id	sid	tid	token	lemma	pos
eurjchem-2489	1	1	a	a	DET
eurjchem-2489	1	2	square	square	ADJ
eurjchem-2489	1	3	planar	planar	ADJ
eurjchem-2489	1	4	copper(ii	copper(ii	NOUN
eurjchem-2489	1	5	)	)	PUNCT
eurjchem-2489	1	6	complex	complex	NOUN
eurjchem-2489	1	7	noncovalently	noncovalently	ADV
eurjchem-2489	1	8	conjugated	conjugate	VERB
eurjchem-2489	1	9	with	with	ADP
eurjchem-2489	1	10	a	a	DET
eurjchem-2489	1	11	p	p	NOUN
eurjchem-2489	1	12	-	-	PUNCT
eurjchem-2489	1	13	cresol	cresol	NOUN
eurjchem-2489	1	14	for	for	ADP
eurjchem-2489	1	15	bioinspired	bioinspire	VERB
eurjchem-2489	1	16	catecholase	catecholase	NOUN
eurjchem-2489	1	17	activity	activity	NOUN
eurjchem-2489	1	18	european	european	ADJ
eurjchem-2489	1	19	journal	journal	PROPN
eurjchem-2489	1	20	of	of	ADP
eurjchem-2489	1	21	chemistry	chemistry	NOUN
eurjchem-2489	1	22	14	14	NUM
eurjchem-2489	1	23	(	(	PUNCT
eurjchem-2489	1	24	4	4	NUM
eurjchem-2489	1	25	)	)	PUNCT
eurjchem-2489	1	26	(	(	PUNCT
eurjchem-2489	1	27	2023	2023	NUM
eurjchem-2489	1	28	)	)	PUNCT
eurjchem-2489	1	29	499	499	NUM
eurjchem-2489	1	30	-	-	SYM
eurjchem-2489	1	31	506	506	NUM
eurjchem-2489	1	32	european	european	ADJ
eurjchem-2489	1	33	journal	journal	NOUN
eurjchem-2489	1	34	of	of	ADP
eurjchem-2489	1	35	chemistry	chemistry	NOUN
eurjchem-2489	1	36	issn	issn	VERB
eurjchem-2489	1	37	2153	2153	NUM
eurjchem-2489	1	38	-	-	SYM
eurjchem-2489	1	39	2249	2249	NUM
eurjchem-2489	1	40	(	(	PUNCT
eurjchem-2489	1	41	print	print	NOUN
eurjchem-2489	1	42	)	)	PUNCT
eurjchem-2489	1	43	/	/	PUNCT
eurjchem-2489	1	44	issn	issn	PROPN
eurjchem-2489	1	45	2153	2153	NUM
eurjchem-2489	1	46	-	-	SYM
eurjchem-2489	1	47	2257	2257	NUM
eurjchem-2489	1	48	(	(	PUNCT
eurjchem-2489	1	49	online	online	ADJ
eurjchem-2489	1	50	)	)	PUNCT
eurjchem-2489	1	51	–	–	PUNCT
eurjchem-2489	2	1	copyright	copyright	NOUN
eurjchem-2489	2	2	©	©	PROPN
eurjchem-2489	2	3	2023	2023	NUM
eurjchem-2489	2	4	the	the	DET
eurjchem-2489	2	5	authors	author	NOUN
eurjchem-2489	2	6	–	–	PUNCT
eurjchem-2489	2	7	atlanta	atlanta	PROPN
eurjchem-2489	2	8	publishing	publishing	PROPN
eurjchem-2489	2	9	house	house	PROPN
eurjchem-2489	2	10	llc	llc	PROPN
eurjchem-2489	2	11	–	–	PUNCT
eurjchem-2489	2	12	printed	print	VERB
eurjchem-2489	2	13	in	in	ADP
eurjchem-2489	2	14	the	the	DET
eurjchem-2489	2	15	usa	usa	PROPN
eurjchem-2489	2	16	.	.	PUNCT
eurjchem-2489	3	1	this	this	DET
eurjchem-2489	3	2	work	work	NOUN
eurjchem-2489	3	3	is	be	AUX
eurjchem-2489	3	4	published	publish	VERB
eurjchem-2489	3	5	and	and	CCONJ
eurjchem-2489	3	6	licensed	license	VERB
eurjchem-2489	3	7	by	by	ADP
eurjchem-2489	3	8	atlanta	atlanta	PROPN
eurjchem-2489	3	9	publishing	publishing	PROPN
eurjchem-2489	3	10	house	house	PROPN
eurjchem-2489	3	11	llc	llc	PROPN
eurjchem-2489	3	12	–	–	PUNCT
eurjchem-2489	3	13	cc	cc	PROPN
eurjchem-2489	3	14	by	by	ADP
eurjchem-2489	3	15	nc	nc	PROPN
eurjchem-2489	3	16	–	–	PUNCT
eurjchem-2489	3	17	some	some	DET
eurjchem-2489	3	18	rights	right	NOUN
eurjchem-2489	3	19	reserved	reserve	VERB
eurjchem-2489	3	20	.	.	PUNCT
eurjchem-2489	4	1	https://dx.doi.org/10.5155/eurjchem.14.4.499-506.2489	https://dx.doi.org/10.5155/eurjchem.14.4.499-506.2489	PROPN
eurjchem-2489	4	2	european	european	PROPN
eurjchem-2489	4	3	journal	journal	PROPN
eurjchem-2489	4	4	of	of	ADP
eurjchem-2489	4	5	chemistry	chemistry	NOUN
eurjchem-2489	4	6	view	view	NOUN
eurjchem-2489	4	7	journal	journal	PROPN
eurjchem-2489	4	8	online	online	PROPN
eurjchem-2489	4	9	view	view	NOUN
eurjchem-2489	4	10	article	article	NOUN
eurjchem-2489	4	11	online	online	VERB
eurjchem-2489	4	12	a	a	DET
eurjchem-2489	4	13	square	square	ADJ
eurjchem-2489	4	14	planar	planar	ADJ
eurjchem-2489	4	15	copper(ii	copper(ii	NOUN
eurjchem-2489	4	16	)	)	PUNCT
eurjchem-2489	4	17	complex	complex	NOUN
eurjchem-2489	4	18	noncovalently	noncovalently	ADV
eurjchem-2489	4	19	conjugated	conjugate	VERB
eurjchem-2489	4	20	with	with	ADP
eurjchem-2489	4	21	a	a	DET
eurjchem-2489	4	22	p	p	NOUN
eurjchem-2489	4	23	-	-	PUNCT
eurjchem-2489	4	24	cresol	cresol	NOUN
eurjchem-2489	4	25	for	for	ADP
eurjchem-2489	4	26	bioinspired	bioinspire	VERB
eurjchem-2489	4	27	catecholase	catecholase	NOUN
eurjchem-2489	4	28	activity	activity	NOUN
eurjchem-2489	4	29	subham	subham	NOUN
eurjchem-2489	4	30	mukherjee	mukherjee	NOUN
eurjchem-2489	4	31	1,2	1,2	NUM
eurjchem-2489	4	32	,	,	PUNCT
eurjchem-2489	4	33	gayetri	gayetri	ADJ
eurjchem-2489	4	34	sarkar	sarkar	NOUN
eurjchem-2489	4	35	1	1	NUM
eurjchem-2489	4	36	,	,	PUNCT
eurjchem-2489	4	37	abhranil	abhranil	NOUN
eurjchem-2489	4	38	de	de	X
eurjchem-2489	4	39	3	3	NUM
eurjchem-2489	4	40	and	and	CCONJ
eurjchem-2489	4	41	bhaskar	bhaskar	NOUN
eurjchem-2489	4	42	biswas	biswas	NOUN
eurjchem-2489	4	43	1	1	NUM
eurjchem-2489	4	44	,	,	PUNCT
eurjchem-2489	4	45	*	*	PROPN
eurjchem-2489	4	46	1	1	NUM
eurjchem-2489	4	47	department	department	NOUN
eurjchem-2489	4	48	of	of	ADP
eurjchem-2489	4	49	chemistry	chemistry	NOUN
eurjchem-2489	4	50	,	,	PUNCT
eurjchem-2489	4	51	university	university	NOUN
eurjchem-2489	4	52	of	of	ADP
eurjchem-2489	4	53	north	north	PROPN
eurjchem-2489	4	54	bengal	bengal	ADJ
eurjchem-2489	4	55	,	,	PUNCT
eurjchem-2489	4	56	darjeeling	darjeeling	NOUN
eurjchem-2489	4	57	,	,	PUNCT
eurjchem-2489	4	58	734013	734013	NUM
eurjchem-2489	4	59	,	,	PUNCT
eurjchem-2489	4	60	india	india	PROPN
eurjchem-2489	4	61	2	2	NUM
eurjchem-2489	4	62	department	department	NOUN
eurjchem-2489	4	63	of	of	ADP
eurjchem-2489	4	64	chemistry	chemistry	NOUN
eurjchem-2489	4	65	,	,	PUNCT
eurjchem-2489	4	66	surya	surya	PROPN
eurjchem-2489	4	67	sen	sen	PROPN
eurjchem-2489	4	68	mahavidyalaya	mahavidyalaya	PROPN
eurjchem-2489	4	69	,	,	PUNCT
eurjchem-2489	4	70	jalpaiguri	jalpaiguri	NOUN
eurjchem-2489	4	71	,	,	PUNCT
eurjchem-2489	4	72	734004	734004	NUM
eurjchem-2489	4	73	,	,	PUNCT
eurjchem-2489	4	74	india	india	PROPN
eurjchem-2489	4	75	3	3	PROPN
eurjchem-2489	4	76	department	department	NOUN
eurjchem-2489	4	77	of	of	ADP
eurjchem-2489	4	78	basic	basic	ADJ
eurjchem-2489	4	79	science	science	NOUN
eurjchem-2489	4	80	and	and	CCONJ
eurjchem-2489	4	81	humanities	humanity	NOUN
eurjchem-2489	4	82	,	,	PUNCT
eurjchem-2489	4	83	hooghly	hooghly	ADV
eurjchem-2489	4	84	engineering	engineering	NOUN
eurjchem-2489	4	85	and	and	CCONJ
eurjchem-2489	4	86	technology	technology	NOUN
eurjchem-2489	4	87	college	college	NOUN
eurjchem-2489	4	88	,	,	PUNCT
eurjchem-2489	4	89	hooghly	hooghly	ADV
eurjchem-2489	4	90	,	,	PUNCT
eurjchem-2489	4	91	712103	712103	NUM
eurjchem-2489	4	92	,	,	PUNCT
eurjchem-2489	4	93	india	india	PROPN
eurjchem-2489	4	94	*	*	PUNCT
eurjchem-2489	4	95	corresponding	correspond	VERB
eurjchem-2489	4	96	author	author	NOUN
eurjchem-2489	4	97	at	at	ADP
eurjchem-2489	4	98	:	:	PUNCT
eurjchem-2489	4	99	department	department	NOUN
eurjchem-2489	4	100	of	of	ADP
eurjchem-2489	4	101	chemistry	chemistry	NOUN
eurjchem-2489	4	102	,	,	PUNCT
eurjchem-2489	4	103	university	university	NOUN
eurjchem-2489	4	104	of	of	ADP
eurjchem-2489	4	105	north	north	PROPN
eurjchem-2489	4	106	bengal	bengal	ADJ
eurjchem-2489	4	107	,	,	PUNCT
eurjchem-2489	4	108	darjeeling	darjeeling	NOUN
eurjchem-2489	4	109	,	,	PUNCT
eurjchem-2489	4	110	734013	734013	NUM
eurjchem-2489	4	111	,	,	PUNCT
eurjchem-2489	4	112	india	india	PROPN
eurjchem-2489	4	113	.	.	PUNCT
eurjchem-2489	5	1	e	e	X
eurjchem-2489	5	2	-	-	NOUN
eurjchem-2489	5	3	mail	mail	NOUN
eurjchem-2489	5	4	:	:	PUNCT
eurjchem-2489	5	5	bhaskarbiswas@nbu.ac.in	bhaskarbiswas@nbu.ac.in	NOUN
eurjchem-2489	5	6	(	(	PUNCT
eurjchem-2489	5	7	b.	b.	PROPN
eurjchem-2489	5	8	biswas	biswas	PROPN
eurjchem-2489	5	9	)	)	PUNCT
eurjchem-2489	5	10	.	.	PUNCT
eurjchem-2489	6	1	10.5155	10.5155	NUM
eurjchem-2489	6	2	/	/	SYM
eurjchem-2489	6	3	eurjchem.14.4.499	eurjchem.14.4.499	PROPN
eurjchem-2489	6	4	-	-	PUNCT
eurjchem-2489	6	5	506.2489	506.2489	NUM
eurjchem-2489	6	6	received	receive	VERB
eurjchem-2489	6	7	:	:	PUNCT
eurjchem-2489	6	8	28	28	NUM
eurjchem-2489	6	9	october	october	PROPN
eurjchem-2489	6	10	2023	2023	NUM
eurjchem-2489	6	11	received	receive	VERB
eurjchem-2489	6	12	in	in	ADP
eurjchem-2489	6	13	revised	revise	VERB
eurjchem-2489	6	14	form	form	NOUN
eurjchem-2489	6	15	:	:	PUNCT
eurjchem-2489	6	16	04	04	NUM
eurjchem-2489	6	17	december	december	PROPN
eurjchem-2489	6	18	2023	2023	NUM
eurjchem-2489	6	19	accepted	accept	VERB
eurjchem-2489	6	20	:	:	PUNCT
eurjchem-2489	6	21	10	10	NUM
eurjchem-2489	6	22	december	december	PROPN
eurjchem-2489	6	23	2023	2023	NUM
eurjchem-2489	6	24	published	publish	VERB
eurjchem-2489	6	25	online	online	NOUN
eurjchem-2489	6	26	:	:	PUNCT
eurjchem-2489	6	27	31	31	NUM
eurjchem-2489	6	28	december	december	PROPN
eurjchem-2489	6	29	2023	2023	NUM
eurjchem-2489	6	30	printed	print	VERB
eurjchem-2489	6	31	:	:	PUNCT
eurjchem-2489	6	32	31	31	NUM
eurjchem-2489	6	33	december	december	PROPN
eurjchem-2489	6	34	2023	2023	NUM
eurjchem-2489	6	35	this	this	DET
eurjchem-2489	6	36	work	work	NOUN
eurjchem-2489	6	37	presents	present	VERB
eurjchem-2489	6	38	the	the	DET
eurjchem-2489	6	39	synthesis	synthesis	NOUN
eurjchem-2489	6	40	of	of	ADP
eurjchem-2489	6	41	an	an	DET
eurjchem-2489	6	42	unprecedented	unprecedented	ADJ
eurjchem-2489	6	43	p	p	NOUN
eurjchem-2489	6	44	-	-	PUNCT
eurjchem-2489	6	45	cresol	cresol	NOUN
eurjchem-2489	6	46	-	-	PUNCT
eurjchem-2489	6	47	conjugated	conjugate	VERB
eurjchem-2489	6	48	copper(ii	copper(ii	NOUN
eurjchem-2489	6	49	)	)	PUNCT
eurjchem-2489	6	50	complex	complex	NOUN
eurjchem-2489	6	51	as	as	ADP
eurjchem-2489	6	52	a	a	DET
eurjchem-2489	6	53	p	p	NOUN
eurjchem-2489	6	54	-	-	PUNCT
eurjchem-2489	6	55	cresol	cresol	NOUN
eurjchem-2489	6	56	-	-	PUNCT
eurjchem-2489	6	57	coupled	couple	VERB
eurjchem-2489	6	58	polydentate	polydentate	ADJ
eurjchem-2489	6	59	ligand	ligand	NOUN
eurjchem-2489	6	60	,	,	PUNCT
eurjchem-2489	6	61	its	its	PRON
eurjchem-2489	6	62	crystal	crystal	NOUN
eurjchem-2489	6	63	structure	structure	NOUN
eurjchem-2489	6	64	,	,	PUNCT
eurjchem-2489	6	65	and	and	CCONJ
eurjchem-2489	6	66	catecholase	catecholase	NOUN
eurjchem-2489	6	67	activity	activity	NOUN
eurjchem-2489	6	68	.	.	PUNCT
eurjchem-2489	7	1	x	x	X
eurjchem-2489	7	2	-	-	NOUN
eurjchem-2489	7	3	ray	ray	NOUN
eurjchem-2489	7	4	crystallography	crystallography	NOUN
eurjchem-2489	7	5	reveals	reveal	VERB
eurjchem-2489	7	6	that	that	SCONJ
eurjchem-2489	7	7	the	the	DET
eurjchem-2489	7	8	cu(ii	cu(ii	PROPN
eurjchem-2489	7	9	)	)	PUNCT
eurjchem-2489	7	10	centre	centre	NOUN
eurjchem-2489	7	11	adopts	adopt	VERB
eurjchem-2489	7	12	a	a	DET
eurjchem-2489	7	13	nearly	nearly	ADV
eurjchem-2489	7	14	planar	planar	ADJ
eurjchem-2489	7	15	coordination	coordination	NOUN
eurjchem-2489	7	16	geometry	geometry	NOUN
eurjchem-2489	7	17	.	.	PUNCT
eurjchem-2489	8	1	crystal	crystal	NOUN
eurjchem-2489	8	2	data	datum	NOUN
eurjchem-2489	8	3	for	for	ADP
eurjchem-2489	8	4	c14h13cu0.5o3	c14h13cu0.5o3	NOUN
eurjchem-2489	8	5	:	:	PUNCT
eurjchem-2489	8	6	monoclinic	monoclinic	ADJ
eurjchem-2489	8	7	,	,	PUNCT
eurjchem-2489	8	8	space	space	NOUN
eurjchem-2489	8	9	group	group	NOUN
eurjchem-2489	8	10	p21	p21	PROPN
eurjchem-2489	8	11	/	/	SYM
eurjchem-2489	8	12	c	c	PROPN
eurjchem-2489	8	13	(	(	PUNCT
eurjchem-2489	8	14	no	no	INTJ
eurjchem-2489	8	15	.	.	NOUN
eurjchem-2489	8	16	14	14	NUM
eurjchem-2489	8	17	)	)	PUNCT
eurjchem-2489	8	18	,	,	PUNCT
eurjchem-2489	8	19	a	a	PRON
eurjchem-2489	8	20	=	=	X
eurjchem-2489	8	21	5.9204(2	5.9204(2	NUM
eurjchem-2489	8	22	)	)	PUNCT
eurjchem-2489	9	1	å	å	NOUN
eurjchem-2489	9	2	,	,	PUNCT
eurjchem-2489	9	3	b	b	X
eurjchem-2489	9	4	=	=	SYM
eurjchem-2489	9	5	21.5615(10	21.5615(10	NUM
eurjchem-2489	9	6	)	)	PUNCT
eurjchem-2489	9	7	å	å	NOUN
eurjchem-2489	9	8	,	,	PUNCT
eurjchem-2489	9	9	c	c	NOUN
eurjchem-2489	9	10	=	=	SYM
eurjchem-2489	9	11	9.0715(4	9.0715(4	X
eurjchem-2489	9	12	)	)	PUNCT
eurjchem-2489	9	13	å	å	NOUN
eurjchem-2489	9	14	,	,	PUNCT
eurjchem-2489	9	15	β	β	NOUN
eurjchem-2489	9	16	=	=	SYM
eurjchem-2489	9	17	91.266(4	91.266(4	NUM
eurjchem-2489	9	18	)	)	PUNCT
eurjchem-2489	9	19	°	°	NOUN
eurjchem-2489	9	20	,	,	PUNCT
eurjchem-2489	9	21	v	v	NOUN
eurjchem-2489	9	22	=	=	SYM
eurjchem-2489	9	23	1157.72(8	1157.72(8	NUM
eurjchem-2489	9	24	)	)	PUNCT
eurjchem-2489	9	25	å3	å3	PROPN
eurjchem-2489	9	26	,	,	PUNCT
eurjchem-2489	9	27	z	z	NOUN
eurjchem-2489	9	28	=	=	SYM
eurjchem-2489	9	29	4	4	NUM
eurjchem-2489	9	30	,	,	PUNCT
eurjchem-2489	9	31	μ(mokα	μ(mokα	NOUN
eurjchem-2489	9	32	)	)	PUNCT
eurjchem-2489	9	33	=	=	PUNCT
eurjchem-2489	10	1	0.987	0.987	NUM
eurjchem-2489	10	2	mm-1	mm-1	NOUN
eurjchem-2489	10	3	,	,	PUNCT
eurjchem-2489	10	4	dcalc	dcalc	NOUN
eurjchem-2489	10	5	=	=	PUNCT
eurjchem-2489	10	6	1.498	1.498	NUM
eurjchem-2489	10	7	g	g	NOUN
eurjchem-2489	10	8	/	/	SYM
eurjchem-2489	10	9	cm3	cm3	NOUN
eurjchem-2489	10	10	,	,	PUNCT
eurjchem-2489	10	11	12647	12647	NUM
eurjchem-2489	10	12	reflections	reflection	NOUN
eurjchem-2489	10	13	measured	measure	VERB
eurjchem-2489	10	14	(	(	PUNCT
eurjchem-2489	10	15	6.884	6.884	NUM
eurjchem-2489	10	16	°	°	NOUN
eurjchem-2489	10	17	≤	≤	NUM
eurjchem-2489	10	18	2θ	2θ	NUM
eurjchem-2489	10	19	≤	≤	NUM
eurjchem-2489	10	20	63.42	63.42	NUM
eurjchem-2489	10	21	°	°	NOUN
eurjchem-2489	10	22	)	)	PUNCT
eurjchem-2489	10	23	,	,	PUNCT
eurjchem-2489	10	24	3233	3233	NUM
eurjchem-2489	10	25	unique	unique	ADJ
eurjchem-2489	10	26	(	(	PUNCT
eurjchem-2489	10	27	rint	rint	NOUN
eurjchem-2489	10	28	=	=	SYM
eurjchem-2489	10	29	0.0618	0.0618	NUM
eurjchem-2489	10	30	,	,	PUNCT
eurjchem-2489	10	31	rsigma	rsigma	ADJ
eurjchem-2489	10	32	=	=	SYM
eurjchem-2489	10	33	0.0512	0.0512	NUM
eurjchem-2489	10	34	)	)	PUNCT
eurjchem-2489	10	35	which	which	PRON
eurjchem-2489	10	36	were	be	AUX
eurjchem-2489	10	37	used	use	VERB
eurjchem-2489	10	38	in	in	ADP
eurjchem-2489	10	39	all	all	DET
eurjchem-2489	10	40	calculations	calculation	NOUN
eurjchem-2489	10	41	.	.	PUNCT
eurjchem-2489	11	1	the	the	DET
eurjchem-2489	11	2	final	final	ADJ
eurjchem-2489	11	3	r1	r1	NOUN
eurjchem-2489	11	4	was	be	AUX
eurjchem-2489	11	5	0.0710	0.0710	NUM
eurjchem-2489	11	6	(	(	PUNCT
eurjchem-2489	11	7	i	i	X
eurjchem-2489	11	8	>	>	X
eurjchem-2489	11	9	2σ(i	2σ(i	NUM
eurjchem-2489	11	10	)	)	PUNCT
eurjchem-2489	11	11	)	)	PUNCT
eurjchem-2489	12	1	and	and	CCONJ
eurjchem-2489	12	2	wr2	wr2	PROPN
eurjchem-2489	12	3	was	be	AUX
eurjchem-2489	12	4	0.2173	0.2173	NUM
eurjchem-2489	12	5	(	(	PUNCT
eurjchem-2489	12	6	all	all	DET
eurjchem-2489	12	7	data	datum	NOUN
eurjchem-2489	12	8	)	)	PUNCT
eurjchem-2489	12	9	.	.	PUNCT
eurjchem-2489	13	1	the	the	DET
eurjchem-2489	13	2	crystallized	crystallized	ADJ
eurjchem-2489	13	3	p	p	NOUN
eurjchem-2489	13	4	-	-	PUNCT
eurjchem-2489	13	5	cresol	cresol	NOUN
eurjchem-2489	13	6	was	be	AUX
eurjchem-2489	13	7	localized	localize	VERB
eurjchem-2489	13	8	in	in	ADP
eurjchem-2489	13	9	complex	complex	ADJ
eurjchem-2489	13	10	units	unit	NOUN
eurjchem-2489	13	11	through	through	ADP
eurjchem-2489	13	12	intermolecular	intermolecular	ADJ
eurjchem-2489	13	13	o···h	o···h	NOUN
eurjchem-2489	13	14	interactions	interaction	NOUN
eurjchem-2489	13	15	and	and	CCONJ
eurjchem-2489	13	16	formed	form	VERB
eurjchem-2489	13	17	a	a	DET
eurjchem-2489	13	18	3d	3d	NUM
eurjchem-2489	13	19	supramolecular	supramolecular	ADJ
eurjchem-2489	13	20	framework	framework	NOUN
eurjchem-2489	13	21	employing	employ	VERB
eurjchem-2489	13	22	short	short	ADV
eurjchem-2489	13	23	-	-	PUNCT
eurjchem-2489	13	24	ranged	range	VERB
eurjchem-2489	13	25	o···h	o···h	NOUN
eurjchem-2489	13	26	and	and	CCONJ
eurjchem-2489	13	27	c	c	NOUN
eurjchem-2489	13	28	-	-	PUNCT
eurjchem-2489	13	29	h···π	h···π	PROPN
eurjchem-2489	13	30	interactions	interaction	NOUN
eurjchem-2489	13	31	in	in	ADP
eurjchem-2489	13	32	the	the	DET
eurjchem-2489	13	33	solid	solid	ADJ
eurjchem-2489	13	34	state	state	NOUN
eurjchem-2489	13	35	.	.	PUNCT
eurjchem-2489	14	1	the	the	DET
eurjchem-2489	14	2	copper(ii	copper(ii	NOUN
eurjchem-2489	14	3	)	)	PUNCT
eurjchem-2489	14	4	complex	complex	NOUN
eurjchem-2489	14	5	has	have	AUX
eurjchem-2489	14	6	been	be	AUX
eurjchem-2489	14	7	evaluated	evaluate	VERB
eurjchem-2489	14	8	as	as	ADP
eurjchem-2489	14	9	a	a	DET
eurjchem-2489	14	10	bioinspired	bioinspired	ADJ
eurjchem-2489	14	11	catalyst	catalyst	NOUN
eurjchem-2489	14	12	in	in	ADP
eurjchem-2489	14	13	the	the	DET
eurjchem-2489	14	14	oxidative	oxidative	ADJ
eurjchem-2489	14	15	transformation	transformation	NOUN
eurjchem-2489	14	16	of	of	ADP
eurjchem-2489	14	17	3,5	3,5	NUM
eurjchem-2489	14	18	-	-	PUNCT
eurjchem-2489	14	19	di	di	NOUN
eurjchem-2489	14	20	-	-	PUNCT
eurjchem-2489	14	21	tert	tert	NOUN
eurjchem-2489	14	22	-	-	PUNCT
eurjchem-2489	14	23	butylcatechol	butylcatechol	NOUN
eurjchem-2489	14	24	(	(	PUNCT
eurjchem-2489	14	25	dtbc	dtbc	PROPN
eurjchem-2489	14	26	)	)	PUNCT
eurjchem-2489	14	27	to	to	ADP
eurjchem-2489	14	28	o	o	NOUN
eurjchem-2489	14	29	-	-	PUNCT
eurjchem-2489	14	30	benzoquinone	benzoquinone	NOUN
eurjchem-2489	14	31	in	in	ADP
eurjchem-2489	14	32	acetonitrile	acetonitrile	NOUN
eurjchem-2489	14	33	with	with	ADP
eurjchem-2489	14	34	a	a	DET
eurjchem-2489	14	35	high	high	ADJ
eurjchem-2489	14	36	turnover	turnover	NOUN
eurjchem-2489	14	37	number	number	NOUN
eurjchem-2489	14	38	,	,	PUNCT
eurjchem-2489	14	39	2.26×104	2.26×104	PROPN
eurjchem-2489	14	40	h–1	h–1	NOUN
eurjchem-2489	14	41	.	.	PUNCT
eurjchem-2489	15	1	electrochemical	electrochemical	ADJ
eurjchem-2489	15	2	analysis	analysis	NOUN
eurjchem-2489	15	3	of	of	ADP
eurjchem-2489	15	4	the	the	DET
eurjchem-2489	15	5	copper(ii	copper(ii	NOUN
eurjchem-2489	15	6	)	)	PUNCT
eurjchem-2489	15	7	complex	complex	NOUN
eurjchem-2489	15	8	in	in	ADP
eurjchem-2489	15	9	the	the	DET
eurjchem-2489	15	10	presence	presence	NOUN
eurjchem-2489	15	11	of	of	ADP
eurjchem-2489	15	12	dtbc	dtbc	PROPN
eurjchem-2489	15	13	recommends	recommend	VERB
eurjchem-2489	15	14	the	the	DET
eurjchem-2489	15	15	generation	generation	NOUN
eurjchem-2489	15	16	of	of	ADP
eurjchem-2489	15	17	a	a	DET
eurjchem-2489	15	18	catechol	catechol	NOUN
eurjchem-2489	15	19	/	/	SYM
eurjchem-2489	15	20	obenzosemiquinone	obenzosemiquinone	NOUN
eurjchem-2489	15	21	redox	redox	ADJ
eurjchem-2489	15	22	couple	couple	NOUN
eurjchem-2489	15	23	during	during	ADP
eurjchem-2489	15	24	catalytic	catalytic	ADJ
eurjchem-2489	15	25	oxidation	oxidation	NOUN
eurjchem-2489	15	26	with	with	ADP
eurjchem-2489	15	27	the	the	DET
eurjchem-2489	15	28	generation	generation	NOUN
eurjchem-2489	15	29	of	of	ADP
eurjchem-2489	15	30	hydrogen	hydrogen	NOUN
eurjchem-2489	15	31	peroxide	peroxide	NOUN
eurjchem-2489	15	32	as	as	ADP
eurjchem-2489	15	33	a	a	DET
eurjchem-2489	15	34	byproduct	byproduct	NOUN
eurjchem-2489	15	35	.	.	PUNCT
eurjchem-2489	16	1	single	single	ADJ
eurjchem-2489	16	2	crystal	crystal	PROPN
eurjchem-2489	16	3	x	x	PROPN
eurjchem-2489	16	4	-	-	NOUN
eurjchem-2489	16	5	ray	ray	NOUN
eurjchem-2489	16	6	structure	structure	NOUN
eurjchem-2489	16	7	characterization	characterization	NOUN
eurjchem-2489	16	8	copper(ii	copper(ii	NOUN
eurjchem-2489	16	9	)	)	PUNCT
eurjchem-2489	16	10	complex	complex	ADJ
eurjchem-2489	16	11	catecholase	catecholase	NOUN
eurjchem-2489	16	12	activity	activity	NOUN
eurjchem-2489	16	13	electrochemical	electrochemical	ADJ
eurjchem-2489	16	14	analysis	analysis	NOUN
eurjchem-2489	16	15	cite	cite	VERB
eurjchem-2489	16	16	this	this	PRON
eurjchem-2489	16	17	:	:	PUNCT
eurjchem-2489	16	18	eur	eur	PROPN
eurjchem-2489	16	19	.	.	PUNCT
eurjchem-2489	17	1	j.	j.	PROPN
eurjchem-2489	17	2	chem	chem	PROPN
eurjchem-2489	17	3	.	.	PUNCT
eurjchem-2489	18	1	2023	2023	NUM
eurjchem-2489	18	2	,	,	PUNCT
eurjchem-2489	18	3	14(4	14(4	NUM
eurjchem-2489	18	4	)	)	PUNCT
eurjchem-2489	18	5	,	,	PUNCT
eurjchem-2489	18	6	499	499	NUM
eurjchem-2489	18	7	-	-	SYM
eurjchem-2489	18	8	506	506	NUM
eurjchem-2489	18	9	journal	journal	NOUN
eurjchem-2489	18	10	website	website	NOUN
eurjchem-2489	18	11	:	:	PUNCT
eurjchem-2489	18	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2489	18	13	1	1	X
eurjchem-2489	18	14	.	.	PUNCT
eurjchem-2489	19	1	introduction	introduction	NOUN
eurjchem-2489	19	2	copper	copper	NOUN
eurjchem-2489	19	3	is	be	AUX
eurjchem-2489	19	4	one	one	NUM
eurjchem-2489	19	5	of	of	ADP
eurjchem-2489	19	6	the	the	DET
eurjchem-2489	19	7	precious	precious	ADJ
eurjchem-2489	19	8	biometals	biometal	NOUN
eurjchem-2489	19	9	,	,	PUNCT
eurjchem-2489	19	10	principally	principally	ADV
eurjchem-2489	19	11	for	for	ADP
eurjchem-2489	19	12	its	its	PRON
eurjchem-2489	19	13	significant	significant	ADJ
eurjchem-2489	19	14	contributions	contribution	NOUN
eurjchem-2489	19	15	to	to	ADP
eurjchem-2489	19	16	biological	biological	ADJ
eurjchem-2489	19	17	processes	process	NOUN
eurjchem-2489	19	18	and	and	CCONJ
eurjchem-2489	19	19	its	its	PRON
eurjchem-2489	19	20	captivating	captivating	ADJ
eurjchem-2489	19	21	synergism	synergism	NOUN
eurjchem-2489	19	22	with	with	ADP
eurjchem-2489	19	23	therapeutics	therapeutic	NOUN
eurjchem-2489	19	24	[	[	X
eurjchem-2489	19	25	1,2	1,2	NUM
eurjchem-2489	19	26	]	]	PUNCT
eurjchem-2489	19	27	.	.	PUNCT
eurjchem-2489	20	1	copper	copper	NOUN
eurjchem-2489	20	2	plays	play	VERB
eurjchem-2489	20	3	a	a	DET
eurjchem-2489	20	4	pivotal	pivotal	ADJ
eurjchem-2489	20	5	role	role	NOUN
eurjchem-2489	20	6	in	in	ADP
eurjchem-2489	20	7	cell	cell	NOUN
eurjchem-2489	20	8	physiology	physiology	NOUN
eurjchem-2489	20	9	as	as	ADP
eurjchem-2489	20	10	a	a	DET
eurjchem-2489	20	11	catalytic	catalytic	ADJ
eurjchem-2489	20	12	cofactor	cofactor	NOUN
eurjchem-2489	20	13	in	in	ADP
eurjchem-2489	20	14	the	the	DET
eurjchem-2489	20	15	redox	redox	ADJ
eurjchem-2489	20	16	events	event	NOUN
eurjchem-2489	20	17	of	of	ADP
eurjchem-2489	20	18	mitochondrial	mitochondrial	ADJ
eurjchem-2489	20	19	respiration	respiration	NOUN
eurjchem-2489	20	20	,	,	PUNCT
eurjchem-2489	20	21	free	free	ADJ
eurjchem-2489	20	22	radical	radical	ADJ
eurjchem-2489	20	23	scavenging	scavenging	NOUN
eurjchem-2489	20	24	,	,	PUNCT
eurjchem-2489	20	25	iron	iron	NOUN
eurjchem-2489	20	26	absorption	absorption	NOUN
eurjchem-2489	20	27	,	,	PUNCT
eurjchem-2489	20	28	and	and	CCONJ
eurjchem-2489	20	29	elastin	elastin	NOUN
eurjchem-2489	20	30	crosslinking	crosslinke	VERB
eurjchem-2489	20	31	[	[	X
eurjchem-2489	20	32	3	3	NUM
eurjchem-2489	20	33	-	-	SYM
eurjchem-2489	20	34	5	5	NUM
eurjchem-2489	20	35	]	]	PUNCT
eurjchem-2489	20	36	.	.	PUNCT
eurjchem-2489	21	1	among	among	ADP
eurjchem-2489	21	2	the	the	DET
eurjchem-2489	21	3	numerous	numerous	ADJ
eurjchem-2489	21	4	activities	activity	NOUN
eurjchem-2489	21	5	of	of	ADP
eurjchem-2489	21	6	copper	copper	NOUN
eurjchem-2489	21	7	ions	ion	NOUN
eurjchem-2489	21	8	in	in	ADP
eurjchem-2489	21	9	biological	biological	ADJ
eurjchem-2489	21	10	applications	application	NOUN
eurjchem-2489	21	11	,	,	PUNCT
eurjchem-2489	21	12	copper	copper	NOUN
eurjchem-2489	21	13	-	-	PUNCT
eurjchem-2489	21	14	mediated	mediate	VERB
eurjchem-2489	21	15	enzymatic	enzymatic	ADJ
eurjchem-2489	21	16	activities	activity	NOUN
eurjchem-2489	21	17	have	have	AUX
eurjchem-2489	21	18	attracted	attract	VERB
eurjchem-2489	21	19	a	a	DET
eurjchem-2489	21	20	large	large	ADJ
eurjchem-2489	21	21	amount	amount	NOUN
eurjchem-2489	21	22	of	of	ADP
eurjchem-2489	21	23	interest	interest	NOUN
eurjchem-2489	21	24	among	among	ADP
eurjchem-2489	21	25	synthetic	synthetic	ADJ
eurjchem-2489	21	26	coordination	coordination	NOUN
eurjchem-2489	21	27	chemists	chemist	NOUN
eurjchem-2489	21	28	.	.	PUNCT
eurjchem-2489	22	1	in	in	ADP
eurjchem-2489	22	2	this	this	DET
eurjchem-2489	22	3	view	view	NOUN
eurjchem-2489	22	4	,	,	PUNCT
eurjchem-2489	22	5	the	the	DET
eurjchem-2489	22	6	catecholase	catecholase	NOUN
eurjchem-2489	22	7	enzyme	enzyme	NOUN
eurjchem-2489	22	8	,	,	PUNCT
eurjchem-2489	22	9	a	a	DET
eurjchem-2489	22	10	copper	copper	NOUN
eurjchem-2489	22	11	-	-	ADJ
eurjchem-2489	22	12	centric	centric	ADJ
eurjchem-2489	22	13	bioenzyme	bioenzyme	NOUN
eurjchem-2489	22	14	,	,	PUNCT
eurjchem-2489	22	15	catalyzes	catalyze	VERB
eurjchem-2489	22	16	the	the	DET
eurjchem-2489	22	17	transformation	transformation	NOUN
eurjchem-2489	22	18	of	of	ADP
eurjchem-2489	22	19	o	o	NOUN
eurjchem-2489	22	20	-	-	NOUN
eurjchem-2489	22	21	diphenols	diphenols	ADJ
eurjchem-2489	22	22	into	into	ADP
eurjchem-2489	22	23	orthoquinones	orthoquinone	NOUN
eurjchem-2489	22	24	by	by	ADP
eurjchem-2489	22	25	coupling	couple	VERB
eurjchem-2489	22	26	with	with	ADP
eurjchem-2489	22	27	oxygen	oxygen	NOUN
eurjchem-2489	22	28	.	.	PUNCT
eurjchem-2489	23	1	o	o	NOUN
eurjchem-2489	23	2	-	-	PUNCT
eurjchem-2489	23	3	diphenols	diphenols	PROPN
eurjchem-2489	23	4	exists	exist	VERB
eurjchem-2489	23	5	in	in	ADP
eurjchem-2489	23	6	various	various	ADJ
eurjchem-2489	23	7	plant	plant	NOUN
eurjchem-2489	23	8	and	and	CCONJ
eurjchem-2489	23	9	fungal	fungal	ADJ
eurjchem-2489	23	10	species	specie	NOUN
eurjchem-2489	23	11	[	[	X
eurjchem-2489	23	12	6,7	6,7	NUM
eurjchem-2489	23	13	]	]	PUNCT
eurjchem-2489	23	14	.	.	PUNCT
eurjchem-2489	24	1	in	in	ADP
eurjchem-2489	24	2	plants	plant	NOUN
eurjchem-2489	24	3	,	,	PUNCT
eurjchem-2489	24	4	catecholase	catecholase	NOUN
eurjchem-2489	24	5	plays	play	VERB
eurjchem-2489	24	6	a	a	DET
eurjchem-2489	24	7	crucial	crucial	ADJ
eurjchem-2489	24	8	role	role	NOUN
eurjchem-2489	24	9	in	in	ADP
eurjchem-2489	24	10	the	the	DET
eurjchem-2489	24	11	oxidative	oxidative	ADJ
eurjchem-2489	24	12	transformation	transformation	NOUN
eurjchem-2489	24	13	of	of	ADP
eurjchem-2489	24	14	catechol	catechol	NOUN
eurjchem-2489	24	15	to	to	ADP
eurjchem-2489	24	16	o	o	NOUN
eurjchem-2489	24	17	-	-	NOUN
eurjchem-2489	24	18	quinone	quinone	ADJ
eurjchem-2489	24	19	,	,	PUNCT
eurjchem-2489	24	20	leading	lead	VERB
eurjchem-2489	24	21	to	to	ADP
eurjchem-2489	24	22	the	the	DET
eurjchem-2489	24	23	development	development	NOUN
eurjchem-2489	24	24	of	of	ADP
eurjchem-2489	24	25	brown	brown	ADJ
eurjchem-2489	24	26	-	-	PUNCT
eurjchem-2489	24	27	colored	color	VERB
eurjchem-2489	24	28	melanin	melanin	NOUN
eurjchem-2489	24	29	through	through	ADP
eurjchem-2489	24	30	rapid	rapid	ADJ
eurjchem-2489	24	31	polymerization	polymerization	NOUN
eurjchem-2489	24	32	[	[	X
eurjchem-2489	24	33	8,9	8,9	NUM
eurjchem-2489	24	34	]	]	PUNCT
eurjchem-2489	24	35	.	.	PUNCT
eurjchem-2489	25	1	in	in	ADP
eurjchem-2489	25	2	contrast	contrast	NOUN
eurjchem-2489	25	3	,	,	PUNCT
eurjchem-2489	25	4	the	the	DET
eurjchem-2489	25	5	potential	potential	ADJ
eurjchem-2489	25	6	coordinating	coordinating	NOUN
eurjchem-2489	25	7	characteristics	characteristic	NOUN
eurjchem-2489	25	8	of	of	ADP
eurjchem-2489	25	9	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	25	10	and	and	CCONJ
eurjchem-2489	25	11	its	its	PRON
eurjchem-2489	25	12	coupling	coupling	NOUN
eurjchem-2489	25	13	with	with	ADP
eurjchem-2489	25	14	earth	earth	NOUN
eurjchem-2489	25	15	-	-	PUNCT
eurjchem-2489	25	16	abundant	abundant	ADJ
eurjchem-2489	25	17	metal	metal	NOUN
eurjchem-2489	25	18	complexes	complex	NOUN
eurjchem-2489	25	19	arouse	arouse	VERB
eurjchem-2489	25	20	great	great	ADJ
eurjchem-2489	25	21	promise	promise	NOUN
eurjchem-2489	25	22	in	in	ADP
eurjchem-2489	25	23	the	the	DET
eurjchem-2489	25	24	discovery	discovery	NOUN
eurjchem-2489	25	25	of	of	ADP
eurjchem-2489	25	26	numerous	numerous	ADJ
eurjchem-2489	25	27	applications	application	NOUN
eurjchem-2489	25	28	in	in	ADP
eurjchem-2489	25	29	both	both	CCONJ
eurjchem-2489	25	30	pure	pure	ADJ
eurjchem-2489	25	31	and	and	CCONJ
eurjchem-2489	25	32	applied	apply	VERB
eurjchem-2489	25	33	chemistry	chemistry	NOUN
eurjchem-2489	25	34	[	[	X
eurjchem-2489	25	35	10,11	10,11	NOUN
eurjchem-2489	25	36	]	]	PUNCT
eurjchem-2489	25	37	.	.	PUNCT
eurjchem-2489	26	1	the	the	DET
eurjchem-2489	26	2	literature	literature	PROPN
eurjchem-2489	26	3	survey	survey	NOUN
eurjchem-2489	26	4	shows	show	VERB
eurjchem-2489	26	5	that	that	SCONJ
eurjchem-2489	26	6	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	26	7	has	have	VERB
eurjchem-2489	26	8	antimicrobial	antimicrobial	ADJ
eurjchem-2489	26	9	properties	property	NOUN
eurjchem-2489	26	10	[	[	X
eurjchem-2489	26	11	12	12	NUM
eurjchem-2489	26	12	]	]	PUNCT
eurjchem-2489	26	13	and	and	CCONJ
eurjchem-2489	26	14	is	be	AUX
eurjchem-2489	26	15	known	know	VERB
eurjchem-2489	26	16	as	as	ADP
eurjchem-2489	26	17	a	a	DET
eurjchem-2489	26	18	bidentate	bidentate	NOUN
eurjchem-2489	26	19	coordinator	coordinator	NOUN
eurjchem-2489	26	20	of	of	ADP
eurjchem-2489	26	21	d	d	PROPN
eurjchem-2489	26	22	elements	element	NOUN
eurjchem-2489	26	23	in	in	ADP
eurjchem-2489	26	24	monoanionic	monoanionic	ADJ
eurjchem-2489	26	25	form	form	NOUN
eurjchem-2489	26	26	,	,	PUNCT
eurjchem-2489	26	27	adopting	adopt	VERB
eurjchem-2489	26	28	a	a	DET
eurjchem-2489	26	29	diversified	diversified	ADJ
eurjchem-2489	26	30	coordination	coordination	NOUN
eurjchem-2489	26	31	with	with	ADP
eurjchem-2489	26	32	metal	metal	NOUN
eurjchem-2489	26	33	centers	center	NOUN
eurjchem-2489	26	34	[	[	X
eurjchem-2489	26	35	13	13	NUM
eurjchem-2489	26	36	]	]	PUNCT
eurjchem-2489	26	37	.	.	PUNCT
eurjchem-2489	27	1	in	in	ADP
eurjchem-2489	27	2	the	the	DET
eurjchem-2489	27	3	biological	biological	ADJ
eurjchem-2489	27	4	world	world	NOUN
eurjchem-2489	27	5	,	,	PUNCT
eurjchem-2489	27	6	copper	copper	NOUN
eurjchem-2489	27	7	ions	ion	NOUN
eurjchem-2489	27	8	in	in	ADP
eurjchem-2489	27	9	the	the	DET
eurjchem-2489	27	10	coordination	coordination	NOUN
eurjchem-2489	27	11	of	of	ADP
eurjchem-2489	27	12	various	various	ADJ
eurjchem-2489	27	13	bio	bio	NOUN
eurjchem-2489	27	14	-	-	PUNCT
eurjchem-2489	27	15	ligands	ligand	NOUN
eurjchem-2489	27	16	exist	exist	VERB
eurjchem-2489	27	17	in	in	ADP
eurjchem-2489	27	18	the	the	DET
eurjchem-2489	27	19	functional	functional	ADJ
eurjchem-2489	27	20	core	core	NOUN
eurjchem-2489	27	21	of	of	ADP
eurjchem-2489	27	22	different	different	ADJ
eurjchem-2489	27	23	metalloproteins	metalloprotein	NOUN
eurjchem-2489	27	24	[	[	X
eurjchem-2489	27	25	14,15	14,15	NUM
eurjchem-2489	27	26	]	]	PUNCT
eurjchem-2489	27	27	.	.	PUNCT
eurjchem-2489	28	1	at	at	ADP
eurjchem-2489	28	2	present	present	ADJ
eurjchem-2489	28	3	,	,	PUNCT
eurjchem-2489	28	4	different	different	ADJ
eurjchem-2489	28	5	scientific	scientific	ADJ
eurjchem-2489	28	6	groups	group	NOUN
eurjchem-2489	28	7	are	be	AUX
eurjchem-2489	28	8	actively	actively	ADV
eurjchem-2489	28	9	engrossed	engross	VERB
eurjchem-2489	28	10	in	in	ADP
eurjchem-2489	28	11	the	the	DET
eurjchem-2489	28	12	catalytic	catalytic	ADJ
eurjchem-2489	28	13	oxidation	oxidation	NOUN
eurjchem-2489	28	14	of	of	ADP
eurjchem-2489	28	15	organic	organic	ADJ
eurjchem-2489	28	16	substrates	substrate	NOUN
eurjchem-2489	28	17	based	base	VERB
eurjchem-2489	28	18	on	on	ADP
eurjchem-2489	28	19	synthetic	synthetic	ADJ
eurjchem-2489	28	20	copper(ii)-based	copper(ii)-base	VERB
eurjchem-2489	28	21	coordination	coordination	NOUN
eurjchem-2489	28	22	compounds	compound	NOUN
eurjchem-2489	29	1	[	[	X
eurjchem-2489	29	2	16,17	16,17	NUM
eurjchem-2489	29	3	]	]	PUNCT
eurjchem-2489	29	4	.	.	PUNCT
eurjchem-2489	30	1	focusing	focus	VERB
eurjchem-2489	30	2	on	on	ADP
eurjchem-2489	30	3	the	the	DET
eurjchem-2489	30	4	importance	importance	NOUN
eurjchem-2489	30	5	of	of	ADP
eurjchem-2489	30	6	the	the	DET
eurjchem-2489	30	7	copper	copper	NOUN
eurjchem-2489	30	8	complexes	complex	NOUN
eurjchem-2489	30	9	,	,	PUNCT
