id	sid	tid	token	lemma	pos
eurjchem-2544	1	1	single	single	ADJ
eurjchem-2544	1	2	and	and	CCONJ
eurjchem-2544	1	3	mixed	mixed	ADJ
eurjchem-2544	1	4	dithiocarbamato	dithiocarbamato	NOUN
eurjchem-2544	1	5	metal(iii	metal(iii	NOUN
eurjchem-2544	1	6	)	)	PUNCT
eurjchem-2544	1	7	complexes	complex	NOUN
eurjchem-2544	1	8	(	(	PUNCT
eurjchem-2544	1	9	co	co	NOUN
eurjchem-2544	1	10	,	,	PUNCT
eurjchem-2544	1	11	rh	rh	PROPN
eurjchem-2544	1	12	,	,	PUNCT
eurjchem-2544	1	13	and	and	CCONJ
eurjchem-2544	1	14	ir	ir	PROPN
eurjchem-2544	1	15	):	):	PUNCT
eurjchem-2544	1	16	crystal	crystal	NOUN
eurjchem-2544	1	17	and	and	CCONJ
eurjchem-2544	1	18	molecular	molecular	ADJ
eurjchem-2544	1	19	structure	structure	NOUN
eurjchem-2544	1	20	description	description	NOUN
eurjchem-2544	1	21	and	and	CCONJ
eurjchem-2544	1	22	interplay	interplay	NOUN
eurjchem-2544	1	23	european	european	PROPN
eurjchem-2544	1	24	journal	journal	PROPN
eurjchem-2544	1	25	of	of	ADP
eurjchem-2544	1	26	chemistry	chemistry	NOUN
eurjchem-2544	1	27	15	15	NUM
eurjchem-2544	1	28	(	(	PUNCT
eurjchem-2544	1	29	3	3	NUM
eurjchem-2544	1	30	)	)	PUNCT
eurjchem-2544	1	31	(	(	PUNCT
eurjchem-2544	1	32	2024	2024	NUM
eurjchem-2544	1	33	)	)	PUNCT
eurjchem-2544	1	34	291	291	NUM
eurjchem-2544	1	35	-	-	SYM
eurjchem-2544	1	36	301	301	NUM
eurjchem-2544	1	37	european	european	ADJ
eurjchem-2544	1	38	journal	journal	PROPN
eurjchem-2544	1	39	of	of	ADP
eurjchem-2544	1	40	chemistry	chemistry	NOUN
eurjchem-2544	1	41	issn	issn	VERB
eurjchem-2544	1	42	2153	2153	NUM
eurjchem-2544	1	43	-	-	SYM
eurjchem-2544	1	44	2249	2249	NUM
eurjchem-2544	1	45	(	(	PUNCT
eurjchem-2544	1	46	print	print	NOUN
eurjchem-2544	1	47	)	)	PUNCT
eurjchem-2544	1	48	/	/	PUNCT
eurjchem-2544	1	49	issn	issn	PROPN
eurjchem-2544	1	50	2153	2153	NUM
eurjchem-2544	1	51	-	-	SYM
eurjchem-2544	1	52	2257	2257	NUM
eurjchem-2544	1	53	(	(	PUNCT
eurjchem-2544	1	54	online	online	ADJ
eurjchem-2544	1	55	)	)	PUNCT
eurjchem-2544	1	56	–	–	PUNCT
eurjchem-2544	2	1	copyright	copyright	NOUN
eurjchem-2544	2	2	©	©	PROPN
eurjchem-2544	2	3	2024	2024	NUM
eurjchem-2544	2	4	the	the	DET
eurjchem-2544	2	5	authors	author	NOUN
eurjchem-2544	2	6	–	–	PUNCT
eurjchem-2544	2	7	atlanta	atlanta	PROPN
eurjchem-2544	2	8	publishing	publishing	PROPN
eurjchem-2544	2	9	house	house	PROPN
eurjchem-2544	2	10	llc	llc	PROPN
eurjchem-2544	2	11	–	–	PUNCT
eurjchem-2544	2	12	printed	print	VERB
eurjchem-2544	2	13	in	in	ADP
eurjchem-2544	2	14	the	the	DET
eurjchem-2544	2	15	usa	usa	PROPN
eurjchem-2544	2	16	.	.	PUNCT
eurjchem-2544	3	1	this	this	DET
eurjchem-2544	3	2	work	work	NOUN
eurjchem-2544	3	3	is	be	AUX
eurjchem-2544	3	4	published	publish	VERB
eurjchem-2544	3	5	and	and	CCONJ
eurjchem-2544	3	6	licensed	license	VERB
eurjchem-2544	3	7	by	by	ADP
eurjchem-2544	3	8	atlanta	atlanta	PROPN
eurjchem-2544	3	9	publishing	publishing	PROPN
eurjchem-2544	3	10	house	house	PROPN
eurjchem-2544	3	11	llc	llc	PROPN
eurjchem-2544	3	12	–	–	PUNCT
eurjchem-2544	3	13	cc	cc	PROPN
eurjchem-2544	3	14	by	by	ADP
eurjchem-2544	3	15	nc	nc	PROPN
eurjchem-2544	3	16	–	–	PUNCT
eurjchem-2544	3	17	some	some	DET
eurjchem-2544	3	18	rights	right	NOUN
eurjchem-2544	3	19	reserved	reserve	VERB
eurjchem-2544	3	20	.	.	PUNCT
eurjchem-2544	4	1	https://dx.doi.org/10.5155/eurjchem.15.3.291-301.2544	https://dx.doi.org/10.5155/eurjchem.15.3.291-301.2544	PROPN
eurjchem-2544	4	2	european	european	PROPN
eurjchem-2544	4	3	journal	journal	PROPN
eurjchem-2544	4	4	of	of	ADP
eurjchem-2544	4	5	chemistry	chemistry	NOUN
eurjchem-2544	4	6	view	view	NOUN
eurjchem-2544	4	7	journal	journal	PROPN
eurjchem-2544	4	8	online	online	PROPN
eurjchem-2544	4	9	view	view	NOUN
eurjchem-2544	4	10	article	article	NOUN
eurjchem-2544	4	11	online	online	NOUN
eurjchem-2544	4	12	single	single	ADJ
eurjchem-2544	4	13	and	and	CCONJ
eurjchem-2544	4	14	mixed	mixed	ADJ
eurjchem-2544	4	15	dithiocarbamato	dithiocarbamato	NOUN
eurjchem-2544	4	16	metal(iii	metal(iii	NOUN
eurjchem-2544	4	17	)	)	PUNCT
eurjchem-2544	4	18	complexes	complex	NOUN
eurjchem-2544	4	19	(	(	PUNCT
eurjchem-2544	4	20	co	co	NOUN
eurjchem-2544	4	21	,	,	PUNCT
eurjchem-2544	4	22	rh	rh	PROPN
eurjchem-2544	4	23	,	,	PUNCT
eurjchem-2544	4	24	and	and	CCONJ
eurjchem-2544	4	25	ir	ir	PROPN
eurjchem-2544	4	26	):	):	PUNCT
eurjchem-2544	4	27	crystal	crystal	NOUN
eurjchem-2544	4	28	and	and	CCONJ
eurjchem-2544	4	29	molecular	molecular	ADJ
eurjchem-2544	4	30	structure	structure	NOUN
eurjchem-2544	4	31	description	description	NOUN
eurjchem-2544	4	32	and	and	CCONJ
eurjchem-2544	4	33	interplay	interplay	NOUN
eurjchem-2544	4	34	ibukun	ibukun	NOUN
eurjchem-2544	4	35	oluwaseun	oluwaseun	PROPN
eurjchem-2544	4	36	shotonwa	shotonwa	ADJ
eurjchem-2544	4	37	1,2	1,2	NUM
eurjchem-2544	4	38	,	,	PUNCT
eurjchem-2544	4	39	*	*	PUNCT
eurjchem-2544	4	40	,	,	PUNCT
eurjchem-2544	4	41	adebayo	adebayo	PROPN
eurjchem-2544	4	42	ponle	ponle	PROPN
eurjchem-2544	4	43	oduwole	oduwole	PROPN
eurjchem-2544	4	44	1,2	1,2	NUM
eurjchem-2544	4	45	,	,	PUNCT
eurjchem-2544	4	46	oluwapelumi	oluwapelumi	PROPN
eurjchem-2544	4	47	martin	martin	PROPN
eurjchem-2544	4	48	agosu	agosu	PROPN
eurjchem-2544	4	49	1,2	1,2	NUM
eurjchem-2544	4	50	,	,	PUNCT
eurjchem-2544	4	51	abosede	abosede	NOUN
eurjchem-2544	4	52	funke	funke	PROPN
eurjchem-2544	4	53	yusuf	yusuf	PROPN
eurjchem-2544	4	54	3	3	NUM
eurjchem-2544	4	55	,	,	PUNCT
eurjchem-2544	4	56	and	and	CCONJ
eurjchem-2544	4	57	simeon	simeon	NOUN
eurjchem-2544	4	58	okechukwu	okechukwu	NOUN
eurjchem-2544	4	59	eze	eze	VERB
eurjchem-2544	4	60	4	4	NUM
eurjchem-2544	4	61	1	1	NUM
eurjchem-2544	4	62	inorganic	inorganic	ADJ
eurjchem-2544	4	63	division	division	NOUN
eurjchem-2544	4	64	,	,	PUNCT
eurjchem-2544	4	65	department	department	NOUN
eurjchem-2544	4	66	of	of	ADP
eurjchem-2544	4	67	chemistry	chemistry	NOUN
eurjchem-2544	4	68	,	,	PUNCT
eurjchem-2544	4	69	lagos	lagos	NOUN
eurjchem-2544	4	70	state	state	PROPN
eurjchem-2544	4	71	university	university	PROPN
eurjchem-2544	4	72	,	,	PUNCT
eurjchem-2544	4	73	ojo	ojo	NOUN
eurjchem-2544	4	74	,	,	PUNCT
eurjchem-2544	4	75	102101	102101	NUM
eurjchem-2544	4	76	,	,	PUNCT
eurjchem-2544	4	77	lagos	lago	NOUN
eurjchem-2544	4	78	,	,	PUNCT
eurjchem-2544	4	79	nigeria	nigeria	PROPN
eurjchem-2544	4	80	2	2	NUM
eurjchem-2544	4	81	physical	physical	ADJ
eurjchem-2544	4	82	and	and	CCONJ
eurjchem-2544	4	83	environmental	environmental	ADJ
eurjchem-2544	4	84	division	division	NOUN
eurjchem-2544	4	85	,	,	PUNCT
eurjchem-2544	4	86	department	department	NOUN
eurjchem-2544	4	87	of	of	ADP
eurjchem-2544	4	88	chemistry	chemistry	NOUN
eurjchem-2544	4	89	,	,	PUNCT
eurjchem-2544	4	90	lagos	lagos	NOUN
eurjchem-2544	4	91	state	state	PROPN
eurjchem-2544	4	92	university	university	PROPN
eurjchem-2544	4	93	,	,	PUNCT
eurjchem-2544	4	94	ojo	ojo	NOUN
eurjchem-2544	4	95	,	,	PUNCT
eurjchem-2544	4	96	102101	102101	NUM
eurjchem-2544	4	97	,	,	PUNCT
eurjchem-2544	4	98	lagos	lago	NOUN
eurjchem-2544	4	99	,	,	PUNCT
eurjchem-2544	4	100	nigeria	nigeria	PROPN
eurjchem-2544	4	101	3	3	NUM
eurjchem-2544	4	102	organic	organic	ADJ
eurjchem-2544	4	103	division	division	NOUN
eurjchem-2544	4	104	,	,	PUNCT
eurjchem-2544	4	105	department	department	NOUN
eurjchem-2544	4	106	of	of	ADP
eurjchem-2544	4	107	chemistry	chemistry	NOUN
eurjchem-2544	4	108	,	,	PUNCT
eurjchem-2544	4	109	lagos	lagos	NOUN
eurjchem-2544	4	110	state	state	PROPN
eurjchem-2544	4	111	university	university	PROPN
eurjchem-2544	4	112	,	,	PUNCT
eurjchem-2544	4	113	ojo	ojo	NOUN
eurjchem-2544	4	114	,	,	PUNCT
eurjchem-2544	4	115	102102	102102	NUM
eurjchem-2544	4	116	,	,	PUNCT
eurjchem-2544	4	117	lagos	lago	NOUN
eurjchem-2544	4	118	,	,	PUNCT
eurjchem-2544	4	119	nigeria	nigeria	PROPN
eurjchem-2544	4	120	4	4	NUM
eurjchem-2544	4	121	chemical	chemical	NOUN
eurjchem-2544	4	122	and	and	CCONJ
eurjchem-2544	4	123	petroleum	petroleum	NOUN
eurjchem-2544	4	124	engineering	engineering	NOUN
eurjchem-2544	4	125	,	,	PUNCT
eurjchem-2544	4	126	university	university	NOUN
eurjchem-2544	4	127	of	of	ADP
eurjchem-2544	4	128	lagos	lagos	PROPN
eurjchem-2544	4	129	,	,	PUNCT
eurjchem-2544	4	130	akoka	akoka	NOUN
eurjchem-2544	4	131	,	,	PUNCT
eurjchem-2544	4	132	yaba	yaba	PROPN
eurjchem-2544	4	133	,	,	PUNCT
eurjchem-2544	4	134	lagos	lagos	PROPN
eurjchem-2544	4	135	,	,	PUNCT
eurjchem-2544	4	136	nigeria	nigeria	PROPN
eurjchem-2544	4	137	*	*	PUNCT
eurjchem-2544	4	138	corresponding	correspond	VERB
eurjchem-2544	4	139	author	author	NOUN
eurjchem-2544	4	140	at	at	ADP
eurjchem-2544	4	141	:	:	PUNCT
eurjchem-2544	4	142	inorganic	inorganic	ADJ
eurjchem-2544	4	143	division	division	NOUN
eurjchem-2544	4	144	,	,	PUNCT
eurjchem-2544	4	145	department	department	NOUN
eurjchem-2544	4	146	of	of	ADP
eurjchem-2544	4	147	chemistry	chemistry	NOUN
eurjchem-2544	4	148	,	,	PUNCT
eurjchem-2544	4	149	lagos	lagos	NOUN
eurjchem-2544	4	150	state	state	PROPN
eurjchem-2544	4	151	university	university	PROPN
eurjchem-2544	4	152	,	,	PUNCT
eurjchem-2544	4	153	ojo	ojo	NOUN
eurjchem-2544	4	154	,	,	PUNCT
eurjchem-2544	4	155	102101	102101	NUM
eurjchem-2544	4	156	,	,	PUNCT
eurjchem-2544	4	157	lagos	lago	NOUN
eurjchem-2544	4	158	,	,	PUNCT
eurjchem-2544	4	159	nigeria	nigeria	PROPN
eurjchem-2544	4	160	.	.	PUNCT
eurjchem-2544	5	1	e	e	X
eurjchem-2544	5	2	-	-	NOUN
eurjchem-2544	5	3	mail	mail	NOUN
eurjchem-2544	5	4	:	:	PUNCT
eurjchem-2544	5	5	ibukun.shotonwa@lasu.edu.ng	ibukun.shotonwa@lasu.edu.ng	NOUN
eurjchem-2544	5	6	(	(	PUNCT
eurjchem-2544	5	7	i.o	i.o	PROPN
eurjchem-2544	5	8	.	.	PROPN
eurjchem-2544	5	9	shotonwa	shotonwa	PROPN
eurjchem-2544	5	10	)	)	PUNCT
eurjchem-2544	5	11	.	.	PUNCT
eurjchem-2544	6	1	10.5155	10.5155	NUM
eurjchem-2544	6	2	/	/	SYM
eurjchem-2544	6	3	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	6	4	-	-	PUNCT
eurjchem-2544	6	5	301.2544	301.2544	NUM
eurjchem-2544	6	6	received	receive	VERB
eurjchem-2544	6	7	:	:	PUNCT
eurjchem-2544	6	8	03	03	NUM
eurjchem-2544	6	9	march	march	NOUN
eurjchem-2544	6	10	2024	2024	NUM
eurjchem-2544	6	11	received	receive	VERB
eurjchem-2544	6	12	in	in	ADP
eurjchem-2544	6	13	revised	revise	VERB
eurjchem-2544	6	14	form	form	NOUN
eurjchem-2544	6	15	:	:	PUNCT
eurjchem-2544	6	16	11	11	NUM
eurjchem-2544	6	17	may	may	AUX
eurjchem-2544	6	18	2024	2024	NUM
eurjchem-2544	6	19	accepted	accept	VERB
eurjchem-2544	6	20	:	:	PUNCT
eurjchem-2544	6	21	12	12	NUM
eurjchem-2544	6	22	june	june	PROPN
eurjchem-2544	6	23	2024	2024	NUM
eurjchem-2544	6	24	published	publish	VERB
eurjchem-2544	6	25	online	online	ADV
eurjchem-2544	6	26	:	:	PUNCT
eurjchem-2544	6	27	30	30	NUM
eurjchem-2544	6	28	september	september	PROPN
eurjchem-2544	6	29	2024	2024	NUM
eurjchem-2544	6	30	printed	print	VERB
eurjchem-2544	6	31	:	:	PUNCT
eurjchem-2544	6	32	30	30	NUM
eurjchem-2544	6	33	september	september	PROPN
eurjchem-2544	6	34	2024	2024	NUM
eurjchem-2544	6	35	this	this	DET
eurjchem-2544	6	36	review	review	NOUN
eurjchem-2544	6	37	focuses	focus	VERB
eurjchem-2544	6	38	on	on	ADP
eurjchem-2544	6	39	the	the	DET
eurjchem-2544	6	40	crystal	crystal	NOUN
eurjchem-2544	6	41	and	and	CCONJ
eurjchem-2544	6	42	molecular	molecular	ADJ
eurjchem-2544	6	43	structures	structure	NOUN
eurjchem-2544	6	44	of	of	ADP
eurjchem-2544	6	45	single	single	ADJ
eurjchem-2544	6	46	and	and	CCONJ
eurjchem-2544	6	47	mixed	mixed	ADJ
eurjchem-2544	6	48	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	6	49	ligands	ligand	NOUN
eurjchem-2544	6	50	of	of	ADP
eurjchem-2544	6	51	cobalt	cobalt	NOUN
eurjchem-2544	6	52	,	,	PUNCT
eurjchem-2544	6	53	rhodium	rhodium	NOUN
eurjchem-2544	6	54	,	,	PUNCT
eurjchem-2544	6	55	and	and	CCONJ
eurjchem-2544	6	56	iridium	iridium	NOUN
eurjchem-2544	6	57	in	in	ADP
eurjchem-2544	6	58	the	the	DET
eurjchem-2544	6	59	+3	+3	PROPN
eurjchem-2544	6	60	oxidation	oxidation	NOUN
eurjchem-2544	6	61	state	state	NOUN
eurjchem-2544	6	62	.	.	PUNCT
eurjchem-2544	7	1	the	the	DET
eurjchem-2544	7	2	complexities	complexity	NOUN
eurjchem-2544	7	3	of	of	ADP
eurjchem-2544	7	4	their	their	PRON
eurjchem-2544	7	5	chelating	chelating	NOUN
eurjchem-2544	7	6	and	and	CCONJ
eurjchem-2544	7	7	bridging	bridging	NOUN
eurjchem-2544	7	8	modes	mode	NOUN
eurjchem-2544	7	9	come	come	VERB
eurjchem-2544	7	10	into	into	ADP
eurjchem-2544	7	11	play	play	NOUN
eurjchem-2544	7	12	through	through	ADP
eurjchem-2544	7	13	modification	modification	NOUN
eurjchem-2544	7	14	of	of	ADP
eurjchem-2544	7	15	the	the	DET
eurjchem-2544	7	16	substituents	substituent	NOUN
eurjchem-2544	7	17	on	on	ADP
eurjchem-2544	7	18	the	the	DET
eurjchem-2544	7	19	carbamate	carbamate	NOUN
eurjchem-2544	7	20	nitrogen	nitrogen	NOUN
eurjchem-2544	7	21	atoms	atom	NOUN
eurjchem-2544	7	22	of	of	ADP
eurjchem-2544	7	23	the	the	DET
eurjchem-2544	7	24	ligands	ligand	NOUN
eurjchem-2544	7	25	and	and	CCONJ
eurjchem-2544	7	26	additional	additional	ADJ
eurjchem-2544	7	27	coordination	coordination	NOUN
eurjchem-2544	7	28	of	of	ADP
eurjchem-2544	7	29	secondary	secondary	ADJ
eurjchem-2544	7	30	phosphino	phosphino	NOUN
eurjchem-2544	7	31	-	-	PUNCT
eurjchem-2544	7	32	containing	contain	VERB
eurjchem-2544	7	33	ligands	ligand	NOUN
eurjchem-2544	7	34	,	,	PUNCT
eurjchem-2544	7	35	culminating	culminate	VERB
eurjchem-2544	7	36	in	in	ADP
eurjchem-2544	7	37	various	various	ADJ
eurjchem-2544	7	38	applications	application	NOUN
eurjchem-2544	7	39	such	such	ADJ
eurjchem-2544	7	40	as	as	ADP
eurjchem-2544	7	41	biological	biological	ADJ
eurjchem-2544	7	42	,	,	PUNCT
eurjchem-2544	7	43	analytical	analytical	ADJ
eurjchem-2544	7	44	,	,	PUNCT
eurjchem-2544	7	45	medicine	medicine	NOUN
eurjchem-2544	7	46	,	,	PUNCT
eurjchem-2544	7	47	and	and	CCONJ
eurjchem-2544	7	48	catalysis	catalysis	NOUN
eurjchem-2544	7	49	.	.	PUNCT
eurjchem-2544	8	1	other	other	ADJ
eurjchem-2544	8	2	considerations	consideration	NOUN
eurjchem-2544	8	3	include	include	VERB
eurjchem-2544	8	4	the	the	DET
eurjchem-2544	8	5	geometrical	geometrical	ADJ
eurjchem-2544	8	6	coordination	coordination	NOUN
eurjchem-2544	8	7	environments	environment	NOUN
eurjchem-2544	8	8	around	around	ADP
eurjchem-2544	8	9	the	the	DET
eurjchem-2544	8	10	metal	metal	NOUN
eurjchem-2544	8	11	centres	centre	NOUN
eurjchem-2544	8	12	and	and	CCONJ
eurjchem-2544	8	13	their	their	PRON
eurjchem-2544	8	14	comparison	comparison	NOUN
eurjchem-2544	8	15	with	with	ADP
eurjchem-2544	8	16	isostructural	isostructural	ADJ
eurjchem-2544	8	17	congeners	congener	NOUN
eurjchem-2544	8	18	.	.	PUNCT
eurjchem-2544	9	1	the	the	DET
eurjchem-2544	9	2	distortions	distortion	NOUN
eurjchem-2544	9	3	around	around	ADP
eurjchem-2544	9	4	the	the	DET
eurjchem-2544	9	5	metal	metal	NOUN
eurjchem-2544	9	6	centres	centre	NOUN
eurjchem-2544	9	7	and	and	CCONJ
eurjchem-2544	9	8	their	their	PRON
eurjchem-2544	9	9	subsequent	subsequent	ADJ
eurjchem-2544	9	10	effects	effect	NOUN
eurjchem-2544	9	11	on	on	ADP
eurjchem-2544	9	12	the	the	DET
eurjchem-2544	9	13	symmetries	symmetry	NOUN
eurjchem-2544	9	14	of	of	ADP
eurjchem-2544	9	15	bonds	bond	NOUN
eurjchem-2544	9	16	in	in	ADP
eurjchem-2544	9	17	the	the	DET
eurjchem-2544	9	18	primary	primary	ADJ
eurjchem-2544	9	19	and	and	CCONJ
eurjchem-2544	9	20	secondary	secondary	ADJ
eurjchem-2544	9	21	coordination	coordination	NOUN
eurjchem-2544	9	22	spheres	sphere	NOUN
eurjchem-2544	9	23	are	be	AUX
eurjchem-2544	9	24	discussed	discuss	VERB
eurjchem-2544	9	25	.	.	PUNCT
eurjchem-2544	10	1	the	the	DET
eurjchem-2544	10	2	trans	tran	NOUN
eurjchem-2544	10	3	-	-	NOUN
eurjchem-2544	10	4	effects	effect	NOUN
eurjchem-2544	10	5	of	of	ADP
eurjchem-2544	10	6	secondary	secondary	ADJ
eurjchem-2544	10	7	p	p	NOUN
eurjchem-2544	10	8	-	-	PUNCT
eurjchem-2544	10	9	ligands	ligand	NOUN
eurjchem-2544	10	10	and	and	CCONJ
eurjchem-2544	10	11	their	their	PRON
eurjchem-2544	10	12	effects	effect	NOUN
eurjchem-2544	10	13	on	on	ADP
eurjchem-2544	10	14	geometrical	geometrical	ADJ
eurjchem-2544	10	15	alignment	alignment	NOUN
eurjchem-2544	10	16	and	and	CCONJ
eurjchem-2544	10	17	structural	structural	ADJ
eurjchem-2544	10	18	stability	stability	NOUN
eurjchem-2544	10	19	have	have	AUX
eurjchem-2544	10	20	become	become	VERB
eurjchem-2544	10	21	valuable	valuable	ADJ
eurjchem-2544	10	22	yardsticks	yardstick	NOUN
eurjchem-2544	10	23	in	in	ADP
eurjchem-2544	10	24	analyzing	analyze	VERB
eurjchem-2544	10	25	structural	structural	ADJ
eurjchem-2544	10	26	modifications	modification	NOUN
eurjchem-2544	10	27	and	and	CCONJ
eurjchem-2544	10	28	stabilities	stability	NOUN
eurjchem-2544	10	29	.	.	PUNCT
eurjchem-2544	11	1	trans	tran	NOUN
eurjchem-2544	11	2	effects	effect	NOUN
eurjchem-2544	11	3	bridging	bridge	VERB
eurjchem-2544	11	4	ligands	ligand	NOUN
eurjchem-2544	11	5	oxidation	oxidation	NOUN
eurjchem-2544	11	6	states	state	NOUN
eurjchem-2544	11	7	crystal	crystal	NOUN
eurjchem-2544	11	8	structure	structure	NOUN
eurjchem-2544	11	9	dithiocarbamates	dithiocarbamate	VERB
eurjchem-2544	11	10	coordination	coordination	NOUN
eurjchem-2544	11	11	chemistry	chemistry	NOUN
eurjchem-2544	11	12	cite	cite	VERB
eurjchem-2544	11	13	this	this	PRON
eurjchem-2544	11	14	:	:	PUNCT
eurjchem-2544	11	15	eur	eur	PROPN
eurjchem-2544	11	16	.	.	PUNCT
eurjchem-2544	12	1	j.	j.	PROPN
eurjchem-2544	12	2	chem	chem	PROPN
eurjchem-2544	12	3	.	.	PUNCT
eurjchem-2544	13	1	2024	2024	NUM
eurjchem-2544	13	2	,	,	PUNCT
eurjchem-2544	13	3	15(3	15(3	NUM
eurjchem-2544	13	4	)	)	PUNCT
eurjchem-2544	13	5	,	,	PUNCT
eurjchem-2544	13	6	291	291	NUM
eurjchem-2544	13	7	-	-	SYM
eurjchem-2544	13	8	301	301	NUM
eurjchem-2544	13	9	journal	journal	NOUN
eurjchem-2544	13	10	website	website	NOUN
eurjchem-2544	13	11	:	:	PUNCT
eurjchem-2544	13	12	www.eurjchem.com	www.eurjchem.com	X
eurjchem-2544	13	13	1	1	X
eurjchem-2544	13	14	.	.	PUNCT
eurjchem-2544	13	15	introduction	introduction	NOUN
eurjchem-2544	13	16	the	the	DET
eurjchem-2544	13	17	m	m	NOUN
eurjchem-2544	13	18	-	-	PUNCT
eurjchem-2544	13	19	s2cnr2	s2cnr2	NOUN
eurjchem-2544	13	20	core	core	NOUN
eurjchem-2544	13	21	in	in	ADP
eurjchem-2544	13	22	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	13	23	chemistry	chemistry	NOUN
eurjchem-2544	13	24	has	have	AUX
eurjchem-2544	13	25	proved	prove	VERB
eurjchem-2544	13	26	to	to	PART
eurjchem-2544	13	27	be	be	AUX
eurjchem-2544	13	28	of	of	ADP
eurjchem-2544	13	29	great	great	ADJ
eurjchem-2544	13	30	use	use	NOUN
eurjchem-2544	13	31	to	to	PART
eurjchem-2544	13	32	synthetic	synthetic	VERB
eurjchem-2544	13	33	and	and	CCONJ
eurjchem-2544	13	34	structural	structural	ADJ
eurjchem-2544	13	35	scientists	scientist	NOUN
eurjchem-2544	13	36	because	because	SCONJ
eurjchem-2544	13	37	of	of	ADP
eurjchem-2544	13	38	the	the	DET
eurjchem-2544	13	39	possibility	possibility	NOUN
eurjchem-2544	13	40	of	of	ADP
eurjchem-2544	13	41	modifying	modify	VERB
eurjchem-2544	13	42	the	the	DET
eurjchem-2544	13	43	r	r	NOUN
eurjchem-2544	13	44	and	and	CCONJ
eurjchem-2544	13	45	r	r	NOUN
eurjchem-2544	13	46	’	'	PUNCT
eurjchem-2544	13	47	substituents	substituent	NOUN
eurjchem-2544	13	48	in	in	ADP
eurjchem-2544	13	49	the	the	DET
eurjchem-2544	13	50	backbone	backbone	NOUN
eurjchem-2544	13	51	of	of	ADP
eurjchem-2544	13	52	the	the	DET
eurjchem-2544	13	53	stable	stable	ADJ
eurjchem-2544	13	54	ligand	ligand	NOUN
eurjchem-2544	13	55	framework	framework	NOUN
eurjchem-2544	13	56	(	(	PUNCT
eurjchem-2544	13	57	scheme	scheme	NOUN
eurjchem-2544	13	58	1	1	NUM
eurjchem-2544	13	59	)	)	PUNCT
eurjchem-2544	13	60	.	.	PUNCT
eurjchem-2544	14	1	modification	modification	NOUN
eurjchem-2544	14	2	of	of	ADP
eurjchem-2544	14	3	organic	organic	ADJ
eurjchem-2544	14	4	substituents	substituent	NOUN
eurjchem-2544	14	5	allows	allow	VERB
eurjchem-2544	14	6	fine	fine	ADV
eurjchem-2544	14	7	-	-	PUNCT
eurjchem-2544	14	8	tuning	tuning	NOUN
eurjchem-2544	14	9	of	of	ADP
eurjchem-2544	14	10	the	the	DET
eurjchem-2544	14	11	chemical	chemical	NOUN
eurjchem-2544	14	12	properties	property	NOUN
eurjchem-2544	14	13	of	of	ADP
eurjchem-2544	14	14	complexes	complex	NOUN
eurjchem-2544	14	15	that	that	PRON
eurjchem-2544	14	16	are	be	AUX
eurjchem-2544	14	17	fast	fast	ADV
eurjchem-2544	14	18	becoming	become	VERB
eurjchem-2544	14	19	commonplace	commonplace	ADJ
eurjchem-2544	14	20	[	[	X
eurjchem-2544	14	21	1	1	NUM
eurjchem-2544	14	22	]	]	PUNCT
eurjchem-2544	14	23	.	.	PUNCT
eurjchem-2544	15	1	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	15	2	and	and	CCONJ
eurjchem-2544	15	3	their	their	PRON
eurjchem-2544	15	4	derivatives	derivative	NOUN
eurjchem-2544	15	5	are	be	AUX
eurjchem-2544	15	6	versatile	versatile	ADJ
eurjchem-2544	15	7	chelating	chelating	NOUN
eurjchem-2544	15	8	compounds	compound	NOUN
eurjchem-2544	15	9	through	through	ADP
eurjchem-2544	15	10	their	their	PRON
eurjchem-2544	15	11	sulfur	sulfur	NOUN
eurjchem-2544	15	12	atoms	atom	NOUN
eurjchem-2544	15	13	,	,	PUNCT
eurjchem-2544	15	14	resulting	result	VERB
eurjchem-2544	15	15	in	in	ADP
eurjchem-2544	15	16	central	central	ADJ
eurjchem-2544	15	17	metal	metal	NOUN
eurjchem-2544	15	18	ions	ion	NOUN
eurjchem-2544	15	19	that	that	PRON
eurjchem-2544	15	20	are	be	AUX
eurjchem-2544	15	21	tetracoordinated	tetracoordinate	VERB
eurjchem-2544	15	22	(	(	PUNCT
eurjchem-2544	15	23	square	square	ADJ
eurjchem-2544	15	24	planar	planar	ADJ
eurjchem-2544	15	25	or	or	CCONJ
eurjchem-2544	15	26	tetrahedral	tetrahedral	ADJ
eurjchem-2544	15	27	)	)	PUNCT
eurjchem-2544	15	28	,	,	PUNCT
eurjchem-2544	15	29	penta	penta	NOUN
eurjchem-2544	15	30	-	-	PUNCT
eurjchem-2544	15	31	coordinated	coordinate	VERB
eurjchem-2544	15	32	,	,	PUNCT
eurjchem-2544	15	33	sometimes	sometimes	ADV
eurjchem-2544	15	34	due	due	ADJ
eurjchem-2544	15	35	to	to	ADP
eurjchem-2544	15	36	dimerization	dimerization	NOUN
eurjchem-2544	15	37	,	,	PUNCT
eurjchem-2544	15	38	or	or	CCONJ
eurjchem-2544	15	39	hexa	hexa	NOUN
eurjchem-2544	15	40	-	-	PUNCT
eurjchem-2544	15	41	coordinated	coordinate	VERB
eurjchem-2544	15	42	in	in	ADP
eurjchem-2544	15	43	a	a	DET
eurjchem-2544	15	44	regular	regular	ADJ
eurjchem-2544	15	45	or	or	CCONJ
eurjchem-2544	15	46	distorted	distorted	ADJ
eurjchem-2544	15	47	fashion	fashion	NOUN
eurjchem-2544	15	48	[	[	X
eurjchem-2544	15	49	2,8	2,8	NUM
eurjchem-2544	15	50	]	]	PUNCT
eurjchem-2544	15	51	.	.	PUNCT
eurjchem-2544	16	1	interestingly	interestingly	ADV
eurjchem-2544	16	2	,	,	PUNCT
eurjchem-2544	16	3	the	the	DET
eurjchem-2544	16	4	introduction	introduction	NOUN
eurjchem-2544	16	5	of	of	ADP
eurjchem-2544	16	6	secondary	secondary	ADJ
eurjchem-2544	16	7	ligands	ligand	NOUN
eurjchem-2544	16	8	along	along	ADP
eurjchem-2544	16	9	with	with	ADP
eurjchem-2544	16	10	auxiliary	auxiliary	ADJ
eurjchem-2544	16	11	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	16	12	anions	anion	NOUN
eurjchem-2544	16	13	results	result	NOUN
eurjchem-2544	16	14	in	in	ADP
eurjchem-2544	16	15	bridges	bridge	NOUN
eurjchem-2544	16	16	that	that	PRON
eurjchem-2544	16	17	invariably	invariably	ADV
eurjchem-2544	16	18	modify	modify	VERB
eurjchem-2544	16	19	the	the	DET
eurjchem-2544	16	20	entire	entire	ADJ
eurjchem-2544	16	21	coordination	coordination	NOUN
eurjchem-2544	16	22	sphere	sphere	ADV
eurjchem-2544	16	23	through	through	ADP
eurjchem-2544	16	24	substantial	substantial	ADJ
eurjchem-2544	16	25	labilization	labilization	NOUN
eurjchem-2544	16	26	to	to	PART
eurjchem-2544	16	27	form	form	VERB
eurjchem-2544	16	28	novel	novel	ADJ
eurjchem-2544	16	29	products	product	NOUN
eurjchem-2544	16	30	[	[	X
eurjchem-2544	16	31	3	3	NUM
eurjchem-2544	16	32	-	-	SYM
eurjchem-2544	16	33	5	5	NUM
eurjchem-2544	16	34	]	]	PUNCT
eurjchem-2544	16	35	.	.	PUNCT
eurjchem-2544	17	1	for	for	ADP
eurjchem-2544	17	2	example	example	NOUN
eurjchem-2544	17	3	,	,	PUNCT
eurjchem-2544	17	4	mixed	mixed	ADJ
eurjchem-2544	17	5	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	17	6	ligands	ligand	NOUN
eurjchem-2544	17	7	and	and	CCONJ
eurjchem-2544	17	8	other	other	ADJ
eurjchem-2544	17	9	notable	notable	ADJ
eurjchem-2544	17	10	p	p	NOUN
eurjchem-2544	17	11	ligands	ligand	NOUN
eurjchem-2544	17	12	,	,	PUNCT
eurjchem-2544	17	13	such	such	ADJ
eurjchem-2544	17	14	as	as	ADP
eurjchem-2544	17	15	phosphines	phosphine	NOUN
eurjchem-2544	17	16	,	,	PUNCT
eurjchem-2544	17	17	phosphinites	phosphinite	NOUN
eurjchem-2544	17	18	,	,	PUNCT
eurjchem-2544	17	19	phosphornites	phosphornite	NOUN
eurjchem-2544	17	20	,	,	PUNCT
eurjchem-2544	17	21	and	and	CCONJ
eurjchem-2544	17	22	phosphites	phosphite	NOUN
eurjchem-2544	17	23	[	[	X
eurjchem-2544	17	24	6	6	NUM
eurjchem-2544	17	25	]	]	PUNCT
eurjchem-2544	17	26	have	have	AUX
eurjchem-2544	17	27	been	be	AUX
eurjchem-2544	17	28	reported	report	VERB
eurjchem-2544	17	29	to	to	PART
eurjchem-2544	17	30	be	be	AUX
eurjchem-2544	17	31	modifiers	modifier	NOUN
eurjchem-2544	17	32	of	of	ADP
eurjchem-2544	17	33	the	the	DET
eurjchem-2544	17	34	underlying	underlie	VERB
eurjchem-2544	17	35	properties	property	NOUN
eurjchem-2544	17	36	of	of	ADP
eurjchem-2544	17	37	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	17	38	complexes	complex	NOUN
eurjchem-2544	17	39	as	as	SCONJ
eurjchem-2544	17	40	revealed	reveal	VERB
eurjchem-2544	17	41	by	by	ADP
eurjchem-2544	17	42	characterization	characterization	NOUN
eurjchem-2544	17	43	through	through	ADP
eurjchem-2544	17	44	x	x	ADJ
eurjchem-2544	17	45	-	-	NOUN
eurjchem-2544	17	46	ray	ray	NOUN
eurjchem-2544	17	47	diffraction	diffraction	NOUN
eurjchem-2544	17	48	studies	study	NOUN
eurjchem-2544	17	49	[	[	X
eurjchem-2544	17	50	5	5	NUM
eurjchem-2544	17	51	]	]	PUNCT
eurjchem-2544	17	52	.	.	PUNCT
eurjchem-2544	18	1	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	18	2	have	have	AUX
eurjchem-2544	18	3	been	be	AUX
eurjchem-2544	18	4	reported	report	VERB
eurjchem-2544	18	5	to	to	PART
eurjchem-2544	18	6	be	be	AUX
eurjchem-2544	18	7	reliable	reliable	ADJ
eurjchem-2544	18	8	auxiliary	auxiliary	ADJ
eurjchem-2544	18	9	ligands	ligand	NOUN
eurjchem-2544	18	10	with	with	ADP
eurjchem-2544	18	11	a	a	DET
eurjchem-2544	18	12	very	very	ADV
eurjchem-2544	18	13	strong	strong	ADJ
eurjchem-2544	18	14	tendency	tendency	NOUN
eurjchem-2544	18	15	to	to	PART
eurjchem-2544	18	16	stabilize	stabilize	VERB
eurjchem-2544	18	17	co(iii)-p	co(iii)-p	NOUN
eurjchem-2544	18	18	bonds	bond	NOUN
eurjchem-2544	18	19	[	[	X
eurjchem-2544	18	20	4	4	NUM
eurjchem-2544	18	21	]	]	PUNCT
eurjchem-2544	18	22	.	.	PUNCT
eurjchem-2544	19	1	moreover	moreover	ADV
eurjchem-2544	19	2	,	,	PUNCT
eurjchem-2544	19	3	the	the	DET
eurjchem-2544	19	4	supramolecular	supramolecular	ADJ
eurjchem-2544	19	5	chemistry	chemistry	NOUN
eurjchem-2544	19	6	of	of	ADP
eurjchem-2544	19	7	hydrogen	hydrogen	NOUN
eurjchem-2544	19	8	bonding	bonding	NOUN
eurjchem-2544	19	9	o···h	o···h	NOUN
eurjchem-2544	19	10	-	-	PUNCT
eurjchem-2544	19	11	p	p	NOUN
eurjchem-2544	19	12	and	and	CCONJ
eurjchem-2544	19	13	agnostic	agnostic	ADJ
eurjchem-2544	19	14	m···h	m···h	PROPN
eurjchem-2544	19	15	-	-	PUNCT
eurjchem-2544	19	16	p	p	NOUN
eurjchem-2544	19	17	interactions	interaction	NOUN
eurjchem-2544	19	18	are	be	AUX
eurjchem-2544	19	19	borne	bear	VERB
eurjchem-2544	19	20	out	out	ADP
eurjchem-2544	19	21	of	of	ADP
eurjchem-2544	19	22	the	the	DET
eurjchem-2544	19	23	stable	stable	ADJ
eurjchem-2544	19	24	mononuclear	mononuclear	ADJ
eurjchem-2544	19	25	secondary	secondary	ADJ
eurjchem-2544	19	26	phosphine	phosphine	NOUN
eurjchem-2544	19	27	complexes	complex	NOUN
eurjchem-2544	19	28	.	.	PUNCT
eurjchem-2544	20	1	these	these	DET
eurjchem-2544	20	2	complexes	complex	NOUN
eurjchem-2544	20	3	also	also	ADV
eurjchem-2544	20	4	provide	provide	VERB
eurjchem-2544	20	5	rational	rational	ADJ
eurjchem-2544	20	6	synthetic	synthetic	ADJ
eurjchem-2544	20	7	pathways	pathway	NOUN
eurjchem-2544	20	8	for	for	ADP
eurjchem-2544	20	9	heterometallic	heterometallic	ADJ
eurjchem-2544	20	10	and	and	CCONJ
eurjchem-2544	20	11	homometallic	homometallic	ADJ
eurjchem-2544	20	12	phosphidebridged	phosphidebridge	VERB
eurjchem-2544	20	13	dior	dior	PROPN
eurjchem-2544	20	14	polynuclear	polynuclear	NOUN
eurjchem-2544	20	15	complexes	complex	NOUN
eurjchem-2544	20	16	;	;	PUNCT
eurjchem-2544	20	17	a	a	DET
eurjchem-2544	20	18	feat	feat	NOUN
eurjchem-2544	20	19	attained	attain	VERB
eurjchem-2544	20	20	by	by	ADP
eurjchem-2544	20	21	the	the	DET
eurjchem-2544	20	22	deprotonation	deprotonation	NOUN
eurjchem-2544	20	23	of	of	ADP
eurjchem-2544	20	24	the	the	DET
eurjchem-2544	20	25	phosphor	phosphor	NOUN
eurjchem-2544	20	26	ligands	ligand	NOUN
eurjchem-2544	20	27	by	by	ADP
eurjchem-2544	20	28	coordination	coordination	NOUN
eurjchem-2544	20	29	[	[	X
eurjchem-2544	20	30	7	7	NUM
eurjchem-2544	20	31	]	]	PUNCT
eurjchem-2544	20	32	.	.	PUNCT
eurjchem-2544	21	1	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	21	2	in	in	ADP
eurjchem-2544	21	3	their	their	PRON
eurjchem-2544	21	4	single	single	ADJ
eurjchem-2544	21	5	and	and	CCONJ
eurjchem-2544	21	6	mixed	mixed	ADJ
eurjchem-2544	21	7	forms	form	NOUN
eurjchem-2544	21	8	are	be	AUX
eurjchem-2544	21	9	quite	quite	ADV
eurjchem-2544	21	10	versatile	versatile	ADJ
eurjchem-2544	21	11	.	.	PUNCT
eurjchem-2544	22	1	they	they	PRON
eurjchem-2544	22	2	have	have	AUX
eurjchem-2544	22	3	been	be	AUX
eurjchem-2544	22	4	used	use	VERB
eurjchem-2544	22	5	in	in	ADP
eurjchem-2544	22	6	the	the	DET
eurjchem-2544	22	7	treatment	treatment	NOUN
eurjchem-2544	22	8	of	of	ADP
eurjchem-2544	22	9	sarcoma	sarcoma	NOUN
eurjchem-2544	22	10	cells	cell	NOUN
eurjchem-2544	22	11	and	and	CCONJ
eurjchem-2544	22	12	alcoholism	alcoholism	NOUN
eurjchem-2544	22	13	[	[	X
eurjchem-2544	22	14	8	8	NUM
eurjchem-2544	22	15	]	]	PUNCT
eurjchem-2544	22	16	;	;	PUNCT
eurjchem-2544	22	17	a	a	DET
eurjchem-2544	22	18	feat	feat	NOUN
eurjchem-2544	22	19	that	that	PRON
eurjchem-2544	22	20	has	have	AUX
eurjchem-2544	22	21	brought	bring	VERB
eurjchem-2544	22	22	diethyldithiocarbamate	diethyldithiocarbamate	NOUN
eurjchem-2544	22	23	to	to	ADP
eurjchem-2544	22	24	the	the	DET
eurjchem-2544	22	25	scientific	scientific	ADJ
eurjchem-2544	22	26	limelight	limelight	NOUN
eurjchem-2544	22	27	as	as	ADP
eurjchem-2544	22	28	the	the	DET
eurjchem-2544	22	29	active	active	ADJ
eurjchem-2544	22	30	metabolite	metabolite	NOUN
eurjchem-2544	22	31	of	of	ADP
eurjchem-2544	22	32	disulfiram	disulfiram	NOUN
eurjchem-2544	22	33	,	,	PUNCT
eurjchem-2544	22	34	an	an	DET
eurjchem-2544	22	35	anti	anti	ADJ
eurjchem-2544	22	36	-	-	ADJ
eurjchem-2544	22	37	alcoholic	alcoholic	ADJ
eurjchem-2544	22	38	drug	drug	NOUN
eurjchem-2544	22	39	[	[	X
eurjchem-2544	22	40	9	9	NUM
eurjchem-2544	22	41	]	]	PUNCT
eurjchem-2544	22	42	.	.	PUNCT
eurjchem-2544	23	1	the	the	DET
eurjchem-2544	23	2	drug	drug	NOUN
eurjchem-2544	23	3	therapy	therapy	NOUN
eurjchem-2544	23	4	potentials	potential	NOUN
eurjchem-2544	23	5	of	of	ADP
eurjchem-2544	23	6	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	23	7	were	be	AUX
eurjchem-2544	23	8	identified	identify	VERB
eurjchem-2544	23	9	by	by	ADP
eurjchem-2544	23	10	their	their	PRON
eurjchem-2544	23	11	ability	ability	NOUN
eurjchem-2544	23	12	to	to	PART
eurjchem-2544	23	13	form	form	VERB
eurjchem-2544	23	14	chelates	chelate	NOUN
eurjchem-2544	23	15	with	with	ADP
eurjchem-2544	23	16	virtually	virtually	ADV
eurjchem-2544	23	17	all	all	PRON
eurjchem-2544	23	18	metals	metal	NOUN
eurjchem-2544	23	19	and	and	CCONJ
eurjchem-2544	23	20	their	their	PRON
eurjchem-2544	23	21	strong	strong	ADJ
eurjchem-2544	23	22	affinity	affinity	NOUN
eurjchem-2544	23	23	for	for	ADP
eurjchem-2544	23	24	human	human	ADJ
eurjchem-2544	23	25	and	and	CCONJ
eurjchem-2544	23	26	enzyme	enzyme	NOUN
eurjchem-2544	23	27	-	-	PUNCT
eurjchem-2544	23	28	based	base	VERB
eurjchem-2544	23	29	thiol	thiol	ADJ
eurjchem-2544	23	30	groups	group	NOUN
eurjchem-2544	23	31	[	[	X
eurjchem-2544	23	32	9	9	NUM
eurjchem-2544	23	33	]	]	PUNCT
eurjchem-2544	23	34	.	.	PUNCT
eurjchem-2544	24	1	abstract	abstract	ADJ
eurjchem-2544	24	2	review	review	NOUN
eurjchem-2544	24	3	article	article	NOUN
eurjchem-2544	24	4	keywords	keyword	VERB
eurjchem-2544	24	5	https://dx.doi.org/10.5155/eurjchem.15.3.291-301.2544	https://dx.doi.org/10.5155/eurjchem.15.3.291-301.2544	PROPN
eurjchem-2544	24	6	https://www.eurjchem.com/	https://www.eurjchem.com/	NOUN
eurjchem-2544	24	7	https://dx.doi.org/10.5155/eurjchem.15.3.291-301.2544	https://dx.doi.org/10.5155/eurjchem.15.3.291-301.2544	PROPN
eurjchem-2544	24	8	mailto:ibukun.shotonwa@lasu.edu.ng	mailto:ibukun.shotonwa@lasu.edu.ng	PROPN
eurjchem-2544	24	9	http://www.eurjchem.com/	http://www.eurjchem.com/	NOUN
eurjchem-2544	24	10	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.15.3.291-301.2544&domain=pdf&date_stamp=2024-09-30	https://crossmark.crossref.org/dialog/?doi=10.5155/eurjchem.15.3.291-301.2544&domain=pdf&date_stamp=2024-09-30	NOUN
eurjchem-2544	24	11	292	292	NUM
eurjchem-2544	24	12	shotonwa	shotonwa	ADJ
eurjchem-2544	24	13	et	et	PROPN
eurjchem-2544	24	14	al	al	PROPN
eurjchem-2544	24	15	.	.	PUNCT
eurjchem-2544	24	16	/	/	SYM
eurjchem-2544	24	17	european	european	PROPN
eurjchem-2544	24	18	journal	journal	PROPN
eurjchem-2544	24	19	of	of	ADP
eurjchem-2544	24	20	chemistry	chemistry	NOUN
eurjchem-2544	24	21	15	15	NUM
eurjchem-2544	24	22	(	(	PUNCT
eurjchem-2544	24	23	3	3	NUM
eurjchem-2544	24	24	)	)	PUNCT
eurjchem-2544	24	25	(	(	PUNCT
eurjchem-2544	24	26	2024	2024	NUM
eurjchem-2544	24	27	)	)	PUNCT
eurjchem-2544	24	28	291	291	NUM
eurjchem-2544	24	29	-	-	SYM
eurjchem-2544	24	30	301	301	NUM
eurjchem-2544	24	31	2024	2024	NUM
eurjchem-2544	24	32	–	–	PUNCT
eurjchem-2544	24	33	european	european	ADJ
eurjchem-2544	24	34	journal	journal	NOUN
eurjchem-2544	24	35	of	of	ADP
eurjchem-2544	24	36	chemistry	chemistry	NOUN
eurjchem-2544	24	37	–	–	PUNCT
eurjchem-2544	24	38	cc	cc	NOUN
eurjchem-2544	24	39	by	by	ADP
eurjchem-2544	24	40	nc	nc	PROPN
eurjchem-2544	24	41	–	–	PUNCT
eurjchem-2544	24	42	doi	doi	PROPN
eurjchem-2544	24	43	:	:	PUNCT
eurjchem-2544	24	44	10.5155	10.5155	NUM
eurjchem-2544	24	45	/	/	SYM
eurjchem-2544	24	46	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	24	47	-	-	PUNCT
eurjchem-2544	24	48	301.2544	301.2544	NUM
eurjchem-2544	24	49	table	table	NOUN
eurjchem-2544	24	50	1	1	NUM
eurjchem-2544	24	51	.	.	PUNCT
eurjchem-2544	24	52	applications	application	NOUN
eurjchem-2544	24	53	of	of	ADP
eurjchem-2544	24	54	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	24	55	.	.	PUNCT
eurjchem-2544	25	1	applications	application	NOUN
eurjchem-2544	25	2	references	reference	NOUN
eurjchem-2544	25	3	thermodynamics	thermodynamic	NOUN
eurjchem-2544	25	4	and	and	CCONJ
eurjchem-2544	25	5	kinetic	kinetic	ADJ
eurjchem-2544	25	6	studies	study	NOUN
eurjchem-2544	25	7	[	[	X
eurjchem-2544	25	8	7	7	NUM
eurjchem-2544	25	9	]	]	SYM
eurjchem-2544	25	10	treatment	treatment	NOUN
eurjchem-2544	25	11	of	of	ADP
eurjchem-2544	25	12	sacoma	sacoma	NOUN
eurjchem-2544	25	13	cells	cell	NOUN
eurjchem-2544	25	14	[	[	X
eurjchem-2544	25	15	8	8	X
eurjchem-2544	25	16	]	]	PUNCT
eurjchem-2544	25	17	protective	protective	ADJ
eurjchem-2544	25	18	agent	agent	NOUN
eurjchem-2544	25	19	against	against	ADP
eurjchem-2544	25	20	dangerous	dangerous	ADJ
eurjchem-2544	25	21	x	x	NOUN
eurjchem-2544	25	22	-	-	NOUN
eurjchem-2544	25	23	rays	ray	NOUN
eurjchem-2544	25	24	[	[	X
eurjchem-2544	25	25	8	8	NUM
eurjchem-2544	25	26	]	]	SYM
eurjchem-2544	25	27	treatment	treatment	NOUN
eurjchem-2544	25	28	of	of	ADP
eurjchem-2544	25	29	alcoholism	alcoholism	NOUN
eurjchem-2544	25	30	[	[	X
eurjchem-2544	25	31	9	9	NUM
eurjchem-2544	25	32	]	]	X
eurjchem-2544	25	33	medicine	medicine	NOUN
eurjchem-2544	25	34	[	[	X
eurjchem-2544	25	35	10	10	NUM
eurjchem-2544	25	36	]	]	PUNCT
eurjchem-2544	25	37	metal	metal	NOUN
eurjchem-2544	25	38	separation	separation	NOUN
eurjchem-2544	25	39	via	via	ADP
eurjchem-2544	25	40	gas	gas	NOUN
eurjchem-2544	25	41	chromatography	chromatography	NOUN
eurjchem-2544	25	42	[	[	X
eurjchem-2544	25	43	12	12	NUM
eurjchem-2544	25	44	]	]	PUNCT
eurjchem-2544	25	45	liquid	liquid	NOUN
eurjchem-2544	25	46	-	-	PUNCT
eurjchem-2544	25	47	liquid	liquid	NOUN
eurjchem-2544	25	48	extraction	extraction	NOUN
eurjchem-2544	25	49	in	in	ADP
eurjchem-2544	25	50	analytical	analytical	ADJ
eurjchem-2544	25	51	chemistry	chemistry	NOUN
eurjchem-2544	26	1	[	[	X
eurjchem-2544	26	2	12	12	NUM
eurjchem-2544	26	3	]	]	X
eurjchem-2544	26	4	biological	biological	ADJ
eurjchem-2544	26	5	studies	study	NOUN
eurjchem-2544	26	6	,	,	PUNCT
eurjchem-2544	26	7	e.g.	e.g.	ADV
eurjchem-2544	26	8	anti	anti	ADJ
eurjchem-2544	26	9	-	-	ADJ
eurjchem-2544	26	10	alkylation	alkylation	ADJ
eurjchem-2544	26	11	[	[	X
eurjchem-2544	26	12	13	13	NUM
eurjchem-2544	26	13	]	]	X
eurjchem-2544	26	14	anti	anti	ADJ
eurjchem-2544	26	15	-	-	NOUN
eurjchem-2544	26	16	hiv	hiv	PROPN
eurjchem-2544	27	1	[	[	X
eurjchem-2544	27	2	14	14	NUM
eurjchem-2544	27	3	]	]	PUNCT
eurjchem-2544	27	4	antidotes	antidote	NOUN
eurjchem-2544	27	5	for	for	ADP
eurjchem-2544	27	6	cadmium	cadmium	NOUN
eurjchem-2544	27	7	intoxication	intoxication	NOUN
eurjchem-2544	27	8	[	[	X
eurjchem-2544	27	9	15	15	NUM
eurjchem-2544	27	10	]	]	PUNCT
eurjchem-2544	27	11	catalysis	catalysis	NOUN
eurjchem-2544	28	1	[	[	X
eurjchem-2544	28	2	16	16	NUM
eurjchem-2544	28	3	]	]	PUNCT
eurjchem-2544	28	4	anticancer	anticancer	NOUN
eurjchem-2544	28	5	agents	agent	NOUN
eurjchem-2544	29	1	[	[	X
eurjchem-2544	29	2	9,17	9,17	X
eurjchem-2544	29	3	]	]	X
eurjchem-2544	29	4	internal	internal	ADJ
eurjchem-2544	29	5	standards	standard	NOUN
eurjchem-2544	29	6	determination	determination	NOUN
eurjchem-2544	29	7	of	of	ADP
eurjchem-2544	29	8	metals	metal	NOUN
eurjchem-2544	29	9	via	via	ADP
eurjchem-2544	29	10	gas	gas	NOUN
eurjchem-2544	29	11	chromatography	chromatography	NOUN
eurjchem-2544	29	12	[	[	X
eurjchem-2544	29	13	18,19	18,19	NUM
eurjchem-2544	29	14	]	]	X
eurjchem-2544	29	15	photoluminescent	photoluminescent	NOUN
eurjchem-2544	29	16	studies	study	NOUN
eurjchem-2544	29	17	[	[	X
eurjchem-2544	29	18	20	20	NUM
eurjchem-2544	29	19	]	]	X
eurjchem-2544	29	20	n	n	PROPN
eurjchem-2544	29	21	s	s	NOUN
eurjchem-2544	29	22	s	s	X
eurjchem-2544	29	23	r	r	NOUN
eurjchem-2544	29	24	'	'	PUNCT
eurjchem-2544	29	25	r	r	NOUN
eurjchem-2544	30	1	n	n	PROPN
eurjchem-2544	30	2	s	s	NOUN
eurjchem-2544	30	3	s	s	X
eurjchem-2544	30	4	r	r	NOUN
eurjchem-2544	30	5	'	'	PUNCT
eurjchem-2544	30	6	r	r	NOUN
eurjchem-2544	30	7	n	n	PROPN
eurjchem-2544	30	8	s	s	NOUN
eurjchem-2544	30	9	s	s	X
eurjchem-2544	30	10	r	r	NOUN
eurjchem-2544	30	11	'	'	PUNCT
eurjchem-2544	30	12	r	r	NOUN
eurjchem-2544	30	13	n	n	PROPN
eurjchem-2544	30	14	s	s	NOUN
eurjchem-2544	30	15	s	s	X
eurjchem-2544	30	16	r	r	NOUN
eurjchem-2544	30	17	'	'	PUNCT
eurjchem-2544	30	18	r	r	NOUN
eurjchem-2544	30	19	(	(	PUNCT
eurjchem-2544	30	20	i	i	NOUN
eurjchem-2544	30	21	)	)	PUNCT
eurjchem-2544	30	22	(	(	PUNCT
eurjchem-2544	30	23	ii	ii	NOUN
eurjchem-2544	30	24	)	)	PUNCT
eurjchem-2544	30	25	(	(	PUNCT
eurjchem-2544	30	26	iii	iii	NOUN
eurjchem-2544	30	27	)	)	PUNCT
eurjchem-2544	30	28	(	(	PUNCT
eurjchem-2544	30	29	iv	iv	X
eurjchem-2544	30	30	)	)	PUNCT
eurjchem-2544	30	31	scheme	scheme	NOUN
eurjchem-2544	30	32	1	1	NUM
eurjchem-2544	30	33	.	.	PUNCT
eurjchem-2544	30	34	resonance	resonance	NOUN
eurjchem-2544	30	35	structure	structure	NOUN
eurjchem-2544	30	36	of	of	ADP
eurjchem-2544	30	37	the	the	DET
eurjchem-2544	30	38	typical	typical	ADJ
eurjchem-2544	30	39	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	30	40	ligand	ligand	NOUN
eurjchem-2544	30	41	.	.	PUNCT
eurjchem-2544	31	1	figure	figure	NOUN
eurjchem-2544	31	2	1	1	NUM
eurjchem-2544	31	3	.	.	PUNCT
eurjchem-2544	32	1	the	the	DET
eurjchem-2544	32	2	molecular	molecular	ADJ
eurjchem-2544	32	3	structure	structure	NOUN
eurjchem-2544	32	4	of	of	ADP
eurjchem-2544	32	5	complex	complex	ADJ
eurjchem-2544	32	6	1	1	NUM
eurjchem-2544	32	7	.	.	PUNCT
eurjchem-2544	33	1	in	in	ADP
eurjchem-2544	33	2	the	the	DET
eurjchem-2544	33	3	last	last	ADJ
eurjchem-2544	33	4	20	20	NUM
eurjchem-2544	33	5	-	-	SYM
eurjchem-2544	33	6	25	25	NUM
eurjchem-2544	33	7	years	year	NOUN
eurjchem-2544	33	8	,	,	PUNCT
eurjchem-2544	33	9	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	33	10	have	have	AUX
eurjchem-2544	33	11	been	be	AUX
eurjchem-2544	33	12	extensively	extensively	ADV
eurjchem-2544	33	13	studied	study	VERB
eurjchem-2544	33	14	as	as	ADP
eurjchem-2544	33	15	anticancer	anticancer	NOUN
eurjchem-2544	33	16	,	,	PUNCT
eurjchem-2544	33	17	antiviral	antiviral	NOUN
eurjchem-2544	33	18	,	,	PUNCT
eurjchem-2544	33	19	antibacterial	antibacterial	ADJ
eurjchem-2544	33	20	,	,	PUNCT
eurjchem-2544	33	21	and	and	CCONJ
eurjchem-2544	33	22	antifungal	antifungal	ADJ
eurjchem-2544	33	23	agents	agent	NOUN
eurjchem-2544	33	24	and	and	CCONJ
eurjchem-2544	33	25	have	have	AUX
eurjchem-2544	33	26	been	be	AUX
eurjchem-2544	33	27	used	use	VERB
eurjchem-2544	33	28	repeatedly	repeatedly	ADV
eurjchem-2544	33	29	in	in	ADP
eurjchem-2544	33	30	neurological	neurological	ADJ
eurjchem-2544	33	31	applications	application	NOUN
eurjchem-2544	33	32	with	with	ADP
eurjchem-2544	33	33	emphasis	emphasis	NOUN
eurjchem-2544	33	34	on	on	ADP
eurjchem-2544	33	35	the	the	DET
eurjchem-2544	33	36	treatment	treatment	NOUN
eurjchem-2544	33	37	of	of	ADP
eurjchem-2544	33	38	alzheimer	alzheimer	PROPN
eurjchem-2544	33	39	's	's	PART
eurjchem-2544	33	40	disease	disease	NOUN
eurjchem-2544	33	41	.	.	PUNCT
eurjchem-2544	34	1	not	not	PART
eurjchem-2544	34	2	left	leave	VERB
eurjchem-2544	34	3	out	out	ADP
eurjchem-2544	34	4	of	of	ADP
eurjchem-2544	34	5	these	these	PRON
eurjchem-2544	34	6	is	be	AUX
eurjchem-2544	34	7	the	the	DET
eurjchem-2544	34	8	attempted	attempt	VERB
eurjchem-2544	34	9	use	use	NOUN
eurjchem-2544	34	10	of	of	ADP
eurjchem-2544	34	11	disulfiram	disulfiram	NOUN
eurjchem-2544	34	12	and	and	CCONJ
eurjchem-2544	34	13	diethyldithiocarbamate	diethyldithiocarbamate	NOUN
eurjchem-2544	34	14	in	in	ADP
eurjchem-2544	34	15	clinical	clinical	ADJ
eurjchem-2544	34	16	trials	trial	NOUN
eurjchem-2544	34	17	as	as	ADP
eurjchem-2544	34	18	antiviral	antiviral	ADJ
eurjchem-2544	34	19	agents	agent	NOUN
eurjchem-2544	34	20	against	against	ADP
eurjchem-2544	34	21	the	the	DET
eurjchem-2544	34	22	human	human	ADJ
eurjchem-2544	34	23	immunodeficiency	immunodeficiency	NOUN
eurjchem-2544	34	24	virus	virus	NOUN
eurjchem-2544	34	25	hiv-1	hiv-1	PUNCT
eurjchem-2544	34	26	and	and	CCONJ
eurjchem-2544	34	27	variable	variable	ADJ
eurjchem-2544	34	28	hiv	hiv	PROPN
eurjchem-2544	34	29	-	-	PUNCT
eurjchem-2544	34	30	rna	rna	PROPN
eurjchem-2544	34	31	(	(	PUNCT
eurjchem-2544	34	32	ribonucleic	ribonucleic	ADJ
eurjchem-2544	34	33	acid	acid	NOUN
eurjchem-2544	34	34	)	)	PUNCT
eurjchem-2544	35	1	[	[	X
eurjchem-2544	35	2	9	9	NUM
eurjchem-2544	35	3	]	]	PUNCT
eurjchem-2544	35	4	.	.	PUNCT
eurjchem-2544	36	1	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	36	2	play	play	VERB
eurjchem-2544	36	3	specific	specific	ADJ
eurjchem-2544	36	4	catalytic	catalytic	ADJ
eurjchem-2544	36	5	roles	role	NOUN
eurjchem-2544	36	6	in	in	ADP
eurjchem-2544	36	7	the	the	DET
eurjchem-2544	36	8	vulcanization	vulcanization	NOUN
eurjchem-2544	36	9	of	of	ADP
eurjchem-2544	36	10	rubber	rubber	NOUN
eurjchem-2544	36	11	and	and	CCONJ
eurjchem-2544	36	12	in	in	ADP
eurjchem-2544	36	13	the	the	DET
eurjchem-2544	36	14	radical	radical	ADJ
eurjchem-2544	36	15	chain	chain	NOUN
eurjchem-2544	36	16	transfer	transfer	NOUN
eurjchem-2544	36	17	of	of	ADP
eurjchem-2544	36	18	polymerization	polymerization	NOUN
eurjchem-2544	36	19	reactions	reaction	NOUN
eurjchem-2544	36	20	[	[	X
eurjchem-2544	36	21	10	10	NUM
eurjchem-2544	36	22	]	]	PUNCT
eurjchem-2544	36	23	.	.	PUNCT
eurjchem-2544	37	1	they	they	PRON
eurjchem-2544	37	2	have	have	AUX
eurjchem-2544	37	3	also	also	ADV
eurjchem-2544	37	4	shown	show	VERB
eurjchem-2544	37	5	extensive	extensive	ADJ
eurjchem-2544	37	6	use	use	NOUN
eurjchem-2544	37	7	as	as	ADP
eurjchem-2544	37	8	electrochemical	electrochemical	ADJ
eurjchem-2544	37	9	sensors	sensor	NOUN
eurjchem-2544	37	10	;	;	PUNCT
eurjchem-2544	37	11	a	a	DET
eurjchem-2544	37	12	technique	technique	NOUN
eurjchem-2544	37	13	that	that	PRON
eurjchem-2544	37	14	is	be	AUX
eurjchem-2544	37	15	simpler	simple	ADJ
eurjchem-2544	37	16	and	and	CCONJ
eurjchem-2544	37	17	cheaper	cheap	ADJ
eurjchem-2544	37	18	compared	compare	VERB
eurjchem-2544	37	19	to	to	PART
eurjchem-2544	37	20	spectroscopy	spectroscopy	VERB
eurjchem-2544	37	21	and	and	CCONJ
eurjchem-2544	37	22	chromatography	chromatography	NOUN
eurjchem-2544	37	23	.	.	PUNCT
eurjchem-2544	38	1	their	their	PRON
eurjchem-2544	38	2	extensive	extensive	ADJ
eurjchem-2544	38	3	use	use	NOUN
eurjchem-2544	38	4	has	have	AUX
eurjchem-2544	38	5	led	lead	VERB
eurjchem-2544	38	6	to	to	ADP
eurjchem-2544	38	7	the	the	DET
eurjchem-2544	38	8	development	development	NOUN
eurjchem-2544	38	9	of	of	ADP
eurjchem-2544	38	10	analytical	analytical	ADJ
eurjchem-2544	38	11	quantification	quantification	NOUN
eurjchem-2544	38	12	of	of	ADP
eurjchem-2544	38	13	the	the	DET
eurjchem-2544	38	14	main	main	ADJ
eurjchem-2544	38	15	metabolites	metabolite	NOUN
eurjchem-2544	38	16	;	;	PUNCT
eurjchem-2544	38	17	ethylene	ethylene	NOUN
eurjchem-2544	38	18	thiourea	thiourea	NOUN
eurjchem-2544	38	19	and	and	CCONJ
eurjchem-2544	38	20	propylene	propylene	NOUN
eurjchem-2544	38	21	thiourea	thiourea	NOUN
eurjchem-2544	38	22	,	,	PUNCT
eurjchem-2544	38	23	which	which	PRON
eurjchem-2544	38	24	are	be	AUX
eurjchem-2544	38	25	the	the	DET
eurjchem-2544	38	26	main	main	ADJ
eurjchem-2544	38	27	sources	source	NOUN
eurjchem-2544	38	28	of	of	ADP
eurjchem-2544	38	29	the	the	DET
eurjchem-2544	38	30	toxic	toxic	ADJ
eurjchem-2544	38	31	nature	nature	NOUN
eurjchem-2544	38	32	of	of	ADP
eurjchem-2544	38	33	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	38	34	[	[	X
eurjchem-2544	38	35	11	11	NUM
eurjchem-2544	38	36	]	]	PUNCT
eurjchem-2544	38	37	.	.	PUNCT
eurjchem-2544	39	1	the	the	DET
eurjchem-2544	39	2	coordination	coordination	NOUN
eurjchem-2544	39	3	chemistry	chemistry	NOUN
eurjchem-2544	39	4	of	of	ADP
eurjchem-2544	39	5	cobalt	cobalt	NOUN
eurjchem-2544	39	6	,	,	PUNCT
eurjchem-2544	39	7	rhodium	rhodium	NOUN
eurjchem-2544	39	8	and	and	CCONJ
eurjchem-2544	39	9	iridium	iridium	NOUN
eurjchem-2544	39	10	is	be	AUX
eurjchem-2544	39	11	favored	favor	VERB
eurjchem-2544	39	12	because	because	SCONJ
eurjchem-2544	39	13	of	of	ADP
eurjchem-2544	39	14	(	(	PUNCT
eurjchem-2544	39	15	i	i	NOUN
eurjchem-2544	39	16	)	)	PUNCT
eurjchem-2544	39	17	the	the	DET
eurjchem-2544	39	18	stability	stability	NOUN
eurjchem-2544	39	19	of	of	ADP
eurjchem-2544	39	20	their	their	PRON
eurjchem-2544	39	21	+3	+3	ADJ
eurjchem-2544	39	22	oxidation	oxidation	NOUN
eurjchem-2544	39	23	states	state	NOUN
eurjchem-2544	39	24	,	,	PUNCT
eurjchem-2544	39	25	(	(	PUNCT
eurjchem-2544	39	26	ii	ii	NOUN
eurjchem-2544	39	27	)	)	PUNCT
eurjchem-2544	39	28	the	the	DET
eurjchem-2544	39	29	formation	formation	NOUN
eurjchem-2544	39	30	of	of	ADP
eurjchem-2544	39	31	varying	vary	VERB
eurjchem-2544	39	32	coordination	coordination	NOUN
eurjchem-2544	39	33	geometries	geometry	NOUN
eurjchem-2544	39	34	by	by	ADP
eurjchem-2544	39	35	coordinating	coordinate	VERB
eurjchem-2544	39	36	with	with	ADP
eurjchem-2544	39	37	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	39	38	ligands	ligand	NOUN
eurjchem-2544	39	39	,	,	PUNCT
eurjchem-2544	39	40	(	(	PUNCT
eurjchem-2544	39	41	iii	iii	X
eurjchem-2544	39	42	)	)	PUNCT
eurjchem-2544	39	43	the	the	DET
eurjchem-2544	39	44	formation	formation	NOUN
eurjchem-2544	39	45	of	of	ADP
eurjchem-2544	39	46	various	various	ADJ
eurjchem-2544	39	47	coordination	coordination	NOUN
eurjchem-2544	39	48	geometries	geometry	NOUN
eurjchem-2544	39	49	from	from	ADP
eurjchem-2544	39	50	the	the	DET
eurjchem-2544	39	51	mixed	mixed	ADJ
eurjchem-2544	39	52	ligand	ligand	ADJ
eurjchem-2544	39	53	complexes	complex	NOUN
eurjchem-2544	39	54	of	of	ADP
eurjchem-2544	39	55	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	39	56	and	and	CCONJ
eurjchem-2544	39	57	phosphorus	phosphorus	NOUN
eurjchem-2544	39	58	binding	bind	VERB
eurjchem-2544	39	59	ligands	ligand	NOUN
eurjchem-2544	39	60	,	,	PUNCT
eurjchem-2544	39	61	and	and	CCONJ
eurjchem-2544	39	62	(	(	PUNCT
eurjchem-2544	39	63	iv	iv	X
eurjchem-2544	39	64	)	)	PUNCT
eurjchem-2544	39	65	the	the	DET
eurjchem-2544	39	66	utilization	utilization	NOUN
eurjchem-2544	39	67	of	of	ADP
eurjchem-2544	39	68	these	these	DET
eurjchem-2544	39	69	geometrically	geometrically	ADV
eurjchem-2544	39	70	aligned	aligned	ADJ
eurjchem-2544	39	71	complexes	complex	NOUN
eurjchem-2544	39	72	to	to	PART
eurjchem-2544	39	73	develop	develop	VERB
eurjchem-2544	39	74	novel	novel	ADJ
eurjchem-2544	39	75	complexes	complex	NOUN
eurjchem-2544	39	76	with	with	ADP
eurjchem-2544	39	77	enormous	enormous	ADJ
eurjchem-2544	39	78	scientific	scientific	ADJ
eurjchem-2544	39	79	applications	application	NOUN
eurjchem-2544	39	80	(	(	PUNCT
eurjchem-2544	39	81	table	table	NOUN
eurjchem-2544	39	82	1	1	NUM
eurjchem-2544	39	83	[	[	X
eurjchem-2544	39	84	7	7	NUM
eurjchem-2544	39	85	-	-	NUM
eurjchem-2544	39	86	10,12	10,12	NUM
eurjchem-2544	39	87	-	-	PUNCT
eurjchem-2544	39	88	20	20	NUM
eurjchem-2544	39	89	]	]	PUNCT
eurjchem-2544	39	90	)	)	PUNCT
eurjchem-2544	39	91	.	.	PUNCT
eurjchem-2544	40	1	the	the	DET
eurjchem-2544	40	2	last	last	ADJ
eurjchem-2544	40	3	5	5	NUM
eurjchem-2544	40	4	-	-	SYM
eurjchem-2544	40	5	6	6	NUM
eurjchem-2544	40	6	decades	decade	NOUN
eurjchem-2544	40	7	have	have	AUX
eurjchem-2544	40	8	witnessed	witness	VERB
eurjchem-2544	40	9	rigorous	rigorous	ADJ
eurjchem-2544	40	10	research	research	NOUN
eurjchem-2544	40	11	that	that	PRON
eurjchem-2544	40	12	highlights	highlight	VERB
eurjchem-2544	40	13	the	the	DET
eurjchem-2544	40	14	significance	significance	NOUN
eurjchem-2544	40	15	of	of	ADP
eurjchem-2544	40	16	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	40	17	chemistry	chemistry	NOUN
eurjchem-2544	40	18	at	at	ADP
eurjchem-2544	40	19	the	the	DET
eurjchem-2544	40	20	crystal	crystal	NOUN
eurjchem-2544	40	21	and	and	CCONJ
eurjchem-2544	40	22	molecular	molecular	ADJ
eurjchem-2544	40	23	levels	level	NOUN
eurjchem-2544	40	24	[	[	X
eurjchem-2544	40	25	21	21	NUM
eurjchem-2544	40	26	-	-	SYM
eurjchem-2544	40	27	23	23	NUM
eurjchem-2544	40	28	]	]	PUNCT
eurjchem-2544	40	29	.	.	PUNCT
eurjchem-2544	41	1	previous	previous	ADJ
eurjchem-2544	41	2	publications	publication	NOUN
eurjchem-2544	41	3	on	on	ADP
eurjchem-2544	41	4	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	41	5	complexes	complex	NOUN
eurjchem-2544	41	6	have	have	AUX
eurjchem-2544	41	7	guided	guide	VERB
eurjchem-2544	41	8	us	we	PRON
eurjchem-2544	41	9	in	in	ADP
eurjchem-2544	41	10	this	this	DET
eurjchem-2544	41	11	review	review	NOUN
eurjchem-2544	41	12	,	,	PUNCT
eurjchem-2544	41	13	wherein	wherein	SCONJ
eurjchem-2544	41	14	we	we	PRON
eurjchem-2544	41	15	present	present	VERB
eurjchem-2544	41	16	single	single	ADJ
eurjchem-2544	41	17	and	and	CCONJ
eurjchem-2544	41	18	mixed	mixed	ADJ
eurjchem-2544	41	19	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	41	20	ligands	ligand	NOUN
eurjchem-2544	41	21	of	of	ADP
eurjchem-2544	41	22	co(iii	co(iii	NOUN
eurjchem-2544	41	23	)	)	PUNCT
eurjchem-2544	41	24	,	,	PUNCT
eurjchem-2544	41	25	rh(iii	rh(iii	PROPN
eurjchem-2544	41	26	)	)	PUNCT
eurjchem-2544	41	27	,	,	PUNCT
eurjchem-2544	41	28	and	and	CCONJ
eurjchem-2544	41	29	ir(iii	ir(iii	NOUN
eurjchem-2544	41	30	)	)	PUNCT
eurjchem-2544	41	31	in	in	ADP
eurjchem-2544	41	32	light	light	NOUN
eurjchem-2544	41	33	of	of	ADP
eurjchem-2544	41	34	their	their	PRON
eurjchem-2544	41	35	chelating	chelating	NOUN
eurjchem-2544	41	36	and	and	CCONJ
eurjchem-2544	41	37	bridging	bridging	NOUN
eurjchem-2544	41	38	coordination	coordination	NOUN
eurjchem-2544	41	39	modes	mode	NOUN
eurjchem-2544	41	40	,	,	PUNCT
eurjchem-2544	41	41	the	the	DET
eurjchem-2544	41	42	effects	effect	NOUN
eurjchem-2544	41	43	of	of	ADP
eurjchem-2544	41	44	substituent	substituent	NOUN
eurjchem-2544	41	45	change	change	NOUN
eurjchem-2544	41	46	on	on	ADP
eurjchem-2544	41	47	the	the	DET
eurjchem-2544	41	48	carbamate	carbamate	NOUN
eurjchem-2544	41	49	n	n	PROPN
eurjchem-2544	41	50	on	on	ADP
eurjchem-2544	41	51	the	the	DET
eurjchem-2544	41	52	overall	overall	ADJ
eurjchem-2544	41	53	structural	structural	ADJ
eurjchem-2544	41	54	patterns	pattern	NOUN
eurjchem-2544	41	55	,	,	PUNCT
eurjchem-2544	41	56	the	the	DET
eurjchem-2544	41	57	geometric	geometric	ADJ
eurjchem-2544	41	58	alignment	alignment	NOUN
eurjchem-2544	41	59	around	around	ADP
eurjchem-2544	41	60	the	the	DET
eurjchem-2544	41	61	metal	metal	NOUN
eurjchem-2544	41	62	of	of	ADP
eurjchem-2544	41	63	focus	focus	NOUN
eurjchem-2544	41	64	and	and	CCONJ
eurjchem-2544	41	65	how	how	SCONJ
eurjchem-2544	41	66	symmetric	symmetric	ADJ
eurjchem-2544	41	67	and	and	CCONJ
eurjchem-2544	41	68	asymmetric	asymmetric	ADJ
eurjchem-2544	41	69	bonds	bond	NOUN
eurjchem-2544	41	70	affect	affect	VERB
eurjchem-2544	41	71	geometry	geometry	NOUN
eurjchem-2544	41	72	and	and	CCONJ
