id	sid	tid	token	lemma	pos
eurjchem-2518	1	1	entropy	entropy	NOUN
eurjchem-2518	1	2	of	of	ADP
eurjchem-2518	1	3	the	the	DET
eurjchem-2518	1	4	surface	surface	NOUN
eurjchem-2518	1	5	catalytic	catalytic	ADJ
eurjchem-2518	1	6	reaction	reaction	NOUN
eurjchem-2518	1	7	:	:	PUNCT
eurjchem-2518	1	8	expansion	expansion	NOUN
eurjchem-2518	1	9	of	of	ADP
eurjchem-2518	1	10	the	the	DET
eurjchem-2518	1	11	advanced	advanced	ADJ
eurjchem-2518	1	12	h2s	h2s	NOUN
eurjchem-2518	1	13	paradigm	paradigm	NOUN
eurjchem-2518	1	14	to	to	PART
eurjchem-2518	1	15	novel	novel	VERB
eurjchem-2518	1	16	catalytic	catalytic	ADJ
eurjchem-2518	1	17	systems	system	NOUN
eurjchem-2518	1	18	european	european	PROPN
eurjchem-2518	1	19	journal	journal	PROPN
eurjchem-2518	1	20	of	of	ADP
eurjchem-2518	1	21	chemistry	chemistry	NOUN
eurjchem-2518	1	22	15	15	NUM
eurjchem-2518	1	23	(	(	PUNCT
eurjchem-2518	1	24	2	2	NUM
eurjchem-2518	1	25	)	)	PUNCT
eurjchem-2518	1	26	(	(	PUNCT
eurjchem-2518	1	27	2024	2024	NUM
eurjchem-2518	1	28	)	)	PUNCT
eurjchem-2518	1	29	186	186	NUM
eurjchem-2518	1	30	-	-	SYM
eurjchem-2518	1	31	193	193	NUM
eurjchem-2518	1	32	european	european	ADJ
eurjchem-2518	1	33	journal	journal	NOUN
eurjchem-2518	1	34	of	of	ADP
eurjchem-2518	1	35	chemistry	chemistry	NOUN
eurjchem-2518	1	36	issn	issn	VERB
eurjchem-2518	1	37	2153	2153	NUM
eurjchem-2518	1	38	-	-	SYM
eurjchem-2518	1	39	2249	2249	NUM
eurjchem-2518	1	40	(	(	PUNCT
eurjchem-2518	1	41	print	print	NOUN
eurjchem-2518	1	42	)	)	PUNCT
eurjchem-2518	1	43	/	/	PUNCT
eurjchem-2518	1	44	issn	issn	PROPN
eurjchem-2518	1	45	2153	2153	NUM
eurjchem-2518	1	46	-	-	SYM
eurjchem-2518	1	47	2257	2257	NUM
eurjchem-2518	1	48	(	(	PUNCT
eurjchem-2518	1	49	online	online	ADJ
eurjchem-2518	1	50	)	)	PUNCT
eurjchem-2518	1	51	–	–	PUNCT
eurjchem-2518	2	1	copyright	copyright	NOUN
eurjchem-2518	2	2	©	©	PROPN
eurjchem-2518	2	3	2024	2024	NUM
eurjchem-2518	2	4	the	the	DET
eurjchem-2518	2	5	authors	author	NOUN
eurjchem-2518	2	6	–	–	PUNCT
eurjchem-2518	2	7	atlanta	atlanta	PROPN
eurjchem-2518	2	8	publishing	publishing	PROPN
eurjchem-2518	2	9	house	house	PROPN
eurjchem-2518	2	10	llc	llc	PROPN
eurjchem-2518	2	11	–	–	PUNCT
eurjchem-2518	2	12	printed	print	VERB
eurjchem-2518	2	13	in	in	ADP
eurjchem-2518	2	14	the	the	DET
eurjchem-2518	2	15	usa	usa	PROPN
eurjchem-2518	2	16	.	.	PUNCT
eurjchem-2518	3	1	this	this	DET
eurjchem-2518	3	2	work	work	NOUN
eurjchem-2518	3	3	is	be	AUX
eurjchem-2518	3	4	published	publish	VERB
eurjchem-2518	3	5	and	and	CCONJ
eurjchem-2518	3	6	licensed	license	VERB
eurjchem-2518	3	7	by	by	ADP
eurjchem-2518	3	8	atlanta	atlanta	PROPN
eurjchem-2518	3	9	publishing	publishing	PROPN
eurjchem-2518	3	10	house	house	PROPN
eurjchem-2518	3	11	llc	llc	PROPN
eurjchem-2518	3	12	–	–	PUNCT
eurjchem-2518	3	13	cc	cc	PROPN
eurjchem-2518	3	14	by	by	ADP
eurjchem-2518	3	15	nc	nc	PROPN
eurjchem-2518	3	16	–	–	PUNCT
eurjchem-2518	3	17	some	some	DET
eurjchem-2518	3	18	rights	right	NOUN
eurjchem-2518	3	19	reserved	reserve	VERB
eurjchem-2518	3	20	.	.	PUNCT
eurjchem-2518	4	1	https://dx.doi.org/10.5155/eurjchem.15.2.186-193.2518	https://dx.doi.org/10.5155/eurjchem.15.2.186-193.2518	ADJ
eurjchem-2518	4	2	european	european	PROPN
eurjchem-2518	4	3	journal	journal	PROPN
eurjchem-2518	4	4	of	of	ADP
eurjchem-2518	4	5	chemistry	chemistry	NOUN
eurjchem-2518	4	6	view	view	NOUN
eurjchem-2518	4	7	journal	journal	PROPN
eurjchem-2518	4	8	online	online	PROPN
eurjchem-2518	4	9	view	view	NOUN
eurjchem-2518	4	10	article	article	NOUN
eurjchem-2518	4	11	online	online	PROPN
eurjchem-2518	4	12	entropy	entropy	PROPN
eurjchem-2518	4	13	of	of	ADP
eurjchem-2518	4	14	the	the	DET
eurjchem-2518	4	15	surface	surface	NOUN
eurjchem-2518	4	16	catalytic	catalytic	ADJ
eurjchem-2518	4	17	reaction	reaction	NOUN
eurjchem-2518	4	18	:	:	PUNCT
eurjchem-2518	4	19	expansion	expansion	NOUN
eurjchem-2518	4	20	of	of	ADP
eurjchem-2518	4	21	the	the	DET
eurjchem-2518	4	22	advanced	advanced	ADJ
eurjchem-2518	4	23	h2s	h2s	NOUN
eurjchem-2518	4	24	paradigm	paradigm	NOUN
eurjchem-2518	4	25	to	to	PART
eurjchem-2518	4	26	novel	novel	VERB
eurjchem-2518	4	27	catalytic	catalytic	ADJ
eurjchem-2518	4	28	systems	system	NOUN
eurjchem-2518	4	29	anatolii	anatolii	NOUN
eurjchem-2518	4	30	startsev	startsev	NOUN
eurjchem-2518	4	31	*	*	PUNCT
eurjchem-2518	4	32	boreskov	boreskov	PROPN
eurjchem-2518	4	33	institute	institute	PROPN
eurjchem-2518	4	34	of	of	ADP
eurjchem-2518	4	35	catalysis	catalysis	NOUN
eurjchem-2518	4	36	,	,	PUNCT
eurjchem-2518	4	37	siberian	siberian	ADJ
eurjchem-2518	4	38	branch	branch	NOUN
eurjchem-2518	4	39	of	of	ADP
eurjchem-2518	4	40	the	the	DET
eurjchem-2518	4	41	russian	russian	PROPN
eurjchem-2518	4	42	academy	academy	PROPN
eurjchem-2518	4	43	of	of	ADP
eurjchem-2518	4	44	sciences	sciences	PROPN
eurjchem-2518	4	45	,	,	PUNCT
eurjchem-2518	4	46	630090	630090	NUM
eurjchem-2518	4	47	novosibirsk	novosibirsk	PROPN
eurjchem-2518	4	48	,	,	PUNCT
eurjchem-2518	4	49	russia	russia	PROPN
eurjchem-2518	4	50	*	*	PUNCT
eurjchem-2518	4	51	corresponding	correspond	VERB
eurjchem-2518	4	52	author	author	NOUN
eurjchem-2518	4	53	at	at	ADP
eurjchem-2518	4	54	:	:	PUNCT
eurjchem-2518	4	55	boreskov	boreskov	PROPN
eurjchem-2518	4	56	institute	institute	PROPN
eurjchem-2518	4	57	of	of	ADP
eurjchem-2518	4	58	catalysis	catalysis	NOUN
eurjchem-2518	4	59	,	,	PUNCT
eurjchem-2518	4	60	siberian	siberian	ADJ
eurjchem-2518	4	61	branch	branch	NOUN
eurjchem-2518	4	62	of	of	ADP
eurjchem-2518	4	63	the	the	DET
eurjchem-2518	4	64	russian	russian	PROPN
eurjchem-2518	4	65	academy	academy	PROPN
eurjchem-2518	4	66	of	of	ADP
eurjchem-2518	4	67	sciences	sciences	PROPN
eurjchem-2518	4	68	,	,	PUNCT
eurjchem-2518	4	69	630090	630090	NUM
eurjchem-2518	4	70	novosibirsk	novosibirsk	PROPN
eurjchem-2518	4	71	,	,	PUNCT
eurjchem-2518	4	72	russia	russia	PROPN
eurjchem-2518	4	73	.	.	PUNCT
eurjchem-2518	5	1	e	e	X
eurjchem-2518	5	2	-	-	NOUN
eurjchem-2518	5	3	mail	mail	NOUN
eurjchem-2518	5	4	:	:	PUNCT
eurjchem-2518	5	5	anatolii.startsev@gmail.com	anatolii.startsev@gmail.com	X
eurjchem-2518	5	6	(	(	PUNCT
eurjchem-2518	5	7	a.	a.	NOUN
eurjchem-2518	5	8	startsev	startsev	PROPN
eurjchem-2518	5	9	)	)	PUNCT
eurjchem-2518	5	10	.	.	PUNCT
eurjchem-2518	6	1	10.5155	10.5155	NUM
eurjchem-2518	6	2	/	/	SYM
eurjchem-2518	6	3	eurjchem.15.2.186	eurjchem.15.2.186	VERB
eurjchem-2518	6	4	-	-	SYM
eurjchem-2518	6	5	193.2518	193.2518	NUM
eurjchem-2518	6	6	received	receive	VERB
eurjchem-2518	6	7	:	:	PUNCT
eurjchem-2518	6	8	8	8	NUM
eurjchem-2518	6	9	february	february	NOUN
eurjchem-2518	6	10	2024	2024	NUM
eurjchem-2518	6	11	received	receive	VERB
eurjchem-2518	6	12	in	in	ADP
eurjchem-2518	6	13	revised	revise	VERB
eurjchem-2518	6	14	form	form	NOUN
eurjchem-2518	6	15	:	:	PUNCT
eurjchem-2518	6	16	12	12	NUM
eurjchem-2518	6	17	march	march	NOUN
eurjchem-2518	6	18	2024	2024	NUM
eurjchem-2518	6	19	accepted	accept	VERB
eurjchem-2518	6	20	:	:	PUNCT
eurjchem-2518	6	21	27	27	NUM
eurjchem-2518	6	22	march	march	NOUN
eurjchem-2518	6	23	2024	2024	NUM
eurjchem-2518	6	24	published	publish	VERB
eurjchem-2518	6	25	online	online	ADV
eurjchem-2518	6	26	:	:	PUNCT
eurjchem-2518	6	27	30	30	NUM
eurjchem-2518	6	28	june	june	PROPN
eurjchem-2518	6	29	2024	2024	NUM
eurjchem-2518	6	30	printed	print	VERB
eurjchem-2518	6	31	:	:	PUNCT
eurjchem-2518	6	32	30	30	NUM
eurjchem-2518	6	33	june	june	PROPN
eurjchem-2518	6	34	2024	2024	NUM
eurjchem-2518	6	35	the	the	DET
eurjchem-2518	6	36	main	main	ADJ
eurjchem-2518	6	37	provisions	provision	NOUN
eurjchem-2518	6	38	of	of	ADP
eurjchem-2518	6	39	the	the	DET
eurjchem-2518	6	40	recently	recently	ADV
eurjchem-2518	6	41	developed	develop	VERB
eurjchem-2518	6	42	concept	concept	NOUN
eurjchem-2518	6	43	of	of	ADP
eurjchem-2518	6	44	the	the	DET
eurjchem-2518	6	45	crucial	crucial	ADJ
eurjchem-2518	6	46	role	role	NOUN
eurjchem-2518	6	47	of	of	ADP
eurjchem-2518	6	48	catalysts	catalyst	NOUN
eurjchem-2518	6	49	in	in	ADP
eurjchem-2518	6	50	the	the	DET
eurjchem-2518	6	51	process	process	NOUN
eurjchem-2518	6	52	of	of	ADP
eurjchem-2518	6	53	low	low	ADJ
eurjchem-2518	6	54	-	-	PUNCT
eurjchem-2518	6	55	temperature	temperature	NOUN
eurjchem-2518	6	56	decomposition	decomposition	NOUN
eurjchem-2518	6	57	of	of	ADP
eurjchem-2518	6	58	h2s	h2s	NOUN
eurjchem-2518	6	59	to	to	PART
eurjchem-2518	6	60	produce	produce	VERB
eurjchem-2518	6	61	hydrogen	hydrogen	NOUN
eurjchem-2518	6	62	and	and	CCONJ
eurjchem-2518	6	63	elemental	elemental	ADJ
eurjchem-2518	6	64	sulfur	sulfur	NOUN
eurjchem-2518	6	65	are	be	AUX
eurjchem-2518	6	66	considered	consider	VERB
eurjchem-2518	6	67	.	.	PUNCT
eurjchem-2518	7	1	the	the	DET
eurjchem-2518	7	2	concept	concept	NOUN
eurjchem-2518	7	3	is	be	AUX
eurjchem-2518	7	4	based	base	VERB
eurjchem-2518	7	5	on	on	ADP
eurjchem-2518	7	6	the	the	DET
eurjchem-2518	7	7	non	non	ADJ
eurjchem-2518	7	8	-	-	ADJ
eurjchem-2518	7	9	equilibrium	equilibrium	ADJ
eurjchem-2518	7	10	thermodynamics	thermodynamic	NOUN
eurjchem-2518	7	11	of	of	ADP
eurjchem-2518	7	12	an	an	DET
eurjchem-2518	7	13	irreversible	irreversible	ADJ
eurjchem-2518	7	14	process	process	NOUN
eurjchem-2518	7	15	in	in	ADP
eurjchem-2518	7	16	an	an	DET
eurjchem-2518	7	17	open	open	ADJ
eurjchem-2518	7	18	system	system	NOUN
eurjchem-2518	7	19	.	.	PUNCT
eurjchem-2518	8	1	it	it	PRON
eurjchem-2518	8	2	is	be	AUX
eurjchem-2518	8	3	shown	show	VERB
eurjchem-2518	8	4	that	that	SCONJ
eurjchem-2518	8	5	irreversible	irreversible	ADJ
eurjchem-2518	8	6	chemical	chemical	NOUN
eurjchem-2518	8	7	reactions	reaction	NOUN
eurjchem-2518	8	8	prohibited	prohibit	VERB
eurjchem-2518	8	9	in	in	ADP
eurjchem-2518	8	10	the	the	DET
eurjchem-2518	8	11	gas	gas	NOUN
eurjchem-2518	8	12	phase	phase	NOUN
eurjchem-2518	8	13	take	take	VERB
eurjchem-2518	8	14	place	place	NOUN
eurjchem-2518	8	15	on	on	ADP
eurjchem-2518	8	16	the	the	DET
eurjchem-2518	8	17	catalyst	catalyst	NOUN
eurjchem-2518	8	18	surface	surface	NOUN
eurjchem-2518	8	19	under	under	ADP
eurjchem-2518	8	20	conditions	condition	NOUN
eurjchem-2518	8	21	of	of	ADP
eurjchem-2518	8	22	nonequilibrium	nonequilibrium	NOUN
eurjchem-2518	8	23	thermodynamics	thermodynamic	NOUN
eurjchem-2518	8	24	at	at	ADP
eurjchem-2518	8	25	ambient	ambient	ADJ
eurjchem-2518	8	26	temperature	temperature	NOUN
eurjchem-2518	8	27	and	and	CCONJ
eurjchem-2518	8	28	pressure	pressure	NOUN
eurjchem-2518	8	29	.	.	PUNCT
eurjchem-2518	9	1	this	this	PRON
eurjchem-2518	9	2	became	become	VERB
eurjchem-2518	9	3	possible	possible	ADJ
eurjchem-2518	9	4	due	due	ADP
eurjchem-2518	9	5	to	to	ADP
eurjchem-2518	9	6	the	the	DET
eurjchem-2518	9	7	gibbs	gibbs	PROPN
eurjchem-2518	9	8	free	free	ADJ
eurjchem-2518	9	9	energy	energy	NOUN
eurjchem-2518	9	10	accumulated	accumulate	VERB
eurjchem-2518	9	11	on	on	ADP
eurjchem-2518	9	12	the	the	DET
eurjchem-2518	9	13	catalyst	catalyst	NOUN
eurjchem-2518	9	14	surface	surface	NOUN
eurjchem-2518	9	15	as	as	ADP
eurjchem-2518	9	16	a	a	DET
eurjchem-2518	9	17	result	result	NOUN
eurjchem-2518	9	18	of	of	ADP
eurjchem-2518	9	19	exothermic	exothermic	ADJ
eurjchem-2518	9	20	processes	process	NOUN
eurjchem-2518	9	21	of	of	ADP
eurjchem-2518	9	22	chemisorption	chemisorption	NOUN
eurjchem-2518	9	23	and	and	CCONJ
eurjchem-2518	9	24	dissociation	dissociation	NOUN
eurjchem-2518	9	25	of	of	ADP
eurjchem-2518	9	26	h2s	h2s	NOUN
eurjchem-2518	9	27	molecules	molecule	NOUN
eurjchem-2518	9	28	and	and	CCONJ
eurjchem-2518	9	29	the	the	DET
eurjchem-2518	9	30	dissipation	dissipation	NOUN
eurjchem-2518	9	31	of	of	ADP
eurjchem-2518	9	32	entropy	entropy	NOUN
eurjchem-2518	9	33	in	in	ADP
eurjchem-2518	9	34	the	the	DET
eurjchem-2518	9	35	form	form	NOUN
eurjchem-2518	9	36	of	of	ADP
eurjchem-2518	9	37	bound	bind	VERB
eurjchem-2518	9	38	energy	energy	NOUN
eurjchem-2518	9	39	into	into	ADP
eurjchem-2518	9	40	the	the	DET
eurjchem-2518	9	41	environment	environment	NOUN
eurjchem-2518	9	42	.	.	PUNCT
eurjchem-2518	10	1	the	the	DET
eurjchem-2518	10	2	innovative	innovative	ADJ
eurjchem-2518	10	3	proposed	propose	VERB
eurjchem-2518	10	4	method	method	NOUN
eurjchem-2518	10	5	of	of	ADP
eurjchem-2518	10	6	h2s	h2s	NOUN
eurjchem-2518	10	7	utilization	utilization	NOUN
eurjchem-2518	10	8	will	will	AUX
eurjchem-2518	10	9	replace	replace	VERB
eurjchem-2518	10	10	the	the	DET
eurjchem-2518	10	11	long	long	ADV
eurjchem-2518	10	12	-	-	PUNCT
eurjchem-2518	10	13	outdated	outdated	ADJ
eurjchem-2518	10	14	claus	claus	NOUN
eurjchem-2518	10	15	method	method	NOUN
eurjchem-2518	10	16	of	of	ADP
eurjchem-2518	10	17	h2s	h2s	NOUN
eurjchem-2518	10	18	disposal	disposal	NOUN
eurjchem-2518	10	19	with	with	ADP
eurjchem-2518	10	20	the	the	DET
eurjchem-2518	10	21	production	production	NOUN
eurjchem-2518	10	22	of	of	ADP
eurjchem-2518	10	23	water	water	NOUN
eurjchem-2518	10	24	and	and	CCONJ
eurjchem-2518	10	25	sulfur	sulfur	NOUN
eurjchem-2518	10	26	(	(	PUNCT
eurjchem-2518	10	27	up	up	ADP
eurjchem-2518	10	28	to	to	PART
eurjchem-2518	10	29	100	100	NUM
eurjchem-2518	10	30	million	million	NUM
eurjchem-2518	10	31	tons	ton	NOUN
eurjchem-2518	10	32	per	per	ADP
eurjchem-2518	10	33	year	year	NOUN
eurjchem-2518	10	34	,	,	PUNCT
eurjchem-2518	10	35	more	more	ADJ
eurjchem-2518	10	36	than	than	ADP
eurjchem-2518	10	37	1,000	1,000	NUM
eurjchem-2518	10	38	units	unit	NOUN
eurjchem-2518	10	39	in	in	ADP
eurjchem-2518	10	40	the	the	DET
eurjchem-2518	10	41	world	world	NOUN
eurjchem-2518	10	42	)	)	PUNCT
eurjchem-2518	10	43	with	with	ADP
eurjchem-2518	10	44	advanced	advanced	ADJ
eurjchem-2518	10	45	technology	technology	NOUN
eurjchem-2518	10	46	to	to	PART
eurjchem-2518	10	47	produce	produce	VERB
eurjchem-2518	10	48	hydrogen	hydrogen	NOUN
eurjchem-2518	10	49	and	and	CCONJ
eurjchem-2518	10	50	diatomic	diatomic	ADJ
eurjchem-2518	10	51	gaseous	gaseous	ADJ
eurjchem-2518	10	52	sulfur	sulfur	NOUN
eurjchem-2518	10	53	.	.	PUNCT
eurjchem-2518	11	1	various	various	ADJ
eurjchem-2518	11	2	types	type	NOUN
eurjchem-2518	11	3	of	of	ADP
eurjchem-2518	11	4	solid	solid	ADJ
eurjchem-2518	11	5	catalysts	catalyst	NOUN
eurjchem-2518	11	6	have	have	AUX
eurjchem-2518	11	7	been	be	AUX
eurjchem-2518	11	8	developed	develop	VERB
eurjchem-2518	11	9	to	to	PART
eurjchem-2518	11	10	implement	implement	VERB
eurjchem-2518	11	11	advanced	advanced	ADJ
eurjchem-2518	11	12	technology	technology	NOUN
eurjchem-2518	11	13	.	.	PUNCT
eurjchem-2518	12	1	the	the	DET
eurjchem-2518	12	2	advanced	advanced	ADJ
eurjchem-2518	12	3	h2s	h2s	NOUN
eurjchem-2518	12	4	paradigm	paradigm	NOUN
eurjchem-2518	12	5	of	of	ADP
eurjchem-2518	12	6	catalytic	catalytic	ADJ
eurjchem-2518	12	7	processing	processing	NOUN
eurjchem-2518	12	8	allows	allow	VERB
eurjchem-2518	12	9	unexpected	unexpected	ADJ
eurjchem-2518	12	10	chemical	chemical	ADJ
eurjchem-2518	12	11	reactions	reaction	NOUN
eurjchem-2518	12	12	to	to	PART
eurjchem-2518	12	13	be	be	AUX
eurjchem-2518	12	14	realized	realize	VERB
eurjchem-2518	12	15	that	that	PRON
eurjchem-2518	12	16	can	can	AUX
eurjchem-2518	12	17	not	not	PART
eurjchem-2518	12	18	be	be	AUX
eurjchem-2518	12	19	carried	carry	VERB
eurjchem-2518	12	20	out	out	ADP
eurjchem-2518	12	21	by	by	ADP
eurjchem-2518	12	22	traditional	traditional	ADJ
eurjchem-2518	12	23	methods	method	NOUN
eurjchem-2518	12	24	under	under	ADP
eurjchem-2518	12	25	normal	normal	ADJ
eurjchem-2518	12	26	conditions	condition	NOUN
eurjchem-2518	12	27	.	.	PUNCT
eurjchem-2518	13	1	atomically	atomically	ADV
eurjchem-2518	13	2	adsorbed	adsorb	VERB
eurjchem-2518	13	3	hydrogen	hydrogen	NOUN
eurjchem-2518	13	4	and	and	CCONJ
eurjchem-2518	13	5	sulfur	sulfur	NOUN
eurjchem-2518	13	6	species	specie	NOUN
eurjchem-2518	13	7	formed	form	VERB
eurjchem-2518	13	8	as	as	ADP
eurjchem-2518	13	9	a	a	DET
eurjchem-2518	13	10	result	result	NOUN
eurjchem-2518	13	11	of	of	ADP
eurjchem-2518	13	12	h2s	h2s	NOUN
eurjchem-2518	13	13	dissociation	dissociation	NOUN
eurjchem-2518	13	14	can	can	AUX
eurjchem-2518	13	15	react	react	VERB
eurjchem-2518	13	16	with	with	ADP
eurjchem-2518	13	17	chemically	chemically	ADV
eurjchem-2518	13	18	inert	inert	ADJ
eurjchem-2518	13	19	molecules	molecule	NOUN
eurjchem-2518	13	20	of	of	ADP
eurjchem-2518	13	21	methane	methane	NOUN
eurjchem-2518	13	22	,	,	PUNCT
eurjchem-2518	13	23	co2	co2	NOUN
eurjchem-2518	13	24	,	,	PUNCT
eurjchem-2518	13	25	nitrogen	nitrogen	NOUN
eurjchem-2518	13	26	,	,	PUNCT
eurjchem-2518	13	27	and	and	CCONJ
eurjchem-2518	13	28	argon	argon	NOUN
eurjchem-2518	13	29	.	.	PUNCT
eurjchem-2518	14	1	it	it	PRON
eurjchem-2518	14	2	is	be	AUX
eurjchem-2518	14	3	concluded	conclude	VERB
eurjchem-2518	14	4	that	that	SCONJ
eurjchem-2518	14	5	at	at	ADP
eurjchem-2518	14	6	the	the	DET
eurjchem-2518	14	7	moment	moment	NOUN
eurjchem-2518	14	8	all	all	DET
eurjchem-2518	14	9	prerequisites	prerequisite	NOUN
eurjchem-2518	14	10	have	have	AUX
eurjchem-2518	14	11	been	be	AUX
eurjchem-2518	14	12	created	create	VERB
eurjchem-2518	14	13	for	for	ADP
eurjchem-2518	14	14	initiating	initiate	VERB
eurjchem-2518	14	15	full	full	ADJ
eurjchem-2518	14	16	-	-	PUNCT
eurjchem-2518	14	17	scale	scale	NOUN
eurjchem-2518	14	18	scientific	scientific	ADJ
eurjchem-2518	14	19	,	,	PUNCT
eurjchem-2518	14	20	technological	technological	ADJ
eurjchem-2518	14	21	,	,	PUNCT
eurjchem-2518	14	22	and	and	CCONJ
eurjchem-2518	14	23	commercial	commercial	ADJ
eurjchem-2518	14	24	projects	project	NOUN
eurjchem-2518	14	25	to	to	PART
eurjchem-2518	14	26	implement	implement	VERB
eurjchem-2518	14	27	the	the	DET
eurjchem-2518	14	28	innovative	innovative	ADJ
eurjchem-2518	14	29	idea	idea	NOUN
eurjchem-2518	14	30	of	of	ADP
eurjchem-2518	14	31	using	use	VERB
eurjchem-2518	14	32	the	the	DET
eurjchem-2518	14	33	toxic	toxic	ADJ
eurjchem-2518	14	34	substance	substance	NOUN
eurjchem-2518	14	35	h2s	h2s	NOUN
eurjchem-2518	14	36	to	to	PART
eurjchem-2518	14	37	serve	serve	VERB
eurjchem-2518	14	38	humanity	humanity	NOUN
eurjchem-2518	14	39	.	.	PUNCT
eurjchem-2518	15	1	entropy	entropy	PROPN
eurjchem-2518	15	2	solid	solid	ADJ
eurjchem-2518	15	3	catalysts	catalyst	NOUN
eurjchem-2518	15	4	gibbs	gibbs	PROPN
eurjchem-2518	15	5	free	free	ADJ
eurjchem-2518	15	6	energy	energy	NOUN
eurjchem-2518	15	7	h2s	h2s	NOUN
eurjchem-2518	15	8	decomposition	decomposition	NOUN
eurjchem-2518	15	9	hydrogen	hydrogen	NOUN
eurjchem-2518	15	10	production	production	NOUN
eurjchem-2518	15	11	non	non	ADJ
eurjchem-2518	15	12	-	-	ADJ
eurjchem-2518	15	13	equilibrium	equilibrium	ADJ
eurjchem-2518	15	14	thermodynamics	thermodynamic	NOUN
eurjchem-2518	15	15	cite	cite	VERB
eurjchem-2518	15	16	this	this	PRON
eurjchem-2518	15	17	:	:	PUNCT
eurjchem-2518	15	18	eur	eur	PROPN
eurjchem-2518	15	19	.	.	PUNCT
eurjchem-2518	16	1	j.	j.	PROPN
eurjchem-2518	16	2	chem	chem	PROPN
eurjchem-2518	16	3	.	.	PUNCT
eurjchem-2518	17	1	2024	2024	NUM
eurjchem-2518	17	2	,	,	PUNCT
eurjchem-2518	17	3	15(2	15(2	NUM
eurjchem-2518	17	4	)	)	PUNCT
eurjchem-2518	17	5	,	,	PUNCT
eurjchem-2518	17	6	186	186	NUM
eurjchem-2518	17	7	-	-	SYM
eurjchem-2518	17	8	193	193	NUM
eurjchem-2518	17	9	journal	journal	NOUN
eurjchem-2518	17	10	website	website	NOUN
eurjchem-2518	17	11	:	:	PUNCT
eurjchem-2518	17	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2518	17	13	1	1	X
eurjchem-2518	17	14	.	.	X
eurjchem-2518	17	15	introduction	introduction	NOUN
eurjchem-2518	17	16	the	the	DET
eurjchem-2518	17	17	problem	problem	NOUN
eurjchem-2518	17	18	of	of	ADP
eurjchem-2518	17	19	predicting	predict	VERB
eurjchem-2518	17	20	the	the	DET
eurjchem-2518	17	21	chemical	chemical	ADJ
eurjchem-2518	17	22	properties	property	NOUN
eurjchem-2518	17	23	of	of	ADP
eurjchem-2518	17	24	solid	solid	ADJ
eurjchem-2518	17	25	catalysts	catalyst	NOUN
eurjchem-2518	17	26	for	for	ADP
eurjchem-2518	17	27	a	a	DET
eurjchem-2518	17	28	specific	specific	ADJ
eurjchem-2518	17	29	reaction	reaction	NOUN
eurjchem-2518	17	30	has	have	AUX
eurjchem-2518	17	31	been	be	AUX
eurjchem-2518	17	32	exciting	exciting	ADJ
eurjchem-2518	17	33	the	the	DET
eurjchem-2518	17	34	minds	mind	NOUN
eurjchem-2518	17	35	of	of	ADP
eurjchem-2518	17	36	scientists	scientist	NOUN
eurjchem-2518	17	37	since	since	SCONJ
eurjchem-2518	17	38	the	the	DET
eurjchem-2518	17	39	understanding	understanding	NOUN
eurjchem-2518	17	40	of	of	ADP
eurjchem-2518	17	41	the	the	DET
eurjchem-2518	17	42	essence	essence	NOUN
eurjchem-2518	17	43	of	of	ADP
eurjchem-2518	17	44	catalysis	catalysis	NOUN
eurjchem-2518	17	45	as	as	ADP
eurjchem-2518	17	46	a	a	DET
eurjchem-2518	17	47	natural	natural	ADJ
eurjchem-2518	17	48	phenomenon	phenomenon	NOUN
eurjchem-2518	17	49	and	and	CCONJ
eurjchem-2518	17	50	since	since	SCONJ
eurjchem-2518	17	51	the	the	DET
eurjchem-2518	17	52	selection	selection	NOUN
eurjchem-2518	17	53	of	of	ADP
eurjchem-2518	17	54	highly	highly	ADV
eurjchem-2518	17	55	active	active	ADJ
eurjchem-2518	17	56	and	and	CCONJ
eurjchem-2518	17	57	selective	selective	ADJ
eurjchem-2518	17	58	catalysts	catalyst	NOUN
eurjchem-2518	17	59	has	have	AUX
eurjchem-2518	17	60	always	always	ADV
eurjchem-2518	17	61	been	be	AUX
eurjchem-2518	17	62	based	base	VERB
eurjchem-2518	17	63	on	on	ADP
eurjchem-2518	17	64	the	the	DET
eurjchem-2518	17	65	intuition	intuition	NOUN
eurjchem-2518	17	66	of	of	ADP
eurjchem-2518	17	67	the	the	DET
eurjchem-2518	17	68	researcher	researcher	NOUN
eurjchem-2518	17	69	.	.	PUNCT
eurjchem-2518	18	1	however	however	ADV
eurjchem-2518	18	2	,	,	PUNCT
eurjchem-2518	18	3	if	if	SCONJ
eurjchem-2518	18	4	for	for	ADP
eurjchem-2518	18	5	a	a	DET
eurjchem-2518	18	6	gas	gas	NOUN
eurjchem-2518	18	7	-	-	PUNCT
eurjchem-2518	18	8	phase	phase	NOUN
eurjchem-2518	18	9	chemical	chemical	NOUN
eurjchem-2518	18	10	process	process	NOUN
eurjchem-2518	18	11	"	"	PUNCT
eurjchem-2518	18	12	resolved	resolve	VERB
eurjchem-2518	18	13	"	"	PUNCT
eurjchem-2518	18	14	by	by	ADP
eurjchem-2518	18	15	equilibrium	equilibrium	NOUN
eurjchem-2518	18	16	classical	classical	ADJ
eurjchem-2518	18	17	thermodynamics	thermodynamic	NOUN
eurjchem-2518	18	18	,	,	PUNCT
eurjchem-2518	18	19	the	the	DET
eurjchem-2518	18	20	problem	problem	NOUN
eurjchem-2518	18	21	boils	boil	VERB
eurjchem-2518	18	22	down	down	ADP
eurjchem-2518	18	23	to	to	ADP
eurjchem-2518	18	24	a	a	DET
eurjchem-2518	18	25	simple	simple	ADJ
eurjchem-2518	18	26	empirical	empirical	ADJ
eurjchem-2518	18	27	selection	selection	NOUN
eurjchem-2518	18	28	of	of	ADP
eurjchem-2518	18	29	a	a	DET
eurjchem-2518	18	30	suitable	suitable	ADJ
eurjchem-2518	18	31	catalyst	catalyst	NOUN
eurjchem-2518	18	32	,	,	PUNCT
eurjchem-2518	18	33	then	then	ADV
eurjchem-2518	18	34	for	for	ADP
eurjchem-2518	18	35	irreversible	irreversible	ADJ
eurjchem-2518	18	36	processes	process	NOUN
eurjchem-2518	18	37	occurring	occur	VERB
eurjchem-2518	18	38	in	in	ADP
eurjchem-2518	18	39	nature	nature	NOUN
eurjchem-2518	18	40	within	within	ADP
eurjchem-2518	18	41	the	the	DET
eurjchem-2518	18	42	framework	framework	NOUN
eurjchem-2518	18	43	of	of	ADP
eurjchem-2518	18	44	non	non	ADJ
eurjchem-2518	18	45	-	-	ADJ
eurjchem-2518	18	46	equilibrium	equilibrium	ADJ
eurjchem-2518	18	47	thermodynamics	thermodynamic	NOUN
eurjchem-2518	18	48	,	,	PUNCT
eurjchem-2518	18	49	such	such	DET
eurjchem-2518	18	50	an	an	DET
eurjchem-2518	18	51	approach	approach	NOUN
eurjchem-2518	18	52	is	be	AUX
eurjchem-2518	18	53	hardly	hardly	ADV
eurjchem-2518	18	54	possible	possible	ADJ
eurjchem-2518	18	55	in	in	ADP
eurjchem-2518	18	56	principle	principle	NOUN
eurjchem-2518	18	57	,	,	PUNCT
eurjchem-2518	18	58	since	since	SCONJ
eurjchem-2518	18	59	it	it	PRON
eurjchem-2518	18	60	requires	require	VERB
eurjchem-2518	18	61	knowledge	knowledge	NOUN
eurjchem-2518	18	62	of	of	ADP
eurjchem-2518	18	63	the	the	DET
eurjchem-2518	18	64	detailed	detailed	ADJ
eurjchem-2518	18	65	mechanism	mechanism	NOUN
eurjchem-2518	18	66	of	of	ADP
eurjchem-2518	18	67	interaction	interaction	NOUN
eurjchem-2518	18	68	of	of	ADP
eurjchem-2518	18	69	substrate	substrate	NOUN
eurjchem-2518	18	70	molecules	molecule	NOUN
eurjchem-2518	18	71	not	not	PART
eurjchem-2518	18	72	only	only	ADV
eurjchem-2518	18	73	among	among	ADP
eurjchem-2518	18	74	themselves	themselves	PRON
eurjchem-2518	18	75	but	but	CCONJ
eurjchem-2518	18	76	also	also	ADV
eurjchem-2518	18	77	knowledge	knowledge	NOUN
eurjchem-2518	18	78	of	of	ADP
eurjchem-2518	18	79	the	the	DET
eurjchem-2518	18	80	elementary	elementary	ADJ
eurjchem-2518	18	81	stage	stage	NOUN
eurjchem-2518	18	82	mechanisms	mechanism	NOUN
eurjchem-2518	18	83	of	of	ADP
eurjchem-2518	18	84	their	their	PRON
eurjchem-2518	18	85	interaction	interaction	NOUN
eurjchem-2518	18	86	with	with	ADP
eurjchem-2518	18	87	active	active	ADJ
eurjchem-2518	18	88	centers	center	NOUN
eurjchem-2518	18	89	of	of	ADP
eurjchem-2518	18	90	biocatalysts	biocatalyst	NOUN
eurjchem-2518	18	91	(	(	PUNCT
eurjchem-2518	18	92	enzymes	enzyme	NOUN
eurjchem-2518	18	93	)	)	PUNCT
eurjchem-2518	18	94	,	,	PUNCT
eurjchem-2518	18	95	taking	take	VERB
eurjchem-2518	18	96	into	into	ADP
eurjchem-2518	18	97	account	account	NOUN
eurjchem-2518	18	98	thermodynamics	thermodynamic	NOUN
eurjchem-2518	18	99	of	of	ADP
eurjchem-2518	18	100	all	all	DET
eurjchem-2518	18	101	these	these	DET
eurjchem-2518	18	102	stages	stage	NOUN
eurjchem-2518	18	103	[	[	X
eurjchem-2518	18	104	1	1	NUM
eurjchem-2518	18	105	]	]	PUNCT
eurjchem-2518	18	106	.	.	PUNCT
eurjchem-2518	19	1	this	this	PRON
eurjchem-2518	19	2	is	be	AUX
eurjchem-2518	19	3	exactly	exactly	ADV
eurjchem-2518	19	4	the	the	DET
eurjchem-2518	19	5	situation	situation	NOUN
eurjchem-2518	19	6	in	in	ADP
eurjchem-2518	19	7	the	the	DET
eurjchem-2518	19	8	case	case	NOUN
eurjchem-2518	19	9	of	of	ADP
eurjchem-2518	19	10	h2s	h2s	NOUN
eurjchem-2518	19	11	assimilation	assimilation	NOUN
eurjchem-2518	19	12	by	by	ADP
eurjchem-2518	19	13	sulfur	sulfur	NOUN
eurjchem-2518	19	14	bacteria	bacteria	NOUN
eurjchem-2518	19	15	.	.	PUNCT
eurjchem-2518	20	1	indeed	indeed	ADV
eurjchem-2518	20	2	,	,	PUNCT
eurjchem-2518	20	3	at	at	ADP
eurjchem-2518	20	4	the	the	DET
eurjchem-2518	20	5	end	end	NOUN
eurjchem-2518	20	6	of	of	ADP
eurjchem-2518	20	7	the	the	DET
eurjchem-2518	20	8	nineteenth	nineteenth	ADJ
eurjchem-2518	20	9	century	century	NOUN
eurjchem-2518	20	10	,	,	PUNCT
eurjchem-2518	20	11	sergey	sergey	PROPN
eurjchem-2518	20	12	vinogradsky	vinogradsky	PROPN
eurjchem-2518	20	13	discovered	discover	VERB
eurjchem-2518	20	14	an	an	DET
eurjchem-2518	20	15	amazing	amazing	ADJ
eurjchem-2518	20	16	process	process	NOUN
eurjchem-2518	20	17	of	of	ADP
eurjchem-2518	20	18	chemosynthesis	chemosynthesis	NOUN
eurjchem-2518	20	19	of	of	ADP
eurjchem-2518	20	20	organic	organic	ADJ
eurjchem-2518	20	21	molecules	molecule	NOUN
eurjchem-2518	20	22	using	use	VERB
eurjchem-2518	20	23	sulfur	sulfur	NOUN
eurjchem-2518	20	24	bacteria	bacteria	NOUN
eurjchem-2518	20	25	that	that	PRON
eurjchem-2518	20	26	catalyze	catalyze	VERB
eurjchem-2518	20	27	the	the	DET
eurjchem-2518	20	28	reaction	reaction	NOUN
eurjchem-2518	20	29	of	of	ADP
eurjchem-2518	20	30	h2s	h2s	NOUN
eurjchem-2518	20	31	interaction	interaction	NOUN
eurjchem-2518	20	32	with	with	ADP
eurjchem-2518	20	33	carbon	carbon	NOUN
eurjchem-2518	20	34	dioxide	dioxide	NOUN
eurjchem-2518	20	35	.	.	PUNCT
eurjchem-2518	21	1	this	this	DET
eurjchem-2518	21	2	process	process	NOUN
eurjchem-2518	21	3	,	,	PUNCT
eurjchem-2518	21	4	unlike	unlike	ADP
eurjchem-2518	21	5	photosynthesis	photosynthesis	NOUN
eurjchem-2518	21	6	known	know	VERB
eurjchem-2518	21	7	at	at	ADP
eurjchem-2518	21	8	that	that	DET
eurjchem-2518	21	9	time	time	NOUN
eurjchem-2518	21	10	,	,	PUNCT
eurjchem-2518	21	11	did	do	AUX
eurjchem-2518	21	12	not	not	PART
eurjchem-2518	21	13	require	require	VERB
eurjchem-2518	21	14	sunlight	sunlight	NOUN
eurjchem-2518	21	15	as	as	ADP
eurjchem-2518	21	16	an	an	DET
eurjchem-2518	21	17	energy	energy	NOUN
eurjchem-2518	21	18	source	source	NOUN
eurjchem-2518	21	19	[	[	X
eurjchem-2518	21	20	2	2	NUM
eurjchem-2518	21	21	]	]	PUNCT
eurjchem-2518	21	22	.	.	PUNCT
eurjchem-2518	22	1	it	it	PRON
eurjchem-2518	22	2	would	would	AUX
eurjchem-2518	22	3	seem	seem	VERB
eurjchem-2518	22	4	that	that	SCONJ
eurjchem-2518	22	5	this	this	DET
eurjchem-2518	22	6	scientific	scientific	ADJ
eurjchem-2518	22	7	discovery	discovery	NOUN
eurjchem-2518	22	8	will	will	AUX
eurjchem-2518	22	9	allow	allow	VERB
eurjchem-2518	22	10	mankind	mankind	NOUN
eurjchem-2518	22	11	to	to	PART
eurjchem-2518	22	12	solve	solve	VERB
eurjchem-2518	22	13	not	not	PART
eurjchem-2518	22	14	only	only	ADV
eurjchem-2518	22	15	the	the	DET
eurjchem-2518	22	16	problem	problem	NOUN
eurjchem-2518	22	17	of	of	ADP
eurjchem-2518	22	18	recycling	recycle	VERB
eurjchem-2518	22	19	toxic	toxic	ADJ
eurjchem-2518	22	20	h2s	h2s	NOUN
eurjchem-2518	22	21	,	,	PUNCT
eurjchem-2518	22	22	but	but	CCONJ
eurjchem-2518	22	23	also	also	ADV
eurjchem-2518	22	24	to	to	PART
eurjchem-2518	22	25	use	use	VERB
eurjchem-2518	22	26	it	it	PRON
eurjchem-2518	22	27	for	for	ADP
eurjchem-2518	22	28	the	the	DET
eurjchem-2518	22	29	synthesis	synthesis	NOUN
eurjchem-2518	22	30	of	of	ADP
eurjchem-2518	22	31	the	the	DET
eurjchem-2518	22	32	chemicals	chemical	NOUN
eurjchem-2518	22	33	demanded	demand	VERB
eurjchem-2518	22	34	.	.	PUNCT
eurjchem-2518	23	1	however	however	ADV
eurjchem-2518	23	2	,	,	PUNCT
eurjchem-2518	23	3	on	on	ADP
eurjchem-2518	23	4	the	the	DET
eurjchem-2518	23	5	way	way	NOUN
eurjchem-2518	23	6	to	to	ADP
eurjchem-2518	23	7	the	the	DET
eurjchem-2518	23	8	realization	realization	NOUN
eurjchem-2518	23	9	of	of	ADP
eurjchem-2518	23	10	this	this	DET
eurjchem-2518	23	11	idea	idea	NOUN
eurjchem-2518	23	12	,	,	PUNCT
eurjchem-2518	23	13	numerous	numerous	ADJ
eurjchem-2518	23	14	problems	problem	NOUN
eurjchem-2518	23	15	arose	arise	VERB
eurjchem-2518	23	16	with	with	ADP
eurjchem-2518	23	17	the	the	DET
eurjchem-2518	23	18	cultivation	cultivation	NOUN
eurjchem-2518	23	19	of	of	ADP
eurjchem-2518	23	20	sulfur	sulfur	NOUN
eurjchem-2518	23	21	bacteria	bacteria	NOUN
eurjchem-2518	23	22	in	in	ADP
eurjchem-2518	23	23	the	the	DET
eurjchem-2518	23	24	laboratory	laboratory	NOUN
eurjchem-2518	23	25	,	,	PUNCT
eurjchem-2518	23	26	which	which	PRON
eurjchem-2518	23	27	did	do	AUX
eurjchem-2518	23	28	not	not	PART
eurjchem-2518	23	29	allow	allow	VERB
eurjchem-2518	23	30	us	we	PRON
eurjchem-2518	23	31	to	to	PART
eurjchem-2518	23	32	solve	solve	VERB
eurjchem-2518	23	33	the	the	DET
eurjchem-2518	23	34	main	main	ADJ
eurjchem-2518	23	35	task	task	NOUN
eurjchem-2518	23	36	to	to	PART
eurjchem-2518	23	37	study	study	VERB
eurjchem-2518	23	38	the	the	DET
eurjchem-2518	23	39	nature	nature	NOUN
eurjchem-2518	23	40	of	of	ADP
eurjchem-2518	23	41	the	the	DET
eurjchem-2518	23	42	catalytically	catalytically	ADV
eurjchem-2518	23	43	active	active	ADJ
eurjchem-2518	23	44	enzymatic	enzymatic	ADJ
eurjchem-2518	23	45	centers	center	NOUN
eurjchem-2518	23	46	of	of	ADP
eurjchem-2518	23	47	these	these	DET
eurjchem-2518	23	48	bacteria	bacteria	NOUN
eurjchem-2518	23	49	and	and	CCONJ
eurjchem-2518	23	50	,	,	PUNCT
eurjchem-2518	23	51	as	as	ADP
eurjchem-2518	23	52	a	a	DET
eurjchem-2518	23	53	result	result	NOUN
eurjchem-2518	23	54	,	,	PUNCT
eurjchem-2518	23	55	the	the	DET
eurjchem-2518	23	56	mechanisms	mechanism	NOUN
eurjchem-2518	23	57	of	of	ADP
eurjchem-2518	23	58	chemosynthesis	chemosynthesis	NOUN
eurjchem-2518	23	59	.	.	PUNCT
eurjchem-2518	24	1	as	as	SCONJ
eurjchem-2518	24	2	is	be	AUX
eurjchem-2518	24	3	well	well	ADV
eurjchem-2518	24	4	known	know	VERB
eurjchem-2518	24	5	,	,	PUNCT
eurjchem-2518	24	6	hydrogen	hydrogen	NOUN
eurjchem-2518	24	7	sulfide	sulfide	NOUN
eurjchem-2518	24	8	,	,	PUNCT
eurjchem-2518	24	9	h2s	h2s	PROPN
eurjchem-2518	24	10	is	be	AUX
eurjchem-2518	24	11	one	one	NUM
eurjchem-2518	24	12	of	of	ADP
eurjchem-2518	24	13	the	the	DET
eurjchem-2518	24	14	most	most	ADV
eurjchem-2518	24	15	toxic	toxic	ADJ
eurjchem-2518	24	16	substances	substance	NOUN
eurjchem-2518	24	17	produced	produce	VERB
eurjchem-2518	24	18	as	as	ADP
eurjchem-2518	24	19	a	a	DET
eurjchem-2518	24	20	forced	forced	ADJ
eurjchem-2518	24	21	and	and	CCONJ
eurjchem-2518	24	22	unavoidable	unavoidable	ADJ
eurjchem-2518	24	23	byproduct	byproduct	NOUN
eurjchem-2518	24	24	in	in	ADP
eurjchem-2518	24	25	the	the	DET
eurjchem-2518	24	26	extractive	extractive	ADJ
eurjchem-2518	24	27	and	and	CCONJ
eurjchem-2518	24	28	processing	processing	NOUN
eurjchem-2518	24	29	industries	industry	NOUN
eurjchem-2518	24	30	in	in	ADP
eurjchem-2518	24	31	volumes	volume	NOUN
eurjchem-2518	24	32	of	of	ADP
eurjchem-2518	24	33	up	up	ADP
eurjchem-2518	24	34	to	to	PART
eurjchem-2518	24	35	one	one	NUM
eurjchem-2518	24	36	hundred	hundred	NUM
eurjchem-2518	24	37	million	million	NUM
eurjchem-2518	24	38	tons	ton	NOUN
eurjchem-2518	24	39	per	per	ADP
eurjchem-2518	24	40	year	year	NOUN
eurjchem-2518	24	41	,	,	PUNCT
eurjchem-2518	24	42	while	while	SCONJ
eurjchem-2518	24	43	its	its	PRON
eurjchem-2518	24	44	content	content	NOUN
eurjchem-2518	24	45	in	in	ADP
eurjchem-2518	24	46	the	the	DET
eurjchem-2518	24	47	bowels	bowel	NOUN
eurjchem-2518	24	48	and	and	CCONJ
eurjchem-2518	24	49	reservoirs	reservoir	NOUN
eurjchem-2518	24	50	of	of	ADP
eurjchem-2518	24	51	the	the	DET
eurjchem-2518	24	52	earth	earth	NOUN
eurjchem-2518	24	53	is	be	AUX
eurjchem-2518	24	54	estimated	estimate	VERB
eurjchem-2518	24	55	at	at	ADP
eurjchem-2518	24	56	tens	ten	NOUN
eurjchem-2518	24	57	of	of	ADP
eurjchem-2518	24	58	billions	billion	NOUN
eurjchem-2518	24	59	of	of	ADP
eurjchem-2518	24	60	tons	ton	NOUN
eurjchem-2518	24	61	.	.	PUNCT
eurjchem-2518	25	1	unlike	unlike	ADP
eurjchem-2518	25	2	its	its	PRON
eurjchem-2518	25	3	chemical	chemical	NOUN
eurjchem-2518	25	4	counterpart	counterpart	NOUN
eurjchem-2518	25	5	,	,	PUNCT
eurjchem-2518	25	6	water	water	NOUN
eurjchem-2518	25	7	,	,	PUNCT
eurjchem-2518	25	8	hydrogen	hydrogen	NOUN
eurjchem-2518	25	9	sulfide	sulfide	NOUN
eurjchem-2518	25	10	is	be	AUX
eurjchem-2518	25	11	a	a	DET
eurjchem-2518	25	12	"	"	PUNCT
eurjchem-2518	25	13	useless	useless	ADJ
eurjchem-2518	25	14	"	"	PUNCT
eurjchem-2518	25	15	substance	substance	NOUN
eurjchem-2518	25	16	that	that	PRON
eurjchem-2518	25	17	has	have	AUX
eurjchem-2518	25	18	not	not	PART
eurjchem-2518	25	19	found	find	VERB
eurjchem-2518	25	20	practical	practical	ADJ
eurjchem-2518	25	21	application	application	NOUN
eurjchem-2518	25	22	in	in	ADP
eurjchem-2518	25	23	human	human	ADJ
eurjchem-2518	25	24	life	life	NOUN
eurjchem-2518	25	25	.	.	PUNCT
eurjchem-2518	26	1	in	in	ADP
eurjchem-2518	26	2	the	the	DET
eurjchem-2518	26	3	interim	interim	NOUN
eurjchem-2518	26	4	,	,	PUNCT
eurjchem-2518	26	5	the	the	DET
eurjchem-2518	26	6	toxicological	toxicological	ADJ
eurjchem-2518	26	7	properties	property	NOUN
eurjchem-2518	26	8	of	of	ADP
eurjchem-2518	26	9	hydrogen	hydrogen	NOUN
eurjchem-2518	26	10	sulfide	sulfide	NOUN
eurjchem-2518	26	11	required	require	VERB
eurjchem-2518	26	12	taking	take	VERB
eurjchem-2518	26	13	all	all	DET
eurjchem-2518	26	14	necessary	necessary	ADJ
eurjchem-2518	26	15	measures	measure	NOUN
eurjchem-2518	26	16	to	to	PART
eurjchem-2518	26	17	destroy	destroy	VERB
eurjchem-2518	26	18	this	this	DET
eurjchem-2518	26	19	substance	substance	NOUN
eurjchem-2518	26	20	to	to	ADP
eurjchem-2518	26	21	the	the	DET
eurjchem-2518	26	22	level	level	NOUN
eurjchem-2518	26	23	of	of	ADP
eurjchem-2518	26	24	safety	safety	NOUN
eurjchem-2518	26	25	standards	standard	NOUN
eurjchem-2518	26	26	.	.	PUNCT
eurjchem-2518	27	1	the	the	DET
eurjchem-2518	27	2	processes	process	NOUN
eurjchem-2518	27	3	of	of	ADP
eurjchem-2518	27	4	h2s	h2s	NOUN
eurjchem-2518	27	5	utilization	utilization	NOUN
eurjchem-2518	27	6	(	(	PUNCT
eurjchem-2518	27	7	more	more	ADJ
eurjchem-2518	27	8	than	than	ADP
eurjchem-2518	27	9	1000	1000	NUM
eurjchem-2518	27	10	installations	installation	NOUN
eurjchem-2518	27	11	worldwide	worldwide	ADV
eurjchem-2518	27	12	)	)	PUNCT
eurjchem-2518	27	13	are	be	AUX
eurjchem-2518	27	14	carried	carry	VERB
eurjchem-2518	27	15	out	out	ADP
eurjchem-2518	27	16	by	by	ADP
eurjchem-2518	27	17	the	the	DET
eurjchem-2518	27	18	claus	claus	NOUN
eurjchem-2518	27	19	method	method	NOUN
eurjchem-2518	27	20	,	,	PUNCT
eurjchem-2518	27	21	discovered	discover	VERB
eurjchem-2518	27	22	back	back	ADV
eurjchem-2518	27	23	in	in	ADP
eurjchem-2518	27	24	the	the	DET
eurjchem-2518	27	25	19th	19th	ADJ
eurjchem-2518	27	26	century	century	NOUN
eurjchem-2518	27	27	;	;	PUNCT
eurjchem-2518	27	28	as	as	ADP
eurjchem-2518	27	29	a	a	DET
eurjchem-2518	27	30	result	result	NOUN
eurjchem-2518	27	31	,	,	PUNCT
eurjchem-2518	27	32	the	the	DET
eurjchem-2518	27	33	purification	purification	NOUN
eurjchem-2518	27	34	products	product	NOUN
eurjchem-2518	27	35	are	be	AUX
eurjchem-2518	27	36	water	water	NOUN
eurjchem-2518	27	37	and	and	CCONJ
eurjchem-2518	27	38	solid	solid	ADJ
eurjchem-2518	27	39	sulfur	sulfur	NOUN
eurjchem-2518	27	40	.	.	PUNCT
eurjchem-2518	28	1	thus	thus	ADV
eurjchem-2518	28	2	,	,	PUNCT
eurjchem-2518	28	3	hydrogen	hydrogen	NOUN
eurjchem-2518	28	4	h2	h2	NOUN
eurjchem-2518	28	5	,	,	PUNCT
eurjchem-2518	28	6	a	a	DET
eurjchem-2518	28	7	constituent	constituent	NOUN
eurjchem-2518	28	8	element	element	NOUN
eurjchem-2518	28	9	of	of	ADP
eurjchem-2518	28	10	hydrogen	hydrogen	NOUN
eurjchem-2518	28	11	sulfide	sulfide	NOUN
eurjchem-2518	28	12	h2s	h2s	NOUN
eurjchem-2518	28	13	,	,	PUNCT
eurjchem-2518	28	14	is	be	AUX
eurjchem-2518	28	15	irreversibly	irreversibly	ADV
eurjchem-2518	28	16	"	"	PUNCT
eurjchem-2518	28	17	lost	lose	VERB
eurjchem-2518	28	18	"	"	PUNCT
eurjchem-2518	28	19	in	in	ADP
eurjchem-2518	28	20	the	the	DET
eurjchem-2518	28	21	form	form	NOUN
eurjchem-2518	28	22	of	of	ADP
eurjchem-2518	28	23	water	water	NOUN
eurjchem-2518	28	24	h2o	h2o	PROPN
eurjchem-2518	28	25	,	,	PUNCT
eurjchem-2518	28	26	thereby	thereby	ADV
eurjchem-2518	28	27	eliminating	eliminate	VERB
eurjchem-2518	28	28	the	the	DET
eurjchem-2518	28	29	possibility	possibility	NOUN
eurjchem-2518	28	30	of	of	ADP
eurjchem-2518	28	31	its	its	PRON
eurjchem-2518	28	32	use	use	NOUN
eurjchem-2518	28	33	as	as	ADP
eurjchem-2518	28	34	an	an	DET
eurjchem-2518	28	35	environ	environ	X
eurjchem-2518	28	36	abstract	abstract	ADJ
eurjchem-2518	28	37	review	review	NOUN
eurjchem-2518	28	38	article	article	NOUN
eurjchem-2518	28	39	keywords	keyword	VERB
eurjchem-2518	28	40	https://dx.doi.org/10.5155/eurjchem.15.2.186-193.2518	https://dx.doi.org/10.5155/eurjchem.15.2.186-193.2518	PROPN
eurjchem-2518	28	41	https://www.eurjchem.com/	https://www.eurjchem.com/	ADJ
eurjchem-2518	28	42	https://dx.doi.org/10.5155/eurjchem.15.2.186-193.2518	https://dx.doi.org/10.5155/eurjchem.15.2.186-193.2518	ADJ
eurjchem-2518	28	43	mailto:anatolii.startsev@gmail.com	mailto:anatolii.startsev@gmail.com	PROPN
eurjchem-2518	28	44	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2518	28	45	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.15.2.186-193.2518&domain=pdf&date_stamp=2024-06-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.15.2.186-193.2518&domain=pdf&date_stamp=2024-06-30	NOUN
eurjchem-2518	28	46	anatolii	anatolii	NOUN
eurjchem-2518	28	47	startsev	startsev	NOUN
eurjchem-2518	28	48	/	/	SYM
eurjchem-2518	28	49	european	european	ADJ
eurjchem-2518	28	50	journal	journal	PROPN
eurjchem-2518	28	51	of	of	ADP
eurjchem-2518	28	52	chemistry	chemistry	NOUN
eurjchem-2518	28	53	15	15	NUM
eurjchem-2518	28	54	(	(	PUNCT
eurjchem-2518	28	55	2	2	NUM
eurjchem-2518	28	56	)	)	PUNCT
eurjchem-2518	28	57	(	(	PUNCT
eurjchem-2518	28	58	2024	2024	NUM
eurjchem-2518	28	59	)	)	PUNCT
eurjchem-2518	28	60	186	186	NUM
eurjchem-2518	28	61	-	-	SYM
eurjchem-2518	28	62	193	193	NUM
eurjchem-2518	28	63	187	187	NUM
eurjchem-2518	28	64	2024	2024	NUM
eurjchem-2518	28	65	–	–	PUNCT
eurjchem-2518	28	66	european	european	ADJ
eurjchem-2518	28	67	journal	journal	NOUN
eurjchem-2518	28	68	of	of	ADP
eurjchem-2518	28	69	chemistry	chemistry	NOUN
eurjchem-2518	28	70	–	–	PUNCT
eurjchem-2518	28	71	cc	cc	NOUN
eurjchem-2518	28	72	by	by	ADP
eurjchem-2518	28	73	nc	nc	PROPN
eurjchem-2518	28	74	–	–	PUNCT
eurjchem-2518	28	75	doi	doi	NOUN
eurjchem-2518	28	76	:	:	PUNCT
eurjchem-2518	28	77	10.5155	10.5155	NUM
eurjchem-2518	28	78	/	/	SYM
eurjchem-2518	28	79	eurjchem.15.2.186	eurjchem.15.2.186	VERB
eurjchem-2518	28	80	-	-	PUNCT
eurjchem-2518	28	81	193.2518	193.2518	NUM
eurjchem-2518	28	82	figure	figure	NOUN
eurjchem-2518	28	83	1	1	NUM
eurjchem-2518	28	84	.	.	PUNCT
eurjchem-2518	29	1	a	a	DET
eurjchem-2518	29	2	fragment	fragment	NOUN
eurjchem-2518	29	3	of	of	ADP
eurjchem-2518	29	4	the	the	DET
eurjchem-2518	29	5	structure	structure	NOUN
eurjchem-2518	29	6	of	of	ADP
eurjchem-2518	29	7	the	the	DET
eurjchem-2518	29	8	electroneutral	electroneutral	ADJ
eurjchem-2518	29	9	macromolecule	macromolecule	NOUN
eurjchem-2518	29	10	of	of	ADP
eurjchem-2518	29	11	the	the	DET
eurjchem-2518	29	12	active	active	ADJ
eurjchem-2518	29	13	component	component	NOUN
eurjchem-2518	29	14	of	of	ADP
eurjchem-2518	29	15	sulfide	sulfide	NOUN
eurjchem-2518	29	16	hds	hds	PROPN
eurjchem-2518	29	17	catalysts	catalyst	VERB
eurjchem-2518	29	18	with	with	ADP
eurjchem-2518	29	19	an	an	DET
eurjchem-2518	29	20	occluded	occluded	ADJ
eurjchem-2518	29	21	hydrogen	hydrogen	NOUN
eurjchem-2518	29	22	and	and	CCONJ
eurjchem-2518	29	23	h2s	h2s	NOUN
eurjchem-2518	29	24	molecule	molecule	NOUN
eurjchem-2518	29	25	adsorbed	adsorb	VERB
eurjchem-2518	29	26	on	on	ADP
eurjchem-2518	29	27	the	the	DET
eurjchem-2518	29	28	active	active	ADJ
eurjchem-2518	29	29	centers	center	NOUN
eurjchem-2518	29	30	of	of	ADP
eurjchem-2518	29	31	the	the	DET
eurjchem-2518	29	32	co(iii	co(iii	NOUN
eurjchem-2518	29	33	)	)	PUNCT
eurjchem-2518	29	34	or	or	CCONJ
eurjchem-2518	29	35	ni(iv	ni(iv	NOUN
eurjchem-2518	29	36	)	)	PUNCT
eurjchem-2518	29	37	atoms	atom	NOUN
eurjchem-2518	29	38	[	[	X
eurjchem-2518	29	39	13,14	13,14	NUM
eurjchem-2518	29	40	]	]	PUNCT
eurjchem-2518	29	41	.	.	PUNCT
eurjchem-2518	30	1	figure	figure	NOUN
eurjchem-2518	30	2	2	2	NUM
eurjchem-2518	30	3	.	.	PUNCT
eurjchem-2518	31	1	scheme	scheme	NOUN
eurjchem-2518	31	2	of	of	ADP
eurjchem-2518	31	3	interaction	interaction	NOUN
eurjchem-2518	31	4	of	of	ADP
eurjchem-2518	31	5	nσ	nσ	PRON
eurjchem-2518	31	6	and	and	CCONJ
eurjchem-2518	31	7	nπ	nπ	NOUN
eurjchem-2518	31	8	orbitals	orbital	NOUN
eurjchem-2518	31	9	of	of	ADP
eurjchem-2518	31	10	h2s	h2s	NOUN
eurjchem-2518	31	11	molecule	molecule	NOUN
eurjchem-2518	31	12	with	with	ADP
eurjchem-2518	31	13	the	the	DET
eurjchem-2518	31	14	3dz2	3dz2	NUM
eurjchem-2518	31	15	and	and	CCONJ
eurjchem-2518	31	16	3dxy	3dxy	NUM
eurjchem-2518	31	17	orbitals	orbital	NOUN
eurjchem-2518	31	18	of	of	ADP
eurjchem-2518	31	19	the	the	DET
eurjchem-2518	31	20	co(iii	co(iii	NOUN
eurjchem-2518	31	21	)	)	PUNCT
eurjchem-2518	31	22	atoms	atom	NOUN
eurjchem-2518	31	23	in	in	ADP
eurjchem-2518	31	24	the	the	DET
eurjchem-2518	31	25	d6	d6	NOUN
eurjchem-2518	31	26	electronic	electronic	ADJ
eurjchem-2518	31	27	configuration	configuration	NOUN
eurjchem-2518	32	1	[	[	X
eurjchem-2518	32	2	13,14	13,14	NUM
eurjchem-2518	32	3	]	]	PUNCT
eurjchem-2518	32	4	.	.	PUNCT
eurjchem-2518	33	1	ho	ho	PROPN
eurjchem-2518	33	2	–	–	PUNCT
eurjchem-2518	33	3	occluded	occluded	ADJ
eurjchem-2518	33	4	hydrogen	hydrogen	NOUN
eurjchem-2518	33	5	,	,	PUNCT
eurjchem-2518	33	6	l	l	NOUN
eurjchem-2518	33	7	–	–	PUNCT
eurjchem-2518	33	8	electron	electron	NOUN