eurjchem-2489	30	10	a	a	DET
eurjchem-2489	30	11	newly	newly	ADV
eurjchem-2489	30	12	designed	design	VERB
eurjchem-2489	30	13	copper(ii	copper(ii	NOUN
eurjchem-2489	30	14	)	)	PUNCT
eurjchem-2489	30	15	complex	complex	NOUN
eurjchem-2489	30	16	with	with	ADP
eurjchem-2489	30	17	structural	structural	ADJ
eurjchem-2489	30	18	characterization	characterization	NOUN
eurjchem-2489	30	19	is	be	AUX
eurjchem-2489	30	20	reported	report	VERB
eurjchem-2489	30	21	with	with	ADP
eurjchem-2489	30	22	the	the	DET
eurjchem-2489	30	23	efficient	efficient	ADJ
eurjchem-2489	30	24	biomimicking	biomimicke	VERB
eurjchem-2489	30	25	activities	activity	NOUN
eurjchem-2489	30	26	of	of	ADP
eurjchem-2489	30	27	catecholase	catecholase	NOUN
eurjchem-2489	30	28	in	in	ADP
eurjchem-2489	30	29	this	this	DET
eurjchem-2489	30	30	study	study	NOUN
eurjchem-2489	30	31	.	.	PUNCT
eurjchem-2489	31	1	2	2	X
eurjchem-2489	31	2	.	.	X
eurjchem-2489	31	3	experimental	experimental	ADJ
eurjchem-2489	31	4	2.1	2.1	NUM
eurjchem-2489	31	5	.	.	PUNCT
eurjchem-2489	31	6	preparation	preparation	NOUN
eurjchem-2489	31	7	of	of	ADP
eurjchem-2489	31	8	the	the	DET
eurjchem-2489	31	9	complex	complex	ADJ
eurjchem-2489	31	10	2.1.1	2.1.1	NUM
eurjchem-2489	31	11	.	.	PUNCT
eurjchem-2489	31	12	chemicals	chemical	NOUN
eurjchem-2489	31	13	,	,	PUNCT
eurjchem-2489	31	14	solvents	solvent	NOUN
eurjchem-2489	31	15	,	,	PUNCT
eurjchem-2489	31	16	and	and	CCONJ
eurjchem-2489	31	17	starting	start	VERB
eurjchem-2489	31	18	materials	material	NOUN
eurjchem-2489	31	19	highly	highly	ADV
eurjchem-2489	31	20	pure	pure	ADJ
eurjchem-2489	31	21	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	31	22	(	(	PUNCT
eurjchem-2489	31	23	alfa	alfa	NOUN
eurjchem-2489	31	24	aeser	aeser	PROPN
eurjchem-2489	31	25	,	,	PUNCT
eurjchem-2489	31	26	uk	uk	PROPN
eurjchem-2489	31	27	)	)	PUNCT
eurjchem-2489	31	28	,	,	PUNCT
eurjchem-2489	31	29	morpholine	morpholine	NOUN
eurjchem-2489	31	30	,	,	PUNCT
eurjchem-2489	31	31	p	p	NOUN
eurjchem-2489	31	32	-	-	PUNCT
eurjchem-2489	31	33	cresol	cresol	NOUN
eurjchem-2489	31	34	(	(	PUNCT
eurjchem-2489	31	35	merck	merck	PROPN
eurjchem-2489	31	36	,	,	PUNCT
eurjchem-2489	31	37	india	india	PROPN
eurjchem-2489	31	38	)	)	PUNCT
eurjchem-2489	31	39	,	,	PUNCT
eurjchem-2489	31	40	copper	copper	NOUN
eurjchem-2489	31	41	acetate	acetate	NOUN
eurjchem-2489	31	42	monohydrate	monohydrate	PROPN
eurjchem-2489	31	43	(	(	PUNCT
eurjchem-2489	31	44	thomas	thomas	PROPN
eurjchem-2489	31	45	baker	baker	PROPN
eurjchem-2489	31	46	,	,	PUNCT
eurjchem-2489	31	47	india	india	PROPN
eurjchem-2489	31	48	)	)	PUNCT
eurjchem-2489	31	49	,	,	PUNCT
eurjchem-2489	31	50	and	and	CCONJ
eurjchem-2489	31	51	other	other	ADJ
eurjchem-2489	31	52	chemicals	chemical	NOUN
eurjchem-2489	31	53	of	of	ADP
eurjchem-2489	31	54	analytical	analytical	ADJ
eurjchem-2489	31	55	grade	grade	NOUN
eurjchem-2489	31	56	were	be	AUX
eurjchem-2489	31	57	purchased	purchase	VERB
eurjchem-2489	31	58	from	from	ADP
eurjchem-2489	31	59	commercial	commercial	ADJ
eurjchem-2489	31	60	outlets	outlet	NOUN
eurjchem-2489	31	61	.	.	PUNCT
eurjchem-2489	32	1	abstract	abstract	ADJ
eurjchem-2489	32	2	research	research	NOUN
eurjchem-2489	32	3	article	article	NOUN
eurjchem-2489	32	4	keywords	keyword	VERB
eurjchem-2489	32	5	https://dx.doi.org/10.5155/eurjchem.14.4.499-506.2489	https://dx.doi.org/10.5155/eurjchem.14.4.499-506.2489	PROPN
eurjchem-2489	32	6	https://www.eurjchem.com/	https://www.eurjchem.com/	NOUN
eurjchem-2489	32	7	https://dx.doi.org/10.5155/eurjchem.14.4.499-506.2489	https://dx.doi.org/10.5155/eurjchem.14.4.499-506.2489	PROPN
eurjchem-2489	32	8	mailto:bhaskarbiswas@nbu.ac.in	mailto:bhaskarbiswas@nbu.ac.in	PROPN
eurjchem-2489	32	9	http://www.eurjchem.com/	http://www.eurjchem.com/	PROPN
eurjchem-2489	32	10	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.4.499-506.2489&domain=pdf&date_stamp=2023-12-31	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.14.4.499-506.2489&domain=pdf&date_stamp=2023-12-31	PROPN
eurjchem-2489	32	11	500	500	NUM
eurjchem-2489	32	12	mukherjee	mukherjee	NOUN
eurjchem-2489	32	13	et	et	PROPN
eurjchem-2489	32	14	al	al	PROPN
eurjchem-2489	32	15	.	.	PUNCT
eurjchem-2489	32	16	/	/	SYM
eurjchem-2489	32	17	european	european	PROPN
eurjchem-2489	32	18	journal	journal	PROPN
eurjchem-2489	32	19	of	of	ADP
eurjchem-2489	32	20	chemistry	chemistry	NOUN
eurjchem-2489	32	21	14	14	NUM
eurjchem-2489	32	22	(	(	PUNCT
eurjchem-2489	32	23	4	4	NUM
eurjchem-2489	32	24	)	)	PUNCT
eurjchem-2489	32	25	(	(	PUNCT
eurjchem-2489	32	26	2023	2023	NUM
eurjchem-2489	32	27	)	)	PUNCT
eurjchem-2489	32	28	499	499	NUM
eurjchem-2489	32	29	-	-	SYM
eurjchem-2489	32	30	506	506	NUM
eurjchem-2489	32	31	2023	2023	NUM
eurjchem-2489	32	32	–	–	PUNCT
eurjchem-2489	32	33	european	european	ADJ
eurjchem-2489	32	34	journal	journal	NOUN
eurjchem-2489	32	35	of	of	ADP
eurjchem-2489	32	36	chemistry	chemistry	NOUN
eurjchem-2489	32	37	–	–	PUNCT
eurjchem-2489	32	38	cc	cc	NOUN
eurjchem-2489	32	39	by	by	ADP
eurjchem-2489	32	40	nc	nc	PROPN
eurjchem-2489	32	41	–	–	PUNCT
eurjchem-2489	32	42	doi	doi	NOUN
eurjchem-2489	32	43	:	:	PUNCT
eurjchem-2489	32	44	10.5155	10.5155	NUM
eurjchem-2489	32	45	/	/	SYM
eurjchem-2489	32	46	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	32	47	-	-	PUNCT
eurjchem-2489	32	48	506.2489	506.2489	NUM
eurjchem-2489	32	49	scheme	scheme	NOUN
eurjchem-2489	32	50	1	1	NUM
eurjchem-2489	32	51	.	.	PUNCT
eurjchem-2489	33	1	synthetic	synthetic	ADJ
eurjchem-2489	33	2	route	route	NOUN
eurjchem-2489	33	3	for	for	ADP
eurjchem-2489	33	4	the	the	DET
eurjchem-2489	33	5	copper(ii	copper(ii	NOUN
eurjchem-2489	33	6	)	)	PUNCT
eurjchem-2489	33	7	complex	complex	NOUN
eurjchem-2489	33	8	.	.	PUNCT
eurjchem-2489	34	1	2.1.2	2.1.2	X
eurjchem-2489	34	2	.	.	NOUN
eurjchem-2489	34	3	general	general	ADJ
eurjchem-2489	34	4	procedure	procedure	NOUN
eurjchem-2489	34	5	for	for	ADP
eurjchem-2489	34	6	the	the	DET
eurjchem-2489	34	7	synthesis	synthesis	NOUN
eurjchem-2489	34	8	of	of	ADP
eurjchem-2489	34	9	copper(ii	copper(ii	NOUN
eurjchem-2489	34	10	)	)	PUNCT
eurjchem-2489	34	11	complex	complex	NOUN
eurjchem-2489	34	12	the	the	DET
eurjchem-2489	34	13	cu	cu	PROPN
eurjchem-2489	34	14	complex	complex	NOUN
eurjchem-2489	34	15	(	(	PUNCT
eurjchem-2489	34	16	1	1	X
eurjchem-2489	34	17	)	)	PUNCT
eurjchem-2489	34	18	was	be	AUX
eurjchem-2489	34	19	prepared	prepare	VERB
eurjchem-2489	34	20	by	by	ADP
eurjchem-2489	34	21	an	an	PRON
eurjchem-2489	34	22	in	in	ADP
eurjchem-2489	34	23	situ	situ	ADJ
eurjchem-2489	34	24	reaction	reaction	NOUN
eurjchem-2489	34	25	with	with	ADP
eurjchem-2489	34	26	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	34	27	in	in	ADP
eurjchem-2489	34	28	the	the	DET
eurjchem-2489	34	29	presence	presence	NOUN
eurjchem-2489	34	30	of	of	ADP
eurjchem-2489	34	31	morpholine	morpholine	NOUN
eurjchem-2489	34	32	and	and	CCONJ
eurjchem-2489	34	33	p	p	NOUN
eurjchem-2489	34	34	-	-	PUNCT
eurjchem-2489	34	35	cresol	cresol	NOUN
eurjchem-2489	34	36	with	with	ADP
eurjchem-2489	34	37	the	the	DET
eurjchem-2489	34	38	objective	objective	NOUN
eurjchem-2489	34	39	of	of	ADP
eurjchem-2489	34	40	designing	design	VERB
eurjchem-2489	34	41	a	a	DET
eurjchem-2489	34	42	mannich	mannich	PRON
eurjchem-2489	34	43	base	base	NOUN
eurjchem-2489	34	44	ligand	ligand	NOUN
eurjchem-2489	34	45	.	.	PUNCT
eurjchem-2489	35	1	a	a	DET
eurjchem-2489	35	2	methanolic	methanolic	NOUN
eurjchem-2489	35	3	solution	solution	NOUN
eurjchem-2489	35	4	of	of	ADP
eurjchem-2489	35	5	salicylaldehyde	salicylaldehyde	PROPN
eurjchem-2489	35	6	(	(	PUNCT
eurjchem-2489	35	7	0.122	0.122	NUM
eurjchem-2489	35	8	g	g	NOUN
eurjchem-2489	35	9	,	,	PUNCT
eurjchem-2489	35	10	1	1	NUM
eurjchem-2489	35	11	mmol	mmol	NOUN
eurjchem-2489	35	12	)	)	PUNCT
eurjchem-2489	35	13	,	,	PUNCT
eurjchem-2489	35	14	morpholine	morpholine	NOUN
eurjchem-2489	35	15	(	(	PUNCT
eurjchem-2489	35	16	0.087	0.087	NUM
eurjchem-2489	35	17	g	g	NOUN
eurjchem-2489	35	18	,	,	PUNCT
eurjchem-2489	35	19	1	1	NUM
eurjchem-2489	35	20	mmol	mmol	NOUN
eurjchem-2489	35	21	)	)	PUNCT
eurjchem-2489	35	22	and	and	CCONJ
eurjchem-2489	35	23	p	p	X
eurjchem-2489	35	24	-	-	PUNCT
eurjchem-2489	35	25	cresol	cresol	NOUN
eurjchem-2489	35	26	(	(	PUNCT
eurjchem-2489	35	27	0.108	0.108	NUM
eurjchem-2489	35	28	g	g	NOUN
eurjchem-2489	35	29	,	,	PUNCT
eurjchem-2489	35	30	1	1	NUM
eurjchem-2489	35	31	mmol	mmol	NOUN
eurjchem-2489	35	32	)	)	PUNCT
eurjchem-2489	35	33	was	be	AUX
eurjchem-2489	35	34	taken	take	VERB
eurjchem-2489	35	35	in	in	ADP
eurjchem-2489	35	36	a	a	DET
eurjchem-2489	35	37	100	100	NUM
eurjchem-2489	35	38	ml	ml	NUM
eurjchem-2489	35	39	two	two	NUM
eurjchem-2489	35	40	-	-	PUNCT
eurjchem-2489	35	41	neck	neck	NOUN
eurjchem-2489	35	42	round	round	ADJ
eurjchem-2489	35	43	-	-	PUNCT
eurjchem-2489	35	44	bottom	bottom	NOUN
eurjchem-2489	35	45	flask	flask	NOUN
eurjchem-2489	35	46	and	and	CCONJ
eurjchem-2489	35	47	refluxed	refluxe	VERB
eurjchem-2489	35	48	for	for	ADP
eurjchem-2489	35	49	6	6	NUM
eurjchem-2489	35	50	hours	hour	NOUN
eurjchem-2489	35	51	.	.	PUNCT
eurjchem-2489	36	1	subsequently	subsequently	ADV
eurjchem-2489	36	2	,	,	PUNCT
eurjchem-2489	36	3	a	a	DET
eurjchem-2489	36	4	solution	solution	NOUN
eurjchem-2489	36	5	of	of	ADP
eurjchem-2489	36	6	cu(oac)2	cu(oac)2	PRON
eurjchem-2489	36	7	(	(	PUNCT
eurjchem-2489	36	8	0.199	0.199	NUM
eurjchem-2489	36	9	g	g	NOUN
eurjchem-2489	36	10	,	,	PUNCT
eurjchem-2489	36	11	1	1	NUM
eurjchem-2489	36	12	mmol	mmol	NOUN
eurjchem-2489	36	13	)	)	PUNCT
eurjchem-2489	36	14	in	in	ADP
eurjchem-2489	36	15	ch3oh	ch3oh	PROPN
eurjchem-2489	36	16	was	be	AUX
eurjchem-2489	36	17	added	add	VERB
eurjchem-2489	36	18	to	to	ADP
eurjchem-2489	36	19	the	the	DET
eurjchem-2489	36	20	reaction	reaction	NOUN
eurjchem-2489	36	21	mixture	mixture	NOUN
eurjchem-2489	36	22	and	and	CCONJ
eurjchem-2489	36	23	the	the	DET
eurjchem-2489	36	24	whole	whole	ADJ
eurjchem-2489	36	25	solution	solution	NOUN
eurjchem-2489	36	26	was	be	AUX
eurjchem-2489	36	27	refluxed	refluxe	VERB
eurjchem-2489	36	28	again	again	ADV
eurjchem-2489	36	29	for	for	ADP
eurjchem-2489	36	30	3	3	NUM
eurjchem-2489	36	31	hours	hour	NOUN
eurjchem-2489	36	32	.	.	PUNCT
eurjchem-2489	37	1	when	when	SCONJ
eurjchem-2489	37	2	the	the	DET
eurjchem-2489	37	3	reaction	reaction	NOUN
eurjchem-2489	37	4	mixture	mixture	NOUN
eurjchem-2489	37	5	was	be	AUX
eurjchem-2489	37	6	cooled	cool	VERB
eurjchem-2489	37	7	for	for	ADP
eurjchem-2489	37	8	an	an	DET
eurjchem-2489	37	9	hour	hour	NOUN
eurjchem-2489	37	10	,	,	PUNCT
eurjchem-2489	37	11	the	the	DET
eurjchem-2489	37	12	crystalline	crystalline	NOUN
eurjchem-2489	37	13	copper	copper	NOUN
eurjchem-2489	37	14	complex	complex	NOUN
eurjchem-2489	37	15	was	be	AUX
eurjchem-2489	37	16	separated	separate	VERB
eurjchem-2489	37	17	from	from	ADP
eurjchem-2489	37	18	the	the	DET
eurjchem-2489	37	19	reaction	reaction	NOUN
eurjchem-2489	37	20	mixture	mixture	NOUN
eurjchem-2489	37	21	.	.	PUNCT
eurjchem-2489	38	1	the	the	DET
eurjchem-2489	38	2	crystalline	crystalline	NOUN
eurjchem-2489	38	3	product	product	NOUN
eurjchem-2489	38	4	was	be	AUX
eurjchem-2489	38	5	collected	collect	VERB
eurjchem-2489	38	6	and	and	CCONJ
eurjchem-2489	38	7	stored	store	VERB
eurjchem-2489	38	8	in	in	ADP
eurjchem-2489	38	9	a	a	DET
eurjchem-2489	38	10	vacuum	vacuum	NOUN
eurjchem-2489	38	11	desiccator	desiccator	NOUN
eurjchem-2489	38	12	.	.	PUNCT
eurjchem-2489	39	1	bis-(2	bis-(2	NOUN
eurjchem-2489	39	2	-	-	PUNCT
eurjchem-2489	39	3	formylphenolato)copper(ii	formylphenolato)copper(ii	NOUN
eurjchem-2489	39	4	)	)	PUNCT
eurjchem-2489	39	5	4	4	NUM
eurjchem-2489	39	6	-	-	PUNCT
eurjchem-2489	39	7	methylphenol	methylphenol	NOUN
eurjchem-2489	39	8	(	(	PUNCT
eurjchem-2489	39	9	1	1	NUM
eurjchem-2489	39	10	):	):	PUNCT
eurjchem-2489	39	11	color	color	NOUN
eurjchem-2489	39	12	:	:	PUNCT
eurjchem-2489	39	13	greenish	greenish	ADJ
eurjchem-2489	39	14	brown	brown	NOUN
eurjchem-2489	39	15	.	.	PUNCT
eurjchem-2489	40	1	yield	yield	NOUN
eurjchem-2489	40	2	:	:	PUNCT
eurjchem-2489	40	3	86.4	86.4	NUM
eurjchem-2489	40	4	%	%	NOUN
eurjchem-2489	40	5	.	.	PUNCT
eurjchem-2489	41	1	ft	ft	PROPN
eurjchem-2489	41	2	-	-	PUNCT
eurjchem-2489	41	3	ir	ir	PROPN
eurjchem-2489	41	4	(	(	PUNCT
eurjchem-2489	41	5	kbr	kbr	PROPN
eurjchem-2489	41	6	,	,	PUNCT
eurjchem-2489	41	7	ν	ν	PROPN
eurjchem-2489	41	8	,	,	PUNCT
eurjchem-2489	41	9	cm-1	cm-1	NUM
eurjchem-2489	41	10	):	):	PUNCT
eurjchem-2489	41	11	3456	3456	NUM
eurjchem-2489	41	12	(	(	PUNCT
eurjchem-2489	41	13	oh	oh	INTJ
eurjchem-2489	41	14	,	,	PUNCT
eurjchem-2489	41	15	phenolic	phenolic	NOUN
eurjchem-2489	41	16	-	-	PUNCT
eurjchem-2489	41	17	oh	oh	NOUN
eurjchem-2489	41	18	)	)	PUNCT
eurjchem-2489	41	19	,	,	PUNCT
eurjchem-2489	41	20	1605	1605	NUM
eurjchem-2489	41	21	(	(	PUNCT
eurjchem-2489	41	22	c	c	NOUN
eurjchem-2489	41	23	=	=	SYM
eurjchem-2489	41	24	o	o	NOUN
eurjchem-2489	41	25	,	,	PUNCT
eurjchem-2489	41	26	(	(	PUNCT
eurjchem-2489	41	27	aldehyde	aldehyde	NOUN
eurjchem-2489	41	28	)	)	PUNCT
eurjchem-2489	41	29	.	.	PUNCT
eurjchem-2489	42	1	anal	anal	PROPN
eurjchem-2489	42	2	.	.	PUNCT
eurjchem-2489	42	3	calcd	calcd	NOUN
eurjchem-2489	42	4	.	.	PUNCT
eurjchem-2489	43	1	for	for	ADP
eurjchem-2489	43	2	c21h18o5cu	c21h18o5cu	NOUN
eurjchem-2489	43	3	(	(	PUNCT
eurjchem-2489	43	4	1	1	NUM
eurjchem-2489	43	5	):	):	PUNCT
eurjchem-2489	43	6	c	c	NOUN
eurjchem-2489	43	7	,	,	PUNCT
eurjchem-2489	43	8	60.94	60.94	NUM
eurjchem-2489	43	9	;	;	PUNCT
eurjchem-2489	43	10	h	h	NOUN
eurjchem-2489	43	11	,	,	PUNCT
eurjchem-2489	43	12	4.38	4.38	NUM
eurjchem-2489	43	13	;	;	PUNCT
eurjchem-2489	43	14	o	o	NOUN
eurjchem-2489	43	15	,	,	PUNCT
eurjchem-2489	43	16	19.33	19.33	NUM
eurjchem-2489	43	17	;	;	PUNCT
eurjchem-2489	43	18	found	find	VERB
eurjchem-2489	43	19	:	:	PUNCT
eurjchem-2489	43	20	c	c	X
eurjchem-2489	43	21	,	,	PUNCT
eurjchem-2489	43	22	60.96	60.96	NUM
eurjchem-2489	43	23	;	;	PUNCT
eurjchem-2489	43	24	h	h	NOUN
eurjchem-2489	43	25	,	,	PUNCT
eurjchem-2489	43	26	4.36	4.36	NUM
eurjchem-2489	43	27	;	;	PUNCT
eurjchem-2489	43	28	o	o	NOUN
eurjchem-2489	43	29	,	,	PUNCT
eurjchem-2489	43	30	19.31	19.31	NUM
eurjchem-2489	43	31	%	%	NOUN
eurjchem-2489	43	32	.	.	PUNCT
eurjchem-2489	44	1	uv	uv	NOUN
eurjchem-2489	44	2	/	/	SYM
eurjchem-2489	44	3	vis	vis	X
eurjchem-2489	44	4	(	(	PUNCT
eurjchem-2489	44	5	chcl3	chcl3	PROPN
eurjchem-2489	44	6	,	,	PUNCT
eurjchem-2489	44	7	λmax	λmax	NOUN
eurjchem-2489	44	8	,	,	PUNCT
eurjchem-2489	44	9	nm	nm	NOUN
eurjchem-2489	44	10	,	,	PUNCT
eurjchem-2489	44	11	(	(	PUNCT
eurjchem-2489	44	12	ε	ε	PROPN
eurjchem-2489	44	13	)	)	PUNCT
eurjchem-2489	44	14	):	):	PUNCT
eurjchem-2489	44	15	315	315	NUM
eurjchem-2489	44	16	(	(	PUNCT
eurjchem-2489	44	17	0.149	0.149	NUM
eurjchem-2489	44	18	)	)	PUNCT
eurjchem-2489	44	19	,	,	PUNCT
eurjchem-2489	44	20	382	382	NUM
eurjchem-2489	44	21	(	(	PUNCT
eurjchem-2489	44	22	0.09	0.09	NUM
eurjchem-2489	44	23	)	)	PUNCT
eurjchem-2489	44	24	.	.	PUNCT
eurjchem-2489	45	1	2.2	2.2	NUM
eurjchem-2489	45	2	.	.	PUNCT
eurjchem-2489	45	3	instrumentation	instrumentation	NOUN
eurjchem-2489	45	4	the	the	DET
eurjchem-2489	45	5	ir	ir	PROPN
eurjchem-2489	45	6	spectrum	spectrum	NOUN
eurjchem-2489	45	7	of	of	ADP
eurjchem-2489	45	8	the	the	DET
eurjchem-2489	45	9	copper	copper	NOUN
eurjchem-2489	45	10	complex	complex	NOUN
eurjchem-2489	45	11	was	be	AUX
eurjchem-2489	45	12	recorded	record	VERB
eurjchem-2489	45	13	in	in	ADP
eurjchem-2489	45	14	400	400	NUM
eurjchem-2489	45	15	-	-	SYM
eurjchem-2489	45	16	3600	3600	NUM
eurjchem-2489	45	17	cm-1	cm-1	VERB
eurjchem-2489	45	18	using	use	VERB
eurjchem-2489	45	19	an	an	DET
eurjchem-2489	45	20	ftir-8400s	ftir-8400s	ADJ
eurjchem-2489	45	21	shimadzu	shimadzu	ADJ
eurjchem-2489	45	22	spectrometer	spectrometer	NOUN
eurjchem-2489	45	23	(	(	PUNCT
eurjchem-2489	45	24	shimadzu	shimadzu	PROPN
eurjchem-2489	45	25	,	,	PUNCT
eurjchem-2489	45	26	kyoto	kyoto	PROPN
eurjchem-2489	45	27	,	,	PUNCT
eurjchem-2489	45	28	japan	japan	PROPN
eurjchem-2489	45	29	)	)	PUNCT
eurjchem-2489	45	30	.	.	PUNCT
eurjchem-2489	46	1	a	a	DET
eurjchem-2489	46	2	hitachi	hitachi	PROPN
eurjchem-2489	46	3	u-2910	u-2910	PROPN
eurjchem-2489	46	4	uv	uv	NOUN
eurjchem-2489	46	5	-	-	PUNCT
eurjchem-2489	46	6	vis	vis	X
eurjchem-2489	46	7	spectrophotometer	spectrophotometer	X
eurjchem-2489	46	8	(	(	PUNCT
eurjchem-2489	46	9	hitachi	hitachi	PROPN
eurjchem-2489	46	10	,	,	PUNCT
eurjchem-2489	46	11	japan	japan	PROPN
eurjchem-2489	46	12	)	)	PUNCT
eurjchem-2489	46	13	was	be	AUX
eurjchem-2489	46	14	used	use	VERB
eurjchem-2489	46	15	to	to	PART
eurjchem-2489	46	16	measure	measure	VERB
eurjchem-2489	46	17	the	the	DET
eurjchem-2489	46	18	uv	uv	NOUN
eurjchem-2489	46	19	-	-	PUNCT
eurjchem-2489	46	20	vis	vis	X
eurjchem-2489	46	21	spectra	spectra	PROPN
eurjchem-2489	46	22	.	.	PUNCT
eurjchem-2489	47	1	a	a	DET
eurjchem-2489	47	2	perkinelmer	perkinelmer	NOUN
eurjchem-2489	47	3	2400	2400	NUM
eurjchem-2489	47	4	chn	chn	PROPN
eurjchem-2489	47	5	microanalyzer	microanalyzer	NOUN
eurjchem-2489	47	6	(	(	PUNCT
eurjchem-2489	47	7	perkin	perkin	PROPN
eurjchem-2489	47	8	elmer	elmer	PROPN
eurjchem-2489	47	9	,	,	PUNCT
eurjchem-2489	47	10	waltham	waltham	PROPN
eurjchem-2489	47	11	,	,	PUNCT
eurjchem-2489	47	12	usa	usa	PROPN
eurjchem-2489	47	13	)	)	PUNCT
eurjchem-2489	47	14	was	be	AUX
eurjchem-2489	47	15	used	use	VERB
eurjchem-2489	47	16	to	to	PART
eurjchem-2489	47	17	record	record	VERB
eurjchem-2489	47	18	the	the	DET
eurjchem-2489	47	19	elemental	elemental	ADJ
eurjchem-2489	47	20	analysis	analysis	NOUN
eurjchem-2489	47	21	.	.	PUNCT
eurjchem-2489	48	1	the	the	DET
eurjchem-2489	48	2	electroanalytical	electroanalytical	ADJ
eurjchem-2489	48	3	instrument	instrument	NOUN
eurjchem-2489	48	4	,	,	PUNCT
eurjchem-2489	48	5	pg	pg	VERB
eurjchem-2489	48	6	lyte1.0	lyte1.0	PROPN
eurjchem-2489	48	7	was	be	AUX
eurjchem-2489	48	8	used	use	VERB
eurjchem-2489	48	9	to	to	PART
eurjchem-2489	48	10	recode	recode	VERB
eurjchem-2489	48	11	the	the	DET
eurjchem-2489	48	12	cyclic	cyclic	ADJ
eurjchem-2489	48	13	voltammograms	voltammogram	NOUN
eurjchem-2489	48	14	in	in	ADP
eurjchem-2489	48	15	acetonitrile	acetonitrile	NOUN
eurjchem-2489	48	16	.	.	PUNCT
eurjchem-2489	49	1	the	the	DET
eurjchem-2489	49	2	platinum	platinum	NOUN
eurjchem-2489	49	3	working	work	VERB
eurjchem-2489	49	4	electrode	electrode	NOUN
eurjchem-2489	49	5	,	,	PUNCT
eurjchem-2489	49	6	platinum	platinum	NOUN
eurjchem-2489	49	7	auxiliary	auxiliary	ADJ
eurjchem-2489	49	8	electrode	electrode	NOUN
eurjchem-2489	49	9	,	,	PUNCT
eurjchem-2489	49	10	and	and	CCONJ
eurjchem-2489	49	11	ag	ag	PROPN
eurjchem-2489	49	12	/	/	SYM
eurjchem-2489	49	13	agcl	agcl	NOUN
eurjchem-2489	49	14	reference	reference	NOUN
eurjchem-2489	49	15	electrode	electrode	NOUN
eurjchem-2489	49	16	were	be	AUX
eurjchem-2489	49	17	used	use	VERB
eurjchem-2489	49	18	for	for	ADP
eurjchem-2489	49	19	the	the	DET
eurjchem-2489	49	20	measurements	measurement	NOUN
eurjchem-2489	49	21	.	.	PUNCT
eurjchem-2489	50	1	2.3	2.3	NUM
eurjchem-2489	50	2	.	.	PUNCT
eurjchem-2489	51	1	x	x	X
eurjchem-2489	51	2	-	-	PUNCT
eurjchem-2489	51	3	ray	ray	NOUN
eurjchem-2489	51	4	diffraction	diffraction	NOUN
eurjchem-2489	51	5	study	study	NOUN
eurjchem-2489	51	6	x	x	NOUN
eurjchem-2489	51	7	-	-	NOUN
eurjchem-2489	51	8	ray	ray	NOUN
eurjchem-2489	51	9	crystallography	crystallography	NOUN
eurjchem-2489	51	10	analysis	analysis	NOUN
eurjchem-2489	51	11	of	of	ADP
eurjchem-2489	51	12	the	the	DET
eurjchem-2489	51	13	cu	cu	PROPN
eurjchem-2489	51	14	complex	complex	NOUN
eurjchem-2489	51	15	was	be	AUX
eurjchem-2489	51	16	performed	perform	VERB
eurjchem-2489	51	17	on	on	ADP
eurjchem-2489	51	18	a	a	DET
eurjchem-2489	51	19	rigaku	rigaku	NOUN
eurjchem-2489	51	20	xtalab	xtalab	NOUN
eurjchem-2489	51	21	mini	mini	ADJ
eurjchem-2489	51	22	diffractometer	diffractometer	NOUN
eurjchem-2489	51	23	equipped	equip	VERB
eurjchem-2489	51	24	with	with	ADP
eurjchem-2489	51	25	a	a	DET
eurjchem-2489	51	26	mercury	mercury	NOUN
eurjchem-2489	51	27	375r	375r	PROPN
eurjchem-2489	51	28	(	(	PUNCT
eurjchem-2489	51	29	2×2	2×2	NUM
eurjchem-2489	51	30	bin	bin	NOUN
eurjchem-2489	51	31	mode	mode	NOUN
eurjchem-2489	51	32	)	)	PUNCT
eurjchem-2489	51	33	ccd	ccd	NOUN
eurjchem-2489	51	34	detector	detector	NOUN
eurjchem-2489	51	35	.	.	PUNCT
eurjchem-2489	52	1	data	datum	NOUN
eurjchem-2489	52	2	were	be	AUX
eurjchem-2489	52	3	collected	collect	VERB
eurjchem-2489	52	4	with	with	ADP
eurjchem-2489	52	5	graphite	graphite	NOUN
eurjchem-2489	52	6	monochromated	monochromate	VERB
eurjchem-2489	52	7	mo	mo	PROPN
eurjchem-2489	52	8	-	-	ADJ
eurjchem-2489	52	9	kα	kα	PROPN
eurjchem-2489	52	10	radiation	radiation	NOUN
eurjchem-2489	52	11	(	(	PUNCT
eurjchem-2489	52	12	λ	λ	X
eurjchem-2489	52	13	=	=	SYM
eurjchem-2489	52	14	0.71073	0.71073	NUM
eurjchem-2489	52	15	å	å	NOUN
eurjchem-2489	52	16	)	)	PUNCT
eurjchem-2489	52	17	at	at	ADP
eurjchem-2489	52	18	293(2	293(2	NUM
eurjchem-2489	52	19	)	)	PUNCT
eurjchem-2489	52	20	k	k	PROPN
eurjchem-2489	52	21	using	use	VERB
eurjchem-2489	52	22	ω	ω	NUM
eurjchem-2489	52	23	scans	scan	NOUN
eurjchem-2489	52	24	.	.	PUNCT
eurjchem-2489	53	1	data	datum	NOUN
eurjchem-2489	53	2	were	be	AUX
eurjchem-2489	53	3	reduced	reduce	VERB
eurjchem-2489	53	4	using	use	VERB
eurjchem-2489	53	5	crysalispro	crysalispro	ADJ
eurjchem-2489	53	6	1.171.39.35c	1.171.39.35c	NUM
eurjchem-2489	54	1	[	[	X
eurjchem-2489	54	2	18	18	NUM
eurjchem-2489	54	3	]	]	PUNCT
eurjchem-2489	54	4	and	and	CCONJ
eurjchem-2489	54	5	the	the	DET
eurjchem-2489	54	6	determination	determination	NOUN
eurjchem-2489	54	7	of	of	ADP
eurjchem-2489	54	8	the	the	DET
eurjchem-2489	54	9	space	space	NOUN
eurjchem-2489	54	10	group	group	NOUN
eurjchem-2489	54	11	was	be	AUX
eurjchem-2489	54	12	made	make	VERB
eurjchem-2489	54	13	using	use	VERB
eurjchem-2489	54	14	olex2	olex2	PROPN
eurjchem-2489	54	15	.	.	PUNCT
eurjchem-2489	55	1	the	the	DET
eurjchem-2489	55	2	structure	structure	NOUN
eurjchem-2489	55	3	was	be	AUX
eurjchem-2489	55	4	resolved	resolve	VERB
eurjchem-2489	55	5	using	use	VERB
eurjchem-2489	55	6	the	the	DET
eurjchem-2489	55	7	dual	dual	ADJ
eurjchem-2489	55	8	space	space	NOUN
eurjchem-2489	55	9	method	method	NOUN
eurjchem-2489	55	10	using	use	VERB
eurjchem-2489	55	11	shelxt-2015	shelxt-2015	NOUN
eurjchem-2489	55	12	[	[	X
eurjchem-2489	55	13	19	19	NUM
eurjchem-2489	55	14	]	]	PUNCT
eurjchem-2489	55	15	and	and	CCONJ
eurjchem-2489	55	16	refined	refined	ADJ
eurjchem-2489	55	17	using	use	VERB
eurjchem-2489	55	18	full	full	ADJ
eurjchem-2489	55	19	-	-	PUNCT
eurjchem-2489	55	20	matrix	matrix	NOUN
eurjchem-2489	55	21	least	least	ADJ
eurjchem-2489	55	22	squares	square	NOUN
eurjchem-2489	55	23	procedures	procedure	NOUN
eurjchem-2489	55	24	using	use	VERB
eurjchem-2489	55	25	the	the	DET
eurjchem-2489	55	26	shelxl-2015	shelxl-2015	NOUN
eurjchem-2489	55	27	[	[	X
eurjchem-2489	55	28	20	20	NUM
eurjchem-2489	55	29	]	]	PUNCT
eurjchem-2489	55	30	software	software	NOUN
eurjchem-2489	55	31	package	package	NOUN
eurjchem-2489	55	32	through	through	ADP
eurjchem-2489	55	33	the	the	DET
eurjchem-2489	55	34	olex2	olex2	PROPN
eurjchem-2489	55	35	suite	suite	NOUN
eurjchem-2489	55	36	[	[	X
eurjchem-2489	55	37	21	21	NUM
eurjchem-2489	55	38	]	]	PUNCT
eurjchem-2489	55	39	.	.	PUNCT
eurjchem-2489	56	1	2.4	2.4	NUM
eurjchem-2489	56	2	.	.	PUNCT
eurjchem-2489	57	1	catecholase	catecholase	NOUN
eurjchem-2489	57	2	activity	activity	NOUN
eurjchem-2489	57	3	of	of	ADP
eurjchem-2489	57	4	the	the	DET
eurjchem-2489	57	5	copper(ii	copper(ii	NOUN
eurjchem-2489	57	6	)	)	PUNCT
eurjchem-2489	57	7	complex	complex	NOUN
eurjchem-2489	57	8	the	the	DET
eurjchem-2489	57	9	catecholase	catecholase	NOUN
eurjchem-2489	57	10	activity	activity	NOUN
eurjchem-2489	57	11	was	be	AUX
eurjchem-2489	57	12	studied	study	VERB
eurjchem-2489	57	13	by	by	ADP
eurjchem-2489	57	14	treatment	treatment	NOUN
eurjchem-2489	57	15	of	of	ADP
eurjchem-2489	57	16	1×10−4	1×10−4	PROPN
eurjchem-2489	57	17	m	m	NOUN
eurjchem-2489	57	18	solution	solution	NOUN
eurjchem-2489	57	19	of	of	ADP
eurjchem-2489	57	20	the	the	DET
eurjchem-2489	57	21	cu(ii	cu(ii	PROPN
eurjchem-2489	57	22	)	)	PUNCT
eurjchem-2489	57	23	complex	complex	NOUN
eurjchem-2489	57	24	with	with	ADP
eurjchem-2489	57	25	1×10−3	1×10−3	PROPN
eurjchem-2489	57	26	m	m	PROPN
eurjchem-2489	57	27	3,5	3,5	NUM
eurjchem-2489	57	28	-	-	PUNCT
eurjchem-2489	57	29	di	di	NOUN
eurjchem-2489	57	30	-	-	PUNCT
eurjchem-2489	57	31	tertbutylcatechol	tertbutylcatechol	NOUN
eurjchem-2489	57	32	(	(	PUNCT
eurjchem-2489	57	33	dtbc	dtbc	PROPN
eurjchem-2489	57	34	)	)	PUNCT
eurjchem-2489	57	35	in	in	ADP
eurjchem-2489	57	36	acetonitrile	acetonitrile	PROPN
eurjchem-2489	57	37	(	(	PUNCT
eurjchem-2489	57	38	acn	acn	PROPN
eurjchem-2489	57	39	)	)	PUNCT
eurjchem-2489	57	40	under	under	ADP
eurjchem-2489	57	41	an	an	DET
eurjchem-2489	57	42	aerobic	aerobic	ADJ
eurjchem-2489	57	43	atmosphere	atmosphere	NOUN
eurjchem-2489	57	44	.	.	PUNCT
eurjchem-2489	58	1	the	the	DET
eurjchem-2489	58	2	change	change	NOUN
eurjchem-2489	58	3	in	in	ADP
eurjchem-2489	58	4	absorbance	absorbance	NOUN
eurjchem-2489	58	5	with	with	ADP
eurjchem-2489	58	6	wavelength	wavelength	NOUN
eurjchem-2489	58	7	(	(	PUNCT
eurjchem-2489	58	8	wavelength	wavelength	NOUN
eurjchem-2489	58	9	scans	scan	NOUN
eurjchem-2489	58	10	)	)	PUNCT
eurjchem-2489	58	11	of	of	ADP
eurjchem-2489	58	12	the	the	DET
eurjchem-2489	58	13	solution	solution	NOUN
eurjchem-2489	58	14	was	be	AUX
eurjchem-2489	58	15	monitored	monitor	VERB
eurjchem-2489	58	16	spectrophotometrically	spectrophotometrically	ADV
eurjchem-2489	58	17	within	within	ADP
eurjchem-2489	58	18	300	300	NUM
eurjchem-2489	58	19	-	-	SYM
eurjchem-2489	58	20	800	800	NUM
eurjchem-2489	58	21	nm	nm	NOUN
eurjchem-2489	58	22	at	at	ADP
eurjchem-2489	58	23	an	an	DET
eurjchem-2489	58	24	interval	interval	NOUN
eurjchem-2489	58	25	of	of	ADP
eurjchem-2489	58	26	5	5	NUM
eurjchem-2489	58	27	minutes	minute	NOUN
eurjchem-2489	58	28	[	[	X
eurjchem-2489	58	29	22	22	NUM
eurjchem-2489	58	30	]	]	PUNCT
eurjchem-2489	58	31	.	.	PUNCT
eurjchem-2489	59	1	kinetic	kinetic	ADJ
eurjchem-2489	59	2	experiments	experiment	NOUN
eurjchem-2489	59	3	were	be	AUX
eurjchem-2489	59	4	also	also	ADV
eurjchem-2489	59	5	performed	perform	VERB
eurjchem-2489	59	6	with	with	ADP
eurjchem-2489	59	7	a	a	DET
eurjchem-2489	59	8	spectrophotometer	spectrophotometer	NOUN
eurjchem-2489	59	9	to	to	PART
eurjchem-2489	59	10	determine	determine	VERB
eurjchem-2489	59	11	the	the	DET
eurjchem-2489	59	12	efficiency	efficiency	NOUN
eurjchem-2489	59	13	of	of	ADP
eurjchem-2489	59	14	catalytic	catalytic	ADJ
eurjchem-2489	59	15	oxidation	oxidation	NOUN
eurjchem-2489	59	16	of	of	ADP
eurjchem-2489	59	17	dtbc	dtbc	PROPN
eurjchem-2489	59	18	by	by	ADP
eurjchem-2489	59	19	the	the	DET
eurjchem-2489	59	20	cu(ii	cu(ii	PROPN
eurjchem-2489	59	21	)	)	PUNCT
eurjchem-2489	59	22	complex	complex	NOUN
eurjchem-2489	59	23	in	in	ADP
eurjchem-2489	59	24	acn	acn	PROPN
eurjchem-2489	60	1	[	[	X
eurjchem-2489	60	2	22	22	NUM
eurjchem-2489	60	3	]	]	PUNCT
eurjchem-2489	60	4	.	.	PUNCT
eurjchem-2489	61	1	the	the	DET
eurjchem-2489	61	2	kinetics	kinetic	NOUN
eurjchem-2489	61	3	of	of	ADP
eurjchem-2489	61	4	the	the	DET
eurjchem-2489	61	5	catalytic	catalytic	ADJ
eurjchem-2489	61	6	transformation	transformation	NOUN
eurjchem-2489	61	7	of	of	ADP
eurjchem-2489	61	8	3,5	3,5	NUM
eurjchem-2489	61	9	-	-	PUNCT
eurjchem-2489	61	10	dtbc	dtbc	NOUN
eurjchem-2489	61	11	were	be	AUX
eurjchem-2489	61	12	performed	perform	VERB
eurjchem-2489	61	13	following	follow	VERB
eurjchem-2489	61	14	the	the	DET
eurjchem-2489	61	15	initial	initial	ADJ
eurjchem-2489	61	16	rate	rate	NOUN
eurjchem-2489	61	17	method	method	NOUN
eurjchem-2489	61	18	.	.	PUNCT
eurjchem-2489	62	1	catalytic	catalytic	ADJ
eurjchem-2489	62	2	oxidation	oxidation	NOUN
eurjchem-2489	62	3	was	be	AUX
eurjchem-2489	62	4	monitored	monitor	VERB
eurjchem-2489	62	5	as	as	ADP
eurjchem-2489	62	6	a	a	DET
eurjchem-2489	62	7	function	function	NOUN
eurjchem-2489	62	8	of	of	ADP
eurjchem-2489	62	9	time	time	NOUN
eurjchem-2489	62	10	with	with	ADP
eurjchem-2489	62	11	the	the	DET
eurjchem-2489	62	12	growth	growth	NOUN
eurjchem-2489	62	13	of	of	ADP
eurjchem-2489	62	14	obenzoquinone	obenzoquinone	ADJ
eurjchem-2489	62	15	species	specie	NOUN
eurjchem-2489	62	16	at	at	ADP
eurjchem-2489	62	17	400	400	NUM
eurjchem-2489	62	18	nm	nm	NOUN
eurjchem-2489	62	19	[	[	X
eurjchem-2489	62	20	23	23	NUM
eurjchem-2489	62	21	]	]	PUNCT
eurjchem-2489	62	22	.	.	PUNCT
eurjchem-2489	63	1	~1×10–3	~1×10–3	PROPN
eurjchem-2489	63	2	m	m	VERB
eurjchem-2489	63	3	solution	solution	NOUN
eurjchem-2489	63	4	of	of	ADP
eurjchem-2489	63	5	the	the	DET
eurjchem-2489	63	6	copper	copper	NOUN
eurjchem-2489	63	7	complex	complex	NOUN
eurjchem-2489	63	8	was	be	AUX
eurjchem-2489	63	9	mixed	mix	VERB
eurjchem-2489	63	10	with	with	ADP
eurjchem-2489	63	11	a	a	DET
eurjchem-2489	63	12	1×10–2	1×10–2	NUM
eurjchem-2489	63	13	m	m	NOUN
eurjchem-2489	63	14	solution	solution	NOUN
eurjchem-2489	63	15	of	of	ADP
eurjchem-2489	63	16	dtbc	dtbc	PROPN
eurjchem-2489	63	17	and	and	CCONJ
eurjchem-2489	63	18	the	the	DET
eurjchem-2489	63	19	conversion	conversion	NOUN
eurjchem-2489	63	20	of	of	ADP
eurjchem-2489	63	21	dtbc	dtbc	PROPN
eurjchem-2489	63	22	to	to	ADP
eurjchem-2489	63	23	3,5	3,5	NUM
eurjchem-2489	63	24	-	-	PUNCT
eurjchem-2489	63	25	di	di	NOUN
eurjchem-2489	63	26	-	-	PUNCT
eurjchem-2489	63	27	tert	tert	NOUN
eurjchem-2489	63	28	-	-	PUNCT
eurjchem-2489	63	29	o	o	NOUN
eurjchem-2489	63	30	-	-	NOUN
eurjchem-2489	63	31	butylquinone	butylquinone	NOUN
eurjchem-2489	63	32	was	be	AUX
eurjchem-2489	63	33	monitored	monitor	VERB
eurjchem-2489	63	34	by	by	ADP
eurjchem-2489	63	35	time	time	NOUN
eurjchem-2489	63	36	scan	scan	NOUN
eurjchem-2489	63	37	at	at	ADP
eurjchem-2489	63	38	a	a	DET
eurjchem-2489	63	39	wavelength	wavelength	NOUN
eurjchem-2489	63	40	of	of	ADP
eurjchem-2489	63	41	400	400	NUM
eurjchem-2489	63	42	nm	nm	NOUN
eurjchem-2489	63	43	in	in	ADP
eurjchem-2489	63	44	acn	acn	PROPN
eurjchem-2489	63	45	.	.	PUNCT
eurjchem-2489	64	1	kinetic	kinetic	ADJ
eurjchem-2489	64	2	analyzes	analyze	NOUN
eurjchem-2489	64	3	were	be	AUX
eurjchem-2489	64	4	performed	perform	VERB
eurjchem-2489	64	5	in	in	ADP
eurjchem-2489	64	6	triplicate	triplicate	NOUN
eurjchem-2489	64	7	to	to	PART
eurjchem-2489	64	8	reveal	reveal	VERB
eurjchem-2489	64	9	the	the	DET
eurjchem-2489	64	10	rate	rate	NOUN
eurjchem-2489	64	11	and	and	CCONJ
eurjchem-2489	64	12	efficiency	efficiency	NOUN
eurjchem-2489	64	13	of	of	ADP
eurjchem-2489	64	14	the	the	DET
eurjchem-2489	64	15	catalytic	catalytic	ADJ
eurjchem-2489	64	16	oxidation	oxidation	NOUN
eurjchem-2489	64	17	reaction	reaction	NOUN
eurjchem-2489	64	18	.	.	PUNCT
eurjchem-2489	65	1	the	the	DET
eurjchem-2489	65	2	involvement	involvement	NOUN
eurjchem-2489	65	3	of	of	ADP
eurjchem-2489	65	4	aerobic	aerobic	ADJ
eurjchem-2489	65	5	oxygen	oxygen	NOUN
eurjchem-2489	65	6	in	in	ADP
eurjchem-2489	65	7	the	the	DET
eurjchem-2489	65	8	oxidation	oxidation	NOUN
eurjchem-2489	65	9	of	of	ADP
eurjchem-2489	65	10	dtbc	dtbc	PROPN
eurjchem-2489	65	11	was	be	AUX
eurjchem-2489	65	12	examined	examine	VERB
eurjchem-2489	65	13	in	in	ADP
eurjchem-2489	65	14	the	the	DET
