id	sid	tid	token	lemma	pos
eurjchem-2402	1	1	exploring	explore	VERB
eurjchem-2402	1	2	dna	dna	NOUN
eurjchem-2402	1	3	-	-	PUNCT
eurjchem-2402	1	4	interaction	interaction	NOUN
eurjchem-2402	1	5	and	and	CCONJ
eurjchem-2402	1	6	molecular	molecular	ADJ
eurjchem-2402	1	7	structure	structure	NOUN
eurjchem-2402	1	8	of	of	ADP
eurjchem-2402	1	9	ruthenium/1,2	ruthenium/1,2	ADJ
eurjchem-2402	1	10	-	-	PUNCT
eurjchem-2402	1	11	bis-(diphenylphosphino)ethane)-based	bis-(diphenylphosphino)ethane)-base	VERB
eurjchem-2402	1	12	complex	complex	ADJ
eurjchem-2402	1	13	european	european	ADJ
eurjchem-2402	1	14	journal	journal	NOUN
eurjchem-2402	1	15	of	of	ADP
eurjchem-2402	1	16	chemistry	chemistry	NOUN
eurjchem-2402	1	17	14	14	NUM
eurjchem-2402	1	18	(	(	PUNCT
eurjchem-2402	1	19	2	2	NUM
eurjchem-2402	1	20	)	)	PUNCT
eurjchem-2402	1	21	(	(	PUNCT
eurjchem-2402	1	22	2023	2023	NUM
eurjchem-2402	1	23	)	)	PUNCT
eurjchem-2402	1	24	193	193	NUM
eurjchem-2402	1	25	-	-	SYM
eurjchem-2402	1	26	201	201	NUM
eurjchem-2402	1	27	european	european	ADJ
eurjchem-2402	1	28	journal	journal	PROPN
eurjchem-2402	1	29	of	of	ADP
eurjchem-2402	1	30	chemistry	chemistry	NOUN
eurjchem-2402	1	31	issn	issn	VERB
eurjchem-2402	1	32	2153	2153	NUM
eurjchem-2402	1	33	-	-	SYM
eurjchem-2402	1	34	2249	2249	NUM
eurjchem-2402	1	35	(	(	PUNCT
eurjchem-2402	1	36	print	print	NOUN
eurjchem-2402	1	37	)	)	PUNCT
eurjchem-2402	1	38	/	/	PUNCT
eurjchem-2402	1	39	issn	issn	PROPN
eurjchem-2402	1	40	2153	2153	NUM
eurjchem-2402	1	41	-	-	SYM
eurjchem-2402	1	42	2257	2257	NUM
eurjchem-2402	1	43	(	(	PUNCT
eurjchem-2402	1	44	online	online	ADJ
eurjchem-2402	1	45	)	)	PUNCT
eurjchem-2402	1	46	–	–	PUNCT
eurjchem-2402	1	47	copyright	copyright	NOUN
eurjchem-2402	1	48	©	©	PROPN
eurjchem-2402	1	49	2023	2023	NUM
eurjchem-2402	1	50	the	the	DET
eurjchem-2402	1	51	authors	author	NOUN
eurjchem-2402	1	52	–	–	PUNCT
eurjchem-2402	1	53	atlanta	atlanta	PROPN
eurjchem-2402	1	54	publishing	publishing	PROPN
eurjchem-2402	1	55	house	house	PROPN
eurjchem-2402	1	56	llc	llc	PROPN
eurjchem-2402	1	57	–	–	PUNCT
eurjchem-2402	1	58	printed	print	VERB
eurjchem-2402	1	59	in	in	ADP
eurjchem-2402	1	60	the	the	DET
eurjchem-2402	1	61	usa	usa	PROPN
eurjchem-2402	1	62	.	.	PUNCT
eurjchem-2402	2	1	this	this	DET
eurjchem-2402	2	2	work	work	NOUN
eurjchem-2402	2	3	is	be	AUX
eurjchem-2402	2	4	published	publish	VERB
eurjchem-2402	2	5	and	and	CCONJ
eurjchem-2402	2	6	licensed	license	VERB
eurjchem-2402	2	7	by	by	ADP
eurjchem-2402	2	8	atlanta	atlanta	PROPN
eurjchem-2402	2	9	publishing	publishing	PROPN
eurjchem-2402	2	10	house	house	PROPN
eurjchem-2402	2	11	llc	llc	PROPN
eurjchem-2402	2	12	–	–	PUNCT
eurjchem-2402	2	13	cc	cc	PROPN
eurjchem-2402	2	14	by	by	ADP
eurjchem-2402	2	15	nc	nc	PROPN
eurjchem-2402	2	16	–	–	PUNCT
eurjchem-2402	2	17	some	some	DET
eurjchem-2402	2	18	rights	right	NOUN
eurjchem-2402	2	19	reserved	reserve	VERB
eurjchem-2402	2	20	.	.	PUNCT
eurjchem-2402	3	1	https://dx.doi.org/10.5155/eurjchem.14.2.193-201.2402	https://dx.doi.org/10.5155/eurjchem.14.2.193-201.2402	PROPN
eurjchem-2402	3	2	european	european	PROPN
eurjchem-2402	3	3	journal	journal	PROPN
eurjchem-2402	3	4	of	of	ADP
eurjchem-2402	3	5	chemistry	chemistry	NOUN
eurjchem-2402	3	6	view	view	NOUN
eurjchem-2402	3	7	journal	journal	PROPN
eurjchem-2402	3	8	online	online	PROPN
eurjchem-2402	3	9	view	view	NOUN
eurjchem-2402	3	10	article	article	NOUN
eurjchem-2402	3	11	online	online	ADV
eurjchem-2402	3	12	exploring	explore	VERB
eurjchem-2402	3	13	dna	dna	NOUN
eurjchem-2402	3	14	-	-	PUNCT
eurjchem-2402	3	15	interaction	interaction	NOUN
eurjchem-2402	3	16	and	and	CCONJ
eurjchem-2402	3	17	molecular	molecular	ADJ
eurjchem-2402	3	18	structure	structure	NOUN
eurjchem-2402	3	19	of	of	ADP
eurjchem-2402	3	20	ruthenium/1,2	ruthenium/1,2	NOUN
eurjchem-2402	3	21	-	-	PUNCT
eurjchem-2402	3	22	bis-(diphenylphosphino)ethane)-based	bis-(diphenylphosphino)ethane)-base	VERB
eurjchem-2402	3	23	complex	complex	ADJ
eurjchem-2402	3	24	victor	victor	NOUN
eurjchem-2402	3	25	cardoso	cardoso	PROPN
eurjchem-2402	3	26	campideli	campideli	PROPN
eurjchem-2402	3	27	1,†	1,†	NUM
eurjchem-2402	3	28	,	,	PUNCT
eurjchem-2402	3	29	jerica	jerica	ADV
eurjchem-2402	3	30	margely	margely	ADV
eurjchem-2402	3	31	montilla	montilla	NOUN
eurjchem-2402	3	32	-	-	PUNCT
eurjchem-2402	3	33	suárez	suárez	NOUN
eurjchem-2402	3	34	1,†	1,†	NUM
eurjchem-2402	3	35	,	,	PUNCT
eurjchem-2402	3	36	tiago	tiago	PROPN
eurjchem-2402	3	37	almeida	almeida	PROPN
eurjchem-2402	3	38	silva	silva	PROPN
eurjchem-2402	3	39	2	2	NUM
eurjchem-2402	3	40	,	,	PUNCT
eurjchem-2402	3	41	dalila	dalila	PROPN
eurjchem-2402	3	42	chaves	chaves	PROPN
eurjchem-2402	3	43	sicupira	sicupira	PROPN
eurjchem-2402	3	44	1	1	NUM
eurjchem-2402	3	45	,	,	PUNCT
eurjchem-2402	3	46	katia	katia	PROPN
eurjchem-2402	3	47	mara	mara	PROPN
eurjchem-2402	3	48	oliveira	oliveira	PROPN
eurjchem-2402	3	49	3	3	PROPN
eurjchem-2402	3	50	and	and	CCONJ
eurjchem-2402	3	51	rodrigo	rodrigo	PROPN
eurjchem-2402	3	52	souza	souza	PROPN
eurjchem-2402	3	53	correa	correa	PROPN
eurjchem-2402	3	54	1	1	NUM
eurjchem-2402	3	55	,	,	PUNCT
eurjchem-2402	3	56	*	*	PROPN
eurjchem-2402	3	57	1	1	NUM
eurjchem-2402	3	58	departamento	departamento	PROPN
eurjchem-2402	3	59	de	de	PROPN
eurjchem-2402	3	60	química	química	PROPN
eurjchem-2402	3	61	,	,	PUNCT
eurjchem-2402	3	62	universidade	universidade	PROPN
eurjchem-2402	3	63	federal	federal	PROPN
eurjchem-2402	3	64	de	de	PROPN
eurjchem-2402	3	65	ouro	ouro	PROPN
eurjchem-2402	3	66	preto	preto	PROPN
eurjchem-2402	3	67	(	(	PUNCT
eurjchem-2402	3	68	ufop	ufop	NOUN
eurjchem-2402	3	69	)	)	PUNCT
eurjchem-2402	3	70	,	,	PUNCT
eurjchem-2402	3	71	ouro	ouro	PROPN
eurjchem-2402	3	72	preto	preto	PROPN
eurjchem-2402	3	73	,	,	PUNCT
eurjchem-2402	3	74	mg	mg	PROPN
eurjchem-2402	3	75	,	,	PUNCT
eurjchem-2402	3	76	35400	35400	NUM
eurjchem-2402	3	77	-	-	PUNCT
eurjchem-2402	3	78	000	000	NUM
eurjchem-2402	3	79	,	,	PUNCT
eurjchem-2402	3	80	brazil	brazil	PROPN
eurjchem-2402	3	81	2	2	NUM
eurjchem-2402	3	82	departamento	departamento	PROPN
eurjchem-2402	3	83	de	de	PROPN
eurjchem-2402	3	84	química	química	PROPN
eurjchem-2402	3	85	,	,	PUNCT
eurjchem-2402	3	86	universidade	universidade	PROPN
eurjchem-2402	3	87	federal	federal	PROPN
eurjchem-2402	3	88	de	de	X
eurjchem-2402	3	89	viçosa	viçosa	PROPN
eurjchem-2402	3	90	(	(	PUNCT
eurjchem-2402	3	91	ufv	ufv	NOUN
eurjchem-2402	3	92	)	)	PUNCT
eurjchem-2402	3	93	,	,	PUNCT
eurjchem-2402	3	94	viçosa	viçosa	PROPN
eurjchem-2402	3	95	,	,	PUNCT
eurjchem-2402	3	96	mg	mg	PROPN
eurjchem-2402	3	97	,	,	PUNCT
eurjchem-2402	3	98	36570	36570	NUM
eurjchem-2402	3	99	-	-	SYM
eurjchem-2402	3	100	900	900	NUM
eurjchem-2402	3	101	,	,	PUNCT
eurjchem-2402	3	102	brazil	brazil	PROPN
eurjchem-2402	3	103	3	3	NUM
eurjchem-2402	3	104	instituto	instituto	PROPN
eurjchem-2402	3	105	de	de	PROPN
eurjchem-2402	3	106	química	química	PROPN
eurjchem-2402	3	107	,	,	PUNCT
eurjchem-2402	3	108	universidade	universidade	PROPN
eurjchem-2402	3	109	de	de	PROPN
eurjchem-2402	3	110	brasília	brasília	PROPN
eurjchem-2402	3	111	(	(	PUNCT
eurjchem-2402	3	112	unb	unb	PROPN
eurjchem-2402	3	113	)	)	PUNCT
eurjchem-2402	3	114	,	,	PUNCT
eurjchem-2402	3	115	brasília	brasília	PROPN
eurjchem-2402	3	116	,	,	PUNCT
eurjchem-2402	3	117	df	df	PROPN
eurjchem-2402	3	118	,	,	PUNCT
eurjchem-2402	3	119	70910	70910	NUM
eurjchem-2402	3	120	-	-	SYM
eurjchem-2402	3	121	900	900	NUM
eurjchem-2402	3	122	,	,	PUNCT
eurjchem-2402	3	123	brazil	brazil	PROPN
eurjchem-2402	3	124	*	*	PUNCT
eurjchem-2402	3	125	corresponding	correspond	VERB
eurjchem-2402	3	126	author	author	NOUN
eurjchem-2402	3	127	at	at	ADP
eurjchem-2402	3	128	:	:	PUNCT
eurjchem-2402	3	129	departamento	departamento	PROPN
eurjchem-2402	3	130	de	de	PROPN
eurjchem-2402	3	131	química	química	PROPN
eurjchem-2402	3	132	,	,	PUNCT
eurjchem-2402	3	133	universidade	universidade	PROPN
eurjchem-2402	3	134	federal	federal	PROPN
eurjchem-2402	3	135	de	de	PROPN
eurjchem-2402	3	136	ouro	ouro	PROPN
eurjchem-2402	3	137	preto	preto	PROPN
eurjchem-2402	3	138	(	(	PUNCT
eurjchem-2402	3	139	ufop	ufop	NOUN
eurjchem-2402	3	140	)	)	PUNCT
eurjchem-2402	3	141	,	,	PUNCT
eurjchem-2402	3	142	ouro	ouro	PROPN
eurjchem-2402	3	143	preto	preto	PROPN
eurjchem-2402	3	144	,	,	PUNCT
eurjchem-2402	3	145	mg	mg	PROPN
eurjchem-2402	3	146	,	,	PUNCT
eurjchem-2402	3	147	35400	35400	NUM
eurjchem-2402	3	148	-	-	PUNCT
eurjchem-2402	3	149	000	000	NUM
eurjchem-2402	3	150	,	,	PUNCT
eurjchem-2402	3	151	brazil	brazil	PROPN
eurjchem-2402	3	152	.	.	PUNCT
eurjchem-2402	4	1	†	†	NOUN
eurjchem-2402	5	1	these	these	DET
eurjchem-2402	5	2	authors	author	NOUN
eurjchem-2402	5	3	contributed	contribute	VERB
eurjchem-2402	5	4	equally	equally	ADV
eurjchem-2402	5	5	.	.	PUNCT
eurjchem-2402	6	1	e	e	X
eurjchem-2402	6	2	-	-	NOUN
eurjchem-2402	6	3	mail	mail	NOUN
eurjchem-2402	6	4	:	:	PUNCT
eurjchem-2402	7	1	rodrigocorrea@ufop.edu.br	rodrigocorrea@ufop.edu.br	INTJ
eurjchem-2402	7	2	(	(	PUNCT
eurjchem-2402	7	3	r.s	r.s	PROPN
eurjchem-2402	7	4	.	.	PROPN
eurjchem-2402	7	5	correa	correa	PROPN
eurjchem-2402	7	6	)	)	PUNCT
eurjchem-2402	7	7	.	.	PUNCT
eurjchem-2402	8	1	10.5155	10.5155	NUM
eurjchem-2402	8	2	/	/	SYM
eurjchem-2402	8	3	eurjchem.14.2.193	eurjchem.14.2.193	NUM
eurjchem-2402	8	4	-	-	SYM
eurjchem-2402	8	5	201.2402	201.2402	NUM
eurjchem-2402	8	6	received	receive	VERB
eurjchem-2402	8	7	:	:	PUNCT
eurjchem-2402	8	8	24	24	NUM
eurjchem-2402	8	9	december	december	PROPN
eurjchem-2402	8	10	2022	2022	NUM
eurjchem-2402	8	11	received	receive	VERB
eurjchem-2402	8	12	in	in	ADP
eurjchem-2402	8	13	revised	revise	VERB
eurjchem-2402	8	14	form	form	NOUN
eurjchem-2402	8	15	:	:	PUNCT
eurjchem-2402	8	16	29	29	NUM
eurjchem-2402	8	17	january	january	PROPN
eurjchem-2402	8	18	2023	2023	NUM
eurjchem-2402	8	19	accepted	accept	VERB
eurjchem-2402	8	20	:	:	PUNCT
eurjchem-2402	8	21	11	11	NUM
eurjchem-2402	8	22	february	february	PROPN
eurjchem-2402	8	23	2023	2023	NUM
eurjchem-2402	8	24	published	publish	VERB
eurjchem-2402	8	25	online	online	ADV
eurjchem-2402	8	26	:	:	PUNCT
eurjchem-2402	8	27	30	30	NUM
eurjchem-2402	8	28	june	june	PROPN
eurjchem-2402	8	29	2023	2023	NUM
eurjchem-2402	8	30	printed	print	VERB
eurjchem-2402	8	31	:	:	PUNCT
eurjchem-2402	8	32	30	30	NUM
eurjchem-2402	8	33	june	june	PROPN
eurjchem-2402	8	34	2023	2023	NUM
eurjchem-2402	8	35	the	the	DET
eurjchem-2402	8	36	mixture	mixture	NOUN
eurjchem-2402	8	37	of	of	ADP
eurjchem-2402	8	38	cis	cis	NOUN
eurjchem-2402	8	39	and	and	CCONJ
eurjchem-2402	8	40	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	PROPN
eurjchem-2402	8	41	]	]	PUNCT
eurjchem-2402	8	42	(	(	PUNCT
eurjchem-2402	8	43	dppe	dppe	PROPN
eurjchem-2402	8	44	:	:	PUNCT
eurjchem-2402	8	45	1,2	1,2	NUM
eurjchem-2402	8	46	-	-	PUNCT
eurjchem-2402	8	47	bis-(diphenylphosphino)ethane	bis-(diphenylphosphino)ethane	NOUN
eurjchem-2402	8	48	)	)	PUNCT
eurjchem-2402	8	49	was	be	AUX
eurjchem-2402	8	50	prepared	prepare	VERB
eurjchem-2402	8	51	and	and	CCONJ
eurjchem-2402	8	52	the	the	DET
eurjchem-2402	8	53	interaction	interaction	NOUN
eurjchem-2402	8	54	with	with	ADP
eurjchem-2402	8	55	ct	ct	PROPN
eurjchem-2402	8	56	-	-	PUNCT
eurjchem-2402	8	57	dna	dna	PROPN
eurjchem-2402	8	58	was	be	AUX
eurjchem-2402	8	59	evaluated	evaluate	VERB
eurjchem-2402	8	60	by	by	ADP
eurjchem-2402	8	61	several	several	ADJ
eurjchem-2402	8	62	methods	method	NOUN
eurjchem-2402	8	63	,	,	PUNCT
eurjchem-2402	8	64	including	include	VERB
eurjchem-2402	8	65	uvvis	uvvis	PROPN
eurjchem-2402	8	66	dna	dna	PROPN
eurjchem-2402	8	67	spectroscopic	spectroscopic	NOUN
eurjchem-2402	8	68	titration	titration	NOUN
eurjchem-2402	8	69	,	,	PUNCT
eurjchem-2402	8	70	viscosity	viscosity	NOUN
eurjchem-2402	8	71	,	,	PUNCT
eurjchem-2402	8	72	and	and	CCONJ
eurjchem-2402	8	73	electrochemical	electrochemical	ADJ
eurjchem-2402	8	74	studies	study	NOUN
eurjchem-2402	8	75	.	.	PUNCT
eurjchem-2402	9	1	investigation	investigation	NOUN
eurjchem-2402	9	2	suggests	suggest	VERB
eurjchem-2402	9	3	that	that	SCONJ
eurjchem-2402	9	4	[	[	X
eurjchem-2402	9	5	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	9	6	]	]	PUNCT
eurjchem-2402	9	7	interacts	interact	VERB
eurjchem-2402	9	8	moderately	moderately	ADV
eurjchem-2402	9	9	with	with	ADP
eurjchem-2402	9	10	ct	ct	PROPN
eurjchem-2402	9	11	-	-	PUNCT
eurjchem-2402	9	12	dna	dna	NOUN
eurjchem-2402	9	13	.	.	PUNCT
eurjchem-2402	10	1	interestingly	interestingly	ADV
eurjchem-2402	10	2	,	,	PUNCT
eurjchem-2402	10	3	the	the	DET
eurjchem-2402	10	4	cisand	cisand	PROPN
eurjchem-2402	10	5	trans	tran	NOUN
eurjchem-2402	10	6	-	-	NOUN
eurjchem-2402	10	7	isomers	isomer	NOUN
eurjchem-2402	10	8	interact	interact	VERB
eurjchem-2402	10	9	differently	differently	ADV
eurjchem-2402	10	10	with	with	ADP
eurjchem-2402	10	11	dna	dna	PROPN
eurjchem-2402	10	12	,	,	PUNCT
eurjchem-2402	10	13	as	as	SCONJ
eurjchem-2402	10	14	proved	prove	VERB
eurjchem-2402	10	15	by	by	ADP
eurjchem-2402	10	16	the	the	DET
eurjchem-2402	10	17	square	square	ADJ
eurjchem-2402	10	18	-	-	PUNCT
eurjchem-2402	10	19	wave	wave	NOUN
eurjchem-2402	10	20	voltammetry	voltammetry	NOUN
eurjchem-2402	10	21	studies	study	NOUN
eurjchem-2402	10	22	.	.	PUNCT
eurjchem-2402	11	1	finally	finally	ADV
eurjchem-2402	11	2	,	,	PUNCT
eurjchem-2402	11	3	the	the	DET
eurjchem-2402	11	4	crystal	crystal	NOUN
eurjchem-2402	11	5	structure	structure	NOUN
eurjchem-2402	11	6	of	of	ADP
eurjchem-2402	11	7	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	11	8	was	be	AUX
eurjchem-2402	11	9	obtained	obtain	VERB
eurjchem-2402	11	10	from	from	ADP
eurjchem-2402	11	11	an	an	DET
eurjchem-2402	11	12	electrochemical	electrochemical	ADJ
eurjchem-2402	11	13	solution	solution	NOUN
eurjchem-2402	11	14	and	and	CCONJ
eurjchem-2402	11	15	studied	study	VERB
eurjchem-2402	11	16	in	in	ADP
eurjchem-2402	11	17	detail	detail	NOUN
eurjchem-2402	11	18	,	,	PUNCT
eurjchem-2402	11	19	which	which	PRON
eurjchem-2402	11	20	presents	present	VERB
eurjchem-2402	11	21	a	a	DET
eurjchem-2402	11	22	distorted	distorted	ADJ
eurjchem-2402	11	23	octahedral	octahedral	ADJ
eurjchem-2402	11	24	geometry	geometry	NOUN
eurjchem-2402	11	25	and	and	CCONJ
eurjchem-2402	11	26	interatomic	interatomic	ADJ
eurjchem-2402	11	27	parameters	parameter	NOUN
eurjchem-2402	11	28	different	different	ADJ
eurjchem-2402	11	29	from	from	ADP
eurjchem-2402	11	30	those	those	PRON
eurjchem-2402	11	31	found	find	VERB
eurjchem-2402	11	32	in	in	ADP
eurjchem-2402	11	33	the	the	DET
eurjchem-2402	11	34	trans[rucl2(dppe)2	trans[rucl2(dppe)2	NOUN
eurjchem-2402	11	35	]	]	X
eurjchem-2402	11	36	complex	complex	ADJ
eurjchem-2402	11	37	.	.	PUNCT
eurjchem-2402	12	1	crystal	crystal	NOUN
eurjchem-2402	12	2	data	datum	NOUN
eurjchem-2402	12	3	for	for	ADP
eurjchem-2402	12	4	c52h48cl4p4ru	c52h48cl4p4ru	PROPN
eurjchem-2402	12	5	:	:	PUNCT
eurjchem-2402	12	6	triclinic	triclinic	ADJ
eurjchem-2402	12	7	,	,	PUNCT
eurjchem-2402	12	8	space	space	NOUN
eurjchem-2402	12	9	group	group	NOUN
eurjchem-2402	12	10	p-1	p-1	NOUN
eurjchem-2402	12	11	(	(	PUNCT
eurjchem-2402	12	12	no	no	INTJ
eurjchem-2402	12	13	.	.	NOUN
eurjchem-2402	12	14	2	2	NUM
eurjchem-2402	12	15	)	)	PUNCT
eurjchem-2402	12	16	,	,	PUNCT
eurjchem-2402	12	17	a	a	DET
eurjchem-2402	12	18	=	=	ADJ
eurjchem-2402	12	19	9.240(3	9.240(3	NUM
eurjchem-2402	12	20	)	)	PUNCT
eurjchem-2402	12	21	å	å	PROPN
eurjchem-2402	12	22	,	,	PUNCT
eurjchem-2402	12	23	b	b	X
eurjchem-2402	12	24	=	=	SYM
eurjchem-2402	12	25	10.9290(18	10.9290(18	NUM
eurjchem-2402	12	26	)	)	PUNCT
eurjchem-2402	12	27	å	å	NOUN
eurjchem-2402	12	28	,	,	PUNCT
eurjchem-2402	12	29	c	c	X
eurjchem-2402	12	30	=	=	SYM
eurjchem-2402	12	31	11.993(3	11.993(3	ADJ
eurjchem-2402	12	32	)	)	PUNCT
eurjchem-2402	12	33	å	å	PROPN
eurjchem-2402	12	34	,	,	PUNCT
eurjchem-2402	12	35	α	α	NOUN
eurjchem-2402	12	36	=	=	SYM
eurjchem-2402	12	37	78.707(11	78.707(11	NUM
eurjchem-2402	12	38	)	)	PUNCT
eurjchem-2402	12	39	°	°	PROPN
eurjchem-2402	12	40	,	,	PUNCT
eurjchem-2402	12	41	β	β	X
eurjchem-2402	12	42	=	=	SYM
eurjchem-2402	12	43	86.712(13	86.712(13	NUM
eurjchem-2402	12	44	)	)	PUNCT
eurjchem-2402	12	45	°	°	PROPN
eurjchem-2402	12	46	,	,	PUNCT
eurjchem-2402	12	47	γ	γ	NOUN
eurjchem-2402	12	48	=	=	SYM
eurjchem-2402	12	49	82.598(13	82.598(13	NUM
eurjchem-2402	12	50	)	)	PUNCT
eurjchem-2402	12	51	°	°	NOUN
eurjchem-2402	12	52	,	,	PUNCT
eurjchem-2402	12	53	v	v	NOUN
eurjchem-2402	12	54	=	=	SYM
eurjchem-2402	12	55	1177.1(5	1177.1(5	NUM
eurjchem-2402	12	56	)	)	PUNCT
eurjchem-2402	12	57	å3	å3	PROPN
eurjchem-2402	12	58	,	,	PUNCT
eurjchem-2402	12	59	z	z	NOUN
eurjchem-2402	12	60	=	=	SYM
eurjchem-2402	12	61	1	1	NUM
eurjchem-2402	12	62	,	,	PUNCT
eurjchem-2402	12	63	t	t	NOUN
eurjchem-2402	12	64	=	=	SYM
eurjchem-2402	12	65	293(2	293(2	NUM
eurjchem-2402	12	66	)	)	PUNCT
eurjchem-2402	12	67	k	k	NOUN
eurjchem-2402	12	68	,	,	PUNCT
eurjchem-2402	12	69	μ(mokα	μ(mokα	NOUN
eurjchem-2402	12	70	)	)	PUNCT
eurjchem-2402	12	71	=	=	NOUN
eurjchem-2402	13	1	0.732	0.732	NUM
eurjchem-2402	13	2	mm-1	mm-1	NOUN
eurjchem-2402	13	3	,	,	PUNCT
eurjchem-2402	13	4	dcalc	dcalc	NOUN
eurjchem-2402	13	5	=	=	NOUN
eurjchem-2402	13	6	1.467	1.467	NUM
eurjchem-2402	13	7	g	g	NOUN
eurjchem-2402	13	8	/	/	SYM
eurjchem-2402	13	9	cm3	cm3	NOUN
eurjchem-2402	13	10	,	,	PUNCT
eurjchem-2402	13	11	8434	8434	NUM
eurjchem-2402	13	12	reflections	reflection	NOUN
eurjchem-2402	13	13	measured	measure	VERB
eurjchem-2402	13	14	(	(	PUNCT
eurjchem-2402	13	15	6.934	6.934	NUM
eurjchem-2402	13	16	°	°	ADP
eurjchem-2402	13	17	≤	≤	NUM
eurjchem-2402	13	18	2θ	2θ	NUM
eurjchem-2402	13	19	≤	≤	PROPN
eurjchem-2402	13	20	51.986	51.986	NUM
eurjchem-2402	13	21	°	°	NUM
eurjchem-2402	13	22	)	)	PUNCT
eurjchem-2402	13	23	,	,	PUNCT
eurjchem-2402	13	24	4607	4607	NUM
eurjchem-2402	13	25	unique	unique	ADJ
eurjchem-2402	13	26	(	(	PUNCT
eurjchem-2402	13	27	rint	rint	NOUN
eurjchem-2402	13	28	=	=	SYM
eurjchem-2402	13	29	0.0973	0.0973	NUM
eurjchem-2402	13	30	,	,	PUNCT
eurjchem-2402	13	31	rsigma	rsigma	ADJ
eurjchem-2402	13	32	=	=	SYM
eurjchem-2402	13	33	0.1171	0.1171	NUM
eurjchem-2402	13	34	)	)	PUNCT
eurjchem-2402	13	35	which	which	PRON
eurjchem-2402	13	36	were	be	AUX
eurjchem-2402	13	37	used	use	VERB
eurjchem-2402	13	38	in	in	ADP
eurjchem-2402	13	39	all	all	DET
eurjchem-2402	13	40	calculations	calculation	NOUN
eurjchem-2402	13	41	.	.	PUNCT
eurjchem-2402	14	1	the	the	DET
eurjchem-2402	14	2	final	final	ADJ
eurjchem-2402	14	3	r1	r1	PROPN
eurjchem-2402	14	4	was	be	AUX
eurjchem-2402	14	5	0.0537	0.0537	NUM
eurjchem-2402	14	6	(	(	PUNCT
eurjchem-2402	14	7	i	i	X
eurjchem-2402	14	8	>	>	X
eurjchem-2402	14	9	2σ(i	2σ(i	NUM
eurjchem-2402	14	10	)	)	PUNCT
eurjchem-2402	14	11	)	)	PUNCT
eurjchem-2402	15	1	and	and	CCONJ
eurjchem-2402	15	2	wr2	wr2	PROPN
eurjchem-2402	15	3	was	be	AUX
eurjchem-2402	15	4	0.1347	0.1347	NUM
eurjchem-2402	15	5	(	(	PUNCT
eurjchem-2402	15	6	all	all	DET
eurjchem-2402	15	7	data	datum	NOUN
eurjchem-2402	15	8	)	)	PUNCT
eurjchem-2402	15	9	.	.	PUNCT
eurjchem-2402	16	1	viscosity	viscosity	NOUN
eurjchem-2402	16	2	dna	dna	PROPN
eurjchem-2402	16	3	interaction	interaction	NOUN
eurjchem-2402	16	4	crystal	crystal	NOUN
eurjchem-2402	16	5	structure	structure	NOUN
eurjchem-2402	16	6	ru	ru	PROPN
eurjchem-2402	16	7	/	/	SYM
eurjchem-2402	16	8	dppe	dppe	PROPN
eurjchem-2402	16	9	complex	complex	ADJ
eurjchem-2402	16	10	uv	uv	NOUN
eurjchem-2402	16	11	-	-	PUNCT
eurjchem-2402	16	12	vis	vis	X
eurjchem-2402	16	13	spectroscopy	spectroscopy	NOUN
eurjchem-2402	16	14	square	square	ADJ
eurjchem-2402	16	15	-	-	PUNCT
eurjchem-2402	16	16	wave	wave	NOUN
eurjchem-2402	16	17	voltammetry	voltammetry	NOUN
eurjchem-2402	16	18	cite	cite	VERB
eurjchem-2402	16	19	this	this	PRON
eurjchem-2402	16	20	:	:	PUNCT
eurjchem-2402	16	21	eur	eur	PROPN
eurjchem-2402	16	22	.	.	PUNCT
eurjchem-2402	17	1	j.	j.	PROPN
eurjchem-2402	17	2	chem	chem	PROPN
eurjchem-2402	17	3	.	.	PUNCT
eurjchem-2402	18	1	2023	2023	NUM
eurjchem-2402	18	2	,	,	PUNCT
eurjchem-2402	18	3	14(2	14(2	NUM
eurjchem-2402	18	4	)	)	PUNCT
eurjchem-2402	18	5	,	,	PUNCT
eurjchem-2402	18	6	193	193	NUM
eurjchem-2402	18	7	-	-	SYM
eurjchem-2402	18	8	201	201	NUM
eurjchem-2402	18	9	journal	journal	NOUN
eurjchem-2402	18	10	website	website	NOUN
eurjchem-2402	18	11	:	:	PUNCT
eurjchem-2402	18	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2402	18	13	1	1	X
eurjchem-2402	18	14	.	.	PUNCT
eurjchem-2402	19	1	introduction	introduction	NOUN
eurjchem-2402	19	2	cancer	cancer	NOUN
eurjchem-2402	19	3	is	be	AUX
eurjchem-2402	19	4	the	the	DET
eurjchem-2402	19	5	replication	replication	NOUN
eurjchem-2402	19	6	of	of	ADP
eurjchem-2402	19	7	tumor	tumor	NOUN
eurjchem-2402	19	8	cells	cell	NOUN
eurjchem-2402	19	9	(	(	PUNCT
eurjchem-2402	19	10	genetically	genetically	ADV
eurjchem-2402	19	11	modified	modify	VERB
eurjchem-2402	19	12	)	)	PUNCT
eurjchem-2402	19	13	and	and	CCONJ
eurjchem-2402	19	14	can	can	AUX
eurjchem-2402	19	15	occur	occur	VERB
eurjchem-2402	19	16	in	in	ADP
eurjchem-2402	19	17	several	several	ADJ
eurjchem-2402	19	18	different	different	ADJ
eurjchem-2402	19	19	ways	way	NOUN
eurjchem-2402	19	20	in	in	ADP
eurjchem-2402	19	21	the	the	DET
eurjchem-2402	19	22	human	human	ADJ
eurjchem-2402	19	23	body	body	NOUN
eurjchem-2402	19	24	.	.	PUNCT
eurjchem-2402	20	1	one	one	NUM
eurjchem-2402	20	2	of	of	ADP
eurjchem-2402	20	3	these	these	DET
eurjchem-2402	20	4	disease	disease	NOUN
eurjchem-2402	20	5	treatments	treatment	NOUN
eurjchem-2402	20	6	consists	consist	VERB
eurjchem-2402	20	7	of	of	ADP
eurjchem-2402	20	8	the	the	DET
eurjchem-2402	20	9	use	use	NOUN
eurjchem-2402	20	10	of	of	ADP
eurjchem-2402	20	11	anticancer	anticancer	NOUN
eurjchem-2402	20	12	drugs	drug	NOUN
eurjchem-2402	20	13	,	,	PUNCT
eurjchem-2402	20	14	known	know	VERB
eurjchem-2402	20	15	as	as	ADP
eurjchem-2402	20	16	chemotherapeutic	chemotherapeutic	ADJ
eurjchem-2402	20	17	agents	agent	NOUN
eurjchem-2402	20	18	,	,	PUNCT
eurjchem-2402	20	19	in	in	ADP
eurjchem-2402	20	20	which	which	PRON
eurjchem-2402	20	21	one	one	NUM
eurjchem-2402	20	22	of	of	ADP
eurjchem-2402	20	23	the	the	DET
eurjchem-2402	20	24	mechanisms	mechanism	NOUN
eurjchem-2402	20	25	of	of	ADP
eurjchem-2402	20	26	action	action	NOUN
eurjchem-2402	20	27	is	be	AUX
eurjchem-2402	20	28	to	to	PART
eurjchem-2402	20	29	interact	interact	VERB
eurjchem-2402	20	30	with	with	ADP
eurjchem-2402	20	31	dna	dna	PROPN
eurjchem-2402	20	32	altering	alter	VERB
eurjchem-2402	20	33	its	its	PRON
eurjchem-2402	20	34	structure	structure	NOUN
eurjchem-2402	20	35	,	,	PUNCT
eurjchem-2402	20	36	leading	lead	VERB
eurjchem-2402	20	37	to	to	ADP
eurjchem-2402	20	38	cell	cell	NOUN
eurjchem-2402	20	39	death	death	NOUN
eurjchem-2402	20	40	,	,	PUNCT
eurjchem-2402	20	41	modulation	modulation	NOUN
eurjchem-2402	20	42	of	of	ADP
eurjchem-2402	20	43	transcription	transcription	NOUN
eurjchem-2402	20	44	,	,	PUNCT
eurjchem-2402	20	45	or	or	CCONJ
eurjchem-2402	20	46	interfering	interfere	VERB
eurjchem-2402	20	47	in	in	ADP
eurjchem-2402	20	48	replication	replication	NOUN
eurjchem-2402	20	49	to	to	PART
eurjchem-2402	20	50	prevent	prevent	VERB
eurjchem-2402	20	51	the	the	DET
eurjchem-2402	20	52	rapid	rapid	ADJ
eurjchem-2402	20	53	proliferation	proliferation	NOUN
eurjchem-2402	20	54	of	of	ADP
eurjchem-2402	20	55	cancer	cancer	NOUN
eurjchem-2402	20	56	cells	cell	NOUN
eurjchem-2402	20	57	in	in	ADP
eurjchem-2402	20	58	the	the	DET
eurjchem-2402	20	59	body	body	NOUN
eurjchem-2402	20	60	[	[	X
eurjchem-2402	20	61	1	1	NUM
eurjchem-2402	20	62	]	]	PUNCT
eurjchem-2402	20	63	.	.	PUNCT
eurjchem-2402	21	1	in	in	ADP
eurjchem-2402	21	2	recent	recent	ADJ
eurjchem-2402	21	3	years	year	NOUN
eurjchem-2402	21	4	,	,	PUNCT
eurjchem-2402	21	5	many	many	ADJ
eurjchem-2402	21	6	studies	study	NOUN
eurjchem-2402	21	7	have	have	AUX
eurjchem-2402	21	8	been	be	AUX
eurjchem-2402	21	9	conducted	conduct	VERB
eurjchem-2402	21	10	based	base	VERB
eurjchem-2402	21	11	on	on	ADP
eurjchem-2402	21	12	metallodrug	metallodrug	NOUN
eurjchem-2402	21	13	development	development	NOUN
eurjchem-2402	21	14	based	base	VERB
eurjchem-2402	21	15	on	on	ADP
eurjchem-2402	21	16	the	the	DET
eurjchem-2402	21	17	interaction	interaction	NOUN
eurjchem-2402	21	18	of	of	ADP
eurjchem-2402	21	19	metal	metal	NOUN
eurjchem-2402	21	20	complexes	complex	NOUN
eurjchem-2402	21	21	with	with	ADP
eurjchem-2402	21	22	dna	dna	PROPN
eurjchem-2402	21	23	,	,	PUNCT
eurjchem-2402	21	24	to	to	PART
eurjchem-2402	21	25	understand	understand	VERB
eurjchem-2402	21	26	the	the	DET
eurjchem-2402	21	27	mechanism	mechanism	NOUN
eurjchem-2402	21	28	of	of	ADP
eurjchem-2402	21	29	action	action	NOUN
eurjchem-2402	21	30	[	[	X
eurjchem-2402	21	31	2	2	NUM
eurjchem-2402	21	32	]	]	PUNCT
eurjchem-2402	21	33	.	.	PUNCT
eurjchem-2402	22	1	since	since	SCONJ
eurjchem-2402	22	2	the	the	DET
eurjchem-2402	22	3	discovery	discovery	NOUN
eurjchem-2402	22	4	of	of	ADP
eurjchem-2402	22	5	cis	cis	NOUN
eurjchem-2402	22	6	-	-	PUNCT
eurjchem-2402	22	7	platin	platin	NOUN
eurjchem-2402	22	8	as	as	ADP
eurjchem-2402	22	9	a	a	DET
eurjchem-2402	22	10	metallodrug	metallodrug	NOUN
eurjchem-2402	22	11	in	in	ADP
eurjchem-2402	22	12	the	the	DET
eurjchem-2402	22	13	late	late	ADJ
eurjchem-2402	22	14	1960s	1960	NOUN
eurjchem-2402	22	15	,	,	PUNCT
eurjchem-2402	22	16	scientists	scientist	NOUN
eurjchem-2402	22	17	have	have	AUX
eurjchem-2402	22	18	been	be	AUX
eurjchem-2402	22	19	looking	look	VERB
eurjchem-2402	22	20	for	for	ADP
eurjchem-2402	22	21	new	new	ADJ
eurjchem-2402	22	22	coordination	coordination	NOUN
eurjchem-2402	22	23	compounds	compound	NOUN
eurjchem-2402	22	24	to	to	PART
eurjchem-2402	22	25	fight	fight	VERB
eurjchem-2402	22	26	cancer	cancer	NOUN
eurjchem-2402	23	1	[	[	X
eurjchem-2402	23	2	3	3	NUM
eurjchem-2402	23	3	]	]	PUNCT
eurjchem-2402	23	4	.	.	PUNCT
eurjchem-2402	24	1	there	there	PRON
eurjchem-2402	24	2	are	be	VERB
eurjchem-2402	24	3	many	many	ADJ
eurjchem-2402	24	4	platinum	platinum	NOUN
eurjchem-2402	24	5	-	-	PUNCT
eurjchem-2402	24	6	based	base	VERB
eurjchem-2402	24	7	complexes	complex	NOUN
eurjchem-2402	24	8	with	with	ADP
eurjchem-2402	24	9	high	high	ADJ
eurjchem-2402	24	10	biological	biological	ADJ
eurjchem-2402	24	11	activity	activity	NOUN
eurjchem-2402	24	12	.	.	PUNCT
eurjchem-2402	25	1	however	however	ADV
eurjchem-2402	25	2	,	,	PUNCT
eurjchem-2402	25	3	side	side	ADJ
eurjchem-2402	25	4	effects	effect	NOUN
eurjchem-2402	25	5	and	and	CCONJ
eurjchem-2402	25	6	resistance	resistance	NOUN
eurjchem-2402	25	7	have	have	AUX
eurjchem-2402	25	8	led	lead	VERB
eurjchem-2402	25	9	many	many	ADJ
eurjchem-2402	25	10	researchers	researcher	NOUN
eurjchem-2402	25	11	to	to	PART
eurjchem-2402	25	12	explore	explore	VERB
eurjchem-2402	25	13	other	other	ADJ
eurjchem-2402	25	14	nonplatinum	nonplatinum	ADJ
eurjchem-2402	25	15	compounds	compound	NOUN
eurjchem-2402	25	16	,	,	PUNCT
eurjchem-2402	25	17	such	such	ADJ
eurjchem-2402	25	18	as	as	ADP
eurjchem-2402	25	19	ruthenium	ruthenium	NOUN
eurjchem-2402	25	20	,	,	PUNCT
eurjchem-2402	25	21	which	which	PRON
eurjchem-2402	25	22	has	have	AUX
eurjchem-2402	25	23	been	be	AUX
eurjchem-2402	25	24	widely	widely	ADV
eurjchem-2402	25	25	studied	study	VERB
eurjchem-2402	25	26	in	in	ADP
eurjchem-2402	25	27	recent	recent	ADJ
eurjchem-2402	25	28	years	year	NOUN
eurjchem-2402	26	1	[	[	X
eurjchem-2402	26	2	4,5	4,5	NUM
eurjchem-2402	26	3	]	]	PUNCT
eurjchem-2402	26	4	.	.	PUNCT
eurjchem-2402	27	1	dna	dna	PROPN
eurjchem-2402	27	2	may	may	AUX
eurjchem-2402	27	3	be	be	AUX
eurjchem-2402	27	4	a	a	DET
eurjchem-2402	27	5	target	target	NOUN
eurjchem-2402	27	6	for	for	ADP
eurjchem-2402	27	7	anticancer	anticancer	NOUN
eurjchem-2402	27	8	metallodrugs	metallodrug	NOUN
eurjchem-2402	27	9	and	and	CCONJ
eurjchem-2402	27	10	recent	recent	ADJ
eurjchem-2402	27	11	studies	study	NOUN
eurjchem-2402	27	12	have	have	AUX
eurjchem-2402	27	13	used	use	VERB
eurjchem-2402	27	14	several	several	ADJ
eurjchem-2402	27	15	compounds	compound	NOUN
eurjchem-2402	27	16	that	that	PRON
eurjchem-2402	27	17	interact	interact	VERB
eurjchem-2402	27	18	with	with	ADP
eurjchem-2402	27	19	dna	dna	PROPN
eurjchem-2402	27	20	as	as	ADP
eurjchem-2402	27	21	useful	useful	ADJ
eurjchem-2402	27	22	tools	tool	NOUN
eurjchem-2402	27	23	to	to	PART
eurjchem-2402	27	24	visualise	visualise	VERB
eurjchem-2402	27	25	dna	dna	ADJ
eurjchem-2402	27	26	damage	damage	NOUN
eurjchem-2402	28	1	[	[	X
eurjchem-2402	28	2	5,6	5,6	NUM
eurjchem-2402	28	3	]	]	X
eurjchem-2402	28	4	.	.	PUNCT
eurjchem-2402	29	1	many	many	ADJ
eurjchem-2402	29	2	assays	assay	NOUN
eurjchem-2402	29	3	are	be	AUX
eurjchem-2402	29	4	powerful	powerful	ADJ
eurjchem-2402	29	5	tools	tool	NOUN
eurjchem-2402	29	6	for	for	ADP
eurjchem-2402	29	7	determining	determine	VERB
eurjchem-2402	29	8	the	the	DET
eurjchem-2402	29	9	mechanism	mechanism	NOUN
eurjchem-2402	29	10	of	of	ADP
eurjchem-2402	29	11	action	action	NOUN
eurjchem-2402	29	12	of	of	ADP
eurjchem-2402	29	13	new	new	ADJ
eurjchem-2402	29	14	molecules	molecule	NOUN
eurjchem-2402	29	15	and	and	CCONJ
eurjchem-2402	29	16	can	can	AUX
eurjchem-2402	29	17	be	be	AUX
eurjchem-2402	29	18	crucial	crucial	ADJ
eurjchem-2402	29	19	to	to	ADP
eurjchem-2402	29	20	the	the	DET
eurjchem-2402	29	21	discovery	discovery	NOUN
eurjchem-2402	29	22	of	of	ADP
eurjchem-2402	29	23	the	the	DET
eurjchem-2402	29	24	next	next	ADJ
eurjchem-2402	29	25	generation	generation	NOUN
eurjchem-2402	29	26	of	of	ADP
eurjchem-2402	29	27	dna	dna	NOUN
eurjchem-2402	29	28	-	-	PUNCT
eurjchem-2402	29	29	binding	bind	VERB
eurjchem-2402	29	30	anticancer	anticancer	NOUN
eurjchem-2402	29	31	metallodrugs	metallodrug	NOUN
eurjchem-2402	29	32	.	.	PUNCT
eurjchem-2402	30	1	the	the	DET
eurjchem-2402	30	2	covalent	covalent	ADJ
eurjchem-2402	30	3	bond	bond	NOUN
eurjchem-2402	30	4	between	between	ADP
eurjchem-2402	30	5	metallodrug	metallodrug	NOUN
eurjchem-2402	30	6	-	-	PUNCT
eurjchem-2402	30	7	dna	dna	PROPN
eurjchem-2402	30	8	is	be	AUX
eurjchem-2402	30	9	an	an	DET
eurjchem-2402	30	10	irreversible	irreversible	ADJ
eurjchem-2402	30	11	chemical	chemical	NOUN
eurjchem-2402	30	12	bond	bond	NOUN
eurjchem-2402	30	13	that	that	PRON
eurjchem-2402	30	14	causes	cause	VERB
eurjchem-2402	30	15	complete	complete	ADJ
eurjchem-2402	30	16	inhibition	inhibition	NOUN
eurjchem-2402	30	17	of	of	ADP
eurjchem-2402	30	18	dna	dna	NOUN
eurjchem-2402	30	19	processes	process	NOUN
eurjchem-2402	30	20	leading	lead	VERB
eurjchem-2402	30	21	to	to	ADP
eurjchem-2402	30	22	cell	cell	NOUN
eurjchem-2402	30	23	death	death	NOUN
eurjchem-2402	30	24	,	,	PUNCT
eurjchem-2402	30	25	as	as	SCONJ
eurjchem-2402	30	26	is	be	AUX
eurjchem-2402	30	27	suggested	suggest	VERB
eurjchem-2402	30	28	to	to	PART
eurjchem-2402	30	29	occur	occur	VERB
eurjchem-2402	30	30	with	with	ADP
eurjchem-2402	30	31	cisplatin	cisplatin	NOUN
eurjchem-2402	30	32	[	[	X
eurjchem-2402	30	33	7	7	NUM
eurjchem-2402	30	34	]	]	PUNCT
eurjchem-2402	30	35	.	.	PUNCT
eurjchem-2402	31	1	on	on	ADP
eurjchem-2402	31	2	the	the	DET
eurjchem-2402	31	3	other	other	ADJ
eurjchem-2402	31	4	hand	hand	NOUN
eurjchem-2402	31	5	,	,	PUNCT
eurjchem-2402	31	6	the	the	DET
eurjchem-2402	31	7	non	non	ADJ
eurjchem-2402	31	8	-	-	ADJ
eurjchem-2402	31	9	covalent	covalent	ADJ
eurjchem-2402	31	10	bond	bond	NOUN
eurjchem-2402	31	11	is	be	AUX
eurjchem-2402	31	12	almost	almost	ADV
eurjchem-2402	31	13	reversible	reversible	ADJ
eurjchem-2402	31	14	or	or	CCONJ
eurjchem-2402	31	15	reversible	reversible	ADJ
eurjchem-2402	31	16	,	,	PUNCT
eurjchem-2402	31	17	in	in	ADP
eurjchem-2402	31	18	which	which	PRON
eurjchem-2402	31	19	metallodrugs	metallodrug	VERB
eurjchem-2402	31	20	interact	interact	VERB
eurjchem-2402	31	21	with	with	ADP
eurjchem-2402	31	22	dna	dna	PROPN
eurjchem-2402	31	23	weakly	weakly	ADJ
eurjchem-2402	31	24	or	or	CCONJ
eurjchem-2402	31	25	moderately	moderately	ADV
eurjchem-2402	31	26	.	.	PUNCT
eurjchem-2402	32	1	generally	generally	ADV
eurjchem-2402	32	2	,	,	PUNCT
eurjchem-2402	32	3	there	there	PRON
eurjchem-2402	32	4	are	be	VERB
eurjchem-2402	32	5	three	three	NUM
eurjchem-2402	32	6	main	main	ADJ
eurjchem-2402	32	7	modes	mode	NOUN
eurjchem-2402	32	8	of	of	ADP
eurjchem-2402	32	9	non	non	ADJ
eurjchem-2402	32	10	-	-	ADJ
eurjchem-2402	32	11	covalent	covalent	ADJ
eurjchem-2402	32	12	interactions	interaction	NOUN
eurjchem-2402	32	13	,	,	PUNCT
eurjchem-2402	32	14	which	which	PRON
eurjchem-2402	32	15	include	include	VERB
eurjchem-2402	32	16	electrostatic	electrostatic	ADJ
eurjchem-2402	32	17	interaction	interaction	NOUN
eurjchem-2402	32	18	,	,	PUNCT
eurjchem-2402	32	19	groove	groove	VERB
eurjchem-2402	32	20	binding	bind	VERB
eurjchem-2402	32	21	,	,	PUNCT
eurjchem-2402	32	22	and	and	CCONJ
eurjchem-2402	32	23	intercalative	intercalative	ADJ
eurjchem-2402	32	24	binding	binding	ADJ
eurjchem-2402	32	25	[	[	X
eurjchem-2402	32	26	8	8	NUM
eurjchem-2402	32	27	-	-	SYM
eurjchem-2402	32	28	10	10	NUM
eurjchem-2402	32	29	]	]	PUNCT
eurjchem-2402	32	30	.	.	PUNCT
eurjchem-2402	33	1	to	to	PART
eurjchem-2402	33	2	determine	determine	VERB
eurjchem-2402	33	3	the	the	DET
eurjchem-2402	33	4	type	type	NOUN
eurjchem-2402	33	5	of	of	ADP
eurjchem-2402	33	6	metallodrug	metallodrug	NOUN
eurjchem-2402	33	7	-	-	PUNCT
eurjchem-2402	33	8	dna	dna	NOUN
eurjchem-2402	33	9	interactions	interaction	NOUN
eurjchem-2402	33	10	,	,	PUNCT
eurjchem-2402	33	11	many	many	ADJ
eurjchem-2402	33	12	techniques	technique	NOUN
eurjchem-2402	33	13	can	can	AUX
eurjchem-2402	33	14	be	be	AUX
eurjchem-2402	33	15	used	use	VERB
eurjchem-2402	33	16	,	,	PUNCT
eurjchem-2402	33	17	including	include	VERB
eurjchem-2402	33	18	cyclic	cyclic	ADJ
eurjchem-2402	33	19	voltammetry	voltammetry	NOUN
eurjchem-2402	33	20	(	(	PUNCT
eurjchem-2402	33	21	cv	cv	PROPN
eurjchem-2402	33	22	)	)	PUNCT
eurjchem-2402	33	23	and	and	CCONJ
eurjchem-2402	33	24	square	square	ADJ
eurjchem-2402	33	25	wave	wave	NOUN
eurjchem-2402	33	26	voltammetry	voltammetry	NOUN
eurjchem-2402	33	27	(	(	PUNCT
eurjchem-2402	33	28	swv	swv	PROPN
eurjchem-2402	33	29	)	)	PUNCT
eurjchem-2402	34	1	[	[	X
eurjchem-2402	34	2	11	11	NUM
eurjchem-2402	34	3	]	]	PUNCT
eurjchem-2402	34	4	,	,	PUNCT
eurjchem-2402	34	5	nuclear	nuclear	ADJ
eurjchem-2402	34	6	magnetic	magnetic	ADJ
eurjchem-2402	34	7	resonance	resonance	NOUN
eurjchem-2402	34	8	(	(	PUNCT
eurjchem-2402	34	9	nmr	nmr	NOUN
eurjchem-2402	34	10	)	)	PUNCT
eurjchem-2402	35	1	[	[	X
eurjchem-2402	35	2	12	12	NUM
eurjchem-2402	35	3	]	]	PUNCT
eurjchem-2402	35	4	,	,	PUNCT
eurjchem-2402	35	5	uv	uv	NOUN
eurjchem-2402	35	6	-	-	PUNCT
eurjchem-2402	35	7	visible	visible	ADJ
eurjchem-2402	35	8	and	and	CCONJ
eurjchem-2402	35	9	fluorescence	fluorescence	NOUN
eurjchem-2402	35	10	titration	titration	NOUN
eurjchem-2402	35	11	studies	study	NOUN
eurjchem-2402	35	12	[	[	X
eurjchem-2402	35	13	13	13	NUM
eurjchem-2402	35	14	]	]	PUNCT
eurjchem-2402	35	15	,	,	PUNCT
eurjchem-2402	35	16	viscosity	viscosity	NOUN
eurjchem-2402	35	17	[	[	X
eurjchem-2402	35	18	14	14	NUM
eurjchem-2402	35	19	]	]	PUNCT
eurjchem-2402	35	20	,	,	PUNCT
eurjchem-2402	35	21	circular	circular	ADJ
eurjchem-2402	35	22	dichroism	dichroism	NOUN
eurjchem-2402	35	23	(	(	PUNCT
eurjchem-2402	35	24	cd	cd	PROPN
eurjchem-2402	35	25	)	)	PUNCT
eurjchem-2402	35	26	and	and	CCONJ
eurjchem-2402	35	27	the	the	DET
eurjchem-2402	35	28	hoechst	hoechst	ADJ
eurjchem-2402	35	29	33	33	NUM
eurjchem-2402	35	30	 	 	SPACE
eurjchem-2402	35	31	258	258	NUM
eurjchem-2402	35	32	staining	stain	VERB
eurjchem-2402	35	33	assay	assay	NOUN
eurjchem-2402	35	34	[	[	X
eurjchem-2402	35	35	15	15	NUM
eurjchem-2402	35	36	]	]	PUNCT
eurjchem-2402	35	37	,	,	PUNCT
eurjchem-2402	35	38	capillary	capillary	ADJ
eurjchem-2402	35	39	electrophoresis	electrophoresis	NOUN
eurjchem-2402	35	40	(	(	PUNCT
eurjchem-2402	35	41	ce	ce	PROPN
eurjchem-2402	35	42	)	)	PUNCT
eurjchem-2402	36	1	[	[	X
eurjchem-2402	36	2	16	16	NUM
eurjchem-2402	36	3	]	]	PUNCT
eurjchem-2402	36	4	and	and	CCONJ
eurjchem-2402	36	5	atomic	atomic	ADJ
eurjchem-2402	36	6	force	force	NOUN
eurjchem-2402	36	7	microscopy	microscopy	NOUN
eurjchem-2402	36	8	(	(	PUNCT
eurjchem-2402	36	9	afm	afm	PROPN
eurjchem-2402	36	10	)	)	PUNCT
eurjchem-2402	37	1	[	[	X
eurjchem-2402	37	2	17	17	NUM
eurjchem-2402	37	3	]	]	PUNCT
eurjchem-2402	37	4	.	.	PUNCT
eurjchem-2402	38	1	abstract	abstract	ADJ
eurjchem-2402	38	2	research	research	NOUN
