-2279	91	15	π	π	NOUN
eurjchem-2279	91	16	stacking	stack	VERB
eurjchem-2279	91	17	interactions	interaction	NOUN
eurjchem-2279	91	18	(	(	PUNCT
eurjchem-2279	91	19	b	b	NOUN
eurjchem-2279	91	20	)	)	PUNCT
eurjchem-2279	91	21	a	a	DET
eurjchem-2279	91	22	depiction	depiction	NOUN
eurjchem-2279	91	23	of	of	ADP
eurjchem-2279	91	24	the	the	DET
eurjchem-2279	91	25	interand	interand	ADJ
eurjchem-2279	91	26	intramolecular	intramolecular	ADJ
eurjchem-2279	91	27	contacts	contact	NOUN
eurjchem-2279	91	28	present	present	ADJ
eurjchem-2279	91	29	in	in	ADP
eurjchem-2279	91	30	the	the	DET
eurjchem-2279	91	31	crystal	crystal	NOUN
eurjchem-2279	91	32	of	of	ADP
eurjchem-2279	91	33	the	the	DET
eurjchem-2279	91	34	title	title	NOUN
eurjchem-2279	91	35	compound	compound	NOUN
eurjchem-2279	91	36	using	use	VERB
eurjchem-2279	91	37	a	a	DET
eurjchem-2279	91	38	capped	cap	VERB
eurjchem-2279	91	39	stick	stick	NOUN
eurjchem-2279	91	40	model	model	NOUN
eurjchem-2279	91	41	with	with	ADP
eurjchem-2279	91	42	standard	standard	PROPN
eurjchem-2279	91	43	cpk	cpk	PROPN
eurjchem-2279	91	44	colors	color	NOUN
eurjchem-2279	91	45	.	.	PUNCT
eurjchem-2279	92	1	contacts	contact	NOUN
eurjchem-2279	92	2	are	be	AUX
eurjchem-2279	92	3	shown	show	VERB
eurjchem-2279	92	4	in	in	ADP
eurjchem-2279	92	5	cyan	cyan	PROPN
eurjchem-2279	92	6	.	.	PUNCT
eurjchem-2279	93	1	148	148	NUM
eurjchem-2279	93	2	stenfors	stenfor	NOUN
eurjchem-2279	93	3	and	and	CCONJ
eurjchem-2279	93	4	ngassa	ngassa	NOUN
eurjchem-2279	93	5	/	/	SYM
eurjchem-2279	93	6	european	european	ADJ
eurjchem-2279	93	7	journal	journal	PROPN
eurjchem-2279	93	8	of	of	ADP
eurjchem-2279	93	9	chemistry	chemistry	NOUN
eurjchem-2279	93	10	13	13	NUM
eurjchem-2279	93	11	(	(	PUNCT
eurjchem-2279	93	12	2	2	NUM
eurjchem-2279	93	13	)	)	PUNCT
eurjchem-2279	93	14	(	(	PUNCT
eurjchem-2279	93	15	2022	2022	NUM
eurjchem-2279	93	16	)	)	PUNCT
eurjchem-2279	93	17	145	145	NUM
eurjchem-2279	93	18	-	-	SYM
eurjchem-2279	93	19	150	150	NUM
eurjchem-2279	93	20	2022	2022	NUM
eurjchem-2279	93	21	–	–	PUNCT
eurjchem-2279	93	22	european	european	ADJ
eurjchem-2279	93	23	journal	journal	NOUN
eurjchem-2279	93	24	of	of	ADP
eurjchem-2279	93	25	chemistry	chemistry	NOUN
eurjchem-2279	93	26	–	–	PUNCT
eurjchem-2279	93	27	cc	cc	NOUN
eurjchem-2279	93	28	by	by	ADP
eurjchem-2279	93	29	nc	nc	PROPN
eurjchem-2279	93	30	–	–	PUNCT
eurjchem-2279	93	31	doi	doi	NOUN
eurjchem-2279	93	32	:	:	PUNCT
eurjchem-2279	93	33	10.5155	10.5155	NUM
eurjchem-2279	93	34	/	/	SYM
eurjchem-2279	93	35	eurjchem.13.2.145	eurjchem.13.2.145	NOUN
eurjchem-2279	93	36	-	-	PUNCT
eurjchem-2279	93	37	150.2279	150.2279	NUM
eurjchem-2279	93	38	figure	figure	NOUN
eurjchem-2279	93	39	3	3	NUM
eurjchem-2279	93	40	.	.	PUNCT
eurjchem-2279	93	41	a	a	DET
eurjchem-2279	93	42	view	view	NOUN
eurjchem-2279	93	43	down	down	ADP
eurjchem-2279	93	44	the	the	DET
eurjchem-2279	93	45	b	b	NOUN
eurjchem-2279	93	46	axis	axis	NOUN
eurjchem-2279	93	47	of	of	ADP
eurjchem-2279	93	48	the	the	DET
eurjchem-2279	93	49	crystal	crystal	NOUN
eurjchem-2279	93	50	packing	packing	NOUN
eurjchem-2279	93	51	showing	show	VERB
eurjchem-2279	93	52	the	the	DET
eurjchem-2279	93	53	supramolecular	supramolecular	ADJ
eurjchem-2279	93	54	sheets	sheet	NOUN
eurjchem-2279	93	55	formed	form	VERB
eurjchem-2279	93	56	via	via	ADP
eurjchem-2279	93	57	non	non	ADJ
eurjchem-2279	93	58	-	-	ADJ
eurjchem-2279	93	59	covalent	covalent	ADJ
eurjchem-2279	93	60	interactions	interaction	NOUN
eurjchem-2279	93	61	.	.	PUNCT
eurjchem-2279	94	1	interand	interand	VERB
eurjchem-2279	94	2	intramolecular	intramolecular	ADJ
eurjchem-2279	94	3	contacts	contact	NOUN
eurjchem-2279	94	4	are	be	AUX
eurjchem-2279	94	5	shown	show	VERB
eurjchem-2279	94	6	in	in	ADP
eurjchem-2279	94	7	cyan	cyan	PROPN
eurjchem-2279	94	8	.	.	PUNCT
eurjchem-2279	95	1	s	s	PART
eurjchem-2279	96	1	o	o	X
eurjchem-2279	96	2	o	o	NOUN
eurjchem-2279	96	3	n	n	CCONJ
eurjchem-2279	96	4	cl	cl	NOUN
eurjchem-2279	97	1	s	s	NOUN
eurjchem-2279	97	2	o	o	NOUN
eurjchem-2279	97	3	o	o	X
eurjchem-2279	97	4	o	o	X
eurjchem-2279	97	5	no2	no2	NOUN
eurjchem-2279	97	6	o2n	o2n	NOUN
eurjchem-2279	97	7	n	n	PROPN
eurjchem-2279	97	8	3	3	NUM
eurjchem-2279	97	9	s	s	NOUN
eurjchem-2279	97	10	o	o	NOUN
eurjchem-2279	97	11	o	o	X
eurjchem-2279	97	12	cl	cl	NOUN
eurjchem-2279	97	13	1	1	NUM
eurjchem-2279	97	14	s	s	NOUN
eurjchem-2279	97	15	o	o	NOUN
eurjchem-2279	97	16	o	o	NOUN
eurjchem-2279	97	17	n	n	CCONJ
eurjchem-2279	97	18	no2ho	no2ho	NUM
eurjchem-2279	97	19	o2n	o2n	NOUN
eurjchem-2279	97	20	s	s	PART
eurjchem-2279	97	21	o	o	NOUN
eurjchem-2279	97	22	o	o	NOUN
eurjchem-2279	97	23	n	n	ADP
eurjchem-2279	97	24	o	o	X
eurjchem-2279	98	1	no2o2n	no2o2n	PROPN
eurjchem-2279	98	2	s	s	X
eurjchem-2279	98	3	o	o	NOUN
eurjchem-2279	98	4	o	o	NOUN
eurjchem-2279	99	1	n	n	CCONJ
eurjchem-2279	100	1	o	o	X
eurjchem-2279	100	2	no2o2n	no2o2n	ADJ
eurjchem-2279	100	3	2	2	NUM
eurjchem-2279	100	4	4	4	NUM
eurjchem-2279	100	5	-cl	-cl	NOUN
eurjchem-2279	100	6	-h	-h	X
eurjchem-2279	100	7	scheme	scheme	NOUN
eurjchem-2279	100	8	2	2	NUM
eurjchem-2279	100	9	.	.	PUNCT
eurjchem-2279	101	1	the	the	DET
eurjchem-2279	101	2	previously	previously	ADV
eurjchem-2279	101	3	proposed	propose	VERB
eurjchem-2279	101	4	mechanism	mechanism	NOUN
eurjchem-2279	101	5	for	for	ADP
eurjchem-2279	101	6	the	the	DET
eurjchem-2279	101	7	treatment	treatment	NOUN
eurjchem-2279	101	8	of	of	ADP
eurjchem-2279	101	9	p	p	NOUN
eurjchem-2279	101	10	-	-	PUNCT
eurjchem-2279	101	11	toluenesulfonyl	toluenesulfonyl	NOUN
eurjchem-2279	101	12	chloride	chloride	NOUN
eurjchem-2279	101	13	(	(	PUNCT
eurjchem-2279	101	14	1	1	NUM
eurjchem-2279	101	15	)	)	PUNCT
eurjchem-2279	101	16	with	with	ADP
eurjchem-2279	101	17	2,4	2,4	NUM
eurjchem-2279	101	18	-	-	PUNCT
eurjchem-2279	101	19	dinitrophenol	dinitrophenol	NOUN
eurjchem-2279	101	20	(	(	PUNCT
eurjchem-2279	101	21	2	2	NUM
eurjchem-2279	101	22	)	)	PUNCT
eurjchem-2279	101	23	in	in	ADP
eurjchem-2279	101	24	the	the	DET
eurjchem-2279	101	25	presence	presence	NOUN
eurjchem-2279	101	26	of	of	ADP
eurjchem-2279	101	27	pyridine	pyridine	NOUN
eurjchem-2279	101	28	and	and	CCONJ
eurjchem-2279	101	29	dichloromethane	dichloromethane	NOUN
eurjchem-2279	101	30	to	to	PART
eurjchem-2279	101	31	form	form	VERB
eurjchem-2279	101	32	,	,	PUNCT
eurjchem-2279	101	33	2,4	2,4	NUM
eurjchem-2279	101	34	-	-	PUNCT
eurjchem-2279	101	35	dinitrophenylpyridinium	dinitrophenylpyridinium	NOUN
eurjchem-2279	101	36	p	p	NOUN
eurjchem-2279	101	37	-	-	PUNCT
eurjchem-2279	101	38	toluenesulfonate	toluenesulfonate	NOUN
eurjchem-2279	101	39	(	(	PUNCT
eurjchem-2279	101	40	3	3	NUM
eurjchem-2279	101	41	)	)	PUNCT
eurjchem-2279	101	42	.	.	PUNCT
eurjchem-2279	102	1	shown	show	VERB
eurjchem-2279	102	2	below	below	ADP
eurjchem-2279	102	3	,	,	PUNCT
eurjchem-2279	102	4	this	this	PRON
eurjchem-2279	102	5	is	be	AUX
eurjchem-2279	102	6	the	the	DET
eurjchem-2279	102	7	desired	desire	VERB
eurjchem-2279	102	8	rearrangement	rearrangement	NOUN
eurjchem-2279	102	9	of	of	ADP
eurjchem-2279	102	10	compound	compound	NOUN
eurjchem-2279	102	11	3	3	NUM
eurjchem-2279	102	12	to	to	PART
eurjchem-2279	102	13	give	give	VERB
eurjchem-2279	102	14	the	the	DET
eurjchem-2279	102	15	sulfonate	sulfonate	ADJ
eurjchem-2279	102	16	product	product	NOUN
eurjchem-2279	102	17	(	(	PUNCT
eurjchem-2279	102	18	4	4	NUM
eurjchem-2279	102	19	)	)	PUNCT
eurjchem-2279	102	20	.	.	PUNCT
eurjchem-2279	103	1	s	s	PRON
eurjchem-2279	103	2	oo	oo	ADJ
eurjchem-2279	103	3	aro	aro	NOUN
eurjchem-2279	103	4	cl	cl	PROPN
eurjchem-2279	103	5	k	k	PROPN
eurjchem-2279	103	6	δ+	δ+	PUNCT
eurjchem-2279	103	7	δ	δ	X
eurjchem-2279	103	8	-s	-s	PRON
eurjchem-2279	103	9	oo	oo	INTJ
eurjchem-2279	103	10	aro	aro	NOUN
eurjchem-2279	103	11	cl	cl	PROPN
eurjchem-2279	103	12	k	k	PROPN
eurjchem-2279	103	13	δ+	δ+	PUNCT
eurjchem-2279	103	14	δ	δ	NOUN
eurjchem-2279	103	15	−	−	NOUN
eurjchem-2279	103	16	r	r	NOUN
eurjchem-2279	103	17	r	r	NOUN
eurjchem-2279	103	18	ts1	ts1	PROPN
eurjchem-2279	103	19	ts2	ts2	PROPN
eurjchem-2279	103	20	scheme	scheme	NOUN
eurjchem-2279	103	21	3	3	NUM
eurjchem-2279	103	22	.	.	PUNCT
eurjchem-2279	103	23	proposed	propose	VERB
eurjchem-2279	103	24	transition	transition	NOUN
eurjchem-2279	103	25	states	state	NOUN
eurjchem-2279	103	26	,	,	PUNCT
eurjchem-2279	103	27	derived	derive	VERB
eurjchem-2279	103	28	from	from	ADP
eurjchem-2279	103	29	a	a	DET
eurjchem-2279	103	30	previous	previous	ADJ
eurjchem-2279	103	31	report	report	NOUN
eurjchem-2279	103	32	by	by	ADP
eurjchem-2279	103	33	um	um	INTJ
eurjchem-2279	103	34	et	et	PROPN
eurjchem-2279	103	35	al	al	PROPN
eurjchem-2279	103	36	.	.	PUNCT
eurjchem-2279	104	1	[	[	X
eurjchem-2279	104	2	31	31	NUM
eurjchem-2279	104	3	]	]	PUNCT
eurjchem-2279	104	4	,	,	PUNCT
eurjchem-2279	104	5	explaining	explain	VERB
eurjchem-2279	104	6	the	the	DET
eurjchem-2279	104	7	role	role	NOUN
eurjchem-2279	104	8	of	of	ADP
eurjchem-2279	104	9	k+	k+	NOUN
eurjchem-2279	104	10	in	in	ADP
eurjchem-2279	104	11	the	the	DET
eurjchem-2279	104	12	formation	formation	NOUN
eurjchem-2279	104	13	of	of	ADP
eurjchem-2279	104	14	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	104	15	.	.	PUNCT
eurjchem-2279	105	1	3.2	3.2	NUM
eurjchem-2279	105	2	.	.	PUNCT
eurjchem-2279	106	1	synthetic	synthetic	ADJ
eurjchem-2279	106	2	techniques	technique	NOUN
eurjchem-2279	106	3	the	the	DET
eurjchem-2279	106	4	synthetic	synthetic	ADJ
eurjchem-2279	106	5	strategy	strategy	NOUN
eurjchem-2279	106	6	employed	employ	VERB
eurjchem-2279	106	7	in	in	ADP
eurjchem-2279	106	8	this	this	DET
eurjchem-2279	106	9	work	work	NOUN
eurjchem-2279	106	10	has	have	AUX
eurjchem-2279	106	11	been	be	AUX
eurjchem-2279	106	12	previously	previously	ADV
eurjchem-2279	106	13	reported	report	VERB
eurjchem-2279	106	14	by	by	ADP
eurjchem-2279	106	15	our	our	PRON
eurjchem-2279	106	16	group	group	NOUN
eurjchem-2279	106	17	[	[	X
eurjchem-2279	106	18	30	30	NUM
eurjchem-2279	106	19	]	]	PUNCT
eurjchem-2279	106	20	.	.	PUNCT
eurjchem-2279	107	1	initial	initial	ADJ
eurjchem-2279	107	2	reaction	reaction	NOUN
eurjchem-2279	107	3	conditions	condition	NOUN
eurjchem-2279	107	4	of	of	ADP
eurjchem-2279	107	5	dichloromethane	dichloromethane	NOUN
eurjchem-2279	107	6	in	in	ADP
eurjchem-2279	107	7	the	the	DET
eurjchem-2279	107	8	presence	presence	NOUN
eurjchem-2279	107	9	of	of	ADP
eurjchem-2279	107	10	pyridine	pyridine	NOUN
eurjchem-2279	107	11	resulted	result	VERB
eurjchem-2279	107	12	in	in	ADP
eurjchem-2279	107	13	the	the	DET
eurjchem-2279	107	14	formation	formation	NOUN
eurjchem-2279	107	15	of	of	ADP
eurjchem-2279	107	16	an	an	DET
eurjchem-2279	107	17	undesired	undesired	ADJ
eurjchem-2279	107	18	pyridinium	pyridinium	NOUN
eurjchem-2279	107	19	salt	salt	NOUN
eurjchem-2279	107	20	as	as	ADP
eurjchem-2279	107	21	the	the	DET
eurjchem-2279	107	22	only	only	ADJ
eurjchem-2279	107	23	product	product	NOUN
eurjchem-2279	107	24	.	.	PUNCT
eurjchem-2279	108	1	scheme	scheme	NOUN
eurjchem-2279	108	2	2	2	NUM
eurjchem-2279	108	3	shows	show	VERB
eurjchem-2279	108	4	the	the	DET
eurjchem-2279	108	5	previously	previously	ADV
eurjchem-2279	108	6	proposed	propose	VERB
eurjchem-2279	108	7	mechanism	mechanism	NOUN
eurjchem-2279	108	8	for	for	ADP
eurjchem-2279	108	9	the	the	DET
eurjchem-2279	108	10	formation	formation	NOUN
eurjchem-2279	108	11	of	of	ADP
eurjchem-2279	108	12	this	this	DET
eurjchem-2279	108	13	pyridinium	pyridinium	NOUN
eurjchem-2279	108	14	salt	salt	NOUN
eurjchem-2279	108	15	.	.	PUNCT
eurjchem-2279	109	1	alternative	alternative	ADJ
eurjchem-2279	109	2	routes	route	NOUN
eurjchem-2279	109	3	were	be	AUX
eurjchem-2279	109	4	explored	explore	VERB
eurjchem-2279	109	5	,	,	PUNCT
eurjchem-2279	109	6	leading	lead	VERB
eurjchem-2279	109	7	to	to	ADP
eurjchem-2279	109	8	the	the	DET
eurjchem-2279	109	9	development	development	NOUN
eurjchem-2279	109	10	of	of	ADP
eurjchem-2279	109	11	a	a	DET
eurjchem-2279	109	12	semi	semi	ADJ
eurjchem-2279	109	13	-	-	ADJ
eurjchem-2279	109	14	miscible	miscible	ADJ
eurjchem-2279	109	15	biphasic	biphasic	ADJ
eurjchem-2279	109	16	system	system	NOUN
eurjchem-2279	109	17	consisting	consist	VERB
eurjchem-2279	109	18	of	of	ADP
eurjchem-2279	109	19	1:1	1:1	NUM
eurjchem-2279	109	20	thf	thf	ADJ
eurjchem-2279	109	21	/	/	SYM
eurjchem-2279	109	22	aqueous	aqueous	ADJ
eurjchem-2279	109	23	k2co3	k2co3	NOUN
eurjchem-2279	109	24	,	,	PUNCT
eurjchem-2279	109	25	the	the	DET
eurjchem-2279	109	26	same	same	ADJ
eurjchem-2279	109	27	technique	technique	NOUN
eurjchem-2279	109	28	employed	employ	VERB
eurjchem-2279	109	29	in	in	ADP
eurjchem-2279	109	30	this	this	DET
eurjchem-2279	109	31	work	work	NOUN
eurjchem-2279	109	32	.	.	PUNCT
eurjchem-2279	110	1	these	these	DET
eurjchem-2279	110	2	conditions	condition	NOUN
eurjchem-2279	110	3	resulted	result	VERB
eurjchem-2279	110	4	in	in	ADP
eurjchem-2279	110	5	higher	high	ADJ
eurjchem-2279	110	6	yields	yield	NOUN
eurjchem-2279	110	7	,	,	PUNCT
