id sid tid token lemma pos eurjchem-34 1 1 microsoft microsoft PROPN eurjchem-34 1 2 word word PROPN eurjchem-34 1 3 european_journal_of_chemistry_1_2_2010_73_75_34 european_journal_of_chemistry_1_2_2010_73_75_34 PROPN eurjchem-34 1 4 european european ADJ eurjchem-34 1 5     SPACE eurjchem-34 1 6 journal journal NOUN eurjchem-34 1 7     SPACE eurjchem-34 1 8 of of ADP eurjchem-34 1 9     SPACE eurjchem-34 1 10 chemistry chemistry NOUN eurjchem-34 1 11     SPACE eurjchem-34 1 12 1 1 NUM eurjchem-34 1 13     SPACE eurjchem-34 1 14 ( ( PUNCT eurjchem-34 1 15 2 2 NUM eurjchem-34 1 16 ) ) PUNCT eurjchem-34 1 17     SPACE eurjchem-34 1 18 ( ( PUNCT eurjchem-34 1 19 2010 2010 NUM eurjchem-34 1 20 ) ) PUNCT eurjchem-34 1 21     SPACE eurjchem-34 1 22 73‐75 73‐75 NUM eurjchem-34 1 23         SPACE eurjchem-34 1 24 european european ADJ eurjchem-34 1 25     SPACE eurjchem-34 1 26 journal journal NOUN eurjchem-34 1 27     SPACE eurjchem-34 1 28 of of ADP eurjchem-34 1 29     SPACE eurjchem-34 1 30 chemistry chemistry NOUN eurjchem-34 1 31     SPACE eurjchem-34 1 32 issn issn VERB eurjchem-34 1 33     SPACE eurjchem-34 1 34 2153‐2249 2153‐2249 NUM eurjchem-34 1 35     SPACE eurjchem-34 1 36 ( ( PUNCT eurjchem-34 1 37 print print NOUN eurjchem-34 1 38 ) ) PUNCT eurjchem-34 1 39     SPACE eurjchem-34 1 40 / / SYM eurjchem-34 1 41     SPACE eurjchem-34 1 42 issn issn VERB eurjchem-34 1 43     SPACE eurjchem-34 1 44 2153‐2257 2153‐2257 NUM eurjchem-34 1 45     SPACE eurjchem-34 1 46 ( ( PUNCT eurjchem-34 1 47 online online ADJ eurjchem-34 1 48 ) ) PUNCT eurjchem-34 1 49     SPACE eurjchem-34 1 50   NOUN eurjchem-34 1 51     SPACE eurjchem-34 1 52 2010 2010 NUM eurjchem-34 1 53     SPACE eurjchem-34 1 54 eurjchem eurjchem NOUN eurjchem-34 1 55     SPACE eurjchem-34 1 56 doi:10.5155 doi:10.5155 PROPN eurjchem-34 1 57 / / SYM eurjchem-34 1 58 eurjchem.1.2.73‐75.34 eurjchem.1.2.73‐75.34 NOUN eurjchem-34 1 59                 SPACE eurjchem-34 1 60 european european ADJ eurjchem-34 1 61     SPACE eurjchem-34 1 62 journal journal NOUN eurjchem-34 1 63     SPACE eurjchem-34 1 64 of of ADP eurjchem-34 1 65     SPACE eurjchem-34 1 66 chemistry chemistry NOUN eurjchem-34 1 67     SPACE eurjchem-34 1 68 journal journal NOUN eurjchem-34 1 69     SPACE eurjchem-34 1 70 homepage homepage NOUN eurjchem-34 1 71 : : PUNCT eurjchem-34 1 72     SPACE eurjchem-34 1 73 www.eurjchem.com www.eurjchem.com NOUN eurjchem-34 1 74                     SPACE eurjchem-34 1 75 synthesis synthesis NOUN eurjchem-34 1 76 , , PUNCT eurjchem-34 1 77     SPACE eurjchem-34 1 78 characterization characterization NOUN eurjchem-34 1 79     SPACE eurjchem-34 1 80 and and CCONJ eurjchem-34 1 81     SPACE eurjchem-34 1 82 crystal crystal NOUN eurjchem-34 1 83     SPACE eurjchem-34 1 84 structure structure NOUN eurjchem-34 1 85     SPACE eurjchem-34 1 86 of of ADP eurjchem-34 1 87       SPACE eurjchem-34 1 88 1‐(4‐methylbenzoyl)‐3‐(4 1‐(4‐methylbenzoyl)‐3‐(4 NUM eurjchem-34 1 89     SPACE eurjchem-34 1 90 aminosulfonylphenyl)thiourea aminosulfonylphenyl)thiourea NOUN eurjchem-34 1 91     SPACE eurjchem-34 1 92 aamer aamer ADJ eurjchem-34 1 93     SPACE eurjchem-34 1 94 saeeda saeeda NOUN eurjchem-34 1 95 , , PUNCT eurjchem-34 1 96 * * NOUN eurjchem-34 1 97     SPACE eurjchem-34 1 98 amara amara NOUN eurjchem-34 1 99     SPACE eurjchem-34 1 100 mumtaza mumtaza PROPN eurjchem-34 1 101     SPACE eurjchem-34 1 102 and and CCONJ eurjchem-34 1 103     SPACE eurjchem-34 1 104 ulrich ulrich NOUN eurjchem-34 1 105     SPACE eurjchem-34 1 106 flörkeb flörkeb VERB eurjchem-34 1 107     SPACE eurjchem-34 1 108 a a DET eurjchem-34 1 109     SPACE eurjchem-34 1 110 department department NOUN eurjchem-34 1 111     SPACE eurjchem-34 1 112 of of ADP eurjchem-34 1 113     SPACE eurjchem-34 1 114 chemistry chemistry NOUN eurjchem-34 1 115 , , PUNCT eurjchem-34 1 116     SPACE eurjchem-34 1 117 quaid­i­azam quaid­i­azam VERB eurjchem-34 1 118     SPACE eurjchem-34 1 119 university university NOUN eurjchem-34 1 120 , , PUNCT eurjchem-34 1 121     SPACE eurjchem-34 1 122 islamabad islamabad PROPN eurjchem-34 1 123 , , PUNCT eurjchem-34 1 124     SPACE eurjchem-34 1 125 45320 45320 NUM eurjchem-34 1 126 , , PUNCT eurjchem-34 1 127     SPACE eurjchem-34 1 128 pakistan pakistan PROPN eurjchem-34 1 129     SPACE eurjchem-34 1 130 b b PROPN eurjchem-34 1 131     SPACE eurjchem-34 1 132 department department NOUN eurjchem-34 1 133     SPACE eurjchem-34 1 134 chemie chemie PROPN eurjchem-34 1 135 , , PUNCT eurjchem-34 1 136     SPACE eurjchem-34 1 137 fakultät fakultät ADJ eurjchem-34 1 138     SPACE eurjchem-34 1 139 fur fur NOUN eurjchem-34 1 140     SPACE eurjchem-34 1 141 naturwissenschaften naturwissenschaften NOUN eurjchem-34 1 142 , , PUNCT eurjchem-34 1 143     SPACE eurjchem-34 1 144 universitat universitat X eurjchem-34 1 145     SPACE eurjchem-34 1 146 paderborn paderborn ADJ eurjchem-34 1 147 , , PUNCT eurjchem-34 1 148     SPACE eurjchem-34 1 149 warburgerstrasse warburgerstrasse NOUN eurjchem-34 1 150     SPACE eurjchem-34 1 151 100 100 NUM eurjchem-34 1 152 , , PUNCT eurjchem-34 1 153     SPACE eurjchem-34 1 154 d­33098 d­33098 NOUN eurjchem-34 1 155 , , PUNCT eurjchem-34 1 156     SPACE eurjchem-34 1 157 paderborn paderborn ADJ eurjchem-34 1 158 , , PUNCT eurjchem-34 1 159     SPACE eurjchem-34 1 160 germany germany PROPN eurjchem-34 1 161     SPACE eurjchem-34 1 162 * * PROPN eurjchem-34 1 163 corresponding corresponding ADJ eurjchem-34 1 164     SPACE eurjchem-34 1 165 author author NOUN eurjchem-34 1 166     SPACE eurjchem-34 1 167 at at ADP eurjchem-34 1 168 : : PUNCT eurjchem-34 1 169     SPACE eurjchem-34 1 170 department department NOUN eurjchem-34 1 171     SPACE eurjchem-34 1 172 of of ADP eurjchem-34 1 173     SPACE eurjchem-34 1 174 chemistry chemistry NOUN eurjchem-34 1 175 , , PUNCT eurjchem-34 1 176     SPACE eurjchem-34 1 177 quaid­i­azam quaid­i­azam VERB eurjchem-34 1 178     SPACE eurjchem-34 1 179 university university NOUN eurjchem-34 1 180 , , PUNCT eurjchem-34 1 181     SPACE eurjchem-34 1 182 islamabad islamabad PROPN eurjchem-34 1 183 , , PUNCT eurjchem-34 1 184     SPACE eurjchem-34 1 185 45320 45320 NUM eurjchem-34 1 186 , , PUNCT eurjchem-34 1 187     SPACE eurjchem-34 1 188 pakistan pakistan PROPN eurjchem-34 1 189 . . PUNCT eurjchem-34 1 190     SPACE eurjchem-34 2 1 tel tel PROPN eurjchem-34 2 2 . . PUNCT eurjchem-34 2 3 : : PUNCT eurjchem-34 2 4     SPACE eurjchem-34 2 5 +92.51.90642128 +92.51.90642128 ADP eurjchem-34 2 6 ; ; PUNCT eurjchem-34 2 7     SPACE eurjchem-34 2 8 fax fax NOUN eurjchem-34 2 9 : : PUNCT eurjchem-34 2 10     SPACE eurjchem-34 2 11 +92.51.90642241 +92.51.90642241 PROPN eurjchem-34 2 12 . . PUNCT eurjchem-34 2 13                                     SPACE eurjchem-34 2 14 e­mail e­mail NOUN eurjchem-34 2 15     SPACE eurjchem-34 2 16 address address NOUN eurjchem-34 2 17 : : PUNCT eurjchem-34 2 18     SPACE eurjchem-34 2 19 aamersaeed@yahoo.com aamersaeed@yahoo.com X eurjchem-34 2 20     SPACE eurjchem-34 2 21 ( ( PUNCT eurjchem-34 2 22 a. a. NOUN eurjchem-34 2 23     SPACE eurjchem-34 2 24 saeed saeed PROPN eurjchem-34 2 25 ) ) PUNCT eurjchem-34 2 26 . . PUNCT eurjchem-34 2 27                                 SPACE eurjchem-34 2 28 article article NOUN eurjchem-34 2 29     SPACE eurjchem-34 2 30 information information NOUN eurjchem-34 2 31         SPACE eurjchem-34 2 32 abstract abstract ADJ eurjchem-34 2 33 received receive VERB eurjchem-34 2 34 : : PUNCT eurjchem-34 2 35     SPACE eurjchem-34 2 36 4 4 NUM eurjchem-34 2 37     SPACE eurjchem-34 2 38 april april PROPN eurjchem-34 2 39     SPACE eurjchem-34 2 40 2010 2010 NUM eurjchem-34 2 41     SPACE eurjchem-34 2 42 received receive VERB eurjchem-34 2 43     SPACE eurjchem-34 2 44 in in ADP eurjchem-34 2 45     SPACE eurjchem-34 2 46 revised revise VERB eurjchem-34 2 47     SPACE eurjchem-34 2 48 form form NOUN eurjchem-34 2 49 : : PUNCT eurjchem-34 2 50     SPACE eurjchem-34 2 51 9 9 NUM eurjchem-34 2 52     SPACE eurjchem-34 2 53 april april PROPN eurjchem-34 2 54     SPACE eurjchem-34 2 55 2010 2010 NUM eurjchem-34 2 56     SPACE eurjchem-34 2 57 accepted accept VERB eurjchem-34 2 58 : : PUNCT eurjchem-34 2 59     SPACE eurjchem-34 2 60 9 9 NUM eurjchem-34 2 61     SPACE eurjchem-34 2 62 april april PROPN eurjchem-34 2 63     SPACE eurjchem-34 2 64 2010 2010 NUM eurjchem-34 2 65     SPACE eurjchem-34 2 66 online online NOUN eurjchem-34 2 67 : : PUNCT eurjchem-34 2 68     SPACE eurjchem-34 2 69 30 30 NUM eurjchem-34 2 70     SPACE eurjchem-34 2 71 june june PROPN eurjchem-34 2 72     SPACE eurjchem-34 2 73 2010 2010 NUM eurjchem-34 2 74     SPACE eurjchem-34 2 75 keywords keyword VERB eurjchem-34 2 76         SPACE eurjchem-34 2 77 an an DET eurjchem-34 2 78     SPACE eurjchem-34 2 79 efficient efficient ADJ eurjchem-34 2 80     SPACE eurjchem-34 2 81 synthesis synthesis NOUN eurjchem-34 2 82     SPACE eurjchem-34 2 83 of of ADP eurjchem-34 2 84     SPACE eurjchem-34 2 85 the the DET eurjchem-34 2 86     SPACE eurjchem-34 2 87 title title NOUN eurjchem-34 2 88     SPACE eurjchem-34 2 89 compound compound NOUN eurjchem-34 2 90 , , PUNCT eurjchem-34 2 91     SPACE eurjchem-34 2 92 1‐(4‐methylbenzoyl)‐3‐(4‐aminosulfonyl 1‐(4‐methylbenzoyl)‐3‐(4‐aminosulfonyl NUM eurjchem-34 2 93 phenyl)thiourea phenyl)thiourea NOUN eurjchem-34 2 94 , , PUNCT eurjchem-34 2 95         SPACE eurjchem-34 2 96 was be AUX eurjchem-34 2 97     SPACE eurjchem-34 2 98 carried carry VERB eurjchem-34 2 99     SPACE eurjchem-34 2 100 out out ADP eurjchem-34 2 101     SPACE eurjchem-34 2 102 by by ADP eurjchem-34 2 103     SPACE eurjchem-34 2 104 reaction reaction NOUN eurjchem-34 2 105     SPACE eurjchem-34 2 106 of of ADP eurjchem-34 2 107     SPACE eurjchem-34 2 108 4‐methylbenzoyl 4‐methylbenzoyl NOUN eurjchem-34 2 109     SPACE eurjchem-34 2 110 chloride chloride NOUN eurjchem-34 2 111     SPACE eurjchem-34 2 112 with with ADP eurjchem-34 2 113     SPACE eurjchem-34 2 114 potassium potassium NOUN eurjchem-34 2 115 thiocyanate thiocyanate NOUN eurjchem-34 2 116     SPACE eurjchem-34 2 117 in in ADP eurjchem-34 2 118     SPACE eurjchem-34 2 119 acetone acetone NOUN eurjchem-34 2 120     SPACE eurjchem-34 2 121 to to PART eurjchem-34 2 122     SPACE eurjchem-34 2 123 afford afford VERB eurjchem-34 2 124     SPACE eurjchem-34 2 125 4‐methylbenzoyl 4‐methylbenzoyl NUM eurjchem-34 2 126     SPACE eurjchem-34 2 127 isothiocyanate isothiocyanate NOUN eurjchem-34 2 128     SPACE eurjchem-34 2 129 in in ADP eurjchem-34 2 130     SPACE eurjchem-34 2 131 situ situ NOUN eurjchem-34 2 132     SPACE eurjchem-34 2 133 followed follow VERB eurjchem-34 2 134     SPACE eurjchem-34 2 135 by by ADP eurjchem-34 2 136     SPACE eurjchem-34 2 137 treatment treatment NOUN eurjchem-34 2 138 with with ADP eurjchem-34 2 139     SPACE eurjchem-34 2 140 sulfanilamide sulfanilamide NOUN eurjchem-34 2 141 . . PUNCT eurjchem-34 2 142     SPACE eurjchem-34 3 1 the the DET eurjchem-34 3 2     SPACE eurjchem-34 3 3 structure structure NOUN eurjchem-34 3 4     SPACE eurjchem-34 3 5 was be AUX eurjchem-34 3 6     SPACE eurjchem-34 3 7 confirmed confirm VERB eurjchem-34 3 8     SPACE eurjchem-34 3 9 by by ADP eurjchem-34 3 10     SPACE eurjchem-34 3 11 spectroscopic spectroscopic NOUN eurjchem-34 3 12     SPACE eurjchem-34 3 13 data datum NOUN eurjchem-34 3 14     SPACE eurjchem-34 3 15 and and CCONJ eurjchem-34 3 16     SPACE eurjchem-34 3 17 elemental elemental ADJ eurjchem-34 3 18 analyses analysis NOUN eurjchem-34 3 19 . . PUNCT eurjchem-34 3 20     SPACE eurjchem-34 4 1 the the DET eurjchem-34 4 2     SPACE eurjchem-34 4 3 molecular molecular ADJ eurjchem-34 4 4     SPACE eurjchem-34 4 5 structure structure NOUN eurjchem-34 4 6     SPACE eurjchem-34 4 7 was be AUX eurjchem-34 4 8     SPACE eurjchem-34 4 9 determined determine VERB eurjchem-34 4 10     SPACE eurjchem-34 4 11 from from ADP eurjchem-34 4 12     SPACE eurjchem-34 4 13 single single ADJ eurjchem-34 4 14     SPACE eurjchem-34 4 15 crystal crystal NOUN eurjchem-34 4 16     SPACE eurjchem-34 4 17 x‐ray x‐ray PROPN eurjchem-34 4 18     SPACE eurjchem-34 4 19 diffraction diffraction NOUN eurjchem-34 4 20     SPACE eurjchem-34 4 21 data datum NOUN eurjchem-34 4 22 . . PUNCT eurjchem-34 4 23     SPACE eurjchem-34 5 1 it it PRON eurjchem-34 5 2 crystallizes crystallize VERB eurjchem-34 5 3     SPACE eurjchem-34 5 4 in in ADP eurjchem-34 5 5     SPACE eurjchem-34 5 6 the the DET eurjchem-34 5 7     SPACE eurjchem-34 5 8 monoclinic monoclinic ADJ eurjchem-34 5 9     SPACE eurjchem-34 5 10 space space NOUN eurjchem-34 5 11     SPACE eurjchem-34 5 12 group group NOUN eurjchem-34 5 13     SPACE eurjchem-34 5 14 p21 p21 PROPN eurjchem-34 5 15 / / SYM eurjchem-34 5 16 n n CCONJ eurjchem-34 5 17     SPACE eurjchem-34 5 18 with with ADP eurjchem-34 5 19     SPACE eurjchem-34 5 20 unit unit NOUN eurjchem-34 5 21     SPACE eurjchem-34 5 22 cell cell NOUN eurjchem-34 5 23     SPACE eurjchem-34 5 24 dimensions dimension NOUN eurjchem-34 5 25     SPACE eurjchem-34 5 26 of of ADP eurjchem-34 5 27     SPACE eurjchem-34 5 28 a a DET eurjchem-34 5 29     SPACE eurjchem-34 5 30 = = NOUN eurjchem-34 5 31     SPACE eurjchem-34 5 32 4.8116(9 4.8116(9 NOUN eurjchem-34 5 33 ) ) PUNCT eurjchem-34 5 34     SPACE eurjchem-34 6 1 å å PROPN eurjchem-34 6 2 , , PUNCT eurjchem-34 6 3 b b NOUN eurjchem-34 6 4     SPACE eurjchem-34 6 5 = = NOUN eurjchem-34 6 6     SPACE eurjchem-34 6 7 17.150(3 17.150(3 NOUN eurjchem-34 6 8 ) ) PUNCT eurjchem-34 6 9     SPACE eurjchem-34 6 10 å å PROPN eurjchem-34 6 11 , , PUNCT eurjchem-34 6 12     SPACE eurjchem-34 6 13 c c NOUN eurjchem-34 6 14     SPACE eurjchem-34 6 15 = = NOUN eurjchem-34 6 16     SPACE eurjchem-34 6 17 18.677(3 18.677(3 NOUN eurjchem-34 6 18 ) ) PUNCT eurjchem-34 6 19     SPACE eurjchem-34 7 1 å å PROPN eurjchem-34 7 2 , , PUNCT eurjchem-34 7 3     SPACE eurjchem-34 7 4   NOUN eurjchem-34 7 5     SPACE eurjchem-34 7 6 = = NOUN eurjchem-34 7 7     SPACE eurjchem-34 7 8 96.487(4 96.487(4 NUM eurjchem-34 7 9 ) ) PUNCT eurjchem-34 7 10     SPACE eurjchem-34 7 11 ° ° PROPN eurjchem-34 7 12 , , PUNCT eurjchem-34 7 13     SPACE eurjchem-34 7 14 and and CCONJ eurjchem-34 7 15     SPACE eurjchem-34 7 16 v v NOUN eurjchem-34 7 17     SPACE eurjchem-34 