id	sid	tid	token	lemma	pos
eurjchem-2463	1	1	synthesis	synthesis	NOUN
eurjchem-2463	1	2	and	and	CCONJ
eurjchem-2463	1	3	structural	structural	ADJ
eurjchem-2463	1	4	characterization	characterization	NOUN
eurjchem-2463	1	5	of	of	ADP
eurjchem-2463	1	6	ti(iii	ti(iii	NOUN
eurjchem-2463	1	7	)	)	PUNCT
eurjchem-2463	1	8	and	and	CCONJ
eurjchem-2463	1	9	mo(iii	mo(iii	NOUN
eurjchem-2463	1	10	)	)	PUNCT
eurjchem-2463	1	11	complexes	complex	NOUN
eurjchem-2463	1	12	supported	support	VERB
eurjchem-2463	1	13	by	by	ADP
eurjchem-2463	1	14	pnp	pnp	PROPN
eurjchem-2463	1	15	pincer	pincer	PROPN
eurjchem-2463	1	16	ligands	ligands	PROPN
eurjchem-2463	1	17	european	european	PROPN
eurjchem-2463	1	18	journal	journal	PROPN
eurjchem-2463	1	19	of	of	ADP
eurjchem-2463	1	20	chemistry	chemistry	NOUN
eurjchem-2463	1	21	14	14	NUM
eurjchem-2463	1	22	(	(	PUNCT
eurjchem-2463	1	23	3	3	NUM
eurjchem-2463	1	24	)	)	PUNCT
eurjchem-2463	1	25	(	(	PUNCT
eurjchem-2463	1	26	2023	2023	NUM
eurjchem-2463	1	27	)	)	PUNCT
eurjchem-2463	1	28	311	311	NUM
eurjchem-2463	1	29	-	-	SYM
eurjchem-2463	1	30	315	315	NUM
eurjchem-2463	1	31	european	european	ADJ
eurjchem-2463	1	32	journal	journal	NOUN
eurjchem-2463	1	33	of	of	ADP
eurjchem-2463	1	34	chemistry	chemistry	NOUN
eurjchem-2463	1	35	issn	issn	VERB
eurjchem-2463	1	36	2153	2153	NUM
eurjchem-2463	1	37	-	-	SYM
eurjchem-2463	1	38	2249	2249	NUM
eurjchem-2463	1	39	(	(	PUNCT
eurjchem-2463	1	40	print	print	NOUN
eurjchem-2463	1	41	)	)	PUNCT
eurjchem-2463	1	42	/	/	PUNCT
eurjchem-2463	1	43	issn	issn	PROPN
eurjchem-2463	1	44	2153	2153	NUM
eurjchem-2463	1	45	-	-	SYM
eurjchem-2463	1	46	2257	2257	NUM
eurjchem-2463	1	47	(	(	PUNCT
eurjchem-2463	1	48	online	online	ADJ
eurjchem-2463	1	49	)	)	PUNCT
eurjchem-2463	1	50	–	–	PUNCT
eurjchem-2463	2	1	copyright	copyright	NOUN
eurjchem-2463	2	2	©	©	PROPN
eurjchem-2463	2	3	2023	2023	NUM
eurjchem-2463	2	4	the	the	DET
eurjchem-2463	2	5	authors	author	NOUN
eurjchem-2463	2	6	–	–	PUNCT
eurjchem-2463	2	7	atlanta	atlanta	PROPN
eurjchem-2463	2	8	publishing	publishing	PROPN
eurjchem-2463	2	9	house	house	PROPN
eurjchem-2463	2	10	llc	llc	PROPN
eurjchem-2463	2	11	–	–	PUNCT
eurjchem-2463	2	12	printed	print	VERB
eurjchem-2463	2	13	in	in	ADP
eurjchem-2463	2	14	the	the	DET
eurjchem-2463	2	15	usa	usa	PROPN
eurjchem-2463	2	16	.	.	PUNCT
eurjchem-2463	3	1	this	this	DET
eurjchem-2463	3	2	work	work	NOUN
eurjchem-2463	3	3	is	be	AUX
eurjchem-2463	3	4	published	publish	VERB
eurjchem-2463	3	5	and	and	CCONJ
eurjchem-2463	3	6	licensed	license	VERB
eurjchem-2463	3	7	by	by	ADP
eurjchem-2463	3	8	atlanta	atlanta	PROPN
eurjchem-2463	3	9	publishing	publishing	PROPN
eurjchem-2463	3	10	house	house	PROPN
eurjchem-2463	3	11	llc	llc	PROPN
eurjchem-2463	3	12	–	–	PUNCT
eurjchem-2463	3	13	cc	cc	PROPN
eurjchem-2463	3	14	by	by	ADP
eurjchem-2463	3	15	nc	nc	PROPN
eurjchem-2463	3	16	–	–	PUNCT
eurjchem-2463	3	17	some	some	DET
eurjchem-2463	3	18	rights	right	NOUN
eurjchem-2463	3	19	reserved	reserve	VERB
eurjchem-2463	3	20	.	.	PUNCT
eurjchem-2463	4	1	https://dx.doi.org/10.5155/eurjchem.14.3.311-315.2463	https://dx.doi.org/10.5155/eurjchem.14.3.311-315.2463	PROPN
eurjchem-2463	4	2	european	european	PROPN
eurjchem-2463	4	3	journal	journal	PROPN
eurjchem-2463	4	4	of	of	ADP
eurjchem-2463	4	5	chemistry	chemistry	NOUN
eurjchem-2463	4	6	view	view	NOUN
eurjchem-2463	4	7	journal	journal	PROPN
eurjchem-2463	4	8	online	online	PROPN
eurjchem-2463	4	9	view	view	NOUN
eurjchem-2463	4	10	article	article	NOUN
eurjchem-2463	4	11	online	online	ADJ
eurjchem-2463	4	12	synthesis	synthesis	NOUN
eurjchem-2463	4	13	and	and	CCONJ
eurjchem-2463	4	14	structural	structural	ADJ
eurjchem-2463	4	15	characterization	characterization	NOUN
eurjchem-2463	4	16	of	of	ADP
eurjchem-2463	4	17	ti(iii	ti(iii	NOUN
eurjchem-2463	4	18	)	)	PUNCT
eurjchem-2463	4	19	and	and	CCONJ
eurjchem-2463	4	20	mo(iii	mo(iii	NOUN
eurjchem-2463	4	21	)	)	PUNCT
eurjchem-2463	4	22	complexes	complex	NOUN
eurjchem-2463	4	23	supported	support	VERB
eurjchem-2463	4	24	by	by	ADP
eurjchem-2463	4	25	pnp	pnp	PROPN
eurjchem-2463	4	26	pincer	pincer	PROPN
eurjchem-2463	4	27	ligands	ligand	NOUN
eurjchem-2463	4	28	rita	rita	PROPN
eurjchem-2463	4	29	ruivo	ruivo	PROPN
eurjchem-2463	4	30	1	1	NUM
eurjchem-2463	4	31	,	,	PUNCT
eurjchem-2463	4	32	luis	luis	PROPN
eurjchem-2463	4	33	alves	alves	PROPN
eurjchem-2463	4	34	2	2	NUM
eurjchem-2463	4	35	,	,	PUNCT
eurjchem-2463	4	36	*	*	PUNCT
eurjchem-2463	4	37	and	and	CCONJ
eurjchem-2463	4	38	ana	ana	PROPN
eurjchem-2463	4	39	martins	martin	NOUN
eurjchem-2463	4	40	1	1	NUM
eurjchem-2463	4	41	,	,	PUNCT
eurjchem-2463	4	42	*	*	PUNCT
eurjchem-2463	4	43	1	1	NUM
eurjchem-2463	4	44	centro	centro	X
eurjchem-2463	4	45	de	de	PROPN
eurjchem-2463	4	46	química	química	PROPN
eurjchem-2463	4	47	estrutural	estrutural	PROPN
eurjchem-2463	4	48	,	,	PUNCT
eurjchem-2463	4	49	instituto	instituto	PROPN
eurjchem-2463	4	50	superior	superior	PROPN
eurjchem-2463	4	51	técnico	técnico	PROPN
eurjchem-2463	4	52	,	,	PUNCT
eurjchem-2463	4	53	universidade	universidade	PROPN
eurjchem-2463	4	54	de	de	PROPN
eurjchem-2463	4	55	lisboa	lisboa	PROPN
eurjchem-2463	4	56	,	,	PUNCT
eurjchem-2463	4	57	av	av	PROPN
eurjchem-2463	4	58	.	.	PUNCT
eurjchem-2463	4	59	rovisco	rovisco	PROPN
eurjchem-2463	4	60	pais	pais	PROPN
eurjchem-2463	4	61	1	1	NUM
eurjchem-2463	4	62	,	,	PUNCT
eurjchem-2463	4	63	1049	1049	NUM
eurjchem-2463	4	64	-	-	SYM
eurjchem-2463	4	65	001	001	NUM
eurjchem-2463	4	66	lisboa	lisboa	NOUN
eurjchem-2463	4	67	,	,	PUNCT
eurjchem-2463	4	68	portugal	portugal	PROPN
eurjchem-2463	4	69	2	2	NUM
eurjchem-2463	4	70	centro	centro	X
eurjchem-2463	4	71	de	de	PROPN
eurjchem-2463	4	72	química	química	PROPN
eurjchem-2463	4	73	estrutural	estrutural	PROPN
eurjchem-2463	4	74	,	,	PUNCT
eurjchem-2463	4	75	associação	associação	PROPN
eurjchem-2463	4	76	do	do	AUX
eurjchem-2463	4	77	instituto	instituto	PROPN
eurjchem-2463	4	78	superior	superior	PROPN
eurjchem-2463	4	79	técnico	técnico	PROPN
eurjchem-2463	4	80	para	para	VERB
eurjchem-2463	4	81	a	a	DET
eurjchem-2463	4	82	investigação	investigação	PROPN
eurjchem-2463	4	83	e	e	X
eurjchem-2463	4	84	desenvolvimento	desenvolvimento	PROPN
eurjchem-2463	4	85	,	,	PUNCT
eurjchem-2463	4	86	av	av	PROPN
eurjchem-2463	4	87	.	.	PUNCT
eurjchem-2463	5	1	antónio	antónio	PROPN
eurjchem-2463	5	2	josé	josé	PROPN
eurjchem-2463	5	3	de	de	PROPN
eurjchem-2463	5	4	almeida	almeida	PROPN
eurjchem-2463	5	5	no	no	DET
eurjchem-2463	5	6	12	12	NUM
eurjchem-2463	5	7	,	,	PUNCT
eurjchem-2463	5	8	1000	1000	NUM
eurjchem-2463	5	9	-	-	SYM
eurjchem-2463	5	10	043	043	NUM
eurjchem-2463	5	11	lisboa	lisboa	NOUN
eurjchem-2463	5	12	,	,	PUNCT
eurjchem-2463	5	13	portugal	portugal	PROPN
eurjchem-2463	5	14	*	*	PUNCT
eurjchem-2463	5	15	corresponding	correspond	VERB
eurjchem-2463	5	16	author	author	NOUN
eurjchem-2463	5	17	at	at	ADP
eurjchem-2463	5	18	:	:	PUNCT
eurjchem-2463	5	19	centro	centro	PROPN
eurjchem-2463	5	20	de	de	PROPN
eurjchem-2463	5	21	química	química	PROPN
eurjchem-2463	5	22	estrutural	estrutural	PROPN
eurjchem-2463	5	23	,	,	PUNCT
eurjchem-2463	5	24	associação	associação	PROPN
eurjchem-2463	5	25	do	do	AUX
eurjchem-2463	5	26	instituto	instituto	PROPN
eurjchem-2463	5	27	superior	superior	PROPN
eurjchem-2463	5	28	técnico	técnico	PROPN
eurjchem-2463	5	29	para	para	VERB
eurjchem-2463	5	30	a	a	DET
eurjchem-2463	5	31	investigação	investigação	PROPN
eurjchem-2463	5	32	e	e	X
eurjchem-2463	5	33	desenvolvimento	desenvolvimento	PROPN
eurjchem-2463	5	34	,	,	PUNCT
eurjchem-2463	5	35	av	av	PROPN
eurjchem-2463	5	36	.	.	PUNCT
eurjchem-2463	6	1	antónio	antónio	PROPN
eurjchem-2463	6	2	josé	josé	PROPN
eurjchem-2463	6	3	de	de	PROPN
eurjchem-2463	6	4	almeida	almeida	PROPN
eurjchem-2463	6	5	no	no	DET
eurjchem-2463	6	6	12	12	NUM
eurjchem-2463	6	7	,	,	PUNCT
eurjchem-2463	6	8	1000	1000	NUM
eurjchem-2463	6	9	-	-	SYM
eurjchem-2463	6	10	043	043	NUM
eurjchem-2463	6	11	lisboa	lisboa	NOUN
eurjchem-2463	6	12	,	,	PUNCT
eurjchem-2463	6	13	portugal	portugal	PROPN
eurjchem-2463	6	14	;	;	PUNCT
eurjchem-2463	6	15	centro	centro	PROPN
eurjchem-2463	6	16	de	de	PROPN
eurjchem-2463	6	17	química	química	PROPN
eurjchem-2463	6	18	estrutural	estrutural	PROPN
eurjchem-2463	6	19	,	,	PUNCT
eurjchem-2463	6	20	instituto	instituto	PROPN
eurjchem-2463	6	21	superior	superior	PROPN
eurjchem-2463	6	22	técnico	técnico	PROPN
eurjchem-2463	6	23	,	,	PUNCT
eurjchem-2463	6	24	universidade	universidade	PROPN
eurjchem-2463	6	25	de	de	PROPN
eurjchem-2463	6	26	lisboa	lisboa	PROPN
eurjchem-2463	6	27	,	,	PUNCT
eurjchem-2463	6	28	av	av	PROPN
eurjchem-2463	6	29	.	.	PUNCT
eurjchem-2463	6	30	rovisco	rovisco	PROPN
eurjchem-2463	6	31	pais	pais	PROPN
eurjchem-2463	6	32	1	1	NUM
eurjchem-2463	6	33	,	,	PUNCT
eurjchem-2463	6	34	1049	1049	NUM
eurjchem-2463	6	35	-	-	SYM
eurjchem-2463	6	36	001	001	NUM
eurjchem-2463	6	37	lisboa	lisboa	NOUN
eurjchem-2463	6	38	,	,	PUNCT
eurjchem-2463	6	39	portugal	portugal	PROPN
eurjchem-2463	6	40	.	.	PUNCT
eurjchem-2463	7	1	e	e	X
eurjchem-2463	7	2	-	-	NOUN
eurjchem-2463	7	3	mail	mail	NOUN
eurjchem-2463	7	4	:	:	PUNCT
eurjchem-2463	7	5	luis.g.alves@tecnico.ulisboa.pt	luis.g.alves@tecnico.ulisboa.pt	PROPN
eurjchem-2463	7	6	(	(	PUNCT
eurjchem-2463	7	7	l.	l.	PROPN
eurjchem-2463	7	8	alves	alves	PROPN
eurjchem-2463	7	9	)	)	PUNCT
eurjchem-2463	7	10	,	,	PUNCT
eurjchem-2463	7	11	ana.martins@tecnico.ulisboa.pt	ana.martins@tecnico.ulisboa.pt	PROPN
eurjchem-2463	7	12	(	(	PUNCT
eurjchem-2463	7	13	a.	a.	NOUN
eurjchem-2463	7	14	martins	martins	PROPN
eurjchem-2463	7	15	)	)	PUNCT
eurjchem-2463	7	16	.	.	PUNCT
eurjchem-2463	8	1	10.5155	10.5155	NUM
eurjchem-2463	8	2	/	/	SYM
eurjchem-2463	8	3	eurjchem.14.3.311	eurjchem.14.3.311	NUM
eurjchem-2463	8	4	-	-	SYM
eurjchem-2463	8	5	315.2463	315.2463	NUM
eurjchem-2463	8	6	received	receive	VERB
eurjchem-2463	8	7	:	:	PUNCT
eurjchem-2463	8	8	21	21	NUM
eurjchem-2463	8	9	june	june	PROPN
eurjchem-2463	8	10	2023	2023	NUM
eurjchem-2463	8	11	received	receive	VERB
eurjchem-2463	8	12	in	in	ADP
eurjchem-2463	8	13	revised	revise	VERB
eurjchem-2463	8	14	form	form	NOUN
eurjchem-2463	8	15	:	:	PUNCT
eurjchem-2463	8	16	04	04	NUM
eurjchem-2463	8	17	july	july	PROPN
eurjchem-2463	8	18	2023	2023	NUM
eurjchem-2463	8	19	accepted	accept	VERB
eurjchem-2463	8	20	:	:	PUNCT
eurjchem-2463	8	21	11	11	NUM
eurjchem-2463	8	22	july	july	PROPN
eurjchem-2463	8	23	2023	2023	NUM
eurjchem-2463	8	24	published	publish	VERB
eurjchem-2463	8	25	online	online	NOUN
eurjchem-2463	8	26	:	:	PUNCT
eurjchem-2463	8	27	30	30	NUM
eurjchem-2463	8	28	september	september	PROPN
eurjchem-2463	8	29	2023	2023	NUM
eurjchem-2463	8	30	printed	print	VERB
eurjchem-2463	8	31	:	:	PUNCT
eurjchem-2463	8	32	30	30	NUM
eurjchem-2463	8	33	september	september	PROPN
eurjchem-2463	8	34	2023	2023	NUM
eurjchem-2463	8	35	new	new	ADJ
eurjchem-2463	8	36	ti(iii	ti(iii	NOUN
eurjchem-2463	8	37	)	)	PUNCT
eurjchem-2463	8	38	and	and	CCONJ
eurjchem-2463	8	39	mo(iii	mo(iii	NOUN
eurjchem-2463	8	40	)	)	PUNCT
eurjchem-2463	8	41	complexes	complex	NOUN
eurjchem-2463	8	42	of	of	ADP
eurjchem-2463	8	43	formulae	formulae	ADJ
eurjchem-2463	8	44	[	[	X
eurjchem-2463	8	45	(	(	PUNCT
eurjchem-2463	8	46	pnp	pnp	PROPN
eurjchem-2463	8	47	-	-	PUNCT
eurjchem-2463	8	48	ph)ticl3	ph)ticl3	PROPN
eurjchem-2463	8	49	]	]	PUNCT
eurjchem-2463	8	50	,	,	PUNCT
eurjchem-2463	8	51	1	1	NUM
eurjchem-2463	8	52	,	,	PUNCT
eurjchem-2463	8	53	and	and	CCONJ
eurjchem-2463	8	54	[	[	X
eurjchem-2463	8	55	(	(	PUNCT
eurjchem-2463	8	56	pnp	pnp	PROPN
eurjchem-2463	8	57	-	-	PUNCT
eurjchem-2463	8	58	ipr)mocl3	ipr)mocl3	PROPN
eurjchem-2463	8	59	]	]	PUNCT
eurjchem-2463	8	60	,	,	PUNCT
eurjchem-2463	8	61	2	2	NUM
eurjchem-2463	8	62	,	,	PUNCT
eurjchem-2463	8	63	where	where	SCONJ
eurjchem-2463	8	64	pnp	pnp	NOUN
eurjchem-2463	8	65	-	-	PUNCT
eurjchem-2463	8	66	ph	ph	NOUN
eurjchem-2463	8	67	=	=	PUNCT
eurjchem-2463	8	68	n	n	CCONJ
eurjchem-2463	8	69	,	,	PUNCT
eurjchem-2463	8	70	n’-bis(diphenylphosphino)-2,6	n’-bis(diphenylphosphino)-2,6	PROPN
eurjchem-2463	8	71	-	-	NOUN
eurjchem-2463	8	72	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	8	73	and	and	CCONJ
eurjchem-2463	8	74	pnp	pnp	PROPN
eurjchem-2463	8	75	-	-	PUNCT
eurjchem-2463	8	76	ipr	ipr	PROPN
eurjchem-2463	8	77	=	=	PUNCT
eurjchem-2463	8	78	n	n	CCONJ
eurjchem-2463	8	79	,	,	PUNCT
eurjchem-2463	8	80	n’bis(diisopropylphosphino)-2,6	n’bis(diisopropylphosphino)-2,6	NOUN
eurjchem-2463	8	81	-	-	PUNCT
eurjchem-2463	8	82	diaminopyridine	diaminopyridine	PROPN
eurjchem-2463	8	83	were	be	AUX
eurjchem-2463	8	84	synthesised	synthesise	VERB
eurjchem-2463	8	85	,	,	PUNCT
eurjchem-2463	8	86	in	in	ADP
eurjchem-2463	8	87	moderate	moderate	ADJ
eurjchem-2463	8	88	yields	yield	NOUN
eurjchem-2463	8	89	,	,	PUNCT
eurjchem-2463	8	90	by	by	ADP
eurjchem-2463	8	91	reaction	reaction	NOUN
eurjchem-2463	8	92	of	of	ADP
eurjchem-2463	8	93	mcl3·(thf)3	mcl3·(thf)3	PROPN
eurjchem-2463	8	94	(	(	PUNCT
eurjchem-2463	8	95	m	m	NOUN
eurjchem-2463	8	96	=	=	ADJ
eurjchem-2463	8	97	ti	ti	NOUN
eurjchem-2463	8	98	and	and	CCONJ
eurjchem-2463	8	99	mo	mo	NOUN
eurjchem-2463	8	100	)	)	PUNCT
eurjchem-2463	8	101	with	with	ADP
eurjchem-2463	8	102	the	the	DET
eurjchem-2463	8	103	suitable	suitable	ADJ
eurjchem-2463	8	104	ligand	ligand	NOUN
eurjchem-2463	8	105	precursor	precursor	NOUN
eurjchem-2463	8	106	.	.	PUNCT
eurjchem-2463	9	1	the	the	DET
eurjchem-2463	9	2	solid	solid	ADJ
eurjchem-2463	9	3	-	-	PUNCT
eurjchem-2463	9	4	state	state	NOUN
eurjchem-2463	9	5	molecular	molecular	ADJ
eurjchem-2463	9	6	structures	structure	NOUN
eurjchem-2463	9	7	of	of	ADP
eurjchem-2463	9	8	complexes	complex	NOUN
eurjchem-2463	9	9	1	1	NUM
eurjchem-2463	9	10	and	and	CCONJ
eurjchem-2463	9	11	2	2	NUM
eurjchem-2463	9	12	were	be	AUX
eurjchem-2463	9	13	obtained	obtain	VERB
eurjchem-2463	9	14	by	by	ADP
eurjchem-2463	9	15	single	single	ADJ
eurjchem-2463	9	16	-	-	PUNCT
eurjchem-2463	9	17	crystal	crystal	NOUN
eurjchem-2463	9	18	x	x	ADJ
eurjchem-2463	9	19	-	-	NOUN
eurjchem-2463	9	20	ray	ray	NOUN
eurjchem-2463	9	21	diffraction	diffraction	NOUN
eurjchem-2463	9	22	.	.	PUNCT
eurjchem-2463	10	1	crystal	crystal	NOUN
eurjchem-2463	10	2	data	datum	NOUN
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eurjchem-2463	10	5	(	(	PUNCT
eurjchem-2463	10	6	1·(c4h8o)2	1·(c4h8o)2	NUM
eurjchem-2463	10	7	):	):	PUNCT
eurjchem-2463	10	8	triclinic	triclinic	ADJ
eurjchem-2463	10	9	,	,	PUNCT
eurjchem-2463	10	10	space	space	NOUN
eurjchem-2463	10	11	group	group	NOUN
eurjchem-2463	10	12	p-1	p-1	NOUN
eurjchem-2463	10	13	(	(	PUNCT
eurjchem-2463	10	14	no	no	INTJ
eurjchem-2463	10	15	.	.	NOUN
eurjchem-2463	10	16	2	2	NUM
eurjchem-2463	10	17	)	)	PUNCT
eurjchem-2463	10	18	,	,	PUNCT
eurjchem-2463	10	19	a	a	DET
eurjchem-2463	10	20	=	=	NOUN
eurjchem-2463	10	21	10.0945(4	10.0945(4	PROPN
eurjchem-2463	10	22	)	)	PUNCT
eurjchem-2463	10	23	å	å	PROPN
eurjchem-2463	10	24	,	,	PUNCT
eurjchem-2463	10	25	b	b	X
eurjchem-2463	10	26	=	=	SYM
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eurjchem-2463	10	28	)	)	PUNCT
eurjchem-2463	10	29	å	å	NOUN
eurjchem-2463	10	30	,	,	PUNCT
eurjchem-2463	10	31	c	c	NOUN
eurjchem-2463	10	32	=	=	SYM
eurjchem-2463	10	33	18.6233(7	18.6233(7	NUM
eurjchem-2463	10	34	)	)	PUNCT
eurjchem-2463	10	35	å	å	PROPN
eurjchem-2463	10	36	,	,	PUNCT
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eurjchem-2463	10	40	)	)	PUNCT
eurjchem-2463	10	41	°	°	NOUN
eurjchem-2463	10	42	,	,	PUNCT
eurjchem-2463	10	43	β	β	X
eurjchem-2463	10	44	=	=	SYM
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eurjchem-2463	10	46	)	)	PUNCT
eurjchem-2463	10	47	°	°	PROPN
eurjchem-2463	10	48	,	,	PUNCT
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eurjchem-2463	10	51	101.705(3	101.705(3	NUM
eurjchem-2463	10	52	)	)	PUNCT
eurjchem-2463	10	53	°	°	NOUN
eurjchem-2463	10	54	,	,	PUNCT
eurjchem-2463	10	55	v	v	NOUN
eurjchem-2463	10	56	=	=	SYM
eurjchem-2463	10	57	1893.65(13	1893.65(13	NOUN
eurjchem-2463	10	58	)	)	PUNCT
eurjchem-2463	10	59	å3	å3	PROPN
eurjchem-2463	10	60	,	,	PUNCT
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eurjchem-2463	10	62	=	=	SYM
eurjchem-2463	10	63	2	2	NUM
eurjchem-2463	10	64	,	,	PUNCT
eurjchem-2463	10	65	µ(mokα	µ(mokα	NUM
eurjchem-2463	10	66	)	)	PUNCT
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eurjchem-2463	10	70	,	,	PUNCT
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eurjchem-2463	10	72	=	=	PUNCT
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eurjchem-2463	10	75	,	,	PUNCT
eurjchem-2463	10	76	20760	20760	NUM
eurjchem-2463	10	77	reflections	reflection	NOUN
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eurjchem-2463	10	79	(	(	PUNCT
eurjchem-2463	10	80	2.021	2.021	NUM
eurjchem-2463	10	81	≤	≤	NUM
eurjchem-2463	10	82	θ	θ	PROPN
eurjchem-2463	10	83	≤	≤	NUM
eurjchem-2463	10	84	27.130	27.130	NUM
eurjchem-2463	10	85	)	)	PUNCT
eurjchem-2463	10	86	,	,	PUNCT
eurjchem-2463	10	87	8327	8327	NUM
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eurjchem-2463	10	89	(	(	PUNCT
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eurjchem-2463	10	91	=	=	SYM
eurjchem-2463	10	92	0.0399	0.0399	NUM
eurjchem-2463	10	93	,	,	PUNCT
eurjchem-2463	10	94	rsigma	rsigma	ADJ
eurjchem-2463	10	95	=	=	SYM
eurjchem-2463	10	96	0.0414	0.0414	NUM
eurjchem-2463	10	97	)	)	PUNCT
eurjchem-2463	10	98	which	which	PRON
eurjchem-2463	10	99	were	be	AUX
eurjchem-2463	10	100	used	use	VERB
eurjchem-2463	10	101	in	in	ADP
eurjchem-2463	10	102	all	all	DET
eurjchem-2463	10	103	calculations	calculation	NOUN
eurjchem-2463	10	104	.	.	PUNCT
eurjchem-2463	11	1	the	the	DET
eurjchem-2463	11	2	final	final	ADJ
eurjchem-2463	11	3	r1	r1	PROPN
eurjchem-2463	11	4	was	be	AUX
eurjchem-2463	11	5	0.0316	0.0316	NUM
eurjchem-2463	11	6	(	(	PUNCT
eurjchem-2463	11	7	i	i	PRON
eurjchem-2463	11	8	>	>	X
eurjchem-2463	11	9	σ(i	σ(i	PROPN
eurjchem-2463	11	10	)	)	PUNCT
eurjchem-2463	11	11	)	)	PUNCT
eurjchem-2463	12	1	and	and	CCONJ
eurjchem-2463	12	2	wr2	wr2	PROPN
eurjchem-2463	12	3	was	be	AUX
eurjchem-2463	12	4	0.0850	0.0850	NUM
eurjchem-2463	12	5	(	(	PUNCT
eurjchem-2463	12	6	all	all	DET
eurjchem-2463	12	7	data	datum	NOUN
eurjchem-2463	12	8	)	)	PUNCT
eurjchem-2463	12	9	.	.	PUNCT
eurjchem-2463	13	1	crystal	crystal	NOUN
eurjchem-2463	13	2	data	datum	NOUN
eurjchem-2463	13	3	for	for	ADP
eurjchem-2463	13	4	c17h33cl3mon3p2	c17h33cl3mon3p2	ADJ
eurjchem-2463	13	5	(	(	PUNCT
eurjchem-2463	13	6	2	2	NUM
eurjchem-2463	13	7	):	):	PUNCT
eurjchem-2463	13	8	tetragonal	tetragonal	ADJ
eurjchem-2463	13	9	,	,	PUNCT
eurjchem-2463	13	10	space	space	NOUN
eurjchem-2463	13	11	group	group	NOUN
eurjchem-2463	13	12	i41	i41	PROPN
eurjchem-2463	13	13	/	/	SYM
eurjchem-2463	13	14	a	a	DET
eurjchem-2463	13	15	(	(	PUNCT
eurjchem-2463	13	16	no	no	NOUN
eurjchem-2463	13	17	.	.	NOUN
eurjchem-2463	13	18	88	88	NUM
eurjchem-2463	13	19	)	)	PUNCT
eurjchem-2463	13	20	,	,	PUNCT
eurjchem-2463	13	21	a	a	DET
eurjchem-2463	13	22	=	=	SYM
eurjchem-2463	13	23	b	b	NOUN
eurjchem-2463	13	24	=	=	SYM
eurjchem-2463	13	25	19.468(4	19.468(4	PROPN
eurjchem-2463	13	26	)	)	PUNCT
eurjchem-2463	13	27	å	å	NOUN
eurjchem-2463	13	28	,	,	PUNCT
eurjchem-2463	13	29	c	c	NOUN
eurjchem-2463	13	30	=	=	SYM
eurjchem-2463	13	31	31.711(6	31.711(6	PROPN
eurjchem-2463	13	32	)	)	PUNCT
eurjchem-2463	13	33	å	å	PROPN
eurjchem-2463	13	34	,	,	PUNCT
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eurjchem-2463	13	36	=	=	X
eurjchem-2463	13	37	β	β	X
eurjchem-2463	13	38	=	=	PUNCT
eurjchem-2463	13	39	γ	γ	X
eurjchem-2463	13	40	=	=	SYM
eurjchem-2463	13	41	90	90	NUM
eurjchem-2463	13	42	°	°	NOUN
eurjchem-2463	13	43	,	,	PUNCT
eurjchem-2463	13	44	v	v	NOUN
eurjchem-2463	13	45	=	=	SYM
eurjchem-2463	13	46	12019(5	12019(5	NUM
eurjchem-2463	13	47	)	)	PUNCT
eurjchem-2463	13	48	å3	å3	PROPN
eurjchem-2463	13	49	,	,	PUNCT
eurjchem-2463	13	50	z	z	PROPN
eurjchem-2463	13	51	=	=	SYM
eurjchem-2463	13	52	16	16	NUM
eurjchem-2463	13	53	,	,	PUNCT
eurjchem-2463	13	54	µ(mokα	µ(mokα	NUM
eurjchem-2463	13	55	)	)	PUNCT
eurjchem-2463	13	56	=	=	SYM
eurjchem-2463	13	57	0.816	0.816	NUM
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eurjchem-2463	13	59	,	,	PUNCT
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eurjchem-2463	13	61	=	=	PROPN
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eurjchem-2463	13	64	,	,	PUNCT
eurjchem-2463	13	65	42367	42367	NUM
eurjchem-2463	13	66	reflections	reflection	NOUN
eurjchem-2463	13	67	measured	measure	VERB
eurjchem-2463	13	68	(	(	PUNCT
eurjchem-2463	13	69	2.569	2.569	NUM
eurjchem-2463	13	70	≤	≤	NUM
eurjchem-2463	13	71	θ	θ	PROPN
eurjchem-2463	13	72	≤	≤	PROPN
eurjchem-2463	13	73	25.347	25.347	NUM
eurjchem-2463	13	74	)	)	PUNCT
eurjchem-2463	13	75	,	,	PUNCT
eurjchem-2463	13	76	5498	5498	NUM
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eurjchem-2463	13	78	(	(	PUNCT
eurjchem-2463	13	79	rint	rint	NOUN
eurjchem-2463	13	80	=	=	SYM
eurjchem-2463	13	81	0.1408	0.1408	NUM
eurjchem-2463	13	82	,	,	PUNCT
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eurjchem-2463	13	84	=	=	SYM
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eurjchem-2463	13	89	used	use	VERB
eurjchem-2463	13	90	in	in	ADP
eurjchem-2463	13	91	all	all	DET
eurjchem-2463	13	92	calculations	calculation	NOUN
eurjchem-2463	13	93	.	.	PUNCT
eurjchem-2463	14	1	the	the	DET
eurjchem-2463	14	2	final	final	ADJ
eurjchem-2463	14	3	r1	r1	NOUN
eurjchem-2463	14	4	was	be	AUX
eurjchem-2463	14	5	0.1005	0.1005	NUM
eurjchem-2463	14	6	(	(	PUNCT
eurjchem-2463	14	7	i	i	PRON
eurjchem-2463	14	8	>	>	X
eurjchem-2463	14	9	σ(i	σ(i	PROPN
eurjchem-2463	14	10	)	)	PUNCT
eurjchem-2463	14	11	)	)	PUNCT
eurjchem-2463	15	1	and	and	CCONJ
eurjchem-2463	15	2	wr2	wr2	PROPN
eurjchem-2463	15	3	was	be	AUX
eurjchem-2463	15	4	0.3194	0.3194	NUM
eurjchem-2463	15	5	(	(	PUNCT
eurjchem-2463	15	6	all	all	DET
eurjchem-2463	15	7	data	datum	NOUN
eurjchem-2463	15	8	)	)	PUNCT
eurjchem-2463	15	9	.	.	PUNCT
eurjchem-2463	16	1	the	the	DET
eurjchem-2463	16	2	coordination	coordination	NOUN
eurjchem-2463	16	3	geometry	geometry	NOUN
eurjchem-2463	16	4	around	around	ADP
eurjchem-2463	16	5	the	the	DET
eurjchem-2463	16	6	titanium	titanium	NOUN
eurjchem-2463	16	7	and	and	CCONJ
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eurjchem-2463	16	9	centers	center	NOUN
eurjchem-2463	16	10	is	be	AUX
eurjchem-2463	16	11	best	well	ADV
eurjchem-2463	16	12	described	describe	VERB
eurjchem-2463	16	13	as	as	ADP
eurjchem-2463	16	14	octahedral	octahedral	ADJ
eurjchem-2463	16	15	,	,	PUNCT
eurjchem-2463	16	16	with	with	ADP
eurjchem-2463	16	17	three	three	NUM
eurjchem-2463	16	18	donor	donor	NOUN
eurjchem-2463	16	19	atoms	atom	NOUN
eurjchem-2463	16	20	of	of	ADP
eurjchem-2463	16	21	the	the	DET
eurjchem-2463	16	22	pnp	pnp	PROPN
eurjchem-2463	16	23	ligand	ligand	NOUN
eurjchem-2463	16	24	and	and	CCONJ
eurjchem-2463	16	25	one	one	NUM
eurjchem-2463	16	26	chlorine	chlorine	NOUN
eurjchem-2463	16	27	atom	atom	NOUN
eurjchem-2463	16	28	occupying	occupy	VERB
eurjchem-2463	16	29	the	the	DET
eurjchem-2463	16	30	equatorial	equatorial	ADJ
eurjchem-2463	16	31	plane	plane	NOUN
eurjchem-2463	16	32	.	.	PUNCT
eurjchem-2463	17	1	the	the	DET
eurjchem-2463	17	2	axial	axial	ADJ
eurjchem-2463	17	3	positions	position	NOUN
eurjchem-2463	17	4	of	of	ADP
eurjchem-2463	17	5	the	the	DET
eurjchem-2463	17	6	octahedron	octahedron	NOUN
eurjchem-2463	17	7	are	be	AUX
eurjchem-2463	17	8	occupied	occupy	VERB
eurjchem-2463	17	9	by	by	ADP
eurjchem-2463	17	10	the	the	DET
eurjchem-2463	17	11	other	other	ADJ
eurjchem-2463	17	12	two	two	NUM
eurjchem-2463	17	13	chlorido	chlorido	NOUN
eurjchem-2463	17	14	ligands	ligand	NOUN
eurjchem-2463	17	15	in	in	ADP
eurjchem-2463	17	16	both	both	DET
eurjchem-2463	17	17	complexes	complex	NOUN
eurjchem-2463	17	18	.	.	PUNCT
eurjchem-2463	18	1	the	the	DET
eurjchem-2463	18	2	nh	nh	PROPN
eurjchem-2463	18	3	spacer	spacer	NOUN
eurjchem-2463	18	4	groups	group	NOUN
eurjchem-2463	18	5	in	in	ADP
eurjchem-2463	18	6	the	the	DET
eurjchem-2463	18	7	pnp	pnp	PROPN
eurjchem-2463	18	8	ligands	ligand	NOUN
eurjchem-2463	18	9	have	have	VERB
eurjchem-2463	18	10	an	an	DET
eurjchem-2463	18	11	important	important	ADJ
eurjchem-2463	18	12	role	role	NOUN
eurjchem-2463	18	13	in	in	ADP
eurjchem-2463	18	14	the	the	DET
eurjchem-2463	18	15	establishment	establishment	NOUN
eurjchem-2463	18	16	of	of	ADP
eurjchem-2463	18	17	hydrogen	hydrogen	NOUN
eurjchem-2463	18	18	bonds	bond	NOUN
eurjchem-2463	18	19	between	between	ADP
eurjchem-2463	18	20	the	the	DET
eurjchem-2463	18	21	complexes	complex	NOUN
eurjchem-2463	18	22	and	and	CCONJ
eurjchem-2463	18	23	molecules	molecule	NOUN
eurjchem-2463	18	24	of	of	ADP
eurjchem-2463	18	25	the	the	DET
eurjchem-2463	18	26	solvent	solvent	NOUN
eurjchem-2463	18	27	or	or	CCONJ
eurjchem-2463	18	28	neighbouring	neighbouring	ADJ
eurjchem-2463	18	29	species	specie	NOUN
eurjchem-2463	18	30	.	.	PUNCT
eurjchem-2463	19	1	titanium	titanium	NOUN
eurjchem-2463	19	2	molybdenum	molybdenum	NOUN
eurjchem-2463	19	3	pincer	pincer	NOUN
eurjchem-2463	19	4	ligands	ligand	NOUN
eurjchem-2463	19	5	metal	metal	NOUN
eurjchem-2463	19	6	complexes	complex	NOUN
eurjchem-2463	19	7	hydrogen	hydrogen	NOUN
eurjchem-2463	19	8	bonding	bond	VERB
eurjchem-2463	19	9	single	single	ADJ
eurjchem-2463	19	10	-	-	PUNCT
eurjchem-2463	19	11	crystal	crystal	NOUN
eurjchem-2463	19	12	x	x	ADJ
eurjchem-2463	19	13	-	-	NOUN
eurjchem-2463	19	14	ray	ray	NOUN
eurjchem-2463	19	15	diffraction	diffraction	NOUN
eurjchem-2463	19	16	cite	cite	VERB
eurjchem-2463	19	17	this	this	PRON
eurjchem-2463	19	18	:	:	PUNCT
eurjchem-2463	19	19	eur	eur	PROPN
eurjchem-2463	19	20	.	.	PUNCT
eurjchem-2463	20	1	j.	j.	PROPN
eurjchem-2463	20	2	chem	chem	PROPN
eurjchem-2463	20	3	.	.	PUNCT
eurjchem-2463	21	1	2023	2023	NUM
eurjchem-2463	21	2	,	,	PUNCT
eurjchem-2463	21	3	14(3	14(3	NUM
eurjchem-2463	21	4	)	)	PUNCT
eurjchem-2463	21	5	,	,	PUNCT
eurjchem-2463	21	6	311	311	NUM
eurjchem-2463	21	7	-	-	SYM
eurjchem-2463	21	8	315	315	NUM
eurjchem-2463	21	9	journal	journal	NOUN
eurjchem-2463	21	10	website	website	NOUN
eurjchem-2463	21	11	:	:	PUNCT
eurjchem-2463	21	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2463	21	13	1	1	X
eurjchem-2463	21	14	.	.	PUNCT
eurjchem-2463	21	15	introduction	introduction	NOUN
eurjchem-2463	21	16	pincer	pincer	NOUN
eurjchem-2463	21	17	ligands	ligand	NOUN
eurjchem-2463	21	18	are	be	AUX
eurjchem-2463	21	19	tridentate	tridentate	ADJ
eurjchem-2463	21	20	chelating	chelating	NOUN
eurjchem-2463	21	21	species	specie	NOUN
eurjchem-2463	21	22	that	that	PRON
eurjchem-2463	21	23	bind	bind	VERB
eurjchem-2463	21	24	tightly	tightly	ADV
eurjchem-2463	21	25	to	to	ADP
eurjchem-2463	21	26	three	three	NUM
eurjchem-2463	21	27	adjacent	adjacent	ADJ
eurjchem-2463	21	28	coplanar	coplanar	ADJ
eurjchem-2463	21	29	coordination	coordination	NOUN
eurjchem-2463	21	30	positions	position	NOUN
eurjchem-2463	21	31	of	of	ADP
eurjchem-2463	21	32	a	a	DET
eurjchem-2463	21	33	metal	metal	NOUN
eurjchem-2463	21	34	center	center	NOUN
eurjchem-2463	21	35	,	,	PUNCT
eurjchem-2463	21	36	typically	typically	ADV
eurjchem-2463	21	37	in	in	ADP
eurjchem-2463	21	38	a	a	DET
eurjchem-2463	21	39	meridional	meridional	ADJ
eurjchem-2463	21	40	configuration	configuration	NOUN
eurjchem-2463	21	41	[	[	X
eurjchem-2463	21	42	1	1	NUM
eurjchem-2463	21	43	]	]	PUNCT
eurjchem-2463	21	44	.	.	PUNCT
eurjchem-2463	22	1	the	the	DET
eurjchem-2463	22	2	stereochemical	stereochemical	ADJ
eurjchem-2463	22	3	parameters	parameter	NOUN
eurjchem-2463	22	4	of	of	ADP
eurjchem-2463	22	5	this	this	DET
eurjchem-2463	22	6	type	type	NOUN
eurjchem-2463	22	7	of	of	ADP
eurjchem-2463	22	8	ligands	ligand	NOUN
eurjchem-2463	22	9	can	can	AUX
eurjchem-2463	22	10	be	be	AUX
eurjchem-2463	22	11	easily	easily	ADV
eurjchem-2463	22	12	controlled	control	VERB
eurjchem-2463	22	13	by	by	ADP
eurjchem-2463	22	14	modification	modification	NOUN
eurjchem-2463	22	15	of	of	ADP
eurjchem-2463	22	16	the	the	DET
eurjchem-2463	22	17	substituents	substituent	NOUN
eurjchem-2463	22	18	at	at	ADP
eurjchem-2463	22	19	the	the	DET
eurjchem-2463	22	20	donor	donor	NOUN
eurjchem-2463	22	21	sites	site	NOUN
eurjchem-2463	22	22	and/or	and/or	CCONJ
eurjchem-2463	22	23	spacers	spacer	VERB
eurjchem-2463	22	24	[	[	X
eurjchem-2463	22	25	2,3	2,3	NUM
eurjchem-2463	22	26	]	]	PUNCT
eurjchem-2463	22	27	.	.	PUNCT
eurjchem-2463	23	1	due	due	ADP
eurjchem-2463	23	2	to	to	ADP
eurjchem-2463	23	3	those	those	DET
eurjchem-2463	23	4	characteristics	characteristic	NOUN
eurjchem-2463	23	5	,	,	PUNCT
eurjchem-2463	23	6	interest	interest	NOUN
eurjchem-2463	23	7	in	in	ADP
eurjchem-2463	23	8	pincer	pincer	NOUN
eurjchem-2463	23	9	ligands	ligand	NOUN
eurjchem-2463	23	10	has	have	AUX
eurjchem-2463	23	11	increased	increase	VERB