eurjchem-2402	38	3	article	article	NOUN
eurjchem-2402	38	4	keywords	keyword	VERB
eurjchem-2402	38	5	https://dx.doi.org/10.5155/eurjchem.14.2.193-201.2402	https://dx.doi.org/10.5155/eurjchem.14.2.193-201.2402	PROPN
eurjchem-2402	38	6	https://www.eurjchem.com/	https://www.eurjchem.com/	VERB
eurjchem-2402	38	7	https://dx.doi.org/10.5155/eurjchem.14.2.193-201.2402	https://dx.doi.org/10.5155/eurjchem.14.2.193-201.2402	PROPN
eurjchem-2402	38	8	mailto:rodrigocorrea@ufop.edu.br	mailto:rodrigocorrea@ufop.edu.br	PROPN
eurjchem-2402	38	9	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2402	38	10	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.2.193-201.2402&domain=pdf&date_stamp=2023-06-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.2.193-201.2402&domain=pdf&date_stamp=2023-06-30	NOUN
eurjchem-2402	38	11	194	194	NUM
eurjchem-2402	38	12	campideli	campideli	NOUN
eurjchem-2402	38	13	et	et	PROPN
eurjchem-2402	38	14	al	al	PROPN
eurjchem-2402	38	15	.	.	PUNCT
eurjchem-2402	38	16	/	/	SYM
eurjchem-2402	38	17	european	european	PROPN
eurjchem-2402	38	18	journal	journal	PROPN
eurjchem-2402	38	19	of	of	ADP
eurjchem-2402	38	20	chemistry	chemistry	NOUN
eurjchem-2402	38	21	14	14	NUM
eurjchem-2402	38	22	(	(	PUNCT
eurjchem-2402	38	23	2	2	NUM
eurjchem-2402	38	24	)	)	PUNCT
eurjchem-2402	38	25	(	(	PUNCT
eurjchem-2402	38	26	2023	2023	NUM
eurjchem-2402	38	27	)	)	PUNCT
eurjchem-2402	38	28	193	193	NUM
eurjchem-2402	38	29	-	-	SYM
eurjchem-2402	38	30	201	201	NUM
eurjchem-2402	38	31	2023	2023	NUM
eurjchem-2402	38	32	–	–	PUNCT
eurjchem-2402	38	33	european	european	ADJ
eurjchem-2402	38	34	journal	journal	NOUN
eurjchem-2402	38	35	of	of	ADP
eurjchem-2402	38	36	chemistry	chemistry	NOUN
eurjchem-2402	38	37	–	–	PUNCT
eurjchem-2402	38	38	cc	cc	NOUN
eurjchem-2402	38	39	by	by	ADP
eurjchem-2402	38	40	nc	nc	PROPN
eurjchem-2402	38	41	–	–	PUNCT
eurjchem-2402	38	42	doi	doi	NOUN
eurjchem-2402	38	43	:	:	PUNCT
eurjchem-2402	38	44	10.5155	10.5155	NUM
eurjchem-2402	38	45	/	/	SYM
eurjchem-2402	38	46	eurjchem.14.2.193	eurjchem.14.2.193	NOUN
eurjchem-2402	38	47	-	-	SYM
eurjchem-2402	38	48	201.2402	201.2402	NUM
eurjchem-2402	38	49	in	in	ADP
eurjchem-2402	38	50	recent	recent	ADJ
eurjchem-2402	38	51	years	year	NOUN
eurjchem-2402	38	52	,	,	PUNCT
eurjchem-2402	38	53	there	there	PRON
eurjchem-2402	38	54	has	have	AUX
eurjchem-2402	38	55	been	be	AUX
eurjchem-2402	38	56	interest	interest	NOUN
eurjchem-2402	38	57	in	in	ADP
eurjchem-2402	38	58	the	the	DET
eurjchem-2402	38	59	discovery	discovery	NOUN
eurjchem-2402	38	60	and	and	CCONJ
eurjchem-2402	38	61	understanding	understanding	NOUN
eurjchem-2402	38	62	of	of	ADP
eurjchem-2402	38	63	the	the	DET
eurjchem-2402	38	64	cytotoxic	cytotoxic	ADJ
eurjchem-2402	38	65	activity	activity	NOUN
eurjchem-2402	38	66	of	of	ADP
eurjchem-2402	38	67	compounds	compound	NOUN
eurjchem-2402	38	68	based	base	VERB
eurjchem-2402	38	69	on	on	ADP
eurjchem-2402	38	70	ruthenium	ruthenium	NOUN
eurjchem-2402	38	71	/	/	SYM
eurjchem-2402	38	72	phosphine	phosphine	NOUN
eurjchem-2402	38	73	and	and	CCONJ
eurjchem-2402	38	74	exploring	explore	VERB
eurjchem-2402	38	75	their	their	PRON
eurjchem-2402	38	76	interaction	interaction	NOUN
eurjchem-2402	38	77	with	with	ADP
eurjchem-2402	38	78	dna	dna	PROPN
eurjchem-2402	38	79	as	as	ADP
eurjchem-2402	38	80	a	a	DET
eurjchem-2402	38	81	possible	possible	ADJ
eurjchem-2402	38	82	target	target	NOUN
eurjchem-2402	38	83	[	[	X
eurjchem-2402	38	84	18	18	NUM
eurjchem-2402	38	85	-	-	SYM
eurjchem-2402	38	86	20	20	NUM
eurjchem-2402	38	87	]	]	PUNCT
eurjchem-2402	38	88	.	.	PUNCT
eurjchem-2402	39	1	the	the	DET
eurjchem-2402	39	2	complex	complex	NOUN
eurjchem-2402	39	3	studied	study	VERB
eurjchem-2402	39	4	in	in	ADP
eurjchem-2402	39	5	the	the	DET
eurjchem-2402	39	6	present	present	ADJ
eurjchem-2402	39	7	report	report	NOUN
eurjchem-2402	39	8	is	be	AUX
eurjchem-2402	39	9	identified	identify	VERB
eurjchem-2402	39	10	as	as	ADP
eurjchem-2402	39	11	[	[	X
eurjchem-2402	39	12	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	39	13	]	]	X
eurjchem-2402	39	14	,	,	PUNCT
eurjchem-2402	39	15	in	in	ADP
eurjchem-2402	39	16	which	which	PRON
eurjchem-2402	39	17	dppe	dppe	PRON
eurjchem-2402	39	18	is	be	AUX
eurjchem-2402	39	19	1,2	1,2	NUM
eurjchem-2402	39	20	-	-	PUNCT
eurjchem-2402	39	21	bis-(diphenylphosphino)ethane	bis-(diphenylphosphino)ethane	NOUN
eurjchem-2402	39	22	and	and	CCONJ
eurjchem-2402	39	23	a	a	DET
eurjchem-2402	39	24	mixture	mixture	NOUN
eurjchem-2402	39	25	of	of	ADP
eurjchem-2402	39	26	cis	cis	NOUN
eurjchem-2402	39	27	and	and	CCONJ
eurjchem-2402	39	28	trans	trans	NOUN
eurjchem-2402	39	29	isomers	isomer	NOUN
eurjchem-2402	39	30	of	of	ADP
eurjchem-2402	39	31	[	[	X
eurjchem-2402	39	32	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	39	33	]	]	PUNCT
eurjchem-2402	39	34	has	have	AUX
eurjchem-2402	39	35	been	be	AUX
eurjchem-2402	39	36	used	use	VERB
eurjchem-2402	39	37	.	.	PUNCT
eurjchem-2402	40	1	the	the	DET
eurjchem-2402	40	2	[	[	X
eurjchem-2402	40	3	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	40	4	]	]	X
eurjchem-2402	40	5	complex	complex	NOUN
eurjchem-2402	40	6	was	be	AUX
eurjchem-2402	40	7	previously	previously	ADV
eurjchem-2402	40	8	used	use	VERB
eurjchem-2402	40	9	as	as	ADP
eurjchem-2402	40	10	a	a	DET
eurjchem-2402	40	11	precursor	precursor	NOUN
eurjchem-2402	40	12	to	to	PART
eurjchem-2402	40	13	obtain	obtain	VERB
eurjchem-2402	40	14	new	new	ADJ
eurjchem-2402	40	15	active	active	ADJ
eurjchem-2402	40	16	compounds	compound	NOUN
eurjchem-2402	41	1	[	[	X
eurjchem-2402	41	2	21,22	21,22	X
eurjchem-2402	41	3	]	]	X
eurjchem-2402	41	4	.	.	PUNCT
eurjchem-2402	42	1	in	in	ADP
eurjchem-2402	42	2	this	this	DET
eurjchem-2402	42	3	study	study	NOUN
eurjchem-2402	42	4	,	,	PUNCT
eurjchem-2402	42	5	the	the	DET
eurjchem-2402	42	6	[	[	X
eurjchem-2402	42	7	rucl2(dppe)2]/dna	rucl2(dppe)2]/dna	PROPN
eurjchem-2402	42	8	interaction	interaction	NOUN
eurjchem-2402	42	9	was	be	AUX
eurjchem-2402	42	10	investigated	investigate	VERB
eurjchem-2402	42	11	using	use	VERB
eurjchem-2402	42	12	viscosity	viscosity	NOUN
eurjchem-2402	42	13	,	,	PUNCT
eurjchem-2402	42	14	uv	uv	NOUN
eurjchem-2402	42	15	-	-	PUNCT
eurjchem-2402	42	16	vis	vis	X
eurjchem-2402	42	17	dna	dna	PROPN
eurjchem-2402	42	18	titration	titration	NOUN
eurjchem-2402	42	19	,	,	PUNCT
eurjchem-2402	42	20	and	and	CCONJ
eurjchem-2402	42	21	square	square	ADJ
eurjchem-2402	42	22	-	-	PUNCT
eurjchem-2402	42	23	wave	wave	NOUN
eurjchem-2402	42	24	voltammetry	voltammetry	NOUN
eurjchem-2402	42	25	.	.	PUNCT
eurjchem-2402	43	1	in	in	ADP
eurjchem-2402	43	2	addition	addition	NOUN
eurjchem-2402	43	3	,	,	PUNCT
eurjchem-2402	43	4	the	the	DET
eurjchem-2402	43	5	crystal	crystal	NOUN
eurjchem-2402	43	6	structure	structure	NOUN
eurjchem-2402	43	7	of	of	ADP
eurjchem-2402	43	8	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	43	9	is	be	AUX
eurjchem-2402	43	10	reported	report	VERB
eurjchem-2402	43	11	.	.	PUNCT
eurjchem-2402	44	1	2	2	X
eurjchem-2402	44	2	.	.	X
eurjchem-2402	44	3	experimental	experimental	ADJ
eurjchem-2402	44	4	2.1	2.1	NUM
eurjchem-2402	44	5	.	.	PUNCT
eurjchem-2402	44	6	synthesis	synthesis	NOUN
eurjchem-2402	44	7	of	of	ADP
eurjchem-2402	44	8	the	the	DET
eurjchem-2402	44	9	cis-[rucl2(dmso)4	cis-[rucl2(dmso)4	PROPN
eurjchem-2402	44	10	]	]	PUNCT
eurjchem-2402	44	11	complex	complex	NOUN
eurjchem-2402	44	12	the	the	DET
eurjchem-2402	44	13	cis-[rucl2(dmso)4	cis-[rucl2(dmso)4	PROPN
eurjchem-2402	44	14	]	]	PUNCT
eurjchem-2402	44	15	complex	complex	NOUN
eurjchem-2402	44	16	was	be	AUX
eurjchem-2402	44	17	synthesised	synthesise	VERB
eurjchem-2402	44	18	by	by	ADP
eurjchem-2402	44	19	refluxing	refluxing	NOUN
eurjchem-2402	44	20	0.5	0.5	NUM
eurjchem-2402	44	21	g	g	PROPN
eurjchem-2402	44	22	(	(	PUNCT
eurjchem-2402	44	23	2.41	2.41	NUM
eurjchem-2402	44	24	mmol	mmol	NOUN
eurjchem-2402	44	25	)	)	PUNCT
eurjchem-2402	44	26	of	of	ADP
eurjchem-2402	44	27	rucl3.xh2o	rucl3.xh2o	PROPN
eurjchem-2402	44	28	in	in	ADP
eurjchem-2402	44	29	dimethyl	dimethyl	NOUN
eurjchem-2402	44	30	sulfoxide	sulfoxide	NOUN
eurjchem-2402	44	31	(	(	PUNCT
eurjchem-2402	44	32	dmso	dmso	PROPN
eurjchem-2402	44	33	)	)	PUNCT
eurjchem-2402	44	34	(	(	PUNCT
eurjchem-2402	44	35	5	5	NUM
eurjchem-2402	44	36	ml	ml	NOUN
eurjchem-2402	44	37	)	)	PUNCT
eurjchem-2402	44	38	for	for	ADP
eurjchem-2402	44	39	15	15	NUM
eurjchem-2402	44	40	minutes	minute	NOUN
eurjchem-2402	44	41	.	.	PUNCT
eurjchem-2402	45	1	the	the	DET
eurjchem-2402	45	2	reaction	reaction	NOUN
eurjchem-2402	45	3	mixture	mixture	NOUN
eurjchem-2402	45	4	was	be	AUX
eurjchem-2402	45	5	cooled	cool	VERB
eurjchem-2402	45	6	to	to	ADP
eurjchem-2402	45	7	room	room	NOUN
eurjchem-2402	45	8	temperature	temperature	NOUN
eurjchem-2402	45	9	and	and	CCONJ
eurjchem-2402	45	10	acetone	acetone	NOUN
eurjchem-2402	45	11	(	(	PUNCT
eurjchem-2402	45	12	20	20	NUM
eurjchem-2402	45	13	ml	ml	NOUN
eurjchem-2402	45	14	)	)	PUNCT
eurjchem-2402	45	15	was	be	AUX
eurjchem-2402	45	16	added	add	VERB
eurjchem-2402	45	17	to	to	PART
eurjchem-2402	45	18	form	form	VERB
eurjchem-2402	45	19	the	the	DET
eurjchem-2402	45	20	yellow	yellow	ADJ
eurjchem-2402	45	21	precipitate	precipitate	NOUN
eurjchem-2402	45	22	,	,	PUNCT
eurjchem-2402	45	23	which	which	PRON
eurjchem-2402	45	24	was	be	AUX
eurjchem-2402	45	25	washed	wash	VERB
eurjchem-2402	45	26	with	with	ADP
eurjchem-2402	45	27	acetone	acetone	NOUN
eurjchem-2402	45	28	and	and	CCONJ
eurjchem-2402	45	29	ethyl	ethyl	PROPN
eurjchem-2402	45	30	ether	ether	PROPN
eurjchem-2402	45	31	and	and	CCONJ
eurjchem-2402	45	32	vacuum	vacuum	NOUN
eurjchem-2402	45	33	-	-	PUNCT
eurjchem-2402	45	34	dried	dry	VERB
eurjchem-2402	45	35	.	.	PUNCT
eurjchem-2402	46	1	2.2	2.2	NUM
eurjchem-2402	46	2	.	.	PUNCT
eurjchem-2402	46	3	synthesis	synthesis	NOUN
eurjchem-2402	46	4	of	of	ADP
eurjchem-2402	46	5	cisand	cisand	NOUN
eurjchem-2402	46	6	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	46	7	]	]	X
eurjchem-2402	46	8	the	the	DET
eurjchem-2402	46	9	mixture	mixture	NOUN
eurjchem-2402	46	10	of	of	ADP
eurjchem-2402	46	11	cisand	cisand	NOUN
eurjchem-2402	46	12	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	46	13	]	]	PUNCT
eurjchem-2402	46	14	complexes	complex	NOUN
eurjchem-2402	46	15	was	be	AUX
eurjchem-2402	46	16	obtained	obtain	VERB
eurjchem-2402	46	17	according	accord	VERB
eurjchem-2402	46	18	to	to	ADP
eurjchem-2402	46	19	the	the	DET
eurjchem-2402	46	20	methodology	methodology	NOUN
eurjchem-2402	46	21	described	describe	VERB
eurjchem-2402	46	22	by	by	ADP
eurjchem-2402	46	23	bautista	bautista	PROPN
eurjchem-2402	46	24	et	et	PROPN
eurjchem-2402	46	25	al	al	PROPN
eurjchem-2402	46	26	.	.	PUNCT
eurjchem-2402	47	1	[	[	X
eurjchem-2402	47	2	23	23	NUM
eurjchem-2402	47	3	]	]	PUNCT
eurjchem-2402	47	4	.	.	PUNCT
eurjchem-2402	48	1	for	for	ADP
eurjchem-2402	48	2	this	this	PRON
eurjchem-2402	48	3	,	,	PUNCT
eurjchem-2402	48	4	cis-[rucl2(dmso)4	cis-[rucl2(dmso)4	PROPN
eurjchem-2402	48	5	]	]	PUNCT
eurjchem-2402	48	6	0.5	0.5	NUM
eurjchem-2402	48	7	g	g	NOUN
eurjchem-2402	48	8	(	(	PUNCT
eurjchem-2402	48	9	1.03	1.03	NUM
eurjchem-2402	48	10	mmol	mmol	NOUN
eurjchem-2402	48	11	)	)	PUNCT
eurjchem-2402	48	12	and	and	CCONJ
eurjchem-2402	48	13	1,2bis(diphenylphosphino)ethylene	1,2bis(diphenylphosphino)ethylene	NUM
eurjchem-2402	48	14	(	(	PUNCT
eurjchem-2402	48	15	dppe	dppe	PROPN
eurjchem-2402	48	16	)	)	PUNCT
eurjchem-2402	48	17	0.94	0.94	NUM
eurjchem-2402	48	18	g	g	NOUN
eurjchem-2402	48	19	(	(	PUNCT
eurjchem-2402	48	20	2.37	2.37	NUM
eurjchem-2402	48	21	mmol	mmol	NOUN
eurjchem-2402	48	22	)	)	PUNCT
eurjchem-2402	48	23	were	be	AUX
eurjchem-2402	48	24	added	add	VERB
eurjchem-2402	48	25	to	to	ADP
eurjchem-2402	48	26	20	20	NUM
eurjchem-2402	48	27	ml	ml	NOUN
eurjchem-2402	48	28	of	of	ADP
eurjchem-2402	48	29	dichloromethane	dichloromethane	NOUN
eurjchem-2402	48	30	.	.	PUNCT
eurjchem-2402	49	1	the	the	DET
eurjchem-2402	49	2	reaction	reaction	NOUN
eurjchem-2402	49	3	mixture	mixture	NOUN
eurjchem-2402	49	4	was	be	AUX
eurjchem-2402	49	5	kept	keep	VERB
eurjchem-2402	49	6	stirring	stir	VERB
eurjchem-2402	49	7	for	for	ADP
eurjchem-2402	49	8	5	5	NUM
eurjchem-2402	49	9	hours	hour	NOUN
eurjchem-2402	49	10	and	and	CCONJ
eurjchem-2402	49	11	then	then	ADV
eurjchem-2402	49	12	the	the	DET
eurjchem-2402	49	13	volume	volume	NOUN
eurjchem-2402	49	14	of	of	ADP
eurjchem-2402	49	15	the	the	DET
eurjchem-2402	49	16	solution	solution	NOUN
eurjchem-2402	49	17	was	be	AUX
eurjchem-2402	49	18	reduced	reduce	VERB
eurjchem-2402	49	19	to	to	ADP
eurjchem-2402	49	20	approximately	approximately	ADV
eurjchem-2402	49	21	3	3	NUM
eurjchem-2402	49	22	ml	ml	NOUN
eurjchem-2402	49	23	.	.	PUNCT
eurjchem-2402	50	1	subsequently	subsequently	ADV
eurjchem-2402	50	2	,	,	PUNCT
eurjchem-2402	50	3	hexane	hexane	NOUN
eurjchem-2402	50	4	was	be	AUX
eurjchem-2402	50	5	added	add	VERB
eurjchem-2402	50	6	to	to	PART
eurjchem-2402	50	7	form	form	VERB
eurjchem-2402	50	8	a	a	DET
eurjchem-2402	50	9	pale	pale	ADJ
eurjchem-2402	50	10	-	-	PUNCT
eurjchem-2402	50	11	yellow	yellow	NOUN
eurjchem-2402	50	12	precipitate	precipitate	NOUN
eurjchem-2402	50	13	,	,	PUNCT
eurjchem-2402	50	14	which	which	PRON
eurjchem-2402	50	15	presents	present	VERB
eurjchem-2402	50	16	the	the	DET
eurjchem-2402	50	17	mixture	mixture	NOUN
eurjchem-2402	50	18	of	of	ADP
eurjchem-2402	50	19	complexes	complex	NOUN
eurjchem-2402	50	20	cis	cis	NOUN
eurjchem-2402	50	21	and	and	CCONJ
eurjchem-2402	50	22	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	50	23	]	]	PUNCT
eurjchem-2402	50	24	.	.	PUNCT
eurjchem-2402	51	1	2.3	2.3	NUM
eurjchem-2402	51	2	.	.	PUNCT
eurjchem-2402	52	1	uv	uv	NOUN
eurjchem-2402	52	2	-	-	PUNCT
eurjchem-2402	52	3	vis	vis	X
eurjchem-2402	52	4	dna	dna	PROPN
eurjchem-2402	52	5	spectroscopic	spectroscopic	NOUN
eurjchem-2402	52	6	titration	titration	NOUN
eurjchem-2402	52	7	the	the	DET
eurjchem-2402	52	8	dna	dna	PROPN
eurjchem-2402	52	9	solution	solution	NOUN
eurjchem-2402	52	10	was	be	AUX
eurjchem-2402	52	11	prepared	prepare	VERB
eurjchem-2402	52	12	by	by	ADP
eurjchem-2402	52	13	adding	add	VERB
eurjchem-2402	52	14	approximately	approximately	ADV
eurjchem-2402	52	15	1.2	1.2	NUM
eurjchem-2402	52	16	mg	mg	NOUN
eurjchem-2402	52	17	of	of	ADP
eurjchem-2402	52	18	ct	ct	PROPN
eurjchem-2402	52	19	-	-	PUNCT
eurjchem-2402	52	20	dna	dna	PROPN
eurjchem-2402	52	21	(	(	PUNCT
eurjchem-2402	52	22	calf	calf	NOUN
eurjchem-2402	52	23	thymus	thymus	NOUN
eurjchem-2402	52	24	)	)	PUNCT
eurjchem-2402	52	25	in	in	ADP
eurjchem-2402	52	26	approximately	approximately	ADV
eurjchem-2402	52	27	1000	1000	NUM
eurjchem-2402	52	28	µl	µl	NOUN
eurjchem-2402	52	29	of	of	ADP
eurjchem-2402	52	30	tris	tris	ADJ
eurjchem-2402	52	31	-	-	PUNCT
eurjchem-2402	52	32	hcl	hcl	NOUN
eurjchem-2402	52	33	buffer	buffer	NOUN
eurjchem-2402	52	34	(	(	PUNCT
eurjchem-2402	52	35	4.5	4.5	NUM
eurjchem-2402	52	36	mmol	mmol	NOUN
eurjchem-2402	52	37	of	of	ADP
eurjchem-2402	52	38	tris	tris	PROPN
eurjchem-2402	52	39	hcl	hcl	PROPN
eurjchem-2402	52	40	,	,	PUNCT
eurjchem-2402	52	41	0.5	0.5	NUM
eurjchem-2402	52	42	mmol	mmol	NOUN
eurjchem-2402	52	43	of	of	ADP
eurjchem-2402	52	44	tris	tris	ADJ
eurjchem-2402	52	45	base	base	NOUN
eurjchem-2402	52	46	and	and	CCONJ
eurjchem-2402	52	47	50	50	NUM
eurjchem-2402	52	48	mmol	mmol	NOUN
eurjchem-2402	52	49	of	of	ADP
eurjchem-2402	52	50	nacl	nacl	NOUN
eurjchem-2402	52	51	)	)	PUNCT
eurjchem-2402	52	52	at	at	ADP
eurjchem-2402	52	53	a	a	DET
eurjchem-2402	52	54	ph	ph	NOUN
eurjchem-2402	52	55	of	of	ADP
eurjchem-2402	52	56	7.4	7.4	NUM
eurjchem-2402	52	57	.	.	PUNCT
eurjchem-2402	53	1	the	the	DET
eurjchem-2402	53	2	exact	exact	ADJ
eurjchem-2402	53	3	concentration	concentration	NOUN
eurjchem-2402	53	4	of	of	ADP
eurjchem-2402	53	5	ctdna	ctdna	NOUN
eurjchem-2402	53	6	was	be	AUX
eurjchem-2402	53	7	provided	provide	VERB
eurjchem-2402	53	8	by	by	ADP
eurjchem-2402	53	9	spectroscopy	spectroscopy	NOUN
eurjchem-2402	53	10	in	in	ADP
eurjchem-2402	53	11	the	the	DET
eurjchem-2402	53	12	uv	uv	NOUN
eurjchem-2402	53	13	-	-	PUNCT
eurjchem-2402	53	14	vis	vis	X
eurjchem-2402	53	15	region	region	NOUN
eurjchem-2402	53	16	.	.	PUNCT
eurjchem-2402	54	1	in	in	ADP
eurjchem-2402	54	2	a	a	DET
eurjchem-2402	54	3	cuvette	cuvette	NOUN
eurjchem-2402	54	4	containing	contain	VERB
eurjchem-2402	54	5	only	only	ADV
eurjchem-2402	54	6	a	a	DET
eurjchem-2402	54	7	buffer	buffer	NOUN
eurjchem-2402	54	8	solution	solution	NOUN
eurjchem-2402	54	9	(	(	PUNCT
eurjchem-2402	54	10	2000	2000	NUM
eurjchem-2402	54	11	μl	μl	NOUN
eurjchem-2402	54	12	)	)	PUNCT
eurjchem-2402	54	13	,	,	PUNCT
eurjchem-2402	54	14	80	80	NUM
eurjchem-2402	54	15	μl	μl	ADP
eurjchem-2402	54	16	of	of	ADP
eurjchem-2402	54	17	ctdna	ctdna	NOUN
eurjchem-2402	54	18	solution	solution	NOUN
eurjchem-2402	54	19	was	be	AUX
eurjchem-2402	54	20	added	add	VERB
eurjchem-2402	54	21	and	and	CCONJ
eurjchem-2402	54	22	the	the	DET
eurjchem-2402	54	23	measurement	measurement	NOUN
eurjchem-2402	54	24	was	be	AUX
eurjchem-2402	54	25	performed	perform	VERB
eurjchem-2402	54	26	on	on	ADP
eurjchem-2402	54	27	the	the	DET
eurjchem-2402	54	28	equipment	equipment	NOUN
eurjchem-2402	54	29	.	.	PUNCT
eurjchem-2402	55	1	it	it	PRON
eurjchem-2402	55	2	is	be	AUX
eurjchem-2402	55	3	known	know	VERB
eurjchem-2402	55	4	that	that	SCONJ
eurjchem-2402	55	5	the	the	DET
eurjchem-2402	55	6	molar	molar	ADJ
eurjchem-2402	55	7	absorptivity	absorptivity	NOUN
eurjchem-2402	55	8	of	of	ADP
eurjchem-2402	55	9	ctdna	ctdna	NOUN
eurjchem-2402	55	10	at	at	ADP
eurjchem-2402	55	11	260	260	NUM
eurjchem-2402	55	12	nm	nm	NOUN
eurjchem-2402	55	13	is	be	AUX
eurjchem-2402	55	14	6600	6600	NUM
eurjchem-2402	55	15	mol-1·cm-1·l	mol-1·cm-1·l	NOUN
eurjchem-2402	55	16	.	.	PUNCT
eurjchem-2402	56	1	therefore	therefore	ADV
eurjchem-2402	56	2	,	,	PUNCT
eurjchem-2402	56	3	knowing	know	VERB
eurjchem-2402	56	4	the	the	DET
eurjchem-2402	56	5	absorbance	absorbance	NOUN
eurjchem-2402	56	6	and	and	CCONJ
eurjchem-2402	56	7	molar	molar	ADJ
eurjchem-2402	56	8	absorptivity	absorptivity	NOUN
eurjchem-2402	56	9	at	at	ADP
eurjchem-2402	56	10	260	260	NUM
eurjchem-2402	56	11	nm	nm	NOUN
eurjchem-2402	56	12	and	and	CCONJ
eurjchem-2402	56	13	the	the	DET
eurjchem-2402	56	14	optical	optical	ADJ
eurjchem-2402	56	15	path	path	NOUN
eurjchem-2402	56	16	of	of	ADP
eurjchem-2402	56	17	the	the	DET
eurjchem-2402	56	18	cuvette	cuvette	NOUN
eurjchem-2402	56	19	(	(	PUNCT
eurjchem-2402	56	20	b	b	NOUN
eurjchem-2402	56	21	=	=	SYM
eurjchem-2402	56	22	1	1	NUM
eurjchem-2402	56	23	cm	cm	NOUN
eurjchem-2402	56	24	)	)	PUNCT
eurjchem-2402	56	25	,	,	PUNCT
eurjchem-2402	56	26	the	the	DET
eurjchem-2402	56	27	concentration	concentration	NOUN
eurjchem-2402	56	28	of	of	ADP
eurjchem-2402	56	29	ct	ct	PROPN
eurjchem-2402	56	30	-	-	PUNCT
eurjchem-2402	56	31	dna	dna	PROPN
eurjchem-2402	56	32	was	be	AUX
eurjchem-2402	56	33	determined	determine	VERB
eurjchem-2402	56	34	using	use	VERB
eurjchem-2402	56	35	the	the	DET
eurjchem-2402	56	36	lambert	lambert	NOUN
eurjchem-2402	56	37	-	-	PUNCT
eurjchem-2402	56	38	beer	beer	NOUN
eurjchem-2402	56	39	law	law	NOUN
eurjchem-2402	56	40	:	:	PUNCT
eurjchem-2402	57	1	𝐴𝐴260	𝐴𝐴260	PROPN
eurjchem-2402	57	2	=	=	SYM
eurjchem-2402	57	3	𝜀𝜀260	𝜀𝜀260	PROPN
eurjchem-2402	57	4	×	×	NOUN
eurjchem-2402	57	5	𝑏𝑏	𝑏𝑏	NUM
eurjchem-2402	57	6	×	×	NOUN
eurjchem-2402	57	7	𝑐𝑐	𝑐𝑐	INTJ
eurjchem-2402	57	8	(	(	PUNCT
eurjchem-2402	57	9	1	1	NUM
eurjchem-2402	57	10	)	)	PUNCT
eurjchem-2402	57	11	titrations	titration	NOUN
eurjchem-2402	57	12	were	be	AUX
eurjchem-2402	57	13	performed	perform	VERB
eurjchem-2402	57	14	using	use	VERB
eurjchem-2402	57	15	two	two	NUM
eurjchem-2402	57	16	cuvettes	cuvette	NOUN
eurjchem-2402	57	17	:	:	PUNCT
eurjchem-2402	57	18	in	in	ADP
eurjchem-2402	57	19	cuvette	cuvette	PROPN
eurjchem-2402	57	20	i	i	PRON
eurjchem-2402	57	21	,	,	PUNCT
eurjchem-2402	57	22	corresponding	correspond	VERB
eurjchem-2402	57	23	to	to	ADP
eurjchem-2402	57	24	the	the	DET
eurjchem-2402	57	25	blank	blank	NOUN
eurjchem-2402	57	26	,	,	PUNCT
eurjchem-2402	57	27	1700	1700	NUM
eurjchem-2402	57	28	μl	μl	ADP
eurjchem-2402	57	29	of	of	ADP
eurjchem-2402	57	30	tris	tris	ADJ
eurjchem-2402	57	31	buffer	buffer	NOUN
eurjchem-2402	57	32	and	and	CCONJ
eurjchem-2402	57	33	300	300	NUM
eurjchem-2402	57	34	μl	μl	ADP
eurjchem-2402	57	35	of	of	ADP
eurjchem-2402	57	36	dmso	dmso	NOUN
eurjchem-2402	57	37	were	be	AUX
eurjchem-2402	57	38	added	add	VERB
eurjchem-2402	57	39	,	,	PUNCT
eurjchem-2402	57	40	and	and	CCONJ
eurjchem-2402	57	41	in	in	ADP
eurjchem-2402	57	42	cuvette	cuvette	PROPN
eurjchem-2402	57	43	ii	ii	PROPN
eurjchem-2402	57	44	,	,	PUNCT
eurjchem-2402	57	45	1700	1700	NUM
eurjchem-2402	57	46	μl	μl	ADP
eurjchem-2402	57	47	of	of	ADP
eurjchem-2402	57	48	tris	tris	ADJ
eurjchem-2402	57	49	buffer	buffer	NOUN
eurjchem-2402	57	50	were	be	AUX
eurjchem-2402	57	51	added	add	VERB
eurjchem-2402	57	52	and	and	CCONJ
eurjchem-2402	57	53	300	300	NUM
eurjchem-2402	57	54	μl	μl	ADP
eurjchem-2402	57	55	of	of	ADP
eurjchem-2402	57	56	the	the	DET
eurjchem-2402	57	57	solution	solution	NOUN
eurjchem-2402	57	58	of	of	ADP
eurjchem-2402	57	59	the	the	DET
eurjchem-2402	57	60	ruthenium	ruthenium	NOUN
eurjchem-2402	57	61	complex	complex	NOUN
eurjchem-2402	57	62	in	in	ADP
eurjchem-2402	57	63	dmso	dmso	NOUN
eurjchem-2402	57	64	(	(	PUNCT
eurjchem-2402	57	65	in	in	ADP
eurjchem-2402	57	66	a	a	DET
eurjchem-2402	57	67	concentration	concentration	NOUN
eurjchem-2402	57	68	that	that	PRON
eurjchem-2402	57	69	does	do	AUX
eurjchem-2402	57	70	not	not	PART
eurjchem-2402	57	71	exceed	exceed	VERB
eurjchem-2402	57	72	the	the	DET
eurjchem-2402	57	73	lambertbeer	lambertbeer	NOUN
eurjchem-2402	57	74	law	law	NOUN
eurjchem-2402	57	75	)	)	PUNCT
eurjchem-2402	57	76	.	.	PUNCT
eurjchem-2402	58	1	then	then	ADV
eurjchem-2402	58	2	successive	successive	ADJ
eurjchem-2402	58	3	additions	addition	NOUN
eurjchem-2402	58	4	of	of	ADP
eurjchem-2402	58	5	10	10	NUM
eurjchem-2402	58	6	µl	µl	NOUN
eurjchem-2402	58	7	of	of	ADP
eurjchem-2402	58	8	ct	ct	PROPN
eurjchem-2402	58	9	-	-	PUNCT
eurjchem-2402	58	10	dna	dna	PROPN
eurjchem-2402	58	11	were	be	AUX
eurjchem-2402	58	12	performed	perform	VERB
eurjchem-2402	58	13	in	in	ADP
eurjchem-2402	58	14	the	the	DET
eurjchem-2402	58	15	two	two	NUM
eurjchem-2402	58	16	cuvettes	cuvette	NOUN
eurjchem-2402	58	17	.	.	PUNCT
eurjchem-2402	59	1	the	the	DET
eurjchem-2402	59	2	solutions	solution	NOUN
eurjchem-2402	59	3	were	be	AUX
eurjchem-2402	59	4	homogenised	homogenise	VERB
eurjchem-2402	59	5	for	for	ADP
eurjchem-2402	59	6	about	about	ADV
eurjchem-2402	59	7	half	half	DET
eurjchem-2402	59	8	a	a	PRON
eurjchem-2402	59	9	minute	minute	NOUN
eurjchem-2402	59	10	and	and	CCONJ
eurjchem-2402	59	11	then	then	ADV
eurjchem-2402	59	12	the	the	DET
eurjchem-2402	59	13	spectrum	spectrum	NOUN
eurjchem-2402	59	14	was	be	AUX
eurjchem-2402	59	15	recorded	record	VERB
eurjchem-2402	59	16	.	.	PUNCT
eurjchem-2402	60	1	the	the	DET
eurjchem-2402	60	2	interaction	interaction	NOUN
eurjchem-2402	60	3	constant	constant	ADJ
eurjchem-2402	60	4	(	(	PUNCT
eurjchem-2402	60	5	kb	kb	PROPN
eurjchem-2402	60	6	)	)	PUNCT
eurjchem-2402	60	7	with	with	ADP
eurjchem-2402	60	8	dna	dna	PROPN
eurjchem-2402	60	9	was	be	AUX
eurjchem-2402	60	10	determined	determine	VERB
eurjchem-2402	60	11	based	base	VERB
eurjchem-2402	60	12	on	on	ADP
eurjchem-2402	60	13	the	the	DET
eurjchem-2402	60	14	absorption	absorption	NOUN
eurjchem-2402	60	15	maximum	maximum	NOUN
eurjchem-2402	60	16	for	for	ADP
eurjchem-2402	60	17	each	each	DET
eurjchem-2402	60	18	complex	complex	NOUN
eurjchem-2402	60	19	,	,	PUNCT
eurjchem-2402	60	20	using	use	VERB
eurjchem-2402	60	21	equation	equation	NOUN
eurjchem-2402	60	22	(	(	PUNCT
eurjchem-2402	60	23	2	2	NUM
eurjchem-2402	60	24	):	):	PUNCT
eurjchem-2402	61	1	[	[	X
eurjchem-2402	61	2	𝐷𝐷𝐷𝐷𝐷𝐷	𝐷𝐷𝐷𝐷𝐷𝐷	X
eurjchem-2402	61	3	]	]	PUNCT
eurjchem-2402	61	4	�	�	PROPN
eurjchem-2402	61	5	𝜀𝜀𝑎𝑎−𝜀𝜀𝑓𝑓	𝜀𝜀𝑎𝑎−𝜀𝜀𝑓𝑓	NOUN
eurjchem-2402	61	6	�	�	X
eurjchem-2402	61	7	=	=	PUNCT
eurjchem-2402	62	1	[	[	X
eurjchem-2402	62	2	𝐷𝐷𝐷𝐷𝐷𝐷	𝐷𝐷𝐷𝐷𝐷𝐷	X
eurjchem-2402	62	3	]	]	X
eurjchem-2402	62	4	�	�	PROPN
eurjchem-2402	62	5	𝜀𝜀𝑏𝑏−𝜀𝜀𝑓𝑓	𝜀𝜀𝑏𝑏−𝜀𝜀𝑓𝑓	NOUN
eurjchem-2402	62	6	�	�	PROPN
eurjchem-2402	62	7	+	+	CCONJ
eurjchem-2402	62	8	1	1	NUM
eurjchem-2402	62	9	�	�	PROPN
eurjchem-2402	62	10	𝐾𝐾𝑏𝑏	𝐾𝐾𝑏𝑏	PROPN
eurjchem-2402	62	11	�	�	PROPN
eurjchem-2402	62	12	𝜀𝜀𝑏𝑏−𝜀𝜀𝑓𝑓	𝜀𝜀𝑏𝑏−𝜀𝜀𝑓𝑓	NOUN
eurjchem-2402	62	13	�	�	PROPN
eurjchem-2402	62	14	�	�	PROPN
eurjchem-2402	62	15	(	(	PUNCT
eurjchem-2402	62	16	2	2	NUM
eurjchem-2402	62	17	)	)	PUNCT
eurjchem-2402	62	18	where	where	SCONJ
eurjchem-2402	62	19	:	:	PUNCT
eurjchem-2402	62	20	εa	εa	NOUN
eurjchem-2402	62	21	,	,	PUNCT
eurjchem-2402	62	22	εf	εf	NOUN
eurjchem-2402	62	23	,	,	PUNCT
eurjchem-2402	62	24	εb	εb	ADP
eurjchem-2402	62	25	are	be	AUX
eurjchem-2402	62	26	the	the	DET
eurjchem-2402	62	27	aobsd/[complex	aobsd/[complex	PROPN
eurjchem-2402	62	28	]	]	X
eurjchem-2402	62	29	,	,	PUNCT
eurjchem-2402	62	30	the	the	DET
eurjchem-2402	62	31	molar	molar	ADJ
eurjchem-2402	62	32	extinction	extinction	NOUN
eurjchem-2402	62	33	coefficient	coefficient	NOUN
eurjchem-2402	62	34	of	of	ADP
eurjchem-2402	62	35	the	the	DET
eurjchem-2402	62	36	free	free	ADJ
eurjchem-2402	62	37	and	and	CCONJ
eurjchem-2402	62	38	bounded	bounded	ADJ
eurjchem-2402	62	39	metal	metal	NOUN
eurjchem-2402	62	40	complexes	complex	NOUN
eurjchem-2402	62	41	,	,	PUNCT
eurjchem-2402	62	42	respecttively	respecttively	ADV
eurjchem-2402	62	43	.	.	PUNCT
eurjchem-2402	63	1	2.4	2.4	NUM
eurjchem-2402	63	2	.	.	PUNCT
eurjchem-2402	64	1	dna	dna	PROPN
eurjchem-2402	64	2	interaction	interaction	NOUN
eurjchem-2402	64	3	by	by	ADP
eurjchem-2402	64	4	electrochemical	electrochemical	ADJ
eurjchem-2402	64	5	studies	study	NOUN
eurjchem-2402	64	6	the	the	DET
eurjchem-2402	64	7	electrochemical	electrochemical	ADJ
eurjchem-2402	64	8	characterization	characterization	NOUN
eurjchem-2402	64	9	of	of	ADP
eurjchem-2402	64	10	the	the	DET
eurjchem-2402	64	11	[	[	X
eurjchem-2402	64	12	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	64	13	]	]	X
eurjchem-2402	64	14	complex	complex	NOUN
eurjchem-2402	64	15	was	be	AUX
eurjchem-2402	64	16	performed	perform	VERB
eurjchem-2402	64	17	using	use	VERB
eurjchem-2402	64	18	a	a	DET
eurjchem-2402	64	19	potentiostat	potentiostat	ADJ
eurjchem-2402	64	20	/	/	SYM
eurjchem-2402	64	21	galvanostat	galvanostat	NOUN
eurjchem-2402	64	22	autolab	autolab	NOUN
eurjchem-2402	64	23	model	model	NOUN
eurjchem-2402	64	24	302n	302n	PROPN
eurjchem-2402	64	25	,	,	PUNCT
eurjchem-2402	64	26	using	use	VERB
eurjchem-2402	64	27	a	a	DET
eurjchem-2402	64	28	glass	glass	NOUN
eurjchem-2402	64	29	cell	cell	NOUN
eurjchem-2402	64	30	and	and	CCONJ
eurjchem-2402	64	31	a	a	DET
eurjchem-2402	64	32	three	three	NUM
eurjchem-2402	64	33	-	-	PUNCT
eurjchem-2402	64	34	electrode	electrode	NOUN
eurjchem-2402	64	35	system	system	NOUN
eurjchem-2402	64	36	,	,	PUNCT
eurjchem-2402	64	37	in	in	ADP
eurjchem-2402	64	38	which	which	PRON
eurjchem-2402	64	39	platinum	platinum	NOUN
eurjchem-2402	64	40	was	be	AUX
eurjchem-2402	64	41	used	use	VERB
eurjchem-2402	64	42	as	as	ADP
eurjchem-2402	64	43	the	the	DET
eurjchem-2402	64	44	working	working	NOUN
eurjchem-2402	64	45	and	and	CCONJ
eurjchem-2402	64	46	auxiliary	auxiliary	ADJ
eurjchem-2402	64	47	electrode	electrode	NOUN
eurjchem-2402	64	48	and	and	CCONJ
eurjchem-2402	64	49	ag	ag	PROPN
eurjchem-2402	64	50	/	/	SYM
eurjchem-2402	64	51	agcl	agcl	NOUN
eurjchem-2402	64	52	(	(	PUNCT
eurjchem-2402	64	53	3.0	3.0	NUM
eurjchem-2402	64	54	mol	mol	NOUN
eurjchem-2402	64	55	/	/	SYM
eurjchem-2402	64	56	l	l	NOUN
eurjchem-2402	64	57	kcl	kcl	PROPN
eurjchem-2402	64	58	)	)	PUNCT
eurjchem-2402	64	59	as	as	ADP
eurjchem-2402	64	60	the	the	DET
eurjchem-2402	64	61	reference	reference	NOUN
eurjchem-2402	64	62	electrode	electrode	NOUN
eurjchem-2402	64	63	.	.	PUNCT
eurjchem-2402	65	1	the	the	DET
eurjchem-2402	65	2	[	[	X
eurjchem-2402	65	3	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	65	4	]	]	X
eurjchem-2402	65	5	complex	complex	ADJ
eurjchem-2402	65	6	solution	solution	NOUN
eurjchem-2402	65	7	was	be	AUX
eurjchem-2402	65	8	prepared	prepare	VERB
eurjchem-2402	65	9	in	in	ADP
eurjchem-2402	65	10	dichloromethane	dichloromethane	NOUN
eurjchem-2402	65	11	(	(	PUNCT
eurjchem-2402	65	12	0.1	0.1	NUM
eurjchem-2402	65	13	mol	mol	NOUN
eurjchem-2402	65	14	/	/	SYM
eurjchem-2402	65	15	l	l	NOUN
eurjchem-2402	65	16	of	of	ADP
eurjchem-2402	65	17	tetrabutyl	tetrabutyl	NOUN
eurjchem-2402	65	18	ammonium	ammonium	NOUN
eurjchem-2402	65	19	perchlorate	perchlorate	NOUN
eurjchem-2402	65	20	(	(	PUNCT
eurjchem-2402	65	21	ptba	ptba	NOUN
eurjchem-2402	65	22	)	)	PUNCT
eurjchem-2402	65	23	)	)	PUNCT
eurjchem-2402	65	24	at	at	ADP
eurjchem-2402	65	25	a	a	DET
eurjchem-2402	65	26	concentration	concentration	NOUN
eurjchem-2402	65	27	of	of	ADP
eurjchem-2402	65	28	2×10	2×10	NUM
eurjchem-2402	65	29	-	-	SYM
eurjchem-2402	65	30	4	4	NUM
eurjchem-2402	65	31	mol	mol	ADP
eurjchem-2402	65	32	/	/	SYM
eurjchem-2402	65	33	l.	l.	PROPN
eurjchem-2402	65	34	cyclic	cyclic	PROPN
eurjchem-2402	65	35	voltammograms	voltammogram	NOUN
eurjchem-2402	65	36	were	be	AUX
eurjchem-2402	65	37	recorded	record	VERB
eurjchem-2402	65	38	in	in	ADP
eurjchem-2402	65	39	the	the	DET
eurjchem-2402	65	40	range	range	NOUN
eurjchem-2402	65	41	of	of	ADP
eurjchem-2402	65	42	0	0	NUM
eurjchem-2402	65	43	to	to	ADP
eurjchem-2402	65	44	+1.6	+1.6	PROPN
eurjchem-2402	65	45	v	v	NOUN
eurjchem-2402	65	46	at	at	ADP
eurjchem-2402	65	47	different	different	ADJ
eurjchem-2402	65	48	scan	scan	ADJ
eurjchem-2402	65	49	rates	rate	NOUN
eurjchem-2402	65	50	(	(	PUNCT
eurjchem-2402	65	51	10	10	NUM
eurjchem-2402	65	52	-	-	SYM
eurjchem-2402	65	53	100	100	NUM
eurjchem-2402	65	54	mv	mv	PROPN
eurjchem-2402	65	55	/	/	SYM
eurjchem-2402	65	56	s	s	PROPN
eurjchem-2402	65	57	)	)	PUNCT
eurjchem-2402	65	58	.	.	PUNCT
eurjchem-2402	66	1	to	to	PART
eurjchem-2402	66	2	assess	assess	VERB
eurjchem-2402	66	3	the	the	DET
eurjchem-2402	66	4	interaction	interaction	NOUN
eurjchem-2402	66	5	of	of	ADP
eurjchem-2402	66	6	the	the	DET
eurjchem-2402	66	7	[	[	X
eurjchem-2402	66	8	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	66	9	]	]	X
eurjchem-2402	66	10	complex	complex	ADJ
eurjchem-2402	66	11	with	with	ADP
eurjchem-2402	66	12	ct	ct	PROPN
eurjchem-2402	66	13	-	-	PUNCT
eurjchem-2402	66	14	dna	dna	PROPN
eurjchem-2402	66	15	,	,	PUNCT
eurjchem-2402	66	16	the	the	DET
eurjchem-2402	66	17	square	square	ADJ
eurjchem-2402	66	18	-	-	PUNCT
eurjchem-2402	66	19	wave	wave	NOUN
eurjchem-2402	66	20	voltammetry	voltammetry	NOUN
eurjchem-2402	66	21	technique	technique	NOUN
eurjchem-2402	66	22	was	be	AUX
eurjchem-2402	66	23	used	use	VERB
eurjchem-2402	66	24	.	.	PUNCT
eurjchem-2402	67	1	a	a	DET
eurjchem-2402	67	2	system	system	NOUN
eurjchem-2402	67	3	of	of	ADP
eurjchem-2402	67	4	three	three	NUM
eurjchem-2402	67	5	electrodes	electrode	NOUN
eurjchem-2402	67	6	was	be	AUX
eurjchem-2402	67	7	used	use	VERB
eurjchem-2402	67	8	,	,	PUNCT
eurjchem-2402	67	9	with	with	ADP
eurjchem-2402	67	10	the	the	DET
eurjchem-2402	67	11	glassy	glassy	NOUN
eurjchem-2402	67	12	carbon	carbon	NOUN
eurjchem-2402	67	13	working	work	VERB
eurjchem-2402	67	14	electrode	electrode	NOUN
eurjchem-2402	67	15	,	,	PUNCT
eurjchem-2402	67	16	ag	ag	PROPN
eurjchem-2402	67	17	/	/	SYM
eurjchem-2402	67	18	agcl	agcl	NOUN
eurjchem-2402	67	19	(	(	PUNCT
eurjchem-2402	67	20	3.0	3.0	NUM
eurjchem-2402	67	21	mol	mol	NOUN
eurjchem-2402	67	22	/	/	SYM
eurjchem-2402	67	23	l	l	NOUN
eurjchem-2402	67	24	kcl	kcl	PROPN
eurjchem-2402	67	25	)	)	PUNCT
eurjchem-2402	67	26	as	as	ADP
eurjchem-2402	67	27	a	a	DET
eurjchem-2402	67	28	reference	reference	NOUN
eurjchem-2402	67	29	electrode	electrode	NOUN
eurjchem-2402	67	30	and	and	CCONJ
eurjchem-2402	67	31	as	as	ADP
eurjchem-2402	67	32	the	the	DET
eurjchem-2402	67	33	auxiliary	auxiliary	ADJ
eurjchem-2402	67	34	electrode	electrode	NOUN
eurjchem-2402	67	35	,	,	PUNCT
eurjchem-2402	67	36	a	a	DET
eurjchem-2402	67	37	platinum	platinum	NOUN
eurjchem-2402	67	38	plate	plate	NOUN
eurjchem-2402	67	39	.	.	PUNCT
eurjchem-2402	68	1	the	the	DET
eurjchem-2402	68	2	[	[	X
eurjchem-2402	68	3	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	68	4	]	]	X
eurjchem-2402	68	5	complex	complex	NOUN
eurjchem-2402	68	6	was	be	AUX
eurjchem-2402	68	7	prepared	prepare	VERB
eurjchem-2402	68	8	in	in	ADP
eurjchem-2402	68	9	a	a	DET
eurjchem-2402	68	10	mixture	mixture	NOUN
eurjchem-2402	68	11	of	of	ADP
eurjchem-2402	68	12	tris	tris	ADJ
eurjchem-2402	68	13	-	-	PUNCT
eurjchem-2402	68	14	hcl	hcl	NOUN
eurjchem-2402	68	15	buffer	buffer	NOUN
eurjchem-2402	68	16	(	(	PUNCT
eurjchem-2402	68	17	4.5	4.5	NUM
eurjchem-2402	68	18	mm	mm	NOUN
eurjchem-2402	68	19	tris	tris	PROPN
eurjchem-2402	68	20	-	-	PUNCT
eurjchem-2402	68	21	hcl	hcl	NOUN
eurjchem-2402	68	22	,	,	PUNCT
eurjchem-2402	68	23	0.5	0.5	NUM
eurjchem-2402	68	24	mm	mm	NOUN
eurjchem-2402	68	25	tris	tris	NOUN
eurjchem-2402	68	26	-	-	PUNCT
eurjchem-2402	68	27	base	base	NOUN
eurjchem-2402	68	28	and	and	CCONJ
eurjchem-2402	68	29	0.1	0.1	NUM
eurjchem-2402	68	30	mol	mol	NOUN
eurjchem-2402	68	31	/	/	SYM
eurjchem-2402	68	32	l	l	NOUN
eurjchem-2402	68	33	nacl	nacl	NOUN
eurjchem-2402	68	34	,	,	PUNCT
eurjchem-2402	68	35	ph	ph	NOUN
eurjchem-2402	68	36	=	=	NOUN
eurjchem-2402	68	37	7.4	7.4	NUM
eurjchem-2402	68	38	)	)	PUNCT
eurjchem-2402	68	39	with	with	ADP
eurjchem-2402	68	40	40	40	NUM
eurjchem-2402	68	41	%	%	NOUN
eurjchem-2402	68	42	dmso	dmso	NOUN
eurjchem-2402	68	43	at	at	ADP
eurjchem-2402	68	44	a	a	DET
eurjchem-2402	68	45	concentration	concentration	NOUN
eurjchem-2402	68	46	of	of	ADP
eurjchem-2402	68	47	1×10	1×10	NUM
eurjchem-2402	68	48	-	-	SYM
eurjchem-2402	68	49	4	4	NUM
eurjchem-2402	68	50	m.	m.	NOUN
eurjchem-2402	68	51	first	first	ADV
eurjchem-2402	68	52	,	,	PUNCT
eurjchem-2402	68	53	the	the	DET
eurjchem-2402	68	54	voltammetric	voltammetric	ADJ
eurjchem-2402	68	55	profile	profile	NOUN
eurjchem-2402	68	56	of	of	ADP
eurjchem-2402	68	57	the	the	DET
eurjchem-2402	68	58	complex	complex	NOUN
eurjchem-2402	68	59	was	be	AUX
eurjchem-2402	68	60	recorded	record	VERB
eurjchem-2402	68	61	and	and	CCONJ
eurjchem-2402	68	62	then	then	ADV
eurjchem-2402	68	63	successive	successive	VERB
eurjchem-2402	68	64	10	10	NUM
eurjchem-2402	68	65	µl	µl	ADP
eurjchem-2402	68	66	aliquots	aliquot	NOUN
eurjchem-2402	68	67	of	of	ADP
eurjchem-2402	68	68	a	a	DET
eurjchem-2402	68	69	ct	ct	ADJ
eurjchem-2402	68	70	-	-	PUNCT
eurjchem-2402	68	71	dna	dna	NOUN
eurjchem-2402	68	72	solution	solution	NOUN
eurjchem-2402	68	73	(	(	PUNCT
eurjchem-2402	68	74	4.67×10	4.67×10	NOUN
eurjchem-2402	68	75	-	-	SYM
eurjchem-2402	68	76	3	3	NUM
eurjchem-2402	68	77	m	m	NOUN
eurjchem-2402	68	78	)	)	PUNCT
eurjchem-2402	68	79	were	be	AUX
eurjchem-2402	68	80	added	add	VERB
eurjchem-2402	68	81	to	to	ADP
eurjchem-2402	68	82	the	the	DET
eurjchem-2402	68	83	complex	complex	ADJ
eurjchem-2402	68	84	solution	solution	NOUN
eurjchem-2402	68	85	.	.	PUNCT
eurjchem-2402	69	1	with	with	ADP
eurjchem-2402	69	2	each	each	DET
eurjchem-2402	69	3	addition	addition	NOUN
eurjchem-2402	69	4	of	of	ADP
eurjchem-2402	69	5	ctdna	ctdna	NOUN
eurjchem-2402	69	6	,	,	PUNCT
eurjchem-2402	69	7	the	the	DET
eurjchem-2402	69	8	system	system	NOUN
eurjchem-2402	69	9	was	be	AUX
eurjchem-2402	69	10	shaken	shake	VERB
eurjchem-2402	69	11	for	for	ADP
eurjchem-2402	69	12	a	a	DET
eurjchem-2402	69	13	period	period	NOUN
eurjchem-2402	69	14	of	of	ADP
eurjchem-2402	69	15	5	5	NUM
eurjchem-2402	69	16	min	min	NOUN
eurjchem-2402	69	17	and	and	CCONJ
eurjchem-2402	69	18	then	then	ADV
eurjchem-2402	69	19	the	the	DET
eurjchem-2402	69	20	voltammogram	voltammogram	NOUN
eurjchem-2402	69	21	was	be	AUX
eurjchem-2402	69	22	recorded	record	VERB
eurjchem-2402	69	23	.	.	PUNCT
eurjchem-2402	70	1	2.5	2.5	NUM
eurjchem-2402	70	2	.	.	PUNCT
eurjchem-2402	70	3	viscosity	viscosity	NOUN
eurjchem-2402	70	4	to	to	PART
eurjchem-2402	70	5	determine	determine	VERB
eurjchem-2402	70	6	the	the	DET
eurjchem-2402	70	7	changes	change	NOUN
eurjchem-2402	70	8	that	that	PRON
eurjchem-2402	70	9	occur	occur	VERB
eurjchem-2402	70	10	in	in	ADP
eurjchem-2402	70	11	the	the	DET
eurjchem-2402	70	12	viscosity	viscosity	NOUN