eurjchem-2544	41	73	association	association	NOUN
eurjchem-2544	41	74	in	in	ADP
eurjchem-2544	41	75	the	the	DET
eurjchem-2544	41	76	primary	primary	ADJ
eurjchem-2544	41	77	and	and	CCONJ
eurjchem-2544	41	78	secondary	secondary	ADJ
eurjchem-2544	41	79	coordination	coordination	NOUN
eurjchem-2544	41	80	spheres	sphere	NOUN
eurjchem-2544	41	81	.	.	PUNCT
eurjchem-2544	42	1	the	the	DET
eurjchem-2544	42	2	modification	modification	NOUN
eurjchem-2544	42	3	of	of	ADP
eurjchem-2544	42	4	bonds	bond	NOUN
eurjchem-2544	42	5	(	(	PUNCT
eurjchem-2544	42	6	lengthening	lengthen	VERB
eurjchem-2544	42	7	or	or	CCONJ
eurjchem-2544	42	8	shortening	shortening	NOUN
eurjchem-2544	42	9	)	)	PUNCT
eurjchem-2544	42	10	via	via	ADP
eurjchem-2544	42	11	trans	trans	PROPN
eurjchem-2544	42	12	effects	effect	NOUN
eurjchem-2544	42	13	of	of	ADP
eurjchem-2544	42	14	specific	specific	ADJ
eurjchem-2544	42	15	functional	functional	ADJ
eurjchem-2544	42	16	groups	group	NOUN
eurjchem-2544	42	17	,	,	PUNCT
eurjchem-2544	42	18	especially	especially	ADV
eurjchem-2544	42	19	the	the	DET
eurjchem-2544	42	20	p	p	NOUN
eurjchem-2544	42	21	-	-	PUNCT
eurjchem-2544	42	22	ligands	ligand	NOUN
eurjchem-2544	42	23	,	,	PUNCT
eurjchem-2544	42	24	will	will	AUX
eurjchem-2544	42	25	be	be	AUX
eurjchem-2544	42	26	discussed	discuss	VERB
eurjchem-2544	42	27	extensively	extensively	ADV
eurjchem-2544	42	28	.	.	PUNCT
eurjchem-2544	43	1	this	this	DET
eurjchem-2544	43	2	review	review	NOUN
eurjchem-2544	43	3	presents	present	VERB
eurjchem-2544	43	4	the	the	DET
eurjchem-2544	43	5	varying	vary	VERB
eurjchem-2544	43	6	structures	structure	NOUN
eurjchem-2544	43	7	of	of	ADP
eurjchem-2544	43	8	the	the	DET
eurjchem-2544	43	9	triad	triad	NUM
eurjchem-2544	43	10	of	of	ADP
eurjchem-2544	43	11	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	43	12	and	and	CCONJ
eurjchem-2544	43	13	their	their	PRON
eurjchem-2544	43	14	mixed	mixed	ADJ
eurjchem-2544	43	15	ligand	ligand	ADJ
eurjchem-2544	43	16	derivatives	derivative	NOUN
eurjchem-2544	43	17	,	,	PUNCT
eurjchem-2544	43	18	which	which	PRON
eurjchem-2544	43	19	is	be	AUX
eurjchem-2544	43	20	valuable	valuable	ADJ
eurjchem-2544	43	21	in	in	ADP
eurjchem-2544	43	22	analyzing	analyze	VERB
eurjchem-2544	43	23	their	their	PRON
eurjchem-2544	43	24	structural	structural	ADJ
eurjchem-2544	43	25	stability	stability	NOUN
eurjchem-2544	43	26	.	.	PUNCT
eurjchem-2544	44	1	based	base	VERB
eurjchem-2544	44	2	on	on	ADP
eurjchem-2544	44	3	the	the	DET
eurjchem-2544	44	4	foregoing	foregoing	NOUN
eurjchem-2544	44	5	,	,	PUNCT
eurjchem-2544	44	6	this	this	DET
eurjchem-2544	44	7	review	review	NOUN
eurjchem-2544	44	8	will	will	AUX
eurjchem-2544	44	9	focus	focus	VERB
eurjchem-2544	44	10	on	on	ADP
eurjchem-2544	44	11	the	the	DET
eurjchem-2544	44	12	crystal	crystal	NOUN
eurjchem-2544	44	13	and	and	CCONJ
eurjchem-2544	44	14	molecular	molecular	ADJ
eurjchem-2544	44	15	structures	structure	NOUN
eurjchem-2544	44	16	of	of	ADP
eurjchem-2544	44	17	single	single	ADJ
eurjchem-2544	44	18	and	and	CCONJ
eurjchem-2544	44	19	mixed	mixed	ADJ
eurjchem-2544	44	20	ligand	ligand	NOUN
eurjchem-2544	44	21	(	(	PUNCT
eurjchem-2544	44	22	p	p	NOUN
eurjchem-2544	44	23	-	-	PUNCT
eurjchem-2544	44	24	ligand	ligand	NOUN
eurjchem-2544	44	25	)	)	PUNCT
eurjchem-2544	44	26	complexes	complex	NOUN
eurjchem-2544	44	27	of	of	ADP
eurjchem-2544	44	28	co	co	PROPN
eurjchem-2544	44	29	,	,	PUNCT
eurjchem-2544	44	30	rh	rh	PROPN
eurjchem-2544	44	31	,	,	PUNCT
eurjchem-2544	44	32	and	and	CCONJ
eurjchem-2544	44	33	ir	ir	X
eurjchem-2544	44	34	in	in	ADP
eurjchem-2544	44	35	the	the	DET
eurjchem-2544	44	36	+3	+3	PROPN
eurjchem-2544	44	37	oxidation	oxidation	NOUN
eurjchem-2544	44	38	states	state	NOUN
eurjchem-2544	44	39	which	which	PRON
eurjchem-2544	44	40	were	be	AUX
eurjchem-2544	44	41	obtained	obtain	VERB
eurjchem-2544	44	42	via	via	ADP
eurjchem-2544	44	43	search	search	NOUN
eurjchem-2544	44	44	of	of	ADP
eurjchem-2544	44	45	the	the	DET
eurjchem-2544	44	46	cambridge	cambridge	PROPN
eurjchem-2544	44	47	structural	structural	ADJ
eurjchem-2544	44	48	database	database	NOUN
eurjchem-2544	44	49	(	(	PUNCT
eurjchem-2544	44	50	csd	csd	NOUN
eurjchem-2544	44	51	)	)	PUNCT
eurjchem-2544	45	1	[	[	X
eurjchem-2544	45	2	24	24	NUM
eurjchem-2544	45	3	]	]	PUNCT
eurjchem-2544	45	4	.	.	PUNCT
eurjchem-2544	46	1	these	these	DET
eurjchem-2544	46	2	structures	structure	NOUN
eurjchem-2544	46	3	are	be	AUX
eurjchem-2544	46	4	subsequently	subsequently	ADV
eurjchem-2544	46	5	extracted	extract	VERB
eurjchem-2544	46	6	with	with	ADP
eurjchem-2544	46	7	mercury	mercury	NOUN
eurjchem-2544	46	8	[	[	X
eurjchem-2544	46	9	25	25	NUM
eurjchem-2544	46	10	]	]	PUNCT
eurjchem-2544	46	11	,	,	PUNCT
eurjchem-2544	46	12	a	a	DET
eurjchem-2544	46	13	conventional	conventional	ADJ
eurjchem-2544	46	14	crystallographic	crystallographic	ADJ
eurjchem-2544	46	15	visualization	visualization	NOUN
eurjchem-2544	46	16	tool	tool	NOUN
eurjchem-2544	46	17	(	(	PUNCT
eurjchem-2544	46	18	table	table	NOUN
eurjchem-2544	46	19	2	2	NUM
eurjchem-2544	46	20	)	)	PUNCT
eurjchem-2544	47	1	[	[	X
eurjchem-2544	47	2	4,5,8	4,5,8	NUM
eurjchem-2544	47	3	-	-	NOUN
eurjchem-2544	47	4	20,26	20,26	NOUN
eurjchem-2544	47	5	-	-	PUNCT
eurjchem-2544	47	6	52	52	NUM
eurjchem-2544	47	7	]	]	PUNCT
eurjchem-2544	47	8	.	.	PUNCT
eurjchem-2544	48	1	shotonwa	shotonwa	PROPN
eurjchem-2544	48	2	et	et	PROPN
eurjchem-2544	48	3	al	al	PROPN
eurjchem-2544	48	4	.	.	PUNCT
eurjchem-2544	48	5	/	/	SYM
eurjchem-2544	48	6	european	european	PROPN
eurjchem-2544	48	7	journal	journal	PROPN
eurjchem-2544	48	8	of	of	ADP
eurjchem-2544	48	9	chemistry	chemistry	NOUN
eurjchem-2544	48	10	15	15	NUM
eurjchem-2544	48	11	(	(	PUNCT
eurjchem-2544	48	12	3	3	NUM
eurjchem-2544	48	13	)	)	PUNCT
eurjchem-2544	48	14	(	(	PUNCT
eurjchem-2544	48	15	2024	2024	NUM
eurjchem-2544	48	16	)	)	PUNCT
eurjchem-2544	48	17	291	291	NUM
eurjchem-2544	48	18	-	-	SYM
eurjchem-2544	48	19	301	301	NUM
eurjchem-2544	48	20	293	293	NUM
eurjchem-2544	48	21	2024	2024	NUM
eurjchem-2544	48	22	–	–	PUNCT
eurjchem-2544	48	23	european	european	ADJ
eurjchem-2544	48	24	journal	journal	NOUN
eurjchem-2544	48	25	of	of	ADP
eurjchem-2544	48	26	chemistry	chemistry	NOUN
eurjchem-2544	48	27	–	–	PUNCT
eurjchem-2544	48	28	cc	cc	NOUN
eurjchem-2544	48	29	by	by	ADP
eurjchem-2544	48	30	nc	nc	PROPN
eurjchem-2544	48	31	–	–	PUNCT
eurjchem-2544	48	32	doi	doi	PROPN
eurjchem-2544	48	33	:	:	PUNCT
eurjchem-2544	48	34	10.5155	10.5155	NUM
eurjchem-2544	48	35	/	/	SYM
eurjchem-2544	48	36	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	48	37	-	-	PUNCT
eurjchem-2544	48	38	301.2544	301.2544	NUM
eurjchem-2544	48	39	table	table	NOUN
eurjchem-2544	48	40	2	2	NUM
eurjchem-2544	48	41	.	.	PUNCT
eurjchem-2544	49	1	refcodes	refcode	NOUN
eurjchem-2544	49	2	,	,	PUNCT
eurjchem-2544	49	3	iupac	iupac	NOUN
eurjchem-2544	49	4	names	name	NOUN
eurjchem-2544	49	5	and	and	CCONJ
eurjchem-2544	49	6	unit	unit	NOUN
eurjchem-2544	49	7	cell	cell	NOUN
eurjchem-2544	49	8	parameters	parameter	NOUN
eurjchem-2544	49	9	of	of	ADP
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eurjchem-2544	91	6	tris(diethyldithiocarbamato)rhodium(iii	tris(diethyldithiocarbamato)rhodium(iii	NOUN
eurjchem-2544	91	7	)	)	PUNCT
eurjchem-2544	92	1	a	a	DET
eurjchem-2544	92	2	=	=	NOUN
eurjchem-2544	92	3	18.07(3	18.07(3	NUM
eurjchem-2544	92	4	)	)	PUNCT
eurjchem-2544	92	5	å	å	PROPN
eurjchem-2544	92	6	,	,	PUNCT
eurjchem-2544	92	7	b	b	X
eurjchem-2544	92	8	=	=	SYM
eurjchem-2544	92	9	8.276(3	8.276(3	PROPN
eurjchem-2544	92	10	)	)	PUNCT
eurjchem-2544	92	11	å	å	PROPN
eurjchem-2544	92	12	,	,	PUNCT
eurjchem-2544	92	13	c	c	NOUN
eurjchem-2544	92	14	=	=	SYM
eurjchem-2544	92	15	15.80(1	15.80(1	NUM
eurjchem-2544	92	16	)	)	PUNCT
eurjchem-2544	92	17	å	å	NOUN
eurjchem-2544	92	18	,	,	PUNCT
eurjchem-2544	92	19	β	β	X
eurjchem-2544	92	20	=	=	SYM
eurjchem-2544	92	21	96.35(4	96.35(4	NOUN
eurjchem-2544	92	22	)	)	PUNCT
eurjchem-2544	92	23	°	°	NOUN
eurjchem-2544	93	1	[	[	X
eurjchem-2544	93	2	50	50	NUM
eurjchem-2544	93	3	]	]	SYM
eurjchem-2544	93	4	18	18	NUM
eurjchem-2544	93	5	edtcir	edtcir	NOUN
eurjchem-2544	93	6	tris(diethyldithiocarbamato)iridium(iii	tris(diethyldithiocarbamato)iridium(iii	NOUN
eurjchem-2544	93	7	)	)	PUNCT
eurjchem-2544	93	8	a	a	DET
eurjchem-2544	93	9	=	=	SYM
eurjchem-2544	93	10	14.071(5	14.071(5	NOUN
eurjchem-2544	93	11	)	)	PUNCT
eurjchem-2544	94	1	å	å	NOUN
eurjchem-2544	94	2	.	.	PUNCT
eurjchem-2544	95	1	b	b	X
eurjchem-2544	95	2	=	=	SYM
eurjchem-2544	95	3	10.477(3	10.477(3	PROPN
eurjchem-2544	95	4	)	)	PUNCT
eurjchem-2544	96	1	å	å	NOUN
eurjchem-2544	96	2	,	,	PUNCT
eurjchem-2544	96	3	c	c	NOUN
eurjchem-2544	96	4	=	=	SYM
eurjchem-2544	96	5	16.980(5	16.980(5	NUM
eurjchem-2544	96	6	)	)	PUNCT
eurjchem-2544	96	7	å	å	NOUN
eurjchem-2544	96	8	,	,	PUNCT
eurjchem-2544	96	9	β	β	X
eurjchem-2544	96	10	=	=	SYM
eurjchem-2544	96	11	108.61(2	108.61(2	NUM
eurjchem-2544	96	12	)	)	PUNCT
eurjchem-2544	96	13	°	°	NOUN
eurjchem-2544	97	1	[	[	X
eurjchem-2544	97	2	52	52	NUM
eurjchem-2544	97	3	]	]	PUNCT
eurjchem-2544	97	4	figure	figure	NOUN
eurjchem-2544	97	5	2	2	NUM
eurjchem-2544	97	6	.	.	PUNCT
eurjchem-2544	98	1	the	the	DET
eurjchem-2544	98	2	stereo	stereo	ADJ
eurjchem-2544	98	3	pair	pair	NOUN
eurjchem-2544	98	4	of	of	ADP
eurjchem-2544	98	5	complex	complex	ADJ
eurjchem-2544	98	6	1	1	NUM
eurjchem-2544	98	7	with	with	ADP
eurjchem-2544	98	8	its	its	PRON
eurjchem-2544	98	9	2	2	NUM
eurjchem-2544	98	10	-	-	ADJ
eurjchem-2544	98	11	fold	fold	ADJ
eurjchem-2544	98	12	axis	axis	NOUN
eurjchem-2544	98	13	stretching	stretch	VERB
eurjchem-2544	98	14	through	through	ADP
eurjchem-2544	98	15	co	co	NOUN
eurjchem-2544	98	16	,	,	PUNCT
eurjchem-2544	98	17	c	c	NOUN
eurjchem-2544	98	18	,	,	PUNCT
eurjchem-2544	98	19	and	and	CCONJ
eurjchem-2544	98	20	carbamate	carbamate	PROPN
eurjchem-2544	98	21	n	n	PROPN
eurjchem-2544	98	22	[	[	X
eurjchem-2544	98	23	8	8	NUM
eurjchem-2544	98	24	]	]	SYM
eurjchem-2544	98	25	.	.	PUNCT
eurjchem-2544	99	1	2	2	X
eurjchem-2544	99	2	.	.	X
eurjchem-2544	99	3	single	single	ADJ
eurjchem-2544	99	4	dithiocarbamato	dithiocarbamato	NOUN
eurjchem-2544	99	5	and	and	CCONJ
eurjchem-2544	99	6	mixed	mixed	ADJ
eurjchem-2544	99	7	ligand	ligand	NOUN
eurjchem-2544	99	8	m(iii	m(iii	NOUN
eurjchem-2544	99	9	)	)	PUNCT
eurjchem-2544	99	10	complexes	complexe	VERB
eurjchem-2544	99	11	2.1	2.1	NUM
eurjchem-2544	99	12	.	.	PUNCT
eurjchem-2544	100	1	co(iii	co(iii	NOUN
eurjchem-2544	100	2	)	)	PUNCT
eurjchem-2544	100	3	complexes	complex	NOUN
eurjchem-2544	100	4	tris(diethyl(dithiocarbamato)-cobalt	tris(diethyl(dithiocarbamato)-cobalt	X
eurjchem-2544	100	5	(	(	PUNCT
eurjchem-2544	100	6	iii	iii	NOUN
eurjchem-2544	100	7	)	)	PUNCT
eurjchem-2544	100	8	(	(	PUNCT
eurjchem-2544	100	9	1	1	NUM
eurjchem-2544	100	10	,	,	PUNCT
eurjchem-2544	100	11	figure	figure	NOUN
eurjchem-2544	100	12	1	1	NUM
eurjchem-2544	100	13	)	)	PUNCT
eurjchem-2544	100	14	belongs	belong	VERB
eurjchem-2544	100	15	to	to	ADP
eurjchem-2544	100	16	the	the	DET
eurjchem-2544	100	17	monoclinic	monoclinic	ADJ
eurjchem-2544	100	18	crystal	crystal	NOUN
eurjchem-2544	100	19	system	system	NOUN
eurjchem-2544	100	20	with	with	ADP
eurjchem-2544	100	21	four	four	NUM
eurjchem-2544	100	22	molecules	molecule	NOUN
eurjchem-2544	100	23	in	in	ADP
eurjchem-2544	100	24	the	the	DET
eurjchem-2544	100	25	unit	unit	NOUN
eurjchem-2544	100	26	cell	cell	NOUN
eurjchem-2544	100	27	.	.	PUNCT
eurjchem-2544	101	1	the	the	DET
eurjchem-2544	101	2	observed	observed	ADJ
eurjchem-2544	101	3	extinctions	extinction	NOUN
eurjchem-2544	101	4	,	,	PUNCT
eurjchem-2544	101	5	hkl	hkl	NOUN
eurjchem-2544	101	6	(	(	PUNCT
eurjchem-2544	101	7	h+k≠2n	h+k≠2n	NUM
eurjchem-2544	101	8	)	)	PUNCT
eurjchem-2544	101	9	and	and	CCONJ
eurjchem-2544	101	10	hol	hol	NOUN
eurjchem-2544	101	11	(	(	PUNCT
eurjchem-2544	101	12	l≠2n	l≠2n	NOUN
eurjchem-2544	101	13	)	)	PUNCT
eurjchem-2544	101	14	are	be	AUX
eurjchem-2544	101	15	in	in	ADP
eurjchem-2544	101	16	agreement	agreement	NOUN
eurjchem-2544	101	17	with	with	ADP
eurjchem-2544	101	18	the	the	DET
eurjchem-2544	101	19	space	space	NOUN
eurjchem-2544	101	20	groups	group	NOUN
eurjchem-2544	101	21	c2	c2	PROPN
eurjchem-2544	101	22	/	/	SYM
eurjchem-2544	101	23	c	c	PROPN
eurjchem-2544	101	24	and	and	CCONJ
eurjchem-2544	101	25	cc	cc	PROPN
eurjchem-2544	101	26	,	,	PUNCT
eurjchem-2544	101	27	respectively	respectively	ADV
eurjchem-2544	101	28	[	[	X
eurjchem-2544	101	29	8	8	NUM
eurjchem-2544	101	30	]	]	PUNCT
eurjchem-2544	101	31	.	.	PUNCT
eurjchem-2544	102	1	with	with	ADP
eurjchem-2544	102	2	a	a	DET
eurjchem-2544	102	3	space	space	NOUN
eurjchem-2544	102	4	group	group	NOUN
eurjchem-2544	102	5	of	of	ADP
eurjchem-2544	102	6	c2	c2	PROPN
eurjchem-2544	102	7	/	/	SYM
eurjchem-2544	102	8	c	c	PROPN
eurjchem-2544	102	9	,	,	PUNCT
eurjchem-2544	102	10	the	the	DET
eurjchem-2544	102	11	entire	entire	ADJ
eurjchem-2544	102	12	molecule	molecule	NOUN
eurjchem-2544	102	13	is	be	AUX
eurjchem-2544	102	14	expected	expect	VERB
eurjchem-2544	102	15	to	to	PART
eurjchem-2544	102	16	possess	possess	VERB
eurjchem-2544	102	17	a	a	DET
eurjchem-2544	102	18	two	two	NUM
eurjchem-2544	102	19	-	-	PUNCT
eurjchem-2544	102	20	fold	fold	ADJ
eurjchem-2544	102	21	symmetry	symmetry	NOUN
eurjchem-2544	102	22	axis	axis	NOUN
eurjchem-2544	102	23	such	such	ADJ
eurjchem-2544	102	24	that	that	SCONJ
eurjchem-2544	102	25	the	the	DET
eurjchem-2544	102	26	central	central	ADJ
eurjchem-2544	102	27	co	co	NOUN
eurjchem-2544	102	28	occupies	occupy	VERB
eurjchem-2544	102	29	a	a	DET
eurjchem-2544	102	30	special	special	ADJ
eurjchem-2544	102	31	position	position	NOUN
eurjchem-2544	102	32	(	(	PUNCT
eurjchem-2544	102	33	4e	4e	NOUN
eurjchem-2544	102	34	)	)	PUNCT
eurjchem-2544	102	35	of	of	ADP
eurjchem-2544	102	36	the	the	DET
eurjchem-2544	102	37	space	space	NOUN
eurjchem-2544	102	38	group	group	NOUN
eurjchem-2544	102	39	.	.	PUNCT
eurjchem-2544	103	1	the	the	DET
eurjchem-2544	103	2	co	co	X
eurjchem-2544	103	3	atom	atom	NOUN
eurjchem-2544	103	4	bisects	bisect	NOUN
eurjchem-2544	103	5	one	one	NUM
eurjchem-2544	103	6	dithiocarbamate	dithiocarbamate	VERB
eurjchem-2544	103	7	ligand	ligand	NOUN
eurjchem-2544	103	8	,	,	PUNCT
eurjchem-2544	103	9	while	while	SCONJ
eurjchem-2544	103	10	all	all	DET
eurjchem-2544	103	11	atoms	atom	NOUN
eurjchem-2544	103	12	in	in	ADP
eurjchem-2544	103	13	the	the	DET
eurjchem-2544	103	14	second	second	ADJ
eurjchem-2544	103	15	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	103	16	ligand	ligand	NOUN
eurjchem-2544	103	17	lie	lie	NOUN
eurjchem-2544	103	18	in	in	ADP
eurjchem-2544	103	19	general	general	ADJ
eurjchem-2544	103	20	positions	position	NOUN
eurjchem-2544	103	21	and	and	CCONJ
eurjchem-2544	103	22	subsequently	subsequently	ADV
eurjchem-2544	103	23	take	take	VERB
eurjchem-2544	103	24	turns	turn	NOUN
eurjchem-2544	103	25	to	to	PART
eurjchem-2544	103	26	generate	generate	VERB
eurjchem-2544	103	27	the	the	DET
eurjchem-2544	103	28	third	third	ADJ
eurjchem-2544	103	29	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2544	103	30	ligand	ligand	NOUN
eurjchem-2544	103	31	via	via	ADP
eurjchem-2544	103	32	rotation	rotation	NOUN
eurjchem-2544	103	33	about	about	ADP
eurjchem-2544	103	34	the	the	DET
eurjchem-2544	103	35	2	2	NUM
eurjchem-2544	103	36	-	-	ADJ
eurjchem-2544	103	37	fold	fold	ADJ
eurjchem-2544	103	38	axis	axis	NOUN
eurjchem-2544	103	39	(	(	PUNCT
eurjchem-2544	103	40	figure	figure	NOUN
eurjchem-2544	103	41	2	2	NUM
eurjchem-2544	103	42	)	)	PUNCT
eurjchem-2544	103	43	.	.	PUNCT
eurjchem-2544	104	1	it	it	PRON
eurjchem-2544	104	2	is	be	AUX
eurjchem-2544	104	3	obvious	obvious	ADJ
eurjchem-2544	104	4	that	that	SCONJ
eurjchem-2544	104	5	the	the	DET
eurjchem-2544	104	6	six	six	NUM
eurjchem-2544	104	7	sulfur	sulfur	NOUN
eurjchem-2544	104	8	atoms	atom	NOUN
eurjchem-2544	104	9	around	around	ADP
eurjchem-2544	104	10	the	the	DET
eurjchem-2544	104	11	cobalt	cobalt	NOUN
eurjchem-2544	104	12	center	center	NOUN
eurjchem-2544	104	13	form	form	VERB
eurjchem-2544	104	14	a	a	DET
eurjchem-2544	104	15	geometry	geometry	NOUN
eurjchem-2544	104	16	that	that	PRON
eurjchem-2544	104	17	is	be	AUX
eurjchem-2544	104	18	quite	quite	ADV
eurjchem-2544	104	19	distorted	distort	VERB
eurjchem-2544	104	20	from	from	ADP
eurjchem-2544	104	21	the	the	DET
eurjchem-2544	104	22	regular	regular	ADJ
eurjchem-2544	104	23	octahedron	octahedron	NOUN
eurjchem-2544	105	1	[	[	PUNCT
eurjchem-2544	105	2	as	as	SCONJ
eurjchem-2544	105	3	seen	see	VERB
eurjchem-2544	105	4	in	in	ADP
eurjchem-2544	105	5	the	the	DET
eurjchem-2544	105	6	s	s	PROPN
eurjchem-2544	105	7	-	-	PUNCT
eurjchem-2544	105	8	co	co	NOUN
eurjchem-2544	105	9	-	-	ADJ
eurjchem-2544	105	10	s	s	PART
eurjchem-2544	105	11	bond	bond	NOUN
eurjchem-2544	105	12	angles	angle	NOUN
eurjchem-2544	105	13	of	of	ADP
eurjchem-2544	105	14	166.21(12	166.21(12	NUM
eurjchem-2544	105	15	)	)	PUNCT
eurjchem-2544	105	16	°	°	NUM
eurjchem-2544	105	17	and	and	CCONJ
eurjchem-2544	105	18	166.51(9)	166.51(9)	NUM
eurjchem-2544	105	19	°	°	PROPN
eurjchem-2544	105	20	.	.	PUNCT
eurjchem-2544	106	1	these	these	DET
eurjchem-2544	106	2	distortions	distortion	NOUN
eurjchem-2544	106	3	are	be	AUX
eurjchem-2544	106	4	attributed	attribute	VERB
eurjchem-2544	106	5	to	to	ADP
eurjchem-2544	106	6	the	the	DET
eurjchem-2544	106	7	imposition	imposition	NOUN
eurjchem-2544	106	8	of	of	ADP
eurjchem-2544	106	9	constraints	constraint	NOUN
eurjchem-2544	106	10	on	on	ADP
eurjchem-2544	106	11	the	the	DET
eurjchem-2544	106	12	entire	entire	ADJ
eurjchem-2544	106	13	geometry	geometry	NOUN
eurjchem-2544	106	14	of	of	ADP
eurjchem-2544	106	15	the	the	DET
eurjchem-2544	106	16	molecule	molecule	NOUN
eurjchem-2544	106	17	by	by	ADP
eurjchem-2544	106	18	the	the	DET
eurjchem-2544	106	19	rigidity	rigidity	NOUN
eurjchem-2544	106	20	of	of	ADP
eurjchem-2544	106	21	the	the	DET
eurjchem-2544	106	22	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	106	23	ligands	ligand	NOUN
eurjchem-2544	106	24	and	and	CCONJ
eurjchem-2544	106	25	the	the	DET
eurjchem-2544	106	26	small	small	ADJ
eurjchem-2544	106	27	bites	bite	NOUN
eurjchem-2544	106	28	of	of	ADP
eurjchem-2544	106	29	the	the	DET
eurjchem-2544	106	30	metal	metal	NOUN
eurjchem-2544	106	31	centers	center	NOUN
eurjchem-2544	106	32	,	,	PUNCT
eurjchem-2544	106	33	which	which	PRON
eurjchem-2544	106	34	are	be	AUX
eurjchem-2544	106	35	s	s	NOUN
eurjchem-2544	106	36	-	-	ADJ
eurjchem-2544	106	37	co	co	NOUN
eurjchem-2544	106	38	-	-	NOUN
eurjchem-2544	106	39	s	s	X
eurjchem-2544	106	40	=	=	NOUN
eurjchem-2544	106	41	76.50(14	76.50(14	NUM
eurjchem-2544	106	42	)	)	PUNCT
eurjchem-2544	106	43	°	°	NUM
eurjchem-2544	106	44	and	and	CCONJ
eurjchem-2544	106	45	76.05(10)	76.05(10)	NUM
eurjchem-2544	106	46	°	°	NUM
eurjchem-2544	106	47	.	.	PUNCT
eurjchem-2544	107	1	in	in	ADP
eurjchem-2544	107	2	comparison	comparison	NOUN
eurjchem-2544	107	3	with	with	ADP
eurjchem-2544	107	4	other	other	ADJ
eurjchem-2544	107	5	similar	similar	ADJ
eurjchem-2544	107	6	complexes	complex	NOUN
eurjchem-2544	107	7	such	such	ADJ
eurjchem-2544	107	8	as	as	ADP
eurjchem-2544	107	9	fe(co)2[s2cn(ch2)5]2	fe(co)2[s2cn(ch2)5]2	NOUN
eurjchem-2544	107	10	[	[	PUNCT
eurjchem-2544	107	11	8	8	NUM
eurjchem-2544	107	12	]	]	PUNCT
eurjchem-2544	107	13	,	,	PUNCT
eurjchem-2544	107	14	ni[s2cn(c2h5)2]2	ni[s2cn(c2h5)2]2	PROPN
eurjchem-2544	107	15	[	[	X
eurjchem-2544	107	16	27	27	NUM
eurjchem-2544	107	17	]	]	PUNCT
eurjchem-2544	107	18	,	,	PUNCT
eurjchem-2544	107	19	cuii[s2cn(c2h5)2]2	cuii[s2cn(c2h5)2]2	VERB
eurjchem-2544	108	1	[	[	X
eurjchem-2544	108	2	28	28	NUM
eurjchem-2544	108	3	]	]	PUNCT
eurjchem-2544	108	4	and	and	CCONJ
eurjchem-2544	108	5	znii[s2cn(ch3)2]2	znii[s2cn(ch3)2]2	PROPN
eurjchem-2544	109	1	[	[	X
eurjchem-2544	109	2	8	8	NUM
eurjchem-2544	109	3	]	]	PUNCT
eurjchem-2544	109	4	,	,	PUNCT
eurjchem-2544	109	5	the	the	DET
eurjchem-2544	109	6	s	s	NOUN
eurjchem-2544	109	7	-	-	PUNCT
eurjchem-2544	109	8	c	c	NOUN
eurjchem-2544	109	9	,	,	PUNCT
eurjchem-2544	109	10	c	c	NOUN
eurjchem-2544	109	11	-	-	PUNCT
eurjchem-2544	109	12	n	n	NOUN
eurjchem-2544	109	13	and	and	CCONJ
eurjchem-2544	109	14	n	n	CCONJ
eurjchem-2544	109	15	-	-	PUNCT
eurjchem-2544	109	16	calkyl	calkyl	PROPN
eurjchem-2544	109	17	bond	bond	NOUN
eurjchem-2544	109	18	distances	distance	NOUN
eurjchem-2544	109	19	are	be	AUX
eurjchem-2544	109	20	in	in	ADP
eurjchem-2544	109	21	close	close	ADJ
eurjchem-2544	109	22	alignment	alignment	NOUN
eurjchem-2544	109	23	except	except	SCONJ
eurjchem-2544	109	24	for	for	ADP
eurjchem-2544	109	25	the	the	DET
eurjchem-2544	109	26	m	m	PROPN
eurjchem-2544	109	27	-	-	PUNCT
eurjchem-2544	109	28	s	s	PART
eurjchem-2544	109	29	bonds	bond	NOUN
eurjchem-2544	109	30	whose	whose	DET
eurjchem-2544	109	31	variations	variation	NOUN
eurjchem-2544	109	32	were	be	AUX
eurjchem-2544	109	33	expected	expect	VERB
eurjchem-2544	109	34	to	to	PART
eurjchem-2544	109	35	align	align	VERB
eurjchem-2544	109	36	with	with	ADP
eurjchem-2544	109	37	the	the	DET
eurjchem-2544	109	38	ionic	ionic	ADJ
eurjchem-2544	109	39	radii	radius	NOUN
eurjchem-2544	109	40	of	of	ADP
eurjchem-2544	109	41	the	the	DET
eurjchem-2544	109	42	central	central	ADJ
eurjchem-2544	109	43	metal	metal	NOUN
eurjchem-2544	109	44	ions	ion	NOUN
eurjchem-2544	109	45	,	,	PUNCT
eurjchem-2544	109	46	but	but	CCONJ
eurjchem-2544	109	47	this	this	PRON
eurjchem-2544	109	48	was	be	AUX
eurjchem-2544	109	49	never	never	ADV
eurjchem-2544	109	50	the	the	DET
eurjchem-2544	109	51	case	case	NOUN
eurjchem-2544	109	52	.	.	PUNCT
eurjchem-2544	110	1	for	for	ADP
eurjchem-2544	110	2	instance	instance	NOUN
eurjchem-2544	110	3	,	,	PUNCT
eurjchem-2544	110	4	the	the	PRON
eurjchem-2544	110	5	longer	long	ADJ
eurjchem-2544	110	6	fe	fe	X
eurjchem-2544	110	7	-	-	PUNCT
eurjchem-2544	110	8	s	s	NOUN
eurjchem-2544	110	9	bond	bond	NOUN
eurjchem-2544	110	10	compared	compare	VERB
eurjchem-2544	110	11	to	to	ADP
eurjchem-2544	110	12	co	co	VERB
eurjchem-2544	110	13	-	-	NOUN
eurjchem-2544	110	14	s	s	PART
eurjchem-2544	110	15	bond	bond	NOUN
eurjchem-2544	110	16	does	do	AUX
eurjchem-2544	110	17	not	not	PART
eurjchem-2544	110	18	align	align	VERB
eurjchem-2544	110	19	with	with	ADP
eurjchem-2544	110	20	the	the	DET
eurjchem-2544	110	21	difference	difference	NOUN
eurjchem-2544	110	22	in	in	ADP
eurjchem-2544	110	23	their	their	PRON
eurjchem-2544	110	24	ionic	ionic	ADJ
eurjchem-2544	110	25	radii	radius	NOUN
eurjchem-2544	110	26	but	but	CCONJ
eurjchem-2544	110	27	reflects	reflect	VERB
eurjchem-2544	110	28	the	the	DET
eurjchem-2544	110	29	differences	difference	NOUN
eurjchem-2544	110	30	in	in	ADP
eurjchem-2544	110	31	their	their	PRON
eurjchem-2544	110	32	individual	individual	ADJ
eurjchem-2544	110	33	charges	charge	NOUN
eurjchem-2544	110	34	.	.	PUNCT
eurjchem-2544	111	1	ni(ii	ni(ii	NOUN
eurjchem-2544	111	2	)	)	PUNCT
eurjchem-2544	111	3	,	,	PUNCT
eurjchem-2544	111	4	cu(ii	cu(ii	PROPN
eurjchem-2544	111	5	)	)	PUNCT
eurjchem-2544	111	6	,	,	PUNCT
eurjchem-2544	111	7	and	and	CCONJ
eurjchem-2544	111	8	zn(ii	zn(ii	NOUN
eurjchem-2544	111	9	)	)	PUNCT
eurjchem-2544	111	10	on	on	ADP
eurjchem-2544	111	11	the	the	DET
eurjchem-2544	111	12	other	other	ADJ
eurjchem-2544	111	13	hand	hand	NOUN
eurjchem-2544	111	14	,	,	PUNCT
eurjchem-2544	111	15	possess	possess	VERB
eurjchem-2544	111	16	smaller	small	ADJ
eurjchem-2544	111	17	m	m	NOUN
eurjchem-2544	111	18	-	-	PUNCT
eurjchem-2544	111	19	s	s	PART
eurjchem-2544	111	20	bonds	bond	NOUN
eurjchem-2544	111	21	compared	compare	VERB
eurjchem-2544	111	22	to	to	ADP
eurjchem-2544	111	23	294	294	NUM
eurjchem-2544	111	24	shotonwa	shotonwa	ADJ
eurjchem-2544	111	25	et	et	PROPN
eurjchem-2544	111	26	al	al	PROPN
eurjchem-2544	111	27	.	.	PUNCT
eurjchem-2544	111	28	/	/	SYM
eurjchem-2544	111	29	european	european	PROPN
eurjchem-2544	111	30	journal	journal	PROPN
eurjchem-2544	111	31	of	of	ADP
eurjchem-2544	111	32	chemistry	chemistry	NOUN
eurjchem-2544	111	33	15	15	NUM
eurjchem-2544	111	34	(	(	PUNCT
eurjchem-2544	111	35	3	3	NUM
eurjchem-2544	111	36	)	)	PUNCT
eurjchem-2544	111	37	(	(	PUNCT
eurjchem-2544	111	38	2024	2024	NUM
eurjchem-2544	111	39	)	)	PUNCT
eurjchem-2544	111	40	291	291	NUM
eurjchem-2544	111	41	-	-	SYM
eurjchem-2544	111	42	301	301	NUM
eurjchem-2544	111	43	2024	2024	NUM
eurjchem-2544	111	44	–	–	PUNCT
eurjchem-2544	111	45	european	european	ADJ
eurjchem-2544	111	46	journal	journal	NOUN
eurjchem-2544	111	47	of	of	ADP
eurjchem-2544	111	48	chemistry	chemistry	NOUN
eurjchem-2544	111	49	–	–	PUNCT
eurjchem-2544	111	50	cc	cc	NOUN
eurjchem-2544	111	51	by	by	ADP
eurjchem-2544	111	52	nc	nc	PROPN
eurjchem-2544	111	53	–	–	PUNCT
eurjchem-2544	111	54	doi	doi	PROPN
eurjchem-2544	111	55	:	:	PUNCT
eurjchem-2544	111	56	10.5155	10.5155	NUM
eurjchem-2544	111	57	/	/	SYM
eurjchem-2544	111	58	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	111	59	-	-	PUNCT
eurjchem-2544	111	60	301.2544	301.2544	NUM
eurjchem-2544	111	61	figure	figure	NOUN
eurjchem-2544	111	62	3	3	NUM
eurjchem-2544	111	63	.	.	PUNCT
eurjchem-2544	111	64	molecular	molecular	ADJ
eurjchem-2544	111	65	structure	structure	NOUN
eurjchem-2544	111	66	of	of	ADP
eurjchem-2544	111	67	complexes	complex	NOUN
eurjchem-2544	111	68	2	2	NUM
eurjchem-2544	111	69	and	and	CCONJ
eurjchem-2544	111	70	3	3	NUM
eurjchem-2544	111	71	.	.	X
eurjchem-2544	111	72	figure	figure	NOUN
eurjchem-2544	111	73	4	4	NUM
eurjchem-2544	111	74	.	.	PUNCT
eurjchem-2544	111	75	molecular	molecular	ADJ
eurjchem-2544	111	76	structure	structure	NOUN
eurjchem-2544	111	77	of	of	ADP
eurjchem-2544	111	78	complexes	complex	NOUN
eurjchem-2544	111	79	4	4	NUM
eurjchem-2544	111	80	and	and	CCONJ
eurjchem-2544	111	81	5	5	NUM
eurjchem-2544	111	82	.	.	X
eurjchem-2544	112	1	those	those	PRON
eurjchem-2544	112	2	of	of	ADP
eurjchem-2544	112	3	co	co	NOUN
eurjchem-2544	112	4	and	and	CCONJ
eurjchem-2544	112	5	fe	fe	X
eurjchem-2544	112	6	despite	despite	SCONJ
eurjchem-2544	112	7	possessing	possess	VERB
eurjchem-2544	112	8	higher	high	ADJ
eurjchem-2544	112	9	ionic	ionic	ADJ
eurjchem-2544	112	10	radii	radius	NOUN
eurjchem-2544	112	11	of	of	ADP
eurjchem-2544	112	12	0.69	0.69	NUM
eurjchem-2544	112	13	,	,	PUNCT
eurjchem-2544	112	14	0.72	0.72	NUM
eurjchem-2544	112	15	and	and	CCONJ
eurjchem-2544	112	16	0.74	0.74	NUM
eurjchem-2544	112	17	å	å	PROPN
eurjchem-2544	112	18	(	(	PUNCT
eurjchem-2544	112	19	compared	compare	VERB
eurjchem-2544	112	20	to	to	ADP
eurjchem-2544	112	21	0.64	0.64	NUM
eurjchem-2544	112	22	å	å	NOUN
eurjchem-2544	112	23	for	for	ADP
eurjchem-2544	112	24	fe(ii	fe(ii	PROPN
eurjchem-2544	112	25	)	)	PUNCT
eurjchem-2544	112	26	and	and	CCONJ
eurjchem-2544	112	27	0.63	0.63	NUM
eurjchem-2544	112	28	å	å	PROPN
eurjchem-2544	112	29	for	for	ADP
eurjchem-2544	112	30	co(ii	co(ii	PROPN
eurjchem-2544	112	31	)	)	PUNCT
eurjchem-2544	112	32	)	)	PUNCT
eurjchem-2544	112	33	.	.	PUNCT
eurjchem-2544	113	1	one	one	NUM
eurjchem-2544	113	2	important	important	ADJ
eurjchem-2544	113	3	factor	factor	NOUN
eurjchem-2544	113	4	that	that	PRON
eurjchem-2544	113	5	accounted	account	VERB
eurjchem-2544	113	6	for	for	ADP
eurjchem-2544	113	7	the	the	DET
eurjchem-2544	113	8	variation	variation	NOUN
eurjchem-2544	113	9	in	in	ADP
eurjchem-2544	113	10	m	m	PROPN
eurjchem-2544	113	11	-	-	PUNCT
eurjchem-2544	113	12	s	s	PART
eurjchem-2544	113	13	bonds	bond	NOUN
eurjchem-2544	113	14	is	be	AUX
eurjchem-2544	113	15	the	the	DET
eurjchem-2544	113	16	coordination	coordination	NOUN
eurjchem-2544	113	17	about	about	ADP
eurjchem-2544	113	18	the	the	DET
eurjchem-2544	113	19	metal	metal	NOUN
eurjchem-2544	113	20	centre	centre	NOUN
eurjchem-2544	113	21	.	.	PUNCT
eurjchem-2544	114	1	fe(iii	fe(iii	NOUN
eurjchem-2544	114	2	)	)	PUNCT
eurjchem-2544	114	3	and	and	CCONJ
eurjchem-2544	114	4	co(iii)i	co(iii)i	ADV
eurjchem-2544	114	5	in	in	ADP
eurjchem-2544	114	6	complex	complex	ADJ
eurjchem-2544	114	7	1	1	NUM
eurjchem-2544	114	8	(	(	PUNCT
eurjchem-2544	114	9	figure	figure	NOUN
eurjchem-2544	114	10	1	1	NUM
eurjchem-2544	114	11	)	)	PUNCT
eurjchem-2544	114	12	are	be	AUX
eurjchem-2544	114	13	hexacoordinated	hexacoordinate	VERB
eurjchem-2544	114	14	,	,	PUNCT
eurjchem-2544	114	15	while	while	SCONJ
eurjchem-2544	114	16	the	the	DET
eurjchem-2544	114	17	ni	ni	PROPN
eurjchem-2544	114	18	,	,	PUNCT
eurjchem-2544	114	19	cu	cu	PROPN
eurjchem-2544	114	20	,	,	PUNCT
eurjchem-2544	114	21	and	and	CCONJ
eurjchem-2544	114	22	zn	zn	PROPN
eurjchem-2544	114	23	complex	complex	NOUN
eurjchem-2544	114	24	are	be	AUX
eurjchem-2544	114	25	tetracoordinated	tetracoordinate	VERB
eurjchem-2544	114	26	with	with	ADP
eurjchem-2544	114	27	ni	ni	PROPN
eurjchem-2544	114	28	-	-	PUNCT
eurjchem-2544	114	29	s	s	NOUN
eurjchem-2544	114	30	bond	bond	NOUN
eurjchem-2544	114	31	distances	distance	NOUN
eurjchem-2544	114	32	in	in	ADP
eurjchem-2544	114	33	the	the	DET
eurjchem-2544	114	34	range	range	NOUN
eurjchem-2544	114	35	of	of	ADP
eurjchem-2544	114	36	2.1	2.1	NUM
eurjchem-2544	114	37	-	-	SYM
eurjchem-2544	114	38	2.3	2.3	NUM
eurjchem-2544	114	39	å	å	NOUN
eurjchem-2544	114	40	compared	compare	VERB
eurjchem-2544	114	41	to	to	ADP
eurjchem-2544	114	42	2.4	2.4	NUM
eurjchem-2544	114	43	-	-	SYM
eurjchem-2544	114	44	2.6	2.6	NUM
eurjchem-2544	114	45	å	å	PROPN
eurjchem-2544	114	46	reported	report	VERB
eurjchem-2544	114	47	for	for	ADP
eurjchem-2544	114	48	hexacoordinated	hexacoordinate	VERB
eurjchem-2544	114	49	ni	ni	PROPN
eurjchem-2544	114	50	-	-	PUNCT
eurjchem-2544	114	51	s	s	X
eurjchem-2544	114	52	[	[	X
eurjchem-2544	114	53	8	8	NUM
eurjchem-2544	114	54	]	]	PUNCT
eurjchem-2544	114	55	.	.	PUNCT
eurjchem-2544	115	1	similarly	similarly	ADV
eurjchem-2544	115	2	,	,	PUNCT
eurjchem-2544	115	3	the	the	DET
eurjchem-2544	115	4	m	m	PROPN
eurjchem-2544	115	5	-	-	PUNCT
eurjchem-2544	115	6	s	s	PART
eurjchem-2544	115	7	bond	bond	NOUN
eurjchem-2544	115	8	distances	distance	NOUN
eurjchem-2544	115	9	in	in	ADP
eurjchem-2544	115	10	the	the	DET
eurjchem-2544	115	11	hexacoordinated	hexacoordinate	VERB
eurjchem-2544	115	12	cu(ii	cu(ii	PROPN
eurjchem-2544	115	13	)	)	PUNCT
eurjchem-2544	115	14	and	and	CCONJ
eurjchem-2544	115	15	zn(ii	zn(ii	NOUN
eurjchem-2544	115	16	)	)	PUNCT
eurjchem-2544	115	17	are	be	AUX
eurjchem-2544	115	18	0.2	0.2	NUM
eurjchem-2544	115	19	-	-	SYM
eurjchem-2544	115	20	0.3	0.3	NUM
eurjchem-2544	115	21	å	å	NOUN
eurjchem-2544	115	22	longer	long	ADV
eurjchem-2544	115	23	than	than	ADP
eurjchem-2544	115	24	those	those	PRON
eurjchem-2544	115	25	found	find	VERB
eurjchem-2544	115	26	in	in	ADP
eurjchem-2544	115	27	their	their	PRON
eurjchem-2544	115	28	tetracoordinated	tetracoordinate	VERB
eurjchem-2544	115	29	congeners	congener	NOUN
eurjchem-2544	115	30	.	.	PUNCT
eurjchem-2544	116	1	the	the	DET
eurjchem-2544	116	2	1.303	1.303	NUM
eurjchem-2544	116	3	and	and	CCONJ
eurjchem-2544	116	4	1.315	1.315	NUM
eurjchem-2544	116	5	å	å	PROPN
eurjchem-2544	116	6	reported	report	VERB
eurjchem-2544	116	7	for	for	ADP
eurjchem-2544	116	8	the	the	DET
eurjchem-2544	116	9	c	c	NOUN
eurjchem-2544	116	10	-	-	PUNCT
eurjchem-2544	116	11	n	n	NOUN
eurjchem-2544	116	12	bonds	bond	NOUN
eurjchem-2544	116	13	are	be	AUX
eurjchem-2544	116	14	strong	strong	ADJ
eurjchem-2544	116	15	indications	indication	NOUN
eurjchem-2544	116	16	of	of	ADP
eurjchem-2544	116	17	a	a	DET
eurjchem-2544	116	18	high	high	ADJ
eurjchem-2544	116	19	degree	degree	NOUN
eurjchem-2544	116	20	of	of	ADP
eurjchem-2544	116	21	double	double	ADJ
eurjchem-2544	116	22	bond	bond	NOUN
eurjchem-2544	116	23	character	character	NOUN
eurjchem-2544	116	24	initiated	initiate	VERB
eurjchem-2544	116	25	by	by	ADP
eurjchem-2544	116	26	the	the	DET
eurjchem-2544	116	27	canonical	canonical	ADJ
eurjchem-2544	116	28	form	form	NOUN
eurjchem-2544	116	29	(	(	PUNCT
eurjchem-2544	116	30	ii	ii	NOUN
eurjchem-2544	116	31	in	in	ADP
eurjchem-2544	116	32	scheme	scheme	NOUN
eurjchem-2544	116	33	1	1	NUM
eurjchem-2544	116	34	)	)	PUNCT
eurjchem-2544	116	35	.	.	PUNCT
eurjchem-2544	117	1	the	the	DET
eurjchem-2544	117	2	canonical	canonical	ADJ
eurjchem-2544	117	3	structure	structure	NOUN
eurjchem-2544	117	4	also	also	ADV
eurjchem-2544	117	5	supports	support	VERB
eurjchem-2544	117	6	identical	identical	ADJ
eurjchem-2544	117	7	c	c	NOUN
eurjchem-2544	117	8	-	-	PUNCT
eurjchem-2544	117	9	s	s	NOUN
eurjchem-2544	117	10	bond	bond	NOUN
eurjchem-2544	117	11	lengths	length	NOUN
eurjchem-2544	117	12	through	through	ADP
eurjchem-2544	117	13	the	the	DET
eurjchem-2544	117	14	trigonal	trigonal	ADJ
eurjchem-2544	117	15	sp2	sp2	NOUN
eurjchem-2544	117	16	angles	angle	NOUN
eurjchem-2544	117	17	of	of	ADP
eurjchem-2544	117	18	117.78	117.78	NUM
eurjchem-2544	117	19	-	-	SYM
eurjchem-2544	117	20	121.11	121.11	NUM
eurjchem-2544	117	21	°	°	NOUN
eurjchem-2544	117	22	around	around	ADP
eurjchem-2544	117	23	carbamate	carbamate	NOUN
eurjchem-2544	117	24	n	n	NOUN
eurjchem-2544	117	25	atoms	atom	NOUN
eurjchem-2544	117	26	and	and	CCONJ
eurjchem-2544	117	27	the	the	DET
eurjchem-2544	117	28	planarity	planarity	NOUN
eurjchem-2544	117	29	of	of	ADP
eurjchem-2544	117	30	cos2cn	cos2cn	PROPN
eurjchem-2544	117	31	fragments	fragment	NOUN
eurjchem-2544	117	32	[	[	X
eurjchem-2544	117	33	29	29	NUM
eurjchem-2544	117	34	]	]	PUNCT
eurjchem-2544	117	35	.	.	PUNCT
eurjchem-2544	118	1	complex	complex	ADJ
eurjchem-2544	118	2	1	1	NUM
eurjchem-2544	118	3	has	have	VERB
eurjchem-2544	118	4	six	six	NUM
eurjchem-2544	118	5	similar	similar	ADJ
eurjchem-2544	118	6	complexes	complex	NOUN
eurjchem-2544	118	7	which	which	PRON
eurjchem-2544	118	8	also	also	ADV
eurjchem-2544	118	9	crystallized	crystallize	VERB
eurjchem-2544	118	10	in	in	ADP
eurjchem-2544	118	11	the	the	DET
eurjchem-2544	118	12	c2	c2	PROPN
eurjchem-2544	118	13	/	/	SYM
eurjchem-2544	118	14	c	c	PROPN
eurjchem-2544	118	15	space	space	NOUN
eurjchem-2544	118	16	group	group	NOUN
eurjchem-2544	118	17	[	[	X
eurjchem-2544	118	18	24	24	NUM
eurjchem-2544	118	19	]	]	PUNCT
eurjchem-2544	118	20	.	.	PUNCT
eurjchem-2544	119	1	with	with	ADP
eurjchem-2544	119	2	emphasis	emphasis	NOUN
eurjchem-2544	119	3	on	on	ADP
eurjchem-2544	119	4	one	one	NUM
eurjchem-2544	119	5	of	of	ADP
eurjchem-2544	119	6	the	the	DET
eurjchem-2544	119	7	variants	variant	NOUN
eurjchem-2544	119	8	of	of	ADP
eurjchem-2544	119	9	complex	complex	ADJ
eurjchem-2544	119	10	1	1	NUM
eurjchem-2544	119	11	(	(	PUNCT
eurjchem-2544	119	12	etdcco06	etdcco06	NOUN
eurjchem-2544	119	13	)	)	PUNCT
eurjchem-2544	120	1	[	[	X
eurjchem-2544	120	2	30	30	NUM
eurjchem-2544	120	3	]	]	PUNCT
eurjchem-2544	120	4	,	,	PUNCT
eurjchem-2544	120	5	h···s	h···	VERB
eurjchem-2544	120	6	contacts	contact	NOUN
eurjchem-2544	120	7	in	in	ADP
eurjchem-2544	120	8	the	the	DET
eurjchem-2544	120	9	range	range	NOUN
eurjchem-2544	120	10	2.979	2.979	NUM
eurjchem-2544	120	11	-	-	SYM
eurjchem-2544	120	12	2.998	2.998	NUM
eurjchem-2544	120	13	å	å	NOUN
eurjchem-2544	120	14	with	with	ADP
eurjchem-2544	120	15	methyland	methyland	NOUN
eurjchem-2544	120	16	methylene	methylene	NOUN
eurjchem-2544	120	17	c	c	NOUN
eurjchem-2544	120	18	-	-	PUNCT
eurjchem-2544	120	19	h	h	NOUN
eurjchem-2544	120	20	donors	donor	NOUN
eurjchem-2544	120	21	.	.	PUNCT
eurjchem-2544	121	1	coiii	coiii	PROPN
eurjchem-2544	121	2	tris(dipropyldithiocarbamate	tris(dipropyldithiocarbamate	PROPN
eurjchem-2544	121	3	)	)	PUNCT
eurjchem-2544	121	4	(	(	PUNCT
eurjchem-2544	121	5	2	2	NUM
eurjchem-2544	121	6	,	,	PUNCT
eurjchem-2544	121	7	figure	figure	VERB
eurjchem-2544	121	8	3	3	NUM
eurjchem-2544	121	9	)	)	PUNCT
eurjchem-2544	121	10	crystallizes	crystallize	NOUN
eurjchem-2544	121	11	in	in	ADP
eurjchem-2544	121	12	the	the	DET
eurjchem-2544	121	13	r-3c	r-3c	PROPN
eurjchem-2544	121	14	space	space	NOUN
eurjchem-2544	121	15	group	group	NOUN
eurjchem-2544	121	16	of	of	ADP
eurjchem-2544	121	17	the	the	DET
eurjchem-2544	121	18	rhombohedral	rhombohedral	ADJ
eurjchem-2544	121	19	crystal	crystal	NOUN
eurjchem-2544	121	20	system	system	NOUN
eurjchem-2544	121	21	.	.	PUNCT
eurjchem-2544	122	1	its	its	PRON
eurjchem-2544	122	2	unit	unit	NOUN
eurjchem-2544	122	3	cell	cell	NOUN
eurjchem-2544	122	4	is	be	AUX
eurjchem-2544	122	5	made	make	VERB
eurjchem-2544	122	6	up	up	ADP
eurjchem-2544	122	7	of	of	ADP
eurjchem-2544	122	8	six	six	NUM
eurjchem-2544	122	9	discrete	discrete	ADJ
eurjchem-2544	122	10	monomeric	monomeric	ADJ
eurjchem-2544	122	11	molecules	molecule	NOUN
eurjchem-2544	122	12	such	such	ADJ
eurjchem-2544	122	13	that	that	SCONJ
eurjchem-2544	122	14	the	the	DET
eurjchem-2544	122	15	co	co	NOUN
eurjchem-2544	122	16	ion	ion	NOUN
eurjchem-2544	122	17	is	be	AUX
eurjchem-2544	122	18	the	the	DET
eurjchem-2544	122	19	intersection	intersection	NOUN
eurjchem-2544	122	20	of	of	ADP
eurjchem-2544	122	21	the	the	DET
eurjchem-2544	122	22	mutually	mutually	ADV
eurjchem-2544	122	23	perpendicular	perpendicular	ADJ
eurjchem-2544	122	24	3	3	NOUN
eurjchem-2544	122	25	-	-	NOUN
eurjchem-2544	122	26	fold	fold	ADJ
eurjchem-2544	122	27	and	and	CCONJ
eurjchem-2544	122	28	2	2	ADJ
eurjchem-2544	122	29	-	-	ADJ
eurjchem-2544	122	30	fold	fold	ADJ
eurjchem-2544	122	31	axes	axis	NOUN
eurjchem-2544	122	32	[	[	X
eurjchem-2544	122	33	12	12	NUM
eurjchem-2544	122	34	]	]	PUNCT
eurjchem-2544	122	35	.	.	PUNCT
eurjchem-2544	123	1	the	the	DET
eurjchem-2544	123	2	central	central	ADJ
eurjchem-2544	123	3	co	co	NOUN
eurjchem-2544	123	4	is	be	AUX
eurjchem-2544	123	5	coordinated	coordinate	VERB
eurjchem-2544	123	6	bidentately	bidentately	ADV
eurjchem-2544	123	7	to	to	ADP
eurjchem-2544	123	8	three	three	NUM
eurjchem-2544	123	9	[	[	X
eurjchem-2544	123	10	s2cnpr2	s2cnpr2	X
eurjchem-2544	123	11	]	]	X
eurjchem-2544	123	12	ligands	ligand	NOUN
eurjchem-2544	123	13	that	that	PRON
eurjchem-2544	123	14	are	be	AUX
eurjchem-2544	123	15	related	relate	VERB
eurjchem-2544	123	16	by	by	ADP
eurjchem-2544	123	17	the	the	DET
eurjchem-2544	123	18	3	3	NUM
eurjchem-2544	123	19	-	-	ADJ
eurjchem-2544	123	20	fold	fold	ADJ
eurjchem-2544	123	21	axis	axis	NOUN
eurjchem-2544	123	22	.	.	PUNCT
eurjchem-2544	124	1	the	the	DET
eurjchem-2544	124	2	distorted	distort	VERB
eurjchem-2544	124	3	hexacoordinated	hexacoordinate	VERB
eurjchem-2544	124	4	geometry	geometry	NOUN
eurjchem-2544	124	5	around	around	ADP
eurjchem-2544	124	6	the	the	DET
eurjchem-2544	124	7	central	central	ADJ
eurjchem-2544	124	8	co	co	NOUN
eurjchem-2544	124	9	is	be	AUX
eurjchem-2544	124	10	formed	form	VERB
eurjchem-2544	124	11	by	by	ADP
eurjchem-2544	124	12	the	the	DET
eurjchem-2544	124	13	meridional	meridional	ADJ
eurjchem-2544	124	14	arrangement	arrangement	NOUN
eurjchem-2544	124	15	of	of	ADP
eurjchem-2544	124	16	the	the	DET
eurjchem-2544	124	17	six	six	NUM
eurjchem-2544	124	18	s	s	NOUN
eurjchem-2544	124	19	atoms	atom	NOUN
eurjchem-2544	124	20	around	around	ADP
eurjchem-2544	124	21	it	it	PRON
eurjchem-2544	124	22	.	.	PUNCT
eurjchem-2544	125	1	its	its	PRON
eurjchem-2544	125	2	distortion	distortion	NOUN
eurjchem-2544	125	3	is	be	AUX
eurjchem-2544	125	4	attached	attach	VERB
eurjchem-2544	125	5	to	to	ADP
eurjchem-2544	125	6	the	the	DET
eurjchem-2544	125	7	enforced	enforce	VERB
eurjchem-2544	125	8	configuration	configuration	NOUN
eurjchem-2544	125	9	of	of	ADP
eurjchem-2544	125	10	the	the	DET
eurjchem-2544	125	11	4	4	NUM
eurjchem-2544	125	12	-	-	PUNCT
eurjchem-2544	125	13	membered	membere	VERB
eurjchem-2544	125	14	chelating	chelating	NOUN
eurjchem-2544	125	15	ring	ring	NOUN
eurjchem-2544	125	16	system	system	NOUN
eurjchem-2544	125	17	resulting	result	VERB
eurjchem-2544	125	18	in	in	ADP
eurjchem-2544	125	19	average	average	ADJ
eurjchem-2544	125	20	co(iii)-s	co(iii)-	NOUN
eurjchem-2544	125	21	distance	distance	NOUN
eurjchem-2544	125	22	of	of	ADP
eurjchem-2544	125	23	2.262(3	2.262(3	NOUN
eurjchem-2544	125	24	)	)	PUNCT
eurjchem-2544	125	25	å	å	NOUN
eurjchem-2544	125	26	,	,	PUNCT
eurjchem-2544	125	27	s	s	NOUN
eurjchem-2544	125	28	-	-	PUNCT
eurjchem-2544	125	29	co	co	NOUN
eurjchem-2544	125	30	-	-	NOUN
eurjchem-2544	125	31	s	s	NOUN
eurjchem-2544	125	32	angles	angle	NOUN
eurjchem-2544	125	33	of	of	ADP
eurjchem-2544	125	34	165.74(11	165.74(11	NUM
eurjchem-2544	125	35	)	)	PUNCT
eurjchem-2544	125	36	and	and	CCONJ
eurjchem-2544	125	37	166.5(2	166.5(2	NUM
eurjchem-2544	125	38	)	)	PUNCT
eurjchem-2544	125	39	°	°	NOUN
eurjchem-2544	125	40	and	and	CCONJ
eurjchem-2544	125	41	the	the	DET
eurjchem-2544	125	42	imposition	imposition	NOUN
eurjchem-2544	125	43	of	of	ADP
eurjchem-2544	125	44	constraints	constraint	NOUN
eurjchem-2544	125	45	on	on	ADP
eurjchem-2544	125	46	the	the	DET
eurjchem-2544	125	47	entire	entire	ADJ
eurjchem-2544	125	48	molecule	molecule	NOUN
eurjchem-2544	125	49	by	by	ADP
eurjchem-2544	125	50	the	the	DET
eurjchem-2544	125	51	rigidity	rigidity	NOUN
eurjchem-2544	125	52	of	of	ADP
eurjchem-2544	125	53	the	the	DET
eurjchem-2544	125	54	ligands	ligand	NOUN
eurjchem-2544	125	55	and	and	CCONJ
eurjchem-2544	125	56	the	the	DET
eurjchem-2544	125	57	small	small	ADJ
eurjchem-2544	125	58	s	s	NOUN
eurjchem-2544	125	59	-	-	PUNCT
eurjchem-2544	125	60	co	co	NOUN
eurjchem-2544	125	61	-	-	ADJ
eurjchem-2544	125	62	s	s	PART
eurjchem-2544	125	63	"	"	PUNCT
eurjchem-2544	125	64	bites	bite	NOUN
eurjchem-2544	125	65	"	"	PUNCT
eurjchem-2544	125	66	of	of	ADP
eurjchem-2544	125	67	76.34(11	76.34(11	NUM
eurjchem-2544	125	68	)	)	PUNCT
eurjchem-2544	125	69	and	and	CCONJ
eurjchem-2544	125	70	76.2(2	76.2(2	NUM
eurjchem-2544	125	71	)	)	PUNCT
eurjchem-2544	125	72	°	°	PUNCT
eurjchem-2544	126	1	[	[	X
eurjchem-2544	126	2	12	12	NUM
eurjchem-2544	126	3	]	]	PUNCT
eurjchem-2544	126	4	.	.	PUNCT
eurjchem-2544	127	1	the	the	DET
eurjchem-2544	127	2	distortions	distortion	NOUN
eurjchem-2544	127	3	in	in	ADP
eurjchem-2544	127	4	complex	complex	ADJ
eurjchem-2544	127	5	2	2	NUM
eurjchem-2544	127	6	are	be	AUX
eurjchem-2544	127	7	not	not	PART
eurjchem-2544	127	8	far	far	ADV
eurjchem-2544	127	9	-	-	PUNCT
eurjchem-2544	127	10	fetched	fetch	VERB
eurjchem-2544	127	11	and	and	CCONJ
eurjchem-2544	127	12	have	have	AUX
eurjchem-2544	127	13	been	be	AUX
eurjchem-2544	127	14	observed	observe	VERB
eurjchem-2544	127	15	in	in	ADP
eurjchem-2544	127	16	other	other	ADJ
eurjchem-2544	127	17	derivatives	derivative	NOUN
eurjchem-2544	127	18	of	of	ADP
eurjchem-2544	127	19	the	the	DET
eurjchem-2544	127	20	form	form	NOUN
eurjchem-2544	127	21	[	[	X
eurjchem-2544	127	22	co(s2cnr2)3	co(s2cnr2)3	X
eurjchem-2544	127	23	]	]	X
eurjchem-2544	127	24	,	,	PUNCT
eurjchem-2544	127	25	where	where	SCONJ
eurjchem-2544	127	26	r	r	NOUN
eurjchem-2544	127	27	=	=	SYM
eurjchem-2544	127	28	et	et	PROPN
eurjchem-2544	127	29	,	,	PUNCT
eurjchem-2544	127	30	ipr	ipr	PROPN
eurjchem-2544	127	31	and	and	CCONJ
eurjchem-2544	127	32	ch2ph	ch2ph	NOUN
eurjchem-2544	127	33	[	[	X
eurjchem-2544	127	34	8,26	8,26	NOUN
eurjchem-2544	127	35	]	]	PUNCT
eurjchem-2544	127	36	.	.	PUNCT
eurjchem-2544	128	1	the	the	DET
eurjchem-2544	128	2	high	high	ADJ
eurjchem-2544	128	3	degree	degree	NOUN
eurjchem-2544	128	4	of	of	ADP
eurjchem-2544	128	5	double	double	ADJ
eurjchem-2544	128	6	bond	bond	NOUN
eurjchem-2544	128	7	character	character	NOUN
eurjchem-2544	128	8	in	in	ADP
eurjchem-2544	128	9	complex	complex	ADJ
eurjchem-2544	128	10	2	2	NUM
eurjchem-2544	128	11	is	be	AUX
eurjchem-2544	128	12	responsible	responsible	ADJ
eurjchem-2544	128	13	for	for	ADP
eurjchem-2544	128	14	the	the	DET
eurjchem-2544	128	15	short	short	ADJ
eurjchem-2544	128	16	n	n	CCONJ
eurjchem-2544	128	17	-	-	PUNCT
eurjchem-2544	128	18	c	c	NOUN
eurjchem-2544	128	19	bond	bond	NOUN
eurjchem-2544	128	20	distance	distance	NOUN
eurjchem-2544	128	21	of	of	ADP
eurjchem-2544	128	22	1.340(9	1.340(9	NUM
eurjchem-2544	128	23	)	)	PUNCT
eurjchem-2544	128	24	å	å	NOUN
eurjchem-2544	128	25	.	.	PUNCT
eurjchem-2544	129	1	the	the	DET
eurjchem-2544	129	2	crystal	crystal	PROPN
eurjchem-2544	129	3	lattice	lattice	NOUN
eurjchem-2544	129	4	of	of	ADP
eurjchem-2544	129	5	complex	complex	ADJ
eurjchem-2544	129	6	2	2	NUM
eurjchem-2544	129	7	is	be	AUX
eurjchem-2544	129	8	dominated	dominate	VERB
eurjchem-2544	129	9	by	by	ADP
eurjchem-2544	129	10	h···h	h···h	PROPN
eurjchem-2544	129	11	interactions	interaction	NOUN
eurjchem-2544	129	12	of	of	ADP
eurjchem-2544	129	13	distance	distance	NOUN
eurjchem-2544	129	14	2.199	2.199	NUM
eurjchem-2544	129	15	å	å	NOUN
eurjchem-2544	129	16	with	with	ADP
eurjchem-2544	129	17	the	the	DET
eurjchem-2544	129	18	methylene	methylene	NOUN
eurjchem-2544	129	19	donor	donor	NOUN
eurjchem-2544	129	20	.	.	PUNCT
eurjchem-2544	130	1	the	the	DET
eurjchem-2544	130	2	cis-[co(dtc)2(phph2)2]bf4·ch3cn·0.5et2o	cis-[co(dtc)2(phph2)2]bf4·ch3cn·0.5et2o	NOUN
eurjchem-2544	130	3	(	(	PUNCT
eurjchem-2544	130	4	where	where	SCONJ
eurjchem-2544	130	5	dtc	dtc	NOUN
eurjchem-2544	130	6	=	=	SYM
eurjchem-2544	130	7	n	n	CCONJ
eurjchem-2544	130	8	,	,	PUNCT
eurjchem-2544	130	9	n	n	CCONJ
eurjchem-2544	130	10	-	-	PUNCT
eurjchem-2544	130	11	dimethyl	dimethyl	NOUN
eurjchem-2544	130	12	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2544	130	13	,	,	PUNCT
eurjchem-2544	130	14	phph2	phph2	NOUN
eurjchem-2544	130	15	=	=	SYM
eurjchem-2544	130	16	diphenylphospine	diphenylphospine	NOUN
eurjchem-2544	130	17	)	)	PUNCT
eurjchem-2544	130	18	(	(	PUNCT
eurjchem-2544	130	19	3	3	X
eurjchem-2544	130	20	,	,	PUNCT
eurjchem-2544	130	21	figure	figure	VERB
eurjchem-2544	130	22	3	3	NUM
eurjchem-2544	130	23	)	)	PUNCT
eurjchem-2544	130	24	crystallizes	crystallize	NOUN
eurjchem-2544	130	25	in	in	ADP
eurjchem-2544	130	26	the	the	DET
eurjchem-2544	130	27	p2	p2	PROPN
eurjchem-2544	130	28	/	/	SYM
eurjchem-2544	130	29	n	n	NOUN
eurjchem-2544	130	30	space	space	NOUN
eurjchem-2544	130	31	group	group	NOUN
eurjchem-2544	130	32	of	of	ADP
eurjchem-2544	130	33	the	the	DET
eurjchem-2544	130	34	monoclinic	monoclinic	ADJ
eurjchem-2544	130	35	crystal	crystal	NOUN
eurjchem-2544	130	36	system	system	NOUN
eurjchem-2544	130	37	[	[	X
eurjchem-2544	130	38	5	5	NUM
eurjchem-2544	130	39	]	]	PUNCT
eurjchem-2544	130	40	.	.	PUNCT
eurjchem-2544	131	1	its	its	PRON
eurjchem-2544	131	2	p	p	ADJ
eurjchem-2544	131	3	-	-	PUNCT
eurjchem-2544	131	4	h	h	NOUN
eurjchem-2544	131	5	bond	bond	NOUN
eurjchem-2544	131	6	distances	distance	NOUN
eurjchem-2544	131	7	of	of	ADP
eurjchem-2544	131	8	1.37(3	1.37(3	NUM
eurjchem-2544	131	9	)	)	PUNCT
eurjchem-2544	131	10	å	å	PROPN
eurjchem-2544	131	11	and	and	CCONJ
eurjchem-2544	131	12	1.36(2	1.36(2	NUM
eurjchem-2544	131	13	)	)	PUNCT
eurjchem-2544	131	14	å	å	PROPN
eurjchem-2544	131	15	are	be	AUX
eurjchem-2544	131	16	consistent	consistent	ADJ
eurjchem-2544	131	17	with	with	ADP
eurjchem-2544	131	18	1h	1h	NUM
eurjchem-2544	131	19	nmr	nmr	NOUN
eurjchem-2544	131	20	measurements	measurement	NOUN
eurjchem-2544	131	21	.	.	PUNCT
eurjchem-2544	132	1	the	the	DET
eurjchem-2544	132	2	two	two	NUM
eurjchem-2544	132	3	phenyl	phenyl	NOUN
eurjchem-2544	132	4	rings	ring	NOUN
eurjchem-2544	132	5	are	be	AUX
eurjchem-2544	132	6	oriented	orient	VERB
eurjchem-2544	132	7	in	in	ADP
eurjchem-2544	132	8	such	such	DET
eurjchem-2544	132	9	a	a	DET
eurjchem-2544	132	10	way	way	NOUN
eurjchem-2544	132	11	that	that	PRON
eurjchem-2544	132	12	the	the	DET
eurjchem-2544	132	13	intramolecular	intramolecular	ADJ
eurjchem-2544	132	14	interaction	interaction	NOUN
eurjchem-2544	132	15	between	between	ADP
eurjchem-2544	132	16	the	the	DET
eurjchem-2544	132	17	two	two	NUM
eurjchem-2544	132	18	steric	steric	ADJ
eurjchem-2544	132	19	phph2	phph2	NOUN
eurjchem-2544	132	20	ligands	ligand	NOUN
eurjchem-2544	132	21	is	be	AUX
eurjchem-2544	132	22	reduced	reduce	VERB
eurjchem-2544	132	23	while	while	SCONJ
eurjchem-2544	132	24	the	the	DET
eurjchem-2544	132	25	dtc	dtc	NOUN
eurjchem-2544	132	26	plane	plane	NOUN
eurjchem-2544	132	27	and	and	CCONJ
eurjchem-2544	132	28	one	one	NUM
eurjchem-2544	132	29	of	of	ADP
eurjchem-2544	132	30	phph2	phph2	NOUN
eurjchem-2544	132	31	’s	’s	PART
eurjchem-2544	132	32	phenyl	phenyl	NOUN
eurjchem-2544	132	33	interact	interact	NOUN
eurjchem-2544	132	34	through	through	ADP
eurjchem-2544	132	35	stacking	stacking	NOUN
eurjchem-2544	132	36	.	.	PUNCT
eurjchem-2544	133	1	the	the	DET
eurjchem-2544	133	2	co	co	ADJ
eurjchem-2544	133	3	-	-	ADJ
eurjchem-2544	133	4	p	p	ADJ
eurjchem-2544	133	5	bond	bond	NOUN
eurjchem-2544	133	6	distances	distance	NOUN
eurjchem-2544	133	7	of	of	ADP
eurjchem-2544	133	8	2.2340(6	2.2340(6	NOUN
eurjchem-2544	133	9	)	)	PUNCT
eurjchem-2544	133	10	and	and	CCONJ
eurjchem-2544	133	11	2.2258(7	2.2258(7	NUM
eurjchem-2544	133	12	)	)	PUNCT
eurjchem-2544	133	13	å	å	NOUN
eurjchem-2544	133	14	are	be	AUX
eurjchem-2544	133	15	shorter	short	ADJ
eurjchem-2544	133	16	than	than	ADP
eurjchem-2544	133	17	those	those	PRON
eurjchem-2544	133	18	observed	observe	VERB
eurjchem-2544	133	19	in	in	ADP
eurjchem-2544	133	20	cis-[co(dtc)2(pme2ph)2]pf6	cis-[co(dtc)2(pme2ph)2]pf6	NOUN
eurjchem-2544	133	21	(	(	PUNCT
eurjchem-2544	133	22	where	where	SCONJ
eurjchem-2544	133	23	pmeph2	pmeph2	NOUN
eurjchem-2544	133	24	is	be	AUX
eurjchem-2544	133	25	sterically	sterically	ADV
eurjchem-2544	133	26	less	less	ADV
eurjchem-2544	133	27	bulky	bulky	ADJ
eurjchem-2544	133	28	but	but	CCONJ
eurjchem-2544	133	29	more	more	ADV
eurjchem-2544	133	30	basic	basic	ADJ
eurjchem-2544	133	31	than	than	ADP
eurjchem-2544	133	32	phph2	phph2	NOUN
eurjchem-2544	133	33	)	)	PUNCT
eurjchem-2544	133	34	with	with	ADP
eurjchem-2544	133	35	co	co	ADJ
eurjchem-2544	133	36	-	-	ADJ
eurjchem-2544	133	37	p	p	ADJ
eurjchem-2544	133	38	bond	bond	NOUN
eurjchem-2544	133	39	distances	distance	NOUN
eurjchem-2544	133	40	of	of	ADP
eurjchem-2544	133	41	2.2795(6	2.2795(6	NUM
eurjchem-2544	133	42	)	)	PUNCT
eurjchem-2544	133	43	and	and	CCONJ
eurjchem-2544	133	44	2.2637(7	2.2637(7	X
eurjchem-2544	133	45	)	)	PUNCT
eurjchem-2544	134	1	å	å	X
eurjchem-2544	135	1	[	[	X
eurjchem-2544	135	2	6	6	NUM
eurjchem-2544	135	3	]	]	PUNCT
eurjchem-2544	135	4	.	.	PUNCT
eurjchem-2544	136	1	the	the	DET
eurjchem-2544	136	2	p	p	NOUN
eurjchem-2544	136	3	-	-	PUNCT
eurjchem-2544	136	4	co	co	ADJ
eurjchem-2544	136	5	-	-	ADJ
eurjchem-2544	136	6	p	p	ADJ
eurjchem-2544	136	7	angle	angle	NOUN
eurjchem-2544	136	8	of	of	ADP
eurjchem-2544	136	9	90.51(2	90.51(2	NUM
eurjchem-2544	136	10	)	)	PUNCT
eurjchem-2544	136	11	°	°	PROPN
eurjchem-2544	136	12	is	be	AUX
eurjchem-2544	136	13	clearly	clearly	ADV
eurjchem-2544	136	14	smaller	small	ADJ
eurjchem-2544	136	15	than	than	ADP
eurjchem-2544	136	16	what	what	PRON
eurjchem-2544	136	17	is	be	AUX
eurjchem-2544	136	18	obtainable	obtainable	ADJ
eurjchem-2544	136	19	in	in	ADP
eurjchem-2544	136	20	cis-[co(dtc)2(pligand)2]+	cis-[co(dtc)2(pligand)2]+	PROPN
eurjchem-2544	136	21	variant	variant	NOUN
eurjchem-2544	136	22	of	of	ADP
eurjchem-2544	136	23	complexes	complex	NOUN
eurjchem-2544	136	24	[	[	X
eurjchem-2544	136	25	4,6	4,6	X
eurjchem-2544	136	26	]	]	PUNCT
eurjchem-2544	136	27	.	.	PUNCT
eurjchem-2544	137	1	the	the	DET
eurjchem-2544	137	2	crystal	crystal	PROPN
eurjchem-2544	137	3	lattice	lattice	NOUN
eurjchem-2544	137	4	of	of	ADP
eurjchem-2544	137	5	complex	complex	ADJ
eurjchem-2544	137	6	3	3	NUM
eurjchem-2544	137	7	is	be	AUX
eurjchem-2544	137	8	dominated	dominate	VERB
eurjchem-2544	137	9	by	by	ADP
eurjchem-2544	137	10	h···f	h···f	PROPN
eurjchem-2544	137	11	,	,	PUNCT
eurjchem-2544	137	12	h···b	h···b	PROPN
eurjchem-2544	137	13	,	,	PUNCT
eurjchem-2544	137	14	h···o	h···o	PROPN
eurjchem-2544	137	15	,	,	PUNCT
eurjchem-2544	137	16	and	and	CCONJ
eurjchem-2544	137	17	h···n	h···n	NOUN
eurjchem-2544	137	18	interactions	interaction	NOUN
eurjchem-2544	137	19	with	with	ADP
eurjchem-2544	137	20	methyl	methyl	NOUN
eurjchem-2544	137	21	-	-	PUNCT
eurjchem-2544	137	22	c	c	NOUN
eurjchem-2544	137	23	-	-	PUNCT
eurjchem-2544	137	24	h.	h.	NOUN
eurjchem-2544	137	25	aromatic	aromatic	NOUN
eurjchem-2544	137	26	-	-	PUNCT
eurjchem-2544	137	27	c	c	NOUN
eurjchem-2544	137	28	-	-	PUNCT
eurjchem-2544	137	29	h	h	NOUN
eurjchem-2544	137	30	and	and	CCONJ
eurjchem-2544	137	31	p	p	ADJ
eurjchem-2544	137	32	-	-	PUNCT
eurjchem-2544	137	33	h	h	NOUN
eurjchem-2544	137	34	donors	donor	NOUN
eurjchem-2544	137	35	,	,	PUNCT
eurjchem-2544	137	36	while	while	SCONJ
eurjchem-2544	137	37	the	the	DET
eurjchem-2544	137	38	o	o	PROPN
eurjchem-2544	137	39	,	,	PUNCT
eurjchem-2544	137	40	f	f	X
eurjchem-2544	137	41	,	,	PUNCT
eurjchem-2544	137	42	and	and	CCONJ
eurjchem-2544	137	43	n	n	PRON
eurjchem-2544	137	44	acceptors	acceptor	NOUN
eurjchem-2544	137	45	are	be	AUX
eurjchem-2544	137	46	from	from	ADP
eurjchem-2544	137	47	diethyl	diethyl	NOUN
eurjchem-2544	137	48	ether	ether	NOUN
eurjchem-2544	137	49	,	,	PUNCT
eurjchem-2544	137	50	tetrafluoroborate	tetrafluoroborate	NOUN
eurjchem-2544	137	51	anion	anion	NOUN
eurjchem-2544	137	52	,	,	PUNCT
eurjchem-2544	137	53	and	and	CCONJ
eurjchem-2544	137	54	acetonitrile	acetonitrile	NOUN
eurjchem-2544	137	55	,	,	PUNCT
eurjchem-2544	137	56	respectively	respectively	ADV
eurjchem-2544	137	57	.	.	PUNCT
eurjchem-2544	138	1	trans-[co(dtc)2(phph2)2bf4	trans-[co(dtc)2(phph2)2bf4	NOUN