eurjchem-2518	33	9	orbitals	orbital	NOUN
eurjchem-2518	33	10	.	.	PUNCT
eurjchem-2518	34	1	figure	figure	VERB
eurjchem-2518	34	2	3	3	NUM
eurjchem-2518	34	3	.	.	PUNCT
eurjchem-2518	35	1	a	a	DET
eurjchem-2518	35	2	fragment	fragment	NOUN
eurjchem-2518	35	3	of	of	ADP
eurjchem-2518	35	4	the	the	DET
eurjchem-2518	35	5	molecular	molecular	ADJ
eurjchem-2518	35	6	structure	structure	NOUN
eurjchem-2518	35	7	of	of	ADP
eurjchem-2518	35	8	the	the	DET
eurjchem-2518	35	9	active	active	ADJ
eurjchem-2518	35	10	component	component	NOUN
eurjchem-2518	35	11	of	of	ADP
eurjchem-2518	35	12	hds	hds	PROPN
eurjchem-2518	35	13	catalyst	catalyst	NOUN
eurjchem-2518	35	14	with	with	ADP
eurjchem-2518	35	15	two	two	NUM
eurjchem-2518	35	16	adsorbed	adsorb	VERB
eurjchem-2518	35	17	h2s	h2s	NOUN
eurjchem-2518	35	18	molecules	molecule	NOUN
eurjchem-2518	35	19	.	.	PUNCT
eurjchem-2518	36	1	mentally	mentally	ADV
eurjchem-2518	36	2	friendly	friendly	ADJ
eurjchem-2518	36	3	"	"	PUNCT
eurjchem-2518	36	4	green	green	ADJ
eurjchem-2518	36	5	"	"	PUNCT
eurjchem-2518	36	6	energy	energy	NOUN
eurjchem-2518	36	7	carrier	carrier	NOUN
eurjchem-2518	36	8	.	.	PUNCT
eurjchem-2518	37	1	therefore	therefore	ADV
eurjchem-2518	37	2	,	,	PUNCT
eurjchem-2518	37	3	many	many	ADJ
eurjchem-2518	37	4	generations	generation	NOUN
eurjchem-2518	37	5	of	of	ADP
eurjchem-2518	37	6	scientists	scientist	NOUN
eurjchem-2518	37	7	and	and	CCONJ
eurjchem-2518	37	8	researchers	researcher	NOUN
eurjchem-2518	37	9	have	have	AUX
eurjchem-2518	37	10	tried	try	VERB
eurjchem-2518	37	11	to	to	PART
eurjchem-2518	37	12	obtain	obtain	VERB
eurjchem-2518	37	13	products	product	NOUN
eurjchem-2518	37	14	in	in	ADP
eurjchem-2518	37	15	demand	demand	NOUN
eurjchem-2518	37	16	from	from	ADP
eurjchem-2518	37	17	this	this	DET
eurjchem-2518	37	18	substance	substance	NOUN
eurjchem-2518	37	19	,	,	PUNCT
eurjchem-2518	37	20	hydrogen	hydrogen	NOUN
eurjchem-2518	37	21	and	and	CCONJ
eurjchem-2518	37	22	sulfur	sulfur	NOUN
eurjchem-2518	37	23	[	[	X
eurjchem-2518	37	24	3	3	NUM
eurjchem-2518	37	25	-	-	SYM
eurjchem-2518	37	26	8	8	NUM
eurjchem-2518	37	27	]	]	PUNCT
eurjchem-2518	37	28	.	.	PUNCT
eurjchem-2518	38	1	until	until	ADP
eurjchem-2518	38	2	recently	recently	ADV
eurjchem-2518	38	3	,	,	PUNCT
eurjchem-2518	38	4	all	all	DET
eurjchem-2518	38	5	numerous	numerous	ADJ
eurjchem-2518	38	6	attempts	attempt	NOUN
eurjchem-2518	38	7	to	to	PART
eurjchem-2518	38	8	implement	implement	VERB
eurjchem-2518	38	9	this	this	DET
eurjchem-2518	38	10	very	very	ADV
eurjchem-2518	38	11	relevant	relevant	ADJ
eurjchem-2518	38	12	and	and	CCONJ
eurjchem-2518	38	13	promising	promising	ADJ
eurjchem-2518	38	14	process	process	NOUN
eurjchem-2518	38	15	on	on	ADP
eurjchem-2518	38	16	an	an	DET
eurjchem-2518	38	17	industrial	industrial	ADJ
eurjchem-2518	38	18	scale	scale	NOUN
eurjchem-2518	38	19	were	be	AUX
eurjchem-2518	38	20	undertaken	undertake	VERB
eurjchem-2518	38	21	within	within	ADP
eurjchem-2518	38	22	the	the	DET
eurjchem-2518	38	23	framework	framework	NOUN
eurjchem-2518	38	24	of	of	ADP
eurjchem-2518	38	25	classical	classical	ADJ
eurjchem-2518	38	26	equilibrium	equilibrium	NOUN
eurjchem-2518	38	27	thermodynamics	thermodynamic	NOUN
eurjchem-2518	38	28	,	,	PUNCT
eurjchem-2518	38	29	using	use	VERB
eurjchem-2518	38	30	a	a	DET
eurjchem-2518	38	31	variety	variety	NOUN
eurjchem-2518	38	32	of	of	ADP
eurjchem-2518	38	33	external	external	ADJ
eurjchem-2518	38	34	energy	energy	NOUN
eurjchem-2518	38	35	sources	source	NOUN
eurjchem-2518	38	36	to	to	PART
eurjchem-2518	38	37	activate	activate	VERB
eurjchem-2518	38	38	the	the	DET
eurjchem-2518	38	39	substrate	substrate	NOUN
eurjchem-2518	38	40	molecule	molecule	NOUN
eurjchem-2518	38	41	h2s	h2s	NOUN
eurjchem-2518	38	42	.	.	PUNCT
eurjchem-2518	39	1	however	however	ADV
eurjchem-2518	39	2	,	,	PUNCT
eurjchem-2518	39	3	so	so	ADV
eurjchem-2518	39	4	far	far	ADV
eurjchem-2518	39	5	none	none	NOUN
eurjchem-2518	39	6	of	of	ADP
eurjchem-2518	39	7	these	these	DET
eurjchem-2518	39	8	approaches	approach	NOUN
eurjchem-2518	39	9	has	have	AUX
eurjchem-2518	39	10	reached	reach	VERB
eurjchem-2518	39	11	the	the	DET
eurjchem-2518	39	12	level	level	NOUN
eurjchem-2518	39	13	of	of	ADP
eurjchem-2518	39	14	readiness	readiness	NOUN
eurjchem-2518	39	15	for	for	ADP
eurjchem-2518	39	16	commercial	commercial	ADJ
eurjchem-2518	39	17	application	application	NOUN
eurjchem-2518	39	18	in	in	ADP
eurjchem-2518	39	19	terms	term	NOUN
eurjchem-2518	39	20	of	of	ADP
eurjchem-2518	39	21	optimal	optimal	ADJ
eurjchem-2518	39	22	combination	combination	NOUN
eurjchem-2518	39	23	of	of	ADP
eurjchem-2518	39	24	the	the	DET
eurjchem-2518	39	25	four	four	NUM
eurjchem-2518	39	26	e	e	NOUN
eurjchem-2518	39	27	’s	’s	NOUN
eurjchem-2518	39	28	energy	energy	NOUN
eurjchem-2518	39	29	,	,	PUNCT
eurjchem-2518	39	30	ecology	ecology	NOUN
eurjchem-2518	39	31	,	,	PUNCT
eurjchem-2518	39	32	economics	economic	NOUN
eurjchem-2518	39	33	and	and	CCONJ
eurjchem-2518	39	34	efficiency	efficiency	NOUN
eurjchem-2518	39	35	[	[	X
eurjchem-2518	39	36	9	9	NUM
eurjchem-2518	39	37	]	]	PUNCT
eurjchem-2518	39	38	.	.	PUNCT
eurjchem-2518	40	1	meanwhile	meanwhile	ADV
eurjchem-2518	40	2	,	,	PUNCT
eurjchem-2518	40	3	an	an	DET
eurjchem-2518	40	4	original	original	ADJ
eurjchem-2518	40	5	solution	solution	NOUN
eurjchem-2518	40	6	to	to	ADP
eurjchem-2518	40	7	this	this	DET
eurjchem-2518	40	8	problem	problem	NOUN
eurjchem-2518	40	9	using	use	VERB
eurjchem-2518	40	10	heterogeneous	heterogeneous	ADJ
eurjchem-2518	40	11	catalysts	catalyst	NOUN
eurjchem-2518	40	12	has	have	AUX
eurjchem-2518	40	13	recently	recently	ADV
eurjchem-2518	40	14	been	be	AUX
eurjchem-2518	40	15	found	find	VERB
eurjchem-2518	40	16	,	,	PUNCT
eurjchem-2518	40	17	which	which	PRON
eurjchem-2518	40	18	is	be	AUX
eurjchem-2518	40	19	based	base	VERB
eurjchem-2518	40	20	on	on	ADP
eurjchem-2518	40	21	the	the	DET
eurjchem-2518	40	22	fundamental	fundamental	ADJ
eurjchem-2518	40	23	principles	principle	NOUN
eurjchem-2518	40	24	of	of	ADP
eurjchem-2518	40	25	biological	biological	ADJ
eurjchem-2518	40	26	thermodynamics	thermodynamic	NOUN
eurjchem-2518	41	1	[	[	X
eurjchem-2518	41	2	10,11	10,11	NOUN
eurjchem-2518	41	3	]	]	PUNCT
eurjchem-2518	41	4	.	.	PUNCT
eurjchem-2518	42	1	in	in	ADP
eurjchem-2518	42	2	this	this	DET
eurjchem-2518	42	3	case	case	NOUN
eurjchem-2518	42	4	,	,	PUNCT
eurjchem-2518	42	5	we	we	PRON
eurjchem-2518	42	6	are	be	AUX
eurjchem-2518	42	7	talking	talk	VERB
eurjchem-2518	42	8	about	about	ADP
eurjchem-2518	42	9	creating	create	VERB
eurjchem-2518	42	10	non	non	ADJ
eurjchem-2518	42	11	-	-	ADJ
eurjchem-2518	42	12	equilibrium	equilibrium	ADJ
eurjchem-2518	42	13	conditions	condition	NOUN
eurjchem-2518	42	14	for	for	ADP
eurjchem-2518	42	15	the	the	DET
eurjchem-2518	42	16	h2s	h2s	NOUN
eurjchem-2518	42	17	decomposition	decomposition	NOUN
eurjchem-2518	42	18	at	at	ADP
eurjchem-2518	42	19	ambient	ambient	ADJ
eurjchem-2518	42	20	temperature	temperature	NOUN
eurjchem-2518	42	21	and	and	CCONJ
eurjchem-2518	42	22	pressure	pressure	NOUN
eurjchem-2518	42	23	,	,	PUNCT
eurjchem-2518	42	24	which	which	PRON
eurjchem-2518	42	25	simulate	simulate	VERB
eurjchem-2518	42	26	irreversible	irreversible	ADJ
eurjchem-2518	42	27	processes	process	NOUN
eurjchem-2518	42	28	of	of	ADP
eurjchem-2518	42	29	chemosynthesis	chemosynthesis	NOUN
eurjchem-2518	42	30	occurring	occur	VERB
eurjchem-2518	42	31	in	in	ADP
eurjchem-2518	42	32	nature	nature	NOUN
eurjchem-2518	42	33	.	.	PUNCT
eurjchem-2518	43	1	we	we	PRON
eurjchem-2518	43	2	have	have	AUX
eurjchem-2518	43	3	shown	show	VERB
eurjchem-2518	43	4	that	that	SCONJ
eurjchem-2518	43	5	catalytic	catalytic	ADJ
eurjchem-2518	43	6	h2s	h2s	NOUN
eurjchem-2518	43	7	decomposition	decomposition	NOUN
eurjchem-2518	43	8	can	can	AUX
eurjchem-2518	43	9	occur	occur	VERB
eurjchem-2518	43	10	exclusively	exclusively	ADV
eurjchem-2518	43	11	on	on	ADP
eurjchem-2518	43	12	the	the	DET
eurjchem-2518	43	13	surface	surface	NOUN
eurjchem-2518	43	14	of	of	ADP
eurjchem-2518	43	15	solid	solid	ADJ
eurjchem-2518	43	16	catalysts	catalyst	NOUN
eurjchem-2518	43	17	due	due	ADP
eurjchem-2518	43	18	to	to	ADP
eurjchem-2518	43	19	the	the	DET
eurjchem-2518	43	20	internal	internal	ADJ
eurjchem-2518	43	21	(	(	PUNCT
eurjchem-2518	43	22	kinetic	kinetic	ADJ
eurjchem-2518	43	23	and	and	CCONJ
eurjchem-2518	43	24	potential	potential	ADJ
eurjchem-2518	43	25	)	)	PUNCT
eurjchem-2518	43	26	energy	energy	NOUN
eurjchem-2518	43	27	of	of	ADP
eurjchem-2518	43	28	the	the	DET
eurjchem-2518	43	29	substrate	substrate	NOUN
eurjchem-2518	43	30	molecules	molecule	NOUN
eurjchem-2518	43	31	,	,	PUNCT
eurjchem-2518	43	32	h2s	h2s	NOUN
eurjchem-2518	43	33	,	,	PUNCT
eurjchem-2518	43	34	without	without	ADP
eurjchem-2518	43	35	the	the	DET
eurjchem-2518	43	36	use	use	NOUN
eurjchem-2518	43	37	of	of	ADP
eurjchem-2518	43	38	external	external	ADJ
eurjchem-2518	43	39	energy	energy	NOUN
eurjchem-2518	43	40	sources	source	NOUN
eurjchem-2518	43	41	.	.	PUNCT
eurjchem-2518	44	1	the	the	DET
eurjchem-2518	44	2	result	result	NOUN
eurjchem-2518	44	3	of	of	ADP
eurjchem-2518	44	4	our	our	PRON
eurjchem-2518	44	5	research	research	NOUN
eurjchem-2518	44	6	was	be	AUX
eurjchem-2518	44	7	the	the	DET
eurjchem-2518	44	8	creation	creation	NOUN
eurjchem-2518	44	9	of	of	ADP
eurjchem-2518	44	10	a	a	DET
eurjchem-2518	44	11	concept	concept	NOUN
eurjchem-2518	44	12	on	on	ADP
eurjchem-2518	44	13	the	the	DET
eurjchem-2518	44	14	decisive	decisive	ADJ
eurjchem-2518	44	15	role	role	NOUN
eurjchem-2518	44	16	of	of	ADP
eurjchem-2518	44	17	solid	solid	ADJ
eurjchem-2518	44	18	catalysts	catalyst	NOUN
eurjchem-2518	44	19	in	in	ADP
eurjchem-2518	44	20	the	the	DET
eurjchem-2518	44	21	irreversible	irreversible	ADJ
eurjchem-2518	44	22	process	process	NOUN
eurjchem-2518	44	23	of	of	ADP
eurjchem-2518	44	24	low	low	ADJ
eurjchem-2518	44	25	-	-	PUNCT
eurjchem-2518	44	26	temperature	temperature	NOUN
eurjchem-2518	44	27	h2s	h2s	NOUN
eurjchem-2518	44	28	decomposition	decomposition	NOUN
eurjchem-2518	44	29	[	[	X
eurjchem-2518	44	30	10	10	NUM
eurjchem-2518	44	31	]	]	PUNCT
eurjchem-2518	44	32	.	.	PUNCT
eurjchem-2518	45	1	taking	take	VERB
eurjchem-2518	45	2	into	into	ADP
eurjchem-2518	45	3	account	account	NOUN
eurjchem-2518	45	4	the	the	DET
eurjchem-2518	45	5	exceptional	exceptional	ADJ
eurjchem-2518	45	6	practical	practical	ADJ
eurjchem-2518	45	7	and	and	CCONJ
eurjchem-2518	45	8	scientific	scientific	ADJ
eurjchem-2518	45	9	significance	significance	NOUN
eurjchem-2518	45	10	of	of	ADP
eurjchem-2518	45	11	this	this	DET
eurjchem-2518	45	12	concept	concept	NOUN
eurjchem-2518	45	13	,	,	PUNCT
eurjchem-2518	45	14	we	we	PRON
eurjchem-2518	45	15	have	have	AUX
eurjchem-2518	45	16	stated	state	VERB
eurjchem-2518	45	17	our	our	PRON
eurjchem-2518	45	18	claim	claim	NOUN
eurjchem-2518	45	19	to	to	PART
eurjchem-2518	45	20	replace	replace	VERB
eurjchem-2518	45	21	the	the	DET
eurjchem-2518	45	22	existing	exist	VERB
eurjchem-2518	45	23	paradigm	paradigm	NOUN
eurjchem-2518	45	24	of	of	ADP
eurjchem-2518	45	25	h2s	h2s	NOUN
eurjchem-2518	45	26	decomposition	decomposition	NOUN
eurjchem-2518	45	27	using	use	VERB
eurjchem-2518	45	28	external	external	ADJ
eurjchem-2518	45	29	energy	energy	NOUN
eurjchem-2518	45	30	sources	source	NOUN
eurjchem-2518	45	31	with	with	ADP
eurjchem-2518	45	32	a	a	DET
eurjchem-2518	45	33	new	new	ADJ
eurjchem-2518	45	34	paradigm	paradigm	NOUN
eurjchem-2518	45	35	of	of	ADP
eurjchem-2518	45	36	low	low	ADJ
eurjchem-2518	45	37	temperature	temperature	NOUN
eurjchem-2518	45	38	h2s	h2s	NOUN
eurjchem-2518	45	39	decomposition	decomposition	NOUN
eurjchem-2518	45	40	due	due	ADP
eurjchem-2518	45	41	to	to	ADP
eurjchem-2518	45	42	the	the	DET
eurjchem-2518	45	43	internal	internal	ADJ
eurjchem-2518	45	44	energy	energy	NOUN
eurjchem-2518	45	45	sources	source	NOUN
eurjchem-2518	45	46	accumulated	accumulate	VERB
eurjchem-2518	45	47	in	in	ADP
eurjchem-2518	45	48	the	the	DET
eurjchem-2518	45	49	chemical	chemical	ADJ
eurjchem-2518	45	50	bonds	bond	NOUN
eurjchem-2518	45	51	of	of	ADP
eurjchem-2518	45	52	h2s	h2s	NOUN
eurjchem-2518	45	53	molecules	molecule	NOUN
eurjchem-2518	45	54	[	[	X
eurjchem-2518	45	55	11	11	NUM
eurjchem-2518	45	56	]	]	PUNCT
eurjchem-2518	45	57	.	.	PUNCT
eurjchem-2518	46	1	experimental	experimental	ADJ
eurjchem-2518	46	2	details	detail	NOUN
eurjchem-2518	46	3	of	of	ADP
eurjchem-2518	46	4	our	our	PRON
eurjchem-2518	46	5	research	research	NOUN
eurjchem-2518	46	6	are	be	AUX
eurjchem-2518	46	7	summarized	summarize	VERB
eurjchem-2518	46	8	in	in	ADP
eurjchem-2518	46	9	[	[	X
eurjchem-2518	46	10	12	12	NUM
eurjchem-2518	46	11	]	]	PUNCT
eurjchem-2518	46	12	.	.	PUNCT
eurjchem-2518	47	1	in	in	ADP
eurjchem-2518	47	2	this	this	DET
eurjchem-2518	47	3	analytical	analytical	ADJ
eurjchem-2518	47	4	review	review	NOUN
eurjchem-2518	47	5	,	,	PUNCT
eurjchem-2518	47	6	we	we	PRON
eurjchem-2518	47	7	will	will	AUX
eurjchem-2518	47	8	try	try	VERB
eurjchem-2518	47	9	to	to	PART
eurjchem-2518	47	10	substantiate	substantiate	VERB
eurjchem-2518	47	11	the	the	DET
eurjchem-2518	47	12	thermodynamic	thermodynamic	ADJ
eurjchem-2518	47	13	possibility	possibility	NOUN
eurjchem-2518	47	14	of	of	ADP
eurjchem-2518	47	15	low	low	ADJ
eurjchem-2518	47	16	-	-	PUNCT
eurjchem-2518	47	17	temperature	temperature	NOUN
eurjchem-2518	47	18	h2s	h2s	NOUN
eurjchem-2518	47	19	decomposition	decomposition	NOUN
eurjchem-2518	47	20	on	on	ADP
eurjchem-2518	47	21	heterogeneous	heterogeneous	ADJ
eurjchem-2518	47	22	catalysts	catalyst	NOUN
eurjchem-2518	47	23	within	within	ADP
eurjchem-2518	47	24	the	the	DET
eurjchem-2518	47	25	framework	framework	NOUN
eurjchem-2518	47	26	of	of	ADP
eurjchem-2518	47	27	an	an	DET
eurjchem-2518	47	28	irreversible	irreversible	ADJ
eurjchem-2518	47	29	non	non	ADJ
eurjchem-2518	47	30	-	-	ADJ
eurjchem-2518	47	31	equilibrium	equilibrium	ADJ
eurjchem-2518	47	32	process	process	NOUN
eurjchem-2518	47	33	,	,	PUNCT
eurjchem-2518	47	34	by	by	ADP
eurjchem-2518	47	35	analogy	analogy	NOUN
eurjchem-2518	47	36	with	with	ADP
eurjchem-2518	47	37	chemosynthesis	chemosynthesis	NOUN
eurjchem-2518	47	38	implemented	implement	VERB
eurjchem-2518	47	39	in	in	ADP
eurjchem-2518	47	40	nature	nature	NOUN
eurjchem-2518	47	41	by	by	ADP
eurjchem-2518	47	42	enzymatic	enzymatic	ADJ
eurjchem-2518	47	43	catalysts	catalyst	NOUN
eurjchem-2518	47	44	of	of	ADP
eurjchem-2518	47	45	sulfur	sulfur	NOUN
eurjchem-2518	47	46	bacteria	bacteria	NOUN
eurjchem-2518	47	47	.	.	PUNCT
eurjchem-2518	48	1	the	the	DET
eurjchem-2518	48	2	main	main	ADJ
eurjchem-2518	48	3	purpose	purpose	NOUN
eurjchem-2518	48	4	of	of	ADP
eurjchem-2518	48	5	this	this	DET
eurjchem-2518	48	6	paper	paper	NOUN
eurjchem-2518	48	7	can	can	AUX
eurjchem-2518	48	8	be	be	AUX
eurjchem-2518	48	9	formulated	formulate	VERB
eurjchem-2518	48	10	as	as	SCONJ
eurjchem-2518	48	11	follows	follow	VERB
eurjchem-2518	48	12	:	:	PUNCT
eurjchem-2518	48	13	is	be	AUX
eurjchem-2518	48	14	it	it	PRON
eurjchem-2518	48	15	possible	possible	ADJ
eurjchem-2518	48	16	to	to	PART
eurjchem-2518	48	17	predict	predict	VERB
eurjchem-2518	48	18	the	the	DET
eurjchem-2518	48	19	catalytic	catalytic	ADJ
eurjchem-2518	48	20	activity	activity	NOUN
eurjchem-2518	48	21	of	of	ADP
eurjchem-2518	48	22	solid	solid	ADJ
eurjchem-2518	48	23	catalysts	catalyst	NOUN
eurjchem-2518	48	24	based	base	VERB
eurjchem-2518	48	25	on	on	ADP
eurjchem-2518	48	26	previously	previously	ADV
eurjchem-2518	48	27	published	publish	VERB
eurjchem-2518	48	28	numerous	numerous	ADJ
eurjchem-2518	48	29	experimental	experimental	ADJ
eurjchem-2518	48	30	and	and	CCONJ
eurjchem-2518	48	31	theoretical	theoretical	ADJ
eurjchem-2518	48	32	dft	dft	PROPN
eurjchem-2518	48	33	studies	study	NOUN
eurjchem-2518	48	34	of	of	ADP
eurjchem-2518	48	35	the	the	DET
eurjchem-2518	48	36	interaction	interaction	NOUN
eurjchem-2518	48	37	of	of	ADP
eurjchem-2518	48	38	an	an	DET
eurjchem-2518	48	39	h2s	h2s	NOUN
eurjchem-2518	48	40	molecule	molecule	NOUN
eurjchem-2518	48	41	with	with	ADP
eurjchem-2518	48	42	the	the	DET
eurjchem-2518	48	43	surface	surface	NOUN
eurjchem-2518	48	44	of	of	ADP
eurjchem-2518	48	45	solid	solid	ADJ
eurjchem-2518	48	46	catalysts	catalyst	NOUN
eurjchem-2518	48	47	using	use	VERB
eurjchem-2518	48	48	non	non	ADJ
eurjchem-2518	48	49	-	-	ADJ
eurjchem-2518	48	50	equilibrium	equilibrium	ADJ
eurjchem-2518	48	51	thermodynamics	thermodynamic	NOUN
eurjchem-2518	48	52	for	for	ADP
eurjchem-2518	48	53	this	this	DET
eurjchem-2518	48	54	purpose	purpose	NOUN
eurjchem-2518	48	55	?	?	PUNCT
eurjchem-2518	49	1	2	2	X
eurjchem-2518	49	2	.	.	X
eurjchem-2518	49	3	initial	initial	ADJ
eurjchem-2518	49	4	data	datum	NOUN
eurjchem-2518	49	5	for	for	ADP
eurjchem-2518	49	6	reflection	reflection	NOUN
eurjchem-2518	49	7	:	:	PUNCT
eurjchem-2518	49	8	sulfide	sulfide	NOUN
eurjchem-2518	49	9	catalysts	catalyst	NOUN
eurjchem-2518	49	10	this	this	DET
eurjchem-2518	49	11	story	story	NOUN
eurjchem-2518	49	12	began	begin	VERB
eurjchem-2518	49	13	at	at	ADP
eurjchem-2518	49	14	the	the	DET
eurjchem-2518	49	15	end	end	NOUN
eurjchem-2518	49	16	of	of	ADP
eurjchem-2518	49	17	the	the	DET
eurjchem-2518	49	18	twentieth	twentieth	ADJ
eurjchem-2518	49	19	century	century	NOUN
eurjchem-2518	49	20	,	,	PUNCT
eurjchem-2518	49	21	when	when	SCONJ
eurjchem-2518	49	22	we	we	PRON
eurjchem-2518	49	23	studied	study	VERB
eurjchem-2518	49	24	the	the	DET
eurjchem-2518	49	25	structure	structure	NOUN
eurjchem-2518	49	26	of	of	ADP
eurjchem-2518	49	27	the	the	DET
eurjchem-2518	49	28	active	active	ADJ
eurjchem-2518	49	29	component	component	NOUN
eurjchem-2518	49	30	and	and	CCONJ
eurjchem-2518	49	31	the	the	DET
eurjchem-2518	49	32	mechanism	mechanism	NOUN
eurjchem-2518	49	33	of	of	ADP
eurjchem-2518	49	34	action	action	NOUN
eurjchem-2518	49	35	of	of	ADP
eurjchem-2518	49	36	sulfide	sulfide	NOUN
eurjchem-2518	49	37	hydrodesulfurization	hydrodesulfurization	NOUN
eurjchem-2518	49	38	(	(	PUNCT
eurjchem-2518	49	39	hds	hds	PROPN
eurjchem-2518	49	40	)	)	PUNCT
eurjchem-2518	49	41	catalysts	catalyst	NOUN
eurjchem-2518	49	42	(	(	PUNCT
eurjchem-2518	49	43	figure	figure	NOUN
eurjchem-2518	49	44	1	1	NUM
eurjchem-2518	49	45	)	)	PUNCT
eurjchem-2518	50	1	[	[	X
eurjchem-2518	50	2	13,14	13,14	NUM
eurjchem-2518	50	3	]	]	PUNCT
eurjchem-2518	50	4	.	.	PUNCT
eurjchem-2518	51	1	according	accord	VERB
eurjchem-2518	51	2	to	to	ADP
eurjchem-2518	51	3	our	our	PRON
eurjchem-2518	51	4	view	view	NOUN
eurjchem-2518	51	5	[	[	X
eurjchem-2518	51	6	13,14	13,14	NUM
eurjchem-2518	51	7	]	]	PUNCT
eurjchem-2518	51	8	,	,	PUNCT
eurjchem-2518	51	9	the	the	DET
eurjchem-2518	51	10	active	active	ADJ
eurjchem-2518	51	11	centers	center	NOUN
eurjchem-2518	51	12	of	of	ADP
eurjchem-2518	51	13	the	the	DET
eurjchem-2518	51	14	sulfide	sulfide	NOUN
eurjchem-2518	51	15	catalysts	catalyst	NOUN
eurjchem-2518	51	16	are	be	AUX
eurjchem-2518	51	17	ni(iv	ni(iv	VERB
eurjchem-2518	51	18	)	)	PUNCT
eurjchem-2518	51	19	or	or	CCONJ
eurjchem-2518	51	20	co(iii	co(iii	NOUN
eurjchem-2518	51	21	)	)	PUNCT
eurjchem-2518	51	22	ions	ion	NOUN
eurjchem-2518	51	23	with	with	ADP
eurjchem-2518	51	24	a	a	DET
eurjchem-2518	51	25	d6	d6	ADJ
eurjchem-2518	51	26	electronic	electronic	ADJ
eurjchem-2518	51	27	configuration	configuration	NOUN
eurjchem-2518	51	28	(	(	PUNCT
eurjchem-2518	51	29	figure	figure	NOUN
eurjchem-2518	51	30	2	2	NUM
eurjchem-2518	51	31	)	)	PUNCT
eurjchem-2518	51	32	,	,	PUNCT
eurjchem-2518	51	33	which	which	PRON
eurjchem-2518	51	34	were	be	AUX
eurjchem-2518	51	35	formed	form	VERB
eurjchem-2518	51	36	as	as	ADP
eurjchem-2518	51	37	a	a	DET
eurjchem-2518	51	38	result	result	NOUN
eurjchem-2518	51	39	of	of	ADP
eurjchem-2518	51	40	the	the	DET
eurjchem-2518	51	41	oxidative	oxidative	ADJ
eurjchem-2518	51	42	addition	addition	NOUN
eurjchem-2518	51	43	of	of	ADP
eurjchem-2518	51	44	hydrogen	hydrogen	NOUN
eurjchem-2518	51	45	in	in	ADP
eurjchem-2518	51	46	the	the	DET
eurjchem-2518	51	47	process	process	NOUN
eurjchem-2518	51	48	of	of	ADP
eurjchem-2518	51	49	catalyst	catalyst	NOUN
eurjchem-2518	51	50	sulfiding	sulfiding	NOUN
eurjchem-2518	51	51	.	.	PUNCT
eurjchem-2518	52	1	this	this	DET
eurjchem-2518	52	2	occluded	occluded	ADJ
eurjchem-2518	52	3	hydrogen	hydrogen	NOUN
eurjchem-2518	52	4	is	be	AUX
eurjchem-2518	52	5	located	locate	VERB
eurjchem-2518	52	6	inside	inside	ADP
eurjchem-2518	52	7	the	the	DET
eurjchem-2518	52	8	active	active	ADJ
eurjchem-2518	52	9	component	component	NOUN
eurjchem-2518	52	10	in	in	ADP
eurjchem-2518	52	11	an	an	DET
eurjchem-2518	52	12	"	"	PUNCT
eurjchem-2518	52	13	empty	empty	ADJ
eurjchem-2518	52	14	"	"	PUNCT
eurjchem-2518	52	15	trigonal	trigonal	ADJ
eurjchem-2518	52	16	prism	prism	NOUN
eurjchem-2518	52	17	of	of	ADP
eurjchem-2518	52	18	six	six	NUM
eurjchem-2518	52	19	sulfur	sulfur	NOUN
eurjchem-2518	52	20	atoms	atom	NOUN
eurjchem-2518	52	21	(	(	PUNCT
eurjchem-2518	52	22	figure	figure	NOUN
eurjchem-2518	52	23	1	1	NUM
eurjchem-2518	52	24	)	)	PUNCT
eurjchem-2518	52	25	and	and	CCONJ
eurjchem-2518	52	26	stabilizes	stabilize	VERB
eurjchem-2518	52	27	an	an	DET
eurjchem-2518	52	28	unusually	unusually	ADV
eurjchem-2518	52	29	high	high	ADJ
eurjchem-2518	52	30	oxidation	oxidation	NOUN
eurjchem-2518	52	31	state	state	NOUN
eurjchem-2518	52	32	of	of	ADP
eurjchem-2518	52	33	the	the	DET
eurjchem-2518	52	34	188	188	NUM
eurjchem-2518	52	35	anatolii	anatolii	NOUN
eurjchem-2518	52	36	startsev	startsev	NOUN
eurjchem-2518	52	37	/	/	SYM
eurjchem-2518	52	38	european	european	ADJ
eurjchem-2518	52	39	journal	journal	PROPN
eurjchem-2518	52	40	of	of	ADP
eurjchem-2518	52	41	chemistry	chemistry	NOUN
eurjchem-2518	52	42	15	15	NUM
eurjchem-2518	52	43	(	(	PUNCT
eurjchem-2518	52	44	2	2	NUM
eurjchem-2518	52	45	)	)	PUNCT
eurjchem-2518	52	46	(	(	PUNCT
eurjchem-2518	52	47	2024	2024	NUM
eurjchem-2518	52	48	)	)	PUNCT
eurjchem-2518	52	49	186	186	NUM
eurjchem-2518	52	50	-	-	SYM
eurjchem-2518	52	51	193	193	NUM
eurjchem-2518	52	52	2024	2024	NUM
eurjchem-2518	52	53	–	–	PUNCT
eurjchem-2518	52	54	european	european	ADJ
eurjchem-2518	52	55	journal	journal	NOUN
eurjchem-2518	52	56	of	of	ADP
eurjchem-2518	52	57	chemistry	chemistry	NOUN
eurjchem-2518	52	58	–	–	PUNCT
eurjchem-2518	52	59	cc	cc	NOUN
eurjchem-2518	52	60	by	by	ADP
eurjchem-2518	52	61	nc	nc	PROPN
eurjchem-2518	52	62	–	–	PUNCT
eurjchem-2518	52	63	doi	doi	NOUN
eurjchem-2518	52	64	:	:	PUNCT
eurjchem-2518	52	65	10.5155	10.5155	NUM
eurjchem-2518	52	66	/	/	SYM
eurjchem-2518	52	67	eurjchem.15.2.186	eurjchem.15.2.186	VERB
eurjchem-2518	52	68	-	-	PUNCT
eurjchem-2518	52	69	193.2518	193.2518	NUM
eurjchem-2518	52	70	table	table	NOUN
eurjchem-2518	52	71	1	1	NUM
eurjchem-2518	52	72	.	.	PUNCT
eurjchem-2518	53	1	dft	dft	PROPN
eurjchem-2518	53	2	calculations	calculation	NOUN
eurjchem-2518	53	3	of	of	ADP
eurjchem-2518	53	4	the	the	DET
eurjchem-2518	53	5	thermodynamic	thermodynamic	ADJ
eurjchem-2518	53	6	parameters	parameter	NOUN
eurjchem-2518	53	7	of	of	ADP
eurjchem-2518	53	8	sequential	sequential	ADJ
eurjchem-2518	53	9	stages	stage	NOUN
eurjchem-2518	53	10	of	of	ADP
eurjchem-2518	53	11	catalytic	catalytic	ADJ
eurjchem-2518	53	12	h2s	h2s	NOUN
eurjchem-2518	53	13	decomposition	decomposition	NOUN
eurjchem-2518	53	14	at	at	ADP
eurjchem-2518	53	15	room	room	NOUN
eurjchem-2518	53	16	temperature	temperature	NOUN
eurjchem-2518	53	17	[	[	X
eurjchem-2518	53	18	13,14	13,14	NUM
eurjchem-2518	53	19	]	]	PUNCT
eurjchem-2518	53	20	.	.	PUNCT
eurjchem-2518	54	1	m	m	VERB
eurjchem-2518	54	2	=	=	PUNCT
eurjchem-2518	55	1	co3	co3	ADJ
eurjchem-2518	55	2	+	+	NOUN
eurjchem-2518	55	3	or	or	CCONJ
eurjchem-2518	55	4	ni4	ni4	NOUN
eurjchem-2518	55	5	+	+	CCONJ
eurjchem-2518	55	6	metal	metal	NOUN
eurjchem-2518	55	7	ions	ion	NOUN
eurjchem-2518	55	8	in	in	ADP
eurjchem-2518	55	9	the	the	DET
eurjchem-2518	55	10	d6	d6	NOUN
eurjchem-2518	55	11	electron	electron	NOUN
eurjchem-2518	55	12	configuration	configuration	NOUN
eurjchem-2518	55	13	,	,	PUNCT
eurjchem-2518	55	14	which	which	PRON
eurjchem-2518	55	15	are	be	AUX
eurjchem-2518	55	16	the	the	DET
eurjchem-2518	55	17	lewis	lewis	PROPN
eurjchem-2518	55	18	active	active	ADJ
eurjchem-2518	55	19	centers	center	NOUN
eurjchem-2518	55	20	in	in	ADP
eurjchem-2518	55	21	the	the	DET
eurjchem-2518	55	22	active	active	ADJ
eurjchem-2518	55	23	component	component	NOUN
eurjchem-2518	55	24	of	of	ADP
eurjchem-2518	55	25	the	the	DET
eurjchem-2518	55	26	sulfide	sulfide	NOUN
eurjchem-2518	55	27	hds	hds	PROPN
eurjchem-2518	55	28	catalysts	catalyst	VERB
eurjchem-2518	55	29	[	[	X
eurjchem-2518	55	30	10	10	NUM
eurjchem-2518	55	31	-	-	SYM
eurjchem-2518	55	32	12	12	NUM
eurjchem-2518	55	33	]	]	PUNCT
eurjchem-2518	55	34	.	.	PUNCT
eurjchem-2518	56	1	stage	stage	NOUN
eurjchem-2518	56	2	reaction	reaction	PROPN
eurjchem-2518	56	3	∆h298	∆h298	PROPN
eurjchem-2518	56	4	,	,	PUNCT
eurjchem-2518	56	5	kcal	kcal	PROPN
eurjchem-2518	56	6	/	/	SYM
eurjchem-2518	56	7	mol	mol	NUM
eurjchem-2518	56	8	∆s	∆s	PROPN
eurjchem-2518	56	9	298	298	NUM
eurjchem-2518	56	10	,	,	PUNCT
eurjchem-2518	56	11	cal	cal	PROPN
eurjchem-2518	56	12	/	/	SYM
eurjchem-2518	56	13	mol.k	mol.k	PROPN
eurjchem-2518	56	14	t∆s	t∆s	NOUN
eurjchem-2518	56	15	*	*	NOUN
eurjchem-2518	56	16	,	,	PUNCT
eurjchem-2518	56	17	kcal	kcal	PROPN
eurjchem-2518	56	18	/	/	SYM
eurjchem-2518	56	19	mol	mol	ADP
eurjchem-2518	56	20	∆g298	∆g298	PROPN
eurjchem-2518	56	21	,	,	PUNCT
eurjchem-2518	56	22	kcal	kcal	PROPN
eurjchem-2518	56	23	/	/	SYM
eurjchem-2518	56	24	mol	mol	ADP
eurjchem-2518	56	25	i	i	PRON
eurjchem-2518	56	26	molecular	molecular	ADJ
eurjchem-2518	56	27	adsorption	adsorption	NOUN
eurjchem-2518	56	28	2	2	NUM
eurjchem-2518	56	29	m	m	NOUN
eurjchem-2518	56	30	+	+	NOUN
eurjchem-2518	56	31	2	2	NUM
eurjchem-2518	56	32	h2s(gas	h2s(gas	NOUN
eurjchem-2518	56	33	)	)	PUNCT
eurjchem-2518	56	34	→	→	SYM
eurjchem-2518	56	35	2	2	NUM
eurjchem-2518	56	36	(	(	PUNCT
eurjchem-2518	56	37	m	m	PROPN
eurjchem-2518	56	38	–	–	PUNCT
eurjchem-2518	56	39	h2s)(ads	h2s)(ad	NOUN
eurjchem-2518	56	40	)	)	PUNCT
eurjchem-2518	56	41	–	–	PUNCT
eurjchem-2518	56	42	12.7	12.7	NUM
eurjchem-2518	56	43	–	–	PUNCT
eurjchem-2518	56	44	39.6	39.6	NUM
eurjchem-2518	56	45	–	–	PUNCT
eurjchem-2518	56	46	11.8	11.8	NUM
eurjchem-2518	56	47	–	–	PUNCT
eurjchem-2518	56	48	0.9	0.9	NUM
eurjchem-2518	56	49	ii	ii	NUM
eurjchem-2518	56	50	dissociative	dissociative	ADJ
eurjchem-2518	56	51	chemisorption	chemisorption	NOUN
eurjchem-2518	56	52	2	2	NUM
eurjchem-2518	56	53	(	(	PUNCT
eurjchem-2518	56	54	m	m	PROPN
eurjchem-2518	56	55	–	–	PUNCT
eurjchem-2518	56	56	h2s)(ads	h2s)(ad	NOUN
eurjchem-2518	56	57	)	)	PUNCT
eurjchem-2518	56	58	→2	→2	PUNCT
eurjchem-2518	56	59	(	(	PUNCT
eurjchem-2518	56	60	m	m	NOUN
eurjchem-2518	56	61	–	–	PUNCT
eurjchem-2518	56	62	sh)(ads	sh)(ad	VERB
eurjchem-2518	56	63	)	)	PUNCT
eurjchem-2518	56	64	+	+	CCONJ
eurjchem-2518	56	65	2	2	NUM
eurjchem-2518	56	66	h(ads	h(ad	NOUN
eurjchem-2518	56	67	)	)	PUNCT
eurjchem-2518	56	68	–	–	PUNCT
eurjchem-2518	56	69	16.0	16.0	NUM
eurjchem-2518	56	70	+2.2	+2.2	NOUN
eurjchem-2518	56	71	+0.7	+0.7	NUM
eurjchem-2518	56	72	–	–	PUNCT
eurjchem-2518	56	73	16.6	16.6	NUM
eurjchem-2518	56	74	iii	iii	NUM
eurjchem-2518	56	75	the	the	DET
eurjchem-2518	56	76	removal	removal	NOUN
eurjchem-2518	56	77	of	of	ADP
eurjchem-2518	56	78	the	the	DET
eurjchem-2518	56	79	first	first	ADJ
eurjchem-2518	56	80	hydrogen	hydrogen	NOUN
eurjchem-2518	56	81	molecule	molecule	NOUN
eurjchem-2518	56	82	2	2	NUM
eurjchem-2518	56	83	(	(	PUNCT
eurjchem-2518	56	84	m	m	PROPN
eurjchem-2518	56	85	–	–	PUNCT
eurjchem-2518	56	86	sh)(ads	sh)(ad	VERB
eurjchem-2518	56	87	)	)	PUNCT
eurjchem-2518	56	88	+	+	CCONJ
eurjchem-2518	56	89	2	2	NUM
eurjchem-2518	56	90	h(ads	h(ad	NOUN
eurjchem-2518	56	91	)	)	PUNCT
eurjchem-2518	56	92	→	→	SYM
eurjchem-2518	56	93	2	2	NUM
eurjchem-2518	56	94	m	m	NOUN
eurjchem-2518	56	95	–	–	PUNCT
eurjchem-2518	56	96	(	(	PUNCT
eurjchem-2518	56	97	µ-s2)(ads	µ-s2)(ad	NOUN
eurjchem-2518	56	98	)	)	PUNCT
eurjchem-2518	56	99	+	+	CCONJ
eurjchem-2518	56	100	2	2	NUM
eurjchem-2518	56	101	h(ads	h(ad	NOUN
eurjchem-2518	56	102	)	)	PUNCT
eurjchem-2518	56	103	+	+	CCONJ
eurjchem-2518	56	104	h2(gas	h2(gas	X
eurjchem-2518	56	105	)	)	PUNCT
eurjchem-2518	56	106	↑	↑	NOUN
eurjchem-2518	56	107	–	–	PUNCT
eurjchem-2518	56	108	0.2	0.2	NUM
eurjchem-2518	56	109	–	–	PUNCT
eurjchem-2518	56	110	21.9	21.9	NUM
eurjchem-2518	56	111	–	–	PUNCT
eurjchem-2518	56	112	6.5	6.5	NUM
eurjchem-2518	56	113	+6.3	+6.3	NUM
eurjchem-2518	56	114	iv	iv	ADP
eurjchem-2518	56	115	the	the	DET
eurjchem-2518	56	116	removal	removal	NOUN
eurjchem-2518	56	117	of	of	ADP
eurjchem-2518	56	118	the	the	DET
eurjchem-2518	56	119	second	second	ADJ
eurjchem-2518	56	120	hydrogen	hydrogen	NOUN
eurjchem-2518	56	121	molecule	molecule	NOUN
eurjchem-2518	56	122	2	2	NUM
eurjchem-2518	56	123	m	m	NOUN
eurjchem-2518	56	124	–	–	PUNCT
eurjchem-2518	56	125	(	(	PUNCT
eurjchem-2518	56	126	µ-s2)(ads	µ-s2)(ad	NOUN
eurjchem-2518	56	127	)	)	PUNCT
eurjchem-2518	56	128	+	+	CCONJ
eurjchem-2518	56	129	2	2	NUM
eurjchem-2518	56	130	h(ads	h(ad	NOUN
eurjchem-2518	56	131	)	)	PUNCT
eurjchem-2518	56	132	→	→	SYM
eurjchem-2518	56	133	2	2	NUM
eurjchem-2518	56	134	m	m	NOUN
eurjchem-2518	56	135	–	–	PUNCT
eurjchem-2518	56	136	(	(	PUNCT
eurjchem-2518	56	137	µ-s2)(ads	µ-s2)(ad	NOUN
eurjchem-2518	56	138	)	)	PUNCT
eurjchem-2518	56	139	+	+	CCONJ
eurjchem-2518	56	140	h2(gas	h2(gas	X
eurjchem-2518	56	141	)	)	PUNCT
eurjchem-2518	56	142	↑	↑	NOUN
eurjchem-2518	57	1	+25.5	+25.5	NOUN
eurjchem-2518	58	1	+35.1	+35.1	PROPN
eurjchem-2518	58	2	+10.5	+10.5	PRON
eurjchem-2518	58	3	+15.0	+15.0	NUM
eurjchem-2518	58	4	v	v	NUM
eurjchem-2518	58	5	recombination	recombination	NOUN
eurjchem-2518	58	6	2	2	NUM
eurjchem-2518	58	7	m	m	NOUN
eurjchem-2518	58	8	–	–	PUNCT
eurjchem-2518	58	9	(	(	PUNCT
eurjchem-2518	58	10	µ-s2)(ads	µ-s2)(ad	NOUN
eurjchem-2518	58	11	)	)	PUNCT
eurjchem-2518	58	12	→	→	SYM
eurjchem-2518	58	13	2	2	NUM
eurjchem-2518	58	14	m	m	NOUN
eurjchem-2518	58	15	+	+	CCONJ
eurjchem-2518	58	16	¼	¼	NOUN
eurjchem-2518	58	17	s8(ads	s8(ad	NOUN
eurjchem-2518	58	18	)	)	PUNCT
eurjchem-2518	58	19	–	–	PUNCT
eurjchem-2518	58	20	19.6	19.6	NUM
eurjchem-2518	58	21	–	–	PUNCT
eurjchem-2518	58	22	29.0	29.0	NUM
eurjchem-2518	58	23	–	–	PUNCT
eurjchem-2518	58	24	8.6	8.6	NUM
eurjchem-2518	58	25	–	–	PUNCT
eurjchem-2518	58	26	11.0	11.0	NUM
eurjchem-2518	58	27	overall	overall	ADJ
eurjchem-2518	58	28	catalytic	catalytic	ADJ
eurjchem-2518	58	29	reaction	reaction	NOUN
eurjchem-2518	58	30	2	2	NUM
eurjchem-2518	58	31	h2s(gas	h2s(gas	NOUN
eurjchem-2518	58	32	)	)	PUNCT
eurjchem-2518	58	33	→	→	SYM
eurjchem-2518	58	34	2	2	NUM
eurjchem-2518	58	35	h2(gas	h2(gas	NOUN
eurjchem-2518	58	36	)	)	PUNCT
eurjchem-2518	58	37	↑	↑	NOUN
eurjchem-2518	58	38	+	+	CCONJ
eurjchem-2518	58	39	¼	¼	NOUN
eurjchem-2518	58	40	s8(ads	s8(ad	NOUN
eurjchem-2518	58	41	)	)	PUNCT
eurjchem-2518	58	42	–	–	PUNCT
eurjchem-2518	58	43	23.0	23.0	NUM
eurjchem-2518	58	44	–	–	PUNCT
eurjchem-2518	58	45	53.2	53.2	NUM
eurjchem-2518	58	46	–	–	PUNCT
eurjchem-2518	58	47	15.9	15.9	NUM
eurjchem-2518	58	48	–	–	SYM
eurjchem-2518	58	49	7.2	7.2	NUM
eurjchem-2518	58	50	gas	gas	NOUN
eurjchem-2518	58	51	phase	phase	NOUN
eurjchem-2518	58	52	2	2	NUM
eurjchem-2518	58	53	h2s(gas	h2s(gas	NOUN
eurjchem-2518	58	54	)	)	PUNCT
eurjchem-2518	58	55	→	→	SYM
eurjchem-2518	58	56	2	2	NUM
eurjchem-2518	58	57	h2(gas	h2(gas	NOUN
eurjchem-2518	58	58	)	)	PUNCT
eurjchem-2518	58	59	↑+	↑+	VERB
eurjchem-2518	58	60	¼	¼	NOUN
eurjchem-2518	58	61	s8(solid	s8(solid	NOUN
eurjchem-2518	58	62	)	)	PUNCT
eurjchem-2518	58	63	+4.9	+4.9	NUM
eurjchem-2518	58	64	–	–	PUNCT
eurjchem-2518	59	1	17.1	17.1	NUM
eurjchem-2518	59	2	+10.0	+10.0	PROPN
eurjchem-2518	59	3	*	*	PUNCT
eurjchem-2518	59	4	–	–	PUNCT
eurjchem-2518	59	5	the	the	DET
eurjchem-2518	59	6	bound	bind	VERB
eurjchem-2518	59	7	(	(	PUNCT
eurjchem-2518	59	8	waste	waste	NOUN
eurjchem-2518	59	9	,	,	PUNCT
eurjchem-2518	59	10	lost	lost	ADJ
eurjchem-2518	59	11	)	)	PUNCT
eurjchem-2518	59	12	energy	energy	NOUN
eurjchem-2518	59	13	t∆s	t∆s	NOUN
eurjchem-2518	59	14	,	,	PUNCT
eurjchem-2518	59	15	which	which	PRON
eurjchem-2518	59	16	is	be	AUX
eurjchem-2518	59	17	dissipated	dissipate	VERB
eurjchem-2518	59	18	into	into	ADP
eurjchem-2518	59	19	the	the	DET
eurjchem-2518	59	20	environment	environment	NOUN
eurjchem-2518	59	21	,	,	PUNCT
eurjchem-2518	59	22	therefore	therefore	ADV
eurjchem-2518	59	23	it	it	PRON
eurjchem-2518	59	24	can	can	AUX
eurjchem-2518	59	25	not	not	PART
eurjchem-2518	59	26	be	be	AUX
eurjchem-2518	59	27	used	use	VERB
eurjchem-2518	59	28	to	to	PART
eurjchem-2518	59	29	make	make	VERB
eurjchem-2518	59	30	useful	useful	ADJ
eurjchem-2518	59	31	action	action	NOUN
eurjchem-2518	59	32	(	(	PUNCT
eurjchem-2518	59	33	chemical	chemical	NOUN
eurjchem-2518	59	34	efficiency	efficiency	NOUN
eurjchem-2518	59	35	in	in	ADP
eurjchem-2518	59	36	the	the	DET
eurjchem-2518	59	37	generation	generation	NOUN
eurjchem-2518	59	38	of	of	ADP
eurjchem-2518	59	39	target	target	NOUN
eurjchem-2518	59	40	products	product	NOUN
eurjchem-2518	59	41	)	)	PUNCT
eurjchem-2518	59	42	.	.	PUNCT
eurjchem-2518	60	1	figure	figure	VERB
eurjchem-2518	60	2	4	4	NUM
eurjchem-2518	60	3	.	.	PUNCT
eurjchem-2518	61	1	structure	structure	NOUN
eurjchem-2518	61	2	of	of	ADP
eurjchem-2518	61	3	the	the	DET
eurjchem-2518	61	4	key	key	ADJ
eurjchem-2518	61	5	surface	surface	NOUN
eurjchem-2518	61	6	intermediate	intermediate	ADJ
eurjchem-2518	61	7	obtained	obtain	VERB
eurjchem-2518	61	8	as	as	ADP
eurjchem-2518	61	9	a	a	DET
eurjchem-2518	61	10	result	result	NOUN
eurjchem-2518	61	11	of	of	ADP
eurjchem-2518	61	12	the	the	DET
eurjchem-2518	61	13	coupling	coupling	NOUN
eurjchem-2518	61	14	of	of	ADP
eurjchem-2518	61	15	adsorbed	adsorb	VERB
eurjchem-2518	61	16	h2s	h2s	NOUN
eurjchem-2518	61	17	molecules	molecule	NOUN
eurjchem-2518	61	18	and	and	CCONJ
eurjchem-2518	61	19	the	the	DET
eurjchem-2518	61	20	removal	removal	NOUN
eurjchem-2518	61	21	of	of	ADP
eurjchem-2518	61	22	molecular	molecular	ADJ
eurjchem-2518	61	23	hydrogen	hydrogen	NOUN
eurjchem-2518	61	24	in	in	ADP
eurjchem-2518	61	25	the	the	DET
eurjchem-2518	61	26	gas	gas	NOUN
eurjchem-2518	61	27	phase	phase	NOUN
eurjchem-2518	61	28	[	[	X
eurjchem-2518	61	29	10,11	10,11	NOUN
eurjchem-2518	61	30	]	]	PUNCT
eurjchem-2518	61	31	.	.	PUNCT
eurjchem-2518	62	1	active	active	ADJ
eurjchem-2518	62	2	metal	metal	NOUN
eurjchem-2518	62	3	atom	atom	NOUN
eurjchem-2518	62	4	,	,	PUNCT
eurjchem-2518	62	5	preventing	prevent	VERB
eurjchem-2518	62	6	its	its	PRON
eurjchem-2518	62	7	reduction	reduction	NOUN
eurjchem-2518	62	8	under	under	ADP
eurjchem-2518	62	9	catalysis	catalysis	NOUN
eurjchem-2518	62	10	conditions	condition	NOUN
eurjchem-2518	62	11	.	.	PUNCT
eurjchem-2518	63	1	figure	figure	NOUN
eurjchem-2518	63	2	3	3	NUM
eurjchem-2518	63	3	shows	show	VERB
eurjchem-2518	63	4	a	a	DET
eurjchem-2518	63	5	fragment	fragment	NOUN
eurjchem-2518	63	6	of	of	ADP
eurjchem-2518	63	7	the	the	DET
eurjchem-2518	63	8	active	active	ADJ
eurjchem-2518	63	9	component	component	NOUN
eurjchem-2518	63	10	with	with	ADP
eurjchem-2518	63	11	two	two	NUM
eurjchem-2518	63	12	adsorbed	adsorb	VERB
eurjchem-2518	63	13	h2s	h2s	NOUN
eurjchem-2518	63	14	molecules	molecule	NOUN
eurjchem-2518	63	15	on	on	ADP
eurjchem-2518	63	16	two	two	NUM
eurjchem-2518	63	17	adjacent	adjacent	ADJ
eurjchem-2518	63	18	atoms	atom	NOUN
eurjchem-2518	63	19	of	of	ADP
eurjchem-2518	63	20	the	the	DET
eurjchem-2518	63	21	active	active	ADJ
eurjchem-2518	63	22	center	center	NOUN
eurjchem-2518	63	23	.	.	PUNCT
eurjchem-2518	64	1	after	after	ADP
eurjchem-2518	64	2	h2s	h2s	NOUN
eurjchem-2518	64	3	adsorption	adsorption	NOUN
eurjchem-2518	64	4	on	on	ADP
eurjchem-2518	64	5	the	the	DET
eurjchem-2518	64	6	surface	surface	NOUN
eurjchem-2518	64	7	of	of	ADP
eurjchem-2518	64	8	sulfide	sulfide	NOUN
eurjchem-2518	64	9	catalysts	catalyst	NOUN
eurjchem-2518	64	10	at	at	ADP
eurjchem-2518	64	11	room	room	NOUN
eurjchem-2518	64	12	temperature	temperature	NOUN
eurjchem-2518	64	13	,	,	PUNCT
eurjchem-2518	64	14	we	we	PRON
eurjchem-2518	64	15	observed	observe	VERB
eurjchem-2518	64	16	a	a	DET
eurjchem-2518	64	17	stoichiometric	stoichiometric	ADJ
eurjchem-2518	64	18	reaction	reaction	NOUN
eurjchem-2518	64	19	of	of	ADP
eurjchem-2518	64	20	hydrogen	hydrogen	NOUN
eurjchem-2518	64	21	release	release	NOUN
eurjchem-2518	64	22	into	into	ADP
eurjchem-2518	64	23	the	the	DET
eurjchem-2518	64	24	gas	gas	NOUN
eurjchem-2518	64	25	phase	phase	NOUN
eurjchem-2518	64	26	by	by	ADP
eurjchem-2518	64	27	reaction	reaction	NOUN
eurjchem-2518	64	28	1	1	NUM
eurjchem-2518	64	29	:	:	SYM
eurjchem-2518	64	30	2	2	NUM
eurjchem-2518	64	31	h2s	h2s	NOUN
eurjchem-2518	64	32	(	(	PUNCT
eurjchem-2518	64	33	h2s2)ads	h2s2)ad	NOUN
eurjchem-2518	64	34	h2	h2	NOUN
eurjchem-2518	64	35	(	(	PUNCT
eurjchem-2518	64	36	g	g	NOUN
eurjchem-2518	64	37	)	)	PUNCT
eurjchem-2518	64	38	sulfide	sulfide	NOUN
eurjchem-2518	64	39	catalyst	catalyst	NOUN
eurjchem-2518	64	40	,	,	PUNCT
eurjchem-2518	64	41	25	25	NUM
eurjchem-2518	64	42	oc	oc	NOUN
eurjchem-2518	64	43	(	(	PUNCT
eurjchem-2518	64	44	1	1	NUM
eurjchem-2518	64	45	)	)	PUNCT
eurjchem-2518	64	46	which	which	PRON
eurjchem-2518	64	47	results	result	VERB
eurjchem-2518	64	48	from	from	ADP
eurjchem-2518	64	49	the	the	DET
eurjchem-2518	64	50	formation	formation	NOUN
eurjchem-2518	64	51	of	of	ADP
eurjchem-2518	64	52	disulfane	disulfane	PROPN
eurjchem-2518	64	53	h2s2	h2s2	PROPN
eurjchem-2518	64	54	(	(	PUNCT
eurjchem-2518	64	55	hydrogen	hydrogen	NOUN
eurjchem-2518	64	56	disulfide	disulfide	NOUN
eurjchem-2518	64	57	)	)	PUNCT
eurjchem-2518	64	58	(	(	PUNCT
eurjchem-2518	64	59	figure	figure	NOUN
eurjchem-2518	64	60	4	4	NUM
eurjchem-2518	64	61	)	)	PUNCT
eurjchem-2518	64	62	.	.	PUNCT
eurjchem-2518	65	1	the	the	DET
eurjchem-2518	65	2	problem	problem	NOUN
eurjchem-2518	65	3	is	be	AUX
eurjchem-2518	65	4	that	that	SCONJ
eurjchem-2518	65	5	the	the	DET
eurjchem-2518	65	6	direct	direct	ADJ
eurjchem-2518	65	7	formation	formation	NOUN
eurjchem-2518	65	8	of	of	ADP
eurjchem-2518	65	9	disulfane	disulfane	PROPN
eurjchem-2518	65	10	h2s2	h2s2	PROPN
eurjchem-2518	65	11	from	from	ADP
eurjchem-2518	65	12	h2s	h2s	PROPN
eurjchem-2518	65	13	in	in	ADP
eurjchem-2518	65	14	the	the	DET
eurjchem-2518	65	15	gas	gas	NOUN
eurjchem-2518	65	16	phase	phase	NOUN
eurjchem-2518	65	17	(	(	PUNCT
eurjchem-2518	65	18	reaction	reaction	NOUN
eurjchem-2518	65	19	2	2	NUM
eurjchem-2518	65	20	):	):	PUNCT
eurjchem-2518	65	21	2	2	NUM
eurjchem-2518	65	22	h2s	h2s	NOUN
eurjchem-2518	65	23	h2h2s2	h2h2s2	NOUN
eurjchem-2518	65	24	(	(	PUNCT
eurjchem-2518	65	25	2	2	NUM
eurjchem-2518	65	26	)	)	PUNCT
eurjchem-2518	65	27	is	be	AUX
eurjchem-2518	65	28	impossible	impossible	ADJ
eurjchem-2518	65	29	because	because	SCONJ
eurjchem-2518	65	30	of	of	ADP
eurjchem-2518	65	31	prohibition	prohibition	NOUN
eurjchem-2518	65	32	by	by	ADP
eurjchem-2518	65	33	the	the	DET
eurjchem-2518	65	34	equilibrium	equilibrium	NOUN
eurjchem-2518	65	35	thermodynamics	thermodynamic	NOUN
eurjchem-2518	65	36	(	(	PUNCT
eurjchem-2518	65	37	∆rho298	∆rho298	PUNCT
eurjchem-2518	65	38	=	=	SYM
eurjchem-2518	65	39	+13.6	+13.6	PROPN
eurjchem-2518	65	40	kcal	kcal	PROPN
eurjchem-2518	65	41	/	/	SYM
eurjchem-2518	65	42	mol	mol	PROPN
eurjchem-2518	65	43	,	,	PUNCT
eurjchem-2518	65	44	∆rso298	∆rso298	PRON
eurjchem-2518	65	45	=	=	SYM
eurjchem-2518	65	46	-3.9	-3.9	NOUN
eurjchem-2518	65	47	cal	cal	PROPN
eurjchem-2518	65	48	/	/	SYM
eurjchem-2518	65	49	mol×k	mol×k	PROPN
eurjchem-2518	65	50	,	,	PUNCT
eurjchem-2518	65	51	∆rgo298	∆rgo298	X
eurjchem-2518	65	52	=	=	SYM
eurjchem-2518	65	53	+14.1	+14.1	PROPN
eurjchem-2518	65	54	kcal	kcal	PROPN
eurjchem-2518	65	55	/	/	SYM
eurjchem-2518	65	56	mol	mol	PROPN
eurjchem-2518	65	57	)	)	PUNCT
eurjchem-2518	65	58	.	.	PUNCT
eurjchem-2518	66	1	thus	thus	ADV
eurjchem-2518	66	2	,	,	PUNCT
eurjchem-2518	66	3	we	we	PRON
eurjchem-2518	66	4	have	have	AUX
eurjchem-2518	66	5	shown	show	VERB
eurjchem-2518	66	6	for	for	ADP
eurjchem-2518	66	7	the	the	DET
eurjchem-2518	66	8	first	first	ADJ
eurjchem-2518	66	9	time	time	NOUN
eurjchem-2518	66	10	that	that	SCONJ
eurjchem-2518	66	11	a	a	DET
eurjchem-2518	66	12	solid	solid	ADJ
eurjchem-2518	66	13	catalyst	catalyst	NOUN
eurjchem-2518	66	14	performs	perform	VERB
eurjchem-2518	66	15	a	a	DET
eurjchem-2518	66	16	very	very	ADV
eurjchem-2518	66	17	specific	specific	ADJ
eurjchem-2518	66	18	function	function	NOUN
eurjchem-2518	66	19	a	a	DET
eurjchem-2518	66	20	process	process	NOUN
eurjchem-2518	66	21	thermodynamically	thermodynamically	ADV
eurjchem-2518	66	22	forbidden	forbid	VERB
eurjchem-2518	66	23	in	in	ADP
eurjchem-2518	66	24	the	the	DET
eurjchem-2518	66	25	gas	gas	NOUN
eurjchem-2518	66	26	phase	phase	NOUN
eurjchem-2518	66	27	is	be	AUX
eurjchem-2518	66	28	realized	realize	VERB
eurjchem-2518	66	29	on	on	ADP
eurjchem-2518	66	30	the	the	DET
eurjchem-2518	66	31	catalyst	catalyst	NOUN
eurjchem-2518	66	32	surface	surface	NOUN
eurjchem-2518	67	1	[	[	X
eurjchem-2518	67	2	10,11	10,11	NOUN
eurjchem-2518	67	3	]	]	PUNCT
eurjchem-2518	67	4	.	.	PUNCT
eurjchem-2518	68	1	this	this	PRON
eurjchem-2518	68	2	became	become	VERB
eurjchem-2518	68	3	possible	possible	ADJ
eurjchem-2518	68	4	due	due	ADP
eurjchem-2518	68	5	to	to	ADP
eurjchem-2518	68	6	the	the	DET
eurjchem-2518	68	7	interaction	interaction	NOUN
eurjchem-2518	68	8	(	(	PUNCT
eurjchem-2518	68	9	coupling	coupling	NOUN
eurjchem-2518	68	10	)	)	PUNCT
eurjchem-2518	68	11	of	of	ADP
eurjchem-2518	68	12	two	two	NUM
eurjchem-2518	68	13	h2s	h2s	NOUN
eurjchem-2518	68	14	molecules	molecule	NOUN
eurjchem-2518	68	15	adsorbed	adsorb	VERB
eurjchem-2518	68	16	on	on	ADP
eurjchem-2518	68	17	neighboring	neighboring	NOUN
eurjchem-2518	68	18	atoms	atom	NOUN
eurjchem-2518	68	19	of	of	ADP
eurjchem-2518	68	20	the	the	DET
eurjchem-2518	68	21	active	active	ADJ
eurjchem-2518	68	22	centers	center	NOUN
eurjchem-2518	68	23	(	(	PUNCT
eurjchem-2518	68	24	ni	ni	PROPN
eurjchem-2518	68	25	or	or	CCONJ
eurjchem-2518	68	26	co	co	ADJ
eurjchem-2518	68	27	in	in	ADP
eurjchem-2518	68	28	d6	d6	NOUN
eurjchem-2518	68	29	electronic	electronic	ADJ
eurjchem-2518	68	30	configuration	configuration	NOUN
eurjchem-2518	68	31	)	)	PUNCT
eurjchem-2518	68	32	of	of	ADP
eurjchem-2518	68	33	the	the	DET
eurjchem-2518	68	34	sulfide	sulfide	NOUN
eurjchem-2518	68	35	catalysts	catalyst	NOUN
eurjchem-2518	68	36	(	(	PUNCT
eurjchem-2518	68	37	figure	figure	NOUN
eurjchem-2518	68	38	4	4	NUM
eurjchem-2518	68	39	)	)	PUNCT
eurjchem-2518	68	40	[	[	X
eurjchem-2518	68	41	10,11	10,11	NOUN
eurjchem-2518	68	42	]	]	PUNCT
eurjchem-2518	68	43	.	.	PUNCT
eurjchem-2518	69	1	this	this	DET
eurjchem-2518	69	2	unusual	unusual	ADJ
eurjchem-2518	69	3	surface	surface	NOUN
eurjchem-2518	69	4	chemical	chemical	NOUN
eurjchem-2518	69	5	reaction	reaction	NOUN
eurjchem-2518	69	6	has	have	AUX
eurjchem-2518	69	7	become	become	VERB
eurjchem-2518	69	8	the	the	DET
eurjchem-2518	69	9	subject	subject	NOUN
eurjchem-2518	69	10	of	of	ADP
eurjchem-2518	69	11	our	our	PRON
eurjchem-2518	69	12	thermodynamic	thermodynamic	ADJ
eurjchem-2518	69	13	studies	study	NOUN
eurjchem-2518	69	14	by	by	ADP
eurjchem-2518	69	15	dft	dft	PROPN
eurjchem-2518	69	16	calculations	calculation	NOUN