eurjchem-2402	70	13	of	of	ADP
eurjchem-2402	70	14	a	a	DET
eurjchem-2402	70	15	ctdna	ctdna	NOUN
eurjchem-2402	70	16	solution	solution	NOUN
eurjchem-2402	70	17	,	,	PUNCT
eurjchem-2402	70	18	solutions	solution	NOUN
eurjchem-2402	70	19	with	with	ADP
eurjchem-2402	70	20	different	different	ADJ
eurjchem-2402	70	21	ct	ct	PROPN
eurjchem-2402	70	22	-	-	PUNCT
eurjchem-2402	70	23	dna	dna	NOUN
eurjchem-2402	70	24	:	:	PUNCT
eurjchem-2402	70	25	metal	metal	NOUN
eurjchem-2402	70	26	complex	complex	ADJ
eurjchem-2402	70	27	molar	molar	ADJ
eurjchem-2402	70	28	ratios	ratio	NOUN
eurjchem-2402	70	29	of	of	ADP
eurjchem-2402	70	30	0.2	0.2	NUM
eurjchem-2402	70	31	,	,	PUNCT
eurjchem-2402	70	32	0.3	0.3	NUM
eurjchem-2402	70	33	,	,	PUNCT
eurjchem-2402	70	34	0.4	0.4	NUM
eurjchem-2402	70	35	,	,	PUNCT
eurjchem-2402	70	36	0.5	0.5	NUM
eurjchem-2402	70	37	and	and	CCONJ
eurjchem-2402	70	38	0.6	0.6	NUM
eurjchem-2402	70	39	were	be	AUX
eurjchem-2402	70	40	prepared	prepare	VERB
eurjchem-2402	70	41	.	.	PUNCT
eurjchem-2402	71	1	viscosity	viscosity	NOUN
eurjchem-2402	71	2	measurements	measurement	NOUN
eurjchem-2402	71	3	were	be	AUX
eurjchem-2402	71	4	made	make	VERB
eurjchem-2402	71	5	using	use	VERB
eurjchem-2402	71	6	an	an	DET
eurjchem-2402	71	7	oswald	oswald	NOUN
eurjchem-2402	71	8	viscometer	viscometer	NOUN
eurjchem-2402	71	9	in	in	ADP
eurjchem-2402	71	10	the	the	DET
eurjchem-2402	71	11	thermostatic	thermostatic	ADJ
eurjchem-2402	71	12	water	water	NOUN
eurjchem-2402	71	13	bath	bath	NOUN
eurjchem-2402	71	14	at	at	ADP
eurjchem-2402	71	15	25	25	NUM
eurjchem-2402	71	16	°	°	PROPN
eurjchem-2402	71	17	c.	c.	PROPN
eurjchem-2402	71	18	thus	thus	ADV
eurjchem-2402	71	19	,	,	PUNCT
eurjchem-2402	71	20	keeping	keep	VERB
eurjchem-2402	71	21	the	the	DET
eurjchem-2402	71	22	concentration	concentration	NOUN
eurjchem-2402	71	23	of	of	ADP
eurjchem-2402	71	24	ct	ct	PROPN
eurjchem-2402	71	25	-	-	PUNCT
eurjchem-2402	71	26	dna	dna	NOUN
eurjchem-2402	71	27	constant	constant	ADJ
eurjchem-2402	71	28	(	(	PUNCT
eurjchem-2402	71	29	3.66×10	3.66×10	NUM
eurjchem-2402	71	30	-	-	SYM
eurjchem-2402	71	31	3	3	NUM
eurjchem-2402	71	32	mol	mol	NOUN
eurjchem-2402	71	33	/	/	SYM
eurjchem-2402	71	34	l	l	NOUN
eurjchem-2402	71	35	)	)	PUNCT
eurjchem-2402	71	36	,	,	PUNCT
eurjchem-2402	71	37	a	a	DET
eurjchem-2402	71	38	viscosity	viscosity	NOUN
eurjchem-2402	71	39	ratio	ratio	NOUN
eurjchem-2402	71	40	η	η	PROPN
eurjchem-2402	71	41	can	can	AUX
eurjchem-2402	71	42	be	be	AUX
eurjchem-2402	71	43	obtained	obtain	VERB
eurjchem-2402	71	44	from	from	ADP
eurjchem-2402	71	45	the	the	DET
eurjchem-2402	71	46	following	follow	VERB
eurjchem-2402	71	47	equation	equation	NOUN
eurjchem-2402	71	48	:	:	PUNCT
eurjchem-2402	71	49	𝜂𝜂	𝜂𝜂	ADP
eurjchem-2402	71	50	=	=	SYM
eurjchem-2402	71	51	𝑡𝑡−𝑡𝑡0	𝑡𝑡−𝑡𝑡0	X
eurjchem-2402	71	52	𝑡𝑡0	𝑡𝑡0	PROPN
eurjchem-2402	71	53	(	(	PUNCT
eurjchem-2402	71	54	3	3	NUM
eurjchem-2402	71	55	)	)	PUNCT
eurjchem-2402	71	56	where	where	SCONJ
eurjchem-2402	71	57	:	:	PUNCT
eurjchem-2402	71	58	t	t	PROPN
eurjchem-2402	71	59	is	be	AUX
eurjchem-2402	71	60	the	the	DET
eurjchem-2402	71	61	elution	elution	NOUN
eurjchem-2402	71	62	time	time	NOUN
eurjchem-2402	71	63	of	of	ADP
eurjchem-2402	71	64	the	the	DET
eurjchem-2402	71	65	solution	solution	NOUN
eurjchem-2402	71	66	ct	ct	PROPN
eurjchem-2402	71	67	-	-	PUNCT
eurjchem-2402	71	68	dna	dna	NOUN
eurjchem-2402	71	69	:	:	PUNCT
eurjchem-2402	71	70	metal	metal	NOUN
eurjchem-2402	71	71	complex	complex	NOUN
eurjchem-2402	71	72	,	,	PUNCT
eurjchem-2402	71	73	and	and	CCONJ
eurjchem-2402	71	74	𝑡𝑡0	𝑡𝑡0	ADJ
eurjchem-2402	71	75	is	be	AUX
eurjchem-2402	71	76	the	the	DET
eurjchem-2402	71	77	elution	elution	NOUN
eurjchem-2402	71	78	time	time	NOUN
eurjchem-2402	71	79	of	of	ADP
eurjchem-2402	71	80	free	free	ADJ
eurjchem-2402	71	81	dna	dna	NOUN
eurjchem-2402	71	82	.	.	PUNCT
eurjchem-2402	72	1	with	with	SCONJ
eurjchem-2402	72	2	the	the	DET
eurjchem-2402	72	3	data	datum	NOUN
eurjchem-2402	72	4	obtained	obtain	VERB
eurjchem-2402	72	5	,	,	PUNCT
eurjchem-2402	72	6	it	it	PRON
eurjchem-2402	72	7	is	be	AUX
eurjchem-2402	72	8	possible	possible	ADJ
eurjchem-2402	72	9	to	to	PART
eurjchem-2402	72	10	construct	construct	VERB
eurjchem-2402	72	11	a	a	DET
eurjchem-2402	72	12	graph	graph	NOUN
eurjchem-2402	72	13	of	of	ADP
eurjchem-2402	72	14	the	the	DET
eurjchem-2402	72	15	relative	relative	ADJ
eurjchem-2402	72	16	viscosity	viscosity	NOUN
eurjchem-2402	72	17	vs.	vs.	X
eurjchem-2402	72	18	[	[	X
eurjchem-2402	72	19	dna]/[complex	dna]/[complex	X
eurjchem-2402	72	20	]	]	X
eurjchem-2402	72	21	,	,	PUNCT
eurjchem-2402	72	22	and	and	CCONJ
eurjchem-2402	72	23	to	to	PART
eurjchem-2402	72	24	evaluate	evaluate	VERB
eurjchem-2402	72	25	the	the	DET
eurjchem-2402	72	26	possible	possible	ADJ
eurjchem-2402	72	27	changes	change	NOUN
eurjchem-2402	72	28	in	in	ADP
eurjchem-2402	72	29	the	the	DET
eurjchem-2402	72	30	viscosity	viscosity	NOUN
eurjchem-2402	72	31	of	of	ADP
eurjchem-2402	72	32	ct	ct	PROPN
eurjchem-2402	72	33	-	-	PUNCT
eurjchem-2402	72	34	dna	dna	PROPN
eurjchem-2402	72	35	,	,	PUNCT
eurjchem-2402	72	36	in	in	ADP
eurjchem-2402	72	37	the	the	DET
eurjchem-2402	72	38	presence	presence	NOUN
eurjchem-2402	72	39	of	of	ADP
eurjchem-2402	72	40	ruthenium	ruthenium	NOUN
eurjchem-2402	72	41	complex	complex	NOUN
eurjchem-2402	72	42	.	.	PUNCT
eurjchem-2402	73	1	2.6	2.6	NUM
eurjchem-2402	73	2	.	.	PUNCT
eurjchem-2402	74	1	x	x	X
eurjchem-2402	74	2	-	-	NOUN
eurjchem-2402	74	3	ray	ray	NOUN
eurjchem-2402	74	4	crystallography	crystallography	NOUN
eurjchem-2402	74	5	study	study	NOUN
eurjchem-2402	74	6	single	single	ADJ
eurjchem-2402	74	7	crystals	crystal	NOUN
eurjchem-2402	74	8	of	of	ADP
eurjchem-2402	74	9	[	[	X
eurjchem-2402	74	10	rucl2(dppe)2]cl	rucl2(dppe)2]cl	PROPN
eurjchem-2402	74	11	were	be	AUX
eurjchem-2402	74	12	obtained	obtain	VERB
eurjchem-2402	74	13	at	at	ADP
eurjchem-2402	74	14	room	room	NOUN
eurjchem-2402	74	15	temperature	temperature	NOUN
eurjchem-2402	74	16	by	by	ADP
eurjchem-2402	74	17	slow	slow	ADJ
eurjchem-2402	74	18	solvent	solvent	ADJ
eurjchem-2402	74	19	evaporation	evaporation	NOUN
eurjchem-2402	74	20	of	of	ADP
eurjchem-2402	74	21	the	the	DET
eurjchem-2402	74	22	electrochemical	electrochemical	ADJ
eurjchem-2402	74	23	solution	solution	NOUN
eurjchem-2402	74	24	.	.	PUNCT
eurjchem-2402	75	1	the	the	DET
eurjchem-2402	75	2	x	x	ADJ
eurjchem-2402	75	3	-	-	NOUN
eurjchem-2402	75	4	ray	ray	NOUN
eurjchem-2402	75	5	diffraction	diffraction	NOUN
eurjchem-2402	75	6	experiment	experiment	NOUN
eurjchem-2402	75	7	was	be	AUX
eurjchem-2402	75	8	carried	carry	VERB
eurjchem-2402	75	9	out	out	ADP
eurjchem-2402	75	10	at	at	ADP
eurjchem-2402	75	11	room	room	NOUN
eurjchem-2402	75	12	temperature	temperature	NOUN
eurjchem-2402	75	13	on	on	ADP
eurjchem-2402	75	14	an	an	DET
eurjchem-2402	75	15	enraf	enraf	ADJ
eurjchem-2402	75	16	-	-	PUNCT
eurjchem-2402	75	17	nonius	nonius	NOUN
eurjchem-2402	75	18	kappa	kappa	ADJ
eurjchem-2402	75	19	-	-	ADJ
eurjchem-2402	75	20	ccd	ccd	ADJ
eurjchem-2402	75	21	diffractometer	diffractometer	NOUN
eurjchem-2402	75	22	using	use	VERB
eurjchem-2402	75	23	the	the	DET
eurjchem-2402	75	24	mokα	mokα	ADJ
eurjchem-2402	75	25	radiation	radiation	NOUN
eurjchem-2402	75	26	(	(	PUNCT
eurjchem-2402	75	27	λ	λ	X
eurjchem-2402	75	28	=	=	SYM
eurjchem-2402	75	29	0.71073	0.71073	NUM
eurjchem-2402	75	30	å	å	NOUN
eurjchem-2402	75	31	)	)	PUNCT
eurjchem-2402	75	32	monochromated	monochromate	VERB
eurjchem-2402	75	33	with	with	ADP
eurjchem-2402	75	34	graphite	graphite	NOUN
eurjchem-2402	75	35	.	.	PUNCT
eurjchem-2402	76	1	the	the	DET
eurjchem-2402	76	2	crystal	crystal	NOUN
eurjchem-2402	76	3	structure	structure	NOUN
eurjchem-2402	76	4	of	of	ADP
eurjchem-2402	76	5	trans[rucl2(dppe)2]cl	trans[rucl2(dppe)2]cl	NOUN
eurjchem-2402	76	6	was	be	AUX
eurjchem-2402	76	7	solved	solve	VERB
eurjchem-2402	76	8	by	by	ADP
eurjchem-2402	76	9	the	the	DET
eurjchem-2402	76	10	direct	direct	ADJ
eurjchem-2402	76	11	method	method	NOUN
eurjchem-2402	76	12	and	and	CCONJ
eurjchem-2402	76	13	refined	refine	VERB
eurjchem-2402	76	14	using	use	VERB
eurjchem-2402	76	15	the	the	DET
eurjchem-2402	76	16	shelxs-97	shelxs-97	PROPN
eurjchem-2402	76	17	and	and	CCONJ
eurjchem-2402	76	18	shelxl-97	shelxl-97	PROPN
eurjchem-2402	76	19	programmes	programme	NOUN
eurjchem-2402	76	20	(	(	PUNCT
eurjchem-2402	76	21	table	table	NOUN
eurjchem-2402	76	22	1	1	NUM
eurjchem-2402	76	23	)	)	PUNCT
eurjchem-2402	77	1	[	[	X
eurjchem-2402	77	2	24	24	NUM
eurjchem-2402	77	3	]	]	PUNCT
eurjchem-2402	77	4	,	,	PUNCT
eurjchem-2402	77	5	respectively	respectively	ADV
eurjchem-2402	77	6	.	.	PUNCT
eurjchem-2402	78	1	absorption	absorption	NOUN
eurjchem-2402	78	2	corrections	correction	NOUN
eurjchem-2402	78	3	were	be	AUX
eurjchem-2402	78	4	carried	carry	VERB
eurjchem-2402	78	5	out	out	ADP
eurjchem-2402	78	6	using	use	VERB
eurjchem-2402	78	7	the	the	DET
eurjchem-2402	78	8	gaussian	gaussian	ADJ
eurjchem-2402	78	9	method	method	NOUN
eurjchem-2402	78	10	,	,	PUNCT
eurjchem-2402	78	11	and	and	CCONJ
eurjchem-2402	78	12	all	all	DET
eurjchem-2402	78	13	non	non	ADJ
eurjchem-2402	78	14	-	-	ADJ
eurjchem-2402	78	15	hydrogen	hydrogen	ADJ
eurjchem-2402	78	16	atoms	atom	NOUN
eurjchem-2402	78	17	of	of	ADP
eurjchem-2402	78	18	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	78	19	were	be	AUX
eurjchem-2402	78	20	located	locate	VERB
eurjchem-2402	78	21	and	and	CCONJ
eurjchem-2402	78	22	refined	refine	VERB
eurjchem-2402	78	23	with	with	ADP
eurjchem-2402	78	24	anisotropic	anisotropic	NOUN
eurjchem-2402	78	25	thermal	thermal	ADJ
eurjchem-2402	78	26	parameters	parameter	NOUN
eurjchem-2402	78	27	.	.	PUNCT
eurjchem-2402	79	1	the	the	DET
eurjchem-2402	79	2	c	c	NOUN
eurjchem-2402	79	3	-	-	PUNCT
eurjchem-2402	79	4	h	h	NOUN
eurjchem-2402	79	5	aromatic	aromatic	ADJ
eurjchem-2402	79	6	hydrogen	hydrogen	NOUN
eurjchem-2402	79	7	atoms	atom	NOUN
eurjchem-2402	79	8	were	be	AUX
eurjchem-2402	79	9	added	add	VERB
eurjchem-2402	79	10	with	with	ADP
eurjchem-2402	79	11	c	c	NOUN
eurjchem-2402	79	12	-	-	PUNCT
eurjchem-2402	79	13	h	h	NOUN
eurjchem-2402	79	14	distance	distance	NOUN
eurjchem-2402	79	15	,	,	PUNCT
eurjchem-2402	79	16	fixed	fix	VERB
eurjchem-2402	79	17	at	at	ADP
eurjchem-2402	79	18	0.93	0.93	NUM
eurjchem-2402	79	19	å	å	NOUN
eurjchem-2402	79	20	,	,	PUNCT
eurjchem-2402	79	21	and	and	CCONJ
eurjchem-2402	79	22	refined	refine	VERB
eurjchem-2402	79	23	with	with	ADP
eurjchem-2402	79	24	fixed	fix	VERB
eurjchem-2402	79	25	displacement	displacement	ADJ
eurjchem-2402	79	26	parameters	parameter	NOUN
eurjchem-2402	80	1	[	[	X
eurjchem-2402	80	2	uiso(h	uiso(h	PROPN
eurjchem-2402	80	3	)	)	PUNCT
eurjchem-2402	80	4	=	=	PROPN
eurjchem-2402	80	5	1.2	1.2	NUM
eurjchem-2402	80	6	ueq(csp2	ueq(csp2	NOUN
eurjchem-2402	80	7	)	)	PUNCT
eurjchem-2402	80	8	]	]	PUNCT
eurjchem-2402	80	9	.	.	PUNCT
eurjchem-2402	81	1	campideli	campideli	PROPN
eurjchem-2402	81	2	et	et	PROPN
eurjchem-2402	81	3	al	al	PROPN
eurjchem-2402	81	4	.	.	PUNCT
eurjchem-2402	81	5	/	/	SYM
eurjchem-2402	81	6	european	european	PROPN
eurjchem-2402	81	7	journal	journal	PROPN
eurjchem-2402	81	8	of	of	ADP
eurjchem-2402	81	9	chemistry	chemistry	NOUN
eurjchem-2402	81	10	14	14	NUM
eurjchem-2402	81	11	(	(	PUNCT
eurjchem-2402	81	12	2	2	NUM
eurjchem-2402	81	13	)	)	PUNCT
eurjchem-2402	81	14	(	(	PUNCT
eurjchem-2402	81	15	2023	2023	NUM
eurjchem-2402	81	16	)	)	PUNCT
eurjchem-2402	81	17	193	193	NUM
eurjchem-2402	81	18	-	-	SYM
eurjchem-2402	81	19	201	201	NUM
eurjchem-2402	81	20	195	195	NUM
eurjchem-2402	81	21	2023	2023	NUM
eurjchem-2402	81	22	–	–	PUNCT
eurjchem-2402	81	23	european	european	ADJ
eurjchem-2402	81	24	journal	journal	NOUN
eurjchem-2402	81	25	of	of	ADP
eurjchem-2402	81	26	chemistry	chemistry	NOUN
eurjchem-2402	81	27	–	–	PUNCT
eurjchem-2402	81	28	cc	cc	NOUN
eurjchem-2402	81	29	by	by	ADP
eurjchem-2402	81	30	nc	nc	PROPN
eurjchem-2402	81	31	–	–	PUNCT
eurjchem-2402	81	32	doi	doi	NOUN
eurjchem-2402	81	33	:	:	PUNCT
eurjchem-2402	81	34	10.5155	10.5155	NUM
eurjchem-2402	81	35	/	/	SYM
eurjchem-2402	81	36	eurjchem.14.2.193	eurjchem.14.2.193	NUM
eurjchem-2402	81	37	-	-	SYM
eurjchem-2402	81	38	201.2402	201.2402	NUM
eurjchem-2402	81	39	table	table	NOUN
eurjchem-2402	81	40	1	1	NUM
eurjchem-2402	81	41	.	.	PUNCT
eurjchem-2402	82	1	crystal	crystal	NOUN
eurjchem-2402	82	2	data	datum	NOUN
eurjchem-2402	82	3	and	and	CCONJ
eurjchem-2402	82	4	structure	structure	NOUN
eurjchem-2402	82	5	refinement	refinement	NOUN
eurjchem-2402	82	6	for	for	ADP
eurjchem-2402	82	7	complex	complex	ADJ
eurjchem-2402	82	8	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	82	9	.	.	PUNCT
eurjchem-2402	83	1	empirical	empirical	ADJ
eurjchem-2402	83	2	formula	formula	NOUN
eurjchem-2402	83	3	c52h48cl4p4ru	c52h48cl4p4ru	PROPN
eurjchem-2402	83	4	formula	formula	NOUN
eurjchem-2402	83	5	weight	weight	NOUN
eurjchem-2402	83	6	(	(	PUNCT
eurjchem-2402	83	7	g	g	NOUN
eurjchem-2402	83	8	/	/	SYM
eurjchem-2402	83	9	mol	mol	NOUN
eurjchem-2402	83	10	)	)	PUNCT
eurjchem-2402	83	11	1039.65	1039.65	NUM
eurjchem-2402	83	12	temperature	temperature	NOUN
eurjchem-2402	83	13	(	(	PUNCT
eurjchem-2402	83	14	k	k	NOUN
eurjchem-2402	83	15	)	)	PUNCT
eurjchem-2402	83	16	293(2	293(2	NUM
eurjchem-2402	83	17	)	)	PUNCT
eurjchem-2402	83	18	crystal	crystal	NOUN
eurjchem-2402	83	19	system	system	NOUN
eurjchem-2402	83	20	triclinic	triclinic	ADJ
eurjchem-2402	83	21	space	space	NOUN
eurjchem-2402	83	22	group	group	NOUN
eurjchem-2402	83	23	p-1	p-1	NOUN
eurjchem-2402	83	24	a	a	PRON
eurjchem-2402	83	25	,	,	PUNCT
eurjchem-2402	83	26	(	(	PUNCT
eurjchem-2402	83	27	å	å	NOUN
eurjchem-2402	83	28	)	)	PUNCT
eurjchem-2402	83	29	9.240(3	9.240(3	NUM
eurjchem-2402	83	30	)	)	PUNCT
eurjchem-2402	83	31	b	b	NOUN
eurjchem-2402	83	32	,	,	PUNCT
eurjchem-2402	83	33	(	(	PUNCT
eurjchem-2402	83	34	å	å	NOUN
eurjchem-2402	83	35	)	)	PUNCT
eurjchem-2402	83	36	10.9290(18	10.9290(18	NUM
eurjchem-2402	83	37	)	)	PUNCT
eurjchem-2402	83	38	c	c	NOUN
eurjchem-2402	83	39	,	,	PUNCT
eurjchem-2402	83	40	(	(	PUNCT
eurjchem-2402	83	41	å	å	NOUN
eurjchem-2402	83	42	)	)	PUNCT
eurjchem-2402	83	43	11.993(3	11.993(3	ADJ
eurjchem-2402	83	44	)	)	PUNCT
eurjchem-2402	83	45	α	α	PROPN
eurjchem-2402	83	46	(	(	PUNCT
eurjchem-2402	83	47	°	°	NOUN
eurjchem-2402	83	48	)	)	PUNCT
eurjchem-2402	83	49	78.707(11	78.707(11	NUM
eurjchem-2402	83	50	)	)	PUNCT
eurjchem-2402	83	51	β	β	X
eurjchem-2402	83	52	(	(	PUNCT
eurjchem-2402	83	53	°	°	PROPN
eurjchem-2402	83	54	)	)	PUNCT
eurjchem-2402	83	55	86.712(13	86.712(13	NUM
eurjchem-2402	83	56	)	)	PUNCT
eurjchem-2402	83	57	γ	γ	X
eurjchem-2402	83	58	(	(	PUNCT
eurjchem-2402	83	59	°	°	PROPN
eurjchem-2402	83	60	)	)	PUNCT
eurjchem-2402	83	61	82.598(13	82.598(13	NUM
eurjchem-2402	83	62	)	)	PUNCT
eurjchem-2402	83	63	volume	volume	NOUN
eurjchem-2402	83	64	(	(	PUNCT
eurjchem-2402	83	65	å3	å3	PROPN
eurjchem-2402	83	66	)	)	PUNCT
eurjchem-2402	83	67	1177.1(5	1177.1(5	NUM
eurjchem-2402	83	68	)	)	PUNCT
eurjchem-2402	83	69	z	z	NOUN
eurjchem-2402	83	70	1	1	NUM
eurjchem-2402	83	71	ρcalc	ρcalc	NOUN
eurjchem-2402	83	72	(	(	PUNCT
eurjchem-2402	83	73	g	g	NOUN
eurjchem-2402	83	74	/	/	SYM
eurjchem-2402	83	75	cm3	cm3	NOUN
eurjchem-2402	83	76	)	)	PUNCT
eurjchem-2402	83	77	1.467	1.467	NUM
eurjchem-2402	83	78	μ	μ	NOUN
eurjchem-2402	83	79	(	(	PUNCT
eurjchem-2402	83	80	mm-1	mm-1	PROPN
eurjchem-2402	83	81	)	)	PUNCT
eurjchem-2402	83	82	0.732	0.732	NUM
eurjchem-2402	83	83	f(000	f(000	NOUN
eurjchem-2402	83	84	)	)	PUNCT
eurjchem-2402	83	85	532.0	532.0	NUM
eurjchem-2402	83	86	crystal	crystal	NOUN
eurjchem-2402	83	87	size	size	NOUN
eurjchem-2402	83	88	(	(	PUNCT
eurjchem-2402	83	89	mm3	mm3	PROPN
eurjchem-2402	83	90	)	)	PUNCT
eurjchem-2402	83	91	0.18	0.18	NUM
eurjchem-2402	83	92	×	×	NOUN
eurjchem-2402	83	93	0.08	0.08	NUM
eurjchem-2402	83	94	×	×	NOUN
eurjchem-2402	83	95	0.03	0.03	NUM
eurjchem-2402	83	96	radiation	radiation	NOUN
eurjchem-2402	83	97	mokα	mokα	NOUN
eurjchem-2402	83	98	(	(	PUNCT
eurjchem-2402	83	99	λ	λ	X
eurjchem-2402	83	100	=	=	SYM
eurjchem-2402	83	101	0.71073	0.71073	NUM
eurjchem-2402	83	102	)	)	PUNCT
eurjchem-2402	83	103	2θ	2θ	NUM
eurjchem-2402	83	104	range	range	VERB
eurjchem-2402	83	105	for	for	ADP
eurjchem-2402	83	106	data	data	NOUN
eurjchem-2402	83	107	collection	collection	NOUN
eurjchem-2402	83	108	(	(	PUNCT
eurjchem-2402	83	109	°	°	PROPN
eurjchem-2402	83	110	)	)	PUNCT
eurjchem-2402	83	111	6.934	6.934	NUM
eurjchem-2402	83	112	to	to	ADP
eurjchem-2402	83	113	51.986	51.986	NUM
eurjchem-2402	83	114	index	index	NOUN
eurjchem-2402	83	115	ranges	range	VERB
eurjchem-2402	83	116	-11	-11	PUNCT
eurjchem-2402	83	117	≤	≤	NUM
eurjchem-2402	83	118	h	h	NOUN
eurjchem-2402	83	119	≤	≤	NOUN
eurjchem-2402	83	120	11	11	NUM
eurjchem-2402	83	121	,	,	PUNCT
eurjchem-2402	83	122	-13	-13	PUNCT
eurjchem-2402	83	123	≤	≤	NUM
eurjchem-2402	84	1	k	k	X
eurjchem-2402	84	2	≤	≤	NUM
eurjchem-2402	84	3	13	13	NUM
eurjchem-2402	84	4	,	,	PUNCT
eurjchem-2402	84	5	-14	-14	PUNCT
eurjchem-2402	84	6	≤	≤	NUM
eurjchem-2402	84	7	l	l	NOUN
eurjchem-2402	84	8	≤	≤	NUM
eurjchem-2402	84	9	14	14	NUM
eurjchem-2402	84	10	reflections	reflection	NOUN
eurjchem-2402	84	11	collected	collect	VERB
eurjchem-2402	84	12	8434	8434	NUM
eurjchem-2402	84	13	independent	independent	ADJ
eurjchem-2402	84	14	reflections	reflection	NOUN
eurjchem-2402	84	15	4607	4607	NUM
eurjchem-2402	85	1	[	[	X
eurjchem-2402	85	2	rint	rint	X
eurjchem-2402	85	3	=	=	SYM
eurjchem-2402	85	4	0.0973	0.0973	NUM
eurjchem-2402	85	5	,	,	PUNCT
eurjchem-2402	85	6	rsigma	rsigma	ADJ
eurjchem-2402	85	7	=	=	SYM
eurjchem-2402	85	8	0.1171	0.1171	NUM
eurjchem-2402	85	9	]	]	X
eurjchem-2402	85	10	data	data	NOUN
eurjchem-2402	85	11	/	/	SYM
eurjchem-2402	85	12	restraints	restraint	NOUN
eurjchem-2402	85	13	/	/	SYM
eurjchem-2402	85	14	parameters	parameter	NOUN
eurjchem-2402	85	15	4607/0/277	4607/0/277	NUM
eurjchem-2402	85	16	goodness	goodness	NOUN
eurjchem-2402	85	17	-	-	PUNCT
eurjchem-2402	85	18	of	of	ADP
eurjchem-2402	85	19	-	-	PUNCT
eurjchem-2402	85	20	fit	fit	NOUN
eurjchem-2402	85	21	on	on	ADP
eurjchem-2402	85	22	f2	f2	PROPN
eurjchem-2402	85	23	0.956	0.956	NUM
eurjchem-2402	85	24	final	final	ADJ
eurjchem-2402	85	25	r	r	NOUN
eurjchem-2402	85	26	indexes	index	NOUN
eurjchem-2402	85	27	[	[	X
eurjchem-2402	85	28	i≥2σ	i≥2σ	X
eurjchem-2402	85	29	(	(	PUNCT
eurjchem-2402	85	30	i	i	NOUN
eurjchem-2402	85	31	)	)	PUNCT
eurjchem-2402	85	32	]	]	PUNCT
eurjchem-2402	86	1	r1	r1	PROPN
eurjchem-2402	86	2	=	=	SYM
eurjchem-2402	86	3	0.0537	0.0537	PROPN
eurjchem-2402	86	4	,	,	PUNCT
eurjchem-2402	86	5	wr2	wr2	PROPN
eurjchem-2402	86	6	=	=	PROPN
eurjchem-2402	86	7	0.1222	0.1222	NUM
eurjchem-2402	86	8	final	final	ADJ
eurjchem-2402	86	9	r	r	NOUN
eurjchem-2402	86	10	indexes	index	NOUN
eurjchem-2402	86	11	[	[	X
eurjchem-2402	86	12	all	all	DET
eurjchem-2402	86	13	data	datum	NOUN
eurjchem-2402	86	14	]	]	PUNCT
eurjchem-2402	86	15	r1	r1	PROPN
eurjchem-2402	86	16	=	=	PUNCT
eurjchem-2402	86	17	0.0795	0.0795	NUM
eurjchem-2402	86	18	,	,	PUNCT
eurjchem-2402	86	19	wr2	wr2	PROPN
eurjchem-2402	86	20	=	=	SYM
eurjchem-2402	86	21	0.1347	0.1347	NUM
eurjchem-2402	86	22	largest	large	ADJ
eurjchem-2402	86	23	diff	diff	NOUN
eurjchem-2402	86	24	.	.	PUNCT
eurjchem-2402	86	25	peak	peak	PROPN
eurjchem-2402	86	26	/	/	SYM
eurjchem-2402	86	27	hole	hole	NOUN
eurjchem-2402	86	28	(	(	PUNCT
eurjchem-2402	86	29	e.å-3	e.å-3	PROPN
eurjchem-2402	86	30	)	)	PUNCT
eurjchem-2402	86	31	0.73/-0.95	0.73/-0.95	NOUN
eurjchem-2402	86	32	cis-[rucl2(dppe)2	cis-[rucl2(dppe)2	PROPN
eurjchem-2402	86	33	]	]	PUNCT
eurjchem-2402	86	34	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	ADP
eurjchem-2402	86	35	]	]	PUNCT
eurjchem-2402	86	36	figure	figure	NOUN
eurjchem-2402	86	37	1	1	NUM
eurjchem-2402	86	38	.	.	PUNCT
eurjchem-2402	87	1	cisand	cisand	ADP
eurjchem-2402	87	2	trans	tran	NOUN
eurjchem-2402	87	3	-	-	NOUN
eurjchem-2402	87	4	isomers	isomer	NOUN
eurjchem-2402	87	5	of	of	ADP
eurjchem-2402	87	6	complex	complex	ADJ
eurjchem-2402	88	1	[	[	X
eurjchem-2402	88	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	88	3	]	]	X
eurjchem-2402	88	4	.	.	PUNCT
eurjchem-2402	89	1	figure	figure	NOUN
eurjchem-2402	89	2	2	2	NUM
eurjchem-2402	89	3	.	.	PUNCT
eurjchem-2402	90	1	absorption	absorption	NOUN
eurjchem-2402	90	2	spectrum	spectrum	NOUN
eurjchem-2402	90	3	in	in	ADP
eurjchem-2402	90	4	the	the	DET
eurjchem-2402	90	5	uv	uv	NOUN
eurjchem-2402	90	6	-	-	PUNCT
eurjchem-2402	90	7	vis	vis	X
eurjchem-2402	90	8	region	region	NOUN
eurjchem-2402	90	9	of	of	ADP
eurjchem-2402	90	10	the	the	DET
eurjchem-2402	90	11	complex	complex	NOUN
eurjchem-2402	91	1	[	[	X
eurjchem-2402	91	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	91	3	]	]	X
eurjchem-2402	91	4	(	(	PUNCT
eurjchem-2402	91	5	isomers	isomer	NOUN
eurjchem-2402	91	6	cis	cis	NOUN
eurjchem-2402	91	7	/	/	SYM
eurjchem-2402	91	8	trans	tran	NOUN
eurjchem-2402	91	9	)	)	PUNCT
eurjchem-2402	91	10	,	,	PUNCT
eurjchem-2402	91	11	in	in	ADP
eurjchem-2402	91	12	the	the	DET
eurjchem-2402	91	13	concentration	concentration	NOUN
eurjchem-2402	91	14	1.5×10	1.5×10	NOUN
eurjchem-2402	91	15	-	-	SYM
eurjchem-2402	91	16	3	3	NUM
eurjchem-2402	91	17	mol	mol	NOUN
eurjchem-2402	91	18	/	/	SYM
eurjchem-2402	91	19	l	l	NOUN
eurjchem-2402	91	20	,	,	PUNCT
eurjchem-2402	91	21	in	in	ADP
eurjchem-2402	91	22	the	the	DET
eurjchem-2402	91	23	presence	presence	NOUN
eurjchem-2402	91	24	of	of	ADP
eurjchem-2402	91	25	successive	successive	ADJ
eurjchem-2402	91	26	additions	addition	NOUN
eurjchem-2402	91	27	of	of	ADP
eurjchem-2402	91	28	rates	rate	NOUN
eurjchem-2402	91	29	of	of	ADP
eurjchem-2402	91	30	ct	ct	PROPN
eurjchem-2402	91	31	-	-	PUNCT
eurjchem-2402	91	32	dna	dna	PROPN
eurjchem-2402	91	33	(	(	PUNCT
eurjchem-2402	91	34	2.05×10	2.05×10	NUM
eurjchem-2402	91	35	-	-	SYM
eurjchem-2402	91	36	3	3	NUM
eurjchem-2402	91	37	mol	mol	PROPN
eurjchem-2402	91	38	/	/	SYM
eurjchem-2402	91	39	l	l	NOUN
eurjchem-2402	91	40	)	)	PUNCT
eurjchem-2402	91	41	,	,	PUNCT
eurjchem-2402	91	42	in	in	ADP
eurjchem-2402	91	43	buffer	buffer	NOUN
eurjchem-2402	91	44	tris	tris	NOUN
eurjchem-2402	91	45	-	-	PUNCT
eurjchem-2402	91	46	hcl	hcl	NOUN
eurjchem-2402	91	47	(	(	PUNCT
eurjchem-2402	91	48	ph	ph	NOUN
eurjchem-2402	91	49	=	=	NOUN
eurjchem-2402	91	50	7.4	7.4	NUM
eurjchem-2402	91	51	)	)	PUNCT
eurjchem-2402	91	52	and	and	CCONJ
eurjchem-2402	91	53	10	10	NUM
eurjchem-2402	91	54	%	%	NOUN
eurjchem-2402	91	55	of	of	ADP
eurjchem-2402	91	56	dmso	dmso	NOUN
eurjchem-2402	91	57	.	.	PUNCT
eurjchem-2402	92	1	the	the	DET
eurjchem-2402	92	2	hydrogen	hydrogen	NOUN
eurjchem-2402	92	3	of	of	ADP
eurjchem-2402	92	4	methylene	methylene	NOUN
eurjchem-2402	92	5	groups	group	NOUN
eurjchem-2402	92	6	of	of	ADP
eurjchem-2402	92	7	dppe	dppe	PROPN
eurjchem-2402	92	8	was	be	AUX
eurjchem-2402	92	9	also	also	ADV
eurjchem-2402	92	10	set	set	VERB
eurjchem-2402	92	11	as	as	ADP
eurjchem-2402	92	12	isotropic	isotropic	NOUN
eurjchem-2402	92	13	with	with	ADP
eurjchem-2402	92	14	a	a	DET
eurjchem-2402	92	15	thermal	thermal	ADJ
eurjchem-2402	92	16	parameter	parameter	NOUN
eurjchem-2402	92	17	20	20	NUM
eurjchem-2402	92	18	%	%	NOUN
eurjchem-2402	92	19	greater	great	ADJ
eurjchem-2402	92	20	than	than	ADP
eurjchem-2402	92	21	the	the	DET
eurjchem-2402	92	22	equivalent	equivalent	ADJ
eurjchem-2402	92	23	isotropic	isotropic	ADJ
eurjchem-2402	92	24	displacement	displacement	ADJ
eurjchem-2402	92	25	parameter	parameter	NOUN
eurjchem-2402	92	26	of	of	ADP
eurjchem-2402	92	27	the	the	DET
eurjchem-2402	92	28	atom	atom	NOUN
eurjchem-2402	92	29	to	to	PART
eurjchem-2402	92	30	which	which	PRON
eurjchem-2402	92	31	each	each	DET
eurjchem-2402	92	32	one	one	NOUN
eurjchem-2402	92	33	was	be	AUX
eurjchem-2402	92	34	bonded	bond	VERB
eurjchem-2402	92	35	,	,	PUNCT
eurjchem-2402	92	36	and	and	CCONJ
eurjchem-2402	92	37	c	c	X
eurjchem-2402	92	38	-	-	PUNCT
eurjchem-2402	92	39	h	h	NOUN
eurjchem-2402	92	40	bond	bond	NOUN
eurjchem-2402	92	41	lengths	length	NOUN
eurjchem-2402	92	42	were	be	AUX
eurjchem-2402	92	43	fixed	fix	VERB
eurjchem-2402	92	44	at	at	ADP
eurjchem-2402	92	45	0.97	0.97	NUM
eurjchem-2402	92	46	å	å	NOUN
eurjchem-2402	92	47	.	.	PUNCT
eurjchem-2402	93	1	for	for	ADP
eurjchem-2402	93	2	structure	structure	NOUN
eurjchem-2402	93	3	representation	representation	NOUN
eurjchem-2402	93	4	,	,	PUNCT
eurjchem-2402	93	5	the	the	DET
eurjchem-2402	93	6	mercury	mercury	NOUN
eurjchem-2402	93	7	4.0	4.0	NUM
eurjchem-2402	93	8	programme	programme	NOUN
eurjchem-2402	93	9	was	be	AUX
eurjchem-2402	93	10	used	use	VERB
eurjchem-2402	93	11	[	[	PUNCT
eurjchem-2402	93	12	25	25	NUM
eurjchem-2402	93	13	]	]	PUNCT
eurjchem-2402	93	14	.	.	PUNCT
eurjchem-2402	94	1	3	3	X
eurjchem-2402	94	2	.	.	NOUN
eurjchem-2402	94	3	results	result	NOUN
eurjchem-2402	94	4	and	and	CCONJ
eurjchem-2402	94	5	discussion	discussion	VERB
eurjchem-2402	94	6	the	the	DET
eurjchem-2402	94	7	mixture	mixture	NOUN
eurjchem-2402	94	8	of	of	ADP
eurjchem-2402	94	9	transand	transand	NOUN
eurjchem-2402	94	10	cis-[rucl2(dppe)2	cis-[rucl2(dppe)2	PROPN
eurjchem-2402	94	11	]	]	PUNCT
eurjchem-2402	94	12	complexes	complex	NOUN
eurjchem-2402	94	13	was	be	AUX
eurjchem-2402	94	14	obtained	obtain	VERB
eurjchem-2402	94	15	from	from	ADP
eurjchem-2402	94	16	the	the	DET
eurjchem-2402	94	17	precursor	precursor	NOUN
eurjchem-2402	94	18	cis-[rucl2(dmso)4	cis-[rucl2(dmso)4	PROPN
eurjchem-2402	94	19	]	]	PUNCT
eurjchem-2402	94	20	by	by	ADP
eurjchem-2402	94	21	replacing	replace	VERB
eurjchem-2402	94	22	the	the	DET
eurjchem-2402	94	23	four	four	NUM
eurjchem-2402	94	24	dmso	dmso	NOUN
eurjchem-2402	94	25	ligands	ligand	NOUN
eurjchem-2402	94	26	with	with	ADP
eurjchem-2402	94	27	two	two	NUM
eurjchem-2402	94	28	diphosphine	diphosphine	ADJ
eurjchem-2402	94	29	dppe	dppe	NOUN
eurjchem-2402	94	30	(	(	PUNCT
eurjchem-2402	94	31	1,2	1,2	NUM
eurjchem-2402	94	32	-	-	PUNCT
eurjchem-2402	94	33	bis(diphenylphosphino)ethane	bis(diphenylphosphino)ethane	NUM
eurjchem-2402	94	34	)	)	PUNCT
eurjchem-2402	94	35	ligands	ligand	NOUN
eurjchem-2402	94	36	,	,	PUNCT
eurjchem-2402	94	37	as	as	SCONJ
eurjchem-2402	94	38	shown	show	VERB
eurjchem-2402	94	39	in	in	ADP
eurjchem-2402	94	40	figure	figure	NOUN
eurjchem-2402	94	41	1	1	NUM
eurjchem-2402	94	42	.	.	PUNCT
eurjchem-2402	95	1	the	the	DET
eurjchem-2402	95	2	mixture	mixture	NOUN
eurjchem-2402	95	3	of	of	ADP
eurjchem-2402	95	4	isomers	isomer	NOUN
eurjchem-2402	95	5	was	be	AUX
eurjchem-2402	95	6	confirmed	confirm	VERB
eurjchem-2402	95	7	by	by	ADP
eurjchem-2402	95	8	31p{1h	31p{1h	NUM
eurjchem-2402	95	9	}	}	PUNCT
eurjchem-2402	95	10	nmr	nmr	NOUN
eurjchem-2402	95	11	,	,	PUNCT
eurjchem-2402	95	12	in	in	ADP
eurjchem-2402	95	13	which	which	PRON
eurjchem-2402	95	14	one	one	NUM
eurjchem-2402	95	15	singlet	singlet	NOUN
eurjchem-2402	95	16	at	at	ADP
eurjchem-2402	95	17	δ	δ	PROPN
eurjchem-2402	95	18	44	44	NUM
eurjchem-2402	95	19	ppm	ppm	NOUN
eurjchem-2402	95	20	is	be	AUX
eurjchem-2402	95	21	related	relate	VERB
eurjchem-2402	95	22	to	to	PART
eurjchem-2402	95	23	isomer	isomer	VERB
eurjchem-2402	95	24	trans	tran	NOUN
eurjchem-2402	95	25	and	and	CCONJ
eurjchem-2402	95	26	two	two	NUM
eurjchem-2402	95	27	triplets	triplet	NOUN
eurjchem-2402	95	28	at	at	ADP
eurjchem-2402	95	29	δ	δ	PROPN
eurjchem-2402	95	30	50.29	50.29	NUM
eurjchem-2402	95	31	and	and	CCONJ
eurjchem-2402	95	32	37.35	37.35	NUM
eurjchem-2402	95	33	ppm	ppm	NOUN
eurjchem-2402	95	34	(	(	PUNCT
eurjchem-2402	95	35	2jp	2jp	NOUN
eurjchem-2402	95	36	-	-	PUNCT
eurjchem-2402	95	37	p	p	NOUN
eurjchem-2402	95	38	=	=	NOUN
eurjchem-2402	95	39	19.6	19.6	NUM
eurjchem-2402	95	40	hz	hz	NOUN
eurjchem-2402	95	41	)	)	PUNCT
eurjchem-2402	95	42	belong	belong	VERB
eurjchem-2402	95	43	to	to	ADP
eurjchem-2402	95	44	isomer	isomer	PROPN
eurjchem-2402	95	45	cis	cis	NOUN
eurjchem-2402	95	46	.	.	PUNCT
eurjchem-2402	96	1	3.1	3.1	NUM
eurjchem-2402	96	2	.	.	PUNCT
eurjchem-2402	97	1	uv	uv	NOUN
eurjchem-2402	97	2	-	-	PUNCT
eurjchem-2402	97	3	vis	vis	X
eurjchem-2402	97	4	dna	dna	PROPN
eurjchem-2402	97	5	spectroscopic	spectroscopic	NOUN
eurjchem-2402	97	6	titration	titration	NOUN
eurjchem-2402	97	7	and	and	CCONJ
eurjchem-2402	97	8	viscosity	viscosity	NOUN
eurjchem-2402	97	9	first	first	ADV
eurjchem-2402	97	10	,	,	PUNCT
eurjchem-2402	97	11	spectrophotometric	spectrophotometric	ADJ
eurjchem-2402	97	12	titrations	titration	NOUN
eurjchem-2402	97	13	were	be	AUX
eurjchem-2402	97	14	performed	perform	VERB
eurjchem-2402	97	15	to	to	PART
eurjchem-2402	97	16	evaluate	evaluate	VERB
eurjchem-2402	97	17	the	the	DET
eurjchem-2402	97	18	interaction	interaction	NOUN
eurjchem-2402	97	19	of	of	ADP
eurjchem-2402	97	20	the	the	DET
eurjchem-2402	97	21	[	[	X
eurjchem-2402	97	22	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	97	23	]	]	X
eurjchem-2402	97	24	complex	complex	NOUN
eurjchem-2402	97	25	with	with	ADP
eurjchem-2402	97	26	ctdna	ctdna	NOUN
eurjchem-2402	97	27	.	.	PUNCT
eurjchem-2402	98	1	this	this	DET
eurjchem-2402	98	2	technique	technique	NOUN
eurjchem-2402	98	3	is	be	AUX
eurjchem-2402	98	4	widely	widely	ADV
eurjchem-2402	98	5	used	use	VERB
eurjchem-2402	98	6	to	to	PART
eurjchem-2402	98	7	determine	determine	VERB
eurjchem-2402	98	8	the	the	DET
eurjchem-2402	98	9	complexdna	complexdna	ADJ
eurjchem-2402	98	10	affinity	affinity	NOUN
eurjchem-2402	98	11	,	,	PUNCT
eurjchem-2402	98	12	in	in	ADP
eurjchem-2402	98	13	which	which	PRON
eurjchem-2402	98	14	the	the	DET
eurjchem-2402	98	15	binding	bind	VERB
eurjchem-2402	98	16	constant	constant	ADJ
eurjchem-2402	98	17	values	value	NOUN
eurjchem-2402	98	18	(	(	PUNCT
eurjchem-2402	98	19	kb	kb	PROPN
eurjchem-2402	98	20	)	)	PUNCT
eurjchem-2402	98	21	can	can	AUX
eurjchem-2402	98	22	indicate	indicate	VERB
eurjchem-2402	98	23	a	a	DET
eurjchem-2402	98	24	high	high	ADJ
eurjchem-2402	98	25	,	,	PUNCT
eurjchem-2402	98	26	moderate	moderate	ADJ
eurjchem-2402	98	27	or	or	CCONJ
eurjchem-2402	98	28	weak	weak	ADJ
eurjchem-2402	98	29	interaction	interaction	NOUN
eurjchem-2402	99	1	[	[	X
eurjchem-2402	99	2	26	26	NUM
eurjchem-2402	99	3	]	]	PUNCT
eurjchem-2402	99	4	.	.	PUNCT
eurjchem-2402	100	1	the	the	DET
eurjchem-2402	100	2	uv	uv	NOUN
eurjchem-2402	100	3	-	-	PUNCT
eurjchem-2402	100	4	vis	vis	X
eurjchem-2402	100	5	spectrum	spectrum	NOUN
eurjchem-2402	100	6	for	for	ADP
eurjchem-2402	100	7	the	the	DET
eurjchem-2402	100	8	[	[	X
eurjchem-2402	100	9	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	100	10	]	]	X
eurjchem-2402	100	11	complex	complex	NOUN
eurjchem-2402	100	12	was	be	AUX
eurjchem-2402	100	13	investigated	investigate	VERB
eurjchem-2402	100	14	in	in	ADP
eurjchem-2402	100	15	the	the	DET
eurjchem-2402	100	16	region	region	NOUN
eurjchem-2402	100	17	between	between	ADP
eurjchem-2402	100	18	200	200	NUM
eurjchem-2402	100	19	and	and	CCONJ
eurjchem-2402	100	20	600	600	NUM
eurjchem-2402	100	21	nm	nm	NOUN
eurjchem-2402	100	22	.	.	PUNCT
eurjchem-2402	101	1	in	in	ADP
eurjchem-2402	101	2	figure	figure	NOUN
eurjchem-2402	101	3	2	2	NUM
eurjchem-2402	101	4	,	,	PUNCT
eurjchem-2402	101	5	it	it	PRON
eurjchem-2402	101	6	is	be	AUX
eurjchem-2402	101	7	possible	possible	ADJ
eurjchem-2402	101	8	to	to	PART
eurjchem-2402	101	9	observe	observe	VERB
eurjchem-2402	101	10	that	that	SCONJ
eurjchem-2402	101	11	the	the	DET
eurjchem-2402	101	12	spectra	spectra	NOUN
eurjchem-2402	101	13	of	of	ADP
eurjchem-2402	101	14	the	the	DET
eurjchem-2402	101	15	mixture	mixture	NOUN
eurjchem-2402	101	16	of	of	ADP
eurjchem-2402	101	17	cisand	cisand	NOUN
eurjchem-2402	101	18	trans[rucl2(dppe)2	trans[rucl2(dppe)2	X
eurjchem-2402	101	19	]	]	X
eurjchem-2402	101	20	complex	complex	ADJ
eurjchem-2402	101	21	decrease	decrease	NOUN
eurjchem-2402	101	22	with	with	ADP
eurjchem-2402	101	23	ct	ct	PROPN
eurjchem-2402	101	24	-	-	PUNCT
eurjchem-2402	101	25	dna	dna	PROPN
eurjchem-2402	101	26	addition	addition	NOUN
eurjchem-2402	101	27	,	,	PUNCT
eurjchem-2402	101	28	resulting	result	VERB
eurjchem-2402	101	29	in	in	ADP
eurjchem-2402	101	30	a	a	DET
eurjchem-2402	101	31	hypochromism	hypochromism	NOUN
eurjchem-2402	101	32	.	.	PUNCT
eurjchem-2402	102	1	196	196	NUM
eurjchem-2402	102	2	campideli	campideli	NOUN
eurjchem-2402	102	3	et	et	PROPN
eurjchem-2402	102	4	al	al	PROPN
eurjchem-2402	102	5	.	.	PUNCT
eurjchem-2402	102	6	/	/	SYM
eurjchem-2402	102	7	european	european	PROPN
eurjchem-2402	102	8	journal	journal	PROPN
eurjchem-2402	102	9	of	of	ADP
eurjchem-2402	102	10	chemistry	chemistry	NOUN
eurjchem-2402	102	11	14	14	NUM
eurjchem-2402	102	12	(	(	PUNCT
eurjchem-2402	102	13	2	2	NUM
eurjchem-2402	102	14	)	)	PUNCT
eurjchem-2402	102	15	(	(	PUNCT
eurjchem-2402	102	16	2023	2023	NUM
eurjchem-2402	102	17	)	)	PUNCT
eurjchem-2402	102	18	193	193	NUM
eurjchem-2402	102	19	-	-	SYM
eurjchem-2402	102	20	201	201	NUM
eurjchem-2402	102	21	2023	2023	NUM
eurjchem-2402	102	22	–	–	PUNCT
eurjchem-2402	102	23	european	european	ADJ
eurjchem-2402	102	24	journal	journal	NOUN
eurjchem-2402	102	25	of	of	ADP
eurjchem-2402	102	26	chemistry	chemistry	NOUN
eurjchem-2402	102	27	–	–	PUNCT
eurjchem-2402	102	28	cc	cc	NOUN
eurjchem-2402	102	29	by	by	ADP
eurjchem-2402	102	30	nc	nc	PROPN
eurjchem-2402	102	31	–	–	PUNCT
eurjchem-2402	102	32	doi	doi	NOUN
eurjchem-2402	102	33	:	:	PUNCT
eurjchem-2402	102	34	10.5155	10.5155	NUM
eurjchem-2402	102	35	/	/	SYM
eurjchem-2402	102	36	eurjchem.14.2.193	eurjchem.14.2.193	NUM
eurjchem-2402	102	37	-	-	SYM
eurjchem-2402	102	38	201.2402	201.2402	NUM
eurjchem-2402	102	39	figure	figure	NOUN
eurjchem-2402	102	40	3	3	NUM
eurjchem-2402	102	41	.	.	NOUN
eurjchem-2402	102	42	relative	relative	ADJ
eurjchem-2402	102	43	viscosity	viscosity	NOUN
eurjchem-2402	102	44	vs	vs	ADP
eurjchem-2402	102	45	[	[	X
eurjchem-2402	102	46	dna]/[complex	dna]/[complex	X
eurjchem-2402	102	47	]	]	X
eurjchem-2402	102	48	,	,	PUNCT
eurjchem-2402	102	49	of	of	ADP
eurjchem-2402	102	50	thiazole	thiazole	NOUN
eurjchem-2402	102	51	orange	orange	NOUN
eurjchem-2402	102	52	and	and	CCONJ
eurjchem-2402	102	53	the	the	DET
eurjchem-2402	102	54	complex	complex	NOUN
eurjchem-2402	103	1	[	[	X
eurjchem-2402	103	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	103	3	]	]	X
eurjchem-2402	103	4	at	at	ADP
eurjchem-2402	103	5	a	a	DET
eurjchem-2402	103	6	concentration	concentration	NOUN
eurjchem-2402	103	7	1.5×10	1.5×10	NOUN
eurjchem-2402	103	8	-	-	SYM
eurjchem-2402	103	9	3	3	NUM
eurjchem-2402	103	10	mol	mol	NOUN
eurjchem-2402	103	11	/	/	SYM
eurjchem-2402	103	12	l	l	NOUN
eurjchem-2402	103	13	,	,	PUNCT
eurjchem-2402	103	14	in	in	ADP
eurjchem-2402	103	15	the	the	DET
eurjchem-2402	103	16	presence	presence	NOUN
eurjchem-2402	103	17	of	of	ADP
eurjchem-2402	103	18	successive	successive	ADJ
eurjchem-2402	103	19	additions	addition	NOUN
eurjchem-2402	103	20	of	of	ADP
eurjchem-2402	103	21	ct	ct	PROPN
eurjchem-2402	103	22	-	-	PUNCT
eurjchem-2402	103	23	dna	dna	PROPN
eurjchem-2402	103	24	ratios	ratio	NOUN
eurjchem-2402	103	25	(	(	PUNCT
eurjchem-2402	103	26	3.66×10	3.66×10	NUM
eurjchem-2402	103	27	-	-	SYM
eurjchem-2402	103	28	3	3	NUM
eurjchem-2402	103	29	mol	mol	NOUN
eurjchem-2402	103	30	/	/	SYM
eurjchem-2402	103	31	l	l	NOUN
eurjchem-2402	103	32	)	)	PUNCT
eurjchem-2402	103	33	,	,	PUNCT
eurjchem-2402	103	34	in	in	ADP
eurjchem-2402	103	35	tris	tris	ADJ
eurjchem-2402	103	36	-	-	PUNCT
eurjchem-2402	103	37	hcl	hcl	NOUN
eurjchem-2402	103	38	buffer	buffer	NOUN
eurjchem-2402	103	39	(	(	PUNCT
eurjchem-2402	103	40	ph	ph	NOUN
eurjchem-2402	103	41	=	=	NOUN
eurjchem-2402	103	42	7.4	7.4	NUM
eurjchem-2402	103	43	)	)	PUNCT
eurjchem-2402	103	44	and	and	CCONJ
eurjchem-2402	103	45	dmso	dmso	NOUN
eurjchem-2402	103	46	.	.	PUNCT
eurjchem-2402	103	47	figure	figure	NOUN
eurjchem-2402	103	48	4	4	NUM
eurjchem-2402	103	49	.	.	PUNCT
eurjchem-2402	103	50	cyclic	cyclic	ADJ
eurjchem-2402	103	51	voltammogram	voltammogram	NOUN
eurjchem-2402	103	52	of	of	ADP
eurjchem-2402	103	53	the	the	DET
eurjchem-2402	103	54	complex	complex	NOUN
eurjchem-2402	103	55	[	[	X
eurjchem-2402	103	56	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	103	57	]	]	X
eurjchem-2402	103	58	(	(	PUNCT
eurjchem-2402	103	59	isomer	isomer	ADJ
eurjchem-2402	103	60	cis	cis	NOUN
eurjchem-2402	103	61	e	e	X
eurjchem-2402	103	62	trans	trans	PROPN
eurjchem-2402	103	63	)	)	PUNCT
eurjchem-2402	103	64	,	,	PUNCT
eurjchem-2402	103	65	in	in	ADP
