id	sid	tid	token	lemma	pos
eurjchem-2485	1	1	in	in	ADP
eurjchem-2485	1	2	an	an	DET
eurjchem-2485	1	3	attempt	attempt	NOUN
eurjchem-2485	1	4	to	to	PART
eurjchem-2485	1	5	add	add	VERB
eurjchem-2485	1	6	ligands	ligand	NOUN
eurjchem-2485	1	7	to	to	ADP
eurjchem-2485	1	8	the	the	DET
eurjchem-2485	1	9	sixth	sixth	ADJ
eurjchem-2485	1	10	(	(	PUNCT
eurjchem-2485	1	11	axial	axial	ADJ
eurjchem-2485	1	12	)	)	PUNCT
eurjchem-2485	1	13	position	position	NOUN
eurjchem-2485	1	14	of	of	ADP
eurjchem-2485	1	15	vanadyl	vanadyl	ADJ
eurjchem-2485	1	16	bis	bis	ADJ
eurjchem-2485	1	17	-	-	NOUN
eurjchem-2485	1	18	acetylacetonate	acetylacetonate	ADJ
eurjchem-2485	1	19	:	:	PUNCT
eurjchem-2485	1	20	a	a	DET
eurjchem-2485	1	21	unique	unique	ADJ
eurjchem-2485	1	22	tetranuclear	tetranuclear	ADJ
eurjchem-2485	1	23	vanadyl	vanadyl	NOUN
eurjchem-2485	1	24	species	specie	NOUN
eurjchem-2485	1	25	european	european	PROPN
eurjchem-2485	1	26	journal	journal	PROPN
eurjchem-2485	1	27	of	of	ADP
eurjchem-2485	1	28	chemistry	chemistry	NOUN
eurjchem-2485	1	29	14	14	NUM
eurjchem-2485	1	30	(	(	PUNCT
eurjchem-2485	1	31	4	4	NUM
eurjchem-2485	1	32	)	)	PUNCT
eurjchem-2485	1	33	(	(	PUNCT
eurjchem-2485	1	34	2023	2023	NUM
eurjchem-2485	1	35	)	)	PUNCT
eurjchem-2485	1	36	494	494	NUM
eurjchem-2485	1	37	-	-	SYM
eurjchem-2485	1	38	498	498	NUM
eurjchem-2485	1	39	european	european	ADJ
eurjchem-2485	1	40	journal	journal	PROPN
eurjchem-2485	1	41	of	of	ADP
eurjchem-2485	1	42	chemistry	chemistry	NOUN
eurjchem-2485	1	43	issn	issn	VERB
eurjchem-2485	1	44	2153	2153	NUM
eurjchem-2485	1	45	-	-	SYM
eurjchem-2485	1	46	2249	2249	NUM
eurjchem-2485	1	47	(	(	PUNCT
eurjchem-2485	1	48	print	print	NOUN
eurjchem-2485	1	49	)	)	PUNCT
eurjchem-2485	1	50	/	/	PUNCT
eurjchem-2485	1	51	issn	issn	PROPN
eurjchem-2485	1	52	2153	2153	NUM
eurjchem-2485	1	53	-	-	SYM
eurjchem-2485	1	54	2257	2257	NUM
eurjchem-2485	1	55	(	(	PUNCT
eurjchem-2485	1	56	online	online	ADJ
eurjchem-2485	1	57	)	)	PUNCT
eurjchem-2485	1	58	–	–	PUNCT
eurjchem-2485	2	1	copyright	copyright	NOUN
eurjchem-2485	2	2	©	©	PROPN
eurjchem-2485	2	3	2023	2023	NUM
eurjchem-2485	2	4	the	the	DET
eurjchem-2485	2	5	authors	author	NOUN
eurjchem-2485	2	6	–	–	PUNCT
eurjchem-2485	2	7	atlanta	atlanta	PROPN
eurjchem-2485	2	8	publishing	publishing	PROPN
eurjchem-2485	2	9	house	house	PROPN
eurjchem-2485	2	10	llc	llc	PROPN
eurjchem-2485	2	11	–	–	PUNCT
eurjchem-2485	2	12	printed	print	VERB
eurjchem-2485	2	13	in	in	ADP
eurjchem-2485	2	14	the	the	DET
eurjchem-2485	2	15	usa	usa	PROPN
eurjchem-2485	2	16	.	.	PUNCT
eurjchem-2485	3	1	this	this	DET
eurjchem-2485	3	2	work	work	NOUN
eurjchem-2485	3	3	is	be	AUX
eurjchem-2485	3	4	published	publish	VERB
eurjchem-2485	3	5	and	and	CCONJ
eurjchem-2485	3	6	licensed	license	VERB
eurjchem-2485	3	7	by	by	ADP
eurjchem-2485	3	8	atlanta	atlanta	PROPN
eurjchem-2485	3	9	publishing	publishing	PROPN
eurjchem-2485	3	10	house	house	PROPN
eurjchem-2485	3	11	llc	llc	PROPN
eurjchem-2485	3	12	–	–	PUNCT
eurjchem-2485	3	13	cc	cc	PROPN
eurjchem-2485	3	14	by	by	ADP
eurjchem-2485	3	15	nc	nc	PROPN
eurjchem-2485	3	16	–	–	PUNCT
eurjchem-2485	3	17	some	some	DET
eurjchem-2485	3	18	rights	right	NOUN
eurjchem-2485	3	19	reserved	reserve	VERB
eurjchem-2485	3	20	.	.	PUNCT
eurjchem-2485	4	1	https://dx.doi.org/10.5155/eurjchem.14.4.494-498.2485	https://dx.doi.org/10.5155/eurjchem.14.4.494-498.2485	PROPN
eurjchem-2485	4	2	european	european	PROPN
eurjchem-2485	4	3	journal	journal	PROPN
eurjchem-2485	4	4	of	of	ADP
eurjchem-2485	4	5	chemistry	chemistry	NOUN
eurjchem-2485	4	6	view	view	NOUN
eurjchem-2485	4	7	journal	journal	PROPN
eurjchem-2485	4	8	online	online	PROPN
eurjchem-2485	4	9	view	view	NOUN
eurjchem-2485	4	10	article	article	NOUN
eurjchem-2485	4	11	online	online	ADV
eurjchem-2485	4	12	in	in	ADP
eurjchem-2485	4	13	an	an	DET
eurjchem-2485	4	14	attempt	attempt	NOUN
eurjchem-2485	4	15	to	to	PART
eurjchem-2485	4	16	add	add	VERB
eurjchem-2485	4	17	ligands	ligand	NOUN
eurjchem-2485	4	18	to	to	ADP
eurjchem-2485	4	19	the	the	DET
eurjchem-2485	4	20	sixth	sixth	ADJ
eurjchem-2485	4	21	(	(	PUNCT
eurjchem-2485	4	22	axial	axial	ADJ
eurjchem-2485	4	23	)	)	PUNCT
eurjchem-2485	4	24	position	position	NOUN
eurjchem-2485	4	25	of	of	ADP
eurjchem-2485	4	26	vanadyl	vanadyl	ADJ
eurjchem-2485	4	27	bis	bis	ADJ
eurjchem-2485	4	28	-	-	NOUN
eurjchem-2485	4	29	acetylacetonate	acetylacetonate	ADJ
eurjchem-2485	4	30	:	:	PUNCT
eurjchem-2485	4	31	a	a	DET
eurjchem-2485	4	32	unique	unique	ADJ
eurjchem-2485	4	33	tetranuclear	tetranuclear	ADJ
eurjchem-2485	4	34	vanadyl	vanadyl	NOUN
eurjchem-2485	4	35	species	species	PROPN
eurjchem-2485	4	36	ivan	ivan	PROPN
eurjchem-2485	4	37	bernal	bernal	PROPN
eurjchem-2485	4	38	1,2	1,2	PROPN
eurjchem-2485	4	39	and	and	CCONJ
eurjchem-2485	4	40	roger	roger	PROPN
eurjchem-2485	4	41	lalancette	lalancette	PROPN
eurjchem-2485	4	42	1	1	NUM
eurjchem-2485	4	43	,	,	PUNCT
eurjchem-2485	4	44	*	*	PROPN
eurjchem-2485	4	45	1	1	NUM
eurjchem-2485	4	46	carl	carl	PROPN
eurjchem-2485	4	47	a.	a.	PROPN
eurjchem-2485	4	48	olson	olson	PROPN
eurjchem-2485	4	49	memorial	memorial	ADJ
eurjchem-2485	4	50	laboratories	laboratory	NOUN
eurjchem-2485	4	51	,	,	PUNCT
eurjchem-2485	4	52	department	department	NOUN
eurjchem-2485	4	53	of	of	ADP
eurjchem-2485	4	54	chemistry	chemistry	PROPN
eurjchem-2485	4	55	,	,	PUNCT
eurjchem-2485	4	56	rutgers	rutgers	PROPN
eurjchem-2485	4	57	university	university	PROPN
eurjchem-2485	4	58	,	,	PUNCT
eurjchem-2485	4	59	73	73	NUM
eurjchem-2485	4	60	warren	warren	PROPN
eurjchem-2485	4	61	st	st	PROPN
eurjchem-2485	4	62	.	.	PROPN
eurjchem-2485	4	63	,	,	PUNCT
eurjchem-2485	4	64	newark	newark	PROPN
eurjchem-2485	4	65	,	,	PUNCT
eurjchem-2485	4	66	nj	nj	PROPN
eurjchem-2485	4	67	,	,	PUNCT
eurjchem-2485	4	68	07102	07102	NUM
eurjchem-2485	4	69	usa	usa	PROPN
eurjchem-2485	4	70	2	2	NUM
eurjchem-2485	4	71	molecular	molecular	PROPN
eurjchem-2485	4	72	sciences	sciences	PROPN
eurjchem-2485	4	73	institute	institute	PROPN
eurjchem-2485	4	74	,	,	PUNCT
eurjchem-2485	4	75	school	school	NOUN
eurjchem-2485	4	76	of	of	ADP
eurjchem-2485	4	77	chemistry	chemistry	NOUN
eurjchem-2485	4	78	,	,	PUNCT
eurjchem-2485	4	79	university	university	NOUN
eurjchem-2485	4	80	of	of	ADP
eurjchem-2485	4	81	the	the	DET
eurjchem-2485	4	82	witwatersrand	witwatersrand	NOUN
eurjchem-2485	4	83	,	,	PUNCT
eurjchem-2485	4	84	private	private	ADJ
eurjchem-2485	4	85	bag	bag	NOUN
eurjchem-2485	4	86	3	3	NUM
eurjchem-2485	4	87	,	,	PUNCT
eurjchem-2485	4	88	2050	2050	NUM
eurjchem-2485	4	89	johannesburg	johannesburg	PROPN
eurjchem-2485	4	90	,	,	PUNCT
eurjchem-2485	4	91	south	south	PROPN
eurjchem-2485	4	92	africa	africa	PROPN
eurjchem-2485	4	93	*	*	PUNCT
eurjchem-2485	4	94	corresponding	correspond	VERB
eurjchem-2485	4	95	author	author	NOUN
eurjchem-2485	4	96	at	at	ADP
eurjchem-2485	4	97	:	:	PUNCT
eurjchem-2485	4	98	carl	carl	PROPN
eurjchem-2485	4	99	a.	a.	PROPN
eurjchem-2485	4	100	olson	olson	PROPN
eurjchem-2485	4	101	memorial	memorial	ADJ
eurjchem-2485	4	102	laboratories	laboratory	NOUN
eurjchem-2485	4	103	,	,	PUNCT
eurjchem-2485	4	104	department	department	NOUN
eurjchem-2485	4	105	of	of	ADP
eurjchem-2485	4	106	chemistry	chemistry	PROPN
eurjchem-2485	4	107	,	,	PUNCT
eurjchem-2485	4	108	rutgers	rutgers	PROPN
eurjchem-2485	4	109	university	university	PROPN
eurjchem-2485	4	110	,	,	PUNCT
eurjchem-2485	4	111	73	73	NUM
eurjchem-2485	4	112	warren	warren	PROPN
eurjchem-2485	4	113	st	st	PROPN
eurjchem-2485	4	114	.	.	PROPN
eurjchem-2485	4	115	,	,	PUNCT
eurjchem-2485	4	116	newark	newark	PROPN
eurjchem-2485	4	117	,	,	PUNCT
eurjchem-2485	4	118	nj	nj	PROPN
eurjchem-2485	4	119	,	,	PUNCT
eurjchem-2485	4	120	07102	07102	NUM
eurjchem-2485	4	121	usa	usa	PROPN
eurjchem-2485	4	122	.	.	PUNCT
eurjchem-2485	5	1	e	e	X
eurjchem-2485	5	2	-	-	NOUN
eurjchem-2485	5	3	mail	mail	NOUN
eurjchem-2485	5	4	:	:	PUNCT
eurjchem-2485	5	5	rogerlal@newark.rutgers.edu	rogerlal@newark.rutgers.edu	PROPN
eurjchem-2485	5	6	(	(	PUNCT
eurjchem-2485	5	7	r.	r.	PROPN
eurjchem-2485	5	8	lalancette	lalancette	PROPN
eurjchem-2485	5	9	)	)	PUNCT
eurjchem-2485	5	10	.	.	PUNCT
eurjchem-2485	6	1	10.5155	10.5155	NUM
eurjchem-2485	6	2	/	/	SYM
eurjchem-2485	6	3	eurjchem.14.4.494	eurjchem.14.4.494	NUM
eurjchem-2485	6	4	-	-	SYM
eurjchem-2485	6	5	498.2485	498.2485	NUM
eurjchem-2485	6	6	received	receive	VERB
eurjchem-2485	6	7	:	:	PUNCT
eurjchem-2485	6	8	23	23	NUM
eurjchem-2485	6	9	october	october	PROPN
eurjchem-2485	6	10	2023	2023	NUM
eurjchem-2485	6	11	received	receive	VERB
eurjchem-2485	6	12	in	in	ADP
eurjchem-2485	6	13	revised	revise	VERB
eurjchem-2485	6	14	form	form	NOUN
eurjchem-2485	6	15	:	:	PUNCT
eurjchem-2485	6	16	20	20	NUM
eurjchem-2485	6	17	november	november	NOUN
eurjchem-2485	6	18	2023	2023	NUM
eurjchem-2485	6	19	accepted	accept	VERB
eurjchem-2485	6	20	:	:	PUNCT
eurjchem-2485	6	21	01	01	NUM
eurjchem-2485	6	22	december	december	PROPN
eurjchem-2485	6	23	2023	2023	NUM
eurjchem-2485	6	24	published	publish	VERB
eurjchem-2485	6	25	online	online	NOUN
eurjchem-2485	6	26	:	:	PUNCT
eurjchem-2485	6	27	31	31	NUM
eurjchem-2485	6	28	december	december	PROPN
eurjchem-2485	6	29	2023	2023	NUM
eurjchem-2485	6	30	printed	print	VERB
eurjchem-2485	6	31	:	:	PUNCT
eurjchem-2485	6	32	31	31	NUM
eurjchem-2485	6	33	december	december	PROPN
eurjchem-2485	6	34	2023	2023	NUM
eurjchem-2485	6	35	we	we	PRON
eurjchem-2485	6	36	have	have	AUX
eurjchem-2485	6	37	explored	explore	VERB
eurjchem-2485	6	38	the	the	DET
eurjchem-2485	6	39	interaction	interaction	NOUN
eurjchem-2485	6	40	of	of	ADP
eurjchem-2485	6	41	[	[	X
eurjchem-2485	6	42	(	(	PUNCT
eurjchem-2485	6	43	acac)2v	acac)2v	NOUN
eurjchem-2485	6	44	=	=	NOUN
eurjchem-2485	6	45	o	o	NOUN
eurjchem-2485	6	46	]	]	X
eurjchem-2485	6	47	(	(	PUNCT
eurjchem-2485	6	48	acac	acac	NOUN
eurjchem-2485	6	49	=	=	SYM
eurjchem-2485	6	50	acetylacetone	acetylacetone	NOUN
eurjchem-2485	6	51	)	)	PUNCT
eurjchem-2485	6	52	with	with	ADP
eurjchem-2485	6	53	a	a	DET
eurjchem-2485	6	54	series	series	NOUN
eurjchem-2485	6	55	of	of	ADP
eurjchem-2485	6	56	potential	potential	ADJ
eurjchem-2485	6	57	ligands	ligand	NOUN
eurjchem-2485	6	58	which	which	PRON
eurjchem-2485	6	59	were	be	AUX
eurjchem-2485	6	60	chosen	choose	VERB
eurjchem-2485	6	61	because	because	SCONJ
eurjchem-2485	6	62	of	of	ADP
eurjchem-2485	6	63	their	their	PRON
eurjchem-2485	6	64	expected	expect	VERB
eurjchem-2485	6	65	ability	ability	NOUN
eurjchem-2485	6	66	to	to	PART
eurjchem-2485	6	67	attach	attach	VERB
eurjchem-2485	6	68	themselves	themselves	PRON
eurjchem-2485	6	69	onto	onto	ADP
eurjchem-2485	6	70	its	its	PRON
eurjchem-2485	6	71	sixth	sixth	ADJ
eurjchem-2485	6	72	(	(	PUNCT
eurjchem-2485	6	73	axial	axial	ADJ
eurjchem-2485	6	74	)	)	PUNCT
eurjchem-2485	6	75	position	position	NOUN
eurjchem-2485	6	76	.	.	PUNCT
eurjchem-2485	7	1	furthermore	furthermore	ADV
eurjchem-2485	7	2	,	,	PUNCT
eurjchem-2485	7	3	some	some	PRON
eurjchem-2485	7	4	of	of	ADP
eurjchem-2485	7	5	the	the	DET
eurjchem-2485	7	6	species	specie	NOUN
eurjchem-2485	7	7	chosen	choose	VERB
eurjchem-2485	7	8	were	be	AUX
eurjchem-2485	7	9	expected	expect	VERB
eurjchem-2485	7	10	to	to	PART
eurjchem-2485	7	11	have	have	VERB
eurjchem-2485	7	12	the	the	DET
eurjchem-2485	7	13	capability	capability	NOUN
eurjchem-2485	7	14	of	of	ADP
eurjchem-2485	7	15	linking	link	VERB
eurjchem-2485	7	16	pairs	pair	NOUN
eurjchem-2485	7	17	of	of	ADP
eurjchem-2485	7	18	[	[	X
eurjchem-2485	7	19	(	(	PUNCT
eurjchem-2485	7	20	acac)2v	acac)2v	NOUN
eurjchem-2485	7	21	=	=	NOUN
eurjchem-2485	7	22	o	o	NOUN
eurjchem-2485	7	23	]	]	X
eurjchem-2485	7	24	molecules	molecule	NOUN
eurjchem-2485	7	25	,	,	PUNCT
eurjchem-2485	7	26	thus	thus	ADV
eurjchem-2485	7	27	creating	create	VERB
eurjchem-2485	7	28	magnetically	magnetically	ADV
eurjchem-2485	7	29	coupled	couple	VERB
eurjchem-2485	7	30	substances	substance	NOUN
eurjchem-2485	7	31	whose	whose	DET
eurjchem-2485	7	32	behavior	behavior	NOUN
eurjchem-2485	7	33	would	would	AUX
eurjchem-2485	7	34	be	be	AUX
eurjchem-2485	7	35	interesting	interesting	ADJ
eurjchem-2485	7	36	to	to	PART
eurjchem-2485	7	37	document	document	VERB
eurjchem-2485	7	38	by	by	ADP
eurjchem-2485	7	39	magnetic	magnetic	ADJ
eurjchem-2485	7	40	as	as	ADV
eurjchem-2485	7	41	well	well	ADV
eurjchem-2485	7	42	as	as	ADP
eurjchem-2485	7	43	structural	structural	ADJ
eurjchem-2485	7	44	methods	method	NOUN
eurjchem-2485	7	45	.	.	PUNCT
eurjchem-2485	8	1	some	some	PRON
eurjchem-2485	8	2	of	of	ADP
eurjchem-2485	8	3	the	the	DET
eurjchem-2485	8	4	synthetic	synthetic	ADJ
eurjchem-2485	8	5	results	result	NOUN
eurjchem-2485	8	6	were	be	AUX
eurjchem-2485	8	7	surprising	surprising	ADJ
eurjchem-2485	8	8	in	in	ADP
eurjchem-2485	8	9	that	that	DET
eurjchem-2485	8	10	unexpected	unexpected	ADJ
eurjchem-2485	8	11	products	product	NOUN
eurjchem-2485	8	12	were	be	AUX
eurjchem-2485	8	13	obtained	obtain	VERB
eurjchem-2485	8	14	which	which	PRON
eurjchem-2485	8	15	we	we	PRON
eurjchem-2485	8	16	had	have	AUX
eurjchem-2485	8	17	not	not	PART
eurjchem-2485	8	18	envisioned	envision	VERB
eurjchem-2485	8	19	;	;	PUNCT
eurjchem-2485	8	20	specifically	specifically	ADV
eurjchem-2485	8	21	,	,	PUNCT
eurjchem-2485	8	22	herein	herein	NOUN
eurjchem-2485	8	23	we	we	PRON
eurjchem-2485	8	24	describe	describe	VERB
eurjchem-2485	8	25	a	a	DET
eurjchem-2485	8	26	tetranuclear	tetranuclear	ADJ
eurjchem-2485	8	27	vanadyl	vanadyl	NOUN
eurjchem-2485	8	28	cluster	cluster	NOUN
eurjchem-2485	8	29	(	(	PUNCT
eurjchem-2485	8	30	crystal	crystal	NOUN
eurjchem-2485	8	31	data	datum	NOUN
eurjchem-2485	8	32	for	for	ADP
eurjchem-2485	8	33	c38h51n4o17clv4	c38h51n4o17clv4	NOUN
eurjchem-2485	8	34	:	:	PUNCT
eurjchem-2485	8	35	orthorhombic	orthorhombic	NOUN
eurjchem-2485	8	36	,	,	PUNCT
eurjchem-2485	8	37	space	space	NOUN
eurjchem-2485	8	38	group	group	NOUN
eurjchem-2485	8	39	pca21	pca21	PROPN
eurjchem-2485	8	40	(	(	PUNCT
eurjchem-2485	8	41	no	no	NOUN
eurjchem-2485	8	42	.	.	NOUN
eurjchem-2485	8	43	29	29	NUM
eurjchem-2485	8	44	)	)	PUNCT
eurjchem-2485	8	45	,	,	PUNCT
eurjchem-2485	8	46	a	a	DET
eurjchem-2485	8	47	=	=	SYM
eurjchem-2485	8	48	26.4698(3	26.4698(3	NUM
eurjchem-2485	8	49	)	)	PUNCT
eurjchem-2485	8	50	å	å	PROPN
eurjchem-2485	8	51	,	,	PUNCT
eurjchem-2485	8	52	b	b	X
eurjchem-2485	8	53	=	=	SYM
eurjchem-2485	8	54	13.5167(2	13.5167(2	PROPN
eurjchem-2485	8	55	)	)	PUNCT
eurjchem-2485	8	56	å	å	NOUN
eurjchem-2485	8	57	,	,	PUNCT
eurjchem-2485	8	58	c	c	NOUN
eurjchem-2485	8	59	=	=	SYM
eurjchem-2485	8	60	12.7659(2	12.7659(2	NUM
eurjchem-2485	8	61	)	)	PUNCT
eurjchem-2485	8	62	å	å	NOUN
eurjchem-2485	8	63	,	,	PUNCT
eurjchem-2485	8	64	v	v	NOUN
eurjchem-2485	8	65	=	=	SYM
eurjchem-2485	8	66	4567.44(11	4567.44(11	NOUN
eurjchem-2485	8	67	)	)	PUNCT
eurjchem-2485	8	68	å3	å3	PROPN
eurjchem-2485	8	69	,	,	PUNCT
eurjchem-2485	8	70	z	z	NOUN
eurjchem-2485	8	71	=	=	SYM
eurjchem-2485	8	72	4	4	NUM
eurjchem-2485	8	73	,	,	PUNCT
eurjchem-2485	8	74	μ(cukα	μ(cukα	NOUN
eurjchem-2485	8	75	)	)	PUNCT
eurjchem-2485	8	76	=	=	VERB
eurjchem-2485	8	77	7.842	7.842	NUM
eurjchem-2485	8	78	mm-1	mm-1	NOUN
eurjchem-2485	8	79	,	,	PUNCT
eurjchem-2485	8	80	dcalc	dcalc	NOUN
eurjchem-2485	8	81	=	=	NOUN
eurjchem-2485	8	82	1.53	1.53	NUM
eurjchem-2485	8	83	g	g	NOUN
eurjchem-2485	8	84	/	/	SYM
eurjchem-2485	8	85	cm3	cm3	NOUN
eurjchem-2485	8	86	,	,	PUNCT
eurjchem-2485	8	87	41277	41277	NUM
eurjchem-2485	8	88	reflections	reflection	NOUN
eurjchem-2485	8	89	measured	measure	VERB
eurjchem-2485	8	90	(	(	PUNCT
eurjchem-2485	8	91	6.538	6.538	NUM
eurjchem-2485	8	92	°	°	NOUN
eurjchem-2485	8	93	≤	≤	ADJ
eurjchem-2485	8	94	2θ	2θ	NUM
eurjchem-2485	8	95	≤	≤	NUM
eurjchem-2485	8	96	137.892	137.892	NUM
eurjchem-2485	8	97	°	°	NOUN
eurjchem-2485	8	98	)	)	PUNCT
eurjchem-2485	8	99	,	,	PUNCT
eurjchem-2485	8	100	7841	7841	NUM
eurjchem-2485	8	101	unique	unique	ADJ
eurjchem-2485	8	102	(	(	PUNCT
eurjchem-2485	8	103	rint	rint	NOUN
eurjchem-2485	8	104	=	=	SYM
eurjchem-2485	8	105	0.0428	0.0428	NUM
eurjchem-2485	8	106	,	,	PUNCT
eurjchem-2485	8	107	rsigma	rsigma	ADJ
eurjchem-2485	8	108	=	=	SYM
eurjchem-2485	8	109	0.0421	0.0421	NUM
eurjchem-2485	8	110	)	)	PUNCT
eurjchem-2485	8	111	which	which	PRON
eurjchem-2485	8	112	were	be	AUX
eurjchem-2485	8	113	used	use	VERB
eurjchem-2485	8	114	in	in	ADP
eurjchem-2485	8	115	all	all	DET
eurjchem-2485	8	116	calculations	calculation	NOUN
eurjchem-2485	8	117	;	;	PUNCT
eurjchem-2485	8	118	the	the	DET
eurjchem-2485	8	119	final	final	ADJ
eurjchem-2485	8	120	r1	r1	NOUN
eurjchem-2485	8	121	was	be	AUX
eurjchem-2485	8	122	0.0675	0.0675	NUM
eurjchem-2485	8	123	(	(	PUNCT
eurjchem-2485	8	124	i	i	X
eurjchem-2485	8	125	>	>	X
eurjchem-2485	8	126	2σ(i	2σ(i	NUM
eurjchem-2485	8	127	)	)	PUNCT
eurjchem-2485	8	128	)	)	PUNCT
eurjchem-2485	9	1	and	and	CCONJ
eurjchem-2485	9	2	wr2	wr2	PROPN
eurjchem-2485	9	3	was	be	AUX
eurjchem-2485	9	4	0.1641	0.1641	NUM
eurjchem-2485	9	5	(	(	PUNCT
eurjchem-2485	9	6	all	all	DET
eurjchem-2485	9	7	data	datum	NOUN
eurjchem-2485	9	8	)	)	PUNCT
eurjchem-2485	9	9	)	)	PUNCT
eurjchem-2485	9	10	,	,	PUNCT
eurjchem-2485	9	11	which	which	PRON
eurjchem-2485	9	12	is	be	AUX
eurjchem-2485	9	13	unusual	unusual	ADJ
eurjchem-2485	9	14	in	in	ADP
eurjchem-2485	9	15	several	several	ADJ
eurjchem-2485	9	16	aspects	aspect	NOUN
eurjchem-2485	9	17	of	of	ADP
eurjchem-2485	9	18	its	its	PRON
eurjchem-2485	9	19	composition	composition	NOUN
eurjchem-2485	9	20	as	as	ADV
eurjchem-2485	9	21	well	well	ADV
eurjchem-2485	9	22	as	as	ADP
eurjchem-2485	9	23	its	its	PRON
eurjchem-2485	9	24	stereochemistry	stereochemistry	NOUN
eurjchem-2485	9	25	.	.	PUNCT
eurjchem-2485	10	1	axial	axial	ADJ
eurjchem-2485	10	2	adducts	adduct	NOUN
eurjchem-2485	10	3	bridging	bridge	VERB
eurjchem-2485	10	4	vanadyls	vanadyls	ADJ
eurjchem-2485	10	5	1,3	1,3	NUM
eurjchem-2485	10	6	-	-	PUNCT
eurjchem-2485	10	7	diazine	diazine	NOUN
eurjchem-2485	10	8	ligands	ligand	NOUN
eurjchem-2485	10	9	vanadyl	vanadyl	VERB
eurjchem-2485	10	10	acetylacetonate	acetylacetonate	NOUN
eurjchem-2485	10	11	tetra	tetra	NOUN
eurjchem-2485	10	12	-	-	PUNCT
eurjchem-2485	10	13	nuclear	nuclear	ADJ
eurjchem-2485	10	14	vanadyl	vanadyl	NOUN
eurjchem-2485	10	15	compounds	compound	VERB
eurjchem-2485	10	16	5and	5and	NUM
eurjchem-2485	10	17	6	6	NUM
eurjchem-2485	10	18	-	-	PUNCT
eurjchem-2485	10	19	coordinated	coordinate	VERB
eurjchem-2485	10	20	vanadyl	vanadyl	NOUN
eurjchem-2485	10	21	species	specie	NOUN
eurjchem-2485	10	22	cite	cite	VERB
eurjchem-2485	10	23	this	this	PRON
eurjchem-2485	10	24	:	:	PUNCT
eurjchem-2485	10	25	eur	eur	PROPN
eurjchem-2485	10	26	.	.	PUNCT
eurjchem-2485	11	1	j.	j.	PROPN
eurjchem-2485	11	2	chem	chem	PROPN
eurjchem-2485	11	3	.	.	PUNCT
eurjchem-2485	12	1	2023	2023	NUM
eurjchem-2485	12	2	,	,	PUNCT
eurjchem-2485	12	3	14(4	14(4	NUM
eurjchem-2485	12	4	)	)	PUNCT
eurjchem-2485	12	5	,	,	PUNCT
eurjchem-2485	12	6	494	494	NUM
eurjchem-2485	12	7	-	-	SYM
eurjchem-2485	12	8	498	498	NUM
eurjchem-2485	12	9	journal	journal	NOUN
eurjchem-2485	12	10	website	website	NOUN
eurjchem-2485	12	11	:	:	PUNCT
eurjchem-2485	12	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2485	12	13	1	1	X
eurjchem-2485	12	14	.	.	PUNCT
eurjchem-2485	12	15	introduction	introduction	NOUN
eurjchem-2485	12	16	in	in	ADP
eurjchem-2485	12	17	the	the	DET
eurjchem-2485	12	18	past	past	NOUN
eurjchem-2485	13	1	[	[	X
eurjchem-2485	13	2	1	1	NUM
eurjchem-2485	13	3	-	-	SYM
eurjchem-2485	13	4	3	3	NUM
eurjchem-2485	13	5	]	]	PUNCT
eurjchem-2485	13	6	,	,	PUNCT
eurjchem-2485	13	7	we	we	PRON
eurjchem-2485	13	8	have	have	AUX
eurjchem-2485	13	9	described	describe	VERB
eurjchem-2485	13	10	studies	study	NOUN
eurjchem-2485	13	11	of	of	ADP
eurjchem-2485	13	12	[	[	X
eurjchem-2485	13	13	(	(	PUNCT
eurjchem-2485	13	14	acac)2v	acac)2v	NOUN
eurjchem-2485	13	15	=	=	NOUN
eurjchem-2485	13	16	o	o	X
eurjchem-2485	13	17	]	]	X
eurjchem-2485	13	18	acting	act	VERB
eurjchem-2485	13	19	as	as	ADP
eurjchem-2485	13	20	a	a	DET
eurjchem-2485	13	21	substrate	substrate	NOUN
eurjchem-2485	13	22	for	for	ADP
eurjchem-2485	13	23	donor	donor	NOUN
eurjchem-2485	13	24	ligands	ligand	NOUN
eurjchem-2485	13	25	capable	capable	ADJ
eurjchem-2485	13	26	of	of	ADP
eurjchem-2485	13	27	attacking	attack	VERB
eurjchem-2485	13	28	the	the	DET
eurjchem-2485	13	29	vanadium	vanadium	NOUN
eurjchem-2485	13	30	moiety	moiety	NOUN
eurjchem-2485	13	31	via	via	ADP
eurjchem-2485	13	32	the	the	DET
eurjchem-2485	13	33	sixth	sixth	ADJ
eurjchem-2485	13	34	position	position	NOUN
eurjchem-2485	13	35	.	.	PUNCT
eurjchem-2485	14	1	in	in	ADP
eurjchem-2485	14	2	[	[	X
eurjchem-2485	14	3	1	1	NUM