eurjchem-2489	65	15	presence	presence	NOUN
eurjchem-2489	65	16	of	of	ADP
eurjchem-2489	65	17	hydrogen	hydrogen	NOUN
eurjchem-2489	65	18	peroxide	peroxide	NOUN
eurjchem-2489	65	19	following	follow	VERB
eurjchem-2489	65	20	a	a	DET
eurjchem-2489	65	21	reported	report	VERB
eurjchem-2489	65	22	procedure	procedure	NOUN
eurjchem-2489	65	23	[	[	X
eurjchem-2489	65	24	24	24	NUM
eurjchem-2489	65	25	]	]	PUNCT
eurjchem-2489	65	26	.	.	PUNCT
eurjchem-2489	66	1	3	3	X
eurjchem-2489	66	2	.	.	NOUN
eurjchem-2489	66	3	results	result	NOUN
eurjchem-2489	66	4	and	and	CCONJ
eurjchem-2489	66	5	discussion	discussion	NOUN
eurjchem-2489	66	6	3.1	3.1	NUM
eurjchem-2489	66	7	.	.	PUNCT
eurjchem-2489	67	1	design	design	NOUN
eurjchem-2489	67	2	,	,	PUNCT
eurjchem-2489	67	3	synthesis	synthesis	NOUN
eurjchem-2489	67	4	and	and	CCONJ
eurjchem-2489	67	5	formulation	formulation	NOUN
eurjchem-2489	67	6	of	of	ADP
eurjchem-2489	67	7	the	the	DET
eurjchem-2489	67	8	copper(ii	copper(ii	NOUN
eurjchem-2489	67	9	)	)	PUNCT
eurjchem-2489	67	10	complex	complex	NOUN
eurjchem-2489	67	11	(	(	PUNCT
eurjchem-2489	67	12	1	1	X
eurjchem-2489	67	13	)	)	PUNCT
eurjchem-2489	67	14	the	the	DET
eurjchem-2489	67	15	cu	cu	PROPN
eurjchem-2489	67	16	complex	complex	NOUN
eurjchem-2489	67	17	was	be	AUX
eurjchem-2489	67	18	formed	form	VERB
eurjchem-2489	67	19	by	by	ADP
eurjchem-2489	67	20	an	an	DET
eurjchem-2489	67	21	in	in	ADP
eurjchem-2489	67	22	situ	situ	ADJ
eurjchem-2489	67	23	reaction	reaction	NOUN
eurjchem-2489	67	24	with	with	ADP
eurjchem-2489	67	25	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	67	26	in	in	ADP
eurjchem-2489	67	27	the	the	DET
eurjchem-2489	67	28	presence	presence	NOUN
eurjchem-2489	67	29	of	of	ADP
eurjchem-2489	67	30	morpholine	morpholine	NOUN
eurjchem-2489	67	31	and	and	CCONJ
eurjchem-2489	67	32	p	p	NOUN
eurjchem-2489	67	33	-	-	PUNCT
eurjchem-2489	67	34	cresol	cresol	NOUN
eurjchem-2489	67	35	.	.	PUNCT
eurjchem-2489	68	1	initially	initially	ADV
eurjchem-2489	68	2	,	,	PUNCT
eurjchem-2489	68	3	we	we	PRON
eurjchem-2489	68	4	intended	intend	VERB
eurjchem-2489	68	5	to	to	PART
eurjchem-2489	68	6	form	form	VERB
eurjchem-2489	68	7	a	a	DET
eurjchem-2489	68	8	mannich	mannich	PRON
eurjchem-2489	68	9	base	base	NOUN
eurjchem-2489	68	10	ligand	ligand	NOUN
eurjchem-2489	68	11	using	use	VERB
eurjchem-2489	68	12	salicylaldehyde	salicylaldehyde	PROPN
eurjchem-2489	68	13	,	,	PUNCT
eurjchem-2489	68	14	morpholine	morpholine	ADJ
eurjchem-2489	68	15	and	and	CCONJ
eurjchem-2489	68	16	p	p	NOUN
eurjchem-2489	68	17	-	-	PUNCT
eurjchem-2489	68	18	cresol	cresol	NOUN
eurjchem-2489	68	19	(	(	PUNCT
eurjchem-2489	68	20	1	1	NUM
eurjchem-2489	68	21	:	:	SYM
eurjchem-2489	68	22	1	1	NUM
eurjchem-2489	68	23	:	:	SYM
eurjchem-2489	68	24	1	1	NUM
eurjchem-2489	68	25	)	)	PUNCT
eurjchem-2489	68	26	refluxed	refluxe	VERB
eurjchem-2489	68	27	in	in	ADP
eurjchem-2489	68	28	methanol	methanol	NOUN
eurjchem-2489	68	29	for	for	ADP
eurjchem-2489	68	30	6	6	NUM
eurjchem-2489	68	31	hours	hour	NOUN
eurjchem-2489	68	32	and	and	CCONJ
eurjchem-2489	68	33	a	a	DET
eurjchem-2489	68	34	methanolic	methanolic	NOUN
eurjchem-2489	68	35	solution	solution	NOUN
eurjchem-2489	68	36	of	of	ADP
eurjchem-2489	68	37	cu(oac)2	cu(oac)2	NOUN
eurjchem-2489	68	38	(	(	PUNCT
eurjchem-2489	68	39	1	1	NUM
eurjchem-2489	68	40	mmol	mmol	NOUN
eurjchem-2489	68	41	)	)	PUNCT
eurjchem-2489	68	42	was	be	AUX
eurjchem-2489	68	43	added	add	VERB
eurjchem-2489	68	44	and	and	CCONJ
eurjchem-2489	68	45	the	the	DET
eurjchem-2489	68	46	mixture	mixture	NOUN
eurjchem-2489	68	47	was	be	AUX
eurjchem-2489	68	48	refluxed	refluxe	VERB
eurjchem-2489	68	49	again	again	ADV
eurjchem-2489	68	50	for	for	ADP
eurjchem-2489	68	51	3	3	NUM
eurjchem-2489	68	52	hours	hour	NOUN
eurjchem-2489	68	53	.	.	PUNCT
eurjchem-2489	69	1	the	the	DET
eurjchem-2489	69	2	synthetic	synthetic	ADJ
eurjchem-2489	69	3	route	route	NOUN
eurjchem-2489	69	4	is	be	AUX
eurjchem-2489	69	5	shown	show	VERB
eurjchem-2489	69	6	in	in	ADP
eurjchem-2489	69	7	scheme	scheme	NOUN
eurjchem-2489	69	8	1	1	NUM
eurjchem-2489	69	9	.	.	PUNCT
eurjchem-2489	70	1	after	after	ADP
eurjchem-2489	70	2	the	the	DET
eurjchem-2489	70	3	analysis	analysis	NOUN
eurjchem-2489	70	4	of	of	ADP
eurjchem-2489	70	5	the	the	DET
eurjchem-2489	70	6	xrd	xrd	NOUN
eurjchem-2489	70	7	study	study	NOUN
eurjchem-2489	70	8	,	,	PUNCT
eurjchem-2489	70	9	we	we	PRON
eurjchem-2489	70	10	found	find	VERB
eurjchem-2489	70	11	that	that	SCONJ
eurjchem-2489	70	12	the	the	DET
eurjchem-2489	70	13	expected	expect	VERB
eurjchem-2489	70	14	ligand	ligand	NOUN
eurjchem-2489	70	15	was	be	AUX
eurjchem-2489	70	16	not	not	PART
eurjchem-2489	70	17	formed	form	VERB
eurjchem-2489	70	18	and	and	CCONJ
eurjchem-2489	70	19	cu	cu	PROPN
eurjchem-2489	70	20	-	-	PUNCT
eurjchem-2489	70	21	acetate	acetate	PROPN
eurjchem-2489	70	22	formed	form	VERB
eurjchem-2489	70	23	an	an	DET
eurjchem-2489	70	24	inner	inner	ADJ
eurjchem-2489	70	25	metallic	metallic	ADJ
eurjchem-2489	70	26	complex	complex	NOUN
eurjchem-2489	70	27	with	with	ADP
eurjchem-2489	70	28	two	two	NUM
eurjchem-2489	70	29	units	unit	NOUN
eurjchem-2489	70	30	of	of	ADP
eurjchem-2489	70	31	salicylaldehyde	salicylaldehyde	PROPN
eurjchem-2489	70	32	.	.	PUNCT
eurjchem-2489	71	1	mukherjee	mukherjee	PROPN
eurjchem-2489	71	2	et	et	PROPN
eurjchem-2489	71	3	al	al	PROPN
eurjchem-2489	71	4	.	.	PUNCT
eurjchem-2489	71	5	/	/	SYM
eurjchem-2489	71	6	european	european	PROPN
eurjchem-2489	71	7	journal	journal	PROPN
eurjchem-2489	71	8	of	of	ADP
eurjchem-2489	71	9	chemistry	chemistry	NOUN
eurjchem-2489	71	10	14	14	NUM
eurjchem-2489	71	11	(	(	PUNCT
eurjchem-2489	71	12	4	4	NUM
eurjchem-2489	71	13	)	)	PUNCT
eurjchem-2489	71	14	(	(	PUNCT
eurjchem-2489	71	15	2023	2023	NUM
eurjchem-2489	71	16	)	)	PUNCT
eurjchem-2489	71	17	499	499	NUM
eurjchem-2489	71	18	-	-	SYM
eurjchem-2489	71	19	506	506	NUM
eurjchem-2489	71	20	501	501	NUM
eurjchem-2489	71	21	2023	2023	NUM
eurjchem-2489	71	22	–	–	PUNCT
eurjchem-2489	71	23	european	european	ADJ
eurjchem-2489	71	24	journal	journal	NOUN
eurjchem-2489	71	25	of	of	ADP
eurjchem-2489	71	26	chemistry	chemistry	NOUN
eurjchem-2489	71	27	–	–	PUNCT
eurjchem-2489	71	28	cc	cc	NOUN
eurjchem-2489	71	29	by	by	ADP
eurjchem-2489	71	30	nc	nc	PROPN
eurjchem-2489	71	31	–	–	PUNCT
eurjchem-2489	71	32	doi	doi	NOUN
eurjchem-2489	71	33	:	:	PUNCT
eurjchem-2489	71	34	10.5155	10.5155	NUM
eurjchem-2489	71	35	/	/	SYM
eurjchem-2489	71	36	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	71	37	-	-	PUNCT
eurjchem-2489	71	38	506.2489	506.2489	NUM
eurjchem-2489	71	39	table	table	NOUN
eurjchem-2489	71	40	1	1	NUM
eurjchem-2489	71	41	.	.	PUNCT
eurjchem-2489	72	1	crystal	crystal	NOUN
eurjchem-2489	72	2	data	datum	NOUN
eurjchem-2489	72	3	and	and	CCONJ
eurjchem-2489	72	4	structure	structure	NOUN
eurjchem-2489	72	5	refinement	refinement	NOUN
eurjchem-2489	72	6	for	for	ADP
eurjchem-2489	72	7	the	the	DET
eurjchem-2489	72	8	copper(ii	copper(ii	NOUN
eurjchem-2489	72	9	)	)	PUNCT
eurjchem-2489	72	10	complex	complex	NOUN
eurjchem-2489	72	11	(	(	PUNCT
eurjchem-2489	72	12	1	1	NUM
eurjchem-2489	72	13	)	)	PUNCT
eurjchem-2489	72	14	.	.	PUNCT
eurjchem-2489	73	1	empirical	empirical	ADJ
eurjchem-2489	73	2	formula	formula	NOUN
eurjchem-2489	73	3	c28h26cuo6	c28h26cuo6	NOUN
eurjchem-2489	73	4	formula	formula	NOUN
eurjchem-2489	73	5	weight	weight	NOUN
eurjchem-2489	73	6	(	(	PUNCT
eurjchem-2489	73	7	g	g	NOUN
eurjchem-2489	73	8	/	/	SYM
eurjchem-2489	73	9	mol	mol	NOUN
eurjchem-2489	73	10	)	)	PUNCT
eurjchem-2489	73	11	261.01	261.01	NUM
eurjchem-2489	73	12	temperature	temperature	NOUN
eurjchem-2489	73	13	(	(	PUNCT
eurjchem-2489	73	14	k	k	NOUN
eurjchem-2489	73	15	)	)	PUNCT
eurjchem-2489	73	16	293(2	293(2	NUM
eurjchem-2489	73	17	)	)	PUNCT
eurjchem-2489	73	18	crystal	crystal	NOUN
eurjchem-2489	73	19	system	system	NOUN
eurjchem-2489	73	20	monoclinic	monoclinic	ADJ
eurjchem-2489	73	21	space	space	NOUN
eurjchem-2489	73	22	group	group	NOUN
eurjchem-2489	73	23	p21	p21	PROPN
eurjchem-2489	73	24	/	/	SYM
eurjchem-2489	73	25	c	c	PROPN
eurjchem-2489	73	26	a	a	PRON
eurjchem-2489	73	27	,	,	PUNCT
eurjchem-2489	73	28	(	(	PUNCT
eurjchem-2489	73	29	å	å	NOUN
eurjchem-2489	73	30	)	)	PUNCT
eurjchem-2489	73	31	5.9204(2	5.9204(2	NUM
eurjchem-2489	73	32	)	)	PUNCT
eurjchem-2489	73	33	b	b	NOUN
eurjchem-2489	73	34	,	,	PUNCT
eurjchem-2489	73	35	(	(	PUNCT
eurjchem-2489	73	36	å	å	NOUN
eurjchem-2489	73	37	)	)	PUNCT
eurjchem-2489	73	38	21.5615(10	21.5615(10	NUM
eurjchem-2489	73	39	)	)	PUNCT
eurjchem-2489	73	40	c	c	X
eurjchem-2489	73	41	,	,	PUNCT
eurjchem-2489	73	42	(	(	PUNCT
eurjchem-2489	73	43	å	å	NOUN
eurjchem-2489	73	44	)	)	PUNCT
eurjchem-2489	73	45	9.0715(4	9.0715(4	NOUN
eurjchem-2489	73	46	)	)	PUNCT
eurjchem-2489	73	47	β	β	X
eurjchem-2489	73	48	(	(	PUNCT
eurjchem-2489	73	49	°	°	PROPN
eurjchem-2489	73	50	)	)	PUNCT
eurjchem-2489	73	51	91.266(4	91.266(4	NUM
eurjchem-2489	73	52	)	)	PUNCT
eurjchem-2489	73	53	volume	volume	NOUN
eurjchem-2489	73	54	(	(	PUNCT
eurjchem-2489	73	55	å3	å3	PROPN
eurjchem-2489	73	56	)	)	PUNCT
eurjchem-2489	73	57	1157.72(8	1157.72(8	NUM
eurjchem-2489	73	58	)	)	PUNCT
eurjchem-2489	73	59	z	z	NOUN
eurjchem-2489	73	60	2	2	NUM
eurjchem-2489	73	61	ρcalc	ρcalc	NOUN
eurjchem-2489	73	62	(	(	PUNCT
eurjchem-2489	73	63	g	g	NOUN
eurjchem-2489	73	64	/	/	SYM
eurjchem-2489	73	65	cm3	cm3	NOUN
eurjchem-2489	73	66	)	)	PUNCT
eurjchem-2489	73	67	1.498	1.498	NUM
eurjchem-2489	73	68	μ	μ	NOUN
eurjchem-2489	73	69	(	(	PUNCT
eurjchem-2489	73	70	mm-1	mm-1	NOUN
eurjchem-2489	73	71	)	)	PUNCT
eurjchem-2489	73	72	0.987	0.987	NUM
eurjchem-2489	73	73	f(000	f(000	NOUN
eurjchem-2489	73	74	)	)	PUNCT
eurjchem-2489	73	75	542.0	542.0	NUM
eurjchem-2489	73	76	crystal	crystal	NOUN
eurjchem-2489	73	77	size	size	NOUN
eurjchem-2489	73	78	(	(	PUNCT
eurjchem-2489	73	79	mm3	mm3	PROPN
eurjchem-2489	73	80	)	)	PUNCT
eurjchem-2489	73	81	0.4	0.4	NUM
eurjchem-2489	73	82	×	×	NOUN
eurjchem-2489	73	83	0.6	0.6	NUM
eurjchem-2489	73	84	×	×	NOUN
eurjchem-2489	73	85	0.2	0.2	NUM
eurjchem-2489	73	86	radiation	radiation	NOUN
eurjchem-2489	73	87	mokα	mokα	NOUN
eurjchem-2489	73	88	(	(	PUNCT
eurjchem-2489	73	89	λ	λ	X
eurjchem-2489	73	90	=	=	SYM
eurjchem-2489	73	91	0.71073	0.71073	NUM
eurjchem-2489	73	92	)	)	PUNCT
eurjchem-2489	73	93	2θ	2θ	NUM
eurjchem-2489	73	94	range	range	VERB
eurjchem-2489	73	95	for	for	ADP
eurjchem-2489	73	96	data	data	NOUN
eurjchem-2489	73	97	collection	collection	NOUN
eurjchem-2489	73	98	(	(	PUNCT
eurjchem-2489	73	99	°	°	ADP
eurjchem-2489	73	100	)	)	PUNCT
eurjchem-2489	73	101	6.884	6.884	NUM
eurjchem-2489	73	102	to	to	ADP
eurjchem-2489	73	103	63.42	63.42	NUM
eurjchem-2489	73	104	index	index	NOUN
eurjchem-2489	73	105	ranges	range	VERB
eurjchem-2489	73	106	-7	-7	X
eurjchem-2489	73	107	≤	≤	NUM
eurjchem-2489	73	108	h	h	NOUN
eurjchem-2489	73	109	≤	≤	NOUN
eurjchem-2489	73	110	8	8	NUM
eurjchem-2489	73	111	,	,	PUNCT
eurjchem-2489	73	112	-30	-30	PUNCT
eurjchem-2489	73	113	≤	≤	NUM
eurjchem-2489	74	1	k	k	X
eurjchem-2489	74	2	≤	≤	NUM
eurjchem-2489	74	3	27	27	NUM
eurjchem-2489	74	4	,	,	PUNCT
eurjchem-2489	74	5	-12	-12	PROPN
eurjchem-2489	74	6	≤	≤	NUM
eurjchem-2489	74	7	l	l	NOUN
eurjchem-2489	74	8	≤	≤	NUM
eurjchem-2489	74	9	10	10	NUM
eurjchem-2489	74	10	reflections	reflection	NOUN
eurjchem-2489	74	11	collected	collect	VERB
eurjchem-2489	74	12	12647	12647	NUM
eurjchem-2489	74	13	independent	independent	ADJ
eurjchem-2489	74	14	reflections	reflection	NOUN
eurjchem-2489	74	15	3233	3233	NUM
eurjchem-2489	74	16	[	[	X
eurjchem-2489	74	17	rint	rint	NOUN
eurjchem-2489	74	18	=	=	SYM
eurjchem-2489	74	19	0.0618	0.0618	NUM
eurjchem-2489	74	20	,	,	PUNCT
eurjchem-2489	74	21	rsigma	rsigma	ADJ
eurjchem-2489	74	22	=	=	PUNCT
eurjchem-2489	74	23	0.0512	0.0512	NUM
eurjchem-2489	74	24	]	]	PUNCT
eurjchem-2489	74	25	data	data	NOUN
eurjchem-2489	74	26	/	/	SYM
eurjchem-2489	74	27	restraints	restraint	NOUN
eurjchem-2489	74	28	/	/	SYM
eurjchem-2489	74	29	parameters	parameter	NOUN
eurjchem-2489	74	30	3233/0/162	3233/0/162	NUM
eurjchem-2489	74	31	goodness	goodness	NOUN
eurjchem-2489	74	32	-	-	PUNCT
eurjchem-2489	74	33	of	of	ADP
eurjchem-2489	74	34	-	-	PUNCT
eurjchem-2489	74	35	fit	fit	NOUN
eurjchem-2489	74	36	on	on	ADP
eurjchem-2489	74	37	f2	f2	PROPN
eurjchem-2489	74	38	1.144	1.144	NUM
eurjchem-2489	74	39	final	final	ADJ
eurjchem-2489	74	40	r	r	NOUN
eurjchem-2489	74	41	indexes	index	NOUN
eurjchem-2489	75	1	[	[	X
eurjchem-2489	75	2	i≥2σ	i≥2σ	X
eurjchem-2489	75	3	(	(	PUNCT
eurjchem-2489	75	4	i	i	NOUN
eurjchem-2489	75	5	)	)	PUNCT
eurjchem-2489	75	6	]	]	PUNCT
eurjchem-2489	75	7	r1	r1	NOUN
eurjchem-2489	75	8	=	=	SYM
eurjchem-2489	75	9	0.0710	0.0710	NUM
eurjchem-2489	75	10	,	,	PUNCT
eurjchem-2489	75	11	wr2	wr2	PROPN
eurjchem-2489	75	12	=	=	PROPN
eurjchem-2489	76	1	0.2120	0.2120	NUM
eurjchem-2489	76	2	final	final	ADJ
eurjchem-2489	76	3	r	r	NOUN
eurjchem-2489	76	4	indexes	index	NOUN
eurjchem-2489	76	5	[	[	X
eurjchem-2489	76	6	all	all	DET
eurjchem-2489	76	7	data	datum	NOUN
eurjchem-2489	76	8	]	]	PUNCT
eurjchem-2489	76	9	r1	r1	NOUN
eurjchem-2489	76	10	=	=	PUNCT
eurjchem-2489	76	11	0.0812	0.0812	NUM
eurjchem-2489	76	12	,	,	PUNCT
eurjchem-2489	76	13	wr2	wr2	PROPN
eurjchem-2489	76	14	=	=	PROPN
eurjchem-2489	76	15	0.2173	0.2173	NUM
eurjchem-2489	76	16	largest	large	ADJ
eurjchem-2489	76	17	diff	diff	NOUN
eurjchem-2489	76	18	.	.	PUNCT
eurjchem-2489	76	19	peak	peak	PROPN
eurjchem-2489	76	20	/	/	SYM
eurjchem-2489	76	21	hole	hole	NOUN
eurjchem-2489	76	22	(	(	PUNCT
eurjchem-2489	76	23	e.å-3	e.å-3	ADJ
eurjchem-2489	76	24	)	)	PUNCT
eurjchem-2489	76	25	0.83/-1.37	0.83/-1.37	PROPN
eurjchem-2489	76	26	figure	figure	NOUN
eurjchem-2489	76	27	1	1	NUM
eurjchem-2489	76	28	.	.	PUNCT
eurjchem-2489	76	29	thermal	thermal	ADJ
eurjchem-2489	76	30	ellipsoidal	ellipsoidal	ADJ
eurjchem-2489	76	31	plots	plot	NOUN
eurjchem-2489	76	32	of	of	ADP
eurjchem-2489	76	33	the	the	DET
eurjchem-2489	76	34	copper(ii	copper(ii	NOUN
eurjchem-2489	76	35	)	)	PUNCT
eurjchem-2489	76	36	complex	complex	NOUN
eurjchem-2489	76	37	.	.	PUNCT
eurjchem-2489	77	1	the	the	DET
eurjchem-2489	77	2	p	p	NOUN
eurjchem-2489	77	3	-	-	PUNCT
eurjchem-2489	77	4	cresol	cresol	NOUN
eurjchem-2489	77	5	unit	unit	NOUN
eurjchem-2489	77	6	is	be	AUX
eurjchem-2489	77	7	situated	situate	VERB
eurjchem-2489	77	8	in	in	ADP
eurjchem-2489	77	9	close	close	ADJ
eurjchem-2489	77	10	proximity	proximity	NOUN
eurjchem-2489	77	11	to	to	ADP
eurjchem-2489	77	12	the	the	DET
eurjchem-2489	77	13	complex	complex	ADJ
eurjchem-2489	77	14	part	part	NOUN
eurjchem-2489	77	15	by	by	ADP
eurjchem-2489	77	16	noncovalent	noncovalent	NOUN
eurjchem-2489	77	17	interaction	interaction	NOUN
eurjchem-2489	77	18	.	.	PUNCT
eurjchem-2489	78	1	the	the	DET
eurjchem-2489	78	2	copper(ii	copper(ii	NOUN
eurjchem-2489	78	3	)	)	PUNCT
eurjchem-2489	78	4	complex	complex	NOUN
eurjchem-2489	78	5	is	be	AUX
eurjchem-2489	78	6	found	find	VERB
eurjchem-2489	78	7	to	to	PART
eurjchem-2489	78	8	be	be	AUX
eurjchem-2489	78	9	soluble	soluble	ADJ
eurjchem-2489	78	10	in	in	ADP
eurjchem-2489	78	11	polar	polar	ADJ
eurjchem-2489	78	12	solvents	solvent	NOUN
eurjchem-2489	78	13	such	such	ADJ
eurjchem-2489	78	14	as	as	ADP
eurjchem-2489	78	15	ch3oh	ch3oh	NUM
eurjchem-2489	78	16	,	,	PUNCT
eurjchem-2489	78	17	c2h5oh	c2h5oh	ADJ
eurjchem-2489	78	18	,	,	PUNCT
eurjchem-2489	78	19	and	and	CCONJ
eurjchem-2489	78	20	ch3cn	ch3cn	NUM
eurjchem-2489	78	21	,	,	PUNCT
eurjchem-2489	78	22	etc	etc	X
eurjchem-2489	78	23	.	.	X
eurjchem-2489	79	1	the	the	DET
eurjchem-2489	79	2	significant	significant	ADJ
eurjchem-2489	79	3	deviation	deviation	NOUN
eurjchem-2489	79	4	from	from	ADP
eurjchem-2489	79	5	the	the	DET
eurjchem-2489	79	6	targeted	target	VERB
eurjchem-2489	79	7	mannich	mannich	NOUN
eurjchem-2489	79	8	base	base	NOUN
eurjchem-2489	79	9	product	product	NOUN
eurjchem-2489	79	10	may	may	AUX
eurjchem-2489	79	11	be	be	AUX
eurjchem-2489	79	12	explained	explain	VERB
eurjchem-2489	79	13	in	in	ADP
eurjchem-2489	79	14	terms	term	NOUN
eurjchem-2489	79	15	of	of	ADP
eurjchem-2489	79	16	the	the	DET
eurjchem-2489	79	17	acid	acid	NOUN
eurjchem-2489	79	18	-	-	PUNCT
eurjchem-2489	79	19	base	base	NOUN
eurjchem-2489	79	20	chemistry	chemistry	NOUN
eurjchem-2489	79	21	of	of	ADP
eurjchem-2489	79	22	the	the	DET
eurjchem-2489	79	23	reactants	reactant	NOUN
eurjchem-2489	79	24	involved	involve	VERB
eurjchem-2489	79	25	.	.	PUNCT
eurjchem-2489	80	1	the	the	DET
eurjchem-2489	80	2	literature	literature	PROPN
eurjchem-2489	80	3	survey	survey	NOUN
eurjchem-2489	80	4	shows	show	VERB
eurjchem-2489	80	5	that	that	SCONJ
eurjchem-2489	80	6	the	the	DET
eurjchem-2489	80	7	pka	pka	PROPN
eurjchem-2489	80	8	values	value	NOUN
eurjchem-2489	80	9	for	for	ADP
eurjchem-2489	80	10	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	80	11	and	and	CCONJ
eurjchem-2489	80	12	p	p	NOUN
eurjchem-2489	80	13	-	-	PUNCT
eurjchem-2489	80	14	cresol	cresol	NOUN
eurjchem-2489	80	15	are	be	AUX
eurjchem-2489	80	16	8.22	8.22	NUM
eurjchem-2489	80	17	and	and	CCONJ
eurjchem-2489	80	18	10.37	10.37	NUM
eurjchem-2489	80	19	[	[	X
eurjchem-2489	80	20	25	25	NUM
eurjchem-2489	80	21	]	]	PUNCT
eurjchem-2489	80	22	in	in	ADP
eurjchem-2489	80	23	typical	typical	ADJ
eurjchem-2489	80	24	cases	case	NOUN
eurjchem-2489	80	25	,	,	PUNCT
eurjchem-2489	80	26	attributed	attribute	VERB
eurjchem-2489	80	27	to	to	ADP
eurjchem-2489	80	28	the	the	DET
eurjchem-2489	80	29	relatively	relatively	ADV
eurjchem-2489	80	30	higher	high	ADJ
eurjchem-2489	80	31	acidity	acidity	NOUN
eurjchem-2489	80	32	of	of	ADP
eurjchem-2489	80	33	salicylaldehyde	salicylaldehyde	PROPN
eurjchem-2489	80	34	.	.	PUNCT
eurjchem-2489	81	1	this	this	DET
eurjchem-2489	81	2	report	report	NOUN
eurjchem-2489	81	3	on	on	ADP
eurjchem-2489	81	4	acidity	acidity	NOUN
eurjchem-2489	81	5	for	for	ADP
eurjchem-2489	81	6	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	81	7	offers	offer	VERB
eurjchem-2489	81	8	a	a	DET
eurjchem-2489	81	9	better	well	ADJ
eurjchem-2489	81	10	delivery	delivery	NOUN
eurjchem-2489	81	11	of	of	ADP
eurjchem-2489	81	12	protons	proton	NOUN
eurjchem-2489	81	13	to	to	ADP
eurjchem-2489	81	14	morpholine	morpholine	VERB
eurjchem-2489	81	15	(	(	PUNCT
eurjchem-2489	81	16	a	a	DET
eurjchem-2489	81	17	2	2	NUM
eurjchem-2489	81	18	°	°	NOUN
eurjchem-2489	81	19	amine	amine	NOUN
eurjchem-2489	81	20	)	)	PUNCT
eurjchem-2489	81	21	,	,	PUNCT
eurjchem-2489	81	22	resulting	result	VERB
eurjchem-2489	81	23	in	in	ADP
eurjchem-2489	81	24	the	the	DET
eurjchem-2489	81	25	deactivation	deactivation	NOUN
eurjchem-2489	81	26	of	of	ADP
eurjchem-2489	81	27	the	the	DET
eurjchem-2489	81	28	nucleophilic	nucleophilic	ADJ
eurjchem-2489	81	29	character	character	NOUN
eurjchem-2489	81	30	of	of	ADP
eurjchem-2489	81	31	the	the	DET
eurjchem-2489	81	32	amine	amine	NOUN
eurjchem-2489	81	33	in	in	ADP
eurjchem-2489	81	34	its	its	PRON
eurjchem-2489	81	35	proton	proton	NOUN
eurjchem-2489	81	36	-	-	PUNCT
eurjchem-2489	81	37	abstracted	abstract	VERB
eurjchem-2489	81	38	form	form	NOUN
eurjchem-2489	81	39	.	.	PUNCT
eurjchem-2489	82	1	when	when	SCONJ
eurjchem-2489	82	2	the	the	DET
eurjchem-2489	82	3	copper	copper	NOUN
eurjchem-2489	82	4	salt	salt	NOUN
eurjchem-2489	82	5	was	be	AUX
eurjchem-2489	82	6	added	add	VERB
eurjchem-2489	82	7	in	in	ADP
eurjchem-2489	82	8	situ	situ	NOUN
eurjchem-2489	82	9	,	,	PUNCT
eurjchem-2489	82	10	a	a	DET
eurjchem-2489	82	11	stable	stable	ADJ
eurjchem-2489	82	12	copper	copper	NOUN
eurjchem-2489	82	13	chelate	chelate	NOUN
eurjchem-2489	82	14	was	be	AUX
eurjchem-2489	82	15	formed	form	VERB
eurjchem-2489	82	16	with	with	ADP
eurjchem-2489	82	17	the	the	DET
eurjchem-2489	82	18	anionic	anionic	ADJ
eurjchem-2489	82	19	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	82	20	.	.	PUNCT
eurjchem-2489	83	1	the	the	DET
eurjchem-2489	83	2	p	p	NOUN
eurjchem-2489	83	3	-	-	PUNCT
eurjchem-2489	83	4	cresol	cresol	NOUN
eurjchem-2489	83	5	turns	turn	VERB
eurjchem-2489	83	6	out	out	ADP
eurjchem-2489	83	7	to	to	PART
eurjchem-2489	83	8	be	be	AUX
eurjchem-2489	83	9	a	a	DET
eurjchem-2489	83	10	crystallized	crystallized	ADJ
eurjchem-2489	83	11	molecule	molecule	NOUN
eurjchem-2489	83	12	in	in	ADP
eurjchem-2489	83	13	the	the	DET
eurjchem-2489	83	14	formation	formation	NOUN
eurjchem-2489	83	15	of	of	ADP
eurjchem-2489	83	16	a	a	DET
eurjchem-2489	83	17	crystalline	crystalline	ADJ
eurjchem-2489	83	18	copper	copper	NOUN
eurjchem-2489	83	19	complex	complex	NOUN
eurjchem-2489	83	20	,	,	PUNCT
eurjchem-2489	83	21	as	as	SCONJ
eurjchem-2489	83	22	revealed	reveal	VERB
eurjchem-2489	83	23	by	by	ADP
eurjchem-2489	83	24	x	x	NOUN
eurjchem-2489	83	25	-	-	NOUN
eurjchem-2489	83	26	ray	ray	NOUN
eurjchem-2489	83	27	crystallography	crystallography	NOUN
eurjchem-2489	83	28	through	through	ADP
eurjchem-2489	83	29	its	its	PRON
eurjchem-2489	83	30	active	active	ADJ
eurjchem-2489	83	31	participation	participation	NOUN
eurjchem-2489	83	32	in	in	ADP
eurjchem-2489	83	33	the	the	DET
eurjchem-2489	83	34	short	short	ADV
eurjchem-2489	83	35	-	-	PUNCT
eurjchem-2489	83	36	ranged	range	VERB
eurjchem-2489	83	37	hydrogen	hydrogen	NOUN
eurjchem-2489	83	38	bonding	bonding	NOUN
eurjchem-2489	83	39	with	with	ADP
eurjchem-2489	83	40	the	the	DET
eurjchem-2489	83	41	complex	complex	NOUN
eurjchem-2489	83	42	without	without	ADP
eurjchem-2489	83	43	any	any	DET
eurjchem-2489	83	44	permanent	permanent	ADJ
eurjchem-2489	83	45	binding	binding	NOUN
eurjchem-2489	83	46	.	.	PUNCT
eurjchem-2489	84	1	3.2	3.2	NUM
eurjchem-2489	84	2	.	.	PUNCT
eurjchem-2489	84	3	description	description	NOUN
eurjchem-2489	84	4	of	of	ADP
eurjchem-2489	84	5	crystal	crystal	NOUN
eurjchem-2489	84	6	structure	structure	NOUN
eurjchem-2489	84	7	and	and	CCONJ
eurjchem-2489	84	8	supramolecular	supramolecular	ADJ
eurjchem-2489	84	9	interactions	interaction	NOUN
eurjchem-2489	84	10	x	x	NOUN
eurjchem-2489	84	11	-	-	NOUN
eurjchem-2489	84	12	ray	ray	NOUN
eurjchem-2489	84	13	diffraction	diffraction	NOUN
eurjchem-2489	84	14	analysis	analysis	NOUN
eurjchem-2489	84	15	reveals	reveal	VERB
eurjchem-2489	84	16	that	that	SCONJ
eurjchem-2489	84	17	a	a	DET
eurjchem-2489	84	18	mononuclear	mononuclear	ADJ
eurjchem-2489	84	19	copper(ii	copper(ii	NOUN
eurjchem-2489	84	20	)	)	PUNCT
eurjchem-2489	84	21	complex	complex	ADJ
eurjchem-2489	84	22	unit	unit	NOUN
eurjchem-2489	84	23	cocrystallizes	cocrystallize	VERB
eurjchem-2489	84	24	with	with	ADP
eurjchem-2489	84	25	a	a	DET
eurjchem-2489	84	26	p	p	NOUN
eurjchem-2489	84	27	-	-	PUNCT
eurjchem-2489	84	28	methyl	methyl	NOUN
eurjchem-2489	84	29	phenol	phenol	NOUN
eurjchem-2489	84	30	in	in	ADP
eurjchem-2489	84	31	a	a	DET
eurjchem-2489	84	32	monoclinic	monoclinic	ADJ
eurjchem-2489	84	33	system	system	NOUN
eurjchem-2489	84	34	adopting	adopt	VERB
eurjchem-2489	84	35	a	a	DET
eurjchem-2489	84	36	p21	p21	NOUN
eurjchem-2489	84	37	/	/	SYM
eurjchem-2489	84	38	c	c	NOUN
eurjchem-2489	84	39	space	space	NOUN
eurjchem-2489	84	40	group	group	NOUN
eurjchem-2489	84	41	.	.	PUNCT
eurjchem-2489	85	1	the	the	DET
eurjchem-2489	85	2	copper(ii	copper(ii	PROPN
eurjchem-2489	85	3	)	)	PUNCT
eurjchem-2489	85	4	centre	centre	NOUN
eurjchem-2489	85	5	has	have	VERB
eurjchem-2489	85	6	a	a	DET
eurjchem-2489	85	7	nearly	nearly	ADV
eurjchem-2489	85	8	square	square	ADJ
eurjchem-2489	85	9	planar	planar	ADJ
eurjchem-2489	85	10	coordination	coordination	NOUN
eurjchem-2489	85	11	geometry	geometry	NOUN
eurjchem-2489	85	12	,	,	PUNCT
eurjchem-2489	85	13	as	as	SCONJ
eurjchem-2489	85	14	evidenced	evidence	VERB
eurjchem-2489	85	15	by	by	ADP
eurjchem-2489	85	16	the	the	DET
eurjchem-2489	85	17	measurement	measurement	NOUN
eurjchem-2489	85	18	of	of	ADP
eurjchem-2489	85	19	crystallographic	crystallographic	ADJ
eurjchem-2489	85	20	bond	bond	NOUN
eurjchem-2489	85	21	angles	angle	NOUN
eurjchem-2489	85	22	.	.	PUNCT
eurjchem-2489	86	1	the	the	DET
eurjchem-2489	86	2	slight	slight	ADJ
eurjchem-2489	86	3	distortion	distortion	NOUN
eurjchem-2489	86	4	to	to	ADP
eurjchem-2489	86	5	the	the	DET
eurjchem-2489	86	6	square	square	ADJ
eurjchem-2489	86	7	plane	plane	NOUN
eurjchem-2489	86	8	appears	appear	VERB
eurjchem-2489	86	9	through	through	ADP
eurjchem-2489	86	10	the	the	DET
eurjchem-2489	86	11	chelating	chelating	NOUN
eurjchem-2489	86	12	angles	angle	NOUN
eurjchem-2489	86	13	of	of	ADP
eurjchem-2489	86	14	the	the	DET
eurjchem-2489	86	15	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	86	16	ligand	ligand	NOUN
eurjchem-2489	86	17	.	.	PUNCT
eurjchem-2489	87	1	the	the	DET
eurjchem-2489	87	2	crystallographic	crystallographic	ADJ
eurjchem-2489	87	3	refinement	refinement	NOUN
eurjchem-2489	87	4	parameter	parameter	NOUN
eurjchem-2489	87	5	is	be	AUX
eurjchem-2489	87	6	summarized	summarize	VERB
eurjchem-2489	87	7	in	in	ADP
eurjchem-2489	87	8	table	table	NOUN
eurjchem-2489	87	9	1	1	NUM
eurjchem-2489	87	10	.	.	PUNCT
eurjchem-2489	88	1	bond	bond	NOUN
eurjchem-2489	88	2	distances	distance	NOUN
eurjchem-2489	88	3	and	and	CCONJ
eurjchem-2489	88	4	bond	bond	NOUN
eurjchem-2489	88	5	angles	angle	NOUN
eurjchem-2489	88	6	for	for	ADP
eurjchem-2489	88	7	copper(ii	copper(ii	NOUN
eurjchem-2489	88	8	)	)	PUNCT
eurjchem-2489	88	9	complex	complex	NOUN
eurjchem-2489	88	10	are	be	AUX
eurjchem-2489	88	11	given	give	VERB
eurjchem-2489	88	12	in	in	ADP
eurjchem-2489	88	13	tables	table	NOUN
eurjchem-2489	88	14	2	2	NUM
eurjchem-2489	88	15	and	and	CCONJ
eurjchem-2489	88	16	3	3	NUM
eurjchem-2489	88	17	,	,	PUNCT
eurjchem-2489	88	18	respectively	respectively	ADV
eurjchem-2489	88	19	.	.	PUNCT
eurjchem-2489	89	1	the	the	DET
eurjchem-2489	89	2	thermal	thermal	ADJ
eurjchem-2489	89	3	ellipsoidal	ellipsoidal	ADJ
eurjchem-2489	89	4	plot	plot	NOUN
eurjchem-2489	89	5	of	of	ADP
eurjchem-2489	89	6	the	the	DET
eurjchem-2489	89	7	cu	cu	PROPN
eurjchem-2489	89	8	complex	complex	NOUN
eurjchem-2489	89	9	is	be	AUX
eurjchem-2489	89	10	shown	show	VERB
eurjchem-2489	89	11	in	in	ADP
eurjchem-2489	89	12	figure	figure	NOUN
eurjchem-2489	89	13	1	1	NUM
eurjchem-2489	89	14	.	.	PUNCT
eurjchem-2489	89	15	self	self	NOUN
eurjchem-2489	89	16	-	-	PUNCT
eurjchem-2489	89	17	assembly	assembly	NOUN
eurjchem-2489	89	18	analysis	analysis	NOUN
eurjchem-2489	89	19	shows	show	VERB
eurjchem-2489	89	20	a	a	DET
eurjchem-2489	89	21	notable	notable	ADJ
eurjchem-2489	89	22	presence	presence	NOUN
eurjchem-2489	89	23	of	of	ADP
eurjchem-2489	89	24	pmethyl	pmethyl	ADJ
eurjchem-2489	89	25	phenol	phenol	NOUN
eurjchem-2489	89	26	along	along	ADP
eurjchem-2489	89	27	with	with	ADP
eurjchem-2489	89	28	the	the	DET
eurjchem-2489	89	29	copper(ii	copper(ii	NOUN
eurjchem-2489	89	30	)	)	PUNCT
eurjchem-2489	89	31	complex	complex	NOUN
eurjchem-2489	89	32	in	in	ADP
eurjchem-2489	89	33	the	the	DET
eurjchem-2489	89	34	crystalline	crystalline	NOUN
eurjchem-2489	89	35	framework	framework	NOUN
eurjchem-2489	89	36	.	.	PUNCT
eurjchem-2489	90	1	in	in	ADP
eurjchem-2489	90	2	the	the	DET
eurjchem-2489	90	3	crystalline	crystalline	ADJ
eurjchem-2489	90	4	architecture	architecture	NOUN
eurjchem-2489	90	5	of	of	ADP
eurjchem-2489	90	6	the	the	DET
eurjchem-2489	90	7	copper	copper	NOUN
eurjchem-2489	90	8	complex	complex	NOUN
eurjchem-2489	90	9	,	,	PUNCT
eurjchem-2489	90	10	the	the	DET
eurjchem-2489	90	11	crystallized	crystallized	ADJ
eurjchem-2489	90	12	p	p	NOUN
eurjchem-2489	90	13	-	-	PUNCT
eurjchem-2489	90	14	cresol	cresol	NOUN
eurjchem-2489	90	15	forms	form	VERB
eurjchem-2489	90	16	a	a	DET
eurjchem-2489	90	17	very	very	ADV
eurjchem-2489	90	18	strong	strong	ADJ
eurjchem-2489	90	19	intermolecular	intermolecular	ADJ
eurjchem-2489	90	20	h	h	NOUN
eurjchem-2489	90	21	-	-	PUNCT
eurjchem-2489	90	22	bonding	bond	VERB
eurjchem-2489	90	23	network	network	NOUN
eurjchem-2489	90	24	with	with	ADP
eurjchem-2489	90	25	the	the	DET
eurjchem-2489	90	26	copper	copper	NOUN
eurjchem-2489	90	27	complex	complex	NOUN
eurjchem-2489	90	28	ranging	range	VERB
eurjchem-2489	90	29	from	from	ADP
eurjchem-2489	90	30	2.00	2.00	NUM
eurjchem-2489	90	31	to	to	ADP
eurjchem-2489	90	32	2.795	2.795	NUM
eurjchem-2489	90	33	å	å	X
eurjchem-2489	90	34	(	(	PUNCT
eurjchem-2489	90	35	o17	o17	PROPN
eurjchem-2489	90	36	-	-	PUNCT
eurjchem-2489	90	37	h17···o10	h17···o10	NOUN
eurjchem-2489	90	38	)	)	PUNCT
eurjchem-2489	90	39	.	.	PUNCT
eurjchem-2489	91	1	investigation	investigation	NOUN
eurjchem-2489	91	2	of	of	ADP
eurjchem-2489	91	3	the	the	DET
eurjchem-2489	91	4	self	self	NOUN
eurjchem-2489	91	5	-	-	PUNCT
eurjchem-2489	91	6	assembly	assembly	NOUN
eurjchem-2489	91	7	of	of	ADP
eurjchem-2489	91	8	the	the	DET
eurjchem-2489	91	9	copper	copper	NOUN
eurjchem-2489	91	10	complex	complex	NOUN
eurjchem-2489	91	11	exhibits	exhibit	VERB
eurjchem-2489	91	12	non	non	ADJ
eurjchem-2489	91	13	-	-	ADJ
eurjchem-2489	91	14	covalent	covalent	ADJ
eurjchem-2489	91	15	interactions	interaction	NOUN
eurjchem-2489	91	16	such	such	ADJ
eurjchem-2489	91	17	as	as	ADP
eurjchem-2489	91	18	o···h	o···h	NOUN
eurjchem-2489	91	19	and	and	CCONJ
eurjchem-2489	91	20	c	c	NOUN
eurjchem-2489	91	21	-	-	PUNCT
eurjchem-2489	91	22	h···π	h···π	PROPN
eurjchem-2489	91	23	(	(	PUNCT
eurjchem-2489	91	24	table	table	NOUN
eurjchem-2489	91	25	4	4	NUM
eurjchem-2489	91	26	)	)	PUNCT
eurjchem-2489	91	27	is	be	AUX
eurjchem-2489	91	28	responsible	responsible	ADJ
eurjchem-2489	91	29	for	for	ADP
eurjchem-2489	91	30	the	the	DET
eurjchem-2489	91	31	network	network	NOUN
eurjchem-2489	91	32	formation	formation	NOUN
eurjchem-2489	91	33	.	.	PUNCT
eurjchem-2489	92	1	the	the	DET
eurjchem-2489	92	2	mononuclear	mononuclear	ADJ
eurjchem-2489	92	3	copper(ii	copper(ii	PROPN
eurjchem-2489	92	4	)	)	PUNCT
eurjchem-2489	92	5	complex	complex	NOUN
eurjchem-2489	92	6	interacts	interact	VERB
eurjchem-2489	92	7	with	with	ADP
eurjchem-2489	92	8	another	another	DET
eurjchem-2489	92	9	complex	complex	ADJ
eurjchem-2489	92	10	unit	unit	NOUN
eurjchem-2489	92	11	through	through	ADP
eurjchem-2489	92	12	strong	strong	ADJ
eurjchem-2489	92	13	o···h	o···h	NOUN
eurjchem-2489	92	14	and	and	CCONJ
eurjchem-2489	92	15	c	c	NOUN
eurjchem-2489	92	16	-	-	PUNCT
eurjchem-2489	92	17	h···π	h···π	PROPN
eurjchem-2489	92	18	and	and	CCONJ
eurjchem-2489	92	19	seems	seem	VERB
eurjchem-2489	92	20	to	to	PART
eurjchem-2489	92	21	be	be	AUX
eurjchem-2489	92	22	a	a	DET
eurjchem-2489	92	23	complex	complex	ADJ
eurjchem-2489	92	24	dimer	dimer	NOUN
eurjchem-2489	92	25	(	(	PUNCT
eurjchem-2489	92	26	figure	figure	NOUN
eurjchem-2489	92	27	2	2	NUM
eurjchem-2489	92	28	)	)	PUNCT
eurjchem-2489	92	29	.	.	PUNCT
eurjchem-2489	93	1	the	the	DET
eurjchem-2489	93	2	hirshfeld	hirshfeld	PROPN
eurjchem-2489	93	3	surface	surface	NOUN
eurjchem-2489	93	4	analysis	analysis	NOUN
eurjchem-2489	93	5	of	of	ADP
eurjchem-2489	93	6	the	the	DET
eurjchem-2489	93	7	copper(ii	copper(ii	NOUN
eurjchem-2489	93	8	)	)	PUNCT
eurjchem-2489	93	9	complex	complex	NOUN
eurjchem-2489	93	10	over	over	ADP
eurjchem-2489	93	11	a	a	DET
eurjchem-2489	93	12	definite	definite	ADJ
eurjchem-2489	93	13	dnorm	dnorm	NOUN
eurjchem-2489	93	14	was	be	AUX
eurjchem-2489	93	15	calculated	calculate	VERB
eurjchem-2489	93	16	with	with	ADP
eurjchem-2489	93	17	crystal	crystal	PROPN
eurjchem-2489	93	18	explorer	explorer	PROPN
eurjchem-2489	93	19	21	21	NUM
eurjchem-2489	93	20	software	software	NOUN