eurjchem-2544	138	2	]	]	X
eurjchem-2544	138	3	(	(	PUNCT
eurjchem-2544	138	4	4	4	NUM
eurjchem-2544	138	5	,	,	PUNCT
eurjchem-2544	138	6	figure	figure	VERB
eurjchem-2544	138	7	4	4	NUM
eurjchem-2544	138	8	)	)	PUNCT
eurjchem-2544	138	9	(	(	PUNCT
eurjchem-2544	138	10	isomer	isomer	NOUN
eurjchem-2544	138	11	of	of	ADP
eurjchem-2544	138	12	complex	complex	ADJ
eurjchem-2544	138	13	3	3	NUM
eurjchem-2544	138	14	)	)	PUNCT
eurjchem-2544	138	15	crystallizes	crystallize	NOUN
eurjchem-2544	138	16	in	in	ADP
eurjchem-2544	138	17	the	the	DET
eurjchem-2544	138	18	c2	c2	PROPN
eurjchem-2544	138	19	/	/	SYM
eurjchem-2544	138	20	c	c	PROPN
eurjchem-2544	138	21	space	space	NOUN
eurjchem-2544	138	22	group	group	NOUN
eurjchem-2544	138	23	of	of	ADP
eurjchem-2544	138	24	the	the	DET
eurjchem-2544	138	25	monoclinic	monoclinic	ADJ
eurjchem-2544	138	26	crystal	crystal	NOUN
eurjchem-2544	138	27	system	system	NOUN
eurjchem-2544	138	28	[	[	X
eurjchem-2544	138	29	5	5	NUM
eurjchem-2544	138	30	]	]	PUNCT
eurjchem-2544	138	31	.	.	PUNCT
eurjchem-2544	139	1	its	its	PRON
eurjchem-2544	139	2	equal	equal	ADJ
eurjchem-2544	139	3	p	p	ADJ
eurjchem-2544	139	4	-	-	PUNCT
eurjchem-2544	139	5	h	h	NOUN
eurjchem-2544	139	6	bond	bond	NOUN
eurjchem-2544	139	7	distances	distance	NOUN
eurjchem-2544	139	8	of	of	ADP
eurjchem-2544	139	9	1.21(3	1.21(3	NUM
eurjchem-2544	139	10	)	)	PUNCT
eurjchem-2544	139	11	å	å	NOUN
eurjchem-2544	139	12	are	be	AUX
eurjchem-2544	139	13	remarkably	remarkably	ADV
eurjchem-2544	139	14	shorter	short	ADJ
eurjchem-2544	139	15	than	than	ADP
eurjchem-2544	139	16	p	p	NOUN
eurjchem-2544	139	17	-	-	PUNCT
eurjchem-2544	139	18	h	h	NOUN
eurjchem-2544	139	19	bond	bond	NOUN
eurjchem-2544	139	20	distances	distance	NOUN
eurjchem-2544	139	21	of	of	ADP
eurjchem-2544	139	22	1.37(3	1.37(3	NUM
eurjchem-2544	139	23	)	)	PUNCT
eurjchem-2544	139	24	and	and	CCONJ
eurjchem-2544	139	25	1.36(2	1.36(2	NUM
eurjchem-2544	139	26	)	)	PUNCT
eurjchem-2544	139	27	å	å	NOUN
eurjchem-2544	139	28	in	in	ADP
eurjchem-2544	139	29	the	the	DET
eurjchem-2544	139	30	cis	cis	NOUN
eurjchem-2544	139	31	-	-	PUNCT
eurjchem-2544	139	32	isomer	isomer	NOUN
eurjchem-2544	139	33	.	.	PUNCT
eurjchem-2544	140	1	its	its	PRON
eurjchem-2544	140	2	co	co	NOUN
eurjchem-2544	140	3	-	-	NOUN
eurjchem-2544	140	4	s	s	PART
eurjchem-2544	140	5	bond	bond	NOUN
eurjchem-2544	140	6	distance	distance	NOUN
eurjchem-2544	140	7	and	and	CCONJ
eurjchem-2544	140	8	bite	bite	VERB
eurjchem-2544	140	9	angles	angle	NOUN
eurjchem-2544	140	10	in	in	ADP
eurjchem-2544	140	11	the	the	DET
eurjchem-2544	140	12	dtc	dtc	PROPN
eurjchem-2544	140	13	ligand	ligand	NOUN
eurjchem-2544	140	14	align	align	VERB
eurjchem-2544	140	15	well	well	ADV
eurjchem-2544	140	16	with	with	ADP
eurjchem-2544	140	17	those	those	PRON
eurjchem-2544	140	18	of	of	ADP
eurjchem-2544	140	19	trans[co(dtc)2pme3	trans[co(dtc)2pme3	NOUN
eurjchem-2544	140	20	-	-	PUNCT
eurjchem-2544	140	21	nphn]bf4	nphn]bf4	NOUN
eurjchem-2544	140	22	(	(	PUNCT
eurjchem-2544	140	23	n	n	NOUN
eurjchem-2544	140	24	=	=	SYM
eurjchem-2544	140	25	1	1	NUM
eurjchem-2544	140	26	,	,	PUNCT
eurjchem-2544	140	27	2	2	NUM
eurjchem-2544	140	28	,	,	PUNCT
eurjchem-2544	140	29	and	and	CCONJ
eurjchem-2544	140	30	3	3	X
eurjchem-2544	140	31	)	)	PUNCT
eurjchem-2544	141	1	[	[	X
eurjchem-2544	141	2	4,6	4,6	X
eurjchem-2544	141	3	]	]	PUNCT
eurjchem-2544	141	4	.	.	PUNCT
eurjchem-2544	142	1	its	its	PRON
eurjchem-2544	142	2	co	co	NOUN
eurjchem-2544	142	3	-	-	NOUN
eurjchem-2544	142	4	p	p	ADJ
eurjchem-2544	142	5	distances	distance	NOUN
eurjchem-2544	142	6	of	of	ADP
eurjchem-2544	142	7	2.276(1	2.276(1	NUM
eurjchem-2544	142	8	)	)	PUNCT
eurjchem-2544	142	9	å	å	NOUN
eurjchem-2544	142	10	are	be	AUX
eurjchem-2544	142	11	much	much	ADV
eurjchem-2544	142	12	shorter	short	ADJ
eurjchem-2544	142	13	than	than	ADP
eurjchem-2544	142	14	those	those	DET
eurjchem-2544	142	15	available	available	ADJ
eurjchem-2544	142	16	shotonwa	shotonwa	PROPN
eurjchem-2544	142	17	et	et	PROPN
eurjchem-2544	142	18	al	al	PROPN
eurjchem-2544	142	19	.	.	PUNCT
eurjchem-2544	142	20	/	/	SYM
eurjchem-2544	142	21	european	european	PROPN
eurjchem-2544	142	22	journal	journal	PROPN
eurjchem-2544	142	23	of	of	ADP
eurjchem-2544	142	24	chemistry	chemistry	NOUN
eurjchem-2544	142	25	15	15	NUM
eurjchem-2544	142	26	(	(	PUNCT
eurjchem-2544	142	27	3	3	NUM
eurjchem-2544	142	28	)	)	PUNCT
eurjchem-2544	142	29	(	(	PUNCT
eurjchem-2544	142	30	2024	2024	NUM
eurjchem-2544	142	31	)	)	PUNCT
eurjchem-2544	142	32	291	291	NUM
eurjchem-2544	142	33	-	-	SYM
eurjchem-2544	142	34	301	301	NUM
eurjchem-2544	142	35	295	295	NUM
eurjchem-2544	142	36	2024	2024	NUM
eurjchem-2544	142	37	–	–	PUNCT
eurjchem-2544	142	38	european	european	ADJ
eurjchem-2544	142	39	journal	journal	NOUN
eurjchem-2544	142	40	of	of	ADP
eurjchem-2544	142	41	chemistry	chemistry	NOUN
eurjchem-2544	142	42	–	–	PUNCT
eurjchem-2544	142	43	cc	cc	NOUN
eurjchem-2544	142	44	by	by	ADP
eurjchem-2544	142	45	nc	nc	PROPN
eurjchem-2544	142	46	–	–	PUNCT
eurjchem-2544	142	47	doi	doi	PROPN
eurjchem-2544	142	48	:	:	PUNCT
eurjchem-2544	142	49	10.5155	10.5155	NUM
eurjchem-2544	142	50	/	/	SYM
eurjchem-2544	142	51	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	142	52	-	-	PUNCT
eurjchem-2544	142	53	301.2544	301.2544	NUM
eurjchem-2544	142	54	figure	figure	NOUN
eurjchem-2544	142	55	5	5	NUM
eurjchem-2544	142	56	.	.	PUNCT
eurjchem-2544	142	57	molecular	molecular	ADJ
eurjchem-2544	142	58	structure	structure	NOUN
eurjchem-2544	142	59	of	of	ADP
eurjchem-2544	142	60	complex	complex	ADJ
eurjchem-2544	142	61	6	6	NUM
eurjchem-2544	142	62	.	.	PUNCT
eurjchem-2544	142	63	figure	figure	NOUN
eurjchem-2544	142	64	6	6	NUM
eurjchem-2544	142	65	.	.	PUNCT
eurjchem-2544	143	1	crystalline	crystalline	PROPN
eurjchem-2544	143	2	3d	3d	PROPN
eurjchem-2544	143	3	aggregate	aggregate	NOUN
eurjchem-2544	143	4	generated	generate	VERB
eurjchem-2544	143	5	from	from	ADP
eurjchem-2544	143	6	complex	complex	ADJ
eurjchem-2544	143	7	6	6	NUM
eurjchem-2544	144	1	[	[	SYM
eurjchem-2544	144	2	20	20	NUM
eurjchem-2544	144	3	]	]	PUNCT
eurjchem-2544	144	4	.	.	PUNCT
eurjchem-2544	145	1	in	in	ADP
eurjchem-2544	145	2	trans-[co(dtc)2pme3	trans-[co(dtc)2pme3	NOUN
eurjchem-2544	145	3	-	-	NOUN
eurjchem-2544	145	4	nphn]bf4	nphn]bf4	NOUN
eurjchem-2544	145	5	despite	despite	SCONJ
eurjchem-2544	145	6	that	that	DET
eurjchem-2544	145	7	pme2ph	pme2ph	NOUN
eurjchem-2544	145	8	and	and	CCONJ
eurjchem-2544	145	9	pme3	pme3	AUX
eurjchem-2544	145	10	exhibiting	exhibit	VERB
eurjchem-2544	145	11	sterically	sterically	ADV
eurjchem-2544	145	12	smaller	small	ADJ
eurjchem-2544	145	13	and	and	CCONJ
eurjchem-2544	145	14	stronger	strong	ADJ
eurjchem-2544	145	15	σ	σ	NOUN
eurjchem-2544	145	16	-	-	PUNCT
eurjchem-2544	145	17	donor	donor	NOUN
eurjchem-2544	145	18	capabilities	capability	NOUN
eurjchem-2544	145	19	compared	compare	VERB
eurjchem-2544	145	20	to	to	ADP
eurjchem-2544	145	21	phph2	phph2	NOUN
eurjchem-2544	145	22	.	.	PUNCT
eurjchem-2544	146	1	trans	tran	NOUN
eurjchem-2544	146	2	interactions	interaction	NOUN
eurjchem-2544	146	3	or	or	CCONJ
eurjchem-2544	146	4	influence	influence	NOUN
eurjchem-2544	146	5	in	in	ADP
eurjchem-2544	146	6	phosphine	phosphine	NOUN
eurjchem-2544	146	7	complexes	complex	NOUN
eurjchem-2544	146	8	are	be	AUX
eurjchem-2544	146	9	indicated	indicate	VERB
eurjchem-2544	146	10	by	by	ADP
eurjchem-2544	146	11	the	the	DET
eurjchem-2544	146	12	short	short	ADJ
eurjchem-2544	146	13	co	co	ADJ
eurjchem-2544	146	14	-	-	ADJ
eurjchem-2544	146	15	p	p	ADJ
eurjchem-2544	146	16	bond	bond	NOUN
eurjchem-2544	146	17	distances	distance	NOUN
eurjchem-2544	146	18	.	.	PUNCT
eurjchem-2544	147	1	several	several	ADJ
eurjchem-2544	147	2	mixed	mixed	ADJ
eurjchem-2544	147	3	ligand	ligand	ADJ
eurjchem-2544	147	4	co(iii	co(iii	NOUN
eurjchem-2544	147	5	)	)	PUNCT
eurjchem-2544	147	6	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	147	7	complexes	complex	NOUN
eurjchem-2544	147	8	incorporating	incorporate	VERB
eurjchem-2544	147	9	phosphines	phosphine	NOUN
eurjchem-2544	147	10	,	,	PUNCT
eurjchem-2544	147	11	phosphinites	phosphinite	NOUN
eurjchem-2544	147	12	,	,	PUNCT
eurjchem-2544	147	13	phosphornites	phosphornite	NOUN
eurjchem-2544	147	14	,	,	PUNCT
eurjchem-2544	147	15	and	and	CCONJ
eurjchem-2544	147	16	phosphites	phosphite	NOUN
eurjchem-2544	147	17	have	have	AUX
eurjchem-2544	147	18	become	become	VERB
eurjchem-2544	147	19	common	common	ADJ
eurjchem-2544	147	20	coupled	couple	VERB
eurjchem-2544	147	21	with	with	ADP
eurjchem-2544	147	22	the	the	DET
eurjchem-2544	147	23	trans	trans	PROPN
eurjchem-2544	147	24	influence	influence	NOUN
eurjchem-2544	147	25	they	they	PRON
eurjchem-2544	147	26	exhibit	exhibit	VERB
eurjchem-2544	147	27	on	on	ADP
eurjchem-2544	147	28	structural	structural	ADJ
eurjchem-2544	147	29	and	and	CCONJ
eurjchem-2544	147	30	molecular	molecular	ADJ
eurjchem-2544	147	31	trends	trend	NOUN
eurjchem-2544	148	1	[	[	X
eurjchem-2544	148	2	3	3	NUM
eurjchem-2544	148	3	-	-	SYM
eurjchem-2544	148	4	6	6	NUM
eurjchem-2544	148	5	]	]	PUNCT
eurjchem-2544	148	6	.	.	PUNCT
eurjchem-2544	149	1	the	the	DET
eurjchem-2544	149	2	crystal	crystal	PROPN
eurjchem-2544	149	3	lattice	lattice	NOUN
eurjchem-2544	149	4	of	of	ADP
eurjchem-2544	149	5	complex	complex	ADJ
eurjchem-2544	149	6	4	4	NUM
eurjchem-2544	149	7	is	be	AUX
eurjchem-2544	149	8	dominated	dominate	VERB
eurjchem-2544	149	9	by	by	ADP
eurjchem-2544	149	10	aromaticc···c	aromaticc···c	ADJ
eurjchem-2544	149	11	-	-	PUNCT
eurjchem-2544	149	12	aromatic	aromatic	ADJ
eurjchem-2544	149	13	methyl	methyl	NOUN
eurjchem-2544	149	14	-	-	PUNCT
eurjchem-2544	149	15	c···f	c···f	VERB
eurjchem-2544	149	16	,	,	PUNCT
eurjchem-2544	149	17	aromatic	aromatic	NOUN
eurjchem-2544	149	18	-	-	PUNCT
eurjchem-2544	149	19	c	c	NOUN
eurjchem-2544	149	20	-	-	PUNCT
eurjchem-2544	149	21	h···f	h···f	NOUN
eurjchem-2544	149	22	with	with	ADP
eurjchem-2544	149	23	the	the	DET
eurjchem-2544	149	24	acceptor	acceptor	NOUN
eurjchem-2544	149	25	f	f	PROPN
eurjchem-2544	149	26	atom	atom	NOUN
eurjchem-2544	149	27	emanating	emanate	VERB
eurjchem-2544	149	28	from	from	ADP
eurjchem-2544	149	29	the	the	DET
eurjchem-2544	149	30	tetrafluoroborate	tetrafluoroborate	NOUN
eurjchem-2544	149	31	anion	anion	NOUN
eurjchem-2544	149	32	.	.	PUNCT
eurjchem-2544	150	1	tris(n	tris(n	VERB
eurjchem-2544	150	2	,	,	PUNCT
eurjchem-2544	150	3	n	n	CCONJ
eurjchem-2544	150	4	-	-	PUNCT
eurjchem-2544	150	5	dimethyldithiocarbamato)cobalt(iii	dimethyldithiocarbamato)cobalt(iii	NOUN
eurjchem-2544	150	6	)	)	PUNCT
eurjchem-2544	150	7	(	(	PUNCT
eurjchem-2544	150	8	5	5	NUM
eurjchem-2544	150	9	,	,	PUNCT
eurjchem-2544	150	10	figure	figure	NOUN
eurjchem-2544	150	11	4	4	NUM
eurjchem-2544	150	12	)	)	PUNCT
eurjchem-2544	150	13	crystallizes	crystallize	NOUN
eurjchem-2544	150	14	in	in	ADP
eurjchem-2544	150	15	the	the	DET
eurjchem-2544	150	16	p21	p21	NOUN
eurjchem-2544	150	17	/	/	SYM
eurjchem-2544	150	18	n	n	PROPN
eurjchem-2544	150	19	space	space	NOUN
eurjchem-2544	150	20	group	group	NOUN
eurjchem-2544	150	21	of	of	ADP
eurjchem-2544	150	22	the	the	DET
eurjchem-2544	150	23	monoclinic	monoclinic	ADJ
eurjchem-2544	150	24	crystal	crystal	NOUN
eurjchem-2544	150	25	system	system	NOUN
eurjchem-2544	150	26	[	[	X
eurjchem-2544	150	27	31	31	NUM
eurjchem-2544	150	28	]	]	PUNCT
eurjchem-2544	150	29	.	.	PUNCT
eurjchem-2544	151	1	it	it	PRON
eurjchem-2544	151	2	has	have	VERB
eurjchem-2544	151	3	three	three	NUM
eurjchem-2544	151	4	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	151	5	ligands	ligand	NOUN
eurjchem-2544	151	6	that	that	PRON
eurjchem-2544	151	7	are	be	AUX
eurjchem-2544	151	8	octahedrally	octahedrally	ADV
eurjchem-2544	151	9	coordinated	coordinate	VERB
eurjchem-2544	151	10	to	to	ADP
eurjchem-2544	151	11	the	the	DET
eurjchem-2544	151	12	co	co	NOUN
eurjchem-2544	151	13	center	center	NOUN
eurjchem-2544	151	14	through	through	ADP
eurjchem-2544	151	15	the	the	DET
eurjchem-2544	151	16	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	151	17	sulfur	sulfur	NOUN
eurjchem-2544	151	18	atoms	atom	NOUN
eurjchem-2544	151	19	.	.	PUNCT
eurjchem-2544	152	1	the	the	DET
eurjchem-2544	152	2	ligand	ligand	ADJ
eurjchem-2544	152	3	dimensions	dimension	NOUN
eurjchem-2544	152	4	are	be	AUX
eurjchem-2544	152	5	in	in	ADP
eurjchem-2544	152	6	alignment	alignment	NOUN
eurjchem-2544	152	7	with	with	ADP
eurjchem-2544	152	8	crystallographic	crystallographic	ADJ
eurjchem-2544	152	9	expectations	expectation	NOUN
eurjchem-2544	152	10	while	while	SCONJ
eurjchem-2544	152	11	the	the	DET
eurjchem-2544	152	12	complex	complex	NOUN
eurjchem-2544	152	13	assumes	assume	VERB
eurjchem-2544	152	14	a	a	DET
eurjchem-2544	152	15	good	good	ADJ
eurjchem-2544	152	16	approximation	approximation	NOUN
eurjchem-2544	152	17	with	with	ADP
eurjchem-2544	152	18	32	32	NUM
eurjchem-2544	152	19	symmetry	symmetry	NOUN
eurjchem-2544	152	20	.	.	PUNCT
eurjchem-2544	153	1	the	the	DET
eurjchem-2544	153	2	co	co	X
eurjchem-2544	153	3	atom	atom	NOUN
eurjchem-2544	153	4	lies	lie	VERB
eurjchem-2544	153	5	in	in	ADP
eurjchem-2544	153	6	nearly	nearly	ADV
eurjchem-2544	153	7	the	the	DET
eurjchem-2544	153	8	plane	plane	NOUN
eurjchem-2544	153	9	of	of	ADP
eurjchem-2544	153	10	the	the	DET
eurjchem-2544	153	11	ligand	ligand	NOUN
eurjchem-2544	153	12	with	with	ADP
eurjchem-2544	153	13	very	very	ADV
eurjchem-2544	153	14	small	small	ADJ
eurjchem-2544	153	15	deviation	deviation	NOUN
eurjchem-2544	153	16	of	of	ADP
eurjchem-2544	153	17	0.18(3	0.18(3	PROPN
eurjchem-2544	153	18	)	)	PUNCT
eurjchem-2544	153	19	,	,	PUNCT
eurjchem-2544	153	20	0.02(1	0.02(1	NOUN
eurjchem-2544	153	21	)	)	PUNCT
eurjchem-2544	153	22	and	and	CCONJ
eurjchem-2544	153	23	0.05(1	0.05(1	NUM
eurjchem-2544	153	24	)	)	PUNCT
eurjchem-2544	153	25	å	å	NOUN
eurjchem-2544	153	26	from	from	ADP
eurjchem-2544	153	27	the	the	DET
eurjchem-2544	153	28	planes	plane	NOUN
eurjchem-2544	153	29	of	of	ADP
eurjchem-2544	153	30	the	the	DET
eurjchem-2544	153	31	three	three	NUM
eurjchem-2544	153	32	ligands	ligand	NOUN
eurjchem-2544	153	33	.	.	PUNCT
eurjchem-2544	154	1	the	the	DET
eurjchem-2544	154	2	cos6	cos6	PROPN
eurjchem-2544	154	3	coordination	coordination	NOUN
eurjchem-2544	154	4	polyhedron	polyhedron	NOUN
eurjchem-2544	154	5	has	have	VERB
eurjchem-2544	154	6	a	a	DET
eurjchem-2544	154	7	co	co	NOUN
eurjchem-2544	154	8	-	-	NOUN
eurjchem-2544	154	9	s	s	ADJ
eurjchem-2544	154	10	mean	mean	ADJ
eurjchem-2544	154	11	bond	bond	NOUN
eurjchem-2544	154	12	distance	distance	NOUN
eurjchem-2544	154	13	of	of	ADP
eurjchem-2544	154	14	2.264	2.264	NUM
eurjchem-2544	154	15	å	å	NOUN
eurjchem-2544	154	16	that	that	PRON
eurjchem-2544	154	17	is	be	AUX
eurjchem-2544	154	18	intermediate	intermediate	ADJ
eurjchem-2544	154	19	between	between	ADP
eurjchem-2544	154	20	what	what	PRON
eurjchem-2544	154	21	was	be	AUX
eurjchem-2544	154	22	observed	observe	VERB
eurjchem-2544	154	23	for	for	ADP
eurjchem-2544	154	24	[	[	X
eurjchem-2544	154	25	co(s2cnh2)3	co(s2cnh2)3	X
eurjchem-2544	154	26	]	]	X
eurjchem-2544	154	27	(	(	PUNCT
eurjchem-2544	154	28	2.275	2.275	NUM
eurjchem-2544	154	29	å	å	NOUN
eurjchem-2544	154	30	)	)	PUNCT
eurjchem-2544	155	1	[	[	X
eurjchem-2544	155	2	32	32	NUM
eurjchem-2544	155	3	]	]	PUNCT
eurjchem-2544	155	4	and	and	CCONJ
eurjchem-2544	155	5	[	[	X
eurjchem-2544	155	6	co(s2(net2)3	co(s2(net2)3	X
eurjchem-2544	155	7	]	]	X
eurjchem-2544	155	8	(	(	PUNCT
eurjchem-2544	155	9	2.258	2.258	NUM
eurjchem-2544	155	10	å	å	NOUN
eurjchem-2544	155	11	)	)	PUNCT
eurjchem-2544	156	1	[	[	X
eurjchem-2544	156	2	33	33	NUM
eurjchem-2544	156	3	]	]	PUNCT
eurjchem-2544	156	4	.	.	PUNCT
eurjchem-2544	157	1	the	the	DET
eurjchem-2544	157	2	intermediacy	intermediacy	NOUN
eurjchem-2544	157	3	of	of	ADP
eurjchem-2544	157	4	the	the	DET
eurjchem-2544	157	5	co	co	NOUN
eurjchem-2544	157	6	-	-	NOUN
eurjchem-2544	157	7	s	s	PART
eurjchem-2544	157	8	bonds	bond	NOUN
eurjchem-2544	157	9	is	be	AUX
eurjchem-2544	157	10	attached	attach	VERB
eurjchem-2544	157	11	to	to	ADP
eurjchem-2544	157	12	the	the	DET
eurjchem-2544	157	13	location	location	NOUN
eurjchem-2544	157	14	of	of	ADP
eurjchem-2544	157	15	[	[	X
eurjchem-2544	157	16	co(s2cnh2)3	co(s2cnh2)3	X
eurjchem-2544	157	17	]	]	X
eurjchem-2544	157	18	and	and	CCONJ
eurjchem-2544	157	19	[	[	X
eurjchem-2544	157	20	co(s2(net2)3	co(s2(net2)3	X
eurjchem-2544	157	21	]	]	X
eurjchem-2544	157	22	on	on	ADP
eurjchem-2544	157	23	the	the	DET
eurjchem-2544	157	24	crystallographic	crystallographic	ADJ
eurjchem-2544	157	25	3	3	NOUN
eurjchem-2544	157	26	-	-	ADJ
eurjchem-2544	157	27	fold	fold	ADJ
eurjchem-2544	157	28	and	and	CCONJ
eurjchem-2544	157	29	2	2	ADJ
eurjchem-2544	157	30	-	-	ADJ
eurjchem-2544	157	31	fold	fold	ADJ
eurjchem-2544	157	32	axes	axis	NOUN
eurjchem-2544	157	33	resulting	result	VERB
eurjchem-2544	157	34	in	in	ADP
eurjchem-2544	157	35	increased	increase	VERB
eurjchem-2544	157	36	and	and	CCONJ
eurjchem-2544	157	37	decreased	decrease	VERB
eurjchem-2544	157	38	bond	bond	NOUN
eurjchem-2544	157	39	lengths	length	NOUN
eurjchem-2544	157	40	,	,	PUNCT
eurjchem-2544	157	41	respectively	respectively	ADV
eurjchem-2544	157	42	.	.	PUNCT
eurjchem-2544	158	1	the	the	DET
eurjchem-2544	158	2	'	'	PUNCT
eurjchem-2544	158	3	bites	bite	NOUN
eurjchem-2544	158	4	'	'	PUNCT
eurjchem-2544	158	5	of	of	ADP
eurjchem-2544	158	6	the	the	DET
eurjchem-2544	158	7	s	s	NOUN
eurjchem-2544	158	8	-	-	PUNCT
eurjchem-2544	158	9	co	co	NOUN
eurjchem-2544	158	10	-	-	NOUN
eurjchem-2544	158	11	s	s	NOUN
eurjchem-2544	158	12	angles	angle	NOUN
eurjchem-2544	158	13	are	be	AUX
eurjchem-2544	158	14	in	in	ADP
eurjchem-2544	158	15	the	the	DET
eurjchem-2544	158	16	range	range	NOUN
eurjchem-2544	158	17	76.25	76.25	NUM
eurjchem-2544	158	18	-	-	SYM
eurjchem-2544	158	19	76.46	76.46	NUM
eurjchem-2544	158	20	°	°	NOUN
eurjchem-2544	158	21	.	.	PUNCT
eurjchem-2544	159	1	its	its	PRON
eurjchem-2544	159	2	c	c	PROPN
eurjchem-2544	159	3	-	-	PUNCT
eurjchem-2544	159	4	s	s	NOUN
eurjchem-2544	159	5	bond	bond	NOUN
eurjchem-2544	159	6	distances	distance	NOUN
eurjchem-2544	159	7	in	in	ADP
eurjchem-2544	159	8	the	the	DET
eurjchem-2544	159	9	range	range	NOUN
eurjchem-2544	159	10	1.7015	1.7015	NUM
eurjchem-2544	159	11	-	-	SYM
eurjchem-2544	159	12	1.7085	1.7085	NUM
eurjchem-2544	159	13	å	å	PROPN
eurjchem-2544	159	14	,	,	PUNCT
eurjchem-2544	159	15	which	which	PRON
eurjchem-2544	159	16	are	be	AUX
eurjchem-2544	159	17	intermediate	intermediate	ADJ
eurjchem-2544	159	18	between	between	ADP
eurjchem-2544	159	19	single	single	ADJ
eurjchem-2544	159	20	c	c	NOUN
eurjchem-2544	159	21	-	-	PUNCT
eurjchem-2544	159	22	s	s	NOUN
eurjchem-2544	159	23	and	and	CCONJ
eurjchem-2544	159	24	double	double	ADJ
eurjchem-2544	159	25	c	c	NOUN
eurjchem-2544	159	26	=	=	SYM
eurjchem-2544	159	27	s	s	PART
eurjchem-2544	159	28	bonds	bond	NOUN
eurjchem-2544	159	29	,	,	PUNCT
eurjchem-2544	159	30	are	be	AUX
eurjchem-2544	159	31	suggestive	suggestive	ADJ
eurjchem-2544	159	32	of	of	ADP
eurjchem-2544	159	33	substantial	substantial	ADJ
eurjchem-2544	159	34	charge	charge	NOUN
eurjchem-2544	159	35	delocalization	delocalization	NOUN
eurjchem-2544	159	36	over	over	ADP
eurjchem-2544	159	37	the	the	DET
eurjchem-2544	159	38	ncs2co	ncs2co	ADJ
eurjchem-2544	159	39	plane	plane	NOUN
eurjchem-2544	159	40	.	.	PUNCT
eurjchem-2544	160	1	the	the	DET
eurjchem-2544	160	2	canonical	canonical	ADJ
eurjchem-2544	160	3	form	form	NOUN
eurjchem-2544	160	4	of	of	ADP
eurjchem-2544	160	5	complex	complex	ADJ
eurjchem-2544	160	6	5	5	NUM
eurjchem-2544	160	7	is	be	AUX
eurjchem-2544	160	8	likely	likely	ADJ
eurjchem-2544	160	9	to	to	PART
eurjchem-2544	160	10	be	be	AUX
eurjchem-2544	160	11	responsible	responsible	ADJ
eurjchem-2544	160	12	for	for	ADP
eurjchem-2544	160	13	its	its	PRON
eurjchem-2544	160	14	high	high	ADJ
eurjchem-2544	160	15	degree	degree	NOUN
eurjchem-2544	160	16	of	of	ADP
eurjchem-2544	160	17	double	double	ADJ
eurjchem-2544	160	18	bond	bond	NOUN
eurjchem-2544	160	19	character	character	NOUN
eurjchem-2544	160	20	as	as	SCONJ
eurjchem-2544	160	21	revealed	reveal	VERB
eurjchem-2544	160	22	by	by	ADP
eurjchem-2544	160	23	c	c	PROPN
eurjchem-2544	160	24	-	-	PUNCT
eurjchem-2544	160	25	n	n	PRON
eurjchem-2544	160	26	bond	bond	NOUN
eurjchem-2544	160	27	distances	distance	NOUN
eurjchem-2544	160	28	of	of	ADP
eurjchem-2544	160	29	1.3147	1.3147	NUM
eurjchem-2544	160	30	,	,	PUNCT
eurjchem-2544	160	31	1.3267	1.3267	NUM
eurjchem-2544	160	32	and	and	CCONJ
eurjchem-2544	160	33	1.3189	1.3189	NUM
eurjchem-2544	160	34	å	å	NOUN
eurjchem-2544	160	35	.	.	PUNCT
eurjchem-2544	161	1	it	it	PRON
eurjchem-2544	161	2	lacks	lack	VERB
eurjchem-2544	161	3	the	the	DET
eurjchem-2544	161	4	n	n	ADV
eurjchem-2544	161	5	-	-	ADJ
eurjchem-2544	161	6	fold	fold	ADJ
eurjchem-2544	161	7	axis	axis	NOUN
eurjchem-2544	161	8	relation	relation	NOUN
eurjchem-2544	161	9	but	but	CCONJ
eurjchem-2544	161	10	is	be	AUX
eurjchem-2544	161	11	driven	drive	VERB
eurjchem-2544	161	12	by	by	ADP
eurjchem-2544	161	13	the	the	DET
eurjchem-2544	161	14	trigonal	trigonal	ADJ
eurjchem-2544	161	15	symmetry	symmetry	NOUN
eurjchem-2544	161	16	.	.	PUNCT
eurjchem-2544	162	1	raston	raston	PROPN
eurjchem-2544	162	2	et	et	PROPN
eurjchem-2544	162	3	al	al	PROPN
eurjchem-2544	162	4	.	.	PUNCT
eurjchem-2544	163	1	[	[	X
eurjchem-2544	163	2	32	32	NUM
eurjchem-2544	163	3	]	]	PUNCT
eurjchem-2544	163	4	also	also	ADV
eurjchem-2544	163	5	suggested	suggest	VERB
eurjchem-2544	163	6	that	that	SCONJ
eurjchem-2544	163	7	the	the	DET
eurjchem-2544	163	8	disparities	disparity	NOUN
eurjchem-2544	163	9	in	in	ADP
eurjchem-2544	163	10	the	the	DET
eurjchem-2544	163	11	co	co	NOUN
eurjchem-2544	163	12	-	-	NOUN
eurjchem-2544	163	13	s	s	PART
eurjchem-2544	163	14	distances	distance	NOUN
eurjchem-2544	163	15	could	could	AUX
eurjchem-2544	163	16	be	be	AUX
eurjchem-2544	163	17	as	as	ADP
eurjchem-2544	163	18	a	a	DET
eurjchem-2544	163	19	result	result	NOUN
eurjchem-2544	163	20	of	of	ADP
eurjchem-2544	163	21	the	the	DET
eurjchem-2544	163	22	variation	variation	NOUN
eurjchem-2544	163	23	in	in	ADP
eurjchem-2544	163	24	the	the	DET
eurjchem-2544	163	25	sulphur	sulphur	NOUN
eurjchem-2544	163	26	environment	environment	NOUN
eurjchem-2544	163	27	around	around	ADP
eurjchem-2544	163	28	the	the	DET
eurjchem-2544	163	29	co	co	NOUN
eurjchem-2544	163	30	centre	centre	NOUN
eurjchem-2544	163	31	.	.	PUNCT
eurjchem-2544	164	1	its	its	PRON
eurjchem-2544	164	2	crystal	crystal	NOUN
eurjchem-2544	164	3	lattice	lattice	NOUN
eurjchem-2544	164	4	is	be	AUX
eurjchem-2544	164	5	dominated	dominate	VERB
eurjchem-2544	164	6	by	by	ADP
eurjchem-2544	164	7	short	short	ADJ
eurjchem-2544	164	8	intermolecular	intermolecular	ADJ
eurjchem-2544	164	9	sp3c···s	sp3c···s	NUM
eurjchem-2544	164	10	contacts	contact	NOUN
eurjchem-2544	164	11	and	and	CCONJ
eurjchem-2544	164	12	hydrogen	hydrogen	NOUN
eurjchem-2544	164	13	bond	bond	NOUN
eurjchem-2544	164	14	interactions	interaction	NOUN
eurjchem-2544	164	15	of	of	ADP
eurjchem-2544	164	16	the	the	DET
eurjchem-2544	164	17	form	form	NOUN
eurjchem-2544	164	18	sp3c	sp3c	PROPN
eurjchem-2544	164	19	-	-	PUNCT
eurjchem-2544	164	20	h···s	h···s	NOUN
eurjchem-2544	164	21	contacts	contact	NOUN
eurjchem-2544	164	22	.	.	PUNCT
eurjchem-2544	165	1	the	the	DET
eurjchem-2544	165	2	sp3c···s	sp3c···s	PROPN
eurjchem-2544	165	3	contacts	contact	NOUN
eurjchem-2544	165	4	of	of	ADP
eurjchem-2544	165	5	3.425	3.425	NUM
eurjchem-2544	165	6	å	å	NOUN
eurjchem-2544	165	7	were	be	AUX
eurjchem-2544	165	8	repeated	repeat	VERB
eurjchem-2544	165	9	throughout	throughout	ADP
eurjchem-2544	165	10	the	the	DET
eurjchem-2544	165	11	lattice	lattice	NOUN
eurjchem-2544	165	12	,	,	PUNCT
eurjchem-2544	165	13	while	while	SCONJ
eurjchem-2544	165	14	h···s	h···	NOUN
eurjchem-2544	165	15	contacts	contact	NOUN
eurjchem-2544	165	16	of	of	ADP
eurjchem-2544	165	17	distances	distance	NOUN
eurjchem-2544	165	18	2.965	2.965	NUM
eurjchem-2544	165	19	,	,	PUNCT
eurjchem-2544	165	20	2.944	2.944	NUM
eurjchem-2544	165	21	,	,	PUNCT
eurjchem-2544	165	22	and	and	CCONJ
eurjchem-2544	165	23	2.830	2.830	NUM
eurjchem-2544	165	24	å	å	NOUN
eurjchem-2544	165	25	were	be	AUX
eurjchem-2544	165	26	recorded	record	VERB
eurjchem-2544	165	27	for	for	ADP
eurjchem-2544	165	28	the	the	DET
eurjchem-2544	165	29	hydrogen	hydrogen	NOUN
eurjchem-2544	165	30	bond	bond	NOUN
eurjchem-2544	165	31	interactions	interaction	NOUN
eurjchem-2544	165	32	.	.	PUNCT
eurjchem-2544	166	1	the	the	DET
eurjchem-2544	166	2	short	short	ADJ
eurjchem-2544	166	3	intermolecular	intermolecular	ADJ
eurjchem-2544	166	4	h···s	h···	NOUN
eurjchem-2544	166	5	contacts	contact	NOUN
eurjchem-2544	166	6	were	be	AUX
eurjchem-2544	166	7	not	not	PART
eurjchem-2544	166	8	worth	worth	ADJ
eurjchem-2544	166	9	reckoning	reckon	VERB
eurjchem-2544	166	10	with	with	ADP
eurjchem-2544	166	11	because	because	SCONJ
eurjchem-2544	166	12	the	the	DET
eurjchem-2544	166	13	positions	position	NOUN
eurjchem-2544	166	14	of	of	ADP
eurjchem-2544	166	15	the	the	DET
eurjchem-2544	166	16	h	h	NOUN
eurjchem-2544	166	17	atoms	atom	NOUN
eurjchem-2544	166	18	were	be	AUX
eurjchem-2544	166	19	not	not	PART
eurjchem-2544	166	20	accurately	accurately	ADV
eurjchem-2544	166	21	determined	determine	VERB
eurjchem-2544	166	22	.	.	PUNCT
eurjchem-2544	167	1	[	[	X
eurjchem-2544	167	2	co(ddc)3	co(ddc)3	X
eurjchem-2544	167	3	]	]	X
eurjchem-2544	167	4	(	(	PUNCT
eurjchem-2544	167	5	6	6	NUM
eurjchem-2544	167	6	,	,	PUNCT
eurjchem-2544	167	7	figure	figure	NOUN
eurjchem-2544	167	8	5	5	NUM
eurjchem-2544	167	9	)	)	PUNCT
eurjchem-2544	167	10	is	be	AUX
eurjchem-2544	167	11	a	a	DET
eurjchem-2544	167	12	neutral	neutral	ADJ
eurjchem-2544	167	13	coordination	coordination	NOUN
eurjchem-2544	167	14	complex	complex	NOUN
eurjchem-2544	167	15	just	just	ADV
eurjchem-2544	167	16	as	as	ADP
eurjchem-2544	167	17	complex	complex	ADJ
eurjchem-2544	167	18	5	5	NUM
eurjchem-2544	167	19	,	,	PUNCT
eurjchem-2544	167	20	where	where	SCONJ
eurjchem-2544	167	21	the	the	DET
eurjchem-2544	167	22	ddc	ddc	NOUN
eurjchem-2544	167	23	is	be	AUX
eurjchem-2544	167	24	obtained	obtain	VERB
eurjchem-2544	167	25	from	from	ADP
eurjchem-2544	167	26	n	n	CCONJ
eurjchem-2544	167	27	,	,	PUNCT
eurjchem-2544	167	28	ndimethyldithiocarbamic	ndimethyldithiocarbamic	ADJ
eurjchem-2544	167	29	acid	acid	NOUN
eurjchem-2544	167	30	hddc	hddc	NOUN
eurjchem-2544	168	1	[	[	X
eurjchem-2544	168	2	20	20	NUM
eurjchem-2544	168	3	]	]	PUNCT
eurjchem-2544	168	4	.	.	PUNCT
eurjchem-2544	169	1	it	it	PRON
eurjchem-2544	169	2	crystallizes	crystallize	VERB
eurjchem-2544	169	3	in	in	ADP
eurjchem-2544	169	4	the	the	DET
eurjchem-2544	169	5	p21	p21	NOUN
eurjchem-2544	169	6	/	/	SYM
eurjchem-2544	169	7	c	c	PROPN
eurjchem-2544	169	8	space	space	NOUN
eurjchem-2544	169	9	group	group	NOUN
eurjchem-2544	169	10	(	(	PUNCT
eurjchem-2544	169	11	compared	compare	VERB
eurjchem-2544	169	12	to	to	ADP
eurjchem-2544	169	13	its	its	PRON
eurjchem-2544	169	14	complex	complex	ADJ
eurjchem-2544	169	15	5	5	NUM
eurjchem-2544	169	16	polymorph	polymorph	NOUN
eurjchem-2544	169	17	which	which	PRON
eurjchem-2544	169	18	crystallizes	crystallize	VERB
eurjchem-2544	169	19	in	in	ADP
eurjchem-2544	169	20	the	the	DET
eurjchem-2544	169	21	p21	p21	NOUN
eurjchem-2544	169	22	/	/	SYM
eurjchem-2544	169	23	n	n	PROPN
eurjchem-2544	169	24	space	space	NOUN
eurjchem-2544	169	25	group	group	NOUN
eurjchem-2544	169	26	)	)	PUNCT
eurjchem-2544	169	27	of	of	ADP
eurjchem-2544	169	28	the	the	DET
eurjchem-2544	169	29	monoclinic	monoclinic	ADJ
eurjchem-2544	169	30	crystal	crystal	NOUN
eurjchem-2544	169	31	system	system	NOUN
eurjchem-2544	169	32	.	.	PUNCT
eurjchem-2544	170	1	the	the	DET
eurjchem-2544	170	2	cobalt	cobalt	NOUN
eurjchem-2544	170	3	center	center	NOUN
eurjchem-2544	170	4	is	be	AUX
eurjchem-2544	170	5	distortedly	distortedly	ADV
eurjchem-2544	170	6	hexacoordinated	hexacoordinate	VERB
eurjchem-2544	170	7	to	to	ADP
eurjchem-2544	170	8	six	six	NUM
eurjchem-2544	170	9	sulfur	sulfur	NOUN
eurjchem-2544	170	10	atoms	atom	NOUN
eurjchem-2544	170	11	of	of	ADP
eurjchem-2544	170	12	n	n	CCONJ
eurjchem-2544	170	13	,	,	PUNCT
eurjchem-2544	170	14	n	n	CCONJ
eurjchem-2544	170	15	-	-	PUNCT
eurjchem-2544	170	16	dimethyldithiocarbamic	dimethyldithiocarbamic	ADJ
eurjchem-2544	170	17	acid	acid	NOUN
eurjchem-2544	170	18	;	;	PUNCT
eurjchem-2544	170	19	two	two	NUM
eurjchem-2544	170	20	sulfur	sulfur	NOUN
eurjchem-2544	170	21	atoms	atom	NOUN
eurjchem-2544	170	22	are	be	AUX
eurjchem-2544	170	23	in	in	ADP
eurjchem-2544	170	24	the	the	DET
eurjchem-2544	170	25	axial	axial	ADJ
eurjchem-2544	170	26	position	position	NOUN
eurjchem-2544	170	27	and	and	CCONJ
eurjchem-2544	170	28	four	four	NUM
eurjchem-2544	170	29	in	in	ADP
eurjchem-2544	170	30	the	the	DET
eurjchem-2544	170	31	equatorial	equatorial	ADJ
eurjchem-2544	170	32	plane	plane	NOUN
eurjchem-2544	170	33	.	.	PUNCT
eurjchem-2544	171	1	its	its	PRON
eurjchem-2544	171	2	asymmetric	asymmetric	ADJ
eurjchem-2544	171	3	unit	unit	NOUN
eurjchem-2544	171	4	contains	contain	VERB
eurjchem-2544	171	5	three	three	NUM
eurjchem-2544	171	6	molecules	molecule	NOUN
eurjchem-2544	171	7	of	of	ADP
eurjchem-2544	171	8	n	n	CCONJ
eurjchem-2544	171	9	,	,	PUNCT
eurjchem-2544	171	10	ndimethyldithiocarbamic	ndimethyldithiocarbamic	ADJ
eurjchem-2544	171	11	acid	acid	NOUN
eurjchem-2544	171	12	and	and	CCONJ
eurjchem-2544	171	13	one	one	NUM
eurjchem-2544	171	14	co(iii	co(iii	NOUN
eurjchem-2544	171	15	)	)	PUNCT
eurjchem-2544	171	16	ion	ion	NOUN
eurjchem-2544	171	17	.	.	PUNCT
eurjchem-2544	172	1	each	each	DET
eurjchem-2544	172	2	hddc	hddc	PROPN
eurjchem-2544	172	3	ligand	ligand	NOUN
eurjchem-2544	172	4	is	be	AUX
eurjchem-2544	172	5	bidentate	bidentate	ADJ
eurjchem-2544	172	6	and	and	CCONJ
eurjchem-2544	172	7	chelates	chelate	NOUN
eurjchem-2544	172	8	to	to	ADP
eurjchem-2544	172	9	the	the	DET
eurjchem-2544	172	10	cobalt	cobalt	NOUN
eurjchem-2544	172	11	centre	centre	NOUN
eurjchem-2544	172	12	forming	form	VERB
eurjchem-2544	172	13	a	a	DET
eurjchem-2544	172	14	4	4	NUM
eurjchem-2544	172	15	-	-	PUNCT
eurjchem-2544	172	16	membered	membere	VERB
eurjchem-2544	172	17	[	[	NOUN
eurjchem-2544	172	18	cs2co	cs2co	NOUN
eurjchem-2544	172	19	]	]	X
eurjchem-2544	172	20	ring	ring	NOUN
eurjchem-2544	172	21	that	that	PRON
eurjchem-2544	172	22	is	be	AUX
eurjchem-2544	172	23	similar	similar	ADJ
eurjchem-2544	172	24	to	to	ADP
eurjchem-2544	172	25	that	that	PRON
eurjchem-2544	172	26	obtained	obtain	VERB
eurjchem-2544	172	27	in	in	ADP
eurjchem-2544	172	28	[	[	X
eurjchem-2544	172	29	co{s2cn(ch2ch2ch2nme2)2}3	co{s2cn(ch2ch2ch2nme2)2}3	X
eurjchem-2544	173	1	[	[	X
eurjchem-2544	173	2	34	34	NUM
eurjchem-2544	173	3	]	]	PUNCT
eurjchem-2544	173	4	.	.	PUNCT
eurjchem-2544	174	1	the	the	DET
eurjchem-2544	174	2	co	co	NOUN
eurjchem-2544	174	3	-	-	NOUN
eurjchem-2544	174	4	s	s	PART
eurjchem-2544	174	5	bond	bond	NOUN
eurjchem-2544	174	6	distances	distance	NOUN
eurjchem-2544	174	7	in	in	ADP
eurjchem-2544	174	8	the	the	DET
eurjchem-2544	174	9	cs2co	cs2co	NOUN
eurjchem-2544	174	10	ring	ring	NOUN
eurjchem-2544	174	11	are	be	AUX
eurjchem-2544	174	12	in	in	ADP
eurjchem-2544	174	13	the	the	DET
eurjchem-2544	174	14	range	range	NOUN
eurjchem-2544	174	15	2.2531(12)-2.2734(13	2.2531(12)-2.2734(13	NUM
eurjchem-2544	174	16	)	)	PUNCT
eurjchem-2544	174	17	å	å	PROPN
eurjchem-2544	174	18	and	and	CCONJ
eurjchem-2544	174	19	are	be	AUX
eurjchem-2544	174	20	slightly	slightly	ADV
eurjchem-2544	174	21	stronger	strong	ADJ
eurjchem-2544	174	22	than	than	ADP
eurjchem-2544	174	23	the	the	DET
eurjchem-2544	174	24	range	range	NOUN
eurjchem-2544	174	25	2.2645(15)-2.2766(15	2.2645(15)-2.2766(15	NUM
eurjchem-2544	174	26	)	)	PUNCT
eurjchem-2544	174	27	å	å	PROPN
eurjchem-2544	174	28	observed	observe	VERB
eurjchem-2544	174	29	in	in	ADP
eurjchem-2544	174	30	[	[	X
eurjchem-2544	174	31	co(ecpzdtc)3	co(ecpzdtc)3	X
eurjchem-2544	174	32	where	where	SCONJ
eurjchem-2544	174	33	ecpzdtc	ecpzdtc	PROPN
eurjchem-2544	174	34	is	be	AUX
eurjchem-2544	174	35	1	1	NUM
eurjchem-2544	174	36	-	-	PUNCT
eurjchem-2544	174	37	ethoxycarbonyl	ethoxycarbonyl	NOUN
eurjchem-2544	174	38	piperazine-4	piperazine-4	NOUN
eurjchem-2544	174	39	-	-	PUNCT
eurjchem-2544	174	40	carbodithioate	carbodithioate	NOUN
eurjchem-2544	174	41	[	[	X
eurjchem-2544	174	42	35	35	NUM
eurjchem-2544	174	43	]	]	PUNCT
eurjchem-2544	174	44	as	as	ADV
eurjchem-2544	174	45	well	well	ADV
eurjchem-2544	174	46	as	as	ADP
eurjchem-2544	174	47	that	that	PRON
eurjchem-2544	174	48	obtained	obtain	VERB
eurjchem-2544	174	49	in	in	ADP
eurjchem-2544	174	50	complex	complex	ADJ
eurjchem-2544	174	51	5	5	NUM
eurjchem-2544	174	52	.	.	PUNCT
eurjchem-2544	175	1	the	the	DET
eurjchem-2544	175	2	'	'	PUNCT
eurjchem-2544	175	3	bites	bite	NOUN
eurjchem-2544	175	4	'	'	PUNCT
eurjchem-2544	175	5	of	of	ADP
eurjchem-2544	175	6	the	the	DET
eurjchem-2544	175	7	s	s	NOUN
eurjchem-2544	175	8	-	-	PUNCT
eurjchem-2544	175	9	co	co	NOUN
eurjchem-2544	175	10	-	-	NOUN
eurjchem-2544	175	11	s	s	NOUN
eurjchem-2544	175	12	angles	angle	NOUN
eurjchem-2544	175	13	are	be	AUX
eurjchem-2544	175	14	in	in	ADP
eurjchem-2544	175	15	the	the	DET
eurjchem-2544	175	16	range	range	NOUN
eurjchem-2544	175	17	76.24(5)-76.61(5	76.24(5)-76.61(5	NUM
eurjchem-2544	175	18	)	)	PUNCT
eurjchem-2544	175	19	°	°	PROPN
eurjchem-2544	175	20	and	and	CCONJ
eurjchem-2544	175	21	are	be	AUX
eurjchem-2544	175	22	quite	quite	ADV
eurjchem-2544	175	23	similar	similar	ADJ
eurjchem-2544	175	24	to	to	ADP
eurjchem-2544	175	25	the	the	DET
eurjchem-2544	175	26	range	range	NOUN
eurjchem-2544	175	27	obtained	obtain	VERB
eurjchem-2544	175	28	for	for	ADP
eurjchem-2544	175	29	complex	complex	ADJ
eurjchem-2544	175	30	5	5	NUM
eurjchem-2544	175	31	.	.	PUNCT
eurjchem-2544	176	1	the	the	DET
eurjchem-2544	176	2	c	c	PROPN
eurjchem-2544	176	3	-	-	PUNCT
eurjchem-2544	176	4	s	s	NOUN
eurjchem-2544	176	5	bond	bond	NOUN
eurjchem-2544	176	6	distances	distance	NOUN
eurjchem-2544	176	7	in	in	ADP
eurjchem-2544	176	8	the	the	DET
eurjchem-2544	176	9	range	range	NOUN
eurjchem-2544	176	10	1.701(4)1.712(6	1.701(4)1.712(6	NUM
eurjchem-2544	176	11	)	)	PUNCT
eurjchem-2544	176	12	å	å	NOUN
eurjchem-2544	176	13	are	be	AUX
eurjchem-2544	176	14	quite	quite	ADV
eurjchem-2544	176	15	similar	similar	ADJ
eurjchem-2544	176	16	to	to	ADP
eurjchem-2544	176	17	those	those	PRON
eurjchem-2544	176	18	of	of	ADP
eurjchem-2544	176	19	complex	complex	ADJ
eurjchem-2544	176	20	5	5	NUM
eurjchem-2544	176	21	and	and	CCONJ
eurjchem-2544	176	22	are	be	AUX
eurjchem-2544	176	23	intermediate	intermediate	ADJ
eurjchem-2544	176	24	between	between	ADP
eurjchem-2544	176	25	single	single	ADJ
eurjchem-2544	176	26	c	c	NOUN
eurjchem-2544	176	27	-	-	PUNCT
eurjchem-2544	176	28	s	s	NOUN
eurjchem-2544	176	29	and	and	CCONJ
eurjchem-2544	176	30	double	double	ADJ
eurjchem-2544	176	31	c	c	NOUN
eurjchem-2544	176	32	=	=	SYM
eurjchem-2544	176	33	s	s	PART
eurjchem-2544	176	34	bonds	bond	NOUN
eurjchem-2544	176	35	,	,	PUNCT
eurjchem-2544	176	36	suggesting	suggest	VERB
eurjchem-2544	176	37	substantial	substantial	ADJ
eurjchem-2544	176	38	charge	charge	NOUN
eurjchem-2544	176	39	delocalization	delocalization	NOUN
eurjchem-2544	176	40	in	in	ADP
eurjchem-2544	176	41	the	the	DET
eurjchem-2544	176	42	ncs2co	ncs2co	ADJ
eurjchem-2544	176	43	plane	plane	NOUN
eurjchem-2544	176	44	[	[	X
eurjchem-2544	176	45	20	20	NUM
eurjchem-2544	176	46	]	]	PUNCT
eurjchem-2544	176	47	.	.	PUNCT
eurjchem-2544	177	1	296	296	NUM
eurjchem-2544	177	2	shotonwa	shotonwa	ADJ
eurjchem-2544	177	3	et	et	PROPN
eurjchem-2544	177	4	al	al	PROPN
eurjchem-2544	177	5	.	.	PUNCT
eurjchem-2544	177	6	/	/	SYM
eurjchem-2544	177	7	european	european	PROPN
eurjchem-2544	177	8	journal	journal	PROPN
eurjchem-2544	177	9	of	of	ADP
eurjchem-2544	177	10	chemistry	chemistry	NOUN
eurjchem-2544	177	11	15	15	NUM
eurjchem-2544	177	12	(	(	PUNCT
eurjchem-2544	177	13	3	3	NUM
eurjchem-2544	177	14	)	)	PUNCT
eurjchem-2544	177	15	(	(	PUNCT
eurjchem-2544	177	16	2024	2024	NUM
eurjchem-2544	177	17	)	)	PUNCT
eurjchem-2544	177	18	291	291	NUM
eurjchem-2544	177	19	-	-	SYM
eurjchem-2544	177	20	301	301	NUM
eurjchem-2544	177	21	2024	2024	NUM
eurjchem-2544	177	22	–	–	PUNCT
eurjchem-2544	177	23	european	european	ADJ
eurjchem-2544	177	24	journal	journal	NOUN
eurjchem-2544	177	25	of	of	ADP
eurjchem-2544	177	26	chemistry	chemistry	NOUN
eurjchem-2544	177	27	–	–	PUNCT
eurjchem-2544	177	28	cc	cc	NOUN
eurjchem-2544	177	29	by	by	ADP
eurjchem-2544	177	30	nc	nc	PROPN
eurjchem-2544	177	31	–	–	PUNCT
eurjchem-2544	177	32	doi	doi	PROPN
eurjchem-2544	177	33	:	:	PUNCT
eurjchem-2544	177	34	10.5155	10.5155	NUM
eurjchem-2544	177	35	/	/	SYM
eurjchem-2544	177	36	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	177	37	-	-	PUNCT
eurjchem-2544	177	38	301.2544	301.2544	NUM
eurjchem-2544	177	39	figure	figure	NOUN
eurjchem-2544	177	40	7	7	NUM
eurjchem-2544	177	41	.	.	PUNCT
eurjchem-2544	177	42	molecular	molecular	ADJ
eurjchem-2544	177	43	structures	structure	NOUN
eurjchem-2544	177	44	of	of	ADP
eurjchem-2544	177	45	complexes	complex	NOUN
eurjchem-2544	177	46	7	7	NUM
eurjchem-2544	177	47	and	and	CCONJ
eurjchem-2544	177	48	8	8	NUM
eurjchem-2544	177	49	with	with	ADP
eurjchem-2544	177	50	its	its	PRON
eurjchem-2544	177	51	distorted	distorted	ADJ
eurjchem-2544	177	52	structure	structure	NOUN
eurjchem-2544	177	53	and	and	CCONJ
eurjchem-2544	177	54	chloroform	chloroform	NOUN
eurjchem-2544	177	55	solvates	solvate	NOUN
eurjchem-2544	177	56	.	.	PUNCT
eurjchem-2544	178	1	figure	figure	VERB
eurjchem-2544	178	2	8	8	NUM
eurjchem-2544	178	3	.	.	PUNCT
eurjchem-2544	179	1	molecular	molecular	ADJ
eurjchem-2544	179	2	structure	structure	NOUN
eurjchem-2544	179	3	of	of	ADP
eurjchem-2544	179	4	complexes	complex	NOUN
eurjchem-2544	179	5	9	9	NUM
eurjchem-2544	179	6	and	and	CCONJ
eurjchem-2544	179	7	10	10	NUM
eurjchem-2544	179	8	.	.	PUNCT
eurjchem-2544	179	9	complexes	complex	NOUN
eurjchem-2544	179	10	5	5	NUM
eurjchem-2544	179	11	and	and	CCONJ
eurjchem-2544	179	12	6	6	NUM
eurjchem-2544	179	13	share	share	NOUN
eurjchem-2544	179	14	quite	quite	ADV
eurjchem-2544	179	15	similar	similar	ADJ
eurjchem-2544	179	16	canonical	canonical	ADJ
eurjchem-2544	179	17	forms	form	NOUN
eurjchem-2544	179	18	which	which	PRON
eurjchem-2544	179	19	are	be	AUX
eurjchem-2544	179	20	likely	likely	ADJ
eurjchem-2544	179	21	to	to	PART
eurjchem-2544	179	22	be	be	AUX
eurjchem-2544	179	23	responsible	responsible	ADJ
eurjchem-2544	179	24	for	for	ADP
eurjchem-2544	179	25	their	their	PRON
eurjchem-2544	179	26	high	high	ADJ
eurjchem-2544	179	27	degree	degree	NOUN
eurjchem-2544	179	28	of	of	ADP
eurjchem-2544	179	29	double	double	ADJ
eurjchem-2544	179	30	bond	bond	NOUN
eurjchem-2544	179	31	character	character	NOUN
eurjchem-2544	179	32	,	,	PUNCT
eurjchem-2544	179	33	as	as	SCONJ
eurjchem-2544	179	34	revealed	reveal	VERB
eurjchem-2544	179	35	by	by	ADP
eurjchem-2544	179	36	complex	complex	ADJ
eurjchem-2544	179	37	6	6	NUM
eurjchem-2544	179	38	’s	’s	NOUN
eurjchem-2544	179	39	c	c	NOUN
eurjchem-2544	179	40	-	-	PUNCT
eurjchem-2544	179	41	n	n	PRON
eurjchem-2544	179	42	bond	bond	NOUN
eurjchem-2544	179	43	distances	distance	NOUN
eurjchem-2544	179	44	of	of	ADP
eurjchem-2544	179	45	1.319(5	1.319(5	NUM
eurjchem-2544	179	46	)	)	PUNCT
eurjchem-2544	179	47	,	,	PUNCT
eurjchem-2544	179	48	1.319(8	1.319(8	NUM
eurjchem-2544	179	49	)	)	PUNCT
eurjchem-2544	179	50	and	and	CCONJ
eurjchem-2544	179	51	1.327(7	1.327(7	NUM
eurjchem-2544	179	52	)	)	PUNCT
eurjchem-2544	180	1	å	å	NOUN
eurjchem-2544	180	2	.	.	PUNCT
eurjchem-2544	181	1	as	as	ADP
eurjchem-2544	181	2	in	in	ADP
eurjchem-2544	181	3	complex	complex	ADJ
eurjchem-2544	181	4	5	5	NUM
eurjchem-2544	181	5	,	,	PUNCT
eurjchem-2544	181	6	the	the	DET
eurjchem-2544	181	7	sp3c···s	sp3c···s	NOUN
eurjchem-2544	181	8	contacts	contact	NOUN
eurjchem-2544	181	9	,	,	PUNCT
eurjchem-2544	181	10	although	although	SCONJ
eurjchem-2544	181	11	shorter	short	ADJ
eurjchem-2544	181	12	by	by	ADP
eurjchem-2544	181	13	0.010	0.010	NUM
eurjchem-2544	181	14	å	å	NOUN
eurjchem-2544	181	15	,	,	PUNCT
eurjchem-2544	181	16	and	and	CCONJ
eurjchem-2544	181	17	the	the	DET
eurjchem-2544	181	18	sp3ch···s	sp3ch···	NOUN
eurjchem-2544	181	19	interactions	interaction	NOUN
eurjchem-2544	181	20	with	with	ADP
eurjchem-2544	181	21	h···s	h···	NOUN
eurjchem-2544	181	22	contact	contact	NOUN
eurjchem-2544	181	23	distances	distance	NOUN
eurjchem-2544	181	24	of	of	ADP
eurjchem-2544	181	25	2.897	2.897	NUM
eurjchem-2544	181	26	,	,	PUNCT
eurjchem-2544	181	27	2.992	2.992	NUM
eurjchem-2544	181	28	and	and	CCONJ
eurjchem-2544	181	29	2.856	2.856	NUM
eurjchem-2544	181	30	å	å	NOUN
eurjchem-2544	181	31	were	be	AUX
eurjchem-2544	181	32	integral	integral	ADJ
eurjchem-2544	181	33	parts	part	NOUN
eurjchem-2544	181	34	of	of	ADP
eurjchem-2544	181	35	the	the	DET
eurjchem-2544	181	36	3d	3d	NUM
eurjchem-2544	181	37	aggregate	aggregate	NOUN
eurjchem-2544	181	38	formed	form	VERB
eurjchem-2544	181	39	from	from	ADP
eurjchem-2544	181	40	complex	complex	ADJ
eurjchem-2544	181	41	6	6	NUM
eurjchem-2544	181	42	(	(	PUNCT
eurjchem-2544	181	43	figure	figure	NOUN
eurjchem-2544	181	44	6	6	NUM
eurjchem-2544	181	45	)	)	PUNCT
eurjchem-2544	181	46	.	.	PUNCT
eurjchem-2544	182	1	from	from	ADP
eurjchem-2544	182	2	a	a	DET
eurjchem-2544	182	3	symmetry	symmetry	NOUN
eurjchem-2544	182	4	perspective	perspective	NOUN
eurjchem-2544	182	5	,	,	PUNCT
eurjchem-2544	182	6	complexes	complexe	VERB
eurjchem-2544	182	7	5	5	NUM
eurjchem-2544	182	8	and	and	CCONJ
eurjchem-2544	182	9	6	6	NUM
eurjchem-2544	182	10	possess	possess	VERB
eurjchem-2544	182	11	the	the	DET
eurjchem-2544	182	12	2	2	NUM
eurjchem-2544	182	13	-	-	ADJ
eurjchem-2544	182	14	fold	fold	ADJ
eurjchem-2544	182	15	screw	screw	NOUN
eurjchem-2544	182	16	axis	axis	NOUN
eurjchem-2544	182	17	with	with	ADP
eurjchem-2544	182	18	direction	direction	NOUN
eurjchem-2544	182	19	[	[	X
eurjchem-2544	182	20	0,1,0	0,1,0	X
eurjchem-2544	182	21	]	]	X
eurjchem-2544	182	22	at	at	ADP
eurjchem-2544	182	23	¼	¼	NOUN
eurjchem-2544	182	24	,	,	PUNCT
eurjchem-2544	182	25	y	y	NOUN
eurjchem-2544	182	26	,	,	PUNCT
eurjchem-2544	182	27	¼	¼	NOUN
eurjchem-2544	182	28	for	for	ADP
eurjchem-2544	182	29	complex	complex	ADJ
eurjchem-2544	182	30	5	5	NUM
eurjchem-2544	182	31	and	and	CCONJ
eurjchem-2544	182	32	0	0	NUM
eurjchem-2544	182	33	,	,	PUNCT
eurjchem-2544	182	34	y	y	NOUN
eurjchem-2544	182	35	,	,	PUNCT
eurjchem-2544	182	36	¼	¼	NOUN
eurjchem-2544	182	37	for	for	ADP
eurjchem-2544	182	38	complex	complex	ADJ
eurjchem-2544	182	39	6	6	NUM
eurjchem-2544	182	40	.	.	PUNCT
eurjchem-2544	183	1	they	they	PRON
eurjchem-2544	183	2	both	both	PRON
eurjchem-2544	183	3	possess	possess	VERB
eurjchem-2544	183	4	inversion	inversion	NOUN
eurjchem-2544	183	5	centres	centre	NOUN
eurjchem-2544	183	6	at	at	ADP
eurjchem-2544	183	7	[	[	X
eurjchem-2544	183	8	0,0,0	0,0,0	NOUN
eurjchem-2544	183	9	]	]	PUNCT
eurjchem-2544	183	10	,	,	PUNCT
eurjchem-2544	183	11	while	while	SCONJ
eurjchem-2544	183	12	their	their	PRON
eurjchem-2544	183	13	glide	glide	NOUN
eurjchem-2544	183	14	planes	plane	NOUN
eurjchem-2544	183	15	are	be	AUX
eurjchem-2544	183	16	perpendicular	perpendicular	ADJ
eurjchem-2544	183	17	to	to	ADP
eurjchem-2544	183	18	[	[	X
eurjchem-2544	183	19	0,1,0	0,1,0	X
eurjchem-2544	183	20	]	]	X
eurjchem-2544	183	21	with	with	ADP
eurjchem-2544	183	22	the	the	DET
eurjchem-2544	183	23	glide	glide	NOUN
eurjchem-2544	183	24	component	component	NOUN
eurjchem-2544	183	25	[	[	X
eurjchem-2544	183	26	½,0,½	½,0,½	NOUN
eurjchem-2544	183	27	]	]	X
eurjchem-2544	183	28	for	for	ADP
eurjchem-2544	183	29	complex	complex	ADJ
eurjchem-2544	183	30	5	5	NUM
eurjchem-2544	183	31	and	and	CCONJ
eurjchem-2544	183	32	[	[	X
eurjchem-2544	183	33	0,0,½	0,0,½	X
eurjchem-2544	183	34	]	]	X
eurjchem-2544	183	35	for	for	ADP
eurjchem-2544	183	36	complex	complex	ADJ
eurjchem-2544	183	37	6	6	NUM
eurjchem-2544	183	38	.	.	PUNCT
eurjchem-2544	183	39	tris(dithiocarbamato)cobalt(iii	tris(dithiocarbamato)cobalt(iii	PROPN
eurjchem-2544	183	40	)	)	PUNCT
eurjchem-2544	183	41	(	(	PUNCT
eurjchem-2544	183	42	7	7	NUM
eurjchem-2544	183	43	,	,	PUNCT
eurjchem-2544	183	44	figure	figure	NOUN
eurjchem-2544	183	45	7	7	NUM
eurjchem-2544	183	46	)	)	PUNCT
eurjchem-2544	183	47	crystallizes	crystallize	NOUN
eurjchem-2544	183	48	in	in	ADP
eurjchem-2544	183	49	the	the	DET
eurjchem-2544	183	50	monoclinic	monoclinic	ADJ
eurjchem-2544	183	51	p21	p21	NOUN
eurjchem-2544	183	52	/	/	SYM
eurjchem-2544	183	53	a	a	DET
eurjchem-2544	183	54	space	space	NOUN
eurjchem-2544	183	55	group	group	NOUN
eurjchem-2544	183	56	[	[	X
eurjchem-2544	183	57	32	32	NUM
eurjchem-2544	183	58	]	]	PUNCT
eurjchem-2544	183	59	.	.	PUNCT
eurjchem-2544	184	1	its	its	PRON
eurjchem-2544	184	2	crystal	crystal	NOUN
eurjchem-2544	184	3	structure	structure	NOUN
eurjchem-2544	184	4	description	description	NOUN
eurjchem-2544	184	5	was	be	AUX
eurjchem-2544	184	6	triggered	trigger	VERB
eurjchem-2544	184	7	by	by	ADP
eurjchem-2544	184	8	the	the	DET
eurjchem-2544	184	9	determination	determination	NOUN
eurjchem-2544	184	10	of	of	ADP
eurjchem-2544	184	11	the	the	DET
eurjchem-2544	184	12	structure	structure	NOUN
eurjchem-2544	184	13	of	of	ADP
eurjchem-2544	184	14	[	[	X
eurjchem-2544	184	15	ni(cs2nh2)2	ni(cs2nh2)2	X
eurjchem-2544	184	16	]	]	PUNCT
eurjchem-2544	184	17	with	with	ADP
eurjchem-2544	184	18	a	a	DET
eurjchem-2544	184	19	mean	mean	ADJ
eurjchem-2544	184	20	c	c	NOUN
eurjchem-2544	184	21	-	-	PUNCT
eurjchem-2544	184	22	n	n	PRON
eurjchem-2544	184	23	bond	bond	NOUN
eurjchem-2544	184	24	distance	distance	NOUN
eurjchem-2544	184	25	of	of	ADP
eurjchem-2544	184	26	1.37(5	1.37(5	NUM
eurjchem-2544	184	27	)	)	PUNCT
eurjchem-2544	184	28	å	å	PROPN
eurjchem-2544	185	1	[	[	X
eurjchem-2544	185	2	36	36	NUM
eurjchem-2544	185	3	]	]	PUNCT
eurjchem-2544	185	4	.	.	PUNCT
eurjchem-2544	186	1	it	it	PRON
eurjchem-2544	186	2	is	be	AUX
eurjchem-2544	186	3	a	a	DET
eurjchem-2544	186	4	discrete	discrete	ADJ
eurjchem-2544	186	5	molecule	molecule	NOUN
eurjchem-2544	186	6	with	with	ADP
eurjchem-2544	186	7	three	three	NUM
eurjchem-2544	186	8	planar	planar	ADJ
eurjchem-2544	186	9	ligands	ligand	NOUN
eurjchem-2544	186	10	that	that	PRON
eurjchem-2544	186	11	are	be	AUX
eurjchem-2544	186	12	coplanar	coplanar	ADJ
eurjchem-2544	186	13	with	with	ADP
eurjchem-2544	186	14	the	the	DET
eurjchem-2544	186	15	co	co	NOUN
eurjchem-2544	186	16	center	center	NOUN
eurjchem-2544	186	17	.	.	PUNCT
eurjchem-2544	187	1	the	the	DET
eurjchem-2544	187	2	arrangement	arrangement	NOUN
eurjchem-2544	187	3	of	of	ADP
eurjchem-2544	187	4	the	the	DET
eurjchem-2544	187	5	three	three	NUM
eurjchem-2544	187	6	planar	planar	ADJ
eurjchem-2544	187	7	ligands	ligand	NOUN
eurjchem-2544	187	8	around	around	ADP
eurjchem-2544	187	9	the	the	DET
eurjchem-2544	187	10	co	co	PROPN
eurjchem-2544	187	11	center	center	PROPN
eurjchem-2544	187	12	results	result	VERB
eurjchem-2544	187	13	in	in	ADP
eurjchem-2544	187	14	a	a	DET
eurjchem-2544	187	15	d3	d3	PROPN
eurjchem-2544	187	16	three	three	NUM
eurjchem-2544	187	17	-	-	PUNCT
eurjchem-2544	187	18	bladed	bladed	ADJ
eurjchem-2544	187	19	propeller	propeller	NOUN
eurjchem-2544	187	20	.	.	PUNCT
eurjchem-2544	188	1	the	the	DET
eurjchem-2544	188	2	geometry	geometry	NOUN
eurjchem-2544	188	3	of	of	ADP
eurjchem-2544	188	4	the	the	DET
eurjchem-2544	188	5	cos6c3n3	cos6c3n3	PROPN
eurjchem-2544	188	6	fragment	fragment	NOUN
eurjchem-2544	188	7	of	of	ADP
eurjchem-2544	188	8	the	the	DET
eurjchem-2544	188	9	molecule	molecule	NOUN
eurjchem-2544	188	10	is	be	AUX
eurjchem-2544	188	11	in	in	ADP
eurjchem-2544	188	12	agreement	agreement	NOUN
eurjchem-2544	188	13	with	with	ADP
eurjchem-2544	188	14	crystallographic	crystallographic	ADJ
eurjchem-2544	188	15	expectations	expectation	NOUN
eurjchem-2544	188	16	and	and	CCONJ
eurjchem-2544	188	17	is	be	AUX
eurjchem-2544	188	18	similar	similar	ADJ
eurjchem-2544	188	19	to	to	ADP
eurjchem-2544	188	20	that	that	PRON
eurjchem-2544	188	21	extracted	extract	VERB
eurjchem-2544	188	22	from	from	ADP
eurjchem-2544	188	23	[	[	X
eurjchem-2544	188	24	co(cs2net2)2	co(cs2net2)2	X
eurjchem-2544	188	25	]	]	X
eurjchem-2544	189	1	[	[	X
eurjchem-2544	189	2	33	33	NUM
eurjchem-2544	189	3	]	]	PUNCT
eurjchem-2544	189	4	.	.	PUNCT
eurjchem-2544	190	1	in	in	ADP
eurjchem-2544	190	2	its	its	PRON
eurjchem-2544	190	3	cos6	cos6	NOUN
eurjchem-2544	190	4	coordination	coordination	NOUN
eurjchem-2544	190	5	polyhedron	polyhedron	NOUN
eurjchem-2544	190	6	,	,	PUNCT
eurjchem-2544	190	7	the	the	DET
eurjchem-2544	190	8	mean	mean	ADJ
eurjchem-2544	190	9	co	co	NOUN
eurjchem-2544	190	10	-	-	NOUN
eurjchem-2544	190	11	s	s	PART
eurjchem-2544	190	12	bond	bond	NOUN
eurjchem-2544	190	13	distance	distance	NOUN
eurjchem-2544	190	14	of	of	ADP
eurjchem-2544	190	15	2.275	2.275	NUM
eurjchem-2544	190	16	å	å	NOUN
eurjchem-2544	190	17	is	be	AUX
eurjchem-2544	190	18	longer	long	ADJ
eurjchem-2544	190	19	and	and	CCONJ
eurjchem-2544	190	20	weaker	weak	ADJ
eurjchem-2544	190	21	than	than	ADP
eurjchem-2544	190	22	2.258	2.258	NUM
eurjchem-2544	190	23	å	å	PROPN
eurjchem-2544	190	24	found	find	VERB
eurjchem-2544	190	25	in	in	ADP
eurjchem-2544	190	26	the	the	DET
eurjchem-2544	190	27	diethyl	diethyl	NOUN
eurjchem-2544	190	28	derivative	derivative	NOUN
eurjchem-2544	191	1	[	[	X
eurjchem-2544	191	2	8,33	8,33	NUM
eurjchem-2544	191	3	]	]	PUNCT
eurjchem-2544	191	4	.	.	PUNCT
eurjchem-2544	192	1	the	the	DET
eurjchem-2544	192	2	reason	reason	NOUN
eurjchem-2544	192	3	for	for	ADP
eurjchem-2544	192	4	the	the	DET
eurjchem-2544	192	5	disparity	disparity	NOUN
eurjchem-2544	192	6	is	be	AUX
eurjchem-2544	192	7	attached	attach	VERB
eurjchem-2544	192	8	to	to	ADP
eurjchem-2544	192	9	the	the	DET
eurjchem-2544	192	10	diminished	diminished	ADJ
eurjchem-2544	192	11	accuracy	accuracy	NOUN
eurjchem-2544	192	12	of	of	ADP
eurjchem-2544	192	13	the	the	DET
eurjchem-2544	192	14	crystal	crystal	NOUN
eurjchem-2544	192	15	data	datum	NOUN
eurjchem-2544	192	16	[	[	X
eurjchem-2544	192	17	36	36	NUM
eurjchem-2544	192	18	-	-	SYM
eurjchem-2544	192	19	38	38	NUM
eurjchem-2544	192	20	]	]	PUNCT
eurjchem-2544	192	21	,	,	PUNCT
eurjchem-2544	192	22	where	where	SCONJ
eurjchem-2544	192	23	the	the	DET
eurjchem-2544	192	24	m	m	PROPN
eurjchem-2544	192	25	-	-	PUNCT
eurjchem-2544	192	26	s	s	NOUN
eurjchem-2544	192	27	bond	bond	NOUN
eurjchem-2544	192	28	distance	distance	NOUN
eurjchem-2544	192	29	is	be	AUX
eurjchem-2544	192	30	a	a	DET
eurjchem-2544	192	31	function	function	NOUN
eurjchem-2544	192	32	of	of	ADP
eurjchem-2544	192	33	the	the	DET
eurjchem-2544	192	34	crystal	crystal	NOUN
eurjchem-2544	192	35	field	field	NOUN
eurjchem-2544	192	36	components	component	NOUN
eurjchem-2544	192	37	of	of	ADP
eurjchem-2544	192	38	the	the	DET
eurjchem-2544	192	39	disubstituted	disubstitute	VERB
eurjchem-2544	192	40	ligand	ligand	NOUN
eurjchem-2544	192	41	which	which	PRON
eurjchem-2544	192	42	tends	tend	VERB
eurjchem-2544	192	43	to	to	PART
eurjchem-2544	192	44	decrease	decrease	VERB
eurjchem-2544	192	45	by	by	ADP
eurjchem-2544	192	46	0.03	0.03	NUM
eurjchem-2544	192	47	å	å	NOUN
eurjchem-2544	192	48	on	on	ADP
eurjchem-2544	192	49	switching	switch	VERB
eurjchem-2544	192	50	from	from	ADP
eurjchem-2544	192	51	a	a	DET
eurjchem-2544	192	52	strong	strong	ADJ
eurjchem-2544	192	53	field	field	NOUN
eurjchem-2544	192	54	ligand	ligand	NOUN
eurjchem-2544	192	55	such	such	ADJ
eurjchem-2544	192	56	as	as	ADP
eurjchem-2544	192	57	[	[	X
eurjchem-2544	192	58	cs2nipr2]to	cs2nipr2]to	PROPN
eurjchem-2544	192	59	a	a	DET
eurjchem-2544	192	60	weak	weak	ADJ
eurjchem-2544	192	61	field	field	NOUN
eurjchem-2544	192	62	ligand	ligand	NOUN
eurjchem-2544	192	63	such	such	ADJ
eurjchem-2544	192	64	as	as	ADP
eurjchem-2544	192	65	[	[	X
eurjchem-2544	192	66	cs2nh2]-	cs2nh2]-	NOUN
eurjchem-2544	192	67	.	.	PUNCT
eurjchem-2544	193	1	the	the	DET
eurjchem-2544	193	2	disparities	disparity	NOUN
eurjchem-2544	193	3	could	could	AUX
eurjchem-2544	193	4	alternatively	alternatively	ADV
eurjchem-2544	193	5	be	be	AUX
eurjchem-2544	193	6	connected	connect	VERB
eurjchem-2544	193	7	to	to	ADP
eurjchem-2544	193	8	the	the	DET
eurjchem-2544	193	9	varying	vary	VERB
eurjchem-2544	193	10	thermal	thermal	ADJ
eurjchem-2544	193	11	motion	motion	NOUN
eurjchem-2544	193	12	of	of	ADP
eurjchem-2544	193	13	the	the	DET
eurjchem-2544	193	14	structures	structure	NOUN
eurjchem-2544	193	15	,	,	PUNCT
eurjchem-2544	193	16	with	with	ADP
eurjchem-2544	193	17	the	the	DET
eurjchem-2544	193	18	unsubstituted	unsubstituted	ADJ
eurjchem-2544	193	19	compound	compound	NOUN
eurjchem-2544	193	20	expected	expect	VERB
eurjchem-2544	193	21	to	to	PART
eurjchem-2544	193	22	possess	possess	VERB
eurjchem-2544	193	23	less	less	ADJ
eurjchem-2544	193	24	thermal	thermal	ADJ
eurjchem-2544	193	25	motion	motion	NOUN