eurjchem-2485	14	4	]	]	PUNCT
eurjchem-2485	14	5	,	,	PUNCT
eurjchem-2485	14	6	we	we	PRON
eurjchem-2485	14	7	documented	document	VERB
eurjchem-2485	14	8	the	the	DET
eurjchem-2485	14	9	magnetic	magnetic	ADJ
eurjchem-2485	14	10	and	and	CCONJ
eurjchem-2485	14	11	spectroscopic	spectroscopic	ADJ
eurjchem-2485	14	12	consequences	consequence	NOUN
eurjchem-2485	14	13	of	of	ADP
eurjchem-2485	14	14	such	such	ADJ
eurjchem-2485	14	15	interactions	interaction	NOUN
eurjchem-2485	14	16	for	for	ADP
eurjchem-2485	14	17	both	both	DET
eurjchem-2485	14	18	solids	solid	NOUN
eurjchem-2485	14	19	and	and	CCONJ
eurjchem-2485	14	20	solutions	solution	NOUN
eurjchem-2485	14	21	and	and	CCONJ
eurjchem-2485	14	22	suggested	suggest	VERB
eurjchem-2485	14	23	that	that	SCONJ
eurjchem-2485	14	24	those	those	DET
eurjchem-2485	14	25	results	result	NOUN
eurjchem-2485	14	26	could	could	AUX
eurjchem-2485	14	27	be	be	AUX
eurjchem-2485	14	28	used	use	VERB
eurjchem-2485	14	29	as	as	ADP
eurjchem-2485	14	30	quantitative	quantitative	ADJ
eurjchem-2485	14	31	gauges	gauge	NOUN
eurjchem-2485	14	32	of	of	ADP
eurjchem-2485	14	33	the	the	DET
eurjchem-2485	14	34	electrondonor	electrondonor	NOUN
eurjchem-2485	14	35	acceptor	acceptor	NOUN
eurjchem-2485	14	36	characteristics	characteristic	NOUN
eurjchem-2485	14	37	of	of	ADP
eurjchem-2485	14	38	such	such	ADJ
eurjchem-2485	14	39	systems	system	NOUN
eurjchem-2485	14	40	.	.	PUNCT
eurjchem-2485	15	1	moreover	moreover	ADV
eurjchem-2485	15	2	,	,	PUNCT
eurjchem-2485	15	3	it	it	PRON
eurjchem-2485	15	4	is	be	AUX
eurjchem-2485	15	5	clear	clear	ADJ
eurjchem-2485	15	6	that	that	SCONJ
eurjchem-2485	15	7	the	the	DET
eurjchem-2485	15	8	subject	subject	NOUN
eurjchem-2485	15	9	could	could	AUX
eurjchem-2485	15	10	be	be	AUX
eurjchem-2485	15	11	vast	vast	ADJ
eurjchem-2485	15	12	since	since	SCONJ
eurjchem-2485	15	13	(	(	PUNCT
eurjchem-2485	15	14	a	a	X
eurjchem-2485	15	15	)	)	PUNCT
eurjchem-2485	15	16	the	the	DET
eurjchem-2485	15	17	acac	acac	NOUN
eurjchem-2485	15	18	ligands	ligand	NOUN
eurjchem-2485	15	19	could	could	AUX
eurjchem-2485	15	20	be	be	AUX
eurjchem-2485	15	21	modified	modify	VERB
eurjchem-2485	15	22	in	in	ADP
eurjchem-2485	15	23	an	an	DET
eurjchem-2485	15	24	orderly	orderly	ADJ
eurjchem-2485	15	25	fashion	fashion	NOUN
eurjchem-2485	15	26	while	while	SCONJ
eurjchem-2485	15	27	retaining	retain	VERB
eurjchem-2485	15	28	the	the	DET
eurjchem-2485	15	29	potential	potential	ADJ
eurjchem-2485	15	30	donor	donor	NOUN
eurjchem-2485	15	31	skeleton	skeleton	NOUN
eurjchem-2485	15	32	constant	constant	ADJ
eurjchem-2485	15	33	;	;	PUNCT
eurjchem-2485	15	34	(	(	PUNCT
eurjchem-2485	15	35	b	b	X
eurjchem-2485	15	36	)	)	PUNCT
eurjchem-2485	15	37	the	the	DET
eurjchem-2485	15	38	ligands	ligand	NOUN
eurjchem-2485	15	39	could	could	AUX
eurjchem-2485	15	40	be	be	AUX
eurjchem-2485	15	41	retained	retain	VERB
eurjchem-2485	15	42	while	while	SCONJ
eurjchem-2485	15	43	changing	change	VERB
eurjchem-2485	15	44	the	the	DET
eurjchem-2485	15	45	potential	potential	ADJ
eurjchem-2485	15	46	donor	donor	NOUN
eurjchem-2485	15	47	;	;	PUNCT
eurjchem-2485	15	48	and	and	CCONJ
eurjchem-2485	15	49	(	(	PUNCT
eurjchem-2485	15	50	c	c	X
eurjchem-2485	15	51	)	)	PUNCT
eurjchem-2485	15	52	the	the	DET
eurjchem-2485	15	53	solvent	solvent	NOUN
eurjchem-2485	15	54	can	can	AUX
eurjchem-2485	15	55	play	play	VERB
eurjchem-2485	15	56	a	a	DET
eurjchem-2485	15	57	role	role	NOUN
eurjchem-2485	15	58	(	(	PUNCT
eurjchem-2485	15	59	being	be	AUX
eurjchem-2485	15	60	able	able	ADJ
eurjchem-2485	15	61	to	to	PART
eurjchem-2485	15	62	compete	compete	VERB
eurjchem-2485	15	63	with	with	ADP
eurjchem-2485	15	64	the	the	DET
eurjchem-2485	15	65	potential	potential	ADJ
eurjchem-2485	15	66	donor	donor	NOUN
eurjchem-2485	15	67	)	)	PUNCT
eurjchem-2485	15	68	,	,	PUNCT
eurjchem-2485	15	69	as	as	ADP
eurjchem-2485	15	70	in	in	ADP
eurjchem-2485	15	71	the	the	DET
eurjchem-2485	15	72	case	case	NOUN
eurjchem-2485	15	73	of	of	ADP
eurjchem-2485	15	74	,	,	PUNCT
eurjchem-2485	15	75	e.g.	e.g.	ADV
eurjchem-2485	15	76	,	,	PUNCT
eurjchem-2485	15	77	pyridine	pyridine	NOUN
eurjchem-2485	15	78	.	.	PUNCT
eurjchem-2485	16	1	in	in	ADP
eurjchem-2485	16	2	the	the	DET
eurjchem-2485	16	3	process	process	NOUN
eurjchem-2485	16	4	of	of	ADP
eurjchem-2485	16	5	carrying	carry	VERB
eurjchem-2485	16	6	out	out	ADP
eurjchem-2485	16	7	a	a	DET
eurjchem-2485	16	8	series	series	NOUN
eurjchem-2485	16	9	of	of	ADP
eurjchem-2485	16	10	such	such	ADJ
eurjchem-2485	16	11	studies	study	NOUN
eurjchem-2485	16	12	,	,	PUNCT
eurjchem-2485	16	13	we	we	PRON
eurjchem-2485	16	14	discovered	discover	VERB
eurjchem-2485	16	15	tiny	tiny	ADJ
eurjchem-2485	16	16	black	black	ADJ
eurjchem-2485	16	17	crystals	crystal	NOUN
eurjchem-2485	16	18	,	,	PUNCT
eurjchem-2485	16	19	which	which	PRON
eurjchem-2485	16	20	are	be	AUX
eurjchem-2485	16	21	the	the	DET
eurjchem-2485	16	22	subject	subject	NOUN
eurjchem-2485	16	23	of	of	ADP
eurjchem-2485	16	24	this	this	DET
eurjchem-2485	16	25	report	report	NOUN
eurjchem-2485	16	26	.	.	PUNCT
eurjchem-2485	17	1	2	2	X
eurjchem-2485	17	2	.	.	X
eurjchem-2485	17	3	experimental	experimental	ADJ
eurjchem-2485	17	4	2.1	2.1	NUM
eurjchem-2485	17	5	.	.	PUNCT
eurjchem-2485	17	6	preparation	preparation	NOUN
eurjchem-2485	17	7	of	of	ADP
eurjchem-2485	17	8	bis	bis	ADJ
eurjchem-2485	17	9	-	-	ADJ
eurjchem-2485	17	10	acetylacetonato	acetylacetonato	ADJ
eurjchem-2485	17	11	-	-	PUNCT
eurjchem-2485	17	12	chloridohydroxydo	chloridohydroxydo	NOUN
eurjchem-2485	17	13	-	-	PUNCT
eurjchem-2485	17	14	tetravanadyl(iv	tetravanadyl(iv	NOUN
eurjchem-2485	17	15	)	)	PUNCT
eurjchem-2485	17	16	complex	complex	NOUN
eurjchem-2485	17	17	(	(	PUNCT
eurjchem-2485	17	18	i	i	NOUN
eurjchem-2485	17	19	)	)	PUNCT
eurjchem-2485	17	20	0.500	0.500	NUM
eurjchem-2485	17	21	g	g	PROPN
eurjchem-2485	17	22	(	(	PUNCT
eurjchem-2485	17	23	1.89	1.89	NUM
eurjchem-2485	17	24	mmoles	mmole	NOUN
eurjchem-2485	17	25	)	)	PUNCT
eurjchem-2485	17	26	of	of	ADP
eurjchem-2485	17	27	vanadyl(acac)2	vanadyl(acac)2	NOUN
eurjchem-2485	17	28	(	(	PUNCT
eurjchem-2485	17	29	c10h14o5v	c10h14o5v	PROPN
eurjchem-2485	17	30	)	)	PUNCT
eurjchem-2485	17	31	and	and	CCONJ
eurjchem-2485	17	32	0.600	0.600	NUM
eurjchem-2485	17	33	g	g	NOUN
eurjchem-2485	17	34	(	(	PUNCT
eurjchem-2485	17	35	7.5	7.5	NUM
eurjchem-2485	17	36	mmoles	mmole	NOUN
eurjchem-2485	17	37	)	)	PUNCT
eurjchem-2485	17	38	of	of	ADP
eurjchem-2485	17	39	pyrimidine	pyrimidine	NOUN
eurjchem-2485	17	40	(	(	PUNCT
eurjchem-2485	17	41	1,3	1,3	NUM
eurjchem-2485	17	42	-	-	PUNCT
eurjchem-2485	17	43	diazine	diazine	NOUN
eurjchem-2485	17	44	)	)	PUNCT
eurjchem-2485	17	45	(	(	PUNCT
eurjchem-2485	17	46	c4h4n2	c4h4n2	X
eurjchem-2485	17	47	)	)	PUNCT
eurjchem-2485	17	48	(	(	PUNCT
eurjchem-2485	17	49	3.97:1	3.97:1	NUM
eurjchem-2485	17	50	mole	mole	NOUN
eurjchem-2485	17	51	ratio	ratio	NOUN
eurjchem-2485	17	52	of	of	ADP
eurjchem-2485	17	53	the	the	DET
eurjchem-2485	17	54	1,3	1,3	NUM
eurjchem-2485	17	55	-	-	PUNCT
eurjchem-2485	17	56	diazine	diazine	NOUN
eurjchem-2485	17	57	ligand	ligand	NOUN
eurjchem-2485	17	58	to	to	PART
eurjchem-2485	17	59	vanadyl	vanadyl	VERB
eurjchem-2485	17	60	)	)	PUNCT
eurjchem-2485	17	61	and	and	CCONJ
eurjchem-2485	17	62	0.5	0.5	NUM
eurjchem-2485	17	63	ml	ml	NOUN
eurjchem-2485	17	64	of	of	ADP
eurjchem-2485	17	65	12	12	NUM
eurjchem-2485	17	66	m	m	NOUN
eurjchem-2485	17	67	hcl	hcl	PROPN
eurjchem-2485	17	68	were	be	AUX
eurjchem-2485	17	69	added	add	VERB
eurjchem-2485	17	70	to	to	ADP
eurjchem-2485	17	71	45	45	NUM
eurjchem-2485	17	72	ml	ml	NOUN
eurjchem-2485	17	73	of	of	ADP
eurjchem-2485	17	74	toluene	toluene	NOUN
eurjchem-2485	17	75	in	in	ADP
eurjchem-2485	17	76	a	a	DET
eurjchem-2485	17	77	sealed	seal	VERB
eurjchem-2485	17	78	glass	glass	NOUN
eurjchem-2485	17	79	pressure	pressure	NOUN
eurjchem-2485	17	80	cell	cell	NOUN
eurjchem-2485	17	81	and	and	CCONJ
eurjchem-2485	17	82	heated	heat	VERB
eurjchem-2485	17	83	at	at	ADP
eurjchem-2485	17	84	130	130	NUM
eurjchem-2485	17	85	°	°	NOUN
eurjchem-2485	17	86	c	c	NOUN
eurjchem-2485	17	87	in	in	ADP
eurjchem-2485	17	88	a	a	DET
eurjchem-2485	17	89	silicone	silicone	NOUN
eurjchem-2485	17	90	oil	oil	NOUN
eurjchem-2485	17	91	bath	bath	NOUN
eurjchem-2485	17	92	for	for	ADP
eurjchem-2485	17	93	1.5	1.5	NUM
eurjchem-2485	17	94	hours	hour	NOUN
eurjchem-2485	17	95	with	with	ADP
eurjchem-2485	17	96	stirring	stirring	NOUN
eurjchem-2485	17	97	.	.	PUNCT
eurjchem-2485	18	1	the	the	DET
eurjchem-2485	18	2	mixture	mixture	NOUN
eurjchem-2485	18	3	was	be	AUX
eurjchem-2485	18	4	allowed	allow	VERB
eurjchem-2485	18	5	to	to	PART
eurjchem-2485	18	6	cool	cool	VERB
eurjchem-2485	18	7	slowly	slowly	ADV
eurjchem-2485	18	8	,	,	PUNCT
eurjchem-2485	18	9	filtered	filter	VERB
eurjchem-2485	18	10	through	through	ADP
eurjchem-2485	18	11	a	a	DET
eurjchem-2485	18	12	sintered	sinter	VERB
eurjchem-2485	18	13	glass	glass	NOUN
eurjchem-2485	18	14	funnel	funnel	NOUN
eurjchem-2485	18	15	,	,	PUNCT
eurjchem-2485	18	16	and	and	CCONJ
eurjchem-2485	18	17	the	the	DET
eurjchem-2485	18	18	filtrate	filtrate	NOUN
eurjchem-2485	18	19	was	be	AUX
eurjchem-2485	18	20	transferred	transfer	VERB
eurjchem-2485	18	21	to	to	ADP
eurjchem-2485	18	22	three	three	NUM
eurjchem-2485	18	23	20	20	NUM
eurjchem-2485	18	24	ml	ml	NOUN
eurjchem-2485	18	25	vials	vial	NOUN
eurjchem-2485	18	26	,	,	PUNCT
eurjchem-2485	18	27	whose	whose	DET
eurjchem-2485	18	28	openings	opening	NOUN
eurjchem-2485	18	29	were	be	AUX
eurjchem-2485	18	30	sealed	seal	VERB
eurjchem-2485	18	31	with	with	ADP
eurjchem-2485	18	32	parafilm	parafilm	NOUN
eurjchem-2485	18	33	through	through	ADP
eurjchem-2485	18	34	which	which	PRON
eurjchem-2485	18	35	was	be	AUX
eurjchem-2485	18	36	poked	poke	VERB
eurjchem-2485	18	37	a	a	DET
eurjchem-2485	18	38	number	number	NOUN
eurjchem-2485	18	39	of	of	ADP
eurjchem-2485	18	40	small	small	ADJ
eurjchem-2485	18	41	holes	hole	NOUN
eurjchem-2485	18	42	.	.	PUNCT
eurjchem-2485	19	1	the	the	DET
eurjchem-2485	19	2	solutions	solution	NOUN
eurjchem-2485	19	3	were	be	AUX
eurjchem-2485	19	4	allowed	allow	VERB
eurjchem-2485	19	5	to	to	PART
eurjchem-2485	19	6	evaporate	evaporate	VERB
eurjchem-2485	19	7	slowly	slowly	ADV
eurjchem-2485	19	8	.	.	PUNCT
eurjchem-2485	20	1	after	after	ADP
eurjchem-2485	20	2	34	34	NUM
eurjchem-2485	20	3	days	day	NOUN
eurjchem-2485	20	4	,	,	PUNCT
eurjchem-2485	20	5	a	a	DET
eurjchem-2485	20	6	small	small	ADJ
eurjchem-2485	20	7	number	number	NOUN
eurjchem-2485	20	8	of	of	ADP
eurjchem-2485	20	9	black	black	ADJ
eurjchem-2485	20	10	crystals	crystal	NOUN
eurjchem-2485	20	11	of	of	ADP
eurjchem-2485	20	12	a	a	DET
eurjchem-2485	20	13	vanadyl	vanadyl	NOUN
eurjchem-2485	20	14	complex	complex	NOUN
eurjchem-2485	20	15	was	be	AUX
eurjchem-2485	20	16	formed	form	VERB
eurjchem-2485	20	17	containing	contain	VERB
eurjchem-2485	20	18	four	four	NUM
eurjchem-2485	20	19	vanadiums	vanadium	NOUN
eurjchem-2485	20	20	,	,	PUNCT
eurjchem-2485	20	21	six	six	NUM
eurjchem-2485	20	22	acac	acac	ADJ
eurjchem-2485	20	23	ligands	ligand	NOUN
eurjchem-2485	20	24	,	,	PUNCT
eurjchem-2485	20	25	two	two	NUM
eurjchem-2485	20	26	1,3	1,3	NUM
eurjchem-2485	20	27	-	-	PUNCT
eurjchem-2485	20	28	diazine	diazine	NOUN
eurjchem-2485	20	29	molecules	molecule	NOUN
eurjchem-2485	20	30	bridging	bridging	NOUN
eurjchem-2485	20	31	,	,	PUNCT
eurjchem-2485	20	32	a	a	DET
eurjchem-2485	20	33	chloride	chloride	NOUN
eurjchem-2485	20	34	anion	anion	NOUN
eurjchem-2485	20	35	and	and	CCONJ
eurjchem-2485	20	36	a	a	DET
eurjchem-2485	20	37	hydroxide	hydroxide	NOUN
eurjchem-2485	20	38	counter	counter	NOUN
eurjchem-2485	20	39	anion	anion	NOUN
eurjchem-2485	20	40	(	(	PUNCT
eurjchem-2485	20	41	which	which	PRON
eurjchem-2485	20	42	is	be	AUX
eurjchem-2485	20	43	bridging	bridge	VERB
eurjchem-2485	20	44	two	two	NUM
eurjchem-2485	20	45	of	of	ADP
eurjchem-2485	20	46	the	the	DET
eurjchem-2485	20	47	vanadyls	vanadyls	ADJ
eurjchem-2485	20	48	)	)	PUNCT
eurjchem-2485	20	49	,	,	PUNCT
eurjchem-2485	20	50	having	have	VERB
eurjchem-2485	20	51	composition	composition	NOUN
eurjchem-2485	20	52	c38h51cln4o17v4	c38h51cln4o17v4	NOUN
eurjchem-2485	20	53	,	,	PUNCT
eurjchem-2485	20	54	which	which	PRON
eurjchem-2485	20	55	showed	show	VERB
eurjchem-2485	20	56	totally	totally	ADV
eurjchem-2485	20	57	unexpected	unexpected	ADJ
eurjchem-2485	20	58	compositional	compositional	ADJ
eurjchem-2485	20	59	and	and	CCONJ
eurjchem-2485	20	60	structural	structural	ADJ
eurjchem-2485	20	61	features	feature	NOUN
eurjchem-2485	20	62	,	,	PUNCT
eurjchem-2485	20	63	as	as	SCONJ
eurjchem-2485	20	64	described	describe	VERB
eurjchem-2485	20	65	in	in	ADP
eurjchem-2485	20	66	what	what	PRON
eurjchem-2485	20	67	follows	follow	VERB
eurjchem-2485	20	68	.	.	PUNCT
eurjchem-2485	21	1	interestingly	interestingly	ADV
eurjchem-2485	21	2	,	,	PUNCT
eurjchem-2485	21	3	in	in	ADP
eurjchem-2485	21	4	preparation	preparation	NOUN
eurjchem-2485	21	5	,	,	PUNCT
eurjchem-2485	21	6	the	the	DET
eurjchem-2485	21	7	addition	addition	NOUN
eurjchem-2485	21	8	of	of	ADP
eurjchem-2485	21	9	12	12	NUM
eurjchem-2485	21	10	m	m	NOUN
eurjchem-2485	21	11	hcl	hcl	PROPN
eurjchem-2485	21	12	led	lead	VERB
eurjchem-2485	21	13	to	to	ADP
eurjchem-2485	21	14	the	the	DET
eurjchem-2485	21	15	removal	removal	NOUN
eurjchem-2485	21	16	of	of	ADP
eurjchem-2485	21	17	one	one	NUM
eurjchem-2485	21	18	acac	acac	ADJ
eurjchem-2485	21	19	ligand	ligand	NOUN
eurjchem-2485	21	20	per	per	ADP
eurjchem-2485	21	21	vanadyl(acac)2	vanadyl(acac)2	NOUN
eurjchem-2485	21	22	(	(	PUNCT
eurjchem-2485	21	23	1,3	1,3	NUM
eurjchem-2485	21	24	-	-	PUNCT
eurjchem-2485	21	25	diazine	diazine	NOUN
eurjchem-2485	21	26	)	)	PUNCT
eurjchem-2485	21	27	fragment	fragment	NOUN
eurjchem-2485	21	28	and	and	CCONJ
eurjchem-2485	21	29	replaced	replace	VERB
eurjchem-2485	21	30	these	these	PRON
eurjchem-2485	21	31	with	with	ADP
eurjchem-2485	21	32	one	one	NUM
eurjchem-2485	21	33	chloride	chloride	NOUN
eurjchem-2485	21	34	and	and	CCONJ
eurjchem-2485	21	35	one	one	NUM
eurjchem-2485	21	36	oh	oh	INTJ
eurjchem-2485	21	37	–	–	PUNCT
eurjchem-2485	21	38	ion	ion	NOUN
eurjchem-2485	21	39	,	,	PUNCT
eurjchem-2485	21	40	to	to	PART
eurjchem-2485	21	41	take	take	VERB
eurjchem-2485	21	42	care	care	NOUN
eurjchem-2485	21	43	of	of	ADP
eurjchem-2485	21	44	the	the	DET
eurjchem-2485	21	45	charge	charge	NOUN
eurjchem-2485	21	46	compensation	compensation	NOUN
eurjchem-2485	21	47	;	;	PUNCT
eurjchem-2485	21	48	the	the	DET
eurjchem-2485	21	49	oh	oh	INTJ
eurjchem-2485	21	50	–	–	PUNCT
eurjchem-2485	21	51	counter	counter	NOUN
eurjchem-2485	21	52	anion	anion	NOUN
eurjchem-2485	21	53	bridges	bridge	NOUN
eurjchem-2485	21	54	the	the	DET
eurjchem-2485	21	55	two	two	NUM
eurjchem-2485	21	56	central	central	ADJ
eurjchem-2485	21	57	vanadyl	vanadyl	NOUN
eurjchem-2485	21	58	moieties	moiety	NOUN
eurjchem-2485	21	59	.	.	PUNCT
eurjchem-2485	22	1	abstract	abstract	ADJ
eurjchem-2485	22	2	research	research	NOUN
eurjchem-2485	22	3	article	article	NOUN
eurjchem-2485	22	4	keywords	keyword	VERB
eurjchem-2485	22	5	https://dx.doi.org/10.5155/eurjchem.14.4.494-498.2485	https://dx.doi.org/10.5155/eurjchem.14.4.494-498.2485	PROPN
eurjchem-2485	22	6	https://www.eurjchem.com/	https://www.eurjchem.com/	VERB
eurjchem-2485	22	7	https://dx.doi.org/10.5155/eurjchem.14.4.494-498.2485	https://dx.doi.org/10.5155/eurjchem.14.4.494-498.2485	PROPN
eurjchem-2485	22	8	mailto:rogerlal@newark.rutgers.edu	mailto:rogerlal@newark.rutgers.edu	PROPN
eurjchem-2485	22	9	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2485	22	10	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.4.494-498.2485&domain=pdf&date_stamp=2023-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.4.494-498.2485&domain=pdf&date_stamp=2023-12-31	NOUN
eurjchem-2485	22	11	bernal	bernal	PROPN
eurjchem-2485	22	12	and	and	CCONJ
eurjchem-2485	22	13	lalancette	lalancette	PROPN
eurjchem-2485	22	14	/	/	SYM
eurjchem-2485	22	15	european	european	PROPN
eurjchem-2485	22	16	journal	journal	PROPN
eurjchem-2485	22	17	of	of	ADP
eurjchem-2485	22	18	chemistry	chemistry	NOUN
eurjchem-2485	22	19	14	14	NUM
eurjchem-2485	22	20	(	(	PUNCT
eurjchem-2485	22	21	4	4	NUM
eurjchem-2485	22	22	)	)	PUNCT
eurjchem-2485	22	23	(	(	PUNCT
eurjchem-2485	22	24	2023	2023	NUM
eurjchem-2485	22	25	)	)	PUNCT
eurjchem-2485	22	26	494	494	NUM
eurjchem-2485	22	27	-	-	SYM
eurjchem-2485	22	28	498	498	NUM
eurjchem-2485	22	29	495	495	NUM
eurjchem-2485	22	30	2023	2023	NUM
eurjchem-2485	22	31	–	–	PUNCT
eurjchem-2485	22	32	european	european	ADJ
eurjchem-2485	22	33	journal	journal	NOUN
eurjchem-2485	22	34	of	of	ADP
eurjchem-2485	22	35	chemistry	chemistry	NOUN
eurjchem-2485	22	36	–	–	PUNCT
eurjchem-2485	22	37	cc	cc	NOUN
eurjchem-2485	22	38	by	by	ADP
eurjchem-2485	22	39	nc	nc	PROPN
eurjchem-2485	22	40	–	–	PUNCT
eurjchem-2485	22	41	doi	doi	NOUN
eurjchem-2485	22	42	:	:	PUNCT
eurjchem-2485	22	43	10.5155	10.5155	NUM
eurjchem-2485	22	44	/	/	SYM
eurjchem-2485	22	45	eurjchem.14.4.494	eurjchem.14.4.494	NUM
eurjchem-2485	22	46	-	-	SYM
eurjchem-2485	22	47	498.2485	498.2485	NUM
eurjchem-2485	22	48	table	table	NOUN
eurjchem-2485	22	49	1	1	NUM
eurjchem-2485	22	50	.	.	PUNCT
eurjchem-2485	22	51	crystal	crystal	NOUN
eurjchem-2485	22	52	data	datum	NOUN
eurjchem-2485	22	53	and	and	CCONJ
eurjchem-2485	22	54	structure	structure	NOUN
eurjchem-2485	22	55	refinement	refinement	NOUN
eurjchem-2485	22	56	for	for	ADP
eurjchem-2485	22	57	compound	compound	NOUN
eurjchem-2485	22	58	i.	i.	PROPN
eurjchem-2485	22	59	empirical	empirical	ADJ
eurjchem-2485	22	60	formula	formula	NOUN
eurjchem-2485	22	61	c38h51n4o17clv4	c38h51n4o17clv4	PROPN
eurjchem-2485	22	62	formula	formula	NOUN
eurjchem-2485	22	63	weight	weight	NOUN
eurjchem-2485	22	64	(	(	PUNCT
eurjchem-2485	22	65	g	g	NOUN
eurjchem-2485	22	66	/	/	SYM
eurjchem-2485	22	67	mol	mol	NOUN
eurjchem-2485	22	68	)	)	PUNCT
eurjchem-2485	22	69	1075.03	1075.03	NUM
eurjchem-2485	22	70	temperature	temperature	NOUN
eurjchem-2485	22	71	(	(	PUNCT
eurjchem-2485	22	72	k	k	NOUN
eurjchem-2485	22	73	)	)	PUNCT
eurjchem-2485	22	74	100(2	100(2	NUM
eurjchem-2485	22	75	)	)	PUNCT
eurjchem-2485	22	76	crystal	crystal	NOUN
eurjchem-2485	22	77	system	system	NOUN
eurjchem-2485	22	78	orthorhombic	orthorhombic	NOUN
eurjchem-2485	22	79	space	space	NOUN
eurjchem-2485	22	80	group	group	NOUN
eurjchem-2485	22	81	pca21	pca21	PROPN
eurjchem-2485	22	82	a	a	PROPN
eurjchem-2485	22	83	,	,	PUNCT
eurjchem-2485	22	84	(	(	PUNCT
eurjchem-2485	22	85	å	å	NOUN
eurjchem-2485	22	86	)	)	PUNCT
eurjchem-2485	22	87	26.4698(3	26.4698(3	NUM
eurjchem-2485	22	88	)	)	PUNCT
eurjchem-2485	22	89	b	b	NOUN
eurjchem-2485	22	90	,	,	PUNCT
eurjchem-2485	22	91	(	(	PUNCT
eurjchem-2485	22	92	å	å	NOUN
eurjchem-2485	22	93	)	)	PUNCT
eurjchem-2485	22	94	13.5167(2	13.5167(2	NUM
eurjchem-2485	22	95	)	)	PUNCT
eurjchem-2485	22	96	c	c	NOUN
eurjchem-2485	22	97	,	,	PUNCT
eurjchem-2485	22	98	(	(	PUNCT
eurjchem-2485	22	99	å	å	NOUN
eurjchem-2485	22	100	)	)	PUNCT
eurjchem-2485	22	101	12.7659(2	12.7659(2	NUM
eurjchem-2485	22	102	)	)	PUNCT
eurjchem-2485	22	103	volume	volume	NOUN
eurjchem-2485	22	104	(	(	PUNCT
eurjchem-2485	22	105	å3	å3	PROPN
eurjchem-2485	22	106	)	)	PUNCT
eurjchem-2485	22	107	4567.44(11	4567.44(11	NOUN
eurjchem-2485	22	108	)	)	PUNCT
eurjchem-2485	22	109	z	z	NOUN
eurjchem-2485	22	110	4	4	NUM
eurjchem-2485	22	111	ρcalc	ρcalc	NOUN
eurjchem-2485	22	112	(	(	PUNCT
eurjchem-2485	22	113	g	g	NOUN
eurjchem-2485	22	114	/	/	SYM
eurjchem-2485	22	115	cm3	cm3	NOUN
eurjchem-2485	22	116	)	)	PUNCT
eurjchem-2485	22	117	1.53	1.53	NUM
eurjchem-2485	22	118	μ	μ	NOUN
eurjchem-2485	22	119	(	(	PUNCT
eurjchem-2485	22	120	mm-1	mm-1	NOUN
eurjchem-2485	22	121	)	)	PUNCT
eurjchem-2485	22	122	7.842	7.842	NUM
eurjchem-2485	22	123	f(000	f(000	NOUN
eurjchem-2485	22	124	)	)	PUNCT
eurjchem-2485	22	125	2208.0	2208.0	NUM
eurjchem-2485	22	126	crystal	crystal	NOUN
eurjchem-2485	22	127	size	size	NOUN
eurjchem-2485	22	128	(	(	PUNCT
eurjchem-2485	22	129	mm3	mm3	PROPN
eurjchem-2485	22	130	)	)	PUNCT
eurjchem-2485	22	131	0.21	0.21	NUM
eurjchem-2485	22	132	×	×	NOUN
eurjchem-2485	22	133	0.144	0.144	NUM
eurjchem-2485	22	134	×	×	NOUN
eurjchem-2485	22	135	0.127	0.127	NUM
eurjchem-2485	22	136	radiation	radiation	NOUN
eurjchem-2485	22	137	cukα	cukα	NOUN
eurjchem-2485	22	138	(	(	PUNCT
eurjchem-2485	22	139	λ	λ	X
eurjchem-2485	22	140	=	=	NOUN
eurjchem-2485	22	141	1.54178	1.54178	NUM
eurjchem-2485	22	142	)	)	PUNCT
eurjchem-2485	22	143	2θ	2θ	NUM
eurjchem-2485	22	144	range	range	VERB
eurjchem-2485	22	145	for	for	ADP
eurjchem-2485	22	146	data	data	NOUN