eurjchem-2279	110	8	less	less	ADV
eurjchem-2279	110	9	environmental	environmental	ADJ
eurjchem-2279	110	10	impact	impact	NOUN
eurjchem-2279	110	11	due	due	ADP
eurjchem-2279	110	12	to	to	ADP
eurjchem-2279	110	13	the	the	DET
eurjchem-2279	110	14	environmentally	environmentally	ADV
eurjchem-2279	110	15	benign	benign	ADJ
eurjchem-2279	110	16	conditions	condition	NOUN
eurjchem-2279	110	17	,	,	PUNCT
eurjchem-2279	110	18	and	and	CCONJ
eurjchem-2279	110	19	shorter	short	ADJ
eurjchem-2279	110	20	reaction	reaction	NOUN
eurjchem-2279	110	21	times	time	NOUN
eurjchem-2279	110	22	.	.	PUNCT
eurjchem-2279	111	1	outlined	outline	VERB
eurjchem-2279	111	2	in	in	ADP
eurjchem-2279	111	3	scheme	scheme	NOUN
eurjchem-2279	111	4	3	3	NUM
eurjchem-2279	111	5	,	,	PUNCT
eurjchem-2279	111	6	previous	previous	ADJ
eurjchem-2279	111	7	reports	report	NOUN
eurjchem-2279	111	8	suggest	suggest	VERB
eurjchem-2279	111	9	a	a	DET
eurjchem-2279	111	10	reaction	reaction	NOUN
eurjchem-2279	111	11	catalyzed	catalyze	VERB
eurjchem-2279	111	12	by	by	ADP
eurjchem-2279	111	13	k+	k+	NOUN
eurjchem-2279	111	14	via	via	ADP
eurjchem-2279	111	15	increased	increase	VERB
eurjchem-2279	111	16	electrophilicy	electrophilicy	ADJ
eurjchem-2279	111	17	of	of	ADP
eurjchem-2279	111	18	the	the	DET
eurjchem-2279	111	19	reaction	reaction	NOUN
eurjchem-2279	111	20	center	center	NOUN
eurjchem-2279	111	21	(	(	PUNCT
eurjchem-2279	111	22	ts1	ts1	PROPN
eurjchem-2279	111	23	)	)	PUNCT
eurjchem-2279	111	24	or	or	CCONJ
eurjchem-2279	111	25	by	by	ADP
eurjchem-2279	111	26	increased	increase	VERB
eurjchem-2279	111	27	nucleofugality	nucleofugality	NOUN
eurjchem-2279	111	28	of	of	ADP
eurjchem-2279	111	29	the	the	DET
eurjchem-2279	111	30	leaving	leave	VERB
eurjchem-2279	111	31	group	group	NOUN
eurjchem-2279	111	32	(	(	PUNCT
eurjchem-2279	111	33	ts2	ts2	PROPN
eurjchem-2279	111	34	)	)	PUNCT
eurjchem-2279	112	1	[	[	X
eurjchem-2279	112	2	31	31	NUM
eurjchem-2279	112	3	]	]	PUNCT
eurjchem-2279	112	4	,	,	PUNCT
eurjchem-2279	112	5	further	far	ADV
eurjchem-2279	112	6	supporting	support	VERB
eurjchem-2279	112	7	the	the	DET
eurjchem-2279	112	8	observed	observed	ADJ
eurjchem-2279	112	9	increase	increase	NOUN
eurjchem-2279	112	10	in	in	ADP
eurjchem-2279	112	11	yield	yield	NOUN
eurjchem-2279	112	12	and	and	CCONJ
eurjchem-2279	112	13	decreased	decrease	VERB
eurjchem-2279	112	14	reaction	reaction	NOUN
eurjchem-2279	112	15	time	time	NOUN
eurjchem-2279	112	16	.	.	PUNCT
eurjchem-2279	113	1	additionally	additionally	ADV
eurjchem-2279	113	2	,	,	PUNCT
eurjchem-2279	113	3	the	the	DET
eurjchem-2279	113	4	highly	highly	ADV
eurjchem-2279	113	5	pure	pure	ADJ
eurjchem-2279	113	6	sulfonate	sulfonate	ADJ
eurjchem-2279	113	7	product	product	NOUN
eurjchem-2279	113	8	can	can	AUX
eurjchem-2279	113	9	be	be	AUX
eurjchem-2279	113	10	isolated	isolate	VERB
eurjchem-2279	113	11	directly	directly	ADV
eurjchem-2279	113	12	from	from	ADP
eurjchem-2279	113	13	the	the	DET
eurjchem-2279	113	14	reaction	reaction	NOUN
eurjchem-2279	113	15	mixture	mixture	NOUN
eurjchem-2279	113	16	.	.	PUNCT
eurjchem-2279	114	1	such	such	ADJ
eurjchem-2279	114	2	conditions	condition	NOUN
eurjchem-2279	114	3	have	have	AUX
eurjchem-2279	114	4	been	be	AUX
eurjchem-2279	114	5	used	use	VERB
eurjchem-2279	114	6	to	to	PART
eurjchem-2279	114	7	synthesize	synthesize	VERB
eurjchem-2279	114	8	a	a	DET
eurjchem-2279	114	9	variety	variety	NOUN
eurjchem-2279	114	10	of	of	ADP
eurjchem-2279	114	11	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	114	12	in	in	ADP
eurjchem-2279	114	13	hopes	hope	NOUN
eurjchem-2279	114	14	of	of	ADP
eurjchem-2279	114	15	studying	study	VERB
eurjchem-2279	114	16	their	their	PRON
eurjchem-2279	114	17	regioselective	regioselective	ADJ
eurjchem-2279	114	18	c	c	NOUN
eurjchem-2279	114	19	–	–	PUNCT
eurjchem-2279	114	20	o	o	NOUN
eurjchem-2279	114	21	/	/	SYM
eurjchem-2279	114	22	s	s	PROPN
eurjchem-2279	114	23	–	–	PUNCT
eurjchem-2279	114	24	o	o	NOUN
eurjchem-2279	114	25	bond	bond	NOUN
eurjchem-2279	114	26	cleavage	cleavage	NOUN
eurjchem-2279	114	27	upon	upon	SCONJ
eurjchem-2279	114	28	treatment	treatment	NOUN
eurjchem-2279	114	29	with	with	ADP
eurjchem-2279	114	30	a	a	DET
eurjchem-2279	114	31	nucleophilic	nucleophilic	ADJ
eurjchem-2279	114	32	amine	amine	NOUN
eurjchem-2279	114	33	.	.	PUNCT
eurjchem-2279	115	1	4	4	X
eurjchem-2279	115	2	.	.	X
eurjchem-2279	115	3	conclusion	conclusion	NOUN
eurjchem-2279	115	4	in	in	ADP
eurjchem-2279	115	5	this	this	DET
eurjchem-2279	115	6	work	work	NOUN
eurjchem-2279	115	7	,	,	PUNCT
eurjchem-2279	115	8	the	the	DET
eurjchem-2279	115	9	synthesis	synthesis	NOUN
eurjchem-2279	115	10	and	and	CCONJ
eurjchem-2279	115	11	crystallographic	crystallographic	ADJ
eurjchem-2279	115	12	characterization	characterization	NOUN
eurjchem-2279	115	13	of	of	ADP
eurjchem-2279	115	14	2,4	2,4	NUM
eurjchem-2279	115	15	-	-	PUNCT
eurjchem-2279	115	16	dinitrophenyl	dinitrophenyl	ADJ
eurjchem-2279	115	17	2,4,6	2,4,6	NUM
eurjchem-2279	115	18	-	-	PUNCT
eurjchem-2279	115	19	trimethylbenzenesulfonate	trimethylbenzenesulfonate	NOUN
eurjchem-2279	115	20	stenfors	stenfor	NOUN
eurjchem-2279	115	21	and	and	CCONJ
eurjchem-2279	115	22	ngassa	ngassa	NOUN
eurjchem-2279	115	23	/	/	SYM
eurjchem-2279	115	24	european	european	ADJ
eurjchem-2279	115	25	journal	journal	PROPN
eurjchem-2279	115	26	of	of	ADP
eurjchem-2279	115	27	chemistry	chemistry	NOUN
eurjchem-2279	115	28	13	13	NUM
eurjchem-2279	115	29	(	(	PUNCT
eurjchem-2279	115	30	2	2	NUM
eurjchem-2279	115	31	)	)	PUNCT
eurjchem-2279	115	32	(	(	PUNCT
eurjchem-2279	115	33	2022	2022	NUM
eurjchem-2279	115	34	)	)	PUNCT
eurjchem-2279	115	35	145	145	NUM
eurjchem-2279	115	36	-	-	SYM
eurjchem-2279	115	37	150	150	NUM
eurjchem-2279	115	38	149	149	NUM
eurjchem-2279	115	39	2022	2022	NUM
eurjchem-2279	115	40	–	–	PUNCT
eurjchem-2279	115	41	european	european	ADJ
eurjchem-2279	115	42	journal	journal	NOUN
eurjchem-2279	115	43	of	of	ADP
eurjchem-2279	115	44	chemistry	chemistry	NOUN
eurjchem-2279	115	45	–	–	PUNCT
eurjchem-2279	115	46	cc	cc	NOUN
eurjchem-2279	115	47	by	by	ADP
eurjchem-2279	115	48	nc	nc	PROPN
eurjchem-2279	115	49	–	–	PUNCT
eurjchem-2279	115	50	doi	doi	NOUN
eurjchem-2279	115	51	:	:	PUNCT
eurjchem-2279	115	52	10.5155	10.5155	NUM
eurjchem-2279	115	53	/	/	SYM
eurjchem-2279	115	54	eurjchem.13.2.145	eurjchem.13.2.145	NOUN
eurjchem-2279	115	55	-	-	PUNCT
eurjchem-2279	115	56	150.2279	150.2279	PROPN
eurjchem-2279	115	57	was	be	AUX
eurjchem-2279	115	58	discussed	discuss	VERB
eurjchem-2279	115	59	.	.	PUNCT
eurjchem-2279	116	1	crystallographic	crystallographic	ADJ
eurjchem-2279	116	2	characterization	characterization	NOUN
eurjchem-2279	116	3	revealed	reveal	VERB
eurjchem-2279	116	4	a	a	DET
eurjchem-2279	116	5	high	high	ADJ
eurjchem-2279	116	6	correlation	correlation	NOUN
eurjchem-2279	116	7	of	of	ADP
eurjchem-2279	116	8	bond	bond	NOUN
eurjchem-2279	116	9	angles	angle	VERB
eurjchem-2279	116	10	around	around	ADP
eurjchem-2279	116	11	the	the	DET
eurjchem-2279	116	12	sulfonyl	sulfonyl	NOUN
eurjchem-2279	116	13	when	when	SCONJ
eurjchem-2279	116	14	compared	compare	VERB
eurjchem-2279	116	15	to	to	ADP
eurjchem-2279	116	16	similar	similar	ADJ
eurjchem-2279	116	17	structures	structure	NOUN
eurjchem-2279	116	18	exhibiting	exhibit	VERB
eurjchem-2279	116	19	gauche	gauche	ADJ
eurjchem-2279	116	20	oriented	orient	VERB
eurjchem-2279	116	21	phenyl	phenyl	NOUN
eurjchem-2279	116	22	rings	ring	NOUN
eurjchem-2279	116	23	about	about	ADP
eurjchem-2279	116	24	the	the	DET
eurjchem-2279	116	25	s	s	PROPN
eurjchem-2279	116	26	–	–	PUNCT
eurjchem-2279	116	27	o	o	NOUN
eurjchem-2279	116	28	bond	bond	NOUN
eurjchem-2279	116	29	axis	axis	NOUN
eurjchem-2279	116	30	.	.	PUNCT
eurjchem-2279	117	1	two	two	NUM
eurjchem-2279	117	2	sets	set	NOUN
eurjchem-2279	117	3	of	of	ADP
eurjchem-2279	117	4	centrosymmetric	centrosymmetric	NOUN
eurjchem-2279	117	5	dimers	dimer	NOUN
eurjchem-2279	117	6	are	be	AUX
eurjchem-2279	117	7	formed	form	VERB
eurjchem-2279	117	8	via	via	ADP
eurjchem-2279	117	9	intermolecular	intermolecular	ADJ
eurjchem-2279	117	10	s	s	PART
eurjchem-2279	117	11	=	=	NOUN
eurjchem-2279	117	12	o⋯n	o⋯n	ADJ
eurjchem-2279	117	13	and	and	CCONJ
eurjchem-2279	117	14	π	π	PROPN
eurjchem-2279	117	15	–	–	PUNCT
eurjchem-2279	117	16	π	π	NOUN
eurjchem-2279	117	17	stacking	stack	VERB
eurjchem-2279	117	18	interactions	interaction	NOUN
eurjchem-2279	117	19	.	.	PUNCT
eurjchem-2279	118	1	nonclassical	nonclassical	ADJ
eurjchem-2279	118	2	c	c	PROPN
eurjchem-2279	118	3	–	–	PUNCT
eurjchem-2279	118	4	h⋯o	h⋯o	VERB
eurjchem-2279	118	5	interactions	interaction	NOUN
eurjchem-2279	118	6	between	between	ADP
eurjchem-2279	118	7	phenyl	phenyl	NOUN
eurjchem-2279	118	8	hydrogen	hydrogen	NOUN
eurjchem-2279	118	9	atoms	atom	NOUN
eurjchem-2279	118	10	further	far	ADV
eurjchem-2279	118	11	assemble	assemble	VERB
eurjchem-2279	118	12	these	these	DET
eurjchem-2279	118	13	dimers	dimer	NOUN
eurjchem-2279	118	14	into	into	ADP
eurjchem-2279	118	15	layers	layer	NOUN
eurjchem-2279	118	16	,	,	PUNCT
eurjchem-2279	118	17	affording	afford	VERB
eurjchem-2279	118	18	supramolecular	supramolecular	ADJ
eurjchem-2279	118	19	sheets	sheet	NOUN
eurjchem-2279	118	20	.	.	PUNCT
eurjchem-2279	119	1	apart	apart	ADV
eurjchem-2279	119	2	from	from	ADP
eurjchem-2279	119	3	characterization	characterization	NOUN
eurjchem-2279	119	4	,	,	PUNCT
eurjchem-2279	119	5	the	the	DET
eurjchem-2279	119	6	aforementioned	aforementioned	ADJ
eurjchem-2279	119	7	synthetic	synthetic	ADJ
eurjchem-2279	119	8	method	method	NOUN
eurjchem-2279	119	9	offers	offer	VERB
eurjchem-2279	119	10	an	an	DET
eurjchem-2279	119	11	efficient	efficient	ADJ
eurjchem-2279	119	12	and	and	CCONJ
eurjchem-2279	119	13	environmentally	environmentally	ADV
eurjchem-2279	119	14	benign	benign	ADJ
eurjchem-2279	119	15	route	route	NOUN
eurjchem-2279	119	16	to	to	PART
eurjchem-2279	119	17	arylsulfonate	arylsulfonate	NOUN
eurjchem-2279	119	18	precursors	precursor	NOUN
eurjchem-2279	119	19	.	.	PUNCT
eurjchem-2279	120	1	subsequent	subsequent	ADJ
eurjchem-2279	120	2	regioselective	regioselective	ADJ
eurjchem-2279	120	3	c	c	NOUN
eurjchem-2279	120	4	–	–	PUNCT
eurjchem-2279	120	5	o	o	NOUN
eurjchem-2279	120	6	/	/	SYM
eurjchem-2279	120	7	s	s	PROPN
eurjchem-2279	120	8	–	–	PUNCT
eurjchem-2279	120	9	o	o	NOUN
eurjchem-2279	120	10	bond	bond	NOUN
eurjchem-2279	120	11	cleavage	cleavage	NOUN
eurjchem-2279	120	12	upon	upon	SCONJ
eurjchem-2279	120	13	amination	amination	NOUN
eurjchem-2279	120	14	affords	afford	NOUN
eurjchem-2279	120	15	either	either	CCONJ
eurjchem-2279	120	16	the	the	DET
eurjchem-2279	120	17	arylsulfomanide	arylsulfomanide	NOUN
eurjchem-2279	120	18	or	or	CCONJ
eurjchem-2279	120	19	corresponding	corresponding	ADJ
eurjchem-2279	120	20	arylamine	arylamine	NOUN
eurjchem-2279	120	21	,	,	PUNCT
eurjchem-2279	120	22	two	two	NUM
eurjchem-2279	120	23	biologically	biologically	ADV
eurjchem-2279	120	24	significant	significant	ADJ
eurjchem-2279	120	25	scaffolds	scaffold	NOUN
eurjchem-2279	120	26	.	.	PUNCT
eurjchem-2279	121	1	crystallographic	crystallographic	ADJ
eurjchem-2279	121	2	characterization	characterization	NOUN
eurjchem-2279	121	3	may	may	AUX
eurjchem-2279	121	4	potentially	potentially	ADV
eurjchem-2279	121	5	offer	offer	VERB
eurjchem-2279	121	6	structural	structural	ADJ
eurjchem-2279	121	7	insight	insight	NOUN
eurjchem-2279	121	8	into	into	ADP
eurjchem-2279	121	9	such	such	ADJ
eurjchem-2279	121	10	regioselective	regioselective	ADJ
eurjchem-2279	121	11	factors	factor	NOUN
eurjchem-2279	121	12	.	.	PUNCT
eurjchem-2279	122	1	various	various	ADJ
eurjchem-2279	122	2	arylsulfonates	arylsulfonate	NOUN
eurjchem-2279	122	3	will	will	AUX
eurjchem-2279	122	4	be	be	AUX
eurjchem-2279	122	5	synthesized	synthesize	VERB
eurjchem-2279	122	6	to	to	PART
eurjchem-2279	122	7	further	far	ADV
eurjchem-2279	122	8	study	study	VERB
eurjchem-2279	122	9	these	these	DET
eurjchem-2279	122	10	factors	factor	NOUN
eurjchem-2279	122	11	and	and	CCONJ
eurjchem-2279	122	12	the	the	DET
eurjchem-2279	122	13	potential	potential	NOUN
eurjchem-2279	122	14	for	for	ADP
eurjchem-2279	122	15	an	an	DET
eurjchem-2279	122	16	efficient	efficient	ADJ
eurjchem-2279	122	17	one	one	NUM
eurjchem-2279	122	18	-	-	PUNCT
eurjchem-2279	122	19	pot	pot	NOUN
eurjchem-2279	122	20	synthesis	synthesis	NOUN
eurjchem-2279	122	21	of	of	ADP
eurjchem-2279	122	22	arylsulfon	arylsulfon	NOUN
eurjchem-2279	122	23	amides	amide	NOUN
eurjchem-2279	122	24	and	and	CCONJ
eurjchem-2279	122	25	arylamines	arylamine	NOUN
eurjchem-2279	122	26	from	from	ADP
eurjchem-2279	122	27	a	a	DET
eurjchem-2279	122	28	single	single	ADJ
eurjchem-2279	122	29	synthetic	synthetic	ADJ
eurjchem-2279	122	30	precursor	precursor	NOUN
eurjchem-2279	122	31	.	.	PUNCT
eurjchem-2279	123	1	furthermore	furthermore	ADV
eurjchem-2279	123	2	,	,	PUNCT
eurjchem-2279	123	3	the	the	DET
eurjchem-2279	123	4	results	result	NOUN