eurjchem-2463	23	12	over	over	ADP
eurjchem-2463	23	13	the	the	DET
eurjchem-2463	23	14	last	last	ADJ
eurjchem-2463	23	15	few	few	ADJ
eurjchem-2463	23	16	years	year	NOUN
eurjchem-2463	23	17	as	as	SCONJ
eurjchem-2463	23	18	their	their	PRON
eurjchem-2463	23	19	metal	metal	NOUN
eurjchem-2463	23	20	complexes	complex	NOUN
eurjchem-2463	23	21	display	display	VERB
eurjchem-2463	23	22	interesting	interesting	ADJ
eurjchem-2463	23	23	thermodynamic	thermodynamic	ADJ
eurjchem-2463	23	24	and	and	CCONJ
eurjchem-2463	23	25	kinetic	kinetic	ADJ
eurjchem-2463	23	26	properties	property	NOUN
eurjchem-2463	23	27	[	[	X
eurjchem-2463	23	28	4	4	NUM
eurjchem-2463	23	29	]	]	PUNCT
eurjchem-2463	23	30	.	.	PUNCT
eurjchem-2463	24	1	anionic	anionic	ADJ
eurjchem-2463	24	2	pincer	pincer	NOUN
eurjchem-2463	24	3	ligands	ligand	NOUN
eurjchem-2463	24	4	based	base	VERB
eurjchem-2463	24	5	on	on	ADP
eurjchem-2463	24	6	1,3disubsituted	1,3disubsituted	NUM
eurjchem-2463	24	7	benzenes	benzene	NOUN
eurjchem-2463	24	8	were	be	AUX
eurjchem-2463	24	9	the	the	DET
eurjchem-2463	24	10	first	first	ADJ
eurjchem-2463	24	11	to	to	PART
eurjchem-2463	24	12	be	be	AUX
eurjchem-2463	24	13	described	describe	VERB
eurjchem-2463	24	14	and	and	CCONJ
eurjchem-2463	24	15	are	be	AUX
eurjchem-2463	24	16	still	still	ADV
eurjchem-2463	24	17	the	the	DET
eurjchem-2463	24	18	most	most	ADV
eurjchem-2463	24	19	used	used	ADJ
eurjchem-2463	24	20	pincer	pincer	NOUN
eurjchem-2463	24	21	structures	structure	NOUN
eurjchem-2463	24	22	[	[	X
eurjchem-2463	24	23	5	5	NUM
eurjchem-2463	24	24	]	]	PUNCT
eurjchem-2463	24	25	.	.	PUNCT
eurjchem-2463	25	1	more	more	ADV
eurjchem-2463	25	2	recently	recently	ADV
eurjchem-2463	25	3	,	,	PUNCT
eurjchem-2463	25	4	pincer	pincer	NOUN
eurjchem-2463	25	5	ligands	ligand	NOUN
eurjchem-2463	25	6	based	base	VERB
eurjchem-2463	25	7	on	on	ADP
eurjchem-2463	25	8	2,6	2,6	NOUN
eurjchem-2463	25	9	-	-	NOUN
eurjchem-2463	25	10	diaminopyridines	diaminopyridine	NOUN
eurjchem-2463	25	11	have	have	AUX
eurjchem-2463	25	12	attracted	attract	VERB
eurjchem-2463	25	13	considerable	considerable	ADJ
eurjchem-2463	25	14	attention	attention	NOUN
eurjchem-2463	25	15	because	because	SCONJ
eurjchem-2463	25	16	their	their	PRON
eurjchem-2463	25	17	mid	mid	ADJ
eurjchem-2463	25	18	to	to	ADP
eurjchem-2463	25	19	late	late	ADJ
eurjchem-2463	25	20	transition	transition	NOUN
eurjchem-2463	25	21	metal	metal	NOUN
eurjchem-2463	25	22	complexes	complex	NOUN
eurjchem-2463	25	23	have	have	AUX
eurjchem-2463	25	24	shown	show	VERB
eurjchem-2463	25	25	important	important	ADJ
eurjchem-2463	25	26	catalytic	catalytic	ADJ
eurjchem-2463	25	27	applications	application	NOUN
eurjchem-2463	25	28	[	[	X
eurjchem-2463	25	29	6	6	NUM
eurjchem-2463	25	30	-	-	SYM
eurjchem-2463	25	31	10	10	NUM
eurjchem-2463	25	32	]	]	PUNCT
eurjchem-2463	25	33	.	.	PUNCT
eurjchem-2463	26	1	on	on	ADP
eurjchem-2463	26	2	the	the	DET
eurjchem-2463	26	3	contrary	contrary	NOUN
eurjchem-2463	26	4	,	,	PUNCT
eurjchem-2463	26	5	early	early	ADJ
eurjchem-2463	26	6	transition	transition	NOUN
eurjchem-2463	26	7	metal	metal	NOUN
eurjchem-2463	26	8	complexes	complex	NOUN
eurjchem-2463	26	9	supported	support	VERB
eurjchem-2463	26	10	by	by	ADP
eurjchem-2463	26	11	this	this	DET
eurjchem-2463	26	12	type	type	NOUN
eurjchem-2463	26	13	of	of	ADP
eurjchem-2463	26	14	ligand	ligand	NOUN
eurjchem-2463	26	15	are	be	AUX
eurjchem-2463	26	16	still	still	ADV
eurjchem-2463	26	17	much	much	ADV
eurjchem-2463	26	18	less	less	ADV
eurjchem-2463	26	19	explored	explore	VERB
eurjchem-2463	26	20	,	,	PUNCT
eurjchem-2463	26	21	limited	limit	VERB
eurjchem-2463	26	22	to	to	ADP
eurjchem-2463	26	23	vanadium	vanadium	NOUN
eurjchem-2463	26	24	species	specie	NOUN
eurjchem-2463	26	25	[	[	X
eurjchem-2463	26	26	11,12	11,12	NUM
eurjchem-2463	26	27	]	]	PUNCT
eurjchem-2463	26	28	.	.	PUNCT
eurjchem-2463	27	1	these	these	DET
eurjchem-2463	27	2	complexes	complex	NOUN
eurjchem-2463	27	3	were	be	AUX
eurjchem-2463	27	4	found	find	VERB
eurjchem-2463	27	5	to	to	PART
eurjchem-2463	27	6	catalyse	catalyse	VERB
eurjchem-2463	27	7	the	the	DET
eurjchem-2463	27	8	homocoupling	homocoupling	NOUN
eurjchem-2463	27	9	of	of	ADP
eurjchem-2463	27	10	phenylmagnesium	phenylmagnesium	NOUN
eurjchem-2463	27	11	bromide	bromide	NOUN
eurjchem-2463	27	12	in	in	ADP
eurjchem-2463	27	13	the	the	DET
eurjchem-2463	27	14	presence	presence	NOUN
eurjchem-2463	27	15	of	of	ADP
eurjchem-2463	27	16	iodomethane	iodomethane	NOUN
eurjchem-2463	27	17	as	as	ADP
eurjchem-2463	27	18	an	an	DET
eurjchem-2463	27	19	oxidising	oxidising	NOUN
eurjchem-2463	27	20	agent	agent	NOUN
eurjchem-2463	27	21	,	,	PUNCT
eurjchem-2463	27	22	at	at	ADP
eurjchem-2463	27	23	room	room	NOUN
eurjchem-2463	27	24	temperature	temperature	NOUN
eurjchem-2463	27	25	,	,	PUNCT
eurjchem-2463	27	26	to	to	PART
eurjchem-2463	27	27	give	give	VERB
eurjchem-2463	27	28	phenylbenzene	phenylbenzene	NOUN
eurjchem-2463	27	29	[	[	X
eurjchem-2463	27	30	12	12	NUM
eurjchem-2463	27	31	]	]	PUNCT
eurjchem-2463	27	32	.	.	PUNCT
eurjchem-2463	28	1	although	although	SCONJ
eurjchem-2463	28	2	a	a	DET
eurjchem-2463	28	3	variety	variety	NOUN
eurjchem-2463	28	4	of	of	ADP
eurjchem-2463	28	5	molybdenum	molybdenum	NOUN
eurjchem-2463	28	6	complexes	complex	NOUN
eurjchem-2463	28	7	in	in	ADP
eurjchem-2463	28	8	several	several	ADJ
eurjchem-2463	28	9	oxidation	oxidation	NOUN
eurjchem-2463	28	10	states	state	NOUN
eurjchem-2463	28	11	can	can	AUX
eurjchem-2463	28	12	be	be	AUX
eurjchem-2463	28	13	found	find	VERB
eurjchem-2463	28	14	in	in	ADP
eurjchem-2463	28	15	the	the	DET
eurjchem-2463	28	16	literature	literature	NOUN
eurjchem-2463	28	17	[	[	X
eurjchem-2463	28	18	13	13	NUM
eurjchem-2463	28	19	-	-	SYM
eurjchem-2463	28	20	25	25	NUM
eurjchem-2463	28	21	]	]	PUNCT
eurjchem-2463	28	22	,	,	PUNCT
eurjchem-2463	28	23	mo(iii	mo(iii	X
eurjchem-2463	28	24	)	)	PUNCT
eurjchem-2463	28	25	complexes	complex	NOUN
eurjchem-2463	28	26	are	be	AUX
eurjchem-2463	28	27	scarcely	scarcely	ADV
eurjchem-2463	28	28	reported	report	VERB
eurjchem-2463	28	29	[	[	PUNCT
eurjchem-2463	28	30	26	26	NUM
eurjchem-2463	28	31	-	-	SYM
eurjchem-2463	28	32	28	28	NUM
eurjchem-2463	28	33	]	]	PUNCT
eurjchem-2463	28	34	.	.	PUNCT
eurjchem-2463	29	1	in	in	ADP
eurjchem-2463	29	2	the	the	DET
eurjchem-2463	29	3	presence	presence	NOUN
eurjchem-2463	29	4	of	of	ADP
eurjchem-2463	29	5	cocp*2	cocp*2	PRON
eurjchem-2463	29	6	(	(	PUNCT
eurjchem-2463	29	7	cp	cp	X
eurjchem-2463	29	8	*	*	PUNCT
eurjchem-2463	29	9	=	=	SYM
eurjchem-2463	29	10	η5	η5	VERB
eurjchem-2463	29	11	-	-	PUNCT
eurjchem-2463	29	12	c5h5	c5h5	NOUN
eurjchem-2463	29	13	)	)	PUNCT
eurjchem-2463	29	14	as	as	ADP
eurjchem-2463	29	15	a	a	DET
eurjchem-2463	29	16	reducing	reduce	VERB
eurjchem-2463	29	17	agent	agent	NOUN
eurjchem-2463	29	18	and	and	CCONJ
eurjchem-2463	29	19	2,4,6	2,4,6	NUM
eurjchem-2463	29	20	-	-	PUNCT
eurjchem-2463	29	21	colidinium	colidinium	NOUN
eurjchem-2463	29	22	trifluoromethanesulfonate	trifluoromethanesulfonate	NOUN
eurjchem-2463	29	23	as	as	ADP
eurjchem-2463	29	24	a	a	DET
eurjchem-2463	29	25	proton	proton	NOUN
eurjchem-2463	29	26	source	source	NOUN
eurjchem-2463	29	27	,	,	PUNCT
eurjchem-2463	29	28	complexes	complex	NOUN
eurjchem-2463	29	29	of	of	ADP
eurjchem-2463	29	30	the	the	DET
eurjchem-2463	29	31	formula	formula	NOUN
eurjchem-2463	29	32	[	[	X
eurjchem-2463	29	33	(	(	PUNCT
eurjchem-2463	29	34	r	r	NOUN
eurjchem-2463	29	35	-	-	PUNCT
eurjchem-2463	29	36	pnpr’)moi3	pnpr’)moi3	NUM
eurjchem-2463	29	37	]	]	PUNCT
eurjchem-2463	29	38	(	(	PUNCT
eurjchem-2463	29	39	r	r	NOUN
eurjchem-2463	29	40	=	=	SYM
eurjchem-2463	29	41	h	h	NOUN
eurjchem-2463	29	42	,	,	PUNCT
eurjchem-2463	29	43	ph	ph	VERB
eurjchem-2463	29	44	,	,	PUNCT
eurjchem-2463	29	45	me	i	PRON
eurjchem-2463	29	46	,	,	PUNCT
eurjchem-2463	29	47	meo	meo	NOUN
eurjchem-2463	29	48	,	,	PUNCT
eurjchem-2463	29	49	ferrocenyl	ferrocenyl	NOUN
eurjchem-2463	29	50	,	,	PUNCT
eurjchem-2463	29	51	and	and	CCONJ
eurjchem-2463	29	52	ruthenocenyl	ruthenocenyl	NOUN
eurjchem-2463	29	53	;	;	PUNCT
eurjchem-2463	29	54	r	r	X
eurjchem-2463	29	55	’	'	PUNCT
eurjchem-2463	29	56	=	=	SYM
eurjchem-2463	29	57	tbu	tbu	PROPN
eurjchem-2463	29	58	,	,	PUNCT
eurjchem-2463	29	59	ipr	ipr	PROPN
eurjchem-2463	29	60	,	,	PUNCT
eurjchem-2463	29	61	ph	ph	NOUN
eurjchem-2463	29	62	,	,	PUNCT
eurjchem-2463	29	63	and	and	CCONJ
eurjchem-2463	29	64	adamantyl	adamantyl	PROPN
eurjchem-2463	29	65	)	)	PUNCT
eurjchem-2463	29	66	were	be	AUX
eurjchem-2463	29	67	effective	effective	ADJ
eurjchem-2463	29	68	catalysts	catalyst	NOUN
eurjchem-2463	29	69	to	to	PART
eurjchem-2463	29	70	produce	produce	VERB
eurjchem-2463	29	71	ammonia	ammonia	NOUN
eurjchem-2463	29	72	from	from	ADP
eurjchem-2463	29	73	molecular	molecular	ADJ
eurjchem-2463	29	74	dinitrogen	dinitrogen	NOUN
eurjchem-2463	29	75	under	under	ADP
eurjchem-2463	29	76	ambient	ambient	ADJ
eurjchem-2463	29	77	conditions	condition	NOUN
eurjchem-2463	29	78	[	[	X
eurjchem-2463	29	79	28	28	NUM
eurjchem-2463	29	80	]	]	PUNCT
eurjchem-2463	29	81	.	.	PUNCT
eurjchem-2463	30	1	here	here	ADV
eurjchem-2463	30	2	,	,	PUNCT
eurjchem-2463	30	3	we	we	PRON
eurjchem-2463	30	4	describe	describe	VERB
eurjchem-2463	30	5	the	the	DET
eurjchem-2463	30	6	synthesis	synthesis	NOUN
eurjchem-2463	30	7	and	and	CCONJ
eurjchem-2463	30	8	structural	structural	ADJ
eurjchem-2463	30	9	characterisation	characterisation	NOUN
eurjchem-2463	30	10	of	of	ADP
eurjchem-2463	30	11	new	new	ADJ
eurjchem-2463	30	12	ti(iii	ti(iii	NOUN
eurjchem-2463	30	13	)	)	PUNCT
eurjchem-2463	30	14	and	and	CCONJ
eurjchem-2463	30	15	mo(iii	mo(iii	NOUN
eurjchem-2463	30	16	)	)	PUNCT
eurjchem-2463	30	17	complexes	complex	NOUN
eurjchem-2463	30	18	supported	support	VERB
eurjchem-2463	30	19	by	by	ADP
eurjchem-2463	30	20	pnp	pnp	PROPN
eurjchem-2463	30	21	pincer	pincer	NOUN
eurjchem-2463	30	22	ligands	ligand	NOUN
eurjchem-2463	30	23	based	base	VERB
eurjchem-2463	30	24	on	on	ADP
eurjchem-2463	30	25	2,6	2,6	NUM
eurjchem-2463	30	26	-	-	NOUN
eurjchem-2463	30	27	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	30	28	.	.	PUNCT
eurjchem-2463	31	1	2	2	X
eurjchem-2463	31	2	.	.	X
eurjchem-2463	31	3	experimental	experimental	ADJ
eurjchem-2463	31	4	2.1	2.1	NUM
eurjchem-2463	31	5	.	.	PUNCT
eurjchem-2463	32	1	general	general	ADJ
eurjchem-2463	32	2	considerations	consideration	NOUN
eurjchem-2463	32	3	the	the	DET
eurjchem-2463	32	4	compounds	compound	NOUN
eurjchem-2463	32	5	n	n	CCONJ
eurjchem-2463	32	6	,	,	PUNCT
eurjchem-2463	32	7	n’-bis(diphenylphosphino)-2,6	n’-bis(diphenylphosphino)-2,6	PROPN
eurjchem-2463	32	8	-	-	NOUN
eurjchem-2463	32	9	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	32	10	(	(	PUNCT
eurjchem-2463	32	11	pnp	pnp	NOUN
eurjchem-2463	32	12	-	-	PUNCT
eurjchem-2463	32	13	ph	ph	NOUN
eurjchem-2463	32	14	)	)	PUNCT
eurjchem-2463	33	1	[	[	X
eurjchem-2463	33	2	29	29	NUM
eurjchem-2463	33	3	]	]	PUNCT
eurjchem-2463	33	4	and	and	CCONJ
eurjchem-2463	33	5	n	n	CCONJ
eurjchem-2463	33	6	,	,	PUNCT
eurjchem-2463	33	7	n’-bis(diisopropylphosphino)2,6	n’-bis(diisopropylphosphino)2,6	NOUN
eurjchem-2463	33	8	-	-	PUNCT
eurjchem-2463	33	9	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	33	10	(	(	PUNCT
eurjchem-2463	33	11	pnp	pnp	NOUN
eurjchem-2463	33	12	-	-	PUNCT
eurjchem-2463	33	13	ipr	ipr	PROPN
eurjchem-2463	33	14	)	)	PUNCT
eurjchem-2463	34	1	[	[	X
eurjchem-2463	34	2	21	21	NUM
eurjchem-2463	34	3	]	]	PUNCT
eurjchem-2463	34	4	were	be	AUX
eurjchem-2463	34	5	prepared	prepare	VERB
eurjchem-2463	34	6	according	accord	VERB
eurjchem-2463	34	7	to	to	ADP
eurjchem-2463	34	8	the	the	DET
eurjchem-2463	34	9	literature	literature	NOUN
eurjchem-2463	34	10	.	.	PUNCT
eurjchem-2463	35	1	abstract	abstract	ADJ
eurjchem-2463	35	2	research	research	NOUN
eurjchem-2463	35	3	article	article	NOUN
eurjchem-2463	35	4	keywords	keyword	VERB
eurjchem-2463	35	5	https://dx.doi.org/10.5155/eurjchem.14.3.311-315.2463	https://dx.doi.org/10.5155/eurjchem.14.3.311-315.2463	PROPN
eurjchem-2463	35	6	https://www.eurjchem.com/	https://www.eurjchem.com/	ADJ
eurjchem-2463	35	7	https://dx.doi.org/10.5155/eurjchem.14.3.311-315.2463	https://dx.doi.org/10.5155/eurjchem.14.3.311-315.2463	PROPN
eurjchem-2463	35	8	mailto:luis.g.alves@tecnico.ulisboa.pt	mailto:luis.g.alves@tecnico.ulisboa.pt	PROPN
eurjchem-2463	35	9	mailto:ana.martins@tecnico.ulisboa.pt	mailto:ana.martins@tecnico.ulisboa.pt	NOUN
eurjchem-2463	35	10	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2463	35	11	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.3.311-315.2463&domain=pdf&date_stamp=2023-09-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.3.311-315.2463&domain=pdf&date_stamp=2023-09-30	VERB
eurjchem-2463	35	12	312	312	NUM
eurjchem-2463	35	13	ruivo	ruivo	NOUN
eurjchem-2463	35	14	et	et	PROPN
eurjchem-2463	35	15	al	al	PROPN
eurjchem-2463	35	16	.	.	PUNCT
eurjchem-2463	35	17	/	/	SYM
eurjchem-2463	35	18	european	european	PROPN
eurjchem-2463	35	19	journal	journal	PROPN
eurjchem-2463	35	20	of	of	ADP
eurjchem-2463	35	21	chemistry	chemistry	NOUN
eurjchem-2463	35	22	14	14	NUM
eurjchem-2463	35	23	(	(	PUNCT
eurjchem-2463	35	24	3	3	NUM
eurjchem-2463	35	25	)	)	PUNCT
eurjchem-2463	35	26	(	(	PUNCT
eurjchem-2463	35	27	2023	2023	NUM
eurjchem-2463	35	28	)	)	PUNCT
eurjchem-2463	35	29	311	311	NUM
eurjchem-2463	35	30	-	-	SYM
eurjchem-2463	35	31	315	315	NUM
eurjchem-2463	35	32	2023	2023	NUM
eurjchem-2463	35	33	–	–	PUNCT
eurjchem-2463	35	34	european	european	ADJ
eurjchem-2463	35	35	journal	journal	NOUN
eurjchem-2463	35	36	of	of	ADP
eurjchem-2463	35	37	chemistry	chemistry	NOUN
eurjchem-2463	35	38	–	–	PUNCT
eurjchem-2463	35	39	cc	cc	NOUN
eurjchem-2463	35	40	by	by	ADP
eurjchem-2463	35	41	nc	nc	PROPN
eurjchem-2463	35	42	–	–	PUNCT
eurjchem-2463	35	43	doi	doi	NOUN
eurjchem-2463	35	44	:	:	PUNCT
eurjchem-2463	35	45	10.5155	10.5155	NUM
eurjchem-2463	35	46	/	/	SYM
eurjchem-2463	35	47	eurjchem.14.3.311	eurjchem.14.3.311	NUM
eurjchem-2463	35	48	-	-	SYM
eurjchem-2463	35	49	315.2463	315.2463	NUM
eurjchem-2463	35	50	scheme	scheme	NOUN
eurjchem-2463	35	51	1	1	NUM
eurjchem-2463	35	52	.	.	PUNCT
eurjchem-2463	36	1	synthetic	synthetic	ADJ
eurjchem-2463	36	2	route	route	NOUN
eurjchem-2463	36	3	for	for	ADP
eurjchem-2463	36	4	the	the	DET
eurjchem-2463	36	5	preparation	preparation	NOUN
eurjchem-2463	36	6	of	of	ADP
eurjchem-2463	36	7	[	[	X
eurjchem-2463	36	8	(	(	PUNCT
eurjchem-2463	36	9	pnp)mcl3	pnp)mcl3	NOUN
eurjchem-2463	36	10	]	]	X
eurjchem-2463	36	11	(	(	PUNCT
eurjchem-2463	36	12	m	m	NOUN
eurjchem-2463	36	13	=	=	SYM
eurjchem-2463	36	14	ti	ti	NOUN
eurjchem-2463	36	15	,	,	PUNCT
eurjchem-2463	36	16	1	1	NUM
eurjchem-2463	36	17	,	,	PUNCT
eurjchem-2463	36	18	and	and	CCONJ
eurjchem-2463	36	19	m	m	PROPN
eurjchem-2463	36	20	=	=	SYM
eurjchem-2463	36	21	mo	mo	PROPN
eurjchem-2463	36	22	,	,	PUNCT
eurjchem-2463	36	23	2	2	NUM
eurjchem-2463	36	24	)	)	PUNCT
eurjchem-2463	36	25	complexes	complex	NOUN
eurjchem-2463	36	26	.	.	PUNCT
eurjchem-2463	37	1	all	all	DET
eurjchem-2463	37	2	other	other	ADJ
eurjchem-2463	37	3	reagents	reagent	NOUN
eurjchem-2463	37	4	were	be	AUX
eurjchem-2463	37	5	commercial	commercial	ADJ
eurjchem-2463	37	6	grade	grade	NOUN
eurjchem-2463	37	7	and	and	CCONJ
eurjchem-2463	37	8	were	be	AUX
eurjchem-2463	37	9	used	use	VERB
eurjchem-2463	37	10	without	without	ADP
eurjchem-2463	37	11	further	further	ADJ
eurjchem-2463	37	12	purification	purification	NOUN
eurjchem-2463	37	13	.	.	PUNCT
eurjchem-2463	38	1	all	all	DET
eurjchem-2463	38	2	manipulations	manipulation	NOUN
eurjchem-2463	38	3	were	be	AUX
eurjchem-2463	38	4	performed	perform	VERB
eurjchem-2463	38	5	under	under	ADP
eurjchem-2463	38	6	an	an	DET
eurjchem-2463	38	7	inert	inert	ADJ
eurjchem-2463	38	8	atmosphere	atmosphere	NOUN
eurjchem-2463	38	9	of	of	ADP
eurjchem-2463	38	10	dry	dry	ADJ
eurjchem-2463	38	11	oxygen	oxygen	NOUN
eurjchem-2463	38	12	-	-	PUNCT
eurjchem-2463	38	13	free	free	ADJ
eurjchem-2463	38	14	nitrogen	nitrogen	NOUN
eurjchem-2463	38	15	by	by	ADP
eurjchem-2463	38	16	means	mean	NOUN
eurjchem-2463	38	17	of	of	ADP
eurjchem-2463	38	18	standard	standard	ADJ
eurjchem-2463	38	19	schlenk	schlenk	NOUN
eurjchem-2463	38	20	and	and	CCONJ
eurjchem-2463	38	21	glovebox	glovebox	NOUN
eurjchem-2463	38	22	techniques	technique	NOUN
eurjchem-2463	38	23	.	.	PUNCT
eurjchem-2463	39	1	solvents	solvent	NOUN
eurjchem-2463	39	2	were	be	AUX
eurjchem-2463	39	3	pre	pre	ADJ
eurjchem-2463	39	4	-	-	ADJ
eurjchem-2463	39	5	dried	dried	ADJ
eurjchem-2463	39	6	using	use	VERB
eurjchem-2463	39	7	4	4	NUM
eurjchem-2463	39	8	å	å	PROPN
eurjchem-2463	39	9	molecular	molecular	ADJ
eurjchem-2463	39	10	sieves	sieve	NOUN
eurjchem-2463	39	11	and	and	CCONJ
eurjchem-2463	39	12	refluxed	refluxe	VERB
eurjchem-2463	39	13	over	over	ADP
eurjchem-2463	39	14	sodium	sodium	NOUN
eurjchem-2463	39	15	benzophenone	benzophenone	NOUN
eurjchem-2463	39	16	in	in	ADP
eurjchem-2463	39	17	an	an	DET
eurjchem-2463	39	18	atmosphere	atmosphere	NOUN
eurjchem-2463	39	19	of	of	ADP
eurjchem-2463	39	20	n2	n2	NOUN
eurjchem-2463	39	21	and	and	CCONJ
eurjchem-2463	39	22	collected	collect	VERB
eurjchem-2463	39	23	by	by	ADP
eurjchem-2463	39	24	distillation	distillation	NOUN
eurjchem-2463	39	25	.	.	PUNCT
eurjchem-2463	40	1	the	the	DET
eurjchem-2463	40	2	1h	1h	NUM
eurjchem-2463	40	3	and	and	CCONJ
eurjchem-2463	40	4	31p{1h	31p{1h	NUM
eurjchem-2463	40	5	}	}	PUNCT
eurjchem-2463	40	6	nmr	nmr	NOUN
eurjchem-2463	40	7	spectra	spectra	NOUN
eurjchem-2463	40	8	were	be	AUX
eurjchem-2463	40	9	recorded	record	VERB
eurjchem-2463	40	10	on	on	ADP
eurjchem-2463	40	11	a	a	DET
eurjchem-2463	40	12	bruker	bruker	NOUN
eurjchem-2463	40	13	avance-250	avance-250	NOUN
eurjchem-2463	40	14	spectrometer	spectrometer	NOUN
eurjchem-2463	40	15	at	at	ADP
eurjchem-2463	40	16	296	296	NUM
eurjchem-2463	40	17	k	k	NOUN
eurjchem-2463	40	18	and	and	CCONJ
eurjchem-2463	40	19	referenced	reference	VERB
eurjchem-2463	40	20	to	to	PART
eurjchem-2463	40	21	tetramethylsilane	tetramethylsilane	VERB
eurjchem-2463	40	22	and	and	CCONJ
eurjchem-2463	40	23	h3po4	h3po4	NOUN
eurjchem-2463	40	24	(	(	PUNCT
eurjchem-2463	40	25	85	85	NUM
eurjchem-2463	40	26	%	%	NOUN
eurjchem-2463	40	27	)	)	PUNCT
eurjchem-2463	40	28	,	,	PUNCT
eurjchem-2463	40	29	respectively	respectively	ADV
eurjchem-2463	40	30	.	.	PUNCT
eurjchem-2463	41	1	elemental	elemental	ADJ
eurjchem-2463	41	2	analyses	analysis	NOUN
eurjchem-2463	41	3	(	(	PUNCT
eurjchem-2463	41	4	c	c	X
eurjchem-2463	41	5	,	,	PUNCT
eurjchem-2463	41	6	h	h	NOUN
eurjchem-2463	41	7	,	,	PUNCT
eurjchem-2463	41	8	n	n	CCONJ
eurjchem-2463	41	9	)	)	PUNCT
eurjchem-2463	41	10	were	be	AUX
eurjchem-2463	41	11	performed	perform	VERB
eurjchem-2463	41	12	in	in	ADP
eurjchem-2463	41	13	a	a	DET
eurjchem-2463	41	14	fisons	fison	NOUN
eurjchem-2463	41	15	chns	chns	ADJ
eurjchem-2463	41	16	/	/	SYM
eurjchem-2463	41	17	o	o	PROPN
eurjchem-2463	41	18	analyser	analyser	NOUN
eurjchem-2463	41	19	carlo	carlo	NOUN
eurjchem-2463	41	20	erba	erba	PROPN
eurjchem-2463	41	21	instruments	instrument	NOUN
eurjchem-2463	41	22	ea-1108	ea-1108	VERB
eurjchem-2463	41	23	equipment	equipment	NOUN
eurjchem-2463	41	24	at	at	ADP
eurjchem-2463	41	25	the	the	DET
eurjchem-2463	41	26	laboratório	laboratório	PROPN
eurjchem-2463	41	27	de	de	PROPN
eurjchem-2463	41	28	análises	análise	NOUN
eurjchem-2463	41	29	do	do	VERB
eurjchem-2463	41	30	instituto	instituto	PROPN
eurjchem-2463	41	31	superior	superior	PROPN
eurjchem-2463	41	32	técnico	técnico	NOUN
eurjchem-2463	41	33	.	.	PUNCT
eurjchem-2463	42	1	2.2	2.2	NUM
eurjchem-2463	42	2	.	.	PUNCT
eurjchem-2463	42	3	synthesis	synthesis	NOUN
eurjchem-2463	42	4	and	and	CCONJ
eurjchem-2463	42	5	characterization	characterization	NOUN
eurjchem-2463	42	6	2.2.1	2.2.1	NUM
eurjchem-2463	42	7	.	.	PUNCT
eurjchem-2463	43	1	n	n	CCONJ
eurjchem-2463	43	2	,	,	PUNCT
eurjchem-2463	43	3	n’-bis(diphenylphosphino)-2,6	n’-bis(diphenylphosphino)-2,6	NOUN
eurjchem-2463	43	4	-	-	NOUN
eurjchem-2463	43	5	diaminopyridine	diaminopyridine	ADJ
eurjchem-2463	43	6	,	,	PUNCT
eurjchem-2463	43	7	pnp	pnp	NOUN
eurjchem-2463	43	8	-	-	PUNCT
eurjchem-2463	43	9	ph	ph	NOUN
eurjchem-2463	43	10	a	a	DET
eurjchem-2463	43	11	solution	solution	NOUN
eurjchem-2463	43	12	of	of	ADP
eurjchem-2463	43	13	ph2pcl	ph2pcl	PROPN
eurjchem-2463	43	14	(	(	PUNCT
eurjchem-2463	43	15	7.20	7.20	NUM
eurjchem-2463	43	16	ml	ml	NOUN
eurjchem-2463	43	17	,	,	PUNCT
eurjchem-2463	43	18	38.96	38.96	NUM
eurjchem-2463	43	19	mmol	mmol	NOUN
eurjchem-2463	43	20	)	)	PUNCT
eurjchem-2463	43	21	in	in	ADP
eurjchem-2463	43	22	toluene	toluene	NOUN
eurjchem-2463	43	23	(	(	PUNCT
eurjchem-2463	43	24	60	60	NUM
eurjchem-2463	43	25	ml	ml	NOUN
eurjchem-2463	43	26	)	)	PUNCT
eurjchem-2463	43	27	was	be	AUX
eurjchem-2463	43	28	added	add	VERB
eurjchem-2463	43	29	dropwise	dropwise	NOUN
eurjchem-2463	43	30	to	to	ADP
eurjchem-2463	43	31	a	a	DET
eurjchem-2463	43	32	solution	solution	NOUN
eurjchem-2463	43	33	of	of	ADP
eurjchem-2463	43	34	triethylamine	triethylamine	NOUN
eurjchem-2463	43	35	(	(	PUNCT
eurjchem-2463	43	36	5.11	5.11	NUM
eurjchem-2463	43	37	ml	ml	NOUN
eurjchem-2463	43	38	,	,	PUNCT
eurjchem-2463	43	39	36.66	36.66	NUM
eurjchem-2463	43	40	mmol	mmol	NOUN
eurjchem-2463	43	41	)	)	PUNCT
eurjchem-2463	43	42	and	and	CCONJ
eurjchem-2463	43	43	2,6	2,6	NUM
eurjchem-2463	43	44	-	-	NOUN
eurjchem-2463	43	45	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	43	46	(	(	PUNCT
eurjchem-2463	43	47	2.00	2.00	NUM
eurjchem-2463	43	48	g	g	NOUN
eurjchem-2463	43	49	,	,	PUNCT
eurjchem-2463	43	50	18.33	18.33	NUM
eurjchem-2463	43	51	mmol	mmol	NOUN
eurjchem-2463	43	52	)	)	PUNCT
eurjchem-2463	43	53	in	in	ADP
eurjchem-2463	43	54	the	the	DET
eurjchem-2463	43	55	same	same	ADJ
eurjchem-2463	43	56	solvent	solvent	NOUN
eurjchem-2463	43	57	(	(	PUNCT
eurjchem-2463	43	58	100	100	NUM
eurjchem-2463	43	59	ml	ml	NOUN
eurjchem-2463	43	60	)	)	PUNCT
eurjchem-2463	43	61	,	,	PUNCT
eurjchem-2463	43	62	at	at	ADP
eurjchem-2463	43	63	0	0	NUM
eurjchem-2463	43	64	°	°	ADP
eurjchem-2463	43	65	c	c	NOUN
eurjchem-2463	43	66	.	.	PUNCT
eurjchem-2463	44	1	the	the	DET
eurjchem-2463	44	2	reaction	reaction	NOUN
eurjchem-2463	44	3	mixture	mixture	NOUN
eurjchem-2463	44	4	was	be	AUX
eurjchem-2463	44	5	heated	heat	VERB
eurjchem-2463	44	6	to	to	ADP
eurjchem-2463	44	7	50	50	NUM
eurjchem-2463	44	8	°	°	NOUN
eurjchem-2463	44	9	c	c	NOUN
eurjchem-2463	44	10	,	,	PUNCT
eurjchem-2463	44	11	and	and	CCONJ
eurjchem-2463	44	12	the	the	DET
eurjchem-2463	44	13	precipitate	precipitate	NOUN
eurjchem-2463	44	14	formed	form	VERB
eurjchem-2463	44	15	was	be	AUX
eurjchem-2463	44	16	filtered	filter	VERB
eurjchem-2463	44	17	off	off	ADP
eurjchem-2463	44	18	.	.	PUNCT
eurjchem-2463	45	1	the	the	DET
eurjchem-2463	45	2	solvent	solvent	NOUN
eurjchem-2463	45	3	was	be	AUX
eurjchem-2463	45	4	removed	remove	VERB
eurjchem-2463	45	5	under	under	ADP
eurjchem-2463	45	6	vacuum	vacuum	NOUN
eurjchem-2463	45	7	and	and	CCONJ
eurjchem-2463	45	8	the	the	DET
eurjchem-2463	45	9	remaining	remain	VERB
eurjchem-2463	45	10	oil	oil	NOUN
eurjchem-2463	45	11	was	be	AUX
eurjchem-2463	45	12	recrystallized	recrystallize	VERB
eurjchem-2463	45	13	from	from	ADP
eurjchem-2463	45	14	toluene	toluene	NOUN
eurjchem-2463	45	15	/	/	SYM
eurjchem-2463	45	16	n	n	CCONJ
eurjchem-2463	45	17	-	-	PUNCT
eurjchem-2463	45	18	hexane	hexane	NOUN
eurjchem-2463	45	19	(	(	PUNCT
eurjchem-2463	45	20	1:1	1:1	NUM
eurjchem-2463	45	21	)	)	PUNCT
eurjchem-2463	45	22	.	.	PUNCT
eurjchem-2463	46	1	color	color	NOUN
eurjchem-2463	46	2	:	:	PUNCT
eurjchem-2463	46	3	white	white	ADJ
eurjchem-2463	46	4	.	.	PUNCT
eurjchem-2463	47	1	yield	yield	NOUN
eurjchem-2463	47	2	:	:	PUNCT
eurjchem-2463	47	3	91	91	NUM
eurjchem-2463	47	4	%	%	NOUN
eurjchem-2463	47	5	.	.	PUNCT
eurjchem-2463	48	1	1h	1h	NUM
eurjchem-2463	48	2	nmr	nmr	NOUN
eurjchem-2463	48	3	(	(	PUNCT
eurjchem-2463	48	4	250.0	250.0	NUM
eurjchem-2463	48	5	mhz	mhz	NOUN
eurjchem-2463	48	6	,	,	PUNCT
eurjchem-2463	48	7	cdcl3	cdcl3	PROPN
eurjchem-2463	48	8	,	,	PUNCT
eurjchem-2463	48	9	δ	δ	PROPN
eurjchem-2463	48	10	,	,	PUNCT
eurjchem-2463	48	11	ppm	ppm	NOUN
eurjchem-2463	48	12	):	):	PUNCT
eurjchem-2463	48	13	7.51	7.51	NUM
eurjchem-2463	48	14	-	-	SYM
eurjchem-2463	48	15	7.38	7.38	NUM
eurjchem-2463	48	16	(	(	PUNCT
eurjchem-2463	48	17	m	m	PROPN
eurjchem-2463	48	18	,	,	PUNCT
eurjchem-2463	48	19	21h	21h	PROPN
eurjchem-2463	48	20	,	,	PUNCT
eurjchem-2463	48	21	py	py	PROPN
eurjchem-2463	48	22	)	)	PUNCT
eurjchem-2463	48	23	,	,	PUNCT
eurjchem-2463	48	24	6.55	6.55	NUM
eurjchem-2463	48	25	(	(	PUNCT
eurjchem-2463	48	26	dd	dd	NOUN
eurjchem-2463	48	27	,	,	PUNCT
eurjchem-2463	48	28	j	j	PROPN
eurjchem-2463	48	29	=	=	SYM
eurjchem-2463	48	30	7.9	7.9	NUM
eurjchem-2463	48	31	hz	hz	VERB
eurjchem-2463	48	32	,	,	PUNCT
eurjchem-2463	48	33	j	j	PROPN
eurjchem-2463	49	1	=	=	SYM
eurjchem-2463	49	2	1.2	1.2	NUM
eurjchem-2463	49	3	,	,	PUNCT
eurjchem-2463	49	4	2h	2h	NUM
eurjchem-2463	49	5	,	,	PUNCT
eurjchem-2463	49	6	py	py	PROPN
eurjchem-2463	49	7	)	)	PUNCT
eurjchem-2463	49	8	,	,	PUNCT
eurjchem-2463	49	9	5.36	5.36	NUM
eurjchem-2463	49	10	(	(	PUNCT
eurjchem-2463	49	11	d	d	PROPN
eurjchem-2463	49	12	,	,	PUNCT
eurjchem-2463	49	13	j	j	PROPN
eurjchem-2463	49	14	=	=	PROPN
eurjchem-2463	49	15	8.2	8.2	NUM
eurjchem-2463	49	16	hz	hz	NOUN
eurjchem-2463	49	17	,	,	PUNCT
eurjchem-2463	49	18	2h	2h	NUM
eurjchem-2463	49	19	,	,	PUNCT
eurjchem-2463	49	20	nh	nh	PROPN
eurjchem-2463	49	21	)	)	PUNCT
eurjchem-2463	49	22	.	.	PUNCT
eurjchem-2463	50	1	31p{1h	31p{1h	NUM
eurjchem-2463	50	2	}	}	PUNCT
eurjchem-2463	50	3	nmr	nmr	NOUN
eurjchem-2463	50	4	(	(	PUNCT
eurjchem-2463	50	5	101.2	101.2	NUM
eurjchem-2463	50	6	mhz	mhz	NOUN
eurjchem-2463	50	7	,	,	PUNCT
eurjchem-2463	50	8	cdcl3	cdcl3	PROPN
eurjchem-2463	50	9	,	,	PUNCT
eurjchem-2463	50	10	δ	δ	PROPN
eurjchem-2463	50	11	,	,	PUNCT
eurjchem-2463	50	12	ppm	ppm	NOUN
eurjchem-2463	50	13	):	):	PUNCT
eurjchem-2463	50	14	27.9	27.9	NUM
eurjchem-2463	50	15	.	.	PUNCT
eurjchem-2463	50	16	2.2.2	2.2.2	NUM
eurjchem-2463	50	17	.	.	NUM
eurjchem-2463	50	18	n	n	CCONJ
eurjchem-2463	50	19	,	,	PUNCT
eurjchem-2463	50	20	n’-bis(diisopropylphosphino)-2,6	n’-bis(diisopropylphosphino)-2,6	NOUN
eurjchem-2463	50	21	-	-	NOUN
eurjchem-2463	50	22	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	50	23	,	,	PUNCT
eurjchem-2463	50	24	pnp	pnp	PROPN
eurjchem-2463	50	25	-	-	PUNCT
eurjchem-2463	50	26	ipr	ipr	PROPN
eurjchem-2463	50	27	triethylamine	triethylamine	NOUN
eurjchem-2463	50	28	(	(	PUNCT
eurjchem-2463	50	29	4.71	4.71	NUM
eurjchem-2463	50	30	ml	ml	NOUN
eurjchem-2463	50	31	,	,	PUNCT
eurjchem-2463	50	32	33.78	33.78	NUM
eurjchem-2463	50	33	mmol	mmol	NOUN
eurjchem-2463	50	34	)	)	PUNCT
eurjchem-2463	50	35	was	be	AUX
eurjchem-2463	50	36	added	add	VERB
eurjchem-2463	50	37	to	to	ADP
eurjchem-2463	50	38	a	a	DET
eurjchem-2463	50	39	suspension	suspension	NOUN
eurjchem-2463	50	40	of	of	ADP
eurjchem-2463	50	41	2,6	2,6	NOUN
eurjchem-2463	50	42	-	-	NOUN
eurjchem-2463	50	43	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	50	44	(	(	PUNCT
eurjchem-2463	50	45	1.82	1.82	NUM
eurjchem-2463	50	46	g	g	NOUN
eurjchem-2463	50	47	,	,	PUNCT
eurjchem-2463	50	48	16.68	16.68	NUM
eurjchem-2463	50	49	mmol	mmol	NOUN
eurjchem-2463	50	50	)	)	PUNCT
eurjchem-2463	50	51	in	in	ADP
eurjchem-2463	50	52	toluene	toluene	NOUN
eurjchem-2463	50	53	(	(	PUNCT
eurjchem-2463	50	54	100	100	NUM
eurjchem-2463	50	55	ml	ml	NOUN
eurjchem-2463	50	56	)	)	PUNCT
eurjchem-2463	50	57	.	.	PUNCT
eurjchem-2463	51	1	the	the	DET
eurjchem-2463	51	2	mixture	mixture	NOUN
eurjchem-2463	51	3	was	be	AUX
eurjchem-2463	51	4	cooled	cool	VERB
eurjchem-2463	51	5	to	to	ADP
eurjchem-2463	51	6	0	0	NUM
eurjchem-2463	51	7	°	°	ADP
eurjchem-2463	51	8	c	c	NOUN
eurjchem-2463	51	9	,	,	PUNCT
eurjchem-2463	51	10	and	and	CCONJ
eurjchem-2463	51	11	ipr2pcl	ipr2pcl	NOUN
eurjchem-2463	51	12	(	(	PUNCT
eurjchem-2463	51	13	5.35	5.35	NUM
eurjchem-2463	51	14	ml	ml	NOUN
eurjchem-2463	51	15	,	,	PUNCT
eurjchem-2463	51	16	33.65	33.65	NUM
eurjchem-2463	51	17	mmol	mmol	NOUN
eurjchem-2463	51	18	)	)	PUNCT
eurjchem-2463	51	19	was	be	AUX
eurjchem-2463	51	20	added	add	VERB
eurjchem-2463	51	21	dropwise	dropwise	NOUN
eurjchem-2463	51	22	.	.	PUNCT
eurjchem-2463	52	1	upon	upon	SCONJ
eurjchem-2463	52	2	further	far	ADV
eurjchem-2463	52	3	cooling	cool	VERB
eurjchem-2463	52	4	to	to	ADP
eurjchem-2463	52	5	-70	-70	PROPN
eurjchem-2463	52	6	°	°	PROPN
eurjchem-2463	52	7	c	c	PROPN
eurjchem-2463	52	8	,	,	PUNCT
eurjchem-2463	52	9	a	a	DET
eurjchem-2463	52	10	2.5	2.5	NUM
eurjchem-2463	52	11	m	m	NOUN
eurjchem-2463	52	12	solution	solution	NOUN
eurjchem-2463	52	13	of	of	ADP
eurjchem-2463	52	14	n	n	CCONJ
eurjchem-2463	52	15	-	-	PUNCT
eurjchem-2463	52	16	buli	buli	NOUN