eurjchem-2518	69	17	(	(	PUNCT
eurjchem-2518	69	18	table	table	NOUN
eurjchem-2518	69	19	1	1	NUM
eurjchem-2518	69	20	)	)	PUNCT
eurjchem-2518	70	1	[	[	X
eurjchem-2518	70	2	10	10	NUM
eurjchem-2518	70	3	-	-	SYM
eurjchem-2518	70	4	14	14	NUM
eurjchem-2518	70	5	]	]	PUNCT
eurjchem-2518	70	6	.	.	PUNCT
eurjchem-2518	71	1	since	since	SCONJ
eurjchem-2518	71	2	reaction	reaction	NOUN
eurjchem-2518	71	3	1	1	NUM
eurjchem-2518	71	4	is	be	AUX
eurjchem-2518	71	5	irreversible	irreversible	ADJ
eurjchem-2518	71	6	and	and	CCONJ
eurjchem-2518	71	7	proceeds	proceed	VERB
eurjchem-2518	71	8	at	at	ADP
eurjchem-2518	71	9	room	room	NOUN
eurjchem-2518	71	10	temperature	temperature	NOUN
eurjchem-2518	71	11	without	without	ADP
eurjchem-2518	71	12	the	the	DET
eurjchem-2518	71	13	use	use	NOUN
eurjchem-2518	71	14	of	of	ADP
eurjchem-2518	71	15	external	external	ADJ
eurjchem-2518	71	16	energy	energy	NOUN
eurjchem-2518	71	17	sources	source	NOUN
eurjchem-2518	71	18	,	,	PUNCT
eurjchem-2518	71	19	a	a	DET
eurjchem-2518	71	20	fair	fair	ADJ
eurjchem-2518	71	21	question	question	NOUN
eurjchem-2518	71	22	arises	arise	VERB
eurjchem-2518	71	23	:	:	PUNCT
eurjchem-2518	71	24	where	where	SCONJ
eurjchem-2518	71	25	does	do	AUX
eurjchem-2518	71	26	the	the	DET
eurjchem-2518	71	27	energy	energy	NOUN
eurjchem-2518	71	28	come	come	VERB
eurjchem-2518	71	29	from	from	ADP
eurjchem-2518	71	30	to	to	PART
eurjchem-2518	71	31	carry	carry	VERB
eurjchem-2518	71	32	out	out	ADP
eurjchem-2518	71	33	this	this	DET
eurjchem-2518	71	34	chemical	chemical	ADJ
eurjchem-2518	71	35	reaction	reaction	NOUN
eurjchem-2518	71	36	?	?	PUNCT
eurjchem-2518	72	1	it	it	PRON
eurjchem-2518	72	2	is	be	AUX
eurjchem-2518	72	3	known	know	VERB
eurjchem-2518	72	4	that	that	SCONJ
eurjchem-2518	72	5	in	in	ADP
eurjchem-2518	72	6	biological	biological	ADJ
eurjchem-2518	72	7	systems	system	NOUN
eurjchem-2518	72	8	,	,	PUNCT
eurjchem-2518	72	9	the	the	DET
eurjchem-2518	72	10	main	main	ADJ
eurjchem-2518	72	11	source	source	NOUN
eurjchem-2518	72	12	of	of	ADP
eurjchem-2518	72	13	energy	energy	NOUN
eurjchem-2518	72	14	for	for	ADP
eurjchem-2518	72	15	ensuring	ensure	VERB
eurjchem-2518	72	16	the	the	DET
eurjchem-2518	72	17	vital	vital	ADJ
eurjchem-2518	72	18	activity	activity	NOUN
eurjchem-2518	72	19	of	of	ADP
eurjchem-2518	72	20	organisms	organism	NOUN
eurjchem-2518	72	21	is	be	AUX
eurjchem-2518	72	22	the	the	DET
eurjchem-2518	72	23	potential	potential	ADJ
eurjchem-2518	72	24	energy	energy	NOUN
eurjchem-2518	72	25	stored	store	VERB
eurjchem-2518	72	26	in	in	ADP
eurjchem-2518	72	27	chemical	chemical	ADJ
eurjchem-2518	72	28	bonds	bond	NOUN
eurjchem-2518	72	29	[	[	X
eurjchem-2518	72	30	1	1	NUM
eurjchem-2518	72	31	]	]	PUNCT
eurjchem-2518	72	32	.	.	PUNCT
eurjchem-2518	73	1	therefore	therefore	ADV
eurjchem-2518	73	2	,	,	PUNCT
eurjchem-2518	73	3	to	to	PART
eurjchem-2518	73	4	answer	answer	VERB
eurjchem-2518	73	5	this	this	DET
eurjchem-2518	73	6	question	question	NOUN
eurjchem-2518	73	7	,	,	PUNCT
eurjchem-2518	73	8	we	we	PRON
eurjchem-2518	73	9	have	have	AUX
eurjchem-2518	73	10	developed	develop	VERB
eurjchem-2518	73	11	the	the	DET
eurjchem-2518	73	12	concept	concept	NOUN
eurjchem-2518	73	13	of	of	ADP
eurjchem-2518	73	14	the	the	DET
eurjchem-2518	73	15	decisive	decisive	ADJ
eurjchem-2518	73	16	role	role	NOUN
eurjchem-2518	73	17	of	of	ADP
eurjchem-2518	73	18	solid	solid	ADJ
eurjchem-2518	73	19	catalysts	catalyst	NOUN
eurjchem-2518	73	20	in	in	ADP
eurjchem-2518	73	21	the	the	DET
eurjchem-2518	73	22	framework	framework	NOUN
eurjchem-2518	73	23	of	of	ADP
eurjchem-2518	73	24	an	an	DET
eurjchem-2518	73	25	irreversible	irreversible	ADJ
eurjchem-2518	73	26	process	process	NOUN
eurjchem-2518	73	27	for	for	ADP
eurjchem-2518	73	28	an	an	DET
eurjchem-2518	73	29	open	open	ADJ
eurjchem-2518	73	30	system	system	NOUN
eurjchem-2518	73	31	that	that	PRON
eurjchem-2518	73	32	occurs	occur	VERB
eurjchem-2518	73	33	under	under	ADP
eurjchem-2518	73	34	non	non	ADJ
eurjchem-2518	73	35	-	-	ADJ
eurjchem-2518	73	36	equilibrium	equilibrium	ADJ
eurjchem-2518	73	37	conditions	condition	NOUN
eurjchem-2518	73	38	[	[	X
eurjchem-2518	73	39	10	10	NUM
eurjchem-2518	73	40	]	]	PUNCT
eurjchem-2518	73	41	.	.	PUNCT
eurjchem-2518	74	1	the	the	DET
eurjchem-2518	74	2	distinctive	distinctive	ADJ
eurjchem-2518	74	3	features	feature	NOUN
eurjchem-2518	74	4	of	of	ADP
eurjchem-2518	74	5	thermodynamics	thermodynamic	NOUN
eurjchem-2518	74	6	of	of	ADP
eurjchem-2518	74	7	nonequilibrium	nonequilibrium	NOUN
eurjchem-2518	74	8	processes	process	NOUN
eurjchem-2518	74	9	are	be	AUX
eurjchem-2518	74	10	that	that	SCONJ
eurjchem-2518	74	11	the	the	DET
eurjchem-2518	74	12	systems	system	NOUN
eurjchem-2518	74	13	considered	consider	VERB
eurjchem-2518	74	14	by	by	ADP
eurjchem-2518	74	15	it	it	PRON
eurjchem-2518	74	16	are	be	AUX
eurjchem-2518	74	17	open	open	ADJ
eurjchem-2518	74	18	to	to	ADP
eurjchem-2518	74	19	flows	flow	NOUN
eurjchem-2518	74	20	of	of	ADP
eurjchem-2518	74	21	matter	matter	NOUN
eurjchem-2518	74	22	and	and	CCONJ
eurjchem-2518	74	23	energy	energy	NOUN
eurjchem-2518	74	24	,	,	PUNCT
eurjchem-2518	74	25	and	and	CCONJ
eurjchem-2518	74	26	the	the	DET
eurjchem-2518	74	27	processes	process	NOUN
eurjchem-2518	74	28	occurring	occur	VERB
eurjchem-2518	74	29	in	in	ADP
eurjchem-2518	74	30	open	open	ADJ
eurjchem-2518	74	31	systems	system	NOUN
eurjchem-2518	74	32	are	be	AUX
eurjchem-2518	74	33	far	far	ADV
eurjchem-2518	74	34	from	from	ADP
eurjchem-2518	74	35	equilibrium	equilibrium	NOUN
eurjchem-2518	74	36	and	and	CCONJ
eurjchem-2518	74	37	irreversible	irreversible	ADJ
eurjchem-2518	74	38	.	.	PUNCT
eurjchem-2518	75	1	in	in	ADP
eurjchem-2518	75	2	the	the	DET
eurjchem-2518	75	3	thermodynamics	thermodynamic	NOUN
eurjchem-2518	75	4	of	of	ADP
eurjchem-2518	75	5	irreversible	irreversible	ADJ
eurjchem-2518	75	6	processes	process	NOUN
eurjchem-2518	75	7	,	,	PUNCT
eurjchem-2518	75	8	an	an	DET
eurjchem-2518	75	9	important	important	ADJ
eurjchem-2518	75	10	concept	concept	NOUN
eurjchem-2518	75	11	is	be	AUX
eurjchem-2518	75	12	the	the	DET
eurjchem-2518	75	13	stationary	stationary	ADJ
eurjchem-2518	75	14	state	state	NOUN
eurjchem-2518	75	15	of	of	ADP
eurjchem-2518	75	16	the	the	DET
eurjchem-2518	75	17	system	system	NOUN
eurjchem-2518	75	18	.	.	PUNCT
eurjchem-2518	76	1	unlike	unlike	ADP
eurjchem-2518	76	2	thermodynamic	thermodynamic	ADJ
eurjchem-2518	76	3	equilibrium	equilibrium	NOUN
eurjchem-2518	76	4	,	,	PUNCT
eurjchem-2518	76	5	the	the	DET
eurjchem-2518	76	6	stationary	stationary	ADJ
eurjchem-2518	76	7	state	state	NOUN
eurjchem-2518	76	8	is	be	AUX
eurjchem-2518	76	9	characterized	characterize	VERB
eurjchem-2518	76	10	by	by	ADP
eurjchem-2518	76	11	a	a	DET
eurjchem-2518	76	12	constant	constant	ADJ
eurjchem-2518	76	13	influx	influx	NOUN
eurjchem-2518	76	14	of	of	ADP
eurjchem-2518	76	15	substances	substance	NOUN
eurjchem-2518	76	16	into	into	ADP
eurjchem-2518	76	17	the	the	DET
eurjchem-2518	76	18	system	system	NOUN
eurjchem-2518	76	19	and	and	CCONJ
eurjchem-2518	76	20	the	the	DET
eurjchem-2518	76	21	removal	removal	NOUN
eurjchem-2518	76	22	of	of	ADP
eurjchem-2518	76	23	reaction	reaction	NOUN
eurjchem-2518	76	24	products	product	NOUN
eurjchem-2518	76	25	,	,	PUNCT
eurjchem-2518	76	26	continuous	continuous	ADJ
eurjchem-2518	76	27	expenditure	expenditure	NOUN
eurjchem-2518	76	28	of	of	ADP
eurjchem-2518	76	29	free	free	ADJ
eurjchem-2518	76	30	energy	energy	NOUN
eurjchem-2518	76	31	,	,	PUNCT
eurjchem-2518	76	32	which	which	PRON
eurjchem-2518	76	33	maintains	maintain	VERB
eurjchem-2518	76	34	a	a	DET
eurjchem-2518	76	35	constant	constant	ADJ
eurjchem-2518	76	36	concentration	concentration	NOUN
eurjchem-2518	76	37	of	of	ADP
eurjchem-2518	76	38	substances	substance	NOUN
eurjchem-2518	76	39	in	in	ADP
eurjchem-2518	76	40	the	the	DET
eurjchem-2518	76	41	system	system	NOUN
eurjchem-2518	76	42	,	,	PUNCT
eurjchem-2518	76	43	and	and	CCONJ
eurjchem-2518	76	44	the	the	DET
eurjchem-2518	76	45	constancy	constancy	NOUN
eurjchem-2518	76	46	of	of	ADP
eurjchem-2518	76	47	thermodynamic	thermodynamic	ADJ
eurjchem-2518	76	48	parameters	parameter	NOUN
eurjchem-2518	76	49	(	(	PUNCT
eurjchem-2518	76	50	including	include	VERB
eurjchem-2518	76	51	internal	internal	ADJ
eurjchem-2518	76	52	energy	energy	NOUN
eurjchem-2518	76	53	and	and	CCONJ
eurjchem-2518	76	54	entropy	entropy	NOUN
eurjchem-2518	76	55	)	)	PUNCT
eurjchem-2518	76	56	.	.	PUNCT
eurjchem-2518	77	1	it	it	PRON
eurjchem-2518	77	2	is	be	AUX
eurjchem-2518	77	3	important	important	ADJ
eurjchem-2518	77	4	that	that	SCONJ
eurjchem-2518	77	5	an	an	DET
eurjchem-2518	77	6	open	open	ADJ
eurjchem-2518	77	7	system	system	NOUN
eurjchem-2518	77	8	can	can	AUX
eurjchem-2518	77	9	exist	exist	VERB
eurjchem-2518	77	10	only	only	ADV
eurjchem-2518	77	11	due	due	ADP
eurjchem-2518	77	12	to	to	ADP
eurjchem-2518	77	13	the	the	DET
eurjchem-2518	77	14	influx	influx	NOUN
eurjchem-2518	77	15	of	of	ADP
eurjchem-2518	77	16	energy	energy	NOUN
eurjchem-2518	77	17	from	from	ADP
eurjchem-2518	77	18	the	the	DET
eurjchem-2518	77	19	outside	outside	NOUN
eurjchem-2518	77	20	and	and	CCONJ
eurjchem-2518	77	21	the	the	DET
eurjchem-2518	77	22	outflow	outflow	NOUN
eurjchem-2518	77	23	of	of	ADP
eurjchem-2518	77	24	energy	energy	NOUN
eurjchem-2518	77	25	into	into	ADP
eurjchem-2518	77	26	the	the	DET
eurjchem-2518	77	27	environment	environment	NOUN
eurjchem-2518	77	28	[	[	X
eurjchem-2518	77	29	15	15	NUM
eurjchem-2518	77	30	]	]	PUNCT
eurjchem-2518	77	31	.	.	PUNCT
eurjchem-2518	78	1	the	the	DET
eurjchem-2518	78	2	main	main	ADJ
eurjchem-2518	78	3	task	task	NOUN
eurjchem-2518	78	4	of	of	ADP
eurjchem-2518	78	5	the	the	DET
eurjchem-2518	78	6	thermodynamics	thermodynamic	NOUN
eurjchem-2518	78	7	of	of	ADP
eurjchem-2518	78	8	irreversible	irreversible	ADJ
eurjchem-2518	78	9	processes	process	NOUN
eurjchem-2518	78	10	is	be	AUX
eurjchem-2518	78	11	to	to	PART
eurjchem-2518	78	12	determine	determine	VERB
eurjchem-2518	78	13	the	the	DET
eurjchem-2518	78	14	value	value	NOUN
eurjchem-2518	78	15	of	of	ADP
eurjchem-2518	78	16	the	the	DET
eurjchem-2518	78	17	increase	increase	NOUN
eurjchem-2518	78	18	and	and	CCONJ
eurjchem-2518	78	19	the	the	DET
eurjchem-2518	78	20	outflow	outflow	NOUN
eurjchem-2518	78	21	of	of	ADP
eurjchem-2518	78	22	entropy	entropy	NOUN
eurjchem-2518	78	23	in	in	ADP
eurjchem-2518	78	24	a	a	DET
eurjchem-2518	78	25	reaction	reaction	NOUN
eurjchem-2518	78	26	system	system	NOUN
eurjchem-2518	78	27	based	base	VERB
eurjchem-2518	78	28	on	on	ADP
eurjchem-2518	78	29	the	the	DET
eurjchem-2518	78	30	gibbs	gibbs	PROPN
eurjchem-2518	78	31	equation	equation	NOUN
eurjchem-2518	78	32	[	[	X
eurjchem-2518	78	33	15	15	NUM
eurjchem-2518	78	34	]	]	PUNCT
eurjchem-2518	78	35	.	.	PUNCT
eurjchem-2518	79	1	in	in	ADP
eurjchem-2518	79	2	a	a	DET
eurjchem-2518	79	3	stationary	stationary	ADJ
eurjchem-2518	79	4	non	non	ADJ
eurjchem-2518	79	5	-	-	ADJ
eurjchem-2518	79	6	equilibrium	equilibrium	ADJ
eurjchem-2518	79	7	process	process	NOUN
eurjchem-2518	79	8	in	in	ADP
eurjchem-2518	79	9	an	an	DET
eurjchem-2518	79	10	open	open	ADJ
eurjchem-2518	79	11	system	system	NOUN
eurjchem-2518	79	12	,	,	PUNCT
eurjchem-2518	79	13	the	the	DET
eurjchem-2518	79	14	positive	positive	ADJ
eurjchem-2518	79	15	production	production	NOUN
eurjchem-2518	79	16	of	of	ADP
eurjchem-2518	79	17	entropy	entropy	NOUN
eurjchem-2518	79	18	inside	inside	ADP
eurjchem-2518	79	19	the	the	DET
eurjchem-2518	79	20	system	system	NOUN
eurjchem-2518	79	21	is	be	AUX
eurjchem-2518	79	22	compensated	compensate	VERB
eurjchem-2518	79	23	by	by	ADP
eurjchem-2518	79	24	the	the	DET
eurjchem-2518	79	25	outflow	outflow	NOUN
eurjchem-2518	79	26	of	of	ADP
eurjchem-2518	79	27	entropy	entropy	NOUN
eurjchem-2518	79	28	into	into	ADP
eurjchem-2518	79	29	the	the	DET
eurjchem-2518	79	30	environment	environment	NOUN
eurjchem-2518	79	31	,	,	PUNCT
eurjchem-2518	79	32	in	in	ADP
eurjchem-2518	79	33	other	other	ADJ
eurjchem-2518	79	34	words	word	NOUN
eurjchem-2518	79	35	,	,	PUNCT
eurjchem-2518	79	36	the	the	DET
eurjchem-2518	79	37	non	non	ADJ
eurjchem-2518	79	38	-	-	ADJ
eurjchem-2518	79	39	equilibrium	equilibrium	ADJ
eurjchem-2518	79	40	state	state	NOUN
eurjchem-2518	79	41	"	"	PUNCT
eurjchem-2518	79	42	dumps	dump	NOUN
eurjchem-2518	79	43	"	"	PUNCT
eurjchem-2518	79	44	the	the	DET
eurjchem-2518	79	45	entropy	entropy	NOUN
eurjchem-2518	79	46	generated	generate	VERB
eurjchem-2518	79	47	inside	inside	ADP
eurjchem-2518	79	48	the	the	DET
eurjchem-2518	79	49	system	system	NOUN
eurjchem-2518	79	50	into	into	ADP
eurjchem-2518	79	51	the	the	DET
eurjchem-2518	79	52	environment	environment	NOUN
eurjchem-2518	79	53	,	,	PUNCT
eurjchem-2518	79	54	thereby	thereby	ADV
eurjchem-2518	79	55	maintaining	maintain	VERB
eurjchem-2518	79	56	a	a	DET
eurjchem-2518	79	57	stationary	stationary	ADJ
eurjchem-2518	79	58	state	state	NOUN
eurjchem-2518	79	59	.	.	PUNCT
eurjchem-2518	80	1	thus	thus	ADV
eurjchem-2518	80	2	,	,	PUNCT
eurjchem-2518	80	3	the	the	DET
eurjchem-2518	80	4	change	change	NOUN
eurjchem-2518	80	5	in	in	ADP
eurjchem-2518	80	6	entropy	entropy	NOUN
eurjchem-2518	80	7	of	of	ADP
eurjchem-2518	80	8	an	an	DET
eurjchem-2518	80	9	open	open	ADJ
eurjchem-2518	80	10	system	system	NOUN
eurjchem-2518	80	11	occurs	occur	VERB
eurjchem-2518	80	12	not	not	PART
eurjchem-2518	80	13	only	only	ADV
eurjchem-2518	80	14	due	due	ADP
eurjchem-2518	80	15	to	to	ADP
eurjchem-2518	80	16	its	its	PRON
eurjchem-2518	80	17	increase	increase	NOUN
eurjchem-2518	80	18	and	and	CCONJ
eurjchem-2518	80	19	the	the	DET
eurjchem-2518	80	20	spontaneous	spontaneous	ADJ
eurjchem-2518	80	21	course	course	NOUN
eurjchem-2518	80	22	of	of	ADP
eurjchem-2518	80	23	irreversible	irreversible	ADJ
eurjchem-2518	80	24	processes	process	NOUN
eurjchem-2518	80	25	within	within	ADP
eurjchem-2518	80	26	the	the	DET
eurjchem-2518	80	27	system	system	NOUN
eurjchem-2518	80	28	itself	itself	PRON
eurjchem-2518	80	29	(	(	PUNCT
eurjchem-2518	80	30	dis	dis	PROPN
eurjchem-2518	80	31	)	)	PUNCT
eurjchem-2518	80	32	,	,	PUNCT
eurjchem-2518	80	33	but	but	CCONJ
eurjchem-2518	80	34	also	also	ADV
eurjchem-2518	80	35	due	due	ADP
eurjchem-2518	80	36	to	to	ADP
eurjchem-2518	80	37	processes	process	NOUN
eurjchem-2518	80	38	of	of	ADP
eurjchem-2518	80	39	exchange	exchange	NOUN
eurjchem-2518	80	40	of	of	ADP
eurjchem-2518	80	41	the	the	DET
eurjchem-2518	80	42	system	system	NOUN
eurjchem-2518	80	43	with	with	ADP
eurjchem-2518	80	44	the	the	DET
eurjchem-2518	80	45	external	external	ADJ
eurjchem-2518	80	46	environment	environment	NOUN
eurjchem-2518	80	47	(	(	PUNCT
eurjchem-2518	80	48	des	des	PROPN
eurjchem-2518	80	49	)	)	PUNCT
eurjchem-2518	81	1	[	[	X
eurjchem-2518	81	2	15	15	NUM
eurjchem-2518	81	3	]	]	PUNCT
eurjchem-2518	81	4	.	.	PUNCT
eurjchem-2518	82	1	in	in	ADP
eurjchem-2518	82	2	the	the	DET
eurjchem-2518	82	3	thermodynamics	thermodynamic	NOUN
eurjchem-2518	82	4	of	of	ADP
eurjchem-2518	82	5	irreversible	irreversible	ADJ
eurjchem-2518	82	6	processes	process	NOUN
eurjchem-2518	82	7	,	,	PUNCT
eurjchem-2518	82	8	it	it	PRON
eurjchem-2518	82	9	is	be	AUX
eurjchem-2518	82	10	postulated	postulate	VERB
eurjchem-2518	82	11	that	that	SCONJ
eurjchem-2518	82	12	the	the	DET
eurjchem-2518	82	13	components	component	NOUN
eurjchem-2518	82	14	dis	dis	PROPN
eurjchem-2518	82	15	and	and	CCONJ
eurjchem-2518	82	16	des	des	PROPN
eurjchem-2518	82	17	are	be	AUX
eurjchem-2518	82	18	independent	independent	ADJ
eurjchem-2518	82	19	and	and	CCONJ
eurjchem-2518	82	20	that	that	SCONJ
eurjchem-2518	82	21	the	the	DET
eurjchem-2518	82	22	total	total	ADJ
eurjchem-2518	82	23	change	change	NOUN
eurjchem-2518	82	24	in	in	ADP
eurjchem-2518	82	25	the	the	DET
eurjchem-2518	82	26	entropy	entropy	NOUN
eurjchem-2518	82	27	of	of	ADP
eurjchem-2518	82	28	an	an	DET
eurjchem-2518	82	29	open	open	ADJ
eurjchem-2518	82	30	system	system	NOUN
eurjchem-2518	82	31	is	be	AUX
eurjchem-2518	82	32	equal	equal	ADJ
eurjchem-2518	82	33	to	to	ADP
eurjchem-2518	82	34	their	their	PRON
eurjchem-2518	82	35	sum	sum	NOUN
eurjchem-2518	82	36	:	:	PUNCT
eurjchem-2518	82	37	ds	ds	ADJ
eurjchem-2518	82	38	=	=	PUNCT
eurjchem-2518	82	39	dis	dis	PROPN
eurjchem-2518	82	40	+	+	X
eurjchem-2518	82	41	des	des	PROPN
eurjchem-2518	82	42	.	.	PROPN
eurjchem-2518	83	1	in	in	ADP
eurjchem-2518	83	2	accordance	accordance	NOUN
eurjchem-2518	83	3	with	with	ADP
eurjchem-2518	83	4	the	the	DET
eurjchem-2518	83	5	gibbs	gibbs	PROPN
eurjchem-2518	83	6	equation	equation	NOUN
eurjchem-2518	83	7	∆g	∆g	PROPN
eurjchem-2518	83	8	=	=	SYM
eurjchem-2518	83	9	∆h	∆h	PROPN
eurjchem-2518	83	10	–	–	PUNCT
eurjchem-2518	83	11	t∆s	t∆s	NOUN
eurjchem-2518	83	12	,	,	PUNCT
eurjchem-2518	83	13	the	the	DET
eurjchem-2518	83	14	spontaneous	spontaneous	ADJ
eurjchem-2518	83	15	pathway	pathway	NOUN
eurjchem-2518	83	16	of	of	ADP
eurjchem-2518	83	17	an	an	DET
eurjchem-2518	83	18	irreversible	irreversible	ADJ
eurjchem-2518	83	19	chemical	chemical	NOUN
eurjchem-2518	83	20	reaction	reaction	NOUN
eurjchem-2518	83	21	is	be	AUX
eurjchem-2518	83	22	ensured	ensure	VERB
eurjchem-2518	83	23	provided	provide	VERB
eurjchem-2518	83	24	that	that	SCONJ
eurjchem-2518	83	25	in	in	ADP
eurjchem-2518	83	26	the	the	DET
eurjchem-2518	83	27	exothermic	exothermic	ADJ
eurjchem-2518	83	28	process	process	NOUN
eurjchem-2518	83	29	(	(	PUNCT
eurjchem-2518	83	30	the	the	DET
eurjchem-2518	83	31	enthalpy	enthalpy	NOUN
eurjchem-2518	83	32	of	of	ADP
eurjchem-2518	83	33	the	the	DET
eurjchem-2518	83	34	reaction	reaction	NOUN
eurjchem-2518	83	35	decreases	decrease	VERB
eurjchem-2518	83	36	,	,	PUNCT
eurjchem-2518	83	37	∆h	∆h	PROPN
eurjchem-2518	83	38	<	<	X
eurjchem-2518	83	39	0	0	NUM
eurjchem-2518	83	40	)	)	PUNCT
eurjchem-2518	83	41	the	the	DET
eurjchem-2518	83	42	entropy	entropy	NOUN
eurjchem-2518	83	43	increases	increase	VERB
eurjchem-2518	83	44	(	(	PUNCT
eurjchem-2518	83	45	δs	δs	NOUN
eurjchem-2518	83	46	>	>	X
eurjchem-2518	83	47	0	0	NUM
eurjchem-2518	83	48	)	)	PUNCT
eurjchem-2518	83	49	.	.	PUNCT
eurjchem-2518	84	1	anatolii	anatolii	NOUN
eurjchem-2518	84	2	startsev	startsev	PROPN
eurjchem-2518	84	3	/	/	SYM
eurjchem-2518	84	4	european	european	ADJ
eurjchem-2518	84	5	journal	journal	PROPN
eurjchem-2518	84	6	of	of	ADP
eurjchem-2518	84	7	chemistry	chemistry	NOUN
eurjchem-2518	84	8	15	15	NUM
eurjchem-2518	84	9	(	(	PUNCT
eurjchem-2518	84	10	2	2	NUM
eurjchem-2518	84	11	)	)	PUNCT
eurjchem-2518	84	12	(	(	PUNCT
eurjchem-2518	84	13	2024	2024	NUM
eurjchem-2518	84	14	)	)	PUNCT
eurjchem-2518	84	15	186	186	NUM
eurjchem-2518	84	16	-	-	SYM
eurjchem-2518	84	17	193	193	NUM
eurjchem-2518	84	18	189	189	NUM
eurjchem-2518	84	19	2024	2024	NUM
eurjchem-2518	84	20	–	–	PUNCT
eurjchem-2518	84	21	european	european	ADJ
eurjchem-2518	84	22	journal	journal	NOUN
eurjchem-2518	84	23	of	of	ADP
eurjchem-2518	84	24	chemistry	chemistry	NOUN
eurjchem-2518	84	25	–	–	PUNCT
eurjchem-2518	84	26	cc	cc	NOUN
eurjchem-2518	84	27	by	by	ADP
eurjchem-2518	84	28	nc	nc	PROPN
eurjchem-2518	84	29	–	–	PUNCT
eurjchem-2518	84	30	doi	doi	NOUN
eurjchem-2518	84	31	:	:	PUNCT
eurjchem-2518	84	32	10.5155	10.5155	NUM
eurjchem-2518	84	33	/	/	SYM
eurjchem-2518	84	34	eurjchem.15.2.186	eurjchem.15.2.186	VERB
eurjchem-2518	84	35	-	-	PUNCT
eurjchem-2518	84	36	193.2518	193.2518	NUM
eurjchem-2518	84	37	figure	figure	NOUN
eurjchem-2518	84	38	5	5	NUM
eurjchem-2518	84	39	.	.	PUNCT
eurjchem-2518	85	1	the	the	DET
eurjchem-2518	85	2	energetic	energetic	ADJ
eurjchem-2518	85	3	profile	profile	NOUN
eurjchem-2518	85	4	of	of	ADP
eurjchem-2518	85	5	hydrogen	hydrogen	NOUN
eurjchem-2518	85	6	sulfide	sulfide	NOUN
eurjchem-2518	85	7	decomposition	decomposition	NOUN
eurjchem-2518	85	8	on	on	ADP
eurjchem-2518	85	9	sulfide	sulfide	NOUN
eurjchem-2518	85	10	catalysts	catalyst	NOUN
eurjchem-2518	85	11	at	at	ADP
eurjchem-2518	85	12	room	room	NOUN
eurjchem-2518	85	13	temperature	temperature	NOUN
eurjchem-2518	85	14	[	[	X
eurjchem-2518	85	15	11	11	NUM
eurjchem-2518	85	16	]	]	PUNCT
eurjchem-2518	85	17	.	.	PUNCT
eurjchem-2518	86	1	however	however	ADV
eurjchem-2518	86	2	,	,	PUNCT
eurjchem-2518	86	3	if	if	SCONJ
eurjchem-2518	86	4	the	the	DET
eurjchem-2518	86	5	entropy	entropy	NOUN
eurjchem-2518	86	6	decreases	decrease	VERB
eurjchem-2518	86	7	as	as	ADP
eurjchem-2518	86	8	a	a	DET
eurjchem-2518	86	9	result	result	NOUN
eurjchem-2518	86	10	of	of	ADP
eurjchem-2518	86	11	an	an	DET
eurjchem-2518	86	12	exothermic	exothermic	ADJ
eurjchem-2518	86	13	reaction	reaction	NOUN
eurjchem-2518	86	14	(	(	PUNCT
eurjchem-2518	86	15	∆h	∆h	PROPN
eurjchem-2518	86	16	<	<	X
eurjchem-2518	86	17	0	0	NUM
eurjchem-2518	86	18	)	)	PUNCT
eurjchem-2518	86	19	(	(	PUNCT
eurjchem-2518	86	20	δs	δs	ADP
eurjchem-2518	86	21	<	<	X
eurjchem-2518	86	22	0	0	NUM
eurjchem-2518	86	23	)	)	PUNCT
eurjchem-2518	86	24	,	,	PUNCT
eurjchem-2518	86	25	then	then	ADV
eurjchem-2518	86	26	the	the	DET
eurjchem-2518	86	27	gibbs	gibbs	PROPN
eurjchem-2518	86	28	equation	equation	NOUN
eurjchem-2518	86	29	defines	define	VERB
eurjchem-2518	86	30	the	the	DET
eurjchem-2518	86	31	boundaries	boundary	NOUN
eurjchem-2518	86	32	of	of	ADP
eurjchem-2518	86	33	the	the	DET
eurjchem-2518	86	34	spontaneous	spontaneous	ADJ
eurjchem-2518	86	35	pathway	pathway	NOUN
eurjchem-2518	86	36	of	of	ADP
eurjchem-2518	86	37	the	the	DET
eurjchem-2518	86	38	process	process	NOUN
eurjchem-2518	86	39	.	.	PUNCT
eurjchem-2518	87	1	therefore	therefore	ADV
eurjchem-2518	87	2	,	,	PUNCT
eurjchem-2518	87	3	if	if	SCONJ
eurjchem-2518	87	4	a	a	DET
eurjchem-2518	87	5	certain	certain	ADJ
eurjchem-2518	87	6	amount	amount	NOUN
eurjchem-2518	87	7	of	of	ADP
eurjchem-2518	87	8	energy	energy	NOUN
eurjchem-2518	87	9	entered	enter	VERB
eurjchem-2518	87	10	the	the	DET
eurjchem-2518	87	11	system	system	NOUN
eurjchem-2518	87	12	as	as	ADP
eurjchem-2518	87	13	a	a	DET
eurjchem-2518	87	14	result	result	NOUN
eurjchem-2518	87	15	of	of	ADP
eurjchem-2518	87	16	an	an	DET
eurjchem-2518	87	17	exothermic	exothermic	ADJ
eurjchem-2518	87	18	process	process	NOUN
eurjchem-2518	87	19	is	be	AUX
eurjchem-2518	87	20	spent	spend	VERB
eurjchem-2518	87	21	on	on	ADP
eurjchem-2518	87	22	the	the	DET
eurjchem-2518	87	23	entropy	entropy	NOUN
eurjchem-2518	87	24	growth	growth	NOUN
eurjchem-2518	87	25	(	(	PUNCT
eurjchem-2518	87	26	which	which	PRON
eurjchem-2518	87	27	is	be	AUX
eurjchem-2518	87	28	inevitable	inevitable	ADJ
eurjchem-2518	87	29	for	for	ADP
eurjchem-2518	87	30	any	any	DET
eurjchem-2518	87	31	irreversible	irreversible	ADJ
eurjchem-2518	87	32	processes	process	NOUN
eurjchem-2518	87	33	)	)	PUNCT
eurjchem-2518	87	34	,	,	PUNCT
eurjchem-2518	87	35	then	then	ADV
eurjchem-2518	87	36	this	this	DET
eurjchem-2518	87	37	part	part	NOUN
eurjchem-2518	87	38	of	of	ADP
eurjchem-2518	87	39	the	the	DET
eurjchem-2518	87	40	energy	energy	NOUN
eurjchem-2518	87	41	is	be	AUX
eurjchem-2518	87	42	lost	lose	VERB
eurjchem-2518	87	43	to	to	PART
eurjchem-2518	87	44	perform	perform	VERB
eurjchem-2518	87	45	a	a	DET
eurjchem-2518	87	46	useful	useful	ADJ
eurjchem-2518	87	47	action	action	NOUN
eurjchem-2518	87	48	(	(	PUNCT
eurjchem-2518	87	49	for	for	ADP
eurjchem-2518	87	50	example	example	NOUN
eurjchem-2518	87	51	,	,	PUNCT
eurjchem-2518	87	52	the	the	DET
eurjchem-2518	87	53	formation	formation	NOUN
eurjchem-2518	87	54	of	of	ADP
eurjchem-2518	87	55	new	new	ADJ
eurjchem-2518	87	56	chemical	chemical	NOUN
eurjchem-2518	87	57	bonds	bond	NOUN
eurjchem-2518	87	58	in	in	ADP
eurjchem-2518	87	59	reaction	reaction	NOUN
eurjchem-2518	87	60	products	product	NOUN
eurjchem-2518	87	61	)	)	PUNCT
eurjchem-2518	87	62	,	,	PUNCT
eurjchem-2518	87	63	it	it	PRON
eurjchem-2518	87	64	dissipates	dissipate	VERB
eurjchem-2518	87	65	into	into	ADP
eurjchem-2518	87	66	the	the	DET
eurjchem-2518	87	67	environment	environment	NOUN
eurjchem-2518	87	68	in	in	ADP
eurjchem-2518	87	69	the	the	DET
eurjchem-2518	87	70	form	form	NOUN
eurjchem-2518	87	71	of	of	ADP
eurjchem-2518	87	72	heat	heat	NOUN
eurjchem-2518	87	73	.	.	PUNCT
eurjchem-2518	88	1	therefore	therefore	ADV
eurjchem-2518	88	2	,	,	PUNCT
eurjchem-2518	88	3	this	this	DET
eurjchem-2518	88	4	tδs	tδs	NOUN
eurjchem-2518	88	5	part	part	NOUN
eurjchem-2518	88	6	of	of	ADP
eurjchem-2518	88	7	the	the	DET
eurjchem-2518	88	8	energy	energy	NOUN
eurjchem-2518	88	9	is	be	AUX
eurjchem-2518	88	10	called	call	VERB
eurjchem-2518	88	11	bound	bound	ADJ
eurjchem-2518	88	12	(	(	PUNCT
eurjchem-2518	88	13	lost	lost	ADJ
eurjchem-2518	88	14	,	,	PUNCT
eurjchem-2518	88	15	waste	waste	NOUN
eurjchem-2518	88	16	)	)	PUNCT
eurjchem-2518	88	17	energy	energy	NOUN
eurjchem-2518	88	18	.	.	PUNCT
eurjchem-2518	89	1	the	the	DET
eurjchem-2518	89	2	remaining	remain	VERB
eurjchem-2518	89	3	part	part	NOUN
eurjchem-2518	89	4	of	of	ADP
eurjchem-2518	89	5	the	the	DET
eurjchem-2518	89	6	energy	energy	NOUN
eurjchem-2518	89	7	can	can	AUX
eurjchem-2518	89	8	be	be	AUX
eurjchem-2518	89	9	used	use	VERB
eurjchem-2518	89	10	to	to	PART
eurjchem-2518	89	11	perform	perform	VERB
eurjchem-2518	89	12	a	a	DET
eurjchem-2518	89	13	useful	useful	ADJ
eurjchem-2518	89	14	action	action	NOUN
eurjchem-2518	89	15	;	;	PUNCT
eurjchem-2518	89	16	therefore	therefore	ADV
eurjchem-2518	89	17	,	,	PUNCT
eurjchem-2518	89	18	gibbs	gibbs	PROPN
eurjchem-2518	89	19	energy	energy	NOUN
eurjchem-2518	89	20	is	be	AUX
eurjchem-2518	89	21	called	call	VERB
eurjchem-2518	89	22	free	free	ADJ
eurjchem-2518	89	23	energy	energy	NOUN
eurjchem-2518	89	24	[	[	X
eurjchem-2518	89	25	1	1	NUM
eurjchem-2518	89	26	]	]	PUNCT
eurjchem-2518	89	27	.	.	PUNCT
eurjchem-2518	90	1	so	so	ADV
eurjchem-2518	90	2	,	,	PUNCT
eurjchem-2518	90	3	the	the	DET
eurjchem-2518	90	4	first	first	ADJ
eurjchem-2518	90	5	stage	stage	NOUN
eurjchem-2518	90	6	of	of	ADP
eurjchem-2518	90	7	the	the	DET
eurjchem-2518	90	8	process	process	NOUN
eurjchem-2518	90	9	under	under	ADP
eurjchem-2518	90	10	consideration	consideration	NOUN
eurjchem-2518	90	11	is	be	AUX
eurjchem-2518	90	12	the	the	DET
eurjchem-2518	90	13	chemisorption	chemisorption	NOUN
eurjchem-2518	90	14	of	of	ADP
eurjchem-2518	90	15	h2s	h2s	NOUN
eurjchem-2518	90	16	molecules	molecule	NOUN
eurjchem-2518	90	17	on	on	ADP
eurjchem-2518	90	18	the	the	DET
eurjchem-2518	90	19	active	active	ADJ
eurjchem-2518	90	20	centers	center	NOUN
eurjchem-2518	90	21	of	of	ADP
eurjchem-2518	90	22	sulfide	sulfide	NOUN
eurjchem-2518	90	23	catalysts	catalyst	NOUN
eurjchem-2518	90	24	.	.	PUNCT
eurjchem-2518	91	1	according	accord	VERB
eurjchem-2518	91	2	to	to	ADP
eurjchem-2518	91	3	our	our	PRON
eurjchem-2518	91	4	idea	idea	NOUN
eurjchem-2518	91	5	,	,	PUNCT
eurjchem-2518	91	6	the	the	DET
eurjchem-2518	91	7	active	active	ADJ
eurjchem-2518	91	8	centers	center	NOUN
eurjchem-2518	91	9	are	be	AUX
eurjchem-2518	91	10	co(iii	co(iii	NOUN
eurjchem-2518	91	11	)	)	PUNCT
eurjchem-2518	91	12	or	or	CCONJ
eurjchem-2518	91	13	ni(iv	ni(iv	NOUN
eurjchem-2518	91	14	)	)	PUNCT
eurjchem-2518	91	15	ions	ion	NOUN
eurjchem-2518	91	16	with	with	ADP
eurjchem-2518	91	17	a	a	DET
eurjchem-2518	91	18	d6	d6	NOUN
eurjchem-2518	91	19	-	-	PUNCT
eurjchem-2518	91	20	electron	electron	NOUN
eurjchem-2518	91	21	configuration	configuration	NOUN
eurjchem-2518	91	22	,	,	PUNCT
eurjchem-2518	91	23	which	which	PRON
eurjchem-2518	91	24	results	result	VERB
eurjchem-2518	91	25	from	from	ADP
eurjchem-2518	91	26	the	the	DET
eurjchem-2518	91	27	oxidative	oxidative	ADJ
eurjchem-2518	91	28	addition	addition	NOUN
eurjchem-2518	91	29	of	of	ADP
eurjchem-2518	91	30	hydrogen	hydrogen	NOUN
eurjchem-2518	91	31	[	[	X
eurjchem-2518	91	32	13,14,16,17	13,14,16,17	NUM
eurjchem-2518	91	33	]	]	PUNCT
eurjchem-2518	91	34	.	.	PUNCT
eurjchem-2518	92	1	formally	formally	ADV
eurjchem-2518	92	2	,	,	PUNCT
eurjchem-2518	92	3	the	the	DET
eurjchem-2518	92	4	“	"	PUNCT
eurjchem-2518	92	5	vacant	vacant	ADJ
eurjchem-2518	92	6	”	"	PUNCT
eurjchem-2518	92	7	molecular	molecular	ADJ
eurjchem-2518	92	8	orbitals	orbital	NOUN
eurjchem-2518	92	9	dz2	dz2	NOUN
eurjchem-2518	92	10	and	and	CCONJ
eurjchem-2518	92	11	dxy	dxy	PROPN
eurjchem-2518	92	12	of	of	ADP
eurjchem-2518	92	13	the	the	DET
eurjchem-2518	92	14	metal	metal	NOUN
eurjchem-2518	92	15	atom	atom	NOUN
eurjchem-2518	92	16	effectively	effectively	ADV
eurjchem-2518	92	17	interact	interact	VERB
eurjchem-2518	92	18	with	with	ADP
eurjchem-2518	92	19	the	the	DET
eurjchem-2518	92	20	occupied	occupy	VERB
eurjchem-2518	92	21	orbitals	orbital	NOUN
eurjchem-2518	92	22	nσ	nσ	PROPN
eurjchem-2518	92	23	and	and	CCONJ
eurjchem-2518	92	24	nπ	nπ	NOUN
eurjchem-2518	92	25	of	of	ADP
eurjchem-2518	92	26	the	the	DET
eurjchem-2518	92	27	h2s	h2s	NOUN
eurjchem-2518	92	28	molecule	molecule	NOUN
eurjchem-2518	92	29	,	,	PUNCT
eurjchem-2518	92	30	respectively	respectively	ADV
eurjchem-2518	92	31	(	(	PUNCT
eurjchem-2518	92	32	figure	figure	NOUN
eurjchem-2518	92	33	2	2	NUM
eurjchem-2518	92	34	)	)	PUNCT
eurjchem-2518	92	35	.	.	PUNCT
eurjchem-2518	93	1	consequently	consequently	ADV
eurjchem-2518	93	2	,	,	PUNCT
eurjchem-2518	93	3	co(iii	co(iii	NOUN
eurjchem-2518	93	4	)	)	PUNCT
eurjchem-2518	93	5	is	be	AUX
eurjchem-2518	93	6	a	a	DET
eurjchem-2518	93	7	lewis	lewis	PROPN
eurjchem-2518	93	8	acid	acid	PROPN
eurjchem-2518	93	9	center	center	NOUN
eurjchem-2518	93	10	with	with	ADP
eurjchem-2518	93	11	vacant	vacant	ADJ
eurjchem-2518	93	12	orbitals	orbital	NOUN
eurjchem-2518	93	13	that	that	PRON
eurjchem-2518	93	14	accept	accept	VERB
eurjchem-2518	93	15	an	an	DET
eurjchem-2518	93	16	electron	electron	NOUN
eurjchem-2518	93	17	pair	pair	NOUN
eurjchem-2518	93	18	from	from	ADP
eurjchem-2518	93	19	a	a	DET
eurjchem-2518	93	20	hydrogen	hydrogen	NOUN
eurjchem-2518	93	21	sulfide	sulfide	NOUN
eurjchem-2518	93	22	donor	donor	NOUN
eurjchem-2518	93	23	molecule	molecule	NOUN
eurjchem-2518	93	24	,	,	PUNCT
eurjchem-2518	93	25	the	the	DET
eurjchem-2518	93	26	lewis	lewis	PROPN
eurjchem-2518	93	27	base	base	NOUN
eurjchem-2518	93	28	,	,	PUNCT
eurjchem-2518	93	29	to	to	PART
eurjchem-2518	93	30	form	form	VERB
eurjchem-2518	93	31	a	a	DET
eurjchem-2518	93	32	new	new	ADJ
eurjchem-2518	93	33	chemical	chemical	NOUN
eurjchem-2518	93	34	bond	bond	NOUN
eurjchem-2518	93	35	[	[	X
eurjchem-2518	93	36	13	13	NUM
eurjchem-2518	93	37	]	]	PUNCT
eurjchem-2518	93	38	.	.	PUNCT
eurjchem-2518	94	1	this	this	DET
eurjchem-2518	94	2	exothermic	exothermic	ADJ
eurjchem-2518	94	3	process	process	NOUN
eurjchem-2518	94	4	(	(	PUNCT
eurjchem-2518	94	5	table	table	NOUN
eurjchem-2518	94	6	1	1	NUM
eurjchem-2518	94	7	)	)	PUNCT
eurjchem-2518	94	8	results	result	NOUN
eurjchem-2518	94	9	in	in	ADP
eurjchem-2518	94	10	a	a	DET
eurjchem-2518	94	11	decrease	decrease	NOUN
eurjchem-2518	94	12	in	in	ADP
eurjchem-2518	94	13	the	the	DET
eurjchem-2518	94	14	entropy	entropy	NOUN
eurjchem-2518	94	15	of	of	ADP
eurjchem-2518	94	16	the	the	DET
eurjchem-2518	94	17	system	system	NOUN
eurjchem-2518	94	18	,	,	PUNCT
eurjchem-2518	94	19	which	which	PRON
eurjchem-2518	94	20	dissipates	dissipate	VERB
eurjchem-2518	94	21	into	into	ADP
eurjchem-2518	94	22	the	the	DET
eurjchem-2518	94	23	environment	environment	NOUN
eurjchem-2518	94	24	in	in	ADP
eurjchem-2518	94	25	the	the	DET
eurjchem-2518	94	26	form	form	NOUN
eurjchem-2518	94	27	of	of	ADP
eurjchem-2518	94	28	bound	bind	VERB
eurjchem-2518	94	29	energy	energy	NOUN
eurjchem-2518	94	30	;	;	PUNCT
eurjchem-2518	94	31	however	however	ADV
eurjchem-2518	94	32	,	,	PUNCT
eurjchem-2518	94	33	the	the	DET
eurjchem-2518	94	34	remaining	remain	VERB
eurjchem-2518	94	35	part	part	NOUN
eurjchem-2518	94	36	of	of	ADP
eurjchem-2518	94	37	the	the	DET
eurjchem-2518	94	38	gibbs	gibbs	PROPN
eurjchem-2518	94	39	free	free	ADJ
eurjchem-2518	94	40	energy	energy	NOUN
eurjchem-2518	94	41	can	can	AUX
eurjchem-2518	94	42	be	be	AUX
eurjchem-2518	94	43	used	use	VERB
eurjchem-2518	94	44	to	to	PART
eurjchem-2518	94	45	maintain	maintain	VERB
eurjchem-2518	94	46	a	a	DET
eurjchem-2518	94	47	chemical	chemical	NOUN
eurjchem-2518	94	48	reaction	reaction	NOUN
eurjchem-2518	94	49	.	.	PUNCT
eurjchem-2518	95	1	in	in	ADP
eurjchem-2518	95	2	the	the	DET
eurjchem-2518	95	3	second	second	ADJ
eurjchem-2518	95	4	stage	stage	NOUN
eurjchem-2518	95	5	,	,	PUNCT
eurjchem-2518	95	6	dissociation	dissociation	NOUN
eurjchem-2518	95	7	of	of	ADP
eurjchem-2518	95	8	the	the	DET
eurjchem-2518	95	9	adsorbed	adsorb	VERB
eurjchem-2518	95	10	h2s	h2s	NOUN
eurjchem-2518	95	11	molecule	molecule	NOUN
eurjchem-2518	95	12	occurs	occur	VERB
eurjchem-2518	95	13	resulting	result	VERB
eurjchem-2518	95	14	as	as	ADP
eurjchem-2518	95	15	a	a	DET
eurjchem-2518	95	16	result	result	NOUN
eurjchem-2518	95	17	of	of	ADP
eurjchem-2518	95	18	the	the	DET
eurjchem-2518	95	19	formation	formation	NOUN
eurjchem-2518	95	20	of	of	ADP
eurjchem-2518	95	21	new	new	ADJ
eurjchem-2518	95	22	chemical	chemical	NOUN
eurjchem-2518	95	23	bonds	bond	NOUN
eurjchem-2518	95	24	with	with	ADP
eurjchem-2518	95	25	the	the	DET
eurjchem-2518	95	26	surface	surface	NOUN
eurjchem-2518	95	27	of	of	ADP
eurjchem-2518	95	28	the	the	DET
eurjchem-2518	95	29	catalyst	catalyst	NOUN
eurjchem-2518	95	30	.	.	PUNCT
eurjchem-2518	96	1	this	this	DET
eurjchem-2518	96	2	exothermic	exothermic	ADJ
eurjchem-2518	96	3	process	process	NOUN
eurjchem-2518	96	4	occurs	occur	VERB
eurjchem-2518	96	5	with	with	ADP
eurjchem-2518	96	6	an	an	DET
eurjchem-2518	96	7	increase	increase	NOUN
eurjchem-2518	96	8	in	in	ADP
eurjchem-2518	96	9	entropy	entropy	NOUN
eurjchem-2518	96	10	and	and	CCONJ
eurjchem-2518	96	11	a	a	DET
eurjchem-2518	96	12	significant	significant	ADJ
eurjchem-2518	96	13	gain	gain	NOUN
eurjchem-2518	96	14	in	in	ADP
eurjchem-2518	96	15	the	the	DET
eurjchem-2518	96	16	gibbs	gibbs	PROPN
eurjchem-2518	96	17	free	free	ADJ
eurjchem-2518	96	18	energy	energy	NOUN
eurjchem-2518	96	19	.	.	PUNCT
eurjchem-2518	97	1	in	in	ADP
eurjchem-2518	97	2	the	the	DET
eurjchem-2518	97	3	next	next	ADJ
eurjchem-2518	97	4	stage	stage	NOUN
eurjchem-2518	97	5	,	,	PUNCT
eurjchem-2518	97	6	a	a	DET
eurjchem-2518	97	7	new	new	ADJ
eurjchem-2518	97	8	sulfursulfur	sulfursulfur	NOUN
eurjchem-2518	97	9	chemical	chemical	NOUN
eurjchem-2518	97	10	bond	bond	NOUN
eurjchem-2518	97	11	is	be	AUX
eurjchem-2518	97	12	formed	form	VERB
eurjchem-2518	97	13	in	in	ADP
eurjchem-2518	97	14	the	the	DET
eurjchem-2518	97	15	key	key	ADJ
eurjchem-2518	97	16	surface	surface	NOUN
eurjchem-2518	97	17	intermediate	intermediate	ADJ
eurjchem-2518	97	18	(	(	PUNCT
eurjchem-2518	97	19	figure	figure	NOUN
eurjchem-2518	97	20	4	4	NUM
eurjchem-2518	97	21	)	)	PUNCT
eurjchem-2518	97	22	,	,	PUNCT
eurjchem-2518	97	23	while	while	SCONJ
eurjchem-2518	97	24	the	the	DET
eurjchem-2518	97	25	hydrogen	hydrogen	NOUN
eurjchem-2518	97	26	molecule	molecule	NOUN
eurjchem-2518	97	27	leaves	leave	VERB
eurjchem-2518	97	28	the	the	DET
eurjchem-2518	97	29	surface	surface	NOUN
eurjchem-2518	97	30	of	of	ADP
eurjchem-2518	97	31	the	the	DET
eurjchem-2518	97	32	catalyst	catalyst	NOUN
eurjchem-2518	97	33	.	.	PUNCT
eurjchem-2518	98	1	this	this	DET
eurjchem-2518	98	2	stage	stage	NOUN
eurjchem-2518	98	3	proceeds	proceed	VERB
eurjchem-2518	98	4	through	through	ADP
eurjchem-2518	98	5	a	a	DET
eurjchem-2518	98	6	small	small	ADJ
eurjchem-2518	98	7	energy	energy	NOUN
eurjchem-2518	98	8	barrier	barrier	NOUN
eurjchem-2518	98	9	;	;	PUNCT
eurjchem-2518	98	10	therefore	therefore	ADV
eurjchem-2518	98	11	,	,	PUNCT
eurjchem-2518	98	12	it	it	PRON
eurjchem-2518	98	13	requires	require	VERB
eurjchem-2518	98	14	the	the	DET
eurjchem-2518	98	15	expenditure	expenditure	NOUN
eurjchem-2518	98	16	of	of	ADP
eurjchem-2518	98	17	free	free	ADJ
eurjchem-2518	98	18	energy	energy	NOUN
eurjchem-2518	98	19	(	(	PUNCT
eurjchem-2518	98	20	figure	figure	NOUN
eurjchem-2518	98	21	5	5	NUM
eurjchem-2518	98	22	,	,	PUNCT
eurjchem-2518	98	23	[	[	X
eurjchem-2518	98	24	11	11	NUM
eurjchem-2518	98	25	]	]	PUNCT
eurjchem-2518	98	26	)	)	PUNCT
eurjchem-2518	98	27	accumulated	accumulate	VERB
eurjchem-2518	98	28	in	in	ADP
eurjchem-2518	98	29	the	the	DET
eurjchem-2518	98	30	previous	previous	ADJ
eurjchem-2518	98	31	stages	stage	NOUN
eurjchem-2518	98	32	.	.	PUNCT
eurjchem-2518	99	1	the	the	DET
eurjchem-2518	99	2	most	most	ADV
eurjchem-2518	99	3	energy	energy	NOUN
eurjchem-2518	99	4	-	-	PUNCT
eurjchem-2518	99	5	consuming	consume	VERB
eurjchem-2518	99	6	stage	stage	NOUN
eurjchem-2518	99	7	(	(	PUNCT
eurjchem-2518	99	8	iv	iv	X
eurjchem-2518	99	9	)	)	PUNCT
eurjchem-2518	99	10	(	(	PUNCT
eurjchem-2518	99	11	table	table	NOUN
eurjchem-2518	99	12	1	1	NUM
eurjchem-2518	99	13	)	)	PUNCT
eurjchem-2518	99	14	is	be	AUX
eurjchem-2518	99	15	the	the	DET
eurjchem-2518	99	16	decomposition	decomposition	NOUN
eurjchem-2518	99	17	of	of	ADP
eurjchem-2518	99	18	a	a	DET
eurjchem-2518	99	19	key	key	ADJ
eurjchem-2518	99	20	surface	surface	NOUN
eurjchem-2518	99	21	intermediate	intermediate	ADJ
eurjchem-2518	99	22	to	to	PART
eurjchem-2518	99	23	form	form	VERB
eurjchem-2518	99	24	reaction	reaction	NOUN
eurjchem-2518	99	25	products	product	NOUN
eurjchem-2518	99	26	.	.	PUNCT
eurjchem-2518	100	1	this	this	DET
eurjchem-2518	100	2	stage	stage	NOUN
eurjchem-2518	100	3	has	have	VERB
eurjchem-2518	100	4	an	an	DET
eurjchem-2518	100	5	energy	energy	NOUN
eurjchem-2518	100	6	barrier	barrier	NOUN
eurjchem-2518	100	7	(	(	PUNCT
eurjchem-2518	100	8	figure	figure	NOUN
eurjchem-2518	100	9	5	5	NUM
eurjchem-2518	100	10	)	)	PUNCT
eurjchem-2518	100	11	and	and	CCONJ
eurjchem-2518	100	12	to	to	PART
eurjchem-2518	100	13	overcome	overcome	VERB
eurjchem-2518	100	14	it	it	PRON
eurjchem-2518	100	15	,	,	PUNCT
eurjchem-2518	100	16	the	the	DET
eurjchem-2518	100	17	free	free	ADJ
eurjchem-2518	100	18	energy	energy	NOUN
eurjchem-2518	100	19	accumulated	accumulate	VERB
eurjchem-2518	100	20	in	in	ADP
eurjchem-2518	100	21	the	the	DET
eurjchem-2518	100	22	previous	previous	ADJ
eurjchem-2518	100	23	stages	stage	NOUN
eurjchem-2518	100	24	is	be	AUX
eurjchem-2518	100	25	used	use	VERB
eurjchem-2518	100	26	,	,	PUNCT
eurjchem-2518	100	27	as	as	ADV
eurjchem-2518	100	28	well	well	ADV
eurjchem-2518	100	29	as	as	ADP
eurjchem-2518	100	30	the	the	DET
eurjchem-2518	100	31	free	free	ADJ
eurjchem-2518	100	32	energy	energy	NOUN
eurjchem-2518	100	33	obtained	obtain	VERB
eurjchem-2518	100	34	as	as	ADP
eurjchem-2518	100	35	a	a	DET
eurjchem-2518	100	36	result	result	NOUN
eurjchem-2518	100	37	of	of	ADP
eurjchem-2518	100	38	the	the	DET
eurjchem-2518	100	39	recombination	recombination	NOUN
eurjchem-2518	100	40	of	of	ADP
eurjchem-2518	100	41	diatomic	diatomic	ADJ
eurjchem-2518	100	42	sulfur	sulfur	NOUN
eurjchem-2518	100	43	into	into	ADP
eurjchem-2518	100	44	a	a	DET
eurjchem-2518	100	45	cycloocta	cycloocta	NOUN
eurjchem-2518	100	46	sulfur	sulfur	NOUN
eurjchem-2518	100	47	and	and	CCONJ
eurjchem-2518	100	48	the	the	DET
eurjchem-2518	100	49	removal	removal	NOUN
eurjchem-2518	100	50	of	of	ADP
eurjchem-2518	100	51	bound	bind	VERB
eurjchem-2518	100	52	energy	energy	NOUN
eurjchem-2518	100	53	in	in	ADP
eurjchem-2518	100	54	the	the	DET
eurjchem-2518	100	55	environment	environment	NOUN
eurjchem-2518	100	56	.	.	PUNCT
eurjchem-2518	101	1	to	to	PART
eurjchem-2518	101	2	remove	remove	VERB
eurjchem-2518	101	3	solid	solid	ADJ
eurjchem-2518	101	4	sulfur	sulfur	NOUN
eurjchem-2518	101	5	from	from	ADP
eurjchem-2518	101	6	the	the	DET
eurjchem-2518	101	7	surface	surface	NOUN
eurjchem-2518	101	8	of	of	ADP
eurjchem-2518	101	9	the	the	DET
eurjchem-2518	101	10	catalyst	catalyst	NOUN
eurjchem-2518	101	11	,	,	PUNCT
eurjchem-2518	101	12	a	a	DET
eurjchem-2518	101	13	very	very	ADV
eurjchem-2518	101	14	simple	simple	ADJ
eurjchem-2518	101	15	technique	technique	NOUN
eurjchem-2518	101	16	is	be	AUX
eurjchem-2518	101	17	used	use	VERB
eurjchem-2518	101	18	,	,	PUNCT
eurjchem-2518	101	19	placing	place	VERB
eurjchem-2518	101	20	the	the	DET
eurjchem-2518	101	21	catalyst	catalyst	NOUN
eurjchem-2518	101	22	in	in	ADP
eurjchem-2518	101	23	a	a	DET
eurjchem-2518	101	24	liquid	liquid	ADJ
eurjchem-2518	101	25	layer	layer	NOUN
eurjchem-2518	101	26	capable	capable	ADJ
eurjchem-2518	101	27	of	of	ADP
eurjchem-2518	101	28	dissolving	dissolve	VERB
eurjchem-2518	101	29	both	both	CCONJ
eurjchem-2518	101	30	the	the	DET
eurjchem-2518	101	31	initial	initial	ADJ
eurjchem-2518	101	32	and	and	CCONJ
eurjchem-2518	101	33	final	final	ADJ
eurjchem-2518	101	34	products	product	NOUN
eurjchem-2518	101	35	of	of	ADP
eurjchem-2518	101	36	the	the	DET
eurjchem-2518	101	37	reaction	reaction	NOUN
eurjchem-2518	101	38	[	[	X
eurjchem-2518	101	39	18,19	18,19	NUM
eurjchem-2518	101	40	]	]	PUNCT
eurjchem-2518	101	41	.	.	PUNCT
eurjchem-2518	102	1	thus	thus	ADV
eurjchem-2518	102	2	,	,	PUNCT
eurjchem-2518	102	3	the	the	DET
eurjchem-2518	102	4	decomposition	decomposition	NOUN
eurjchem-2518	102	5	of	of	ADP
eurjchem-2518	102	6	h2s	h2s	NOUN
eurjchem-2518	102	7	on	on	ADP
eurjchem-2518	102	8	sulfide	sulfide	NOUN
eurjchem-2518	102	9	catalysts	catalyst	NOUN
eurjchem-2518	102	10	at	at	ADP
eurjchem-2518	102	11	room	room	NOUN
eurjchem-2518	102	12	temperature	temperature	NOUN
eurjchem-2518	102	13	is	be	AUX
eurjchem-2518	102	14	an	an	DET
eurjchem-2518	102	15	exothermic	exothermic	ADJ
eurjchem-2518	102	16	process	process	NOUN
eurjchem-2518	102	17	that	that	PRON
eurjchem-2518	102	18	proceeds	proceed	VERB
eurjchem-2518	102	19	spontaneously	spontaneously	ADV
eurjchem-2518	102	20	with	with	ADP
eurjchem-2518	102	21	a	a	DET
eurjchem-2518	102	22	decrease	decrease	NOUN
eurjchem-2518	102	23	in	in	ADP
eurjchem-2518	102	24	the	the	DET
eurjchem-2518	102	25	entropy	entropy	NOUN
eurjchem-2518	102	26	of	of	ADP
eurjchem-2518	102	27	the	the	DET
eurjchem-2518	102	28	system	system	NOUN
eurjchem-2518	102	29	,	,	PUNCT
eurjchem-2518	102	30	which	which	PRON
eurjchem-2518	102	31	is	be	AUX
eurjchem-2518	102	32	dissipated	dissipate	VERB
eurjchem-2518	102	33	in	in	ADP
eurjchem-2518	102	34	the	the	DET
eurjchem-2518	102	35	environment	environment	NOUN
eurjchem-2518	102	36	in	in	ADP
eurjchem-2518	102	37	the	the	DET
eurjchem-2518	102	38	form	form	NOUN
eurjchem-2518	102	39	of	of	ADP
eurjchem-2518	102	40	waste	waste	NOUN
eurjchem-2518	102	41	energy	energy	NOUN
eurjchem-2518	102	42	(	(	PUNCT
eurjchem-2518	102	43	reaction	reaction	NOUN
eurjchem-2518	102	44	3	3	NUM
eurjchem-2518	102	45	):	):	PUNCT
eurjchem-2518	102	46	2	2	NUM
eurjchem-2518	102	47	h2s	h2s	NOUN
eurjchem-2518	102	48	1/4	1/4	NUM
eurjchem-2518	102	49	(	(	PUNCT
eurjchem-2518	102	50	s8)ads2	s8)ads2	PROPN
eurjchem-2518	102	51	h2	h2	PROPN
eurjchem-2518	102	52	(	(	PUNCT
eurjchem-2518	102	53	g	g	NOUN
eurjchem-2518	102	54	)	)	PUNCT
eurjchem-2518	102	55	sulfide	sulfide	NOUN
eurjchem-2518	102	56	catalyst	catalyst	NOUN
eurjchem-2518	102	57	,	,	PUNCT
eurjchem-2518	102	58	25	25	NUM
eurjchem-2518	102	59	oc	oc	NOUN
eurjchem-2518	102	60	(	(	PUNCT
eurjchem-2518	102	61	3	3	X
eurjchem-2518	102	62	)	)	PUNCT
eurjchem-2518	102	63	the	the	DET
eurjchem-2518	102	64	driving	drive	VERB
eurjchem-2518	102	65	force	force	NOUN
eurjchem-2518	102	66	of	of	ADP
eurjchem-2518	102	67	the	the	DET
eurjchem-2518	102	68	process	process	NOUN
eurjchem-2518	102	69	is	be	AUX
eurjchem-2518	102	70	the	the	DET
eurjchem-2518	102	71	formation	formation	NOUN
eurjchem-2518	102	72	of	of	ADP
eurjchem-2518	102	73	reaction	reaction	NOUN
eurjchem-2518	102	74	products	product	NOUN