7 18 = = NOUN eurjchem-34 7 19     SPACE eurjchem-34 7 20 1531.4(5 1531.4(5 NOUN eurjchem-34 7 21 ) ) PUNCT eurjchem-34 7 22     SPACE eurjchem-34 7 23 å3 å3 PROPN eurjchem-34 7 24 . . PUNCT eurjchem-34 7 25     SPACE eurjchem-34 8 1 thiourea thiourea NOUN eurjchem-34 8 2       SPACE eurjchem-34 8 3 sulfonyl sulfonyl NOUN eurjchem-34 8 4     SPACE eurjchem-34 8 5 thiourea thiourea NOUN eurjchem-34 8 6     SPACE eurjchem-34 8 7 single single ADJ eurjchem-34 8 8     SPACE eurjchem-34 8 9 crystal crystal NOUN eurjchem-34 8 10     SPACE eurjchem-34 8 11 x‐ray x‐ray PROPN eurjchem-34 8 12     SPACE eurjchem-34 8 13 diffraction diffraction NOUN eurjchem-34 8 14         SPACE eurjchem-34 8 15 1 1 NUM eurjchem-34 8 16 . . PUNCT eurjchem-34 8 17     SPACE eurjchem-34 8 18 introduction introduction NOUN eurjchem-34 8 19         SPACE eurjchem-34 8 20 1,3‐disubstitued 1,3‐disubstitue VERB eurjchem-34 8 21     SPACE eurjchem-34 8 22 thioureas thiourea NOUN eurjchem-34 8 23     SPACE eurjchem-34 8 24 are be AUX eurjchem-34 8 25     SPACE eurjchem-34 8 26 extremely extremely ADV eurjchem-34 8 27     SPACE eurjchem-34 8 28 versatile versatile ADJ eurjchem-34 8 29     SPACE eurjchem-34 8 30 building building NOUN eurjchem-34 8 31     SPACE eurjchem-34 8 32 blocks block NOUN eurjchem-34 8 33     SPACE eurjchem-34 8 34 for for ADP eurjchem-34 8 35     SPACE eurjchem-34 8 36 the the DET eurjchem-34 8 37     SPACE eurjchem-34 8 38 synthesis synthesis NOUN eurjchem-34 8 39     SPACE eurjchem-34 8 40 of of ADP eurjchem-34 8 41     SPACE eurjchem-34 8 42 a a DET eurjchem-34 8 43     SPACE eurjchem-34 8 44 variety variety NOUN eurjchem-34 8 45     SPACE eurjchem-34 8 46 of of ADP eurjchem-34 8 47     SPACE eurjchem-34 8 48 heterocyclic heterocyclic NOUN eurjchem-34 8 49     SPACE eurjchem-34 8 50 compounds compound NOUN eurjchem-34 8 51     SPACE eurjchem-34 8 52 and and CCONJ eurjchem-34 8 53     SPACE eurjchem-34 8 54 exhibit exhibit VERB eurjchem-34 8 55     SPACE eurjchem-34 8 56 a a DET eurjchem-34 8 57     SPACE eurjchem-34 8 58 wide wide ADJ eurjchem-34 8 59     SPACE eurjchem-34 8 60 spectrum spectrum NOUN eurjchem-34 8 61     SPACE eurjchem-34 8 62 of of ADP eurjchem-34 8 63     SPACE eurjchem-34 8 64 bioactivities bioactivitie NOUN eurjchem-34 8 65 . . PUNCT eurjchem-34 8 66     SPACE eurjchem-34 9 1 n n CCONJ eurjchem-34 9 2 , , PUNCT eurjchem-34 9 3 n‐dialkyl‐n‐ n‐dialkyl‐n‐ ADJ eurjchem-34 9 4 aroyl aroyl NOUN eurjchem-34 9 5     SPACE eurjchem-34 9 6 thioureas thiourea NOUN eurjchem-34 9 7     SPACE eurjchem-34 9 8 are be AUX eurjchem-34 9 9     SPACE eurjchem-34 9 10 efficient efficient ADJ eurjchem-34 9 11     SPACE eurjchem-34 9 12 ligands ligand NOUN eurjchem-34 9 13     SPACE eurjchem-34 9 14 for for ADP eurjchem-34 9 15     SPACE eurjchem-34 9 16 the the DET eurjchem-34 9 17     SPACE eurjchem-34 9 18 separation separation NOUN eurjchem-34 9 19     SPACE eurjchem-34 9 20 of of ADP eurjchem-34 9 21     SPACE eurjchem-34 9 22 platinum platinum NOUN eurjchem-34 9 23     SPACE eurjchem-34 9 24 group group NOUN eurjchem-34 9 25     SPACE eurjchem-34 9 26 metals metal NOUN eurjchem-34 9 27     SPACE eurjchem-34 9 28 [ [ X eurjchem-34 9 29 1 1 NUM eurjchem-34 9 30 ] ] PUNCT eurjchem-34 9 31 . . PUNCT eurjchem-34 9 32     SPACE eurjchem-34 10 1 1,3‐dialkyl 1,3‐dialkyl NUM eurjchem-34 10 2     SPACE eurjchem-34 10 3 or or CCONJ eurjchem-34 10 4     SPACE eurjchem-34 10 5 diaryl diaryl NOUN eurjchem-34 10 6     SPACE eurjchem-34 10 7 thioureas thiourea NOUN eurjchem-34 10 8     SPACE eurjchem-34 10 9 exhibit exhibit NOUN eurjchem-34 10 10     SPACE eurjchem-34 10 11 significant significant ADJ eurjchem-34 10 12     SPACE eurjchem-34 10 13 antifungal antifungal ADJ eurjchem-34 10 14     SPACE eurjchem-34 10 15 activity activity NOUN eurjchem-34 10 16     SPACE eurjchem-34 10 17 against against ADP eurjchem-34 10 18     SPACE eurjchem-34 10 19 plant plant NOUN eurjchem-34 10 20     SPACE eurjchem-34 10 21 pathogens pathogen NOUN eurjchem-34 10 22     SPACE eurjchem-34 10 23 pyricularia pyricularia NOUN eurjchem-34 10 24     SPACE eurjchem-34 10 25 oryzae oryzae PROPN eurjchem-34 10 26     SPACE eurjchem-34 10 27 and and CCONJ eurjchem-34 10 28     SPACE eurjchem-34 10 29 drechslera drechslera NOUN eurjchem-34 10 30     SPACE eurjchem-34 10 31 oryzae oryzae PROPN eurjchem-34 10 32     SPACE eurjchem-34 11 1 [ [ X eurjchem-34 11 2 2 2 NUM eurjchem-34 11 3 ] ] PUNCT eurjchem-34 11 4 . . PUNCT eurjchem-34 11 5     SPACE eurjchem-34 12 1 1‐benzoyl‐3‐(4,6‐ 1‐benzoyl‐3‐(4,6‐ PROPN eurjchem-34 12 2 disubstituted‐pyrimidin‐2‐yl)thioureas disubstituted‐pyrimidin‐2‐yl)thioureas PROPN eurjchem-34 12 3     SPACE eurjchem-34 12 4 display display NOUN eurjchem-34 12 5     SPACE eurjchem-34 12 6 excellent excellent ADJ eurjchem-34 12 7     SPACE eurjchem-34 12 8 herbicidal herbicidal NOUN eurjchem-34 12 9     SPACE eurjchem-34 12 10 activity activity NOUN eurjchem-34 12 11     SPACE eurjchem-34 12 12 [ [ X eurjchem-34 12 13 3 3 NUM eurjchem-34 12 14 ] ] PUNCT eurjchem-34 12 15 . . PUNCT eurjchem-34 12 16     SPACE eurjchem-34 13 1 acyl acyl NOUN eurjchem-34 13 2     SPACE eurjchem-34 13 3 thioureas thiourea NOUN eurjchem-34 13 4     SPACE eurjchem-34 13 5 are be AUX eurjchem-34 13 6     SPACE eurjchem-34 13 7 well well ADV eurjchem-34 13 8     SPACE eurjchem-34 13 9 known know VERB eurjchem-34 13 10     SPACE eurjchem-34 13 11 for for ADP eurjchem-34 13 12     SPACE eurjchem-34 13 13 their their PRON eurjchem-34 13 14     SPACE eurjchem-34 13 15 superior superior ADJ eurjchem-34 13 16     SPACE eurjchem-34 13 17 pesticidal pesticidal NOUN eurjchem-34 13 18 , , PUNCT eurjchem-34 13 19     SPACE eurjchem-34 13 20 fungicidal fungicidal NOUN eurjchem-34 13 21 , , PUNCT eurjchem-34 13 22     SPACE eurjchem-34 13 23 antiviral antiviral NOUN eurjchem-34 13 24     SPACE eurjchem-34 13 25 and and CCONJ eurjchem-34 13 26     SPACE eurjchem-34 13 27 plant plant NOUN eurjchem-34 13 28     SPACE eurjchem-34 13 29 growth growth NOUN eurjchem-34 13 30     SPACE eurjchem-34 13 31 regulating regulate VERB eurjchem-34 13 32     SPACE eurjchem-34 13 33 activities activity NOUN eurjchem-34 13 34     SPACE eurjchem-34 13 35 [ [ X eurjchem-34 13 36 4 4 NUM eurjchem-34 13 37 ] ] PUNCT eurjchem-34 13 38 . . PUNCT eurjchem-34 13 39     SPACE eurjchem-34 14 1 1‐aroyl‐3‐arylthioureas 1‐aroyl‐3‐arylthioureas NUM eurjchem-34 14 2     SPACE eurjchem-34 14 3 have have AUX eurjchem-34 14 4     SPACE eurjchem-34 14 5 recently recently ADV eurjchem-34 14 6     SPACE eurjchem-34 14 7 been be AUX eurjchem-34 14 8     SPACE eurjchem-34 14 9 used use VERB eurjchem-34 14 10     SPACE eurjchem-34 14 11 in in ADP eurjchem-34 14 12     SPACE eurjchem-34 14 13 the the DET eurjchem-34 14 14     SPACE eurjchem-34 14 15 synthesis synthesis NOUN eurjchem-34 14 16     SPACE eurjchem-34 14 17 of of ADP eurjchem-34 14 18     SPACE eurjchem-34 14 19 imidazole‐2‐thiones imidazole‐2‐thione NOUN eurjchem-34 14 20     SPACE eurjchem-34 14 21 and and CCONJ eurjchem-34 14 22     SPACE eurjchem-34 14 23 imino imino NOUN eurjchem-34 14 24     SPACE eurjchem-34 14 25 thiazolines thiazoline NOUN eurjchem-34 14 26     SPACE eurjchem-34 14 27 [ [ X eurjchem-34 14 28 5,6 5,6 NUM eurjchem-34 14 29 ] ] X eurjchem-34 14 30 . . PUNCT eurjchem-34 14 31     SPACE eurjchem-34 14 32 sulfanilamide sulfanilamide NOUN eurjchem-34 14 33     SPACE eurjchem-34 14 34 and and CCONJ eurjchem-34 14 35     SPACE eurjchem-34 14 36 its its PRON eurjchem-34 14 37     SPACE eurjchem-34 14 38 derivatives derivative NOUN eurjchem-34 14 39     SPACE eurjchem-34 14 40 are be AUX eurjchem-34 14 41     SPACE eurjchem-34 14 42 still still ADV eurjchem-34 14 43     SPACE eurjchem-34 14 44 widely widely ADV eurjchem-34 14 45     SPACE eurjchem-34 14 46 used use VERB eurjchem-34 14 47     SPACE eurjchem-34 14 48 in in ADP eurjchem-34 14 49     SPACE eurjchem-34 14 50 chemotherapy chemotherapy NOUN eurjchem-34 14 51     SPACE eurjchem-34 14 52 effectively effectively ADV eurjchem-34 14 53     SPACE eurjchem-34 14 54 against against ADP eurjchem-34 14 55     SPACE eurjchem-34 14 56 a a DET eurjchem-34 14 57     SPACE eurjchem-34 14 58 broad broad ADJ eurjchem-34 14 59     SPACE eurjchem-34 14 60 range range NOUN eurjchem-34 14 61     SPACE eurjchem-34 14 62 of of ADP eurjchem-34 14 63     SPACE eurjchem-34 14 64 microorganisms microorganism NOUN eurjchem-34 14 65     SPACE eurjchem-34 15 1 [ [ X eurjchem-34 15 2 7‐8 7‐8 NUM eurjchem-34 15 3 ] ] X eurjchem-34 15 4 . . PUNCT eurjchem-34 15 5     SPACE eurjchem-34 15 6 these these PRON eurjchem-34 15 7     SPACE eurjchem-34 15 8 are be AUX eurjchem-34 15 9     SPACE eurjchem-34 15 10 true true ADJ eurjchem-34 15 11     SPACE eurjchem-34 15 12 anti‐metabolites anti‐metabolite NOUN eurjchem-34 15 13 ; ; PUNCT eurjchem-34 15 14     SPACE eurjchem-34 15 15 they they PRON eurjchem-34 15 16     SPACE eurjchem-34 15 17 block block VERB eurjchem-34 15 18     SPACE eurjchem-34 15 19 a a DET eurjchem-34 15 20     SPACE eurjchem-34 15 21 specific specific ADJ eurjchem-34 15 22     SPACE eurjchem-34 15 23 step step NOUN eurjchem-34 15 24     SPACE eurjchem-34 15 25 in in ADP eurjchem-34 15 26     SPACE eurjchem-34 15 27 the the DET eurjchem-34 15 28     SPACE eurjchem-34 15 29 biosynthetic biosynthetic ADJ eurjchem-34 15 30     SPACE eurjchem-34 15 31 pathway pathway NOUN eurjchem-34 15 32     SPACE eurjchem-34 15 33 of of ADP eurjchem-34 15 34     SPACE eurjchem-34 15 35 folic folic ADJ eurjchem-34 15 36     SPACE eurjchem-34 15 37 acid acid NOUN eurjchem-34 15 38     SPACE eurjchem-34 16 1 [ [ X eurjchem-34 16 2 9 9 NUM eurjchem-34 16 3 ] ] PUNCT eurjchem-34 16 4 . . PUNCT eurjchem-34 16 5     SPACE eurjchem-34 17 1 more more ADJ eurjchem-34 17 2     SPACE eurjchem-34 17 3 than than ADP eurjchem-34 17 4     SPACE eurjchem-34 17 5 12000 12000 NUM eurjchem-34 17 6     SPACE eurjchem-34 17 7 sulfonyl sulfonyl NOUN eurjchem-34 17 8     SPACE eurjchem-34 17 9 thiourea thiourea NOUN eurjchem-34 17 10     SPACE eurjchem-34 17 11 derivatives derivative NOUN eurjchem-34 17 12     SPACE eurjchem-34 17 13 are be AUX eurjchem-34 17 14     SPACE eurjchem-34 17 15 known know VERB eurjchem-34 17 16     SPACE eurjchem-34 17 17 and and CCONJ eurjchem-34 17 18     SPACE eurjchem-34 17 19 some some PRON eurjchem-34 17 20     SPACE eurjchem-34 17 21 of of ADP eurjchem-34 17 22     SPACE eurjchem-34 17 23 them they PRON eurjchem-34 17 24     SPACE eurjchem-34 17 25 are be AUX eurjchem-34 17 26     SPACE eurjchem-34 17 27 very very ADV eurjchem-34 17 28     SPACE eurjchem-34 17 29 potent potent ADJ eurjchem-34 17 30     SPACE eurjchem-34 17 31 hypoglycemic hypoglycemic ADJ eurjchem-34 17 32     SPACE eurjchem-34 17 33 agents agent NOUN eurjchem-34 17 34     SPACE eurjchem-34 17 35 due due ADJ eurjchem-34 17 36     SPACE eurjchem-34 17 37 to to ADP eurjchem-34 17 38     SPACE eurjchem-34 17 39 their their PRON eurjchem-34 17 40     SPACE eurjchem-34 17 41 ability ability NOUN eurjchem-34 17 42     SPACE eurjchem-34 17 43 to to PART eurjchem-34 17 44     SPACE eurjchem-34 17 45 stimulate stimulate VERB eurjchem-34 17 46     SPACE eurjchem-34 17 47 the the DET eurjchem-34 17 48     SPACE eurjchem-34 17 49 release release NOUN eurjchem-34 17 50     SPACE eurjchem-34 17 51 of of ADP eurjchem-34 17 52     SPACE eurjchem-34 17 53 insulin insulin NOUN eurjchem-34 17 54     SPACE eurjchem-34 17 55 from from ADP eurjchem-34 17 56     SPACE eurjchem-34 17 57 the the DET eurjchem-34 17 58     SPACE eurjchem-34 17 59 pancreatic pancreatic ADJ eurjchem-34 17 60     SPACE eurjchem-34 17 61 islets islet NOUN eurjchem-34 17 62 . . PUNCT eurjchem-34 17 63     SPACE eurjchem-34 18 1 examples example NOUN eurjchem-34 18 2     SPACE eurjchem-34 18 3 of of ADP eurjchem-34 18 4     SPACE eurjchem-34 18 5 the the DET eurjchem-34 18 6     SPACE eurjchem-34 18 7 first first ADJ eurjchem-34 18 8     SPACE eurjchem-34 18 9 generation generation NOUN eurjchem-34 18 10     SPACE eurjchem-34 18 11 sulfonylureas sulfonylurea NOUN eurjchem-34 18 12     SPACE eurjchem-34 18 13 include include VERB eurjchem-34 18 14     SPACE eurjchem-34 18 15 carbutamide carbutamide NOUN eurjchem-34 18 16 , , PUNCT eurjchem-34 18 17     SPACE eurjchem-34 18 18 the the DET eurjchem-34 18 19     SPACE eurjchem-34 18 20 first first ADJ eurjchem-34 18 21     SPACE eurjchem-34 18 22 sulfonylurea sulfonylurea NOUN eurjchem-34 18 23     SPACE eurjchem-34 18 24 used use VERB eurjchem-34 18 25     SPACE eurjchem-34 18 26 as as ADP eurjchem-34 18 27     SPACE eurjchem-34 18 28 an an DET eurjchem-34 18 29     SPACE eurjchem-34 18 30 effective effective ADJ eurjchem-34 18 31     SPACE eurjchem-34 18 32 oral oral ADJ eurjchem-34 18 33     SPACE eurjchem-34 18 34 hypoglycemic hypoglycemic ADJ eurjchem-34 18 35     SPACE eurjchem-34 18 36 agent agent NOUN eurjchem-34 18 37     SPACE eurjchem-34 18 38 which which PRON eurjchem-34 18 39     SPACE eurjchem-34 18 40 is be AUX eurjchem-34 18 41     SPACE eurjchem-34 18 42 more more ADJ eurjchem-34 18 43     SPACE eurjchem-34 18 44 effective effective ADJ eurjchem-34 18 45     SPACE eurjchem-34 18 46 than than ADP eurjchem-34 18 47     SPACE eurjchem-34 18 48 iptd iptd ADV eurjchem-34 18 49 , , PUNCT eurjchem-34 18 50     SPACE eurjchem-34 18 51 tolbutamide tolbutamide ADJ eurjchem-34 18 52 , , PUNCT eurjchem-34 18 53     SPACE eurjchem-34 18 54 chlorpropamide chlorpropamide VERB eurjchem-34 18 55 , , PUNCT eurjchem-34 18 56     SPACE eurjchem-34 18 57 tolazamide tolazamide NOUN eurjchem-34 18 58     SPACE eurjchem-34 18 59 and and CCONJ eurjchem-34 18 60     SPACE eurjchem-34 18 61 those those PRON eurjchem-34 18 62     SPACE eurjchem-34 18 63 as as ADP eurjchem-34 18 64     SPACE eurjchem-34 18 65 the the DET eurjchem-34 18 66     SPACE eurjchem-34 18 67 second second ADJ eurjchem-34 18 68     SPACE eurjchem-34 18 69 generation generation NOUN eurjchem-34 18 70     SPACE eurjchem-34 18 71 are be AUX eurjchem-34 18 72     SPACE eurjchem-34 18 73 glyburide glyburide NOUN eurjchem-34 18 74     SPACE eurjchem-34 18 75 and and CCONJ eurjchem-34 18 76     SPACE eurjchem-34 18 77 glipizide glipizide NOUN eurjchem-34 18 78 . . PUNCT eurjchem-34 18 79     SPACE eurjchem-34 19 1 the the DET eurjchem-34 19 2     SPACE eurjchem-34 19 