eurjchem-2485	22	147	collection	collection	NOUN
eurjchem-2485	22	148	(	(	PUNCT
eurjchem-2485	22	149	°	°	PROPN
eurjchem-2485	22	150	)	)	PUNCT
eurjchem-2485	22	151	6.538	6.538	NUM
eurjchem-2485	22	152	to	to	ADP
eurjchem-2485	22	153	137.892	137.892	NUM
eurjchem-2485	22	154	index	index	NOUN
eurjchem-2485	22	155	ranges	range	VERB
eurjchem-2485	22	156	-30	-30	PROPN
eurjchem-2485	22	157	≤	≤	NUM
eurjchem-2485	22	158	h	h	NOUN
eurjchem-2485	22	159	≤	≤	NUM
eurjchem-2485	22	160	31	31	NUM
eurjchem-2485	22	161	,	,	PUNCT
eurjchem-2485	22	162	-15	-15	PUNCT
eurjchem-2485	22	163	≤	≤	NUM
eurjchem-2485	23	1	k	k	X
eurjchem-2485	23	2	≤	≤	NUM
eurjchem-2485	23	3	14	14	NUM
eurjchem-2485	23	4	,	,	PUNCT
eurjchem-2485	23	5	-14	-14	PUNCT
eurjchem-2485	23	6	≤	≤	NUM
eurjchem-2485	23	7	l	l	NOUN
eurjchem-2485	23	8	≤	≤	NUM
eurjchem-2485	23	9	15	15	NUM
eurjchem-2485	23	10	reflections	reflection	NOUN
eurjchem-2485	23	11	collected	collect	VERB
eurjchem-2485	23	12	41277	41277	NUM
eurjchem-2485	23	13	independent	independent	ADJ
eurjchem-2485	23	14	reflections	reflection	NOUN
eurjchem-2485	23	15	7841	7841	NUM
eurjchem-2485	24	1	[	[	X
eurjchem-2485	24	2	rint	rint	X
eurjchem-2485	24	3	=	=	SYM
eurjchem-2485	24	4	0.0428	0.0428	NUM
eurjchem-2485	24	5	,	,	PUNCT
eurjchem-2485	24	6	rsigma	rsigma	ADJ
eurjchem-2485	24	7	=	=	SYM
eurjchem-2485	24	8	0.0421	0.0421	NUM
eurjchem-2485	24	9	]	]	PUNCT
eurjchem-2485	24	10	data	data	NOUN
eurjchem-2485	24	11	/	/	SYM
eurjchem-2485	24	12	restraints	restraint	NOUN
eurjchem-2485	24	13	/	/	SYM
eurjchem-2485	24	14	parameters	parameter	NOUN
eurjchem-2485	24	15	7841/13/590	7841/13/590	NUM
eurjchem-2485	24	16	goodness	goodness	NOUN
eurjchem-2485	24	17	-	-	PUNCT
eurjchem-2485	24	18	of	of	ADP
eurjchem-2485	24	19	-	-	PUNCT
eurjchem-2485	24	20	fit	fit	NOUN
eurjchem-2485	24	21	on	on	ADP
eurjchem-2485	24	22	f2	f2	PROPN
eurjchem-2485	24	23	1.062	1.062	NUM
eurjchem-2485	24	24	final	final	ADJ
eurjchem-2485	24	25	r	r	NOUN
eurjchem-2485	24	26	indexes	index	NOUN
eurjchem-2485	25	1	[	[	X
eurjchem-2485	25	2	i≥2σ	i≥2σ	X
eurjchem-2485	25	3	(	(	PUNCT
eurjchem-2485	25	4	i	i	NOUN
eurjchem-2485	25	5	)	)	PUNCT
eurjchem-2485	25	6	]	]	PUNCT
eurjchem-2485	26	1	r1	r1	PROPN
eurjchem-2485	26	2	=	=	PUNCT
eurjchem-2485	26	3	0.0675	0.0675	NUM
eurjchem-2485	26	4	,	,	PUNCT
eurjchem-2485	26	5	wr2	wr2	PROPN
eurjchem-2485	26	6	=	=	PUNCT
eurjchem-2485	26	7	0.1512	0.1512	NUM
eurjchem-2485	26	8	final	final	ADJ
eurjchem-2485	26	9	r	r	NOUN
eurjchem-2485	26	10	indexes	index	NOUN
eurjchem-2485	26	11	[	[	X
eurjchem-2485	26	12	all	all	DET
eurjchem-2485	26	13	data	datum	NOUN
eurjchem-2485	26	14	]	]	PUNCT
eurjchem-2485	26	15	r1	r1	PROPN
eurjchem-2485	26	16	=	=	PUNCT
eurjchem-2485	26	17	0.0854	0.0854	PROPN
eurjchem-2485	26	18	,	,	PUNCT
eurjchem-2485	26	19	wr2	wr2	PROPN
eurjchem-2485	26	20	=	=	PROPN
eurjchem-2485	26	21	0.1641	0.1641	NUM
eurjchem-2485	26	22	largest	large	ADJ
eurjchem-2485	26	23	diff	diff	NOUN
eurjchem-2485	26	24	.	.	PUNCT
eurjchem-2485	26	25	peak	peak	PROPN
eurjchem-2485	26	26	/	/	SYM
eurjchem-2485	26	27	hole	hole	NOUN
eurjchem-2485	26	28	(	(	PUNCT
eurjchem-2485	26	29	e.å-3	e.å-3	PROPN
eurjchem-2485	26	30	)	)	PUNCT
eurjchem-2485	26	31	3.23/-1.28	3.23/-1.28	PROPN
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eurjchem-2485	26	33	parameter	parameter	NOUN
eurjchem-2485	26	34	0.51(2	0.51(2	NUM
eurjchem-2485	26	35	)	)	PUNCT
eurjchem-2485	26	36	ccdc	ccdc	NOUN
eurjchem-2485	26	37	no	no	INTJ
eurjchem-2485	26	38	.	.	PUNCT
eurjchem-2485	26	39	2201346	2201346	NUM
eurjchem-2485	26	40	programs	program	NOUN
eurjchem-2485	26	41	saint	saint	PROPN
eurjchem-2485	26	42	,	,	PUNCT
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eurjchem-2485	26	44	,	,	PUNCT
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eurjchem-2485	27	1	[	[	X
eurjchem-2485	27	2	4	4	NUM
eurjchem-2485	27	3	-	-	SYM
eurjchem-2485	27	4	6	6	NUM
eurjchem-2485	27	5	]	]	PUNCT
eurjchem-2485	27	6	,	,	PUNCT
eurjchem-2485	27	7	shelxl	shelxl	VERB
eurjchem-2485	27	8	[	[	X
eurjchem-2485	27	9	8	8	NUM
eurjchem-2485	27	10	]	]	PUNCT
eurjchem-2485	27	11	,	,	PUNCT
eurjchem-2485	27	12	diamond	diamond	NOUN
eurjchem-2485	28	1	[	[	X
eurjchem-2485	28	2	11	11	NUM
eurjchem-2485	28	3	]	]	PUNCT
eurjchem-2485	28	4	.	.	PUNCT
eurjchem-2485	29	1	figure	figure	NOUN
eurjchem-2485	29	2	1	1	NUM
eurjchem-2485	29	3	.	.	PUNCT
eurjchem-2485	30	1	the	the	DET
eurjchem-2485	30	2	tetra	tetra	NOUN
eurjchem-2485	30	3	-	-	PUNCT
eurjchem-2485	30	4	nuclear	nuclear	ADJ
eurjchem-2485	30	5	species	specie	NOUN
eurjchem-2485	30	6	incorporates	incorporate	VERB
eurjchem-2485	30	7	two	two	NUM
eurjchem-2485	30	8	vanadyls	vanadyls	ADJ
eurjchem-2485	30	9	,	,	PUNCT
eurjchem-2485	30	10	each	each	PRON
eurjchem-2485	30	11	with	with	ADP
eurjchem-2485	30	12	2	2	NUM
eurjchem-2485	30	13	acac	acac	NOUN
eurjchem-2485	30	14	ligands	ligand	NOUN
eurjchem-2485	30	15	,	,	PUNCT
eurjchem-2485	30	16	and	and	CCONJ
eurjchem-2485	30	17	has	have	VERB
eurjchem-2485	30	18	a	a	DET
eurjchem-2485	30	19	1,3	1,3	NUM
eurjchem-2485	30	20	-	-	PUNCT
eurjchem-2485	30	21	diazine	diazine	NOUN
eurjchem-2485	30	22	in	in	ADP
eurjchem-2485	30	23	the	the	DET
eurjchem-2485	30	24	sixth	sixth	ADJ
eurjchem-2485	30	25	position	position	NOUN
eurjchem-2485	30	26	.	.	PUNCT
eurjchem-2485	31	1	the	the	DET
eurjchem-2485	31	2	two	two	NUM
eurjchem-2485	31	3	central	central	ADJ
eurjchem-2485	31	4	vanadyl	vanadyl	NOUN
eurjchem-2485	31	5	moieties	moiety	NOUN
eurjchem-2485	31	6	,	,	PUNCT
eurjchem-2485	31	7	which	which	PRON
eurjchem-2485	31	8	have	have	VERB
eurjchem-2485	31	9	only	only	ADV
eurjchem-2485	31	10	one	one	NUM
eurjchem-2485	31	11	acac	acac	ADJ
eurjchem-2485	31	12	ligand	ligand	NOUN
eurjchem-2485	31	13	each	each	PRON
eurjchem-2485	31	14	,	,	PUNCT
eurjchem-2485	31	15	are	be	AUX
eurjchem-2485	31	16	joined	join	VERB
eurjchem-2485	31	17	to	to	ADP
eurjchem-2485	31	18	the	the	DET
eurjchem-2485	31	19	'	'	PUNCT
eurjchem-2485	31	20	outer	outer	ADJ
eurjchem-2485	31	21	'	'	PUNCT
eurjchem-2485	31	22	vanadyl	vanadyl	NOUN
eurjchem-2485	31	23	fragments	fragment	NOUN
eurjchem-2485	31	24	via	via	ADP
eurjchem-2485	31	25	1,3	1,3	NUM
eurjchem-2485	31	26	-	-	PUNCT
eurjchem-2485	31	27	diazine	diazine	NOUN
eurjchem-2485	31	28	linkers	linker	NOUN
eurjchem-2485	31	29	.	.	PUNCT
eurjchem-2485	32	1	finally	finally	ADV
eurjchem-2485	32	2	,	,	PUNCT
eurjchem-2485	32	3	v3	v3	PROPN
eurjchem-2485	32	4	is	be	AUX
eurjchem-2485	32	5	bonded	bond	VERB
eurjchem-2485	32	6	exclusively	exclusively	ADV
eurjchem-2485	32	7	by	by	ADP
eurjchem-2485	32	8	a	a	DET
eurjchem-2485	32	9	cl	cl	NOUN
eurjchem-2485	32	10	–	–	PUNCT
eurjchem-2485	32	11	counter	counter	NOUN
eurjchem-2485	32	12	anion	anion	NOUN
eurjchem-2485	32	13	,	,	PUNCT
eurjchem-2485	32	14	while	while	SCONJ
eurjchem-2485	32	15	v3	v3	PROPN
eurjchem-2485	32	16	and	and	CCONJ
eurjchem-2485	32	17	v4	v4	NOUN
eurjchem-2485	32	18	are	be	AUX
eurjchem-2485	32	19	bridged	bridge	VERB
eurjchem-2485	32	20	by	by	ADP
eurjchem-2485	32	21	the	the	DET
eurjchem-2485	32	22	unique	unique	ADJ
eurjchem-2485	32	23	oh	oh	INTJ
eurjchem-2485	32	24	–	–	PUNCT
eurjchem-2485	32	25	(	(	PUNCT
eurjchem-2485	32	26	o17	o17	NOUN
eurjchem-2485	32	27	)	)	PUNCT
eurjchem-2485	32	28	.	.	PUNCT
eurjchem-2485	33	1	furthermore	furthermore	ADV
eurjchem-2485	33	2	,	,	PUNCT
eurjchem-2485	33	3	a	a	X
eurjchem-2485	33	4	)	)	PUNCT
eurjchem-2485	33	5	no	no	DET
eurjchem-2485	33	6	oxidation	oxidation	NOUN
eurjchem-2485	33	7	-	-	PUNCT
eurjchem-2485	33	8	reduction	reduction	NOUN
eurjchem-2485	33	9	reaction	reaction	NOUN
eurjchem-2485	33	10	was	be	AUX
eurjchem-2485	33	11	found	find	VERB
eurjchem-2485	33	12	,	,	PUNCT
eurjchem-2485	33	13	and	and	CCONJ
eurjchem-2485	33	14	b	b	X
eurjchem-2485	33	15	)	)	PUNCT
eurjchem-2485	33	16	hcl	hcl	PROPN
eurjchem-2485	33	17	merely	merely	ADV
eurjchem-2485	33	18	causes	cause	VERB
eurjchem-2485	33	19	displacement	displacement	NOUN
eurjchem-2485	33	20	of	of	ADP
eurjchem-2485	33	21	the	the	DET
eurjchem-2485	33	22	acac	acac	PROPN
eurjchem-2485	33	23	ligands	ligand	NOUN
eurjchem-2485	33	24	from	from	ADP
eurjchem-2485	33	25	the	the	DET
eurjchem-2485	33	26	possible	possible	ADJ
eurjchem-2485	33	27	dimer	dimer	NOUN
eurjchem-2485	33	28	,	,	PUNCT
eurjchem-2485	33	29	and	and	CCONJ
eurjchem-2485	33	30	the	the	DET
eurjchem-2485	33	31	resulting	result	VERB
eurjchem-2485	33	32	fragments	fragment	NOUN
eurjchem-2485	33	33	are	be	AUX
eurjchem-2485	33	34	linked	link	VERB
eurjchem-2485	33	35	to	to	PART
eurjchem-2485	33	36	form	form	VERB
eurjchem-2485	33	37	the	the	DET
eurjchem-2485	33	38	tetramer	tetramer	NOUN
eurjchem-2485	33	39	.	.	PUNCT
eurjchem-2485	34	1	2.2	2.2	NUM
eurjchem-2485	34	2	.	.	PUNCT
eurjchem-2485	35	1	x	x	X
eurjchem-2485	35	2	-	-	PUNCT
eurjchem-2485	35	3	ray	ray	NOUN
eurjchem-2485	35	4	diffraction	diffraction	NOUN
eurjchem-2485	35	5	data	datum	NOUN
eurjchem-2485	35	6	collection	collection	NOUN
eurjchem-2485	35	7	and	and	CCONJ
eurjchem-2485	35	8	processing	process	VERB
eurjchem-2485	35	9	a	a	DET
eurjchem-2485	35	10	suitable	suitable	ADJ
eurjchem-2485	35	11	crystal	crystal	NOUN
eurjchem-2485	35	12	was	be	AUX
eurjchem-2485	35	13	mounted	mount	VERB
eurjchem-2485	35	14	on	on	ADP
eurjchem-2485	35	15	a	a	DET
eurjchem-2485	35	16	bruker	bruker	NOUN
eurjchem-2485	35	17	-	-	PUNCT
eurjchem-2485	35	18	axs	axs	PROPN
eurjchem-2485	35	19	smart	smart	ADJ
eurjchem-2485	35	20	apexii	apexii	NOUN
eurjchem-2485	35	21	ccd	ccd	PROPN
eurjchem-2485	35	22	diffractometer	diffractometer	NOUN
eurjchem-2485	35	23	at	at	ADP
eurjchem-2485	35	24	100(1	100(1	NUM
eurjchem-2485	35	25	)	)	PUNCT
eurjchem-2485	35	26	k.	k.	NOUN
eurjchem-2485	35	27	cell	cell	NOUN
eurjchem-2485	35	28	dimensions	dimension	NOUN
eurjchem-2485	35	29	and	and	CCONJ
eurjchem-2485	35	30	intensities	intensity	NOUN
eurjchem-2485	35	31	were	be	AUX
eurjchem-2485	35	32	collected	collect	VERB
eurjchem-2485	35	33	with	with	ADP
eurjchem-2485	35	34	cukα	cukα	ADJ
eurjchem-2485	35	35	radiation	radiation	NOUN
eurjchem-2485	35	36	(	(	PUNCT
eurjchem-2485	35	37	λ	λ	X
eurjchem-2485	35	38	=	=	X
eurjchem-2485	35	39	1.54178	1.54178	NUM
eurjchem-2485	35	40	å	å	NOUN
eurjchem-2485	35	41	)	)	PUNCT
eurjchem-2485	35	42	.	.	PUNCT
eurjchem-2485	36	1	data	datum	NOUN
eurjchem-2485	36	2	processing	processing	NOUN
eurjchem-2485	36	3	,	,	PUNCT
eurjchem-2485	36	4	lorentz	lorentz	PROPN
eurjchem-2485	36	5	polarization	polarization	NOUN
eurjchem-2485	36	6	,	,	PUNCT
eurjchem-2485	36	7	and	and	CCONJ
eurjchem-2485	36	8	face	face	NOUN
eurjchem-2485	36	9	-	-	PUNCT
eurjchem-2485	36	10	indexed	index	VERB
eurjchem-2485	36	11	numerical	numerical	ADJ
eurjchem-2485	36	12	absorption	absorption	NOUN
eurjchem-2485	36	13	corrections	correction	NOUN
eurjchem-2485	36	14	were	be	AUX
eurjchem-2485	36	15	performed	perform	VERB
eurjchem-2485	36	16	using	use	VERB
eurjchem-2485	36	17	saint	saint	NOUN
eurjchem-2485	36	18	,	,	PUNCT
eurjchem-2485	36	19	apex	apex	NOUN
eurjchem-2485	36	20	and	and	CCONJ
eurjchem-2485	36	21	sadabs	sadab	NOUN
eurjchem-2485	36	22	computer	computer	NOUN
eurjchem-2485	36	23	programs	program	NOUN
eurjchem-2485	36	24	[	[	X
eurjchem-2485	36	25	4	4	NUM
eurjchem-2485	36	26	-	-	SYM
eurjchem-2485	36	27	6	6	NUM
eurjchem-2485	36	28	]	]	PUNCT
eurjchem-2485	36	29	.	.	PUNCT
eurjchem-2485	37	1	the	the	DET
eurjchem-2485	37	2	structure	structure	NOUN
eurjchem-2485	37	3	was	be	AUX
eurjchem-2485	37	4	solved	solve	VERB
eurjchem-2485	37	5	by	by	ADP
eurjchem-2485	37	6	direct	direct	ADJ
eurjchem-2485	37	7	methods	method	NOUN
eurjchem-2485	37	8	and	and	CCONJ
eurjchem-2485	37	9	refined	refine	VERB
eurjchem-2485	37	10	by	by	ADP
eurjchem-2485	37	11	full	full	ADJ
eurjchem-2485	37	12	-	-	PUNCT
eurjchem-2485	37	13	matrix	matrix	NOUN
eurjchem-2485	37	14	least	least	ADJ
eurjchem-2485	37	15	squares	square	NOUN
eurjchem-2485	37	16	on	on	ADP
eurjchem-2485	37	17	f2	f2	PROPN
eurjchem-2485	37	18	,	,	PUNCT
eurjchem-2485	37	19	using	use	VERB
eurjchem-2485	37	20	the	the	DET
eurjchem-2485	37	21	shelxtl	shelxtl	NOUN
eurjchem-2485	37	22	v6.14	v6.14	PROPN
eurjchem-2485	37	23	program	program	NOUN
eurjchem-2485	37	24	package	package	NOUN
eurjchem-2485	37	25	[	[	X
eurjchem-2485	37	26	79	79	NUM
eurjchem-2485	37	27	]	]	PUNCT
eurjchem-2485	37	28	.	.	PUNCT
eurjchem-2485	38	1	non	non	ADJ
eurjchem-2485	38	2	-	-	ADJ
eurjchem-2485	38	3	h	h	ADJ
eurjchem-2485	38	4	atoms	atom	NOUN
eurjchem-2485	38	5	were	be	AUX
eurjchem-2485	38	6	refined	refine	VERB
eurjchem-2485	38	7	anisotropically	anisotropically	ADV
eurjchem-2485	38	8	.	.	PUNCT
eurjchem-2485	39	1	all	all	DET
eurjchem-2485	39	2	h	h	NOUN
eurjchem-2485	39	3	atoms	atom	NOUN
eurjchem-2485	39	4	were	be	AUX
eurjchem-2485	39	5	found	find	VERB
eurjchem-2485	39	6	on	on	ADP
eurjchem-2485	39	7	electron	electron	NOUN
eurjchem-2485	39	8	density	density	NOUN
eurjchem-2485	39	9	difference	difference	NOUN
eurjchem-2485	39	10	maps	map	NOUN
eurjchem-2485	39	11	;	;	PUNCT
eurjchem-2485	39	12	the	the	DET
eurjchem-2485	39	13	methyl	methyl	NOUN
eurjchem-2485	39	14	h	h	NOUN
eurjchem-2485	39	15	atoms	atom	NOUN
eurjchem-2485	39	16	were	be	AUX
eurjchem-2485	39	17	placed	place	VERB
eurjchem-2485	39	18	in	in	ADP
eurjchem-2485	39	19	ideal	ideal	ADJ
eurjchem-2485	39	20	staggered	stagger	VERB
eurjchem-2485	39	21	positions	position	NOUN
eurjchem-2485	39	22	with	with	ADP
eurjchem-2485	39	23	c	c	NOUN
eurjchem-2485	39	24	-	-	PUNCT
eurjchem-2485	39	25	h	h	NOUN
eurjchem-2485	39	26	distances	distance	NOUN
eurjchem-2485	39	27	of	of	ADP
eurjchem-2485	39	28	0.98	0.98	NUM
eurjchem-2485	39	29	å	å	NOUN
eurjchem-2485	39	30	and	and	CCONJ
eurjchem-2485	39	31	uiso(h	uiso(h	PROPN
eurjchem-2485	39	32	)	)	PUNCT
eurjchem-2485	39	33	=	=	SYM
eurjchem-2485	39	34	1.5ueq(c	1.5ueq(c	PROPN
eurjchem-2485	39	35	)	)	PUNCT
eurjchem-2485	39	36	;	;	PUNCT
eurjchem-2485	39	37	the	the	DET
eurjchem-2485	39	38	methine	methine	NOUN
eurjchem-2485	39	39	hs	hs	PROPN
eurjchem-2485	39	40	were	be	AUX
eurjchem-2485	39	41	placed	place	VERB
eurjchem-2485	39	42	in	in	ADP
eurjchem-2485	39	43	geometrically	geometrically	ADV
eurjchem-2485	39	44	idealized	idealize	VERB
eurjchem-2485	39	45	positions	position	NOUN
eurjchem-2485	39	46	and	and	CCONJ
eurjchem-2485	39	47	constrained	constrain	VERB
eurjchem-2485	39	48	to	to	PART
eurjchem-2485	39	49	ride	ride	VERB
eurjchem-2485	39	50	on	on	ADP
eurjchem-2485	39	51	their	their	PRON
eurjchem-2485	39	52	parent	parent	NOUN
eurjchem-2485	39	53	c	c	NOUN
eurjchem-2485	39	54	atoms	atom	NOUN
eurjchem-2485	39	55	with	with	ADP
eurjchem-2485	39	56	c	c	NOUN
eurjchem-2485	39	57	-	-	PUNCT
eurjchem-2485	39	58	h	h	NOUN
eurjchem-2485	39	59	distances	distance	NOUN
eurjchem-2485	39	60	of	of	ADP
eurjchem-2485	39	61	0.95	0.95	NUM
eurjchem-2485	39	62	å	å	NOUN
eurjchem-2485	39	63	and	and	CCONJ
eurjchem-2485	39	64	uiso(h	uiso(h	PROPN
eurjchem-2485	39	65	)	)	PUNCT
eurjchem-2485	39	66	=	=	SYM
eurjchem-2485	39	67	1.2ueq(c	1.2ueq(c	NUM
eurjchem-2485	39	68	)	)	PUNCT
eurjchem-2485	39	69	.	.	PUNCT
eurjchem-2485	40	1	the	the	DET
eurjchem-2485	40	2	crystal	crystal	PROPN
eurjchem-2485	40	3	data	data	PROPN
eurjchem-2485	40	4	,	,	PUNCT
eurjchem-2485	40	5	intensity	intensity	NOUN
eurjchem-2485	40	6	data	datum	NOUN
eurjchem-2485	40	7	collection	collection	NOUN
eurjchem-2485	40	8	,	,	PUNCT
eurjchem-2485	40	9	and	and	CCONJ
eurjchem-2485	40	10	structure	structure	NOUN
eurjchem-2485	40	11	refinement	refinement	NOUN
eurjchem-2485	40	12	details	detail	NOUN
eurjchem-2485	40	13	are	be	AUX
eurjchem-2485	40	14	summarized	summarize	VERB
eurjchem-2485	40	15	in	in	ADP
eurjchem-2485	40	16	table	table	NOUN
eurjchem-2485	40	17	1	1	NUM
eurjchem-2485	40	18	.	.	PUNCT
eurjchem-2485	41	1	the	the	DET
eurjchem-2485	41	2	xray	xray	PROPN
eurjchem-2485	41	3	data	datum	NOUN
eurjchem-2485	41	4	for	for	ADP
eurjchem-2485	41	5	i	i	PRON
eurjchem-2485	41	6	have	have	AUX
eurjchem-2485	41	7	been	be	AUX
eurjchem-2485	41	8	deposited	deposit	VERB
eurjchem-2485	41	9	in	in	ADP
eurjchem-2485	41	10	ccdc	ccdc	PROPN
eurjchem-2485	41	11	#	#	SYM
eurjchem-2485	41	12	2201346	2201346	NUM
eurjchem-2485	41	13	[	[	X
eurjchem-2485	41	14	10	10	NUM
eurjchem-2485	41	15	]	]	PUNCT
eurjchem-2485	41	16	.	.	PUNCT
eurjchem-2485	42	1	3	3	X
eurjchem-2485	42	2	.	.	NOUN
eurjchem-2485	42	3	results	result	NOUN
eurjchem-2485	42	4	and	and	CCONJ
eurjchem-2485	42	5	discussion	discussion	VERB
eurjchem-2485	42	6	the	the	DET
eurjchem-2485	42	7	molecule	molecule	NOUN
eurjchem-2485	42	8	consists	consist	VERB
eurjchem-2485	42	9	of	of	ADP
eurjchem-2485	42	10	two	two	NUM
eurjchem-2485	42	11	terminal	terminal	ADJ
eurjchem-2485	42	12	fragments	fragment	NOUN
eurjchem-2485	42	13	[	[	X
eurjchem-2485	42	14	(	(	PUNCT
eurjchem-2485	42	15	acac)2v	acac)2v	NOUN
eurjchem-2485	42	16	=	=	NOUN
eurjchem-2485	42	17	o	o	X
eurjchem-2485	42	18	]	]	X
eurjchem-2485	42	19	whose	whose	DET
eurjchem-2485	42	20	sixth	sixth	ADJ
eurjchem-2485	42	21	position	position	NOUN
eurjchem-2485	42	22	(	(	PUNCT
eurjchem-2485	42	23	per	per	ADP
eurjchem-2485	42	24	vanadyl	vanadyl	NOUN
eurjchem-2485	42	25	moiety	moiety	NOUN
eurjchem-2485	42	26	)	)	PUNCT
eurjchem-2485	42	27	is	be	AUX
eurjchem-2485	42	28	filled	fill	VERB
eurjchem-2485	42	29	with	with	ADP
eurjchem-2485	42	30	1,3	1,3	NUM
eurjchem-2485	42	31	-	-	PUNCT
eurjchem-2485	42	32	diazine	diazine	NOUN
eurjchem-2485	42	33	,	,	PUNCT
eurjchem-2485	42	34	as	as	SCONJ
eurjchem-2485	42	35	shown	show	VERB
eurjchem-2485	42	36	below	below	ADV
eurjchem-2485	42	37	in	in	ADP
eurjchem-2485	42	38	figure	figure	NOUN
eurjchem-2485	42	39	1	1	NUM
eurjchem-2485	42	40	.	.	PUNCT
eurjchem-2485	43	1	these	these	DET
eurjchem-2485	43	2	two	two	NUM
eurjchem-2485	43	3	fragments	fragment	NOUN
eurjchem-2485	43	4	are	be	AUX
eurjchem-2485	43	5	joined	join	VERB
eurjchem-2485	43	6	by	by	ADP
eurjchem-2485	43	7	an	an	DET
eurjchem-2485	43	8	asymmetric	asymmetric	ADJ
eurjchem-2485	43	9	species	specie	NOUN
eurjchem-2485	43	10	consisting	consist	VERB
eurjchem-2485	43	11	of	of	ADP
eurjchem-2485	43	12	a	a	DET
eurjchem-2485	43	13	dinuclear	dinuclear	ADJ
eurjchem-2485	43	14	vanadyl	vanadyl	NOUN
eurjchem-2485	43	15	cation	cation	NOUN
eurjchem-2485	43	16	moiety	moiety	NOUN
eurjchem-2485	43	17	bridged	bridge	VERB
eurjchem-2485	43	18	by	by	ADP
eurjchem-2485	43	19	a	a	DET
eurjchem-2485	43	20	hydroxide	hydroxide	NOUN
eurjchem-2485	43	21	(	(	PUNCT
eurjchem-2485	43	22	o17	o17	PROPN
eurjchem-2485	43	23	)	)	PUNCT
eurjchem-2485	43	24	(	(	PUNCT
eurjchem-2485	43	25	for	for	ADP
eurjchem-2485	43	26	more	more	ADJ
eurjchem-2485	43	27	details	detail	NOUN
eurjchem-2485	43	28	,	,	PUNCT
eurjchem-2485	43	29	see	see	VERB
eurjchem-2485	43	30	figure	figure	NOUN
eurjchem-2485	43	31	2	2	NUM
eurjchem-2485	43	32	)	)	PUNCT
eurjchem-2485	43	33	;	;	PUNCT
eurjchem-2485	43	34	however	however	ADV
eurjchem-2485	43	35	,	,	PUNCT
eurjchem-2485	43	36	the	the	DET
eurjchem-2485	43	37	two	two	NUM
eurjchem-2485	43	38	aforementioned	aforementioned	ADJ
eurjchem-2485	43	39	fragments	fragment	NOUN
eurjchem-2485	43	40	differ	differ	VERB
eurjchem-2485	43	41	in	in	ADP
eurjchem-2485	43	42	that	that	PRON
eurjchem-2485	43	43	only	only	ADJ
eurjchem-2485	43	44	v3	v3	PROPN
eurjchem-2485	43	45	has	have	VERB
eurjchem-2485	43	46	a	a	DET
eurjchem-2485	43	47	dangling	dangle	VERB
eurjchem-2485	43	48	cl	cl	NOUN
eurjchem-2485	43	49	counter	counter	NOUN
eurjchem-2485	43	50	anion	anion	NOUN
eurjchem-2485	43	51	.	.	PUNCT
eurjchem-2485	44	1	figure	figure	NOUN
eurjchem-2485	44	2	2	2	NUM
eurjchem-2485	44	3	shows	show	VERB
eurjchem-2485	44	4	the	the	DET
eurjchem-2485	44	5	central	central	ADJ
eurjchem-2485	44	6	vanadyl	vanadyl	NOUN
eurjchem-2485	44	7	cations	cation	NOUN
eurjchem-2485	44	8	with	with	ADP
eurjchem-2485	44	9	the	the	DET
eurjchem-2485	44	10	bridging	bridge	VERB
eurjchem-2485	44	11	hydroxide	hydroxide	NOUN
eurjchem-2485	44	12	and	and	CCONJ
eurjchem-2485	44	13	the	the	DET
eurjchem-2485	44	14	single	single	ADJ
eurjchem-2485	44	15	terminal	terminal	ADJ
eurjchem-2485	44	16	chloride	chloride	NOUN
eurjchem-2485	44	17	anion	anion	NOUN
eurjchem-2485	44	18	.	.	PUNCT
eurjchem-2485	45	1	the	the	DET
eurjchem-2485	45	2	distances	distance	NOUN
eurjchem-2485	45	3	in	in	ADP
eurjchem-2485	45	4	structure	structure	NOUN
eurjchem-2485	45	5	(	(	PUNCT
eurjchem-2485	45	6	i	i	NOUN
eurjchem-2485	45	7	)	)	PUNCT
eurjchem-2485	45	8	are	be	AUX
eurjchem-2485	45	9	the	the	DET
eurjchem-2485	45	10	following	follow	VERB
eurjchem-2485	45	11	:	:	PUNCT
eurjchem-2485	45	12	v3	v3	PROPN
eurjchem-2485	45	13	-	-	PUNCT
eurjchem-2485	45	14	cl1	cl1	NOUN