eurjchem-2518	102	75	in	in	ADP
eurjchem-2518	102	76	the	the	DET
eurjchem-2518	102	77	ground	ground	NOUN
eurjchem-2518	102	78	electronic	electronic	ADJ
eurjchem-2518	102	79	state	state	NOUN
eurjchem-2518	102	80	,	,	PUNCT
eurjchem-2518	102	81	singlet	singlet	ADJ
eurjchem-2518	102	82	hydrogen	hydrogen	NOUN
eurjchem-2518	102	83	and	and	CCONJ
eurjchem-2518	102	84	solid	solid	ADJ
eurjchem-2518	102	85	singlet	singlet	NOUN
eurjchem-2518	102	86	sulfur	sulfur	NOUN
eurjchem-2518	102	87	,	,	PUNCT
eurjchem-2518	102	88	having	have	VERB
eurjchem-2518	102	89	a	a	DET
eurjchem-2518	102	90	minimum	minimum	NOUN
eurjchem-2518	102	91	of	of	ADP
eurjchem-2518	102	92	free	free	ADJ
eurjchem-2518	102	93	energy	energy	NOUN
eurjchem-2518	102	94	.	.	PUNCT
eurjchem-2518	103	1	in	in	ADP
eurjchem-2518	103	2	the	the	DET
eurjchem-2518	103	3	gas	gas	NOUN
eurjchem-2518	103	4	phase	phase	NOUN
eurjchem-2518	103	5	,	,	PUNCT
eurjchem-2518	103	6	this	this	DET
eurjchem-2518	103	7	process	process	NOUN
eurjchem-2518	103	8	is	be	AUX
eurjchem-2518	103	9	impossible	impossible	ADJ
eurjchem-2518	103	10	.	.	PUNCT
eurjchem-2518	104	1	3	3	X
eurjchem-2518	104	2	.	.	X
eurjchem-2518	104	3	initial	initial	ADJ
eurjchem-2518	104	4	data	datum	NOUN
eurjchem-2518	104	5	for	for	ADP
eurjchem-2518	104	6	reflection	reflection	NOUN
eurjchem-2518	104	7	:	:	PUNCT
eurjchem-2518	104	8	metal	metal	NOUN
eurjchem-2518	104	9	catalysts	catalyst	VERB
eurjchem-2518	104	10	the	the	DET
eurjchem-2518	104	11	starting	starting	NOUN
eurjchem-2518	104	12	point	point	NOUN
eurjchem-2518	104	13	for	for	ADP
eurjchem-2518	104	14	reflection	reflection	NOUN
eurjchem-2518	104	15	is	be	AUX
eurjchem-2518	104	16	an	an	DET
eurjchem-2518	104	17	article	article	NOUN
eurjchem-2518	104	18	published	publish	VERB
eurjchem-2518	104	19	in	in	ADP
eurjchem-2518	104	20	1986	1986	NUM
eurjchem-2518	104	21	[	[	X
eurjchem-2518	104	22	20	20	NUM
eurjchem-2518	104	23	]	]	PUNCT
eurjchem-2518	104	24	,	,	PUNCT
eurjchem-2518	104	25	in	in	ADP
eurjchem-2518	104	26	which	which	PRON
eurjchem-2518	104	27	the	the	DET
eurjchem-2518	104	28	behavior	behavior	NOUN
eurjchem-2518	104	29	of	of	ADP
eurjchem-2518	104	30	h2s	h2s	PROPN
eurjchem-2518	104	31	on	on	ADP
eurjchem-2518	104	32	the	the	DET
eurjchem-2518	104	33	surface	surface	NOUN
eurjchem-2518	104	34	of	of	ADP
eurjchem-2518	104	35	a	a	DET
eurjchem-2518	104	36	platinum	platinum	NOUN
eurjchem-2518	104	37	single	single	ADJ
eurjchem-2518	104	38	crystal	crystal	NOUN
eurjchem-2518	104	39	pt(111	pt(111	X
eurjchem-2518	104	40	)	)	PUNCT
eurjchem-2518	104	41	was	be	AUX
eurjchem-2518	104	42	experimentally	experimentally	ADV
eurjchem-2518	104	43	studied	study	VERB
eurjchem-2518	104	44	.	.	PUNCT
eurjchem-2518	105	1	after	after	ADP
eurjchem-2518	105	2	h2s	h2s	NOUN
eurjchem-2518	105	3	adsorption	adsorption	NOUN
eurjchem-2518	105	4	at	at	ADP
eurjchem-2518	105	5	110	110	NUM
eurjchem-2518	105	6	k	k	NOUN
eurjchem-2518	105	7	,	,	PUNCT
eurjchem-2518	105	8	bands	band	NOUN
eurjchem-2518	105	9	appear	appear	VERB
eurjchem-2518	105	10	in	in	ADP
eurjchem-2518	105	11	the	the	DET
eurjchem-2518	105	12	high	high	ADJ
eurjchem-2518	105	13	resolution	resolution	NOUN
eurjchem-2518	105	14	electron	electron	NOUN
eurjchem-2518	105	15	energy	energy	NOUN
eurjchem-2518	105	16	-	-	PUNCT
eurjchem-2518	105	17	loss	loss	NOUN
eurjchem-2518	105	18	spectroscopy	spectroscopy	NOUN
eurjchem-2518	105	19	(	(	PUNCT
eurjchem-2518	105	20	hreels	hreel	NOUN
eurjchem-2518	105	21	)	)	PUNCT
eurjchem-2518	105	22	spectra	spectra	NOUN
eurjchem-2518	105	23	at	at	ADP
eurjchem-2518	105	24	375	375	NUM
eurjchem-2518	105	25	and	and	CCONJ
eurjchem-2518	105	26	585	585	NUM
eurjchem-2518	105	27	cm-1	cm-1	NOUN
eurjchem-2518	105	28	,	,	PUNCT
eurjchem-2518	105	29	which	which	PRON
eurjchem-2518	105	30	indicates	indicate	VERB
eurjchem-2518	105	31	the	the	DET
eurjchem-2518	105	32	chemisorption	chemisorption	NOUN
eurjchem-2518	105	33	of	of	ADP
eurjchem-2518	105	34	h2s	h2s	NOUN
eurjchem-2518	105	35	with	with	ADP
eurjchem-2518	105	36	the	the	DET
eurjchem-2518	105	37	formation	formation	NOUN
eurjchem-2518	105	38	of	of	ADP
eurjchem-2518	105	39	a	a	DET
eurjchem-2518	105	40	pt	pt	PROPN
eurjchem-2518	105	41	–	–	PUNCT
eurjchem-2518	105	42	s	s	PART
eurjchem-2518	105	43	bond	bond	NOUN
eurjchem-2518	105	44	.	.	PUNCT
eurjchem-2518	106	1	after	after	ADP
eurjchem-2518	106	2	heating	heat	VERB
eurjchem-2518	106	3	to	to	ADP
eurjchem-2518	106	4	155	155	NUM
eurjchem-2518	106	5	k	k	NOUN
eurjchem-2518	106	6	,	,	PUNCT
eurjchem-2518	106	7	two	two	NUM
eurjchem-2518	106	8	additional	additional	ADJ
eurjchem-2518	106	9	bands	band	NOUN
eurjchem-2518	106	10	appear	appear	VERB
eurjchem-2518	106	11	in	in	ADP
eurjchem-2518	106	12	the	the	DET
eurjchem-2518	106	13	spectra	spectra	NOUN
eurjchem-2518	106	14	at	at	ADP
eurjchem-2518	106	15	585	585	NUM
eurjchem-2518	106	16	and	and	CCONJ
eurjchem-2518	106	17	685	685	NUM
eurjchem-2518	106	18	cm1	cm1	NOUN
eurjchem-2518	106	19	,	,	PUNCT
eurjchem-2518	106	20	which	which	PRON
eurjchem-2518	106	21	are	be	AUX
eurjchem-2518	106	22	attributed	attribute	VERB
eurjchem-2518	106	23	to	to	ADP
eurjchem-2518	106	24	two	two	NUM
eurjchem-2518	106	25	forms	form	NOUN
eurjchem-2518	106	26	of	of	ADP
eurjchem-2518	106	27	deformation	deformation	NOUN
eurjchem-2518	106	28	vibrations	vibration	NOUN
eurjchem-2518	106	29	of	of	ADP
eurjchem-2518	106	30	the	the	DET
eurjchem-2518	106	31	s	s	NOUN
eurjchem-2518	106	32	-	-	PUNCT
eurjchem-2518	106	33	h	h	NOUN
eurjchem-2518	106	34	bonds	bond	NOUN
eurjchem-2518	106	35	in	in	ADP
eurjchem-2518	106	36	the	the	DET
eurjchem-2518	106	37	surface	surface	NOUN
eurjchem-2518	106	38	structures	structure	NOUN
eurjchem-2518	106	39	.	.	PUNCT
eurjchem-2518	107	1	both	both	PRON
eurjchem-2518	107	2	of	of	ADP
eurjchem-2518	107	3	these	these	DET
eurjchem-2518	107	4	bands	band	NOUN
eurjchem-2518	107	5	disappear	disappear	VERB
eurjchem-2518	107	6	after	after	ADP
eurjchem-2518	107	7	heating	heat	VERB
eurjchem-2518	107	8	the	the	DET
eurjchem-2518	107	9	surface	surface	NOUN
eurjchem-2518	107	10	to	to	ADP
eurjchem-2518	107	11	185	185	NUM
eurjchem-2518	107	12	k	k	NOUN
eurjchem-2518	107	13	,	,	PUNCT
eurjchem-2518	107	14	while	while	SCONJ
eurjchem-2518	107	15	the	the	DET
eurjchem-2518	107	16	molecular	molecular	ADJ
eurjchem-2518	107	17	hydrogen	hydrogen	NOUN
eurjchem-2518	107	18	h2	h2	NOUN
eurjchem-2518	107	19	is	be	AUX
eurjchem-2518	107	20	desorbed	desorb	VERB
eurjchem-2518	107	21	into	into	ADP
eurjchem-2518	107	22	the	the	DET
eurjchem-2518	107	23	gas	gas	NOUN
eurjchem-2518	107	24	phase	phase	NOUN
eurjchem-2518	107	25	;	;	PUNCT
eurjchem-2518	107	26	however	however	ADV
eurjchem-2518	107	27	,	,	PUNCT
eurjchem-2518	107	28	a	a	DET
eurjchem-2518	107	29	single	single	ADJ
eurjchem-2518	107	30	band	band	NOUN
eurjchem-2518	107	31	375	375	NUM
eurjchem-2518	107	32	cm-1	cm-1	NOUN
eurjchem-2518	107	33	remains	remain	VERB
eurjchem-2518	107	34	in	in	ADP
eurjchem-2518	107	35	the	the	DET
eurjchem-2518	107	36	spectra	spectra	NOUN
eurjchem-2518	107	37	,	,	PUNCT
eurjchem-2518	107	38	attributed	attribute	VERB
eurjchem-2518	107	39	to	to	ADP
eurjchem-2518	107	40	the	the	DET
eurjchem-2518	107	41	pt	pt	PROPN
eurjchem-2518	107	42	-	-	PUNCT
eurjchem-2518	107	43	s	s	NOUN
eurjchem-2518	107	44	stretching	stretch	VERB
eurjchem-2518	107	45	mode	mode	NOUN
eurjchem-2518	107	46	of	of	ADP
eurjchem-2518	107	47	the	the	DET
eurjchem-2518	107	48	adsorbed	adsorb	VERB
eurjchem-2518	107	49	sulfur	sulfur	NOUN
eurjchem-2518	107	50	.	.	PUNCT
eurjchem-2518	108	1	the	the	DET
eurjchem-2518	108	2	chemical	chemical	ADJ
eurjchem-2518	108	3	state	state	NOUN
eurjchem-2518	108	4	of	of	ADP
eurjchem-2518	108	5	this	this	DET
eurjchem-2518	108	6	monatomic	monatomic	ADJ
eurjchem-2518	108	7	sulfur	sulfur	NOUN
eurjchem-2518	108	8	is	be	AUX
eurjchem-2518	108	9	not	not	PART
eurjchem-2518	108	10	discussed	discuss	VERB
eurjchem-2518	108	11	in	in	ADP
eurjchem-2518	108	12	the	the	DET
eurjchem-2518	108	13	article	article	NOUN
eurjchem-2518	108	14	[	[	X
eurjchem-2518	108	15	20	20	NUM
eurjchem-2518	108	16	]	]	PUNCT
eurjchem-2518	108	17	,	,	PUNCT
eurjchem-2518	108	18	so	so	ADV
eurjchem-2518	108	19	let	let	VERB
eurjchem-2518	108	20	us	we	PRON
eurjchem-2518	108	21	try	try	VERB
eurjchem-2518	108	22	to	to	PART
eurjchem-2518	108	23	understand	understand	VERB
eurjchem-2518	108	24	its	its	PRON
eurjchem-2518	108	25	nature	nature	NOUN
eurjchem-2518	108	26	based	base	VERB
eurjchem-2518	108	27	on	on	ADP
eurjchem-2518	108	28	the	the	DET
eurjchem-2518	108	29	well	well	ADV
eurjchem-2518	108	30	-	-	PUNCT
eurjchem-2518	108	31	known	know	VERB
eurjchem-2518	108	32	chemical	chemical	NOUN
eurjchem-2518	108	33	properties	property	NOUN
eurjchem-2518	108	34	of	of	ADP
eurjchem-2518	108	35	h2s	h2s	NOUN
eurjchem-2518	108	36	.	.	PUNCT
eurjchem-2518	109	1	the	the	DET
eurjchem-2518	109	2	fact	fact	NOUN
eurjchem-2518	109	3	is	be	AUX
eurjchem-2518	109	4	that	that	SCONJ
eurjchem-2518	109	5	the	the	DET
eurjchem-2518	109	6	appearance	appearance	NOUN
eurjchem-2518	109	7	of	of	ADP
eurjchem-2518	109	8	molecular	molecular	ADJ
eurjchem-2518	109	9	hydrogen	hydrogen	NOUN
eurjchem-2518	109	10	in	in	ADP
eurjchem-2518	109	11	the	the	DET
eurjchem-2518	109	12	gas	gas	NOUN
eurjchem-2518	109	13	phase	phase	NOUN
eurjchem-2518	109	14	should	should	AUX
eurjchem-2518	109	15	be	be	AUX
eurjchem-2518	109	16	caused	cause	VERB
eurjchem-2518	109	17	by	by	ADP
eurjchem-2518	109	18	the	the	DET
eurjchem-2518	109	19	decomposition	decomposition	NOUN
eurjchem-2518	109	20	reaction	reaction	NOUN
eurjchem-2518	109	21	of	of	ADP
eurjchem-2518	109	22	h2s	h2s	NOUN
eurjchem-2518	109	23	,	,	PUNCT
eurjchem-2518	109	24	leading	lead	VERB
eurjchem-2518	109	25	to	to	ADP
eurjchem-2518	109	26	the	the	DET
eurjchem-2518	109	27	formation	formation	NOUN
eurjchem-2518	109	28	of	of	ADP
eurjchem-2518	109	29	surface	surface	NOUN
eurjchem-2518	109	30	monatomic	monatomic	ADJ
eurjchem-2518	109	31	sulfur	sulfur	NOUN
eurjchem-2518	109	32	(	(	PUNCT
eurjchem-2518	109	33	reaction	reaction	NOUN
eurjchem-2518	109	34	4	4	NUM
eurjchem-2518	109	35	)	)	PUNCT
eurjchem-2518	110	1	[	[	X
eurjchem-2518	110	2	s0]adsh2	s0]adsh2	ADJ
eurjchem-2518	110	3	(	(	PUNCT
eurjchem-2518	110	4	g	g	NOUN
eurjchem-2518	110	5	)	)	PUNCT
eurjchem-2518	110	6	pt	pt	PROPN
eurjchem-2518	110	7	,	,	PUNCT
eurjchem-2518	110	8	185	185	NUM
eurjchem-2518	110	9	k	k	PROPN
eurjchem-2518	110	10	h2s	h2s	PROPN
eurjchem-2518	110	11	(	(	PUNCT
eurjchem-2518	110	12	4	4	NUM
eurjchem-2518	110	13	)	)	PUNCT
eurjchem-2518	110	14	which	which	PRON
eurjchem-2518	110	15	should	should	AUX
eurjchem-2518	110	16	be	be	AUX
eurjchem-2518	110	17	resulted	result	VERB
eurjchem-2518	110	18	in	in	ADP
eurjchem-2518	110	19	the	the	DET
eurjchem-2518	110	20	formation	formation	NOUN
eurjchem-2518	110	21	of	of	ADP
eurjchem-2518	110	22	the	the	DET
eurjchem-2518	110	23	surface	surface	NOUN
eurjchem-2518	110	24	platinum	platinum	NOUN
eurjchem-2518	110	25	sulfide	sulfide	NOUN
eurjchem-2518	110	26	{	{	PUNCT
eurjchem-2518	110	27	pts	pts	NOUN
eurjchem-2518	110	28	}	}	PUNCT
eurjchem-2518	110	29	,	,	PUNCT
eurjchem-2518	110	30	as	as	SCONJ
eurjchem-2518	110	31	required	require	VERB
eurjchem-2518	110	32	by	by	ADP
eurjchem-2518	110	33	the	the	DET
eurjchem-2518	110	34	stoichiometric	stoichiometric	ADJ
eurjchem-2518	110	35	chemical	chemical	NOUN
eurjchem-2518	110	36	reaction	reaction	NOUN
eurjchem-2518	110	37	of	of	ADP
eurjchem-2518	110	38	platinum	platinum	NOUN
eurjchem-2518	110	39	oxidation	oxidation	NOUN
eurjchem-2518	110	40	with	with	ADP
eurjchem-2518	110	41	h2s	h2s	NOUN
eurjchem-2518	110	42	.	.	PUNCT
eurjchem-2518	111	1	however	however	ADV
eurjchem-2518	111	2	,	,	PUNCT
eurjchem-2518	111	3	it	it	PRON
eurjchem-2518	111	4	is	be	AUX
eurjchem-2518	111	5	well	well	ADV
eurjchem-2518	111	6	known	know	VERB
eurjchem-2518	111	7	that	that	SCONJ
eurjchem-2518	111	8	h2s	h2s	NOUN
eurjchem-2518	111	9	exhibits	exhibit	VERB
eurjchem-2518	111	10	only	only	ADV
eurjchem-2518	111	11	reducing	reduce	VERB
eurjchem-2518	111	12	properties	property	NOUN
eurjchem-2518	111	13	(	(	PUNCT
eurjchem-2518	111	14	as	as	ADP
eurjchem-2518	111	15	,	,	PUNCT
eurjchem-2518	111	16	indeed	indeed	ADV
eurjchem-2518	111	17	,	,	PUNCT
eurjchem-2518	111	18	all	all	DET
eurjchem-2518	111	19	metals	metal	NOUN
eurjchem-2518	111	20	)	)	PUNCT
eurjchem-2518	111	21	since	since	SCONJ
eurjchem-2518	111	22	sulfur	sulfur	NOUN
eurjchem-2518	111	23	is	be	AUX
eurjchem-2518	111	24	in	in	ADP
eurjchem-2518	111	25	the	the	DET
eurjchem-2518	111	26	lowest	low	ADJ
eurjchem-2518	111	27	oxidation	oxidation	NOUN
eurjchem-2518	111	28	state	state	NOUN
eurjchem-2518	111	29	,	,	PUNCT
eurjchem-2518	111	30	hence	hence	ADV
eurjchem-2518	111	31	the	the	DET
eurjchem-2518	111	32	reaction	reaction	NOUN
eurjchem-2518	111	33	above	above	ADV
eurjchem-2518	111	34	must	must	AUX
eurjchem-2518	111	35	be	be	AUX
eurjchem-2518	111	36	a	a	DET
eurjchem-2518	111	37	catalytic	catalytic	ADJ
eurjchem-2518	111	38	one	one	NOUN
eurjchem-2518	111	39	with	with	ADP
eurjchem-2518	111	40	the	the	DET
eurjchem-2518	111	41	formation	formation	NOUN
eurjchem-2518	111	42	of	of	ADP
eurjchem-2518	111	43	atomic	atomic	ADJ
eurjchem-2518	111	44	zero	zero	NUM
eurjchem-2518	111	45	-	-	PUNCT
eurjchem-2518	111	46	valence	valence	NOUN
eurjchem-2518	111	47	sulfur	sulfur	NOUN
eurjchem-2518	111	48	as	as	ADP
eurjchem-2518	111	49	a	a	DET
eurjchem-2518	111	50	product	product	NOUN
eurjchem-2518	111	51	of	of	ADP
eurjchem-2518	111	52	h2s	h2s	NOUN
eurjchem-2518	111	53	decomposition	decomposition	NOUN
eurjchem-2518	111	54	.	.	PUNCT
eurjchem-2518	112	1	this	this	PRON
eurjchem-2518	112	2	applies	apply	VERB
eurjchem-2518	112	3	to	to	ADP
eurjchem-2518	112	4	all	all	DET
eurjchem-2518	112	5	transition	transition	NOUN
eurjchem-2518	112	6	metals	metal	NOUN
eurjchem-2518	112	7	.	.	PUNCT
eurjchem-2518	113	1	at	at	ADP
eurjchem-2518	113	2	ambient	ambient	ADJ
eurjchem-2518	113	3	temperature	temperature	NOUN
eurjchem-2518	113	4	and	and	CCONJ
eurjchem-2518	113	5	pressure	pressure	NOUN
eurjchem-2518	113	6	,	,	PUNCT
eurjchem-2518	113	7	the	the	DET
eurjchem-2518	113	8	h2s	h2s	NOUN
eurjchem-2518	113	9	molecule	molecule	NOUN
eurjchem-2518	113	10	is	be	AUX
eurjchem-2518	113	11	stable	stable	ADJ
eurjchem-2518	113	12	indefinitely	indefinitely	ADV
eurjchem-2518	113	13	for	for	ADP
eurjchem-2518	113	14	a	a	DET
eurjchem-2518	113	15	long	long	ADJ
eurjchem-2518	113	16	time	time	NOUN
eurjchem-2518	113	17	in	in	ADP
eurjchem-2518	113	18	the	the	DET
eurjchem-2518	113	19	absence	absence	NOUN
eurjchem-2518	113	20	of	of	ADP
eurjchem-2518	113	21	external	external	ADJ
eurjchem-2518	113	22	influences	influence	NOUN
eurjchem-2518	113	23	.	.	PUNCT
eurjchem-2518	114	1	however	however	ADV
eurjchem-2518	114	2	,	,	PUNCT
eurjchem-2518	114	3	we	we	PRON
eurjchem-2518	114	4	found	find	VERB
eurjchem-2518	114	5	[	[	X
eurjchem-2518	114	6	21	21	NUM
eurjchem-2518	114	7	-	-	SYM
eurjchem-2518	114	8	23	23	NUM
eurjchem-2518	114	9	]	]	PUNCT
eurjchem-2518	114	10	that	that	SCONJ
eurjchem-2518	114	11	if	if	SCONJ
eurjchem-2518	114	12	h2s	h2s	PROPN
eurjchem-2518	114	13	passes	pass	VERB
eurjchem-2518	114	14	through	through	ADP
eurjchem-2518	114	15	a	a	DET
eurjchem-2518	114	16	metal	metal	NOUN
eurjchem-2518	114	17	catalyst	catalyst	NOUN
eurjchem-2518	114	18	at	at	ADP
eurjchem-2518	114	19	room	room	NOUN
eurjchem-2518	114	20	temperature	temperature	NOUN
eurjchem-2518	114	21	,	,	PUNCT
eurjchem-2518	114	22	then	then	ADV
eurjchem-2518	114	23	hydrogen	hydrogen	NOUN
eurjchem-2518	114	24	and	and	CCONJ
eurjchem-2518	114	25	gaseous	gaseous	ADJ
eurjchem-2518	114	26	diatomic	diatomic	ADJ
eurjchem-2518	114	27	sulfur	sulfur	NOUN
eurjchem-2518	114	28	are	be	AUX
eurjchem-2518	114	29	produced	produce	VERB
eurjchem-2518	114	30	at	at	ADP
eurjchem-2518	114	31	the	the	DET
eurjchem-2518	114	32	outlet	outlet	NOUN
eurjchem-2518	114	33	.	.	PUNCT
eurjchem-2518	115	1	190	190	NUM
eurjchem-2518	115	2	anatolii	anatolii	NOUN
eurjchem-2518	115	3	startsev	startsev	NOUN
eurjchem-2518	115	4	/	/	SYM
eurjchem-2518	115	5	european	european	ADJ
eurjchem-2518	115	6	journal	journal	PROPN
eurjchem-2518	115	7	of	of	ADP
eurjchem-2518	115	8	chemistry	chemistry	NOUN
eurjchem-2518	115	9	15	15	NUM
eurjchem-2518	115	10	(	(	PUNCT
eurjchem-2518	115	11	2	2	NUM
eurjchem-2518	115	12	)	)	PUNCT
eurjchem-2518	115	13	(	(	PUNCT
eurjchem-2518	115	14	2024	2024	NUM
eurjchem-2518	115	15	)	)	PUNCT
eurjchem-2518	115	16	186	186	NUM
eurjchem-2518	115	17	-	-	SYM
eurjchem-2518	115	18	193	193	NUM
eurjchem-2518	115	19	2024	2024	NUM
eurjchem-2518	115	20	–	–	PUNCT
eurjchem-2518	115	21	european	european	ADJ
eurjchem-2518	115	22	journal	journal	NOUN
eurjchem-2518	115	23	of	of	ADP
eurjchem-2518	115	24	chemistry	chemistry	NOUN
eurjchem-2518	115	25	–	–	PUNCT
eurjchem-2518	115	26	cc	cc	NOUN
eurjchem-2518	115	27	by	by	ADP
eurjchem-2518	115	28	nc	nc	PROPN
eurjchem-2518	115	29	–	–	PUNCT
eurjchem-2518	115	30	doi	doi	NOUN
eurjchem-2518	115	31	:	:	PUNCT
eurjchem-2518	115	32	10.5155	10.5155	NUM
eurjchem-2518	115	33	/	/	SYM
eurjchem-2518	115	34	eurjchem.15.2.186	eurjchem.15.2.186	VERB
eurjchem-2518	115	35	-	-	PUNCT
eurjchem-2518	115	36	193.2518	193.2518	NUM
eurjchem-2518	115	37	table	table	NOUN
eurjchem-2518	115	38	2	2	NUM
eurjchem-2518	115	39	.	.	PUNCT
eurjchem-2518	115	40	dft	dft	PROPN
eurjchem-2518	115	41	calculation	calculation	NOUN
eurjchem-2518	115	42	of	of	ADP
eurjchem-2518	115	43	energy	energy	NOUN
eurjchem-2518	115	44	adsorption	adsorption	NOUN
eurjchem-2518	115	45	and	and	CCONJ
eurjchem-2518	115	46	dissociation	dissociation	NOUN
eurjchem-2518	115	47	of	of	ADP
eurjchem-2518	115	48	h2s	h2s	NOUN
eurjchem-2518	115	49	molecules	molecule	NOUN
eurjchem-2518	115	50	on	on	ADP
eurjchem-2518	115	51	the	the	DET
eurjchem-2518	115	52	surface	surface	NOUN
eurjchem-2518	115	53	of	of	ADP
eurjchem-2518	115	54	selected	select	VERB
eurjchem-2518	115	55	metals	metal	NOUN
eurjchem-2518	115	56	(	(	PUNCT
eurjchem-2518	115	57	kcal	kcal	NOUN
eurjchem-2518	115	58	/	/	SYM
eurjchem-2518	115	59	mol	mol	NOUN
eurjchem-2518	115	60	)	)	PUNCT
eurjchem-2518	115	61	.	.	PUNCT
eurjchem-2518	116	1	no	no	DET
eurjchem-2518	116	2	stage	stage	NOUN
eurjchem-2518	116	3	pt(111	pt(111	ADJ
eurjchem-2518	116	4	)	)	PUNCT
eurjchem-2518	116	5	ni(111	ni(111	NUM
eurjchem-2518	116	6	)	)	PUNCT
eurjchem-2518	116	7	ni(111	ni(111	NUM
eurjchem-2518	116	8	)	)	PUNCT
eurjchem-2518	116	9	(	(	PUNCT
eurjchem-2518	116	10	ni	ni	PROPN
eurjchem-2518	116	11	-	-	PUNCT
eurjchem-2518	116	12	mo	mo	NOUN
eurjchem-2518	116	13	)	)	PUNCT
eurjchem-2518	116	14	pd(111	pd(111	NOUN
eurjchem-2518	116	15	)	)	PUNCT
eurjchem-2518	116	16	pd(111	pd(111	NOUN
eurjchem-2518	116	17	)	)	PUNCT
eurjchem-2518	116	18	cu(111	cu(111	NOUN
eurjchem-2518	116	19	)	)	PUNCT
eurjchem-2518	116	20	fe(100	fe(100	NOUN
eurjchem-2518	116	21	)	)	PUNCT
eurjchem-2518	116	22	cu(111	cu(111	NOUN
eurjchem-2518	116	23	)	)	PUNCT
eurjchem-2518	116	24	ni(110	ni(110	PROPN
eurjchem-2518	116	25	)	)	PUNCT
eurjchem-2518	116	26	fe(110	fe(110	NOUN
eurjchem-2518	116	27	)	)	PUNCT
eurjchem-2518	116	28	i	i	PRON
eurjchem-2518	116	29	h2s	h2s	NOUN
eurjchem-2518	116	30	→	→	SYM
eurjchem-2518	116	31	h2s(ads	h2s(ad	NOUN
eurjchem-2518	116	32	)	)	PUNCT
eurjchem-2518	116	33	−21.0	−21.0	PROPN
eurjchem-2518	116	34	−12.9	−12.9	NOUN
eurjchem-2518	116	35	−12.6	−12.6	PROPN
eurjchem-2518	116	36	−18.4	−18.4	PUNCT
eurjchem-2518	116	37	−16.4	−16.4	PROPN
eurjchem-2518	116	38	−12.0	−12.0	PROPN
eurjchem-2518	116	39	−6.0	−6.0	PROPN
eurjchem-2518	116	40	−10.6	−10.6	NOUN
eurjchem-2518	116	41	−5.3	−5.3	NOUN
eurjchem-2518	116	42	−15.9	−15.9	VERB
eurjchem-2518	116	43	−13.6	−13.6	PROPN
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eurjchem-2518	117	11	)	)	PUNCT
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eurjchem-2518	119	1	+	+	CCONJ
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eurjchem-2518	120	11	25	25	NUM
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eurjchem-2518	121	1	[	[	X
eurjchem-2518	121	2	25	25	NUM
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eurjchem-2518	121	8	26	26	NUM
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eurjchem-2518	121	10	[	[	X
eurjchem-2518	121	11	27	27	NUM
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eurjchem-2518	122	1	[	[	X
eurjchem-2518	122	2	28	28	NUM
eurjchem-2518	122	3	]	]	X
eurjchem-2518	123	1	[	[	X
eurjchem-2518	123	2	29	29	NUM
eurjchem-2518	123	3	]	]	X
eurjchem-2518	124	1	[	[	X
eurjchem-2518	124	2	30	30	NUM
eurjchem-2518	124	3	]	]	X
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eurjchem-2518	125	3	]	]	PUNCT
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eurjchem-2518	126	3	]	]	PUNCT
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eurjchem-2518	126	6	,	,	PUNCT
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eurjchem-2518	126	10	,	,	PUNCT
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eurjchem-2518	127	13	,	,	PUNCT
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eurjchem-2518	127	18	time	time	NOUN
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eurjchem-2518	127	22	energy	energy	NOUN
eurjchem-2518	127	23	are	be	AUX
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eurjchem-2518	127	26	the	the	DET
eurjchem-2518	127	27	environment	environment	NOUN
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eurjchem-2518	127	30	,	,	PUNCT
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eurjchem-2518	127	32	h2s	h2s	NOUN
eurjchem-2518	127	33	decomposition	decomposition	NOUN
eurjchem-2518	127	34	reaction	reaction	NOUN
eurjchem-2518	127	35	proceeds	proceed	NOUN
eurjchem-2518	127	36	due	due	ADP
eurjchem-2518	127	37	to	to	ADP
eurjchem-2518	127	38	the	the	DET
eurjchem-2518	127	39	free	free	ADJ
eurjchem-2518	127	40	and	and	CCONJ
eurjchem-2518	127	41	internal	internal	ADJ
eurjchem-2518	127	42	energy	energy	NOUN
eurjchem-2518	127	43	of	of	ADP
eurjchem-2518	127	44	the	the	DET
eurjchem-2518	127	45	h2s	h2s	NOUN
eurjchem-2518	127	46	molecule	molecule	NOUN
eurjchem-2518	127	47	,	,	PUNCT
eurjchem-2518	127	48	as	as	SCONJ
eurjchem-2518	127	49	is	be	AUX
eurjchem-2518	127	50	the	the	DET
eurjchem-2518	127	51	case	case	NOUN
eurjchem-2518	127	52	in	in	ADP
eurjchem-2518	127	53	biological	biological	ADJ
eurjchem-2518	127	54	systems	system	NOUN
eurjchem-2518	127	55	(	(	PUNCT
eurjchem-2518	127	56	reaction	reaction	NOUN
eurjchem-2518	127	57	5	5	NUM
eurjchem-2518	127	58	):	):	PUNCT
eurjchem-2518	127	59	2	2	NUM
eurjchem-2518	127	60	h2s	h2s	NOUN
eurjchem-2518	127	61	3s2(g)2	3s2(g)2	NUM
eurjchem-2518	127	62	h2	h2	NOUN
eurjchem-2518	127	63	(	(	PUNCT
eurjchem-2518	127	64	g	g	NOUN
eurjchem-2518	127	65	)	)	PUNCT
eurjchem-2518	127	66	metal	metal	NOUN
eurjchem-2518	127	67	catalyst	catalyst	NOUN
eurjchem-2518	127	68	,	,	PUNCT
eurjchem-2518	127	69	25	25	NUM
eurjchem-2518	127	70	oc	oc	NOUN
eurjchem-2518	127	71	(	(	PUNCT
eurjchem-2518	127	72	5	5	NUM
eurjchem-2518	127	73	)	)	PUNCT
eurjchem-2518	127	74	the	the	DET
eurjchem-2518	127	75	process	process	NOUN
eurjchem-2518	127	76	is	be	AUX
eurjchem-2518	127	77	irreversible	irreversible	ADJ
eurjchem-2518	127	78	;	;	PUNCT
eurjchem-2518	127	79	in	in	ADP
eurjchem-2518	127	80	a	a	DET
eurjchem-2518	127	81	stationary	stationary	ADJ
eurjchem-2518	127	82	state	state	NOUN
eurjchem-2518	127	83	in	in	ADP
eurjchem-2518	127	84	the	the	DET
eurjchem-2518	127	85	gas	gas	NOUN
eurjchem-2518	127	86	phase	phase	NOUN
eurjchem-2518	127	87	at	at	ADP
eurjchem-2518	127	88	room	room	NOUN
eurjchem-2518	127	89	temperature	temperature	NOUN
eurjchem-2518	127	90	and	and	CCONJ
eurjchem-2518	127	91	atmospheric	atmospheric	ADJ
eurjchem-2518	127	92	pressure	pressure	NOUN
eurjchem-2518	127	93	on	on	ADP
eurjchem-2518	127	94	metal	metal	NOUN
eurjchem-2518	127	95	catalysts	catalyst	NOUN
eurjchem-2518	127	96	,	,	PUNCT
eurjchem-2518	127	97	the	the	DET
eurjchem-2518	127	98	h2s	h2s	NOUN
eurjchem-2518	127	99	conversion	conversion	NOUN
eurjchem-2518	127	100	may	may	AUX
eurjchem-2518	127	101	reach	reach	VERB
eurjchem-2518	127	102	100	100	NUM
eurjchem-2518	127	103	%	%	NOUN
eurjchem-2518	127	104	.	.	PUNCT
eurjchem-2518	128	1	the	the	DET
eurjchem-2518	128	2	unexpected	unexpected	ADJ
eurjchem-2518	128	3	product	product	NOUN
eurjchem-2518	128	4	of	of	ADP
eurjchem-2518	128	5	reaction	reaction	NOUN
eurjchem-2518	128	6	5	5	NUM
eurjchem-2518	128	7	turned	turn	VERB
eurjchem-2518	128	8	out	out	ADP
eurjchem-2518	128	9	to	to	PART
eurjchem-2518	128	10	be	be	AUX
eurjchem-2518	128	11	diatomic	diatomic	ADJ
eurjchem-2518	128	12	gaseous	gaseous	ADJ
eurjchem-2518	128	13	sulfur	sulfur	NOUN
eurjchem-2518	128	14	.	.	PUNCT
eurjchem-2518	129	1	a	a	DET
eurjchem-2518	129	2	thorough	thorough	ADJ
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eurjchem-2518	129	5	the	the	DET
eurjchem-2518	129	6	extensive	extensive	ADJ
eurjchem-2518	129	7	data	datum	NOUN
eurjchem-2518	129	8	in	in	ADP
eurjchem-2518	129	9	the	the	DET
eurjchem-2518	129	10	literature	literature	NOUN
eurjchem-2518	129	11	has	have	AUX
eurjchem-2518	129	12	shown	show	VERB
eurjchem-2518	129	13	that	that	SCONJ
eurjchem-2518	129	14	we	we	PRON
eurjchem-2518	129	15	have	have	AUX
eurjchem-2518	129	16	obtained	obtain	VERB
eurjchem-2518	129	17	diatomic	diatomic	ADJ
eurjchem-2518	129	18	sulfur	sulfur	NOUN
eurjchem-2518	129	19	for	for	ADP
eurjchem-2518	129	20	the	the	DET
eurjchem-2518	129	21	first	first	ADJ
eurjchem-2518	129	22	time	time	NOUN
eurjchem-2518	129	23	in	in	ADP
eurjchem-2518	129	24	the	the	DET
eurjchem-2518	129	25	ground	ground	NOUN
eurjchem-2518	129	26	triplet	triplet	NOUN
eurjchem-2518	129	27	state	state	NOUN
eurjchem-2518	129	28	{	{	PUNCT
eurjchem-2518	129	29	s2x	s2x	ADJ
eurjchem-2518	129	30	3σ	3σ	NOUN
eurjchem-2518	129	31	-	-	PUNCT
eurjchem-2518	129	32	g	g	NOUN
eurjchem-2518	129	33	}	}	PUNCT
eurjchem-2518	130	1	[	[	X
eurjchem-2518	130	2	22,23	22,23	NOUN
eurjchem-2518	130	3	]	]	PUNCT
eurjchem-2518	130	4	,	,	PUNCT
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eurjchem-2518	130	6	earlier	early	ADV
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eurjchem-2518	130	8	quantum	quantum	ADJ
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eurjchem-2518	130	12	isoelectronic	isoelectronic	ADJ
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eurjchem-2518	131	37	only	only	ADV
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eurjchem-2518	131	41	;	;	PUNCT
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eurjchem-2518	131	49	into	into	ADP
eurjchem-2518	131	50	“	"	PUNCT
eurjchem-2518	131	51	normal	normal	ADJ
eurjchem-2518	131	52	”	"	PUNCT
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eurjchem-2518	131	54	sulfur	sulfur	NOUN
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eurjchem-2518	132	5	by	by	ADP
eurjchem-2518	132	6	us	we	PRON
eurjchem-2518	132	7	using	use	VERB
eurjchem-2518	132	8	platinum	platinum	NOUN
eurjchem-2518	132	9	as	as	ADP
eurjchem-2518	132	10	a	a	DET
eurjchem-2518	132	11	catalyst	catalyst	NOUN
eurjchem-2518	132	12	.	.	PUNCT
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eurjchem-2518	133	2	,	,	PUNCT
eurjchem-2518	133	3	it	it	PRON
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eurjchem-2518	133	6	out	out	ADP
eurjchem-2518	133	7	that	that	SCONJ
eurjchem-2518	133	8	stainless	stainless	ADJ
eurjchem-2518	133	9	steel	steel	NOUN
eurjchem-2518	133	10	chips	chip	NOUN
eurjchem-2518	133	11	of	of	ADP
eurjchem-2518	133	12	chemical	chemical	ADJ
eurjchem-2518	133	13	composition	composition	NOUN
eurjchem-2518	133	14	(	(	PUNCT
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eurjchem-2518	133	24	to	to	PART
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eurjchem-2518	134	8	dispersed	disperse	VERB
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eurjchem-2518	134	12	a	a	DET
eurjchem-2518	134	13	similar	similar	ADJ
eurjchem-2518	134	14	chemical	chemical	NOUN
eurjchem-2518	134	15	constituent	constituent	NOUN
eurjchem-2518	134	16	supported	support	VERB
eurjchem-2518	134	17	on	on	ADP
eurjchem-2518	134	18	various	various	ADJ
eurjchem-2518	134	19	carriers	carrier	NOUN
eurjchem-2518	134	20	silica	silica	NOUN
eurjchem-2518	134	21	,	,	PUNCT
eurjchem-2518	134	22	alumina	alumina	NOUN
eurjchem-2518	134	23	,	,	PUNCT
eurjchem-2518	134	24	carbon	carbon	NOUN
eurjchem-2518	134	25	support	support	NOUN
eurjchem-2518	134	26	sibunit	sibunit	NOUN
eurjchem-2518	134	27	,	,	PUNCT
eurjchem-2518	134	28	etc	etc	X
eurjchem-2518	134	29	.	.	X
eurjchem-2518	134	30	for	for	ADP
eurjchem-2518	134	31	all	all	DET
eurjchem-2518	134	32	catalytic	catalytic	ADJ
eurjchem-2518	134	33	systems	system	NOUN
eurjchem-2518	134	34	mentioned	mention	VERB
eurjchem-2518	134	35	,	,	PUNCT
eurjchem-2518	134	36	we	we	PRON
eurjchem-2518	134	37	observed	observe	VERB
eurjchem-2518	134	38	similar	similar	ADJ
eurjchem-2518	134	39	patterns	pattern	NOUN
eurjchem-2518	134	40	of	of	ADP
eurjchem-2518	134	41	h2s	h2s	NOUN
eurjchem-2518	134	42	decomposition	decomposition	NOUN
eurjchem-2518	134	43	.	.	PUNCT
eurjchem-2518	135	1	moreover	moreover	ADV
eurjchem-2518	135	2	,	,	PUNCT
eurjchem-2518	135	3	we	we	PRON
eurjchem-2518	135	4	have	have	AUX
eurjchem-2518	135	5	discovered	discover	VERB
eurjchem-2518	135	6	a	a	DET
eurjchem-2518	135	7	number	number	NOUN
eurjchem-2518	135	8	of	of	ADP
eurjchem-2518	135	9	new	new	ADJ
eurjchem-2518	135	10	catalytic	catalytic	ADJ
eurjchem-2518	135	11	compositions	composition	NOUN
eurjchem-2518	135	12	that	that	PRON
eurjchem-2518	135	13	also	also	ADV
eurjchem-2518	135	14	follow	follow	VERB
eurjchem-2518	135	15	general	general	ADJ
eurjchem-2518	135	16	rules	rule	NOUN
eurjchem-2518	135	17	;	;	PUNCT
eurjchem-2518	135	18	therefore	therefore	ADV
eurjchem-2518	135	19	,	,	PUNCT
eurjchem-2518	135	20	they	they	PRON
eurjchem-2518	135	21	are	be	AUX
eurjchem-2518	135	22	registered	register	VERB
eurjchem-2518	135	23	in	in	ADP
eurjchem-2518	135	24	our	our	PRON
eurjchem-2518	135	25	patent	patent	NOUN
eurjchem-2518	135	26	[	[	X
eurjchem-2518	135	27	24	24	NUM
eurjchem-2518	135	28	]	]	PUNCT
eurjchem-2518	135	29	.	.	PUNCT
eurjchem-2518	136	1	in	in	ADP
eurjchem-2518	136	2	recent	recent	ADJ
eurjchem-2518	136	3	times	time	NOUN
eurjchem-2518	136	4	,	,	PUNCT
eurjchem-2518	136	5	numerous	numerous	ADJ
eurjchem-2518	136	6	experimental	experimental	ADJ
eurjchem-2518	136	7	and	and	CCONJ
eurjchem-2518	136	8	theoretical	theoretical	ADJ
eurjchem-2518	136	9	studies	study	NOUN
eurjchem-2518	136	10	of	of	ADP
eurjchem-2518	136	11	the	the	DET
eurjchem-2518	136	12	h2s	h2s	NOUN
eurjchem-2518	136	13	interaction	interaction	NOUN
eurjchem-2518	136	14	with	with	ADP
eurjchem-2518	136	15	the	the	DET
eurjchem-2518	136	16	surface	surface	NOUN
eurjchem-2518	136	17	of	of	ADP
eurjchem-2518	136	18	various	various	ADJ
eurjchem-2518	136	19	metals	metal	NOUN
eurjchem-2518	136	20	have	have	AUX
eurjchem-2518	136	21	appeared	appear	VERB
eurjchem-2518	136	22	.	.	PUNCT
eurjchem-2518	137	1	these	these	DET
eurjchem-2518	137	2	works	work	NOUN
eurjchem-2518	137	3	primarily	primarily	ADV
eurjchem-2518	137	4	aim	aim	VERB
eurjchem-2518	137	5	to	to	PART
eurjchem-2518	137	6	understand	understand	VERB
eurjchem-2518	137	7	the	the	DET
eurjchem-2518	137	8	mechanisms	mechanism	NOUN
eurjchem-2518	137	9	of	of	ADP
eurjchem-2518	137	10	deactivation	deactivation	NOUN
eurjchem-2518	137	11	and	and	CCONJ
eurjchem-2518	137	12	inhibition	inhibition	NOUN
eurjchem-2518	137	13	of	of	ADP
eurjchem-2518	137	14	the	the	DET
eurjchem-2518	137	15	properties	property	NOUN
eurjchem-2518	137	16	of	of	ADP
eurjchem-2518	137	17	metal	metal	NOUN
eurjchem-2518	137	18	catalysts	catalyst	NOUN
eurjchem-2518	137	19	as	as	ADV
eurjchem-2518	137	20	well	well	ADV
eurjchem-2518	137	21	as	as	ADP
eurjchem-2518	137	22	their	their	PRON
eurjchem-2518	137	23	toxic	toxic	ADJ
eurjchem-2518	137	24	effects	effect	NOUN
eurjchem-2518	137	25	on	on	ADP
eurjchem-2518	137	26	membranes	membrane	NOUN
eurjchem-2518	137	27	.	.	PUNCT
eurjchem-2518	138	1	the	the	DET
eurjchem-2518	138	2	main	main	ADJ
eurjchem-2518	138	3	conclusion	conclusion	NOUN
eurjchem-2518	138	4	from	from	ADP
eurjchem-2518	138	5	all	all	DET
eurjchem-2518	138	6	these	these	DET
eurjchem-2518	138	7	studies	study	NOUN
eurjchem-2518	138	8	is	be	AUX
eurjchem-2518	138	9	that	that	SCONJ
eurjchem-2518	138	10	h2s	h2s	NOUN
eurjchem-2518	138	11	easily	easily	ADV
eurjchem-2518	138	12	dissociates	dissociate	NOUN
eurjchem-2518	138	13	on	on	ADP
eurjchem-2518	138	14	most	most	ADJ
eurjchem-2518	138	15	metals	metal	NOUN
eurjchem-2518	138	16	already	already	ADV
eurjchem-2518	138	17	at	at	ADP
eurjchem-2518	138	18	very	very	ADV
eurjchem-2518	138	19	low	low	ADJ
eurjchem-2518	138	20	temperatures	temperature	NOUN
eurjchem-2518	138	21	(	(	PUNCT
eurjchem-2518	138	22	generally	generally	ADV
eurjchem-2518	138	23	below	below	ADP
eurjchem-2518	138	24	185	185	NUM
eurjchem-2518	138	25	k	k	NOUN
eurjchem-2518	138	26	)	)	PUNCT
eurjchem-2518	139	1	[	[	X
eurjchem-2518	139	2	25	25	NUM
eurjchem-2518	139	3	]	]	PUNCT
eurjchem-2518	139	4	.	.	PUNCT
eurjchem-2518	140	1	table	table	NOUN
eurjchem-2518	140	2	2	2	NUM
eurjchem-2518	140	3	presents	present	VERB
eurjchem-2518	140	4	the	the	DET
eurjchem-2518	140	5	results	result	NOUN
eurjchem-2518	140	6	of	of	ADP
eurjchem-2518	140	7	the	the	DET
eurjchem-2518	140	8	dft	dft	PROPN
eurjchem-2518	140	9	studies	study	NOUN
eurjchem-2518	140	10	of	of	ADP
eurjchem-2518	140	11	h2s	h2s	NOUN
eurjchem-2518	140	12	dissociation	dissociation	NOUN
eurjchem-2518	140	13	on	on	ADP
eurjchem-2518	140	14	the	the	DET
eurjchem-2518	140	15	surface	surface	NOUN
eurjchem-2518	140	16	of	of	ADP
eurjchem-2518	140	17	some	some	DET
eurjchem-2518	140	18	metals	metal	NOUN
eurjchem-2518	140	19	[	[	X
eurjchem-2518	140	20	25	25	NUM
eurjchem-2518	140	21	-	-	SYM
eurjchem-2518	140	22	32	32	NUM
eurjchem-2518	140	23	]	]	PUNCT
eurjchem-2518	140	24	.	.	PUNCT
eurjchem-2518	141	1	a	a	DET
eurjchem-2518	141	2	characteristic	characteristic	ADJ
eurjchem-2518	141	3	feature	feature	NOUN
eurjchem-2518	141	4	of	of	ADP
eurjchem-2518	141	5	h2s	h2s	NOUN
eurjchem-2518	141	6	adsorption	adsorption	NOUN
eurjchem-2518	141	7	on	on	ADP
eurjchem-2518	141	8	the	the	DET
eurjchem-2518	141	9	surface	surface	NOUN
eurjchem-2518	141	10	of	of	ADP
eurjchem-2518	141	11	transition	transition	NOUN
eurjchem-2518	141	12	metals	metal	NOUN
eurjchem-2518	141	13	is	be	AUX
eurjchem-2518	141	14	that	that	SCONJ
eurjchem-2518	141	15	the	the	DET
eurjchem-2518	141	16	chemisorption	chemisorption	NOUN
eurjchem-2518	141	17	stage	stage	NOUN
eurjchem-2518	141	18	is	be	AUX
eurjchem-2518	141	19	accompanied	accompany	VERB
eurjchem-2518	141	20	by	by	ADP
eurjchem-2518	141	21	a	a	DET
eurjchem-2518	141	22	further	further	ADJ
eurjchem-2518	141	23	process	process	NOUN
eurjchem-2518	141	24	of	of	ADP
eurjchem-2518	141	25	its	its	PRON
eurjchem-2518	141	26	dissociation	dissociation	NOUN
eurjchem-2518	141	27	,	,	PUNCT
eurjchem-2518	141	28	leading	lead	VERB
eurjchem-2518	141	29	to	to	ADP
eurjchem-2518	141	30	the	the	DET
eurjchem-2518	141	31	formation	formation	NOUN
eurjchem-2518	141	32	of	of	ADP
eurjchem-2518	141	33	surface	surface	NOUN
eurjchem-2518	141	34	atomic	atomic	ADJ
eurjchem-2518	141	35	species	specie	NOUN
eurjchem-2518	141	36	.	.	PUNCT
eurjchem-2518	142	1	dissociation	dissociation	NOUN
eurjchem-2518	142	2	occurs	occur	VERB
eurjchem-2518	142	3	in	in	ADP
eurjchem-2518	142	4	two	two	NUM
eurjchem-2518	142	5	stages	stage	NOUN
eurjchem-2518	142	6	;	;	PUNCT
eurjchem-2518	142	7	each	each	PRON
eurjchem-2518	142	8	of	of	ADP
eurjchem-2518	142	9	these	these	DET
eurjchem-2518	142	10	exothermic	exothermic	ADJ
eurjchem-2518	142	11	stages	stage	NOUN
eurjchem-2518	142	12	occurs	occur	VERB
eurjchem-2518	142	13	through	through	ADP
eurjchem-2518	142	14	a	a	DET
eurjchem-2518	142	15	small	small	ADJ
eurjchem-2518	142	16	energy	energy	NOUN
eurjchem-2518	142	17	barrier	barrier	NOUN
eurjchem-2518	142	18	and	and	CCONJ
eurjchem-2518	142	19	leads	lead	VERB
eurjchem-2518	142	20	to	to	ADP
eurjchem-2518	142	21	energy	energy	NOUN
eurjchem-2518	142	22	accumulation	accumulation	NOUN
eurjchem-2518	142	23	on	on	ADP
eurjchem-2518	142	24	the	the	DET
eurjchem-2518	142	25	metal	metal	NOUN
eurjchem-2518	142	26	surface	surface	NOUN
eurjchem-2518	142	27	.	.	PUNCT
eurjchem-2518	143	1	it	it	PRON
eurjchem-2518	143	2	is	be	AUX
eurjchem-2518	143	3	very	very	ADV
eurjchem-2518	143	4	important	important	ADJ
eurjchem-2518	143	5	that	that	SCONJ
eurjchem-2518	143	6	h2s	h2s	NOUN
eurjchem-2518	143	7	dissociation	dissociation	NOUN
eurjchem-2518	143	8	into	into	ADP
eurjchem-2518	143	9	atoms	atom	NOUN
eurjchem-2518	143	10	has	have	VERB
eurjchem-2518	143	11	neither	neither	CCONJ
eurjchem-2518	143	12	thermodynamic	thermodynamic	ADJ
eurjchem-2518	143	13	nor	nor	CCONJ
eurjchem-2518	143	14	kinetic	kinetic	ADJ
eurjchem-2518	143	15	limitations	limitation	NOUN
eurjchem-2518	143	16	.	.	PUNCT
eurjchem-2518	144	1	attention	attention	NOUN
eurjchem-2518	144	2	is	be	AUX
eurjchem-2518	144	3	drawn	draw	VERB
eurjchem-2518	144	4	to	to	ADP
eurjchem-2518	144	5	the	the	DET
eurjchem-2518	144	6	good	good	ADJ
eurjchem-2518	144	7	reproducibility	reproducibility	NOUN
eurjchem-2518	144	8	of	of	ADP
eurjchem-2518	144	9	the	the	DET
eurjchem-2518	144	10	calculation	calculation	NOUN
eurjchem-2518	144	11	results	result	VERB
eurjchem-2518	144	12	for	for	ADP
eurjchem-2518	144	13	the	the	DET
eurjchem-2518	144	14	same	same	ADJ
eurjchem-2518	144	15	systems	system	NOUN
eurjchem-2518	144	16	performed	perform	VERB
eurjchem-2518	144	17	by	by	ADP
eurjchem-2518	144	18	different	different	ADJ
eurjchem-2518	144	19	authors	author	NOUN
eurjchem-2518	144	20	.	.	PUNCT
eurjchem-2518	145	1	as	as	SCONJ
eurjchem-2518	145	2	already	already	ADV
eurjchem-2518	145	3	noted	note	VERB
eurjchem-2518	145	4	,	,	PUNCT
eurjchem-2518	145	5	metals	metal	NOUN
eurjchem-2518	145	6	like	like	ADP
eurjchem-2518	145	7	hydrogen	hydrogen	NOUN
eurjchem-2518	145	8	sulfide	sulfide	NOUN
eurjchem-2518	145	9	are	be	AUX
eurjchem-2518	145	10	reducing	reduce	VERB
eurjchem-2518	145	11	agents	agent	NOUN
eurjchem-2518	145	12	;	;	PUNCT
eurjchem-2518	145	13	therefore	therefore	ADV
eurjchem-2518	145	14	,	,	PUNCT
eurjchem-2518	145	15	the	the	DET
eurjchem-2518	145	16	process	process	NOUN
eurjchem-2518	145	17	of	of	ADP
eurjchem-2518	145	18	adsorption	adsorption	NOUN
eurjchem-2518	145	19	and	and	CCONJ
eurjchem-2518	145	20	h2s	h2s	NOUN
eurjchem-2518	145	21	dissociation	dissociation	NOUN
eurjchem-2518	145	22	on	on	ADP
eurjchem-2518	145	23	the	the	DET
eurjchem-2518	145	24	surface	surface	NOUN
eurjchem-2518	145	25	of	of	ADP
eurjchem-2518	145	26	metals	metal	NOUN
eurjchem-2518	145	27	can	can	AUX
eurjchem-2518	145	28	not	not	PART
eurjchem-2518	145	29	be	be	AUX
eurjchem-2518	145	30	attributed	attribute	VERB
eurjchem-2518	145	31	to	to	ADP
eurjchem-2518	145	32	traditional	traditional	ADJ
eurjchem-2518	145	33	redox	redox	ADJ
eurjchem-2518	145	34	chemical	chemical	NOUN
eurjchem-2518	145	35	processes	process	NOUN
eurjchem-2518	145	36	,	,	PUNCT
eurjchem-2518	145	37	as	as	SCONJ
eurjchem-2518	145	38	is	be	AUX
eurjchem-2518	145	39	the	the	DET
eurjchem-2518	145	40	case	case	NOUN
eurjchem-2518	145	41	in	in	ADP
eurjchem-2518	145	42	a	a	DET
eurjchem-2518	145	43	closed	closed	ADJ
eurjchem-2518	145	44	thermochemical	thermochemical	ADJ
eurjchem-2518	145	45	cycle	cycle	NOUN
eurjchem-2518	145	46	of	of	ADP
eurjchem-2518	145	47	hydrogen	hydrogen	NOUN
eurjchem-2518	145	48	production	production	NOUN
eurjchem-2518	145	49	using	use	VERB
eurjchem-2518	145	50	sulfides	sulfide	NOUN
eurjchem-2518	145	51	of	of	ADP
eurjchem-2518	145	52	multivalent	multivalent	NOUN
eurjchem-2518	145	53	metals	metal	NOUN
eurjchem-2518	145	54	.	.	PUNCT
eurjchem-2518	146	1	however	however	ADV
eurjchem-2518	146	2	,	,	PUNCT
eurjchem-2518	146	3	a	a	DET
eurjchem-2518	146	4	significant	significant	ADJ
eurjchem-2518	146	5	accumulation	accumulation	NOUN
eurjchem-2518	146	6	in	in	ADP
eurjchem-2518	146	7	energy	energy	NOUN
eurjchem-2518	146	8	during	during	ADP
eurjchem-2518	146	9	h2s	h2s	NOUN
eurjchem-2518	146	10	dissociation	dissociation	NOUN
eurjchem-2518	146	11	and	and	CCONJ
eurjchem-2518	146	12	the	the	DET
eurjchem-2518	146	13	formation	formation	NOUN
eurjchem-2518	146	14	of	of	ADP
eurjchem-2518	146	15	atomic	atomic	ADJ
eurjchem-2518	146	16	surface	surface	NOUN
eurjchem-2518	146	17	species	specie	NOUN
eurjchem-2518	146	18	of	of	ADP
eurjchem-2518	146	19	sulfur	sulfur	NOUN
eurjchem-2518	146	20	and	and	CCONJ
eurjchem-2518	146	21	hydrogen	hydrogen	NOUN
eurjchem-2518	146	22	suggest	suggest	VERB
eurjchem-2518	146	23	that	that	SCONJ
eurjchem-2518	146	24	this	this	DET
eurjchem-2518	146	25	process	process	NOUN
eurjchem-2518	146	26	can	can	AUX
eurjchem-2518	146	27	be	be	AUX
eurjchem-2518	146	28	catalytic	catalytic	ADJ
eurjchem-2518	146	29	,	,	PUNCT
eurjchem-2518	146	30	provided	provide	VERB
eurjchem-2518	146	31	that	that	SCONJ
eurjchem-2518	146	32	the	the	DET
eurjchem-2518	146	33	energy	energy	NOUN
eurjchem-2518	146	34	stored	store	VERB
eurjchem-2518	146	35	in	in	ADP
eurjchem-2518	146	36	the	the	DET
eurjchem-2518	146	37	processes	process	NOUN
eurjchem-2518	146	38	of	of	ADP
eurjchem-2518	146	39	adsorption	adsorption	NOUN
eurjchem-2518	146	40	and	and	CCONJ
eurjchem-2518	146	41	h2s	h2s	NOUN
eurjchem-2518	146	42	dissociation	dissociation	NOUN
eurjchem-2518	146	43	will	will	AUX
eurjchem-2518	146	44	be	be	AUX
eurjchem-2518	146	45	sufficient	sufficient	ADJ
eurjchem-2518	146	46	for	for	ADP
eurjchem-2518	146	47	the	the	DET
eurjchem-2518	146	48	synthesis	synthesis	NOUN
eurjchem-2518	146	49	of	of	ADP
eurjchem-2518	146	50	reaction	reaction	NOUN
eurjchem-2518	146	51	products	product	NOUN
eurjchem-2518	146	52	and	and	CCONJ
eurjchem-2518	146	53	their	their	PRON
eurjchem-2518	146	54	desorption	desorption	NOUN
eurjchem-2518	146	55	into	into	ADP
eurjchem-2518	146	56	the	the	DET
eurjchem-2518	146	57	gas	gas	NOUN
eurjchem-2518	146	58	phase	phase	NOUN
eurjchem-2518	146	59	.	.	PUNCT
eurjchem-2518	147	1	of	of	ADP
eurjchem-2518	147	2	course	course	NOUN
eurjchem-2518	147	3	,	,	PUNCT
eurjchem-2518	147	4	it	it	PRON
eurjchem-2518	147	5	would	would	AUX
eurjchem-2518	147	6	be	be	AUX
eurjchem-2518	147	7	necessary	necessary	ADJ
eurjchem-2518	147	8	to	to	PART
eurjchem-2518	147	9	calculate	calculate	VERB
eurjchem-2518	147	10	the	the	DET
eurjchem-2518	147	11	entropy	entropy	NOUN
eurjchem-2518	147	12	at	at	ADP
eurjchem-2518	147	13	all	all	DET
eurjchem-2518	147	14	elementary	elementary	ADJ
eurjchem-2518	147	15	stages	stage	NOUN
eurjchem-2518	147	16	of	of	ADP
eurjchem-2518	147	17	the	the	DET
eurjchem-2518	147	18	h2s	h2s	NOUN
eurjchem-2518	147	19	dissociation	dissociation	NOUN
eurjchem-2518	147	20	process	process	NOUN
eurjchem-2518	147	21	,	,	PUNCT
eurjchem-2518	147	22	as	as	SCONJ
eurjchem-2518	147	23	we	we	PRON
eurjchem-2518	147	24	did	do	VERB
eurjchem-2518	147	25	for	for	ADP
eurjchem-2518	147	26	sulfide	sulfide	NOUN
eurjchem-2518	147	27	catalysts	catalyst	NOUN
eurjchem-2518	147	28	(	(	PUNCT
eurjchem-2518	147	29	table	table	NOUN
eurjchem-2518	147	30	1	1	NUM
eurjchem-2518	147	31	,	,	PUNCT