eurjchem-2544	193	26	than	than	ADP
eurjchem-2544	193	27	the	the	DET
eurjchem-2544	193	28	diethyl	diethyl	NOUN
eurjchem-2544	193	29	derivative	derivative	NOUN
eurjchem-2544	193	30	.	.	PUNCT
eurjchem-2544	194	1	in	in	ADP
eurjchem-2544	194	2	complex	complex	ADJ
eurjchem-2544	194	3	7	7	NUM
eurjchem-2544	194	4	,	,	PUNCT
eurjchem-2544	194	5	the	the	DET
eurjchem-2544	194	6	systematic	systematic	ADJ
eurjchem-2544	194	7	distortion	distortion	NOUN
eurjchem-2544	194	8	of	of	ADP
eurjchem-2544	194	9	the	the	DET
eurjchem-2544	194	10	cos6	cos6	PROPN
eurjchem-2544	194	11	coordination	coordination	NOUN
eurjchem-2544	194	12	core	core	NOUN
eurjchem-2544	194	13	reduces	reduce	VERB
eurjchem-2544	194	14	the	the	DET
eurjchem-2544	194	15	symmetry	symmetry	NOUN
eurjchem-2544	194	16	from	from	ADP
eurjchem-2544	194	17	d3	d3	PROPN
eurjchem-2544	194	18	to	to	ADP
eurjchem-2544	194	19	c3	c3	PROPN
eurjchem-2544	194	20	,	,	PUNCT
eurjchem-2544	194	21	resulting	result	VERB
eurjchem-2544	194	22	in	in	ADP
eurjchem-2544	194	23	asymmetric	asymmetric	ADJ
eurjchem-2544	194	24	co	co	NOUN
eurjchem-2544	194	25	-	-	PROPN
eurjchem-2544	194	26	s	s	PART
eurjchem-2544	194	27	bond	bond	NOUN
eurjchem-2544	194	28	distances	distance	NOUN
eurjchem-2544	194	29	as	as	ADV
eurjchem-2544	194	30	well	well	ADV
eurjchem-2544	194	31	as	as	ADP
eurjchem-2544	194	32	s	s	NOUN
eurjchem-2544	194	33	-	-	PUNCT
eurjchem-2544	194	34	co	co	NOUN
eurjchem-2544	194	35	-	-	ADJ
eurjchem-2544	194	36	s	s	PART
eurjchem-2544	194	37	bond	bond	NOUN
eurjchem-2544	194	38	angles	angle	NOUN
eurjchem-2544	194	39	.	.	PUNCT
eurjchem-2544	195	1	the	the	DET
eurjchem-2544	195	2	asymmetry	asymmetry	NOUN
eurjchem-2544	195	3	in	in	ADP
eurjchem-2544	195	4	this	this	DET
eurjchem-2544	195	5	case	case	NOUN
eurjchem-2544	195	6	culminates	culminate	VERB
eurjchem-2544	195	7	in	in	ADP
eurjchem-2544	195	8	an	an	DET
eurjchem-2544	195	9	increase	increase	NOUN
eurjchem-2544	195	10	in	in	ADP
eurjchem-2544	195	11	the	the	DET
eurjchem-2544	195	12	number	number	NOUN
eurjchem-2544	195	13	of	of	ADP
eurjchem-2544	195	14	short	short	ADJ
eurjchem-2544	195	15	s···h	s···h	PROPN
eurjchem-2544	195	16	interactions	interaction	NOUN
eurjchem-2544	195	17	.	.	PUNCT
eurjchem-2544	196	1	trigonal	trigonal	ADJ
eurjchem-2544	196	2	pyramidal	pyramidal	ADJ
eurjchem-2544	196	3	distortions	distortion	NOUN
eurjchem-2544	196	4	were	be	AUX
eurjchem-2544	196	5	observed	observe	VERB
eurjchem-2544	196	6	about	about	ADP
eurjchem-2544	196	7	carbamate	carbamate	NOUN
eurjchem-2544	196	8	n	n	NOUN
eurjchem-2544	196	9	atoms	atom	NOUN
eurjchem-2544	196	10	and	and	CCONJ
eurjchem-2544	196	11	these	these	PRON
eurjchem-2544	196	12	may	may	AUX
eurjchem-2544	196	13	emanate	emanate	VERB
eurjchem-2544	196	14	from	from	ADP
eurjchem-2544	196	15	hydrogen	hydrogen	NOUN
eurjchem-2544	196	16	bonding	bonding	NOUN
eurjchem-2544	196	17	interactions	interaction	NOUN
eurjchem-2544	196	18	,	,	PUNCT
eurjchem-2544	196	19	which	which	PRON
eurjchem-2544	196	20	expose	expose	VERB
eurjchem-2544	196	21	the	the	DET
eurjchem-2544	196	22	nitrogen	nitrogen	NOUN
eurjchem-2544	196	23	to	to	PART
eurjchem-2544	196	24	sp3	sp3	VERB
eurjchem-2544	196	25	orbital	orbital	ADJ
eurjchem-2544	196	26	contribution	contribution	NOUN
eurjchem-2544	196	27	.	.	PUNCT
eurjchem-2544	197	1	the	the	DET
eurjchem-2544	197	2	difficult	difficult	ADJ
eurjchem-2544	197	3	scattering	scatter	VERB
eurjchem-2544	197	4	model	model	NOUN
eurjchem-2544	197	5	of	of	ADP
eurjchem-2544	197	6	the	the	DET
eurjchem-2544	197	7	hydrogen	hydrogen	NOUN
eurjchem-2544	197	8	atoms	atom	NOUN
eurjchem-2544	197	9	of	of	ADP
eurjchem-2544	197	10	complex	complex	ADJ
eurjchem-2544	197	11	7	7	NUM
eurjchem-2544	197	12	is	be	AUX
eurjchem-2544	197	13	responsible	responsible	ADJ
eurjchem-2544	197	14	for	for	ADP
eurjchem-2544	197	15	the	the	DET
eurjchem-2544	197	16	shorter	short	ADJ
eurjchem-2544	197	17	mean	mean	NOUN
eurjchem-2544	198	1	c	c	X
eurjchem-2544	198	2	-	-	PUNCT
eurjchem-2544	198	3	s	s	NOUN
eurjchem-2544	198	4	bond	bond	NOUN
eurjchem-2544	198	5	distance	distance	NOUN
eurjchem-2544	198	6	of	of	ADP
eurjchem-2544	198	7	1.70(2	1.70(2	NUM
eurjchem-2544	198	8	)	)	PUNCT
eurjchem-2544	198	9	å	å	NOUN
eurjchem-2544	198	10	compared	compare	VERB
eurjchem-2544	198	11	to	to	ADP
eurjchem-2544	198	12	those	those	PRON
eurjchem-2544	198	13	of	of	ADP
eurjchem-2544	198	14	the	the	DET
eurjchem-2544	198	15	accurately	accurately	ADV
eurjchem-2544	198	16	solved	solve	VERB
eurjchem-2544	198	17	diethyldithiocarbamate	diethyldithiocarbamate	NOUN
eurjchem-2544	198	18	crystal	crystal	NOUN
eurjchem-2544	198	19	,	,	PUNCT
eurjchem-2544	198	20	which	which	PRON
eurjchem-2544	198	21	is	be	AUX
eurjchem-2544	198	22	in	in	ADP
eurjchem-2544	198	23	the	the	DET
eurjchem-2544	198	24	range	range	NOUN
eurjchem-2544	198	25	1.71	1.71	NUM
eurjchem-2544	198	26	-	-	SYM
eurjchem-2544	198	27	1.73	1.73	NUM
eurjchem-2544	198	28	å	å	NOUN
eurjchem-2544	198	29	.	.	PUNCT
eurjchem-2544	199	1	likewise	likewise	ADV
eurjchem-2544	199	2	,	,	PUNCT
eurjchem-2544	199	3	the	the	DET
eurjchem-2544	199	4	mean	mean	ADJ
eurjchem-2544	199	5	c	c	NOUN
eurjchem-2544	199	6	-	-	PUNCT
eurjchem-2544	199	7	n	n	PRON
eurjchem-2544	199	8	bond	bond	NOUN
eurjchem-2544	199	9	distance	distance	NOUN
eurjchem-2544	199	10	of	of	ADP
eurjchem-2544	199	11	1.32(1	1.32(1	NUM
eurjchem-2544	199	12	)	)	PUNCT
eurjchem-2544	199	13	å	å	PROPN
eurjchem-2544	199	14	is	be	AUX
eurjchem-2544	199	15	even	even	ADV
eurjchem-2544	199	16	much	much	ADV
eurjchem-2544	199	17	shorter	short	ADJ
eurjchem-2544	199	18	than	than	ADP
eurjchem-2544	199	19	that	that	PRON
eurjchem-2544	199	20	observed	observe	VERB
eurjchem-2544	199	21	in	in	ADP
eurjchem-2544	199	22	accurately	accurately	ADV
eurjchem-2544	199	23	solved	solve	VERB
eurjchem-2544	199	24	diethyldithio	diethyldithio	NOUN
eurjchem-2544	199	25	-	-	PUNCT
eurjchem-2544	199	26	carbamate	carbamate	NOUN
eurjchem-2544	199	27	.	.	PUNCT
eurjchem-2544	200	1	these	these	DET
eurjchem-2544	200	2	data	datum	NOUN
eurjchem-2544	200	3	lend	lend	VERB
eurjchem-2544	200	4	fact	fact	NOUN
eurjchem-2544	200	5	to	to	ADP
eurjchem-2544	200	6	the	the	DET
eurjchem-2544	200	7	wrong	wrong	NOUN
eurjchem-2544	200	8	and	and	CCONJ
eurjchem-2544	200	9	longer	long	ADJ
eurjchem-2544	200	10	than	than	ADP
eurjchem-2544	200	11	normal	normal	ADJ
eurjchem-2544	200	12	estimation	estimation	NOUN
eurjchem-2544	200	13	of	of	ADP
eurjchem-2544	200	14	1.37(5	1.37(5	NUM
eurjchem-2544	200	15	)	)	PUNCT
eurjchem-2544	200	16	å	å	PROPN
eurjchem-2544	200	17	for	for	ADP
eurjchem-2544	200	18	the	the	DET
eurjchem-2544	200	19	c	c	PROPN
eurjchem-2544	200	20	-	-	PUNCT
eurjchem-2544	200	21	n	n	PRON
eurjchem-2544	200	22	bond	bond	NOUN
eurjchem-2544	200	23	in	in	ADP
eurjchem-2544	200	24	[	[	X
eurjchem-2544	200	25	ni(cs2nh2)2	ni(cs2nh2)2	ADJ
eurjchem-2544	200	26	.	.	PUNCT
eurjchem-2544	201	1	one	one	NUM
eurjchem-2544	201	2	reason	reason	NOUN
eurjchem-2544	201	3	for	for	ADP
eurjchem-2544	201	4	the	the	DET
eurjchem-2544	201	5	overestimation	overestimation	NOUN
eurjchem-2544	201	6	is	be	AUX
eurjchem-2544	201	7	the	the	DET
eurjchem-2544	201	8	bias	bias	NOUN
eurjchem-2544	201	9	of	of	ADP
eurjchem-2544	201	10	the	the	DET
eurjchem-2544	201	11	position	position	NOUN
eurjchem-2544	201	12	of	of	ADP
eurjchem-2544	201	13	carbamate	carbamate	ADJ
eurjchem-2544	201	14	nitrogen	nitrogen	NOUN
eurjchem-2544	201	15	around	around	ADP
eurjchem-2544	201	16	hydrogen	hydrogen	NOUN
eurjchem-2544	201	17	atoms	atom	NOUN
eurjchem-2544	201	18	[	[	X
eurjchem-2544	201	19	32	32	NUM
eurjchem-2544	201	20	]	]	PUNCT
eurjchem-2544	201	21	.	.	PUNCT
eurjchem-2544	202	1	its	its	PRON
eurjchem-2544	202	2	crystal	crystal	NOUN
eurjchem-2544	202	3	lattice	lattice	NOUN
eurjchem-2544	202	4	is	be	AUX
eurjchem-2544	202	5	dominated	dominate	VERB
eurjchem-2544	202	6	by	by	ADP
eurjchem-2544	202	7	short	short	ADJ
eurjchem-2544	202	8	intermolecular	intermolecular	ADJ
eurjchem-2544	202	9	n	n	CCONJ
eurjchem-2544	202	10	-	-	PUNCT
eurjchem-2544	202	11	h···s	h···	NOUN
eurjchem-2544	202	12	,	,	PUNCT
eurjchem-2544	202	13	s2c···h	s2c···h	NOUN
eurjchem-2544	202	14	-	-	PUNCT
eurjchem-2544	202	15	n	n	NOUN
eurjchem-2544	202	16	and	and	CCONJ
eurjchem-2544	202	17	s···s	s···s	PROPN
eurjchem-2544	202	18	,	,	PUNCT
eurjchem-2544	202	19	sp3c···s	sp3c···s	NUM
eurjchem-2544	202	20	contacts	contact	NOUN
eurjchem-2544	202	21	.	.	PUNCT
eurjchem-2544	203	1	complex	complex	ADJ
eurjchem-2544	203	2	8	8	NUM
eurjchem-2544	203	3	’s	’s	PART
eurjchem-2544	203	4	(	(	PUNCT
eurjchem-2544	203	5	figure	figure	NOUN
eurjchem-2544	203	6	7	7	NUM
eurjchem-2544	203	7	)	)	PUNCT
eurjchem-2544	203	8	crystal	crystal	NOUN
eurjchem-2544	203	9	structure	structure	NOUN
eurjchem-2544	203	10	is	be	AUX
eurjchem-2544	203	11	part	part	NOUN
eurjchem-2544	203	12	of	of	ADP
eurjchem-2544	203	13	a	a	DET
eurjchem-2544	203	14	2:1	2:1	NUM
eurjchem-2544	203	15	salt	salt	NOUN
eurjchem-2544	203	16	of	of	ADP
eurjchem-2544	203	17	the	the	DET
eurjchem-2544	203	18	cation	cation	NOUN
eurjchem-2544	203	19	[	[	X
eurjchem-2544	203	20	co(s2cnet2)2(dppe)]+	co(s2cnet2)2(dppe)]+	X
eurjchem-2544	203	21	and	and	CCONJ
eurjchem-2544	203	22	anion	anion	NOUN
eurjchem-2544	203	23	[	[	X
eurjchem-2544	203	24	cl3zno	cl3zno	PROPN
eurjchem-2544	203	25	:	:	PUNCT
eurjchem-2544	203	26	o(ph)2	o(ph)2	NUM
eurjchem-2544	203	27	pch2ch2p(ph)2	pch2ch2p(ph)2	NOUN
eurjchem-2544	203	28	:	:	PUNCT
eurjchem-2544	203	29	ozncl3]2[39	ozncl3]2[39	NOUN
eurjchem-2544	203	30	]	]	PUNCT
eurjchem-2544	203	31	.	.	PUNCT
eurjchem-2544	204	1	it	it	PRON
eurjchem-2544	204	2	crystallizes	crystallize	VERB
eurjchem-2544	204	3	in	in	ADP
eurjchem-2544	204	4	the	the	DET
eurjchem-2544	204	5	triclinic	triclinic	ADJ
eurjchem-2544	204	6	p-1	p-1	NOUN
eurjchem-2544	204	7	space	space	NOUN
eurjchem-2544	204	8	group	group	NOUN
eurjchem-2544	204	9	.	.	PUNCT
eurjchem-2544	205	1	the	the	DET
eurjchem-2544	205	2	salt	salt	NOUN
eurjchem-2544	205	3	[	[	X
eurjchem-2544	205	4	co(s2cnme2)2(dmpf)][bph4	co(s2cnme2)2(dmpf)][bph4	X
eurjchem-2544	205	5	]	]	X
eurjchem-2544	206	1	[	[	X
eurjchem-2544	206	2	3	3	NUM
eurjchem-2544	206	3	]	]	PUNCT
eurjchem-2544	206	4	,	,	PUNCT
eurjchem-2544	206	5	where	where	SCONJ
eurjchem-2544	206	6	dmpf	dmpf	NOUN
eurjchem-2544	206	7	=	=	SYM
eurjchem-2544	206	8	1,1’-bis(dimethylphosphino)ferrocene	1,1’-bis(dimethylphosphino)ferrocene	NUM
eurjchem-2544	206	9	,	,	PUNCT
eurjchem-2544	206	10	shares	share	VERB
eurjchem-2544	206	11	close	close	ADJ
eurjchem-2544	206	12	similarities	similarity	NOUN
eurjchem-2544	206	13	with	with	ADP
eurjchem-2544	206	14	complex	complex	ADJ
eurjchem-2544	206	15	8	8	NUM
eurjchem-2544	206	16	.	.	PUNCT
eurjchem-2544	207	1	they	they	PRON
eurjchem-2544	207	2	both	both	PRON
eurjchem-2544	207	3	possess	possess	VERB
eurjchem-2544	207	4	similar	similar	ADJ
eurjchem-2544	207	5	co	co	NOUN
eurjchem-2544	207	6	-	-	NOUN
eurjchem-2544	207	7	s	s	X
eurjchem-2544	207	8	and	and	CCONJ
eurjchem-2544	207	9	co	co	ADJ
eurjchem-2544	207	10	-	-	ADJ
eurjchem-2544	207	11	p	p	ADJ
eurjchem-2544	207	12	bond	bond	NOUN
eurjchem-2544	207	13	distances	distance	NOUN
eurjchem-2544	207	14	.	.	PUNCT
eurjchem-2544	208	1	the	the	DET
eurjchem-2544	208	2	trans	trans	PROPN
eurjchem-2544	208	3	influence	influence	NOUN
eurjchem-2544	208	4	of	of	ADP
eurjchem-2544	208	5	the	the	DET
eurjchem-2544	208	6	p	p	NOUN
eurjchem-2544	208	7	-	-	PUNCT
eurjchem-2544	208	8	donor	donor	NOUN
eurjchem-2544	208	9	of	of	ADP
eurjchem-2544	208	10	the	the	DET
eurjchem-2544	208	11	ligand	ligand	NOUN
eurjchem-2544	208	12	is	be	AUX
eurjchem-2544	208	13	reflected	reflect	VERB
eurjchem-2544	208	14	in	in	ADP
eurjchem-2544	208	15	the	the	DET
eurjchem-2544	208	16	co	co	NOUN
eurjchem-2544	208	17	-	-	NOUN
eurjchem-2544	208	18	s	s	PART
eurjchem-2544	208	19	trans	tran	NOUN
eurjchem-2544	208	20	to	to	ADP
eurjchem-2544	208	21	p	p	NOUN
eurjchem-2544	208	22	being	be	AUX
eurjchem-2544	208	23	longer	long	ADJ
eurjchem-2544	208	24	than	than	ADP
eurjchem-2544	208	25	the	the	DET
eurjchem-2544	208	26	co	co	NOUN
eurjchem-2544	208	27	-	-	NOUN
eurjchem-2544	208	28	s	s	PART
eurjchem-2544	208	29	trans	tran	NOUN
eurjchem-2544	208	30	to	to	ADP
eurjchem-2544	208	31	s	s	PRON
eurjchem-2544	208	32	by	by	ADP
eurjchem-2544	208	33	0.03	0.03	NUM
eurjchem-2544	208	34	å	å	PROPN
eurjchem-2544	208	35	[	[	X
eurjchem-2544	208	36	8	8	NUM
eurjchem-2544	208	37	]	]	PUNCT
eurjchem-2544	208	38	.	.	PUNCT
eurjchem-2544	209	1	the	the	DET
eurjchem-2544	209	2	bite	bite	NOUN
eurjchem-2544	209	3	angle	angle	NOUN
eurjchem-2544	209	4	around	around	ADP
eurjchem-2544	209	5	the	the	DET
eurjchem-2544	209	6	cobalt	cobalt	NOUN
eurjchem-2544	209	7	centres	centre	NOUN
eurjchem-2544	209	8	of	of	ADP
eurjchem-2544	209	9	the	the	DET
eurjchem-2544	209	10	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	209	11	ligands	ligand	NOUN
eurjchem-2544	209	12	for	for	ADP
eurjchem-2544	209	13	the	the	DET
eurjchem-2544	209	14	two	two	NUM
eurjchem-2544	209	15	complexes	complex	NOUN
eurjchem-2544	209	16	is	be	AUX
eurjchem-2544	209	17	~76	~76	NUM
eurjchem-2544	209	18	°	°	NOUN
eurjchem-2544	209	19	while	while	SCONJ
eurjchem-2544	209	20	dmpf	dmpf	NOUN
eurjchem-2544	209	21	’s	’s	PART
eurjchem-2544	209	22	bite	bite	NOUN
eurjchem-2544	209	23	angle	angle	NOUN
eurjchem-2544	209	24	of	of	ADP
eurjchem-2544	209	25	102.3(1	102.3(1	NUM
eurjchem-2544	209	26	)	)	PUNCT
eurjchem-2544	209	27	°	°	PROPN
eurjchem-2544	209	28	around	around	ADP
eurjchem-2544	209	29	the	the	DET
eurjchem-2544	209	30	co(iii	co(iii	NOUN
eurjchem-2544	209	31	)	)	PUNCT
eurjchem-2544	209	32	centre	centre	NOUN
eurjchem-2544	209	33	is	be	AUX
eurjchem-2544	209	34	greater	great	ADJ
eurjchem-2544	209	35	than	than	ADP
eurjchem-2544	209	36	dppe	dppe	PROPN
eurjchem-2544	209	37	’s	’s	PART
eurjchem-2544	209	38	87.01(2)	87.01(2)	NOUN
eurjchem-2544	209	39	°	°	NOUN
eurjchem-2544	209	40	.	.	PUNCT
eurjchem-2544	210	1	the	the	DET
eurjchem-2544	210	2	anion	anion	NOUN
eurjchem-2544	210	3	[	[	X
eurjchem-2544	210	4	cl3zno	cl3zno	PROPN
eurjchem-2544	210	5	:	:	PUNCT
eurjchem-2544	210	6	o(ph)2pch2ch2p(ph)2	o(ph)2pch2ch2p(ph)2	NOUN
eurjchem-2544	210	7	:	:	PUNCT
eurjchem-2544	210	8	ozncl3]2is	ozncl3]2is	NOUN
eurjchem-2544	210	9	peculiar	peculiar	ADJ
eurjchem-2544	210	10	for	for	ADP
eurjchem-2544	210	11	its	its	PRON
eurjchem-2544	210	12	bridging	bridging	NOUN
eurjchem-2544	210	13	1,2bis(diphenylphosphinoyl)ethane	1,2bis(diphenylphosphinoyl)ethane	PROPN
eurjchem-2544	210	14	ligand	ligand	NOUN
eurjchem-2544	210	15	.	.	PUNCT
eurjchem-2544	211	1	however	however	ADV
eurjchem-2544	211	2	,	,	PUNCT
eurjchem-2544	211	3	such	such	ADJ
eurjchem-2544	211	4	bridging	bridging	NOUN
eurjchem-2544	211	5	coordination	coordination	NOUN
eurjchem-2544	211	6	patterns	pattern	NOUN
eurjchem-2544	211	7	have	have	AUX
eurjchem-2544	211	8	previously	previously	ADV
eurjchem-2544	211	9	been	be	AUX
eurjchem-2544	211	10	reported	report	VERB
eurjchem-2544	211	11	in	in	ADP
eurjchem-2544	211	12	co(ii	co(ii	ADJ
eurjchem-2544	211	13	)	)	PUNCT
eurjchem-2544	211	14	complexes	complex	NOUN
eurjchem-2544	211	15	[	[	X
eurjchem-2544	211	16	cocl2{o:(ph)2pch2ch2p(ph)2	cocl2{o:(ph)2pch2ch2p(ph)2	NOUN
eurjchem-2544	211	17	:	:	PUNCT
eurjchem-2544	211	18	o}]2	o}]2	ADJ
eurjchem-2544	211	19	;	;	PUNCT
eurjchem-2544	211	20	a	a	DET
eurjchem-2544	211	21	cyclic	cyclic	ADJ
eurjchem-2544	211	22	dimer	dimer	NOUN
eurjchem-2544	212	1	[	[	X
eurjchem-2544	212	2	40	40	NUM
eurjchem-2544	212	3	]	]	PUNCT
eurjchem-2544	212	4	,	,	PUNCT
eurjchem-2544	213	1	[	[	X
eurjchem-2544	213	2	cocl2{o:(ph)2pch2ch2p(ph)2	cocl2{o:(ph)2pch2ch2p(ph)2	ADP
eurjchem-2544	213	3	:	:	PUNCT
eurjchem-2544	213	4	o}]n	o}]n	PROPN
eurjchem-2544	213	5	,	,	PUNCT
eurjchem-2544	213	6	a	a	DET
eurjchem-2544	213	7	linear	linear	ADJ
eurjchem-2544	213	8	polymeric	polymeric	ADJ
eurjchem-2544	213	9	complex	complex	NOUN
eurjchem-2544	214	1	[	[	X
eurjchem-2544	214	2	39	39	NUM
eurjchem-2544	214	3	]	]	PUNCT
eurjchem-2544	214	4	and	and	CCONJ
eurjchem-2544	214	5	[	[	X
eurjchem-2544	214	6	co(co)(dppe)2cl3coo:(ph)2pch2ch2	co(co)(dppe)2cl3coo:(ph)2pch2ch2	PROPN
eurjchem-2544	214	7	p(ph)2	p(ph)2	NOUN
eurjchem-2544	214	8	:	:	PUNCT
eurjchem-2544	214	9	ococl3	ococl3	PROPN
eurjchem-2544	214	10	]	]	PUNCT
eurjchem-2544	214	11	;	;	PUNCT
eurjchem-2544	214	12	an	an	DET
eurjchem-2544	214	13	ionic	ionic	ADJ
eurjchem-2544	214	14	coordination	coordination	NOUN
eurjchem-2544	214	15	salt	salt	NOUN
eurjchem-2544	214	16	[	[	X
eurjchem-2544	214	17	39	39	NUM
eurjchem-2544	214	18	]	]	PUNCT
eurjchem-2544	214	19	.	.	PUNCT
eurjchem-2544	214	20	di(n	di(n	NOUN
eurjchem-2544	214	21	,	,	PUNCT
eurjchem-2544	214	22	ndiethyldithiocarbamato)[1	ndiethyldithiocarbamato)[1	NOUN
eurjchem-2544	214	23	,	,	PUNCT
eurjchem-2544	214	24	2	2	NUM
eurjchem-2544	214	25	-	-	SYM
eurjchem-2544	214	26	bis(diphenylphosphine)ethane	bis(diphenylphosphine)ethane	NUM
eurjchem-2544	214	27	]	]	PUNCT
eurjchem-2544	214	28	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	214	29	)	)	PUNCT
eurjchem-2544	214	30	tetrachlorocadimate	tetrachlorocadimate	NOUN
eurjchem-2544	214	31	{	{	PUNCT
eurjchem-2544	214	32	[	[	X
eurjchem-2544	214	33	co(s2cnet2)2(dppe)]2[cdcl4	co(s2cnet2)2(dppe)]2[cdcl4	X
eurjchem-2544	214	34	]	]	X
eurjchem-2544	214	35	which	which	PRON
eurjchem-2544	214	36	shares	share	VERB
eurjchem-2544	214	37	a	a	DET
eurjchem-2544	214	38	similar	similar	ADJ
eurjchem-2544	214	39	cation	cation	NOUN
eurjchem-2544	214	40	with	with	ADP
eurjchem-2544	214	41	complex	complex	ADJ
eurjchem-2544	214	42	8	8	NUM
eurjchem-2544	214	43	crystallizes	crystallize	NOUN
eurjchem-2544	214	44	in	in	ADP
eurjchem-2544	214	45	the	the	DET
eurjchem-2544	214	46	triclinic	triclinic	ADJ
eurjchem-2544	214	47	p-1	p-1	NOUN
eurjchem-2544	214	48	space	space	NOUN
eurjchem-2544	214	49	group	group	NOUN
eurjchem-2544	214	50	.	.	PUNCT
eurjchem-2544	215	1	its	its	PRON
eurjchem-2544	215	2	crystal	crystal	NOUN
eurjchem-2544	215	3	lattice	lattice	NOUN
eurjchem-2544	215	4	is	be	AUX
eurjchem-2544	215	5	dominated	dominate	VERB
eurjchem-2544	215	6	by	by	ADP
eurjchem-2544	215	7	a	a	DET
eurjchem-2544	215	8	considerably	considerably	ADV
eurjchem-2544	215	9	distorted	distorted	ADJ
eurjchem-2544	215	10	structure	structure	NOUN
eurjchem-2544	215	11	coupled	couple	VERB
eurjchem-2544	215	12	with	with	ADP
eurjchem-2544	215	13	a	a	DET
eurjchem-2544	215	14	substantial	substantial	ADJ
eurjchem-2544	215	15	amount	amount	NOUN
eurjchem-2544	215	16	of	of	ADP
eurjchem-2544	215	17	chloroform	chloroform	NOUN
eurjchem-2544	215	18	solvates	solvate	NOUN
eurjchem-2544	215	19	.	.	PUNCT
eurjchem-2544	216	1	therefore	therefore	ADV
eurjchem-2544	216	2	,	,	PUNCT
eurjchem-2544	216	3	only	only	ADV
eurjchem-2544	216	4	its	its	PRON
eurjchem-2544	216	5	unit	unit	NOUN
eurjchem-2544	216	6	cell	cell	NOUN
eurjchem-2544	216	7	parameters	parameter	NOUN
eurjchem-2544	216	8	a	a	DET
eurjchem-2544	216	9	=	=	NUM
eurjchem-2544	216	10	23.6388	23.6388	NUM
eurjchem-2544	216	11	10	10	NUM
eurjchem-2544	216	12	)	)	PUNCT
eurjchem-2544	216	13	å	å	PROPN
eurjchem-2544	216	14	,	,	PUNCT
eurjchem-2544	216	15	b	b	X
eurjchem-2544	216	16	=	=	SYM
eurjchem-2544	216	17	11.4468(4	11.4468(4	NUM
eurjchem-2544	216	18	)	)	PUNCT
eurjchem-2544	216	19	å	å	NOUN
eurjchem-2544	216	20	,	,	PUNCT
eurjchem-2544	216	21	c	c	NOUN
eurjchem-2544	216	22	=	=	SYM
eurjchem-2544	216	23	47.2679(2	47.2679(2	PROPN
eurjchem-2544	216	24	)	)	PUNCT
eurjchem-2544	216	25	å	å	NOUN
eurjchem-2544	216	26	,	,	PUNCT
eurjchem-2544	216	27	and	and	CCONJ
eurjchem-2544	216	28	β	β	X
eurjchem-2544	216	29	=	=	SYM
eurjchem-2544	217	1	104.0990	104.0990	NUM
eurjchem-2544	217	2	°	°	NOUN
eurjchem-2544	217	3	were	be	AUX
eurjchem-2544	217	4	determined	determine	VERB
eurjchem-2544	217	5	[	[	PUNCT
eurjchem-2544	217	6	39	39	NUM
eurjchem-2544	217	7	]	]	PUNCT
eurjchem-2544	217	8	.	.	PUNCT
eurjchem-2544	218	1	its	its	PRON
eurjchem-2544	218	2	crystal	crystal	NOUN
eurjchem-2544	218	3	lattice	lattice	NOUN
eurjchem-2544	218	4	is	be	AUX
eurjchem-2544	218	5	dominated	dominate	VERB
eurjchem-2544	218	6	by	by	ADP
eurjchem-2544	218	7	short	short	ADJ
eurjchem-2544	218	8	intermolecular	intermolecular	ADJ
eurjchem-2544	218	9	c···h	c···h	PROPN
eurjchem-2544	218	10	,	,	PUNCT
eurjchem-2544	218	11	h···h	h···h	PROPN
eurjchem-2544	218	12	,	,	PUNCT
eurjchem-2544	218	13	h···cl	h···cl	NOUN
eurjchem-2544	218	14	,	,	PUNCT
eurjchem-2544	218	15	s···cl	s···cl	NOUN
eurjchem-2544	218	16	,	,	PUNCT
eurjchem-2544	218	17	c···c	c···c	PROPN
eurjchem-2544	218	18	,	,	PUNCT
eurjchem-2544	218	19	and	and	CCONJ
eurjchem-2544	218	20	c···cl	c···cl	NOUN
eurjchem-2544	218	21	contacts	contact	NOUN
eurjchem-2544	218	22	.	.	PUNCT
eurjchem-2544	219	1	shotonwa	shotonwa	PROPN
eurjchem-2544	219	2	et	et	PROPN
eurjchem-2544	219	3	al	al	PROPN
eurjchem-2544	219	4	.	.	PUNCT
eurjchem-2544	219	5	/	/	SYM
eurjchem-2544	219	6	european	european	PROPN
eurjchem-2544	219	7	journal	journal	PROPN
eurjchem-2544	219	8	of	of	ADP
eurjchem-2544	219	9	chemistry	chemistry	NOUN
eurjchem-2544	219	10	15	15	NUM
eurjchem-2544	219	11	(	(	PUNCT
eurjchem-2544	219	12	3	3	NUM
eurjchem-2544	219	13	)	)	PUNCT
eurjchem-2544	219	14	(	(	PUNCT
eurjchem-2544	219	15	2024	2024	NUM
eurjchem-2544	219	16	)	)	PUNCT
eurjchem-2544	219	17	291	291	NUM
eurjchem-2544	219	18	-	-	SYM
eurjchem-2544	219	19	301	301	NUM
eurjchem-2544	219	20	297	297	NUM
eurjchem-2544	219	21	2024	2024	NUM
eurjchem-2544	219	22	–	–	PUNCT
eurjchem-2544	219	23	european	european	ADJ
eurjchem-2544	219	24	journal	journal	NOUN
eurjchem-2544	219	25	of	of	ADP
eurjchem-2544	219	26	chemistry	chemistry	NOUN
eurjchem-2544	219	27	–	–	PUNCT
eurjchem-2544	219	28	cc	cc	NOUN
eurjchem-2544	219	29	by	by	ADP
eurjchem-2544	219	30	nc	nc	PROPN
eurjchem-2544	219	31	–	–	PUNCT
eurjchem-2544	219	32	doi	doi	PROPN
eurjchem-2544	219	33	:	:	PUNCT
eurjchem-2544	219	34	10.5155	10.5155	NUM
eurjchem-2544	219	35	/	/	SYM
eurjchem-2544	219	36	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	219	37	-	-	PUNCT
eurjchem-2544	219	38	301.2544	301.2544	NUM
eurjchem-2544	219	39	figure	figure	NOUN
eurjchem-2544	219	40	9	9	NUM
eurjchem-2544	219	41	.	.	PUNCT
eurjchem-2544	220	1	molecular	molecular	ADJ
eurjchem-2544	220	2	structures	structure	NOUN
eurjchem-2544	220	3	of	of	ADP
eurjchem-2544	220	4	complexes	complex	NOUN
eurjchem-2544	220	5	11	11	NUM
eurjchem-2544	220	6	and	and	CCONJ
eurjchem-2544	220	7	12	12	NUM
eurjchem-2544	220	8	.	.	PUNCT
eurjchem-2544	221	1	figure	figure	NOUN
eurjchem-2544	221	2	10	10	NUM
eurjchem-2544	221	3	.	.	PUNCT
eurjchem-2544	222	1	molecular	molecular	ADJ
eurjchem-2544	222	2	structure	structure	NOUN
eurjchem-2544	222	3	of	of	ADP
eurjchem-2544	222	4	complexes	complex	NOUN
eurjchem-2544	222	5	13	13	NUM
eurjchem-2544	222	6	,	,	PUNCT
eurjchem-2544	222	7	14	14	NUM
eurjchem-2544	222	8	,	,	PUNCT
eurjchem-2544	222	9	and	and	CCONJ
eurjchem-2544	222	10	15	15	NUM
eurjchem-2544	222	11	.	.	X
eurjchem-2544	223	1	cis-[co(dtc)2(etpb)2]bf4	cis-[co(dtc)2(etpb)2]bf4	PROPN
eurjchem-2544	223	2	(	(	PUNCT
eurjchem-2544	223	3	dtc	dtc	NOUN
eurjchem-2544	223	4	=	=	SYM
eurjchem-2544	223	5	dimethyldithiocarbamaato	dimethyldithiocarbamaato	NOUN
eurjchem-2544	223	6	ion	ion	NOUN
eurjchem-2544	223	7	(	(	PUNCT
eurjchem-2544	223	8	ch3)2ncs2-	ch3)2ncs2-	NOUN
eurjchem-2544	223	9	)	)	PUNCT
eurjchem-2544	223	10	and	and	CCONJ
eurjchem-2544	223	11	etpb	etpb	NOUN
eurjchem-2544	223	12	=	=	SYM
eurjchem-2544	223	13	4	4	NUM
eurjchem-2544	223	14	-	-	PUNCT
eurjchem-2544	223	15	ethyl-2,6,7	ethyl-2,6,7	NOUN
eurjchem-2544	223	16	-	-	PUNCT
eurjchem-2544	223	17	trioxa-1	trioxa-1	NUM
eurjchem-2544	223	18	-	-	PUNCT
eurjchem-2544	223	19	phospha	phospha	NOUN
eurjchem-2544	223	20	bicyclo[2.2.2	bicyclo[2.2.2	NOUN
eurjchem-2544	223	21	]	]	X
eurjchem-2544	223	22	octane	octane	NOUN
eurjchem-2544	223	23	(	(	PUNCT
eurjchem-2544	223	24	p(och2)3cc2h5	p(och2)3cc2h5	NOUN
eurjchem-2544	223	25	)	)	PUNCT
eurjchem-2544	223	26	)	)	PUNCT
eurjchem-2544	224	1	(	(	PUNCT
eurjchem-2544	224	2	9	9	NUM
eurjchem-2544	224	3	,	,	PUNCT
eurjchem-2544	224	4	figure	figure	NOUN
eurjchem-2544	224	5	8)	8)	NUM
eurjchem-2544	224	6	crystallizes	crystallize	NOUN
eurjchem-2544	224	7	in	in	ADP
eurjchem-2544	224	8	the	the	DET
eurjchem-2544	224	9	monoclinic	monoclinic	ADJ
eurjchem-2544	224	10	c2	c2	PROPN
eurjchem-2544	224	11	/	/	SYM
eurjchem-2544	224	12	c	c	PROPN
eurjchem-2544	224	13	space	space	NOUN
eurjchem-2544	224	14	group	group	NOUN
eurjchem-2544	225	1	[	[	X
eurjchem-2544	225	2	4	4	NUM
eurjchem-2544	225	3	]	]	PUNCT
eurjchem-2544	225	4	.	.	PUNCT
eurjchem-2544	226	1	its	its	PRON
eurjchem-2544	226	2	central	central	ADJ
eurjchem-2544	226	3	co	co	NOUN
eurjchem-2544	226	4	ion	ion	NOUN
eurjchem-2544	226	5	sits	sit	VERB
eurjchem-2544	226	6	in	in	ADP
eurjchem-2544	226	7	a	a	DET
eurjchem-2544	226	8	distorted	distorted	ADJ
eurjchem-2544	226	9	octahedron	octahedron	NOUN
eurjchem-2544	226	10	that	that	PRON
eurjchem-2544	226	11	consists	consist	VERB
eurjchem-2544	226	12	of	of	ADP
eurjchem-2544	226	13	a	a	DET
eurjchem-2544	226	14	cis	cis	NOUN
eurjchem-2544	226	15	configuration	configuration	NOUN
eurjchem-2544	226	16	arrangement	arrangement	NOUN
eurjchem-2544	226	17	of	of	ADP
eurjchem-2544	226	18	two	two	NUM
eurjchem-2544	226	19	etpb	etpb	NOUN
eurjchem-2544	226	20	ligands	ligand	NOUN
eurjchem-2544	226	21	.	.	PUNCT
eurjchem-2544	227	1	the	the	DET
eurjchem-2544	227	2	mean	mean	ADJ
eurjchem-2544	227	3	distance	distance	NOUN
eurjchem-2544	227	4	of	of	ADP
eurjchem-2544	227	5	2.171(1	2.171(1	NUM
eurjchem-2544	227	6	)	)	PUNCT
eurjchem-2544	227	7	å	å	NOUN
eurjchem-2544	227	8	for	for	ADP
eurjchem-2544	227	9	co	co	NOUN
eurjchem-2544	227	10	-	-	NOUN
eurjchem-2544	227	11	p	p	ADJ
eurjchem-2544	227	12	bonds	bond	NOUN
eurjchem-2544	227	13	resembles	resemble	VERB
eurjchem-2544	227	14	the	the	DET
eurjchem-2544	227	15	2.165(3	2.165(3	NUM
eurjchem-2544	227	16	)	)	PUNCT
eurjchem-2544	227	17	å	å	PROPN
eurjchem-2544	227	18	reported	report	VERB
eurjchem-2544	227	19	for	for	ADP
eurjchem-2544	227	20	trans-[cocl(dmgh)2(pome	trans-[cocl(dmgh)2(pome	NOUN
eurjchem-2544	227	21	)	)	PUNCT
eurjchem-2544	227	22	,	,	PUNCT
eurjchem-2544	227	23	where	where	SCONJ
eurjchem-2544	227	24	dmgh	dmgh	NOUN
eurjchem-2544	227	25	=	=	SYM
eurjchem-2544	227	26	dimethylglyoximate	dimethylglyoximate	ADJ
eurjchem-2544	227	27	ion	ion	NOUN
eurjchem-2544	227	28	and	and	CCONJ
eurjchem-2544	227	29	pome	pome	NOUN
eurjchem-2544	227	30	=	=	SYM
eurjchem-2544	227	31	trimethylphosphite	trimethylphosphite	NOUN
eurjchem-2544	227	32	[	[	X
eurjchem-2544	227	33	p(och3)3	p(och3)3	X
eurjchem-2544	227	34	]	]	X
eurjchem-2544	228	1	[	[	X
eurjchem-2544	228	2	4	4	NUM
eurjchem-2544	228	3	]	]	PUNCT
eurjchem-2544	228	4	.	.	PUNCT
eurjchem-2544	229	1	these	these	DET
eurjchem-2544	229	2	distances	distance	NOUN
eurjchem-2544	229	3	are	be	AUX
eurjchem-2544	229	4	the	the	DET
eurjchem-2544	229	5	shortest	short	ADJ
eurjchem-2544	229	6	ever	ever	ADV
eurjchem-2544	229	7	reported	report	VERB
eurjchem-2544	229	8	for	for	ADP
eurjchem-2544	229	9	co	co	ADJ
eurjchem-2544	229	10	-	-	ADJ
eurjchem-2544	229	11	p	p	ADJ
eurjchem-2544	229	12	bonds	bond	NOUN
eurjchem-2544	229	13	in	in	ADP
eurjchem-2544	229	14	co(iii)-phospine	co(iii)-phospine	NOUN
eurjchem-2544	229	15	complexes	complex	NOUN
eurjchem-2544	229	16	.	.	PUNCT
eurjchem-2544	230	1	other	other	ADJ
eurjchem-2544	230	2	weaker	weak	ADJ
eurjchem-2544	230	3	and	and	CCONJ
eurjchem-2544	230	4	longer	long	ADJ
eurjchem-2544	230	5	co	co	ADJ
eurjchem-2544	230	6	-	-	ADJ
eurjchem-2544	230	7	p	p	ADJ
eurjchem-2544	230	8	bonds	bond	NOUN
eurjchem-2544	230	9	include	include	VERB
eurjchem-2544	230	10	a	a	DET
eurjchem-2544	230	11	mean	mean	ADJ
eurjchem-2544	230	12	value	value	NOUN
eurjchem-2544	230	13	of	of	ADP
eurjchem-2544	230	14	2.244(6	2.244(6	NUM
eurjchem-2544	230	15	)	)	PUNCT
eurjchem-2544	230	16	å	å	NOUN
eurjchem-2544	230	17	for	for	ADP
eurjchem-2544	230	18	trans-[co(ncs)2(poet)4]·b(c6h5)4	trans-[co(ncs)2(poet)4]·b(c6h5)4	ADJ
eurjchem-2544	230	19	[	[	X
eurjchem-2544	230	20	41	41	NUM
eurjchem-2544	230	21	]	]	PUNCT
eurjchem-2544	230	22	,	,	PUNCT
eurjchem-2544	230	23	where	where	SCONJ
eurjchem-2544	230	24	poet	poet	NOUN
eurjchem-2544	230	25	=	=	NOUN
eurjchem-2544	230	26	triethylphosphine	triethylphosphine	NOUN
eurjchem-2544	230	27	(	(	PUNCT
eurjchem-2544	230	28	p(oc2h5)3	p(oc2h5)3	NOUN
eurjchem-2544	230	29	)	)	PUNCT
eurjchem-2544	230	30	,	,	PUNCT
eurjchem-2544	230	31	2.222(2)-2.257(2	2.222(2)-2.257(2	SYM
eurjchem-2544	230	32	)	)	PUNCT
eurjchem-2544	230	33	å	å	NOUN
eurjchem-2544	230	34	for	for	ADP
eurjchem-2544	230	35	trans-[cox	trans-[cox	X
eurjchem-2544	230	36	(	(	PUNCT
eurjchem-2544	230	37	dmgh)2(pome	dmgh)2(pome	NOUN
eurjchem-2544	230	38	)	)	PUNCT
eurjchem-2544	230	39	]	]	PUNCT
eurjchem-2544	231	1	(	(	PUNCT
eurjchem-2544	231	2	x	x	X
eurjchem-2544	231	3	=	=	SYM
eurjchem-2544	231	4	cn-	cn-	PROPN
eurjchem-2544	231	5	,	,	PUNCT
eurjchem-2544	231	6	ch2cn-	ch2cn-	NOUN
eurjchem-2544	231	7	,	,	PUNCT
eurjchem-2544	231	8	ch3-	ch3-	PROPN
eurjchem-2544	231	9	,	,	PUNCT
eurjchem-2544	231	10	ch2cf3-	ch2cf3-	NOUN
eurjchem-2544	231	11	)	)	PUNCT
eurjchem-2544	232	1	[	[	X
eurjchem-2544	232	2	42	42	NUM
eurjchem-2544	232	3	]	]	PUNCT
eurjchem-2544	232	4	and	and	CCONJ
eurjchem-2544	232	5	2.270(1	2.270(1	NUM
eurjchem-2544	232	6	)	)	PUNCT
eurjchem-2544	232	7	å	å	NOUN
eurjchem-2544	232	8	for	for	ADP
eurjchem-2544	232	9	trans-[co(i	trans-[co(i	NOUN
eurjchem-2544	232	10	-	-	PUNCT
eurjchem-2544	232	11	c3h7	c3h7	NOUN
eurjchem-2544	232	12	)	)	PUNCT
eurjchem-2544	232	13	(	(	PUNCT
eurjchem-2544	232	14	dmgh)2{p(och2)3cch3	dmgh)2{p(och2)3cch3	ADJ
eurjchem-2544	232	15	}	}	PUNCT
eurjchem-2544	232	16	]	]	PUNCT
eurjchem-2544	233	1	[	[	X
eurjchem-2544	233	2	42	42	NUM
eurjchem-2544	233	3	]	]	PUNCT
eurjchem-2544	233	4	.	.	PUNCT
eurjchem-2544	234	1	the	the	DET
eurjchem-2544	234	2	co	co	NOUN
eurjchem-2544	234	3	-	-	NOUN
eurjchem-2544	234	4	s	s	PART
eurjchem-2544	234	5	bonds	bond	NOUN
eurjchem-2544	234	6	recorded	record	VERB
eurjchem-2544	234	7	a	a	DET
eurjchem-2544	234	8	mean	mean	ADJ
eurjchem-2544	234	9	value	value	NOUN
eurjchem-2544	234	10	of	of	ADP
eurjchem-2544	234	11	2.284(2	2.284(2	NUM
eurjchem-2544	234	12	)	)	PUNCT
eurjchem-2544	234	13	å	å	NOUN
eurjchem-2544	234	14	for	for	ADP
eurjchem-2544	234	15	those	those	DET
eurjchem-2544	234	16	trans	tran	NOUN
eurjchem-2544	234	17	to	to	PART
eurjchem-2544	234	18	etpb	etpb	PROPN
eurjchem-2544	234	19	and	and	CCONJ
eurjchem-2544	234	20	2.267(1	2.267(1	NUM
eurjchem-2544	234	21	)	)	PUNCT
eurjchem-2544	234	22	å	å	NOUN
eurjchem-2544	234	23	for	for	SCONJ
eurjchem-2544	234	24	those	those	DET
eurjchem-2544	234	25	trans	tran	NOUN
eurjchem-2544	234	26	to	to	PART
eurjchem-2544	234	27	dtc	dtc	VERB
eurjchem-2544	234	28	.	.	PUNCT
eurjchem-2544	235	1	the	the	DET
eurjchem-2544	235	2	co	co	ADJ
eurjchem-2544	235	3	-	-	ADJ
eurjchem-2544	235	4	smean	smean	ADJ
eurjchem-2544	235	5	=	=	SYM
eurjchem-2544	235	6	2.267(1	2.267(1	NUM
eurjchem-2544	235	7	)	)	PUNCT
eurjchem-2544	235	8	å	å	NOUN
eurjchem-2544	235	9	resembles	resemble	VERB
eurjchem-2544	235	10	those	those	PRON
eurjchem-2544	235	11	found	find	VERB
eurjchem-2544	235	12	in	in	ADP
eurjchem-2544	235	13	co(dtc)3	co(dtc)3	NOUN
eurjchem-2544	235	14	=	=	SYM
eurjchem-2544	235	15	2.264(2	2.264(2	NUM
eurjchem-2544	235	16	)	)	PUNCT
eurjchem-2544	235	17	å	å	PROPN
eurjchem-2544	236	1	[	[	X
eurjchem-2544	236	2	43	43	NUM
eurjchem-2544	236	3	]	]	PUNCT
eurjchem-2544	236	4	and	and	CCONJ
eurjchem-2544	236	5	[	[	X
eurjchem-2544	236	6	co(dtc)(en)2]2	co(dtc)(en)2]2	PUNCT
eurjchem-2544	236	7	+	+	ADJ
eurjchem-2544	236	8	=	=	SYM
eurjchem-2544	236	9	2.263(3	2.263(3	NUM
eurjchem-2544	236	10	)	)	PUNCT
eurjchem-2544	236	11	å	å	NOUN
eurjchem-2544	236	12	[	[	X
eurjchem-2544	236	13	4	4	NUM
eurjchem-2544	236	14	]	]	PUNCT
eurjchem-2544	236	15	(	(	PUNCT
eurjchem-2544	236	16	en	en	X
eurjchem-2544	236	17	=	=	NOUN
eurjchem-2544	236	18	ethylenediammine	ethylenediammine	NOUN
eurjchem-2544	236	19	)	)	PUNCT
eurjchem-2544	236	20	.	.	PUNCT
eurjchem-2544	237	1	the	the	DET
eurjchem-2544	237	2	elongation	elongation	NOUN
eurjchem-2544	237	3	encountered	encounter	VERB
eurjchem-2544	237	4	by	by	ADP
eurjchem-2544	237	5	the	the	DET
eurjchem-2544	237	6	co	co	NOUN
eurjchem-2544	237	7	-	-	NOUN
eurjchem-2544	237	8	s	s	PART
eurjchem-2544	237	9	bonds	bond	NOUN
eurjchem-2544	237	10	trans	tran	NOUN
eurjchem-2544	237	11	to	to	ADP
eurjchem-2544	237	12	etpb	etpb	PROPN
eurjchem-2544	237	13	is	be	AUX
eurjchem-2544	237	14	connected	connect	VERB
eurjchem-2544	237	15	to	to	ADP
eurjchem-2544	237	16	the	the	DET
eurjchem-2544	237	17	small	small	ADJ
eurjchem-2544	237	18	trans	tran	NOUN
eurjchem-2544	237	19	influence	influence	NOUN
eurjchem-2544	237	20	of	of	ADP
eurjchem-2544	237	21	etpb	etpb	PROPN
eurjchem-2544	237	22	(	(	PUNCT
eurjchem-2544	237	23	0.017(2	0.017(2	PROPN
eurjchem-2544	237	24	)	)	PUNCT
eurjchem-2544	238	1	å	å	NOUN
eurjchem-2544	238	2	)	)	PUNCT
eurjchem-2544	238	3	unlike	unlike	ADP
eurjchem-2544	238	4	the	the	DET
eurjchem-2544	238	5	co	co	NOUN
eurjchem-2544	238	6	-	-	NOUN
eurjchem-2544	238	7	n	n	NOUN
eurjchem-2544	238	8	and	and	CCONJ
eurjchem-2544	238	9	co	co	ADJ
eurjchem-2544	238	10	-	-	NOUN
eurjchem-2544	238	11	o	o	ADJ
eurjchem-2544	238	12	bonds	bond	NOUN
eurjchem-2544	238	13	of	of	ADP
eurjchem-2544	238	14	the	the	DET
eurjchem-2544	238	15	mixedligand	mixedligand	NOUN
eurjchem-2544	238	16	co(iii)-phosphine	co(iii)-phosphine	NOUN
eurjchem-2544	238	17	complexes	complex	NOUN
eurjchem-2544	238	18	which	which	PRON
eurjchem-2544	238	19	gave	give	VERB
eurjchem-2544	238	20	a	a	DET
eurjchem-2544	238	21	higher	high	ADJ
eurjchem-2544	238	22	trans	trans	PROPN
eurjchem-2544	238	23	influence	influence	NOUN
eurjchem-2544	238	24	of	of	ADP
eurjchem-2544	238	25	0.04	0.04	NUM
eurjchem-2544	238	26	-	-	PUNCT
eurjchem-2544	238	27	0.06	0.06	NUM
eurjchem-2544	238	28	å	å	PROPN
eurjchem-2544	239	1	[	[	X
eurjchem-2544	239	2	44	44	NUM
eurjchem-2544	239	3	]	]	PUNCT
eurjchem-2544	239	4	.	.	PUNCT
eurjchem-2544	240	1	[	[	X
eurjchem-2544	240	2	co(pipdtc)(pome)4](bf4)2	co(pipdtc)(pome)4](bf4)2	X
eurjchem-2544	240	3	(	(	PUNCT
eurjchem-2544	240	4	10	10	NUM
eurjchem-2544	240	5	,	,	PUNCT
eurjchem-2544	240	6	figure	figure	NOUN
eurjchem-2544	240	7	8)	8)	NUM
eurjchem-2544	240	8	,	,	PUNCT
eurjchem-2544	240	9	where	where	SCONJ
eurjchem-2544	240	10	pipdtc	pipdtc	ADJ
eurjchem-2544	240	11	=	=	SYM
eurjchem-2544	240	12	piperidyldithiocarbamate	piperidyldithiocarbamate	NOUN
eurjchem-2544	240	13	cation	cation	NOUN
eurjchem-2544	240	14	with	with	ADP
eurjchem-2544	240	15	a	a	DET
eurjchem-2544	240	16	seemingly	seemingly	ADV
eurjchem-2544	240	17	disordered	disorder	VERB
eurjchem-2544	240	18	tetrafluoroborate	tetrafluoroborate	ADJ
eurjchem-2544	240	19	anion	anion	NOUN
eurjchem-2544	240	20	,	,	PUNCT
eurjchem-2544	240	21	crystallizes	crystallize	VERB
eurjchem-2544	240	22	in	in	ADP
eurjchem-2544	240	23	the	the	DET
eurjchem-2544	240	24	monoclinic	monoclinic	ADJ
eurjchem-2544	240	25	p21	p21	NOUN
eurjchem-2544	240	26	/	/	SYM
eurjchem-2544	240	27	c	c	NOUN
eurjchem-2544	240	28	space	space	NOUN
eurjchem-2544	240	29	group	group	NOUN
eurjchem-2544	241	1	[	[	X
eurjchem-2544	241	2	4	4	NUM
eurjchem-2544	241	3	]	]	PUNCT
eurjchem-2544	241	4	.	.	PUNCT
eurjchem-2544	242	1	trans	tran	NOUN
eurjchem-2544	242	2	-	-	NOUN
eurjchem-2544	242	3	effect	effect	VERB
eurjchem-2544	242	4	/	/	SYM
eurjchem-2544	242	5	influence	influence	NOUN
eurjchem-2544	242	6	of	of	ADP
eurjchem-2544	242	7	p	p	NOUN
eurjchem-2544	242	8	and	and	CCONJ
eurjchem-2544	242	9	s	s	X
eurjchem-2544	242	10	on	on	ADP
eurjchem-2544	242	11	the	the	DET
eurjchem-2544	242	12	co	co	NOUN
eurjchem-2544	242	13	-	-	ADJ
eurjchem-2544	242	14	p	p	ADJ
eurjchem-2544	242	15	bonds	bond	NOUN
eurjchem-2544	242	16	was	be	AUX
eurjchem-2544	242	17	depicted	depict	VERB
eurjchem-2544	242	18	as	as	ADP
eurjchem-2544	242	19	elongated	elongate	VERB
eurjchem-2544	242	20	2.242(2	2.242(2	NUM
eurjchem-2544	242	21	)	)	PUNCT
eurjchem-2544	242	22	å	å	PROPN
eurjchem-2544	242	23	and	and	CCONJ
eurjchem-2544	242	24	2.208(3	2.208(3	NUM
eurjchem-2544	242	25	)	)	PUNCT
eurjchem-2544	242	26	å	å	NOUN
eurjchem-2544	242	27	,	,	PUNCT
eurjchem-2544	242	28	respectively	respectively	ADV
eurjchem-2544	242	29	.	.	PUNCT
eurjchem-2544	243	1	the	the	DET
eurjchem-2544	243	2	extended	extended	ADJ
eurjchem-2544	243	3	elongation	elongation	NOUN
eurjchem-2544	243	4	of	of	ADP
eurjchem-2544	243	5	the	the	DET
eurjchem-2544	243	6	co	co	NOUN
eurjchem-2544	243	7	-	-	NOUN
eurjchem-2544	243	8	p	p	ADJ
eurjchem-2544	243	9	bonds	bond	NOUN
eurjchem-2544	243	10	trans	tran	NOUN
eurjchem-2544	243	11	to	to	ADP
eurjchem-2544	243	12	p	p	NOUN
eurjchem-2544	243	13	compared	compare	VERB
eurjchem-2544	243	14	to	to	ADP
eurjchem-2544	243	15	s	s	PRON
eurjchem-2544	243	16	is	be	AUX
eurjchem-2544	243	17	connected	connect	VERB
eurjchem-2544	243	18	to	to	ADP
eurjchem-2544	243	19	the	the	DET
eurjchem-2544	243	20	extra	extra	ADJ
eurjchem-2544	243	21	mutual	mutual	ADJ
eurjchem-2544	243	22	trans	tran	NOUN
eurjchem-2544	243	23	influence	influence	NOUN
eurjchem-2544	243	24	from	from	ADP
eurjchem-2544	243	25	some	some	PRON
eurjchem-2544	243	26	of	of	ADP
eurjchem-2544	243	27	the	the	DET
eurjchem-2544	243	28	pome	pome	NOUN
eurjchem-2544	243	29	ligands	ligand	NOUN
eurjchem-2544	243	30	.	.	PUNCT
eurjchem-2544	244	1	the	the	DET
eurjchem-2544	244	2	mean	mean	ADJ
eurjchem-2544	244	3	distance	distance	NOUN
eurjchem-2544	244	4	for	for	ADP
eurjchem-2544	244	5	co	co	NOUN
eurjchem-2544	244	6	-	-	NOUN
eurjchem-2544	244	7	s	s	PART
eurjchem-2544	244	8	bonds	bond	NOUN
eurjchem-2544	244	9	is	be	AUX
eurjchem-2544	244	10	2.288(3	2.288(3	NUM
eurjchem-2544	244	11	)	)	PUNCT
eurjchem-2544	245	1	å	å	NOUN
eurjchem-2544	245	2	.	.	PUNCT
eurjchem-2544	246	1	interestingly	interestingly	ADV
eurjchem-2544	246	2	,	,	PUNCT
eurjchem-2544	246	3	the	the	DET
eurjchem-2544	246	4	study	study	NOUN
eurjchem-2544	246	5	of	of	ADP
eurjchem-2544	246	6	complex	complex	ADJ
eurjchem-2544	246	7	10	10	NUM
eurjchem-2544	246	8	made	make	VERB
eurjchem-2544	246	9	matsui	matsui	PROPN
eurjchem-2544	246	10	et	et	PROPN
eurjchem-2544	246	11	al	al	PROPN
eurjchem-2544	246	12	.	.	PROPN
eurjchem-2544	246	13	investigate	investigate	VERB
eurjchem-2544	246	14	further	far	ADV
eurjchem-2544	246	15	and	and	CCONJ
eurjchem-2544	246	16	come	come	VERB
eurjchem-2544	246	17	up	up	ADP
eurjchem-2544	246	18	with	with	ADP
eurjchem-2544	246	19	the	the	DET
eurjchem-2544	246	20	conclusion	conclusion	NOUN
eurjchem-2544	246	21	that	that	SCONJ
eurjchem-2544	246	22	the	the	DET
eurjchem-2544	246	23	trans	tran	NOUN
eurjchem-2544	246	24	-	-	NOUN
eurjchem-2544	246	25	influences	influence	NOUN
eurjchem-2544	246	26	of	of	ADP
eurjchem-2544	246	27	phosphites	phosphite	NOUN
eurjchem-2544	246	28	,	,	PUNCT
eurjchem-2544	246	29	phosphornites	phosphornite	NOUN
eurjchem-2544	246	30	,	,	PUNCT
eurjchem-2544	246	31	and	and	CCONJ
eurjchem-2544	246	32	phosphines	phosphine	VERB
eurjchem-2544	246	33	on	on	ADP
eurjchem-2544	246	34	co(iii	co(iii	NOUN
eurjchem-2544	246	35	)	)	PUNCT
eurjchem-2544	246	36	ions	ion	NOUN
eurjchem-2544	246	37	are	be	AUX
eurjchem-2544	246	38	similar	similar	ADJ
eurjchem-2544	246	39	[	[	X
eurjchem-2544	246	40	4	4	NUM
eurjchem-2544	246	41	]	]	PUNCT
eurjchem-2544	246	42	.	.	PUNCT
eurjchem-2544	247	1	[	[	X
eurjchem-2544	247	2	co(dtc)3]·2cubr·2ch3cn	co(dtc)3]·2cubr·2ch3cn	X
eurjchem-2544	247	3	(	(	PUNCT
eurjchem-2544	247	4	dtc	dtc	NOUN
eurjchem-2544	247	5	=	=	SYM
eurjchem-2544	247	6	n	n	CCONJ
eurjchem-2544	247	7	,	,	PUNCT
eurjchem-2544	247	8	n	n	CCONJ
eurjchem-2544	247	9	-	-	PUNCT
eurjchem-2544	247	10	dimethyl(dithio	dimethyl(dithio	PROPN
eurjchem-2544	247	11	carbamato	carbamato	NOUN
eurjchem-2544	247	12	)	)	PUNCT
eurjchem-2544	247	13	(	(	PUNCT
eurjchem-2544	247	14	11	11	NUM
eurjchem-2544	247	15	,	,	PUNCT
eurjchem-2544	247	16	figure	figure	NOUN
eurjchem-2544	247	17	9	9	NUM
eurjchem-2544	247	18	)	)	PUNCT
eurjchem-2544	247	19	is	be	AUX
eurjchem-2544	247	20	a	a	DET
eurjchem-2544	247	21	typical	typical	ADJ
eurjchem-2544	247	22	example	example	NOUN
eurjchem-2544	247	23	of	of	ADP
eurjchem-2544	247	24	the	the	DET
eurjchem-2544	247	25	1:2	1:2	NUM
eurjchem-2544	247	26	heterobimetallic	heterobimetallic	ADJ
eurjchem-2544	247	27	adduct	adduct	NOUN
eurjchem-2544	247	28	.	.	PUNCT
eurjchem-2544	248	1	it	it	PRON
eurjchem-2544	248	2	crystallizes	crystallize	VERB
eurjchem-2544	248	3	in	in	ADP
eurjchem-2544	248	4	the	the	DET
eurjchem-2544	248	5	monoclinic	monoclinic	ADJ
eurjchem-2544	248	6	c2	c2	PROPN
eurjchem-2544	248	7	/	/	SYM
eurjchem-2544	248	8	c	c	PROPN
eurjchem-2544	248	9	space	space	NOUN
eurjchem-2544	248	10	group	group	NOUN
eurjchem-2544	248	11	[	[	X
eurjchem-2544	248	12	45	45	NUM
eurjchem-2544	248	13	]	]	PUNCT
eurjchem-2544	248	14	.	.	PUNCT
eurjchem-2544	249	1	its	its	PRON
eurjchem-2544	249	2	asymmetric	asymmetric	ADJ
eurjchem-2544	249	3	unit	unit	NOUN
eurjchem-2544	249	4	is	be	AUX
eurjchem-2544	249	5	made	make	VERB
eurjchem-2544	249	6	up	up	ADP
eurjchem-2544	249	7	of	of	ADP
eurjchem-2544	249	8	a	a	DET
eurjchem-2544	249	9	cubr	cubr	NOUN
eurjchem-2544	249	10	unit	unit	NOUN
eurjchem-2544	249	11	,	,	PUNCT
eurjchem-2544	249	12	a	a	DET
eurjchem-2544	249	13	ch3cn	ch3cn	NUM
eurjchem-2544	249	14	molecule	molecule	NOUN
eurjchem-2544	249	15	,	,	PUNCT
eurjchem-2544	249	16	and	and	CCONJ
eurjchem-2544	249	17	one	one	NUM
eurjchem-2544	249	18	-	-	PUNCT
eurjchem-2544	249	19	half	half	NOUN
eurjchem-2544	249	20	of	of	ADP
eurjchem-2544	249	21	the	the	DET
eurjchem-2544	249	22	co(s2(net2)3	co(s2(net2)3	NOUN
eurjchem-2544	249	23	molecule	molecule	NOUN
eurjchem-2544	249	24	that	that	PRON
eurjchem-2544	249	25	sits	sit	VERB
eurjchem-2544	249	26	on	on	ADP
eurjchem-2544	249	27	a	a	DET
eurjchem-2544	249	28	crystallographic	crystallographic	ADJ
eurjchem-2544	249	29	two	two	NUM
eurjchem-2544	249	30	-	-	PUNCT
eurjchem-2544	249	31	fold	fold	ADJ
eurjchem-2544	249	32	axis	axis	NOUN
eurjchem-2544	249	33	.	.	PUNCT
eurjchem-2544	250	1	the	the	DET
eurjchem-2544	250	2	cubr	cubr	NOUN
eurjchem-2544	250	3	unit	unit	NOUN
eurjchem-2544	250	4	is	be	AUX
eurjchem-2544	250	5	located	locate	VERB
eurjchem-2544	250	6	in	in	ADP
eurjchem-2544	250	7	an	an	DET
eurjchem-2544	250	8	inversion	inversion	NOUN
eurjchem-2544	250	9	center	center	NOUN
eurjchem-2544	250	10	for	for	ADP
eurjchem-2544	250	11	the	the	DET
eurjchem-2544	250	12	dimeric	dimeric	ADJ
eurjchem-2544	250	13	planar	planar	ADJ
eurjchem-2544	250	14	cu2br2	cu2br2	NOUN
eurjchem-2544	250	15	that	that	PRON
eurjchem-2544	250	16	associates	associate	VERB
eurjchem-2544	250	17	with	with	ADP
eurjchem-2544	250	18	two	two	NUM
eurjchem-2544	250	19	[	[	X
eurjchem-2544	250	20	co(s2cnet2)3	co(s2cnet2)3	X
eurjchem-2544	250	21	]	]	X
eurjchem-2544	250	22	molecules	molecule	NOUN
eurjchem-2544	250	23	of	of	ADP
eurjchem-2544	250	24	reversed	reversed	ADJ
eurjchem-2544	250	25	chirality	chirality	NOUN
eurjchem-2544	250	26	.	.	PUNCT
eurjchem-2544	251	1	the	the	DET
eurjchem-2544	251	2	co	co	NOUN
eurjchem-2544	251	3	-	-	PROPN
eurjchem-2544	251	4	s	s	PART
eurjchem-2544	251	5	bond	bond	NOUN
eurjchem-2544	251	6	distances	distance	NOUN
eurjchem-2544	251	7	vary	vary	VERB
eurjchem-2544	251	8	depending	depend	VERB
eurjchem-2544	251	9	on	on	ADP
eurjchem-2544	251	10	the	the	DET
eurjchem-2544	251	11	source	source	NOUN
eurjchem-2544	251	12	of	of	ADP
eurjchem-2544	251	13	the	the	DET
eurjchem-2544	251	14	sulfur	sulfur	NOUN
eurjchem-2544	251	15	atoms	atom	NOUN
eurjchem-2544	251	16	.	.	PUNCT
eurjchem-2544	252	1	for	for	ADP
eurjchem-2544	252	2	example	example	NOUN
eurjchem-2544	252	3	,	,	PUNCT
eurjchem-2544	252	4	when	when	SCONJ
eurjchem-2544	252	5	s	s	X
eurjchem-2544	252	6	in	in	ADP
eurjchem-2544	252	7	co	co	NOUN
eurjchem-2544	252	8	-	-	NOUN
eurjchem-2544	252	9	s	s	PART
eurjchem-2544	252	10	is	be	AUX
eurjchem-2544	252	11	chelated	chelate	VERB
eurjchem-2544	252	12	to	to	ADP
eurjchem-2544	252	13	copper	copper	NOUN
eurjchem-2544	252	14	,	,	PUNCT
eurjchem-2544	252	15	the	the	DET
eurjchem-2544	252	16	distance	distance	NOUN
eurjchem-2544	252	17	between	between	ADP
eurjchem-2544	252	18	co	co	NOUN
eurjchem-2544	252	19	and	and	CCONJ
eurjchem-2544	252	20	s	s	VERB
eurjchem-2544	252	21	is	be	AUX
eurjchem-2544	252	22	in	in	ADP
eurjchem-2544	252	23	the	the	DET
eurjchem-2544	252	24	range	range	NOUN
eurjchem-2544	252	25	2.281(5)2.292(4	2.281(5)2.292(4	NUM
eurjchem-2544	252	26	)	)	PUNCT
eurjchem-2544	252	27	å	å	NOUN
eurjchem-2544	252	28	,	,	PUNCT
eurjchem-2544	252	29	while	while	SCONJ
eurjchem-2544	252	30	for	for	ADP
eurjchem-2544	252	31	unchelated	unchelated	ADJ
eurjchem-2544	252	32	sulfur	sulfur	NOUN
eurjchem-2544	252	33	,	,	PUNCT
eurjchem-2544	252	34	the	the	DET
eurjchem-2544	252	35	distance	distance	NOUN
eurjchem-2544	252	36	between	between	ADP
eurjchem-2544	252	37	the	the	DET
eurjchem-2544	252	38	co	co	NOUN
eurjchem-2544	252	39	and	and	CCONJ
eurjchem-2544	252	40	s	s	PROPN
eurjchem-2544	252	41	bonds	bond	NOUN
eurjchem-2544	252	42	is	be	AUX
eurjchem-2544	252	43	2.245(5	2.245(5	NUM
eurjchem-2544	252	44	)	)	PUNCT
eurjchem-2544	252	45	å	å	NOUN
eurjchem-2544	252	46	.	.	PUNCT
eurjchem-2544	253	1	on	on	ADP
eurjchem-2544	253	2	the	the	DET
eurjchem-2544	253	3	other	other	ADJ
eurjchem-2544	253	4	hand	hand	NOUN
eurjchem-2544	253	5	,	,	PUNCT
eurjchem-2544	253	6	the	the	DET
eurjchem-2544	253	7	range	range	NOUN
eurjchem-2544	253	8	2.265(1)-2.268(1	2.265(1)-2.268(1	NOUN
eurjchem-2544	253	9	)	)	PUNCT
eurjchem-2544	253	10	å	å	PROPN
eurjchem-2544	253	11	was	be	AUX
eurjchem-2544	253	12	obtained	obtain	VERB
eurjchem-2544	253	13	for	for	ADP
eurjchem-2544	253	14	co	co	NOUN
eurjchem-2544	253	15	-	-	NOUN
eurjchem-2544	253	16	s	s	PART
eurjchem-2544	253	17	bonds	bond	NOUN
eurjchem-2544	253	18	in	in	ADP
eurjchem-2544	253	19	the	the	DET
eurjchem-2544	253	20	parent	parent	NOUN
eurjchem-2544	253	21	complex	complex	NOUN
eurjchem-2544	253	22	[	[	X
eurjchem-2544	253	23	45	45	NUM
eurjchem-2544	253	24	]	]	PUNCT
eurjchem-2544	253	25	.	.	PUNCT
eurjchem-2544	254	1	the	the	DET
eurjchem-2544	254	2	acetonitrile	acetonitrile	ADJ
eurjchem-2544	254	3	solvate	solvate	NOUN
eurjchem-2544	254	4	occupies	occupie	NOUN
eurjchem-2544	254	5	voids	void	NOUN
eurjchem-2544	254	6	left	leave	VERB
eurjchem-2544	254	7	unfilled	unfilled	ADJ
eurjchem-2544	254	8	when	when	SCONJ
eurjchem-2544	254	9	the	the	DET
eurjchem-2544	254	10	sulfur	sulfur	NOUN
eurjchem-2544	254	11	atoms	atom	NOUN
eurjchem-2544	254	12	are	be	AUX
eurjchem-2544	254	13	uncoordinated	uncoordinated	ADJ
eurjchem-2544	254	14	with	with	ADP
eurjchem-2544	254	15	cubr	cubr	NOUN
eurjchem-2544	254	16	.	.	PUNCT
eurjchem-2544	255	1	the	the	DET
eurjchem-2544	255	2	crystal	crystal	PROPN
eurjchem-2544	255	3	lattice	lattice	NOUN
eurjchem-2544	255	4	of	of	ADP
eurjchem-2544	255	5	complex	complex	ADJ
eurjchem-2544	255	6	11	11	NUM
eurjchem-2544	255	7	is	be	AUX
eurjchem-2544	255	8	host	host	NOUN
eurjchem-2544	255	9	to	to	ADP
eurjchem-2544	255	10	a	a	DET
eurjchem-2544	255	11	number	number	NOUN
eurjchem-2544	255	12	of	of	ADP
eurjchem-2544	255	13	short	short	ADJ
eurjchem-2544	255	14	intermolecular	intermolecular	ADJ
eurjchem-2544	255	15	interactions	interaction	NOUN
eurjchem-2544	255	16	such	such	ADJ
eurjchem-2544	255	17	as	as	ADP
eurjchem-2544	255	18	c···n	c···n	PROPN
eurjchem-2544	255	19	,	,	PUNCT
eurjchem-2544	255	20	h···n	h···n	PROPN
eurjchem-2544	255	21	,	,	PUNCT
eurjchem-2544	255	22	c···h	c···h	PROPN
eurjchem-2544	255	23	,	,	PUNCT
eurjchem-2544	255	24	h···o	h···o	PROPN
eurjchem-2544	255	25	,	,	PUNCT
eurjchem-2544	255	26	h···h	h···h	PROPN
eurjchem-2544	255	27	,	,	PUNCT
eurjchem-2544	255	28	c···c	c···c	PROPN
eurjchem-2544	255	29	,	,	PUNCT
eurjchem-2544	255	30	c···f	c···f	PROPN
eurjchem-2544	255	31	,	,	PUNCT
eurjchem-2544	255	32	h···f	h···f	PROPN
eurjchem-2544	255	33	,	,	PUNCT
eurjchem-2544	255	34	o···o	o···o	PROPN
eurjchem-2544	255	35	,	,	PUNCT
eurjchem-2544	255	36	n···o	n···o	PROPN
eurjchem-2544	255	37	and	and	CCONJ
eurjchem-2544	255	38	c···o	c···o	PROPN
eurjchem-2544	255	39	contacts	contact	NOUN
eurjchem-2544	255	40	.	.	PUNCT
eurjchem-2544	256	1	[	[	X
eurjchem-2544	256	2	co(dtc)3]·3cui	co(dtc)3]·3cui	X
eurjchem-2544	256	3	(	(	PUNCT
eurjchem-2544	256	4	dtc	dtc	NOUN
eurjchem-2544	256	5	=	=	PUNCT
eurjchem-2544	256	6	tetramethylene	tetramethylene	NOUN
eurjchem-2544	256	7	dithiocarbamato	dithiocarbamato	PROPN
eurjchem-2544	256	8	)	)	PUNCT
eurjchem-2544	256	9	(	(	PUNCT
eurjchem-2544	256	10	12	12	NUM
eurjchem-2544	256	11	,	,	PUNCT
eurjchem-2544	256	12	figure	figure	NOUN
eurjchem-2544	256	13	9	9	NUM
eurjchem-2544	256	14	)	)	PUNCT
eurjchem-2544	256	15	is	be	AUX
eurjchem-2544	256	16	a	a	DET
eurjchem-2544	256	17	typical	typical	ADJ
eurjchem-2544	256	18	example	example	NOUN
eurjchem-2544	256	19	of	of	ADP
eurjchem-2544	256	20	the	the	DET
eurjchem-2544	256	21	1:3	1:3	NUM
eurjchem-2544	256	22	heterobimetallic	heterobimetallic	ADJ
eurjchem-2544	256	23	adduct	adduct	NOUN
eurjchem-2544	256	24	.	.	PUNCT
eurjchem-2544	257	1	it	it	PRON
eurjchem-2544	257	2	crystallizes	crystallize	VERB
eurjchem-2544	257	3	in	in	ADP
eurjchem-2544	257	4	the	the	DET
eurjchem-2544	257	5	i-43d	i-43d	NOUN
eurjchem-2544	257	6	space	space	NOUN
eurjchem-2544	257	7	group	group	NOUN
eurjchem-2544	257	8	of	of	ADP
eurjchem-2544	257	9	the	the	DET
eurjchem-2544	257	10	cubic	cubic	ADJ
eurjchem-2544	257	11	crystal	crystal	NOUN
eurjchem-2544	257	12	system	system	NOUN
eurjchem-2544	257	13	.	.	PUNCT
eurjchem-2544	258	1	its	its	PRON
eurjchem-2544	258	2	asymmetric	asymmetric	ADJ
eurjchem-2544	258	3	unit	unit	NOUN
eurjchem-2544	258	4	consists	consist	VERB
eurjchem-2544	258	5	of	of	ADP
eurjchem-2544	258	6	one	one	NUM
eurjchem-2544	258	7	-	-	PUNCT
eurjchem-2544	258	8	third	third	NOUN
eurjchem-2544	258	9	of	of	ADP
eurjchem-2544	258	10	co[(s2cn(ch2)4]3	co[(s2cn(ch2)4]3	NOUN
eurjchem-2544	258	11	whose	whose	DET
eurjchem-2544	258	12	co	co	NOUN
eurjchem-2544	258	13	atom	atom	NOUN
eurjchem-2544	258	14	sits	sit	VERB
eurjchem-2544	258	15	on	on	ADP
eurjchem-2544	258	16	a	a	DET
eurjchem-2544	258	17	crystallographic	crystallographic	ADJ
eurjchem-2544	258	18	three	three	NUM
eurjchem-2544	258	19	-	-	ADJ
eurjchem-2544	258	20	fold	fold	ADJ
eurjchem-2544	258	21	axis	axis	NOUN
eurjchem-2544	258	22	.	.	PUNCT
eurjchem-2544	259	1	one	one	NUM
eurjchem-2544	259	2	-	-	PUNCT
eurjchem-2544	259	3	half	half	NOUN
eurjchem-2544	259	4	of	of	ADP
eurjchem-2544	259	5	the	the	DET
eurjchem-2544	259	6	cu2i2	cu2i2	PROPN
eurjchem-2544	259	7	dimer	dimer	NOUN
eurjchem-2544	259	8	sits	sit	VERB
eurjchem-2544	259	9	on	on	ADP
eurjchem-2544	259	10	a	a	DET
eurjchem-2544	259	11	crystallographic	crystallographic	ADJ
eurjchem-2544	259	12	2	2	NUM
eurjchem-2544	259	13	-	-	ADJ
eurjchem-2544	259	14	fold	fold	ADJ
eurjchem-2544	259	15	axis	axis	NOUN
eurjchem-2544	259	16	,	,	PUNCT
eurjchem-2544	259	17	thus	thus	ADV
eurjchem-2544	259	18	forming	form	VERB
eurjchem-2544	259	19	a	a	DET
eurjchem-2544	259	20	polymeric	polymeric	ADJ
eurjchem-2544	259	21	bridge	bridge	NOUN
eurjchem-2544	259	22	with	with	ADP
eurjchem-2544	259	23	the	the	DET
eurjchem-2544	259	24	complex	complex	NOUN
eurjchem-2544	259	25	.	.	PUNCT
eurjchem-2544	260	1	two	two	NUM
eurjchem-2544	260	2	independent	independent	ADJ
eurjchem-2544	260	3	co	co	NOUN
eurjchem-2544	260	4	-	-	NOUN
eurjchem-2544	260	5	s	s	ADJ
eurjchem-2544	260	6	distances	distance	NOUN
eurjchem-2544	260	7	of	of	ADP
eurjchem-2544	260	8	2.259(1	2.259(1	NUM
eurjchem-2544	260	9	)	)	PUNCT
eurjchem-2544	260	10	and	and	CCONJ
eurjchem-2544	260	11	2.304(5	2.304(5	NUM
eurjchem-2544	260	12	)	)	PUNCT
eurjchem-2544	260	13	å	å	PROPN
eurjchem-2544	260	14	were	be	AUX
eurjchem-2544	260	15	obtained	obtain	VERB
eurjchem-2544	260	16	despite	despite	SCONJ
eurjchem-2544	260	17	having	have	VERB
eurjchem-2544	260	18	all	all	DET
eurjchem-2544	260	19	sulfur	sulfur	NOUN
eurjchem-2544	260	20	atoms	atom	NOUN
eurjchem-2544	260	21	coordinated	coordinate	VERB
eurjchem-2544	260	22	to	to	ADP
eurjchem-2544	260	23	the	the	DET
eurjchem-2544	260	24	copper	copper	NOUN
eurjchem-2544	260	25	atom	atom	NOUN
eurjchem-2544	261	1	[	[	X
eurjchem-2544	261	2	45	45	NUM
eurjchem-2544	261	3	]	]	PUNCT
eurjchem-2544	261	4	.	.	PUNCT
eurjchem-2544	262	1	table	table	NOUN
eurjchem-2544	262	2	3	3	NUM
eurjchem-2544	262	3	shows	show	VERB
eurjchem-2544	262	4	the	the	DET
eurjchem-2544	262	5	selected	select	VERB
eurjchem-2544	262	6	bond	bond	NOUN
eurjchem-2544	262	7	distances	distance	NOUN
eurjchem-2544	262	8	,	,	PUNCT
eurjchem-2544	262	9	angles	angle	NOUN
eurjchem-2544	262	10	,	,	PUNCT
eurjchem-2544	262	11	and	and	CCONJ
eurjchem-2544	262	12	solvents	solvent	NOUN
eurjchem-2544	262	13	for	for	ADP
eurjchem-2544	262	14	crystal	crystal	NOUN
eurjchem-2544	262	15	growth	growth	NOUN
eurjchem-2544	262	16	of	of	ADP
eurjchem-2544	262	17	complexes	complex	NOUN
eurjchem-2544	262	18	1	1	NUM
eurjchem-2544	262	19	-	-	SYM
eurjchem-2544	262	20	12	12	NUM
eurjchem-2544	262	21	.	.	PUNCT
eurjchem-2544	263	1	it	it	PRON
eurjchem-2544	263	2	shows	show	VERB
eurjchem-2544	263	3	the	the	DET
eurjchem-2544	263	4	changes	change	NOUN
eurjchem-2544	263	5	in	in	ADP
eurjchem-2544	263	6	bond	bond	NOUN
eurjchem-2544	263	7	angle	angle	NOUN
eurjchem-2544	263	8	and	and	CCONJ
eurjchem-2544	263	9	distances	distance	NOUN
eurjchem-2544	263	10	as	as	SCONJ
eurjchem-2544	263	11	the	the	DET
eurjchem-2544	263	12	r	r	NOUN
eurjchem-2544	263	13	substituents	substituent	NOUN
eurjchem-2544	263	14	in	in	ADP
eurjchem-2544	263	15	the	the	DET
eurjchem-2544	263	16	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	263	17	backbone	backbone	NOUN
eurjchem-2544	263	18	changes	change	NOUN
eurjchem-2544	263	19	or	or	CCONJ
eurjchem-2544	263	20	the	the	DET
eurjchem-2544	263	21	ligand	ligand	ADJ
eurjchem-2544	263	22	framework	framework	NOUN
eurjchem-2544	263	23	is	be	AUX
eurjchem-2544	263	24	replaced	replace	VERB
eurjchem-2544	263	25	with	with	ADP
eurjchem-2544	263	26	a	a	DET
eurjchem-2544	263	27	secondary	secondary	ADJ
eurjchem-2544	263	28	ligand	ligand	NOUN
eurjchem-2544	263	29	such	such	ADJ
eurjchem-2544	263	30	as	as	ADP
eurjchem-2544	263	31	the	the	DET
eurjchem-2544	263	32	p	p	NOUN
eurjchem-2544	263	33	-	-	PUNCT
eurjchem-2544	263	34	ligand	ligand	NOUN
eurjchem-2544	263	35	.	.	PUNCT
eurjchem-2544	264	1	its	its	PRON
eurjchem-2544	264	2	crystal	crystal	NOUN
eurjchem-2544	264	3	lattice	lattice	NOUN
eurjchem-2544	264	4	consists	consist	VERB
eurjchem-2544	264	5	of	of	ADP
eurjchem-2544	264	6	short	short	ADJ
eurjchem-2544	264	7	intermolecular	intermolecular	ADJ
eurjchem-2544	264	8	interactions	interaction	NOUN
eurjchem-2544	264	9	such	such	ADJ
eurjchem-2544	264	10	as	as	ADP
eurjchem-2544	264	11	h···s	h···	NOUN
eurjchem-2544	264	12	,	,	PUNCT
eurjchem-2544	264	13	cu···co	cu···co	VERB
eurjchem-2544	264	14	,	,	PUNCT
eurjchem-2544	264	15	cu···s	cu···s	PROPN
eurjchem-2544	264	16	,	,	PUNCT
eurjchem-2544	264	17	cu···c	cu···c	PROPN
eurjchem-2544	264	18	,	,	PUNCT
eurjchem-2544	264	19	cu···cu	cu···cu	PROPN
eurjchem-2544	264	20	and	and	CCONJ
eurjchem-2544	264	21	cu···i	cu···i	PROPN
eurjchem-2544	264	22	contacts	contact	NOUN
eurjchem-2544	264	23	.	.	PUNCT
eurjchem-2544	265	1	298	298	NUM
eurjchem-2544	265	2	shotonwa	shotonwa	ADJ
eurjchem-2544	265	3	et	et	PROPN
eurjchem-2544	265	4	al	al	PROPN
eurjchem-2544	265	5	.	.	PUNCT
eurjchem-2544	265	6	/	/	SYM
eurjchem-2544	265	7	european	european	PROPN
eurjchem-2544	265	8	journal	journal	PROPN
eurjchem-2544	265	9	of	of	ADP
eurjchem-2544	265	10	chemistry	chemistry	NOUN
eurjchem-2544	265	11	15	15	NUM
eurjchem-2544	265	12	(	(	PUNCT
eurjchem-2544	265	13	3	3	NUM
eurjchem-2544	265	14	)	)	PUNCT
eurjchem-2544	265	15	(	(	PUNCT
eurjchem-2544	265	16	2024	2024	NUM
eurjchem-2544	265	17	)	)	PUNCT
eurjchem-2544	265	18	291	291	NUM
eurjchem-2544	265	19	-	-	SYM
eurjchem-2544	265	20	301	301	NUM
eurjchem-2544	265	21	2024	2024	NUM
eurjchem-2544	265	22	–	–	PUNCT
eurjchem-2544	265	23	european	european	ADJ
eurjchem-2544	265	24	journal	journal	NOUN
eurjchem-2544	265	25	of	of	ADP
eurjchem-2544	265	26	chemistry	chemistry	NOUN
eurjchem-2544	265	27	–	–	PUNCT
eurjchem-2544	265	28	cc	cc	NOUN
eurjchem-2544	265	29	by	by	ADP
eurjchem-2544	265	30	nc	nc	PROPN
eurjchem-2544	265	31	–	–	PUNCT
eurjchem-2544	265	32	doi	doi	PROPN
eurjchem-2544	265	33	:	:	PUNCT
eurjchem-2544	265	34	10.5155	10.5155	NUM
eurjchem-2544	265	35	/	/	SYM
eurjchem-2544	265	36	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	265	37	-	-	PUNCT
eurjchem-2544	265	38	301.2544	301.2544	NUM
eurjchem-2544	265	39	table	table	NOUN
eurjchem-2544	265	40	3	3	NUM
eurjchem-2544	265	41	.	.	PUNCT
eurjchem-2544	265	42	selected	select	VERB
eurjchem-2544	265	43	bond	bond	NOUN
eurjchem-2544	265	44	distances	distance	NOUN
eurjchem-2544	265	45	,	,	PUNCT
eurjchem-2544	265	46	angles	angle	NOUN
eurjchem-2544	265	47	,	,	PUNCT
eurjchem-2544	265	48	and	and	CCONJ
eurjchem-2544	265	49	crystal	crystal	NOUN
eurjchem-2544	265	50	growth	growth	NOUN
eurjchem-2544	265	51	solvents	solvent	NOUN
eurjchem-2544	265	52	for	for	ADP
eurjchem-2544	265	53	complexes	complex	NOUN
eurjchem-2544	265	54	1	1	NUM
eurjchem-2544	265	55	-	-	SYM
eurjchem-2544	265	56	18	18	NUM
eurjchem-2544	265	57	.	.	PUNCT
eurjchem-2544	265	58	complexes	complex	NOUN
eurjchem-2544	265	59	co	co	NOUN
eurjchem-2544	265	60	-	-	PROPN
eurjchem-2544	265	61	s	s	X
eurjchem-2544	265	62	(	(	PUNCT
eurjchem-2544	265	63	å	å	NOUN
eurjchem-2544	265	64	)	)	PUNCT
eurjchem-2544	265	65	co	co	NOUN
eurjchem-2544	265	66	-	-	NOUN
eurjchem-2544	265	67	p	p	X
eurjchem-2544	265	68	(	(	PUNCT
eurjchem-2544	265	69	å	å	PROPN
eurjchem-2544	265	70	)	)	PUNCT
eurjchem-2544	265	71	a	a	DET
eurjchem-2544	265	72	s	s	NOUN
eurjchem-2544	265	73	-	-	PUNCT
eurjchem-2544	265	74	co	co	NOUN
eurjchem-2544	265	75	-	-	NOUN
eurjchem-2544	265	76	s	s	X
eurjchem-2544	265	77	(	(	PUNCT
eurjchem-2544	265	78	°	°	ADP
eurjchem-2544	265	79	)	)	PUNCT
eurjchem-2544	265	80	p	p	NOUN
eurjchem-2544	265	81	-	-	PUNCT
eurjchem-2544	265	82	co	co	NOUN
eurjchem-2544	265	83	-	-	NOUN
eurjchem-2544	265	84	p	p	X
eurjchem-2544	265	85	(	(	PUNCT
eurjchem-2544	265	86	°	°	PROPN
eurjchem-2544	265	87	)	)	PUNCT
eurjchem-2544	265	88	b	b	X
eurjchem-2544	265	89	solvent(s	solvent(s	PROPN
eurjchem-2544	265	90	)	)	PUNCT
eurjchem-2544	265	91	for	for	ADP
eurjchem-2544	265	92	crystal	crystal	NOUN
eurjchem-2544	265	93	growth	growth	NOUN
eurjchem-2544	265	94	ref	ref	NOUN
eurjchem-2544	265	95	.	.	PUNCT
eurjchem-2544	266	1	1	1	NUM
eurjchem-2544	266	2	2.263(3)-2.270(3	2.263(3)-2.270(3	NOUN
eurjchem-2544	266	3	)	)	PUNCT
eurjchem-2544	266	4	76.1(1)-76.5(1	76.1(1)-76.5(1	NUM
eurjchem-2544	266	5	)	)	PUNCT
eurjchem-2544	266	6	benzene	benzene	NOUN
eurjchem-2544	266	7	-	-	PUNCT
eurjchem-2544	266	8	ethanol	ethanol	NOUN
eurjchem-2544	266	9	(	(	PUNCT
eurjchem-2544	266	10	1:1	1:1	NUM
eurjchem-2544	266	11	)	)	PUNCT
eurjchem-2544	267	1	[	[	X
eurjchem-2544	267	2	8	8	NUM
eurjchem-2544	267	3	]	]	SYM
eurjchem-2544	267	4	2	2	NUM
eurjchem-2544	267	5	2.262(3	2.262(3	NUM
eurjchem-2544	267	6	)	)	PUNCT
eurjchem-2544	267	7	76.2(2)-166.5(2	76.2(2)-166.5(2	NOUN
eurjchem-2544	267	8	)	)	PUNCT
eurjchem-2544	267	9	acetone	acetone	NOUN
eurjchem-2544	268	1	[	[	X
eurjchem-2544	268	2	12	12	NUM
eurjchem-2544	268	3	]	]	SYM
eurjchem-2544	268	4	3	3	NUM
eurjchem-2544	268	5	2.2578(8)-2.2963(7	2.2578(8)-2.2963(7	NUM
eurjchem-2544	268	6	)	)	PUNCT
eurjchem-2544	268	7	2.2258(7)-2.2340(6)a	2.2258(7)-2.2340(6)a	NUM
eurjchem-2544	268	8	76.47(3)-167.84(3	76.47(3)-167.84(3	NUM
eurjchem-2544	268	9	)	)	PUNCT
eurjchem-2544	268	10	90.51(2)b	90.51(2)b	NUM
eurjchem-2544	268	11	diffusion	diffusion	NOUN
eurjchem-2544	268	12	of	of	ADP
eurjchem-2544	268	13	diethyl	diethyl	NOUN
eurjchem-2544	268	14	ether	ether	PROPN
eurjchem-2544	268	15	vapour	vapour	NOUN
eurjchem-2544	268	16	into	into	ADP
eurjchem-2544	268	17	acetonitrile	acetonitrile	ADJ
eurjchem-2544	268	18	solution	solution	NOUN
eurjchem-2544	268	19	[	[	X
eurjchem-2544	268	20	5	5	NUM
eurjchem-2544	268	21	]	]	SYM
eurjchem-2544	268	22	4	4	NUM
eurjchem-2544	268	23	2.269	2.269	NUM
eurjchem-2544	268	24	2.276a	2.276a	NUM
eurjchem-2544	268	25	77.03	77.03	NUM
eurjchem-2544	268	26	-	-	SYM
eurjchem-2544	268	27	102.97	102.97	NUM
eurjchem-2544	268	28	180b	180b	PROPN
eurjchem-2544	268	29	methanol	methanol	NOUN
eurjchem-2544	268	30	-	-	PUNCT
eurjchem-2544	268	31	dichloromethane	dichloromethane	NOUN
eurjchem-2544	268	32	(	(	PUNCT
eurjchem-2544	268	33	2:1	2:1	NUM
eurjchem-2544	268	34	)	)	PUNCT
eurjchem-2544	269	1	[	[	X
eurjchem-2544	269	2	5	5	NUM
eurjchem-2544	269	3	]	]	SYM
eurjchem-2544	269	4	5	5	NUM
eurjchem-2544	269	5	2.254(2)-2.273(2	2.254(2)-2.273(2	NOUN
eurjchem-2544	269	6	)	)	PUNCT
eurjchem-2544	269	7	76.2(1)-167.2(1	76.2(1)-167.2(1	NUM
eurjchem-2544	269	8	)	)	PUNCT
eurjchem-2544	269	9	acetone	acetone	NOUN
eurjchem-2544	270	1	[	[	X
eurjchem-2544	270	2	31	31	NUM
eurjchem-2544	270	3	]	]	SYM
eurjchem-2544	270	4	6	6	NUM
eurjchem-2544	270	5	2.253(1)-2.273(2	2.253(1)-2.273(2	NUM
eurjchem-2544	270	6	)	)	PUNCT
eurjchem-2544	270	7	76.24(5)-94.52(5	76.24(5)-94.52(5	NOUN
eurjchem-2544	270	8	)	)	PUNCT
eurjchem-2544	270	9	water	water	NOUN
eurjchem-2544	270	10	-	-	PUNCT
eurjchem-2544	270	11	n	n	CCONJ
eurjchem-2544	270	12	,	,	PUNCT
eurjchem-2544	270	13	n	n	CCONJ
eurjchem-2544	270	14	-	-	PUNCT
eurjchem-2544	270	15	dimethylformamide	dimethylformamide	NOUN
eurjchem-2544	270	16	[	[	X
eurjchem-2544	270	17	20	20	NUM
eurjchem-2544	270	18	]	]	SYM
eurjchem-2544	270	19	7	7	NUM
eurjchem-2544	270	20	2.258(1)-2.292(1	2.258(1)-2.292(1	NOUN
eurjchem-2544	270	21	)	)	PUNCT
eurjchem-2544	270	22	76.32(3)-167.65(4	76.32(3)-167.65(4	NUM
eurjchem-2544	270	23	)	)	PUNCT
eurjchem-2544	270	24	ethanol	ethanol	NOUN
eurjchem-2544	270	25	[	[	X
eurjchem-2544	270	26	32	32	NUM
eurjchem-2544	270	27	]	]	SYM
eurjchem-2544	270	28	8	8	NUM
eurjchem-2544	270	29	2.265(2)-2.304(1	2.265(2)-2.304(1	NOUN
eurjchem-2544	270	30	)	)	PUNCT
eurjchem-2544	270	31	2.237(2)-2.242(2)a	2.237(2)-2.242(2)a	NUM
eurjchem-2544	270	32	75.95(7)-169.44(7	75.95(7)-169.44(7	NUM
eurjchem-2544	270	33	)	)	PUNCT
eurjchem-2544	270	34	87.01b	87.01b	NUM
eurjchem-2544	270	35	chloroform	chloroform	NOUN
eurjchem-2544	271	1	[	[	X
eurjchem-2544	271	2	39	39	NUM
eurjchem-2544	271	3	]	]	SYM
eurjchem-2544	271	4	9	9	NUM
eurjchem-2544	271	5	2.271(1)-2.278(2	2.271(1)-2.278(2	NUM
eurjchem-2544	271	6	)	)	PUNCT
eurjchem-2544	271	7	2.169(1)-2.172(1)a	2.169(1)-2.172(1)a	NUM
eurjchem-2544	271	8	76.00(5)-165.21(5	76.00(5)-165.21(5	NUM
eurjchem-2544	271	9	)	)	PUNCT
eurjchem-2544	271	10	92.51(5)b	92.51(5)b	NUM
eurjchem-2544	271	11	chloroform	chloroform	NOUN
eurjchem-2544	272	1	[	[	X
eurjchem-2544	272	2	4	4	NUM
eurjchem-2544	272	3	]	]	SYM
eurjchem-2544	272	4	10	10	NUM
eurjchem-2544	272	5	2.282(3)-2.294(2	2.282(3)-2.294(2	NOUN
eurjchem-2544	272	6	)	)	PUNCT
eurjchem-2544	272	7	2.199(2)-2.241(2)a	2.199(2)-2.241(2)a	NUM
eurjchem-2544	272	8	75.52	75.52	NUM
eurjchem-2544	272	9	(	(	PUNCT
eurjchem-2544	272	10	7	7	NUM
eurjchem-2544	272	11	)	)	PUNCT
eurjchem-2544	272	12	87.71(8)-170.80(8)b	87.71(8)-170.80(8)b	NUM
eurjchem-2544	272	13	dichloromethane	dichloromethane	NOUN
eurjchem-2544	273	1	[	[	X
eurjchem-2544	273	2	4	4	NUM
eurjchem-2544	273	3	]	]	SYM
eurjchem-2544	273	4	11	11	NUM
eurjchem-2544	273	5	2.281(5)-2.292(4	2.281(5)-2.292(4	NUM
eurjchem-2544	273	6	)	)	PUNCT
eurjchem-2544	273	7	76.4	76.4	NUM
eurjchem-2544	273	8	-	-	SYM
eurjchem-2544	273	9	92.9	92.9	NUM
eurjchem-2544	273	10	acetonitrile	acetonitrile	NOUN
eurjchem-2544	273	11	[	[	X
eurjchem-2544	273	12	45	45	NUM
eurjchem-2544	273	13	]	]	SYM
eurjchem-2544	273	14	12	12	NUM
eurjchem-2544	273	15	2.259(1)-2.304(5	2.259(1)-2.304(5	NUM
eurjchem-2544	273	16	)	)	PUNCT
eurjchem-2544	273	17	76.3(2)-93.2(2	76.3(2)-93.2(2	NUM
eurjchem-2544	273	18	)	)	PUNCT
eurjchem-2544	273	19	acetonitrile	acetonitrile	NOUN
eurjchem-2544	273	20	-	-	PUNCT
eurjchem-2544	273	21	dichloromethane	dichloromethane	NOUN
eurjchem-2544	273	22	[	[	X
eurjchem-2544	273	23	45	45	NUM
eurjchem-2544	273	24	]	]	SYM
eurjchem-2544	273	25	13	13	NUM
eurjchem-2544	273	26	2.255(2)-2.284(3	2.255(2)-2.284(3	NOUN
eurjchem-2544	273	27	)	)	PUNCT
eurjchem-2544	273	28	76.46(7)-96.36(7	76.46(7)-96.36(7	NUM
eurjchem-2544	273	29	)	)	PUNCT
eurjchem-2544	273	30	slow	slow	ADJ
eurjchem-2544	273	31	diffusion	diffusion	NOUN
eurjchem-2544	273	32	of	of	ADP
eurjchem-2544	273	33	acetonitrile	acetonitrile	NOUN
eurjchem-2544	273	34	into	into	ADP
eurjchem-2544	273	35	dichloromethane	dichloromethane	NOUN
eurjchem-2544	273	36	solutions	solution	NOUN
eurjchem-2544	273	37	of	of	ADP
eurjchem-2544	273	38	complexes	complex	NOUN
eurjchem-2544	273	39	[	[	X
eurjchem-2544	273	40	26	26	NUM
eurjchem-2544	273	41	]	]	SYM
eurjchem-2544	273	42	14	14	NUM
eurjchem-2544	273	43	2.251(4)-2.287(4	2.251(4)-2.287(4	NUM
eurjchem-2544	273	44	)	)	PUNCT
eurjchem-2544	273	45	76.3(1)-98.1(1	76.3(1)-98.1(1	NUM
eurjchem-2544	273	46	)	)	PUNCT
eurjchem-2544	273	47	slow	slow	ADJ
eurjchem-2544	273	48	diffusion	diffusion	NOUN
eurjchem-2544	273	49	of	of	ADP
eurjchem-2544	273	50	acetonitrile	acetonitrile	NOUN
eurjchem-2544	273	51	into	into	ADP
eurjchem-2544	273	52	dichloromethane	dichloromethane	NOUN
eurjchem-2544	273	53	solutions	solution	NOUN
eurjchem-2544	273	54	of	of	ADP
eurjchem-2544	273	55	complexes	complex	NOUN
eurjchem-2544	273	56	[	[	X
eurjchem-2544	273	57	26	26	NUM
eurjchem-2544	273	58	]	]	SYM
eurjchem-2544	273	59	15	15	NUM
eurjchem-2544	273	60	2.249	2.249	NUM
eurjchem-2544	273	61	-	-	SYM
eurjchem-2544	273	62	2.274	2.274	NUM
eurjchem-2544	273	63	76.0	76.0	NUM
eurjchem-2544	273	64	-	-	SYM
eurjchem-2544	273	65	95.0	95.0	NUM
eurjchem-2544	273	66	slow	slow	ADJ
eurjchem-2544	273	67	diffusion	diffusion	NOUN
eurjchem-2544	273	68	of	of	ADP
eurjchem-2544	273	69	acetonitrile	acetonitrile	NOUN
eurjchem-2544	273	70	into	into	ADP
eurjchem-2544	273	71	dichloromethane	dichloromethane	NOUN
eurjchem-2544	273	72	solutions	solution	NOUN
eurjchem-2544	273	73	of	of	ADP
eurjchem-2544	273	74	complexes	complex	NOUN
eurjchem-2544	273	75	[	[	X
eurjchem-2544	273	76	26	26	NUM
eurjchem-2544	273	77	]	]	SYM
eurjchem-2544	273	78	16	16	NUM
eurjchem-2544	273	79	2.352(2)-2.382(2	2.352(2)-2.382(2	NUM
eurjchem-2544	273	80	)	)	PUNCT
eurjchem-2544	273	81	71.1(1)-167.8(1	71.1(1)-167.8(1	X
eurjchem-2544	273	82	)	)	PUNCT
eurjchem-2544	273	83	dichloromethane	dichloromethane	NOUN
eurjchem-2544	273	84	-	-	PUNCT
eurjchem-2544	273	85	ethanol	ethanol	NOUN
eurjchem-2544	273	86	[	[	X
eurjchem-2544	273	87	48	48	NUM
eurjchem-2544	273	88	]	]	SYM
eurjchem-2544	273	89	17	17	NUM
eurjchem-2544	273	90	2.355(7)-2.379(7	2.355(7)-2.379(7	NOUN
eurjchem-2544	273	91	)	)	PUNCT
eurjchem-2544	273	92	88.4(1)-114.5(1	88.4(1)-114.5(1	NOUN
eurjchem-2544	273	93	)	)	PUNCT
eurjchem-2544	273	94	chloroform	chloroform	NOUN
eurjchem-2544	273	95	-	-	PUNCT
eurjchem-2544	273	96	cyclohexane	cyclohexane	NOUN
eurjchem-2544	274	1	[	[	NOUN
eurjchem-2544	274	2	50	50	NUM
eurjchem-2544	274	3	]	]	SYM
eurjchem-2544	274	4	18	18	NUM
eurjchem-2544	274	5	2.365(2)-2.370(2	2.365(2)-2.370(2	NOUN
eurjchem-2544	274	6	)	)	PUNCT
eurjchem-2544	274	7	93.31(8)-166.65(7	93.31(8)-166.65(7	NUM
eurjchem-2544	274	8	)	)	PUNCT
eurjchem-2544	274	9	acetone	acetone	NOUN
eurjchem-2544	275	1	[	[	X
eurjchem-2544	275	2	52	52	NUM
eurjchem-2544	275	3	]	]	PUNCT
eurjchem-2544	275	4	tris(pyrrolidine-1	tris(pyrrolidine-1	PROPN
eurjchem-2544	275	5	-	-	PUNCT
eurjchem-2544	275	6	carbodithioato)cobalt	carbodithioato)cobalt	PROPN
eurjchem-2544	275	7	(	(	PUNCT
eurjchem-2544	275	8	iii	iii	NOUN
eurjchem-2544	275	9	)	)	PUNCT
eurjchem-2544	275	10	of	of	ADP
eurjchem-2544	275	11	the	the	DET
eurjchem-2544	275	12	formula	formula	NOUN
eurjchem-2544	275	13	[	[	X
eurjchem-2544	275	14	co(s2cn(ch2)4)3	co(s2cn(ch2)4)3	X
eurjchem-2544	275	15	]	]	X
eurjchem-2544	275	16	(	(	PUNCT
eurjchem-2544	275	17	13	13	NUM
eurjchem-2544	275	18	,	,	PUNCT
eurjchem-2544	275	19	figure	figure	NOUN
eurjchem-2544	275	20	10	10	NUM
eurjchem-2544	275	21	)	)	PUNCT
eurjchem-2544	275	22	crystallizes	crystallize	NOUN
eurjchem-2544	275	23	in	in	ADP
eurjchem-2544	275	24	the	the	DET
eurjchem-2544	275	25	c2	c2	PROPN
eurjchem-2544	275	26	/	/	SYM
eurjchem-2544	275	27	c	c	PROPN
eurjchem-2544	275	28	space	space	NOUN
eurjchem-2544	275	29	group	group	NOUN
eurjchem-2544	275	30	of	of	ADP
eurjchem-2544	275	31	the	the	DET
eurjchem-2544	275	32	monoclinic	monoclinic	ADJ
eurjchem-2544	275	33	crystal	crystal	NOUN
eurjchem-2544	275	34	system	system	NOUN
eurjchem-2544	275	35	[	[	X
eurjchem-2544	275	36	26	26	NUM
eurjchem-2544	275	37	]	]	PUNCT
eurjchem-2544	275	38	.	.	PUNCT
eurjchem-2544	276	1	its	its	PRON
eurjchem-2544	276	2	asymmetric	asymmetric	ADJ
eurjchem-2544	276	3	unit	unit	NOUN
eurjchem-2544	276	4	consists	consist	VERB
eurjchem-2544	276	5	of	of	ADP
eurjchem-2544	276	6	two	two	NUM
eurjchem-2544	276	7	molecules	molecule	NOUN
eurjchem-2544	276	8	of	of	ADP
eurjchem-2544	276	9	complex	complex	ADJ
eurjchem-2544	276	10	13	13	NUM
eurjchem-2544	276	11	and	and	CCONJ
eurjchem-2544	276	12	the	the	DET
eurjchem-2544	276	13	ligand	ligand	NOUN
eurjchem-2544	276	14	of	of	ADP
eurjchem-2544	276	15	one	one	NUM
eurjchem-2544	276	16	of	of	ADP
eurjchem-2544	276	17	the	the	DET
eurjchem-2544	276	18	molecules	molecule	NOUN
eurjchem-2544	276	19	is	be	AUX
eurjchem-2544	276	20	located	locate	VERB
eurjchem-2544	276	21	on	on	ADP
eurjchem-2544	276	22	a	a	DET
eurjchem-2544	276	23	crystallographic	crystallographic	ADJ
eurjchem-2544	276	24	2	2	NUM
eurjchem-2544	276	25	-	-	ADJ
eurjchem-2544	276	26	fold	fold	ADJ
eurjchem-2544	276	27	axis	axis	NOUN
eurjchem-2544	276	28	.	.	PUNCT
eurjchem-2544	277	1	the	the	DET
eurjchem-2544	277	2	geometrical	geometrical	ADJ
eurjchem-2544	277	3	alignments	alignment	NOUN
eurjchem-2544	277	4	of	of	ADP
eurjchem-2544	277	5	the	the	DET
eurjchem-2544	277	6	two	two	NUM
eurjchem-2544	277	7	molecules	molecule	NOUN
eurjchem-2544	277	8	are	be	AUX
eurjchem-2544	277	9	not	not	PART
eurjchem-2544	277	10	significantly	significantly	ADV
eurjchem-2544	277	11	different	different	ADJ
eurjchem-2544	277	12	except	except	SCONJ
eurjchem-2544	277	13	for	for	ADP
eurjchem-2544	277	14	their	their	PRON
eurjchem-2544	277	15	cos	cos	ADJ
eurjchem-2544	277	16	bond	bond	NOUN
eurjchem-2544	277	17	distances	distance	NOUN
eurjchem-2544	277	18	,	,	PUNCT
eurjchem-2544	277	19	which	which	PRON
eurjchem-2544	277	20	show	show	VERB
eurjchem-2544	277	21	a	a	DET
eurjchem-2544	277	22	considerable	considerable	ADJ
eurjchem-2544	277	23	long	long	ADJ
eurjchem-2544	277	24	-	-	PUNCT
eurjchem-2544	277	25	range	range	NOUN
eurjchem-2544	277	26	stretch	stretch	NOUN
eurjchem-2544	277	27	of	of	ADP
eurjchem-2544	277	28	2.254(3)-2.291(2	2.254(3)-2.291(2	NOUN
eurjchem-2544	277	29	)	)	PUNCT
eurjchem-2544	277	30	å	å	NOUN
eurjchem-2544	277	31	.	.	PUNCT
eurjchem-2544	278	1	such	such	ADJ
eurjchem-2544	278	2	stretches	stretch	NOUN
eurjchem-2544	278	3	have	have	AUX
eurjchem-2544	278	4	been	be	AUX
eurjchem-2544	278	5	observed	observe	VERB
eurjchem-2544	278	6	in	in	ADP
eurjchem-2544	278	7	heterobimetallic	heterobimetallic	ADJ
eurjchem-2544	278	8	adducts	adduct	NOUN
eurjchem-2544	278	9	;	;	PUNCT
eurjchem-2544	278	10	[	[	X
eurjchem-2544	278	11	co(s2cn(ch2)4)3]·3cui	co(s2cn(ch2)4)3]·3cui	X
eurjchem-2544	279	1	[	[	X
eurjchem-2544	279	2	45	45	NUM
eurjchem-2544	279	3	]	]	PUNCT
eurjchem-2544	279	4	,	,	PUNCT
eurjchem-2544	280	1	[	[	X
eurjchem-2544	280	2	co(s2	co(s2	X
eurjchem-2544	280	3	cn(ch2)4)3]·cubr	cn(ch2)4)3]·cubr	NOUN
eurjchem-2544	280	4	[	[	X
eurjchem-2544	280	5	46	46	NUM
eurjchem-2544	280	6	]	]	PUNCT
eurjchem-2544	280	7	,	,	PUNCT
eurjchem-2544	280	8	and	and	CCONJ
eurjchem-2544	280	9	[	[	X
eurjchem-2544	280	10	co(s2cn(ch2)4)3]·3cubr·mecn	co(s2cn(ch2)4)3]·3cubr·mecn	X
eurjchem-2544	280	11	[	[	X
eurjchem-2544	280	12	47	47	NUM
eurjchem-2544	280	13	]	]	PUNCT
eurjchem-2544	280	14	with	with	ADP
eurjchem-2544	280	15	ranges	range	NOUN
eurjchem-2544	280	16	2.259(1)-2.304(5	2.259(1)-2.304(5	NUM
eurjchem-2544	280	17	)	)	PUNCT
eurjchem-2544	280	18	,	,	PUNCT
eurjchem-2544	280	19	2.258(2)-2.307(2	2.258(2)-2.307(2	NUM
eurjchem-2544	280	20	)	)	PUNCT
eurjchem-2544	280	21	and	and	CCONJ
eurjchem-2544	280	22	2.26(1)-2.30(1	2.26(1)-2.30(1	NUM
eurjchem-2544	280	23	)	)	PUNCT
eurjchem-2544	280	24	å	å	NOUN
eurjchem-2544	280	25	,	,	PUNCT
eurjchem-2544	280	26	respectively	respectively	ADV
eurjchem-2544	280	27	.	.	PUNCT
eurjchem-2544	281	1	the	the	DET
eurjchem-2544	281	2	stretch	stretch	ADJ
eurjchem-2544	281	3	phenomenon	phenomenon	NOUN
eurjchem-2544	281	4	has	have	AUX
eurjchem-2544	281	5	also	also	ADV
eurjchem-2544	281	6	been	be	AUX
eurjchem-2544	281	7	observed	observe	VERB
eurjchem-2544	281	8	in	in	ADP
eurjchem-2544	281	9	the	the	DET
eurjchem-2544	281	10	dihydrogen	dihydrogen	NOUN
eurjchem-2544	281	11	complex	complex	NOUN
eurjchem-2544	281	12	[	[	X
eurjchem-2544	281	13	co(s2cnh2)3	co(s2cnh2)3	X
eurjchem-2544	281	14	]	]	X
eurjchem-2544	281	15	[	[	X
eurjchem-2544	281	16	32	32	NUM
eurjchem-2544	281	17	]	]	PUNCT
eurjchem-2544	281	18	.	.	PUNCT
eurjchem-2544	282	1	the	the	DET
eurjchem-2544	282	2	striking	striking	ADJ
eurjchem-2544	282	3	variation	variation	NOUN
eurjchem-2544	282	4	in	in	ADP
eurjchem-2544	282	5	the	the	DET
eurjchem-2544	282	6	co	co	NOUN
eurjchem-2544	282	7	-	-	NOUN
eurjchem-2544	282	8	s	s	PART
eurjchem-2544	282	9	bond	bond	NOUN
eurjchem-2544	282	10	distances	distance	NOUN
eurjchem-2544	282	11	is	be	AUX
eurjchem-2544	282	12	attached	attach	VERB
eurjchem-2544	282	13	to	to	ADP
eurjchem-2544	282	14	the	the	DET
eurjchem-2544	282	15	rigid	rigid	ADJ
eurjchem-2544	282	16	pyrrolidine	pyrrolidine	ADJ
eurjchem-2544	282	17	ligands	ligand	NOUN
eurjchem-2544	282	18	,	,	PUNCT
eurjchem-2544	282	19	which	which	PRON
eurjchem-2544	282	20	enforce	enforce	VERB
eurjchem-2544	282	21	a	a	DET
eurjchem-2544	282	22	level	level	NOUN
eurjchem-2544	282	23	of	of	ADP
eurjchem-2544	282	24	restriction	restriction	NOUN
eurjchem-2544	282	25	on	on	ADP
eurjchem-2544	282	26	the	the	DET
eurjchem-2544	282	27	number	number	NOUN
eurjchem-2544	282	28	of	of	ADP
eurjchem-2544	282	29	adaptable	adaptable	ADJ
eurjchem-2544	282	30	conformations	conformation	NOUN
eurjchem-2544	282	31	so	so	SCONJ
eurjchem-2544	282	32	that	that	SCONJ
eurjchem-2544	282	33	the	the	DET
eurjchem-2544	282	34	molecule	molecule	NOUN
eurjchem-2544	282	35	can	can	AUX
eurjchem-2544	282	36	retain	retain	VERB
eurjchem-2544	282	37	a	a	DET
eurjchem-2544	282	38	stable	stable	ADJ
eurjchem-2544	282	39	geometry	geometry	NOUN
eurjchem-2544	282	40	.	.	PUNCT
eurjchem-2544	283	1	its	its	PRON
eurjchem-2544	283	2	crystal	crystal	NOUN
eurjchem-2544	283	3	lattice	lattice	NOUN
eurjchem-2544	283	4	is	be	AUX
eurjchem-2544	283	5	dominated	dominate	VERB
eurjchem-2544	283	6	by	by	ADP
eurjchem-2544	283	7	short	short	ADJ
eurjchem-2544	283	8	h···s	h···	NOUN
eurjchem-2544	283	9	and	and	CCONJ
eurjchem-2544	283	10	h···h	h···h	PROPN
eurjchem-2544	283	11	contacts	contact	NOUN
eurjchem-2544	283	12	from	from	ADP
eurjchem-2544	283	13	hydrogenbond	hydrogenbond	ADJ
eurjchem-2544	283	14	interactions	interaction	NOUN
eurjchem-2544	283	15	in	in	ADP
eurjchem-2544	283	16	the	the	DET
eurjchem-2544	283	17	range	range	NOUN
eurjchem-2544	283	18	2.816	2.816	NUM
eurjchem-2544	283	19	-	-	SYM
eurjchem-2544	283	20	2.850	2.850	NUM
eurjchem-2544	283	21	å	å	NOUN
eurjchem-2544	283	22	and	and	CCONJ
eurjchem-2544	283	23	2.343	2.343	NUM
eurjchem-2544	283	24	å	å	NOUN
eurjchem-2544	283	25	,	,	PUNCT
eurjchem-2544	283	26	respectively	respectively	ADV
eurjchem-2544	283	27	.	.	PUNCT
eurjchem-2544	284	1	tris(n	tris(n	VERB
eurjchem-2544	284	2	,	,	PUNCT
eurjchem-2544	284	3	n	n	CCONJ
eurjchem-2544	284	4	-	-	PUNCT
eurjchem-2544	284	5	dibenzyldithiocarbamato)cobalt(iii	dibenzyldithiocarbamato)cobalt(iii	NOUN
eurjchem-2544	284	6	)	)	PUNCT
eurjchem-2544	284	7	of	of	ADP
eurjchem-2544	284	8	the	the	DET
eurjchem-2544	284	9	formula	formula	NOUN
eurjchem-2544	284	10	[	[	X
eurjchem-2544	284	11	co(s2cn(ch2ph)2)3	co(s2cn(ch2ph)2)3	X
eurjchem-2544	284	12	]	]	X
eurjchem-2544	284	13	(	(	PUNCT
eurjchem-2544	284	14	14	14	NUM
eurjchem-2544	284	15	,	,	PUNCT
eurjchem-2544	284	16	figure	figure	NOUN
eurjchem-2544	284	17	10	10	NUM
eurjchem-2544	284	18	)	)	PUNCT
eurjchem-2544	284	19	crystallizes	crystallize	NOUN
eurjchem-2544	284	20	in	in	ADP
eurjchem-2544	284	21	the	the	DET
eurjchem-2544	284	22	non	non	ADJ
eurjchem-2544	284	23	-	-	ADJ
eurjchem-2544	284	24	centrosymmetric	centrosymmetric	ADJ
eurjchem-2544	284	25	p2/1	p2/1	NOUN
eurjchem-2544	284	26	space	space	NOUN
eurjchem-2544	284	27	group	group	NOUN
eurjchem-2544	284	28	with	with	ADP
eurjchem-2544	284	29	two	two	NUM
eurjchem-2544	284	30	molecules	molecule	NOUN
eurjchem-2544	284	31	of	of	ADP
eurjchem-2544	284	32	opposite	opposite	ADJ
eurjchem-2544	284	33	chirality	chirality	NOUN
eurjchem-2544	284	34	in	in	ADP
eurjchem-2544	284	35	the	the	DET
eurjchem-2544	284	36	asymmetric	asymmetric	ADJ
eurjchem-2544	284	37	unit	unit	NOUN
eurjchem-2544	285	1	[	[	X
eurjchem-2544	285	2	26	26	NUM
eurjchem-2544	285	3	]	]	PUNCT
eurjchem-2544	285	4	.	.	PUNCT
eurjchem-2544	286	1	it	it	PRON
eurjchem-2544	286	2	is	be	AUX
eurjchem-2544	286	3	isostructural	isostructural	ADJ
eurjchem-2544	286	4	with	with	ADP
eurjchem-2544	286	5	a	a	DET
eurjchem-2544	286	6	[	[	X
eurjchem-2544	286	7	feiii(s2cn(ch2ph)2)3	feiii(s2cn(ch2ph)2)3	X
eurjchem-2544	286	8	]	]	X
eurjchem-2544	286	9	crystalline	crystalline	ADJ
eurjchem-2544	286	10	analogue	analogue	NOUN
eurjchem-2544	286	11	[	[	X
eurjchem-2544	286	12	15	15	NUM
eurjchem-2544	286	13	]	]	PUNCT
eurjchem-2544	286	14	.	.	PUNCT
eurjchem-2544	287	1	the	the	DET
eurjchem-2544	287	2	cos	cos	PROPN
eurjchem-2544	287	3	distances	distance	NOUN
eurjchem-2544	287	4	in	in	ADP
eurjchem-2544	287	5	the	the	DET
eurjchem-2544	287	6	two	two	NUM
eurjchem-2544	287	7	molecules	molecule	NOUN
eurjchem-2544	287	8	spread	spread	VERB
eurjchem-2544	287	9	out	out	ADP
eurjchem-2544	287	10	in	in	ADP
eurjchem-2544	287	11	the	the	DET
eurjchem-2544	287	12	range	range	NOUN
eurjchem-2544	287	13	2.250(3)-2.283(4	2.250(3)-2.283(4	NOUN
eurjchem-2544	287	14	)	)	PUNCT
eurjchem-2544	287	15	å	å	NOUN
eurjchem-2544	287	16	to	to	PART
eurjchem-2544	287	17	form	form	VERB
eurjchem-2544	287	18	an	an	DET
eurjchem-2544	287	19	average	average	ADJ
eurjchem-2544	287	20	value	value	NOUN
eurjchem-2544	287	21	of	of	ADP
eurjchem-2544	287	22	2.26	2.26	NUM
eurjchem-2544	287	23	å	å	NOUN
eurjchem-2544	287	24	.	.	PUNCT
eurjchem-2544	288	1	the	the	DET
eurjchem-2544	288	2	deviations	deviation	NOUN
eurjchem-2544	288	3	of	of	ADP
eurjchem-2544	288	4	the	the	DET
eurjchem-2544	288	5	co	co	NOUN
eurjchem-2544	288	6	atoms	atom	NOUN
eurjchem-2544	288	7	from	from	ADP
eurjchem-2544	288	8	the	the	DET
eurjchem-2544	288	9	s2cn	s2cn	PROPN
eurjchem-2544	288	10	planes	plane	NOUN
eurjchem-2544	288	11	are	be	AUX
eurjchem-2544	288	12	0.420	0.420	NUM
eurjchem-2544	288	13	,	,	PUNCT
eurjchem-2544	288	14	0.214	0.214	NUM
eurjchem-2544	288	15	,	,	PUNCT
eurjchem-2544	288	16	0.428	0.428	NUM
eurjchem-2544	288	17	,	,	PUNCT
eurjchem-2544	288	18	0.422	0.422	NUM
eurjchem-2544	288	19	,	,	PUNCT
eurjchem-2544	288	20	0.331	0.331	NUM
eurjchem-2544	288	21	and	and	CCONJ
eurjchem-2544	288	22	0.263	0.263	NUM
eurjchem-2544	288	23	å	å	NOUN
eurjchem-2544	288	24	.	.	PUNCT
eurjchem-2544	289	1	the	the	DET
eurjchem-2544	289	2	phenyl	phenyl	NOUN
eurjchem-2544	289	3	rings	ring	NOUN
eurjchem-2544	289	4	are	be	AUX
eurjchem-2544	289	5	closely	closely	ADV
eurjchem-2544	289	6	normal	normal	ADJ
eurjchem-2544	289	7	to	to	ADP
eurjchem-2544	289	8	the	the	DET
eurjchem-2544	289	9	s2cn	s2cn	ADJ
eurjchem-2544	289	10	plane	plane	NOUN
eurjchem-2544	289	11	with	with	ADP
eurjchem-2544	289	12	angles	angle	NOUN
eurjchem-2544	289	13	59.4	59.4	NUM
eurjchem-2544	289	14	-	-	SYM
eurjchem-2544	289	15	87.7	87.7	NUM
eurjchem-2544	289	16	°	°	NOUN
eurjchem-2544	289	17	in	in	ADP
eurjchem-2544	289	18	molecule	molecule	NOUN
eurjchem-2544	289	19	1	1	NUM
eurjchem-2544	289	20	and	and	CCONJ
eurjchem-2544	289	21	66.4	66.4	NUM
eurjchem-2544	289	22	-	-	SYM
eurjchem-2544	289	23	87.7	87.7	NUM
eurjchem-2544	289	24	°	°	NOUN
eurjchem-2544	289	25	in	in	ADP
eurjchem-2544	289	26	molecule	molecule	NOUN
eurjchem-2544	289	27	2	2	NUM
eurjchem-2544	289	28	.	.	PUNCT
eurjchem-2544	290	1	the	the	DET
eurjchem-2544	290	2	crystal	crystal	PROPN
eurjchem-2544	290	3	lattice	lattice	NOUN
eurjchem-2544	290	4	of	of	ADP
eurjchem-2544	290	5	complex	complex	ADJ
eurjchem-2544	290	6	14	14	NUM
eurjchem-2544	290	7	is	be	AUX
eurjchem-2544	290	8	dominated	dominate	VERB
eurjchem-2544	290	9	by	by	ADP
eurjchem-2544	290	10	short	short	ADJ
eurjchem-2544	290	11	intermolecular	intermolecular	ADJ
eurjchem-2544	290	12	h···h	h···h	PROPN
eurjchem-2544	290	13	,	,	PUNCT
eurjchem-2544	290	14	c···h	c···h	PROPN
eurjchem-2544	290	15	,	,	PUNCT
eurjchem-2544	290	16	and	and	CCONJ
eurjchem-2544	290	17	h···s	h···s	NOUN
eurjchem-2544	290	18	contacts	contact	NOUN
eurjchem-2544	290	19	.	.	PUNCT
eurjchem-2544	291	1	tris(n	tris(n	VERB
eurjchem-2544	291	2	,	,	PUNCT
eurjchem-2544	291	3	n	n	CCONJ
eurjchem-2544	291	4	-	-	PUNCT
eurjchem-2544	291	5	diisopropyldithiocarbamato)cobalt(iii	diisopropyldithiocarbamato)cobalt(iii	NOUN
eurjchem-2544	291	6	)	)	PUNCT
eurjchem-2544	291	7	of	of	ADP
eurjchem-2544	291	8	the	the	DET
eurjchem-2544	291	9	formula	formula	NOUN
eurjchem-2544	291	10	[	[	X
eurjchem-2544	291	11	co(s2cnpri2)3	co(s2cnpri2)3	PROPN
eurjchem-2544	291	12	(	(	PUNCT
eurjchem-2544	291	13	15	15	NUM
eurjchem-2544	291	14	,	,	PUNCT
eurjchem-2544	291	15	figure	figure	NOUN
eurjchem-2544	291	16	10	10	NUM
eurjchem-2544	291	17	)	)	PUNCT
eurjchem-2544	291	18	crystallizes	crystallize	NOUN
eurjchem-2544	291	19	in	in	ADP
eurjchem-2544	291	20	the	the	DET
eurjchem-2544	291	21	rhombohedral	rhombohedral	ADJ
eurjchem-2544	291	22	r3c	r3c	PROPN
eurjchem-2544	291	23	space	space	NOUN
eurjchem-2544	291	24	group	group	NOUN
eurjchem-2544	291	25	[	[	X
eurjchem-2544	291	26	26	26	NUM
eurjchem-2544	291	27	]	]	PUNCT
eurjchem-2544	291	28	.	.	PUNCT
eurjchem-2544	292	1	the	the	DET
eurjchem-2544	292	2	molecule	molecule	NOUN
eurjchem-2544	292	3	lies	lie	VERB
eurjchem-2544	292	4	on	on	ADP
eurjchem-2544	292	5	a	a	DET
eurjchem-2544	292	6	crystallographic	crystallographic	ADJ
eurjchem-2544	292	7	3	3	NUM
eurjchem-2544	292	8	-	-	ADJ
eurjchem-2544	292	9	fold	fold	ADJ
eurjchem-2544	292	10	axis	axis	NOUN
eurjchem-2544	292	11	such	such	ADJ
eurjchem-2544	292	12	that	that	SCONJ
eurjchem-2544	292	13	the	the	DET
eurjchem-2544	292	14	asymmetric	asymmetric	ADJ
eurjchem-2544	292	15	unit	unit	NOUN
eurjchem-2544	292	16	consists	consist	VERB
eurjchem-2544	292	17	of	of	ADP
eurjchem-2544	292	18	just	just	ADV
eurjchem-2544	292	19	one	one	NUM
eurjchem-2544	292	20	ligand	ligand	NOUN
eurjchem-2544	292	21	framework	framework	NOUN
eurjchem-2544	292	22	.	.	PUNCT
eurjchem-2544	293	1	the	the	DET
eurjchem-2544	293	2	precision	precision	NOUN
eurjchem-2544	293	3	of	of	ADP
eurjchem-2544	293	4	its	its	PRON
eurjchem-2544	293	5	determination	determination	NOUN
eurjchem-2544	293	6	was	be	AUX
eurjchem-2544	293	7	vehemently	vehemently	ADV
eurjchem-2544	293	8	affected	affect	VERB
eurjchem-2544	293	9	by	by	ADP
eurjchem-2544	293	10	the	the	DET
eurjchem-2544	293	11	high	high	ADJ
eurjchem-2544	293	12	temperature	temperature	NOUN
eurjchem-2544	293	13	(	(	PUNCT
eurjchem-2544	293	14	295	295	NUM
eurjchem-2544	293	15	k	k	NOUN
eurjchem-2544	293	16	)	)	PUNCT
eurjchem-2544	293	17	of	of	ADP
eurjchem-2544	293	18	the	the	DET
eurjchem-2544	293	19	measurement	measurement	NOUN
eurjchem-2544	293	20	,	,	PUNCT
eurjchem-2544	293	21	resulting	result	VERB
eurjchem-2544	293	22	in	in	ADP
eurjchem-2544	293	23	a	a	DET
eurjchem-2544	293	24	high	high	ADJ
eurjchem-2544	293	25	thermal	thermal	ADJ
eurjchem-2544	293	26	motion	motion	NOUN
eurjchem-2544	293	27	disorder	disorder	NOUN
eurjchem-2544	293	28	.	.	PUNCT
eurjchem-2544	294	1	deviations	deviation	NOUN
eurjchem-2544	294	2	of	of	ADP
eurjchem-2544	294	3	0.09	0.09	NUM
eurjchem-2544	294	4	and	and	CCONJ
eurjchem-2544	294	5	-0.14	-0.14	PRON
eurjchem-2544	294	6	å	å	NOUN
eurjchem-2544	294	7	were	be	AUX
eurjchem-2544	294	8	experienced	experience	VERB
eurjchem-2544	294	9	by	by	ADP
eurjchem-2544	294	10	c2	c2	PROPN
eurjchem-2544	294	11	and	and	CCONJ
eurjchem-2544	294	12	c5	c5	PROPN
eurjchem-2544	294	13	,	,	PUNCT
eurjchem-2544	294	14	respectively	respectively	ADV
eurjchem-2544	294	15	,	,	PUNCT
eurjchem-2544	294	16	while	while	SCONJ
eurjchem-2544	294	17	the	the	DET
eurjchem-2544	294	18	co	co	X
eurjchem-2544	294	19	atom	atom	NOUN
eurjchem-2544	294	20	deviated	deviate	VERB
eurjchem-2544	294	21	by	by	ADP
eurjchem-2544	294	22	0.17	0.17	NUM
eurjchem-2544	294	23	å	å	PROPN
eurjchem-2544	294	24	from	from	ADP
eurjchem-2544	294	25	the	the	DET
eurjchem-2544	294	26	s2cn	s2cn	PROPN
eurjchem-2544	294	27	plane	plane	NOUN
eurjchem-2544	294	28	.	.	PUNCT
eurjchem-2544	295	1	a	a	DET
eurjchem-2544	295	2	difference	difference	NOUN
eurjchem-2544	295	3	of	of	ADP
eurjchem-2544	295	4	0.02	0.02	NUM
eurjchem-2544	295	5	å	å	NOUN
eurjchem-2544	295	6	was	be	AUX
eurjchem-2544	295	7	observed	observe	VERB
eurjchem-2544	295	8	for	for	ADP
eurjchem-2544	295	9	the	the	DET
eurjchem-2544	295	10	two	two	NUM
eurjchem-2544	295	11	independent	independent	ADJ
eurjchem-2544	295	12	co	co	NOUN
eurjchem-2544	295	13	-	-	ADJ
eurjchem-2544	295	14	s	s	PART
eurjchem-2544	295	15	bond	bond	NOUN
eurjchem-2544	295	16	distances	distance	NOUN
eurjchem-2544	295	17	whose	whose	DET
eurjchem-2544	295	18	average	average	NOUN
eurjchem-2544	295	19	equals	equal	VERB
eurjchem-2544	295	20	2.26	2.26	NUM
eurjchem-2544	295	21	å	å	NOUN
eurjchem-2544	295	22	.	.	PUNCT
eurjchem-2544	296	1	the	the	DET
eurjchem-2544	296	2	high	high	ADJ
eurjchem-2544	296	3	-	-	PUNCT
eurjchem-2544	296	4	temperature	temperature	NOUN
eurjchem-2544	296	5	determination	determination	NOUN
eurjchem-2544	296	6	prevented	prevent	VERB
eurjchem-2544	296	7	satisfactory	satisfactory	ADJ
eurjchem-2544	296	8	resolution	resolution	NOUN
eurjchem-2544	296	9	of	of	ADP
eurjchem-2544	296	10	the	the	DET
eurjchem-2544	296	11	components	component	NOUN
eurjchem-2544	296	12	of	of	ADP
eurjchem-2544	296	13	the	the	DET
eurjchem-2544	296	14	non	non	ADJ
eurjchem-2544	296	15	-	-	ADJ
eurjchem-2544	296	16	hydrogen	hydrogen	ADJ
eurjchem-2544	296	17	atoms	atom	NOUN
eurjchem-2544	296	18	.	.	PUNCT
eurjchem-2544	297	1	the	the	DET
eurjchem-2544	297	2	pyramidal	pyramidal	ADJ
eurjchem-2544	297	3	geometry	geometry	NOUN
eurjchem-2544	297	4	expected	expect	VERB
eurjchem-2544	297	5	of	of	ADP
eurjchem-2544	297	6	the	the	DET
eurjchem-2544	297	7	central	central	ADJ
eurjchem-2544	297	8	carbon	carbon	NOUN
eurjchem-2544	297	9	atom	atom	NOUN
eurjchem-2544	297	10	of	of	ADP
eurjchem-2544	297	11	the	the	DET
eurjchem-2544	297	12	isopropyl	isopropyl	NOUN
eurjchem-2544	297	13	groups	group	NOUN
eurjchem-2544	297	14	is	be	AUX
eurjchem-2544	297	15	not	not	PART
eurjchem-2544	297	16	adequately	adequately	ADV
eurjchem-2544	297	17	defined	define	VERB
eurjchem-2544	297	18	.	.	PUNCT
eurjchem-2544	298	1	it	it	PRON
eurjchem-2544	298	2	was	be	AUX
eurjchem-2544	298	3	observed	observe	VERB
eurjchem-2544	298	4	that	that	SCONJ
eurjchem-2544	298	5	the	the	DET
eurjchem-2544	298	6	influence	influence	NOUN
eurjchem-2544	298	7	of	of	ADP
eurjchem-2544	298	8	substituents	substituent	NOUN
eurjchem-2544	298	9	(	(	PUNCT
eurjchem-2544	298	10	aliphatic	aliphatic	ADJ
eurjchem-2544	298	11	hydrocarbons	hydrocarbon	NOUN
eurjchem-2544	298	12	)	)	PUNCT
eurjchem-2544	298	13	on	on	ADP
eurjchem-2544	298	14	sulfur	sulfur	NOUN
eurjchem-2544	298	15	atoms	atom	NOUN
eurjchem-2544	298	16	through	through	ADP
eurjchem-2544	298	17	the	the	DET
eurjchem-2544	298	18	ligand	ligand	ADJ
eurjchem-2544	298	19	field	field	NOUN
eurjchem-2544	298	20	strength	strength	NOUN
eurjchem-2544	298	21	is	be	AUX
eurjchem-2544	298	22	not	not	PART
eurjchem-2544	298	23	through	through	ADP
eurjchem-2544	298	24	the	the	DET
eurjchem-2544	298	25	predicted	predict	VERB
eurjchem-2544	298	26	π	π	NOUN
eurjchem-2544	298	27	-	-	NOUN
eurjchem-2544	298	28	bonding	bonding	NOUN
eurjchem-2544	298	29	of	of	ADP
eurjchem-2544	298	30	the	the	DET
eurjchem-2544	298	31	s2cn	s2cn	ADJ
eurjchem-2544	298	32	moiety	moiety	NOUN
eurjchem-2544	298	33	but	but	CCONJ
eurjchem-2544	298	34	through	through	ADP
eurjchem-2544	298	35	intra	intra	ADJ
eurjchem-2544	298	36	-	-	ADJ
eurjchem-2544	298	37	ligand	ligand	ADJ
eurjchem-2544	298	38	s···h	s···h	PROPN
eurjchem-2544	298	39	-	-	PUNCT
eurjchem-2544	298	40	c	c	NOUN
eurjchem-2544	298	41	interactions	interaction	NOUN
eurjchem-2544	298	42	whose	whose	DET
eurjchem-2544	298	43	strength	strength	NOUN
eurjchem-2544	298	44	rises	rise	VERB
eurjchem-2544	298	45	with	with	ADP
eurjchem-2544	298	46	increase	increase	NOUN
eurjchem-2544	298	47	in	in	ADP
eurjchem-2544	298	48	the	the	DET
eurjchem-2544	298	49	bulkiness	bulkiness	NOUN
eurjchem-2544	298	50	of	of	ADP
eurjchem-2544	298	51	the	the	DET
eurjchem-2544	298	52	substituents	substituent	NOUN
eurjchem-2544	298	53	.	.	PUNCT
eurjchem-2544	299	1	table	table	NOUN
eurjchem-2544	299	2	3	3	NUM
eurjchem-2544	299	3	shows	show	VERB
eurjchem-2544	299	4	the	the	DET
eurjchem-2544	299	5	selected	select	VERB
eurjchem-2544	299	6	bond	bond	NOUN
eurjchem-2544	299	7	distances	distance	NOUN
eurjchem-2544	299	8	,	,	PUNCT
eurjchem-2544	299	9	angles	angle	NOUN
eurjchem-2544	299	10	,	,	PUNCT
eurjchem-2544	299	11	and	and	CCONJ
eurjchem-2544	299	12	solvents	solvent	NOUN
eurjchem-2544	299	13	for	for	ADP
eurjchem-2544	299	14	crystal	crystal	NOUN
eurjchem-2544	299	15	growth	growth	NOUN
eurjchem-2544	299	16	in	in	ADP
eurjchem-2544	299	17	complexes	complex	NOUN
eurjchem-2544	299	18	1	1	NUM
eurjchem-2544	299	19	-	-	SYM
eurjchem-2544	299	20	18	18	NUM
eurjchem-2544	299	21	.	.	PUNCT
eurjchem-2544	300	1	it	it	PRON
eurjchem-2544	300	2	shows	show	VERB
eurjchem-2544	300	3	the	the	DET
eurjchem-2544	300	4	changes	change	NOUN
eurjchem-2544	300	5	in	in	ADP
eurjchem-2544	300	6	bond	bond	NOUN
eurjchem-2544	300	7	angles	angle	NOUN
eurjchem-2544	300	8	and	and	CCONJ
eurjchem-2544	300	9	distance	distance	NOUN
eurjchem-2544	300	10	as	as	SCONJ
eurjchem-2544	300	11	the	the	DET
eurjchem-2544	300	12	r	r	NOUN
eurjchem-2544	300	13	substituents	substituent	NOUN
eurjchem-2544	300	14	in	in	ADP
eurjchem-2544	300	15	the	the	DET
eurjchem-2544	300	16	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	300	17	backbones	backbone	NOUN
eurjchem-2544	300	18	are	be	AUX
eurjchem-2544	300	19	changed	change	VERB
eurjchem-2544	300	20	or	or	CCONJ
eurjchem-2544	300	21	modified	modify	VERB
eurjchem-2544	300	22	.	.	PUNCT
eurjchem-2544	301	1	2.2	2.2	NUM
eurjchem-2544	301	2	.	.	PUNCT
eurjchem-2544	302	1	rh(iii	rh(iii	NOUN
eurjchem-2544	302	2	)	)	PUNCT
eurjchem-2544	302	3	complexes	complexe	VERB
eurjchem-2544	302	4	dichloromethane	dichloromethane	NOUN
eurjchem-2544	302	5	-	-	PUNCT
eurjchem-2544	302	6	solvated	solvate	VERB
eurjchem-2544	302	7	tris-(morpholinocarbodithiato	tris-(morpholinocarbodithiato	NOUN
eurjchem-2544	302	8	)	)	PUNCT
eurjchem-2544	302	9	rhodium(iii	rhodium(iii	NOUN
eurjchem-2544	302	10	)	)	PUNCT
eurjchem-2544	302	11	(	(	PUNCT
eurjchem-2544	302	12	16	16	NUM
eurjchem-2544	302	13	,	,	PUNCT
eurjchem-2544	302	14	figure	figure	VERB
eurjchem-2544	302	15	11	11	NUM
eurjchem-2544	302	16	)	)	PUNCT
eurjchem-2544	302	17	that	that	PRON
eurjchem-2544	302	18	crystallizes	crystallize	VERB
eurjchem-2544	302	19	in	in	ADP
eurjchem-2544	302	20	the	the	DET
eurjchem-2544	302	21	p-1	p-1	NOUN
eurjchem-2544	302	22	space	space	NOUN
eurjchem-2544	302	23	group	group	NOUN
eurjchem-2544	302	24	of	of	ADP
eurjchem-2544	302	25	the	the	DET
eurjchem-2544	302	26	triclinic	triclinic	ADJ
eurjchem-2544	302	27	crystal	crystal	NOUN
eurjchem-2544	302	28	system	system	NOUN
eurjchem-2544	302	29	is	be	AUX
eurjchem-2544	302	30	isostructural	isostructural	ADJ
eurjchem-2544	302	31	with	with	ADP
eurjchem-2544	302	32	the	the	DET
eurjchem-2544	302	33	chromium(iii	chromium(iii	NOUN
eurjchem-2544	302	34	)	)	PUNCT
eurjchem-2544	302	35	and	and	CCONJ
eurjchem-2544	302	36	manganese(iii	manganese(iii	NOUN
eurjchem-2544	302	37	)	)	PUNCT
eurjchem-2544	302	38	congeners	congener	NOUN
eurjchem-2544	302	39	and	and	CCONJ
eurjchem-2544	302	40	isomorphous	isomorphous	NOUN
eurjchem-2544	302	41	with	with	ADP
eurjchem-2544	302	42	the	the	DET
eurjchem-2544	302	43	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	302	44	)	)	PUNCT
eurjchem-2544	302	45	analogue	analogue	NOUN
eurjchem-2544	303	1	[	[	X
eurjchem-2544	303	2	48	48	NUM
eurjchem-2544	303	3	]	]	PUNCT
eurjchem-2544	303	4	.	.	PUNCT
eurjchem-2544	304	1	its	its	PRON
eurjchem-2544	304	2	molecular	molecular	ADJ
eurjchem-2544	304	3	structure	structure	NOUN
eurjchem-2544	304	4	possesses	possess	VERB
eurjchem-2544	304	5	stereoscopic	stereoscopic	ADJ
eurjchem-2544	304	6	pairs	pair	NOUN
eurjchem-2544	304	7	in	in	ADP
eurjchem-2544	304	8	its	its	PRON
eurjchem-2544	304	9	molecular	molecular	ADJ
eurjchem-2544	304	10	packing	packing	NOUN
eurjchem-2544	304	11	in	in	ADP
eurjchem-2544	304	12	the	the	DET
eurjchem-2544	304	13	unit	unit	NOUN
eurjchem-2544	304	14	cell	cell	NOUN
eurjchem-2544	304	15	.	.	PUNCT
eurjchem-2544	305	1	these	these	DET
eurjchem-2544	305	2	peculiarities	peculiarity	NOUN
eurjchem-2544	305	3	are	be	AUX
eurjchem-2544	305	4	present	present	ADJ
eurjchem-2544	305	5	in	in	ADP
eurjchem-2544	305	6	the	the	DET
eurjchem-2544	305	7	mn(iii	mn(iii	NOUN
eurjchem-2544	305	8	)	)	PUNCT
eurjchem-2544	305	9	,	,	PUNCT
eurjchem-2544	305	10	cr(iii	cr(iii	PRON
eurjchem-2544	305	11	)	)	PUNCT
eurjchem-2544	305	12	,	,	PUNCT
eurjchem-2544	305	13	and	and	CCONJ
eurjchem-2544	305	14	co(iii	co(iii	NOUN
eurjchem-2544	305	15	)	)	PUNCT
eurjchem-2544	305	16	analogues	analogue	NOUN
eurjchem-2544	305	17	.	.	PUNCT
eurjchem-2544	306	1	each	each	DET
eurjchem-2544	306	2	molecule	molecule	NOUN
eurjchem-2544	306	3	of	of	ADP
eurjchem-2544	306	4	the	the	DET
eurjchem-2544	306	5	dichloromethane	dichloromethane	NOUN
eurjchem-2544	306	6	solvate	solvate	NOUN
eurjchem-2544	306	7	approaches	approach	VERB
eurjchem-2544	306	8	the	the	DET
eurjchem-2544	306	9	complex	complex	NOUN
eurjchem-2544	306	10	by	by	ADP
eurjchem-2544	306	11	inclusion	inclusion	NOUN
eurjchem-2544	306	12	.	.	PUNCT
eurjchem-2544	307	1	the	the	DET
eurjchem-2544	307	2	crystal	crystal	PROPN
eurjchem-2544	307	3	lattice	lattice	NOUN
eurjchem-2544	307	4	of	of	ADP
eurjchem-2544	307	5	complex	complex	ADJ
eurjchem-2544	307	6	16	16	NUM
eurjchem-2544	307	7	is	be	AUX
eurjchem-2544	307	8	made	make	VERB
eurjchem-2544	307	9	up	up	ADP
eurjchem-2544	307	10	of	of	ADP
eurjchem-2544	307	11	well	well	ADV
eurjchem-2544	307	12	-	-	PUNCT
eurjchem-2544	307	13	separated	separate	VERB
eurjchem-2544	307	14	metal	metal	NOUN
eurjchem-2544	307	15	complexes	complex	NOUN
eurjchem-2544	307	16	that	that	PRON
eurjchem-2544	307	17	have	have	VERB
eurjchem-2544	307	18	solvate	solvate	ADJ
eurjchem-2544	307	19	molecules	molecule	NOUN
eurjchem-2544	307	20	fitted	fit	VERB
eurjchem-2544	307	21	into	into	ADP
eurjchem-2544	307	22	crystallographic	crystallographic	ADJ
eurjchem-2544	307	23	holes	hole	NOUN
eurjchem-2544	307	24	.	.	PUNCT
eurjchem-2544	308	1	its	its	PRON
eurjchem-2544	308	2	ms6	ms6	NOUN
eurjchem-2544	308	3	coordination	coordination	NOUN
eurjchem-2544	308	4	core	core	NOUN
eurjchem-2544	308	5	is	be	AUX
eurjchem-2544	308	6	a	a	DET
eurjchem-2544	308	7	trigonally	trigonally	ADV
eurjchem-2544	308	8	distorted	distort	VERB
eurjchem-2544	308	9	octahedron	octahedron	NOUN
eurjchem-2544	308	10	with	with	ADP
eurjchem-2544	308	11	symmetrical	symmetrical	ADJ
eurjchem-2544	308	12	spherical	spherical	ADJ
eurjchem-2544	308	13	ground	ground	NOUN
eurjchem-2544	308	14	states	state	NOUN
eurjchem-2544	308	15	.	.	PUNCT
eurjchem-2544	309	1	the	the	DET
eurjchem-2544	309	2	mn(iii	mn(iii	NOUN
eurjchem-2544	309	3	)	)	PUNCT
eurjchem-2544	309	4	analogue	analogue	NOUN
eurjchem-2544	309	5	is	be	AUX
eurjchem-2544	309	6	an	an	DET
eurjchem-2544	309	7	exception	exception	NOUN
eurjchem-2544	309	8	in	in	ADP
eurjchem-2544	309	9	this	this	DET
eurjchem-2544	309	10	respect	respect	NOUN
eurjchem-2544	309	11	,	,	PUNCT
eurjchem-2544	309	12	with	with	ADP
eurjchem-2544	309	13	significant	significant	ADJ
eurjchem-2544	309	14	deviations	deviation	NOUN
eurjchem-2544	309	15	from	from	ADP
eurjchem-2544	309	16	the	the	DET
eurjchem-2544	309	17	ms6	ms6	NOUN
eurjchem-2544	309	18	model	model	NOUN
eurjchem-2544	309	19	with	with	ADP
eurjchem-2544	309	20	uneven	uneven	PROPN
eurjchem-2544	309	21	mn	mn	PROPN
eurjchem-2544	309	22	-	-	PUNCT
eurjchem-2544	309	23	s	s	PART
eurjchem-2544	309	24	bond	bond	NOUN
eurjchem-2544	309	25	distances	distance	NOUN
eurjchem-2544	309	26	that	that	PRON
eurjchem-2544	309	27	are	be	AUX
eurjchem-2544	309	28	attributed	attribute	VERB
eurjchem-2544	309	29	to	to	ADP
eurjchem-2544	309	30	jahn	jahn	NOUN
eurjchem-2544	309	31	-	-	PUNCT
eurjchem-2544	309	32	teller	teller	NOUN
eurjchem-2544	309	33	-	-	PUNCT
eurjchem-2544	309	34	driven	drive	VERB
eurjchem-2544	309	35	tetragonal	tetragonal	ADJ
eurjchem-2544	309	36	distortion	distortion	NOUN
eurjchem-2544	309	37	.	.	PUNCT
eurjchem-2544	310	1	typically	typically	ADV
eurjchem-2544	310	2	,	,	PUNCT
eurjchem-2544	310	3	the	the	DET
eurjchem-2544	310	4	mean	mean	ADJ
eurjchem-2544	310	5	m	m	NOUN
eurjchem-2544	310	6	-	-	PUNCT
eurjchem-2544	310	7	s	s	PART
eurjchem-2544	310	8	bond	bond	NOUN
eurjchem-2544	310	9	distances	distance	NOUN
eurjchem-2544	310	10	increase	increase	VERB
eurjchem-2544	310	11	down	down	ADP
eurjchem-2544	310	12	the	the	DET
eurjchem-2544	310	13	group	group	NOUN
eurjchem-2544	310	14	for	for	ADP
eurjchem-2544	310	15	co	co	PROPN
eurjchem-2544	310	16	and	and	CCONJ
eurjchem-2544	310	17	rh	rh	PROPN
eurjchem-2544	310	18	metals	metal	NOUN
eurjchem-2544	310	19	with	with	ADP
eurjchem-2544	310	20	d⁶	d⁶	NOUN
eurjchem-2544	310	21	configuration	configuration	NOUN
eurjchem-2544	310	22	;	;	PUNCT
eurjchem-2544	310	23	co	co	VERB
eurjchem-2544	310	24	-	-	NOUN
eurjchem-2544	310	25	s	s	X
eurjchem-2544	310	26	=	=	SYM
eurjchem-2544	310	27	2.275	2.275	NUM
eurjchem-2544	310	28	å	å	X
eurjchem-2544	310	29	and	and	CCONJ
eurjchem-2544	310	30	rh	rh	PROPN
eurjchem-2544	310	31	-	-	PUNCT
eurjchem-2544	310	32	s	s	PART
eurjchem-2544	310	33	=	=	PUNCT
eurjchem-2544	310	34	2.369	2.369	NUM
eurjchem-2544	310	35	å	å	NOUN
eurjchem-2544	310	36	.	.	PUNCT
eurjchem-2544	311	1	furthermore	furthermore	ADV
eurjchem-2544	311	2	,	,	PUNCT
eurjchem-2544	311	3	there	there	PRON
eurjchem-2544	311	4	is	be	VERB
eurjchem-2544	311	5	an	an	DET
eurjchem-2544	311	6	increase	increase	NOUN
eurjchem-2544	311	7	in	in	ADP
eurjchem-2544	311	8	the	the	DET
eurjchem-2544	311	9	m	m	PROPN
eurjchem-2544	311	10	-	-	PUNCT
eurjchem-2544	311	11	s	s	NOUN
eurjchem-2544	311	12	distances	distance	NOUN
eurjchem-2544	311	13	of	of	ADP
eurjchem-2544	311	14	cr	cr	PROPN
eurjchem-2544	311	15	,	,	PUNCT
eurjchem-2544	311	16	mn	mn	PROPN
eurjchem-2544	311	17	,	,	PUNCT
eurjchem-2544	311	18	and	and	CCONJ
eurjchem-2544	311	19	fe	fe	NOUN
eurjchem-2544	311	20	as	as	ADP
eurjchem-2544	311	21	the	the	DET
eurjchem-2544	311	22	unpaired	unpaired	ADJ
eurjchem-2544	311	23	electron	electron	NOUN
eurjchem-2544	311	24	occupancy	occupancy	NOUN
eurjchem-2544	311	25	in	in	ADP
eurjchem-2544	311	26	the	the	DET
eurjchem-2544	311	27	d	d	ADJ
eurjchem-2544	311	28	-	-	ADJ
eurjchem-2544	311	29	shell	shell	ADJ
eurjchem-2544	311	30	increases	increase	NOUN
eurjchem-2544	311	31	;	;	PUNCT
eurjchem-2544	311	32	cr	cr	X
eurjchem-2544	311	33	-	-	PUNCT
eurjchem-2544	311	34	s	s	X
eurjchem-2544	311	35	(	(	PUNCT
eurjchem-2544	311	36	d³	d³	PROPN
eurjchem-2544	311	37	)	)	PUNCT
eurjchem-2544	311	38	=	=	NUM
eurjchem-2544	311	39	2.406	2.406	NUM
eurjchem-2544	311	40	å	å	PROPN
eurjchem-2544	311	41	,	,	PUNCT
eurjchem-2544	311	42	mn	mn	PROPN
eurjchem-2544	311	43	-	-	PUNCT
eurjchem-2544	311	44	s	s	X
eurjchem-2544	311	45	(	(	PUNCT
eurjchem-2544	311	46	d⁴	d⁴	NOUN
eurjchem-2544	311	47	)	)	PUNCT
eurjchem-2544	311	48	=	=	PUNCT
eurjchem-2544	311	49	2.461	2.461	NUM
eurjchem-2544	311	50	å	å	PROPN
eurjchem-2544	311	51	and	and	CCONJ
eurjchem-2544	311	52	fe	fe	PROPN
eurjchem-2544	311	53	-	-	PUNCT
eurjchem-2544	311	54	s	s	X
eurjchem-2544	311	55	(	(	PUNCT
eurjchem-2544	311	56	d⁵	d⁵	PROPN
eurjchem-2544	311	57	)	)	PUNCT
eurjchem-2544	311	58	=	=	PUNCT
eurjchem-2544	311	59	2.430	2.430	NUM
eurjchem-2544	311	60	å	å	NOUN
eurjchem-2544	311	61	.	.	PUNCT
eurjchem-2544	312	1	the	the	DET
eurjchem-2544	312	2	"	"	PUNCT
eurjchem-2544	312	3	bite	bite	NOUN
eurjchem-2544	312	4	"	"	PUNCT
eurjchem-2544	312	5	angle	angle	NOUN
eurjchem-2544	312	6	s	s	PROPN
eurjchem-2544	312	7	-	-	PUNCT
eurjchem-2544	312	8	m	m	NOUN
eurjchem-2544	312	9	-	-	PUNCT
eurjchem-2544	312	10	s	s	NOUN
eurjchem-2544	312	11	of	of	ADP
eurjchem-2544	312	12	the	the	DET
eurjchem-2544	312	13	ligand	ligand	NOUN
eurjchem-2544	312	14	shares	share	VERB
eurjchem-2544	312	15	a	a	DET
eurjchem-2544	312	16	strong	strong	ADJ
eurjchem-2544	312	17	correlation	correlation	NOUN
eurjchem-2544	312	18	with	with	ADP
eurjchem-2544	312	19	the	the	DET
eurjchem-2544	312	20	m	m	PROPN
eurjchem-2544	312	21	-	-	PUNCT
eurjchem-2544	312	22	s	s	PART
eurjchem-2544	312	23	bond	bond	NOUN
eurjchem-2544	312	24	distances	distance	NOUN
eurjchem-2544	312	25	independent	independent	ADJ
eurjchem-2544	312	26	of	of	ADP
eurjchem-2544	312	27	factors	factor	NOUN
eurjchem-2544	312	28	such	such	ADJ
eurjchem-2544	312	29	as	as	ADP
eurjchem-2544	312	30	trigonal	trigonal	ADJ
eurjchem-2544	312	31	distortion	distortion	NOUN
eurjchem-2544	312	32	,	,	PUNCT
eurjchem-2544	312	33	tetragonal	tetragonal	ADJ
eurjchem-2544	312	34	distortion	distortion	NOUN
eurjchem-2544	312	35	,	,	PUNCT
eurjchem-2544	312	36	or	or	CCONJ
eurjchem-2544	312	37	packing	pack	VERB
eurjchem-2544	312	38	effects	effect	NOUN
eurjchem-2544	312	39	[	[	X
eurjchem-2544	312	40	49	49	NUM
eurjchem-2544	312	41	]	]	PUNCT
eurjchem-2544	312	42	.	.	PUNCT
eurjchem-2544	313	1	its	its	PRON
eurjchem-2544	313	2	crystal	crystal	NOUN
eurjchem-2544	313	3	lattice	lattice	PROPN
eurjchem-2544	313	4	hosts	host	NOUN
eurjchem-2544	313	5	short	short	ADJ
eurjchem-2544	313	6	h···cl	h···cl	NOUN
eurjchem-2544	313	7	,	,	PUNCT
eurjchem-2544	313	8	h···s	h···	NOUN
eurjchem-2544	313	9	,	,	PUNCT
eurjchem-2544	313	10	and	and	CCONJ
eurjchem-2544	313	11	h···o	h···o	PROPN
eurjchem-2544	313	12	intermolecular	intermolecular	ADJ
eurjchem-2544	313	13	hydrogen	hydrogen	NOUN
eurjchem-2544	313	14	bond	bond	NOUN
eurjchem-2544	313	15	interactions	interaction	NOUN
eurjchem-2544	313	16	.	.	PUNCT
eurjchem-2544	314	1	shotonwa	shotonwa	PROPN
eurjchem-2544	314	2	et	et	PROPN
eurjchem-2544	314	3	al	al	PROPN
eurjchem-2544	314	4	.	.	PUNCT
eurjchem-2544	314	5	/	/	SYM
eurjchem-2544	314	6	european	european	PROPN
eurjchem-2544	314	7	journal	journal	PROPN
eurjchem-2544	314	8	of	of	ADP
eurjchem-2544	314	9	chemistry	chemistry	NOUN
eurjchem-2544	314	10	15	15	NUM
eurjchem-2544	314	11	(	(	PUNCT
eurjchem-2544	314	12	3	3	NUM
eurjchem-2544	314	13	)	)	PUNCT
eurjchem-2544	314	14	(	(	PUNCT
eurjchem-2544	314	15	2024	2024	NUM
eurjchem-2544	314	16	)	)	PUNCT
eurjchem-2544	314	17	291	291	NUM
eurjchem-2544	314	18	-	-	SYM
eurjchem-2544	314	19	301	301	NUM
eurjchem-2544	314	20	299	299	NUM
eurjchem-2544	314	21	2024	2024	NUM
eurjchem-2544	314	22	–	–	PUNCT
eurjchem-2544	314	23	european	european	ADJ
eurjchem-2544	314	24	journal	journal	NOUN
eurjchem-2544	314	25	of	of	ADP
eurjchem-2544	314	26	chemistry	chemistry	NOUN
eurjchem-2544	314	27	–	–	PUNCT
eurjchem-2544	314	28	cc	cc	NOUN
eurjchem-2544	314	29	by	by	ADP
eurjchem-2544	314	30	nc	nc	PROPN
eurjchem-2544	314	31	–	–	PUNCT
eurjchem-2544	314	32	doi	doi	PROPN
eurjchem-2544	314	33	:	:	PUNCT
eurjchem-2544	314	34	10.5155	10.5155	NUM
eurjchem-2544	314	35	/	/	SYM
eurjchem-2544	314	36	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	314	37	-	-	PUNCT
eurjchem-2544	314	38	301.2544	301.2544	NUM
eurjchem-2544	314	39	figure	figure	NOUN
eurjchem-2544	314	40	11	11	NUM
eurjchem-2544	314	41	.	.	PUNCT
eurjchem-2544	315	1	molecular	molecular	ADJ
eurjchem-2544	315	2	structure	structure	NOUN
eurjchem-2544	315	3	of	of	ADP
eurjchem-2544	315	4	complexes	complex	NOUN
eurjchem-2544	315	5	16	16	NUM
eurjchem-2544	315	6	-	-	SYM
eurjchem-2544	315	7	18	18	NUM
eurjchem-2544	315	8	.	.	PUNCT
eurjchem-2544	315	9	figure	figure	NOUN
eurjchem-2544	315	10	12	12	NUM
eurjchem-2544	315	11	.	.	PUNCT
eurjchem-2544	316	1	the	the	DET
eurjchem-2544	316	2	irs6	irs6	PROPN
eurjchem-2544	316	3	coordination	coordination	NOUN
eurjchem-2544	316	4	polyhedron	polyhedron	NOUN
eurjchem-2544	316	5	as	as	SCONJ
eurjchem-2544	316	6	projected	project	VERB
eurjchem-2544	316	7	on	on	ADP
eurjchem-2544	316	8	a	a	DET
eurjchem-2544	316	9	3	3	NUM
eurjchem-2544	316	10	-	-	ADJ
eurjchem-2544	316	11	fold	fold	ADJ
eurjchem-2544	316	12	axis	axis	NOUN
eurjchem-2544	316	13	[	[	X
eurjchem-2544	316	14	52	52	NUM
eurjchem-2544	316	15	]	]	PUNCT
eurjchem-2544	316	16	.	.	PUNCT
eurjchem-2544	317	1	tris(diethyldithiocarbamato)rhodium(iii	tris(diethyldithiocarbamato)rhodium(iii	PROPN
eurjchem-2544	317	2	)	)	PUNCT
eurjchem-2544	317	3	(	(	PUNCT
eurjchem-2544	317	4	17	17	NUM
eurjchem-2544	317	5	,	,	PUNCT
eurjchem-2544	317	6	figure	figure	NOUN
eurjchem-2544	317	7	11	11	NUM
eurjchem-2544	317	8	)	)	PUNCT