eurjchem-2402	103	66	concentration	concentration	NOUN
eurjchem-2402	103	67	2×10	2×10	NUM
eurjchem-2402	103	68	-	-	SYM
eurjchem-2402	103	69	4	4	NUM
eurjchem-2402	103	70	mol	mol	NOUN
eurjchem-2402	103	71	/	/	SYM
eurjchem-2402	103	72	l	l	NOUN
eurjchem-2402	103	73	in	in	ADP
eurjchem-2402	103	74	0.1	0.1	NUM
eurjchem-2402	103	75	mol	mol	ADP
eurjchem-2402	103	76	/	/	SYM
eurjchem-2402	103	77	l	l	NOUN
eurjchem-2402	103	78	ptba	ptba	NOUN
eurjchem-2402	103	79	,	,	PUNCT
eurjchem-2402	103	80	in	in	ADP
eurjchem-2402	103	81	ch2cl2	ch2cl2	NOUN
eurjchem-2402	103	82	.	.	PUNCT
eurjchem-2402	103	83	scan	scan	ADJ
eurjchem-2402	103	84	rate	rate	NOUN
eurjchem-2402	103	85	=	=	PROPN
eurjchem-2402	103	86	50	50	NUM
eurjchem-2402	103	87	mv	mv	NOUN
eurjchem-2402	103	88	/	/	SYM
eurjchem-2402	103	89	s.	s.	PROPN
eurjchem-2402	103	90	the	the	DET
eurjchem-2402	103	91	initial	initial	ADJ
eurjchem-2402	103	92	spectrum	spectrum	NOUN
eurjchem-2402	103	93	(	(	PUNCT
eurjchem-2402	103	94	black	black	NOUN
eurjchem-2402	103	95	)	)	PUNCT
eurjchem-2402	103	96	corresponds	correspond	VERB
eurjchem-2402	103	97	to	to	ADP
eurjchem-2402	103	98	the	the	DET
eurjchem-2402	103	99	free	free	ADJ
eurjchem-2402	103	100	complex	complex	NOUN
eurjchem-2402	103	101	(	(	PUNCT
eurjchem-2402	103	102	in	in	ADP
eurjchem-2402	103	103	the	the	DET
eurjchem-2402	103	104	absence	absence	NOUN
eurjchem-2402	103	105	of	of	ADP
eurjchem-2402	103	106	dna	dna	PROPN
eurjchem-2402	103	107	)	)	PUNCT
eurjchem-2402	103	108	,	,	PUNCT
eurjchem-2402	103	109	while	while	SCONJ
eurjchem-2402	103	110	the	the	DET
eurjchem-2402	103	111	other	other	ADJ
eurjchem-2402	103	112	data	datum	NOUN
eurjchem-2402	103	113	were	be	AUX
eurjchem-2402	103	114	obtained	obtain	VERB
eurjchem-2402	103	115	after	after	ADP
eurjchem-2402	103	116	successive	successive	ADJ
eurjchem-2402	103	117	additions	addition	NOUN
eurjchem-2402	103	118	of	of	ADP
eurjchem-2402	103	119	10	10	NUM
eurjchem-2402	103	120	µl	µl	NOUN
eurjchem-2402	103	121	of	of	ADP
eurjchem-2402	103	122	ct	ct	PROPN
eurjchem-2402	103	123	-	-	PUNCT
eurjchem-2402	103	124	dna	dna	NOUN
eurjchem-2402	103	125	to	to	ADP
eurjchem-2402	103	126	the	the	DET
eurjchem-2402	103	127	complex	complex	ADJ
eurjchem-2402	103	128	solution	solution	NOUN
eurjchem-2402	103	129	.	.	PUNCT
eurjchem-2402	104	1	the	the	DET
eurjchem-2402	104	2	kb	kb	PROPN
eurjchem-2402	104	3	value	value	NOUN
eurjchem-2402	104	4	was	be	AUX
eurjchem-2402	104	5	calculated	calculate	VERB
eurjchem-2402	104	6	from	from	ADP
eurjchem-2402	104	7	the	the	DET
eurjchem-2402	104	8	absorption	absorption	NOUN
eurjchem-2402	104	9	band	band	NOUN
eurjchem-2402	104	10	(	(	PUNCT
eurjchem-2402	104	11	λmax	λmax	NOUN
eurjchem-2402	104	12	)	)	PUNCT
eurjchem-2402	104	13	at	at	ADP
eurjchem-2402	104	14	about	about	ADV
eurjchem-2402	104	15	250	250	NUM
eurjchem-2402	104	16	nm	nm	NOUN
eurjchem-2402	104	17	to	to	ADP
eurjchem-2402	104	18	the	the	DET
eurjchem-2402	104	19	complex	complex	NOUN
eurjchem-2402	104	20	,	,	PUNCT
eurjchem-2402	104	21	and	and	CCONJ
eurjchem-2402	104	22	the	the	DET
eurjchem-2402	104	23	kb	kb	PROPN
eurjchem-2402	104	24	value	value	NOUN
eurjchem-2402	104	25	is	be	AUX
eurjchem-2402	104	26	3.9×104	3.9×104	PROPN
eurjchem-2402	104	27	m-1	m-1	NUM
eurjchem-2402	104	28	,	,	PUNCT
eurjchem-2402	104	29	revealing	reveal	VERB
eurjchem-2402	104	30	a	a	DET
eurjchem-2402	104	31	moderate	moderate	ADJ
eurjchem-2402	104	32	interaction	interaction	NOUN
eurjchem-2402	104	33	compared	compare	VERB
eurjchem-2402	104	34	with	with	ADP
eurjchem-2402	104	35	other	other	ADJ
eurjchem-2402	104	36	metal	metal	NOUN
eurjchem-2402	104	37	complexes	complex	NOUN
eurjchem-2402	104	38	reported	report	VERB
eurjchem-2402	104	39	in	in	ADP
eurjchem-2402	104	40	the	the	DET
eurjchem-2402	104	41	literature	literature	NOUN
eurjchem-2402	105	1	[	[	X
eurjchem-2402	105	2	27,28	27,28	NUM
eurjchem-2402	105	3	]	]	X
eurjchem-2402	105	4	.	.	PUNCT
eurjchem-2402	106	1	in	in	ADP
eurjchem-2402	106	2	addition	addition	NOUN
eurjchem-2402	106	3	,	,	PUNCT
eurjchem-2402	106	4	to	to	PART
eurjchem-2402	106	5	better	well	ADV
eurjchem-2402	106	6	understand	understand	VERB
eurjchem-2402	106	7	the	the	DET
eurjchem-2402	106	8	interaction	interaction	NOUN
eurjchem-2402	106	9	between	between	ADP
eurjchem-2402	106	10	the	the	DET
eurjchem-2402	106	11	ruthenium	ruthenium	NOUN
eurjchem-2402	106	12	complex	complex	NOUN
eurjchem-2402	106	13	and	and	CCONJ
eurjchem-2402	106	14	ct	ct	PROPN
eurjchem-2402	106	15	-	-	PUNCT
eurjchem-2402	106	16	dna	dna	PROPN
eurjchem-2402	106	17	,	,	PUNCT
eurjchem-2402	106	18	viscosity	viscosity	NOUN
eurjchem-2402	106	19	measurements	measurement	NOUN
eurjchem-2402	106	20	were	be	AUX
eurjchem-2402	106	21	performed	perform	VERB
eurjchem-2402	106	22	.	.	PUNCT
eurjchem-2402	107	1	intercalation	intercalation	NOUN
eurjchem-2402	107	2	and	and	CCONJ
eurjchem-2402	107	3	groove	groove	NOUN
eurjchem-2402	107	4	-	-	PUNCT
eurjchem-2402	107	5	binding	bind	VERB
eurjchem-2402	107	6	interactions	interaction	NOUN
eurjchem-2402	107	7	have	have	AUX
eurjchem-2402	107	8	been	be	AUX
eurjchem-2402	107	9	reported	report	VERB
eurjchem-2402	107	10	to	to	PART
eurjchem-2402	107	11	contribute	contribute	VERB
eurjchem-2402	107	12	to	to	ADP
eurjchem-2402	107	13	an	an	DET
eurjchem-2402	107	14	increase	increase	NOUN
eurjchem-2402	107	15	in	in	ADP
eurjchem-2402	107	16	viscosity	viscosity	NOUN
eurjchem-2402	107	17	,	,	PUNCT
eurjchem-2402	107	18	whereas	whereas	SCONJ
eurjchem-2402	107	19	covalent	covalent	ADJ
eurjchem-2402	107	20	binding	binding	NOUN
eurjchem-2402	107	21	can	can	AUX
eurjchem-2402	107	22	cause	cause	VERB
eurjchem-2402	107	23	a	a	DET
eurjchem-2402	107	24	decrease	decrease	NOUN
eurjchem-2402	107	25	in	in	ADP
eurjchem-2402	107	26	the	the	DET
eurjchem-2402	107	27	relative	relative	ADJ
eurjchem-2402	107	28	viscosity	viscosity	NOUN
eurjchem-2402	107	29	of	of	ADP
eurjchem-2402	107	30	ct	ct	PROPN
eurjchem-2402	107	31	-	-	NOUN
eurjchem-2402	107	32	dna	dna	NOUN
eurjchem-2402	107	33	[	[	X
eurjchem-2402	107	34	29	29	NUM
eurjchem-2402	107	35	]	]	PUNCT
eurjchem-2402	107	36	.	.	PUNCT
eurjchem-2402	108	1	when	when	SCONJ
eurjchem-2402	108	2	the	the	DET
eurjchem-2402	108	3	concentration	concentration	NOUN
eurjchem-2402	108	4	of	of	ADP
eurjchem-2402	108	5	the	the	DET
eurjchem-2402	108	6	ruthenium	ruthenium	NOUN
eurjchem-2402	108	7	complex	complex	ADJ
eurjchem-2402	108	8	increases	increase	NOUN
eurjchem-2402	108	9	,	,	PUNCT
eurjchem-2402	108	10	the	the	DET
eurjchem-2402	108	11	relative	relative	ADJ
eurjchem-2402	108	12	viscosity	viscosity	NOUN
eurjchem-2402	108	13	of	of	ADP
eurjchem-2402	108	14	ct	ct	PROPN
eurjchem-2402	108	15	-	-	PUNCT
eurjchem-2402	108	16	dna	dna	PROPN
eurjchem-2402	108	17	decreases	decrease	VERB
eurjchem-2402	108	18	(	(	PUNCT
eurjchem-2402	108	19	figure	figure	NOUN
eurjchem-2402	108	20	3	3	NUM
eurjchem-2402	108	21	)	)	PUNCT
eurjchem-2402	108	22	.	.	PUNCT
eurjchem-2402	109	1	for	for	ADP
eurjchem-2402	109	2	comparison	comparison	NOUN
eurjchem-2402	109	3	,	,	PUNCT
eurjchem-2402	109	4	dna	dna	PROPN
eurjchem-2402	109	5	viscosity	viscosity	NOUN
eurjchem-2402	109	6	was	be	AUX
eurjchem-2402	109	7	performed	perform	VERB
eurjchem-2402	109	8	using	use	VERB
eurjchem-2402	109	9	a	a	DET
eurjchem-2402	109	10	dna	dna	PROPN
eurjchem-2402	109	11	intercalator	intercalator	NOUN
eurjchem-2402	109	12	,	,	PUNCT
eurjchem-2402	109	13	known	know	VERB
eurjchem-2402	109	14	as	as	ADP
eurjchem-2402	109	15	thiazole	thiazole	NOUN
eurjchem-2402	109	16	orange	orange	NOUN
eurjchem-2402	110	1	[	[	X
eurjchem-2402	110	2	30	30	NUM
eurjchem-2402	110	3	]	]	PUNCT
eurjchem-2402	110	4	,	,	PUNCT
eurjchem-2402	110	5	which	which	PRON
eurjchem-2402	110	6	increases	increase	VERB
eurjchem-2402	110	7	dna	dna	NOUN
eurjchem-2402	110	8	viscosity	viscosity	NOUN
eurjchem-2402	110	9	in	in	ADP
eurjchem-2402	110	10	all	all	DET
eurjchem-2402	110	11	molar	molar	ADJ
eurjchem-2402	110	12	additions	addition	NOUN
eurjchem-2402	110	13	studied	study	VERB
eurjchem-2402	110	14	.	.	PUNCT
eurjchem-2402	111	1	therefore	therefore	ADV
eurjchem-2402	111	2	,	,	PUNCT
eurjchem-2402	111	3	a	a	DET
eurjchem-2402	111	4	different	different	ADJ
eurjchem-2402	111	5	curve	curve	NOUN
eurjchem-2402	111	6	profile	profile	NOUN
eurjchem-2402	111	7	for	for	ADP
eurjchem-2402	111	8	the	the	DET
eurjchem-2402	111	9	ruthenium	ruthenium	NOUN
eurjchem-2402	111	10	complex	complex	NOUN
eurjchem-2402	111	11	compared	compare	VERB
eurjchem-2402	111	12	with	with	ADP
eurjchem-2402	111	13	thiazole	thiazole	NOUN
eurjchem-2402	111	14	orange	orange	NOUN
eurjchem-2402	111	15	may	may	AUX
eurjchem-2402	111	16	suggest	suggest	VERB
eurjchem-2402	111	17	that	that	SCONJ
eurjchem-2402	111	18	the	the	DET
eurjchem-2402	111	19	complex	complex	NOUN
eurjchem-2402	111	20	does	do	AUX
eurjchem-2402	111	21	not	not	PART
eurjchem-2402	111	22	act	act	VERB
eurjchem-2402	111	23	as	as	ADP
eurjchem-2402	111	24	a	a	DET
eurjchem-2402	111	25	dna	dna	PROPN
eurjchem-2402	111	26	intercalator	intercalator	NOUN
eurjchem-2402	111	27	.	.	PUNCT
eurjchem-2402	112	1	3.2	3.2	NUM
eurjchem-2402	112	2	.	.	PUNCT
eurjchem-2402	113	1	electrochemical	electrochemical	ADJ
eurjchem-2402	113	2	and	and	CCONJ
eurjchem-2402	113	3	dna	dna	PROPN
eurjchem-2402	113	4	interaction	interaction	NOUN
eurjchem-2402	113	5	study	study	NOUN
eurjchem-2402	113	6	by	by	ADP
eurjchem-2402	113	7	square	square	ADJ
eurjchem-2402	113	8	wave	wave	NOUN
eurjchem-2402	113	9	voltammetry	voltammetry	NOUN
eurjchem-2402	113	10	the	the	DET
eurjchem-2402	113	11	complex	complex	NOUN
eurjchem-2402	114	1	[	[	X
eurjchem-2402	114	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	114	3	]	]	PUNCT
eurjchem-2402	114	4	was	be	AUX
eurjchem-2402	114	5	characterized	characterize	VERB
eurjchem-2402	114	6	using	use	VERB
eurjchem-2402	114	7	cyclic	cyclic	ADJ
eurjchem-2402	114	8	voltammetry	voltammetry	NOUN
eurjchem-2402	114	9	(	(	PUNCT
eurjchem-2402	114	10	figure	figure	NOUN
eurjchem-2402	114	11	4	4	NUM
eurjchem-2402	114	12	)	)	PUNCT
eurjchem-2402	114	13	.	.	PUNCT
eurjchem-2402	115	1	this	this	DET
eurjchem-2402	115	2	technique	technique	NOUN
eurjchem-2402	115	3	was	be	AUX
eurjchem-2402	115	4	used	use	VERB
eurjchem-2402	115	5	because	because	SCONJ
eurjchem-2402	115	6	of	of	ADP
eurjchem-2402	115	7	its	its	PRON
eurjchem-2402	115	8	sensitivity	sensitivity	NOUN
eurjchem-2402	115	9	to	to	ADP
eurjchem-2402	115	10	redox	redox	NOUN
eurjchem-2402	115	11	processes	process	NOUN
eurjchem-2402	115	12	.	.	PUNCT
eurjchem-2402	116	1	cyclic	cyclic	ADJ
eurjchem-2402	116	2	voltammograms	voltammogram	NOUN
eurjchem-2402	116	3	were	be	AUX
eurjchem-2402	116	4	investigated	investigate	VERB
eurjchem-2402	116	5	in	in	ADP
eurjchem-2402	116	6	the	the	DET
eurjchem-2402	116	7	range	range	NOUN
eurjchem-2402	116	8	of	of	ADP
eurjchem-2402	116	9	0	0	NUM
eurjchem-2402	116	10	to	to	ADP
eurjchem-2402	116	11	+1.6	+1.6	PROPN
eurjchem-2402	116	12	v	v	NOUN
eurjchem-2402	116	13	at	at	ADP
eurjchem-2402	116	14	different	different	ADJ
eurjchem-2402	116	15	scan	scan	ADJ
eurjchem-2402	116	16	rates	rate	NOUN
eurjchem-2402	116	17	,	,	PUNCT
eurjchem-2402	116	18	and	and	CCONJ
eurjchem-2402	116	19	the	the	DET
eurjchem-2402	116	20	recorded	record	VERB
eurjchem-2402	116	21	cyclic	cyclic	NOUN
eurjchem-2402	116	22	voltammograms	voltammogram	NOUN
eurjchem-2402	116	23	in	in	ADP
eurjchem-2402	116	24	the	the	DET
eurjchem-2402	116	25	scan	scan	ADJ
eurjchem-2402	116	26	rate	rate	NOUN
eurjchem-2402	116	27	range	range	NOUN
eurjchem-2402	116	28	of	of	ADP
eurjchem-2402	116	29	10	10	NUM
eurjchem-2402	116	30	-	-	SYM
eurjchem-2402	116	31	100	100	NUM
eurjchem-2402	116	32	mv	mv	PROPN
eurjchem-2402	116	33	/	/	SYM
eurjchem-2402	116	34	s	s	PART
eurjchem-2402	116	35	can	can	AUX
eurjchem-2402	116	36	be	be	AUX
eurjchem-2402	116	37	seen	see	VERB
eurjchem-2402	116	38	in	in	ADP
eurjchem-2402	116	39	figure	figure	NOUN
eurjchem-2402	116	40	5	5	NUM
eurjchem-2402	116	41	.	.	PUNCT
eurjchem-2402	117	1	in	in	ADP
eurjchem-2402	117	2	the	the	DET
eurjchem-2402	117	3	cyclic	cyclic	PROPN
eurjchem-2402	117	4	voltammogram	voltammogram	NOUN
eurjchem-2402	117	5	shown	show	VERB
eurjchem-2402	117	6	in	in	ADP
eurjchem-2402	117	7	figure	figure	NOUN
eurjchem-2402	117	8	4	4	NUM
eurjchem-2402	117	9	,	,	PUNCT
eurjchem-2402	117	10	the	the	DET
eurjchem-2402	117	11	electrochemical	electrochemical	ADJ
eurjchem-2402	117	12	profile	profile	NOUN
eurjchem-2402	117	13	of	of	ADP
eurjchem-2402	117	14	the	the	DET
eurjchem-2402	117	15	[	[	X
eurjchem-2402	117	16	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	117	17	]	]	X
eurjchem-2402	117	18	complex	complex	ADJ
eurjchem-2402	117	19	presents	present	VERB
eurjchem-2402	117	20	two	two	NUM
eurjchem-2402	117	21	oxidation	oxidation	NOUN
eurjchem-2402	117	22	processes	process	NOUN
eurjchem-2402	117	23	ru(ii)/ru(iii	ru(ii)/ru(iii	NOUN
eurjchem-2402	117	24	)	)	PUNCT
eurjchem-2402	117	25	at	at	ADP
eurjchem-2402	117	26	+0.632	+0.632	PROPN
eurjchem-2402	117	27	v	v	NOUN
eurjchem-2402	117	28	and	and	CCONJ
eurjchem-2402	117	29	+0.926	+0.926	PROPN
eurjchem-2402	117	30	v	v	NOUN
eurjchem-2402	117	31	,	,	PUNCT
eurjchem-2402	117	32	referring	refer	VERB
eurjchem-2402	117	33	to	to	ADP
eurjchem-2402	117	34	the	the	DET
eurjchem-2402	117	35	cisand	cisand	PROPN
eurjchem-2402	117	36	trans	tran	NOUN
eurjchem-2402	117	37	-	-	NOUN
eurjchem-2402	117	38	isomers	isomer	NOUN
eurjchem-2402	117	39	of	of	ADP
eurjchem-2402	117	40	the	the	DET
eurjchem-2402	117	41	[	[	X
eurjchem-2402	117	42	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	117	43	]	]	X
eurjchem-2402	117	44	complex	complex	ADJ
eurjchem-2402	117	45	,	,	PUNCT
eurjchem-2402	117	46	respectively	respectively	ADV
eurjchem-2402	117	47	.	.	PUNCT
eurjchem-2402	118	1	the	the	DET
eurjchem-2402	118	2	oxidation	oxidation	NOUN
eurjchem-2402	118	3	potential	potential	ADJ
eurjchem-2402	118	4	ru(ii)/ru(iii	ru(ii)/ru(iii	NOUN
eurjchem-2402	118	5	)	)	PUNCT
eurjchem-2402	118	6	for	for	SCONJ
eurjchem-2402	118	7	the	the	DET
eurjchem-2402	118	8	cis	cis	NOUN
eurjchem-2402	118	9	isomer	isomer	PROPN
eurjchem-2402	118	10	occurs	occur	VERB
eurjchem-2402	118	11	in	in	ADP
eurjchem-2402	118	12	a	a	DET
eurjchem-2402	118	13	more	more	ADV
eurjchem-2402	118	14	positive	positive	ADJ
eurjchem-2402	118	15	region	region	NOUN
eurjchem-2402	118	16	(	(	PUNCT
eurjchem-2402	118	17	+0.926	+0.926	PROPN
eurjchem-2402	118	18	v	v	NOUN
eurjchem-2402	118	19	)	)	PUNCT
eurjchem-2402	118	20	when	when	SCONJ
eurjchem-2402	118	21	compared	compare	VERB
eurjchem-2402	118	22	to	to	ADP
eurjchem-2402	118	23	the	the	DET
eurjchem-2402	118	24	trans	trans	PROPN
eurjchem-2402	118	25	isomer	isomer	PROPN
eurjchem-2402	118	26	(	(	PUNCT
eurjchem-2402	118	27	+0.632	+0.632	PROPN
eurjchem-2402	118	28	v	v	NOUN
eurjchem-2402	118	29	)	)	PUNCT
eurjchem-2402	118	30	,	,	PUNCT
eurjchem-2402	118	31	indicating	indicate	VERB
eurjchem-2402	118	32	that	that	SCONJ
eurjchem-2402	118	33	in	in	ADP
eurjchem-2402	118	34	cis	cis	NOUN
eurjchem-2402	118	35	-	-	PUNCT
eurjchem-2402	118	36	configuration	configuration	NOUN
eurjchem-2402	118	37	ruthenium	ruthenium	NOUN
eurjchem-2402	118	38	is	be	AUX
eurjchem-2402	118	39	more	more	ADV
eurjchem-2402	118	40	deficient	deficient	ADJ
eurjchem-2402	118	41	in	in	ADP
eurjchem-2402	118	42	electron	electron	NOUN
eurjchem-2402	118	43	density	density	NOUN
eurjchem-2402	118	44	,	,	PUNCT
eurjchem-2402	118	45	requiring	require	VERB
eurjchem-2402	118	46	a	a	DET
eurjchem-2402	118	47	higher	high	ADJ
eurjchem-2402	118	48	potential	potential	NOUN
eurjchem-2402	118	49	for	for	ADP
eurjchem-2402	118	50	oxidation	oxidation	NOUN
eurjchem-2402	118	51	of	of	ADP
eurjchem-2402	118	52	the	the	DET
eurjchem-2402	118	53	metal	metal	NOUN
eurjchem-2402	118	54	.	.	PUNCT
eurjchem-2402	119	1	the	the	DET
eurjchem-2402	119	2	redox	redox	ADJ
eurjchem-2402	119	3	potential	potential	NOUN
eurjchem-2402	119	4	for	for	ADP
eurjchem-2402	119	5	the	the	DET
eurjchem-2402	119	6	cis	cis	NOUN
eurjchem-2402	119	7	-	-	PUNCT
eurjchem-2402	119	8	isomer	isomer	NOUN
eurjchem-2402	119	9	occurs	occur	VERB
eurjchem-2402	119	10	at	at	ADP
eurjchem-2402	119	11	a	a	DET
eurjchem-2402	119	12	higher	high	ADJ
eurjchem-2402	119	13	potential	potential	NOUN
eurjchem-2402	119	14	than	than	ADP
eurjchem-2402	119	15	that	that	PRON
eurjchem-2402	119	16	of	of	ADP
eurjchem-2402	119	17	the	the	DET
eurjchem-2402	119	18	trans	trans	NOUN
eurjchem-2402	119	19	-	-	NOUN
eurjchem-2402	119	20	isomer	isomer	ADJ
eurjchem-2402	119	21	as	as	ADP
eurjchem-2402	119	22	a	a	DET
eurjchem-2402	119	23	result	result	NOUN
eurjchem-2402	119	24	of	of	ADP
eurjchem-2402	119	25	the	the	DET
eurjchem-2402	119	26	increase	increase	NOUN
eurjchem-2402	119	27	in	in	ADP
eurjchem-2402	119	28	the	the	DET
eurjchem-2402	119	29	back	back	NOUN
eurjchem-2402	119	30	-	-	PUNCT
eurjchem-2402	119	31	donation	donation	NOUN
eurjchem-2402	119	32	of	of	ADP
eurjchem-2402	119	33	ruthenium	ruthenium	NOUN
eurjchem-2402	119	34	to	to	ADP
eurjchem-2402	119	35	the	the	DET
eurjchem-2402	119	36	phosphorus	phosphorus	NOUN
eurjchem-2402	119	37	atom	atom	NOUN
eurjchem-2402	119	38	in	in	ADP
eurjchem-2402	119	39	the	the	DET
eurjchem-2402	119	40	cis	cis	NOUN
eurjchem-2402	119	41	-	-	PUNCT
eurjchem-2402	119	42	isomer	isomer	NOUN
eurjchem-2402	119	43	.	.	PUNCT
eurjchem-2402	120	1	this	this	DET
eurjchem-2402	120	2	behaviour	behaviour	NOUN
eurjchem-2402	120	3	occurs	occur	VERB
eurjchem-2402	120	4	because	because	SCONJ
eurjchem-2402	120	5	phosphorus	phosphorus	NOUN
eurjchem-2402	120	6	trans	tran	NOUN
eurjchem-2402	120	7	to	to	ADP
eurjchem-2402	120	8	phosphorus	phosphorus	NOUN
eurjchem-2402	120	9	increases	increase	VERB
eurjchem-2402	120	10	the	the	DET
eurjchem-2402	120	11	trans	trans	PROPN
eurjchem-2402	120	12	cooperative	cooperative	ADJ
eurjchem-2402	120	13	effect	effect	NOUN
eurjchem-2402	120	14	,	,	PUNCT
eurjchem-2402	120	15	lowering	lower	VERB
eurjchem-2402	120	16	the	the	DET
eurjchem-2402	120	17	redox	redox	ADJ
eurjchem-2402	120	18	potential	potential	NOUN
eurjchem-2402	120	19	,	,	PUNCT
eurjchem-2402	120	20	which	which	PRON
eurjchem-2402	120	21	agrees	agree	VERB
eurjchem-2402	120	22	with	with	ADP
eurjchem-2402	120	23	expected	expect	VERB
eurjchem-2402	120	24	by	by	ADP
eurjchem-2402	120	25	sullivan	sullivan	PROPN
eurjchem-2402	120	26	and	and	CCONJ
eurjchem-2402	120	27	meyer	meyer	PROPN
eurjchem-2402	121	1	[	[	X
eurjchem-2402	121	2	31	31	NUM
eurjchem-2402	121	3	]	]	PUNCT
eurjchem-2402	121	4	.	.	PUNCT
eurjchem-2402	122	1	from	from	ADP
eurjchem-2402	122	2	the	the	DET
eurjchem-2402	122	3	cyclic	cyclic	ADJ
eurjchem-2402	122	4	voltammograms	voltammogram	NOUN
eurjchem-2402	122	5	obtained	obtain	VERB
eurjchem-2402	122	6	at	at	ADP
eurjchem-2402	122	7	different	different	ADJ
eurjchem-2402	122	8	scan	scan	ADJ
eurjchem-2402	122	9	rates	rate	NOUN
eurjchem-2402	122	10	,	,	PUNCT
eurjchem-2402	122	11	linear	linear	ADJ
eurjchem-2402	122	12	relationships	relationship	NOUN
eurjchem-2402	122	13	between	between	ADP
eurjchem-2402	122	14	anodic	anodic	ADJ
eurjchem-2402	122	15	peak	peak	NOUN
eurjchem-2402	122	16	current	current	NOUN
eurjchem-2402	122	17	and	and	CCONJ
eurjchem-2402	122	18	the	the	DET
eurjchem-2402	122	19	square	square	ADJ
eurjchem-2402	122	20	root	root	NOUN
eurjchem-2402	122	21	of	of	ADP
eurjchem-2402	122	22	the	the	DET
eurjchem-2402	122	23	scan	scan	ADJ
eurjchem-2402	122	24	rate	rate	NOUN
eurjchem-2402	122	25	(	(	PUNCT
eurjchem-2402	122	26	ip	ip	NOUN
eurjchem-2402	122	27	vs.	vs.	ADP
eurjchem-2402	122	28	v1/2	v1/2	NOUN
eurjchem-2402	122	29	shown	show	VERB
eurjchem-2402	122	30	in	in	ADP
eurjchem-2402	122	31	figure	figure	NOUN
eurjchem-2402	122	32	5	5	NUM
eurjchem-2402	122	33	)	)	PUNCT
eurjchem-2402	122	34	were	be	AUX
eurjchem-2402	122	35	obtained	obtain	VERB
eurjchem-2402	122	36	for	for	ADP
eurjchem-2402	122	37	the	the	DET
eurjchem-2402	122	38	oxidation	oxidation	NOUN
eurjchem-2402	122	39	peak	peak	NOUN
eurjchem-2402	122	40	of	of	ADP
eurjchem-2402	122	41	the	the	DET
eurjchem-2402	122	42	cis	cis	NOUN
eurjchem-2402	122	43	and	and	CCONJ
eurjchem-2402	122	44	trans	trans	NOUN
eurjchem-2402	122	45	isomers	isomer	NOUN
eurjchem-2402	122	46	,	,	PUNCT
eurjchem-2402	122	47	showing	show	VERB
eurjchem-2402	122	48	that	that	SCONJ
eurjchem-2402	122	49	both	both	DET
eurjchem-2402	122	50	redox	redox	NOUN
eurjchem-2402	122	51	processes	process	NOUN
eurjchem-2402	122	52	were	be	AUX
eurjchem-2402	122	53	controlled	control	VERB
eurjchem-2402	122	54	only	only	ADV
eurjchem-2402	122	55	by	by	ADP
eurjchem-2402	122	56	diffusion	diffusion	NOUN
eurjchem-2402	122	57	.	.	PUNCT
eurjchem-2402	123	1	the	the	DET
eurjchem-2402	123	2	electrochemical	electrochemical	ADJ
eurjchem-2402	123	3	response	response	NOUN
eurjchem-2402	123	4	of	of	ADP
eurjchem-2402	123	5	the	the	DET
eurjchem-2402	123	6	complex	complex	NOUN
eurjchem-2402	123	7	can	can	AUX
eurjchem-2402	123	8	change	change	VERB
eurjchem-2402	123	9	in	in	ADP
eurjchem-2402	123	10	the	the	DET
eurjchem-2402	123	11	presence	presence	NOUN
eurjchem-2402	123	12	of	of	ADP
eurjchem-2402	123	13	dna	dna	PROPN
eurjchem-2402	123	14	.	.	PUNCT
eurjchem-2402	124	1	intercalation	intercalation	NOUN
eurjchem-2402	124	2	interactions	interaction	NOUN
eurjchem-2402	124	3	lead	lead	VERB
eurjchem-2402	124	4	to	to	ADP
eurjchem-2402	124	5	the	the	DET
eurjchem-2402	124	6	potential	potential	ADJ
eurjchem-2402	124	7	shift	shift	NOUN
eurjchem-2402	124	8	to	to	ADP
eurjchem-2402	124	9	positive	positive	ADJ
eurjchem-2402	124	10	values	value	NOUN
eurjchem-2402	124	11	as	as	ADP
eurjchem-2402	124	12	a	a	DET
eurjchem-2402	124	13	result	result	NOUN
eurjchem-2402	124	14	of	of	ADP
eurjchem-2402	124	15	the	the	DET
eurjchem-2402	124	16	increase	increase	NOUN
eurjchem-2402	124	17	in	in	ADP
eurjchem-2402	124	18	the	the	DET
eurjchem-2402	124	19	diffusion	diffusion	NOUN
eurjchem-2402	124	20	coefficient	coefficient	NOUN
eurjchem-2402	124	21	caused	cause	VERB
eurjchem-2402	124	22	by	by	ADP
eurjchem-2402	124	23	the	the	DET
eurjchem-2402	124	24	dna	dna	PROPN
eurjchem-2402	124	25	molecule	molecule	NOUN
eurjchem-2402	124	26	.	.	PUNCT
eurjchem-2402	125	1	campideli	campideli	NOUN
eurjchem-2402	125	2	et	et	PROPN
eurjchem-2402	125	3	al	al	PROPN
eurjchem-2402	125	4	.	.	PUNCT
eurjchem-2402	125	5	/	/	SYM
eurjchem-2402	125	6	european	european	PROPN
eurjchem-2402	125	7	journal	journal	PROPN
eurjchem-2402	125	8	of	of	ADP
eurjchem-2402	125	9	chemistry	chemistry	NOUN
eurjchem-2402	125	10	14	14	NUM
eurjchem-2402	125	11	(	(	PUNCT
eurjchem-2402	125	12	2	2	NUM
eurjchem-2402	125	13	)	)	PUNCT
eurjchem-2402	125	14	(	(	PUNCT
eurjchem-2402	125	15	2023	2023	NUM
eurjchem-2402	125	16	)	)	PUNCT
eurjchem-2402	125	17	193	193	NUM
eurjchem-2402	125	18	-	-	SYM
eurjchem-2402	125	19	201	201	NUM
eurjchem-2402	125	20	197	197	NUM
eurjchem-2402	125	21	2023	2023	NUM
eurjchem-2402	125	22	–	–	PUNCT
eurjchem-2402	125	23	european	european	ADJ
eurjchem-2402	125	24	journal	journal	NOUN
eurjchem-2402	125	25	of	of	ADP
eurjchem-2402	125	26	chemistry	chemistry	NOUN
eurjchem-2402	125	27	–	–	PUNCT
eurjchem-2402	125	28	cc	cc	NOUN
eurjchem-2402	125	29	by	by	ADP
eurjchem-2402	125	30	nc	nc	PROPN
eurjchem-2402	125	31	–	–	PUNCT
eurjchem-2402	125	32	doi	doi	NOUN
eurjchem-2402	125	33	:	:	PUNCT
eurjchem-2402	125	34	10.5155	10.5155	NUM
eurjchem-2402	125	35	/	/	SYM
eurjchem-2402	125	36	eurjchem.14.2.193	eurjchem.14.2.193	NUM
eurjchem-2402	125	37	-	-	SYM
eurjchem-2402	125	38	201.2402	201.2402	NUM
eurjchem-2402	125	39	(	(	PUNCT
eurjchem-2402	125	40	a	a	NOUN
eurjchem-2402	125	41	)	)	PUNCT
eurjchem-2402	125	42	(	(	PUNCT
eurjchem-2402	125	43	b	b	X
eurjchem-2402	125	44	)	)	PUNCT
eurjchem-2402	125	45	(	(	PUNCT
eurjchem-2402	125	46	c	c	X
eurjchem-2402	125	47	)	)	PUNCT
eurjchem-2402	125	48	figure	figure	NOUN
eurjchem-2402	125	49	5	5	NUM
eurjchem-2402	125	50	.	.	PUNCT
eurjchem-2402	126	1	(	(	PUNCT
eurjchem-2402	126	2	a	a	X
eurjchem-2402	126	3	)	)	PUNCT
eurjchem-2402	126	4	cyclic	cyclic	ADJ
eurjchem-2402	126	5	voltammogram	voltammogram	NOUN
eurjchem-2402	126	6	of	of	ADP
eurjchem-2402	126	7	the	the	DET
eurjchem-2402	126	8	complex	complex	NOUN
eurjchem-2402	126	9	[	[	X
eurjchem-2402	126	10	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	126	11	]	]	X
eurjchem-2402	126	12	(	(	PUNCT
eurjchem-2402	126	13	isomer	isomer	ADJ
eurjchem-2402	126	14	cis	cis	NOUN
eurjchem-2402	126	15	and	and	CCONJ
eurjchem-2402	126	16	trans	tran	NOUN
eurjchem-2402	126	17	)	)	PUNCT
eurjchem-2402	126	18	,	,	PUNCT
eurjchem-2402	126	19	at	at	ADP
eurjchem-2402	126	20	concentration	concentration	NOUN
eurjchem-2402	126	21	2×10	2×10	NUM
eurjchem-2402	126	22	-	-	SYM
eurjchem-2402	126	23	4	4	NUM
eurjchem-2402	126	24	mol	mol	NOUN
eurjchem-2402	126	25	/	/	SYM
eurjchem-2402	126	26	l	l	NOUN
eurjchem-2402	126	27	in	in	ADP
eurjchem-2402	126	28	0.1	0.1	NUM
eurjchem-2402	126	29	mol	mol	ADP
eurjchem-2402	126	30	/	/	SYM
eurjchem-2402	126	31	l	l	NOUN
eurjchem-2402	126	32	ptba	ptba	NOUN
eurjchem-2402	126	33	,	,	PUNCT
eurjchem-2402	126	34	in	in	ADP
eurjchem-2402	126	35	ch2cl2	ch2cl2	NOUN
eurjchem-2402	126	36	at	at	ADP
eurjchem-2402	126	37	different	different	ADJ
eurjchem-2402	126	38	scan	scan	ADJ
eurjchem-2402	126	39	rates	rate	NOUN
eurjchem-2402	126	40	:	:	PUNCT
eurjchem-2402	126	41	(	(	PUNCT
eurjchem-2402	126	42	i	i	NOUN
eurjchem-2402	126	43	)	)	PUNCT
eurjchem-2402	126	44	10	10	NUM
eurjchem-2402	126	45	mv	mv	PROPN
eurjchem-2402	126	46	/	/	SYM
eurjchem-2402	126	47	s	s	PROPN
eurjchem-2402	126	48	;	;	PUNCT
eurjchem-2402	126	49	(	(	PUNCT
eurjchem-2402	126	50	ii	ii	NOUN
eurjchem-2402	126	51	)	)	PUNCT
eurjchem-2402	126	52	20	20	NUM
eurjchem-2402	126	53	mv	mv	PROPN
eurjchem-2402	126	54	/	/	SYM
eurjchem-2402	126	55	s	s	PROPN
eurjchem-2402	126	56	;	;	PUNCT
eurjchem-2402	126	57	(	(	PUNCT
eurjchem-2402	126	58	iii	iii	NOUN
eurjchem-2402	126	59	)	)	PUNCT
eurjchem-2402	126	60	30	30	NUM
eurjchem-2402	126	61	mv	mv	PROPN
eurjchem-2402	126	62	/	/	SYM
eurjchem-2402	126	63	s	s	PROPN
eurjchem-2402	126	64	;	;	PUNCT
eurjchem-2402	126	65	(	(	PUNCT
eurjchem-2402	126	66	iv	iv	X
eurjchem-2402	126	67	)	)	PUNCT
eurjchem-2402	126	68	40	40	NUM
eurjchem-2402	126	69	mv	mv	PROPN
eurjchem-2402	126	70	/	/	SYM
eurjchem-2402	126	71	s	s	PROPN
eurjchem-2402	126	72	;	;	PUNCT
eurjchem-2402	126	73	(	(	PUNCT
eurjchem-2402	126	74	v	v	NOUN
eurjchem-2402	126	75	)	)	PUNCT
eurjchem-2402	126	76	50	50	NUM
eurjchem-2402	126	77	mv	mv	PROPN
eurjchem-2402	126	78	/	/	SYM
eurjchem-2402	126	79	s	s	PROPN
eurjchem-2402	126	80	;	;	PUNCT
eurjchem-2402	126	81	(	(	PUNCT
eurjchem-2402	126	82	vi	vi	X
eurjchem-2402	126	83	)	)	PUNCT
eurjchem-2402	126	84	75	75	NUM
eurjchem-2402	126	85	mv	mv	PROPN
eurjchem-2402	126	86	/	/	SYM
eurjchem-2402	126	87	s	s	X
eurjchem-2402	126	88	and	and	CCONJ
eurjchem-2402	126	89	(	(	PUNCT
eurjchem-2402	126	90	vii	vii	PROPN
eurjchem-2402	126	91	)	)	PUNCT
eurjchem-2402	126	92	100	100	NUM
eurjchem-2402	126	93	mv	mv	PROPN
eurjchem-2402	126	94	/	/	SYM
eurjchem-2402	126	95	s.	s.	PROPN
eurjchem-2402	126	96	(	(	PUNCT
eurjchem-2402	126	97	b	b	X
eurjchem-2402	126	98	,	,	PUNCT
eurjchem-2402	126	99	c	c	NOUN
eurjchem-2402	126	100	)	)	PUNCT
eurjchem-2402	126	101	graph	graph	NOUN
eurjchem-2402	126	102	of	of	ADP
eurjchem-2402	126	103	ip	ip	NOUN
eurjchem-2402	126	104	vs.	vs.	ADP
eurjchem-2402	126	105	v1/2	v1/2	NOUN
eurjchem-2402	126	106	obtained	obtain	VERB
eurjchem-2402	126	107	for	for	ADP
eurjchem-2402	126	108	the	the	DET
eurjchem-2402	126	109	anodic	anodic	ADJ
eurjchem-2402	126	110	peak	peak	NOUN
eurjchem-2402	126	111	of	of	ADP
eurjchem-2402	126	112	the	the	DET
eurjchem-2402	126	113	isomer	isomer	ADJ
eurjchem-2402	126	114	trans	trans	PROPN
eurjchem-2402	126	115	and	and	CCONJ
eurjchem-2402	126	116	isomer	isomer	ADJ
eurjchem-2402	126	117	cis	cis	NOUN
eurjchem-2402	126	118	.	.	PUNCT
eurjchem-2402	127	1	on	on	ADP
eurjchem-2402	127	2	the	the	DET
eurjchem-2402	127	3	contrary	contrary	NOUN
eurjchem-2402	127	4	,	,	PUNCT
eurjchem-2402	127	5	electrostatic	electrostatic	ADJ
eurjchem-2402	127	6	interactions	interaction	NOUN
eurjchem-2402	127	7	promote	promote	VERB
eurjchem-2402	127	8	a	a	DET
eurjchem-2402	127	9	displacement	displacement	NOUN
eurjchem-2402	127	10	of	of	ADP
eurjchem-2402	127	11	the	the	DET
eurjchem-2402	127	12	potential	potential	NOUN
eurjchem-2402	127	13	to	to	ADP
eurjchem-2402	127	14	more	more	ADV
eurjchem-2402	127	15	negative	negative	ADJ
eurjchem-2402	127	16	values	value	NOUN
eurjchem-2402	127	17	,	,	PUNCT
eurjchem-2402	127	18	since	since	SCONJ
eurjchem-2402	127	19	electrons	electron	NOUN
eurjchem-2402	127	20	are	be	AUX
eurjchem-2402	127	21	transferred	transfer	VERB
eurjchem-2402	127	22	from	from	ADP
eurjchem-2402	127	23	dna	dna	NOUN
eurjchem-2402	127	24	to	to	ADP
eurjchem-2402	127	25	the	the	DET
eurjchem-2402	127	26	complex	complex	ADJ
eurjchem-2402	127	27	.	.	PUNCT
eurjchem-2402	128	1	covalent	covalent	ADJ
eurjchem-2402	128	2	interactions	interaction	NOUN
eurjchem-2402	128	3	,	,	PUNCT
eurjchem-2402	128	4	when	when	SCONJ
eurjchem-2402	128	5	new	new	ADJ
eurjchem-2402	128	6	species	specie	NOUN
eurjchem-2402	128	7	are	be	AUX
eurjchem-2402	128	8	generated	generate	VERB
eurjchem-2402	128	9	,	,	PUNCT
eurjchem-2402	128	10	lead	lead	VERB
eurjchem-2402	128	11	to	to	ADP
eurjchem-2402	128	12	the	the	DET
eurjchem-2402	128	13	appearance	appearance	NOUN
eurjchem-2402	128	14	of	of	ADP
eurjchem-2402	128	15	new	new	ADJ
eurjchem-2402	128	16	redox	redox	NOUN
eurjchem-2402	128	17	processes	process	NOUN
eurjchem-2402	128	18	or	or	CCONJ
eurjchem-2402	128	19	the	the	DET
eurjchem-2402	128	20	disappearance	disappearance	NOUN
eurjchem-2402	128	21	of	of	ADP
eurjchem-2402	128	22	existing	exist	VERB
eurjchem-2402	128	23	processes	process	NOUN
eurjchem-2402	128	24	.	.	PUNCT
eurjchem-2402	129	1	interactions	interaction	NOUN
eurjchem-2402	129	2	between	between	ADP
eurjchem-2402	129	3	the	the	DET
eurjchem-2402	129	4	dna	dna	PROPN
eurjchem-2402	129	5	grooves	groove	NOUN
eurjchem-2402	129	6	may	may	AUX
eurjchem-2402	129	7	not	not	PART
eurjchem-2402	129	8	promote	promote	VERB
eurjchem-2402	129	9	significant	significant	ADJ
eurjchem-2402	129	10	changes	change	NOUN
eurjchem-2402	129	11	in	in	ADP
eurjchem-2402	129	12	potential	potential	ADJ
eurjchem-2402	129	13	values	value	NOUN
eurjchem-2402	129	14	,	,	PUNCT
eurjchem-2402	129	15	but	but	CCONJ
eurjchem-2402	129	16	they	they	PRON
eurjchem-2402	129	17	do	do	AUX
eurjchem-2402	129	18	change	change	VERB
eurjchem-2402	129	19	the	the	DET
eurjchem-2402	129	20	number	number	NOUN
eurjchem-2402	129	21	of	of	ADP
eurjchem-2402	129	22	complexes	complex	NOUN
eurjchem-2402	129	23	available	available	ADJ
eurjchem-2402	129	24	that	that	PRON
eurjchem-2402	129	25	can	can	AUX
eurjchem-2402	129	26	undergo	undergo	VERB
eurjchem-2402	129	27	redox	redox	ADJ
eurjchem-2402	129	28	reactions	reaction	NOUN
eurjchem-2402	129	29	,	,	PUNCT
eurjchem-2402	129	30	as	as	ADP
eurjchem-2402	129	31	in	in	ADP
eurjchem-2402	129	32	other	other	ADJ
eurjchem-2402	129	33	modes	mode	NOUN
eurjchem-2402	129	34	of	of	ADP
eurjchem-2402	129	35	interaction	interaction	NOUN
eurjchem-2402	129	36	,	,	PUNCT
eurjchem-2402	129	37	affecting	affect	VERB
eurjchem-2402	129	38	the	the	DET
eurjchem-2402	129	39	intensity	intensity	NOUN
eurjchem-2402	129	40	of	of	ADP
eurjchem-2402	129	41	electrochemical	electrochemical	ADJ
eurjchem-2402	129	42	processes	process	NOUN
eurjchem-2402	129	43	[	[	X
eurjchem-2402	129	44	13,32	13,32	NUM
eurjchem-2402	129	45	]	]	X
eurjchem-2402	129	46	electrochemical	electrochemical	ADJ
eurjchem-2402	129	47	study	study	NOUN
eurjchem-2402	129	48	of	of	ADP
eurjchem-2402	129	49	the	the	DET
eurjchem-2402	129	50	interaction	interaction	NOUN
eurjchem-2402	129	51	with	with	ADP
eurjchem-2402	129	52	ct	ct	PROPN
eurjchem-2402	129	53	-	-	NOUN
eurjchem-2402	129	54	dna	dna	PROPN
eurjchem-2402	129	55	with	with	ADP
eurjchem-2402	129	56	the	the	DET
eurjchem-2402	129	57	mixture	mixture	NOUN
eurjchem-2402	129	58	of	of	ADP
eurjchem-2402	129	59	cisand	cisand	NOUN
eurjchem-2402	129	60	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	129	61	]	]	PUNCT
eurjchem-2402	129	62	complexes	complex	NOUN
eurjchem-2402	129	63	was	be	AUX
eurjchem-2402	129	64	performed	perform	VERB
eurjchem-2402	129	65	using	use	VERB
eurjchem-2402	129	66	swv	swv	PROPN
eurjchem-2402	129	67	.	.	PUNCT
eurjchem-2402	130	1	this	this	DET
eurjchem-2402	130	2	technique	technique	NOUN
eurjchem-2402	130	3	was	be	AUX
eurjchem-2402	130	4	used	use	VERB
eurjchem-2402	130	5	because	because	SCONJ
eurjchem-2402	130	6	of	of	ADP
eurjchem-2402	130	7	its	its	PRON
eurjchem-2402	130	8	high	high	ADJ
eurjchem-2402	130	9	sensitivity	sensitivity	NOUN
eurjchem-2402	130	10	to	to	ADP
eurjchem-2402	130	11	redox	redox	NOUN
eurjchem-2402	130	12	processes	process	NOUN
eurjchem-2402	130	13	and	and	CCONJ
eurjchem-2402	130	14	reaction	reaction	NOUN
eurjchem-2402	130	15	formation	formation	NOUN
eurjchem-2402	130	16	,	,	PUNCT
eurjchem-2402	130	17	which	which	PRON
eurjchem-2402	130	18	is	be	AUX
eurjchem-2402	130	19	greater	great	ADJ
eurjchem-2402	130	20	than	than	ADP
eurjchem-2402	130	21	that	that	PRON
eurjchem-2402	130	22	of	of	ADP
eurjchem-2402	130	23	the	the	DET
eurjchem-2402	130	24	cyclic	cyclic	ADJ
eurjchem-2402	130	25	voltammetry	voltammetry	NOUN
eurjchem-2402	130	26	technique	technique	NOUN
eurjchem-2402	130	27	.	.	PUNCT
eurjchem-2402	131	1	figure	figure	NOUN
eurjchem-2402	131	2	6	6	NUM
eurjchem-2402	131	3	shows	show	VERB
eurjchem-2402	131	4	the	the	DET
eurjchem-2402	131	5	recorded	record	VERB
eurjchem-2402	131	6	voltammetric	voltammetric	ADJ
eurjchem-2402	131	7	profile	profile	NOUN
eurjchem-2402	131	8	of	of	ADP
eurjchem-2402	131	9	the	the	DET
eurjchem-2402	131	10	complex	complex	NOUN
eurjchem-2402	131	11	with	with	ADP
eurjchem-2402	131	12	successive	successive	ADJ
eurjchem-2402	131	13	10	10	NUM
eurjchem-2402	131	14	µl	µl	ADP
eurjchem-2402	131	15	aliquots	aliquot	NOUN
eurjchem-2402	131	16	of	of	ADP
eurjchem-2402	131	17	a	a	DET
eurjchem-2402	131	18	ct	ct	ADJ
eurjchem-2402	131	19	-	-	PUNCT
eurjchem-2402	131	20	dna	dna	PROPN
eurjchem-2402	131	21	solution	solution	NOUN
eurjchem-2402	131	22	.	.	PUNCT
eurjchem-2402	132	1	after	after	ADP
eurjchem-2402	132	2	adding	add	VERB
eurjchem-2402	132	3	different	different	ADJ
eurjchem-2402	132	4	concentrations	concentration	NOUN
eurjchem-2402	132	5	of	of	ADP
eurjchem-2402	132	6	ct	ct	PROPN
eurjchem-2402	132	7	-	-	PUNCT
eurjchem-2402	132	8	dna	dna	NOUN
eurjchem-2402	132	9	to	to	ADP
eurjchem-2402	132	10	the	the	DET
eurjchem-2402	132	11	solution	solution	NOUN
eurjchem-2402	132	12	containing	contain	VERB
eurjchem-2402	132	13	the	the	DET
eurjchem-2402	132	14	mixture	mixture	NOUN
eurjchem-2402	132	15	of	of	ADP
eurjchem-2402	132	16	cis	cis	NOUN
eurjchem-2402	132	17	and	and	CCONJ
eurjchem-2402	132	18	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	132	19	]	]	PUNCT
eurjchem-2402	132	20	complexes	complex	NOUN
eurjchem-2402	132	21	(	(	PUNCT
eurjchem-2402	132	22	figure	figure	NOUN
eurjchem-2402	132	23	6	6	NUM
eurjchem-2402	132	24	)	)	PUNCT
eurjchem-2402	132	25	,	,	PUNCT
eurjchem-2402	132	26	a	a	DET
eurjchem-2402	132	27	significant	significant	ADJ
eurjchem-2402	132	28	current	current	ADJ
eurjchem-2402	132	29	decrease	decrease	NOUN
eurjchem-2402	132	30	was	be	AUX
eurjchem-2402	132	31	observed	observe	VERB
eurjchem-2402	132	32	in	in	ADP
eurjchem-2402	132	33	the	the	DET
eurjchem-2402	132	34	ru(ii)/ru(iii	ru(ii)/ru(iii	NOUN
eurjchem-2402	132	35	)	)	PUNCT
eurjchem-2402	132	36	redox	redox	ADJ
eurjchem-2402	132	37	process	process	NOUN
eurjchem-2402	132	38	,	,	PUNCT
eurjchem-2402	132	39	indicating	indicate	VERB
eurjchem-2402	132	40	that	that	SCONJ
eurjchem-2402	132	41	complex	complex	ADJ
eurjchem-2402	132	42	/	/	SYM
eurjchem-2402	132	43	dna	dna	NOUN
eurjchem-2402	132	44	interactions	interaction	NOUN
eurjchem-2402	132	45	are	be	AUX
eurjchem-2402	132	46	occurring	occur	VERB
eurjchem-2402	132	47	.	.	PUNCT
eurjchem-2402	133	1	in	in	ADP
eurjchem-2402	133	2	the	the	DET
eurjchem-2402	133	3	cis	cis	NOUN
eurjchem-2402	133	4	-	-	PUNCT
eurjchem-2402	133	5	isomer	isomer	NOUN
eurjchem-2402	133	6	(	(	PUNCT