eurjchem-2279	123	5	afforded	afford	VERB
eurjchem-2279	123	6	from	from	ADP
eurjchem-2279	123	7	various	various	ADJ
eurjchem-2279	123	8	reaction	reaction	NOUN
eurjchem-2279	123	9	conditions	condition	NOUN
eurjchem-2279	123	10	will	will	AUX
eurjchem-2279	123	11	provide	provide	VERB
eurjchem-2279	123	12	insight	insight	NOUN
eurjchem-2279	123	13	into	into	ADP
eurjchem-2279	123	14	the	the	DET
eurjchem-2279	123	15	mechanistic	mechanistic	ADJ
eurjchem-2279	123	16	details	detail	NOUN
eurjchem-2279	123	17	for	for	ADP
eurjchem-2279	123	18	the	the	DET
eurjchem-2279	123	19	nucleophilic	nucleophilic	ADJ
eurjchem-2279	123	20	substitution	substitution	NOUN
eurjchem-2279	123	21	of	of	ADP
eurjchem-2279	123	22	sulfonyls	sulfonyls	NOUN
eurjchem-2279	123	23	.	.	PUNCT
eurjchem-2279	124	1	acknowledgements	acknowledgement	VERB
eurjchem-2279	124	2	the	the	DET
eurjchem-2279	124	3	authors	author	NOUN
eurjchem-2279	124	4	thank	thank	VERB
eurjchem-2279	124	5	pfizer	pfizer	PROPN
eurjchem-2279	124	6	inc	inc	PROPN
eurjchem-2279	124	7	.	.	PROPN
eurjchem-2279	124	8	for	for	ADP
eurjchem-2279	124	9	the	the	DET
eurjchem-2279	124	10	donation	donation	NOUN
eurjchem-2279	124	11	of	of	ADP
eurjchem-2279	124	12	a	a	DET
eurjchem-2279	124	13	varian	varian	PROPN
eurjchem-2279	124	14	inova	inova	PROPN
eurjchem-2279	124	15	400	400	NUM
eurjchem-2279	124	16	ft	ft	NOUN
eurjchem-2279	124	17	nmr	nmr	NOUN
eurjchem-2279	124	18	.	.	PUNCT
eurjchem-2279	125	1	the	the	DET
eurjchem-2279	125	2	ccd	ccd	NOUN
eurjchem-2279	125	3	-	-	PUNCT
eurjchem-2279	125	4	based	base	VERB
eurjchem-2279	125	5	x	x	NOUN
eurjchem-2279	125	6	-	-	NOUN
eurjchem-2279	125	7	ray	ray	NOUN
eurjchem-2279	125	8	diffractometers	diffractometer	NOUN
eurjchem-2279	125	9	at	at	ADP
eurjchem-2279	125	10	michigan	michigan	PROPN
eurjchem-2279	125	11	state	state	PROPN
eurjchem-2279	125	12	university	university	PROPN
eurjchem-2279	125	13	were	be	AUX
eurjchem-2279	125	14	replaced	replace	VERB
eurjchem-2279	125	15	and/or	and/or	CCONJ
eurjchem-2279	125	16	upgraded	upgrade	VERB
eurjchem-2279	125	17	with	with	ADP
eurjchem-2279	125	18	departmental	departmental	ADJ
eurjchem-2279	125	19	funds	fund	NOUN
eurjchem-2279	125	20	.	.	PUNCT
eurjchem-2279	126	1	supporting	support	VERB
eurjchem-2279	126	2	information	information	NOUN
eurjchem-2279	126	3	ccdc-2157592	ccdc-2157592	NOUN
eurjchem-2279	126	4	contains	contain	VERB
eurjchem-2279	126	5	the	the	DET
eurjchem-2279	126	6	supplementary	supplementary	ADJ
eurjchem-2279	126	7	crystallographic	crystallographic	ADJ
eurjchem-2279	126	8	data	datum	NOUN
eurjchem-2279	126	9	for	for	ADP
eurjchem-2279	126	10	this	this	DET
eurjchem-2279	126	11	paper	paper	NOUN
eurjchem-2279	126	12	.	.	PUNCT
eurjchem-2279	127	1	these	these	DET
eurjchem-2279	127	2	data	datum	NOUN
eurjchem-2279	127	3	can	can	AUX
eurjchem-2279	127	4	be	be	AUX
eurjchem-2279	127	5	obtained	obtain	VERB
eurjchem-2279	127	6	free	free	ADJ
eurjchem-2279	127	7	of	of	ADP
eurjchem-2279	127	8	charge	charge	NOUN
eurjchem-2279	127	9	via	via	ADP
eurjchem-2279	127	10	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	PROPN
eurjchem-2279	127	11	,	,	PUNCT
eurjchem-2279	127	12	or	or	CCONJ
eurjchem-2279	127	13	by	by	ADP
eurjchem-2279	127	14	e	e	NOUN
eurjchem-2279	127	15	-	-	ADJ
eurjchem-2279	127	16	mailing	mailing	ADJ
eurjchem-2279	127	17	data_request@	data_request@	ADJ
eurjchem-2279	127	18	ccdc.cam.ac.uk	ccdc.cam.ac.uk	ADJ
eurjchem-2279	127	19	,	,	PUNCT
eurjchem-2279	127	20	or	or	CCONJ
eurjchem-2279	127	21	by	by	ADP
eurjchem-2279	127	22	contacting	contact	VERB
eurjchem-2279	127	23	the	the	DET
eurjchem-2279	127	24	cambridge	cambridge	PROPN
eurjchem-2279	127	25	crystallographic	crystallographic	PROPN
eurjchem-2279	127	26	data	data	PROPN
eurjchem-2279	127	27	centre	centre	NOUN
eurjchem-2279	127	28	,	,	PUNCT
eurjchem-2279	127	29	12	12	NUM
eurjchem-2279	127	30	union	union	NOUN
eurjchem-2279	127	31	road	road	NOUN
eurjchem-2279	127	32	,	,	PUNCT
eurjchem-2279	127	33	cambridge	cambridge	PROPN
eurjchem-2279	127	34	cb2	cb2	PROPN
eurjchem-2279	127	35	1ez	1ez	PROPN
eurjchem-2279	127	36	,	,	PUNCT
eurjchem-2279	127	37	uk	uk	PROPN
eurjchem-2279	127	38	;	;	PUNCT
eurjchem-2279	127	39	fax	fax	NOUN
eurjchem-2279	127	40	:	:	PUNCT
eurjchem-2279	127	41	+44(0)1223	+44(0)1223	PROPN
eurjchem-2279	127	42	-	-	PUNCT
eurjchem-2279	127	43	336033	336033	NUM
eurjchem-2279	127	44	.	.	PUNCT
eurjchem-2279	128	1	disclosure	disclosure	NOUN
eurjchem-2279	128	2	statement	statement	NOUN
eurjchem-2279	128	3	conflict	conflict	NOUN
eurjchem-2279	128	4	of	of	ADP
eurjchem-2279	128	5	interest	interest	NOUN
eurjchem-2279	128	6	:	:	PUNCT
eurjchem-2279	128	7	the	the	DET
eurjchem-2279	128	8	authors	author	NOUN
eurjchem-2279	128	9	declare	declare	VERB
eurjchem-2279	128	10	that	that	SCONJ
eurjchem-2279	128	11	they	they	PRON
eurjchem-2279	128	12	have	have	VERB
eurjchem-2279	128	13	no	no	DET
eurjchem-2279	128	14	conflict	conflict	NOUN
eurjchem-2279	128	15	of	of	ADP
eurjchem-2279	128	16	interest	interest	NOUN
eurjchem-2279	128	17	.	.	PUNCT
eurjchem-2279	129	1	ethical	ethical	ADJ
eurjchem-2279	129	2	approval	approval	NOUN
eurjchem-2279	129	3	:	:	PUNCT
eurjchem-2279	130	1	all	all	DET
eurjchem-2279	130	2	ethical	ethical	ADJ
eurjchem-2279	130	3	guidelines	guideline	NOUN
eurjchem-2279	130	4	have	have	AUX
eurjchem-2279	130	5	been	be	AUX
eurjchem-2279	130	6	adhered	adhere	VERB
eurjchem-2279	130	7	.	.	PUNCT
eurjchem-2279	131	1	sample	sample	NOUN
eurjchem-2279	131	2	availability	availability	NOUN
eurjchem-2279	131	3	:	:	PUNCT
eurjchem-2279	131	4	samples	sample	NOUN
eurjchem-2279	131	5	of	of	ADP
eurjchem-2279	131	6	the	the	DET
eurjchem-2279	131	7	compounds	compound	NOUN
eurjchem-2279	131	8	are	be	AUX
eurjchem-2279	131	9	available	available	ADJ
eurjchem-2279	131	10	from	from	ADP
eurjchem-2279	131	11	the	the	DET
eurjchem-2279	131	12	author	author	NOUN
eurjchem-2279	131	13	.	.	PUNCT
eurjchem-2279	132	1	credit	credit	NOUN
eurjchem-2279	132	2	authorship	authorship	NOUN
eurjchem-2279	132	3	contribution	contribution	NOUN
eurjchem-2279	132	4	statement	statement	NOUN
eurjchem-2279	132	5	conceptualization	conceptualization	NOUN
eurjchem-2279	132	6	:	:	PUNCT
eurjchem-2279	132	7	brock	brock	PROPN
eurjchem-2279	132	8	anton	anton	PROPN
eurjchem-2279	132	9	stenfors	stenfor	NOUN
eurjchem-2279	132	10	,	,	PUNCT
eurjchem-2279	132	11	felix	felix	PROPN
eurjchem-2279	132	12	nyuangem	nyuangem	PROPN
eurjchem-2279	132	13	ngassa	ngassa	NOUN
eurjchem-2279	132	14	;	;	PUNCT
eurjchem-2279	132	15	methodology	methodology	NOUN
eurjchem-2279	132	16	:	:	PUNCT
eurjchem-2279	132	17	brock	brock	PROPN
eurjchem-2279	132	18	anton	anton	PROPN
eurjchem-2279	132	19	stenfors	stenfor	NOUN
eurjchem-2279	132	20	,	,	PUNCT
eurjchem-2279	132	21	felix	felix	PROPN
eurjchem-2279	132	22	nyuangem	nyuangem	PROPN
eurjchem-2279	132	23	ngassa	ngassa	NOUN
eurjchem-2279	132	24	;	;	PUNCT
eurjchem-2279	132	25	software	software	NOUN
eurjchem-2279	132	26	:	:	PUNCT
eurjchem-2279	132	27	brock	brock	PROPN
eurjchem-2279	132	28	anton	anton	PROPN
eurjchem-2279	132	29	stenfors	stenfor	NOUN
eurjchem-2279	132	30	,	,	PUNCT
eurjchem-2279	132	31	felix	felix	PROPN
eurjchem-2279	132	32	nyuangem	nyuangem	PROPN
eurjchem-2279	132	33	ngassa	ngassa	NOUN
eurjchem-2279	132	34	;	;	PUNCT
eurjchem-2279	132	35	validation	validation	NOUN
eurjchem-2279	132	36	:	:	PUNCT
eurjchem-2279	132	37	brock	brock	PROPN
eurjchem-2279	132	38	anton	anton	PROPN
eurjchem-2279	132	39	stenfors	stenfor	NOUN
eurjchem-2279	132	40	,	,	PUNCT
eurjchem-2279	132	41	felix	felix	PROPN
eurjchem-2279	132	42	nyuangem	nyuangem	PROPN
eurjchem-2279	132	43	ngassa	ngassa	NOUN
eurjchem-2279	132	44	;	;	PUNCT
eurjchem-2279	132	45	formal	formal	ADJ
eurjchem-2279	132	46	analysis	analysis	NOUN
eurjchem-2279	132	47	:	:	PUNCT
eurjchem-2279	132	48	brock	brock	PROPN
eurjchem-2279	132	49	anton	anton	PROPN
eurjchem-2279	132	50	stenfors	stenfor	NOUN
eurjchem-2279	132	51	,	,	PUNCT
eurjchem-2279	132	52	felix	felix	PROPN
eurjchem-2279	132	53	nyuangem	nyuangem	PROPN
eurjchem-2279	132	54	ngassa	ngassa	NOUN
eurjchem-2279	132	55	;	;	PUNCT
eurjchem-2279	132	56	investigation	investigation	NOUN
eurjchem-2279	132	57	:	:	PUNCT
eurjchem-2279	132	58	brock	brock	PROPN
eurjchem-2279	132	59	anton	anton	PROPN
eurjchem-2279	132	60	stenfors	stenfor	NOUN
eurjchem-2279	132	61	,	,	PUNCT
eurjchem-2279	132	62	felix	felix	PROPN
eurjchem-2279	132	63	nyuangem	nyuangem	PROPN
eurjchem-2279	132	64	ngassa	ngassa	NOUN
eurjchem-2279	132	65	;	;	PUNCT
eurjchem-2279	132	66	resources	resource	NOUN
eurjchem-2279	132	67	:	:	PUNCT
eurjchem-2279	132	68	brock	brock	PROPN
eurjchem-2279	132	69	anton	anton	PROPN
eurjchem-2279	132	70	stenfors	stenfor	NOUN
eurjchem-2279	132	71	,	,	PUNCT
eurjchem-2279	132	72	felix	felix	PROPN
eurjchem-2279	132	73	nyuangem	nyuangem	PROPN
eurjchem-2279	132	74	ngassa	ngassa	NOUN
eurjchem-2279	132	75	;	;	PUNCT
eurjchem-2279	132	76	data	datum	NOUN
eurjchem-2279	132	77	curation	curation	NOUN
eurjchem-2279	132	78	:	:	PUNCT
eurjchem-2279	132	79	brock	brock	PROPN
eurjchem-2279	132	80	anton	anton	PROPN
eurjchem-2279	132	81	stenfors	stenfor	NOUN
eurjchem-2279	132	82	,	,	PUNCT
eurjchem-2279	132	83	felix	felix	PROPN
eurjchem-2279	132	84	nyuangem	nyuangem	PROPN
eurjchem-2279	132	85	ngassa	ngassa	PROPN
eurjchem-2279	132	86	;	;	PUNCT
eurjchem-2279	132	87	writing	write	VERB
eurjchem-2279	132	88	original	original	ADJ
eurjchem-2279	132	89	draft	draft	NOUN
eurjchem-2279	132	90	:	:	PUNCT
eurjchem-2279	132	91	brock	brock	PROPN
eurjchem-2279	132	92	anton	anton	PROPN
eurjchem-2279	132	93	stenfors	stenfor	NOUN
eurjchem-2279	132	94	,	,	PUNCT
eurjchem-2279	132	95	felix	felix	PROPN
eurjchem-2279	132	96	nyuangem	nyuangem	PROPN
eurjchem-2279	132	97	ngassa	ngassa	PROPN
eurjchem-2279	132	98	;	;	PUNCT
eurjchem-2279	132	99	writing	write	VERB
eurjchem-2279	132	100	review	review	NOUN
eurjchem-2279	132	101	and	and	CCONJ
eurjchem-2279	132	102	editing	editing	NOUN
eurjchem-2279	132	103	:	:	PUNCT
eurjchem-2279	132	104	brock	brock	PROPN
eurjchem-2279	132	105	anton	anton	PROPN
eurjchem-2279	132	106	stenfors	stenfor	NOUN
eurjchem-2279	132	107	,	,	PUNCT
eurjchem-2279	132	108	felix	felix	PROPN
eurjchem-2279	132	109	nyuangem	nyuangem	PROPN
eurjchem-2279	132	110	ngassa	ngassa	NOUN
eurjchem-2279	132	111	;	;	PUNCT
eurjchem-2279	132	112	visualization	visualization	NOUN
eurjchem-2279	132	113	:	:	PUNCT
eurjchem-2279	132	114	brock	brock	PROPN
eurjchem-2279	132	115	anton	anton	PROPN
eurjchem-2279	132	116	stenfors	stenfor	NOUN
eurjchem-2279	132	117	,	,	PUNCT
eurjchem-2279	132	118	felix	felix	PROPN
eurjchem-2279	132	119	nyuangem	nyuangem	PROPN
eurjchem-2279	132	120	ngassa	ngassa	PROPN
eurjchem-2279	132	121	;	;	PUNCT
eurjchem-2279	132	122	funding	funding	NOUN
eurjchem-2279	132	123	acquisition	acquisition	NOUN
eurjchem-2279	132	124	:	:	PUNCT
eurjchem-2279	132	125	felix	felix	PROPN
eurjchem-2279	132	126	nyuangem	nyuangem	PROPN
eurjchem-2279	132	127	ngassa	ngassa	NOUN
eurjchem-2279	132	128	;	;	PUNCT
eurjchem-2279	132	129	supervision	supervision	NOUN
eurjchem-2279	132	130	:	:	PUNCT
eurjchem-2279	132	131	felix	felix	PROPN
eurjchem-2279	132	132	nyuangem	nyuangem	PROPN
eurjchem-2279	132	133	ngassa	ngassa	NOUN
eurjchem-2279	132	134	;	;	PUNCT
eurjchem-2279	132	135	project	project	NOUN
eurjchem-2279	132	136	administration	administration	NOUN
eurjchem-2279	132	137	:	:	PUNCT
eurjchem-2279	132	138	felix	felix	PROPN
eurjchem-2279	132	139	nyuangem	nyuangem	PROPN
eurjchem-2279	132	140	ngassa	ngassa	PROPN
eurjchem-2279	132	141	.	.	PUNCT
eurjchem-2279	133	1	funding	funding	NOUN
eurjchem-2279	133	2	funding	funding	NOUN
eurjchem-2279	133	3	for	for	ADP
eurjchem-2279	133	4	this	this	DET
eurjchem-2279	133	5	research	research	NOUN
eurjchem-2279	133	6	was	be	AUX
eurjchem-2279	133	7	provided	provide	VERB
eurjchem-2279	133	8	by	by	ADP
eurjchem-2279	133	9	:	:	PUNCT
eurjchem-2279	133	10	national	national	PROPN
eurjchem-2279	133	11	science	science	PROPN
eurjchem-2279	133	12	foundation	foundation	PROPN
eurjchem-2279	133	13	,	,	PUNCT
eurjchem-2279	133	14	directorate	directorate	VERB
eurjchem-2279	133	15	for	for	ADP
eurjchem-2279	133	16	mathematical	mathematical	ADJ
eurjchem-2279	133	17	and	and	CCONJ
eurjchem-2279	133	18	physical	physical	ADJ
eurjchem-2279	133	19	sciences	science	NOUN
eurjchem-2279	133	20	(	(	PUNCT
eurjchem-2279	133	21	grant	grant	VERB
eurjchem-2279	133	22	no	no	INTJ
eurjchem-2279	133	23	.	.	PUNCT
eurjchem-2279	134	1	mri	mri	PROPN
eurjchem-2279	134	2	che1725699	che1725699	NOUN
eurjchem-2279	134	3	;	;	PUNCT
eurjchem-2279	134	4	grant	grant	VERB
eurjchem-2279	134	5	no	no	PRON
eurjchem-2279	134	6	.	.	PUNCT
eurjchem-2279	134	7	mri	mri	NOUN
eurjchem-2279	134	8	che-1919817	che-1919817	NOUN
eurjchem-2279	134	9	)	)	PUNCT
eurjchem-2279	134	10	;	;	PUNCT
eurjchem-2279	134	11	gvsu	gvsu	PROPN
eurjchem-2279	134	12	chemistry	chemistry	PROPN