eurjchem-2485	45	15	=	=	SYM
eurjchem-2485	45	16	2.284(4	2.284(4	NUM
eurjchem-2485	45	17	)	)	PUNCT
eurjchem-2485	45	18	å	å	PROPN
eurjchem-2485	45	19	,	,	PUNCT
eurjchem-2485	45	20	v3	v3	PROPN
eurjchem-2485	45	21	-	-	PUNCT
eurjchem-2485	45	22	o17	o17	PROPN
eurjchem-2485	45	23	=	=	SYM
eurjchem-2485	45	24	2.141(8	2.141(8	NUM
eurjchem-2485	45	25	)	)	PUNCT
eurjchem-2485	45	26	and	and	CCONJ
eurjchem-2485	45	27	v4	v4	NOUN
eurjchem-2485	45	28	-	-	PUNCT
eurjchem-2485	45	29	o17	o17	NOUN
eurjchem-2485	45	30	=	=	SYM
eurjchem-2485	45	31	1.731(8	1.731(8	NUM
eurjchem-2485	45	32	)	)	PUNCT
eurjchem-2485	46	1	å	å	NOUN
eurjchem-2485	46	2	.	.	PUNCT
eurjchem-2485	47	1	the	the	DET
eurjchem-2485	47	2	distance	distance	NOUN
eurjchem-2485	47	3	of	of	ADP
eurjchem-2485	47	4	v	v	NOUN
eurjchem-2485	47	5	-	-	ADV
eurjchem-2485	47	6	oh	oh	NOUN
eurjchem-2485	47	7	can	can	AUX
eurjchem-2485	47	8	be	be	AUX
eurjchem-2485	47	9	compared	compare	VERB
eurjchem-2485	47	10	with	with	ADP
eurjchem-2485	47	11	1.968	1.968	NUM
eurjchem-2485	47	12	and	and	CCONJ
eurjchem-2485	47	13	1.959	1.959	NUM
eurjchem-2485	47	14	å	å	PROPN
eurjchem-2485	47	15	found	find	VERB
eurjchem-2485	47	16	in	in	ADP
eurjchem-2485	47	17	the	the	DET
eurjchem-2485	47	18	literature	literature	NOUN
eurjchem-2485	47	19	[	[	X
eurjchem-2485	47	20	12	12	NUM
eurjchem-2485	47	21	]	]	PUNCT
eurjchem-2485	47	22	.	.	PUNCT
eurjchem-2485	48	1	the	the	DET
eurjchem-2485	48	2	v	v	NOUN
eurjchem-2485	48	3	-	-	PUNCT
eurjchem-2485	48	4	cl	cl	NOUN
eurjchem-2485	48	5	distance	distance	NOUN
eurjchem-2485	48	6	from	from	ADP
eurjchem-2485	48	7	the	the	DET
eurjchem-2485	48	8	literature	literature	NOUN
eurjchem-2485	48	9	ranges	range	VERB
eurjchem-2485	48	10	from	from	ADP
eurjchem-2485	48	11	2.275	2.275	NUM
eurjchem-2485	48	12	to	to	ADP
eurjchem-2485	48	13	2.3031	2.3031	NUM
eurjchem-2485	48	14	å	å	X
eurjchem-2485	49	1	[	[	X
eurjchem-2485	49	2	13	13	NUM
eurjchem-2485	49	3	]	]	PUNCT
eurjchem-2485	49	4	;	;	PUNCT
eurjchem-2485	49	5	the	the	DET
eurjchem-2485	49	6	v	v	NOUN
eurjchem-2485	49	7	-	-	PUNCT
eurjchem-2485	49	8	cl	cl	NOUN
eurjchem-2485	49	9	distance	distance	NOUN
eurjchem-2485	49	10	in	in	ADP
eurjchem-2485	49	11	a	a	DET
eurjchem-2485	49	12	bridging	bridging	NOUN
eurjchem-2485	49	13	cl	cl	NOUN
eurjchem-2485	49	14	(	(	PUNCT
eurjchem-2485	49	15	between	between	ADP
eurjchem-2485	49	16	two	two	NUM
eurjchem-2485	49	17	vanadyls	vanadyls	ADJ
eurjchem-2485	49	18	)	)	PUNCT
eurjchem-2485	49	19	is	be	AUX
eurjchem-2485	49	20	2.470	2.470	NUM
eurjchem-2485	49	21	-	-	SYM
eurjchem-2485	49	22	2.490	2.490	NUM
eurjchem-2485	49	23	å	å	NOUN
eurjchem-2485	49	24	[	[	X
eurjchem-2485	49	25	14	14	NUM
eurjchem-2485	49	26	]	]	PUNCT
eurjchem-2485	49	27	.	.	PUNCT
eurjchem-2485	50	1	the	the	DET
eurjchem-2485	50	2	selected	select	VERB
eurjchem-2485	50	3	bond	bond	NOUN
eurjchem-2485	50	4	distances	distance	NOUN
eurjchem-2485	50	5	and	and	CCONJ
eurjchem-2485	50	6	angles	angle	NOUN
eurjchem-2485	50	7	are	be	AUX
eurjchem-2485	50	8	given	give	VERB
eurjchem-2485	50	9	in	in	ADP
eurjchem-2485	50	10	table	table	NOUN
eurjchem-2485	50	11	2	2	NUM
eurjchem-2485	50	12	.	.	SYM
eurjchem-2485	50	13	496	496	NUM
eurjchem-2485	50	14	bernal	bernal	PROPN
eurjchem-2485	50	15	and	and	CCONJ
eurjchem-2485	50	16	lalancette	lalancette	PROPN
eurjchem-2485	50	17	/	/	SYM
eurjchem-2485	50	18	european	european	PROPN
eurjchem-2485	50	19	journal	journal	PROPN
eurjchem-2485	50	20	of	of	ADP
eurjchem-2485	50	21	chemistry	chemistry	NOUN
eurjchem-2485	50	22	14	14	NUM
eurjchem-2485	50	23	(	(	PUNCT
eurjchem-2485	50	24	4	4	NUM
eurjchem-2485	50	25	)	)	PUNCT
eurjchem-2485	50	26	(	(	PUNCT
eurjchem-2485	50	27	2023	2023	NUM
eurjchem-2485	50	28	)	)	PUNCT
eurjchem-2485	50	29	494	494	NUM
eurjchem-2485	50	30	-	-	SYM
eurjchem-2485	50	31	498	498	NUM
eurjchem-2485	50	32	2023	2023	NUM
eurjchem-2485	50	33	–	–	PUNCT
eurjchem-2485	50	34	european	european	ADJ
eurjchem-2485	50	35	journal	journal	NOUN
eurjchem-2485	50	36	of	of	ADP
eurjchem-2485	50	37	chemistry	chemistry	NOUN
eurjchem-2485	50	38	–	–	PUNCT
eurjchem-2485	50	39	cc	cc	NOUN
eurjchem-2485	50	40	by	by	ADP
eurjchem-2485	50	41	nc	nc	PROPN
eurjchem-2485	50	42	–	–	PUNCT
eurjchem-2485	50	43	doi	doi	NOUN
eurjchem-2485	50	44	:	:	PUNCT
eurjchem-2485	50	45	10.5155	10.5155	NUM
eurjchem-2485	50	46	/	/	SYM
eurjchem-2485	50	47	eurjchem.14.4.494	eurjchem.14.4.494	NUM
eurjchem-2485	50	48	-	-	SYM
eurjchem-2485	50	49	498.2485	498.2485	NUM
eurjchem-2485	50	50	table	table	NOUN
eurjchem-2485	50	51	2	2	NUM
eurjchem-2485	50	52	.	.	NUM
eurjchem-2485	50	53	selected	select	VERB
eurjchem-2485	50	54	bond	bond	NOUN
eurjchem-2485	50	55	distances	distance	NOUN
eurjchem-2485	50	56	(	(	PUNCT
eurjchem-2485	50	57	å	å	NOUN
eurjchem-2485	50	58	)	)	PUNCT
eurjchem-2485	50	59	and	and	CCONJ
eurjchem-2485	50	60	angles	angle	NOUN
eurjchem-2485	50	61	(	(	PUNCT
eurjchem-2485	50	62	o	o	NOUN
eurjchem-2485	50	63	)	)	PUNCT
eurjchem-2485	50	64	for	for	ADP
eurjchem-2485	50	65	compound	compound	NOUN
eurjchem-2485	50	66	i.	i.	PROPN
eurjchem-2485	50	67	atom	atom	PROPN
eurjchem-2485	50	68	atom	atom	NOUN
eurjchem-2485	50	69	length	length	NOUN
eurjchem-2485	50	70	(	(	PUNCT
eurjchem-2485	50	71	å	å	NOUN
eurjchem-2485	50	72	)	)	PUNCT
eurjchem-2485	50	73	atom	atom	NOUN
eurjchem-2485	50	74	atom	atom	NOUN
eurjchem-2485	50	75	length	length	NOUN
eurjchem-2485	50	76	(	(	PUNCT
eurjchem-2485	50	77	å	å	NOUN
eurjchem-2485	50	78	)	)	PUNCT
eurjchem-2485	50	79	v3	v3	PROPN
eurjchem-2485	50	80	cl1	cl1	PROPN
eurjchem-2485	50	81	2.284(4	2.284(4	NOUN
eurjchem-2485	50	82	)	)	PUNCT
eurjchem-2485	50	83	v2	v2	PROPN
eurjchem-2485	50	84	o9	o9	NOUN
eurjchem-2485	50	85	2.010(9	2.010(9	NUM
eurjchem-2485	50	86	)	)	PUNCT
eurjchem-2485	50	87	v3	v3	PROPN
eurjchem-2485	50	88	o17	o17	PROPN
eurjchem-2485	50	89	2.141(8	2.141(8	NUM
eurjchem-2485	50	90	)	)	PUNCT
eurjchem-2485	51	1	v2	v2	PROPN
eurjchem-2485	51	2	o10	o10	NOUN
eurjchem-2485	51	3	1.972(8	1.972(8	NUM
eurjchem-2485	51	4	)	)	PUNCT
eurjchem-2485	51	5	v4	v4	NOUN
eurjchem-2485	51	6	o17	o17	NOUN
eurjchem-2485	51	7	1.731(8	1.731(8	NUM
eurjchem-2485	51	8	)	)	PUNCT
eurjchem-2485	52	1	v2	v2	PROPN
eurjchem-2485	52	2	n4	n4	PROPN
eurjchem-2485	52	3	2.452(12	2.452(12	NUM
eurjchem-2485	52	4	)	)	PUNCT
eurjchem-2485	52	5	v1	v1	NOUN
eurjchem-2485	52	6	o1	o1	NOUN
eurjchem-2485	52	7	1.602(10	1.602(10	NUM
eurjchem-2485	52	8	)	)	PUNCT
eurjchem-2485	52	9	v3	v3	PROPN
eurjchem-2485	52	10	o11	o11	PROPN
eurjchem-2485	52	11	1.665(10	1.665(10	NUM
eurjchem-2485	52	12	)	)	PUNCT
eurjchem-2485	52	13	v1	v1	NOUN
eurjchem-2485	52	14	o2	o2	ADJ
eurjchem-2485	52	15	1.990(9	1.990(9	NUM
eurjchem-2485	52	16	)	)	PUNCT
eurjchem-2485	52	17	v3	v3	PROPN
eurjchem-2485	52	18	o12	o12	PROPN
eurjchem-2485	52	19	2.044(10	2.044(10	NUM
eurjchem-2485	52	20	)	)	PUNCT
eurjchem-2485	52	21	v1	v1	PROPN
eurjchem-2485	52	22	o3	o3	PROPN
eurjchem-2485	52	23	2.012(10	2.012(10	NUM
eurjchem-2485	52	24	)	)	PUNCT
eurjchem-2485	52	25	v3	v3	PROPN
eurjchem-2485	52	26	o13	o13	NOUN
eurjchem-2485	52	27	1.956(9	1.956(9	NUM
eurjchem-2485	52	28	)	)	PUNCT
eurjchem-2485	52	29	v1	v1	NOUN
eurjchem-2485	52	30	o4	o4	PROPN
eurjchem-2485	52	31	1.985(9	1.985(9	NUM
eurjchem-2485	52	32	)	)	PUNCT
eurjchem-2485	52	33	v3	v3	PROPN
eurjchem-2485	52	34	n3	n3	PROPN
eurjchem-2485	52	35	2.077(11	2.077(11	NUM
eurjchem-2485	52	36	)	)	PUNCT
eurjchem-2485	52	37	v1	v1	PROPN
eurjchem-2485	52	38	o5	o5	PROPN
eurjchem-2485	52	39	2.027(9	2.027(9	NUM
eurjchem-2485	52	40	)	)	PUNCT
eurjchem-2485	52	41	v4	v4	NOUN
eurjchem-2485	52	42	o14	o14	NOUN
eurjchem-2485	52	43	1.602(12	1.602(12	NUM
eurjchem-2485	52	44	)	)	PUNCT
eurjchem-2485	52	45	v1	v1	NOUN
eurjchem-2485	52	46	n1	n1	NOUN
eurjchem-2485	52	47	2.477(11	2.477(11	NUM
eurjchem-2485	52	48	)	)	PUNCT
eurjchem-2485	52	49	v4	v4	NOUN
eurjchem-2485	52	50	o15	o15	X
eurjchem-2485	52	51	1.981(10	1.981(10	NUM
eurjchem-2485	52	52	)	)	PUNCT
eurjchem-2485	53	1	v2	v2	NOUN
eurjchem-2485	53	2	o6	o6	NOUN
eurjchem-2485	53	3	1.592(9	1.592(9	NUM
eurjchem-2485	53	4	)	)	PUNCT
eurjchem-2485	53	5	v4	v4	PROPN
eurjchem-2485	53	6	o16	o16	PROPN
eurjchem-2485	53	7	1.967(9	1.967(9	NUM
eurjchem-2485	53	8	)	)	PUNCT
eurjchem-2485	53	9	v2	v2	PROPN
eurjchem-2485	53	10	o7	o7	PROPN
eurjchem-2485	53	11	1.994(9	1.994(9	NUM
eurjchem-2485	53	12	)	)	PUNCT
eurjchem-2485	53	13	v4	v4	NOUN
eurjchem-2485	53	14	n2	n2	NOUN
eurjchem-2485	53	15	2.225(11	2.225(11	NUM
eurjchem-2485	53	16	)	)	PUNCT
eurjchem-2485	53	17	v2	v2	PROPN
eurjchem-2485	53	18	o8	o8	NOUN
eurjchem-2485	53	19	1.977(11	1.977(11	NUM
eurjchem-2485	53	20	)	)	PUNCT
eurjchem-2485	53	21	atom	atom	NOUN
eurjchem-2485	53	22	atom	atom	NOUN
eurjchem-2485	53	23	atom	atom	NOUN
eurjchem-2485	53	24	angle	angle	NOUN
eurjchem-2485	53	25	(	(	PUNCT
eurjchem-2485	53	26	°	°	NOUN
eurjchem-2485	53	27	)	)	PUNCT
eurjchem-2485	53	28	atom	atom	NOUN
eurjchem-2485	53	29	atom	atom	NOUN
eurjchem-2485	53	30	atom	atom	NOUN
eurjchem-2485	53	31	angle	angle	NOUN
eurjchem-2485	53	32	(	(	PUNCT
eurjchem-2485	53	33	°	°	NOUN
eurjchem-2485	53	34	)	)	PUNCT
eurjchem-2485	53	35	o1	o1	NOUN
eurjchem-2485	53	36	v1	v1	NOUN
eurjchem-2485	53	37	o2	o2	PROPN
eurjchem-2485	53	38	101.0(4	101.0(4	NUM
eurjchem-2485	53	39	)	)	PUNCT
eurjchem-2485	53	40	o10	o10	NOUN
eurjchem-2485	53	41	v2	v2	NOUN
eurjchem-2485	53	42	o9	o9	PROPN
eurjchem-2485	53	43	89.0(3	89.0(3	NUM
eurjchem-2485	53	44	)	)	PUNCT
eurjchem-2485	53	45	o1	o1	NOUN
eurjchem-2485	53	46	v1	v1	NOUN
eurjchem-2485	53	47	o3	o3	PROPN
eurjchem-2485	53	48	98.5(4	98.5(4	NUM
eurjchem-2485	53	49	)	)	PUNCT
eurjchem-2485	53	50	o10	o10	NOUN
eurjchem-2485	53	51	v2	v2	PROPN
eurjchem-2485	53	52	n4	n4	PROPN
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eurjchem-2485	53	54	)	)	PUNCT
eurjchem-2485	53	55	o1	o1	NOUN
eurjchem-2485	53	56	v1	v1	NOUN
eurjchem-2485	53	57	o4	o4	PROPN
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eurjchem-2485	53	61	v3	v3	PROPN
eurjchem-2485	53	62	cl1	cl1	PROPN
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eurjchem-2485	53	66	v1	v1	NOUN
eurjchem-2485	53	67	o5	o5	PROPN
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eurjchem-2485	53	71	v3	v3	PROPN
eurjchem-2485	53	72	cl1	cl1	PROPN
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eurjchem-2485	53	74	)	)	PUNCT
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eurjchem-2485	53	76	v1	v1	NOUN
eurjchem-2485	53	77	n1	n1	PROPN
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eurjchem-2485	53	79	)	)	PUNCT
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eurjchem-2485	53	81	v3	v3	PROPN
eurjchem-2485	53	82	o17	o17	PROPN
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eurjchem-2485	53	84	)	)	PUNCT
eurjchem-2485	53	85	o2	o2	PROPN
eurjchem-2485	53	86	v1	v1	PROPN
eurjchem-2485	53	87	o3	o3	PROPN
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eurjchem-2485	53	89	)	)	PUNCT
eurjchem-2485	53	90	o11	o11	PROPN
eurjchem-2485	53	91	v3	v3	PROPN
eurjchem-2485	53	92	o12	o12	PROPN
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eurjchem-2485	53	94	)	)	PUNCT
eurjchem-2485	53	95	o2	o2	PROPN
eurjchem-2485	53	96	v1	v1	PROPN
eurjchem-2485	53	97	o5	o5	PROPN
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eurjchem-2485	53	99	)	)	PUNCT
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eurjchem-2485	53	101	v3	v3	PROPN
eurjchem-2485	53	102	o13	o13	NOUN
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eurjchem-2485	53	104	)	)	PUNCT
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eurjchem-2485	53	106	v1	v1	NOUN
eurjchem-2485	53	107	n1	n1	PROPN
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eurjchem-2485	53	109	)	)	PUNCT
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eurjchem-2485	53	111	v3	v3	PROPN
eurjchem-2485	53	112	n3	n3	PROPN
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eurjchem-2485	53	114	)	)	PUNCT
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eurjchem-2485	53	116	v1	v1	PROPN
eurjchem-2485	53	117	o5	o5	PROPN
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eurjchem-2485	53	119	)	)	PUNCT
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eurjchem-2485	53	121	v3	v3	PROPN
eurjchem-2485	53	122	cl1	cl1	PROPN
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eurjchem-2485	53	124	)	)	PUNCT
eurjchem-2485	53	125	o3	o3	PROPN
eurjchem-2485	53	126	v1	v1	PROPN
eurjchem-2485	53	127	n1	n1	PROPN
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eurjchem-2485	53	129	)	)	PUNCT
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eurjchem-2485	53	131	v3	v3	PROPN
eurjchem-2485	53	132	o17	o17	PROPN
eurjchem-2485	53	133	87.6(4	87.6(4	PROPN
eurjchem-2485	53	134	)	)	PUNCT
eurjchem-2485	54	1	o4	o4	PROPN
eurjchem-2485	54	2	v1	v1	VERB
eurjchem-2485	54	3	o2	o2	PROPN
eurjchem-2485	54	4	86.0(4	86.0(4	PROPN
eurjchem-2485	54	5	)	)	PUNCT
eurjchem-2485	54	6	o12	o12	PROPN
eurjchem-2485	54	7	v3	v3	PROPN
eurjchem-2485	54	8	n3	n3	PROPN
eurjchem-2485	54	9	82.8(4	82.8(4	PROPN
eurjchem-2485	54	10	)	)	PUNCT
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eurjchem-2485	54	12	v1	v1	PROPN
eurjchem-2485	54	13	o3	o3	PROPN
eurjchem-2485	54	14	157.9(4	157.9(4	NUM
eurjchem-2485	54	15	)	)	PUNCT
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eurjchem-2485	54	17	v3	v3	PROPN
eurjchem-2485	54	18	cl1	cl1	PROPN
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eurjchem-2485	54	20	)	)	PUNCT
eurjchem-2485	54	21	o4	o4	PROPN
eurjchem-2485	54	22	v1	v1	PROPN
eurjchem-2485	54	23	o5	o5	PROPN
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eurjchem-2485	54	25	)	)	PUNCT
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eurjchem-2485	54	27	v3	v3	PROPN
eurjchem-2485	54	28	o17	o17	PROPN
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eurjchem-2485	54	30	)	)	PUNCT
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eurjchem-2485	54	32	v1	v1	VERB
eurjchem-2485	54	33	n1	n1	ADJ
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eurjchem-2485	54	35	)	)	PUNCT
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eurjchem-2485	54	37	v3	v3	PROPN
eurjchem-2485	54	38	o12	o12	PROPN
eurjchem-2485	54	39	88.0(4	88.0(4	NUM
eurjchem-2485	54	40	)	)	PUNCT
eurjchem-2485	54	41	o5	o5	PROPN
eurjchem-2485	54	42	v1	v1	PROPN
eurjchem-2485	54	43	n1	n1	PROPN
eurjchem-2485	54	44	79.5(4	79.5(4	NOUN
eurjchem-2485	54	45	)	)	PUNCT
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eurjchem-2485	54	47	v3	v3	PROPN
eurjchem-2485	54	48	n3	n3	PROPN
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eurjchem-2485	54	50	)	)	PUNCT
eurjchem-2485	54	51	o6	o6	PROPN
eurjchem-2485	54	52	v2	v2	PROPN
eurjchem-2485	54	53	o7	o7	PROPN
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eurjchem-2485	54	55	)	)	PUNCT
eurjchem-2485	54	56	n3	n3	PROPN
eurjchem-2485	54	57	v3	v3	PROPN
eurjchem-2485	54	58	cl1	cl1	PROPN
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eurjchem-2485	55	1	o6	o6	VERB
eurjchem-2485	55	2	v2	v2	NOUN
eurjchem-2485	55	3	o8	o8	NOUN
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eurjchem-2485	55	5	)	)	PUNCT
eurjchem-2485	55	6	n3	n3	PROPN
eurjchem-2485	55	7	v3	v3	PROPN
eurjchem-2485	55	8	o17	o17	PROPN
eurjchem-2485	55	9	79.5(4	79.5(4	PROPN
eurjchem-2485	55	10	)	)	PUNCT
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eurjchem-2485	55	12	v2	v2	PROPN
eurjchem-2485	55	13	o9	o9	PROPN
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eurjchem-2485	55	15	)	)	PUNCT
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eurjchem-2485	55	17	v4	v4	NOUN
eurjchem-2485	55	18	o15	o15	NOUN
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eurjchem-2485	55	20	)	)	PUNCT
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eurjchem-2485	55	22	v2	v2	PROPN
eurjchem-2485	55	23	o10	o10	NUM
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eurjchem-2485	55	25	)	)	PUNCT
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eurjchem-2485	55	27	v4	v4	PROPN
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eurjchem-2485	55	30	)	)	PUNCT
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eurjchem-2485	55	32	v2	v2	PROPN
eurjchem-2485	56	1	n4	n4	PROPN
eurjchem-2485	56	2	179.4(5	179.4(5	PROPN
eurjchem-2485	56	3	)	)	PUNCT
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eurjchem-2485	56	5	v4	v4	PROPN
eurjchem-2485	56	6	n2	n2	NOUN
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eurjchem-2485	56	8	)	)	PUNCT
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eurjchem-2485	56	11	o9	o9	PROPN
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eurjchem-2485	56	13	)	)	PUNCT
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eurjchem-2485	56	15	v4	v4	VERB
eurjchem-2485	56	16	o17	o17	ADJ
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eurjchem-2485	56	18	)	)	PUNCT
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eurjchem-2485	56	20	v2	v2	PROPN
eurjchem-2485	56	21	n4	n4	PROPN
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eurjchem-2485	56	23	)	)	PUNCT
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eurjchem-2485	56	25	v4	v4	NOUN
eurjchem-2485	56	26	o15	o15	NOUN
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eurjchem-2485	56	28	)	)	PUNCT
eurjchem-2485	57	1	o8	o8	PROPN
eurjchem-2485	57	2	v2	v2	PROPN
eurjchem-2485	57	3	o7	o7	PROPN
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eurjchem-2485	57	5	)	)	PUNCT
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eurjchem-2485	57	7	v4	v4	VERB
eurjchem-2485	57	8	o16	o16	X
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eurjchem-2485	57	10	)	)	PUNCT
eurjchem-2485	57	11	o8	o8	NOUN
eurjchem-2485	57	12	v2	v2	NOUN
eurjchem-2485	57	13	o9	o9	NOUN
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eurjchem-2485	57	15	)	)	PUNCT
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eurjchem-2485	57	17	v4	v4	PROPN
eurjchem-2485	57	18	n2	n2	PROPN
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eurjchem-2485	57	20	)	)	PUNCT
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eurjchem-2485	57	22	v2	v2	PROPN
eurjchem-2485	57	23	n4	n4	PROPN
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eurjchem-2485	57	25	)	)	PUNCT
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eurjchem-2485	57	27	v4	v4	PROPN
eurjchem-2485	57	28	n2	n2	ADJ
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eurjchem-2485	57	30	)	)	PUNCT
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eurjchem-2485	57	33	n4	n4	PROPN
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eurjchem-2485	57	35	)	)	PUNCT
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eurjchem-2485	57	37	v4	v4	PROPN
eurjchem-2485	57	38	o15	o15	NOUN
eurjchem-2485	57	39	87.3(4	87.3(4	NOUN
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eurjchem-2485	57	42	v2	v2	PROPN
eurjchem-2485	57	43	o7	o7	PROPN
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eurjchem-2485	57	45	)	)	PUNCT
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eurjchem-2485	57	47	v4	v4	NOUN
eurjchem-2485	57	48	n2	n2	ADJ
eurjchem-2485	57	49	167.4(4	167.4(4	NUM
eurjchem-2485	57	50	)	)	PUNCT
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eurjchem-2485	57	52	v2	v2	NOUN
eurjchem-2485	57	53	o8	o8	NOUN
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eurjchem-2485	57	55	)	)	PUNCT
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eurjchem-2485	57	57	2	2	NUM
eurjchem-2485	57	58	.	.	PUNCT
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eurjchem-2485	58	12	factors	factor	NOUN
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eurjchem-2485	58	14	form	form	VERB
eurjchem-2485	58	15	part	part	NOUN
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eurjchem-2485	58	17	the	the	DET
eurjchem-2485	58	18	discussion	discussion	NOUN
eurjchem-2485	58	19	that	that	PRON
eurjchem-2485	58	20	follows	follow	VERB
eurjchem-2485	58	21	.	.	PUNCT
eurjchem-2485	59	1	figure	figure	VERB
eurjchem-2485	59	2	3	3	NUM
eurjchem-2485	59	3	.	.	PUNCT
eurjchem-2485	59	4	adahui	adahui	PROPN
eurjchem-2485	60	1	[	[	X
eurjchem-2485	60	2	15	15	NUM
eurjchem-2485	60	3	]	]	PUNCT
eurjchem-2485	60	4	as	as	SCONJ
eurjchem-2485	60	5	drawn	draw	VERB
eurjchem-2485	60	6	from	from	ADP
eurjchem-2485	60	7	the	the	DET
eurjchem-2485	60	8	data	datum	NOUN
eurjchem-2485	60	9	in	in	ADP
eurjchem-2485	60	10	the	the	DET
eurjchem-2485	60	11	cif	cif	PROPN
eurjchem-2485	60	12	document	document	NOUN
eurjchem-2485	60	13	in	in	ADP
eurjchem-2485	60	14	the	the	DET
eurjchem-2485	60	15	csd	csd	NOUN
eurjchem-2485	61	1	[	[	X
eurjchem-2485	61	2	10	10	NUM
eurjchem-2485	61	3	]	]	PUNCT