eurjchem-2463	52	17	in	in	ADP
eurjchem-2463	52	18	hexane	hexane	NOUN
eurjchem-2463	52	19	(	(	PUNCT
eurjchem-2463	52	20	13.51	13.51	NUM
eurjchem-2463	52	21	ml	ml	NOUN
eurjchem-2463	52	22	,	,	PUNCT
eurjchem-2463	52	23	33.78	33.78	NUM
eurjchem-2463	52	24	mmol	mmol	NOUN
eurjchem-2463	52	25	)	)	PUNCT
eurjchem-2463	52	26	was	be	AUX
eurjchem-2463	52	27	slowly	slowly	ADV
eurjchem-2463	52	28	added	add	VERB
eurjchem-2463	52	29	.	.	PUNCT
eurjchem-2463	53	1	the	the	DET
eurjchem-2463	53	2	solution	solution	NOUN
eurjchem-2463	53	3	was	be	AUX
eurjchem-2463	53	4	allowed	allow	VERB
eurjchem-2463	53	5	to	to	PART
eurjchem-2463	53	6	reach	reach	VERB
eurjchem-2463	53	7	room	room	NOUN
eurjchem-2463	53	8	temperature	temperature	NOUN
eurjchem-2463	53	9	and	and	CCONJ
eurjchem-2463	53	10	then	then	ADV
eurjchem-2463	53	11	stirred	stir	VERB
eurjchem-2463	53	12	overnight	overnight	ADV
eurjchem-2463	53	13	at	at	ADP
eurjchem-2463	53	14	80	80	NUM
eurjchem-2463	53	15	°	°	NOUN
eurjchem-2463	53	16	c	c	NOUN
eurjchem-2463	53	17	.	.	PUNCT
eurjchem-2463	54	1	the	the	DET
eurjchem-2463	54	2	reaction	reaction	NOUN
eurjchem-2463	54	3	mixture	mixture	NOUN
eurjchem-2463	54	4	was	be	AUX
eurjchem-2463	54	5	filtered	filter	VERB
eurjchem-2463	54	6	,	,	PUNCT
eurjchem-2463	54	7	and	and	CCONJ
eurjchem-2463	54	8	the	the	DET
eurjchem-2463	54	9	solvent	solvent	NOUN
eurjchem-2463	54	10	was	be	AUX
eurjchem-2463	54	11	removed	remove	VERB
eurjchem-2463	54	12	under	under	ADP
eurjchem-2463	54	13	vacuum	vacuum	NOUN
eurjchem-2463	54	14	.	.	PUNCT
eurjchem-2463	55	1	the	the	DET
eurjchem-2463	55	2	remaining	remain	VERB
eurjchem-2463	55	3	oil	oil	NOUN
eurjchem-2463	55	4	was	be	AUX
eurjchem-2463	55	5	recrystallized	recrystallize	VERB
eurjchem-2463	55	6	from	from	ADP
eurjchem-2463	55	7	toluene	toluene	NOUN
eurjchem-2463	55	8	/	/	SYM
eurjchem-2463	55	9	n	n	CCONJ
eurjchem-2463	55	10	-	-	PUNCT
eurjchem-2463	55	11	hexane	hexane	NOUN
eurjchem-2463	55	12	(	(	PUNCT
eurjchem-2463	55	13	1:1	1:1	NUM
eurjchem-2463	55	14	)	)	PUNCT
eurjchem-2463	55	15	.	.	PUNCT
eurjchem-2463	56	1	color	color	NOUN
eurjchem-2463	56	2	:	:	PUNCT
eurjchem-2463	56	3	white	white	ADJ
eurjchem-2463	56	4	.	.	PUNCT
eurjchem-2463	57	1	yield	yield	NOUN
eurjchem-2463	57	2	:	:	PUNCT
eurjchem-2463	57	3	97	97	NUM
eurjchem-2463	57	4	%	%	NOUN
eurjchem-2463	57	5	.	.	PUNCT
eurjchem-2463	58	1	1h	1h	NUM
eurjchem-2463	58	2	nmr	nmr	NOUN
eurjchem-2463	58	3	(	(	PUNCT
eurjchem-2463	58	4	250.0	250.0	NUM
eurjchem-2463	58	5	mhz	mhz	NOUN
eurjchem-2463	58	6	,	,	PUNCT
eurjchem-2463	58	7	cdcl3	cdcl3	PROPN
eurjchem-2463	58	8	,	,	PUNCT
eurjchem-2463	58	9	δ	δ	PROPN
eurjchem-2463	58	10	,	,	PUNCT
eurjchem-2463	58	11	ppm	ppm	NUM
eurjchem-2463	58	12	):	):	PUNCT
eurjchem-2463	58	13	7.20	7.20	NUM
eurjchem-2463	58	14	(	(	PUNCT
eurjchem-2463	58	15	t	t	PROPN
eurjchem-2463	58	16	,	,	PUNCT
eurjchem-2463	58	17	j	j	PROPN
eurjchem-2463	58	18	=	=	SYM
eurjchem-2463	58	19	8.1	8.1	NUM
eurjchem-2463	58	20	hz	hz	NOUN
eurjchem-2463	58	21	,	,	PUNCT
eurjchem-2463	58	22	1h	1h	NUM
eurjchem-2463	58	23	,	,	PUNCT
eurjchem-2463	58	24	py	py	PROPN
eurjchem-2463	58	25	)	)	PUNCT
eurjchem-2463	58	26	,	,	PUNCT
eurjchem-2463	58	27	6.38	6.38	NUM
eurjchem-2463	58	28	(	(	PUNCT
eurjchem-2463	58	29	dd	dd	PROPN
eurjchem-2463	58	30	,	,	PUNCT
eurjchem-2463	58	31	j	j	PROPN
eurjchem-2463	59	1	=	=	SYM
eurjchem-2463	59	2	8.0	8.0	NUM
eurjchem-2463	59	3	hz	hz	VERB
eurjchem-2463	59	4	,	,	PUNCT
eurjchem-2463	59	5	j	j	PROPN
eurjchem-2463	60	1	=	=	NOUN
eurjchem-2463	60	2	2.1	2.1	NUM
eurjchem-2463	60	3	,	,	PUNCT
eurjchem-2463	60	4	2h	2h	NUM
eurjchem-2463	60	5	,	,	PUNCT
eurjchem-2463	60	6	py	py	PROPN
eurjchem-2463	60	7	)	)	PUNCT
eurjchem-2463	60	8	,	,	PUNCT
eurjchem-2463	60	9	4.38	4.38	NUM
eurjchem-2463	60	10	(	(	PUNCT
eurjchem-2463	60	11	d	d	PROPN
eurjchem-2463	60	12	,	,	PUNCT
eurjchem-2463	60	13	j	j	PROPN
eurjchem-2463	60	14	=	=	PROPN
eurjchem-2463	60	15	10.7	10.7	NUM
eurjchem-2463	60	16	hz	hz	NOUN
eurjchem-2463	60	17	,	,	PUNCT
eurjchem-2463	60	18	2h	2h	NUM
eurjchem-2463	60	19	,	,	PUNCT
eurjchem-2463	60	20	nh	nh	PROPN
eurjchem-2463	60	21	)	)	PUNCT
eurjchem-2463	60	22	,	,	PUNCT
eurjchem-2463	60	23	1.69	1.69	NUM
eurjchem-2463	60	24	(	(	PUNCT
eurjchem-2463	60	25	m	m	PROPN
eurjchem-2463	60	26	,	,	PUNCT
eurjchem-2463	60	27	j	j	PROPN
eurjchem-2463	60	28	=	=	SYM
eurjchem-2463	60	29	7.0	7.0	NUM
eurjchem-2463	60	30	,	,	PUNCT
eurjchem-2463	60	31	j	j	PROPN
eurjchem-2463	61	1	=	=	SYM
eurjchem-2463	61	2	1.9	1.9	NUM
eurjchem-2463	61	3	hz	hz	NOUN
eurjchem-2463	61	4	,	,	PUNCT
eurjchem-2463	61	5	4h	4h	NOUN
eurjchem-2463	61	6	,	,	PUNCT
eurjchem-2463	61	7	ch(ch3)2	ch(ch3)2	NOUN
eurjchem-2463	61	8	)	)	PUNCT
eurjchem-2463	61	9	,	,	PUNCT
eurjchem-2463	61	10	1.05	1.05	NUM
eurjchem-2463	61	11	-	-	SYM
eurjchem-2463	61	12	0.93	0.93	NUM
eurjchem-2463	61	13	(	(	PUNCT
eurjchem-2463	61	14	m	m	PROPN
eurjchem-2463	61	15	,	,	PUNCT
eurjchem-2463	61	16	24h	24h	NOUN
eurjchem-2463	61	17	,	,	PUNCT
eurjchem-2463	61	18	ch(ch3)2	ch(ch3)2	NOUN
eurjchem-2463	61	19	)	)	PUNCT
eurjchem-2463	61	20	.	.	PUNCT
eurjchem-2463	62	1	31p{1h	31p{1h	NUM
eurjchem-2463	62	2	}	}	PUNCT
eurjchem-2463	62	3	nmr	nmr	NOUN
eurjchem-2463	62	4	(	(	PUNCT
eurjchem-2463	62	5	101.2	101.2	NUM
eurjchem-2463	62	6	mhz	mhz	NOUN
eurjchem-2463	62	7	,	,	PUNCT
eurjchem-2463	62	8	cdcl3	cdcl3	PROPN
eurjchem-2463	62	9	,	,	PUNCT
eurjchem-2463	62	10	δ	δ	PROPN
eurjchem-2463	62	11	,	,	PUNCT
eurjchem-2463	62	12	ppm	ppm	NOUN
eurjchem-2463	62	13	):	):	PUNCT
eurjchem-2463	62	14	49.2	49.2	NUM
eurjchem-2463	62	15	.	.	PUNCT
eurjchem-2463	62	16	2.2.3	2.2.3	NUM
eurjchem-2463	62	17	.	.	PUNCT
eurjchem-2463	63	1	[	[	X
eurjchem-2463	63	2	(	(	PUNCT
eurjchem-2463	63	3	pnp	pnp	PROPN
eurjchem-2463	63	4	-	-	PUNCT
eurjchem-2463	63	5	ph)ticl3	ph)ticl3	PROPN
eurjchem-2463	63	6	]	]	PUNCT
eurjchem-2463	63	7	,	,	PUNCT
eurjchem-2463	63	8	1	1	NUM
eurjchem-2463	63	9	a	a	DET
eurjchem-2463	63	10	solution	solution	NOUN
eurjchem-2463	63	11	of	of	ADP
eurjchem-2463	63	12	pnp	pnp	NOUN
eurjchem-2463	63	13	-	-	PUNCT
eurjchem-2463	63	14	ph	ph	NOUN
eurjchem-2463	63	15	(	(	PUNCT
eurjchem-2463	63	16	250	250	NUM
eurjchem-2463	63	17	mg	mg	NOUN
eurjchem-2463	63	18	,	,	PUNCT
eurjchem-2463	63	19	0.52	0.52	NUM
eurjchem-2463	63	20	mmol	mmol	NOUN
eurjchem-2463	63	21	)	)	PUNCT
eurjchem-2463	63	22	in	in	ADP
eurjchem-2463	63	23	thf	thf	NOUN
eurjchem-2463	63	24	was	be	AUX
eurjchem-2463	63	25	added	add	VERB
eurjchem-2463	63	26	to	to	ADP
eurjchem-2463	63	27	a	a	DET
eurjchem-2463	63	28	suspension	suspension	NOUN
eurjchem-2463	63	29	of	of	ADP
eurjchem-2463	63	30	ticl3·(thf)3	ticl3·(thf)3	NOUN
eurjchem-2463	63	31	(	(	PUNCT
eurjchem-2463	63	32	175	175	NUM
eurjchem-2463	63	33	mg	mg	PROPN
eurjchem-2463	63	34	,	,	PUNCT
eurjchem-2463	63	35	0.47	0.47	NUM
eurjchem-2463	63	36	mmol	mmol	NOUN
eurjchem-2463	63	37	)	)	PUNCT
eurjchem-2463	63	38	in	in	ADP
eurjchem-2463	63	39	the	the	DET
eurjchem-2463	63	40	same	same	ADJ
eurjchem-2463	63	41	solvent	solvent	NOUN
eurjchem-2463	63	42	,	,	PUNCT
eurjchem-2463	63	43	and	and	CCONJ
eurjchem-2463	63	44	the	the	DET
eurjchem-2463	63	45	reaction	reaction	NOUN
eurjchem-2463	63	46	mixture	mixture	NOUN
eurjchem-2463	63	47	was	be	AUX
eurjchem-2463	63	48	refluxed	refluxe	VERB
eurjchem-2463	63	49	overnight	overnight	ADV
eurjchem-2463	63	50	.	.	PUNCT
eurjchem-2463	64	1	the	the	DET
eurjchem-2463	64	2	solvent	solvent	NOUN
eurjchem-2463	64	3	was	be	AUX
eurjchem-2463	64	4	evaporated	evaporate	VERB
eurjchem-2463	64	5	,	,	PUNCT
eurjchem-2463	64	6	and	and	CCONJ
eurjchem-2463	64	7	the	the	DET
eurjchem-2463	64	8	brown	brown	ADJ
eurjchem-2463	64	9	solid	solid	NOUN
eurjchem-2463	64	10	obtained	obtain	VERB
eurjchem-2463	64	11	was	be	AUX
eurjchem-2463	64	12	washed	wash	VERB
eurjchem-2463	64	13	with	with	ADP
eurjchem-2463	64	14	small	small	ADJ
eurjchem-2463	64	15	portions	portion	NOUN
eurjchem-2463	64	16	of	of	ADP
eurjchem-2463	64	17	toluene	toluene	NOUN
eurjchem-2463	64	18	and	and	CCONJ
eurjchem-2463	64	19	dried	dry	VERB
eurjchem-2463	64	20	in	in	ADP
eurjchem-2463	64	21	vacuum	vacuum	NOUN
eurjchem-2463	64	22	.	.	PUNCT
eurjchem-2463	65	1	crystals	crystal	NOUN
eurjchem-2463	65	2	suitable	suitable	ADJ
eurjchem-2463	65	3	for	for	ADP
eurjchem-2463	65	4	single	single	ADJ
eurjchem-2463	65	5	crystal	crystal	NOUN
eurjchem-2463	65	6	x	x	PROPN
eurjchem-2463	65	7	-	-	NOUN
eurjchem-2463	65	8	ray	ray	NOUN
eurjchem-2463	65	9	diffraction	diffraction	NOUN
eurjchem-2463	65	10	were	be	AUX
eurjchem-2463	65	11	obtained	obtain	VERB
eurjchem-2463	65	12	by	by	ADP
eurjchem-2463	65	13	slow	slow	ADJ
eurjchem-2463	65	14	concentration	concentration	NOUN
eurjchem-2463	65	15	of	of	ADP
eurjchem-2463	65	16	a	a	DET
eurjchem-2463	65	17	thf	thf	NOUN
eurjchem-2463	65	18	solution	solution	NOUN
eurjchem-2463	65	19	at	at	ADP
eurjchem-2463	65	20	room	room	NOUN
eurjchem-2463	65	21	temperature	temperature	NOUN
eurjchem-2463	65	22	using	use	VERB
eurjchem-2463	65	23	a	a	DET
eurjchem-2463	65	24	h	h	NOUN
eurjchem-2463	65	25	-	-	PUNCT
eurjchem-2463	65	26	shape	shape	NOUN
eurjchem-2463	65	27	glass	glass	NOUN
eurjchem-2463	65	28	tube	tube	NOUN
eurjchem-2463	65	29	containing	contain	VERB
eurjchem-2463	65	30	the	the	DET
eurjchem-2463	65	31	solution	solution	NOUN
eurjchem-2463	65	32	of	of	ADP
eurjchem-2463	65	33	the	the	DET
eurjchem-2463	65	34	compound	compound	NOUN
eurjchem-2463	65	35	and	and	CCONJ
eurjchem-2463	65	36	a	a	DET
eurjchem-2463	65	37	small	small	ADJ
eurjchem-2463	65	38	volume	volume	NOUN
eurjchem-2463	65	39	of	of	ADP
eurjchem-2463	65	40	toluene	toluene	NOUN
eurjchem-2463	65	41	in	in	ADP
eurjchem-2463	65	42	each	each	DET
eurjchem-2463	65	43	side	side	NOUN
eurjchem-2463	65	44	of	of	ADP
eurjchem-2463	65	45	the	the	DET
eurjchem-2463	65	46	tube	tube	NOUN
eurjchem-2463	65	47	.	.	PUNCT
eurjchem-2463	66	1	color	color	NOUN
eurjchem-2463	66	2	:	:	PUNCT
eurjchem-2463	66	3	brown	brown	ADJ
eurjchem-2463	66	4	.	.	PUNCT
eurjchem-2463	67	1	yield	yield	NOUN
eurjchem-2463	67	2	:	:	PUNCT
eurjchem-2463	67	3	55	55	NUM
eurjchem-2463	67	4	%	%	NOUN
eurjchem-2463	67	5	.	.	PUNCT
eurjchem-2463	68	1	anal	anal	ADJ
eurjchem-2463	68	2	.	.	PUNCT
eurjchem-2463	68	3	calcd	calcd	NOUN
eurjchem-2463	68	4	for	for	ADP
eurjchem-2463	68	5	c29h25cl3n3p2ti·(c4h8o)2·(h2o)2	c29h25cl3n3p2ti·(c4h8o)2·(h2o)2	NOUN
eurjchem-2463	68	6	:	:	PUNCT
eurjchem-2463	68	7	c	c	NOUN
eurjchem-2463	68	8	,	,	PUNCT
eurjchem-2463	68	9	54.73	54.73	NUM
eurjchem-2463	68	10	;	;	PUNCT
eurjchem-2463	68	11	h	h	NOUN
eurjchem-2463	68	12	,	,	PUNCT
eurjchem-2463	68	13	5.59	5.59	NUM
eurjchem-2463	68	14	;	;	PUNCT
eurjchem-2463	68	15	n	n	CCONJ
eurjchem-2463	68	16	,	,	PUNCT
eurjchem-2463	68	17	5.18	5.18	NUM
eurjchem-2463	68	18	.	.	PUNCT
eurjchem-2463	68	19	found	find	VERB
eurjchem-2463	68	20	:	:	PUNCT
eurjchem-2463	69	1	c	c	X
eurjchem-2463	69	2	,	,	PUNCT
eurjchem-2463	69	3	54.04	54.04	NUM
eurjchem-2463	69	4	;	;	PUNCT
eurjchem-2463	69	5	h	h	X
eurjchem-2463	69	6	,	,	PUNCT
eurjchem-2463	69	7	4.75	4.75	NUM
eurjchem-2463	69	8	;	;	PUNCT
eurjchem-2463	69	9	n	n	CCONJ
eurjchem-2463	69	10	,	,	PUNCT
eurjchem-2463	69	11	4.90	4.90	NUM
eurjchem-2463	69	12	%	%	NOUN
eurjchem-2463	69	13	.	.	PUNCT
eurjchem-2463	70	1	2.2.4	2.2.4	NUM
eurjchem-2463	70	2	.	.	PUNCT
eurjchem-2463	71	1	[	[	X
eurjchem-2463	71	2	(	(	PUNCT
eurjchem-2463	71	3	pnp	pnp	PROPN
eurjchem-2463	71	4	-	-	PUNCT
eurjchem-2463	71	5	ipr)mocl3	ipr)mocl3	PROPN
eurjchem-2463	71	6	]	]	PUNCT
eurjchem-2463	71	7	,	,	PUNCT
eurjchem-2463	71	8	2	2	NUM
eurjchem-2463	71	9	a	a	DET
eurjchem-2463	71	10	solution	solution	NOUN
eurjchem-2463	71	11	of	of	ADP
eurjchem-2463	71	12	pnp	pnp	PROPN
eurjchem-2463	71	13	-	-	PUNCT
eurjchem-2463	71	14	ipr	ipr	PROPN
eurjchem-2463	71	15	(	(	PUNCT
eurjchem-2463	71	16	341	341	NUM
eurjchem-2463	71	17	mg	mg	NOUN
eurjchem-2463	71	18	,	,	PUNCT
eurjchem-2463	71	19	1.00	1.00	NUM
eurjchem-2463	71	20	mmol	mmol	NOUN
eurjchem-2463	71	21	)	)	PUNCT
eurjchem-2463	71	22	in	in	ADP
eurjchem-2463	71	23	toluene	toluene	NOUN
eurjchem-2463	71	24	was	be	AUX
eurjchem-2463	71	25	added	add	VERB
eurjchem-2463	71	26	to	to	ADP
eurjchem-2463	71	27	a	a	DET
eurjchem-2463	71	28	suspension	suspension	NOUN
eurjchem-2463	71	29	of	of	ADP
eurjchem-2463	71	30	mocl3·(thf)3	mocl3·(thf)3	NOUN
eurjchem-2463	71	31	(	(	PUNCT
eurjchem-2463	71	32	374	374	NUM
eurjchem-2463	71	33	mg	mg	NOUN
eurjchem-2463	71	34	,	,	PUNCT
eurjchem-2463	71	35	0.90	0.90	NUM
eurjchem-2463	71	36	mmol	mmol	NOUN
eurjchem-2463	71	37	)	)	PUNCT
eurjchem-2463	71	38	in	in	ADP
eurjchem-2463	71	39	the	the	DET
eurjchem-2463	71	40	same	same	ADJ
eurjchem-2463	71	41	solvent	solvent	NOUN
eurjchem-2463	71	42	.	.	PUNCT
eurjchem-2463	72	1	the	the	DET
eurjchem-2463	72	2	reaction	reaction	NOUN
eurjchem-2463	72	3	mixture	mixture	NOUN
eurjchem-2463	72	4	was	be	AUX
eurjchem-2463	72	5	refluxed	refluxe	VERB
eurjchem-2463	72	6	overnight	overnight	ADV
eurjchem-2463	72	7	,	,	PUNCT
eurjchem-2463	72	8	providing	provide	VERB
eurjchem-2463	72	9	a	a	DET
eurjchem-2463	72	10	green	green	ADJ
eurjchem-2463	72	11	precipitate	precipitate	NOUN
eurjchem-2463	72	12	.	.	PUNCT
eurjchem-2463	73	1	the	the	DET
eurjchem-2463	73	2	solid	solid	ADJ
eurjchem-2463	73	3	was	be	AUX
eurjchem-2463	73	4	filtered	filter	VERB
eurjchem-2463	73	5	off	off	ADP
eurjchem-2463	73	6	,	,	PUNCT
eurjchem-2463	73	7	washed	wash	VERB
eurjchem-2463	73	8	with	with	ADP
eurjchem-2463	73	9	small	small	ADJ
eurjchem-2463	73	10	portions	portion	NOUN
eurjchem-2463	73	11	of	of	ADP
eurjchem-2463	73	12	et2o	et2o	PROPN
eurjchem-2463	73	13	,	,	PUNCT
eurjchem-2463	73	14	and	and	CCONJ
eurjchem-2463	73	15	dried	dry	VERB
eurjchem-2463	73	16	under	under	ADP
eurjchem-2463	73	17	vacuum	vacuum	NOUN
eurjchem-2463	73	18	.	.	PUNCT
eurjchem-2463	74	1	crystals	crystal	NOUN
eurjchem-2463	74	2	suitable	suitable	ADJ
eurjchem-2463	74	3	for	for	ADP
eurjchem-2463	74	4	single	single	ADJ
eurjchem-2463	74	5	-	-	PUNCT
eurjchem-2463	74	6	crystal	crystal	NOUN
eurjchem-2463	74	7	x	x	ADJ
eurjchem-2463	74	8	-	-	NOUN
eurjchem-2463	74	9	ray	ray	NOUN
eurjchem-2463	74	10	diffraction	diffraction	NOUN
eurjchem-2463	74	11	were	be	AUX
eurjchem-2463	74	12	obtained	obtain	VERB
eurjchem-2463	74	13	by	by	ADP
eurjchem-2463	74	14	slow	slow	ADJ
eurjchem-2463	74	15	concentration	concentration	NOUN
eurjchem-2463	74	16	of	of	ADP
eurjchem-2463	74	17	a	a	DET
eurjchem-2463	74	18	ch2cl2	ch2cl2	NOUN
eurjchem-2463	74	19	solution	solution	NOUN
eurjchem-2463	74	20	at	at	ADP
eurjchem-2463	74	21	room	room	NOUN
eurjchem-2463	74	22	temperature	temperature	NOUN
eurjchem-2463	74	23	using	use	VERB
eurjchem-2463	74	24	a	a	DET
eurjchem-2463	74	25	h	h	NOUN
eurjchem-2463	74	26	-	-	PUNCT
eurjchem-2463	74	27	shape	shape	NOUN
eurjchem-2463	74	28	glass	glass	NOUN
eurjchem-2463	74	29	tube	tube	NOUN
eurjchem-2463	74	30	containing	contain	VERB
eurjchem-2463	74	31	the	the	DET
eurjchem-2463	74	32	solution	solution	NOUN
eurjchem-2463	74	33	of	of	ADP
eurjchem-2463	74	34	the	the	DET
eurjchem-2463	74	35	compound	compound	NOUN
eurjchem-2463	74	36	and	and	CCONJ
eurjchem-2463	74	37	a	a	DET
eurjchem-2463	74	38	small	small	ADJ
eurjchem-2463	74	39	volume	volume	NOUN
eurjchem-2463	74	40	of	of	ADP
eurjchem-2463	74	41	toluene	toluene	NOUN
eurjchem-2463	74	42	in	in	ADP
eurjchem-2463	74	43	each	each	DET
eurjchem-2463	74	44	side	side	NOUN
eurjchem-2463	74	45	of	of	ADP
eurjchem-2463	74	46	the	the	DET
eurjchem-2463	74	47	tube	tube	NOUN
eurjchem-2463	74	48	.	.	PUNCT
eurjchem-2463	75	1	color	color	NOUN
eurjchem-2463	75	2	:	:	PUNCT
eurjchem-2463	75	3	green	green	ADJ
eurjchem-2463	75	4	.	.	PUNCT
eurjchem-2463	76	1	yield	yield	NOUN
eurjchem-2463	76	2	:	:	PUNCT
eurjchem-2463	76	3	64	64	NUM
eurjchem-2463	76	4	%	%	NOUN
eurjchem-2463	76	5	.	.	PUNCT
eurjchem-2463	77	1	anal	anal	ADJ
eurjchem-2463	77	2	.	.	PUNCT
eurjchem-2463	77	3	calcd	calcd	NOUN
eurjchem-2463	77	4	for	for	ADP
eurjchem-2463	77	5	c17h33cl3	c17h33cl3	PROPN
eurjchem-2463	77	6	mon3p2·(ch2cl2)0.3	mon3p2·(ch2cl2)0.3	PROPN
eurjchem-2463	77	7	:	:	PUNCT
eurjchem-2463	77	8	c	c	X
eurjchem-2463	77	9	,	,	PUNCT
eurjchem-2463	77	10	36.51	36.51	NUM
eurjchem-2463	77	11	;	;	PUNCT
eurjchem-2463	77	12	h	h	NOUN
eurjchem-2463	77	13	,	,	PUNCT
eurjchem-2463	77	14	5.95	5.95	NUM
eurjchem-2463	77	15	;	;	PUNCT
eurjchem-2463	77	16	n	n	CCONJ
eurjchem-2463	77	17	,	,	PUNCT
eurjchem-2463	77	18	7.38	7.38	NUM
eurjchem-2463	77	19	.	.	PUNCT
eurjchem-2463	77	20	found	find	VERB
eurjchem-2463	77	21	:	:	PUNCT
eurjchem-2463	78	1	c	c	X
eurjchem-2463	78	2	,	,	PUNCT
eurjchem-2463	78	3	36.38	36.38	NUM
eurjchem-2463	78	4	;	;	PUNCT
eurjchem-2463	79	1	h	h	NOUN
eurjchem-2463	79	2	,	,	PUNCT
eurjchem-2463	79	3	6.28	6.28	NUM
eurjchem-2463	79	4	;	;	PUNCT
eurjchem-2463	79	5	n	n	CCONJ
eurjchem-2463	79	6	,	,	PUNCT
eurjchem-2463	79	7	7.36	7.36	NUM
eurjchem-2463	79	8	%	%	NOUN
eurjchem-2463	79	9	.	.	PUNCT
eurjchem-2463	80	1	2.3	2.3	NUM
eurjchem-2463	80	2	.	.	PUNCT
eurjchem-2463	80	3	general	general	ADJ
eurjchem-2463	80	4	procedure	procedure	NOUN
eurjchem-2463	80	5	for	for	ADP
eurjchem-2463	80	6	x	x	NOUN
eurjchem-2463	80	7	-	-	NOUN
eurjchem-2463	80	8	ray	ray	NOUN
eurjchem-2463	80	9	crystallography	crystallography	NOUN
eurjchem-2463	80	10	suitable	suitable	ADJ
eurjchem-2463	80	11	crystals	crystal	NOUN
eurjchem-2463	80	12	of	of	ADP
eurjchem-2463	80	13	compounds	compound	NOUN
eurjchem-2463	80	14	1	1	NUM
eurjchem-2463	80	15	and	and	CCONJ
eurjchem-2463	80	16	2	2	NUM
eurjchem-2463	80	17	were	be	AUX
eurjchem-2463	80	18	coated	coat	VERB
eurjchem-2463	80	19	and	and	CCONJ
eurjchem-2463	80	20	selected	select	VERB
eurjchem-2463	80	21	in	in	ADP
eurjchem-2463	80	22	fomblin	fomblin	PROPN
eurjchem-2463	80	23	®	®	NOUN
eurjchem-2463	80	24	oil	oil	NOUN
eurjchem-2463	80	25	in	in	ADP
eurjchem-2463	80	26	an	an	DET
eurjchem-2463	80	27	inert	inert	ADJ
eurjchem-2463	80	28	atmosphere	atmosphere	NOUN
eurjchem-2463	80	29	of	of	ADP
eurjchem-2463	80	30	nitrogen	nitrogen	NOUN
eurjchem-2463	80	31	.	.	PUNCT
eurjchem-2463	81	1	the	the	DET
eurjchem-2463	81	2	crystals	crystal	NOUN
eurjchem-2463	81	3	were	be	AUX
eurjchem-2463	81	4	then	then	ADV
eurjchem-2463	81	5	mounted	mount	VERB
eurjchem-2463	81	6	on	on	ADP
eurjchem-2463	81	7	a	a	DET
eurjchem-2463	81	8	loop	loop	NOUN
eurjchem-2463	81	9	external	external	ADJ
eurjchem-2463	81	10	to	to	ADP
eurjchem-2463	81	11	the	the	DET
eurjchem-2463	81	12	glovebox	glovebox	NOUN
eurjchem-2463	81	13	environment	environment	NOUN
eurjchem-2463	81	14	and	and	CCONJ
eurjchem-2463	81	15	data	datum	NOUN
eurjchem-2463	81	16	was	be	AUX
eurjchem-2463	81	17	collected	collect	VERB
eurjchem-2463	81	18	using	use	VERB
eurjchem-2463	81	19	graphite	graphite	NOUN
eurjchem-2463	81	20	monochromated	monochromate	VERB
eurjchem-2463	81	21	mo	mo	PROPN
eurjchem-2463	81	22	-	-	ADJ
eurjchem-2463	81	23	kα	kα	PROPN
eurjchem-2463	81	24	radiation	radiation	NOUN
eurjchem-2463	81	25	(	(	PUNCT
eurjchem-2463	81	26	λ	λ	X
eurjchem-2463	81	27	=	=	SYM
eurjchem-2463	81	28	0.71073	0.71073	NUM
eurjchem-2463	81	29	å	å	NOUN
eurjchem-2463	81	30	)	)	PUNCT
eurjchem-2463	81	31	on	on	ADP
eurjchem-2463	81	32	a	a	DET
eurjchem-2463	81	33	bruker	bruker	PROPN
eurjchem-2463	81	34	axs	axs	PROPN
eurjchem-2463	81	35	-	-	PUNCT
eurjchem-2463	81	36	kappa	kappa	PROPN
eurjchem-2463	81	37	apex	apex	PROPN
eurjchem-2463	81	38	ii	ii	PROPN
eurjchem-2463	81	39	diffractometer	diffractometer	PROPN
eurjchem-2463	81	40	.	.	PUNCT
eurjchem-2463	82	1	cell	cell	NOUN
eurjchem-2463	82	2	parameters	parameter	NOUN
eurjchem-2463	82	3	were	be	AUX
eurjchem-2463	82	4	retrieved	retrieve	VERB
eurjchem-2463	82	5	using	use	VERB
eurjchem-2463	82	6	bruker	bruker	ADJ
eurjchem-2463	82	7	smart	smart	ADJ
eurjchem-2463	82	8	software	software	NOUN
eurjchem-2463	82	9	and	and	CCONJ
eurjchem-2463	82	10	refined	refined	ADJ
eurjchem-2463	82	11	using	use	VERB
eurjchem-2463	82	12	bruker	bruker	PROPN
eurjchem-2463	82	13	saint	saint	NOUN
eurjchem-2463	82	14	on	on	ADP
eurjchem-2463	82	15	all	all	DET
eurjchem-2463	82	16	observed	observe	VERB
eurjchem-2463	82	17	reflections	reflection	NOUN
eurjchem-2463	82	18	[	[	X
eurjchem-2463	82	19	30	30	NUM
eurjchem-2463	82	20	]	]	PUNCT
eurjchem-2463	82	21	.	.	PUNCT
eurjchem-2463	83	1	absorption	absorption	NOUN
eurjchem-2463	83	2	corrections	correction	NOUN
eurjchem-2463	83	3	were	be	AUX
eurjchem-2463	83	4	applied	apply	VERB
eurjchem-2463	83	5	using	use	VERB
eurjchem-2463	83	6	sadabs	sadab	NOUN
eurjchem-2463	84	1	[	[	X
eurjchem-2463	84	2	31	31	NUM
eurjchem-2463	84	3	]	]	PUNCT
eurjchem-2463	84	4	.	.	PUNCT
eurjchem-2463	85	1	the	the	DET
eurjchem-2463	85	2	structures	structure	NOUN
eurjchem-2463	85	3	were	be	AUX
eurjchem-2463	85	4	solved	solve	VERB
eurjchem-2463	85	5	by	by	ADP
eurjchem-2463	85	6	direct	direct	ADJ
eurjchem-2463	85	7	methods	method	NOUN
eurjchem-2463	85	8	using	use	VERB
eurjchem-2463	85	9	sir97	sir97	PROPN
eurjchem-2463	85	10	[	[	X
eurjchem-2463	85	11	32	32	NUM
eurjchem-2463	85	12	]	]	PUNCT
eurjchem-2463	85	13	.	.	PUNCT
eurjchem-2463	86	1	structure	structure	NOUN
eurjchem-2463	86	2	refinement	refinement	NOUN
eurjchem-2463	86	3	was	be	AUX
eurjchem-2463	86	4	done	do	VERB
eurjchem-2463	86	5	using	use	VERB
eurjchem-2463	86	6	shelxl-2018/3	shelxl-2018/3	PROPN
eurjchem-2463	86	7	[	[	PUNCT
eurjchem-2463	86	8	33	33	NUM
eurjchem-2463	86	9	]	]	PUNCT
eurjchem-2463	86	10	.	.	PUNCT
eurjchem-2463	87	1	these	these	DET
eurjchem-2463	87	2	programs	program	NOUN
eurjchem-2463	87	3	are	be	AUX
eurjchem-2463	87	4	part	part	NOUN
eurjchem-2463	87	5	of	of	ADP
eurjchem-2463	87	6	the	the	DET
eurjchem-2463	87	7	wingx	wingx	PROPN
eurjchem-2463	87	8	software	software	NOUN
eurjchem-2463	87	9	package	package	NOUN
eurjchem-2463	87	10	version	version	NOUN
eurjchem-2463	87	11	2021.3	2021.3	NUM
eurjchem-2463	87	12	[	[	X
eurjchem-2463	87	13	34	34	NUM
eurjchem-2463	87	14	]	]	PUNCT
eurjchem-2463	87	15	.	.	PUNCT
eurjchem-2463	88	1	hydrogen	hydrogen	NOUN
eurjchem-2463	88	2	atoms	atom	NOUN
eurjchem-2463	88	3	bonded	bond	VERB
eurjchem-2463	88	4	to	to	ADP
eurjchem-2463	88	5	nitrogen	nitrogen	PROPN
eurjchem-2463	88	6	were	be	AUX
eurjchem-2463	88	7	located	locate	VERB
eurjchem-2463	88	8	on	on	ADP
eurjchem-2463	88	9	the	the	DET
eurjchem-2463	88	10	difference	difference	NOUN
eurjchem-2463	88	11	map	map	NOUN
eurjchem-2463	88	12	and	and	CCONJ
eurjchem-2463	88	13	refined	refine	VERB
eurjchem-2463	88	14	freely	freely	ADV
eurjchem-2463	88	15	.	.	PUNCT
eurjchem-2463	89	1	hydrogen	hydrogen	NOUN
eurjchem-2463	89	2	atoms	atom	NOUN
eurjchem-2463	89	3	bonded	bond	VERB
eurjchem-2463	89	4	to	to	ADP
eurjchem-2463	89	5	carbons	carbon	NOUN
eurjchem-2463	89	6	were	be	AUX
eurjchem-2463	89	7	inserted	insert	VERB
eurjchem-2463	89	8	in	in	ADP
eurjchem-2463	89	9	the	the	DET
eurjchem-2463	89	10	calculated	calculate	VERB
eurjchem-2463	89	11	positions	position	NOUN
eurjchem-2463	89	12	and	and	CCONJ
eurjchem-2463	89	13	allowed	allow	VERB
eurjchem-2463	89	14	to	to	PART
eurjchem-2463	89	15	refine	refine	VERB
eurjchem-2463	89	16	riding	ride	VERB
eurjchem-2463	89	17	in	in	ADP
eurjchem-2463	89	18	the	the	DET
eurjchem-2463	89	19	parent	parent	NOUN
eurjchem-2463	89	20	atom	atom	NOUN
eurjchem-2463	89	21	.	.	PUNCT
eurjchem-2463	90	1	compound	compound	NOUN
eurjchem-2463	90	2	2	2	NUM
eurjchem-2463	90	3	crystalized	crystalize	VERB
eurjchem-2463	90	4	with	with	ADP
eurjchem-2463	90	5	diffuse	diffuse	NOUN
eurjchem-2463	90	6	and	and	CCONJ
eurjchem-2463	90	7	disordered	disordered	ADJ
eurjchem-2463	90	8	solvent	solvent	ADJ
eurjchem-2463	90	9	molecules	molecule	NOUN
eurjchem-2463	90	10	that	that	PRON
eurjchem-2463	90	11	could	could	AUX
eurjchem-2463	90	12	not	not	PART
eurjchem-2463	90	13	be	be	AUX
eurjchem-2463	90	14	modeled	model	VERB
eurjchem-2463	90	15	.	.	PUNCT
eurjchem-2463	91	1	therefore	therefore	ADV
eurjchem-2463	91	2	,	,	PUNCT
eurjchem-2463	91	3	they	they	PRON
eurjchem-2463	91	4	were	be	AUX
eurjchem-2463	91	5	removed	remove	VERB
eurjchem-2463	91	6	using	use	VERB
eurjchem-2463	91	7	the	the	DET
eurjchem-2463	91	8	squeeze	squeeze	NOUN
eurjchem-2463	91	9	/	/	SYM
eurjchem-2463	91	10	platon	platon	NOUN
eurjchem-2463	91	11	sequence	sequence	NOUN
eurjchem-2463	91	12	[	[	X
eurjchem-2463	91	13	35	35	NUM
eurjchem-2463	91	14	]	]	PUNCT
eurjchem-2463	91	15	.	.	PUNCT
eurjchem-2463	92	1	a	a	DET
eurjchem-2463	92	2	total	total	ADJ
eurjchem-2463	92	3	void	void	NOUN
eurjchem-2463	92	4	of	of	ADP
eurjchem-2463	92	5	3774	3774	NUM
eurjchem-2463	92	6	å3	å3	PROPN
eurjchem-2463	92	7	containing	contain	VERB
eurjchem-2463	92	8	1516	1516	NUM
eurjchem-2463	92	9	electrons	electron	NOUN
eurjchem-2463	92	10	per	per	ADP
eurjchem-2463	92	11	unit	unit	NOUN
eurjchem-2463	92	12	cell	cell	NOUN
eurjchem-2463	92	13	was	be	AUX
eurjchem-2463	92	14	found	find	VERB
eurjchem-2463	92	15	and	and	CCONJ
eurjchem-2463	92	16	fits	fit	VERB
eurjchem-2463	92	17	well	well	ADV
eurjchem-2463	92	18	for	for	ADP
eurjchem-2463	92	19	two	two	NUM
eurjchem-2463	92	20	molecules	molecule	NOUN
eurjchem-2463	92	21	of	of	ADP
eurjchem-2463	92	22	dichloromethane	dichloromethane	NOUN
eurjchem-2463	92	23	(	(	PUNCT
eurjchem-2463	92	24	42	42	NUM
eurjchem-2463	92	25	electrons	electron	NOUN
eurjchem-2463	92	26	)	)	PUNCT
eurjchem-2463	92	27	in	in	ADP
eurjchem-2463	92	28	the	the	DET
eurjchem-2463	92	29	asymmetric	asymmetric	ADJ
eurjchem-2463	92	30	unit	unit	NOUN
eurjchem-2463	92	31	.	.	PUNCT
eurjchem-2463	93	1	the	the	DET
eurjchem-2463	93	2	poor	poor	ADJ
eurjchem-2463	93	3	diffracting	diffract	VERB
eurjchem-2463	93	4	power	power	NOUN
eurjchem-2463	93	5	and	and	CCONJ
eurjchem-2463	93	6	crystal	crystal	NOUN
eurjchem-2463	93	7	quality	quality	NOUN
eurjchem-2463	93	8	of	of	ADP
eurjchem-2463	93	9	2	2	NUM
eurjchem-2463	93	10	(	(	PUNCT
eurjchem-2463	93	11	as	as	SCONJ
eurjchem-2463	93	12	attested	attest	VERB
eurjchem-2463	93	13	by	by	ADP
eurjchem-2463	93	14	the	the	DET
eurjchem-2463	93	15	rint	rint	NOUN
eurjchem-2463	93	16	value	value	NOUN
eurjchem-2463	93	17	obtained	obtain	VERB
eurjchem-2463	93	18	)	)	PUNCT
eurjchem-2463	93	19	precluded	preclude	VERB
eurjchem-2463	93	20	the	the	DET
eurjchem-2463	93	21	final	final	ADJ
eurjchem-2463	93	22	refinement	refinement	NOUN
eurjchem-2463	93	23	to	to	PART
eurjchem-2463	93	24	lower	lower	VERB
eurjchem-2463	93	25	the	the	DET
eurjchem-2463	93	26	corresponding	correspond	VERB
eurjchem-2463	93	27	r	r	NOUN
eurjchem-2463	93	28	values	value	NOUN
eurjchem-2463	93	29	.	.	PUNCT
eurjchem-2463	94	1	crystallographic	crystallographic	ADJ
eurjchem-2463	94	2	and	and	CCONJ
eurjchem-2463	94	3	experimental	experimental	ADJ
eurjchem-2463	94	4	details	detail	NOUN
eurjchem-2463	94	5	of	of	ADP
eurjchem-2463	94	6	data	datum	NOUN
eurjchem-2463	94	7	collection	collection	NOUN
eurjchem-2463	94	8	and	and	CCONJ
eurjchem-2463	94	9	crystal	crystal	NOUN
eurjchem-2463	94	10	structure	structure	NOUN
eurjchem-2463	94	11	determinations	determination	NOUN
eurjchem-2463	94	12	for	for	ADP
eurjchem-2463	94	13	compounds	compound	NOUN
eurjchem-2463	94	14	1	1	NUM
eurjchem-2463	94	15	and	and	CCONJ
eurjchem-2463	94	16	2	2	NUM
eurjchem-2463	94	17	are	be	AUX
eurjchem-2463	94	18	available	available	ADJ
eurjchem-2463	94	19	in	in	ADP
eurjchem-2463	94	20	table	table	NOUN
eurjchem-2463	94	21	1	1	NUM
eurjchem-2463	94	22	.	.	PUNCT
eurjchem-2463	95	1	illustrations	illustration	NOUN
eurjchem-2463	95	2	of	of	ADP
eurjchem-2463	95	3	molecular	molecular	ADJ
eurjchem-2463	95	4	structures	structure	NOUN
eurjchem-2463	95	5	were	be	AUX
eurjchem-2463	95	6	made	make	VERB
eurjchem-2463	95	7	with	with	ADP
eurjchem-2463	95	8	ortep-3	ortep-3	NUM
eurjchem-2463	95	9	for	for	ADP
eurjchem-2463	95	10	windows	window	NOUN
eurjchem-2463	95	11	[	[	X
eurjchem-2463	95	12	36	36	NUM
eurjchem-2463	95	13	]	]	PUNCT
eurjchem-2463	95	14	.	.	PUNCT
eurjchem-2463	96	1	3	3	X
eurjchem-2463	96	2	.	.	NOUN
eurjchem-2463	96	3	results	result	NOUN
eurjchem-2463	96	4	and	and	CCONJ
eurjchem-2463	96	5	discussion	discussion	NOUN
eurjchem-2463	96	6	treatment	treatment	NOUN
eurjchem-2463	96	7	of	of	ADP
eurjchem-2463	96	8	mcl3·(thf)3	mcl3·(thf)3	PROPN
eurjchem-2463	96	9	(	(	PUNCT
eurjchem-2463	96	10	m	m	NOUN
eurjchem-2463	96	11	=	=	ADJ
eurjchem-2463	96	12	ti	ti	NOUN
eurjchem-2463	96	13	and	and	CCONJ
eurjchem-2463	96	14	mo	mo	NOUN
eurjchem-2463	96	15	)	)	PUNCT
eurjchem-2463	96	16	with	with	ADP
eurjchem-2463	96	17	the	the	DET
eurjchem-2463	96	18	suitable	suitable	ADJ
eurjchem-2463	96	19	pnp	pnp	PROPN
eurjchem-2463	96	20	ligand	ligand	PROPN
eurjchem-2463	96	21	afforded	afford	VERB
eurjchem-2463	96	22	complexes	complex	NOUN
eurjchem-2463	96	23	[	[	X
eurjchem-2463	96	24	(	(	PUNCT
eurjchem-2463	96	25	pnp	pnp	PROPN
eurjchem-2463	96	26	-	-	PUNCT
eurjchem-2463	96	27	ph)ticl3	ph)ticl3	PROPN
eurjchem-2463	96	28	]	]	PUNCT