3 present present ADJ eurjchem-34 19 4     SPACE eurjchem-34 19 5 work work NOUN eurjchem-34 19 6     SPACE eurjchem-34 19 7 aimed aim VERB eurjchem-34 19 8     SPACE eurjchem-34 19 9 at at ADP eurjchem-34 19 10     SPACE eurjchem-34 19 11 appending append VERB eurjchem-34 19 12     SPACE eurjchem-34 19 13 the the DET eurjchem-34 19 14     SPACE eurjchem-34 19 15 sulfanilamide sulfanilamide NOUN eurjchem-34 19 16     SPACE eurjchem-34 19 17 moiety moiety NOUN eurjchem-34 19 18     SPACE eurjchem-34 19 19 to to ADP eurjchem-34 19 20     SPACE eurjchem-34 19 21 thiourea thiourea NOUN eurjchem-34 19 22     SPACE eurjchem-34 19 23 nucleus nucleus NOUN eurjchem-34 19 24     SPACE eurjchem-34 19 25 in in ADP eurjchem-34 19 26     SPACE eurjchem-34 19 27 order order NOUN eurjchem-34 19 28     SPACE eurjchem-34 19 29 to to PART eurjchem-34 19 30     SPACE eurjchem-34 19 31 combine combine VERB eurjchem-34 19 32     SPACE eurjchem-34 19 33 their their PRON eurjchem-34 19 34     SPACE eurjchem-34 19 35 beneficial beneficial ADJ eurjchem-34 19 36     SPACE eurjchem-34 19 37 effects effect NOUN eurjchem-34 19 38     SPACE eurjchem-34 19 39 in in ADP eurjchem-34 19 40     SPACE eurjchem-34 19 41 a a DET eurjchem-34 19 42     SPACE eurjchem-34 19 43 single single ADJ eurjchem-34 19 44     SPACE eurjchem-34 19 45 structure structure NOUN eurjchem-34 19 46     SPACE eurjchem-34 19 47 with with ADP eurjchem-34 19 48     SPACE eurjchem-34 19 49 expected expect VERB eurjchem-34 19 50     SPACE eurjchem-34 19 51 bioactivities bioactivitie NOUN eurjchem-34 19 52     SPACE eurjchem-34 19 53 including include VERB eurjchem-34 19 54     SPACE eurjchem-34 19 55 anticancer anticancer NOUN eurjchem-34 19 56     SPACE eurjchem-34 19 57 activity activity NOUN eurjchem-34 19 58 . . PUNCT eurjchem-34 19 59       SPACE eurjchem-34 20 1 the the DET eurjchem-34 20 2     SPACE eurjchem-34 20 3 title title NOUN eurjchem-34 20 4     SPACE eurjchem-34 20 5 compound compound NOUN eurjchem-34 20 6 , , PUNCT eurjchem-34 20 7     SPACE eurjchem-34 20 8 1‐(4‐methylbenzoyl)‐3‐(4‐amino 1‐(4‐methylbenzoyl)‐3‐(4‐amino NUM eurjchem-34 20 9     SPACE eurjchem-34 20 10 sulfonylphenyl)thiourea sulfonylphenyl)thiourea PROPN eurjchem-34 20 11 , , PUNCT eurjchem-34 20 12     SPACE eurjchem-34 20 13 belong belong VERB eurjchem-34 20 14     SPACE eurjchem-34 20 15 to to ADP eurjchem-34 20 16     SPACE eurjchem-34 20 17 a a DET eurjchem-34 20 18     SPACE eurjchem-34 20 19 unique unique ADJ eurjchem-34 20 20     SPACE eurjchem-34 20 21 class class NOUN eurjchem-34 20 22     SPACE eurjchem-34 20 23 of of ADP eurjchem-34 20 24     SPACE eurjchem-34 20 25 thioureas thiourea NOUN eurjchem-34 20 26     SPACE eurjchem-34 20 27 in in ADP eurjchem-34 20 28     SPACE eurjchem-34 20 29 which which PRON eurjchem-34 20 30     SPACE eurjchem-34 20 31 the the DET eurjchem-34 20 32     SPACE eurjchem-34 20 33 free free ADJ eurjchem-34 20 34     SPACE eurjchem-34 20 35 aniline aniline NOUN eurjchem-34 20 36     SPACE eurjchem-34 20 37 nitrogen nitrogen NOUN eurjchem-34 20 38     SPACE eurjchem-34 20 39 is be AUX eurjchem-34 20 40     SPACE eurjchem-34 20 41 incorporated incorporate VERB eurjchem-34 20 42     SPACE eurjchem-34 20 43 into into ADP eurjchem-34 20 44     SPACE eurjchem-34 20 45 the the DET eurjchem-34 20 46     SPACE eurjchem-34 20 47 thiourea thiourea NOUN eurjchem-34 20 48     SPACE eurjchem-34 20 49 structure structure NOUN eurjchem-34 20 50     SPACE eurjchem-34 20 51 compared compare VERB eurjchem-34 20 52     SPACE eurjchem-34 20 53 to to ADP eurjchem-34 20 54     SPACE eurjchem-34 20 55 all all DET eurjchem-34 20 56     SPACE eurjchem-34 20 57 other other ADJ eurjchem-34 20 58     SPACE eurjchem-34 20 59 known know VERB eurjchem-34 20 60     SPACE eurjchem-34 20 61 urea urea NOUN eurjchem-34 20 62     SPACE eurjchem-34 20 63 derivatives derivative NOUN eurjchem-34 20 64     SPACE eurjchem-34 20 65 which which PRON eurjchem-34 20 66     SPACE eurjchem-34 20 67 involve involve VERB eurjchem-34 20 68     SPACE eurjchem-34 20 69 the the DET eurjchem-34 20 70     SPACE eurjchem-34 20 71 sulfonamide sulfonamide NOUN eurjchem-34 20 72     SPACE eurjchem-34 20 73 amino amino NOUN eurjchem-34 20 74     SPACE eurjchem-34 20 75 group group NOUN eurjchem-34 20 76     SPACE eurjchem-34 20 77 as as ADP eurjchem-34 20 78     SPACE eurjchem-34 20 79 part part NOUN eurjchem-34 20 80     SPACE eurjchem-34 20 81 of of ADP eurjchem-34 20 82     SPACE eurjchem-34 20 83 the the DET eurjchem-34 20 84     SPACE eurjchem-34 20 85 thiourea thiourea NOUN eurjchem-34 20 86     SPACE eurjchem-34 20 87 moiety moiety NOUN eurjchem-34 20 88 . . PUNCT eurjchem-34 20 89         SPACE eurjchem-34 21 1 2 2 NUM eurjchem-34 21 2 . . PUNCT eurjchem-34 21 3     SPACE eurjchem-34 21 4 experimental experimental ADJ eurjchem-34 21 5         SPACE eurjchem-34 21 6 2.1 2.1 NUM eurjchem-34 21 7 . . PUNCT eurjchem-34 21 8     SPACE eurjchem-34 21 9 instrumentation instrumentation NOUN eurjchem-34 21 10         SPACE eurjchem-34 21 11 melting melt VERB eurjchem-34 21 12     SPACE eurjchem-34 21 13 points point NOUN eurjchem-34 21 14     SPACE eurjchem-34 21 15 were be AUX eurjchem-34 21 16     SPACE eurjchem-34 21 17 recorded record VERB eurjchem-34 21 18     SPACE eurjchem-34 21 19 using use VERB eurjchem-34 21 20     SPACE eurjchem-34 21 21 a a DET eurjchem-34 21 22     SPACE eurjchem-34 21 23 digital digital ADJ eurjchem-34 21 24     SPACE eurjchem-34 21 25 gallenkamp gallenkamp NOUN eurjchem-34 21 26     SPACE eurjchem-34 21 27 ( ( PUNCT eurjchem-34 21 28 sanyo sanyo PROPN eurjchem-34 21 29 ) ) PUNCT eurjchem-34 21 30     SPACE eurjchem-34 21 31 model model NOUN eurjchem-34 21 32     SPACE eurjchem-34 21 33 mpd.bm mpd.bm NOUN eurjchem-34 21 34     SPACE eurjchem-34 21 35 3.5 3.5 NUM eurjchem-34 21 36     SPACE eurjchem-34 21 37 apparatus apparatus NOUN eurjchem-34 21 38     SPACE eurjchem-34 21 39 and and CCONJ eurjchem-34 21 40     SPACE eurjchem-34 21 41 are be AUX eurjchem-34 21 42     SPACE eurjchem-34 21 43 uncorrected uncorrecte VERB eurjchem-34 21 44 . . PUNCT eurjchem-34 21 45     SPACE eurjchem-34 22 1 1h 1h NUM eurjchem-34 22 2     SPACE eurjchem-34 22 3 and and CCONJ eurjchem-34 22 4     SPACE eurjchem-34 22 5 13c 13c NOUN eurjchem-34 22 6     SPACE eurjchem-34 22 7 nmr nmr NOUN eurjchem-34 22 8     SPACE eurjchem-34 22 9 spectra spectra NOUN eurjchem-34 22 10     SPACE eurjchem-34 22 11 were be AUX eurjchem-34 22 12     SPACE eurjchem-34 22 13 determined determine VERB eurjchem-34 22 14     SPACE eurjchem-34 22 15 as as ADP eurjchem-34 22 16     SPACE eurjchem-34 22 17 chloroform‐d chloroform‐d PROPN eurjchem-34 22 18     SPACE eurjchem-34 22 19 solutions solution NOUN eurjchem-34 22 20     SPACE eurjchem-34 22 21 using use VERB eurjchem-34 22 22     SPACE eurjchem-34 22 23 a a DET eurjchem-34 22 24     SPACE eurjchem-34 22 25 bruker bruker NOUN eurjchem-34 22 26     SPACE eurjchem-34 22 27 am‐300 am‐300 ADJ eurjchem-34 22 28     SPACE eurjchem-34 22 29 spectrophotometer spectrophotometer NOUN eurjchem-34 22 30 .. .. PUNCT eurjchem-34 22 31     SPACE eurjchem-34 22 32 ftir ftir PROPN eurjchem-34 22 33     SPACE eurjchem-34 22 34 spectra spectra PROPN eurjchem-34 22 35     SPACE eurjchem-34 22 36 were be AUX eurjchem-34 22 37     SPACE eurjchem-34 22 38 recorded record VERB eurjchem-34 22 39     SPACE eurjchem-34 22 40 on on ADP eurjchem-34 22 41     SPACE eurjchem-34 22 42 an an DET eurjchem-34 22 43     SPACE eurjchem-34 22 44 fts fts X eurjchem-34 22 45     SPACE eurjchem-34 22 46 3000 3000 NUM eurjchem-34 22 47     SPACE eurjchem-34 22 48 mx mx NOUN eurjchem-34 22 49     SPACE eurjchem-34 22 50 spectrophotometer spectrophotometer NOUN eurjchem-34 22 51 . . PUNCT eurjchem-34 22 52     SPACE eurjchem-34 22 53 mass mass PROPN eurjchem-34 22 54     SPACE eurjchem-34 22 55 spectra spectra NOUN eurjchem-34 22 56     SPACE eurjchem-34 22 57 was be AUX eurjchem-34 22 58     SPACE eurjchem-34 22 59 acquired acquire VERB eurjchem-34 22 60     SPACE eurjchem-34 22 61 ( ( PUNCT eurjchem-34 22 62 ei ei NOUN eurjchem-34 22 63 , , PUNCT eurjchem-34 22 64     SPACE eurjchem-34 22 65 70ev 70ev NOUN eurjchem-34 22 66 ) ) PUNCT eurjchem-34 22 67     SPACE eurjchem-34 22 68 on on ADP eurjchem-34 22 69     SPACE eurjchem-34 22 70 a a DET eurjchem-34 22 71     SPACE eurjchem-34 22 72 mat mat NOUN eurjchem-34 22 73     SPACE eurjchem-34 22 74 312 312 NUM eurjchem-34 22 75     SPACE eurjchem-34 22 76 instrument instrument NOUN eurjchem-34 22 77 , , PUNCT eurjchem-34 22 78     SPACE eurjchem-34 22 79 and and CCONJ eurjchem-34 22 80     SPACE eurjchem-34 22 81 elemental elemental NOUN eurjchem-34 22 82     SPACE eurjchem-34 22 83 analyses analysis NOUN eurjchem-34 22 84     SPACE eurjchem-34 22 85 were be AUX eurjchem-34 22 86     SPACE eurjchem-34 22 87 conducted conduct VERB eurjchem-34 22 88     SPACE eurjchem-34 22 89 using use VERB eurjchem-34 22 90     SPACE eurjchem-34 22 91 a a DET eurjchem-34 22 92     SPACE eurjchem-34 22 93 leco‐183 leco‐183 NOUN eurjchem-34 22 94     SPACE eurjchem-34 22 95 chns chns PROPN eurjchem-34 22 96     SPACE eurjchem-34 22 97 analyzer analyzer NOUN eurjchem-34 22 98 . . PUNCT eurjchem-34 22 99     SPACE eurjchem-34 22 100 crystallographic crystallographic ADJ eurjchem-34 22 101     SPACE eurjchem-34 22 102 data datum NOUN eurjchem-34 22 103     SPACE eurjchem-34 22 104 were be AUX eurjchem-34 22 105     SPACE eurjchem-34 22 106 collected collect VERB eurjchem-34 22 107     SPACE eurjchem-34 22 108 on on ADP eurjchem-34 22 109     SPACE eurjchem-34 22 110 a a DET eurjchem-34 22 111     SPACE eurjchem-34 22 112 bruker‐axs bruker‐ax NOUN eurjchem-34 22 113     SPACE eurjchem-34 22 114 smart smart ADJ eurjchem-34 22 115     SPACE eurjchem-34 22 116 apex apex NOUN eurjchem-34 22 117     SPACE eurjchem-34 22 118 ccd ccd NOUN eurjchem-34 22 119     SPACE eurjchem-34 22 120 diffractometer diffractometer NOUN eurjchem-34 22 121 . . PUNCT eurjchem-34 22 122     SPACE eurjchem-34 23 1 the the DET eurjchem-34 23 2     SPACE eurjchem-34 23 3 crystal crystal NOUN eurjchem-34 23 4     SPACE eurjchem-34 23 5 structure structure NOUN eurjchem-34 23 6     SPACE eurjchem-34 23 7 was be AUX eurjchem-34 23 8     SPACE eurjchem-34 23 9 solved solve VERB eurjchem-34 23 10     SPACE eurjchem-34 23 11 by by ADP eurjchem-34 23 12     SPACE eurjchem-34 23 13 direct direct ADJ eurjchem-34 23 14     SPACE eurjchem-34 23 15 methods method NOUN eurjchem-34 23 16 . . PUNCT eurjchem-34 23 17     SPACE eurjchem-34 24 1 h‐atoms h‐atom NOUN eurjchem-34 24 2     SPACE eurjchem-34 24 3 were be AUX eurjchem-34 24 4     SPACE eurjchem-34 24 5 located locate VERB eurjchem-34 24 6     SPACE eurjchem-34 24 7 from from ADP eurjchem-34 24 8     SPACE eurjchem-34 24 9 difference difference NOUN eurjchem-34 24 10     SPACE eurjchem-34 24 11 fourier fourier NOUN eurjchem-34 24 12     SPACE eurjchem-34 24 13 maps map NOUN eurjchem-34 24 14     SPACE eurjchem-34 24 15 and and CCONJ eurjchem-34 24 16     SPACE eurjchem-34 24 17 then then ADV eurjchem-34 24 18     SPACE eurjchem-34 24 19 refined refine VERB eurjchem-34 24 20     SPACE eurjchem-34 24 21 at at ADP eurjchem-34 24 22     SPACE eurjchem-34 24 23 idealized idealize VERB eurjchem-34 24 24     SPACE eurjchem-34 24 25 positions position NOUN eurjchem-34 24 26     SPACE eurjchem-34 24 27 with with ADP eurjchem-34 24 28     SPACE eurjchem-34 24 29 riding ride VERB eurjchem-34 24 30     SPACE eurjchem-34 24 31 model model NOUN eurjchem-34 24 32 . . PUNCT eurjchem-34 24 33     SPACE eurjchem-34 25 1 details detail NOUN eurjchem-34 25 2     SPACE eurjchem-34 25 3 on on ADP eurjchem-34 25 4     SPACE eurjchem-34 25 5 data datum NOUN eurjchem-34 25 6     SPACE eurjchem-34 25 7 collection collection NOUN eurjchem-34 25 8     SPACE eurjchem-34 25 9 and and CCONJ eurjchem-34 25 10     SPACE eurjchem-34 25 11 refinement refinement NOUN eurjchem-34 25 12     SPACE eurjchem-34 25 13 are be AUX eurjchem-34 25 14     SPACE eurjchem-34 25 15 given give VERB eurjchem-34 25 16     SPACE eurjchem-34 25 17 in in ADP eurjchem-34 25 18     SPACE eurjchem-34 25 19 table table NOUN eurjchem-34 25 20     SPACE eurjchem-34 25 21 1 1 NUM eurjchem-34 25 22 . . PUNCT eurjchem-34 25 23           SPACE eurjchem-34 25 24 2.2 2.2 NUM eurjchem-34 25 25 . . PUNCT eurjchem-34 25 26     SPACE eurjchem-34 26 1 synthesis synthesis NOUN eurjchem-34 26 2         SPACE eurjchem-34 26 3 a a DET eurjchem-34 26 4     SPACE eurjchem-34 26 5 solution solution NOUN eurjchem-34 26 6     SPACE eurjchem-34 26 7 of of ADP eurjchem-34 26 8     SPACE eurjchem-34 26 9 4‐methylbenzoyl 4‐methylbenzoyl NOUN eurjchem-34 26 10     SPACE eurjchem-34 26 11 chloride chloride NOUN eurjchem-34 26 12     SPACE eurjchem-34 26 13 ( ( PUNCT eurjchem-34 26 14 10 10 NUM eurjchem-34 26 15     SPACE eurjchem-34 26 16 mmol mmol NOUN eurjchem-34 26 17 ) ) PUNCT eurjchem-34 26 18     SPACE eurjchem-34 26 19 in in ADP eurjchem-34 26 20     SPACE eurjchem-34 26 21 acetone acetone NOUN eurjchem-34 26 22     SPACE eurjchem-34 26 23 ( ( PUNCT eurjchem-34 26 24 50 50 NUM eurjchem-34 26 25     SPACE eurjchem-34 26 26 ml ml NOUN eurjchem-34 26 27 ) ) PUNCT eurjchem-34 26 28     SPACE eurjchem-34 26 29 was be AUX eurjchem-34 26 30     SPACE eurjchem-34 26 31 added add VERB eurjchem-34 26 32     SPACE eurjchem-34 26 33 dropwise dropwise NOUN eurjchem-34 26 34     SPACE eurjchem-34 26 35 to to ADP eurjchem-34 26 36     SPACE eurjchem-34 26 37 a a DET eurjchem-34 26 38     SPACE eurjchem-34 26 39 suspension suspension NOUN eurjchem-34 26 40     SPACE eurjchem-34 26 41 of of ADP eurjchem-34 26 42     SPACE eurjchem-34 26 43 potassium potassium NOUN eurjchem-34 26 44     SPACE eurjchem-34 26 45 thiocyanate thiocyanate NOUN eurjchem-34 26 46     SPACE eurjchem-34 26 47 ( ( PUNCT eurjchem-34 26 48 10 10 NUM eurjchem-34 26 49     SPACE eurjchem-34 26 50 mmol mmol NOUN eurjchem-34 26 51 ) ) PUNCT eurjchem-34 26 52     SPACE eurjchem-34 26 53 in in ADP eurjchem-34 26 54     SPACE eurjchem-34 26 55 acetone acetone NOUN eurjchem-34 26 56     SPACE eurjchem-34 26 57 ( ( PUNCT eurjchem-34 26 58 30 30 NUM eurjchem-34 26 59     SPACE eurjchem-34 26 60 ml ml NOUN eurjchem-34 26 61 ) ) PUNCT eurjchem-34 26 62     SPACE eurjchem-34 26 63 and and CCONJ eurjchem-34 26 64     SPACE eurjchem-34 26 65 the the DET eurjchem-34 26 66     SPACE eurjchem-34 26 67 reaction reaction NOUN eurjchem-34 26 68     SPACE eurjchem-34 26 69 mixture mixture NOUN eurjchem-34 26 70     SPACE eurjchem-34 26 71 was be AUX eurjchem-34 26 72     SPACE eurjchem-34 26 73 refluxed refluxe VERB eurjchem-34 26 74     SPACE eurjchem-34 26 75 for for ADP eurjchem-34 26 76     SPACE eurjchem-34 26 77 30 30 NUM eurjchem-34 26 78     SPACE eurjchem-34 26 79 min min NOUN eurjchem-34 26 80 . . PROPN eurjchem-34 26 81     SPACE eurjchem-34 26 82 after after ADP eurjchem-34 26 83     SPACE eurjchem-34 26 84 cooling cool VERB eurjchem-34 26 85     SPACE eurjchem-34 26 86 to to PART eurjchem-34 26 87     SPACE eurjchem-34 26 88 room room NOUN eurjchem-34 26 89     SPACE eurjchem-34 26 90 temperature temperature NOUN eurjchem-34 26 91 , , PUNCT eurjchem-34 26 92     SPACE eurjchem-34 26 93 a a DET eurjchem-34 26 94     SPACE eurjchem-34 26 95 solution solution NOUN eurjchem-34 26 96     SPACE eurjchem-34 26 97 of of ADP eurjchem-34 26 98     SPACE eurjchem-34 26 99 sulfanilamide sulfanilamide NOUN eurjchem-34 26 100     SPACE eurjchem-34 26 101 ( ( PUNCT eurjchem-34 26 102 10 10 NUM eurjchem-34 26 103     SPACE eurjchem-34 26 104 mmol mmol NOUN eurjchem-34 26 105 ) ) PUNCT eurjchem-34 26 106     SPACE eurjchem-34 26 107 in in ADP eurjchem-34 26 108     SPACE eurjchem-34 26 109 acetone acetone NOUN eurjchem-34 26 110     SPACE eurjchem-34 26 111 ( ( PUNCT eurjchem-34 26 112 10 10 NUM eurjchem-34 26 113     SPACE eurjchem-34 26 114 ml ml NOUN eurjchem-34 26 115 ) ) PUNCT eurjchem-34 26 116     SPACE eurjchem-34 26 117 was be AUX eurjchem-34 26 118     SPACE eurjchem-34 26 119 added add VERB eurjchem-34 26 120     SPACE eurjchem-34 26 121 and and CCONJ eurjchem-34 26 122     SPACE eurjchem-34 26 123 the the DET eurjchem-34 26 124     SPACE eurjchem-34 26 125 resulting result VERB eurjchem-34 26 126     SPACE eurjchem-34 26 127 mixture mixture NOUN eurjchem-34 26 128     SPACE eurjchem-34 26 129 was be AUX eurjchem-34 26 130     SPACE eurjchem-34 26 131 refluxed refluxe VERB eurjchem-34 26 132     SPACE eurjchem-34 26 133 for for ADP eurjchem-34 26 134     SPACE eurjchem-34 26 135 3 3 NUM eurjchem-34 26 136     SPACE eurjchem-34 26 137 h h NOUN eurjchem-34 26 138     SPACE eurjchem-34 26 139 ( ( PUNCT eurjchem-34 26 140 scheme scheme NOUN eurjchem-34 26 141     SPACE eurjchem-34 26 142 1 1 NUM eurjchem-34 26 143 ) ) PUNCT eurjchem-34 26 144 . . PUNCT eurjchem-34 26 145     SPACE eurjchem-34 27 1 the the DET eurjchem-34 27 2     SPACE eurjchem-34 27 3 reaction reaction NOUN eurjchem-34 27 4     SPACE eurjchem-34 27 5 mixture mixture NOUN eurjchem-34 27 6     SPACE eurjchem-34 27 7 was be AUX eurjchem-34 27 8     SPACE eurjchem-34 27 9 poured pour VERB eurjchem-34 27 10     SPACE eurjchem-34 27 11 into into ADP eurjchem-34 27 12     SPACE eurjchem-34 27 13 cold cold ADJ eurjchem-34 27 14     SPACE eurjchem-34 27 15 water water NOUN eurjchem-34 27 16     SPACE eurjchem-34 27 17 and and CCONJ eurjchem-34 27 18     SPACE eurjchem-34 27 19 the the DET eurjchem-34 27 20     SPACE eurjchem-34 27 21 precipitated precipitate VERB eurjchem-34 27 22     SPACE eurjchem-34 27 23 thiourea thiourea NOUN eurjchem-34 27 24     SPACE eurjchem-34 27 25 was be AUX eurjchem-34 27 26     SPACE eurjchem-34 27 27 recrystallized recrystallize VERB eurjchem-34 27 28     SPACE eurjchem-34 27 29 using use VERB eurjchem-34 27 30     SPACE eurjchem-34 27 31 aqueous aqueous ADJ eurjchem-34 27 32     SPACE eurjchem-34 27 33 methanol methanol NOUN eurjchem-34 27 34 . . PUNCT eurjchem-34 27 35     SPACE eurjchem-34 28 1 yield yield NOUN eurjchem-34 28 2     SPACE eurjchem-34 28 3 = = NOUN eurjchem-34 28 4     SPACE eurjchem-34 28 5 ( ( PUNCT eurjchem-34 28 6 1.33 1.33 NUM eurjchem-34 28 7     SPACE eurjchem-34 28 8 g g NOUN eurjchem-34 28 9 , , PUNCT eurjchem-34 28 10     SPACE eurjchem-34 28 11 64 64 NUM eurjchem-34 28 12 % % NOUN eurjchem-34 28 13 ) ) PUNCT eurjchem-34 28 14 . . PUNCT eurjchem-34 28 15     SPACE eurjchem-34 29 1 rf rf VERB eurjchem-34 29 2     SPACE eurjchem-34 29 3 = = NOUN eurjchem-34 29 4     SPACE eurjchem-34 29 5 0.7 0.7 NUM eurjchem-34 29 6 ; ; PUNCT eurjchem-34 29 7     SPACE eurjchem-34 29 8 m.p m.p PROPN eurjchem-34 29 9 . . PROPN eurjchem-34 29 10 : : PUNCT eurjchem-34 29 11     SPACE eurjchem-34 29 12 209‐ 209‐ NUM eurjchem-34 29 13 210oc 210oc PROPN eurjchem-34 29 14 . . PUNCT eurjchem-34 29 15     SPACE eurjchem-34 30 1 ir ir PROPN eurjchem-34 30 2     SPACE eurjchem-34 30 3 ( ( PUNCT eurjchem-34 30 4 cm−1 cm−1 PROPN eurjchem-34 30 5 ): ): PUNCT eurjchem-34 30 6     SPACE eurjchem-34 30 7 1590 1590 NUM eurjchem-34 30 8     SPACE eurjchem-34 30 9 ( ( PUNCT eurjchem-34 30 10 arom arom NOUN eurjchem-34 30 11 . . PUNCT eurjchem-34 30 12     SPACE eurjchem-34 31 1 c c X eurjchem-34 31 2 = = SYM eurjchem-34 31 3 c c NOUN eurjchem-34 31 4 ) ) PUNCT eurjchem-34 31 5 , , PUNCT eurjchem-34 31 6     SPACE eurjchem-34 31 7 1663 1663 NUM eurjchem-34 31 8     SPACE eurjchem-34 31 9 ( ( PUNCT eurjchem-34 31 10 c c NOUN eurjchem-34 31 11 = = NOUN eurjchem-34 31 12 o o NOUN eurjchem-34 31 13 ) ) PUNCT eurjchem-34 31 14 , , PUNCT eurjchem-34 31 15     SPACE eurjchem-34 31 16 3317 3317 NUM eurjchem-34 31 17     SPACE eurjchem-34 31 18 ( ( PUNCT eurjchem-34 31 19 n−h n−h PROPN eurjchem-34 31 20 ) ) PUNCT eurjchem-34 31 21 , , PUNCT eurjchem-34 31 22     SPACE eurjchem-34 31 23 1263 1263 NUM eurjchem-34 31 24     SPACE eurjchem-34 31 25 ( ( PUNCT eurjchem-34 31 26 c c X eurjchem-34 31 27 = = SYM eurjchem-34 31 28 s s NOUN eurjchem-34 31 29 ) ) PUNCT eurjchem-34 31 30 , , PUNCT eurjchem-34 31 31     SPACE eurjchem-34 31 32 1158 1158 NUM eurjchem-34 31 33     SPACE eurjchem-34 31 34 ( ( PUNCT eurjchem-34 31 35 c−n c−n PROPN eurjchem-34 31 36 ) ) PUNCT eurjchem-34 31 37 , , PUNCT eurjchem-34 31 38     SPACE eurjchem-34 31 39 1334 1334 NUM eurjchem-34 31 40     SPACE eurjchem-34 31 41 ( ( PUNCT eurjchem-34 31 42 s s NOUN eurjchem-34 31 43 = = NOUN eurjchem-34 31 44 o o NOUN eurjchem-34 31 45 ) ) PUNCT eurjchem-34 31 46 . . PUNCT eurjchem-34 31 47     SPACE eurjchem-34 32 1 74 74 NUM eurjchem-34 32 2     SPACE eurjchem-34 32 3 saeed saeed PROPN eurjchem-34 32 4     SPACE eurjchem-34 32 5 et et PROPN eurjchem-34 32 6     SPACE eurjchem-34 32 7 al al PROPN eurjchem-34 32 8 . . PROPN eurjchem-34 32 9     SPACE eurjchem-34 32 10 / / SYM eurjchem-34 32 11     SPACE eurjchem-34 32 12 european european ADJ eurjchem-34 32 13     SPACE eurjchem-34 32 14 journal journal NOUN eurjchem-34 32 15     SPACE eurjchem-34 32 16 of of ADP eurjchem-34 32 17     SPACE eurjchem-34 32 18 chemistry chemistry NOUN eurjchem-34 32 19     SPACE eurjchem-34 32 20 1 1 NUM eurjchem-34 32 21     SPACE eurjchem-34 32 22 ( ( PUNCT eurjchem-34 32 23 2 2 NUM eurjchem-34 32 24 ) ) PUNCT eurjchem-34 32 25     SPACE eurjchem-34 32 26 ( ( PUNCT eurjchem-34 32 27 2010 2010 NUM eurjchem-34 32 28 ) ) PUNCT eurjchem-34 32 29     SPACE eurjchem-34 33 1 73­75 73­75 NUM eurjchem-34 33 2                 SPACE eurjchem-34 33 3 scheme scheme NOUN eurjchem-34 33 4     SPACE eurjchem-34 33 5 1 1 NUM eurjchem-34 33 6                 SPACE eurjchem-34 33 7 figure figure NOUN eurjchem-34 33 8     SPACE eurjchem-34 33 9 1 1 NUM eurjchem-34 33 10 . . PUNCT eurjchem-34 33 11     SPACE eurjchem-34 33 12 molecular molecular ADJ eurjchem-34 33 13     SPACE eurjchem-34 33 14 structure structure NOUN eurjchem-34 33 15     SPACE eurjchem-34 33 16 of of ADP eurjchem-34 33 17     SPACE eurjchem-34 33 18 the the DET eurjchem-34 33 19     SPACE eurjchem-34 33 20 title title NOUN eurjchem-34 33 21     SPACE eurjchem-34 33 22 compound compound NOUN eurjchem-34 33 23     SPACE eurjchem-34 33 24 with with ADP eurjchem-34 33 25     SPACE eurjchem-34 33 26 the the DET eurjchem-34 33 27     SPACE eurjchem-34 33 28 atom‐numbering atom‐numbering ADJ eurjchem-34 33 29     SPACE eurjchem-34 33 30 scheme scheme NOUN eurjchem-34 33 31 . . PUNCT eurjchem-34 33 32     SPACE eurjchem-34 33 33 displacement displacement NOUN eurjchem-34 33 34     SPACE eurjchem-34 33 35 ellipsoids ellipsoid NOUN eurjchem-34 33 36     SPACE eurjchem-34 33 37 plotted plot VERB eurjchem-34 33 38     SPACE eurjchem-34 33 39 at at ADP eurjchem-34 33 40     SPACE eurjchem-34 33 41 50 50 NUM eurjchem-34 33 42 % % NOUN eurjchem-34 33 43     SPACE eurjchem-34 33 44 probability probability NOUN eurjchem-34 33 45     SPACE eurjchem-34 33 46 level level NOUN eurjchem-34 33 47 . . PUNCT eurjchem-34 33 48         SPACE eurjchem-34 34 1 table table NOUN eurjchem-34 34 2     SPACE eurjchem-34 34 3 1 1 NUM eurjchem-34 34 4 . . PUNCT eurjchem-34 34 5         SPACE eurjchem-34 34 6 crystal crystal PROPN eurjchem-34 34 7     SPACE eurjchem-34 34 8 data datum NOUN eurjchem-34 34 9     SPACE eurjchem-34 34 10 and and CCONJ eurjchem-34 34 11     SPACE eurjchem-34 34 12 structure structure NOUN eurjchem-34 34 13     SPACE eurjchem-34 34 14 refinement refinement NOUN eurjchem-34 34 15     SPACE eurjchem-34 34 16 for for ADP eurjchem-34 34 17     SPACE eurjchem-34 34 18 1‐(4‐methylbenzoyl)‐3‐ 1‐(4‐methylbenzoyl)‐3‐ NUM eurjchem-34 34 19 ( ( PUNCT eurjchem-34 34 20 4‐aminosulfonylphenyl)thiourea 4‐aminosulfonylphenyl)thiourea NOUN eurjchem-34 34 21 . . PUNCT eurjchem-34 34 22     SPACE eurjchem-34 34 23 empirical empirical ADJ eurjchem-34 34 24     SPACE eurjchem-34 34 25 formula formula NOUN eurjchem-34 34 26       SPACE eurjchem-34 34 27 c15h15n3o3s2 c15h15n3o3s2 NOUN eurjchem-34 34 28     SPACE eurjchem-34 34 29 formula formula NOUN eurjchem-34 34 30     SPACE eurjchem-34 34 31 weight weight NOUN eurjchem-34 34 32       SPACE eurjchem-34 34 33 349.42 349.42 NUM eurjchem-34 34 34 temperature temperature NOUN eurjchem-34 34 35       SPACE eurjchem-34 34 36 120(2 120(2 NUM eurjchem-34 34 37 ) ) PUNCT eurjchem-34 34 38     SPACE eurjchem-34 34 39 k k NOUN eurjchem-34 34 40     SPACE eurjchem-34 34 41 wavelength wavelength NOUN eurjchem-34 34 42       SPACE eurjchem-34 34 43 0.71073 0.71073 NUM eurjchem-34 34 44     SPACE eurjchem-34 34 45 å å PROPN eurjchem-34 34 46     SPACE eurjchem-34 34 47 crystal crystal NOUN eurjchem-34 34 48     SPACE eurjchem-34 34 49 system system NOUN eurjchem-34 34 50       SPACE eurjchem-34 34 51 monoclinic monoclinic ADJ eurjchem-34 34 52     SPACE eurjchem-34 34 53 space space NOUN eurjchem-34 34 54     SPACE eurjchem-34 34 55 group group NOUN eurjchem-34 34 56 , , PUNCT eurjchem-34 34 57     SPACE eurjchem-34 34 58 z z NOUN eurjchem-34 34 59       SPACE eurjchem-34 34 60 p p PRON eurjchem-34 34 61     SPACE eurjchem-34 34 62 21 21 NUM eurjchem-34 34 63 / / SYM eurjchem-34 34 64 n n CCONJ eurjchem-34 34 65 , , PUNCT eurjchem-34 34 66     SPACE eurjchem-34 34 67 4 4 NUM eurjchem-34 34 68     SPACE eurjchem-34 34 69 unit unit NOUN eurjchem-34 34 70     SPACE eurjchem-34 34 71 cell cell NOUN eurjchem-34 34 72     SPACE eurjchem-34 34 73 dimensions dimension NOUN eurjchem-34 34 74     SPACE eurjchem-34 34 75 a a DET eurjchem-34 34 76     SPACE eurjchem-34 34 77 = = NOUN eurjchem-34 34 78     SPACE eurjchem-34 34 79 4.8116(9 4.8116(9 NOUN eurjchem-34 34 80 ) ) PUNCT eurjchem-34 34 81     SPACE eurjchem-34 35 1 å å PROPN eurjchem-34 35 2 . . PUNCT eurjchem-34 35 3     SPACE eurjchem-34 35 4 b b X eurjchem-34 35 5     SPACE eurjchem-34 35 6 = = NOUN eurjchem-34 35 7     SPACE eurjchem-34 35 8 17.150(3 17.150(3 NOUN eurjchem-34 35 9 ) ) PUNCT eurjchem-34 35 10     SPACE eurjchem-34 35 11 å å PROPN eurjchem-34 35 12       SPACE eurjchem-34 35 13 c c NOUN eurjchem-34 35 14     SPACE eurjchem-34 35 15 = = NOUN eurjchem-34 35 16     SPACE eurjchem-34 35 17 18.677(3 18.677(3 NOUN eurjchem-34 35 18 ) ) PUNCT eurjchem-34 35 19     SPACE eurjchem-34 36 1 å å PROPN eurjchem-34 36 2 . . PUNCT eurjchem-34 36 3     SPACE eurjchem-34 36 4 = = NOUN eurjchem-34 36 5     SPACE eurjchem-34 36 6 96.487(4) 96.487(4) NUM eurjchem-34 36 7 ° ° PROPN eurjchem-34 36 8 . . PUNCT eurjchem-34 36 9     SPACE eurjchem-34 36 10 volume volume NOUN eurjchem-34 36 11     SPACE eurjchem-34 36 12 1531.4(5 1531.4(5 NOUN eurjchem-34 36 13 ) ) PUNCT eurjchem-34 36 14     SPACE eurjchem-34 36 15 å3 å3 PROPN eurjchem-34 36 16     SPACE eurjchem-34 36 17 density density NOUN eurjchem-34 36 18     SPACE eurjchem-34 36 19 ( ( PUNCT eurjchem-34 36 20 calculated calculate VERB eurjchem-34 36 21 ) ) PUNCT eurjchem-34 36 22     SPACE eurjchem-34 36 23 1.516 1.516 NUM eurjchem-34 36 24     SPACE eurjchem-34 36 25 mg mg PROPN eurjchem-34 36 26 / / SYM eurjchem-34 36 27 m3 m3 PROPN eurjchem-34 36 28     SPACE eurjchem-34 36 29 absorption absorption NOUN eurjchem-34 36 30     SPACE eurjchem-34 36 31 coefficient coefficient NOUN eurjchem-34 36 32     SPACE eurjchem-34 36 33 0.366 0.366 VERB eurjchem-34 36 34     SPACE eurjchem-34 36 35 mm‐1 mm‐1 PROPN eurjchem-34 36 36     SPACE eurjchem-34 36 37 f(000 f(000 PROPN eurjchem-34 36 38 ) ) PUNCT eurjchem-34 36 39     SPACE eurjchem-34 36 40 728 728 NUM eurjchem-34 36 41     SPACE eurjchem-34 36 42 crystal crystal NOUN eurjchem-34 36 43     SPACE eurjchem-34 36 44 size size NOUN eurjchem-34 36 45     SPACE eurjchem-34 36 46 0.49 0.49 NUM eurjchem-34 36 47     SPACE eurjchem-34 36 48 x x NOUN eurjchem-34 36 49     SPACE eurjchem-34 36 50 0.20 0.20 NUM eurjchem-34 36 51     SPACE eurjchem-34 36 52 x x NOUN eurjchem-34 36 53     SPACE eurjchem-34 36 54 0.05 0.05 NUM eurjchem-34 36 55     SPACE eurjchem-34 36 56 mm3 mm3 PROPN eurjchem-34 36 57     SPACE eurjchem-34 36 58 theta theta NOUN eurjchem-34 36 59     SPACE eurjchem-34 36 60 range range NOUN eurjchem-34 36 61     SPACE eurjchem-34 36 62 for for ADP eurjchem-34 36 63     SPACE eurjchem-34 36 64 data datum NOUN eurjchem-34 36 65     SPACE eurjchem-34 36 66 collection collection NOUN eurjchem-34 36 67     SPACE eurjchem-34 36 68 1.62 1.62 NUM eurjchem-34 36 69     SPACE eurjchem-34 36 70 to to ADP eurjchem-34 36 71     SPACE eurjchem-34 36 72 27.87 27.87 NUM eurjchem-34 36 73 ° ° PROPN eurjchem-34 36 74     SPACE eurjchem-34 36 75 index index NOUN eurjchem-34 36 76     SPACE eurjchem-34 36 77 ranges range VERB eurjchem-34 36 78     SPACE eurjchem-34 36 79 ‐6 ‐6 NOUN eurjchem-34 36 80     SPACE eurjchem-34 36 81 ≤ ≤ NOUN eurjchem-34 36 82     SPACE eurjchem-34 36 83 h h NOUN