eurjchem-2485	61	4	.	.	PUNCT
eurjchem-2485	62	1	the	the	DET
eurjchem-2485	62	2	'	'	PUNCT
eurjchem-2485	62	3	bare	bare	ADJ
eurjchem-2485	62	4	'	'	PUNCT
eurjchem-2485	62	5	carbon	carbon	NOUN
eurjchem-2485	62	6	atoms	atom	NOUN
eurjchem-2485	62	7	do	do	AUX
eurjchem-2485	62	8	not	not	PART
eurjchem-2485	62	9	contain	contain	VERB
eurjchem-2485	62	10	substituents	substituent	NOUN
eurjchem-2485	62	11	because	because	SCONJ
eurjchem-2485	62	12	they	they	PRON
eurjchem-2485	62	13	are	be	AUX
eurjchem-2485	62	14	disordered	disorder	VERB
eurjchem-2485	62	15	cf3	cf3	NOUN
eurjchem-2485	62	16	fragments	fragment	NOUN
eurjchem-2485	62	17	.	.	PUNCT
eurjchem-2485	63	1	despite	despite	SCONJ
eurjchem-2485	63	2	the	the	DET
eurjchem-2485	63	3	disorder	disorder	NOUN
eurjchem-2485	63	4	,	,	PUNCT
eurjchem-2485	63	5	it	it	PRON
eurjchem-2485	63	6	is	be	AUX
eurjchem-2485	63	7	an	an	DET
eurjchem-2485	63	8	excellent	excellent	ADJ
eurjchem-2485	63	9	model	model	NOUN
eurjchem-2485	63	10	for	for	ADP
eurjchem-2485	63	11	what	what	PRON
eurjchem-2485	63	12	we	we	PRON
eurjchem-2485	63	13	envision	envision	VERB
eurjchem-2485	63	14	as	as	SCONJ
eurjchem-2485	63	15	the	the	DET
eurjchem-2485	63	16	process	process	NOUN
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eurjchem-2485	64	4	/	/	SYM
eurjchem-2485	64	5	european	european	PROPN
eurjchem-2485	64	6	journal	journal	PROPN
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eurjchem-2485	64	10	(	(	PUNCT
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eurjchem-2485	64	13	(	(	PUNCT
eurjchem-2485	64	14	2023	2023	NUM
eurjchem-2485	64	15	)	)	PUNCT
eurjchem-2485	64	16	494	494	NUM
eurjchem-2485	64	17	-	-	SYM
eurjchem-2485	64	18	498	498	NUM
eurjchem-2485	64	19	497	497	NUM
eurjchem-2485	64	20	2023	2023	NUM
eurjchem-2485	64	21	–	–	PUNCT
eurjchem-2485	64	22	european	european	ADJ
eurjchem-2485	64	23	journal	journal	NOUN
eurjchem-2485	64	24	of	of	ADP
eurjchem-2485	64	25	chemistry	chemistry	NOUN
eurjchem-2485	64	26	–	–	PUNCT
eurjchem-2485	64	27	cc	cc	NOUN
eurjchem-2485	64	28	by	by	ADP
eurjchem-2485	64	29	nc	nc	PROPN
eurjchem-2485	64	30	–	–	PUNCT
eurjchem-2485	64	31	doi	doi	NOUN
eurjchem-2485	64	32	:	:	PUNCT
eurjchem-2485	64	33	10.5155	10.5155	NUM
eurjchem-2485	64	34	/	/	SYM
eurjchem-2485	64	35	eurjchem.14.4.494	eurjchem.14.4.494	NUM
eurjchem-2485	64	36	-	-	SYM
eurjchem-2485	64	37	498.2485	498.2485	NUM
eurjchem-2485	64	38	complex	complex	NOUN
eurjchem-2485	64	39	(	(	PUNCT
eurjchem-2485	64	40	i	i	NOUN
eurjchem-2485	64	41	)	)	PUNCT
eurjchem-2485	64	42	may	may	AUX
eurjchem-2485	64	43	have	have	AUX
eurjchem-2485	64	44	been	be	AUX
eurjchem-2485	64	45	obtained	obtain	VERB
eurjchem-2485	64	46	as	as	SCONJ
eurjchem-2485	64	47	follows	follow	VERB
eurjchem-2485	64	48	:	:	PUNCT
eurjchem-2485	64	49	1,3	1,3	NUM
eurjchem-2485	64	50	-	-	PUNCT
eurjchem-2485	64	51	diazine	diazine	NOUN
eurjchem-2485	64	52	attaches	attach	VERB
eurjchem-2485	64	53	itself	itself	PRON
eurjchem-2485	64	54	to	to	ADP
eurjchem-2485	64	55	the	the	DET
eurjchem-2485	64	56	axial	axial	ADJ
eurjchem-2485	64	57	position	position	NOUN
eurjchem-2485	64	58	of	of	ADP
eurjchem-2485	64	59	each	each	PRON
eurjchem-2485	64	60	of	of	ADP
eurjchem-2485	64	61	the	the	DET
eurjchem-2485	64	62	two	two	NUM
eurjchem-2485	64	63	[	[	X
eurjchem-2485	64	64	(	(	PUNCT
eurjchem-2485	64	65	acac)2v	acac)2v	NOUN
eurjchem-2485	64	66	=	=	NOUN
eurjchem-2485	64	67	o	o	NOUN
eurjchem-2485	64	68	]	]	X
eurjchem-2485	64	69	molecules	molecule	NOUN
eurjchem-2485	64	70	(	(	PUNCT
eurjchem-2485	64	71	such	such	ADJ
eurjchem-2485	64	72	attachments	attachment	NOUN
eurjchem-2485	64	73	are	be	AUX
eurjchem-2485	64	74	illustrated	illustrate	VERB
eurjchem-2485	64	75	elsewhere	elsewhere	ADV
eurjchem-2485	64	76	[	[	X
eurjchem-2485	64	77	1,3,15	1,3,15	NUM
eurjchem-2485	64	78	]	]	NUM
eurjchem-2485	64	79	)	)	PUNCT
eurjchem-2485	64	80	,	,	PUNCT
eurjchem-2485	64	81	thereby	thereby	ADV
eurjchem-2485	64	82	forming	form	VERB
eurjchem-2485	64	83	a	a	DET
eurjchem-2485	64	84	dimer	dimer	NOUN
eurjchem-2485	64	85	in	in	ADP
eurjchem-2485	64	86	which	which	PRON
eurjchem-2485	64	87	the	the	DET
eurjchem-2485	64	88	μ2	μ2	NOUN
eurjchem-2485	64	89	bridge	bridge	NOUN
eurjchem-2485	64	90	is	be	AUX
eurjchem-2485	64	91	the	the	DET
eurjchem-2485	64	92	1,3	1,3	NUM
eurjchem-2485	64	93	-	-	PUNCT
eurjchem-2485	64	94	diazine	diazine	NOUN
eurjchem-2485	64	95	,	,	PUNCT
eurjchem-2485	64	96	a	a	DET
eurjchem-2485	64	97	particularly	particularly	ADV
eurjchem-2485	64	98	effective	effective	ADJ
eurjchem-2485	64	99	model	model	NOUN
eurjchem-2485	64	100	being	be	AUX
eurjchem-2485	64	101	that	that	PRON
eurjchem-2485	64	102	of	of	ADP
eurjchem-2485	64	103	adahui	adahui	NOUN
eurjchem-2485	65	1	[	[	X
eurjchem-2485	65	2	15	15	NUM
eurjchem-2485	65	3	]	]	X
eurjchem-2485	65	4	,	,	PUNCT
eurjchem-2485	66	1	which	which	PRON
eurjchem-2485	66	2	,	,	PUNCT
eurjchem-2485	66	3	for	for	ADP
eurjchem-2485	66	4	the	the	DET
eurjchem-2485	66	5	convenience	convenience	NOUN
eurjchem-2485	66	6	of	of	ADP
eurjchem-2485	66	7	the	the	DET
eurjchem-2485	66	8	readers	reader	NOUN
eurjchem-2485	66	9	,	,	PUNCT
eurjchem-2485	66	10	we	we	PRON
eurjchem-2485	66	11	have	have	AUX
eurjchem-2485	66	12	redrawn	redrawn	NOUN
eurjchem-2485	66	13	as	as	ADP
eurjchem-2485	66	14	figure	figure	NOUN
eurjchem-2485	66	15	3	3	NUM
eurjchem-2485	66	16	,	,	PUNCT
eurjchem-2485	66	17	below	below	ADV
eurjchem-2485	66	18	;	;	PUNCT
eurjchem-2485	66	19	(	(	PUNCT
eurjchem-2485	66	20	b	b	X
eurjchem-2485	66	21	)	)	PUNCT
eurjchem-2485	66	22	as	as	ADP
eurjchem-2485	66	23	for	for	ADP
eurjchem-2485	66	24	the	the	DET
eurjchem-2485	66	25	bridging	bridge	VERB
eurjchem-2485	66	26	hydroxide	hydroxide	NOUN
eurjchem-2485	66	27	,	,	PUNCT
eurjchem-2485	66	28	these	these	PRON
eurjchem-2485	66	29	are	be	AUX
eurjchem-2485	66	30	ubiquitous	ubiquitous	ADJ
eurjchem-2485	66	31	in	in	ADP
eurjchem-2485	66	32	ccdc	ccdc	PROPN
eurjchem-2485	66	33	[	[	X
eurjchem-2485	66	34	16	16	NUM
eurjchem-2485	66	35	-	-	SYM
eurjchem-2485	66	36	18	18	NUM
eurjchem-2485	66	37	]	]	PUNCT
eurjchem-2485	66	38	,	,	PUNCT
eurjchem-2485	66	39	as	as	ADP
eurjchem-2485	66	40	examples	example	NOUN
eurjchem-2485	66	41	.	.	PUNCT
eurjchem-2485	67	1	4	4	X
eurjchem-2485	67	2	.	.	X
eurjchem-2485	67	3	conclusions	conclusion	NOUN
eurjchem-2485	67	4	the	the	DET
eurjchem-2485	67	5	process	process	NOUN
eurjchem-2485	67	6	by	by	ADP
eurjchem-2485	67	7	which	which	PRON
eurjchem-2485	67	8	(	(	PUNCT
eurjchem-2485	67	9	i	i	NOUN
eurjchem-2485	67	10	)	)	PUNCT
eurjchem-2485	67	11	is	be	AUX
eurjchem-2485	67	12	formed	form	VERB
eurjchem-2485	67	13	is	be	AUX
eurjchem-2485	67	14	obviously	obviously	ADV
eurjchem-2485	67	15	very	very	ADV
eurjchem-2485	67	16	complex	complex	ADJ
eurjchem-2485	67	17	,	,	PUNCT
eurjchem-2485	67	18	involving	involve	VERB
eurjchem-2485	67	19	several	several	ADJ
eurjchem-2485	67	20	displacement	displacement	NOUN
eurjchem-2485	67	21	and	and	CCONJ
eurjchem-2485	67	22	formation	formation	NOUN
eurjchem-2485	67	23	steps	step	NOUN
eurjchem-2485	67	24	;	;	PUNCT
eurjchem-2485	67	25	our	our	PRON
eurjchem-2485	67	26	above	above	ADJ
eurjchem-2485	67	27	suggestion	suggestion	NOUN
eurjchem-2485	67	28	is	be	AUX
eurjchem-2485	67	29	likely	likely	ADJ
eurjchem-2485	67	30	to	to	PART
eurjchem-2485	67	31	be	be	AUX
eurjchem-2485	67	32	simplistic	simplistic	ADJ
eurjchem-2485	67	33	,	,	PUNCT
eurjchem-2485	67	34	but	but	CCONJ
eurjchem-2485	67	35	it	it	PRON
eurjchem-2485	67	36	is	be	AUX
eurjchem-2485	67	37	a	a	DET
eurjchem-2485	67	38	reasonable	reasonable	ADJ
eurjchem-2485	67	39	description	description	NOUN
eurjchem-2485	67	40	of	of	ADP
eurjchem-2485	67	41	the	the	DET
eurjchem-2485	67	42	process	process	NOUN
eurjchem-2485	67	43	of	of	ADP
eurjchem-2485	67	44	its	its	PRON
eurjchem-2485	67	45	formation	formation	NOUN
eurjchem-2485	67	46	based	base	VERB
eurjchem-2485	67	47	on	on	ADP
eurjchem-2485	67	48	known	know	VERB
eurjchem-2485	67	49	synthetic	synthetic	ADJ
eurjchem-2485	67	50	and	and	CCONJ
eurjchem-2485	67	51	structural	structural	ADJ
eurjchem-2485	67	52	studies	study	NOUN
eurjchem-2485	67	53	of	of	ADP
eurjchem-2485	67	54	vanadyl	vanadyl	NOUN
eurjchem-2485	67	55	(	(	PUNCT
eurjchem-2485	67	56	see	see	VERB
eurjchem-2485	67	57	refs	ref	NOUN
eurjchem-2485	67	58	.	.	PUNCT
eurjchem-2485	68	1	[	[	X
eurjchem-2485	68	2	1	1	X
eurjchem-2485	68	3	]	]	PUNCT
eurjchem-2485	68	4	and	and	CCONJ
eurjchem-2485	68	5	[	[	X
eurjchem-2485	68	6	3	3	NUM
eurjchem-2485	68	7	]	]	PUNCT
eurjchem-2485	68	8	,	,	PUNCT
eurjchem-2485	68	9	and	and	CCONJ
eurjchem-2485	68	10	references	reference	NOUN
eurjchem-2485	68	11	therein	therein	ADV
eurjchem-2485	68	12	)	)	PUNCT
eurjchem-2485	68	13	.	.	PUNCT
eurjchem-2485	69	1	meanwhile	meanwhile	ADV
eurjchem-2485	69	2	,	,	PUNCT
eurjchem-2485	69	3	we	we	PRON
eurjchem-2485	69	4	are	be	AUX
eurjchem-2485	69	5	attempting	attempt	VERB
eurjchem-2485	69	6	to	to	PART
eurjchem-2485	69	7	trap	trap	VERB
eurjchem-2485	69	8	intermediates	intermediate	NOUN
eurjchem-2485	69	9	,	,	PUNCT
eurjchem-2485	69	10	such	such	ADJ
eurjchem-2485	69	11	as	as	ADP
eurjchem-2485	69	12	those	those	PRON
eurjchem-2485	69	13	suggested	suggest	VERB
eurjchem-2485	69	14	above	above	ADV
eurjchem-2485	69	15	,	,	PUNCT
eurjchem-2485	69	16	in	in	ADP
eurjchem-2485	69	17	an	an	DET
eurjchem-2485	69	18	effort	effort	NOUN
eurjchem-2485	69	19	to	to	PART
eurjchem-2485	69	20	unravel	unravel	VERB
eurjchem-2485	69	21	the	the	DET
eurjchem-2485	69	22	process	process	NOUN
eurjchem-2485	69	23	of	of	ADP
eurjchem-2485	69	24	formation	formation	NOUN
eurjchem-2485	69	25	of	of	ADP
eurjchem-2485	69	26	this	this	DET
eurjchem-2485	69	27	unique	unique	ADJ
eurjchem-2485	69	28	species	specie	NOUN
eurjchem-2485	69	29	.	.	PUNCT
eurjchem-2485	70	1	currently	currently	ADV
eurjchem-2485	70	2	we	we	PRON
eurjchem-2485	70	3	are	be	AUX
eurjchem-2485	70	4	hindered	hinder	VERB
eurjchem-2485	70	5	in	in	ADP
eurjchem-2485	70	6	making	make	VERB
eurjchem-2485	70	7	magnetic	magnetic	ADJ
eurjchem-2485	70	8	or	or	CCONJ
eurjchem-2485	70	9	any	any	DET
eurjchem-2485	70	10	other	other	ADJ
eurjchem-2485	70	11	measurements	measurement	NOUN
eurjchem-2485	70	12	by	by	ADP
eurjchem-2485	70	13	the	the	DET
eurjchem-2485	70	14	lack	lack	NOUN
eurjchem-2485	70	15	of	of	ADP
eurjchem-2485	70	16	enough	enough	ADJ
eurjchem-2485	70	17	material	material	NOUN
eurjchem-2485	70	18	,	,	PUNCT
eurjchem-2485	70	19	which	which	PRON
eurjchem-2485	70	20	,	,	PUNCT
eurjchem-2485	70	21	as	as	SCONJ
eurjchem-2485	70	22	mentioned	mention	VERB
eurjchem-2485	70	23	above	above	ADV
eurjchem-2485	70	24	,	,	PUNCT
eurjchem-2485	70	25	consisted	consist	VERB
eurjchem-2485	70	26	of	of	ADP
eurjchem-2485	70	27	only	only	ADV
eurjchem-2485	70	28	a	a	DET
eurjchem-2485	70	29	few	few	ADJ
eurjchem-2485	70	30	,	,	PUNCT
eurjchem-2485	70	31	very	very	ADV
eurjchem-2485	70	32	obviously	obviously	ADV
eurjchem-2485	70	33	(	(	PUNCT
eurjchem-2485	70	34	black	black	ADJ
eurjchem-2485	70	35	)	)	PUNCT
eurjchem-2485	70	36	different	different	ADJ
eurjchem-2485	70	37	,	,	PUNCT
eurjchem-2485	70	38	well	well	ADV
eurjchem-2485	70	39	-	-	PUNCT
eurjchem-2485	70	40	defined	define	VERB
eurjchem-2485	70	41	crystals	crystal	NOUN
eurjchem-2485	70	42	.	.	PUNCT
eurjchem-2485	71	1	recently	recently	ADV
eurjchem-2485	71	2	,	,	PUNCT
eurjchem-2485	71	3	it	it	PRON
eurjchem-2485	71	4	has	have	AUX
eurjchem-2485	71	5	been	be	AUX
eurjchem-2485	71	6	pointed	point	VERB
eurjchem-2485	71	7	out	out	ADP
eurjchem-2485	71	8	[	[	X
eurjchem-2485	71	9	19	19	NUM
eurjchem-2485	71	10	]	]	PUNCT
eurjchem-2485	71	11	,	,	PUNCT
eurjchem-2485	71	12	and	and	CCONJ
eurjchem-2485	71	13	references	reference	NOUN
eurjchem-2485	71	14	therein	therein	ADV
eurjchem-2485	71	15	]	]	PUNCT
eurjchem-2485	71	16	,	,	PUNCT
eurjchem-2485	71	17	that	that	SCONJ
eurjchem-2485	71	18	there	there	PRON
eurjchem-2485	71	19	are	be	VERB
eurjchem-2485	71	20	cases	case	NOUN
eurjchem-2485	71	21	in	in	ADP
eurjchem-2485	71	22	which	which	PRON
eurjchem-2485	71	23	the	the	DET
eurjchem-2485	71	24	selection	selection	NOUN
eurjchem-2485	71	25	of	of	ADP
eurjchem-2485	71	26	the	the	DET
eurjchem-2485	71	27	space	space	NOUN
eurjchem-2485	71	28	group	group	NOUN
eurjchem-2485	71	29	is	be	AUX
eurjchem-2485	71	30	not	not	PART
eurjchem-2485	71	31	straightforward	straightforward	ADJ
eurjchem-2485	71	32	because	because	SCONJ
eurjchem-2485	71	33	molecules	molecule	NOUN
eurjchem-2485	71	34	containing	contain	VERB
eurjchem-2485	71	35	flexible	flexible	ADJ
eurjchem-2485	71	36	fragments	fragment	NOUN
eurjchem-2485	71	37	pack	pack	VERB
eurjchem-2485	71	38	better	well	ADV
eurjchem-2485	71	39	if	if	SCONJ
eurjchem-2485	71	40	they	they	PRON
eurjchem-2485	71	41	undergo	undergo	VERB
eurjchem-2485	71	42	relatively	relatively	ADV
eurjchem-2485	71	43	small	small	ADJ
eurjchem-2485	71	44	torsional	torsional	ADJ
eurjchem-2485	71	45	motions	motion	NOUN
eurjchem-2485	71	46	that	that	PRON
eurjchem-2485	71	47	lead	lead	VERB
eurjchem-2485	71	48	to	to	ADP
eurjchem-2485	71	49	conformational	conformational	ADJ
eurjchem-2485	71	50	disorder	disorder	NOUN
eurjchem-2485	71	51	,	,	PUNCT
eurjchem-2485	71	52	for	for	ADP
eurjchem-2485	71	53	example	example	NOUN
eurjchem-2485	71	54	,	,	PUNCT
eurjchem-2485	71	55	in	in	ADP
eurjchem-2485	71	56	[	[	PUNCT
eurjchem-2485	71	57	co(en)3]i3·h2o	co(en)3]i3·h2o	NOUN
eurjchem-2485	71	58	[	[	X
eurjchem-2485	71	59	19	19	NUM
eurjchem-2485	71	60	]	]	PUNCT
eurjchem-2485	71	61	,	,	PUNCT
eurjchem-2485	71	62	which	which	PRON
eurjchem-2485	71	63	had	have	VERB
eurjchem-2485	71	64	previously	previously	ADV
eurjchem-2485	71	65	[	[	AUX
eurjchem-2485	71	66	21	21	NUM
eurjchem-2485	71	67	]	]	PUNCT
eurjchem-2485	71	68	been	be	AUX
eurjchem-2485	71	69	assigned	assign	VERB
eurjchem-2485	71	70	the	the	DET
eurjchem-2485	71	71	space	space	NOUN
eurjchem-2485	71	72	group	group	NOUN
eurjchem-2485	71	73	pbca	pbca	PROPN
eurjchem-2485	71	74	,	,	PUNCT
eurjchem-2485	71	75	and	and	CCONJ
eurjchem-2485	71	76	most	most	ADV
eurjchem-2485	71	77	recently	recently	ADV
eurjchem-2485	71	78	proven	prove	VERB
eurjchem-2485	71	79	to	to	PART
eurjchem-2485	71	80	be	be	AUX
eurjchem-2485	71	81	a	a	DET
eurjchem-2485	71	82	case	case	NOUN
eurjchem-2485	71	83	of	of	ADP
eurjchem-2485	71	84	kryptoracemic	kryptoracemic	ADJ
eurjchem-2485	71	85	crystallization	crystallization	NOUN
eurjchem-2485	71	86	in	in	ADP
eurjchem-2485	71	87	which	which	PRON
eurjchem-2485	71	88	the	the	DET
eurjchem-2485	71	89	en	en	PROPN
eurjchem-2485	71	90	ligands	ligand	NOUN
eurjchem-2485	71	91	’	'	PUNCT
eurjchem-2485	71	92	torsional	torsional	ADJ
eurjchem-2485	71	93	angles	angle	NOUN
eurjchem-2485	71	94	required	require	VERB
eurjchem-2485	71	95	to	to	PART
eurjchem-2485	71	96	be	be	AUX
eurjchem-2485	71	97	enantiomorphic	enantiomorphic	ADJ
eurjchem-2485	71	98	pairs	pair	NOUN
eurjchem-2485	71	99	fail	fail	VERB
eurjchem-2485	71	100	to	to	PART
eurjchem-2485	71	101	do	do	VERB
eurjchem-2485	71	102	so	so	ADV
eurjchem-2485	71	103	.	.	PUNCT
eurjchem-2485	72	1	a	a	DET
eurjchem-2485	72	2	detailed	detailed	ADJ
eurjchem-2485	72	3	analysis	analysis	NOUN
eurjchem-2485	72	4	of	of	ADP
eurjchem-2485	72	5	this	this	DET
eurjchem-2485	72	6	problem	problem	NOUN
eurjchem-2485	72	7	is	be	AUX
eurjchem-2485	72	8	given	give	VERB
eurjchem-2485	72	9	in	in	ADP
eurjchem-2485	72	10	[	[	X
eurjchem-2485	72	11	20	20	NUM
eurjchem-2485	72	12	]	]	PUNCT
eurjchem-2485	72	13	,	,	PUNCT
eurjchem-2485	72	14	where	where	SCONJ
eurjchem-2485	72	15	it	it	PRON
eurjchem-2485	72	16	was	be	AUX
eurjchem-2485	72	17	shown	show	VERB
eurjchem-2485	72	18	that	that	SCONJ
eurjchem-2485	72	19	lowering	lower	VERB
eurjchem-2485	72	20	the	the	DET
eurjchem-2485	72	21	space	space	NOUN
eurjchem-2485	72	22	group	group	NOUN
eurjchem-2485	72	23	from	from	ADP
eurjchem-2485	72	24	pbca	pbca	PROPN
eurjchem-2485	72	25	to	to	ADP
eurjchem-2485	72	26	one	one	NUM
eurjchem-2485	72	27	of	of	ADP
eurjchem-2485	72	28	its	its	PRON
eurjchem-2485	72	29	subgroups	subgroup	NOUN
eurjchem-2485	72	30	,	,	PUNCT
eurjchem-2485	72	31	pca21	pca21	PROPN
eurjchem-2485	72	32	,	,	PUNCT
eurjchem-2485	72	33	still	still	ADV
eurjchem-2485	72	34	resulted	result	VERB
eurjchem-2485	72	35	in	in	ADP
eurjchem-2485	72	36	an	an	DET
eurjchem-2485	72	37	unacceptable	unacceptable	ADJ
eurjchem-2485	72	38	chemical	chemical	NOUN
eurjchem-2485	72	39	model	model	NOUN
eurjchem-2485	72	40	,	,	PUNCT
eurjchem-2485	72	41	while	while	SCONJ
eurjchem-2485	72	42	further	far	ADV
eurjchem-2485	72	43	lowering	lower	VERB
eurjchem-2485	72	44	the	the	DET
eurjchem-2485	72	45	symmetry	symmetry	NOUN
eurjchem-2485	72	46	to	to	ADP
eurjchem-2485	72	47	that	that	PRON
eurjchem-2485	72	48	of	of	ADP
eurjchem-2485	72	49	p212121	p212121	VERB
eurjchem-2485	72	50	completely	completely	ADV
eurjchem-2485	72	51	cleared	clear	VERB
eurjchem-2485	72	52	the	the	DET
eurjchem-2485	72	53	problems	problem	NOUN
eurjchem-2485	72	54	encountered	encounter	VERB
eurjchem-2485	72	55	previously	previously	ADV
eurjchem-2485	72	56	[	[	X
eurjchem-2485	72	57	20	20	NUM
eurjchem-2485	72	58	]	]	PUNCT
eurjchem-2485	72	59	.	.	PUNCT
eurjchem-2485	73	1	here	here	ADV
eurjchem-2485	73	2	,	,	PUNCT
eurjchem-2485	73	3	we	we	PRON
eurjchem-2485	73	4	refrain	refrain	VERB
eurjchem-2485	73	5	from	from	ADP
eurjchem-2485	73	6	describing	describe	VERB
eurjchem-2485	73	7	these	these	DET
eurjchem-2485	73	8	problems	problem	NOUN
eurjchem-2485	73	9	in	in	ADP
eurjchem-2485	73	10	more	more	ADJ
eurjchem-2485	73	11	detail	detail	NOUN
eurjchem-2485	73	12	because	because	SCONJ
eurjchem-2485	73	13	they	they	PRON
eurjchem-2485	73	14	are	be	AUX
eurjchem-2485	73	15	long	long	ADJ
eurjchem-2485	73	16	and	and	CCONJ
eurjchem-2485	73	17	complex	complex	ADJ
eurjchem-2485	73	18	and	and	CCONJ
eurjchem-2485	73	19	require	require	VERB
eurjchem-2485	73	20	additional	additional	ADJ
eurjchem-2485	73	21	illustrative	illustrative	ADJ
eurjchem-2485	73	22	figures	figure	NOUN
eurjchem-2485	73	23	already	already	ADV
eurjchem-2485	73	24	available	available	ADJ
eurjchem-2485	73	25	in	in	ADP
eurjchem-2485	73	26	[	[	X
eurjchem-2485	73	27	19	19	NUM
eurjchem-2485	73	28	]	]	PUNCT
eurjchem-2485	73	29	,	,	PUNCT
eurjchem-2485	73	30	to	to	PART
eurjchem-2485	73	31	which	which	PRON
eurjchem-2485	73	32	the	the	DET
eurjchem-2485	73	33	interested	interested	ADJ
eurjchem-2485	73	34	readers	reader	NOUN
eurjchem-2485	73	35	are	be	AUX
eurjchem-2485	73	36	directed	direct	VERB
eurjchem-2485	73	37	.	.	PUNCT
eurjchem-2485	74	1	when	when	SCONJ
eurjchem-2485	74	2	collecting	collect	VERB
eurjchem-2485	74	3	the	the	DET
eurjchem-2485	74	4	data	datum	NOUN
eurjchem-2485	74	5	set	set	VERB
eurjchem-2485	74	6	described	describe	VERB
eurjchem-2485	74	7	here	here	ADV
eurjchem-2485	74	8	,	,	PUNCT
eurjchem-2485	74	9	we	we	PRON
eurjchem-2485	74	10	solved	solve	VERB
eurjchem-2485	74	11	the	the	DET
eurjchem-2485	74	12	structure	structure	NOUN
eurjchem-2485	74	13	in	in	ADP
eurjchem-2485	74	14	the	the	DET
eurjchem-2485	74	15	p1	p1	PROPN
eurjchem-2485	74	16	space	space	NOUN
eurjchem-2485	74	17	group	group	NOUN
eurjchem-2485	74	18	and	and	CCONJ
eurjchem-2485	74	19	submitted	submit	VERB
eurjchem-2485	74	20	the	the	DET
eurjchem-2485	74	21	results	result	NOUN
eurjchem-2485	74	22	to	to	ADP
eurjchem-2485	74	23	the	the	DET
eurjchem-2485	74	24	platon	platon	PROPN
eurjchem-2485	74	25	program	program	NOUN
eurjchem-2485	75	1	[	[	X
eurjchem-2485	75	2	21	21	NUM
eurjchem-2485	75	3	]	]	PUNCT
eurjchem-2485	75	4	,	,	PUNCT
eurjchem-2485	75	5	resulting	result	VERB
eurjchem-2485	75	6	in	in	ADP
eurjchem-2485	75	7	a	a	DET
eurjchem-2485	75	8	recommendation	recommendation	NOUN
eurjchem-2485	75	9	of	of	ADP
eurjchem-2485	75	10	pbca	pbca	NOUN
eurjchem-2485	75	11	as	as	ADP
eurjchem-2485	75	12	the	the	DET
eurjchem-2485	75	13	correct	correct	ADJ
eurjchem-2485	75	14	space	space	NOUN
eurjchem-2485	75	15	group	group	NOUN
eurjchem-2485	75	16	,	,	PUNCT
eurjchem-2485	75	17	which	which	PRON
eurjchem-2485	75	18	we	we	PRON
eurjchem-2485	75	19	accepted	accept	VERB
eurjchem-2485	75	20	.	.	PUNCT
eurjchem-2485	76	1	however	however	ADV
eurjchem-2485	76	2	,	,	PUNCT
eurjchem-2485	76	3	refinement	refinement	NOUN
eurjchem-2485	76	4	in	in	ADP
eurjchem-2485	76	5	that	that	DET
eurjchem-2485	76	6	space	space	NOUN
eurjchem-2485	76	7	group	group	NOUN
eurjchem-2485	76	8	resulted	result	VERB
eurjchem-2485	76	9	in	in	ADP
eurjchem-2485	76	10	another	another	DET
eurjchem-2485	76	11	totally	totally	ADV
eurjchem-2485	76	12	unacceptable	unacceptable	ADJ