eurjchem-2463	96	29	,	,	PUNCT
eurjchem-2463	96	30	1	1	NUM
eurjchem-2463	96	31	,	,	PUNCT
eurjchem-2463	96	32	and	and	CCONJ
eurjchem-2463	96	33	[	[	X
eurjchem-2463	96	34	(	(	PUNCT
eurjchem-2463	96	35	pnpipr)mocl3	pnpipr)mocl3	X
eurjchem-2463	96	36	]	]	X
eurjchem-2463	96	37	,	,	PUNCT
eurjchem-2463	96	38	2	2	NUM
eurjchem-2463	96	39	,	,	PUNCT
eurjchem-2463	96	40	where	where	SCONJ
eurjchem-2463	96	41	pnp	pnp	NOUN
eurjchem-2463	96	42	-	-	PUNCT
eurjchem-2463	96	43	ph	ph	NOUN
eurjchem-2463	96	44	=	=	PUNCT
eurjchem-2463	96	45	n	n	CCONJ
eurjchem-2463	96	46	,	,	PUNCT
eurjchem-2463	96	47	n’-bis(diphenylphosphino)2,6	n’-bis(diphenylphosphino)2,6	NOUN
eurjchem-2463	96	48	-	-	NOUN
eurjchem-2463	96	49	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	96	50	and	and	CCONJ
eurjchem-2463	96	51	pnp	pnp	PROPN
eurjchem-2463	96	52	-	-	PUNCT
eurjchem-2463	96	53	ipr	ipr	PROPN
eurjchem-2463	96	54	=	=	PUNCT
eurjchem-2463	96	55	n	n	CCONJ
eurjchem-2463	96	56	,	,	PUNCT
eurjchem-2463	96	57	n’-bis(diisopropylphosphino)-2,6	n’-bis(diisopropylphosphino)-2,6	NOUN
eurjchem-2463	96	58	-	-	NOUN
eurjchem-2463	96	59	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	96	60	,	,	PUNCT
eurjchem-2463	96	61	in	in	ADP
eurjchem-2463	96	62	moderated	moderated	ADJ
eurjchem-2463	96	63	yields	yield	NOUN
eurjchem-2463	96	64	as	as	SCONJ
eurjchem-2463	96	65	shown	show	VERB
eurjchem-2463	96	66	in	in	ADP
eurjchem-2463	96	67	scheme	scheme	NOUN
eurjchem-2463	96	68	1	1	NUM
eurjchem-2463	96	69	.	.	PUNCT
eurjchem-2463	97	1	ruivo	ruivo	PROPN
eurjchem-2463	97	2	et	et	PROPN
eurjchem-2463	97	3	al	al	PROPN
eurjchem-2463	97	4	.	.	PUNCT
eurjchem-2463	97	5	/	/	SYM
eurjchem-2463	97	6	european	european	PROPN
eurjchem-2463	97	7	journal	journal	PROPN
eurjchem-2463	97	8	of	of	ADP
eurjchem-2463	97	9	chemistry	chemistry	NOUN
eurjchem-2463	97	10	14	14	NUM
eurjchem-2463	97	11	(	(	PUNCT
eurjchem-2463	97	12	3	3	NUM
eurjchem-2463	97	13	)	)	PUNCT
eurjchem-2463	97	14	(	(	PUNCT
eurjchem-2463	97	15	2023	2023	NUM
eurjchem-2463	97	16	)	)	PUNCT
eurjchem-2463	97	17	311	311	NUM
eurjchem-2463	97	18	-	-	SYM
eurjchem-2463	97	19	315	315	NUM
eurjchem-2463	97	20	313	313	NUM
eurjchem-2463	97	21	2023	2023	NUM
eurjchem-2463	97	22	–	–	PUNCT
eurjchem-2463	97	23	european	european	ADJ
eurjchem-2463	97	24	journal	journal	NOUN
eurjchem-2463	97	25	of	of	ADP
eurjchem-2463	97	26	chemistry	chemistry	NOUN
eurjchem-2463	97	27	–	–	PUNCT
eurjchem-2463	97	28	cc	cc	NOUN
eurjchem-2463	97	29	by	by	ADP
eurjchem-2463	97	30	nc	nc	PROPN
eurjchem-2463	97	31	–	–	PUNCT
eurjchem-2463	97	32	doi	doi	NOUN
eurjchem-2463	97	33	:	:	PUNCT
eurjchem-2463	97	34	10.5155	10.5155	NUM
eurjchem-2463	97	35	/	/	SYM
eurjchem-2463	97	36	eurjchem.14.3.311	eurjchem.14.3.311	NUM
eurjchem-2463	97	37	-	-	SYM
eurjchem-2463	97	38	315.2463	315.2463	NUM
eurjchem-2463	97	39	table	table	NOUN
eurjchem-2463	97	40	1	1	NUM
eurjchem-2463	97	41	.	.	PUNCT
eurjchem-2463	98	1	crystal	crystal	NOUN
eurjchem-2463	98	2	data	datum	NOUN
eurjchem-2463	98	3	and	and	CCONJ
eurjchem-2463	98	4	details	detail	NOUN
eurjchem-2463	98	5	of	of	ADP
eurjchem-2463	98	6	structure	structure	NOUN
eurjchem-2463	98	7	refinement	refinement	NOUN
eurjchem-2463	98	8	for	for	ADP
eurjchem-2463	98	9	compounds	compound	NOUN
eurjchem-2463	98	10	1	1	NUM
eurjchem-2463	98	11	and	and	CCONJ
eurjchem-2463	98	12	2	2	NUM
eurjchem-2463	98	13	.	.	X
eurjchem-2463	98	14	parameter	parameter	NOUN
eurjchem-2463	98	15	1·(c4h8o)2	1·(c4h8o)2	NUM
eurjchem-2463	98	16	2	2	NUM
eurjchem-2463	98	17	empirical	empirical	ADJ
eurjchem-2463	98	18	formula	formula	NOUN
eurjchem-2463	98	19	c37h41cl3n3o2p2ti	c37h41cl3n3o2p2ti	NOUN
eurjchem-2463	98	20	c17h33cl3mon3p2	c17h33cl3mon3p2	NOUN
eurjchem-2463	98	21	formula	formula	NOUN
eurjchem-2463	98	22	weight	weight	NOUN
eurjchem-2463	98	23	775.89	775.89	NUM
eurjchem-2463	98	24	543.69	543.69	NUM
eurjchem-2463	98	25	temperature	temperature	NOUN
eurjchem-2463	98	26	(	(	PUNCT
eurjchem-2463	98	27	k	k	NOUN
eurjchem-2463	98	28	)	)	PUNCT
eurjchem-2463	98	29	296(2	296(2	NUM
eurjchem-2463	98	30	)	)	PUNCT
eurjchem-2463	98	31	296(2	296(2	NUM
eurjchem-2463	98	32	)	)	PUNCT
eurjchem-2463	98	33	crystal	crystal	NOUN
eurjchem-2463	98	34	system	system	NOUN
eurjchem-2463	98	35	,	,	PUNCT
eurjchem-2463	98	36	space	space	NOUN
eurjchem-2463	98	37	group	group	NOUN
eurjchem-2463	98	38	triclinic	triclinic	NOUN
eurjchem-2463	98	39	,	,	PUNCT
eurjchem-2463	98	40	p-1	p-1	NOUN
eurjchem-2463	98	41	tetragonal	tetragonal	NOUN
eurjchem-2463	98	42	,	,	PUNCT
eurjchem-2463	98	43	i41	i41	PROPN
eurjchem-2463	98	44	/	/	SYM
eurjchem-2463	98	45	a	a	DET
eurjchem-2463	98	46	a	a	NOUN
eurjchem-2463	98	47	,	,	PUNCT
eurjchem-2463	98	48	(	(	PUNCT
eurjchem-2463	98	49	aå	aå	ADV
eurjchem-2463	98	50	)	)	PUNCT
eurjchem-2463	98	51	10.0945(4	10.0945(4	NUM
eurjchem-2463	98	52	)	)	PUNCT
eurjchem-2463	98	53	19.468(4	19.468(4	PROPN
eurjchem-2463	98	54	)	)	PUNCT
eurjchem-2463	98	55	b	b	NOUN
eurjchem-2463	98	56	,	,	PUNCT
eurjchem-2463	98	57	(	(	PUNCT
eurjchem-2463	98	58	aå	aå	ADV
eurjchem-2463	98	59	)	)	PUNCT
eurjchem-2463	98	60	10.3002(4	10.3002(4	NUM
eurjchem-2463	98	61	)	)	PUNCT
eurjchem-2463	98	62	19.468(4	19.468(4	PROPN
eurjchem-2463	98	63	)	)	PUNCT
eurjchem-2463	98	64	c	c	NOUN
eurjchem-2463	98	65	,	,	PUNCT
eurjchem-2463	98	66	(	(	PUNCT
eurjchem-2463	98	67	aå	aå	ADV
eurjchem-2463	98	68	)	)	PUNCT
eurjchem-2463	98	69	18.6233(7	18.6233(7	NUM
eurjchem-2463	98	70	)	)	PUNCT
eurjchem-2463	98	71	31.711(6	31.711(6	NOUN
eurjchem-2463	98	72	)	)	PUNCT
eurjchem-2463	98	73	α	α	X
eurjchem-2463	98	74	,	,	PUNCT
eurjchem-2463	98	75	(	(	PUNCT
eurjchem-2463	98	76	°	°	PRON
eurjchem-2463	98	77	)	)	PUNCT
eurjchem-2463	98	78	92.412(2	92.412(2	NUM
eurjchem-2463	98	79	)	)	PUNCT
eurjchem-2463	98	80	90	90	NUM
eurjchem-2463	98	81	β	β	NOUN
eurjchem-2463	98	82	,	,	PUNCT
eurjchem-2463	98	83	(	(	PUNCT
eurjchem-2463	98	84	°	°	PRON
eurjchem-2463	98	85	)	)	PUNCT
eurjchem-2463	98	86	91.108(2	91.108(2	NUM
eurjchem-2463	98	87	)	)	PUNCT
eurjchem-2463	98	88	90	90	NUM
eurjchem-2463	98	89	γ	γ	NOUN
eurjchem-2463	98	90	,	,	PUNCT
eurjchem-2463	98	91	(	(	PUNCT
eurjchem-2463	98	92	°	°	PRON
eurjchem-2463	98	93	)	)	PUNCT
eurjchem-2463	98	94	101.705(3	101.705(3	NUM
eurjchem-2463	98	95	)	)	PUNCT
eurjchem-2463	98	96	90	90	NUM
eurjchem-2463	98	97	volume	volume	NOUN
eurjchem-2463	98	98	(	(	PUNCT
eurjchem-2463	98	99	å3	å3	PROPN
eurjchem-2463	98	100	)	)	PUNCT
eurjchem-2463	98	101	1893.65(13	1893.65(13	NUM
eurjchem-2463	98	102	)	)	PUNCT
eurjchem-2463	98	103	12019(5	12019(5	NUM
eurjchem-2463	98	104	)	)	PUNCT
eurjchem-2463	98	105	z	z	NOUN
eurjchem-2463	98	106	2	2	NUM
eurjchem-2463	98	107	16	16	NUM
eurjchem-2463	98	108	ρcalc	ρcalc	NOUN
eurjchem-2463	98	109	(	(	PUNCT
eurjchem-2463	98	110	g	g	NOUN
eurjchem-2463	98	111	/	/	SYM
eurjchem-2463	98	112	cm3	cm3	NOUN
eurjchem-2463	98	113	)	)	PUNCT
eurjchem-2463	98	114	1.361	1.361	NUM
eurjchem-2463	98	115	1.202	1.202	NUM
eurjchem-2463	98	116	μ	μ	NUM
eurjchem-2463	98	117	(	(	PUNCT
eurjchem-2463	98	118	mm-1	mm-1	X
eurjchem-2463	98	119	)	)	PUNCT
eurjchem-2463	98	120	0.559	0.559	NUM
eurjchem-2463	98	121	0.816	0.816	NUM
eurjchem-2463	98	122	f(000	f(000	NOUN
eurjchem-2463	98	123	)	)	PUNCT
eurjchem-2463	98	124	806	806	NUM
eurjchem-2463	98	125	4464	4464	NUM
eurjchem-2463	98	126	crystal	crystal	NOUN
eurjchem-2463	98	127	size	size	NOUN
eurjchem-2463	98	128	(	(	PUNCT
eurjchem-2463	98	129	mm3	mm3	PROPN
eurjchem-2463	98	130	)	)	PUNCT
eurjchem-2463	98	131	0.10	0.10	NUM
eurjchem-2463	98	132	×	×	NOUN
eurjchem-2463	98	133	0.20	0.20	NUM
eurjchem-2463	98	134	×	×	NOUN
eurjchem-2463	98	135	0.35	0.35	NUM
eurjchem-2463	98	136	0.20	0.20	NUM
eurjchem-2463	98	137	×	×	NOUN
eurjchem-2463	98	138	0.20	0.20	NUM
eurjchem-2463	98	139	×	×	NOUN
eurjchem-2463	98	140	0.20	0.20	NUM
eurjchem-2463	98	141	θ	θ	NOUN
eurjchem-2463	98	142	range	range	NOUN
eurjchem-2463	98	143	for	for	ADP
eurjchem-2463	98	144	data	data	NOUN
eurjchem-2463	98	145	collection	collection	NOUN
eurjchem-2463	98	146	(	(	PUNCT
eurjchem-2463	98	147	°	°	PROPN
eurjchem-2463	98	148	)	)	PUNCT
eurjchem-2463	98	149	2.021	2.021	NUM
eurjchem-2463	98	150	to	to	ADP
eurjchem-2463	98	151	27.130	27.130	NUM
eurjchem-2463	98	152	2.569	2.569	NUM
eurjchem-2463	98	153	to	to	ADP
eurjchem-2463	98	154	25.347	25.347	NUM
eurjchem-2463	98	155	index	index	NOUN
eurjchem-2463	98	156	ranges	range	VERB
eurjchem-2463	98	157	-12	-12	PUNCT
eurjchem-2463	98	158	≤	≤	NUM
eurjchem-2463	98	159	h	h	NOUN
eurjchem-2463	98	160	≤	≤	NOUN
eurjchem-2463	98	161	12	12	NUM
eurjchem-2463	98	162	,	,	PUNCT
eurjchem-2463	98	163	-9	-9	PROPN
eurjchem-2463	98	164	≤	≤	NUM
eurjchem-2463	99	1	k	k	X
eurjchem-2463	99	2	≤	≤	NUM
eurjchem-2463	99	3	13	13	NUM
eurjchem-2463	99	4	,	,	PUNCT
eurjchem-2463	99	5	-23	-23	PUNCT
eurjchem-2463	99	6	≤	≤	NUM
eurjchem-2463	99	7	l	l	NOUN
eurjchem-2463	99	8	≤	≤	NUM
eurjchem-2463	99	9	20	20	NUM
eurjchem-2463	99	10	-23	-23	SYM
eurjchem-2463	99	11	≤	≤	NUM
eurjchem-2463	99	12	h	h	NOUN
eurjchem-2463	99	13	≤	≤	NOUN
eurjchem-2463	99	14	23	23	NUM
eurjchem-2463	99	15	,	,	PUNCT
eurjchem-2463	99	16	-23	-23	PUNCT
eurjchem-2463	99	17	≤	≤	NUM
eurjchem-2463	100	1	k	k	X
eurjchem-2463	100	2	≤	≤	NUM
eurjchem-2463	100	3	23	23	NUM
eurjchem-2463	100	4	,	,	PUNCT
eurjchem-2463	100	5	-33	-33	PROPN
eurjchem-2463	100	6	≤	≤	NUM
eurjchem-2463	100	7	l	l	NOUN
eurjchem-2463	100	8	≤	≤	NUM
eurjchem-2463	100	9	38	38	NUM
eurjchem-2463	100	10	reflections	reflection	NOUN
eurjchem-2463	100	11	collected	collect	VERB
eurjchem-2463	100	12	20760	20760	NUM
eurjchem-2463	100	13	42367	42367	NUM
eurjchem-2463	100	14	independent	independent	ADJ
eurjchem-2463	100	15	reflections	reflection	NOUN
eurjchem-2463	100	16	8327	8327	NUM
eurjchem-2463	101	1	[	[	X
eurjchem-2463	101	2	rint	rint	X
eurjchem-2463	101	3	=	=	SYM
eurjchem-2463	101	4	0.0399	0.0399	NUM
eurjchem-2463	101	5	,	,	PUNCT
eurjchem-2463	101	6	rsigma	rsigma	ADJ
eurjchem-2463	101	7	=	=	SYM
eurjchem-2463	101	8	0.0414	0.0414	NUM
eurjchem-2463	101	9	]	]	PUNCT
eurjchem-2463	101	10	5498	5498	NUM
eurjchem-2463	101	11	[	[	X
eurjchem-2463	101	12	rint	rint	X
eurjchem-2463	101	13	=	=	SYM
eurjchem-2463	101	14	0.1408	0.1408	NUM
eurjchem-2463	101	15	,	,	PUNCT
eurjchem-2463	101	16	rsigma	rsigma	ADJ
eurjchem-2463	101	17	=	=	PUNCT
eurjchem-2463	101	18	0.1293	0.1293	NUM
eurjchem-2463	101	19	]	]	PUNCT
eurjchem-2463	101	20	data	data	NOUN
eurjchem-2463	101	21	/	/	SYM
eurjchem-2463	101	22	restraints	restraint	NOUN
eurjchem-2463	101	23	/	/	SYM
eurjchem-2463	101	24	parameters	parameter	NOUN
eurjchem-2463	101	25	8327/0/441	8327/0/441	NUM
eurjchem-2463	101	26	5498/25/235	5498/25/235	NUM
eurjchem-2463	101	27	goodness	goodness	NOUN
eurjchem-2463	101	28	-	-	PUNCT
eurjchem-2463	101	29	of	of	ADP
eurjchem-2463	101	30	-	-	PUNCT
eurjchem-2463	101	31	fit	fit	NOUN
eurjchem-2463	101	32	on	on	ADP
eurjchem-2463	101	33	f2	f2	PROPN
eurjchem-2463	101	34	1.058	1.058	NUM
eurjchem-2463	101	35	1.016	1.016	NUM
eurjchem-2463	101	36	final	final	ADJ
eurjchem-2463	101	37	r	r	NOUN
eurjchem-2463	101	38	indexes	index	NOUN
eurjchem-2463	101	39	[	[	X
eurjchem-2463	101	40	i≥2σ(i	i≥2σ(i	NOUN
eurjchem-2463	101	41	)	)	PUNCT
eurjchem-2463	101	42	]	]	PUNCT
eurjchem-2463	102	1	r1	r1	PROPN
eurjchem-2463	102	2	=	=	SYM
eurjchem-2463	102	3	0.0316	0.0316	PROPN
eurjchem-2463	102	4	,	,	PUNCT
eurjchem-2463	102	5	wr2	wr2	PROPN
eurjchem-2463	102	6	=	=	PROPN
eurjchem-2463	102	7	0.0818	0.0818	NUM
eurjchem-2463	102	8	r1	r1	NOUN
eurjchem-2463	102	9	=	=	PUNCT
eurjchem-2463	102	10	0.1005	0.1005	NUM
eurjchem-2463	102	11	,	,	PUNCT
eurjchem-2463	102	12	wr2	wr2	PROPN
eurjchem-2463	102	13	=	=	PROPN
eurjchem-2463	102	14	0.2728	0.2728	NUM
eurjchem-2463	102	15	final	final	ADJ
eurjchem-2463	102	16	r	r	NOUN
eurjchem-2463	102	17	indexes	index	NOUN
eurjchem-2463	102	18	[	[	X
eurjchem-2463	102	19	all	all	DET
eurjchem-2463	102	20	data	datum	NOUN
eurjchem-2463	102	21	]	]	PUNCT
eurjchem-2463	102	22	r1	r1	NOUN
eurjchem-2463	102	23	=	=	SYM
eurjchem-2463	102	24	0.0380	0.0380	NUM
eurjchem-2463	102	25	,	,	PUNCT
eurjchem-2463	102	26	wr2	wr2	PROPN
eurjchem-2463	102	27	=	=	PROPN
eurjchem-2463	102	28	0.0850	0.0850	NUM
eurjchem-2463	102	29	r1	r1	NOUN
eurjchem-2463	102	30	=	=	PUNCT
eurjchem-2463	102	31	0.2049	0.2049	NUM
eurjchem-2463	102	32	,	,	PUNCT
eurjchem-2463	102	33	wr2	wr2	PROPN
eurjchem-2463	102	34	=	=	PROPN
eurjchem-2463	102	35	0.3194	0.3194	NUM
eurjchem-2463	102	36	largest	large	ADJ
eurjchem-2463	102	37	diff	diff	NOUN
eurjchem-2463	102	38	.	.	PUNCT
eurjchem-2463	102	39	peak	peak	PROPN
eurjchem-2463	102	40	/	/	SYM
eurjchem-2463	102	41	hole	hole	NOUN
eurjchem-2463	102	42	(	(	PUNCT
eurjchem-2463	102	43	e	e	NOUN
eurjchem-2463	102	44	å-3	å-3	NUM
eurjchem-2463	102	45	)	)	PUNCT
eurjchem-2463	102	46	0.340/-0.374	0.340/-0.374	NOUN
eurjchem-2463	102	47	0.797/-0.428	0.797/-0.428	NUM
eurjchem-2463	102	48	table	table	NOUN
eurjchem-2463	102	49	2	2	NUM
eurjchem-2463	102	50	.	.	PUNCT
eurjchem-2463	102	51	relevant	relevant	ADJ
eurjchem-2463	102	52	intermolecular	intermolecular	ADJ
eurjchem-2463	102	53	hydrogen	hydrogen	NOUN
eurjchem-2463	102	54	bond	bond	NOUN
eurjchem-2463	102	55	distances	distance	NOUN
eurjchem-2463	102	56	(	(	PUNCT
eurjchem-2463	102	57	å	å	NOUN
eurjchem-2463	102	58	)	)	PUNCT
eurjchem-2463	102	59	and	and	CCONJ
eurjchem-2463	102	60	angles	angle	NOUN
eurjchem-2463	102	61	(	(	PUNCT
eurjchem-2463	102	62	°	°	NOUN
eurjchem-2463	102	63	)	)	PUNCT
eurjchem-2463	102	64	of	of	ADP
eurjchem-2463	102	65	compounds	compound	NOUN
eurjchem-2463	102	66	1	1	NUM
eurjchem-2463	102	67	and	and	CCONJ
eurjchem-2463	102	68	2	2	NUM
eurjchem-2463	102	69	.	.	X
eurjchem-2463	103	1	compound	compound	NOUN
eurjchem-2463	103	2	d	d	PROPN
eurjchem-2463	103	3	-	-	PUNCT
eurjchem-2463	103	4	h···a	h···a	ADJ
eurjchem-2463	103	5	d(d	d(d	PROPN
eurjchem-2463	103	6	-	-	PUNCT
eurjchem-2463	103	7	h	h	NOUN
eurjchem-2463	103	8	)	)	PUNCT
eurjchem-2463	103	9	d(h···a	d(h···a	NOUN
eurjchem-2463	103	10	)	)	PUNCT
eurjchem-2463	103	11	d(d···a	d(d···a	NOUN
eurjchem-2463	103	12	)	)	PUNCT
eurjchem-2463	103	13	(	(	PUNCT
eurjchem-2463	103	14	dĥa	dĥa	ADV
eurjchem-2463	103	15	)	)	PUNCT
eurjchem-2463	103	16	symmetry	symmetry	NOUN
eurjchem-2463	103	17	operation	operation	NOUN
eurjchem-2463	103	18	1	1	NUM
eurjchem-2463	103	19	n(2)-h(2n)···o(2_$1	n(2)-h(2n)···o(2_$1	NOUN
eurjchem-2463	103	20	)	)	PUNCT
eurjchem-2463	103	21	0.84	0.84	NUM
eurjchem-2463	103	22	2.02	2.02	NUM
eurjchem-2463	103	23	2.8574(1	2.8574(1	NOUN
eurjchem-2463	103	24	)	)	PUNCT
eurjchem-2463	103	25	174	174	NUM
eurjchem-2463	103	26	x	x	NOUN
eurjchem-2463	103	27	,	,	PUNCT
eurjchem-2463	103	28	1+y	1+y	NUM
eurjchem-2463	103	29	,	,	PUNCT
eurjchem-2463	103	30	z	z	NOUN
eurjchem-2463	103	31	n(3)-h(3n)···o(1	n(3)-h(3n)···o(1	NOUN
eurjchem-2463	103	32	)	)	PUNCT
eurjchem-2463	103	33	0.82	0.82	NUM
eurjchem-2463	103	34	2.05	2.05	NUM
eurjchem-2463	103	35	2.8562(1	2.8562(1	NUM
eurjchem-2463	103	36	)	)	PUNCT
eurjchem-2463	103	37	171	171	NUM
eurjchem-2463	103	38	1	1	NUM
eurjchem-2463	103	39	-	-	PUNCT
eurjchem-2463	103	40	x	x	NOUN
eurjchem-2463	103	41	,	,	PUNCT
eurjchem-2463	103	42	1	1	NUM
eurjchem-2463	103	43	-	-	SYM
eurjchem-2463	103	44	y	y	NOUN
eurjchem-2463	103	45	,	,	PUNCT
eurjchem-2463	103	46	1	1	NUM
eurjchem-2463	103	47	-	-	PUNCT
eurjchem-2463	103	48	z	z	PROPN
eurjchem-2463	103	49	2	2	NUM
eurjchem-2463	103	50	n(2)-h(2n)···cl(3_$1	n(2)-h(2n)···cl(3_$1	PROPN
eurjchem-2463	103	51	)	)	PUNCT
eurjchem-2463	103	52	0.86	0.86	NUM
eurjchem-2463	103	53	2.51	2.51	NUM
eurjchem-2463	103	54	3.3523(7	3.3523(7	NUM
eurjchem-2463	103	55	)	)	PUNCT
eurjchem-2463	103	56	166	166	NUM
eurjchem-2463	103	57	-¼+y	-¼+y	NOUN
eurjchem-2463	103	58	,	,	PUNCT
eurjchem-2463	103	59	¼-x	¼-x	NOUN
eurjchem-2463	103	60	,	,	PUNCT
eurjchem-2463	103	61	¼-z	¼-z	PROPN
eurjchem-2463	103	62	n(3)-h(3n)···cl(2_$2	n(3)-h(3n)···cl(2_$2	PROPN
eurjchem-2463	103	63	)	)	PUNCT
eurjchem-2463	103	64	0.86	0.86	NUM
eurjchem-2463	103	65	2.44	2.44	NUM
eurjchem-2463	103	66	3.2843(7	3.2843(7	NUM
eurjchem-2463	103	67	)	)	PUNCT
eurjchem-2463	103	68	168	168	NUM
eurjchem-2463	103	69	¾-y	¾-y	PROPN
eurjchem-2463	103	70	,	,	PUNCT
eurjchem-2463	103	71	¼+x	¼+x	NOUN
eurjchem-2463	103	72	,	,	PUNCT
eurjchem-2463	103	73	¼+z	¼+z	ADJ
eurjchem-2463	103	74	figure	figure	NOUN
eurjchem-2463	103	75	1	1	NUM
eurjchem-2463	103	76	.	.	PUNCT
eurjchem-2463	104	1	ortep	ortep	NOUN
eurjchem-2463	104	2	diagram	diagram	NOUN
eurjchem-2463	104	3	of	of	ADP
eurjchem-2463	104	4	1	1	NUM
eurjchem-2463	104	5	showing	show	VERB
eurjchem-2463	104	6	thermal	thermal	ADJ
eurjchem-2463	104	7	ellipsoids	ellipsoid	NOUN
eurjchem-2463	104	8	at	at	ADP
eurjchem-2463	104	9	40	40	NUM
eurjchem-2463	104	10	%	%	NOUN
eurjchem-2463	104	11	probability	probability	NOUN
eurjchem-2463	104	12	level	level	NOUN
eurjchem-2463	104	13	.	.	PUNCT
eurjchem-2463	105	1	selected	select	VERB
eurjchem-2463	105	2	hydrogen	hydrogen	NOUN
eurjchem-2463	105	3	atoms	atom	NOUN
eurjchem-2463	105	4	are	be	AUX
eurjchem-2463	105	5	omitted	omit	VERB
eurjchem-2463	105	6	for	for	ADP
eurjchem-2463	105	7	clarity	clarity	NOUN
eurjchem-2463	105	8	.	.	PUNCT
eurjchem-2463	106	1	dashed	dash	VERB
eurjchem-2463	106	2	lines	line	NOUN
eurjchem-2463	106	3	represent	represent	VERB
eurjchem-2463	106	4	hydrogen	hydrogen	NOUN
eurjchem-2463	106	5	bonds	bond	NOUN
eurjchem-2463	106	6	.	.	PUNCT
eurjchem-2463	107	1	selected	select	VERB
eurjchem-2463	107	2	bond	bond	NOUN
eurjchem-2463	107	3	lengths	length	NOUN
eurjchem-2463	107	4	(	(	PUNCT
eurjchem-2463	107	5	å	å	NOUN
eurjchem-2463	107	6	)	)	PUNCT
eurjchem-2463	107	7	and	and	CCONJ
eurjchem-2463	107	8	angles	angle	NOUN
eurjchem-2463	107	9	(	(	PUNCT
eurjchem-2463	107	10	°	°	PROPN
eurjchem-2463	107	11	):	):	PUNCT
eurjchem-2463	107	12	ti(1)-n(1	ti(1)-n(1	X
eurjchem-2463	107	13	)	)	PUNCT
eurjchem-2463	107	14	2.235(1	2.235(1	NUM
eurjchem-2463	107	15	)	)	PUNCT
eurjchem-2463	107	16	,	,	PUNCT
eurjchem-2463	107	17	ti(1)-p(1	ti(1)-p(1	NOUN
eurjchem-2463	107	18	)	)	PUNCT
eurjchem-2463	107	19	2.5487(4	2.5487(4	NUM
eurjchem-2463	107	20	)	)	PUNCT
eurjchem-2463	107	21	,	,	PUNCT
eurjchem-2463	107	22	ti(1)-p(2	ti(1)-p(2	NOUN
eurjchem-2463	107	23	)	)	PUNCT
eurjchem-2463	107	24	2.5839(5	2.5839(5	NUM
eurjchem-2463	107	25	)	)	PUNCT
eurjchem-2463	107	26	,	,	PUNCT
eurjchem-2463	107	27	ti(1)-cl(1	ti(1)-cl(1	NUM
eurjchem-2463	107	28	)	)	PUNCT
eurjchem-2463	107	29	2.3146(4	2.3146(4	NUM
eurjchem-2463	107	30	)	)	PUNCT
eurjchem-2463	107	31	,	,	PUNCT
eurjchem-2463	107	32	ti(1)-cl(2	ti(1)-cl(2	NOUN
eurjchem-2463	107	33	)	)	PUNCT
eurjchem-2463	107	34	2.3650(4	2.3650(4	NUM
eurjchem-2463	107	35	)	)	PUNCT
eurjchem-2463	107	36	,	,	PUNCT
eurjchem-2463	107	37	ti(1)-cl(3	ti(1)-cl(3	NOUN
eurjchem-2463	107	38	)	)	PUNCT
eurjchem-2463	107	39	2.3310(4	2.3310(4	NUM
eurjchem-2463	107	40	)	)	PUNCT
eurjchem-2463	107	41	;	;	PUNCT
eurjchem-2463	107	42	p(1)-ti(1)-n(1	p(1)-ti(1)-n(1	NOUN
eurjchem-2463	107	43	)	)	PUNCT
eurjchem-2463	107	44	77.63(3	77.63(3	NOUN
eurjchem-2463	107	45	)	)	PUNCT
eurjchem-2463	107	46	,	,	PUNCT
eurjchem-2463	107	47	p(2)-ti(1)-n(1	p(2)-ti(1)-n(1	NOUN
eurjchem-2463	107	48	)	)	PUNCT
eurjchem-2463	107	49	76.90(3	76.90(3	NOUN
eurjchem-2463	107	50	)	)	PUNCT
eurjchem-2463	107	51	,	,	PUNCT
eurjchem-2463	107	52	p(1)-ti(1)-cl(2	p(1)-ti(1)-cl(2	NOUN
eurjchem-2463	107	53	)	)	PUNCT
eurjchem-2463	107	54	102.62(2	102.62(2	NUM
eurjchem-2463	107	55	)	)	PUNCT
eurjchem-2463	107	56	,	,	PUNCT
eurjchem-2463	107	57	p(2)-ti(1)-cl(2	p(2)-ti(1)-cl(2	NOUN
eurjchem-2463	107	58	)	)	PUNCT
eurjchem-2463	107	59	102.89(2	102.89(2	NUM
eurjchem-2463	107	60	)	)	PUNCT
eurjchem-2463	107	61	,	,	PUNCT
eurjchem-2463	107	62	p(1)-ti(1)-p(2	p(1)-ti(1)-p(2	PROPN
eurjchem-2463	107	63	)	)	PUNCT
eurjchem-2463	107	64	154.37(2	154.37(2	NUM
eurjchem-2463	107	65	)	)	PUNCT
eurjchem-2463	107	66	,	,	PUNCT
eurjchem-2463	107	67	n(1)-ti(1)-cl(2	n(1)-ti(1)-cl(2	NOUN
eurjchem-2463	107	68	)	)	PUNCT
eurjchem-2463	107	69	179.13(3	179.13(3	NUM
eurjchem-2463	107	70	)	)	PUNCT
eurjchem-2463	107	71	,	,	PUNCT
eurjchem-2463	107	72	cl(1)-ti(1)-cl(3	cl(1)-ti(1)-cl(3	NOUN
eurjchem-2463	107	73	)	)	PUNCT
eurjchem-2463	107	74	168.85(2	168.85(2	NUM
eurjchem-2463	107	75	)	)	PUNCT
eurjchem-2463	107	76	.	.	PUNCT
eurjchem-2463	108	1	crystals	crystal	NOUN
eurjchem-2463	108	2	of	of	ADP
eurjchem-2463	108	3	1	1	NUM
eurjchem-2463	108	4	and	and	CCONJ
eurjchem-2463	108	5	2	2	NUM
eurjchem-2463	108	6	suitable	suitable	ADJ
eurjchem-2463	108	7	for	for	ADP
eurjchem-2463	108	8	single	single	ADJ
eurjchem-2463	108	9	-	-	PUNCT
eurjchem-2463	108	10	crystal	crystal	NOUN
eurjchem-2463	108	11	x	x	ADJ
eurjchem-2463	108	12	-	-	NOUN
eurjchem-2463	108	13	ray	ray	NOUN
eurjchem-2463	108	14	diffraction	diffraction	NOUN
eurjchem-2463	108	15	were	be	AUX
eurjchem-2463	108	16	obtained	obtain	VERB
eurjchem-2463	108	17	by	by	ADP
eurjchem-2463	108	18	slow	slow	ADJ
eurjchem-2463	108	19	concentration	concentration	NOUN
eurjchem-2463	108	20	of	of	ADP
eurjchem-2463	108	21	thf	thf	NOUN
eurjchem-2463	108	22	and	and	CCONJ
eurjchem-2463	108	23	dichloromethane	dichloromethane	NOUN
eurjchem-2463	108	24	solutions	solution	NOUN
eurjchem-2463	108	25	,	,	PUNCT
eurjchem-2463	108	26	respectively	respectively	ADV
eurjchem-2463	108	27	,	,	PUNCT
eurjchem-2463	108	28	at	at	ADP
eurjchem-2463	108	29	room	room	NOUN
eurjchem-2463	108	30	temperature	temperature	NOUN
eurjchem-2463	108	31	,	,	PUNCT
eurjchem-2463	108	32	using	use	VERB
eurjchem-2463	108	33	an	an	DET
eurjchem-2463	108	34	h	h	NOUN
eurjchem-2463	108	35	-	-	PUNCT
eurjchem-2463	108	36	shaped	shape	VERB
eurjchem-2463	108	37	glass	glass	NOUN
eurjchem-2463	108	38	tube	tube	NOUN
eurjchem-2463	108	39	containing	contain	VERB
eurjchem-2463	108	40	the	the	DET
eurjchem-2463	108	41	solution	solution	NOUN
eurjchem-2463	108	42	of	of	ADP
eurjchem-2463	108	43	the	the	DET
eurjchem-2463	108	44	compound	compound	NOUN
eurjchem-2463	108	45	and	and	CCONJ
eurjchem-2463	108	46	toluene	toluene	NOUN
eurjchem-2463	108	47	in	in	ADP
eurjchem-2463	108	48	each	each	DET
eurjchem-2463	108	49	side	side	NOUN
eurjchem-2463	108	50	of	of	ADP
eurjchem-2463	108	51	the	the	DET
eurjchem-2463	108	52	tube	tube	NOUN
eurjchem-2463	108	53	.	.	PUNCT
eurjchem-2463	109	1	in	in	ADP
eurjchem-2463	109	2	these	these	DET
eurjchem-2463	109	3	conditions	condition	NOUN
eurjchem-2463	109	4	,	,	PUNCT
eurjchem-2463	109	5	the	the	DET
eurjchem-2463	109	6	evaporation	evaporation	NOUN
eurjchem-2463	109	7	of	of	ADP
eurjchem-2463	109	8	the	the	DET
eurjchem-2463	109	9	solvent	solvent	NOUN
eurjchem-2463	109	10	is	be	AUX
eurjchem-2463	109	11	determined	determine	VERB
eurjchem-2463	109	12	by	by	ADP
eurjchem-2463	109	13	dissolution	dissolution	NOUN
eurjchem-2463	109	14	and	and	CCONJ
eurjchem-2463	109	15	diffusion	diffusion	NOUN
eurjchem-2463	109	16	into	into	ADP
eurjchem-2463	109	17	toluene	toluene	NOUN
eurjchem-2463	109	18	.	.	PUNCT
eurjchem-2463	110	1	complex	complex	ADJ
eurjchem-2463	110	2	1	1	NUM
eurjchem-2463	110	3	crystallized	crystallize	VERB
eurjchem-2463	110	4	in	in	ADP
eurjchem-2463	110	5	the	the	DET
eurjchem-2463	110	6	triclinic	triclinic	ADJ
eurjchem-2463	110	7	p-1	p-1	NOUN
eurjchem-2463	110	8	space	space	NOUN
eurjchem-2463	110	9	group	group	NOUN
eurjchem-2463	110	10	,	,	PUNCT
eurjchem-2463	110	11	while	while	SCONJ
eurjchem-2463	110	12	complex	complex	ADJ
eurjchem-2463	110	13	2	2	NUM
eurjchem-2463	110	14	crystallized	crystallize	VERB
eurjchem-2463	110	15	in	in	ADP
eurjchem-2463	110	16	the	the	DET
eurjchem-2463	110	17	tetragonal	tetragonal	ADJ
eurjchem-2463	110	18	i41	i41	PROPN
eurjchem-2463	110	19	/	/	SYM
eurjchem-2463	110	20	a	a	DET
eurjchem-2463	110	21	space	space	NOUN
eurjchem-2463	110	22	group	group	NOUN
eurjchem-2463	110	23	.	.	PUNCT
eurjchem-2463	111	1	ortep	ortep	NOUN
eurjchem-2463	111	2	diagrams	diagram	NOUN
eurjchem-2463	111	3	of	of	ADP
eurjchem-2463	111	4	complexes	complex	NOUN
eurjchem-2463	111	5	1	1	NUM
eurjchem-2463	111	6	and	and	CCONJ
eurjchem-2463	111	7	2	2	NUM
eurjchem-2463	111	8	and	and	CCONJ
eurjchem-2463	111	9	the	the	DET
eurjchem-2463	111	10	selected	select	VERB
eurjchem-2463	111	11	bond	bond	NOUN
eurjchem-2463	111	12	lengths	length	NOUN
eurjchem-2463	111	13	and	and	CCONJ
eurjchem-2463	111	14	angles	angle	NOUN
eurjchem-2463	111	15	are	be	AUX
eurjchem-2463	111	16	shown	show	VERB
eurjchem-2463	111	17	in	in	ADP
eurjchem-2463	111	18	figures	figure	NOUN
eurjchem-2463	111	19	1	1	NUM
eurjchem-2463	111	20	and	and	CCONJ
eurjchem-2463	111	21	2	2	NUM
eurjchem-2463	111	22	,	,	PUNCT
eurjchem-2463	111	23	respectively	respectively	ADV
eurjchem-2463	111	24	.	.	PUNCT
eurjchem-2463	112	1	the	the	DET
eurjchem-2463	112	2	solid	solid	ADJ
eurjchem-2463	112	3	-	-	PUNCT
eurjchem-2463	112	4	state	state	NOUN
eurjchem-2463	112	5	molecular	molecular	ADJ
eurjchem-2463	112	6	structures	structure	NOUN
eurjchem-2463	112	7	of	of	ADP
eurjchem-2463	112	8	complexes	complex	NOUN
eurjchem-2463	112	9	1	1	NUM
eurjchem-2463	112	10	and	and	CCONJ
eurjchem-2463	112	11	2	2	NUM
eurjchem-2463	112	12	determined	determine	VERB
eurjchem-2463	112	13	by	by	ADP
eurjchem-2463	112	14	single	single	ADJ
eurjchem-2463	112	15	crystal	crystal	NOUN
eurjchem-2463	112	16	x	x	PROPN
eurjchem-2463	112	17	-	-	NOUN
eurjchem-2463	112	18	ray	ray	NOUN
eurjchem-2463	112	19	diffraction	diffraction	NOUN
eurjchem-2463	112	20	show	show	NOUN
eurjchem-2463	112	21	distorted	distort	VERB
eurjchem-2463	112	22	octahedral	octahedral	ADJ
eurjchem-2463	112	23	trivalent	trivalent	NOUN
eurjchem-2463	112	24	titanium	titanium	NOUN
eurjchem-2463	112	25	and	and	CCONJ
eurjchem-2463	112	26	molybdenum	molybdenum	NOUN
eurjchem-2463	112	27	centers	center	NOUN
eurjchem-2463	112	28	.	.	PUNCT
eurjchem-2463	113	1	the	the	DET
eurjchem-2463	113	2	three	three	NUM
eurjchem-2463	113	3	donor	donor	NOUN
eurjchem-2463	113	4	atoms	atom	NOUN
eurjchem-2463	113	5	of	of	ADP
eurjchem-2463	113	6	the	the	DET
eurjchem-2463	113	7	pnp	pnp	PROPN
eurjchem-2463	113	8	ligand	ligand	NOUN
eurjchem-2463	113	9	and	and	CCONJ
eurjchem-2463	113	10	one	one	NUM
eurjchem-2463	113	11	chloride	chloride	NOUN
eurjchem-2463	113	12	atom	atom	NOUN
eurjchem-2463	113	13	occupy	occupy	VERB
eurjchem-2463	113	14	the	the	DET
eurjchem-2463	113	15	equatorial	equatorial	ADJ
eurjchem-2463	113	16	plane	plane	NOUN
eurjchem-2463	113	17	of	of	ADP
eurjchem-2463	113	18	both	both	DET
eurjchem-2463	113	19	octahedra	octahedron	NOUN
eurjchem-2463	113	20	,	,	PUNCT
eurjchem-2463	113	21	which	which	PRON
eurjchem-2463	113	22	is	be	AUX
eurjchem-2463	113	23	usually	usually	ADV
eurjchem-2463	113	24	defined	define	VERB
eurjchem-2463	113	25	as	as	ADP
eurjchem-2463	113	26	the	the	DET
eurjchem-2463	113	27	one	one	NOUN
eurjchem-2463	113	28	containing	contain	VERB
eurjchem-2463	113	29	the	the	DET
eurjchem-2463	113	30	donor	donor	NOUN
eurjchem-2463	113	31	atoms	atom	NOUN
eurjchem-2463	113	32	of	of	ADP
eurjchem-2463	113	33	the	the	DET
eurjchem-2463	113	34	pincer	pincer	NOUN
eurjchem-2463	113	35	ligand	ligand	NOUN
eurjchem-2463	113	36	.	.	PUNCT
eurjchem-2463	114	1	the	the	DET
eurjchem-2463	114	2	p	p	PROPN
eurjchem-2463	114	3	-	-	PUNCT
eurjchem-2463	114	4	m	m	NOUN
eurjchem-2463	114	5	-	-	PUNCT
eurjchem-2463	114	6	cl	cl	NOUN
eurjchem-2463	114	7	angles	angle	NOUN
eurjchem-2463	114	8	are	be	AUX
eurjchem-2463	114	9	wider	wide	ADJ
eurjchem-2463	114	10	than	than	ADP
eurjchem-2463	114	11	90	90	NUM
eurjchem-2463	114	12	°	°	NOUN
eurjchem-2463	114	13	,	,	PUNCT
eurjchem-2463	114	14	while	while	SCONJ
eurjchem-2463	114	15	the	the	DET
eurjchem-2463	114	16	n	n	CCONJ
eurjchem-2463	114	17	-	-	PUNCT
eurjchem-2463	114	18	m	m	NOUN
eurjchem-2463	114	19	-	-	PUNCT
eurjchem-2463	114	20	p	p	NOUN
eurjchem-2463	114	21	and	and	CCONJ
eurjchem-2463	114	22	the	the	DET
eurjchem-2463	114	23	p	p	PROPN
eurjchem-2463	114	24	-	-	PUNCT
eurjchem-2463	114	25	m	m	NOUN
eurjchem-2463	114	26	-	-	ADJ
eurjchem-2463	114	27	p	p	NOUN
eurjchem-2463	114	28	angles	angle	NOUN
eurjchem-2463	114	29	are	be	AUX
eurjchem-2463	114	30	narrower	narrow	ADJ
eurjchem-2463	114	31	than	than	ADP
eurjchem-2463	114	32	90	90	NUM
eurjchem-2463	114	33	°	°	NUM
eurjchem-2463	114	34	and	and	CCONJ
eurjchem-2463	114	35	180	180	NUM
eurjchem-2463	114	36	°	°	NOUN
eurjchem-2463	114	37	,	,	PUNCT
eurjchem-2463	114	38	respectively	respectively	ADV
eurjchem-2463	114	39	,	,	PUNCT
eurjchem-2463	114	40	as	as	ADP
eurjchem-2463	114	41	a	a	DET
eurjchem-2463	114	42	consequence	consequence	NOUN
eurjchem-2463	114	43	of	of	ADP
eurjchem-2463	114	44	the	the	DET
eurjchem-2463	114	45	chelating	chelate	VERB
eurjchem-2463	114	46	nature	nature	NOUN
eurjchem-2463	114	47	of	of	ADP
eurjchem-2463	114	48	the	the	DET
eurjchem-2463	114	49	pincer	pincer	NOUN