eurjchem-34 36 84 ≤ ≤ NOUN eurjchem-34 36 85     SPACE eurjchem-34 36 86 6 6 NUM eurjchem-34 36 87     SPACE eurjchem-34 36 88 ‐22 ‐22 NOUN eurjchem-34 36 89     SPACE eurjchem-34 36 90 ≤ ≤ NOUN eurjchem-34 36 91     SPACE eurjchem-34 36 92 k k NOUN eurjchem-34 36 93     SPACE eurjchem-34 36 94 ≤ ≤ NOUN eurjchem-34 36 95     SPACE eurjchem-34 36 96 22 22 NUM eurjchem-34 36 97     SPACE eurjchem-34 36 98 ‐17 ‐17 NOUN eurjchem-34 36 99     SPACE eurjchem-34 36 100 ≤ ≤ NOUN eurjchem-34 36 101     SPACE eurjchem-34 36 102 l l NOUN eurjchem-34 36 103     SPACE eurjchem-34 36 104 ≤ ≤ NOUN eurjchem-34 36 105     SPACE eurjchem-34 36 106 24 24 NUM eurjchem-34 36 107     SPACE eurjchem-34 36 108 reflections reflection NOUN eurjchem-34 36 109     SPACE eurjchem-34 36 110 collected collect VERB eurjchem-34 36 111     SPACE eurjchem-34 36 112 13460 13460 NUM eurjchem-34 36 113 independent independent ADJ eurjchem-34 36 114     SPACE eurjchem-34 36 115 reflections reflection NOUN eurjchem-34 36 116     SPACE eurjchem-34 36 117 3665 3665 NUM eurjchem-34 36 118     SPACE eurjchem-34 37 1 [ [ X eurjchem-34 37 2 r(int r(int NOUN eurjchem-34 37 3 ) ) PUNCT eurjchem-34 37 4     SPACE eurjchem-34 38 1 = = NOUN eurjchem-34 38 2     SPACE eurjchem-34 38 3 0.0435 0.0435 NUM eurjchem-34 38 4 ] ] PUNCT eurjchem-34 38 5     SPACE eurjchem-34 38 6 completeness completeness NOUN eurjchem-34 38 7     SPACE eurjchem-34 38 8 to to ADP eurjchem-34 38 9     SPACE eurjchem-34 38 10 theta theta VERB eurjchem-34 38 11     SPACE eurjchem-34 38 12 = = NOUN eurjchem-34 38 13     SPACE eurjchem-34 38 14 27.87 27.87 NUM eurjchem-34 38 15 ° ° NOUN eurjchem-34 38 16     SPACE eurjchem-34 38 17 99.9 99.9 NUM eurjchem-34 38 18     SPACE eurjchem-34 38 19 % % NOUN eurjchem-34 38 20     SPACE eurjchem-34 38 21 absorption absorption NOUN eurjchem-34 38 22     SPACE eurjchem-34 38 23 correction correction NOUN eurjchem-34 38 24     SPACE eurjchem-34 38 25 semi‐empirical semi‐empirical NOUN eurjchem-34 38 26     SPACE eurjchem-34 38 27 from from ADP eurjchem-34 38 28     SPACE eurjchem-34 38 29 equivalents equivalent NOUN eurjchem-34 38 30 max max PROPN eurjchem-34 38 31 . . PUNCT eurjchem-34 38 32     SPACE eurjchem-34 38 33 and and CCONJ eurjchem-34 38 34     SPACE eurjchem-34 38 35 min min PROPN eurjchem-34 38 36 . . PROPN eurjchem-34 38 37     SPACE eurjchem-34 38 38 transmission transmission NOUN eurjchem-34 38 39     SPACE eurjchem-34 38 40 0.9819 0.9819 NUM eurjchem-34 38 41     SPACE eurjchem-34 38 42 and and CCONJ eurjchem-34 38 43     SPACE eurjchem-34 38 44 0.8409 0.8409 NUM eurjchem-34 38 45     SPACE eurjchem-34 38 46 refinement refinement NOUN eurjchem-34 38 47     SPACE eurjchem-34 38 48 method method NOUN eurjchem-34 38 49     SPACE eurjchem-34 38 50 full‐matrix full‐matrix NOUN eurjchem-34 38 51     SPACE eurjchem-34 38 52 least‐squares least‐square NOUN eurjchem-34 38 53     SPACE eurjchem-34 38 54 on on ADP eurjchem-34 38 55     SPACE eurjchem-34 38 56 f2 f2 PROPN eurjchem-34 38 57 data datum NOUN eurjchem-34 38 58     SPACE eurjchem-34 38 59 / / SYM eurjchem-34 38 60     SPACE eurjchem-34 38 61 restraints restraint NOUN eurjchem-34 38 62     SPACE eurjchem-34 38 63 / / SYM eurjchem-34 38 64     SPACE eurjchem-34 38 65 parameters parameter NOUN eurjchem-34 38 66     SPACE eurjchem-34 38 67 3665 3665 NUM eurjchem-34 38 68     SPACE eurjchem-34 38 69 / / SYM eurjchem-34 38 70     SPACE eurjchem-34 38 71 1 1 NUM eurjchem-34 38 72     SPACE eurjchem-34 38 73 / / SYM eurjchem-34 38 74     SPACE eurjchem-34 38 75 217 217 NUM eurjchem-34 38 76     SPACE eurjchem-34 38 77 goodness‐of‐fit goodness‐of‐fit NOUN eurjchem-34 38 78     SPACE eurjchem-34 38 79 on on ADP eurjchem-34 38 80     SPACE eurjchem-34 38 81 f2 f2 PROPN eurjchem-34 38 82     SPACE eurjchem-34 38 83 1.019 1.019 NUM eurjchem-34 38 84 final final ADJ eurjchem-34 38 85     SPACE eurjchem-34 38 86 r r NOUN eurjchem-34 38 87     SPACE eurjchem-34 38 88 indices index NOUN eurjchem-34 38 89     SPACE eurjchem-34 38 90 [ [ X eurjchem-34 38 91 i>2sigma(i i>2sigma(i NOUN eurjchem-34 38 92 ) ) PUNCT eurjchem-34 38 93 ] ] PUNCT eurjchem-34 38 94     SPACE eurjchem-34 38 95 r1 r1 X eurjchem-34 38 96     SPACE eurjchem-34 38 97 = = NOUN eurjchem-34 38 98     SPACE eurjchem-34 38 99 0.0437 0.0437 NUM eurjchem-34 38 100 , , PUNCT eurjchem-34 38 101     SPACE eurjchem-34 38 102 wr2 wr2 PROPN eurjchem-34 38 103     SPACE eurjchem-34 38 104 = = PROPN eurjchem-34 38 105     SPACE eurjchem-34 38 106 0.1012 0.1012 NUM eurjchem-34 38 107     SPACE eurjchem-34 38 108 r r NOUN eurjchem-34 38 109     SPACE eurjchem-34 38 110 indices index NOUN eurjchem-34 38 111     SPACE eurjchem-34 38 112 ( ( PUNCT eurjchem-34 38 113 all all DET eurjchem-34 38 114     SPACE eurjchem-34 38 115 data datum NOUN eurjchem-34 38 116 ) ) PUNCT eurjchem-34 38 117     SPACE eurjchem-34 38 118 r1 r1 PROPN eurjchem-34 38 119     SPACE eurjchem-34 38 120 = = NOUN eurjchem-34 38 121     SPACE eurjchem-34 38 122 0.0602 0.0602 NUM eurjchem-34 38 123 , , PUNCT eurjchem-34 38 124     SPACE eurjchem-34 38 125 wr2 wr2 PROPN eurjchem-34 38 126     SPACE eurjchem-34 38 127 = = NOUN eurjchem-34 38 128     SPACE eurjchem-34 38 129 0.1089 0.1089 NUM eurjchem-34 38 130     SPACE eurjchem-34 38 131 largest large ADJ eurjchem-34 38 132     SPACE eurjchem-34 38 133 diff diff NOUN eurjchem-34 38 134 . . PUNCT eurjchem-34 38 135     SPACE eurjchem-34 38 136 peak peak NOUN eurjchem-34 38 137     SPACE eurjchem-34 38 138 and and CCONJ eurjchem-34 38 139     SPACE eurjchem-34 38 140 hole hole NOUN eurjchem-34 38 141     SPACE eurjchem-34 38 142 0.409 0.409 NUM eurjchem-34 38 143     SPACE eurjchem-34 38 144 and and CCONJ eurjchem-34 38 145     SPACE eurjchem-34 38 146 ‐0.263 ‐0.263 NOUN eurjchem-34 38 147     SPACE eurjchem-34 38 148 e.å‐3 e.å‐3 PROPN eurjchem-34 38 149     SPACE eurjchem-34 38 150 measurement measurement NOUN eurjchem-34 38 151     SPACE eurjchem-34 38 152 bruker bruker NOUN eurjchem-34 38 153     SPACE eurjchem-34 38 154 smart smart ADJ eurjchem-34 38 155     SPACE eurjchem-34 38 156 apex apex NOUN eurjchem-34 38 157     SPACE eurjchem-34 38 158 ccd ccd PROPN eurjchem-34 38 159     SPACE eurjchem-34 38 160 diffractometer diffractometer NOUN eurjchem-34 38 161 program program NOUN eurjchem-34 38 162     SPACE eurjchem-34 38 163 system system NOUN eurjchem-34 38 164     SPACE eurjchem-34 38 165 saint saint NOUN eurjchem-34 38 166 structure structure NOUN eurjchem-34 38 167     SPACE eurjchem-34 38 168 determination determination NOUN eurjchem-34 38 169     SPACE eurjchem-34 38 170 direct direct ADJ eurjchem-34 38 171     SPACE eurjchem-34 38 172 methods method NOUN eurjchem-34 38 173     SPACE eurjchem-34 38 174 ( ( PUNCT eurjchem-34 38 175 shelxl‐97 shelxl‐97 NOUN eurjchem-34 38 176 , , PUNCT eurjchem-34 38 177     SPACE eurjchem-34 38 178 shelxtl shelxtl NOUN eurjchem-34 38 179 ) ) PUNCT eurjchem-34 38 180 ccdc ccdc PROPN eurjchem-34 38 181       SPACE eurjchem-34 38 182 679109 679109 NUM eurjchem-34 38 183           SPACE eurjchem-34 38 184 3 3 NUM eurjchem-34 38 185 . . PUNCT eurjchem-34 38 186     SPACE eurjchem-34 38 187 results result VERB eurjchem-34 38 188     SPACE eurjchem-34 38 189 and and CCONJ eurjchem-34 38 190     SPACE eurjchem-34 38 191 discussion discussion NOUN eurjchem-34 38 192         SPACE eurjchem-34 38 193 4‐methylbenzoyl 4‐methylbenzoyl NUM eurjchem-34 38 194     SPACE eurjchem-34 38 195 chloride chloride NOUN eurjchem-34 38 196     SPACE eurjchem-34 38 197 ( ( PUNCT eurjchem-34 38 198 1 1 NUM eurjchem-34 38 199 ) ) PUNCT eurjchem-34 38 200     SPACE eurjchem-34 38 201 was be AUX eurjchem-34 38 202     SPACE eurjchem-34 38 203 obtained obtain VERB eurjchem-34 38 204     SPACE eurjchem-34 38 205 from from ADP eurjchem-34 38 206     SPACE eurjchem-34 38 207 the the DET eurjchem-34 38 208     SPACE eurjchem-34 38 209 corresponding corresponding ADJ eurjchem-34 38 210     SPACE eurjchem-34 38 211 acid acid NOUN eurjchem-34 38 212     SPACE eurjchem-34 38 213 according according NOUN eurjchem-34 38 214     SPACE eurjchem-34 38 215 to to ADP eurjchem-34 38 216     SPACE eurjchem-34 38 217 the the DET eurjchem-34 38 218     SPACE eurjchem-34 38 219 standard standard ADJ eurjchem-34 38 220     SPACE eurjchem-34 38 221 procedure procedure NOUN eurjchem-34 38 222 . . PUNCT eurjchem-34 38 223     SPACE eurjchem-34 39 1 it it PRON eurjchem-34 39 2     SPACE eurjchem-34 39 3 was be AUX eurjchem-34 39 4     SPACE eurjchem-34 39 5 then then ADV eurjchem-34 39 6     SPACE eurjchem-34 39 7 treated treat VERB eurjchem-34 39 8     SPACE eurjchem-34 39 9 in in ADP eurjchem-34 39 10     SPACE eurjchem-34 39 11 a a DET eurjchem-34 39 12     SPACE eurjchem-34 39 13 1:1 1:1 NUM eurjchem-34 39 14     SPACE eurjchem-34 39 15 molar molar ADJ eurjchem-34 39 16     SPACE eurjchem-34 39 17 ratio ratio NOUN eurjchem-34 39 18     SPACE eurjchem-34 39 19 with with ADP eurjchem-34 39 20     SPACE eurjchem-34 39 21 potassium potassium NOUN eurjchem-34 39 22     SPACE eurjchem-34 39 23 thiocyanate thiocyanate NOUN eurjchem-34 39 24     SPACE eurjchem-34 39 25 in in ADP eurjchem-34 39 26     SPACE eurjchem-34 39 27 dry dry ADJ eurjchem-34 39 28     SPACE eurjchem-34 39 29 acetone acetone NOUN eurjchem-34 39 30     SPACE eurjchem-34 39 31 to to PART eurjchem-34 39 32     SPACE eurjchem-34 39 33 afford afford VERB eurjchem-34 39 34     SPACE eurjchem-34 39 35 the the DET eurjchem-34 39 36     SPACE eurjchem-34 39 37 4‐methylbenzoyl 4‐methylbenzoyl NUM eurjchem-34 39 38     SPACE eurjchem-34 39 39 isothiocyante isothiocyante NOUN eurjchem-34 39 40     SPACE eurjchem-34 39 41 intermediate intermediate ADJ eurjchem-34 39 42     SPACE eurjchem-34 39 43 which which PRON eurjchem-34 39 44     SPACE eurjchem-34 39 45 was be AUX eurjchem-34 39 46     SPACE eurjchem-34 39 47 not not PART eurjchem-34 39 48     SPACE eurjchem-34 39 49 separated separate VERB eurjchem-34 39 50 . . PUNCT eurjchem-34 39 51     SPACE eurjchem-34 39 52 condensation condensation NOUN eurjchem-34 39 53     SPACE eurjchem-34 39 54 of of ADP eurjchem-34 39 55     SPACE eurjchem-34 39 56 the the DET eurjchem-34 39 57     SPACE eurjchem-34 39 58 latter latter ADJ eurjchem-34 39 59     SPACE eurjchem-34 39 60 with with ADP eurjchem-34 39 61     SPACE eurjchem-34 39 62 an an DET eurjchem-34 39 63     SPACE eurjchem-34 39 64 equimolar equimolar NOUN eurjchem-34 39 65     SPACE eurjchem-34 39 66 quantity quantity NOUN eurjchem-34 39 67     SPACE eurjchem-34 39 68 of of ADP eurjchem-34 39 69     SPACE eurjchem-34 39 70 sulfanilamide sulfanilamide NOUN eurjchem-34 39 71     SPACE eurjchem-34 39 72 ( ( PUNCT eurjchem-34 39 73 2 2 NUM eurjchem-34 39 74 ) ) PUNCT eurjchem-34 39 75     SPACE eurjchem-34 39 76 in in ADP eurjchem-34 39 77     SPACE eurjchem-34 39 78 anhydrous anhydrous ADJ eurjchem-34 39 79     SPACE eurjchem-34 39 80 acetone acetone NOUN eurjchem-34 39 81     SPACE eurjchem-34 39 82 furnished furnish VERB eurjchem-34 39 83     SPACE eurjchem-34 39 84 the the DET eurjchem-34 39 85     SPACE eurjchem-34 39 86 1‐(4‐methylbenzoyl)‐3‐(4‐ 1‐(4‐methylbenzoyl)‐3‐(4‐ NUM eurjchem-34 39 87 aminosulfonylphenyl)thiourea aminosulfonylphenyl)thiourea NOUN eurjchem-34 39 88     SPACE eurjchem-34 39 89 ( ( PUNCT eurjchem-34 39 90 3 3 NUM eurjchem-34 39 91 ) ) PUNCT eurjchem-34 39 92     SPACE eurjchem-34 39 93 in in ADP eurjchem-34 39 94     SPACE eurjchem-34 39 95 91 91 NUM eurjchem-34 39 96 % % NOUN eurjchem-34 39 97     SPACE eurjchem-34 39 98 yield yield NOUN eurjchem-34 39 99     SPACE eurjchem-34 39 100 ( ( PUNCT eurjchem-34 39 101 scheme scheme NOUN eurjchem-34 39 102     SPACE eurjchem-34 39 103 1 1 NUM eurjchem-34 39 104 ) ) PUNCT eurjchem-34 39 105 . . PUNCT eurjchem-34 39 106       SPACE eurjchem-34 40 1 colorless colorless ADJ eurjchem-34 40 2     SPACE eurjchem-34 40 3 crystals crystal NOUN eurjchem-34 40 4     SPACE eurjchem-34 40 5 of of ADP eurjchem-34 40 6     SPACE eurjchem-34 40 7 1‐(4‐methylbenzoyl)‐3‐(4‐amino 1‐(4‐methylbenzoyl)‐3‐(4‐amino NUM eurjchem-34 40 8     SPACE eurjchem-34 40 9 sulfonylphenyl)thiourea sulfonylphenyl)thiourea PROPN eurjchem-34 40 10 , , PUNCT eurjchem-34 40 11     SPACE eurjchem-34 40 12 suitable suitable ADJ eurjchem-34 40 13     SPACE eurjchem-34 40 14 for for ADP eurjchem-34 40 15     SPACE eurjchem-34 40 16 x‐ray x‐ray ADJ eurjchem-34 40 17     SPACE eurjchem-34 40 18 analysis analysis NOUN eurjchem-34 40 19 , , PUNCT eurjchem-34 40 20     SPACE eurjchem-34 40 21 were be AUX eurjchem-34 40 22     SPACE eurjchem-34 40 23 obtained obtain VERB eurjchem-34 40 24     SPACE eurjchem-34 40 25 by by ADP eurjchem-34 40 26     SPACE eurjchem-34 40 27 slow slow ADJ eurjchem-34 40 28     SPACE eurjchem-34 40 29 evaporation evaporation NOUN eurjchem-34 40 30     SPACE eurjchem-34 40 31 from from ADP eurjchem-34 40 32     SPACE eurjchem-34 40 33 ethyl ethyl PROPN eurjchem-34 40 34     SPACE eurjchem-34 40 35 acetate acetate NOUN eurjchem-34 40 36 / / SYM eurjchem-34 40 37 petroleum petroleum NOUN eurjchem-34 40 38     SPACE eurjchem-34 40 39 ether ether NOUN eurjchem-34 40 40     SPACE eurjchem-34 40 41 ( ( PUNCT eurjchem-34 40 42 1:2 1:2 NUM eurjchem-34 40 43 ) ) PUNCT eurjchem-34 40 44     SPACE eurjchem-34 40 45 solvent solvent NOUN eurjchem-34 40 46     SPACE eurjchem-34 40 47 mixture mixture NOUN eurjchem-34 40 48 . . PUNCT eurjchem-34 40 49     SPACE eurjchem-34 41 1 the the DET eurjchem-34 41 2     SPACE eurjchem-34 41 3 thiourea thiourea NOUN eurjchem-34 41 4     SPACE eurjchem-34 41 5 was be AUX eurjchem-34 41 6     SPACE eurjchem-34 41 7 characterized characterize VERB eurjchem-34 41 8     SPACE eurjchem-34 41 9 by by ADP eurjchem-34 41 10     SPACE eurjchem-34 41 11 typical typical ADJ eurjchem-34 41 12     SPACE eurjchem-34 41 13 ir ir VERB eurjchem-34 41 14     SPACE eurjchem-34 41 15 stretching stretch VERB eurjchem-34 41 16     SPACE eurjchem-34 41 17 vibrations vibration NOUN eurjchem-34 41 18     SPACE eurjchem-34 41 19 of of ADP eurjchem-34 41 20     SPACE eurjchem-34 41 21 n−h n−h NOUN eurjchem-34 41 22     SPACE eurjchem-34 41 23 at at ADP eurjchem-34 41 24     SPACE eurjchem-34 41 25 3318 3318 NUM eurjchem-34 41 26     SPACE eurjchem-34 41 27 cm−1 cm−1 NOUN eurjchem-34 41 28 , , PUNCT eurjchem-34 41 29     SPACE eurjchem-34 41 