eurjchem-2489	93	21	[	[	X
eurjchem-2489	93	22	26	26	NUM
eurjchem-2489	93	23	]	]	PUNCT
eurjchem-2489	93	24	.	.	PUNCT
eurjchem-2489	94	1	surface	surface	NOUN
eurjchem-2489	94	2	volume	volume	NOUN
eurjchem-2489	94	3	and	and	CCONJ
eurjchem-2489	94	4	area	area	NOUN
eurjchem-2489	94	5	are	be	AUX
eurjchem-2489	94	6	calculated	calculate	VERB
eurjchem-2489	94	7	as	as	ADP
eurjchem-2489	94	8	281.68	281.68	NUM
eurjchem-2489	94	9	å3	å3	NOUN
eurjchem-2489	94	10	and	and	CCONJ
eurjchem-2489	94	11	282.63	282.63	NUM
eurjchem-2489	94	12	å2	å2	NOUN
eurjchem-2489	94	13	.	.	PUNCT
eurjchem-2489	95	1	the	the	DET
eurjchem-2489	95	2	red	red	ADJ
eurjchem-2489	95	3	highlighted	highlight	VERB
eurjchem-2489	95	4	spots	spot	NOUN
eurjchem-2489	95	5	indicate	indicate	VERB
eurjchem-2489	95	6	the	the	DET
eurjchem-2489	95	7	dnorm	dnorm	ADJ
eurjchem-2489	95	8	area	area	NOUN
eurjchem-2489	95	9	and	and	CCONJ
eurjchem-2489	95	10	present	present	VERB
eurjchem-2489	95	11	close	close	ADJ
eurjchem-2489	95	12	noncovalent	noncovalent	NOUN
eurjchem-2489	95	13	interactions	interaction	NOUN
eurjchem-2489	95	14	in	in	ADP
eurjchem-2489	95	15	the	the	DET
eurjchem-2489	95	16	copper	copper	NOUN
eurjchem-2489	95	17	complex	complex	NOUN
eurjchem-2489	95	18	with	with	ADP
eurjchem-2489	95	19	the	the	DET
eurjchem-2489	95	20	-oh	-oh	ADJ
eurjchem-2489	95	21	group	group	NOUN
eurjchem-2489	95	22	of	of	ADP
eurjchem-2489	95	23	the	the	DET
eurjchem-2489	95	24	p	p	NOUN
eurjchem-2489	95	25	-	-	PUNCT
eurjchem-2489	95	26	cresol	cresol	NOUN
eurjchem-2489	95	27	unit	unit	NOUN
eurjchem-2489	95	28	(	(	PUNCT
eurjchem-2489	95	29	figure	figure	NOUN
eurjchem-2489	95	30	3a	3a	NUM
eurjchem-2489	95	31	)	)	PUNCT
eurjchem-2489	95	32	.	.	PUNCT
eurjchem-2489	96	1	the	the	DET
eurjchem-2489	96	2	contribution	contribution	NOUN
eurjchem-2489	96	3	of	of	ADP
eurjchem-2489	96	4	each	each	DET
eurjchem-2489	96	5	element	element	NOUN
eurjchem-2489	96	6	in	in	ADP
eurjchem-2489	96	7	the	the	DET
eurjchem-2489	96	8	noncovalent	noncovalent	NOUN
eurjchem-2489	96	9	interactions	interaction	NOUN
eurjchem-2489	96	10	is	be	AUX
eurjchem-2489	96	11	given	give	VERB
eurjchem-2489	96	12	in	in	ADP
eurjchem-2489	96	13	table	table	NOUN
eurjchem-2489	96	14	5	5	NUM
eurjchem-2489	96	15	.	.	PUNCT
eurjchem-2489	97	1	the	the	DET
eurjchem-2489	97	2	blue	blue	ADJ
eurjchem-2489	97	3	area	area	NOUN
eurjchem-2489	97	4	in	in	ADP
eurjchem-2489	97	5	the	the	DET
eurjchem-2489	97	6	dnorm	dnorm	NOUN
eurjchem-2489	97	7	cites	cite	VERB
eurjchem-2489	97	8	important	important	ADJ
eurjchem-2489	97	9	ch···π	ch···π	PROPN
eurjchem-2489	97	10	interactions	interaction	NOUN
eurjchem-2489	97	11	between	between	ADP
eurjchem-2489	97	12	the	the	DET
eurjchem-2489	97	13	phenyl	phenyl	NOUN
eurjchem-2489	97	14	centroid	centroid	NOUN
eurjchem-2489	97	15	and	and	CCONJ
eurjchem-2489	97	16	the	the	DET
eurjchem-2489	97	17	h	h	NOUN
eurjchem-2489	97	18	of	of	ADP
eurjchem-2489	97	19	the	the	DET
eurjchem-2489	97	20	c	c	PROPN
eurjchem-2489	97	21	attached	attach	VERB
eurjchem-2489	97	22	to	to	ADP
eurjchem-2489	97	23	the	the	DET
eurjchem-2489	97	24	phenyl	phenyl	NOUN
eurjchem-2489	97	25	and	and	CCONJ
eurjchem-2489	97	26	methyl	methyl	NOUN
eurjchem-2489	97	27	groups	group	NOUN
eurjchem-2489	97	28	.	.	PUNCT
eurjchem-2489	98	1	white	white	ADJ
eurjchem-2489	98	2	areas	area	NOUN
eurjchem-2489	98	3	denote	denote	VERB
eurjchem-2489	98	4	no	no	DET
eurjchem-2489	98	5	interaction	interaction	NOUN
eurjchem-2489	98	6	.	.	PUNCT
eurjchem-2489	99	1	the	the	DET
eurjchem-2489	99	2	interactions	interaction	NOUN
eurjchem-2489	99	3	in	in	ADP
eurjchem-2489	99	4	the	the	DET
eurjchem-2489	99	5	copper(ii	copper(ii	NOUN
eurjchem-2489	99	6	)	)	PUNCT
eurjchem-2489	99	7	complex	complex	NOUN
eurjchem-2489	99	8	are	be	AUX
eurjchem-2489	99	9	obtained	obtain	VERB
eurjchem-2489	99	10	from	from	ADP
eurjchem-2489	99	11	fingerprint	fingerprint	NOUN
eurjchem-2489	99	12	plots	plot	NOUN
eurjchem-2489	99	13	(	(	PUNCT
eurjchem-2489	99	14	table	table	NOUN
eurjchem-2489	99	15	5	5	NUM
eurjchem-2489	99	16	,	,	PUNCT
eurjchem-2489	99	17	figure	figure	NOUN
eurjchem-2489	99	18	4	4	NUM
eurjchem-2489	99	19	)	)	PUNCT
eurjchem-2489	99	20	.	.	PUNCT
eurjchem-2489	100	1	502	502	NUM
eurjchem-2489	100	2	mukherjee	mukherjee	NOUN
eurjchem-2489	100	3	et	et	PROPN
eurjchem-2489	100	4	al	al	PROPN
eurjchem-2489	100	5	.	.	PUNCT
eurjchem-2489	100	6	/	/	SYM
eurjchem-2489	100	7	european	european	PROPN
eurjchem-2489	100	8	journal	journal	PROPN
eurjchem-2489	100	9	of	of	ADP
eurjchem-2489	100	10	chemistry	chemistry	NOUN
eurjchem-2489	100	11	14	14	NUM
eurjchem-2489	100	12	(	(	PUNCT
eurjchem-2489	100	13	4	4	NUM
eurjchem-2489	100	14	)	)	PUNCT
eurjchem-2489	100	15	(	(	PUNCT
eurjchem-2489	100	16	2023	2023	NUM
eurjchem-2489	100	17	)	)	PUNCT
eurjchem-2489	100	18	499	499	NUM
eurjchem-2489	100	19	-	-	SYM
eurjchem-2489	100	20	506	506	NUM
eurjchem-2489	100	21	2023	2023	NUM
eurjchem-2489	100	22	–	–	PUNCT
eurjchem-2489	100	23	european	european	ADJ
eurjchem-2489	100	24	journal	journal	NOUN
eurjchem-2489	100	25	of	of	ADP
eurjchem-2489	100	26	chemistry	chemistry	NOUN
eurjchem-2489	100	27	–	–	PUNCT
eurjchem-2489	100	28	cc	cc	NOUN
eurjchem-2489	100	29	by	by	ADP
eurjchem-2489	100	30	nc	nc	PROPN
eurjchem-2489	100	31	–	–	PUNCT
eurjchem-2489	100	32	doi	doi	NOUN
eurjchem-2489	100	33	:	:	PUNCT
eurjchem-2489	100	34	10.5155	10.5155	NUM
eurjchem-2489	100	35	/	/	SYM
eurjchem-2489	100	36	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	100	37	-	-	PUNCT
eurjchem-2489	100	38	506.2489	506.2489	NUM
eurjchem-2489	100	39	table	table	NOUN
eurjchem-2489	100	40	2	2	NUM
eurjchem-2489	100	41	.	.	PUNCT
eurjchem-2489	100	42	bond	bond	NOUN
eurjchem-2489	100	43	distances	distance	NOUN
eurjchem-2489	100	44	for	for	ADP
eurjchem-2489	100	45	copper(ii	copper(ii	NOUN
eurjchem-2489	100	46	)	)	PUNCT
eurjchem-2489	100	47	complex	complex	NOUN
eurjchem-2489	100	48	(	(	PUNCT
eurjchem-2489	100	49	1	1	NUM
eurjchem-2489	100	50	)	)	PUNCT
eurjchem-2489	100	51	.	.	PUNCT
eurjchem-2489	101	1	atom	atom	NOUN
eurjchem-2489	101	2	atom	atom	NOUN
eurjchem-2489	101	3	length	length	NOUN
eurjchem-2489	101	4	,	,	PUNCT
eurjchem-2489	101	5	å	å	PROPN
eurjchem-2489	101	6	atom	atom	NOUN
eurjchem-2489	101	7	atom	atom	NOUN
eurjchem-2489	101	8	length	length	NOUN
eurjchem-2489	101	9	,	,	PUNCT
eurjchem-2489	101	10	å	å	PROPN
eurjchem-2489	101	11	cu1	cu1	NOUN
eurjchem-2489	101	12	o10	o10	PROPN
eurjchem-2489	101	13	1.928(3	1.928(3	NUM
eurjchem-2489	101	14	)	)	PUNCT
eurjchem-2489	101	15	c11	c11	NOUN
eurjchem-2489	101	16	c12	c12	PROPN
eurjchem-2489	101	17	1.390(5	1.390(5	NUM
eurjchem-2489	101	18	)	)	PUNCT
eurjchem-2489	101	19	cu1	cu1	NOUN
eurjchem-2489	102	1	o101	o101	PROPN
eurjchem-2489	102	2	1.928(3	1.928(3	PROPN
eurjchem-2489	102	3	)	)	PUNCT
eurjchem-2489	102	4	c2	c2	PROPN
eurjchem-2489	102	5	c8	c8	PROPN
eurjchem-2489	102	6	1.423(5	1.423(5	NUM
eurjchem-2489	102	7	)	)	PUNCT
eurjchem-2489	102	8	cu1	cu1	NOUN
eurjchem-2489	102	9	o9	o9	PROPN
eurjchem-2489	102	10	1.899(3	1.899(3	NUM
eurjchem-2489	102	11	)	)	PUNCT
eurjchem-2489	103	1	c2	c2	PROPN
eurjchem-2489	103	2	c7	c7	PROPN
eurjchem-2489	103	3	1.421(5	1.421(5	NUM
eurjchem-2489	103	4	)	)	PUNCT
eurjchem-2489	103	5	cu1	cu1	NOUN
eurjchem-2489	103	6	o91	o91	NOUN
eurjchem-2489	103	7	1.899(3	1.899(3	NUM
eurjchem-2489	103	8	)	)	PUNCT
eurjchem-2489	103	9	c15	c15	PROPN
eurjchem-2489	103	10	c14	c14	PROPN
eurjchem-2489	103	11	1.393(5	1.393(5	NUM
eurjchem-2489	103	12	)	)	PUNCT
eurjchem-2489	103	13	o10	o10	PROPN
eurjchem-2489	103	14	c3	c3	PROPN
eurjchem-2489	103	15	1.312(4	1.312(4	NUM
eurjchem-2489	103	16	)	)	PUNCT
eurjchem-2489	103	17	c7	c7	PROPN
eurjchem-2489	103	18	c6	c6	PROPN
eurjchem-2489	103	19	1.379(6	1.379(6	NUM
eurjchem-2489	103	20	)	)	PUNCT
eurjchem-2489	103	21	o17	o17	PROPN
eurjchem-2489	103	22	c11	c11	NOUN
eurjchem-2489	103	23	1.365(4	1.365(4	NUM
eurjchem-2489	103	24	)	)	PUNCT
eurjchem-2489	103	25	c18	c18	NOUN
eurjchem-2489	103	26	c14	c14	PROPN
eurjchem-2489	103	27	1.510(5	1.510(5	PROPN
eurjchem-2489	103	28	)	)	PUNCT
eurjchem-2489	103	29	o9	o9	PROPN
eurjchem-2489	103	30	c8	c8	PROPN
eurjchem-2489	103	31	1.245(5	1.245(5	NUM
eurjchem-2489	103	32	)	)	PUNCT
eurjchem-2489	103	33	c13	c13	PROPN
eurjchem-2489	103	34	c14	c14	PROPN
eurjchem-2489	103	35	1.395(5	1.395(5	PROPN
eurjchem-2489	103	36	)	)	PUNCT
eurjchem-2489	103	37	c16	c16	PROPN
eurjchem-2489	103	38	c11	c11	PROPN
eurjchem-2489	103	39	1.397(5	1.397(5	NUM
eurjchem-2489	103	40	)	)	PUNCT
eurjchem-2489	103	41	c13	c13	PROPN
eurjchem-2489	103	42	c12	c12	PROPN
eurjchem-2489	103	43	1.398(5	1.398(5	PROPN
eurjchem-2489	103	44	)	)	PUNCT
eurjchem-2489	103	45	c16	c16	PROPN
eurjchem-2489	103	46	c15	c15	PROPN
eurjchem-2489	103	47	1.391(5	1.391(5	NUM
eurjchem-2489	103	48	)	)	PUNCT
eurjchem-2489	103	49	c5	c5	PROPN
eurjchem-2489	103	50	c4	c4	PROPN
eurjchem-2489	103	51	1.379(6	1.379(6	NUM
eurjchem-2489	103	52	)	)	PUNCT
eurjchem-2489	104	1	c3	c3	PROPN
eurjchem-2489	104	2	c2	c2	PROPN
eurjchem-2489	104	3	1.418(5	1.418(5	NUM
eurjchem-2489	104	4	)	)	PUNCT
eurjchem-2489	104	5	c5	c5	PROPN
eurjchem-2489	104	6	c6	c6	PROPN
eurjchem-2489	104	7	1.402(6	1.402(6	NUM
eurjchem-2489	104	8	)	)	PUNCT
eurjchem-2489	104	9	c3	c3	PROPN
eurjchem-2489	104	10	c4	c4	PROPN
eurjchem-2489	104	11	1.415(5	1.415(5	NUM
eurjchem-2489	104	12	)	)	PUNCT
eurjchem-2489	104	13	11	11	NUM
eurjchem-2489	104	14	-	-	SYM
eurjchem-2489	104	15	x	x	NOUN
eurjchem-2489	104	16	,	,	PUNCT
eurjchem-2489	104	17	1	1	NUM
eurjchem-2489	104	18	-	-	SYM
eurjchem-2489	104	19	y	y	NOUN
eurjchem-2489	104	20	,	,	PUNCT
eurjchem-2489	104	21	2	2	NUM
eurjchem-2489	104	22	-	-	PUNCT
eurjchem-2489	104	23	z.	z.	NOUN
eurjchem-2489	104	24	table	table	NOUN
eurjchem-2489	104	25	3	3	NUM
eurjchem-2489	104	26	.	.	PUNCT
eurjchem-2489	104	27	bond	bond	NOUN
eurjchem-2489	104	28	angles	angle	NOUN
eurjchem-2489	104	29	for	for	ADP
eurjchem-2489	104	30	copper(ii	copper(ii	NOUN
eurjchem-2489	104	31	)	)	PUNCT
eurjchem-2489	104	32	complex	complex	NOUN
eurjchem-2489	104	33	(	(	PUNCT
eurjchem-2489	104	34	1	1	NUM
eurjchem-2489	104	35	)	)	PUNCT
eurjchem-2489	104	36	.	.	PUNCT
eurjchem-2489	105	1	atom	atom	NOUN
eurjchem-2489	105	2	atom	atom	NOUN
eurjchem-2489	105	3	atom	atom	NOUN
eurjchem-2489	105	4	angle	angle	NOUN
eurjchem-2489	105	5	,	,	PUNCT
eurjchem-2489	105	6	°	°	ADP
eurjchem-2489	105	7	atom	atom	NOUN
eurjchem-2489	105	8	atom	atom	NOUN
eurjchem-2489	105	9	atom	atom	NOUN
eurjchem-2489	105	10	angle	angle	NOUN
eurjchem-2489	105	11	,	,	PUNCT
eurjchem-2489	105	12	°	°	DET
eurjchem-2489	105	13	o10	o10	NOUN
eurjchem-2489	105	14	cu1	cu1	NOUN
eurjchem-2489	105	15	o101	o101	PROPN
eurjchem-2489	106	1	180.0	180.0	NUM
eurjchem-2489	106	2	c3	c3	PROPN
eurjchem-2489	106	3	c2	c2	PROPN
eurjchem-2489	106	4	c8	c8	PROPN
eurjchem-2489	106	5	122.3(3	122.3(3	NUM
eurjchem-2489	106	6	)	)	PUNCT
eurjchem-2489	106	7	o91	o91	NOUN
eurjchem-2489	106	8	cu1	cu1	NOUN
eurjchem-2489	106	9	o10	o10	NOUN
eurjchem-2489	106	10	86.45(11	86.45(11	NUM
eurjchem-2489	106	11	)	)	PUNCT
eurjchem-2489	107	1	c3	c3	PROPN
eurjchem-2489	107	2	c2	c2	PROPN
eurjchem-2489	107	3	c7	c7	PROPN
eurjchem-2489	107	4	120.8(3	120.8(3	NUM
eurjchem-2489	107	5	)	)	PUNCT
eurjchem-2489	107	6	o9	o9	PROPN
eurjchem-2489	107	7	cu1	cu1	NOUN
eurjchem-2489	107	8	o101	o101	PROPN
eurjchem-2489	107	9	86.45(12	86.45(12	NUM
eurjchem-2489	107	10	)	)	PUNCT
eurjchem-2489	107	11	c7	c7	PROPN
eurjchem-2489	107	12	c2	c2	PROPN
eurjchem-2489	107	13	c8	c8	PROPN
eurjchem-2489	107	14	117.0(3	117.0(3	NUM
eurjchem-2489	107	15	)	)	PUNCT
eurjchem-2489	107	16	o91	o91	NOUN
eurjchem-2489	107	17	cu1	cu1	NOUN
eurjchem-2489	107	18	o101	o101	PROPN
eurjchem-2489	107	19	93.55(12	93.55(12	NUM
eurjchem-2489	107	20	)	)	PUNCT
eurjchem-2489	108	1	c16	c16	PROPN
eurjchem-2489	108	2	c15	c15	PROPN
eurjchem-2489	108	3	c14	c14	PROPN
eurjchem-2489	108	4	121.6(3	121.6(3	PROPN
eurjchem-2489	108	5	)	)	PUNCT
eurjchem-2489	109	1	o9	o9	PROPN
eurjchem-2489	109	2	cu1	cu1	NOUN
eurjchem-2489	109	3	o10	o10	NOUN
eurjchem-2489	109	4	93.55(12	93.55(12	NOUN
eurjchem-2489	109	5	)	)	PUNCT
eurjchem-2489	110	1	o9	o9	PROPN
eurjchem-2489	110	2	c8	c8	PROPN
eurjchem-2489	110	3	c2	c2	PROPN
eurjchem-2489	110	4	127.5(3	127.5(3	NUM
eurjchem-2489	110	5	)	)	PUNCT
eurjchem-2489	110	6	o9	o9	PROPN
eurjchem-2489	110	7	cu1	cu1	NOUN
eurjchem-2489	110	8	o91	o91	PROPN
eurjchem-2489	110	9	180.0	180.0	NUM
eurjchem-2489	110	10	c6	c6	PROPN
eurjchem-2489	110	11	c7	c7	PROPN
eurjchem-2489	110	12	c2	c2	PROPN
eurjchem-2489	110	13	120.5(4	120.5(4	NUM
eurjchem-2489	110	14	)	)	PUNCT
eurjchem-2489	110	15	c3	c3	PROPN
eurjchem-2489	110	16	o10	o10	PROPN
eurjchem-2489	110	17	cu1	cu1	PROPN
eurjchem-2489	110	18	126.2(2	126.2(2	NUM
eurjchem-2489	110	19	)	)	PUNCT
eurjchem-2489	110	20	c14	c14	PROPN
eurjchem-2489	110	21	c13	c13	PROPN
eurjchem-2489	110	22	c12	c12	PROPN
eurjchem-2489	110	23	120.9(3	120.9(3	NUM
eurjchem-2489	110	24	)	)	PUNCT
eurjchem-2489	110	25	c8	c8	PROPN
eurjchem-2489	110	26	o9	o9	PROPN
eurjchem-2489	110	27	cu1	cu1	PROPN
eurjchem-2489	110	28	126.3(3	126.3(3	NUM
eurjchem-2489	110	29	)	)	PUNCT
eurjchem-2489	110	30	c15	c15	PROPN
eurjchem-2489	110	31	c14	c14	PROPN
eurjchem-2489	110	32	c18	c18	PROPN
eurjchem-2489	110	33	120.7(3	120.7(3	NUM
eurjchem-2489	110	34	)	)	PUNCT
eurjchem-2489	110	35	c15	c15	PROPN
eurjchem-2489	110	36	c16	c16	PROPN
eurjchem-2489	110	37	c11	c11	PROPN
eurjchem-2489	110	38	119.6(3	119.6(3	NUM
eurjchem-2489	110	39	)	)	PUNCT
eurjchem-2489	110	40	c15	c15	PROPN
eurjchem-2489	110	41	c14	c14	PROPN
eurjchem-2489	110	42	c13	c13	PROPN
eurjchem-2489	110	43	118.1(3	118.1(3	NUM
eurjchem-2489	110	44	)	)	PUNCT
eurjchem-2489	110	45	o10	o10	PROPN
eurjchem-2489	110	46	c3	c3	PROPN
eurjchem-2489	110	47	c2	c2	PROPN
eurjchem-2489	110	48	123.8(3	123.8(3	PROPN
eurjchem-2489	110	49	)	)	PUNCT
eurjchem-2489	110	50	c13	c13	PROPN
eurjchem-2489	110	51	c14	c14	PROPN
eurjchem-2489	110	52	c18	c18	PROPN
eurjchem-2489	110	53	121.1(3	121.1(3	NUM
eurjchem-2489	110	54	)	)	PUNCT
eurjchem-2489	110	55	o10	o10	PROPN
eurjchem-2489	110	56	c3	c3	PROPN
eurjchem-2489	110	57	c4	c4	PROPN
eurjchem-2489	110	58	119.0(3	119.0(3	NOUN
eurjchem-2489	110	59	)	)	PUNCT
eurjchem-2489	110	60	c4	c4	NOUN
eurjchem-2489	110	61	c5	c5	PROPN
eurjchem-2489	110	62	c6	c6	PROPN
eurjchem-2489	110	63	121.7(4	121.7(4	NUM
eurjchem-2489	110	64	)	)	PUNCT
eurjchem-2489	110	65	c4	c4	NOUN
eurjchem-2489	110	66	c3	c3	PROPN
eurjchem-2489	110	67	c2	c2	PROPN
eurjchem-2489	110	68	117.2(3	117.2(3	NUM
eurjchem-2489	110	69	)	)	PUNCT
eurjchem-2489	110	70	c5	c5	PROPN
eurjchem-2489	110	71	c4	c4	PROPN
eurjchem-2489	110	72	c3	c3	PROPN
eurjchem-2489	110	73	121.1(4	121.1(4	NUM
eurjchem-2489	110	74	)	)	PUNCT
eurjchem-2489	110	75	o17	o17	PROPN
eurjchem-2489	110	76	c11	c11	NOUN
eurjchem-2489	110	77	c16	c16	NOUN
eurjchem-2489	110	78	122.8(3	122.8(3	NUM
eurjchem-2489	110	79	)	)	PUNCT
eurjchem-2489	110	80	c7	c7	PROPN
eurjchem-2489	110	81	c6	c6	PROPN
eurjchem-2489	110	82	c5	c5	PROPN
eurjchem-2489	110	83	118.8(4	118.8(4	NUM
eurjchem-2489	110	84	)	)	PUNCT
eurjchem-2489	110	85	o17	o17	PROPN
eurjchem-2489	110	86	c11	c11	NOUN
eurjchem-2489	110	87	c12	c12	PROPN
eurjchem-2489	110	88	117.6(3	117.6(3	NUM
eurjchem-2489	110	89	)	)	PUNCT
eurjchem-2489	110	90	c11	c11	NOUN
eurjchem-2489	110	91	c12	c12	PROPN
eurjchem-2489	110	92	c13	c13	PROPN
eurjchem-2489	110	93	120.1(3	120.1(3	NUM
eurjchem-2489	110	94	)	)	PUNCT
eurjchem-2489	110	95	c12	c12	PROPN
eurjchem-2489	110	96	c11	c11	NOUN
eurjchem-2489	110	97	c16	c16	PROPN
eurjchem-2489	110	98	119.6(3	119.6(3	NUM
eurjchem-2489	110	99	)	)	PUNCT
eurjchem-2489	110	100	11	11	NUM
eurjchem-2489	110	101	-	-	SYM
eurjchem-2489	110	102	x	x	NOUN
eurjchem-2489	110	103	,	,	PUNCT
eurjchem-2489	110	104	1	1	NUM
eurjchem-2489	110	105	-	-	SYM
eurjchem-2489	110	106	y	y	NOUN
eurjchem-2489	110	107	,	,	PUNCT
eurjchem-2489	110	108	2	2	NUM
eurjchem-2489	110	109	-	-	PUNCT
eurjchem-2489	110	110	z.	z.	NOUN
eurjchem-2489	110	111	table	table	NOUN
eurjchem-2489	110	112	4	4	NUM
eurjchem-2489	110	113	.	.	PUNCT
eurjchem-2489	111	1	hydrogen	hydrogen	NOUN
eurjchem-2489	111	2	bond	bond	NOUN
eurjchem-2489	111	3	and	and	CCONJ
eurjchem-2489	111	4	c	c	NOUN
eurjchem-2489	111	5	–	–	PUNCT
eurjchem-2489	111	6	h···π	h···π	NOUN
eurjchem-2489	111	7	interaction	interaction	NOUN
eurjchem-2489	111	8	parameters	parameter	NOUN
eurjchem-2489	111	9	for	for	ADP
eurjchem-2489	111	10	copper(ii	copper(ii	NOUN
eurjchem-2489	111	11	)	)	PUNCT
eurjchem-2489	111	12	complex	complex	NOUN
eurjchem-2489	111	13	(	(	PUNCT
eurjchem-2489	111	14	å	å	PROPN
eurjchem-2489	111	15	,	,	PUNCT
eurjchem-2489	111	16	°	°	NUM
eurjchem-2489	111	17	)	)	PUNCT
eurjchem-2489	111	18	.	.	PUNCT
eurjchem-2489	112	1	d	d	X
eurjchem-2489	112	2	-	-	PUNCT
eurjchem-2489	112	3	h···a	h···a	ADJ
eurjchem-2489	112	4	d	d	PROPN
eurjchem-2489	112	5	-	-	PUNCT
eurjchem-2489	112	6	h	h	PROPN
eurjchem-2489	112	7	h···a	h···a	PROPN
eurjchem-2489	112	8	d···a	d···a	PROPN
eurjchem-2489	112	9	∠	∠	NOUN
eurjchem-2489	112	10	d	d	PROPN
eurjchem-2489	112	11	-	-	PUNCT
eurjchem-2489	112	12	h···a	h···a	PROPN
eurjchem-2489	112	13	symmetry	symmetry	NOUN
eurjchem-2489	112	14	code	code	NOUN
eurjchem-2489	112	15	o17	o17	NOUN
eurjchem-2489	112	16	–	–	PUNCT
eurjchem-2489	112	17	h17···o10	h17···o10	VERB
eurjchem-2489	112	18	0.8200	0.8200	NUM
eurjchem-2489	112	19	2.0000	2.0000	NUM
eurjchem-2489	112	20	2.795(4	2.795(4	NOUN
eurjchem-2489	112	21	)	)	PUNCT
eurjchem-2489	112	22	165.00	165.00	NUM
eurjchem-2489	112	23	1	1	NUM
eurjchem-2489	112	24	-	-	PUNCT
eurjchem-2489	112	25	x	x	NOUN
eurjchem-2489	112	26	,	,	PUNCT
eurjchem-2489	112	27	-1/2+y	-1/2+y	INTJ
eurjchem-2489	112	28	,	,	PUNCT
eurjchem-2489	112	29	3/2	3/2	NUM
eurjchem-2489	112	30	-	-	PUNCT
eurjchem-2489	112	31	z	z	NOUN
eurjchem-2489	112	32	x	x	NOUN
eurjchem-2489	112	33	-	-	ADJ
eurjchem-2489	112	34	h···cg	h···cg	ADJ
eurjchem-2489	112	35	h···cg	h···cg	PROPN
eurjchem-2489	112	36	x···cg	x···cg	PROPN
eurjchem-2489	112	37	∠	∠	PROPN
eurjchem-2489	112	38	x	x	PROPN
eurjchem-2489	112	39	-	-	ADJ
eurjchem-2489	112	40	h···cg	h···cg	ADJ
eurjchem-2489	112	41	symmetry	symmetry	NOUN
eurjchem-2489	112	42	code	code	NOUN
eurjchem-2489	112	43	c(6)-h(6)···cg(4	c(6)-h(6)···cg(4	NOUN
eurjchem-2489	112	44	)	)	PUNCT
eurjchem-2489	112	45	2.83	2.83	NUM
eurjchem-2489	112	46	3.487(4	3.487(4	NUM
eurjchem-2489	112	47	)	)	PUNCT
eurjchem-2489	112	48	129	129	NUM
eurjchem-2489	112	49	2	2	NUM
eurjchem-2489	112	50	-	-	PUNCT
eurjchem-2489	112	51	x	x	NOUN
eurjchem-2489	112	52	,	,	PUNCT
eurjchem-2489	112	53	1	1	NUM
eurjchem-2489	112	54	-	-	SYM
eurjchem-2489	112	55	y	y	NOUN
eurjchem-2489	112	56	,	,	PUNCT
eurjchem-2489	112	57	1	1	NUM
eurjchem-2489	112	58	-	-	PUNCT
eurjchem-2489	112	59	z	z	NOUN
eurjchem-2489	112	60	c(18)-h(18b)···cg(4	c(18)-h(18b)···cg(4	PROPN
eurjchem-2489	112	61	)	)	PUNCT
eurjchem-2489	112	62	2.99	2.99	NUM
eurjchem-2489	112	63	3.570(4	3.570(4	NUM
eurjchem-2489	112	64	)	)	PUNCT
eurjchem-2489	112	65	120	120	NUM
eurjchem-2489	112	66	x	x	NOUN
eurjchem-2489	112	67	,	,	PUNCT
eurjchem-2489	112	68	1/2	1/2	NUM
eurjchem-2489	112	69	-	-	SYM
eurjchem-2489	112	70	y	y	NOUN
eurjchem-2489	112	71	,	,	PUNCT
eurjchem-2489	112	72	-1/2+z	-1/2+z	PROPN
eurjchem-2489	112	73	figure	figure	NOUN
eurjchem-2489	112	74	2	2	NUM
eurjchem-2489	112	75	.	.	X
eurjchem-2489	113	1	p	p	X
eurjchem-2489	113	2	-	-	PUNCT
eurjchem-2489	113	3	cresol	cresol	NOUN
eurjchem-2489	113	4	mediated	mediate	VERB
eurjchem-2489	113	5	the	the	DET
eurjchem-2489	113	6	supramolecular	supramolecular	ADJ
eurjchem-2489	113	7	framework	framework	NOUN
eurjchem-2489	113	8	of	of	ADP
eurjchem-2489	113	9	the	the	DET
eurjchem-2489	113	10	copper(ii	copper(ii	NOUN
eurjchem-2489	113	11	)	)	PUNCT
eurjchem-2489	113	12	complex	complex	NOUN
eurjchem-2489	113	13	through	through	ADP
eurjchem-2489	113	14	o···h	o···h	NOUN
eurjchem-2489	113	15	and	and	CCONJ
eurjchem-2489	113	16	c	c	NOUN
eurjchem-2489	113	17	–	–	PUNCT
eurjchem-2489	113	18	h···π	h···π	NOUN
eurjchem-2489	113	19	interactions	interaction	NOUN
eurjchem-2489	113	20	.	.	PUNCT
eurjchem-2489	114	1	(	(	PUNCT
eurjchem-2489	114	2	a	a	X
eurjchem-2489	114	3	)	)	PUNCT
eurjchem-2489	114	4	(	(	PUNCT
eurjchem-2489	114	5	b	b	X
eurjchem-2489	114	6	)	)	PUNCT
eurjchem-2489	114	7	(	(	PUNCT
eurjchem-2489	114	8	c	c	X
eurjchem-2489	114	9	)	)	PUNCT
eurjchem-2489	114	10	figure	figure	NOUN
eurjchem-2489	114	11	3	3	NUM
eurjchem-2489	114	12	.	.	PUNCT
eurjchem-2489	115	1	(	(	PUNCT
eurjchem-2489	115	2	a	a	X
eurjchem-2489	115	3	)	)	PUNCT
eurjchem-2489	115	4	the	the	DET
eurjchem-2489	115	5	red	red	ADJ
eurjchem-2489	115	6	highlighted	highlight	VERB
eurjchem-2489	115	7	spots	spot	NOUN
eurjchem-2489	115	8	indicate	indicate	VERB
eurjchem-2489	115	9	the	the	DET
eurjchem-2489	115	10	dnorm	dnorm	ADJ
eurjchem-2489	115	11	area	area	NOUN
eurjchem-2489	115	12	with	with	ADP
eurjchem-2489	115	13	the	the	DET
eurjchem-2489	115	14	closest	close	ADJ
eurjchem-2489	115	15	non	non	ADJ
eurjchem-2489	115	16	-	-	ADJ
eurjchem-2489	115	17	covalent	covalent	ADJ
eurjchem-2489	115	18	interactions	interaction	NOUN
eurjchem-2489	115	19	in	in	ADP
eurjchem-2489	115	20	the	the	DET
eurjchem-2489	115	21	copper(ii	copper(ii	NOUN
eurjchem-2489	115	22	)	)	PUNCT
eurjchem-2489	115	23	complex	complex	NOUN
eurjchem-2489	115	24	with	with	ADP
eurjchem-2489	115	25	the	the	DET
eurjchem-2489	115	26	-oh	-oh	ADJ
eurjchem-2489	115	27	group	group	NOUN
eurjchem-2489	115	28	of	of	ADP
eurjchem-2489	115	29	p	p	PROPN
eurjchem-2489	115	30	-	-	PUNCT
eurjchem-2489	115	31	cresol	cresol	NOUN
eurjchem-2489	115	32	unit	unit	NOUN
eurjchem-2489	115	33	,	,	PUNCT
eurjchem-2489	115	34	(	(	PUNCT
eurjchem-2489	115	35	b	b	X
eurjchem-2489	115	36	)	)	PUNCT
eurjchem-2489	115	37	hirshfeld	hirshfeld	PROPN
eurjchem-2489	115	38	surface	surface	NOUN
eurjchem-2489	115	39	shape	shape	NOUN
eurjchem-2489	115	40	index	index	NOUN
eurjchem-2489	115	41	indicating	indicate	VERB
eurjchem-2489	115	42	the	the	DET
eurjchem-2489	115	43	hs	hs	PROPN
eurjchem-2489	115	44	flatness	flatness	NOUN
eurjchem-2489	115	45	or	or	CCONJ
eurjchem-2489	115	46	curvature	curvature	VERB
eurjchem-2489	115	47	and	and	CCONJ
eurjchem-2489	115	48	(	(	PUNCT
eurjchem-2489	115	49	c	c	X
eurjchem-2489	115	50	)	)	PUNCT
eurjchem-2489	115	51	curvedness	curvedness	ADJ
eurjchem-2489	115	52	of	of	ADP
eurjchem-2489	115	53	the	the	DET
eurjchem-2489	115	54	surface	surface	NOUN
eurjchem-2489	115	55	indicating	indicate	VERB
eurjchem-2489	115	56	concavity	concavity	NOUN
eurjchem-2489	115	57	or	or	CCONJ
eurjchem-2489	115	58	convexity	convexity	NOUN
eurjchem-2489	115	59	of	of	ADP
eurjchem-2489	115	60	the	the	DET
eurjchem-2489	115	61	hirshfeld	hirshfeld	PROPN
eurjchem-2489	115	62	surface	surface	NOUN
eurjchem-2489	115	63	.	.	PUNCT
eurjchem-2489	116	1	mukherjee	mukherjee	PROPN
eurjchem-2489	116	2	et	et	PROPN
eurjchem-2489	116	3	al	al	PROPN
eurjchem-2489	116	4	.	.	PUNCT
eurjchem-2489	116	5	/	/	SYM
eurjchem-2489	116	6	european	european	PROPN
eurjchem-2489	116	7	journal	journal	PROPN
eurjchem-2489	116	8	of	of	ADP
eurjchem-2489	116	9	chemistry	chemistry	NOUN
eurjchem-2489	116	10	14	14	NUM
eurjchem-2489	116	11	(	(	PUNCT
eurjchem-2489	116	12	4	4	NUM
eurjchem-2489	116	13	)	)	PUNCT
eurjchem-2489	116	14	(	(	PUNCT
eurjchem-2489	116	15	2023	2023	NUM
eurjchem-2489	116	16	)	)	PUNCT
eurjchem-2489	116	17	499	499	NUM
eurjchem-2489	116	18	-	-	SYM
eurjchem-2489	116	19	506	506	NUM
eurjchem-2489	116	20	503	503	NUM
eurjchem-2489	116	21	2023	2023	NUM
eurjchem-2489	116	22	–	–	PUNCT
eurjchem-2489	116	23	european	european	ADJ
eurjchem-2489	116	24	journal	journal	NOUN
eurjchem-2489	116	25	of	of	ADP
eurjchem-2489	116	26	chemistry	chemistry	NOUN
eurjchem-2489	116	27	–	–	PUNCT
eurjchem-2489	116	28	cc	cc	NOUN
eurjchem-2489	116	29	by	by	ADP
eurjchem-2489	116	30	nc	nc	PROPN
eurjchem-2489	116	31	–	–	PUNCT
eurjchem-2489	116	32	doi	doi	NOUN
eurjchem-2489	116	33	:	:	PUNCT
eurjchem-2489	116	34	10.5155	10.5155	NUM
eurjchem-2489	116	35	/	/	SYM
eurjchem-2489	116	36	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	116	37	-	-	PUNCT
eurjchem-2489	116	38	506.2489	506.2489	NUM
eurjchem-2489	116	39	table	table	NOUN
eurjchem-2489	116	40	5	5	NUM
eurjchem-2489	116	41	.	.	PUNCT
eurjchem-2489	116	42	percentage	percentage	NOUN
eurjchem-2489	116	43	share	share	NOUN
eurjchem-2489	116	44	of	of	ADP
eurjchem-2489	116	45	the	the	DET
eurjchem-2489	116	46	interaction	interaction	NOUN
eurjchem-2489	116	47	of	of	ADP
eurjchem-2489	116	48	each	each	DET
eurjchem-2489	116	49	atom	atom	NOUN
eurjchem-2489	116	50	with	with	ADP
eurjchem-2489	116	51	other	other	ADJ
eurjchem-2489	116	52	atoms	atom	NOUN
eurjchem-2489	116	53	when	when	SCONJ
eurjchem-2489	116	54	they	they	PRON
eurjchem-2489	116	55	are	be	AUX
eurjchem-2489	116	56	in	in	ADP
eurjchem-2489	116	57	or	or	CCONJ
eurjchem-2489	116	58	out	out	ADP
eurjchem-2489	116	59	of	of	ADP
eurjchem-2489	116	60	the	the	DET
eurjchem-2489	116	61	hirshfeld	hirshfeld	PROPN
eurjchem-2489	116	62	surface	surface	NOUN
eurjchem-2489	116	63	for	for	ADP
eurjchem-2489	116	64	copper(ii	copper(ii	NOUN
eurjchem-2489	116	65	)	)	PUNCT
eurjchem-2489	116	66	complex	complex	NOUN
eurjchem-2489	116	67	.	.	PUNCT
eurjchem-2489	117	1	inside	inside	ADP
eurjchem-2489	117	2	outside	outside	ADP
eurjchem-2489	117	3	%	%	NOUN
eurjchem-2489	117	4	surface	surface	NOUN
eurjchem-2489	117	5	area	area	NOUN
eurjchem-2489	117	6	included	include	VERB
eurjchem-2489	117	7	inside	inside	ADP
eurjchem-2489	117	8	outside	outside	ADP
eurjchem-2489	117	9	%	%	NOUN
eurjchem-2489	117	10	surface	surface	NOUN
eurjchem-2489	117	11	area	area	NOUN
eurjchem-2489	117	12	included	include	VERB
eurjchem-2489	117	13	all	all	DET
eurjchem-2489	117	14	all	all	DET
eurjchem-2489	117	15	100.0	100.0	NUM
eurjchem-2489	117	16	cu	cu	NOUN
eurjchem-2489	117	17	o	o	NOUN
eurjchem-2489	117	18	0.0	0.0	NUM
eurjchem-2489	117	19	all	all	PRON
eurjchem-2489	117	20	cu	cu	PROPN
eurjchem-2489	117	21	2.6	2.6	NUM
eurjchem-2489	117	22	c	c	NOUN
eurjchem-2489	117	23	c	c	PROPN
eurjchem-2489	117	24	3.4	3.4	NUM
eurjchem-2489	117	25	all	all	PRON
eurjchem-2489	117	26	c	c	PROPN
eurjchem-2489	117	27	17.9	17.9	NUM
eurjchem-2489	117	28	c	c	NOUN
eurjchem-2489	117	29	h	h	NOUN
eurjchem-2489	117	30	13.1	13.1	NUM
eurjchem-2489	118	1	all	all	PRON
eurjchem-2489	118	2	h	h	VERB
eurjchem-2489	119	1	67.9	67.9	NUM
eurjchem-2489	119	2	c	c	NOUN
eurjchem-2489	119	3	o	o	NOUN
eurjchem-2489	119	4	4.3	4.3	NUM
eurjchem-2489	119	5	all	all	PRON
eurjchem-2489	119	6	o	o	PROPN
eurjchem-2489	119	7	11.6	11.6	NUM
eurjchem-2489	119	8	h	h	NOUN
eurjchem-2489	119	9	h	h	NOUN
eurjchem-2489	119	10	40.3	40.3	NUM
eurjchem-2489	119	11	cu	cu	NOUN
eurjchem-2489	119	12	c	c	PROPN
eurjchem-2489	119	13	2.6	2.6	NUM
eurjchem-2489	119	14	h	h	NOUN
eurjchem-2489	119	15	o	o	NOUN
eurjchem-2489	119	16	7.2	7.2	NUM
eurjchem-2489	119	17	cu	cu	NOUN
eurjchem-2489	119	18	h	h	NOUN
eurjchem-2489	120	1	0.1	0.1	NUM
eurjchem-2489	120	2	o	o	NOUN
eurjchem-2489	120	3	o	o	NOUN
eurjchem-2489	120	4	0.1	0.1	NUM
eurjchem-2489	120	5	figure	figure	NOUN
eurjchem-2489	120	6	4	4	NUM
eurjchem-2489	120	7	.	.	NOUN
eurjchem-2489	120	8	2	2	NUM
eurjchem-2489	120	9	-	-	PUNCT
eurjchem-2489	120	10	dimensional	dimensional	ADJ
eurjchem-2489	120	11	fingerprint	fingerprint	NOUN
eurjchem-2489	120	12	plots	plot	NOUN
eurjchem-2489	120	13	of	of	ADP
eurjchem-2489	120	14	the	the	DET
eurjchem-2489	120	15	copper(ii	copper(ii	NOUN
eurjchem-2489	120	16	)	)	PUNCT
eurjchem-2489	120	17	complex	complex	NOUN
eurjchem-2489	120	18	(	(	PUNCT
eurjchem-2489	120	19	1	1	NUM
eurjchem-2489	120	20	)	)	PUNCT
eurjchem-2489	120	21	.	.	PUNCT
eurjchem-2489	121	1	3.3	3.3	NUM
eurjchem-2489	121	2	.	.	PUNCT
eurjchem-2489	122	1	solution	solution	NOUN
eurjchem-2489	122	2	property	property	NOUN
eurjchem-2489	122	3	of	of	ADP
eurjchem-2489	122	4	the	the	DET
eurjchem-2489	122	5	copper(ii	copper(ii	NOUN
eurjchem-2489	122	6	)	)	PUNCT
eurjchem-2489	122	7	complex	complex	NOUN
eurjchem-2489	122	8	the	the	DET
eurjchem-2489	122	9	cu(ii	cu(ii	PROPN
eurjchem-2489	122	10	)	)	PUNCT
eurjchem-2489	122	11	complex	complex	NOUN
eurjchem-2489	122	12	displayed	display	VERB
eurjchem-2489	122	13	the	the	DET
eurjchem-2489	122	14	electronic	electronic	ADJ
eurjchem-2489	122	15	bands	band	NOUN
eurjchem-2489	122	16	at	at	ADP
eurjchem-2489	122	17	315	315	NUM
eurjchem-2489	122	18	and	and	CCONJ
eurjchem-2489	122	19	382	382	NUM
eurjchem-2489	122	20	nm	nm	NOUN
eurjchem-2489	122	21	in	in	ADP
eurjchem-2489	122	22	acn	acn	PROPN
eurjchem-2489	122	23	at	at	ADP
eurjchem-2489	122	24	room	room	NOUN
eurjchem-2489	122	25	temperature	temperature	NOUN
eurjchem-2489	122	26	.	.	PUNCT
eurjchem-2489	123	1	the	the	DET
eurjchem-2489	123	2	electronic	electronic	ADJ
eurjchem-2489	123	3	bands	band	NOUN
eurjchem-2489	123	4	at	at	ADP
eurjchem-2489	123	5	315	315	NUM
eurjchem-2489	123	6	and	and	CCONJ
eurjchem-2489	123	7	382	382	NUM
eurjchem-2489	123	8	nm	nm	NOUN
eurjchem-2489	123	9	in	in	ADP
eurjchem-2489	123	10	the	the	DET
eurjchem-2489	123	11	complex	complex	NOUN
eurjchem-2489	123	12	can	can	AUX
eurjchem-2489	123	13	be	be	AUX
eurjchem-2489	123	14	assigned	assign	VERB
eurjchem-2489	123	15	to	to	ADP
eurjchem-2489	123	16	the	the	DET
eurjchem-2489	123	17	presence	presence	NOUN
eurjchem-2489	123	18	of	of	ADP
eurjchem-2489	123	19	π	π	PROPN
eurjchem-2489	123	20	→	→	SYM
eurjchem-2489	123	21	π	π	PROPN
eurjchem-2489	123	22	*	*	PUNCT
eurjchem-2489	123	23	and	and	CCONJ
eurjchem-2489	123	24	charge	charge	NOUN
eurjchem-2489	123	25	transfer	transfer	NOUN
eurjchem-2489	123	26	(	(	PUNCT
eurjchem-2489	123	27	ct	ct	NOUN
eurjchem-2489	123	28	)	)	PUNCT
eurjchem-2489	123	29	transitions	transition	NOUN
eurjchem-2489	123	30	,	,	PUNCT
eurjchem-2489	123	31	respectively	respectively	ADV
eurjchem-2489	123	32	[	[	X
eurjchem-2489	123	33	2,3	2,3	NUM
eurjchem-2489	123	34	]	]	PUNCT
eurjchem-2489	123	35	.	.	PUNCT
eurjchem-2489	124	1	3.4	3.4	NUM
eurjchem-2489	124	2	.	.	PUNCT
eurjchem-2489	124	3	catecholase	catecholase	NOUN
eurjchem-2489	124	4	activity	activity	NOUN
eurjchem-2489	124	5	of	of	ADP
eurjchem-2489	124	6	the	the	DET
eurjchem-2489	124	7	copper(ii	copper(ii	NOUN
eurjchem-2489	124	8	)	)	PUNCT
eurjchem-2489	124	9	complex	complex	NOUN
eurjchem-2489	124	10	the	the	DET
eurjchem-2489	124	11	catecholase	catecholase	NOUN
eurjchem-2489	124	12	-	-	PUNCT
eurjchem-2489	124	13	mimicking	mimic	VERB
eurjchem-2489	124	14	activity	activity	NOUN
eurjchem-2489	124	15	of	of	ADP
eurjchem-2489	124	16	the	the	DET
eurjchem-2489	124	17	synthetic	synthetic	ADJ
eurjchem-2489	124	18	copper(ii	copper(ii	NOUN
eurjchem-2489	124	19	)	)	PUNCT
eurjchem-2489	124	20	complex	complex	NOUN
eurjchem-2489	124	21	has	have	AUX
eurjchem-2489	124	22	been	be	AUX
eurjchem-2489	124	23	examined	examine	VERB
eurjchem-2489	124	24	by	by	ADP
eurjchem-2489	124	25	considering	consider	VERB
eurjchem-2489	124	26	3,5dtbc	3,5dtbc	NUM
eurjchem-2489	124	27	as	as	ADP
eurjchem-2489	124	28	a	a	DET
eurjchem-2489	124	29	model	model	NOUN
eurjchem-2489	124	30	substrate	substrate	NOUN
eurjchem-2489	124	31	.	.	PUNCT
eurjchem-2489	125	1	dtbc	dtbc	PROPN
eurjchem-2489	125	2	contains	contain	VERB
eurjchem-2489	125	3	two	two	NUM