eurjchem-2463	114	50	ligand	ligand	NOUN
eurjchem-2463	114	51	.	.	PUNCT
eurjchem-2463	115	1	the	the	DET
eurjchem-2463	115	2	axial	axial	ADJ
eurjchem-2463	115	3	positions	position	NOUN
eurjchem-2463	115	4	are	be	AUX
eurjchem-2463	115	5	occupied	occupy	VERB
eurjchem-2463	115	6	by	by	ADP
eurjchem-2463	115	7	two	two	NUM
eurjchem-2463	115	8	chlorine	chlorine	NOUN
eurjchem-2463	115	9	atoms	atom	NOUN
eurjchem-2463	115	10	that	that	PRON
eurjchem-2463	115	11	define	define	VERB
eurjchem-2463	115	12	cl	cl	NOUN
eurjchem-2463	115	13	-	-	PUNCT
eurjchem-2463	115	14	m	m	NOUN
eurjchem-2463	115	15	-	-	PUNCT
eurjchem-2463	115	16	cl	cl	NOUN
eurjchem-2463	115	17	angles	angle	NOUN
eurjchem-2463	115	18	that	that	PRON
eurjchem-2463	115	19	deviate	deviate	VERB
eurjchem-2463	115	20	from	from	ADP
eurjchem-2463	115	21	linearity	linearity	NOUN
eurjchem-2463	115	22	(	(	PUNCT
eurjchem-2463	115	23	168.85(2	168.85(2	NUM
eurjchem-2463	115	24	)	)	PUNCT
eurjchem-2463	115	25	°	°	NOUN
eurjchem-2463	115	26	in	in	ADP
eurjchem-2463	115	27	1	1	NUM
eurjchem-2463	115	28	and	and	CCONJ
eurjchem-2463	115	29	176.7(2	176.7(2	NUM
eurjchem-2463	115	30	)	)	PUNCT
eurjchem-2463	115	31	°	°	PROPN
eurjchem-2463	115	32	in	in	ADP
eurjchem-2463	115	33	2	2	NUM
eurjchem-2463	115	34	)	)	PUNCT
eurjchem-2463	115	35	and	and	CCONJ
eurjchem-2463	115	36	are	be	AUX
eurjchem-2463	115	37	contracted	contract	VERB
eurjchem-2463	115	38	toward	toward	ADP
eurjchem-2463	115	39	the	the	DET
eurjchem-2463	115	40	pyridine	pyridine	ADJ
eurjchem-2463	115	41	ring	ring	NOUN
eurjchem-2463	115	42	.	.	PUNCT
eurjchem-2463	116	1	the	the	DET
eurjchem-2463	116	2	same	same	ADJ
eurjchem-2463	116	3	pattern	pattern	NOUN
eurjchem-2463	116	4	is	be	AUX
eurjchem-2463	116	5	observed	observe	VERB
eurjchem-2463	116	6	for	for	ADP
eurjchem-2463	116	7	the	the	DET
eurjchem-2463	116	8	p	p	PROPN
eurjchem-2463	116	9	-	-	PUNCT
eurjchem-2463	116	10	m	m	NOUN
eurjchem-2463	116	11	-	-	ADJ
eurjchem-2463	116	12	p	p	NOUN
eurjchem-2463	116	13	angles	angle	NOUN
eurjchem-2463	116	14	(	(	PUNCT
eurjchem-2463	116	15	154.37(2	154.37(2	NUM
eurjchem-2463	116	16	)	)	PUNCT
eurjchem-2463	116	17	°	°	NOUN
eurjchem-2463	116	18	in	in	ADP
eurjchem-2463	116	19	1	1	NUM
eurjchem-2463	116	20	and	and	CCONJ
eurjchem-2463	116	21	156.1(1	156.1(1	NUM
eurjchem-2463	116	22	)	)	PUNCT
eurjchem-2463	116	23	°	°	NOUN
eurjchem-2463	116	24	in	in	ADP
eurjchem-2463	116	25	2	2	NUM
eurjchem-2463	116	26	)	)	PUNCT
eurjchem-2463	116	27	.	.	PUNCT
eurjchem-2463	117	1	this	this	DET
eurjchem-2463	117	2	feature	feature	NOUN
eurjchem-2463	117	3	is	be	AUX
eurjchem-2463	117	4	also	also	ADV
eurjchem-2463	117	5	observed	observe	VERB
eurjchem-2463	117	6	in	in	ADP
eurjchem-2463	117	7	other	other	ADJ
eurjchem-2463	117	8	m(iii	m(iii	ADJ
eurjchem-2463	117	9	)	)	PUNCT
eurjchem-2463	117	10	complexes	complex	NOUN
eurjchem-2463	117	11	(	(	PUNCT
eurjchem-2463	117	12	m	m	PROPN
eurjchem-2463	117	13	=	=	SYM
eurjchem-2463	117	14	v	v	PROPN
eurjchem-2463	118	1	[	[	X
eurjchem-2463	118	2	11,12	11,12	NOUN
eurjchem-2463	118	3	]	]	PUNCT
eurjchem-2463	118	4	,	,	PUNCT
eurjchem-2463	118	5	cr	cr	X
eurjchem-2463	119	1	[	[	X
eurjchem-2463	119	2	12,37,38	12,37,38	NUM
eurjchem-2463	119	3	]	]	PUNCT
eurjchem-2463	119	4	,	,	PUNCT
eurjchem-2463	119	5	mo	mo	PROPN
eurjchem-2463	119	6	[	[	X
eurjchem-2463	119	7	27	27	NUM
eurjchem-2463	119	8	]	]	PUNCT
eurjchem-2463	119	9	,	,	PUNCT
eurjchem-2463	119	10	ru	ru	PROPN
eurjchem-2463	120	1	[	[	X
eurjchem-2463	120	2	39	39	NUM
eurjchem-2463	120	3	]	]	PUNCT
eurjchem-2463	120	4	,	,	PUNCT
eurjchem-2463	120	5	and	and	CCONJ
eurjchem-2463	120	6	in	in	ADP
eurjchem-2463	120	7	[	[	X
eurjchem-2463	120	8	40	40	NUM
eurjchem-2463	120	9	]	]	PUNCT
eurjchem-2463	120	10	)	)	PUNCT
eurjchem-2463	120	11	supported	support	VERB
eurjchem-2463	120	12	by	by	ADP
eurjchem-2463	120	13	pnp	pnp	PROPN
eurjchem-2463	120	14	ligands	ligand	NOUN
eurjchem-2463	120	15	based	base	VERB
eurjchem-2463	120	16	on	on	ADP
eurjchem-2463	120	17	2,6	2,6	NUM
eurjchem-2463	120	18	-	-	NOUN
eurjchem-2463	120	19	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	120	20	.	.	PUNCT
eurjchem-2463	121	1	complex	complex	ADJ
eurjchem-2463	121	2	1	1	NUM
eurjchem-2463	121	3	crystallized	crystallize	VERB
eurjchem-2463	121	4	with	with	ADP
eurjchem-2463	121	5	two	two	NUM
eurjchem-2463	121	6	molecules	molecule	NOUN
eurjchem-2463	121	7	of	of	ADP
eurjchem-2463	121	8	thf	thf	NOUN
eurjchem-2463	121	9	that	that	PRON
eurjchem-2463	121	10	interact	interact	VERB
eurjchem-2463	121	11	with	with	ADP
eurjchem-2463	121	12	the	the	DET
eurjchem-2463	121	13	nh	nh	PROPN
eurjchem-2463	121	14	spacers	spacer	NOUN
eurjchem-2463	121	15	of	of	ADP
eurjchem-2463	121	16	the	the	DET
eurjchem-2463	121	17	pnp	pnp	PROPN
eurjchem-2463	121	18	ligand	ligand	NOUN
eurjchem-2463	121	19	by	by	ADP
eurjchem-2463	121	20	n	n	CCONJ
eurjchem-2463	121	21	-	-	PUNCT
eurjchem-2463	121	22	h···o	h···o	PROPN
eurjchem-2463	121	23	hydrogen	hydrogen	NOUN
eurjchem-2463	121	24	bonds	bond	NOUN
eurjchem-2463	121	25	with	with	ADP
eurjchem-2463	121	26	bridging	bridging	NOUN
eurjchem-2463	121	27	distances	distance	NOUN
eurjchem-2463	121	28	of	of	ADP
eurjchem-2463	121	29	2.02	2.02	NUM
eurjchem-2463	121	30	and	and	CCONJ
eurjchem-2463	121	31	2.05	2.05	NUM
eurjchem-2463	121	32	å	å	NOUN
eurjchem-2463	121	33	.	.	PUNCT
eurjchem-2463	122	1	complex	complex	ADJ
eurjchem-2463	122	2	1	1	NUM
eurjchem-2463	122	3	is	be	AUX
eurjchem-2463	122	4	isostructural	isostructural	ADJ
eurjchem-2463	122	5	with	with	ADP
eurjchem-2463	122	6	vanadium(iii	vanadium(iii	NOUN
eurjchem-2463	122	7	)	)	PUNCT
eurjchem-2463	122	8	trichlorido	trichlorido	NOUN
eurjchem-2463	122	9	[	[	X
eurjchem-2463	122	10	(	(	PUNCT
eurjchem-2463	122	11	pnp	pnp	NOUN
eurjchem-2463	122	12	-	-	PUNCT
eurjchem-2463	122	13	ph)vcl3]·(c4h8o)2	ph)vcl3]·(c4h8o)2	PROPN
eurjchem-2463	122	14	already	already	ADV
eurjchem-2463	122	15	reported	report	VERB
eurjchem-2463	122	16	in	in	ADP
eurjchem-2463	122	17	the	the	DET
eurjchem-2463	122	18	literature	literature	NOUN
eurjchem-2463	122	19	[	[	X
eurjchem-2463	122	20	11	11	NUM
eurjchem-2463	122	21	]	]	PUNCT
eurjchem-2463	122	22	.	.	PUNCT
eurjchem-2463	123	1	complex	complex	ADJ
eurjchem-2463	123	2	2	2	NUM
eurjchem-2463	123	3	shows	show	VERB
eurjchem-2463	123	4	two	two	NUM
eurjchem-2463	123	5	hydrogen	hydrogen	NOUN
eurjchem-2463	123	6	bonds	bond	NOUN
eurjchem-2463	123	7	of	of	ADP
eurjchem-2463	123	8	the	the	DET
eurjchem-2463	123	9	type	type	NOUN
eurjchem-2463	123	10	n	n	CCONJ
eurjchem-2463	123	11	-	-	PUNCT
eurjchem-2463	123	12	h···cl	h···cl	NOUN
eurjchem-2463	123	13	established	establish	VERB
eurjchem-2463	123	14	between	between	ADP
eurjchem-2463	123	15	the	the	DET
eurjchem-2463	123	16	amino	amino	NOUN
eurjchem-2463	123	17	spacers	spacer	NOUN
eurjchem-2463	123	18	and	and	CCONJ
eurjchem-2463	123	19	the	the	DET
eurjchem-2463	123	20	chlorine	chlorine	NOUN
eurjchem-2463	123	21	atoms	atom	NOUN
eurjchem-2463	123	22	of	of	ADP
eurjchem-2463	123	23	neighboring	neighboring	NOUN
eurjchem-2463	123	24	molecules	molecule	NOUN
eurjchem-2463	123	25	,	,	PUNCT
eurjchem-2463	123	26	which	which	PRON
eurjchem-2463	123	27	are	be	AUX
eurjchem-2463	123	28	responsible	responsible	ADJ
eurjchem-2463	123	29	for	for	ADP
eurjchem-2463	123	30	the	the	DET
eurjchem-2463	123	31	molecular	molecular	ADJ
eurjchem-2463	123	32	assembly	assembly	NOUN
eurjchem-2463	123	33	.	.	PUNCT
eurjchem-2463	124	1	the	the	DET
eurjchem-2463	124	2	n(3)h(3n)···cl(2	n(3)h(3n)···cl(2	PROPN
eurjchem-2463	124	3	)	)	PUNCT
eurjchem-2463	124	4	interactions	interaction	NOUN
eurjchem-2463	124	5	between	between	ADP
eurjchem-2463	124	6	molecules	molecule	NOUN
eurjchem-2463	124	7	of	of	ADP
eurjchem-2463	124	8	2	2	NUM
eurjchem-2463	124	9	,	,	PUNCT
eurjchem-2463	124	10	at	at	ADP
eurjchem-2463	124	11	the	the	DET
eurjchem-2463	124	12	supramolecular	supramolecular	ADJ
eurjchem-2463	124	13	level	level	NOUN
eurjchem-2463	124	14	,	,	PUNCT
eurjchem-2463	124	15	define	define	VERB
eurjchem-2463	124	16	helicoidal	helicoidal	ADJ
eurjchem-2463	124	17	chains	chain	NOUN
eurjchem-2463	124	18	that	that	PRON
eurjchem-2463	124	19	grow	grow	VERB
eurjchem-2463	124	20	along	along	ADP
eurjchem-2463	124	21	the	the	DET
eurjchem-2463	124	22	a	a	DET
eurjchem-2463	124	23	direction	direction	NOUN
eurjchem-2463	124	24	.	.	PUNCT
eurjchem-2463	125	1	these	these	DET
eurjchem-2463	125	2	chains	chain	NOUN
eurjchem-2463	125	3	interact	interact	VERB
eurjchem-2463	125	4	with	with	ADP
eurjchem-2463	125	5	each	each	DET
eurjchem-2463	125	6	other	other	ADJ
eurjchem-2463	125	7	by	by	ADP
eurjchem-2463	125	8	n(2)h(2n)···cl(3	n(2)h(2n)···cl(3	NUM
eurjchem-2463	125	9	)	)	PUNCT
eurjchem-2463	125	10	hydrogen	hydrogen	NOUN
eurjchem-2463	125	11	bonds	bond	NOUN
eurjchem-2463	125	12	with	with	ADP
eurjchem-2463	125	13	a	a	DET
eurjchem-2463	125	14	distance	distance	NOUN
eurjchem-2463	125	15	of	of	ADP
eurjchem-2463	125	16	2.51	2.51	NUM
eurjchem-2463	125	17	å	å	NOUN
eurjchem-2463	125	18	,	,	PUNCT
eurjchem-2463	125	19	creating	create	VERB
eurjchem-2463	125	20	a	a	DET
eurjchem-2463	125	21	three	three	NUM
eurjchem-2463	125	22	-	-	PUNCT
eurjchem-2463	125	23	dimensional	dimensional	ADJ
eurjchem-2463	125	24	network	network	NOUN
eurjchem-2463	125	25	as	as	SCONJ
eurjchem-2463	125	26	shown	show	VERB
eurjchem-2463	125	27	in	in	ADP
eurjchem-2463	125	28	figure	figure	NOUN
eurjchem-2463	125	29	3	3	NUM
eurjchem-2463	125	30	.	.	PUNCT
eurjchem-2463	126	1	detailed	detailed	ADJ
eurjchem-2463	126	2	hydrogen	hydrogen	NOUN
eurjchem-2463	126	3	bond	bond	NOUN
eurjchem-2463	126	4	lengths	length	NOUN
eurjchem-2463	126	5	and	and	CCONJ
eurjchem-2463	126	6	angles	angle	NOUN
eurjchem-2463	126	7	found	find	VERB
eurjchem-2463	126	8	in	in	ADP
eurjchem-2463	126	9	complexes	complex	NOUN
eurjchem-2463	126	10	1	1	NUM
eurjchem-2463	126	11	and	and	CCONJ
eurjchem-2463	126	12	2	2	NUM
eurjchem-2463	126	13	are	be	AUX
eurjchem-2463	126	14	shown	show	VERB
eurjchem-2463	126	15	in	in	ADP
eurjchem-2463	126	16	table	table	NOUN
eurjchem-2463	126	17	2	2	NUM
eurjchem-2463	126	18	.	.	SYM
eurjchem-2463	126	19	314	314	NUM
eurjchem-2463	126	20	ruivo	ruivo	NOUN
eurjchem-2463	126	21	et	et	PROPN
eurjchem-2463	126	22	al	al	PROPN
eurjchem-2463	126	23	.	.	PUNCT
eurjchem-2463	126	24	/	/	SYM
eurjchem-2463	126	25	european	european	PROPN
eurjchem-2463	126	26	journal	journal	PROPN
eurjchem-2463	126	27	of	of	ADP
eurjchem-2463	126	28	chemistry	chemistry	NOUN
eurjchem-2463	126	29	14	14	NUM
eurjchem-2463	126	30	(	(	PUNCT
eurjchem-2463	126	31	3	3	NUM
eurjchem-2463	126	32	)	)	PUNCT
eurjchem-2463	126	33	(	(	PUNCT
eurjchem-2463	126	34	2023	2023	NUM
eurjchem-2463	126	35	)	)	PUNCT
eurjchem-2463	126	36	311	311	NUM
eurjchem-2463	126	37	-	-	SYM
eurjchem-2463	126	38	315	315	NUM
eurjchem-2463	126	39	2023	2023	NUM
eurjchem-2463	126	40	–	–	PUNCT
eurjchem-2463	126	41	european	european	ADJ
eurjchem-2463	126	42	journal	journal	NOUN
eurjchem-2463	126	43	of	of	ADP
eurjchem-2463	126	44	chemistry	chemistry	NOUN
eurjchem-2463	126	45	–	–	PUNCT
eurjchem-2463	126	46	cc	cc	NOUN
eurjchem-2463	126	47	by	by	ADP
eurjchem-2463	126	48	nc	nc	PROPN
eurjchem-2463	126	49	–	–	PUNCT
eurjchem-2463	126	50	doi	doi	NOUN
eurjchem-2463	126	51	:	:	PUNCT
eurjchem-2463	126	52	10.5155	10.5155	NUM
eurjchem-2463	126	53	/	/	SYM
eurjchem-2463	126	54	eurjchem.14.3.311	eurjchem.14.3.311	NOUN
eurjchem-2463	126	55	-	-	SYM
eurjchem-2463	126	56	315.2463	315.2463	NUM
eurjchem-2463	126	57	figure	figure	NOUN
eurjchem-2463	126	58	2	2	NUM
eurjchem-2463	126	59	.	.	PUNCT
eurjchem-2463	126	60	ortep	ortep	NOUN
eurjchem-2463	126	61	diagram	diagram	NOUN
eurjchem-2463	126	62	of	of	ADP
eurjchem-2463	126	63	2	2	NUM
eurjchem-2463	126	64	showing	show	VERB
eurjchem-2463	126	65	thermal	thermal	ADJ
eurjchem-2463	126	66	ellipsoids	ellipsoid	NOUN
eurjchem-2463	126	67	at	at	ADP
eurjchem-2463	126	68	30	30	NUM
eurjchem-2463	126	69	%	%	NOUN
eurjchem-2463	126	70	probability	probability	NOUN
eurjchem-2463	126	71	level	level	NOUN
eurjchem-2463	126	72	.	.	PUNCT
eurjchem-2463	127	1	selected	select	VERB
eurjchem-2463	127	2	hydrogen	hydrogen	NOUN
eurjchem-2463	127	3	atoms	atom	NOUN
eurjchem-2463	127	4	were	be	AUX
eurjchem-2463	127	5	omitted	omit	VERB
eurjchem-2463	127	6	for	for	ADP
eurjchem-2463	127	7	clarity	clarity	NOUN
eurjchem-2463	127	8	.	.	PUNCT
eurjchem-2463	128	1	dashed	dash	VERB
eurjchem-2463	128	2	lines	line	NOUN
eurjchem-2463	128	3	represent	represent	VERB
eurjchem-2463	128	4	hydrogen	hydrogen	NOUN
eurjchem-2463	128	5	bonds	bond	NOUN
eurjchem-2463	128	6	.	.	PUNCT
eurjchem-2463	129	1	selected	select	VERB
eurjchem-2463	129	2	bond	bond	NOUN
eurjchem-2463	129	3	lengths	length	NOUN
eurjchem-2463	129	4	(	(	PUNCT
eurjchem-2463	129	5	å	å	NOUN
eurjchem-2463	129	6	)	)	PUNCT
eurjchem-2463	129	7	and	and	CCONJ
eurjchem-2463	129	8	angles	angle	NOUN
eurjchem-2463	129	9	(	(	PUNCT
eurjchem-2463	129	10	°	°	PROPN
eurjchem-2463	129	11	):	):	PUNCT
eurjchem-2463	129	12	mo(1)-n(1	mo(1)-n(1	NOUN
eurjchem-2463	129	13	)	)	PUNCT
eurjchem-2463	129	14	2.173(8	2.173(8	NUM
eurjchem-2463	129	15	)	)	PUNCT
eurjchem-2463	129	16	,	,	PUNCT
eurjchem-2463	129	17	mo(1)-p(1	mo(1)-p(1	NOUN
eurjchem-2463	129	18	)	)	PUNCT
eurjchem-2463	129	19	2.556(4	2.556(4	NUM
eurjchem-2463	129	20	)	)	PUNCT
eurjchem-2463	129	21	,	,	PUNCT
eurjchem-2463	129	22	mo(1)-p(2	mo(1)-p(2	NOUN
eurjchem-2463	129	23	)	)	PUNCT
eurjchem-2463	129	24	2.489(4	2.489(4	NUM
eurjchem-2463	129	25	)	)	PUNCT
eurjchem-2463	129	26	,	,	PUNCT
eurjchem-2463	129	27	mo(1)-cl(1	mo(1)-cl(1	X
eurjchem-2463	129	28	)	)	PUNCT
eurjchem-2463	129	29	2.232(5	2.232(5	NUM
eurjchem-2463	129	30	)	)	PUNCT
eurjchem-2463	129	31	,	,	PUNCT
eurjchem-2463	129	32	mo(1)-cl(2	mo(1)-cl(2	NOUN
eurjchem-2463	129	33	)	)	PUNCT
eurjchem-2463	129	34	2.421(3	2.421(3	NUM
eurjchem-2463	129	35	)	)	PUNCT
eurjchem-2463	129	36	,	,	PUNCT
eurjchem-2463	129	37	mo(1)-cl(3	mo(1)-cl(3	NOUN
eurjchem-2463	129	38	)	)	PUNCT
eurjchem-2463	129	39	2.474(3	2.474(3	NUM
eurjchem-2463	129	40	)	)	PUNCT
eurjchem-2463	129	41	;	;	PUNCT
eurjchem-2463	129	42	p(1)-mo(1)-n(1	p(1)-mo(1)-n(1	X
eurjchem-2463	129	43	)	)	PUNCT
eurjchem-2463	129	44	77.8(3	77.8(3	NOUN
eurjchem-2463	129	45	)	)	PUNCT
eurjchem-2463	129	46	,	,	PUNCT
eurjchem-2463	129	47	p(2)-mo(1)-n(1	p(2)-mo(1)-n(1	NOUN
eurjchem-2463	129	48	)	)	PUNCT
eurjchem-2463	129	49	78.7(3	78.7(3	NUM
eurjchem-2463	129	50	)	)	PUNCT
eurjchem-2463	129	51	,	,	PUNCT
eurjchem-2463	129	52	p(1)-mo(1)-cl(2	p(1)-mo(1)-cl(2	NOUN
eurjchem-2463	129	53	)	)	PUNCT
eurjchem-2463	129	54	103.1(1	103.1(1	NUM
eurjchem-2463	129	55	)	)	PUNCT
eurjchem-2463	129	56	,	,	PUNCT
eurjchem-2463	129	57	p(2)-mo(1)-cl(2	p(2)-mo(1)-cl(2	NOUN
eurjchem-2463	129	58	)	)	PUNCT
eurjchem-2463	129	59	100.1(1	100.1(1	NUM
eurjchem-2463	129	60	)	)	PUNCT
eurjchem-2463	129	61	,	,	PUNCT
eurjchem-2463	129	62	p(1)-mo(1)-p(2	p(1)-mo(1)-p(2	NOUN
eurjchem-2463	129	63	)	)	PUNCT
eurjchem-2463	129	64	156.1(1	156.1(1	NUM
eurjchem-2463	129	65	)	)	PUNCT
eurjchem-2463	129	66	,	,	PUNCT
eurjchem-2463	129	67	n(1)-mo(1)-cl(2	n(1)-mo(1)-cl(2	NUM
eurjchem-2463	129	68	)	)	PUNCT
eurjchem-2463	129	69	176.3(2	176.3(2	NUM
eurjchem-2463	129	70	)	)	PUNCT
eurjchem-2463	129	71	,	,	PUNCT
eurjchem-2463	129	72	cl(1)-mo(1)-cl(3	cl(1)-mo(1)-cl(3	PROPN
eurjchem-2463	129	73	)	)	PUNCT
eurjchem-2463	129	74	176.7(2	176.7(2	NUM
eurjchem-2463	129	75	)	)	PUNCT
eurjchem-2463	129	76	.	.	PUNCT
eurjchem-2463	130	1	figure	figure	VERB
eurjchem-2463	131	1	3	3	NUM
eurjchem-2463	131	2	.	.	PUNCT
eurjchem-2463	132	1	polyhedral	polyhedral	ADJ
eurjchem-2463	132	2	view	view	NOUN
eurjchem-2463	132	3	of	of	ADP
eurjchem-2463	132	4	the	the	DET
eurjchem-2463	132	5	crystal	crystal	NOUN
eurjchem-2463	132	6	structure	structure	NOUN
eurjchem-2463	132	7	of	of	ADP
eurjchem-2463	132	8	2	2	NUM
eurjchem-2463	132	9	along	along	ADP
eurjchem-2463	132	10	the	the	DET
eurjchem-2463	132	11	b	b	NOUN
eurjchem-2463	132	12	-	-	PUNCT
eurjchem-2463	132	13	axis	axis	NOUN
eurjchem-2463	132	14	showing	showing	NOUN
eurjchem-2463	132	15	chains	chain	NOUN
eurjchem-2463	132	16	growing	grow	VERB
eurjchem-2463	132	17	in	in	ADP
eurjchem-2463	132	18	the	the	DET
eurjchem-2463	132	19	a	a	DET
eurjchem-2463	132	20	direction	direction	NOUN
eurjchem-2463	132	21	.	.	PUNCT
eurjchem-2463	133	1	dashed	dash	VERB
eurjchem-2463	133	2	blue	blue	ADJ
eurjchem-2463	133	3	lines	line	NOUN
eurjchem-2463	133	4	represent	represent	VERB
eurjchem-2463	133	5	hydrogen	hydrogen	NOUN
eurjchem-2463	133	6	bonds	bond	NOUN
eurjchem-2463	133	7	.	.	PUNCT
eurjchem-2463	134	1	4	4	X
eurjchem-2463	134	2	.	.	X
eurjchem-2463	134	3	conclusions	conclusion	NOUN
eurjchem-2463	135	1	[	[	X
eurjchem-2463	135	2	(	(	PUNCT
eurjchem-2463	135	3	pnp	pnp	PROPN
eurjchem-2463	135	4	-	-	PUNCT
eurjchem-2463	135	5	ph)ticl3	ph)ticl3	PROPN
eurjchem-2463	135	6	]	]	PUNCT
eurjchem-2463	135	7	and	and	CCONJ
eurjchem-2463	135	8	[	[	X
eurjchem-2463	135	9	(	(	PUNCT
eurjchem-2463	135	10	pnp	pnp	PROPN
eurjchem-2463	135	11	-	-	PUNCT
eurjchem-2463	135	12	ipr)mocl3	ipr)mocl3	PROPN
eurjchem-2463	135	13	]	]	X
eurjchem-2463	135	14	(	(	PUNCT
eurjchem-2463	135	15	pnp	pnp	NOUN
eurjchem-2463	135	16	-	-	PUNCT
eurjchem-2463	135	17	ph	ph	ADJ
eurjchem-2463	135	18	=	=	PUNCT
eurjchem-2463	135	19	n	n	CCONJ
eurjchem-2463	135	20	,	,	PUNCT
eurjchem-2463	135	21	n’bis(diphenylphosphino)-2,6	n’bis(diphenylphosphino)-2,6	PROPN
eurjchem-2463	135	22	-	-	PUNCT
eurjchem-2463	135	23	diaminopyridine	diaminopyridine	PROPN
eurjchem-2463	135	24	and	and	CCONJ
eurjchem-2463	135	25	pnp	pnp	PROPN
eurjchem-2463	135	26	-	-	PUNCT
eurjchem-2463	135	27	ipr	ipr	PROPN
eurjchem-2463	135	28	=	=	PUNCT
eurjchem-2463	135	29	n	n	CCONJ
eurjchem-2463	135	30	,	,	PUNCT
eurjchem-2463	135	31	n’-bis(diisopropylphosphino)-2,6	n’-bis(diisopropylphosphino)-2,6	NOUN
eurjchem-2463	135	32	-	-	NOUN
eurjchem-2463	135	33	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	135	34	)	)	PUNCT
eurjchem-2463	135	35	were	be	AUX
eurjchem-2463	135	36	synthesized	synthesize	VERB
eurjchem-2463	135	37	and	and	CCONJ
eurjchem-2463	135	38	characterized	characterize	VERB
eurjchem-2463	135	39	.	.	PUNCT
eurjchem-2463	136	1	the	the	DET
eurjchem-2463	136	2	solid	solid	ADJ
eurjchem-2463	136	3	-	-	PUNCT
eurjchem-2463	136	4	state	state	NOUN
eurjchem-2463	136	5	molecular	molecular	ADJ
eurjchem-2463	136	6	structures	structure	NOUN
eurjchem-2463	136	7	of	of	ADP
eurjchem-2463	136	8	both	both	DET
eurjchem-2463	136	9	complexes	complex	NOUN
eurjchem-2463	136	10	were	be	AUX
eurjchem-2463	136	11	determined	determine	VERB
eurjchem-2463	136	12	by	by	ADP
eurjchem-2463	136	13	single	single	ADJ
eurjchem-2463	136	14	-	-	PUNCT
eurjchem-2463	136	15	crystal	crystal	NOUN
eurjchem-2463	136	16	x	x	ADJ
eurjchem-2463	136	17	-	-	NOUN
eurjchem-2463	136	18	ray	ray	NOUN
eurjchem-2463	136	19	diffraction	diffraction	NOUN
eurjchem-2463	136	20	and	and	CCONJ
eurjchem-2463	136	21	reveal	reveal	VERB
eurjchem-2463	136	22	distorted	distort	VERB
eurjchem-2463	136	23	octahedral	octahedral	ADJ
eurjchem-2463	136	24	geometries	geometry	NOUN
eurjchem-2463	136	25	.	.	PUNCT
eurjchem-2463	137	1	the	the	DET
eurjchem-2463	137	2	equatorial	equatorial	ADJ
eurjchem-2463	137	3	planes	plane	NOUN
eurjchem-2463	137	4	of	of	ADP
eurjchem-2463	137	5	the	the	DET
eurjchem-2463	137	6	octahedra	octahedron	NOUN
eurjchem-2463	137	7	are	be	AUX
eurjchem-2463	137	8	occupied	occupy	VERB
eurjchem-2463	137	9	by	by	ADP
eurjchem-2463	137	10	the	the	DET
eurjchem-2463	137	11	three	three	NUM
eurjchem-2463	137	12	donor	donor	NOUN
eurjchem-2463	137	13	atoms	atom	NOUN
eurjchem-2463	137	14	of	of	ADP
eurjchem-2463	137	15	the	the	DET
eurjchem-2463	137	16	pnp	pnp	PROPN
eurjchem-2463	137	17	ligands	ligand	NOUN
eurjchem-2463	137	18	and	and	CCONJ
eurjchem-2463	137	19	one	one	NUM
eurjchem-2463	137	20	chlorine	chlorine	NOUN
eurjchem-2463	137	21	atom	atom	NOUN
eurjchem-2463	137	22	.	.	PUNCT
eurjchem-2463	138	1	the	the	DET
eurjchem-2463	138	2	axial	axial	ADJ
eurjchem-2463	138	3	positions	position	NOUN
eurjchem-2463	138	4	are	be	AUX
eurjchem-2463	138	5	occupied	occupy	VERB
eurjchem-2463	138	6	by	by	ADP
eurjchem-2463	138	7	the	the	DET
eurjchem-2463	138	8	other	other	ADJ
eurjchem-2463	138	9	two	two	NUM
eurjchem-2463	138	10	chlorido	chlorido	NOUN
eurjchem-2463	138	11	ligands	ligand	NOUN
eurjchem-2463	138	12	.	.	PUNCT
eurjchem-2463	139	1	the	the	DET
eurjchem-2463	139	2	presence	presence	NOUN
eurjchem-2463	139	3	of	of	ADP
eurjchem-2463	139	4	nh	nh	PROPN
eurjchem-2463	139	5	amino	amino	NOUN
eurjchem-2463	139	6	spacer	spacer	NOUN
eurjchem-2463	139	7	groups	group	NOUN
eurjchem-2463	139	8	in	in	ADP
eurjchem-2463	139	9	pnp	pnp	PROPN
eurjchem-2463	139	10	ligands	ligand	NOUN
eurjchem-2463	139	11	plays	play	VERB
eurjchem-2463	139	12	an	an	DET
eurjchem-2463	139	13	important	important	ADJ
eurjchem-2463	139	14	role	role	NOUN
eurjchem-2463	139	15	in	in	ADP
eurjchem-2463	139	16	the	the	DET
eurjchem-2463	139	17	establishment	establishment	NOUN
eurjchem-2463	139	18	of	of	ADP
eurjchem-2463	139	19	hydrogen	hydrogen	NOUN
eurjchem-2463	139	20	bonds	bond	NOUN
eurjchem-2463	139	21	between	between	ADP
eurjchem-2463	139	22	the	the	DET
eurjchem-2463	139	23	complexes	complex	NOUN
eurjchem-2463	139	24	and	and	CCONJ
eurjchem-2463	139	25	the	the	DET
eurjchem-2463	139	26	molecules	molecule	NOUN
eurjchem-2463	139	27	of	of	ADP
eurjchem-2463	139	28	the	the	DET
eurjchem-2463	139	29	solvent	solvent	NOUN
eurjchem-2463	139	30	or	or	CCONJ
eurjchem-2463	139	31	neighboring	neighboring	NOUN
eurjchem-2463	139	32	species	specie	NOUN
eurjchem-2463	139	33	.	.	PUNCT
eurjchem-2463	140	1	such	such	ADJ
eurjchem-2463	140	2	interactions	interaction	NOUN
eurjchem-2463	140	3	are	be	AUX
eurjchem-2463	140	4	also	also	ADV
eurjchem-2463	140	5	responsible	responsible	ADJ
eurjchem-2463	140	6	for	for	ADP
eurjchem-2463	140	7	the	the	DET
eurjchem-2463	140	8	supramolecular	supramolecular	ADJ
eurjchem-2463	140	9	assembly	assembly	NOUN
eurjchem-2463	140	10	of	of	ADP
eurjchem-2463	140	11	[	[	X
eurjchem-2463	140	12	(	(	PUNCT
eurjchem-2463	140	13	pnp	pnp	PROPN
eurjchem-2463	140	14	-	-	PUNCT
eurjchem-2463	140	15	ipr)mocl3	ipr)mocl3	PROPN
eurjchem-2463	140	16	]	]	PUNCT
eurjchem-2463	140	17	that	that	PRON
eurjchem-2463	140	18	reveals	reveal	VERB
eurjchem-2463	140	19	a	a	DET
eurjchem-2463	140	20	three	three	NUM
eurjchem-2463	140	21	-	-	PUNCT
eurjchem-2463	140	22	dimensional	dimensional	ADJ
eurjchem-2463	140	23	network	network	NOUN
eurjchem-2463	140	24	defined	define	VERB
eurjchem-2463	140	25	by	by	ADP
eurjchem-2463	140	26	helicoidal	helicoidal	ADJ
eurjchem-2463	140	27	chains	chain	NOUN
eurjchem-2463	140	28	growing	grow	VERB
eurjchem-2463	140	29	in	in	ADP
eurjchem-2463	140	30	the	the	DET
eurjchem-2463	140	31	a	a	DET
eurjchem-2463	140	32	direction	direction	NOUN
eurjchem-2463	140	33	.	.	PUNCT
eurjchem-2463	141	1	to	to	ADP
eurjchem-2463	141	2	our	our	PRON
eurjchem-2463	141	3	knowledge	knowledge	NOUN
eurjchem-2463	141	4	,	,	PUNCT
eurjchem-2463	141	5	[	[	X
eurjchem-2463	141	6	(	(	PUNCT
eurjchem-2463	141	7	pnp	pnp	PROPN
eurjchem-2463	141	8	-	-	PUNCT
eurjchem-2463	141	9	ph)ticl3	ph)ticl3	PROPN
eurjchem-2463	141	10	]	]	PUNCT
eurjchem-2463	141	11	is	be	AUX
eurjchem-2463	141	12	the	the	DET
eurjchem-2463	141	13	first	first	ADJ
eurjchem-2463	141	14	titanium	titanium	NOUN
eurjchem-2463	141	15	complex	complex	NOUN
eurjchem-2463	141	16	supported	support	VERB
eurjchem-2463	141	17	by	by	ADP
eurjchem-2463	141	18	a	a	DET
eurjchem-2463	141	19	pnp	pnp	PROPN
eurjchem-2463	141	20	pincer	pincer	PROPN
eurjchem-2463	141	21	ligand	ligand	PROPN
eurjchem-2463	141	22	based	base	VERB
eurjchem-2463	141	23	on	on	ADP
eurjchem-2463	141	24	2,6	2,6	NUM
eurjchem-2463	141	25	-	-	NOUN
eurjchem-2463	141	26	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	141	27	to	to	PART
eurjchem-2463	141	28	be	be	AUX
eurjchem-2463	141	29	described	describe	VERB
eurjchem-2463	141	30	.	.	PUNCT
eurjchem-2463	142	1	acknowledgements	acknowledgement	NOUN
eurjchem-2463	142	2	the	the	DET
eurjchem-2463	142	3	authors	author	NOUN
eurjchem-2463	142	4	are	be	AUX
eurjchem-2463	142	5	grateful	grateful	ADJ
eurjchem-2463	142	6	to	to	PART
eurjchem-2463	142	7	fundação	fundação	VERB
eurjchem-2463	142	8	para	para	VERB
eurjchem-2463	142	9	a	a	DET
eurjchem-2463	142	10	ciência	ciência	PROPN
eurjchem-2463	142	11	e	e	ADP
eurjchem-2463	142	12	a	a	DET
eurjchem-2463	142	13	tecnologia	tecnologia	NOUN
eurjchem-2463	142	14	,	,	PUNCT
eurjchem-2463	142	15	portugal	portugal	PROPN
eurjchem-2463	142	16	,	,	PUNCT
eurjchem-2463	142	17	for	for	ADP
eurjchem-2463	142	18	funding	funding	NOUN
eurjchem-2463	142	19	(	(	PUNCT
eurjchem-2463	142	20	uid	uid	PROPN
eurjchem-2463	142	21	/	/	SYM
eurjchem-2463	142	22	qui/00100/2019	qui/00100/2019	NOUN
eurjchem-2463	142	23	,	,	PUNCT
eurjchem-2463	142	24	uidb/00100/2020	uidb/00100/2020	NOUN
eurjchem-2463	142	25	,	,	PUNCT
eurjchem-2463	142	26	uidp/00100/2020	uidp/00100/2020	NOUN
eurjchem-2463	142	27	,	,	PUNCT
eurjchem-2463	142	28	la	la	PROPN
eurjchem-2463	142	29	/	/	SYM
eurjchem-2463	142	30	p/0056/2020	p/0056/2020	PROPN
eurjchem-2463	142	31	and	and	CCONJ
eurjchem-2463	142	32	catsus	catsus	PROPN
eurjchem-2463	142	33	pd	pd	PROPN
eurjchem-2463	142	34	/	/	SYM
eurjchem-2463	142	35	bd/135533/2018	bd/135533/2018	NOUN
eurjchem-2463	142	36	.	.	PUNCT
eurjchem-2463	143	1	supporting	support	VERB
eurjchem-2463	143	2	information	information	NOUN
eurjchem-2463	143	3	ccdc-2224820	ccdc-2224820	NOUN
eurjchem-2463	143	4	and	and	CCONJ
eurjchem-2463	143	5	2224821	2224821	NUM
eurjchem-2463	143	6	contain	contain	VERB
eurjchem-2463	143	7	the	the	DET
eurjchem-2463	143	8	supplementary	supplementary	ADJ
eurjchem-2463	143	9	crystallographic	crystallographic	ADJ
eurjchem-2463	143	10	data	datum	NOUN
eurjchem-2463	143	11	for	for	ADP
eurjchem-2463	143	12	this	this	DET
eurjchem-2463	143	13	paper	paper	NOUN
eurjchem-2463	143	14	.	.	PUNCT
eurjchem-2463	144	1	these	these	DET
eurjchem-2463	144	2	data	datum	NOUN
eurjchem-2463	144	3	can	can	AUX
eurjchem-2463	144	4	be	be	AUX
eurjchem-2463	144	5	obtained	obtain	VERB
eurjchem-2463	144	6	free	free	ADJ
eurjchem-2463	144	7	of	of	ADP
eurjchem-2463	144	8	charge	charge	NOUN
eurjchem-2463	144	9	via	via	ADP
eurjchem-2463	144	10	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	PROPN
eurjchem-2463	144	11	,	,	PUNCT
eurjchem-2463	144	12	or	or	CCONJ
eurjchem-2463	144	13	by	by	ADP
eurjchem-2463	144	14	e	e	NOUN
eurjchem-2463	144	15	-	-	ADJ
eurjchem-2463	144	16	mailing	mailing	ADJ
eurjchem-2463	144	17	data_request@	data_request@	ADJ
eurjchem-2463	144	18	ccdc.cam.ac.uk	ccdc.cam.ac.uk	ADJ
eurjchem-2463	144	19	,	,	PUNCT
eurjchem-2463	144	20	or	or	CCONJ
eurjchem-2463	144	21	by	by	ADP
eurjchem-2463	144	22	contacting	contact	VERB
eurjchem-2463	144	23	the	the	DET
eurjchem-2463	144	24	cambridge	cambridge	PROPN
eurjchem-2463	144	25	crystallographic	crystallographic	PROPN
eurjchem-2463	144	26	data	data	PROPN
eurjchem-2463	144	27	centre	centre	NOUN
eurjchem-2463	144	28	,	,	PUNCT
eurjchem-2463	144	29	12	12	NUM
eurjchem-2463	144	30	union	union	NOUN
eurjchem-2463	144	31	road	road	NOUN
eurjchem-2463	144	32	,	,	PUNCT
eurjchem-2463	144	33	cambridge	cambridge	PROPN
eurjchem-2463	144	34	cb2	cb2	PROPN
eurjchem-2463	144	35	1ez	1ez	PROPN
eurjchem-2463	144	36	,	,	PUNCT
eurjchem-2463	144	37	uk	uk	PROPN
eurjchem-2463	144	38	;	;	PUNCT
eurjchem-2463	144	39	fax	fax	NOUN
eurjchem-2463	144	40	:	:	PUNCT
eurjchem-2463	144	41	+44(0)1223	+44(0)1223	PROPN
eurjchem-2463	144	42	-	-	PUNCT
eurjchem-2463	144	43	336033	336033	NUM
eurjchem-2463	144	44	.	.	PUNCT
eurjchem-2463	145	1	disclosure	disclosure	NOUN
eurjchem-2463	145	2	statement	statement	NOUN
eurjchem-2463	145	3	conflict	conflict	NOUN
eurjchem-2463	145	4	of	of	ADP
eurjchem-2463	145	5	interest	interest	NOUN
eurjchem-2463	145	6	:	:	PUNCT
eurjchem-2463	145	7	the	the	DET
eurjchem-2463	145	8	authors	author	NOUN
eurjchem-2463	145	9	declare	declare	VERB
eurjchem-2463	145	10	that	that	SCONJ
eurjchem-2463	145	11	they	they	PRON
eurjchem-2463	145	12	have	have	VERB
eurjchem-2463	145	13	no	no	DET
eurjchem-2463	145	14	conflict	conflict	NOUN
eurjchem-2463	145	15	of	of	ADP
eurjchem-2463	145	16	interest	interest	NOUN
eurjchem-2463	145	17	.	.	PUNCT
eurjchem-2463	146	1	ethical	ethical	ADJ
eurjchem-2463	146	2	approval	approval	NOUN
eurjchem-2463	146	3	:	:	PUNCT
eurjchem-2463	147	1	all	all	DET
eurjchem-2463	147	2	ethical	ethical	ADJ
eurjchem-2463	147	3	guidelines	guideline	NOUN
eurjchem-2463	147	4	have	have	AUX
eurjchem-2463	147	5	been	be	AUX
eurjchem-2463	147	6	adhered	adhere	VERB
eurjchem-2463	147	7	to	to	ADP
eurjchem-2463	147	8	.	.	PUNCT
eurjchem-2463	148	1	sample	sample	NOUN