eurjchem-2518	147	32	figure	figure	NOUN
eurjchem-2518	147	33	5	5	NUM
eurjchem-2518	147	34	)	)	PUNCT
eurjchem-2518	147	35	.	.	PUNCT
eurjchem-2518	148	1	this	this	PRON
eurjchem-2518	148	2	would	would	AUX
eurjchem-2518	148	3	allow	allow	VERB
eurjchem-2518	148	4	us	we	PRON
eurjchem-2518	148	5	to	to	PART
eurjchem-2518	148	6	determine	determine	VERB
eurjchem-2518	148	7	the	the	DET
eurjchem-2518	148	8	gibbs	gibbs	PROPN
eurjchem-2518	148	9	free	free	ADJ
eurjchem-2518	148	10	energy	energy	NOUN
eurjchem-2518	148	11	of	of	ADP
eurjchem-2518	148	12	both	both	DET
eurjchem-2518	148	13	individual	individual	ADJ
eurjchem-2518	148	14	stages	stage	NOUN
eurjchem-2518	148	15	and	and	CCONJ
eurjchem-2518	148	16	the	the	DET
eurjchem-2518	148	17	catalytic	catalytic	ADJ
eurjchem-2518	148	18	process	process	NOUN
eurjchem-2518	148	19	as	as	ADP
eurjchem-2518	148	20	a	a	DET
eurjchem-2518	148	21	whole	whole	NOUN
eurjchem-2518	148	22	.	.	PUNCT
eurjchem-2518	149	1	in	in	ADP
eurjchem-2518	149	2	the	the	DET
eurjchem-2518	149	3	absence	absence	NOUN
eurjchem-2518	149	4	of	of	ADP
eurjchem-2518	149	5	such	such	DET
eurjchem-2518	149	6	an	an	DET
eurjchem-2518	149	7	opportunity	opportunity	NOUN
eurjchem-2518	149	8	,	,	PUNCT
eurjchem-2518	149	9	we	we	PRON
eurjchem-2518	149	10	will	will	AUX
eurjchem-2518	149	11	try	try	VERB
eurjchem-2518	149	12	to	to	PART
eurjchem-2518	149	13	solve	solve	VERB
eurjchem-2518	149	14	this	this	DET
eurjchem-2518	149	15	problem	problem	NOUN
eurjchem-2518	149	16	(	(	PUNCT
eurjchem-2518	149	17	reaction	reaction	NOUN
eurjchem-2518	149	18	5	5	NUM
eurjchem-2518	149	19	)	)	PUNCT
eurjchem-2518	149	20	within	within	ADP
eurjchem-2518	149	21	the	the	DET
eurjchem-2518	149	22	framework	framework	NOUN
eurjchem-2518	149	23	of	of	ADP
eurjchem-2518	149	24	the	the	DET
eurjchem-2518	149	25	laws	law	NOUN
eurjchem-2518	149	26	of	of	ADP
eurjchem-2518	149	27	thermochemistry	thermochemistry	NOUN
eurjchem-2518	149	28	,	,	PUNCT
eurjchem-2518	149	29	using	use	VERB
eurjchem-2518	149	30	the	the	DET
eurjchem-2518	149	31	basic	basic	ADJ
eurjchem-2518	149	32	provisions	provision	NOUN
eurjchem-2518	149	33	of	of	ADP
eurjchem-2518	149	34	the	the	DET
eurjchem-2518	149	35	concept	concept	NOUN
eurjchem-2518	149	36	of	of	ADP
eurjchem-2518	149	37	the	the	DET
eurjchem-2518	149	38	decisive	decisive	ADJ
eurjchem-2518	149	39	role	role	NOUN
eurjchem-2518	149	40	of	of	ADP
eurjchem-2518	149	41	catalysts	catalyst	NOUN
eurjchem-2518	149	42	in	in	ADP
eurjchem-2518	149	43	non	non	ADJ
eurjchem-2518	149	44	-	-	ADJ
eurjchem-2518	149	45	equilibrium	equilibrium	ADJ
eurjchem-2518	149	46	thermodynamics	thermodynamic	NOUN
eurjchem-2518	150	1	[	[	X
eurjchem-2518	150	2	10,11	10,11	NOUN
eurjchem-2518	150	3	]	]	PUNCT
eurjchem-2518	150	4	.	.	PUNCT
eurjchem-2518	151	1	in	in	ADP
eurjchem-2518	151	2	our	our	PRON
eurjchem-2518	151	3	discussion	discussion	NOUN
eurjchem-2518	151	4	,	,	PUNCT
eurjchem-2518	151	5	we	we	PRON
eurjchem-2518	151	6	will	will	AUX
eurjchem-2518	151	7	use	use	VERB
eurjchem-2518	151	8	the	the	DET
eurjchem-2518	151	9	properties	property	NOUN
eurjchem-2518	151	10	of	of	ADP
eurjchem-2518	151	11	platinum	platinum	NOUN
eurjchem-2518	151	12	catalysts	catalyst	NOUN
eurjchem-2518	151	13	,	,	PUNCT
eurjchem-2518	151	14	since	since	SCONJ
eurjchem-2518	151	15	it	it	PRON
eurjchem-2518	151	16	was	be	AUX
eurjchem-2518	151	17	on	on	ADP
eurjchem-2518	151	18	platinum	platinum	NOUN
eurjchem-2518	151	19	that	that	PRON
eurjchem-2518	151	20	we	we	PRON
eurjchem-2518	151	21	discovered	discover	VERB
eurjchem-2518	151	22	the	the	DET
eurjchem-2518	151	23	reaction	reaction	NOUN
eurjchem-2518	151	24	of	of	ADP
eurjchem-2518	151	25	low	low	ADJ
eurjchem-2518	151	26	-	-	PUNCT
eurjchem-2518	151	27	temperature	temperature	NOUN
eurjchem-2518	151	28	h2s	h2s	NOUN
eurjchem-2518	151	29	decomposition	decomposition	NOUN
eurjchem-2518	151	30	[	[	X
eurjchem-2518	151	31	21	21	NUM
eurjchem-2518	151	32	]	]	PUNCT
eurjchem-2518	151	33	,	,	PUNCT
eurjchem-2518	151	34	and	and	CCONJ
eurjchem-2518	151	35	in	in	ADP
eurjchem-2518	151	36	the	the	DET
eurjchem-2518	151	37	literature	literature	NOUN
eurjchem-2518	151	38	there	there	PRON
eurjchem-2518	151	39	is	be	VERB
eurjchem-2518	151	40	information	information	NOUN
eurjchem-2518	151	41	about	about	ADP
eurjchem-2518	151	42	the	the	DET
eurjchem-2518	151	43	energy	energy	NOUN
eurjchem-2518	151	44	of	of	ADP
eurjchem-2518	151	45	the	the	DET
eurjchem-2518	151	46	interaction	interaction	NOUN
eurjchem-2518	151	47	of	of	ADP
eurjchem-2518	151	48	reaction	reaction	NOUN
eurjchem-2518	151	49	products	product	NOUN
eurjchem-2518	151	50	with	with	ADP
eurjchem-2518	151	51	the	the	DET
eurjchem-2518	151	52	surface	surface	NOUN
eurjchem-2518	151	53	of	of	ADP
eurjchem-2518	151	54	a	a	DET
eurjchem-2518	151	55	single	single	ADJ
eurjchem-2518	151	56	platinum	platinum	NOUN
eurjchem-2518	151	57	crystal	crystal	NOUN
eurjchem-2518	151	58	.	.	PUNCT
eurjchem-2518	152	1	as	as	SCONJ
eurjchem-2518	152	2	is	be	AUX
eurjchem-2518	152	3	known	know	VERB
eurjchem-2518	152	4	,	,	PUNCT
eurjchem-2518	152	5	the	the	DET
eurjchem-2518	152	6	energy	energy	NOUN
eurjchem-2518	152	7	of	of	ADP
eurjchem-2518	152	8	a	a	DET
eurjchem-2518	152	9	chemical	chemical	NOUN
eurjchem-2518	152	10	bond	bond	NOUN
eurjchem-2518	152	11	is	be	AUX
eurjchem-2518	152	12	an	an	DET
eurjchem-2518	152	13	important	important	ADJ
eurjchem-2518	152	14	molecular	molecular	ADJ
eurjchem-2518	152	15	constant	constant	ADJ
eurjchem-2518	152	16	,	,	PUNCT
eurjchem-2518	152	17	one	one	NUM
eurjchem-2518	152	18	of	of	ADP
eurjchem-2518	152	19	the	the	DET
eurjchem-2518	152	20	main	main	ADJ
eurjchem-2518	152	21	characteristics	characteristic	NOUN
eurjchem-2518	152	22	of	of	ADP
eurjchem-2518	152	23	a	a	DET
eurjchem-2518	152	24	molecule	molecule	NOUN
eurjchem-2518	152	25	[	[	X
eurjchem-2518	152	26	33	33	NUM
eurjchem-2518	152	27	-	-	SYM
eurjchem-2518	152	28	35	35	NUM
eurjchem-2518	152	29	]	]	PUNCT
eurjchem-2518	152	30	.	.	PUNCT
eurjchem-2518	153	1	the	the	DET
eurjchem-2518	153	2	energy	energy	NOUN
eurjchem-2518	153	3	of	of	ADP
eurjchem-2518	153	4	breaking	break	VERB
eurjchem-2518	153	5	a	a	DET
eurjchem-2518	153	6	chemical	chemical	NOUN
eurjchem-2518	153	7	bond	bond	NOUN
eurjchem-2518	153	8	is	be	AUX
eurjchem-2518	153	9	the	the	DET
eurjchem-2518	153	10	minimum	minimum	ADJ
eurjchem-2518	153	11	energy	energy	NOUN
eurjchem-2518	153	12	that	that	PRON
eurjchem-2518	153	13	must	must	AUX
eurjchem-2518	153	14	be	be	AUX
eurjchem-2518	153	15	communicated	communicate	VERB
eurjchem-2518	153	16	to	to	ADP
eurjchem-2518	153	17	a	a	DET
eurjchem-2518	153	18	molecule	molecule	NOUN
eurjchem-2518	153	19	for	for	SCONJ
eurjchem-2518	153	20	it	it	PRON
eurjchem-2518	153	21	to	to	PART
eurjchem-2518	153	22	split	split	VERB
eurjchem-2518	153	23	into	into	ADP
eurjchem-2518	153	24	appropriate	appropriate	ADJ
eurjchem-2518	153	25	parts	part	NOUN
eurjchem-2518	153	26	.	.	PUNCT
eurjchem-2518	154	1	the	the	DET
eurjchem-2518	154	2	dissociation	dissociation	NOUN
eurjchem-2518	154	3	energy	energy	NOUN
eurjchem-2518	154	4	of	of	ADP
eurjchem-2518	154	5	a	a	DET
eurjchem-2518	154	6	chemical	chemical	NOUN
eurjchem-2518	154	7	bond	bond	NOUN
eurjchem-2518	154	8	do	do	VERB
eurjchem-2518	154	9	or	or	CCONJ
eurjchem-2518	154	10	d298	d298	PROPN
eurjchem-2518	154	11	is	be	AUX
eurjchem-2518	154	12	defined	define	VERB
eurjchem-2518	154	13	as	as	ADP
eurjchem-2518	154	14	a	a	DET
eurjchem-2518	154	15	change	change	NOUN
eurjchem-2518	154	16	in	in	ADP
eurjchem-2518	154	17	the	the	DET
eurjchem-2518	154	18	standard	standard	ADJ
eurjchem-2518	154	19	enthalpy	enthalpy	NOUN
eurjchem-2518	154	20	of	of	ADP
eurjchem-2518	154	21	formation	formation	NOUN
eurjchem-2518	154	22	of	of	ADP
eurjchem-2518	154	23	reaction	reaction	NOUN
eurjchem-2518	154	24	products	product	NOUN
eurjchem-2518	154	25	and	and	CCONJ
eurjchem-2518	154	26	the	the	DET
eurjchem-2518	154	27	initial	initial	ADJ
eurjchem-2518	154	28	chemical	chemical	NOUN
eurjchem-2518	154	29	compounds	compound	NOUN
eurjchem-2518	154	30	.	.	PUNCT
eurjchem-2518	155	1	in	in	ADP
eurjchem-2518	155	2	our	our	PRON
eurjchem-2518	155	3	case	case	NOUN
eurjchem-2518	155	4	,	,	PUNCT
eurjchem-2518	155	5	for	for	ADP
eurjchem-2518	155	6	reaction	reaction	NOUN
eurjchem-2518	155	7	6	6	NUM
eurjchem-2518	155	8	,	,	PUNCT
eurjchem-2518	155	9	2	2	NUM
eurjchem-2518	155	10	h2s	h2s	NOUN
eurjchem-2518	155	11	⇋	⇋	PUNCT
eurjchem-2518	155	12	2	2	NUM
eurjchem-2518	155	13	h2	h2	NOUN
eurjchem-2518	155	14	+	+	CCONJ
eurjchem-2518	155	15	s2	s2	PROPN
eurjchem-2518	155	16	(	(	PUNCT
eurjchem-2518	155	17	6	6	NUM
eurjchem-2518	155	18	)	)	PUNCT
eurjchem-2518	155	19	the	the	DET
eurjchem-2518	155	20	dissociation	dissociation	NOUN
eurjchem-2518	155	21	energy	energy	NOUN
eurjchem-2518	155	22	d298	d298	PROPN
eurjchem-2518	155	23	of	of	ADP
eurjchem-2518	155	24	the	the	DET
eurjchem-2518	155	25	hs	hs	PROPN
eurjchem-2518	155	26	–	–	PROPN
eurjchem-2518	155	27	h	h	NOUN
eurjchem-2518	155	28	bond	bond	NOUN
eurjchem-2518	155	29	in	in	ADP
eurjchem-2518	155	30	the	the	DET
eurjchem-2518	155	31	h2s	h2s	NOUN
eurjchem-2518	155	32	molecule	molecule	NOUN
eurjchem-2518	155	33	under	under	ADP
eurjchem-2518	155	34	standard	standard	ADJ
eurjchem-2518	155	35	conditions	condition	NOUN
eurjchem-2518	155	36	is	be	AUX
eurjchem-2518	155	37	92	92	NUM
eurjchem-2518	155	38	kcal	kcal	NOUN
eurjchem-2518	155	39	/	/	SYM
eurjchem-2518	155	40	mol	mol	PROPN
eurjchem-2518	156	1	[	[	X
eurjchem-2518	156	2	33	33	NUM
eurjchem-2518	156	3	]	]	PUNCT
eurjchem-2518	156	4	,	,	PUNCT
eurjchem-2518	156	5	while	while	SCONJ
eurjchem-2518	156	6	the	the	DET
eurjchem-2518	156	7	dissociation	dissociation	NOUN
eurjchem-2518	156	8	of	of	ADP
eurjchem-2518	156	9	the	the	DET
eurjchem-2518	156	10	second	second	ADJ
eurjchem-2518	156	11	s	s	PROPN
eurjchem-2518	156	12	–	–	PUNCT
eurjchem-2518	156	13	h	h	PRON
eurjchem-2518	156	14	bond	bond	NOUN
eurjchem-2518	156	15	requires	require	VERB
eurjchem-2518	156	16	only	only	ADV
eurjchem-2518	156	17	82.3	82.3	NUM
eurjchem-2518	156	18	kcal	kcal	NOUN
eurjchem-2518	156	19	/	/	SYM
eurjchem-2518	156	20	mol	mol	PROPN
eurjchem-2518	156	21	.	.	PUNCT
eurjchem-2518	157	1	in	in	ADP
eurjchem-2518	157	2	reaction	reaction	NOUN
eurjchem-2518	157	3	6	6	NUM
eurjchem-2518	157	4	,	,	PUNCT
eurjchem-2518	157	5	two	two	NUM
eurjchem-2518	157	6	h2s	h2s	NOUN
eurjchem-2518	157	7	molecules	molecule	NOUN
eurjchem-2518	157	8	have	have	VERB
eurjchem-2518	157	9	four	four	NUM
eurjchem-2518	157	10	hs	hs	ADJ
eurjchem-2518	157	11	–	–	PUNCT
eurjchem-2518	157	12	h	h	NOUN
eurjchem-2518	157	13	bonds	bond	NOUN
eurjchem-2518	157	14	to	to	PART
eurjchem-2518	157	15	be	be	AUX
eurjchem-2518	157	16	broken	break	VERB
eurjchem-2518	157	17	,	,	PUNCT
eurjchem-2518	157	18	which	which	PRON
eurjchem-2518	157	19	gives	give	VERB
eurjchem-2518	157	20	the	the	DET
eurjchem-2518	157	21	total	total	ADJ
eurjchem-2518	157	22	dissociation	dissociation	NOUN
eurjchem-2518	157	23	energy	energy	NOUN
eurjchem-2518	157	24	of	of	ADP
eurjchem-2518	157	25	the	the	DET
eurjchem-2518	157	26	two	two	NUM
eurjchem-2518	157	27	molecules	molecule	NOUN
eurjchem-2518	157	28	σd298	σd298	X
eurjchem-2518	158	1	=	=	PRON
eurjchem-2518	159	1	(	(	PUNCT
eurjchem-2518	159	2	92.0	92.0	NUM
eurjchem-2518	159	3	+	+	NUM
eurjchem-2518	159	4	82.3)×2	82.3)×2	NUM
eurjchem-2518	159	5	=	=	SYM
eurjchem-2518	159	6	348.6	348.6	NUM
eurjchem-2518	159	7	kcal	kcal	NOUN
eurjchem-2518	159	8	/	/	SYM
eurjchem-2518	159	9	mol	mol	PROPN
eurjchem-2518	159	10	.	.	PUNCT
eurjchem-2518	160	1	at	at	ADP
eurjchem-2518	160	2	the	the	DET
eurjchem-2518	160	3	same	same	ADJ
eurjchem-2518	160	4	time	time	NOUN
eurjchem-2518	160	5	,	,	PUNCT
eurjchem-2518	160	6	two	two	NUM
eurjchem-2518	160	7	bonds	bond	NOUN
eurjchem-2518	160	8	h	h	NOUN
eurjchem-2518	160	9	–	–	PUNCT
eurjchem-2518	160	10	h	h	NOUN
eurjchem-2518	160	11	(	(	PUNCT
eurjchem-2518	160	12	σd298	σd298	X
eurjchem-2518	160	13	=	=	SYM
eurjchem-2518	161	1	2×104.2	2×104.2	NUM
eurjchem-2518	161	2	=	=	SYM
eurjchem-2518	161	3	208.4	208.4	NUM
eurjchem-2518	161	4	kcal	kcal	NOUN
eurjchem-2518	161	5	/	/	SYM
eurjchem-2518	161	6	mol	mol	NOUN
eurjchem-2518	161	7	)	)	PUNCT
eurjchem-2518	161	8	and	and	CCONJ
eurjchem-2518	161	9	one	one	NUM
eurjchem-2518	161	10	bond	bond	NOUN
eurjchem-2518	161	11	s	s	PART
eurjchem-2518	161	12	–	–	PUNCT
eurjchem-2518	161	13	s	s	X
eurjchem-2518	161	14	d298	d298	PROPN
eurjchem-2518	161	15	=	=	SYM
eurjchem-2518	161	16	99.8	99.8	NUM
eurjchem-2518	161	17	kcal	kcal	NOUN
eurjchem-2518	161	18	/	/	SYM
eurjchem-2518	161	19	mol	mol	NOUN
eurjchem-2518	161	20	are	be	AUX
eurjchem-2518	161	21	formed	form	VERB
eurjchem-2518	161	22	[	[	X
eurjchem-2518	161	23	33	33	NUM
eurjchem-2518	161	24	]	]	PUNCT
eurjchem-2518	161	25	.	.	PUNCT
eurjchem-2518	162	1	from	from	ADP
eurjchem-2518	162	2	this	this	PRON
eurjchem-2518	162	3	it	it	PRON
eurjchem-2518	162	4	follows	follow	VERB
eurjchem-2518	162	5	that	that	SCONJ
eurjchem-2518	162	6	the	the	DET
eurjchem-2518	162	7	total	total	ADJ
eurjchem-2518	162	8	energy	energy	NOUN
eurjchem-2518	162	9	of	of	ADP
eurjchem-2518	162	10	bond	bond	NOUN
eurjchem-2518	162	11	dissociation	dissociation	NOUN
eurjchem-2518	162	12	in	in	ADP
eurjchem-2518	162	13	the	the	DET
eurjchem-2518	162	14	initial	initial	ADJ
eurjchem-2518	162	15	hydrogen	hydrogen	NOUN
eurjchem-2518	162	16	sulfide	sulfide	NOUN
eurjchem-2518	162	17	exceeds	exceed	VERB
eurjchem-2518	162	18	this	this	DET
eurjchem-2518	162	19	indicator	indicator	NOUN
eurjchem-2518	162	20	for	for	ADP
eurjchem-2518	162	21	the	the	DET
eurjchem-2518	162	22	products	product	NOUN
eurjchem-2518	162	23	of	of	ADP
eurjchem-2518	162	24	the	the	DET
eurjchem-2518	162	25	reaction	reaction	NOUN
eurjchem-2518	162	26	6	6	NUM
eurjchem-2518	162	27	to	to	ADP
eurjchem-2518	162	28	∆d298	∆d298	PROPN
eurjchem-2518	162	29	=	=	PUNCT
eurjchem-2518	162	30	σd298(2	σd298(2	ADJ
eurjchem-2518	162	31	h2s	h2s	NOUN
eurjchem-2518	162	32	)	)	PUNCT
eurjchem-2518	162	33	−	−	PROPN
eurjchem-2518	162	34	σd298(2	σd298(2	PROPN
eurjchem-2518	162	35	h2	h2	PROPN
eurjchem-2518	162	36	+	+	CCONJ
eurjchem-2518	162	37	s2	s2	PROPN
eurjchem-2518	162	38	)	)	PUNCT
eurjchem-2518	162	39	=	=	NOUN
eurjchem-2518	162	40	40.4	40.4	NUM
eurjchem-2518	162	41	kcal	kcal	NOUN
eurjchem-2518	162	42	/	/	SYM
eurjchem-2518	162	43	mol	mol	PROPN
eurjchem-2518	162	44	.	.	PUNCT
eurjchem-2518	163	1	in	in	ADP
eurjchem-2518	163	2	other	other	ADJ
eurjchem-2518	163	3	words	word	NOUN
eurjchem-2518	163	4	,	,	PUNCT
eurjchem-2518	163	5	this	this	PRON
eurjchem-2518	163	6	means	mean	VERB
eurjchem-2518	163	7	that	that	SCONJ
eurjchem-2518	163	8	the	the	DET
eurjchem-2518	163	9	initial	initial	ADJ
eurjchem-2518	163	10	h2s	h2s	NOUN
eurjchem-2518	163	11	molecule	molecule	NOUN
eurjchem-2518	163	12	is	be	AUX
eurjchem-2518	163	13	stable	stable	ADJ
eurjchem-2518	163	14	and	and	CCONJ
eurjchem-2518	163	15	does	do	AUX
eurjchem-2518	163	16	not	not	PART
eurjchem-2518	163	17	turn	turn	VERB
eurjchem-2518	163	18	into	into	ADP
eurjchem-2518	163	19	reaction	reaction	NOUN
eurjchem-2518	163	20	products	product	NOUN
eurjchem-2518	163	21	h2	h2	NOUN
eurjchem-2518	163	22	and	and	CCONJ
eurjchem-2518	163	23	s2	s2	NOUN
eurjchem-2518	163	24	at	at	ADP
eurjchem-2518	163	25	room	room	NOUN
eurjchem-2518	163	26	temperature	temperature	NOUN
eurjchem-2518	163	27	;	;	PUNCT
eurjchem-2518	163	28	therefore	therefore	ADV
eurjchem-2518	163	29	,	,	PUNCT
eurjchem-2518	163	30	additional	additional	ADJ
eurjchem-2518	163	31	energy	energy	NOUN
eurjchem-2518	163	32	is	be	AUX
eurjchem-2518	163	33	needed	need	VERB
eurjchem-2518	163	34	to	to	PART
eurjchem-2518	163	35	carry	carry	VERB
eurjchem-2518	163	36	out	out	ADP
eurjchem-2518	163	37	reaction	reaction	NOUN
eurjchem-2518	163	38	6	6	NUM
eurjchem-2518	163	39	.	.	PUNCT
eurjchem-2518	164	1	since	since	SCONJ
eurjchem-2518	164	2	there	there	PRON
eurjchem-2518	164	3	is	be	VERB
eurjchem-2518	164	4	no	no	DET
eurjchem-2518	164	5	external	external	ADJ
eurjchem-2518	164	6	energy	energy	NOUN
eurjchem-2518	164	7	source	source	NOUN
eurjchem-2518	164	8	in	in	ADP
eurjchem-2518	164	9	reaction	reaction	NOUN
eurjchem-2518	164	10	5	5	NUM
eurjchem-2518	164	11	,	,	PUNCT
eurjchem-2518	164	12	therefore	therefore	ADV
eurjchem-2518	164	13	,	,	PUNCT
eurjchem-2518	164	14	to	to	PART
eurjchem-2518	164	15	carry	carry	VERB
eurjchem-2518	164	16	out	out	ADP
eurjchem-2518	164	17	reaction	reaction	NOUN
eurjchem-2518	164	18	6	6	NUM
eurjchem-2518	164	19	on	on	ADP
eurjchem-2518	164	20	the	the	DET
eurjchem-2518	164	21	surface	surface	NOUN
eurjchem-2518	164	22	of	of	ADP
eurjchem-2518	164	23	the	the	DET
eurjchem-2518	164	24	catalyst	catalyst	NOUN
eurjchem-2518	164	25	,	,	PUNCT
eurjchem-2518	164	26	this	this	DET
eurjchem-2518	164	27	energy	energy	NOUN
eurjchem-2518	164	28	can	can	AUX
eurjchem-2518	164	29	be	be	AUX
eurjchem-2518	164	30	obtained	obtain	VERB
eurjchem-2518	164	31	due	due	ADP
eurjchem-2518	164	32	to	to	ADP
eurjchem-2518	164	33	the	the	DET
eurjchem-2518	164	34	adsorption	adsorption	NOUN
eurjchem-2518	164	35	and	and	CCONJ
eurjchem-2518	164	36	dissociation	dissociation	NOUN
eurjchem-2518	164	37	energy	energy	NOUN
eurjchem-2518	164	38	of	of	ADP
eurjchem-2518	164	39	the	the	DET
eurjchem-2518	164	40	h2s	h2s	NOUN
eurjchem-2518	164	41	molecule	molecule	NOUN
eurjchem-2518	164	42	.	.	PUNCT
eurjchem-2518	165	1	subtracting	subtract	VERB
eurjchem-2518	165	2	from	from	ADP
eurjchem-2518	165	3	the	the	DET
eurjchem-2518	165	4	total	total	ADJ
eurjchem-2518	165	5	dissociation	dissociation	NOUN
eurjchem-2518	165	6	energy	energy	NOUN
eurjchem-2518	165	7	of	of	ADP
eurjchem-2518	165	8	two	two	NUM
eurjchem-2518	165	9	h2s	h2s	NOUN
eurjchem-2518	165	10	molecules	molecule	NOUN
eurjchem-2518	165	11	∆ediss	∆ediss	NUM
eurjchem-2518	165	12	-	-	PUNCT
eurjchem-2518	165	13	total	total	NOUN
eurjchem-2518	165	14	=	=	PROPN
eurjchem-2518	165	15	−117.6	−117.6	PROPN
eurjchem-2518	165	16	kcal	kcal	PROPN
eurjchem-2518	165	17	/	/	SYM
eurjchem-2518	165	18	mol	mol	PROPN
eurjchem-2518	165	19	,	,	PUNCT
eurjchem-2518	165	20	the	the	DET
eurjchem-2518	165	21	energy	energy	NOUN
eurjchem-2518	165	22	necessary	necessary	ADJ
eurjchem-2518	165	23	for	for	ADP
eurjchem-2518	165	24	the	the	DET
eurjchem-2518	165	25	implementation	implementation	NOUN
eurjchem-2518	165	26	of	of	ADP
eurjchem-2518	165	27	reaction	reaction	NOUN
eurjchem-2518	165	28	6	6	NUM
eurjchem-2518	165	29	,	,	PUNCT
eurjchem-2518	165	30	we	we	PRON
eurjchem-2518	165	31	obtain	obtain	VERB
eurjchem-2518	165	32	some	some	DET
eurjchem-2518	165	33	excess	excess	ADJ
eurjchem-2518	165	34	energy	energy	NOUN
eurjchem-2518	165	35	∆esurplus	∆esurplus	NOUN
eurjchem-2518	165	36	=	=	NOUN
eurjchem-2518	166	1	−77.2	−77.2	SYM
eurjchem-2518	166	2	kcal	kcal	NOUN
eurjchem-2518	166	3	/	/	SYM
eurjchem-2518	166	4	mol	mol	NOUN
eurjchem-2518	166	5	that	that	PRON
eurjchem-2518	166	6	can	can	AUX
eurjchem-2518	166	7	be	be	AUX
eurjchem-2518	166	8	spent	spend	VERB
eurjchem-2518	166	9	to	to	PART
eurjchem-2518	166	10	close	close	VERB
eurjchem-2518	166	11	the	the	DET
eurjchem-2518	166	12	catalytic	catalytic	ADJ
eurjchem-2518	166	13	cycle	cycle	NOUN
eurjchem-2518	166	14	,	,	PUNCT
eurjchem-2518	166	15	i.e.	i.e.	X
eurjchem-2518	166	16	,	,	PUNCT
eurjchem-2518	166	17	for	for	ADP
eurjchem-2518	166	18	desorbing	desorb	VERB
eurjchem-2518	166	19	reaction	reaction	NOUN
eurjchem-2518	166	20	products	product	NOUN
eurjchem-2518	166	21	into	into	ADP
eurjchem-2518	166	22	the	the	DET
eurjchem-2518	166	23	gas	gas	NOUN
eurjchem-2518	166	24	phase	phase	NOUN
eurjchem-2518	166	25	.	.	PUNCT
eurjchem-2518	167	1	taking	take	VERB
eurjchem-2518	167	2	into	into	ADP
eurjchem-2518	167	3	account	account	NOUN
eurjchem-2518	167	4	that	that	SCONJ
eurjchem-2518	167	5	on	on	ADP
eurjchem-2518	167	6	the	the	DET
eurjchem-2518	167	7	surface	surface	NOUN
eurjchem-2518	167	8	of	of	ADP
eurjchem-2518	167	9	platinum	platinum	NOUN
eurjchem-2518	167	10	,	,	PUNCT
eurjchem-2518	167	11	the	the	DET
eurjchem-2518	167	12	stabilization	stabilization	NOUN
eurjchem-2518	167	13	energy	energy	NOUN
eurjchem-2518	167	14	of	of	ADP
eurjchem-2518	167	15	the	the	DET
eurjchem-2518	167	16	s2	s2	NOUN
eurjchem-2518	167	17	molecule	molecule	NOUN
eurjchem-2518	167	18	is	be	AUX
eurjchem-2518	167	19	−45	−45	ADV
eurjchem-2518	167	20	kcal	kcal	PROPN
eurjchem-2518	167	21	/	/	SYM
eurjchem-2518	167	22	mol	mol	PROPN
eurjchem-2518	168	1	[	[	X
eurjchem-2518	168	2	36	36	NUM
eurjchem-2518	168	3	]	]	PUNCT
eurjchem-2518	168	4	,	,	PUNCT
eurjchem-2518	168	5	while	while	SCONJ
eurjchem-2518	168	6	for	for	ADP
eurjchem-2518	168	7	hydrogen	hydrogen	NOUN
eurjchem-2518	168	8	it	it	PRON
eurjchem-2518	168	9	varies	vary	VERB
eurjchem-2518	168	10	within	within	ADP
eurjchem-2518	168	11	−(9.5÷12	−(9.5÷12	PRON
eurjchem-2518	168	12	)	)	PUNCT
eurjchem-2518	168	13	kcal	kcal	NOUN
eurjchem-2518	168	14	/	/	SYM
eurjchem-2518	168	15	mol	mol	ADP
eurjchem-2518	169	1	[	[	X
eurjchem-2518	169	2	37,38	37,38	NOUN
eurjchem-2518	169	3	]	]	PUNCT
eurjchem-2518	169	4	,	,	PUNCT
eurjchem-2518	169	5	anatolii	anatolii	NOUN
eurjchem-2518	169	6	startsev	startsev	NOUN
eurjchem-2518	169	7	/	/	SYM
eurjchem-2518	169	8	european	european	ADJ
eurjchem-2518	169	9	journal	journal	PROPN
eurjchem-2518	169	10	of	of	ADP
eurjchem-2518	169	11	chemistry	chemistry	NOUN
eurjchem-2518	169	12	15	15	NUM
eurjchem-2518	169	13	(	(	PUNCT
eurjchem-2518	169	14	2	2	NUM
eurjchem-2518	169	15	)	)	PUNCT
eurjchem-2518	169	16	(	(	PUNCT
eurjchem-2518	169	17	2024	2024	NUM
eurjchem-2518	169	18	)	)	PUNCT
eurjchem-2518	169	19	186	186	NUM
eurjchem-2518	169	20	-	-	SYM
eurjchem-2518	169	21	193	193	NUM
eurjchem-2518	169	22	191	191	NUM
eurjchem-2518	169	23	2024	2024	NUM
eurjchem-2518	169	24	–	–	PUNCT
eurjchem-2518	169	25	european	european	ADJ
eurjchem-2518	169	26	journal	journal	NOUN
eurjchem-2518	169	27	of	of	ADP
eurjchem-2518	169	28	chemistry	chemistry	NOUN
eurjchem-2518	169	29	–	–	PUNCT
eurjchem-2518	169	30	cc	cc	NOUN
eurjchem-2518	169	31	by	by	ADP
eurjchem-2518	169	32	nc	nc	PROPN
eurjchem-2518	169	33	–	–	PUNCT
eurjchem-2518	169	34	doi	doi	NOUN
eurjchem-2518	169	35	:	:	PUNCT
eurjchem-2518	169	36	10.5155	10.5155	NUM
eurjchem-2518	169	37	/	/	SYM
eurjchem-2518	169	38	eurjchem.15.2.186	eurjchem.15.2.186	NOUN
eurjchem-2518	169	39	-	-	SYM
eurjchem-2518	169	40	193.2518	193.2518	NUM
eurjchem-2518	169	41	we	we	PRON
eurjchem-2518	169	42	conclude	conclude	VERB
eurjchem-2518	169	43	that	that	SCONJ
eurjchem-2518	169	44	after	after	ADP
eurjchem-2518	169	45	desorption	desorption	NOUN
eurjchem-2518	169	46	of	of	ADP
eurjchem-2518	169	47	the	the	DET
eurjchem-2518	169	48	reaction	reaction	NOUN
eurjchem-2518	169	49	products	product	NOUN
eurjchem-2518	169	50	in	in	ADP
eurjchem-2518	169	51	the	the	DET
eurjchem-2518	169	52	gas	gas	NOUN
eurjchem-2518	169	53	phase	phase	NOUN
eurjchem-2518	169	54	,	,	PUNCT
eurjchem-2518	169	55	we	we	PRON
eurjchem-2518	169	56	have	have	VERB
eurjchem-2518	169	57	a	a	DET
eurjchem-2518	169	58	small	small	ADJ
eurjchem-2518	169	59	excess	excess	NOUN
eurjchem-2518	169	60	of	of	ADP
eurjchem-2518	169	61	energy	energy	NOUN
eurjchem-2518	169	62	∆etotal.min	∆etotal.min	NOUN
eurjchem-2518	169	63	=	=	SYM
eurjchem-2518	169	64	−(8.2÷13.2	−(8.2÷13.2	NUM
eurjchem-2518	169	65	)	)	PUNCT
eurjchem-2518	169	66	kcal	kcal	PROPN
eurjchem-2518	169	67	/	/	SYM
eurjchem-2518	169	68	mol	mol	PROPN
eurjchem-2518	169	69	,	,	PUNCT
eurjchem-2518	169	70	which	which	PRON
eurjchem-2518	169	71	means	mean	VERB
eurjchem-2518	169	72	the	the	DET
eurjchem-2518	169	73	exothermic	exothermic	ADJ
eurjchem-2518	169	74	nature	nature	NOUN
eurjchem-2518	169	75	of	of	ADP
eurjchem-2518	169	76	the	the	DET
eurjchem-2518	169	77	catalytic	catalytic	ADJ
eurjchem-2518	169	78	cycle	cycle	NOUN
eurjchem-2518	169	79	.	.	PUNCT
eurjchem-2518	170	1	however	however	ADV
eurjchem-2518	170	2	,	,	PUNCT
eurjchem-2518	170	3	in	in	ADP
eurjchem-2518	170	4	catalytic	catalytic	ADJ
eurjchem-2518	170	5	reaction	reaction	NOUN
eurjchem-2518	170	6	5	5	NUM
eurjchem-2518	170	7	,	,	PUNCT
eurjchem-2518	170	8	a	a	DET
eurjchem-2518	170	9	spontaneous	spontaneous	ADJ
eurjchem-2518	170	10	transition	transition	NOUN
eurjchem-2518	170	11	of	of	ADP
eurjchem-2518	170	12	diatomic	diatomic	ADJ
eurjchem-2518	170	13	sulfur	sulfur	NOUN
eurjchem-2518	170	14	to	to	ADP
eurjchem-2518	170	15	the	the	DET
eurjchem-2518	170	16	ground	ground	NOUN
eurjchem-2518	170	17	triplet	triplet	NOUN
eurjchem-2518	170	18	state	state	NOUN
eurjchem-2518	170	19	is	be	AUX
eurjchem-2518	170	20	carried	carry	VERB
eurjchem-2518	170	21	out	out	ADP
eurjchem-2518	170	22	with	with	ADP
eurjchem-2518	170	23	the	the	DET
eurjchem-2518	170	24	release	release	NOUN
eurjchem-2518	170	25	of	of	ADP
eurjchem-2518	170	26	energy	energy	NOUN
eurjchem-2518	170	27	of	of	ADP
eurjchem-2518	170	28	12.6	12.6	NUM
eurjchem-2518	170	29	kcal	kcal	NOUN
eurjchem-2518	170	30	/	/	SYM
eurjchem-2518	170	31	mol	mol	PROPN
eurjchem-2518	171	1	[	[	X
eurjchem-2518	171	2	23	23	NUM
eurjchem-2518	171	3	]	]	PUNCT
eurjchem-2518	171	4	,	,	PUNCT
eurjchem-2518	171	5	therefore	therefore	ADV
eurjchem-2518	171	6	,	,	PUNCT
eurjchem-2518	171	7	this	this	DET
eurjchem-2518	171	8	energy	energy	NOUN
eurjchem-2518	171	9	should	should	AUX
eurjchem-2518	171	10	be	be	AUX
eurjchem-2518	171	11	added	add	VERB
eurjchem-2518	171	12	to	to	ADP
eurjchem-2518	171	13	the	the	DET
eurjchem-2518	171	14	exothermic	exothermic	ADJ
eurjchem-2518	171	15	effect	effect	NOUN
eurjchem-2518	171	16	of	of	ADP
eurjchem-2518	171	17	the	the	DET
eurjchem-2518	171	18	reaction	reaction	NOUN
eurjchem-2518	171	19	under	under	ADP
eurjchem-2518	171	20	consideration	consideration	NOUN
eurjchem-2518	171	21	,	,	PUNCT
eurjchem-2518	171	22	which	which	PRON
eurjchem-2518	171	23	corresponds	correspond	VERB
eurjchem-2518	171	24	to	to	ADP
eurjchem-2518	171	25	∆etotal.max	∆etotal.max	PROPN
eurjchem-2518	171	26	=	=	SYM
eurjchem-2518	171	27	−(20.8÷25.8	−(20.8÷25.8	X
eurjchem-2518	171	28	)	)	PUNCT
eurjchem-2518	171	29	kcal	kcal	PROPN
eurjchem-2518	171	30	/	/	SYM
eurjchem-2518	171	31	mol	mol	PROPN
eurjchem-2518	171	32	.	.	PUNCT
eurjchem-2518	172	1	the	the	DET
eurjchem-2518	172	2	driving	drive	VERB
eurjchem-2518	172	3	force	force	NOUN
eurjchem-2518	172	4	of	of	ADP
eurjchem-2518	172	5	the	the	DET
eurjchem-2518	172	6	process	process	NOUN
eurjchem-2518	172	7	is	be	AUX
eurjchem-2518	172	8	the	the	DET
eurjchem-2518	172	9	formation	formation	NOUN
eurjchem-2518	172	10	of	of	ADP
eurjchem-2518	172	11	reaction	reaction	NOUN
eurjchem-2518	172	12	products	product	NOUN
eurjchem-2518	172	13	in	in	ADP
eurjchem-2518	172	14	the	the	DET
eurjchem-2518	172	15	ground	ground	NOUN
eurjchem-2518	172	16	electronic	electronic	ADJ
eurjchem-2518	172	17	state	state	NOUN
eurjchem-2518	172	18	:	:	PUNCT
eurjchem-2518	172	19	singlet	singlet	ADJ
eurjchem-2518	172	20	hydrogen	hydrogen	NOUN
eurjchem-2518	172	21	and	and	CCONJ
eurjchem-2518	172	22	diatomic	diatomic	ADJ
eurjchem-2518	172	23	triplet	triplet	NOUN
eurjchem-2518	172	24	sulfur	sulfur	NOUN
eurjchem-2518	172	25	,	,	PUNCT
eurjchem-2518	172	26	having	have	VERB
eurjchem-2518	172	27	a	a	DET
eurjchem-2518	172	28	minimum	minimum	NOUN
eurjchem-2518	172	29	of	of	ADP
eurjchem-2518	172	30	free	free	ADJ
eurjchem-2518	172	31	energy	energy	NOUN
eurjchem-2518	172	32	.	.	PUNCT
eurjchem-2518	173	1	of	of	ADP
eurjchem-2518	173	2	course	course	NOUN
eurjchem-2518	173	3	,	,	PUNCT
eurjchem-2518	173	4	a	a	DET
eurjchem-2518	173	5	similar	similar	ADJ
eurjchem-2518	173	6	analysis	analysis	NOUN
eurjchem-2518	173	7	can	can	AUX
eurjchem-2518	173	8	be	be	AUX
eurjchem-2518	173	9	done	do	VERB
eurjchem-2518	173	10	for	for	ADP
eurjchem-2518	173	11	other	other	ADJ
eurjchem-2518	173	12	metals	metal	NOUN
eurjchem-2518	173	13	from	from	ADP
eurjchem-2518	173	14	table	table	NOUN
eurjchem-2518	173	15	2	2	NUM
eurjchem-2518	173	16	,	,	PUNCT
eurjchem-2518	173	17	however	however	ADV
eurjchem-2518	173	18	,	,	PUNCT
eurjchem-2518	173	19	this	this	PRON
eurjchem-2518	173	20	requires	require	VERB
eurjchem-2518	173	21	to	to	PART
eurjchem-2518	173	22	know	know	VERB
eurjchem-2518	173	23	the	the	DET
eurjchem-2518	173	24	interaction	interaction	NOUN
eurjchem-2518	173	25	energies	energy	NOUN
eurjchem-2518	173	26	of	of	ADP
eurjchem-2518	173	27	molecules	molecule	NOUN
eurjchem-2518	173	28	with	with	ADP
eurjchem-2518	173	29	the	the	DET
eurjchem-2518	173	30	surface	surface	NOUN
eurjchem-2518	173	31	of	of	ADP
eurjchem-2518	173	32	the	the	DET
eurjchem-2518	173	33	corresponding	corresponding	ADJ
eurjchem-2518	173	34	metal	metal	NOUN
eurjchem-2518	173	35	.	.	PUNCT
eurjchem-2518	174	1	a	a	DET
eurjchem-2518	174	2	very	very	ADV
eurjchem-2518	174	3	important	important	ADJ
eurjchem-2518	174	4	conclusion	conclusion	NOUN
eurjchem-2518	174	5	follows	follow	VERB
eurjchem-2518	174	6	from	from	ADP
eurjchem-2518	174	7	the	the	DET
eurjchem-2518	174	8	consideration	consideration	NOUN
eurjchem-2518	174	9	of	of	ADP
eurjchem-2518	174	10	the	the	DET
eurjchem-2518	174	11	energy	energy	NOUN
eurjchem-2518	174	12	redistribution	redistribution	NOUN
eurjchem-2518	174	13	of	of	ADP
eurjchem-2518	174	14	the	the	DET
eurjchem-2518	174	15	dissociation	dissociation	NOUN
eurjchem-2518	174	16	of	of	ADP
eurjchem-2518	174	17	the	the	DET
eurjchem-2518	174	18	h2s	h2s	NOUN
eurjchem-2518	174	19	molecule	molecule	NOUN
eurjchem-2518	174	20	on	on	ADP
eurjchem-2518	174	21	the	the	DET
eurjchem-2518	174	22	surface	surface	NOUN
eurjchem-2518	174	23	of	of	ADP
eurjchem-2518	174	24	the	the	DET
eurjchem-2518	174	25	metal	metal	NOUN
eurjchem-2518	174	26	catalysts	catalyst	NOUN
eurjchem-2518	174	27	.	.	PUNCT
eurjchem-2518	175	1	in	in	ADP
eurjchem-2518	175	2	this	this	DET
eurjchem-2518	175	3	case	case	NOUN
eurjchem-2518	175	4	,	,	PUNCT
eurjchem-2518	175	5	the	the	DET
eurjchem-2518	175	6	first	first	ADJ
eurjchem-2518	175	7	law	law	NOUN
eurjchem-2518	175	8	of	of	ADP
eurjchem-2518	175	9	thermodynamics	thermodynamic	NOUN
eurjchem-2518	175	10	of	of	ADP
eurjchem-2518	175	11	energy	energy	NOUN
eurjchem-2518	175	12	conservation	conservation	NOUN
eurjchem-2518	175	13	is	be	AUX
eurjchem-2518	175	14	fully	fully	ADV
eurjchem-2518	175	15	realized	realize	VERB
eurjchem-2518	175	16	:	:	PUNCT
eurjchem-2518	175	17	energy	energy	NOUN
eurjchem-2518	175	18	does	do	AUX
eurjchem-2518	175	19	not	not	PART
eurjchem-2518	175	20	appear	appear	VERB
eurjchem-2518	175	21	out	out	ADP
eurjchem-2518	175	22	of	of	ADP
eurjchem-2518	175	23	nothing	nothing	PRON
eurjchem-2518	175	24	and	and	CCONJ
eurjchem-2518	175	25	does	do	AUX
eurjchem-2518	175	26	not	not	PART
eurjchem-2518	175	27	disappear	disappear	VERB
eurjchem-2518	175	28	into	into	ADP
eurjchem-2518	175	29	nowhere	nowhere	ADV
eurjchem-2518	175	30	,	,	PUNCT
eurjchem-2518	175	31	but	but	CCONJ
eurjchem-2518	175	32	turns	turn	VERB
eurjchem-2518	175	33	from	from	ADP
eurjchem-2518	175	34	one	one	NUM
eurjchem-2518	175	35	form	form	NOUN
eurjchem-2518	175	36	into	into	ADP
eurjchem-2518	175	37	another	another	PRON
eurjchem-2518	175	38	.	.	PUNCT
eurjchem-2518	176	1	in	in	ADP
eurjchem-2518	176	2	other	other	ADJ
eurjchem-2518	176	3	words	word	NOUN
eurjchem-2518	176	4	,	,	PUNCT
eurjchem-2518	176	5	the	the	DET
eurjchem-2518	176	6	surface	surface	NOUN
eurjchem-2518	176	7	of	of	ADP
eurjchem-2518	176	8	the	the	DET
eurjchem-2518	176	9	catalyst	catalyst	NOUN
eurjchem-2518	176	10	provides	provide	VERB
eurjchem-2518	176	11	the	the	DET
eurjchem-2518	176	12	possibility	possibility	NOUN
eurjchem-2518	176	13	of	of	ADP
eurjchem-2518	176	14	transferring	transfer	VERB
eurjchem-2518	176	15	the	the	DET
eurjchem-2518	176	16	internal	internal	ADJ
eurjchem-2518	176	17	energy	energy	NOUN
eurjchem-2518	176	18	of	of	ADP
eurjchem-2518	176	19	the	the	DET
eurjchem-2518	176	20	h2s	h2s	NOUN
eurjchem-2518	176	21	molecule	molecule	NOUN
eurjchem-2518	176	22	to	to	PART
eurjchem-2518	176	23	create	create	VERB
eurjchem-2518	176	24	new	new	ADJ
eurjchem-2518	176	25	chemical	chemical	NOUN
eurjchem-2518	176	26	bonds	bond	NOUN
eurjchem-2518	176	27	in	in	ADP
eurjchem-2518	176	28	the	the	DET
eurjchem-2518	176	29	reaction	reaction	NOUN
eurjchem-2518	176	30	products	product	NOUN
eurjchem-2518	176	31	and	and	CCONJ
eurjchem-2518	176	32	their	their	PRON
eurjchem-2518	176	33	desorption	desorption	NOUN
eurjchem-2518	176	34	into	into	ADP
eurjchem-2518	176	35	the	the	DET
eurjchem-2518	176	36	gas	gas	NOUN
eurjchem-2518	176	37	phase	phase	NOUN
eurjchem-2518	176	38	,	,	PUNCT
eurjchem-2518	176	39	thus	thus	ADV
eurjchem-2518	176	40	closing	close	VERB
eurjchem-2518	176	41	the	the	DET
eurjchem-2518	176	42	catalytic	catalytic	ADJ
eurjchem-2518	176	43	cycle	cycle	NOUN
eurjchem-2518	176	44	.	.	PUNCT
eurjchem-2518	177	1	the	the	DET
eurjchem-2518	177	2	second	second	ADJ
eurjchem-2518	177	3	important	important	ADJ
eurjchem-2518	177	4	conclusion	conclusion	NOUN
eurjchem-2518	177	5	is	be	AUX
eurjchem-2518	177	6	that	that	SCONJ
eurjchem-2518	177	7	since	since	SCONJ
eurjchem-2518	177	8	the	the	DET
eurjchem-2518	177	9	entropy	entropy	NOUN
eurjchem-2518	177	10	of	of	ADP
eurjchem-2518	177	11	reaction	reaction	NOUN
eurjchem-2518	177	12	5	5	NUM
eurjchem-2518	177	13	increases	increase	VERB
eurjchem-2518	177	14	∆s	∆s	PROPN
eurjchem-2518	177	15	>	>	X
eurjchem-2518	177	16	0	0	PUNCT
eurjchem-2518	178	1	(	(	PUNCT
eurjchem-2518	178	2	the	the	DET
eurjchem-2518	178	3	number	number	NOUN
eurjchem-2518	178	4	of	of	ADP
eurjchem-2518	178	5	gaseous	gaseous	ADJ
eurjchem-2518	178	6	molecules	molecule	NOUN
eurjchem-2518	178	7	increases	increase	NOUN
eurjchem-2518	178	8	)	)	PUNCT
eurjchem-2518	178	9	,	,	PUNCT
eurjchem-2518	178	10	and	and	CCONJ
eurjchem-2518	178	11	the	the	DET
eurjchem-2518	178	12	reaction	reaction	NOUN
eurjchem-2518	178	13	itself	itself	PRON
eurjchem-2518	178	14	is	be	AUX
eurjchem-2518	178	15	exothermic	exothermic	ADJ
eurjchem-2518	178	16	∆h	∆h	PROPN
eurjchem-2518	178	17	<	<	X
eurjchem-2518	178	18	0	0	NUM
eurjchem-2518	178	19	,	,	PUNCT
eurjchem-2518	178	20	the	the	DET
eurjchem-2518	178	21	gibbs	gibbs	PROPN
eurjchem-2518	178	22	free	free	ADJ
eurjchem-2518	178	23	energy	energy	NOUN
eurjchem-2518	178	24	will	will	AUX
eurjchem-2518	178	25	always	always	ADV
eurjchem-2518	178	26	be	be	AUX
eurjchem-2518	178	27	negative	negative	ADJ
eurjchem-2518	178	28	,	,	PUNCT
eurjchem-2518	178	29	which	which	PRON
eurjchem-2518	178	30	means	mean	VERB
eurjchem-2518	178	31	the	the	DET
eurjchem-2518	178	32	spontaneous	spontaneous	ADJ
eurjchem-2518	178	33	course	course	NOUN
eurjchem-2518	178	34	of	of	ADP
eurjchem-2518	178	35	catalytic	catalytic	ADJ
eurjchem-2518	178	36	reaction	reaction	NOUN
eurjchem-2518	178	37	5	5	NUM
eurjchem-2518	178	38	.	.	PUNCT
eurjchem-2518	179	1	however	however	ADV
eurjchem-2518	179	2	,	,	PUNCT
eurjchem-2518	179	3	the	the	DET
eurjchem-2518	179	4	paradox	paradox	NOUN
eurjchem-2518	179	5	lies	lie	VERB
eurjchem-2518	179	6	in	in	ADP
eurjchem-2518	179	7	the	the	DET
eurjchem-2518	179	8	fact	fact	NOUN
eurjchem-2518	179	9	that	that	SCONJ
eurjchem-2518	179	10	the	the	DET
eurjchem-2518	179	11	increase	increase	NOUN
eurjchem-2518	179	12	in	in	ADP
eurjchem-2518	179	13	entropy	entropy	NOUN
eurjchem-2518	179	14	in	in	ADP
eurjchem-2518	179	15	combination	combination	NOUN
eurjchem-2518	179	16	with	with	ADP
eurjchem-2518	179	17	the	the	DET
eurjchem-2518	179	18	exothermic	exothermic	ADJ
eurjchem-2518	179	19	effect	effect	NOUN
eurjchem-2518	179	20	will	will	AUX
eurjchem-2518	179	21	inevitably	inevitably	ADV
eurjchem-2518	179	22	lead	lead	VERB
eurjchem-2518	179	23	to	to	ADP
eurjchem-2518	179	24	heating	heating	NOUN
eurjchem-2518	179	25	of	of	ADP
eurjchem-2518	179	26	the	the	DET
eurjchem-2518	179	27	catalytic	catalytic	ADJ
eurjchem-2518	179	28	system	system	NOUN
eurjchem-2518	179	29	,	,	PUNCT
eurjchem-2518	179	30	and	and	CCONJ
eurjchem-2518	179	31	therefore	therefore	ADV
eurjchem-2518	179	32	,	,	PUNCT
eurjchem-2518	179	33	in	in	ADP
eurjchem-2518	179	34	order	order	NOUN
eurjchem-2518	179	35	to	to	PART
eurjchem-2518	179	36	maintain	maintain	VERB
eurjchem-2518	179	37	the	the	DET
eurjchem-2518	179	38	stationary	stationary	ADJ
eurjchem-2518	179	39	state	state	NOUN
eurjchem-2518	179	40	of	of	ADP
eurjchem-2518	179	41	the	the	DET
eurjchem-2518	179	42	system	system	NOUN
eurjchem-2518	179	43	,	,	PUNCT
eurjchem-2518	179	44	the	the	DET
eurjchem-2518	179	45	heat	heat	NOUN
eurjchem-2518	179	46	must	must	AUX
eurjchem-2518	179	47	be	be	AUX
eurjchem-2518	179	48	removed	remove	VERB
eurjchem-2518	179	49	.	.	PUNCT
eurjchem-2518	180	1	for	for	ADP
eurjchem-2518	180	2	this	this	DET
eurjchem-2518	180	3	reason	reason	NOUN
eurjchem-2518	180	4	,	,	PUNCT
eurjchem-2518	180	5	we	we	PRON
eurjchem-2518	180	6	observed	observe	VERB
eurjchem-2518	180	7	an	an	DET
eurjchem-2518	180	8	abnormal	abnormal	ADJ
eurjchem-2518	180	9	temperature	temperature	NOUN
eurjchem-2518	180	10	dependence	dependence	NOUN
eurjchem-2518	180	11	of	of	ADP
eurjchem-2518	180	12	h2s	h2s	NOUN
eurjchem-2518	180	13	decomposition	decomposition	NOUN
eurjchem-2518	180	14	on	on	ADP
eurjchem-2518	180	15	metal	metal	NOUN
eurjchem-2518	180	16	catalysts	catalyst	NOUN
eurjchem-2518	180	17	[	[	X
eurjchem-2518	180	18	21	21	NUM
eurjchem-2518	180	19	]	]	PUNCT
eurjchem-2518	180	20	–	–	PUNCT
eurjchem-2518	180	21	the	the	DET
eurjchem-2518	180	22	efficiency	efficiency	NOUN
eurjchem-2518	180	23	of	of	ADP
eurjchem-2518	180	24	the	the	DET
eurjchem-2518	180	25	process	process	NOUN
eurjchem-2518	180	26	increases	increase	VERB
eurjchem-2518	180	27	with	with	ADP
eurjchem-2518	180	28	decreasing	decrease	VERB
eurjchem-2518	180	29	temperature	temperature	NOUN
eurjchem-2518	180	30	.	.	PUNCT
eurjchem-2518	181	1	an	an	DET
eurjchem-2518	181	2	even	even	ADV
eurjchem-2518	181	3	more	more	ADV
eurjchem-2518	181	4	convincing	convincing	ADJ
eurjchem-2518	181	5	example	example	NOUN
eurjchem-2518	181	6	is	be	AUX
eurjchem-2518	181	7	that	that	SCONJ
eurjchem-2518	181	8	hydrogen	hydrogen	NOUN
eurjchem-2518	181	9	is	be	AUX
eurjchem-2518	181	10	already	already	ADV
eurjchem-2518	181	11	formed	form	VERB
eurjchem-2518	181	12	from	from	ADP
eurjchem-2518	181	13	h2s	h2s	NOUN
eurjchem-2518	181	14	on	on	ADP
eurjchem-2518	181	15	the	the	DET
eurjchem-2518	181	16	pt	pt	PROPN
eurjchem-2518	181	17	surface	surface	NOUN
eurjchem-2518	181	18	already	already	ADV
eurjchem-2518	181	19	at	at	ADP
eurjchem-2518	181	20	185	185	NUM
eurjchem-2518	181	21	k	k	NOUN
eurjchem-2518	181	22	(	(	PUNCT
eurjchem-2518	181	23	−88	−88	PROPN
eurjchem-2518	181	24	°	°	ADP
eurjchem-2518	181	25	c	c	NOUN
eurjchem-2518	181	26	)	)	PUNCT
eurjchem-2518	181	27	,	,	PUNCT
eurjchem-2518	181	28	while	while	SCONJ
eurjchem-2518	181	29	water	water	NOUN
eurjchem-2518	181	30	on	on	ADP
eurjchem-2518	181	31	pt	pt	NOUN
eurjchem-2518	181	32	does	do	AUX
eurjchem-2518	181	33	not	not	PART
eurjchem-2518	181	34	dissociate	dissociate	VERB
eurjchem-2518	181	35	into	into	ADP
eurjchem-2518	181	36	atoms	atom	NOUN
eurjchem-2518	181	37	[	[	X
eurjchem-2518	181	38	20	20	NUM
eurjchem-2518	181	39	]	]	PUNCT
eurjchem-2518	181	40	.	.	PUNCT
eurjchem-2518	182	1	in	in	ADP
eurjchem-2518	182	2	the	the	DET
eurjchem-2518	182	3	gas	gas	NOUN
eurjchem-2518	182	4	phase	phase	NOUN
eurjchem-2518	182	5	,	,	PUNCT
eurjchem-2518	182	6	this	this	DET
eurjchem-2518	182	7	process	process	NOUN
eurjchem-2518	182	8	is	be	AUX
eurjchem-2518	182	9	not	not	PART
eurjchem-2518	182	10	possible	possible	ADJ
eurjchem-2518	182	11	.	.	PUNCT
eurjchem-2518	183	1	no	no	ADV
eurjchem-2518	183	2	doubt	doubt	ADV
eurjchem-2518	183	3	,	,	PUNCT
eurjchem-2518	183	4	this	this	DET
eurjchem-2518	183	5	reaction	reaction	NOUN
eurjchem-2518	183	6	mechanism	mechanism	NOUN
eurjchem-2518	183	7	requires	require	VERB
eurjchem-2518	183	8	a	a	DET
eurjchem-2518	183	9	comprehensive	comprehensive	ADJ
eurjchem-2518	183	10	study	study	NOUN
eurjchem-2518	183	11	by	by	ADP
eurjchem-2518	183	12	theoretical	theoretical	ADJ
eurjchem-2518	183	13	and	and	CCONJ
eurjchem-2518	183	14	experimental	experimental	ADJ
eurjchem-2518	183	15	methods	method	NOUN
eurjchem-2518	183	16	,	,	PUNCT
eurjchem-2518	183	17	taking	take	VERB
eurjchem-2518	183	18	into	into	ADP
eurjchem-2518	183	19	account	account	NOUN
eurjchem-2518	183	20	the	the	DET
eurjchem-2518	183	21	entropy	entropy	NOUN
eurjchem-2518	183	22	and	and	CCONJ
eurjchem-2518	183	23	determining	determine	VERB
eurjchem-2518	183	24	the	the	DET
eurjchem-2518	183	25	gibbs	gibbs	PROPN
eurjchem-2518	183	26	free	free	ADJ
eurjchem-2518	183	27	energy	energy	NOUN
eurjchem-2518	183	28	at	at	ADP
eurjchem-2518	183	29	all	all	DET
eurjchem-2518	183	30	stages	stage	NOUN
eurjchem-2518	183	31	of	of	ADP
eurjchem-2518	183	32	the	the	DET
eurjchem-2518	183	33	catalytic	catalytic	ADJ
eurjchem-2518	183	34	cycle	cycle	NOUN
eurjchem-2518	183	35	,	,	PUNCT
eurjchem-2518	183	36	similar	similar	ADJ
eurjchem-2518	183	37	to	to	ADP
eurjchem-2518	183	38	that	that	PRON
eurjchem-2518	183	39	we	we	PRON
eurjchem-2518	183	40	have	have	AUX
eurjchem-2518	183	41	done	do	VERB
eurjchem-2518	183	42	for	for	ADP
eurjchem-2518	183	43	sulfide	sulfide	NOUN
eurjchem-2518	183	44	catalysts	catalyst	NOUN
eurjchem-2518	183	45	(	(	PUNCT
eurjchem-2518	183	46	see	see	VERB
eurjchem-2518	183	47	previous	previous	ADJ
eurjchem-2518	183	48	section	section	NOUN
eurjchem-2518	183	49	)	)	PUNCT
eurjchem-2518	183	50	.	.	PUNCT
eurjchem-2518	184	1	4	4	X
eurjchem-2518	184	2	.	.	X
eurjchem-2518	184	3	entropy	entropy	NOUN
eurjchem-2518	184	4	of	of	ADP
eurjchem-2518	184	5	the	the	DET
eurjchem-2518	184	6	surface	surface	NOUN
eurjchem-2518	184	7	catalytic	catalytic	ADJ
eurjchem-2518	184	8	reaction	reaction	NOUN
eurjchem-2518	184	9	:	:	PUNCT
eurjchem-2518	184	10	why	why	SCONJ
eurjchem-2518	184	11	is	be	AUX
eurjchem-2518	184	12	it	it	PRON
eurjchem-2518	184	13	important	important	ADJ
eurjchem-2518	184	14	and	and	CCONJ
eurjchem-2518	184	15	necessary	necessary	ADJ
eurjchem-2518	184	16	?	?	PUNCT
eurjchem-2518	185	1	it	it	PRON
eurjchem-2518	185	2	is	be	AUX
eurjchem-2518	185	3	quite	quite	ADV
eurjchem-2518	185	4	obvious	obvious	ADJ
eurjchem-2518	185	5	that	that	SCONJ
eurjchem-2518	185	6	the	the	DET
eurjchem-2518	185	7	first	first	ADJ
eurjchem-2518	185	8	law	law	NOUN
eurjchem-2518	185	9	of	of	ADP
eurjchem-2518	185	10	thermodynamics	thermodynamic	NOUN
eurjchem-2518	185	11	,	,	PUNCT
eurjchem-2518	185	12	which	which	PRON
eurjchem-2518	185	13	we	we	PRON
eurjchem-2518	185	14	used	use	VERB
eurjchem-2518	185	15	to	to	PART
eurjchem-2518	185	16	analyze	analyze	VERB
eurjchem-2518	185	17	the	the	DET
eurjchem-2518	185	18	possibility	possibility	NOUN
eurjchem-2518	185	19	of	of	ADP
eurjchem-2518	185	20	h2s	h2s	NOUN
eurjchem-2518	185	21	decomposition	decomposition	NOUN
eurjchem-2518	185	22	on	on	ADP
eurjchem-2518	185	23	platinum	platinum	NOUN
eurjchem-2518	185	24	,	,	PUNCT
eurjchem-2518	185	25	can	can	AUX
eurjchem-2518	185	26	not	not	PART
eurjchem-2518	185	27	give	give	VERB
eurjchem-2518	185	28	an	an	DET
eurjchem-2518	185	29	unambiguous	unambiguous	ADJ
eurjchem-2518	185	30	answer	answer	NOUN
eurjchem-2518	185	31	to	to	ADP
eurjchem-2518	185	32	the	the	DET
eurjchem-2518	185	33	key	key	ADJ