eurjchem-2485	76	13	model	model	NOUN
eurjchem-2485	76	14	;	;	PUNCT
eurjchem-2485	76	15	therefore	therefore	ADV
eurjchem-2485	76	16	,	,	PUNCT
eurjchem-2485	76	17	we	we	PRON
eurjchem-2485	76	18	resorted	resort	VERB
eurjchem-2485	76	19	to	to	ADP
eurjchem-2485	76	20	the	the	DET
eurjchem-2485	76	21	previously	previously	ADV
eurjchem-2485	76	22	successful	successful	ADJ
eurjchem-2485	76	23	procedure	procedure	NOUN
eurjchem-2485	76	24	of	of	ADP
eurjchem-2485	76	25	changing	change	VERB
eurjchem-2485	76	26	the	the	DET
eurjchem-2485	76	27	space	space	NOUN
eurjchem-2485	76	28	group	group	NOUN
eurjchem-2485	76	29	to	to	ADP
eurjchem-2485	76	30	pca21	pca21	PROPN
eurjchem-2485	76	31	,	,	PUNCT
eurjchem-2485	76	32	(	(	PUNCT
eurjchem-2485	76	33	an	an	DET
eurjchem-2485	76	34	acceptable	acceptable	ADJ
eurjchem-2485	76	35	subgroup	subgroup	NOUN
eurjchem-2485	76	36	of	of	ADP
eurjchem-2485	76	37	pbca	pbca	PROPN
eurjchem-2485	76	38	)	)	PUNCT
eurjchem-2485	76	39	,	,	PUNCT
eurjchem-2485	76	40	producing	produce	VERB
eurjchem-2485	76	41	the	the	DET
eurjchem-2485	76	42	model	model	NOUN
eurjchem-2485	76	43	described	describe	VERB
eurjchem-2485	76	44	in	in	ADP
eurjchem-2485	76	45	figure	figure	NOUN
eurjchem-2485	76	46	1	1	NUM
eurjchem-2485	76	47	.	.	PUNCT
eurjchem-2485	77	1	the	the	DET
eurjchem-2485	77	2	bottom	bottom	ADJ
eurjchem-2485	77	3	line	line	NOUN
eurjchem-2485	77	4	is	be	AUX
eurjchem-2485	77	5	that	that	SCONJ
eurjchem-2485	77	6	the	the	DET
eurjchem-2485	77	7	newly	newly	ADV
eurjchem-2485	77	8	proposed	propose	VERB
eurjchem-2485	77	9	model	model	NOUN
eurjchem-2485	77	10	must	must	AUX
eurjchem-2485	77	11	make	make	VERB
eurjchem-2485	77	12	chemical	chemical	ADJ
eurjchem-2485	77	13	sense	sense	NOUN
eurjchem-2485	77	14	and	and	CCONJ
eurjchem-2485	77	15	will	will	AUX
eurjchem-2485	77	16	do	do	VERB
eurjchem-2485	77	17	so	so	ADV
eurjchem-2485	77	18	if	if	SCONJ
eurjchem-2485	77	19	the	the	DET
eurjchem-2485	77	20	appropriate	appropriate	ADJ
eurjchem-2485	77	21	space	space	NOUN
eurjchem-2485	77	22	group	group	NOUN
eurjchem-2485	77	23	is	be	AUX
eurjchem-2485	77	24	chosen	choose	VERB
eurjchem-2485	77	25	,	,	PUNCT
eurjchem-2485	77	26	which	which	PRON
eurjchem-2485	77	27	,	,	PUNCT
eurjchem-2485	77	28	in	in	ADP
eurjchem-2485	77	29	this	this	DET
eurjchem-2485	77	30	case	case	NOUN
eurjchem-2485	77	31	,	,	PUNCT
eurjchem-2485	77	32	is	be	AUX
eurjchem-2485	77	33	pca21	pca21	ADJ
eurjchem-2485	77	34	.	.	PUNCT
eurjchem-2485	78	1	with	with	ADP
eurjchem-2485	78	2	respect	respect	NOUN
eurjchem-2485	78	3	to	to	ADP
eurjchem-2485	78	4	the	the	DET
eurjchem-2485	78	5	flack	flack	ADJ
eurjchem-2485	78	6	parameter	parameter	NOUN
eurjchem-2485	78	7	[	[	X
eurjchem-2485	78	8	0.51(2	0.51(2	NOUN
eurjchem-2485	78	9	)	)	PUNCT
eurjchem-2485	78	10	]	]	PUNCT
eurjchem-2485	78	11	,	,	PUNCT
eurjchem-2485	78	12	it	it	PRON
eurjchem-2485	78	13	is	be	AUX
eurjchem-2485	78	14	not	not	PART
eurjchem-2485	78	15	surprising	surprising	ADJ
eurjchem-2485	78	16	that	that	SCONJ
eurjchem-2485	78	17	platon	platon	PROPN
eurjchem-2485	79	1	[	[	X
eurjchem-2485	79	2	21	21	NUM
eurjchem-2485	79	3	]	]	PUNCT
eurjchem-2485	79	4	suggests	suggest	VERB
eurjchem-2485	79	5	that	that	SCONJ
eurjchem-2485	79	6	the	the	DET
eurjchem-2485	79	7	space	space	NOUN
eurjchem-2485	79	8	group	group	NOUN
eurjchem-2485	79	9	is	be	AUX
eurjchem-2485	79	10	pbca	pbca	VERB
eurjchem-2485	79	11	,	,	PUNCT
eurjchem-2485	79	12	which	which	PRON
eurjchem-2485	79	13	we	we	PRON
eurjchem-2485	79	14	have	have	AUX
eurjchem-2485	79	15	demonstrated	demonstrate	VERB
eurjchem-2485	79	16	above	above	ADV
eurjchem-2485	79	17	to	to	PART
eurjchem-2485	79	18	be	be	AUX
eurjchem-2485	79	19	incorrect	incorrect	ADJ
eurjchem-2485	79	20	.	.	PUNCT
eurjchem-2485	80	1	the	the	DET
eurjchem-2485	80	2	core	core	NOUN
eurjchem-2485	80	3	of	of	ADP
eurjchem-2485	80	4	the	the	DET
eurjchem-2485	80	5	cluster	cluster	NOUN
eurjchem-2485	80	6	in	in	ADP
eurjchem-2485	80	7	figure	figure	NOUN
eurjchem-2485	80	8	2	2	NUM
eurjchem-2485	80	9	(	(	PUNCT
eurjchem-2485	80	10	and	and	CCONJ
eurjchem-2485	80	11	the	the	DET
eurjchem-2485	80	12	graphical	graphical	ADJ
eurjchem-2485	80	13	abstract	abstract	NOUN
eurjchem-2485	80	14	)	)	PUNCT
eurjchem-2485	80	15	suggests	suggest	VERB
eurjchem-2485	80	16	that	that	SCONJ
eurjchem-2485	80	17	if	if	SCONJ
eurjchem-2485	80	18	the	the	DET
eurjchem-2485	80	19	bridge	bridge	NOUN
eurjchem-2485	80	20	were	be	AUX
eurjchem-2485	80	21	symmetrical	symmetrical	ADJ
eurjchem-2485	80	22	(	(	PUNCT
eurjchem-2485	80	23	for	for	ADP
eurjchem-2485	80	24	example	example	NOUN
eurjchem-2485	80	25	,	,	PUNCT
eurjchem-2485	80	26	two	two	NUM
eurjchem-2485	80	27	chlorides	chloride	NOUN
eurjchem-2485	80	28	or	or	CCONJ
eurjchem-2485	80	29	two	two	NUM
eurjchem-2485	80	30	hydroxides	hydroxide	NOUN
eurjchem-2485	80	31	)	)	PUNCT
eurjchem-2485	80	32	,	,	PUNCT
eurjchem-2485	80	33	the	the	DET
eurjchem-2485	80	34	resulting	result	VERB
eurjchem-2485	80	35	fragment	fragment	NOUN
eurjchem-2485	80	36	would	would	AUX
eurjchem-2485	80	37	approximately	approximately	ADV
eurjchem-2485	80	38	have	have	VERB
eurjchem-2485	80	39	an	an	DET
eurjchem-2485	80	40	inversion	inversion	NOUN
eurjchem-2485	80	41	center	center	NOUN
eurjchem-2485	80	42	.	.	PUNCT
eurjchem-2485	81	1	additionally	additionally	ADV
eurjchem-2485	81	2	,	,	PUNCT
eurjchem-2485	81	3	figure	figure	NOUN
eurjchem-2485	81	4	1	1	NUM
eurjchem-2485	81	5	,	,	PUNCT
eurjchem-2485	81	6	which	which	PRON
eurjchem-2485	81	7	shows	show	VERB
eurjchem-2485	81	8	the	the	DET
eurjchem-2485	81	9	entire	entire	ADJ
eurjchem-2485	81	10	molecule	molecule	NOUN
eurjchem-2485	81	11	,	,	PUNCT
eurjchem-2485	81	12	shares	share	VERB
eurjchem-2485	81	13	the	the	DET
eurjchem-2485	81	14	same	same	ADJ
eurjchem-2485	81	15	characteristics	characteristic	NOUN
eurjchem-2485	81	16	.	.	PUNCT
eurjchem-2485	82	1	therefore	therefore	ADV
eurjchem-2485	82	2	,	,	PUNCT
eurjchem-2485	82	3	the	the	DET
eurjchem-2485	82	4	x	x	NOUN
eurjchem-2485	82	5	-	-	NOUN
eurjchem-2485	82	6	ray	ray	NOUN
eurjchem-2485	82	7	scattering	scatter	VERB
eurjchem-2485	82	8	power	power	NOUN
eurjchem-2485	82	9	of	of	ADP
eurjchem-2485	82	10	such	such	DET
eurjchem-2485	82	11	an	an	DET
eurjchem-2485	82	12	“	"	PUNCT
eurjchem-2485	82	13	asymmetric	asymmetric	ADJ
eurjchem-2485	82	14	”	"	PUNCT
eurjchem-2485	82	15	unit	unit	NOUN
eurjchem-2485	82	16	would	would	AUX
eurjchem-2485	82	17	skew	skew	VERB
eurjchem-2485	82	18	the	the	DET
eurjchem-2485	82	19	statistical	statistical	ADJ
eurjchem-2485	82	20	distribution	distribution	NOUN
eurjchem-2485	82	21	of	of	ADP
eurjchem-2485	82	22	xrays	xray	NOUN
eurjchem-2485	82	23	such	such	ADJ
eurjchem-2485	82	24	that	that	SCONJ
eurjchem-2485	82	25	the	the	DET
eurjchem-2485	82	26	overall	overall	ADJ
eurjchem-2485	82	27	lattice	lattice	NOUN
eurjchem-2485	82	28	would	would	AUX
eurjchem-2485	82	29	resemble	resemble	VERB
eurjchem-2485	82	30	that	that	PRON
eurjchem-2485	82	31	of	of	ADP
eurjchem-2485	82	32	a	a	DET
eurjchem-2485	82	33	higher	high	ADJ
eurjchem-2485	82	34	symmetry	symmetry	NOUN
eurjchem-2485	82	35	space	space	NOUN
eurjchem-2485	82	36	group	group	NOUN
eurjchem-2485	82	37	,	,	PUNCT
eurjchem-2485	82	38	such	such	ADJ
eurjchem-2485	82	39	as	as	SCONJ
eurjchem-2485	82	40	suggested	suggest	VERB
eurjchem-2485	82	41	by	by	ADP
eurjchem-2485	82	42	platon	platon	PROPN
eurjchem-2485	82	43	,	,	PUNCT
eurjchem-2485	82	44	which	which	PRON
eurjchem-2485	82	45	recommended	recommend	VERB
eurjchem-2485	82	46	the	the	DET
eurjchem-2485	82	47	use	use	NOUN
eurjchem-2485	82	48	of	of	ADP
eurjchem-2485	82	49	pbca	pbca	NOUN
eurjchem-2485	82	50	.	.	PUNCT
eurjchem-2485	83	1	we	we	PRON
eurjchem-2485	83	2	have	have	AUX
eurjchem-2485	83	3	observed	observe	VERB
eurjchem-2485	83	4	this	this	DET
eurjchem-2485	83	5	situation	situation	NOUN
eurjchem-2485	83	6	on	on	ADP
eurjchem-2485	83	7	two	two	NUM
eurjchem-2485	83	8	different	different	ADJ
eurjchem-2485	83	9	occasions	occasion	NOUN
eurjchem-2485	83	10	in	in	ADP
eurjchem-2485	83	11	our	our	PRON
eurjchem-2485	83	12	own	own	ADJ
eurjchem-2485	83	13	work	work	NOUN
eurjchem-2485	83	14	:	:	PUNCT
eurjchem-2485	83	15	the	the	DET
eurjchem-2485	83	16	abovementioned	abovementione	VERB
eurjchem-2485	83	17	[	[	X
eurjchem-2485	83	18	co(en)3]i3·h2o	co(en)3]i3·h2o	NOUN
eurjchem-2485	83	19	[	[	X
eurjchem-2485	83	20	19	19	NUM
eurjchem-2485	83	21	]	]	PUNCT
eurjchem-2485	83	22	,	,	PUNCT
eurjchem-2485	83	23	and	and	CCONJ
eurjchem-2485	83	24	in	in	ADP
eurjchem-2485	83	25	our	our	PRON
eurjchem-2485	83	26	article	article	NOUN
eurjchem-2485	83	27	describing	describe	VERB
eurjchem-2485	83	28	previous	previous	ADJ
eurjchem-2485	83	29	work	work	NOUN
eurjchem-2485	83	30	with	with	ADP
eurjchem-2485	83	31	a	a	DET
eurjchem-2485	83	32	co(iii	co(iii	NOUN
eurjchem-2485	83	33	)	)	PUNCT
eurjchem-2485	83	34	complex	complex	NOUN
eurjchem-2485	83	35	with	with	ADP
eurjchem-2485	83	36	l	l	NOUN
eurjchem-2485	83	37	and	and	CCONJ
eurjchem-2485	83	38	d	d	ADP
eurjchem-2485	83	39	leucinato	leucinato	NOUN
eurjchem-2485	83	40	as	as	ADP
eurjchem-2485	83	41	ligands	ligand	NOUN
eurjchem-2485	83	42	where	where	SCONJ
eurjchem-2485	83	43	the	the	DET
eurjchem-2485	83	44	(	(	PUNCT
eurjchem-2485	83	45	l	l	NOUN
eurjchem-2485	83	46	:	:	PUNCT
eurjchem-2485	83	47	d	d	ADJ
eurjchem-2485	83	48	)	)	PUNCT
eurjchem-2485	83	49	ratios	ratio	NOUN
eurjchem-2485	83	50	of	of	ADP
eurjchem-2485	83	51	the	the	DET
eurjchem-2485	83	52	ligands	ligand	NOUN
eurjchem-2485	83	53	were	be	AUX
eurjchem-2485	83	54	not	not	PART
eurjchem-2485	83	55	(	(	PUNCT
eurjchem-2485	83	56	1:1	1:1	NUM
eurjchem-2485	83	57	)	)	PUNCT
eurjchem-2485	84	1	[	[	X
eurjchem-2485	84	2	22	22	NUM
eurjchem-2485	84	3	]	]	PUNCT
eurjchem-2485	84	4	.	.	PUNCT
eurjchem-2485	85	1	acknowledgements	acknowledgement	VERB
eurjchem-2485	85	2	the	the	DET
eurjchem-2485	85	3	authors	author	NOUN
eurjchem-2485	85	4	acknowledge	acknowledge	VERB
eurjchem-2485	85	5	support	support	NOUN
eurjchem-2485	85	6	by	by	ADP
eurjchem-2485	85	7	nsf	nsf	PROPN
eurjchem-2485	85	8	-	-	PUNCT
eurjchem-2485	85	9	crif	crif	PROPN
eurjchem-2485	85	10	grant	grant	NOUN
eurjchem-2485	85	11	no	no	NOUN
eurjchem-2485	85	12	.	.	NOUN
eurjchem-2485	85	13	0443538	0443538	NUM
eurjchem-2485	86	1	for	for	ADP
eurjchem-2485	86	2	part	part	NOUN
eurjchem-2485	86	3	of	of	ADP
eurjchem-2485	86	4	the	the	DET
eurjchem-2485	86	5	purchase	purchase	NOUN
eurjchem-2485	86	6	of	of	ADP
eurjchem-2485	86	7	the	the	DET
eurjchem-2485	86	8	x	x	NOUN
eurjchem-2485	86	9	-	-	NOUN
eurjchem-2485	86	10	ray	ray	NOUN
eurjchem-2485	86	11	diffractometer	diffractometer	NOUN
eurjchem-2485	86	12	.	.	PUNCT
eurjchem-2485	87	1	we	we	PRON
eurjchem-2485	87	2	thank	thank	VERB
eurjchem-2485	87	3	dr	dr	PROPN
eurjchem-2485	87	4	.	.	PROPN
eurjchem-2485	87	5	evrim	evrim	PROPN
eurjchem-2485	87	6	arslan	arslan	PROPN
eurjchem-2485	87	7	for	for	ADP
eurjchem-2485	87	8	helping	help	VERB
eurjchem-2485	87	9	to	to	PART
eurjchem-2485	87	10	prepare	prepare	VERB
eurjchem-2485	87	11	the	the	DET
eurjchem-2485	87	12	complex	complex	NOUN
eurjchem-2485	87	13	.	.	PUNCT
eurjchem-2485	88	1	supporting	support	VERB
eurjchem-2485	88	2	information	information	NOUN
eurjchem-2485	88	3	ccdc-2201346	ccdc-2201346	NOUN
eurjchem-2485	88	4	contains	contain	VERB
eurjchem-2485	88	5	the	the	DET
eurjchem-2485	88	6	supplementary	supplementary	ADJ
eurjchem-2485	88	7	crystallographic	crystallographic	ADJ
eurjchem-2485	88	8	data	datum	NOUN
eurjchem-2485	88	9	for	for	ADP
eurjchem-2485	88	10	this	this	DET
eurjchem-2485	88	11	paper	paper	NOUN
eurjchem-2485	88	12	.	.	PUNCT
eurjchem-2485	89	1	these	these	DET
eurjchem-2485	89	2	data	datum	NOUN
eurjchem-2485	89	3	can	can	AUX
eurjchem-2485	89	4	be	be	AUX
eurjchem-2485	89	5	obtained	obtain	VERB
eurjchem-2485	89	6	free	free	ADJ
eurjchem-2485	89	7	of	of	ADP
eurjchem-2485	89	8	charge	charge	NOUN
eurjchem-2485	89	9	via	via	ADP
eurjchem-2485	89	10	www.ccdc.cam.ac.uk/	www.ccdc.cam.ac.uk/	ADP
eurjchem-2485	89	11	data_request	data_request	PROPN
eurjchem-2485	89	12	/	/	SYM
eurjchem-2485	89	13	cif	cif	PROPN
eurjchem-2485	89	14	,	,	PUNCT
eurjchem-2485	89	15	or	or	CCONJ
eurjchem-2485	89	16	by	by	ADP
eurjchem-2485	89	17	e	e	NOUN
eurjchem-2485	89	18	-	-	ADJ
eurjchem-2485	89	19	mailing	mailing	ADJ
eurjchem-2485	89	20	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-2485	89	21	,	,	PUNCT
eurjchem-2485	89	22	or	or	CCONJ
eurjchem-2485	89	23	by	by	ADP
eurjchem-2485	89	24	contacting	contact	VERB
eurjchem-2485	89	25	the	the	DET
eurjchem-2485	89	26	cambridge	cambridge	PROPN
eurjchem-2485	89	27	crystallographic	crystallographic	PROPN
eurjchem-2485	89	28	data	data	PROPN
eurjchem-2485	89	29	centre	centre	NOUN
eurjchem-2485	89	30	,	,	PUNCT
eurjchem-2485	89	31	12	12	NUM
eurjchem-2485	89	32	union	union	NOUN
eurjchem-2485	89	33	road	road	NOUN
eurjchem-2485	89	34	,	,	PUNCT
eurjchem-2485	89	35	cambridge	cambridge	PROPN
eurjchem-2485	89	36	cb2	cb2	PROPN
eurjchem-2485	89	37	1ez	1ez	PROPN
eurjchem-2485	89	38	,	,	PUNCT
eurjchem-2485	89	39	uk	uk	PROPN
eurjchem-2485	89	40	;	;	PUNCT
eurjchem-2485	89	41	fax	fax	NOUN
eurjchem-2485	89	42	:	:	PUNCT
eurjchem-2485	89	43	+44(0)1223	+44(0)1223	PROPN
eurjchem-2485	89	44	-	-	PUNCT
eurjchem-2485	89	45	336033	336033	NUM
eurjchem-2485	89	46	.	.	PUNCT
eurjchem-2485	90	1	ccdc	ccdc	PROPN
eurjchem-2485	90	2	compound	compound	NOUN
eurjchem-2485	90	3	codes	code	NOUN
eurjchem-2485	90	4	:	:	PUNCT
eurjchem-2485	91	1	aqapep	aqapep	INTJ
eurjchem-2485	92	1	[	[	X
eurjchem-2485	92	2	13	13	NUM
eurjchem-2485	92	3	]	]	PUNCT
eurjchem-2485	92	4	;	;	PUNCT
eurjchem-2485	92	5	decyeq	decyeq	NOUN
eurjchem-2485	92	6	[	[	X
eurjchem-2485	92	7	14	14	NUM
eurjchem-2485	92	8	]	]	X
eurjchem-2485	92	9	;	;	PUNCT
eurjchem-2485	92	10	adahui	adahui	PROPN
eurjchem-2485	93	1	[	[	X
eurjchem-2485	93	2	15	15	NUM
eurjchem-2485	93	3	]	]	X
eurjchem-2485	93	4	;	;	PUNCT
eurjchem-2485	93	5	ezepaa	ezepaa	NOUN
eurjchem-2485	93	6	[	[	X
eurjchem-2485	93	7	16	16	NUM
eurjchem-2485	93	8	]	]	PUNCT
eurjchem-2485	93	9	;	;	PUNCT
eurjchem-2485	93	10	hofyae	hofyae	NOUN
eurjchem-2485	93	11	[	[	X
eurjchem-2485	93	12	17	17	NUM
eurjchem-2485	93	13	]	]	PUNCT
eurjchem-2485	93	14	;	;	PUNCT
eurjchem-2485	93	15	pasfiy	pasfiy	NOUN
eurjchem-2485	93	16	[	[	X
eurjchem-2485	93	17	18	18	NUM
eurjchem-2485	93	18	]	]	X
eurjchem-2485	93	19	;	;	PUNCT
eurjchem-2485	93	20	encoih	encoih	X
eurjchem-2485	93	21	[	[	X
eurjchem-2485	93	22	20	20	NUM
eurjchem-2485	93	23	]	]	PUNCT
eurjchem-2485	93	24	.	.	PUNCT
eurjchem-2485	94	1	disclosure	disclosure	NOUN
eurjchem-2485	94	2	statement	statement	NOUN
eurjchem-2485	94	3	conflict	conflict	NOUN
eurjchem-2485	94	4	of	of	ADP
eurjchem-2485	94	5	interest	interest	NOUN
eurjchem-2485	94	6	:	:	PUNCT
eurjchem-2485	94	7	the	the	DET
eurjchem-2485	94	8	authors	author	NOUN
eurjchem-2485	94	9	have	have	AUX
eurjchem-2485	94	10	declared	declare	VERB
eurjchem-2485	94	11	that	that	SCONJ
eurjchem-2485	94	12	there	there	PRON
eurjchem-2485	94	13	are	be	VERB
eurjchem-2485	94	14	no	no	DET
eurjchem-2485	94	15	competing	compete	VERB
eurjchem-2485	94	16	interests	interest	NOUN
eurjchem-2485	94	17	.	.	PUNCT
eurjchem-2485	95	1	ethical	ethical	ADJ
eurjchem-2485	95	2	approval	approval	NOUN
eurjchem-2485	95	3	:	:	PUNCT
eurjchem-2485	96	1	all	all	DET
eurjchem-2485	96	2	ethical	ethical	ADJ
eurjchem-2485	96	3	guidelines	guideline	NOUN
eurjchem-2485	96	4	have	have	AUX
eurjchem-2485	96	5	been	be	AUX
eurjchem-2485	96	6	adhered	adhere	VERB
eurjchem-2485	96	7	to	to	ADP
eurjchem-2485	96	8	.	.	PUNCT
eurjchem-2485	97	1	credit	credit	NOUN
eurjchem-2485	97	2	authorship	authorship	NOUN
eurjchem-2485	97	3	contribution	contribution	NOUN
eurjchem-2485	97	4	statement	statement	NOUN
eurjchem-2485	97	5	conceptualization	conceptualization	NOUN
eurjchem-2485	97	6	:	:	PUNCT
eurjchem-2485	97	7	roger	roger	PROPN
eurjchem-2485	97	8	lalancette	lalancette	PROPN
eurjchem-2485	97	9	,	,	PUNCT
eurjchem-2485	97	10	ivan	ivan	PROPN
eurjchem-2485	97	11	bernal	bernal	PROPN
eurjchem-2485	97	12	;	;	PUNCT
eurjchem-2485	97	13	methodology	methodology	NOUN
eurjchem-2485	97	14	:	:	PUNCT
eurjchem-2485	97	15	roger	roger	PROPN
eurjchem-2485	97	16	lalancette	lalancette	PROPN
eurjchem-2485	97	17	,	,	PUNCT
eurjchem-2485	97	18	ivan	ivan	PROPN
eurjchem-2485	97	19	bernal	bernal	PROPN
eurjchem-2485	97	20	;	;	PUNCT
eurjchem-2485	97	21	software	software	NOUN
eurjchem-2485	97	22	:	:	PUNCT
eurjchem-2485	97	23	roger	roger	PROPN
eurjchem-2485	97	24	lalancette	lalancette	PROPN
eurjchem-2485	97	25	,	,	PUNCT
eurjchem-2485	97	26	ivan	ivan	PROPN
eurjchem-2485	97	27	bernal	bernal	PROPN
eurjchem-2485	97	28	;	;	PUNCT
eurjchem-2485	97	29	validation	validation	NOUN
eurjchem-2485	97	30	:	:	PUNCT
eurjchem-2485	97	31	roger	roger	PROPN
eurjchem-2485	97	32	lalancette	lalancette	PROPN
eurjchem-2485	97	33	,	,	PUNCT
eurjchem-2485	97	34	ivan	ivan	PROPN
eurjchem-2485	97	35	bernal	bernal	PROPN
eurjchem-2485	97	36	;	;	PUNCT
eurjchem-2485	97	37	formal	formal	ADJ
eurjchem-2485	97	38	analysis	analysis	NOUN
eurjchem-2485	97	39	:	:	PUNCT
eurjchem-2485	97	40	roger	roger	PROPN
eurjchem-2485	97	41	lalancette	lalancette	PROPN
eurjchem-2485	97	42	,	,	PUNCT
eurjchem-2485	97	43	ivan	ivan	PROPN
eurjchem-2485	97	44	bernal	bernal	PROPN
eurjchem-2485	97	45	;	;	PUNCT
eurjchem-2485	97	46	investigation	investigation	NOUN
eurjchem-2485	97	47	:	:	PUNCT
eurjchem-2485	97	48	roger	roger	PROPN
eurjchem-2485	97	49	lalancette	lalancette	PROPN
eurjchem-2485	97	50	,	,	PUNCT
eurjchem-2485	97	51	ivan	ivan	PROPN
eurjchem-2485	97	52	bernal	bernal	PROPN
eurjchem-2485	97	53	;	;	PUNCT
eurjchem-2485	97	54	resources	resource	NOUN
eurjchem-2485	97	55	:	:	PUNCT
eurjchem-2485	97	56	roger	roger	PROPN
eurjchem-2485	97	57	lalancette	lalancette	PROPN
eurjchem-2485	97	58	,	,	PUNCT
eurjchem-2485	97	59	ivan	ivan	PROPN
eurjchem-2485	97	60	bernal	bernal	PROPN
eurjchem-2485	97	61	;	;	PUNCT
eurjchem-2485	97	62	data	datum	NOUN
eurjchem-2485	97	63	curation	curation	NOUN
eurjchem-2485	97	64	:	:	PUNCT
eurjchem-2485	97	65	roger	roger	PROPN
eurjchem-2485	97	66	lalancette	lalancette	PROPN
eurjchem-2485	97	67	,	,	PUNCT
eurjchem-2485	97	68	ivan	ivan	PROPN
eurjchem-2485	97	69	bernal	bernal	PROPN
eurjchem-2485	97	70	;	;	PUNCT
eurjchem-2485	97	71	writing	write	VERB
eurjchem-2485	97	72	original	original	ADJ
eurjchem-2485	97	73	draft	draft	NOUN
eurjchem-2485	97	74	:	:	PUNCT
eurjchem-2485	97	75	roger	roger	PROPN
eurjchem-2485	97	76	lalancette	lalancette	PROPN
eurjchem-2485	97	77	,	,	PUNCT
eurjchem-2485	97	78	ivan	ivan	PROPN
eurjchem-2485	97	79	bernal	bernal	PROPN
eurjchem-2485	97	80	;	;	PUNCT
eurjchem-2485	97	81	writing	write	VERB
eurjchem-2485	97	82	review	review	NOUN
eurjchem-2485	97	83	and	and	CCONJ
eurjchem-2485	97	84	editing	editing	NOUN
eurjchem-2485	97	85	:	:	PUNCT
eurjchem-2485	97	86	roger	roger	PROPN
eurjchem-2485	97	87	lalancette	lalancette	PROPN
eurjchem-2485	97	88	,	,	PUNCT
eurjchem-2485	97	89	ivan	ivan	PROPN
eurjchem-2485	97	90	bernal	bernal	PROPN
eurjchem-2485	97	91	;	;	PUNCT
eurjchem-2485	97	92	visualization	visualization	NOUN
eurjchem-2485	97	93	:	:	PUNCT
eurjchem-2485	97	94	roger	roger	PROPN
eurjchem-2485	97	95	lalancette	lalancette	PROPN
eurjchem-2485	97	96	,	,	PUNCT
eurjchem-2485	97	97	ivan	ivan	PROPN
eurjchem-2485	97	98	bernal	bernal	PROPN
eurjchem-2485	97	99	;	;	PUNCT
eurjchem-2485	97	100	supervision	supervision	NOUN
eurjchem-2485	97	101	:	:	PUNCT
eurjchem-2485	97	102	roger	roger	PROPN
eurjchem-2485	97	103	lalancette	lalancette	PROPN
eurjchem-2485	97	104	;	;	PUNCT
eurjchem-2485	97	105	project	project	NOUN
eurjchem-2485	97	106	administration	administration	NOUN
eurjchem-2485	97	107	:	:	PUNCT
eurjchem-2485	97	108	roger	roger	PROPN
eurjchem-2485	97	109	lalancette	lalancette	PROPN
eurjchem-2485	97	110	,	,	PUNCT
eurjchem-2485	97	111	ivan	ivan	PROPN
eurjchem-2485	97	112	bernal	bernal	PROPN
eurjchem-2485	97	113	.	.	PUNCT
eurjchem-2485	98	1	funding	funding	NOUN
eurjchem-2485	98	2	we	we	PRON
eurjchem-2485	98	3	acknowledge	acknowledge	VERB
eurjchem-2485	98	4	the	the	DET
eurjchem-2485	98	5	national	national	PROPN
eurjchem-2485	98	6	science	science	PROPN
eurjchem-2485	98	7	foundation	foundation	PROPN
eurjchem-2485	98	8	for	for	ADP
eurjchem-2485	98	9	nsf	nsf	PROPN
eurjchem-2485	98	10	-	-	PUNCT
eurjchem-2485	98	11	crif	crif	PROPN
eurjchem-2485	98	12	grant	grant	NOUN
eurjchem-2485	98	13	no	no	NOUN
eurjchem-2485	98	14	.	.	NOUN
eurjchem-2485	98	15	0443538	0443538	NUM
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eurjchem-2485	98	17	part	part	NOUN