eurjchem-2279	134	13	department	department	PROPN
eurjchem-2279	134	14	’s	’s	PART
eurjchem-2279	134	15	weldon	weldon	PROPN
eurjchem-2279	134	16	fund	fund	PROPN
eurjchem-2279	134	17	.	.	PUNCT
eurjchem-2279	135	1	orcid	orcid	NOUN
eurjchem-2279	135	2	and	and	CCONJ
eurjchem-2279	135	3	email	email	NOUN
eurjchem-2279	135	4	brock	brock	PROPN
eurjchem-2279	135	5	anton	anton	PROPN
eurjchem-2279	135	6	stenfors	stenfors	PROPN
eurjchem-2279	135	7	stenforb@mail.gvsu.edu	stenforb@mail.gvsu.edu	PROPN
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eurjchem-2279	135	9	felix	felix	PROPN
eurjchem-2279	135	10	nyuangem	nyuangem	PROPN
eurjchem-2279	135	11	ngassa	ngassa	PROPN
eurjchem-2279	135	12	ngassaf@gvsu.edu	ngassaf@gvsu.edu	PROPN
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eurjchem-2279	136	2	references	reference	NOUN
eurjchem-2279	136	3	[	[	X
eurjchem-2279	136	4	1	1	NUM
eurjchem-2279	136	5	]	]	PUNCT
eurjchem-2279	136	6	.	.	PUNCT
eurjchem-2279	137	1	miller	miller	PROPN
eurjchem-2279	137	2	,	,	PUNCT
eurjchem-2279	137	3	s.	s.	PROPN
eurjchem-2279	137	4	c.	c.	PROPN
eurjchem-2279	137	5	profiling	profiling	NOUN
eurjchem-2279	137	6	sulfonate	sulfonate	ADJ
eurjchem-2279	137	7	ester	ester	NOUN
eurjchem-2279	137	8	stability	stability	NOUN
eurjchem-2279	137	9	:	:	PUNCT
eurjchem-2279	137	10	identification	identification	NOUN
eurjchem-2279	137	11	of	of	ADP
eurjchem-2279	137	12	complementary	complementary	ADJ
eurjchem-2279	137	13	protecting	protect	VERB
eurjchem-2279	137	14	groups	group	NOUN
eurjchem-2279	137	15	for	for	ADP
eurjchem-2279	137	16	sulfonates	sulfonate	NOUN
eurjchem-2279	137	17	.	.	PUNCT
eurjchem-2279	138	1	j.	j.	PROPN
eurjchem-2279	138	2	org	org	PROPN
eurjchem-2279	138	3	.	.	PUNCT
eurjchem-2279	138	4	chem	chem	PROPN
eurjchem-2279	138	5	.	.	PUNCT
eurjchem-2279	139	1	2010	2010	NUM
eurjchem-2279	139	2	,	,	PUNCT
eurjchem-2279	139	3	75	75	NUM
eurjchem-2279	139	4	,	,	PUNCT
eurjchem-2279	139	5	4632–4635	4632–4635	NOUN
eurjchem-2279	139	6	.	.	PUNCT
eurjchem-2279	140	1	[	[	X
eurjchem-2279	140	2	2	2	NUM
eurjchem-2279	140	3	]	]	PUNCT
eurjchem-2279	140	4	.	.	PUNCT
eurjchem-2279	140	5	crossland	crossland	PROPN
eurjchem-2279	140	6	,	,	PUNCT
eurjchem-2279	140	7	r.	r.	PROPN
eurjchem-2279	140	8	k.	k.	PROPN
eurjchem-2279	140	9	;	;	PUNCT
eurjchem-2279	140	10	wells	wells	PROPN
eurjchem-2279	140	11	,	,	PUNCT
eurjchem-2279	140	12	w.	w.	PROPN
eurjchem-2279	140	13	e.	e.	PROPN
eurjchem-2279	140	14	;	;	PUNCT
eurjchem-2279	140	15	shiner	shiner	NOUN
eurjchem-2279	140	16	,	,	PUNCT
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eurjchem-2279	140	18	j.	j.	PROPN
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eurjchem-2279	140	20	jr	jr	PROPN
eurjchem-2279	140	21	sulfonate	sulfonate	NOUN
eurjchem-2279	140	22	leaving	leave	VERB
eurjchem-2279	140	23	groups	group	NOUN
eurjchem-2279	140	24	,	,	PUNCT
eurjchem-2279	140	25	structure	structure	NOUN
eurjchem-2279	140	26	and	and	CCONJ
eurjchem-2279	140	27	reactivity	reactivity	NOUN
eurjchem-2279	140	28	.	.	PUNCT
eurjchem-2279	141	1	2,2,2	2,2,2	NUM
eurjchem-2279	141	2	-	-	NOUN
eurjchem-2279	141	3	trifluoroethanesulfonate	trifluoroethanesulfonate	NOUN
eurjchem-2279	141	4	.	.	PUNCT
eurjchem-2279	142	1	j.	j.	PROPN
eurjchem-2279	142	2	am	am	PROPN
eurjchem-2279	142	3	.	.	PUNCT
eurjchem-2279	143	1	chem	chem	NOUN
eurjchem-2279	143	2	.	.	PUNCT
eurjchem-2279	144	1	soc	soc	PROPN
eurjchem-2279	144	2	.	.	PUNCT
eurjchem-2279	145	1	1971	1971	NUM
eurjchem-2279	145	2	,	,	PUNCT
eurjchem-2279	145	3	93	93	NUM
eurjchem-2279	145	4	,	,	PUNCT
eurjchem-2279	145	5	4217–4219	4217–4219	NUM
eurjchem-2279	145	6	.	.	PUNCT
eurjchem-2279	146	1	[	[	X
eurjchem-2279	146	2	3	3	NUM
eurjchem-2279	146	3	]	]	PUNCT
eurjchem-2279	146	4	.	.	PUNCT
eurjchem-2279	147	1	el	el	PROPN
eurjchem-2279	147	2	-	-	PUNCT
eurjchem-2279	147	3	gamal	gamal	PROPN
eurjchem-2279	147	4	,	,	PUNCT
eurjchem-2279	147	5	m.	m.	NOUN
eurjchem-2279	147	6	i.	i.	PROPN
eurjchem-2279	147	7	;	;	PUNCT
eurjchem-2279	147	8	semreen	semreen	VERB
eurjchem-2279	147	9	,	,	PUNCT
eurjchem-2279	147	10	m.	m.	PROPN
eurjchem-2279	147	11	h.	h.	PROPN
eurjchem-2279	147	12	;	;	PUNCT
eurjchem-2279	147	13	foster	foster	ADJ
eurjchem-2279	147	14	,	,	PUNCT
eurjchem-2279	147	15	p.	p.	NOUN
eurjchem-2279	147	16	a.	a.	NOUN
eurjchem-2279	147	17	;	;	PUNCT
eurjchem-2279	147	18	potter	potter	PROPN
eurjchem-2279	147	19	,	,	PUNCT
eurjchem-2279	147	20	b.	b.	PROPN
eurjchem-2279	148	1	v.	v.	PROPN
eurjchem-2279	148	2	l.	l.	PROPN
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eurjchem-2279	148	4	,	,	PUNCT
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eurjchem-2279	148	6	,	,	PUNCT
eurjchem-2279	148	7	and	and	CCONJ
eurjchem-2279	148	8	biological	biological	ADJ
eurjchem-2279	148	9	evaluation	evaluation	NOUN
eurjchem-2279	148	10	of	of	ADP
eurjchem-2279	148	11	new	new	ADJ
eurjchem-2279	148	12	arylamide	arylamide	ADJ
eurjchem-2279	148	13	derivatives	derivative	NOUN
eurjchem-2279	148	14	possessing	possess	VERB
eurjchem-2279	148	15	sulfonate	sulfonate	NOUN
eurjchem-2279	148	16	or	or	CCONJ
eurjchem-2279	148	17	sulfamate	sulfamate	VERB
eurjchem-2279	148	18	moieties	moiety	NOUN
eurjchem-2279	148	19	as	as	ADP
eurjchem-2279	148	20	steroid	steroid	NOUN
eurjchem-2279	148	21	sulfatase	sulfatase	NOUN
eurjchem-2279	148	22	enzyme	enzyme	NOUN
eurjchem-2279	148	23	inhibitors	inhibitor	NOUN
eurjchem-2279	148	24	.	.	PUNCT
eurjchem-2279	149	1	bioorg	bioorg	VERB
eurjchem-2279	149	2	.	.	PUNCT
eurjchem-2279	150	1	med	med	PROPN
eurjchem-2279	150	2	.	.	PUNCT
eurjchem-2279	150	3	chem	chem	PROPN
eurjchem-2279	150	4	.	.	PUNCT
eurjchem-2279	151	1	2016	2016	NUM
eurjchem-2279	151	2	,	,	PUNCT
eurjchem-2279	151	3	24	24	NUM
eurjchem-2279	151	4	,	,	PUNCT
eurjchem-2279	151	5	2762–2767	2762–2767	NUM
eurjchem-2279	151	6	.	.	PUNCT
eurjchem-2279	152	1	[	[	X
eurjchem-2279	152	2	4	4	NUM
eurjchem-2279	152	3	]	]	PUNCT
eurjchem-2279	152	4	.	.	PUNCT
eurjchem-2279	153	1	fortin	fortin	PROPN
eurjchem-2279	153	2	,	,	PUNCT
eurjchem-2279	153	3	s.	s.	PROPN
eurjchem-2279	153	4	;	;	PUNCT
eurjchem-2279	153	5	wei	wei	PROPN
eurjchem-2279	153	6	,	,	PUNCT
eurjchem-2279	153	7	l.	l.	PROPN
eurjchem-2279	153	8	;	;	PUNCT
eurjchem-2279	153	9	moreau	moreau	PROPN
eurjchem-2279	153	10	,	,	PUNCT
eurjchem-2279	153	11	e.	e.	PROPN
eurjchem-2279	153	12	;	;	PUNCT
eurjchem-2279	153	13	lacroix	lacroix	PROPN
eurjchem-2279	153	14	,	,	PUNCT
eurjchem-2279	153	15	j.	j.	PROPN
eurjchem-2279	153	16	;	;	PUNCT
eurjchem-2279	153	17	côté	côté	PROPN
eurjchem-2279	153	18	,	,	PUNCT
eurjchem-2279	153	19	m.-f	m.-f	PROPN
eurjchem-2279	153	20	.	.	PUNCT
eurjchem-2279	153	21	;	;	PUNCT
eurjchem-2279	153	22	petitclerc	petitclerc	PROPN
eurjchem-2279	153	23	,	,	PUNCT
eurjchem-2279	153	24	e.	e.	PROPN
eurjchem-2279	153	25	;	;	PUNCT
eurjchem-2279	153	26	kotra	kotra	PROPN
eurjchem-2279	153	27	,	,	PUNCT
eurjchem-2279	153	28	l.	l.	PROPN
eurjchem-2279	153	29	p.	p.	PROPN
eurjchem-2279	153	30	;	;	PUNCT
eurjchem-2279	153	31	c	c	X
eurjchem-2279	153	32	-	-	PUNCT
eurjchem-2279	153	33	gaudreault	gaudreault	NOUN
eurjchem-2279	153	34	,	,	PUNCT
eurjchem-2279	153	35	r.	r.	PROPN
eurjchem-2279	153	36	design	design	PROPN
eurjchem-2279	153	37	,	,	PUNCT
eurjchem-2279	153	38	synthesis	synthesis	NOUN
eurjchem-2279	153	39	,	,	PUNCT
eurjchem-2279	153	40	biological	biological	ADJ
eurjchem-2279	153	41	evaluation	evaluation	NOUN
eurjchem-2279	153	42	,	,	PUNCT
eurjchem-2279	153	43	and	and	CCONJ
eurjchem-2279	153	44	structure	structure	NOUN
eurjchem-2279	153	45	-	-	PUNCT
eurjchem-2279	153	46	activity	activity	NOUN
eurjchem-2279	153	47	relationships	relationship	NOUN
eurjchem-2279	153	48	of	of	ADP
eurjchem-2279	153	49	substituted	substitute	VERB
eurjchem-2279	153	50	phenyl	phenyl	NOUN
eurjchem-2279	153	51	4-(2oxoimidazolidin-1	4-(2oxoimidazolidin-1	PROPN
eurjchem-2279	153	52	-	-	PUNCT
eurjchem-2279	153	53	yl)benzenesulfonates	yl)benzenesulfonate	NOUN
eurjchem-2279	153	54	as	as	ADP
eurjchem-2279	153	55	new	new	ADJ
eurjchem-2279	153	56	tubulin	tubulin	NOUN
eurjchem-2279	153	57	inhibitors	inhibitor	NOUN
eurjchem-2279	153	58	mimicking	mimic	VERB
eurjchem-2279	153	59	combretastatin	combretastatin	PROPN
eurjchem-2279	153	60	a-4	a-4	PROPN
eurjchem-2279	153	61	.	.	PUNCT
eurjchem-2279	154	1	j.	j.	PROPN
eurjchem-2279	154	2	med	med	PROPN
eurjchem-2279	154	3	.	.	PROPN
eurjchem-2279	154	4	chem	chem	PROPN
eurjchem-2279	154	5	.	.	PUNCT
eurjchem-2279	155	1	2011	2011	NUM
eurjchem-2279	155	2	,	,	PUNCT
eurjchem-2279	155	3	54	54	NUM
eurjchem-2279	155	4	,	,	PUNCT
eurjchem-2279	155	5	4559–4580	4559–4580	NOUN
eurjchem-2279	155	6	.	.	PUNCT
eurjchem-2279	156	1	[	[	X
eurjchem-2279	156	2	5	5	NUM
eurjchem-2279	156	3	]	]	PUNCT
eurjchem-2279	156	4	.	.	PUNCT
eurjchem-2279	157	1	castro	castro	PROPN
eurjchem-2279	157	2	,	,	PUNCT
eurjchem-2279	157	3	e.	e.	PROPN
eurjchem-2279	157	4	a.	a.	PROPN
eurjchem-2279	157	5	;	;	PUNCT
eurjchem-2279	157	6	andújar	andújar	NOUN
eurjchem-2279	157	7	,	,	PUNCT
eurjchem-2279	157	8	m.	m.	NOUN
eurjchem-2279	157	9	;	;	PUNCT
eurjchem-2279	157	10	toro	toro	PROPN
eurjchem-2279	157	11	,	,	PUNCT
eurjchem-2279	157	12	a.	a.	NOUN
eurjchem-2279	157	13	;	;	PUNCT
eurjchem-2279	157	14	santos	santos	PROPN
eurjchem-2279	157	15	,	,	PUNCT
eurjchem-2279	157	16	j.	j.	PROPN
eurjchem-2279	157	17	g.	g.	PROPN
eurjchem-2279	157	18	kinetics	kinetics	PROPN
eurjchem-2279	157	19	and	and	CCONJ
eurjchem-2279	157	20	mechanism	mechanism	NOUN
eurjchem-2279	157	21	of	of	ADP
eurjchem-2279	157	22	the	the	DET
eurjchem-2279	157	23	aminolysis	aminolysis	NOUN
eurjchem-2279	157	24	of	of	ADP
eurjchem-2279	157	25	4	4	NUM
eurjchem-2279	157	26	-	-	PUNCT
eurjchem-2279	157	27	methylphenyl	methylphenyl	NOUN
eurjchem-2279	157	28	and	and	CCONJ
eurjchem-2279	157	29	4	4	NUM
eurjchem-2279	157	30	-	-	PUNCT
eurjchem-2279	157	31	chlorophenyl	chlorophenyl	ADJ
eurjchem-2279	157	32	4nitrophenyl	4nitrophenyl	NUM
eurjchem-2279	157	33	carbonates	carbonate	NOUN
eurjchem-2279	157	34	in	in	ADP
eurjchem-2279	157	35	aqueous	aqueous	ADJ
eurjchem-2279	157	36	ethanol	ethanol	NOUN
eurjchem-2279	157	37	.	.	PUNCT
eurjchem-2279	158	1	j.	j.	PROPN
eurjchem-2279	158	2	org	org	PROPN
eurjchem-2279	158	3	.	.	PUNCT
eurjchem-2279	158	4	chem	chem	PROPN
eurjchem-2279	158	5	.	.	PUNCT
eurjchem-2279	159	1	2003	2003	NUM
eurjchem-2279	159	2	,	,	PUNCT
eurjchem-2279	159	3	68	68	NUM
eurjchem-2279	159	4	,	,	PUNCT
eurjchem-2279	159	5	3608–3613	3608–3613	NUM
eurjchem-2279	159	6	.	.	PUNCT
eurjchem-2279	160	1	[	[	X
eurjchem-2279	160	2	6	6	NUM
eurjchem-2279	160	3	]	]	PUNCT
eurjchem-2279	160	4	.	.	PUNCT
eurjchem-2279	161	1	terrier	terrier	NOUN
eurjchem-2279	161	2	,	,	PUNCT
eurjchem-2279	161	3	f.	f.	PROPN
eurjchem-2279	161	4	;	;	PUNCT
eurjchem-2279	161	5	le	le	X
eurjchem-2279	161	6	guével	guével	PROPN
eurjchem-2279	161	7	,	,	PUNCT
eurjchem-2279	161	8	e.	e.	PROPN
eurjchem-2279	161	9	;	;	PUNCT
eurjchem-2279	161	10	chatrousse	chatrousse	PROPN
eurjchem-2279	161	11	,	,	PUNCT
eurjchem-2279	161	12	a.	a.	NOUN
eurjchem-2279	161	13	p.	p.	NOUN
eurjchem-2279	161	14	;	;	PUNCT
eurjchem-2279	161	15	moutiers	moutier	NOUN
eurjchem-2279	161	16	,	,	PUNCT
eurjchem-2279	161	17	g.	g.	PROPN
eurjchem-2279	161	18	;	;	PUNCT
eurjchem-2279	161	19	buncel	buncel	PROPN
eurjchem-2279	161	20	,	,	PUNCT
eurjchem-2279	161	21	e.	e.	PROPN
eurjchem-2279	161	22	the	the	DET
eurjchem-2279	161	23	levelling	levelling	NOUN
eurjchem-2279	161	24	effect	effect	NOUN
eurjchem-2279	161	25	of	of	ADP
eurjchem-2279	161	26	solvational	solvational	ADJ
eurjchem-2279	161	27	imbalances	imbalance	NOUN
eurjchem-2279	161	28	in	in	ADP
eurjchem-2279	161	29	the	the	DET
eurjchem-2279	161	30	reactions	reaction	NOUN
eurjchem-2279	161	31	of	of	ADP
eurjchem-2279	161	32	oximate	oximate	NOUN
eurjchem-2279	161	33	αnucleophiles	αnucleophile	NOUN
eurjchem-2279	161	34	with	with	ADP
eurjchem-2279	161	35	electrophilic	electrophilic	ADJ
eurjchem-2279	161	36	phosphorus	phosphorus	NOUN
eurjchem-2279	161	37	centers	center	NOUN
eurjchem-2279	161	38	.	.	PUNCT
eurjchem-2279	162	1	relevance	relevance	NOUN
eurjchem-2279	162	2	to	to	ADP
eurjchem-2279	162	3	detoxification	detoxification	NOUN
eurjchem-2279	162	4	of	of	ADP
eurjchem-2279	162	5	organophosphorus	organophosphorus	NOUN
eurjchem-2279	162	6	esters	ester	NOUN
eurjchem-2279	162	7	.	.	PUNCT
eurjchem-2279	163	1	chem	chem	NOUN
eurjchem-2279	163	2	.	.	PUNCT
eurjchem-2279	164	1	commun	commun	PROPN
eurjchem-2279	164	2	.	.	PUNCT
eurjchem-2279	165	1	(	(	PUNCT
eurjchem-2279	165	2	camb	camb	PROPN
eurjchem-2279	165	3	.	.	PUNCT
eurjchem-2279	165	4	)	)	PUNCT
eurjchem-2279	166	1	2003	2003	NUM
eurjchem-2279	166	2	,	,	PUNCT
eurjchem-2279	166	3	600–601	600–601	NUM
eurjchem-2279	166	4	.	.	PUNCT
eurjchem-2279	167	1	[	[	X
eurjchem-2279	167	2	7	7	NUM
eurjchem-2279	167	3	]	]	PUNCT
eurjchem-2279	167	4	.	.	PUNCT
eurjchem-2279	168	1	um	um	INTJ