eurjchem-2518	185	34	question	question	NOUN
eurjchem-2518	185	35	:	:	PUNCT
eurjchem-2518	185	36	is	be	AUX
eurjchem-2518	185	37	it	it	PRON
eurjchem-2518	185	38	possible	possible	ADJ
eurjchem-2518	185	39	in	in	ADP
eurjchem-2518	185	40	the	the	DET
eurjchem-2518	185	41	system	system	NOUN
eurjchem-2518	185	42	(	(	PUNCT
eurjchem-2518	185	43	h2s	h2s	NOUN
eurjchem-2518	185	44	–	–	PUNCT
eurjchem-2518	185	45	metal	metal	NOUN
eurjchem-2518	185	46	)	)	PUNCT
eurjchem-2518	185	47	noted	note	VERB
eurjchem-2518	185	48	in	in	ADP
eurjchem-2518	185	49	table	table	NOUN
eurjchem-2518	185	50	2	2	NUM
eurjchem-2518	185	51	a	a	DET
eurjchem-2518	185	52	spontaneous	spontaneous	ADJ
eurjchem-2518	185	53	catalytic	catalytic	ADJ
eurjchem-2518	185	54	process	process	NOUN
eurjchem-2518	185	55	to	to	PART
eurjchem-2518	185	56	occur	occur	VERB
eurjchem-2518	185	57	?	?	PUNCT
eurjchem-2518	186	1	to	to	PART
eurjchem-2518	186	2	answer	answer	VERB
eurjchem-2518	186	3	the	the	DET
eurjchem-2518	186	4	question	question	NOUN
eurjchem-2518	186	5	,	,	PUNCT
eurjchem-2518	186	6	these	these	DET
eurjchem-2518	186	7	systems	system	NOUN
eurjchem-2518	186	8	should	should	AUX
eurjchem-2518	186	9	be	be	AUX
eurjchem-2518	186	10	considered	consider	VERB
eurjchem-2518	186	11	within	within	ADP
eurjchem-2518	186	12	the	the	DET
eurjchem-2518	186	13	framework	framework	NOUN
eurjchem-2518	186	14	of	of	ADP
eurjchem-2518	186	15	the	the	DET
eurjchem-2518	186	16	second	second	ADJ
eurjchem-2518	186	17	law	law	NOUN
eurjchem-2518	186	18	of	of	ADP
eurjchem-2518	186	19	thermodynamics	thermodynamic	NOUN
eurjchem-2518	186	20	.	.	PUNCT
eurjchem-2518	187	1	first	first	ADV
eurjchem-2518	187	2	of	of	ADP
eurjchem-2518	187	3	all	all	PRON
eurjchem-2518	187	4	,	,	PUNCT
eurjchem-2518	187	5	this	this	DET
eurjchem-2518	187	6	problem	problem	NOUN
eurjchem-2518	187	7	seems	seem	VERB
eurjchem-2518	187	8	to	to	PART
eurjchem-2518	187	9	be	be	AUX
eurjchem-2518	187	10	very	very	ADV
eurjchem-2518	187	11	relevant	relevant	ADJ
eurjchem-2518	187	12	in	in	ADP
eurjchem-2518	187	13	connection	connection	NOUN
eurjchem-2518	187	14	with	with	ADP
eurjchem-2518	187	15	the	the	DET
eurjchem-2518	187	16	possibility	possibility	NOUN
eurjchem-2518	187	17	of	of	ADP
eurjchem-2518	187	18	avoiding	avoid	VERB
eurjchem-2518	187	19	time	time	NOUN
eurjchem-2518	187	20	-	-	PUNCT
eurjchem-2518	187	21	consuming	consume	VERB
eurjchem-2518	187	22	experimental	experimental	ADJ
eurjchem-2518	187	23	work	work	NOUN
eurjchem-2518	187	24	with	with	ADP
eurjchem-2518	187	25	toxic	toxic	ADJ
eurjchem-2518	187	26	and	and	CCONJ
eurjchem-2518	187	27	fetid	fetid	ADJ
eurjchem-2518	187	28	h2s	h2s	NOUN
eurjchem-2518	187	29	.	.	PUNCT
eurjchem-2518	188	1	secondly	secondly	ADV
eurjchem-2518	188	2	,	,	PUNCT
eurjchem-2518	188	3	the	the	DET
eurjchem-2518	188	4	prediction	prediction	NOUN
eurjchem-2518	188	5	of	of	ADP
eurjchem-2518	188	6	the	the	DET
eurjchem-2518	188	7	possibility	possibility	NOUN
eurjchem-2518	188	8	of	of	ADP
eurjchem-2518	188	9	carrying	carry	VERB
eurjchem-2518	188	10	out	out	ADP
eurjchem-2518	188	11	unusual	unusual	ADJ
eurjchem-2518	188	12	catalytic	catalytic	ADJ
eurjchem-2518	188	13	reactions	reaction	NOUN
eurjchem-2518	188	14	involving	involve	VERB
eurjchem-2518	188	15	h2s	h2s	NOUN
eurjchem-2518	188	16	may	may	AUX
eurjchem-2518	188	17	be	be	AUX
eurjchem-2518	188	18	of	of	ADP
eurjchem-2518	188	19	the	the	DET
eurjchem-2518	188	20	highest	high	ADJ
eurjchem-2518	188	21	scientific	scientific	ADJ
eurjchem-2518	188	22	and	and	CCONJ
eurjchem-2518	188	23	practical	practical	ADJ
eurjchem-2518	188	24	interest	interest	NOUN
eurjchem-2518	188	25	.	.	PUNCT
eurjchem-2518	189	1	having	having	AUX
eurjchem-2518	189	2	considered	consider	VERB
eurjchem-2518	189	3	the	the	DET
eurjchem-2518	189	4	necessary	necessary	ADJ
eurjchem-2518	189	5	background	background	NOUN
eurjchem-2518	189	6	,	,	PUNCT
eurjchem-2518	189	7	let	let	VERB
eurjchem-2518	189	8	us	we	PRON
eurjchem-2518	189	9	look	look	VERB
eurjchem-2518	189	10	at	at	ADP
eurjchem-2518	189	11	the	the	DET
eurjchem-2518	189	12	problem	problem	NOUN
eurjchem-2518	189	13	of	of	ADP
eurjchem-2518	189	14	predicting	predict	VERB
eurjchem-2518	189	15	the	the	DET
eurjchem-2518	189	16	catalytic	catalytic	ADJ
eurjchem-2518	189	17	activity	activity	NOUN
eurjchem-2518	189	18	for	for	ADP
eurjchem-2518	189	19	the	the	DET
eurjchem-2518	189	20	(	(	PUNCT
eurjchem-2518	189	21	h2s	h2s	NOUN
eurjchem-2518	189	22	–	–	PUNCT
eurjchem-2518	189	23	metal	metal	NOUN
eurjchem-2518	189	24	)	)	PUNCT
eurjchem-2518	189	25	system	system	NOUN
eurjchem-2518	189	26	,	,	PUNCT
eurjchem-2518	189	27	some	some	DET
eurjchem-2518	189	28	examples	example	NOUN
eurjchem-2518	189	29	of	of	ADP
eurjchem-2518	189	30	which	which	PRON
eurjchem-2518	189	31	are	be	AUX
eurjchem-2518	189	32	shown	show	VERB
eurjchem-2518	189	33	in	in	ADP
eurjchem-2518	189	34	table	table	NOUN
eurjchem-2518	189	35	2	2	NUM
eurjchem-2518	189	36	.	.	PUNCT
eurjchem-2518	190	1	this	this	DET
eurjchem-2518	190	2	very	very	ADV
eurjchem-2518	190	3	attractive	attractive	ADJ
eurjchem-2518	190	4	task	task	NOUN
eurjchem-2518	190	5	should	should	AUX
eurjchem-2518	190	6	begin	begin	VERB
eurjchem-2518	190	7	with	with	ADP
eurjchem-2518	190	8	calculating	calculate	VERB
eurjchem-2518	190	9	the	the	DET
eurjchem-2518	190	10	entropy	entropy	NOUN
eurjchem-2518	190	11	of	of	ADP
eurjchem-2518	190	12	the	the	DET
eurjchem-2518	190	13	successive	successive	ADJ
eurjchem-2518	190	14	stages	stage	NOUN
eurjchem-2518	190	15	of	of	ADP
eurjchem-2518	190	16	h2s	h2s	NOUN
eurjchem-2518	190	17	dissociation	dissociation	NOUN
eurjchem-2518	190	18	,	,	PUNCT
eurjchem-2518	190	19	as	as	SCONJ
eurjchem-2518	190	20	we	we	PRON
eurjchem-2518	190	21	have	have	AUX
eurjchem-2518	190	22	done	do	VERB
eurjchem-2518	190	23	for	for	ADP
eurjchem-2518	190	24	sulfide	sulfide	NOUN
eurjchem-2518	190	25	catalysts	catalyst	NOUN
eurjchem-2518	190	26	(	(	PUNCT
eurjchem-2518	190	27	see	see	VERB
eurjchem-2518	190	28	above	above	ADV
eurjchem-2518	190	29	)	)	PUNCT
eurjchem-2518	190	30	.	.	PUNCT
eurjchem-2518	191	1	in	in	ADP
eurjchem-2518	191	2	this	this	DET
eurjchem-2518	191	3	case	case	NOUN
eurjchem-2518	191	4	,	,	PUNCT
eurjchem-2518	191	5	it	it	PRON
eurjchem-2518	191	6	is	be	AUX
eurjchem-2518	191	7	necessary	necessary	ADJ
eurjchem-2518	191	8	to	to	PART
eurjchem-2518	191	9	consider	consider	VERB
eurjchem-2518	191	10	the	the	DET
eurjchem-2518	191	11	isothermal	isothermal	ADJ
eurjchem-2518	191	12	isobaric	isobaric	ADJ
eurjchem-2518	191	13	process	process	NOUN
eurjchem-2518	191	14	occurring	occur	VERB
eurjchem-2518	191	15	on	on	ADP
eurjchem-2518	191	16	the	the	DET
eurjchem-2518	191	17	surface	surface	NOUN
eurjchem-2518	191	18	of	of	ADP
eurjchem-2518	191	19	the	the	DET
eurjchem-2518	191	20	catalyst	catalyst	NOUN
eurjchem-2518	191	21	within	within	ADP
eurjchem-2518	191	22	the	the	DET
eurjchem-2518	191	23	framework	framework	NOUN
eurjchem-2518	191	24	of	of	ADP
eurjchem-2518	191	25	non	non	ADJ
eurjchem-2518	191	26	-	-	ADJ
eurjchem-2518	191	27	equilibrium	equilibrium	ADJ
eurjchem-2518	191	28	thermodynamics	thermodynamic	NOUN
eurjchem-2518	191	29	for	for	ADP
eurjchem-2518	191	30	an	an	DET
eurjchem-2518	191	31	open	open	ADJ
eurjchem-2518	191	32	system	system	NOUN
eurjchem-2518	191	33	,	,	PUNCT
eurjchem-2518	191	34	i.e.	i.e.	X
eurjchem-2518	191	35	with	with	ADP
eurjchem-2518	191	36	continuous	continuous	ADJ
eurjchem-2518	191	37	supply	supply	NOUN
eurjchem-2518	191	38	with	with	ADP
eurjchem-2518	191	39	h2s	h2s	NOUN
eurjchem-2518	191	40	and	and	CCONJ
eurjchem-2518	191	41	removal	removal	NOUN
eurjchem-2518	191	42	of	of	ADP
eurjchem-2518	191	43	reaction	reaction	NOUN
eurjchem-2518	191	44	products	product	NOUN
eurjchem-2518	191	45	from	from	ADP
eurjchem-2518	191	46	the	the	DET
eurjchem-2518	191	47	catalyst	catalyst	NOUN
eurjchem-2518	191	48	surface	surface	NOUN
eurjchem-2518	192	1	[	[	X
eurjchem-2518	192	2	10,11	10,11	NOUN
eurjchem-2518	192	3	]	]	X
eurjchem-2518	192	4	.	.	PUNCT
eurjchem-2518	193	1	therefore	therefore	ADV
eurjchem-2518	193	2	,	,	PUNCT
eurjchem-2518	193	3	knowing	know	VERB
eurjchem-2518	193	4	the	the	DET
eurjchem-2518	193	5	entropy	entropy	NOUN
eurjchem-2518	193	6	change	change	NOUN
eurjchem-2518	193	7	of	of	ADP
eurjchem-2518	193	8	each	each	DET
eurjchem-2518	193	9	elementary	elementary	ADJ
eurjchem-2518	193	10	stage	stage	NOUN
eurjchem-2518	193	11	of	of	ADP
eurjchem-2518	193	12	the	the	DET
eurjchem-2518	193	13	h2s	h2s	PROPN
eurjchem-2518	193	14	dissociation	dissociation	NOUN
eurjchem-2518	193	15	,	,	PUNCT
eurjchem-2518	193	16	the	the	DET
eurjchem-2518	193	17	gibbs	gibbs	PROPN
eurjchem-2518	193	18	free	free	ADJ
eurjchem-2518	193	19	energy	energy	NOUN
eurjchem-2518	193	20	value	value	NOUN
eurjchem-2518	193	21	for	for	ADP
eurjchem-2518	193	22	the	the	DET
eurjchem-2518	193	23	descending	descend	VERB
eurjchem-2518	193	24	branch	branch	NOUN
eurjchem-2518	193	25	of	of	ADP
eurjchem-2518	193	26	the	the	DET
eurjchem-2518	193	27	process	process	NOUN
eurjchem-2518	193	28	energetic	energetic	ADJ
eurjchem-2518	193	29	profile	profile	NOUN
eurjchem-2518	193	30	will	will	AUX
eurjchem-2518	193	31	be	be	AUX
eurjchem-2518	193	32	obtained	obtain	VERB
eurjchem-2518	193	33	(	(	PUNCT
eurjchem-2518	193	34	see	see	VERB
eurjchem-2518	193	35	figure	figure	NOUN
eurjchem-2518	193	36	2	2	NUM
eurjchem-2518	193	37	)	)	PUNCT
eurjchem-2518	193	38	.	.	PUNCT
eurjchem-2518	194	1	the	the	DET
eurjchem-2518	194	2	desorption	desorption	NOUN
eurjchem-2518	194	3	(	(	PUNCT
eurjchem-2518	194	4	ascending	ascend	VERB
eurjchem-2518	194	5	)	)	PUNCT
eurjchem-2518	194	6	branch	branch	NOUN
eurjchem-2518	194	7	of	of	ADP
eurjchem-2518	194	8	the	the	DET
eurjchem-2518	194	9	energy	energy	NOUN
eurjchem-2518	194	10	profile	profile	NOUN
eurjchem-2518	194	11	does	do	AUX
eurjchem-2518	194	12	not	not	PART
eurjchem-2518	194	13	seem	seem	VERB
eurjchem-2518	194	14	to	to	PART
eurjchem-2518	194	15	have	have	VERB
eurjchem-2518	194	16	any	any	DET
eurjchem-2518	194	17	thermodynamic	thermodynamic	ADJ
eurjchem-2518	194	18	or	or	CCONJ
eurjchem-2518	194	19	kinetic	kinetic	ADJ
eurjchem-2518	194	20	limitations	limitation	NOUN
eurjchem-2518	194	21	.	.	PUNCT
eurjchem-2518	195	1	indeed	indeed	ADV
eurjchem-2518	195	2	,	,	PUNCT
eurjchem-2518	195	3	molecular	molecular	ADJ
eurjchem-2518	195	4	hydrogen	hydrogen	NOUN
eurjchem-2518	195	5	easily	easily	ADV
eurjchem-2518	195	6	leaves	leave	VERB
eurjchem-2518	195	7	the	the	DET
eurjchem-2518	195	8	surface	surface	NOUN
eurjchem-2518	195	9	of	of	ADP
eurjchem-2518	195	10	the	the	DET
eurjchem-2518	195	11	catalyst	catalyst	NOUN
eurjchem-2518	195	12	because	because	SCONJ
eurjchem-2518	195	13	of	of	ADP
eurjchem-2518	195	14	the	the	DET
eurjchem-2518	195	15	low	low	ADJ
eurjchem-2518	195	16	heat	heat	NOUN
eurjchem-2518	195	17	of	of	ADP
eurjchem-2518	195	18	adsorption	adsorption	NOUN
eurjchem-2518	195	19	compared	compare	VERB
eurjchem-2518	195	20	to	to	ADP
eurjchem-2518	195	21	the	the	DET
eurjchem-2518	195	22	potential	potential	ADJ
eurjchem-2518	195	23	energy	energy	NOUN
eurjchem-2518	195	24	accumulated	accumulate	VERB
eurjchem-2518	195	25	on	on	ADP
eurjchem-2518	195	26	the	the	DET
eurjchem-2518	195	27	surface	surface	NOUN
eurjchem-2518	195	28	.	.	PUNCT
eurjchem-2518	196	1	the	the	DET
eurjchem-2518	196	2	limiting	limit	VERB
eurjchem-2518	196	3	stage	stage	NOUN
eurjchem-2518	196	4	of	of	ADP
eurjchem-2518	196	5	the	the	DET
eurjchem-2518	196	6	surface	surface	NOUN
eurjchem-2518	196	7	reaction	reaction	NOUN
eurjchem-2518	196	8	is	be	AUX
eurjchem-2518	196	9	apparently	apparently	ADV
eurjchem-2518	196	10	the	the	DET
eurjchem-2518	196	11	formation	formation	NOUN
eurjchem-2518	196	12	of	of	ADP
eurjchem-2518	196	13	diatomic	diatomic	ADJ
eurjchem-2518	196	14	sulfur	sulfur	NOUN
eurjchem-2518	196	15	,	,	PUNCT
eurjchem-2518	196	16	which	which	PRON
eurjchem-2518	196	17	occurs	occur	VERB
eurjchem-2518	196	18	through	through	ADP
eurjchem-2518	196	19	a	a	DET
eurjchem-2518	196	20	low	low	ADJ
eurjchem-2518	196	21	energetic	energetic	ADJ
eurjchem-2518	196	22	barrier	barrier	NOUN
eurjchem-2518	196	23	due	due	ADP
eurjchem-2518	196	24	to	to	ADP
eurjchem-2518	196	25	the	the	DET
eurjchem-2518	196	26	need	need	NOUN
eurjchem-2518	196	27	for	for	ADP
eurjchem-2518	196	28	migration	migration	NOUN
eurjchem-2518	196	29	of	of	ADP
eurjchem-2518	196	30	atomic	atomic	ADJ
eurjchem-2518	196	31	zerovalence	zerovalence	NOUN
eurjchem-2518	196	32	sulfur	sulfur	NOUN
eurjchem-2518	196	33	along	along	ADP
eurjchem-2518	196	34	the	the	DET
eurjchem-2518	196	35	catalyst	catalyst	NOUN
eurjchem-2518	196	36	surface	surface	NOUN
eurjchem-2518	196	37	.	.	PUNCT
eurjchem-2518	197	1	however	however	ADV
eurjchem-2518	197	2	,	,	PUNCT
eurjchem-2518	197	3	singlet	singlet	ADJ
eurjchem-2518	197	4	sulfur	sulfur	NOUN
eurjchem-2518	197	5	,	,	PUNCT
eurjchem-2518	197	6	which	which	PRON
eurjchem-2518	197	7	initially	initially	ADV
eurjchem-2518	197	8	forms	form	VERB
eurjchem-2518	197	9	a	a	DET
eurjchem-2518	197	10	h2s	h2s	NOUN
eurjchem-2518	197	11	molecule	molecule	NOUN
eurjchem-2518	197	12	,	,	PUNCT
eurjchem-2518	197	13	spontaneously	spontaneously	ADV
eurjchem-2518	197	14	transmits	transmit	VERB
eurjchem-2518	197	15	to	to	ADP
eurjchem-2518	197	16	the	the	DET
eurjchem-2518	197	17	ground	ground	NOUN
eurjchem-2518	197	18	triplet	triplet	NOUN
eurjchem-2518	197	19	state	state	NOUN
eurjchem-2518	197	20	,	,	PUNCT
eurjchem-2518	197	21	since	since	SCONJ
eurjchem-2518	197	22	the	the	DET
eurjchem-2518	197	23	presence	presence	NOUN
eurjchem-2518	197	24	of	of	ADP
eurjchem-2518	197	25	free	free	ADJ
eurjchem-2518	197	26	electrons	electron	NOUN
eurjchem-2518	197	27	in	in	ADP
eurjchem-2518	197	28	the	the	DET
eurjchem-2518	197	29	metal	metal	NOUN
eurjchem-2518	197	30	conduction	conduction	NOUN
eurjchem-2518	197	31	band	band	NOUN
eurjchem-2518	197	32	helps	help	VERB
eurjchem-2518	197	33	to	to	PART
eurjchem-2518	197	34	lift	lift	VERB
eurjchem-2518	197	35	the	the	DET
eurjchem-2518	197	36	ban	ban	NOUN
eurjchem-2518	197	37	on	on	ADP
eurjchem-2518	197	38	electronic	electronic	ADJ
eurjchem-2518	197	39	transitions	transition	NOUN
eurjchem-2518	197	40	of	of	ADP
eurjchem-2518	197	41	singlet	singlet	ADJ
eurjchem-2518	197	42	sulfur	sulfur	NOUN
eurjchem-2518	197	43	to	to	ADP
eurjchem-2518	197	44	the	the	DET
eurjchem-2518	197	45	thermodynamically	thermodynamically	ADV
eurjchem-2518	197	46	most	most	ADV
eurjchem-2518	197	47	stable	stable	ADJ
eurjchem-2518	197	48	ground	ground	NOUN
eurjchem-2518	197	49	triplet	triplet	NOUN
eurjchem-2518	197	50	state	state	NOUN
eurjchem-2518	197	51	.	.	PUNCT
eurjchem-2518	198	1	in	in	ADP
eurjchem-2518	198	2	an	an	DET
eurjchem-2518	198	3	isolated	isolated	ADJ
eurjchem-2518	198	4	s2	s2	NOUN
eurjchem-2518	198	5	molecule	molecule	NOUN
eurjchem-2518	198	6	,	,	PUNCT
eurjchem-2518	198	7	the	the	DET
eurjchem-2518	198	8	direct	direct	ADJ
eurjchem-2518	198	9	singlet	singlet	NOUN
eurjchem-2518	198	10	-	-	PUNCT
eurjchem-2518	198	11	triplet	triplet	NOUN
eurjchem-2518	198	12	transition	transition	NOUN
eurjchem-2518	198	13	is	be	AUX
eurjchem-2518	198	14	prohibited	prohibit	VERB
eurjchem-2518	198	15	by	by	ADP
eurjchem-2518	198	16	the	the	DET
eurjchem-2518	198	17	selection	selection	NOUN
eurjchem-2518	198	18	rules	rule	NOUN
eurjchem-2518	198	19	.	.	PUNCT
eurjchem-2518	199	1	recall	recall	VERB
eurjchem-2518	199	2	that	that	SCONJ
eurjchem-2518	199	3	the	the	DET
eurjchem-2518	199	4	entropy	entropy	NOUN
eurjchem-2518	199	5	of	of	ADP
eurjchem-2518	199	6	reaction	reaction	NOUN
eurjchem-2518	199	7	5	5	NUM
eurjchem-2518	199	8	is	be	AUX
eurjchem-2518	199	9	always	always	ADV
eurjchem-2518	199	10	positive	positive	ADJ
eurjchem-2518	199	11	because	because	SCONJ
eurjchem-2518	199	12	the	the	DET
eurjchem-2518	199	13	number	number	NOUN
eurjchem-2518	199	14	of	of	ADP
eurjchem-2518	199	15	gaseous	gaseous	ADJ
eurjchem-2518	199	16	reaction	reaction	NOUN
eurjchem-2518	199	17	products	product	NOUN
eurjchem-2518	199	18	increases	increase	NOUN
eurjchem-2518	199	19	.	.	PUNCT
eurjchem-2518	200	1	thus	thus	ADV
eurjchem-2518	200	2	,	,	PUNCT
eurjchem-2518	200	3	if	if	SCONJ
eurjchem-2518	200	4	the	the	DET
eurjchem-2518	200	5	thermodynamic	thermodynamic	ADJ
eurjchem-2518	200	6	calculations	calculation	NOUN
eurjchem-2518	200	7	of	of	ADP
eurjchem-2518	200	8	the	the	DET
eurjchem-2518	200	9	surface	surface	NOUN
eurjchem-2518	200	10	reaction	reaction	NOUN
eurjchem-2518	200	11	turn	turn	VERB
eurjchem-2518	200	12	out	out	ADP
eurjchem-2518	200	13	to	to	PART
eurjchem-2518	200	14	be	be	AUX
eurjchem-2518	200	15	favorable	favorable	ADJ
eurjchem-2518	200	16	for	for	ADP
eurjchem-2518	200	17	the	the	DET
eurjchem-2518	200	18	implementation	implementation	NOUN
eurjchem-2518	200	19	of	of	ADP
eurjchem-2518	200	20	the	the	DET
eurjchem-2518	200	21	catalytic	catalytic	ADJ
eurjchem-2518	200	22	process	process	NOUN
eurjchem-2518	200	23	in	in	ADP
eurjchem-2518	200	24	the	the	DET
eurjchem-2518	200	25	system	system	NOUN
eurjchem-2518	200	26	(	(	PUNCT
eurjchem-2518	200	27	h2s	h2s	NOUN
eurjchem-2518	200	28	–	–	PUNCT
eurjchem-2518	200	29	metal	metal	NOUN
eurjchem-2518	200	30	)	)	PUNCT
eurjchem-2518	200	31	(	(	PUNCT
eurjchem-2518	200	32	table	table	NOUN
eurjchem-2518	200	33	2	2	NUM
eurjchem-2518	200	34	)	)	PUNCT
eurjchem-2518	200	35	,	,	PUNCT
eurjchem-2518	200	36	then	then	ADV
eurjchem-2518	200	37	this	this	PRON
eurjchem-2518	200	38	will	will	AUX
eurjchem-2518	200	39	mean	mean	VERB
eurjchem-2518	200	40	confirmation	confirmation	NOUN
eurjchem-2518	200	41	of	of	ADP
eurjchem-2518	200	42	our	our	PRON
eurjchem-2518	200	43	concept	concept	NOUN
eurjchem-2518	200	44	on	on	ADP
eurjchem-2518	200	45	the	the	DET
eurjchem-2518	200	46	decisive	decisive	ADJ
eurjchem-2518	200	47	role	role	NOUN
eurjchem-2518	200	48	of	of	ADP
eurjchem-2518	200	49	catalysts	catalyst	NOUN
eurjchem-2518	200	50	in	in	ADP
eurjchem-2518	200	51	the	the	DET
eurjchem-2518	200	52	process	process	NOUN
eurjchem-2518	200	53	of	of	ADP
eurjchem-2518	200	54	low	low	ADJ
eurjchem-2518	200	55	-	-	PUNCT
eurjchem-2518	200	56	temperature	temperature	NOUN
eurjchem-2518	200	57	h2s	h2s	NOUN
eurjchem-2518	200	58	decomposition	decomposition	NOUN
eurjchem-2518	200	59	[	[	X
eurjchem-2518	200	60	10,11	10,11	NOUN
eurjchem-2518	200	61	]	]	PUNCT
eurjchem-2518	200	62	.	.	PUNCT
eurjchem-2518	201	1	these	these	DET
eurjchem-2518	201	2	metals	metal	NOUN
eurjchem-2518	201	3	are	be	AUX
eurjchem-2518	201	4	also	also	ADV
eurjchem-2518	201	5	mentioned	mention	VERB
eurjchem-2518	201	6	in	in	ADP
eurjchem-2518	201	7	the	the	DET
eurjchem-2518	201	8	patent	patent	NOUN
eurjchem-2518	201	9	[	[	X
eurjchem-2518	201	10	24	24	NUM
eurjchem-2518	201	11	]	]	PUNCT
eurjchem-2518	201	12	.	.	PUNCT
eurjchem-2518	202	1	however	however	ADV
eurjchem-2518	202	2	,	,	PUNCT
eurjchem-2518	202	3	in	in	ADP
eurjchem-2518	202	4	this	this	DET
eurjchem-2518	202	5	case	case	NOUN
eurjchem-2518	202	6	,	,	PUNCT
eurjchem-2518	202	7	we	we	PRON
eurjchem-2518	202	8	will	will	AUX
eurjchem-2518	202	9	be	be	AUX
eurjchem-2518	202	10	interested	interested	ADJ
eurjchem-2518	202	11	in	in	ADP
eurjchem-2518	202	12	catalytic	catalytic	ADJ
eurjchem-2518	202	13	reactions	reaction	NOUN
eurjchem-2518	202	14	in	in	ADP
eurjchem-2518	202	15	which	which	PRON
eurjchem-2518	202	16	atomic	atomic	ADJ
eurjchem-2518	202	17	hydrogen	hydrogen	NOUN
eurjchem-2518	202	18	and	and	CCONJ
eurjchem-2518	202	19	sulfur	sulfur	NOUN
eurjchem-2518	202	20	,	,	PUNCT
eurjchem-2518	202	21	obtained	obtain	VERB
eurjchem-2518	202	22	on	on	ADP
eurjchem-2518	202	23	the	the	DET
eurjchem-2518	202	24	surface	surface	NOUN
eurjchem-2518	202	25	of	of	ADP
eurjchem-2518	202	26	solid	solid	ADJ
eurjchem-2518	202	27	catalysts	catalyst	NOUN
eurjchem-2518	202	28	in	in	ADP
eurjchem-2518	202	29	the	the	DET
eurjchem-2518	202	30	process	process	NOUN
eurjchem-2518	202	31	of	of	ADP
eurjchem-2518	202	32	low	low	ADJ
eurjchem-2518	202	33	-	-	PUNCT
eurjchem-2518	202	34	temperature	temperature	NOUN
eurjchem-2518	202	35	h2s	h2s	NOUN
eurjchem-2518	202	36	decomposition	decomposition	NOUN
eurjchem-2518	202	37	,	,	PUNCT
eurjchem-2518	202	38	may	may	AUX
eurjchem-2518	202	39	interact	interact	VERB
eurjchem-2518	202	40	with	with	ADP
eurjchem-2518	202	41	chemically	chemically	ADV
eurjchem-2518	202	42	inert	inert	ADJ
eurjchem-2518	202	43	molecules	molecule	NOUN
eurjchem-2518	202	44	of	of	ADP
eurjchem-2518	202	45	methane	methane	NOUN
eurjchem-2518	202	46	,	,	PUNCT
eurjchem-2518	202	47	carbon	carbon	NOUN
eurjchem-2518	202	48	dioxide	dioxide	NOUN
eurjchem-2518	202	49	,	,	PUNCT
eurjchem-2518	202	50	molecular	molecular	ADJ
eurjchem-2518	202	51	nitrogen	nitrogen	NOUN
eurjchem-2518	202	52	,	,	PUNCT
eurjchem-2518	202	53	and	and	CCONJ
eurjchem-2518	202	54	argon	argon	NOUN
eurjchem-2518	202	55	.	.	PUNCT
eurjchem-2518	203	1	so	so	ADV
eurjchem-2518	203	2	,	,	PUNCT
eurjchem-2518	203	3	it	it	PRON
eurjchem-2518	203	4	should	should	AUX
eurjchem-2518	203	5	be	be	AUX
eurjchem-2518	203	6	expected	expect	VERB
eurjchem-2518	203	7	that	that	SCONJ
eurjchem-2518	203	8	the	the	DET
eurjchem-2518	203	9	atomically	atomically	ADV
eurjchem-2518	203	10	dispersed	disperse	VERB
eurjchem-2518	203	11	surface	surface	NOUN
eurjchem-2518	203	12	species	specie	NOUN
eurjchem-2518	203	13	of	of	ADP
eurjchem-2518	203	14	hydrogen	hydrogen	NOUN
eurjchem-2518	203	15	and	and	CCONJ
eurjchem-2518	203	16	sulfur	sulfur	NOUN
eurjchem-2518	203	17	produced	produce	VERB
eurjchem-2518	203	18	in	in	ADP
eurjchem-2518	203	19	reaction	reaction	NOUN
eurjchem-2518	203	20	7	7	NUM
eurjchem-2518	203	21	,	,	PUNCT
eurjchem-2518	203	22	(	(	PUNCT
eurjchem-2518	203	23	7	7	X
eurjchem-2518	203	24	)	)	PUNCT
eurjchem-2518	203	25	have	have	VERB
eurjchem-2518	203	26	an	an	DET
eurjchem-2518	203	27	extremely	extremely	ADV
eurjchem-2518	203	28	high	high	ADJ
eurjchem-2518	203	29	reactivity	reactivity	NOUN
eurjchem-2518	203	30	;	;	PUNCT
eurjchem-2518	203	31	therefore	therefore	ADV
eurjchem-2518	203	32	,	,	PUNCT
eurjchem-2518	203	33	they	they	PRON
eurjchem-2518	203	34	can	can	AUX
eurjchem-2518	203	35	enter	enter	VERB
eurjchem-2518	203	36	into	into	ADP
eurjchem-2518	203	37	coupling	couple	VERB
eurjchem-2518	203	38	reactions	reaction	NOUN
eurjchem-2518	203	39	with	with	ADP
eurjchem-2518	203	40	chemically	chemically	ADV
eurjchem-2518	203	41	inert	inert	ADJ
eurjchem-2518	203	42	molecules	molecule	NOUN
eurjchem-2518	203	43	[	[	X
eurjchem-2518	203	44	11,12	11,12	NUM
eurjchem-2518	203	45	]	]	PUNCT
eurjchem-2518	203	46	.	.	PUNCT
eurjchem-2518	204	1	for	for	ADP
eurjchem-2518	204	2	example	example	NOUN
eurjchem-2518	204	3	,	,	PUNCT
eurjchem-2518	204	4	a	a	DET
eurjchem-2518	204	5	methane	methane	NOUN
eurjchem-2518	204	6	molecule	molecule	NOUN
eurjchem-2518	204	7	dissociates	dissociate	NOUN
eurjchem-2518	204	8	very	very	ADV
eurjchem-2518	204	9	weakly	weakly	ADV
eurjchem-2518	204	10	on	on	ADP
eurjchem-2518	204	11	the	the	DET
eurjchem-2518	204	12	surface	surface	NOUN
eurjchem-2518	204	13	of	of	ADP
eurjchem-2518	204	14	pt(111	pt(111	ADJ
eurjchem-2518	204	15	)	)	PUNCT
eurjchem-2518	204	16	at	at	ADP
eurjchem-2518	204	17	room	room	NOUN
eurjchem-2518	204	18	temperature	temperature	NOUN
eurjchem-2518	204	19	[	[	X
eurjchem-2518	204	20	39	39	NUM
eurjchem-2518	204	21	]	]	PUNCT
eurjchem-2518	204	22	,	,	PUNCT
eurjchem-2518	204	23	however	however	ADV
eurjchem-2518	204	24	,	,	PUNCT
eurjchem-2518	204	25	in	in	ADP
eurjchem-2518	204	26	the	the	DET
eurjchem-2518	204	27	presence	presence	NOUN
eurjchem-2518	204	28	of	of	ADP
eurjchem-2518	204	29	adsorbed	adsorb	VERB
eurjchem-2518	204	30	atomic	atomic	ADJ
eurjchem-2518	204	31	sulfur	sulfur	NOUN
eurjchem-2518	204	32	species	specie	NOUN
eurjchem-2518	204	33	,	,	PUNCT
eurjchem-2518	204	34	the	the	DET
eurjchem-2518	204	35	following	follow	VERB
eurjchem-2518	204	36	chemical	chemical	ADJ
eurjchem-2518	204	37	reaction	reaction	NOUN
eurjchem-2518	204	38	(	(	PUNCT
eurjchem-2518	204	39	reaction	reaction	NOUN
eurjchem-2518	204	40	8)	8)	NUM
eurjchem-2518	204	41	is	be	AUX
eurjchem-2518	204	42	apparently	apparently	ADV
eurjchem-2518	204	43	possible	possible	ADJ
eurjchem-2518	204	44	.	.	PUNCT
eurjchem-2518	205	1	2	2	NUM
eurjchem-2518	205	2	{	{	PUNCT
eurjchem-2518	205	3	s	s	NOUN
eurjchem-2518	205	4	*	*	NOUN
eurjchem-2518	205	5	}	}	PUNCT
eurjchem-2518	205	6	ch4	ch4	NOUN
eurjchem-2518	205	7	cs2	cs2	NOUN
eurjchem-2518	205	8	2h2	2h2	NUM
eurjchem-2518	205	9	metal	metal	NOUN
eurjchem-2518	205	10	,	,	PUNCT
eurjchem-2518	205	11	25	25	NUM
eurjchem-2518	205	12	oc	oc	NOUN
eurjchem-2518	205	13	(	(	PUNCT
eurjchem-2518	205	14	8)	8)	NUM
eurjchem-2518	205	15	reaction	reaction	NOUN
eurjchem-2518	205	16	8	8	NUM
eurjchem-2518	205	17	is	be	AUX
eurjchem-2518	205	18	attractive	attractive	ADJ
eurjchem-2518	205	19	because	because	SCONJ
eurjchem-2518	205	20	methane	methane	NOUN
eurjchem-2518	205	21	hydrate	hydrate	NOUN
eurjchem-2518	205	22	and	and	CCONJ
eurjchem-2518	205	23	h2s	h2s	NOUN
eurjchem-2518	205	24	,	,	PUNCT
eurjchem-2518	205	25	whose	whose	DET
eurjchem-2518	205	26	reserves	reserve	NOUN
eurjchem-2518	205	27	,	,	PUNCT
eurjchem-2518	205	28	for	for	ADP
eurjchem-2518	205	29	example	example	NOUN
eurjchem-2518	205	30	,	,	PUNCT
eurjchem-2518	205	31	in	in	ADP
eurjchem-2518	205	32	the	the	DET
eurjchem-2518	205	33	black	black	PROPN
eurjchem-2518	205	34	sea	sea	PROPN
eurjchem-2518	205	35	,	,	PUNCT
eurjchem-2518	205	36	are	be	AUX
eurjchem-2518	205	37	practically	practically	ADV
eurjchem-2518	205	38	inexhaustible	inexhaustible	ADJ
eurjchem-2518	205	39	[	[	X
eurjchem-2518	205	40	40	40	NUM
eurjchem-2518	205	41	]	]	PUNCT
eurjchem-2518	205	42	,	,	PUNCT
eurjchem-2518	205	43	can	can	AUX
eurjchem-2518	205	44	be	be	AUX
eurjchem-2518	205	45	involved	involve	VERB
eurjchem-2518	205	46	in	in	ADP
eurjchem-2518	205	47	joint	joint	ADJ
eurjchem-2518	205	48	processing	processing	NOUN
eurjchem-2518	205	49	to	to	PART
eurjchem-2518	205	50	produce	produce	VERB
eurjchem-2518	205	51	the	the	DET
eurjchem-2518	205	52	target	target	NOUN
eurjchem-2518	205	53	product	product	NOUN
eurjchem-2518	205	54	,	,	PUNCT
eurjchem-2518	205	55	hydrogen	hydrogen	NOUN
eurjchem-2518	205	56	.	.	PUNCT
eurjchem-2518	206	1	a	a	DET
eurjchem-2518	206	2	similar	similar	ADJ
eurjchem-2518	206	3	coupling	coupling	NOUN
eurjchem-2518	206	4	of	of	ADP
eurjchem-2518	206	5	reactions	reaction	NOUN
eurjchem-2518	206	6	can	can	AUX
eurjchem-2518	206	7	occur	occur	VERB
eurjchem-2518	206	8	in	in	ADP
eurjchem-2518	206	9	the	the	DET
eurjchem-2518	206	10	case	case	NOUN
eurjchem-2518	206	11	of	of	ADP
eurjchem-2518	206	12	carbon	carbon	NOUN
eurjchem-2518	206	13	dioxide	dioxide	NOUN
eurjchem-2518	206	14	,	,	PUNCT
eurjchem-2518	206	15	which	which	PRON
eurjchem-2518	206	16	also	also	ADV
eurjchem-2518	206	17	weakly	weakly	ADJ
eurjchem-2518	206	18	dissociates	dissociate	NOUN
eurjchem-2518	206	19	on	on	ADP
eurjchem-2518	206	20	the	the	DET
eurjchem-2518	206	21	surface	surface	NOUN
eurjchem-2518	206	22	of	of	ADP
eurjchem-2518	206	23	solid	solid	ADJ
eurjchem-2518	206	24	catalysts	catalyst	NOUN
eurjchem-2518	206	25	(	(	PUNCT
eurjchem-2518	206	26	reaction	reaction	NOUN
eurjchem-2518	206	27	9	9	NUM
eurjchem-2518	206	28	)	)	PUNCT
eurjchem-2518	207	1	[	[	X
eurjchem-2518	207	2	41	41	NUM
eurjchem-2518	207	3	]	]	X
eurjchem-2518	207	4	:	:	PUNCT
eurjchem-2518	207	5	(	(	PUNCT
eurjchem-2518	207	6	9	9	X
eurjchem-2518	207	7	)	)	PUNCT
eurjchem-2518	207	8	apparently	apparently	ADV
eurjchem-2518	207	9	,	,	PUNCT
eurjchem-2518	207	10	it	it	PRON
eurjchem-2518	207	11	is	be	AUX
eurjchem-2518	207	12	this	this	DET
eurjchem-2518	207	13	reaction	reaction	NOUN
eurjchem-2518	207	14	9	9	NUM
eurjchem-2518	207	15	that	that	PRON
eurjchem-2518	207	16	underlies	underlie	VERB
eurjchem-2518	207	17	the	the	DET
eurjchem-2518	207	18	process	process	NOUN
eurjchem-2518	207	19	of	of	ADP
eurjchem-2518	207	20	chemosynthesis	chemosynthesis	NOUN
eurjchem-2518	207	21	by	by	ADP
eurjchem-2518	207	22	sulfur	sulfur	NOUN
eurjchem-2518	207	23	bacteria	bacteria	NOUN
eurjchem-2518	208	1	[	[	X
eurjchem-2518	208	2	2	2	NUM
eurjchem-2518	208	3	]	]	PUNCT
eurjchem-2518	208	4	.	.	PUNCT
eurjchem-2518	209	1	however	however	ADV
eurjchem-2518	209	2	,	,	PUNCT
eurjchem-2518	209	3	to	to	PART
eurjchem-2518	209	4	activate	activate	VERB
eurjchem-2518	209	5	the	the	DET
eurjchem-2518	209	6	co2	co2	NOUN
eurjchem-2518	209	7	molecule	molecule	NOUN
eurjchem-2518	209	8	,	,	PUNCT
eurjchem-2518	209	9	a	a	DET
eurjchem-2518	209	10	second	second	ADJ
eurjchem-2518	209	11	metal	metal	NOUN
eurjchem-2518	209	12	should	should	AUX
eurjchem-2518	209	13	be	be	AUX
eurjchem-2518	209	14	selected	select	VERB
eurjchem-2518	209	15	,	,	PUNCT
eurjchem-2518	209	16	as	as	SCONJ
eurjchem-2518	209	17	suggested	suggest	VERB
eurjchem-2518	209	18	by	by	ADP
eurjchem-2518	209	19	the	the	DET
eurjchem-2518	209	20	results	result	NOUN
eurjchem-2518	209	21	of	of	ADP
eurjchem-2518	209	22	the	the	DET
eurjchem-2518	209	23	work	work	NOUN
eurjchem-2518	209	24	[	[	X
eurjchem-2518	209	25	41	41	NUM
eurjchem-2518	209	26	]	]	PUNCT
eurjchem-2518	209	27	.	.	PUNCT
eurjchem-2518	210	1	192	192	NUM
eurjchem-2518	210	2	anatolii	anatolii	NOUN
eurjchem-2518	210	3	startsev	startsev	NOUN
eurjchem-2518	210	4	/	/	SYM
eurjchem-2518	210	5	european	european	ADJ
eurjchem-2518	210	6	journal	journal	PROPN
eurjchem-2518	210	7	of	of	ADP
eurjchem-2518	210	8	chemistry	chemistry	NOUN
eurjchem-2518	210	9	15	15	NUM
eurjchem-2518	210	10	(	(	PUNCT
eurjchem-2518	210	11	2	2	NUM
eurjchem-2518	210	12	)	)	PUNCT
eurjchem-2518	210	13	(	(	PUNCT
eurjchem-2518	210	14	2024	2024	NUM
eurjchem-2518	210	15	)	)	PUNCT
eurjchem-2518	210	16	186	186	NUM
eurjchem-2518	210	17	-	-	SYM
eurjchem-2518	210	18	193	193	NUM
eurjchem-2518	210	19	2024	2024	NUM
eurjchem-2518	210	20	–	–	PUNCT
eurjchem-2518	210	21	european	european	ADJ
eurjchem-2518	210	22	journal	journal	NOUN
eurjchem-2518	210	23	of	of	ADP
eurjchem-2518	210	24	chemistry	chemistry	NOUN
eurjchem-2518	210	25	–	–	PUNCT
eurjchem-2518	210	26	cc	cc	NOUN
eurjchem-2518	210	27	by	by	ADP
eurjchem-2518	210	28	nc	nc	PROPN
eurjchem-2518	210	29	–	–	PUNCT
eurjchem-2518	210	30	doi	doi	NOUN
eurjchem-2518	210	31	:	:	PUNCT
eurjchem-2518	210	32	10.5155	10.5155	NUM
eurjchem-2518	210	33	/	/	SYM
eurjchem-2518	210	34	eurjchem.15.2.186	eurjchem.15.2.186	VERB
eurjchem-2518	210	35	-	-	SYM
eurjchem-2518	210	36	193.2518	193.2518	NUM
eurjchem-2518	210	37	all	all	DET
eurjchem-2518	210	38	biological	biological	ADJ
eurjchem-2518	210	39	reactions	reaction	NOUN
eurjchem-2518	210	40	of	of	ADP
eurjchem-2518	210	41	nitrogen	nitrogen	NOUN
eurjchem-2518	210	42	fixation	fixation	NOUN
eurjchem-2518	210	43	are	be	AUX
eurjchem-2518	210	44	catalyzed	catalyze	VERB
eurjchem-2518	210	45	by	by	ADP
eurjchem-2518	210	46	enzymes	enzyme	NOUN
eurjchem-2518	210	47	called	call	VERB
eurjchem-2518	210	48	nitrogenases	nitrogenase	NOUN
eurjchem-2518	210	49	with	with	ADP
eurjchem-2518	210	50	fe	fe	NOUN
eurjchem-2518	210	51	as	as	ADP
eurjchem-2518	210	52	a	a	DET
eurjchem-2518	210	53	catalytic	catalytic	ADJ
eurjchem-2518	210	54	active	active	ADJ
eurjchem-2518	210	55	center	center	NOUN
eurjchem-2518	210	56	[	[	X
eurjchem-2518	210	57	42	42	NUM
eurjchem-2518	210	58	]	]	PUNCT
eurjchem-2518	210	59	,	,	PUNCT
eurjchem-2518	210	60	which	which	PRON
eurjchem-2518	210	61	convert	convert	VERB
eurjchem-2518	210	62	a	a	DET
eurjchem-2518	210	63	strong	strong	ADJ
eurjchem-2518	210	64	triple	triple	ADJ
eurjchem-2518	210	65	n	n	CCONJ
eurjchem-2518	210	66	–	–	PUNCT
eurjchem-2518	210	67	n	n	DET
eurjchem-2518	210	68	bond	bond	NOUN
eurjchem-2518	210	69	into	into	ADP
eurjchem-2518	210	70	ammonia	ammonia	NOUN
eurjchem-2518	210	71	nh3	nh3	NOUN
eurjchem-2518	210	72	under	under	ADP
eurjchem-2518	210	73	normal	normal	ADJ
eurjchem-2518	210	74	conditions	condition	NOUN
eurjchem-2518	210	75	.	.	PUNCT
eurjchem-2518	211	1	however	however	ADV
eurjchem-2518	211	2	,	,	PUNCT
eurjchem-2518	211	3	the	the	DET
eurjchem-2518	211	4	industrial	industrial	ADJ
eurjchem-2518	211	5	process	process	NOUN
eurjchem-2518	211	6	requires	require	VERB
eurjchem-2518	211	7	high	high	ADJ
eurjchem-2518	211	8	pressures	pressure	NOUN
eurjchem-2518	211	9	(	(	PUNCT
eurjchem-2518	211	10	around	around	ADV
eurjchem-2518	211	11	200	200	NUM
eurjchem-2518	211	12	atm	atm	NOUN
eurjchem-2518	211	13	)	)	PUNCT
eurjchem-2518	211	14	and	and	CCONJ
eurjchem-2518	211	15	high	high	ADJ
eurjchem-2518	211	16	temperatures	temperature	NOUN
eurjchem-2518	211	17	(	(	PUNCT
eurjchem-2518	211	18	at	at	ADP
eurjchem-2518	211	19	least	least	ADV
eurjchem-2518	211	20	400	400	NUM
eurjchem-2518	211	21	°	°	NOUN
eurjchem-2518	211	22	c	c	NOUN
eurjchem-2518	211	23	)	)	PUNCT
eurjchem-2518	211	24	.	.	PUNCT
eurjchem-2518	212	1	meanwhile	meanwhile	ADV
eurjchem-2518	212	2	,	,	PUNCT
eurjchem-2518	212	3	in	in	ADP
eurjchem-2518	212	4	our	our	PRON
eurjchem-2518	212	5	case	case	NOUN
eurjchem-2518	212	6	,	,	PUNCT
eurjchem-2518	212	7	this	this	DET
eurjchem-2518	212	8	reaction	reaction	NOUN
eurjchem-2518	212	9	occurs	occur	VERB
eurjchem-2518	212	10	at	at	ADP
eurjchem-2518	212	11	room	room	NOUN
eurjchem-2518	212	12	temperature	temperature	NOUN
eurjchem-2518	212	13	and	and	CCONJ
eurjchem-2518	212	14	pressure	pressure	NOUN
eurjchem-2518	212	15	if	if	SCONJ
eurjchem-2518	212	16	there	there	PRON
eurjchem-2518	212	17	is	be	VERB
eurjchem-2518	212	18	a	a	DET
eurjchem-2518	212	19	source	source	NOUN
eurjchem-2518	212	20	of	of	ADP
eurjchem-2518	212	21	active	active	ADJ
eurjchem-2518	212	22	hydrogen	hydrogen	NOUN
eurjchem-2518	212	23	produced	produce	VERB
eurjchem-2518	212	24	from	from	ADP
eurjchem-2518	212	25	h2s	h2s	NOUN
eurjchem-2518	212	26	on	on	ADP
eurjchem-2518	212	27	stainless	stainless	ADJ
eurjchem-2518	212	28	steel	steel	NOUN
eurjchem-2518	212	29	chips	chip	NOUN
eurjchem-2518	212	30	(	(	PUNCT
eurjchem-2518	212	31	7	7	X
eurjchem-2518	212	32	)	)	PUNCT
eurjchem-2518	213	1	[	[	X
eurjchem-2518	213	2	11	11	NUM
eurjchem-2518	213	3	]	]	PUNCT
eurjchem-2518	213	4	.	.	PUNCT
eurjchem-2518	214	1	finally	finally	ADV
eurjchem-2518	214	2	,	,	PUNCT
eurjchem-2518	214	3	an	an	DET
eurjchem-2518	214	4	absolutely	absolutely	ADV
eurjchem-2518	214	5	incredible	incredible	ADJ
eurjchem-2518	214	6	result	result	NOUN
eurjchem-2518	214	7	has	have	AUX
eurjchem-2518	214	8	been	be	AUX
eurjchem-2518	214	9	obtained	obtain	VERB
eurjchem-2518	214	10	when	when	SCONJ
eurjchem-2518	214	11	the	the	DET
eurjchem-2518	214	12	stream	stream	NOUN
eurjchem-2518	214	13	(	(	PUNCT
eurjchem-2518	214	14	ar	ar	NOUN
eurjchem-2518	214	15	+	+	NOUN
eurjchem-2518	214	16	h2s	h2s	NOUN
eurjchem-2518	214	17	)	)	PUNCT
eurjchem-2518	214	18	was	be	AUX
eurjchem-2518	214	19	passed	pass	VERB
eurjchem-2518	214	20	through	through	ADP
eurjchem-2518	214	21	a	a	DET
eurjchem-2518	214	22	platinum	platinum	NOUN
eurjchem-2518	214	23	catalyst	catalyst	NOUN
eurjchem-2518	214	24	or	or	CCONJ
eurjchem-2518	214	25	stainless	stainless	ADJ
eurjchem-2518	214	26	steel	steel	NOUN
eurjchem-2518	214	27	chips	chip	NOUN
eurjchem-2518	214	28	at	at	ADP
eurjchem-2518	214	29	room	room	NOUN
eurjchem-2518	214	30	temperature	temperature	NOUN
eurjchem-2518	214	31	.	.	PUNCT
eurjchem-2518	215	1	along	along	ADP
eurjchem-2518	215	2	with	with	ADP
eurjchem-2518	215	3	sulfur	sulfur	NOUN
eurjchem-2518	215	4	gas	gas	NOUN
eurjchem-2518	215	5	,	,	PUNCT
eurjchem-2518	215	6	a	a	DET
eurjchem-2518	215	7	new	new	ADJ
eurjchem-2518	215	8	substance	substance	NOUN
eurjchem-2518	215	9	was	be	AUX
eurjchem-2518	215	10	obtained	obtain	VERB
eurjchem-2518	215	11	at	at	ADP
eurjchem-2518	215	12	the	the	DET
eurjchem-2518	215	13	reactor	reactor	NOUN
eurjchem-2518	215	14	outlet	outlet	NOUN
eurjchem-2518	215	15	instead	instead	ADV
eurjchem-2518	215	16	of	of	ADP
eurjchem-2518	215	17	the	the	DET
eurjchem-2518	215	18	expected	expect	VERB
eurjchem-2518	215	19	hydrogen	hydrogen	NOUN
eurjchem-2518	215	20	,	,	PUNCT
eurjchem-2518	215	21	to	to	PART
eurjchem-2518	215	22	which	which	PRON
eurjchem-2518	215	23	the	the	DET
eurjchem-2518	215	24	formula	formula	NOUN
eurjchem-2518	215	25	was	be	AUX
eurjchem-2518	215	26	attributed	attribute	VERB
eurjchem-2518	215	27	hydrogen	hydrogen	NOUN
eurjchem-2518	215	28	argonide	argonide	NOUN
eurjchem-2518	215	29	h2ar	h2ar	PUNCT
eurjchem-2518	216	1	[	[	X
eurjchem-2518	216	2	11,12	11,12	NUM
eurjchem-2518	216	3	]	]	PUNCT
eurjchem-2518	216	4	.	.	PUNCT
eurjchem-2518	217	1	since	since	SCONJ
eurjchem-2518	217	2	the	the	DET
eurjchem-2518	217	3	heat	heat	NOUN
eurjchem-2518	217	4	of	of	ADP
eurjchem-2518	217	5	adsorption	adsorption	NOUN
eurjchem-2518	217	6	of	of	ADP
eurjchem-2518	217	7	argon	argon	NOUN
eurjchem-2518	217	8	on	on	ADP
eurjchem-2518	217	9	platinum	platinum	NOUN
eurjchem-2518	217	10	is	be	AUX
eurjchem-2518	217	11	only	only	ADV
eurjchem-2518	217	12	3	3	NUM
eurjchem-2518	217	13	kcal	kcal	NOUN
eurjchem-2518	217	14	/	/	SYM
eurjchem-2518	217	15	mol	mol	PROPN
eurjchem-2518	218	1	[	[	X
eurjchem-2518	218	2	43	43	NUM
eurjchem-2518	218	3	]	]	PUNCT
eurjchem-2518	218	4	,	,	PUNCT
eurjchem-2518	218	5	it	it	PRON
eurjchem-2518	218	6	can	can	AUX
eurjchem-2518	218	7	be	be	AUX
eurjchem-2518	218	8	assumed	assume	VERB
eurjchem-2518	218	9	that	that	SCONJ
eurjchem-2518	218	10	the	the	DET
eurjchem-2518	218	11	hydrogen	hydrogen	NOUN
eurjchem-2518	218	12	activated	activate	VERB
eurjchem-2518	218	13	in	in	ADP
eurjchem-2518	218	14	the	the	DET
eurjchem-2518	218	15	reaction	reaction	NOUN
eurjchem-2518	218	16	7	7	NUM
eurjchem-2518	218	17	,	,	PUNCT
eurjchem-2518	218	18	even	even	ADV
eurjchem-2518	218	19	in	in	ADP
eurjchem-2518	218	20	this	this	DET
eurjchem-2518	218	21	case	case	NOUN
eurjchem-2518	218	22	,	,	PUNCT
eurjchem-2518	218	23	effectively	effectively	ADV
eurjchem-2518	218	24	interacts	interact	VERB
eurjchem-2518	218	25	with	with	ADP
eurjchem-2518	218	26	the	the	DET
eurjchem-2518	218	27	adsorbed	adsorb	VERB
eurjchem-2518	218	28	argon	argon	NOUN
eurjchem-2518	218	29	atom	atom	NOUN
eurjchem-2518	218	30	.	.	PUNCT
eurjchem-2518	219	1	the	the	DET
eurjchem-2518	219	2	answer	answer	NOUN
eurjchem-2518	219	3	to	to	ADP
eurjchem-2518	219	4	this	this	DET
eurjchem-2518	219	5	question	question	NOUN
eurjchem-2518	219	6	can	can	AUX
eurjchem-2518	219	7	probably	probably	ADV
eurjchem-2518	219	8	be	be	AUX
eurjchem-2518	219	9	obtained	obtain	VERB
eurjchem-2518	219	10	from	from	ADP
eurjchem-2518	219	11	thermodynamic	thermodynamic	ADJ
eurjchem-2518	219	12	calculations	calculation	NOUN
eurjchem-2518	219	13	of	of	ADP
eurjchem-2518	219	14	the	the	DET
eurjchem-2518	219	15	entropy	entropy	NOUN
eurjchem-2518	219	16	of	of	ADP
eurjchem-2518	219	17	the	the	DET
eurjchem-2518	219	18	surface	surface	NOUN
eurjchem-2518	219	19	reaction	reaction	NOUN
eurjchem-2518	219	20	and	and	CCONJ
eurjchem-2518	219	21	,	,	PUNCT
eurjchem-2518	219	22	as	as	ADP
eurjchem-2518	219	23	a	a	DET
eurjchem-2518	219	24	result	result	NOUN
eurjchem-2518	219	25	,	,	PUNCT
eurjchem-2518	219	26	the	the	DET
eurjchem-2518	219	27	gibbs	gibbs	PROPN
eurjchem-2518	219	28	free	free	ADJ
eurjchem-2518	219	29	energy	energy	NOUN
eurjchem-2518	219	30	.	.	PUNCT
eurjchem-2518	220	1	if	if	SCONJ
eurjchem-2518	220	2	our	our	PRON
eurjchem-2518	220	3	experimental	experimental	ADJ
eurjchem-2518	220	4	observations	observation	NOUN
eurjchem-2518	220	5	are	be	AUX
eurjchem-2518	220	6	confirmed	confirm	VERB
eurjchem-2518	220	7	,	,	PUNCT
eurjchem-2518	220	8	it	it	PRON
eurjchem-2518	220	9	will	will	AUX
eurjchem-2518	220	10	mean	mean	VERB
eurjchem-2518	220	11	that	that	PRON
eurjchem-2518	220	12	stable	stable	ADJ
eurjchem-2518	220	13	under	under	ADP
eurjchem-2518	220	14	normal	normal	ADJ
eurjchem-2518	220	15	conditions	condition	NOUN
eurjchem-2518	220	16	,	,	PUNCT
eurjchem-2518	220	17	the	the	DET
eurjchem-2518	220	18	hydrogen	hydrogen	NOUN
eurjchem-2518	220	19	argonide	argonide	NOUN
eurjchem-2518	220	20	molecule	molecule	NOUN
eurjchem-2518	220	21	h2ar	h2ar	PUNCT
eurjchem-2518	220	22	can	can	AUX
eurjchem-2518	220	23	be	be	AUX
eurjchem-2518	220	24	used	use	VERB
eurjchem-2518	220	25	for	for	ADP
eurjchem-2518	220	26	the	the	DET
eurjchem-2518	220	27	accumulation	accumulation	NOUN
eurjchem-2518	220	28	,	,	PUNCT
eurjchem-2518	220	29	storage	storage	NOUN
eurjchem-2518	220	30	,	,	PUNCT
eurjchem-2518	220	31	and	and	CCONJ
eurjchem-2518	220	32	transportation	transportation	NOUN
eurjchem-2518	220	33	of	of	ADP
eurjchem-2518	220	34	hydrogen	hydrogen	NOUN
eurjchem-2518	220	35	.	.	PUNCT
eurjchem-2518	221	1	moreover	moreover	ADV
eurjchem-2518	221	2	,	,	PUNCT
eurjchem-2518	221	3	when	when	SCONJ
eurjchem-2518	221	4	hydrogen	hydrogen	NOUN
eurjchem-2518	221	5	argonide	argonide	NOUN
eurjchem-2518	221	6	is	be	AUX
eurjchem-2518	221	7	burned	burn	VERB
eurjchem-2518	221	8	in	in	ADP
eurjchem-2518	221	9	fuel	fuel	NOUN
eurjchem-2518	221	10	cells	cell	NOUN
eurjchem-2518	221	11	or	or	CCONJ
eurjchem-2518	221	12	in	in	ADP
eurjchem-2518	221	13	the	the	DET
eurjchem-2518	221	14	presence	presence	NOUN
eurjchem-2518	221	15	of	of	ADP
eurjchem-2518	221	16	oxygen	oxygen	NOUN
eurjchem-2518	221	17	,	,	PUNCT
eurjchem-2518	221	18	water	water	NOUN
eurjchem-2518	221	19	and	and	CCONJ
eurjchem-2518	221	20	argon	argon	NOUN
eurjchem-2518	221	21	are	be	AUX
eurjchem-2518	221	22	released	release	VERB
eurjchem-2518	221	23	,	,	PUNCT
eurjchem-2518	221	24	which	which	PRON
eurjchem-2518	221	25	returns	return	VERB
eurjchem-2518	221	26	to	to	ADP
eurjchem-2518	221	27	the	the	DET
eurjchem-2518	221	28	atmosphere	atmosphere	NOUN
eurjchem-2518	221	29	without	without	ADP
eurjchem-2518	221	30	damaging	damage	VERB
eurjchem-2518	221	31	the	the	DET
eurjchem-2518	221	32	environment	environment	NOUN
eurjchem-2518	221	33	.	.	PUNCT
eurjchem-2518	222	1	there	there	PRON
eurjchem-2518	222	2	is	be	VERB
eurjchem-2518	222	3	also	also	ADV
eurjchem-2518	222	4	a	a	DET
eurjchem-2518	222	5	reason	reason	NOUN
eurjchem-2518	222	6	to	to	PART
eurjchem-2518	222	7	assume	assume	VERB
eurjchem-2518	222	8	that	that	SCONJ
eurjchem-2518	222	9	the	the	DET
eurjchem-2518	222	10	chemical	chemical	NOUN
eurjchem-2518	222	11	analogues	analogue	NOUN
eurjchem-2518	222	12	h2ne	h2ne	ADV
eurjchem-2518	222	13	–	–	PUNCT
eurjchem-2518	222	14	hydrogen	hydrogen	NOUN
eurjchem-2518	222	15	neonide	neonide	NOUN
eurjchem-2518	222	16	and	and	CCONJ
eurjchem-2518	222	17	h2he	h2he	NOUN
eurjchem-2518	222	18	–	–	PUNCT
eurjchem-2518	222	19	hydrogen	hydrogen	NOUN
eurjchem-2518	222	20	helionide	helionide	ADV
eurjchem-2518	222	21	can	can	AUX
eurjchem-2518	222	22	be	be	AUX
eurjchem-2518	222	23	obtained	obtain	VERB
eurjchem-2518	222	24	in	in	ADP
eurjchem-2518	222	25	a	a	DET
eurjchem-2518	222	26	similar	similar	ADJ
eurjchem-2518	222	27	way	way	NOUN
eurjchem-2518	222	28	.	.	PUNCT
eurjchem-2518	223	1	to	to	PART
eurjchem-2518	223	2	verify	verify	VERB
eurjchem-2518	223	3	and	and	CCONJ
eurjchem-2518	223	4	substantiate	substantiate	VERB
eurjchem-2518	223	5	this	this	DET
eurjchem-2518	223	6	hypothesis	hypothesis	NOUN
eurjchem-2518	223	7	,	,	PUNCT
eurjchem-2518	223	8	targeted	target	VERB
eurjchem-2518	223	9	experimental	experimental	ADJ
eurjchem-2518	223	10	studies	study	NOUN
eurjchem-2518	223	11	using	use	VERB