30 c c NOUN eurjchem-34 41 31 = = NOUN eurjchem-34 41 32 o o NOUN eurjchem-34 41 33     SPACE eurjchem-34 41 34 at at ADP eurjchem-34 41 35     SPACE eurjchem-34 41 36 1663 1663 NUM eurjchem-34 41 37     SPACE eurjchem-34 41 38 cm−1 cm−1 NOUN eurjchem-34 41 39 , , PUNCT eurjchem-34 41 40     SPACE eurjchem-34 41 41 c c NOUN eurjchem-34 41 42 = = SYM eurjchem-34 41 43 s s NOUN eurjchem-34 41 44     SPACE eurjchem-34 41 45 at at ADP eurjchem-34 41 46     SPACE eurjchem-34 41 47 1263 1263 NUM eurjchem-34 41 48     SPACE eurjchem-34 41 49 cm−1 cm−1 NOUN eurjchem-34 41 50 , , PUNCT eurjchem-34 41 51     SPACE eurjchem-34 41 52 c−n c−n NOUN eurjchem-34 41 53     SPACE eurjchem-34 41 54 at at ADP eurjchem-34 41 55     SPACE eurjchem-34 41 56 1154 1154 NUM eurjchem-34 41 57     SPACE eurjchem-34 41 58 cm−1 cm−1 NOUN eurjchem-34 41 59 , , PUNCT eurjchem-34 41 60     SPACE eurjchem-34 41 61 and and CCONJ eurjchem-34 41 62     SPACE eurjchem-34 41 63 s s PART eurjchem-34 41 64 = = NOUN eurjchem-34 41 65 o o NOUN eurjchem-34 41 66     SPACE eurjchem-34 41 67 at at ADP eurjchem-34 41 68     SPACE eurjchem-34 41 69 1334 1334 NUM eurjchem-34 41 70     SPACE eurjchem-34 41 71 cm−1 cm−1 NOUN eurjchem-34 41 72     SPACE eurjchem-34 41 73 in in ADP eurjchem-34 41 74     SPACE eurjchem-34 41 75 addition addition NOUN eurjchem-34 41 76     SPACE eurjchem-34 41 77 to to ADP eurjchem-34 41 78     SPACE eurjchem-34 41 79 the the DET eurjchem-34 41 80     SPACE eurjchem-34 41 81 aromatic aromatic ADJ eurjchem-34 41 82     SPACE eurjchem-34 41 83 ring ring NOUN eurjchem-34 41 84     SPACE eurjchem-34 41 85 at at ADP eurjchem-34 41 86     SPACE eurjchem-34 41 87 1590 1590 NUM eurjchem-34 41 88     SPACE eurjchem-34 41 89 cm−1 cm−1 NOUN eurjchem-34 41 90 . . PUNCT eurjchem-34 41 91       SPACE eurjchem-34 41 92 in in ADP eurjchem-34 41 93     SPACE eurjchem-34 41 94 1h 1h NUM eurjchem-34 41 95     SPACE eurjchem-34 41 96 nmr nmr NOUN eurjchem-34 41 97     SPACE eurjchem-34 41 98 the the DET eurjchem-34 41 99     SPACE eurjchem-34 41 100 singlet singlet NOUN eurjchem-34 41 101     SPACE eurjchem-34 41 102 for for ADP eurjchem-34 41 103     SPACE eurjchem-34 41 104 the the DET eurjchem-34 41 105     SPACE eurjchem-34 41 106 aromatic aromatic ADJ eurjchem-34 41 107     SPACE eurjchem-34 41 108 methyl methyl NOUN eurjchem-34 41 109     SPACE eurjchem-34 41 110 appeared appear VERB eurjchem-34 41 111     SPACE eurjchem-34 41 112 at at ADP eurjchem-34 41 113     SPACE eurjchem-34 41 114   VERB eurjchem-34 41 115     SPACE eurjchem-34 41 116 2.43 2.43 NUM eurjchem-34 41 117     SPACE eurjchem-34 41 118 and and CCONJ eurjchem-34 41 119     SPACE eurjchem-34 41 120 the the DET eurjchem-34 41 121     SPACE eurjchem-34 41 122 characteristic characteristic ADJ eurjchem-34 41 123     SPACE eurjchem-34 41 124 broad broad ADJ eurjchem-34 41 125     SPACE eurjchem-34 41 126 singlets singlet NOUN eurjchem-34 41 127     SPACE eurjchem-34 41 128 at at ADP eurjchem-34 41 129     SPACE eurjchem-34 41 130   NOUN eurjchem-34 41 131     SPACE eurjchem-34 41 132 9.19 9.19 NUM eurjchem-34 41 133     SPACE eurjchem-34 41 134 and and CCONJ eurjchem-34 41 135     SPACE eurjchem-34 41 136   VERB eurjchem-34 41 137     SPACE eurjchem-34 41 138 12.76 12.76 NUM eurjchem-34 41 139     SPACE eurjchem-34 41 140 for for ADP eurjchem-34 41 141     SPACE eurjchem-34 41 142 the the DET eurjchem-34 41 143     SPACE eurjchem-34 41 144 protons proton NOUN eurjchem-34 41 145     SPACE eurjchem-34 41 146 of of ADP eurjchem-34 41 147     SPACE eurjchem-34 41 148 n1 n1 NOUN eurjchem-34 41 149     SPACE eurjchem-34 41 150 and and CCONJ eurjchem-34 41 151     SPACE eurjchem-34 41 152 n3 n3 NOUN eurjchem-34 41 153     SPACE eurjchem-34 41 154 respectively respectively ADV eurjchem-34 41 155 . . PUNCT eurjchem-34 41 156     SPACE eurjchem-34 41 157 the the DET eurjchem-34 41 158     SPACE eurjchem-34 41 159 signals signal NOUN eurjchem-34 41 160     SPACE eurjchem-34 41 161 for for ADP eurjchem-34 41 162     SPACE eurjchem-34 41 163 the the DET eurjchem-34 41 164     SPACE eurjchem-34 41 165 aromatic aromatic ADJ eurjchem-34 41 166     SPACE eurjchem-34 41 167 protons proton NOUN eurjchem-34 41 168     SPACE eurjchem-34 41 169 were be AUX eurjchem-34 41 170     SPACE eurjchem-34 41 171 also also ADV eurjchem-34 41 172     SPACE eurjchem-34 41 173 noted note VERB eurjchem-34 41 174 . . PUNCT eurjchem-34 41 175     SPACE eurjchem-34 41 176 13c 13c NOUN eurjchem-34 41 177     SPACE eurjchem-34 41 178 nmr nmr NOUN eurjchem-34 41 179     SPACE eurjchem-34 41 180 showed show VERB eurjchem-34 41 181     SPACE eurjchem-34 41 182 peaks peak NOUN eurjchem-34 41 183     SPACE eurjchem-34 41 184 at at ADP eurjchem-34 41 185     SPACE eurjchem-34 41 186   VERB eurjchem-34 41 187     SPACE eurjchem-34 41 188 23.9 23.9 NUM eurjchem-34 41 189     SPACE eurjchem-34 41 190 for for ADP eurjchem-34 41 191     SPACE eurjchem-34 41 192 the the DET eurjchem-34 41 193     SPACE eurjchem-34 41 194 aromatic aromatic ADJ eurjchem-34 41 195     SPACE eurjchem-34 41 196 methyl methyl NOUN eurjchem-34 41 197     SPACE eurjchem-34 41 198 and and CCONJ eurjchem-34 41 199     SPACE eurjchem-34 41 200 at at ADP eurjchem-34 41 201     SPACE eurjchem-34 41 202   VERB eurjchem-34 41 203     SPACE eurjchem-34 41 204 170.3 170.3 NUM eurjchem-34 41 205     SPACE eurjchem-34 41 206 and and CCONJ eurjchem-34 41 207     SPACE eurjchem-34 41 208   VERB eurjchem-34 41 209     SPACE eurjchem-34 41 210 179.4 179.4 NUM eurjchem-34 41 211     SPACE eurjchem-34 41 212 for for ADP eurjchem-34 41 213     SPACE eurjchem-34 41 214 c c PROPN eurjchem-34 41 215 = = NOUN eurjchem-34 41 216 o o NOUN eurjchem-34 41 217     SPACE eurjchem-34 41 218 and and CCONJ eurjchem-34 41 219     SPACE eurjchem-34 41 220 c c NOUN eurjchem-34 41 221 = = SYM eurjchem-34 41 222 s s NOUN eurjchem-34 41 223     SPACE eurjchem-34 41 224 respectively respectively ADV eurjchem-34 41 225 . . PUNCT eurjchem-34 41 226     SPACE eurjchem-34 41 227 mass mass PROPN eurjchem-34 41 228     SPACE eurjchem-34 41 229 spectrum spectrum NOUN eurjchem-34 41 230     SPACE eurjchem-34 41 231 of of ADP eurjchem-34 41 232     SPACE eurjchem-34 41 233 the the DET eurjchem-34 41 234     SPACE eurjchem-34 41 235 compound compound NOUN eurjchem-34 41 236     SPACE eurjchem-34 41 237 showed show VERB eurjchem-34 41 238     SPACE eurjchem-34 41 239 the the DET eurjchem-34 41 240     SPACE eurjchem-34 41 241 molecular molecular ADJ eurjchem-34 41 242     SPACE eurjchem-34 41 243 ion ion NOUN eurjchem-34 41 244     SPACE eurjchem-34 41 245 peak peak NOUN eurjchem-34 41 246     SPACE eurjchem-34 41 247 at at ADP eurjchem-34 41 248     SPACE eurjchem-34 41 249 m m PROPN eurjchem-34 41 250 / / PROPN eurjchem-34 42 1 z z NOUN eurjchem-34 42 2     SPACE eurjchem-34 42 3 304 304 NUM eurjchem-34 42 4 . . PUNCT eurjchem-34 42 5     SPACE eurjchem-34 43 1 the the DET eurjchem-34 43 2     SPACE eurjchem-34 43 3 major major ADJ eurjchem-34 43 4     SPACE eurjchem-34 43 5 fragment fragment NOUN eurjchem-34 43 6     SPACE eurjchem-34 43 7 at at ADP eurjchem-34 43 8     SPACE eurjchem-34 43 9 m m PROPN eurjchem-34 43 10 / / PROPN eurjchem-34 43 11 z z NOUN eurjchem-34 43 12     SPACE eurjchem-34 43 13 168.9 168.9 NUM eurjchem-34 43 14     SPACE eurjchem-34 43 15 ( ( PUNCT eurjchem-34 43 16 50 50 NUM eurjchem-34 43 17     SPACE eurjchem-34 43 18 % % NOUN eurjchem-34 43 19 ) ) PUNCT eurjchem-34 43 20     SPACE eurjchem-34 43 21 was be AUX eurjchem-34 43 22     SPACE eurjchem-34 43 23 derived derive VERB eurjchem-34 43 24     SPACE eurjchem-34 43 25 from from ADP eurjchem-34 43 26     SPACE eurjchem-34 43 27 the the DET eurjchem-34 43 28     SPACE eurjchem-34 43 29 n‐mclafferty n‐mclafferty NOUN eurjchem-34 43 30     SPACE eurjchem-34 43 31 rearrangement rearrangement NOUN eurjchem-34 43 32     SPACE eurjchem-34 43 33 and and CCONJ eurjchem-34 43 34     SPACE eurjchem-34 43 35 the the DET eurjchem-34 43 36     SPACE eurjchem-34 43 37 base base NOUN eurjchem-34 43 38     SPACE eurjchem-34 43 39 peak peak NOUN eurjchem-34 43 40     SPACE eurjchem-34 43 41 at at ADP eurjchem-34 43 42     SPACE eurjchem-34 43 43 m m PROPN eurjchem-34 43 44 / / PROPN eurjchem-34 43 45 z z NOUN eurjchem-34 43 46     SPACE eurjchem-34 43 47 119 119 NUM eurjchem-34 43 48     SPACE eurjchem-34 43 49 originated originate VERB eurjchem-34 43 50     SPACE eurjchem-34 43 51 from from ADP eurjchem-34 43 52     SPACE eurjchem-34 43 53 the the DET eurjchem-34 43 54     SPACE eurjchem-34 43 55 4‐methylbenzoyl 4‐methylbenzoyl NUM eurjchem-34 43 56     SPACE eurjchem-34 43 57 cation cation NOUN eurjchem-34 43 58 . . PUNCT eurjchem-34 43 59     SPACE eurjchem-34 44 1 the the DET eurjchem-34 44 2     SPACE eurjchem-34 44 3 molecular molecular ADJ eurjchem-34 44 4     SPACE eurjchem-34 44 5 structure structure NOUN eurjchem-34 44 6     SPACE eurjchem-34 44 7 of of ADP eurjchem-34 44 8     SPACE eurjchem-34 44 9 the the DET eurjchem-34 44 10     SPACE eurjchem-34 44 11 title title NOUN eurjchem-34 44 12     SPACE eurjchem-34 44 13 compound compound NOUN eurjchem-34 44 14     SPACE eurjchem-34 44 15 is be AUX eurjchem-34 44 16     SPACE eurjchem-34 44 17 depicted depict VERB eurjchem-34 44 18     SPACE eurjchem-34 44 19 in in ADP eurjchem-34 44 20     SPACE eurjchem-34 44 21 figure figure NOUN eurjchem-34 44 22     SPACE eurjchem-34 44 23 2 2 NUM eurjchem-34 44 24 . . PUNCT eurjchem-34 44 25     SPACE eurjchem-34 44 26 table table NOUN eurjchem-34 44 27     SPACE eurjchem-34 44 28 1 1 NUM eurjchem-34 44 29     SPACE eurjchem-34 44 30 gives give VERB eurjchem-34 44 31     SPACE eurjchem-34 44 32 the the DET eurjchem-34 44 33     SPACE eurjchem-34 44 34 crystal crystal NOUN eurjchem-34 44 35     SPACE eurjchem-34 44 36 data datum NOUN eurjchem-34 44 37     SPACE eurjchem-34 44 38 and and CCONJ eurjchem-34 44 39     SPACE eurjchem-34 44 40 the the DET eurjchem-34 44 41     SPACE eurjchem-34 44 42 structure structure NOUN eurjchem-34 44 43     SPACE eurjchem-34 44 44 refinement refinement NOUN eurjchem-34 44 45 ; ; PUNCT eurjchem-34 44 46     SPACE eurjchem-34 44 47 selected select VERB eurjchem-34 44 48     SPACE eurjchem-34 44 49 bond bond NOUN eurjchem-34 44 50     SPACE eurjchem-34 44 51 lengths length NOUN eurjchem-34 44 52     SPACE eurjchem-34 44 53 and and CCONJ eurjchem-34 44 54     SPACE eurjchem-34 44 55 angles angle NOUN eurjchem-34 44 56     SPACE eurjchem-34 44 57 as as ADV eurjchem-34 44 58     SPACE eurjchem-34 44 59 well well ADV eurjchem-34 44 60     SPACE eurjchem-34 44 61 as as SCONJ eurjchem-34 44 62     SPACE eurjchem-34 44 63 hydrogen hydrogen NOUN eurjchem-34 44 64     SPACE eurjchem-34 44 65 bonds bond NOUN eurjchem-34 44 66     SPACE eurjchem-34 44 67 are be AUX eurjchem-34 44 68     SPACE eurjchem-34 44 69 presented present VERB eurjchem-34 44 70     SPACE eurjchem-34 44 71 in in ADP eurjchem-34 44 72     SPACE eurjchem-34 44 73 table table NOUN eurjchem-34 44 74     SPACE eurjchem-34 44 75 2 2 NUM eurjchem-34 44 76 . . PUNCT eurjchem-34 44 77     SPACE eurjchem-34 44 78 the the DET eurjchem-34 44 79     SPACE eurjchem-34 44 80 torsion torsion NOUN eurjchem-34 44 81     SPACE eurjchem-34 44 82 angles angle NOUN eurjchem-34 44 83     SPACE eurjchem-34 44 84 c7‐n2‐c8‐o1 c7‐n2‐c8‐o1 NOUN eurjchem-34 44 85     SPACE eurjchem-34 44 86 of of ADP eurjchem-34 44 87     SPACE eurjchem-34 44 88 2.3(3 2.3(3 NUM eurjchem-34 44 89 ) ) PUNCT eurjchem-34 44 90 ° ° NOUN eurjchem-34 44 91     SPACE eurjchem-34 44 92 and and CCONJ eurjchem-34 44 93     SPACE eurjchem-34 44 94 c8‐n2‐c7‐n1 c8‐n2‐c7‐n1 NOUN eurjchem-34 44 95     SPACE eurjchem-34 44 96 of of ADP eurjchem-34 44 97     SPACE eurjchem-34 44 98 – – PUNCT eurjchem-34 44 99 6.1(3 6.1(3 NUM eurjchem-34 44 100 ) ) PUNCT eurjchem-34 44 101 ° ° NOUN eurjchem-34 44 102     SPACE eurjchem-34 44 103 reflect reflect VERB eurjchem-34 44 104     SPACE eurjchem-34 44 105 the the DET eurjchem-34 44 106     SPACE eurjchem-34 44 107 almost almost ADV eurjchem-34 44 108     SPACE eurjchem-34 44 109 planar planar ADJ eurjchem-34 44 110     SPACE eurjchem-34 44 111 conformation conformation NOUN eurjchem-34 44 112     SPACE eurjchem-34 44 113 of of ADP eurjchem-34 44 114     SPACE eurjchem-34 44 115 the the DET eurjchem-34 44 116     SPACE eurjchem-34 44 117 molecule molecule NOUN eurjchem-34 44 118     SPACE eurjchem-34 44 119 with with ADP eurjchem-34 44 120     SPACE eurjchem-34 44 121 respect respect NOUN eurjchem-34 44 122     SPACE eurjchem-34 44 123 to to ADP eurjchem-34 44 124     SPACE eurjchem-34 44 125 the the DET eurjchem-34 44 126     SPACE eurjchem-34 44 127 thiocarbonyl thiocarbonyl NOUN eurjchem-34 44 128     SPACE eurjchem-34 44 129 and and CCONJ eurjchem-34 44 130     SPACE eurjchem-34 44 131 carbonyl carbonyl NOUN eurjchem-34 44 132     SPACE eurjchem-34 44 133 parts part NOUN eurjchem-34 44 134 . . PUNCT eurjchem-34 44 135     SPACE eurjchem-34 45 1 the the DET eurjchem-34 45 2     SPACE eurjchem-34 45 3 two two NUM eurjchem-34 45 4     SPACE eurjchem-34 45 5 aromatic aromatic ADJ eurjchem-34 45 6     SPACE eurjchem-34 45 7 rings ring NOUN eurjchem-34 45 8     SPACE eurjchem-34 45 9 form form NOUN eurjchem-34 45 10     SPACE eurjchem-34 45 11 a a DET eurjchem-34 45 12     SPACE eurjchem-34 45 13 dihedral dihedral ADJ eurjchem-34 45 14     SPACE eurjchem-34 45 15 angle angle NOUN eurjchem-34 45 16     SPACE eurjchem-34 45 17 of of ADP eurjchem-34 45 18     SPACE eurjchem-34 45 19 42.82(8 42.82(8 NUM eurjchem-34 45 20 ) ) PUNCT eurjchem-34 45 21 ° ° NOUN eurjchem-34 45 22     SPACE eurjchem-34 45 23 and and CCONJ eurjchem-34 45 24     SPACE eurjchem-34 45 25 the the DET eurjchem-34 45 26     SPACE eurjchem-34 45 27 associated associate VERB eurjchem-34 45 28     SPACE eurjchem-34 45 29 n2‐c8‐c9‐c10 n2‐c8‐c9‐c10 NUM eurjchem-34 45 30     SPACE eurjchem-34 45 31 torsion torsion NOUN eurjchem-34 45 32     SPACE eurjchem-34 45 33 angle angle NOUN eurjchem-34 45 34     SPACE eurjchem-34 45 35 is be AUX eurjchem-34 45 36     SPACE eurjchem-34 45 37 9.6(3) 9.6(3) NUM eurjchem-34 45 38 ° ° PROPN eurjchem-34 45 39 . . PUNCT eurjchem-34 45 40     SPACE eurjchem-34 45 41 bond bond NOUN eurjchem-34 45 42     SPACE eurjchem-34 45 43 parameters parameter NOUN eurjchem-34 45 44     