eurjchem-2402	133	7	figure	figure	NOUN
eurjchem-2402	133	8	6	6	NUM
eurjchem-2402	133	9	)	)	PUNCT
eurjchem-2402	133	10	,	,	PUNCT
eurjchem-2402	133	11	the	the	DET
eurjchem-2402	133	12	current	current	NOUN
eurjchem-2402	133	13	of	of	ADP
eurjchem-2402	133	14	the	the	DET
eurjchem-2402	133	15	ru(ii)/ru(iii	ru(ii)/ru(iii	NOUN
eurjchem-2402	133	16	)	)	PUNCT
eurjchem-2402	133	17	redox	redox	ADJ
eurjchem-2402	133	18	process	process	NOUN
eurjchem-2402	133	19	decreases	decrease	VERB
eurjchem-2402	133	20	and	and	CCONJ
eurjchem-2402	133	21	the	the	DET
eurjchem-2402	133	22	potential	potential	NOUN
eurjchem-2402	133	23	does	do	AUX
eurjchem-2402	133	24	not	not	PART
eurjchem-2402	133	25	change	change	VERB
eurjchem-2402	133	26	;	;	PUNCT
eurjchem-2402	133	27	this	this	DET
eurjchem-2402	133	28	behaviour	behaviour	NOUN
eurjchem-2402	133	29	may	may	AUX
eurjchem-2402	133	30	indicate	indicate	VERB
eurjchem-2402	133	31	an	an	DET
eurjchem-2402	133	32	interaction	interaction	NOUN
eurjchem-2402	133	33	between	between	ADP
eurjchem-2402	133	34	the	the	DET
eurjchem-2402	133	35	dna	dna	PROPN
eurjchem-2402	133	36	grooves	groove	VERB
eurjchem-2402	133	37	.	.	PUNCT
eurjchem-2402	134	1	on	on	ADP
eurjchem-2402	134	2	the	the	DET
eurjchem-2402	134	3	other	other	ADJ
eurjchem-2402	134	4	hand	hand	NOUN
eurjchem-2402	134	5	,	,	PUNCT
eurjchem-2402	134	6	analysing	analyse	VERB
eurjchem-2402	134	7	the	the	DET
eurjchem-2402	134	8	ru(ii)/ru(iii	ru(ii)/ru(iii	NOUN
eurjchem-2402	134	9	)	)	PUNCT
eurjchem-2402	134	10	redox	redox	ADJ
eurjchem-2402	134	11	process	process	NOUN
eurjchem-2402	134	12	for	for	ADP
eurjchem-2402	134	13	the	the	DET
eurjchem-2402	134	14	trans	trans	NOUN
eurjchem-2402	134	15	-	-	ADJ
eurjchem-2402	134	16	isomer	isomer	ADJ
eurjchem-2402	134	17	after	after	ADP
eurjchem-2402	134	18	successive	successive	ADJ
eurjchem-2402	134	19	ct	ct	PROPN
eurjchem-2402	134	20	-	-	PUNCT
eurjchem-2402	134	21	dna	dna	PROPN
eurjchem-2402	134	22	additions	addition	NOUN
eurjchem-2402	134	23	(	(	PUNCT
eurjchem-2402	134	24	figure	figure	NOUN
eurjchem-2402	134	25	6	6	NUM
eurjchem-2402	134	26	)	)	PUNCT
eurjchem-2402	134	27	,	,	PUNCT
eurjchem-2402	134	28	it	it	PRON
eurjchem-2402	134	29	is	be	AUX
eurjchem-2402	134	30	possible	possible	ADJ
eurjchem-2402	134	31	to	to	PART
eurjchem-2402	134	32	observe	observe	VERB
eurjchem-2402	134	33	that	that	SCONJ
eurjchem-2402	134	34	the	the	DET
eurjchem-2402	134	35	potential	potential	NOUN
eurjchem-2402	134	36	shifted	shift	VERB
eurjchem-2402	134	37	to	to	ADP
eurjchem-2402	134	38	the	the	DET
eurjchem-2402	134	39	most	most	ADV
eurjchem-2402	134	40	positive	positive	ADJ
eurjchem-2402	134	41	region	region	NOUN
eurjchem-2402	134	42	and	and	CCONJ
eurjchem-2402	134	43	a	a	DET
eurjchem-2402	134	44	subsequent	subsequent	ADJ
eurjchem-2402	134	45	increase	increase	NOUN
eurjchem-2402	134	46	in	in	ADP
eurjchem-2402	134	47	the	the	DET
eurjchem-2402	134	48	peak	peak	NOUN
eurjchem-2402	134	49	current	current	NOUN
eurjchem-2402	134	50	,	,	PUNCT
eurjchem-2402	134	51	in	in	ADP
eurjchem-2402	134	52	the	the	DET
eurjchem-2402	134	53	case	case	NOUN
eurjchem-2402	134	54	of	of	ADP
eurjchem-2402	134	55	the	the	DET
eurjchem-2402	134	56	latest	late	ADJ
eurjchem-2402	134	57	ct	ct	ADJ
eurjchem-2402	134	58	-	-	PUNCT
eurjchem-2402	134	59	dna	dna	NOUN
eurjchem-2402	134	60	additions	addition	NOUN
eurjchem-2402	134	61	.	.	PUNCT
eurjchem-2402	135	1	this	this	DET
eurjchem-2402	135	2	result	result	NOUN
eurjchem-2402	135	3	indicates	indicate	VERB
eurjchem-2402	135	4	that	that	SCONJ
eurjchem-2402	135	5	the	the	DET
eurjchem-2402	135	6	trans	trans	PROPN
eurjchem-2402	135	7	-	-	ADJ
eurjchem-2402	135	8	isomer	isomer	ADJ
eurjchem-2402	135	9	may	may	AUX
eurjchem-2402	135	10	be	be	AUX
eurjchem-2402	135	11	interacting	interact	VERB
eurjchem-2402	135	12	with	with	ADP
eurjchem-2402	135	13	ct	ct	PROPN
eurjchem-2402	135	14	-	-	NOUN
eurjchem-2402	135	15	dna	dna	NOUN
eurjchem-2402	135	16	through	through	ADP
eurjchem-2402	135	17	intercalation	intercalation	NOUN
eurjchem-2402	135	18	or	or	CCONJ
eurjchem-2402	135	19	even	even	ADV
eurjchem-2402	135	20	through	through	ADP
eurjchem-2402	135	21	covalence	covalence	NOUN
eurjchem-2402	135	22	,	,	PUNCT
eurjchem-2402	135	23	different	different	ADJ
eurjchem-2402	135	24	from	from	ADP
eurjchem-2402	135	25	the	the	DET
eurjchem-2402	135	26	behaviour	behaviour	NOUN
eurjchem-2402	135	27	observed	observe	VERB
eurjchem-2402	135	28	in	in	ADP
eurjchem-2402	135	29	the	the	DET
eurjchem-2402	135	30	cis	cis	NOUN
eurjchem-2402	135	31	-	-	PUNCT
eurjchem-2402	135	32	isomer	isomer	NOUN
eurjchem-2402	135	33	of	of	ADP
eurjchem-2402	135	34	the	the	DET
eurjchem-2402	135	35	[	[	X
eurjchem-2402	135	36	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	135	37	]	]	X
eurjchem-2402	135	38	complex	complex	ADJ
eurjchem-2402	135	39	.	.	PUNCT
eurjchem-2402	136	1	to	to	PART
eurjchem-2402	136	2	investigate	investigate	VERB
eurjchem-2402	136	3	whether	whether	SCONJ
eurjchem-2402	136	4	the	the	DET
eurjchem-2402	136	5	redox	redox	ADJ
eurjchem-2402	136	6	potential	potential	ADJ
eurjchem-2402	136	7	changes	change	NOUN
eurjchem-2402	136	8	due	due	ADJ
eurjchem-2402	136	9	to	to	ADP
eurjchem-2402	136	10	the	the	DET
eurjchem-2402	136	11	dilution	dilution	NOUN
eurjchem-2402	136	12	effect	effect	NOUN
eurjchem-2402	136	13	,	,	PUNCT
eurjchem-2402	136	14	we	we	PRON
eurjchem-2402	136	15	recorded	record	VERB
eurjchem-2402	136	16	a	a	DET
eurjchem-2402	136	17	square	square	ADJ
eurjchem-2402	136	18	-	-	PUNCT
eurjchem-2402	136	19	wave	wave	NOUN
eurjchem-2402	136	20	voltammogram	voltammogram	NOUN
eurjchem-2402	136	21	of	of	ADP
eurjchem-2402	136	22	the	the	DET
eurjchem-2402	136	23	complex	complex	NOUN
eurjchem-2402	136	24	adding	add	VERB
eurjchem-2402	136	25	only	only	ADV
eurjchem-2402	136	26	tris	tris	ADJ
eurjchem-2402	136	27	-	-	PUNCT
eurjchem-2402	136	28	hcl	hcl	NOUN
eurjchem-2402	136	29	buffer	buffer	NOUN
eurjchem-2402	136	30	(	(	PUNCT
eurjchem-2402	136	31	without	without	ADP
eurjchem-2402	136	32	dna	dna	PROPN
eurjchem-2402	136	33	)	)	PUNCT
eurjchem-2402	136	34	,	,	PUNCT
eurjchem-2402	136	35	and	and	CCONJ
eurjchem-2402	136	36	no	no	DET
eurjchem-2402	136	37	significant	significant	ADJ
eurjchem-2402	136	38	changes	change	NOUN
eurjchem-2402	136	39	were	be	AUX
eurjchem-2402	136	40	observed	observe	VERB
eurjchem-2402	136	41	.	.	PUNCT
eurjchem-2402	137	1	thus	thus	ADV
eurjchem-2402	137	2	,	,	PUNCT
eurjchem-2402	137	3	the	the	DET
eurjchem-2402	137	4	peak	peak	ADJ
eurjchem-2402	137	5	current	current	ADJ
eurjchem-2402	137	6	decrease	decrease	NOUN
eurjchem-2402	137	7	occurs	occur	VERB
eurjchem-2402	137	8	through	through	ADP
eurjchem-2402	137	9	dna	dna	PROPN
eurjchem-2402	137	10	interaction	interaction	NOUN
eurjchem-2402	137	11	.	.	PUNCT
eurjchem-2402	138	1	3.3	3.3	NUM
eurjchem-2402	138	2	.	.	PUNCT
eurjchem-2402	139	1	single	single	ADJ
eurjchem-2402	139	2	crystal	crystal	PROPN
eurjchem-2402	139	3	x	x	PROPN
eurjchem-2402	139	4	-	-	NOUN
eurjchem-2402	139	5	ray	ray	NOUN
eurjchem-2402	139	6	diffraction	diffraction	NOUN
eurjchem-2402	139	7	of	of	ADP
eurjchem-2402	139	8	complex	complex	ADJ
eurjchem-2402	139	9	trans[rucl2(dppe)2]cl	trans[rucl2(dppe)2]cl	NOUN
eurjchem-2402	139	10	the	the	DET
eurjchem-2402	139	11	electrochemical	electrochemical	ADJ
eurjchem-2402	139	12	solution	solution	NOUN
eurjchem-2402	139	13	produced	produce	VERB
eurjchem-2402	139	14	orange	orange	NOUN
eurjchem-2402	139	15	crystals	crystal	NOUN
eurjchem-2402	139	16	after	after	ADP
eurjchem-2402	139	17	one	one	NUM
eurjchem-2402	139	18	week	week	NOUN
eurjchem-2402	139	19	.	.	PUNCT
eurjchem-2402	140	1	the	the	DET
eurjchem-2402	140	2	crystals	crystal	NOUN
eurjchem-2402	140	3	were	be	AUX
eurjchem-2402	140	4	analysed	analyse	VERB
eurjchem-2402	140	5	by	by	ADP
eurjchem-2402	140	6	single	single	ADJ
eurjchem-2402	140	7	crystal	crystal	PROPN
eurjchem-2402	140	8	xray	xray	PROPN
eurjchem-2402	140	9	diffraction	diffraction	PROPN
eurjchem-2402	140	10	and	and	CCONJ
eurjchem-2402	140	11	resulted	result	VERB
eurjchem-2402	140	12	in	in	ADP
eurjchem-2402	140	13	the	the	DET
eurjchem-2402	140	14	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	140	15	complex	complex	NOUN
eurjchem-2402	140	16	(	(	PUNCT
eurjchem-2402	140	17	figure	figure	NOUN
eurjchem-2402	140	18	7	7	NUM
eurjchem-2402	140	19	)	)	PUNCT
eurjchem-2402	140	20	.	.	PUNCT
eurjchem-2402	141	1	we	we	PRON
eurjchem-2402	141	2	highlight	highlight	VERB
eurjchem-2402	141	3	that	that	SCONJ
eurjchem-2402	141	4	in	in	ADP
eurjchem-2402	141	5	the	the	DET
eurjchem-2402	141	6	crystal	crystal	NOUN
eurjchem-2402	141	7	structure	structure	NOUN
eurjchem-2402	141	8	the	the	DET
eurjchem-2402	141	9	metal	metal	NOUN
eurjchem-2402	141	10	center	center	NOUN
eurjchem-2402	141	11	is	be	AUX
eurjchem-2402	141	12	in	in	ADP
eurjchem-2402	141	13	ru3	ru3	NOUN
eurjchem-2402	141	14	+	+	CCONJ
eurjchem-2402	141	15	oxidation	oxidation	ADJ
eurjchem-2402	141	16	state	state	NOUN
eurjchem-2402	141	17	,	,	PUNCT
eurjchem-2402	141	18	thus	thus	ADV
eurjchem-2402	141	19	this	this	PRON
eurjchem-2402	141	20	is	be	AUX
eurjchem-2402	141	21	an	an	DET
eurjchem-2402	141	22	unpublished	unpublished	ADJ
eurjchem-2402	141	23	structure	structure	NOUN
eurjchem-2402	141	24	,	,	PUNCT
eurjchem-2402	141	25	given	give	VERB
eurjchem-2402	141	26	that	that	SCONJ
eurjchem-2402	141	27	in	in	ADP
eurjchem-2402	141	28	the	the	DET
eurjchem-2402	141	29	literature	literature	NOUN
eurjchem-2402	141	30	only	only	ADV
eurjchem-2402	141	31	the	the	DET
eurjchem-2402	141	32	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	141	33	]	]	PUNCT
eurjchem-2402	141	34	was	be	AUX
eurjchem-2402	141	35	reported	report	VERB
eurjchem-2402	141	36	and	and	CCONJ
eurjchem-2402	141	37	the	the	DET
eurjchem-2402	141	38	metal	metal	NOUN
eurjchem-2402	141	39	center	center	NOUN
eurjchem-2402	141	40	is	be	AUX
eurjchem-2402	141	41	ru2	ru2	NOUN
eurjchem-2402	141	42	+	+	PROPN
eurjchem-2402	141	43	.	.	PUNCT
eurjchem-2402	142	1	the	the	DET
eurjchem-2402	142	2	x	x	NOUN
eurjchem-2402	142	3	-	-	NOUN
eurjchem-2402	142	4	ray	ray	NOUN
eurjchem-2402	142	5	crystallographic	crystallographic	ADJ
eurjchem-2402	142	6	studies	study	NOUN
eurjchem-2402	142	7	confirm	confirm	VERB
eurjchem-2402	142	8	the	the	DET
eurjchem-2402	142	9	presence	presence	NOUN
eurjchem-2402	142	10	of	of	ADP
eurjchem-2402	142	11	two	two	NUM
eurjchem-2402	142	12	dppe	dppe	NOUN
eurjchem-2402	142	13	as	as	ADP
eurjchem-2402	142	14	bidentate	bidentate	NOUN
eurjchem-2402	142	15	ligands	ligand	NOUN
eurjchem-2402	142	16	and	and	CCONJ
eurjchem-2402	142	17	two	two	NUM
eurjchem-2402	142	18	chlorido	chlorido	NOUN
eurjchem-2402	142	19	ligands	ligand	NOUN
eurjchem-2402	142	20	in	in	ADP
eurjchem-2402	142	21	a	a	DET
eurjchem-2402	142	22	trans	trans	NOUN
eurjchem-2402	142	23	-	-	NOUN
eurjchem-2402	142	24	configuration	configuration	NOUN
eurjchem-2402	142	25	.	.	PUNCT
eurjchem-2402	143	1	in	in	ADP
eurjchem-2402	143	2	the	the	DET
eurjchem-2402	143	3	structure	structure	NOUN
eurjchem-2402	143	4	,	,	PUNCT
eurjchem-2402	143	5	the	the	DET
eurjchem-2402	143	6	ru	ru	NOUN
eurjchem-2402	143	7	atom	atom	NOUN
eurjchem-2402	143	8	is	be	AUX
eurjchem-2402	143	9	located	locate	VERB
eurjchem-2402	143	10	on	on	ADP
eurjchem-2402	143	11	an	an	DET
eurjchem-2402	143	12	inversion	inversion	NOUN
eurjchem-2402	143	13	centre	centre	NOUN
eurjchem-2402	143	14	;	;	PUNCT
eurjchem-2402	143	15	thus	thus	ADV
eurjchem-2402	143	16	,	,	PUNCT
eurjchem-2402	143	17	a	a	DET
eurjchem-2402	143	18	half	half	ADJ
eurjchem-2402	143	19	-	-	PUNCT
eurjchem-2402	143	20	molecule	molecule	NOUN
eurjchem-2402	143	21	is	be	AUX
eurjchem-2402	143	22	observed	observe	VERB
eurjchem-2402	143	23	in	in	ADP
eurjchem-2402	143	24	the	the	DET
eurjchem-2402	143	25	asymmetric	asymmetric	ADJ
eurjchem-2402	143	26	unit	unit	NOUN
eurjchem-2402	143	27	.	.	PUNCT
eurjchem-2402	144	1	the	the	DET
eurjchem-2402	144	2	complex	complex	ADJ
eurjchem-2402	144	3	presents	present	VERB
eurjchem-2402	144	4	a	a	DET
eurjchem-2402	144	5	slightly	slightly	ADV
eurjchem-2402	144	6	distorted	distorted	ADJ
eurjchem-2402	144	7	octahedral	octahedral	ADJ
eurjchem-2402	144	8	geometry	geometry	NOUN
eurjchem-2402	144	9	,	,	PUNCT
eurjchem-2402	144	10	as	as	SCONJ
eurjchem-2402	144	11	highlighted	highlight	VERB
eurjchem-2402	144	12	by	by	ADP
eurjchem-2402	144	13	the	the	DET
eurjchem-2402	144	14	bond	bond	NOUN
eurjchem-2402	144	15	angles	angle	VERB
eurjchem-2402	144	16	around	around	ADP
eurjchem-2402	144	17	the	the	DET
eurjchem-2402	144	18	metal	metal	NOUN
eurjchem-2402	144	19	centres	centre	NOUN
eurjchem-2402	144	20	(	(	PUNCT
eurjchem-2402	144	21	table	table	NOUN
eurjchem-2402	144	22	2	2	NUM
eurjchem-2402	144	23	)	)	PUNCT
eurjchem-2402	144	24	.	.	PUNCT
eurjchem-2402	145	1	in	in	ADP
eurjchem-2402	145	2	the	the	DET
eurjchem-2402	145	3	complex	complex	ADJ
eurjchem-2402	145	4	structure	structure	NOUN
eurjchem-2402	145	5	,	,	PUNCT
eurjchem-2402	145	6	the	the	DET
eurjchem-2402	145	7	cl1ru1	cl1ru1	NOUN
eurjchem-2402	145	8	-	-	PUNCT
eurjchem-2402	145	9	p1	p1	NOUN
eurjchem-2402	145	10	(	(	PUNCT
eurjchem-2402	145	11	98.53(4)/81.47(4	98.53(4)/81.47(4	NUM
eurjchem-2402	145	12	)	)	PUNCT
eurjchem-2402	145	13	°	°	NUM
eurjchem-2402	145	14	)	)	PUNCT
eurjchem-2402	145	15	and	and	CCONJ
eurjchem-2402	145	16	cl1	cl1	PROPN
eurjchem-2402	145	17	-	-	PUNCT
eurjchem-2402	145	18	ru1	ru1	NOUN
eurjchem-2402	145	19	-	-	PUNCT
eurjchem-2402	145	20	p2	p2	NOUN
eurjchem-2402	145	21	(	(	PUNCT
eurjchem-2402	145	22	91.74(4)/	91.74(4)/	NUM
eurjchem-2402	145	23	88.26(4	88.26(4	NUM
eurjchem-2402	145	24	)	)	PUNCT
eurjchem-2402	145	25	°	°	PROPN
eurjchem-2402	145	26	)	)	PUNCT
eurjchem-2402	145	27	bond	bond	NOUN
eurjchem-2402	145	28	angles	angle	NOUN
eurjchem-2402	145	29	are	be	AUX
eurjchem-2402	145	30	close	close	ADJ
eurjchem-2402	145	31	to	to	PART
eurjchem-2402	145	32	90	90	NUM
eurjchem-2402	145	33	°	°	NOUN
eurjchem-2402	145	34	,	,	PUNCT
eurjchem-2402	145	35	and	and	CCONJ
eurjchem-2402	145	36	the	the	DET
eurjchem-2402	145	37	p1	p1	NOUN
eurjchem-2402	145	38	-	-	PUNCT
eurjchem-2402	145	39	ru1	ru1	NOUN
eurjchem-2402	145	40	-	-	PUNCT
eurjchem-2402	145	41	p2	p2	NOUN
eurjchem-2402	145	42	(	(	PUNCT
eurjchem-2402	145	43	99.03(4)/80.97(4	99.03(4)/80.97(4	NUM
eurjchem-2402	145	44	)	)	PUNCT
eurjchem-2402	145	45	°	°	PROPN
eurjchem-2402	145	46	)	)	PUNCT
eurjchem-2402	145	47	bond	bond	NOUN
eurjchem-2402	145	48	angle	angle	NOUN
eurjchem-2402	145	49	is	be	AUX
eurjchem-2402	145	50	far	far	ADV
eurjchem-2402	145	51	from	from	ADP
eurjchem-2402	145	52	the	the	DET
eurjchem-2402	145	53	expected	expect	VERB
eurjchem-2402	145	54	value	value	NOUN
eurjchem-2402	145	55	of	of	ADP
eurjchem-2402	145	56	90	90	NUM
eurjchem-2402	145	57	°	°	NOUN
eurjchem-2402	145	58	due	due	ADP
eurjchem-2402	145	59	to	to	ADP
eurjchem-2402	145	60	the	the	DET
eurjchem-2402	145	61	tension	tension	NOUN
eurjchem-2402	145	62	of	of	ADP
eurjchem-2402	145	63	the	the	DET
eurjchem-2402	145	64	five	five	NUM
eurjchem-2402	145	65	-	-	PUNCT
eurjchem-2402	145	66	membered	membere	VERB
eurjchem-2402	145	67	chelate	chelate	NOUN
eurjchem-2402	145	68	rings	ring	NOUN
eurjchem-2402	145	69	of	of	ADP
eurjchem-2402	145	70	the	the	DET
eurjchem-2402	145	71	dppe	dppe	PROPN
eurjchem-2402	145	72	ligand	ligand	NOUN
eurjchem-2402	145	73	.	.	PUNCT
eurjchem-2402	146	1	the	the	DET
eurjchem-2402	146	2	cl1	cl1	PROPN
eurjchem-2402	146	3	-	-	PUNCT
eurjchem-2402	146	4	ru1	ru1	PROPN
eurjchem-2402	146	5	-	-	PUNCT
eurjchem-2402	146	6	cl2	cl2	NOUN
eurjchem-2402	146	7	bond	bond	NOUN
eurjchem-2402	146	8	angle	angle	NOUN
eurjchem-2402	146	9	adopting	adopt	VERB
eurjchem-2402	146	10	a	a	DET
eurjchem-2402	146	11	transconfiguration	transconfiguration	NOUN
eurjchem-2402	146	12	is	be	AUX
eurjchem-2402	146	13	180	180	NUM
eurjchem-2402	146	14	°	°	NOUN
eurjchem-2402	146	15	.	.	NOUN
eurjchem-2402	146	16	198	198	NUM
eurjchem-2402	146	17	campideli	campideli	NOUN
eurjchem-2402	146	18	et	et	PROPN
eurjchem-2402	146	19	al	al	PROPN
eurjchem-2402	146	20	.	.	PUNCT
eurjchem-2402	146	21	/	/	SYM
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eurjchem-2402	146	23	journal	journal	PROPN
eurjchem-2402	146	24	of	of	ADP
eurjchem-2402	146	25	chemistry	chemistry	NOUN
eurjchem-2402	146	26	14	14	NUM
eurjchem-2402	146	27	(	(	PUNCT
eurjchem-2402	146	28	2	2	NUM
eurjchem-2402	146	29	)	)	PUNCT
eurjchem-2402	146	30	(	(	PUNCT
eurjchem-2402	146	31	2023	2023	NUM
eurjchem-2402	146	32	)	)	PUNCT
eurjchem-2402	146	33	193	193	NUM
eurjchem-2402	146	34	-	-	SYM
eurjchem-2402	146	35	201	201	NUM
eurjchem-2402	146	36	2023	2023	NUM
eurjchem-2402	146	37	–	–	PUNCT
eurjchem-2402	146	38	european	european	ADJ
eurjchem-2402	146	39	journal	journal	NOUN
eurjchem-2402	146	40	of	of	ADP
eurjchem-2402	146	41	chemistry	chemistry	NOUN
eurjchem-2402	146	42	–	–	PUNCT
eurjchem-2402	146	43	cc	cc	NOUN
eurjchem-2402	146	44	by	by	ADP
eurjchem-2402	146	45	nc	nc	PROPN
eurjchem-2402	146	46	–	–	PUNCT
eurjchem-2402	146	47	doi	doi	NOUN
eurjchem-2402	146	48	:	:	PUNCT
eurjchem-2402	146	49	10.5155	10.5155	NUM
eurjchem-2402	146	50	/	/	SYM
eurjchem-2402	146	51	eurjchem.14.2.193	eurjchem.14.2.193	NUM
eurjchem-2402	146	52	-	-	SYM
eurjchem-2402	146	53	201.2402	201.2402	NUM
eurjchem-2402	146	54	(	(	PUNCT
eurjchem-2402	146	55	a	a	NOUN
eurjchem-2402	146	56	)	)	PUNCT
eurjchem-2402	146	57	(	(	PUNCT
eurjchem-2402	146	58	b	b	X
eurjchem-2402	146	59	)	)	PUNCT
eurjchem-2402	146	60	(	(	PUNCT
eurjchem-2402	146	61	c	c	X
eurjchem-2402	146	62	)	)	PUNCT
eurjchem-2402	146	63	figure	figure	NOUN
eurjchem-2402	146	64	6	6	NUM
eurjchem-2402	146	65	.	.	PUNCT
eurjchem-2402	147	1	(	(	PUNCT
eurjchem-2402	147	2	a	a	X
eurjchem-2402	147	3	)	)	PUNCT
eurjchem-2402	147	4	square	square	ADJ
eurjchem-2402	147	5	wave	wave	NOUN
eurjchem-2402	147	6	voltammograms	voltammogram	NOUN
eurjchem-2402	147	7	obtained	obtain	VERB
eurjchem-2402	147	8	in	in	ADP
eurjchem-2402	147	9	buffer	buffer	NOUN
eurjchem-2402	147	10	tris	tris	NOUN
eurjchem-2402	147	11	-	-	PUNCT
eurjchem-2402	147	12	hcl	hcl	NOUN
eurjchem-2402	147	13	(	(	PUNCT
eurjchem-2402	147	14	ph	ph	NOUN
eurjchem-2402	147	15	=	=	SYM
eurjchem-2402	147	16	7.4)-40	7.4)-40	NOUN
eurjchem-2402	147	17	%	%	NOUN
eurjchem-2402	147	18	(	(	PUNCT
eurjchem-2402	147	19	v	v	NOUN
eurjchem-2402	147	20	/	/	SYM
eurjchem-2402	147	21	v	v	NOUN
eurjchem-2402	147	22	)	)	PUNCT
eurjchem-2402	147	23	dmso	dmso	NOUN
eurjchem-2402	147	24	containing	contain	VERB
eurjchem-2402	147	25	(	(	PUNCT
eurjchem-2402	147	26	i	i	NOUN
eurjchem-2402	147	27	)	)	PUNCT
eurjchem-2402	148	1	[	[	X
eurjchem-2402	148	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	148	3	]	]	X
eurjchem-2402	148	4	100	100	NUM
eurjchem-2402	148	5	µm	µm	NUM
eurjchem-2402	148	6	;	;	PUNCT
eurjchem-2402	148	7	(	(	PUNCT
eurjchem-2402	148	8	ii	ii	NOUN
eurjchem-2402	148	9	)	)	PUNCT
eurjchem-2402	149	1	[	[	X
eurjchem-2402	149	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	149	3	]	]	X
eurjchem-2402	149	4	100	100	NUM
eurjchem-2402	149	5	µm	µm	ADP
eurjchem-2402	149	6	+	+	CCONJ
eurjchem-2402	149	7	dna	dna	PROPN
eurjchem-2402	149	8	15.5	15.5	NUM
eurjchem-2402	149	9	µm	µm	NOUN
eurjchem-2402	149	10	;	;	PUNCT
eurjchem-2402	149	11	(	(	PUNCT
eurjchem-2402	149	12	iii	iii	X
eurjchem-2402	149	13	)	)	PUNCT
eurjchem-2402	150	1	[	[	X
eurjchem-2402	150	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	150	3	]	]	X
eurjchem-2402	150	4	100	100	NUM
eurjchem-2402	150	5	µm	µm	ADP
eurjchem-2402	150	6	+	+	NOUN
eurjchem-2402	151	1	ct	ct	PROPN
eurjchem-2402	152	1	-	-	PUNCT
eurjchem-2402	152	2	dna	dna	PROPN
eurjchem-2402	152	3	30.9	30.9	NUM
eurjchem-2402	152	4	µm	µm	NUM
eurjchem-2402	152	5	;	;	PUNCT
eurjchem-2402	152	6	(	(	PUNCT
eurjchem-2402	152	7	iv	iv	X
eurjchem-2402	152	8	)	)	PUNCT
eurjchem-2402	152	9	cis-[rucl2(dppe)2	cis-[rucl2(dppe)2	PROPN
eurjchem-2402	152	10	]	]	PUNCT
eurjchem-2402	153	1	100	100	NUM
eurjchem-2402	153	2	µm	µm	ADP
eurjchem-2402	153	3	+	+	NOUN
eurjchem-2402	154	1	ct	ct	PROPN
eurjchem-2402	155	1	-	-	PUNCT
eurjchem-2402	155	2	dna	dna	PROPN
eurjchem-2402	155	3	46.2	46.2	NUM
eurjchem-2402	155	4	µm	µm	NOUN
eurjchem-2402	155	5	;	;	PUNCT
eurjchem-2402	155	6	(	(	PUNCT
eurjchem-2402	155	7	v	v	NOUN
eurjchem-2402	155	8	)	)	PUNCT
eurjchem-2402	156	1	[	[	X
eurjchem-2402	156	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	156	3	]	]	X
eurjchem-2402	156	4	100	100	NUM
eurjchem-2402	156	5	µm	µm	ADP
eurjchem-2402	156	6	+	+	NOUN
eurjchem-2402	157	1	ct	ct	PROPN
eurjchem-2402	158	1	-	-	PUNCT
eurjchem-2402	158	2	dna	dna	PROPN
eurjchem-2402	158	3	61.4	61.4	NUM
eurjchem-2402	158	4	µm	µm	NUM
eurjchem-2402	158	5	;	;	PUNCT
eurjchem-2402	158	6	(	(	PUNCT
eurjchem-2402	158	7	vi	vi	NOUN
eurjchem-2402	158	8	)	)	PUNCT
eurjchem-2402	159	1	[	[	X
eurjchem-2402	159	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	159	3	]	]	X
eurjchem-2402	159	4	100	100	NUM
eurjchem-2402	159	5	µm	µm	ADP
eurjchem-2402	159	6	+	+	NOUN
eurjchem-2402	160	1	ct	ct	PROPN
eurjchem-2402	161	1	-	-	PUNCT
eurjchem-2402	161	2	dna	dna	PROPN
eurjchem-2402	161	3	76.5	76.5	NUM
eurjchem-2402	161	4	µm	µm	NUM
eurjchem-2402	161	5	;	;	PUNCT
eurjchem-2402	161	6	(	(	PUNCT
eurjchem-2402	161	7	vii	vii	PROPN
eurjchem-2402	161	8	)	)	PUNCT
eurjchem-2402	162	1	[	[	X
eurjchem-2402	162	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	162	3	]	]	X
eurjchem-2402	162	4	100	100	NUM
eurjchem-2402	162	5	µm	µm	ADP
eurjchem-2402	162	6	+	+	NOUN
eurjchem-2402	163	1	ct	ct	PROPN
eurjchem-2402	164	1	-	-	PUNCT
eurjchem-2402	164	2	dna	dna	PROPN
eurjchem-2402	164	3	91.6	91.6	NUM
eurjchem-2402	164	4	µm	µm	NOUN
eurjchem-2402	164	5	and	and	CCONJ
eurjchem-2402	164	6	(	(	PUNCT
eurjchem-2402	164	7	vii	vii	PROPN
eurjchem-2402	164	8	)	)	PUNCT
eurjchem-2402	165	1	[	[	X
eurjchem-2402	165	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	165	3	]	]	X
eurjchem-2402	165	4	100	100	NUM
eurjchem-2402	165	5	µm	µm	ADP
eurjchem-2402	165	6	+	+	NOUN
eurjchem-2402	166	1	ct	ct	PROPN
eurjchem-2402	167	1	-	-	PUNCT
eurjchem-2402	167	2	dna	dna	PROPN
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eurjchem-2402	167	4	µm	µm	NOUN
eurjchem-2402	167	5	.	.	PUNCT
eurjchem-2402	168	1	parameters	parameters	PROPN
eurjchem-2402	168	2	swv	swv	PROPN
eurjchem-2402	168	3	:	:	PUNCT
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eurjchem-2402	168	5	(	(	PUNCT
eurjchem-2402	168	6	f	f	X
eurjchem-2402	168	7	)	)	PUNCT
eurjchem-2402	168	8	=	=	SYM
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eurjchem-2402	168	10	hz	hz	ADJ
eurjchem-2402	168	11	,	,	PUNCT
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eurjchem-2402	168	13	(	(	PUNCT
eurjchem-2402	168	14	a	a	X
eurjchem-2402	168	15	)	)	PUNCT
eurjchem-2402	168	16	=	=	SYM
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eurjchem-2402	168	19	,	,	PUNCT
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eurjchem-2402	168	23	(	(	PUNCT
eurjchem-2402	168	24	δes	δes	ADJ
eurjchem-2402	168	25	)	)	PUNCT
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eurjchem-2402	168	29	.	.	PUNCT
eurjchem-2402	168	30	(	(	PUNCT
eurjchem-2402	168	31	b	b	X
eurjchem-2402	168	32	)	)	PUNCT
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eurjchem-2402	168	35	peak	peak	NOUN
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eurjchem-2402	168	40	-	-	PUNCT
eurjchem-2402	168	41	dna	dna	PROPN
eurjchem-2402	168	42	(	(	PUNCT
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eurjchem-2402	168	45	[	[	X
eurjchem-2402	168	46	ct	ct	PROPN
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eurjchem-2402	168	50	)	)	PUNCT
eurjchem-2402	168	51	and	and	CCONJ
eurjchem-2402	168	52	(	(	PUNCT
eurjchem-2402	168	53	c	c	NOUN
eurjchem-2402	168	54	)	)	PUNCT
eurjchem-2402	168	55	peak	peak	NOUN
eurjchem-2402	168	56	current	current	ADJ
eurjchem-2402	168	57	versus	versus	ADP
eurjchem-2402	168	58	concentration	concentration	NOUN
eurjchem-2402	168	59	ct	ct	PROPN
eurjchem-2402	168	60	-	-	PUNCT
eurjchem-2402	168	61	dna	dna	PROPN
eurjchem-2402	168	62	(	(	PUNCT
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eurjchem-2402	168	65	[	[	X
eurjchem-2402	168	66	ct	ct	PROPN
eurjchem-2402	168	67	-	-	NOUN
eurjchem-2402	168	68	dna	dna	NOUN
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eurjchem-2402	168	70	)	)	PUNCT
eurjchem-2402	168	71	.	.	PUNCT
eurjchem-2402	169	1	figure	figure	VERB
eurjchem-2402	169	2	7	7	NUM
eurjchem-2402	169	3	.	.	PUNCT
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eurjchem-2402	170	2	structure	structure	NOUN
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eurjchem-2402	170	4	[	[	PUNCT
eurjchem-2402	170	5	rucl2(dppe)2]cl	rucl2(dppe)2]cl	PROPN
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eurjchem-2402	170	7	ellipsoids	ellipsoid	NOUN
eurjchem-2402	170	8	drawn	draw	VERB
eurjchem-2402	170	9	at	at	ADP
eurjchem-2402	170	10	30	30	NUM
eurjchem-2402	170	11	%	%	NOUN
eurjchem-2402	170	12	probability	probability	NOUN
eurjchem-2402	170	13	.	.	PUNCT
eurjchem-2402	171	1	furthermore	furthermore	ADV
eurjchem-2402	171	2	,	,	PUNCT
eurjchem-2402	171	3	it	it	PRON
eurjchem-2402	171	4	is	be	AUX
eurjchem-2402	171	5	observed	observe	VERB
eurjchem-2402	171	6	that	that	SCONJ
eurjchem-2402	171	7	the	the	DET
eurjchem-2402	171	8	bond	bond	NOUN
eurjchem-2402	171	9	lengths	length	NOUN
eurjchem-2402	171	10	of	of	ADP
eurjchem-2402	171	11	ru	ru	NOUN
eurjchem-2402	171	12	-	-	PUNCT
eurjchem-2402	171	13	p	p	NOUN
eurjchem-2402	171	14	and	and	CCONJ
eurjchem-2402	171	15	ru	ru	NOUN
eurjchem-2402	171	16	-	-	NOUN
eurjchem-2402	171	17	cl	cl	NOUN
eurjchem-2402	171	18	are	be	AUX
eurjchem-2402	171	19	in	in	ADP
eurjchem-2402	171	20	agreement	agreement	NOUN
eurjchem-2402	171	21	with	with	ADP
eurjchem-2402	171	22	the	the	DET
eurjchem-2402	171	23	values	value	NOUN
eurjchem-2402	171	24	reported	report	VERB
eurjchem-2402	171	25	for	for	ADP
eurjchem-2402	171	26	ru(iii	ru(iii	NOUN
eurjchem-2402	171	27	)	)	PUNCT
eurjchem-2402	171	28	complexes	complex	NOUN
eurjchem-2402	172	1	[	[	X
eurjchem-2402	172	2	33,34	33,34	NOUN
eurjchem-2402	172	3	]	]	PUNCT
eurjchem-2402	172	4	.	.	PUNCT
eurjchem-2402	173	1	in	in	ADP
eurjchem-2402	173	2	the	the	DET
eurjchem-2402	173	3	literature	literature	NOUN
eurjchem-2402	173	4	,	,	PUNCT
eurjchem-2402	173	5	four	four	NUM
eurjchem-2402	173	6	crystal	crystal	NOUN
eurjchem-2402	173	7	structures	structure	NOUN
eurjchem-2402	173	8	containing	contain	VERB
eurjchem-2402	173	9	the	the	DET
eurjchem-2402	173	10	complex	complex	ADJ
eurjchem-2402	173	11	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	173	12	]	]	PUNCT
eurjchem-2402	173	13	were	be	AUX
eurjchem-2402	173	14	reported	report	VERB
eurjchem-2402	173	15	.	.	PUNCT
eurjchem-2402	174	1	a	a	DET
eurjchem-2402	174	2	solvent	solvent	NOUN
eurjchem-2402	174	3	-	-	PUNCT
eurjchem-2402	174	4	free	free	ADJ
eurjchem-2402	174	5	structure	structure	NOUN
eurjchem-2402	174	6	of	of	ADP
eurjchem-2402	174	7	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	174	8	]	]	PUNCT
eurjchem-2402	175	1	[	[	X
eurjchem-2402	175	2	35	35	NUM
eurjchem-2402	175	3	]	]	PUNCT
eurjchem-2402	175	4	and	and	CCONJ
eurjchem-2402	175	5	three	three	NUM
eurjchem-2402	175	6	other	other	ADJ
eurjchem-2402	175	7	crystalline	crystalline	NOUN
eurjchem-2402	175	8	forms	form	NOUN
eurjchem-2402	175	9	containing	contain	VERB
eurjchem-2402	175	10	one	one	NUM
eurjchem-2402	175	11	dichloromethane	dichloromethane	NOUN
eurjchem-2402	175	12	solvate	solvate	NOUN
eurjchem-2402	176	1	[	[	X
eurjchem-2402	176	2	36	36	NUM
eurjchem-2402	176	3	]	]	PUNCT
eurjchem-2402	176	4	,	,	PUNCT
eurjchem-2402	176	5	one	one	NUM
eurjchem-2402	176	6	chloroform	chloroform	NOUN
eurjchem-2402	176	7	solvate	solvate	NOUN
eurjchem-2402	176	8	,	,	PUNCT
eurjchem-2402	176	9	and	and	CCONJ
eurjchem-2402	176	10	one	one	NUM
eurjchem-2402	176	11	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-2402	176	12	solvate	solvate	NOUN
eurjchem-2402	177	1	[	[	X
eurjchem-2402	177	2	37	37	NUM
eurjchem-2402	177	3	]	]	PUNCT
eurjchem-2402	177	4	.	.	PUNCT
eurjchem-2402	178	1	when	when	SCONJ
eurjchem-2402	178	2	the	the	DET
eurjchem-2402	178	3	structure	structure	NOUN
eurjchem-2402	178	4	of	of	ADP
eurjchem-2402	178	5	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	178	6	is	be	AUX
eurjchem-2402	178	7	compared	compare	VERB
eurjchem-2402	178	8	with	with	ADP
eurjchem-2402	178	9	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	178	10	]	]	PUNCT
eurjchem-2402	179	1	[	[	X
eurjchem-2402	179	2	36	36	NUM
eurjchem-2402	179	3	]	]	X
eurjchem-2402	179	4	,	,	PUNCT
eurjchem-2402	179	5	many	many	ADJ
eurjchem-2402	179	6	differences	difference	NOUN
eurjchem-2402	179	7	can	can	AUX
eurjchem-2402	179	8	be	be	AUX
eurjchem-2402	179	9	observed	observe	VERB
eurjchem-2402	179	10	.	.	PUNCT
eurjchem-2402	180	1	in	in	ADP
eurjchem-2402	180	2	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	180	3	the	the	DET
eurjchem-2402	180	4	ru	ru	NOUN
eurjchem-2402	180	5	-	-	PUNCT
eurjchem-2402	180	6	cl	cl	NOUN
eurjchem-2402	180	7	distance	distance	NOUN
eurjchem-2402	180	8	is	be	AUX
eurjchem-2402	180	9	2.3310(12	2.3310(12	NUM
eurjchem-2402	180	10	)	)	PUNCT
eurjchem-2402	180	11	å	å	NOUN
eurjchem-2402	180	12	,	,	PUNCT
eurjchem-2402	180	13	while	while	SCONJ
eurjchem-2402	180	14	the	the	DET
eurjchem-2402	180	15	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	180	16	]	]	PUNCT
eurjchem-2402	180	17	is	be	AUX
eurjchem-2402	180	18	slightly	slightly	ADV
eurjchem-2402	180	19	larger	large	ADJ
eurjchem-2402	181	1	[	[	X
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eurjchem-2402	181	3	)	)	PUNCT
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eurjchem-2402	181	5	]	]	X
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eurjchem-2402	181	10	for	for	ADP
eurjchem-2402	181	11	a	a	DET
eurjchem-2402	181	12	low	low	ADV
eurjchem-2402	181	13	-	-	PUNCT
eurjchem-2402	181	14	charged	charge	VERB
eurjchem-2402	181	15	metal	metal	NOUN
eurjchem-2402	181	16	.	.	PUNCT
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eurjchem-2402	182	2	the	the	DET
eurjchem-2402	182	3	other	other	ADJ
eurjchem-2402	182	4	hand	hand	NOUN
eurjchem-2402	182	5	,	,	PUNCT
eurjchem-2402	182	6	the	the	DET
eurjchem-2402	182	7	ruii	ruii	NOUN
eurjchem-2402	182	8	-	-	PUNCT
eurjchem-2402	182	9	p	p	NOUN
eurjchem-2402	182	10	bond	bond	NOUN
eurjchem-2402	182	11	distance	distance	NOUN
eurjchem-2402	182	12	for	for	ADP
eurjchem-2402	182	13	[	[	X
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eurjchem-2402	182	15	]	]	X
eurjchem-2402	182	16	is	be	AUX
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eurjchem-2402	182	18	)	)	PUNCT
eurjchem-2402	182	19	å	å	PROPN
eurjchem-2402	183	1	[	[	X
eurjchem-2402	183	2	36	36	NUM
eurjchem-2402	183	3	]	]	PUNCT
eurjchem-2402	183	4	and	and	CCONJ
eurjchem-2402	183	5	2.3811(13	2.3811(13	NUM
eurjchem-2402	183	6	)	)	PUNCT
eurjchem-2402	183	7	å	å	NOUN
eurjchem-2402	183	8	[	[	X
eurjchem-2402	183	9	37	37	NUM
eurjchem-2402	183	10	]	]	PUNCT
eurjchem-2402	183	11	,	,	PUNCT
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eurjchem-2402	183	14	the	the	DET
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eurjchem-2402	183	16	reported	report	VERB
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eurjchem-2402	183	18	,	,	PUNCT
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eurjchem-2402	183	21	-	-	ADJ
eurjchem-2402	183	22	p	p	ADJ
eurjchem-2402	183	23	bond	bond	NOUN
eurjchem-2402	183	24	distance	distance	NOUN
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eurjchem-2402	183	26	also	also	ADV
eurjchem-2402	183	27	slightly	slightly	ADV
eurjchem-2402	183	28	larger	large	ADJ
eurjchem-2402	183	29	[	[	X
eurjchem-2402	183	30	ru1	ru1	ADJ
eurjchem-2402	183	31	-	-	ADJ
eurjchem-2402	183	32	p1	p1	NOUN
eurjchem-2402	183	33	=	=	PUNCT
eurjchem-2402	183	34	2.4587(11	2.4587(11	NUM
eurjchem-2402	183	35	)	)	PUNCT
eurjchem-2402	183	36	and	and	CCONJ
eurjchem-2402	183	37	ru1	ru1	NOUN
eurjchem-2402	183	38	-	-	NOUN
eurjchem-2402	183	39	p2	p2	NOUN
eurjchem-2402	183	40	=	=	SYM
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eurjchem-2402	183	42	)	)	PUNCT
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eurjchem-2402	183	52	,	,	PUNCT
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eurjchem-2402	183	54	the	the	DET
eurjchem-2402	183	55	ru(iii	ru(iii	NOUN
eurjchem-2402	183	56	)	)	PUNCT
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eurjchem-2402	183	58	,	,	PUNCT
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eurjchem-2402	183	60	ru	ru	NOUN
eurjchem-2402	183	61	-	-	PUNCT
eurjchem-2402	183	62	ligand	ligand	ADJ
eurjchem-2402	183	63	back	back	ADJ
eurjchem-2402	183	64	-	-	PUNCT
eurjchem-2402	183	65	donation	donation	NOUN
eurjchem-2402	183	66	decreases	decrease	NOUN
eurjchem-2402	183	67	,	,	PUNCT
eurjchem-2402	183	68	thus	thus	ADV
eurjchem-2402	183	69	,	,	PUNCT
eurjchem-2402	183	70	ru	ru	PROPN
eurjchem-2402	183	71	-	-	ADJ
eurjchem-2402	183	72	p	p	NOUN
eurjchem-2402	183	73	bond	bond	NOUN
eurjchem-2402	183	74	is	be	AUX
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eurjchem-2402	183	77	.	.	PUNCT
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eurjchem-2402	184	2	et	et	PROPN
eurjchem-2402	184	3	al	al	PROPN
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eurjchem-2402	184	5	/	/	SYM
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eurjchem-2402	184	11	(	(	PUNCT
eurjchem-2402	184	12	2	2	NUM
eurjchem-2402	184	13	)	)	PUNCT
eurjchem-2402	184	14	(	(	PUNCT
eurjchem-2402	184	15	2023	2023	NUM
eurjchem-2402	184	16	)	)	PUNCT
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eurjchem-2402	184	18	-	-	SYM
eurjchem-2402	184	19	201	201	NUM
eurjchem-2402	184	20	199	199	NUM
eurjchem-2402	184	21	2023	2023	NUM
eurjchem-2402	184	22	–	–	PUNCT
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eurjchem-2402	184	24	journal	journal	NOUN
eurjchem-2402	184	25	of	of	ADP
eurjchem-2402	184	26	chemistry	chemistry	NOUN
eurjchem-2402	184	27	–	–	PUNCT
eurjchem-2402	184	28	cc	cc	NOUN
eurjchem-2402	184	29	by	by	ADP
eurjchem-2402	184	30	nc	nc	PROPN
eurjchem-2402	184	31	–	–	PUNCT
eurjchem-2402	184	32	doi	doi	NOUN
eurjchem-2402	184	33	:	:	PUNCT
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eurjchem-2402	184	35	/	/	SYM
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eurjchem-2402	184	37	-	-	SYM
eurjchem-2402	184	38	201.2402	201.2402	NUM
eurjchem-2402	184	39	table	table	NOUN
eurjchem-2402	184	40	2	2	NUM
eurjchem-2402	184	41	.	.	PUNCT
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eurjchem-2402	185	2	lengths	length	NOUN
eurjchem-2402	185	3	and	and	CCONJ
eurjchem-2402	185	4	angles	angle	NOUN
eurjchem-2402	185	5	for	for	ADP
eurjchem-2402	185	6	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	185	7	*	*	PUNCT
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eurjchem-2402	186	2	lengths	length	NOUN
eurjchem-2402	186	3	atom	atom	NOUN
eurjchem-2402	186	4	atom	atom	NOUN
eurjchem-2402	186	5	length	length	NOUN
eurjchem-2402	186	6	(	(	PUNCT
eurjchem-2402	186	7	å	å	NOUN
eurjchem-2402	186	8	)	)	PUNCT
eurjchem-2402	186	9	atom	atom	NOUN
eurjchem-2402	186	10	atom	atom	NOUN
eurjchem-2402	186	11	length	length	NOUN
eurjchem-2402	186	12	(	(	PUNCT
eurjchem-2402	186	13	å	å	NOUN
eurjchem-2402	186	14	)	)	PUNCT
eurjchem-2402	186	15	ru1	ru1	PROPN
eurjchem-2402	186	16	p21	p21	PROPN
eurjchem-2402	186	17	2.4374(11	2.4374(11	NUM
eurjchem-2402	186	18	)	)	PUNCT
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eurjchem-2402	187	2	c213	c213	NUM
eurjchem-2402	187	3	1.390(6	1.390(6	NUM
eurjchem-2402	187	4	)	)	PUNCT
eurjchem-2402	187	5	ru1	ru1	PROPN
eurjchem-2402	187	6	p2	p2	PROPN
eurjchem-2402	187	7	2.4374(11	2.4374(11	NUM
eurjchem-2402	187	8	)	)	PUNCT
eurjchem-2402	188	1	c111	c111	PROPN
eurjchem-2402	188	2	c116	c116	NUM
eurjchem-2402	188	3	1.386(6	1.386(6	NUM
eurjchem-2402	188	4	)	)	PUNCT
eurjchem-2402	188	5	ru1	ru1	PROPN
eurjchem-2402	188	6	p11	p11	NOUN
eurjchem-2402	188	7	2.4586(11	2.4586(11	NUM
eurjchem-2402	188	8	)	)	PUNCT
eurjchem-2402	189	1	c111	c111	PROPN
eurjchem-2402	189	2	c112	c112	PROPN
eurjchem-2402	189	3	1.398(6	1.398(6	NUM
eurjchem-2402	189	4	)	)	PUNCT
eurjchem-2402	189	5	ru1	ru1	PROPN