eurjchem-2463	148	2	availability	availability	NOUN
eurjchem-2463	148	3	:	:	PUNCT
eurjchem-2463	148	4	samples	sample	NOUN
eurjchem-2463	148	5	of	of	ADP
eurjchem-2463	148	6	the	the	DET
eurjchem-2463	148	7	compounds	compound	NOUN
eurjchem-2463	148	8	are	be	AUX
eurjchem-2463	148	9	available	available	ADJ
eurjchem-2463	148	10	from	from	ADP
eurjchem-2463	148	11	the	the	DET
eurjchem-2463	148	12	author	author	NOUN
eurjchem-2463	148	13	.	.	PUNCT
eurjchem-2463	149	1	credit	credit	NOUN
eurjchem-2463	149	2	authorship	authorship	NOUN
eurjchem-2463	149	3	contribution	contribution	NOUN
eurjchem-2463	149	4	statement	statement	NOUN
eurjchem-2463	149	5	conceptualization	conceptualization	NOUN
eurjchem-2463	149	6	:	:	PUNCT
eurjchem-2463	149	7	ana	ana	PROPN
eurjchem-2463	149	8	martins	martins	PROPN
eurjchem-2463	149	9	;	;	PUNCT
eurjchem-2463	149	10	investigation	investigation	NOUN
eurjchem-2463	149	11	:	:	PUNCT
eurjchem-2463	149	12	rita	rita	PROPN
eurjchem-2463	149	13	ruivo	ruivo	PROPN
eurjchem-2463	149	14	,	,	PUNCT
eurjchem-2463	149	15	luis	luis	PROPN
eurjchem-2463	149	16	alves	alves	PROPN
eurjchem-2463	149	17	;	;	PUNCT
eurjchem-2463	149	18	writing	write	VERB
eurjchem-2463	149	19	original	original	ADJ
eurjchem-2463	149	20	draft	draft	NOUN
eurjchem-2463	149	21	:	:	PUNCT
eurjchem-2463	149	22	luis	luis	PROPN
eurjchem-2463	149	23	alves	alves	PROPN
eurjchem-2463	149	24	;	;	PUNCT
eurjchem-2463	149	25	writing	write	VERB
eurjchem-2463	149	26	review	review	NOUN
eurjchem-2463	149	27	and	and	CCONJ
eurjchem-2463	149	28	editing	editing	NOUN
eurjchem-2463	149	29	:	:	PUNCT
eurjchem-2463	149	30	luis	luis	PROPN
eurjchem-2463	149	31	alves	alves	PROPN
eurjchem-2463	149	32	,	,	PUNCT
eurjchem-2463	149	33	ana	ana	PROPN
eurjchem-2463	149	34	martins	martin	NOUN
eurjchem-2463	149	35	;	;	PUNCT
eurjchem-2463	149	36	supervision	supervision	NOUN
eurjchem-2463	149	37	:	:	PUNCT
eurjchem-2463	149	38	ana	ana	PROPN
eurjchem-2463	149	39	martins	martins	PROPN
eurjchem-2463	149	40	;	;	PUNCT
eurjchem-2463	149	41	project	project	NOUN
eurjchem-2463	149	42	administration	administration	NOUN
eurjchem-2463	149	43	:	:	PUNCT
eurjchem-2463	149	44	ana	ana	PROPN
eurjchem-2463	149	45	martins	martins	PROPN
eurjchem-2463	149	46	.	.	PUNCT
eurjchem-2463	150	1	funding	fund	VERB
eurjchem-2463	150	2	fundação	fundação	NOUN
eurjchem-2463	150	3	para	para	NOUN
eurjchem-2463	150	4	a	a	DET
eurjchem-2463	150	5	ciência	ciência	PROPN
eurjchem-2463	150	6	e	e	ADP
eurjchem-2463	150	7	a	a	DET
eurjchem-2463	150	8	tecnologia	tecnologia	NOUN
eurjchem-2463	150	9	,	,	PUNCT
eurjchem-2463	150	10	portugal	portugal	PROPN
eurjchem-2463	150	11	https://dx.doi.org/10.13039/501100001871	https://dx.doi.org/10.13039/501100001871	PROPN
eurjchem-2463	150	12	orcid	orcid	PROPN
eurjchem-2463	150	13	and	and	CCONJ
eurjchem-2463	150	14	email	email	NOUN
eurjchem-2463	150	15	rita	rita	PROPN
eurjchem-2463	151	1	ruivo	ruivo	PROPN
eurjchem-2463	151	2	rita.alvarez.ruivo@tecnico.ulisboa.pt	rita.alvarez.ruivo@tecnico.ulisboa.pt	PROPN
eurjchem-2463	151	3	https://orcid.org/0000-0002-4223-0651	https://orcid.org/0000-0002-4223-0651	PROPN
eurjchem-2463	151	4	luis	luis	PROPN
eurjchem-2463	151	5	alves	alves	PROPN
eurjchem-2463	151	6	luis.g.alves@tecnico.ulisboa.pt	luis.g.alves@tecnico.ulisboa.pt	PROPN
eurjchem-2463	152	1	https://orcid.org/0000-0002-7938-9850	https://orcid.org/0000-0002-7938-9850	NOUN
eurjchem-2463	152	2	ana	ana	PROPN
eurjchem-2463	152	3	martins	martin	VERB
eurjchem-2463	152	4	ana.martins@tecnico.ulisboa.pt	ana.martins@tecnico.ulisboa.pt	ADV
eurjchem-2463	152	5	https://orcid.org/0000-0002-3922-5501	https://orcid.org/0000-0002-3922-5501	VERB
eurjchem-2463	152	6	https://www.ccdc.cam.ac.uk/structures/	https://www.ccdc.cam.ac.uk/structures/	ADJ
eurjchem-2463	152	7	mailto:data_request@ccdc.cam.ac.uk	mailto:data_request@ccdc.cam.ac.uk	NOUN
eurjchem-2463	152	8	mailto:data_request@ccdc.cam.ac.uk	mailto:data_request@ccdc.cam.ac.uk	VERB
eurjchem-2463	152	9	https://dx.doi.org/10.13039/501100001871	https://dx.doi.org/10.13039/501100001871	NOUN
eurjchem-2463	152	10	mailto:rita.alvarez.ruivo@tecnico.ulisboa.pt	mailto:rita.alvarez.ruivo@tecnico.ulisboa.pt	X
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eurjchem-2463	152	12	mailto:luis.g.alves@tecnico.ulisboa.pt	mailto:luis.g.alves@tecnico.ulisboa.pt	NOUN
eurjchem-2463	152	13	https://orcid.org/0000-0002-7938-9850	https://orcid.org/0000-0002-7938-9850	NOUN
eurjchem-2463	152	14	mailto:ana.martins@tecnico.ulisboa.pt	mailto:ana.martins@tecnico.ulisboa.pt	NOUN
eurjchem-2463	152	15	https://orcid.org/0000-0002-3922-5501	https://orcid.org/0000-0002-3922-5501	PROPN
eurjchem-2463	152	16	ruivo	ruivo	PROPN
eurjchem-2463	152	17	et	et	PROPN
eurjchem-2463	152	18	al	al	PROPN
eurjchem-2463	152	19	.	.	PUNCT
eurjchem-2463	152	20	/	/	SYM
eurjchem-2463	152	21	european	european	PROPN
eurjchem-2463	152	22	journal	journal	PROPN
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eurjchem-2463	152	26	(	(	PUNCT
eurjchem-2463	152	27	3	3	NUM
eurjchem-2463	152	28	)	)	PUNCT
eurjchem-2463	152	29	(	(	PUNCT
eurjchem-2463	152	30	2023	2023	NUM
eurjchem-2463	152	31	)	)	PUNCT
eurjchem-2463	152	32	311	311	NUM
eurjchem-2463	152	33	-	-	SYM
eurjchem-2463	152	34	315	315	NUM
eurjchem-2463	152	35	315	315	NUM
eurjchem-2463	152	36	2023	2023	NUM
eurjchem-2463	152	37	–	–	PUNCT
eurjchem-2463	152	38	european	european	ADJ
eurjchem-2463	152	39	journal	journal	NOUN
eurjchem-2463	152	40	of	of	ADP
eurjchem-2463	152	41	chemistry	chemistry	NOUN
eurjchem-2463	152	42	–	–	PUNCT
eurjchem-2463	152	43	cc	cc	NOUN
eurjchem-2463	152	44	by	by	ADP
eurjchem-2463	152	45	nc	nc	PROPN
eurjchem-2463	152	46	–	–	PUNCT
eurjchem-2463	152	47	doi	doi	NOUN
eurjchem-2463	152	48	:	:	PUNCT
eurjchem-2463	152	49	10.5155	10.5155	NUM
eurjchem-2463	152	50	/	/	SYM
eurjchem-2463	152	51	eurjchem.14.3.311	eurjchem.14.3.311	NUM
eurjchem-2463	152	52	-	-	SYM
eurjchem-2463	152	53	315.2463	315.2463	NUM
eurjchem-2463	152	54	references	reference	NOUN
eurjchem-2463	152	55	[	[	X
eurjchem-2463	152	56	1	1	NUM
eurjchem-2463	152	57	]	]	PUNCT
eurjchem-2463	152	58	.	.	PUNCT
eurjchem-2463	153	1	peris	peris	PROPN
eurjchem-2463	153	2	,	,	PUNCT
eurjchem-2463	153	3	e.	e.	PROPN
eurjchem-2463	153	4	;	;	PUNCT
eurjchem-2463	153	5	crabtree	crabtree	PROPN
eurjchem-2463	153	6	,	,	PUNCT
eurjchem-2463	153	7	r.	r.	PROPN
eurjchem-2463	153	8	h.	h.	PROPN
eurjchem-2463	153	9	key	key	ADJ
eurjchem-2463	153	10	factors	factor	NOUN
eurjchem-2463	153	11	in	in	ADP
eurjchem-2463	153	12	pincer	pincer	PROPN
eurjchem-2463	153	13	ligand	ligand	PROPN
eurjchem-2463	153	14	design	design	PROPN
eurjchem-2463	153	15	.	.	PUNCT
eurjchem-2463	154	1	chem	chem	NOUN
eurjchem-2463	154	2	.	.	PUNCT
eurjchem-2463	155	1	soc	soc	PROPN
eurjchem-2463	155	2	.	.	PUNCT
eurjchem-2463	156	1	rev	rev	PROPN
eurjchem-2463	156	2	.	.	PROPN
eurjchem-2463	156	3	2018	2018	NUM
eurjchem-2463	156	4	,	,	PUNCT
eurjchem-2463	156	5	47	47	NUM
eurjchem-2463	156	6	,	,	PUNCT
eurjchem-2463	156	7	1959–1968	1959–1968	NUM
eurjchem-2463	156	8	.	.	PUNCT
eurjchem-2463	157	1	[	[	X
eurjchem-2463	157	2	2	2	NUM
eurjchem-2463	157	3	]	]	PUNCT
eurjchem-2463	157	4	.	.	PUNCT
eurjchem-2463	158	1	lawrence	lawrence	PROPN
eurjchem-2463	158	2	,	,	PUNCT
eurjchem-2463	158	3	m.	m.	PROPN
eurjchem-2463	158	4	a.	a.	PROPN
eurjchem-2463	158	5	w.	w.	PROPN
eurjchem-2463	158	6	;	;	PUNCT
eurjchem-2463	158	7	green	green	ADJ
eurjchem-2463	158	8	,	,	PUNCT
eurjchem-2463	158	9	k.-a	k.-a	PROPN
eurjchem-2463	158	10	.	.	PUNCT
eurjchem-2463	158	11	;	;	PUNCT
eurjchem-2463	158	12	nelson	nelson	PROPN
eurjchem-2463	158	13	,	,	PUNCT
eurjchem-2463	158	14	p.	p.	PROPN
eurjchem-2463	158	15	n.	n.	NOUN
eurjchem-2463	158	16	;	;	PUNCT
eurjchem-2463	158	17	lorraine	lorraine	PROPN
eurjchem-2463	158	18	,	,	PUNCT
eurjchem-2463	158	19	s.	s.	PROPN
eurjchem-2463	158	20	c.	c.	PROPN
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eurjchem-2463	158	22	:	:	PUNCT
eurjchem-2463	158	23	pincer	pincer	NOUN
eurjchem-2463	158	24	ligands	ligand	NOUN
eurjchem-2463	158	25	—	—	PUNCT
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eurjchem-2463	158	27	,	,	PUNCT
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eurjchem-2463	158	29	and	and	CCONJ
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eurjchem-2463	158	31	.	.	PUNCT
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eurjchem-2463	159	2	2018	2018	NUM
eurjchem-2463	159	3	,	,	PUNCT
eurjchem-2463	159	4	143	143	NUM
eurjchem-2463	159	5	,	,	PUNCT
eurjchem-2463	159	6	11–27	11–27	NUM
eurjchem-2463	159	7	.	.	PUNCT
eurjchem-2463	160	1	[	[	X
eurjchem-2463	160	2	3	3	NUM
eurjchem-2463	160	3	]	]	PUNCT
eurjchem-2463	160	4	.	.	PUNCT
eurjchem-2463	161	1	van	van	PROPN
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eurjchem-2463	161	3	,	,	PUNCT
eurjchem-2463	161	4	g.	g.	PROPN
eurjchem-2463	161	5	;	;	PUNCT
eurjchem-2463	161	6	milstein	milstein	PROPN
eurjchem-2463	161	7	,	,	PUNCT
eurjchem-2463	161	8	d.	d.	PROPN
eurjchem-2463	161	9	organometallic	organometallic	PROPN
eurjchem-2463	161	10	pincer	pincer	NOUN
eurjchem-2463	161	11	chemistry	chemistry	NOUN
eurjchem-2463	161	12	;	;	PUNCT
eurjchem-2463	161	13	springer	springer	NOUN
eurjchem-2463	161	14	:	:	PUNCT
eurjchem-2463	161	15	berlin	berlin	PROPN
eurjchem-2463	161	16	,	,	PUNCT
eurjchem-2463	161	17	germany	germany	PROPN
eurjchem-2463	161	18	,	,	PUNCT
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eurjchem-2463	161	20	.	.	PUNCT
eurjchem-2463	162	1	[	[	X
eurjchem-2463	162	2	4	4	NUM
eurjchem-2463	162	3	]	]	PUNCT
eurjchem-2463	162	4	.	.	PUNCT
eurjchem-2463	163	1	van	van	PROPN
eurjchem-2463	163	2	koten	koten	PROPN
eurjchem-2463	163	3	,	,	PUNCT
eurjchem-2463	163	4	g.	g.	PROPN
eurjchem-2463	163	5	;	;	PUNCT
eurjchem-2463	163	6	gossage	gossage	NOUN
eurjchem-2463	163	7	,	,	PUNCT
eurjchem-2463	163	8	r.	r.	PROPN
eurjchem-2463	163	9	a.	a.	PROPN
eurjchem-2463	164	1	the	the	DET
eurjchem-2463	164	2	privileged	privileged	ADJ
eurjchem-2463	164	3	pincer	pincer	NOUN
eurjchem-2463	164	4	-	-	PUNCT
eurjchem-2463	164	5	metal	metal	NOUN
eurjchem-2463	164	6	platform	platform	NOUN
eurjchem-2463	164	7	:	:	PUNCT
eurjchem-2463	164	8	coordination	coordination	NOUN
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eurjchem-2463	164	10	&	&	CCONJ
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eurjchem-2463	164	12	;	;	PUNCT
eurjchem-2463	164	13	springer	springer	NOUN
eurjchem-2463	164	14	:	:	PUNCT
eurjchem-2463	164	15	berlin	berlin	PROPN
eurjchem-2463	164	16	,	,	PUNCT
eurjchem-2463	164	17	germany	germany	PROPN
eurjchem-2463	164	18	,	,	PUNCT
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eurjchem-2463	164	20	.	.	PUNCT
eurjchem-2463	165	1	[	[	X
eurjchem-2463	165	2	5	5	NUM
eurjchem-2463	165	3	]	]	PUNCT
eurjchem-2463	165	4	.	.	PUNCT
eurjchem-2463	166	1	murugesan	murugesan	ADJ
eurjchem-2463	166	2	,	,	PUNCT
eurjchem-2463	166	3	s.	s.	PROPN
eurjchem-2463	166	4	;	;	PUNCT
eurjchem-2463	166	5	kirchner	kirchner	PROPN
eurjchem-2463	166	6	,	,	PUNCT
eurjchem-2463	166	7	k.	k.	PROPN
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eurjchem-2463	166	9	-	-	ADJ
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eurjchem-2463	166	16	pcp	pcp	NOUN
eurjchem-2463	166	17	pincer	pincer	NOUN
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eurjchem-2463	166	19	.	.	PUNCT
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eurjchem-2463	167	3	.	.	PROPN
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eurjchem-2463	167	5	,	,	PUNCT
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eurjchem-2463	167	7	,	,	PUNCT
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eurjchem-2463	167	9	.	.	PUNCT
eurjchem-2463	168	1	[	[	X
eurjchem-2463	168	2	6	6	NUM
eurjchem-2463	168	3	]	]	PUNCT
eurjchem-2463	168	4	.	.	PUNCT
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eurjchem-2463	169	2	,	,	PUNCT
eurjchem-2463	169	3	g.	g.	PROPN
eurjchem-2463	169	4	;	;	PUNCT
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eurjchem-2463	169	6	,	,	PUNCT
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eurjchem-2463	169	17	.	.	PUNCT
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eurjchem-2463	170	2	.	.	PUNCT
eurjchem-2463	171	1	chem	chem	PROPN
eurjchem-2463	171	2	.	.	PUNCT
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eurjchem-2463	172	2	.	.	PUNCT
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eurjchem-2463	173	2	,	,	PUNCT
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eurjchem-2463	173	4	,	,	PUNCT
eurjchem-2463	173	5	741–765	741–765	NUM
eurjchem-2463	173	6	.	.	PUNCT
eurjchem-2463	174	1	[	[	X
eurjchem-2463	174	2	7	7	NUM
eurjchem-2463	174	3	]	]	PUNCT
eurjchem-2463	174	4	.	.	PUNCT
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eurjchem-2463	174	9	;	;	PUNCT
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eurjchem-2463	174	11	,	,	PUNCT
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eurjchem-2463	174	17	-	-	PUNCT
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eurjchem-2463	174	20	:	:	PUNCT
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eurjchem-2463	174	30	&	&	CCONJ
eurjchem-2463	174	31	sons	son	NOUN
eurjchem-2463	174	32	,	,	PUNCT
eurjchem-2463	174	33	2014	2014	NUM
eurjchem-2463	174	34	.	.	PUNCT
eurjchem-2463	175	1	[	[	X
eurjchem-2463	175	2	8	8	NUM
eurjchem-2463	175	3	]	]	PUNCT
eurjchem-2463	175	4	.	.	PUNCT
eurjchem-2463	175	5	gorgas	gorgas	PROPN
eurjchem-2463	175	6	,	,	PUNCT
eurjchem-2463	175	7	n.	n.	PROPN
eurjchem-2463	175	8	;	;	PUNCT
eurjchem-2463	175	9	alves	alves	PROPN
eurjchem-2463	175	10	,	,	PUNCT
eurjchem-2463	175	11	l.	l.	PROPN
eurjchem-2463	175	12	g.	g.	PROPN
eurjchem-2463	175	13	;	;	PUNCT
eurjchem-2463	175	14	stöger	stöger	ADV
eurjchem-2463	175	15	,	,	PUNCT
eurjchem-2463	175	16	b.	b.	PROPN
eurjchem-2463	175	17	;	;	PUNCT
eurjchem-2463	175	18	martins	martin	NOUN
eurjchem-2463	175	19	,	,	PUNCT
eurjchem-2463	175	20	a.	a.	NOUN
eurjchem-2463	175	21	m.	m.	NOUN
eurjchem-2463	175	22	;	;	PUNCT
eurjchem-2463	175	23	veiros	veiros	PROPN
eurjchem-2463	175	24	,	,	PUNCT
eurjchem-2463	175	25	l.	l.	PROPN
eurjchem-2463	175	26	f.	f.	PROPN
eurjchem-2463	175	27	;	;	PUNCT
eurjchem-2463	175	28	kirchner	kirchner	PROPN
eurjchem-2463	175	29	,	,	PUNCT
eurjchem-2463	175	30	k.	k.	PROPN
eurjchem-2463	175	31	stable	stable	ADJ
eurjchem-2463	175	32	,	,	PUNCT
eurjchem-2463	175	33	yet	yet	CCONJ
eurjchem-2463	175	34	highly	highly	ADV
eurjchem-2463	175	35	reactive	reactive	ADJ
eurjchem-2463	175	36	nonclassical	nonclassical	ADJ
eurjchem-2463	175	37	iron(ii	iron(ii	NOUN
eurjchem-2463	175	38	)	)	PUNCT
eurjchem-2463	175	39	polyhydride	polyhydride	NOUN
eurjchem-2463	175	40	pincer	pincer	NOUN
eurjchem-2463	175	41	complexes	complex	NOUN
eurjchem-2463	175	42	:	:	PUNCT
eurjchem-2463	175	43	z	z	ADJ
eurjchem-2463	175	44	-	-	PUNCT
eurjchem-2463	175	45	selective	selective	ADJ
eurjchem-2463	175	46	dimerization	dimerization	NOUN
eurjchem-2463	175	47	and	and	CCONJ
eurjchem-2463	175	48	hydroboration	hydroboration	NOUN
eurjchem-2463	175	49	of	of	ADP
eurjchem-2463	175	50	terminal	terminal	ADJ
eurjchem-2463	175	51	alkynes	alkyne	NOUN
eurjchem-2463	175	52	.	.	PUNCT
eurjchem-2463	176	1	j.	j.	PROPN
eurjchem-2463	176	2	am	am	PROPN
eurjchem-2463	176	3	.	.	PUNCT
eurjchem-2463	177	1	chem	chem	NOUN
eurjchem-2463	177	2	.	.	PUNCT
eurjchem-2463	178	1	soc	soc	PROPN
eurjchem-2463	178	2	.	.	PUNCT
eurjchem-2463	179	1	2017	2017	NUM
eurjchem-2463	179	2	,	,	PUNCT
eurjchem-2463	179	3	139	139	NUM
eurjchem-2463	179	4	,	,	PUNCT
eurjchem-2463	179	5	8130–8133	8130–8133	NUM
eurjchem-2463	179	6	.	.	PUNCT
eurjchem-2463	180	1	[	[	X
eurjchem-2463	180	2	9	9	NUM
eurjchem-2463	180	3	]	]	PUNCT
eurjchem-2463	180	4	.	.	PUNCT
eurjchem-2463	180	5	bertini	bertini	PROPN
eurjchem-2463	180	6	,	,	PUNCT
eurjchem-2463	180	7	f.	f.	PROPN
eurjchem-2463	180	8	;	;	PUNCT
eurjchem-2463	180	9	glatz	glatz	ADJ
eurjchem-2463	180	10	,	,	PUNCT
eurjchem-2463	180	11	m.	m.	NOUN
eurjchem-2463	180	12	;	;	PUNCT
eurjchem-2463	180	13	stöger	stöger	ADV
eurjchem-2463	180	14	,	,	PUNCT
eurjchem-2463	180	15	b.	b.	PROPN
eurjchem-2463	180	16	;	;	PUNCT
eurjchem-2463	180	17	peruzzini	peruzzini	NOUN
eurjchem-2463	180	18	,	,	PUNCT
eurjchem-2463	180	19	m.	m.	NOUN
eurjchem-2463	180	20	;	;	PUNCT
eurjchem-2463	180	21	veiros	veiros	PROPN
eurjchem-2463	180	22	,	,	PUNCT
eurjchem-2463	180	23	l.	l.	PROPN
eurjchem-2463	180	24	f.	f.	PROPN
eurjchem-2463	180	25	;	;	PUNCT
eurjchem-2463	180	26	kirchner	kirchner	PROPN
eurjchem-2463	180	27	,	,	PUNCT
eurjchem-2463	180	28	k.	k.	PROPN
eurjchem-2463	180	29	;	;	PUNCT
eurjchem-2463	180	30	gonsalvi	gonsalvi	PROPN
eurjchem-2463	180	31	,	,	PUNCT
eurjchem-2463	180	32	l.	l.	PROPN
eurjchem-2463	180	33	carbon	carbon	NOUN
eurjchem-2463	180	34	dioxide	dioxide	NOUN
eurjchem-2463	180	35	reduction	reduction	NOUN
eurjchem-2463	180	36	to	to	PART
eurjchem-2463	180	37	methanol	methanol	NOUN
eurjchem-2463	180	38	catalyzed	catalyze	VERB
eurjchem-2463	180	39	by	by	ADP
eurjchem-2463	180	40	mn(i	mn(i	PROPN
eurjchem-2463	180	41	)	)	PUNCT
eurjchem-2463	180	42	pnp	pnp	PROPN
eurjchem-2463	180	43	pincer	pincer	NOUN
eurjchem-2463	180	44	complexes	complexe	VERB
eurjchem-2463	180	45	under	under	ADP
eurjchem-2463	180	46	mild	mild	ADJ
eurjchem-2463	180	47	reaction	reaction	NOUN
eurjchem-2463	180	48	conditions	condition	NOUN
eurjchem-2463	180	49	.	.	PUNCT
eurjchem-2463	181	1	acs	acs	PROPN
eurjchem-2463	181	2	catal	catal	PROPN
eurjchem-2463	181	3	.	.	PUNCT
eurjchem-2463	182	1	2019	2019	NUM
eurjchem-2463	182	2	,	,	PUNCT
eurjchem-2463	182	3	9	9	NUM
eurjchem-2463	182	4	,	,	PUNCT
eurjchem-2463	182	5	632–639	632–639	NUM
eurjchem-2463	182	6	.	.	PUNCT
eurjchem-2463	183	1	[	[	X
eurjchem-2463	183	2	10	10	NUM
eurjchem-2463	183	3	]	]	PUNCT
eurjchem-2463	183	4	.	.	PUNCT
eurjchem-2463	184	1	mastalir	mastalir	NOUN
eurjchem-2463	184	2	,	,	PUNCT
eurjchem-2463	184	3	m.	m.	NOUN
eurjchem-2463	184	4	;	;	PUNCT
eurjchem-2463	184	5	pittenauer	pittenauer	PROPN
eurjchem-2463	184	6	,	,	PUNCT
eurjchem-2463	184	7	e.	e.	PROPN
eurjchem-2463	184	8	;	;	PUNCT
eurjchem-2463	184	9	stöger	stöger	ADV
eurjchem-2463	184	10	,	,	PUNCT
eurjchem-2463	184	11	b.	b.	PROPN
eurjchem-2463	184	12	;	;	PUNCT
eurjchem-2463	184	13	allmaier	allmaier	PROPN
eurjchem-2463	184	14	,	,	PUNCT
eurjchem-2463	184	15	g.	g.	PROPN
eurjchem-2463	184	16	;	;	PUNCT
eurjchem-2463	184	17	kirchner	kirchner	PROPN
eurjchem-2463	184	18	,	,	PUNCT
eurjchem-2463	184	19	k.	k.	PROPN
eurjchem-2463	185	1	three	three	NUM
eurjchem-2463	185	2	different	different	ADJ
eurjchem-2463	185	3	reactions	reaction	NOUN
eurjchem-2463	185	4	,	,	PUNCT
eurjchem-2463	185	5	one	one	NUM
eurjchem-2463	185	6	catalyst	catalyst	NOUN
eurjchem-2463	185	7	:	:	PUNCT
eurjchem-2463	185	8	a	a	DET
eurjchem-2463	185	9	cu(i	cu(i	NOUN
eurjchem-2463	185	10	)	)	PUNCT
eurjchem-2463	185	11	pnp	pnp	PROPN
eurjchem-2463	185	12	pincer	pincer	NOUN
eurjchem-2463	185	13	complex	complex	NOUN
eurjchem-2463	185	14	as	as	ADP
eurjchem-2463	185	15	catalyst	catalyst	NOUN
eurjchem-2463	185	16	for	for	ADP
eurjchem-2463	185	17	c	c	NOUN
eurjchem-2463	185	18	-	-	PUNCT
eurjchem-2463	185	19	c	c	NOUN
eurjchem-2463	185	20	and	and	CCONJ
eurjchem-2463	185	21	c	c	NOUN
eurjchem-2463	185	22	-	-	PUNCT
eurjchem-2463	185	23	n	n	PRON
eurjchem-2463	185	24	cross	cross	NOUN
eurjchem-2463	185	25	-	-	NOUN
eurjchem-2463	185	26	couplings	coupling	NOUN
eurjchem-2463	185	27	.	.	PUNCT
eurjchem-2463	186	1	org	org	PROPN
eurjchem-2463	186	2	.	.	PUNCT
eurjchem-2463	187	1	lett	lett	PROPN
eurjchem-2463	187	2	.	.	PROPN
eurjchem-2463	188	1	2017	2017	NUM
eurjchem-2463	188	2	,	,	PUNCT
eurjchem-2463	188	3	19	19	NUM
eurjchem-2463	188	4	,	,	PUNCT
eurjchem-2463	188	5	2178	2178	NUM
eurjchem-2463	188	6	–	–	PUNCT
eurjchem-2463	188	7	2181	2181	NUM
eurjchem-2463	188	8	.	.	PUNCT
eurjchem-2463	189	1	[	[	X
eurjchem-2463	189	2	11	11	NUM
eurjchem-2463	189	3	]	]	PUNCT
eurjchem-2463	189	4	.	.	PUNCT
eurjchem-2463	190	1	ruivo	ruivo	PROPN
eurjchem-2463	190	2	,	,	PUNCT
eurjchem-2463	190	3	r.	r.	PROPN
eurjchem-2463	190	4	;	;	PUNCT
eurjchem-2463	190	5	alves	alves	PROPN
eurjchem-2463	190	6	,	,	PUNCT
eurjchem-2463	190	7	l.	l.	PROPN
eurjchem-2463	190	8	g.	g.	PROPN
eurjchem-2463	190	9	;	;	PUNCT
eurjchem-2463	190	10	kirchner	kirchner	PROPN
eurjchem-2463	190	11	,	,	PUNCT
eurjchem-2463	190	12	k.	k.	PROPN
eurjchem-2463	190	13	;	;	PUNCT
eurjchem-2463	190	14	martins	martin	NOUN
eurjchem-2463	190	15	,	,	PUNCT
eurjchem-2463	190	16	a.	a.	NOUN
eurjchem-2463	190	17	m.	m.	NOUN
eurjchem-2463	190	18	supramolecular	supramolecular	ADJ
eurjchem-2463	190	19	structures	structure	NOUN
eurjchem-2463	190	20	of	of	ADP
eurjchem-2463	190	21	v(iii	v(iii	NOUN
eurjchem-2463	190	22	)	)	PUNCT
eurjchem-2463	190	23	complexes	complex	NOUN
eurjchem-2463	190	24	supported	support	VERB
eurjchem-2463	190	25	by	by	ADP
eurjchem-2463	190	26	pnp	pnp	PROPN
eurjchem-2463	190	27	pincer	pincer	PROPN
eurjchem-2463	190	28	ligands	ligand	NOUN
eurjchem-2463	190	29	.	.	PUNCT
eurjchem-2463	191	1	j.	j.	PROPN
eurjchem-2463	191	2	mol	mol	PROPN
eurjchem-2463	191	3	.	.	PROPN
eurjchem-2463	191	4	struct	struct	NOUN
eurjchem-2463	191	5	.	.	PUNCT
eurjchem-2463	192	1	2017	2017	NUM
eurjchem-2463	192	2	,	,	PUNCT
eurjchem-2463	192	3	1149	1149	NUM
eurjchem-2463	192	4	,	,	PUNCT
eurjchem-2463	192	5	229–234	229–234	NUM
eurjchem-2463	192	6	.	.	PUNCT
eurjchem-2463	193	1	[	[	X
eurjchem-2463	193	2	12	12	NUM
eurjchem-2463	193	3	]	]	PUNCT
eurjchem-2463	193	4	.	.	PUNCT
eurjchem-2463	194	1	mastalir	mastalir	NOUN
eurjchem-2463	194	2	,	,	PUNCT
eurjchem-2463	194	3	m.	m.	NOUN
eurjchem-2463	194	4	;	;	PUNCT
eurjchem-2463	194	5	glatz	glatz	ADJ
eurjchem-2463	194	6	,	,	PUNCT
eurjchem-2463	194	7	m.	m.	NOUN
eurjchem-2463	194	8	;	;	PUNCT
eurjchem-2463	194	9	stöger	stöger	ADV
eurjchem-2463	194	10	,	,	PUNCT
eurjchem-2463	194	11	b.	b.	PROPN
eurjchem-2463	194	12	;	;	PUNCT
eurjchem-2463	194	13	weil	weil	PROPN
eurjchem-2463	194	14	,	,	PUNCT
eurjchem-2463	194	15	m.	m.	NOUN
eurjchem-2463	194	16	;	;	PUNCT
eurjchem-2463	194	17	pittenauer	pittenauer	PROPN
eurjchem-2463	194	18	,	,	PUNCT
eurjchem-2463	194	19	e.	e.	PROPN
eurjchem-2463	194	20	;	;	PUNCT
eurjchem-2463	194	21	allmaier	allmaier	PROPN
eurjchem-2463	194	22	,	,	PUNCT
eurjchem-2463	194	23	g.	g.	PROPN
eurjchem-2463	194	24	;	;	PUNCT
eurjchem-2463	194	25	kirchner	kirchner	PROPN
eurjchem-2463	194	26	,	,	PUNCT
eurjchem-2463	194	27	k.	k.	PROPN
eurjchem-2463	194	28	synthesis	synthesis	PROPN
eurjchem-2463	194	29	,	,	PUNCT
eurjchem-2463	194	30	characterization	characterization	NOUN
eurjchem-2463	194	31	and	and	CCONJ
eurjchem-2463	194	32	reactivity	reactivity	NOUN
eurjchem-2463	194	33	of	of	ADP
eurjchem-2463	194	34	vanadium	vanadium	NOUN
eurjchem-2463	194	35	,	,	PUNCT
eurjchem-2463	194	36	chromium	chromium	NOUN
eurjchem-2463	194	37	,	,	PUNCT
eurjchem-2463	194	38	and	and	CCONJ
eurjchem-2463	194	39	manganese	manganese	ADJ
eurjchem-2463	194	40	pnp	pnp	NOUN
eurjchem-2463	194	41	pincer	pincer	NOUN
eurjchem-2463	194	42	complexes	complex	NOUN
eurjchem-2463	194	43	.	.	PUNCT
eurjchem-2463	195	1	inorganica	inorganica	PROPN
eurjchem-2463	195	2	chim	chim	PROPN
eurjchem-2463	195	3	.	.	PUNCT
eurjchem-2463	196	1	acta	acta	PROPN
eurjchem-2463	196	2	2017	2017	NUM
eurjchem-2463	196	3	,	,	PUNCT
eurjchem-2463	196	4	455	455	NUM
eurjchem-2463	196	5	,	,	PUNCT
eurjchem-2463	196	6	707–714	707–714	NUM
eurjchem-2463	196	7	.	.	PUNCT
eurjchem-2463	197	1	[	[	X
eurjchem-2463	197	2	13	13	NUM
eurjchem-2463	197	3	]	]	SYM
eurjchem-2463	197	4	.	.	PUNCT
eurjchem-2463	197	5	mastalir	mastalir	NOUN
eurjchem-2463	197	6	,	,	PUNCT
eurjchem-2463	197	7	m.	m.	NOUN
eurjchem-2463	197	8	;	;	PUNCT
eurjchem-2463	197	9	de	de	X
eurjchem-2463	197	10	aguiar	aguiar	PROPN
eurjchem-2463	197	11	,	,	PUNCT
eurjchem-2463	197	12	s.	s.	PROPN
eurjchem-2463	197	13	r.	r.	PROPN
eurjchem-2463	197	14	m.	m.	PROPN
eurjchem-2463	197	15	m.	m.	PROPN
eurjchem-2463	197	16	;	;	PUNCT
eurjchem-2463	197	17	glatz	glatz	ADJ
eurjchem-2463	197	18	,	,	PUNCT
eurjchem-2463	197	19	m.	m.	NOUN
eurjchem-2463	197	20	;	;	PUNCT
eurjchem-2463	197	21	stöger	stöger	ADV
eurjchem-2463	197	22	,	,	PUNCT
eurjchem-2463	197	23	b.	b.	PROPN
eurjchem-2463	197	24	;	;	PUNCT
eurjchem-2463	197	25	kirchner	kirchner	PROPN
eurjchem-2463	197	26	,	,	PUNCT
eurjchem-2463	197	27	k.	k.	PROPN
eurjchem-2463	198	1	a	a	DET
eurjchem-2463	198	2	convenient	convenient	ADJ
eurjchem-2463	198	3	solvothermal	solvothermal	ADJ
eurjchem-2463	198	4	synthesis	synthesis	NOUN
eurjchem-2463	198	5	of	of	ADP
eurjchem-2463	198	6	group	group	NOUN
eurjchem-2463	198	7	6	6	NUM
eurjchem-2463	198	8	pnp	pnp	PROPN
eurjchem-2463	198	9	pincer	pincer	NOUN
eurjchem-2463	198	10	tricarbonyl	tricarbonyl	NOUN
eurjchem-2463	198	11	complexes	complex	NOUN
eurjchem-2463	198	12	.	.	PUNCT
eurjchem-2463	199	1	organometallics	organometallic	NOUN
eurjchem-2463	199	2	2016	2016	NUM
eurjchem-2463	199	3	,	,	PUNCT
eurjchem-2463	199	4	35	35	NUM
eurjchem-2463	199	5	,	,	PUNCT
eurjchem-2463	199	6	229–232	229–232	NUM
eurjchem-2463	199	7	.	.	PUNCT
eurjchem-2463	200	1	[	[	X
eurjchem-2463	200	2	14	14	NUM
eurjchem-2463	200	3	]	]	PUNCT
eurjchem-2463	200	4	.	.	PUNCT
eurjchem-2463	201	1	arashiba	arashiba	PROPN
eurjchem-2463	201	2	,	,	PUNCT
eurjchem-2463	201	3	k.	k.	PROPN
eurjchem-2463	201	4	;	;	PUNCT
eurjchem-2463	201	5	sasaki	sasaki	PROPN
eurjchem-2463	201	6	,	,	PUNCT
eurjchem-2463	201	7	k.	k.	PROPN
eurjchem-2463	201	8	;	;	PUNCT
eurjchem-2463	201	9	kuriyama	kuriyama	PROPN
eurjchem-2463	201	10	,	,	PUNCT
eurjchem-2463	201	11	s.	s.	PROPN
eurjchem-2463	201	12	;	;	PUNCT
eurjchem-2463	201	13	miyake	miyake	PROPN
eurjchem-2463	201	14	,	,	PUNCT
eurjchem-2463	201	15	y.	y.	PROPN
eurjchem-2463	201	16	;	;	PUNCT
eurjchem-2463	201	17	nakanishi	nakanishi	PROPN
eurjchem-2463	201	18	,	,	PUNCT
eurjchem-2463	201	19	h.	h.	PROPN
eurjchem-2463	201	20	;	;	PUNCT
eurjchem-2463	201	21	nishibayashi	nishibayashi	PROPN
eurjchem-2463	201	22	,	,	PUNCT
eurjchem-2463	201	23	y.	y.	NOUN
eurjchem-2463	201	24	synthesis	synthesis	NOUN
eurjchem-2463	201	25	and	and	CCONJ
eurjchem-2463	201	26	protonation	protonation	NOUN
eurjchem-2463	201	27	of	of	ADP
eurjchem-2463	201	28	molybdenum	molybdenum	NOUN
eurjchem-2463	201	29	–	–	PUNCT
eurjchem-2463	201	30	and	and	CCONJ
eurjchem-2463	201	31	tungsten	tungsten	VERB
eurjchem-2463	201	32	–	–	PUNCT
eurjchem-2463	201	33	dinitrogen	dinitrogen	NOUN
eurjchem-2463	201	34	complexes	complex	NOUN
eurjchem-2463	201	35	bearing	bear	VERB
eurjchem-2463	201	36	pnp	pnp	NOUN
eurjchem-2463	201	37	-	-	PUNCT
eurjchem-2463	201	38	type	type	NOUN
eurjchem-2463	201	39	pincer	pincer	NOUN
eurjchem-2463	201	40	ligands	ligand	NOUN
eurjchem-2463	201	41	.	.	PUNCT
eurjchem-2463	202	1	organometallics	organometallic	NOUN
eurjchem-2463	202	2	2012	2012	NUM
eurjchem-2463	202	3	,	,	PUNCT
eurjchem-2463	202	4	31	31	NUM
eurjchem-2463	202	5	,	,	PUNCT
eurjchem-2463	202	6	2035–2041	2035–2041	NUM
eurjchem-2463	202	7	.	.	PUNCT
eurjchem-2463	203	1	[	[	X
eurjchem-2463	203	2	15	15	NUM
eurjchem-2463	203	3	]	]	PUNCT
eurjchem-2463	203	4	.	.	PUNCT
eurjchem-2463	204	1	arashiba	arashiba	PROPN
eurjchem-2463	204	2	,	,	PUNCT
eurjchem-2463	204	3	k.	k.	PROPN
eurjchem-2463	204	4	;	;	PUNCT
eurjchem-2463	204	5	eizawa	eizawa	PROPN
eurjchem-2463	204	6	,	,	PUNCT
eurjchem-2463	204	7	a.	a.	NOUN
eurjchem-2463	204	8	;	;	PUNCT
eurjchem-2463	204	9	tanaka	tanaka	PROPN
eurjchem-2463	204	10	,	,	PUNCT
eurjchem-2463	204	11	h.	h.	PROPN
eurjchem-2463	204	12	;	;	PUNCT
eurjchem-2463	204	13	nakajima	nakajima	PROPN
eurjchem-2463	204	14	,	,	PUNCT
eurjchem-2463	204	15	k.	k.	PROPN
eurjchem-2463	204	16	;	;	PUNCT
eurjchem-2463	204	17	yoshizawa	yoshizawa	PROPN
eurjchem-2463	204	18	,	,	PUNCT
eurjchem-2463	204	19	k.	k.	PROPN
eurjchem-2463	204	20	;	;	PUNCT
eurjchem-2463	204	21	nishibayashi	nishibayashi	PROPN
eurjchem-2463	204	22	,	,	PUNCT
eurjchem-2463	204	23	y.	y.	PROPN
eurjchem-2463	204	24	catalytic	catalytic	ADJ
eurjchem-2463	204	25	nitrogen	nitrogen	NOUN
eurjchem-2463	204	26	fixation	fixation	NOUN
eurjchem-2463	204	27	via	via	ADP
eurjchem-2463	204	28	direct	direct	ADJ
eurjchem-2463	204	29	cleavage	cleavage	NOUN
eurjchem-2463	204	30	of	of	ADP
eurjchem-2463	204	31	nitrogen	nitrogen	NOUN
eurjchem-2463	204	32	–	–	PUNCT
eurjchem-2463	204	33	nitrogen	nitrogen	NOUN
eurjchem-2463	204	34	triple	triple	ADJ
eurjchem-2463	204	35	bond	bond	NOUN
eurjchem-2463	204	36	of	of	ADP
eurjchem-2463	204	37	molecular	molecular	ADJ
eurjchem-2463	204	38	dinitrogen	dinitrogen	NOUN
eurjchem-2463	204	39	under	under	ADP
eurjchem-2463	204	40	ambient	ambient	ADJ
eurjchem-2463	204	41	reaction	reaction	NOUN
eurjchem-2463	204	42	conditions	condition	NOUN