eurjchem-2544	317	9	crystallizes	crystallize	NOUN
eurjchem-2544	317	10	in	in	ADP
eurjchem-2544	317	11	the	the	DET
eurjchem-2544	317	12	monoclinic	monoclinic	ADJ
eurjchem-2544	317	13	p21	p21	NOUN
eurjchem-2544	317	14	/	/	SYM
eurjchem-2544	317	15	a	a	DET
eurjchem-2544	317	16	space	space	NOUN
eurjchem-2544	317	17	group	group	NOUN
eurjchem-2544	317	18	with	with	ADP
eurjchem-2544	317	19	z	z	PROPN
eurjchem-2544	318	1	=	=	SYM
eurjchem-2544	318	2	4	4	NUM
eurjchem-2544	318	3	in	in	ADP
eurjchem-2544	318	4	the	the	DET
eurjchem-2544	318	5	unit	unit	NOUN
eurjchem-2544	318	6	cell	cell	NOUN
eurjchem-2544	318	7	.	.	PUNCT
eurjchem-2544	319	1	its	its	PRON
eurjchem-2544	319	2	unit	unit	NOUN
eurjchem-2544	319	3	cell	cell	NOUN
eurjchem-2544	319	4	dimensions	dimension	NOUN
eurjchem-2544	319	5	are	be	AUX
eurjchem-2544	319	6	similar	similar	ADJ
eurjchem-2544	319	7	to	to	ADP
eurjchem-2544	319	8	those	those	PRON
eurjchem-2544	319	9	reported	report	VERB
eurjchem-2544	319	10	for	for	ADP
eurjchem-2544	319	11	mn	mn	PROPN
eurjchem-2544	319	12	and	and	CCONJ
eurjchem-2544	319	13	as	as	ADP
eurjchem-2544	319	14	derivatives	derivative	NOUN
eurjchem-2544	319	15	.	.	PUNCT
eurjchem-2544	320	1	the	the	DET
eurjchem-2544	320	2	solved	solve	VERB
eurjchem-2544	320	3	structure	structure	NOUN
eurjchem-2544	320	4	of	of	ADP
eurjchem-2544	320	5	compound	compound	NOUN
eurjchem-2544	320	6	17	17	NUM
eurjchem-2544	320	7	did	do	AUX
eurjchem-2544	320	8	not	not	PART
eurjchem-2544	320	9	show	show	VERB
eurjchem-2544	320	10	distortion	distortion	NOUN
eurjchem-2544	320	11	of	of	ADP
eurjchem-2544	320	12	the	the	DET
eurjchem-2544	320	13	rhs6	rhs6	NOUN
eurjchem-2544	320	14	core	core	NOUN
eurjchem-2544	320	15	,	,	PUNCT
eurjchem-2544	320	16	while	while	SCONJ
eurjchem-2544	320	17	the	the	DET
eurjchem-2544	320	18	as	as	ADP
eurjchem-2544	320	19	and	and	CCONJ
eurjchem-2544	320	20	mn	mn	PROPN
eurjchem-2544	320	21	derivatives	derivative	NOUN
eurjchem-2544	320	22	showed	show	VERB
eurjchem-2544	320	23	varying	vary	VERB
eurjchem-2544	320	24	large	large	ADJ
eurjchem-2544	320	25	distortions	distortion	NOUN
eurjchem-2544	320	26	about	about	ADP
eurjchem-2544	320	27	their	their	PRON
eurjchem-2544	320	28	ms6	ms6	NOUN
eurjchem-2544	320	29	cores	core	NOUN
eurjchem-2544	320	30	.	.	PUNCT
eurjchem-2544	321	1	interestingly	interestingly	ADV
eurjchem-2544	321	2	,	,	PUNCT
eurjchem-2544	321	3	[	[	X
eurjchem-2544	321	4	rh(cs2net2)3	rh(cs2net2)3	X
eurjchem-2544	321	5	]	]	X
eurjchem-2544	321	6	and	and	CCONJ
eurjchem-2544	321	7	[	[	AUX
eurjchem-2544	321	8	as(cs2net2)3	as(cs2net2)3	X
eurjchem-2544	321	9	]	]	X
eurjchem-2544	321	10	have	have	AUX
eurjchem-2544	321	11	previously	previously	ADV
eurjchem-2544	321	12	been	be	AUX
eurjchem-2544	321	13	determined	determine	VERB
eurjchem-2544	321	14	[	[	PUNCT
eurjchem-2544	321	15	50	50	NUM
eurjchem-2544	321	16	]	]	PUNCT
eurjchem-2544	321	17	.	.	PUNCT
eurjchem-2544	322	1	its	its	PRON
eurjchem-2544	322	2	lattices	lattice	NOUN
eurjchem-2544	322	3	contain	contain	VERB
eurjchem-2544	322	4	discrete	discrete	ADJ
eurjchem-2544	322	5	molecules	molecule	NOUN
eurjchem-2544	322	6	of	of	ADP
eurjchem-2544	322	7	[	[	X
eurjchem-2544	322	8	rh(cs2net2)3	rh(cs2net2)3	X
eurjchem-2544	322	9	]	]	X
eurjchem-2544	322	10	.	.	PUNCT
eurjchem-2544	323	1	despite	despite	SCONJ
eurjchem-2544	323	2	being	be	AUX
eurjchem-2544	323	3	isomorphous	isomorphous	ADJ
eurjchem-2544	323	4	with	with	ADP
eurjchem-2544	323	5	the	the	DET
eurjchem-2544	323	6	as(iii	as(iii	NOUN
eurjchem-2544	323	7	)	)	PUNCT
eurjchem-2544	323	8	and	and	CCONJ
eurjchem-2544	323	9	mn(iii	mn(iii	NOUN
eurjchem-2544	323	10	)	)	PUNCT
eurjchem-2544	323	11	analogues	analogue	NOUN
eurjchem-2544	323	12	,	,	PUNCT
eurjchem-2544	323	13	they	they	PRON
eurjchem-2544	323	14	are	be	AUX
eurjchem-2544	323	15	still	still	ADV
eurjchem-2544	323	16	quite	quite	ADV
eurjchem-2544	323	17	different	different	ADJ
eurjchem-2544	323	18	geometrically	geometrically	ADV
eurjchem-2544	323	19	and	and	CCONJ
eurjchem-2544	323	20	from	from	ADP
eurjchem-2544	323	21	the	the	DET
eurjchem-2544	323	22	perspective	perspective	NOUN
eurjchem-2544	323	23	of	of	ADP
eurjchem-2544	323	24	their	their	PRON
eurjchem-2544	323	25	crystal	crystal	NOUN
eurjchem-2544	323	26	packing	packing	NOUN
eurjchem-2544	323	27	.	.	PUNCT
eurjchem-2544	324	1	the	the	DET
eurjchem-2544	324	2	rh	rh	PROPN
eurjchem-2544	324	3	atom	atom	NOUN
eurjchem-2544	324	4	is	be	AUX
eurjchem-2544	324	5	distortedly	distortedly	ADV
eurjchem-2544	324	6	hexacoordinated	hexacoordinate	VERB
eurjchem-2544	324	7	to	to	ADP
eurjchem-2544	324	8	three	three	NUM
eurjchem-2544	324	9	quasibidentate	quasibidentate	NOUN
eurjchem-2544	324	10	ligands	ligand	NOUN
eurjchem-2544	324	11	whose	whose	DET
eurjchem-2544	324	12	s2cnc2	s2cnc2	ADJ
eurjchem-2544	324	13	fragments	fragment	NOUN
eurjchem-2544	324	14	are	be	AUX
eurjchem-2544	324	15	planar	planar	ADJ
eurjchem-2544	324	16	and	and	CCONJ
eurjchem-2544	324	17	lie	lie	VERB
eurjchem-2544	324	18	parallel	parallel	ADJ
eurjchem-2544	324	19	to	to	ADP
eurjchem-2544	324	20	the	the	DET
eurjchem-2544	324	21	faces	face	NOUN
eurjchem-2544	324	22	of	of	ADP
eurjchem-2544	324	23	the	the	DET
eurjchem-2544	324	24	unit	unit	NOUN
eurjchem-2544	324	25	cell	cell	NOUN
eurjchem-2544	324	26	.	.	PUNCT
eurjchem-2544	325	1	complex	complex	ADJ
eurjchem-2544	325	2	17	17	NUM
eurjchem-2544	325	3	is	be	AUX
eurjchem-2544	325	4	different	different	ADJ
eurjchem-2544	325	5	from	from	ADP
eurjchem-2544	325	6	other	other	ADJ
eurjchem-2544	325	7	[	[	X
eurjchem-2544	325	8	m(dtc)3	m(dtc)3	X
eurjchem-2544	325	9	]	]	X
eurjchem-2544	325	10	systems	system	NOUN
eurjchem-2544	325	11	whose	whose	DET
eurjchem-2544	325	12	overall	overall	ADJ
eurjchem-2544	325	13	molecular	molecular	ADJ
eurjchem-2544	325	14	symmetries	symmetry	NOUN
eurjchem-2544	325	15	align	align	VERB
eurjchem-2544	325	16	well	well	ADV
eurjchem-2544	325	17	with	with	ADP
eurjchem-2544	325	18	the	the	DET
eurjchem-2544	325	19	d3	d3	PROPN
eurjchem-2544	325	20	approximation	approximation	NOUN
eurjchem-2544	325	21	.	.	PUNCT
eurjchem-2544	326	1	the	the	DET
eurjchem-2544	326	2	terminal	terminal	ADJ
eurjchem-2544	326	3	methyl	methyl	NOUN
eurjchem-2544	326	4	groups	group	NOUN
eurjchem-2544	326	5	on	on	ADP
eurjchem-2544	326	6	the	the	DET
eurjchem-2544	326	7	ligand	ligand	NOUN
eurjchem-2544	326	8	lie	lie	NOUN
eurjchem-2544	326	9	on	on	ADP
eurjchem-2544	326	10	alternate	alternate	ADJ
eurjchem-2544	326	11	sides	side	NOUN
eurjchem-2544	326	12	of	of	ADP
eurjchem-2544	326	13	the	the	DET
eurjchem-2544	326	14	ligand	ligand	ADJ
eurjchem-2544	326	15	plane	plane	NOUN
eurjchem-2544	326	16	without	without	ADP
eurjchem-2544	326	17	symmetry	symmetry	NOUN
eurjchem-2544	326	18	.	.	PUNCT
eurjchem-2544	327	1	two	two	NUM
eurjchem-2544	327	2	ligands	ligand	NOUN
eurjchem-2544	327	3	give	give	VERB
eurjchem-2544	327	4	the	the	DET
eurjchem-2544	327	5	bladed	bladed	ADJ
eurjchem-2544	327	6	propeller	propeller	NOUN
eurjchem-2544	327	7	configuration	configuration	NOUN
eurjchem-2544	327	8	,	,	PUNCT
eurjchem-2544	327	9	whereas	whereas	SCONJ
eurjchem-2544	327	10	the	the	DET
eurjchem-2544	327	11	third	third	ADJ
eurjchem-2544	327	12	ligand	ligand	NOUN
eurjchem-2544	327	13	is	be	AUX
eurjchem-2544	327	14	the	the	DET
eurjchem-2544	327	15	mirror	mirror	NOUN
eurjchem-2544	327	16	image	image	NOUN
eurjchem-2544	327	17	of	of	ADP
eurjchem-2544	327	18	the	the	DET
eurjchem-2544	327	19	configuration	configuration	NOUN
eurjchem-2544	327	20	.	.	PUNCT
eurjchem-2544	328	1	the	the	DET
eurjchem-2544	328	2	flexibility	flexibility	NOUN
eurjchem-2544	328	3	of	of	ADP
eurjchem-2544	328	4	the	the	DET
eurjchem-2544	328	5	solid	solid	ADJ
eurjchem-2544	328	6	-	-	PUNCT
eurjchem-2544	328	7	state	state	NOUN
eurjchem-2544	328	8	packing	packing	NOUN
eurjchem-2544	328	9	effect	effect	NOUN
eurjchem-2544	328	10	is	be	AUX
eurjchem-2544	328	11	reflected	reflect	VERB
eurjchem-2544	328	12	in	in	ADP
eurjchem-2544	328	13	the	the	DET
eurjchem-2544	328	14	strong	strong	ADJ
eurjchem-2544	328	15	possibility	possibility	NOUN
eurjchem-2544	328	16	of	of	ADP
eurjchem-2544	328	17	free	free	ADJ
eurjchem-2544	328	18	rotation	rotation	NOUN
eurjchem-2544	328	19	about	about	ADP
eurjchem-2544	328	20	the	the	DET
eurjchem-2544	328	21	ethyl	ethyl	NOUN
eurjchem-2544	328	22	-	-	PUNCT
eurjchem-2544	328	23	nitrogen	nitrogen	NOUN
eurjchem-2544	328	24	bonds	bond	NOUN
eurjchem-2544	328	25	.	.	PUNCT
eurjchem-2544	329	1	there	there	PRON
eurjchem-2544	329	2	is	be	VERB
eurjchem-2544	329	3	also	also	ADV
eurjchem-2544	329	4	a	a	DET
eurjchem-2544	329	5	crystal	crystal	NOUN
eurjchem-2544	329	6	-	-	PUNCT
eurjchem-2544	329	7	clear	clear	ADJ
eurjchem-2544	329	8	distortion	distortion	NOUN
eurjchem-2544	329	9	from	from	ADP
eurjchem-2544	329	10	the	the	DET
eurjchem-2544	329	11	ideal	ideal	PROPN
eurjchem-2544	329	12	d3	d3	PROPN
eurjchem-2544	329	13	symmetry	symmetry	NOUN
eurjchem-2544	329	14	as	as	SCONJ
eurjchem-2544	329	15	revealed	reveal	VERB
eurjchem-2544	329	16	by	by	ADP
eurjchem-2544	329	17	the	the	DET
eurjchem-2544	329	18	asymmetrical	asymmetrical	ADJ
eurjchem-2544	329	19	rh	rh	PROPN
eurjchem-2544	329	20	-	-	PUNCT
eurjchem-2544	329	21	s	s	NOUN
eurjchem-2544	329	22	bond	bond	NOUN
eurjchem-2544	329	23	distances	distance	NOUN
eurjchem-2544	329	24	and	and	CCONJ
eurjchem-2544	329	25	ligand	ligand	NOUN
eurjchem-2544	329	26	bite	bite	NOUN
eurjchem-2544	329	27	angles	angle	NOUN
eurjchem-2544	329	28	around	around	ADP
eurjchem-2544	329	29	the	the	DET
eurjchem-2544	329	30	rh	rh	PROPN
eurjchem-2544	329	31	centre	centre	NOUN
eurjchem-2544	329	32	;	;	PUNCT
eurjchem-2544	329	33	although	although	SCONJ
eurjchem-2544	329	34	the	the	DET
eurjchem-2544	329	35	rh	rh	PROPN
eurjchem-2544	329	36	-	-	PUNCT
eurjchem-2544	329	37	s	s	PART
eurjchem-2544	329	38	distances	distance	NOUN
eurjchem-2544	329	39	do	do	AUX
eurjchem-2544	329	40	not	not	PART
eurjchem-2544	329	41	deviate	deviate	VERB
eurjchem-2544	329	42	from	from	ADP
eurjchem-2544	329	43	the	the	DET
eurjchem-2544	329	44	mean	mean	ADJ
eurjchem-2544	329	45	value	value	NOUN
eurjchem-2544	329	46	of	of	ADP
eurjchem-2544	329	47	2.36(8	2.36(8	NUM
eurjchem-2544	329	48	)	)	PUNCT
eurjchem-2544	329	49	å	å	NOUN
eurjchem-2544	329	50	.	.	PUNCT
eurjchem-2544	329	51	table	table	NOUN
eurjchem-2544	329	52	3	3	NUM
eurjchem-2544	329	53	shows	show	VERB
eurjchem-2544	329	54	the	the	DET
eurjchem-2544	329	55	selected	select	VERB
eurjchem-2544	329	56	bond	bond	NOUN
eurjchem-2544	329	57	distances	distance	NOUN
eurjchem-2544	329	58	,	,	PUNCT
eurjchem-2544	329	59	angles	angle	NOUN
eurjchem-2544	329	60	,	,	PUNCT
eurjchem-2544	329	61	and	and	CCONJ
eurjchem-2544	329	62	solvent	solvent	NOUN
eurjchem-2544	329	63	for	for	ADP
eurjchem-2544	329	64	crystal	crystal	NOUN
eurjchem-2544	329	65	growth	growth	NOUN
eurjchem-2544	329	66	in	in	ADP
eurjchem-2544	329	67	complexes	complex	NOUN
eurjchem-2544	329	68	16	16	NUM
eurjchem-2544	329	69	and	and	CCONJ
eurjchem-2544	329	70	17	17	NUM
eurjchem-2544	329	71	.	.	PUNCT
eurjchem-2544	330	1	it	it	PRON
eurjchem-2544	330	2	shows	show	VERB
eurjchem-2544	330	3	the	the	DET
eurjchem-2544	330	4	changes	change	NOUN
eurjchem-2544	330	5	in	in	ADP
eurjchem-2544	330	6	bond	bond	NOUN
eurjchem-2544	330	7	angles	angle	NOUN
eurjchem-2544	330	8	and	and	CCONJ
eurjchem-2544	330	9	distance	distance	NOUN
eurjchem-2544	330	10	as	as	SCONJ
eurjchem-2544	330	11	the	the	DET
eurjchem-2544	330	12	r	r	NOUN
eurjchem-2544	330	13	substituents	substituent	NOUN
eurjchem-2544	330	14	in	in	ADP
eurjchem-2544	330	15	the	the	DET
eurjchem-2544	330	16	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	330	17	backbones	backbone	NOUN
eurjchem-2544	330	18	are	be	AUX
eurjchem-2544	330	19	changed	change	VERB
eurjchem-2544	330	20	or	or	CCONJ
eurjchem-2544	330	21	modified	modify	VERB
eurjchem-2544	330	22	.	.	PUNCT
eurjchem-2544	331	1	unfortunately	unfortunately	ADV
eurjchem-2544	331	2	,	,	PUNCT
eurjchem-2544	331	3	hydrogen	hydrogen	NOUN
eurjchem-2544	331	4	atoms	atom	NOUN
eurjchem-2544	331	5	were	be	AUX
eurjchem-2544	331	6	missing	miss	VERB
eurjchem-2544	331	7	from	from	ADP
eurjchem-2544	331	8	the	the	DET
eurjchem-2544	331	9	refinement	refinement	NOUN
eurjchem-2544	331	10	of	of	ADP
eurjchem-2544	331	11	the	the	DET
eurjchem-2544	331	12	crystal	crystal	NOUN
eurjchem-2544	331	13	structure	structure	NOUN
eurjchem-2544	331	14	of	of	ADP
eurjchem-2544	331	15	complex	complex	ADJ
eurjchem-2544	331	16	17	17	NUM
eurjchem-2544	331	17	.	.	PUNCT
eurjchem-2544	332	1	hence	hence	ADV
eurjchem-2544	332	2	,	,	PUNCT
eurjchem-2544	332	3	its	its	PRON
eurjchem-2544	332	4	lattice	lattice	NOUN
eurjchem-2544	332	5	lacks	lack	VERB
eurjchem-2544	332	6	intramolecular	intramolecular	ADJ
eurjchem-2544	332	7	and	and	CCONJ
eurjchem-2544	332	8	intermolecular	intermolecular	ADJ
eurjchem-2544	332	9	short	short	ADJ
eurjchem-2544	332	10	contacts	contact	NOUN
eurjchem-2544	332	11	and	and	CCONJ
eurjchem-2544	332	12	hydrogenbond	hydrogenbond	ADJ
eurjchem-2544	332	13	interactions	interaction	NOUN
eurjchem-2544	332	14	.	.	PUNCT
eurjchem-2544	333	1	interestingly	interestingly	ADV
eurjchem-2544	333	2	,	,	PUNCT
eurjchem-2544	333	3	the	the	DET
eurjchem-2544	333	4	redetermined	redetermined	ADJ
eurjchem-2544	333	5	polymorph	polymorph	NOUN
eurjchem-2544	333	6	(	(	PUNCT
eurjchem-2544	333	7	refcode	refcode	PROPN
eurjchem-2544	333	8	:	:	PUNCT
eurjchem-2544	333	9	tedcrh01	tedcrh01	NOUN
eurjchem-2544	333	10	)	)	PUNCT
eurjchem-2544	334	1	[	[	X
eurjchem-2544	334	2	51	51	NUM
eurjchem-2544	334	3	]	]	PUNCT
eurjchem-2544	334	4	of	of	ADP
eurjchem-2544	334	5	complex	complex	ADJ
eurjchem-2544	334	6	17	17	NUM
eurjchem-2544	334	7	was	be	AUX
eurjchem-2544	334	8	reported	report	VERB
eurjchem-2544	334	9	almost	almost	ADV
eurjchem-2544	334	10	24	24	NUM
eurjchem-2544	334	11	years	year	NOUN
eurjchem-2544	334	12	later	later	ADV
eurjchem-2544	334	13	as	as	ADP
eurjchem-2544	334	14	a	a	DET
eurjchem-2544	334	15	crystal	crystal	NOUN
eurjchem-2544	334	16	in	in	ADP
eurjchem-2544	334	17	the	the	DET
eurjchem-2544	334	18	space	space	NOUN
eurjchem-2544	334	19	group	group	NOUN
eurjchem-2544	334	20	c2	c2	PROPN
eurjchem-2544	334	21	/	/	SYM
eurjchem-2544	334	22	c.	c.	PROPN
eurjchem-2544	334	23	a	a	DET
eurjchem-2544	334	24	comparison	comparison	NOUN
eurjchem-2544	334	25	of	of	ADP
eurjchem-2544	334	26	its	its	PRON
eurjchem-2544	334	27	molecular	molecular	ADJ
eurjchem-2544	334	28	structure	structure	NOUN
eurjchem-2544	334	29	with	with	ADP
eurjchem-2544	334	30	that	that	PRON
eurjchem-2544	334	31	of	of	ADP
eurjchem-2544	334	32	complex	complex	ADJ
eurjchem-2544	334	33	17	17	NUM
eurjchem-2544	334	34	revealed	reveal	VERB
eurjchem-2544	334	35	some	some	DET
eurjchem-2544	334	36	fascinating	fascinating	ADJ
eurjchem-2544	334	37	trends	trend	NOUN
eurjchem-2544	334	38	.	.	PUNCT
eurjchem-2544	335	1	for	for	ADP
eurjchem-2544	335	2	example	example	NOUN
eurjchem-2544	335	3	,	,	PUNCT
eurjchem-2544	335	4	the	the	DET
eurjchem-2544	335	5	distances	distance	NOUN
eurjchem-2544	335	6	of	of	ADP
eurjchem-2544	335	7	the	the	DET
eurjchem-2544	335	8	rh	rh	PROPN
eurjchem-2544	335	9	-	-	PUNCT
eurjchem-2544	335	10	s	s	PROPN
eurjchem-2544	335	11	bonds	bond	NOUN
eurjchem-2544	335	12	of	of	ADP
eurjchem-2544	335	13	2.351	2.351	NUM
eurjchem-2544	335	14	and	and	CCONJ
eurjchem-2544	335	15	2.353	2.353	NUM
eurjchem-2544	335	16	å	å	PROPN
eurjchem-2544	335	17	reveal	reveal	VERB
eurjchem-2544	335	18	the	the	DET
eurjchem-2544	335	19	symmetrical	symmetrical	ADJ
eurjchem-2544	335	20	nature	nature	NOUN
eurjchem-2544	335	21	of	of	ADP
eurjchem-2544	335	22	tedcrh01	tedcrh01	NOUN
eurjchem-2544	335	23	compared	compare	VERB
eurjchem-2544	335	24	to	to	ADP
eurjchem-2544	335	25	the	the	DET
eurjchem-2544	335	26	unsymmetrical	unsymmetrical	ADJ
eurjchem-2544	335	27	nature	nature	NOUN
eurjchem-2544	335	28	of	of	ADP
eurjchem-2544	335	29	the	the	DET
eurjchem-2544	335	30	rh	rh	PROPN
eurjchem-2544	335	31	-	-	PUNCT
eurjchem-2544	335	32	s	s	PROPN
eurjchem-2544	335	33	bonds	bond	NOUN
eurjchem-2544	335	34	(	(	PUNCT
eurjchem-2544	335	35	2.360	2.360	NUM
eurjchem-2544	335	36	.	.	PUNCT
eurjchem-2544	336	1	2.363	2.363	NUM
eurjchem-2544	336	2	,	,	PUNCT
eurjchem-2544	336	3	2.3552	2.3552	NUM
eurjchem-2544	336	4	,	,	PUNCT
eurjchem-2544	336	5	2.378	2.378	NUM
eurjchem-2544	336	6	,	,	PUNCT
eurjchem-2544	336	7	2.3601	2.3601	NUM
eurjchem-2544	336	8	,	,	PUNCT
eurjchem-2544	336	9	and	and	CCONJ
eurjchem-2544	336	10	2.369	2.369	NUM
eurjchem-2544	336	11	å	å	NOUN
eurjchem-2544	336	12	)	)	PUNCT
eurjchem-2544	336	13	in	in	ADP
eurjchem-2544	336	14	complex	complex	ADJ
eurjchem-2544	336	15	17	17	NUM
eurjchem-2544	336	16	.	.	PUNCT
eurjchem-2544	337	1	likewise	likewise	ADV
eurjchem-2544	337	2	,	,	PUNCT
eurjchem-2544	337	3	the	the	DET
eurjchem-2544	337	4	symmetrical	symmetrical	ADJ
eurjchem-2544	337	5	nature	nature	NOUN
eurjchem-2544	337	6	of	of	ADP
eurjchem-2544	337	7	tedcrh01	tedcrh01	NOUN
eurjchem-2544	337	8	is	be	AUX
eurjchem-2544	337	9	reflected	reflect	VERB
eurjchem-2544	337	10	by	by	ADP
eurjchem-2544	337	11	their	their	PRON
eurjchem-2544	337	12	c	c	PROPN
eurjchem-2544	337	13	-	-	PUNCT
eurjchem-2544	337	14	s	s	NOUN
eurjchem-2544	337	15	bonds	bond	NOUN
eurjchem-2544	337	16	of	of	ADP
eurjchem-2544	337	17	lengths	length	NOUN
eurjchem-2544	337	18	1.712	1.712	NUM
eurjchem-2544	337	19	,	,	PUNCT
eurjchem-2544	337	20	1.712	1.712	NUM
eurjchem-2544	337	21	,	,	PUNCT
eurjchem-2544	337	22	1.709(6	1.709(6	NUM
eurjchem-2544	337	23	)	)	PUNCT
eurjchem-2544	337	24	,	,	PUNCT
eurjchem-2544	337	25	1.704(6	1.704(6	NUM
eurjchem-2544	337	26	)	)	PUNCT
eurjchem-2544	337	27	,	,	PUNCT
eurjchem-2544	337	28	1.704(6	1.704(6	NUM
eurjchem-2544	337	29	)	)	PUNCT
eurjchem-2544	337	30	and	and	CCONJ
eurjchem-2544	337	31	1.709(6	1.709(6	NUM
eurjchem-2544	337	32	)	)	PUNCT
eurjchem-2544	337	33	å	å	PROPN
eurjchem-2544	337	34	and	and	CCONJ
eurjchem-2544	337	35	c	c	NOUN
eurjchem-2544	337	36	-	-	PUNCT
eurjchem-2544	337	37	n	n	PRON
eurjchem-2544	337	38	bonds	bond	NOUN
eurjchem-2544	337	39	of	of	ADP
eurjchem-2544	337	40	lengths	length	NOUN
eurjchem-2544	337	41	1.33	1.33	NUM
eurjchem-2544	337	42	,	,	PUNCT
eurjchem-2544	337	43	1.330(6	1.330(6	NUM
eurjchem-2544	337	44	)	)	PUNCT
eurjchem-2544	337	45	and	and	CCONJ
eurjchem-2544	337	46	1.330(6	1.330(6	X
eurjchem-2544	337	47	)	)	PUNCT
eurjchem-2544	337	48	å	å	NOUN
eurjchem-2544	337	49	compared	compare	VERB
eurjchem-2544	337	50	to	to	ADP
eurjchem-2544	337	51	the	the	DET
eurjchem-2544	337	52	unsymmetrical	unsymmetrical	ADJ
eurjchem-2544	337	53	1.692	1.692	NUM
eurjchem-2544	337	54	,	,	PUNCT
eurjchem-2544	337	55	1.7279	1.7279	NUM
eurjchem-2544	337	56	,	,	PUNCT
eurjchem-2544	337	57	1.728	1.728	NUM
eurjchem-2544	337	58	,	,	PUNCT
eurjchem-2544	337	59	1.7303	1.7303	NUM
eurjchem-2544	337	60	,	,	PUNCT
eurjchem-2544	337	61	1.707	1.707	NUM
eurjchem-2544	337	62	and	and	CCONJ
eurjchem-2544	337	63	1.683	1.683	NUM
eurjchem-2544	337	64	å	å	PROPN
eurjchem-2544	337	65	for	for	ADP
eurjchem-2544	337	66	c	c	NOUN
eurjchem-2544	337	67	-	-	PUNCT
eurjchem-2544	337	68	s	s	NOUN
eurjchem-2544	337	69	and	and	CCONJ
eurjchem-2544	337	70	1.3795	1.3795	NUM
eurjchem-2544	337	71	,	,	PUNCT
eurjchem-2544	337	72	1.323	1.323	NUM
eurjchem-2544	337	73	and	and	CCONJ
eurjchem-2544	337	74	1.357	1.357	NUM
eurjchem-2544	337	75	å	å	PROPN
eurjchem-2544	337	76	recorded	record	VERB
eurjchem-2544	337	77	for	for	ADP
eurjchem-2544	337	78	c	c	NOUN
eurjchem-2544	337	79	-	-	PUNCT
eurjchem-2544	337	80	n	n	PRON
eurjchem-2544	337	81	bonds	bond	NOUN
eurjchem-2544	337	82	.	.	PUNCT
eurjchem-2544	338	1	in	in	ADP
eurjchem-2544	338	2	terms	term	NOUN
eurjchem-2544	338	3	of	of	ADP
eurjchem-2544	338	4	the	the	DET
eurjchem-2544	338	5	s	s	PROPN
eurjchem-2544	338	6	-	-	PUNCT
eurjchem-2544	338	7	rh	rh	PROPN
eurjchem-2544	338	8	-	-	PUNCT
eurjchem-2544	338	9	s	s	NOUN
eurjchem-2544	338	10	bond	bond	NOUN
eurjchem-2544	338	11	angles	angle	NOUN
eurjchem-2544	338	12	,	,	PUNCT
eurjchem-2544	338	13	tedcrh01	tedcrh01	NOUN
eurjchem-2544	338	14	shows	show	VERB
eurjchem-2544	338	15	slightly	slightly	ADV
eurjchem-2544	338	16	symmetrical	symmetrical	ADJ
eurjchem-2544	338	17	bites	bite	NOUN
eurjchem-2544	338	18	of	of	ADP
eurjchem-2544	338	19	73.70	73.70	NUM
eurjchem-2544	338	20	,	,	PUNCT
eurjchem-2544	338	21	74.11	74.11	NUM
eurjchem-2544	338	22	,	,	PUNCT
eurjchem-2544	338	23	and	and	CCONJ
eurjchem-2544	338	24	73.70	73.70	NUM
eurjchem-2544	338	25	°	°	NUM
eurjchem-2544	338	26	compared	compare	VERB
eurjchem-2544	338	27	to	to	ADP
eurjchem-2544	338	28	the	the	DET
eurjchem-2544	338	29	unsymmetrical	unsymmetrical	ADJ
eurjchem-2544	338	30	73.57	73.57	NUM
eurjchem-2544	338	31	,	,	PUNCT
eurjchem-2544	338	32	73.62	73.62	NUM
eurjchem-2544	338	33	and	and	CCONJ
eurjchem-2544	338	34	73.43	73.43	NUM
eurjchem-2544	338	35	°	°	PRON
eurjchem-2544	338	36	recorded	record	VERB
eurjchem-2544	338	37	for	for	ADP
eurjchem-2544	338	38	complex	complex	ADJ
eurjchem-2544	338	39	17	17	NUM
eurjchem-2544	338	40	.	.	PUNCT
eurjchem-2544	339	1	the	the	DET
eurjchem-2544	339	2	two	two	NUM
eurjchem-2544	339	3	complexes	complex	NOUN
eurjchem-2544	339	4	share	share	VERB
eurjchem-2544	339	5	similar	similar	ADJ
eurjchem-2544	339	6	properties	property	NOUN
eurjchem-2544	339	7	related	relate	VERB
eurjchem-2544	339	8	to	to	ADP
eurjchem-2544	339	9	symmetry	symmetry	NOUN
eurjchem-2544	339	10	,	,	PUNCT
eurjchem-2544	339	11	such	such	ADJ
eurjchem-2544	339	12	as	as	ADP
eurjchem-2544	339	13	the	the	DET
eurjchem-2544	339	14	two	two	NUM
eurjchem-2544	339	15	-	-	ADJ
eurjchem-2544	339	16	fold	fold	ADJ
eurjchem-2544	339	17	screw	screw	NOUN
eurjchem-2544	339	18	axis	axis	NOUN
eurjchem-2544	339	19	.	.	PUNCT
eurjchem-2544	340	1	on	on	ADP
eurjchem-2544	340	2	the	the	DET
eurjchem-2544	340	3	other	other	ADJ
eurjchem-2544	340	4	hand	hand	NOUN
eurjchem-2544	340	5	,	,	PUNCT
eurjchem-2544	340	6	complex	complex	ADJ
eurjchem-2544	340	7	17	17	NUM
eurjchem-2544	340	8	has	have	VERB
eurjchem-2544	340	9	an	an	DET
eurjchem-2544	340	10	inversion	inversion	NOUN
eurjchem-2544	340	11	center	center	NOUN
eurjchem-2544	340	12	at	at	ADP
eurjchem-2544	340	13	[	[	X
eurjchem-2544	340	14	0,0,0	0,0,0	NOUN
eurjchem-2544	340	15	]	]	PUNCT
eurjchem-2544	340	16	and	and	CCONJ
eurjchem-2544	340	17	a	a	DET
eurjchem-2544	340	18	glide	glide	ADJ
eurjchem-2544	340	19	plane	plane	NOUN
eurjchem-2544	340	20	that	that	PRON
eurjchem-2544	340	21	is	be	AUX
eurjchem-2544	340	22	perpendicular	perpendicular	ADJ
eurjchem-2544	340	23	to	to	ADP
eurjchem-2544	340	24	the	the	DET
eurjchem-2544	340	25	[	[	X
eurjchem-2544	340	26	0,1,0	0,1,0	NUM
eurjchem-2544	340	27	]	]	X
eurjchem-2544	340	28	axis	axis	NOUN
eurjchem-2544	340	29	with	with	ADP
eurjchem-2544	340	30	a	a	DET
eurjchem-2544	340	31	glide	glide	ADJ
eurjchem-2544	340	32	component	component	NOUN
eurjchem-2544	340	33	[	[	X
eurjchem-2544	340	34	½,0,0	½,0,0	NOUN
eurjchem-2544	340	35	]	]	PUNCT
eurjchem-2544	340	36	.	.	PUNCT
eurjchem-2544	341	1	tedcrh01	tedcrh01	PROPN
eurjchem-2544	341	2	differs	differ	VERB
eurjchem-2544	341	3	considerably	considerably	ADV
eurjchem-2544	341	4	from	from	ADP
eurjchem-2544	341	5	complex	complex	ADJ
eurjchem-2544	341	6	17	17	NUM
eurjchem-2544	341	7	by	by	ADP
eurjchem-2544	341	8	virtue	virtue	NOUN
eurjchem-2544	341	9	of	of	ADP
eurjchem-2544	341	10	its	its	PRON
eurjchem-2544	341	11	2	2	NUM
eurjchem-2544	341	12	-	-	ADJ
eurjchem-2544	341	13	fold	fold	ADJ
eurjchem-2544	341	14	rotation	rotation	NOUN
eurjchem-2544	341	15	axis	axis	NOUN
eurjchem-2544	341	16	,	,	PUNCT
eurjchem-2544	341	17	centering	center	VERB
eurjchem-2544	341	18	vector	vector	NOUN
eurjchem-2544	341	19	,	,	PUNCT
eurjchem-2544	341	20	inversion	inversion	NOUN
eurjchem-2544	341	21	centre	centre	NOUN
eurjchem-2544	341	22	at	at	ADP
eurjchem-2544	341	23	[	[	X
eurjchem-2544	341	24	¼,¼,0	¼,¼,0	NOUN
eurjchem-2544	341	25	]	]	PUNCT
eurjchem-2544	341	26	,	,	PUNCT
eurjchem-2544	341	27	a	a	DET
eurjchem-2544	341	28	glide	glide	ADJ
eurjchem-2544	341	29	plane	plane	NOUN
eurjchem-2544	341	30	perpendicular	perpendicular	NOUN
eurjchem-2544	341	31	to	to	ADP
eurjchem-2544	341	32	the	the	DET
eurjchem-2544	341	33	[	[	X
eurjchem-2544	341	34	1,1,0	1,1,0	NUM
eurjchem-2544	341	35	]	]	X
eurjchem-2544	341	36	axis	axis	NOUN
eurjchem-2544	341	37	with	with	ADP
eurjchem-2544	341	38	a	a	DET
eurjchem-2544	341	39	glide	glide	ADJ
eurjchem-2544	341	40	component	component	NOUN
eurjchem-2544	341	41	[	[	X
eurjchem-2544	341	42	0,0,½	0,0,½	X
eurjchem-2544	341	43	]	]	X
eurjchem-2544	341	44	and	and	CCONJ
eurjchem-2544	341	45	another	another	DET
eurjchem-2544	341	46	glide	glide	ADJ
eurjchem-2544	341	47	plane	plane	NOUN
eurjchem-2544	341	48	that	that	PRON
eurjchem-2544	341	49	is	be	AUX
eurjchem-2544	341	50	perpendicular	perpendicular	ADJ
eurjchem-2544	341	51	to	to	ADP
eurjchem-2544	341	52	[	[	X
eurjchem-2544	341	53	0,1,0	0,1,0	X
eurjchem-2544	341	54	]	]	X
eurjchem-2544	341	55	with	with	ADP
eurjchem-2544	341	56	a	a	DET
eurjchem-2544	341	57	glide	glide	ADJ
eurjchem-2544	341	58	component	component	NOUN
eurjchem-2544	341	59	[	[	X
eurjchem-2544	341	60	½,0,½	½,0,½	NOUN
eurjchem-2544	341	61	]	]	X
eurjchem-2544	341	62	.	.	PUNCT
eurjchem-2544	342	1	its	its	PRON
eurjchem-2544	342	2	crystal	crystal	NOUN
eurjchem-2544	342	3	lattice	lattice	NOUN
eurjchem-2544	342	4	is	be	AUX
eurjchem-2544	342	5	dominated	dominate	VERB
eurjchem-2544	342	6	by	by	ADP
eurjchem-2544	342	7	hydrogen	hydrogen	NOUN
eurjchem-2544	342	8	-	-	PUNCT
eurjchem-2544	342	9	bond	bond	NOUN
eurjchem-2544	342	10	interactions	interaction	NOUN
eurjchem-2544	342	11	with	with	ADP
eurjchem-2544	342	12	h···s	h···	NOUN
eurjchem-2544	342	13	contacts	contact	NOUN
eurjchem-2544	342	14	of	of	ADP
eurjchem-2544	342	15	distances	distance	NOUN
eurjchem-2544	342	16	2.989	2.989	NUM
eurjchem-2544	342	17	,	,	PUNCT
eurjchem-2544	342	18	2.989	2.989	NUM
eurjchem-2544	342	19	,	,	PUNCT
eurjchem-2544	342	20	2.366	2.366	NUM
eurjchem-2544	342	21	,	,	PUNCT
eurjchem-2544	342	22	2.366	2.366	NUM
eurjchem-2544	342	23	,	,	PUNCT
eurjchem-2544	342	24	2.947	2.947	NUM
eurjchem-2544	342	25	and	and	CCONJ
eurjchem-2544	342	26	2.947	2.947	NUM
eurjchem-2544	342	27	å	å	NOUN
eurjchem-2544	342	28	resulting	result	VERB
eurjchem-2544	342	29	in	in	ADP
eurjchem-2544	342	30	a	a	DET
eurjchem-2544	342	31	crystalline	crystalline	NOUN
eurjchem-2544	342	32	2d	2d	NOUN
eurjchem-2544	342	33	aggregate	aggregate	NOUN
eurjchem-2544	342	34	.	.	PUNCT
eurjchem-2544	343	1	2.3	2.3	NUM
eurjchem-2544	343	2	.	.	PUNCT
eurjchem-2544	343	3	ir(iii	ir(iii	NOUN
eurjchem-2544	343	4	)	)	PUNCT
eurjchem-2544	343	5	complexes	complexe	VERB
eurjchem-2544	343	6	tris(diethyl(dithiocarbamato)iridium(iii	tris(diethyl(dithiocarbamato)iridium(iii	NOUN
eurjchem-2544	343	7	)	)	PUNCT
eurjchem-2544	343	8	(	(	PUNCT
eurjchem-2544	343	9	18	18	NUM
eurjchem-2544	343	10	,	,	PUNCT
eurjchem-2544	343	11	figure	figure	NOUN
eurjchem-2544	343	12	11	11	NUM
eurjchem-2544	343	13	)	)	PUNCT
eurjchem-2544	344	1	[	[	X
eurjchem-2544	344	2	52	52	NUM
eurjchem-2544	344	3	]	]	PUNCT
eurjchem-2544	344	4	,	,	PUNCT
eurjchem-2544	344	5	which	which	PRON
eurjchem-2544	344	6	is	be	AUX
eurjchem-2544	344	7	isostructural	isostructural	ADJ
eurjchem-2544	344	8	with	with	ADP
eurjchem-2544	344	9	its	its	PRON
eurjchem-2544	344	10	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	344	11	)	)	PUNCT
eurjchem-2544	344	12	analogue	analogue	NOUN
eurjchem-2544	345	1	[	[	X
eurjchem-2544	345	2	8,33	8,33	NUM
eurjchem-2544	345	3	]	]	PUNCT
eurjchem-2544	345	4	,	,	PUNCT
eurjchem-2544	345	5	crystallizes	crystallize	VERB
eurjchem-2544	345	6	in	in	ADP
eurjchem-2544	345	7	the	the	DET
eurjchem-2544	345	8	c2	c2	PROPN
eurjchem-2544	345	9	/	/	SYM
eurjchem-2544	345	10	c	c	PROPN
eurjchem-2544	345	11	space	space	NOUN
eurjchem-2544	345	12	group	group	NOUN
eurjchem-2544	345	13	of	of	ADP
eurjchem-2544	345	14	the	the	DET
eurjchem-2544	345	15	monoclinic	monoclinic	ADJ
eurjchem-2544	345	16	crystal	crystal	NOUN
eurjchem-2544	345	17	system	system	NOUN
eurjchem-2544	345	18	with	with	ADP
eurjchem-2544	345	19	the	the	DET
eurjchem-2544	345	20	structural	structural	ADJ
eurjchem-2544	345	21	formula	formula	NOUN
eurjchem-2544	345	22	[	[	X
eurjchem-2544	345	23	ir(s2cnet2)3	ir(s2cnet2)3	PROPN
eurjchem-2544	345	24	]	]	X
eurjchem-2544	345	25	.	.	PUNCT
eurjchem-2544	346	1	its	its	PRON
eurjchem-2544	346	2	unit	unit	NOUN
eurjchem-2544	346	3	cell	cell	NOUN
eurjchem-2544	346	4	is	be	AUX
eurjchem-2544	346	5	made	make	VERB
eurjchem-2544	346	6	up	up	ADP
eurjchem-2544	346	7	of	of	ADP
eurjchem-2544	346	8	discrete	discrete	ADJ
eurjchem-2544	346	9	molecules	molecule	NOUN
eurjchem-2544	346	10	seated	seat	VERB
eurjchem-2544	346	11	on	on	ADP
eurjchem-2544	346	12	a	a	DET
eurjchem-2544	346	13	2	2	NUM
eurjchem-2544	346	14	-	-	ADJ
eurjchem-2544	346	15	fold	fold	ADJ
eurjchem-2544	346	16	symmetry	symmetry	NOUN
eurjchem-2544	346	17	that	that	PRON
eurjchem-2544	346	18	passes	pass	VERB
eurjchem-2544	346	19	through	through	ADP
eurjchem-2544	346	20	(	(	PUNCT
eurjchem-2544	346	21	i	i	NOUN
eurjchem-2544	346	22	)	)	PUNCT
eurjchem-2544	346	23	the	the	DET
eurjchem-2544	346	24	axis	axis	NOUN
eurjchem-2544	346	25	of	of	ADP
eurjchem-2544	346	26	one	one	NUM
eurjchem-2544	346	27	of	of	ADP
eurjchem-2544	346	28	the	the	DET
eurjchem-2544	346	29	ligands	ligand	NOUN
eurjchem-2544	346	30	and	and	CCONJ
eurjchem-2544	346	31	(	(	PUNCT
eurjchem-2544	346	32	ii	ii	NOUN
eurjchem-2544	346	33	)	)	PUNCT
eurjchem-2544	346	34	the	the	DET
eurjchem-2544	346	35	metal	metal	NOUN
eurjchem-2544	346	36	atom	atom	NOUN
eurjchem-2544	346	37	.	.	PUNCT
eurjchem-2544	347	1	the	the	DET
eurjchem-2544	347	2	other	other	ADJ
eurjchem-2544	347	3	ligand	ligand	NOUN
eurjchem-2544	347	4	has	have	VERB
eurjchem-2544	347	5	a	a	DET
eurjchem-2544	347	6	slightly	slightly	ADV
eurjchem-2544	347	7	distorted	distorted	ADJ
eurjchem-2544	347	8	s2cnc2	s2cnc2	ADJ
eurjchem-2544	347	9	plane	plane	NOUN
eurjchem-2544	347	10	,	,	PUNCT
eurjchem-2544	347	11	as	as	ADV
eurjchem-2544	347	12	well	well	ADV
eurjchem-2544	347	13	as	as	ADP
eurjchem-2544	347	14	an	an	DET
eurjchem-2544	347	15	iridium	iridium	NOUN
eurjchem-2544	347	16	center	center	NOUN
eurjchem-2544	347	17	,	,	PUNCT
eurjchem-2544	347	18	whose	whose	DET
eurjchem-2544	347	19	deviation	deviation	NOUN
eurjchem-2544	347	20	from	from	ADP
eurjchem-2544	347	21	the	the	DET
eurjchem-2544	347	22	plane	plane	NOUN
eurjchem-2544	347	23	is	be	AUX
eurjchem-2544	347	24	small	small	ADJ
eurjchem-2544	347	25	but	but	CCONJ
eurjchem-2544	347	26	significant	significant	ADJ
eurjchem-2544	347	27	.	.	PUNCT
eurjchem-2544	348	1	the	the	DET
eurjchem-2544	348	2	mean	mean	ADJ
eurjchem-2544	348	3	ir	ir	PROPN
eurjchem-2544	348	4	-	-	PUNCT
eurjchem-2544	348	5	s	s	PART
eurjchem-2544	348	6	bond	bond	NOUN
eurjchem-2544	348	7	distance	distance	NOUN
eurjchem-2544	348	8	of	of	ADP
eurjchem-2544	348	9	2.36(7	2.36(7	NUM
eurjchem-2544	348	10	)	)	PUNCT
eurjchem-2544	348	11	å	å	PROPN
eurjchem-2544	348	12	in	in	ADP
eurjchem-2544	348	13	compound	compound	NOUN
eurjchem-2544	348	14	18	18	NUM
eurjchem-2544	348	15	is	be	AUX
eurjchem-2544	348	16	reasonably	reasonably	ADV
eurjchem-2544	348	17	consistent	consistent	ADJ
eurjchem-2544	348	18	with	with	ADP
eurjchem-2544	348	19	what	what	PRON
eurjchem-2544	348	20	was	be	AUX
eurjchem-2544	348	21	reported	report	VERB
eurjchem-2544	348	22	for	for	ADP
eurjchem-2544	348	23	[	[	X
eurjchem-2544	348	24	ir2(c7h7s2)3(co)2(pph3)2	ir2(c7h7s2)3(co)2(pph3)2	X
eurjchem-2544	348	25	]	]	X
eurjchem-2544	349	1	[	[	X
eurjchem-2544	349	2	52	52	NUM
eurjchem-2544	349	3	]	]	PUNCT
eurjchem-2544	349	4	.	.	PUNCT
eurjchem-2544	350	1	just	just	ADV
eurjchem-2544	350	2	as	as	ADP
eurjchem-2544	350	3	in	in	ADP
eurjchem-2544	350	4	other	other	ADJ
eurjchem-2544	350	5	metal	metal	NOUN
eurjchem-2544	350	6	complexes	complex	NOUN
eurjchem-2544	350	7	of	of	ADP
eurjchem-2544	350	8	the	the	DET
eurjchem-2544	350	9	form	form	NOUN
eurjchem-2544	350	10	[	[	X
eurjchem-2544	350	11	m(s2net2)3	m(s2net2)3	X
eurjchem-2544	350	12	]	]	X
eurjchem-2544	350	13	where	where	SCONJ
eurjchem-2544	350	14	m	m	VERB
eurjchem-2544	350	15	=	=	PUNCT
eurjchem-2544	350	16	co	co	NOUN
eurjchem-2544	350	17	[	[	X
eurjchem-2544	350	18	8,33	8,33	NUM
eurjchem-2544	350	19	]	]	PUNCT
eurjchem-2544	350	20	,	,	PUNCT
eurjchem-2544	350	21	fe	fe	X
eurjchem-2544	351	1	[	[	X
eurjchem-2544	351	2	53	53	NUM
eurjchem-2544	351	3	]	]	PUNCT
eurjchem-2544	351	4	,	,	PUNCT
eurjchem-2544	351	5	cr	cr	X
eurjchem-2544	352	1	[	[	X
eurjchem-2544	352	2	52	52	NUM
eurjchem-2544	352	3	]	]	PUNCT
eurjchem-2544	352	4	,	,	PUNCT
eurjchem-2544	352	5	ru	ru	PROPN
eurjchem-2544	353	1	[	[	X
eurjchem-2544	353	2	54	54	NUM
eurjchem-2544	353	3	]	]	PUNCT
eurjchem-2544	353	4	,	,	PUNCT
eurjchem-2544	353	5	the	the	DET
eurjchem-2544	353	6	electronic	electronic	ADJ
eurjchem-2544	353	7	distortion	distortion	NOUN
eurjchem-2544	353	8	mechanism	mechanism	NOUN
eurjchem-2544	353	9	is	be	AUX
eurjchem-2544	353	10	inherently	inherently	ADV
eurjchem-2544	353	11	absent	absent	ADJ
eurjchem-2544	353	12	resulting	result	VERB
eurjchem-2544	353	13	in	in	ADP
eurjchem-2544	353	14	the	the	DET
eurjchem-2544	353	15	ms6	ms6	NOUN
eurjchem-2544	353	16	geometry	geometry	NOUN
eurjchem-2544	353	17	(	(	PUNCT
eurjchem-2544	353	18	figure	figure	NOUN
eurjchem-2544	353	19	12	12	NUM
eurjchem-2544	353	20	)	)	PUNCT
eurjchem-2544	353	21	that	that	PRON
eurjchem-2544	353	22	is	be	AUX
eurjchem-2544	353	23	approximately	approximately	ADV
eurjchem-2544	353	24	equivalent	equivalent	ADJ
eurjchem-2544	353	25	to	to	PART
eurjchem-2544	353	26	d3	d3	VERB
eurjchem-2544	353	27	with	with	ADP
eurjchem-2544	353	28	a	a	DET
eurjchem-2544	353	29	structural	structural	ADJ
eurjchem-2544	353	30	moiety	moiety	NOUN
eurjchem-2544	353	31	that	that	PRON
eurjchem-2544	353	32	depends	depend	VERB
eurjchem-2544	353	33	on	on	ADP
eurjchem-2544	353	34	the	the	DET
eurjchem-2544	353	35	metal	metal	NOUN
eurjchem-2544	353	36	-	-	PUNCT
eurjchem-2544	353	37	sulphur	sulphur	NOUN
eurjchem-2544	353	38	distance	distance	NOUN
eurjchem-2544	353	39	.	.	PUNCT
eurjchem-2544	354	1	the	the	DET
eurjchem-2544	354	2	geometrical	geometrical	ADJ
eurjchem-2544	354	3	alignments	alignment	NOUN
eurjchem-2544	354	4	in	in	ADP
eurjchem-2544	354	5	complex	complex	ADJ
eurjchem-2544	354	6	18	18	NUM
eurjchem-2544	354	7	have	have	AUX
eurjchem-2544	354	8	been	be	AUX
eurjchem-2544	354	9	considered	consider	VERB
eurjchem-2544	354	10	'	'	PUNCT
eurjchem-2544	354	11	anomalous	anomalous	ADJ
eurjchem-2544	354	12	'	'	PUNCT
eurjchem-2544	354	13	,	,	PUNCT
eurjchem-2544	354	14	as	as	SCONJ
eurjchem-2544	354	15	they	they	PRON
eurjchem-2544	354	16	should	should	AUX
eurjchem-2544	354	17	clearly	clearly	ADV
eurjchem-2544	354	18	have	have	AUX
eurjchem-2544	354	19	crystallized	crystallize	VERB
eurjchem-2544	354	20	in	in	ADP
eurjchem-2544	354	21	the	the	DET
eurjchem-2544	354	22	p21	p21	NOUN
eurjchem-2544	354	23	/	/	SYM
eurjchem-2544	354	24	c	c	PROPN
eurjchem-2544	354	25	space	space	NOUN
eurjchem-2544	354	26	group	group	NOUN
eurjchem-2544	354	27	rather	rather	ADV
eurjchem-2544	354	28	than	than	ADP
eurjchem-2544	354	29	c2	c2	PROPN
eurjchem-2544	354	30	/	/	SYM
eurjchem-2544	354	31	c.	c.	PROPN
eurjchem-2544	354	32	the	the	DET
eurjchem-2544	354	33	possibility	possibility	NOUN
eurjchem-2544	354	34	of	of	ADP
eurjchem-2544	354	35	a	a	DET
eurjchem-2544	354	36	300	300	NUM
eurjchem-2544	354	37	shotonwa	shotonwa	ADJ
eurjchem-2544	354	38	et	et	PROPN
eurjchem-2544	354	39	al	al	PROPN
eurjchem-2544	354	40	.	.	PUNCT
eurjchem-2544	354	41	/	/	SYM
eurjchem-2544	354	42	european	european	PROPN
eurjchem-2544	354	43	journal	journal	PROPN
eurjchem-2544	354	44	of	of	ADP
eurjchem-2544	354	45	chemistry	chemistry	NOUN
eurjchem-2544	354	46	15	15	NUM
eurjchem-2544	354	47	(	(	PUNCT
eurjchem-2544	354	48	3	3	NUM
eurjchem-2544	354	49	)	)	PUNCT
eurjchem-2544	354	50	(	(	PUNCT
eurjchem-2544	354	51	2024	2024	NUM
eurjchem-2544	354	52	)	)	PUNCT
eurjchem-2544	354	53	291	291	NUM
eurjchem-2544	354	54	-	-	SYM
eurjchem-2544	354	55	301	301	NUM
eurjchem-2544	354	56	2024	2024	NUM
eurjchem-2544	354	57	–	–	PUNCT
eurjchem-2544	354	58	european	european	ADJ
eurjchem-2544	354	59	journal	journal	NOUN
eurjchem-2544	354	60	of	of	ADP
eurjchem-2544	354	61	chemistry	chemistry	NOUN
eurjchem-2544	354	62	–	–	PUNCT
eurjchem-2544	354	63	cc	cc	NOUN
eurjchem-2544	354	64	by	by	ADP
eurjchem-2544	354	65	nc	nc	PROPN
eurjchem-2544	354	66	–	–	PUNCT
eurjchem-2544	354	67	doi	doi	PROPN
eurjchem-2544	354	68	:	:	PUNCT
eurjchem-2544	354	69	10.5155	10.5155	NUM
eurjchem-2544	354	70	/	/	SYM
eurjchem-2544	354	71	eurjchem.15.3.291	eurjchem.15.3.291	NUM
eurjchem-2544	354	72	-	-	PUNCT
eurjchem-2544	354	73	301.2544	301.2544	NUM
eurjchem-2544	354	74	wrong	wrong	ADJ
eurjchem-2544	354	75	assignment	assignment	NOUN
eurjchem-2544	354	76	of	of	ADP
eurjchem-2544	354	77	c2	c2	PROPN
eurjchem-2544	354	78	/	/	SYM
eurjchem-2544	354	79	c	c	PROPN
eurjchem-2544	354	80	was	be	AUX
eurjchem-2544	354	81	dismissed	dismiss	VERB
eurjchem-2544	354	82	after	after	ADP
eurjchem-2544	354	83	a	a	DET
eurjchem-2544	354	84	series	series	NOUN
eurjchem-2544	354	85	of	of	ADP
eurjchem-2544	354	86	long	long	ADJ
eurjchem-2544	354	87	exposures	exposure	NOUN
eurjchem-2544	354	88	to	to	ADP
eurjchem-2544	354	89	weissenberg	weissenberg	PROPN
eurjchem-2544	354	90	photographs	photograph	NOUN
eurjchem-2544	354	91	.	.	PUNCT
eurjchem-2544	354	92	table	table	NOUN
eurjchem-2544	354	93	3	3	NUM
eurjchem-2544	354	94	shows	show	VERB
eurjchem-2544	354	95	the	the	DET
eurjchem-2544	354	96	selected	select	VERB
eurjchem-2544	354	97	bond	bond	NOUN
eurjchem-2544	354	98	distances	distance	NOUN
eurjchem-2544	354	99	,	,	PUNCT
eurjchem-2544	354	100	angles	angle	NOUN
eurjchem-2544	354	101	,	,	PUNCT
eurjchem-2544	354	102	and	and	CCONJ
eurjchem-2544	354	103	solvents	solvent	NOUN
eurjchem-2544	354	104	for	for	ADP
eurjchem-2544	354	105	crystal	crystal	NOUN
eurjchem-2544	354	106	growth	growth	NOUN
eurjchem-2544	354	107	in	in	ADP
eurjchem-2544	354	108	complex	complex	ADJ
eurjchem-2544	354	109	18	18	NUM
eurjchem-2544	354	110	.	.	PUNCT
eurjchem-2544	355	1	it	it	PRON
eurjchem-2544	355	2	shows	show	VERB
eurjchem-2544	355	3	the	the	DET
eurjchem-2544	355	4	changes	change	NOUN
eurjchem-2544	355	5	in	in	ADP
eurjchem-2544	355	6	bond	bond	NOUN
eurjchem-2544	355	7	angles	angle	NOUN
eurjchem-2544	355	8	and	and	CCONJ
eurjchem-2544	355	9	distance	distance	NOUN
eurjchem-2544	355	10	as	as	SCONJ
eurjchem-2544	355	11	the	the	DET
eurjchem-2544	355	12	r	r	NOUN
eurjchem-2544	355	13	substituents	substituent	NOUN
eurjchem-2544	355	14	in	in	ADP
eurjchem-2544	355	15	the	the	DET
eurjchem-2544	355	16	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	355	17	backbones	backbone	NOUN
eurjchem-2544	355	18	are	be	AUX
eurjchem-2544	355	19	changed	change	VERB
eurjchem-2544	355	20	or	or	CCONJ
eurjchem-2544	355	21	modified	modify	VERB
eurjchem-2544	355	22	.	.	PUNCT
eurjchem-2544	356	1	3	3	X
eurjchem-2544	356	2	.	.	X
eurjchem-2544	356	3	conclusions	conclusion	NOUN
eurjchem-2544	356	4	and	and	CCONJ
eurjchem-2544	356	5	future	future	ADJ
eurjchem-2544	356	6	perspectives	perspective	NOUN
eurjchem-2544	356	7	the	the	DET
eurjchem-2544	356	8	solid	solid	ADJ
eurjchem-2544	356	9	-	-	PUNCT
eurjchem-2544	356	10	state	state	NOUN
eurjchem-2544	356	11	crystal	crystal	NOUN
eurjchem-2544	356	12	and	and	CCONJ
eurjchem-2544	356	13	molecular	molecular	ADJ
eurjchem-2544	356	14	description	description	NOUN
eurjchem-2544	356	15	of	of	ADP
eurjchem-2544	356	16	single	single	ADJ
eurjchem-2544	356	17	and	and	CCONJ
eurjchem-2544	356	18	mixed	mixed	ADJ
eurjchem-2544	356	19	ligand	ligand	NOUN
eurjchem-2544	356	20	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	356	21	complexes	complex	NOUN
eurjchem-2544	356	22	of	of	ADP
eurjchem-2544	356	23	cobalt	cobalt	NOUN
eurjchem-2544	356	24	,	,	PUNCT
eurjchem-2544	356	25	rhodium	rhodium	NOUN
eurjchem-2544	356	26	,	,	PUNCT
eurjchem-2544	356	27	and	and	CCONJ
eurjchem-2544	356	28	iridium	iridium	NOUN
eurjchem-2544	356	29	in	in	ADP
eurjchem-2544	356	30	the	the	DET
eurjchem-2544	356	31	+3	+3	PROPN
eurjchem-2544	356	32	oxidation	oxidation	NOUN
eurjchem-2544	356	33	states	state	NOUN
eurjchem-2544	356	34	are	be	AUX
eurjchem-2544	356	35	presented	present	VERB
eurjchem-2544	356	36	herewith	herewith	ADP
eurjchem-2544	356	37	their	their	PRON
eurjchem-2544	356	38	wide	wide	ADJ
eurjchem-2544	356	39	arrays	array	NOUN
eurjchem-2544	356	40	of	of	ADP
eurjchem-2544	356	41	chelating	chelating	NOUN
eurjchem-2544	356	42	and	and	CCONJ
eurjchem-2544	356	43	bridging	bridging	NOUN
eurjchem-2544	356	44	modes	mode	NOUN
eurjchem-2544	356	45	ranging	range	VERB
eurjchem-2544	356	46	from	from	ADP
eurjchem-2544	356	47	monomeric	monomeric	ADJ
eurjchem-2544	356	48	,	,	PUNCT
eurjchem-2544	356	49	dimeric	dimeric	ADJ
eurjchem-2544	356	50	,	,	PUNCT
eurjchem-2544	356	51	and	and	CCONJ
eurjchem-2544	356	52	polymeric	polymeric	ADJ
eurjchem-2544	356	53	networks	network	NOUN
eurjchem-2544	356	54	to	to	ADP
eurjchem-2544	356	55	3d	3d	NUM
eurjchem-2544	356	56	supramolecular	supramolecular	ADJ
eurjchem-2544	356	57	aggregates	aggregate	NOUN
eurjchem-2544	356	58	.	.	PUNCT
eurjchem-2544	357	1	the	the	DET
eurjchem-2544	357	2	diversity	diversity	NOUN
eurjchem-2544	357	3	in	in	ADP
eurjchem-2544	357	4	their	their	PRON
eurjchem-2544	357	5	coordination	coordination	NOUN
eurjchem-2544	357	6	modes	mode	NOUN
eurjchem-2544	357	7	is	be	AUX
eurjchem-2544	357	8	connected	connect	VERB
eurjchem-2544	357	9	to	to	ADP
eurjchem-2544	357	10	the	the	DET
eurjchem-2544	357	11	steric	steric	ADJ
eurjchem-2544	357	12	profile	profile	NOUN
eurjchem-2544	357	13	of	of	ADP
eurjchem-2544	357	14	the	the	DET
eurjchem-2544	357	15	carbamate	carbamate	NOUN
eurjchem-2544	357	16	n	n	NOUN
eurjchem-2544	357	17	substituents	substituent	NOUN
eurjchem-2544	357	18	on	on	ADP
eurjchem-2544	357	19	the	the	DET
eurjchem-2544	357	20	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	357	21	ligands	ligand	NOUN
eurjchem-2544	357	22	and	and	CCONJ
eurjchem-2544	357	23	the	the	DET
eurjchem-2544	357	24	trans	trans	PROPN
eurjchem-2544	357	25	effects	effect	NOUN
eurjchem-2544	357	26	of	of	ADP
eurjchem-2544	357	27	p	p	NOUN
eurjchem-2544	357	28	-	-	PUNCT
eurjchem-2544	357	29	ligands	ligand	NOUN
eurjchem-2544	357	30	other	other	ADJ
eurjchem-2544	357	31	than	than	ADP
eurjchem-2544	357	32	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	357	33	,	,	PUNCT
eurjchem-2544	357	34	pointing	point	VERB
eurjchem-2544	357	35	out	out	ADP
eurjchem-2544	357	36	the	the	DET
eurjchem-2544	357	37	importance	importance	NOUN
eurjchem-2544	357	38	of	of	ADP
eurjchem-2544	357	39	modifying	modify	VERB
eurjchem-2544	357	40	the	the	DET
eurjchem-2544	357	41	ligand	ligand	ADJ
eurjchem-2544	357	42	backbones	backbone	NOUN
eurjchem-2544	357	43	and	and	CCONJ
eurjchem-2544	357	44	coordination	coordination	NOUN
eurjchem-2544	357	45	spheres	sphere	NOUN
eurjchem-2544	357	46	(	(	PUNCT
eurjchem-2544	357	47	primary	primary	ADJ
eurjchem-2544	357	48	and	and	CCONJ
eurjchem-2544	357	49	secondary	secondary	ADJ
eurjchem-2544	357	50	)	)	PUNCT
eurjchem-2544	357	51	with	with	ADP
eurjchem-2544	357	52	the	the	DET
eurjchem-2544	357	53	aim	aim	NOUN
eurjchem-2544	357	54	of	of	ADP
eurjchem-2544	357	55	generating	generate	VERB
eurjchem-2544	357	56	different	different	ADJ
eurjchem-2544	357	57	structural	structural	ADJ
eurjchem-2544	357	58	platforms	platform	NOUN
eurjchem-2544	357	59	.	.	PUNCT
eurjchem-2544	358	1	the	the	DET
eurjchem-2544	358	2	continuous	continuous	ADJ
eurjchem-2544	358	3	determination	determination	NOUN
eurjchem-2544	358	4	of	of	ADP
eurjchem-2544	358	5	geometrical	geometrical	ADJ
eurjchem-2544	358	6	alignments	alignment	NOUN
eurjchem-2544	358	7	and	and	CCONJ
eurjchem-2544	358	8	structural	structural	ADJ
eurjchem-2544	358	9	types	type	NOUN
eurjchem-2544	358	10	in	in	ADP
eurjchem-2544	358	11	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	358	12	and	and	CCONJ
eurjchem-2544	358	13	their	their	PRON
eurjchem-2544	358	14	derivatives	derivative	NOUN
eurjchem-2544	358	15	no	no	ADV
eurjchem-2544	358	16	doubt	doubt	ADV
eurjchem-2544	358	17	increased	increase	VERB
eurjchem-2544	358	18	their	their	PRON
eurjchem-2544	358	19	utility	utility	NOUN
eurjchem-2544	358	20	in	in	ADP
eurjchem-2544	358	21	the	the	DET
eurjchem-2544	358	22	fields	field	NOUN
eurjchem-2544	358	23	of	of	ADP
eurjchem-2544	358	24	chemistry	chemistry	NOUN
eurjchem-2544	358	25	,	,	PUNCT
eurjchem-2544	358	26	biology	biology	NOUN
eurjchem-2544	358	27	,	,	PUNCT
eurjchem-2544	358	28	medicine	medicine	NOUN
eurjchem-2544	358	29	,	,	PUNCT
eurjchem-2544	358	30	and	and	CCONJ
eurjchem-2544	358	31	material	material	NOUN
eurjchem-2544	358	32	science	science	NOUN
eurjchem-2544	358	33	.	.	PUNCT
eurjchem-2544	359	1	acknowledgements	acknowledgement	NOUN
eurjchem-2544	359	2	ibukun	ibukun	PROPN
eurjchem-2544	359	3	oluwaseun	oluwaseun	PROPN
eurjchem-2544	359	4	shotonwa	shotonwa	ADJ
eurjchem-2544	359	5	thanks	thank	NOUN
eurjchem-2544	359	6	the	the	DET
eurjchem-2544	359	7	cambridge	cambridge	PROPN
eurjchem-2544	359	8	crystallographic	crystallographic	PROPN
eurjchem-2544	359	9	data	data	PROPN
eurjchem-2544	359	10	center	center	PROPN
eurjchem-2544	359	11	(	(	PUNCT
eurjchem-2544	359	12	ccdc	ccdc	PROPN
eurjchem-2544	359	13	)	)	PUNCT
eurjchem-2544	359	14	for	for	ADP
eurjchem-2544	359	15	providing	provide	VERB
eurjchem-2544	359	16	access	access	NOUN
eurjchem-2544	359	17	to	to	ADP
eurjchem-2544	359	18	the	the	DET
eurjchem-2544	359	19	cambridge	cambridge	PROPN
eurjchem-2544	359	20	structural	structural	ADJ
eurjchem-2544	359	21	database	database	NOUN
eurjchem-2544	359	22	(	(	PUNCT
eurjchem-2544	359	23	csd	csd	PROPN
eurjchem-2544	359	24	)	)	PUNCT
eurjchem-2544	359	25	through	through	ADP
eurjchem-2544	359	26	the	the	DET
eurjchem-2544	359	27	csd	csd	NOUN
eurjchem-2544	359	28	-	-	PUNCT
eurjchem-2544	359	29	enterprise	enterprise	NOUN
eurjchem-2544	359	30	under	under	ADP
eurjchem-2544	359	31	the	the	DET
eurjchem-2544	359	32	frank	frank	PROPN
eurjchem-2544	359	33	h.	h.	PROPN
eurjchem-2544	359	34	allen	allen	PROPN
eurjchem-2544	359	35	international	international	PROPN
eurjchem-2544	359	36	research	research	PROPN
eurjchem-2544	359	37	and	and	CCONJ
eurjchem-2544	359	38	educational	educational	ADJ
eurjchem-2544	359	39	(	(	PUNCT
eurjchem-2544	359	40	faire	faire	X
eurjchem-2544	359	41	)	)	PUNCT
eurjchem-2544	359	42	grant	grant	NOUN
eurjchem-2544	359	43	(	(	PUNCT
eurjchem-2544	359	44	21188	21188	NUM
eurjchem-2544	359	45	)	)	PUNCT
eurjchem-2544	359	46	and	and	CCONJ
eurjchem-2544	359	47	the	the	DET
eurjchem-2544	359	48	institution	institution	NOUN
eurjchem-2544	359	49	-	-	PUNCT
eurjchem-2544	359	50	based	base	VERB
eurjchem-2544	359	51	research	research	NOUN
eurjchem-2544	359	52	intervention	intervention	NOUN
eurjchem-2544	359	53	of	of	ADP
eurjchem-2544	359	54	the	the	DET
eurjchem-2544	359	55	tertiary	tertiary	ADJ
eurjchem-2544	359	56	education	education	PROPN
eurjchem-2544	359	57	trust	trust	NOUN
eurjchem-2544	359	58	fund	fund	PROPN
eurjchem-2544	359	59	(	(	PUNCT
eurjchem-2544	359	60	tetfund	tetfund	NOUN
eurjchem-2544	359	61	)	)	PUNCT
eurjchem-2544	360	1	[	[	X
eurjchem-2544	360	2	6th	6th	ADJ
eurjchem-2544	360	3	batch	batch	NOUN
eurjchem-2544	360	4	research	research	NOUN
eurjchem-2544	360	5	project	project	NOUN
eurjchem-2544	360	6	(	(	PUNCT
eurjchem-2544	360	7	rp	rp	NOUN
eurjchem-2544	360	8	)	)	PUNCT
eurjchem-2544	360	9	disbursement	disbursement	NOUN
eurjchem-2544	360	10	]	]	PUNCT
eurjchem-2544	360	11	.	.	PUNCT
eurjchem-2544	361	1	disclosure	disclosure	NOUN
eurjchem-2544	361	2	statement	statement	NOUN
eurjchem-2544	361	3	conflict	conflict	NOUN
eurjchem-2544	361	4	of	of	ADP
eurjchem-2544	361	5	interest	interest	NOUN
eurjchem-2544	361	6	:	:	PUNCT
eurjchem-2544	361	7	the	the	DET
eurjchem-2544	361	8	authors	author	NOUN
eurjchem-2544	361	9	declare	declare	VERB
eurjchem-2544	361	10	that	that	SCONJ
eurjchem-2544	361	11	they	they	PRON
eurjchem-2544	361	12	have	have	VERB
eurjchem-2544	361	13	no	no	DET
eurjchem-2544	361	14	conflict	conflict	NOUN
eurjchem-2544	361	15	of	of	ADP
eurjchem-2544	361	16	interest	interest	NOUN
eurjchem-2544	361	17	in	in	ADP
eurjchem-2544	361	18	this	this	DET
eurjchem-2544	361	19	work	work	NOUN
eurjchem-2544	361	20	.	.	PUNCT
eurjchem-2544	362	1	ethical	ethical	ADJ
eurjchem-2544	362	2	approval	approval	NOUN
eurjchem-2544	362	3	:	:	PUNCT
eurjchem-2544	363	1	all	all	DET
eurjchem-2544	363	2	ethical	ethical	ADJ
eurjchem-2544	363	3	guidelines	guideline	NOUN
eurjchem-2544	363	4	have	have	AUX
eurjchem-2544	363	5	been	be	AUX
eurjchem-2544	363	6	strictly	strictly	ADV
eurjchem-2544	363	7	adhered	adhere	VERB
eurjchem-2544	363	8	to	to	ADP
eurjchem-2544	363	9	.	.	PUNCT
eurjchem-2544	364	1	sample	sample	NOUN
eurjchem-2544	364	2	availability	availability	NOUN
eurjchem-2544	364	3	:	:	PUNCT
eurjchem-2544	364	4	samples	sample	NOUN
eurjchem-2544	364	5	of	of	ADP
eurjchem-2544	364	6	crystals	crystal	NOUN
eurjchem-2544	364	7	are	be	AUX
eurjchem-2544	364	8	not	not	PART
eurjchem-2544	364	9	available	available	ADJ
eurjchem-2544	364	10	from	from	ADP
eurjchem-2544	364	11	the	the	DET
eurjchem-2544	364	12	author(s	author(s	NOUN
eurjchem-2544	364	13	)	)	PUNCT
eurjchem-2544	364	14	.	.	PUNCT
eurjchem-2544	365	1	credit	credit	NOUN
eurjchem-2544	365	2	authorship	authorship	NOUN
eurjchem-2544	365	3	contribution	contribution	NOUN
eurjchem-2544	365	4	statement	statement	NOUN
eurjchem-2544	365	5	conceptualization	conceptualization	NOUN
eurjchem-2544	365	6	:	:	PUNCT
eurjchem-2544	365	7	ibukun	ibukun	NOUN
eurjchem-2544	365	8	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	9	shotonwa	shotonwa	ADJ
eurjchem-2544	365	10	;	;	PUNCT
eurjchem-2544	365	11	methodology	methodology	NOUN
eurjchem-2544	365	12	:	:	PUNCT
eurjchem-2544	365	13	ibukun	ibukun	NOUN
eurjchem-2544	365	14	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	15	shotonwa	shotonwa	ADJ
eurjchem-2544	365	16	;	;	PUNCT
eurjchem-2544	365	17	software	software	NOUN
eurjchem-2544	365	18	:	:	PUNCT
eurjchem-2544	365	19	ibukun	ibukun	NOUN
eurjchem-2544	365	20	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	21	shotonwa	shotonwa	ADJ
eurjchem-2544	365	22	;	;	PUNCT
eurjchem-2544	365	23	validation	validation	NOUN
eurjchem-2544	365	24	:	:	PUNCT
eurjchem-2544	365	25	ibukun	ibukun	NOUN
eurjchem-2544	365	26	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	27	shotonwa	shotonwa	ADJ
eurjchem-2544	365	28	;	;	PUNCT
eurjchem-2544	365	29	formal	formal	ADJ
eurjchem-2544	365	30	analysis	analysis	NOUN
eurjchem-2544	365	31	:	:	PUNCT
eurjchem-2544	365	32	ibukun	ibukun	NOUN
eurjchem-2544	365	33	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	34	shotonwa	shotonwa	ADJ
eurjchem-2544	365	35	,	,	PUNCT
eurjchem-2544	365	36	adebayo	adebayo	PROPN
eurjchem-2544	365	37	ponle	ponle	PROPN
eurjchem-2544	365	38	oduwole	oduwole	PROPN
eurjchem-2544	365	39	,	,	PUNCT
eurjchem-2544	365	40	oluwapelumi	oluwapelumi	PROPN
eurjchem-2544	365	41	martin	martin	PROPN
eurjchem-2544	365	42	agosu	agosu	PROPN
eurjchem-2544	365	43	,	,	PUNCT
eurjchem-2544	365	44	abosede	abosede	NOUN
eurjchem-2544	365	45	funke	funke	PROPN
eurjchem-2544	365	46	yusuf	yusuf	PROPN
eurjchem-2544	365	47	,	,	PUNCT
eurjchem-2544	365	48	simeon	simeon	PROPN
eurjchem-2544	365	49	okechukwu	okechukwu	PROPN
eurjchem-2544	365	50	eze	eze	PROPN
eurjchem-2544	365	51	;	;	PUNCT
eurjchem-2544	365	52	investigation	investigation	NOUN
eurjchem-2544	365	53	:	:	PUNCT
eurjchem-2544	365	54	ibukun	ibukun	NOUN
eurjchem-2544	365	55	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	56	shotonwa	shotonwa	ADJ
eurjchem-2544	365	57	;	;	PUNCT
eurjchem-2544	365	58	resources	resource	NOUN
eurjchem-2544	365	59	:	:	PUNCT
eurjchem-2544	365	60	adebayo	adebayo	PROPN
eurjchem-2544	365	61	ponle	ponle	PROPN
eurjchem-2544	365	62	oduwole	oduwole	PROPN
eurjchem-2544	365	63	,	,	PUNCT
eurjchem-2544	365	64	oluwapelumi	oluwapelumi	PROPN
eurjchem-2544	365	65	martin	martin	PROPN
eurjchem-2544	365	66	agosu	agosu	PROPN
eurjchem-2544	365	67	,	,	PUNCT
eurjchem-2544	365	68	abosede	abosede	NOUN
eurjchem-2544	365	69	funke	funke	PROPN
eurjchem-2544	365	70	yusuf	yusuf	PROPN
eurjchem-2544	365	71	,	,	PUNCT
eurjchem-2544	365	72	simeon	simeon	PROPN
eurjchem-2544	365	73	okechukwu	okechukwu	PROPN
eurjchem-2544	365	74	eze	eze	PROPN
eurjchem-2544	365	75	;	;	PUNCT
eurjchem-2544	365	76	data	datum	NOUN
eurjchem-2544	365	77	curation	curation	NOUN
eurjchem-2544	365	78	:	:	PUNCT
eurjchem-2544	365	79	ibukun	ibukun	NOUN
eurjchem-2544	365	80	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	81	shotonwa	shotonwa	ADJ
eurjchem-2544	365	82	;	;	PUNCT