eurjchem-2279	168	2	,	,	PUNCT
eurjchem-2279	168	3	i.-h	i.-h	PROPN
eurjchem-2279	168	4	.	.	PUNCT
eurjchem-2279	168	5	;	;	PUNCT
eurjchem-2279	169	1	chun	chun	PROPN
eurjchem-2279	169	2	,	,	PUNCT
eurjchem-2279	169	3	s.-m	s.-m	PROPN
eurjchem-2279	169	4	.	.	PUNCT
eurjchem-2279	169	5	;	;	PUNCT
eurjchem-2279	169	6	chae	chae	NOUN
eurjchem-2279	169	7	,	,	PUNCT
eurjchem-2279	169	8	o.-m	o.-m	PROPN
eurjchem-2279	169	9	.	.	PUNCT
eurjchem-2279	169	10	;	;	PUNCT
eurjchem-2279	169	11	fujio	fujio	ADJ
eurjchem-2279	169	12	,	,	PUNCT
eurjchem-2279	169	13	m.	m.	NOUN
eurjchem-2279	169	14	;	;	PUNCT
eurjchem-2279	169	15	tsuno	tsuno	PROPN
eurjchem-2279	169	16	,	,	PUNCT
eurjchem-2279	169	17	y.	y.	NOUN
eurjchem-2279	169	18	effect	effect	NOUN
eurjchem-2279	169	19	of	of	ADP
eurjchem-2279	169	20	amine	amine	ADJ
eurjchem-2279	169	21	nature	nature	NOUN
eurjchem-2279	169	22	on	on	ADP
eurjchem-2279	169	23	reaction	reaction	NOUN
eurjchem-2279	169	24	rate	rate	NOUN
eurjchem-2279	169	25	and	and	CCONJ
eurjchem-2279	169	26	mechanism	mechanism	NOUN
eurjchem-2279	169	27	in	in	ADP
eurjchem-2279	169	28	nucleophilic	nucleophilic	ADJ
eurjchem-2279	169	29	substitution	substitution	NOUN
eurjchem-2279	169	30	reactions	reaction	NOUN
eurjchem-2279	169	31	of	of	ADP
eurjchem-2279	169	32	2,4	2,4	NUM
eurjchem-2279	169	33	-	-	PUNCT
eurjchem-2279	169	34	dinitrophenyl	dinitrophenyl	ADJ
eurjchem-2279	169	35	x	x	ADJ
eurjchem-2279	169	36	-	-	PUNCT
eurjchem-2279	169	37	substituted	substitute	VERB
eurjchem-2279	169	38	benzenesulfonates	benzenesulfonate	NOUN
eurjchem-2279	169	39	with	with	ADP
eurjchem-2279	169	40	alicyclic	alicyclic	ADJ
eurjchem-2279	169	41	secondary	secondary	ADJ
eurjchem-2279	169	42	amines	amine	NOUN
eurjchem-2279	169	43	.	.	PUNCT
eurjchem-2279	170	1	j.	j.	PROPN
eurjchem-2279	170	2	org	org	PROPN
eurjchem-2279	170	3	.	.	PUNCT
eurjchem-2279	170	4	chem	chem	PROPN
eurjchem-2279	170	5	.	.	PUNCT
eurjchem-2279	171	1	2004	2004	NUM
eurjchem-2279	171	2	,	,	PUNCT
eurjchem-2279	171	3	69	69	NUM
eurjchem-2279	171	4	,	,	PUNCT
eurjchem-2279	171	5	3166–3172	3166–3172	NUM
eurjchem-2279	171	6	.	.	PUNCT
eurjchem-2279	172	1	[	[	X
eurjchem-2279	172	2	8	8	NUM
eurjchem-2279	172	3	]	]	PUNCT
eurjchem-2279	172	4	.	.	PUNCT
eurjchem-2279	173	1	qrareya	qrareya	PROPN
eurjchem-2279	173	2	,	,	PUNCT
eurjchem-2279	173	3	h.	h.	PROPN
eurjchem-2279	173	4	;	;	PUNCT
eurjchem-2279	173	5	protti	protti	PROPN
eurjchem-2279	173	6	,	,	PUNCT
eurjchem-2279	173	7	s.	s.	PROPN
eurjchem-2279	173	8	;	;	PUNCT
eurjchem-2279	173	9	fagnoni	fagnoni	NOUN
eurjchem-2279	173	10	,	,	PUNCT
eurjchem-2279	173	11	m.	m.	NOUN
eurjchem-2279	173	12	aryl	aryl	NOUN
eurjchem-2279	173	13	imidazylates	imidazylate	NOUN
eurjchem-2279	173	14	and	and	CCONJ
eurjchem-2279	173	15	aryl	aryl	NOUN
eurjchem-2279	173	16	sulfates	sulfate	NOUN
eurjchem-2279	173	17	as	as	ADP
eurjchem-2279	173	18	electrophiles	electrophile	NOUN
eurjchem-2279	173	19	in	in	ADP
eurjchem-2279	173	20	metal	metal	NOUN
eurjchem-2279	173	21	-	-	PUNCT
eurjchem-2279	173	22	free	free	ADJ
eurjchem-2279	173	23	ars(n)1	ars(n)1	ADJ
eurjchem-2279	173	24	reactions	reaction	NOUN
eurjchem-2279	173	25	.	.	PUNCT
eurjchem-2279	174	1	j.	j.	PROPN
eurjchem-2279	174	2	org	org	PROPN
eurjchem-2279	174	3	.	.	PUNCT
eurjchem-2279	174	4	chem	chem	PROPN
eurjchem-2279	174	5	.	.	PUNCT
eurjchem-2279	175	1	2014	2014	NUM
eurjchem-2279	175	2	,	,	PUNCT
eurjchem-2279	175	3	79	79	NUM
eurjchem-2279	175	4	,	,	PUNCT
eurjchem-2279	175	5	11527–11533	11527–11533	NUM
eurjchem-2279	175	6	.	.	PUNCT
eurjchem-2279	176	1	[	[	X
eurjchem-2279	176	2	9	9	NUM
eurjchem-2279	176	3	]	]	PUNCT
eurjchem-2279	176	4	.	.	PUNCT
eurjchem-2279	176	5	stefanidis	stefanidis	PROPN
eurjchem-2279	176	6	,	,	PUNCT
eurjchem-2279	176	7	d.	d.	PROPN
eurjchem-2279	176	8	;	;	PUNCT
eurjchem-2279	176	9	cho	cho	PROPN
eurjchem-2279	176	10	,	,	PUNCT
eurjchem-2279	176	11	s.	s.	PROPN
eurjchem-2279	176	12	;	;	PUNCT
eurjchem-2279	176	13	dhe	dhe	PROPN
eurjchem-2279	176	14	-	-	PUNCT
eurjchem-2279	176	15	paganon	paganon	NOUN
eurjchem-2279	176	16	,	,	PUNCT
eurjchem-2279	176	17	s.	s.	PROPN
eurjchem-2279	176	18	;	;	PUNCT
eurjchem-2279	176	19	jencks	jenck	NOUN
eurjchem-2279	176	20	,	,	PUNCT
eurjchem-2279	176	21	w.	w.	PROPN
eurjchem-2279	176	22	p.	p.	PROPN
eurjchem-2279	176	23	structurereactivity	structurereactivity	PROPN
eurjchem-2279	176	24	correlations	correlation	NOUN
eurjchem-2279	176	25	for	for	ADP
eurjchem-2279	176	26	reactions	reaction	NOUN
eurjchem-2279	176	27	of	of	ADP
eurjchem-2279	176	28	substituted	substitute	VERB
eurjchem-2279	176	29	phenolate	phenolate	NOUN
eurjchem-2279	176	30	anions	anion	NOUN
eurjchem-2279	176	31	with	with	ADP
eurjchem-2279	176	32	acetate	acetate	NOUN
eurjchem-2279	176	33	and	and	CCONJ
eurjchem-2279	176	34	formate	formate	NOUN
eurjchem-2279	176	35	esters	ester	NOUN
eurjchem-2279	176	36	.	.	PUNCT
eurjchem-2279	177	1	j.	j.	PROPN
eurjchem-2279	177	2	am	am	PROPN
eurjchem-2279	177	3	.	.	PUNCT
eurjchem-2279	178	1	chem	chem	NOUN
eurjchem-2279	178	2	.	.	PUNCT
eurjchem-2279	179	1	soc	soc	PROPN
eurjchem-2279	179	2	.	.	PUNCT
eurjchem-2279	180	1	1993	1993	NUM
eurjchem-2279	180	2	,	,	PUNCT
eurjchem-2279	180	3	115	115	NUM
eurjchem-2279	180	4	,	,	PUNCT
eurjchem-2279	180	5	1650	1650	NUM
eurjchem-2279	180	6	–	–	PUNCT
eurjchem-2279	180	7	1656	1656	NUM
eurjchem-2279	180	8	.	.	PUNCT
eurjchem-2279	181	1	[	[	X
eurjchem-2279	181	2	10	10	NUM
eurjchem-2279	181	3	]	]	PUNCT
eurjchem-2279	181	4	.	.	PUNCT
eurjchem-2279	182	1	lee	lee	PROPN
eurjchem-2279	182	2	,	,	PUNCT
eurjchem-2279	182	3	h.	h.	PROPN
eurjchem-2279	182	4	w.	w.	PROPN
eurjchem-2279	182	5	;	;	PUNCT
eurjchem-2279	182	6	guha	guha	PROPN
eurjchem-2279	182	7	,	,	PUNCT
eurjchem-2279	182	8	a.	a.	PROPN
eurjchem-2279	182	9	k.	k.	PROPN
eurjchem-2279	182	10	;	;	PUNCT
eurjchem-2279	182	11	kim	kim	PROPN
eurjchem-2279	182	12	,	,	PUNCT
eurjchem-2279	182	13	c.	c.	PROPN
eurjchem-2279	182	14	k.	k.	PROPN
eurjchem-2279	182	15	;	;	PUNCT
eurjchem-2279	182	16	lee	lee	PROPN
eurjchem-2279	182	17	,	,	PUNCT
eurjchem-2279	182	18	i.	i.	PROPN
eurjchem-2279	182	19	transition	transition	PROPN
eurjchem-2279	182	20	-	-	PUNCT
eurjchem-2279	182	21	state	state	NOUN
eurjchem-2279	182	22	variation	variation	NOUN
eurjchem-2279	182	23	in	in	ADP
eurjchem-2279	182	24	the	the	DET
eurjchem-2279	182	25	nucleophilic	nucleophilic	ADJ
eurjchem-2279	182	26	substitution	substitution	NOUN
eurjchem-2279	182	27	reactions	reaction	NOUN
eurjchem-2279	182	28	of	of	ADP
eurjchem-2279	182	29	aryl	aryl	PROPN
eurjchem-2279	182	30	bis(4	bis(4	NOUN
eurjchem-2279	182	31	-	-	PUNCT
eurjchem-2279	182	32	methoxyphenyl	methoxyphenyl	NOUN
eurjchem-2279	182	33	)	)	PUNCT
eurjchem-2279	182	34	phosphates	phosphate	NOUN
eurjchem-2279	182	35	with	with	ADP
eurjchem-2279	182	36	pyridines	pyridine	NOUN
eurjchem-2279	182	37	in	in	ADP
eurjchem-2279	182	38	acetonitrile	acetonitrile	NOUN
eurjchem-2279	182	39	.	.	PUNCT
eurjchem-2279	183	1	j.	j.	PROPN
eurjchem-2279	183	2	org	org	PROPN
eurjchem-2279	183	3	.	.	PUNCT
eurjchem-2279	184	1	chem	chem	PROPN
eurjchem-2279	184	2	.	.	PUNCT
eurjchem-2279	185	1	2002	2002	NUM
eurjchem-2279	185	2	,	,	PUNCT
eurjchem-2279	185	3	67	67	NUM
eurjchem-2279	185	4	,	,	PUNCT
eurjchem-2279	185	5	2215–2222	2215–2222	NUM
eurjchem-2279	185	6	.	.	PUNCT
eurjchem-2279	186	1	[	[	X
eurjchem-2279	186	2	11	11	NUM
eurjchem-2279	186	3	]	]	PUNCT
eurjchem-2279	186	4	.	.	PUNCT
eurjchem-2279	186	5	ratushnyy	ratushnyy	NOUN
eurjchem-2279	186	6	,	,	PUNCT
eurjchem-2279	186	7	m.	m.	NOUN
eurjchem-2279	186	8	;	;	PUNCT
eurjchem-2279	186	9	kamenova	kamenova	X
eurjchem-2279	186	10	,	,	PUNCT
eurjchem-2279	186	11	m.	m.	NOUN
eurjchem-2279	186	12	;	;	PUNCT
eurjchem-2279	186	13	gevorgyan	gevorgyan	PROPN
eurjchem-2279	186	14	,	,	PUNCT
eurjchem-2279	186	15	v.	v.	ADP
eurjchem-2279	186	16	a	a	DET
eurjchem-2279	186	17	mild	mild	ADJ
eurjchem-2279	186	18	light	light	ADJ
eurjchem-2279	186	19	-	-	PUNCT
eurjchem-2279	186	20	induced	induce	VERB
eurjchem-2279	186	21	cleavage	cleavage	NOUN
eurjchem-2279	186	22	of	of	ADP
eurjchem-2279	186	23	the	the	DET
eurjchem-2279	186	24	s	s	PROPN
eurjchem-2279	186	25	-	-	NOUN
eurjchem-2279	186	26	o	o	NOUN
eurjchem-2279	186	27	bond	bond	NOUN
eurjchem-2279	186	28	of	of	ADP
eurjchem-2279	186	29	aryl	aryl	NOUN
eurjchem-2279	186	30	sulfonate	sulfonate	ADJ
eurjchem-2279	186	31	esters	ester	NOUN
eurjchem-2279	186	32	enables	enable	VERB
eurjchem-2279	186	33	efficient	efficient	ADJ
eurjchem-2279	186	34	sulfonylation	sulfonylation	NOUN
eurjchem-2279	186	35	of	of	ADP
eurjchem-2279	186	36	vinylarenes	vinylarene	NOUN
eurjchem-2279	186	37	.	.	PUNCT
eurjchem-2279	187	1	chem	chem	NOUN
eurjchem-2279	187	2	.	.	PUNCT
eurjchem-2279	188	1	sci	sci	PROPN
eurjchem-2279	188	2	.	.	PROPN
eurjchem-2279	188	3	2018	2018	NUM
eurjchem-2279	188	4	,	,	PUNCT
eurjchem-2279	188	5	9	9	NUM
eurjchem-2279	188	6	,	,	PUNCT
eurjchem-2279	188	7	7193–7197	7193–7197	NOUN
eurjchem-2279	188	8	.	.	PUNCT
eurjchem-2279	189	1	[	[	X
eurjchem-2279	189	2	12	12	NUM
eurjchem-2279	189	3	]	]	PUNCT
eurjchem-2279	189	4	.	.	PUNCT
eurjchem-2279	190	1	atanasova	atanasova	PROPN
eurjchem-2279	190	2	,	,	PUNCT
eurjchem-2279	190	3	t.	t.	PROPN
eurjchem-2279	190	4	p.	p.	PROPN
eurjchem-2279	190	5	;	;	PUNCT
eurjchem-2279	191	1	riley	riley	PROPN
eurjchem-2279	191	2	,	,	PUNCT
eurjchem-2279	191	3	s.	s.	PROPN
eurjchem-2279	191	4	;	;	PUNCT
eurjchem-2279	191	5	biros	biros	PROPN
eurjchem-2279	191	6	,	,	PUNCT
eurjchem-2279	191	7	s.	s.	PROPN
eurjchem-2279	191	8	m.	m.	PROPN
eurjchem-2279	191	9	;	;	PUNCT
eurjchem-2279	191	10	staples	staple	NOUN
eurjchem-2279	191	11	,	,	PUNCT
eurjchem-2279	191	12	r.	r.	PROPN
eurjchem-2279	191	13	j.	j.	PROPN
eurjchem-2279	191	14	;	;	PUNCT
eurjchem-2279	191	15	ngassa	ngassa	NOUN
eurjchem-2279	191	16	,	,	PUNCT
eurjchem-2279	191	17	f.	f.	PROPN
eurjchem-2279	191	18	n.	n.	PROPN
eurjchem-2279	191	19	crystal	crystal	PROPN
eurjchem-2279	191	20	structure	structure	NOUN
eurjchem-2279	191	21	of	of	ADP
eurjchem-2279	191	22	3,5	3,5	NUM
eurjchem-2279	191	23	-	-	PUNCT
eurjchem-2279	191	24	di	di	NOUN
eurjchem-2279	191	25	-	-	PUNCT
eurjchem-2279	191	26	methyl	methyl	NOUN
eurjchem-2279	191	27	-	-	PUNCT
eurjchem-2279	191	28	phenyl	phenyl	NOUN
eurjchem-2279	191	29	2	2	NUM
eurjchem-2279	191	30	-	-	PUNCT
eurjchem-2279	191	31	nitro	nitro	NOUN
eurjchem-2279	191	32	-	-	PUNCT
eurjchem-2279	191	33	benzene	benzene	NOUN
eurjchem-2279	191	34	-	-	PUNCT
eurjchem-2279	191	35	sulfonate	sulfonate	NOUN
eurjchem-2279	191	36	.	.	PUNCT
eurjchem-2279	192	1	acta	acta	PROPN
eurjchem-2279	192	2	crystallogr	crystallogr	PROPN
eurjchem-2279	192	3	.	.	PUNCT
eurjchem-2279	193	1	e	e	PROPN
eurjchem-2279	193	2	crystallogr	crystallogr	PROPN
eurjchem-2279	193	3	.	.	PUNCT
eurjchem-2279	194	1	commun	commun	PROPN
eurjchem-2279	194	2	.	.	PROPN
eurjchem-2279	195	1	2015	2015	NUM
eurjchem-2279	195	2	,	,	PUNCT
eurjchem-2279	195	3	71	71	NUM
eurjchem-2279	195	4	,	,	PUNCT
eurjchem-2279	195	5	1045–1047	1045–1047	NUM
eurjchem-2279	195	6	.	.	PUNCT
eurjchem-2279	196	1	[	[	X
eurjchem-2279	196	2	13	13	NUM
eurjchem-2279	196	3	]	]	PUNCT
eurjchem-2279	196	4	.	.	PUNCT
eurjchem-2279	197	1	riley	riley	PROPN
eurjchem-2279	197	2	,	,	PUNCT
eurjchem-2279	197	3	s.	s.	PROPN
eurjchem-2279	197	4	;	;	PUNCT
eurjchem-2279	197	5	staples	staple	NOUN
eurjchem-2279	197	6	,	,	PUNCT
eurjchem-2279	197	7	r.	r.	PROPN
eurjchem-2279	197	8	j.	j.	PROPN
eurjchem-2279	197	9	;	;	PUNCT
eurjchem-2279	197	10	biros	biros	PROPN
eurjchem-2279	197	11	,	,	PUNCT
eurjchem-2279	197	12	s.	s.	PROPN
eurjchem-2279	197	13	m.	m.	PROPN
eurjchem-2279	197	14	;	;	PUNCT
eurjchem-2279	197	15	ngassa	ngassa	NOUN
eurjchem-2279	197	16	,	,	PUNCT
eurjchem-2279	197	17	f.	f.	PROPN
eurjchem-2279	197	18	n.	n.	PROPN
eurjchem-2279	197	19	crystal	crystal	PROPN
eurjchem-2279	197	20	structure	structure	NOUN
eurjchem-2279	197	21	of	of	ADP
eurjchem-2279	197	22	phenyl	phenyl	NOUN
eurjchem-2279	197	23	2,4,5	2,4,5	NUM
eurjchem-2279	197	24	-	-	PUNCT
eurjchem-2279	197	25	tri	tri	ADJ
eurjchem-2279	197	26	-	-	ADJ
eurjchem-2279	197	27	chloro	chloro	NOUN
eurjchem-2279	197	28	-	-	PUNCT
eurjchem-2279	197	29	benzene	benzene	NOUN
eurjchem-2279	197	30	-	-	PUNCT
eurjchem-2279	197	31	sulfonate	sulfonate	NOUN
eurjchem-2279	197	32	.	.	PUNCT
eurjchem-2279	198	1	acta	acta	PROPN
eurjchem-2279	198	2	crystallogr	crystallogr	PROPN
eurjchem-2279	198	3	.	.	PUNCT
eurjchem-2279	199	1	e	e	PROPN
eurjchem-2279	199	2	crystallogr	crystallogr	PROPN
eurjchem-2279	199	3	.	.	PUNCT
eurjchem-2279	200	1	commun	commun	PROPN
eurjchem-2279	200	2	.	.	PROPN
eurjchem-2279	201	1	2016	2016	NUM
eurjchem-2279	201	2	,	,	PUNCT
eurjchem-2279	201	3	72	72	NUM
eurjchem-2279	201	4	,	,	PUNCT
eurjchem-2279	201	5	789–792	789–792	NUM
eurjchem-2279	201	6	.	.	PUNCT
eurjchem-2279	202	1	[	[	X
eurjchem-2279	202	2	14	14	NUM
eurjchem-2279	202	3	]	]	PUNCT
eurjchem-2279	202	4	.	.	PUNCT
eurjchem-2279	203	1	supuran	supuran	NOUN