eurjchem-2485	98	18	of	of	ADP
eurjchem-2485	98	19	the	the	DET
eurjchem-2485	98	20	purchase	purchase	NOUN
eurjchem-2485	98	21	of	of	ADP
eurjchem-2485	98	22	the	the	DET
eurjchem-2485	98	23	x	x	NOUN
eurjchem-2485	98	24	-	-	NOUN
eurjchem-2485	98	25	ray	ray	NOUN
eurjchem-2485	98	26	diffractometer	diffractometer	NOUN
eurjchem-2485	98	27	.	.	PUNCT
eurjchem-2485	99	1	orcid	orcid	NOUN
eurjchem-2485	99	2	and	and	CCONJ
eurjchem-2485	99	3	email	email	NOUN
eurjchem-2485	99	4	ivan	ivan	PROPN
eurjchem-2485	99	5	bernal	bernal	PROPN
eurjchem-2485	100	1	bernalibg@gmail.com	bernalibg@gmail.com	PROPN
eurjchem-2485	101	1	https://orcid.org/0000-0002-8168-5907	https://orcid.org/0000-0002-8168-5907	PROPN
eurjchem-2485	101	2	roger	roger	PROPN
eurjchem-2485	101	3	lalancette	lalancette	PROPN
eurjchem-2485	101	4	roger.lalancette@gmail.com	roger.lalancette@gmail.com	PROPN
eurjchem-2485	101	5	rogerlal@newark.rutgers.edu	rogerlal@newark.rutgers.edu	PROPN
eurjchem-2485	101	6	https://orcid.org/0000-0002-3470-532x	https://orcid.org/0000-0002-3470-532x	PROPN
eurjchem-2485	101	7	references	reference	NOUN
eurjchem-2485	101	8	[	[	X
eurjchem-2485	101	9	1	1	NUM
eurjchem-2485	101	10	]	]	PUNCT
eurjchem-2485	101	11	.	.	PUNCT
eurjchem-2485	102	1	bernal	bernal	PROPN
eurjchem-2485	102	2	,	,	PUNCT
eurjchem-2485	102	3	i.	i.	PROPN
eurjchem-2485	102	4	;	;	PUNCT
eurjchem-2485	102	5	rieger	rieger	PROPN
eurjchem-2485	102	6	,	,	PUNCT
eurjchem-2485	102	7	p.	p.	NOUN
eurjchem-2485	102	8	h.	h.	PROPN
eurjchem-2485	103	1	solvent	solvent	PROPN
eurjchem-2485	103	2	effects	effect	NOUN
eurjchem-2485	103	3	on	on	ADP
eurjchem-2485	103	4	the	the	DET
eurjchem-2485	103	5	optical	optical	ADJ
eurjchem-2485	103	6	and	and	CCONJ
eurjchem-2485	103	7	electron	electron	NOUN
eurjchem-2485	103	8	spin	spin	NOUN
eurjchem-2485	103	9	resonance	resonance	NOUN
eurjchem-2485	103	10	spectra	spectra	NOUN
eurjchem-2485	103	11	of	of	ADP
eurjchem-2485	103	12	vanadyl	vanadyl	PROPN
eurjchem-2485	103	13	acetylacetonate	acetylacetonate	NOUN
eurjchem-2485	103	14	.	.	PUNCT
eurjchem-2485	103	15	inorg	inorg	PROPN
eurjchem-2485	103	16	.	.	PUNCT
eurjchem-2485	104	1	chem	chem	PROPN
eurjchem-2485	104	2	.	.	PUNCT
eurjchem-2485	105	1	1963	1963	NUM
eurjchem-2485	105	2	,	,	PUNCT
eurjchem-2485	105	3	2	2	NUM
eurjchem-2485	105	4	,	,	PUNCT
eurjchem-2485	105	5	256–260	256–260	NUM
eurjchem-2485	105	6	.	.	PUNCT
eurjchem-2485	106	1	[	[	X
eurjchem-2485	106	2	2	2	NUM
eurjchem-2485	106	3	]	]	PUNCT
eurjchem-2485	106	4	.	.	PUNCT
eurjchem-2485	107	1	arslan	arslan	PROPN
eurjchem-2485	107	2	,	,	PUNCT
eurjchem-2485	107	3	e.	e.	PROPN
eurjchem-2485	107	4	;	;	PUNCT
eurjchem-2485	107	5	lalancette	lalancette	PROPN
eurjchem-2485	107	6	,	,	PUNCT
eurjchem-2485	107	7	r.	r.	PROPN
eurjchem-2485	107	8	a.	a.	PROPN
eurjchem-2485	107	9	;	;	PUNCT
eurjchem-2485	107	10	bernal	bernal	PROPN
eurjchem-2485	107	11	,	,	PUNCT
eurjchem-2485	107	12	i.	i.	PROPN
eurjchem-2485	107	13	an	an	DET
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eurjchem-2485	107	15	and	and	CCONJ
eurjchem-2485	107	16	unusual	unusual	ADJ
eurjchem-2485	107	17	v(5+)10	v(5+)10	NOUN
eurjchem-2485	107	18	cluster	cluster	NOUN
eurjchem-2485	107	19	containing	contain	VERB
eurjchem-2485	107	20	oxygen	oxygen	NOUN
eurjchem-2485	107	21	bridges	bridge	NOUN
eurjchem-2485	107	22	as	as	ADV
eurjchem-2485	107	23	well	well	ADV
eurjchem-2485	107	24	as	as	ADP
eurjchem-2485	107	25	six	six	NUM
eurjchem-2485	107	26	bidentate	bidentate	NOUN
eurjchem-2485	107	27	acetylacetonates	acetylacetonate	NOUN
eurjchem-2485	107	28	.	.	PUNCT
eurjchem-2485	107	29	struct	struct	NOUN
eurjchem-2485	107	30	.	.	PUNCT
eurjchem-2485	107	31	chem	chem	NOUN
eurjchem-2485	107	32	.	.	PUNCT
eurjchem-2485	108	1	2020	2020	NUM
eurjchem-2485	108	2	,	,	PUNCT
eurjchem-2485	108	3	31	31	NUM
eurjchem-2485	108	4	,	,	PUNCT
eurjchem-2485	108	5	1217–1222	1217–1222	NUM
eurjchem-2485	108	6	.	.	PUNCT
eurjchem-2485	109	1	[	[	X
eurjchem-2485	109	2	3	3	NUM
eurjchem-2485	109	3	]	]	PUNCT
eurjchem-2485	109	4	.	.	PUNCT
eurjchem-2485	110	1	arslan	arslan	PROPN
eurjchem-2485	110	2	,	,	PUNCT
eurjchem-2485	110	3	e.	e.	PROPN
eurjchem-2485	110	4	;	;	PUNCT
eurjchem-2485	110	5	bernal	bernal	PROPN
eurjchem-2485	110	6	,	,	PUNCT
eurjchem-2485	110	7	i.	i.	PROPN
eurjchem-2485	110	8	;	;	PUNCT
eurjchem-2485	110	9	lalancette	lalancette	PROPN
eurjchem-2485	110	10	,	,	PUNCT
eurjchem-2485	110	11	r.	r.	PROPN
eurjchem-2485	110	12	vanadyl(acetylacetonate)2	vanadyl(acetylacetonate)2	PROPN
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eurjchem-2485	110	18	-	-	PUNCT
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eurjchem-2485	110	25	at	at	ADP
eurjchem-2485	110	26	130	130	NUM
eurjchem-2485	110	27	°	°	NOUN
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eurjchem-2485	110	29	:	:	PUNCT
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eurjchem-2485	110	32	structure	structure	NOUN
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eurjchem-2485	110	34	its	its	PRON
eurjchem-2485	110	35	axial	axial	ADJ
eurjchem-2485	110	36	formamide	formamide	ADJ
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eurjchem-2485	110	38	.	.	PUNCT
eurjchem-2485	111	1	eur	eur	PROPN
eurjchem-2485	111	2	.	.	PUNCT
eurjchem-2485	112	1	j.	j.	PROPN
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eurjchem-2485	112	3	.	.	PUNCT
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eurjchem-2485	113	2	,	,	PUNCT
eurjchem-2485	113	3	13	13	NUM
eurjchem-2485	113	4	,	,	PUNCT
eurjchem-2485	113	5	168–171	168–171	NUM
eurjchem-2485	113	6	.	.	PUNCT
eurjchem-2485	114	1	[	[	X
eurjchem-2485	114	2	4	4	NUM
eurjchem-2485	114	3	]	]	PUNCT
eurjchem-2485	114	4	.	.	PUNCT
eurjchem-2485	115	1	bruker	bruker	PROPN
eurjchem-2485	115	2	(	(	PUNCT
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eurjchem-2485	116	5	.	.	PUNCT
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eurjchem-2485	117	11	.	.	PUNCT
eurjchem-2485	118	1	[	[	X
eurjchem-2485	118	2	5	5	NUM
eurjchem-2485	118	3	]	]	PUNCT
eurjchem-2485	118	4	.	.	PUNCT
eurjchem-2485	119	1	bruker	bruker	PROPN
eurjchem-2485	119	2	(	(	PUNCT
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eurjchem-2485	119	4	)	)	PUNCT
eurjchem-2485	119	5	.	.	PUNCT
eurjchem-2485	120	1	apex2	apex2	PROPN
eurjchem-2485	120	2	,	,	PUNCT
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eurjchem-2485	120	5	.	.	PUNCT
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eurjchem-2485	121	4	.	.	PROPN
eurjchem-2485	121	5	,	,	PUNCT
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eurjchem-2485	121	7	,	,	PUNCT
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eurjchem-2485	121	9	,	,	PUNCT
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eurjchem-2485	121	11	.	.	PUNCT
eurjchem-2485	122	1	[	[	X
eurjchem-2485	122	2	6	6	NUM
eurjchem-2485	122	3	]	]	PUNCT
eurjchem-2485	122	4	.	.	PUNCT
eurjchem-2485	123	1	bruker	bruker	PROPN
eurjchem-2485	123	2	(	(	PUNCT
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eurjchem-2485	123	4	)	)	PUNCT
eurjchem-2485	123	5	.	.	PUNCT
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eurjchem-2485	124	2	,	,	PUNCT
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eurjchem-2485	124	5	.	.	PUNCT
eurjchem-2485	125	1	bruker	bruker	PROPN
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eurjchem-2485	125	4	.	.	PROPN
eurjchem-2485	125	5	,	,	PUNCT
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eurjchem-2485	125	9	,	,	PUNCT
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eurjchem-2485	126	4	.	.	PUNCT
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eurjchem-2485	127	6	–	–	PUNCT
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eurjchem-2485	130	8	–	–	PUNCT
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eurjchem-2485	131	3	]	]	PUNCT
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eurjchem-2485	133	3	.	.	PUNCT
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eurjchem-2485	134	2	.	.	PUNCT
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eurjchem-2485	135	2	,	,	PUNCT
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eurjchem-2485	135	6	.	.	PUNCT
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eurjchem-2485	136	3	]	]	PUNCT
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eurjchem-2485	137	3	.	.	PUNCT
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eurjchem-2485	149	20	)	)	PUNCT
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eurjchem-2485	149	25	–	–	PUNCT
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eurjchem-2485	149	30	–	–	PUNCT
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eurjchem-2485	150	3	]	]	PUNCT
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eurjchem-2485	151	4	;	;	PUNCT
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eurjchem-2485	151	8	(	(	PUNCT
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eurjchem-2485	151	10	)	)	PUNCT
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eurjchem-2485	152	5	gbr	gbr	PROPN
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eurjchem-2485	152	7	.	.	PROPN
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eurjchem-2485	153	2	,	,	PUNCT
eurjchem-2485	153	3	53227	53227	NUM
eurjchem-2485	153	4	bonn	bonn	PROPN
eurjchem-2485	153	5	,	,	PUNCT
eurjchem-2485	153	6	germany	germany	PROPN
eurjchem-2485	153	7	.	.	PUNCT
eurjchem-2485	154	1	[	[	X
eurjchem-2485	154	2	12	12	NUM
eurjchem-2485	154	3	]	]	PUNCT
eurjchem-2485	154	4	.	.	PUNCT
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eurjchem-2485	155	4	i.	i.	PROPN
eurjchem-2485	155	5	;	;	PUNCT
eurjchem-2485	155	6	chang	chang	PROPN
eurjchem-2485	155	7	,	,	PUNCT
eurjchem-2485	155	8	y.-d	y.-d	PROPN
eurjchem-2485	155	9	.	.	PUNCT
eurjchem-2485	155	10	;	;	PUNCT
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eurjchem-2485	155	12	,	,	PUNCT
eurjchem-2485	155	13	q.	q.	PROPN
eurjchem-2485	155	14	;	;	PUNCT
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eurjchem-2485	155	16	,	,	PUNCT
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eurjchem-2485	155	38	-	-	PUNCT
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eurjchem-2485	156	7	)	)	PUNCT
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eurjchem-2485	157	6	-	-	PUNCT
eurjchem-2485	157	7	valence	valence	NOUN
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eurjchem-2485	157	9	(	(	PUNCT
eurjchem-2485	157	10	iv)squarate	iv)squarate	ADJ
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eurjchem-2485	157	12	[	[	X
eurjchem-2485	157	13	(	(	PUNCT
eurjchem-2485	157	14	n	n	X
eurjchem-2485	157	15	-	-	PUNCT
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eurjchem-2485	158	4	(	(	PUNCT
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eurjchem-2485	158	10	binuclear	binuclear	NOUN
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eurjchem-2485	158	12	species	specie	NOUN
eurjchem-2485	158	13	[	[	X
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eurjchem-2485	158	15	]	]	X
eurjchem-2485	158	16	.	.	PUNCT
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eurjchem-2485	159	2	.	.	PUNCT
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eurjchem-2485	160	2	.	.	PUNCT
eurjchem-2485	161	1	1994	1994	NUM
eurjchem-2485	161	2	,	,	PUNCT
eurjchem-2485	161	3	33	33	NUM
eurjchem-2485	161	4	,	,	PUNCT
eurjchem-2485	161	5	6340–6350	6340–6350	NUM
eurjchem-2485	161	6	.	.	PUNCT
eurjchem-2485	162	1	[	[	X
eurjchem-2485	162	2	13	13	NUM
eurjchem-2485	162	3	]	]	SYM
eurjchem-2485	162	4	.	.	PUNCT
eurjchem-2485	162	5	blackburn	blackburn	PROPN
eurjchem-2485	162	6	,	,	PUNCT
eurjchem-2485	162	7	b.	b.	PROPN
eurjchem-2485	162	8	j.	j.	PROPN
eurjchem-2485	162	9	;	;	PUNCT
eurjchem-2485	162	10	crane	crane	PROPN
eurjchem-2485	162	11	,	,	PUNCT
eurjchem-2485	162	12	j.	j.	PROPN
eurjchem-2485	162	13	h.	h.	PROPN
eurjchem-2485	162	14	;	;	PUNCT
eurjchem-2485	162	15	knapp	knapp	PROPN
eurjchem-2485	162	16	,	,	PUNCT
eurjchem-2485	162	17	c.	c.	PROPN
eurjchem-2485	162	18	e.	e.	PROPN
eurjchem-2485	162	19	;	;	PUNCT
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eurjchem-2485	162	21	,	,	PUNCT
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eurjchem-2485	162	23	j.	j.	PROPN
eurjchem-2485	162	24	;	;	PUNCT
eurjchem-2485	162	25	marchand	marchand	PROPN
eurjchem-2485	162	26	,	,	PUNCT
eurjchem-2485	162	27	p.	p.	PROPN
eurjchem-2485	162	28	;	;	PUNCT
eurjchem-2485	162	29	pugh	pugh	PROPN
eurjchem-2485	162	30	,	,	PUNCT
eurjchem-2485	162	31	d.	d.	PROPN
eurjchem-2485	162	32	;	;	PUNCT
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eurjchem-2485	162	34	,	,	PUNCT
eurjchem-2485	162	35	j.	j.	PROPN
eurjchem-2485	162	36	c.	c.	PROPN
eurjchem-2485	162	37	;	;	PUNCT
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eurjchem-2485	162	39	,	,	PUNCT
eurjchem-2485	162	40	i.	i.	PROPN
eurjchem-2485	162	41	p.	p.	PROPN
eurjchem-2485	162	42	;	;	PUNCT
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eurjchem-2485	162	44	,	,	PUNCT
eurjchem-2485	162	45	c.	c.	PROPN
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eurjchem-2485	162	51	with	with	ADP
eurjchem-2485	162	52	β	β	NOUN
eurjchem-2485	162	53	-	-	NOUN
eurjchem-2485	162	54	diketones	diketone	NOUN
eurjchem-2485	162	55	and	and	CCONJ
eurjchem-2485	162	56	diesters	diester	NOUN
eurjchem-2485	162	57	as	as	ADP
eurjchem-2485	162	58	precursors	precursor	NOUN
eurjchem-2485	162	59	for	for	ADP
eurjchem-2485	162	60	vanadium	vanadium	NOUN
eurjchem-2485	162	61	nitride	nitride	NOUN
eurjchem-2485	162	62	and	and	CCONJ
eurjchem-2485	162	63	carbide	carbide	NOUN
eurjchem-2485	162	64	.	.	PUNCT
eurjchem-2485	163	1	mater	mater	NOUN
eurjchem-2485	163	2	.	.	PUNCT
eurjchem-2485	164	1	des	des	PROPN
eurjchem-2485	164	2	.	.	PROPN
eurjchem-2485	164	3	2016	2016	NUM
eurjchem-2485	164	4	,	,	PUNCT
eurjchem-2485	164	5	108	108	NUM
eurjchem-2485	164	6	,	,	PUNCT
eurjchem-2485	164	7	780–790	780–790	NUM
eurjchem-2485	164	8	.	.	PUNCT
eurjchem-2485	165	1	[	[	X
eurjchem-2485	165	2	14	14	NUM
eurjchem-2485	165	3	]	]	PUNCT
eurjchem-2485	165	4	.	.	PUNCT
eurjchem-2485	166	1	bouma	bouma	PROPN
eurjchem-2485	166	2	,	,	PUNCT
eurjchem-2485	166	3	r.	r.	PROPN
eurjchem-2485	166	4	j.	j.	PROPN
eurjchem-2485	166	5	;	;	PUNCT
eurjchem-2485	166	6	teuben	teuben	PROPN
eurjchem-2485	166	7	,	,	PUNCT
eurjchem-2485	166	8	j.	j.	PROPN
eurjchem-2485	166	9	h.	h.	PROPN
eurjchem-2485	166	10	;	;	PUNCT
eurjchem-2485	166	11	beukema	beukema	ADV
eurjchem-2485	166	12	,	,	PUNCT
eurjchem-2485	166	13	w.	w.	PROPN
eurjchem-2485	166	14	r.	r.	PROPN
eurjchem-2485	166	15	;	;	PUNCT
eurjchem-2485	166	16	bansemer	bansemer	NOUN
eurjchem-2485	166	17	,	,	PUNCT
eurjchem-2485	166	18	r.	r.	PROPN
eurjchem-2485	166	19	l.	l.	PROPN
eurjchem-2485	166	20	;	;	PUNCT
eurjchem-2485	166	21	huffman	huffman	PROPN
eurjchem-2485	166	22	,	,	PUNCT
eurjchem-2485	166	23	j.	j.	PROPN
eurjchem-2485	166	24	c.	c.	PROPN
eurjchem-2485	166	25	;	;	PUNCT
eurjchem-2485	166	26	caulton	caulton	PROPN
eurjchem-2485	166	27	,	,	PUNCT
eurjchem-2485	166	28	k.	k.	PROPN
eurjchem-2485	166	29	g.	g.	PROPN
eurjchem-2485	166	30	identification	identification	NOUN
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eurjchem-2485	166	32	the	the	DET
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eurjchem-2485	166	34	reduction	reduction	NOUN
eurjchem-2485	166	35	product	product	NOUN
eurjchem-2485	166	36	of	of	ADP
eurjchem-2485	166	37	vcl3.3thf	vcl3.3thf	PROPN
eurjchem-2485	166	38	as	as	ADP
eurjchem-2485	166	39	[	[	X
eurjchem-2485	166	40	v2cl3(thf)6]2[zn2cl6	v2cl3(thf)6]2[zn2cl6	NOUN
eurjchem-2485	166	41	]	]	PUNCT
eurjchem-2485	166	42	.	.	PUNCT
eurjchem-2485	167	1	inorg	inorg	PROPN
eurjchem-2485	167	2	.	.	PUNCT
eurjchem-2485	168	1	chem	chem	PROPN
eurjchem-2485	168	2	.	.	PUNCT
eurjchem-2485	169	1	1984	1984	NUM
eurjchem-2485	169	2	,	,	PUNCT
eurjchem-2485	169	3	23	23	NUM
eurjchem-2485	169	4	,	,	PUNCT
eurjchem-2485	169	5	2715	2715	NUM
eurjchem-2485	169	6	–	–	PUNCT
eurjchem-2485	169	7	2718	2718	NUM
eurjchem-2485	169	8	.	.	PUNCT
eurjchem-2485	170	1	[	[	X
eurjchem-2485	170	2	15	15	NUM
eurjchem-2485	170	3	]	]	SYM
eurjchem-2485	170	4	.	.	PUNCT
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eurjchem-2485	171	2	,	,	PUNCT
eurjchem-2485	171	3	t.	t.	PROPN
eurjchem-2485	171	4	;	;	PUNCT
eurjchem-2485	171	5	mitsubori	mitsubori	X
eurjchem-2485	171	6	,	,	PUNCT
eurjchem-2485	171	7	s.-i	s.-i	PROPN
eurjchem-2485	171	8	.	.	PROPN
eurjchem-2485	171	9	;	;	PUNCT
eurjchem-2485	171	10	nogami	nogami	NOUN
eurjchem-2485	171	11	,	,	PUNCT
eurjchem-2485	171	12	t.	t.	PROPN
eurjchem-2485	171	13	;	;	PUNCT
eurjchem-2485	171	14	takeda	takeda	PROPN
eurjchem-2485	171	15	,	,	PUNCT
eurjchem-2485	171	16	n.	n.	PROPN
eurjchem-2485	171	17	;	;	PUNCT
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eurjchem-2485	171	19	,	,	PUNCT
eurjchem-2485	171	20	m.	m.	NOUN
eurjchem-2485	171	21	;	;	PUNCT
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eurjchem-2485	171	23	,	,	PUNCT
eurjchem-2485	171	24	h.	h.	PROPN
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eurjchem-2485	171	29	vanadium(iv	vanadium(iv	PROPN
eurjchem-2485	171	30	)	)	PUNCT
eurjchem-2485	171	31	dπ	dπ	ADP
eurjchem-2485	171	32	spins	spin	VERB
eurjchem-2485	171	33	across	across	ADP
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eurjchem-2485	171	35	rings	ring	NOUN
eurjchem-2485	171	36	:	:	PUNCT
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eurjchem-2485	171	38	complexes	complex	NOUN
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eurjchem-2485	171	40	oxovanadium(iv	oxovanadium(iv	NOUN
eurjchem-2485	171	41	)	)	PUNCT
eurjchem-2485	171	42	bis(1,1,1,5,5,5	bis(1,1,1,5,5,5	PROPN
eurjchem-2485	171	43	-	-	PUNCT
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eurjchem-2485	171	45	-	-	PUNCT
eurjchem-2485	171	46	dionate	dionate	NOUN
eurjchem-2485	171	47	)	)	PUNCT
eurjchem-2485	171	48	bridged	bridge	VERB
eurjchem-2485	171	49	by	by	ADP
eurjchem-2485	171	50	pyrimidine	pyrimidine	NOUN
eurjchem-2485	171	51	derivatives	derivative	NOUN
eurjchem-2485	171	52	.	.	PUNCT
eurjchem-2485	172	1	inorg	inorg	PROPN
eurjchem-2485	172	2	.	.	PUNCT
eurjchem-2485	173	1	chem	chem	PROPN
eurjchem-2485	173	2	.	.	PUNCT
eurjchem-2485	174	1	2001	2001	NUM
eurjchem-2485	174	2	,	,	PUNCT
eurjchem-2485	174	3	40	40	NUM
eurjchem-2485	174	4	,	,	PUNCT
eurjchem-2485	174	5	7059–7064	7059–7064	NUM
eurjchem-2485	174	6	.	.	PUNCT
eurjchem-2485	175	1	[	[	X
eurjchem-2485	175	2	16	16	NUM
eurjchem-2485	175	3	]	]	PUNCT
eurjchem-2485	175	4	.	.	PUNCT
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eurjchem-2485	176	2	-	-	PUNCT
eurjchem-2485	176	3	cabarrecq	cabarrecq	NOUN
eurjchem-2485	176	4	,	,	PUNCT
eurjchem-2485	176	5	c.	c.	PROPN
eurjchem-2485	176	6	;	;	PUNCT
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eurjchem-2485	176	8	,	,	PUNCT
eurjchem-2485	176	9	a.	a.	NOUN
eurjchem-2485	176	10	;	;	PUNCT
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eurjchem-2485	176	12	,	,	PUNCT
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eurjchem-2485	176	14	;	;	PUNCT
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eurjchem-2485	176	16	,	,	PUNCT
eurjchem-2485	176	17	j.	j.	PROPN
eurjchem-2485	176	18	c.	c.	PROPN
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eurjchem-2485	176	21	vanadium(iii	vanadium(iii	NOUN
eurjchem-2485	176	22	)	)	PUNCT
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eurjchem-2485	176	24	(	(	PUNCT
eurjchem-2485	176	25	iv	iv	X
eurjchem-2485	176	26	)	)	PUNCT
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eurjchem-2485	176	28	species	specie	NOUN
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eurjchem-2485	176	31	,	,	PUNCT
eurjchem-2485	176	32	structure	structure	NOUN
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eurjchem-2485	176	34	characterization	characterization	NOUN
eurjchem-2485	176	35	of	of	ADP
eurjchem-2485	176	36	[	[	X
eurjchem-2485	176	37	v(oh)(h2o)2(c4o4)]2·2h2o	v(oh)(h2o)2(c4o4)]2·2h2o	NOUN
eurjchem-2485	176	38	and	and	CCONJ
eurjchem-2485	176	39	(	(	PUNCT
eurjchem-2485	176	40	nh4)[(vo)2(oh)(c4o4)2(h2o)3]·3h2o	nh4)[(vo)2(oh)(c4o4)2(h2o)3]·3h2o	NUM
eurjchem-2485	176	41	.	.	PUNCT
eurjchem-2485	177	1	j.	j.	PROPN
eurjchem-2485	177	2	solid	solid	PROPN
eurjchem-2485	177	3	state	state	PROPN
eurjchem-2485	177	4	chem	chem	NOUN
eurjchem-2485	177	5	.	.	PUNCT
eurjchem-2485	178	1	2004	2004	NUM
eurjchem-2485	178	2	,	,	PUNCT
eurjchem-2485	178	3	177	177	NUM
eurjchem-2485	178	4	,	,	PUNCT
eurjchem-2485	178	5	2575–2583	2575–2583	NUM
eurjchem-2485	178	6	.	.	PUNCT