eurjchem-2489	125	4	bulky	bulky	ADJ
eurjchem-2489	125	5	t	t	NOUN
eurjchem-2489	125	6	-	-	PUNCT
eurjchem-2489	125	7	butyl	butyl	NOUN
eurjchem-2489	125	8	substituents	substituent	NOUN
eurjchem-2489	125	9	at	at	ADP
eurjchem-2489	125	10	the	the	DET
eurjchem-2489	125	11	phenyl	phenyl	NOUN
eurjchem-2489	125	12	ring	ring	NOUN
eurjchem-2489	125	13	and	and	CCONJ
eurjchem-2489	125	14	helps	help	VERB
eurjchem-2489	125	15	to	to	PART
eurjchem-2489	125	16	lower	lower	VERB
eurjchem-2489	125	17	the	the	DET
eurjchem-2489	125	18	quinonecatechol	quinonecatechol	NOUN
eurjchem-2489	125	19	reduction	reduction	NOUN
eurjchem-2489	125	20	potential	potential	NOUN
eurjchem-2489	125	21	.	.	PUNCT
eurjchem-2489	126	1	the	the	DET
eurjchem-2489	126	2	low	low	ADJ
eurjchem-2489	126	3	quinone	quinone	NOUN
eurjchem-2489	126	4	-	-	PUNCT
eurjchem-2489	126	5	catechol	catechol	NOUN
eurjchem-2489	126	6	reduction	reduction	NOUN
eurjchem-2489	126	7	potential	potential	NOUN
eurjchem-2489	126	8	facilitates	facilitate	VERB
eurjchem-2489	126	9	the	the	DET
eurjchem-2489	126	10	oxidation	oxidation	NOUN
eurjchem-2489	126	11	of	of	ADP
eurjchem-2489	126	12	catechol	catechol	NOUN
eurjchem-2489	126	13	to	to	ADP
eurjchem-2489	126	14	the	the	DET
eurjchem-2489	126	15	corresponding	corresponding	ADJ
eurjchem-2489	126	16	o	o	NOUN
eurjchem-2489	126	17	-	-	NOUN
eurjchem-2489	126	18	quinone	quinone	ADJ
eurjchem-2489	126	19	,	,	PUNCT
eurjchem-2489	126	20	dtbq	dtbq	NOUN
eurjchem-2489	126	21	under	under	ADP
eurjchem-2489	126	22	ambient	ambient	ADJ
eurjchem-2489	126	23	reaction	reaction	NOUN
eurjchem-2489	126	24	conditions	condition	NOUN
eurjchem-2489	126	25	(	(	PUNCT
eurjchem-2489	126	26	scheme	scheme	NOUN
eurjchem-2489	126	27	2	2	NUM
eurjchem-2489	126	28	)	)	PUNCT
eurjchem-2489	126	29	.	.	PUNCT
eurjchem-2489	127	1	it	it	PRON
eurjchem-2489	127	2	is	be	AUX
eurjchem-2489	127	3	well	well	ADV
eurjchem-2489	127	4	documented	document	VERB
eurjchem-2489	127	5	that	that	SCONJ
eurjchem-2489	127	6	dtbq	dtbq	NOUN
eurjchem-2489	127	7	is	be	AUX
eurjchem-2489	127	8	quite	quite	ADV
eurjchem-2489	127	9	stable	stable	ADJ
eurjchem-2489	127	10	in	in	ADP
eurjchem-2489	127	11	solution	solution	NOUN
eurjchem-2489	127	12	and	and	CCONJ
eurjchem-2489	127	13	displays	display	VERB
eurjchem-2489	127	14	a	a	DET
eurjchem-2489	127	15	characteristic	characteristic	ADJ
eurjchem-2489	127	16	absorption	absorption	NOUN
eurjchem-2489	127	17	peak	peak	NOUN
eurjchem-2489	127	18	at	at	ADP
eurjchem-2489	127	19	401	401	NUM
eurjchem-2489	127	20	nm	nm	NOUN
eurjchem-2489	127	21	in	in	ADP
eurjchem-2489	127	22	acetonitrile	acetonitrile	NOUN
eurjchem-2489	128	1	[	[	X
eurjchem-2489	128	2	3	3	NUM
eurjchem-2489	128	3	]	]	PUNCT
eurjchem-2489	128	4	.	.	PUNCT
eurjchem-2489	129	1	the	the	DET
eurjchem-2489	129	2	nature	nature	NOUN
eurjchem-2489	129	3	of	of	ADP
eurjchem-2489	129	4	the	the	DET
eurjchem-2489	129	5	changes	change	NOUN
eurjchem-2489	129	6	in	in	ADP
eurjchem-2489	129	7	the	the	DET
eurjchem-2489	129	8	spectral	spectral	ADJ
eurjchem-2489	129	9	bands	band	NOUN
eurjchem-2489	129	10	during	during	ADP
eurjchem-2489	129	11	catalytic	catalytic	ADJ
eurjchem-2489	129	12	oxidation	oxidation	NOUN
eurjchem-2489	129	13	was	be	AUX
eurjchem-2489	129	14	monitored	monitor	VERB
eurjchem-2489	129	15	with	with	ADP
eurjchem-2489	129	16	a	a	DET
eurjchem-2489	129	17	uv	uv	NOUN
eurjchem-2489	129	18	-	-	PUNCT
eurjchem-2489	129	19	vis	vis	X
eurjchem-2489	129	20	spectrophotometer	spectrophotometer	NOUN
eurjchem-2489	129	21	for	for	ADP
eurjchem-2489	129	22	a	a	DET
eurjchem-2489	129	23	1.5	1.5	NUM
eurjchem-2489	129	24	h	h	NOUN
eurjchem-2489	129	25	period	period	NOUN
eurjchem-2489	129	26	(	(	PUNCT
eurjchem-2489	129	27	figure	figure	NOUN
eurjchem-2489	129	28	5	5	NUM
eurjchem-2489	129	29	)	)	PUNCT
eurjchem-2489	129	30	.	.	PUNCT
eurjchem-2489	130	1	the	the	DET
eurjchem-2489	130	2	copper	copper	NOUN
eurjchem-2489	130	3	complex	complex	NOUN
eurjchem-2489	130	4	displays	display	VERB
eurjchem-2489	130	5	a	a	DET
eurjchem-2489	130	6	characteristic	characteristic	ADJ
eurjchem-2489	130	7	electronic	electronic	ADJ
eurjchem-2489	130	8	transition	transition	NOUN
eurjchem-2489	130	9	at	at	ADP
eurjchem-2489	130	10	378	378	NUM
eurjchem-2489	130	11	nm	nm	NOUN
eurjchem-2489	130	12	.	.	PUNCT
eurjchem-2489	131	1	upon	upon	SCONJ
eurjchem-2489	131	2	the	the	DET
eurjchem-2489	131	3	addition	addition	NOUN
eurjchem-2489	131	4	of	of	ADP
eurjchem-2489	131	5	the	the	DET
eurjchem-2489	131	6	cu(ii	cu(ii	PROPN
eurjchem-2489	131	7	)	)	PUNCT
eurjchem-2489	131	8	complex	complex	NOUN
eurjchem-2489	131	9	to	to	ADP
eurjchem-2489	131	10	the	the	DET
eurjchem-2489	131	11	dtbc	dtbc	PROPN
eurjchem-2489	131	12	solution	solution	NOUN
eurjchem-2489	131	13	,	,	PUNCT
eurjchem-2489	131	14	a	a	DET
eurjchem-2489	131	15	new	new	ADJ
eurjchem-2489	131	16	electronic	electronic	ADJ
eurjchem-2489	131	17	band	band	NOUN
eurjchem-2489	131	18	at	at	ADP
eurjchem-2489	131	19	400	400	NUM
eurjchem-2489	131	20	nm	nm	PRON
eurjchem-2489	131	21	started	start	VERB
eurjchem-2489	131	22	to	to	PART
eurjchem-2489	131	23	develop	develop	VERB
eurjchem-2489	131	24	with	with	ADP
eurjchem-2489	131	25	increasing	increase	VERB
eurjchem-2489	131	26	absorbance	absorbance	NOUN
eurjchem-2489	131	27	(	(	PUNCT
eurjchem-2489	131	28	figure	figure	NOUN
eurjchem-2489	131	29	5	5	NUM
eurjchem-2489	131	30	)	)	PUNCT
eurjchem-2489	131	31	.	.	PUNCT
eurjchem-2489	132	1	the	the	DET
eurjchem-2489	132	2	rise	rise	NOUN
eurjchem-2489	132	3	of	of	ADP
eurjchem-2489	132	4	the	the	DET
eurjchem-2489	132	5	optical	optical	ADJ
eurjchem-2489	132	6	band	band	NOUN
eurjchem-2489	132	7	at	at	ADP
eurjchem-2489	132	8	400	400	NUM
eurjchem-2489	132	9	nm	nm	NOUN
eurjchem-2489	132	10	is	be	AUX
eurjchem-2489	132	11	a	a	DET
eurjchem-2489	132	12	definite	definite	ADJ
eurjchem-2489	132	13	signature	signature	NOUN
eurjchem-2489	132	14	of	of	ADP
eurjchem-2489	132	15	the	the	DET
eurjchem-2489	132	16	oxidation	oxidation	NOUN
eurjchem-2489	132	17	of	of	ADP
eurjchem-2489	132	18	dtbc	dtbc	PROPN
eurjchem-2489	132	19	in	in	ADP
eurjchem-2489	132	20	acn	acn	PROPN
eurjchem-2489	132	21	.	.	PUNCT
eurjchem-2489	133	1	interestingly	interestingly	ADV
eurjchem-2489	133	2	,	,	PUNCT
eurjchem-2489	133	3	a	a	DET
eurjchem-2489	133	4	new	new	ADJ
eurjchem-2489	133	5	optical	optical	ADJ
eurjchem-2489	133	6	band	band	NOUN
eurjchem-2489	133	7	also	also	ADV
eurjchem-2489	133	8	appeared	appear	VERB
eurjchem-2489	133	9	at	at	ADP
eurjchem-2489	133	10	551	551	NUM
eurjchem-2489	133	11	nm	nm	NOUN
eurjchem-2489	133	12	with	with	ADP
eurjchem-2489	133	13	a	a	DET
eurjchem-2489	133	14	decrease	decrease	NOUN
eurjchem-2489	133	15	of	of	ADP
eurjchem-2489	133	16	the	the	DET
eurjchem-2489	133	17	absorbance	absorbance	NOUN
eurjchem-2489	133	18	for	for	ADP
eurjchem-2489	133	19	the	the	DET
eurjchem-2489	133	20	electronic	electronic	ADJ
eurjchem-2489	133	21	band	band	NOUN
eurjchem-2489	133	22	at	at	ADP
eurjchem-2489	133	23	700	700	NUM
eurjchem-2489	133	24	nm	nm	NOUN
eurjchem-2489	133	25	.	.	PUNCT
eurjchem-2489	134	1	the	the	DET
eurjchem-2489	134	2	appearance	appearance	NOUN
eurjchem-2489	134	3	and	and	CCONJ
eurjchem-2489	134	4	disappearance	disappearance	NOUN
eurjchem-2489	134	5	of	of	ADP
eurjchem-2489	134	6	the	the	DET
eurjchem-2489	134	7	electronic	electronic	ADJ
eurjchem-2489	134	8	bands	band	NOUN
eurjchem-2489	134	9	occurred	occur	VERB
eurjchem-2489	134	10	through	through	ADP
eurjchem-2489	134	11	the	the	DET
eurjchem-2489	134	12	existence	existence	NOUN
eurjchem-2489	134	13	of	of	ADP
eurjchem-2489	134	14	an	an	DET
eurjchem-2489	134	15	isobestic	isobestic	ADJ
eurjchem-2489	134	16	point	point	NOUN
eurjchem-2489	134	17	at	at	ADP
eurjchem-2489	134	18	605	605	NUM
eurjchem-2489	134	19	nm	nm	NOUN
eurjchem-2489	134	20	,	,	PUNCT
eurjchem-2489	134	21	ensuring	ensure	VERB
eurjchem-2489	134	22	an	an	DET
eurjchem-2489	134	23	equilibrium	equilibrium	NOUN
eurjchem-2489	134	24	between	between	ADP
eurjchem-2489	134	25	the	the	DET
eurjchem-2489	134	26	copper	copper	NOUN
eurjchem-2489	134	27	complex	complex	ADJ
eurjchem-2489	134	28	-	-	PUNCT
eurjchem-2489	134	29	dtbc	dtbc	ADJ
eurjchem-2489	134	30	adducts	adduct	NOUN
eurjchem-2489	134	31	and	and	CCONJ
eurjchem-2489	134	32	the	the	DET
eurjchem-2489	134	33	copper	copper	NOUN
eurjchem-2489	134	34	complex	complex	ADJ
eurjchem-2489	134	35	-	-	PUNCT
eurjchem-2489	134	36	semibenzoquinonate	semibenzoquinonate	NOUN
eurjchem-2489	134	37	species	specie	NOUN
eurjchem-2489	134	38	[	[	X
eurjchem-2489	134	39	6,27	6,27	NUM
eurjchem-2489	134	40	]	]	PUNCT
eurjchem-2489	134	41	.	.	PUNCT
eurjchem-2489	135	1	the	the	DET
eurjchem-2489	135	2	appearance	appearance	NOUN
eurjchem-2489	135	3	of	of	ADP
eurjchem-2489	135	4	this	this	DET
eurjchem-2489	135	5	new	new	ADJ
eurjchem-2489	135	6	electronic	electronic	ADJ
eurjchem-2489	135	7	band	band	NOUN
eurjchem-2489	135	8	at	at	ADP
eurjchem-2489	135	9	400	400	NUM
eurjchem-2489	135	10	nm	nm	NOUN
eurjchem-2489	135	11	in	in	ADP
eurjchem-2489	135	12	the	the	DET
eurjchem-2489	135	13	spectrophotometric	spectrophotometric	ADJ
eurjchem-2489	135	14	scan	scan	NOUN
eurjchem-2489	135	15	is	be	AUX
eurjchem-2489	135	16	assigned	assign	VERB
eurjchem-2489	135	17	to	to	ADP
eurjchem-2489	135	18	the	the	DET
eurjchem-2489	135	19	production	production	NOUN
eurjchem-2489	135	20	of	of	ADP
eurjchem-2489	135	21	obenzoquinone	obenzoquinone	ADJ
eurjchem-2489	135	22	species	specie	NOUN
eurjchem-2489	135	23	in	in	ADP
eurjchem-2489	135	24	acn	acn	PROPN
eurjchem-2489	135	25	.	.	PUNCT
eurjchem-2489	136	1	the	the	DET
eurjchem-2489	136	2	kinetics	kinetic	NOUN
eurjchem-2489	136	3	of	of	ADP
eurjchem-2489	136	4	the	the	DET
eurjchem-2489	136	5	catalytic	catalytic	ADJ
eurjchem-2489	136	6	oxidation	oxidation	NOUN
eurjchem-2489	136	7	of	of	ADP
eurjchem-2489	136	8	dtbc	dtbc	PROPN
eurjchem-2489	136	9	was	be	AUX
eurjchem-2489	136	10	studied	study	VERB
eurjchem-2489	136	11	to	to	PART
eurjchem-2489	136	12	determine	determine	VERB
eurjchem-2489	136	13	the	the	DET
eurjchem-2489	136	14	catalytic	catalytic	ADJ
eurjchem-2489	136	15	performance	performance	NOUN
eurjchem-2489	136	16	of	of	ADP
eurjchem-2489	136	17	the	the	DET
eurjchem-2489	136	18	copper(ii	copper(ii	NOUN
eurjchem-2489	136	19	)	)	PUNCT
eurjchem-2489	136	20	complex	complex	NOUN
eurjchem-2489	136	21	.	.	PUNCT
eurjchem-2489	137	1	the	the	DET
eurjchem-2489	137	2	kinetic	kinetic	ADJ
eurjchem-2489	137	3	parameter	parameter	NOUN
eurjchem-2489	137	4	of	of	ADP
eurjchem-2489	137	5	the	the	DET
eurjchem-2489	137	6	catalytic	catalytic	ADJ
eurjchem-2489	137	7	oxidation	oxidation	NOUN
eurjchem-2489	137	8	of	of	ADP
eurjchem-2489	137	9	dtbc	dtbc	PROPN
eurjchem-2489	137	10	was	be	AUX
eurjchem-2489	137	11	evaluated	evaluate	VERB
eurjchem-2489	137	12	employing	employ	VERB
eurjchem-2489	137	13	the	the	DET
eurjchem-2489	137	14	method	method	NOUN
eurjchem-2489	137	15	of	of	ADP
eurjchem-2489	137	16	the	the	DET
eurjchem-2489	137	17	initial	initial	ADJ
eurjchem-2489	137	18	rate	rate	NOUN
eurjchem-2489	137	19	.	.	PUNCT
eurjchem-2489	138	1	the	the	DET
eurjchem-2489	138	2	growth	growth	NOUN
eurjchem-2489	138	3	of	of	ADP
eurjchem-2489	138	4	o	o	NOUN
eurjchem-2489	138	5	-	-	NOUN
eurjchem-2489	138	6	benzoquinone	benzoquinone	NOUN
eurjchem-2489	138	7	was	be	AUX
eurjchem-2489	138	8	monitored	monitor	VERB
eurjchem-2489	138	9	as	as	ADP
eurjchem-2489	138	10	a	a	DET
eurjchem-2489	138	11	function	function	NOUN
eurjchem-2489	138	12	of	of	ADP
eurjchem-2489	138	13	time	time	NOUN
eurjchem-2489	138	14	with	with	ADP
eurjchem-2489	138	15	respect	respect	NOUN
eurjchem-2489	138	16	to	to	ADP
eurjchem-2489	138	17	400	400	NUM
eurjchem-2489	138	18	nm	nm	NOUN
eurjchem-2489	138	19	(	(	PUNCT
eurjchem-2489	138	20	figure	figure	NOUN
eurjchem-2489	138	21	5	5	NUM
eurjchem-2489	138	22	)	)	PUNCT
eurjchem-2489	139	1	[	[	X
eurjchem-2489	139	2	25	25	NUM
eurjchem-2489	139	3	]	]	PUNCT
eurjchem-2489	139	4	.	.	PUNCT
eurjchem-2489	140	1	the	the	DET
eurjchem-2489	140	2	nature	nature	NOUN
eurjchem-2489	140	3	of	of	ADP
eurjchem-2489	140	4	oxidation	oxidation	NOUN
eurjchem-2489	140	5	kinetics	kinetic	NOUN
eurjchem-2489	140	6	was	be	AUX
eurjchem-2489	140	7	examined	examine	VERB
eurjchem-2489	140	8	by	by	ADP
eurjchem-2489	140	9	plotting	plot	VERB
eurjchem-2489	140	10	the	the	DET
eurjchem-2489	140	11	rate	rate	NOUN
eurjchem-2489	140	12	constants	constant	NOUN
eurjchem-2489	140	13	vs.	vs.	ADP
eurjchem-2489	140	14	the	the	DET
eurjchem-2489	140	15	concentration	concentration	NOUN
eurjchem-2489	140	16	of	of	ADP
eurjchem-2489	140	17	dtbc	dtbc	PROPN
eurjchem-2489	140	18	as	as	SCONJ
eurjchem-2489	140	19	shown	show	VERB
eurjchem-2489	140	20	in	in	ADP
eurjchem-2489	140	21	figure	figure	NOUN
eurjchem-2489	140	22	5	5	NUM
eurjchem-2489	140	23	.	.	PUNCT
eurjchem-2489	141	1	the	the	DET
eurjchem-2489	141	2	firstorder	firstorder	NOUN
eurjchem-2489	141	3	saturation	saturation	NOUN
eurjchem-2489	141	4	kinetics	kinetic	NOUN
eurjchem-2489	141	5	of	of	ADP
eurjchem-2489	141	6	the	the	DET
eurjchem-2489	141	7	oxidation	oxidation	NOUN
eurjchem-2489	141	8	reaction	reaction	NOUN
eurjchem-2489	141	9	seems	seem	VERB
eurjchem-2489	141	10	to	to	PART
eurjchem-2489	141	11	be	be	AUX
eurjchem-2489	141	12	suitable	suitable	ADJ
eurjchem-2489	141	13	in	in	ADP
eurjchem-2489	141	14	the	the	DET
eurjchem-2489	141	15	michaelis	michaelis	PROPN
eurjchem-2489	141	16	–	–	PUNCT
eurjchem-2489	141	17	menten	menten	ADJ
eurjchem-2489	141	18	model	model	NOUN
eurjchem-2489	141	19	and	and	CCONJ
eurjchem-2489	141	20	can	can	AUX
eurjchem-2489	141	21	be	be	AUX
eurjchem-2489	141	22	expressed	express	VERB
eurjchem-2489	141	23	as	as	ADP
eurjchem-2489	141	24	equation	equation	NOUN
eurjchem-2489	141	25	(	(	PUNCT
eurjchem-2489	141	26	1	1	NUM
eurjchem-2489	141	27	):	):	PUNCT
eurjchem-2489	141	28	(	(	PUNCT
eurjchem-2489	141	29	1	1	X
eurjchem-2489	141	30	)	)	PUNCT
eurjchem-2489	141	31	where	where	SCONJ
eurjchem-2489	141	32	v	v	NOUN
eurjchem-2489	141	33	indicates	indicate	VERB
eurjchem-2489	141	34	the	the	DET
eurjchem-2489	141	35	rate	rate	NOUN
eurjchem-2489	141	36	of	of	ADP
eurjchem-2489	141	37	the	the	DET
eurjchem-2489	141	38	oxidation	oxidation	NOUN
eurjchem-2489	141	39	reaction	reaction	NOUN
eurjchem-2489	141	40	,	,	PUNCT
eurjchem-2489	141	41	km	km	PROPN
eurjchem-2489	141	42	denotes	denote	VERB
eurjchem-2489	141	43	the	the	DET
eurjchem-2489	141	44	michaelis	michaeli	NOUN
eurjchem-2489	141	45	-	-	PUNCT
eurjchem-2489	141	46	menten	menten	VERB
eurjchem-2489	141	47	constant	constant	ADJ
eurjchem-2489	141	48	,	,	PUNCT
eurjchem-2489	141	49	vmax	vmax	PROPN
eurjchem-2489	141	50	presents	present	VERB
eurjchem-2489	141	51	the	the	DET
eurjchem-2489	141	52	maximum	maximum	ADJ
eurjchem-2489	141	53	velocity	velocity	NOUN
eurjchem-2489	141	54	of	of	ADP
eurjchem-2489	141	55	the	the	DET
eurjchem-2489	141	56	reaction	reaction	NOUN
eurjchem-2489	141	57	,	,	PUNCT
eurjchem-2489	141	58	and	and	CCONJ
eurjchem-2489	141	59	[	[	X
eurjchem-2489	141	60	s	s	X
eurjchem-2489	141	61	]	]	X
eurjchem-2489	141	62	is	be	AUX
eurjchem-2489	141	63	the	the	DET
eurjchem-2489	141	64	concentration	concentration	NOUN
eurjchem-2489	141	65	of	of	ADP
eurjchem-2489	141	66	the	the	DET
eurjchem-2489	141	67	dtbc	dtbc	PROPN
eurjchem-2489	141	68	.	.	PUNCT
eurjchem-2489	142	1	the	the	DET
eurjchem-2489	142	2	values	value	NOUN
eurjchem-2489	142	3	of	of	ADP
eurjchem-2489	142	4	the	the	DET
eurjchem-2489	142	5	kinetic	kinetic	ADJ
eurjchem-2489	142	6	parameters	parameter	NOUN
eurjchem-2489	142	7	were	be	AUX
eurjchem-2489	142	8	determined	determine	VERB
eurjchem-2489	142	9	from	from	ADP
eurjchem-2489	142	10	the	the	DET
eurjchem-2489	142	11	michaelis	michaeli	NOUN
eurjchem-2489	142	12	-	-	PUNCT
eurjchem-2489	142	13	menten	menten	ADJ
eurjchem-2489	142	14	equation	equation	NOUN
eurjchem-2489	142	15	as	as	ADP
eurjchem-2489	142	16	vmax	vmax	PROPN
eurjchem-2489	142	17	(	(	PUNCT
eurjchem-2489	142	18	ms-1	ms-1	ADJ
eurjchem-2489	142	19	)	)	PUNCT
eurjchem-2489	142	20	=	=	SYM
eurjchem-2489	142	21	6.26×10	6.26×10	X
eurjchem-2489	142	22	-	-	PUNCT
eurjchem-2489	142	23	4	4	NUM
eurjchem-2489	142	24	;	;	PUNCT
eurjchem-2489	142	25	km	km	NOUN
eurjchem-2489	142	26	=	=	SYM
eurjchem-2489	143	1	3.80×10	3.80×10	NUM
eurjchem-2489	143	2	-	-	SYM
eurjchem-2489	143	3	3	3	NUM
eurjchem-2489	143	4	[	[	X
eurjchem-2489	143	5	std	std	NOUN
eurjchem-2489	143	6	.	.	NOUN
eurjchem-2489	143	7	error	error	NOUN
eurjchem-2489	143	8	for	for	ADP
eurjchem-2489	143	9	vmax	vmax	PROPN
eurjchem-2489	143	10	(	(	PUNCT
eurjchem-2489	143	11	ms-1	ms-1	ADJ
eurjchem-2489	143	12	)	)	PUNCT
eurjchem-2489	143	13	=	=	PUNCT
eurjchem-2489	144	1	3.40×10	3.40×10	NUM
eurjchem-2489	144	2	-	-	SYM
eurjchem-2489	144	3	5	5	NUM
eurjchem-2489	144	4	;	;	PUNCT
eurjchem-2489	144	5	std	std	NOUN
eurjchem-2489	144	6	.	.	NOUN
eurjchem-2489	144	7	error	error	NOUN
eurjchem-2489	144	8	for	for	ADP
eurjchem-2489	144	9	km	km	PROPN
eurjchem-2489	144	10	(	(	PUNCT
eurjchem-2489	144	11	m)=	m)=	NOUN
eurjchem-2489	144	12	5.49×10	5.49×10	NUM
eurjchem-2489	144	13	-	-	SYM
eurjchem-2489	144	14	4	4	NUM
eurjchem-2489	144	15	]	]	PUNCT
eurjchem-2489	144	16	.	.	PUNCT
eurjchem-2489	145	1	504	504	NUM
eurjchem-2489	145	2	mukherjee	mukherjee	NOUN
eurjchem-2489	145	3	et	et	PROPN
eurjchem-2489	145	4	al	al	PROPN
eurjchem-2489	145	5	.	.	PUNCT
eurjchem-2489	145	6	/	/	SYM
eurjchem-2489	145	7	european	european	PROPN
eurjchem-2489	145	8	journal	journal	PROPN
eurjchem-2489	145	9	of	of	ADP
eurjchem-2489	145	10	chemistry	chemistry	NOUN
eurjchem-2489	145	11	14	14	NUM
eurjchem-2489	145	12	(	(	PUNCT
eurjchem-2489	145	13	4	4	NUM
eurjchem-2489	145	14	)	)	PUNCT
eurjchem-2489	145	15	(	(	PUNCT
eurjchem-2489	145	16	2023	2023	NUM
eurjchem-2489	145	17	)	)	PUNCT
eurjchem-2489	145	18	499	499	NUM
eurjchem-2489	145	19	-	-	SYM
eurjchem-2489	145	20	506	506	NUM
eurjchem-2489	145	21	2023	2023	NUM
eurjchem-2489	145	22	–	–	PUNCT
eurjchem-2489	145	23	european	european	ADJ
eurjchem-2489	145	24	journal	journal	NOUN
eurjchem-2489	145	25	of	of	ADP
eurjchem-2489	145	26	chemistry	chemistry	NOUN
eurjchem-2489	145	27	–	–	PUNCT
eurjchem-2489	145	28	cc	cc	NOUN
eurjchem-2489	145	29	by	by	ADP
eurjchem-2489	145	30	nc	nc	PROPN
eurjchem-2489	145	31	–	–	PUNCT
eurjchem-2489	145	32	doi	doi	NOUN
eurjchem-2489	145	33	:	:	PUNCT
eurjchem-2489	145	34	10.5155	10.5155	NUM
eurjchem-2489	145	35	/	/	SYM
eurjchem-2489	145	36	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	145	37	-	-	SYM
eurjchem-2489	145	38	506.2489	506.2489	NUM
eurjchem-2489	146	1	oh	oh	INTJ
eurjchem-2489	146	2	oh	oh	INTJ
eurjchem-2489	146	3	o	o	INTJ
eurjchem-2489	146	4	ocu(ii	ocu(ii	NOUN
eurjchem-2489	146	5	)	)	PUNCT
eurjchem-2489	146	6	catalyst	catalyst	NOUN
eurjchem-2489	146	7	scheme	scheme	NOUN
eurjchem-2489	146	8	2	2	NUM
eurjchem-2489	146	9	.	.	PUNCT
eurjchem-2489	146	10	catalytic	catalytic	ADJ
eurjchem-2489	146	11	oxidation	oxidation	NOUN
eurjchem-2489	146	12	of	of	ADP
eurjchem-2489	146	13	dtbc	dtbc	PROPN
eurjchem-2489	146	14	to	to	PART
eurjchem-2489	146	15	dtbq	dtbq	VERB
eurjchem-2489	146	16	.	.	PUNCT
eurjchem-2489	147	1	(	(	PUNCT
eurjchem-2489	147	2	a	a	X
eurjchem-2489	147	3	)	)	PUNCT
eurjchem-2489	147	4	(	(	PUNCT
eurjchem-2489	147	5	b	b	X
eurjchem-2489	147	6	)	)	PUNCT
eurjchem-2489	147	7	(	(	PUNCT
eurjchem-2489	147	8	c	c	X
eurjchem-2489	147	9	)	)	PUNCT
eurjchem-2489	147	10	(	(	PUNCT
eurjchem-2489	147	11	d	d	X
eurjchem-2489	147	12	)	)	PUNCT
eurjchem-2489	147	13	figure	figure	NOUN
eurjchem-2489	147	14	5	5	NUM
eurjchem-2489	147	15	.	.	PUNCT
eurjchem-2489	148	1	(	(	PUNCT
eurjchem-2489	148	2	a	a	X
eurjchem-2489	148	3	)	)	PUNCT
eurjchem-2489	148	4	rise	rise	NOUN
eurjchem-2489	148	5	of	of	ADP
eurjchem-2489	148	6	a	a	DET
eurjchem-2489	148	7	new	new	ADJ
eurjchem-2489	148	8	electronic	electronic	ADJ
eurjchem-2489	148	9	band	band	NOUN
eurjchem-2489	148	10	at	at	ADP
eurjchem-2489	148	11	400	400	NUM
eurjchem-2489	148	12	nm	nm	NOUN
eurjchem-2489	148	13	after	after	ADP
eurjchem-2489	148	14	addition	addition	NOUN
eurjchem-2489	148	15	of	of	ADP
eurjchem-2489	148	16	dtbc	dtbc	PROPN
eurjchem-2489	148	17	to	to	ADP
eurjchem-2489	148	18	the	the	DET
eurjchem-2489	148	19	copper	copper	NOUN
eurjchem-2489	148	20	(	(	PUNCT
eurjchem-2489	148	21	ii	ii	NOUN
eurjchem-2489	148	22	)	)	PUNCT
eurjchem-2489	148	23	complex	complex	NOUN
eurjchem-2489	148	24	in	in	ADP
eurjchem-2489	148	25	acn	acn	PROPN
eurjchem-2489	148	26	with	with	ADP
eurjchem-2489	148	27	a	a	DET
eurjchem-2489	148	28	time	time	NOUN
eurjchem-2489	148	29	interval	interval	NOUN
eurjchem-2489	148	30	of	of	ADP
eurjchem-2489	148	31	5	5	NUM
eurjchem-2489	148	32	min	min	NOUN
eurjchem-2489	148	33	,	,	PUNCT
eurjchem-2489	148	34	(	(	PUNCT
eurjchem-2489	148	35	b	b	NOUN
eurjchem-2489	148	36	)	)	PUNCT
eurjchem-2489	148	37	time	time	NOUN
eurjchem-2489	148	38	vs	vs	ADP
eurjchem-2489	148	39	absorbance	absorbance	NOUN
eurjchem-2489	148	40	plot	plot	NOUN
eurjchem-2489	148	41	at	at	ADP
eurjchem-2489	148	42	400	400	NUM
eurjchem-2489	148	43	nm	nm	NOUN
eurjchem-2489	148	44	,	,	PUNCT
eurjchem-2489	148	45	(	(	PUNCT
eurjchem-2489	148	46	c	c	NOUN
eurjchem-2489	148	47	)	)	PUNCT
eurjchem-2489	148	48	rate	rate	NOUN
eurjchem-2489	148	49	vs	vs	ADP
eurjchem-2489	148	50	[	[	X
eurjchem-2489	148	51	dtbc	dtbc	X
eurjchem-2489	148	52	]	]	X
eurjchem-2489	148	53	plot	plot	NOUN
eurjchem-2489	148	54	and	and	CCONJ
eurjchem-2489	148	55	(	(	PUNCT
eurjchem-2489	148	56	d	d	NOUN
eurjchem-2489	148	57	)	)	PUNCT
eurjchem-2489	148	58	1	1	NUM
eurjchem-2489	148	59	/	/	SYM
eurjchem-2489	148	60	rate	rate	NOUN
eurjchem-2489	148	61	vs	vs	ADP
eurjchem-2489	148	62	1	1	NUM
eurjchem-2489	148	63	/	/	SYM
eurjchem-2489	148	64	dtbc	dtbc	ADJ
eurjchem-2489	148	65	plots	plot	NOUN
eurjchem-2489	148	66	.	.	PUNCT
eurjchem-2489	149	1	the	the	DET
eurjchem-2489	149	2	catalyst	catalyst	NOUN
eurjchem-2489	149	3	turnover	turnover	NOUN
eurjchem-2489	149	4	number	number	NOUN
eurjchem-2489	149	5	for	for	ADP
eurjchem-2489	149	6	the	the	DET
eurjchem-2489	149	7	catalyst	catalyst	NOUN
eurjchem-2489	149	8	was	be	AUX
eurjchem-2489	149	9	found	find	VERB
eurjchem-2489	149	10	to	to	PART
eurjchem-2489	149	11	be	be	AUX
eurjchem-2489	149	12	2.26×104	2.26×104	NUM
eurjchem-2489	149	13	h-1	h-1	NOUN
eurjchem-2489	149	14	.	.	PUNCT
eurjchem-2489	150	1	the	the	DET
eurjchem-2489	150	2	catalytic	catalytic	ADJ
eurjchem-2489	150	3	efficiency	efficiency	NOUN
eurjchem-2489	150	4	for	for	ADP
eurjchem-2489	150	5	the	the	DET
eurjchem-2489	150	6	catalytic	catalytic	ADJ
eurjchem-2489	150	7	oxidation	oxidation	NOUN
eurjchem-2489	150	8	of	of	ADP
eurjchem-2489	150	9	dtbc	dtbc	PROPN
eurjchem-2489	150	10	was	be	AUX
eurjchem-2489	150	11	determined	determine	VERB
eurjchem-2489	150	12	as	as	ADP
eurjchem-2489	150	13	kcat	kcat	NOUN
eurjchem-2489	150	14	/	/	SYM
eurjchem-2489	150	15	km	km	NOUN
eurjchem-2489	150	16	=	=	SYM
eurjchem-2489	150	17	5.94×105	5.94×105	NUM
eurjchem-2489	150	18	.	.	PUNCT
eurjchem-2489	151	1	the	the	DET
eurjchem-2489	151	2	redox	redox	ADJ
eurjchem-2489	151	3	activities	activity	NOUN
eurjchem-2489	151	4	of	of	ADP
eurjchem-2489	151	5	the	the	DET
eurjchem-2489	151	6	copper	copper	NOUN
eurjchem-2489	151	7	complex	complex	NOUN
eurjchem-2489	151	8	and	and	CCONJ
eurjchem-2489	151	9	its	its	PRON
eurjchem-2489	151	10	activities	activity	NOUN
eurjchem-2489	151	11	toward	toward	ADP
eurjchem-2489	151	12	the	the	DET
eurjchem-2489	151	13	biomimetics	biomimetic	NOUN
eurjchem-2489	151	14	of	of	ADP
eurjchem-2489	151	15	catecholase	catecholase	NOUN
eurjchem-2489	151	16	activities	activity	NOUN
eurjchem-2489	151	17	were	be	AUX
eurjchem-2489	151	18	studied	study	VERB
eurjchem-2489	151	19	by	by	ADP
eurjchem-2489	151	20	electrochemical	electrochemical	ADJ
eurjchem-2489	151	21	analysis	analysis	NOUN
eurjchem-2489	151	22	in	in	ADP
eurjchem-2489	151	23	ch3cn	ch3cn	NUM
eurjchem-2489	151	24	at	at	ADP
eurjchem-2489	151	25	295	295	NUM
eurjchem-2489	151	26	k.	k.	NOUN
eurjchem-2489	152	1	the	the	DET
eurjchem-2489	152	2	redox	redox	ADJ
eurjchem-2489	152	3	behavior	behavior	NOUN
eurjchem-2489	152	4	of	of	ADP
eurjchem-2489	152	5	the	the	DET
eurjchem-2489	152	6	copper	copper	NOUN
eurjchem-2489	152	7	complex	complex	NOUN
eurjchem-2489	152	8	was	be	AUX
eurjchem-2489	152	9	recorded	record	VERB
eurjchem-2489	152	10	using	use	VERB
eurjchem-2489	152	11	ag	ag	PROPN
eurjchem-2489	152	12	/	/	SYM
eurjchem-2489	152	13	agcl	agcl	ADJ
eurjchem-2489	152	14	reference	reference	NOUN
eurjchem-2489	152	15	under	under	ADP
eurjchem-2489	152	16	an	an	DET
eurjchem-2489	152	17	aerobic	aerobic	ADJ
eurjchem-2489	152	18	atmosphere	atmosphere	NOUN
eurjchem-2489	152	19	.	.	PUNCT
eurjchem-2489	153	1	the	the	DET
eurjchem-2489	153	2	cyclic	cyclic	ADJ
eurjchem-2489	153	3	voltammograms	voltammogram	NOUN
eurjchem-2489	153	4	are	be	AUX
eurjchem-2489	153	5	illustrated	illustrate	VERB
eurjchem-2489	153	6	in	in	ADP
eurjchem-2489	153	7	figure	figure	NOUN
eurjchem-2489	153	8	6	6	NUM
eurjchem-2489	153	9	.	.	PUNCT
eurjchem-2489	154	1	the	the	DET
eurjchem-2489	154	2	copper(ii	copper(ii	NOUN
eurjchem-2489	154	3	)	)	PUNCT
eurjchem-2489	154	4	complex	complex	NOUN
eurjchem-2489	154	5	exhibits	exhibit	VERB
eurjchem-2489	154	6	two	two	NUM
eurjchem-2489	154	7	distinct	distinct	ADJ
eurjchem-2489	154	8	cathodic	cathodic	NOUN
eurjchem-2489	154	9	waves	wave	NOUN
eurjchem-2489	154	10	at	at	ADP
eurjchem-2489	154	11	-0.97	-0.97	NOUN
eurjchem-2489	154	12	and	and	CCONJ
eurjchem-2489	154	13	-1.18	-1.18	NOUN
eurjchem-2489	154	14	v	v	NOUN
eurjchem-2489	154	15	,	,	PUNCT
eurjchem-2489	154	16	corresponding	correspond	VERB
eurjchem-2489	154	17	to	to	ADP
eurjchem-2489	154	18	cu2+/cu+	cu2+/cu+	NOUN
eurjchem-2489	154	19	and	and	CCONJ
eurjchem-2489	154	20	cu+/cu0	cu+/cu0	NOUN
eurjchem-2489	154	21	redox	redox	ADJ
eurjchem-2489	154	22	couples	couple	NOUN
eurjchem-2489	154	23	,	,	PUNCT
eurjchem-2489	154	24	respectively	respectively	ADV
eurjchem-2489	154	25	,	,	PUNCT
eurjchem-2489	154	26	in	in	ADP
eurjchem-2489	154	27	solution	solution	NOUN
eurjchem-2489	154	28	.	.	PUNCT
eurjchem-2489	155	1	notably	notably	ADV
eurjchem-2489	155	2	,	,	PUNCT
eurjchem-2489	155	3	the	the	DET
eurjchem-2489	155	4	appearance	appearance	NOUN
eurjchem-2489	155	5	of	of	ADP
eurjchem-2489	155	6	the	the	DET
eurjchem-2489	155	7	anodic	anodic	ADJ
eurjchem-2489	155	8	waves	wave	NOUN
eurjchem-2489	155	9	at	at	ADP
eurjchem-2489	155	10	+1.37	+1.37	PROPN
eurjchem-2489	155	11	and	and	CCONJ
eurjchem-2489	155	12	+1.56	+1.56	PROPN
eurjchem-2489	155	13	v	v	NOUN
eurjchem-2489	155	14	can	can	AUX
eurjchem-2489	155	15	be	be	AUX
eurjchem-2489	155	16	attributed	attribute	VERB
eurjchem-2489	155	17	to	to	ADP
eurjchem-2489	155	18	the	the	DET
eurjchem-2489	155	19	phenoxide	phenoxide	NOUN
eurjchem-2489	155	20	/	/	SYM
eurjchem-2489	155	21	phenoxide	phenoxide	NOUN
eurjchem-2489	155	22	anion	anion	NOUN
eurjchem-2489	155	23	radical	radical	ADJ
eurjchem-2489	155	24	(	(	PUNCT
eurjchem-2489	155	25	o−/o∙−	o−/o∙−	NOUN
eurjchem-2489	155	26	)	)	PUNCT
eurjchem-2489	155	27	redox	redox	ADJ
eurjchem-2489	155	28	couples	couple	NOUN
eurjchem-2489	155	29	of	of	ADP
eurjchem-2489	155	30	the	the	DET
eurjchem-2489	155	31	chelated	chelate	VERB
eurjchem-2489	155	32	-	-	NOUN
eurjchem-2489	155	33	salicylaldehyde	salicylaldehyde	NOUN
eurjchem-2489	155	34	in	in	ADP
eurjchem-2489	155	35	the	the	DET
eurjchem-2489	155	36	copper	copper	NOUN
eurjchem-2489	155	37	and	and	CCONJ
eurjchem-2489	155	38	free	free	ADJ
eurjchem-2489	155	39	p	p	NOUN
eurjchem-2489	155	40	-	-	PUNCT
eurjchem-2489	155	41	cresol	cresol	NOUN
eurjchem-2489	155	42	cocrystallized	cocrystallize	VERB
eurjchem-2489	155	43	with	with	ADP
eurjchem-2489	155	44	the	the	DET
eurjchem-2489	155	45	complex	complex	NOUN
eurjchem-2489	155	46	.	.	PUNCT
eurjchem-2489	156	1	the	the	DET
eurjchem-2489	156	2	catecholase	catecholase	NOUN
eurjchem-2489	156	3	activity	activity	NOUN
eurjchem-2489	156	4	was	be	AUX
eurjchem-2489	156	5	authenticated	authenticate	VERB
eurjchem-2489	156	6	by	by	ADP
eurjchem-2489	156	7	the	the	DET
eurjchem-2489	156	8	change	change	NOUN
eurjchem-2489	156	9	in	in	ADP
eurjchem-2489	156	10	cyclic	cyclic	ADJ
eurjchem-2489	156	11	voltammograms	voltammogram	NOUN
eurjchem-2489	156	12	of	of	ADP
eurjchem-2489	156	13	the	the	DET
eurjchem-2489	156	14	copper	copper	NOUN
eurjchem-2489	156	15	complex	complex	NOUN
eurjchem-2489	156	16	upon	upon	SCONJ
eurjchem-2489	156	17	sequential	sequential	ADJ
eurjchem-2489	156	18	addition	addition	NOUN
eurjchem-2489	156	19	of	of	ADP
eurjchem-2489	156	20	dtbc	dtbc	PROPN
eurjchem-2489	156	21	in	in	ADP
eurjchem-2489	156	22	ch3cn	ch3cn	NOUN
eurjchem-2489	156	23	at	at	ADP
eurjchem-2489	156	24	295	295	NUM
eurjchem-2489	156	25	k.	k.	NOUN
eurjchem-2489	156	26	cyclic	cyclic	PROPN
eurjchem-2489	156	27	voltammograms	voltammogram	NOUN
eurjchem-2489	156	28	of	of	ADP
eurjchem-2489	156	29	the	the	DET
eurjchem-2489	156	30	copper	copper	NOUN
eurjchem-2489	156	31	complex	complex	NOUN
eurjchem-2489	156	32	after	after	SCONJ
eurjchem-2489	156	33	gradual	gradual	ADJ
eurjchem-2489	156	34	addition	addition	NOUN
eurjchem-2489	156	35	of	of	ADP
eurjchem-2489	156	36	dtbc	dtbc	PROPN
eurjchem-2489	156	37	displayed	display	VERB
eurjchem-2489	156	38	the	the	DET
eurjchem-2489	156	39	shift	shift	NOUN
eurjchem-2489	156	40	of	of	ADP
eurjchem-2489	156	41	the	the	DET
eurjchem-2489	156	42	cathodic	cathodic	NOUN
eurjchem-2489	156	43	wave	wave	NOUN
eurjchem-2489	156	44	at	at	ADP
eurjchem-2489	156	45	-1.18	-1.18	ADP
eurjchem-2489	156	46	to	to	PART
eurjchem-2489	156	47	-1.61	-1.61	ADJ
eurjchem-2489	156	48	v	v	NOUN
eurjchem-2489	156	49	,	,	PUNCT
eurjchem-2489	156	50	while	while	SCONJ
eurjchem-2489	156	51	the	the	DET
eurjchem-2489	156	52	wave	wave	NOUN
eurjchem-2489	156	53	at	at	ADP
eurjchem-2489	156	54	-0.97	-0.97	NOUN
eurjchem-2489	156	55	v	v	NOUN
eurjchem-2489	156	56	due	due	ADP
eurjchem-2489	156	57	to	to	ADP
eurjchem-2489	156	58	cu(ii)/cu(i	cu(ii)/cu(i	NOUN
eurjchem-2489	156	59	)	)	PUNCT
eurjchem-2489	156	60	species	specie	NOUN
eurjchem-2489	156	61	gets	get	AUX
eurjchem-2489	156	62	diminished	diminish	VERB
eurjchem-2489	156	63	.	.	PUNCT
eurjchem-2489	157	1	in	in	ADP
eurjchem-2489	157	2	contrast	contrast	NOUN
eurjchem-2489	157	3	,	,	PUNCT
eurjchem-2489	157	4	the	the	DET
eurjchem-2489	157	5	replicate	replicate	ADJ
eurjchem-2489	157	6	cathodic	cathodic	NOUN
eurjchem-2489	157	7	waves	wave	NOUN
eurjchem-2489	157	8	at	at	ADP
eurjchem-2489	157	9	-0.45	-0.45	NUM
eurjchem-2489	157	10	v	v	NOUN
eurjchem-2489	157	11	and	and	CCONJ
eurjchem-2489	157	12	the	the	DET
eurjchem-2489	157	13	replicate	replicate	ADJ
eurjchem-2489	157	14	anodic	anodic	ADJ
eurjchem-2489	157	15	peak	peak	NOUN
eurjchem-2489	157	16	at	at	ADP
eurjchem-2489	157	17	0.45	0.45	NUM
eurjchem-2489	157	18	v	v	NOUN
eurjchem-2489	157	19	newly	newly	ADV
eurjchem-2489	157	20	appeared	appear	VERB
eurjchem-2489	157	21	which	which	PRON
eurjchem-2489	157	22	is	be	AUX
eurjchem-2489	157	23	assignable	assignable	ADJ
eurjchem-2489	157	24	to	to	ADP
eurjchem-2489	157	25	the	the	DET
eurjchem-2489	157	26	cat	cat	NOUN
eurjchem-2489	157	27	/	/	SYM
eurjchem-2489	157	28	sq	sq	ADJ