eurjchem-2463	204	43	.	.	PUNCT
eurjchem-2463	205	1	bull	bull	NOUN
eurjchem-2463	205	2	.	.	PUNCT
eurjchem-2463	206	1	chem	chem	PROPN
eurjchem-2463	206	2	.	.	PUNCT
eurjchem-2463	207	1	soc	soc	PROPN
eurjchem-2463	207	2	.	.	PUNCT
eurjchem-2463	208	1	jpn	jpn	PROPN
eurjchem-2463	208	2	.	.	PROPN
eurjchem-2463	208	3	2017	2017	NUM
eurjchem-2463	208	4	,	,	PUNCT
eurjchem-2463	208	5	90	90	NUM
eurjchem-2463	208	6	,	,	PUNCT
eurjchem-2463	208	7	1111–1118	1111–1118	NUM
eurjchem-2463	208	8	.	.	PUNCT
eurjchem-2463	209	1	[	[	X
eurjchem-2463	209	2	16	16	NUM
eurjchem-2463	209	3	]	]	PUNCT
eurjchem-2463	209	4	.	.	PUNCT
eurjchem-2463	210	1	de	de	PROPN
eurjchem-2463	210	2	aguiar	aguiar	PROPN
eurjchem-2463	210	3	,	,	PUNCT
eurjchem-2463	210	4	s.	s.	PROPN
eurjchem-2463	210	5	r.	r.	PROPN
eurjchem-2463	210	6	m.	m.	PROPN
eurjchem-2463	210	7	m.	m.	PROPN
eurjchem-2463	210	8	;	;	PUNCT
eurjchem-2463	210	9	stöger	stöger	ADV
eurjchem-2463	210	10	,	,	PUNCT
eurjchem-2463	210	11	b.	b.	PROPN
eurjchem-2463	210	12	;	;	PUNCT
eurjchem-2463	210	13	pittenauer	pittenauer	PROPN
eurjchem-2463	210	14	,	,	PUNCT
eurjchem-2463	210	15	e.	e.	PROPN
eurjchem-2463	210	16	;	;	PUNCT
eurjchem-2463	210	17	puchberger	puchberger	ADJ
eurjchem-2463	210	18	,	,	PUNCT
eurjchem-2463	210	19	m.	m.	NOUN
eurjchem-2463	210	20	;	;	PUNCT
eurjchem-2463	210	21	allmaier	allmaier	PROPN
eurjchem-2463	210	22	,	,	PUNCT
eurjchem-2463	210	23	g.	g.	PROPN
eurjchem-2463	210	24	;	;	PUNCT
eurjchem-2463	210	25	veiros	veiros	PROPN
eurjchem-2463	210	26	,	,	PUNCT
eurjchem-2463	210	27	l.	l.	PROPN
eurjchem-2463	210	28	f.	f.	PROPN
eurjchem-2463	210	29	;	;	PUNCT
eurjchem-2463	210	30	kirchner	kirchner	PROPN
eurjchem-2463	210	31	,	,	PUNCT
eurjchem-2463	210	32	k.	k.	PROPN
eurjchem-2463	211	1	a	a	DET
eurjchem-2463	211	2	complete	complete	ADJ
eurjchem-2463	211	3	series	series	NOUN
eurjchem-2463	211	4	of	of	ADP
eurjchem-2463	211	5	halocarbonyl	halocarbonyl	PROPN
eurjchem-2463	211	6	molybdenum	molybdenum	PROPN
eurjchem-2463	211	7	pnp	pnp	PROPN
eurjchem-2463	211	8	pincer	pincer	NOUN
eurjchem-2463	211	9	complexes	complexe	VERB
eurjchem-2463	211	10	unexpected	unexpected	ADJ
eurjchem-2463	211	11	differences	difference	NOUN
eurjchem-2463	211	12	between	between	ADP
eurjchem-2463	211	13	nh	nh	PROPN
eurjchem-2463	211	14	and	and	CCONJ
eurjchem-2463	211	15	nme	nme	PROPN
eurjchem-2463	211	16	spacers	spacer	NOUN
eurjchem-2463	211	17	.	.	PUNCT
eurjchem-2463	212	1	j.	j.	PROPN
eurjchem-2463	212	2	organomet	organomet	PROPN
eurjchem-2463	212	3	.	.	PUNCT
eurjchem-2463	213	1	chem	chem	NOUN
eurjchem-2463	213	2	.	.	PUNCT
eurjchem-2463	214	1	2014	2014	NUM
eurjchem-2463	214	2	,	,	PUNCT
eurjchem-2463	214	3	760	760	NUM
eurjchem-2463	214	4	,	,	PUNCT
eurjchem-2463	214	5	74–83	74–83	NUM
eurjchem-2463	214	6	.	.	PUNCT
eurjchem-2463	215	1	[	[	X
eurjchem-2463	215	2	17	17	NUM
eurjchem-2463	215	3	]	]	PUNCT
eurjchem-2463	215	4	.	.	PUNCT
eurjchem-2463	215	5	kinoshita	kinoshita	PROPN
eurjchem-2463	215	6	,	,	PUNCT
eurjchem-2463	215	7	e.	e.	PROPN
eurjchem-2463	215	8	;	;	PUNCT
eurjchem-2463	215	9	arashiba	arashiba	PROPN
eurjchem-2463	215	10	,	,	PUNCT
eurjchem-2463	215	11	k.	k.	PROPN
eurjchem-2463	215	12	;	;	PUNCT
eurjchem-2463	215	13	kuriyama	kuriyama	PROPN
eurjchem-2463	215	14	,	,	PUNCT
eurjchem-2463	215	15	s.	s.	PROPN
eurjchem-2463	215	16	;	;	PUNCT
eurjchem-2463	215	17	eizawa	eizawa	PROPN
eurjchem-2463	215	18	,	,	PUNCT
eurjchem-2463	215	19	a.	a.	NOUN
eurjchem-2463	215	20	;	;	PUNCT
eurjchem-2463	215	21	nakajima	nakajima	PROPN
eurjchem-2463	215	22	,	,	PUNCT
eurjchem-2463	215	23	k.	k.	PROPN
eurjchem-2463	215	24	;	;	PUNCT
eurjchem-2463	215	25	nishibayashi	nishibayashi	PROPN
eurjchem-2463	215	26	,	,	PUNCT
eurjchem-2463	215	27	y.	y.	NOUN
eurjchem-2463	215	28	synthesis	synthesis	NOUN
eurjchem-2463	215	29	and	and	CCONJ
eurjchem-2463	215	30	catalytic	catalytic	ADJ
eurjchem-2463	215	31	activity	activity	NOUN
eurjchem-2463	215	32	of	of	ADP
eurjchem-2463	215	33	molybdenum	molybdenum	NOUN
eurjchem-2463	215	34	–	–	PUNCT
eurjchem-2463	215	35	nitride	nitride	ADJ
eurjchem-2463	215	36	complexes	complex	NOUN
eurjchem-2463	215	37	bearing	bear	VERB
eurjchem-2463	215	38	pincer	pincer	NOUN
eurjchem-2463	215	39	ligands	ligand	NOUN
eurjchem-2463	215	40	:	:	PUNCT
eurjchem-2463	215	41	molybdenum	molybdenum	NOUN
eurjchem-2463	215	42	-	-	PUNCT
eurjchem-2463	215	43	nitride	nitride	NOUN
eurjchem-2463	215	44	complexes	complex	NOUN
eurjchem-2463	215	45	bearing	bear	VERB
eurjchem-2463	215	46	pincer	pincer	NOUN
eurjchem-2463	215	47	ligands	ligand	NOUN
eurjchem-2463	215	48	.	.	PUNCT
eurjchem-2463	216	1	eur	eur	PROPN
eurjchem-2463	216	2	.	.	PUNCT
eurjchem-2463	217	1	j.	j.	PROPN
eurjchem-2463	217	2	inorg	inorg	PROPN
eurjchem-2463	217	3	.	.	PUNCT
eurjchem-2463	218	1	chem	chem	PROPN
eurjchem-2463	218	2	.	.	PUNCT
eurjchem-2463	219	1	2015	2015	NUM
eurjchem-2463	219	2	,	,	PUNCT
eurjchem-2463	219	3	2015	2015	NUM
eurjchem-2463	219	4	,	,	PUNCT
eurjchem-2463	219	5	1789–1794	1789–1794	NUM
eurjchem-2463	219	6	.	.	PUNCT
eurjchem-2463	220	1	[	[	X
eurjchem-2463	220	2	18	18	NUM
eurjchem-2463	220	3	]	]	PUNCT
eurjchem-2463	220	4	.	.	PUNCT
eurjchem-2463	220	5	de	de	X
eurjchem-2463	220	6	aguiar	aguiar	PROPN
eurjchem-2463	220	7	,	,	PUNCT
eurjchem-2463	220	8	s.	s.	PROPN
eurjchem-2463	220	9	r.	r.	PROPN
eurjchem-2463	220	10	m.	m.	PROPN
eurjchem-2463	220	11	m.	m.	PROPN
eurjchem-2463	220	12	;	;	PUNCT
eurjchem-2463	220	13	schröder	schröder	NOUN
eurjchem-2463	220	14	-	-	PUNCT
eurjchem-2463	220	15	holzhacker	holzhacker	PROPN
eurjchem-2463	220	16	,	,	PUNCT
eurjchem-2463	220	17	c.	c.	PROPN
eurjchem-2463	220	18	;	;	PUNCT
eurjchem-2463	220	19	pecak	pecak	NOUN
eurjchem-2463	220	20	,	,	PUNCT
eurjchem-2463	220	21	j.	j.	PROPN
eurjchem-2463	220	22	;	;	PUNCT
eurjchem-2463	220	23	stöger	stöger	ADV
eurjchem-2463	220	24	,	,	PUNCT
eurjchem-2463	220	25	b.	b.	PROPN
eurjchem-2463	220	26	;	;	PUNCT
eurjchem-2463	220	27	kirchner	kirchner	PROPN
eurjchem-2463	220	28	,	,	PUNCT
eurjchem-2463	220	29	k.	k.	NOUN
eurjchem-2463	220	30	synthesis	synthesis	NOUN
eurjchem-2463	220	31	and	and	CCONJ
eurjchem-2463	220	32	characterization	characterization	NOUN
eurjchem-2463	220	33	of	of	ADP
eurjchem-2463	220	34	taddol	taddol	NOUN
eurjchem-2463	220	35	-	-	PUNCT
eurjchem-2463	220	36	based	base	VERB
eurjchem-2463	220	37	chiral	chiral	ADJ
eurjchem-2463	220	38	group	group	NOUN
eurjchem-2463	220	39	six	six	NUM
eurjchem-2463	220	40	pnp	pnp	PROPN
eurjchem-2463	220	41	pincer	pincer	NOUN
eurjchem-2463	220	42	tricarbonyl	tricarbonyl	NOUN
eurjchem-2463	220	43	complexes	complex	NOUN
eurjchem-2463	220	44	.	.	PUNCT
eurjchem-2463	221	1	monatsh	monatsh	ADJ
eurjchem-2463	221	2	.	.	PUNCT
eurjchem-2463	221	3	chem	chem	PROPN
eurjchem-2463	221	4	.	.	PUNCT
eurjchem-2463	222	1	2019	2019	NUM
eurjchem-2463	222	2	,	,	PUNCT
eurjchem-2463	222	3	150	150	NUM
eurjchem-2463	222	4	,	,	PUNCT
eurjchem-2463	222	5	103–109	103–109	NUM
eurjchem-2463	222	6	.	.	PUNCT
eurjchem-2463	223	1	[	[	X
eurjchem-2463	223	2	19	19	NUM
eurjchem-2463	223	3	]	]	PUNCT
eurjchem-2463	223	4	.	.	PUNCT
eurjchem-2463	224	1	tanaka	tanaka	PROPN
eurjchem-2463	224	2	,	,	PUNCT
eurjchem-2463	224	3	h.	h.	PROPN
eurjchem-2463	224	4	;	;	PUNCT
eurjchem-2463	224	5	arashiba	arashiba	PROPN
eurjchem-2463	224	6	,	,	PUNCT
eurjchem-2463	224	7	k.	k.	PROPN
eurjchem-2463	224	8	;	;	PUNCT
eurjchem-2463	224	9	kuriyama	kuriyama	PROPN
eurjchem-2463	224	10	,	,	PUNCT
eurjchem-2463	224	11	s.	s.	PROPN
eurjchem-2463	224	12	;	;	PUNCT
eurjchem-2463	224	13	sasada	sasada	PROPN
eurjchem-2463	224	14	,	,	PUNCT
eurjchem-2463	224	15	a.	a.	PROPN
eurjchem-2463	224	16	;	;	PUNCT
eurjchem-2463	224	17	nakajima	nakajima	PROPN
eurjchem-2463	224	18	,	,	PUNCT
eurjchem-2463	224	19	k.	k.	PROPN
eurjchem-2463	224	20	;	;	PUNCT
eurjchem-2463	224	21	yoshizawa	yoshizawa	PROPN
eurjchem-2463	224	22	,	,	PUNCT
eurjchem-2463	224	23	k.	k.	PROPN
eurjchem-2463	224	24	;	;	PUNCT
eurjchem-2463	224	25	nishibayashi	nishibayashi	PROPN
eurjchem-2463	224	26	,	,	PUNCT
eurjchem-2463	224	27	y.	y.	NOUN
eurjchem-2463	224	28	unique	unique	ADJ
eurjchem-2463	224	29	behaviour	behaviour	NOUN
eurjchem-2463	224	30	of	of	ADP
eurjchem-2463	224	31	dinitrogenbridged	dinitrogenbridge	VERB
eurjchem-2463	224	32	dimolybdenum	dimolybdenum	ADJ
eurjchem-2463	224	33	complexes	complex	NOUN
eurjchem-2463	224	34	bearing	bear	VERB
eurjchem-2463	224	35	pincer	pincer	PROPN
eurjchem-2463	224	36	ligand	ligand	NOUN
eurjchem-2463	224	37	towards	towards	ADP
eurjchem-2463	224	38	catalytic	catalytic	ADJ
eurjchem-2463	224	39	formation	formation	NOUN
eurjchem-2463	224	40	of	of	ADP
eurjchem-2463	224	41	ammonia	ammonia	NOUN
eurjchem-2463	224	42	.	.	PUNCT
eurjchem-2463	225	1	nat	nat	PROPN
eurjchem-2463	225	2	.	.	PUNCT
eurjchem-2463	226	1	commun	commun	PROPN
eurjchem-2463	226	2	.	.	PUNCT
eurjchem-2463	227	1	2014	2014	NUM
eurjchem-2463	227	2	,	,	PUNCT
eurjchem-2463	227	3	5	5	NUM
eurjchem-2463	227	4	,	,	PUNCT
eurjchem-2463	227	5	3737	3737	NUM
eurjchem-2463	227	6	.	.	PUNCT
eurjchem-2463	228	1	[	[	X
eurjchem-2463	228	2	20	20	NUM
eurjchem-2463	228	3	]	]	PUNCT
eurjchem-2463	228	4	.	.	PUNCT
eurjchem-2463	229	1	álvarez	álvarez	PROPN
eurjchem-2463	229	2	,	,	PUNCT
eurjchem-2463	229	3	m.	m.	NOUN
eurjchem-2463	229	4	;	;	PUNCT
eurjchem-2463	229	5	galindo	galindo	PROPN
eurjchem-2463	229	6	,	,	PUNCT
eurjchem-2463	229	7	a.	a.	NOUN
eurjchem-2463	229	8	;	;	PUNCT
eurjchem-2463	229	9	pérez	pérez	NOUN
eurjchem-2463	229	10	,	,	PUNCT
eurjchem-2463	229	11	p.	p.	PROPN
eurjchem-2463	229	12	j.	j.	PROPN
eurjchem-2463	229	13	;	;	PUNCT
eurjchem-2463	229	14	carmona	carmona	PROPN
eurjchem-2463	229	15	,	,	PUNCT
eurjchem-2463	229	16	e.	e.	PROPN
eurjchem-2463	229	17	molybdenum	molybdenum	PROPN
eurjchem-2463	229	18	and	and	CCONJ
eurjchem-2463	229	19	tungsten	tungsten	NOUN
eurjchem-2463	229	20	complexes	complex	NOUN
eurjchem-2463	229	21	with	with	ADP
eurjchem-2463	229	22	carbon	carbon	NOUN
eurjchem-2463	229	23	dioxide	dioxide	NOUN
eurjchem-2463	229	24	and	and	CCONJ
eurjchem-2463	229	25	ethylene	ethylene	NOUN
eurjchem-2463	229	26	ligands	ligand	NOUN
eurjchem-2463	229	27	.	.	PUNCT
eurjchem-2463	230	1	chem	chem	NOUN
eurjchem-2463	230	2	.	.	PUNCT
eurjchem-2463	231	1	sci	sci	PROPN
eurjchem-2463	231	2	.	.	PROPN
eurjchem-2463	231	3	2019	2019	NUM
eurjchem-2463	231	4	,	,	PUNCT
eurjchem-2463	231	5	10	10	NUM
eurjchem-2463	231	6	,	,	PUNCT
eurjchem-2463	231	7	8541–8546	8541–8546	NUM
eurjchem-2463	231	8	.	.	PUNCT
eurjchem-2463	232	1	[	[	X
eurjchem-2463	232	2	21	21	NUM
eurjchem-2463	232	3	]	]	PUNCT
eurjchem-2463	232	4	.	.	PUNCT
eurjchem-2463	233	1	benito	benito	PROPN
eurjchem-2463	233	2	-	-	PROPN
eurjchem-2463	233	3	garagorri	garagorri	PROPN
eurjchem-2463	233	4	,	,	PUNCT
eurjchem-2463	233	5	d.	d.	PROPN
eurjchem-2463	233	6	;	;	PUNCT
eurjchem-2463	233	7	becker	becker	PROPN
eurjchem-2463	233	8	,	,	PUNCT
eurjchem-2463	233	9	e.	e.	PROPN
eurjchem-2463	233	10	;	;	PUNCT
eurjchem-2463	233	11	wiedermann	wiedermann	PROPN
eurjchem-2463	233	12	,	,	PUNCT
eurjchem-2463	233	13	j.	j.	PROPN
eurjchem-2463	233	14	;	;	PUNCT
eurjchem-2463	233	15	lackner	lackner	PROPN
eurjchem-2463	233	16	,	,	PUNCT
eurjchem-2463	233	17	w.	w.	PROPN
eurjchem-2463	233	18	;	;	PUNCT
eurjchem-2463	233	19	pollak	pollak	PROPN
eurjchem-2463	233	20	,	,	PUNCT
eurjchem-2463	233	21	m.	m.	NOUN
eurjchem-2463	233	22	;	;	PUNCT
eurjchem-2463	233	23	mereiter	mereiter	NOUN
eurjchem-2463	233	24	,	,	PUNCT
eurjchem-2463	233	25	k.	k.	PROPN
eurjchem-2463	233	26	;	;	PUNCT
eurjchem-2463	233	27	kisala	kisala	PROPN
eurjchem-2463	233	28	,	,	PUNCT
eurjchem-2463	233	29	j.	j.	PROPN
eurjchem-2463	233	30	;	;	PUNCT
eurjchem-2463	233	31	kirchner	kirchner	PROPN
eurjchem-2463	233	32	,	,	PUNCT
eurjchem-2463	233	33	k.	k.	PROPN
eurjchem-2463	233	34	achiral	achiral	PROPN
eurjchem-2463	233	35	and	and	CCONJ
eurjchem-2463	233	36	chiral	chiral	ADJ
eurjchem-2463	233	37	transition	transition	NOUN
eurjchem-2463	233	38	metal	metal	NOUN
eurjchem-2463	233	39	complexes	complex	NOUN
eurjchem-2463	233	40	with	with	ADP
eurjchem-2463	233	41	modularly	modularly	ADV
eurjchem-2463	233	42	designed	design	VERB
eurjchem-2463	233	43	tridentate	tridentate	PROPN
eurjchem-2463	233	44	pnp	pnp	PROPN
eurjchem-2463	233	45	pincer	pincer	NOUN
eurjchem-2463	233	46	-	-	PUNCT
eurjchem-2463	233	47	type	type	NOUN
eurjchem-2463	233	48	ligands	ligand	NOUN
eurjchem-2463	233	49	based	base	VERB
eurjchem-2463	233	50	on	on	ADP
eurjchem-2463	233	51	n	n	CCONJ
eurjchem-2463	233	52	-	-	PUNCT
eurjchem-2463	233	53	heterocyclic	heterocyclic	ADJ
eurjchem-2463	233	54	diamines	diamine	NOUN
eurjchem-2463	233	55	.	.	PUNCT
eurjchem-2463	234	1	organometallics	organometallic	NOUN
eurjchem-2463	234	2	2006	2006	NUM
eurjchem-2463	234	3	,	,	PUNCT
eurjchem-2463	234	4	25	25	NUM
eurjchem-2463	234	5	,	,	PUNCT
eurjchem-2463	234	6	1900–1913	1900–1913	NUM
eurjchem-2463	234	7	.	.	PUNCT
eurjchem-2463	235	1	[	[	X
eurjchem-2463	235	2	22	22	NUM
eurjchem-2463	235	3	]	]	PUNCT
eurjchem-2463	235	4	.	.	PUNCT
eurjchem-2463	236	1	oztopcu	oztopcu	ADV
eurjchem-2463	236	2	,	,	PUNCT
eurjchem-2463	236	3	o.	o.	PROPN
eurjchem-2463	236	4	;	;	PUNCT
eurjchem-2463	236	5	holzhacker	holzhacker	PROPN
eurjchem-2463	236	6	,	,	PUNCT
eurjchem-2463	236	7	c.	c.	PROPN
eurjchem-2463	236	8	;	;	PUNCT
eurjchem-2463	236	9	puchberger	puchberger	ADJ
eurjchem-2463	236	10	,	,	PUNCT
eurjchem-2463	236	11	m.	m.	NOUN
eurjchem-2463	236	12	;	;	PUNCT
eurjchem-2463	236	13	weil	weil	PROPN
eurjchem-2463	236	14	,	,	PUNCT
eurjchem-2463	236	15	m.	m.	NOUN
eurjchem-2463	236	16	;	;	PUNCT
eurjchem-2463	236	17	mereiter	mereiter	NOUN
eurjchem-2463	236	18	,	,	PUNCT
eurjchem-2463	236	19	k.	k.	PROPN
eurjchem-2463	236	20	;	;	PUNCT
eurjchem-2463	236	21	veiros	veiros	PROPN
eurjchem-2463	236	22	,	,	PUNCT
eurjchem-2463	236	23	l.	l.	PROPN
eurjchem-2463	236	24	f.	f.	PROPN
eurjchem-2463	236	25	;	;	PUNCT
eurjchem-2463	236	26	kirchner	kirchner	PROPN
eurjchem-2463	236	27	,	,	PUNCT
eurjchem-2463	236	28	k.	k.	NOUN
eurjchem-2463	236	29	synthesis	synthesis	NOUN
eurjchem-2463	236	30	and	and	CCONJ
eurjchem-2463	236	31	characterization	characterization	NOUN
eurjchem-2463	236	32	of	of	ADP
eurjchem-2463	236	33	hydrido	hydrido	NOUN
eurjchem-2463	236	34	carbonyl	carbonyl	NOUN
eurjchem-2463	236	35	molybdenum	molybdenum	NOUN
eurjchem-2463	236	36	and	and	CCONJ
eurjchem-2463	236	37	tungsten	tungsten	VERB
eurjchem-2463	236	38	pnp	pnp	PROPN
eurjchem-2463	236	39	pincer	pincer	NOUN
eurjchem-2463	236	40	complexes	complex	NOUN
eurjchem-2463	236	41	.	.	PUNCT
eurjchem-2463	237	1	organometallics	organometallic	NOUN
eurjchem-2463	237	2	2013	2013	NUM
eurjchem-2463	237	3	,	,	PUNCT
eurjchem-2463	237	4	32	32	NUM
eurjchem-2463	237	5	,	,	PUNCT
eurjchem-2463	237	6	3042–3052	3042–3052	NUM
eurjchem-2463	237	7	.	.	PUNCT
eurjchem-2463	238	1	[	[	X
eurjchem-2463	238	2	23	23	NUM
eurjchem-2463	238	3	]	]	PUNCT
eurjchem-2463	238	4	.	.	PUNCT
eurjchem-2463	239	1	de	de	PROPN
eurjchem-2463	239	2	aguiar	aguiar	PROPN
eurjchem-2463	239	3	,	,	PUNCT
eurjchem-2463	239	4	s.	s.	PROPN
eurjchem-2463	239	5	r.	r.	PROPN
eurjchem-2463	239	6	m.	m.	PROPN
eurjchem-2463	239	7	m.	m.	PROPN
eurjchem-2463	239	8	;	;	PUNCT
eurjchem-2463	239	9	öztopcu	öztopcu	PROPN
eurjchem-2463	239	10	,	,	PUNCT
eurjchem-2463	239	11	ö.	ö.	PROPN
eurjchem-2463	239	12	;	;	PUNCT
eurjchem-2463	239	13	troiani	troiani	PROPN
eurjchem-2463	239	14	,	,	PUNCT
eurjchem-2463	239	15	a.	a.	NOUN
eurjchem-2463	239	16	;	;	PUNCT
eurjchem-2463	239	17	de	de	X
eurjchem-2463	239	18	petris	petris	PROPN
eurjchem-2463	239	19	,	,	PUNCT
eurjchem-2463	239	20	g.	g.	PROPN
eurjchem-2463	239	21	;	;	PUNCT
eurjchem-2463	239	22	weil	weil	PROPN
eurjchem-2463	239	23	,	,	PUNCT
eurjchem-2463	239	24	m.	m.	NOUN
eurjchem-2463	239	25	;	;	PUNCT
eurjchem-2463	239	26	stöger	stöger	ADV
eurjchem-2463	239	27	,	,	PUNCT
eurjchem-2463	239	28	b.	b.	PROPN
eurjchem-2463	239	29	;	;	PUNCT
eurjchem-2463	239	30	pittenauer	pittenauer	PROPN
eurjchem-2463	239	31	,	,	PUNCT
eurjchem-2463	239	32	e.	e.	PROPN
eurjchem-2463	239	33	;	;	PUNCT
eurjchem-2463	239	34	allmaier	allmaier	PROPN
eurjchem-2463	239	35	,	,	PUNCT
eurjchem-2463	239	36	g.	g.	PROPN
eurjchem-2463	239	37	;	;	PUNCT
eurjchem-2463	239	38	veiros	veiros	PROPN
eurjchem-2463	239	39	,	,	PUNCT
eurjchem-2463	239	40	l.	l.	PROPN
eurjchem-2463	239	41	f.	f.	PROPN
eurjchem-2463	239	42	;	;	PUNCT
eurjchem-2463	239	43	kirchner	kirchner	PROPN
eurjchem-2463	239	44	,	,	PUNCT
eurjchem-2463	239	45	k.	k.	PROPN
eurjchem-2463	239	46	formation	formation	NOUN
eurjchem-2463	239	47	of	of	ADP
eurjchem-2463	239	48	mono	mono	PROPN
eurjchem-2463	239	49	oxo	oxo	NOUN
eurjchem-2463	239	50	molybdenum(iv	molybdenum(iv	PROPN
eurjchem-2463	239	51	)	)	PUNCT
eurjchem-2463	239	52	pnp	pnp	NOUN
eurjchem-2463	239	53	pincer	pincer	NOUN
eurjchem-2463	239	54	complexes	complex	NOUN
eurjchem-2463	239	55	:	:	PUNCT
eurjchem-2463	239	56	interplay	interplay	NOUN
eurjchem-2463	239	57	between	between	ADP
eurjchem-2463	239	58	water	water	NOUN
eurjchem-2463	239	59	and	and	CCONJ
eurjchem-2463	239	60	molecular	molecular	ADJ
eurjchem-2463	239	61	oxygen	oxygen	NOUN
eurjchem-2463	239	62	:	:	PUNCT
eurjchem-2463	239	63	formation	formation	NOUN
eurjchem-2463	239	64	of	of	ADP
eurjchem-2463	239	65	mono	mono	PROPN
eurjchem-2463	239	66	oxo	oxo	NOUN
eurjchem-2463	239	67	molybdenum(iv	molybdenum(iv	PROPN
eurjchem-2463	239	68	)	)	PUNCT
eurjchem-2463	239	69	pnp	pnp	NOUN
eurjchem-2463	239	70	pincer	pincer	NOUN
eurjchem-2463	239	71	complexes	complex	NOUN
eurjchem-2463	239	72	:	:	PUNCT
eurjchem-2463	239	73	interplay	interplay	NOUN
eurjchem-2463	239	74	between	between	ADP
eurjchem-2463	239	75	water	water	NOUN
eurjchem-2463	239	76	and	and	CCONJ
eurjchem-2463	239	77	molecular	molecular	ADJ
eurjchem-2463	239	78	oxygen	oxygen	NOUN
eurjchem-2463	239	79	.	.	PUNCT
eurjchem-2463	240	1	eur	eur	PROPN
eurjchem-2463	240	2	.	.	PUNCT
eurjchem-2463	240	3	j.	j.	PROPN
eurjchem-2463	240	4	inorg	inorg	PROPN
eurjchem-2463	240	5	.	.	PUNCT
eurjchem-2463	241	1	chem	chem	PROPN
eurjchem-2463	241	2	.	.	PUNCT
eurjchem-2463	242	1	2018	2018	NUM
eurjchem-2463	242	2	,	,	PUNCT
eurjchem-2463	242	3	2018	2018	NUM
eurjchem-2463	242	4	,	,	PUNCT
eurjchem-2463	242	5	876–884	876–884	NUM
eurjchem-2463	242	6	.	.	PUNCT
eurjchem-2463	243	1	[	[	X
eurjchem-2463	243	2	24	24	NUM
eurjchem-2463	243	3	]	]	PUNCT
eurjchem-2463	243	4	.	.	PUNCT
eurjchem-2463	244	1	aguiar	aguiar	PROPN
eurjchem-2463	244	2	,	,	PUNCT
eurjchem-2463	244	3	s.	s.	PROPN
eurjchem-2463	244	4	r.	r.	PROPN
eurjchem-2463	244	5	m.	m.	PROPN
eurjchem-2463	244	6	m.	m.	PROPN
eurjchem-2463	244	7	de	de	PROPN
eurjchem-2463	244	8	;	;	PUNCT
eurjchem-2463	244	9	stöger	stöger	ADV
eurjchem-2463	244	10	,	,	PUNCT
eurjchem-2463	244	11	b.	b.	PROPN
eurjchem-2463	244	12	;	;	PUNCT
eurjchem-2463	244	13	pittenauer	pittenauer	PROPN
eurjchem-2463	244	14	,	,	PUNCT
eurjchem-2463	244	15	e.	e.	PROPN
eurjchem-2463	244	16	;	;	PUNCT
eurjchem-2463	244	17	allmaier	allmaier	PROPN
eurjchem-2463	244	18	,	,	PUNCT
eurjchem-2463	244	19	g.	g.	PROPN
eurjchem-2463	244	20	;	;	PUNCT
eurjchem-2463	244	21	veiros	veiros	PROPN
eurjchem-2463	244	22	,	,	PUNCT
eurjchem-2463	244	23	l.	l.	PROPN
eurjchem-2463	244	24	f.	f.	PROPN
eurjchem-2463	244	25	;	;	PUNCT
eurjchem-2463	244	26	kirchner	kirchner	PROPN
eurjchem-2463	244	27	,	,	PUNCT
eurjchem-2463	244	28	k.	k.	PROPN
eurjchem-2463	244	29	structural	structural	ADJ
eurjchem-2463	244	30	diversity	diversity	NOUN
eurjchem-2463	244	31	of	of	ADP
eurjchem-2463	244	32	halocarbonyl	halocarbonyl	ADJ
eurjchem-2463	244	33	molybdenum	molybdenum	NOUN
eurjchem-2463	244	34	and	and	CCONJ
eurjchem-2463	244	35	tungsten	tungsten	VERB
eurjchem-2463	244	36	pnp	pnp	PROPN
eurjchem-2463	244	37	pincer	pincer	NOUN
eurjchem-2463	244	38	complexes	complexe	VERB
eurjchem-2463	244	39	through	through	ADP
eurjchem-2463	244	40	ligand	ligand	PROPN
eurjchem-2463	244	41	modifications	modification	NOUN
eurjchem-2463	244	42	.	.	PUNCT
eurjchem-2463	245	1	dalton	dalton	PROPN
eurjchem-2463	245	2	trans	trans	PROPN
eurjchem-2463	245	3	.	.	PROPN
eurjchem-2463	245	4	2016	2016	NUM
eurjchem-2463	245	5	,	,	PUNCT
eurjchem-2463	245	6	45	45	NUM
eurjchem-2463	245	7	,	,	PUNCT
eurjchem-2463	245	8	13834–13845	13834–13845	NUM
eurjchem-2463	245	9	.	.	PUNCT
eurjchem-2463	246	1	[	[	X
eurjchem-2463	246	2	25	25	NUM
eurjchem-2463	246	3	]	]	PUNCT
eurjchem-2463	246	4	.	.	PUNCT
eurjchem-2463	246	5	de	de	X
eurjchem-2463	246	6	aguiar	aguiar	PROPN
eurjchem-2463	246	7	,	,	PUNCT
eurjchem-2463	246	8	s.	s.	PROPN
eurjchem-2463	246	9	r.	r.	PROPN
eurjchem-2463	246	10	m.	m.	PROPN
eurjchem-2463	246	11	m.	m.	PROPN
eurjchem-2463	246	12	;	;	PUNCT
eurjchem-2463	246	13	öztopcu	öztopcu	PROPN
eurjchem-2463	246	14	,	,	PUNCT
eurjchem-2463	246	15	ö.	ö.	NOUN
eurjchem-2463	246	16	;	;	PUNCT
eurjchem-2463	246	17	stöger	stöger	ADV
eurjchem-2463	246	18	,	,	PUNCT
eurjchem-2463	246	19	b.	b.	PROPN
eurjchem-2463	246	20	;	;	PUNCT
eurjchem-2463	246	21	mereiter	mereiter	PROPN
eurjchem-2463	246	22	,	,	PUNCT
eurjchem-2463	246	23	k.	k.	PROPN
eurjchem-2463	246	24	;	;	PUNCT
eurjchem-2463	246	25	veiros	veiros	PROPN
eurjchem-2463	246	26	,	,	PUNCT
eurjchem-2463	246	27	l.	l.	PROPN
eurjchem-2463	246	28	f.	f.	PROPN
eurjchem-2463	246	29	;	;	PUNCT
eurjchem-2463	246	30	pittenauer	pittenauer	PROPN
eurjchem-2463	246	31	,	,	PUNCT
eurjchem-2463	246	32	e.	e.	PROPN
eurjchem-2463	246	33	;	;	PUNCT
eurjchem-2463	246	34	allmaier	allmaier	PROPN
eurjchem-2463	246	35	,	,	PUNCT
eurjchem-2463	246	36	g.	g.	PROPN
eurjchem-2463	246	37	;	;	PUNCT
eurjchem-2463	246	38	kirchner	kirchner	PROPN
eurjchem-2463	246	39	,	,	PUNCT
eurjchem-2463	246	40	k.	k.	NOUN
eurjchem-2463	246	41	synthesis	synthesis	NOUN
eurjchem-2463	246	42	and	and	CCONJ
eurjchem-2463	246	43	reactivity	reactivity	NOUN
eurjchem-2463	246	44	of	of	ADP
eurjchem-2463	246	45	coordinatively	coordinatively	ADV
eurjchem-2463	246	46	unsaturated	unsaturate	VERB
eurjchem-2463	246	47	halocarbonyl	halocarbonyl	ADJ
eurjchem-2463	246	48	molybdenum	molybdenum	NOUN
eurjchem-2463	246	49	pnp	pnp	PROPN
eurjchem-2463	246	50	pincer	pincer	NOUN
eurjchem-2463	246	51	complexes	complex	NOUN
eurjchem-2463	246	52	.	.	PUNCT
eurjchem-2463	247	1	dalton	dalton	PROPN
eurjchem-2463	247	2	trans	trans	PROPN
eurjchem-2463	247	3	.	.	PROPN
eurjchem-2463	247	4	2014	2014	NUM
eurjchem-2463	247	5	,	,	PUNCT
eurjchem-2463	247	6	43	43	NUM
eurjchem-2463	247	7	,	,	PUNCT
eurjchem-2463	247	8	14669–14679	14669–14679	NUM
eurjchem-2463	247	9	.	.	PUNCT
eurjchem-2463	248	1	[	[	X
eurjchem-2463	248	2	26	26	NUM
eurjchem-2463	248	3	]	]	PUNCT
eurjchem-2463	248	4	.	.	PUNCT
eurjchem-2463	248	5	kinoshita	kinoshita	PROPN
eurjchem-2463	248	6	,	,	PUNCT
eurjchem-2463	248	7	e.	e.	PROPN
eurjchem-2463	248	8	;	;	PUNCT
eurjchem-2463	248	9	arashiba	arashiba	PROPN
eurjchem-2463	248	10	,	,	PUNCT
eurjchem-2463	248	11	k.	k.	PROPN
eurjchem-2463	248	12	;	;	PUNCT
eurjchem-2463	248	13	kuriyama	kuriyama	PROPN
eurjchem-2463	248	14	,	,	PUNCT
eurjchem-2463	248	15	s.	s.	PROPN
eurjchem-2463	248	16	;	;	PUNCT
eurjchem-2463	248	17	miyake	miyake	PROPN
eurjchem-2463	248	18	,	,	PUNCT
eurjchem-2463	248	19	y.	y.	PROPN
eurjchem-2463	248	20	;	;	PUNCT
eurjchem-2463	248	21	shimazaki	shimazaki	PROPN
eurjchem-2463	248	22	,	,	PUNCT
eurjchem-2463	248	23	r.	r.	PROPN
eurjchem-2463	248	24	;	;	PUNCT
eurjchem-2463	248	25	nakanishi	nakanishi	PROPN
eurjchem-2463	248	26	,	,	PUNCT
eurjchem-2463	248	27	h.	h.	PROPN
eurjchem-2463	248	28	;	;	PUNCT
eurjchem-2463	248	29	nishibayashi	nishibayashi	PROPN
eurjchem-2463	248	30	,	,	PUNCT
eurjchem-2463	248	31	y.	y.	NOUN
eurjchem-2463	248	32	synthesis	synthesis	NOUN
eurjchem-2463	248	33	and	and	CCONJ
eurjchem-2463	248	34	catalytic	catalytic	ADJ
eurjchem-2463	248	35	activity	activity	NOUN
eurjchem-2463	248	36	of	of	ADP
eurjchem-2463	248	37	molybdenum	molybdenum	NOUN
eurjchem-2463	248	38	–	–	PUNCT
eurjchem-2463	248	39	dinitrogen	dinitrogen	NOUN
eurjchem-2463	248	40	complexes	complex	NOUN
eurjchem-2463	248	41	bearing	bear	VERB
eurjchem-2463	248	42	unsymmetric	unsymmetric	ADJ
eurjchem-2463	248	43	pnp	pnp	NOUN
eurjchem-2463	248	44	-	-	PUNCT
eurjchem-2463	248	45	type	type	NOUN
eurjchem-2463	248	46	pincer	pincer	NOUN
eurjchem-2463	248	47	ligands	ligand	NOUN
eurjchem-2463	248	48	.	.	PUNCT
eurjchem-2463	249	1	organometallics	organometallic	NOUN
eurjchem-2463	249	2	2012	2012	NUM
eurjchem-2463	249	3	,	,	PUNCT
eurjchem-2463	249	4	31	31	NUM
eurjchem-2463	249	5	,	,	PUNCT
eurjchem-2463	249	6	8437–8443	8437–8443	NUM
eurjchem-2463	249	7	.	.	PUNCT
eurjchem-2463	250	1	[	[	X
eurjchem-2463	250	2	27	27	NUM
eurjchem-2463	250	3	]	]	PUNCT
eurjchem-2463	250	4	.	.	PUNCT
eurjchem-2463	251	1	stucke	stucke	PROPN
eurjchem-2463	251	2	,	,	PUNCT
eurjchem-2463	251	3	n.	n.	NOUN
eurjchem-2463	251	4	;	;	PUNCT
eurjchem-2463	251	5	krahmer	krahmer	NOUN
eurjchem-2463	251	6	,	,	PUNCT
eurjchem-2463	251	7	j.	j.	PROPN
eurjchem-2463	251	8	;	;	PUNCT
eurjchem-2463	251	9	näther	näther	PROPN
eurjchem-2463	251	10	,	,	PUNCT
eurjchem-2463	251	11	c.	c.	PROPN
eurjchem-2463	251	12	;	;	PUNCT
eurjchem-2463	251	13	tuczek	tuczek	NOUN
eurjchem-2463	251	14	,	,	PUNCT
eurjchem-2463	251	15	f.	f.	PROPN
eurjchem-2463	251	16	molybdenum	molybdenum	PROPN
eurjchem-2463	251	17	complexes	complex	NOUN
eurjchem-2463	251	18	supported	support	VERB
eurjchem-2463	251	19	by	by	ADP
eurjchem-2463	251	20	pn3p	pn3p	VERB
eurjchem-2463	251	21	pincer	pincer	NOUN
eurjchem-2463	251	22	ligands	ligand	NOUN
eurjchem-2463	251	23	:	:	PUNCT
eurjchem-2463	251	24	synthesis	synthesis	NOUN
eurjchem-2463	251	25	,	,	PUNCT
eurjchem-2463	251	26	characterization	characterization	NOUN
eurjchem-2463	251	27	,	,	PUNCT
eurjchem-2463	251	28	and	and	CCONJ
eurjchem-2463	251	29	application	application	NOUN
eurjchem-2463	251	30	to	to	ADP
eurjchem-2463	251	31	synthetic	synthetic	ADJ
eurjchem-2463	251	32	nitrogen	nitrogen	NOUN
eurjchem-2463	251	33	fixation	fixation	NOUN
eurjchem-2463	251	34	:	:	PUNCT
eurjchem-2463	251	35	molybdenum	molybdenum	NOUN
eurjchem-2463	251	36	complexes	complex	NOUN
eurjchem-2463	251	37	supported	support	VERB
eurjchem-2463	251	38	by	by	ADP
eurjchem-2463	251	39	pn3p	pn3p	VERB
eurjchem-2463	251	40	pincer	pincer	NOUN
eurjchem-2463	251	41	ligands	ligand	NOUN
eurjchem-2463	251	42	:	:	PUNCT
eurjchem-2463	251	43	synthesis	synthesis	NOUN
eurjchem-2463	251	44	,	,	PUNCT
eurjchem-2463	251	45	characterization	characterization	NOUN
eurjchem-2463	251	46	,	,	PUNCT
eurjchem-2463	251	47	and	and	CCONJ
eurjchem-2463	251	48	application	application	NOUN
eurjchem-2463	251	49	to	to	ADP
eurjchem-2463	251	50	synthetic	synthetic	ADJ
eurjchem-2463	251	51	nitrogen	nitrogen	NOUN
eurjchem-2463	251	52	fixation	fixation	NOUN
eurjchem-2463	251	53	.	.	PUNCT
eurjchem-2463	252	1	eur	eur	PROPN
eurjchem-2463	252	2	.	.	PUNCT
eurjchem-2463	253	1	j.	j.	PROPN
eurjchem-2463	253	2	inorg	inorg	PROPN
eurjchem-2463	253	3	.	.	PUNCT
eurjchem-2463	254	1	chem	chem	PROPN
eurjchem-2463	254	2	.	.	PUNCT
eurjchem-2463	255	1	2018	2018	NUM
eurjchem-2463	255	2	,	,	PUNCT
eurjchem-2463	255	3	2018	2018	NUM
eurjchem-2463	255	4	,	,	PUNCT
eurjchem-2463	255	5	5108–5116	5108–5116	NUM
eurjchem-2463	255	6	.	.	PUNCT
eurjchem-2463	256	1	[	[	X
eurjchem-2463	256	2	28	28	NUM
eurjchem-2463	256	3	]	]	PUNCT
eurjchem-2463	256	4	.	.	PUNCT
eurjchem-2463	257	1	itabashi	itabashi	PROPN
eurjchem-2463	257	2	,	,	PUNCT
eurjchem-2463	257	3	t.	t.	PROPN
eurjchem-2463	257	4	;	;	PUNCT
eurjchem-2463	257	5	mori	mori	PROPN
eurjchem-2463	257	6	,	,	PUNCT
eurjchem-2463	257	7	i.	i.	PROPN
eurjchem-2463	257	8	;	;	PUNCT
eurjchem-2463	257	9	arashiba	arashiba	PROPN
eurjchem-2463	257	10	,	,	PUNCT
eurjchem-2463	257	11	k.	k.	PROPN
eurjchem-2463	257	12	;	;	PUNCT
eurjchem-2463	257	13	eizawa	eizawa	PROPN
eurjchem-2463	257	14	,	,	PUNCT
eurjchem-2463	257	15	a.	a.	NOUN
eurjchem-2463	257	16	;	;	PUNCT
eurjchem-2463	257	17	nakajima	nakajima	PROPN
eurjchem-2463	257	18	,	,	PUNCT
eurjchem-2463	257	19	k.	k.	PROPN
eurjchem-2463	257	20	;	;	PUNCT
eurjchem-2463	257	21	nishibayashi	nishibayashi	PROPN
eurjchem-2463	257	22	,	,	PUNCT
eurjchem-2463	257	23	y.	y.	NOUN
eurjchem-2463	257	24	effect	effect	NOUN
eurjchem-2463	257	25	of	of	ADP
eurjchem-2463	257	26	substituents	substituent	NOUN
eurjchem-2463	257	27	on	on	ADP
eurjchem-2463	257	28	molybdenum	molybdenum	NOUN
eurjchem-2463	257	29	triiodide	triiodide	NOUN
eurjchem-2463	257	30	complexes	complex	NOUN
eurjchem-2463	257	31	bearing	bear	VERB
eurjchem-2463	257	32	pnp	pnp	NOUN
eurjchem-2463	257	33	-	-	PUNCT
eurjchem-2463	257	34	type	type	NOUN
eurjchem-2463	257	35	pincer	pincer	NOUN
eurjchem-2463	257	36	ligands	ligand	NOUN
eurjchem-2463	257	37	toward	toward	ADP
eurjchem-2463	257	38	catalytic	catalytic	ADJ
eurjchem-2463	257	39	nitrogen	nitrogen	NOUN