eurjchem-2544	365	83	writing	write	VERB
eurjchem-2544	365	84	original	original	ADJ
eurjchem-2544	365	85	draft	draft	NOUN
eurjchem-2544	365	86	:	:	PUNCT
eurjchem-2544	365	87	ibukun	ibukun	NOUN
eurjchem-2544	365	88	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	89	shotonwa	shotonwa	ADJ
eurjchem-2544	365	90	;	;	PUNCT
eurjchem-2544	365	91	writing	write	VERB
eurjchem-2544	365	92	review	review	NOUN
eurjchem-2544	365	93	and	and	CCONJ
eurjchem-2544	365	94	editing	editing	NOUN
eurjchem-2544	365	95	:	:	PUNCT
eurjchem-2544	365	96	ibukun	ibukun	NOUN
eurjchem-2544	365	97	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	98	shotonwa	shotonwa	ADJ
eurjchem-2544	365	99	,	,	PUNCT
eurjchem-2544	365	100	adebayo	adebayo	PROPN
eurjchem-2544	365	101	ponle	ponle	PROPN
eurjchem-2544	365	102	oduwole	oduwole	PROPN
eurjchem-2544	365	103	,	,	PUNCT
eurjchem-2544	365	104	oluwapelumi	oluwapelumi	PROPN
eurjchem-2544	365	105	martin	martin	PROPN
eurjchem-2544	365	106	agosu	agosu	PROPN
eurjchem-2544	365	107	,	,	PUNCT
eurjchem-2544	365	108	abosede	abosede	NOUN
eurjchem-2544	365	109	funke	funke	PROPN
eurjchem-2544	365	110	yusuf	yusuf	PROPN
eurjchem-2544	365	111	,	,	PUNCT
eurjchem-2544	365	112	simeon	simeon	PROPN
eurjchem-2544	365	113	okechukwu	okechukwu	PROPN
eurjchem-2544	365	114	eze	eze	PROPN
eurjchem-2544	365	115	;	;	PUNCT
eurjchem-2544	365	116	visualization	visualization	NOUN
eurjchem-2544	365	117	:	:	PUNCT
eurjchem-2544	365	118	adebayo	adebayo	PROPN
eurjchem-2544	365	119	ponle	ponle	PROPN
eurjchem-2544	365	120	oduwole	oduwole	PROPN
eurjchem-2544	365	121	,	,	PUNCT
eurjchem-2544	365	122	oluwapelumi	oluwapelumi	PROPN
eurjchem-2544	365	123	martin	martin	PROPN
eurjchem-2544	365	124	agosu	agosu	PROPN
eurjchem-2544	365	125	,	,	PUNCT
eurjchem-2544	365	126	abosede	abosede	NOUN
eurjchem-2544	365	127	funke	funke	PROPN
eurjchem-2544	365	128	yusuf	yusuf	PROPN
eurjchem-2544	365	129	,	,	PUNCT
eurjchem-2544	365	130	simeon	simeon	PROPN
eurjchem-2544	365	131	okechukwu	okechukwu	PROPN
eurjchem-2544	365	132	eze	eze	PROPN
eurjchem-2544	365	133	;	;	PUNCT
eurjchem-2544	365	134	funding	funding	NOUN
eurjchem-2544	365	135	acquisition	acquisition	NOUN
eurjchem-2544	365	136	:	:	PUNCT
eurjchem-2544	365	137	ibukun	ibukun	NOUN
eurjchem-2544	365	138	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	139	shotonwa	shotonwa	ADJ
eurjchem-2544	365	140	;	;	PUNCT
eurjchem-2544	365	141	supervision	supervision	NOUN
eurjchem-2544	365	142	:	:	PUNCT
eurjchem-2544	365	143	ibukun	ibukun	NOUN
eurjchem-2544	365	144	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	145	shotonwa	shotonwa	ADJ
eurjchem-2544	365	146	;	;	PUNCT
eurjchem-2544	365	147	project	project	NOUN
eurjchem-2544	365	148	administration	administration	NOUN
eurjchem-2544	365	149	:	:	PUNCT
eurjchem-2544	365	150	ibukun	ibukun	NOUN
eurjchem-2544	365	151	oluwaseun	oluwaseun	PROPN
eurjchem-2544	365	152	shotonwa	shotonwa	ADJ
eurjchem-2544	365	153	.	.	PUNCT
eurjchem-2544	366	1	orcid	orcid	NOUN
eurjchem-2544	366	2	and	and	CCONJ
eurjchem-2544	366	3	email	email	NOUN
eurjchem-2544	366	4	ibukun	ibukun	NOUN
eurjchem-2544	366	5	oluwaseun	oluwaseun	PROPN
eurjchem-2544	366	6	shotonwa	shotonwa	VERB
eurjchem-2544	366	7	ibukun.shotonwa@lasu.edu.ng	ibukun.shotonwa@lasu.edu.ng	PROPN
eurjchem-2544	366	8	https://orcid.org/0000-0002-5364-717x	https://orcid.org/0000-0002-5364-717x	PROPN
eurjchem-2544	366	9	adebayo	adebayo	PROPN
eurjchem-2544	366	10	ponle	ponle	PROPN
eurjchem-2544	366	11	oduwole	oduwole	PROPN
eurjchem-2544	366	12	peemine24@gmail.com	peemine24@gmail.com	PROPN
eurjchem-2544	366	13	https://orcid.org/0009-0009-6898-6906	https://orcid.org/0009-0009-6898-6906	PROPN
eurjchem-2544	366	14	oluwapelumi	oluwapelumi	PROPN
eurjchem-2544	366	15	martin	martin	PROPN
eurjchem-2544	366	16	agosu	agosu	PROPN
eurjchem-2544	366	17	agosumartino@gmail.com	agosumartino@gmail.com	PROPN
eurjchem-2544	367	1	https://orcid.org/0009-0005-8732-2495	https://orcid.org/0009-0005-8732-2495	PROPN
eurjchem-2544	367	2	abosede	abosede	PROPN
eurjchem-2544	367	3	funke	funke	PROPN
eurjchem-2544	367	4	yusuf	yusuf	PROPN
eurjchem-2544	367	5	abosedeyusuf95@gmail.com	abosedeyusuf95@gmail.com	PROPN
eurjchem-2544	367	6	https://orcid.org/0009-0007-6001-6257	https://orcid.org/0009-0007-6001-6257	PROPN
eurjchem-2544	367	7	simeon	simeon	PROPN
eurjchem-2544	367	8	okechukwu	okechukwu	NOUN
eurjchem-2544	367	9	eze	eze	VERB
eurjchem-2544	367	10	simonsokey20@gmail.com	simonsokey20@gmail.com	X
eurjchem-2544	367	11	https://orcid.org/0009-0001-6298-2367	https://orcid.org/0009-0001-6298-2367	NOUN
eurjchem-2544	367	12	references	reference	VERB
eurjchem-2544	367	13	[	[	X
eurjchem-2544	367	14	1	1	NUM
eurjchem-2544	367	15	]	]	PUNCT
eurjchem-2544	367	16	.	.	PUNCT
eurjchem-2544	368	1	odularu	odularu	PROPN
eurjchem-2544	368	2	,	,	PUNCT
eurjchem-2544	368	3	a.	a.	NOUN
eurjchem-2544	368	4	t.	t.	PROPN
eurjchem-2544	368	5	;	;	PUNCT
eurjchem-2544	368	6	ajibade	ajibade	PROPN
eurjchem-2544	368	7	,	,	PUNCT
eurjchem-2544	369	1	p.	p.	NOUN
eurjchem-2544	369	2	a.	a.	NOUN
eurjchem-2544	369	3	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	369	4	:	:	PUNCT
eurjchem-2544	369	5	challenges	challenge	NOUN
eurjchem-2544	369	6	,	,	PUNCT
eurjchem-2544	369	7	control	control	NOUN
eurjchem-2544	369	8	,	,	PUNCT
eurjchem-2544	369	9	and	and	CCONJ
eurjchem-2544	369	10	approaches	approach	NOUN
eurjchem-2544	369	11	to	to	ADP
eurjchem-2544	369	12	excellent	excellent	ADJ
eurjchem-2544	369	13	yield	yield	NOUN
eurjchem-2544	369	14	,	,	PUNCT
eurjchem-2544	369	15	characterization	characterization	NOUN
eurjchem-2544	369	16	,	,	PUNCT
eurjchem-2544	369	17	and	and	CCONJ
eurjchem-2544	369	18	their	their	PRON
eurjchem-2544	369	19	biological	biological	ADJ
eurjchem-2544	369	20	applications	application	NOUN
eurjchem-2544	369	21	.	.	PUNCT
eurjchem-2544	370	1	bioinorg	bioinorg	PROPN
eurjchem-2544	370	2	.	.	PROPN
eurjchem-2544	370	3	chem	chem	PROPN
eurjchem-2544	370	4	.	.	PUNCT
eurjchem-2544	371	1	appl	appl	PROPN
eurjchem-2544	371	2	.	.	PROPN
eurjchem-2544	372	1	2019	2019	NUM
eurjchem-2544	372	2	,	,	PUNCT
eurjchem-2544	372	3	2019	2019	NUM
eurjchem-2544	372	4	,	,	PUNCT
eurjchem-2544	372	5	1–15	1–15	NUM
eurjchem-2544	372	6	.	.	PUNCT
eurjchem-2544	373	1	[	[	X
eurjchem-2544	373	2	2	2	NUM
eurjchem-2544	373	3	]	]	PUNCT
eurjchem-2544	373	4	.	.	PUNCT
eurjchem-2544	373	5	hogarth	hogarth	PROPN
eurjchem-2544	373	6	,	,	PUNCT
eurjchem-2544	373	7	g.	g.	PROPN
eurjchem-2544	373	8	transition	transition	NOUN
eurjchem-2544	373	9	metal	metal	NOUN
eurjchem-2544	373	10	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	373	11	:	:	PUNCT
eurjchem-2544	373	12	1978–2003	1978–2003	NUM
eurjchem-2544	373	13	.	.	X
eurjchem-2544	373	14	progress	progress	NOUN
eurjchem-2544	373	15	in	in	ADP
eurjchem-2544	373	16	inorganic	inorganic	ADJ
eurjchem-2544	373	17	chemistry	chemistry	NOUN
eurjchem-2544	373	18	2005	2005	NUM
eurjchem-2544	373	19	,	,	PUNCT
eurjchem-2544	373	20	71–561	71–561	PROPN
eurjchem-2544	373	21	.	.	PUNCT
eurjchem-2544	374	1	[	[	X
eurjchem-2544	374	2	3	3	NUM
eurjchem-2544	374	3	]	]	PUNCT
eurjchem-2544	374	4	.	.	PUNCT
eurjchem-2544	375	1	adachi	adachi	PROPN
eurjchem-2544	375	2	,	,	PUNCT
eurjchem-2544	375	3	m.	m.	NOUN
eurjchem-2544	375	4	;	;	PUNCT
eurjchem-2544	375	5	kita	kita	PROPN
eurjchem-2544	375	6	,	,	PUNCT
eurjchem-2544	375	7	m.	m.	NOUN
eurjchem-2544	375	8	;	;	PUNCT
eurjchem-2544	375	9	kashiwabara	kashiwabara	PROPN
eurjchem-2544	375	10	,	,	PUNCT
eurjchem-2544	375	11	k.	k.	PROPN
eurjchem-2544	375	12	;	;	PUNCT
eurjchem-2544	375	13	fujita	fujita	PROPN
eurjchem-2544	375	14	,	,	PUNCT
eurjchem-2544	375	15	j.	j.	PROPN
eurjchem-2544	375	16	;	;	PUNCT
eurjchem-2544	375	17	iitaka	iitaka	ADV
eurjchem-2544	375	18	,	,	PUNCT
eurjchem-2544	375	19	n.	n.	PROPN
eurjchem-2544	375	20	;	;	PUNCT
eurjchem-2544	375	21	kurachi	kurachi	PROPN
eurjchem-2544	375	22	,	,	PUNCT
eurjchem-2544	375	23	s.	s.	PROPN
eurjchem-2544	375	24	;	;	PUNCT
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eurjchem-2544	375	26	,	,	PUNCT
eurjchem-2544	375	27	s.	s.	PROPN
eurjchem-2544	375	28	;	;	PUNCT
eurjchem-2544	375	29	jin	jin	NOUN
eurjchem-2544	375	30	,	,	PUNCT
eurjchem-2544	375	31	d.-m	d.-m	PROPN
eurjchem-2544	375	32	.	.	PUNCT
eurjchem-2544	376	1	preparation	preparation	NOUN
eurjchem-2544	376	2	and	and	CCONJ
eurjchem-2544	376	3	characterization	characterization	NOUN
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eurjchem-2544	376	5	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	376	6	)	)	PUNCT
eurjchem-2544	376	7	complexes	complex	NOUN
eurjchem-2544	376	8	containing	contain	VERB
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eurjchem-2544	376	10	(	(	PUNCT
eurjchem-2544	376	11	dppf	dppf	NOUN
eurjchem-2544	376	12	)	)	PUNCT
eurjchem-2544	376	13	or	or	CCONJ
eurjchem-2544	376	14	1,1′-bis(dimethylphosphino)ferrocene	1,1′-bis(dimethylphosphino)ferrocene	NUM
eurjchem-2544	376	15	(	(	PUNCT
eurjchem-2544	376	16	dmpf	dmpf	NOUN
eurjchem-2544	376	17	)	)	PUNCT
eurjchem-2544	376	18	as	as	ADP
eurjchem-2544	376	19	a	a	DET
eurjchem-2544	376	20	bidentate	bidentate	NOUN
eurjchem-2544	376	21	ligand	ligand	NOUN
eurjchem-2544	376	22	,	,	PUNCT
eurjchem-2544	376	23	and	and	CCONJ
eurjchem-2544	376	24	molecular	molecular	ADJ
eurjchem-2544	376	25	structures	structure	NOUN
eurjchem-2544	376	26	of	of	ADP
eurjchem-2544	376	27	[	[	X
eurjchem-2544	376	28	co(acac)2(dmpf)]b(c6h5)4	co(acac)2(dmpf)]b(c6h5)4	PROPN
eurjchem-2544	376	29	and	and	CCONJ
eurjchem-2544	376	30	[	[	X
eurjchem-2544	376	31	co(dtc)2(dmpf)]b(c6h5)4	co(dtc)2(dmpf)]b(c6h5)4	X
eurjchem-2544	376	32	(	(	PUNCT
eurjchem-2544	376	33	acac	acac	ADJ
eurjchem-2544	376	34	=	=	PUNCT
eurjchem-2544	376	35	2,4	2,4	NUM
eurjchem-2544	376	36	-	-	PUNCT
eurjchem-2544	376	37	pentanedionate	pentanedionate	NOUN
eurjchem-2544	376	38	ion	ion	NOUN
eurjchem-2544	376	39	,	,	PUNCT
eurjchem-2544	376	40	dtc	dtc	NOUN
eurjchem-2544	376	41	=	=	SYM
eurjchem-2544	376	42	dimethyldithiocarbamate	dimethyldithiocarbamate	NOUN
eurjchem-2544	376	43	ion	ion	NOUN
eurjchem-2544	376	44	)	)	PUNCT
eurjchem-2544	376	45	.	.	PUNCT
eurjchem-2544	377	1	bull	bull	NOUN
eurjchem-2544	377	2	.	.	PUNCT
eurjchem-2544	378	1	chem	chem	PROPN
eurjchem-2544	378	2	.	.	PUNCT
eurjchem-2544	379	1	soc	soc	PROPN
eurjchem-2544	379	2	.	.	PUNCT
eurjchem-2544	380	1	jpn	jpn	PROPN
eurjchem-2544	380	2	.	.	PROPN
eurjchem-2544	380	3	1992	1992	NUM
eurjchem-2544	380	4	,	,	PUNCT
eurjchem-2544	380	5	65	65	NUM
eurjchem-2544	380	6	,	,	PUNCT
eurjchem-2544	380	7	2037	2037	NUM
eurjchem-2544	380	8	–	–	PUNCT
eurjchem-2544	380	9	2044	2044	NUM
eurjchem-2544	380	10	.	.	PUNCT
eurjchem-2544	381	1	[	[	X
eurjchem-2544	381	2	4	4	NUM
eurjchem-2544	381	3	]	]	PUNCT
eurjchem-2544	381	4	.	.	PUNCT
eurjchem-2544	381	5	matsui	matsui	PROPN
eurjchem-2544	381	6	,	,	PUNCT
eurjchem-2544	381	7	h.	h.	PROPN
eurjchem-2544	381	8	;	;	PUNCT
eurjchem-2544	381	9	kita	kita	PROPN
eurjchem-2544	381	10	,	,	PUNCT
eurjchem-2544	381	11	m.	m.	NOUN
eurjchem-2544	381	12	;	;	PUNCT
eurjchem-2544	381	13	kashiwabara	kashiwabara	PROPN
eurjchem-2544	381	14	,	,	PUNCT
eurjchem-2544	381	15	k.	k.	PROPN
eurjchem-2544	381	16	;	;	PUNCT
eurjchem-2544	381	17	fujita	fujita	PROPN
eurjchem-2544	381	18	,	,	PUNCT
eurjchem-2544	381	19	j.	j.	PROPN
eurjchem-2544	381	20	preparation	preparation	NOUN
eurjchem-2544	381	21	and	and	CCONJ
eurjchem-2544	381	22	characterization	characterization	NOUN
eurjchem-2544	381	23	of	of	ADP
eurjchem-2544	381	24	dithiocarbamatocobalt(iii	dithiocarbamatocobalt(iii	NOUN
eurjchem-2544	381	25	)	)	PUNCT
eurjchem-2544	381	26	complexes	complex	NOUN
eurjchem-2544	381	27	containing	contain	VERB
eurjchem-2544	381	28	phosphites	phosphite	NOUN
eurjchem-2544	381	29	,	,	PUNCT
eurjchem-2544	381	30	and	and	CCONJ
eurjchem-2544	381	31	molecular	molecular	ADJ
eurjchem-2544	381	32	structures	structure	NOUN
eurjchem-2544	381	33	of	of	ADP
eurjchem-2544	381	34	cis-[co(ch3)2(ncs2)2	cis-[co(ch3)2(ncs2)2	ADJ
eurjchem-2544	381	35	p(och2)3c(c2h5)2]bf4	p(och2)3c(c2h5)2]bf4	PROPN
eurjchem-2544	381	36	and	and	CCONJ
eurjchem-2544	381	37	[	[	PUNCT
eurjchem-2544	381	38	co(ch2ch2ch2ch2ch2ncs2){p(och3)3}4	co(ch2ch2ch2ch2ch2ncs2){p(och3)3}4	X
eurjchem-2544	381	39	]	]	PUNCT
eurjchem-2544	381	40	(	(	PUNCT
eurjchem-2544	381	41	bf4)2	bf4)2	PROPN
eurjchem-2544	381	42	.	.	PUNCT
eurjchem-2544	382	1	bull	bull	NOUN
eurjchem-2544	382	2	.	.	PUNCT
eurjchem-2544	383	1	chem	chem	PROPN
eurjchem-2544	383	2	.	.	PUNCT
eurjchem-2544	384	1	soc	soc	PROPN
eurjchem-2544	384	2	.	.	PUNCT
eurjchem-2544	385	1	jpn	jpn	PROPN
eurjchem-2544	385	2	.	.	PROPN
eurjchem-2544	385	3	1993	1993	NUM
eurjchem-2544	385	4	,	,	PUNCT
eurjchem-2544	385	5	66	66	NUM
eurjchem-2544	385	6	,	,	PUNCT
eurjchem-2544	385	7	1140–1148	1140–1148	NUM
eurjchem-2544	385	8	.	.	PUNCT
eurjchem-2544	386	1	[	[	X
eurjchem-2544	386	2	5	5	NUM
eurjchem-2544	386	3	]	]	PUNCT
eurjchem-2544	386	4	.	.	PUNCT
eurjchem-2544	387	1	suzuki	suzuki	PROPN
eurjchem-2544	387	2	,	,	PUNCT
eurjchem-2544	387	3	t.	t.	PROPN
eurjchem-2544	387	4	;	;	PUNCT
eurjchem-2544	387	5	iwatsuki	iwatsuki	PROPN
eurjchem-2544	387	6	,	,	PUNCT
eurjchem-2544	387	7	s.	s.	PROPN
eurjchem-2544	387	8	;	;	PUNCT
eurjchem-2544	387	9	takagi	takagi	PROPN
eurjchem-2544	387	10	,	,	PUNCT
eurjchem-2544	387	11	h.	h.	PROPN
eurjchem-2544	387	12	d.	d.	PROPN
eurjchem-2544	387	13	;	;	PUNCT
eurjchem-2544	387	14	kashiwabara	kashiwabara	PROPN
eurjchem-2544	387	15	,	,	PUNCT
eurjchem-2544	387	16	k.	k.	PROPN
eurjchem-2544	388	1	a	a	DET
eurjchem-2544	388	2	geometrical	geometrical	ADJ
eurjchem-2544	388	3	isomeric	isomeric	ADJ
eurjchem-2544	388	4	pair	pair	NOUN
eurjchem-2544	388	5	of	of	ADP
eurjchem-2544	388	6	novel	novel	ADJ
eurjchem-2544	388	7	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	388	8	)	)	PUNCT
eurjchem-2544	388	9	complexes	complex	NOUN
eurjchem-2544	388	10	containing	contain	VERB
eurjchem-2544	388	11	diphenyl	diphenyl	NOUN
eurjchem-2544	388	12	phosphine	phosphine	NOUN
eurjchem-2544	388	13	:	:	PUNCT
eurjchem-2544	388	14	cisand	cisand	ADV
eurjchem-2544	388	15	trans-[co(dtc)2(phph2)2]bf4	trans-[co(dtc)2(phph2)2]bf4	PROPN
eurjchem-2544	388	16	(	(	PUNCT
eurjchem-2544	388	17	dtc	dtc	NOUN
eurjchem-2544	388	18	=	=	SYM
eurjchem-2544	388	19	n	n	CCONJ
eurjchem-2544	388	20	,	,	PUNCT
eurjchem-2544	388	21	ndimethyldithiocarbamate	ndimethyldithiocarbamate	ADJ
eurjchem-2544	388	22	)	)	PUNCT
eurjchem-2544	388	23	.	.	PUNCT
eurjchem-2544	389	1	chem	chem	PROPN
eurjchem-2544	389	2	.	.	PUNCT
eurjchem-2544	390	1	lett	lett	PROPN
eurjchem-2544	390	2	.	.	PUNCT
eurjchem-2544	391	1	2001	2001	NUM
eurjchem-2544	391	2	,	,	PUNCT
eurjchem-2544	391	3	30	30	NUM
eurjchem-2544	391	4	,	,	PUNCT
eurjchem-2544	391	5	1068–1069	1068–1069	NUM
eurjchem-2544	391	6	.	.	PUNCT
eurjchem-2544	392	1	[	[	X
eurjchem-2544	392	2	6	6	NUM
eurjchem-2544	392	3	]	]	PUNCT
eurjchem-2544	392	4	.	.	PUNCT
eurjchem-2544	393	1	suzuki	suzuki	PROPN
eurjchem-2544	393	2	,	,	PUNCT
eurjchem-2544	393	3	t.	t.	PROPN
eurjchem-2544	393	4	;	;	PUNCT
eurjchem-2544	393	5	kashiwamura	kashiwamura	PROPN
eurjchem-2544	393	6	,	,	PUNCT
eurjchem-2544	393	7	s.	s.	PROPN
eurjchem-2544	393	8	;	;	PUNCT
eurjchem-2544	393	9	kashiwabara	kashiwabara	PROPN
eurjchem-2544	393	10	,	,	PUNCT
eurjchem-2544	393	11	k.	k.	PROPN
eurjchem-2544	393	12	preparation	preparation	PROPN
eurjchem-2544	393	13	,	,	PUNCT
eurjchem-2544	393	14	crystal	crystal	NOUN
eurjchem-2544	393	15	structures	structure	NOUN
eurjchem-2544	393	16	and	and	CCONJ
eurjchem-2544	393	17	spectroscopic	spectroscopic	ADJ
eurjchem-2544	393	18	properties	property	NOUN
eurjchem-2544	393	19	of	of	ADP
eurjchem-2544	393	20	a	a	DET
eurjchem-2544	393	21	series	series	NOUN
eurjchem-2544	393	22	of	of	ADP
eurjchem-2544	393	23	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	393	24	)	)	PUNCT
eurjchem-2544	393	25	phosphine	phosphine	NOUN
eurjchem-2544	393	26	complexes	complex	NOUN
eurjchem-2544	393	27	:	:	PUNCT
eurjchem-2544	393	28	transand	transand	NOUN
eurjchem-2544	393	29	cis-[co(dtc)2(pme3−nphn)2]+	cis-[co(dtc)2(pme3−nphn)2]+	X
eurjchem-2544	393	30	(	(	PUNCT
eurjchem-2544	393	31	dtc	dtc	NOUN
eurjchem-2544	393	32	=	=	SYM
eurjchem-2544	393	33	n	n	CCONJ
eurjchem-2544	393	34	,	,	PUNCT
eurjchem-2544	393	35	n	n	CCONJ
eurjchem-2544	393	36	-	-	PUNCT
eurjchem-2544	393	37	dimethyldithiocarbamate	dimethyldithiocarbamate	NOUN
eurjchem-2544	393	38	;	;	PUNCT
eurjchem-2544	393	39	n	n	NOUN
eurjchem-2544	393	40	=	=	SYM
eurjchem-2544	393	41	0	0	NUM
eurjchem-2544	393	42	,	,	PUNCT
eurjchem-2544	393	43	1	1	NUM
eurjchem-2544	393	44	,	,	PUNCT
eurjchem-2544	393	45	2	2	NUM
eurjchem-2544	393	46	or	or	CCONJ
eurjchem-2544	393	47	3	3	NUM
eurjchem-2544	393	48	)	)	PUNCT
eurjchem-2544	393	49	.	.	PUNCT
eurjchem-2544	394	1	bull	bull	NOUN
eurjchem-2544	394	2	.	.	PUNCT
eurjchem-2544	395	1	chem	chem	PROPN
eurjchem-2544	395	2	.	.	PUNCT
eurjchem-2544	396	1	soc	soc	PROPN
eurjchem-2544	396	2	.	.	PUNCT
eurjchem-2544	397	1	jpn	jpn	PROPN
eurjchem-2544	397	2	.	.	PROPN
eurjchem-2544	397	3	2001	2001	NUM
eurjchem-2544	397	4	,	,	PUNCT
eurjchem-2544	397	5	74	74	NUM
eurjchem-2544	397	6	,	,	PUNCT
eurjchem-2544	397	7	2349–2359	2349–2359	NOUN
eurjchem-2544	397	8	.	.	PUNCT
eurjchem-2544	398	1	[	[	X
eurjchem-2544	398	2	7	7	NUM
eurjchem-2544	398	3	]	]	PUNCT
eurjchem-2544	398	4	.	.	PUNCT
eurjchem-2544	399	1	iwatsuki	iwatsuki	PROPN
eurjchem-2544	399	2	,	,	PUNCT
eurjchem-2544	399	3	s.	s.	PROPN
eurjchem-2544	399	4	;	;	PUNCT
eurjchem-2544	399	5	suzuki	suzuki	PROPN
eurjchem-2544	399	6	,	,	PUNCT
eurjchem-2544	399	7	t.	t.	PROPN
eurjchem-2544	399	8	;	;	PUNCT
eurjchem-2544	399	9	hasegawa	hasegawa	PROPN
eurjchem-2544	399	10	,	,	PUNCT
eurjchem-2544	399	11	a.	a.	NOUN
eurjchem-2544	399	12	;	;	PUNCT
eurjchem-2544	399	13	funahashi	funahashi	PROPN
eurjchem-2544	399	14	,	,	PUNCT
eurjchem-2544	399	15	s.	s.	PROPN
eurjchem-2544	399	16	;	;	PUNCT
eurjchem-2544	399	17	kashiwabara	kashiwabara	PROPN
eurjchem-2544	399	18	,	,	PUNCT
eurjchem-2544	399	19	k.	k.	PROPN
eurjchem-2544	399	20	;	;	PUNCT
eurjchem-2544	399	21	takagi	takagi	PROPN
eurjchem-2544	399	22	,	,	PUNCT
eurjchem-2544	399	23	h.	h.	PROPN
eurjchem-2544	399	24	d.	d.	PROPN
eurjchem-2544	399	25	preparation	preparation	PROPN
eurjchem-2544	399	26	,	,	PUNCT
eurjchem-2544	399	27	crystal	crystal	NOUN
eurjchem-2544	399	28	structures	structure	NOUN
eurjchem-2544	399	29	and	and	CCONJ
eurjchem-2544	399	30	isomerization	isomerization	NOUN
eurjchem-2544	399	31	kinetics	kinetic	NOUN
eurjchem-2544	399	32	of	of	ADP
eurjchem-2544	399	33	cisand	cisand	PROPN
eurjchem-2544	399	34	trans-[co(dtc)2(phph2)2]+	trans-[co(dtc)2(phph2)2]+	PROPN
eurjchem-2544	399	35	:	:	PUNCT
eurjchem-2544	399	36	thermodynamically	thermodynamically	ADV
eurjchem-2544	399	37	and	and	CCONJ
eurjchem-2544	399	38	kinetically	kinetically	ADV
eurjchem-2544	399	39	stable	stable	ADJ
eurjchem-2544	399	40	cobalt(iii)–p	cobalt(iii)–p	PROPN
eurjchem-2544	399	41	bonds	bond	NOUN
eurjchem-2544	399	42	through	through	ADP
eurjchem-2544	399	43	interplay	interplay	NOUN
eurjchem-2544	399	44	of	of	ADP
eurjchem-2544	399	45	σ	σ	NOUN
eurjchem-2544	399	46	-	-	PUNCT
eurjchem-2544	399	47	donicity	donicity	NOUN
eurjchem-2544	399	48	,	,	PUNCT
eurjchem-2544	399	49	π	π	NOUN
eurjchem-2544	399	50	-	-	NOUN
eurjchem-2544	399	51	acidity	acidity	NOUN
eurjchem-2544	399	52	,	,	PUNCT
eurjchem-2544	399	53	and	and	CCONJ
eurjchem-2544	399	54	steric	steric	ADJ
eurjchem-2544	399	55	bulkiness	bulkiness	NOUN
eurjchem-2544	399	56	.	.	PUNCT
eurjchem-2544	400	1	j.	j.	PROPN
eurjchem-2544	400	2	chem	chem	PROPN
eurjchem-2544	400	3	.	.	PUNCT
eurjchem-2544	401	1	soc	soc	PROPN
eurjchem-2544	401	2	.	.	PUNCT
eurjchem-2544	402	1	2002	2002	NUM
eurjchem-2544	402	2	,	,	PUNCT
eurjchem-2544	402	3	3593–3602	3593–3602	NUM
eurjchem-2544	402	4	.	.	PUNCT
eurjchem-2544	403	1	[	[	X
eurjchem-2544	403	2	8	8	NUM
eurjchem-2544	403	3	]	]	PUNCT
eurjchem-2544	403	4	.	.	PUNCT
eurjchem-2544	404	1	brennan	brennan	PROPN
eurjchem-2544	404	2	,	,	PUNCT
eurjchem-2544	404	3	t.	t.	PROPN
eurjchem-2544	404	4	;	;	PUNCT
eurjchem-2544	404	5	bernal	bernal	PROPN
eurjchem-2544	404	6	,	,	PUNCT
eurjchem-2544	404	7	i.	i.	NOUN
eurjchem-2544	404	8	crystal	crystal	PROPN
eurjchem-2544	404	9	and	and	CCONJ
eurjchem-2544	404	10	molecular	molecular	ADJ
eurjchem-2544	404	11	structure	structure	NOUN
eurjchem-2544	404	12	of	of	ADP
eurjchem-2544	404	13	tris(diethyldithiocarbamato)cobalt(iii	tris(diethyldithiocarbamato)cobalt(iii	NOUN
eurjchem-2544	404	14	)	)	PUNCT
eurjchem-2544	404	15	.	.	PUNCT
eurjchem-2544	405	1	j.	j.	PROPN
eurjchem-2544	405	2	phys	phys	PROPN
eurjchem-2544	405	3	.	.	PUNCT
eurjchem-2544	406	1	chem	chem	PROPN
eurjchem-2544	406	2	.	.	PUNCT
eurjchem-2544	407	1	1969	1969	NUM
eurjchem-2544	407	2	,	,	PUNCT
eurjchem-2544	407	3	73	73	NUM
eurjchem-2544	407	4	,	,	PUNCT
eurjchem-2544	407	5	443	443	NUM
eurjchem-2544	407	6	–	–	PUNCT
eurjchem-2544	407	7	445	445	NUM
eurjchem-2544	407	8	.	.	PUNCT
eurjchem-2544	408	1	[	[	X
eurjchem-2544	408	2	9	9	NUM
eurjchem-2544	408	3	]	]	PUNCT
eurjchem-2544	408	4	.	.	PUNCT
eurjchem-2544	409	1	kaul	kaul	PROPN
eurjchem-2544	409	2	,	,	PUNCT
eurjchem-2544	409	3	l.	l.	PROPN
eurjchem-2544	409	4	;	;	PUNCT
eurjchem-2544	409	5	süss	süss	PROPN
eurjchem-2544	409	6	,	,	PUNCT
eurjchem-2544	409	7	r.	r.	PROPN
eurjchem-2544	409	8	;	;	PUNCT
eurjchem-2544	409	9	zannettino	zannettino	PROPN
eurjchem-2544	409	10	,	,	PUNCT
eurjchem-2544	409	11	a.	a.	NOUN
eurjchem-2544	409	12	;	;	PUNCT
eurjchem-2544	409	13	richter	richter	PROPN
eurjchem-2544	409	14	,	,	PUNCT
eurjchem-2544	409	15	k.	k.	PROPN
eurjchem-2544	410	1	the	the	DET
eurjchem-2544	410	2	revival	revival	NOUN
eurjchem-2544	410	3	of	of	ADP
eurjchem-2544	410	4	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	410	5	:	:	PUNCT
eurjchem-2544	410	6	from	from	ADP
eurjchem-2544	410	7	pesticides	pesticide	NOUN
eurjchem-2544	410	8	to	to	ADP
eurjchem-2544	410	9	innovative	innovative	ADJ
eurjchem-2544	410	10	medical	medical	ADJ
eurjchem-2544	410	11	treatments	treatment	NOUN
eurjchem-2544	410	12	.	.	PUNCT
eurjchem-2544	411	1	iscience	iscience	NOUN
eurjchem-2544	411	2	2021	2021	NUM
eurjchem-2544	411	3	,	,	PUNCT
eurjchem-2544	411	4	24	24	NUM
eurjchem-2544	411	5	,	,	PUNCT
eurjchem-2544	411	6	102092	102092	NUM
eurjchem-2544	411	7	.	.	PUNCT
eurjchem-2544	412	1	[	[	X
eurjchem-2544	412	2	10	10	NUM
eurjchem-2544	412	3	]	]	PUNCT
eurjchem-2544	412	4	.	.	PUNCT
eurjchem-2544	413	1	ajiboye	ajiboye	PROPN
eurjchem-2544	413	2	,	,	PUNCT
eurjchem-2544	413	3	t.	t.	PROPN
eurjchem-2544	413	4	o.	o.	PROPN
eurjchem-2544	413	5	;	;	PUNCT
eurjchem-2544	413	6	ajiboye	ajiboye	VERB
eurjchem-2544	413	7	,	,	PUNCT
eurjchem-2544	413	8	t.	t.	PROPN
eurjchem-2544	413	9	t.	t.	PROPN
eurjchem-2544	413	10	;	;	PUNCT
eurjchem-2544	413	11	marzouki	marzouki	PROPN
eurjchem-2544	413	12	,	,	PUNCT
eurjchem-2544	413	13	r.	r.	PROPN
eurjchem-2544	413	14	;	;	PUNCT
eurjchem-2544	413	15	onwudiwe	onwudiwe	NOUN
eurjchem-2544	413	16	,	,	PUNCT
eurjchem-2544	413	17	d.	d.	PROPN
eurjchem-2544	413	18	c.	c.	PROPN
eurjchem-2544	414	1	the	the	DET
eurjchem-2544	414	2	versatility	versatility	NOUN
eurjchem-2544	414	3	in	in	ADP
eurjchem-2544	414	4	the	the	DET
eurjchem-2544	414	5	applications	application	NOUN
eurjchem-2544	414	6	of	of	ADP
eurjchem-2544	414	7	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	414	8	.	.	PUNCT
eurjchem-2544	415	1	int	int	NOUN
eurjchem-2544	415	2	.	.	PUNCT
eurjchem-2544	416	1	j.	j.	PROPN
eurjchem-2544	416	2	mol	mol	PROPN
eurjchem-2544	416	3	.	.	PUNCT
eurjchem-2544	417	1	sci	sci	PROPN
eurjchem-2544	417	2	.	.	PROPN
eurjchem-2544	417	3	2022	2022	NUM
eurjchem-2544	417	4	,	,	PUNCT
eurjchem-2544	417	5	23	23	NUM
eurjchem-2544	417	6	,	,	PUNCT
eurjchem-2544	417	7	1317	1317	NUM
eurjchem-2544	417	8	.	.	PUNCT
eurjchem-2544	418	1	[	[	X
eurjchem-2544	418	2	11	11	NUM
eurjchem-2544	418	3	]	]	PUNCT
eurjchem-2544	418	4	.	.	PUNCT
eurjchem-2544	418	5	campanale	campanale	PROPN
eurjchem-2544	418	6	,	,	PUNCT
eurjchem-2544	418	7	c.	c.	NOUN
eurjchem-2544	418	8	;	;	PUNCT
eurjchem-2544	418	9	triozzi	triozzi	NOUN
eurjchem-2544	418	10	,	,	PUNCT
eurjchem-2544	418	11	m.	m.	NOUN
eurjchem-2544	418	12	;	;	PUNCT
eurjchem-2544	418	13	ragonese	ragonese	PROPN
eurjchem-2544	418	14	,	,	PUNCT
eurjchem-2544	418	15	a.	a.	NOUN
eurjchem-2544	418	16	;	;	PUNCT
eurjchem-2544	418	17	losacco	losacco	PROPN
eurjchem-2544	418	18	,	,	PUNCT
eurjchem-2544	418	19	d.	d.	PROPN
eurjchem-2544	418	20	;	;	PUNCT
eurjchem-2544	418	21	massarelli	massarelli	PROPN
eurjchem-2544	418	22	,	,	PUNCT
eurjchem-2544	418	23	c.	c.	PROPN
eurjchem-2544	418	24	dithiocarbamates	dithiocarbamates	PROPN
eurjchem-2544	418	25	:	:	PUNCT
eurjchem-2544	418	26	properties	property	NOUN
eurjchem-2544	418	27	,	,	PUNCT
eurjchem-2544	418	28	methodological	methodological	ADJ
eurjchem-2544	418	29	approaches	approach	NOUN
eurjchem-2544	418	30	and	and	CCONJ
eurjchem-2544	418	31	challenges	challenge	NOUN
eurjchem-2544	418	32	to	to	ADP
eurjchem-2544	418	33	their	their	PRON
eurjchem-2544	418	34	control	control	NOUN
eurjchem-2544	418	35	.	.	PUNCT
eurjchem-2544	419	1	toxics	toxic	NOUN
eurjchem-2544	419	2	2023	2023	NUM
eurjchem-2544	419	3	,	,	PUNCT
eurjchem-2544	419	4	11	11	NUM
eurjchem-2544	419	5	,	,	PUNCT
eurjchem-2544	419	6	851	851	NUM
eurjchem-2544	419	7	.	.	PUNCT
eurjchem-2544	420	1	[	[	X
eurjchem-2544	420	2	12	12	NUM
eurjchem-2544	420	3	]	]	PUNCT
eurjchem-2544	420	4	.	.	PUNCT
eurjchem-2544	421	1	jian	jian	PROPN
eurjchem-2544	421	2	,	,	PUNCT
eurjchem-2544	421	3	f.	f.	PROPN
eurjchem-2544	421	4	;	;	PUNCT
eurjchem-2544	421	5	bei	bei	PROPN
eurjchem-2544	421	6	,	,	PUNCT
eurjchem-2544	421	7	f.	f.	PROPN
eurjchem-2544	421	8	;	;	PUNCT
eurjchem-2544	421	9	zhao	zhao	PROPN
eurjchem-2544	421	10	,	,	PUNCT
eurjchem-2544	421	11	p.	p.	PROPN
eurjchem-2544	421	12	;	;	PUNCT
eurjchem-2544	421	13	wang	wang	PROPN
eurjchem-2544	421	14	,	,	PUNCT
eurjchem-2544	421	15	x.	x.	NOUN
eurjchem-2544	421	16	;	;	PUNCT
eurjchem-2544	421	17	fun	fun	NOUN
eurjchem-2544	421	18	,	,	PUNCT
eurjchem-2544	421	19	h.	h.	PROPN
eurjchem-2544	421	20	;	;	PUNCT
eurjchem-2544	421	21	chinnakali	chinnakali	PROPN
eurjchem-2544	421	22	,	,	PUNCT
eurjchem-2544	421	23	k.	k.	NOUN
eurjchem-2544	421	24	synthesis	synthesis	PROPN
eurjchem-2544	421	25	,	,	PUNCT
eurjchem-2544	421	26	crystal	crystal	NOUN
eurjchem-2544	421	27	structure	structure	NOUN
eurjchem-2544	421	28	and	and	CCONJ
eurjchem-2544	421	29	stability	stability	NOUN
eurjchem-2544	421	30	studies	study	NOUN
eurjchem-2544	421	31	of	of	ADP
eurjchem-2544	421	32	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	421	33	complexes	complex	NOUN
eurjchem-2544	421	34	of	of	ADP
eurjchem-2544	421	35	some	some	DET
eurjchem-2544	421	36	transition	transition	NOUN
eurjchem-2544	421	37	elements	element	NOUN
eurjchem-2544	421	38	(	(	PUNCT
eurjchem-2544	421	39	m	m	NOUN
eurjchem-2544	421	40	=	=	NOUN
eurjchem-2544	421	41	co	co	X
eurjchem-2544	421	42	,	,	PUNCT
eurjchem-2544	421	43	ni	ni	PROPN
eurjchem-2544	421	44	,	,	PUNCT
eurjchem-2544	421	45	pd	pd	PROPN
eurjchem-2544	421	46	)	)	PUNCT
eurjchem-2544	421	47	.	.	PUNCT
eurjchem-2544	422	1	j.	j.	PROPN
eurjchem-2544	422	2	coord	coord	PROPN
eurjchem-2544	422	3	.	.	PUNCT
eurjchem-2544	423	1	chem	chem	PROPN
eurjchem-2544	423	2	.	.	PUNCT
eurjchem-2544	424	1	2002	2002	NUM
eurjchem-2544	424	2	,	,	PUNCT
eurjchem-2544	424	3	55	55	NUM
eurjchem-2544	424	4	,	,	PUNCT
eurjchem-2544	424	5	429–437	429–437	NUM
eurjchem-2544	424	6	.	.	PUNCT
eurjchem-2544	425	1	[	[	X
eurjchem-2544	425	2	13	13	NUM
eurjchem-2544	425	3	]	]	PUNCT
eurjchem-2544	425	4	.	.	PUNCT
eurjchem-2544	426	1	gringeri	gringeri	PROPN
eurjchem-2544	426	2	,	,	PUNCT
eurjchem-2544	426	3	a.	a.	NOUN
eurjchem-2544	426	4	;	;	PUNCT
eurjchem-2544	426	5	keng	keng	PROPN
eurjchem-2544	426	6	,	,	PUNCT
eurjchem-2544	426	7	p.	p.	PROPN
eurjchem-2544	426	8	c.	c.	PROPN
eurjchem-2544	426	9	;	;	PUNCT
eurjchem-2544	426	10	borch	borch	PROPN
eurjchem-2544	426	11	,	,	PUNCT
eurjchem-2544	426	12	r.	r.	PROPN
eurjchem-2544	426	13	f.	f.	PROPN
eurjchem-2544	426	14	diethyldithiocarbamate	diethyldithiocarbamate	PROPN
eurjchem-2544	426	15	inhibition	inhibition	NOUN
eurjchem-2544	426	16	of	of	ADP
eurjchem-2544	426	17	murine	murine	ADJ
eurjchem-2544	426	18	bone	bone	NOUN
eurjchem-2544	426	19	marrow	marrow	NOUN
eurjchem-2544	426	20	toxicity	toxicity	NOUN
eurjchem-2544	426	21	caused	cause	VERB
eurjchem-2544	426	22	by	by	ADP
eurjchem-2544	426	23	cis	cis	NOUN
eurjchem-2544	426	24	-	-	PUNCT
eurjchem-2544	426	25	diamminedichloro	diamminedichloro	NOUN
eurjchem-2544	426	26	platinum(ii	platinum(ii	NOUN
eurjchem-2544	426	27	)	)	PUNCT
eurjchem-2544	426	28	or	or	CCONJ
eurjchem-2544	426	29	diammine-(1,1	diammine-(1,1	NOUN
eurjchem-2544	426	30	-	-	PUNCT
eurjchem-2544	426	31	cyclobutanedicarboxylato	cyclobutanedicarboxylato	NOUN
eurjchem-2544	426	32	)	)	PUNCT
eurjchem-2544	426	33	platinum(ii	platinum(ii	NOUN
eurjchem-2544	426	34	)	)	PUNCT
eurjchem-2544	426	35	.	.	PUNCT
eurjchem-2544	427	1	cancer	cancer	NOUN
eurjchem-2544	427	2	res	re	NOUN
eurjchem-2544	427	3	.	.	PUNCT
eurjchem-2544	427	4	1988	1988	NUM
eurjchem-2544	427	5	,	,	PUNCT
eurjchem-2544	427	6	48	48	NUM
eurjchem-2544	427	7	,	,	PUNCT
eurjchem-2544	427	8	5708–5712	5708–5712	NOUN
eurjchem-2544	427	9	.	.	PUNCT
eurjchem-2544	428	1	[	[	X
eurjchem-2544	428	2	14	14	NUM
eurjchem-2544	428	3	]	]	PUNCT
eurjchem-2544	428	4	.	.	PUNCT
eurjchem-2544	429	1	hersh	hersh	PROPN
eurjchem-2544	429	2	,	,	PUNCT
eurjchem-2544	429	3	e.	e.	PROPN
eurjchem-2544	429	4	m.	m.	PROPN
eurjchem-2544	429	5	ditiocarb	ditiocarb	PROPN
eurjchem-2544	429	6	sodium	sodium	PROPN
eurjchem-2544	429	7	(	(	PUNCT
eurjchem-2544	429	8	diethyldithiocarbamate	diethyldithiocarbamate	NOUN
eurjchem-2544	429	9	)	)	PUNCT
eurjchem-2544	429	10	therapy	therapy	NOUN
eurjchem-2544	429	11	in	in	ADP
eurjchem-2544	429	12	patients	patient	NOUN
eurjchem-2544	429	13	with	with	ADP
eurjchem-2544	429	14	symptomatic	symptomatic	ADJ
eurjchem-2544	429	15	hiv	hiv	PROPN
eurjchem-2544	429	16	infection	infection	NOUN
eurjchem-2544	429	17	and	and	CCONJ
eurjchem-2544	429	18	aids	aids	PROPN
eurjchem-2544	429	19	:	:	PUNCT
eurjchem-2544	429	20	a	a	DET
eurjchem-2544	429	21	randomized	randomized	ADJ
eurjchem-2544	429	22	,	,	PUNCT
eurjchem-2544	429	23	double	double	ADJ
eurjchem-2544	429	24	-	-	PUNCT
eurjchem-2544	429	25	blind	blind	ADJ
eurjchem-2544	429	26	,	,	PUNCT
eurjchem-2544	429	27	placebo	placebo	NOUN
eurjchem-2544	429	28	-	-	PUNCT
eurjchem-2544	429	29	controlled	control	VERB
eurjchem-2544	429	30	,	,	PUNCT
eurjchem-2544	429	31	multicenter	multicenter	ADJ
eurjchem-2544	429	32	study	study	NOUN
eurjchem-2544	429	33	.	.	PUNCT
eurjchem-2544	430	1	jama	jama	PROPN
eurjchem-2544	430	2	1991	1991	NUM
eurjchem-2544	430	3	,	,	PUNCT
eurjchem-2544	430	4	265	265	NUM
eurjchem-2544	430	5	,	,	PUNCT
eurjchem-2544	430	6	1538	1538	NUM
eurjchem-2544	430	7	.	.	PUNCT
eurjchem-2544	431	1	[	[	X
eurjchem-2544	431	2	15	15	NUM
eurjchem-2544	431	3	]	]	PUNCT
eurjchem-2544	431	4	.	.	PUNCT
eurjchem-2544	432	1	shinobu	shinobu	PROPN
eurjchem-2544	432	2	,	,	PUNCT
eurjchem-2544	432	3	l.	l.	PROPN
eurjchem-2544	432	4	a.	a.	PROPN
eurjchem-2544	432	5	;	;	PUNCT
eurjchem-2544	432	6	jones	jones	PROPN
eurjchem-2544	432	7	,	,	PUNCT
eurjchem-2544	432	8	s.	s.	PROPN
eurjchem-2544	432	9	g.	g.	PROPN
eurjchem-2544	432	10	;	;	PUNCT
eurjchem-2544	432	11	jones	jones	PROPN
eurjchem-2544	432	12	,	,	PUNCT
eurjchem-2544	432	13	m.	m.	NOUN
eurjchem-2544	432	14	m.	m.	PROPN
eurjchem-2544	432	15	sodium	sodium	PROPN
eurjchem-2544	432	16	n	n	CCONJ
eurjchem-2544	432	17	-	-	PUNCT
eurjchem-2544	432	18	methyl	methyl	NOUN
eurjchem-2544	432	19	-	-	PUNCT
eurjchem-2544	432	20	d	d	NOUN
eurjchem-2544	432	21	-	-	PUNCT
eurjchem-2544	432	22	glucamine	glucamine	ADJ
eurjchem-2544	432	23	dithiocarbamate	dithiocarbamate	NOUN
eurjchem-2544	432	24	and	and	CCONJ
eurjchem-2544	432	25	cadmium	cadmium	NOUN
eurjchem-2544	432	26	intoxication	intoxication	NOUN
eurjchem-2544	432	27	.	.	PUNCT
eurjchem-2544	433	1	acta	acta	PROPN
eurjchem-2544	433	2	pharmacol	pharmacol	PROPN
eurjchem-2544	433	3	.	.	PUNCT
eurjchem-2544	434	1	toxicol	toxicol	PROPN
eurjchem-2544	434	2	.	.	PUNCT
eurjchem-2544	435	1	(	(	PUNCT
eurjchem-2544	435	2	copenh	copenh	ADJ
eurjchem-2544	435	3	.	.	PUNCT
eurjchem-2544	435	4	)	)	PUNCT
eurjchem-2544	435	5	1984	1984	NUM
eurjchem-2544	435	6	,	,	PUNCT
eurjchem-2544	435	7	54	54	NUM
eurjchem-2544	435	8	,	,	PUNCT
eurjchem-2544	435	9	189–194	189–194	NUM
eurjchem-2544	435	10	.	.	PUNCT
eurjchem-2544	436	1	[	[	X
eurjchem-2544	436	2	16	16	NUM
eurjchem-2544	436	3	]	]	PUNCT
eurjchem-2544	436	4	.	.	PUNCT
eurjchem-2544	437	1	adeyemi	adeyemi	ADV
eurjchem-2544	437	2	,	,	PUNCT
eurjchem-2544	437	3	j.	j.	PROPN
eurjchem-2544	437	4	o.	o.	PROPN
eurjchem-2544	437	5	;	;	PUNCT
eurjchem-2544	437	6	onwudiwe	onwudiwe	NOUN
eurjchem-2544	437	7	,	,	PUNCT
eurjchem-2544	437	8	d.	d.	PROPN
eurjchem-2544	437	9	c.	c.	PROPN
eurjchem-2544	437	10	the	the	DET
eurjchem-2544	437	11	mechanisms	mechanism	NOUN
eurjchem-2544	437	12	of	of	ADP
eurjchem-2544	437	13	action	action	NOUN
eurjchem-2544	437	14	involving	involve	VERB
eurjchem-2544	437	15	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	437	16	complexes	complex	NOUN
eurjchem-2544	437	17	in	in	ADP
eurjchem-2544	437	18	biological	biological	ADJ
eurjchem-2544	437	19	systems	system	NOUN
eurjchem-2544	437	20	.	.	PUNCT
eurjchem-2544	438	1	inorganica	inorganica	PROPN
eurjchem-2544	438	2	chim	chim	PROPN
eurjchem-2544	438	3	.	.	PUNCT
eurjchem-2544	439	1	acta	acta	PROPN
eurjchem-2544	439	2	2020	2020	NUM
eurjchem-2544	439	3	,	,	PUNCT
eurjchem-2544	439	4	511	511	NUM
eurjchem-2544	439	5	,	,	PUNCT
eurjchem-2544	439	6	119809	119809	NUM
eurjchem-2544	439	7	.	.	PUNCT
eurjchem-2544	440	1	[	[	X
eurjchem-2544	440	2	17	17	NUM
eurjchem-2544	440	3	]	]	PUNCT
eurjchem-2544	440	4	.	.	PUNCT
eurjchem-2544	441	1	kamoon	kamoon	PROPN
eurjchem-2544	441	2	,	,	PUNCT
eurjchem-2544	441	3	r.	r.	PROPN
eurjchem-2544	441	4	a.	a.	PROPN
eurjchem-2544	441	5	;	;	PUNCT
eurjchem-2544	441	6	nadhum	nadhum	NOUN
eurjchem-2544	441	7	,	,	PUNCT
eurjchem-2544	441	8	s.	s.	PROPN
eurjchem-2544	441	9	a.	a.	PROPN
eurjchem-2544	441	10	;	;	PUNCT
eurjchem-2544	441	11	mohammed	mohammed	PROPN
eurjchem-2544	441	12	,	,	PUNCT
eurjchem-2544	441	13	m.	m.	PROPN
eurjchem-2544	441	14	h.	h.	PROPN
eurjchem-2544	441	15	dithiocarbamates	dithiocarbamate	VERB
eurjchem-2544	441	16	derivatives	derivative	NOUN
eurjchem-2544	441	17	as	as	ADP
eurjchem-2544	441	18	anticancer	anticancer	NOUN
eurjchem-2544	441	19	agents	agent	NOUN
eurjchem-2544	441	20	:	:	PUNCT
eurjchem-2544	441	21	a	a	DET
eurjchem-2544	441	22	review	review	NOUN
eurjchem-2544	441	23	.	.	PUNCT
eurjchem-2544	442	1	annals	annal	NOUN
eurjchem-2544	442	2	of	of	ADP
eurjchem-2544	442	3	tropical	tropical	ADJ
eurjchem-2544	442	4	medicine	medicine	NOUN
eurjchem-2544	442	5	and	and	CCONJ
eurjchem-2544	442	6	public	public	ADJ
eurjchem-2544	442	7	health	health	NOUN
eurjchem-2544	442	8	2020	2020	NUM
eurjchem-2544	442	9	,	,	PUNCT
eurjchem-2544	442	10	23	23	NUM
eurjchem-2544	442	11	.	.	PUNCT
eurjchem-2544	443	1	[	[	X
eurjchem-2544	443	2	18	18	NUM
eurjchem-2544	443	3	]	]	PUNCT
eurjchem-2544	443	4	.	.	PUNCT
eurjchem-2544	444	1	chung	chung	PROPN
eurjchem-2544	444	2	,	,	PUNCT
eurjchem-2544	444	3	s.	s.	PROPN
eurjchem-2544	444	4	w.	w.	PROPN
eurjchem-2544	444	5	c.	c.	PROPN
eurjchem-2544	444	6	;	;	PUNCT
eurjchem-2544	444	7	wong	wong	PROPN
eurjchem-2544	444	8	,	,	PUNCT
eurjchem-2544	444	9	w.	w.	PROPN
eurjchem-2544	444	10	w.	w.	PROPN
eurjchem-2544	444	11	k.	k.	PROPN
eurjchem-2544	444	12	chromatographic	chromatographic	ADJ
eurjchem-2544	444	13	analysis	analysis	NOUN
eurjchem-2544	444	14	of	of	ADP
eurjchem-2544	444	15	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	444	16	residues	residue	NOUN
eurjchem-2544	444	17	and	and	CCONJ
eurjchem-2544	444	18	their	their	PRON
eurjchem-2544	444	19	metabolites	metabolite	NOUN
eurjchem-2544	444	20	in	in	ADP
eurjchem-2544	444	21	foods	food	NOUN
eurjchem-2544	444	22	employed	employ	VERB
eurjchem-2544	444	23	in	in	ADP
eurjchem-2544	444	24	dietary	dietary	ADJ
eurjchem-2544	444	25	exposure	exposure	NOUN
eurjchem-2544	444	26	studies	study	NOUN
eurjchem-2544	444	27	—	—	PUNCT
eurjchem-2544	444	28	a	a	DET
eurjchem-2544	444	29	review	review	NOUN
eurjchem-2544	444	30	.	.	PUNCT
eurjchem-2544	445	1	food	food	NOUN
eurjchem-2544	445	2	addit	addit	NOUN
eurjchem-2544	445	3	.	.	PUNCT
eurjchem-2544	446	1	contam	contam	PROPN
eurjchem-2544	446	2	.	.	PUNCT
eurjchem-2544	447	1	part	part	NOUN
eurjchem-2544	447	2	a	a	DET
eurjchem-2544	447	3	chem	chem	NOUN
eurjchem-2544	447	4	.	.	PUNCT
eurjchem-2544	448	1	anal	anal	PROPN
eurjchem-2544	448	2	.	.	PUNCT
eurjchem-2544	449	1	control	control	PROPN
eurjchem-2544	449	2	expo	expo	PROPN
eurjchem-2544	449	3	.	.	PUNCT
eurjchem-2544	450	1	risk	risk	NOUN
eurjchem-2544	450	2	assess	assess	NOUN
eurjchem-2544	450	3	.	.	PUNCT
eurjchem-2544	451	1	2022	2022	NUM
eurjchem-2544	451	2	,	,	PUNCT
eurjchem-2544	451	3	39	39	NUM
eurjchem-2544	451	4	,	,	PUNCT
eurjchem-2544	451	5	1731–1743	1731–1743	NUM
eurjchem-2544	451	6	.	.	PUNCT
eurjchem-2544	452	1	[	[	X
eurjchem-2544	452	2	19	19	NUM
eurjchem-2544	452	3	]	]	PUNCT
eurjchem-2544	452	4	.	.	PUNCT
eurjchem-2544	453	1	chawla	chawla	PROPN
eurjchem-2544	453	2	,	,	PUNCT
eurjchem-2544	453	3	s.	s.	PROPN
eurjchem-2544	453	4	;	;	PUNCT
eurjchem-2544	453	5	patel	patel	PROPN
eurjchem-2544	453	6	,	,	PUNCT
eurjchem-2544	453	7	h.	h.	PROPN
eurjchem-2544	453	8	k.	k.	PROPN
eurjchem-2544	453	9	;	;	PUNCT
eurjchem-2544	453	10	kalasariya	kalasariya	PROPN
eurjchem-2544	453	11	,	,	PUNCT
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eurjchem-2544	453	13	l.	l.	PROPN
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eurjchem-2544	453	18	g.	g.	PROPN
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eurjchem-2544	454	5	thiram	thiram	NOUN
eurjchem-2544	454	6	,	,	PUNCT
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eurjchem-2544	454	9	,	,	PUNCT
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eurjchem-2544	454	16	max	max	PROPN
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eurjchem-2544	457	1	(	(	PUNCT
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eurjchem-2544	457	5	,	,	PUNCT
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eurjchem-2544	457	7	,	,	PUNCT
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eurjchem-2544	457	9	.	.	PUNCT
eurjchem-2544	458	1	[	[	X
eurjchem-2544	458	2	20	20	NUM
eurjchem-2544	458	3	]	]	PUNCT
eurjchem-2544	458	4	.	.	PUNCT
eurjchem-2544	459	1	fan	fan	PROPN
eurjchem-2544	459	2	,	,	PUNCT
eurjchem-2544	459	3	l.	l.	PROPN
eurjchem-2544	459	4	;	;	PUNCT
eurjchem-2544	459	5	li	li	PROPN
eurjchem-2544	459	6	,	,	PUNCT
eurjchem-2544	459	7	l.	l.	PROPN
eurjchem-2544	459	8	;	;	PUNCT
eurjchem-2544	459	9	xu	xu	PROPN
eurjchem-2544	459	10	,	,	PUNCT
eurjchem-2544	459	11	b.	b.	PROPN
eurjchem-2544	459	12	;	;	PUNCT
eurjchem-2544	459	13	qiao	qiao	PROPN
eurjchem-2544	459	14	,	,	PUNCT
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eurjchem-2544	459	16	;	;	PUNCT
eurjchem-2544	459	17	li	li	PROPN
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eurjchem-2544	459	20	;	;	PUNCT
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eurjchem-2544	459	22	,	,	PUNCT
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eurjchem-2544	459	25	,	,	PUNCT
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eurjchem-2544	459	36	ligand	ligand	NOUN
eurjchem-2544	459	37	involving	involve	VERB
eurjchem-2544	459	38	in	in	ADP
eurjchem-2544	459	39	situ	situ	ADJ
eurjchem-2544	459	40	ligand	ligand	NOUN
eurjchem-2544	459	41	synthesis	synthesis	NOUN
eurjchem-2544	459	42	.	.	PUNCT
eurjchem-2544	460	1	inorganica	inorganica	PROPN
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eurjchem-2544	461	3	,	,	PUNCT
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eurjchem-2544	461	5	,	,	PUNCT
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eurjchem-2544	462	21	(	(	PUNCT
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eurjchem-2544	462	23	)	)	PUNCT
eurjchem-2544	462	24	(	(	PUNCT
eurjchem-2544	462	25	2024	2024	NUM
eurjchem-2544	462	26	)	)	PUNCT
eurjchem-2544	462	27	291	291	NUM
eurjchem-2544	462	28	-	-	SYM
eurjchem-2544	462	29	301	301	NUM
eurjchem-2544	462	30	301	301	NUM
eurjchem-2544	462	31	2024	2024	NUM
eurjchem-2544	462	32	–	–	PUNCT
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eurjchem-2544	462	37	–	–	PUNCT
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eurjchem-2544	462	41	–	–	PUNCT
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eurjchem-2544	462	47	-	-	PUNCT
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eurjchem-2544	462	50	21	21	NUM
eurjchem-2544	462	51	]	]	PUNCT
eurjchem-2544	462	52	.	.	PUNCT
eurjchem-2544	463	1	islam	islam	PROPN
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eurjchem-2544	463	5	;	;	PUNCT
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eurjchem-2544	463	7	,	,	PUNCT
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eurjchem-2544	463	9	;	;	PUNCT
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eurjchem-2544	463	13	;	;	PUNCT
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eurjchem-2544	463	17	;	;	PUNCT
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eurjchem-2544	463	19	,	,	PUNCT
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eurjchem-2544	463	21	;	;	PUNCT
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eurjchem-2544	463	25	n.	n.	PROPN
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eurjchem-2544	463	41	precursors	precursor	NOUN
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eurjchem-2544	463	45	.	.	PUNCT
eurjchem-2544	464	1	nanoscale	nanoscale	PROPN
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eurjchem-2544	464	7	,	,	PUNCT
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eurjchem-2544	464	9	.	.	PUNCT
eurjchem-2544	465	1	[	[	X
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eurjchem-2544	465	3	]	]	PUNCT
eurjchem-2544	465	4	.	.	PUNCT
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eurjchem-2544	466	5	;	;	PUNCT
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eurjchem-2544	466	16	-	-	PUNCT
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eurjchem-2544	467	7	.	.	PUNCT
eurjchem-2544	468	1	[	[	X
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eurjchem-2544	468	3	]	]	PUNCT
eurjchem-2544	468	4	.	.	PUNCT
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eurjchem-2544	469	5	;	;	PUNCT
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eurjchem-2544	470	9	-	-	PUNCT
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eurjchem-2544	472	2	.	.	PUNCT
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eurjchem-2544	473	2	.	.	PUNCT
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eurjchem-2544	474	2	.	.	PUNCT
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eurjchem-2544	475	6	.	.	PUNCT
eurjchem-2544	476	1	[	[	X
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eurjchem-2544	485	1	[	[	X
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eurjchem-2544	485	4	.	.	PUNCT
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eurjchem-2544	486	5	;	;	PUNCT
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eurjchem-2544	486	7	,	,	PUNCT
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eurjchem-2544	486	34	;	;	PUNCT
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eurjchem-2544	486	36	,	,	PUNCT
eurjchem-2544	486	37	r.	r.	PROPN
eurjchem-2544	486	38	;	;	PUNCT
eurjchem-2544	486	39	van	van	PROPN
eurjchem-2544	486	40	de	de	X
eurjchem-2544	486	41	streek	streek	PROPN
eurjchem-2544	486	42	,	,	PUNCT
eurjchem-2544	486	43	j.	j.	PROPN
eurjchem-2544	486	44	;	;	PUNCT
eurjchem-2544	486	45	wood	wood	NOUN
eurjchem-2544	486	46	,	,	PUNCT
eurjchem-2544	486	47	p.	p.	NOUN
eurjchem-2544	486	48	a.	a.	PROPN
eurjchem-2544	486	49	mercury	mercury	PROPN
eurjchem-2544	486	50	csd	csd	PROPN
eurjchem-2544	486	51	2.0	2.0	NUM
eurjchem-2544	486	52	–	–	PUNCT
eurjchem-2544	486	53	new	new	ADJ
eurjchem-2544	486	54	features	feature	NOUN
eurjchem-2544	486	55	for	for	ADP
eurjchem-2544	486	56	the	the	DET
eurjchem-2544	486	57	visualization	visualization	NOUN
eurjchem-2544	486	58	and	and	CCONJ
eurjchem-2544	486	59	investigation	investigation	NOUN
eurjchem-2544	486	60	of	of	ADP
eurjchem-2544	486	61	crystal	crystal	NOUN
eurjchem-2544	486	62	structures	structure	NOUN
eurjchem-2544	486	63	.	.	PUNCT
eurjchem-2544	487	1	j.	j.	PROPN
eurjchem-2544	487	2	appl	appl	PROPN
eurjchem-2544	487	3	.	.	PROPN
eurjchem-2544	487	4	crystallogr	crystallogr	PROPN
eurjchem-2544	487	5	.	.	PUNCT
eurjchem-2544	488	1	2008	2008	NUM
eurjchem-2544	488	2	,	,	PUNCT
eurjchem-2544	488	3	41	41	NUM
eurjchem-2544	488	4	,	,	PUNCT
eurjchem-2544	488	5	466	466	NUM
eurjchem-2544	488	6	–	–	PUNCT
eurjchem-2544	488	7	470	470	NUM
eurjchem-2544	488	8	.	.	PUNCT
eurjchem-2544	489	1	[	[	X
eurjchem-2544	489	2	26	26	NUM
eurjchem-2544	489	3	]	]	PUNCT
eurjchem-2544	489	4	.	.	PUNCT
eurjchem-2544	490	1	healy	healy	PROPN
eurjchem-2544	490	2	,	,	PUNCT
eurjchem-2544	490	3	p.	p.	PROPN
eurjchem-2544	490	4	c.	c.	PROPN
eurjchem-2544	490	5	;	;	PUNCT
eurjchem-2544	490	6	connor	connor	PROPN
eurjchem-2544	490	7	,	,	PUNCT
eurjchem-2544	490	8	j.	j.	PROPN
eurjchem-2544	490	9	w.	w.	PROPN
eurjchem-2544	490	10	;	;	PUNCT
eurjchem-2544	490	11	skelton	skelton	PROPN
eurjchem-2544	490	12	,	,	PUNCT
eurjchem-2544	490	13	b.	b.	PROPN
eurjchem-2544	490	14	w.	w.	PROPN
eurjchem-2544	490	15	;	;	PUNCT
eurjchem-2544	490	16	white	white	ADJ
eurjchem-2544	490	17	,	,	PUNCT
eurjchem-2544	490	18	a.	a.	NOUN
eurjchem-2544	490	19	h.	h.	PROPN
eurjchem-2544	490	20	alkyl	alkyl	PROPN
eurjchem-2544	490	21	substituent	substituent	NOUN
eurjchem-2544	490	22	effects	effect	NOUN
eurjchem-2544	490	23	in	in	ADP
eurjchem-2544	490	24	diamagnetic	diamagnetic	ADJ
eurjchem-2544	490	25	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	490	26	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	490	27	)	)	PUNCT
eurjchem-2544	490	28	and	and	CCONJ
eurjchem-2544	490	29	nickel(ii	nickel(ii	ADJ
eurjchem-2544	490	30	)	)	PUNCT
eurjchem-2544	490	31	complexes	complex	NOUN
eurjchem-2544	490	32	.	.	PUNCT
eurjchem-2544	491	1	aust	aust	PROPN
eurjchem-2544	491	2	.	.	PUNCT
eurjchem-2544	492	1	j.	j.	PROPN
eurjchem-2544	492	2	chem	chem	PROPN
eurjchem-2544	492	3	.	.	PUNCT
eurjchem-2544	493	1	1990	1990	NUM
eurjchem-2544	493	2	,	,	PUNCT
eurjchem-2544	493	3	43	43	NUM
eurjchem-2544	493	4	,	,	PUNCT
eurjchem-2544	493	5	1083	1083	NUM
eurjchem-2544	493	6	.	.	PUNCT
eurjchem-2544	494	1	[	[	X
eurjchem-2544	494	2	27	27	NUM
eurjchem-2544	494	3	]	]	PUNCT
eurjchem-2544	494	4	.	.	PUNCT
eurjchem-2544	495	1	bonamico	bonamico	NOUN
eurjchem-2544	495	2	,	,	PUNCT
eurjchem-2544	495	3	m.	m.	NOUN
eurjchem-2544	495	4	;	;	PUNCT
eurjchem-2544	495	5	dessy	dessy	PROPN
eurjchem-2544	495	6	,	,	PUNCT
eurjchem-2544	495	7	g.	g.	PROPN
eurjchem-2544	495	8	;	;	PUNCT
eurjchem-2544	495	9	mariani	mariani	PROPN
eurjchem-2544	495	10	,	,	PUNCT
eurjchem-2544	495	11	c.	c.	PROPN
eurjchem-2544	495	12	;	;	PUNCT
eurjchem-2544	495	13	vaciago	vaciago	PROPN
eurjchem-2544	495	14	,	,	PUNCT
eurjchem-2544	495	15	a.	a.	NOUN
eurjchem-2544	495	16	;	;	PUNCT
eurjchem-2544	495	17	zambonelli	zambonelli	PROPN
eurjchem-2544	495	18	,	,	PUNCT
eurjchem-2544	495	19	l.	l.	PROPN
eurjchem-2544	495	20	structural	structural	ADJ
eurjchem-2544	495	21	studies	study	NOUN
eurjchem-2544	495	22	of	of	ADP
eurjchem-2544	495	23	metal	metal	NOUN
eurjchem-2544	495	24	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	495	25	.	.	PUNCT
eurjchem-2544	496	1	i.	i.	PROPN
eurjchem-2544	496	2	the	the	DET
eurjchem-2544	496	3	crystal	crystal	PROPN
eurjchem-2544	496	4	and	and	CCONJ
eurjchem-2544	496	5	molecular	molecular	ADJ
eurjchem-2544	496	6	structure	structure	NOUN
eurjchem-2544	496	7	of	of	ADP
eurjchem-2544	496	8	the	the	DET
eurjchem-2544	496	9	α	α	NOUN
eurjchem-2544	496	10	-	-	PUNCT
eurjchem-2544	496	11	form	form	NOUN
eurjchem-2544	496	12	of	of	ADP
eurjchem-2544	496	13	nickel	nickel	NOUN
eurjchem-2544	496	14	diethyldithiocarbamate	diethyldithiocarbamate	NOUN
eurjchem-2544	496	15	.	.	PUNCT
eurjchem-2544	497	1	acta	acta	PROPN
eurjchem-2544	497	2	crystallogr	crystallogr	PROPN
eurjchem-2544	497	3	.	.	PUNCT
eurjchem-2544	498	1	1965	1965	NUM
eurjchem-2544	498	2	,	,	PUNCT
eurjchem-2544	498	3	19	19	NUM
eurjchem-2544	498	4	,	,	PUNCT
eurjchem-2544	498	5	619–626	619–626	NUM
eurjchem-2544	498	6	.	.	PUNCT
eurjchem-2544	499	1	[	[	X
eurjchem-2544	499	2	28	28	NUM
eurjchem-2544	499	3	]	]	PUNCT
eurjchem-2544	499	4	.	.	PUNCT
eurjchem-2544	500	1	bonamico	bonamico	NOUN
eurjchem-2544	500	2	,	,	PUNCT
eurjchem-2544	500	3	m.	m.	NOUN
eurjchem-2544	500	4	;	;	PUNCT
eurjchem-2544	500	5	dessy	dessy	PROPN
eurjchem-2544	500	6	,	,	PUNCT
eurjchem-2544	500	7	g.	g.	PROPN
eurjchem-2544	500	8	;	;	PUNCT
eurjchem-2544	500	9	mugnoli	mugnoli	PROPN
eurjchem-2544	500	10	,	,	PUNCT
eurjchem-2544	500	11	a.	a.	NOUN
eurjchem-2544	500	12	;	;	PUNCT
eurjchem-2544	500	13	vaciago	vaciago	PROPN
eurjchem-2544	500	14	,	,	PUNCT
eurjchem-2544	500	15	a.	a.	NOUN
eurjchem-2544	500	16	;	;	PUNCT
eurjchem-2544	500	17	zambonelli	zambonelli	PROPN
eurjchem-2544	500	18	,	,	PUNCT
eurjchem-2544	500	19	l.	l.	PROPN
eurjchem-2544	500	20	structural	structural	ADJ
eurjchem-2544	500	21	studies	study	NOUN
eurjchem-2544	500	22	of	of	ADP
eurjchem-2544	500	23	metal	metal	NOUN
eurjchem-2544	500	24	dithiocarbamates	dithiocarbamate	NOUN
eurjchem-2544	500	25	.	.	PUNCT
eurjchem-2544	501	1	ii	ii	PROPN
eurjchem-2544	501	2	.	.	PUNCT
eurjchem-2544	502	1	the	the	DET
eurjchem-2544	502	2	crystal	crystal	NOUN
eurjchem-2544	502	3	and	and	CCONJ
eurjchem-2544	502	4	molecular	molecular	ADJ
eurjchem-2544	502	5	structure	structure	NOUN
eurjchem-2544	502	6	of	of	ADP
eurjchem-2544	502	7	copper	copper	NOUN
eurjchem-2544	502	8	diethyldithiocarbamate	diethyldithiocarbamate	NOUN
eurjchem-2544	502	9	.	.	PUNCT
eurjchem-2544	503	1	acta	acta	PROPN
eurjchem-2544	503	2	crystallogr	crystallogr	PROPN
eurjchem-2544	503	3	.	.	PUNCT
eurjchem-2544	504	1	1965	1965	NUM
eurjchem-2544	504	2	,	,	PUNCT
eurjchem-2544	504	3	19	19	NUM
eurjchem-2544	504	4	,	,	PUNCT
eurjchem-2544	504	5	886–897	886–897	NUM
eurjchem-2544	504	6	.	.	PUNCT
eurjchem-2544	505	1	[	[	X
eurjchem-2544	505	2	29	29	NUM
eurjchem-2544	505	3	]	]	PUNCT
eurjchem-2544	505	4	.	.	PUNCT
eurjchem-2544	506	1	lopez	lopez	NOUN
eurjchem-2544	506	2	-	-	PUNCT
eurjchem-2544	506	3	castro	castro	PROPN
eurjchem-2544	506	4	,	,	PUNCT
eurjchem-2544	506	5	a.	a.	NOUN
eurjchem-2544	506	6	;	;	PUNCT
eurjchem-2544	506	7	truter	truter	ADV
eurjchem-2544	506	8	,	,	PUNCT
eurjchem-2544	506	9	m.	m.	PROPN
eurjchem-2544	506	10	r.	r.	PROPN
eurjchem-2544	506	11	the	the	DET
eurjchem-2544	506	12	crystal	crystal	PROPN
eurjchem-2544	506	13	and	and	CCONJ
eurjchem-2544	506	14	molecular	molecular	ADJ
eurjchem-2544	506	15	structure	structure	NOUN
eurjchem-2544	506	16	of	of	ADP
eurjchem-2544	506	17	dichlorotetrakisthioureanickel	dichlorotetrakisthioureanickel	NOUN
eurjchem-2544	506	18	,	,	PUNCT
eurjchem-2544	506	19	[	[	X
eurjchem-2544	506	20	(	(	PUNCT
eurjchem-2544	506	21	nh2)2cs]4nicl2	nh2)2cs]4nicl2	PROPN
eurjchem-2544	506	22	.	.	PUNCT
eurjchem-2544	506	23	j.	j.	PROPN
eurjchem-2544	506	24	chem	chem	PROPN
eurjchem-2544	506	25	.	.	PUNCT
eurjchem-2544	507	1	soc	soc	PROPN
eurjchem-2544	507	2	.	.	PUNCT
eurjchem-2544	508	1	1963	1963	NUM
eurjchem-2544	508	2	,	,	PUNCT
eurjchem-2544	508	3	1309	1309	NUM
eurjchem-2544	508	4	.	.	PUNCT
eurjchem-2544	509	1	[	[	X
eurjchem-2544	509	2	30	30	NUM
eurjchem-2544	509	3	]	]	PUNCT
eurjchem-2544	509	4	.	.	PUNCT
eurjchem-2544	510	1	bolte	bolte	PROPN
eurjchem-2544	510	2	,	,	PUNCT
eurjchem-2544	510	3	m.	m.	NOUN
eurjchem-2544	510	4	tris(n	tris(n	PROPN
eurjchem-2544	510	5	,	,	PUNCT
eurjchem-2544	510	6	n	n	CCONJ
eurjchem-2544	510	7	-	-	PUNCT
eurjchem-2544	510	8	diethyldithiocarbamato	diethyldithiocarbamato	NOUN
eurjchem-2544	510	9	-	-	PUNCT
eurjchem-2544	510	10	s	s	NOUN
eurjchem-2544	510	11	,	,	PUNCT
eurjchem-2544	510	12	s')-cobalt(iii	s')-cobalt(iii	NOUN
eurjchem-2544	510	13	)	)	PUNCT
eurjchem-2544	510	14	.	.	PUNCT
eurjchem-2544	511	1	csd	csd	PROPN
eurjchem-2544	511	2	commun	commun	PROPN
eurjchem-2544	511	3	.	.	PUNCT
eurjchem-2544	512	1	2006	2006	NUM
eurjchem-2544	512	2	.	.	PUNCT
eurjchem-2544	513	1	[	[	X
eurjchem-2544	513	2	31	31	NUM
eurjchem-2544	513	3	]	]	PUNCT
eurjchem-2544	513	4	.	.	PUNCT
eurjchem-2544	514	1	iwasaki	iwasaki	PROPN
eurjchem-2544	514	2	,	,	PUNCT
eurjchem-2544	514	3	h.	h.	PROPN
eurjchem-2544	514	4	;	;	PUNCT
eurjchem-2544	514	5	kobayashi	kobayashi	PROPN
eurjchem-2544	514	6	,	,	PUNCT