eurjchem-2489	157	29	redox	redox	ADJ
eurjchem-2489	157	30	couple	couple	NOUN
eurjchem-2489	157	31	(	(	PUNCT
eurjchem-2489	157	32	cat	cat	NOUN
eurjchem-2489	157	33	=	=	SYM
eurjchem-2489	157	34	catechol	catechol	NOUN
eurjchem-2489	157	35	,	,	PUNCT
eurjchem-2489	157	36	sq	sq	NOUN
eurjchem-2489	157	37	=	=	ADJ
eurjchem-2489	157	38	o	o	NOUN
eurjchem-2489	157	39	-	-	NOUN
eurjchem-2489	157	40	benzosemiquinone	benzosemiquinone	NOUN
eurjchem-2489	157	41	and	and	CCONJ
eurjchem-2489	157	42	isq	isq	PROPN
eurjchem-2489	157	43	=	=	SYM
eurjchem-2489	157	44	oiminobenzosemiquinone	oiminobenzosemiquinone	PROPN
eurjchem-2489	157	45	)	)	PUNCT
eurjchem-2489	157	46	.	.	PUNCT
eurjchem-2489	158	1	this	this	DET
eurjchem-2489	158	2	peak	peak	NOUN
eurjchem-2489	158	3	is	be	AUX
eurjchem-2489	158	4	a	a	DET
eurjchem-2489	158	5	definite	definite	ADJ
eurjchem-2489	158	6	sign	sign	NOUN
eurjchem-2489	158	7	of	of	ADP
eurjchem-2489	158	8	the	the	DET
eurjchem-2489	158	9	oxidation	oxidation	NOUN
eurjchem-2489	158	10	of	of	ADP
eurjchem-2489	158	11	dtbc	dtbc	PROPN
eurjchem-2489	158	12	.	.	PUNCT
eurjchem-2489	159	1	the	the	DET
eurjchem-2489	159	2	disappearance	disappearance	NOUN
eurjchem-2489	159	3	of	of	ADP
eurjchem-2489	159	4	the	the	DET
eurjchem-2489	159	5	cu2+/cu+	cu2+/cu+	NOUN
eurjchem-2489	159	6	peak	peak	NOUN
eurjchem-2489	159	7	indicates	indicate	VERB
eurjchem-2489	159	8	the	the	DET
eurjchem-2489	159	9	involvement	involvement	NOUN
eurjchem-2489	159	10	of	of	ADP
eurjchem-2489	159	11	cu2	cu2	NOUN
eurjchem-2489	159	12	+	+	X
eurjchem-2489	159	13	in	in	ADP
eurjchem-2489	159	14	the	the	DET
eurjchem-2489	159	15	oxidation	oxidation	NOUN
eurjchem-2489	159	16	processes	process	NOUN
eurjchem-2489	159	17	[	[	X
eurjchem-2489	159	18	5	5	NUM
eurjchem-2489	159	19	]	]	PUNCT
eurjchem-2489	159	20	.	.	PUNCT
eurjchem-2489	160	1	further	far	ADV
eurjchem-2489	160	2	,	,	PUNCT
eurjchem-2489	160	3	the	the	DET
eurjchem-2489	160	4	chemical	chemical	ADJ
eurjchem-2489	160	5	fate	fate	NOUN
eurjchem-2489	160	6	of	of	ADP
eurjchem-2489	160	7	molecular	molecular	ADJ
eurjchem-2489	160	8	oxygen	oxygen	NOUN
eurjchem-2489	160	9	in	in	ADP
eurjchem-2489	160	10	the	the	DET
eurjchem-2489	160	11	participation	participation	NOUN
eurjchem-2489	160	12	of	of	ADP
eurjchem-2489	160	13	dtbc	dtbc	PROPN
eurjchem-2489	160	14	oxidation	oxidation	NOUN
eurjchem-2489	160	15	was	be	AUX
eurjchem-2489	160	16	assessed	assess	VERB
eurjchem-2489	160	17	from	from	ADP
eurjchem-2489	160	18	the	the	DET
eurjchem-2489	160	19	production	production	NOUN
eurjchem-2489	160	20	of	of	ADP
eurjchem-2489	160	21	hydrogen	hydrogen	NOUN
eurjchem-2489	160	22	peroxide	peroxide	NOUN
eurjchem-2489	160	23	[	[	X
eurjchem-2489	160	24	28	28	NUM
eurjchem-2489	160	25	]	]	PUNCT
eurjchem-2489	160	26	.	.	PUNCT
eurjchem-2489	161	1	an	an	DET
eurjchem-2489	161	2	electronic	electronic	ADJ
eurjchem-2489	161	3	band	band	NOUN
eurjchem-2489	161	4	at	at	ADP
eurjchem-2489	161	5	λmax	λmax	NOUN
eurjchem-2489	161	6	351	351	NUM
eurjchem-2489	161	7	nm	nm	NOUN
eurjchem-2489	161	8	established	establish	VERB
eurjchem-2489	161	9	the	the	DET
eurjchem-2489	161	10	presence	presence	NOUN
eurjchem-2489	161	11	of	of	ADP
eurjchem-2489	161	12	hydrogen	hydrogen	NOUN
eurjchem-2489	161	13	peroxide	peroxide	NOUN
eurjchem-2489	161	14	in	in	ADP
eurjchem-2489	161	15	the	the	DET
eurjchem-2489	161	16	oxidation	oxidation	NOUN
eurjchem-2489	161	17	of	of	ADP
eurjchem-2489	161	18	dtbc	dtbc	PROPN
eurjchem-2489	161	19	and	and	CCONJ
eurjchem-2489	161	20	thus	thus	ADV
eurjchem-2489	161	21	confirmed	confirm	VERB
eurjchem-2489	161	22	the	the	DET
eurjchem-2489	161	23	reduction	reduction	NOUN
eurjchem-2489	161	24	of	of	ADP
eurjchem-2489	161	25	oxygen	oxygen	NOUN
eurjchem-2489	161	26	to	to	PART
eurjchem-2489	161	27	h2o2	h2o2	VERB
eurjchem-2489	161	28	in	in	ADP
eurjchem-2489	161	29	the	the	DET
eurjchem-2489	161	30	course	course	NOUN
eurjchem-2489	161	31	of	of	ADP
eurjchem-2489	161	32	the	the	DET
eurjchem-2489	161	33	oxidation	oxidation	NOUN
eurjchem-2489	161	34	.	.	PUNCT
eurjchem-2489	162	1	furthermore	furthermore	ADV
eurjchem-2489	162	2	,	,	PUNCT
eurjchem-2489	162	3	the	the	DET
eurjchem-2489	162	4	durability	durability	NOUN
eurjchem-2489	162	5	of	of	ADP
eurjchem-2489	162	6	the	the	DET
eurjchem-2489	162	7	copper(ii	copper(ii	NOUN
eurjchem-2489	162	8	)	)	PUNCT
eurjchem-2489	162	9	catalyst	catalyst	NOUN
eurjchem-2489	162	10	was	be	AUX
eurjchem-2489	162	11	consolidated	consolidate	VERB
eurjchem-2489	162	12	in	in	ADP
eurjchem-2489	162	13	the	the	DET
eurjchem-2489	162	14	oxidative	oxidative	ADJ
eurjchem-2489	162	15	transformation	transformation	NOUN
eurjchem-2489	162	16	of	of	ADP
eurjchem-2489	162	17	dtbc	dtbc	NOUN
eurjchem-2489	162	18	by	by	ADP
eurjchem-2489	162	19	correlating	correlate	VERB
eurjchem-2489	162	20	the	the	DET
eurjchem-2489	162	21	uv	uv	NOUN
eurjchem-2489	162	22	-	-	PUNCT
eurjchem-2489	162	23	vis	vis	X
eurjchem-2489	162	24	spectrum	spectrum	NOUN
eurjchem-2489	162	25	of	of	ADP
eurjchem-2489	162	26	the	the	DET
eurjchem-2489	162	27	solution	solution	NOUN
eurjchem-2489	162	28	after	after	ADP
eurjchem-2489	162	29	isolating	isolate	VERB
eurjchem-2489	162	30	the	the	DET
eurjchem-2489	162	31	oxidation	oxidation	NOUN
eurjchem-2489	162	32	product	product	NOUN
eurjchem-2489	162	33	.	.	PUNCT
eurjchem-2489	163	1	mukherjee	mukherjee	PROPN
eurjchem-2489	163	2	et	et	PROPN
eurjchem-2489	163	3	al	al	PROPN
eurjchem-2489	163	4	.	.	PUNCT
eurjchem-2489	163	5	/	/	SYM
eurjchem-2489	163	6	european	european	PROPN
eurjchem-2489	163	7	journal	journal	PROPN
eurjchem-2489	163	8	of	of	ADP
eurjchem-2489	163	9	chemistry	chemistry	NOUN
eurjchem-2489	163	10	14	14	NUM
eurjchem-2489	163	11	(	(	PUNCT
eurjchem-2489	163	12	4	4	NUM
eurjchem-2489	163	13	)	)	PUNCT
eurjchem-2489	163	14	(	(	PUNCT
eurjchem-2489	163	15	2023	2023	NUM
eurjchem-2489	163	16	)	)	PUNCT
eurjchem-2489	163	17	499	499	NUM
eurjchem-2489	163	18	-	-	SYM
eurjchem-2489	163	19	506	506	NUM
eurjchem-2489	163	20	505	505	NUM
eurjchem-2489	163	21	2023	2023	NUM
eurjchem-2489	163	22	–	–	PUNCT
eurjchem-2489	163	23	european	european	ADJ
eurjchem-2489	163	24	journal	journal	NOUN
eurjchem-2489	163	25	of	of	ADP
eurjchem-2489	163	26	chemistry	chemistry	NOUN
eurjchem-2489	163	27	–	–	PUNCT
eurjchem-2489	163	28	cc	cc	NOUN
eurjchem-2489	163	29	by	by	ADP
eurjchem-2489	163	30	nc	nc	PROPN
eurjchem-2489	163	31	–	–	PUNCT
eurjchem-2489	163	32	doi	doi	NOUN
eurjchem-2489	163	33	:	:	PUNCT
eurjchem-2489	163	34	10.5155	10.5155	NUM
eurjchem-2489	163	35	/	/	SYM
eurjchem-2489	163	36	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	163	37	-	-	PUNCT
eurjchem-2489	163	38	506.2489	506.2489	NUM
eurjchem-2489	163	39	o	o	NOUN
eurjchem-2489	164	1	o	o	X
eurjchem-2489	165	1	o	o	X
eurjchem-2489	165	2	o	o	X
eurjchem-2489	165	3	cu	cu	NOUN
eurjchem-2489	166	1	o	o	NOUN
eurjchem-2489	167	1	o	o	X
eurjchem-2489	168	1	o	o	X
eurjchem-2489	169	1	o	o	X
eurjchem-2489	169	2	cu	cu	NOUN
eurjchem-2489	170	1	oh	oh	INTJ
eurjchem-2489	170	2	oh	oh	INTJ
eurjchem-2489	171	1	butbut	butbut	INTJ
eurjchem-2489	171	2	o	o	NOUN
eurjchem-2489	172	1	o	o	NOUN
eurjchem-2489	173	1	but	but	CCONJ
eurjchem-2489	174	1	but	but	CCONJ
eurjchem-2489	174	2	o	o	NOUN
eurjchem-2489	174	3	o	o	X
eurjchem-2489	175	1	o	o	X
eurjchem-2489	175	2	o	o	X
eurjchem-2489	175	3	cu	cu	NOUN
eurjchem-2489	175	4	o	o	X
eurjchem-2489	176	1	o	o	NOUN
eurjchem-2489	177	1	but	but	CCONJ
eurjchem-2489	178	1	but	but	CCONJ
eurjchem-2489	178	2	o	o	NOUN
eurjchem-2489	178	3	o	o	NOUN
eurjchem-2489	179	1	but	but	CCONJ
eurjchem-2489	180	1	but	but	CCONJ
eurjchem-2489	180	2	oh	oh	INTJ
eurjchem-2489	181	1	oh	oh	INTJ
eurjchem-2489	182	1	but	but	CCONJ
eurjchem-2489	183	1	but	but	CCONJ
eurjchem-2489	183	2	o	o	NOUN
eurjchem-2489	183	3	o	o	X
eurjchem-2489	184	1	o	o	X
eurjchem-2489	184	2	o	o	X
eurjchem-2489	184	3	cu	cu	NOUN
eurjchem-2489	184	4	o	o	X
eurjchem-2489	185	1	o	o	NOUN
eurjchem-2489	186	1	but	but	CCONJ
eurjchem-2489	187	1	but	but	CCONJ
eurjchem-2489	187	2	o	o	NOUN
eurjchem-2489	188	1	o	o	X
eurjchem-2489	188	2	h2o2	h2o2	NOUN
eurjchem-2489	188	3	o	o	X
eurjchem-2489	188	4	o	o	NOUN
eurjchem-2489	188	5	scheme	scheme	NOUN
eurjchem-2489	188	6	3	3	X
eurjchem-2489	188	7	.	.	NOUN
eurjchem-2489	188	8	plausible	plausible	ADJ
eurjchem-2489	188	9	mechanistic	mechanistic	ADJ
eurjchem-2489	188	10	cycle	cycle	NOUN
eurjchem-2489	188	11	for	for	ADP
eurjchem-2489	188	12	catecholase	catecholase	NOUN
eurjchem-2489	188	13	activity	activity	NOUN
eurjchem-2489	188	14	of	of	ADP
eurjchem-2489	188	15	the	the	DET
eurjchem-2489	188	16	copper(ii	copper(ii	NOUN
eurjchem-2489	188	17	)	)	PUNCT
eurjchem-2489	188	18	complex	complex	NOUN
eurjchem-2489	188	19	.	.	PUNCT
eurjchem-2489	189	1	figure	figure	NOUN
eurjchem-2489	189	2	6	6	NUM
eurjchem-2489	189	3	.	.	PUNCT
eurjchem-2489	189	4	cyclic	cyclic	ADJ
eurjchem-2489	189	5	voltammogram	voltammogram	NOUN
eurjchem-2489	189	6	of	of	ADP
eurjchem-2489	189	7	the	the	DET
eurjchem-2489	189	8	copper(ii	copper(ii	NOUN
eurjchem-2489	189	9	)	)	PUNCT
eurjchem-2489	189	10	complex	complex	NOUN
eurjchem-2489	189	11	with	with	ADP
eurjchem-2489	189	12	sequential	sequential	ADJ
eurjchem-2489	189	13	addition	addition	NOUN
eurjchem-2489	189	14	of	of	ADP
eurjchem-2489	189	15	dtbc	dtbc	PROPN
eurjchem-2489	189	16	in	in	ADP
eurjchem-2489	189	17	ch3cn	ch3cn	NOUN
eurjchem-2489	189	18	under	under	ADP
eurjchem-2489	189	19	aerobic	aerobic	ADJ
eurjchem-2489	189	20	conditions	condition	NOUN
eurjchem-2489	189	21	.	.	PUNCT
eurjchem-2489	190	1	the	the	DET
eurjchem-2489	190	2	solution	solution	NOUN
eurjchem-2489	190	3	containing	contain	VERB
eurjchem-2489	190	4	the	the	DET
eurjchem-2489	190	5	copper	copper	NOUN
eurjchem-2489	190	6	complex	complex	NOUN
eurjchem-2489	190	7	as	as	SCONJ
eurjchem-2489	190	8	a	a	DET
eurjchem-2489	190	9	catalyst	catalyst	NOUN
eurjchem-2489	190	10	produces	produce	VERB
eurjchem-2489	190	11	types	type	NOUN
eurjchem-2489	190	12	of	of	ADP
eurjchem-2489	190	13	electronic	electronic	ADJ
eurjchem-2489	190	14	bands	band	NOUN
eurjchem-2489	190	15	at	at	ADP
eurjchem-2489	190	16	315	315	NUM
eurjchem-2489	190	17	and	and	CCONJ
eurjchem-2489	190	18	382	382	NUM
eurjchem-2489	190	19	nm	nm	NOUN
eurjchem-2489	190	20	similar	similar	ADJ
eurjchem-2489	190	21	to	to	ADP
eurjchem-2489	190	22	the	the	DET
eurjchem-2489	190	23	electronic	electronic	ADJ
eurjchem-2489	190	24	bands	band	NOUN
eurjchem-2489	190	25	of	of	ADP
eurjchem-2489	190	26	the	the	DET
eurjchem-2489	190	27	original	original	ADJ
eurjchem-2489	190	28	copper	copper	NOUN
eurjchem-2489	190	29	complex	complex	NOUN
eurjchem-2489	190	30	displayed	display	VERB
eurjchem-2489	190	31	in	in	ADP
eurjchem-2489	190	32	acn	acn	PROPN
eurjchem-2489	190	33	and	and	CCONJ
eurjchem-2489	190	34	ensures	ensure	VERB
eurjchem-2489	190	35	the	the	DET
eurjchem-2489	190	36	durability	durability	NOUN
eurjchem-2489	190	37	of	of	ADP
eurjchem-2489	190	38	the	the	DET
eurjchem-2489	190	39	catalyst	catalyst	NOUN
eurjchem-2489	190	40	in	in	ADP
eurjchem-2489	190	41	dtbc	dtbc	PROPN
eurjchem-2489	190	42	oxidation	oxidation	NOUN
eurjchem-2489	190	43	.	.	PUNCT
eurjchem-2489	191	1	therefore	therefore	ADV
eurjchem-2489	191	2	,	,	PUNCT
eurjchem-2489	191	3	based	base	VERB
eurjchem-2489	191	4	on	on	ADP
eurjchem-2489	191	5	the	the	DET
eurjchem-2489	191	6	experimental	experimental	ADJ
eurjchem-2489	191	7	results	result	NOUN
eurjchem-2489	191	8	,	,	PUNCT
eurjchem-2489	191	9	a	a	DET
eurjchem-2489	191	10	plausible	plausible	ADJ
eurjchem-2489	191	11	mechanistic	mechanistic	ADJ
eurjchem-2489	191	12	cycle	cycle	NOUN
eurjchem-2489	191	13	for	for	ADP
eurjchem-2489	191	14	the	the	DET
eurjchem-2489	191	15	catalytic	catalytic	ADJ
eurjchem-2489	191	16	oxidation	oxidation	NOUN
eurjchem-2489	191	17	of	of	ADP
eurjchem-2489	191	18	dtbc	dtbc	PROPN
eurjchem-2489	191	19	may	may	AUX
eurjchem-2489	191	20	be	be	AUX
eurjchem-2489	191	21	proposed	propose	VERB
eurjchem-2489	191	22	according	accord	VERB
eurjchem-2489	191	23	to	to	ADP
eurjchem-2489	191	24	scheme	scheme	NOUN
eurjchem-2489	191	25	3	3	NUM
eurjchem-2489	191	26	.	.	NOUN
eurjchem-2489	191	27	4	4	NUM
eurjchem-2489	191	28	.	.	PUNCT
eurjchem-2489	192	1	conclusions	conclusion	NOUN
eurjchem-2489	192	2	this	this	DET
eurjchem-2489	192	3	research	research	NOUN
eurjchem-2489	192	4	work	work	NOUN
eurjchem-2489	192	5	deals	deal	NOUN
eurjchem-2489	192	6	with	with	ADP
eurjchem-2489	192	7	the	the	DET
eurjchem-2489	192	8	synthesis	synthesis	NOUN
eurjchem-2489	192	9	,	,	PUNCT
eurjchem-2489	192	10	crystal	crystal	NOUN
eurjchem-2489	192	11	structure	structure	NOUN
eurjchem-2489	192	12	,	,	PUNCT
eurjchem-2489	192	13	and	and	CCONJ
eurjchem-2489	192	14	biomimetics	biomimetic	NOUN
eurjchem-2489	192	15	of	of	ADP
eurjchem-2489	192	16	catecholase	catecholase	NOUN
eurjchem-2489	192	17	activity	activity	NOUN
eurjchem-2489	192	18	of	of	ADP
eurjchem-2489	192	19	the	the	DET
eurjchem-2489	192	20	copper(ii	copper(ii	NOUN
eurjchem-2489	192	21	)	)	PUNCT
eurjchem-2489	192	22	complex	complex	NOUN
eurjchem-2489	192	23	.	.	PUNCT
eurjchem-2489	193	1	the	the	DET
eurjchem-2489	193	2	copper(ii	copper(ii	NOUN
eurjchem-2489	193	3	)	)	PUNCT
eurjchem-2489	193	4	centre	centre	NOUN
eurjchem-2489	193	5	adopts	adopt	VERB
eurjchem-2489	193	6	a	a	DET
eurjchem-2489	193	7	nearly	nearly	ADV
eurjchem-2489	193	8	perfect	perfect	ADJ
eurjchem-2489	193	9	square	square	ADJ
eurjchem-2489	193	10	planar	planar	ADJ
eurjchem-2489	193	11	geometry	geometry	NOUN
eurjchem-2489	193	12	and	and	CCONJ
eurjchem-2489	193	13	coexists	coexist	VERB
eurjchem-2489	193	14	with	with	ADP
eurjchem-2489	193	15	p	p	NOUN
eurjchem-2489	193	16	-	-	PUNCT
eurjchem-2489	193	17	cresol	cresol	NOUN
eurjchem-2489	193	18	in	in	ADP
eurjchem-2489	193	19	the	the	DET
eurjchem-2489	193	20	solid	solid	ADJ
eurjchem-2489	193	21	state	state	NOUN
eurjchem-2489	193	22	through	through	ADP
eurjchem-2489	193	23	an	an	DET
eurjchem-2489	193	24	intermolecular	intermolecular	ADJ
eurjchem-2489	193	25	hydrogen	hydrogen	NOUN
eurjchem-2489	193	26	bonding	bonding	NOUN
eurjchem-2489	193	27	interaction	interaction	NOUN
eurjchem-2489	193	28	.	.	PUNCT
eurjchem-2489	194	1	the	the	DET
eurjchem-2489	194	2	deviation	deviation	NOUN
eurjchem-2489	194	3	from	from	ADP
eurjchem-2489	194	4	the	the	DET
eurjchem-2489	194	5	formation	formation	NOUN
eurjchem-2489	194	6	of	of	ADP
eurjchem-2489	194	7	the	the	DET
eurjchem-2489	194	8	mannich	mannich	NOUN
eurjchem-2489	194	9	base	base	NOUN
eurjchem-2489	194	10	can	can	AUX
eurjchem-2489	194	11	be	be	AUX
eurjchem-2489	194	12	explained	explain	VERB
eurjchem-2489	194	13	in	in	ADP
eurjchem-2489	194	14	terms	term	NOUN
eurjchem-2489	194	15	of	of	ADP
eurjchem-2489	194	16	acid	acid	NOUN
eurjchem-2489	194	17	-	-	PUNCT
eurjchem-2489	194	18	base	base	NOUN
eurjchem-2489	194	19	chemistry	chemistry	NOUN
eurjchem-2489	194	20	and	and	CCONJ
eurjchem-2489	194	21	,	,	PUNCT
eurjchem-2489	194	22	under	under	ADP
eurjchem-2489	194	23	the	the	DET
eurjchem-2489	194	24	reaction	reaction	NOUN
eurjchem-2489	194	25	condition	condition	NOUN
eurjchem-2489	194	26	,	,	PUNCT
eurjchem-2489	194	27	upon	upon	SCONJ
eurjchem-2489	194	28	in	in	ADP
eurjchem-2489	194	29	situ	situ	ADJ
eurjchem-2489	194	30	addition	addition	NOUN
eurjchem-2489	194	31	of	of	ADP
eurjchem-2489	194	32	the	the	DET
eurjchem-2489	194	33	copper	copper	NOUN
eurjchem-2489	194	34	salt	salt	NOUN
eurjchem-2489	194	35	leads	lead	VERB
eurjchem-2489	194	36	to	to	ADP
eurjchem-2489	194	37	the	the	DET
eurjchem-2489	194	38	generation	generation	NOUN
eurjchem-2489	194	39	of	of	ADP
eurjchem-2489	194	40	the	the	DET
eurjchem-2489	194	41	copper(ii	copper(ii	NOUN
eurjchem-2489	194	42	)	)	PUNCT
eurjchem-2489	194	43	complex	complex	NOUN
eurjchem-2489	194	44	where	where	SCONJ
eurjchem-2489	194	45	the	the	DET
eurjchem-2489	194	46	p	p	NOUN
eurjchem-2489	194	47	-	-	PUNCT
eurjchem-2489	194	48	cresol	cresol	NOUN
eurjchem-2489	194	49	supports	support	VERB
eurjchem-2489	194	50	the	the	DET
eurjchem-2489	194	51	crystallization	crystallization	NOUN
eurjchem-2489	194	52	of	of	ADP
eurjchem-2489	194	53	the	the	DET
eurjchem-2489	194	54	complex	complex	NOUN
eurjchem-2489	194	55	.	.	PUNCT
eurjchem-2489	195	1	the	the	DET
eurjchem-2489	195	2	copper(ii	copper(ii	NOUN
eurjchem-2489	195	3	)	)	PUNCT
eurjchem-2489	195	4	complex	complex	NOUN
eurjchem-2489	195	5	exhibits	exhibit	VERB
eurjchem-2489	195	6	excellent	excellent	ADJ
eurjchem-2489	195	7	catalytic	catalytic	ADJ
eurjchem-2489	195	8	oxidation	oxidation	NOUN
eurjchem-2489	195	9	activity	activity	NOUN
eurjchem-2489	195	10	,	,	PUNCT
eurjchem-2489	195	11	denoted	denote	VERB
eurjchem-2489	195	12	by	by	ADP
eurjchem-2489	195	13	kcat	kcat	PROPN
eurjchem-2489	195	14	/	/	SYM
eurjchem-2489	195	15	km	km	PROPN
eurjchem-2489	195	16	,	,	PUNCT
eurjchem-2489	195	17	which	which	PRON
eurjchem-2489	195	18	is	be	AUX
eurjchem-2489	195	19	found	find	VERB
eurjchem-2489	195	20	to	to	PART
eurjchem-2489	195	21	have	have	VERB
eurjchem-2489	195	22	the	the	DET
eurjchem-2489	195	23	value	value	NOUN
eurjchem-2489	195	24	of	of	ADP
eurjchem-2489	195	25	5.94×105	5.94×105	NUM
eurjchem-2489	195	26	.	.	PUNCT
eurjchem-2489	196	1	electrochemical	electrochemical	ADJ
eurjchem-2489	196	2	and	and	CCONJ
eurjchem-2489	196	3	spectrophotometric	spectrophotometric	ADJ
eurjchem-2489	196	4	spectral	spectral	ADJ
eurjchem-2489	196	5	studies	study	NOUN
eurjchem-2489	196	6	of	of	ADP
eurjchem-2489	196	7	the	the	DET
eurjchem-2489	196	8	cu(ii	cu(ii	PROPN
eurjchem-2489	196	9	)	)	PUNCT
eurjchem-2489	196	10	complex	complex	NOUN
eurjchem-2489	196	11	in	in	ADP
eurjchem-2489	196	12	the	the	DET
eurjchem-2489	196	13	presence	presence	NOUN
eurjchem-2489	196	14	of	of	ADP
eurjchem-2489	196	15	dtbc	dtbc	PROPN
eurjchem-2489	196	16	suggest	suggest	VERB
eurjchem-2489	196	17	the	the	DET
eurjchem-2489	196	18	development	development	NOUN
eurjchem-2489	196	19	of	of	ADP
eurjchem-2489	196	20	an	an	DET
eurjchem-2489	196	21	isobestic	isobestic	ADJ
eurjchem-2489	196	22	point	point	NOUN
eurjchem-2489	196	23	at	at	ADP
eurjchem-2489	196	24	~595	~595	NUM
eurjchem-2489	196	25	nm	nm	NOUN
eurjchem-2489	196	26	that	that	PRON
eurjchem-2489	196	27	represents	represent	VERB
eurjchem-2489	196	28	the	the	DET
eurjchem-2489	196	29	transformation	transformation	NOUN
eurjchem-2489	196	30	of	of	ADP
eurjchem-2489	196	31	the	the	DET
eurjchem-2489	196	32	cu(ii	cu(ii	PROPN
eurjchem-2489	196	33	)	)	PUNCT
eurjchem-2489	196	34	complex	complex	ADJ
eurjchem-2489	196	35	-	-	PUNCT
eurjchem-2489	196	36	dtbc	dtbc	ADJ
eurjchem-2489	196	37	adduct	adduct	NOUN
eurjchem-2489	196	38	into	into	ADP
eurjchem-2489	196	39	cu(ii	cu(ii	PROPN
eurjchem-2489	196	40	)	)	PUNCT
eurjchem-2489	196	41	complex	complex	ADJ
eurjchem-2489	196	42	-	-	PUNCT
eurjchem-2489	196	43	dtbsq	dtbsq	ADJ
eurjchem-2489	196	44	species	specie	NOUN
eurjchem-2489	196	45	in	in	ADP
eurjchem-2489	196	46	solution	solution	NOUN
eurjchem-2489	196	47	.	.	PUNCT
eurjchem-2489	197	1	cyclic	cyclic	ADJ
eurjchem-2489	197	2	voltammogram	voltammogram	NOUN
eurjchem-2489	197	3	analysis	analysis	NOUN
eurjchem-2489	197	4	confirms	confirm	VERB
eurjchem-2489	197	5	the	the	DET
eurjchem-2489	197	6	presence	presence	NOUN
eurjchem-2489	197	7	of	of	ADP
eurjchem-2489	197	8	semiquinone	semiquinone	NOUN
eurjchem-2489	197	9	at	at	ADP
eurjchem-2489	197	10	+0.45	+0.45	PROPN
eurjchem-2489	197	11	v	v	NOUN
eurjchem-2489	197	12	and	and	CCONJ
eurjchem-2489	197	13	offers	offer	VERB
eurjchem-2489	197	14	a	a	DET
eurjchem-2489	197	15	new	new	ADJ
eurjchem-2489	197	16	addition	addition	NOUN
eurjchem-2489	197	17	of	of	ADP
eurjchem-2489	197	18	the	the	DET
eurjchem-2489	197	19	copper	copper	NOUN
eurjchem-2489	197	20	complex	complex	NOUN
eurjchem-2489	197	21	that	that	PRON
eurjchem-2489	197	22	effectively	effectively	ADV
eurjchem-2489	197	23	mimics	mimic	VERB
eurjchem-2489	197	24	catecholase	catecholase	NOUN
eurjchem-2489	197	25	functionality	functionality	NOUN
eurjchem-2489	197	26	.	.	PUNCT
eurjchem-2489	198	1	acknowledgements	acknowledgement	NOUN
eurjchem-2489	198	2	dr	dr	PROPN
eurjchem-2489	198	3	.	.	PROPN
eurjchem-2489	198	4	bhaskar	bhaskar	PROPN
eurjchem-2489	198	5	biswas	biswas	PROPN
eurjchem-2489	198	6	gratefully	gratefully	ADV
eurjchem-2489	198	7	acknowledges	acknowledge	VERB
eurjchem-2489	198	8	the	the	DET
eurjchem-2489	198	9	financial	financial	ADJ
eurjchem-2489	198	10	support	support	NOUN
eurjchem-2489	198	11	received	receive	VERB
eurjchem-2489	198	12	from	from	ADP
eurjchem-2489	198	13	the	the	DET
eurjchem-2489	198	14	university	university	NOUN
eurjchem-2489	198	15	of	of	ADP
eurjchem-2489	198	16	north	north	PROPN
eurjchem-2489	198	17	bengal	bengal	ADJ
eurjchem-2489	198	18	,	,	PUNCT
eurjchem-2489	198	19	darjeeling	darjeele	VERB
eurjchem-2489	198	20	734013	734013	NUM
eurjchem-2489	198	21	,	,	PUNCT
eurjchem-2489	198	22	india	india	PROPN
eurjchem-2489	198	23	.	.	PUNCT
eurjchem-2489	199	1	supporting	support	VERB
eurjchem-2489	199	2	information	information	NOUN
eurjchem-2489	199	3	ccdc-2299271	ccdc-2299271	NOUN
eurjchem-2489	199	4	contains	contain	VERB
eurjchem-2489	199	5	the	the	DET
eurjchem-2489	199	6	supplementary	supplementary	ADJ
eurjchem-2489	199	7	crystallographic	crystallographic	ADJ
eurjchem-2489	199	8	data	datum	NOUN
eurjchem-2489	199	9	for	for	ADP
eurjchem-2489	199	10	this	this	DET
eurjchem-2489	199	11	paper	paper	NOUN
eurjchem-2489	199	12	.	.	PUNCT
eurjchem-2489	200	1	these	these	DET
eurjchem-2489	200	2	data	datum	NOUN
eurjchem-2489	200	3	can	can	AUX
eurjchem-2489	200	4	be	be	AUX
eurjchem-2489	200	5	obtained	obtain	VERB
eurjchem-2489	200	6	free	free	ADJ
eurjchem-2489	200	7	of	of	ADP
eurjchem-2489	200	8	charge	charge	NOUN
eurjchem-2489	200	9	via	via	ADP
eurjchem-2489	200	10	www.ccdc.cam.ac.uk/	www.ccdc.cam.ac.uk/	ADP
eurjchem-2489	200	11	data_request	data_request	PROPN
eurjchem-2489	200	12	/	/	SYM
eurjchem-2489	200	13	cif	cif	PROPN
eurjchem-2489	200	14	,	,	PUNCT
eurjchem-2489	200	15	or	or	CCONJ
eurjchem-2489	200	16	by	by	ADP
eurjchem-2489	200	17	e	e	NOUN
eurjchem-2489	200	18	-	-	ADJ
eurjchem-2489	200	19	mailing	mailing	ADJ
eurjchem-2489	200	20	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	PROPN
eurjchem-2489	200	21	,	,	PUNCT
eurjchem-2489	200	22	or	or	CCONJ
eurjchem-2489	200	23	by	by	ADP
eurjchem-2489	200	24	contacting	contact	VERB
eurjchem-2489	200	25	the	the	DET
eurjchem-2489	200	26	cambridge	cambridge	PROPN
eurjchem-2489	200	27	crystallographic	crystallographic	PROPN
eurjchem-2489	200	28	data	data	PROPN
eurjchem-2489	200	29	centre	centre	NOUN
eurjchem-2489	200	30	,	,	PUNCT
eurjchem-2489	200	31	12	12	NUM
eurjchem-2489	200	32	union	union	NOUN
eurjchem-2489	200	33	road	road	NOUN
eurjchem-2489	200	34	,	,	PUNCT
eurjchem-2489	200	35	cambridge	cambridge	PROPN
eurjchem-2489	200	36	cb2	cb2	PROPN
eurjchem-2489	200	37	1ez	1ez	PROPN
eurjchem-2489	200	38	,	,	PUNCT
eurjchem-2489	200	39	uk	uk	PROPN
eurjchem-2489	200	40	;	;	PUNCT
eurjchem-2489	200	41	fax	fax	NOUN
eurjchem-2489	200	42	:	:	PUNCT
eurjchem-2489	200	43	+44(0)1223	+44(0)1223	PROPN
eurjchem-2489	200	44	-	-	PUNCT
eurjchem-2489	200	45	336033	336033	NUM
eurjchem-2489	200	46	.	.	PUNCT
eurjchem-2489	201	1	http://www.ccdc.cam.ac.uk/%20data_request/cif	http://www.ccdc.cam.ac.uk/%20data_request/cif	PROPN
eurjchem-2489	201	2	http://www.ccdc.cam.ac.uk/%20data_request/cif	http://www.ccdc.cam.ac.uk/%20data_request/cif	PROPN
eurjchem-2489	201	3	mailto:data_request@ccdc.cam.ac.uk	mailto:data_request@ccdc.cam.ac.uk	VERB
eurjchem-2489	201	4	506	506	NUM
eurjchem-2489	201	5	mukherjee	mukherjee	NOUN
eurjchem-2489	201	6	et	et	PROPN
eurjchem-2489	201	7	al	al	PROPN
eurjchem-2489	201	8	.	.	PUNCT
eurjchem-2489	201	9	/	/	SYM
eurjchem-2489	201	10	european	european	PROPN
eurjchem-2489	201	11	journal	journal	PROPN
eurjchem-2489	201	12	of	of	ADP
eurjchem-2489	201	13	chemistry	chemistry	NOUN
eurjchem-2489	201	14	14	14	NUM
eurjchem-2489	201	15	(	(	PUNCT
eurjchem-2489	201	16	4	4	NUM
eurjchem-2489	201	17	)	)	PUNCT
eurjchem-2489	201	18	(	(	PUNCT
eurjchem-2489	201	19	2023	2023	NUM
eurjchem-2489	201	20	)	)	PUNCT
eurjchem-2489	201	21	499	499	NUM
eurjchem-2489	201	22	-	-	SYM
eurjchem-2489	201	23	506	506	NUM
eurjchem-2489	201	24	2023	2023	NUM
eurjchem-2489	201	25	–	–	PUNCT
eurjchem-2489	201	26	european	european	ADJ
eurjchem-2489	201	27	journal	journal	NOUN
eurjchem-2489	201	28	of	of	ADP
eurjchem-2489	201	29	chemistry	chemistry	NOUN
eurjchem-2489	201	30	–	–	PUNCT
eurjchem-2489	201	31	cc	cc	NOUN
eurjchem-2489	201	32	by	by	ADP
eurjchem-2489	201	33	nc	nc	PROPN
eurjchem-2489	201	34	–	–	PUNCT
eurjchem-2489	201	35	doi	doi	NOUN
eurjchem-2489	201	36	:	:	PUNCT
eurjchem-2489	201	37	10.5155	10.5155	NUM
eurjchem-2489	201	38	/	/	SYM
eurjchem-2489	201	39	eurjchem.14.4.499	eurjchem.14.4.499	NOUN
eurjchem-2489	201	40	-	-	PUNCT
eurjchem-2489	201	41	506.2489	506.2489	NUM
eurjchem-2489	201	42	disclosure	disclosure	NOUN
eurjchem-2489	201	43	statement	statement	NOUN
eurjchem-2489	201	44	conflict	conflict	NOUN
eurjchem-2489	201	45	of	of	ADP
eurjchem-2489	201	46	interest	interest	NOUN
eurjchem-2489	201	47	:	:	PUNCT
eurjchem-2489	201	48	the	the	DET
eurjchem-2489	201	49	authors	author	NOUN
eurjchem-2489	201	50	declare	declare	VERB
eurjchem-2489	201	51	that	that	SCONJ
eurjchem-2489	201	52	they	they	PRON
eurjchem-2489	201	53	have	have	VERB
eurjchem-2489	201	54	no	no	DET
eurjchem-2489	201	55	conflict	conflict	NOUN
eurjchem-2489	201	56	of	of	ADP
eurjchem-2489	201	57	interest	interest	NOUN
eurjchem-2489	201	58	.	.	PUNCT
eurjchem-2489	202	1	author	author	NOUN
eurjchem-2489	202	2	contributions	contribution	NOUN
eurjchem-2489	202	3	:	:	PUNCT
eurjchem-2489	202	4	all	all	DET
eurjchem-2489	202	5	authors	author	NOUN
eurjchem-2489	202	6	contributed	contribute	VERB
eurjchem-2489	202	7	equally	equally	ADV
eurjchem-2489	202	8	to	to	ADP
eurjchem-2489	202	9	this	this	DET
eurjchem-2489	202	10	work	work	NOUN
eurjchem-2489	202	11	.	.	PUNCT
eurjchem-2489	203	1	ethical	ethical	ADJ
eurjchem-2489	203	2	approval	approval	NOUN
eurjchem-2489	203	3	:	:	PUNCT
eurjchem-2489	204	1	all	all	DET
eurjchem-2489	204	2	ethical	ethical	ADJ
eurjchem-2489	204	3	guidelines	guideline	NOUN
eurjchem-2489	204	4	have	have	AUX
eurjchem-2489	204	5	been	be	AUX
eurjchem-2489	204	6	adhered	adhere	VERB
eurjchem-2489	204	7	.	.	PUNCT
eurjchem-2489	205	1	sample	sample	NOUN
eurjchem-2489	205	2	availability	availability	NOUN
eurjchem-2489	205	3	:	:	PUNCT
eurjchem-2489	205	4	samples	sample	NOUN
eurjchem-2489	205	5	of	of	ADP
eurjchem-2489	205	6	the	the	DET
eurjchem-2489	205	7	compounds	compound	NOUN
eurjchem-2489	205	8	are	be	AUX
eurjchem-2489	205	9	available	available	ADJ
eurjchem-2489	205	10	from	from	ADP
eurjchem-2489	205	11	the	the	DET
eurjchem-2489	205	12	author	author	NOUN
eurjchem-2489	205	13	.	.	PUNCT
eurjchem-2489	206	1	credit	credit	NOUN
eurjchem-2489	206	2	authorship	authorship	NOUN
eurjchem-2489	206	3	contribution	contribution	NOUN
eurjchem-2489	206	4	statement	statement	NOUN
eurjchem-2489	206	5	conceptualization	conceptualization	NOUN
eurjchem-2489	206	6	:	:	PUNCT
eurjchem-2489	206	7	subham	subham	NOUN
eurjchem-2489	206	8	mukherjee	mukherjee	NOUN
eurjchem-2489	206	9	,	,	PUNCT
eurjchem-2489	206	10	bhaskar	bhaskar	PROPN
eurjchem-2489	206	11	biswas	biswas	PROPN
eurjchem-2489	206	12	;	;	PUNCT
eurjchem-2489	206	13	methodology	methodology	NOUN
eurjchem-2489	206	14	:	:	PUNCT
eurjchem-2489	206	15	subham	subham	NOUN
eurjchem-2489	206	16	mukherjee	mukherjee	NOUN
eurjchem-2489	206	17	,	,	PUNCT
eurjchem-2489	206	18	gayetri	gayetri	ADJ
eurjchem-2489	206	19	sarkar	sarkar	NOUN
eurjchem-2489	206	20	;	;	PUNCT
eurjchem-2489	206	21	validation	validation	NOUN
eurjchem-2489	206	22	:	:	PUNCT
eurjchem-2489	206	23	subham	subham	NOUN
eurjchem-2489	206	24	mukherjee	mukherjee	NOUN
eurjchem-2489	206	25	,	,	PUNCT
eurjchem-2489	206	26	gayetri	gayetri	ADJ
eurjchem-2489	206	27	sarkar	sarkar	NOUN
eurjchem-2489	206	28	;	;	PUNCT
eurjchem-2489	206	29	abhranil	abhranil	NOUN
eurjchem-2489	206	30	de	de	X
eurjchem-2489	206	31	;	;	PUNCT
eurjchem-2489	206	32	formal	formal	ADJ
eurjchem-2489	206	33	analysis	analysis	NOUN
eurjchem-2489	206	34	:	:	PUNCT
eurjchem-2489	206	35	subham	subham	NOUN
eurjchem-2489	206	36	mukherjee	mukherjee	NOUN
eurjchem-2489	206	37	,	,	PUNCT
eurjchem-2489	206	38	gayetri	gayetri	ADJ
eurjchem-2489	206	39	sarkar	sarkar	NOUN
eurjchem-2489	206	40	;	;	PUNCT
eurjchem-2489	206	41	abhranil	abhranil	NOUN
eurjchem-2489	206	42	de	de	PROPN
eurjchem-2489	206	43	;	;	PUNCT
eurjchem-2489	206	44	investigation	investigation	NOUN
eurjchem-2489	206	45	:	:	PUNCT
eurjchem-2489	206	46	subham	subham	NOUN
eurjchem-2489	206	47	mukherjee	mukherjee	NOUN
eurjchem-2489	206	48	,	,	PUNCT
eurjchem-2489	206	49	gayetri	gayetri	ADJ
eurjchem-2489	206	50	sarkar	sarkar	NOUN
eurjchem-2489	206	51	;	;	PUNCT
eurjchem-2489	206	52	abhranil	abhranil	NOUN
eurjchem-2489	206	53	de	de	PROPN
eurjchem-2489	206	54	;	;	PUNCT
eurjchem-2489	206	55	resources	resource	NOUN
eurjchem-2489	206	56	:	:	PUNCT
eurjchem-2489	206	57	subham	subham	NOUN
eurjchem-2489	206	58	mukherjee	mukherjee	NOUN
eurjchem-2489	206	59	,	,	PUNCT
eurjchem-2489	206	60	bhaskar	bhaskar	PROPN
eurjchem-2489	206	61	biswas	biswas	PROPN
eurjchem-2489	206	62	;	;	PUNCT
eurjchem-2489	206	63	data	datum	NOUN
eurjchem-2489	206	64	curation	curation	NOUN
eurjchem-2489	206	65	:	:	PUNCT
eurjchem-2489	206	66	subham	subham	NOUN
eurjchem-2489	206	67	mukherjee	mukherjee	NOUN
eurjchem-2489	206	68	,	,	PUNCT
eurjchem-2489	206	69	gayetri	gayetri	ADJ
eurjchem-2489	206	70	sarkar	sarkar	NOUN
eurjchem-2489	206	71	;	;	PUNCT
eurjchem-2489	206	72	abhranil	abhranil	NOUN
eurjchem-2489	206	73	de	de	PROPN
eurjchem-2489	206	74	;	;	PUNCT
eurjchem-2489	206	75	writing	write	VERB
eurjchem-2489	206	76	original	original	ADJ
eurjchem-2489	206	77	draft	draft	NOUN
eurjchem-2489	206	78	:	:	PUNCT
eurjchem-2489	206	79	subham	subham	NOUN
eurjchem-2489	206	80	mukherjee	mukherjee	NOUN
eurjchem-2489	206	81	,	,	PUNCT
eurjchem-2489	206	82	bhaskar	bhaskar	PROPN
eurjchem-2489	206	83	biswas	biswas	PROPN
eurjchem-2489	206	84	;	;	PUNCT
eurjchem-2489	206	85	writing	write	VERB
eurjchem-2489	206	86	review	review	NOUN
eurjchem-2489	206	87	and	and	CCONJ
eurjchem-2489	206	88	editing	editing	NOUN
eurjchem-2489	206	89	:	:	PUNCT
eurjchem-2489	206	90	bhaskar	bhaskar	PROPN
eurjchem-2489	206	91	biswas	biswas	PROPN
eurjchem-2489	206	92	.	.	PUNCT
eurjchem-2489	207	1	orcid	orcid	NOUN
eurjchem-2489	207	2	and	and	CCONJ
eurjchem-2489	207	3	email	email	NOUN
eurjchem-2489	207	4	subham	subham	NOUN
eurjchem-2489	207	5	mukherjee	mukherjee	PROPN
eurjchem-2489	207	6	smukherjee@suryasencollege.org.in	smukherjee@suryasencollege.org.in	PROPN
eurjchem-2489	207	7	https://orcid.org/0000-0002-1541-2839	https://orcid.org/0000-0002-1541-2839	ADV
eurjchem-2489	207	8	gayetri	gayetri	PROPN
eurjchem-2489	207	9	sarkar	sarkar	NOUN
eurjchem-2489	207	10	iamgayetri007@gmail.com	iamgayetri007@gmail.com	X
eurjchem-2489	208	1	https://orcid.org/0009-0008-9729-9331	https://orcid.org/0009-0008-9729-9331	ADV
eurjchem-2489	208	2	abhranil	abhranil	PROPN
eurjchem-2489	208	3	de	de	PROPN
eurjchem-2489	208	4	abhranilde@gmail.com	abhranilde@gmail.com	PROPN