eurjchem-2279	203	2	,	,	PUNCT
eurjchem-2279	203	3	c.	c.	PROPN
eurjchem-2279	203	4	t.	t.	PROPN
eurjchem-2279	203	5	;	;	PUNCT
eurjchem-2279	203	6	casini	casini	PROPN
eurjchem-2279	203	7	,	,	PUNCT
eurjchem-2279	203	8	a.	a.	NOUN
eurjchem-2279	203	9	;	;	PUNCT
eurjchem-2279	203	10	scozzafava	scozzafava	NOUN
eurjchem-2279	203	11	,	,	PUNCT
eurjchem-2279	203	12	a.	a.	NOUN
eurjchem-2279	203	13	protease	protease	NOUN
eurjchem-2279	203	14	inhibitors	inhibitor	NOUN
eurjchem-2279	203	15	of	of	ADP
eurjchem-2279	203	16	the	the	DET
eurjchem-2279	203	17	sulfonamide	sulfonamide	NOUN
eurjchem-2279	203	18	type	type	NOUN
eurjchem-2279	203	19	:	:	PUNCT
eurjchem-2279	203	20	anticancer	anticancer	NOUN
eurjchem-2279	203	21	,	,	PUNCT
eurjchem-2279	203	22	antiinflammatory	antiinflammatory	NOUN
eurjchem-2279	203	23	,	,	PUNCT
eurjchem-2279	203	24	and	and	CCONJ
eurjchem-2279	203	25	antiviral	antiviral	ADJ
eurjchem-2279	203	26	agents	agent	NOUN
eurjchem-2279	203	27	.	.	PUNCT
eurjchem-2279	204	1	med	med	PROPN
eurjchem-2279	204	2	.	.	PUNCT
eurjchem-2279	205	1	res	re	NOUN
eurjchem-2279	205	2	.	.	PUNCT
eurjchem-2279	206	1	rev	rev	PROPN
eurjchem-2279	206	2	.	.	PROPN
eurjchem-2279	206	3	2003	2003	NUM
eurjchem-2279	206	4	,	,	PUNCT
eurjchem-2279	206	5	23	23	NUM
eurjchem-2279	206	6	,	,	PUNCT
eurjchem-2279	206	7	535–558	535–558	NUM
eurjchem-2279	206	8	.	.	PUNCT
eurjchem-2279	207	1	[	[	X
eurjchem-2279	207	2	15	15	NUM
eurjchem-2279	207	3	]	]	PUNCT
eurjchem-2279	207	4	.	.	PUNCT
eurjchem-2279	208	1	mirza	mirza	PROPN
eurjchem-2279	208	2	,	,	PUNCT
eurjchem-2279	208	3	a.	a.	PROPN
eurjchem-2279	208	4	;	;	PUNCT
eurjchem-2279	208	5	desai	desai	PROPN
eurjchem-2279	208	6	,	,	PUNCT
eurjchem-2279	208	7	r.	r.	PROPN
eurjchem-2279	208	8	;	;	PUNCT
eurjchem-2279	208	9	reynisson	reynisson	PROPN
eurjchem-2279	208	10	,	,	PUNCT
eurjchem-2279	208	11	j.	j.	PROPN
eurjchem-2279	208	12	known	know	VERB
eurjchem-2279	208	13	drug	drug	NOUN
eurjchem-2279	208	14	space	space	NOUN
eurjchem-2279	208	15	as	as	ADP
eurjchem-2279	208	16	a	a	DET
eurjchem-2279	208	17	metric	metric	NOUN
eurjchem-2279	208	18	in	in	ADP
eurjchem-2279	208	19	exploring	explore	VERB
eurjchem-2279	208	20	the	the	DET
eurjchem-2279	208	21	boundaries	boundary	NOUN
eurjchem-2279	208	22	of	of	ADP
eurjchem-2279	208	23	drug	drug	NOUN
eurjchem-2279	208	24	-	-	PUNCT
eurjchem-2279	208	25	like	like	ADJ
eurjchem-2279	208	26	chemical	chemical	NOUN
eurjchem-2279	208	27	space	space	NOUN
eurjchem-2279	208	28	.	.	PUNCT
eurjchem-2279	209	1	eur	eur	PROPN
eurjchem-2279	209	2	.	.	PUNCT
eurjchem-2279	210	1	j.	j.	PROPN
eurjchem-2279	210	2	med	med	PROPN
eurjchem-2279	210	3	.	.	PROPN
eurjchem-2279	210	4	chem	chem	PROPN
eurjchem-2279	210	5	.	.	PUNCT
eurjchem-2279	211	1	2009	2009	NUM
eurjchem-2279	211	2	,	,	PUNCT
eurjchem-2279	211	3	44	44	NUM
eurjchem-2279	211	4	,	,	PUNCT
eurjchem-2279	211	5	5006–5011	5006–5011	NUM
eurjchem-2279	211	6	.	.	PUNCT
eurjchem-2279	212	1	[	[	X
eurjchem-2279	212	2	16	16	NUM
eurjchem-2279	212	3	]	]	PUNCT
eurjchem-2279	212	4	.	.	PUNCT
eurjchem-2279	213	1	willcott	willcott	PROPN
eurjchem-2279	213	2	,	,	PUNCT
eurjchem-2279	213	3	m.	m.	PROPN
eurjchem-2279	213	4	r.	r.	PROPN
eurjchem-2279	213	5	mestre	mestre	PROPN
eurjchem-2279	213	6	nova	nova	PROPN
eurjchem-2279	213	7	.	.	PUNCT
eurjchem-2279	214	1	j.	j.	PROPN
eurjchem-2279	214	2	am	am	PROPN
eurjchem-2279	214	3	.	.	PUNCT
eurjchem-2279	215	1	chem	chem	NOUN
eurjchem-2279	215	2	.	.	PUNCT
eurjchem-2279	216	1	soc	soc	PROPN
eurjchem-2279	216	2	.	.	PUNCT
eurjchem-2279	217	1	2009	2009	NUM
eurjchem-2279	217	2	,	,	PUNCT
eurjchem-2279	217	3	131	131	NUM
eurjchem-2279	217	4	,	,	PUNCT
eurjchem-2279	217	5	13180	13180	NUM
eurjchem-2279	217	6	–	–	PUNCT
eurjchem-2279	217	7	13180	13180	NUM
eurjchem-2279	217	8	.	.	PUNCT
eurjchem-2279	218	1	[	[	X
eurjchem-2279	218	2	17	17	NUM
eurjchem-2279	218	3	]	]	PUNCT
eurjchem-2279	218	4	.	.	PUNCT
eurjchem-2279	219	1	bruker	bruker	PROPN
eurjchem-2279	219	2	(	(	PUNCT
eurjchem-2279	219	3	2013	2013	NUM
eurjchem-2279	219	4	)	)	PUNCT
eurjchem-2279	219	5	.	.	PUNCT
eurjchem-2279	220	1	apex2	apex2	PROPN
eurjchem-2279	220	2	.	.	PUNCT
eurjchem-2279	221	1	bruker	bruker	PROPN
eurjchem-2279	221	2	axs	axs	PROPN
eurjchem-2279	221	3	inc	inc	PROPN
eurjchem-2279	221	4	.	.	PROPN
eurjchem-2279	221	5	,	,	PUNCT
eurjchem-2279	221	6	madison	madison	PROPN
eurjchem-2279	221	7	,	,	PUNCT
eurjchem-2279	221	8	wisconsin	wisconsin	PROPN
eurjchem-2279	221	9	,	,	PUNCT
eurjchem-2279	221	10	usa	usa	PROPN
eurjchem-2279	221	11	.	.	PUNCT
eurjchem-2279	222	1	[	[	X
eurjchem-2279	222	2	18	18	NUM
eurjchem-2279	222	3	]	]	PUNCT
eurjchem-2279	222	4	.	.	PUNCT
eurjchem-2279	222	5	bruker	bruker	PROPN
eurjchem-2279	222	6	(	(	PUNCT
eurjchem-2279	222	7	2013	2013	NUM
eurjchem-2279	222	8	)	)	PUNCT
eurjchem-2279	222	9	.	.	PUNCT
eurjchem-2279	223	1	saint	saint	PROPN
eurjchem-2279	223	2	.	.	PUNCT
eurjchem-2279	224	1	bruker	bruker	PROPN
eurjchem-2279	224	2	axs	axs	PROPN
eurjchem-2279	224	3	inc	inc	PROPN
eurjchem-2279	224	4	.	.	PROPN
eurjchem-2279	224	5	,	,	PUNCT
eurjchem-2279	224	6	madison	madison	PROPN
eurjchem-2279	224	7	,	,	PUNCT
eurjchem-2279	224	8	wisconsin	wisconsin	PROPN
eurjchem-2279	224	9	,	,	PUNCT
eurjchem-2279	224	10	usa	usa	PROPN
eurjchem-2279	224	11	.	.	PUNCT
eurjchem-2279	225	1	[	[	X
eurjchem-2279	225	2	19	19	NUM
eurjchem-2279	225	3	]	]	PUNCT
eurjchem-2279	225	4	.	.	PUNCT
eurjchem-2279	226	1	sheldrick	sheldrick	NOUN
eurjchem-2279	226	2	,	,	PUNCT
eurjchem-2279	226	3	g.	g.	PROPN
eurjchem-2279	226	4	m.	m.	PROPN
eurjchem-2279	226	5	crystal	crystal	PROPN
eurjchem-2279	226	6	structure	structure	NOUN
eurjchem-2279	226	7	refinement	refinement	NOUN
eurjchem-2279	226	8	with	with	ADP
eurjchem-2279	226	9	shelxl	shelxl	NOUN
eurjchem-2279	226	10	.	.	PUNCT
eurjchem-2279	227	1	acta	acta	PROPN
eurjchem-2279	227	2	crystallogr	crystallogr	PROPN
eurjchem-2279	227	3	.	.	PUNCT
eurjchem-2279	228	1	c	c	PROPN
eurjchem-2279	228	2	struct	struct	NOUN
eurjchem-2279	228	3	.	.	PUNCT
eurjchem-2279	229	1	chem	chem	NOUN
eurjchem-2279	229	2	.	.	PUNCT
eurjchem-2279	230	1	2015	2015	NUM
eurjchem-2279	230	2	,	,	PUNCT
eurjchem-2279	230	3	71	71	NUM
eurjchem-2279	230	4	,	,	PUNCT
eurjchem-2279	230	5	3–8	3–8	NUM
eurjchem-2279	230	6	.	.	PUNCT
eurjchem-2279	231	1	[	[	X
eurjchem-2279	231	2	20	20	NUM
eurjchem-2279	231	3	]	]	PUNCT
eurjchem-2279	231	4	.	.	PUNCT
eurjchem-2279	231	5	sheldrick	sheldrick	NOUN
eurjchem-2279	231	6	,	,	PUNCT
eurjchem-2279	231	7	g.	g.	PROPN
eurjchem-2279	231	8	m.	m.	PROPN
eurjchem-2279	231	9	a	a	DET
eurjchem-2279	231	10	short	short	ADJ
eurjchem-2279	231	11	history	history	NOUN
eurjchem-2279	231	12	of	of	ADP
eurjchem-2279	231	13	shelx	shelx	NOUN
eurjchem-2279	231	14	.	.	PUNCT
eurjchem-2279	232	1	acta	acta	PROPN
eurjchem-2279	232	2	crystallogr	crystallogr	PROPN
eurjchem-2279	232	3	.	.	PUNCT
eurjchem-2279	233	1	a	a	DET
eurjchem-2279	233	2	2008	2008	NUM
eurjchem-2279	233	3	,	,	PUNCT
eurjchem-2279	233	4	64	64	NUM
eurjchem-2279	233	5	,	,	PUNCT
eurjchem-2279	233	6	112–122	112–122	NUM
eurjchem-2279	233	7	.	.	PUNCT
eurjchem-2279	234	1	[	[	X
eurjchem-2279	234	2	21	21	NUM
eurjchem-2279	234	3	]	]	PUNCT
eurjchem-2279	234	4	.	.	PUNCT
eurjchem-2279	235	1	dolomanov	dolomanov	PROPN
eurjchem-2279	235	2	,	,	PUNCT
eurjchem-2279	235	3	o.	o.	PROPN
eurjchem-2279	235	4	v.	v.	PROPN
eurjchem-2279	235	5	;	;	PUNCT
eurjchem-2279	235	6	bourhis	bourhis	NOUN
eurjchem-2279	235	7	,	,	PUNCT
eurjchem-2279	235	8	l.	l.	PROPN
eurjchem-2279	235	9	j.	j.	PROPN
eurjchem-2279	235	10	;	;	PUNCT
eurjchem-2279	235	11	gildea	gildea	PROPN
eurjchem-2279	235	12	,	,	PUNCT
eurjchem-2279	235	13	r.	r.	PROPN
eurjchem-2279	235	14	j.	j.	PROPN
eurjchem-2279	235	15	;	;	PUNCT
eurjchem-2279	235	16	howard	howard	PROPN
eurjchem-2279	235	17	,	,	PUNCT
eurjchem-2279	235	18	j.	j.	PROPN
eurjchem-2279	235	19	a.	a.	PROPN
eurjchem-2279	235	20	k.	k.	PROPN
eurjchem-2279	235	21	;	;	PUNCT
eurjchem-2279	235	22	puschmann	puschmann	PROPN
eurjchem-2279	235	23	,	,	PUNCT
eurjchem-2279	235	24	h.	h.	PROPN
eurjchem-2279	235	25	olex2	olex2	PROPN
eurjchem-2279	235	26	:	:	PUNCT
eurjchem-2279	235	27	a	a	DET
eurjchem-2279	235	28	complete	complete	ADJ
eurjchem-2279	235	29	structure	structure	NOUN
eurjchem-2279	235	30	solution	solution	NOUN
eurjchem-2279	235	31	,	,	PUNCT
eurjchem-2279	235	32	refinement	refinement	NOUN
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eurjchem-2279	235	34	analysis	analysis	NOUN
eurjchem-2279	235	35	program	program	NOUN
eurjchem-2279	235	36	.	.	PUNCT
eurjchem-2279	236	1	j.	j.	PROPN
eurjchem-2279	236	2	appl	appl	PROPN
eurjchem-2279	236	3	.	.	PROPN
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eurjchem-2279	236	5	.	.	PUNCT
eurjchem-2279	237	1	2009	2009	NUM
eurjchem-2279	237	2	,	,	PUNCT
eurjchem-2279	237	3	42	42	NUM
eurjchem-2279	237	4	,	,	PUNCT
eurjchem-2279	237	5	339–341	339–341	NUM
eurjchem-2279	237	6	.	.	PUNCT
eurjchem-2279	238	1	[	[	X
eurjchem-2279	238	2	22	22	NUM
eurjchem-2279	238	3	]	]	PUNCT
eurjchem-2279	238	4	.	.	PUNCT
eurjchem-2279	238	5	bourhis	bourhis	PROPN
eurjchem-2279	238	6	,	,	PUNCT
eurjchem-2279	238	7	l.	l.	PROPN
eurjchem-2279	238	8	j.	j.	PROPN
eurjchem-2279	238	9	;	;	PUNCT
eurjchem-2279	238	10	dolomanov	dolomanov	PROPN
eurjchem-2279	238	11	,	,	PUNCT
eurjchem-2279	238	12	o.	o.	PROPN
eurjchem-2279	238	13	v.	v.	PROPN
eurjchem-2279	238	14	;	;	PUNCT
eurjchem-2279	238	15	gildea	gildea	PROPN
eurjchem-2279	238	16	,	,	PUNCT
eurjchem-2279	238	17	r.	r.	PROPN
eurjchem-2279	238	18	j.	j.	PROPN
eurjchem-2279	238	19	;	;	PUNCT
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eurjchem-2279	238	21	,	,	PUNCT
eurjchem-2279	238	22	j.	j.	PROPN
eurjchem-2279	238	23	a.	a.	PROPN
eurjchem-2279	238	24	k.	k.	PROPN
eurjchem-2279	238	25	;	;	PUNCT
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eurjchem-2279	238	43	environment	environment	NOUN
eurjchem-2279	238	44	olex2	olex2	PROPN
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eurjchem-2279	238	46	.	.	PUNCT
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eurjchem-2279	241	1	adv	adv	PROPN
eurjchem-2279	241	2	.	.	PROPN
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eurjchem-2279	241	4	,	,	PUNCT
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eurjchem-2279	241	6	,	,	PUNCT
eurjchem-2279	241	7	59	59	NUM
eurjchem-2279	241	8	–	–	PUNCT
eurjchem-2279	241	9	75	75	NUM
eurjchem-2279	241	10	.	.	PUNCT
eurjchem-2279	242	1	[	[	X
eurjchem-2279	242	2	23	23	NUM
eurjchem-2279	242	3	]	]	PUNCT
eurjchem-2279	242	4	.	.	PUNCT
eurjchem-2279	243	1	macrae	macrae	PROPN
eurjchem-2279	243	2	,	,	PUNCT
eurjchem-2279	243	3	c.	c.	PROPN
eurjchem-2279	243	4	f.	f.	PROPN
eurjchem-2279	243	5	;	;	PUNCT
eurjchem-2279	243	6	sovago	sovago	PROPN
eurjchem-2279	243	7	,	,	PUNCT
eurjchem-2279	243	8	i.	i.	NOUN
eurjchem-2279	243	9	;	;	PUNCT
eurjchem-2279	243	10	cottrell	cottrell	PROPN
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eurjchem-2279	243	12	s.	s.	PROPN
eurjchem-2279	243	13	j.	j.	PROPN
eurjchem-2279	243	14	;	;	PUNCT
eurjchem-2279	243	15	galek	galek	PROPN
eurjchem-2279	243	16	,	,	PUNCT
eurjchem-2279	243	17	p.	p.	PROPN
eurjchem-2279	243	18	t.	t.	PROPN
eurjchem-2279	243	19	a.	a.	PROPN
eurjchem-2279	243	20	;	;	PUNCT
eurjchem-2279	243	21	mccabe	mccabe	PROPN
eurjchem-2279	243	22	,	,	PUNCT
eurjchem-2279	243	23	p.	p.	NOUN
eurjchem-2279	243	24	;	;	PUNCT
eurjchem-2279	243	25	pidcock	pidcock	PROPN
eurjchem-2279	243	26	,	,	PUNCT
eurjchem-2279	243	27	e.	e.	PROPN
eurjchem-2279	243	28	;	;	PUNCT
eurjchem-2279	243	29	platings	plating	NOUN
eurjchem-2279	243	30	,	,	PUNCT
eurjchem-2279	243	31	m.	m.	NOUN
eurjchem-2279	243	32	;	;	PUNCT
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eurjchem-2279	243	34	,	,	PUNCT
eurjchem-2279	243	35	g.	g.	PROPN
eurjchem-2279	243	36	p.	p.	PROPN
eurjchem-2279	243	37	;	;	PUNCT
eurjchem-2279	243	38	stevens	stevens	PROPN
eurjchem-2279	243	39	,	,	PUNCT
eurjchem-2279	243	40	j.	j.	PROPN
eurjchem-2279	243	41	s.	s.	PROPN
eurjchem-2279	243	42	;	;	PUNCT
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eurjchem-2279	243	44	,	,	PUNCT
eurjchem-2279	243	45	m.	m.	NOUN
eurjchem-2279	243	46	;	;	PUNCT
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eurjchem-2279	243	48	,	,	PUNCT
eurjchem-2279	243	49	p.	p.	NOUN
eurjchem-2279	243	50	a.	a.	NOUN
eurjchem-2279	243	51	mercury	mercury	PROPN
eurjchem-2279	243	52	4.0	4.0	NUM
eurjchem-2279	243	53	:	:	PUNCT
eurjchem-2279	243	54	from	from	ADP
eurjchem-2279	243	55	visualization	visualization	NOUN
eurjchem-2279	243	56	to	to	ADP
eurjchem-2279	243	57	analysis	analysis	NOUN
eurjchem-2279	243	58	,	,	PUNCT
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eurjchem-2279	243	61	prediction	prediction	NOUN
eurjchem-2279	243	62	.	.	PUNCT
eurjchem-2279	244	1	j.	j.	PROPN
eurjchem-2279	244	2	appl	appl	PROPN
eurjchem-2279	244	3	.	.	PROPN
eurjchem-2279	244	4	crystallogr	crystallogr	PROPN