eurjchem-2544	514	7	k.	k.	PROPN
eurjchem-2544	514	8	structure	structure	NOUN
eurjchem-2544	514	9	of	of	ADP
eurjchem-2544	514	10	tris(n	tris(n	PROPN
eurjchem-2544	514	11	,	,	PUNCT
eurjchem-2544	514	12	ndimethyldithiocarbamato)cobalt(iii	ndimethyldithiocarbamato)cobalt(iii	NUM
eurjchem-2544	514	13	)	)	PUNCT
eurjchem-2544	514	14	.	.	PUNCT
eurjchem-2544	515	1	acta	acta	PROPN
eurjchem-2544	515	2	crystallogr	crystallogr	PROPN
eurjchem-2544	515	3	.	.	PUNCT
eurjchem-2544	516	1	b	b	NOUN
eurjchem-2544	516	2	1980	1980	NUM
eurjchem-2544	516	3	,	,	PUNCT
eurjchem-2544	516	4	36	36	NUM
eurjchem-2544	516	5	,	,	PUNCT
eurjchem-2544	516	6	1657–1659	1657–1659	NUM
eurjchem-2544	516	7	.	.	PUNCT
eurjchem-2544	517	1	[	[	X
eurjchem-2544	517	2	32	32	NUM
eurjchem-2544	517	3	]	]	PUNCT
eurjchem-2544	517	4	.	.	PUNCT
eurjchem-2544	518	1	raston	raston	PROPN
eurjchem-2544	518	2	,	,	PUNCT
eurjchem-2544	518	3	c.	c.	PROPN
eurjchem-2544	518	4	l.	l.	PROPN
eurjchem-2544	518	5	;	;	PUNCT
eurjchem-2544	518	6	white	white	ADJ
eurjchem-2544	518	7	,	,	PUNCT
eurjchem-2544	518	8	a.	a.	PROPN
eurjchem-2544	518	9	h.	h.	PROPN
eurjchem-2544	518	10	;	;	PUNCT
eurjchem-2544	518	11	willis	willis	PROPN
eurjchem-2544	518	12	,	,	PUNCT
eurjchem-2544	518	13	a.	a.	PROPN
eurjchem-2544	518	14	c.	c.	PROPN
eurjchem-2544	518	15	crystal	crystal	PROPN
eurjchem-2544	518	16	structure	structure	NOUN
eurjchem-2544	518	17	of	of	ADP
eurjchem-2544	518	18	tris(dithiocarbamato)cobalt(iii	tris(dithiocarbamato)cobalt(iii	NOUN
eurjchem-2544	518	19	)	)	PUNCT
eurjchem-2544	518	20	.	.	PUNCT
eurjchem-2544	519	1	j.	j.	PROPN
eurjchem-2544	519	2	chem	chem	PROPN
eurjchem-2544	519	3	.	.	PUNCT
eurjchem-2544	520	1	soc	soc	PROPN
eurjchem-2544	520	2	.	.	PROPN
eurjchem-2544	520	3	,	,	PUNCT
eurjchem-2544	520	4	dalton	dalton	PROPN
eurjchem-2544	520	5	trans	trans	PROPN
eurjchem-2544	520	6	.	.	PROPN
eurjchem-2544	521	1	1975	1975	NUM
eurjchem-2544	521	2	,	,	PUNCT
eurjchem-2544	521	3	2429	2429	NUM
eurjchem-2544	521	4	.	.	PUNCT
eurjchem-2544	522	1	[	[	X
eurjchem-2544	522	2	33	33	NUM
eurjchem-2544	522	3	]	]	SYM
eurjchem-2544	522	4	.	.	PUNCT
eurjchem-2544	523	1	merlino	merlino	PROPN
eurjchem-2544	523	2	,	,	PUNCT
eurjchem-2544	523	3	s.	s.	PROPN
eurjchem-2544	523	4	crystal	crystal	PROPN
eurjchem-2544	523	5	and	and	CCONJ
eurjchem-2544	523	6	molecular	molecular	ADJ
eurjchem-2544	523	7	structure	structure	NOUN
eurjchem-2544	523	8	of	of	ADP
eurjchem-2544	523	9	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	523	10	)	)	PUNCT
eurjchem-2544	523	11	tris(n	tris(n	PROPN
eurjchem-2544	523	12	,	,	PUNCT
eurjchem-2544	523	13	ndiethyldithiocarbamate	ndiethyldithiocarbamate	NOUN
eurjchem-2544	523	14	)	)	PUNCT
eurjchem-2544	523	15	.	.	PUNCT
eurjchem-2544	524	1	acta	acta	PROPN
eurjchem-2544	524	2	crystallogr	crystallogr	PROPN
eurjchem-2544	524	3	.	.	PUNCT
eurjchem-2544	525	1	b	b	NOUN
eurjchem-2544	525	2	1968	1968	NUM
eurjchem-2544	525	3	,	,	PUNCT
eurjchem-2544	525	4	24	24	NUM
eurjchem-2544	525	5	,	,	PUNCT
eurjchem-2544	525	6	1441–1448	1441–1448	NUM
eurjchem-2544	525	7	.	.	PUNCT
eurjchem-2544	526	1	[	[	X
eurjchem-2544	526	2	34	34	NUM
eurjchem-2544	526	3	]	]	PUNCT
eurjchem-2544	526	4	.	.	PUNCT
eurjchem-2544	526	5	hogarth	hogarth	PROPN
eurjchem-2544	526	6	,	,	PUNCT
eurjchem-2544	526	7	g.	g.	PROPN
eurjchem-2544	526	8	;	;	PUNCT
eurjchem-2544	526	9	rainford	rainford	PROPN
eurjchem-2544	526	10	-	-	PUNCT
eurjchem-2544	526	11	brent	brent	PROPN
eurjchem-2544	526	12	,	,	PUNCT
eurjchem-2544	526	13	e.-j	e.-j	PROPN
eurjchem-2544	526	14	.	.	PROPN
eurjchem-2544	526	15	c.-r	c.-r	PROPN
eurjchem-2544	526	16	.	.	PUNCT
eurjchem-2544	527	1	c.	c.	PROPN
eurjchem-2544	527	2	r.	r.	PROPN
eurjchem-2544	527	3	;	;	PUNCT
eurjchem-2544	527	4	kabir	kabir	PROPN
eurjchem-2544	527	5	,	,	PUNCT
eurjchem-2544	527	6	s.	s.	PROPN
eurjchem-2544	527	7	e.	e.	PROPN
eurjchem-2544	527	8	;	;	PUNCT
eurjchem-2544	527	9	richards	richards	PROPN
eurjchem-2544	527	10	,	,	PUNCT
eurjchem-2544	527	11	i.	i.	PROPN
eurjchem-2544	527	12	;	;	PUNCT
eurjchem-2544	527	13	wilton	wilton	PROPN
eurjchem-2544	527	14	-	-	PUNCT
eurjchem-2544	527	15	ely	ely	PROPN
eurjchem-2544	527	16	,	,	PUNCT
eurjchem-2544	527	17	j.	j.	PROPN
eurjchem-2544	527	18	d.	d.	PROPN
eurjchem-2544	527	19	e.	e.	PROPN
eurjchem-2544	527	20	t.	t.	PROPN
eurjchem-2544	527	21	;	;	PUNCT
eurjchem-2544	527	22	zhang	zhang	PROPN
eurjchem-2544	527	23	,	,	PUNCT
eurjchem-2544	527	24	q.	q.	PROPN
eurjchem-2544	527	25	functionalised	functionalise	VERB
eurjchem-2544	527	26	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	527	27	complexes	complex	NOUN
eurjchem-2544	527	28	:	:	PUNCT
eurjchem-2544	527	29	synthesis	synthesis	NOUN
eurjchem-2544	527	30	and	and	CCONJ
eurjchem-2544	527	31	molecular	molecular	ADJ
eurjchem-2544	527	32	structures	structure	NOUN
eurjchem-2544	527	33	of	of	ADP
eurjchem-2544	527	34	2diethylaminoethyl	2diethylaminoethyl	NUM
eurjchem-2544	527	35	and	and	CCONJ
eurjchem-2544	527	36	3	3	NUM
eurjchem-2544	527	37	-	-	PUNCT
eurjchem-2544	527	38	dimethylaminopropyl	dimethylaminopropyl	ADJ
eurjchem-2544	527	39	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	527	40	complexes	complex	NOUN
eurjchem-2544	527	41	[	[	X
eurjchem-2544	527	42	ms2cn{(ch2ch2net2)2}n	ms2cn{(ch2ch2net2)2}n	X
eurjchem-2544	527	43	]	]	X
eurjchem-2544	527	44	and	and	CCONJ
eurjchem-2544	527	45	[	[	X
eurjchem-2544	527	46	ms2cn{(ch2ch2ch2	ms2cn{(ch2ch2ch2	NOUN
eurjchem-2544	527	47	nme2)2}n	nme2)2}n	NOUN
eurjchem-2544	527	48	]	]	X
eurjchem-2544	527	49	(	(	PUNCT
eurjchem-2544	527	50	n=2	n=2	X
eurjchem-2544	527	51	,	,	PUNCT
eurjchem-2544	527	52	m	m	PROPN
eurjchem-2544	527	53	=	=	NOUN
eurjchem-2544	527	54	ni	ni	PROPN
eurjchem-2544	527	55	,	,	PUNCT
eurjchem-2544	527	56	cu	cu	PROPN
eurjchem-2544	527	57	,	,	PUNCT
eurjchem-2544	527	58	zn	zn	PROPN
eurjchem-2544	527	59	,	,	PUNCT
eurjchem-2544	527	60	pd	pd	PROPN
eurjchem-2544	527	61	;	;	PUNCT
eurjchem-2544	527	62	n=3	n=3	NOUN
eurjchem-2544	527	63	,	,	PUNCT
eurjchem-2544	527	64	m	m	VERB
eurjchem-2544	527	65	=	=	NOUN
eurjchem-2544	527	66	co	co	NOUN
eurjchem-2544	527	67	)	)	PUNCT
eurjchem-2544	527	68	.	.	PUNCT
eurjchem-2544	528	1	inorganica	inorganica	PROPN
eurjchem-2544	528	2	chim	chim	PROPN
eurjchem-2544	528	3	.	.	PUNCT
eurjchem-2544	529	1	acta	acta	PROPN
eurjchem-2544	529	2	2009	2009	NUM
eurjchem-2544	529	3	,	,	PUNCT
eurjchem-2544	529	4	362	362	NUM
eurjchem-2544	529	5	,	,	PUNCT
eurjchem-2544	529	6	2020–2026	2020–2026	NUM
eurjchem-2544	529	7	.	.	PUNCT
eurjchem-2544	530	1	[	[	X
eurjchem-2544	530	2	35	35	NUM
eurjchem-2544	530	3	]	]	PUNCT
eurjchem-2544	530	4	.	.	PUNCT
eurjchem-2544	531	1	dulare	dulare	PROPN
eurjchem-2544	531	2	,	,	PUNCT
eurjchem-2544	531	3	r.	r.	PROPN
eurjchem-2544	531	4	;	;	PUNCT
eurjchem-2544	531	5	bharty	bharty	NOUN
eurjchem-2544	531	6	,	,	PUNCT
eurjchem-2544	531	7	m.	m.	NOUN
eurjchem-2544	531	8	k.	k.	PROPN
eurjchem-2544	531	9	;	;	PUNCT
eurjchem-2544	531	10	singh	singh	PROPN
eurjchem-2544	531	11	,	,	PUNCT
eurjchem-2544	531	12	a.	a.	NOUN
eurjchem-2544	531	13	;	;	PUNCT
eurjchem-2544	531	14	singh	singh	PROPN
eurjchem-2544	531	15	,	,	PUNCT
eurjchem-2544	531	16	n.	n.	PROPN
eurjchem-2544	531	17	k.	k.	PROPN
eurjchem-2544	531	18	synthesis	synthesis	PROPN
eurjchem-2544	531	19	,	,	PUNCT
eurjchem-2544	531	20	spectral	spectral	ADJ
eurjchem-2544	531	21	and	and	CCONJ
eurjchem-2544	531	22	structural	structural	ADJ
eurjchem-2544	531	23	studies	study	NOUN
eurjchem-2544	531	24	of	of	ADP
eurjchem-2544	531	25	1	1	NUM
eurjchem-2544	531	26	-	-	PUNCT
eurjchem-2544	531	27	ethoxycarbonyl	ethoxycarbonyl	NOUN
eurjchem-2544	531	28	-	-	PUNCT
eurjchem-2544	531	29	piperazine-4	piperazine-4	NOUN
eurjchem-2544	531	30	-	-	PUNCT
eurjchem-2544	531	31	carbodithioate	carbodithioate	NOUN
eurjchem-2544	531	32	and	and	CCONJ
eurjchem-2544	531	33	its	its	PRON
eurjchem-2544	531	34	co(iii	co(iii	NOUN
eurjchem-2544	531	35	)	)	PUNCT
eurjchem-2544	531	36	,	,	PUNCT
eurjchem-2544	531	37	zn(ii	zn(ii	NUM
eurjchem-2544	531	38	)	)	PUNCT
eurjchem-2544	531	39	and	and	CCONJ
eurjchem-2544	531	40	cd(ii	cd(ii	ADJ
eurjchem-2544	531	41	)	)	PUNCT
eurjchem-2544	531	42	complexes	complex	NOUN
eurjchem-2544	531	43	.	.	PUNCT
eurjchem-2544	532	1	polyhedron	polyhedron	NOUN
eurjchem-2544	532	2	2012	2012	NUM
eurjchem-2544	532	3	,	,	PUNCT
eurjchem-2544	532	4	31	31	NUM
eurjchem-2544	532	5	,	,	PUNCT
eurjchem-2544	532	6	373	373	NUM
eurjchem-2544	532	7	–	–	PUNCT
eurjchem-2544	532	8	378	378	NUM
eurjchem-2544	532	9	.	.	PUNCT
eurjchem-2544	533	1	[	[	X
eurjchem-2544	533	2	36	36	NUM
eurjchem-2544	533	3	]	]	PUNCT
eurjchem-2544	533	4	.	.	PUNCT
eurjchem-2544	533	5	gasparri	gasparri	PROPN
eurjchem-2544	533	6	,	,	PUNCT
eurjchem-2544	533	7	g.	g.	PROPN
eurjchem-2544	533	8	f.	f.	PROPN
eurjchem-2544	533	9	;	;	PUNCT
eurjchem-2544	533	10	nardelli	nardelli	PROPN
eurjchem-2544	533	11	,	,	PUNCT
eurjchem-2544	533	12	m.	m.	NOUN
eurjchem-2544	533	13	;	;	PUNCT
eurjchem-2544	533	14	villa	villa	PROPN
eurjchem-2544	533	15	,	,	PUNCT
eurjchem-2544	533	16	a.	a.	NOUN
eurjchem-2544	533	17	the	the	DET
eurjchem-2544	533	18	crystal	crystal	NOUN
eurjchem-2544	533	19	and	and	CCONJ
eurjchem-2544	533	20	molecular	molecular	ADJ
eurjchem-2544	533	21	structure	structure	NOUN
eurjchem-2544	533	22	of	of	ADP
eurjchem-2544	533	23	nickel	nickel	NOUN
eurjchem-2544	533	24	bis(dithiocarbamate	bis(dithiocarbamate	NOUN
eurjchem-2544	533	25	)	)	PUNCT
eurjchem-2544	533	26	.	.	PUNCT
eurjchem-2544	534	1	acta	acta	PROPN
eurjchem-2544	534	2	crystallogr	crystallogr	PROPN
eurjchem-2544	534	3	.	.	PUNCT
eurjchem-2544	535	1	1967	1967	NUM
eurjchem-2544	535	2	,	,	PUNCT
eurjchem-2544	535	3	23	23	NUM
eurjchem-2544	535	4	,	,	PUNCT
eurjchem-2544	535	5	384–391	384–391	NUM
eurjchem-2544	535	6	.	.	PUNCT
eurjchem-2544	536	1	[	[	X
eurjchem-2544	536	2	37	37	NUM
eurjchem-2544	536	3	]	]	PUNCT
eurjchem-2544	536	4	.	.	PUNCT
eurjchem-2544	537	1	newman	newman	PROPN
eurjchem-2544	537	2	,	,	PUNCT
eurjchem-2544	537	3	p.	p.	PROPN
eurjchem-2544	537	4	w.	w.	PROPN
eurjchem-2544	537	5	g.	g.	PROPN
eurjchem-2544	537	6	;	;	PUNCT
eurjchem-2544	537	7	white	white	ADJ
eurjchem-2544	537	8	,	,	PUNCT
eurjchem-2544	537	9	a.	a.	PROPN
eurjchem-2544	537	10	h.	h.	PROPN
eurjchem-2544	537	11	crystal	crystal	PROPN
eurjchem-2544	537	12	structure	structure	NOUN
eurjchem-2544	537	13	of	of	ADP
eurjchem-2544	537	14	bis(nn	bis(nn	NOUN
eurjchem-2544	537	15	-	-	PUNCT
eurjchem-2544	537	16	diisopropyldithiocarbamato)nickel(ii	diisopropyldithiocarbamato)nickel(ii	NOUN
eurjchem-2544	537	17	)	)	PUNCT
eurjchem-2544	537	18	.	.	PUNCT
eurjchem-2544	538	1	j.	j.	PROPN
eurjchem-2544	538	2	chem	chem	PROPN
eurjchem-2544	538	3	.	.	PUNCT
eurjchem-2544	539	1	soc	soc	PROPN
eurjchem-2544	539	2	.	.	PROPN
eurjchem-2544	539	3	,	,	PUNCT
eurjchem-2544	539	4	dalton	dalton	PROPN
eurjchem-2544	539	5	trans	trans	PROPN
eurjchem-2544	539	6	.	.	PROPN
eurjchem-2544	539	7	1972	1972	NUM
eurjchem-2544	539	8	,	,	PUNCT
eurjchem-2544	539	9	2239	2239	NUM
eurjchem-2544	539	10	.	.	PUNCT
eurjchem-2544	540	1	[	[	X
eurjchem-2544	540	2	38	38	NUM
eurjchem-2544	540	3	]	]	PUNCT
eurjchem-2544	540	4	.	.	PUNCT
eurjchem-2544	541	1	newman	newman	PROPN
eurjchem-2544	541	2	,	,	PUNCT
eurjchem-2544	541	3	p.	p.	PROPN
eurjchem-2544	541	4	w.	w.	PROPN
eurjchem-2544	541	5	g.	g.	PROPN
eurjchem-2544	541	6	;	;	PUNCT
eurjchem-2544	541	7	white	white	ADJ
eurjchem-2544	541	8	,	,	PUNCT
eurjchem-2544	541	9	a.	a.	PROPN
eurjchem-2544	541	10	h.	h.	PROPN
eurjchem-2544	541	11	crystal	crystal	PROPN
eurjchem-2544	541	12	structure	structure	NOUN
eurjchem-2544	541	13	of	of	ADP
eurjchem-2544	541	14	bis(n	bis(n	PROPN
eurjchem-2544	541	15	-	-	PUNCT
eurjchem-2544	541	16	methyl	methyl	NOUN
eurjchem-2544	541	17	dithiocarbamato)nickel(ii	dithiocarbamato)nickel(ii	PROPN
eurjchem-2544	541	18	)	)	PUNCT
eurjchem-2544	541	19	.	.	PUNCT
eurjchem-2544	542	1	j.	j.	PROPN
eurjchem-2544	542	2	chem	chem	PROPN
eurjchem-2544	542	3	.	.	PUNCT
eurjchem-2544	543	1	soc	soc	PROPN
eurjchem-2544	543	2	.	.	PROPN
eurjchem-2544	543	3	,	,	PUNCT
eurjchem-2544	543	4	dalton	dalton	PROPN
eurjchem-2544	543	5	trans	trans	PROPN
eurjchem-2544	543	6	.	.	PROPN
eurjchem-2544	544	1	1972	1972	NUM
eurjchem-2544	544	2	,	,	PUNCT
eurjchem-2544	544	3	1460	1460	NUM
eurjchem-2544	544	4	.	.	PUNCT
eurjchem-2544	545	1	[	[	X
eurjchem-2544	545	2	39	39	NUM
eurjchem-2544	545	3	]	]	PUNCT
eurjchem-2544	545	4	.	.	PUNCT
eurjchem-2544	545	5	exarchos	exarchos	PROPN
eurjchem-2544	545	6	,	,	PUNCT
eurjchem-2544	545	7	g.	g.	PROPN
eurjchem-2544	545	8	;	;	PUNCT
eurjchem-2544	545	9	robinson	robinson	PROPN
eurjchem-2544	545	10	,	,	PUNCT
eurjchem-2544	545	11	s.	s.	PROPN
eurjchem-2544	545	12	d.	d.	PROPN
eurjchem-2544	545	13	;	;	PUNCT
eurjchem-2544	545	14	steed	steed	PROPN
eurjchem-2544	545	15	,	,	PUNCT
eurjchem-2544	545	16	j.	j.	PROPN
eurjchem-2544	545	17	w.	w.	PROPN
eurjchem-2544	545	18	the	the	DET
eurjchem-2544	545	19	synthesis	synthesis	NOUN
eurjchem-2544	545	20	of	of	ADP
eurjchem-2544	545	21	new	new	ADJ
eurjchem-2544	545	22	bimetallic	bimetallic	ADJ
eurjchem-2544	545	23	complex	complex	ADJ
eurjchem-2544	545	24	salts	salt	NOUN
eurjchem-2544	545	25	by	by	ADP
eurjchem-2544	545	26	halide	halide	NOUN
eurjchem-2544	545	27	/	/	SYM
eurjchem-2544	545	28	sulfur	sulfur	NOUN
eurjchem-2544	545	29	chelate	chelate	NOUN
eurjchem-2544	545	30	cross	cross	NOUN
eurjchem-2544	545	31	transfer	transfer	NOUN
eurjchem-2544	545	32	:	:	PUNCT
eurjchem-2544	545	33	x	x	X
eurjchem-2544	545	34	-	-	PUNCT
eurjchem-2544	545	35	ray	ray	NOUN
eurjchem-2544	545	36	crystal	crystal	NOUN
eurjchem-2544	545	37	structures	structure	NOUN
eurjchem-2544	545	38	of	of	ADP
eurjchem-2544	545	39	the	the	DET
eurjchem-2544	545	40	salts	salt	NOUN
eurjchem-2544	545	41	[	[	X
eurjchem-2544	545	42	ni(s2cnet2)(dppe)]2[hgbr4	ni(s2cnet2)(dppe)]2[hgbr4	NOUN
eurjchem-2544	545	43	]	]	PUNCT
eurjchem-2544	545	44	,	,	PUNCT
eurjchem-2544	546	1	[	[	X
eurjchem-2544	546	2	pt(s2cnet2)(dppe)]2[cdcl4	pt(s2cnet2)(dppe)]2[cdcl4	X
eurjchem-2544	546	3	]	]	X
eurjchem-2544	546	4	,	,	PUNCT
eurjchem-2544	547	1	[	[	X
eurjchem-2544	547	2	co(s2cnet2)2(dppe)]2[cl3zno:(ph)2pch2ch2p(ph)2	co(s2cnet2)2(dppe)]2[cl3zno:(ph)2pch2ch2p(ph)2	NOUN
eurjchem-2544	547	3	:	:	PUNCT
eurjchem-2544	547	4	ozncl3	ozncl3	PROPN
eurjchem-2544	547	5	]	]	PUNCT
eurjchem-2544	547	6	and	and	CCONJ
eurjchem-2544	547	7	[	[	X
eurjchem-2544	547	8	pd(s2cnnbu2)(bipy)]2[cdcl4	pd(s2cnnbu2)(bipy)]2[cdcl4	NUM
eurjchem-2544	547	9	]	]	PUNCT
eurjchem-2544	547	10	.	.	PUNCT
eurjchem-2544	548	1	polyhedron	polyhedron	PROPN
eurjchem-2544	548	2	2001	2001	NUM
eurjchem-2544	548	3	,	,	PUNCT
eurjchem-2544	548	4	20	20	NUM
eurjchem-2544	548	5	,	,	PUNCT
eurjchem-2544	548	6	2951–2963	2951–2963	NUM
eurjchem-2544	548	7	.	.	PUNCT
eurjchem-2544	549	1	[	[	X
eurjchem-2544	549	2	40	40	NUM
eurjchem-2544	549	3	]	]	PUNCT
eurjchem-2544	549	4	.	.	PUNCT
eurjchem-2544	550	1	ai	ai	PROPN
eurjchem-2544	550	2	-	-	PUNCT
eurjchem-2544	550	3	resayes	resayes	PROPN
eurjchem-2544	550	4	,	,	PUNCT
eurjchem-2544	550	5	s.	s.	PROPN
eurjchem-2544	550	6	i.	i.	PROPN
eurjchem-2544	550	7	;	;	PUNCT
eurjchem-2544	550	8	hitchcock	hitchcock	PROPN
eurjchem-2544	550	9	,	,	PUNCT
eurjchem-2544	550	10	p.	p.	PROPN
eurjchem-2544	550	11	b.	b.	PROPN
eurjchem-2544	550	12	;	;	PUNCT
eurjchem-2544	550	13	nixon	nixon	PROPN
eurjchem-2544	550	14	,	,	PUNCT
eurjchem-2544	550	15	j.	j.	PROPN
eurjchem-2544	550	16	f.	f.	PROPN
eurjchem-2544	550	17	synthesis	synthesis	PROPN
eurjchem-2544	550	18	and	and	CCONJ
eurjchem-2544	550	19	molecular	molecular	ADJ
eurjchem-2544	550	20	structure	structure	NOUN
eurjchem-2544	550	21	of	of	ADP
eurjchem-2544	550	22	the	the	DET
eurjchem-2544	550	23	novel	novel	ADJ
eurjchem-2544	550	24	bimetallic	bimetallic	NOUN
eurjchem-2544	550	25	complex	complex	NOUN
eurjchem-2544	551	1	[	[	X
eurjchem-2544	551	2	cocl2ph2p(o)ch2ch2	cocl2ph2p(o)ch2ch2	NOUN
eurjchem-2544	551	3	p(o)ph22	p(o)ph22	NOUN
eurjchem-2544	551	4	]	]	PUNCT
eurjchem-2544	551	5	,	,	PUNCT
eurjchem-2544	551	6	containing	contain	VERB
eurjchem-2544	551	7	a	a	DET
eurjchem-2544	551	8	14	14	NUM
eurjchem-2544	551	9	-	-	PUNCT
eurjchem-2544	551	10	membered	membere	VERB
eurjchem-2544	551	11	ring	ring	NOUN
eurjchem-2544	551	12	.	.	PUNCT
eurjchem-2544	552	1	j.	j.	PROPN
eurjchem-2544	552	2	chem	chem	PROPN
eurjchem-2544	552	3	.	.	PUNCT
eurjchem-2544	553	1	soc	soc	PROPN
eurjchem-2544	553	2	.	.	PUNCT
eurjchem-2544	554	1	chem	chem	PROPN
eurjchem-2544	554	2	.	.	PUNCT
eurjchem-2544	555	1	commun	commun	PROPN
eurjchem-2544	555	2	.	.	PUNCT
eurjchem-2544	555	3	1991	1991	NUM
eurjchem-2544	555	4	,	,	PUNCT
eurjchem-2544	555	5	78	78	NUM
eurjchem-2544	555	6	.	.	PUNCT
eurjchem-2544	556	1	[	[	X
eurjchem-2544	556	2	41	41	NUM
eurjchem-2544	556	3	]	]	PUNCT
eurjchem-2544	556	4	.	.	PUNCT
eurjchem-2544	557	1	albertin	albertin	PROPN
eurjchem-2544	557	2	,	,	PUNCT
eurjchem-2544	557	3	g.	g.	PROPN
eurjchem-2544	557	4	;	;	PUNCT
eurjchem-2544	557	5	pelizzi	pelizzi	PROPN
eurjchem-2544	557	6	,	,	PUNCT
eurjchem-2544	557	7	g.	g.	PROPN
eurjchem-2544	557	8	;	;	PUNCT
eurjchem-2544	557	9	bordignon	bordignon	NOUN
eurjchem-2544	557	10	,	,	PUNCT
eurjchem-2544	557	11	e.	e.	PROPN
eurjchem-2544	557	12	synthesis	synthesis	NOUN
eurjchem-2544	557	13	and	and	CCONJ
eurjchem-2544	557	14	characterization	characterization	NOUN
eurjchem-2544	557	15	of	of	ADP
eurjchem-2544	557	16	phosphite	phosphite	NOUN
eurjchem-2544	557	17	-	-	PUNCT
eurjchem-2544	557	18	containing	contain	VERB
eurjchem-2544	557	19	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	557	20	)	)	PUNCT
eurjchem-2544	557	21	complexes	complex	NOUN
eurjchem-2544	557	22	obtained	obtain	VERB
eurjchem-2544	557	23	via	via	ADP
eurjchem-2544	557	24	disproportionation	disproportionation	NOUN
eurjchem-2544	557	25	reactions	reaction	NOUN
eurjchem-2544	557	26	of	of	ADP
eurjchem-2544	557	27	pentacoordinate	pentacoordinate	NOUN
eurjchem-2544	557	28	mononitrosyl	mononitrosyl	ADJ
eurjchem-2544	557	29	derivatives	derivative	NOUN
eurjchem-2544	557	30	.	.	PUNCT
eurjchem-2544	558	1	crystal	crystal	NOUN
eurjchem-2544	558	2	structure	structure	NOUN
eurjchem-2544	558	3	of	of	ADP
eurjchem-2544	558	4	trans	trans	PROPN
eurjchem-2544	558	5	-	-	PROPN
eurjchem-2544	558	6	bis(isothiocyanato	bis(isothiocyanato	PROPN
eurjchem-2544	558	7	)	)	PUNCT
eurjchem-2544	558	8	tetrakis(triethyl	tetrakis(triethyl	PROPN
eurjchem-2544	558	9	phosphite)cobalt(iii	phosphite)cobalt(iii	PROPN
eurjchem-2544	558	10	)	)	PUNCT
eurjchem-2544	558	11	tetraphenylborate	tetraphenylborate	NOUN
eurjchem-2544	558	12	.	.	PUNCT
eurjchem-2544	558	13	inorg	inorg	PROPN
eurjchem-2544	558	14	.	.	PUNCT
eurjchem-2544	559	1	chem	chem	PROPN
eurjchem-2544	559	2	.	.	PUNCT
eurjchem-2544	560	1	1983	1983	NUM
eurjchem-2544	560	2	,	,	PUNCT
eurjchem-2544	560	3	22	22	NUM
eurjchem-2544	560	4	,	,	PUNCT
eurjchem-2544	560	5	515–520	515–520	NUM
eurjchem-2544	560	6	.	.	PUNCT
eurjchem-2544	561	1	[	[	X
eurjchem-2544	561	2	42	42	NUM
eurjchem-2544	561	3	]	]	PUNCT
eurjchem-2544	561	4	.	.	PUNCT
eurjchem-2544	562	1	bresciani	bresciani	NOUN
eurjchem-2544	562	2	-	-	PUNCT
eurjchem-2544	562	3	pahor	pahor	NOUN
eurjchem-2544	562	4	,	,	PUNCT
eurjchem-2544	562	5	n.	n.	NOUN
eurjchem-2544	562	6	;	;	PUNCT
eurjchem-2544	562	7	forcolin	forcolin	PROPN
eurjchem-2544	562	8	,	,	PUNCT
eurjchem-2544	562	9	m.	m.	NOUN
eurjchem-2544	562	10	;	;	PUNCT
eurjchem-2544	562	11	marzilli	marzilli	PROPN
eurjchem-2544	562	12	,	,	PUNCT
eurjchem-2544	562	13	l.	l.	PROPN
eurjchem-2544	562	14	g.	g.	PROPN
eurjchem-2544	562	15	;	;	PUNCT
eurjchem-2544	562	16	randaccio	randaccio	NOUN
eurjchem-2544	562	17	,	,	PUNCT
eurjchem-2544	562	18	l.	l.	PROPN
eurjchem-2544	562	19	;	;	PUNCT
eurjchem-2544	562	20	summers	summer	NOUN
eurjchem-2544	562	21	,	,	PUNCT
eurjchem-2544	562	22	m.	m.	PROPN
eurjchem-2544	562	23	f.	f.	PROPN
eurjchem-2544	562	24	;	;	PUNCT
eurjchem-2544	562	25	toscano	toscano	PROPN
eurjchem-2544	562	26	,	,	PUNCT
eurjchem-2544	562	27	p.	p.	PROPN
eurjchem-2544	562	28	j.	j.	PROPN
eurjchem-2544	563	1	organocobalt	organocobalt	PROPN
eurjchem-2544	563	2	b12	b12	NOUN
eurjchem-2544	563	3	models	model	NOUN
eurjchem-2544	563	4	:	:	PUNCT
eurjchem-2544	563	5	axial	axial	ADJ
eurjchem-2544	563	6	ligand	ligand	NOUN
eurjchem-2544	563	7	effects	effect	NOUN
eurjchem-2544	563	8	on	on	ADP
eurjchem-2544	563	9	the	the	DET
eurjchem-2544	563	10	structural	structural	ADJ
eurjchem-2544	563	11	and	and	CCONJ
eurjchem-2544	563	12	coordination	coordination	NOUN
eurjchem-2544	563	13	chemistry	chemistry	NOUN
eurjchem-2544	563	14	of	of	ADP
eurjchem-2544	563	15	cobaloximes	cobaloxime	NOUN
eurjchem-2544	563	16	.	.	PUNCT
eurjchem-2544	564	1	coord	coord	NOUN
eurjchem-2544	564	2	.	.	PUNCT
eurjchem-2544	565	1	chem	chem	PROPN
eurjchem-2544	565	2	.	.	PUNCT
eurjchem-2544	566	1	rev	rev	PROPN
eurjchem-2544	566	2	.	.	PROPN
eurjchem-2544	566	3	1985	1985	NUM
eurjchem-2544	566	4	,	,	PUNCT
eurjchem-2544	566	5	63	63	NUM
eurjchem-2544	566	6	,	,	PUNCT
eurjchem-2544	566	7	1–125	1–125	NUM
eurjchem-2544	566	8	.	.	PUNCT
eurjchem-2544	567	1	[	[	X
eurjchem-2544	567	2	43	43	NUM
eurjchem-2544	567	3	]	]	PUNCT
eurjchem-2544	567	4	.	.	PUNCT
eurjchem-2544	568	1	iwasaki	iwasaki	PROPN
eurjchem-2544	568	2	,	,	PUNCT
eurjchem-2544	568	3	h.	h.	PROPN
eurjchem-2544	568	4	;	;	PUNCT
eurjchem-2544	568	5	kobayashi	kobayashi	PROPN
eurjchem-2544	568	6	,	,	PUNCT
eurjchem-2544	568	7	k.	k.	PROPN
eurjchem-2544	568	8	structure	structure	NOUN
eurjchem-2544	568	9	of	of	ADP
eurjchem-2544	568	10	bis(n	bis(n	PROPN
eurjchem-2544	568	11	,	,	PUNCT
eurjchem-2544	568	12	n	n	CCONJ
eurjchem-2544	568	13	-	-	PUNCT
eurjchem-2544	568	14	diisopropyl	diisopropyl	NOUN
eurjchem-2544	568	15	dithiocarbamato)copper(ii	dithiocarbamato)copper(ii	NOUN
eurjchem-2544	568	16	)	)	PUNCT
eurjchem-2544	568	17	.	.	PUNCT
eurjchem-2544	569	1	acta	acta	PROPN
eurjchem-2544	569	2	crystallogr	crystallogr	PROPN
eurjchem-2544	569	3	.	.	PUNCT
eurjchem-2544	570	1	b	b	NOUN
eurjchem-2544	570	2	1980	1980	NUM
eurjchem-2544	570	3	,	,	PUNCT
eurjchem-2544	570	4	36	36	NUM
eurjchem-2544	570	5	,	,	PUNCT
eurjchem-2544	570	6	1655–1657	1655–1657	NUM
eurjchem-2544	570	7	.	.	PUNCT
eurjchem-2544	571	1	[	[	X
eurjchem-2544	571	2	44	44	NUM
eurjchem-2544	571	3	]	]	PUNCT
eurjchem-2544	571	4	.	.	PUNCT
eurjchem-2544	572	1	ohba	ohba	PROPN
eurjchem-2544	572	2	,	,	PUNCT
eurjchem-2544	572	3	s.	s.	PROPN
eurjchem-2544	572	4	;	;	PUNCT
eurjchem-2544	572	5	saito	saito	PROPN
eurjchem-2544	572	6	,	,	PUNCT
eurjchem-2544	572	7	y.	y.	PROPN
eurjchem-2544	572	8	;	;	PUNCT
eurjchem-2544	572	9	ohishi	ohishi	PROPN
eurjchem-2544	572	10	,	,	PUNCT
eurjchem-2544	572	11	t.	t.	PROPN
eurjchem-2544	572	12	;	;	PUNCT
eurjchem-2544	572	13	kashiwabara	kashiwabara	PROPN
eurjchem-2544	572	14	,	,	PUNCT
eurjchem-2544	572	15	k.	k.	PROPN
eurjchem-2544	572	16	;	;	PUNCT
eurjchem-2544	572	17	fujita	fujita	PROPN
eurjchem-2544	572	18	,	,	PUNCT
eurjchem-2544	572	19	j.	j.	PROPN
eurjchem-2544	572	20	structure	structure	PROPN
eurjchem-2544	572	21	of	of	ADP
eurjchem-2544	572	22	(	(	PUNCT
eurjchem-2544	572	23	+	+	NOUN
eurjchem-2544	572	24	)	)	PUNCT
eurjchem-2544	572	25	589-[1,2bis(dimethylphosphino)ethane]bis(ethylenediamine)cobalt(iii	589-[1,2bis(dimethylphosphino)ethane]bis(ethylenediamine)cobalt(iii	X
eurjchem-2544	572	26	)	)	PUNCT
eurjchem-2544	572	27	tribromide	tribromide	NOUN
eurjchem-2544	572	28	sesquihydrate	sesquihydrate	NOUN
eurjchem-2544	572	29	,	,	PUNCT
eurjchem-2544	572	30	[	[	X
eurjchem-2544	572	31	co(c2h8n2)2(c6h16p2)]br3.3/2h2o	co(c2h8n2)2(c6h16p2)]br3.3/2h2o	NOUN
eurjchem-2544	572	32	.	.	PUNCT
eurjchem-2544	573	1	acta	acta	PROPN
eurjchem-2544	573	2	crystallogr	crystallogr	PROPN
eurjchem-2544	573	3	.	.	PUNCT
eurjchem-2544	574	1	c	c	PROPN
eurjchem-2544	574	2	1983	1983	NUM
eurjchem-2544	574	3	,	,	PUNCT
eurjchem-2544	574	4	39	39	NUM
eurjchem-2544	574	5	,	,	PUNCT
eurjchem-2544	574	6	49–51	49–51	NUM
eurjchem-2544	574	7	.	.	PUNCT
eurjchem-2544	575	1	[	[	X
eurjchem-2544	575	2	45	45	NUM
eurjchem-2544	575	3	]	]	PUNCT
eurjchem-2544	575	4	.	.	PUNCT
eurjchem-2544	576	1	engelhardt	engelhardt	PROPN
eurjchem-2544	576	2	,	,	PUNCT
eurjchem-2544	576	3	l.	l.	PROPN
eurjchem-2544	576	4	m.	m.	PROPN
eurjchem-2544	576	5	;	;	PUNCT
eurjchem-2544	576	6	healy	healy	PROPN
eurjchem-2544	576	7	,	,	PUNCT
eurjchem-2544	576	8	p.	p.	PROPN
eurjchem-2544	576	9	c.	c.	PROPN
eurjchem-2544	576	10	;	;	PUNCT
eurjchem-2544	576	11	shephard	shephard	PROPN
eurjchem-2544	576	12	,	,	PUNCT
eurjchem-2544	576	13	r.	r.	PROPN
eurjchem-2544	576	14	m.	m.	PROPN
eurjchem-2544	576	15	;	;	PUNCT
eurjchem-2544	576	16	skelton	skelton	PROPN
eurjchem-2544	576	17	,	,	PUNCT
eurjchem-2544	576	18	b.	b.	PROPN
eurjchem-2544	576	19	w.	w.	PROPN
eurjchem-2544	576	20	;	;	PUNCT
eurjchem-2544	576	21	white	white	ADJ
eurjchem-2544	576	22	,	,	PUNCT
eurjchem-2544	576	23	a.	a.	PROPN
eurjchem-2544	576	24	h.	h.	PROPN
eurjchem-2544	576	25	lewis	lewis	PROPN
eurjchem-2544	576	26	-	-	PUNCT
eurjchem-2544	576	27	base	base	NOUN
eurjchem-2544	576	28	adducts	adduct	NOUN
eurjchem-2544	576	29	of	of	ADP
eurjchem-2544	576	30	group	group	NOUN
eurjchem-2544	576	31	11	11	NUM
eurjchem-2544	576	32	metal(i	metal(i	ADJ
eurjchem-2544	576	33	)	)	PUNCT
eurjchem-2544	576	34	compounds	compound	NOUN
eurjchem-2544	576	35	.	.	PUNCT
eurjchem-2544	577	1	47	47	NUM
eurjchem-2544	577	2	.	.	PUNCT
eurjchem-2544	578	1	a	a	DET
eurjchem-2544	578	2	novel	novel	ADJ
eurjchem-2544	578	3	series	series	NOUN
eurjchem-2544	578	4	of	of	ADP
eurjchem-2544	578	5	1:1	1:1	NUM
eurjchem-2544	578	6	,	,	PUNCT
eurjchem-2544	578	7	2:1	2:1	NUM
eurjchem-2544	578	8	,	,	PUNCT
eurjchem-2544	578	9	and	and	CCONJ
eurjchem-2544	578	10	3:1	3:1	NUM
eurjchem-2544	578	11	heterobimetallic	heterobimetallic	ADJ
eurjchem-2544	578	12	adducts	adduct	NOUN
eurjchem-2544	578	13	from	from	ADP
eurjchem-2544	578	14	the	the	DET
eurjchem-2544	578	15	reaction	reaction	NOUN
eurjchem-2544	578	16	of	of	ADP
eurjchem-2544	578	17	copper(i	copper(i	NOUN
eurjchem-2544	578	18	)	)	PUNCT
eurjchem-2544	578	19	halides	halide	NOUN
eurjchem-2544	578	20	with	with	ADP
eurjchem-2544	578	21	tris(dithiocarbamato)cobalt(iii	tris(dithiocarbamato)cobalt(iii	NOUN
eurjchem-2544	578	22	)	)	PUNCT
eurjchem-2544	578	23	complexes	complex	NOUN
eurjchem-2544	578	24	.	.	PUNCT
eurjchem-2544	579	1	inorg	inorg	PROPN
eurjchem-2544	579	2	.	.	PUNCT
eurjchem-2544	580	1	chem	chem	PROPN
eurjchem-2544	580	2	.	.	PUNCT
eurjchem-2544	581	1	1988	1988	NUM
eurjchem-2544	581	2	,	,	PUNCT
eurjchem-2544	581	3	27	27	NUM
eurjchem-2544	581	4	,	,	PUNCT
eurjchem-2544	581	5	2371–2373	2371–2373	NUM
eurjchem-2544	581	6	.	.	PUNCT
eurjchem-2544	582	1	[	[	X
eurjchem-2544	582	2	46	46	NUM
eurjchem-2544	582	3	]	]	PUNCT
eurjchem-2544	582	4	.	.	PUNCT
eurjchem-2544	582	5	engelhardt	engelhardt	PROPN
eurjchem-2544	582	6	,	,	PUNCT
eurjchem-2544	582	7	l.	l.	PROPN
eurjchem-2544	582	8	m.	m.	PROPN
eurjchem-2544	582	9	;	;	PUNCT
eurjchem-2544	582	10	healy	healy	PROPN
eurjchem-2544	582	11	,	,	PUNCT
eurjchem-2544	582	12	p.	p.	PROPN
eurjchem-2544	582	13	c.	c.	PROPN
eurjchem-2544	582	14	;	;	PUNCT
eurjchem-2544	582	15	papasergio	papasergio	NOUN
eurjchem-2544	582	16	,	,	PUNCT
eurjchem-2544	582	17	r.	r.	PROPN
eurjchem-2544	582	18	i.	i.	PROPN
eurjchem-2544	582	19	;	;	PUNCT
eurjchem-2544	582	20	white	white	ADJ
eurjchem-2544	582	21	,	,	PUNCT
eurjchem-2544	582	22	a.	a.	PROPN
eurjchem-2544	582	23	h.	h.	PROPN
eurjchem-2544	582	24	lewis	lewis	PROPN
eurjchem-2544	582	25	base	base	PROPN
eurjchem-2544	582	26	adducts	adduct	NOUN
eurjchem-2544	582	27	of	of	ADP
eurjchem-2544	582	28	group	group	NOUN
eurjchem-2544	582	29	11	11	NUM
eurjchem-2544	582	30	metal	metal	NOUN
eurjchem-2544	582	31	compounds	compound	NOUN
eurjchem-2544	582	32	.	.	PUNCT
eurjchem-2544	583	1	10	10	NUM
eurjchem-2544	583	2	.	.	PUNCT
eurjchem-2544	584	1	the	the	DET
eurjchem-2544	584	2	1:1	1:1	NUM
eurjchem-2544	584	3	heterobimetallic	heterobimetallic	ADJ
eurjchem-2544	584	4	adduct	adduct	NOUN
eurjchem-2544	584	5	of	of	ADP
eurjchem-2544	584	6	tris(pyrrolidinecarbodithioato)cobalt(iii	tris(pyrrolidinecarbodithioato)cobalt(iii	NOUN
eurjchem-2544	584	7	)	)	PUNCT
eurjchem-2544	584	8	with	with	ADP
eurjchem-2544	584	9	copper(i	copper(i	PROPN
eurjchem-2544	584	10	)	)	PUNCT
eurjchem-2544	584	11	bromide	bromide	NOUN
eurjchem-2544	584	12	.	.	PUNCT
eurjchem-2544	585	1	inorg	inorg	PROPN
eurjchem-2544	585	2	.	.	PUNCT
eurjchem-2544	586	1	chem	chem	PROPN
eurjchem-2544	586	2	.	.	PUNCT
eurjchem-2544	587	1	1985	1985	NUM
eurjchem-2544	587	2	,	,	PUNCT
eurjchem-2544	587	3	24	24	NUM
eurjchem-2544	587	4	,	,	PUNCT
eurjchem-2544	587	5	382–385	382–385	NUM
eurjchem-2544	587	6	.	.	PUNCT
eurjchem-2544	588	1	[	[	X
eurjchem-2544	588	2	47	47	NUM
eurjchem-2544	588	3	]	]	PUNCT
eurjchem-2544	588	4	.	.	PUNCT
eurjchem-2544	589	1	healy	healy	PROPN
eurjchem-2544	589	2	,	,	PUNCT
eurjchem-2544	589	3	p.	p.	PROPN
eurjchem-2544	589	4	c.	c.	PROPN
eurjchem-2544	589	5	;	;	PUNCT
eurjchem-2544	589	6	skelton	skelton	PROPN
eurjchem-2544	589	7	,	,	PUNCT
eurjchem-2544	589	8	b.	b.	PROPN
eurjchem-2544	589	9	w.	w.	PROPN
eurjchem-2544	589	10	;	;	PUNCT
eurjchem-2544	589	11	white	white	ADJ
eurjchem-2544	589	12	,	,	PUNCT
eurjchem-2544	589	13	a.	a.	PROPN
eurjchem-2544	589	14	h.	h.	PROPN
eurjchem-2544	589	15	lewis	lewis	PROPN
eurjchem-2544	589	16	base	base	PROPN
eurjchem-2544	589	17	adducts	adduct	NOUN
eurjchem-2544	589	18	of	of	ADP
eurjchem-2544	589	19	group	group	NOUN
eurjchem-2544	589	20	11	11	NUM
eurjchem-2544	589	21	metal(i	metal(i	ADJ
eurjchem-2544	589	22	)	)	PUNCT
eurjchem-2544	589	23	complexes	complex	NOUN
eurjchem-2544	589	24	.	.	PUNCT
eurjchem-2544	590	1	part	part	NOUN
eurjchem-2544	590	2	48	48	NUM
eurjchem-2544	590	3	.	.	PUNCT
eurjchem-2544	591	1	heterobimetallic	heterobimetallic	PROPN
eurjchem-2544	591	2	tris(dithio	tris(dithio	PROPN
eurjchem-2544	591	3	carbamato)cobalt(iii)–copper(i	carbamato)cobalt(iii)–copper(i	PROPN
eurjchem-2544	591	4	)	)	PUNCT
eurjchem-2544	591	5	halide	halide	NOUN
eurjchem-2544	591	6	adducts	adduct	NOUN
eurjchem-2544	591	7	as	as	ADP
eurjchem-2544	591	8	a	a	DET
eurjchem-2544	591	9	vehicle	vehicle	NOUN
eurjchem-2544	591	10	for	for	ADP
eurjchem-2544	591	11	novel	novel	NOUN
eurjchem-2544	591	12	copper(i	copper(i	NOUN
eurjchem-2544	591	13	)	)	PUNCT
eurjchem-2544	591	14	halide	halide	NOUN
eurjchem-2544	591	15	clusters	cluster	NOUN
eurjchem-2544	591	16	(	(	PUNCT
eurjchem-2544	591	17	structurally	structurally	ADV
eurjchem-2544	591	18	characterized	characterize	VERB
eurjchem-2544	591	19	)	)	PUNCT
eurjchem-2544	591	20	.	.	PUNCT
eurjchem-2544	592	1	j.	j.	PROPN
eurjchem-2544	592	2	chem	chem	PROPN
eurjchem-2544	592	3	.	.	PUNCT
eurjchem-2544	593	1	soc	soc	PROPN
eurjchem-2544	593	2	.	.	PROPN
eurjchem-2544	593	3	,	,	PUNCT
eurjchem-2544	593	4	dalton	dalton	PROPN
eurjchem-2544	593	5	trans	trans	PROPN
eurjchem-2544	593	6	.	.	PROPN
eurjchem-2544	593	7	1989	1989	NUM
eurjchem-2544	593	8	,	,	PUNCT
eurjchem-2544	593	9	971–976	971–976	NUM
eurjchem-2544	593	10	.	.	PUNCT
eurjchem-2544	594	1	[	[	X
eurjchem-2544	594	2	48	48	NUM
eurjchem-2544	594	3	]	]	PUNCT
eurjchem-2544	594	4	.	.	PUNCT
eurjchem-2544	594	5	butcher	butcher	NOUN
eurjchem-2544	594	6	,	,	PUNCT
eurjchem-2544	594	7	r.	r.	PROPN
eurjchem-2544	594	8	j.	j.	PROPN
eurjchem-2544	594	9	;	;	PUNCT
eurjchem-2544	594	10	sinn	sinn	PROPN
eurjchem-2544	594	11	,	,	PUNCT
eurjchem-2544	594	12	e.	e.	PROPN
eurjchem-2544	594	13	crystal	crystal	PROPN
eurjchem-2544	594	14	and	and	CCONJ
eurjchem-2544	594	15	molecular	molecular	ADJ
eurjchem-2544	594	16	structures	structure	NOUN
eurjchem-2544	594	17	of	of	ADP
eurjchem-2544	594	18	dichloromethane	dichloromethane	NOUN
eurjchem-2544	594	19	-	-	PUNCT
eurjchem-2544	594	20	solvated	solvate	VERB
eurjchem-2544	594	21	tris(morpholinocarbodithioato)complexes	tris(morpholinocarbodithioato)complexe	NOUN
eurjchem-2544	594	22	of	of	ADP
eurjchem-2544	594	23	chromium(iii	chromium(iii	NOUN
eurjchem-2544	594	24	)	)	PUNCT
eurjchem-2544	594	25	,	,	PUNCT
eurjchem-2544	594	26	manganese(iii	manganese(iii	NOUN
eurjchem-2544	594	27	)	)	PUNCT
eurjchem-2544	594	28	,	,	PUNCT
eurjchem-2544	594	29	and	and	CCONJ
eurjchem-2544	594	30	rhodium(iii	rhodium(iii	NOUN
eurjchem-2544	594	31	)	)	PUNCT
eurjchem-2544	594	32	.	.	PUNCT
eurjchem-2544	595	1	comparison	comparison	NOUN
eurjchem-2544	595	2	of	of	ADP
eurjchem-2544	595	3	co	co	ADJ
eurjchem-2544	595	4	-	-	NOUN
eurjchem-2544	595	5	ordination	ordination	ADJ
eurjchem-2544	595	6	spheres	sphere	NOUN
eurjchem-2544	595	7	.	.	PUNCT
eurjchem-2544	596	1	j.	j.	PROPN
eurjchem-2544	596	2	chem	chem	PROPN
eurjchem-2544	596	3	.	.	PUNCT
eurjchem-2544	597	1	soc	soc	PROPN
eurjchem-2544	597	2	.	.	PROPN
eurjchem-2544	597	3	,	,	PUNCT
eurjchem-2544	597	4	dalton	dalton	PROPN
eurjchem-2544	597	5	trans	trans	PROPN
eurjchem-2544	597	6	.	.	PROPN
eurjchem-2544	598	1	1975	1975	NUM
eurjchem-2544	598	2	,	,	PUNCT
eurjchem-2544	598	3	2517	2517	NUM
eurjchem-2544	598	4	.	.	PUNCT
eurjchem-2544	599	1	[	[	X
eurjchem-2544	599	2	49	49	NUM
eurjchem-2544	599	3	]	]	PUNCT
eurjchem-2544	599	4	.	.	PUNCT
eurjchem-2544	599	5	healy	healy	PROPN
eurjchem-2544	599	6	,	,	PUNCT
eurjchem-2544	599	7	p.	p.	PROPN
eurjchem-2544	599	8	c.	c.	PROPN
eurjchem-2544	599	9	;	;	PUNCT
eurjchem-2544	599	10	sinn	sinn	PROPN
eurjchem-2544	599	11	,	,	PUNCT
eurjchem-2544	599	12	e.	e.	PROPN
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eurjchem-2544	599	14	tris(4	tris(4	NOUN
eurjchem-2544	599	15	-	-	PUNCT
eurjchem-2544	599	16	morpholinecarbodithioato	morpholinecarbodithioato	NOUN
eurjchem-2544	599	17	-	-	PUNCT
eurjchem-2544	599	18	s	s	PROPN
eurjchem-2544	599	19	,	,	PUNCT
eurjchem-2544	599	20	s	s	NOUN
eurjchem-2544	599	21	’	'	PUNCT
eurjchem-2544	599	22	)	)	PUNCT
eurjchem-2544	599	23	complexes	complex	NOUN
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eurjchem-2544	599	25	iron(iii	iron(iii	NOUN
eurjchem-2544	599	26	)	)	PUNCT
eurjchem-2544	599	27	and	and	CCONJ
eurjchem-2544	599	28	cobalt(iii	cobalt(iii	NOUN
eurjchem-2544	599	29	)	)	PUNCT
eurjchem-2544	599	30	.	.	PUNCT
eurjchem-2544	600	1	direct	direct	ADJ
eurjchem-2544	600	2	comparison	comparison	NOUN
eurjchem-2544	600	3	of	of	ADP
eurjchem-2544	600	4	d5	d5	NOUN
eurjchem-2544	600	5	and	and	CCONJ
eurjchem-2544	600	6	d6	d6	NOUN
eurjchem-2544	600	7	analogs	analog	NOUN
eurjchem-2544	600	8	and	and	CCONJ
eurjchem-2544	600	9	study	study	NOUN
eurjchem-2544	600	10	of	of	ADP
eurjchem-2544	600	11	solvation	solvation	NOUN
eurjchem-2544	600	12	effects	effect	NOUN
eurjchem-2544	600	13	.	.	PUNCT
eurjchem-2544	601	1	inorg	inorg	PROPN
eurjchem-2544	601	2	.	.	PUNCT
eurjchem-2544	602	1	chem	chem	PROPN
eurjchem-2544	602	2	.	.	PUNCT
eurjchem-2544	603	1	1975	1975	NUM
eurjchem-2544	603	2	,	,	PUNCT
eurjchem-2544	603	3	14	14	NUM
eurjchem-2544	603	4	,	,	PUNCT
eurjchem-2544	603	5	109–115	109–115	NUM
eurjchem-2544	603	6	.	.	PUNCT
eurjchem-2544	604	1	[	[	X
eurjchem-2544	604	2	50	50	NUM
eurjchem-2544	604	3	]	]	PUNCT
eurjchem-2544	604	4	.	.	PUNCT
eurjchem-2544	605	1	raston	raston	PROPN
eurjchem-2544	605	2	,	,	PUNCT
eurjchem-2544	605	3	c.	c.	PROPN
eurjchem-2544	605	4	l.	l.	PROPN
eurjchem-2544	605	5	;	;	PUNCT
eurjchem-2544	605	6	white	white	ADJ
eurjchem-2544	605	7	,	,	PUNCT
eurjchem-2544	605	8	a.	a.	PROPN
eurjchem-2544	605	9	h.	h.	PROPN
eurjchem-2544	605	10	crystal	crystal	PROPN
eurjchem-2544	605	11	structures	structure	NOUN
eurjchem-2544	605	12	of	of	ADP
eurjchem-2544	605	13	tris(diethyldi	tris(diethyldi	PROPN
eurjchem-2544	605	14	thiocarbamato)-rhodium(iii	thiocarbamato)-rhodium(iii	NOUN
eurjchem-2544	605	15	)	)	PUNCT
eurjchem-2544	605	16	and	and	CCONJ
eurjchem-2544	605	17	-arsenic(iii	-arsenic(iii	PRON
eurjchem-2544	605	18	)	)	PUNCT
eurjchem-2544	605	19	.	.	PUNCT
eurjchem-2544	606	1	j.	j.	PROPN
eurjchem-2544	606	2	chem	chem	PROPN
eurjchem-2544	606	3	.	.	PUNCT
eurjchem-2544	607	1	soc	soc	PROPN
eurjchem-2544	607	2	.	.	PROPN
eurjchem-2544	607	3	,	,	PUNCT
eurjchem-2544	607	4	dalton	dalton	PROPN
eurjchem-2544	607	5	trans	trans	PROPN
eurjchem-2544	607	6	.	.	PROPN
eurjchem-2544	608	1	1975	1975	NUM
eurjchem-2544	608	2	,	,	PUNCT
eurjchem-2544	608	3	2425	2425	NUM
eurjchem-2544	608	4	.	.	PUNCT
eurjchem-2544	609	1	[	[	X
eurjchem-2544	609	2	51	51	NUM
eurjchem-2544	609	3	]	]	PUNCT
eurjchem-2544	609	4	.	.	PUNCT
eurjchem-2544	610	1	cano	cano	PROPN
eurjchem-2544	610	2	,	,	PUNCT
eurjchem-2544	610	3	m.	m.	NOUN
eurjchem-2544	610	4	;	;	PUNCT
eurjchem-2544	610	5	ovejero	ovejero	ADJ
eurjchem-2544	610	6	,	,	PUNCT
eurjchem-2544	610	7	p.	p.	NOUN
eurjchem-2544	610	8	;	;	PUNCT
eurjchem-2544	610	9	heras	hera	NOUN
eurjchem-2544	610	10	,	,	PUNCT
eurjchem-2544	610	11	j.	j.	PROPN
eurjchem-2544	610	12	v.	v.	PROPN
eurjchem-2544	610	13	;	;	PUNCT
eurjchem-2544	610	14	pinilla	pinilla	NOUN
eurjchem-2544	610	15	,	,	PUNCT
eurjchem-2544	610	16	e.	e.	PROPN
eurjchem-2544	610	17	;	;	PUNCT
eurjchem-2544	610	18	ruiz	ruiz	PROPN
eurjchem-2544	610	19	,	,	PUNCT
eurjchem-2544	610	20	f.	f.	PROPN
eurjchem-2544	610	21	a.	a.	PROPN
eurjchem-2544	610	22	;	;	PUNCT
eurjchem-2544	610	23	monge	monge	PROPN
eurjchem-2544	610	24	,	,	PUNCT
eurjchem-2544	610	25	a.	a.	NOUN
eurjchem-2544	610	26	the	the	DET
eurjchem-2544	610	27	reactivity	reactivity	NOUN
eurjchem-2544	610	28	of	of	ADP
eurjchem-2544	610	29	[	[	X
eurjchem-2544	610	30	rh(s2cnet2	rh(s2cnet2	NOUN
eurjchem-2544	610	31	)	)	PUNCT
eurjchem-2544	610	32	(	(	PUNCT
eurjchem-2544	610	33	co)2	co)2	NOUN
eurjchem-2544	610	34	]	]	PUNCT
eurjchem-2544	610	35	towards	towards	ADP
eurjchem-2544	610	36	hpzan	hpzan	NOUN
eurjchem-2544	610	37	.	.	PUNCT
eurjchem-2544	611	1	polyhedron	polyhedron	NOUN
eurjchem-2544	611	2	1998	1998	NUM
eurjchem-2544	611	3	,	,	PUNCT
eurjchem-2544	611	4	17	17	NUM
eurjchem-2544	611	5	,	,	PUNCT
eurjchem-2544	611	6	2115–2125	2115–2125	NUM
eurjchem-2544	611	7	.	.	PUNCT
eurjchem-2544	612	1	[	[	X
eurjchem-2544	612	2	52	52	NUM
eurjchem-2544	612	3	]	]	PUNCT
eurjchem-2544	612	4	.	.	PUNCT
eurjchem-2544	613	1	raston	raston	PROPN
eurjchem-2544	613	2	,	,	PUNCT
eurjchem-2544	613	3	c.	c.	PROPN
eurjchem-2544	613	4	l.	l.	PROPN
eurjchem-2544	613	5	;	;	PUNCT
eurjchem-2544	613	6	white	white	ADJ
eurjchem-2544	613	7	,	,	PUNCT
eurjchem-2544	613	8	a.	a.	PROPN
eurjchem-2544	613	9	h.	h.	PROPN
eurjchem-2544	613	10	crystal	crystal	PROPN
eurjchem-2544	613	11	structure	structure	NOUN
eurjchem-2544	613	12	of	of	ADP
eurjchem-2544	613	13	tris(diethyldithioby	tris(diethyldithioby	PROPN
eurjchem-2544	613	14	carbamato)iridium(iii	carbamato)iridium(iii	PART
eurjchem-2544	613	15	)	)	PUNCT
eurjchem-2544	613	16	.	.	PUNCT
eurjchem-2544	614	1	j.	j.	PROPN
eurjchem-2544	614	2	chem	chem	PROPN
eurjchem-2544	614	3	.	.	PUNCT
eurjchem-2544	615	1	soc	soc	PROPN
eurjchem-2544	615	2	.	.	PROPN
eurjchem-2544	615	3	,	,	PUNCT
eurjchem-2544	615	4	dalton	dalton	PROPN
eurjchem-2544	615	5	trans	trans	PROPN
eurjchem-2544	615	6	.	.	PROPN
eurjchem-2544	615	7	1976	1976	NUM
eurjchem-2544	615	8	,	,	PUNCT
eurjchem-2544	615	9	32	32	NUM
eurjchem-2544	615	10	.	.	PUNCT
eurjchem-2544	616	1	[	[	X
eurjchem-2544	616	2	53	53	NUM
eurjchem-2544	616	3	]	]	PUNCT
eurjchem-2544	616	4	.	.	PUNCT
eurjchem-2544	617	1	leipoldt	leipoldt	PROPN
eurjchem-2544	617	2	,	,	PUNCT
eurjchem-2544	617	3	j.	j.	PROPN
eurjchem-2544	617	4	g.	g.	PROPN
eurjchem-2544	617	5	;	;	PUNCT
eurjchem-2544	617	6	coppens	coppen	NOUN
eurjchem-2544	617	7	,	,	PUNCT
eurjchem-2544	617	8	p.	p.	NOUN
eurjchem-2544	617	9	correlation	correlation	NOUN
eurjchem-2544	617	10	between	between	ADP
eurjchem-2544	617	11	structureand	structureand	NOUN
eurjchem-2544	617	12	temperature	temperature	NOUN
eurjchem-2544	617	13	-	-	PUNCT
eurjchem-2544	617	14	dependent	dependent	ADJ
eurjchem-2544	617	15	magnetic	magnetic	ADJ
eurjchem-2544	617	16	behavior	behavior	NOUN
eurjchem-2544	617	17	of	of	ADP
eurjchem-2544	617	18	iron	iron	NOUN
eurjchem-2544	617	19	dithiocarbamate	dithiocarbamate	ADJ
eurjchem-2544	617	20	complexes	complex	NOUN
eurjchem-2544	617	21	.	.	PUNCT
eurjchem-2544	618	1	crystal	crystal	NOUN
eurjchem-2544	618	2	structure	structure	NOUN
eurjchem-2544	618	3	of	of	ADP
eurjchem-2544	618	4	tris(n	tris(n	PROPN
eurjchem-2544	618	5	,	,	PUNCT
eurjchem-2544	618	6	n	n	PRON
eurjchem-2544	618	7	diethyldithiocarbamato	diethyldithiocarbamato	NOUN
eurjchem-2544	618	8	)	)	PUNCT
eurjchem-2544	618	9	iron(iii	iron(iii	NOUN
eurjchem-2544	618	10	)	)	PUNCT
eurjchem-2544	618	11	at	at	ADP
eurjchem-2544	618	12	297.deg	297.deg	NUM
eurjchem-2544	618	13	.	.	PUNCT
eurjchem-2544	618	14	and	and	CCONJ
eurjchem-2544	618	15	79.deg.k	79.deg.k	NUM
eurjchem-2544	618	16	.	.	PUNCT
eurjchem-2544	618	17	inorg	inorg	PROPN
eurjchem-2544	618	18	.	.	PUNCT
eurjchem-2544	619	1	chem	chem	PROPN
eurjchem-2544	619	2	.	.	PUNCT
eurjchem-2544	620	1	1973	1973	NUM
eurjchem-2544	620	2	,	,	PUNCT
eurjchem-2544	620	3	12	12	NUM
eurjchem-2544	620	4	,	,	PUNCT
eurjchem-2544	620	5	2269–2274	2269–2274	NUM
eurjchem-2544	620	6	.	.	PUNCT
eurjchem-2544	621	1	[	[	X
eurjchem-2544	621	2	54	54	NUM
eurjchem-2544	621	3	]	]	PUNCT
eurjchem-2544	621	4	.	.	PUNCT
eurjchem-2544	622	1	pignolet	pignolet	PROPN
eurjchem-2544	622	2	,	,	PUNCT
eurjchem-2544	622	3	l.	l.	PROPN
eurjchem-2544	622	4	h.	h.	PROPN
eurjchem-2544	622	5	dynamic	dynamic	ADJ
eurjchem-2544	622	6	stereochemistry	stereochemistry	NOUN
eurjchem-2544	622	7	of	of	ADP
eurjchem-2544	622	8	tris	tris	ADJ
eurjchem-2544	622	9	-	-	PUNCT
eurjchem-2544	622	10	chelate	chelate	NOUN
eurjchem-2544	622	11	complexes	complex	NOUN
eurjchem-2544	622	12	.	.	PUNCT
eurjchem-2544	623	1	iv	iv	X
eurjchem-2544	623	2	.	.	PUNCT
eurjchem-2544	623	3	crystal	crystal	NOUN
eurjchem-2544	623	4	structure	structure	NOUN
eurjchem-2544	623	5	of	of	ADP
eurjchem-2544	623	6	tris(n	tris(n	PROPN
eurjchem-2544	623	7	,	,	PUNCT
eurjchem-2544	623	8	n	n	CCONJ
eurjchem-2544	623	9	-	-	PUNCT
eurjchem-2544	623	10	diethyldithiocarbamato)ruthenium(iii	diethyldithiocarbamato)ruthenium(iii	PROPN
eurjchem-2544	623	11	)	)	PUNCT
eurjchem-2544	623	12	.	.	PUNCT
eurjchem-2544	624	1	inorg	inorg	PROPN
eurjchem-2544	624	2	.	.	PUNCT
eurjchem-2544	625	1	chem	chem	PROPN
eurjchem-2544	625	2	.	.	PUNCT
eurjchem-2544	626	1	1974	1974	NUM
eurjchem-2544	626	2	,	,	PUNCT
eurjchem-2544	626	3	13	13	NUM
eurjchem-2544	626	4	,	,	PUNCT
eurjchem-2544	626	5	2051–2055	2051–2055	NUM
eurjchem-2544	626	6	.	.	PUNCT
eurjchem-2544	627	1	copyright	copyright	NOUN
eurjchem-2544	627	2	©	©	ADP
eurjchem-2544	627	3	2024	2024	NUM
eurjchem-2544	627	4	by	by	ADP
eurjchem-2544	627	5	authors	author	NOUN
eurjchem-2544	627	6	.	.	PUNCT
eurjchem-2544	628	1	this	this	DET
eurjchem-2544	628	2	work	work	NOUN
eurjchem-2544	628	3	is	be	AUX
eurjchem-2544	628	4	published	publish	VERB
eurjchem-2544	628	5	and	and	CCONJ
eurjchem-2544	628	6	licensed	license	VERB
eurjchem-2544	628	7	by	by	ADP
eurjchem-2544	628	8	atlanta	atlanta	PROPN
eurjchem-2544	628	9	publishing	publishing	PROPN
eurjchem-2544	628	10	house	house	PROPN
eurjchem-2544	628	11	llc	llc	PROPN
eurjchem-2544	628	12	,	,	PUNCT
eurjchem-2544	628	13	atlanta	atlanta	PROPN
eurjchem-2544	628	14	,	,	PUNCT
eurjchem-2544	628	15	ga	ga	PROPN
eurjchem-2544	628	16	,	,	PUNCT
eurjchem-2544	628	17	usa	usa	PROPN
eurjchem-2544	628	18	.	.	PUNCT
eurjchem-2544	629	1	the	the	DET
eurjchem-2544	629	2	full	full	ADJ
eurjchem-2544	629	3	terms	term	NOUN
eurjchem-2544	629	4	of	of	ADP
eurjchem-2544	629	5	this	this	DET
eurjchem-2544	629	6	license	license	NOUN
eurjchem-2544	629	7	are	be	AUX
eurjchem-2544	629	8	available	available	ADJ
eurjchem-2544	629	9	at	at	ADP
eurjchem-2544	629	10	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2544	629	11	and	and	CCONJ
eurjchem-2544	629	12	incorporate	incorporate	VERB
eurjchem-2544	629	13	the	the	DET
eurjchem-2544	629	14	creative	creative	ADJ
eurjchem-2544	629	15	commons	common	NOUN
eurjchem-2544	629	16	attribution	attribution	NOUN
eurjchem-2544	629	17	-	-	PUNCT
eurjchem-2544	629	18	non	non	ADJ
eurjchem-2544	629	19	commercial	commercial	NOUN
eurjchem-2544	629	20	(	(	PUNCT
eurjchem-2544	629	21	cc	cc	NOUN
eurjchem-2544	629	22	by	by	ADP
eurjchem-2544	629	23	nc	nc	PROPN
eurjchem-2544	629	24	)	)	PUNCT
eurjchem-2544	629	25	(	(	PUNCT
eurjchem-2544	629	26	international	international	ADJ
eurjchem-2544	629	27	,	,	PUNCT
eurjchem-2544	629	28	v4.0	v4.0	NOUN
eurjchem-2544	629	29	)	)	PUNCT
eurjchem-2544	629	30	license	license	NOUN
eurjchem-2544	629	31	(	(	PUNCT
eurjchem-2544	629	32	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	NOUN
eurjchem-2544	629	33	)	)	PUNCT
eurjchem-2544	629	34	.	.	PUNCT
eurjchem-2544	630	1	by	by	ADP
eurjchem-2544	630	2	accessing	access	VERB
eurjchem-2544	630	3	the	the	DET
eurjchem-2544	630	4	work	work	NOUN
eurjchem-2544	630	5	,	,	PUNCT
eurjchem-2544	630	6	you	you	PRON
eurjchem-2544	630	7	hereby	hereby	ADV
eurjchem-2544	630	8	accept	accept	VERB
eurjchem-2544	630	9	the	the	DET
eurjchem-2544	630	10	terms	term	NOUN
eurjchem-2544	630	11	.	.	PUNCT
eurjchem-2544	631	1	this	this	PRON
eurjchem-2544	631	2	is	be	AUX
eurjchem-2544	631	3	an	an	DET
eurjchem-2544	631	4	open	open	ADJ
eurjchem-2544	631	5	access	access	NOUN
eurjchem-2544	631	6	article	article	NOUN
eurjchem-2544	631	7	distributed	distribute	VERB
eurjchem-2544	631	8	under	under	ADP
eurjchem-2544	631	9	the	the	DET
eurjchem-2544	631	10	terms	term	NOUN
eurjchem-2544	631	11	and	and	CCONJ
eurjchem-2544	631	12	conditions	condition	NOUN
eurjchem-2544	631	13	of	of	ADP
eurjchem-2544	631	14	the	the	DET
eurjchem-2544	631	15	cc	cc	PROPN
eurjchem-2544	631	16	by	by	ADP
eurjchem-2544	631	17	nc	nc	PROPN
eurjchem-2544	631	18	license	license	PROPN
eurjchem-2544	631	19	,	,	PUNCT
eurjchem-2544	631	20	which	which	PRON
eurjchem-2544	631	21	permits	permit	VERB
eurjchem-2544	631	22	unrestricted	unrestricted	ADJ
eurjchem-2544	631	23	non	non	ADJ
eurjchem-2544	631	24	-	-	ADJ
eurjchem-2544	631	25	commercial	commercial	ADJ
eurjchem-2544	631	26	use	use	NOUN
eurjchem-2544	631	27	,	,	PUNCT
eurjchem-2544	631	28	distribution	distribution	NOUN
eurjchem-2544	631	29	,	,	PUNCT
eurjchem-2544	631	30	and	and	CCONJ
eurjchem-2544	631	31	reproduction	reproduction	NOUN
eurjchem-2544	631	32	in	in	ADP
eurjchem-2544	631	33	any	any	DET
eurjchem-2544	631	34	medium	medium	NOUN
eurjchem-2544	631	35	,	,	PUNCT
eurjchem-2544	631	36	provided	provide	VERB
eurjchem-2544	631	37	the	the	DET
eurjchem-2544	631	38	original	original	ADJ
eurjchem-2544	631	39	work	work	NOUN
eurjchem-2544	631	40	is	be	AUX
eurjchem-2544	631	41	properly	properly	ADV
eurjchem-2544	631	42	cited	cite	VERB
eurjchem-2544	631	43	without	without	ADP
eurjchem-2544	631	44	any	any	DET
eurjchem-2544	631	45	further	further	ADJ
eurjchem-2544	631	46	permission	permission	NOUN
eurjchem-2544	631	47	from	from	ADP
eurjchem-2544	631	48	atlanta	atlanta	PROPN
eurjchem-2544	631	49	publishing	publishing	PROPN
eurjchem-2544	631	50	house	house	PROPN
eurjchem-2544	631	51	llc	llc	PROPN
eurjchem-2544	631	52	(	(	PUNCT
eurjchem-2544	631	53	european	european	PROPN
eurjchem-2544	631	54	journal	journal	PROPN
eurjchem-2544	631	55	of	of	ADP
eurjchem-2544	631	56	chemistry	chemistry	NOUN
eurjchem-2544	631	57	)	)	PUNCT
eurjchem-2544	631	58	.	.	PUNCT
eurjchem-2544	632	1	no	no	DET
eurjchem-2544	632	2	use	use	NOUN
eurjchem-2544	632	3	,	,	PUNCT
eurjchem-2544	632	4	distribution	distribution	NOUN
eurjchem-2544	632	5	,	,	PUNCT
eurjchem-2544	632	6	or	or	CCONJ
eurjchem-2544	632	7	reproduction	reproduction	NOUN
eurjchem-2544	632	8	is	be	AUX
eurjchem-2544	632	9	permitted	permit	VERB
eurjchem-2544	632	10	which	which	PRON
eurjchem-2544	632	11	does	do	AUX
eurjchem-2544	632	12	not	not	PART
eurjchem-2544	632	13	comply	comply	VERB
eurjchem-2544	632	14	with	with	ADP
eurjchem-2544	632	15	these	these	DET
eurjchem-2544	632	16	terms	term	NOUN
eurjchem-2544	632	17	.	.	PUNCT
eurjchem-2544	633	1	permissions	permission	NOUN
eurjchem-2544	633	2	for	for	ADP
eurjchem-2544	633	3	commercial	commercial	ADJ
eurjchem-2544	633	4	use	use	NOUN
eurjchem-2544	633	5	of	of	ADP
eurjchem-2544	633	6	this	this	DET
eurjchem-2544	633	7	work	work	NOUN
eurjchem-2544	633	8	beyond	beyond	ADP
eurjchem-2544	633	9	the	the	DET
eurjchem-2544	633	10	scope	scope	NOUN
eurjchem-2544	633	11	of	of	ADP
eurjchem-2544	633	12	the	the	DET
eurjchem-2544	633	13	license	license	NOUN
eurjchem-2544	633	14	(	(	PUNCT
eurjchem-2544	633	15	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2544	633	16	)	)	PUNCT
eurjchem-2544	633	17	are	be	AUX
eurjchem-2544	633	18	administered	administer	VERB
eurjchem-2544	633	19	by	by	ADP
eurjchem-2544	633	20	atlanta	atlanta	PROPN
eurjchem-2544	633	21	publishing	publishing	PROPN
eurjchem-2544	633	22	house	house	PROPN
eurjchem-2544	633	23	llc	llc	PROPN
eurjchem-2544	633	24	(	(	PUNCT
eurjchem-2544	633	25	european	european	PROPN
eurjchem-2544	633	26	journal	journal	PROPN
eurjchem-2544	633	27	of	of	ADP
eurjchem-2544	633	28	chemistry	chemistry	NOUN
eurjchem-2544	633	29	)	)	PUNCT
eurjchem-2544	633	30	.	.	PUNCT
eurjchem-2544	634	1	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	VERB
eurjchem-2544	634	2	http://creativecommons.org/licenses/by-nc/4.0	http://creativecommons.org/licenses/by-nc/4.0	PROPN
eurjchem-2544	634	3	https://www.eurjchem.com/index.php/eurjchem/terms	https://www.eurjchem.com/index.php/eurjchem/term	NOUN
eurjchem-2544	634	4	1	1	NUM
eurjchem-2544	634	5	.	.	PUNCT
eurjchem-2544	635	1	introduction	introduction	NOUN
eurjchem-2544	635	2	2	2	NUM
eurjchem-2544	635	3	.	.	PUNCT
eurjchem-2544	635	4	single	single	ADJ
eurjchem-2544	635	5	dithiocarbamato	dithiocarbamato	NOUN
eurjchem-2544	635	6	and	and	CCONJ
eurjchem-2544	635	7	mixed	mixed	ADJ
eurjchem-2544	635	8	ligand	ligand	NOUN
eurjchem-2544	635	9	m(iii	m(iii	NOUN
eurjchem-2544	635	10	)	)	PUNCT
eurjchem-2544	635	11	complexes	complexe	VERB
eurjchem-2544	635	12	2.1	2.1	NUM
eurjchem-2544	635	13	.	.	PUNCT
eurjchem-2544	636	1	co(iii	co(iii	NOUN
eurjchem-2544	636	2	)	)	PUNCT
eurjchem-2544	636	3	complexes	complexe	VERB
eurjchem-2544	636	4	2.2	2.2	NUM
eurjchem-2544	636	5	.	.	PUNCT
eurjchem-2544	637	1	rh(iii	rh(iii	NOUN
eurjchem-2544	637	2	)	)	PUNCT
eurjchem-2544	637	3	complexes	complexe	VERB
eurjchem-2544	637	4	2.3	2.3	NUM
eurjchem-2544	637	5	.	.	PUNCT
eurjchem-2544	638	1	ir(iii	ir(iii	NOUN
eurjchem-2544	638	2	)	)	PUNCT
eurjchem-2544	638	3	complexes	complexe	VERB
eurjchem-2544	638	4	3	3	NUM
eurjchem-2544	638	5	.	.	PUNCT
eurjchem-2544	638	6	conclusions	conclusion	NOUN
eurjchem-2544	638	7	and	and	CCONJ
eurjchem-2544	638	8	future	future	ADJ
eurjchem-2544	638	9	perspectives	perspective	NOUN
eurjchem-2544	638	10	acknowledgements	acknowledgement	VERB
eurjchem-2544	638	11	disclosure	disclosure	NOUN
eurjchem-2544	638	12	statement	statement	NOUN
eurjchem-2544	638	13	credit	credit	NOUN
eurjchem-2544	638	14	authorship	authorship	NOUN
eurjchem-2544	638	15	contribution	contribution	NOUN
eurjchem-2544	638	16	statement	statement	NOUN
eurjchem-2544	638	17	orcid	orcid	NOUN
eurjchem-2544	638	18	and	and	CCONJ
eurjchem-2544	638	19	email	email	NOUN
eurjchem-2544	638	20	references	reference	NOUN
eurjchem-2544	638	21	printfield10	printfield10	PROPN
eurjchem-2544	638	22	:	:	PUNCT
eurjchem-2544	638	23	printfield11	printfield11	NOUN
eurjchem-2544	638	24	:	:	PUNCT
eurjchem-2544	638	25	printfield12	printfield12	PROPN
eurjchem-2544	638	26	:	:	PUNCT
eurjchem-2544	638	27	printfield13	printfield13	VERB
eurjchem-2544	638	28	:	:	PUNCT
eurjchem-2544	638	29	printfield14	printfield14	NOUN
eurjchem-2544	638	30	:	:	PUNCT
eurjchem-2544	638	31	printfield15	printfield15	NOUN
eurjchem-2544	638	32	:	:	PUNCT
eurjchem-2544	638	33	printfield16	printfield16	ADJ
eurjchem-2544	638	34	:	:	PUNCT
eurjchem-2544	638	35	printfield17	printfield17	NOUN
eurjchem-2544	638	36	:	:	PUNCT
eurjchem-2544	638	37	printfield18	printfield18	NOUN
eurjchem-2544	638	38	:	:	PUNCT
eurjchem-2544	638	39	printfield19	printfield19	NOUN
eurjchem-2544	638	40	:	:	PUNCT
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eurjchem-2544	638	42	:	:	PUNCT
eurjchem-2544	638	43	printfield20	printfield20	PROPN
eurjchem-2544	638	44	:	:	PUNCT
eurjchem-2544	638	45	printfield21	printfield21	ADJ
eurjchem-2544	638	46	:	:	PUNCT
eurjchem-2544	638	47	printfield22	printfield22	NOUN
eurjchem-2544	638	48	:	:	PUNCT
eurjchem-2544	638	49	printfield23	printfield23	NOUN
eurjchem-2544	638	50	:	:	PUNCT
eurjchem-2544	638	51	printfield24	printfield24	NOUN
eurjchem-2544	638	52	:	:	PUNCT
eurjchem-2544	638	53	printfield25	printfield25	NOUN
eurjchem-2544	638	54	:	:	PUNCT
eurjchem-2544	638	55	printfield26	printfield26	ADJ
eurjchem-2544	638	56	:	:	PUNCT
eurjchem-2544	638	57	printfield27	printfield27	NOUN
eurjchem-2544	638	58	:	:	PUNCT
eurjchem-2544	638	59	printfield28	printfield28	NOUN
eurjchem-2544	638	60	:	:	PUNCT
eurjchem-2544	638	61	printfield29	printfield29	ADV
eurjchem-2544	638	62	:	:	PUNCT
eurjchem-2544	638	63	printfield210	printfield210	PROPN
eurjchem-2544	638	64	:	:	PUNCT