eurjchem-2489	208	5	https://orcid.org/0000-0003-2266-9023	https://orcid.org/0000-0003-2266-9023	PROPN
eurjchem-2489	208	6	bhaskar	bhaskar	PROPN
eurjchem-2489	208	7	biswas	biswas	PROPN
eurjchem-2489	208	8	bhaskarbiswas@nbu.ac.in	bhaskarbiswas@nbu.ac.in	PROPN
eurjchem-2489	209	1	mr.bbiswas@rediffmail.com	mr.bbiswas@rediffmail.com	PROPN
eurjchem-2489	209	2	https://orcid.org/0000-0002-5447-9729	https://orcid.org/0000-0002-5447-9729	PROPN
eurjchem-2489	209	3	references	reference	VERB
eurjchem-2489	209	4	[	[	X
eurjchem-2489	209	5	1	1	NUM
eurjchem-2489	209	6	]	]	PUNCT
eurjchem-2489	209	7	.	.	PUNCT
eurjchem-2489	210	1	debnath	debnath	PROPN
eurjchem-2489	210	2	,	,	PUNCT
eurjchem-2489	210	3	a.	a.	NOUN
eurjchem-2489	210	4	;	;	PUNCT
eurjchem-2489	210	5	diyali	diyali	PROPN
eurjchem-2489	210	6	,	,	PUNCT
eurjchem-2489	210	7	s.	s.	PROPN
eurjchem-2489	210	8	;	;	PUNCT
eurjchem-2489	210	9	das	das	PROPN
eurjchem-2489	210	10	,	,	PUNCT
eurjchem-2489	210	11	m.	m.	NOUN
eurjchem-2489	210	12	;	;	PUNCT
eurjchem-2489	210	13	panda	panda	NOUN
eurjchem-2489	210	14	,	,	PUNCT
eurjchem-2489	210	15	s.	s.	PROPN
eurjchem-2489	210	16	j.	j.	PROPN
eurjchem-2489	210	17	;	;	PUNCT
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eurjchem-2489	210	19	,	,	PUNCT
eurjchem-2489	210	20	d.	d.	PROPN
eurjchem-2489	210	21	;	;	PUNCT
eurjchem-2489	210	22	dhak	dhak	PROPN
eurjchem-2489	210	23	,	,	PUNCT
eurjchem-2489	210	24	d.	d.	PROPN
eurjchem-2489	210	25	;	;	PUNCT
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eurjchem-2489	210	27	,	,	PUNCT
eurjchem-2489	210	28	c.	c.	PROPN
eurjchem-2489	210	29	s.	s.	PROPN
eurjchem-2489	210	30	;	;	PUNCT
eurjchem-2489	210	31	ray	ray	PROPN
eurjchem-2489	210	32	,	,	PUNCT
eurjchem-2489	210	33	p.	p.	PROPN
eurjchem-2489	210	34	p.	p.	PROPN
eurjchem-2489	210	35	;	;	PUNCT
eurjchem-2489	210	36	biswas	biswas	PROPN
eurjchem-2489	210	37	,	,	PUNCT
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eurjchem-2489	210	43	reaction	reaction	NOUN
eurjchem-2489	210	44	(	(	PUNCT
eurjchem-2489	210	45	her	her	NOUN
eurjchem-2489	210	46	)	)	PUNCT
eurjchem-2489	210	47	through	through	ADP
eurjchem-2489	210	48	the	the	DET
eurjchem-2489	210	49	electrical	electrical	ADJ
eurjchem-2489	210	50	mobility	mobility	NOUN
eurjchem-2489	210	51	of	of	ADP
eurjchem-2489	210	52	an	an	DET
eurjchem-2489	210	53	embossed	emboss	VERB
eurjchem-2489	210	54	ag(i)molecular	ag(i)molecular	ADJ
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eurjchem-2489	210	56	and	and	CCONJ
eurjchem-2489	210	57	a	a	DET
eurjchem-2489	210	58	cu(ii)-coordination	cu(ii)-coordination	NOUN
eurjchem-2489	210	59	polymer	polymer	NOUN
eurjchem-2489	210	60	.	.	PUNCT
eurjchem-2489	211	1	dalton	dalton	PROPN
eurjchem-2489	211	2	trans	trans	PROPN
eurjchem-2489	211	3	.	.	PROPN
eurjchem-2489	212	1	2023	2023	NUM
eurjchem-2489	212	2	,	,	PUNCT
eurjchem-2489	212	3	52	52	NUM
eurjchem-2489	212	4	,	,	PUNCT
eurjchem-2489	212	5	8850–8856	8850–8856	NUM
eurjchem-2489	212	6	.	.	PUNCT
eurjchem-2489	213	1	[	[	X
eurjchem-2489	213	2	2	2	NUM
eurjchem-2489	213	3	]	]	PUNCT
eurjchem-2489	213	4	.	.	PUNCT
eurjchem-2489	213	5	kundu	kundu	NOUN
eurjchem-2489	213	6	,	,	PUNCT
eurjchem-2489	213	7	s.	s.	PROPN
eurjchem-2489	213	8	;	;	PUNCT
eurjchem-2489	213	9	saha	saha	PROPN
eurjchem-2489	213	10	,	,	PUNCT
eurjchem-2489	213	11	s.	s.	PROPN
eurjchem-2489	213	12	;	;	PUNCT
eurjchem-2489	213	13	panda	panda	NOUN
eurjchem-2489	213	14	,	,	PUNCT
eurjchem-2489	213	15	s.	s.	PROPN
eurjchem-2489	213	16	j.	j.	PROPN
eurjchem-2489	213	17	;	;	PUNCT
eurjchem-2489	213	18	purohit	purohit	PROPN
eurjchem-2489	213	19	,	,	PUNCT
eurjchem-2489	213	20	c.	c.	PROPN
eurjchem-2489	213	21	s.	s.	PROPN
eurjchem-2489	213	22	;	;	PUNCT
eurjchem-2489	213	23	biswas	biswas	PROPN
eurjchem-2489	213	24	,	,	PUNCT
eurjchem-2489	213	25	b.	b.	PROPN
eurjchem-2489	213	26	tailor	tailor	NOUN
eurjchem-2489	213	27	-	-	PUNCT
eurjchem-2489	213	28	made	make	VERB
eurjchem-2489	213	29	isostructural	isostructural	ADJ
eurjchem-2489	213	30	copper(ii	copper(ii	NOUN
eurjchem-2489	213	31	)	)	PUNCT
eurjchem-2489	213	32	and	and	CCONJ
eurjchem-2489	213	33	nickel(ii	nickel(ii	ADJ
eurjchem-2489	213	34	)	)	PUNCT
eurjchem-2489	213	35	complexes	complex	NOUN
eurjchem-2489	213	36	with	with	ADP
eurjchem-2489	213	37	a	a	DET
eurjchem-2489	213	38	newly	newly	ADV
eurjchem-2489	213	39	designed	design	VERB
eurjchem-2489	213	40	(	(	PUNCT
eurjchem-2489	213	41	n	n	X
eurjchem-2489	213	42	,	,	PUNCT
eurjchem-2489	213	43	n)-donor	n)-donor	PUNCT
eurjchem-2489	213	44	scaffold	scaffold	NOUN
eurjchem-2489	213	45	as	as	ADP
eurjchem-2489	213	46	functional	functional	ADJ
eurjchem-2489	213	47	mimics	mimic	NOUN
eurjchem-2489	213	48	of	of	ADP
eurjchem-2489	213	49	alkaline	alkaline	NOUN
eurjchem-2489	213	50	phosphatase	phosphatase	NOUN
eurjchem-2489	213	51	.	.	PUNCT
eurjchem-2489	214	1	new	new	ADJ
eurjchem-2489	214	2	j	j	PROPN
eurjchem-2489	214	3	chem	chem	NOUN
eurjchem-2489	214	4	2023	2023	NUM
eurjchem-2489	214	5	,	,	PUNCT
eurjchem-2489	214	6	47	47	NUM
eurjchem-2489	214	7	,	,	PUNCT
eurjchem-2489	214	8	5894–5902	5894–5902	NUM
eurjchem-2489	214	9	.	.	PUNCT
eurjchem-2489	215	1	[	[	X
eurjchem-2489	215	2	3	3	NUM
eurjchem-2489	215	3	]	]	PUNCT
eurjchem-2489	215	4	.	.	PUNCT
eurjchem-2489	216	1	mudi	mudi	PROPN
eurjchem-2489	216	2	,	,	PUNCT
eurjchem-2489	216	3	p.	p.	PROPN
eurjchem-2489	216	4	k.	k.	PROPN
eurjchem-2489	216	5	;	;	PUNCT
eurjchem-2489	216	6	mahato	mahato	PROPN
eurjchem-2489	216	7	,	,	PUNCT
eurjchem-2489	216	8	r.	r.	PROPN
eurjchem-2489	216	9	k.	k.	PROPN
eurjchem-2489	216	10	;	;	PUNCT
eurjchem-2489	216	11	joshi	joshi	PROPN
eurjchem-2489	216	12	,	,	PUNCT
eurjchem-2489	216	13	m.	m.	NOUN
eurjchem-2489	216	14	;	;	PUNCT
eurjchem-2489	216	15	shit	shit	NOUN
eurjchem-2489	216	16	,	,	PUNCT
eurjchem-2489	216	17	m.	m.	NOUN
eurjchem-2489	216	18	;	;	PUNCT
eurjchem-2489	216	19	choudhury	choudhury	PROPN
eurjchem-2489	216	20	,	,	PUNCT
eurjchem-2489	216	21	a.	a.	PROPN
eurjchem-2489	216	22	r.	r.	PROPN
eurjchem-2489	216	23	;	;	PUNCT
eurjchem-2489	216	24	das	das	PROPN
eurjchem-2489	216	25	,	,	PUNCT
eurjchem-2489	216	26	h.	h.	PROPN
eurjchem-2489	216	27	s.	s.	PROPN
eurjchem-2489	216	28	;	;	PUNCT
eurjchem-2489	216	29	biswas	biswas	PROPN
eurjchem-2489	216	30	,	,	PUNCT
eurjchem-2489	216	31	b.	b.	PROPN
eurjchem-2489	216	32	copper(ii	copper(ii	PROPN
eurjchem-2489	216	33	)	)	PUNCT
eurjchem-2489	216	34	complexes	complex	NOUN
eurjchem-2489	216	35	with	with	ADP
eurjchem-2489	216	36	a	a	DET
eurjchem-2489	216	37	benzimidazole	benzimidazole	ADJ
eurjchem-2489	216	38	functionalized	functionalize	VERB
eurjchem-2489	216	39	schiff	schiff	NOUN
eurjchem-2489	216	40	base	base	NOUN
eurjchem-2489	216	41	:	:	PUNCT
eurjchem-2489	216	42	synthesis	synthesis	NOUN
eurjchem-2489	216	43	,	,	PUNCT
eurjchem-2489	216	44	crystal	crystal	NOUN
eurjchem-2489	216	45	structures	structure	NOUN
eurjchem-2489	216	46	,	,	PUNCT
eurjchem-2489	216	47	and	and	CCONJ
eurjchem-2489	216	48	role	role	NOUN
eurjchem-2489	216	49	of	of	ADP
eurjchem-2489	216	50	ancillary	ancillary	ADJ
eurjchem-2489	216	51	ions	ion	NOUN
eurjchem-2489	216	52	in	in	ADP
eurjchem-2489	216	53	phenoxazinone	phenoxazinone	NOUN
eurjchem-2489	216	54	synthase	synthase	NOUN
eurjchem-2489	216	55	activity	activity	NOUN
eurjchem-2489	216	56	.	.	PUNCT
eurjchem-2489	217	1	appl	appl	PROPN
eurjchem-2489	217	2	.	.	PUNCT
eurjchem-2489	218	1	organomet	organomet	PROPN
eurjchem-2489	218	2	.	.	PUNCT
eurjchem-2489	219	1	chem	chem	NOUN
eurjchem-2489	219	2	.	.	PUNCT
eurjchem-2489	220	1	2021	2021	NUM
eurjchem-2489	220	2	,	,	PUNCT
eurjchem-2489	220	3	35	35	NUM
eurjchem-2489	220	4	,	,	PUNCT
eurjchem-2489	220	5	e6211	e6211	PROPN
eurjchem-2489	220	6	.	.	PUNCT
eurjchem-2489	221	1	[	[	X
eurjchem-2489	221	2	4	4	NUM
eurjchem-2489	221	3	]	]	PUNCT
eurjchem-2489	221	4	.	.	PUNCT
eurjchem-2489	222	1	garai	garai	PROPN
eurjchem-2489	222	2	,	,	PUNCT
eurjchem-2489	222	3	m.	m.	NOUN
eurjchem-2489	222	4	;	;	PUNCT
eurjchem-2489	222	5	dey	dey	PROPN
eurjchem-2489	222	6	,	,	PUNCT
eurjchem-2489	222	7	d.	d.	PROPN
eurjchem-2489	222	8	;	;	PUNCT
eurjchem-2489	222	9	yadav	yadav	PROPN
eurjchem-2489	222	10	,	,	PUNCT
eurjchem-2489	222	11	h.	h.	PROPN
eurjchem-2489	222	12	r.	r.	PROPN
eurjchem-2489	222	13	;	;	PUNCT
eurjchem-2489	222	14	choudhury	choudhury	PROPN
eurjchem-2489	222	15	,	,	PUNCT
eurjchem-2489	222	16	a.	a.	PROPN
eurjchem-2489	222	17	r.	r.	PROPN
eurjchem-2489	222	18	;	;	PUNCT
eurjchem-2489	222	19	maji	maji	PROPN
eurjchem-2489	222	20	,	,	PUNCT
eurjchem-2489	222	21	m.	m.	NOUN
eurjchem-2489	222	22	;	;	PUNCT
eurjchem-2489	222	23	biswas	biswas	PROPN
eurjchem-2489	222	24	,	,	PUNCT
eurjchem-2489	222	25	b.	b.	PROPN
eurjchem-2489	222	26	catalytic	catalytic	ADJ
eurjchem-2489	222	27	fate	fate	NOUN
eurjchem-2489	222	28	of	of	ADP
eurjchem-2489	222	29	two	two	NUM
eurjchem-2489	222	30	copper	copper	NOUN
eurjchem-2489	222	31	complexes	complex	NOUN
eurjchem-2489	222	32	towards	towards	ADP
eurjchem-2489	222	33	phenoxazinone	phenoxazinone	PROPN
eurjchem-2489	222	34	synthase	synthase	NOUN
eurjchem-2489	222	35	and	and	CCONJ
eurjchem-2489	222	36	catechol	catechol	NOUN
eurjchem-2489	222	37	dioxygenase	dioxygenase	NOUN
eurjchem-2489	222	38	activity	activity	NOUN
eurjchem-2489	222	39	.	.	PUNCT
eurjchem-2489	223	1	chemistryselect	chemistryselect	NOUN
eurjchem-2489	223	2	2017	2017	NUM
eurjchem-2489	223	3	,	,	PUNCT
eurjchem-2489	223	4	2	2	NUM
eurjchem-2489	223	5	,	,	PUNCT
eurjchem-2489	223	6	11040–11047	11040–11047	NUM
eurjchem-2489	223	7	.	.	PUNCT
eurjchem-2489	224	1	[	[	X
eurjchem-2489	224	2	5	5	NUM
eurjchem-2489	224	3	]	]	PUNCT
eurjchem-2489	224	4	.	.	PUNCT
eurjchem-2489	224	5	tapiero	tapiero	PROPN
eurjchem-2489	224	6	,	,	PUNCT
eurjchem-2489	224	7	h.	h.	PROPN
eurjchem-2489	224	8	;	;	PUNCT
eurjchem-2489	224	9	townsend	townsend	PROPN
eurjchem-2489	224	10	,	,	PUNCT
eurjchem-2489	224	11	d.	d.	PROPN
eurjchem-2489	224	12	m.	m.	PROPN
eurjchem-2489	224	13	;	;	PUNCT
eurjchem-2489	224	14	tew	tew	PROPN
eurjchem-2489	224	15	,	,	PUNCT
eurjchem-2489	224	16	k.	k.	PROPN
eurjchem-2489	224	17	d.	d.	PROPN
eurjchem-2489	224	18	trace	trace	NOUN
eurjchem-2489	224	19	elements	element	NOUN
eurjchem-2489	224	20	in	in	ADP
eurjchem-2489	224	21	human	human	ADJ
eurjchem-2489	224	22	physiology	physiology	NOUN
eurjchem-2489	224	23	and	and	CCONJ
eurjchem-2489	224	24	pathology	pathology	NOUN
eurjchem-2489	224	25	.	.	PUNCT
eurjchem-2489	225	1	copper	copper	NOUN
eurjchem-2489	225	2	.	.	PROPN
eurjchem-2489	225	3	biomed	biome	VERB
eurjchem-2489	225	4	.	.	PUNCT
eurjchem-2489	226	1	pharmacother	pharmacother	ADJ
eurjchem-2489	226	2	.	.	PUNCT
eurjchem-2489	227	1	2003	2003	NUM
eurjchem-2489	227	2	,	,	PUNCT
eurjchem-2489	227	3	57	57	NUM
eurjchem-2489	227	4	,	,	PUNCT
eurjchem-2489	227	5	386–398	386–398	NUM
eurjchem-2489	227	6	.	.	PUNCT
eurjchem-2489	228	1	[	[	X
eurjchem-2489	228	2	6	6	NUM
eurjchem-2489	228	3	]	]	PUNCT
eurjchem-2489	228	4	.	.	PUNCT
eurjchem-2489	228	5	gerdemann	gerdemann	PROPN
eurjchem-2489	228	6	,	,	PUNCT
eurjchem-2489	228	7	c.	c.	PROPN
eurjchem-2489	228	8	;	;	PUNCT
eurjchem-2489	228	9	eicken	eicken	VERB
eurjchem-2489	228	10	,	,	PUNCT
eurjchem-2489	228	11	c.	c.	PROPN
eurjchem-2489	228	12	;	;	PUNCT
eurjchem-2489	228	13	krebs	krebs	PROPN
eurjchem-2489	228	14	,	,	PUNCT
eurjchem-2489	228	15	b.	b.	PROPN
eurjchem-2489	229	1	the	the	DET
eurjchem-2489	229	2	crystal	crystal	NOUN
eurjchem-2489	229	3	structure	structure	NOUN
eurjchem-2489	229	4	of	of	ADP
eurjchem-2489	229	5	catechol	catechol	NOUN
eurjchem-2489	229	6	oxidase	oxidase	NOUN
eurjchem-2489	229	7	:	:	PUNCT
eurjchem-2489	229	8	new	new	ADJ
eurjchem-2489	229	9	insight	insight	NOUN
eurjchem-2489	229	10	into	into	ADP
eurjchem-2489	229	11	the	the	DET
eurjchem-2489	229	12	function	function	NOUN
eurjchem-2489	229	13	of	of	ADP
eurjchem-2489	229	14	type-3	type-3	NUM
eurjchem-2489	229	15	copper	copper	NOUN
eurjchem-2489	229	16	proteins	protein	NOUN
eurjchem-2489	229	17	.	.	PUNCT
eurjchem-2489	230	1	acc	acc	PROPN
eurjchem-2489	230	2	.	.	PROPN
eurjchem-2489	230	3	chem	chem	PROPN
eurjchem-2489	230	4	.	.	PUNCT
eurjchem-2489	231	1	res	re	NOUN
eurjchem-2489	231	2	.	.	PROPN
eurjchem-2489	231	3	2002	2002	NUM
eurjchem-2489	231	4	,	,	PUNCT
eurjchem-2489	231	5	35	35	NUM
eurjchem-2489	231	6	,	,	PUNCT
eurjchem-2489	231	7	183–191	183–191	NUM
eurjchem-2489	231	8	.	.	PUNCT
eurjchem-2489	232	1	[	[	X
eurjchem-2489	232	2	7	7	NUM
eurjchem-2489	232	3	]	]	PUNCT
eurjchem-2489	232	4	.	.	PUNCT
eurjchem-2489	233	1	halder	halder	PROPN
eurjchem-2489	233	2	,	,	PUNCT
eurjchem-2489	233	3	j.	j.	PROPN
eurjchem-2489	233	4	;	;	PUNCT
eurjchem-2489	233	5	tamuli	tamuli	PROPN
eurjchem-2489	233	6	,	,	PUNCT
eurjchem-2489	233	7	p.	p.	NOUN
eurjchem-2489	233	8	;	;	PUNCT
eurjchem-2489	233	9	bhaduri	bhaduri	NOUN
eurjchem-2489	233	10	,	,	PUNCT
eurjchem-2489	233	11	a.	a.	NOUN
eurjchem-2489	233	12	n.	n.	PROPN
eurjchem-2489	233	13	isolation	isolation	NOUN
eurjchem-2489	233	14	and	and	CCONJ
eurjchem-2489	233	15	characterization	characterization	NOUN
eurjchem-2489	233	16	of	of	ADP
eurjchem-2489	233	17	polyphenol	polyphenol	NOUN
eurjchem-2489	233	18	oxidase	oxidase	NOUN
eurjchem-2489	233	19	from	from	ADP
eurjchem-2489	233	20	indian	indian	ADJ
eurjchem-2489	233	21	tea	tea	NOUN
eurjchem-2489	233	22	leaf	leaf	NOUN
eurjchem-2489	233	23	(	(	PUNCT
eurjchem-2489	233	24	camellia	camellia	NOUN
eurjchem-2489	233	25	sinensis	sinensis	NOUN
eurjchem-2489	233	26	)	)	PUNCT
eurjchem-2489	233	27	.	.	PUNCT
eurjchem-2489	234	1	j.	j.	PROPN
eurjchem-2489	234	2	nutr	nutr	PROPN
eurjchem-2489	234	3	.	.	PROPN
eurjchem-2489	234	4	biochem	biochem	PROPN
eurjchem-2489	234	5	.	.	PUNCT
eurjchem-2489	235	1	1998	1998	NUM
eurjchem-2489	235	2	,	,	PUNCT
eurjchem-2489	235	3	9	9	NUM
eurjchem-2489	235	4	,	,	PUNCT
eurjchem-2489	235	5	75–80	75–80	PROPN
eurjchem-2489	235	6	.	.	PUNCT
eurjchem-2489	236	1	[	[	X
eurjchem-2489	236	2	8	8	NUM
eurjchem-2489	236	3	]	]	PUNCT
eurjchem-2489	236	4	.	.	PUNCT
eurjchem-2489	237	1	koval	koval	PROPN
eurjchem-2489	237	2	,	,	PUNCT
eurjchem-2489	237	3	i.	i.	PROPN
eurjchem-2489	237	4	a.	a.	PROPN
eurjchem-2489	237	5	;	;	PUNCT
eurjchem-2489	237	6	gamez	gamez	NOUN
eurjchem-2489	237	7	,	,	PUNCT
eurjchem-2489	237	8	p.	p.	PROPN
eurjchem-2489	237	9	;	;	PUNCT
eurjchem-2489	237	10	belle	belle	PROPN
eurjchem-2489	237	11	,	,	PUNCT
eurjchem-2489	237	12	c.	c.	PROPN
eurjchem-2489	237	13	;	;	PUNCT
eurjchem-2489	237	14	selmeczi	selmeczi	PROPN
eurjchem-2489	237	15	,	,	PUNCT
eurjchem-2489	237	16	k.	k.	PROPN
eurjchem-2489	237	17	;	;	PUNCT
eurjchem-2489	237	18	reedijk	reedijk	PROPN
eurjchem-2489	237	19	,	,	PUNCT
eurjchem-2489	237	20	j.	j.	PROPN
eurjchem-2489	237	21	synthetic	synthetic	PROPN
eurjchem-2489	237	22	models	model	NOUN
eurjchem-2489	237	23	of	of	ADP
eurjchem-2489	237	24	the	the	DET
eurjchem-2489	237	25	active	active	ADJ
eurjchem-2489	237	26	site	site	NOUN
eurjchem-2489	237	27	of	of	ADP
eurjchem-2489	237	28	catechol	catechol	NOUN
eurjchem-2489	237	29	oxidase	oxidase	NOUN
eurjchem-2489	237	30	:	:	PUNCT
eurjchem-2489	237	31	mechanistic	mechanistic	ADJ
eurjchem-2489	237	32	studies	study	NOUN
eurjchem-2489	237	33	.	.	PUNCT
eurjchem-2489	238	1	chem	chem	NOUN
eurjchem-2489	238	2	.	.	PUNCT
eurjchem-2489	239	1	soc	soc	PROPN
eurjchem-2489	239	2	.	.	PUNCT
eurjchem-2489	240	1	rev	rev	PROPN
eurjchem-2489	240	2	.	.	PROPN
eurjchem-2489	240	3	2006	2006	NUM
eurjchem-2489	240	4	,	,	PUNCT
eurjchem-2489	240	5	35	35	NUM
eurjchem-2489	240	6	,	,	PUNCT
eurjchem-2489	240	7	814–840	814–840	NUM
eurjchem-2489	240	8	.	.	PUNCT
eurjchem-2489	241	1	[	[	X
eurjchem-2489	241	2	9	9	NUM
eurjchem-2489	241	3	]	]	PUNCT
eurjchem-2489	241	4	.	.	PUNCT
eurjchem-2489	242	1	drewry	drewry	PROPN
eurjchem-2489	242	2	,	,	PUNCT
eurjchem-2489	242	3	j.	j.	PROPN
eurjchem-2489	242	4	a.	a.	PROPN
eurjchem-2489	242	5	;	;	PUNCT
eurjchem-2489	242	6	gunning	gun	VERB
eurjchem-2489	242	7	,	,	PUNCT
eurjchem-2489	242	8	p.	p.	NOUN
eurjchem-2489	242	9	t.	t.	PROPN
eurjchem-2489	243	1	recent	recent	ADJ
eurjchem-2489	243	2	advances	advance	NOUN
eurjchem-2489	243	3	in	in	ADP
eurjchem-2489	243	4	biosensory	biosensory	ADJ
eurjchem-2489	243	5	and	and	CCONJ
eurjchem-2489	243	6	medicinal	medicinal	ADJ
eurjchem-2489	243	7	therapeutic	therapeutic	ADJ
eurjchem-2489	243	8	applications	application	NOUN
eurjchem-2489	243	9	of	of	ADP
eurjchem-2489	243	10	zinc(ii	zinc(ii	PROPN
eurjchem-2489	243	11	)	)	PUNCT
eurjchem-2489	243	12	and	and	CCONJ
eurjchem-2489	243	13	copper(ii	copper(ii	NOUN
eurjchem-2489	243	14	)	)	PUNCT
eurjchem-2489	243	15	coordination	coordination	NOUN
eurjchem-2489	243	16	complexes	complex	NOUN
eurjchem-2489	243	17	.	.	PUNCT
eurjchem-2489	244	1	coord	coord	NOUN
eurjchem-2489	244	2	.	.	PUNCT
eurjchem-2489	245	1	chem	chem	PROPN
eurjchem-2489	245	2	.	.	PUNCT
eurjchem-2489	246	1	rev	rev	PROPN
eurjchem-2489	246	2	.	.	PROPN
eurjchem-2489	246	3	2011	2011	NUM
eurjchem-2489	246	4	,	,	PUNCT
eurjchem-2489	246	5	255	255	NUM
eurjchem-2489	246	6	,	,	PUNCT
eurjchem-2489	246	7	459–472	459–472	NUM
eurjchem-2489	246	8	.	.	PUNCT
eurjchem-2489	247	1	[	[	X
eurjchem-2489	247	2	10	10	NUM
eurjchem-2489	247	3	]	]	PUNCT
eurjchem-2489	247	4	.	.	PUNCT
eurjchem-2489	247	5	sorenson	sorenson	PROPN
eurjchem-2489	247	6	,	,	PUNCT
eurjchem-2489	247	7	j.	j.	PROPN
eurjchem-2489	247	8	r.	r.	PROPN
eurjchem-2489	247	9	j.	j.	PROPN
eurjchem-2489	247	10	6	6	NUM
eurjchem-2489	247	11	copper	copper	NOUN
eurjchem-2489	247	12	complexes	complex	NOUN
eurjchem-2489	247	13	offer	offer	VERB
eurjchem-2489	247	14	a	a	DET
eurjchem-2489	247	15	physiological	physiological	ADJ
eurjchem-2489	247	16	approach	approach	NOUN
eurjchem-2489	247	17	to	to	ADP
eurjchem-2489	247	18	treatment	treatment	NOUN
eurjchem-2489	247	19	of	of	ADP
eurjchem-2489	247	20	chronic	chronic	ADJ
eurjchem-2489	247	21	diseases	disease	NOUN
eurjchem-2489	247	22	.	.	PUNCT
eurjchem-2489	248	1	in	in	ADP
eurjchem-2489	248	2	progress	progress	NOUN
eurjchem-2489	248	3	in	in	ADP
eurjchem-2489	248	4	medicinal	medicinal	ADJ
eurjchem-2489	248	5	chemistry	chemistry	NOUN
eurjchem-2489	248	6	;	;	PUNCT
eurjchem-2489	248	7	elsevier	elsevier	NOUN
eurjchem-2489	248	8	,	,	PUNCT
eurjchem-2489	248	9	1989	1989	NUM
eurjchem-2489	248	10	;	;	PUNCT
eurjchem-2489	248	11	pp	pp	ADP
eurjchem-2489	248	12	.	.	PUNCT
eurjchem-2489	249	1	437–568	437–568	NUM
eurjchem-2489	249	2	.	.	PUNCT
eurjchem-2489	250	1	[	[	X
eurjchem-2489	250	2	11	11	NUM
eurjchem-2489	250	3	]	]	PUNCT
eurjchem-2489	250	4	.	.	PUNCT
eurjchem-2489	251	1	jayamani	jayamani	PROPN
eurjchem-2489	251	2	,	,	PUNCT
eurjchem-2489	251	3	a.	a.	NOUN
eurjchem-2489	251	4	;	;	PUNCT
eurjchem-2489	251	5	sengottuvelan	sengottuvelan	NOUN
eurjchem-2489	251	6	,	,	PUNCT
eurjchem-2489	251	7	n.	n.	NOUN
eurjchem-2489	251	8	;	;	PUNCT
eurjchem-2489	251	9	chakkaravarthi	chakkaravarthi	PROPN
eurjchem-2489	251	10	,	,	PUNCT
eurjchem-2489	251	11	g.	g.	PROPN
eurjchem-2489	251	12	synthesis	synthesis	PROPN
eurjchem-2489	251	13	,	,	PUNCT
eurjchem-2489	251	14	structural	structural	ADJ
eurjchem-2489	251	15	,	,	PUNCT
eurjchem-2489	251	16	electrochemical	electrochemical	ADJ
eurjchem-2489	251	17	,	,	PUNCT
eurjchem-2489	251	18	dna	dna	NOUN
eurjchem-2489	251	19	interaction	interaction	NOUN
eurjchem-2489	251	20	,	,	PUNCT
eurjchem-2489	251	21	antimicrobial	antimicrobial	ADJ
eurjchem-2489	251	22	and	and	CCONJ
eurjchem-2489	251	23	molecular	molecular	ADJ
eurjchem-2489	251	24	docking	docking	NOUN
eurjchem-2489	251	25	studies	study	NOUN
eurjchem-2489	251	26	on	on	ADP
eurjchem-2489	251	27	dimeric	dimeric	ADJ
eurjchem-2489	251	28	copper(ii	copper(ii	NOUN
eurjchem-2489	251	29	)	)	PUNCT
eurjchem-2489	251	30	complexes	complex	NOUN
eurjchem-2489	251	31	involving	involve	VERB
eurjchem-2489	251	32	some	some	DET
eurjchem-2489	251	33	potential	potential	ADJ
eurjchem-2489	251	34	bidentate	bidentate	NOUN
eurjchem-2489	251	35	ligands	ligand	NOUN
eurjchem-2489	251	36	.	.	PUNCT
eurjchem-2489	252	1	polyhedron	polyhedron	NOUN
eurjchem-2489	252	2	2014	2014	NUM
eurjchem-2489	252	3	,	,	PUNCT
eurjchem-2489	252	4	81	81	NUM
eurjchem-2489	252	5	,	,	PUNCT
eurjchem-2489	252	6	764–776	764–776	NUM
eurjchem-2489	252	7	.	.	PUNCT
eurjchem-2489	253	1	[	[	X
eurjchem-2489	253	2	12	12	NUM
eurjchem-2489	253	3	]	]	PUNCT
eurjchem-2489	253	4	.	.	PUNCT
eurjchem-2489	254	1	elo	elo	NOUN
eurjchem-2489	254	2	,	,	PUNCT
eurjchem-2489	254	3	h.	h.	PROPN
eurjchem-2489	254	4	;	;	PUNCT
eurjchem-2489	254	5	kuure	kuure	NOUN
eurjchem-2489	254	6	,	,	PUNCT
eurjchem-2489	254	7	m.	m.	NOUN
eurjchem-2489	254	8	;	;	PUNCT
eurjchem-2489	254	9	pelttari	pelttari	PROPN
eurjchem-2489	254	10	,	,	PUNCT
eurjchem-2489	254	11	e.	e.	PROPN
eurjchem-2489	254	12	correlation	correlation	NOUN
eurjchem-2489	254	13	of	of	ADP
eurjchem-2489	254	14	the	the	DET
eurjchem-2489	254	15	antimicrobial	antimicrobial	ADJ
eurjchem-2489	254	16	activity	activity	NOUN
eurjchem-2489	254	17	of	of	ADP
eurjchem-2489	254	18	salicylaldehydes	salicylaldehyde	NOUN
eurjchem-2489	254	19	with	with	ADP
eurjchem-2489	254	20	broadening	broaden	VERB
eurjchem-2489	254	21	of	of	ADP
eurjchem-2489	254	22	the	the	DET
eurjchem-2489	254	23	nmr	nmr	NOUN
eurjchem-2489	254	24	signal	signal	NOUN
eurjchem-2489	254	25	of	of	ADP
eurjchem-2489	254	26	the	the	DET
eurjchem-2489	254	27	hydroxyl	hydroxyl	NOUN
eurjchem-2489	254	28	proton	proton	NOUN
eurjchem-2489	254	29	.	.	PUNCT
eurjchem-2489	255	1	possible	possible	ADJ
eurjchem-2489	255	2	involvement	involvement	NOUN
eurjchem-2489	255	3	of	of	ADP
eurjchem-2489	255	4	proton	proton	NOUN
eurjchem-2489	255	5	exchange	exchange	NOUN
eurjchem-2489	255	6	processes	process	NOUN
eurjchem-2489	255	7	in	in	ADP
eurjchem-2489	255	8	the	the	DET
eurjchem-2489	255	9	antimicrobial	antimicrobial	ADJ
eurjchem-2489	255	10	activity	activity	NOUN
eurjchem-2489	255	11	.	.	PUNCT
eurjchem-2489	256	1	eur	eur	PROPN
eurjchem-2489	256	2	.	.	PUNCT
eurjchem-2489	257	1	j.	j.	PROPN
eurjchem-2489	257	2	med	med	PROPN
eurjchem-2489	257	3	.	.	PROPN
eurjchem-2489	257	4	chem	chem	PROPN
eurjchem-2489	257	5	.	.	PUNCT
eurjchem-2489	258	1	2015	2015	NUM
eurjchem-2489	258	2	,	,	PUNCT
eurjchem-2489	258	3	92	92	NUM
eurjchem-2489	258	4	,	,	PUNCT
eurjchem-2489	258	5	750–753	750–753	NUM
eurjchem-2489	258	6	.	.	PUNCT
eurjchem-2489	259	1	[	[	X
eurjchem-2489	259	2	13	13	NUM
eurjchem-2489	259	3	]	]	PUNCT
eurjchem-2489	259	4	.	.	PUNCT
eurjchem-2489	260	1	costa	costa	PROPN
eurjchem-2489	260	2	pessoa	pessoa	PROPN
eurjchem-2489	260	3	,	,	PUNCT
eurjchem-2489	260	4	j.	j.	PROPN
eurjchem-2489	260	5	;	;	PUNCT
eurjchem-2489	260	6	cavaco	cavaco	PROPN
eurjchem-2489	260	7	,	,	PUNCT
eurjchem-2489	260	8	i.	i.	PROPN
eurjchem-2489	260	9	;	;	PUNCT
eurjchem-2489	260	10	correia	correia	PROPN
eurjchem-2489	260	11	,	,	PUNCT
eurjchem-2489	260	12	i.	i.	PROPN
eurjchem-2489	260	13	;	;	PUNCT
eurjchem-2489	260	14	tomaz	tomaz	PROPN
eurjchem-2489	260	15	,	,	PUNCT
eurjchem-2489	260	16	i.	i.	PROPN
eurjchem-2489	260	17	;	;	PUNCT
eurjchem-2489	260	18	duarte	duarte	PROPN
eurjchem-2489	260	19	,	,	PUNCT
eurjchem-2489	260	20	t.	t.	PROPN
eurjchem-2489	260	21	;	;	PUNCT
eurjchem-2489	260	22	matias	matias	PROPN
eurjchem-2489	260	23	,	,	PUNCT
eurjchem-2489	260	24	p.	p.	PROPN
eurjchem-2489	260	25	m.	m.	NOUN
eurjchem-2489	260	26	oxovanadium(iv	oxovanadium(iv	PROPN
eurjchem-2489	260	27	)	)	PUNCT
eurjchem-2489	260	28	complexes	complex	NOUN
eurjchem-2489	260	29	with	with	ADP
eurjchem-2489	260	30	aromatic	aromatic	ADJ
eurjchem-2489	260	31	aldehydes	aldehyde	NOUN
eurjchem-2489	260	32	.	.	PUNCT
eurjchem-2489	261	1	j.	j.	PROPN
eurjchem-2489	261	2	inorg	inorg	PROPN
eurjchem-2489	261	3	.	.	PUNCT
eurjchem-2489	262	1	biochem	biochem	PROPN
eurjchem-2489	262	2	.	.	PUNCT
eurjchem-2489	263	1	2000	2000	NUM
eurjchem-2489	263	2	,	,	PUNCT
eurjchem-2489	263	3	80	80	NUM
eurjchem-2489	263	4	,	,	PUNCT
eurjchem-2489	263	5	35–39	35–39	NUM
eurjchem-2489	263	6	.	.	PUNCT
eurjchem-2489	264	1	[	[	X
eurjchem-2489	264	2	14	14	NUM
eurjchem-2489	264	3	]	]	PUNCT
eurjchem-2489	264	4	.	.	PUNCT
eurjchem-2489	265	1	solomon	solomon	PROPN
eurjchem-2489	265	2	,	,	PUNCT
eurjchem-2489	265	3	e.	e.	PROPN
eurjchem-2489	265	4	i.	i.	PROPN
eurjchem-2489	265	5	;	;	PUNCT
eurjchem-2489	265	6	heppner	heppner	PROPN
eurjchem-2489	265	7	,	,	PUNCT
eurjchem-2489	265	8	d.	d.	PROPN
eurjchem-2489	265	9	e.	e.	PROPN
eurjchem-2489	265	10	;	;	PUNCT
eurjchem-2489	265	11	johnston	johnston	PROPN
eurjchem-2489	265	12	,	,	PUNCT
eurjchem-2489	265	13	e.	e.	PROPN
eurjchem-2489	265	14	m.	m.	PROPN
eurjchem-2489	265	15	;	;	PUNCT
eurjchem-2489	265	16	ginsbach	ginsbach	PROPN
eurjchem-2489	265	17	,	,	PUNCT
eurjchem-2489	265	18	j.	j.	PROPN
eurjchem-2489	265	19	w.	w.	PROPN
eurjchem-2489	265	20	;	;	PUNCT
eurjchem-2489	265	21	cirera	cirera	PROPN
eurjchem-2489	265	22	,	,	PUNCT
eurjchem-2489	265	23	j.	j.	PROPN
eurjchem-2489	265	24	;	;	PUNCT
eurjchem-2489	265	25	qayyum	qayyum	NOUN
eurjchem-2489	265	26	,	,	PUNCT
eurjchem-2489	265	27	m.	m.	NOUN
eurjchem-2489	265	28	;	;	PUNCT
eurjchem-2489	265	29	kieber	kieber	PROPN
eurjchem-2489	265	30	-	-	PUNCT
eurjchem-2489	265	31	emmons	emmons	PROPN
eurjchem-2489	265	32	,	,	PUNCT
eurjchem-2489	265	33	m.	m.	NOUN
eurjchem-2489	265	34	t.	t.	PROPN
eurjchem-2489	265	35	;	;	PUNCT
eurjchem-2489	265	36	kjaergaard	kjaergaard	PROPN
eurjchem-2489	265	37	,	,	PUNCT
eurjchem-2489	265	38	c.	c.	PROPN
eurjchem-2489	265	39	h.	h.	PROPN
eurjchem-2489	265	40	;	;	PUNCT
eurjchem-2489	265	41	hadt	hadt	PROPN
eurjchem-2489	265	42	,	,	PUNCT
eurjchem-2489	265	43	r.	r.	PROPN
eurjchem-2489	265	44	g.	g.	PROPN
eurjchem-2489	265	45	;	;	PUNCT
eurjchem-2489	265	46	tian	tian	PROPN
eurjchem-2489	265	47	,	,	PUNCT
eurjchem-2489	265	48	l.	l.	PROPN
eurjchem-2489	265	49	copper	copper	PROPN
eurjchem-2489	265	50	active	active	ADJ
eurjchem-2489	265	51	sites	site	NOUN
eurjchem-2489	265	52	in	in	ADP
eurjchem-2489	265	53	biology	biology	NOUN
eurjchem-2489	265	54	.	.	PUNCT
eurjchem-2489	266	1	chem	chem	PROPN
eurjchem-2489	266	2	.	.	PUNCT
eurjchem-2489	267	1	rev	rev	PROPN
eurjchem-2489	267	2	.	.	PROPN
eurjchem-2489	267	3	2014	2014	NUM
eurjchem-2489	267	4	,	,	PUNCT
eurjchem-2489	267	5	114	114	NUM
eurjchem-2489	267	6	,	,	PUNCT
eurjchem-2489	267	7	3659	3659	NUM
eurjchem-2489	267	8	–	–	PUNCT
eurjchem-2489	267	9	3853	3853	NUM
eurjchem-2489	267	10	.	.	PUNCT
eurjchem-2489	268	1	[	[	X
eurjchem-2489	268	2	15	15	NUM
eurjchem-2489	268	3	]	]	PUNCT
eurjchem-2489	268	4	.	.	PUNCT
eurjchem-2489	269	1	solomon	solomon	PROPN
eurjchem-2489	269	2	,	,	PUNCT
eurjchem-2489	269	3	e.	e.	PROPN
eurjchem-2489	269	4	i.	i.	PROPN
eurjchem-2489	269	5	;	;	PUNCT
eurjchem-2489	269	6	baldwin	baldwin	PROPN
eurjchem-2489	269	7	,	,	PUNCT
eurjchem-2489	269	8	m.	m.	NOUN
eurjchem-2489	269	9	j.	j.	PROPN
eurjchem-2489	269	10	;	;	PUNCT
eurjchem-2489	269	11	lowery	lowery	PROPN
eurjchem-2489	269	12	,	,	PUNCT
eurjchem-2489	269	13	m.	m.	PROPN
eurjchem-2489	269	14	d.	d.	PROPN
eurjchem-2489	269	15	electronic	electronic	PROPN
eurjchem-2489	269	16	structures	structure	NOUN
eurjchem-2489	269	17	of	of	ADP
eurjchem-2489	269	18	active	active	ADJ
eurjchem-2489	269	19	sites	site	NOUN
eurjchem-2489	269	20	in	in	ADP
eurjchem-2489	269	21	copper	copper	NOUN
eurjchem-2489	269	22	proteins	protein	NOUN
eurjchem-2489	269	23	:	:	PUNCT
eurjchem-2489	269	24	contributions	contribution	NOUN
eurjchem-2489	269	25	to	to	ADP
eurjchem-2489	269	26	reactivity	reactivity	NOUN
eurjchem-2489	269	27	.	.	PUNCT
eurjchem-2489	270	1	chem	chem	NOUN
eurjchem-2489	270	2	.	.	PUNCT
eurjchem-2489	271	1	rev	rev	PROPN
eurjchem-2489	271	2	.	.	PROPN
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eurjchem-2489	271	4	,	,	PUNCT
eurjchem-2489	271	5	92	92	NUM
eurjchem-2489	271	6	,	,	PUNCT
eurjchem-2489	271	7	521–542	521–542	NUM
eurjchem-2489	271	8	.	.	PUNCT
eurjchem-2489	272	1	[	[	X
eurjchem-2489	272	2	16	16	NUM
eurjchem-2489	272	3	]	]	PUNCT
eurjchem-2489	272	4	.	.	PUNCT
eurjchem-2489	273	1	punniyamurthy	punniyamurthy	ADJ
eurjchem-2489	273	2	,	,	PUNCT
eurjchem-2489	273	3	t.	t.	PROPN
eurjchem-2489	273	4	;	;	PUNCT
eurjchem-2489	273	5	rout	rout	PROPN
eurjchem-2489	273	6	,	,	PUNCT
eurjchem-2489	273	7	l.	l.	PROPN
eurjchem-2489	273	8	recent	recent	ADJ
eurjchem-2489	273	9	advances	advance	NOUN
eurjchem-2489	273	10	in	in	ADP
eurjchem-2489	273	11	copper	copper	NOUN
eurjchem-2489	273	12	-	-	PUNCT
eurjchem-2489	273	13	catalyzed	catalyze	VERB
eurjchem-2489	273	14	oxidation	oxidation	NOUN
eurjchem-2489	273	15	of	of	ADP
eurjchem-2489	273	16	organic	organic	ADJ
eurjchem-2489	273	17	compounds	compound	NOUN
eurjchem-2489	273	18	.	.	PUNCT
eurjchem-2489	274	1	coord	coord	NOUN
eurjchem-2489	274	2	.	.	PUNCT
eurjchem-2489	275	1	chem	chem	PROPN
eurjchem-2489	275	2	.	.	PUNCT
eurjchem-2489	276	1	rev	rev	PROPN
eurjchem-2489	276	2	.	.	PROPN
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eurjchem-2489	276	4	,	,	PUNCT
eurjchem-2489	276	5	252	252	NUM
eurjchem-2489	276	6	,	,	PUNCT
eurjchem-2489	276	7	134	134	NUM
eurjchem-2489	276	8	–	–	PUNCT
eurjchem-2489	276	9	154	154	NUM
eurjchem-2489	276	10	.	.	PUNCT
eurjchem-2489	277	1	[	[	X
eurjchem-2489	277	2	17	17	NUM
eurjchem-2489	277	3	]	]	PUNCT
eurjchem-2489	277	4	.	.	PUNCT
eurjchem-2489	278	1	selmeczi	selmeczi	PROPN
eurjchem-2489	278	2	,	,	PUNCT
eurjchem-2489	278	3	k.	k.	PROPN
eurjchem-2489	278	4	;	;	PUNCT
eurjchem-2489	278	5	réglier	réglier	NOUN
eurjchem-2489	278	6	,	,	PUNCT
eurjchem-2489	278	7	m.	m.	NOUN
eurjchem-2489	278	8	;	;	PUNCT
eurjchem-2489	278	9	giorgi	giorgi	NOUN
eurjchem-2489	278	10	,	,	PUNCT
eurjchem-2489	278	11	m.	m.	NOUN
eurjchem-2489	278	12	;	;	PUNCT
eurjchem-2489	278	13	speier	speier	NOUN
eurjchem-2489	278	14	,	,	PUNCT
eurjchem-2489	278	15	g.	g.	PROPN
eurjchem-2489	278	16	catechol	catechol	NOUN
eurjchem-2489	278	17	oxidase	oxidase	NOUN
eurjchem-2489	278	18	activity	activity	NOUN
eurjchem-2489	278	19	of	of	ADP
eurjchem-2489	278	20	dicopper	dicopper	NOUN
eurjchem-2489	278	21	complexes	complex	NOUN
eurjchem-2489	278	22	with	with	ADP
eurjchem-2489	278	23	n	n	CCONJ
eurjchem-2489	278	24	-	-	PUNCT
eurjchem-2489	278	25	donor	donor	NOUN
eurjchem-2489	278	26	ligands	ligand	NOUN
eurjchem-2489	278	27	☆	☆	NOUN
eurjchem-2489	278	28	.	.	PUNCT
eurjchem-2489	278	29	coord	coord	NOUN
eurjchem-2489	278	30	.	.	PUNCT
eurjchem-2489	279	1	chem	chem	PROPN
eurjchem-2489	279	2	.	.	PUNCT
eurjchem-2489	280	1	rev	rev	PROPN
eurjchem-2489	280	2	.	.	PROPN
eurjchem-2489	280	3	2003	2003	NUM
eurjchem-2489	280	4	,	,	PUNCT
eurjchem-2489	280	5	245	245	NUM
eurjchem-2489	280	6	,	,	PUNCT
eurjchem-2489	280	7	191–201	191–201	NUM
eurjchem-2489	280	8	.	.	PUNCT
eurjchem-2489	281	1	[	[	X
eurjchem-2489	281	2	18	18	NUM
eurjchem-2489	281	3	]	]	PUNCT
eurjchem-2489	281	4	.	.	PUNCT
eurjchem-2489	282	1	agilent	agilent	PROPN
eurjchem-2489	282	2	(	(	PUNCT
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eurjchem-2489	282	4	)	)	PUNCT
eurjchem-2489	282	5	.	.	PUNCT
eurjchem-2489	283	1	crysalis	crysalis	PROPN
eurjchem-2489	283	2	pro	pro	X
eurjchem-2489	283	3	.	.	PUNCT
eurjchem-2489	284	1	agilent	agilent	PROPN
eurjchem-2489	284	2	technologies	technologies	PROPN
eurjchem-2489	284	3	ltd	ltd	PROPN
eurjchem-2489	284	4	,	,	PUNCT
eurjchem-2489	284	5	yarnton	yarnton	PROPN
eurjchem-2489	284	6	,	,	PUNCT