eurjchem-2402	189	6	p1	p1	NOUN
eurjchem-2402	189	7	2.4587(11	2.4587(11	NUM
eurjchem-2402	189	8	)	)	PUNCT
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eurjchem-2402	191	1	c125	c125	PROPN
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eurjchem-2402	191	3	)	)	PUNCT
eurjchem-2402	191	4	ru1	ru1	PROPN
eurjchem-2402	191	5	cl1	cl1	NOUN
eurjchem-2402	191	6	2.3310(12	2.3310(12	NUM
eurjchem-2402	191	7	)	)	PUNCT
eurjchem-2402	192	1	c124	c124	PROPN
eurjchem-2402	193	1	c125	c125	PROPN
eurjchem-2402	193	2	1.369(7	1.369(7	NUM
eurjchem-2402	193	3	)	)	PUNCT
eurjchem-2402	193	4	ru1	ru1	PROPN
eurjchem-2402	193	5	cl11	cl11	PROPN
eurjchem-2402	193	6	2.3310(12	2.3310(12	NUM
eurjchem-2402	193	7	)	)	PUNCT
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eurjchem-2402	194	1	c123	c123	PROPN
eurjchem-2402	194	2	1.367(6	1.367(6	NUM
eurjchem-2402	194	3	)	)	PUNCT
eurjchem-2402	194	4	p2	p2	VERB
eurjchem-2402	194	5	c211	c211	PROPN
eurjchem-2402	194	6	1.825(4	1.825(4	NUM
eurjchem-2402	194	7	)	)	PUNCT
eurjchem-2402	194	8	c122	c122	PROPN
eurjchem-2402	194	9	c123	c123	PROPN
eurjchem-2402	194	10	1.389(6	1.389(6	NUM
eurjchem-2402	194	11	)	)	PUNCT
eurjchem-2402	194	12	p2	p2	PROPN
eurjchem-2402	194	13	c221	c221	PROPN
eurjchem-2402	194	14	1.823(4	1.823(4	NUM
eurjchem-2402	194	15	)	)	PUNCT
eurjchem-2402	194	16	c226	c226	PROPN
eurjchem-2402	195	1	c225	c225	PROPN
eurjchem-2402	195	2	1.383(6	1.383(6	NUM
eurjchem-2402	195	3	)	)	PUNCT
eurjchem-2402	195	4	p2	p2	PROPN
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eurjchem-2402	195	7	)	)	PUNCT
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eurjchem-2402	196	1	c115	c115	PROPN
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eurjchem-2402	196	3	)	)	PUNCT
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eurjchem-2402	196	7	)	)	PUNCT
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eurjchem-2402	197	1	c214	c214	PROPN
eurjchem-2402	197	2	1.357(7	1.357(7	NUM
eurjchem-2402	197	3	)	)	PUNCT
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eurjchem-2402	197	7	)	)	PUNCT
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eurjchem-2402	198	2	1.383(6	1.383(6	NUM
eurjchem-2402	198	3	)	)	PUNCT
eurjchem-2402	198	4	p1	p1	NOUN
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eurjchem-2402	198	7	)	)	PUNCT
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eurjchem-2402	198	11	)	)	PUNCT
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eurjchem-2402	199	3	)	)	PUNCT
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eurjchem-2402	200	2	c214	c214	PROPN
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eurjchem-2402	200	4	)	)	PUNCT
eurjchem-2402	200	5	c211	c211	PROPN
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eurjchem-2402	201	3	)	)	PUNCT
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eurjchem-2402	201	5	c115	c115	PROPN
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eurjchem-2402	201	7	)	)	PUNCT
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eurjchem-2402	201	11	)	)	PUNCT
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eurjchem-2402	201	15	)	)	PUNCT
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eurjchem-2402	201	17	c222	c222	PROPN
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eurjchem-2402	201	19	)	)	PUNCT
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eurjchem-2402	202	3	)	)	PUNCT
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eurjchem-2402	204	3	)	)	PUNCT
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eurjchem-2402	205	2	c224	c224	PROPN
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eurjchem-2402	205	4	)	)	PUNCT
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eurjchem-2402	206	4	)	)	PUNCT
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eurjchem-2402	208	18	(	(	PUNCT
eurjchem-2402	208	19	°	°	PROPN
eurjchem-2402	208	20	)	)	PUNCT
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eurjchem-2402	208	22	ru1	ru1	PROPN
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eurjchem-2402	208	29	)	)	PUNCT
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eurjchem-2402	208	31	ru1	ru1	PROPN
eurjchem-2402	208	32	p1	p1	PROPN
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eurjchem-2402	208	34	)	)	PUNCT
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eurjchem-2402	208	36	c221	c221	PROPN
eurjchem-2402	208	37	p2	p2	PROPN
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eurjchem-2402	208	39	)	)	PUNCT
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eurjchem-2402	208	41	ru1	ru1	PROPN
eurjchem-2402	208	42	p1	p1	NOUN
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eurjchem-2402	210	2	p2	p2	X
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eurjchem-2402	210	4	)	)	PUNCT
eurjchem-2402	210	5	p2	p2	VERB
eurjchem-2402	210	6	ru1	ru1	PROPN
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eurjchem-2402	210	8	99.03(4	99.03(4	NUM
eurjchem-2402	210	9	)	)	PUNCT
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eurjchem-2402	212	2	p1	p1	NOUN
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eurjchem-2402	212	4	)	)	PUNCT
eurjchem-2402	212	5	p21	p21	NOUN
eurjchem-2402	212	6	ru1	ru1	PROPN
eurjchem-2402	212	7	p11	p11	NOUN
eurjchem-2402	212	8	80.97(4	80.97(4	NUM
eurjchem-2402	212	9	)	)	PUNCT
eurjchem-2402	213	1	c126	c126	NOUN
eurjchem-2402	214	1	c121	c121	NUM
eurjchem-2402	214	2	c122	c122	NUM
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eurjchem-2402	214	4	)	)	PUNCT
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eurjchem-2402	214	6	ru1	ru1	PROPN
eurjchem-2402	214	7	p1	p1	NOUN
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eurjchem-2402	214	10	c121	c121	PROPN
eurjchem-2402	214	11	p1	p1	PROPN
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eurjchem-2402	214	13	)	)	PUNCT
eurjchem-2402	214	14	cl1	cl1	PROPN
eurjchem-2402	214	15	ru1	ru1	PROPN
eurjchem-2402	214	16	p21	p21	PROPN
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eurjchem-2402	214	18	)	)	PUNCT
eurjchem-2402	215	1	c211	c211	X
eurjchem-2402	216	1	c212	c212	PROPN
eurjchem-2402	216	2	c213	c213	SYM
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eurjchem-2402	216	4	)	)	PUNCT
eurjchem-2402	217	1	cl11	cl11	PROPN
eurjchem-2402	217	2	ru1	ru1	PROPN
eurjchem-2402	217	3	p2	p2	PROPN
eurjchem-2402	217	4	91.74(4	91.74(4	NOUN
eurjchem-2402	217	5	)	)	PUNCT
eurjchem-2402	218	1	c116	c116	PROPN
eurjchem-2402	219	1	c111	c111	ADJ
eurjchem-2402	219	2	p1	p1	PROPN
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eurjchem-2402	219	4	)	)	PUNCT
eurjchem-2402	219	5	cl1	cl1	NOUN
eurjchem-2402	219	6	ru1	ru1	PROPN
eurjchem-2402	219	7	p2	p2	PROPN
eurjchem-2402	219	8	88.26(4	88.26(4	NUM
eurjchem-2402	219	9	)	)	PUNCT
eurjchem-2402	219	10	c116	c116	PROPN
eurjchem-2402	220	1	c111	c111	ADJ
eurjchem-2402	220	2	c112	c112	PROPN
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eurjchem-2402	220	4	)	)	PUNCT
eurjchem-2402	221	1	cl11	cl11	PROPN
eurjchem-2402	221	2	ru1	ru1	PROPN
eurjchem-2402	221	3	p21	p21	PROPN
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eurjchem-2402	221	5	)	)	PUNCT
eurjchem-2402	222	1	c112	c112	PUNCT
eurjchem-2402	223	1	c111	c111	ADJ
eurjchem-2402	223	2	p1	p1	NOUN
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eurjchem-2402	223	4	)	)	PUNCT
eurjchem-2402	224	1	cl11	cl11	PROPN
eurjchem-2402	224	2	ru1	ru1	PROPN
eurjchem-2402	224	3	p11	p11	NOUN
eurjchem-2402	224	4	81.47(4	81.47(4	NOUN
eurjchem-2402	224	5	)	)	PUNCT
eurjchem-2402	225	1	c231	c231	PROPN
eurjchem-2402	225	2	c131	c131	PROPN
eurjchem-2402	225	3	p1	p1	NOUN
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eurjchem-2402	225	5	)	)	PUNCT
eurjchem-2402	225	6	cl1	cl1	NOUN
eurjchem-2402	225	7	ru1	ru1	PROPN
eurjchem-2402	225	8	p11	p11	NOUN
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eurjchem-2402	225	10	)	)	PUNCT
eurjchem-2402	226	1	c121	c121	PROPN
eurjchem-2402	226	2	c126	c126	PROPN
eurjchem-2402	227	1	c125	c125	PROPN
eurjchem-2402	227	2	120.2(4	120.2(4	X
eurjchem-2402	227	3	)	)	PUNCT
eurjchem-2402	227	4	cl1	cl1	PROPN
eurjchem-2402	227	5	ru1	ru1	PROPN
eurjchem-2402	227	6	p1	p1	PROPN
eurjchem-2402	227	7	81.47(4	81.47(4	NOUN
eurjchem-2402	227	8	)	)	PUNCT
eurjchem-2402	228	1	c123	c123	PROPN
eurjchem-2402	228	2	c124	c124	PROPN
eurjchem-2402	229	1	c125	c125	NUM
eurjchem-2402	229	2	120.4(4	120.4(4	NUM
eurjchem-2402	229	3	)	)	PUNCT
eurjchem-2402	230	1	cl11	cl11	PROPN
eurjchem-2402	230	2	ru1	ru1	PROPN
eurjchem-2402	230	3	p1	p1	PROPN
eurjchem-2402	230	4	98.53(4	98.53(4	NOUN
eurjchem-2402	230	5	)	)	PUNCT
eurjchem-2402	231	1	c121	c121	PRON
eurjchem-2402	232	1	c122	c122	NUM
eurjchem-2402	232	2	c123	c123	PROPN
eurjchem-2402	232	3	120.5(4	120.5(4	NUM
eurjchem-2402	232	4	)	)	PUNCT
eurjchem-2402	233	1	cl11	cl11	PROPN
eurjchem-2402	233	2	ru1	ru1	PROPN
eurjchem-2402	233	3	cl1	cl1	NOUN
eurjchem-2402	233	4	180.0	180.0	NUM
eurjchem-2402	233	5	c225	c225	PROPN
eurjchem-2402	233	6	c226	c226	PROPN
eurjchem-2402	233	7	c221	c221	PROPN
eurjchem-2402	233	8	121.3(5	121.3(5	NUM
eurjchem-2402	233	9	)	)	PUNCT
eurjchem-2402	233	10	c211	c211	PROPN
eurjchem-2402	233	11	p2	p2	VERB
eurjchem-2402	233	12	ru1	ru1	NOUN
eurjchem-2402	233	13	118.35(13	118.35(13	NUM
eurjchem-2402	233	14	)	)	PUNCT
eurjchem-2402	233	15	c115	c115	PROPN
eurjchem-2402	234	1	c116	c116	PROPN
eurjchem-2402	235	1	c111	c111	PROPN
eurjchem-2402	235	2	121.5(4	121.5(4	NOUN
eurjchem-2402	235	3	)	)	PUNCT
eurjchem-2402	235	4	c211	c211	PROPN
eurjchem-2402	235	5	p2	p2	X
eurjchem-2402	235	6	c231	c231	PROPN
eurjchem-2402	235	7	103.6(2	103.6(2	ADV
eurjchem-2402	235	8	)	)	PUNCT
eurjchem-2402	235	9	c124	c124	PROPN
eurjchem-2402	236	1	c125	c125	PROPN
eurjchem-2402	236	2	c126	c126	NUM
eurjchem-2402	236	3	119.9(4	119.9(4	NUM
eurjchem-2402	236	4	)	)	PUNCT
eurjchem-2402	236	5	c221	c221	PROPN
eurjchem-2402	236	6	p2	p2	PROPN
eurjchem-2402	236	7	ru1	ru1	PROPN
eurjchem-2402	236	8	118.74(15	118.74(15	NUM
eurjchem-2402	236	9	)	)	PUNCT
eurjchem-2402	236	10	c124	c124	PROPN
eurjchem-2402	237	1	c123	c123	PROPN
eurjchem-2402	238	1	c122	c122	NUM
eurjchem-2402	238	2	119.9(5	119.9(5	X
eurjchem-2402	238	3	)	)	PUNCT
eurjchem-2402	238	4	c221	c221	PROPN
eurjchem-2402	238	5	p2	p2	PROPN
eurjchem-2402	238	6	c211	c211	PROPN
eurjchem-2402	238	7	102.89(19	102.89(19	NOUN
eurjchem-2402	238	8	)	)	PUNCT
eurjchem-2402	239	1	c214	c214	PROPN
eurjchem-2402	239	2	c213	c213	NUM
eurjchem-2402	240	1	c212	c212	PROPN
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eurjchem-2402	240	3	)	)	PUNCT
eurjchem-2402	240	4	c221	c221	PROPN
eurjchem-2402	240	5	p2	p2	PROPN
eurjchem-2402	240	6	c231	c231	PROPN
eurjchem-2402	240	7	103.56(18	103.56(18	NUM
eurjchem-2402	240	8	)	)	PUNCT
eurjchem-2402	240	9	c215	c215	PROPN
eurjchem-2402	241	1	c216	c216	NUM
eurjchem-2402	241	2	c211	c211	NUM
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eurjchem-2402	241	4	)	)	PUNCT
eurjchem-2402	242	1	c231	c231	PROPN
eurjchem-2402	242	2	p2	p2	VERB
eurjchem-2402	242	3	ru1	ru1	PROPN
eurjchem-2402	242	4	107.79(13	107.79(13	NUM
eurjchem-2402	242	5	)	)	PUNCT
eurjchem-2402	243	1	c113	c113	PROPN
eurjchem-2402	243	2	c112	c112	PUNCT
eurjchem-2402	244	1	c111	c111	ADJ
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eurjchem-2402	244	3	)	)	PUNCT
eurjchem-2402	244	4	c121	c121	PROPN
eurjchem-2402	244	5	p1	p1	NOUN
eurjchem-2402	244	6	ru1	ru1	NOUN
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eurjchem-2402	244	8	)	)	PUNCT
eurjchem-2402	244	9	c216	c216	NUM
eurjchem-2402	245	1	c215	c215	PROPN
eurjchem-2402	245	2	c214	c214	PROPN
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eurjchem-2402	245	4	)	)	PUNCT
eurjchem-2402	245	5	c111	c111	PROPN
eurjchem-2402	245	6	p1	p1	NOUN
eurjchem-2402	245	7	ru1	ru1	PROPN
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eurjchem-2402	245	9	)	)	PUNCT
eurjchem-2402	245	10	c113	c113	PROPN
eurjchem-2402	245	11	c114	c114	PROPN
eurjchem-2402	245	12	c115	c115	PROPN
eurjchem-2402	245	13	120.0(4	120.0(4	NUM
eurjchem-2402	245	14	)	)	PUNCT
eurjchem-2402	245	15	c111	c111	PROPN
eurjchem-2402	245	16	p1	p1	NOUN
eurjchem-2402	245	17	c121	c121	PROPN
eurjchem-2402	245	18	102.02(18	102.02(18	NUM
eurjchem-2402	245	19	)	)	PUNCT
eurjchem-2402	246	1	c114	c114	PROPN
eurjchem-2402	247	1	c115	c115	PROPN
eurjchem-2402	247	2	c116	c116	PROPN
eurjchem-2402	247	3	119.5(5	119.5(5	NUM
eurjchem-2402	247	4	)	)	PUNCT
eurjchem-2402	247	5	c111	c111	PROPN
eurjchem-2402	247	6	p1	p1	NOUN
eurjchem-2402	247	7	c131	c131	PROPN
eurjchem-2402	247	8	107.09(19	107.09(19	NUM
eurjchem-2402	247	9	)	)	PUNCT
eurjchem-2402	248	1	c224	c224	PROPN
eurjchem-2402	249	1	c225	c225	PROPN
eurjchem-2402	250	1	c226	c226	PROPN
eurjchem-2402	250	2	119.5(5	119.5(5	NUM
eurjchem-2402	250	3	)	)	PUNCT
eurjchem-2402	251	1	c131	c131	PROPN
eurjchem-2402	251	2	p1	p1	PROPN
eurjchem-2402	251	3	ru1	ru1	PROPN
eurjchem-2402	251	4	103.19(14	103.19(14	NOUN
eurjchem-2402	251	5	)	)	PUNCT
eurjchem-2402	252	1	c224	c224	PROPN
eurjchem-2402	253	1	c223	c223	PROPN
eurjchem-2402	253	2	c222	c222	PROPN
eurjchem-2402	253	3	120.5(5	120.5(5	NUM
eurjchem-2402	253	4	)	)	PUNCT
eurjchem-2402	254	1	c131	c131	PROPN
eurjchem-2402	254	2	p1	p1	NOUN
eurjchem-2402	254	3	c121	c121	NUM
eurjchem-2402	254	4	99.5(2	99.5(2	NOUN
eurjchem-2402	254	5	)	)	PUNCT
eurjchem-2402	254	6	c225	c225	PROPN
eurjchem-2402	255	1	c224	c224	PROPN
eurjchem-2402	256	1	c223	c223	PROPN
eurjchem-2402	256	2	120.5(4	120.5(4	NUM
eurjchem-2402	256	3	)	)	PUNCT
eurjchem-2402	256	4	c212	c212	PROPN
eurjchem-2402	257	1	c211	c211	PROPN
eurjchem-2402	257	2	p2	p2	PROPN
eurjchem-2402	257	3	121.6(3	121.6(3	NUM
eurjchem-2402	257	4	)	)	PUNCT
eurjchem-2402	258	1	c223	c223	PROPN
eurjchem-2402	258	2	c222	c222	PROPN
eurjchem-2402	258	3	c221	c221	PROPN
eurjchem-2402	258	4	119.9(4	119.9(4	NUM
eurjchem-2402	258	5	)	)	PUNCT
eurjchem-2402	259	1	c212	c212	PROPN
eurjchem-2402	260	1	c211	c211	PUNCT
eurjchem-2402	260	2	c216	c216	NUM
eurjchem-2402	260	3	118.2(4	118.2(4	X
eurjchem-2402	260	4	)	)	PUNCT
eurjchem-2402	260	5	c213	c213	X
eurjchem-2402	261	1	c214	c214	PROPN
eurjchem-2402	261	2	c215	c215	NUM
eurjchem-2402	261	3	120.5(5	120.5(5	NUM
eurjchem-2402	261	4	)	)	PUNCT
eurjchem-2402	261	5	c216	c216	PUNCT
eurjchem-2402	262	1	c211	c211	PROPN
eurjchem-2402	262	2	p2	p2	PROPN
eurjchem-2402	262	3	120.2(3	120.2(3	NUM
eurjchem-2402	262	4	)	)	PUNCT
eurjchem-2402	263	1	c114	c114	PROPN
eurjchem-2402	264	1	c113	c113	PROPN
eurjchem-2402	264	2	c112	c112	PROPN
eurjchem-2402	264	3	120.7(5	120.7(5	NUM
eurjchem-2402	264	4	)	)	SYM
eurjchem-2402	264	5	6	6	NUM
eurjchem-2402	264	6	c221	c221	PROPN
eurjchem-2402	264	7	p2	p2	PROPN
eurjchem-2402	264	8	120.2(3	120.2(3	NUM
eurjchem-2402	264	9	)	)	PUNCT
eurjchem-2402	264	10	*	*	PUNCT
eurjchem-2402	264	11	symmetry	symmetry	PROPN
eurjchem-2402	264	12	code	code	NOUN
eurjchem-2402	264	13	:	:	PUNCT
eurjchem-2402	264	14	1	1	NUM
eurjchem-2402	264	15	-x	-x	NUM
eurjchem-2402	264	16	,	,	PUNCT
eurjchem-2402	264	17	2	2	NUM
eurjchem-2402	264	18	-	-	SYM
eurjchem-2402	264	19	y	y	PROPN
eurjchem-2402	264	20	,	,	PUNCT
eurjchem-2402	264	21	-z	-z	X
eurjchem-2402	264	22	.	.	PROPN
eurjchem-2402	264	23	figure	figure	NOUN
eurjchem-2402	264	24	8	8	NUM
eurjchem-2402	264	25	.	.	PUNCT
eurjchem-2402	265	1	c	c	X
eurjchem-2402	265	2	-	-	PUNCT
eurjchem-2402	265	3	h···clhydrogen	h···clhydrogen	NOUN
eurjchem-2402	265	4	bonding	bonding	NOUN
eurjchem-2402	265	5	and	and	CCONJ
eurjchem-2402	265	6	cl-···clhalogen	cl-···clhalogen	NOUN
eurjchem-2402	265	7	bond	bond	NOUN
eurjchem-2402	265	8	,	,	PUNCT
eurjchem-2402	265	9	stabilizing	stabilize	VERB
eurjchem-2402	265	10	the	the	DET
eurjchem-2402	265	11	crystal	crystal	NOUN
eurjchem-2402	265	12	structure	structure	NOUN
eurjchem-2402	265	13	of	of	ADP
eurjchem-2402	265	14	the	the	DET
eurjchem-2402	265	15	complex	complex	ADJ
eurjchem-2402	265	16	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	NOUN
eurjchem-2402	265	17	.	.	PUNCT
eurjchem-2402	266	1	200	200	NUM
eurjchem-2402	266	2	campideli	campideli	NOUN
eurjchem-2402	266	3	et	et	PROPN
eurjchem-2402	266	4	al	al	PROPN
eurjchem-2402	266	5	.	.	PUNCT
eurjchem-2402	266	6	/	/	SYM
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eurjchem-2402	266	8	journal	journal	PROPN
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eurjchem-2402	266	11	14	14	NUM
eurjchem-2402	266	12	(	(	PUNCT
eurjchem-2402	266	13	2	2	NUM
eurjchem-2402	266	14	)	)	PUNCT
eurjchem-2402	266	15	(	(	PUNCT
eurjchem-2402	266	16	2023	2023	NUM
eurjchem-2402	266	17	)	)	PUNCT
eurjchem-2402	266	18	193	193	NUM
eurjchem-2402	266	19	-	-	SYM
eurjchem-2402	266	20	201	201	NUM
eurjchem-2402	266	21	2023	2023	NUM
eurjchem-2402	266	22	–	–	PUNCT
eurjchem-2402	266	23	european	european	ADJ
eurjchem-2402	266	24	journal	journal	NOUN
eurjchem-2402	266	25	of	of	ADP
eurjchem-2402	266	26	chemistry	chemistry	NOUN
eurjchem-2402	266	27	–	–	PUNCT
eurjchem-2402	266	28	cc	cc	NOUN
eurjchem-2402	266	29	by	by	ADP
eurjchem-2402	266	30	nc	nc	PROPN
eurjchem-2402	266	31	–	–	PUNCT
eurjchem-2402	266	32	doi	doi	NOUN
eurjchem-2402	266	33	:	:	PUNCT
eurjchem-2402	266	34	10.5155	10.5155	NUM
eurjchem-2402	266	35	/	/	SYM
eurjchem-2402	266	36	eurjchem.14.2.193	eurjchem.14.2.193	NOUN
eurjchem-2402	266	37	-	-	SYM
eurjchem-2402	266	38	201.2402	201.2402	NUM
eurjchem-2402	266	39	the	the	DET
eurjchem-2402	266	40	crystal	crystal	NOUN
eurjchem-2402	266	41	structure	structure	NOUN
eurjchem-2402	266	42	of	of	ADP
eurjchem-2402	266	43	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	266	44	presents	present	VERB
eurjchem-2402	266	45	non	non	ADJ
eurjchem-2402	266	46	-	-	ADJ
eurjchem-2402	266	47	classical	classical	ADJ
eurjchem-2402	266	48	c	c	NOUN
eurjchem-2402	266	49	-	-	PUNCT
eurjchem-2402	266	50	h···cl1s	h···cl1s	ADJ
eurjchem-2402	266	51	hydrogen	hydrogen	NOUN
eurjchem-2402	266	52	bonding	bonding	NOUN
eurjchem-2402	266	53	,	,	PUNCT
eurjchem-2402	266	54	keeping	keep	VERB
eurjchem-2402	266	55	the	the	DET
eurjchem-2402	266	56	counter	counter	NOUN
eurjchem-2402	266	57	-	-	NOUN
eurjchem-2402	266	58	ion	ion	NOUN
eurjchem-2402	266	59	caged	caged	NOUN
eurjchem-2402	266	60	(	(	PUNCT
eurjchem-2402	266	61	figure	figure	NOUN
eurjchem-2402	266	62	8)	8)	NUM
eurjchem-2402	266	63	.	.	PUNCT
eurjchem-2402	267	1	the	the	DET
eurjchem-2402	267	2	c	c	NOUN
eurjchem-2402	267	3	-	-	PUNCT
eurjchem-2402	267	4	h···cl	h···cl	NOUN
eurjchem-2402	267	5	intermolecular	intermolecular	ADJ
eurjchem-2402	267	6	contacts	contact	NOUN
eurjchem-2402	267	7	are	be	AUX
eurjchem-2402	267	8	around	around	ADP
eurjchem-2402	267	9	2.8	2.8	NUM
eurjchem-2402	267	10	å	å	NOUN
eurjchem-2402	267	11	.	.	PUNCT
eurjchem-2402	268	1	furthermore	furthermore	ADV
eurjchem-2402	268	2	,	,	PUNCT
eurjchem-2402	268	3	the	the	DET
eurjchem-2402	268	4	complex	complex	ADJ
eurjchem-2402	268	5	presents	present	VERB
eurjchem-2402	268	6	an	an	DET
eurjchem-2402	268	7	intermolecular	intermolecular	ADJ
eurjchem-2402	268	8	cl···cl	cl···cl	NOUN
eurjchem-2402	268	9	halogen	halogen	NOUN
eurjchem-2402	268	10	bond	bond	NOUN
eurjchem-2402	268	11	at	at	ADP
eurjchem-2402	268	12	3.123	3.123	NUM
eurjchem-2402	268	13	å	å	PROPN
eurjchem-2402	268	14	,	,	PUNCT
eurjchem-2402	268	15	which	which	PRON
eurjchem-2402	268	16	is	be	AUX
eurjchem-2402	268	17	consistent	consistent	ADJ
eurjchem-2402	268	18	with	with	ADP
eurjchem-2402	268	19	values	value	NOUN
eurjchem-2402	268	20	reported	report	VERB
eurjchem-2402	268	21	elsewhere	elsewhere	ADV
eurjchem-2402	268	22	[	[	X
eurjchem-2402	268	23	38	38	NUM
eurjchem-2402	268	24	]	]	PUNCT
eurjchem-2402	268	25	.	.	PUNCT
eurjchem-2402	269	1	4	4	X
eurjchem-2402	269	2	.	.	X
eurjchem-2402	269	3	conclusions	conclusion	NOUN
eurjchem-2402	269	4	in	in	ADP
eurjchem-2402	269	5	summary	summary	NOUN
eurjchem-2402	269	6	,	,	PUNCT
eurjchem-2402	269	7	the	the	DET
eurjchem-2402	269	8	interaction	interaction	NOUN
eurjchem-2402	269	9	with	with	ADP
eurjchem-2402	269	10	dna	dna	NOUN
eurjchem-2402	269	11	of	of	ADP
eurjchem-2402	269	12	cis	cis	NOUN
eurjchem-2402	269	13	and	and	CCONJ
eurjchem-2402	269	14	trans	trans	NOUN
eurjchem-2402	269	15	isomers	isomer	NOUN
eurjchem-2402	269	16	of	of	ADP
eurjchem-2402	269	17	the	the	DET
eurjchem-2402	269	18	complex	complex	NOUN
eurjchem-2402	270	1	[	[	X
eurjchem-2402	270	2	rucl2(dppe)2	rucl2(dppe)2	X
eurjchem-2402	270	3	]	]	PUNCT
eurjchem-2402	270	4	was	be	AUX
eurjchem-2402	270	5	investigated	investigate	VERB
eurjchem-2402	270	6	.	.	PUNCT
eurjchem-2402	271	1	uv	uv	NOUN
eurjchem-2402	271	2	-	-	PUNCT
eurjchem-2402	271	3	vis	vis	X
eurjchem-2402	271	4	and	and	CCONJ
eurjchem-2402	271	5	viscosity	viscosity	NOUN
eurjchem-2402	271	6	analysis	analysis	NOUN
eurjchem-2402	271	7	showed	show	VERB
eurjchem-2402	271	8	that	that	SCONJ
eurjchem-2402	271	9	the	the	DET
eurjchem-2402	271	10	cisand	cisand	PROPN
eurjchem-2402	271	11	trans	trans	ADJ
eurjchem-2402	271	12	-	-	ADJ
eurjchem-2402	271	13	isomer	isomer	ADJ
eurjchem-2402	271	14	mixtures	mixture	NOUN
eurjchem-2402	271	15	exhibit	exhibit	VERB
eurjchem-2402	271	16	moderate	moderate	ADJ
eurjchem-2402	271	17	interaction	interaction	NOUN
eurjchem-2402	271	18	with	with	ADP
eurjchem-2402	271	19	dna	dna	PROPN
eurjchem-2402	271	20	.	.	PUNCT
eurjchem-2402	272	1	interestingly	interestingly	ADV
eurjchem-2402	272	2	,	,	PUNCT
eurjchem-2402	272	3	dna	dna	NOUN
eurjchem-2402	272	4	interaction	interaction	NOUN
eurjchem-2402	272	5	by	by	ADP
eurjchem-2402	272	6	square	square	ADJ
eurjchem-2402	272	7	wave	wave	PROPN
eurjchem-2402	272	8	voltammetric	voltammetric	PROPN
eurjchem-2402	272	9	indicates	indicate	VERB
eurjchem-2402	272	10	that	that	SCONJ
eurjchem-2402	272	11	the	the	DET
eurjchem-2402	272	12	interaction	interaction	NOUN
eurjchem-2402	272	13	of	of	ADP
eurjchem-2402	272	14	cis	cis	NOUN
eurjchem-2402	272	15	-	-	PUNCT
eurjchem-2402	272	16	isomer	isomer	NOUN
eurjchem-2402	272	17	may	may	AUX
eurjchem-2402	272	18	occur	occur	VERB
eurjchem-2402	272	19	by	by	ADP
eurjchem-2402	272	20	dna	dna	PROPN
eurjchem-2402	272	21	grooves	groove	NOUN
eurjchem-2402	272	22	,	,	PUNCT
eurjchem-2402	272	23	while	while	SCONJ
eurjchem-2402	272	24	the	the	DET
eurjchem-2402	272	25	complex	complex	ADJ
eurjchem-2402	272	26	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	272	27	]	]	PUNCT
eurjchem-2402	272	28	probably	probably	ADV
eurjchem-2402	272	29	interacts	interact	VERB
eurjchem-2402	272	30	with	with	ADP
eurjchem-2402	272	31	dna	dna	NOUN
eurjchem-2402	272	32	by	by	ADP
eurjchem-2402	272	33	intercalation	intercalation	NOUN
eurjchem-2402	272	34	or	or	CCONJ
eurjchem-2402	272	35	by	by	ADP
eurjchem-2402	272	36	covalence	covalence	NOUN
eurjchem-2402	272	37	.	.	PUNCT
eurjchem-2402	273	1	finally	finally	ADV
eurjchem-2402	273	2	,	,	PUNCT
eurjchem-2402	273	3	the	the	DET
eurjchem-2402	273	4	crystal	crystal	NOUN
eurjchem-2402	273	5	structure	structure	NOUN
eurjchem-2402	273	6	of	of	ADP
eurjchem-2402	273	7	the	the	DET
eurjchem-2402	273	8	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	273	9	complex	complex	NOUN
eurjchem-2402	273	10	was	be	AUX
eurjchem-2402	273	11	presented	present	VERB
eurjchem-2402	273	12	and	and	CCONJ
eurjchem-2402	273	13	compared	compare	VERB
eurjchem-2402	273	14	with	with	ADP
eurjchem-2402	273	15	the	the	DET
eurjchem-2402	273	16	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	273	17	]	]	X
eurjchem-2402	273	18	complex	complex	NOUN
eurjchem-2402	273	19	.	.	PUNCT
eurjchem-2402	274	1	this	this	DET
eurjchem-2402	274	2	study	study	NOUN
eurjchem-2402	274	3	contributes	contribute	VERB
eurjchem-2402	274	4	to	to	ADP
eurjchem-2402	274	5	a	a	DET
eurjchem-2402	274	6	better	well	ADJ
eurjchem-2402	274	7	understanding	understanding	NOUN
eurjchem-2402	274	8	of	of	ADP
eurjchem-2402	274	9	complex	complex	ADJ
eurjchem-2402	274	10	/	/	SYM
eurjchem-2402	274	11	dna	dna	NOUN
eurjchem-2402	274	12	interaction	interaction	NOUN
eurjchem-2402	274	13	,	,	PUNCT
eurjchem-2402	274	14	mainly	mainly	ADV
eurjchem-2402	274	15	,	,	PUNCT
eurjchem-2402	274	16	allowing	allow	VERB
eurjchem-2402	274	17	identification	identification	NOUN
eurjchem-2402	274	18	of	of	ADP
eurjchem-2402	274	19	two	two	NUM
eurjchem-2402	274	20	different	different	ADJ
eurjchem-2402	274	21	dna	dna	NOUN
eurjchem-2402	274	22	interaction	interaction	NOUN
eurjchem-2402	274	23	modes	mode	NOUN
eurjchem-2402	274	24	by	by	ADP
eurjchem-2402	274	25	using	use	VERB
eurjchem-2402	274	26	square	square	ADJ
eurjchem-2402	274	27	wave	wave	NOUN
eurjchem-2402	274	28	voltammograms	voltammogram	NOUN
eurjchem-2402	274	29	.	.	PUNCT
eurjchem-2402	275	1	acknowledgements	acknowledgement	NOUN
eurjchem-2402	275	2	we	we	PRON
eurjchem-2402	275	3	would	would	AUX
eurjchem-2402	275	4	like	like	VERB
eurjchem-2402	275	5	to	to	PART
eurjchem-2402	275	6	thank	thank	VERB
eurjchem-2402	275	7	conselho	conselho	PROPN
eurjchem-2402	275	8	nacional	nacional	PROPN
eurjchem-2402	275	9	de	de	X
eurjchem-2402	275	10	desenvolvimento	desenvolvimento	PROPN
eurjchem-2402	275	11	cientı́fico	cientı́fico	PROPN
eurjchem-2402	275	12	e	e	PROPN
eurjchem-2402	275	13	tecnológico	tecnológico	PROPN
eurjchem-2402	275	14	(	(	PUNCT
eurjchem-2402	275	15	cnpq	cnpq	NOUN
eurjchem-2402	275	16	)	)	PUNCT
eurjchem-2402	275	17	,	,	PUNCT
eurjchem-2402	275	18	coordenação	coordenação	PROPN
eurjchem-2402	275	19	de	de	PROPN
eurjchem-2402	275	20	aperfeiçoamento	aperfeiçoamento	PROPN
eurjchem-2402	275	21	de	de	X
eurjchem-2402	275	22	pessoal	pessoal	PROPN
eurjchem-2402	275	23	de	de	X
eurjchem-2402	275	24	nı́vel	nı́vel	PROPN
eurjchem-2402	275	25	superior	superior	ADJ
eurjchem-2402	275	26	(	(	PUNCT
eurjchem-2402	275	27	capes	cape	NOUN
eurjchem-2402	275	28	)	)	PUNCT
eurjchem-2402	275	29	,	,	PUNCT
eurjchem-2402	275	30	and	and	CCONJ
eurjchem-2402	275	31	fundação	fundação	PROPN
eurjchem-2402	275	32	de	de	X
eurjchem-2402	275	33	amparo	amparo	PROPN
eurjchem-2402	275	34	à	à	PROPN
eurjchem-2402	275	35	pesquisa	pesquisa	PROPN
eurjchem-2402	275	36	do	do	AUX
eurjchem-2402	275	37	estado	estado	PROPN
eurjchem-2402	275	38	de	de	PROPN
eurjchem-2402	275	39	minas	minas	PROPN
eurjchem-2402	275	40	gerais	gerais	PROPN
eurjchem-2402	275	41	(	(	PUNCT
eurjchem-2402	275	42	fapemig	fapemig	PROPN
eurjchem-2402	275	43	)	)	PUNCT
eurjchem-2402	275	44	for	for	ADP
eurjchem-2402	275	45	the	the	DET
eurjchem-2402	275	46	financial	financial	ADJ
eurjchem-2402	275	47	support	support	NOUN
eurjchem-2402	275	48	.	.	PUNCT
eurjchem-2402	276	1	jerica	jerica	ADJ
eurjchem-2402	276	2	margely	margely	ADV
eurjchem-2402	276	3	montilla	montilla	NOUN
eurjchem-2402	276	4	-	-	PUNCT
eurjchem-2402	276	5	suárez	suárez	NOUN
eurjchem-2402	276	6	thanks	thank	NOUN
eurjchem-2402	276	7	the	the	DET
eurjchem-2402	276	8	universidade	universidade	PROPN
eurjchem-2402	276	9	federal	federal	PROPN
eurjchem-2402	276	10	de	de	PROPN
eurjchem-2402	276	11	ouro	ouro	PROPN
eurjchem-2402	276	12	preto	preto	PROPN
eurjchem-2402	276	13	for	for	ADP
eurjchem-2402	276	14	master	master	NOUN
eurjchem-2402	276	15	’s	’s	PART
eurjchem-2402	276	16	fellowship	fellowship	NOUN
eurjchem-2402	276	17	.	.	PUNCT
eurjchem-2402	277	1	the	the	DET
eurjchem-2402	277	2	authors	author	NOUN
eurjchem-2402	277	3	thank	thank	VERB
eurjchem-2402	277	4	professor	professor	PROPN
eurjchem-2402	277	5	javier	javier	PROPN
eurjchem-2402	277	6	ellena	ellena	PROPN
eurjchem-2402	277	7	for	for	ADP
eurjchem-2402	277	8	crystallographic	crystallographic	ADJ
eurjchem-2402	277	9	facilities	facility	NOUN
eurjchem-2402	277	10	and	and	CCONJ
eurjchem-2402	277	11	professor	professor	NOUN
eurjchem-2402	277	12	alzir	alzir	PROPN
eurjchem-2402	277	13	a.	a.	PROPN
eurjchem-2402	277	14	batista	batista	PROPN
eurjchem-2402	277	15	for	for	ADP
eurjchem-2402	277	16	providing	provide	VERB
eurjchem-2402	277	17	the	the	DET
eurjchem-2402	277	18	ruthenium	ruthenium	NOUN
eurjchem-2402	277	19	salt	salt	NOUN
eurjchem-2402	277	20	.	.	PUNCT
eurjchem-2402	278	1	supporting	support	VERB
eurjchem-2402	278	2	information	information	NOUN
eurjchem-2402	278	3	ccdc-2232620	ccdc-2232620	NOUN
eurjchem-2402	278	4	contains	contain	VERB
eurjchem-2402	278	5	the	the	DET
eurjchem-2402	278	6	supplementary	supplementary	ADJ
eurjchem-2402	278	7	crystallographic	crystallographic	ADJ
eurjchem-2402	278	8	data	datum	NOUN
eurjchem-2402	278	9	for	for	ADP
eurjchem-2402	278	10	this	this	DET
eurjchem-2402	278	11	paper	paper	NOUN
eurjchem-2402	278	12	.	.	PUNCT
eurjchem-2402	279	1	these	these	DET
eurjchem-2402	279	2	data	datum	NOUN
eurjchem-2402	279	3	can	can	AUX
eurjchem-2402	279	4	be	be	AUX
eurjchem-2402	279	5	obtained	obtain	VERB
eurjchem-2402	279	6	free	free	ADJ
eurjchem-2402	279	7	of	of	ADP
eurjchem-2402	279	8	charge	charge	NOUN
eurjchem-2402	279	9	via	via	ADP
eurjchem-2402	279	10	https://www.ccdc.cam	https://www.ccdc.cam	PROPN
eurjchem-2402	279	11	.	.	PUNCT
eurjchem-2402	280	1	ac.uk/structures/	ac.uk/structures/	PROPN
eurjchem-2402	280	2	,	,	PUNCT
eurjchem-2402	280	3	or	or	CCONJ
eurjchem-2402	280	4	by	by	ADP
eurjchem-2402	280	5	e	e	NOUN
eurjchem-2402	280	6	-	-	ADJ
eurjchem-2402	280	7	mailing	mailing	ADJ
eurjchem-2402	280	8	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-2402	280	9	,	,	PUNCT
eurjchem-2402	280	10	or	or	CCONJ
eurjchem-2402	280	11	by	by	ADP
eurjchem-2402	280	12	contacting	contact	VERB
eurjchem-2402	280	13	the	the	DET
eurjchem-2402	280	14	cambridge	cambridge	PROPN
eurjchem-2402	280	15	crystallographic	crystallographic	PROPN
eurjchem-2402	280	16	data	data	PROPN
eurjchem-2402	280	17	centre	centre	NOUN
eurjchem-2402	280	18	,	,	PUNCT
eurjchem-2402	280	19	12	12	NUM
eurjchem-2402	280	20	union	union	NOUN
eurjchem-2402	280	21	road	road	NOUN
eurjchem-2402	280	22	,	,	PUNCT
eurjchem-2402	280	23	cambridge	cambridge	PROPN
eurjchem-2402	280	24	cb2	cb2	PROPN
eurjchem-2402	280	25	1ez	1ez	PROPN
eurjchem-2402	280	26	,	,	PUNCT
eurjchem-2402	280	27	uk	uk	PROPN
eurjchem-2402	280	28	;	;	PUNCT
eurjchem-2402	280	29	fax	fax	NOUN
eurjchem-2402	280	30	:	:	PUNCT
eurjchem-2402	280	31	+44(0)1223	+44(0)1223	PROPN
eurjchem-2402	280	32	-	-	PUNCT
eurjchem-2402	280	33	336033	336033	NUM
eurjchem-2402	280	34	.	.	PUNCT
eurjchem-2402	281	1	disclosure	disclosure	NOUN
eurjchem-2402	281	2	statement	statement	NOUN
eurjchem-2402	281	3	conflict	conflict	NOUN
eurjchem-2402	281	4	of	of	ADP
eurjchem-2402	281	5	interest	interest	NOUN
eurjchem-2402	281	6	:	:	PUNCT
eurjchem-2402	281	7	the	the	DET
eurjchem-2402	281	8	authors	author	NOUN
eurjchem-2402	281	9	declare	declare	VERB
eurjchem-2402	281	10	that	that	SCONJ
eurjchem-2402	281	11	they	they	PRON
eurjchem-2402	281	12	have	have	VERB
eurjchem-2402	281	13	no	no	DET
eurjchem-2402	281	14	known	know	VERB
eurjchem-2402	281	15	competing	compete	VERB
eurjchem-2402	281	16	financial	financial	ADJ
eurjchem-2402	281	17	interests	interest	NOUN
eurjchem-2402	281	18	or	or	CCONJ
eurjchem-2402	281	19	personal	personal	ADJ
eurjchem-2402	281	20	relationships	relationship	NOUN
eurjchem-2402	281	21	that	that	PRON
eurjchem-2402	281	22	could	could	AUX
eurjchem-2402	281	23	appear	appear	VERB
eurjchem-2402	281	24	to	to	PART
eurjchem-2402	281	25	influence	influence	VERB
eurjchem-2402	281	26	the	the	DET
eurjchem-2402	281	27	work	work	NOUN
eurjchem-2402	281	28	reported	report	VERB
eurjchem-2402	281	29	in	in	ADP
eurjchem-2402	281	30	this	this	DET
eurjchem-2402	281	31	paper	paper	NOUN
eurjchem-2402	281	32	.	.	PUNCT
eurjchem-2402	282	1	sample	sample	NOUN
eurjchem-2402	282	2	availability	availability	NOUN
eurjchem-2402	282	3	:	:	PUNCT
eurjchem-2402	282	4	samples	sample	NOUN
eurjchem-2402	282	5	of	of	ADP
eurjchem-2402	282	6	the	the	DET
eurjchem-2402	282	7	compound	compound	NOUN
eurjchem-2402	282	8	are	be	AUX
eurjchem-2402	282	9	available	available	ADJ
eurjchem-2402	282	10	from	from	ADP
eurjchem-2402	282	11	the	the	DET
eurjchem-2402	282	12	author	author	NOUN
eurjchem-2402	282	13	.	.	PUNCT
eurjchem-2402	283	1	credit	credit	NOUN
eurjchem-2402	283	2	authorship	authorship	NOUN
eurjchem-2402	283	3	contribution	contribution	NOUN
eurjchem-2402	283	4	statement	statement	NOUN
eurjchem-2402	283	5	conceptualization	conceptualization	NOUN
eurjchem-2402	283	6	:	:	PUNCT
eurjchem-2402	283	7	victor	victor	PROPN
eurjchem-2402	283	8	cardoso	cardoso	PROPN
eurjchem-2402	283	9	campideli	campideli	PROPN
eurjchem-2402	283	10	,	,	PUNCT
eurjchem-2402	283	11	jerica	jerica	ADV
eurjchem-2402	283	12	margely	margely	ADV
eurjchem-2402	283	13	montilla	montilla	NOUN
eurjchem-2402	283	14	-	-	PUNCT
eurjchem-2402	283	15	suárez	suárez	NOUN
eurjchem-2402	283	16	,	,	PUNCT
eurjchem-2402	283	17	rodrigo	rodrigo	PROPN
eurjchem-2402	283	18	souza	souza	PROPN
eurjchem-2402	283	19	corrêa	corrêa	PROPN
eurjchem-2402	283	20	;	;	PUNCT
eurjchem-2402	283	21	methodology	methodology	NOUN
eurjchem-2402	283	22	:	:	PUNCT
eurjchem-2402	283	23	victor	victor	PROPN
eurjchem-2402	283	24	cardoso	cardoso	PROPN
eurjchem-2402	283	25	campideli	campideli	PROPN
eurjchem-2402	283	26	,	,	PUNCT
eurjchem-2402	283	27	jerica	jerica	ADV
eurjchem-2402	283	28	margely	margely	ADV
eurjchem-2402	283	29	montilla	montilla	NOUN
eurjchem-2402	283	30	-	-	PUNCT
eurjchem-2402	283	31	suárez	suárez	NOUN
eurjchem-2402	283	32	,	,	PUNCT
eurjchem-2402	283	33	tiago	tiago	PROPN
eurjchem-2402	283	34	almeida	almeida	PROPN
eurjchem-2402	283	35	silva	silva	PROPN
eurjchem-2402	283	36	,	,	PUNCT
eurjchem-2402	283	37	dalila	dalila	PROPN
eurjchem-2402	283	38	chaves	chaves	PROPN
eurjchem-2402	283	39	sicupira	sicupira	PROPN
eurjchem-2402	283	40	,	,	PUNCT
eurjchem-2402	283	41	katia	katia	PROPN
eurjchem-2402	283	42	mara	mara	PROPN
eurjchem-2402	283	43	oliveira	oliveira	PROPN
eurjchem-2402	283	44	,	,	PUNCT
eurjchem-2402	283	45	rodrigo	rodrigo	PROPN
eurjchem-2402	283	46	souza	souza	PROPN
eurjchem-2402	283	47	correa	correa	PROPN
eurjchem-2402	283	48	;	;	PUNCT
eurjchem-2402	283	49	software	software	PROPN
eurjchem-2402	283	50	:	:	PUNCT
eurjchem-2402	283	51	katia	katia	PROPN
eurjchem-2402	283	52	mara	mara	PROPN
eurjchem-2402	283	53	oliveira	oliveira	PROPN
eurjchem-2402	283	54	,	,	PUNCT
eurjchem-2402	283	55	rodrigo	rodrigo	PROPN
eurjchem-2402	283	56	souza	souza	PROPN
eurjchem-2402	283	57	correa	correa	PROPN
eurjchem-2402	283	58	;	;	PUNCT
eurjchem-2402	283	59	validation	validation	NOUN
eurjchem-2402	283	60	:	:	PUNCT
eurjchem-2402	283	61	tiago	tiago	PROPN
eurjchem-2402	283	62	almeida	almeida	PROPN
eurjchem-2402	283	63	silva	silva	PROPN
eurjchem-2402	283	64	,	,	PUNCT
eurjchem-2402	283	65	dalila	dalila	PROPN
eurjchem-2402	283	66	chaves	chaves	PROPN
eurjchem-2402	283	67	sicupira	sicupira	PROPN
eurjchem-2402	283	68	,	,	PUNCT
eurjchem-2402	283	69	katia	katia	PROPN
eurjchem-2402	283	70	mara	mara	PROPN
eurjchem-2402	283	71	oliveira	oliveira	PROPN
eurjchem-2402	283	72	,	,	PUNCT
eurjchem-2402	283	73	rodrigo	rodrigo	PROPN
eurjchem-2402	283	74	souza	souza	PROPN
eurjchem-2402	283	75	correa	correa	PROPN
eurjchem-2402	283	76	;	;	PUNCT
eurjchem-2402	283	77	formal	formal	ADJ
eurjchem-2402	283	78	analysis	analysis	NOUN
eurjchem-2402	283	79	:	:	PUNCT
eurjchem-2402	283	80	victor	victor	PROPN
eurjchem-2402	283	81	cardoso	cardoso	PROPN
eurjchem-2402	283	82	campideli	campideli	PROPN
eurjchem-2402	283	83	,	,	PUNCT
eurjchem-2402	283	84	jerica	jerica	ADV
eurjchem-2402	283	85	margely	margely	ADV
eurjchem-2402	283	86	montilla	montilla	NOUN
eurjchem-2402	283	87	-	-	PUNCT
eurjchem-2402	283	88	suárez	suárez	NOUN
eurjchem-2402	283	89	,	,	PUNCT
eurjchem-2402	283	90	katia	katia	PROPN
eurjchem-2402	283	91	mara	mara	PROPN
eurjchem-2402	283	92	oliveira	oliveira	PROPN
eurjchem-2402	283	93	;	;	PUNCT
eurjchem-2402	283	94	investigation	investigation	NOUN
eurjchem-2402	283	95	:	:	PUNCT
eurjchem-2402	283	96	victor	victor	PROPN
eurjchem-2402	283	97	cardoso	cardoso	PROPN
eurjchem-2402	283	98	campideli	campideli	PROPN
eurjchem-2402	283	99	,	,	PUNCT
eurjchem-2402	283	100	jerica	jerica	ADV
eurjchem-2402	283	101	margely	margely	ADV
eurjchem-2402	283	102	montilla	montilla	NOUN
eurjchem-2402	283	103	-	-	PUNCT
eurjchem-2402	283	104	suárez	suárez	NOUN
eurjchem-2402	283	105	,	,	PUNCT
eurjchem-2402	283	106	tiago	tiago	PROPN
eurjchem-2402	283	107	almeida	almeida	PROPN
eurjchem-2402	283	108	silva	silva	PROPN
eurjchem-2402	283	109	;	;	PUNCT
eurjchem-2402	283	110	resources	resource	NOUN
eurjchem-2402	283	111	:	:	PUNCT