eurjchem-2463	257	40	fixation	fixation	NOUN
eurjchem-2463	257	41	.	.	PUNCT
eurjchem-2463	258	1	dalton	dalton	PROPN
eurjchem-2463	258	2	trans	trans	PROPN
eurjchem-2463	258	3	.	.	PROPN
eurjchem-2463	259	1	2019	2019	NUM
eurjchem-2463	259	2	,	,	PUNCT
eurjchem-2463	259	3	48	48	NUM
eurjchem-2463	259	4	,	,	PUNCT
eurjchem-2463	259	5	3182–3186	3182–3186	NUM
eurjchem-2463	259	6	.	.	PUNCT
eurjchem-2463	260	1	[	[	X
eurjchem-2463	260	2	29	29	NUM
eurjchem-2463	260	3	]	]	PUNCT
eurjchem-2463	260	4	.	.	PUNCT
eurjchem-2463	261	1	schirmer	schirmer	PROPN
eurjchem-2463	261	2	,	,	PUNCT
eurjchem-2463	261	3	w.	w.	PROPN
eurjchem-2463	261	4	;	;	PUNCT
eurjchem-2463	261	5	flörke	flörke	PROPN
eurjchem-2463	261	6	,	,	PUNCT
eurjchem-2463	261	7	u.	u.	PROPN
eurjchem-2463	261	8	;	;	PUNCT
eurjchem-2463	261	9	haupt	haupt	PROPN
eurjchem-2463	261	10	,	,	PUNCT
eurjchem-2463	261	11	h.-j	h.-j	PROPN
eurjchem-2463	261	12	.	.	PUNCT
eurjchem-2463	262	1	darstellung	darstellung	PROPN
eurjchem-2463	262	2	,	,	PUNCT
eurjchem-2463	262	3	eigenschaften	eigenschaften	VERB
eurjchem-2463	262	4	und	und	PROPN
eurjchem-2463	262	5	molekülstrukturen	molekülstrukturen	PROPN
eurjchem-2463	262	6	von	von	PROPN
eurjchem-2463	262	7	komplexen	komplexen	PROPN
eurjchem-2463	262	8	des	des	PROPN
eurjchem-2463	262	9	versteiften	versteiften	PROPN
eurjchem-2463	262	10	dreizähnigen	dreizähnigen	VERB
eurjchem-2463	262	11	chelatliganden	chelatliganden	PROPN
eurjchem-2463	262	12	n	n	CCONJ
eurjchem-2463	262	13	,	,	PUNCT
eurjchem-2463	262	14	n’-bis(diphenylphosphino)-2,6	n’-bis(diphenylphosphino)-2,6	PROPN
eurjchem-2463	262	15	-	-	PUNCT
eurjchem-2463	262	16	diaminopyridin	diaminopyridin	VERB
eurjchem-2463	262	17	mit	mit	NOUN
eurjchem-2463	262	18	mii	mii	PROPN
eurjchem-2463	262	19	und	und	VERB
eurjchem-2463	262	20	m0	m0	NOUN
eurjchem-2463	262	21	-	-	PUNCT
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eurjchem-2463	263	1	[	[	X
eurjchem-2463	263	2	mii	mii	NOUN
eurjchem-2463	263	3	=	=	SYM
eurjchem-2463	263	4	ni	ni	PROPN
eurjchem-2463	263	5	,	,	PUNCT
eurjchem-2463	263	6	pd	pd	PROPN
eurjchem-2463	263	7	,	,	PUNCT
eurjchem-2463	263	8	pt	pt	PROPN
eurjchem-2463	263	9	;	;	PUNCT
eurjchem-2463	263	10	m0	m0	PROPN
eurjchem-2463	263	11	=	=	SYM
eurjchem-2463	263	12	cr	cr	PROPN
eurjchem-2463	263	13	,	,	PUNCT
eurjchem-2463	263	14	mo	mo	PROPN
eurjchem-2463	263	15	,	,	PUNCT
eurjchem-2463	263	16	w	w	NOUN
eurjchem-2463	263	17	]	]	PUNCT
eurjchem-2463	263	18	.	.	PUNCT
eurjchem-2463	264	1	z.	z.	PROPN
eurjchem-2463	264	2	anorg	anorg	PROPN
eurjchem-2463	264	3	.	.	PUNCT
eurjchem-2463	265	1	allg	allg	PROPN
eurjchem-2463	265	2	.	.	PUNCT
eurjchem-2463	266	1	chem	chem	NOUN
eurjchem-2463	266	2	.	.	PUNCT
eurjchem-2463	267	1	1987	1987	NUM
eurjchem-2463	267	2	,	,	PUNCT
eurjchem-2463	267	3	545	545	NUM
eurjchem-2463	267	4	,	,	PUNCT
eurjchem-2463	267	5	83–97	83–97	NUM
eurjchem-2463	267	6	.	.	PUNCT
eurjchem-2463	268	1	[	[	X
eurjchem-2463	268	2	30	30	NUM
eurjchem-2463	268	3	]	]	PUNCT
eurjchem-2463	268	4	.	.	PUNCT
eurjchem-2463	269	1	bruker	bruker	PROPN
eurjchem-2463	269	2	(	(	PUNCT
eurjchem-2463	269	3	1997	1997	NUM
eurjchem-2463	269	4	-	-	SYM
eurjchem-2463	269	5	2003	2003	NUM
eurjchem-2463	269	6	)	)	PUNCT
eurjchem-2463	269	7	.	.	PUNCT
eurjchem-2463	270	1	saint	saint	PROPN
eurjchem-2463	270	2	.	.	PUNCT
eurjchem-2463	271	1	bruker	bruker	PROPN
eurjchem-2463	271	2	axs	axs	PROPN
eurjchem-2463	271	3	inc	inc	PROPN
eurjchem-2463	271	4	.	.	PROPN
eurjchem-2463	271	5	,	,	PUNCT
eurjchem-2463	271	6	madison	madison	PROPN
eurjchem-2463	271	7	,	,	PUNCT
eurjchem-2463	271	8	wisconsin	wisconsin	PROPN
eurjchem-2463	271	9	,	,	PUNCT
eurjchem-2463	271	10	usa	usa	PROPN
eurjchem-2463	271	11	.	.	PUNCT
eurjchem-2463	272	1	[	[	X
eurjchem-2463	272	2	31	31	NUM
eurjchem-2463	272	3	]	]	PUNCT
eurjchem-2463	272	4	.	.	PUNCT
eurjchem-2463	272	5	sheldrick	sheldrick	NOUN
eurjchem-2463	272	6	,	,	PUNCT
eurjchem-2463	272	7	g.	g.	PROPN
eurjchem-2463	272	8	m.	m.	PROPN
eurjchem-2463	272	9	sadabs	sadabs	PROPN
eurjchem-2463	272	10	,	,	PUNCT
eurjchem-2463	272	11	program	program	NOUN
eurjchem-2463	272	12	for	for	ADP
eurjchem-2463	272	13	empirical	empirical	ADJ
eurjchem-2463	272	14	absorption	absorption	NOUN
eurjchem-2463	272	15	corrections	correction	NOUN
eurjchem-2463	272	16	,	,	PUNCT
eurjchem-2463	272	17	university	university	NOUN
eurjchem-2463	272	18	of	of	ADP
eurjchem-2463	272	19	göttingen	göttingen	NOUN
eurjchem-2463	272	20	,	,	PUNCT
eurjchem-2463	272	21	1996	1996	NUM
eurjchem-2463	272	22	.	.	PUNCT
eurjchem-2463	273	1	[	[	X
eurjchem-2463	273	2	32	32	NUM
eurjchem-2463	273	3	]	]	PUNCT
eurjchem-2463	273	4	.	.	PUNCT
eurjchem-2463	274	1	altomare	altomare	PROPN
eurjchem-2463	274	2	,	,	PUNCT
eurjchem-2463	274	3	a.	a.	NOUN
eurjchem-2463	274	4	;	;	PUNCT
eurjchem-2463	274	5	burla	burla	PROPN
eurjchem-2463	274	6	,	,	PUNCT
eurjchem-2463	274	7	m.	m.	PROPN
eurjchem-2463	274	8	c.	c.	PROPN
eurjchem-2463	274	9	;	;	PUNCT
eurjchem-2463	274	10	camalli	camalli	PROPN
eurjchem-2463	274	11	,	,	PUNCT
eurjchem-2463	274	12	m.	m.	NOUN
eurjchem-2463	274	13	;	;	PUNCT
eurjchem-2463	274	14	cascarano	cascarano	PROPN
eurjchem-2463	274	15	,	,	PUNCT
eurjchem-2463	274	16	g.	g.	PROPN
eurjchem-2463	274	17	l.	l.	PROPN
eurjchem-2463	274	18	;	;	PUNCT
eurjchem-2463	274	19	giacovazzo	giacovazzo	PROPN
eurjchem-2463	274	20	,	,	PUNCT
eurjchem-2463	274	21	c.	c.	NOUN
eurjchem-2463	274	22	;	;	PUNCT
eurjchem-2463	274	23	guagliardi	guagliardi	PROPN
eurjchem-2463	274	24	,	,	PUNCT
eurjchem-2463	274	25	a.	a.	NOUN
eurjchem-2463	274	26	;	;	PUNCT
eurjchem-2463	274	27	moliterni	moliterni	PROPN
eurjchem-2463	274	28	,	,	PUNCT
eurjchem-2463	274	29	a.	a.	PROPN
eurjchem-2463	274	30	g.	g.	PROPN
eurjchem-2463	274	31	g.	g.	PROPN
eurjchem-2463	274	32	;	;	PUNCT
eurjchem-2463	274	33	polidori	polidori	PROPN
eurjchem-2463	274	34	,	,	PUNCT
eurjchem-2463	274	35	g.	g.	PROPN
eurjchem-2463	274	36	;	;	PUNCT
eurjchem-2463	274	37	spagna	spagna	PROPN
eurjchem-2463	274	38	,	,	PUNCT
eurjchem-2463	274	39	r.	r.	PROPN
eurjchem-2463	274	40	sir97	sir97	PROPN
eurjchem-2463	274	41	:	:	PUNCT
eurjchem-2463	274	42	a	a	DET
eurjchem-2463	274	43	new	new	ADJ
eurjchem-2463	274	44	tool	tool	NOUN
eurjchem-2463	274	45	for	for	ADP
eurjchem-2463	274	46	crystal	crystal	NOUN
eurjchem-2463	274	47	structure	structure	NOUN
eurjchem-2463	274	48	determination	determination	NOUN
eurjchem-2463	274	49	and	and	CCONJ
eurjchem-2463	274	50	refinement	refinement	NOUN
eurjchem-2463	274	51	.	.	PUNCT
eurjchem-2463	275	1	j.	j.	PROPN
eurjchem-2463	275	2	appl	appl	PROPN
eurjchem-2463	275	3	.	.	PROPN
eurjchem-2463	275	4	crystallogr	crystallogr	PROPN
eurjchem-2463	275	5	.	.	PUNCT
eurjchem-2463	276	1	1999	1999	NUM
eurjchem-2463	276	2	,	,	PUNCT
eurjchem-2463	276	3	32	32	NUM
eurjchem-2463	276	4	,	,	PUNCT
eurjchem-2463	276	5	115–119	115–119	NUM
eurjchem-2463	276	6	.	.	PUNCT
eurjchem-2463	277	1	[	[	X
eurjchem-2463	277	2	33	33	NUM
eurjchem-2463	277	3	]	]	PUNCT
eurjchem-2463	277	4	.	.	PUNCT
eurjchem-2463	277	5	sheldrick	sheldrick	NOUN
eurjchem-2463	277	6	,	,	PUNCT
eurjchem-2463	277	7	g.	g.	PROPN
eurjchem-2463	277	8	m.	m.	PROPN
eurjchem-2463	277	9	crystal	crystal	PROPN
eurjchem-2463	277	10	structure	structure	NOUN
eurjchem-2463	277	11	refinement	refinement	NOUN
eurjchem-2463	277	12	with	with	ADP
eurjchem-2463	277	13	shelxl	shelxl	NOUN
eurjchem-2463	277	14	.	.	PUNCT
eurjchem-2463	278	1	acta	acta	PROPN
eurjchem-2463	278	2	crystallogr	crystallogr	PROPN
eurjchem-2463	278	3	.	.	PUNCT
eurjchem-2463	279	1	c	c	PROPN
eurjchem-2463	279	2	struct	struct	NOUN
eurjchem-2463	279	3	.	.	PUNCT
eurjchem-2463	280	1	chem	chem	NOUN
eurjchem-2463	280	2	.	.	PUNCT
eurjchem-2463	281	1	2015	2015	NUM
eurjchem-2463	281	2	,	,	PUNCT
eurjchem-2463	281	3	71	71	NUM
eurjchem-2463	281	4	,	,	PUNCT
eurjchem-2463	281	5	3–8	3–8	NUM
eurjchem-2463	281	6	.	.	PUNCT
eurjchem-2463	282	1	[	[	X
eurjchem-2463	282	2	34	34	NUM
eurjchem-2463	282	3	]	]	PUNCT
eurjchem-2463	282	4	.	.	PUNCT
eurjchem-2463	283	1	farrugia	farrugia	PROPN
eurjchem-2463	283	2	,	,	PUNCT
eurjchem-2463	283	3	l.	l.	PROPN
eurjchem-2463	283	4	j.	j.	PROPN
eurjchem-2463	283	5	wingx	wingx	PROPN
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eurjchem-2463	283	8	for	for	ADP
eurjchem-2463	283	9	windows	window	NOUN
eurjchem-2463	283	10	:	:	PUNCT
eurjchem-2463	283	11	an	an	DET
eurjchem-2463	283	12	update	update	NOUN
eurjchem-2463	283	13	.	.	PUNCT
eurjchem-2463	284	1	j.	j.	PROPN
eurjchem-2463	284	2	appl	appl	PROPN
eurjchem-2463	284	3	.	.	PROPN
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eurjchem-2463	284	5	.	.	PUNCT
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eurjchem-2463	285	2	,	,	PUNCT
eurjchem-2463	285	3	45	45	NUM
eurjchem-2463	285	4	,	,	PUNCT
eurjchem-2463	285	5	849–854	849–854	NUM
eurjchem-2463	285	6	.	.	PUNCT
eurjchem-2463	286	1	[	[	X
eurjchem-2463	286	2	35	35	NUM
eurjchem-2463	286	3	]	]	PUNCT
eurjchem-2463	286	4	.	.	PUNCT
eurjchem-2463	287	1	spek	spek	PROPN
eurjchem-2463	287	2	,	,	PUNCT
eurjchem-2463	287	3	a.	a.	PROPN
eurjchem-2463	287	4	l.	l.	PROPN
eurjchem-2463	287	5	structure	structure	PROPN
eurjchem-2463	287	6	validation	validation	NOUN
eurjchem-2463	287	7	in	in	ADP
eurjchem-2463	287	8	chemical	chemical	ADJ
eurjchem-2463	287	9	crystallography	crystallography	NOUN
eurjchem-2463	287	10	.	.	PUNCT
eurjchem-2463	288	1	acta	acta	PROPN
eurjchem-2463	288	2	crystallogr	crystallogr	PROPN
eurjchem-2463	288	3	.	.	PUNCT
eurjchem-2463	289	1	d	d	X
eurjchem-2463	289	2	biol	biol	PROPN
eurjchem-2463	289	3	.	.	PUNCT
eurjchem-2463	290	1	crystallogr	crystallogr	PROPN
eurjchem-2463	290	2	.	.	PUNCT
eurjchem-2463	291	1	2009	2009	NUM
eurjchem-2463	291	2	,	,	PUNCT
eurjchem-2463	291	3	65	65	NUM
eurjchem-2463	291	4	,	,	PUNCT
eurjchem-2463	291	5	148–155	148–155	NUM
eurjchem-2463	291	6	.	.	PUNCT
eurjchem-2463	292	1	[	[	X
eurjchem-2463	292	2	36	36	NUM
eurjchem-2463	292	3	]	]	PUNCT
eurjchem-2463	292	4	.	.	PUNCT
eurjchem-2463	293	1	farrugia	farrugia	PROPN
eurjchem-2463	293	2	,	,	PUNCT
eurjchem-2463	293	3	l.	l.	PROPN
eurjchem-2463	293	4	j.	j.	PROPN
eurjchem-2463	293	5	ortep-3	ortep-3	PROPN
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eurjchem-2463	293	7	windows	window	NOUN
eurjchem-2463	293	8	a	a	DET
eurjchem-2463	293	9	version	version	NOUN
eurjchem-2463	293	10	of	of	ADP
eurjchem-2463	293	11	ortep	ortep	NOUN
eurjchem-2463	293	12	-	-	PUNCT
eurjchem-2463	293	13	iii	iii	NOUN
eurjchem-2463	293	14	with	with	ADP
eurjchem-2463	293	15	a	a	DET
eurjchem-2463	293	16	graphical	graphical	ADJ
eurjchem-2463	293	17	user	user	NOUN
eurjchem-2463	293	18	interface	interface	NOUN
eurjchem-2463	293	19	(	(	PUNCT
eurjchem-2463	293	20	gui	gui	PROPN
eurjchem-2463	293	21	)	)	PUNCT
eurjchem-2463	293	22	.	.	PUNCT
eurjchem-2463	294	1	j.	j.	PROPN
eurjchem-2463	294	2	appl	appl	PROPN
eurjchem-2463	294	3	.	.	PROPN
eurjchem-2463	294	4	crystallogr	crystallogr	PROPN
eurjchem-2463	294	5	.	.	PUNCT
eurjchem-2463	295	1	1997	1997	NUM
eurjchem-2463	295	2	,	,	PUNCT
eurjchem-2463	295	3	30	30	NUM
eurjchem-2463	295	4	,	,	PUNCT
eurjchem-2463	295	5	565–565	565–565	NUM
eurjchem-2463	295	6	.	.	PUNCT
eurjchem-2463	296	1	[	[	X
eurjchem-2463	296	2	37	37	NUM
eurjchem-2463	296	3	]	]	PUNCT
eurjchem-2463	296	4	.	.	PUNCT
eurjchem-2463	297	1	gong	gong	PROPN
eurjchem-2463	297	2	,	,	PUNCT
eurjchem-2463	297	3	d.	d.	PROPN
eurjchem-2463	297	4	;	;	PUNCT
eurjchem-2463	297	5	liu	liu	PROPN
eurjchem-2463	297	6	,	,	PUNCT
eurjchem-2463	297	7	w.	w.	PROPN
eurjchem-2463	297	8	;	;	PUNCT
eurjchem-2463	297	9	chen	chen	PROPN
eurjchem-2463	297	10	,	,	PUNCT
eurjchem-2463	297	11	t.	t.	PROPN
eurjchem-2463	297	12	;	;	PUNCT
eurjchem-2463	297	13	chen	chen	PROPN
eurjchem-2463	297	14	,	,	PUNCT
eurjchem-2463	297	15	z.-r	z.-r	PROPN
eurjchem-2463	297	16	.	.	PROPN
eurjchem-2463	297	17	;	;	PUNCT
eurjchem-2463	297	18	huang	huang	PROPN
eurjchem-2463	297	19	,	,	PUNCT
eurjchem-2463	297	20	k.-w	k.-w	PROPN
eurjchem-2463	297	21	.	.	PUNCT
eurjchem-2463	298	1	ethylene	ethylene	NOUN
eurjchem-2463	298	2	polymerization	polymerization	NOUN
eurjchem-2463	298	3	by	by	ADP
eurjchem-2463	298	4	pn3	pn3	NOUN
eurjchem-2463	298	5	-	-	PUNCT
eurjchem-2463	298	6	type	type	NOUN
eurjchem-2463	298	7	pincer	pincer	NOUN
eurjchem-2463	298	8	chromium(iii	chromium(iii	NOUN
eurjchem-2463	298	9	)	)	PUNCT
eurjchem-2463	298	10	complexes	complex	NOUN
eurjchem-2463	298	11	.	.	PUNCT
eurjchem-2463	299	1	j.	j.	PROPN
eurjchem-2463	299	2	mol	mol	PROPN
eurjchem-2463	299	3	.	.	PROPN
eurjchem-2463	299	4	catal	catal	PROPN
eurjchem-2463	299	5	.	.	PUNCT
eurjchem-2463	300	1	a	a	DET
eurjchem-2463	300	2	chem	chem	NOUN
eurjchem-2463	300	3	.	.	PUNCT
eurjchem-2463	301	1	2014	2014	NUM
eurjchem-2463	301	2	,	,	PUNCT
eurjchem-2463	301	3	395	395	NUM
eurjchem-2463	301	4	,	,	PUNCT
eurjchem-2463	301	5	100–107	100–107	NUM
eurjchem-2463	301	6	.	.	PUNCT
eurjchem-2463	302	1	[	[	X
eurjchem-2463	302	2	38	38	NUM
eurjchem-2463	302	3	]	]	PUNCT
eurjchem-2463	302	4	.	.	PUNCT
eurjchem-2463	302	5	alzamly	alzamly	PROPN
eurjchem-2463	302	6	,	,	PUNCT
eurjchem-2463	302	7	a.	a.	NOUN
eurjchem-2463	302	8	;	;	PUNCT
eurjchem-2463	302	9	gambarotta	gambarotta	PROPN
eurjchem-2463	302	10	,	,	PUNCT
eurjchem-2463	302	11	s.	s.	PROPN
eurjchem-2463	302	12	;	;	PUNCT
eurjchem-2463	302	13	korobkov	korobkov	PROPN
eurjchem-2463	302	14	,	,	PUNCT
eurjchem-2463	302	15	i.	i.	NOUN
eurjchem-2463	302	16	synthesis	synthesis	PROPN
eurjchem-2463	302	17	,	,	PUNCT
eurjchem-2463	302	18	structures	structure	NOUN
eurjchem-2463	302	19	,	,	PUNCT
eurjchem-2463	302	20	and	and	CCONJ
eurjchem-2463	302	21	ethylene	ethylene	NOUN
eurjchem-2463	302	22	oligomerization	oligomerization	NOUN
eurjchem-2463	302	23	activity	activity	NOUN
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eurjchem-2463	302	25	bis(phosphanylamine)pyridine	bis(phosphanylamine)pyridine	NUM
eurjchem-2463	302	26	chromium	chromium	NOUN
eurjchem-2463	302	27	/	/	SYM
eurjchem-2463	302	28	aluminate	aluminate	NOUN
eurjchem-2463	302	29	complexes	complex	NOUN
eurjchem-2463	302	30	.	.	PUNCT
eurjchem-2463	303	1	organometallics	organometallic	NOUN
eurjchem-2463	303	2	2013	2013	NUM
eurjchem-2463	303	3	,	,	PUNCT
eurjchem-2463	303	4	32	32	NUM
eurjchem-2463	303	5	,	,	PUNCT
eurjchem-2463	303	6	7107	7107	NUM
eurjchem-2463	303	7	–	–	PUNCT
eurjchem-2463	303	8	7115	7115	NUM
eurjchem-2463	303	9	.	.	PUNCT
eurjchem-2463	304	1	[	[	X
eurjchem-2463	304	2	39	39	NUM
eurjchem-2463	304	3	]	]	PUNCT
eurjchem-2463	304	4	.	.	PUNCT
eurjchem-2463	305	1	matayoshi	matayoshi	ADJ
eurjchem-2463	305	2	,	,	PUNCT
eurjchem-2463	305	3	k.	k.	PROPN
eurjchem-2463	305	4	;	;	PUNCT
eurjchem-2463	305	5	seragaki	seragaki	PROPN
eurjchem-2463	305	6	,	,	PUNCT
eurjchem-2463	305	7	m.	m.	NOUN
eurjchem-2463	305	8	;	;	PUNCT
eurjchem-2463	305	9	mukai	mukai	PROPN
eurjchem-2463	305	10	,	,	PUNCT
eurjchem-2463	305	11	k.	k.	PROPN
eurjchem-2463	305	12	;	;	PUNCT
eurjchem-2463	305	13	asato	asato	PROPN
eurjchem-2463	305	14	,	,	PUNCT
eurjchem-2463	305	15	e.	e.	PROPN
eurjchem-2463	305	16	;	;	PUNCT
eurjchem-2463	305	17	takara	takara	PROPN
eurjchem-2463	305	18	,	,	PUNCT
eurjchem-2463	305	19	s.	s.	PROPN
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eurjchem-2463	305	23	structure	structure	NOUN
eurjchem-2463	305	24	of	of	ADP
eurjchem-2463	305	25	[	[	X
eurjchem-2463	305	26	rucl3{n	rucl3{n	NOUN
eurjchem-2463	305	27	,	,	PUNCT
eurjchem-2463	305	28	n′-bis(diphenylphosphino)-2,6diaminopyridine}]·3ch3oh	n′-bis(diphenylphosphino)-2,6diaminopyridine}]·3ch3oh	PROPN
eurjchem-2463	305	29	.	.	PUNCT
eurjchem-2463	306	1	x	x	X
eurjchem-2463	306	2	-	-	PUNCT
eurjchem-2463	306	3	ray	ray	NOUN
eurjchem-2463	306	4	struct	struct	NOUN
eurjchem-2463	306	5	.	.	PUNCT
eurjchem-2463	307	1	anal	anal	PROPN
eurjchem-2463	307	2	.	.	PUNCT
eurjchem-2463	308	1	online	online	ADJ
eurjchem-2463	308	2	2012	2012	NUM
eurjchem-2463	308	3	,	,	PUNCT
eurjchem-2463	308	4	28	28	NUM
eurjchem-2463	308	5	,	,	PUNCT
eurjchem-2463	308	6	57	57	NUM
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eurjchem-2463	308	8	58	58	NUM
eurjchem-2463	308	9	.	.	PUNCT
eurjchem-2463	309	1	[	[	X
eurjchem-2463	309	2	40	40	NUM
eurjchem-2463	309	3	]	]	PUNCT
eurjchem-2463	309	4	.	.	PUNCT
eurjchem-2463	310	1	haupt	haupt	PROPN
eurjchem-2463	310	2	,	,	PUNCT
eurjchem-2463	310	3	h.-j	h.-j	PROPN
eurjchem-2463	310	4	.	.	PUNCT
eurjchem-2463	310	5	;	;	PUNCT
eurjchem-2463	310	6	flörke	flörke	PROPN
eurjchem-2463	310	7	,	,	PUNCT
eurjchem-2463	310	8	u.	u.	PROPN
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eurjchem-2463	310	12	n	n	CCONJ
eurjchem-2463	310	13	,	,	PUNCT
eurjchem-2463	310	14	n’-bis(diphenyl	n’-bis(diphenyl	ADJ
eurjchem-2463	310	15	phosphino)-2,6	phosphino)-2,6	NOUN
eurjchem-2463	310	16	-	-	PUNCT
eurjchem-2463	310	17	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	310	18	-	-	PUNCT
eurjchem-2463	310	19	trichloroindium(iii	trichloroindium(iii	NOUN
eurjchem-2463	310	20	)	)	PUNCT
eurjchem-2463	310	21	bis-(tetra	bis-(tetra	PROPN
eurjchem-2463	310	22	hydrofurane	hydrofurane	NOUN
eurjchem-2463	310	23	)	)	PUNCT
eurjchem-2463	310	24	,	,	PUNCT
eurjchem-2463	310	25	(	(	PUNCT
eurjchem-2463	310	26	nhp(c6h5)2)2(c5h3n)cl3in(c4h8o)2	nhp(c6h5)2)2(c5h3n)cl3in(c4h8o)2	NOUN
eurjchem-2463	310	27	.	.	PUNCT
eurjchem-2463	310	28	z.	z.	PROPN
eurjchem-2463	310	29	kristallogr	kristallogr	PROPN
eurjchem-2463	310	30	.	.	PUNCT
eurjchem-2463	311	1	cryst	cryst	PROPN
eurjchem-2463	311	2	.	.	PUNCT
eurjchem-2463	312	1	mater	mater	PROPN
eurjchem-2463	312	2	.	.	PROPN
eurjchem-2463	313	1	1991	1991	NUM
eurjchem-2463	313	2	,	,	PUNCT
eurjchem-2463	313	3	196	196	NUM
eurjchem-2463	313	4	,	,	PUNCT
eurjchem-2463	313	5	299–301	299–301	NUM
eurjchem-2463	313	6	.	.	PUNCT
eurjchem-2463	314	1	copyright	copyright	NOUN
eurjchem-2463	314	2	©	©	PROPN
eurjchem-2463	314	3	2023	2023	NUM
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eurjchem-2463	314	5	authors	author	NOUN
eurjchem-2463	314	6	.	.	PUNCT
eurjchem-2463	315	1	this	this	DET
eurjchem-2463	315	2	work	work	NOUN
eurjchem-2463	315	3	is	be	AUX
eurjchem-2463	315	4	published	publish	VERB
eurjchem-2463	315	5	and	and	CCONJ
eurjchem-2463	315	6	licensed	license	VERB
eurjchem-2463	315	7	by	by	ADP
eurjchem-2463	315	8	atlanta	atlanta	PROPN
eurjchem-2463	315	9	publishing	publishing	PROPN
eurjchem-2463	315	10	house	house	PROPN
eurjchem-2463	315	11	llc	llc	PROPN
eurjchem-2463	315	12	,	,	PUNCT
eurjchem-2463	315	13	atlanta	atlanta	PROPN
eurjchem-2463	315	14	,	,	PUNCT
eurjchem-2463	315	15	ga	ga	PROPN
eurjchem-2463	315	16	,	,	PUNCT
eurjchem-2463	315	17	usa	usa	PROPN
eurjchem-2463	315	18	.	.	PUNCT
eurjchem-2463	316	1	the	the	DET
eurjchem-2463	316	2	full	full	ADJ
eurjchem-2463	316	3	terms	term	NOUN
eurjchem-2463	316	4	of	of	ADP
eurjchem-2463	316	5	this	this	DET
eurjchem-2463	316	6	license	license	NOUN
eurjchem-2463	316	7	are	be	AUX
eurjchem-2463	316	8	available	available	ADJ
eurjchem-2463	316	9	at	at	ADP
eurjchem-2463	316	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2463	316	11	and	and	CCONJ
eurjchem-2463	316	12	incorporate	incorporate	VERB
eurjchem-2463	316	13	the	the	DET
eurjchem-2463	316	14	creative	creative	ADJ
eurjchem-2463	316	15	commons	common	NOUN
eurjchem-2463	316	16	attribution	attribution	NOUN
eurjchem-2463	316	17	-	-	PUNCT
eurjchem-2463	316	18	non	non	ADJ
eurjchem-2463	316	19	commercial	commercial	NOUN
eurjchem-2463	316	20	(	(	PUNCT
eurjchem-2463	316	21	cc	cc	NOUN
eurjchem-2463	316	22	by	by	ADP
eurjchem-2463	316	23	nc	nc	PROPN
eurjchem-2463	316	24	)	)	PUNCT
eurjchem-2463	316	25	(	(	PUNCT
eurjchem-2463	316	26	international	international	ADJ
eurjchem-2463	316	27	,	,	PUNCT
eurjchem-2463	316	28	v4.0	v4.0	NOUN
eurjchem-2463	316	29	)	)	PUNCT
eurjchem-2463	316	30	license	license	NOUN
eurjchem-2463	316	31	(	(	PUNCT
eurjchem-2463	316	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2463	316	33	)	)	PUNCT
eurjchem-2463	316	34	.	.	PUNCT
eurjchem-2463	317	1	by	by	ADP
eurjchem-2463	317	2	accessing	access	VERB
eurjchem-2463	317	3	the	the	DET
eurjchem-2463	317	4	work	work	NOUN
eurjchem-2463	317	5	,	,	PUNCT
eurjchem-2463	317	6	you	you	PRON
eurjchem-2463	317	7	hereby	hereby	ADV
eurjchem-2463	317	8	accept	accept	VERB
eurjchem-2463	317	9	the	the	DET
eurjchem-2463	317	10	terms	term	NOUN
eurjchem-2463	317	11	.	.	PUNCT
eurjchem-2463	318	1	this	this	PRON
eurjchem-2463	318	2	is	be	AUX
eurjchem-2463	318	3	an	an	DET
eurjchem-2463	318	4	open	open	ADJ
eurjchem-2463	318	5	access	access	NOUN
eurjchem-2463	318	6	article	article	NOUN
eurjchem-2463	318	7	distributed	distribute	VERB
eurjchem-2463	318	8	under	under	ADP
eurjchem-2463	318	9	the	the	DET
eurjchem-2463	318	10	terms	term	NOUN
eurjchem-2463	318	11	and	and	CCONJ
eurjchem-2463	318	12	conditions	condition	NOUN
eurjchem-2463	318	13	of	of	ADP
eurjchem-2463	318	14	the	the	DET
eurjchem-2463	318	15	cc	cc	PROPN
eurjchem-2463	318	16	by	by	ADP
eurjchem-2463	318	17	nc	nc	PROPN
eurjchem-2463	318	18	license	license	PROPN
eurjchem-2463	318	19	,	,	PUNCT
eurjchem-2463	318	20	which	which	PRON
eurjchem-2463	318	21	permits	permit	VERB
eurjchem-2463	318	22	unrestricted	unrestricted	ADJ
eurjchem-2463	318	23	non	non	ADJ
eurjchem-2463	318	24	-	-	ADJ
eurjchem-2463	318	25	commercial	commercial	ADJ
eurjchem-2463	318	26	use	use	NOUN
eurjchem-2463	318	27	,	,	PUNCT
eurjchem-2463	318	28	distribution	distribution	NOUN
eurjchem-2463	318	29	,	,	PUNCT
eurjchem-2463	318	30	and	and	CCONJ
eurjchem-2463	318	31	reproduction	reproduction	NOUN
eurjchem-2463	318	32	in	in	ADP
eurjchem-2463	318	33	any	any	DET
eurjchem-2463	318	34	medium	medium	NOUN
eurjchem-2463	318	35	,	,	PUNCT
eurjchem-2463	318	36	provided	provide	VERB
eurjchem-2463	318	37	the	the	DET
eurjchem-2463	318	38	original	original	ADJ
eurjchem-2463	318	39	work	work	NOUN
eurjchem-2463	318	40	is	be	AUX
eurjchem-2463	318	41	properly	properly	ADV
eurjchem-2463	318	42	cited	cite	VERB
eurjchem-2463	318	43	without	without	ADP
eurjchem-2463	318	44	any	any	DET
eurjchem-2463	318	45	further	further	ADJ
eurjchem-2463	318	46	permission	permission	NOUN
eurjchem-2463	318	47	from	from	ADP
eurjchem-2463	318	48	atlanta	atlanta	PROPN
eurjchem-2463	318	49	publishing	publishing	PROPN
eurjchem-2463	318	50	house	house	PROPN
eurjchem-2463	318	51	llc	llc	PROPN
eurjchem-2463	318	52	(	(	PUNCT
eurjchem-2463	318	53	european	european	PROPN
eurjchem-2463	318	54	journal	journal	PROPN
eurjchem-2463	318	55	of	of	ADP
eurjchem-2463	318	56	chemistry	chemistry	NOUN
eurjchem-2463	318	57	)	)	PUNCT
eurjchem-2463	318	58	.	.	PUNCT
eurjchem-2463	319	1	no	no	DET
eurjchem-2463	319	2	use	use	NOUN
eurjchem-2463	319	3	,	,	PUNCT
eurjchem-2463	319	4	distribution	distribution	NOUN
eurjchem-2463	319	5	,	,	PUNCT
eurjchem-2463	319	6	or	or	CCONJ
eurjchem-2463	319	7	reproduction	reproduction	NOUN
eurjchem-2463	319	8	is	be	AUX
eurjchem-2463	319	9	permitted	permit	VERB
eurjchem-2463	319	10	which	which	PRON
eurjchem-2463	319	11	does	do	AUX
eurjchem-2463	319	12	not	not	PART
eurjchem-2463	319	13	comply	comply	VERB
eurjchem-2463	319	14	with	with	ADP
eurjchem-2463	319	15	these	these	DET
eurjchem-2463	319	16	terms	term	NOUN
eurjchem-2463	319	17	.	.	PUNCT
eurjchem-2463	320	1	permissions	permission	NOUN
eurjchem-2463	320	2	for	for	ADP
eurjchem-2463	320	3	commercial	commercial	ADJ
eurjchem-2463	320	4	use	use	NOUN
eurjchem-2463	320	5	of	of	ADP
eurjchem-2463	320	6	this	this	DET
eurjchem-2463	320	7	work	work	NOUN
eurjchem-2463	320	8	beyond	beyond	ADP
eurjchem-2463	320	9	the	the	DET
eurjchem-2463	320	10	scope	scope	NOUN
eurjchem-2463	320	11	of	of	ADP
eurjchem-2463	320	12	the	the	DET
eurjchem-2463	320	13	license	license	NOUN
eurjchem-2463	320	14	(	(	PUNCT
eurjchem-2463	320	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2463	320	16	)	)	PUNCT
eurjchem-2463	320	17	are	be	AUX
eurjchem-2463	320	18	administered	administer	VERB
eurjchem-2463	320	19	by	by	ADP
eurjchem-2463	320	20	atlanta	atlanta	PROPN
eurjchem-2463	320	21	publishing	publishing	PROPN
eurjchem-2463	320	22	house	house	PROPN
eurjchem-2463	320	23	llc	llc	PROPN
eurjchem-2463	320	24	(	(	PUNCT
eurjchem-2463	320	25	european	european	PROPN
eurjchem-2463	320	26	journal	journal	PROPN
eurjchem-2463	320	27	of	of	ADP
eurjchem-2463	320	28	chemistry	chemistry	NOUN
eurjchem-2463	320	29	)	)	PUNCT
eurjchem-2463	320	30	.	.	PUNCT
eurjchem-2463	321	1	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2463	321	2	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2463	321	3	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2463	321	4	1	1	NUM
eurjchem-2463	321	5	.	.	PUNCT
eurjchem-2463	321	6	introduction	introduction	NOUN
eurjchem-2463	321	7	2	2	NUM
eurjchem-2463	321	8	.	.	PUNCT
eurjchem-2463	321	9	experimental	experimental	ADJ
eurjchem-2463	321	10	2.1	2.1	NUM
eurjchem-2463	321	11	.	.	PUNCT
eurjchem-2463	322	1	general	general	ADJ
eurjchem-2463	322	2	considerations	consideration	NOUN
eurjchem-2463	322	3	2.2	2.2	NUM
eurjchem-2463	322	4	.	.	PUNCT
eurjchem-2463	323	1	synthesis	synthesis	NOUN
eurjchem-2463	323	2	and	and	CCONJ
eurjchem-2463	323	3	characterization	characterization	NOUN
eurjchem-2463	323	4	2.2.1	2.2.1	NUM
eurjchem-2463	323	5	.	.	PUNCT
eurjchem-2463	324	1	n	n	CCONJ
eurjchem-2463	324	2	,	,	PUNCT
eurjchem-2463	324	3	n’-bis(diphenylphosphino)-2,6	n’-bis(diphenylphosphino)-2,6	NOUN
eurjchem-2463	324	4	-	-	NOUN
eurjchem-2463	324	5	diaminopyridine	diaminopyridine	ADJ
eurjchem-2463	324	6	,	,	PUNCT
eurjchem-2463	324	7	pnp	pnp	NOUN
eurjchem-2463	324	8	-	-	PUNCT
eurjchem-2463	324	9	ph	ph	ADJ
eurjchem-2463	324	10	2.2.2	2.2.2	NUM
eurjchem-2463	324	11	.	.	PUNCT
eurjchem-2463	325	1	n	n	CCONJ
eurjchem-2463	325	2	,	,	PUNCT
eurjchem-2463	325	3	n’-bis(diisopropylphosphino)-2,6	n’-bis(diisopropylphosphino)-2,6	NOUN
eurjchem-2463	325	4	-	-	NOUN
eurjchem-2463	325	5	diaminopyridine	diaminopyridine	NOUN
eurjchem-2463	325	6	,	,	PUNCT
eurjchem-2463	325	7	pnp	pnp	PROPN
eurjchem-2463	325	8	-	-	PUNCT
eurjchem-2463	325	9	ipr	ipr	PROPN
eurjchem-2463	325	10	2.2.3	2.2.3	NUM
eurjchem-2463	325	11	.	.	PUNCT
eurjchem-2463	326	1	[	[	X
eurjchem-2463	326	2	(	(	PUNCT
eurjchem-2463	326	3	pnp	pnp	PROPN
eurjchem-2463	326	4	-	-	PUNCT
eurjchem-2463	326	5	ph)ticl3	ph)ticl3	PROPN
eurjchem-2463	326	6	]	]	PUNCT
eurjchem-2463	326	7	,	,	PUNCT
eurjchem-2463	326	8	1	1	NUM
eurjchem-2463	326	9	2.2.4	2.2.4	NUM
eurjchem-2463	326	10	.	.	PUNCT
eurjchem-2463	327	1	[	[	X
eurjchem-2463	327	2	(	(	PUNCT
eurjchem-2463	327	3	pnp	pnp	PROPN
eurjchem-2463	327	4	-	-	PUNCT
eurjchem-2463	327	5	ipr)mocl3	ipr)mocl3	PROPN
eurjchem-2463	327	6	]	]	PUNCT
eurjchem-2463	327	7	,	,	PUNCT
eurjchem-2463	327	8	2	2	NUM
eurjchem-2463	327	9	2.3	2.3	NUM
eurjchem-2463	327	10	.	.	PUNCT
eurjchem-2463	328	1	general	general	ADJ
eurjchem-2463	328	2	procedure	procedure	NOUN
eurjchem-2463	328	3	for	for	ADP
eurjchem-2463	328	4	x	x	NOUN
eurjchem-2463	328	5	-	-	NOUN
eurjchem-2463	328	6	ray	ray	NOUN
eurjchem-2463	328	7	crystallography	crystallography	NOUN
eurjchem-2463	328	8	3	3	NUM
eurjchem-2463	328	9	.	.	NOUN
eurjchem-2463	328	10	results	result	NOUN
eurjchem-2463	328	11	and	and	CCONJ
eurjchem-2463	328	12	discussion	discussion	NOUN
eurjchem-2463	328	13	4	4	NUM
eurjchem-2463	328	14	.	.	PUNCT
eurjchem-2463	329	1	conclusions	conclusion	NOUN
eurjchem-2463	329	2	acknowledgements	acknowledgement	NOUN
eurjchem-2463	329	3	supporting	support	VERB
eurjchem-2463	329	4	information	information	NOUN
eurjchem-2463	329	5	disclosure	disclosure	NOUN
eurjchem-2463	329	6	statement	statement	NOUN
eurjchem-2463	329	7	credit	credit	NOUN
eurjchem-2463	329	8	authorship	authorship	NOUN
eurjchem-2463	329	9	contribution	contribution	NOUN
eurjchem-2463	329	10	statement	statement	NOUN
eurjchem-2463	329	11	funding	fund	VERB
eurjchem-2463	329	12	orcid	orcid	NOUN
eurjchem-2463	329	13	and	and	CCONJ
eurjchem-2463	329	14	email	email	NOUN
eurjchem-2463	329	15	references	reference	NOUN
eurjchem-2463	329	16	printfield10	printfield10	PROPN
eurjchem-2463	329	17	:	:	PUNCT
eurjchem-2463	329	18	printfield11	printfield11	NOUN
eurjchem-2463	329	19	:	:	PUNCT
eurjchem-2463	329	20	printfield12	printfield12	PROPN
eurjchem-2463	329	21	:	:	PUNCT
eurjchem-2463	329	22	printfield13	printfield13	VERB
eurjchem-2463	329	23	:	:	PUNCT
eurjchem-2463	329	24	printfield14	printfield14	NOUN
eurjchem-2463	329	25	:	:	PUNCT
eurjchem-2463	329	26	printfield20	printfield20	PROPN
eurjchem-2463	329	27	:	:	PUNCT
eurjchem-2463	329	28	printfield21	printfield21	ADJ
eurjchem-2463	329	29	:	:	PUNCT
eurjchem-2463	329	30	printfield22	printfield22	NOUN
eurjchem-2463	329	31	:	:	PUNCT
eurjchem-2463	329	32	printfield23	printfield23	NOUN
eurjchem-2463	329	33	:	:	PUNCT
eurjchem-2463	329	34	printfield24	printfield24	NOUN
eurjchem-2463	329	35	:	:	PUNCT