eurjchem-2489	284	7	oxfordshire	oxfordshire	PROPN
eurjchem-2489	284	8	,	,	PUNCT
eurjchem-2489	284	9	england	england	PROPN
eurjchem-2489	284	10	.	.	PUNCT
eurjchem-2489	285	1	[	[	X
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eurjchem-2489	285	3	]	]	PUNCT
eurjchem-2489	285	4	.	.	PUNCT
eurjchem-2489	285	5	sheldrick	sheldrick	NOUN
eurjchem-2489	285	6	,	,	PUNCT
eurjchem-2489	285	7	g.	g.	PROPN
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eurjchem-2489	285	10	–	–	PUNCT
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eurjchem-2489	285	13	-	-	PUNCT
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eurjchem-2489	285	16	crystalstructure	crystalstructure	NOUN
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eurjchem-2489	285	18	.	.	PUNCT
eurjchem-2489	286	1	acta	acta	PROPN
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eurjchem-2489	286	3	.	.	PUNCT
eurjchem-2489	287	1	a	a	DET
eurjchem-2489	287	2	found	find	VERB
eurjchem-2489	287	3	.	.	PUNCT
eurjchem-2489	288	1	adv	adv	PROPN
eurjchem-2489	288	2	.	.	PROPN
eurjchem-2489	288	3	2015	2015	NUM
eurjchem-2489	288	4	,	,	PUNCT
eurjchem-2489	288	5	71	71	NUM
eurjchem-2489	288	6	,	,	PUNCT
eurjchem-2489	288	7	3	3	NUM
eurjchem-2489	288	8	–	–	PUNCT
eurjchem-2489	288	9	8	8	NUM
eurjchem-2489	288	10	.	.	PUNCT
eurjchem-2489	289	1	[	[	X
eurjchem-2489	289	2	20	20	NUM
eurjchem-2489	289	3	]	]	PUNCT
eurjchem-2489	289	4	.	.	PUNCT
eurjchem-2489	289	5	sheldrick	sheldrick	NOUN
eurjchem-2489	289	6	,	,	PUNCT
eurjchem-2489	289	7	g.	g.	PROPN
eurjchem-2489	289	8	m.	m.	PROPN
eurjchem-2489	289	9	crystal	crystal	PROPN
eurjchem-2489	289	10	structure	structure	NOUN
eurjchem-2489	289	11	refinement	refinement	NOUN
eurjchem-2489	289	12	with	with	ADP
eurjchem-2489	289	13	shelxl	shelxl	NOUN
eurjchem-2489	289	14	.	.	PUNCT
eurjchem-2489	290	1	acta	acta	PROPN
eurjchem-2489	290	2	crystallogr	crystallogr	PROPN
eurjchem-2489	290	3	.	.	PUNCT
eurjchem-2489	291	1	c	c	PROPN
eurjchem-2489	291	2	struct	struct	NOUN
eurjchem-2489	291	3	.	.	PUNCT
eurjchem-2489	292	1	chem	chem	NOUN
eurjchem-2489	292	2	.	.	PUNCT
eurjchem-2489	293	1	2015	2015	NUM
eurjchem-2489	293	2	,	,	PUNCT
eurjchem-2489	293	3	71	71	NUM
eurjchem-2489	293	4	,	,	PUNCT
eurjchem-2489	293	5	3–8	3–8	NUM
eurjchem-2489	293	6	.	.	PUNCT
eurjchem-2489	294	1	[	[	X
eurjchem-2489	294	2	21	21	NUM
eurjchem-2489	294	3	]	]	PUNCT
eurjchem-2489	294	4	.	.	PUNCT
eurjchem-2489	295	1	dolomanov	dolomanov	PROPN
eurjchem-2489	295	2	,	,	PUNCT
eurjchem-2489	295	3	o.	o.	PROPN
eurjchem-2489	295	4	v.	v.	PROPN
eurjchem-2489	295	5	;	;	PUNCT
eurjchem-2489	295	6	bourhis	bourhis	NOUN
eurjchem-2489	295	7	,	,	PUNCT
eurjchem-2489	295	8	l.	l.	PROPN
eurjchem-2489	295	9	j.	j.	PROPN
eurjchem-2489	295	10	;	;	PUNCT
eurjchem-2489	295	11	gildea	gildea	PROPN
eurjchem-2489	295	12	,	,	PUNCT
eurjchem-2489	295	13	r.	r.	PROPN
eurjchem-2489	295	14	j.	j.	PROPN
eurjchem-2489	295	15	;	;	PUNCT
eurjchem-2489	295	16	howard	howard	PROPN
eurjchem-2489	295	17	,	,	PUNCT
eurjchem-2489	295	18	j.	j.	PROPN
eurjchem-2489	295	19	a.	a.	PROPN
eurjchem-2489	295	20	k.	k.	PROPN
eurjchem-2489	295	21	;	;	PUNCT
eurjchem-2489	295	22	puschmann	puschmann	PROPN
eurjchem-2489	295	23	,	,	PUNCT
eurjchem-2489	295	24	h.	h.	PROPN
eurjchem-2489	295	25	olex2	olex2	PROPN
eurjchem-2489	295	26	:	:	PUNCT
eurjchem-2489	295	27	a	a	DET
eurjchem-2489	295	28	complete	complete	ADJ
eurjchem-2489	295	29	structure	structure	NOUN
eurjchem-2489	295	30	solution	solution	NOUN
eurjchem-2489	295	31	,	,	PUNCT
eurjchem-2489	295	32	refinement	refinement	NOUN
eurjchem-2489	295	33	and	and	CCONJ
eurjchem-2489	295	34	analysis	analysis	NOUN
eurjchem-2489	295	35	program	program	NOUN
eurjchem-2489	295	36	.	.	PUNCT
eurjchem-2489	296	1	j.	j.	PROPN
eurjchem-2489	296	2	appl	appl	PROPN
eurjchem-2489	296	3	.	.	PROPN
eurjchem-2489	296	4	crystallogr	crystallogr	PROPN
eurjchem-2489	296	5	.	.	PUNCT
eurjchem-2489	297	1	2009	2009	NUM
eurjchem-2489	297	2	,	,	PUNCT
eurjchem-2489	297	3	42	42	NUM
eurjchem-2489	297	4	,	,	PUNCT
eurjchem-2489	297	5	339–341	339–341	NUM
eurjchem-2489	297	6	.	.	PUNCT
eurjchem-2489	298	1	[	[	X
eurjchem-2489	298	2	22	22	NUM
eurjchem-2489	298	3	]	]	PUNCT
eurjchem-2489	298	4	.	.	PUNCT
eurjchem-2489	298	5	mukherjee	mukherjee	PROPN
eurjchem-2489	298	6	,	,	PUNCT
eurjchem-2489	298	7	s.	s.	PROPN
eurjchem-2489	298	8	;	;	PUNCT
eurjchem-2489	298	9	pal	pal	NOUN
eurjchem-2489	298	10	,	,	PUNCT
eurjchem-2489	298	11	c.	c.	PROPN
eurjchem-2489	298	12	k.	k.	PROPN
eurjchem-2489	298	13	;	;	PUNCT
eurjchem-2489	298	14	kotakonda	kotakonda	PROPN
eurjchem-2489	298	15	,	,	PUNCT
eurjchem-2489	298	16	m.	m.	NOUN
eurjchem-2489	298	17	;	;	PUNCT
eurjchem-2489	298	18	joshi	joshi	PROPN
eurjchem-2489	298	19	,	,	PUNCT
eurjchem-2489	298	20	m.	m.	NOUN
eurjchem-2489	298	21	;	;	PUNCT
eurjchem-2489	298	22	shit	shit	NOUN
eurjchem-2489	298	23	,	,	PUNCT
eurjchem-2489	298	24	m.	m.	NOUN
eurjchem-2489	298	25	;	;	PUNCT
eurjchem-2489	298	26	ghosh	ghosh	PROPN
eurjchem-2489	298	27	,	,	PUNCT
eurjchem-2489	298	28	p.	p.	PROPN
eurjchem-2489	298	29	;	;	PUNCT
eurjchem-2489	298	30	choudhury	choudhury	PROPN
eurjchem-2489	298	31	,	,	PUNCT
eurjchem-2489	298	32	a.	a.	PROPN
eurjchem-2489	298	33	r.	r.	PROPN
eurjchem-2489	298	34	;	;	PUNCT
eurjchem-2489	298	35	biswas	biswas	PROPN
eurjchem-2489	298	36	,	,	PUNCT
eurjchem-2489	298	37	b.	b.	PROPN
eurjchem-2489	298	38	solvent	solvent	PROPN
eurjchem-2489	298	39	induced	induce	VERB
eurjchem-2489	298	40	distortion	distortion	NOUN
eurjchem-2489	298	41	in	in	ADP
eurjchem-2489	298	42	a	a	DET
eurjchem-2489	298	43	square	square	ADJ
eurjchem-2489	298	44	planar	planar	ADJ
eurjchem-2489	298	45	copper(ii	copper(ii	NOUN
eurjchem-2489	298	46	)	)	PUNCT
eurjchem-2489	298	47	complex	complex	NOUN
eurjchem-2489	298	48	containing	contain	VERB
eurjchem-2489	298	49	an	an	DET
eurjchem-2489	298	50	azo	azo	NOUN
eurjchem-2489	298	51	-	-	PUNCT
eurjchem-2489	298	52	functionalized	functionalize	VERB
eurjchem-2489	298	53	schiff	schiff	NOUN
eurjchem-2489	298	54	base	base	NOUN
eurjchem-2489	298	55	:	:	PUNCT
eurjchem-2489	298	56	synthesis	synthesis	NOUN
eurjchem-2489	298	57	,	,	PUNCT
eurjchem-2489	298	58	crystal	crystal	NOUN
eurjchem-2489	298	59	structure	structure	NOUN
eurjchem-2489	298	60	,	,	PUNCT
eurjchem-2489	298	61	in	in	ADP
eurjchem-2489	298	62	-	-	PUNCT
eurjchem-2489	298	63	vitro	vitro	X
eurjchem-2489	298	64	fungicidal	fungicidal	NOUN
eurjchem-2489	298	65	and	and	CCONJ
eurjchem-2489	298	66	antiproliferative	antiproliferative	NOUN
eurjchem-2489	298	67	,	,	PUNCT
eurjchem-2489	298	68	and	and	CCONJ
eurjchem-2489	298	69	catecholase	catecholase	NOUN
eurjchem-2489	298	70	activity	activity	NOUN
eurjchem-2489	298	71	.	.	PUNCT
eurjchem-2489	299	1	j.	j.	PROPN
eurjchem-2489	299	2	mol	mol	PROPN
eurjchem-2489	299	3	.	.	PROPN
eurjchem-2489	299	4	struct	struct	NOUN
eurjchem-2489	299	5	.	.	PUNCT
eurjchem-2489	299	6	2021	2021	NUM
eurjchem-2489	299	7	,	,	PUNCT
eurjchem-2489	299	8	1245	1245	NUM
eurjchem-2489	299	9	,	,	PUNCT
eurjchem-2489	299	10	131057	131057	NUM
eurjchem-2489	299	11	.	.	PUNCT
eurjchem-2489	300	1	[	[	X
eurjchem-2489	300	2	23	23	NUM
eurjchem-2489	300	3	]	]	PUNCT
eurjchem-2489	300	4	.	.	PUNCT
eurjchem-2489	301	1	dey	dey	PROPN
eurjchem-2489	301	2	,	,	PUNCT
eurjchem-2489	301	3	d.	d.	PROPN
eurjchem-2489	301	4	;	;	PUNCT
eurjchem-2489	301	5	de	de	PROPN
eurjchem-2489	301	6	,	,	PUNCT
eurjchem-2489	301	7	a.	a.	NOUN
eurjchem-2489	301	8	;	;	PUNCT
eurjchem-2489	301	9	yadav	yadav	PROPN
eurjchem-2489	301	10	,	,	PUNCT
eurjchem-2489	301	11	h.	h.	PROPN
eurjchem-2489	301	12	r.	r.	PROPN
eurjchem-2489	301	13	;	;	PUNCT
eurjchem-2489	301	14	guin	guin	PROPN
eurjchem-2489	301	15	,	,	PUNCT
eurjchem-2489	301	16	p.	p.	PROPN
eurjchem-2489	301	17	s.	s.	PROPN
eurjchem-2489	301	18	;	;	PUNCT
eurjchem-2489	301	19	choudhury	choudhury	PROPN
eurjchem-2489	301	20	,	,	PUNCT
eurjchem-2489	301	21	a.	a.	PROPN
eurjchem-2489	301	22	r.	r.	PROPN
eurjchem-2489	301	23	;	;	PUNCT
eurjchem-2489	301	24	kole	kole	PROPN
eurjchem-2489	301	25	,	,	PUNCT
eurjchem-2489	301	26	n.	n.	PROPN
eurjchem-2489	301	27	;	;	PUNCT
eurjchem-2489	301	28	biswas	biswas	PROPN
eurjchem-2489	301	29	,	,	PUNCT
eurjchem-2489	301	30	b.	b.	PROPN
eurjchem-2489	302	1	an	an	DET
eurjchem-2489	302	2	oxido	oxido	ADV
eurjchem-2489	302	3	-	-	PUNCT
eurjchem-2489	302	4	bridged	bridge	VERB
eurjchem-2489	302	5	diiron(ii	diiron(ii	NOUN
eurjchem-2489	302	6	)	)	PUNCT
eurjchem-2489	302	7	complex	complex	NOUN
eurjchem-2489	302	8	as	as	ADP
eurjchem-2489	302	9	functional	functional	ADJ
eurjchem-2489	302	10	model	model	NOUN
eurjchem-2489	302	11	of	of	ADP
eurjchem-2489	302	12	catechol	catechol	NOUN
eurjchem-2489	302	13	dioxygenase	dioxygenase	NOUN
eurjchem-2489	302	14	.	.	PUNCT
eurjchem-2489	303	1	chemistryselect	chemistryselect	NOUN
eurjchem-2489	303	2	2016	2016	NUM
eurjchem-2489	303	3	,	,	PUNCT
eurjchem-2489	303	4	1	1	NUM
eurjchem-2489	303	5	,	,	PUNCT
eurjchem-2489	303	6	1910–1916	1910–1916	NUM
eurjchem-2489	303	7	.	.	PUNCT
eurjchem-2489	304	1	[	[	X
eurjchem-2489	304	2	24	24	NUM
eurjchem-2489	304	3	]	]	PUNCT
eurjchem-2489	304	4	.	.	PUNCT
eurjchem-2489	305	1	de	de	PROPN
eurjchem-2489	305	2	,	,	PUNCT
eurjchem-2489	305	3	a.	a.	NOUN
eurjchem-2489	305	4	;	;	PUNCT
eurjchem-2489	305	5	dey	dey	PROPN
eurjchem-2489	305	6	,	,	PUNCT
eurjchem-2489	305	7	d.	d.	PROPN
eurjchem-2489	305	8	;	;	PUNCT
eurjchem-2489	305	9	yadav	yadav	PROPN
eurjchem-2489	305	10	,	,	PUNCT
eurjchem-2489	305	11	h.	h.	PROPN
eurjchem-2489	305	12	r.	r.	PROPN
eurjchem-2489	305	13	;	;	PUNCT
eurjchem-2489	305	14	maji	maji	PROPN
eurjchem-2489	305	15	,	,	PUNCT
eurjchem-2489	305	16	m.	m.	NOUN
eurjchem-2489	305	17	;	;	PUNCT
eurjchem-2489	305	18	rane	rane	PROPN
eurjchem-2489	305	19	,	,	PUNCT
eurjchem-2489	305	20	v.	v.	PROPN
eurjchem-2489	305	21	;	;	PUNCT
eurjchem-2489	305	22	kadam	kadam	PROPN
eurjchem-2489	305	23	,	,	PUNCT
eurjchem-2489	305	24	r.	r.	PROPN
eurjchem-2489	305	25	m.	m.	PROPN
eurjchem-2489	305	26	;	;	PUNCT
eurjchem-2489	305	27	choudhury	choudhury	PROPN
eurjchem-2489	305	28	,	,	PUNCT
eurjchem-2489	305	29	a.	a.	PROPN
eurjchem-2489	305	30	r.	r.	PROPN
eurjchem-2489	305	31	;	;	PUNCT
eurjchem-2489	305	32	biswas	biswas	PROPN
eurjchem-2489	305	33	,	,	PUNCT
eurjchem-2489	305	34	b.	b.	PROPN
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eurjchem-2489	305	36	hetero	hetero	NOUN
eurjchem-2489	305	37	-	-	PUNCT
eurjchem-2489	305	38	geometric	geometric	ADJ
eurjchem-2489	305	39	discrete	discrete	ADJ
eurjchem-2489	305	40	copper(ii	copper(ii	NOUN
eurjchem-2489	305	41	)	)	PUNCT
eurjchem-2489	305	42	complexes	complex	NOUN
eurjchem-2489	305	43	:	:	PUNCT
eurjchem-2489	305	44	crystal	crystal	NOUN
eurjchem-2489	305	45	structure	structure	NOUN
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eurjchem-2489	305	47	bio	bio	NOUN
eurjchem-2489	305	48	-	-	ADJ
eurjchem-2489	305	49	mimicking	mimicking	NOUN
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eurjchem-2489	305	52	activity	activity	NOUN
eurjchem-2489	305	53	.	.	PUNCT
eurjchem-2489	306	1	j.	j.	PROPN
eurjchem-2489	306	2	chem	chem	PROPN
eurjchem-2489	306	3	.	.	PUNCT
eurjchem-2489	307	1	sci	sci	PROPN
eurjchem-2489	307	2	.	.	PUNCT
eurjchem-2489	308	1	(	(	PUNCT
eurjchem-2489	308	2	bangalore	bangalore	PROPN
eurjchem-2489	308	3	)	)	PUNCT
eurjchem-2489	308	4	2016	2016	NUM
eurjchem-2489	308	5	,	,	PUNCT
eurjchem-2489	308	6	128	128	NUM
eurjchem-2489	308	7	,	,	PUNCT
eurjchem-2489	308	8	1775–1782	1775–1782	NUM
eurjchem-2489	308	9	.	.	PUNCT
eurjchem-2489	309	1	[	[	X
eurjchem-2489	309	2	25	25	NUM
eurjchem-2489	309	3	]	]	PUNCT
eurjchem-2489	309	4	.	.	PUNCT
eurjchem-2489	310	1	liptak	liptak	PROPN
eurjchem-2489	310	2	,	,	PUNCT
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eurjchem-2489	310	4	d.	d.	PROPN
eurjchem-2489	310	5	;	;	PUNCT
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eurjchem-2489	310	7	,	,	PUNCT
eurjchem-2489	310	8	k.	k.	PROPN
eurjchem-2489	310	9	c.	c.	PROPN
eurjchem-2489	310	10	;	;	PUNCT
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eurjchem-2489	310	12	,	,	PUNCT
eurjchem-2489	310	13	p.	p.	NOUN
eurjchem-2489	310	14	g.	g.	PROPN
eurjchem-2489	310	15	;	;	PUNCT
eurjchem-2489	310	16	feldgus	feldgus	PROPN
eurjchem-2489	310	17	,	,	PUNCT
eurjchem-2489	310	18	s.	s.	PROPN
eurjchem-2489	310	19	;	;	PUNCT
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eurjchem-2489	310	21	,	,	PUNCT
eurjchem-2489	310	22	g.	g.	PROPN
eurjchem-2489	310	23	c.	c.	PROPN
eurjchem-2489	310	24	absolute	absolute	PROPN
eurjchem-2489	310	25	pka	pka	PROPN
eurjchem-2489	310	26	determinations	determination	NOUN
eurjchem-2489	310	27	for	for	ADP
eurjchem-2489	310	28	substituted	substitute	VERB
eurjchem-2489	310	29	phenols	phenol	NOUN
eurjchem-2489	310	30	.	.	PUNCT
eurjchem-2489	311	1	j.	j.	PROPN
eurjchem-2489	311	2	am	am	PROPN
eurjchem-2489	311	3	.	.	PUNCT
eurjchem-2489	312	1	chem	chem	NOUN
eurjchem-2489	312	2	.	.	PUNCT
eurjchem-2489	313	1	soc	soc	PROPN
eurjchem-2489	313	2	.	.	PUNCT
eurjchem-2489	314	1	2002	2002	NUM
eurjchem-2489	314	2	,	,	PUNCT
eurjchem-2489	314	3	124	124	NUM
eurjchem-2489	314	4	,	,	PUNCT
eurjchem-2489	314	5	6421–6427	6421–6427	NOUN
eurjchem-2489	314	6	.	.	PUNCT
eurjchem-2489	315	1	[	[	X
eurjchem-2489	315	2	26	26	NUM
eurjchem-2489	315	3	]	]	PUNCT
eurjchem-2489	315	4	.	.	PUNCT
eurjchem-2489	316	1	spackman	spackman	PROPN
eurjchem-2489	316	2	,	,	PUNCT
eurjchem-2489	316	3	p.	p.	PROPN
eurjchem-2489	316	4	r.	r.	PROPN
eurjchem-2489	316	5	;	;	PUNCT
eurjchem-2489	316	6	turner	turner	PROPN
eurjchem-2489	316	7	,	,	PUNCT
eurjchem-2489	316	8	m.	m.	PROPN
eurjchem-2489	316	9	j.	j.	PROPN
eurjchem-2489	316	10	;	;	PUNCT
eurjchem-2489	316	11	mckinnon	mckinnon	PROPN
eurjchem-2489	316	12	,	,	PUNCT
eurjchem-2489	316	13	j.	j.	PROPN
eurjchem-2489	316	14	j.	j.	PROPN
eurjchem-2489	316	15	;	;	PUNCT
eurjchem-2489	316	16	wolff	wolff	PROPN
eurjchem-2489	316	17	,	,	PUNCT
eurjchem-2489	316	18	s.	s.	PROPN
eurjchem-2489	316	19	k.	k.	PROPN
eurjchem-2489	316	20	;	;	PUNCT
eurjchem-2489	316	21	grimwood	grimwood	PROPN
eurjchem-2489	316	22	,	,	PUNCT
eurjchem-2489	316	23	d.	d.	PROPN
eurjchem-2489	316	24	j.	j.	PROPN
eurjchem-2489	316	25	;	;	PUNCT
eurjchem-2489	316	26	jayatilaka	jayatilaka	PROPN
eurjchem-2489	316	27	,	,	PUNCT
eurjchem-2489	316	28	d.	d.	PROPN
eurjchem-2489	316	29	;	;	PUNCT
eurjchem-2489	316	30	spackman	spackman	NOUN
eurjchem-2489	316	31	,	,	PUNCT
eurjchem-2489	316	32	m.	m.	NOUN
eurjchem-2489	316	33	a.	a.	NOUN
eurjchem-2489	316	34	crystalexplorer	crystalexplorer	PROPN
eurjchem-2489	316	35	:	:	PUNCT
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eurjchem-2489	316	49	crystals	crystal	NOUN
eurjchem-2489	316	50	.	.	PUNCT
eurjchem-2489	317	1	j.	j.	PROPN
eurjchem-2489	317	2	appl	appl	PROPN
eurjchem-2489	317	3	.	.	PROPN
eurjchem-2489	317	4	crystallogr	crystallogr	PROPN
eurjchem-2489	317	5	.	.	PUNCT
eurjchem-2489	318	1	2021	2021	NUM
eurjchem-2489	318	2	,	,	PUNCT
eurjchem-2489	318	3	54	54	NUM
eurjchem-2489	318	4	,	,	PUNCT
eurjchem-2489	318	5	1006–1011	1006–1011	NUM
eurjchem-2489	318	6	.	.	PUNCT
eurjchem-2489	319	1	[	[	X
eurjchem-2489	319	2	27	27	NUM
eurjchem-2489	319	3	]	]	PUNCT
eurjchem-2489	319	4	.	.	PUNCT
eurjchem-2489	320	1	de	de	PROPN
eurjchem-2489	320	2	,	,	PUNCT
eurjchem-2489	320	3	a.	a.	NOUN
eurjchem-2489	320	4	;	;	PUNCT
eurjchem-2489	320	5	garai	garai	PROPN
eurjchem-2489	320	6	,	,	PUNCT
eurjchem-2489	320	7	m.	m.	NOUN
eurjchem-2489	320	8	;	;	PUNCT
eurjchem-2489	320	9	yadav	yadav	PROPN
eurjchem-2489	320	10	,	,	PUNCT
eurjchem-2489	320	11	h.	h.	PROPN
eurjchem-2489	320	12	r.	r.	PROPN
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eurjchem-2489	320	15	,	,	PUNCT
eurjchem-2489	320	16	a.	a.	PROPN
eurjchem-2489	320	17	r.	r.	PROPN
eurjchem-2489	320	18	;	;	PUNCT
eurjchem-2489	320	19	biswas	biswas	PROPN
eurjchem-2489	320	20	,	,	PUNCT
eurjchem-2489	320	21	b.	b.	PROPN
eurjchem-2489	320	22	catalytic	catalytic	ADJ
eurjchem-2489	320	23	promiscuity	promiscuity	NOUN
eurjchem-2489	320	24	of	of	ADP
eurjchem-2489	320	25	an	an	DET
eurjchem-2489	320	26	iron(ii)–phenanthroline	iron(ii)–phenanthroline	ADJ
eurjchem-2489	320	27	complex	complex	ADJ
eurjchem-2489	320	28	.	.	PUNCT
eurjchem-2489	321	1	appl	appl	PROPN
eurjchem-2489	321	2	.	.	PUNCT
eurjchem-2489	322	1	organomet	organomet	PROPN
eurjchem-2489	322	2	.	.	PUNCT
eurjchem-2489	323	1	chem	chem	NOUN
eurjchem-2489	323	2	.	.	PUNCT
eurjchem-2489	324	1	2017	2017	NUM
eurjchem-2489	324	2	,	,	PUNCT
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eurjchem-2489	324	4	,	,	PUNCT
eurjchem-2489	324	5	e3551	e3551	INTJ
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eurjchem-2489	325	1	[	[	X
eurjchem-2489	325	2	28	28	NUM
eurjchem-2489	325	3	]	]	PUNCT
eurjchem-2489	325	4	.	.	PUNCT
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eurjchem-2489	326	3	d.	d.	PROPN
eurjchem-2489	326	4	l.	l.	PROPN
eurjchem-2489	326	5	;	;	PUNCT
eurjchem-2489	326	6	bai	bai	PROPN
eurjchem-2489	326	7	,	,	PUNCT
eurjchem-2489	326	8	k.	k.	PROPN
eurjchem-2489	326	9	s.	s.	PROPN
eurjchem-2489	326	10	n	n	CCONJ
eurjchem-2489	326	11	-	-	PUNCT
eurjchem-2489	326	12	salicylideneglycinato	salicylideneglycinato	NOUN
eurjchem-2489	326	13	complexes	complex	NOUN
eurjchem-2489	326	14	.	.	PUNCT
eurjchem-2489	327	1	comparison	comparison	NOUN
eurjchem-2489	327	2	with	with	ADP
eurjchem-2489	327	3	pyridoxal	pyridoxal	NOUN
eurjchem-2489	327	4	.	.	PUNCT
eurjchem-2489	328	1	anal	anal	PROPN
eurjchem-2489	328	2	.	.	PUNCT
eurjchem-2489	328	3	chem	chem	PROPN
eurjchem-2489	328	4	.	.	PUNCT
eurjchem-2489	329	1	1968	1968	NUM
eurjchem-2489	329	2	,	,	PUNCT
eurjchem-2489	329	3	40	40	NUM
eurjchem-2489	329	4	,	,	PUNCT
eurjchem-2489	329	5	575–581	575–581	NUM
eurjchem-2489	329	6	.	.	PUNCT
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eurjchem-2489	330	2	©	©	PROPN
eurjchem-2489	330	3	2023	2023	NUM
eurjchem-2489	330	4	by	by	ADP
eurjchem-2489	330	5	authors	author	NOUN
eurjchem-2489	330	6	.	.	PUNCT
eurjchem-2489	331	1	this	this	DET
eurjchem-2489	331	2	work	work	NOUN
eurjchem-2489	331	3	is	be	AUX
eurjchem-2489	331	4	published	publish	VERB
eurjchem-2489	331	5	and	and	CCONJ
eurjchem-2489	331	6	licensed	license	VERB
eurjchem-2489	331	7	by	by	ADP
eurjchem-2489	331	8	atlanta	atlanta	PROPN
eurjchem-2489	331	9	publishing	publishing	PROPN
eurjchem-2489	331	10	house	house	PROPN
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eurjchem-2489	331	12	,	,	PUNCT
eurjchem-2489	331	13	atlanta	atlanta	PROPN
eurjchem-2489	331	14	,	,	PUNCT
eurjchem-2489	331	15	ga	ga	PROPN
eurjchem-2489	331	16	,	,	PUNCT
eurjchem-2489	331	17	usa	usa	PROPN
eurjchem-2489	331	18	.	.	PUNCT
eurjchem-2489	332	1	the	the	DET
eurjchem-2489	332	2	full	full	ADJ
eurjchem-2489	332	3	terms	term	NOUN
eurjchem-2489	332	4	of	of	ADP
eurjchem-2489	332	5	this	this	DET
eurjchem-2489	332	6	license	license	NOUN
eurjchem-2489	332	7	are	be	AUX
eurjchem-2489	332	8	available	available	ADJ
eurjchem-2489	332	9	at	at	ADP
eurjchem-2489	332	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2489	332	11	and	and	CCONJ
eurjchem-2489	332	12	incorporate	incorporate	VERB
eurjchem-2489	332	13	the	the	DET
eurjchem-2489	332	14	creative	creative	ADJ
eurjchem-2489	332	15	commons	common	NOUN
eurjchem-2489	332	16	attribution	attribution	NOUN
eurjchem-2489	332	17	-	-	PUNCT
eurjchem-2489	332	18	non	non	ADJ
eurjchem-2489	332	19	commercial	commercial	NOUN
eurjchem-2489	332	20	(	(	PUNCT
eurjchem-2489	332	21	cc	cc	NOUN
eurjchem-2489	332	22	by	by	ADP
eurjchem-2489	332	23	nc	nc	PROPN
eurjchem-2489	332	24	)	)	PUNCT
eurjchem-2489	332	25	(	(	PUNCT
eurjchem-2489	332	26	international	international	ADJ
eurjchem-2489	332	27	,	,	PUNCT
eurjchem-2489	332	28	v4.0	v4.0	NOUN
eurjchem-2489	332	29	)	)	PUNCT
eurjchem-2489	332	30	license	license	NOUN
eurjchem-2489	332	31	(	(	PUNCT
eurjchem-2489	332	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2489	332	33	)	)	PUNCT
eurjchem-2489	332	34	.	.	PUNCT
eurjchem-2489	333	1	by	by	ADP
eurjchem-2489	333	2	accessing	access	VERB
eurjchem-2489	333	3	the	the	DET
eurjchem-2489	333	4	work	work	NOUN
eurjchem-2489	333	5	,	,	PUNCT
eurjchem-2489	333	6	you	you	PRON
eurjchem-2489	333	7	hereby	hereby	ADV
eurjchem-2489	333	8	accept	accept	VERB
eurjchem-2489	333	9	the	the	DET
eurjchem-2489	333	10	terms	term	NOUN
eurjchem-2489	333	11	.	.	PUNCT
eurjchem-2489	334	1	this	this	PRON
eurjchem-2489	334	2	is	be	AUX
eurjchem-2489	334	3	an	an	DET
eurjchem-2489	334	4	open	open	ADJ
eurjchem-2489	334	5	access	access	NOUN
eurjchem-2489	334	6	article	article	NOUN
eurjchem-2489	334	7	distributed	distribute	VERB
eurjchem-2489	334	8	under	under	ADP
eurjchem-2489	334	9	the	the	DET
eurjchem-2489	334	10	terms	term	NOUN
eurjchem-2489	334	11	and	and	CCONJ
eurjchem-2489	334	12	conditions	condition	NOUN
eurjchem-2489	334	13	of	of	ADP
eurjchem-2489	334	14	the	the	DET
eurjchem-2489	334	15	cc	cc	PROPN
eurjchem-2489	334	16	by	by	ADP
eurjchem-2489	334	17	nc	nc	PROPN
eurjchem-2489	334	18	license	license	PROPN
eurjchem-2489	334	19	,	,	PUNCT
eurjchem-2489	334	20	which	which	PRON
eurjchem-2489	334	21	permits	permit	VERB
eurjchem-2489	334	22	unrestricted	unrestricted	ADJ
eurjchem-2489	334	23	non	non	ADJ
eurjchem-2489	334	24	-	-	ADJ
eurjchem-2489	334	25	commercial	commercial	ADJ
eurjchem-2489	334	26	use	use	NOUN
eurjchem-2489	334	27	,	,	PUNCT
eurjchem-2489	334	28	distribution	distribution	NOUN
eurjchem-2489	334	29	,	,	PUNCT
eurjchem-2489	334	30	and	and	CCONJ
eurjchem-2489	334	31	reproduction	reproduction	NOUN
eurjchem-2489	334	32	in	in	ADP
eurjchem-2489	334	33	any	any	DET
eurjchem-2489	334	34	medium	medium	NOUN
eurjchem-2489	334	35	,	,	PUNCT
eurjchem-2489	334	36	provided	provide	VERB
eurjchem-2489	334	37	the	the	DET
eurjchem-2489	334	38	original	original	ADJ
eurjchem-2489	334	39	work	work	NOUN
eurjchem-2489	334	40	is	be	AUX
eurjchem-2489	334	41	properly	properly	ADV
eurjchem-2489	334	42	cited	cite	VERB
eurjchem-2489	334	43	without	without	ADP
eurjchem-2489	334	44	any	any	DET
eurjchem-2489	334	45	further	further	ADJ
eurjchem-2489	334	46	permission	permission	NOUN
eurjchem-2489	334	47	from	from	ADP
eurjchem-2489	334	48	atlanta	atlanta	PROPN
eurjchem-2489	334	49	publishing	publishing	PROPN
eurjchem-2489	334	50	house	house	PROPN
eurjchem-2489	334	51	llc	llc	PROPN
eurjchem-2489	334	52	(	(	PUNCT
eurjchem-2489	334	53	european	european	PROPN
eurjchem-2489	334	54	journal	journal	PROPN
eurjchem-2489	334	55	of	of	ADP
eurjchem-2489	334	56	chemistry	chemistry	NOUN
eurjchem-2489	334	57	)	)	PUNCT
eurjchem-2489	334	58	.	.	PUNCT
eurjchem-2489	335	1	no	no	DET
eurjchem-2489	335	2	use	use	NOUN
eurjchem-2489	335	3	,	,	PUNCT
eurjchem-2489	335	4	distribution	distribution	NOUN
eurjchem-2489	335	5	,	,	PUNCT
eurjchem-2489	335	6	or	or	CCONJ
eurjchem-2489	335	7	reproduction	reproduction	NOUN
eurjchem-2489	335	8	is	be	AUX
eurjchem-2489	335	9	permitted	permit	VERB
eurjchem-2489	335	10	which	which	PRON
eurjchem-2489	335	11	does	do	AUX
eurjchem-2489	335	12	not	not	PART
eurjchem-2489	335	13	comply	comply	VERB
eurjchem-2489	335	14	with	with	ADP
eurjchem-2489	335	15	these	these	DET
eurjchem-2489	335	16	terms	term	NOUN
eurjchem-2489	335	17	.	.	PUNCT
eurjchem-2489	336	1	permissions	permission	NOUN
eurjchem-2489	336	2	for	for	ADP
eurjchem-2489	336	3	commercial	commercial	ADJ
eurjchem-2489	336	4	use	use	NOUN
eurjchem-2489	336	5	of	of	ADP
eurjchem-2489	336	6	this	this	DET
eurjchem-2489	336	7	work	work	NOUN
eurjchem-2489	336	8	beyond	beyond	ADP
eurjchem-2489	336	9	the	the	DET
eurjchem-2489	336	10	scope	scope	NOUN
eurjchem-2489	336	11	of	of	ADP
eurjchem-2489	336	12	the	the	DET
eurjchem-2489	336	13	license	license	NOUN
eurjchem-2489	336	14	(	(	PUNCT
eurjchem-2489	336	15	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2489	336	16	)	)	PUNCT
eurjchem-2489	336	17	are	be	AUX
eurjchem-2489	336	18	administered	administer	VERB
eurjchem-2489	336	19	by	by	ADP
eurjchem-2489	336	20	atlanta	atlanta	PROPN
eurjchem-2489	336	21	publishing	publishing	PROPN
eurjchem-2489	336	22	house	house	PROPN
eurjchem-2489	336	23	llc	llc	PROPN
eurjchem-2489	336	24	(	(	PUNCT
eurjchem-2489	336	25	european	european	PROPN
eurjchem-2489	336	26	journal	journal	PROPN
eurjchem-2489	336	27	of	of	ADP
eurjchem-2489	336	28	chemistry	chemistry	NOUN
eurjchem-2489	336	29	)	)	PUNCT
eurjchem-2489	336	30	.	.	PUNCT
eurjchem-2489	337	1	mailto:smukherjee@suryasencollege.org.in	mailto:smukherjee@suryasencollege.org.in	VERB
eurjchem-2489	337	2	https://orcid.org/0000-0002-1541-2839	https://orcid.org/0000-0002-1541-2839	ADV
eurjchem-2489	337	3	mailto:iamgayetri007@gmail.com	mailto:iamgayetri007@gmail.com	PROPN
eurjchem-2489	337	4	https://orcid.org/0009-0008-9729-9331	https://orcid.org/0009-0008-9729-9331	PROPN
eurjchem-2489	337	5	mailto:abhranilde@gmail.com	mailto:abhranilde@gmail.com	PROPN
eurjchem-2489	337	6	https://orcid.org/0000-0003-2266-9023	https://orcid.org/0000-0003-2266-9023	PROPN
eurjchem-2489	337	7	mailto:bhaskarbiswas@nbu.ac.in	mailto:bhaskarbiswas@nbu.ac.in	PROPN
eurjchem-2489	337	8	mailto:mr.bbiswas@rediffmail.com	mailto:mr.bbiswas@rediffmail.com	PROPN
eurjchem-2489	337	9	https://orcid.org/0000-0002-5447-9729	https://orcid.org/0000-0002-5447-9729	PROPN
eurjchem-2489	337	10	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	PROPN
eurjchem-2489	337	11	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2489	337	12	http://www.eurjchem.com/index.php/eurjchem/pages/view/terms	http://www.eurjchem.com/index.php/eurjchem/pages/view/term	NOUN
eurjchem-2489	337	13	1	1	NUM
eurjchem-2489	337	14	.	.	PUNCT
eurjchem-2489	338	1	introduction	introduction	NOUN
eurjchem-2489	338	2	2	2	NUM
eurjchem-2489	338	3	.	.	PUNCT
eurjchem-2489	338	4	experimental	experimental	ADJ
eurjchem-2489	338	5	2.1	2.1	NUM
eurjchem-2489	338	6	.	.	PUNCT
eurjchem-2489	339	1	preparation	preparation	NOUN
eurjchem-2489	339	2	of	of	ADP
eurjchem-2489	339	3	the	the	DET
eurjchem-2489	339	4	complex	complex	ADJ
eurjchem-2489	339	5	2.1.1	2.1.1	NUM
eurjchem-2489	339	6	.	.	PUNCT
eurjchem-2489	340	1	chemicals	chemical	NOUN
eurjchem-2489	340	2	,	,	PUNCT
eurjchem-2489	340	3	solvents	solvent	NOUN
eurjchem-2489	340	4	,	,	PUNCT
eurjchem-2489	340	5	and	and	CCONJ
eurjchem-2489	340	6	starting	start	VERB
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eurjchem-2489	340	9	.	.	PUNCT
eurjchem-2489	340	10	general	general	ADJ
eurjchem-2489	340	11	procedure	procedure	NOUN
eurjchem-2489	340	12	for	for	ADP
eurjchem-2489	340	13	the	the	DET
eurjchem-2489	340	14	synthesis	synthesis	NOUN
eurjchem-2489	340	15	of	of	ADP
eurjchem-2489	340	16	copper(ii	copper(ii	NOUN
eurjchem-2489	340	17	)	)	PUNCT
eurjchem-2489	340	18	complex	complex	ADJ
eurjchem-2489	340	19	2.2	2.2	NUM
eurjchem-2489	340	20	.	.	PUNCT
eurjchem-2489	341	1	instrumentation	instrumentation	NOUN
eurjchem-2489	341	2	2.3	2.3	NUM
eurjchem-2489	341	3	.	.	PUNCT
eurjchem-2489	342	1	x	x	X
eurjchem-2489	342	2	-	-	PUNCT
eurjchem-2489	342	3	ray	ray	NOUN
eurjchem-2489	342	4	diffraction	diffraction	NOUN
eurjchem-2489	342	5	study	study	NOUN
eurjchem-2489	342	6	2.4	2.4	NUM
eurjchem-2489	342	7	.	.	PUNCT
eurjchem-2489	343	1	catecholase	catecholase	NOUN
eurjchem-2489	343	2	activity	activity	NOUN
eurjchem-2489	343	3	of	of	ADP
eurjchem-2489	343	4	the	the	DET
eurjchem-2489	343	5	copper(ii	copper(ii	NOUN
eurjchem-2489	343	6	)	)	PUNCT
eurjchem-2489	343	7	complex	complex	ADJ
eurjchem-2489	343	8	3	3	NUM
eurjchem-2489	343	9	.	.	NOUN
eurjchem-2489	343	10	results	result	NOUN
eurjchem-2489	343	11	and	and	CCONJ
eurjchem-2489	343	12	discussion	discussion	NOUN
eurjchem-2489	343	13	3.1	3.1	NUM
eurjchem-2489	343	14	.	.	PUNCT
eurjchem-2489	344	1	design	design	NOUN
eurjchem-2489	344	2	,	,	PUNCT
eurjchem-2489	344	3	synthesis	synthesis	NOUN
eurjchem-2489	344	4	and	and	CCONJ
eurjchem-2489	344	5	formulation	formulation	NOUN
eurjchem-2489	344	6	of	of	ADP
eurjchem-2489	344	7	the	the	DET
eurjchem-2489	344	8	copper(ii	copper(ii	NOUN
eurjchem-2489	344	9	)	)	PUNCT
eurjchem-2489	344	10	complex	complex	NOUN
eurjchem-2489	344	11	(	(	PUNCT
eurjchem-2489	344	12	1	1	NUM
eurjchem-2489	344	13	)	)	PUNCT
eurjchem-2489	344	14	3.2	3.2	NUM
eurjchem-2489	344	15	.	.	PUNCT
eurjchem-2489	344	16	description	description	NOUN
eurjchem-2489	344	17	of	of	ADP
eurjchem-2489	344	18	crystal	crystal	NOUN
eurjchem-2489	344	19	structure	structure	NOUN
eurjchem-2489	344	20	and	and	CCONJ
eurjchem-2489	344	21	supramolecular	supramolecular	ADJ
eurjchem-2489	344	22	interactions	interaction	NOUN
eurjchem-2489	344	23	3.3	3.3	NUM
eurjchem-2489	344	24	.	.	PUNCT
eurjchem-2489	345	1	solution	solution	NOUN
eurjchem-2489	345	2	property	property	NOUN
eurjchem-2489	345	3	of	of	ADP
eurjchem-2489	345	4	the	the	DET
eurjchem-2489	345	5	copper(ii	copper(ii	NOUN
eurjchem-2489	345	6	)	)	PUNCT
eurjchem-2489	345	7	complex	complex	ADJ
eurjchem-2489	345	8	3.4	3.4	NUM
eurjchem-2489	345	9	.	.	PUNCT
eurjchem-2489	346	1	catecholase	catecholase	NOUN
eurjchem-2489	346	2	activity	activity	NOUN
eurjchem-2489	346	3	of	of	ADP
eurjchem-2489	346	4	the	the	DET
eurjchem-2489	346	5	copper(ii	copper(ii	NOUN
eurjchem-2489	346	6	)	)	PUNCT
eurjchem-2489	346	7	complex	complex	ADJ
eurjchem-2489	346	8	4	4	NUM
eurjchem-2489	346	9	.	.	PUNCT
eurjchem-2489	347	1	conclusions	conclusion	NOUN
eurjchem-2489	347	2	acknowledgements	acknowledgement	NOUN
eurjchem-2489	347	3	supporting	support	VERB
eurjchem-2489	347	4	information	information	NOUN
eurjchem-2489	347	5	disclosure	disclosure	NOUN
eurjchem-2489	347	6	statement	statement	NOUN
eurjchem-2489	347	7	credit	credit	NOUN
eurjchem-2489	347	8	authorship	authorship	NOUN
eurjchem-2489	347	9	contribution	contribution	NOUN
eurjchem-2489	347	10	statement	statement	NOUN
eurjchem-2489	347	11	orcid	orcid	NOUN
eurjchem-2489	347	12	and	and	CCONJ
eurjchem-2489	347	13	email	email	NOUN
eurjchem-2489	347	14	references	reference	NOUN
eurjchem-2489	347	15	printfield10	printfield10	PROPN
eurjchem-2489	347	16	:	:	PUNCT
eurjchem-2489	347	17	printfield11	printfield11	NOUN
eurjchem-2489	347	18	:	:	PUNCT
eurjchem-2489	347	19	printfield12	printfield12	PROPN
eurjchem-2489	347	20	:	:	PUNCT
eurjchem-2489	347	21	printfield13	printfield13	VERB
eurjchem-2489	347	22	:	:	PUNCT
eurjchem-2489	347	23	printfield14	printfield14	NOUN
eurjchem-2489	347	24	:	:	PUNCT
eurjchem-2489	347	25	printfield15	printfield15	NOUN
eurjchem-2489	347	26	:	:	PUNCT
eurjchem-2489	347	27	printfield16	printfield16	ADJ
eurjchem-2489	347	28	:	:	PUNCT
eurjchem-2489	347	29	printfield17	printfield17	NOUN
eurjchem-2489	347	30	:	:	PUNCT
eurjchem-2489	347	31	printfield20	printfield20	PROPN
eurjchem-2489	347	32	:	:	PUNCT
eurjchem-2489	348	1	printfield21	printfield21	ADJ
eurjchem-2489	348	2	:	:	PUNCT
eurjchem-2489	348	3	printfield22	printfield22	NOUN
eurjchem-2489	348	4	:	:	PUNCT
eurjchem-2489	348	5	printfield23	printfield23	NOUN
eurjchem-2489	348	6	:	:	PUNCT
eurjchem-2489	348	7	printfield24	printfield24	NOUN
eurjchem-2489	348	8	:	:	PUNCT
eurjchem-2489	348	9	printfield25	printfield25	NOUN
eurjchem-2489	348	10	:	:	PUNCT
eurjchem-2489	348	11	printfield26	printfield26	ADJ
eurjchem-2489	348	12	:	:	PUNCT
eurjchem-2489	348	13	printfield27	printfield27	NOUN
eurjchem-2489	348	14	:	:	PUNCT