eurjchem-2402	283	112	dalila	dalila	PROPN
eurjchem-2402	283	113	chaves	chaves	PROPN
eurjchem-2402	283	114	sicupira	sicupira	PROPN
eurjchem-2402	283	115	,	,	PUNCT
eurjchem-2402	283	116	katia	katia	PROPN
eurjchem-2402	283	117	mara	mara	PROPN
eurjchem-2402	283	118	oliveira	oliveira	PROPN
eurjchem-2402	283	119	,	,	PUNCT
eurjchem-2402	283	120	rodrigo	rodrigo	PROPN
eurjchem-2402	283	121	souza	souza	PROPN
eurjchem-2402	283	122	correa	correa	PROPN
eurjchem-2402	283	123	;	;	PUNCT
eurjchem-2402	283	124	data	data	NOUN
eurjchem-2402	283	125	curation	curation	NOUN
eurjchem-2402	283	126	:	:	PUNCT
eurjchem-2402	283	127	victor	victor	PROPN
eurjchem-2402	283	128	cardoso	cardoso	PROPN
eurjchem-2402	283	129	campideli	campideli	PROPN
eurjchem-2402	283	130	,	,	PUNCT
eurjchem-2402	283	131	jerica	jerica	PROPN
eurjchem-2402	283	132	margely	margely	ADV
eurjchem-2402	283	133	montillasuárez	montillasuárez	PROPN
eurjchem-2402	283	134	,	,	PUNCT
eurjchem-2402	283	135	katia	katia	PROPN
eurjchem-2402	283	136	mara	mara	PROPN
eurjchem-2402	283	137	oliveira	oliveira	PROPN
eurjchem-2402	283	138	;	;	PUNCT
eurjchem-2402	283	139	writing	write	VERB
eurjchem-2402	283	140	original	original	ADJ
eurjchem-2402	283	141	draft	draft	NOUN
eurjchem-2402	283	142	:	:	PUNCT
eurjchem-2402	283	143	victor	victor	PROPN
eurjchem-2402	283	144	cardoso	cardoso	PROPN
eurjchem-2402	283	145	campideli	campideli	PROPN
eurjchem-2402	283	146	,	,	PUNCT
eurjchem-2402	283	147	jerica	jerica	ADV
eurjchem-2402	283	148	margely	margely	ADV
eurjchem-2402	283	149	montilla	montilla	NOUN
eurjchem-2402	283	150	-	-	PUNCT
eurjchem-2402	283	151	suárez	suárez	NOUN
eurjchem-2402	283	152	,	,	PUNCT
eurjchem-2402	283	153	katia	katia	PROPN
eurjchem-2402	283	154	mara	mara	PROPN
eurjchem-2402	283	155	oliveira	oliveira	PROPN
eurjchem-2402	283	156	,	,	PUNCT
eurjchem-2402	283	157	rodrigo	rodrigo	PROPN
eurjchem-2402	283	158	souza	souza	PROPN
eurjchem-2402	283	159	correa	correa	PROPN
eurjchem-2402	283	160	;	;	PUNCT
eurjchem-2402	283	161	writing	write	VERB
eurjchem-2402	283	162	review	review	NOUN
eurjchem-2402	283	163	and	and	CCONJ
eurjchem-2402	283	164	editing	editing	NOUN
eurjchem-2402	283	165	:	:	PUNCT
eurjchem-2402	283	166	katia	katia	PROPN
eurjchem-2402	283	167	mara	mara	PROPN
eurjchem-2402	283	168	oliveira	oliveira	PROPN
eurjchem-2402	283	169	,	,	PUNCT
eurjchem-2402	283	170	rodrigo	rodrigo	PROPN
eurjchem-2402	283	171	souza	souza	PROPN
eurjchem-2402	283	172	correa	correa	PROPN
eurjchem-2402	283	173	;	;	PUNCT
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eurjchem-2402	283	175	:	:	PUNCT
eurjchem-2402	283	176	katia	katia	PROPN
eurjchem-2402	283	177	mara	mara	PROPN
eurjchem-2402	283	178	oliveira	oliveira	PROPN
eurjchem-2402	283	179	,	,	PUNCT
eurjchem-2402	283	180	rodrigo	rodrigo	PROPN
eurjchem-2402	283	181	souza	souza	PROPN
eurjchem-2402	283	182	correa	correa	PROPN
eurjchem-2402	283	183	;	;	PUNCT
eurjchem-2402	283	184	funding	funding	NOUN
eurjchem-2402	283	185	acquisition	acquisition	NOUN
eurjchem-2402	283	186	:	:	PUNCT
eurjchem-2402	283	187	rodrigo	rodrigo	PROPN
eurjchem-2402	283	188	souza	souza	PROPN
eurjchem-2402	283	189	correa	correa	PROPN
eurjchem-2402	283	190	;	;	PUNCT
eurjchem-2402	283	191	supervision	supervision	PROPN
eurjchem-2402	283	192	:	:	PUNCT
eurjchem-2402	283	193	katia	katia	PROPN
eurjchem-2402	283	194	mara	mara	PROPN
eurjchem-2402	283	195	oliveira	oliveira	PROPN
eurjchem-2402	283	196	,	,	PUNCT
eurjchem-2402	283	197	rodrigo	rodrigo	PROPN
eurjchem-2402	283	198	souza	souza	PROPN
eurjchem-2402	283	199	correa	correa	PROPN
eurjchem-2402	283	200	;	;	PUNCT
eurjchem-2402	283	201	project	project	NOUN
eurjchem-2402	283	202	administration	administration	NOUN
eurjchem-2402	283	203	:	:	PUNCT
eurjchem-2402	283	204	dalila	dalila	PROPN
eurjchem-2402	283	205	chaves	chaves	PROPN
eurjchem-2402	283	206	sicupira	sicupira	PROPN
eurjchem-2402	283	207	,	,	PUNCT
eurjchem-2402	283	208	katia	katia	PROPN
eurjchem-2402	283	209	mara	mara	PROPN
eurjchem-2402	283	210	oliveira	oliveira	PROPN
eurjchem-2402	283	211	,	,	PUNCT
eurjchem-2402	283	212	rodrigo	rodrigo	PROPN
eurjchem-2402	283	213	souza	souza	PROPN
eurjchem-2402	283	214	correa	correa	PROPN
eurjchem-2402	283	215	.	.	PROPN
eurjchem-2402	284	1	funding	fund	VERB
eurjchem-2402	284	2	this	this	DET
eurjchem-2402	284	3	research	research	NOUN
eurjchem-2402	284	4	was	be	AUX
eurjchem-2402	284	5	funded	fund	VERB
eurjchem-2402	284	6	by	by	ADP
eurjchem-2402	284	7	fundação	fundação	PROPN
eurjchem-2402	284	8	de	de	X
eurjchem-2402	284	9	amparo	amparo	PROPN
eurjchem-2402	284	10	à	à	X
eurjchem-2402	284	11	pesquisa	pesquisa	PROPN
eurjchem-2402	284	12	do	do	AUX
eurjchem-2402	284	13	estado	estado	VERB
eurjchem-2402	284	14	de	de	PROPN
eurjchem-2402	284	15	minas	minas	PROPN
eurjchem-2402	284	16	gerais	gerais	PROPN
eurjchem-2402	284	17	(	(	PUNCT
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eurjchem-2402	284	19	apq-01674	apq-01674	NOUN
eurjchem-2402	284	20	-	-	PUNCT
eurjchem-2402	284	21	18	18	NUM
eurjchem-2402	284	22	)	)	PUNCT
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eurjchem-2402	284	25	nacional	nacional	PROPN
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eurjchem-2402	284	27	desenvolvimento	desenvolvimento	PROPN
eurjchem-2402	284	28	científico	científico	PROPN
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eurjchem-2402	284	30	tecnológico	tecnológico	PROPN
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eurjchem-2402	284	32	cnpq	cnpq	PROPN
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eurjchem-2402	284	35	3	3	NUM
eurjchem-2402	284	36	)	)	PUNCT
eurjchem-2402	284	37	.	.	PUNCT
eurjchem-2402	285	1	orcid	orcid	NOUN
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eurjchem-2402	285	5	cardoso	cardoso	PROPN
eurjchem-2402	285	6	campideli	campideli	PROPN
eurjchem-2402	285	7	victor.campideli@aluno.ufop.edu.br	victor.campideli@aluno.ufop.edu.br	PUNCT
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eurjchem-2402	285	10	margely	margely	ADV
eurjchem-2402	285	11	montilla	montilla	NOUN
eurjchem-2402	285	12	-	-	PUNCT
eurjchem-2402	285	13	suárez	suárez	NOUN
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eurjchem-2402	286	1	dalila	dalila	PROPN
eurjchem-2402	286	2	chaves	chaves	PROPN
eurjchem-2402	286	3	sicupira	sicupira	PROPN
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eurjchem-2402	286	6	katia	katia	PROPN
eurjchem-2402	286	7	mara	mara	PROPN
eurjchem-2402	286	8	oliveira	oliveira	PROPN
eurjchem-2402	286	9	katia.oliveira@unb.br	katia.oliveira@unb.br	PROPN
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eurjchem-2402	286	12	souza	souza	PROPN
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eurjchem-2402	286	14	rodrigocorrea@ufop.edu.br	rodrigocorrea@ufop.edu.br	PROPN
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eurjchem-2402	286	18	1	1	NUM
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eurjchem-2402	290	2	.	.	PUNCT
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eurjchem-2402	291	2	,	,	PUNCT
eurjchem-2402	291	3	4	4	NUM
eurjchem-2402	291	4	,	,	PUNCT
eurjchem-2402	291	5	218–227	218–227	NUM
eurjchem-2402	291	6	.	.	PUNCT
eurjchem-2402	292	1	[	[	X
eurjchem-2402	292	2	2	2	NUM
eurjchem-2402	292	3	]	]	PUNCT
eurjchem-2402	292	4	.	.	PUNCT
eurjchem-2402	293	1	kumar	kumar	PROPN
eurjchem-2402	293	2	,	,	PUNCT
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eurjchem-2402	293	4	s.	s.	PROPN
eurjchem-2402	293	5	;	;	PUNCT
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eurjchem-2402	293	7	,	,	PUNCT
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eurjchem-2402	293	10	;	;	PUNCT
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eurjchem-2402	293	35	complexes	complex	NOUN
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eurjchem-2402	293	38	-	-	PUNCT
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eurjchem-2402	293	40	-	-	PUNCT
eurjchem-2402	293	41	hydroxybenzylidene)-2	hydroxybenzylidene)-2	NOUN
eurjchem-2402	293	42	-	-	PUNCT
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eurjchem-2402	294	1	eur	eur	PROPN
eurjchem-2402	294	2	.	.	PUNCT
eurjchem-2402	295	1	j.	j.	PROPN
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eurjchem-2402	295	3	.	.	PUNCT
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eurjchem-2402	296	2	,	,	PUNCT
eurjchem-2402	296	3	2	2	NUM
eurjchem-2402	296	4	,	,	PUNCT
eurjchem-2402	296	5	394–403	394–403	NUM
eurjchem-2402	296	6	.	.	PUNCT
eurjchem-2402	297	1	[	[	X
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eurjchem-2402	297	3	]	]	PUNCT
eurjchem-2402	297	4	.	.	PUNCT
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eurjchem-2402	298	4	;	;	PUNCT
eurjchem-2402	298	5	vancamp	vancamp	PROPN
eurjchem-2402	298	6	,	,	PUNCT
eurjchem-2402	298	7	l.	l.	PROPN
eurjchem-2402	298	8	;	;	PUNCT
eurjchem-2402	298	9	krigas	krigas	PROPN
eurjchem-2402	298	10	,	,	PUNCT
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eurjchem-2402	298	12	inhibition	inhibition	NOUN
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eurjchem-2402	298	16	in	in	ADP
eurjchem-2402	298	17	escherichia	escherichia	NOUN
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eurjchem-2402	300	19	.	.	PUNCT
eurjchem-2402	301	1	chem	chem	NOUN
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eurjchem-2402	302	2	.	.	PROPN
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eurjchem-2402	302	8	.	.	PUNCT
eurjchem-2402	303	1	[	[	X
eurjchem-2402	303	2	5	5	NUM
eurjchem-2402	303	3	]	]	PUNCT
eurjchem-2402	303	4	.	.	PUNCT
eurjchem-2402	304	1	mukhtar	mukhtar	PROPN
eurjchem-2402	304	2	,	,	PUNCT
eurjchem-2402	304	3	s.	s.	PROPN
eurjchem-2402	304	4	d.	d.	PROPN
eurjchem-2402	304	5	;	;	PUNCT
eurjchem-2402	304	6	suhail	suhail	PROPN
eurjchem-2402	304	7	,	,	PUNCT
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eurjchem-2402	304	12	drugs	drug	NOUN
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eurjchem-2402	304	14	a	a	DET
eurjchem-2402	304	15	briefreview	briefreview	NOUN
eurjchem-2402	304	16	.	.	PUNCT
eurjchem-2402	305	1	eur	eur	PROPN
eurjchem-2402	305	2	.	.	PUNCT
eurjchem-2402	306	1	j.	j.	PROPN
eurjchem-2402	306	2	chem	chem	PROPN
eurjchem-2402	306	3	.	.	PUNCT
eurjchem-2402	307	1	2022	2022	NUM
eurjchem-2402	307	2	,	,	PUNCT
eurjchem-2402	307	3	13	13	NUM
eurjchem-2402	307	4	,	,	PUNCT
eurjchem-2402	307	5	483–490	483–490	NUM
eurjchem-2402	307	6	.	.	PUNCT
eurjchem-2402	308	1	[	[	X
eurjchem-2402	308	2	6	6	NUM
eurjchem-2402	308	3	]	]	PUNCT
eurjchem-2402	308	4	.	.	PUNCT
eurjchem-2402	309	1	palchaudhuri	palchaudhuri	PROPN
eurjchem-2402	309	2	,	,	PUNCT
eurjchem-2402	309	3	r.	r.	PROPN
eurjchem-2402	309	4	;	;	PUNCT
eurjchem-2402	309	5	hergenrother	hergenrother	PROPN
eurjchem-2402	309	6	,	,	PUNCT
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eurjchem-2402	309	8	j.	j.	PROPN
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eurjchem-2402	309	15	compounds	compound	NOUN
eurjchem-2402	309	16	:	:	PUNCT
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eurjchem-2402	309	23	binding	bind	VERB
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eurjchem-2402	309	25	the	the	DET
eurjchem-2402	309	26	mechanism	mechanism	NOUN
eurjchem-2402	309	27	of	of	ADP
eurjchem-2402	309	28	action	action	NOUN
eurjchem-2402	309	29	.	.	PUNCT
eurjchem-2402	310	1	curr	curr	PROPN
eurjchem-2402	310	2	.	.	PUNCT
eurjchem-2402	311	1	opin	opin	NOUN
eurjchem-2402	311	2	.	.	PUNCT
eurjchem-2402	312	1	biotechnol	biotechnol	PROPN
eurjchem-2402	312	2	.	.	PUNCT
eurjchem-2402	313	1	2007	2007	NUM
eurjchem-2402	313	2	,	,	PUNCT
eurjchem-2402	313	3	18	18	NUM
eurjchem-2402	313	4	,	,	PUNCT
eurjchem-2402	313	5	497–503	497–503	NUM
eurjchem-2402	313	6	.	.	PUNCT
eurjchem-2402	314	1	[	[	X
eurjchem-2402	314	2	7	7	NUM
eurjchem-2402	314	3	]	]	PUNCT
eurjchem-2402	314	4	.	.	PUNCT
eurjchem-2402	314	5	reedijk	reedijk	PROPN
eurjchem-2402	314	6	,	,	PUNCT
eurjchem-2402	314	7	j.	j.	PROPN
eurjchem-2402	314	8	;	;	PUNCT
eurjchem-2402	314	9	lohman	lohman	PROPN
eurjchem-2402	314	10	,	,	PUNCT
eurjchem-2402	314	11	p.	p.	NOUN
eurjchem-2402	314	12	h.	h.	PROPN
eurjchem-2402	314	13	cisplatin	cisplatin	NOUN
eurjchem-2402	314	14	:	:	PUNCT
eurjchem-2402	314	15	synthesis	synthesis	NOUN
eurjchem-2402	314	16	,	,	PUNCT
eurjchem-2402	314	17	antitumour	antitumour	NOUN
eurjchem-2402	314	18	activity	activity	NOUN
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eurjchem-2402	314	20	mechanism	mechanism	NOUN
eurjchem-2402	314	21	of	of	ADP
eurjchem-2402	314	22	action	action	NOUN
eurjchem-2402	314	23	.	.	PUNCT
eurjchem-2402	315	1	pharm	pharm	NOUN
eurjchem-2402	315	2	.	.	PUNCT
eurjchem-2402	316	1	weekbl	weekbl	PROPN
eurjchem-2402	316	2	.	.	PUNCT
eurjchem-2402	317	1	sci	sci	PROPN
eurjchem-2402	317	2	.	.	PROPN
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eurjchem-2402	317	4	,	,	PUNCT
eurjchem-2402	317	5	7	7	NUM
eurjchem-2402	317	6	,	,	PUNCT
eurjchem-2402	317	7	173–180	173–180	NUM
eurjchem-2402	317	8	.	.	PUNCT
eurjchem-2402	318	1	[	[	X
eurjchem-2402	318	2	8	8	NUM
eurjchem-2402	318	3	]	]	PUNCT
eurjchem-2402	318	4	.	.	PUNCT
eurjchem-2402	319	1	rehman	rehman	PROPN
eurjchem-2402	319	2	,	,	PUNCT
eurjchem-2402	319	3	s.	s.	PROPN
eurjchem-2402	319	4	u.	u.	PROPN
eurjchem-2402	319	5	;	;	PUNCT
eurjchem-2402	319	6	sarwar	sarwar	PROPN
eurjchem-2402	319	7	,	,	PUNCT
eurjchem-2402	319	8	t.	t.	PROPN
eurjchem-2402	319	9	;	;	PUNCT
eurjchem-2402	319	10	husain	husain	PROPN
eurjchem-2402	319	11	,	,	PUNCT
eurjchem-2402	319	12	m.	m.	NOUN
eurjchem-2402	319	13	a.	a.	NOUN
eurjchem-2402	319	14	;	;	PUNCT
eurjchem-2402	319	15	ishqi	ishqi	PROPN
eurjchem-2402	319	16	,	,	PUNCT
eurjchem-2402	319	17	h.	h.	PROPN
eurjchem-2402	319	18	m.	m.	NOUN
eurjchem-2402	319	19	;	;	PUNCT
eurjchem-2402	319	20	tabish	tabish	PROPN
eurjchem-2402	319	21	,	,	PUNCT
eurjchem-2402	319	22	m.	m.	NOUN
eurjchem-2402	319	23	studying	study	VERB
eurjchem-2402	319	24	non	non	ADJ
eurjchem-2402	319	25	-	-	ADJ
eurjchem-2402	319	26	covalent	covalent	ADJ
eurjchem-2402	319	27	drug	drug	NOUN
eurjchem-2402	319	28	-	-	PUNCT
eurjchem-2402	319	29	dna	dna	NOUN
eurjchem-2402	319	30	interactions	interaction	NOUN
eurjchem-2402	319	31	.	.	PUNCT
eurjchem-2402	320	1	arch	arch	NOUN
eurjchem-2402	320	2	.	.	PUNCT
eurjchem-2402	321	1	biochem	biochem	PROPN
eurjchem-2402	321	2	.	.	PUNCT
eurjchem-2402	322	1	biophys	biophy	NOUN
eurjchem-2402	322	2	.	.	PUNCT
eurjchem-2402	323	1	2015	2015	NUM
eurjchem-2402	323	2	,	,	PUNCT
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eurjchem-2402	323	4	,	,	PUNCT
eurjchem-2402	323	5	49–60	49–60	NUM
eurjchem-2402	323	6	.	.	PUNCT
eurjchem-2402	324	1	[	[	X
eurjchem-2402	324	2	9	9	NUM
eurjchem-2402	324	3	]	]	PUNCT
eurjchem-2402	324	4	.	.	PUNCT
eurjchem-2402	325	1	el	el	NOUN
eurjchem-2402	325	2	-	-	PUNCT
eurjchem-2402	325	3	shekeil	shekeil	PROPN
eurjchem-2402	325	4	,	,	PUNCT
eurjchem-2402	325	5	a.	a.	NOUN
eurjchem-2402	325	6	g.	g.	PROPN
eurjchem-2402	325	7	;	;	PUNCT
eurjchem-2402	325	8	abubakr	abubakr	VERB
eurjchem-2402	325	9	,	,	PUNCT
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eurjchem-2402	325	11	o.	o.	PROPN
eurjchem-2402	325	12	;	;	PUNCT
eurjchem-2402	325	13	al	al	PROPN
eurjchem-2402	325	14	-	-	PUNCT
eurjchem-2402	325	15	aghbari	aghbari	PROPN
eurjchem-2402	325	16	,	,	PUNCT
eurjchem-2402	325	17	s.	s.	PROPN
eurjchem-2402	325	18	a.	a.	PROPN
eurjchem-2402	325	19	;	;	PUNCT
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eurjchem-2402	325	21	,	,	PUNCT
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eurjchem-2402	325	23	y.	y.	PROPN
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eurjchem-2402	325	26	:	:	PUNCT
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eurjchem-2402	325	28	and	and	CCONJ
eurjchem-2402	325	29	dna	dna	PROPN
eurjchem-2402	325	30	cleavage	cleavage	NOUN
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eurjchem-2402	325	35	schiff	schiff	NOUN
eurjchem-2402	325	36	base	base	NOUN
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eurjchem-2402	325	38	(	(	PUNCT
eurjchem-2402	325	39	iv	iv	NOUN
eurjchem-2402	325	40	)	)	PUNCT
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eurjchem-2402	325	42	.	.	PUNCT
eurjchem-2402	326	1	eur	eur	PROPN
eurjchem-2402	326	2	.	.	PUNCT
eurjchem-2402	327	1	j.	j.	PROPN
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eurjchem-2402	327	3	.	.	PUNCT
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eurjchem-2402	328	2	,	,	PUNCT
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eurjchem-2402	328	4	,	,	PUNCT
eurjchem-2402	328	5	410–414	410–414	NUM
eurjchem-2402	328	6	.	.	PUNCT
eurjchem-2402	329	1	[	[	X
eurjchem-2402	329	2	10	10	NUM
eurjchem-2402	329	3	]	]	PUNCT
eurjchem-2402	329	4	.	.	PUNCT
eurjchem-2402	330	1	geierstanger	geierstanger	PROPN
eurjchem-2402	330	2	,	,	PUNCT
eurjchem-2402	330	3	b.	b.	PROPN
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eurjchem-2402	330	5	;	;	PUNCT
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eurjchem-2402	330	7	,	,	PUNCT
eurjchem-2402	330	8	d.	d.	PROPN
eurjchem-2402	330	9	e.	e.	PROPN
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eurjchem-2402	330	12	the	the	DET
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eurjchem-2402	330	15	of	of	ADP
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eurjchem-2402	330	17	.	.	PUNCT
eurjchem-2402	331	1	annu	annu	PROPN
eurjchem-2402	331	2	.	.	PUNCT
eurjchem-2402	332	1	rev	rev	PROPN
eurjchem-2402	332	2	.	.	PROPN
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eurjchem-2402	332	4	.	.	PUNCT
eurjchem-2402	333	1	biomol	biomol	PROPN
eurjchem-2402	333	2	.	.	PUNCT
eurjchem-2402	333	3	struct	struct	NOUN
eurjchem-2402	333	4	.	.	PUNCT
eurjchem-2402	334	1	1995	1995	NUM
eurjchem-2402	334	2	,	,	PUNCT
eurjchem-2402	334	3	24	24	NUM
eurjchem-2402	334	4	,	,	PUNCT
eurjchem-2402	334	5	463–493	463–493	NUM
eurjchem-2402	334	6	.	.	PUNCT
eurjchem-2402	335	1	[	[	X
eurjchem-2402	335	2	11	11	NUM
eurjchem-2402	335	3	]	]	PUNCT
eurjchem-2402	335	4	.	.	PUNCT
eurjchem-2402	336	1	rupar	rupar	PROPN
eurjchem-2402	336	2	,	,	PUNCT
eurjchem-2402	336	3	j.	j.	PROPN
eurjchem-2402	336	4	;	;	PUNCT
eurjchem-2402	336	5	dobričić	dobričić	PROPN
eurjchem-2402	336	6	,	,	PUNCT
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eurjchem-2402	336	10	,	,	PUNCT
eurjchem-2402	336	11	j.	j.	PROPN
eurjchem-2402	336	12	;	;	PUNCT
eurjchem-2402	336	13	čudina	čudina	PROPN
eurjchem-2402	336	14	,	,	PUNCT
eurjchem-2402	336	15	o.	o.	PROPN
eurjchem-2402	336	16	;	;	PUNCT
eurjchem-2402	336	17	aleksić	aleksić	PROPN
eurjchem-2402	336	18	,	,	PUNCT
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eurjchem-2402	336	20	m.	m.	PROPN
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eurjchem-2402	336	23	voltammetric	voltammetric	PROPN
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eurjchem-2402	336	26	interaction	interaction	NOUN
eurjchem-2402	336	27	between	between	ADP
eurjchem-2402	336	28	9	9	NUM
eurjchem-2402	336	29	-	-	PUNCT
eurjchem-2402	336	30	acridinyl	acridinyl	NOUN
eurjchem-2402	336	31	amino	amino	NOUN
eurjchem-2402	336	32	acid	acid	NOUN
eurjchem-2402	336	33	derivatives	derivative	NOUN
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eurjchem-2402	336	36	.	.	PUNCT
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eurjchem-2402	337	3	,	,	PUNCT
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eurjchem-2402	337	5	,	,	PUNCT
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eurjchem-2402	337	7	.	.	PUNCT
eurjchem-2402	338	1	[	[	X
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eurjchem-2402	338	4	.	.	PUNCT
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eurjchem-2402	339	5	nmr	nmr	PROPN
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eurjchem-2402	339	9	—	—	PUNCT
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eurjchem-2402	339	12	.	.	PUNCT
eurjchem-2402	340	1	prog	prog	NOUN
eurjchem-2402	340	2	.	.	PUNCT
eurjchem-2402	340	3	nucl	nucl	PROPN
eurjchem-2402	340	4	.	.	PUNCT
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eurjchem-2402	341	2	.	.	PUNCT
eurjchem-2402	342	1	reson	reson	PROPN
eurjchem-2402	342	2	.	.	PUNCT
eurjchem-2402	343	1	spectrosc	spectrosc	PROPN
eurjchem-2402	343	2	.	.	PUNCT
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eurjchem-2402	344	2	,	,	PUNCT
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eurjchem-2402	344	6	.	.	PUNCT
eurjchem-2402	345	1	[	[	X
eurjchem-2402	345	2	13	13	NUM
eurjchem-2402	345	3	]	]	PUNCT
eurjchem-2402	345	4	.	.	PUNCT
eurjchem-2402	346	1	sirajuddin	sirajuddin	PROPN
eurjchem-2402	346	2	,	,	PUNCT
eurjchem-2402	346	3	m.	m.	NOUN
eurjchem-2402	346	4	;	;	PUNCT
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eurjchem-2402	346	10	,	,	PUNCT
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eurjchem-2402	346	23	,	,	PUNCT
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eurjchem-2402	346	29	.	.	PUNCT
eurjchem-2402	347	1	j.	j.	PROPN
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eurjchem-2402	347	3	.	.	PUNCT
eurjchem-2402	348	1	photobiol	photobiol	PROPN
eurjchem-2402	348	2	.	.	PUNCT
eurjchem-2402	349	1	b	b	X
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eurjchem-2402	349	3	,	,	PUNCT
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eurjchem-2402	349	5	,	,	PUNCT
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eurjchem-2402	349	7	.	.	PUNCT
eurjchem-2402	350	1	[	[	X
eurjchem-2402	350	2	14	14	NUM
eurjchem-2402	350	3	]	]	PUNCT
eurjchem-2402	350	4	.	.	PUNCT
eurjchem-2402	351	1	gonçalves	gonçalves	PROPN
eurjchem-2402	351	2	,	,	PUNCT
eurjchem-2402	351	3	g.	g.	PROPN
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eurjchem-2402	351	5	;	;	PUNCT
eurjchem-2402	351	6	de	de	X
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eurjchem-2402	351	9	a.	a.	PROPN
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eurjchem-2402	351	11	;	;	PUNCT
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eurjchem-2402	351	13	,	,	PUNCT
eurjchem-2402	351	14	j.	j.	PROPN
eurjchem-2402	351	15	;	;	PUNCT
eurjchem-2402	351	16	oliveira	oliveira	PROPN
eurjchem-2402	351	17	,	,	PUNCT
eurjchem-2402	351	18	k.	k.	PROPN
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eurjchem-2402	351	20	;	;	PUNCT
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eurjchem-2402	351	23	r.	r.	PROPN
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eurjchem-2402	351	29	six	six	NUM
eurjchem-2402	351	30	-	-	PUNCT
eurjchem-2402	351	31	coordinated	coordinate	VERB
eurjchem-2402	351	32	bis(5,5′-dimethyl-2,2′bipyridine	bis(5,5′-dimethyl-2,2′bipyridine	NOUN
eurjchem-2402	351	33	)	)	PUNCT
eurjchem-2402	351	34	nitratocopper(ii	nitratocopper(ii	ADJ
eurjchem-2402	351	35	)	)	PUNCT
eurjchem-2402	351	36	nitrate	nitrate	NOUN
eurjchem-2402	351	37	and	and	CCONJ
eurjchem-2402	351	38	its	its	PRON
eurjchem-2402	351	39	dna	dna	PROPN
eurjchem-2402	351	40	interactions	interaction	NOUN
eurjchem-2402	351	41	.	.	PUNCT
eurjchem-2402	352	1	j.	j.	PROPN
eurjchem-2402	352	2	mol	mol	PROPN
eurjchem-2402	352	3	.	.	PROPN
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eurjchem-2402	352	5	.	.	PUNCT
eurjchem-2402	352	6	2021	2021	NUM
eurjchem-2402	352	7	,	,	PUNCT
eurjchem-2402	352	8	1224	1224	NUM
eurjchem-2402	352	9	,	,	PUNCT
eurjchem-2402	352	10	129035	129035	NUM
eurjchem-2402	352	11	.	.	PUNCT
eurjchem-2402	353	1	[	[	X
eurjchem-2402	353	2	15	15	NUM
eurjchem-2402	353	3	]	]	PUNCT
eurjchem-2402	353	4	.	.	PUNCT
eurjchem-2402	354	1	oliveira	oliveira	PROPN
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eurjchem-2402	354	3	k.	k.	PROPN
eurjchem-2402	354	4	m.	m.	PROPN
eurjchem-2402	354	5	;	;	PUNCT
eurjchem-2402	354	6	honorato	honorato	PROPN
eurjchem-2402	354	7	,	,	PUNCT
eurjchem-2402	354	8	j.	j.	PROPN
eurjchem-2402	354	9	;	;	PUNCT
eurjchem-2402	354	10	gonçalves	gonçalves	PROPN
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eurjchem-2402	354	14	;	;	PUNCT
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eurjchem-2402	354	18	r.	r.	PROPN
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eurjchem-2402	355	1	dalton	dalton	PROPN
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eurjchem-2402	356	6	.	.	PUNCT
eurjchem-2402	357	1	[	[	X
eurjchem-2402	357	2	16	16	NUM
eurjchem-2402	357	3	]	]	PUNCT
eurjchem-2402	357	4	.	.	PUNCT
eurjchem-2402	358	1	hartinger	hartinger	PROPN
eurjchem-2402	358	2	,	,	PUNCT
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eurjchem-2402	358	12	,	,	PUNCT
eurjchem-2402	358	13	b.	b.	PROPN
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eurjchem-2402	359	5	-	-	ADJ
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eurjchem-2402	359	8	research	research	NOUN
eurjchem-2402	359	9	:	:	PUNCT
eurjchem-2402	359	10	advances	advance	NOUN
eurjchem-2402	359	11	and	and	CCONJ
eurjchem-2402	359	12	future	future	ADJ
eurjchem-2402	359	13	challenges	challenge	NOUN
eurjchem-2402	359	14	.	.	PUNCT
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eurjchem-2402	360	3	,	,	PUNCT
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eurjchem-2402	360	5	,	,	PUNCT
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eurjchem-2402	360	7	.	.	PUNCT
eurjchem-2402	361	1	[	[	X
eurjchem-2402	361	2	17	17	NUM
eurjchem-2402	361	3	]	]	PUNCT
eurjchem-2402	361	4	.	.	PUNCT
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eurjchem-2402	362	2	,	,	PUNCT
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eurjchem-2402	362	4	;	;	PUNCT
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eurjchem-2402	362	8	;	;	PUNCT
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eurjchem-2402	362	12	;	;	PUNCT
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eurjchem-2402	362	16	;	;	PUNCT
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eurjchem-2402	362	24	,	,	PUNCT
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eurjchem-2402	365	2	,	,	PUNCT
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eurjchem-2402	365	4	,	,	PUNCT
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eurjchem-2402	366	4	.	.	PUNCT
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eurjchem-2402	367	5	;	;	PUNCT
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eurjchem-2402	367	7	,	,	PUNCT
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eurjchem-2402	367	9	;	;	PUNCT
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eurjchem-2402	369	2	.	.	PUNCT
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eurjchem-2402	370	2	,	,	PUNCT
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eurjchem-2402	371	1	[	[	X
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eurjchem-2402	371	3	]	]	PUNCT
eurjchem-2402	371	4	.	.	PUNCT
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eurjchem-2402	372	2	,	,	PUNCT
eurjchem-2402	372	3	k.	k.	PROPN
eurjchem-2402	372	4	m.	m.	PROPN
eurjchem-2402	372	5	;	;	PUNCT
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eurjchem-2402	372	7	,	,	PUNCT
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eurjchem-2402	372	10	;	;	PUNCT
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eurjchem-2402	372	15	;	;	PUNCT
eurjchem-2402	372	16	cominetti	cominetti	PROPN
eurjchem-2402	372	17	,	,	PUNCT
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eurjchem-2402	372	20	;	;	PUNCT
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eurjchem-2402	372	64	(	(	PUNCT
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eurjchem-2402	372	66	)	)	PUNCT
eurjchem-2402	372	67	(	(	PUNCT
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eurjchem-2402	372	69	)	)	PUNCT
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eurjchem-2402	372	75	–	–	PUNCT
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eurjchem-2402	372	84	–	–	PUNCT
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eurjchem-2402	372	88	/	/	SYM
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eurjchem-2402	372	90	-	-	SYM
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eurjchem-2402	374	2	,	,	PUNCT
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eurjchem-2402	374	6	.	.	PUNCT
eurjchem-2402	375	1	[	[	X
eurjchem-2402	375	2	20	20	NUM
eurjchem-2402	375	3	]	]	PUNCT
eurjchem-2402	375	4	.	.	PUNCT
eurjchem-2402	375	5	carvalho	carvalho	PROPN
eurjchem-2402	375	6	,	,	PUNCT
eurjchem-2402	375	7	d.	d.	PROPN
eurjchem-2402	375	8	e.	e.	PROPN
eurjchem-2402	375	9	l.	l.	PROPN
eurjchem-2402	375	10	;	;	PUNCT
eurjchem-2402	375	11	oliveira	oliveira	PROPN
eurjchem-2402	375	12	,	,	PUNCT
eurjchem-2402	375	13	k.	k.	PROPN
eurjchem-2402	375	14	m.	m.	PROPN
eurjchem-2402	375	15	;	;	PUNCT
eurjchem-2402	375	16	bomfim	bomfim	NOUN
eurjchem-2402	375	17	,	,	PUNCT
eurjchem-2402	375	18	l.	l.	PROPN
eurjchem-2402	375	19	m.	m.	PROPN
eurjchem-2402	375	20	;	;	PUNCT
eurjchem-2402	375	21	soares	soare	NOUN
eurjchem-2402	375	22	,	,	PUNCT
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eurjchem-2402	376	4	,	,	PUNCT
eurjchem-2402	376	5	d.	d.	PROPN
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eurjchem-2402	376	7	;	;	PUNCT
eurjchem-2402	376	8	batista	batista	PROPN
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eurjchem-2402	376	10	a.	a.	NOUN
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eurjchem-2402	376	13	correa	correa	PROPN
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eurjchem-2402	376	15	r.	r.	PROPN
eurjchem-2402	376	16	s.	s.	PROPN
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eurjchem-2402	377	1	acs	acs	PROPN
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eurjchem-2402	377	4	,	,	PUNCT
eurjchem-2402	377	5	5	5	NUM
eurjchem-2402	377	6	,	,	PUNCT
eurjchem-2402	377	7	122–130	122–130	NUM
eurjchem-2402	377	8	.	.	PUNCT
eurjchem-2402	378	1	[	[	X
eurjchem-2402	378	2	21	21	NUM
eurjchem-2402	378	3	]	]	PUNCT
eurjchem-2402	378	4	.	.	PUNCT
eurjchem-2402	379	1	graminha	graminha	NOUN
eurjchem-2402	379	2	,	,	PUNCT
eurjchem-2402	379	3	a.	a.	PROPN
eurjchem-2402	379	4	e.	e.	PROPN
eurjchem-2402	379	5	;	;	PUNCT
eurjchem-2402	379	6	popolin	popolin	PROPN
eurjchem-2402	379	7	,	,	PUNCT
eurjchem-2402	379	8	c.	c.	PROPN
eurjchem-2402	379	9	;	;	PUNCT
eurjchem-2402	379	10	honorato	honorato	PROPN
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eurjchem-2402	379	12	araujo	araujo	PROPN
eurjchem-2402	379	13	-	-	PUNCT
eurjchem-2402	379	14	neto	neto	NOUN
eurjchem-2402	379	15	,	,	PUNCT
eurjchem-2402	379	16	j.	j.	PROPN
eurjchem-2402	379	17	;	;	PUNCT
eurjchem-2402	379	18	correa	correa	PROPN
eurjchem-2402	379	19	,	,	PUNCT
eurjchem-2402	379	20	r.	r.	PROPN
eurjchem-2402	379	21	s.	s.	PROPN
eurjchem-2402	379	22	;	;	PUNCT
eurjchem-2402	379	23	de	de	PROPN
eurjchem-2402	379	24	oliveira	oliveira	PROPN
eurjchem-2402	379	25	,	,	PUNCT
eurjchem-2402	379	26	k.	k.	PROPN
eurjchem-2402	379	27	m.	m.	PROPN
eurjchem-2402	379	28	;	;	PUNCT
eurjchem-2402	379	29	godoy	godoy	PROPN
eurjchem-2402	379	30	,	,	PUNCT
eurjchem-2402	379	31	l.	l.	PROPN
eurjchem-2402	379	32	r.	r.	PROPN
eurjchem-2402	379	33	;	;	PUNCT
eurjchem-2402	379	34	vegas	vegas	PROPN
eurjchem-2402	379	35	,	,	PUNCT
eurjchem-2402	379	36	l.	l.	PROPN
eurjchem-2402	379	37	c.	c.	PROPN
eurjchem-2402	379	38	;	;	PUNCT
eurjchem-2402	379	39	ellena	ellena	PROPN
eurjchem-2402	379	40	,	,	PUNCT
eurjchem-2402	379	41	j.	j.	PROPN
eurjchem-2402	379	42	;	;	PUNCT
eurjchem-2402	379	43	batista	batista	PROPN
eurjchem-2402	379	44	,	,	PUNCT
eurjchem-2402	379	45	a.	a.	NOUN
eurjchem-2402	379	46	a.	a.	PROPN
eurjchem-2402	379	47	;	;	PUNCT
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eurjchem-2402	379	49	,	,	PUNCT
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eurjchem-2402	379	51	r.	r.	PROPN
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eurjchem-2402	379	57	acid	acid	NOUN
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eurjchem-2402	379	61	triple	triple	ADJ
eurjchem-2402	379	62	-	-	PUNCT
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eurjchem-2402	379	65	cell	cell	NOUN
eurjchem-2402	379	66	death	death	NOUN
eurjchem-2402	379	67	via	via	ADP
eurjchem-2402	379	68	the	the	DET
eurjchem-2402	379	69	intrinsic	intrinsic	ADJ
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eurjchem-2402	379	71	pathway	pathway	NOUN
eurjchem-2402	379	72	.	.	PUNCT
eurjchem-2402	380	1	eur	eur	PROPN
eurjchem-2402	380	2	.	.	PUNCT
eurjchem-2402	381	1	j.	j.	PROPN
eurjchem-2402	381	2	med	med	PROPN
eurjchem-2402	381	3	.	.	PROPN
eurjchem-2402	381	4	chem	chem	PROPN
eurjchem-2402	381	5	.	.	PUNCT
eurjchem-2402	382	1	2022	2022	NUM
eurjchem-2402	382	2	,	,	PUNCT
eurjchem-2402	382	3	243	243	NUM
eurjchem-2402	382	4	,	,	PUNCT
eurjchem-2402	382	5	114772	114772	NUM
eurjchem-2402	382	6	.	.	PUNCT
eurjchem-2402	383	1	[	[	X
eurjchem-2402	383	2	22	22	NUM
eurjchem-2402	383	3	]	]	PUNCT
eurjchem-2402	383	4	.	.	PUNCT
eurjchem-2402	384	1	da	da	PROPN
eurjchem-2402	384	2	silva	silva	PROPN
eurjchem-2402	384	3	,	,	PUNCT
eurjchem-2402	384	4	m.	m.	NOUN
eurjchem-2402	384	5	m.	m.	NOUN
eurjchem-2402	384	6	;	;	PUNCT
eurjchem-2402	384	7	ribeiro	ribeiro	PROPN
eurjchem-2402	384	8	,	,	PUNCT
eurjchem-2402	384	9	g.	g.	PROPN
eurjchem-2402	384	10	h.	h.	PROPN
eurjchem-2402	384	11	;	;	PUNCT
eurjchem-2402	384	12	de	de	PROPN
eurjchem-2402	384	13	camargo	camargo	PROPN
eurjchem-2402	384	14	,	,	PUNCT
eurjchem-2402	384	15	m.	m.	PROPN
eurjchem-2402	384	16	s.	s.	PROPN
eurjchem-2402	384	17	;	;	PUNCT
eurjchem-2402	384	18	ferreira	ferreira	PROPN
eurjchem-2402	384	19	,	,	PUNCT
eurjchem-2402	384	20	a.	a.	NOUN
eurjchem-2402	384	21	g.	g.	PROPN
eurjchem-2402	384	22	;	;	PUNCT
eurjchem-2402	384	23	ribeiro	ribeiro	PROPN
eurjchem-2402	384	24	,	,	PUNCT
eurjchem-2402	384	25	l.	l.	PROPN
eurjchem-2402	384	26	;	;	PUNCT
eurjchem-2402	384	27	barbosa	barbosa	PROPN
eurjchem-2402	384	28	,	,	PUNCT
eurjchem-2402	384	29	m.	m.	PROPN
eurjchem-2402	384	30	i.	i.	PROPN
eurjchem-2402	384	31	f.	f.	PROPN
eurjchem-2402	384	32	;	;	PUNCT
eurjchem-2402	384	33	deflon	deflon	PROPN
eurjchem-2402	384	34	,	,	PUNCT
eurjchem-2402	384	35	v.	v.	ADP
eurjchem-2402	384	36	m.	m.	NOUN
eurjchem-2402	384	37	;	;	PUNCT
eurjchem-2402	384	38	castelli	castelli	PROPN
eurjchem-2402	384	39	,	,	PUNCT
eurjchem-2402	384	40	s.	s.	PROPN
eurjchem-2402	384	41	;	;	PUNCT
eurjchem-2402	384	42	desideri	desideri	PROPN
eurjchem-2402	384	43	,	,	PUNCT
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eurjchem-2402	384	45	;	;	PUNCT
eurjchem-2402	384	46	corrêa	corrêa	PROPN
eurjchem-2402	384	47	,	,	PUNCT
eurjchem-2402	384	48	r.	r.	PROPN
eurjchem-2402	384	49	s.	s.	PROPN
eurjchem-2402	384	50	;	;	PUNCT
eurjchem-2402	384	51	ribeiro	ribeiro	PROPN
eurjchem-2402	384	52	,	,	PUNCT
eurjchem-2402	384	53	a.	a.	PROPN
eurjchem-2402	384	54	b.	b.	PROPN
eurjchem-2402	384	55	;	;	PUNCT
eurjchem-2402	384	56	nicolella	nicolella	PROPN
eurjchem-2402	384	57	,	,	PUNCT
eurjchem-2402	384	58	h.	h.	PROPN
eurjchem-2402	384	59	d.	d.	PROPN
eurjchem-2402	384	60	;	;	PUNCT
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eurjchem-2402	384	63	s.	s.	PROPN
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eurjchem-2402	384	65	;	;	PUNCT
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eurjchem-2402	384	67	,	,	PUNCT
eurjchem-2402	384	68	d.	d.	PROPN
eurjchem-2402	384	69	c.	c.	PROPN
eurjchem-2402	384	70	;	;	PUNCT
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eurjchem-2402	384	72	,	,	PUNCT
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eurjchem-2402	384	79	with	with	ADP
eurjchem-2402	384	80	mercapto	mercapto	NOUN
eurjchem-2402	384	81	ligands	ligand	NOUN
eurjchem-2402	384	82	that	that	PRON
eurjchem-2402	384	83	inhibit	inhibit	VERB
eurjchem-2402	384	84	topoisomerase	topoisomerase	NOUN
eurjchem-2402	384	85	ib	ib	NOUN
eurjchem-2402	384	86	and	and	CCONJ
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eurjchem-2402	384	89	growth	growth	NOUN
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eurjchem-2402	384	91	vivo	vivo	NOUN
eurjchem-2402	384	92	.	.	PUNCT
eurjchem-2402	385	1	inorg	inorg	PROPN
eurjchem-2402	385	2	.	.	PUNCT
eurjchem-2402	386	1	chem	chem	PROPN
eurjchem-2402	386	2	.	.	PUNCT
eurjchem-2402	387	1	2021	2021	NUM
eurjchem-2402	387	2	,	,	PUNCT
eurjchem-2402	387	3	60	60	NUM
eurjchem-2402	387	4	,	,	PUNCT