eurjchem-2485	179	1	[	[	X
eurjchem-2485	179	2	17	17	NUM
eurjchem-2485	179	3	]	]	SYM
eurjchem-2485	179	4	.	.	PUNCT
eurjchem-2485	180	1	ma	ma	PROPN
eurjchem-2485	180	2	,	,	PUNCT
eurjchem-2485	180	3	j.	j.	PROPN
eurjchem-2485	180	4	;	;	PUNCT
eurjchem-2485	180	5	zhao	zhao	PROPN
eurjchem-2485	180	6	,	,	PUNCT
eurjchem-2485	180	7	k.-q	k.-q	PROPN
eurjchem-2485	180	8	.	.	PUNCT
eurjchem-2485	180	9	;	;	PUNCT
eurjchem-2485	180	10	walton	walton	PROPN
eurjchem-2485	180	11	,	,	PUNCT
eurjchem-2485	180	12	m.	m.	PROPN
eurjchem-2485	180	13	j.	j.	PROPN
eurjchem-2485	180	14	;	;	PUNCT
eurjchem-2485	180	15	wright	wright	PROPN
eurjchem-2485	180	16	,	,	PUNCT
eurjchem-2485	180	17	j.	j.	PROPN
eurjchem-2485	180	18	a.	a.	PROPN
eurjchem-2485	180	19	;	;	PUNCT
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eurjchem-2485	180	21	,	,	PUNCT
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eurjchem-2485	180	24	a.	a.	PROPN
eurjchem-2485	180	25	;	;	PUNCT
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eurjchem-2485	180	30	j.	j.	PROPN
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eurjchem-2485	180	35	;	;	PUNCT
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eurjchem-2485	180	37	,	,	PUNCT
eurjchem-2485	180	38	w.-h	w.-h	NOUN
eurjchem-2485	180	39	.	.	PUNCT
eurjchem-2485	180	40	;	;	PUNCT
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eurjchem-2485	180	42	,	,	PUNCT
eurjchem-2485	180	43	c.	c.	PROPN
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eurjchem-2485	180	45	complexes	complex	NOUN
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eurjchem-2485	180	47	bi	bi	ADJ
eurjchem-2485	180	48	-	-	ADJ
eurjchem-2485	180	49	dentate	dentate	ADJ
eurjchem-2485	180	50	phenoxyimine	phenoxyimine	NOUN
eurjchem-2485	180	51	ligands	ligand	NOUN
eurjchem-2485	180	52	:	:	PUNCT
eurjchem-2485	180	53	synthesis	synthesis	NOUN
eurjchem-2485	180	54	,	,	PUNCT
eurjchem-2485	180	55	structural	structural	ADJ
eurjchem-2485	180	56	studies	study	NOUN
eurjchem-2485	180	57	and	and	CCONJ
eurjchem-2485	180	58	ethylene	ethylene	NOUN
eurjchem-2485	180	59	polymerization	polymerization	NOUN
eurjchem-2485	180	60	capability	capability	NOUN
eurjchem-2485	180	61	.	.	PUNCT
eurjchem-2485	181	1	dalton	dalton	PROPN
eurjchem-2485	181	2	trans	trans	PROPN
eurjchem-2485	181	3	.	.	PROPN
eurjchem-2485	181	4	2014	2014	NUM
eurjchem-2485	181	5	,	,	PUNCT
eurjchem-2485	181	6	43	43	NUM
eurjchem-2485	181	7	,	,	PUNCT
eurjchem-2485	181	8	8300	8300	NUM
eurjchem-2485	181	9	–	–	PUNCT
eurjchem-2485	181	10	8310	8310	NUM
eurjchem-2485	181	11	.	.	PUNCT
eurjchem-2485	182	1	[	[	X
eurjchem-2485	182	2	18	18	NUM
eurjchem-2485	182	3	]	]	PUNCT
eurjchem-2485	182	4	.	.	PUNCT
eurjchem-2485	182	5	crans	crans	PROPN
eurjchem-2485	182	6	,	,	PUNCT
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eurjchem-2485	182	8	c.	c.	PROPN
eurjchem-2485	182	9	;	;	PUNCT
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eurjchem-2485	182	11	,	,	PUNCT
eurjchem-2485	182	12	r.	r.	PROPN
eurjchem-2485	182	13	w.	w.	PROPN
eurjchem-2485	182	14	;	;	PUNCT
eurjchem-2485	182	15	gottlieb	gottlieb	PROPN
eurjchem-2485	182	16	,	,	PUNCT
eurjchem-2485	182	17	m.	m.	PROPN
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eurjchem-2485	182	19	;	;	PUNCT
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eurjchem-2485	182	23	p.	p.	PROPN
eurjchem-2485	182	24	;	;	PUNCT
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eurjchem-2485	182	26	,	,	PUNCT
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eurjchem-2485	182	30	)	)	PUNCT
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eurjchem-2485	182	33	propanediolate	propanediolate	NOUN
eurjchem-2485	182	34	chloride	chloride	NOUN
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eurjchem-2485	182	36	:	:	PUNCT
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eurjchem-2485	182	38	clusters	cluster	NOUN
eurjchem-2485	182	39	.	.	PUNCT
eurjchem-2485	183	1	inorg	inorg	PROPN
eurjchem-2485	183	2	.	.	PUNCT
eurjchem-2485	184	1	chem	chem	PROPN
eurjchem-2485	184	2	.	.	PUNCT
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eurjchem-2485	185	2	,	,	PUNCT
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eurjchem-2485	185	4	,	,	PUNCT
eurjchem-2485	185	5	4939–4949	4939–4949	NUM
eurjchem-2485	185	6	.	.	PUNCT
eurjchem-2485	186	1	[	[	X
eurjchem-2485	186	2	19	19	NUM
eurjchem-2485	186	3	]	]	PUNCT
eurjchem-2485	186	4	.	.	PUNCT
eurjchem-2485	187	1	sohail	sohail	PROPN
eurjchem-2485	187	2	,	,	PUNCT
eurjchem-2485	187	3	k.	k.	PROPN
eurjchem-2485	187	4	;	;	PUNCT
eurjchem-2485	187	5	lalancette	lalancette	PROPN
eurjchem-2485	187	6	,	,	PUNCT
eurjchem-2485	187	7	r.	r.	PROPN
eurjchem-2485	187	8	a.	a.	PROPN
eurjchem-2485	187	9	;	;	PUNCT
eurjchem-2485	187	10	bernal	bernal	PROPN
eurjchem-2485	187	11	,	,	PUNCT
eurjchem-2485	187	12	i.	i.	PROPN
eurjchem-2485	187	13	;	;	PUNCT
eurjchem-2485	187	14	guo	guo	PROPN
eurjchem-2485	187	15	,	,	PUNCT
eurjchem-2485	187	16	x.	x.	PROPN
eurjchem-2485	187	17	;	;	PUNCT
eurjchem-2485	187	18	zhao	zhao	X
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eurjchem-2485	187	20	l.	l.	PROPN
eurjchem-2485	188	1	revisiting	revisit	VERB
eurjchem-2485	188	2	the	the	DET
eurjchem-2485	188	3	structure	structure	NOUN
eurjchem-2485	188	4	of	of	ADP
eurjchem-2485	188	5	(	(	PUNCT
eurjchem-2485	188	6	±)-[co(en)3]i3·h2o	±)-[co(en)3]i3·h2o	PROPN
eurjchem-2485	188	7	–	–	PUNCT
eurjchem-2485	188	8	x	x	NOUN
eurjchem-2485	188	9	-	-	NOUN
eurjchem-2485	188	10	ray	ray	NOUN
eurjchem-2485	188	11	crystallographic	crystallographic	ADJ
eurjchem-2485	188	12	and	and	CCONJ
eurjchem-2485	188	13	secondharmonic	secondharmonic	ADJ
eurjchem-2485	188	14	results	result	NOUN
eurjchem-2485	188	15	.	.	PUNCT
eurjchem-2485	189	1	z.	z.	PROPN
eurjchem-2485	189	2	kristallogr	kristallogr	PROPN
eurjchem-2485	189	3	.	.	PUNCT
eurjchem-2485	190	1	cryst	cryst	PROPN
eurjchem-2485	190	2	.	.	PUNCT
eurjchem-2485	191	1	mater	mater	NOUN
eurjchem-2485	191	2	.	.	PUNCT
eurjchem-2485	192	1	2022	2022	NUM
eurjchem-2485	192	2	,	,	PUNCT
eurjchem-2485	192	3	237	237	NUM
eurjchem-2485	192	4	,	,	PUNCT
eurjchem-2485	192	5	393–402	393–402	NUM
eurjchem-2485	192	6	.	.	PUNCT
eurjchem-2485	193	1	[	[	X
eurjchem-2485	193	2	20	20	NUM
eurjchem-2485	193	3	]	]	PUNCT
eurjchem-2485	193	4	.	.	PUNCT
eurjchem-2485	194	1	whuler	whuler	NOUN
eurjchem-2485	194	2	,	,	PUNCT
eurjchem-2485	194	3	a.	a.	NOUN
eurjchem-2485	194	4	;	;	PUNCT
eurjchem-2485	194	5	spinat	spinat	NOUN
eurjchem-2485	194	6	,	,	PUNCT
eurjchem-2485	194	7	p.	p.	NOUN
eurjchem-2485	194	8	;	;	PUNCT
eurjchem-2485	194	9	brouty	brouty	NOUN
eurjchem-2485	194	10	,	,	PUNCT
eurjchem-2485	194	11	c.	c.	PROPN
eurjchem-2485	194	12	structure	structure	NOUN
eurjchem-2485	194	13	de	de	X
eurjchem-2485	194	14	l’iodure	l’iodure	PROPN
eurjchem-2485	194	15	de	de	X
eurjchem-2485	194	16	tris(éthylènediamine)cobalt(iii	tris(éthylènediamine)cobalt(iii	NOUN
eurjchem-2485	194	17	)	)	PUNCT
eurjchem-2485	194	18	monohydraté	monohydraté	PROPN
eurjchem-2485	194	19	.	.	PUNCT
eurjchem-2485	194	20	acta	acta	PROPN
eurjchem-2485	194	21	crystallogr	crystallogr	PROPN
eurjchem-2485	194	22	.	.	PUNCT
eurjchem-2485	195	1	b	b	NOUN
eurjchem-2485	195	2	1980	1980	NUM
eurjchem-2485	195	3	,	,	PUNCT
eurjchem-2485	195	4	36	36	NUM
eurjchem-2485	195	5	,	,	PUNCT
eurjchem-2485	195	6	1086–1091	1086–1091	NUM
eurjchem-2485	195	7	.	.	PUNCT
eurjchem-2485	196	1	[	[	X
eurjchem-2485	196	2	21	21	NUM
eurjchem-2485	196	3	]	]	PUNCT
eurjchem-2485	196	4	.	.	PUNCT
eurjchem-2485	197	1	spek	spek	PROPN
eurjchem-2485	197	2	,	,	PUNCT
eurjchem-2485	197	3	a.	a.	PROPN
eurjchem-2485	197	4	l.	l.	PROPN
eurjchem-2485	197	5	structure	structure	PROPN
eurjchem-2485	197	6	validation	validation	NOUN
eurjchem-2485	197	7	in	in	ADP
eurjchem-2485	197	8	chemical	chemical	ADJ
eurjchem-2485	197	9	crystallography	crystallography	NOUN
eurjchem-2485	197	10	.	.	PUNCT
eurjchem-2485	198	1	acta	acta	PROPN
eurjchem-2485	198	2	crystallogr	crystallogr	PROPN
eurjchem-2485	198	3	.	.	PUNCT
eurjchem-2485	199	1	d	d	X
eurjchem-2485	199	2	biol	biol	PROPN
eurjchem-2485	199	3	.	.	PUNCT
eurjchem-2485	200	1	crystallogr	crystallogr	PROPN
eurjchem-2485	200	2	.	.	PUNCT
eurjchem-2485	201	1	2009	2009	NUM
eurjchem-2485	201	2	,	,	PUNCT
eurjchem-2485	201	3	65	65	NUM
eurjchem-2485	201	4	,	,	PUNCT
eurjchem-2485	201	5	148–155	148–155	NUM
eurjchem-2485	201	6	.	.	PUNCT
eurjchem-2485	202	1	[	[	X
eurjchem-2485	202	2	22	22	NUM
eurjchem-2485	202	3	]	]	PUNCT
eurjchem-2485	202	4	.	.	PUNCT
eurjchem-2485	202	5	bernal	bernal	PROPN
eurjchem-2485	202	6	,	,	PUNCT
eurjchem-2485	202	7	i.	i.	PROPN
eurjchem-2485	202	8	;	;	PUNCT
eurjchem-2485	202	9	lalancette	lalancette	PROPN
eurjchem-2485	202	10	,	,	PUNCT
eurjchem-2485	202	11	r.	r.	PROPN
eurjchem-2485	202	12	a.	a.	PROPN
eurjchem-2485	202	13	unbalanced	unbalanced	ADJ
eurjchem-2485	202	14	racemates	racemate	NOUN
eurjchem-2485	202	15	:	:	PUNCT
eurjchem-2485	202	16	solid	solid	ADJ
eurjchem-2485	202	17	state	state	NOUN
eurjchem-2485	202	18	solutions	solution	NOUN
eurjchem-2485	202	19	containing	contain	VERB
eurjchem-2485	202	20	enantiomeric	enantiomeric	ADJ
eurjchem-2485	202	21	pairs	pair	NOUN
eurjchem-2485	202	22	crystallizing	crystallize	VERB
eurjchem-2485	202	23	in	in	ADP
eurjchem-2485	202	24	sohncke	sohncke	NOUN
eurjchem-2485	202	25	space	space	NOUN
eurjchem-2485	202	26	groups	group	NOUN
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eurjchem-2485	202	28	(	(	PUNCT
eurjchem-2485	202	29	l	l	NOUN
eurjchem-2485	202	30	:	:	PUNCT
eurjchem-2485	202	31	d	d	X
eurjchem-2485	202	32	)	)	PUNCT
eurjchem-2485	202	33	ratios	ratio	NOUN
eurjchem-2485	202	34	other	other	ADJ
eurjchem-2485	202	35	than	than	ADP
eurjchem-2485	202	36	(	(	PUNCT
eurjchem-2485	202	37	1:1	1:1	NUM
eurjchem-2485	202	38	)	)	PUNCT
eurjchem-2485	202	39	–	–	PUNCT
eurjchem-2485	202	40	illustrated	illustrate	VERB
eurjchem-2485	202	41	with	with	ADP
eurjchem-2485	202	42	crystals	crystal	NOUN
eurjchem-2485	202	43	of	of	ADP
eurjchem-2485	202	44	a	a	DET
eurjchem-2485	202	45	co(iii	co(iii	NOUN
eurjchem-2485	202	46	)	)	PUNCT
eurjchem-2485	202	47	coordination	coordination	NOUN
eurjchem-2485	202	48	compound	compound	NOUN
eurjchem-2485	202	49	.	.	PUNCT
eurjchem-2485	203	1	z.	z.	PROPN
eurjchem-2485	203	2	kristallogr	kristallogr	PROPN
eurjchem-2485	203	3	.	.	PUNCT
eurjchem-2485	204	1	cryst	cryst	PROPN
eurjchem-2485	204	2	.	.	PUNCT
eurjchem-2485	205	1	mater	mater	NOUN
eurjchem-2485	205	2	.	.	PUNCT
eurjchem-2485	206	1	2022	2022	NUM
eurjchem-2485	206	2	,	,	PUNCT
eurjchem-2485	206	3	237	237	NUM
eurjchem-2485	206	4	,	,	PUNCT
eurjchem-2485	206	5	311	311	NUM
eurjchem-2485	206	6	–	–	PUNCT
eurjchem-2485	206	7	316	316	NUM
eurjchem-2485	206	8	.	.	PUNCT
eurjchem-2485	207	1	copyright	copyright	NOUN
eurjchem-2485	207	2	©	©	PROPN
eurjchem-2485	207	3	2023	2023	NUM
eurjchem-2485	207	4	by	by	ADP
eurjchem-2485	207	5	authors	author	NOUN
eurjchem-2485	207	6	.	.	PUNCT
eurjchem-2485	208	1	this	this	DET
eurjchem-2485	208	2	work	work	NOUN
eurjchem-2485	208	3	is	be	AUX
eurjchem-2485	208	4	published	publish	VERB
eurjchem-2485	208	5	and	and	CCONJ
eurjchem-2485	208	6	licensed	license	VERB
eurjchem-2485	208	7	by	by	ADP
eurjchem-2485	208	8	atlanta	atlanta	PROPN
eurjchem-2485	208	9	publishing	publishing	PROPN
eurjchem-2485	208	10	house	house	PROPN
eurjchem-2485	208	11	llc	llc	PROPN
eurjchem-2485	208	12	,	,	PUNCT
eurjchem-2485	208	13	atlanta	atlanta	PROPN
eurjchem-2485	208	14	,	,	PUNCT
eurjchem-2485	208	15	ga	ga	PROPN
eurjchem-2485	208	16	,	,	PUNCT
eurjchem-2485	208	17	usa	usa	PROPN
eurjchem-2485	208	18	.	.	PUNCT
eurjchem-2485	209	1	the	the	DET
eurjchem-2485	209	2	full	full	ADJ
eurjchem-2485	209	3	terms	term	NOUN
eurjchem-2485	209	4	of	of	ADP
eurjchem-2485	209	5	this	this	DET
eurjchem-2485	209	6	license	license	NOUN
eurjchem-2485	209	7	are	be	AUX
eurjchem-2485	209	8	available	available	ADJ
eurjchem-2485	209	9	at	at	ADP
eurjchem-2485	209	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2485	209	11	and	and	CCONJ
eurjchem-2485	209	12	incorporate	incorporate	VERB
eurjchem-2485	209	13	the	the	DET
eurjchem-2485	209	14	creative	creative	ADJ
eurjchem-2485	209	15	commons	common	NOUN
eurjchem-2485	209	16	attribution	attribution	NOUN
eurjchem-2485	209	17	-	-	PUNCT
eurjchem-2485	209	18	non	non	ADJ
eurjchem-2485	209	19	commercial	commercial	NOUN
eurjchem-2485	209	20	(	(	PUNCT
eurjchem-2485	209	21	cc	cc	NOUN
eurjchem-2485	209	22	by	by	ADP
eurjchem-2485	209	23	nc	nc	PROPN
eurjchem-2485	209	24	)	)	PUNCT
eurjchem-2485	209	25	(	(	PUNCT
eurjchem-2485	209	26	international	international	ADJ
eurjchem-2485	209	27	,	,	PUNCT
eurjchem-2485	209	28	v4.0	v4.0	NOUN
eurjchem-2485	209	29	)	)	PUNCT
eurjchem-2485	209	30	license	license	NOUN
eurjchem-2485	209	31	(	(	PUNCT
eurjchem-2485	209	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2485	209	33	)	)	PUNCT
eurjchem-2485	209	34	.	.	PUNCT
eurjchem-2485	210	1	by	by	ADP
eurjchem-2485	210	2	accessing	access	VERB
eurjchem-2485	210	3	the	the	DET
eurjchem-2485	210	4	work	work	NOUN
eurjchem-2485	210	5	,	,	PUNCT
eurjchem-2485	210	6	you	you	PRON
eurjchem-2485	210	7	hereby	hereby	ADV
eurjchem-2485	210	8	accept	accept	VERB
eurjchem-2485	210	9	the	the	DET
eurjchem-2485	210	10	terms	term	NOUN
eurjchem-2485	210	11	.	.	PUNCT
eurjchem-2485	211	1	this	this	PRON
eurjchem-2485	211	2	is	be	AUX
eurjchem-2485	211	3	an	an	DET
eurjchem-2485	211	4	open	open	ADJ
eurjchem-2485	211	5	access	access	NOUN
eurjchem-2485	211	6	article	article	NOUN
eurjchem-2485	211	7	distributed	distribute	VERB
eurjchem-2485	211	8	under	under	ADP
eurjchem-2485	211	9	the	the	DET
eurjchem-2485	211	10	terms	term	NOUN
eurjchem-2485	211	11	and	and	CCONJ
eurjchem-2485	211	12	conditions	condition	NOUN
eurjchem-2485	211	13	of	of	ADP
eurjchem-2485	211	14	the	the	DET
eurjchem-2485	211	15	cc	cc	PROPN
eurjchem-2485	211	16	by	by	ADP
eurjchem-2485	211	17	nc	nc	PROPN
eurjchem-2485	211	18	license	license	PROPN
eurjchem-2485	211	19	,	,	PUNCT
eurjchem-2485	211	20	which	which	PRON
eurjchem-2485	211	21	permits	permit	VERB
eurjchem-2485	211	22	unrestricted	unrestricted	ADJ
eurjchem-2485	211	23	non	non	ADJ
eurjchem-2485	211	24	-	-	ADJ
eurjchem-2485	211	25	commercial	commercial	ADJ
eurjchem-2485	211	26	use	use	NOUN
eurjchem-2485	211	27	,	,	PUNCT
eurjchem-2485	211	28	distribution	distribution	NOUN
eurjchem-2485	211	29	,	,	PUNCT
eurjchem-2485	211	30	and	and	CCONJ
eurjchem-2485	211	31	reproduction	reproduction	NOUN
eurjchem-2485	211	32	in	in	ADP
eurjchem-2485	211	33	any	any	DET
eurjchem-2485	211	34	medium	medium	NOUN
eurjchem-2485	211	35	,	,	PUNCT
eurjchem-2485	211	36	provided	provide	VERB
eurjchem-2485	211	37	the	the	DET
eurjchem-2485	211	38	original	original	ADJ
eurjchem-2485	211	39	work	work	NOUN
eurjchem-2485	211	40	is	be	AUX
eurjchem-2485	211	41	properly	properly	ADV
eurjchem-2485	211	42	cited	cite	VERB
eurjchem-2485	211	43	without	without	ADP
eurjchem-2485	211	44	any	any	DET
eurjchem-2485	211	45	further	further	ADJ
eurjchem-2485	211	46	permission	permission	NOUN
eurjchem-2485	211	47	from	from	ADP
eurjchem-2485	211	48	atlanta	atlanta	PROPN
eurjchem-2485	211	49	publishing	publishing	PROPN
eurjchem-2485	211	50	house	house	PROPN
eurjchem-2485	211	51	llc	llc	PROPN
eurjchem-2485	211	52	(	(	PUNCT
eurjchem-2485	211	53	european	european	PROPN
eurjchem-2485	211	54	journal	journal	PROPN
eurjchem-2485	211	55	of	of	ADP
eurjchem-2485	211	56	chemistry	chemistry	NOUN
eurjchem-2485	211	57	)	)	PUNCT
eurjchem-2485	211	58	.	.	PUNCT
eurjchem-2485	212	1	no	no	DET
eurjchem-2485	212	2	use	use	NOUN
eurjchem-2485	212	3	,	,	PUNCT
eurjchem-2485	212	4	distribution	distribution	NOUN
eurjchem-2485	212	5	,	,	PUNCT
eurjchem-2485	212	6	or	or	CCONJ
eurjchem-2485	212	7	reproduction	reproduction	NOUN
eurjchem-2485	212	8	is	be	AUX
eurjchem-2485	212	9	permitted	permit	VERB
eurjchem-2485	212	10	which	which	PRON
eurjchem-2485	212	11	does	do	AUX
eurjchem-2485	212	12	not	not	PART
eurjchem-2485	212	13	comply	comply	VERB
eurjchem-2485	212	14	with	with	ADP
eurjchem-2485	212	15	these	these	DET
eurjchem-2485	212	16	terms	term	NOUN
eurjchem-2485	212	17	.	.	PUNCT
eurjchem-2485	213	1	permissions	permission	NOUN
eurjchem-2485	213	2	for	for	ADP
eurjchem-2485	213	3	commercial	commercial	ADJ
eurjchem-2485	213	4	use	use	NOUN
eurjchem-2485	213	5	of	of	ADP
eurjchem-2485	213	6	this	this	DET
eurjchem-2485	213	7	work	work	NOUN
eurjchem-2485	213	8	beyond	beyond	ADP
eurjchem-2485	213	9	the	the	DET
eurjchem-2485	213	10	scope	scope	NOUN
eurjchem-2485	213	11	of	of	ADP
eurjchem-2485	213	12	the	the	DET
eurjchem-2485	213	13	license	license	NOUN
eurjchem-2485	213	14	(	(	PUNCT
eurjchem-2485	213	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2485	213	16	)	)	PUNCT
eurjchem-2485	213	17	are	be	AUX
eurjchem-2485	213	18	administered	administer	VERB
eurjchem-2485	213	19	by	by	ADP
eurjchem-2485	213	20	atlanta	atlanta	PROPN
eurjchem-2485	213	21	publishing	publishing	PROPN
eurjchem-2485	213	22	house	house	PROPN
eurjchem-2485	213	23	llc	llc	PROPN
eurjchem-2485	213	24	(	(	PUNCT
eurjchem-2485	213	25	european	european	PROPN
eurjchem-2485	213	26	journal	journal	PROPN
eurjchem-2485	213	27	of	of	ADP
eurjchem-2485	213	28	chemistry	chemistry	NOUN
eurjchem-2485	213	29	)	)	PUNCT
eurjchem-2485	213	30	.	.	PUNCT
eurjchem-2485	214	1	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2485	214	2	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2485	214	3	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2485	214	4	1	1	NUM
eurjchem-2485	214	5	.	.	PUNCT
eurjchem-2485	214	6	introduction	introduction	NOUN
eurjchem-2485	214	7	2	2	NUM
eurjchem-2485	214	8	.	.	PUNCT
eurjchem-2485	214	9	experimental	experimental	ADJ
eurjchem-2485	214	10	2.1	2.1	NUM
eurjchem-2485	214	11	.	.	PUNCT
eurjchem-2485	215	1	preparation	preparation	NOUN
eurjchem-2485	215	2	of	of	ADP
eurjchem-2485	215	3	bis	bis	ADJ
eurjchem-2485	215	4	-	-	ADJ
eurjchem-2485	215	5	acetylacetonato	acetylacetonato	NOUN
eurjchem-2485	215	6	-	-	PUNCT
eurjchem-2485	215	7	chlorido	chlorido	NOUN
eurjchem-2485	215	8	-	-	PUNCT
eurjchem-2485	215	9	hydroxydo	hydroxydo	NOUN
eurjchem-2485	215	10	-	-	PUNCT
eurjchem-2485	215	11	tetravanadyl(iv	tetravanadyl(iv	NOUN
eurjchem-2485	215	12	)	)	PUNCT
eurjchem-2485	215	13	complex	complex	NOUN
eurjchem-2485	215	14	(	(	PUNCT
eurjchem-2485	215	15	i	i	NOUN
eurjchem-2485	215	16	)	)	PUNCT
eurjchem-2485	215	17	2.2	2.2	NUM
eurjchem-2485	215	18	.	.	PUNCT
eurjchem-2485	216	1	x	x	X
eurjchem-2485	216	2	-	-	PUNCT
eurjchem-2485	216	3	ray	ray	NOUN
eurjchem-2485	216	4	diffraction	diffraction	NOUN
eurjchem-2485	216	5	data	data	NOUN
eurjchem-2485	216	6	collection	collection	NOUN
eurjchem-2485	216	7	and	and	CCONJ
eurjchem-2485	216	8	processing	processing	NOUN
eurjchem-2485	216	9	3	3	NUM
eurjchem-2485	216	10	.	.	NOUN
eurjchem-2485	216	11	results	result	NOUN
eurjchem-2485	216	12	and	and	CCONJ
eurjchem-2485	216	13	discussion	discussion	NOUN
eurjchem-2485	216	14	4	4	NUM
eurjchem-2485	216	15	.	.	PUNCT
eurjchem-2485	217	1	conclusions	conclusion	NOUN
eurjchem-2485	217	2	acknowledgements	acknowledgement	NOUN
eurjchem-2485	217	3	supporting	support	VERB
eurjchem-2485	217	4	information	information	NOUN
eurjchem-2485	217	5	disclosure	disclosure	NOUN
eurjchem-2485	217	6	statement	statement	NOUN
eurjchem-2485	217	7	credit	credit	NOUN
eurjchem-2485	217	8	authorship	authorship	NOUN
eurjchem-2485	217	9	contribution	contribution	NOUN
eurjchem-2485	217	10	statement	statement	NOUN
eurjchem-2485	217	11	funding	fund	VERB
eurjchem-2485	217	12	orcid	orcid	NOUN
eurjchem-2485	217	13	and	and	CCONJ
eurjchem-2485	217	14	email	email	NOUN
eurjchem-2485	217	15	references	reference	NOUN
eurjchem-2485	217	16	printfield10	printfield10	PROPN
eurjchem-2485	217	17	:	:	PUNCT
eurjchem-2485	217	18	printfield11	printfield11	NOUN
eurjchem-2485	217	19	:	:	PUNCT
eurjchem-2485	217	20	printfield12	printfield12	PROPN
eurjchem-2485	217	21	:	:	PUNCT
eurjchem-2485	217	22	printfield13	printfield13	VERB
eurjchem-2485	217	23	:	:	PUNCT
eurjchem-2485	217	24	printfield14	printfield14	NOUN
eurjchem-2485	217	25	:	:	PUNCT
eurjchem-2485	217	26	printfield20	printfield20	PROPN
eurjchem-2485	217	27	:	:	PUNCT
eurjchem-2485	217	28	printfield21	printfield21	ADJ
eurjchem-2485	217	29	:	:	PUNCT
eurjchem-2485	217	30	printfield22	printfield22	NOUN
eurjchem-2485	217	31	:	:	PUNCT
eurjchem-2485	217	32	printfield23	printfield23	NOUN
eurjchem-2485	217	33	:	:	PUNCT
eurjchem-2485	217	34	printfield24	printfield24	NOUN
eurjchem-2485	217	35	:	:	PUNCT