SPACE eurjchem-34 45 45 ( ( PUNCT eurjchem-34 45 46 table table NOUN eurjchem-34 45 47     SPACE eurjchem-34 45 48 1 1 NUM eurjchem-34 45 49 ) ) PUNCT eurjchem-34 45 50     SPACE eurjchem-34 45 51 in in SCONJ eurjchem-34 45 52     SPACE eurjchem-34 45 53 general general NOUN eurjchem-34 45 54     SPACE eurjchem-34 45 55 are be AUX eurjchem-34 45 56     SPACE eurjchem-34 45 57 typical typical ADJ eurjchem-34 45 58     SPACE eurjchem-34 45 59 for for ADP eurjchem-34 45 60     SPACE eurjchem-34 45 61 this this DET eurjchem-34 45 62     SPACE eurjchem-34 45 63 type type NOUN eurjchem-34 45 64     SPACE eurjchem-34 45 65 of of ADP eurjchem-34 45 66     SPACE eurjchem-34 45 67 a a DET eurjchem-34 45 68     SPACE eurjchem-34 45 69 compound compound NOUN eurjchem-34 45 70 . . PUNCT eurjchem-34 45 71     SPACE eurjchem-34 45 72 similar similar ADJ eurjchem-34 45 73     SPACE eurjchem-34 45 74 geometric geometric ADJ eurjchem-34 45 75     SPACE eurjchem-34 45 76 parameters parameter NOUN eurjchem-34 45 77     SPACE eurjchem-34 45 78 are be AUX eurjchem-34 45 79     SPACE eurjchem-34 45 80 valid valid ADJ eurjchem-34 45 81     SPACE eurjchem-34 45 82 for for ADP eurjchem-34 45 83     SPACE eurjchem-34 45 84 the the DET eurjchem-34 45 85     SPACE eurjchem-34 45 86 related related ADJ eurjchem-34 45 87     SPACE eurjchem-34 45 88 molecular molecular ADJ eurjchem-34 45 89     SPACE eurjchem-34 45 90 structures structure NOUN eurjchem-34 45 91     SPACE eurjchem-34 45 92 of of ADP eurjchem-34 45 93     SPACE eurjchem-34 45 94 1‐ 1‐ NUM eurjchem-34 45 95 ( ( PUNCT eurjchem-34 45 96 4‐methylbenzoyl)‐3‐(4‐nitro 4‐methylbenzoyl)‐3‐(4‐nitro NUM eurjchem-34 45 97 / / SYM eurjchem-34 45 98 halogeno‐phenyl)thiourea halogeno‐phenyl)thiourea ADJ eurjchem-34 45 99     SPACE eurjchem-34 46 1 [ [ PUNCT eurjchem-34 46 2 9‐ 9‐ NUM eurjchem-34 46 3 11 11 NUM eurjchem-34 46 4 ] ] PUNCT eurjchem-34 46 5 ; ; PUNCT eurjchem-34 46 6     SPACE eurjchem-34 46 7 the the DET eurjchem-34 46 8     SPACE eurjchem-34 46 9 most most ADJ eurjchem-34 46 10     SPACE eurjchem-34 46 11 distinct distinct ADJ eurjchem-34 46 12     SPACE eurjchem-34 46 13 difference difference NOUN eurjchem-34 46 14     SPACE eurjchem-34 46 15 is be AUX eurjchem-34 46 16     SPACE eurjchem-34 46 17 reflected reflect VERB eurjchem-34 46 18     SPACE eurjchem-34 46 19 by by ADP eurjchem-34 46 20     SPACE eurjchem-34 46 21 the the DET eurjchem-34 46 22     SPACE eurjchem-34 46 23 dihedral dihedral ADJ eurjchem-34 46 24     SPACE eurjchem-34 46 25 angles angle NOUN eurjchem-34 46 26     SPACE eurjchem-34 46 27 between between ADP eurjchem-34 46 28     SPACE eurjchem-34 46 29 the the DET eurjchem-34 46 30     SPACE eurjchem-34 46 31 aryl aryl NOUN eurjchem-34 46 32     SPACE eurjchem-34 46 33 rings ring NOUN eurjchem-34 46 34 : : PUNCT eurjchem-34 46 35     SPACE eurjchem-34 46 36 for for ADP eurjchem-34 46 37     SPACE eurjchem-34 46 38 the the DET eurjchem-34 46 39     SPACE eurjchem-34 46 40 nitro nitro NOUN eurjchem-34 46 41     SPACE eurjchem-34 46 42 compound compound NOUN eurjchem-34 46 43     SPACE eurjchem-34 47 1 [ [ X eurjchem-34 47 2 11 11 NUM eurjchem-34 47 3 ] ] SYM eurjchem-34 47 4     SPACE eurjchem-34 47 5 it it PRON eurjchem-34 47 6     SPACE eurjchem-34 47 7 is be AUX eurjchem-34 47 8     SPACE eurjchem-34 47 9 28.1(1 28.1(1 NUM eurjchem-34 47 10 ) ) PUNCT eurjchem-34 47 11 ° ° NOUN eurjchem-34 47 12 , , PUNCT eurjchem-34 47 13     SPACE eurjchem-34 47 14 for for ADP eurjchem-34 47 15     SPACE eurjchem-34 47 16 the the DET eurjchem-34 47 17     SPACE eurjchem-34 47 18 br br NOUN eurjchem-34 47 19     SPACE eurjchem-34 48 1 [ [ X eurjchem-34 48 2 12 12 NUM eurjchem-34 48 3 ] ] SYM eurjchem-34 48 4     SPACE eurjchem-34 48 5 and and CCONJ eurjchem-34 48 6     SPACE eurjchem-34 48 7 the the DET eurjchem-34 48 8     SPACE eurjchem-34 48 9 cl cl NOUN eurjchem-34 48 10     SPACE eurjchem-34 48 11 compounds compound VERB eurjchem-34 48 12     SPACE eurjchem-34 49 1 [ [ X eurjchem-34 49 2 10 10 NUM eurjchem-34 49 3 ] ] PUNCT eurjchem-34 49 4     SPACE eurjchem-34 49 5 it it PRON eurjchem-34 49 6     SPACE eurjchem-34 49 7 measures measure VERB eurjchem-34 49 8     SPACE eurjchem-34 49 9 14.3(1 14.3(1 NUM eurjchem-34 49 10 ) ) PUNCT eurjchem-34 49 11 ° ° NOUN eurjchem-34 49 12     SPACE eurjchem-34 49 13 and and CCONJ eurjchem-34 49 14     SPACE eurjchem-34 49 15 30.5(1 30.5(1 PROPN eurjchem-34 49 16 ) ) PUNCT eurjchem-34 49 17 ° ° NOUN eurjchem-34 49 18 , , PUNCT eurjchem-34 49 19     SPACE eurjchem-34 49 20 respectively respectively ADV eurjchem-34 49 21 . . PUNCT eurjchem-34 49 22     SPACE eurjchem-34 50 1 strong strong ADJ eurjchem-34 50 2     SPACE eurjchem-34 50 3 intermolecular intermolecular ADJ eurjchem-34 50 4     SPACE eurjchem-34 50 5 n(3)‐ n(3)‐ PROPN eurjchem-34 50 6 saeed saeed PROPN eurjchem-34 50 7     SPACE eurjchem-34 50 8 et et PROPN eurjchem-34 50 9     SPACE eurjchem-34 50 10 al al PROPN eurjchem-34 50 11 . . PROPN eurjchem-34 50 12     SPACE eurjchem-34 50 13 / / SYM eurjchem-34 50 14     SPACE eurjchem-34 50 15 european european ADJ eurjchem-34 50 16     SPACE eurjchem-34 50 17 journal journal NOUN eurjchem-34 50 18     SPACE eurjchem-34 50 19 of of ADP eurjchem-34 50 20     SPACE eurjchem-34 50 21 chemistry chemistry NOUN eurjchem-34 50 22     SPACE eurjchem-34 50 23 1 1 NUM eurjchem-34 50 24     SPACE eurjchem-34 50 25 ( ( PUNCT eurjchem-34 50 26 2 2 NUM eurjchem-34 50 27 ) ) PUNCT eurjchem-34 50 28     SPACE eurjchem-34 50 29 ( ( PUNCT eurjchem-34 50 30 2010 2010 NUM eurjchem-34 50 31 ) ) PUNCT eurjchem-34 50 32     SPACE eurjchem-34 51 1 73­75 73­75 NUM eurjchem-34 51 2     SPACE eurjchem-34 51 3 75 75 NUM eurjchem-34 51 4     SPACE eurjchem-34 51 5 h h NOUN eurjchem-34 51 6 … … PUNCT eurjchem-34 51 7 o(2 o(2 PROPN eurjchem-34 51 8 ) ) PUNCT eurjchem-34 51 9     SPACE eurjchem-34 51 10 hydrogen hydrogen NOUN eurjchem-34 51 11     SPACE eurjchem-34 51 12 bonds bond NOUN eurjchem-34 51 13     SPACE eurjchem-34 51 14 link link NOUN eurjchem-34 51 15     SPACE eurjchem-34 51 16 molecules molecule NOUN eurjchem-34 51 17     SPACE eurjchem-34 51 18 to to ADP eurjchem-34 51 19     SPACE eurjchem-34 51 20 head‐to‐head head‐to‐head PROPN eurjchem-34 51 21     SPACE eurjchem-34 51 22 dimers dimer NOUN eurjchem-34 51 23     SPACE eurjchem-34 51 24 that that PRON eurjchem-34 51 25     SPACE eurjchem-34 51 26 are be AUX eurjchem-34 51 27     SPACE eurjchem-34 51 28 stacked stack VERB eurjchem-34 51 29     SPACE eurjchem-34 51 30 along along ADP eurjchem-34 51 31     SPACE eurjchem-34 52 1 [ [ X eurjchem-34 52 2 100 100 NUM eurjchem-34 52 3 ] ] PUNCT eurjchem-34 52 4     SPACE eurjchem-34 52 5 ( ( PUNCT eurjchem-34 52 6 table table NOUN eurjchem-34 52 7     SPACE eurjchem-34 52 8 2 2 NUM eurjchem-34 52 9 ) ) PUNCT eurjchem-34 52 10 . . PUNCT eurjchem-34 52 11         SPACE eurjchem-34 53 1 table table NOUN eurjchem-34 53 2     SPACE eurjchem-34 53 3 2 2 NUM eurjchem-34 53 4 . . PUNCT eurjchem-34 53 5     SPACE eurjchem-34 53 6 selected select VERB eurjchem-34 53 7     SPACE eurjchem-34 53 8 geometric geometric ADJ eurjchem-34 53 9     SPACE eurjchem-34 53 10 parameters parameter NOUN eurjchem-34 53 11     SPACE eurjchem-34 53 12 ( ( PUNCT eurjchem-34 53 13 å å PROPN eurjchem-34 53 14 , , PUNCT eurjchem-34 53 15     SPACE eurjchem-34 53 16 ° ° NOUN eurjchem-34 53 17 ) ) PUNCT eurjchem-34 53 18     SPACE eurjchem-34 53 19 for for ADP eurjchem-34 53 20     SPACE eurjchem-34 53 21 1‐(4‐methylbenzoyl)‐3‐(4‐ 1‐(4‐methylbenzoyl)‐3‐(4‐ NUM eurjchem-34 53 22 aminosulfonylphenyl)thiourea aminosulfonylphenyl)thiourea PROPN eurjchem-34 53 23 . . PUNCT eurjchem-34 53 24     SPACE eurjchem-34 53 25 bond bond NOUN eurjchem-34 53 26     SPACE eurjchem-34 53 27 lengths length NOUN eurjchem-34 53 28     SPACE eurjchem-34 53 29 s1‐c7 s1‐c7 PROPN eurjchem-34 53 30     SPACE eurjchem-34 53 31 1.656(2 1.656(2 NUM eurjchem-34 53 32 ) ) PUNCT eurjchem-34 53 33     SPACE eurjchem-34 53 34 c1‐n1 c1‐n1 ADV eurjchem-34 53 35     SPACE eurjchem-34 53 36 1.411(3 1.411(3 NUM eurjchem-34 53 37 ) ) PUNCT eurjchem-34 53 38     SPACE eurjchem-34 53 39 c7‐n1 c7‐n1 NOUN eurjchem-34 53 40     SPACE eurjchem-34 53 41 1.346(2 1.346(2 NUM eurjchem-34 53 42 ) ) PUNCT eurjchem-34 53 43     SPACE eurjchem-34 53 44 c7‐n2 c7‐n2 NOUN eurjchem-34 53 45     SPACE eurjchem-34 53 46 1.394(2 1.394(2 NUM eurjchem-34 53 47 ) ) PUNCT eurjchem-34 53 48     SPACE eurjchem-34 53 49 c8‐n2 c8‐n2 NOUN eurjchem-34 53 50     SPACE eurjchem-34 53 51 1.374(2 1.374(2 NUM eurjchem-34 53 52 ) ) PUNCT eurjchem-34 53 53     SPACE eurjchem-34 53 54 c8‐o1 c8‐o1 NOUN eurjchem-34 53 55     SPACE eurjchem-34 53 56 1.230(2 1.230(2 NUM eurjchem-34 53 57 ) ) PUNCT eurjchem-34 53 58     SPACE eurjchem-34 53 59 c8‐c9 c8‐c9 NUM eurjchem-34 53 60     SPACE eurjchem-34 53 61 1.479(3 1.479(3 NUM eurjchem-34 53 62 ) ) PUNCT eurjchem-34 53 63     SPACE eurjchem-34 53 64 s2‐c4 s2‐c4 ADV eurjchem-34 53 65     SPACE eurjchem-34 53 66 1.7607(19 1.7607(19 NUM eurjchem-34 53 67 ) ) PUNCT eurjchem-34 53 68     SPACE eurjchem-34 53 69 s2‐n3 s2‐n3 NOUN eurjchem-34 53 70     SPACE eurjchem-34 53 71 1.6172(19 1.6172(19 NUM eurjchem-34 53 72 ) ) PUNCT eurjchem-34 53 73     SPACE eurjchem-34 53 74 h3‐h2 h3‐h2 NOUN eurjchem-34 53 75     SPACE eurjchem-34 53 76 0.88(3 0.88(3 NOUN eurjchem-34 53 77 ) ) PUNCT eurjchem-34 53 78     SPACE eurjchem-34 53 79 h2 h2 NOUN eurjchem-34 53 80 … … PUNCT eurjchem-34 53 81 .o2 .o2 NOUN eurjchem-34 53 82     SPACE eurjchem-34 53 83 2.18(3 2.18(3 NUM eurjchem-34 53 84 ) ) PUNCT eurjchem-34 53 85     SPACE eurjchem-34 53 86 n3 n3 NOUN eurjchem-34 53 87 … … SYM eurjchem-34 53 88 .o2 .o2 NOUN eurjchem-34 53 89     SPACE eurjchem-34 53 90 3.016(3 3.016(3 NUM eurjchem-34 53 91 ) ) PUNCT eurjchem-34 53 92     SPACE eurjchem-34 53 93 bond bond NOUN eurjchem-34 53 94     SPACE eurjchem-34 53 95 angles angle VERB eurjchem-34 53 96     SPACE eurjchem-34 53 97 c1‐n1‐c7 c1‐n1‐c7 PROPN eurjchem-34 53 98     SPACE eurjchem-34 53 99 128.50(17 128.50(17 NUM eurjchem-34 53 100 ) ) PUNCT eurjchem-34 53 101     SPACE eurjchem-34 53 102 n1‐c7‐n2 n1‐c7‐n2 PROPN eurjchem-34 53 103     SPACE eurjchem-34 53 104 114.38(17 114.38(17 NUM eurjchem-34 53 105 ) ) PUNCT eurjchem-34 53 106     SPACE eurjchem-34 53 107 c7‐n2‐c8 c7‐n2‐c8 PROPN eurjchem-34 53 108     SPACE eurjchem-34 53 109 128.47(16 128.47(16 NUM eurjchem-34 53 110 ) ) PUNCT eurjchem-34 53 111     SPACE eurjchem-34 53 112 n2‐c8‐c9 n2‐c8‐c9 PROPN eurjchem-34 53 113     SPACE eurjchem-34 53 114 117.40(17 117.40(17 NUM eurjchem-34 53 115 ) ) PUNCT eurjchem-34 53 116     SPACE eurjchem-34 53 117 n3‐h2 n3‐h2 NOUN eurjchem-34 53 118 … … PUNCT eurjchem-34 53 119 .o2 .o2 NOUN eurjchem-34 53 120     SPACE eurjchem-34 53 121 158(2 158(2 NUM eurjchem-34 53 122 ) ) PUNCT eurjchem-34 53 123         SPACE eurjchem-34 53 124 acknowledgement acknowledgement NOUN eurjchem-34 53 125           SPACE eurjchem-34 53 126 a.m. a.m. ADV eurjchem-34 53 127     SPACE eurjchem-34 53 128 gratefully gratefully ADV eurjchem-34 53 129     SPACE eurjchem-34 53 130 acknowledges acknowledge VERB eurjchem-34 53 131     SPACE eurjchem-34 53 132 a a DET eurjchem-34 53 133     SPACE eurjchem-34 53 134 research research NOUN eurjchem-34 53 135     SPACE eurjchem-34 53 136 scholarship scholarship NOUN eurjchem-34 53 137     SPACE eurjchem-34 53 138 from from ADP eurjchem-34 53 139     SPACE eurjchem-34 53 140 hec hec PROPN eurjchem-34 53 141     SPACE eurjchem-34 53 142 islamabad islamabad PROPN eurjchem-34 53 143     SPACE eurjchem-34 53 144 under under ADP eurjchem-34 53 145     SPACE eurjchem-34 53 146 hec hec PROPN eurjchem-34 53 147     SPACE eurjchem-34 53 148 indigenous indigenous ADJ eurjchem-34 53 149     SPACE eurjchem-34 53 150 phd phd NOUN eurjchem-34 53 151     SPACE eurjchem-34 53 152 scholarship scholarship NOUN eurjchem-34 53 153     SPACE eurjchem-34 53 154 5000 5000 NUM eurjchem-34 53 155     SPACE eurjchem-34 53 156 scheme scheme NOUN eurjchem-34 53 157 . . PUNCT eurjchem-34 53 158         SPACE eurjchem-34 53 159 supplementary supplementary ADJ eurjchem-34 53 160     SPACE eurjchem-34 53 161 material material NOUN eurjchem-34 53 162         SPACE eurjchem-34 53 163 ccdc‐679109 ccdc‐679109 VERB eurjchem-34 53 164     SPACE eurjchem-34 53 165 contains contain VERB eurjchem-34 53 166     SPACE eurjchem-34 53 167 the the DET eurjchem-34 53 168     SPACE eurjchem-34 53 169 supplementary supplementary ADJ eurjchem-34 53 170     SPACE eurjchem-34 53 171 crystallographic crystallographic ADJ eurjchem-34 53 172     SPACE eurjchem-34 53 173 data datum NOUN eurjchem-34 53 174     SPACE eurjchem-34 53 175 for for ADP eurjchem-34 53 176     SPACE eurjchem-34 53 177 this this DET eurjchem-34 53 178     SPACE eurjchem-34 53 179 paper paper NOUN eurjchem-34 53 180 . . PUNCT eurjchem-34 53 181     SPACE eurjchem-34 54 1 these these DET eurjchem-34 54 2     SPACE eurjchem-34 54 3 data datum NOUN eurjchem-34 54 4     SPACE eurjchem-34 54 5 can can AUX eurjchem-34 54 6     SPACE eurjchem-34 54 7 be be AUX eurjchem-34 54 8     SPACE eurjchem-34 54 9 obtained obtain VERB eurjchem-34 54 10     SPACE eurjchem-34 54 11 free free ADJ eurjchem-34 54 12     SPACE eurjchem-34 54 13 of of ADP eurjchem-34 54 14     SPACE eurjchem-34 54 15 charge charge NOUN eurjchem-34 54 16     SPACE eurjchem-34 54 17 via via ADP eurjchem-34 54 18     SPACE eurjchem-34 54 19 www.ccdc.cam.ac.uk/data_request/cif www.ccdc.cam.ac.uk/data_request/cif NOUN eurjchem-34 54 20 , , PUNCT eurjchem-34 54 21     SPACE eurjchem-34 54 22 or or CCONJ eurjchem-34 54 23     SPACE eurjchem-34 54 24 by by ADP eurjchem-34 54 25     SPACE eurjchem-34 54 26 e‐mailing e‐mailing NOUN eurjchem-34 54 27     SPACE eurjchem-34 54 28 data_request@ccdc.cam.ac.uk data_request@ccdc.cam.ac.uk PROPN eurjchem-34 54 29 , , PUNCT eurjchem-34 54 30     SPACE eurjchem-34 54 31 or or CCONJ eurjchem-34 54 32     SPACE eurjchem-34 54 33 by by ADP eurjchem-34 54 34     SPACE eurjchem-34 54 35 contacting contact VERB eurjchem-34 54 36     SPACE eurjchem-34 54 37 the the DET eurjchem-34 54 38     SPACE eurjchem-34 54 39 cambridge cambridge PROPN eurjchem-34 54 40     SPACE eurjchem-34 54 41 crystallographic crystallographic ADJ eurjchem-34 54 42     SPACE eurjchem-34 54 43 data