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eurjchem-2402	387	6	.	.	PUNCT
eurjchem-2402	388	1	[	[	X
eurjchem-2402	388	2	23	23	NUM
eurjchem-2402	388	3	]	]	PUNCT
eurjchem-2402	388	4	.	.	PUNCT
eurjchem-2402	389	1	bautista	bautista	PROPN
eurjchem-2402	389	2	,	,	PUNCT
eurjchem-2402	389	3	m.	m.	NOUN
eurjchem-2402	389	4	t.	t.	PROPN
eurjchem-2402	389	5	;	;	PUNCT
eurjchem-2402	389	6	cappellani	cappellani	PROPN
eurjchem-2402	389	7	,	,	PUNCT
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eurjchem-2402	389	20	;	;	PUNCT
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eurjchem-2402	389	22	,	,	PUNCT
eurjchem-2402	389	23	c.	c.	PROPN
eurjchem-2402	389	24	t.	t.	PROPN
eurjchem-2402	389	25	;	;	PUNCT
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eurjchem-2402	389	49	+	+	CCONJ
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eurjchem-2402	389	52	=	=	NOUN
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eurjchem-2402	389	54	,	,	PUNCT
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eurjchem-2402	389	56	;	;	PUNCT
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eurjchem-2402	389	58	=	=	SYM
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eurjchem-2402	389	60	,	,	PUNCT
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eurjchem-2402	389	64	trends	trend	NOUN
eurjchem-2402	389	65	in	in	ADP
eurjchem-2402	389	66	properties	property	NOUN
eurjchem-2402	389	67	down	down	ADP
eurjchem-2402	389	68	the	the	DET
eurjchem-2402	389	69	iron	iron	NOUN
eurjchem-2402	389	70	group	group	NOUN
eurjchem-2402	389	71	triad	triad	PROPN
eurjchem-2402	389	72	.	.	PUNCT
eurjchem-2402	390	1	j.	j.	PROPN
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eurjchem-2402	390	3	.	.	PUNCT
eurjchem-2402	391	1	chem	chem	NOUN
eurjchem-2402	391	2	.	.	PUNCT
eurjchem-2402	392	1	soc	soc	PROPN
eurjchem-2402	392	2	.	.	PUNCT
eurjchem-2402	393	1	1991	1991	NUM
eurjchem-2402	393	2	,	,	PUNCT
eurjchem-2402	393	3	113	113	NUM
eurjchem-2402	393	4	,	,	PUNCT
eurjchem-2402	393	5	4876–4887	4876–4887	NUM
eurjchem-2402	393	6	.	.	PUNCT
eurjchem-2402	394	1	[	[	X
eurjchem-2402	394	2	24	24	NUM
eurjchem-2402	394	3	]	]	PUNCT
eurjchem-2402	394	4	.	.	PUNCT
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eurjchem-2402	394	6	,	,	PUNCT
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eurjchem-2402	394	8	m.	m.	PROPN
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eurjchem-2402	396	1	c	c	PROPN
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eurjchem-2402	398	2	,	,	PUNCT
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eurjchem-2402	399	1	[	[	X
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eurjchem-2402	399	3	]	]	PUNCT
eurjchem-2402	399	4	.	.	PUNCT
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eurjchem-2402	400	5	;	;	PUNCT
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eurjchem-2402	400	10	;	;	PUNCT
eurjchem-2402	400	11	chisholm	chisholm	PROPN
eurjchem-2402	400	12	,	,	PUNCT
eurjchem-2402	400	13	j.	j.	PROPN
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eurjchem-2402	400	15	;	;	PUNCT
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eurjchem-2402	400	18	p.	p.	PROPN
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eurjchem-2402	400	20	;	;	PUNCT
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eurjchem-2402	400	24	;	;	PUNCT
eurjchem-2402	400	25	pidcock	pidcock	PROPN
eurjchem-2402	400	26	,	,	PUNCT
eurjchem-2402	400	27	e.	e.	PROPN
eurjchem-2402	400	28	;	;	PUNCT
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eurjchem-2402	400	37	r.	r.	PROPN
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eurjchem-2402	400	42	,	,	PUNCT
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eurjchem-2402	401	5	.	.	PUNCT
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eurjchem-2402	402	2	,	,	PUNCT
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eurjchem-2402	402	4	,	,	PUNCT
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eurjchem-2402	402	6	–	–	PUNCT
eurjchem-2402	402	7	470	470	NUM
eurjchem-2402	402	8	.	.	PUNCT
eurjchem-2402	403	1	[	[	X
eurjchem-2402	403	2	26	26	NUM
eurjchem-2402	403	3	]	]	PUNCT
eurjchem-2402	403	4	.	.	PUNCT
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eurjchem-2402	404	2	,	,	PUNCT
eurjchem-2402	404	3	s.	s.	PROPN
eurjchem-2402	404	4	h.	h.	PROPN
eurjchem-2402	404	5	;	;	PUNCT
eurjchem-2402	404	6	abdel	abdel	PROPN
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eurjchem-2402	404	25	)	)	PUNCT
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eurjchem-2402	404	28	)	)	PUNCT
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eurjchem-2402	404	30	cu(ii	cu(ii	PROPN
eurjchem-2402	404	31	)	)	PUNCT
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eurjchem-2402	404	34	)	)	PUNCT
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eurjchem-2402	404	41	n2s2	n2s2	PROPN
eurjchem-2402	404	42	.	.	PROPN
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eurjchem-2402	405	1	j.	j.	PROPN
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eurjchem-2402	406	2	,	,	PUNCT
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eurjchem-2402	406	6	.	.	PUNCT
eurjchem-2402	407	1	[	[	X
eurjchem-2402	407	2	27	27	NUM
eurjchem-2402	407	3	]	]	PUNCT
eurjchem-2402	407	4	.	.	PUNCT
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eurjchem-2402	408	2	,	,	PUNCT
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eurjchem-2402	408	17	)	)	PUNCT
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eurjchem-2402	408	20	)	)	PUNCT
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eurjchem-2402	408	22	mn(ii	mn(ii	PROPN
eurjchem-2402	408	23	)	)	PUNCT
eurjchem-2402	408	24	,	,	PUNCT
eurjchem-2402	408	25	zn(ii	zn(ii	NUM
eurjchem-2402	408	26	)	)	PUNCT
eurjchem-2402	408	27	and	and	CCONJ
eurjchem-2402	408	28	vo(ii	vo(ii	NOUN
eurjchem-2402	408	29	)	)	PUNCT
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eurjchem-2402	408	35	.	.	PUNCT
eurjchem-2402	409	1	eur	eur	PROPN
eurjchem-2402	409	2	.	.	PUNCT
eurjchem-2402	410	1	j.	j.	PROPN
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eurjchem-2402	412	1	[	[	X
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eurjchem-2402	412	3	]	]	PUNCT
eurjchem-2402	412	4	.	.	PUNCT
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eurjchem-2402	413	13	i.	i.	PROPN
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eurjchem-2402	413	15	;	;	PUNCT
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eurjchem-2402	413	41	;	;	PUNCT
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eurjchem-2402	413	47	)	)	PUNCT
eurjchem-2402	413	48	–	–	PUNCT
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eurjchem-2402	413	58	.	.	PUNCT
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eurjchem-2402	415	2	,	,	PUNCT
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eurjchem-2402	415	4	,	,	PUNCT
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eurjchem-2402	415	6	.	.	PUNCT
eurjchem-2402	416	1	[	[	X
eurjchem-2402	416	2	29	29	NUM
eurjchem-2402	416	3	]	]	PUNCT
eurjchem-2402	416	4	.	.	PUNCT
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eurjchem-2402	417	2	,	,	PUNCT
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eurjchem-2402	417	4	.	.	PUNCT
eurjchem-2402	417	5	;	;	PUNCT
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eurjchem-2402	417	7	,	,	PUNCT
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eurjchem-2402	417	9	;	;	PUNCT
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eurjchem-2402	417	13	;	;	PUNCT
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eurjchem-2402	422	2	,	,	PUNCT
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eurjchem-2402	423	4	.	.	PUNCT
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eurjchem-2402	424	5	;	;	PUNCT
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eurjchem-2402	424	13	displacement	displacement	NOUN
eurjchem-2402	424	14	assay	assay	VERB
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eurjchem-2402	426	2	.	.	PUNCT
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eurjchem-2402	426	4	,	,	PUNCT
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eurjchem-2402	427	4	.	.	PUNCT
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eurjchem-2402	428	5	;	;	PUNCT
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eurjchem-2402	429	19	osii	osii	PROPN
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eurjchem-2402	429	21	.	.	PUNCT
eurjchem-2402	430	1	inorg	inorg	PROPN
eurjchem-2402	430	2	.	.	PUNCT
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eurjchem-2402	431	2	.	.	PUNCT
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eurjchem-2402	432	6	.	.	PUNCT
eurjchem-2402	433	1	[	[	X
eurjchem-2402	433	2	32	32	NUM
eurjchem-2402	433	3	]	]	PUNCT
eurjchem-2402	433	4	.	.	PUNCT
eurjchem-2402	434	1	lu	lu	PROPN
eurjchem-2402	434	2	,	,	PUNCT
eurjchem-2402	434	3	x.	x.	PROPN
eurjchem-2402	434	4	;	;	PUNCT
eurjchem-2402	434	5	zhu	zhu	PROPN
eurjchem-2402	434	6	,	,	PUNCT
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eurjchem-2402	434	8	;	;	PUNCT
eurjchem-2402	434	9	zhang	zhang	PROPN
eurjchem-2402	434	10	,	,	PUNCT
eurjchem-2402	434	11	m.	m.	NOUN
eurjchem-2402	434	12	;	;	PUNCT
eurjchem-2402	434	13	liu	liu	PROPN
eurjchem-2402	434	14	,	,	PUNCT
eurjchem-2402	434	15	h.	h.	PROPN
eurjchem-2402	434	16	;	;	PUNCT
eurjchem-2402	434	17	kang	kang	PROPN
eurjchem-2402	434	18	,	,	PUNCT
eurjchem-2402	434	19	j.	j.	PROPN
eurjchem-2402	434	20	voltammetric	voltammetric	PROPN
eurjchem-2402	434	21	studies	study	NOUN
eurjchem-2402	434	22	of	of	ADP
eurjchem-2402	434	23	the	the	DET
eurjchem-2402	434	24	interaction	interaction	NOUN
eurjchem-2402	434	25	of	of	ADP
eurjchem-2402	434	26	transition	transition	NOUN
eurjchem-2402	434	27	-	-	PUNCT
eurjchem-2402	434	28	metal	metal	NOUN
eurjchem-2402	434	29	complexes	complex	NOUN
eurjchem-2402	434	30	with	with	ADP
eurjchem-2402	434	31	dna	dna	PROPN
eurjchem-2402	434	32	.	.	PUNCT
eurjchem-2402	435	1	j.	j.	PROPN
eurjchem-2402	435	2	biochem	biochem	PROPN
eurjchem-2402	435	3	.	.	PUNCT
eurjchem-2402	436	1	biophys	biophy	NOUN
eurjchem-2402	436	2	.	.	PUNCT
eurjchem-2402	437	1	methods	method	NOUN
eurjchem-2402	437	2	2002	2002	NUM
eurjchem-2402	437	3	,	,	PUNCT
eurjchem-2402	437	4	52	52	NUM
eurjchem-2402	437	5	,	,	PUNCT
eurjchem-2402	437	6	189–200	189–200	NUM
eurjchem-2402	437	7	.	.	PUNCT
eurjchem-2402	438	1	[	[	X
eurjchem-2402	438	2	33	33	NUM
eurjchem-2402	438	3	]	]	PUNCT
eurjchem-2402	438	4	.	.	PUNCT
eurjchem-2402	439	1	barbosa	barbosa	PROPN
eurjchem-2402	439	2	,	,	PUNCT
eurjchem-2402	439	3	m.	m.	PROPN
eurjchem-2402	439	4	i.	i.	PROPN
eurjchem-2402	439	5	f.	f.	PROPN
eurjchem-2402	439	6	;	;	PUNCT
eurjchem-2402	439	7	corrêa	corrêa	PROPN
eurjchem-2402	439	8	,	,	PUNCT
eurjchem-2402	439	9	r.	r.	PROPN
eurjchem-2402	439	10	s.	s.	PROPN
eurjchem-2402	439	11	;	;	PUNCT
eurjchem-2402	439	12	de	de	PROPN
eurjchem-2402	439	13	oliveira	oliveira	PROPN
eurjchem-2402	439	14	,	,	PUNCT
eurjchem-2402	439	15	k.	k.	PROPN
eurjchem-2402	439	16	m.	m.	PROPN
eurjchem-2402	439	17	;	;	PUNCT
eurjchem-2402	439	18	rodrigues	rodrigues	PROPN
eurjchem-2402	439	19	,	,	PUNCT
eurjchem-2402	439	20	c.	c.	PROPN
eurjchem-2402	439	21	;	;	PUNCT
eurjchem-2402	439	22	ellena	ellena	PROPN
eurjchem-2402	439	23	,	,	PUNCT
eurjchem-2402	439	24	j.	j.	PROPN
eurjchem-2402	439	25	;	;	PUNCT
eurjchem-2402	439	26	nascimento	nascimento	PROPN
eurjchem-2402	439	27	,	,	PUNCT
eurjchem-2402	439	28	o.	o.	PROPN
eurjchem-2402	439	29	r.	r.	PROPN
eurjchem-2402	439	30	;	;	PUNCT
eurjchem-2402	439	31	rocha	rocha	PROPN
eurjchem-2402	439	32	,	,	PUNCT
eurjchem-2402	439	33	v.	v.	PROPN
eurjchem-2402	439	34	p.	p.	PROPN
eurjchem-2402	439	35	c.	c.	PROPN
eurjchem-2402	439	36	;	;	PUNCT
eurjchem-2402	439	37	nonato	nonato	PROPN
eurjchem-2402	439	38	,	,	PUNCT
eurjchem-2402	439	39	f.	f.	PROPN
eurjchem-2402	439	40	r.	r.	PROPN
eurjchem-2402	439	41	;	;	PUNCT
eurjchem-2402	439	42	macedo	macedo	PROPN
eurjchem-2402	439	43	,	,	PUNCT
eurjchem-2402	439	44	t.	t.	PROPN
eurjchem-2402	439	45	s.	s.	PROPN
eurjchem-2402	439	46	;	;	PUNCT
eurjchem-2402	439	47	barbosa	barbosa	PROPN
eurjchem-2402	439	48	-	-	PUNCT
eurjchem-2402	439	49	filho	filho	PROPN
eurjchem-2402	439	50	,	,	PUNCT
eurjchem-2402	439	51	j.	j.	PROPN
eurjchem-2402	439	52	m.	m.	PROPN
eurjchem-2402	439	53	;	;	PUNCT
eurjchem-2402	439	54	soares	soare	NOUN
eurjchem-2402	439	55	,	,	PUNCT
eurjchem-2402	439	56	m.	m.	PROPN
eurjchem-2402	439	57	b.	b.	PROPN
eurjchem-2402	440	1	p.	p.	PROPN
eurjchem-2402	440	2	;	;	PUNCT
eurjchem-2402	440	3	batista	batista	PROPN
eurjchem-2402	440	4	,	,	PUNCT
eurjchem-2402	440	5	a.	a.	NOUN
eurjchem-2402	440	6	a.	a.	NOUN
eurjchem-2402	440	7	antiparasitic	antiparasitic	ADJ
eurjchem-2402	440	8	activities	activity	NOUN
eurjchem-2402	440	9	of	of	ADP
eurjchem-2402	440	10	novel	novel	ADJ
eurjchem-2402	440	11	ruthenium	ruthenium	NOUN
eurjchem-2402	440	12	/	/	SYM
eurjchem-2402	440	13	lapachol	lapachol	NOUN
eurjchem-2402	440	14	complexes	complex	NOUN
eurjchem-2402	440	15	.	.	PUNCT
eurjchem-2402	441	1	j.	j.	PROPN
eurjchem-2402	441	2	inorg	inorg	PROPN
eurjchem-2402	441	3	.	.	PUNCT
eurjchem-2402	442	1	biochem	biochem	PROPN
eurjchem-2402	442	2	.	.	PUNCT
eurjchem-2402	443	1	2014	2014	NUM
eurjchem-2402	443	2	,	,	PUNCT
eurjchem-2402	443	3	136	136	NUM
eurjchem-2402	443	4	,	,	PUNCT
eurjchem-2402	443	5	33–39	33–39	NUM
eurjchem-2402	443	6	.	.	PUNCT
eurjchem-2402	444	1	[	[	X
eurjchem-2402	444	2	34	34	NUM
eurjchem-2402	444	3	]	]	PUNCT
eurjchem-2402	444	4	.	.	PUNCT
eurjchem-2402	444	5	dinelli	dinelli	PROPN
eurjchem-2402	444	6	,	,	PUNCT
eurjchem-2402	444	7	l.	l.	PROPN
eurjchem-2402	444	8	r.	r.	PROPN
eurjchem-2402	444	9	;	;	PUNCT
eurjchem-2402	444	10	batista	batista	PROPN
eurjchem-2402	444	11	,	,	PUNCT
eurjchem-2402	444	12	a.	a.	NOUN
eurjchem-2402	444	13	a.	a.	PROPN
eurjchem-2402	444	14	;	;	PUNCT
eurjchem-2402	444	15	wohnrath	wohnrath	NOUN
eurjchem-2402	444	16	,	,	PUNCT
eurjchem-2402	444	17	k.	k.	PROPN
eurjchem-2402	444	18	;	;	PUNCT
eurjchem-2402	444	19	de	de	X
eurjchem-2402	444	20	araujo	araujo	NOUN
eurjchem-2402	444	21	,	,	PUNCT
eurjchem-2402	444	22	m.	m.	NOUN
eurjchem-2402	444	23	p.	p.	NOUN
eurjchem-2402	444	24	;	;	PUNCT
eurjchem-2402	444	25	queiroz	queiroz	ADV
eurjchem-2402	444	26	,	,	PUNCT
eurjchem-2402	444	27	s.	s.	PROPN
eurjchem-2402	444	28	l.	l.	PROPN
eurjchem-2402	444	29	;	;	PUNCT
eurjchem-2402	444	30	bonfadini	bonfadini	PROPN
eurjchem-2402	444	31	,	,	PUNCT
eurjchem-2402	444	32	m.	m.	NOUN
eurjchem-2402	444	33	r.	r.	PROPN
eurjchem-2402	444	34	;	;	PUNCT
eurjchem-2402	444	35	oliva	oliva	PROPN
eurjchem-2402	444	36	,	,	PUNCT
eurjchem-2402	444	37	g.	g.	PROPN
eurjchem-2402	444	38	;	;	PUNCT
eurjchem-2402	444	39	nascimento	nascimento	PROPN
eurjchem-2402	444	40	,	,	PUNCT
eurjchem-2402	444	41	o.	o.	PROPN
eurjchem-2402	444	42	r.	r.	PROPN
eurjchem-2402	444	43	;	;	PUNCT
eurjchem-2402	444	44	cyr	cyr	PROPN
eurjchem-2402	444	45	,	,	PUNCT
eurjchem-2402	444	46	p.	p.	PROPN
eurjchem-2402	444	47	w.	w.	PROPN
eurjchem-2402	444	48	;	;	PUNCT
eurjchem-2402	444	49	macfarlane	macfarlane	PROPN
eurjchem-2402	444	50	,	,	PUNCT
eurjchem-2402	444	51	k.	k.	PROPN
eurjchem-2402	444	52	s.	s.	PROPN
eurjchem-2402	444	53	;	;	PUNCT
eurjchem-2402	444	54	james	james	PROPN
eurjchem-2402	444	55	,	,	PUNCT
eurjchem-2402	444	56	b.	b.	PROPN
eurjchem-2402	444	57	r.	r.	PROPN
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eurjchem-2402	444	62	[	[	X
eurjchem-2402	444	63	rucl3(p	rucl3(p	NOUN
eurjchem-2402	444	64	-	-	PUNCT
eurjchem-2402	444	65	p)(h2o	p)(h2o	NOUN
eurjchem-2402	444	66	)	)	PUNCT
eurjchem-2402	444	67	]	]	PUNCT
eurjchem-2402	444	68	complexes	complex	NOUN
eurjchem-2402	444	69	;	;	PUNCT
eurjchem-2402	444	70	p	p	X
eurjchem-2402	444	71	-	-	PUNCT
eurjchem-2402	444	72	p	p	NOUN
eurjchem-2402	444	73	=	=	NOUN
eurjchem-2402	444	74	achiral	achiral	ADJ
eurjchem-2402	444	75	or	or	CCONJ
eurjchem-2402	444	76	chiral	chiral	ADJ
eurjchem-2402	444	77	,	,	PUNCT
eurjchem-2402	444	78	chelating	chelate	VERB
eurjchem-2402	444	79	ditertiary	ditertiary	ADJ
eurjchem-2402	444	80	phosphine	phosphine	NOUN
eurjchem-2402	444	81	ligands	ligand	NOUN
eurjchem-2402	444	82	.	.	PUNCT
eurjchem-2402	445	1	inorg	inorg	PROPN
eurjchem-2402	445	2	.	.	PUNCT
eurjchem-2402	446	1	chem	chem	PROPN
eurjchem-2402	446	2	.	.	PUNCT
eurjchem-2402	447	1	1999	1999	NUM
eurjchem-2402	447	2	,	,	PUNCT
eurjchem-2402	447	3	38	38	NUM
eurjchem-2402	447	4	,	,	PUNCT
eurjchem-2402	447	5	5341–5345	5341–5345	NUM
eurjchem-2402	447	6	.	.	PUNCT
eurjchem-2402	448	1	[	[	X
eurjchem-2402	448	2	35	35	NUM
eurjchem-2402	448	3	]	]	PUNCT
eurjchem-2402	448	4	.	.	PUNCT
eurjchem-2402	448	5	polam	polam	PROPN
eurjchem-2402	448	6	,	,	PUNCT
eurjchem-2402	448	7	j.	j.	PROPN
eurjchem-2402	448	8	r.	r.	PROPN
eurjchem-2402	448	9	;	;	PUNCT
eurjchem-2402	448	10	porter	porter	NOUN
eurjchem-2402	448	11	,	,	PUNCT
eurjchem-2402	448	12	l.	l.	PROPN
eurjchem-2402	448	13	c.	c.	PROPN
eurjchem-2402	448	14	ru(ii	ru(ii	PROPN
eurjchem-2402	448	15	)	)	PUNCT
eurjchem-2402	448	16	complexes	complex	NOUN
eurjchem-2402	448	17	containing	contain	VERB
eurjchem-2402	448	18	chelating	chelate	VERB
eurjchem-2402	448	19	phosphine	phosphine	NOUN
eurjchem-2402	448	20	ligands	ligand	NOUN
eurjchem-2402	448	21	.	.	PUNCT
eurjchem-2402	449	1	synthesis	synthesis	NOUN
eurjchem-2402	449	2	,	,	PUNCT
eurjchem-2402	449	3	characterization	characterization	NOUN
eurjchem-2402	449	4	,	,	PUNCT
eurjchem-2402	449	5	and	and	CCONJ
eurjchem-2402	449	6	x	x	X
eurjchem-2402	449	7	-	-	NOUN
eurjchem-2402	449	8	ray	ray	NOUN
eurjchem-2402	449	9	crystal	crystal	NOUN
eurjchem-2402	449	10	structures	structure	NOUN
eurjchem-2402	449	11	of	of	ADP
eurjchem-2402	449	12	dichlorobis(1,2	dichlorobis(1,2	NOUN
eurjchem-2402	449	13	-	-	PUNCT
eurjchem-2402	449	14	bis(diphenylphosphino)ethane)ru(ii	bis(diphenylphosphino)ethane)ru(ii	PROPN
eurjchem-2402	449	15	)	)	PUNCT
eurjchem-2402	449	16	and	and	CCONJ
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eurjchem-2402	449	18	coordinatively	coordinatively	ADV
eurjchem-2402	449	19	unsaturated	unsaturate	VERB
eurjchem-2402	449	20	trigonal	trigonal	ADJ
eurjchem-2402	449	21	-	-	PUNCT
eurjchem-2402	449	22	bipyramidal	bipyramidal	ADJ
eurjchem-2402	449	23	cation	cation	NOUN
eurjchem-2402	449	24	,	,	PUNCT
eurjchem-2402	449	25	chlorobis-(1,2	chlorobis-(1,2	PROPN
eurjchem-2402	449	26	-	-	PUNCT
eurjchem-2402	449	27	bis(diphenylphosphino)ethane)ru(ii	bis(diphenylphosphino)ethane)ru(ii	PROPN
eurjchem-2402	449	28	)	)	PUNCT
eurjchem-2402	449	29	.	.	PUNCT
eurjchem-2402	450	1	j.	j.	PROPN
eurjchem-2402	450	2	coord	coord	PROPN
eurjchem-2402	450	3	.	.	PUNCT
eurjchem-2402	451	1	chem	chem	NOUN
eurjchem-2402	451	2	.	.	PUNCT
eurjchem-2402	452	1	1993	1993	NUM
eurjchem-2402	452	2	,	,	PUNCT
eurjchem-2402	452	3	29	29	NUM
eurjchem-2402	452	4	,	,	PUNCT
eurjchem-2402	452	5	109–119	109–119	NUM
eurjchem-2402	452	6	.	.	PUNCT
eurjchem-2402	453	1	[	[	X
eurjchem-2402	453	2	36	36	NUM
eurjchem-2402	453	3	]	]	PUNCT
eurjchem-2402	453	4	.	.	PUNCT
eurjchem-2402	454	1	lobana	lobana	NOUN
eurjchem-2402	454	2	,	,	PUNCT
eurjchem-2402	454	3	t.	t.	PROPN
eurjchem-2402	454	4	s.	s.	PROPN
eurjchem-2402	454	5	;	;	PUNCT
eurjchem-2402	454	6	singh	singh	PROPN
eurjchem-2402	454	7	,	,	PUNCT
eurjchem-2402	454	8	r.	r.	PROPN
eurjchem-2402	454	9	;	;	PUNCT
eurjchem-2402	454	10	tiekink	tiekink	PROPN
eurjchem-2402	454	11	,	,	PUNCT
eurjchem-2402	454	12	e.	e.	PROPN
eurjchem-2402	454	13	r.	r.	PROPN
eurjchem-2402	454	14	t.	t.	PROPN
eurjchem-2402	454	15	the	the	DET
eurjchem-2402	454	16	crystal	crystal	PROPN
eurjchem-2402	454	17	and	and	CCONJ
eurjchem-2402	454	18	molecular	molecular	ADJ
eurjchem-2402	454	19	structure	structure	NOUN
eurjchem-2402	454	20	of	of	ADP
eurjchem-2402	454	21	bis[1,2	bis[1,2	NOUN
eurjchem-2402	454	22	-	-	PUNCT
eurjchem-2402	454	23	bis(diphenylphosphino)ethane	bis(diphenylphosphino)ethane	NUM
eurjchem-2402	454	24	]	]	PUNCT
eurjchem-2402	454	25	dichloro	dichloro	X
eurjchem-2402	454	26	ruthenium(ii	ruthenium(ii	NOUN
eurjchem-2402	454	27	)	)	PUNCT
eurjchem-2402	454	28	.	.	PUNCT
eurjchem-2402	455	1	j.	j.	PROPN
eurjchem-2402	455	2	coord	coord	PROPN
eurjchem-2402	455	3	.	.	PUNCT
eurjchem-2402	456	1	chem	chem	NOUN
eurjchem-2402	456	2	.	.	PUNCT
eurjchem-2402	457	1	1990	1990	NUM
eurjchem-2402	457	2	,	,	PUNCT
eurjchem-2402	457	3	21	21	NUM
eurjchem-2402	457	4	,	,	PUNCT
eurjchem-2402	457	5	225–229	225–229	NUM
eurjchem-2402	457	6	.	.	PUNCT
eurjchem-2402	458	1	[	[	X
eurjchem-2402	458	2	37	37	NUM
eurjchem-2402	458	3	]	]	PUNCT
eurjchem-2402	458	4	.	.	PUNCT
eurjchem-2402	458	5	chang	chang	PROPN
eurjchem-2402	458	6	,	,	PUNCT
eurjchem-2402	458	7	c.-w	c.-w	PROPN
eurjchem-2402	458	8	.	.	PROPN
eurjchem-2402	458	9	;	;	PUNCT
eurjchem-2402	458	10	ting	ting	NOUN
eurjchem-2402	458	11	,	,	PUNCT
eurjchem-2402	458	12	p.-c	p.-c	PROPN
eurjchem-2402	458	13	.	.	PUNCT
eurjchem-2402	459	1	;	;	PUNCT
eurjchem-2402	459	2	lin	lin	PROPN
eurjchem-2402	459	3	,	,	PUNCT
eurjchem-2402	459	4	y.-c	y.-c	PROPN
eurjchem-2402	459	5	.	.	PUNCT
eurjchem-2402	459	6	;	;	PUNCT
eurjchem-2402	459	7	lee	lee	PROPN
eurjchem-2402	459	8	,	,	PUNCT
eurjchem-2402	459	9	g.-h	g.-h	PROPN
eurjchem-2402	459	10	.	.	PUNCT
eurjchem-2402	459	11	;	;	PUNCT
eurjchem-2402	459	12	wang	wang	PROPN
eurjchem-2402	459	13	,	,	PUNCT
eurjchem-2402	459	14	y.	y.	NOUN
eurjchem-2402	459	15	synthesis	synthesis	NOUN
eurjchem-2402	459	16	of	of	ADP
eurjchem-2402	459	17	ruthenium	ruthenium	NOUN
eurjchem-2402	459	18	vinylidene	vinylidene	NOUN
eurjchem-2402	459	19	complexes	complex	NOUN
eurjchem-2402	459	20	with	with	ADP
eurjchem-2402	459	21	dppe	dppe	PROPN
eurjchem-2402	459	22	ligand	ligand	NOUN
eurjchem-2402	459	23	and	and	CCONJ
eurjchem-2402	459	24	their	their	PRON
eurjchem-2402	459	25	cyclopropenation	cyclopropenation	NOUN
eurjchem-2402	459	26	reaction	reaction	NOUN
eurjchem-2402	459	27	.	.	PUNCT
eurjchem-2402	460	1	j.	j.	PROPN
eurjchem-2402	460	2	organomet	organomet	PROPN
eurjchem-2402	460	3	.	.	PUNCT
eurjchem-2402	461	1	chem	chem	NOUN
eurjchem-2402	461	2	.	.	PUNCT
eurjchem-2402	462	1	1998	1998	NUM
eurjchem-2402	462	2	,	,	PUNCT
eurjchem-2402	462	3	553	553	NUM
eurjchem-2402	462	4	,	,	PUNCT
eurjchem-2402	462	5	417–425	417–425	NUM
eurjchem-2402	462	6	.	.	PUNCT
eurjchem-2402	463	1	[	[	X
eurjchem-2402	463	2	38	38	NUM
eurjchem-2402	463	3	]	]	PUNCT
eurjchem-2402	463	4	.	.	PUNCT
eurjchem-2402	463	5	foi	foi	PROPN
eurjchem-2402	463	6	,	,	PUNCT
eurjchem-2402	463	7	a.	a.	NOUN
eurjchem-2402	463	8	;	;	PUNCT
eurjchem-2402	463	9	corrêa	corrêa	PROPN
eurjchem-2402	463	10	,	,	PUNCT
eurjchem-2402	463	11	r.	r.	PROPN
eurjchem-2402	463	12	s.	s.	PROPN
eurjchem-2402	463	13	;	;	PUNCT
eurjchem-2402	463	14	ellena	ellena	PROPN
eurjchem-2402	463	15	,	,	PUNCT
eurjchem-2402	463	16	j.	j.	PROPN
eurjchem-2402	463	17	;	;	PUNCT
eurjchem-2402	463	18	doctorovich	doctorovich	PROPN
eurjchem-2402	463	19	,	,	PUNCT
eurjchem-2402	463	20	f.	f.	PROPN
eurjchem-2402	463	21	;	;	PUNCT
eurjchem-2402	463	22	di	di	NOUN
eurjchem-2402	463	23	salvo	salvo	NOUN
eurjchem-2402	463	24	,	,	PUNCT
eurjchem-2402	463	25	f.	f.	PROPN
eurjchem-2402	463	26	halogen⋯halogen	halogen⋯halogen	PROPN
eurjchem-2402	463	27	contacts	contact	NOUN
eurjchem-2402	463	28	for	for	ADP
eurjchem-2402	463	29	the	the	DET
eurjchem-2402	463	30	stabilization	stabilization	NOUN
eurjchem-2402	463	31	of	of	ADP
eurjchem-2402	463	32	a	a	DET
eurjchem-2402	463	33	new	new	ADJ
eurjchem-2402	463	34	polymorph	polymorph	NOUN
eurjchem-2402	463	35	of	of	ADP
eurjchem-2402	463	36	9,10	9,10	NOUN
eurjchem-2402	463	37	-	-	PUNCT
eurjchem-2402	463	38	dichloroanthracene	dichloroanthracene	NOUN
eurjchem-2402	463	39	.	.	PUNCT
eurjchem-2402	464	1	j.	j.	PROPN
eurjchem-2402	464	2	mol	mol	PROPN
eurjchem-2402	464	3	.	.	PROPN
eurjchem-2402	464	4	struct	struct	NOUN
eurjchem-2402	464	5	.	.	PUNCT
eurjchem-2402	465	1	2014	2014	NUM
eurjchem-2402	465	2	,	,	PUNCT
eurjchem-2402	465	3	1059	1059	NUM
eurjchem-2402	465	4	,	,	PUNCT
eurjchem-2402	465	5	1–7	1–7	NUM
eurjchem-2402	465	6	.	.	PUNCT
eurjchem-2402	465	7	copyright	copyright	NOUN
eurjchem-2402	465	8	©	©	PROPN
eurjchem-2402	465	9	2023	2023	NUM
eurjchem-2402	465	10	by	by	ADP
eurjchem-2402	465	11	authors	author	NOUN
eurjchem-2402	465	12	.	.	PUNCT
eurjchem-2402	466	1	this	this	DET
eurjchem-2402	466	2	work	work	NOUN
eurjchem-2402	466	3	is	be	AUX
eurjchem-2402	466	4	published	publish	VERB
eurjchem-2402	466	5	and	and	CCONJ
eurjchem-2402	466	6	licensed	license	VERB
eurjchem-2402	466	7	by	by	ADP
eurjchem-2402	466	8	atlanta	atlanta	PROPN
eurjchem-2402	466	9	publishing	publishing	PROPN
eurjchem-2402	466	10	house	house	PROPN
eurjchem-2402	466	11	llc	llc	PROPN
eurjchem-2402	466	12	,	,	PUNCT
eurjchem-2402	466	13	atlanta	atlanta	PROPN
eurjchem-2402	466	14	,	,	PUNCT
eurjchem-2402	466	15	ga	ga	PROPN
eurjchem-2402	466	16	,	,	PUNCT
eurjchem-2402	466	17	usa	usa	PROPN
eurjchem-2402	466	18	.	.	PUNCT
eurjchem-2402	467	1	the	the	DET
eurjchem-2402	467	2	full	full	ADJ
eurjchem-2402	467	3	terms	term	NOUN
eurjchem-2402	467	4	of	of	ADP
eurjchem-2402	467	5	this	this	DET
eurjchem-2402	467	6	license	license	NOUN
eurjchem-2402	467	7	are	be	AUX
eurjchem-2402	467	8	available	available	ADJ
eurjchem-2402	467	9	at	at	ADP
eurjchem-2402	467	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2402	467	11	and	and	CCONJ
eurjchem-2402	467	12	incorporate	incorporate	VERB
eurjchem-2402	467	13	the	the	DET
eurjchem-2402	467	14	creative	creative	ADJ
eurjchem-2402	467	15	commons	common	NOUN
eurjchem-2402	467	16	attribution	attribution	NOUN
eurjchem-2402	467	17	-	-	PUNCT
eurjchem-2402	467	18	non	non	ADJ
eurjchem-2402	467	19	commercial	commercial	NOUN
eurjchem-2402	467	20	(	(	PUNCT
eurjchem-2402	467	21	cc	cc	NOUN
eurjchem-2402	467	22	by	by	ADP
eurjchem-2402	467	23	nc	nc	PROPN
eurjchem-2402	467	24	)	)	PUNCT
eurjchem-2402	467	25	(	(	PUNCT
eurjchem-2402	467	26	international	international	ADJ
eurjchem-2402	467	27	,	,	PUNCT
eurjchem-2402	467	28	v4.0	v4.0	NOUN
eurjchem-2402	467	29	)	)	PUNCT
eurjchem-2402	467	30	license	license	NOUN
eurjchem-2402	467	31	(	(	PUNCT
eurjchem-2402	467	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2402	467	33	)	)	PUNCT
eurjchem-2402	467	34	.	.	PUNCT
eurjchem-2402	468	1	by	by	ADP
eurjchem-2402	468	2	accessing	access	VERB
eurjchem-2402	468	3	the	the	DET
eurjchem-2402	468	4	work	work	NOUN
eurjchem-2402	468	5	,	,	PUNCT
eurjchem-2402	468	6	you	you	PRON
eurjchem-2402	468	7	hereby	hereby	ADV
eurjchem-2402	468	8	accept	accept	VERB
eurjchem-2402	468	9	the	the	DET
eurjchem-2402	468	10	terms	term	NOUN
eurjchem-2402	468	11	.	.	PUNCT
eurjchem-2402	469	1	this	this	PRON
eurjchem-2402	469	2	is	be	AUX
eurjchem-2402	469	3	an	an	DET
eurjchem-2402	469	4	open	open	ADJ
eurjchem-2402	469	5	access	access	NOUN
eurjchem-2402	469	6	article	article	NOUN
eurjchem-2402	469	7	distributed	distribute	VERB
eurjchem-2402	469	8	under	under	ADP
eurjchem-2402	469	9	the	the	DET
eurjchem-2402	469	10	terms	term	NOUN
eurjchem-2402	469	11	and	and	CCONJ
eurjchem-2402	469	12	conditions	condition	NOUN
eurjchem-2402	469	13	of	of	ADP
eurjchem-2402	469	14	the	the	DET
eurjchem-2402	469	15	cc	cc	PROPN
eurjchem-2402	469	16	by	by	ADP
eurjchem-2402	469	17	nc	nc	PROPN
eurjchem-2402	469	18	license	license	PROPN
eurjchem-2402	469	19	,	,	PUNCT
eurjchem-2402	469	20	which	which	PRON
eurjchem-2402	469	21	permits	permit	VERB
eurjchem-2402	469	22	unrestricted	unrestricted	ADJ
eurjchem-2402	469	23	non	non	ADJ
eurjchem-2402	469	24	-	-	ADJ
eurjchem-2402	469	25	commercial	commercial	ADJ
eurjchem-2402	469	26	use	use	NOUN
eurjchem-2402	469	27	,	,	PUNCT
eurjchem-2402	469	28	distribution	distribution	NOUN
eurjchem-2402	469	29	,	,	PUNCT
eurjchem-2402	469	30	and	and	CCONJ
eurjchem-2402	469	31	reproduction	reproduction	NOUN
eurjchem-2402	469	32	in	in	ADP
eurjchem-2402	469	33	any	any	DET
eurjchem-2402	469	34	medium	medium	NOUN
eurjchem-2402	469	35	,	,	PUNCT
eurjchem-2402	469	36	provided	provide	VERB
eurjchem-2402	469	37	the	the	DET
eurjchem-2402	469	38	original	original	ADJ
eurjchem-2402	469	39	work	work	NOUN
eurjchem-2402	469	40	is	be	AUX
eurjchem-2402	469	41	properly	properly	ADV
eurjchem-2402	469	42	cited	cite	VERB
eurjchem-2402	469	43	without	without	ADP
eurjchem-2402	469	44	any	any	DET
eurjchem-2402	469	45	further	further	ADJ
eurjchem-2402	469	46	permission	permission	NOUN
eurjchem-2402	469	47	from	from	ADP
eurjchem-2402	469	48	atlanta	atlanta	PROPN
eurjchem-2402	469	49	publishing	publishing	PROPN
eurjchem-2402	469	50	house	house	PROPN
eurjchem-2402	469	51	llc	llc	PROPN
eurjchem-2402	469	52	(	(	PUNCT
eurjchem-2402	469	53	european	european	PROPN
eurjchem-2402	469	54	journal	journal	PROPN
eurjchem-2402	469	55	of	of	ADP
eurjchem-2402	469	56	chemistry	chemistry	NOUN
eurjchem-2402	469	57	)	)	PUNCT
eurjchem-2402	469	58	.	.	PUNCT
eurjchem-2402	470	1	no	no	DET
eurjchem-2402	470	2	use	use	NOUN
eurjchem-2402	470	3	,	,	PUNCT
eurjchem-2402	470	4	distribution	distribution	NOUN
eurjchem-2402	470	5	,	,	PUNCT
eurjchem-2402	470	6	or	or	CCONJ
eurjchem-2402	470	7	reproduction	reproduction	NOUN
eurjchem-2402	470	8	is	be	AUX
eurjchem-2402	470	9	permitted	permit	VERB
eurjchem-2402	470	10	which	which	PRON
eurjchem-2402	470	11	does	do	AUX
eurjchem-2402	470	12	not	not	PART
eurjchem-2402	470	13	comply	comply	VERB
eurjchem-2402	470	14	with	with	ADP
eurjchem-2402	470	15	these	these	DET
eurjchem-2402	470	16	terms	term	NOUN
eurjchem-2402	470	17	.	.	PUNCT
eurjchem-2402	471	1	permissions	permission	NOUN
eurjchem-2402	471	2	for	for	ADP
eurjchem-2402	471	3	commercial	commercial	ADJ
eurjchem-2402	471	4	use	use	NOUN
eurjchem-2402	471	5	of	of	ADP
eurjchem-2402	471	6	this	this	DET
eurjchem-2402	471	7	work	work	NOUN
eurjchem-2402	471	8	beyond	beyond	ADP
eurjchem-2402	471	9	the	the	DET
eurjchem-2402	471	10	scope	scope	NOUN
eurjchem-2402	471	11	of	of	ADP
eurjchem-2402	471	12	the	the	DET
eurjchem-2402	471	13	license	license	NOUN
eurjchem-2402	471	14	(	(	PUNCT
eurjchem-2402	471	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2402	471	16	)	)	PUNCT
eurjchem-2402	471	17	are	be	AUX
eurjchem-2402	471	18	administered	administer	VERB
eurjchem-2402	471	19	by	by	ADP
eurjchem-2402	471	20	atlanta	atlanta	PROPN
eurjchem-2402	471	21	publishing	publishing	PROPN
eurjchem-2402	471	22	house	house	PROPN
eurjchem-2402	471	23	llc	llc	PROPN
eurjchem-2402	471	24	(	(	PUNCT
eurjchem-2402	471	25	european	european	PROPN
eurjchem-2402	471	26	journal	journal	PROPN
eurjchem-2402	471	27	of	of	ADP
eurjchem-2402	471	28	chemistry	chemistry	NOUN
eurjchem-2402	471	29	)	)	PUNCT
eurjchem-2402	471	30	.	.	PUNCT
eurjchem-2402	472	1	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2402	472	2	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2402	472	3	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2402	472	4	1	1	NUM
eurjchem-2402	472	5	.	.	PUNCT
eurjchem-2402	472	6	introduction	introduction	NOUN
eurjchem-2402	472	7	2	2	NUM
eurjchem-2402	472	8	.	.	PUNCT
eurjchem-2402	472	9	experimental	experimental	ADJ
eurjchem-2402	472	10	2.1	2.1	NUM
eurjchem-2402	472	11	.	.	PUNCT
eurjchem-2402	473	1	synthesis	synthesis	NOUN
eurjchem-2402	473	2	of	of	ADP
eurjchem-2402	473	3	the	the	DET
eurjchem-2402	473	4	cis-[rucl2(dmso)4	cis-[rucl2(dmso)4	PROPN
eurjchem-2402	473	5	]	]	PUNCT
eurjchem-2402	473	6	complex	complex	ADJ
eurjchem-2402	473	7	2.2	2.2	NUM
eurjchem-2402	473	8	.	.	PUNCT
eurjchem-2402	474	1	synthesis	synthesis	NOUN
eurjchem-2402	474	2	of	of	ADP
eurjchem-2402	474	3	cisand	cisand	NOUN
eurjchem-2402	474	4	trans-[rucl2(dppe)2	trans-[rucl2(dppe)2	NOUN
eurjchem-2402	474	5	]	]	X
eurjchem-2402	474	6	2.3	2.3	NUM
eurjchem-2402	474	7	.	.	PUNCT
eurjchem-2402	475	1	uv	uv	NOUN
eurjchem-2402	475	2	-	-	PUNCT
eurjchem-2402	475	3	vis	vis	X
eurjchem-2402	475	4	dna	dna	PROPN
eurjchem-2402	475	5	spectroscopic	spectroscopic	NOUN
eurjchem-2402	475	6	titration	titration	NOUN
eurjchem-2402	475	7	2.4	2.4	NUM
eurjchem-2402	475	8	.	.	PUNCT
eurjchem-2402	476	1	dna	dna	PROPN
eurjchem-2402	476	2	interaction	interaction	NOUN
eurjchem-2402	476	3	by	by	ADP
eurjchem-2402	476	4	electrochemical	electrochemical	ADJ
eurjchem-2402	476	5	studies	study	NOUN
eurjchem-2402	476	6	2.5	2.5	NUM
eurjchem-2402	476	7	.	.	PUNCT
eurjchem-2402	477	1	viscosity	viscosity	NOUN
eurjchem-2402	477	2	2.6	2.6	NUM
eurjchem-2402	477	3	.	.	PUNCT
eurjchem-2402	478	1	x	x	X
eurjchem-2402	478	2	-	-	NOUN
eurjchem-2402	478	3	ray	ray	NOUN
eurjchem-2402	478	4	crystallography	crystallography	NOUN
eurjchem-2402	478	5	study	study	NOUN
eurjchem-2402	478	6	3	3	NUM
eurjchem-2402	478	7	.	.	NOUN
eurjchem-2402	478	8	results	result	NOUN
eurjchem-2402	478	9	and	and	CCONJ
eurjchem-2402	478	10	discussion	discussion	NOUN
eurjchem-2402	478	11	3.1	3.1	NUM
eurjchem-2402	478	12	.	.	PUNCT
eurjchem-2402	479	1	uv	uv	NOUN
eurjchem-2402	479	2	-	-	PUNCT
eurjchem-2402	479	3	vis	vis	X
eurjchem-2402	479	4	dna	dna	PROPN
eurjchem-2402	479	5	spectroscopic	spectroscopic	NOUN
eurjchem-2402	479	6	titration	titration	NOUN
eurjchem-2402	479	7	and	and	CCONJ
eurjchem-2402	479	8	viscosity	viscosity	NOUN
eurjchem-2402	479	9	3.2	3.2	NUM
eurjchem-2402	479	10	.	.	PUNCT
eurjchem-2402	480	1	electrochemical	electrochemical	ADJ
eurjchem-2402	480	2	and	and	CCONJ
eurjchem-2402	480	3	dna	dna	PROPN
eurjchem-2402	480	4	interaction	interaction	NOUN
eurjchem-2402	480	5	study	study	NOUN
eurjchem-2402	480	6	by	by	ADP
eurjchem-2402	480	7	square	square	ADJ
eurjchem-2402	480	8	wave	wave	NOUN
eurjchem-2402	480	9	voltammetry	voltammetry	NOUN
eurjchem-2402	480	10	3.3	3.3	NUM
eurjchem-2402	480	11	.	.	PUNCT
eurjchem-2402	481	1	single	single	ADJ
eurjchem-2402	481	2	crystal	crystal	PROPN
eurjchem-2402	481	3	x	x	PROPN
eurjchem-2402	481	4	-	-	NOUN
eurjchem-2402	481	5	ray	ray	NOUN
eurjchem-2402	481	6	diffraction	diffraction	NOUN
eurjchem-2402	481	7	of	of	ADP
eurjchem-2402	481	8	complex	complex	ADJ
eurjchem-2402	481	9	trans-[rucl2(dppe)2]cl	trans-[rucl2(dppe)2]cl	PROPN
eurjchem-2402	481	10	4	4	NUM
eurjchem-2402	481	11	.	.	PUNCT
eurjchem-2402	482	1	conclusions	conclusion	NOUN
eurjchem-2402	482	2	acknowledgements	acknowledgement	NOUN
eurjchem-2402	482	3	supporting	support	VERB
eurjchem-2402	482	4	information	information	NOUN
eurjchem-2402	482	5	disclosure	disclosure	NOUN
eurjchem-2402	482	6	statement	statement	NOUN
eurjchem-2402	482	7	credit	credit	NOUN
eurjchem-2402	482	8	authorship	authorship	NOUN
eurjchem-2402	482	9	contribution	contribution	NOUN
eurjchem-2402	482	10	statement	statement	NOUN
eurjchem-2402	482	11	funding	fund	VERB
eurjchem-2402	482	12	orcid	orcid	NOUN
eurjchem-2402	482	13	and	and	CCONJ
eurjchem-2402	482	14	email	email	NOUN
eurjchem-2402	482	15	references	reference	NOUN
eurjchem-2402	482	16	printfield10	printfield10	PROPN
eurjchem-2402	482	17	:	:	PUNCT
eurjchem-2402	482	18	printfield11	printfield11	NOUN
eurjchem-2402	482	19	:	:	PUNCT
eurjchem-2402	482	20	printfield12	printfield12	PROPN
eurjchem-2402	482	21	:	:	PUNCT
eurjchem-2402	482	22	printfield13	printfield13	VERB
eurjchem-2402	482	23	:	:	PUNCT
eurjchem-2402	482	24	printfield14	printfield14	NOUN
eurjchem-2402	482	25	:	:	PUNCT
eurjchem-2402	482	26	printfield15	printfield15	NOUN
eurjchem-2402	482	27	:	:	PUNCT
eurjchem-2402	482	28	printfield16	printfield16	ADJ
eurjchem-2402	482	29	:	:	PUNCT
eurjchem-2402	482	30	printfield17	printfield17	NOUN
eurjchem-2402	482	31	:	:	PUNCT
eurjchem-2402	482	32	printfield18	printfield18	NOUN
eurjchem-2402	482	33	:	:	PUNCT
eurjchem-2402	482	34	printfield20	printfield20	PROPN
eurjchem-2402	482	35	:	:	PUNCT
eurjchem-2402	482	36	printfield21	printfield21	ADJ
eurjchem-2402	482	37	:	:	PUNCT
eurjchem-2402	482	38	printfield22	printfield22	NOUN
eurjchem-2402	482	39	:	:	PUNCT
eurjchem-2402	482	40	printfield23	printfield23	NOUN
eurjchem-2402	482	41	:	:	PUNCT
eurjchem-2402	482	42	printfield24	printfield24	NOUN
eurjchem-2402	482	43	:	:	PUNCT
eurjchem-2402	482	44	printfield25	printfield25	NOUN
eurjchem-2402	482	45	:	:	PUNCT
eurjchem-2402	482	46	printfield26	printfield26	ADJ
eurjchem-2402	482	47	:	:	PUNCT
eurjchem-2402	482	48	printfield27	printfield27	NOUN
eurjchem-2402	482	49	:	:	PUNCT
eurjchem-2402	482	50	printfield28	printfield28	NOUN
eurjchem-2402	482	51	:	:	PUNCT