eurjchem-2518	223	12	modern	modern	ADJ
eurjchem-2518	223	13	physicochemical	physicochemical	ADJ
eurjchem-2518	223	14	methods	method	NOUN
eurjchem-2518	223	15	involving	involve	VERB
eurjchem-2518	223	16	theoretical	theoretical	ADJ
eurjchem-2518	223	17	calculations	calculation	NOUN
eurjchem-2518	223	18	of	of	ADP
eurjchem-2518	223	19	the	the	DET
eurjchem-2518	223	20	non	non	ADJ
eurjchem-2518	223	21	-	-	ADJ
eurjchem-2518	223	22	equilibrium	equilibrium	ADJ
eurjchem-2518	223	23	thermodynamics	thermodynamic	NOUN
eurjchem-2518	223	24	of	of	ADP
eurjchem-2518	223	25	an	an	DET
eurjchem-2518	223	26	open	open	ADJ
eurjchem-2518	223	27	system	system	NOUN
eurjchem-2518	223	28	and	and	CCONJ
eurjchem-2518	223	29	the	the	DET
eurjchem-2518	223	30	mechanism	mechanism	NOUN
eurjchem-2518	223	31	of	of	ADP
eurjchem-2518	223	32	the	the	DET
eurjchem-2518	223	33	catalytic	catalytic	ADJ
eurjchem-2518	223	34	stages	stage	NOUN
eurjchem-2518	223	35	of	of	ADP
eurjchem-2518	223	36	the	the	DET
eurjchem-2518	223	37	interaction	interaction	NOUN
eurjchem-2518	223	38	of	of	ADP
eurjchem-2518	223	39	atomic	atomic	ADJ
eurjchem-2518	223	40	hydrogen	hydrogen	NOUN
eurjchem-2518	223	41	with	with	ADP
eurjchem-2518	223	42	adsorbed	adsorb	VERB
eurjchem-2518	223	43	argon	argon	NOUN
eurjchem-2518	223	44	and	and	CCONJ
eurjchem-2518	223	45	nitrogen	nitrogen	NOUN
eurjchem-2518	223	46	molecules	molecule	NOUN
eurjchem-2518	223	47	are	be	AUX
eurjchem-2518	223	48	necessary	necessary	ADJ
eurjchem-2518	223	49	.	.	PUNCT
eurjchem-2518	224	1	currently	currently	ADV
eurjchem-2518	224	2	,	,	PUNCT
eurjchem-2518	224	3	the	the	DET
eurjchem-2518	224	4	author	author	NOUN
eurjchem-2518	224	5	does	do	AUX
eurjchem-2518	224	6	not	not	PART
eurjchem-2518	224	7	have	have	VERB
eurjchem-2518	224	8	such	such	DET
eurjchem-2518	224	9	an	an	DET
eurjchem-2518	224	10	opportunity	opportunity	NOUN
eurjchem-2518	224	11	,	,	PUNCT
eurjchem-2518	224	12	so	so	ADV
eurjchem-2518	224	13	the	the	DET
eurjchem-2518	224	14	author	author	NOUN
eurjchem-2518	224	15	will	will	AUX
eurjchem-2518	224	16	be	be	AUX
eurjchem-2518	224	17	very	very	ADV
eurjchem-2518	224	18	grateful	grateful	ADJ
eurjchem-2518	224	19	for	for	ADP
eurjchem-2518	224	20	any	any	DET
eurjchem-2518	224	21	expression	expression	NOUN
eurjchem-2518	224	22	of	of	ADP
eurjchem-2518	224	23	interest	interest	NOUN
eurjchem-2518	224	24	from	from	ADP
eurjchem-2518	224	25	the	the	DET
eurjchem-2518	224	26	scientific	scientific	ADJ
eurjchem-2518	224	27	community	community	NOUN
eurjchem-2518	224	28	and	and	CCONJ
eurjchem-2518	224	29	is	be	AUX
eurjchem-2518	224	30	ready	ready	ADJ
eurjchem-2518	224	31	to	to	PART
eurjchem-2518	224	32	share	share	VERB
eurjchem-2518	224	33	all	all	DET
eurjchem-2518	224	34	available	available	ADJ
eurjchem-2518	224	35	information	information	NOUN
eurjchem-2518	224	36	to	to	PART
eurjchem-2518	224	37	achieve	achieve	VERB
eurjchem-2518	224	38	his	his	PRON
eurjchem-2518	224	39	goals	goal	NOUN
eurjchem-2518	224	40	.	.	PUNCT
eurjchem-2518	225	1	5	5	X
eurjchem-2518	225	2	.	.	X
eurjchem-2518	225	3	conclusion	conclusion	NOUN
eurjchem-2518	225	4	entropy	entropy	NOUN
eurjchem-2518	225	5	of	of	ADP
eurjchem-2518	225	6	the	the	DET
eurjchem-2518	225	7	surface	surface	NOUN
eurjchem-2518	225	8	catalytic	catalytic	ADJ
eurjchem-2518	225	9	reaction	reaction	NOUN
eurjchem-2518	225	10	:	:	PUNCT
eurjchem-2518	225	11	why	why	SCONJ
eurjchem-2518	225	12	is	be	AUX
eurjchem-2518	225	13	it	it	PRON
eurjchem-2518	225	14	important	important	ADJ
eurjchem-2518	225	15	and	and	CCONJ
eurjchem-2518	225	16	necessary	necessary	ADJ
eurjchem-2518	225	17	?	?	PUNCT
eurjchem-2518	226	1	based	base	VERB
eurjchem-2518	226	2	on	on	ADP
eurjchem-2518	226	3	the	the	DET
eurjchem-2518	226	4	concept	concept	NOUN
eurjchem-2518	226	5	of	of	ADP
eurjchem-2518	226	6	the	the	DET
eurjchem-2518	226	7	decisive	decisive	ADJ
eurjchem-2518	226	8	role	role	NOUN
eurjchem-2518	226	9	of	of	ADP
eurjchem-2518	226	10	solid	solid	ADJ
eurjchem-2518	226	11	catalysts	catalyst	NOUN
eurjchem-2518	226	12	in	in	ADP
eurjchem-2518	226	13	the	the	DET
eurjchem-2518	226	14	process	process	NOUN
eurjchem-2518	226	15	of	of	ADP
eurjchem-2518	226	16	low	low	ADJ
eurjchem-2518	226	17	-	-	PUNCT
eurjchem-2518	226	18	temperature	temperature	NOUN
eurjchem-2518	226	19	decomposition	decomposition	NOUN
eurjchem-2518	226	20	of	of	ADP
eurjchem-2518	226	21	h2s	h2s	NOUN
eurjchem-2518	226	22	,	,	PUNCT
eurjchem-2518	226	23	we	we	PRON
eurjchem-2518	226	24	conclude	conclude	VERB
eurjchem-2518	226	25	that	that	SCONJ
eurjchem-2518	226	26	under	under	ADP
eurjchem-2518	226	27	conditions	condition	NOUN
eurjchem-2518	226	28	of	of	ADP
eurjchem-2518	226	29	non	non	ADJ
eurjchem-2518	226	30	-	-	ADJ
eurjchem-2518	226	31	equilibrium	equilibrium	ADJ
eurjchem-2518	226	32	thermodynamics	thermodynamic	NOUN
eurjchem-2518	226	33	,	,	PUNCT
eurjchem-2518	226	34	reactions	reaction	NOUN
eurjchem-2518	226	35	prohibited	prohibit	VERB
eurjchem-2518	226	36	in	in	ADP
eurjchem-2518	226	37	the	the	DET
eurjchem-2518	226	38	gas	gas	NOUN
eurjchem-2518	226	39	phase	phase	NOUN
eurjchem-2518	226	40	are	be	AUX
eurjchem-2518	226	41	carried	carry	VERB
eurjchem-2518	226	42	out	out	ADP
eurjchem-2518	226	43	on	on	ADP
eurjchem-2518	226	44	the	the	DET
eurjchem-2518	226	45	catalyst	catalyst	NOUN
eurjchem-2518	226	46	surface	surface	NOUN
eurjchem-2518	226	47	.	.	PUNCT
eurjchem-2518	227	1	this	this	PRON
eurjchem-2518	227	2	was	be	AUX
eurjchem-2518	227	3	made	make	VERB
eurjchem-2518	227	4	possible	possible	ADJ
eurjchem-2518	227	5	by	by	ADP
eurjchem-2518	227	6	using	use	VERB
eurjchem-2518	227	7	the	the	DET
eurjchem-2518	227	8	internal	internal	ADJ
eurjchem-2518	227	9	energy	energy	NOUN
eurjchem-2518	227	10	of	of	ADP
eurjchem-2518	227	11	h2s	h2s	NOUN
eurjchem-2518	227	12	molecules	molecule	NOUN
eurjchem-2518	227	13	to	to	PART
eurjchem-2518	227	14	accumulate	accumulate	VERB
eurjchem-2518	227	15	the	the	DET
eurjchem-2518	227	16	free	free	ADJ
eurjchem-2518	227	17	energy	energy	NOUN
eurjchem-2518	227	18	obtained	obtain	VERB
eurjchem-2518	227	19	as	as	ADP
eurjchem-2518	227	20	a	a	DET
eurjchem-2518	227	21	result	result	NOUN
eurjchem-2518	227	22	of	of	ADP
eurjchem-2518	227	23	exothermic	exothermic	ADJ
eurjchem-2518	227	24	processes	process	NOUN
eurjchem-2518	227	25	of	of	ADP
eurjchem-2518	227	26	chemisorption	chemisorption	NOUN
eurjchem-2518	227	27	and	and	CCONJ
eurjchem-2518	227	28	dissociation	dissociation	NOUN
eurjchem-2518	227	29	of	of	ADP
eurjchem-2518	227	30	h2s	h2s	NOUN
eurjchem-2518	227	31	molecules	molecule	NOUN
eurjchem-2518	227	32	to	to	ADP
eurjchem-2518	227	33	an	an	DET
eurjchem-2518	227	34	atomically	atomically	ADV
eurjchem-2518	227	35	adsorbed	adsorb	VERB
eurjchem-2518	227	36	species	specie	NOUN
eurjchem-2518	227	37	and	and	CCONJ
eurjchem-2518	227	38	dissipation	dissipation	NOUN
eurjchem-2518	227	39	of	of	ADP
eurjchem-2518	227	40	entropy	entropy	NOUN
eurjchem-2518	227	41	in	in	ADP
eurjchem-2518	227	42	the	the	DET
eurjchem-2518	227	43	form	form	NOUN
eurjchem-2518	227	44	of	of	ADP
eurjchem-2518	227	45	bound	bind	VERB
eurjchem-2518	227	46	energy	energy	NOUN
eurjchem-2518	227	47	in	in	ADP
eurjchem-2518	227	48	the	the	DET
eurjchem-2518	227	49	environment	environment	NOUN
eurjchem-2518	227	50	.	.	PUNCT
eurjchem-2518	228	1	to	to	PART
eurjchem-2518	228	2	obtain	obtain	VERB
eurjchem-2518	228	3	data	datum	NOUN
eurjchem-2518	228	4	on	on	ADP
eurjchem-2518	228	5	the	the	DET
eurjchem-2518	228	6	gibbs	gibbs	PROPN
eurjchem-2518	228	7	free	free	ADJ
eurjchem-2518	228	8	energy	energy	NOUN
eurjchem-2518	228	9	,	,	PUNCT
eurjchem-2518	228	10	knowledge	knowledge	NOUN
eurjchem-2518	228	11	of	of	ADP
eurjchem-2518	228	12	the	the	DET
eurjchem-2518	228	13	entropy	entropy	NOUN
eurjchem-2518	228	14	of	of	ADP
eurjchem-2518	228	15	all	all	DET
eurjchem-2518	228	16	stages	stage	NOUN
eurjchem-2518	228	17	of	of	ADP
eurjchem-2518	228	18	the	the	DET
eurjchem-2518	228	19	surface	surface	NOUN
eurjchem-2518	228	20	catalytic	catalytic	ADJ
eurjchem-2518	228	21	reaction	reaction	NOUN
eurjchem-2518	228	22	is	be	AUX
eurjchem-2518	228	23	necessary	necessary	ADJ
eurjchem-2518	228	24	.	.	PUNCT
eurjchem-2518	229	1	the	the	DET
eurjchem-2518	229	2	generally	generally	ADV
eurjchem-2518	229	3	accepted	accept	VERB
eurjchem-2518	229	4	paradigm	paradigm	NOUN
eurjchem-2518	229	5	of	of	ADP
eurjchem-2518	229	6	h2s	h2s	NOUN
eurjchem-2518	229	7	decomposition	decomposition	NOUN
eurjchem-2518	229	8	into	into	ADP
eurjchem-2518	229	9	constituent	constituent	ADJ
eurjchem-2518	229	10	elements	element	NOUN
eurjchem-2518	229	11	using	use	VERB
eurjchem-2518	229	12	external	external	ADJ
eurjchem-2518	229	13	energy	energy	NOUN
eurjchem-2518	229	14	sources	source	NOUN
eurjchem-2518	229	15	has	have	AUX
eurjchem-2518	229	16	not	not	PART
eurjchem-2518	229	17	yet	yet	ADV
eurjchem-2518	229	18	allowed	allow	VERB
eurjchem-2518	229	19	to	to	PART
eurjchem-2518	229	20	create	create	VERB
eurjchem-2518	229	21	an	an	DET
eurjchem-2518	229	22	acceptable	acceptable	ADJ
eurjchem-2518	229	23	technology	technology	NOUN
eurjchem-2518	229	24	for	for	ADP
eurjchem-2518	229	25	producing	produce	VERB
eurjchem-2518	229	26	hydrogen	hydrogen	NOUN
eurjchem-2518	229	27	and	and	CCONJ
eurjchem-2518	229	28	sulfur	sulfur	NOUN
eurjchem-2518	229	29	from	from	ADP
eurjchem-2518	229	30	the	the	DET
eurjchem-2518	229	31	point	point	NOUN
eurjchem-2518	229	32	of	of	ADP
eurjchem-2518	229	33	view	view	NOUN
eurjchem-2518	229	34	of	of	ADP
eurjchem-2518	229	35	finding	find	VERB
eurjchem-2518	229	36	the	the	DET
eurjchem-2518	229	37	optimal	optimal	ADJ
eurjchem-2518	229	38	combination	combination	NOUN
eurjchem-2518	229	39	of	of	ADP
eurjchem-2518	229	40	the	the	DET
eurjchem-2518	229	41	four	four	NUM
eurjchem-2518	229	42	'	'	PUNCT
eurjchem-2518	229	43	e	e	NOUN
eurjchem-2518	229	44	'	'	NOUN
eurjchem-2518	229	45	:	:	PUNCT
eurjchem-2518	229	46	ecology	ecology	NOUN
eurjchem-2518	229	47	,	,	PUNCT
eurjchem-2518	229	48	economy	economy	NOUN
eurjchem-2518	229	49	,	,	PUNCT
eurjchem-2518	229	50	efficiency	efficiency	NOUN
eurjchem-2518	229	51	and	and	CCONJ
eurjchem-2518	229	52	energy	energy	NOUN
eurjchem-2518	229	53	.	.	PUNCT
eurjchem-2518	230	1	the	the	DET
eurjchem-2518	230	2	advanced	advanced	ADJ
eurjchem-2518	230	3	paradigm	paradigm	NOUN
eurjchem-2518	230	4	of	of	ADP
eurjchem-2518	230	5	lowtemperature	lowtemperature	NOUN
eurjchem-2518	230	6	catalytic	catalytic	ADJ
eurjchem-2518	230	7	decomposition	decomposition	NOUN
eurjchem-2518	230	8	of	of	ADP
eurjchem-2518	230	9	h2s	h2s	PROPN
eurjchem-2518	230	10	is	be	AUX
eurjchem-2518	230	11	apparently	apparently	ADV
eurjchem-2518	230	12	the	the	DET
eurjchem-2518	230	13	very	very	ADJ
eurjchem-2518	230	14	tool	tool	NOUN
eurjchem-2518	230	15	for	for	ADP
eurjchem-2518	230	16	solving	solve	VERB
eurjchem-2518	230	17	the	the	DET
eurjchem-2518	230	18	extremely	extremely	ADV
eurjchem-2518	230	19	urgent	urgent	ADJ
eurjchem-2518	230	20	problem	problem	NOUN
eurjchem-2518	230	21	of	of	ADP
eurjchem-2518	230	22	not	not	PART
eurjchem-2518	230	23	only	only	ADV
eurjchem-2518	230	24	the	the	DET
eurjchem-2518	230	25	disposal	disposal	NOUN
eurjchem-2518	230	26	of	of	ADP
eurjchem-2518	230	27	toxic	toxic	ADJ
eurjchem-2518	230	28	h2s	h2s	NOUN
eurjchem-2518	230	29	with	with	ADP
eurjchem-2518	230	30	the	the	DET
eurjchem-2518	230	31	production	production	NOUN
eurjchem-2518	230	32	of	of	ADP
eurjchem-2518	230	33	demanded	demand	VERB
eurjchem-2518	230	34	products	product	NOUN
eurjchem-2518	230	35	,	,	PUNCT
eurjchem-2518	230	36	but	but	CCONJ
eurjchem-2518	230	37	also	also	ADV
eurjchem-2518	230	38	opens	open	VERB
eurjchem-2518	230	39	up	up	ADP
eurjchem-2518	230	40	a	a	DET
eurjchem-2518	230	41	wide	wide	ADJ
eurjchem-2518	230	42	prospect	prospect	NOUN
eurjchem-2518	230	43	of	of	ADP
eurjchem-2518	230	44	using	use	VERB
eurjchem-2518	230	45	atomic	atomic	ADJ
eurjchem-2518	230	46	hydrogen	hydrogen	NOUN
eurjchem-2518	230	47	and	and	CCONJ
eurjchem-2518	230	48	sulfur	sulfur	NOUN
eurjchem-2518	230	49	for	for	ADP
eurjchem-2518	230	50	the	the	DET
eurjchem-2518	230	51	implementation	implementation	NOUN
eurjchem-2518	230	52	of	of	ADP
eurjchem-2518	230	53	unexpected	unexpected	ADJ
eurjchem-2518	230	54	chemical	chemical	NOUN
eurjchem-2518	230	55	reactions	reaction	NOUN
eurjchem-2518	230	56	and	and	CCONJ
eurjchem-2518	230	57	the	the	DET
eurjchem-2518	230	58	production	production	NOUN
eurjchem-2518	230	59	of	of	ADP
eurjchem-2518	230	60	new	new	ADJ
eurjchem-2518	230	61	,	,	PUNCT
eurjchem-2518	230	62	previously	previously	ADV
eurjchem-2518	230	63	unknown	unknown	ADJ
eurjchem-2518	230	64	chemicals	chemical	NOUN
eurjchem-2518	230	65	.	.	PUNCT
eurjchem-2518	231	1	the	the	DET
eurjchem-2518	231	2	development	development	NOUN
eurjchem-2518	231	3	potential	potential	NOUN
eurjchem-2518	231	4	of	of	ADP
eurjchem-2518	231	5	the	the	DET
eurjchem-2518	231	6	paradigm	paradigm	NOUN
eurjchem-2518	231	7	is	be	AUX
eurjchem-2518	231	8	limited	limit	VERB
eurjchem-2518	231	9	by	by	ADP
eurjchem-2518	231	10	the	the	DET
eurjchem-2518	231	11	volume	volume	NOUN
eurjchem-2518	231	12	of	of	ADP
eurjchem-2518	231	13	processed	process	VERB
eurjchem-2518	231	14	h2s	h2s	NOUN
eurjchem-2518	231	15	,	,	PUNCT
eurjchem-2518	231	16	which	which	PRON
eurjchem-2518	231	17	,	,	PUNCT
eurjchem-2518	231	18	in	in	ADP
eurjchem-2518	231	19	turn	turn	NOUN
eurjchem-2518	231	20	,	,	PUNCT
eurjchem-2518	231	21	is	be	AUX
eurjchem-2518	231	22	limited	limit	VERB
eurjchem-2518	231	23	by	by	ADP
eurjchem-2518	231	24	the	the	DET
eurjchem-2518	231	25	amount	amount	NOUN
eurjchem-2518	231	26	of	of	ADP
eurjchem-2518	231	27	sulfur	sulfur	NOUN
eurjchem-2518	231	28	consumed	consume	VERB
eurjchem-2518	231	29	.	.	PUNCT
eurjchem-2518	232	1	the	the	DET
eurjchem-2518	232	2	situation	situation	NOUN
eurjchem-2518	232	3	may	may	AUX
eurjchem-2518	232	4	change	change	VERB
eurjchem-2518	232	5	if	if	SCONJ
eurjchem-2518	232	6	new	new	ADJ
eurjchem-2518	232	7	unexpected	unexpected	ADJ
eurjchem-2518	232	8	solutions	solution	NOUN
eurjchem-2518	232	9	are	be	AUX
eurjchem-2518	232	10	found	find	VERB
eurjchem-2518	232	11	for	for	ADP
eurjchem-2518	232	12	the	the	DET
eurjchem-2518	232	13	use	use	NOUN
eurjchem-2518	232	14	of	of	ADP
eurjchem-2518	232	15	triplet	triplet	NOUN
eurjchem-2518	232	16	sulfur	sulfur	NOUN
eurjchem-2518	232	17	as	as	ADP
eurjchem-2518	232	18	a	a	DET
eurjchem-2518	232	19	reagent	reagent	NOUN
eurjchem-2518	232	20	for	for	ADP
eurjchem-2518	232	21	the	the	DET
eurjchem-2518	232	22	synthesis	synthesis	NOUN
eurjchem-2518	232	23	of	of	ADP
eurjchem-2518	232	24	new	new	ADJ
eurjchem-2518	232	25	substances	substance	NOUN
eurjchem-2518	232	26	and	and	CCONJ
eurjchem-2518	232	27	materials	material	NOUN
eurjchem-2518	232	28	in	in	ADP
eurjchem-2518	232	29	chemistry	chemistry	NOUN
eurjchem-2518	232	30	,	,	PUNCT
eurjchem-2518	232	31	industry	industry	NOUN
eurjchem-2518	232	32	,	,	PUNCT
eurjchem-2518	232	33	mechanical	mechanical	ADJ
eurjchem-2518	232	34	engineering	engineering	NOUN
eurjchem-2518	232	35	,	,	PUNCT
eurjchem-2518	232	36	medicine	medicine	NOUN
eurjchem-2518	232	37	,	,	PUNCT
eurjchem-2518	232	38	pharmacology	pharmacology	NOUN
eurjchem-2518	232	39	,	,	PUNCT
eurjchem-2518	232	40	etc	etc	X
eurjchem-2518	232	41	.	.	X
eurjchem-2518	232	42	toxic	toxic	ADJ
eurjchem-2518	232	43	and	and	CCONJ
eurjchem-2518	232	44	"	"	PUNCT
eurjchem-2518	232	45	useless	useless	ADJ
eurjchem-2518	232	46	"	"	PUNCT
eurjchem-2518	232	47	h2s	h2	NOUN
eurjchem-2518	232	48	,	,	PUNCT
eurjchem-2518	232	49	which	which	PRON
eurjchem-2518	232	50	has	have	AUX
eurjchem-2518	232	51	not	not	PART
eurjchem-2518	232	52	found	find	VERB
eurjchem-2518	232	53	practical	practical	ADJ
eurjchem-2518	232	54	application	application	NOUN
eurjchem-2518	232	55	in	in	ADP
eurjchem-2518	232	56	human	human	ADJ
eurjchem-2518	232	57	life	life	NOUN
eurjchem-2518	232	58	,	,	PUNCT
eurjchem-2518	232	59	turned	turn	VERB
eurjchem-2518	232	60	out	out	ADP
eurjchem-2518	232	61	to	to	PART
eurjchem-2518	232	62	be	be	AUX
eurjchem-2518	232	63	the	the	DET
eurjchem-2518	232	64	very	very	ADJ
eurjchem-2518	232	65	substance	substance	NOUN
eurjchem-2518	232	66	that	that	PRON
eurjchem-2518	232	67	underlies	underlie	VERB
eurjchem-2518	232	68	the	the	DET
eurjchem-2518	232	69	process	process	NOUN
eurjchem-2518	232	70	of	of	ADP
eurjchem-2518	232	71	chemosynthesis	chemosynthesis	NOUN
eurjchem-2518	232	72	of	of	ADP
eurjchem-2518	232	73	organic	organic	ADJ
eurjchem-2518	232	74	matter	matter	NOUN
eurjchem-2518	232	75	from	from	ADP
eurjchem-2518	232	76	co2	co2	NOUN
eurjchem-2518	232	77	created	create	VERB
eurjchem-2518	232	78	by	by	ADP
eurjchem-2518	232	79	nature	nature	NOUN
eurjchem-2518	232	80	,	,	PUNCT
eurjchem-2518	232	81	which	which	PRON
eurjchem-2518	232	82	laid	lay	VERB
eurjchem-2518	232	83	the	the	DET
eurjchem-2518	232	84	foundation	foundation	NOUN
eurjchem-2518	232	85	for	for	ADP
eurjchem-2518	232	86	biological	biological	ADJ
eurjchem-2518	232	87	life	life	NOUN
eurjchem-2518	232	88	on	on	ADP
eurjchem-2518	232	89	earth	earth	NOUN
eurjchem-2518	232	90	.	.	PUNCT
eurjchem-2518	233	1	unlike	unlike	ADP
eurjchem-2518	233	2	its	its	PRON
eurjchem-2518	233	3	chemical	chemical	NOUN
eurjchem-2518	233	4	counterpart	counterpart	NOUN
eurjchem-2518	233	5	,	,	PUNCT
eurjchem-2518	233	6	water	water	NOUN
eurjchem-2518	233	7	,	,	PUNCT
eurjchem-2518	233	8	which	which	PRON
eurjchem-2518	233	9	is	be	AUX
eurjchem-2518	233	10	the	the	DET
eurjchem-2518	233	11	primary	primary	ADJ
eurjchem-2518	233	12	basis	basis	NOUN
eurjchem-2518	233	13	of	of	ADP
eurjchem-2518	233	14	the	the	DET
eurjchem-2518	233	15	existence	existence	NOUN
eurjchem-2518	233	16	of	of	ADP
eurjchem-2518	233	17	all	all	DET
eurjchem-2518	233	18	biological	biological	ADJ
eurjchem-2518	233	19	organisms	organism	NOUN
eurjchem-2518	233	20	,	,	PUNCT
eurjchem-2518	233	21	h2s	h2s	PROPN
eurjchem-2518	233	22	is	be	AUX
eurjchem-2518	233	23	a	a	DET
eurjchem-2518	233	24	supplier	supplier	NOUN
eurjchem-2518	233	25	of	of	ADP
eurjchem-2518	233	26	hydrogen	hydrogen	NOUN
eurjchem-2518	233	27	and	and	CCONJ
eurjchem-2518	233	28	energy	energy	NOUN
eurjchem-2518	233	29	for	for	ADP
eurjchem-2518	233	30	the	the	DET
eurjchem-2518	233	31	lifesupport	lifesupport	PROPN
eurjchem-2518	233	32	processes	process	NOUN
eurjchem-2518	233	33	of	of	ADP
eurjchem-2518	233	34	these	these	DET
eurjchem-2518	233	35	organisms	organism	NOUN
eurjchem-2518	233	36	.	.	PUNCT
eurjchem-2518	234	1	this	this	DET
eurjchem-2518	234	2	extremely	extremely	ADV
eurjchem-2518	234	3	important	important	ADJ
eurjchem-2518	234	4	role	role	NOUN
eurjchem-2518	234	5	of	of	ADP
eurjchem-2518	234	6	h2s	h2s	PROPN
eurjchem-2518	234	7	is	be	AUX
eurjchem-2518	234	8	apparently	apparently	ADV
eurjchem-2518	234	9	due	due	ADJ
eurjchem-2518	234	10	to	to	ADP
eurjchem-2518	234	11	the	the	DET
eurjchem-2518	234	12	unique	unique	ADJ
eurjchem-2518	234	13	property	property	NOUN
eurjchem-2518	234	14	of	of	ADP
eurjchem-2518	234	15	this	this	DET
eurjchem-2518	234	16	molecule	molecule	NOUN
eurjchem-2518	234	17	the	the	DET
eurjchem-2518	234	18	standard	standard	ADJ
eurjchem-2518	234	19	enthalpy	enthalpy	NOUN
eurjchem-2518	234	20	of	of	ADP
eurjchem-2518	234	21	formation	formation	NOUN
eurjchem-2518	234	22	(	(	PUNCT
eurjchem-2518	234	23	∆fho298	∆fho298	SYM
eurjchem-2518	234	24	=	=	SYM
eurjchem-2518	234	25	−4.82	−4.82	NUM
eurjchem-2518	234	26	kcal	kcal	PROPN
eurjchem-2518	234	27	/	/	SYM
eurjchem-2518	234	28	mol	mol	NOUN
eurjchem-2518	234	29	)	)	PUNCT
eurjchem-2518	234	30	is	be	AUX
eurjchem-2518	234	31	the	the	DET
eurjchem-2518	234	32	smallest	small	ADJ
eurjchem-2518	234	33	among	among	ADP
eurjchem-2518	234	34	all	all	DET
eurjchem-2518	234	35	known	know	VERB
eurjchem-2518	234	36	potential	potential	ADJ
eurjchem-2518	234	37	sources	source	NOUN
eurjchem-2518	234	38	of	of	ADP
eurjchem-2518	234	39	hydrogen	hydrogen	NOUN
eurjchem-2518	234	40	,	,	PUNCT
eurjchem-2518	234	41	which	which	PRON
eurjchem-2518	234	42	means	mean	VERB
eurjchem-2518	234	43	minimal	minimal	ADJ
eurjchem-2518	234	44	energy	energy	NOUN
eurjchem-2518	234	45	consumption	consumption	NOUN
eurjchem-2518	234	46	during	during	ADP
eurjchem-2518	234	47	splitting	splitting	NOUN
eurjchem-2518	234	48	of	of	ADP
eurjchem-2518	234	49	the	the	DET
eurjchem-2518	234	50	molecule	molecule	NOUN
eurjchem-2518	234	51	.	.	PUNCT
eurjchem-2518	235	1	the	the	DET
eurjchem-2518	235	2	driving	drive	VERB
eurjchem-2518	235	3	force	force	NOUN
eurjchem-2518	235	4	behind	behind	ADP
eurjchem-2518	235	5	the	the	DET
eurjchem-2518	235	6	decomposition	decomposition	NOUN
eurjchem-2518	235	7	of	of	ADP
eurjchem-2518	235	8	h2s	h2s	PROPN
eurjchem-2518	235	9	is	be	AUX
eurjchem-2518	235	10	the	the	DET
eurjchem-2518	235	11	formation	formation	NOUN
eurjchem-2518	235	12	of	of	ADP
eurjchem-2518	235	13	final	final	ADJ
eurjchem-2518	235	14	products	product	NOUN
eurjchem-2518	235	15	in	in	ADP
eurjchem-2518	235	16	the	the	DET
eurjchem-2518	235	17	ground	ground	NOUN
eurjchem-2518	235	18	electronic	electronic	ADJ
eurjchem-2518	235	19	state	state	NOUN
eurjchem-2518	235	20	(	(	PUNCT
eurjchem-2518	235	21	i.e.	i.e.	X
eurjchem-2518	235	22	having	have	VERB
eurjchem-2518	235	23	minimal	minimal	ADJ
eurjchem-2518	235	24	free	free	ADJ
eurjchem-2518	235	25	energy	energy	NOUN
eurjchem-2518	235	26	)	)	PUNCT
eurjchem-2518	235	27	–	–	PUNCT
eurjchem-2518	235	28	singlet	singlet	ADJ
eurjchem-2518	235	29	hydrogen	hydrogen	NOUN
eurjchem-2518	235	30	,	,	PUNCT
eurjchem-2518	235	31	solid	solid	ADJ
eurjchem-2518	235	32	sulfur	sulfur	NOUN
eurjchem-2518	235	33	and	and	CCONJ
eurjchem-2518	235	34	a	a	DET
eurjchem-2518	235	35	diatomic	diatomic	ADJ
eurjchem-2518	235	36	sulfur	sulfur	NOUN
eurjchem-2518	235	37	molecule	molecule	NOUN
eurjchem-2518	235	38	in	in	ADP
eurjchem-2518	235	39	the	the	DET
eurjchem-2518	235	40	ground	ground	NOUN
eurjchem-2518	235	41	triplet	triplet	NOUN
eurjchem-2518	235	42	state	state	NOUN
eurjchem-2518	235	43	.	.	PUNCT
eurjchem-2518	236	1	at	at	ADP
eurjchem-2518	236	2	the	the	DET
eurjchem-2518	236	3	same	same	ADJ
eurjchem-2518	236	4	time	time	NOUN
eurjchem-2518	236	5	,	,	PUNCT
eurjchem-2518	236	6	the	the	DET
eurjchem-2518	236	7	annual	annual	ADJ
eurjchem-2518	236	8	increase	increase	NOUN
eurjchem-2518	236	9	in	in	ADP
eurjchem-2518	236	10	h2s	h2s	NOUN
eurjchem-2518	236	11	is	be	AUX
eurjchem-2518	236	12	hundreds	hundred	NOUN
eurjchem-2518	236	13	of	of	ADP
eurjchem-2518	236	14	millions	million	NOUN
eurjchem-2518	236	15	of	of	ADP
eurjchem-2518	236	16	tons	ton	NOUN
eurjchem-2518	236	17	due	due	ADP
eurjchem-2518	236	18	to	to	ADP
eurjchem-2518	236	19	the	the	DET
eurjchem-2518	236	20	activity	activity	NOUN
eurjchem-2518	236	21	of	of	ADP
eurjchem-2518	236	22	anaerobic	anaerobic	ADJ
eurjchem-2518	236	23	sulfate	sulfate	NOUN
eurjchem-2518	236	24	-	-	PUNCT
eurjchem-2518	236	25	reducing	reduce	VERB
eurjchem-2518	236	26	bacteria	bacteria	NOUN
eurjchem-2518	236	27	,	,	PUNCT
eurjchem-2518	236	28	which	which	PRON
eurjchem-2518	236	29	ensures	ensure	VERB
eurjchem-2518	236	30	a	a	DET
eurjchem-2518	236	31	continuous	continuous	ADJ
eurjchem-2518	236	32	cycle	cycle	NOUN
eurjchem-2518	236	33	of	of	ADP
eurjchem-2518	236	34	h2s	h2s	NOUN
eurjchem-2518	236	35	in	in	ADP
eurjchem-2518	236	36	nature	nature	NOUN
eurjchem-2518	236	37	.	.	PUNCT
eurjchem-2518	237	1	at	at	ADP
eurjchem-2518	237	2	the	the	DET
eurjchem-2518	237	3	moment	moment	NOUN
eurjchem-2518	237	4	,	,	PUNCT
eurjchem-2518	237	5	apparently	apparently	ADV
eurjchem-2518	237	6	,	,	PUNCT
eurjchem-2518	237	7	all	all	DET
eurjchem-2518	237	8	prerequisites	prerequisite	NOUN
eurjchem-2518	237	9	have	have	AUX
eurjchem-2518	237	10	been	be	AUX
eurjchem-2518	237	11	created	create	VERB
eurjchem-2518	237	12	for	for	ADP
eurjchem-2518	237	13	initiating	initiate	VERB
eurjchem-2518	237	14	full	full	ADJ
eurjchem-2518	237	15	-	-	PUNCT
eurjchem-2518	237	16	scale	scale	NOUN
eurjchem-2518	237	17	scientific	scientific	ADJ
eurjchem-2518	237	18	,	,	PUNCT
eurjchem-2518	237	19	technological	technological	ADJ
eurjchem-2518	237	20	,	,	PUNCT
eurjchem-2518	237	21	and	and	CCONJ
eurjchem-2518	237	22	commercial	commercial	ADJ
eurjchem-2518	237	23	projects	project	NOUN
eurjchem-2518	237	24	to	to	PART
eurjchem-2518	237	25	implement	implement	VERB
eurjchem-2518	237	26	the	the	DET
eurjchem-2518	237	27	innovative	innovative	ADJ
eurjchem-2518	237	28	idea	idea	NOUN
eurjchem-2518	237	29	of	of	ADP
eurjchem-2518	237	30	using	use	VERB
eurjchem-2518	237	31	the	the	DET
eurjchem-2518	237	32	toxic	toxic	ADJ
eurjchem-2518	237	33	substance	substance	NOUN
eurjchem-2518	237	34	h2s	h2s	NOUN
eurjchem-2518	237	35	created	create	VERB
eurjchem-2518	237	36	by	by	ADP
eurjchem-2518	237	37	nature	nature	NOUN
eurjchem-2518	237	38	to	to	PART
eurjchem-2518	237	39	serve	serve	VERB
eurjchem-2518	237	40	humanity	humanity	NOUN
eurjchem-2518	237	41	.	.	PUNCT
eurjchem-2518	238	1	today	today	NOUN
eurjchem-2518	238	2	we	we	PRON
eurjchem-2518	238	3	have	have	VERB
eurjchem-2518	238	4	a	a	DET
eurjchem-2518	238	5	unique	unique	ADJ
eurjchem-2518	238	6	opportunity	opportunity	NOUN
eurjchem-2518	238	7	to	to	PART
eurjchem-2518	238	8	use	use	VERB
eurjchem-2518	238	9	this	this	DET
eurjchem-2518	238	10	"	"	PUNCT
eurjchem-2518	238	11	gift	gift	NOUN
eurjchem-2518	238	12	"	"	PUNCT
eurjchem-2518	238	13	of	of	ADP
eurjchem-2518	238	14	nature	nature	NOUN
eurjchem-2518	238	15	to	to	PART
eurjchem-2518	238	16	solve	solve	VERB
eurjchem-2518	238	17	scientific	scientific	ADJ
eurjchem-2518	238	18	and	and	CCONJ
eurjchem-2518	238	19	technological	technological	ADJ
eurjchem-2518	238	20	problems	problem	NOUN
eurjchem-2518	238	21	that	that	PRON
eurjchem-2518	238	22	can	can	AUX
eurjchem-2518	238	23	not	not	PART
eurjchem-2518	238	24	be	be	AUX
eurjchem-2518	238	25	implemented	implement	VERB
eurjchem-2518	238	26	within	within	ADP
eurjchem-2518	238	27	the	the	DET
eurjchem-2518	238	28	existing	exist	VERB
eurjchem-2518	238	29	paradigm	paradigm	NOUN
eurjchem-2518	238	30	of	of	ADP
eurjchem-2518	238	31	h2s	h2s	NOUN
eurjchem-2518	238	32	processing	processing	NOUN
eurjchem-2518	238	33	.	.	PUNCT
eurjchem-2518	239	1	for	for	ADP
eurjchem-2518	239	2	this	this	DET
eurjchem-2518	239	3	purpose	purpose	NOUN
eurjchem-2518	239	4	,	,	PUNCT
eurjchem-2518	239	5	we	we	PRON
eurjchem-2518	239	6	have	have	AUX
eurjchem-2518	239	7	actually	actually	ADV
eurjchem-2518	239	8	reproduced	reproduce	VERB
eurjchem-2518	239	9	biological	biological	ADJ
eurjchem-2518	239	10	processes	process	NOUN
eurjchem-2518	239	11	carried	carry	VERB
eurjchem-2518	239	12	out	out	ADP
eurjchem-2518	239	13	in	in	ADP
eurjchem-2518	239	14	nature	nature	NOUN
eurjchem-2518	239	15	by	by	ADP
eurjchem-2518	239	16	biocatalysts	biocatalyst	NOUN
eurjchem-2518	239	17	–	–	PUNCT
eurjchem-2518	239	18	enzymes	enzyme	NOUN
eurjchem-2518	239	19	,	,	PUNCT
eurjchem-2518	239	20	using	use	VERB
eurjchem-2518	239	21	heterogeneous	heterogeneous	ADJ
eurjchem-2518	239	22	catalytic	catalytic	ADJ
eurjchem-2518	239	23	systems	system	NOUN
eurjchem-2518	239	24	.	.	PUNCT
eurjchem-2518	240	1	in	in	ADP
eurjchem-2518	240	2	turn	turn	NOUN
eurjchem-2518	240	3	,	,	PUNCT
eurjchem-2518	240	4	we	we	PRON
eurjchem-2518	240	5	have	have	AUX
eurjchem-2518	240	6	discovered	discover	VERB
eurjchem-2518	240	7	a	a	DET
eurjchem-2518	240	8	new	new	ADJ
eurjchem-2518	240	9	phenomenon	phenomenon	NOUN
eurjchem-2518	240	10	in	in	ADP
eurjchem-2518	240	11	heterogeneous	heterogeneous	ADJ
eurjchem-2518	240	12	catalysis	catalysis	NOUN
eurjchem-2518	240	13	,	,	PUNCT
eurjchem-2518	240	14	the	the	DET
eurjchem-2518	240	15	use	use	NOUN
eurjchem-2518	240	16	of	of	ADP
eurjchem-2518	240	17	the	the	DET
eurjchem-2518	240	18	internal	internal	ADJ
eurjchem-2518	240	19	energy	energy	NOUN
eurjchem-2518	240	20	of	of	ADP
eurjchem-2518	240	21	the	the	DET
eurjchem-2518	240	22	chemical	chemical	ADJ
eurjchem-2518	240	23	bonds	bond	NOUN
eurjchem-2518	240	24	of	of	ADP
eurjchem-2518	240	25	the	the	DET
eurjchem-2518	240	26	h2s	h2s	NOUN
eurjchem-2518	240	27	molecule	molecule	NOUN
eurjchem-2518	240	28	to	to	PART
eurjchem-2518	240	29	carry	carry	VERB
eurjchem-2518	240	30	out	out	ADP
eurjchem-2518	240	31	chemical	chemical	NOUN
eurjchem-2518	240	32	reactions	reaction	NOUN
eurjchem-2518	240	33	that	that	PRON
eurjchem-2518	240	34	can	can	AUX
eurjchem-2518	240	35	not	not	PART
eurjchem-2518	240	36	be	be	AUX
eurjchem-2518	240	37	carried	carry	VERB
eurjchem-2518	240	38	out	out	ADP
eurjchem-2518	240	39	in	in	ADP
eurjchem-2518	240	40	the	the	DET
eurjchem-2518	240	41	gas	gas	NOUN
eurjchem-2518	240	42	phase	phase	NOUN
eurjchem-2518	240	43	in	in	ADP
eurjchem-2518	240	44	the	the	DET
eurjchem-2518	240	45	absence	absence	NOUN
eurjchem-2518	240	46	of	of	ADP
eurjchem-2518	240	47	solid	solid	ADJ
eurjchem-2518	240	48	catalysts	catalyst	NOUN
eurjchem-2518	240	49	,	,	PUNCT
eurjchem-2518	240	50	which	which	PRON
eurjchem-2518	240	51	undoubtedly	undoubtedly	ADV
eurjchem-2518	240	52	models	model	VERB
eurjchem-2518	240	53	biological	biological	ADJ
eurjchem-2518	240	54	processes	process	NOUN
eurjchem-2518	240	55	.	.	PUNCT
eurjchem-2518	241	1	it	it	PRON
eurjchem-2518	241	2	should	should	AUX
eurjchem-2518	241	3	be	be	AUX
eurjchem-2518	241	4	emphasized	emphasize	VERB
eurjchem-2518	241	5	the	the	DET
eurjchem-2518	241	6	special	special	ADJ
eurjchem-2518	241	7	role	role	NOUN
eurjchem-2518	241	8	of	of	ADP
eurjchem-2518	241	9	catalysis	catalysis	NOUN
eurjchem-2518	241	10	for	for	ADP
eurjchem-2518	241	11	chemistry	chemistry	NOUN
eurjchem-2518	241	12	as	as	ADP
eurjchem-2518	241	13	a	a	DET
eurjchem-2518	241	14	science	science	NOUN
eurjchem-2518	241	15	in	in	ADP
eurjchem-2518	241	16	general	general	ADJ
eurjchem-2518	241	17	,	,	PUNCT
eurjchem-2518	241	18	and	and	CCONJ
eurjchem-2518	241	19	for	for	ADP
eurjchem-2518	241	20	many	many	ADJ
eurjchem-2518	241	21	biological	biological	ADJ
eurjchem-2518	241	22	processes	process	NOUN
eurjchem-2518	241	23	occurring	occur	VERB
eurjchem-2518	241	24	under	under	ADP
eurjchem-2518	241	25	the	the	DET
eurjchem-2518	241	26	action	action	NOUN
eurjchem-2518	241	27	of	of	ADP
eurjchem-2518	241	28	biocatalysts	biocatalyst	NOUN
eurjchem-2518	241	29	,	,	PUNCT
eurjchem-2518	241	30	enzymes	enzyme	NOUN
eurjchem-2518	241	31	.	.	PUNCT
eurjchem-2518	242	1	currently	currently	ADV
eurjchem-2518	242	2	,	,	PUNCT
eurjchem-2518	242	3	the	the	DET
eurjchem-2518	242	4	role	role	NOUN
eurjchem-2518	242	5	of	of	ADP
eurjchem-2518	242	6	catalysis	catalysis	NOUN
eurjchem-2518	242	7	in	in	ADP
eurjchem-2518	242	8	human	human	ADJ
eurjchem-2518	242	9	activity	activity	NOUN
eurjchem-2518	242	10	is	be	AUX
eurjchem-2518	242	11	significantly	significantly	ADV
eurjchem-2518	242	12	increasing	increase	VERB
eurjchem-2518	242	13	due	due	ADP
eurjchem-2518	242	14	to	to	ADP
eurjchem-2518	242	15	the	the	DET
eurjchem-2518	242	16	purposeful	purposeful	ADJ
eurjchem-2518	242	17	search	search	NOUN
eurjchem-2518	242	18	for	for	ADP
eurjchem-2518	242	19	and	and	CCONJ
eurjchem-2518	242	20	creation	creation	NOUN
eurjchem-2518	242	21	of	of	ADP
eurjchem-2518	242	22	highly	highly	ADV
eurjchem-2518	242	23	active	active	ADJ
eurjchem-2518	242	24	and	and	CCONJ
eurjchem-2518	242	25	selective	selective	ADJ
eurjchem-2518	242	26	catalysts	catalyst	NOUN
eurjchem-2518	242	27	capable	capable	ADJ
eurjchem-2518	242	28	of	of	ADP
eurjchem-2518	242	29	effectively	effectively	ADV
eurjchem-2518	242	30	solving	solve	VERB
eurjchem-2518	242	31	the	the	DET
eurjchem-2518	242	32	economic	economic	ADJ
eurjchem-2518	242	33	and	and	CCONJ
eurjchem-2518	242	34	environmental	environmental	ADJ
eurjchem-2518	242	35	problems	problem	NOUN
eurjchem-2518	242	36	of	of	ADP
eurjchem-2518	242	37	chemical	chemical	NOUN
eurjchem-2518	242	38	processes	process	NOUN
eurjchem-2518	242	39	.	.	PUNCT
eurjchem-2518	243	1	however	however	ADV
eurjchem-2518	243	2	,	,	PUNCT
eurjchem-2518	243	3	the	the	DET
eurjchem-2518	243	4	possibilities	possibility	NOUN
eurjchem-2518	243	5	of	of	ADP
eurjchem-2518	243	6	catalysis	catalysis	NOUN
eurjchem-2518	243	7	are	be	AUX
eurjchem-2518	243	8	far	far	ADV
eurjchem-2518	243	9	from	from	ADP
eurjchem-2518	243	10	being	be	AUX
eurjchem-2518	243	11	exhausted	exhaust	VERB
eurjchem-2518	243	12	,	,	PUNCT
eurjchem-2518	243	13	since	since	SCONJ
eurjchem-2518	243	14	nature	nature	NOUN
eurjchem-2518	243	15	has	have	AUX
eurjchem-2518	243	16	created	create	VERB
eurjchem-2518	243	17	unique	unique	ADJ
eurjchem-2518	243	18	biocatalysts	biocatalyst	NOUN
eurjchem-2518	243	19	that	that	PRON
eurjchem-2518	243	20	,	,	PUNCT
eurjchem-2518	243	21	under	under	ADP
eurjchem-2518	243	22	environmental	environmental	ADJ
eurjchem-2518	243	23	conditions	condition	NOUN
eurjchem-2518	243	24	,	,	PUNCT
eurjchem-2518	243	25	are	be	AUX
eurjchem-2518	243	26	capable	capable	ADJ
eurjchem-2518	243	27	of	of	ADP
eurjchem-2518	243	28	performing	perform	VERB
eurjchem-2518	243	29	processes	process	NOUN
eurjchem-2518	243	30	that	that	PRON
eurjchem-2518	243	31	can	can	AUX
eurjchem-2518	243	32	not	not	PART
eurjchem-2518	243	33	yet	yet	ADV
eurjchem-2518	243	34	be	be	AUX
eurjchem-2518	243	35	implemented	implement	VERB
eurjchem-2518	243	36	on	on	ADP
eurjchem-2518	243	37	an	an	DET
eurjchem-2518	243	38	industrial	industrial	ADJ
eurjchem-2518	243	39	scale	scale	NOUN
eurjchem-2518	243	40	.	.	PUNCT
eurjchem-2518	244	1	in	in	ADP
eurjchem-2518	244	2	our	our	PRON
eurjchem-2518	244	3	opinion	opinion	NOUN
eurjchem-2518	244	4	,	,	PUNCT
eurjchem-2518	244	5	a	a	DET
eurjchem-2518	244	6	qualitative	qualitative	ADJ
eurjchem-2518	244	7	shift	shift	NOUN
eurjchem-2518	244	8	to	to	ADP
eurjchem-2518	244	9	a	a	DET
eurjchem-2518	244	10	new	new	ADJ
eurjchem-2518	244	11	paradigm	paradigm	NOUN
eurjchem-2518	244	12	of	of	ADP
eurjchem-2518	244	13	the	the	DET
eurjchem-2518	244	14	science	science	NOUN
eurjchem-2518	244	15	of	of	ADP
eurjchem-2518	244	16	catalysis	catalysis	NOUN
eurjchem-2518	244	17	can	can	AUX
eurjchem-2518	244	18	be	be	AUX
eurjchem-2518	244	19	achieved	achieve	VERB
eurjchem-2518	244	20	if	if	SCONJ
eurjchem-2518	244	21	we	we	PRON
eurjchem-2518	244	22	direct	direct	VERB
eurjchem-2518	244	23	our	our	PRON
eurjchem-2518	244	24	efforts	effort	NOUN
eurjchem-2518	244	25	to	to	PART
eurjchem-2518	244	26	create	create	VERB
eurjchem-2518	244	27	"	"	PUNCT
eurjchem-2518	244	28	man	man	NOUN
eurjchem-2518	244	29	-	-	PUNCT
eurjchem-2518	244	30	made	make	VERB
eurjchem-2518	244	31	"	"	PUNCT
eurjchem-2518	244	32	irreversible	irreversible	ADJ
eurjchem-2518	244	33	catalytic	catalytic	ADJ
eurjchem-2518	244	34	processes	process	NOUN
eurjchem-2518	244	35	operating	operate	VERB
eurjchem-2518	244	36	in	in	ADP
eurjchem-2518	244	37	thermodynamically	thermodynamically	ADV
eurjchem-2518	244	38	non	non	ADJ
eurjchem-2518	244	39	-	-	ADJ
eurjchem-2518	244	40	equilibrium	equilibrium	ADJ
eurjchem-2518	244	41	conditions	condition	NOUN
eurjchem-2518	244	42	characteristic	characteristic	ADJ
eurjchem-2518	244	43	of	of	ADP
eurjchem-2518	244	44	all	all	DET
eurjchem-2518	244	45	biological	biological	ADJ
eurjchem-2518	244	46	processes	process	NOUN
eurjchem-2518	244	47	.	.	PUNCT
eurjchem-2518	245	1	the	the	DET
eurjchem-2518	245	2	author	author	NOUN
eurjchem-2518	245	3	really	really	ADV
eurjchem-2518	245	4	hopes	hope	VERB
eurjchem-2518	245	5	that	that	SCONJ
eurjchem-2518	245	6	the	the	DET
eurjchem-2518	245	7	relevance	relevance	NOUN
eurjchem-2518	245	8	of	of	ADP
eurjchem-2518	245	9	the	the	DET
eurjchem-2518	245	10	raised	raise	VERB
eurjchem-2518	245	11	scientific	scientific	ADJ
eurjchem-2518	245	12	problem	problem	NOUN
eurjchem-2518	245	13	and	and	CCONJ
eurjchem-2518	245	14	the	the	DET
eurjchem-2518	245	15	prospect	prospect	NOUN
eurjchem-2518	245	16	of	of	ADP
eurjchem-2518	245	17	obtaining	obtain	VERB
eurjchem-2518	245	18	new	new	ADJ
eurjchem-2518	245	19	knowledge	knowledge	NOUN
eurjchem-2518	245	20	in	in	ADP
eurjchem-2518	245	21	previously	previously	ADV
eurjchem-2518	245	22	unknown	unknown	ADJ
eurjchem-2518	245	23	fields	field	NOUN
eurjchem-2518	245	24	of	of	ADP
eurjchem-2518	245	25	science	science	NOUN
eurjchem-2518	245	26	will	will	AUX
eurjchem-2518	245	27	allow	allow	VERB
eurjchem-2518	245	28	us	we	PRON
eurjchem-2518	245	29	to	to	PART
eurjchem-2518	245	30	overcome	overcome	VERB
eurjchem-2518	245	31	all	all	DET
eurjchem-2518	245	32	obstacles	obstacle	NOUN
eurjchem-2518	245	33	in	in	ADP
eurjchem-2518	245	34	our	our	PRON
eurjchem-2518	245	35	very	very	ADV
eurjchem-2518	245	36	difficult	difficult	ADJ
eurjchem-2518	245	37	time	time	NOUN
eurjchem-2518	245	38	to	to	PART
eurjchem-2518	245	39	solve	solve	VERB
eurjchem-2518	245	40	the	the	DET
eurjchem-2518	245	41	problem	problem	NOUN
eurjchem-2518	245	42	of	of	ADP
eurjchem-2518	245	43	sustainable	sustainable	ADJ
eurjchem-2518	245	44	human	human	ADJ
eurjchem-2518	245	45	development	development	NOUN
eurjchem-2518	245	46	.	.	PUNCT
eurjchem-2518	246	1	disclosure	disclosure	NOUN
eurjchem-2518	246	2	statement	statement	NOUN
eurjchem-2518	246	3	conflict	conflict	NOUN
eurjchem-2518	246	4	of	of	ADP
eurjchem-2518	246	5	interest	interest	NOUN
eurjchem-2518	246	6	:	:	PUNCT
eurjchem-2518	246	7	the	the	DET
eurjchem-2518	246	8	author	author	NOUN
eurjchem-2518	246	9	declares	declare	VERB
eurjchem-2518	246	10	that	that	SCONJ
eurjchem-2518	246	11	i	i	PRON
eurjchem-2518	246	12	have	have	VERB
eurjchem-2518	246	13	no	no	DET
eurjchem-2518	246	14	conflict	conflict	NOUN
eurjchem-2518	246	15	of	of	ADP
eurjchem-2518	246	16	interest	interest	NOUN
eurjchem-2518	246	17	.	.	PUNCT
eurjchem-2518	247	1	ethical	ethical	ADJ
eurjchem-2518	247	2	approval	approval	NOUN
eurjchem-2518	247	3	:	:	PUNCT
eurjchem-2518	248	1	all	all	DET
eurjchem-2518	248	2	ethical	ethical	ADJ
eurjchem-2518	248	3	guidelines	guideline	NOUN
eurjchem-2518	248	4	have	have	AUX
eurjchem-2518	248	5	been	be	AUX
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eurjchem-2518	249	9	(	(	PUNCT
eurjchem-2518	249	10	2	2	NUM
eurjchem-2518	249	11	)	)	PUNCT
eurjchem-2518	249	12	(	(	PUNCT
eurjchem-2518	249	13	2024	2024	NUM
eurjchem-2518	249	14	)	)	PUNCT
eurjchem-2518	249	15	186	186	NUM
eurjchem-2518	249	16	-	-	SYM
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eurjchem-2518	249	18	193	193	NUM
eurjchem-2518	249	19	2024	2024	NUM
eurjchem-2518	249	20	–	–	PUNCT
eurjchem-2518	249	21	european	european	ADJ
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eurjchem-2518	249	25	–	–	PUNCT
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eurjchem-2518	249	28	nc	nc	PROPN
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eurjchem-2518	249	46	[	[	X
eurjchem-2518	249	47	1	1	NUM
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eurjchem-2518	250	8	;	;	PUNCT
eurjchem-2518	250	9	cambridge	cambridge	PROPN
eurjchem-2518	250	10	university	university	PROPN
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eurjchem-2518	250	12	,	,	PUNCT
eurjchem-2518	250	13	2008	2008	NUM
eurjchem-2518	250	14	.	.	PUNCT
eurjchem-2518	251	1	[	[	X
eurjchem-2518	251	2	2	2	NUM
eurjchem-2518	251	3	]	]	PUNCT
eurjchem-2518	251	4	.	.	PUNCT
eurjchem-2518	252	1	schlegel	schlegel	PROPN
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eurjchem-2518	252	11	;	;	PUNCT
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eurjchem-2518	253	1	[	[	X
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eurjchem-2518	253	3	]	]	PUNCT
eurjchem-2518	253	4	.	.	PUNCT
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eurjchem-2518	254	16	.	.	PUNCT
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eurjchem-2518	255	3	.	.	PUNCT
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eurjchem-2518	256	2	.	.	PROPN
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eurjchem-2518	256	8	.	.	PUNCT
eurjchem-2518	257	1	[	[	X
eurjchem-2518	257	2	4	4	NUM
eurjchem-2518	257	3	]	]	PUNCT
eurjchem-2518	257	4	.	.	PUNCT
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eurjchem-2518	258	2	,	,	PUNCT
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eurjchem-2518	258	8	:	:	PUNCT
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eurjchem-2518	258	15	:	:	PUNCT
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eurjchem-2518	259	1	[	[	X
eurjchem-2518	259	2	5	5	NUM
eurjchem-2518	259	3	]	]	PUNCT
eurjchem-2518	259	4	.	.	PUNCT
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eurjchem-2518	260	5	;	;	PUNCT
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eurjchem-2518	261	2	,	,	PUNCT
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eurjchem-2518	261	5	;	;	PUNCT
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eurjchem-2518	263	1	j.	j.	PROPN
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eurjchem-2518	265	2	,	,	PUNCT
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eurjchem-2518	265	4	,	,	PUNCT
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eurjchem-2518	265	6	.	.	PUNCT
eurjchem-2518	266	1	[	[	X
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eurjchem-2518	266	4	.	.	PUNCT
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eurjchem-2518	267	13	.	.	PUNCT
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eurjchem-2518	270	6	.	.	PUNCT
eurjchem-2518	271	1	[	[	X
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eurjchem-2518	271	3	]	]	PUNCT
eurjchem-2518	271	4	.	.	PUNCT
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eurjchem-2518	272	10	;	;	PUNCT
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eurjchem-2518	272	13	y.	y.	PROPN
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eurjchem-2518	274	9	.	.	PUNCT
eurjchem-2518	275	1	[	[	X
eurjchem-2518	275	2	8	8	NUM
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eurjchem-2518	275	4	.	.	PUNCT
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eurjchem-2518	276	14	k.	k.	PROPN
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eurjchem-2518	276	16	;	;	PUNCT
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eurjchem-2518	276	44	,	,	PUNCT
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eurjchem-2518	276	47	;	;	PUNCT
eurjchem-2518	276	48	yiin	yiin	PROPN
eurjchem-2518	276	49	,	,	PUNCT
eurjchem-2518	276	50	c.	c.	PROPN
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eurjchem-2518	276	52	;	;	PUNCT
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eurjchem-2518	276	76	(	(	PUNCT
eurjchem-2518	276	77	h2	h2	NOUN
eurjchem-2518	276	78	)	)	PUNCT
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eurjchem-2518	276	84	:	:	PUNCT
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eurjchem-2518	276	90	.	.	PUNCT
eurjchem-2518	277	1	chem	chem	PROPN
eurjchem-2518	277	2	.	.	PUNCT
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eurjchem-2518	278	2	.	.	PUNCT
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eurjchem-2518	278	5	,	,	PUNCT
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eurjchem-2518	278	7	,	,	PUNCT
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eurjchem-2518	279	1	[	[	X
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eurjchem-2518	279	4	.	.	PUNCT
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eurjchem-2518	280	3	h.	h.	PROPN