data NOUN eurjchem-34 54 44     SPACE eurjchem-34 54 45 centre centre NOUN eurjchem-34 54 46 , , PUNCT eurjchem-34 54 47     SPACE eurjchem-34 54 48 12 12 NUM eurjchem-34 54 49     SPACE eurjchem-34 54 50 union union NOUN eurjchem-34 54 51     SPACE eurjchem-34 54 52 road road NOUN eurjchem-34 54 53 , , PUNCT eurjchem-34 54 54     SPACE eurjchem-34 54 55 cambridge cambridge PROPN eurjchem-34 54 56     SPACE eurjchem-34 54 57 cb21ez cb21ez PROPN eurjchem-34 54 58 , , PUNCT eurjchem-34 54 59     SPACE eurjchem-34 54 60 uk uk PROPN eurjchem-34 54 61 ; ; PUNCT eurjchem-34 54 62     SPACE eurjchem-34 54 63 fax fax NOUN eurjchem-34 54 64 : : PUNCT eurjchem-34 54 65     SPACE eurjchem-34 54 66 +44(0)1223‐336033 +44(0)1223‐336033 ADJ eurjchem-34 54 67 . . PUNCT eurjchem-34 54 68         SPACE eurjchem-34 54 69 references reference NOUN eurjchem-34 54 70           SPACE eurjchem-34 55 1 [ [ X eurjchem-34 55 2 1 1 NUM eurjchem-34 55 3 ] ] PUNCT eurjchem-34 55 4 . . PUNCT eurjchem-34 56 1 koch koch PROPN eurjchem-34 56 2 , , PUNCT eurjchem-34 56 3     SPACE eurjchem-34 56 4 k.r k.r PROPN eurjchem-34 56 5 . . PROPN eurjchem-34 56 6     SPACE eurjchem-34 56 7 coord coord NOUN eurjchem-34 56 8 . . PUNCT eurjchem-34 56 9     SPACE eurjchem-34 56 10 chem chem NOUN eurjchem-34 56 11 . . PUNCT eurjchem-34 56 12     SPACE eurjchem-34 56 13 rev.2001 rev.2001 NOUN eurjchem-34 56 14 , , PUNCT eurjchem-34 56 15     SPACE eurjchem-34 56 16 216­217 216­217 NUM eurjchem-34 56 17 , , PUNCT eurjchem-34 56 18     SPACE eurjchem-34 56 19 473‐488 473‐488 NOUN eurjchem-34 56 20       SPACE eurjchem-34 57 1 [ [ X eurjchem-34 57 2 2 2 NUM eurjchem-34 57 3 ] ] PUNCT eurjchem-34 57 4 . . PUNCT eurjchem-34 58 1 krishnamurthy krishnamurthy PROPN eurjchem-34 58 2 , , PUNCT eurjchem-34 58 3     SPACE eurjchem-34 58 4 r. r. PROPN eurjchem-34 58 5 ; ; PUNCT eurjchem-34 58 6     SPACE eurjchem-34 58 7 govindaraghavan govindaraghavan NOUN eurjchem-34 58 8 , , PUNCT eurjchem-34 58 9     SPACE eurjchem-34 58 10 s. s. PROPN eurjchem-34 58 11 ; ; PUNCT eurjchem-34 58 12     SPACE eurjchem-34 58 13 narayanasamy narayanasamy NOUN eurjchem-34 58 14 , , PUNCT eurjchem-34 58 15     SPACE eurjchem-34 58 16 j. j. PROPN eurjchem-34 58 17     SPACE eurjchem-34 58 18 pesticide pesticide NOUN eurjchem-34 58 19     SPACE eurjchem-34 58 20 science science NOUN eurjchem-34 58 21     SPACE eurjchem-34 58 22 1999 1999 NUM eurjchem-34 58 23 , , PUNCT eurjchem-34 58 24     SPACE eurjchem-34 58 25 52 52 NUM eurjchem-34 58 26 , , PUNCT eurjchem-34 58 27     SPACE eurjchem-34 58 28 145‐151 145‐151 NUM eurjchem-34 58 29 . . PUNCT eurjchem-34 58 30     SPACE eurjchem-34 59 1 [ [ X eurjchem-34 59 2 3 3 NUM eurjchem-34 59 3 ] ] PUNCT eurjchem-34 59 4 . . PUNCT eurjchem-34 60 1 sijia sijia NOUN eurjchem-34 60 2 , , PUNCT eurjchem-34 60 3     SPACE eurjchem-34 60 4 x. x. NOUN eurjchem-34 60 5 ; ; PUNCT eurjchem-34 60 6     SPACE eurjchem-34 60 7 liping liping PROPN eurjchem-34 60 8 , , PUNCT eurjchem-34 60 9     SPACE eurjchem-34 60 10 d. d. PROPN eurjchem-34 60 11 ; ; PUNCT eurjchem-34 60 12     SPACE eurjchem-34 60 13 .shaoyong .shaoyong PROPN eurjchem-34 60 14 , , PUNCT eurjchem-34 60 15     SPACE eurjchem-34 60 16 c. c. NOUN eurjchem-34 60 17 ; ; PUNCT eurjchem-34 60 18     SPACE eurjchem-34 60 19 liangbin liangbin NOUN eurjchem-34 60 20 , , PUNCT eurjchem-34 60 21     SPACE eurjchem-34 60 22 j. j. PROPN eurjchem-34 60 23     SPACE eurjchem-34 60 24 chem chem NOUN eurjchem-34 60 25 . . PUNCT eurjchem-34 60 26     SPACE eurjchem-34 61 1 j. j. PROPN eurjchem-34 61 2     SPACE eurjchem-34 61 3 internet internet NOUN eurjchem-34 61 4     SPACE eurjchem-34 61 5 2003 2003 NUM eurjchem-34 61 6 , , PUNCT eurjchem-34 61 7     SPACE eurjchem-34 61 8 5 5 NUM eurjchem-34 61 9 , , PUNCT eurjchem-34 61 10     SPACE eurjchem-34 61 11 67‐70 67‐70 NOUN eurjchem-34 61 12 . . PUNCT eurjchem-34 61 13     SPACE eurjchem-34 62 1 [ [ X eurjchem-34 62 2 4 4 NUM eurjchem-34 62 3 ] ] PUNCT eurjchem-34 62 4 . . PUNCT eurjchem-34 63 1 wang wang PROPN eurjchem-34 63 2 , , PUNCT eurjchem-34 63 3     SPACE eurjchem-34 63 4 x‐c x‐c PROPN eurjchem-34 63 5 . . PUNCT eurjchem-34 63 6 ; ; PUNCT eurjchem-34 63 7     SPACE eurjchem-34 63 8 wang wang PROPN eurjchem-34 63 9 , , PUNCT eurjchem-34 63 10     SPACE eurjchem-34 63 11 v. v. PROPN eurjchem-34 63 12 ; ; PUNCT eurjchem-34 63 13     SPACE eurjchem-34 63 14 quan quan PROPN eurjchem-34 63 15 , , PUNCT eurjchem-34 63 16     SPACE eurjchem-34 63 17 z‐j z‐j PROPN eurjchem-34 63 18 . . PUNCT eurjchem-34 63 19 ; ; PUNCT eurjchem-34 63 20     SPACE eurjchem-34 64 1 wang wang PROPN eurjchem-34 64 2 , , PUNCT eurjchem-34 64 3     SPACE eurjchem-34 64 4 m‐g m‐g PROPN eurjchem-34 64 5 . . PUNCT eurjchem-34 64 6 ; ; PUNCT eurjchem-34 64 7     SPACE eurjchem-34 64 8 li li PROPN eurjchem-34 64 9 , , PUNCT eurjchem-34 64 10     SPACE eurjchem-34 64 11 z. z. PROPN eurjchem-34 64 12     SPACE eurjchem-34 64 13 j. j. PROPN eurjchem-34 64 14     SPACE eurjchem-34 64 15 chem chem NOUN eurjchem-34 64 16 . . PUNCT eurjchem-34 64 17     SPACE eurjchem-34 64 18 res re NOUN eurjchem-34 64 19 . . PUNCT eurjchem-34 64 20 , , PUNCT eurjchem-34 64 21     SPACE eurjchem-34 64 22 2005 2005 NUM eurjchem-34 64 23 , , PUNCT eurjchem-34 64 24     SPACE eurjchem-34 64 25 61 61 NUM eurjchem-34 64 26 , , PUNCT eurjchem-34 64 27     SPACE eurjchem-34 64 28 689‐690 689‐690 NUM eurjchem-34 64 29 . . PUNCT eurjchem-34 64 30     SPACE eurjchem-34 65 1 [ [ X eurjchem-34 65 2 5 5 NUM eurjchem-34 65 3 ] ] PUNCT eurjchem-34 65 4 . . PUNCT eurjchem-34 66 1 saeed saeed PROPN eurjchem-34 66 2 , , PUNCT eurjchem-34 66 3     SPACE eurjchem-34 66 4 a. a. NOUN eurjchem-34 66 5 ; ; PUNCT eurjchem-34 66 6     SPACE eurjchem-34 66 7 parvez parvez ADJ eurjchem-34 66 8 , , PUNCT eurjchem-34 66 9     SPACE eurjchem-34 66 10 m. m. NOUN eurjchem-34 66 11     SPACE eurjchem-34 66 12 j. j. PROPN eurjchem-34 66 13     SPACE eurjchem-34 66 14 heterocyl heterocyl NOUN eurjchem-34 66 15 . . PUNCT eurjchem-34 66 16     SPACE eurjchem-34 66 17 chem chem NOUN eurjchem-34 66 18 . . PUNCT eurjchem-34 66 19     SPACE eurjchem-34 66 20 2006 2006 NUM eurjchem-34 66 21 , , PUNCT eurjchem-34 66 22     SPACE eurjchem-34 66 23 43 43 NUM eurjchem-34 66 24 , , PUNCT eurjchem-34 66 25     SPACE eurjchem-34 66 26 1027‐1030 1027‐1030 NUM eurjchem-34 66 27 . . PUNCT eurjchem-34 66 28       SPACE eurjchem-34 67 1 [ [ X eurjchem-34 67 2 6 6 NUM eurjchem-34 67 3 ] ] PUNCT eurjchem-34 67 4 . . PUNCT eurjchem-34 67 5 snieckus sniecku NOUN eurjchem-34 67 6 , , PUNCT eurjchem-34 67 7     SPACE eurjchem-34 67 8 v v NOUN eurjchem-34 67 9 ; ; PUNCT eurjchem-34 67 10     SPACE eurjchem-34 67 11 chem chem NOUN eurjchem-34 67 12 . . PUNCT eurjchem-34 67 13     SPACE eurjchem-34 67 14 rev rev VERB eurjchem-34 67 15 . . PUNCT eurjchem-34 67 16     SPACE eurjchem-34 67 17 1990 1990 NUM eurjchem-34 67 18 , , PUNCT eurjchem-34 67 19     SPACE eurjchem-34 67 20 90 90 NUM eurjchem-34 67 21 , , PUNCT eurjchem-34 67 22     SPACE eurjchem-34 67 23 879‐933 879‐933 NOUN eurjchem-34 67 24       SPACE eurjchem-34 68 1 [ [ X eurjchem-34 68 2 7 7 NUM eurjchem-34 68 3 ] ] PUNCT eurjchem-34 68 4 . . PUNCT eurjchem-34 69 1 bestmann bestmann PROPN eurjchem-34 69 2 , , PUNCT eurjchem-34 69 3     SPACE eurjchem-34 69 4 h.j h.j PROPN eurjchem-34 69 5 . . PROPN eurjchem-34 69 6 ; ; PUNCT eurjchem-34 69 7     SPACE eurjchem-34 69 8 kern kern PROPN eurjchem-34 69 9 , , PUNCT eurjchem-34 69 10     SPACE eurjchem-34 69 11 f. f. PROPN eurjchem-34 69 12 ; ; PUNCT eurjchem-34 69 13     SPACE eurjchem-34 69 14 schafer schafer NOUN eurjchem-34 69 15 , , PUNCT eurjchem-34 69 16     SPACE eurjchem-34 69 17 d. d. PROPN eurjchem-34 69 18 ; ; PUNCT eurjchem-34 69 19     SPACE eurjchem-34 69 20 witschel witschel PROPN eurjchem-34 69 21 , , PUNCT eurjchem-34 69 22     SPACE eurjchem-34 69 23 m.c m.c PROPN eurjchem-34 69 24 . . PROPN eurjchem-34 69 25     SPACE eurjchem-34 69 26 angew angew PROPN eurjchem-34 69 27 . . PUNCT eurjchem-34 69 28     SPACE eurjchem-34 69 29 chem chem NOUN eurjchem-34 69 30 . . PUNCT eurjchem-34 69 31     SPACE eurjchem-34 69 32 int int NOUN eurjchem-34 69 33 . . PUNCT eurjchem-34 69 34     SPACE eurjchem-34 70 1 ed ed NOUN eurjchem-34 70 2 . . PUNCT eurjchem-34 70 3     SPACE eurjchem-34 70 4 engl engl PROPN eurjchem-34 70 5 . . PUNCT eurjchem-34 70 6     SPACE eurjchem-34 70 7 1992 1992 NUM eurjchem-34 70 8     SPACE eurjchem-34 70 9 31 31 NUM eurjchem-34 70 10 , , PUNCT eurjchem-34 70 11     SPACE eurjchem-34 70 12 795‐796 795‐796 NUM eurjchem-34 70 13 . . PUNCT eurjchem-34 70 14     SPACE eurjchem-34 71 1 [ [ X eurjchem-34 71 2 8 8 NUM eurjchem-34 71 3 ] ] PUNCT eurjchem-34 71 4 . . PUNCT eurjchem-34 71 5 stokstad stokstad PROPN eurjchem-34 71 6 , , PUNCT eurjchem-34 71 7     SPACE eurjchem-34 71 8 e. e. PROPN eurjchem-34 71 9     SPACE eurjchem-34 71 10 l. l. PROPN eurjchem-34 71 11     SPACE eurjchem-34 71 12 r. r. PROPN eurjchem-34 71 13 ; ; PUNCT eurjchem-34 71 14     SPACE eurjchem-34 71 15 jãoekes jãoeke NOUN eurjchem-34 71 16 , , PUNCT eurjchem-34 71 17     SPACE eurjchem-34 71 18 t. t. PROPN eurjchem-34 71 19     SPACE eurjchem-34 71 20 h. h. PROPN eurjchem-34 71 21     SPACE eurjchem-34 71 22 j. j. PROPN eurjchem-34 71 23     SPACE eurjchem-34 71 24 nutr nutr PROPN eurjchem-34 71 25 . . PUNCT eurjchem-34 71 26     SPACE eurjchem-34 71 27 1987 1987 NUM eurjchem-34 71 28 , , PUNCT eurjchem-34 71 29     SPACE eurjchem-34 71 30 117 117 NUM eurjchem-34 71 31 ; ; PUNCT eurjchem-34 71 32     SPACE eurjchem-34 71 33 1335‐1341 1335‐1341 NUM eurjchem-34 71 34 . . PUNCT eurjchem-34 71 35     SPACE eurjchem-34 71 36 [ [ X eurjchem-34 71 37 9 9 NUM eurjchem-34 71 38 ] ] PUNCT eurjchem-34 71 39 . . PUNCT eurjchem-34 72 1 botet botet PROPN eurjchem-34 72 2 , , PUNCT eurjchem-34 72 3     SPACE eurjchem-34 72 4 j. j. PROPN eurjchem-34 72 5 ; ; PUNCT eurjchem-34 72 6     SPACE eurjchem-34 72 7 mateos mateo NOUN eurjchem-34 72 8 , , PUNCT eurjchem-34 72 9     SPACE eurjchem-34 72 10 l. l. PROPN eurjchem-34 72 11 ; ; PUNCT eurjchem-34 72 12     SPACE eurjchem-34 72 13 revuelta revuelta NOUN eurjchem-34 72 14 , , PUNCT eurjchem-34 72 15     SPACE eurjchem-34 72 16 j. j. PROPN eurjchem-34 72 17     SPACE eurjchem-34 72 18 l l PROPN eurjchem-34 72 19 ; ; PUNCT eurjchem-34 72 20     SPACE eurjchem-34 72 21 santos santo NOUN eurjchem-34 72 22 , , PUNCT eurjchem-34 72 23     SPACE eurjchem-34 72 24 m. m. NOUN eurjchem-34 72 25     SPACE eurjchem-34 72 26 a. a. NOUN eurjchem-34 72 27     SPACE eurjchem-34 72 28 eukaryotic eukaryotic ADJ eurjchem-34 72 29     SPACE eurjchem-34 72 30 cell cell NOUN eurjchem-34 72 31 , , PUNCT eurjchem-34 72 32     SPACE eurjchem-34 72 33 2007 2007 NUM eurjchem-34 72 34 , , PUNCT eurjchem-34 72 35     SPACE eurjchem-34 72 36 2102–2111 2102–2111 NUM eurjchem-34 72 37 . . PUNCT eurjchem-34 72 38     SPACE eurjchem-34 73 1 [ [ X eurjchem-34 73 2 10 10 NUM eurjchem-34 73 3 ] ] PUNCT eurjchem-34 73 4 . . PUNCT eurjchem-34 74 1 saeed saeed PROPN eurjchem-34 74 2 , , PUNCT eurjchem-34 74 3     SPACE eurjchem-34 74 4 a. a. NOUN eurjchem-34 74 5 ; ; PUNCT eurjchem-34 74 6     SPACE eurjchem-34 74 7 flörke flörke NOUN eurjchem-34 74 8 , , PUNCT eurjchem-34 74 9     SPACE eurjchem-34 74 10 u. u. NOUN eurjchem-34 74 11     SPACE eurjchem-34 74 12 acta acta PROPN eurjchem-34 74 13     SPACE eurjchem-34 74 14 cryst cryst PROPN eurjchem-34 74 15 . . PUNCT eurjchem-34 74 16     SPACE eurjchem-34 75 1 2006 2006 NUM eurjchem-34 75 2 , , PUNCT eurjchem-34 75 3     SPACE eurjchem-34 75 4 e62 e62 NOUN eurjchem-34 75 5 , , PUNCT eurjchem-34 75 6     SPACE eurjchem-34 75 7 o2924‐ o2924‐ NOUN eurjchem-34 75 8     SPACE eurjchem-34 75 9 o2924 o2924 NOUN eurjchem-34 75 10 . . PUNCT eurjchem-34 75 11     SPACE eurjchem-34 76 1 [ [ X eurjchem-34 76 2 11 11 NUM eurjchem-34 76 3 ] ] PUNCT eurjchem-34 76 4 . . PUNCT eurjchem-34 77 1 yusof yusof PROPN eurjchem-34 77 2 , , PUNCT eurjchem-34 77 3     SPACE eurjchem-34 77 4 m. m. NOUN eurjchem-34 77 5     SPACE eurjchem-34 77 6 s. s. PROPN eurjchem-34 77 7     SPACE eurjchem-34 77 8 m. m. NOUN eurjchem-34 77 9 ; ; PUNCT eurjchem-34 77 10     SPACE eurjchem-34 77 11 hamid hamid PROPN eurjchem-34 77 12 , , PUNCT eurjchem-34 77 13     SPACE eurjchem-34 77 14 m. m. NOUN eurjchem-34 77 15     SPACE eurjchem-34 77 16 a. a. NOUN eurjchem-34 77 17 ; ; PUNCT eurjchem-34 77 18     SPACE eurjchem-34 77 19 ramli ramli ADJ eurjchem-34 77 20 , , PUNCT eurjchem-34 77 21     SPACE eurjchem-34 77 22 r. r. PROPN eurjchem-34 77 23     SPACE eurjchem-34 77 24 n. n. PROPN eurjchem-34 77 25     SPACE eurjchem-34 77 26 h. h. PROPN eurjchem-34 77 27     SPACE eurjchem-34 77 28 r. r. PROPN eurjchem-34 77 29 ; ; PUNCT eurjchem-34 77 30     SPACE eurjchem-34 77 31 yamin yamin PROPN eurjchem-34 77 32 , , PUNCT eurjchem-34 77 33     SPACE eurjchem-34 77 34 b. b. PROPN eurjchem-34 77 35     SPACE eurjchem-34 77 36 m. m. NOUN eurjchem-34 77 37     SPACE eurjchem-34 77 38 acta acta PROPN eurjchem-34 77 39     SPACE eurjchem-34 77 40 cryst cryst PROPN eurjchem-34 77 41 . . PUNCT eurjchem-34 77 42     SPACE eurjchem-34 78 1 2006 2006 NUM eurjchem-34 78 2 , , PUNCT eurjchem-34 78 3     SPACE eurjchem-34 78 4 e62 e62 NOUN eurjchem-34 78 5 , , PUNCT eurjchem-34 78 6     SPACE eurjchem-34 78 7 o2131‐ o2131‐ NOUN eurjchem-34 78 8     SPACE eurjchem-34 78 9 o2131 o2131 PROPN eurjchem-34 78 10 . . PUNCT eurjchem-34 78 11     SPACE eurjchem-34 79 1 [ [ X eurjchem-34 79 2 12 12 NUM eurjchem-34 79 3 ] ] PUNCT eurjchem-34 79 4 . . PUNCT eurjchem-34 80 1 saeed saeed PROPN eurjchem-34 80 2 , , PUNCT eurjchem-34 80 3     SPACE eurjchem-34 80 4 a. a. NOUN eurjchem-34 80 5 ; ; PUNCT eurjchem-34 80 6     SPACE eurjchem-34 80 7 flörke flörke NOUN eurjchem-34 80 8 , , PUNCT eurjchem-34 80 9     SPACE eurjchem-34 80 10 u. u. NOUN eurjchem-34 80 11     SPACE eurjchem-34 80 12 acta acta PROPN eurjchem-34 80 13     SPACE eurjchem-34 80 14 cryst cryst PROPN eurjchem-34 80 15 . . PUNCT eurjchem-34 80 16     SPACE eurjchem-34 81 1 2006 2006 NUM eurjchem-34 81 2 , , PUNCT eurjchem-34 81 3     SPACE eurjchem-34 81 4 e62 e62 NOUN eurjchem-34 81 5 , , PUNCT eurjchem-34 81 6     SPACE eurjchem-34 81 7 o5036‐o5036 o5036‐o5036 NOUN eurjchem-34 81 8 . . PUNCT eurjchem-34 81 9       SPACE