eurjchem-2279	244	5	.	.	PUNCT
eurjchem-2279	245	1	2020	2020	NUM
eurjchem-2279	245	2	,	,	PUNCT
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eurjchem-2279	245	4	,	,	PUNCT
eurjchem-2279	245	5	226–235	226–235	NUM
eurjchem-2279	245	6	.	.	PUNCT
eurjchem-2279	246	1	[	[	X
eurjchem-2279	246	2	24	24	NUM
eurjchem-2279	246	3	]	]	PUNCT
eurjchem-2279	246	4	.	.	PUNCT
eurjchem-2279	247	1	macrae	macrae	PROPN
eurjchem-2279	247	2	,	,	PUNCT
eurjchem-2279	247	3	c.	c.	PROPN
eurjchem-2279	247	4	f.	f.	PROPN
eurjchem-2279	247	5	;	;	PUNCT
eurjchem-2279	247	6	bruno	bruno	PROPN
eurjchem-2279	247	7	,	,	PUNCT
eurjchem-2279	247	8	i.	i.	PROPN
eurjchem-2279	247	9	j.	j.	PROPN
eurjchem-2279	247	10	;	;	PUNCT
eurjchem-2279	247	11	chisholm	chisholm	PROPN
eurjchem-2279	247	12	,	,	PUNCT
eurjchem-2279	247	13	j.	j.	PROPN
eurjchem-2279	247	14	a.	a.	PROPN
eurjchem-2279	247	15	;	;	PUNCT
eurjchem-2279	247	16	edgington	edgington	PROPN
eurjchem-2279	247	17	,	,	PUNCT
eurjchem-2279	247	18	p.	p.	PROPN
eurjchem-2279	247	19	r.	r.	PROPN
eurjchem-2279	247	20	;	;	PUNCT
eurjchem-2279	247	21	mccabe	mccabe	PROPN
eurjchem-2279	247	22	,	,	PUNCT
eurjchem-2279	247	23	p.	p.	NOUN
eurjchem-2279	247	24	;	;	PUNCT
eurjchem-2279	247	25	pidcock	pidcock	PROPN
eurjchem-2279	247	26	,	,	PUNCT
eurjchem-2279	247	27	e.	e.	PROPN
eurjchem-2279	247	28	;	;	PUNCT
eurjchem-2279	247	29	rodriguez	rodriguez	NOUN
eurjchem-2279	247	30	-	-	PUNCT
eurjchem-2279	247	31	monge	monge	PROPN
eurjchem-2279	247	32	,	,	PUNCT
eurjchem-2279	247	33	l.	l.	PROPN
eurjchem-2279	247	34	;	;	PUNCT
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eurjchem-2279	247	36	,	,	PUNCT
eurjchem-2279	247	37	r.	r.	PROPN
eurjchem-2279	247	38	;	;	PUNCT
eurjchem-2279	247	39	van	van	PROPN
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eurjchem-2279	247	41	streek	streek	PROPN
eurjchem-2279	247	42	,	,	PUNCT
eurjchem-2279	247	43	j.	j.	PROPN
eurjchem-2279	247	44	;	;	PUNCT
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eurjchem-2279	247	46	,	,	PUNCT
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eurjchem-2279	247	51	2.0	2.0	NUM
eurjchem-2279	247	52	–	–	PUNCT
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eurjchem-2279	247	63	.	.	PUNCT
eurjchem-2279	248	1	j.	j.	PROPN
eurjchem-2279	248	2	appl	appl	PROPN
eurjchem-2279	248	3	.	.	PROPN
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eurjchem-2279	248	5	.	.	PUNCT
eurjchem-2279	249	1	2008	2008	NUM
eurjchem-2279	249	2	,	,	PUNCT
eurjchem-2279	249	3	41	41	NUM
eurjchem-2279	249	4	,	,	PUNCT
eurjchem-2279	249	5	466	466	NUM
eurjchem-2279	249	6	–	–	PUNCT
eurjchem-2279	249	7	470	470	NUM
eurjchem-2279	249	8	.	.	PUNCT
eurjchem-2279	250	1	[	[	X
eurjchem-2279	250	2	25	25	NUM
eurjchem-2279	250	3	]	]	PUNCT
eurjchem-2279	250	4	.	.	PUNCT
eurjchem-2279	251	1	macrae	macrae	PROPN
eurjchem-2279	251	2	,	,	PUNCT
eurjchem-2279	251	3	c.	c.	PROPN
eurjchem-2279	251	4	f.	f.	PROPN
eurjchem-2279	251	5	;	;	PUNCT
eurjchem-2279	251	6	edgington	edgington	PROPN
eurjchem-2279	251	7	,	,	PUNCT
eurjchem-2279	251	8	p.	p.	PROPN
eurjchem-2279	251	9	r.	r.	PROPN
eurjchem-2279	251	10	;	;	PUNCT
eurjchem-2279	251	11	mccabe	mccabe	PROPN
eurjchem-2279	251	12	,	,	PUNCT
eurjchem-2279	251	13	p.	p.	NOUN
eurjchem-2279	251	14	;	;	PUNCT
eurjchem-2279	251	15	pidcock	pidcock	PROPN
eurjchem-2279	251	16	,	,	PUNCT
eurjchem-2279	251	17	e.	e.	PROPN
eurjchem-2279	251	18	;	;	PUNCT
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eurjchem-2279	251	20	,	,	PUNCT
eurjchem-2279	251	21	g.	g.	PROPN
eurjchem-2279	251	22	p.	p.	PROPN
eurjchem-2279	251	23	;	;	PUNCT
eurjchem-2279	251	24	taylor	taylor	PROPN
eurjchem-2279	251	25	,	,	PUNCT
eurjchem-2279	251	26	r.	r.	PROPN
eurjchem-2279	251	27	;	;	PUNCT
eurjchem-2279	251	28	towler	towler	NOUN
eurjchem-2279	251	29	,	,	PUNCT
eurjchem-2279	251	30	m.	m.	NOUN
eurjchem-2279	251	31	;	;	PUNCT
eurjchem-2279	251	32	van	van	PROPN
eurjchem-2279	251	33	de	de	X
eurjchem-2279	251	34	streek	streek	PROPN
eurjchem-2279	251	35	,	,	PUNCT
eurjchem-2279	251	36	j.	j.	PROPN
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eurjchem-2279	251	38	:	:	PUNCT
eurjchem-2279	251	39	visualization	visualization	NOUN
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eurjchem-2279	251	41	analysis	analysis	NOUN
eurjchem-2279	251	42	of	of	ADP
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eurjchem-2279	251	45	.	.	PUNCT
eurjchem-2279	252	1	j.	j.	PROPN
eurjchem-2279	252	2	appl	appl	PROPN
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eurjchem-2279	252	5	.	.	PUNCT
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eurjchem-2279	253	2	,	,	PUNCT
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eurjchem-2279	253	4	,	,	PUNCT
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eurjchem-2279	253	6	.	.	PUNCT
eurjchem-2279	254	1	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	ADJ
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eurjchem-2279	254	4	mailto:stenforb@mail.gvsu.edu	mailto:stenforb@mail.gvsu.edu	NOUN
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eurjchem-2279	254	12	/	/	SYM
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eurjchem-2279	254	18	(	(	PUNCT
eurjchem-2279	254	19	2	2	NUM
eurjchem-2279	254	20	)	)	PUNCT
eurjchem-2279	254	21	(	(	PUNCT
eurjchem-2279	254	22	2022	2022	NUM
eurjchem-2279	254	23	)	)	PUNCT
eurjchem-2279	254	24	145	145	NUM
eurjchem-2279	254	25	-	-	SYM
eurjchem-2279	254	26	150	150	NUM
eurjchem-2279	254	27	2022	2022	NUM
eurjchem-2279	254	28	–	–	PUNCT
eurjchem-2279	254	29	european	european	ADJ
eurjchem-2279	254	30	journal	journal	NOUN
eurjchem-2279	254	31	of	of	ADP
eurjchem-2279	254	32	chemistry	chemistry	NOUN
eurjchem-2279	254	33	–	–	PUNCT
eurjchem-2279	254	34	cc	cc	NOUN
eurjchem-2279	254	35	by	by	ADP
eurjchem-2279	254	36	nc	nc	PROPN
eurjchem-2279	254	37	–	–	PUNCT
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eurjchem-2279	254	39	:	:	PUNCT
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eurjchem-2279	254	41	/	/	SYM
eurjchem-2279	254	42	eurjchem.13.2.145	eurjchem.13.2.145	NOUN
eurjchem-2279	254	43	-	-	SYM
eurjchem-2279	254	44	150.2279	150.2279	PROPN
eurjchem-2279	254	45	[	[	X
eurjchem-2279	254	46	26	26	NUM
eurjchem-2279	254	47	]	]	PUNCT
eurjchem-2279	254	48	.	.	PUNCT
eurjchem-2279	255	1	bruno	bruno	PROPN
eurjchem-2279	255	2	,	,	PUNCT
eurjchem-2279	255	3	i.	i.	PROPN
eurjchem-2279	255	4	j.	j.	PROPN
eurjchem-2279	255	5	;	;	PUNCT
eurjchem-2279	255	6	cole	cole	PROPN
eurjchem-2279	255	7	,	,	PUNCT
eurjchem-2279	255	8	j.	j.	PROPN
eurjchem-2279	255	9	c.	c.	PROPN
eurjchem-2279	255	10	;	;	PUNCT
eurjchem-2279	255	11	edgington	edgington	PROPN
eurjchem-2279	255	12	,	,	PUNCT
eurjchem-2279	255	13	p.	p.	PROPN
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eurjchem-2279	255	15	;	;	PUNCT
eurjchem-2279	255	16	kessler	kessler	PROPN
eurjchem-2279	255	17	,	,	PUNCT
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eurjchem-2279	255	19	;	;	PUNCT
eurjchem-2279	255	20	macrae	macrae	PROPN
eurjchem-2279	255	21	,	,	PUNCT
eurjchem-2279	255	22	c.	c.	PROPN
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eurjchem-2279	255	24	;	;	PUNCT
eurjchem-2279	255	25	mccabe	mccabe	PROPN
eurjchem-2279	255	26	,	,	PUNCT
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eurjchem-2279	255	29	pearson	pearson	PROPN
eurjchem-2279	255	30	,	,	PUNCT
eurjchem-2279	255	31	j.	j.	PROPN
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eurjchem-2279	255	34	,	,	PUNCT
eurjchem-2279	255	35	r.	r.	PROPN
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eurjchem-2279	255	37	software	software	NOUN
eurjchem-2279	255	38	for	for	ADP
eurjchem-2279	255	39	searching	search	VERB
eurjchem-2279	255	40	the	the	DET
eurjchem-2279	255	41	cambridge	cambridge	PROPN
eurjchem-2279	255	42	structural	structural	ADJ
eurjchem-2279	255	43	database	database	NOUN
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eurjchem-2279	255	45	visualizing	visualize	VERB
eurjchem-2279	255	46	crystal	crystal	NOUN
eurjchem-2279	255	47	structures	structure	NOUN
eurjchem-2279	255	48	.	.	PUNCT
eurjchem-2279	256	1	acta	acta	PROPN
eurjchem-2279	256	2	crystallogr	crystallogr	PROPN
eurjchem-2279	256	3	.	.	PUNCT
eurjchem-2279	257	1	b	b	NOUN
eurjchem-2279	257	2	2002	2002	NUM
eurjchem-2279	257	3	,	,	PUNCT
eurjchem-2279	257	4	58	58	NUM
eurjchem-2279	257	5	,	,	PUNCT
eurjchem-2279	257	6	389–397	389–397	NUM
eurjchem-2279	257	7	.	.	PUNCT
eurjchem-2279	258	1	[	[	X
eurjchem-2279	258	2	27	27	NUM
eurjchem-2279	258	3	]	]	PUNCT
eurjchem-2279	258	4	.	.	PUNCT
eurjchem-2279	258	5	taylor	taylor	PROPN
eurjchem-2279	258	6	,	,	PUNCT
eurjchem-2279	258	7	r.	r.	PROPN
eurjchem-2279	258	8	;	;	PUNCT
eurjchem-2279	258	9	macrae	macrae	PROPN
eurjchem-2279	258	10	,	,	PUNCT
eurjchem-2279	258	11	c.	c.	PROPN
eurjchem-2279	258	12	f.	f.	PROPN
eurjchem-2279	258	13	rules	rule	VERB
eurjchem-2279	258	14	governing	govern	VERB
eurjchem-2279	258	15	the	the	DET
eurjchem-2279	258	16	crystal	crystal	NOUN
eurjchem-2279	258	17	packing	packing	NOUN
eurjchem-2279	258	18	of	of	ADP
eurjchem-2279	258	19	mono	mono	NOUN
eurjchem-2279	258	20	and	and	CCONJ
eurjchem-2279	258	21	dialcohols	dialcohol	NOUN
eurjchem-2279	258	22	.	.	PUNCT
eurjchem-2279	259	1	acta	acta	PROPN
eurjchem-2279	259	2	crystallogr	crystallogr	PROPN
eurjchem-2279	259	3	.	.	PUNCT
eurjchem-2279	260	1	b	b	NOUN
eurjchem-2279	260	2	2001	2001	NUM
eurjchem-2279	260	3	,	,	PUNCT
eurjchem-2279	260	4	57	57	NUM
eurjchem-2279	260	5	,	,	PUNCT
eurjchem-2279	260	6	815–827	815–827	NUM
eurjchem-2279	260	7	.	.	PUNCT
eurjchem-2279	261	1	[	[	X
eurjchem-2279	261	2	28	28	NUM
eurjchem-2279	261	3	]	]	PUNCT
eurjchem-2279	261	4	.	.	PUNCT
eurjchem-2279	262	1	krause	krause	PROPN
eurjchem-2279	262	2	,	,	PUNCT
eurjchem-2279	262	3	l.	l.	PROPN
eurjchem-2279	262	4	;	;	PUNCT
eurjchem-2279	262	5	herbst	herbst	PROPN
eurjchem-2279	262	6	-	-	PUNCT
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eurjchem-2279	262	8	,	,	PUNCT
eurjchem-2279	262	9	r.	r.	PROPN
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eurjchem-2279	262	13	g.	g.	PROPN
eurjchem-2279	262	14	m.	m.	PROPN
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eurjchem-2279	262	17	,	,	PUNCT
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eurjchem-2279	262	21	silver	silver	NOUN
eurjchem-2279	262	22	and	and	CCONJ
eurjchem-2279	262	23	molybdenum	molybdenum	NOUN
eurjchem-2279	262	24	microfocus	microfocus	NOUN
eurjchem-2279	262	25	x	x	NOUN
eurjchem-2279	262	26	-	-	NOUN
eurjchem-2279	262	27	ray	ray	NOUN
eurjchem-2279	262	28	sources	source	NOUN
eurjchem-2279	262	29	for	for	ADP
eurjchem-2279	262	30	single	single	ADJ
eurjchem-2279	262	31	-	-	PUNCT
eurjchem-2279	262	32	crystal	crystal	NOUN
eurjchem-2279	262	33	structure	structure	NOUN
eurjchem-2279	262	34	determination	determination	NOUN
eurjchem-2279	262	35	.	.	PUNCT
eurjchem-2279	263	1	j.	j.	PROPN
eurjchem-2279	263	2	appl	appl	PROPN
eurjchem-2279	263	3	.	.	PROPN
eurjchem-2279	263	4	crystallogr	crystallogr	PROPN
eurjchem-2279	263	5	.	.	PUNCT
eurjchem-2279	264	1	2015	2015	NUM
eurjchem-2279	264	2	,	,	PUNCT
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eurjchem-2279	264	4	,	,	PUNCT
eurjchem-2279	264	5	3–10	3–10	NOUN
eurjchem-2279	264	6	.	.	PUNCT
eurjchem-2279	265	1	[	[	X
eurjchem-2279	265	2	29	29	NUM
eurjchem-2279	265	3	]	]	PUNCT
eurjchem-2279	265	4	.	.	PUNCT
eurjchem-2279	266	1	yang	yang	PROPN
eurjchem-2279	266	2	,	,	PUNCT
eurjchem-2279	266	3	l.	l.	PROPN
eurjchem-2279	266	4	;	;	PUNCT
eurjchem-2279	266	5	powell	powell	PROPN
eurjchem-2279	266	6	,	,	PUNCT
eurjchem-2279	266	7	d.	d.	PROPN
eurjchem-2279	266	8	r.	r.	PROPN
eurjchem-2279	266	9	;	;	PUNCT
eurjchem-2279	266	10	houser	houser	PROPN
eurjchem-2279	266	11	,	,	PUNCT
eurjchem-2279	266	12	r.	r.	PROPN
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eurjchem-2279	266	17	copper(i	copper(i	PROPN
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eurjchem-2279	266	22	ligands	ligand	NOUN
eurjchem-2279	266	23	:	:	PUNCT
eurjchem-2279	266	24	structural	structural	ADJ
eurjchem-2279	266	25	analysis	analysis	NOUN
eurjchem-2279	266	26	with	with	ADP
eurjchem-2279	266	27	a	a	DET
eurjchem-2279	266	28	new	new	ADJ
eurjchem-2279	266	29	four	four	NUM
eurjchem-2279	266	30	-	-	PUNCT
eurjchem-2279	266	31	coordinate	coordinate	NOUN
eurjchem-2279	266	32	geometry	geometry	NOUN
eurjchem-2279	266	33	index	index	NOUN
eurjchem-2279	266	34	,	,	PUNCT
eurjchem-2279	266	35	tau4	tau4	PROPN
eurjchem-2279	266	36	.	.	PUNCT
eurjchem-2279	267	1	dalton	dalton	PROPN
eurjchem-2279	267	2	trans	trans	PROPN
eurjchem-2279	267	3	.	.	PROPN
eurjchem-2279	268	1	2007	2007	NUM
eurjchem-2279	268	2	,	,	PUNCT
eurjchem-2279	268	3	955	955	NUM
eurjchem-2279	268	4	–	–	PUNCT
eurjchem-2279	268	5	964	964	NUM
eurjchem-2279	268	6	.	.	PUNCT
eurjchem-2279	269	1	[	[	X
eurjchem-2279	269	2	30	30	NUM
eurjchem-2279	269	3	]	]	PUNCT
eurjchem-2279	269	4	.	.	PUNCT