eurjchem-2518	280	4	;	;	PUNCT
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eurjchem-2518	280	6	,	,	PUNCT
eurjchem-2518	280	7	z.	z.	PROPN
eurjchem-2518	280	8	;	;	PUNCT
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eurjchem-2518	280	23	.	.	PUNCT
eurjchem-2518	281	1	j.	j.	PROPN
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eurjchem-2518	281	3	.	.	PUNCT
eurjchem-2518	282	1	chem	chem	PROPN
eurjchem-2518	282	2	.	.	PUNCT
eurjchem-2518	283	1	c	c	PROPN
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eurjchem-2518	283	3	.	.	PUNCT
eurjchem-2518	284	1	interfaces	interface	NOUN
eurjchem-2518	284	2	2023	2023	NUM
eurjchem-2518	284	3	,	,	PUNCT
eurjchem-2518	284	4	127	127	NUM
eurjchem-2518	284	5	,	,	PUNCT
eurjchem-2518	284	6	9022–9029	9022–9029	NUM
eurjchem-2518	284	7	.	.	PUNCT
eurjchem-2518	285	1	[	[	X
eurjchem-2518	285	2	10	10	NUM
eurjchem-2518	285	3	]	]	PUNCT
eurjchem-2518	285	4	.	.	PUNCT
eurjchem-2518	286	1	startsev	startsev	PROPN
eurjchem-2518	286	2	,	,	PUNCT
eurjchem-2518	286	3	a.	a.	NOUN
eurjchem-2518	286	4	n.	n.	NOUN
eurjchem-2518	286	5	the	the	DET
eurjchem-2518	286	6	crucial	crucial	ADJ
eurjchem-2518	286	7	role	role	NOUN
eurjchem-2518	286	8	of	of	ADP
eurjchem-2518	286	9	catalysts	catalyst	NOUN
eurjchem-2518	286	10	in	in	ADP
eurjchem-2518	286	11	the	the	DET
eurjchem-2518	286	12	reaction	reaction	NOUN
eurjchem-2518	286	13	of	of	ADP
eurjchem-2518	286	14	low	low	ADJ
eurjchem-2518	286	15	temperature	temperature	NOUN
eurjchem-2518	286	16	decomposition	decomposition	NOUN
eurjchem-2518	286	17	of	of	ADP
eurjchem-2518	286	18	hydrogen	hydrogen	NOUN
eurjchem-2518	286	19	sulfide	sulfide	NOUN
eurjchem-2518	286	20	:	:	PUNCT
eurjchem-2518	286	21	non	non	ADJ
eurjchem-2518	286	22	-	-	ADJ
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eurjchem-2518	286	25	of	of	ADP
eurjchem-2518	286	26	the	the	DET
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eurjchem-2518	286	28	process	process	NOUN
eurjchem-2518	286	29	in	in	ADP
eurjchem-2518	286	30	an	an	DET
eurjchem-2518	286	31	open	open	ADJ
eurjchem-2518	286	32	system	system	NOUN
eurjchem-2518	286	33	.	.	PUNCT
eurjchem-2518	287	1	mol	mol	PROPN
eurjchem-2518	287	2	.	.	PUNCT
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eurjchem-2518	287	4	.	.	PUNCT
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eurjchem-2518	288	2	,	,	PUNCT
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eurjchem-2518	288	4	,	,	PUNCT
eurjchem-2518	288	5	111240	111240	NUM
eurjchem-2518	288	6	.	.	PUNCT
eurjchem-2518	289	1	[	[	X
eurjchem-2518	289	2	11	11	NUM
eurjchem-2518	289	3	]	]	PUNCT
eurjchem-2518	289	4	.	.	PUNCT
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eurjchem-2518	290	2	,	,	PUNCT
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eurjchem-2518	290	4	n.	n.	PROPN
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eurjchem-2518	290	9	paradigm	paradigm	NOUN
eurjchem-2518	290	10	.	.	PUNCT
eurjchem-2518	291	1	j.	j.	PROPN
eurjchem-2518	291	2	sulphur	sulphur	PROPN
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eurjchem-2518	291	4	.	.	PUNCT
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eurjchem-2518	292	2	,	,	PUNCT
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eurjchem-2518	292	4	,	,	PUNCT
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eurjchem-2518	292	6	.	.	PUNCT
eurjchem-2518	293	1	[	[	X
eurjchem-2518	293	2	12	12	NUM
eurjchem-2518	293	3	]	]	PUNCT
eurjchem-2518	293	4	.	.	PUNCT
eurjchem-2518	293	5	startsev	startsev	PROPN
eurjchem-2518	293	6	,	,	PUNCT
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eurjchem-2518	293	8	n.	n.	PROPN
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eurjchem-2518	293	13	of	of	ADP
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eurjchem-2518	293	15	sulfide	sulfide	NOUN
eurjchem-2518	293	16	into	into	ADP
eurjchem-2518	293	17	hydrogen	hydrogen	NOUN
eurjchem-2518	293	18	.	.	PUNCT
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eurjchem-2518	294	2	(	(	PUNCT
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eurjchem-2518	294	6	,	,	PUNCT
eurjchem-2518	294	7	2024	2024	NUM
eurjchem-2518	294	8	)	)	PUNCT
eurjchem-2518	294	9	.	.	PUNCT
eurjchem-2518	295	1	[	[	X
eurjchem-2518	295	2	13	13	NUM
eurjchem-2518	295	3	]	]	PUNCT
eurjchem-2518	295	4	.	.	PUNCT
eurjchem-2518	296	1	startsev	startsev	PROPN
eurjchem-2518	296	2	,	,	PUNCT
eurjchem-2518	296	3	a.	a.	NOUN
eurjchem-2518	296	4	n.	n.	NOUN
eurjchem-2518	296	5	concept	concept	NOUN
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eurjchem-2518	296	7	acid	acid	ADJ
eurjchem-2518	296	8	–	–	PUNCT
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eurjchem-2518	296	11	by	by	ADP
eurjchem-2518	296	12	metal	metal	NOUN
eurjchem-2518	296	13	sulfides	sulfide	NOUN
eurjchem-2518	296	14	.	.	PUNCT
eurjchem-2518	297	1	catal	catal	NOUN
eurjchem-2518	297	2	.	.	PUNCT
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eurjchem-2518	298	3	,	,	PUNCT
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eurjchem-2518	298	5	,	,	PUNCT
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eurjchem-2518	298	7	.	.	PUNCT
eurjchem-2518	299	1	[	[	X
eurjchem-2518	299	2	14	14	NUM
eurjchem-2518	299	3	]	]	PUNCT
eurjchem-2518	299	4	.	.	PUNCT
eurjchem-2518	300	1	zakharov	zakharov	PROPN
eurjchem-2518	300	2	,	,	PUNCT
eurjchem-2518	300	3	i.	i.	PROPN
eurjchem-2518	300	4	i.	i.	PROPN
eurjchem-2518	300	5	;	;	PUNCT
eurjchem-2518	300	6	startsev	startsev	PROPN
eurjchem-2518	300	7	,	,	PUNCT
eurjchem-2518	300	8	a.	a.	NOUN
eurjchem-2518	300	9	n.	n.	NOUN
eurjchem-2518	300	10	;	;	PUNCT
eurjchem-2518	300	11	zhidomirov	zhidomirov	NOUN
eurjchem-2518	300	12	,	,	PUNCT
eurjchem-2518	300	13	g.	g.	PROPN
eurjchem-2518	300	14	m.	m.	PROPN
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eurjchem-2518	300	16	parmon	parmon	PROPN
eurjchem-2518	300	17	,	,	PUNCT
eurjchem-2518	300	18	v.	v.	ADP
eurjchem-2518	300	19	n.	n.	PROPN
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eurjchem-2518	300	21	addition	addition	NOUN
eurjchem-2518	300	22	of	of	ADP
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eurjchem-2518	300	24	as	as	ADP
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eurjchem-2518	300	26	key	key	ADJ
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eurjchem-2518	300	30	active	active	ADJ
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eurjchem-2518	300	33	in	in	ADP
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eurjchem-2518	300	35	hds	hds	PROPN
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eurjchem-2518	300	37	bimetallic	bimetallic	NOUN
eurjchem-2518	300	38	catalysts	catalyst	NOUN
eurjchem-2518	300	39	:	:	PUNCT
eurjchem-2518	300	40	ab	ab	PROPN
eurjchem-2518	300	41	initio	initio	PROPN
eurjchem-2518	300	42	mo	mo	PROPN
eurjchem-2518	300	43	/	/	SYM
eurjchem-2518	300	44	mp2	mp2	PROPN
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eurjchem-2518	300	46	.	.	PUNCT
eurjchem-2518	301	1	j.	j.	PROPN
eurjchem-2518	301	2	mol	mol	PROPN
eurjchem-2518	301	3	.	.	PROPN
eurjchem-2518	301	4	catal	catal	PROPN
eurjchem-2518	301	5	.	.	PUNCT
eurjchem-2518	302	1	a	a	DET
eurjchem-2518	302	2	chem	chem	NOUN
eurjchem-2518	302	3	.	.	PUNCT
eurjchem-2518	303	1	1999	1999	NUM
eurjchem-2518	303	2	,	,	PUNCT
eurjchem-2518	303	3	137	137	NUM
eurjchem-2518	303	4	,	,	PUNCT
eurjchem-2518	303	5	101–111	101–111	NUM
eurjchem-2518	303	6	.	.	PUNCT
eurjchem-2518	304	1	[	[	X
eurjchem-2518	304	2	15	15	NUM
eurjchem-2518	304	3	]	]	PUNCT
eurjchem-2518	304	4	.	.	PUNCT
eurjchem-2518	304	5	prigogine	prigogine	NOUN
eurjchem-2518	304	6	,	,	PUNCT
eurjchem-2518	304	7	i.	i.	NOUN
eurjchem-2518	304	8	introduction	introduction	NOUN
eurjchem-2518	304	9	to	to	ADP
eurjchem-2518	304	10	thermodynamics	thermodynamic	NOUN
eurjchem-2518	304	11	of	of	ADP
eurjchem-2518	304	12	irreversible	irreversible	ADJ
eurjchem-2518	304	13	processes	process	NOUN
eurjchem-2518	304	14	;	;	PUNCT
eurjchem-2518	304	15	3rd	3rd	ADJ
eurjchem-2518	304	16	ed	ed	NOUN
eurjchem-2518	304	17	.	.	PUNCT
eurjchem-2518	304	18	;	;	PUNCT
eurjchem-2518	304	19	john	john	PROPN
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eurjchem-2518	304	21	&	&	CCONJ
eurjchem-2518	304	22	sons	sons	PROPN
eurjchem-2518	304	23	:	:	PUNCT
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eurjchem-2518	304	25	,	,	PUNCT
eurjchem-2518	304	26	tn	tn	PROPN
eurjchem-2518	304	27	,	,	PUNCT
eurjchem-2518	304	28	1968	1968	NUM
eurjchem-2518	304	29	.	.	PUNCT
eurjchem-2518	305	1	[	[	X
eurjchem-2518	305	2	16	16	NUM
eurjchem-2518	305	3	]	]	PUNCT
eurjchem-2518	305	4	.	.	PUNCT
eurjchem-2518	306	1	startsev	startsev	PROPN
eurjchem-2518	306	2	,	,	PUNCT
eurjchem-2518	306	3	a.	a.	NOUN
eurjchem-2518	306	4	n.	n.	NOUN
eurjchem-2518	306	5	;	;	PUNCT
eurjchem-2518	306	6	zakharov	zakharov	PROPN
eurjchem-2518	306	7	,	,	PUNCT
eurjchem-2518	306	8	i.	i.	PROPN
eurjchem-2518	306	9	i.	i.	PROPN
eurjchem-2518	306	10	;	;	PUNCT
eurjchem-2518	306	11	voroshina	voroshina	NOUN
eurjchem-2518	306	12	,	,	PUNCT
eurjchem-2518	306	13	o.	o.	PROPN
eurjchem-2518	306	14	v.	v.	PROPN
eurjchem-2518	306	15	;	;	PUNCT
eurjchem-2518	306	16	pashigreva	pashigreva	PROPN
eurjchem-2518	306	17	,	,	PUNCT
eurjchem-2518	306	18	a.	a.	NOUN
eurjchem-2518	306	19	v.	v.	PROPN
eurjchem-2518	306	20	;	;	PUNCT
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eurjchem-2518	306	22	,	,	PUNCT
eurjchem-2518	306	23	v.	v.	ADP
eurjchem-2518	306	24	n.	n.	ADJ
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eurjchem-2518	306	26	-	-	PUNCT
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eurjchem-2518	306	28	decomposition	decomposition	NOUN
eurjchem-2518	306	29	of	of	ADP
eurjchem-2518	306	30	hydrogen	hydrogen	NOUN
eurjchem-2518	306	31	sulfide	sulfide	NOUN
eurjchem-2518	306	32	under	under	ADP
eurjchem-2518	306	33	the	the	DET
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eurjchem-2518	306	35	of	of	ADP
eurjchem-2518	306	36	conjugate	conjugate	ADJ
eurjchem-2518	306	37	chemisorption	chemisorption	NOUN
eurjchem-2518	306	38	and	and	CCONJ
eurjchem-2518	306	39	catalysis	catalysis	NOUN
eurjchem-2518	306	40	.	.	PUNCT
eurjchem-2518	307	1	dokl	dokl	NOUN
eurjchem-2518	307	2	.	.	PUNCT
eurjchem-2518	308	1	phys	phy	NOUN
eurjchem-2518	308	2	.	.	PUNCT
eurjchem-2518	309	1	chem	chem	PROPN
eurjchem-2518	309	2	.	.	PUNCT
eurjchem-2518	310	1	2004	2004	NUM
eurjchem-2518	310	2	,	,	PUNCT
eurjchem-2518	310	3	399	399	NUM
eurjchem-2518	310	4	,	,	PUNCT
eurjchem-2518	310	5	283–286	283–286	NUM
eurjchem-2518	310	6	.	.	PUNCT
eurjchem-2518	311	1	[	[	X
eurjchem-2518	311	2	17	17	NUM
eurjchem-2518	311	3	]	]	PUNCT
eurjchem-2518	311	4	.	.	PUNCT
eurjchem-2518	312	1	zakharov	zakharov	PROPN
eurjchem-2518	312	2	,	,	PUNCT
eurjchem-2518	312	3	i.	i.	PROPN
eurjchem-2518	312	4	i.	i.	PROPN
eurjchem-2518	312	5	;	;	PUNCT
eurjchem-2518	312	6	startsev	startsev	PROPN
eurjchem-2518	312	7	,	,	PUNCT
eurjchem-2518	312	8	a.	a.	NOUN
eurjchem-2518	312	9	n.	n.	NOUN
eurjchem-2518	312	10	;	;	PUNCT
eurjchem-2518	312	11	voroshina	voroshina	NOUN
eurjchem-2518	312	12	,	,	PUNCT
eurjchem-2518	313	1	o.	o.	PROPN
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eurjchem-2518	313	3	;	;	PUNCT
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eurjchem-2518	313	5	,	,	PUNCT
eurjchem-2518	313	6	a.	a.	NOUN
eurjchem-2518	313	7	v.	v.	PROPN
eurjchem-2518	313	8	;	;	PUNCT
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eurjchem-2518	313	10	,	,	PUNCT
eurjchem-2518	313	11	n.	n.	PROPN
eurjchem-2518	313	12	a.	a.	PROPN
eurjchem-2518	313	13	;	;	PUNCT
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eurjchem-2518	313	15	,	,	PUNCT
eurjchem-2518	313	16	v.	v.	ADP
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eurjchem-2518	313	18	the	the	DET
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eurjchem-2518	313	20	mechanism	mechanism	NOUN
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eurjchem-2518	313	24	of	of	ADP
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eurjchem-2518	313	26	sulfide	sulfide	NOUN
eurjchem-2518	313	27	under	under	ADP
eurjchem-2518	313	28	conjugated	conjugated	ADJ
eurjchem-2518	313	29	chemisorption	chemisorption	NOUN
eurjchem-2518	313	30	-	-	PUNCT
eurjchem-2518	313	31	catalysis	catalysis	NOUN
eurjchem-2518	313	32	conditions	condition	NOUN
eurjchem-2518	313	33	.	.	PUNCT
eurjchem-2518	314	1	russ	russ	PROPN
eurjchem-2518	314	2	.	.	PUNCT
eurjchem-2518	315	1	j.	j.	PROPN
eurjchem-2518	315	2	phys	phys	PROPN
eurjchem-2518	315	3	.	.	PUNCT
eurjchem-2518	316	1	chem	chem	PROPN
eurjchem-2518	316	2	.	.	PUNCT
eurjchem-2518	317	1	2006	2006	NUM
eurjchem-2518	317	2	,	,	PUNCT
eurjchem-2518	317	3	80	80	NUM
eurjchem-2518	317	4	,	,	PUNCT
eurjchem-2518	317	5	1403–1410	1403–1410	NUM
eurjchem-2518	317	6	.	.	PUNCT
eurjchem-2518	318	1	[	[	X
eurjchem-2518	318	2	18	18	NUM
eurjchem-2518	318	3	]	]	PUNCT
eurjchem-2518	318	4	.	.	PUNCT
eurjchem-2518	318	5	startsev	startsev	PROPN
eurjchem-2518	318	6	,	,	PUNCT
eurjchem-2518	318	7	a.	a.	NOUN
eurjchem-2518	318	8	n.	n.	NOUN
eurjchem-2518	318	9	;	;	PUNCT
eurjchem-2518	318	10	pashigreva	pashigreva	PROPN
eurjchem-2518	318	11	,	,	PUNCT
eurjchem-2518	318	12	a.	a.	NOUN
eurjchem-2518	318	13	v.	v.	PROPN
eurjchem-2518	318	14	;	;	PUNCT
eurjchem-2518	318	15	voroshina	voroshina	NOUN
eurjchem-2518	318	16	,	,	PUNCT
eurjchem-2518	318	17	o.	o.	PROPN
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eurjchem-2518	318	19	;	;	PUNCT
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eurjchem-2518	318	21	,	,	PUNCT
eurjchem-2518	318	22	i.	i.	PROPN
eurjchem-2518	318	23	i.	i.	PROPN
eurjchem-2518	318	24	;	;	PUNCT
eurjchem-2518	318	25	parmon	parmon	PROPN
eurjchem-2518	318	26	,	,	PUNCT
eurjchem-2518	318	27	v.	v.	ADP
eurjchem-2518	318	28	n.	n.	PROPN
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eurjchem-2518	318	32	of	of	ADP
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eurjchem-2518	318	34	sulfide	sulfide	NOUN
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eurjchem-2518	318	36	mercaptans	mercaptan	NOUN
eurjchem-2518	318	37	.	.	PUNCT
eurjchem-2518	319	1	russ	russ	PROPN
eurjchem-2518	319	2	.	.	PUNCT
eurjchem-2518	320	1	patent	patent	NOUN
eurjchem-2518	320	2	no	no	DET
eurjchem-2518	320	3	2,261,838	2,261,838	NUM
eurjchem-2518	320	4	,	,	PUNCT
eurjchem-2518	320	5	2005	2005	NUM
eurjchem-2518	320	6	.	.	PUNCT
eurjchem-2518	321	1	[	[	X
eurjchem-2518	321	2	19	19	NUM
eurjchem-2518	321	3	]	]	PUNCT
eurjchem-2518	321	4	.	.	PUNCT
eurjchem-2518	321	5	startsev	startsev	PROPN
eurjchem-2518	321	6	,	,	PUNCT
eurjchem-2518	321	7	a.	a.	NOUN
eurjchem-2518	321	8	n.	n.	PROPN
eurjchem-2518	321	9	;	;	PUNCT
eurjchem-2518	321	10	kruglyakova	kruglyakova	PROPN
eurjchem-2518	321	11	,	,	PUNCT
eurjchem-2518	321	12	o.	o.	PROPN
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eurjchem-2518	321	14	;	;	PUNCT
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eurjchem-2518	325	7	,	,	PUNCT
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eurjchem-2518	327	2	.	.	PROPN
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eurjchem-2518	327	4	,	,	PUNCT
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eurjchem-2518	328	3	]	]	PUNCT
eurjchem-2518	328	4	.	.	PUNCT
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eurjchem-2518	329	2	,	,	PUNCT
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eurjchem-2518	329	5	;	;	PUNCT
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eurjchem-2518	329	7	,	,	PUNCT
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eurjchem-2518	329	32	,	,	PUNCT
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eurjchem-2518	331	2	.	.	PUNCT
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eurjchem-2518	332	2	,	,	PUNCT
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eurjchem-2518	333	3	]	]	PUNCT
eurjchem-2518	333	4	.	.	PUNCT
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eurjchem-2518	334	7	,	,	PUNCT
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eurjchem-2518	336	3	.	.	PUNCT
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eurjchem-2518	337	2	.	.	PUNCT
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eurjchem-2518	340	2	23	23	NUM
eurjchem-2518	340	3	]	]	PUNCT
eurjchem-2518	340	4	.	.	PUNCT
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eurjchem-2518	343	2	,	,	PUNCT
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eurjchem-2518	344	3	]	]	PUNCT
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eurjchem-2518	348	1	surf	surf	PROPN
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eurjchem-2518	350	3	]	]	PUNCT
eurjchem-2518	350	4	.	.	PUNCT
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eurjchem-2518	352	1	surf	surf	PROPN
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eurjchem-2518	353	2	.	.	PROPN
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eurjchem-2518	353	4	,	,	PUNCT
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eurjchem-2518	353	8	.	.	PUNCT
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eurjchem-2518	354	4	.	.	PUNCT
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eurjchem-2518	356	2	.	.	PUNCT
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eurjchem-2518	357	3	,	,	PUNCT
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eurjchem-2518	357	5	,	,	PUNCT
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eurjchem-2518	357	7	.	.	PUNCT
eurjchem-2518	358	1	[	[	X
eurjchem-2518	358	2	28	28	NUM
eurjchem-2518	358	3	]	]	PUNCT
eurjchem-2518	358	4	.	.	PUNCT
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eurjchem-2518	359	4	;	;	PUNCT
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eurjchem-2518	359	8	.	.	PUNCT
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eurjchem-2518	360	5	perfect	perfect	ADJ
eurjchem-2518	360	6	and	and	CCONJ
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eurjchem-2518	360	8	-	-	PUNCT
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eurjchem-2518	360	10	ni(110	ni(110	NOUN
eurjchem-2518	360	11	)	)	PUNCT
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eurjchem-2518	360	15	first	first	ADJ
eurjchem-2518	360	16	-	-	PUNCT
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eurjchem-2518	360	19	.	.	PUNCT
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eurjchem-2518	362	5	,	,	PUNCT
eurjchem-2518	362	6	45	45	NUM
eurjchem-2518	362	7	,	,	PUNCT
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eurjchem-2518	362	9	.	.	PUNCT
eurjchem-2518	363	1	[	[	X
eurjchem-2518	363	2	29	29	NUM
eurjchem-2518	363	3	]	]	PUNCT
eurjchem-2518	363	4	.	.	PUNCT
eurjchem-2518	364	1	hyman	hyman	PROPN
eurjchem-2518	364	2	,	,	PUNCT
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eurjchem-2518	364	4	p.	p.	PROPN
eurjchem-2518	364	5	;	;	PUNCT
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eurjchem-2518	364	7	,	,	PUNCT
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eurjchem-2518	364	9	t.	t.	PROPN
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eurjchem-2518	364	12	,	,	PUNCT
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eurjchem-2518	365	4	theory	theory	NOUN
eurjchem-2518	365	5	study	study	NOUN
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eurjchem-2518	365	7	h2s	h2s	NOUN
eurjchem-2518	365	8	decomposition	decomposition	NOUN
eurjchem-2518	365	9	on	on	ADP
eurjchem-2518	365	10	the	the	DET
eurjchem-2518	365	11	(	(	PUNCT
eurjchem-2518	365	12	111	111	NUM
eurjchem-2518	365	13	)	)	PUNCT
eurjchem-2518	365	14	surfaces	surface	NOUN
eurjchem-2518	365	15	of	of	ADP
eurjchem-2518	365	16	model	model	NOUN
eurjchem-2518	365	17	pd	pd	NOUN
eurjchem-2518	365	18	-	-	PUNCT
eurjchem-2518	365	19	alloys	alloy	NOUN
eurjchem-2518	365	20	.	.	PUNCT
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eurjchem-2518	366	2	.	.	PUNCT
eurjchem-2518	367	1	sci	sci	PROPN
eurjchem-2518	367	2	.	.	PROPN
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eurjchem-2518	367	4	,	,	PUNCT
eurjchem-2518	367	5	601	601	NUM
eurjchem-2518	367	6	,	,	PUNCT
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eurjchem-2518	367	8	.	.	PUNCT
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eurjchem-2518	368	2	30	30	NUM
eurjchem-2518	368	3	]	]	PUNCT
eurjchem-2518	368	4	.	.	PUNCT
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eurjchem-2518	369	2	,	,	PUNCT
eurjchem-2518	369	3	d.	d.	PROPN
eurjchem-2518	369	4	e.	e.	PROPN
eurjchem-2518	369	5	;	;	PUNCT
eurjchem-2518	369	6	carter	carter	PROPN
eurjchem-2518	369	7	,	,	PUNCT
eurjchem-2518	369	8	e.	e.	PROPN
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eurjchem-2518	369	10	adsorption	adsorption	NOUN
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eurjchem-2518	369	13	,	,	PUNCT
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eurjchem-2518	369	17	h2s	h2s	PROPN
eurjchem-2518	369	18	on	on	ADP
eurjchem-2518	369	19	fe(100	fe(100	NOUN
eurjchem-2518	369	20	)	)	PUNCT
eurjchem-2518	369	21	from	from	ADP
eurjchem-2518	369	22	first	first	ADJ
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eurjchem-2518	369	24	.	.	PUNCT
eurjchem-2518	370	1	j.	j.	PROPN
eurjchem-2518	370	2	phys	phys	PROPN
eurjchem-2518	370	3	.	.	PUNCT
eurjchem-2518	371	1	chem	chem	PROPN
eurjchem-2518	371	2	.	.	PUNCT
eurjchem-2518	372	1	b	b	NOUN
eurjchem-2518	372	2	2004	2004	NUM
eurjchem-2518	372	3	,	,	PUNCT
eurjchem-2518	372	4	108	108	NUM
eurjchem-2518	372	5	,	,	PUNCT
eurjchem-2518	372	6	19140	19140	NUM
eurjchem-2518	372	7	–	–	PUNCT
eurjchem-2518	372	8	19145	19145	NUM
eurjchem-2518	372	9	.	.	PUNCT
eurjchem-2518	373	1	[	[	X
eurjchem-2518	373	2	31	31	NUM
eurjchem-2518	373	3	]	]	PUNCT
eurjchem-2518	373	4	.	.	PUNCT
eurjchem-2518	374	1	abufager	abufag	ADJ
eurjchem-2518	374	2	,	,	PUNCT
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eurjchem-2518	374	4	n.	n.	PROPN
eurjchem-2518	374	5	;	;	PUNCT
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eurjchem-2518	375	2	,	,	PUNCT
eurjchem-2518	375	3	p.	p.	PROPN
eurjchem-2518	375	4	g.	g.	PROPN
eurjchem-2518	375	5	;	;	PUNCT
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eurjchem-2518	375	7	,	,	PUNCT
eurjchem-2518	375	8	c.	c.	PROPN
eurjchem-2518	375	9	;	;	PUNCT
eurjchem-2518	375	10	busnengo	busnengo	PROPN
eurjchem-2518	375	11	,	,	PUNCT
eurjchem-2518	375	12	h.	h.	PROPN
eurjchem-2518	375	13	f.	f.	PROPN
eurjchem-2518	375	14	dft	dft	PROPN
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eurjchem-2518	375	17	dissociative	dissociative	ADJ
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eurjchem-2518	375	20	hydrogen	hydrogen	NOUN
eurjchem-2518	375	21	sulfide	sulfide	NOUN
eurjchem-2518	375	22	on	on	ADP
eurjchem-2518	375	23	cu(111	cu(111	NOUN
eurjchem-2518	375	24	)	)	PUNCT
eurjchem-2518	375	25	and	and	CCONJ
eurjchem-2518	375	26	au(111	au(111	NOUN
eurjchem-2518	375	27	)	)	PUNCT
eurjchem-2518	375	28	.	.	PUNCT
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eurjchem-2518	376	3	,	,	PUNCT
eurjchem-2518	376	4	24	24	NUM
eurjchem-2518	376	5	,	,	PUNCT
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eurjchem-2518	376	7	.	.	PUNCT
eurjchem-2518	377	1	[	[	X
eurjchem-2518	377	2	32	32	NUM
eurjchem-2518	377	3	]	]	PUNCT
eurjchem-2518	377	4	.	.	PUNCT
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eurjchem-2518	378	2	,	,	PUNCT
eurjchem-2518	378	3	s.	s.	PROPN
eurjchem-2518	378	4	o.	o.	PROPN
eurjchem-2518	378	5	;	;	PUNCT
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eurjchem-2518	378	7	,	,	PUNCT
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eurjchem-2518	378	10	;	;	PUNCT
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eurjchem-2518	378	12	,	,	PUNCT
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eurjchem-2518	378	14	;	;	PUNCT
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eurjchem-2518	378	25	step	step	NOUN
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eurjchem-2518	378	27	the	the	DET
eurjchem-2518	378	28	h2s	h2s	NOUN
eurjchem-2518	378	29	reaction	reaction	NOUN
eurjchem-2518	378	30	on	on	ADP
eurjchem-2518	378	31	fe	fe	X
eurjchem-2518	378	32	(	(	PUNCT
eurjchem-2518	378	33	110	110	NUM
eurjchem-2518	378	34	)	)	PUNCT
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eurjchem-2518	379	2	.	.	PUNCT
eurjchem-2518	380	1	surf	surf	PROPN
eurjchem-2518	380	2	.	.	PUNCT
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eurjchem-2518	381	2	.	.	PROPN
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eurjchem-2518	381	8	.	.	PUNCT
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eurjchem-2518	382	2	33	33	NUM
eurjchem-2518	382	3	]	]	PUNCT
eurjchem-2518	382	4	.	.	PUNCT
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eurjchem-2518	383	2	,	,	PUNCT
eurjchem-2518	383	3	s.	s.	PROPN
eurjchem-2518	383	4	w.	w.	PROPN
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eurjchem-2518	383	6	and	and	CCONJ
eurjchem-2518	383	7	kinetics	kinetic	NOUN
eurjchem-2518	383	8	of	of	ADP
eurjchem-2518	383	9	sulfur	sulfur	NOUN
eurjchem-2518	383	10	-	-	PUNCT
eurjchem-2518	383	11	containing	contain	VERB
eurjchem-2518	383	12	molecules	molecule	NOUN
eurjchem-2518	383	13	and	and	CCONJ
eurjchem-2518	383	14	radicals	radical	NOUN
eurjchem-2518	383	15	.	.	PUNCT
eurjchem-2518	384	1	chem	chem	PROPN
eurjchem-2518	384	2	.	.	PUNCT
eurjchem-2518	385	1	rev	rev	PROPN
eurjchem-2518	385	2	.	.	PROPN
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eurjchem-2518	385	4	,	,	PUNCT
eurjchem-2518	385	5	78	78	NUM
eurjchem-2518	385	6	,	,	PUNCT
eurjchem-2518	385	7	23–35	23–35	NUM
eurjchem-2518	385	8	.	.	PUNCT
eurjchem-2518	386	1	[	[	X
eurjchem-2518	386	2	34	34	NUM
eurjchem-2518	386	3	]	]	PUNCT
eurjchem-2518	386	4	.	.	PUNCT
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eurjchem-2518	387	2	,	,	PUNCT
eurjchem-2518	387	3	v.	v.	PROPN
eurjchem-2518	387	4	i.	i.	PROPN
eurjchem-2518	387	5	;	;	PUNCT
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eurjchem-2518	387	7	,	,	PUNCT
eurjchem-2518	387	8	l.	l.	PROPN
eurjchem-2518	387	9	v.	v.	PROPN
eurjchem-2518	387	10	;	;	PUNCT
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eurjchem-2518	387	12	,	,	PUNCT
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eurjchem-2518	387	18	v.	v.	PROPN
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eurjchem-2518	387	20	;	;	PUNCT
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eurjchem-2518	387	22	,	,	PUNCT
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eurjchem-2518	387	24	l.	l.	PROPN
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eurjchem-2518	387	30	electron	electron	NOUN
eurjchem-2518	387	31	affinities	affinity	NOUN
eurjchem-2518	387	32	;	;	PUNCT
eurjchem-2518	387	33	st	st	PROPN
eurjchem-2518	387	34	martin	martin	PROPN
eurjchem-2518	387	35	’s	’s	PART
eurjchem-2518	387	36	press	press	NOUN
eurjchem-2518	387	37	:	:	PUNCT
eurjchem-2518	387	38	new	new	PROPN
eurjchem-2518	387	39	york	york	PROPN
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eurjchem-2518	388	6	,	,	PUNCT
eurjchem-2518	388	7	2024	2024	NUM
eurjchem-2518	388	8	)	)	PUNCT
eurjchem-2518	388	9	.	.	PUNCT
eurjchem-2518	389	1	[	[	X
eurjchem-2518	389	2	35	35	NUM
eurjchem-2518	389	3	]	]	PUNCT
eurjchem-2518	389	4	.	.	PUNCT
eurjchem-2518	390	1	darwent	darwent	NOUN
eurjchem-2518	390	2	,	,	PUNCT
eurjchem-2518	390	3	b.	b.	PROPN
eurjchem-2518	390	4	d.	d.	PROPN
eurjchem-2518	390	5	bond	bond	PROPN
eurjchem-2518	390	6	dissociation	dissociation	NOUN
eurjchem-2518	390	7	energies	energy	NOUN
eurjchem-2518	390	8	in	in	ADP
eurjchem-2518	390	9	simple	simple	ADJ
eurjchem-2518	390	10	molecules	molecule	NOUN
eurjchem-2518	390	11	;	;	PUNCT
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eurjchem-2518	390	13	bureau	bureau	PROPN
eurjchem-2518	390	14	of	of	ADP
eurjchem-2518	390	15	standards	standard	NOUN
eurjchem-2518	390	16	:	:	PUNCT
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eurjchem-2518	390	18	,	,	PUNCT
eurjchem-2518	390	19	md	md	PROPN
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eurjchem-2518	390	22	.	.	PUNCT
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eurjchem-2518	391	2	36	36	NUM
eurjchem-2518	391	3	]	]	PUNCT
eurjchem-2518	391	4	.	.	PUNCT
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eurjchem-2518	392	2	,	,	PUNCT
eurjchem-2518	392	3	j.	j.	PROPN
eurjchem-2518	392	4	a.	a.	PROPN
eurjchem-2518	392	5	;	;	PUNCT
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eurjchem-2518	392	7	,	,	PUNCT
eurjchem-2518	392	8	j.	j.	PROPN
eurjchem-2518	392	9	;	;	PUNCT
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eurjchem-2518	392	11	,	,	PUNCT
eurjchem-2518	392	12	m.	m.	NOUN
eurjchem-2518	392	13	;	;	PUNCT
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eurjchem-2518	392	15	,	,	PUNCT
eurjchem-2518	392	16	t.	t.	PROPN
eurjchem-2518	392	17	;	;	PUNCT
eurjchem-2518	392	18	chaturvedi	chaturvedi	PROPN
eurjchem-2518	392	19	,	,	PUNCT
eurjchem-2518	392	20	s.	s.	PROPN
eurjchem-2518	392	21	;	;	PUNCT
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eurjchem-2518	392	23	,	,	PUNCT
eurjchem-2518	392	24	a.	a.	NOUN
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eurjchem-2518	392	26	of	of	ADP
eurjchem-2518	392	27	sulfur	sulfur	NOUN
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eurjchem-2518	392	29	pt(111	pt(111	ADJ
eurjchem-2518	392	30	)	)	PUNCT
eurjchem-2518	392	31	and	and	CCONJ
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eurjchem-2518	392	33	/	/	SYM
eurjchem-2518	392	34	pt(111	pt(111	ADJ
eurjchem-2518	392	35	):	):	PUNCT
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eurjchem-2518	392	37	of	of	ADP
eurjchem-2518	392	38	coverage	coverage	NOUN
eurjchem-2518	392	39	and	and	CCONJ
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eurjchem-2518	392	41	–	–	PUNCT
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eurjchem-2518	392	43	bonding	bonding	NOUN
eurjchem-2518	392	44	on	on	ADP
eurjchem-2518	392	45	reactivity	reactivity	NOUN
eurjchem-2518	392	46	toward	toward	ADP
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eurjchem-2518	392	48	.	.	PUNCT
eurjchem-2518	393	1	j.	j.	PROPN
eurjchem-2518	393	2	chem	chem	PROPN
eurjchem-2518	393	3	.	.	PUNCT
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eurjchem-2518	394	2	.	.	PUNCT
eurjchem-2518	395	1	2000	2000	NUM
eurjchem-2518	395	2	,	,	PUNCT
eurjchem-2518	395	3	113	113	NUM
eurjchem-2518	395	4	,	,	PUNCT
eurjchem-2518	395	5	11284–11292	11284–11292	NUM
eurjchem-2518	395	6	.	.	PUNCT
eurjchem-2518	396	1	[	[	X
eurjchem-2518	396	2	37	37	NUM
eurjchem-2518	396	3	]	]	SYM
eurjchem-2518	396	4	.	.	PUNCT
eurjchem-2518	397	1	christmann	christmann	PROPN
eurjchem-2518	397	2	,	,	PUNCT
eurjchem-2518	397	3	k.	k.	PROPN
eurjchem-2518	397	4	;	;	PUNCT
eurjchem-2518	397	5	ertl	ertl	PROPN
eurjchem-2518	397	6	,	,	PUNCT
eurjchem-2518	397	7	g.	g.	PROPN
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eurjchem-2518	397	13	):	):	PUNCT
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eurjchem-2518	397	17	atomic	atomic	ADJ
eurjchem-2518	397	18	steps	step	NOUN
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eurjchem-2518	398	2	.	.	PUNCT
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eurjchem-2518	400	3	]	]	PUNCT
eurjchem-2518	400	4	.	.	PUNCT
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eurjchem-2518	405	3	]	]	PUNCT
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eurjchem-2518	406	21	)	)	PUNCT
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eurjchem-2518	410	3	]	]	PUNCT
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eurjchem-2518	416	2	41	41	NUM
eurjchem-2518	416	3	]	]	PUNCT
eurjchem-2518	416	4	.	.	PUNCT
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eurjchem-2518	417	51	a.	a.	PROPN
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eurjchem-2518	417	102	,	,	PUNCT
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eurjchem-2518	419	8	.	.	PUNCT
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eurjchem-2518	420	2	42	42	NUM
eurjchem-2518	420	3	]	]	PUNCT
eurjchem-2518	420	4	.	.	PUNCT
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eurjchem-2518	423	4	,	,	PUNCT
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eurjchem-2518	423	6	,	,	PUNCT
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eurjchem-2518	423	8	.	.	PUNCT
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eurjchem-2518	424	3	]	]	PUNCT
eurjchem-2518	424	4	.	.	PUNCT
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eurjchem-2518	425	2	,	,	PUNCT
eurjchem-2518	425	3	h.	h.	PROPN
eurjchem-2518	425	4	;	;	PUNCT
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eurjchem-2518	425	9	;	;	PUNCT
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eurjchem-2518	430	3	is	be	AUX
eurjchem-2518	430	4	published	publish	VERB
eurjchem-2518	430	5	and	and	CCONJ
eurjchem-2518	430	6	licensed	license	VERB
eurjchem-2518	430	7	by	by	ADP
eurjchem-2518	430	8	atlanta	atlanta	PROPN
eurjchem-2518	430	9	publishing	publishing	PROPN
eurjchem-2518	430	10	house	house	PROPN
eurjchem-2518	430	11	llc	llc	PROPN
eurjchem-2518	430	12	,	,	PUNCT
eurjchem-2518	430	13	atlanta	atlanta	PROPN
eurjchem-2518	430	14	,	,	PUNCT
eurjchem-2518	430	15	ga	ga	PROPN
eurjchem-2518	430	16	,	,	PUNCT
eurjchem-2518	430	17	usa	usa	PROPN
eurjchem-2518	430	18	.	.	PUNCT
eurjchem-2518	431	1	the	the	DET
eurjchem-2518	431	2	full	full	ADJ
eurjchem-2518	431	3	terms	term	NOUN
eurjchem-2518	431	4	of	of	ADP
eurjchem-2518	431	5	this	this	DET
eurjchem-2518	431	6	license	license	NOUN
eurjchem-2518	431	7	are	be	AUX
eurjchem-2518	431	8	available	available	ADJ
eurjchem-2518	431	9	at	at	ADP
eurjchem-2518	431	10	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2518	431	11	and	and	CCONJ
eurjchem-2518	431	12	incorporate	incorporate	VERB
eurjchem-2518	431	13	the	the	DET
eurjchem-2518	431	14	creative	creative	ADJ
eurjchem-2518	431	15	commons	common	NOUN
eurjchem-2518	431	16	attribution	attribution	NOUN
eurjchem-2518	431	17	-	-	PUNCT
eurjchem-2518	431	18	non	non	ADJ
eurjchem-2518	431	19	commercial	commercial	NOUN
eurjchem-2518	431	20	(	(	PUNCT
eurjchem-2518	431	21	cc	cc	NOUN
eurjchem-2518	431	22	by	by	ADP
eurjchem-2518	431	23	nc	nc	PROPN
eurjchem-2518	431	24	)	)	PUNCT
eurjchem-2518	431	25	(	(	PUNCT
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eurjchem-2518	431	30	license	license	NOUN
eurjchem-2518	431	31	(	(	PUNCT
eurjchem-2518	431	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2518	431	33	)	)	PUNCT
eurjchem-2518	431	34	.	.	PUNCT
eurjchem-2518	432	1	by	by	ADP
eurjchem-2518	432	2	accessing	access	VERB
eurjchem-2518	432	3	the	the	DET
eurjchem-2518	432	4	work	work	NOUN
eurjchem-2518	432	5	,	,	PUNCT
eurjchem-2518	432	6	you	you	PRON
eurjchem-2518	432	7	hereby	hereby	ADV
eurjchem-2518	432	8	accept	accept	VERB
eurjchem-2518	432	9	the	the	DET
eurjchem-2518	432	10	terms	term	NOUN
eurjchem-2518	432	11	.	.	PUNCT
eurjchem-2518	433	1	this	this	PRON
eurjchem-2518	433	2	is	be	AUX
eurjchem-2518	433	3	an	an	DET
eurjchem-2518	433	4	open	open	ADJ
eurjchem-2518	433	5	access	access	NOUN
eurjchem-2518	433	6	article	article	NOUN
eurjchem-2518	433	7	distributed	distribute	VERB
eurjchem-2518	433	8	under	under	ADP
eurjchem-2518	433	9	the	the	DET
eurjchem-2518	433	10	terms	term	NOUN
eurjchem-2518	433	11	and	and	CCONJ
eurjchem-2518	433	12	conditions	condition	NOUN
eurjchem-2518	433	13	of	of	ADP
eurjchem-2518	433	14	the	the	DET
eurjchem-2518	433	15	cc	cc	PROPN
eurjchem-2518	433	16	by	by	ADP
eurjchem-2518	433	17	nc	nc	PROPN
eurjchem-2518	433	18	license	license	PROPN
eurjchem-2518	433	19	,	,	PUNCT
eurjchem-2518	433	20	which	which	PRON
eurjchem-2518	433	21	permits	permit	VERB
eurjchem-2518	433	22	unrestricted	unrestricted	ADJ
eurjchem-2518	433	23	non	non	ADJ
eurjchem-2518	433	24	-	-	ADJ
eurjchem-2518	433	25	commercial	commercial	ADJ
eurjchem-2518	433	26	use	use	NOUN
eurjchem-2518	433	27	,	,	PUNCT
eurjchem-2518	433	28	distribution	distribution	NOUN
eurjchem-2518	433	29	,	,	PUNCT
eurjchem-2518	433	30	and	and	CCONJ
eurjchem-2518	433	31	reproduction	reproduction	NOUN
eurjchem-2518	433	32	in	in	ADP
eurjchem-2518	433	33	any	any	DET
eurjchem-2518	433	34	medium	medium	NOUN
eurjchem-2518	433	35	,	,	PUNCT
eurjchem-2518	433	36	provided	provide	VERB
eurjchem-2518	433	37	the	the	DET
eurjchem-2518	433	38	original	original	ADJ
eurjchem-2518	433	39	work	work	NOUN
eurjchem-2518	433	40	is	be	AUX
eurjchem-2518	433	41	properly	properly	ADV
eurjchem-2518	433	42	cited	cite	VERB
eurjchem-2518	433	43	without	without	ADP
eurjchem-2518	433	44	any	any	DET
eurjchem-2518	433	45	further	further	ADJ
eurjchem-2518	433	46	permission	permission	NOUN
eurjchem-2518	433	47	from	from	ADP
eurjchem-2518	433	48	atlanta	atlanta	PROPN
eurjchem-2518	433	49	publishing	publishing	PROPN
eurjchem-2518	433	50	house	house	PROPN
eurjchem-2518	433	51	llc	llc	PROPN
eurjchem-2518	433	52	(	(	PUNCT
eurjchem-2518	433	53	european	european	PROPN
eurjchem-2518	433	54	journal	journal	PROPN
eurjchem-2518	433	55	of	of	ADP
eurjchem-2518	433	56	chemistry	chemistry	NOUN
eurjchem-2518	433	57	)	)	PUNCT
eurjchem-2518	433	58	.	.	PUNCT
eurjchem-2518	434	1	no	no	DET
eurjchem-2518	434	2	use	use	NOUN
eurjchem-2518	434	3	,	,	PUNCT
eurjchem-2518	434	4	distribution	distribution	NOUN
eurjchem-2518	434	5	,	,	PUNCT
eurjchem-2518	434	6	or	or	CCONJ
eurjchem-2518	434	7	reproduction	reproduction	NOUN
eurjchem-2518	434	8	is	be	AUX
eurjchem-2518	434	9	permitted	permit	VERB
eurjchem-2518	434	10	which	which	PRON
eurjchem-2518	434	11	does	do	AUX
eurjchem-2518	434	12	not	not	PART
eurjchem-2518	434	13	comply	comply	VERB
eurjchem-2518	434	14	with	with	ADP
eurjchem-2518	434	15	these	these	DET
eurjchem-2518	434	16	terms	term	NOUN
eurjchem-2518	434	17	.	.	PUNCT
eurjchem-2518	435	1	permissions	permission	NOUN
eurjchem-2518	435	2	for	for	ADP
eurjchem-2518	435	3	commercial	commercial	ADJ
eurjchem-2518	435	4	use	use	NOUN
eurjchem-2518	435	5	of	of	ADP
eurjchem-2518	435	6	this	this	DET
eurjchem-2518	435	7	work	work	NOUN
eurjchem-2518	435	8	beyond	beyond	ADP
eurjchem-2518	435	9	the	the	DET
eurjchem-2518	435	10	scope	scope	NOUN
eurjchem-2518	435	11	of	of	ADP
eurjchem-2518	435	12	the	the	DET
eurjchem-2518	435	13	license	license	NOUN
eurjchem-2518	435	14	(	(	PUNCT
eurjchem-2518	435	15	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2518	435	16	)	)	PUNCT
eurjchem-2518	435	17	are	be	AUX
eurjchem-2518	435	18	administered	administer	VERB
eurjchem-2518	435	19	by	by	ADP
eurjchem-2518	435	20	atlanta	atlanta	PROPN
eurjchem-2518	435	21	publishing	publishing	PROPN
eurjchem-2518	435	22	house	house	PROPN
eurjchem-2518	435	23	llc	llc	PROPN
eurjchem-2518	435	24	(	(	PUNCT
eurjchem-2518	435	25	european	european	PROPN
eurjchem-2518	435	26	journal	journal	PROPN
eurjchem-2518	435	27	of	of	ADP
eurjchem-2518	435	28	chemistry	chemistry	NOUN
eurjchem-2518	435	29	)	)	PUNCT
eurjchem-2518	435	30	.	.	PUNCT
eurjchem-2518	436	1	mailto:anatolii.startsev@gmail.com	mailto:anatolii.startsev@gmail.com	X
eurjchem-2518	436	2	mailto:anatolii-startsev@yandex.ru	mailto:anatolii-startsev@yandex.ru	PROPN
eurjchem-2518	437	1	https://orcid.org/0000-0002-0241-7534	https://orcid.org/0000-0002-0241-7534	PROPN
eurjchem-2518	437	2	http://eng.startsev-an.ru/	http://eng.startsev-an.ru/	NOUN
eurjchem-2518	437	3	http://eng.startsev-an.ru/wp-content/uploads/2017/01/jcce-2013-7-1007-startsev.pdf	http://eng.startsev-an.ru/wp-content/uploads/2017/01/jcce-2013-7-1007-startsev.pdf	SYM
eurjchem-2518	438	1	http://eng.startsev-an.ru/wp-content/uploads/2017/01/jcce-2013-7-1007-startsev.pdf	http://eng.startsev-an.ru/wp-content/uploads/2017/01/jcce-2013-7-1007-startsev.pdf	X
eurjchem-2518	439	1	https://archive.org/details/bondenergiesioni0000vive	https://archive.org/details/bondenergiesioni0000vive	ADJ
eurjchem-2518	439	2	https://www.isjaee.com/jour/article/view/2108?locale=en_us	https://www.isjaee.com/jour/article/view/2108?locale=en_us	ADP
eurjchem-2518	439	3	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2518	439	4	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2518	439	5	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2518	439	6	1	1	NUM
eurjchem-2518	439	7	.	.	PUNCT
eurjchem-2518	439	8	introduction	introduction	NOUN
eurjchem-2518	439	9	2	2	NUM
eurjchem-2518	439	10	.	.	PUNCT
eurjchem-2518	439	11	initial	initial	ADJ
eurjchem-2518	439	12	data	datum	NOUN
eurjchem-2518	439	13	for	for	ADP
eurjchem-2518	439	14	reflection	reflection	NOUN
eurjchem-2518	439	15	:	:	PUNCT
eurjchem-2518	439	16	sulfide	sulfide	NOUN
eurjchem-2518	439	17	catalysts	catalyst	NOUN
eurjchem-2518	439	18	3	3	NUM
eurjchem-2518	439	19	.	.	PUNCT
eurjchem-2518	439	20	initial	initial	ADJ
eurjchem-2518	439	21	data	datum	NOUN
eurjchem-2518	439	22	for	for	ADP
eurjchem-2518	439	23	reflection	reflection	NOUN
eurjchem-2518	439	24	:	:	PUNCT
eurjchem-2518	439	25	metal	metal	NOUN
eurjchem-2518	439	26	catalysts	catalyst	NOUN
eurjchem-2518	439	27	4	4	NUM
eurjchem-2518	439	28	.	.	X
eurjchem-2518	439	29	entropy	entropy	NOUN
eurjchem-2518	439	30	of	of	ADP
eurjchem-2518	439	31	the	the	DET
eurjchem-2518	439	32	surface	surface	NOUN
eurjchem-2518	439	33	catalytic	catalytic	ADJ
eurjchem-2518	439	34	reaction	reaction	NOUN
eurjchem-2518	439	35	:	:	PUNCT
eurjchem-2518	439	36	why	why	SCONJ
eurjchem-2518	439	37	is	be	AUX
eurjchem-2518	439	38	it	it	PRON
eurjchem-2518	439	39	important	important	ADJ
eurjchem-2518	439	40	and	and	CCONJ
eurjchem-2518	439	41	necessary	necessary	ADJ
eurjchem-2518	439	42	?	?	PUNCT
eurjchem-2518	440	1	5	5	X
eurjchem-2518	440	2	.	.	X
eurjchem-2518	440	3	conclusion	conclusion	NOUN
eurjchem-2518	440	4	disclosure	disclosure	NOUN
eurjchem-2518	440	5	statement	statement	NOUN
eurjchem-2518	440	6	orcid	orcid	NOUN
eurjchem-2518	440	7	and	and	CCONJ
eurjchem-2518	440	8	email	email	NOUN
eurjchem-2518	440	9	references	reference	NOUN
eurjchem-2518	440	10	printfield10	printfield10	PROPN
eurjchem-2518	440	11	:	:	PUNCT
eurjchem-2518	440	12	printfield11	printfield11	NOUN
eurjchem-2518	440	13	:	:	PUNCT
eurjchem-2518	440	14	printfield12	printfield12	PROPN
eurjchem-2518	440	15	:	:	PUNCT
eurjchem-2518	440	16	printfield13	printfield13	VERB
eurjchem-2518	440	17	:	:	PUNCT
eurjchem-2518	440	18	printfield14	printfield14	NOUN
eurjchem-2518	440	19	:	:	PUNCT
eurjchem-2518	440	20	printfield15	printfield15	NOUN
eurjchem-2518	440	21	:	:	PUNCT
eurjchem-2518	440	22	printfield16	printfield16	ADJ
eurjchem-2518	440	23	:	:	PUNCT
eurjchem-2518	440	24	printfield17	printfield17	NOUN
eurjchem-2518	440	25	:	:	PUNCT
eurjchem-2518	440	26	printfield20	printfield20	PROPN
eurjchem-2518	440	27	:	:	PUNCT
eurjchem-2518	440	28	printfield21	printfield21	ADJ
eurjchem-2518	440	29	:	:	PUNCT
eurjchem-2518	440	30	printfield22	printfield22	NOUN
eurjchem-2518	440	31	:	:	PUNCT
eurjchem-2518	440	32	printfield23	printfield23	NOUN
eurjchem-2518	440	33	:	:	PUNCT
eurjchem-2518	440	34	printfield24	printfield24	NOUN
eurjchem-2518	440	35	:	:	PUNCT
eurjchem-2518	440	36	printfield25	printfield25	NOUN
eurjchem-2518	440	37	:	:	PUNCT
eurjchem-2518	440	38	printfield26	printfield26	ADJ
eurjchem-2518	440	39	:	:	PUNCT
eurjchem-2518	440	40	printfield27	printfield27	NOUN
eurjchem-2518	440	41	:	:	PUNCT