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eurjchem-2279	270	2	,	,	PUNCT
eurjchem-2279	270	3	b.	b.	PROPN
eurjchem-2279	270	4	a.	a.	PROPN
eurjchem-2279	270	5	;	;	PUNCT
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eurjchem-2279	270	7	,	,	PUNCT
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eurjchem-2279	270	10	;	;	PUNCT
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eurjchem-2279	270	12	,	,	PUNCT
eurjchem-2279	270	13	s.	s.	PROPN
eurjchem-2279	270	14	m.	m.	PROPN
eurjchem-2279	270	15	;	;	PUNCT
eurjchem-2279	270	16	ngassa	ngassa	NOUN
eurjchem-2279	270	17	,	,	PUNCT
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eurjchem-2279	270	19	n.	n.	PROPN
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eurjchem-2279	270	23	characterization	characterization	NOUN
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eurjchem-2279	270	25	x	x	VERB
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eurjchem-2279	270	29	-	-	PUNCT
eurjchem-2279	270	30	dinitrophenyl4′-phenylbenzenesulfonates	dinitrophenyl4′-phenylbenzenesulfonate	NOUN
eurjchem-2279	270	31	.	.	PUNCT
eurjchem-2279	271	1	chemistry	chemistry	NOUN
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eurjchem-2279	271	3	,	,	PUNCT
eurjchem-2279	271	4	2	2	NUM
eurjchem-2279	271	5	,	,	PUNCT
eurjchem-2279	271	6	591–599	591–599	NUM
eurjchem-2279	271	7	.	.	PUNCT
eurjchem-2279	272	1	[	[	X
eurjchem-2279	272	2	31	31	NUM
eurjchem-2279	272	3	]	]	PUNCT
eurjchem-2279	272	4	.	.	PUNCT
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eurjchem-2279	272	8	.	.	PUNCT
eurjchem-2279	272	9	;	;	PUNCT
eurjchem-2279	273	1	kang	kang	PROPN
eurjchem-2279	273	2	,	,	PUNCT
eurjchem-2279	273	3	j.-s	j.-s	PROPN
eurjchem-2279	273	4	.	.	PUNCT
eurjchem-2279	273	5	;	;	PUNCT
eurjchem-2279	273	6	shin	shin	PROPN
eurjchem-2279	273	7	,	,	PUNCT
eurjchem-2279	273	8	y.-h	y.-h	PROPN
eurjchem-2279	273	9	.	.	PUNCT
eurjchem-2279	273	10	;	;	PUNCT
eurjchem-2279	274	1	buncel	buncel	PROPN
eurjchem-2279	274	2	,	,	PUNCT
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eurjchem-2279	275	6	displacement	displacement	ADJ
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eurjchem-2279	275	10	benzenesulfonates	benzenesulfonate	NOUN
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eurjchem-2279	275	12	potassium	potassium	NOUN
eurjchem-2279	275	13	ethoxide	ethoxide	NOUN
eurjchem-2279	275	14	:	:	PUNCT
eurjchem-2279	275	15	role	role	NOUN
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eurjchem-2279	275	17	k+	k+	NOUN
eurjchem-2279	275	18	ion	ion	NOUN
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eurjchem-2279	275	20	reaction	reaction	NOUN
eurjchem-2279	275	21	mechanism	mechanism	NOUN
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eurjchem-2279	275	30	.	.	PUNCT
eurjchem-2279	276	1	j.	j.	PROPN
eurjchem-2279	276	2	org	org	PROPN
eurjchem-2279	276	3	.	.	PUNCT
eurjchem-2279	276	4	chem	chem	PROPN
eurjchem-2279	276	5	.	.	PUNCT
eurjchem-2279	277	1	2013	2013	NUM
eurjchem-2279	277	2	,	,	PUNCT
eurjchem-2279	277	3	78	78	NUM
eurjchem-2279	277	4	,	,	PUNCT
eurjchem-2279	277	5	490–497	490–497	NUM
eurjchem-2279	277	6	.	.	PUNCT
eurjchem-2279	278	1	copyright	copyright	NOUN
eurjchem-2279	278	2	©	©	ADP
eurjchem-2279	278	3	2022	2022	NUM
eurjchem-2279	278	4	by	by	ADP
eurjchem-2279	278	5	authors	author	NOUN
eurjchem-2279	278	6	.	.	PUNCT
eurjchem-2279	279	1	this	this	DET
eurjchem-2279	279	2	work	work	NOUN
eurjchem-2279	279	3	is	be	AUX
eurjchem-2279	279	4	published	publish	VERB
eurjchem-2279	279	5	and	and	CCONJ
eurjchem-2279	279	6	licensed	license	VERB
eurjchem-2279	279	7	by	by	ADP
eurjchem-2279	279	8	atlanta	atlanta	PROPN
eurjchem-2279	279	9	publishing	publishing	PROPN
eurjchem-2279	279	10	house	house	PROPN
eurjchem-2279	279	11	llc	llc	PROPN
eurjchem-2279	279	12	,	,	PUNCT
eurjchem-2279	279	13	atlanta	atlanta	PROPN
eurjchem-2279	279	14	,	,	PUNCT
eurjchem-2279	279	15	ga	ga	PROPN
eurjchem-2279	279	16	,	,	PUNCT
eurjchem-2279	279	17	usa	usa	PROPN
eurjchem-2279	279	18	.	.	PUNCT
eurjchem-2279	280	1	the	the	DET
eurjchem-2279	280	2	full	full	ADJ
eurjchem-2279	280	3	terms	term	NOUN
eurjchem-2279	280	4	of	of	ADP
eurjchem-2279	280	5	this	this	DET
eurjchem-2279	280	6	license	license	NOUN
eurjchem-2279	280	7	are	be	AUX
eurjchem-2279	280	8	available	available	ADJ
eurjchem-2279	280	9	at	at	ADP
eurjchem-2279	280	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2279	280	11	and	and	CCONJ
eurjchem-2279	280	12	incorporate	incorporate	VERB
eurjchem-2279	280	13	the	the	DET
eurjchem-2279	280	14	creative	creative	ADJ
eurjchem-2279	280	15	commons	common	NOUN
eurjchem-2279	280	16	attribution	attribution	NOUN
eurjchem-2279	280	17	-	-	PUNCT
eurjchem-2279	280	18	non	non	ADJ
eurjchem-2279	280	19	commercial	commercial	NOUN
eurjchem-2279	280	20	(	(	PUNCT
eurjchem-2279	280	21	cc	cc	NOUN
eurjchem-2279	280	22	by	by	ADP
eurjchem-2279	280	23	nc	nc	PROPN
eurjchem-2279	280	24	)	)	PUNCT
eurjchem-2279	280	25	(	(	PUNCT
eurjchem-2279	280	26	international	international	ADJ
eurjchem-2279	280	27	,	,	PUNCT
eurjchem-2279	280	28	v4.0	v4.0	NOUN
eurjchem-2279	280	29	)	)	PUNCT
eurjchem-2279	280	30	license	license	NOUN
eurjchem-2279	280	31	(	(	PUNCT
eurjchem-2279	280	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2279	280	33	)	)	PUNCT
eurjchem-2279	280	34	.	.	PUNCT
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eurjchem-2279	281	3	the	the	DET
eurjchem-2279	281	4	work	work	NOUN
eurjchem-2279	281	5	,	,	PUNCT
eurjchem-2279	281	6	you	you	PRON
eurjchem-2279	281	7	hereby	hereby	ADV
eurjchem-2279	281	8	accept	accept	VERB
eurjchem-2279	281	9	the	the	DET
eurjchem-2279	281	10	terms	term	NOUN
eurjchem-2279	281	11	.	.	PUNCT
eurjchem-2279	282	1	this	this	PRON
eurjchem-2279	282	2	is	be	AUX
eurjchem-2279	282	3	an	an	DET
eurjchem-2279	282	4	open	open	ADJ
eurjchem-2279	282	5	access	access	NOUN
eurjchem-2279	282	6	article	article	NOUN
eurjchem-2279	282	7	distributed	distribute	VERB
eurjchem-2279	282	8	under	under	ADP
eurjchem-2279	282	9	the	the	DET
eurjchem-2279	282	10	terms	term	NOUN
eurjchem-2279	282	11	and	and	CCONJ
eurjchem-2279	282	12	conditions	condition	NOUN
eurjchem-2279	282	13	of	of	ADP
eurjchem-2279	282	14	the	the	DET
eurjchem-2279	282	15	cc	cc	PROPN
eurjchem-2279	282	16	by	by	ADP
eurjchem-2279	282	17	nc	nc	PROPN
eurjchem-2279	282	18	license	license	PROPN
eurjchem-2279	282	19	,	,	PUNCT
eurjchem-2279	282	20	which	which	PRON
eurjchem-2279	282	21	permits	permit	VERB
eurjchem-2279	282	22	unrestricted	unrestricted	ADJ
eurjchem-2279	282	23	non	non	ADJ
eurjchem-2279	282	24	-	-	ADJ
eurjchem-2279	282	25	commercial	commercial	ADJ
eurjchem-2279	282	26	use	use	NOUN
eurjchem-2279	282	27	,	,	PUNCT
eurjchem-2279	282	28	distribution	distribution	NOUN
eurjchem-2279	282	29	,	,	PUNCT
eurjchem-2279	282	30	and	and	CCONJ
eurjchem-2279	282	31	reproduction	reproduction	NOUN
eurjchem-2279	282	32	in	in	ADP
eurjchem-2279	282	33	any	any	DET
eurjchem-2279	282	34	medium	medium	NOUN
eurjchem-2279	282	35	,	,	PUNCT
eurjchem-2279	282	36	provided	provide	VERB
eurjchem-2279	282	37	the	the	DET
eurjchem-2279	282	38	original	original	ADJ
eurjchem-2279	282	39	work	work	NOUN
eurjchem-2279	282	40	is	be	AUX
eurjchem-2279	282	41	properly	properly	ADV
eurjchem-2279	282	42	cited	cite	VERB
eurjchem-2279	282	43	without	without	ADP
eurjchem-2279	282	44	any	any	DET
eurjchem-2279	282	45	further	further	ADJ
eurjchem-2279	282	46	permission	permission	NOUN
eurjchem-2279	282	47	from	from	ADP
eurjchem-2279	282	48	atlanta	atlanta	PROPN
eurjchem-2279	282	49	publishing	publishing	PROPN
eurjchem-2279	282	50	house	house	PROPN
eurjchem-2279	282	51	llc	llc	PROPN
eurjchem-2279	282	52	(	(	PUNCT
eurjchem-2279	282	53	european	european	PROPN
eurjchem-2279	282	54	journal	journal	PROPN
eurjchem-2279	282	55	of	of	ADP
eurjchem-2279	282	56	chemistry	chemistry	NOUN
eurjchem-2279	282	57	)	)	PUNCT
eurjchem-2279	282	58	.	.	PUNCT
eurjchem-2279	283	1	no	no	DET
eurjchem-2279	283	2	use	use	NOUN
eurjchem-2279	283	3	,	,	PUNCT
eurjchem-2279	283	4	distribution	distribution	NOUN
eurjchem-2279	283	5	or	or	CCONJ
eurjchem-2279	283	6	reproduction	reproduction	NOUN
eurjchem-2279	283	7	is	be	AUX
eurjchem-2279	283	8	permitted	permit	VERB
eurjchem-2279	283	9	which	which	PRON
eurjchem-2279	283	10	does	do	AUX
eurjchem-2279	283	11	not	not	PART
eurjchem-2279	283	12	comply	comply	VERB
eurjchem-2279	283	13	with	with	ADP
eurjchem-2279	283	14	these	these	DET
eurjchem-2279	283	15	terms	term	NOUN
eurjchem-2279	283	16	.	.	PUNCT
eurjchem-2279	284	1	permissions	permission	NOUN
eurjchem-2279	284	2	for	for	ADP
eurjchem-2279	284	3	commercial	commercial	ADJ
eurjchem-2279	284	4	use	use	NOUN
eurjchem-2279	284	5	of	of	ADP
eurjchem-2279	284	6	this	this	DET
eurjchem-2279	284	7	work	work	NOUN
eurjchem-2279	284	8	beyond	beyond	ADP
eurjchem-2279	284	9	the	the	DET
eurjchem-2279	284	10	scope	scope	NOUN
eurjchem-2279	284	11	of	of	ADP
eurjchem-2279	284	12	the	the	DET
eurjchem-2279	284	13	license	license	NOUN
eurjchem-2279	284	14	(	(	PUNCT
eurjchem-2279	284	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2279	284	16	)	)	PUNCT
eurjchem-2279	284	17	are	be	AUX
eurjchem-2279	284	18	administered	administer	VERB
eurjchem-2279	284	19	by	by	ADP
eurjchem-2279	284	20	atlanta	atlanta	PROPN
eurjchem-2279	284	21	publishing	publishing	PROPN
eurjchem-2279	284	22	house	house	PROPN
eurjchem-2279	284	23	llc	llc	PROPN
eurjchem-2279	284	24	(	(	PUNCT
eurjchem-2279	284	25	european	european	PROPN
eurjchem-2279	284	26	journal	journal	PROPN
eurjchem-2279	284	27	of	of	ADP
eurjchem-2279	284	28	chemistry	chemistry	NOUN
eurjchem-2279	284	29	)	)	PUNCT
eurjchem-2279	284	30	.	.	PUNCT
eurjchem-2279	285	1	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2279	285	2	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2279	285	3	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2279	285	4	1	1	NUM
eurjchem-2279	285	5	.	.	PUNCT
eurjchem-2279	285	6	introduction	introduction	NOUN
eurjchem-2279	285	7	2	2	NUM
eurjchem-2279	285	8	.	.	PUNCT
eurjchem-2279	285	9	experimental	experimental	ADJ
eurjchem-2279	285	10	2.1	2.1	NUM
eurjchem-2279	285	11	.	.	PUNCT
eurjchem-2279	285	12	instrumentation	instrumentation	NOUN
eurjchem-2279	285	13	and	and	CCONJ
eurjchem-2279	285	14	materials	material	NOUN
eurjchem-2279	285	15	2.2	2.2	NUM
eurjchem-2279	285	16	.	.	PUNCT
eurjchem-2279	285	17	synthesis	synthesis	VERB
eurjchem-2279	285	18	2.3	2.3	NUM
eurjchem-2279	285	19	.	.	PUNCT
eurjchem-2279	285	20	crystallographic	crystallographic	ADJ
eurjchem-2279	285	21	characterization	characterization	NOUN
eurjchem-2279	285	22	3	3	NUM
eurjchem-2279	285	23	.	.	NOUN
eurjchem-2279	285	24	results	result	NOUN
eurjchem-2279	285	25	and	and	CCONJ
eurjchem-2279	285	26	discussion	discussion	NOUN
eurjchem-2279	285	27	3.1	3.1	NUM
eurjchem-2279	285	28	.	.	PUNCT
eurjchem-2279	285	29	crystallographic	crystallographic	ADJ
eurjchem-2279	285	30	characterization	characterization	NOUN
eurjchem-2279	285	31	3.2	3.2	NUM
eurjchem-2279	285	32	.	.	PUNCT
eurjchem-2279	286	1	synthetic	synthetic	ADJ
eurjchem-2279	286	2	techniques	technique	NOUN
eurjchem-2279	286	3	4	4	NUM
eurjchem-2279	286	4	.	.	PUNCT
eurjchem-2279	286	5	conclusion	conclusion	NOUN
eurjchem-2279	286	6	acknowledgements	acknowledgement	NOUN
eurjchem-2279	286	7	supporting	support	VERB
eurjchem-2279	286	8	information	information	NOUN
eurjchem-2279	286	9	disclosure	disclosure	NOUN
eurjchem-2279	286	10	statement	statement	NOUN
eurjchem-2279	286	11	credit	credit	NOUN
eurjchem-2279	286	12	authorship	authorship	NOUN
eurjchem-2279	286	13	contribution	contribution	NOUN
eurjchem-2279	286	14	statement	statement	NOUN
eurjchem-2279	286	15	funding	fund	VERB
eurjchem-2279	286	16	orcid	orcid	NOUN
eurjchem-2279	286	17	and	and	CCONJ
eurjchem-2279	286	18	email	email	NOUN
eurjchem-2279	286	19	references	reference	NOUN
eurjchem-2279	286	20	printfield10	printfield10	PROPN
eurjchem-2279	286	21	:	:	PUNCT
eurjchem-2279	286	22	printfield11	printfield11	NOUN
eurjchem-2279	286	23	:	:	PUNCT
eurjchem-2279	286	24	printfield12	printfield12	PROPN
eurjchem-2279	286	25	:	:	PUNCT
eurjchem-2279	286	26	printfield13	printfield13	VERB
eurjchem-2279	286	27	:	:	PUNCT
eurjchem-2279	286	28	printfield14	printfield14	NOUN
eurjchem-2279	286	29	:	:	PUNCT
eurjchem-2279	286	30	printfield15	printfield15	NOUN
eurjchem-2279	286	31	:	:	PUNCT
eurjchem-2279	286	32	printfield20	printfield20	PROPN
eurjchem-2279	286	33	:	:	PUNCT
eurjchem-2279	286	34	printfield21	printfield21	ADJ
eurjchem-2279	286	35	:	:	PUNCT
eurjchem-2279	286	36	printfield22	printfield22	NOUN
eurjchem-2279	286	37	:	:	PUNCT
eurjchem-2279	286	38	printfield23	printfield23	NOUN
eurjchem-2279	286	39	:	:	PUNCT
eurjchem-2279	286	40	printfield24	printfield24	NOUN
eurjchem-2279	286	41	:	:	PUNCT
eurjchem-2279	286	42	printfield25	printfield25	NOUN
eurjchem-2279	286	43	:	:	PUNCT